BOSTON
PUBLIC
LIBRARY
'.J^:
UNITED STATES TARIFF COMMISSION
7^
SYNTHETIC
ORGANIC CHEMICALS
United States Production
and Sales, 1972
TC Publication 681
RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON
SYNTHETIC ORGANIC CHEMICALS
Synthetic Organic Chemicals, United States Production and Sales, 1967 (TC Publication 295,
1969), $2.00
♦Synthetic Organic Chemicals, United States Production and Sales, 1968 (TC Publication 327,
1970), $2.00
♦Synthetic Organic Chemicals, United States Production and Sales, 1969 (TC Publication 412,
1971), $2.00
♦Synthetic Organic Chemicals, United States Production and Sales, 1970 (TC Publication 479,
1972), $2.00
Synthetic Organic Chemicals, United States Production and Sales, 1971 (TC Publication 614,
1973), $2.40
NOTE.— The reports preceded by an asterisk (*) are out of print. The other reports listed above may
purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20'!
All U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in tb
official depository libraries throughout the United States.
4ol
UNITED STATES TARIFF COMMISSION
SYNTHETIC
ORGANIC CHEMICALS
United States Production
and Sales, 1972
UNDER THE PROVISIONS OF
SECTION 332 OF THE TARIFF
ACT OF 1930, AS AMENDED
U.S. GOVERNMENT PRINTING OFFICE
WASHINGTON : 1974
TC PubUcation 681
UNITED STATES TARIFF COMMISSION
Catherine Bedell, Chairman
Joseph O. Parker, Vice Chairman
Will E. Leonard, Jr.
George M. Moore
J. Banks Young
Italo H. Ablondi
Kenneth R. Mason, Secretary
Address all communications
UNITED STATES TARIFF COMMISSION
Washington, D.C. 20436
For sale by the Superintendent of Documents. U.S. Government Printing Office, Washington. D.C. 20402
Price $2.70 Stock Number 4900-00038
CONTENTS
Page
Introduction 1
Summary 3
General 4
Tar 7
Tar crudes 7
Crude products from petroleum and natural gas
for chemical conversion 13
Cyclic intermediates 19
Dyes 55
Organic pigments 91
Medicinal chemicals 101
Flavor and perfume materials 121
Plastics and resin materials 133
Rubber-processing chemicals 141
Elastomers 149
Plasticizers 153
Surface-active agents 161
Pesticides and related products 189
Miscellaneous chemicals 199
APPENDIXES
A. Director of manufacturers 243
B. U.S. imports of benzenoid chemicals
and products 257
C. Cyclic intermediates: Glossary of
synonymous names 259
INTRODUCTION
This is the fifty-sixth annual report of the U.S. Tariff Commission on domestic production and sales of
synthetic organic chemicals and the raw materials from which they are made. It is authorized under the provisions
of section 332 of the Tariff .i^ct of 1930, as amended. The report consists of fourteen sections, each covering a
specified group (based principally on use) of organic chemicals as follows: tar and tar crudes; crude products from
petroleum and natural gas; intermediates; dyes; pigments; medicinal chemicals; flavor and perfume materials; plastics
and resin materials; rubber-processing chemicals; elastomers; plasticizers; surface-active agents; pesticides and
related products; and miscellaneous organic chemicals. Data have been supplied by approximately 800 producers.
The first table in each section gives statistics on products and groups of products in as great detail as is
possible without revealing the operations of individual producers. Statistics for an individual chemical or group
of chemicals are given only when there are three or more producers, no one or two of which may be predominant. More-
over, even when there are three or more producers, statistics are not given if there is any possibility that their
publication would violate tlie statutory provisions relating to unlawful disclosure of information accepted in con-
fidence by the Commission. '
"bata are reported by producers for only those items where the volume of production or sales exceeds 1,000 pounds
or the value of sales exceeds $1,000. They are usually given in terms of undiluted materials; however, products of
95 percent -or more purity are considered to be 100 percent pure. Commercial concentrations are applied to dyes,
certain plastics and resins, and a few solvents; such concentrations are specifically noted.
The statistics given in this report include data from all known domestic producers of the items covered and in-
clude the total output of each company's plants, i.e., the quantities produced for consumption within the producing
plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, there-
fore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to
changes in inventory.
The second table in each section lists all items for which data on production or sales have been reported, by
primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters
which is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes
of the manufacturers reporting in that section. Table I of the .A.ppendix is a directory, alphabetized by the names of
the manufacturers reporting in all sections and includes their office addresses.
Information on the synonymous names of the organic chemicals included in this report may be found in the SOCMA
Handbook: Commevoial Organic Chemical Names, published by the Chemical Abstracts Service of the .(^erican Chemical
Society, or the Colour Index (2d edition), published by the Society of Dyers and Colourists.
Table 2 of the Appendix summarizes and gives the competitive status of U.S. general imports in 1972 of benzenoid
intermediates and finished benzenoid products, entered under schedule 4, parts IB and IC, of the Tariff Schedules of
the United States.
As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise
specified) are definf^d as follows:
PEODUCTION is the total quantity pf a commodity made available
by original manufacturers only. It is the sum — expressed in terms
of 100% active ingredient unless othenrtse specified in the reporting
instructions — of the quantities:
Produced, separated, and consumed in the same plant or
establishment. A commodity is considered separated
when it is isolated from the reaction system and/or
when it is weighed, analyzed, or otherwise measured.
This includes byproducts and ooproduats that are not
classifiable as waste materials;
Produced and transferred to other plants or establish-
ments of the same firm;
Produced and sold to other firms, including production
for another under a toll agreement (i.e., an agreement,
under which one firm furnishes the raw materials- and
pays the processing costs and the other firm prepares
the finished product and returns it to the first firm)
Produced and held in stock.
Title 18, U.S.C. 1905 and Title 44, U.S.C. 3508
INTRODUCTION
PRODUCTION EXCLUDES:
Purification of a commodity^ unless inclusion of
suck processing is specifically requested in
the reporting instructions for individual
sections'.
Intermediate products which are formed in the
manufacturing process, but are not isolated
from the reaction system — that is, not
weighed, analyzed, or otherwise measured;
Materials that are used in the process but
which are recovered for re-use or sale;
Haste products having no economic significance.
SALES are actual quantities of commodities sold by ORIGINAL
MANUFACTURERS ONLY. Sales include the quantity and value of:
Shipments of a commodity for domestic use and
for export, or segregation in a warehouse
when title has passed to the purchaser in a
bona fide sale;
Shipments of a commodity produced by others under
toll agreements;
Shipments to subsidiary or affiliated companies.
SALES EXCLUDE:
All intra-company transfers within a corporate entity;
All sales of purchased commodities;
All shipments of a commodity produced for others
under toll agreements.
VALUE OF SALES is the net selling value f.o.b. plant or
warehouse, or delivered value, whichever represents the normal
industry practice.
SUMMARY 3
Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products from petroleum and
natural gas in 1972 was 266,419 million pounds--an increase of 12.0 percent over the output in 1971 (see table 1).
Sales of these materials in 1972, which totaled 150,818 million pounds, valued at $16,028 million, were 12.8 percent
larger than in 1971 in terms of quantity and 13.5 percent larger in terras of value. These figures include data on pro-
duction and sales of chemicals measured at several successive steps in the manufacturing process, and therefore they
necessarily reflect some duplication.
In 1972, production of all synthetic organic chemicals, including cyclic intermediates and finished chemical prod-
ucts, totaled 164,218 million pounds, or 15.2 percent more than the output in 1971. Production increased in 1972 com-
pared to 1971 for all subgroups of products. Among the groups with large volumes of production, plastics and resin
materials (25,921 million pounds) lead with an increase of 23.0 percent and cyclic intermediates (34,967 million pounds)
followed with an increase of 16.7 percent. Other groups in the large-volume production category increased as follows:
plasticiiers (1,708 million pounds), 14.3 percent; miscellaneous chemicals (90,476 million pounds), 13.9 percent;
elastomers (4,914 million pounds), 6.4 percent; surface-active agents (4,039 million pounds), 5.5 percent. In the groups
with smaller quantities of production, flavor and perfume materials (110 million pounds) increased 14.6 percent; organic
pigments (66 million pounds) rose 13.0 percent; rubber-processing chemicals (361 million pounds) was up 11.6 percent;
dyes (263 million pounds) increased 8.0 percent. Smaller increases were shown by medicinal chemicals (234 million
pounds), 5.0 percent and pesticides and related products (1,158 million pounds), 1.9 percent.
TABLE 1,
Synthetic organic chemicals and their raw materials;
U.S. production and sales, 1971 and 1972
Increase
or
decrease
(-), 1972
over
1971'
Increase
or
decrease
(-), 1972
over
1971'
Increase
or
decrease
(-), 1972
over
1971'
Grand total
Tar
Tar crudes
Crude products from petroleum
and natural gas
Synthetic organic chemicals,
total ^
Cyclic intermediates
Dyes
Organic pigments
Medicinal chemicals
Flavor and perfume materials-
Plastics and resin materials-
Rubber-processing chemicals--
Elastomers (synthetic
rubbers)
Plasticizers
Surface-active agents
Pesticides and related
products
Miscellaneous chemicals
Million
pounds
Percent
12.0
Million \Million\ \ Million
pounds \pounds \ Pereent dollars
133,666 I 150,8181
Million
dollars
6,794
7,621
142,503
7,472
7,937!
10.0
4.1
3,341
5,436
3,409|
5,304 i
2.0
-2.4
164,218| 15.2
45,752 1 47,900
79,157 : 94,205;
123
1,078
12,883
40
126
1,177
Percent
13.5
10.2
2.4
14,686 14.0
29
953
34
967
244
265
58
66
223
234
96
110
21
071
25
921
323
361
4
616
4
914
1
494
1
708
3
828
4
039
1
136
1
158
79
460
90
476
12,971
16,196
24.9
230
255
10.9
47
53
13.1
152
163
7.2
85
104
22.7
18,473
22,946
24.2
246
280
13.9
4,031
4,136
2.6
1,404
1,637
16.6
2,186
2,258
3.3
946
1,022
8.0
38,367
45.155
17.7
1,252
423
130
487
84
3,507
159
1,034
258
422
979
4,148
1,434
480
149
490
88
4,258
178
1,095
291
451
1,092
4,680
5.3
21.4
11.5
12.8
1 Percentages calculated from figures rounded to thousands.
2 Because of rounding, figures may not add to the totals shown.
SYNTHETIC ORGANIC CHEMICALS, 1972
GENERAL
In this report, synthetic organic chemicals are classified on the basis of their princip,al use as follows; cyclic
intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials,
rubber-processing materials, elastomers, plasticizers , surface-active agents, pesticides and related products and miscel-
laneous chemicals (acyclic intermediates and acyclic and cyclic finished products). Most of these groups are further
subdivided either by use or by chemical composition. As intermediate chemicals are used in the manufacture of finished
products, aggregate figures that cover both intermediates and finished products necessarily include considerable duplica-
tion.
Total production of synthetic organic chemicals (intermediates and finished products combined) in 1972 was 164,218
million pounds, or 15.2 percent more than the output of 142,503 million pounds reported for 1971 and 56.8 percent more
than the output of 104,711 million pounds reported for 1967 (see table 2). Sales of synthetic organic chemicals in 1972
amounted to 94,205 million pounds, valued at Sl4,686 million, compared with 97,137 million pounds, valued at $12,883
million in 1971 and 55,177 million pounds, valued at 510,438 million in 1967. Production of all cyclic products (inter-
mediates and finished products combined) in 1972 totaled 53,637 million pounds or 15.9 percent more than the 46,273 mil-
lion pounds reported for 1971 and 60.2 percent more than the 33,479 million pounds reported for 1967. Production of all
acyclic products in 1971 totaled 110,580 million pounds, or 14.9 percent more than the 96,230 million pounds reported
for 1971 and 55 . 2 percent more than the 71,232 nillion pounds reported for 1967.
TABLE 2. --Synthetic organic chemicals; Summary of U.S. production and sales
OF intermediates and finished products, 1967, 1971, and 1972
[Production and sales in tliousands of pounds; sales value in thousands of dollars]
Organic chemicals, cyclic and acyclic,
grand total :
Production
Sales
Sales value
Cyclic, total:
Production
Sales
Sales value
Acyclic, total :
Produc tion
Sales
Sales value
1. Cijolic Intermediates
Production
Sales
Sales value
2. Dyes
Production
Sales
Sales value
2. Organic Pigments
Production
Sales
Sales value
4. Medicinal Chemicals
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
,711,357
,176,823
,438,453
,479,469
,328,628
,610,29'
,2 31,888
,848,195
,828,160
,793,132
,461,180
,000,359
206,240
198,592
332,049
53,322
42,867
108,354
110,129
70,120
348,873
69,941
56,804
36,402
142,502,514
79,136,628
12,882,816
46,272,717
25,859,561
5,793,591
96,229,797
55,277,067
29,952,917
12,970,553
1,252,300
243,729
229,544
422,627
58,326
47,052
130,013
132,582
84,913
90,636
67,309
54.856
164,217,690
94,205,254
14,685,582
53,637,371
31,082,064
6,516,824
110,580,319
63,123,190
8,168,758
34,967,181
16,195,641
1,433,855
263,304
254,536
479,688
65,897
53,215
149,343
132
586
81
082
433
259
101
747
82
128
56
878
Increase, or decrease (-
1972 over
1967
1972 over
1971
Percent
Percent
56.8
70.7
40.7
15.2
19.0
14.0
60.2
60.8
41.4
15.9
20.2
12.5
55.2
76.1
40.2
14.9
18.5
15.2
68.2
71.2
43.3
16.7
24.9
14.5
27.7
28.2
44.5
8.0
10.9
13.5
23.6
24.1
37.8
13.0
13.1
14.9
20.4
15.6
24.2
(0
-4.5
.4
45.5
44.6
12.3
22.0
See footnotes at end of table.
GENERAL
TABLE 2. --Synthetic organic chemicals: Summary of U.S. production and sales
OF intermediates and finished products, 1967. 1971, AND 1972--C0NTINUED
[Production and sales in thousands of pounds; sales value in thousands of dollars]
5. Flavor and perfume Materials
Cyclic:
Product! on- -
Sales
Sales value-
Acyclic:
Production- -
Sales
Sales value-
Cyclic :
Production- -
Sales
Sales value-
Acyclic:
Product! on- -
Sales
Sales value-
Cyclic:
Product! on- -
Sales
Sales value-
Acyclic :
Production--
Sales
Sales value-
Cyclic:
Production-
Sale
Sales value-
Acyclic:
Production- -
Sales
Sales value-
9. Plastiai-zers
Cyclic:
Production--
Sales
Sales value-
Acyc lie:
Product ion- -
Sales
Sales value-
Plastics and Resin Materials
Rubber-Proaessing Cherriaal
8. Elastomers (Synthetic Rubbers)
57,978
47,285
52,866
5,033,497
4,224,121
1,036,940
8,759,452
7,753,242
1,635,690
220,139
169,970
116,318
43,994
30,878
15,477
2,297,637
1 ,940,099
439,580
1,524 ,908
1,321,945
434,657
929,871
865,084
167,827
332,908
296,767
93,142
49,682
42,180
52,884
46,744
42,585
31,084
7,266,038
6,262,651
1,400,553
13,804,685
12,210,359
2,105,989
276,146
211,065
142,541
2,614,054
2,239,804
484,130
2,002,046
1,790,837
550,315
1,130,440
1,074,541
157,925
363,598
329,555
99,840
51 ,868
48,212
54,168
58,605
55,780
8,946,997
7,807,933
1,715,579
16,973,665
15,138,142
2,542,861
309,930
240,044
157,944
51,091
40,199
2,705,599
2,177,303
470,549
2,208,360
1,958,960
624,257
1,301 ,955
1,273,191
180,051
406,358
364,306
110,513
Increase, or decrease (-)
1972 over
1967
2.0
2.5
77.8
84.8
65.5
93.8
95.3
55.5
16.1
30.2
27.3
17.8
12.2
7.1
44.8
48.2
43.6
40.0
47.2
See footnote at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Synthetic organic chemicals: Summary of U,S, production and sales
OF INTERMEDIATES AND FINISHED PRODUCTS, 1967, 197], AND 1972--CONTINUED
[Production and sales in thousands of pounds; sales value in thousands of dollars]
10. Surface-Aative Agents
Cyclic: '
Production
Sales
Sales value-'
Acyclic:
Production
Sales
Sales value
II. Pesticides and Related Products
Cyclic:
Production
Sales
Sales value
Acyclic:
Production
Sales
Sales value
12. Miscellaneous Chemicals
Cyclic:
Production--
Sales
Sales value-
Acyclic:
Production--
Sales
Sales value-
1,418
444
852
238
95
810
2,060
851
897
78h
220
877
823,158
681,532
627,742
226,505
215,831
159,301
1,535,922
775,540
283,575
58,159,771
25,225,631
3,192,119
1,542,881
995,580
120,795
1,190,110
301,685
827
590
669
143
819
028
308
127
277
194
160
055
1,032,535
379,093
77,281,270
37,334,192
3,768,587
1,641,552
1,053,240
129,792
2,397,235
1,204,306
320,976
839,360
719,707
889,613
318,338
301,858
202,095
2,411,142
1,177,960
422,983
88,064,920
43,977,511
4,257,239
Increase, or decrease (- }
33.4
6.4
5.8
7.5
1.4
7.6
8.6
3.3
8.9
26.3
14.1
11.6
Standard reference base period for Federal Government general-purpose inde.x numbers.
Less than 0.05 percent.
Includes Ligninsulfonates
The following tabulation shows, by chemical groups, the number of companies that reported production in 1971 of
one or more of the chemical included in the groups listed in table 2;
Chemical
Cyclic intermediates
Dyes
Organic pigments
Medicinal chemicals
Flavor and perfume materials-
Plastics and resin materials-
Ntmber
of _
compcDiiee
Chem-oal group
Rubber-processing chemicals
Elastomers (synthetic rubbers)-
Plasticizers
Surface- active agents
Pesticides and related products-
Miscellaneous chemicals
of _
ciompani.es
TAR AND TAR CRUDES
Tar
Coal tar is produced chiefly by the steel industry as a byproduct
of the manufacture of coke; water-gas tar and oil-gas tar are produced
by the fuel-gas industry. Production of coal tar, therefore, depends
on the demand for steel; production of water-gas tar and oil-gas tar
reflects the consumption of manufactured gas for industrial and house-
hold use. Water-gas and oil -gas tars have properties intermediate be-
tween those of petroleum asphalts and coal tars. Petroleum asphalts
are not usually considered to be raw materials for chemicals.
The quantity of tar produced in the United States in 1972 was al-
most entirely coal tar which amounted to 747 million gallons (see table 1^).
Production in 1972 was 10 percent more than the 679 million gallons of
coal tar produced in 1971. Sales of coal tar in 1972 amounted to 341
million gallons, valued at $40 million, compared with 334 million gallons,
valued at $36 million, in 1971. U.S. production of water-gas and oil-gas
tars was not reported to the Commission for 1971 or 1972; production of
these tars in 1968 amounted to 21 million gallons, according to trade
publications .
Consumption of tar in 1972 amounted to 716 million gallons, of which
82.8 percent was consumed in distillation. Tar used by the producers as
fuel amounted to 119 million gallons. A lesser amount, 4.3 million gallons,
was consumed by coke-oven operators in miscellaneous uses fsee table lA) .
Tar Crudes
Tar crudes are obtained from coke-oven gas and by distilling coal
tar, water-gas tar, and oil-gas tar. The most important tar crudes are
benzene, toluene, xylene, naphthalene, creosote oil, and pitch of tar.
Some of these products are identical with those obtained from petroleum.
Data for materials obtained from petroleum are included, for the most
part, with the statistics for like materials obtained from coke-oven
gas and tars, and are shown in tables 1 and IB.
Domestic production of industrial and specification grades of
benzene reported by coke-oven operators and petroleum refinery operators^
in 1972 amounted to 1,252 million gallons--16.4 percent more than the
^ See also table 2 of this section which lists the products in table 1
and identifies the manufacturers by code. These codes are given in table
^ Statistics on production and sales of benzene, toluene, and xylene by
tar distillers cannot be shown because publication would reveal the oper-
ations of individual companies.
SYNTHETIC ORGANIC CHEMICALS, 1972
1,076 million gallons reported for 1971. These statistics include data
for benzene produced from light oil and petroleum. Sales of benzene by-
coke-oven operators and petroleum refiners in 1972 amounted to 679 mil-
lion gallons, valued at $138 million, compared with 593 million gallons,
valued at $119 million, in 1971. In 1972 the output of toluene^ (in-
cluding material produced for use in blending in aviation fuel) amounted
to 916 million gallons--4.5 percent more than the 876 million gallons
reported for 1971. Sales of toluene in 1972 were 546 million gallons,
valued at $92 million, compared with 484 million gallons, valued at
$80 million, in 1971. The output of xylene^ in 1972 (including that
produced for blending in motor fuels) was 739 million gallons, com-
pared with 612 million gallons in 1971. Over 99 percent of the 739
million gallons of xylene produced in 1972 was obtained from petroleum
sources .
Production of crude naphthalene in 1972 (including 231 million
pounds of petroleum-derived naphthalene) amounted to 641 million pounds,
compared with 619 million pounds in 1971. In 1972 the output of creosote
oil for wood preservation was 139 million gallons (100 percent creosote
basis), compared with 142 million gallons in 1971. Production of road
tar in 1972 was 30 million gallons, compared with 40 million gallons in
1971.
Some of the products obtained from tars and included in the
statistics in table 1 are obtained from other products for which data
are also included in the table. The statistics, therefore, involve
considerable duplication, and for this reason no group totals or grand
totals are given. After duplication has been eliminated insofar as
possible, the estimated net value of the output (from all sources) of
these products and of tar burned as fuel was $698 million in 1972,
compared with $617 million in 1971. The total value of sales of those
products obtained from coke-oven gas and tars shown in table 1 (ex-
clusive of coal tar itself), amounted to $126 million in 197.2, compared
with $123 million in 1971.
Data for 1972 tar crudes was supplied by 12 companies and company
divisions.
See footnote 2 on page 7,
TAR
TAR CRUDES
TABLE 1,--Tar and tar crudes: U,S, production and sales> 1972
[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders (...)
are used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists separately all products for which data on production or sales were reported and identifies the manu-
facturers reporting to the U.S. Tariff Commission]
Production
Quantity
Tar: Coke-oven operators
Crude light oil:^ Coke-oven operators
Intermediate light oil: Coke-oven operators
Light-oil distillates:
Benzene, specification and industrial
grades, total^ '*
Coke-oven operators
Petroleum refiners
Toluene, all grades, total ^ **
Coke-oven operators
Petroleum refiners
Xylene, all grades' '*
Coke-oven ope ra tors
Petroleum refiners
Solvent naphtha: Coke-oven operators'
Naphthalene, crude (tar distillers and coke-
oven operators), total^
Solidifying at--
Less than 74° C
74° C. to less than 79° C
Crude tar-acid oils:' Coke-oven operators--
Creosote oil (Dead Oil) (tar distillers and
coke-oven operators) (100% creosote
basis J , total ^ —
Distillate as such (100° creosote basis)--
Creosote content of coal tar solution
(100% creosote basis)'
All other distillates, total
Coke-oven operators, total
From light oil
Other"
Tar distillers^
Tar, road
Tar, refined, for other uses
Pitch of tar (tar distillers and coke-oven
operators) , total
Soft (water softening point less than
110° F.)
Medium (water softening point 110° F. to
160° F.)
Hard (water softening point over 160° F.)^
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 gal-
1,000 Ib-
1,000 Ib-
1,000 gal--
1,000 gal--
1,000 gal--
1,000 gal--
1,000 gal--
1,000 gal--
1 ,000 gal--
1 ,000 gal--
1,000 gal--
1,000 gal--
1,000 gal--
1 ,000 tons
1,000 tons
1 ,000 tons
1 ,000 tons
747,186
214,201
3,704
1,252,442
79,849
1,172,593
915,872
14,571
901,301
739,332
3,351
735,981
2,815
17,374
392,701
9,731
25,213
6,905
3,898
3,007
29,807
14,395
1,568
340,875
86,915
754
679,235
80,225
599,010
545,880
13,954
531,926
560,432
3,208
557,224
2,596
1,000
dollars
39,634
9,584
138,478
16,338
122,140
91,529
2,501
89,028
94,128
578
93,550
462
9,627
215,364
144
10,281
22,956
16,187
' 6,769
3,675
2,520
2,837
14,507
29,873
13,082
1,009
1,060
849
211
2,615
5,493
3,516
(')
.20
.34
.07
177
633
10,035
30,783
56.69
48.63
Unit value per gallon, pound, or ton, as specified.
^ Includes only data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines. Data on U.S. pro-
duction of water-gas tar and oil-gas tar are not collected by the Tariff Commission, but according to trade publica-
tions, production of these tars amounted to 21 million gallons in 1968.
' Data reported by tar distillers are not included because publication would disclose the operations of individual
companies. Production of benzene, toluene, and xylene by tar distillers decreased in 1972, compared with 1971. The
annual production statistics for petroleum refiners on benzene, toluene, and xylene are not comparable with the com-
bined monthly production figures, because of fiscal year revisions.
Note. --Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Fossil Fuels,
U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum refineries
are compiled by the U.S. Tariff Commission.
SYNTHETIC ORGANIC CHEMICALS, 1972
Footnotes for table 1 — Continued
'* Includes data for material produced for use in blending motor fuels.
^ Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphthalene
from one grade to another, the figures may include some duplication.
' Statistics include data only for creosote oil sold for, or used in, wood preserving.
' In 1972, production of coal-tar solution containing creosote (100% solution basis) amounted to 38,144 thousand gal-
ons ; sales were 36,232 thousand gallons, valued at 6,769 thousand dollars, with a unit value of $0.19 per gallon.
° Includes data for crude sodium phenolate.
^ Includes data for crude light oil, benzene, toluene, xylene, solvent naphtha, ethylbenzene , rubber-reclaiming oils,
pyridine crude bases, crude tar-acid oils, crude cresylic acid, neutral oils, methylnaphthalene , crude tar for other
uses, and unspecified tar distillates.
'° Includes hard pitch and pitch emulsion, along with a small amount of medium pitch produced by coke-oven operators.
TABLE 1A.--TAR; U.S. production and consumption^ 1971 and 1972
(In thousands of gallons)
Product
1971
19 72
PRODUCTION
679,377
747,186
CONSUMPTION
685,684
715,823
572,160
592,507
230,959
341,201
111,877
1,647
273,388
319,119
4,286
Reported to the Division of Fossil Fuels, U.S. Bureau of Mine^.
Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort
plants and distilled by companies operating tar-distillation plants. Statistics also include tar consumed other than
by distillation by tar distillers.
TAR AND TAR CRUDES
TABLE IB. --Tar and tar crudes; Summary of U.S. production of specified products,
1967, 1971, and 1972
Unit
of
quantit
Increase, or
decrease (-)
1972 over
1967
1972 over
1971
Tar'
Benzene : '
Coke-oven operators -
Petroleum refiners--
Total
1,000 gal-
1,000 gal-
1,000 gal-
90,642
878,704
679,377
72,147
1,003,760
Toluene : ^
Coke-oven operators-
Petroleum refiners--
Total
1,000 eal--
1,000
1,000 gal-
969,346
19,357
624,454
79,849
1,172,592
Percent
-4.2
-11.9
33.4
Xylene:'
Coke-oven operators-
Petroleum refiners--
Total
1,000 gal-
1,000 gal-
1,000 gal-
643,811
5,488
449,349
862,921
1,252,442
14,571
901,301
2,906
609,419
3,351
735,981
-38.9
63.8
Naphthalene :
Crude ^
Petroleum naphthalene.
Total
ill grades-
1,000 gal--
1,000 Ib-
1,000 Ib-
454,837
520,991
376,679
612,325
360,607
258,312
410,075
230,643
-21.3
-38.8
Creosote oil (Dead oil):
Distillate as such (100% creosote
basis)
Creosote content of coal tar solution
(100% creosote basis)
Total
1,000 gal-
1,000 gal-
108,832
17,402
115,669
26,208
114,095
25,213
1,000 gal--
126,234
141,877
139,308
10.4
Peyaent
10.0
15.3
20.8
-1.8
Standard reference base period for Federal Government general -purpose index numbers.
^ Includes only data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines.
Data reported by tar distillers are not included because publication would disclose the operations of individual
companies.
* Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly
figures which included some o-xylene.
5 Naphthalene solidifying at less than 79° C. Figures include production by tar distillers and coke-oven operators
and represent combined data for the commercial grades of naphthalene. Because of conversion between grades, the figures
may include some duplication. Statistics on naphthalene refined from domestic crudes are reported in the section on
cyclic intermediates.
Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserving.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Tar crudes for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Tar crudes for which separate statistics are given in table 1 are marked with an asterisk (*) ; products not so
marked do not appear in table 1 because the reported data are accepted in confidence and may not be published.
Manufacturers' identification codes shown below are taken from table 3. Table 3 identifies all U.S. producers of
tar crudes (except producers that report to the Division of Fossil Fuels, U.S. Bureau of Mines)]
Manufacturers' identification codes
(according to list in table 3)
•Crude light oil
Light-oil distillates;
Benzene, specification grades'
Toluene, specification grades'
Xylene, all grades
Solvent naphtha
All other light-oil distillates'
Pyridine crude bases
'Naphthalene, crude, solidifying at--
*Less than 74° C'
*74° C. to less than 79° C:'
74° C. to less than 76° C
76° C. to less than 79° C
Methylnaphthalene
Crude tar-acid oils:'
Tar-acid content S% to less than 24"^
Tar-acid content 24*o to 50-6
Cres\'lic acid, crude
•Creosote oil (Dead oil);
'Distillate as such'
•Creosote in coal tar solution'
•All other distillate products'
•Tar, road
Tar for other uses:
Crude
•Refined'
•Pitch of tar:
•Soft (water softening point less than 110° F.)'--
•Medium (water softening point 110° F. to 160° F.)
•Hard (water softening point above 160° F.)'
Pitch emulsion
CBT.
ACY, KPP.
ACY, KPP.
ACY.
ACY, NEV, PAI.
KPT, PAI.
KPT.
COP.
KPT.
ASC,
KPT.
KPT.
KPT.
ASC,
WTC.
KPT.
ASC, CBT, COP, HUS, KPT, RIL, WTC.
ASC, KPT, RIL, WTC.
ASC, KPT, PAI.
ASC, KPT, RIL.
KPT, RIL.
ASC, KPT, RIL.
ASC, KPT, WTC.
ASC, CBT, COP, KPT, RIL, WTC.
ASC, HUS, KPT, RIL.
JEN.
Does not include manufacturers' identification codes for producers who report to the Division of Fossil Fuels,
U.S. Bureau of Mines. Those producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, November 27,
1973, entitled "Coke Producers in the U.S. in 1972".
TABLE 3. --Tar and tar crudes: Directory of manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of tar and tar crudes to the U.S. Tariff Commission for
1972 are listed below in the order of their identification codes as used in table 21
Code
Name of
company
Code
Name of company
ACY
American Cyan amid Co.
KPT
Koppers Co., Inc., Organic Materials Div.
ASC
Allied Chemical Corp. ,
Semet-Solvay Div.
CBT
Samuel Cabot, Inc.
NEV
Neville Diemical Co.
COP
Coopers Creek Chemical
Corp.
HUS
Husky Industries, Inc.
PAI
Pennsylvania Industrial Chemical Corp.
JEN
Jennison-Wright Corp.
RIL
WTC
Reilly Tar 5 Chemical Corp.
Witco Cnemical Co., Inc.
KPP
Sinclair-Koppers Co.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1, o*^ the Appendix.
13
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR
CHEMICAL CONVERSION
Crude products that are derived from petroleum and natural gas ^
are related to the intermediates and finished products made from such
crudes in much the same way that crude products derived from the dis-
tillation of coal tar are related to their intermediates and finished
products. Many of the crude products derived from petroleum are
identical with those derived from coal tar (e.g., benzene, toluene,
and xylene). Considerable duplication exists in the statistics on the
production and sales of petroleum crudes because some of these crude
chemicals are converted to other crude products derived from petroleum
and because data on some production and sales are reported at succes-
sive stages in the conversion process. The statistics are sufficiently
accurate^ however, to indicate trends in the industry. Many of the
crude products for which data are included in the statistics may be
used either as fuel or as basic materials from which to derive other
chemicals. In this report every effort has been made to exclude data on
materials that are used as fuel; however, data are included on toluene
and xylene which are used in blending aviation and motor fuel.
The output of crude products derived from petroleum and natural gas
as a group amounted to 86,792 million pounds in 1972, or 7.0 percent
more than the 81,043 million pounds reported for 1971 (table 1).^ The
larger output in 1972 is accounted for chiefly by increased production of
ethylene, propylene and benzene. Sales of crude chemicals from
petroleum in 1972 amounted to 47,900 million pounds, valued at $1,177
million, compared with 45,752 million pounds, valued at $1,078 million,
in 1971.
The output of aromatic and naphthenic products from petroleum
amounted to 23,753 million pounds in 1972, compared with 21,449 million
pounds in 1971. Sales amounted to $351 million in 1972, and ^308
million in 1971. The output of 1° and 2° benzene from petroleum in 1972
(8,654 million pounds) was 17,1 percent more than the 7,388 million
pounds produced in 1971.
Production of all aliphatic hydrocarbons and derivatives from
petroleum and natural gas was 63,039 million pounds in 1972, compared
with 59,594 million pounds in 1971. Sales Of these products were
valued at $825 million in 1972 compared with $769 million in 1971.
Production of ethylene was 20,852 million pounds in 1972--13.0 percent
more than the 18,450 million pounds produced in 1971. The output of
1,3-butadiene in 1972 (3,527 million pounds) was the largest on record.
Data for 19 72 crude products from petroleum and natural gas for
chemical conversion was supplied by 73 companies and company divisions.
^ Statistics on aromatic chemicals from coal tar are given in the re-
port on "Tar and Tar Crudes".
^ See also table 2 which lists these products and identifies the manu-
facturers by codes. These codes are given in table 3.
SYNTHETIC ORGANIC CHEMICALS, 1972 '
TABLE 1. --Crude products from petroleum and natural gas for chemical conversion:
U.S. production and SALESy 1972
[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported
data on production or sales may be published. {Leaders (...) are used where the reported data are accepted in confidence
and may not be published or where no data were reported.) Table 2 lists separately all products from petroleum and
natural gas for chemical conversion for which data on production or sales were reported and identifies the
manufacturers of each]
Quantity
Grand total
2
aromatics and napiithenes
Total
Benzene (1° and 2°)
Naphthalene, all grades
Naplithenic acid
Toluene, all grades, total
Nitration grade, 1°
Pure commercial grade, 2-
Solvent grade, 90%
All other
Xylenes, mixed, total
3° grade
5'^ grade
All other'
All other aromatics and naphthenes"*
ALIPHATIC HYDROCARBONS
Total
C hydrocarbons, total
Acetylene
Ethane
Ethylene
Cj and Cg hydrocarbons, mixed
C3 hydrocarbons, total
Propane
Propylene'
Cit hydrocarbons, total
1 , 5- Butadiene, grade for rubbers (elastomers)-
Butadiene and butylene fractions
n- Butane
1-Butene
1-Butene and 2-butene mixtures'
Isobutane
Isobutylene
All other*
C5 hydrocarbons, total
Isopentane (2-Methylbutane)
Isoprene (2-Methyl-l ,3-butadiene)
Pentenes, mixed
All other'
1,000
pounds
3,792,187
,752,898
8,653,736
230,643
33,190
6,552,591
4,877,029
429,868
152,401
1,093,293
5,306,422
1,184,423
383,384
3,758,615
2,976,316
26,297,040
5,136,540
20,852,144
133,062
18,079,972
9,608,315
8,471,657
10,610,
3,527,422
567,998
2,331,119
61,597
752,791
942,082
600,184
1,827,734
962,223
7,967
372,663
318,978
262,615
1,000
47,899,859
1,000
do t tars
1,176,609
15,402,465
4,420,693
164,314
3.867,231
,828,364
255,584
783,283
4,017,5.J5
744,195
401,381
2,872,009
3,995,766
5,649,443
8,620,910
3,918,302
2,230,009
436,231
443,707
46.617
782,157
315,564
1,397,859
351,401
122,140
7,753
66,662
5,738
16,628
93,550
16,539
9,995
67,016
36,729
168,252
107,445
111,765
251,300
173,844
11,817
4,367
2,386
21,681
11,808
25.397
CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSIC:!
TABLE 1,— Crude products from petroleum and natural gas for chemical conversion;
U.S. production and sales, 1972
Quantity
Unit
value'
1,000
1,000
aliphatic HYDROCARBONS--Continued
All other aliphatic hydrocarbons, derivatives, and
mixtures, total
Alpha olefins
Heptenes, mixed
Hexanes and other Cj. hydrocarbons
Nonene (Tr ipropy lene)
n-Paraffins, total
Carbon chain length, C^-Cj^
Other
Polybutene
Tetrapropylene
Hydrocarbon derivatives
All other"
956
265
517
434
83
838
339
668
341
590
063
653
279
199
784
454
198
080
210
173
114
246
087
583
4,134,378
iini,084
26,713
299,807
247,040
747,744
276,351
471,393
139,356
57,322
82,760
2,132,552
1,000
dollars
133.389
Per
pound
21,946
847
8,621
8,446
23,151
5.170
17,981
10,217
2,034
10,008
48,119
.055
.032
.029
.034
.031
.019
.038
.073
.035
.121
.023
' Calculated from rounded figures.
2 The chemical raw materials designated as aromatics are in some cases identical with those obtained from the
distillation of coal tar; however, the statistics given in the table above related only to such materials as are de-
rived from petroleum and natural gas. Statistics on production or sales of benzene, toluene, xylene, and naphthalene
from all sources are given in tables 1 and IB of the report "Tar and Tar Crudes, 1972."
5 Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines.
" Includes data for crude cresylic acid, alkyl aromatics, distillates, solvents , miscellaneous cyclic hydrocarbons
and sales of naphthenic acid.
5 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of
the Census.
' Includes data for propane-propylene mixture.
' The statistics represent principally the butene content of crude refinery gases from which butadiene is manu-
factured.
8 Includes data for mixed butanes, 2-butene, mixed butylene, and mixed olefins.
' Includes data for isopentane, pentenes, and C5 hydrocar^joi mixtures.
'" Includes data for the following molecular weight ranfer.: Ce-C?; Ca-Cio; C,i-C,5; Cjj-Cn; C15-C20; and
" Includes compounds having a molecular weight of 3,000 or less.
'2 Includes data for butyl, ethyl, methyl, and miscellaneous mercaptans .
" Includes data for di-isobutylene, methane-ethane-ethylene mixture, heptane, methane, octanes, hydrocarbon mixtures,
sales of acetvlene and of mixed C- and C, hydrocarbons.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2, --Crude products from petroleum and natural gas for chemical conversion for which
U.S, production or sales were reported, identified by manufacturer, 1972
[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in
table 1 are marked below with an asterisk (*) ; products not so marked do not appear in table 1 because the reported
data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken
from table 3. An x signifies that the manufacturer did not consent to his identification with the designated product
Manufacturers' identification codes
(according to list in table 3)
AROMATICS AND NAPHTHENES
*Benzene (except motor grade) :
'Benzene, 1°
*Benzene, 2°
Cresylic acid, crude
♦Naphthalene, all grades-
*Naphthenic acids:
Acid number lower than 150
Acid number 150-199
Acid number 200-224
Sodium carbolate and phenate, crude
*Toluene:
*Nitration grade, 1°
*Pure commercial grade, 2°
'Solvent grade, 90°i.
All other
'Xylenes, mixed:
Aviation grade
*3° grade
*5° grade
All other
All other aromatics, naphthenes, distillates and solvents
ALIPHATIC m'DROCARBGNS
Ci hydrocarbon: Methane
*C 2 hydrpcarbons:
'Acetylene
'Ethane
'Ethylene
*C 2 and C 3 hydrocarbons, mixed
*C 3 hydrocarbons:
'Propane
'Propane-propylene mixture
'Propylene
*C 1, hydrocarbons :
♦1,3-Butadiene, grade for rubbers (elastomers)
'Butadiene and butylene fractions
*n- Butane
'1-Butene
2-Butene
ACU, AMO, APR, ASH, ATR, CCP, CSP, CSD, CSO, CSP, DLH,
ENJ, GDC, GRS, MOC, MON, PLC, PPR, SHC, SHO, SKO, SM,
SNT, SOG, SUN, TOG, TX, UCC, UOC.
CPI, DOW, SHO, SOG.
PRO.
ASH. GOL, MON. SUN, TID.
SOG, SUN, TX.
ATR, PRO, SOG, SUN.
ATR, PRD, see.
ATR.
ASH, ATR, CCP, CSD, CSP, DLH, ENJ, GOG, MOG, MON, PLC,
PPR, SHC, SHO, SNT, SOG, SUN, TOG, TX, UCC, UOG.
ATR, CPI, DOW, ENJ, MON, UCC.
AGG, FG, SKO.
ATR, CPI, CSD, ELP, GRS, GYR, PLC, PPR, SHO, SM, SOG.
CSO.
CSD, DLH, GOC, MOG, PPR, SHO, SUN, UOG.
ASH, ATR, SOG.
AMO, CCP, CPI, CSD, CSP, ENJ, HGR, MON, PPR, SHC, SNT,
SOG, STY, SUN, TOG, UCC.
AGG, ACU, ATR, CBN, CPX, DUP, ELP, ENJ, FG, GOG, JCG,
MOC, MON, OMG, PLC, SHC, SOG, SOG, TX, UCC.
DOW, DUP, MNO, RH, UCC.
ACU, ATR, DOW, ENJ, MON, OMG, PAN, PLC, PUE, SHO, SM,
TX, USI.
ACU, ATR, BFG, CBN, GO, CPX, DOW, DUP, EKX, ELP, ENJ,
FRO, GOC, JCG, KPP, MON, NWP, OMG, PLC, PUE, SHC, SM,
SNO, UCC, USI.
CCP, GO, CSO, PLC.
AMO, ASH, ATR, COR, CPI, CSD, CSO, CSP, ENJ, GOG,
GRS, MOG, OMG, PAN, PLC, PUE, SHO, SM, SNT, SOG, SUN,
TX, UOC, USI.
GOG.
ACU, AMO, ASH, ATR, BFG, CBN, CCP, COR, CPX, CSO, DOW,
DUP, EKX, KLP, ENJ, GOG, JCC, KPP, MOC, MON, NWP,
PLC, PUE, SHC, SHO, SIO, SM, SNT, SOG, SUN, TX, UCC.
ATR, BFG, GPY, DOW, ELP, ENJ, FRS, MON, PLC, PTT, PUE,
SBI, SHC, SM, TID, TUS, UCC.
ACU, ATR, CO, CPX, DOW, EKX, GOC, GYR, KPP, PLC, SHO,
UCC.
ATR, BFG, COR, CPI, CSD, CSP, GRS, OMC, PAN, PLC, SHO,
SM, SNT, SUN, USI.
GOC, PLC, PTT.
MON, PLC.
CRUDE PRODUCTS FRO^l PETROLEUM
NATURAL GAS FOR CHEMICAL CONVERSION
TABLE 2, --Crude products from petroleum and natural gas for chemical conversion for which
U,S, production or sales were reported, identified by manufacturer, 1972--Continued
Manufacturers' identification codes
(according to list in table 3}
ALIPHATIC HYDROCARBONS- -Continued
*C^ hydrocarbons--Continued
*1-Butene and 2-butene mixture
*Isobutane
*Isobutylene
All other
*C^ hydrocarbons:
*lsopentane (2- Methyl butane)
*lsoprene (2-Methyl-l , 3-butadiene)
n-Pentane
*Pentenes, mixed
All other
'Cf hydrocarbons:
*Hexane
Neohexane (2, 2-Dimethylbutane)
All other
Cj hydrocarbons:
n-Heptane
*Heptenes, mixed
All other
Cg hydrocarbons:
Diisobutylene (Diisobutene)
n-Octane
All other
Hydrocarbons, Cg and above:
*Nonene CTripropylene)
*Polybutene
*Tetrapropylene
Triisobutylene
All other
*A11 other aliphatic hydrocarbons, derivatives and
mixtures;
Hydrocarbons :
*Alpha olefins--Molecular weight ranges:
Cj.-C,
Cj-'^io
Ci,-Cl5
All otner
*n-Paraf fins--Carbon chain length:
C^.C,
♦C-c,,
C,o-Ci6
All other
*Hydrocarbon derivatives:
n- Amyl mercap tan
tert-Amyl mercaptan (2-Methyl-2-butanethiol) —
1- Butane thiol
tcrt- Butyl -mercaptan (2-Methyl-2-propanethiol)-
Cyclohexyl mercaptan
Di-tert- butyl disulfide
Di-tert-nonylpoly sulfide
Ethyl mercaptan (Ethanethiol)
n-Hexadecyl mercaptan
I s opropy 1 mercaptan
Methyl mercaptan (Methanethiol)
tert-Nonyl mercaptan
n-Propyl mercaptan (1-Propanethiol)
All other
Mixtures, not elsewhere classified
AMD, ATR, CSO, ENJ, GDC, PLC, PIT, SHO, TX .
AIR, CSP, ELP, GRS, CMC, PAN, PLC, SHO, USI.
ENJ, PLC, SHC, SHO, x.
APR, ATR, BFG, CBN," ENJ, GRS, JCC, MON, PLC, PUE, SM,
USI.
APR, PAN, PLC, SHO, SM.
BFG, ENJ, GYR, MON, SHC.
APR, PLC.
GYR, MON, TX.
CBN, ELP, MON, PLC, SHC, UCC.
APR, ENJ, PLC, SOG, UOC.
PLC.
APR, BFG, PLC, SWC.
EKX, PLC, SOG.
AIP, ENJ, GOC, SOI, TID.
ENJ, HCR, PLC, UOC.
BFG, PTT, TX.
SOG.
ENJ, PLC.
AIP, ATR, CSD, ENJ, SUN, UOC.
ACC, CSD, SOC.
ATR, CO, ENJ, SOC, SUN, TX, UOC.
X.
ACC, ATR. CO, CPI, ENJ, KPP, PLC, PUE, SOC, TID, TNA,
UCC.
GOC, GYR, SOC.
GOC, SOC.
GOC, SOC.
EKX, GOC, SOC, TID, TNA.
SOG.
BFG, HCR, SOG.
ENJ, SOG, UCC.
CO.
ATR, PUE, UCC.
PAS.
PLC.
PAS, PLC.
PAS.
PAS.
PLC.
PAS.
PAS, PLC.
PAS.
PAS.
ACC, PAS.
PAS.
PAS, PLC.
EKX, PAS, PLC, UCC.
ATR, GYR, MON.
SWHETIC ORG,AfHC CHB1ICALS. 1^72
TABLE 3,— Crude products from petroleum and natural gas for chemical conversion:
Directory of manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of crude products from petroleum and natural gas for
chemical conversion to the U.S. Tariff Commission for 1972 are listed below in the order of their identification
codes as used in table 2]
Code
Name of company
Code
Name of company
ACC
Amoco Chemicals Corp.
MNO
Monochem, Inc.
ACU
Allied Chemical Corp. , Union Texas
MOC
Marathon Oil Co., Texas Refining Div.
Petroleum Div.
MON
Monsanto Co.
AIP
Air Products 6 Chemicals, Inc.
AMO
American Oil Co. (Texas)
NWP
Northern Petrochemical Co.
APR
Atlas Processing Co.
ASH
Ashland Oil, Inc.
OCC
Oxirane Chemical Co.
ATR
Atlantic Richfield Co., ARCO Chemical Co.
Div.
OMC
Olin Corp.
PAN
Amoco Production Co.
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
PAS
Pennwalt Corp.
Co. Div.
PLC
PPR
Phillips Petroleum Co.
Phillips Puerto Rico Core, Inc.
CBN
Cities Service Co., Petrochemical Div.
PRO
Productol Chemical Co., Inc.
CCP
Crown Central Petroleum Corp.
PTT
Petro-Tex Chemical Corp.
CO
Continental Oil Co.
PUE
Puerto Rico Olefins
COL
Collier Carbon 6 Chemical Corp.
COR
Commonwealth Oil 5 Refining Co., Inc.
RH
Rohm S Haas Co.
CPI
Commonwealth Petrochemicals, Inc.
CPX
Chemplex Co.
SBI
Standard Brands Chemical Inudstries,
nc.
CPY
Copolymer Rubber 6 Chemical Corp.
SHC
Shell Oil Co., Shell Qiemical Co. Div
CSD
Cosden Oil 5 Chemical Corp.
SHO
Shell Oil Co.
CSO
Cities Service Oil Co.
SIO
Standard Oil Co. of Ohio
CSP
Coastal States Petrochemical Co.
SKO
SM
Skelly Oil Co.
Mobil Chemical Co.
DLH
Amerada Hess Corp.
SM
Mobil Oil Corp.
DOW
Dow Chemical Co.
SNO
SunOlin Chemical Co.
DUP
E. I. duPont de Nemours § Co., Inc.
SNT
Suntide Refining Co.
SOC
Standard Oil Co. of California, Chevron
EKX
Eastman Kodak Co. , Texas Eastman Co. Div.
Chemical Co.
ELP
El Paso Products Co.
SOG
Charter International Oil Co.
ENJ
Exxon Chemical Co. U.S.A.
SOI
STY
American Oil Co. (Maryland)
Styrochera Corp.
FG
Foster Grant Co. , Inc.
SUN
Sun Oil Co.
FRO
Vulcan Materials Co., Chemicals Div.
SWC
Shell 6 Commonwealth Chemicals, Inc.
FRS
Firestone Tire 5 Rubber Co., Firestone
Synthetic Rubber § Latex Co. Div.
TID
TNA
Getty Oil Co.
Ethyl Corp.
GOC
Gulf Oil Corp. , Gulf Oil Chemicals
TOG
Tenneco Oil Co.
Co. - United States
TUS
Texas-U.S. Chemical Co.
GRS
Champlin Petroleum Co.
TX
Texaco, Inc.
GYR
Goodyear Tire ii Rubber Co.
UCC
Union Carbide Corp.
HCR
Hercor Chemical Corp.
UOC
US I
Union Oil Co. of California
National Distillers f, Qiemical Corp.,
JCC
Jefferson Chemical Co. , Inc.
U.S. Industrial Chemicals Co. Div.
KPP
Sinclair-Koppers Co.
Note.-
-Complete names and addresses of the above reporti
ng compc
inies are listed in Table 1, of the Anpe
ndix.
19
CYCLIC INTERMEDIATES
Cyclic intermediates are synthetic organic chemicals derived princi-
pally from petroleum and natural gas and from coal-tar crudes produced by
destructive distillation (pyrolysis) of coal. Most cyclic intermediates are
used in the manufacture of more advanced synthetic organic chemicals and
finished products, such as dyes, medicinal chemicals, elastomers (synthetic
rubbers), pesticides, and plastics and resin materials. Some intermediates,
however, are sold as end products without further processing. For example,
refined naphthalene may be used as a raw material in the manufacture of 2-
naphthol or of other more advanced intermediates, or it may be packaged and
sold as a moth repellent or as a deodorant. In 1972 about 46 percent of
the total output of cyclic intermediates was sold; the rest was consumed
chiefly by the producing plants in the manufacture of more advanced interi-
mediates and finished products.
Total production of cyclic intermediates in 1972--34,967 million
pounds--was the largest on record, and was 16.7 percent larger than the out-
put of 29,953 million pounds reported for 1971. The larger output of cyclic
intermediates in 1972 reflects the increased demand by the chemical products
industries, particularly those industries that produce plastics materials,
dyes, pigments, and plasticizers. Sales of cyclic intermediates in 1972
were 16,196 million pounds, valued at $1,434 million, compared with 12,971
million pounds, valued at $1,252 million, in 1971.
Production of styrene in 1972 was 5,941 million pounds, or 26.9 percent
more than the 4,682 million pounds produced in 1971. Output of ethylbenzene
was 5,676 million pounds, an increase of 13.9 percent from the 4,984 million
pounds produced in 1971. Other intermediates whose production exceeded 1
billion pounds in 1972 were cyclohexane (2,298 million pounds), cumene
(2,293 million pounds), p-xylene (2,208 million pounds), dimethyl tere-
phthalate (2,167 million pounds), phenol (2,096 million pounds), and tere-
phthalic acid (1,929 million pounds). Other large-volume intermediates
produced in 1972 were phthalic anhydride (933 million pounds), o-xylene
(832 million pounds), cyclohexanone (783 million pounds), isocyanates
(702 million pounds), nitrobenzene (551 million pounds), straight chain
alkylbenzenes (524 million pounds), 2,4 and 2,6-dinitrotoluenes (434 mil-
lion pounds), aniline (410 million pounds), and monochlorobenzene (404
million pounds). The above 17 chemicals accounted for 86 percent of the
total output of cyclic intermediates in 1972. Production of 15 of the
above chemicals increased in 1972 compared to 1971; the output of alkyl
benzenes decreased by 4.7 percent and of monochlorobenzene by 1.3 percent.
SYNTHETIC ORGANIC CHEHICALS. 1972
TABLE 1.— Cyclic intermediates; U.S, production and sales, 1972
[Listed below are all cyclic intermediates for which any reported data on production or sales may be published.
(Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no date
were reported.) Table 2 lists alphabetically all cyclic intermediates for which data on production or sales were
reported and identifies the manufacturers of each]
Production
Quantity
Total
Acetanilide, tech
Acetophenone, tech
A Ikyl benzenes^
1-Aminoanthraquinone and salt
7- (p-Aminobenzamido) -4 -hydroxy- 2-napht ha lenesulfonic acid-
l-Amino-2-bromo-4-hydroxyanthraquinone
l-Araino-5-chloroanthraquinone
l-Aniino-2,4-dibronioanthraquinone
l-Amino-9, lO-dihydro-9, 10-dioxo-4-p-toluenesulfonamido-2-
anthracenesulfonic acid, sodium salt
N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon-
amide
p- [(p-Aminophenyl)azo]benzenesulfonic acid
Aniline (Aniline oil)
Anilinoraethanesulfonic acid and salt
o-Anisidine
o-Anisidinoraethanesulfonic acid
Anisole, tech
Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone)
Benzaldehyde, tech
7H-Benz[de]anthracen-7-one ( Ben zan throne)
Benzoic acid, tech
2-Benzothiazolethiol, sodium salt
[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'- (2H, 2 'H)-dione
(Pyrazoleanthrone yellow)
[4,4'-Bi-7H-benz|de]anthracene]-7,7'-dione
Biphenyl
1 , 4- Bi s [ 1 - anthraquinony lamino ] anthraquinone
3- Bromo-7H-benz[de] anthracene- 7-one (5- Bromobenzan throne) -
2-Bromo-4 ,6-dinitro aniline
1-Chloroanthraquinone
Chlorobenzene, mono
6-Chlororaetanilic acid
l-Chloro-2-methyl anthraquinone
1-Chloro-S-nitroanthraquinone
4-Chloro-3-nitrobenzenesulfonaraide
a-Chlorotoluene (Benzyl chloride)
Cinnamoyl chloride
Cresols, total'
o-Cresol
(m,p)-Cresol
All other"
Cresylic acid, refined'
Cumen e
Cyclohexane
Cyclohexanone
Cyclohexylamine
1 ,4-Diaminoanthraquinone
2, 6-Diaminoanthraquinone
1 ,4-Diamino-2,3-dihydroanthraquinone
4,4'-Diamino-2,2'-stilbenedisulfonic acid
1,000
pounds
34,967,181
524,009
359
724
36
1,014
456
409
820
686
o
106
664
195
64
4
607
1
184
155
505
9
667
149
626
114
403,505
6
91
40
507
80,357
49,668
28,292
28,313
54,981
2,292,949
2,298,394
783,440
104
1,000
pounds
16,195,641
1,000
dollars
1,433,855
1,679
502,995
4,231
14,273
1,345,895
2,018,404
56,960
1,443
1,989
7
303
4
438
8
617
7
442
46
882
60
168
7
055
1
174
See footnotes at end of table.
CYCLIC INTERMEDIATES
TABLE 1.— Cyclic intermediates: U.S. production and sales. 1972— Continued
4,5'-Dibenzamido-l,r-iminodianthraquinone
3,9-Dibromo-7H-benz[de]anthracen-7-one
o-Dichlorobenzene
p-Dichlorobenzene
3,3'-Dichlorobenzidine base and salts
Dicyclopentadiene (includes cyclopentadiene)
N,N-Di ethyl aniline
9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic acid and
salt
9, lO-Dihydro-9, lO-dioxo-l-anthracenesulfonic acid and salt
(Gold salt)
1 ,4-Dihydroxyanthraquinone (Quinizarin)
l,8-Dihydroxyanthraquinone(Chryazin)
1 ,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro
chrysazin)
16, 17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone)
N,N-Dimethylaniline
N,N-Dimethylbenzyl amine
2, 2- Dimethyl -1 , 1 ' -bianthraquinone
4,4'-Dinitrostilbene-2,2'-disulfonic acid
2, 4 (and 2, 6)-Dinitrotoluene
Diphenyl amine
1 ,4-Di-p-toluidinoanthraquinone
Divinylbenzene-
N- Ethyl aniline, refined
2-(N-Ethylanilinc;)ethanol
Ethylbenzene ^
N-Ethyl-N- phenyl benzyl amine
Hydroquinone, tech
3-Hydroxy-2-methylcinchoninic acid
6-Hydroxy-2-naphthalenesulfonic acid, sodium salt
1,1'- Iminobis [4-aminoanthraquinone]
1,1 ' -Iminodianthraquinone (1, 1 ' -Dianthrimide)
Isocyanic acid derivatives, total
Toluene-2,4- and 2,6-diisocyanate (80/20 mixture)
Other isocyanic acid derivatives
4,4'-Isopropylidenediphenol (Bisphenol A)
Leuco quinizarin (1 ,4, 9, 10-Anthratetrol)
dl-p-Mentha-1 ,8-diene (Limonene)
Metanilic acid (m-Aminobenzenesulfonic acid)
4,4'-Methylenedianiline
p- (5-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid
3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z)
a-Methylstyrene
Nitrobenzene
5-Nitro-o-toluenesulfonic acid [S03H=1]
5-Nitro-o-toluidine [NH2=1]
Nony 1 pheno 1
1- [ (7-Oxo-7H-benz [de] ant hracene-3-yl) amino] anthra-
quinone ■
Phenol, total'
Natural, from coal tar and petroleum
Synthetic, total
From cumene ■
Other synthetic
1- Phenyl -1,2-propanedione, 2-oxime
Phthalic anhydride
Picolines'
Production
Sales
Quantity '
Value
value'
2,000
1,000
1,000
Per
pounds
pounds
dollars
pound
55
166
62,386
62,389
7,233
$0.12
77,317
70,704
6,285
.09
4,612
4,618
5,792
1.25
91,267
71,673
2,802
.04
3,556
2,639
1,417
.54
249
997
2,095
107
159
141
8,073
1,671
.21
79
59
90
1.53
38
9,230
433,885
33,845
16,981
3,957
.23
86
3,367
2,698
1,720
.64
1,866
218
5,675,900
447,259
13,812
.03
478
11,779
11,616
9,129
.79
430
637
44
60
701, M8
508,847
156,742
.31
419,404
362,876
101,516
.28
282,244
145,971
55,226
.38
255,189
77,197
11,957
.15
87
9,273
...
1,082
1,888
830
.44
157
61
43
61
1.42
37 398
26 112
1,317
. .05
551,169
12,622
804
• .06
8,017
397
100,295
40,625
4,648
.11
292
2,096,125
1,016,215
65,944
.07
44,298
25,687
1,772
.07
2,051,827
990,528
64,172
.07
1,810,884
240,943
238
932,978
634,050
44,274
.07
6,416
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS. F72
TABLE 1, --Cyclic intermediates: U,S, production and sales, 1972--Continued
Unit
value'
Piper id in e
Prop i oph enone
Salicylaldehyde
Salicylic acid, tech
Styrene, all grades
Terephthalic acid
Terephthalic acid, dimethyl ester
1 ,4,5, 8-Tetrahydroxyanthraquinone, leuco derivative--
6,6'-Thiodimetanilic acid
Toluene- 2, 4 -diamine (4-ni-Tolylenedianiine)
4-(o-Tolyazo)-o-toluidine CCI. Solvent Yellow 3)
1 , 2,4-Trichlorobenzene
1,3, 3-Trimethyl-A^,a-indolineacetaldehyde
1 ,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)-
7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid
(J Acid Urea)
Violanthrone (Dibenzanthrone)
o- Xylene
p- Xylene
All other cyclic intermediates
1,000
pOWlds
477
289
4,468
47,095
5,940,729
1,928,907
2,167,332
54
175
167,902
395
15,552
338
701
237
489
831,782
2,207,556
3,391,402
1,000
pounds
163
3,547
9,136
2,810,182
55,316
675,700
2,102,848
1,973,680
1,000
dollars
160
3,577
3,708
160,568
50,349
16,195
94,816
434,790
Per
pound
'^ Calculated from rounded figures.
^ Includes straight-chain dodecylbenzene, tridecylbenzene and other straight-chain alkylbenzenes . Branched-chain
alkylbenzenes are included in all other cyclic intermediates.
' Includes data for coke ovens and gas-retort ovens, reported to the Division of Fossil Fuels, U.S. Bureau of Mines
and for tar and petroleum refineries and other producers, reported to the U.S. Tariff Commission.
'' Figures include (o,m,p)-cresol from coal tar and some m-cresol and p-cresol.
^ Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture.
CYCLIC INTERMEDIATES
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Cyclic intermediates for which separate statistics are given in table 1 are marked with an asterisk (*); cyclic
intermediates not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shoim below are taken from table 3. An x signifies that
the manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
Acenaph thenequinone
8-Acetamido-l- C4-acetamido-2-hydroxy-5-nitrophenylazo) -
2-naphthol .
5-Acetamido-2-aminobenzenesulfonic acid
3-[ C2-Acetamido-4-aminophenyl)azo]-l ,5-naphthalene-
disulfonic acid.
2,2'- [(S-Acetamido-2-ethoxyphenyl)imino]diethanol
2,2'- [ (5-Acetamido-2-methoxyphenyl) imino] diet hand
4-Acetamido-2-hydroxybenzoic acid
a- Acetamido-p- toluenes ulfonamide
*Acetanilide, tech
Acetic acid, phenyl ester
Acetoacetani lide
o-Acetoacetanisidide
Acetoacet-2 ,5-dimethoxy-4-chloroani lide
o-Acetoacetotoluidide
2 ' ,4' -Acetoacetoxylidide
1 ' -Acetonaphthone
Acetone phenylhydrazone
* Ace t ophenone , tech
p-Acetotoluidide
p- Ace tylbenzenes ulfonamide
p-Acetylbenzenesulfonic acid, sodium salt
p- Ace tylbenzenesulfony lure thane
N-Acetylsulfanilyl chloride
*Alkylbenzenes:
Dodecylbenzene (including tridecylbenzene) :
'Straight chain
Other
Alkylphenols , mixed
Alkylpiperazines, mixed
Alky 1 pyridines, mixed
a-dl-5-Allyl-6-imino-l-nethyl-5- (l-methyl-2-nentynyll -
barbituric acid.
a-dl-5-Allyl -5- (1 -methyl -2-pcntynyn-l-methylbarbituric
acid.
3'-Aminoacetanilide
4'-Aminoacetanilide (Acetyl-p-phenylenedi amine)
2'-Aminoacetophenone
3' -Aminoacetoplienone
4'-Aminoacetophenone
5 '-Amino- 2- (p-aminoanilino)benzenesulfonic acid
1- Amino- 4- (3-amino-4-sulfoani lino)-9, lO-dihydro-9, 10-
dioxo-2-anthracenesulfonic acid.
2- (p-Aminoanilino)-5-nitrobenzenesulfonic acid
3-Amino-p-anisanilide
*1-Aminoanthraquinone and salt
2-Aminoanthraquinone and salt
N- (4-Amino-l-anthraquinonyl) anthrani lie acid
BJL.
TRC.
GAF.
IPX.
TCH.
TCH.
SDW.
SDW.
CTN, EKT, MRK, SAL.
UCC.
FMP, HST.
FMP, HST, UCC.
FMP.
FMP, HST, t'CC.
HST.
CIV.
DUP.
ACP, CLK. SKO, UCC.
EK.
LIL.
LIL.
LIL.
ACY, CTN, MRK, SAL.
BRP, CO, MON, I'CC, WTC.
CO, SOC, UCC. UCC.
PRD.
AIP.
UCC.
LIL.
LIL.
AAP.
CAP,
TRC.
EK.
CTN.
EK.
TRC,
YAW.
TRC.
TRC.
PCW.
AAP,
ACY.
MAY,
SDC,
TRC
ACY,
GAF.
GAF.
See footnotes at end of table
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972--CONT I NUED
N-(5-Amino-l-anthraqiiinonyl)anthraniUc acid
4-Aminoantipyrine ''
6-Amino-3,4'-azodibenzenesulfonic rcid (C.I. Acid
Yellow 9) .
Aminoazoxylene toluene homologues
p-Aminobenzamide
1- Amino- 4-benzaiiiidoanthraquinone
l-Amino-S-benzamidoanthraquinone
7_ [p- (p-Aminobenzamido)benzamido]-4-hydroxy-2-
naphthalenesulfonic acid.
*7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic
acid.
2-Amino-p-benzenedisulfonic acid [SOjH^l]
o-Aminobenzene thiol
4-Aminobenzenethiosulfonic acid, sodium salt
2 - Ami nobenz imidazole
4-Aminobenzophenone
2-Amino-6-benzothiazolecarhoxylic acid
2-(m-Aminobenzoyl)-o-acetanisidide
N-(4-Amino-3-brorao-l-anthraquinonyl)-p-toluidine
sulfonic acid.
Stand 8)-Amino-8(and 5)-bromo-9,10-dihydro-9,10-dioxo-
l,6(and 1 ,7)anthracenedisulfonic acid.
*l-Amino-2-bromo-4-hydroxyanthraquinone
1- Amino- 2-bromo-4-p-toluidinoanthraquinone
*l-Amino-5-chloroanthraquinone
l-Amino-8-chloroanthraquinone
2 -Amino- 1 - ch 1 oroanth raquinone
2-Amino-3-chloroanthraquinone
4- Amino-6-chloro-m-benzenedi sulfonamide ---
4-Amino-6-chloro-m-benzenedi sulfonamide hydrochloride
2-Aiiiino-6-chlorobenzothiazole hydrochloride
o-(3-Amino-4-chlorobenzoyl1benzoic acid
1- Amino- 2 -chloro-4-hydroxyanthraqui none
3-Amino-5-chloro-2-hydroxybenzenesulfonic acid
2-Amino-4-chlorophenol
l-(2-Amino-5-chlorophenyl)-l-phenylmethylenimine
2-Amino-6-chloropyrazine
3-Amino-6-chloropyridazine
2-Amino-5-chloro-p-toluenesulfonic acid [Sn3H=l]
6-Amino-4-chloro-m-toluenesulfonic acid [S03H=1]
2-Amino-p-cresol
*l-Amino-2,4-dibromoanthraquinone
1- Amino- 2 , 4- di ch 1 oroanthraquinone
2-Amino-4,6-dichloro-5-cresol
4-Amino-2,6-dichorophenol hydrochloride
Manufacturers' identification codes
(according to list in table 31
DUP.
VPC.
ACY,
CMC
ACS.
ICC,
SDH
(lAY,
TRC
ACY,
TRC
CMC.
CMC, GAP, TRC, VPC.
DUP, TRC.
PIS, FMT.
SDC.
EK.
DUP.
DUP.
GAP.
TRC.
TRC.
AAP, DUP, UN, VPC.
ACS, TRC.
ACY, HAY, TRC.
DUP.
DUP, ICI.
GAP.
ABB.
ABB.
DUP.
AAP.
TRC.
TRC.
SW.
ABB.
ACY.
ACY.
HSC.
DUP, HSC.
TRC.
AAP, DUP, HN, TRC, VPC.
TRC.
EK.
EK.
CYCLIC INTERMEDIATES
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported,
IDENTIFIED EY MANUFACTURER, 1972— CONTINUED
*l-Aiiiino-9,10-dihydro-9, 10-dioxo-4-p-toluenesulfonaiiiido-
2-anthracenesulfonic acid, sodium salt.
5-Amino-4,5 '-dihydroxy-3,4' - [(2-methoxy-5-raethyl-p-
pheny lene )bis(azo)]-di- 2, 7-naphthalenedi sulfonic acid,
5 ' -benzenesulf onate .
3-Amino-9-ethylcarbazole
N- C2-Aminoethyl)-N-ethyl-m-toluidine
3-Amino-a-ethylhydrocinnamic acid
N- [2- C4-Amino-N-ethyl-m-toluidino)ethyl]methane-
sulfonamide, hemisulfate.
N-Aminohexamethyleneimine
4- Amino- 5-hydroxy- 2, 7-naphthalenedi sulfonic acid,
benzenesulfonate.
4-Amino-5-hydroxy-2 ,7-naphthalenedisulfonic acid
(H acid), monosodium salt.
4-Araino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4-
acid) .
6-Amino-4-hydroxy-2-naphthalenesulfonic acid CGarama
acid], sodium salt.
7-.iVmino-4-hydroxy-2-naphthalenesulfonic acid (,J acid) ,
sodium salt.
2- (2- Amino- 5-hydroxy- 7-sulf 0-1 -naph thy lazo) -5 -nit ro-
benzoic acid.
4-Amino-3-(6-methanesulfoaminoethyl)-N,N-diethylaniline
hydrochloride.
*N- (4- Amino- 3- me thoxy-1-anth raquinonyl)-p- toluenes ulfon-
amide.
5-Amino-6-raethoxy-2-naphthalenesulfonic acid
4-Amino-5-methoxy-o-toluene sulfonic acid
m- [(4-Amino-3-methox\'phenyl)azo]benzenesulfonic acid
8- Amino- 6-methoxyquino line
4- [(4-AjTdno-5-methoxy-o-tolyl)azo]-5-hydroxy-2 ,7-
naphthalenedisulfonic acid, benzenesulfonate.
3- [ (4- Amino- 5 -methoxy-o-tolyl )azo]-l,5-naDh thalenedi sul-
fonic acid.
7- [ (4- Amino-S-methoxy-o-tolyl) azo] - 1 , 3-nanhthalenedi -
sulfonic acid.
4-.%nino-4'-(3-methyl-S-oxo-2-pyrazolin-l-yl)-2,2'-stil-
benedisulfonic acid.
2 -. Ami no- 3-me thy 1 pyridine
2-Amino-6-methylpyridine
2-Amino-4-methylpyrimidine C2-Amino-4-raethyl-l ,3-
diazine) .
2- Amino- 4- (methylsulfonyl) phenol .
2-Amino-5-methyl-l ,3,4-thiadiazole
4-Aminonaphth [2 ,3-c]acridan-5 ,8, 14-trione
2 - Amino- 1 ,5 -naph thalenedi sulfonic acid
3-Amino-l ,5-naphthalenedisulfonic acid (C acid)
3-Amino-2 ,7-naphthalenedisulfonic acid
6-Amino-l ,3-naphthalenedisulfonic acid (Amino I acid)
7-Amino-l ,3-naphthalenedisulfonic acid (Amino G acid)
l-Amino-2-naphthalenesulfonic acid (o-N'aphthionic acid)-
2-Amino-l-naphthalenesulfonic acid (Tobias acid)
4-Amino-l-naphthalenesulfonic acid (Naphthionic acid)
4-Amino-l-naphthalenesulfonic acid, sodium salt
4(and 5)-Amino-l-naphthalenesulfonic acid
Manufacturers' identification codes
(according to list in table 3)
AAP
DUP, GAF.
TRC
SDC
WAY
SDW
WAY
F^^p
TRC
ACS
ACY,
GAF. TRC.
TRC.
HN,
TRC.
TRC.
EKT.
AAP,
DUP, GAF.
TRC.
ACS.
DUP,
TRC.
PD.
TRC.
TRC.
TRC.
TRC.
RIL.
RIL.
ACY.
TRC.
ACY.
DUP.
ACY,
SDH.
TRC.
TRC.
UN,
TRC.
DUP,
TRC.
DUP.
ACY,
SW.
ACY,
DUP.
ACY,
TRC.
DUP.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification code
(according to list in table 5)
-Amino-2-naphthalenesulfonic acid (Broenner's acid)
-Amino-l,3,6-naphthalenetrisulfonic acid
-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid)-
-Amino-2-naphthol
- (4-Amino-l-naphthyla:o)-4- (1 , 1 ,3,3-tetramethylbutyl)
phenol .
-Amino-4-nitroacetani lide
-Amino-5- (m-nitrobenzamido) -p-toluenesulfonic acid
-Amino-5-nitroben2enesulfonic acid [S03H=1]
- Amino -4'»n itro-3-niethoxyazobenzene
- 2- Amino- 1- (p-nltrophenyl) -1 ,3-propanediol
-2-Amino-l-(p-nitrophenyl)-l ,3-propanediol
-Amino-4'-nitro-2,2'-stilbenedisulfonic acid
- Amino- 5-nitrothia:ole
' -Aminooxani lie acid
'-Aminooxanilic acid
-Arainopenicillanic acid
-Aminophenol
-(p-Aminophenoxy)ethanol hydrochloride
- [ (p-Aminophenyl) azojbenzenesulfonic acid
- [(p-Aminophenyl)azo]benzenesulfonic acid
- [(4-Aminophenyl)azo]-l ,3-naph thai enedi sulfonic acid —
-Amino- 8- (phenylazo)-2-naphthol
-Amino-5-(phenylazo)-2-naphthol
- [ (p-Aminophenyl )azo] - 1-naph thy 1 amine
- [(p-Arainophenyl)azo] salicylic acid
-[ (p-Aminophenyl) azojsalicylic acid, sodium salt
,2 '-(m-Aminophenylimino)diethanol , diacetate ester
- (p-Aminophenyl) -6 -me thy Ibenzothiazole
- (p-Aminophenyl) -6-metliyl-7-ben20thia2olesulfonlc acid
and salt.
- (m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid--
- Amino- 2-propoxybenzoic acid
- ( Ami nopropyl)cyclohexyl amine
- Ami nopyri dine
-Aminopyridine
- Ami nopyrimi dine
-Aminorhodanine
-Aminosalicylic acid
-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic acid
-Ami no- 4- (1, 1,3,3- tetramethylbutyl ) phenol
-Amino- 4- (1,1 ,3,3-tetramethylbutyl) phenol hydro-
chloride.
-Aminothiazole
-Amino-p-toluamide
-Amino-p-toluenesulfonamide
-Amino-m-toluenesulfonic acid [SOjHsl]
-.Amino-m-toluenesulfonic acid [SOjHsl]
-'\mino-o-toluenesulfonic acid [50^11=1]
- Amino- 2-p-toluidinobenzenesulfonic acid
- (4-Amino-m-tolyla2o)benzenesulfonic acid
- [ (4- Amino-o-tolyl)azo]-l,5-naphthalenedi sulfonic acid-
- [ (4- Amino-o-tolyl)azo]-l,3-naphthalenedi sulfonic acid-
SNA,
TRC.
DUP.
ACS.
TRC.
r;AF.
SDC.
GAF.
ACS,
GAF, TRC
SDC.
PD.
PD.
UN,
TRC.
PCW.
cun,
TRC.
DUP ,
VPC.
TRD.
•1AL.
GAF.
TRC.
ACY,
DUP, TRC
TRC.
ALL.
ALL.
ACS.
TRC,
VPC.
ACS.
DUP,
TCH.
DUP.
DUP,
TRC.
TRC,
VPC.
SDW.
ABB.
NEP,
RIL.
RIL.
ACY.
EK.
MLS,
TRC.
GAF.
GAF.
GAF.
ACY,
MRK.
SDH,
X.
SDW.
ACY,
DUP.
DUP.
use.
TRC.
TRC.
TRC.
TRC.
CYCLIC IiJTERMEDIATES
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
2-Ainino-3,5-xylenesulfonic acid [S03H=1]
5-Amino-2,4-xylenesulfonic acid
•Aniline (Aniline oil)
Aniline hydrochloride
2 '-Anilino-6-diethylaniino-5-methylf luoran
2-Anilinoethanol
7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl
J acid) .
*Anilinomethane5Ulfonic acid and salt
8-Anilino- 1-naphthalenesulfonic acid (Phenyl peri acid)-
8-Ani lino- 1-naphthalenesulfonic acid, magnesium salt
m-Ani linophenol
D-Ani linophenol
o-Anis aldehyde
m-Anisidine
*o-.Anisidine
p-Anisidine
*o-Anisidinoniethanesulfonic acid
*Anisole, tech
3- (o-Anisyla2o)benzenesulfonic acid, sodium salt
Anthracene
Anthranilic acid (o-Aminobenzoic acid)'
*Anthra[l,9 cd]pyrazol-6(2H) -one (Pyrazoleanthrone)
Anthraquinone , 100°s
1 ,5-Anthraquinonedisulfonic acid
1 , 8- Anthraquinonedi sulfonic acid
1,1'- [1,5 (and 1 ,8) -Anthraquinonylenediaminolbis-
naphth [2 ,3-c]acridan-5,8, 14-trione.
N,N' - (1 ,5-Anthraquinonylene)dianthrani lie acid
N,N'- (l,5-Anthraquinonylene)dioxamic acid
(l-Anthraquinonyl)-l , 2 -hydrazinedi sulfonic acid,
disodium salt.
4' ,4' ' '-Azobis [4-biphenylcarboxylic acid]
Barbituric acid, sodium derivative
*Benzaldehyde, tech
l-Benzamido-4-bromoanthraquinone
1 - Ben z ami do- 4 -chloro anthraquinone
1-Benzamido-S-chloroanthraquinone
4-Benzamido-5-hydroxy-2,7-naphthalenedisulfonic acid
7-Benzamido-4-hydroxy-2-naphthalenesulfonic acid
Benzani lide
Benz (a) anthracene- 7,1 2- di one
*7H-Benz [de] anthracen-7-one (Benzathrone)
m-Benzenedisulfonic acid
Benzenesulfonamide
Benzenes ulfonic acid
Ben zenesu 1 f ony 1 chloride
1,2,4 ,5-Ben2enetetracarboxylic- 1,2, : 4, 5 -di anhydride
1,2,4-Benzenetricarboxylic acid, 1 ,2-anhydride (Tri-
mellitic anhydride).
Benzhydrol (Diphenylmethanol)
Benzidine hydrochloride and sulfate
SDH.
DUP.
ACS,
ACY,
DUP,
FST,
MAL,
MOB, RUC, USR
ACY,
EK.
SDH.
TCH.
CMC,
TRC.
ACS,
ACY,
ATL
DUP,
TRC,
VPC.
DUP,
SDC.
EK.
GAP.
SDC.
ASL.
EK.
AAP,
pi IP,
x.
DUP,
MON.
AAP,
ATL,
GAP
TRC,
VPC.
CTN,
DUP
GIV
LIL.
ACS.
EK.
DUP,
sw.
DUP,
GAP,
TRC
TRC.
CMG.
CMC.
DUP.
GAP,
TRC.
GAP,
SW.
DUP,
GAP.
DUP,
TRC.
ABB.
BPC,
m.
MNR,
VEL.
AAP.
GAP.
MAY,
TRC.
TRC.
TRC.
DUP.
EK.
MP,
ACY,
DUP
GAP,
ICI,
MAY, SDC, TRC
KPT,
UPF.
NES.
NES,
UPF.
NES.
DUP,
PCR
ACC.
PD,
UOP.
ACS,
LAK.
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
Benzidine sulfate, purified
*Ben2oic acid, tech
Benzoin
Benzoinisobutyl ether
a- Benzoin oxime
Benzonitrile
*2-Ben20thiazolethiol sodium salt
p-Benzoquinonedi oxime
IH-Benzotriazole
2H-3,l-Benzoxazine-2,4(lH)-dione
o-Benzoylbenzoic acid
Benzoyl chloride
N-Benzylacetamide
Benzyl amine
4- (Benzyl ami no) - 6- ch loro-m- ben zenedi sulfonic acid
5- [4-N-Benzylaniino-N-methylphenylazo] -l,2,4-tria20le
p- (Benzyl ami no) phenol
Benzyl chloro formate
4-Benzyl-6-chloro-3-keto-7-sulfamyl-l ,2 ,4-ben2ylthia-
diazine-l,l-dioxide.
1- Benzyl- 4 ,5-dimethyl-6- (p-methoxybenzyl) -1 ,2,3,6-tetra-
hydropyridine oxalate.
Benzyl disulfide
5- ( Ben zy 1 ethyl amino) -o-toluenesulf on ic acid
N-Benzyl-N-ethyl-m-toluidine
3-Benzyl-l,2,3,4,5,6-hexahydro-8-hydroxy-cis-6, 11-
dimethyl-2 ,6-methano-5-benza20cine hydrobromide .
6-Benzylidineaminopenicillanic acid, tertiary
octylamine salt.
4,4'- Benzyl idenedi-o-toluidine
4,4'-Benzylidinedi-2 ,5-xylidine
Ben zyli dene phthalide
p- (Ben zyloxy) phenol
l-Benzyl-4-phenylisonipecotic acid
l-Benzyl-4-phenylisonipecotonitrile
Benzyltrimethylajnmonium chloride
Ben zyltri methyl ammonium hydroxide
Benzyltrimethylammonium methoxide
*[3,3'-Bianthra[l,9-cd]pyra2ole]-6,6'-(2H,2'H)dione
(Pyrazoleanthrone yellow) .
[3,3'-Bi-7H-benz[de]anthracene]-7,7'-dione
* [4,4 '-Bi-7H-ben-[de] anthracene] -7, 7 '-dione
l,l'-Bi-2-naphthol
*Biphenyl
2,2'-Biquinoline
Bis-p-aminocyclohexylme thane
* 1,4- Bis [1- an thraquinonyl amino] anthraquinone
1,4-Bis [l-anthraquinonylaminojanthraquinone and 1,4-Bis
[5-chloro-l-anthraquinonylamino]anthraquinone (mixed) .
2,6-Bis(p-azidobenzylidene)-4-methylcyclohexanone
Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper
derivative.
UK, HN, KLM, HON, PFZ. VEL.
BPC.
BPC.
RSA.
VEL.
ACY,
GYR
USR, X
SDC.
FHT
SW.
SW.
ACY,
GAP
HK,
GAP,
VEL.
SDW.
ARS,
MLS
ABB.
TRC.
SDW.
CCW.
ACS.
ACS, DUP.
SDW.
TRn.
ACY.
ACS.
LIL.
EK.
SDW.
SDW .
MLS.
MLS.
MLS.
DUP, GAP, TRC.
DUP.
ACY, DUP, ICI, MAY.
EK.
CUE, DOW, GOC, MON, SNT.
EK.
DUP.
ACY, DUP, GAP, MAY, TRC.
TRC.
WAY .
TRC.
See footnotes at end of table.
I
CYCLIC INTERMEDIATES
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
4,4'-Bis [diethylaiiiino]benzhydrol salt, 2,7-naphthalene-
disulfonic acid, mixture.
4- Bis [ (p-diethylaininophenyl)meth\'l]-2 ,7-naphthalene-
disulfonic acid, leuco fonn.
4 ,4' -Bis [dimethylaminojbenzhydrol (Michler's hydrol)
4,4 '-Bis (dime thy 1 amino) ben ihydrol ,disulfinate
4,4'-Bis [dimethylamino]benzophenone (Michler's ketone)--
Bis [p- (diniethylamino)phenyl]methanesulfoni c acid and
salt.
3,3' -Bis [3' ,3'-(l'-ethyl-2'-niethyi;)indolyl]phthalide
3'- [Bis (2-hydroxye thy 1) amino] acetanilide
3' - [Bis (2-hydroxyethyl) amino] -p-acetoaniside
3'- [Bis (2-hydroxyethyl) araino]benzanilide, diacetate
ester.
3'- [Bis (2-hydroxye thy 1) amino] methanesulfoanilide,
diacetate ester.
4,4 '-Bis (p-methoxyphenyl')-3-hexanone
1,4-Bis [2- (4-methyl-5-phenyloxazolyl) jbenzene (Dimethyl
POPOP) .
Bis- (o-nitrophenyl) sulfide
1,4-Bis [2-(5-phenyloxazolyl))benzene {P0P0P1
2- Bromoace t ophenone
p-Bromoaniline
p-Bromoanisole
* 3- Bromo-7H-benzfdel anthracene- 7- one (3-Bromo-
benzan throne) .
Bromobenzene, mono
p-Bromobenzenesulfonyl chloride
p-Bromobenzhydrol
p-Bromobenzoic acid
4- Bromob en z ophenone
Bromoch 1 oroben zene
6-Bromo-5-chlorobenzoxazolone
*2-Bromo-4,6-dinitroaniline
Bromof lucres ce in
3-Bromo-2-hydroxy-4 ,4 ,5 ,5-tetramethyl-2-cyclopentene-
1-one.
l-Bromo-4-(methylajnino)anthraquinone
6-Bromo-3-methyl-7H-dibenz[f ,ij ]isoquinoline-2,7- (3H)-
dione.
3- (Bromome thy 1 ) thi ophene
l-Bromonaphthalene
2-Bromo-4' -nitroacet ophenone
p-Bromophenol
(p - Bromoph eny 1) ace tonit rile
4- Bromo- 1 -ph th alami dopen t ane
a-Bromotoluene
m-Bromotoluene
p-Bromotoluene
2 - Bromo- 1 , 3 , 5- 1 ri ethy Iben zene
p-Butoxybenz aldehyde
p-Butoxyphenol
4- [3- (p-Butoxyphenoxy)propyl]morpholine
1 - ( Buty 1 amino) an thraquinone
p- Butyl aniline
3- (N-Butylanilino)propionitrile
SDH,
SW.
SW.
DSC,
DUP,
SDH
ACS.
SDH.
GAP.
TCH.
DUP,
TCH.
LIL.
ARA.
ARA.
EK.
OPC.
ACY, DUP, GAP, MAY, TRC.
PD.
DOW.
AAP, HST, SDC, TRC.
ICC.
AAP, EDO.
AAP.
SOW.
EK.
GAP.
EK.
BPC.
PD.
EK.
EK.
BPC, EK.
DUP.
EK.
ABB.
ABB.
AAP.
DUP.
TCH.
552-743 O - 74 - 3
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972~CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
2-tert-Butylanthraquinone
p-tert-Butylhenzaldehyde
n - Buty Ibenzene
sec-Butylbenzene
tert- Buty Ibenzene
p-tert-Butylbenzoic acid
2-tert-Butyl-p-cre5 0l
6-tert-Butyl-iii-cresol
Cn- Buty Icyclopentadienyl) eye lopentadienyl iron
2 '-tert- Buty 1-4' ,6 '-dimethylacetophenone
4 -Butyl -a- (dimethyl amino) -o-cresol
2-tert-Butyl-4-ethylphenol
N^- Buty l-4-methoxyiiiet anil amide
2-tert-Butyl-5-methylanisole
o-sec-Butylphenol
p- sec- Buty Iphenol
o- 1 ert - But y Ipheno 1
p- tert- Buty Iphenol
tert- Buty Is tyrene
p- tert - Buty Itoluene
5- tert- Buty 1-1, 2, 3- trimethy Ibenzene
5- tert- Buty 1-m- xylene
6-tert-Butyl-2,4-xylenol
d-10-Camphorsulfonic acid
Camphosulfonic acid
Carbazole , refined
1- (4-Carbonyl-o-anisyl)-3-raethyl-3- (2-sulfoethyl)
triazene .
4,4'-Carbonylbis [phthalic anhydride]
6 -Carboxy fluorescein
[(o-Carboxyphenyl) thio]ethylmercury
Cedrene
2 '-Chloroacetoacetanilide
2'-Chloroacetophenone
3' -Chloroacetophenone
4'-Chloroacetophenone
4'-(Chloroacetyl)acetaniline
2'-Chloroacetyl-2 , 6- dime thy ani line
9-Chloroacridine
m-Chloroani line
o-Chloroaniline
p-Chloroaniline
3-(o-Chloroanilino)propionitrile
5-Chloro-o-anisidine [NH2=1] (4-Chloro-o-anisidine
[0CH3=1]).
5-Chloro-o-anisidine hydrochloride
*l-Chloroantliraquinone
2-Chloroanthraquinone
o-Chlorobenzaldehyde
p-Qnlorobenzaldehyde
4- (p-Chlorobenzamido)anthraquinone-l,2-acridone
Chloro-7H-benz[de]anthracen-7-one (Chlorobenzanthrone) -
*Ch 1 oroben zene , mono
p-Chlorobenzenesulfinic acid
p-Chlorobenzenesulf on amide
p-Chlorobenzenesulfonic acid
o-Chlorobenzoic acid
2-Chlorobenzoxazole
7-Chlorobenzo[b]thiophen- 3(210 -one
5-Chloro-2-benzoxazolinone
o-(p-Chlorobenzoyl) benzoic acid
DUP.
GIV.
PLC.
PLC.
EK, MTR, PLC, UOP.
sue.
ACY.
KPT, PRD.
ARA.
GIV.
RH.
ACY.
ALL.
GIV.
DOW, IN A.
DOW.
IN A.
DOW, PRD, SCN, UCC.
DOW.
GIV, SHC.
GIV.
GIV.
PIT.
OTC.
KF.
SDC.
GAF.
PCR.
EK.
LIL.
GIV.
FHP, HST.
LIL.
DUP.
SDW.
EK.
DUP, GAF.
DUP, MON, USR.
DUP, MON.
DUP, TCH.
ALL.
GAF.
ACY,
ACY,
HN, [
HN.
GAF.
ACY,
ACS,
TRC.
ACY.
HTR,
HN.
EK.
ACS.
SW.
ACY.
GAF, MAY, TRC.
GAF.
DOW, DVC, HK, MON, MTO, PPG, SCC.
CYCLIC INTERMEDIATES
TABLE 2, —Cyclic intermediates for which U.S, production or sales were reported^
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
p-Chlorobenzoyl chloride
4,4'- (o-Chlorobenz>'lidene)di-2,5-xylidine
Chloro(p-chlorophenyl)pheny line thane
Chlorocyclohexane
4-Chloro-2-cyclopentylphenol
l-Chloro-2 ,5-diethoxy-4-nitrobenzene
2-Chloro-N,N-diethyl-4-nitro aniline
2-Chloro-3' ,4'-dihydroxyacetophenone
2-Chloro-l ,4-dihydroxyanthraquinone
4' -Chloro-2 ' ,5 ' -dimethoxyacetoacetanilide
5-Chloro-2 ,4-dimethoxyani line
[(4-Chloro-2,5-diniethylphenyl)thio] acetic acid
1- Chloro-2, 4- dinitrobenzene (Dinitrochlorobenzene)
5-C]iloro-4,6-dinitrobenzenesulfonic acid
4-Chloro-3, 5-dinitrobenzenesulfonic acid, potassium salt-
4-Chloro-5,5-dinitrobenzoic acid
3- Chlorodi phenyl amine
Ch 1 o rod iphenylme thane
5-Chloro-2,4-disulfonyl- (N-benzyl)ani line
N-(2-Chloroethyl)-4- (2-chloro-4-nitrophenylazo)-N-ethyl-
aniline.
4- [ (2- Chloroethyl) ethyl amino] -o-tolualdehyde
4- [ (2- Ch 1 oroe thy 1) ethyl amino ]-o-tolui dine
p- [( 2- Chloroethyl) methyl amino] benzaldehyde
l-Chloro-3-f luorobenzene
Chloroformic acid, benzyl ester
Chloroformic acid, phenyl ester
3' -Chloro-4'-hydroxyacetophenone
3-Chloro-4-hydrox>'phenylacetothiomorpholide
7-Chloro-4-hydroxyquinidine
7-Chloro-4-hydroxyquinidine hydrochloride
3-Chloro-4-hydroxyquinoline-3,4-carbonic acid
4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide
4-Chlorometanilic acid
5-Chlorometani lie acid
*6-Chlororaetanilic acid
N- [(S-Chloro-2-methoxyphenyl)azo]5arcosine
p- (Chloromethyl)anisole
*l-Chloro-2-methylanthraquinone
6-Chloro-4-methylbenzo[b]thiophene-2-ol
a-Chloromethylnaphthalene , crude
4-Chloro-N-methyl-3-nitrobenzenesulfonamide
Chloromethylphenyl ether
2-Chloro-5- (N-methylsulfamoyl) sulfanilamide
5-Chloro-2-CN-methylsulfonyl)-4-sulfarayl-N-benzylani line-
Chloronaphthalenes
2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline)
4-Chloro-2-nitroaniline CP"Chloro-o-nitroaniline)
*l-Chloro-5-nitroanthraquinone
l-Chloro-2-nitrobenzene CChloro-o-nitrobenzene)
HN.
GAF.
OPC, UOP.
ACY.
DOW.
GAF.
DUP.
SDW.
HSU.
PCW.
PCW.
ACS.
DUP, SDC.
TRC.
X.
GAF.
GAF.
GAF.
.WP.
TRC.
F.K.
CTN.
CTN.
ABB.
ABB.
i PD
PD.
SDH.
TRC.
DUP.
ACS.
AAP, GAF, TRC.
ATL.
SDW.
ACY, DUP. TRC.
ACY.
BPC.
TRC.
BPC.
ABB.
ABB.
KPT.
DUP.
DUP.
ACY, MAY, TRC.
DUP, r!ON.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 51
l-Chloro-3-nitrobenzene (Qiloro-m-nitrobenzene)
l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene)
2-Chloro-5-nitrobenzenesulfuric acid
*4-Chloro-3-nitrobenzene sulfonamide
4-Chloro-3-nitrobenzenesulfonanilide
2-Chloro-5-nitrobenzenesulfonic acid
2-Chloro-5-ni trobenzenesulfonic acid, sodium salt
4-Chloro-3-nitrobenzenesulfonic acid
4-Chloro-3-nitrobenzenesulfonyl chloride
2-Chloro-4-nitrobenzoic acid
2-Chloro-5-nitrobenzoic acid
2~Chloro-5-nitrophenyl methyl sulfone
4-Chloro-3-nitrophenyl methyl sulfone
2-Chloro-4-nitrotoluene
4-Chloro-2-nitrotoluene
o-Chlorophenol
p-Chlorophenol
2-Chlorophenothiazine
(p-Chlorophenyl)acetonitrile
4-Chloro-a-phenyl-o-cresol
4-Chloro-o-phenylenediamine
2-Chloro-l , 3-phenylenedi amine- S- sulfonic acid
2,2 '- fn-Chlorophenylimino)diethanol
2,2 ' - (m-Chlorophenyl imino)diethanol , diacetate ester
2- (o-Chlorophenyl)-2- (methylamine)cyclohexanone
3- to-Chlorophenyl) -S-methyl-4-isoxazolecarboxylic acid ,
acid chloride.
1- (o-Chloropl"ienyi)-3-methyl-2-pyrazolin-5-one-
1- (p-Chlorophenyl}-3-methyl-2-pyrazolin-S-one
p-Chlorophenyl methyl sulfone
2-Chloro-4-phenylphenol
o-Chlorophenylphthalimide, potassium salt
4-Chlorophthalic acid
3-Chloropropenylbenzene CCinnamyl chloride-)
1- (3-Chloropropyl)-4-methylpiperazine
7-Chloro-4-quinolinol
4-Chlororesorcinol
5-Chlorosal icy aldehyde
Chlorostyrene, mono
2-Chloro-5-sulfamoylbenzoic acid
2-Chlorothiophene
p-Chlorothiophenol
m-Chlorotoluene
o-Chlorotoluene
p-Chlorotoluene
*a-Chlorotoluene (Benzyl chloride)
3-Chloro-o-toluidine [NHj=l]
3-Chloro-p-toluidine [NHj=l]
4-Chloro-o-toluidine [NHj=l] and hydrochloride
5-Chloro-o-toluidine [NH =1] (4-Chloro-o-toluidine
[CH3 = 1]).
5-Chloro-o-toluidine hydrochloride [Nllj = l]
N- [ (5 -ailoro-o-tolyl)azo]sar cosine
DUP.
DUP,
MON.
TRC.
MP,
DUP,
GAF, ICC, TRC
TRC.
ACS,
TRC.
DUP.
ACS,
GAF,
TRC.
AAP,
SDC.
RSA,
SAL.
TRC.
TRC.
TRC.
DUP.
DUP.
DOW,
MON.
DOW,
MON.
SK.
OPC,
UOP.
flON.
FMT.
SDC.
TCH.
SDC.
HST.
DUP
HST, TRC
TRC.
DOW.
PD.
sw.
SDW.
SK.
SDW.
AAP,
GAF.
EK.
DOW.
TRC.
FIS.
SFA.
HK,
HN.
UN.
UN.
BPC,
MON, VEL
DUP.
DUP.
BUC.
DUP.
ATL,
SDH.
ALL,
ATL.
CYCLIC INTERMEDIATES
TABLE 2, --Cyclic intermediates for which U,S, production or sales were reported^
IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 5)
l-(6-Chloro-o-tolyl)-3-nethyl-2-pyrazolin-5-one
[ (4- Chloro-o-tolyl)thio] acetic acid
4-Chloro-a,a,a-trifluoro-3-nitrotoluene
6-Chloro-a,a,a-trif luoro-m-toluidine
Chlorotriphenylme thane
a-Chloro-p- xylene
2 -Chloro-p- xylene
4-Chloro-2,5-xylenesulfonyl chloride
Cholesteryl nonanoate
Cholesteryl oleyl carbonate (Mesomorphic)
Cholestyramine, pure
Cholic acid
•Cinnamoyl chloride
*Cresols : ^
m-Cresol
*o-Cresol :
From coal tar
From petroleum
Synthetic
p-Cresol
Cresols , mixed: '
*(m,p)-Cresol ;
From coal tar
From petroleum
(o,m,p)-Cresol :
From coal tar
From petroleum
Other
*Cresylic acid, refined:'
From coal tar
From petroleum
Synthetic
Cryptocyanine
*Cumene
2-[p-(Cyanoacetamido)nhenyl]-6-methyl-7-ben:othia:ole-
sulfonic acid.
Cyanoacetic acid, 2-ethylhexyl ester
p-Cyanobenzaldehyde
4- [(2-Cyanoethyl)ethylamino]-o-tolualdehyde
P- [ (2-Cyanoethyl)methylamino]benzaldehyde
:i-Cyano-B-methylcinnamic acid, ethyl ester
*Cyclohexane —
1 ,2-Cyclohexanedicarboxylic anhydride
1 ,3-Cyclohexanedione
Cyclohexanol
*Cyclohexanone
Cyclohexanone oxime
Cyclohexene
3-Cyclohexene-l-carboxaldehyde-l,2,3,6-tetrahydro-
benzaldehyde.
HST.
(lAF.
PCIV.
HK,
PCW.
EK.
BPC.
DUP.
ACS.
EK.
EK.
MRK.
WIL.
ARS,
imp,
X.
KPT,
PRD.
KPT.
MER,
fJPC,
PRD,
KPT,
PIT.
HPC,
SW.
Acr,
KPT.
HER,
NPC,
PRD.
ACP
KPT.
NPC
NPC
KPT
MER
NPC,
PRD.
PIT
ASH, CLK, CSP, DOW, GOC, MOC, MON, SIIC, SKO, SNT,
SOC, TX, UCC.
DUP.
DUP, GAF.
DUP, GAF.
.A.Sll, CSD, EN.I, GOC, GRS, PI.C, PPR, SWC, TX , UOC.
ACS .
PD.
ACP, CNP, DUP, HON.
ACP, CEL, CNP, DBC, DUP, MON.
ACP, CNP.
EK, PLC, USR.
UCC.
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2.— Cyclic intermediates for which U,S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
rianuf acturers ' identification codes
(according to list in table 3)
4-Cyclohexene- 1,2-dicarboximide
4-Cyclohexene- 1 ,2-dicarboxylic anhydride
Cyclohexene oxide
"Cyclohexylamine
N^-Cyclohexylmetanilamide
Cyclohexyl-2-Tiropanone
N-Cyclohexyltaurine, sodium salt
Cy c 1 open tadienyl iron
Cyclopentanol
Cyclopentene
p-Cymene
De cab romobi phenyl
Deoxycholic acid
Diacenaphtho[l,2-j : 1 ,2 ' -il]f luoranthene (Decacvclene)--
l,5Cand 1,8) -Diacetamidoanthraquinone
l,5-Diacetaiiiido-4,8-dibromoanthraquinone
3,5-Diacetamido-2,4,6-triiodobenzoic acid
3- (Diallylcarb;moyl)-l,2,2-trimethylcyclopentan-
carboxylic acid.
N^N^- Dial lylmel amine
Diallylchlorendate
*1 ,4-Diaminoanthraqiiinone
1 ,5-Diaininoanthraquinone
l,5(and 1,8) -Diaminoanthraquinone
*2,6-Diaminoanthraquinone
3,3' -Diaminobenzani lide
3,4-Diaminobenzanilide
2 ,4-Diaminobenzenesulfonic acid [SO H=l]
2,5-Diaminobenzenesulfonic acid [50^11=1]
3,5-Diaminobenzoic acid dihydrochloride
4,4 ' -Diamino- 1,1' -bianthraquinone-3,3' -di sulfonic
acid, disodium salts.
4,4'-Diamino-2 ,2 '-biphenyldi sulfonic acid
1 ,3-Daiminocyclohexane
3, 7- Diamino- 4, 6 -dibenzothiophenedi sulfonic acid,
5,5-dioxide, disodium salt.
1 ,4- Diamino- 2 ,3-dichloroanthraquinone
*1 ,4- Diamino- 2 ,3-dihydroanthraquinone
4, 8- Diamino- 9,10- dlhydro- 1,5- dihydroxy -9,10 -dioxo- 2,6-
anthracenedisulfonic acid.
1 ,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedi-
carboximide.
1 ,5-Diamino-4,8-dihydroxyanthraquinone
1 ,8-Diamino-4,5-dihydroxyanthraquinone
4,5-Diamino-l ,8-dihydroxyanthraquinone
1,4- Diamino- 5 -nitroanthraquinone
2 ,4-Diamino-6-phenyl-s-triazine
2,6-Diaminopyridine
*4,4'-Diamino-2,2'-stilbenedisulfonic acid
3,5-Diamino-p-toluenesulfonic acid [Sn^H^l]
3. 5- Diamino- 2 ,4 ,6-triiodobenzoic acid
1,4: 3,6-Dianhydroglucitol
2,5-Dianilinoterephthalic acid
Diary Iguanidine
SFC.
PIT.
USR.
ABB, HON RBC, VGC.
CMC.
niv, LIL.
r,AF.
ARA.
LIL.
ARA, PLC.
ACS, HN, HPC.
IVIL.
SDC.
AAP.
TRC.
SDW .
HTlT.
ACY.
SAR.
CMC,
DUP,
GAF, SDC
GAF,
TRC.
AAP,
TRC.
AAP,
GAF,
TRC.
TRC.
X.
DUP,
TRC.
TRC.
ACS,
ACY
DUP.
ACY.
CMG,
DUP
AAP,
TRC.
ACY
VPC.
,\AP.
ICI.
GAF.
RU,
NEP,
ACY,
GAF.
SDW.
ICI.
X, X
DUP.
ATL, DUP, GAF,HSH , ICC, MAY, TRC.
VEL.
RIL,
CGY, GAF, SDH, TRC, VPC.
CYCLIC INTERflEDIATES
TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
p-Diazo-N,N- dimethyl aniline- 1- amino- 8-naphthol- 3-siil-
fonate-6-sulfonic acid, sodium salt.
1,5-Dibenzamidoanthraquinone
6, ll-Dibenzajiiido-16H-dinaphtho[2,3-a,2' ,3' -i] carbazole-
5,10,15,17-tetrone.
*4,5'-Dibenzamido-l ,1 '-iminodianthraquinone
1,5-Dibenzoylnaphthalene
2-(N,N-Dibenzyl)amino-4-acetamidoanisole
Dibenzylazodicarboxylate
N,N' -Dibenzyle thy lenedi amine
N,N'-Dibenzylethylenediamine di acetate
N,N'-Dibenzylidenetoluene-a,a-di amine
5' ,4 ' -Dibenzyloxy-2-bromobutyrophenone
3,4-Dibenzyloxybutyrophenone
2 , 4 ' - Dib romoace tophenone
*3,9-Dibromo-7H-benz[de]anthracen-7-one
m-Dibromobenzene
p-Dibromobenzene
4,4'-Dibromobenzil
ar-Dibromoethylbenzene
2,6-Dibromo-4-nitroaniline
2 ,6-Dibromo-4-ni trophenol
a ,a-Dibromo-p-nitrotoluene
5 , 13-Dibromo-8 , 16-pyranthrenedione
3,5-Dibromo-3' -tri f luoTOmethylsalicylani lide
p-Dibutoxybenzene (DBB)
2,5-Dibutoxy-4-morpholinobenzenediazonium sulfate
1 ,1 '-Di-n-butyldicyclopentadienyliron
2,6-Di-tert-butyl-4-nonylphenol
Dibutyltin bis(cyclohexylmaleate)
3',4'-Dichloroacetophenone
2,4-Dichloroaniline
3,4-Dichloroaniline
2,5-Dichloroaniline and hydrochloride [NH2=1]
3-(2,4-Dichloroanilino)-l-(2,4,6-trichlorophenyl)-2-
pyrazolin-5-one .
1 ,5-Dichloroanthraquinone
1 ,5 (and 1 ,8) -Dichloroanthraquinone
Dichlorobenzanthrone
m-Dichlorobenzene
*o-Dichlorobenzene
oCand p)-Dichlorobenzene
*p-Dichlorobenzene
4, 6 -Dichloro-m-benzenedi sulfonamide
2,S-Dichlorobenzenesulfonyl chloride
*3,3'-Dichlorobenzidine base and salts
2,2'-DichIorobenzil
2 ,4-Dichlorobenzoic acid
4,7-Dichlorobenzo[b]thiophen-3(2H)-one
2,4-Dichlorobenzoyl chloride
Dichlorobenzyl chloride-
4,4- C2,6-Dichlorobenzylidene)di-2,6-xylidine
4,5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l ,2-dicarbo-
nitrile.
Dichlorodiphenylsilane
2',7'-Dichlorofluorescein
2-C5,8-Dichloro-l-hydroxy-2-naphthylazol-l-phenol-4-
sulfon amide.
Manufacturers' identification code
(according to list in table 3)
TRC.
TCI.
ACY, GAF, MAY, TRC.
GAP, TRC, VPC.
SDC.
KF, WTL.
hfYT.
mT.
SDH.
SDW.
SDW.
EK.
DUP, GAF, MAY, TRC.
EK.
DOW.
NES.
DOW.
SDC.
SW.
DUP.
ICI.
PCW.
ALL.
ALL.
ARA.
GAF.
x.
EK.
DUP, MON.
BUG, DUP.
TRC.
AAP.
ACY.
EK.
ACS,
DVC.
ACS,
ABB.
ACS.
ACS,
flTO.
HN.
BPC.
DUP.
ARA.
DCC.
EK.
TRC .
DOW, DUP, MON, NEV, PPG, SCC, SVT.
DOW. DVC, MON, PPG, SCC, SVT.
CIVN, LAK, UPJ.
SY'ITHETIC ORGAfllC CIIErilCALS, 197?
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
faccording to list in table 3)
5 ,14-Dichloroisoviolanthrone
Di (chloromethyl)diphenyl oxide
2,5-Dichloro-4- (3-niethyl-5-oxo-2-pyrazolin-l-yl)ben:ene
sulfonic acid.
2,6-Dichloro-4-ni troani line
1 ,2-Dichloro-4-nitrobenzene
1 , 4- Dichloro- 2 -nitrobenzene (Nitro-p-dichlorobenzene)
2 ,4-Dichlorophenol
3,4-Dichlorphenyl isocyanate
3- (2' ,6'-Dichlorophenyl)-5-iriethyl-isoxazole-4-carbonyl
chloride .
[ (2,5-Dichlorophenyl)thio]acetic acid
2,6-Dichloropyrazine
5,6-Dichloropyridazine
4,7-Dichloroquinoline
2 ,3-Dichloroquinoxaline
2,5-Dichlorosulfanilic acid [Sn3H=l]
2,5-Dichloro-4-sulfobenzenediazonium sulfate
p,a-Dichlorotoluene
a,a-Dichlorotoluene (Benzal chloride)
Di eye lohexy lamina
N,N'-3-Dicyclohexy 1-2- thiourea
*Dicyclopentadiene (includes cyclopentadiene)
Dicyclopentadiene dioxide
Didodecylbenzene
3-Diethanolainine-4-ethoxyacetanilide
p-Diethanolaminomethoxyacetanilide
p-Diethoxybenzene
p- (Diethylaniino)benzaldehyde
p- (Diethylamino)benzenediazonium chloride, zinc chloride
salt.
3'- [2- (Diethylamino)ethyl]-4'-hydroxyacetanilide
a- [ (2- Diethyl amino) ethyl ]-a-phenylcyclohexanemethanol ,
hydrochloride .
7' -Diethylamino-4-methylcoumarin
m- (Diethylamino)phenol (N ,N-Diethyl-3-aminophenol)
3- [(4' -N, N- Die thy 1 amino) phenylazo]-lH-l ,2 ,4-triazole
3-(Diethylamino)propiophenone
4- (Die thy 1 amino) -o-tolualdehyde
*N,N- Diethyl aniline
N,N-Diethyl-m-anisidine
Diethylbenzene
N, N - Di e thy Icyclohexyl amine
a,a'-Diethyl-4 ,4 '-dimethoxystilbene
N,N-Diethylmetanilic acid
n' ,n' -Diethyl- 4-methoxymetanilamide
N,N-Diethyl-4-nitroso-m-anisidine hydrochloride
N, N- Die thy 1-4-nitroso-m-pheneti dine
N, N - Di e thy 1-m-pheneti dine
N,N-Diethyl-p-phenylenedi amine oxalate
N ,N-Diethyl-m-toluidine
N,N-Diethyl-p-toluidine
Di f ur f ury 1 i di nepent ae rythri tol
10,ll-Dihydro-5H-dibenzo[a,d]cycloheptan-5-one
MON, VGC.
HOC, MON, UCC, VEL.
ICI.
BPC.
DCC, HST, TRC.
CWN, SW.
DlIP, MON.
DIIP.
DOW, MON.
nic.
nic.
ACS.
ACY.
ACY.
PD, SDW.
EK.
DUP.
TRC.
HN.
BPC.
ABB,
ABB.
EN J,
VEL.
cn.
HST.
H.ST.
ALL, GAP.
ACS, DUP, TRC.
HST.
PD.
ACY.
CAF.
ACY.
TRC.
ACY.
DUP.
ACS, ACY, DSC,
DUP.
DOW, KPP.
DUP.
LIL.
DUP.
PCW.
DUP.
GAP.
GAF.
EK.
DUP.
RSA.
SDC.
LIL.
CYCLIC INTERMEDIATES
TABLE 2, --Cyclic intfirmediates for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
9 , 10-Dihydro- 1 , 4-dihydroxy-9 , Id-dioxo- 2- anthracene -
sulfonic acid (2-Quinizarinsulfonic acid).
9, 10-Dihydro- 9, 10 -dioxo- 1 ,5- anthracenedi sulfonic aci
9,10-Dihvdro-9
disodium salt.
9,10-Dihydro-9
disulfonic acid and salt
10- dioxo- 1,5- anthracenedi sulfonic acid.
10- dioxo- 1,5 (and l,f
10- dioxo- 1 , 8- anthracene disulfonic acid.
10 -dioxo- 2 ,6- anthracenedi sulfonic acid
9,10-Dihydro-9
potassium sa
*9, 10-Dihydro- 9
and salt.
*9,10-Dihydro-9,10-dioxo- 1-anthracenesulfonic acid and
salt (Gold salt).
9,10-Dihydro-9, lO-dioxo-2-anthracenesulfonic acid and
salt (Silver salt) .
9,10-Dihydro-9,10-dioxo-2,7-anthraquinonedisulfonic
acid.
[Dihydrogen 3,3' ' -phthalocyaninedisulfonate(2-) ]copper-
10, ll-Dihydro-5- [3- (methylaminopropyl) ]-5H-dibenzo[a,d]
cyclohepten-5-ol .
9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic
acid.
d-Dihydrophenylglycine
*l,4-Dihydroxyanthraquinone (Quinizarin)
1,5-Dihydroxyanthraquinone (Anthrarufin)
1 ,5 (and 1,8) -Di hydroxy an thraquin one
*l,8-Dihydroxyanthraquinone (Chrysazin)
2,6-Dihydroxyanthraquinone (Anthraf lavic acid)
2,4-Dihydroxybenzaldehyde
2, 5-Dihydroxybenoic acid
3,6-Dihydroxybenzonorbornane
2,4-Dihydroxybenzophenone
2,4-Dihydroxy-3,3-dimethylbutyrolactone
l,5-Dihydroxy-4,8-dinitroanthraquinone
*l,8-Dihydroxy-4,5-dinitroanthraquinone r4,5-Dinitro-
chrysazin) .
4,5-Dihydroxy-2 ,7-naphthalenedisulfonic acid (Chrono-
tropic acid) .
6 ,7-Dihydroxy-2-naphthalenesulfonic acid
4 , 5- Dihydroxy- 3- (p- sulf opheny lazo) - 2 , 7-n aphtha lene-
disulfonic acid, trisodium salt.
* 16, 17- Dihydroxy viol an throne (Dihydroxydibenzanthrone)--
m-Diiodobenzene
3,5-Diiodosalicylic acid, lithium salt
Di i s opr opy Ibenzene
MP, HSH, PAT.
TRC.
GAF,
GAP,
TRC.
A'\P,
GAF,
TRC.
AAP,
ACY,
MAY,
TRC
DUP.
AAP.
ICl.
LIL.
AAP,
ACY,
DUP,
GAF,
HSH,
ICC,
MAY,
TRC
DUP,
GAF,
TRC.
ACY,
TRC.
CHG ,
GAF,
TRC.
GAF,
TRC.
EK.
ARS.
EK.
DUP,
GAF.
PD.
TRC,
VPC.
DUP,
GAF,
ICl,
TRC.
ACY, DUP, ICl, MAY.
EK.
DOW.
SY'lTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
2 ' ,5 '- Dime thoxy ace toacetani lide
2, 5- Dime thoxy aniline
1 ,5 (and 1,8) -Dimethoxyanthraquinone
2, 5- Dime thoxybenz aldehyde
m- D ime th oxyben zene
3,3'-Dimethoxybenzidine (o-Dianisidine)
3,3'-Dimethoxybenzidine hydrochloride
2 ,6-Dimethoxybenzoic acid
N,N'- [(3,3'-Dimethoxy-4,4'-biphenylylene)bis(azo) ]bis
(N-methyltaurine) .
2,5-Dimethoxy-B-methyl-S-nitrostyrene
2,5-Diriethoxy-a-methylphenethylamine
2,5-Dimethoxy-4'-nitrostilbene
4- (2' ,5 '-Dimethoxyphenethyl) aniline hydrochloride
(3,4-Dimethoxyphenyl) acetic acid
1- (3,4 ' -Dimethox>'phenyl)-2-aminopropane
2,5-Diraethoxytetrahydrofuran
2,5-Dimethoxytoluene
16, 17- Dime thoxy violanthrone
p- (Dime thy lamino) ben zaldehyde
p-Dimethylaminobenzenediazonium chloride, zinc cliloride
salt.
m- (Dime thy lamino) benzoic acid
5- (p- Dime thy laminobenzylidenejrhodanine
6-Dimethylamino-2- [2- (2,5-dimethyl-l-phenyl-3-pyrryl')-
vinyl]-l-methyl-l-quinolinium methyl sulfate.
m- (Dime thy lamino) phenol
2,6-Dimethyl-4-aminophenol
*N,N-Di methyl aniline
7, 12- Dime thy Ibenz [a] anthracene
2,5-Dimethylbenzenesulfonic acid
3,3'-Dimethylbenzidine (o-Tolidine)
3,3' - Dime thylbenzi dine hydrochloride
*N,N- Dime thy Ibenzyl amine
a,a-Dimethylbenzyl hydroperoxide
*2,2'-Dimethyl-l ,1 '-bianthraquinone
N,N-Dimethylcyclohexylamine
5,5-Dimethylhydantoin
1 ,l-Dimethyl-3- (m-hydroxyphenyl)urea
2, 3- Dimethyl indole
D,L-cis , trans -2, 2- Dimethyl -3- isobutenylcyc lop ropane-
l-carboxylic acid, ethyl ester.
2 ,5-Dimethyl-4(2)-morpholinylmethylphenol , hydro-
chloride.
N,N-Dimethyl-l-n aph thy 1 amine
N,N- Dime thy 1-p-nitrosoani line
6,6-Dimethyl-2-norpinene-2-ethanol
2,4-Dimethylphenol
N, N- Dime thy 1-p-phenylazoani line
N,N- Dime thy 1-p-phenylenediamine
HST.
EKT, PCW.
TRC.
Cmi, UPJ.
ACY, ARS.
SDH.
CIVN.
ARS.
GAF.
PD, X.
UPJ.
LIL.
LIL.
HEX.
EK.
ICI.
BJL, GAF.
HST.
ACS, ACY, DSC, DUP, SW .
EK.
CIVN.
cm.
EK.
ARS,
MLS,
RH, SW.
CLK.
ACY,
DUP,
GAF, TRC
ABB,
DUP.
GLY.
CIWJ.
DUP.
BPC.
IDC.
EK.
ACY,
RDA.
EK.
EK.
EKT.
CYCLIC INTFR'lEDIATES
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER, 1972--CoNT INUED
Manufacturers' identification codes
(according to list in table 3)
N,N- Dime thy l-m-phenylenedi amine dihydrochloride
N,N- Dime thy 1-p-phenylenedi amine dihydrochloride
N,N- Dime thy 1-p-phenylenedi amine monohydrochloride
N,N- Dime thy l-p-phenylenedi amine sulfate
1,4- Dime thy Ipiperazine
N,N-Dimethylsulfanilic acid
Dime thy 1 - 5- sulfoi soph thai ate
N,N-Dime thy 1-o-tolui dine
N, N- Dime thy 1-m-tolui dine
N,N-Dimethyl-p-toluidine
2,4-Dinitroacetani lide
2,4-Dinitroaniline
p- (2,4-Dinitroanilino)phenol
1,5 (and 1 ,8)-Dinitroanthraquinone
N,N'- (2,4-Dinitro-l ,5-anthraquinonylene)dioxamic acid--
3,3' -Dinitrobenzanilide
m-Dinitrobenzene
2,4-Dinitrobenzenesulfonic acid
2,4-Dinitrobenzenesulfonic acid, sodium salt
3,S-Dinitrobenzoic acid
3,5-Dinitrobenzoyl chloride
10, 10' -Dinitro [3,3 '-bi-7H-benz[de] anthracene] -7,7' -
dione.
Dinitrocaprylphenol
2 , 4- Din i t rocumene
l-(3,5-Dinitro-2-hydroxphenylazo)-2-naphthol
2,6-Dinitro-4-isopropylphenol
2,4-Dinitrophenol , tech
3,5-Dinitrosalicylic acid
*4,4'-Dinitrostilbene-2,2 'di sulfonic acid
2 ,4-Dinitrotoluene
*2,4(and 2 ,6)-Dinitrotoluene
3,5-Dinitro-p-toluenesulfonic acid
Dinonylphenol
Di-tert-pentylphenol
Di-tert-amylphenoxyacetyl chloride
2-(2,4-Di-tert-pentylphenoxy)butyric acid, tech
1 ,5-Diphenoxyanthraquinone
Diphenylacetoni tri le, tech
*Diphenylamine
2,8-Diphenylanthra[l,2-d:6,5-d']bisthiazole-6,12-dione-
2,5-Diphenyl-p-benzoquinone
Diphenyldecyl phosphite
2 ,2'-Diphenyl-4-dimethylamine
N,N' -Diphenylethylenedi amine
Diphenylme thane
2,5-Diphenyloxazole
4,7-Diphenyl-l ,10-phenanthroline
1, 3- Di phenyl-! ,3-propanedione
4,4 '-Dithiodiani line
2,2'-Dithiodibenzoic acid
*l,4-Di-p-toIuidinoanthraquinone
1,8-Di-p-toluidinoanthraquinone
2,5-Di-p-toluidinoterephthalic acid
p-Ditolylmercapto-2 ,5-diethoxybenzenediazonium chloridt
zinc chloride salt.
EK.
.TCC.
AAP.
EK,
RSA.
SDC.
AAP,
SDC.
GAP,
SDC.
AAP,
TRC.
TRC.
TRC.
DUP.
EK,
TRC.
EK,
NES.
SAL.
EK.
DUP,
MAY.
RH.
DUP.
TRC.
X.
AAP,
SDC.
EK,
SAL.
ACY,
CGY,
DUP,
GAP, HN, SDH,
TRC
ACS,
DUP,
RUC.
AIP,
DUP,
MOB,
UCC.
GAP.
GAP
JCC.
PAS.
EK.
EK.
VPC.
FIS
ACY
DUP,
ORO,
RUC, USR.
GAP
EK.
X.
LIL
RPC
PD.
ARA
EK.
EK.
EK.
SDC
LIL
SW.
ACS
ATL,
GAP
TRC.
ICI
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
*Divinylben2ene
Uodecylbenzene. (See Alkylbenzenes . )
Dodecylbenzyl chloride
Dodecylmethylbenzyl chloride
p-Dodecylphenol
2,2 '- (Ethanediylidenedinitrilo)diphenol
l,2-Epoxy-3-(2-biphenylyl)propane
p-EthoxybeHzaldehyde
o- E thoxyben zoic acid
p(p- (Ethoxybenzy li dene) amino] ben zonit rile
N- (p-Ethoxybenzyli dene) -p-butyl aniline
l-(4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3-inethyl-
isoquinidine (Dioxyline base).
2-Ethoxy-l-naphthoyl chloride
m-Ethoxyphenol
4-Ethoxy-o-phenylenediamine
N'- (6- Ethoxy-3-pyridazinyl) sulfanilamide
Ethyl -in- aminobenzoate methanesulfonate
3-(Ethylamino)-p-cresol
a- (N-Ethylamino)-p-toluenesulfonamide
3- (Ethylamino)-p-toluenesulfonic acid [S03H=1]
*N~ Ethyl aniline, refined
*2-(N-Ethyanilino)ethanol
[2-(N-Ethylanilino)ethyl]trimethylammonium chloride
3- (N- E thy lanilino)propionit rile
a-(N-Ethylanilino)-m-toluenesulfonic acid
a- (N-Ethylanilino)-p-toluenesulfonic acid
2-Ethylanthraquinone
*Ethylbenzene
Ethylbenzyl chloride
2- (N-Ethyl-N-S-cyanoethyl)-4-acetaminoanisole
N-Ethylcyclohexylamine
1-Ethylcytosine
3,3'-Ethylenedioxydiphenol
Ethylene glycol dibenzenesulfonate
3- Ethyl- 2- [5- (3-ethyl-2-benzothiazolinylidene) -1 ,
3-pentadienyl] -benzothiazolium iodide.
Ethyl hydrocaffeate
2- [N-Ethyl-p- [(6-methoxy-2-benzothiazolyl )azo]anilino]
ethanol .
N-Ethyl-N- (2-methylsulfonamidoethyl)-m-toluidine
N-Ethyl- 1-naph thy 1 amine
9-Ethyl-3-nitrocarbazole
a-Ethyl-3-nitrocinnamic acid
N- [2- (N-Ethyl-4-nitroso-m-toluidino)ethyl]methane-
sulfonamide.
Ethylphenylmalonic acid, diethylester
*N-Ethyl-N-phenylbenzylamine
5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP) —
1-Ethylpiperidine
6-Ethyl-l , 2,3, 4-tetrahydro- 1,1,4, 4-tetramethyl-
naphthalene .
N-Ethyl-p-toluenesulfonamide
N-Ethyl-m-toluidine
N-Ethyl-o-toluidine
2- (N-Ethyl-m-toluidino) ethanol
DOW, FG, KPP.
GAP,
EK.
NES.
ACY.
EK.
BJL.
TRC.
ACY.
EK.
DUP.
AAP.
DUP.
ACS, ACY, DUP.
DUP, EKT, TCH.
DUP.
TCH.
GAP, SDH, WJ.
ACS, TRC.
DUP.
ATR, CSD, DOW, EN.7 , FG , KPP, MCB, MON , SHC, SKC, SNT,
Snc, STY, TOC, UCC.
BPC.
SDC.
ABB, USR.
PD.
IDC.
NES.
TRC.
WAY.
DSC, DUP.
SDC.
SDW.
WAY.
BPC, HAL.
ACS, DUP, SDH.
UCC.
RIL.
GIV.
EK.
DUP.
DUP.
TCH.
CYCLIC INTERHEDIATES
TAELE 2, --Cyclic intermediates for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
{according to list in table 3)
3- (N-Ethyl-m-toluidino)propionitri le
a- (N-Ethyl-m-toluidino) -m- toluene sulfonic acid
1-Ethynyl-l-cyclohexanol
Fluorescein (3' ,6 '-Dihydroxyfluoran)
o-Fluoroben2oic acid
l-Fluoro-2,4-dinitrobenzene
d- 2- Formami do- 1 -phenyl - 1 , 3-propanedi o 1
4-Formyl-m-benzenedisulfonic acid
o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde)
Furan
Furfuryl alcohol
Fur furyl amine
N-Glycolylarsanilic acid, sodium salt
Hexabromobenzene
Hexabromobiphenyl
Hexachlorobenzene
Hexachlorocyclopentadiene
1,4 ,5,6,7,7-Hexachloro-5-norbornene-2 ,3-dicarboxylic
acid.
1 ,4,5,6,7,7-Hexachloro-5-norbomene-2 ,3-dicarbox>'lic
anhydride .
Hexadecachlorophthalocyanine copper complex
Hexafluorobenzene
1,2,3,4,5 ,6-Hexahydro-8-hydroxy-cis-6,ll-dimethyl-2,6-
methano-2-benzazocine .
Hexahydro- l-methyl-4-phenyl-lH-azepine-4-carbonitrile--
Hexamethylenimine
Hippuric acid
p-Hydrazinobenzenesulfonic acid
2-Hydrazinobenzothiazole
Hydroquinone, di (6-hydroxyethyl) ether
*Hydroquinone , tech
6-Hydroxy-p-acetophenetidide
3 ' - Hydroxy ace t ophen one
4* -Hydroxy ace tophenone
6'-Hydroxy-m-acetotoluidide
1- (p-Hydroxyanilino)-4-naphthol
p-Hydroxybenzaldehyde
p-Hydroxybenzenesulfonic acid
p-Hydroxybenzoic acid
3 '-Hydroxy- 2- (N-benzy 1-N-methyl amino) acetophen one
4-Hydroxycoumarin
2-Hydroxy-3,5-diiodobenzoic acid
3- [N- (2-Hydroxyethyl)anilino]propionitrile, acetate
3- [N-(2-Hydroxyethyl)anilino]propionitrile, benzoate
N- (B-Hydroxyethyl)-2 ,4-dihydroxybenzamide
N- fB-Hydroxyethyl)-2,5-dihydroxybenzamide
N- (6-Hydroxyethyl)-3,5-dihydroxybenzamide
3- [N- (2-Hydroxyethyl)-m-toluidino]propionitrile
3-Hydroxy-N- (2-hydroxyethyl)-2-naphthamide
N- [7-Hydroxy-8- [2-hydroxy-5- (methylsulfamoylphenyUazo]
l-naphthyl]acetamide.
6 ' -Hydroxy-5 '- [ C2-hydroxy-5-nitrophenyl) azo] -m-aceto-
toluidide.
N- [7-Hydroxy-8- [ (2-hydroxy-S-nitrophenyl) azol-l-
naphthyllacetamide.
7-Hydroxy-8- [ (4 ' - [ (p-hydroxyphenyl) azo] -3, 3' -dimethyl -
4-biphenylyl)azo]-l ,3-naphthalenedi sulfonic acid.
DUP, TCH.
GAF.
EKT.
ICC.
FIN.
EK.
PD.
GAF.
SDH.
QKO.
QKO.
MLS.
SDW.
MCH, NES.
MCH.
DVC.
MK, VEL.
HK.
VEL.
TRC.
WHC.
SDW.
IVYT.
CEL.
BPC.
GAF, STG, WJ.
FK.
CTN.
CRS, DA, EKT.
GAF.
CTN, SDH.
BJL.
TRC.
TRC.
DOW.
DOW, PRD, UPF.
HN.
SDW.
ABB.
EK.
TCH.
DUP, x.
IDC.
ARS.
IDC.
TCH.
IDC.
TRC.
TRC.
TRC.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
4-Hydroxy-4-isopropylmetanilamido
4- Hydroxymet anil amide
4-Hydroxymetanilide
3' -Hydroxy- 2- (raethy 1 amino) ace tophenone
*3-Hydroxy-2-methylcinchoninic acid
4-Hydroxy-N'-raethylmet anil amide
5-Hydroxymethyl-2-norbornene
N- (Hydroxymethyl)phthalimide
3-Hydroxy-N- (3-N-morpholinopropyl)-2-naphthajnide
3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt-
y-Hydro xy-1 , 5-naphthalenedisulfoni c acid
7-Hydroxy-l ,3-naphthalenedisulfonic acid, disodium salt-
4-Hydroxy-2-naphthalenesulfonamide
4-Hydroxy-l-naphthalenesulfonic acid
6-Hydroxy-2-naphthalenesulfonic acid
8-Hydroxy-l-naphthalenesulfonic acid
4-Hydroxy-2-naphthalenesulfonic acid, benzenesulfonate,
sodium salt.
*6-Hydroxy-2-naphthalenesulfonic acid, sodium salt
8-Hydroxy-l-naphthalenesulfonic acid, y-sulfone
3-Hydroxy-2-naphthanilide (Naphthol AS)
l-Hydroxy-2-naphthoic acid, methyl ester
3-Hydroxy-2-naphthoic acid (B.O.N.)
5-Hydroxy-2-naphthoic acid, methyl ester
3-Hydroxy-2-naphtho-o-toluidide
N- (2- Hydroxy- 1-naph thy l)acet amide
N- (7-Hydroxy- 1-naphthyl) ace t amide
N- (7-Hydroxy-l-naphthyl)benzamide
1- (2-Hydroxy- 1-naphthyl azo)-6-nitro- 2-naphtho 1-4-
sulfonic acid.
3- [ (7-Hydroxy-l-naphthyl)carbamoyl]acetanilide
4-Hydroxv-7- (p-nitrobenzamido) -2-naphthalenesulfonic
acid.
2-Hydroxy-5-nitrometanilic acid
1- (2-Hydroxy-4-nitrophenylazo)-2-naphthol
2,2'- (2-Hydroxy- 4-nitropheny limine) die thanol
2-Hydroxy-4-n-octoxybenzophenone
0- [ (p-Hydroxyphenyl) azojbenzoic acid
3- [ (4- (4-Hydroxyphenylazo)2,5-dimethoxyphenylazo) ]-
benzenesulfonic acid.
lla-Hydroxyprogesterone
2 ' - Hydr oxyp rop i ophenone
N- Hydroxys uccini mi de
N-Hydroxysuccinimide, triethylamine salt
2-Hydroxy- 4- sulfo-1-naphthalenediazonium hydroxide
inner salt.
1 -Hydroxy- 4- p-toluidinoanthraquinone
2- Imidazolidinone
2- Imidazolidinone modifications
*1 ,1 ' -Iminobis [4-aminoanthraquinone]
Ijl'-Iminobis [4-benzamidoanthraquinone]
1 ,1 '-Iminobis [5-benzamidoanthraquinone]
7,7'- Iminobis [ 4 -hydroxy-2-naphthalenesulfonic acid]
1 ,1 '-Iminobis [4-nitroanthraquinone]
*1, I'-Iminodianthraquinone (1 , 1 '-Dianthrimide)
Indole- 2, 3- di one
Indophenol, sodium salt
GAF, ICC, SDC, IRC.
TRC.
TRC.
TRC.
DUP,
TRC.
CTN.
DUP,
TRC
ARS.
ACY.
IDC.
ACY,
DUP,
ACY.
GAF.
DUP.
SNA,
VPC.
GAF.
ACY, TRC, WJ.
TRC.
ATL.
x.
PCW.
WAY.
ATL.
ACY.
GAF, TRC.
TRC.
TRC.
TRC.
GAF.
TRC.
TRC.
WAY.
ACY, CCW.
EK.
TRC.
UPJ.
uor.
BJL,
EK.
BJL.
ACY.
GAF,
ICI.
VAL.
RH.
ACY,
GAF,
TRC
ACY.
GAF,
TRC.
TRC.
ACY,
TRC.
ACY,
GAF,
TRC
TRC.
EK.
CYCLIC INTERMEDIATES
TABLE 2.— Cyclic intermediates for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER^ 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
a- lodotoluene
Isobutylbenzene
*Isocyanic acid derivatives:
Bitolylene diisocyanate CTODI)
p-Chlorophenyl isocyanate
Cyclohexylisocyanate
Dianisidine diisocyanate (DADI)
Diphenylmethane- 4,4 '-diisocyanate (MDI)
Phenylisocyanate
Polyisocyanates (complex)
Pol>inethylene pol>-phenyl isocyanate
Toluene 2, 4- diisocyanate
Toluene 2,4- and 2 ,6-diisocyanate (65/35 mixture)
♦Toluene 2,4- and 2 ,6-dii50cyanate (80/20 mixture)
p-Toluenesulfonyl isocyanate
Other
Isoni cot inonit rile
2-Isonitrosoacetanilide
Isophthalic acid (Benzene- 1 ,3-dicarboxylic acid)
Isophthalic acid, diallyl ester
Isophthalic acid, dimethyl ester
Isophthalic acid, dlphenyl ester
Isophthaloyl chloride
p- Isopropylbenzoic acid
4,4'-Isopropylidenebis [2,6-dibromophenol] (Tetrabromo-
bisphenol A) .
4,4'-Isopropylidenebis [2,6-dichlorophenol] (Tetrachloro-
bisphenol A)
5,5'-Isopropyl
*4,4 '-Isopropyl
4,4' -Isopropyl
denebis (2-hydroxy-m-xylene,a,a' -diol)-
denediphenol (Bisphenol A)
denediphenol , ethoxylated
4,4'- I sop ropy li denediphenol , propoxylated
o- Isopropylphenol
Isopropylphenols, mixed
4- I sop ropy 1-m-phenylenedi amine
I sovio Ian throne (Isodibenzanthrone)
Leuco quinizarin (1,4,9,10-Anthratetrol)
2,4-Lutidine
2,6-Lutidine
3,4-Lutidine
3,5- Luti dine
Malonani lide
Mandelonitrile
Melamine
p-Mentha-1 ,4(8)-diene
dl-p-Mentha-l,8-diene (Limonene)
p-Menth-1-ene
o-Mercaptobenzoic acid (Thiosalicylic acid)
Metanilic acid (m-Arainobenzenesulfonic acid)
N- (p-Methoxybenzylidene)-p-butyl aniline
6-Methoxymetanilic acid
4'-Methoxy-2- (p-raethox\'phenyl)acetophenone
Methoxymethyldiphenyl oxide"
N- (2-Methoxy- 1-naph thy Dacet amide
6-Methoxy-8-nitroquinoline
(p-Methoxyphenyl) acetic acid
6-Methoxy- 2- (phenyl thio)quinoline
m-Methoxyphenolisocyanate
EK.
PLC, TNA.
CIVN,
MOB.
OTC.
CIVN,
ACS,
HOB,
MOB.
MOB,
DUP,
DUP,
ACS,
CITO.
DUP,
RIL.
TRC,
ACC.
FMP.
MTR.
BJL.
DUP.
UPJ.
MOB, UPJ.
UPJ.
RUC, UPJ.
MOB.
MOB.
DUP, MOB, OMC, RUC, UGC, WYN.
MOB, UCC, X.
EK.
DOW.
DVC.
ARK.
DOW, GE, SHC, UCC.
ICI.
ICI.
TNA.
FMP, KPT.
DUP.
MAY, TRC.
EKT, HSH, TRC.
KPT, RIL.
RIL.
UCC.
RIL.
PCW.
KF.
ACY, PPC.
GIV.
ARZ, GIV, HN, NCI.
GIV.
AMB, LIL.
ACY, DUP, TRC.
EK.
GAF.
CTN.
BPC.
TRC.
PD.
UOP.
EK.
EK, OTC.
SYNTHETIC ORGANIC CHEf^ICALS, 197.2
TABLE 2,— Cyclic intermediates for which U.S, production or sales were reported;
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
4 ' -Me thoxNT) rop i ophenone
1- (Methyl ami no) anthraquinone
1- (Methylamiiio)-4-p-toluidinoanthraquinone
N-Me thy 1 aniline
2- (N-Methylanilino)ethanol
3-(N-Methylanilino)propionitrile
5-Methyl-o-anisidine [NH2=1]
m-Methylanisole
2-Methyl anthraquinone
3-Methylbenzo[f]quinoline
2-Methylbenzothiazole
N-Methylbenzyl amine
Methylbenzyl ether
5-(l-Methylbutyl)barbituric acid
N-Methyl-N-carboxyanthranilic anhydride
3-Methylcholanthrene
Methylcyclohexane
2-Methylcyclohexanone
l-Methyl-4-cyclohexene-l,2-dicarboxylic anhydride
Methyl eye lopentadiene
N-Methyldicyclohexylamine
4-Methyl-a,a-diphenyl-l-piperazineethanol, dihydro-
chloride.
N-Me thy leneani line
4 ,4'-Methylenebi5[2-chloroaniline]
4 ,4'-Methylenebis [N,N- diethyl aniline]
4,4'-Methylenebis[N,N-dimethylaniline] (Methane base)
4,4'-Methylenebis(3-hydroxy-2-naphthoic acid) disodium
salt.
2,2'-Methylenebis(4-methyl-6-nonyl-p-cresol)
*4, 4 '-Methylenedi aniline
S,5'-Methylenedisalicylic acid
Methy Ihydroquinone
2-Methyl indole
2 -Methyl indole- 3- carboxaldehyde
6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic
acid.
5-Methyl-4-nitro-o-anisidine
4-Methyl-2-nitroanisole
2-Methyl -5-nitroimidazole
N-Me thy 1-N-nitroso-p-toluenesulfonamide
2-Methyl-5-norbomene-2,3-dicarboxylic anhydride
Methylnorbomene-2,3-dicarboxylic anhydride, isomers
m- (3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonaiiiide —
„. (3.Methyl-S-oxo-2-pyrazolin-l-yl)benzenesulfonic acid-
*p_(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid-
3- (3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalene-
disulfonic acid.
6-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l ,3-naphthalene-
disulfonic acid.
4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic
acid 1S03H=1].
2-Methyl-5-phenylbenzoxazole
1-Methyl-l-phenylhydrazine
l-Methyl-4-phenylisonipecotic acid
5-Methyl-3-phenyl-4-isoxazolecarboxylic acid
5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydro-
chloride.
*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z)
Manufacturers' identification codes
(according to list in table 3)
LIL.
AAP,
ACY,
ICI
BDO,
GAP,
ICI
ACY,
DUP.
TCIL
DUP.
SW.
GIV.
ACY.
ACY.
FMT.
MLS,
SDW.
UCC.
LIL.
UCC.
EN .J.
PCW.
DUP.
ACY,
TRC.
ACY,
DUP,
SDH.
EK,
PD.
ACY.
ACS
DOW,
MOB,
RUC
HN.
ARS
EKT.
TRC
GAP
DUP
RDA.
ALD,
EK.
VEL.
ACS.
VPC.
TRC.
ACY,
GAP,
TRC.
TRC.
TRC.
CMG,
TRC.
SDW.
ARS.
ARS.
ACY, DUP, GAP, SDH. VPC.
CYCLIC INTERMEDIATES
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported.
Identified by manufacturer, 1972--Continued
4-Methyl-l-piperazine acetic acid, methyl ester
3-Methyl-2-pyrazolin-S-one
1-Methylpyrrole
*a-Methylstyrene
ar-Methylstyrene (Vinyl toluene)
2-(Methyl5ulfonyl)-4-nitroaniline
4- [Methyl thio)-m-cresol
3-Methylthiophene
3-Methyl- 1- (thiosulfophenyl)-2-pyrazolin-5-one , sodium
salt.
3-Methyl -6 -r)-toluidino-7H-diben2[f,ij ]isoquinoline-
2,7('3H)-dione.
3-Methyl-l-n-tolyl-2-pyrazolin-5-one
16-A-Methyltriene carbethoxylate
Naphthalene, solidifying at 79° C. or above (refined
flake) (from domestic canide) .
1 ,4-Naphthalenediol
1-Naphthalenesulfonic acid
2-Naphthalenesulfonic acid
1-Naphthalenesulfonic acid, sodium salt
2-Naphthalenesulfonic acid, sodium salt
2-Naphthalenesulfonyl chloride
1 ,4,5,8-Naphthalenetetracarboxylic acid
Naphthalimide
1-Naphthol (a-Naphthol)
2-Naphthol, tech. (6-Naphthol) '
p-Naphtholbenzein
l-Naphthol-3,6-disulfonic acid, monosodium salt
l-Naphthol-2-sulfonic acid, potassium salt
1 ,2- Naphthoquinone
l,2-Naphthoquinone-4-sulfonic acid, sodium salt
Naphth[l ,2-d] [1,2 ,3]oxadiazole-S-sulfonic acid
2-(2H-Naphth[l,2-d]triazol-2-yl)-4-(l,l,3,3-tetramethyl-
butyl)phenol.
1 - Naph thy 1 acetate
1-Naphthyl amine (rt-Naph thy 1 amine)
2- (l-Naphthylamino)ethanol
p- (2-Naphthylamino)phenol (N- (p-Hyd^oxyphenyl)-2-
naphthylamine) .
N- (1- Naph thy l)ethylenedi amine dihydrochloride
(2-Naphthyloxy) acetic acid
(2-Naphthyloxy) acetic acid, sodium salt
(2-Naph thy Ithio) acetic acid
Nicotinonitrile (3-Cyanopyridine)
4'-Nitroacetanilide
2'-Nitro-Ti-acetanisiHirie
4'-Nitro-o-acetanisidide
2-Nitro-p-acetophenetidide
3' -Nitroacetophenone
m-Nitro aniline
o-Nitroaniline
DUP.
DUP.
.\CP, CLK, DOW, HPC, SKO, USS.
DOIV.
TRC.
CRZ.
SDW.
SDC.
ICI.
HST.
sen.
KPT, IVTC.
EK.
TRC.
ACY, EK, FIN, m.
TRC
ACY.
DUP.
TRC
ACS.
UCC
ACY.
EK.
HN.
EK.
EK.
EK.
DUP.
TCU.
SDC.
RSA.
EK.
BKL.
ACY.
NEP, RIL.
GAP, TRC.
DUP.
DUP.
AAP.
SDH.
X.
MON.
See footnotes at end of table.
552-743 O - 74 - 4
SYFITHETIC ORGANIC CIlEniCALS. 1972
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED EY MANUFACTURER, 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 5)
P-Nitroaniline
2-Nitro-p-anisidine [NHj=l]
4-Nitro-o-anisidine [NH2=1]
5-Nitro-o-anisidine [NH2=1]
o-Nitroanisole
p-Nitroanisole
5-Nitroanthranilic acid
1-Nitroanthraquinone
2- (4-Nitro-2-anthraquinonyl)anthra[2,3-d]-oxazole-5 ,10-
dione.
m-Nitrobenzaldehyde
p-Nitrobenzaraide
3'-Nitrobenzanilide
♦Nitrobenzene
p-Nitrobenzenediazonium tetraf luoroborate
m-Nitrobenzenesulfonic acid
m-Nitrobenzenesulfonic acid, sodium salt
p-Nitrobenzenesulfonyl chloride
5-Nitro-2-benzimidazolinone
m-Nitrobenzoic acid
0 - Ni troben zoi c acid
p-Nitrobenzoic acid
m-Nitrobenzoic acid, sodium salt
o-Nitrobenzoic acid, sodium salt
2- (m-Nitrobenzoyl)-o-acetanisidide
p-Ni troben zoyl azide
m-Nitrobenzoyl chloride
p-Nitrobenzoyl chloride
p-Nitrobenzyl chloro formate
4- (p-Nitrobenzyl) pyridine
4 '-Nitro-4-biphenylcarboxylic acid
4-Nitro-sec-butylbenzene
2-Nitro-p-cresol
2-Nitro-p-cymene
Nitrodiphenylamine
5-Nitro-2-furanmethanediol , di acetate
5-Nitroisophthalic acid
1-Nitronaphthalene
3-Nitro-l ,5-naphthalenedisulfonic acid
7 (and 8) -Nitronaphth [ 1 ,2-d] [1 ,2 , 3]oxadiazole- 5 -sulfonic
acid-
p-Nitrophenethyl alcohol
o-Nitrophenol
p-Nitrophenol
p-Nitrophenol, sodium salt
4 '- (p-Nitrophenyl)acetophenone
4- [ (p-Nitrophenyl)azo]-o-anisidine
4-Nitro-o-phenylenediamine
2- (o-Nitrophenylazo)-p-cresol (nH=l)
(p-Nitrophenyl) hydrazine
2,2'-[(m-NitrophenylH''iino]diethanol
p-Nitrophenyl isocyanate
2-(p-Nitrophenyl)-2H-naphthol[l,2-d]triazole-6,8-
disulfonic acid.
l-(m-Nitropheny 1-5-0X0- 2-pyTazoline-3-carboxylic
acid.
3-Nitrophthalic acid
AAP,
HON.
DUP.
DUP.
BUG.
DUP,
X.
DUP.
TRC.
ACY,
TRC.
GAP.
SDll.
IGG.
MP .
AGS.
ACY ,
niip.
FST
EK.
ACY,
DUP.
GAP,
MGN ,
MRA,
SAL
EK.
DUP.
SAL,
SDU,
WAY.
SAL,
WAY.
DUP.
SAL,
WAY .
WAY.
GAP.
EK.
DUP,
TRC.
WAY.
SW.
EK.
ACY,
HON.
NOR.
PIS,
MAL.
DUP.
TRC.
ACS,
GAP, TRC
PCW.
MON.
DUP, MON, SDC, UOP.
DUP.
DUP, PIS.
AAP.
DUP, PMT.
TRC.
EK.
DUP.
CYCLIC INTERMEDIATES
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972— CoNT INUED
3-Nitrophthalic anhydride
4-Nitrophthalimide
--Nitroresorcinol
5- Nitrosalicyl aldehyde
l-Nitroso-2-naphthol
p-Nitrosophenol
4-Nitro5tilbene
B-Nitrostyrene
4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)-
2,2'-stilbenedisulfonic acid.
m-Nitrotoluene
o-Nitrotoluene
p-Nitrotoluene
Nitrotoluene mixtures
p-Nitrotoluenesulfonic acid
*5-Nitro-o-toluenesulfonic acid [SO^Hsl]
3-Nitro-p-toluenesulfonic acid [S03H=1]
2-Nitro-iii-toluic acid
3-Nitro-p-toluic acid, methyl ester
*5-Nitro-o-toIuidine [NH2=1]-
2-Nitro-p-toluidine [NH2=1]
S-Nitro-2-p-toluidinobenzenesulfonic acid
16-Nitroviolanthrone
4- Nitrc-m- xylene
*Nonylphenol
5-Norbomene-2 ,3-dicarboxvlic anhydride
Oxalacetic acid, diethylester, Cp-sulfophenyl) -
hydrazone .
Oxanilide
*1- [ (7- Oxo-7H-benz[de] anthracene- 3-yl) amino] ant hra-
quinone .
l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]-
dianthraquinone .
S- 0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic acid
(Pyrazolone T) .
5-0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic acid,
ethyl ester.
4,4 '-Oxydi aniline
Penicillin G, N-ethylpiperidine salt
Pent achloropyri dine
1,1,3,3,5-Pentamethylindan
p-Pentyl aniline
p-Pentyloxybenzoyl chloride
o-Pentylphenol to-Amylphenol)
p-tert-Pentylphenol
3,4,9,10-Penylenetetracarboxylic-3,4:9,10-diimide
Phenethylamine
a-Phenethylamine
Phenethylamine sulfate
o-Phenethylbenzoic acid
m-Phenetidine
o-Phenetidine
p-Phenetidine
•Phenol :
'Natural :
*From coal tar:^
39°C., m.p
82%- 84%
All other
*From petroleum
See footnotes at end of table.
Manufacturers' identification codes
(according to list in table 3)
EK.
EK.
EK.
ACY, SDC.
GAP.
cm.
TRC.
DIJP
FST.
DUP
FST.
DUP,
EST.
DIIP,
FST,
HN.
CGY.
ACS,
ACY.
DUP.
GAF
SDH, TRC
DIG.
TRC.
SAL.
SDH.
BUG,
DUP,
PCW,
SDH
DIIP,
GAF,
SW.
TRC.
ICI.
DUP.
GAF.
JCC,
MON,
RH,
UCC.
VRL.
TRC.
EK.
ACY,
DUP,
GAF,
MAY,
TRC.
MAY,
TRC.
STG.
STG.
DOW.
GIV.
EK.
EK.
PAS.
PAS.
ACS.
MLS.
MLS.
MLS.
LIL.
EK.
MON.
MON.
KPT.
AGP.
ACP, KPT.
MLR, NPC, PRD.
SYNTHETIC ORGANIC CHEI^ICALS> 1972
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported^
IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
*Synthetic:
By caustic fusion: U.S.P
From chlorobenzene by liquid-pbase hydrolysis:
U.S.P
*Froin curaene by oxidation: U.S.P
Other
Phenolsulfonaphthalein, sodium salt
Phenolsulfonic acid, lithium salt
Phenoxyacetic acid, sodium salt
2- Phen oxyprop i ony 1 chloride
Phenylacetic acid (a-Toluic acid)
Phenylacetic acid, ethyl ester, tech
Phenylacetic acid, methyl ester
Phenylacetic acid, potassium salt
Phenylacetic acid, sodium salt
Phenylacetonitrile (a-Tolunitrile)
4'-Phenylacet ophenone
Pheny 1 ace ty 1 chloride
N-Phenylanthranilic acid
Pheny larsine oxide
p-Phenylazoaniline (C. 1. Solvent Yellow 1) and hydro-
chloride .
4- CPhenylazoJdiphenyl amine
4- (Pheny lazo)-l-naph thy lamine
5- (Pheny lazo) salicylic acid
1- Pheny lb iguanide hydrochloride
4-Phenyl-3-buten-2-one
Phenyl chloro formate
a-Phenyl-o-cresol
1- Pheny Icyclopentanecarboxylic acid
m- Pheny lenedi amine
o- Pheny lenedi amine
p- Pheny lenedi amine
p- Pheny lenedi amine dihydrochloride
d- Phenylephrine
dl- Phenylephrine
1- Pheny lethanol
Phenyl ether (Diphenyl oxide)
d(-) Pheny Iglycine
dl- Pheny Iglycine (racemic)
N- Pheny Iglycine
Pheny Iglycol ethers
df-)Phenylglycyl chloride hydrochloride
5-Phenylhydantoin
Phenyl hydrazine hydrochloride
Pheny l-l-hydroxy-2-naphthoate
2,2 '- [ (Phenyl )imino] die thanol (N- Pheny Idiethanol amine )-
2,2'-[(Phenyl)imino]diethanol, diacetate ester
3,3'- [ (Pheny l)imi no] dipropionitrile
Phenylmalonic acid, diethyl ester
3- Phenyl -5-methyli50xazole-4-carbonyl chloride
Pheny 1-a-naph thy lamine
o- Pheny Iphenol
p-Phenylphenol
o- Pheny Iphenol , chlorinated
o-Phenylphenol, sodium salt
N- Pheny 1-p-pheny lenedi amine
Pheny Iphosphinic acid
Pheny Iphosphonothioic di chloride
•lAL,
RCI.
now.
AGP,
CLK,
HON,
SHC
KLM.
HK.
SAL.
BPC.
ARS.
BPC,
GIV,
MAL.
BPC,
HAL.
BPC.
BPC,
OPC.
npc.
BPC,
SDW,
OPC,
UOP
DUP.
B.JL.
SDW.
EK.
ACS,
ACY,
nup.
TRC.
SDC.
SDW.
EK.
RBC.
SK.
ACY, DUP.
DUP, SW, TRC.
ACY, DUP, SDC.
EK.
SDW.
SDW.
UCC.
DOW .
BKL, KF, QIC, UPJ.
KF.
EK.
ncc.
KF, OTC, x.
ABB.
EK.
EK.
TCH.
SDC.
DUP.
BPC.
AR.S.
UCC.
DOW, RCI.
DOW.
DOW.
DOW.
USR.
SFA.
CYCLIC INTERflEDIATES
TABLE 2, --Cyclic intermediates for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972--CONTI NUED
Manufacturers* identification codes
(according to list in table 3)
Pheny Iphosphorous di ch lori de
*I-Phenyl-1 ,2-propanedione , 2-oxime
Pheny 1-2-prop an one
l-Phenyl-5-pyrazolone-3-carboxylic acid, ethyl estei-
dl- Phenyl succinic acid
Phenyl sulfide
Pheny 1 sul f one
1- Phenyl -2- thiourea
Pheny lundecanoic acid
Phloroglucinol
l(2H]-Phthala2inone
Phthalaldehyde
Phthalic acid
Phthalic acid, diallyl ester
*Phthalic anhydride
Phthalide
Phthalimide
Phthalimide, potassium salt
[Phthalocyaninato(2-) ] copper
Phthalocyanine, copper complex, di-(and tri-)chloro-
methyl .
Phthaloyl chloride (Phthalyl chloride)
*Picolines : ^
2-Picoline (a-Picoline)
3-Picoline (8-Picoline)
4- Pi CO line CY-Picoline)
Pi CO line (3,4-mixture)
Picolinonitrile (2-Cyanopyridine)
3- Pi CO lyl amine
Picric acid (Trinitrophenol)
2,5-Piperazinedione
*Piperidine
3-Piperidinopropiophenone hydrochloride
Polyethylbenzene
Poly-m-phenoxylene
Potassium eye lohexanebuty rate
Primuline base
Primulinesulfonic acid
'Propiophenone
8 , 16 - Pyranthrenedi one
Pyridine, refined:^
2" P\'ridine
Other grades
Pyridine hydrochloride
3-Pyridinemethanol
2(lH)-Pyridone
2-Pyrimidinol
2(lH)-Pyrimidinone
2- Pyrrol idinone
Quinaldine
SFA.
NEP,
ORT.
NES.
EK.
EK.
EK.
EK.
FMP.
AGP,
ACS,
DUP,
EK.
GAF.
TRC.
ENJ, KPT, MON, PTO, RCl, SOC , STP, UCC, USS, WYN.
FMT.
SW.
KPT,
NEP,
RIL, UCC
NEP,
RIL.
RIL,
UCC.
KPT.
NEP.
RIL.
SDC.
EK.
ABB,
DUP,
RIL.
ACY,
SDW.
UCC.
EK.
EK.
DUP.
ATL.
ORT,
PD,
UCC, UOP.
ICI,
TRC
KPT,
NEP
RIL.
KPT,
NEP
EK.
RIL.
FMT.
COY.
VAL.
GAF.
ACS,
ACY
See footnotes at end of table.
SYNTilETIC ORGANIC CHEMICALS. 197^
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
Quinoline ;
1° and 2° Quinoline
Quinoline (synthetic)
Other grades
2,4-Quinolinediol
Quinophthalone (Quinoline yellow base)
Resorcinol , tech'
Resorcinol, raonoacetate (non-medicinal grade)'
S-Resorcylic acid
*Salicyl aldehyde
Salicyl aldehyde oxime
*Salicylic acid, tech
Salicylic acid, airanonium chromium complex
Salicylic -acid, sodium chromium complex
*Styrene, all grades
5 - Sul f amoy lanthranilic acid
Sulfanilamide, tech
Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt-
4-Sulfoanthranilic acid
5-Sulfoisophthalic acid, 1,3-dimethyl ester, sodium
salt.
5-Sulfoisophthalic acid, lithium salt
5-Sulfoisophthalic acid, sodium salt
2,4' and 4 ,4' -Sulfonyldiphenol
4,4'-Sulfonyldiphenol (4,4'-Dihydroxydiphenylsulfone)--
4-Sulfophthalic acid ■---■_---■-
*Tereph thalic acid
*Terephthalic acid, dimethyl ester
Terephthalic acid, diphenyl ester
Terephthaloyldiacetic acid, diethyl ester
Terpheny 1 (Pheny lb ipheny 1)
3,3' ,4,4 '-Tetraaminobenzophenone
3,3' ,4,4'-Tetraaminobiphenyl
[4, 4', 4'', 4'' '-Tetraaminophthalocyaninato(21 ] copper
3' ,3' ' ,5'5' '-Tetrabromophenolphthalein, ethyl ester
Tetrabromoph thalic anhydride
1 ,4,5,8-Tetrachloroanthraquinone
1 ,2,4,S-Tetrachlorobenzene
1,2,4 ,5-Tetrachloro-3-nitrobenzene
Tetrachloroph thalic anhydride
3,3' ,4' ,5-Tetrachlorosalicylanilide
Tetrachloroviolanthrone
Tetrahydrofuran
Tetrahydrofurfuryl methacrylate
*1 ,4 ,5 ,8-Tetrahydroxyanthraquinone, leuco derivative
1 ,4 ,5,8-Tetrakis(l-anthraquinonylamino)anthraquinone
(Pentanthrimide) .
N,N,3,5-Tetramethylaniline
1 ,2,4,5-Tetramethylbenzene (Durene)
N,N,N',N'-Tet rame thylbenzidine
p-(l,l,3,3-Tetramethylbutyl)phenol
N,N,N' ,N'-Tetraraethyl-p-phenylenediamine dihydro-
chloride.
[4, 4', 4'', 4'' '-Tetranitrophthalocyaninato(2) ] copper
KPT.
EK.
KPT.
PCW.
ACS.
KPT,
UPF
AAP.
KPT,
UPF
DOW ,
MTR
RDA.
EK.
DOW ,
HN,
HON, SDU.
TRC.
TRC.
ACC,
CSD
DOW, ELP, FG, GOC, KPP, MCB, MON, SHC , SKC
SNT, UCC.
TRC.
SAL.
ACS,
ACY,
DUP.
CMC,
TRC.
PCW.
PCW.
PCW.
UPF.
HON,
UPF.
ClfN,
HSC.
ACC,
DUP,
EKT, SM.
ACC,
DUP,
EKT, UPC.
BJL.
PCW.
MON.
BJL.
UPJ.
.SDC.
EK.
MCH.
DUP,
GAP.
DOW,
UK.
SDH.
MON.
EK.
GAP.
DUP,
QKO.
SAR.
ACS,
GAP,
HN, TRC.
GAP.
»
GAP, PRO, Rll, SCN.
I
CYCLIC INTERMEDIATES
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONT INUED
3,3'-Thiobis [7H-benz[de] anthracen-7-one]
2,2'-Thiobis [S-nitrobenzenesulfonic acid]
4,4'-Thiodianiline
*6,6'-Thiodinietanilic acid
2-Thiophene acetic acid
2-Thiopheneacetonitrile
2-Thiophenecarboxaldehyde
Thiophenol
sym- Thymol
*Toluene-2,4-diamine (4-m-Tolylenedi amine)
Toluene- 2, 4- di sulfonic acid
p-Toluenesulfinic acid, sodium salt
o-Toluenesulfonamide
p-Toluenesulfonamide
o(and p) -Toluenesulfonic acid
p- Toluenes ulfonic acid
p-Toluenesulfonic acid-2-chloroethyl ester
p-Toluenesulfonic acid, methyl ester
p-Toluenesulfonic acid, monohydrate
p-Toluenesulfonyl chloride
a-Toluenesulfonyl fluoride
m-Toluic acid
o-Toluic acid
p-Toluic acid
m-Toluidine
o-Toluidine
p-Toluidine
o-Toluidine hydrochloride
p-Toluidine hydrochloride
To lui dines, mixed
2-o-Toluidinoethanol
m-Toluidinoraethanesulfonic acid
o- To lui dinome thanes ulfonic acid
0- (p-Toluoyl) ben zoic acid
N-(p-Tolylazo)sarcosine
*4-(o-Tolylazo)-o-toluidine (C. I. Solvent Yellow 3) •
4- [o-Tolylazo)-o-toluidine hydrochloride
1-p-Tolyldodecane
2,2'- (m-Tolyliraino)diethanol
2,2'-(m-Tolylimino)diethanol, diacetate ester
o-Tolylisocyanate
p-Tolylisocyanate
p-Tolylmercuric chloride
Tolyltriazole
N,N,N-Tribenzyl amine
1,2, 3 (and 1 ,2 ,4) -Trichlorobenzene
*1 ,2, 4 -Trichlorobenzene
N,2,6-Trichloro-p-benzoquinoneiraine
1 ,1 ,l-Trichloro-2 , 2- diphenyl ethane
Trichloromel amine
l,2,4-Trichloro-5-nitrobenzene
Trichlorophenylsilane
Trifluoropropylmethylsiloxane
a,a,a,-Trichlorotoluene (Benzotri chloride)
a,2,4-Trichlorotoluene
2,4,6-Trichloro-s-triazine (Cyanuric chloride)
Manufacturers '
(according
identification codes
:o list in table 3)
HAY,
GAF.
ACY.
ACS,
BPC.
BPC.
ATL, GAF, LIL.
KPT.
ACY,
SFA
GIV
ACS
GAF.
EK, NES,
flON.
MON.
MON, NES,
TEN, HON,
GAF.
ICI.
NES.
MON .
EK.
BPC.
BPC.
BPC.
DUP.
DUP, FST.
DUP.
.AAP, ACY.
EK.
DUP.
TCH.
VPC.
GAF, TRC,
ACY, DUP.
BUC, GAF.
ACY, ALL, DUP, GAF,
GAF.
X.
EKT, TCU.
SDC.
EK.
EK.
EK.
SN.
MLS.
PPG.
DOW, DVC, HK, SVT.
EK.
aVN.
IVTH.
ALL.
DCC, UCC.
DCC.
HK, VEL.
HN.
CGY, NIL.
DUP. OMC, RUC, UCC.
UPF.
UPF.
VPC.
SYflTHETIC 0RG'\:JIC CHE'IICALS, P7?
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONT INUED
Manufacturers' identification codes
(according to list in table 3)
1,3,5-Triethylbenzene
a,a,c«-Trifluorotoluene
1,2,4-Trihydroxyanthraquinone
4,5,7-Trihydroxyisoflavone
Trimellitic anhydride, acid chloride
1 ,2,3-Trimethylbenzene (Hemimellitene)
1,2,4-Trimethylbenzene (Pseudocumene)
1,3,5-Triinethylbenzene (Mesitylene)
2,3,3-Trimethyl-3H-indole
♦1 ,3,3-Trimethyl-A^ ,a-indolineacetaldehyde
*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)--
Trimethylphenyl ammonium chloride
2,4,6-Trimethylpyridine
l-(Trimethyls'ilylUmidazole
2,4,6-Trinitrobenzenesulfonic acid
2,4,7-Trinitrofluoren-9-one
Triphenyl amine
Triphenylme thane
Triphenylmethanol
a, a' ,a' ' -Tris (dime thy 1 amino )mesitol
Tri5(2-methyl-l-aziridinyl)phosphine oxide
Tris(l ,10-phenanthroline)iron(in sulfate
*7,7' -Ureylenebis [4-hydroxy-2-naphthalenesulfonic acid]
(J Acid Urea) .
Verat raldehyde (3,4- Dimethoxyben zal dehyde )
p-Vinylbenzenesulfonic acid, sodium salt
Vinyl eye lohexane
2-Vinylcyclohexene
5-Vinyl-2-picoline (M\'T)
2-Vinylpyridine
4-Vinylpyridine
Vinyl toluene
*Viol an throne (Dibenzanthrone)
Xanthene-9-carboxylic acid
m~ Xylene
*o- Xylene
*p- Xylene
m-Xylenesulfonic acid
Xylenol crystals
2, 6 - Xylene I , synthetic
Xylenols :
Low b.p
Medium b.p
Xylidines :
2,4-Xylidine
2,6-Xylidine
Original mixture
4- (2,4-Xylylazo)-o-toluidine
4-(2,5-Xylylazo)-o-toluidine
4-(2,4-Xylylazo)-2,5-xylidine
4- (Xylylazo) xylidines, mixed
All other cyclic intermediates
DUP.
HK.
GAP.
EK.
ARS.
SNT.
SNT.
SNT.
GAP.
ACS,
DUP,
X.
KPT.
EK.
EK.
EK, 1
EK.
EK.
EK.
RH.
ARS,
EK.
ATL,
ATL, DUP, GAP, TRC, VPC.
GAP, TRC, VPC.
ICC.
CTIG, GAP, TRC, VPC.
GIV, SLV.
DUP.
BFG.
UCC.
PLC.
MAY, RIL.
RIL.
FG.
ACS, ACY, DUP, GAF, ICI, MAY, SDC, TRC.
HAL.
ATR, SNT.
ATR, CCP, CPI, CSD, CSO, ENJ, MON, PPR, SHC, SHO, SNT,
snc, TOC.
ACC, ATR, CSO, ENJ, HCR, PPR, SHC, SHO, SNT, SOC, SOG,
TOC.
NES.
NES.
GE, KPT.
NPC.
NPC.
DUP.
DUP.
DUP.
ACS.
ACY.
ACS.
GAF.
'^AP, ABB, ALL, ALD, ARS, ATL, B,1L, BKL, BPC, CMC, CTN ,
DUP, EK, FMP, GAF, HEX, .ICC, KF , LIL, MRK, PCW, PD,
PRD, RH, SW, TCH, TKL, UCC, UOP, WYT, x, x, x, x, ".
See report on Medicinal Chemicals for data on medicinal grade of this item.
Does not include manufacturers' identification codes for producers that renort to the Division of Fossil Fuels,
U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers
in the United States in 1972, Nov. 2?, 1973.
CYCLIC IITERflEDIATES
TABLE 3.— Cyclic intermediates: Directory of manufacturers, 1972
ALPHABbTICAL UIRECTURY BY CUCIE
[Names ot manufacturers that reported production or sales of cyclic intermediates to the U.S. Tariff Commission for
1972 are listed below in the order of their identification codes as used in table 2]
Loae
Name of company
Code
Name of company
MP
American Aniline Products, Inc.
FG
Foster Grant Co. , Inc.
ABB
Abbott Laboratories
FIN
Fine Organics, Inc.
ACC
Amoco Chemical Corp.
FIS
Fisher Chemical Co., Inc.
Allied Chemical Corp. :
FMP
FMC Corp., Industrial Chemical Div.
ACF
Plastics Division
Business Croup
ACS
Specialty Chemicals Division
fmt
Fairmount Chemical Co., Inc.
ACY
American Cyanamid Co.
fst
First Chemical Corp.
AlP
Air Products f, Chemicals, Inc.
ALD
Aldrich Chemical Co., Inc.
GAF
GAF Corp., Chemical Division
ALL
Alliance Chemical, Inc.
GE
General Electric Co.
AMB
American Bio-Synthetics Corp.
GIV
Givaudan Corp.
ARA
Arapahoe Chemical Division of Syntex Corp.
GLY
Glyco Chemicals, Inc.
AKK
Armstrong Cork Co.
GOC
Gulf Oil Corp., Gulf Oil Lo. Chemical Co.- U
S.
ARS
Arsynco, Inc.
GRS
Champlin Petroleum Co.
ARZ
Arizona Chemical Co.
GYR
Goodyear Tire i, Rubber Co.
ASH
Ashland Oil, Inc.
ASL
Ansul Chemical Co.
HCR
Hercor Chemical Corp.
ATL
Atlantic Chemical Corp.
HEX
Hexagon Laboratories, Inc.
AIR
Atlantic Richfield Co., ARCO Chemical Co. Div.
HK
HN
Hooker Chemical Corp.
Tenneco Chemicals, Inc.
EDO
Benzenoid Organlcs, Inc.
HPC
Hercules, Inc.
BFG
B.F, Goodrich Co., B.F. Goodrich Chemical Co.
HSC
Chemetron Corp., Pigments Division
Div.
HSH
Harshaw Chemical (_o.. Division of Kewanee
.^tl
Atlantic Richfield Co., ARCO Chemical Co. Div.
hst
Oil Co.
American Hoechst Corp.
BLlO
Benzenoid Organics, Inc.
BJL
Burdick 5 Jackson Laboratories, Inc.
ICC
Inmont Corp.
BM
Millmaster Onyx Corp., Millmaster Chemical
ICI
ICI America, Inc. 6 Specialty Chemicals Div.
Division, Berkeley Chemical Dept.
luc
Industrial Dyestuff Co.
BPC
Stauffer Chemical Co., Specialty-Chemical Div.,
Benzol Products Dept.
JCC
Jefferson Chemical Co., Inc.
BRP
BP Oil Corp.
BUC
Blackman-Uhler Chemical Co.
KF
KLM
Kay-Fries Chemicals, Inc.
Kalana Chemical Co.
CCP
Crown Central Petroleum Corp.
KPP
iJinclair-Koppers Co.
CCW
Cincinnati Milacron Chemicals, Inc.
KPi
Koppers Co., Inc., Organic Materials Division
CEL
Celanese Corp., Celanese Chemical Co.
CGY
Ciba-Geigy Corp.
LAK
Lakeway Chemicals, Inc.
CHL
Chemol, Inc.
LIL
Ell Lilly 1, Co. S Puerto Rico
CHP
C. H. Patrick Co., Inc.
CLK
Clark Chemical Corp.
MAL
Mallinckrodt Chemical Works
CMC
Nyanza, Inc.
MAY
Otto B. May, Inc.
CNP
Nipro, Inc.
MCB
Borg-Warner Corp., Marbon Chemical Division
CO
Continental Oil Co.
MCH
Michigan Chemical Corp.
CPI
Commonwealth Petrochemicals, Inc.
MER
Merichem Co.
CRS
Carus Corp., Carus Chemical Co.
MET
M and T Chemicals, Inc.
CRZ
Crown iellerbach Corp., Chemical Products Div.
MLS
Miles Laboratories, Inc., Marschall Division
CSD
Cosden Oil f, Chemical Co.
MNR
Monroe Chemical Co.
CSO
Cities Service Oil Co.
MOB
Mobay Chemical to.
CSP
Coastal States Petrochemical Co.
MOC
Marathon Oil Co., Texas Refining Division
ctn
Chemetron Corp., Organic Chemical Division
MCN
Monsanto Co.
CWN
Upjohn Co., Fine Chemical Division
MKA
MRK
Crown-Metro, Inc.
Merck 6 Co. , Inc.
DA
Diamond Shamrock Corp.
MRT
Morton Chemical Co. Div. ot Morton-Norwich
DBC
Dow Badische Co.
Products, Inc.
DCC
Dow Corning Corp.
MTO
Montrose Chemical Co.
DOW
Dow Chemical Co.
MTR
Sobin Chemicals, Inc., Montrose Chemical Division
DSC
Dye Specialties, Inc.
DUP
E.I. duPont de Nemours 6 Co. , Inc.
NCI
Union Camp Corp., Chemicals Division
DVC
Dover Chemical Corp.
NtP
NES
Nepera Chemical Co., Inc.
Nease Chemical Co., Inc.
EK
Eastman Kodak Co. :
NEV
Neville Chemical Co.
EKT
Tennessee Eastman Co. Division
NIL
Nilok Chemicals, Inc.
ELF
El Paso Products Co.
NOR
Norwich Pharmacal Co.
ENJ
Exxon Chemical Co. U.S.A.
NPC
Northwest Petrochemical Corp.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3.— Cyclic intermediates; Directory of Manufacturers, 1972— Continued
Code
Name of company
Code
Name of company
OMC
Olin Corp.
SKO
Skelly Oil Co.
UPC
Urbis Products Corp.
SLV
Sterwm Chemicals, Inc.
URO
Chevron Chemical Co.
SM
Mobil Chemical Co.
ORT
Roehr Chemicals, Inc.
SNA
Sun Chemical Corp.
ore
Story Chemical Corp., Ott Div.
SNT
Suntide Refining Co.
SOC
Standard uil Co. of California, Chevron
PAS
Pennwalt Chemicals Corp.
Chemical Co.
PAT
Morton Chemical Co. Div. of Morton-Norwich
SOG
Charter International uil Co.
Products, Inc.
stg
Stange Co.
PCK
Princeton Chemical Research, Inc.
stp
Stepan Chemical Co.
PCW
Pfister Chemical, Inc.
STY
Styrochem Corp.
PD
Parke, Davis 5 Co.
SVl
Solvent Chemical Co., Inc.
PFZ
Pfizer, Inc.
SW
Sherwin-Williams Co.
PIT
Pitt-Consol Chemical Co.
SWC
Shell fi Commonwealth Chemicals, Inc.
PLC
Phillips Petroleum Co.
PPC
Premier Petrochemical Co.
TCH
Emery Industries, Inc., Trylon Chemical Div.
PPG
PPG Industries, Inc.
TEN
Cities Service Co., Copperhill Operations
PPR
Philllips Puerto Rico Core, Inc.
TKL
Thiokol Chemical Corp.
PRD
Productol Chemical Co., Inc.
TMS
Sterling Drug, Inc., Thomasset Color Division
pto
Puerto Rico Chemical Co., Inc.
TNA
Ethyl Corp.
pit
Petro-iex Chemical Corp.
TOC
Tenneco Oil Co.
TRC
Toms River Chemical Corp.
QKU
Quaker Oats Co.
TRD
Trade Enterprises, Inc.
TX
Texaco, Inc.
RBC
Fike Chemicals, Inc.
RCI
Reichhold Chemicals, Inc.
DCC
Union Carbide Corp.
RDA
Rhodia, Inc.
UUC
Union Oil Co. of California
KM
Khom 5 Haas Co.
UOP
Universal Oil Products Co., UOP Chemical Div.
RIL
Keilly lar t. Chemical Corp.
UPF
United States Pipe 6 Foundry Co.
RPC
Millnaster Unyx Corp., Refined-'Jnyx Division
UPJ
Upjohn Co.
KSA
R.S.A. Corp.
USR
Uniroyal, Inc., chemical Division
RUC
Rubicon Chemicals, Inc.
USS
USS Chemicals Div. of U.S. Steel Corp.
SAL
Salsbury Laboratories
VAL
Valchem Corp.
SAR
Sartomer Industries, Inc.
VEL
Velsicol Chemical Corp.
sec
Standard Chlorine of Delaware, Inc.
vgc
Virginia Chemicals, Inc.
sen
Schering Corp.
VPC
Baychem Corp., Verona Div.
SCN
Schenectady Chemicals, Inc.
yDC
Martin-Marietta Corp., Sodyeco Div.
WAY
Philip A. Hunt Chemical Corp., Wayland
Sterling Drug, Inc. :
Chemical Division
SUH
Hilton-Uavis Chemical Co. Division
WCC
Witco Chemical Corp., Witfield Chemical Div.
SDW
Winthrop Laboratories Division
WHC
Whittaker Corp., Research 5 Development
Stauffer Chemical Co.:
WIL
Wilson g Co., Inc., Wilson Laboratories Div.
SFA
Agricultural Division
WJ
Warner- Jenkinson Manufacturing Co.
SFC
Calhio Chemicals, inc.
WTC
Witco Chemical Co., Inc.
SFS
Specialty Chemical Division
WYN
BASF-Wyandotte Corp.
SHC
Shell Oil Co., Shell Chemical Co. Division
WYT
Wyeth Laboratories, Inc., Wyeth Laboratories
SHO
Shell Oil Co.
Div. of American Home Products Corp.
SK
Smith, Klein t, French Laboratories
SKC
Sinclair-Koppers Chemical Co.
YAW
Y.S. Young Co., Young Aniline Works Division
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix.
55
DYES
Domestic synthetic dyes are derived in whole or in part from cyclic
intermediates. Approximately two-thirds of the dyes consumed in the
United States are used by the textile industry to dye natural and syn-
thetic fibers or fabrics; about one-sixth is used for coloring paper; and
the rest is used chiefly in the production of organic pigments and in
dying of leather and plastics. Of the several thousand different synthe-
tic dyes that are known, more than one thousand are manufactured by one or
more domestic producers. The large number of dyes results from the many
different types of materials to which dyes are applied, the different con-
ditions of service for which dyes are required, and the costs that a
particular use can bear. Dyes are sold as pastes, powders, lumps, and
solutions; concentrations vary from 6 percent to 100 percent. The con-
centration, form, and purity of a dye are determined largely by the use
for which it is intended.
Total domestic production of dyes in 1972 amounted to 263 million
pounds, or 8.0 percent more than the 244 million pounds produced in 1971
(table 1).^ Sales of dyes in 1972 amounted to 255 million pounds, valued
at $480 million, compared with 230 million pounds, valued at $423 million,
in 1971. In terms of quantity, sales of dyes in 1972 were 10.9 percent
larger than in 1971 and in terms of value, 13.5 percent larger. The
average unit value of sales of all dyes in 1972 was $1.88 per pound, com-
pared with $1.84 per pound in 1971.
For many important ayes, production was larger in 1972 than in 1971.
Vat Yellow 2 production increased 49.4 percent from 2,211,000 pounds in
1971 to 3,304,000 pounds in 1972. Basic Yellow 11 production increased
by 45.5 percent from 1,174,000 pounds in 1971 to 1,708,000 pounds in
1972. Other important dyes whose output in 1972 was substantially larger
than in 1971 were Acid Red 88 (43.0 percent increase). Direct Yellow 44
(28.0 percent increase). Disperse Yellow 54 (27.0 percent increase).
Direct Black 38 (26.8 percent increase), and Disperse Red 60 (19.0 per-
cent increase) .
On the other hand, the production of several important dyes was
smaller in 1972 than in 1971. Production of Vat Green 1 was 1,800,000
pounds in 1972, or 54.6 percent less than the 3,966,000 pounds produced
in 1971. Production of Vat Green 3 was 1,402,000 pounds in 1972, or
32.3 percent less than the 2,070,000 pounds produced in 1971. The pro-
duction of Disperse Blue 3 was 29.9 percent less in 1972 than in 1971;
that of Disperse Yellow 23 was 29.3 percent smaller; that of FD§C Yellow
No. 6 was 20.5 percent smaller; that of Direct Blue 2 was 19.8 percent
smaller; and that of Vat Black 25 was 10.4 percent smaller.
Table lA is a summary of production and sales of dyes in 1972 by
class of application. Five application classes of dyes accounted for
72.1 percent of all dyes produced in 1972. Vat dyes accounted for 20.9
See also table 2 of this report which lists these products and
identifies the manufacturers by codes. These codes are given in table 3.
56
SYNTHETIC ORGANIC CHEMICALS, 1972 .
percent of the total; disperse dyes for 15.2 percent; direct dyes for
14.3 percent; acid dyes for 11.3 percent; and fluorescent brighteners for
10.4 percent. Of these five classes of dyes, the production of vat dyes
was 8.3 percent larger in 1972 than in 1971; the production of disperse
dyes was 14.5 percent larger; the production of acid dyes was 11.0 percent
larger; the production of direct dyes was 8.5 percent larger; and the pro-
duction of fluorescent brighteners was 8.4 percent smaller.
1972 production of the remaining classes increased over that of 1971
as follows: Food, drug and cosmetic colors (17.6 percent); solvent dyes
(17.2 percent); mordant dyes (13.0 percent); basic dyes (8.6 percent).
Production of two classes decreased: Azoic compositions (28.3 percent) and
fiber-reactive dyes (0.4 percent).
Table IB shows production and sales of dyes by chemical class. In
1972, three chemical classes of dyes accounted for about two-thirds of all
dyes produced. Azo dyes accounted for 35.0 percent of the total; anthra-
quinone dyes for 17.7 percent of the total; and stilbene dyes for 11.7
percent. The production of azo dyes was 12.2 percent larger in 1972 than
in 1971, that of stilbene dyes was 3.9 percent smaller, and that of the
anthraquinone dyes, 1.3 percent smaller.
Of the remaining chemical classes of dyes for which statistics are
published five exceeded 1971 production by the following percentages;
methine (43.4), quinoline (20.9), triarylme thane (15.4), xanthene (10.1),
and cyanine (5.2). Production of five other classes, however, fell below
1971 levels; phthalocyanine (23.7), nitro (5.9), oxazine (5.7), thiazole
(4.6) and azoic dyes and components (1.2).
DYES
TABLE L— Dyes: U.S, production and sales, 1972
[Listed below are all dyes for which any reported data on production or sales may be published. (Leaders are used
where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all dyes for which data on production or sales were reported and identifies the manufacturer of each]
Dye
:,ooo
pounds
Grand total
ACID DYES
Total
Acid yellow dyes, total
Acid Yellow 11
Acid Yellow 17
Acid Yellow 23
Acid Yellow .^6
Acid Yellow 38
Acid Yellow 40
Acid Yellow 42
Acid Yellow 54
Acid Yellow 65
Acid Yellow 76
Acid Yellow 99
Acid Yellow 151
Acid Yellow 159
All other
Acid orange dyes, total
Acid Orange 7
Acid Orange 8
Acid Orange 10
Acid Orange 24
Acid Orange 60
Acid iirange 64
Acid Orange 74
Acid Orange 86
Acid Orange 116
All other
Acid red dyes, total
Acid Red 1
Acid Red 4
Acid Red 18
Acid Red 26
Acid Red 37
Acid Red 73
Acid Red 85
Acid Red 88
Acid Red 89
Acid Red 99
Acid Red 114
Acid Red 115
Acid Red 137
Acid Red 151
Acid Red 182
Acid Red 186
Acid Red 266
Acid Red 337
All other
263,304
470
280
164
100
88
110
1,322
469
3,641
799
1,096
236
126
1,171
42
169
424
39
200
981
268
210
1,412
1,000
pounds
254,536
1,000
dollars
549
280
176
lis
171
1,231
459
3,026
570
315
280
870
222
182
722
1,014
363
102
115
246
152
975
42
144
362
53
155
926
102
207
1,269
1,224
662
545
151
179
115
170
2,736
1,285
8,580
8,464
465
415
1,339
645
158
229
361
1,656
2,508
14,478
225
151
199
789
349
1,552
65
514
958
130
592
2,014
305
69
1,151
843
4,397
See footnotes at end of table.
SYNTHETIC ORfiANIC CHEMICALS^ 1^7'?
TABLE 1,— Dyes; U.S. production and sales^ 1972— Continued
Quantity Value
ACID DYES--Continued
1,000
pounds
Acid violet dyes, total-
Acid Violet 1
Acid Violet 5
Acid Violet 7
Acid Violet 12
Acid Violet 17
Acid Violet 43
Acid Violet 49
All other
Acid blue dyes, total-
Acid Blue 7
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
All other-
ue 40-
ue 41-
ue 45-
ue 62-
ue 78
ue 113
ue 118
ue 120
ue 158 and 158A-
ue 230
Acid green dyes, total-
Acid Green 3
Acid Green 9
Acid Green 16
Acid Green 20
Acid Green 25
All other
Acid brown dyes, total-
Acid Brown 14
All other
Acid black dyes,
Acid Black 1
Acid Black 24--
Acid Black 52--
Acid Black 107-
All other
123
136
,535
368
126
532
AZOIC DYES AND COMPONENTS
Azoic Compositions
Total
c Yellow 1
c Yellow 2
c Orange 3
c Red 1
c Red 2
c Red 6
984
319
1,798
1,000
pounds
1,000
do I lars
5,021
35
1,441
368
119
516
27
342
179
733
729
4,086
828
333
1,962
194
156
366
248
16,472
130
1,983
1,979
446
2,253
112
204
841
517
295
1,834
114
1,155
639
1,473
1,998
1,632
976
4,235
See footnotes at end of table.
DYES
TABLE 1.--DYES: U.S. production and sales> 1972~Continued
Dye
AZOIC DYES AND COMPONENTS- -Continued
Azoic Compositions — Continued
Azoic Blue 3
Azoic green dyes-
Azoic brown dyes, total -
Azoic Brown 9
All other
Azoic black dyes
All other azoic coinpositions-
Azoia Diazo Components,
(Fast Colop Bases)
Total-
Azoic Diazo Component 4, base
Azoic Diazo Component 10, base
Azoic Diazo Component 32, base
All other azoic diazo components, bases-
Azoia Diazo Components, Salts
(Fast Colop Salts)
Azoic Diazo
Azoic Diazo
Aozic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
Azoic Diazo
All other a
Component 1 , sa
Component 3, sa
Component S, sa
Component 8, sa
Component 9, sa
Component 10, salt
Component 1 1
Component 12
Component 13
Component 28, salt
Component 49, salt
zoic diazo components, salts-
salt-
salt-
salt-
Asoia Coupling Components
(Naphthol AS and Derivatives)
Total-
Azoic Coupling Component 14
Azoic Coupling Component 15
Azoic Coupling Component 18
Azoic Coupling Component 19
Azoic Coupling Component 21
Azoic Coupling Component 29
All other azoic coupling components-
BASIC DYES
Total-
asic yellow dyes,
Basic Yellow 2--
Basic Yellow 11-
Basic Yellow 13-
All other
1,000
pounds
270
118
509
451
1,226
251
779
5,395
404
1,708
201
3,082
Quantity Value
1,000
pounds
389
1,009
400
369
495
604
569
473
477
453
646
103
107
113
331
308
252
27
27
41
31
56
418
358
391
452
372
531
165
193
88
84
267
669
335
553
17,824
4,930
565
1,506
221
2,638
1,000
dollars
270
344
1,073
1,218
146
353
45
299
283
410
13,546
1,179
4,530
541
7,296
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1972"
TABLE 1.~Dyes; U.S. production and sales, 1972— Continued
Production
Quantity Value
BASIC DYES- -Continued
Basic orange dyes, total
Basic Orange 2
Basic Orange 21
All other
Basic red dyes, total
Basic Red 13
Basic Red 14
All other
Basic violet dyes, total
Basic Violet 1
Basic Violet 16
All other
Basic blue dyes, total
Basic Blue 5
All other
Basic Green 1
Basic Brown 1
Basic Brown 4
All other basic dyes
DIRECT DYES
Total
Direct yellow dyes, total
Direct Yellow 4
Direct Yellow 6
Direct Yellow 11
Direct Yellow 12
Direct Yellow 28
Direct Yellow 29
Direct Yellow 44
Direct Yellow 50
Direct Yellow 84
Direct Yellow 105
Direct Yellow 106
All other
Direct orange dyes, total
Direct Orange 8
Direct Orange 15
Direct Orange 26
Direct Orange 29
Direct Orange 54
Direct Orange 37
Direct Orange 39
Direct Orange 72
Direct Orange 73
Direct Orange 81
Direct Orange 102
All other
Direct red dyes, total
Direct Red 1
Direct Red 2
Direct Red 4
See footnotes at end of tabic.
1,000
pounds
446
873
381
715
1,765
3,736
1,224
492
2,020
5,154
147
480
781
37.672
11,595
498
494
2,439
201
237
32
1,116
504
721
268
1,068
4,017
2,234
102
112
26
228
325
113
80
415
366
1,000
pounds
1,000
dollars
483
917
536
664
1,839
930
450
2,094
121
144
504
931
10,792
497
467
2,348
207
234
43
911
485
720
239
893
3,748
117
278
154
271
102
306
356
140
220
774
2,398
1,213
1,649
1,454
5,256
423
259
806
,139
19,448
877
844
2,198
673
539
98
1,915
554
1,592
8,101
149
363
134
228
303
842
1,146
278
474
176
DYES
TABLE 1,--Dyes: U.S. production and sales, 1972--Continued
Dye
Quantity Value
DIRECT DYES--Continued
Direct red dyes--Cont inued
Direct Red 16
Direct Red 23
Direct Red 24
Direct Red 26
Direct Red 28
Direct Red 31
Direct Red 37
Direct Red 39
Direct Red 72
Direct Red 75
Direct Red 79
Direct Red 80
Direct Red 81
Direct Red 83
All other
Direct violet dyes, total-
Direct Violet 9
Direct Violet 51
All other
Direct blue dyes, total —
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
Direct
lue 15
22
25
lue 71
lue 76
lue 78
lue 80
lue 86
lue 98
lue 120 and 120A-
lue 126
lue 218
Dii
All other
Direct green dyes, total
Direct Green 1 --
Direct Green 6
All other
Direct brown dyes, total
Direct Brown 2
Direct Brown 31
Direct Brown 74
Direct Brown 95
Direct Brown 111
Direct Brown 154
All other
Direct black dyes, total
Direct Black 4
Direct Black 9
Direct Black 22
Direct Black 38
Direct Black 51
See footnotes at end of table.
1,000
pounds
361
105
174
107
162
378
,025
288
234
237
133
565
618
340
146
144
,099
,646
234
404
216
1,712
258
121
391
340
853
,701
69
1,000
pounds
210
368
135
148
297
14
169
536
552
200
1,111
282
320
926
298
191
158
15
56
118
65
129
476
652
268
142
121
1,101
1,584
714
199
273
242
460
361
1,000
dollars
220
636
786
344
433
716
56
518
1,002
1,350
11,896
751
1,109
276
428
293
35
159
368
102
420
879
388
,271
,529
282
495
1,011
2,716
444
356
470
643
485
4,566
203
552-743 O - 74 - 5
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE L— Dyes: U.S. production and sales, 1972— Continued
Dye
Production
Quantity
DIRECT DYES- -Continued
Direct black dyes--Continued
Direct Black 80
All other
DISPERSE DYES
Total
Disperse yellow dyes, total
Disperse Yellow 3
Disperse Yellow S
Disperse Yellow 23
Disperse Yellow 33
Disperse Yellow 34
Disperse Yellow 42
Disperse Yellow 54
All other
Disperse orange dyes, total
Disperse Orange 3
Disperse Orange 5
Disperse Orange 17
Disperse Orange 25
All other
Disperse red dyes, total
Disperse Red 1
Disperse Red 5
Disperse Red 11
Disperse Red 15
Disperse Red 17
Disperse Red 55
Disperse Red 60
Disperse Red 65
All other
Disperse violet dyes, total-7
Disperse Violet 1
Disperse Violet 4
Disperse Violet 27
All other
Disperse blue dyes, total
Disperse Blue 1
Disperse Blue 3
Disperse Blue 7
Disperse Blue 64
Disperse Blue 95
All other
Disperse black dyes, total
Disperse Black 1
All other
All other disperse dyes
1,000
pounds
813
595
8,039
2,810
75
820
358
158
714
1,030
2,074
4,746
130
492
,962
262
105
128
76
154
444
1,845
230
4,920
233
556
351
1,300
385
13,583
335
1,110
1,000
pounds
403
504
1,000
dollars
8,293
3,143
1,010
296
160
660
1,048
1,976
4,039
129
470
3,294
70
88
89
169
489
1,685
219
4,573
96
25
230
568
15,665
330
1,289
376
491
13,179
1,268
273
995
4,425
1,473
514
276
1,333
4,076
4,922
8,632
166
914
7,273
26,254
502
99
634
280
256
3,016
5,698
490
15,259
3,503
496
2,541
48,679
1,641
2,266
2,892
946
40,934
2,238
465
1,773
See footnotes at
if tablf
DYES
TABLE 1.--DYES: U.S. production and sales^ 1972— Continued
Dye
Quantity
FIBER-REACTIVE DYES
Fiber-reactive dyes, total
Reactive yellow dyes
Reactive blue dyes
All other reactive dyes
FLUORESCENT BRIGHTENING AGENTS
Total
Fluorescent Brightening Agent 28
All other fluorescent brightening agents
FOOD, DRUG, AND COSMETIC COLORS
Total
Food, Drug, and Cosmetic Dyes
Total
FD5C Red No. 2
FD5C Red No. 3
FD5C Yellow No. 5
FDSC Yellow No. 6
All other food, drug, and cosmetic dyes
Dpug and Cosmetic and External Drug
and Cosmetic Dyes
Total
D6C Green dyes
DSC Orange No. 4
DSC red dyes, total
DSC Red No. 7
DSC Red No. 19
DSC Red No. 21
DSC Red 36
All other
All other drug 6 cosmetic and e.xternal drug S
cosmetic dyes
MORDANT DYES
Total
Mordant yellow dyes
Mordant orange dyes
Mordant red dyes
Mordant brown dyes, total
Mordant Brown 1
Mordant Brown 33
All other
Mordant black dyes, total
Mordant Black 11 ---
Mordant Black 17
All other
See footnotes at end of table.
1,000
pounds
5,699
481
749
2,469
4,644
4,351
971
292
1,109
812
1,167
80
217
114
895
439
151
305
1,000
pounds
3,562
1,000
dollars
15,582
482
739
2,341
1,580
25,862
4,323
1,088
265
1,167
890
913
1,711
6.S1
139
287
2,010
36,259
17,752
2,923
2,356
3,601
2,376
6,496
102
107
1,027
160
353
251
857
164
215
SYNTHETIC QR^AHK CHF^ICALS. 1972'
TABLE 1.— Dyes: U.S. production and sales^ 1972— Continued
Dye
1,000
pounds
MORDANT DYES--Continued
All other mordant dyes
SOLVENT DYES
Total
Solvent yellow dyes, total
Solvent Yellow 14
All other
Solvent orange dyes, total
Solvent Orange 5
All other
Solvent red dyes, total
Solvent Red 26
Solvent Red 49
All other
Solvent blue dyes, total
Solvent Blue 38
All other
Solvent Green 3
Solvent Brown 12
All other solvent dyes
VAT DYES
Total
Vat yellow dyes, total
Vat Yellow 2, 8-1/2°,
Vat Yellow 4, 12-1/2-i
All other
Vat orange dyes, total
Vat Orange 1, 20«.
Vat Orange 2, 12%
Vat Orange 3, 13-1/2%
Vat Orange 9, 12%
Vat Orange 15, 10%
All other
Vat red dyes, total
Vat Red 1, 13^
Vat Red 13, 11%
All other
Vat violet dyes, total
Vat Violet 1, 11%
Vat Violet 9, 12%
Vat Violet 13, 6-1/4%
All other
Vat blue dyes, total
Vat Blue 6, 8-1/3%
Vat Blue 18, 13%
All other
See footnotes at end of table.
121
S19
2,362
1,691
147
1,544
1,044
2,671
900
328
529
417
349
177
186
2,911
656
28,471
1,000
pounds
614
965
131
1,531
4,648
218
1,111
999
416
267
171
504
152
1,000
dollars
22,319
3,685
154
1,253
669
5,332
9,017
3,645
904
115
249
1,317
2,787
3,482
1,028
1,056
1,398
896
784
647
DYES
TABLE 1.~Dyes; U.S. production and sales, 1972— Continued
Dye
Quantity
Unit
value'
1,000
pounds
VAT DYES- -Continued
Vat green dyes, total
Vat Green 1, 6%
Vat Green 5, 10°>
All other
Vat brown dyes, total
Vat Brown 1, 1 Ti
Vat Brown 3, ll^j
All other
Vat black dyes, total
Vat Black 25, 12-1/2%
Vat Black 27, 12-1/2%
All other
All other dyes^
1,800
1,402
2,179
826
644
3,348
1,381
606
1,327
23,015
1,000
pounds
1,000
dollars
2,187
1,887
2,078
4,986
875
808
3,303
5,602
1,503
688
1,411
21,931
2,101
2,307
9,758
1,549
1,623
6,586
1,746
1,024
1,787
Per
pound
1.11
1.11
1.77
2.01
1.99
1.27
1.16
1.49
1.27
.74
Calculated from rounded figures.
' Includes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of
dyes may not be published separately because publication would disclose information received in confidence.
SYNTHETIC ORGANIC CHENICALS, 1972
TABLE lA,— Dyes: U.S. production and sales^ by class of application^ 1972
Class of application
Quantity
Unit
value'
1,000
pounds
Total
Acid
Azoic dyes and components:
Azoic compos itions
Azoic diazo components, bases (Fast color bases) —
Azoic diazo components, salts (Fast color salts) —
Azoic coupling components (Naphthol AS derivatives)
Basic
Direct
Disperse
Fiber-reactive
Fluorescent brightening agents
Food, drug, and cosmetic colors
Mordant
Solvent
Vat
All other^
1,000
:>ounds
254,536
1,000
do I lavs
29,739
2,515
1,226
3,569
2,905
17,999
39,927
3,699
27,321
4,644
1,465
12,468
55,140
23,015
28,039
2,021
743
3,178
2,360
17,824
34,519
38,327
3,562
27,442
4,609
1,711
11,959
56,311
21,931
71,663
3,397
1,352
3,811
5,693
48,876
59,167
107,576
15,582
38,269
19,788
2,567
22,319
63,312
16,316
Per
pound
1.68
1.82
1.20
2.41
2.74
1.71
2.81
4.37
1.39
4.29
1.50
1.87
1.12
.74
^Calculated from rounded figures.
Ir.cludes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of dyes
may not be published separately because publication would disclose information received in confidence.
TABLE IB.— Dyes: U.S. production and sales^ by chemical class., 1972
Chemical class
Production
Unit
value'
Aminoketone--
Anthraquinone
Azo, total
Monoazo
Disazo
Trisazo
Polyazo
Not specified-
Azoic
Cyanine
Ketone imine —
Methine
Nitro
Oxazine
Phthalocyanine-
Quinoline
Stilbene
Thiazole
Tr iaryl me thane -
Xanthene
All other^
1,000
pounds
263.304
92,028
39,018
29,964
10,540
2,691
9,815
10,264
916
455
5,576
1,376
480
1,381
2,705
30,898
352
8,903
1,167
151
1,000
pounds
254,536
1,000
dollars
87,398
60
38,431
28,403
9,519
2,270
8,775
8,365
885
611
5,171
1,253
537
1,474
2,278
30,538
365
8,443
1,052
58,032
172
,399
191,561
95,724
57,988
10,985
3,641
23,223
14,316
2,168
1,318
14,752
2,429
2,004
3,365
7,876
38,122
1,032
20,386
6,262
48,526
per
pound
$1.S8
1.15
1.60
2.65
1.71
2.45
2.16
2.85
1.94
3.73
2.28
3.46
1.25
2.83
2.41
5.95
Calculated from rounded figures.
^ Includes production and sales of azine, coumarin, indigoid, nitroso, oxidation bases, sulfur, thiazine, and miscel-
laneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose
information received in confidence.
DYES
TABLE 2. --Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972
[Dyes for which separate statistics are given in table 1 are marked below with an asterisk (*); dyes not so marked do
not appear in table 1 because the reported data are accepted in confidence and may not be published. Manufacturers'
identification codes shown below are taken from table 3. An x signifies that the manufacturer did not consent to
his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
ACID DYES
*Acid yellow dyes:
Acid Yellow 1 I ACY
Acid Yellow 3 ', ACS
Acid Yellow 4 SDH
*Acid Yellow 11 | ATL
Acid Yellow 14 ' TRC
*Acid Yellow 17 i ACS
Acid Yellow 19 BAS
*Acid Yellow 23 AAP
Acid Yellow 25 GAP
Acid Yellow 29 GAP
*Acid Yellow 34 ACS
*Acid Yellow 36 ACS
*Acid Yellow 38 ACS
*Acid Yellow 40 ALT
•Acid Yellow 42 AAP
Acid Yellow 44 AAP
Acid Yellow 49 ! DUP
*Acid Yellow 54 ACS
Acid Yellow 59 VPC
Acid Yellow 63 AAP
•Acid Yellow 65 ALT
Acid Yellow 73 ACS
*Acid Yellow 76 ACS
Acid Yellow 79 VPC
*Acid Yellow 99 CMC
Acid Yellow 114 TRC
Acid Yellow 121 GAP
Acid Yellow 124 ATL
Acid Yellow 127 TRC
Acid Yellow 128 ALT
Acid Yellow 129 TRC
Acid Yellow 135 GAP
"Acid Yellow 151 ACY
Acid Yellow 152 ACY
*Acid Yellow 159 ACS
Acid Yellow 174 DUP
Acid Yellow 175 DUP
Acid Yellow 190 HST
Acid Yellow 198 DUP
Other acid yellow dyes ACY
*Acid orange dyes :
Acid Orange 1 GAP
Acid Orange 2 | ACS
Acid Orange 5 i ACY
Acid Orange 6 ACS
•Acid Orange 7 AAP
VI
•Acid Orange 8 ACS
•Acid Orange 10 ACS
Acid Orange 12 ACS
*Acid Orange 24 ACS
Acid Orange 31 AAP
Acid Orange 45 ACS
Acid Orange 51 CMC
Acid Orange 52 ACS
Acid Orange 56 GAP
•Acid Orange 60 ATL
Acid Orange 62 TRC
BDO, CMC, VPC.
ATL, BDO, CMG, DUP, HN, PDC, SDH, TRC, VPC.
CMC, YAW.
ACS, ACY, GAP, MRX., PDC, TRC, VPC, WJ , YAW.
TRC.
ATL, PDC.
DUP, GAP, TRC.
ATL, GAP.
ATL, DUP, TRC, VPC.
ACY, GAP, VPC.
GAP, VPC.
VPC.
ACY, HN, TRC, VPC.
ACS.
FAB, TRC, YAW.
SDH.
GAP, TRC.
CAP, TRC, VPC.
ATL, DUP, FAB, GAP, HN, TRC, VPC.
ALT, FAB, GAP, HN, TRC, VPC.
TRC, VPC.
ALT, CMG, GAP, TRC, VPC.
ACS, ACY, ATL, CPC, DUP, GAF, HN, PDC, TRC,
ACY, AIL, DUP,
ACY, ATL, DUP,
PSC.
ACY, DUP, GAP, TRC, YAW.
YAW.
TRC.
ATL.
DUP, GAF, HN, TRC, VPC.
GAF, HN, TRC, VPC.
GAF, TRC, VPC, YAW.
SYNTHETIC
iC CHEMICALS, 1972
TABLE 2,— Dyes for which U.S, production or sales were reported, identified
BY MANUFACTURER, 1972--CoNTI NUED
Manufacturers' identification codes
(according to list in table 3)
aCID DYES- -Continued
*Acid orange dyes--Continued
Acid Orange 63
*Acid Orange 64
Acid Orange 69
Acid Orange 72
*Acid Orange 74
Acid Orange 76
*Acid Orange 86
*Acid Orange 116
Acid Orange 119
Acid Orange 128
Acid Orange 132
Acid Orange 136
Other acid orange dyes
*Acid red dyes:
*Acid Red 1
*Acid Red 4
Acid Red 14
Acid Red 17
*Acid Red 18
*Acid Red 26
Acid Red 27
Acid Red 32
Acid Red 35
Acid Red 35
•Acid Red 37
Acid Red 52
Acid Red 57
Acid Red 66
*Acid Red 73
Acid Red 80
*Acid Red 85
Acid Red 87
*Acid Red 88
*Acid Red 89
Acid Red 97 --■
*Acid Red 99
Acid Red 106
Acid Red 111
*Acid Red 114
*Acid Red US
Acid Red 119
Acid Red 133
Acid Red 134
*Acid Red 137
Acid Red 138
*Acid Red 151
Acid Red 167
Acid Red 175
Acid Red 178
Acid Red 179
*Acid Red 182
Acid Red 185
*Acid Red 186
Acid Red 191
Acid Red 194
Acid Red 201
Acid Red 211
Acid Red 212
Acid Red 213
*Acid Red 266
Acid Red 277
Acid Red 299
Acid Red 509
GAF,
TRC.
ACS,
ACY,
DUP.
ACY.
GAF.
CMG,
GAF,
TRC .
TRC.
ACS,
ALT,
CMG,
IRC.
ACS,
ALT,
CMG,
FAB,
GAF,
TRC,
VPC,
YAW.
TRC.
DUP.
DUP.
DUP.
ALT,
GAF,
TRC,
VPC.
ACS,
ACY,
ATL,
BDO,
DUP
GAF,
SDH,
TRC, VPC, YAW
AAP,
ATL,
BDO,
GAF,
PDC
TRC,
VPC,
YAW.
ACS,
ATL,
GAF,
PDC,
YAW
ACS,
ATL,
TRC.
ACS,
ATL,
BDO,
GAF,
TRC
ACY,
ATL,
CPC.
ACS.
GAF.
YAW.
AAP,
GAF.
ACS,
ATL,
DUP,
GAF,
HN,
TRC.
GAF.
AIL,
TRC.
AAP,
ATL.
ACS,
ACY,
ATL,
DUP,
GAF
PSC
TRC
VPC, YAW.
ATL,
ICI.
ACb,
ALT,
DUP,
GAF,
HN,
VPC,
YAW.
SDH.
ACS,
ACY,
AIL,
UUP,
GAF
TRC
SDH
YAW.
AAP,
ATL,
BDO,
GAF,
HN.
ATL,
GAF.
ATL,
FAB,
HN,
TRC,
YAW .
YAW.
ATL.
ACS,
ALT,
.ATL
DUP,
GAF
TRC
VPC
ACb,
AIL,
GAF
ALT,
ATL.
GAF.
TRC.
ACS,
ATL,
DUP,
GAF
HN,
TRC.
ALT.
AAP,
ACY,
ALT
ATL
DUP
HN,
TRC,
VPC, YAW.
ACS,
ATL,
DUP,
TRC
DUP.
DUP.
TRC
ACS,
ALT,
ATL,
BDO
CMG
DUP
GAF
HN.
TRC
ATL
CMG,
GAF
VPC
TRC
TRC
TRC
DUP
TRC
TRC
DUP
TRC
VPC
VPC
ALT
TRC
TRC
DYES
TABLE 2.
-Dyes for which U.S. production or sales were reported^ identified
BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
ACID DYES--Continued
et dyes :
olet 1--
t dye
*Acid red dyes--Continued
•Acid Red 337
Acid Ked 350
Other acid red dyes
*Acid vio
•Acid V
*Acid V
*Acid V
*Acid V
*Acid V
Acid V
Aciv V
Acid V
•Acid V
•Acid V
Acid V
Acid V
Acid V
Other a
•Acid blue
Acid B
•Acid B
•Acid B
Acid B
Acid B
Acid B
•Acid B
•Acid B
Acid B
Acid B
•Acid B
•Acid B
*Acid B
•Acid B
•Acid B
Acid B
Acid B
Acid B
•Acid B
Acid B
Acid B
Acid B
Acid B
Acid B:
Acid B
Acid B
•Acid B
•Acid B
•Acid B
Acid B
Acid B
Acid B
•Acid B
Acid B
Acid B
Acid B
Acid B
Acid B
♦Acid B
Acid B
DUP, TRC, VPC.
GAF.
ALT, CMC, DUP, GAF, TRC, VPC.
olet 3---
olet 7---
olet 12--
olet 17--
olet 29--
olet 34--
olet 41--
olet 43--
olet 49--
olet 56--
olet 58--
olet 76--
cid violf
dyes :
ue 1
ue 7
ue 9
ue 15
ue 20
ue 23
ue 25
ue 27
ue 29
ue 34
ue 40
ue 41
ue 43
ue 45
ue 62
ue 74-
ue 78-
ue 104-
ue 113-
ue 118
ue 120
ue 122
ue 127
ue 145
ue 158 and 158A-
ue 165
ue 179
ue 198
ue 203
ue 221
ue 230
ue 231
Other acid blue dyes-
BDO
ACS
AAP
BDO
DUP
HSH
AIL
CMG
ATL
ACS
GAF
GAF
ACS
CMG
ACS
ACS
ACS
GAF
ACS
TRC
ACS
ATL
PDC
ACS
ACS
ATL
ACS
ACY
ACS
CMG
GAF
ACS
ACS
ATL
ICI
GAF
TRC
ACS
HSC
ACS
ACS
Tl
ACS
ACS
DUP
CMG
ACS
BDO
DUP
GAF
VPC
VPC
VPC
ACS
TRC
ACY, ALT, ATL, GAF, HN, TRC, VPC.
CMG, GAF.
ACY, TRC, YAW.
ACS, ATL, BDO, CMG, GAF, TRC, VPC.
CMG, DUP, GAF.
GAF, SDH.
ICI.
CMG, HSH, ICI.
ACY, SDH, FRC.
GAF.
ACY, ATL, GAF, VPC.
GAF, SDH.
ATL, BDO, CMG, DUP, GAF, TRC, VPC.
BDO, CMG, GAF.
YAW.
ALT, ATL, BDO, CMG, DUP, GAF, ICI, TRC, VPC.
BDO, CMG.
ICI, TRC.
ATL, CMC, DUP, GAF, HN, TRC.
ALT, BDO, CMG, GAF.
DUP.
ATL, BDO, DUP, GAF, ICI, IRC.
TRC.
ATL, YAW.
GAF.
ALT, ATL, BDO, CMG, UUP, FAB, GAF, HN, PDC,
:, YAW.
ATL, HN.
ATL, GAF.
DUP.
CMG, GAF, HN, TRC, VPC.
SYNTHETIC ORGANIC CHEMICALS, 1972 ■
TABLE 2. —Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972--CONTINUED
Dye
Manufacturers' identification codes
(according to list in table 3)
ACID DYES--Continued
"Acid green dyes:
Acid Green 1
*Acid Green 3
Acid Green 5
*Acid Green 9
Acid Green 12
*Acid Green 16
Acid Green 19
*Acid Green 20
Acid Green 22
*Acid Green 25
Acid Green 35
Acid Green 41
Acid Green 50
Acid Green 58
Acid Green 70
Acid Green 84
Other acid green dyes
*Acid brown dyes:
Acid Brown 1
Acid Brown 6
*Acid Brown 14
Acid Brown 19
Acid Brown 22
Acid Brown 28
Acid Brown 31
Acid Brown 45
Acid Brown 96
Acid Brown 97
Acid Brown 98
Acid Brown 152
Acid Brown 158
Acid Brown 243
Other acid brown dyes
*Acid black dyes :
*Acid Black 1
Acid Black 2
*Acid Black 24
Acid Black 26, 26A and 26B
Acid Black 29
Acid Black 48
*Acid Black 52
Acid Black 53
Acid Black 58
Acid Black 60
Acid Black 92
*Acid Black 107
Acid Black 108
Acid Black 139
Acid Black 140
Acid Black 172
Other acid black dyes
AZOIC DYES AND COMPONENTS
Azoic Compositions
Azoic yellow dyes:
'Azoic Yellow 1
*Azoic Yellow 2
Azoic Yellow 3
Other azoic yellow dyes
ACS
ACY,
DUP.
ACS
ACY,
GAP,
TRC
CAP
ACS
ACY,
GAP
GAP
ACS
GAP,
TRC.
ALT
ATL
BDO,
GAP,
PDC
TRC
GAP
ACS
ATL,
GAP,
HSH
ICI
TRC, VPC
TRC
ICi
VPC.
ACY
GAP.
TRC
TRC
VPC
ACY
ALT,
VPC.
GAP
GAP
AAP
ACY,
DUP.
GAP
TRC
YAW.
TRC
DUP
TRC
GAP
TRC
ACY
ACY
ACY
TRC,
YAW.
GAP
GAP
GAP
ACY
ALT,
DUP,
GAP
VPC
YAW.
AAP
ACS,
ACY,
ATL
DUP
GAP, HN,
ACS
ACY.
ACS
DUP,
GAP.
ATL
DUP,
TRC
GAP
YAW.
ACY
TRC.
ACS
ATL,
DUP,
PAB
GAP
HN, TRC,
PSC
CMC
TRC .
BOO
TRC.
ACY
ACS
DUP,
GAP,
TRC
GAP
VPC
CMC
VPC
ALT
ATL,
UN,
PDC,
VPC,
YAW.
ALL, ATL, SDH.
ALL, ATL, BUC,
ATL, BUC.
ATL.
DYES
TABLE 2.— Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972~CONTINUED
Manufacturers' identification codes
(according to list in table 3)
AZOIC DYES AND COMPONENTS- -Continued
Azoic Compositions- -Continued
Azoic orange dyes:
*Azoic Orange 3
Azoic Orange 10
Azoic red dyes:
*Azoic Red 1
*Azoic Red 2
"Azoic Red 6
Azoic Red 12
Azoic Red 16
Azoic Red 73
Azoic Red 74
Other azoic red dyes
Azoic violet dyes:
Azoic Violet 1
Other azoic violet dyes
Azoic blue dyes :
Azoic Blue 2
*Azoic Blue 3
Azoic Blue 6
Azoic Blue 7
Other azoic blue dyes
•Azoic green dyes:
Azoic Green 1
Other azoic green dyes
Azoic brown dyes:
Azoic Brown 3
Azoic Brown 7
•Azoic Brown 9
Azoic Brown 10
Azoic Brown 26
Other azoic brown dyes
*Azoic black dyes:
Azoic Black 1
Azoic Black 4
Azoic Black 15
Other azoic black dyes
Azoic Diazo Components, Bases
(Fast Color Bases)
Azoic Diazo Component 2, base
Azoic Diazo Component 3, base
*Azoic Diazo Component 4, base
Azoic Diazo Component 5, base
Azoic Diazo Component 8, base
*Azoic Diazo Component 10, base
Azoic Diazo Component 11, base
Azoic Diazo Component 12, base
Azoic Diazo Component 13, base
Azoic Diazo Component 14, base
Azoic Diazo Component 28, base
*Azoic Diazo Component 32, base
Azoic Diazo Component 34, base
Azoic Diazo Component 44, base
Azoic Diazo Component 46, base
Azoic Diazo Component 48, base
Other azoic diazo components, base
ALL,
ATL,
BUC,
X.
BUC.
ALL,
ATL,
BUC,
SDH,
X.
ALL,
ATL,
BUC,
GAF,
X.
AIL,
BUC,
SDH,
X.
ATL.
ATI.
GAF.
GAP.
ALL,
X.
ATL,
BUC.
ALL.
ATL.
ALL,
ATL,
BUC,
GAF,
HST,
SDH, X
ATL.
GAF.
ATL,
GAF.
ATL.
ALL,
BUC.
X.
ATL,
BUC.
ALL,
.ATL,
BUC,
GAF,
HST,
VPC, X
ATL,
BUC.
GAF.
ALL,
ATL,
GAF,
VPC.
HST.
ATL,
BUC,
GAF.
GAF.
ALL,
ATL,
GAF.
ATL, BUC.
BUC.
ALL, BUC, GAF, SDH.
ATL, GAF.
SDH.
ATL, BUC, GAF.
ATL.
BUC, SDH.
ATL, BUC.
AAP.
ALL, BUC, GAF.
ALL, ATL, BUC.
ALL.
BUC.
ATL.
GAF.
ALL.
SYNTHETIC ORGANICAL CHEMICALS. 1°72
TABLE 2,— Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER. 1972~CONTINUED
Manufacturers' identification codes
(according to list in table 3J
AZOIC DYES AND COMPONENTS--Continued
Azoic Diazo Components, Salts
(Fast Colov Salts)
*Azoic
Azoic
♦Azoic
*Azoic
*Azoic
*Azoic
*Azoic
*Azoic
*Azoic
*Azoic
*Azoic
Azoic
Azoic
*Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
*Azoic
Azoic
Other
AZOIC
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
Azoic
*Azoic
*Azoic
Azoic
Azoic
*Azoic
*Azoic
Azoic
*Azoic
Azoic
*Azoic
Azoic
Azoic
*Azoic
Azoic
Other
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
Diazo
azoic
salt-
salt-
salt-
salt-
salt-
salt--
salt-
salt-
Component 1
Component 2
Component 3
Component 5
Component 6
Component 8
Component 9
Component 10
Component 11
Component 12, salt
Component 13, salt
Component 14, salt
Component
Component
Component 32, salt
14, salt
15, salt
16, salt
;7, salt
salt-
salt-
Component
Component
Component
Component
Component 41, salt
Component 42, salt
Component 44, salt
Component 48, salt
Component 49, salt
Component 121, salt
diazo components, salts
Azoio Coupling Components
(Naphthol AS and Derivatives )
Coupling Component 2
Coupling Component 3
Coupling Component 4
Coupling Component 5
Coupling Component 7
Coupling Component 8
Coupling Component 10
Coupling Component 11
Coupling Component 12
Coupling Component 13
Coupling Component 14
Coupling Component IS
Coupling Component 16
Coupling Component 17
Coupling Component 18
Coupling Component 19
Coupling Component 20
Coupling Component 21
Coupling Component 24
Coupling Component 29
Coupling Component 34
Coupling Component 35
Coupling Component 45
Coupling Component 107
azoic coupling components-
AAP, ALL,
BUC.
AAP, ALL,
AAP, ALL,
AAP, BUC,
AAP, ALL,
AAP, ALL,
ALL, BUC,
AAP, ALL,
AAP, ALL,
AAP, ALL.
AAP.
ALL, BUC.
ALL, BUC,
ALL.
ALL, GAP.
BUC, GAP.
GAP.
GAP.
ALL, BUC.
ALL, GAP.
ALL, BUC.
BUC, SDH.
AAP, ALL,
GAP.
ALL.
BUC, GAP, SDH.
BUC, GAP, SDH.
BUC, GAP, SDH.
GAP.
BUC, GAP.
BUC, GAP , SDH.
GAP.
BUC.
BUC, GAP, SDH.
BUC, GAP, SDH.
GAP, SDH.
AIL,
BUC,
GAP,
PCW.
ALL,
BUC,
PCW.
ATL,
BUC,
GAP.
BUC.
BUC,
HST,
PCW,
SDH.
ATL,
BUC,
PCW.
ATL,
PCW.
ATL,
BUC,
PCW.
ATL,
BUC,
PCW .
GAP,
HST.
ATL,
BUC,
PCW.
ALL,
BUC,
GAP,
PCW.
BUC.
ATL,
BUC,
PCW.
ALL,
ATL,
BUC,
GAP, PCW
BUC,
GAP,
PCW.
ATL,
BUC,
GAP,
PCW.
ATL,
BUC,
PCW.
PCW.
ATL,
BUC,
PCW.
ATL,
BUC,
PCW.
ALL,
BUC,
HST,
PCW.
ATL,
BUC,
GAP.
HST.
ATL,
GAP,
VPC.
DYES
TABLE 2,— Dyes for which U.S. production or sales were reported^ identified
BY MANUFACTURER^ 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
BASIC DYES
*Basic yellow dyes:
Basic Yellow 1
*Basic Yellow 2
*Basic Yellow 11
*Basic Yellow 15
Basic Yellow 15
Basic Yellow 21
Basic Yellow 28
Basic Yellow 29
Basic Yellow 51
Basic Yellow 57
Basic Yellow 41
Basic Yellow 52
Basic Yellow 53
Other basic yellow dyes
*Basic orange dyes:
Basic Orange 1
*Basic Orange 2
*Basic Orange 21
Basic Orange 24
Basic Orange 25
Basic Orange 26
Basic Orange 27
Basic Orange 28
Basic Orange 51
Basic Orange 39
Other basic orange dyes
*Basic red dyes:
Basic Red 1
Basic Red 2
Basic Red 9
Basic Red 12
*Basic Red 13
•Basic Red 14
Basic Red 15
Basic Red 16
Basic Red 17
Basic Red 18
Basic Red 19
Basic Red 22
Basic Red 29
Basic Red 30
Basic Red 46
Basic Red 49
Basic Red 73
Other basic red dyes
*Basic violet dyes:
•Basic Violet 1
Basic Violet 2
Basic Violet 3
Basic Violet 4
Basic Violet 7
Basic Violet 10
Basic Violet 11
Basic Violet 13
Basic Violet 14
Basic Violet 15
•Basic Violet 16
Basic Violet 18
Basic Violet 24
Other basic violet dyes
DUP
ACS
ACS
ACS
DUP
ACS
VPC
DUP
DUP
ACY
ACY
DUP
DUP
AIL
ACS
ACS
ACS
DUP
DUP
DUP
VPC
VPC
ACY
DUP
DUP
BAS
ACS
DSC
ACY
ACS
ACS
ATL
DUP
DUP
ATL
DUP
ACY
BAS
ACY
ACS
DUP
DUP
ATL
ACS
DSC
DSC
DSC
ATL
ACY
ACY
DSC
DSC
DUP
ATL
ACY
DUP
ACY
ACY, DUP.
ACY, ATL. DUP. GAF, TRC, VPC.
.ATL, DUP, GAF, VPC.
VPC.
DUP.
BAS, DUP, EKT, GAF.
ACY, DUP, GAF, PSC, TRC.
ACY, DSC, DUP, GAF, PSC, TRC.
ALT, ATL, DUP, GAF, TRC, VPC.
DUP.
DUP.
HSC.
DUP.
ATL, GAF, TRC, VPC.
ACY, ATL, DUP, FAB, GAF, VPC.
DUP, GAF, TRC.
DUP, GAF, VPC.
TRC.
TRC.
GAF.
DUP, EKT, VPC.
ACY, DSC, DUP, HSC.
DUP.
DUP.
GAF.
DUP, GAF.
DUP. FAB, GAF, TRC, VPC.
SYNTHETIC ORGANIC CHEfllCALS. Wl
TABLE 2,
-Dyes for which U,S, production or sales were reported, identified
by manufacturer, 1972--c0ntinued
Dye
Manufacturers' identification codes
(according to list in table 3)
BASIC DYES--Continued
*Basic blue dyes
Basic B]
Basic B]
Basil
Basic Bl
*Basic
Basic
Basic Bl
Basic Bl
Basic Bl
Basic Bl
Basic Bl
Basic B]
Basic B]
Basic Bl
ue
Basic B]
Basic B]
Basic B]
Basic Bl
Basic Bl
Basic B]
Basi
Basic Bl
Basil
Basi(
ue 11-
ue 21-
ue 22-
ue 26-
ue 3S-
ue 41-
ue 45-
ue 47-
ue 76-
ue 77-
ue 82-
lue 87
lue 97
Other basic blue dyes--
Basic green dyes:
*Basic Green 1
Basic Green 3
Basic Green 4
Basic green 7
Basic brown dyes;
*Basic Brown 1
Basic Brown 2
*Basic Brown 4
Other basic brown dyes-
Basic black dyes :
Basic Black 9
Other basic black dyes-
DIRECT DYES
•Direct yellow dyes;
'Direct Yellow 4--
Direct Yellow 5--
*Direct Yellow 6--
Direct Yellow 7--
Direct Yellow 8--
*Direct Yellow 11-
•Direct Yellow 12-
Direct Yellow 20-
Direct Yellow 23-
Direct Yellow 26-
Direct Yellow 27-
*Direct Yellow 28-
*Direct Yellow 29-
Direct Yellow 34-
Direct Yellow 39-
Direct Yellow 41-
*Direct Yellow 44-
*Direct Yellow 50-
Direct Yellow 59-
DSC,
GAP,
SDH,
VPC.
DSC.
DUP,
GAP,
HST.
DUP.
DSC,
SDH,
VPC.
ACY.
DSC,
DUP,
SDH.
ACS,
ACY,
DUP.
DSC,
SDH.
DUP.
ACS,
DUP.
DSC,
DUP.
DUP.
IRC.
VPC.
VPC.
ACY,
BAS.
GAP.
VPC.
EKT.
ACY.
DUP.
DUP,
TRC.
DUP.
DUP.
ACS,
ALT,
BAS,
EKT, VPC
ACS,
ACY,
DSC,
DUP.
DUP.
ACS,
ACY,
DSC,
DUP, VPC
DSC.
ACS, ACY, DUP, GAP, PSC, TRC.
GAP.
ACS, ACY, DSC, DUP, GAP, PSC, TRC.
DUP.
VPC.
ALT, DSC, VPC.
ACS,
ACS,
ACS,
ATL.
ACS,
ACS,
ACS,
TRC.
DUP.
ATL,
GAP.
ACS,
ATL,
ALT,
TRC.
ATL.
ACS,
ALT,
ATL.
ACY, ATL, DUP, GAP,
ACY, GAP.
ACY, DUP, GAP, TRC.
HN, TRC, VPC.
ATL, GAP.
ACY, ALT, DUP, GAP, HN, SDH, TRC, VPC.
ACY, ATL, CMC, DUP, FAB, GAP, HN, TRC.
ATL, DUP, GAP, PDC, TRC.
DUP, GAP.
ATL, DUP, FAB, GAP, HN, HSH, TRC, VPC.
■ATL, DUP, PAB, GAP, HN, HSH, TRC, VPC.
DYES
TABLE 2.--DVES for which U.S. production or sales were reported^ identified
BY manufacturer, 1972--Continued
Manufacturers' identification codes
(according to list in table 3)
DIRECT DYES--Continued
'Direct yellow dyes--Continued
Direct Yellow 63
Direct Yellow 81
♦Direct Yellow 84-
Direct Yellow 103
♦Direct Yellow 105
•Direct Yellow 106
Direct Yellow 107
Direct Yellow 114
Direct Yellow 117
Direct Yellow 118
Direct Yellow 119
Direct Yellow 120
Direct Yellow 127
Direct Yellow 131
Direct Yellow 132
Other direct yellow dyes
♦Direct orange dyes:
Direct Orange 1
Direct Orange 6
♦Direct Orange 8
Direct Orange 10
Direct Orange 11
♦Direct Orange 15
♦Direct Orange 26
♦Direct Orange 29
♦Direct Orange 54
♦Direct Orange 37
♦Direct Orange 39
Direct Orange 59
Direct Orange 61
Direct Orange 67
♦Direct Orange 72
♦Direct Orange 73
Direct Orange 74
Direct Orange 78
Direct Orange 79
Direct Orange 80
♦Direct Orange 81
Direct Orange 83
Direct Orange 88
♦Direct Orange 102
Direct Orange 110
Other direct orange dyes
♦Direct red dyes:
♦Direct Red 1
♦Direct Red 2
♦Direct Red 4
Direct Red 7
Direct Red 10
Direct Red 13
♦Direct Red 16
Direct Red 20
♦Direct Red 23
♦Direct Red 24
♦Direct Red 26
♦Direct Red 28
♦Direct Red 31
Direct Red 32
♦Direct Red 37
DUP.
AIL.
ATL,
ACS.
ALT,
ACS,
ACS,
ACY.
TRC.
TRC.
DUP.
DUP.
DUP,
DUP.
VPC .
AAP,
AAP,
ACS.
ACS,
AAP.
GAP.
ACS,
ACS,
ATL,
ACS,
ACY,
ACY,
DUP,
TRC.
VPC.
ACS,
DUP,
DUP,
VPC.
DUP.
VPC.
DUP,
GAP.
DUP.
ACS,
TRC.
ALT,
DUP,
ACS,
ACS.
ATL.
AAP.
YAW.
ACS,
ATL,
ACS,
AAP,
ACS,
ACS,
ACS,
ACS.
ACS,
DUP, FAB, GAP, HN, TRC, VPC.
HN, TRC.
ALT, FAB, GAF, UN, TRC.
TRC.
ACY, ALT, ATL, DUP, FAB, GAF, HSH, TRC, VPC.
ALT, ATL, BDO.
DUP, FAB, GAF, YAW.
ACY, DUP, GAF, HN, TRC.
ATL, GAF, HSM, TRC.
FAB, HN, TRC, VPC.
ATL, CMG, DUP. GAF.
ATL, CMG, GAF.
ALT, ATL, CMG, DUP, FAB, GAF, UN.
GAF.
ATL, FAB, »i, HSH, IRC, VPC.
GAF, TRC, VPC.
HSH.
ACY, ATL, DUP, GAF.
ATL.
FAB, GAF, TRC, YAW.
ATL, DUP, FAB, HN, TRC.
ATL, TRC, VPC.
ATL, DUP, TRC.
GAF.
ATL, DUP, FAB, GAF, HN, TRC, VPC.
ACS, ATL, FAB, HN, HSH, TRC, VPC.
ATL, DUP, FAB, GAF, HN, HSH, TRC.
DUP, FAB, YAW.
ATL, GAF, HSH.
DUP, GAF, YAW.
SYNTHETIC ORG'\NIC CHEMICALS. 1972
TABLE 2,— Dyes for which U.S. production or sales were reported, identified
BY manufacturer. 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
DIRECT DYES--Continued
*Direct red dyes--Continued
♦Direct Red 39
Direct Red 62
♦Direct Red 72
Direct Red 73
♦Direct Red 75
Direct Red 76
♦Direct Red 79
♦Direct Red 80
♦Direct Red 81
♦Direct Red 83
Direct Red 84
Direct Red 95
Direct Red 100-
Direct Red 117
Direct Red 120
Direct Red 122
Direct Red 12i--=-
Direct Red 127 and 127A
Direct Red 139
Direct Red 149
Direct Red 152
Direct Red 153
Direct Red 209
Direct Red 212
Direct Red 236
Other direct red dyes
♦Direct violet dyes;
Direct Violet 7
♦Direct Violet 9
Direct Violet 14
Direct Violet 22
Direct Violet 47
Direct Violet 48
♦Direct Violet 51
Direct Violet 62
Direct Violet 66
Direct Violet 67
Other direct violet dyes
♦Direct blue dyes:
♦Direct Blue 1
♦Direct Blue 2
♦Direct Blue 6
♦Direct Blue 8
Direct Blue 14
♦Direct Blue 15
♦Direct Blue 22
Direct Blue 24
♦Direct Blue 25
Direct Blue 26
Direct Blue 67
♦Direct Blue 71
Direct Blue 74
Direct Blue 75
♦Direct Blue 76
♦Direct Blue 78
♦Direct Blue 80
Direct Blue 81
♦Direct Blue 86
ATL
ATL
ACS
ACS
ATL
GAP
ATL
ACS
ACS
v:
ACS
ATL
VPC
ATL
DUP
CMC
ATL
ATL
ATL
VPC
ATL
CMC
ATL
TRC
VPC
DUP
ALT
ACS
ACS
AIL
DUP
GAP
ACS
ACS
ACY
ATL
DUP
ALT
AAP
AAP
ACS
ACS
ACS
ACS
ATL
ACS
ATL
ATL
ACS
DUP
TRC
ACS
ACS
ACS
ATL
ALT
DUP, GAP, TRC, YAW.
TRC.
ATL, DUP, GAP, IRC.
ATL.
CMG, GAP.
CMC, HN, TRC, VPC.
ALT, ATL, FAB, HN, HSH, SDH, TRC, VPC.
ACY, ALT, ATL, BDO, DUP, GAP, HN, HSH, PDC, TRC,
PC, YAW.
ALT, ATL, PAB, HN, HSH, TRC, VPC.
TRC, VPC.
GAP.
CMG.
CMG.
VPC.
ATL, DUP, GAP, HN, HSH, TRC, VPC.
ATL.
ATL, UUP, GAP, HN, TRC.
ATL, DUP.
TRC.
VPC.
ACS, ACY, ATL, CMG, DUP, PAB, GAP, HN, IRC,
:, YAW.
ACS, DUP, FAB, GAP, HN, HSH, TRC, VPC, YAW.
ACS, ACY, DUP, GAP, HN, HSH, YAW.
ALT, ATL, DUP, GAP.
ATL, HN, TRC.
ATL, DUP, GAP, VPC, YAW.
ATL, CMG.
YAW.
ATL, GAP, TRC, YAW.
TRC.
ATL, GAP, TRC.
ALT, ATL, GAP, HN, HSH, TRC, VPC.
ATL, CMG, DUP, TRC.
ALT, ATL, DUP, FAB, GAP, HN, HSH, TRC, VPC.
ATL, DUP, PAB, GAP, HN, ICC, SDH, TRC.
DYES
TABLE 2.— Dyes for which U.S. production or sales were reported^ identified
BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
DIRECT DYES--Continued
Direct Bl
*Direct
Direct Bl
Direct Bl
•Direct Bl
♦Direct Bl
Direct Bl
Direct Bl
Direct Bl
Direct Bl
Direct Bl
Direc
Direct Bl
•Direct Bl
Direct Bl
Direct Bl
•Direct blue dyes- -Continued
Direct Blue 87
lue 91
lue 98
lue 100
lue 104
lue 120 and 120A--
lue 126
lue 136
lue 143
lue 151
lue 160
lue 189
lue 191
lue 199
lue 218
lue 224
lue 263
Other direct blue dyes
•Direct green dyes :
•Direct Green 1
•Direct Green 6
Direct Green 8
Direct Green 26
Direct Green 27
Direct Green 28
Direct Green 38
Direct Green 39
Direct Green 45
Direct Green 47
Direct Green 51
Direct Green 69
Other direct green dyes —
•Direct brown dyes :
Direct Brown 1
Direct Brown lA
*Direct Brown 2
Direct Brown 6
•Direct Brown 31
Direct Brown 32
Direct Brown 40
Direct Brown 44
Direct Brown 48
Direct Brown 59
•Direct Brown 74
•Direct Brown 95
Direct Brown 106
•Direct Brown 111
Direct Brown 112
•Direct Brown 154
Direct Brown 218
Other direct brown dyes
•Direct black dyes:
•Direct Black 4
Direct Black 8
•Direct Black 9
Direct Black 17
Direct Black 19
•Direct Black 22
Direct Black 36
ICI.
TRC.
ATL,
GAF,
TRC,
VPC
ALT,
FAB,
HN.
DUP.
ATL.
DUP,
FAB,
HN,
TRC.
ATL,
UUP,
HSH,
TKC
VPC.
GAP.
DUP.
ATL,
TRC.
TRC.
FAB,
TRC.
AAP,
ACS,
GAF.
DUP,
GAF.
ACS,
ALT,
ATL,
DUP
FAB
GAF
HN,
TRC. VPC
ATL.
DUP.
ALT,
ATL,
DUP,
GAF
VPC
AAP,
ACS,
DUP,
FAB
GAF
TRC
YAW
AAP,
ACS,
DUP,
FAB
GAF
HN,
TRC,
YAW.
TRC.
DUP,
TRC.
DUP,
TRC.
TRC.
DUP,
GAF.
GAF.
ATL,
VPC.
ATL,
DUP,
GAF.
TRC.
TRC.
ACY,
ALT,
TRC.
HN.
GAF,
TRC,
YAW.
AAP,
ACS,
ACY,
DUP
FAB,
GAF
HN,
HSH, TRC
YAW.
AAP,
ATL,
DUP,
GAF
YAW
GAF.
AAP.
GAF,
YAW.
AAP.
YAW
AAP,
ACS,
DUP.
ACS,
ATL,
DUP,
FAB
GAF
HN,
HSH,
TRC, YAW
GAF.
DUP,
GAF,
TRC,
VPC
ATL.
ACS,
DUP,
FAB,
YAW
ACS.
ALT,
HSH,
VPC.
ACS,
FAB,
GAF,
HN,
YAW.
YAW.
ACS,
ATL,
DUP.
GAF.
ATL,
HN,
TRC.
ALT,
ATL,
GAF,
HN,
TKC,
VPC,
YAW.
AAP.
552-743 O - 74 - 6
SYNTHETIC nRfiflNIC CHEniCai.S, 1972
TABLE 2. —Dyes for which U.S. production or sales were reported, identified
BY manufacturer, 1972--Continued
DIRECT DYES--Continued
'Direct black dyes--Continued
Direct Black 37
♦Direct Black 38
Direct Black 44
•Direct Black 51
Direct Black 56
Direct Black 71
Direct Black 75
Direct Black 78
♦Direct Black 80
Direct Black 95
Direct Black 190
Other direct black dyes
DISPERSE DYES
♦Disperse yellow dyes:
Disperse Yellow 1
Disperse Yellow 2
♦Disperse Yellow 3
♦Disperse Yellow 5
Disperse Yellow 8
♦Disperse Yellow 23
Disperse Yellow 31
Disperse Yellow 32
♦Disperse Yellow 33
♦Disperse Yellow 34
♦Disperse Yellow 42
Disperse Yellow 50
♦Disperse Yellow 54
Disperse Yellow 58
Disperse Yellow 64
Disperse Yellow 67
Disperse Yellow 68
Disperse Yellow 69
Disperse Yellow 77
Disperse Yellow 85
Disperse Yellow 86
Disperse Yellow 87
Disperse Yellow 88
Disperse Yellow 89
Disperse Yellow 93
Disperse Yellow 95
Disperse Yellow 96
Disperse Yellow 118
Disperse Yellow 125
Other disperse yellow dyes
♦Disperse orange dyes:
♦Disperse Orange 5
♦Disperse Orange 5
Disperse Orange 16
♦Disperse Orange 17
Disperse Orange 21
♦Disperse Orange 25
Disperse Orange 29
Disperse Orange 30
Disperse Orange 37
Disperse Orange 38
Disperse Orange 41
Disperse Orange 44
Disperse Orange 57
Manufacturers' identi
(according to list
catioi
table
codes
5)
FAB, GAP,
ATL, DUP,
HSH, YAW.
GAP, TRC.
YAW.
ICC, TRC.
AAP.
ACS,
TRC.
ACS,
ACS.
ATL.
GAP.
ACS, FAB, HN.
ACS, ATL, FAB, HN, HSH,
ACS.
ACS, HN.
ACY, ALT, ATL, HSH, TRC, YAW.
GAP.
DUP.
AAP, ALT, DUP, GAP, HN, ICC, TRC.
GAF, HN, ICC.
TRC.
AAP, ALT, DUP, EKl, GAF,
GAP.
DUP.
AAP, EKT, GAF, ICC, TRC.
AAP, EKT, ICC.
AAP, BUC, DUP, EKT, GAF, HN, ICC, SDC,
AAP, ATL, DUP, GAF, HN, ICC, SDL, TKC.
HST.
BUC, DUP.
DUP.
HST.
ACY.
VPC.
EKT.
AAP, EKT.
EKT.
EKT.
EKT.
VPC.
VPC.
VPC .
AAP.
SDC.
ATL, BUC,
EKT, GAF, MAY, SDC, TRC, VPC.
DUP,
BUC,
GAF, HN, TRC.
EKT, GAF, SDC.
AAP
AAP
.AAP.
AAP, EKT, GAF, HN,
TRC.
DUP, EKT, HN, TRC.
AAP, GAF.
ICC, TRC.
TRC.
TRC.
DUP.
DUP.
EKT.
DYES
TABLE 2, —Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
DISPERSE DYES--Continued
*Disperse orange dyes --Continued
Disperse Orange 58
Disperse Orange 59
Disperse Orange 62
Disperse Orange 65
Disperse Orange 75
Disperse Orange 78
Disperse Orange 89
Disperse Orange 90
Disperse Orange 94
Other disperse orange dyes
*Disperse red dyes:
*Disperse Red 1
Disperse Red 4
•Disperse Red 5
Disperse Red 7
Disperse Red 9
'Disperse Red 11
Disperse Red 13
•Disperse Red 15
•Disperse Red 17
Disperse Red 21
Disperse Red 30
Disperse Red 51
Disperse Red 35
Disperse Red 54
•Disperse Red 55
Disperse Red 59
•Disperse Red 60
•Disperse Red 65
Disperse Red 66
Disperse Red 73
Disperse Red 78
Disperse Red 82
Disperse Red 86
Disperse Red 90
Disperse Red 96
Disperse Red 117
Disperse Red 133
Disperse Red 135
Disperse Red 136
Disperse Red 137
Disperse Red 138
Disperse Red 139
Disperse Red 140
Disperse Red 159
Disperse Red 161
Disperse Red 162
Disperse Red 167
Disperse Red 176
Disperse Red 177
Disperse Red 178
Disperse Red 179
Disperse Red 180
Other disperse red dyes
'Disperse violet dyes;
'Disperse Violet 1
•Disperse Violet 4
Disperse Violet 8
Disperse Violet 17
AAP
EKT
BUC
VPC
DUP
IRC
AAP
AAP
SDC
ALT
AAP
BUC
AAP
MP
AIL
AAP
GAF
CMC
AAP
EKT
EKT
ICC
EKT
ICC
DUP
ACY
AAP
DUP
AAP
TRC
ICC
VPC
EKT
VPC
ACY
EKT
VPC
AAP
EKT
EKT
EKT
VPC
AAP
VPC
DUP
DUP
GAF
ICC
ICC
ICC
ICC
ICC
DUP
AAP
AAP
GAF
DUP
EKT.
ICC.
DUP.
ATL, BUC, EKT, GAF, MAY, SDC.
DUP, EKT, GAF, HN, ICC, TRC.
GAF, TRC.
EKT, GAF, ICC.
GAF.
BUC, DUP, GAF, ICC.
ICC.
GAF, HSH, ICC, TRC.
DUP, EKT, GAF, ICC, TRC.
TRC.
GAF, HN, ICC, TRC.
DUP, GAF.
ATL, DUP, EKT, GAF, HN, SDC, TRC, VPC.
EKT, ICC, TRC.
TRC.
GAF.
EKT, GAF, MAY, SDC, TRC, VPC.
GAF, HSH, ICC, TRC.
GAF, ICC.
SY^ITHETIC ORGA^JIC CHEMICALS. 1<^72
TABLE 2,— Dyes for which U,S, production or sales were reported, identified
BY manufacturer, 1972--Conti nued
Manufacturers' identification codes
{according to list in table 3)
DISPERSE DYES- -Continued
et dyes--Continued
olet 2b
olet 27
olet 28
olet 40
olet 41
olet 42
olet 43
olet 44
olet 57
rse violet dyes
dyes:
ue 1
ue 3
ue 7
*Disperse vio
Disperse V
*Disperse V
Disperse V
Disperse V
Disperse V
Disperse V
Disperse V
Disperse V
Disperse V
Other dispe
*Disperse blue
*Disperse B
*Disperse B
*Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B,
Disperse b
Disperse B
'Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse K.
Disperse B
Disperse b
•Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Disperse B
Other disperse blue dyes-
Disperse green dyes
ue 27--
ue 35--
ue 54--
ue 55--
ue 56--
ue 60--
ue 61--
ue 62--
ue 64--
ue 70--
ue 71--
ue 72--
ue 75--
ue 79--
ue 81--
ue 85--
ue 94--
ue 95--
ue 102-
ue 109-
ue 112-
ue 116-
ue 117-
ue 118-
ue 119-
ue 120-
ue 121-
ue 123-
ue 125-
ue 132-
ue 133-
ue 138-
ue 139-
ue 150-
ue 152-
ue 165-
ue 166-
ue 172-
ue 173-
DUP.
AAP,
ACY,
DUP,
EKT,
ICC
TRC.
DUP,
TRC.
VPC.
EKT.
EKT.
EKT.
EKT.
trc.
GAP,
SDC.
AAP,
GAP,
ICC,
TRC
AAP,
DUP,
EKT,
GAP,
HN,
HSH, ICC, TRC.
DUP,
GAP,
HN,
ICC,
TRC.
HSU.
GAP.
EKT,
ICC.
ICI.
ICC.
TRC.
DUP,
ICC,
TRC,
VPC
DUP.
DUP.
DUP,
EKT,
GAP,
SDC
DUP,
EKT,
GAP,
TRC
AAP.
VPC.
ICI.
ACY,
ICC,
TRC.
EKT,
HST,
TRC
VPC.
TRC.
BAS.
GAP,
HST,
ICC
EKT.
DUP.
EKT.
ACY.
EKT.
EKT.
EKT.
EKT,
GAP.
EKT.
EKT.
TRC.
DUP.
DUP.
VPC.
VPC.
DUP.
HST.
VPC.
ICC.
DUP,
ICC.
AAP.
ALT,
ATL,
DUP
EKT
GAP,
HN, HSH, ICC, MAY, SDC
TRC, VPC.
GAP,
VPC.
DYES
TABLE 2. --Dyes for which U.S. production or sales were reported, identified
BY manufacturer, 1972--Continued
Manufacturers' identification codes
(according to list in table 3)
DISPERSE DYES--Continued
Disperse brown dyes;
Disperse Brown 1
Disperse Brown 2
Disperse Brown 7
Disperse Brown 8
Disperse Brown 11
Other disperse brown dyes
♦Disperse black dyes r
♦Disperse Black 1
Disperse Black 2
Disperse Black 9
Disperse Black 33
Disperse Black 34
Other disperse black dyes
FIBER-REACTIVE DYES
♦Reactive yellow dyes:
Reactive Yellow 1
Reactive Yellow 2
Reactive Yellow 3
Reactive Yellow 4
Reactive Yellow 6
Reactive Yellow 7
Reactive Yellow 13
Reactive Yellow 15
Reactive Yellow 17
Reactive Yellow 18
Reactive Yellow 24
Reactive Yellow 25
Reactive Yellow 31
Reactive Yellow 37
Reactive Yellow 42
Reactive Yellow 62
Reactive orange dyes:
Reactive Orange 1
Reactive Orange 4
Reactive Orange 5
Reactive Orange 12
Reactive Orange 13
Reactive Orange 14
Reactive Orange 16
Reactive Orange 49
Reactive Orange 50
Reactive red dyes:
Reactive Red 1
Reactive Red 2
Reactive Red 4
Reactive Red 5
Reactive Red 8
Reactive Red 11
Reactive Red 21
Reactive Red 29
Reactive Red 31
Reactive Red 33
Reactive Red 40
Reactive Red 41
Reactive Red 58
Reactive Red 94
Reactive Red 105
AAP, TRC.
DUP, EKT, GAF.
EKT.
VPC .
AAP.
CAP, ICC, SDC.
AAP, ATL, DUP, GAF, TRC.
ATL, TRC.
AAP, EKT.
EKT.
EKT.
ALT, ATL, BUC, DUP, GAF, ICC. SDC.
ICI.
TRC.
TRC.
ICI.
TRC.
ICI.
HST
UST .
HST.
ICI.
HST.
VPC.
HST.
HST.
ICI,
ACY.
ICI.
ICI.
TRC.
ICI.
ICI.
ICI.
HST.
ACY.
HST.
ICI.
ICI.
TRC.
ICI.
ICI.
ICI.
HST.
ICI.
ICI.
ICI.
VPC.
VPC.
ICI.
HST.
HST.
.SYNTHETIC nPGANIC CHEMICALS, W^.
TABLE 2,— Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURERj 1972~CoNTINUED
Dye
Manufacturers' identification codes
Caccording to list in table 3)
FIBER- REACTIVE DYES--Continued
Reactive violet dyes:
Reactive Violet 1
Reactive Violet 4
Reactive Violet 5
*Reactive blue dyes:
Reactive Blue 2
Reactive Blue 3
Reactive Blue 4
Reactive Blue 5
Reactive Blue 7
Reactive Blue 19
Reactive Blue 21
Reactive Blue 25
Reactive Blue 29
Reactive Blue 30
Reactive Blue 38
Reactive Blue 71
Reactive Blue 89
Reactive Blue 90
Reactive Blue 91
Reactive green dyes: Reactive Green 6
Reactive brown dyes:
Reactive Brown 9
Reactive Brown 10
Other reactive brown dyes
Reactive black dyes:
Reactive Black S
Reactive Black 9
FLUOROESCENT BRIGHTENING AGENTS
Fluoroescent Brightening Agent 1
Fluoroescent Brightening Agent 6
Fluoroescent Brightening Agent 8
Fluoroescent Brightening Agent 9
Fluoroescent Brightening Agent 22
Fluoroescent Brightening Agent 24
Fluoroescent Brightening Agent 25
*Fluoroescent Brightening Agent 28
Fluoroescent Brightening Agent 30
Fluoroescent Brightening Agent 33
Fluoroescent Brightening Agent 45
Fluoroescent Brightening Agent 46
Fluoroescent Brightening Agent 49
Fluoroescent Brightening Agent 52
Fluoroescent Brightening Agent 54
Fluoroescent Brightening Agent 59
Fluoroescent Brightening Agent 61
Fluoroescent Brightening Agent 68
Fluoroescent Brightening Agent 71
Fluoroescent Brightening Agent 75
Fluoroescent Brightening Agent 102
Fluoroescent Brightening Agent 108
Fluoroescent Brightening Agent 109
Fluoroescent Brightening Agent 114
Fluoroescent Brightening Agent 125
Fluoroescent Brightening Agent 126
Fluoroescent Brightening Agent 128
Fluoroescent Brightening Agent 130
ICI.
HST.
HST.
TRC.
ICI.
ICI.
ICI, TRC.
TRC.
HST.
HST.
ICI.
VPC.
VPC.
HST.
ICI.
HST.
HST.
HST.
ICI.
ICI.
ICI.
HST.
CGY.
ACY.
ACY.
ACY,
CGY.
CGY.
GAF.
ACY,
GAF.
GAF.
GAF.
CGY.
S.
s.
CGY.
CGY.
ACY.
CCW,
ACY,
GAF.
DUP,
GAF.
GAF-
VPC.
ACY.
SDH.
SDH.
ACY.
GAF, SDH.
CCW, DUP, SDH, VPC.
GAF.
GAF .
DYES
TABLE 2, —Dyes for which U.S, production or sales were reported^ identified
BY manufacturer, 1972--Conti nued
Manufacturers' identification codes
faccording to list in table 3}
FLUOROESCENT BRIGHTENING AGENTS--Continued
Fluoroescent Brightening Agent 158
Fluoroescent Brightening Agent 159
Other fluoroescent brightening agents
FOOD, DRUG, AND COSMETIC COLORS
foody Drug, and Cosmetic Dyes
FDSC Blue No. 1
FD6C Blue No. 2
FD5C Green No. 5
*FDf,C Red No. 2
*FD§C Red No. 3
FD8C Red No. 4
FD5C Red No. 40
FD6C Violet No. 1
*FD5C Yellow No. 5
*FD5C Yellow No. 6
Other food, drug, and cosmetic dyes
Drug and Cosmetic Dyes
D5C Blue No. 6
D5C Green No. 5
DiiC Green No. 6
D6C Green No. 8
*D5C Orange No. 4
DSC Orange No. 5
DSC Orange No. 10
DSC Orange No. 17
DSC Red No. 2
DSC Red No. 3
DSC Red No. 6
*DSC Red No. 7
DSC Red No. 8
DSC Red No. 9
DSC Red No. 10
DSC Red No. 11
DSC Red No. 12
DSC Red No. 13
DSC Red No. 17
*D6C Red No. 19
*DSC Red No. 21
DSC Red No. 22
DSC Red No. 27
DSC Red No. 28
DSC Red No. 30
DSC Red No. 31
DSC Red No. 33
DSC Red No. 34
*D6C Red No. 36
DSC Red No. 37
DSC Red No. 59
DSC Violet No. 2
DSC Yellow No. 5
DSC Yellow No. 6
DSC Yellow No. 7
DSC Yellow No. 8
DSC Yellow No. 10
DSC Yellow No. 11
ACY.
ACY.
ACY, CCW, CGY, GAF, PCW,
ACS,
ALT,
KON,
SDH,
WJ.
ACS,
ALT,
KON,
SDH,
WJ.
WJ.
ACS,
ALT,
KON,
SDH,
STG
ACS,
ALT,
KON,
SDH,
STG
ALT,
KON
ACS,
WJ.
ACS,
SDH,
WJ.
ACS,
ALT,
KON,
STG.
WJ.
ACS,
ALT,
KON,
SDH,
STG
STG.
ACS,
KON.
ACS,
KON.
ACS,
KON.
KON,
SDH.
ACS,
KON,
SNA, TMS
SNA,
TMS.
TMS.
SNA.
KON.
KON,
TMS.
KON,
SNA,
TMS.
KON,
SNA,
TMS.
KON,
SNA.
KON,
SNA,
TMS.
KON,
SNA.
KON,
SNA.
SNA,
TMS.
SNA,
TMS.
KON.
ACS,
KON,
SNA, TMS
KON,
SNA,
TMS.
ACS,
KON,
SDH.
TMS.
ACS,
TOS.
KON,
TMS.
KON.
ACS,
KON.
KON.
ALT,
KON,
TMS.
.\CS.
SDH.
ACS.
KON.
KON.
KON.
KON.
KON.
ACS,
KON.
SYNTHETIC ORGVIIC CHEHICUS, 1972
TABLE 2.— Dyes for which U.S. production or sales were reported, identified
BY manufacturer, 1972— Conti nued
Manufacturers' identification codes
(according to list in table 3J
FOOD, DRUG, AND COSMETIC COLORS--Cont inued
Drug and Cosmetic Dyes, External
Ext. D5C Green No. 1
Ext. DSC Yellow No. 1
Ext. D6C Yellow No. 7
INGRAIN DYES
Ingrain blue dyes:
Ingrain Blue 1
Ingrain Blue 2
Ingrain Blue 3
MORDANT DYES
♦Mordant yellow dyes:
Mordant Yellow 1
Mordant Yellow 5
Mordant Yellow 8
Mordant Yellow 14
Mordant Yellow 16
Mordant Yellow 20
Mordant Yellow 26
Mordant Yellow 29
Mordant Yellow 30
Mordant Yellow 36
*Mordant orange dyes :
Mordant Orange 1
Mordant Orange 4
Mordant Orange 6
Mordant Orange 8
'Mordant red dyes :
Mordant Red 3
Mordant Red 7
Mordant Red 9
Mordant Red 11
Mordant Red 64
Mordant violet dyes: Mordant Violet S
Mordant blue dyes:
Mordant Blue 1
Mordant Blue 3
Mordant Blue 9
Mordant Blue 19
Mordant green dyes: Mordant Green 36
•Mordant brown dyes :
*Mordant Brown 1
Mordant Brown 12
Mordant Brown 13
Mordant Brown 15
Mordant Brown 18
Mordant Brown 19
Mordant Brown 21
*Mordant Brown 33
Mordant Brown 40 >-
Mordant Brown 63
Mordant Brown 70
•Mordant black dyes:
Mordant Black 3
Mordant Black 8
Mordant Black 9
•Mordant Black 11
Mordant Black 13
•Mordant Black 17
Mordant Black 19
Mordant Black 26
Other mordant black dyes
ACS, KON.
ACS, KON.
KON.
ICI.
VPC.
ICI.
ATL
TRC
ACS
ACS
ACY
ACS
VPC
GAP
TRC
PDC
ACY
GAP
ATL
TRC
ACY
ACY
MRX
ACY
PDC
PDC
GAP
GAP
CMC
PDC
ACS
PDC
ACS
GAP
ACS
GAP
GAP
ACS
CMG
TRC
DUP
TRC
VPC
ACS
ACS
HSH
ACS
PDC
TRC
CMG
GAP, PDC.
PDC.
PDC.
ATL.
ATL.
PDC, TRC.
PDC.
GAP, PDC, TRC.
ATL, BDO, GAP, PDC, TRC.
PDC,
CMG, DUP, GAP, TRC, YAW.
VPC.
GAP, PDC, TRC.
GAP.
.^TL, VPC.
ATL, GAP, TRC, VPC.
ACY, GAP, TRC.
DYES
TABLE 2.— Dyes for which U.S. production or sales were reported, identified
BY manufacturer, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
OXIDATION BASES
Oxidation Base 8 and 8A
Oxidation Base 21
Oxidation Base 22
Oxidation Base 25
Other oxidation bases
SOLVENT DYES
'Solvent yellow dyes:
Solvent Yellow 1
Solvent Yellow 2
Solvent Yellow 3
Solvent Yellow 13
♦Solvent Yellow 14
Solvent Yellow 19
Solvent Yellow 29
Solvent Yellow 30
Solvent Yellow 33
Solvent Yellow 34
Solvent Yellow 40
Solvent Yellow 42
Solvent Yellow 43
Solvent Yellow 44
Solvent Yellow 45
Solvent Yellow 47
Solvent Yellow 56
Solvent Yellow 71
Solvent Yellow 72
Solvent Yellow 87
Other solvent yellow dyes
'Solvent orange dyes:
Solvent Orange 2
'Solvent Orange 3
Solvent Orange 5
Solvent Orange 7
Solvent Orange 20
Solvent Orange 23
Solvent Orange 24
Solvent Orange 25
Solvent Orange 31
Solvent Orange 48
Solvent Orange 51
Other solvent orange dyes
'Solvent red dyes:
Solvent Red 1
Solvent Red 8
Solvent Red 22
Solvent Red 24
'Solvent Red 26
Solvent Red 27
Solvent Red 33
Solvent Red 35
Solvent Red 40
Solvent Red 41
'Solvent Red 49
Solvent Red 52
ACY.
PDC.
ACY.
ACY.
ACY.
AAP.
DUP,
GAF,
PSC.
ACS,
PSC.
ACY,
GAF.
AAP,
ACS,
ACY,
DUP, GAF, PSC
GAF.
GAP.
ACS.
AAP,
ACS,
ACY.
DSC.
ACS.
ACS.
GAF.
ACS.
ACS.
ACY,
DUP,
GAF.
AAP,
ACS,
ACY.
ACY.
ACY.
ACY.
AAP,
ATL,
DSC,
PAT.
PSC.
AAP,
.ACS,
ACY,
DSC, GAF, PSC
GAF.
ACS,
ACY,
GAF.
ACY,
GAF.
ACS.
DUP.
ACY,
DUP
ACS.
ACY.
ACY.
AAP,
ACY,
DSC,
DUP.
PSC.
GAF.
GAF.
ACY,
DUP
GAF.
AAP,
ACS,
ACY,
PSC.
ACS.
DUP,
GAF
GAF.
GAF.
DSC.
ACY,
DSC,
DUP,
GAF.
AAP,
ICI
SYNTHETIC ORGANIC CHEMICALS, 197?
TABLE 2,— Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
SOLVENT UYES--Continued
*Solvent red dye5--Continued
Solvent Red 68
Solvent Red 69
Solvent Red 74
Solvent Red 75
Solvent Red 105
Solvent Red 108
Solvent Red 111
Solvent Red 115
Solvent Red 126
Other solvent red dyes
Solvent violet dyes:
Solvent Violet 8
Solvent Violet 9
Solvent Violet 13
Solvent Violet 14
Solvent Violet 17
Other solvent violet dyes-
*Solvent blue dyes:
Solvent Blue 3
Solvent Blue 4
Solvent Blue 5
Solvent Blue 6
Solvent Blue 7
Solvent Blue 9
Solvent Bl
Solvent Bl
Solvent Bl
Solvent Bl
Solvent Bl
*Solvent Bl
Solvent Bl
Solvent Bl
Solvent Bl
Solvent Bl
Solvent Blue 74
Other solvent blue dyes--
Solvent green dyes:
Solvent Green 1
*Solvent Green 3
Other solvent green dyes-
Solvent brown dyes :
Solvent Brown 11
'Solvent Brown 12
Solvent Brown 19
Solvent Brown 20
Solvent Brown 22
Solvent Brown 38
Other solvent brown dyes-
Solvent black dyes:
Solvent Black 3
Solvent Black 5
Solvent Black 7
Solvent Black 12
Solvent Black 13
Solvent Black 17
Solvent Black 26
Other solvent black dyes-
ue
11
ue
12
ue
16
ue
36
ue
37
ue
38
ue
43
ue
57
ue
58
ue
59
ACS.
DSC,
DUP.
ACS.
ACS.
ACY.
ACY.
ACY.
ACY.
ACY.
AAP,
ACY,
ATL,
DSC,
ICI, PAT
ACY,
DSC,
DUP.
DSC.
AAP.
ATL,
HSH,
ICl.
AAP,
ICI.
ACS.
AAP,
DSC,
PAT.
ACY,
SW.
DSC,
DUP.
DSC.
DSC.
ACY.
GAP.
BDO,
GAP,
ICI.
ACS,
BDO.
ACS.
AAP,
DUP.
DUP.
ACS,
ACY,
ATL,
DUP,
GAP.
ACS.
DUP.
ACY.
ACY.
ACS.
ACY,
DSC,
GAP,
PAT,
SDH.
ACY,
DSC.
AAP,
ACS,
ATL,
GAP,
HSH, PAT
DSC,
GAP.
GAP.
ACY,
DSC,
GAP.
DUP.
ACY.
DUP.
DUP,
PSC.
ACY.
DSC.
ACS.
ACS,
ACY,
DSC,
DUP.
ACS,
ACY,
DSC.
ACS.
ACS.
DUP.
ACY.
ATL,
DSC,
GAP,
PAT.
DYES
TABLE 2. —Dyes for which U.S. production or sales were reported, identified
BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
SULFUR DYES
Sulfur yellow dyes:
Leuco Sulfur Yellow 1
Leuco Sulfur Yellow 2
Sulfur Yellow 4
Leuco Sulfur Yellow 4
Leuco Sulfur Yellow 9
Leuco Sulfur Yellow 15
Other sulfur yellow dyes
Sulfur Orange 1
Sulfur red dyes ;
Leuco Sulfur Red S
Other sulfur red dyes
Sulfur blue dyes:
Sulfur Blue 5
Sulfur Blue 7
Leuco Sulfur Blue 7
Solubilized Sulfur Blue 7
Sulfur Blue 8
Leuco Sulfur Blue 8
Sulfur Blue 9
Leuco Sulfur Blue 11
Leuco Sulfur Blue 13
Other sulfur blue dyes
Sulfur green dyes:
Sulfur Green 2
Leuco Sulfur Green 2
Leuco Sulfur Green 3
Sulfur Green 14
Leuco Sulfur Green 16
Other sulfur green dyes
Sulfur brown dyes:
Leuco Sulfur Brown 1
Solubilized Sulfur Brown 1
Leuco Sulfur Brown 3
Sulfur Brown 10
Leuco Sulfur Brown 10
Solubilized Sulfur Brown 10
Sulfur Brown 12
Sulfur Brown 14
Leuco Sulfur Brown 14
Leuco Sulfur Brown 20
Sulfur Brown 26
Leuco Sulfur Brown 26
Sulfur Brown 37
Solubilized Sulfur Brown 37
Leuco Sulfur Brown 81
Leuco Sulfur Brown 82
Other sulfur brown dyes
Sulfur black dyes:
Sulfur Black 1
Leuco Sulfur Black 1
Solubilized Sulfur Black 1
Sulfur Black 2
Leuco Sulfur Black 2
Solubilized Sulfur Black 2
Leuco Sulfur Black 10
Sulfur Black 11
Leuco Sulfur Black 11
Other sulfur black dyes
SDC.
ACY, SDC.
SDC.
SDC.
SIC.
AC\ .
ACY, SDC.
SIC.
SDC.
SDC.
ACY.
ACY, SDC.
ACY, SDC, SIC.
SDC.
SDC.
SDC.
SDC.
SDC.
ACY.
SDC.
SDC.
SDC.
SDC.
SDC.
SDC.
ACY, SDC.
SIC.
SIC.
SDC.
SDC.
SDC, STC.
SDC.
SDC.
SDC.
SDC.
STC.
ACY.
STC.
SDC.
SDC.
ACY.
ACY.
ACY, SDC.
SDC.
ACY, SDC, STC.
STC.
SDC.
ACY, SDC.
SDC.
ACY.
SDC.
SDC.
SDC.
SYNTHETIC ORGANIC CHEMICALS. 1972 '
TABLE 2. --Dyes for which U.S. production or sales were reported, identified
BY manufacturer. 1972--Continued
Manufacturers' identification codes
(according to list in table 3J
VAT DYES
*Vat yellow dyes:
Vat Yellow 1, 12-1/2%
*Vat Yellow 2. 8-1/2°.
Vat Yellow 3, 12-l/2°6
*Vat Yellow 4, 12-1/2%
Solubilized Vat Yellow 4, 37-1/2°*
Vat Yellow 10, 10%
Vat Yellow 14, 12-1/2%
Vat Yellow IS, 11-1/2%
Vat Yellow 21, 9-1/2%
Vat Yellow 22, 10%
Vat Yellow 33, 15%
Other vat yellow dyes
*Vat orange dyes:
*Vat Orange 1, 20%
Solubilized Vat Orange 1, 26%
*Vat Orange 2, 12%
*Vat Orange 3, 13-1/2%
Vat Orange 4, 6%
Vat Orange 5, 10%
Solubilized Vat Orange 5, 30%
Vat Orange 7, 11%
*Vat Orange 9, 12%
Vat Orange 11, 6%
*Vat Orange 15, 10%
Other vat orange dyes
*Vat red dyes:
*Vat Red 1, 13%
Solubilized Vat Red 1, 37%
Vat Red 10, 18%
Vat Red 12, 8-1/2%
*Vat Red 13, 11%
Vat Red 14, 10%
Vat Red 15, 10%
Vat Red 16, 11%
Vat Red 23
Vat Red 29, 18%
Vat Red 32, 20%
Vat Red 41, 20%
Vat Red 52, 10%
Other vat red dyes
*Vat violet dyes:
*Vat Violet 1, 11%
Vat Violet 2, 20%
Vat Violet 3, 15%
*Vat Violet 9, 12%
*Vat Violet 13, 6-1/4%
Vat Violet 14, 12-1/2%
Vat Violet 17, 12-1/2%
Vat Violet 21
Other vat violet dyes
*Vat blue dyes:
Vat Blue 1, 20%
Vat Blue 4, 10%
Vat Blue 5, 16%
*Vat Blue 6, 8-1/3%
Solubilized Vat Blue 6, 17-1/2%--
Vat Blue 12, 6-1/2%
Vat Blue 14, 8-1/3%
Vat Blue 16, 16-1/2%
ACS
AAP
DUP
ATL
HST
GAF
IRC
ACY
ATL
DUP
TRC
GAF
ACY
HST
ACY
DUP
DUP
HSi
HST
GAF
ACY
DUP
AAP
SDC
AAP
HST
GAF
DUP
DUP
GAF
HST
DUP
DUP
GAF
DUP
HST
DUP
TRC
ACY
ACY
HST
DUP
ATL
ATL
DUP
VPC
GAF
ACS
ACY
ATL
ACY
HST
DUP
DUP
DUP
ATL, GAF, ICI, TRC, VPC.
GAF, HST, VPC.
ICI.
VPC.
MAY, VPC.
ATL, DUP, GAF, HST, ICl, IRC, VPC.
DUP, GAF, ICI, TRC.
GAF, HST.
HST, TRC.
DUP, GAF, ICl, TRC.
ACS, ACY, GAF, ICI, TRC, VPC.
ATL, ACY, HST, ICl.
GAF, TRC.
HST.
TRC.
ATL, DUP, GAF, ICI, MAY, TRC.
HST.
GAF, ICI, MAY, TRC.
DUP, GAF, HST, ICI, TRC.
DUP, GAF.
HST.
DUP, GAF, ICl, TRC.
DYES
TABLE 2.— Dyes for which U.S. production or sales were reported, identified
BY manufacturer, 1972— CONTINUED
VAT DYES--Continued
"Vat blue dyes --Continued
*Vat Blue 18, 13%
Vat Blue 20, 14%
Vat Blue 29
Vat Blue 39, n".,
Vat Blue 43
Vat Blue 53, 20-1/2%
Vat Blue 60
Vat Blue 67
Other vat blue dyes
*Vat green dyes:
*Vat Green 1, 6%
Solubilized Vat Green 1, 12-1/2-0
*Vat Green 3, lOi
Solubilized Vat Green 3, 26%
Vat Green 8, 8-1/2%
Vat Green 9, 12-1/2%
Vat Green 20, 6%
Vat Green 32
Other vat green dyes
*Vat brown dyes:
*Vat Brown 1, 11%
*Vat Brown 3, 11%
Vat Brown 5, 13%
Vat Brown 11, 12%
Vat Brown 12, 12-1/2%
Vat Brown 13, 17%
Vat Brown 20, 10-1/2%
Vat Brown 28, 22%
Vat Brown 29, 13%
Vat Brown 40, 14%
Vat Brown 57, 12.8%
Other vat brown dyes
*Vat black dyes:
Solubilized Vat Black 1, 27-1/2%
Vat Black 9, 16%
Vat Black 13, 14%
Vat Black 22, 19%
*Vat Black 25, 12-1/2%
*Vat Black 27, 12-1/2%
Vat Black 34, 16%
Vat Black 37
Vat Black 38, 20%
Vat Black 52, 18-1/2%
Other vat black dyes
All other dyes
Manufacturers' identification codes
[according to list in table 3J
AAP,
ACY
.AAP.
■ACS
GAP.
GAP.
SDC.
GAP.
DUP.
HST.
CAF,
MAY
ACY,
DUP
ICI.
AAP,
ACY
ICI.
ATL,
DUP
ACY,
ATL
DUP.
VPC.
ACY,
GAP
ACY,
DUP
AAP,
ACY
ACY,
HST
MAY,
TRC
DUP.
MAY.
GAP.
ICI.
ACY.
DUP.
HST,
TRC
GAP,
SDC
HST.
GAP,
MAY
DUP.
ACY.
TRC
AAP,
ACY
ACY,
BDO
ICI.
GAP.
GAP.
ACY.
ATL,
GAP
ATL, DUP, GAP, MAY, TRC.
ACY, ATL, DUP, GAP, MAY, SDC. TRC.
GAP, ICI, MAY, TRC.
ATL, DUP, GAP, ICI, MAY, TRC.
GAP.
GAP, HST, MAY, SDC, TRC.
GAP, ICI, MAY, TRC.
DUP, GAP, ICI, TRC, VPC.
DUP, GAP, ICI, MAY, TRC.
DUP, GAP, ICI, MAY, TRC.
MAY, SDC, TRC.
ACY, DUP, GAP, HSH, PAT, SDC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3, --Dyes; Directory of manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of dye manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are listed bela
in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
AAP
American Aniline Products, Inc.
ICC
Inmont Corp.
ACS
Allied Chemical Corp., Specialty Chemicals
Div.
ICI
ICI America, Inc.
ACY
American Cyanamid Co.
ALL
Alliance Chemical, Inc.
ALT
Crompton 5 Knowles Corp., Dyes § Chemicals
Div.
KON
H. Kohnstamm 6 Co., Inc.
ATL
Atlantic Chemical Corp.
MAY
MRX
Otto B. May, Inc.
Max Marx Color § Chemical Co.
BAS
BASF Wyandotte Corp.
EDO
Benzenoid Organics, Inc.
sue
Blackman-Uhler Chemical Co.
PAT
Morton-Norwich Products, Inc., Morton
Co. Div.
Chemical
PCW
Pfister Chemical Works
CCW
Cincinnati Malacron Chemicals, Inc.
PDC
Berncolors-Poughkeepsie, Inc.
CGY
Ciba-Geigy Corp.
PSC
Passaic Color g Chemical Co.
CNG
Nyanza, Inc.
CPC
Childs Pulp Colors, Inc.
S
Sandoz, Inc., Sandoz Color 6 Chemical
5 Div.
SDC
Martin-Marietta Corp., Sodyeco Div.
DSC
Dye Specialties, Inc.
SDH
Sterling Drug, Inc., Hilton-Davis Ch
smical
DUP
E. I. duPont de Nemours § Co., Inc.
SNA
STC
STG
Co. Div.
Sun Chemical Corp.
Sou-Tex Chemical Co., Inc.
Stange Co.
EKT
Eastman Kodak Co. , Tennessee Eastman
Co. Div.
sw
Sherwin-Williams Co.
FAB
Fabricolor Manufacturing Corp.
TMS
TRC
Sterling Drug, Inc., Thomasset Colors
Toms River Chemical Corp.
Div.
GAF
GAF Corp., Chemical Div.
VPC
Baychem Corp., Verona Div.
HN
Tenneco Chemicals, Inc.
use
Chemetron Corp., Pigments Div.
WJ
Warner-Jenkinson Manufacturing Co.
HSH
Harshaw Chemical Co. Div. of Kewanee
Oil Co.
HST
American Hoechst Corp.
YAW
Y. S. Young, Young Aniline Works Div.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix
91
ORGANIC PIGMENTS
As the terms are used in this report, organic pigments are toners
and lakes derived in whole or in part from benzenoid chemicals and colors.
Statistics on production and sales of all organic pigments in 1972
are given in table 1. 1/ Statistics on sales of a few selected pigments
by commercial forms (dry full-strength form, dry extended form, dry dis-
persions, aqueous dispersions, and flushed colors) are given in table lA.
Individual toners and lakes are identified in this report by the names
used in the third edition of the Colour Index.
Total production of organic pigments in 1972 was 65.9 million pounds--
13.0 percent more than the 58.3 million pounds produced in 1971 and 16.6
percent more than the 56.5 million pounds produced in 1970. Total sales
of organic pigments in 1972 amounted to 53.2 million pounds, valued at
$149.3 million, compared with 47.1 million pounds, valued at $130.0 mil-
lion, in 1971 and 47.2 million pounds, valued at $123.0 million, in 1970.
In terms of quantity, sales of organic pigments in 1972 were 13.1 percent
greater than in 1971 and 12.8 percent greater than in 1970; in terms of
value, sales in 1972 were 14.9 percent greater than in 1971 and 21.5 per-
cent greater than in 1970.
Production of toners in 1972 amounted to 62.9 million pounds--14.1
percent more than the 55.1 million pounds reported for 1971. Sales in
1972 were 50.5 million pounds, valued at $145.9 million, compared with
44.2 million pounds, valued at $126.6 million, in 1971. Sales in 1972
were thus 14.1 percent more than those in 1971 in terms of quantity,
and 15.3 percent more in terms of value. The individual toners listed
in the report which were produced in the largest quantities in 1972
were Pigment Yellow 12, 6.5 million pounds; Pigment Blue 15, beta form,
6.0 million pounds; and Pigment Red 49, barium toner, 4.6 million pounds.
Production of lakes totaled 3.0 million pounds in 1972--6.8 percent
less than the 3,2 million pounds reported for 1971. Sales of lakes in
1972 amounted to 2.7 million pounds, valued at $3.4 million, compared
with sales in 1971 of 2.8 million pounds, valued at $3.4 million. Sales
in 1972 were thus 3.4 percent less than those in 1971 in terms of quantity ^
and substantially unchanged in terms of value.
For each of 15 selected pigments, or groups of pigments, table lA
gives data on sales by commercial forms. Pigment Yellow 12, Pigment Red
53, Pigment Blue 15, beta form, and Pigment Blue 19 were sold principally
in the flushed form. The remaining 7 pigments, or groups of pigments,
for which statistics are published were sold principally in the dry full-
strength form. Statistics on sales by commercial forms could not be
published for Pigment Red 49, calcium toner. Pigment Red 49, sodium toner.
Pigment Red 90, and Pigment Violet 3, fugitive, without revealing the
operations of individual companies.
1/ See also table 2 which lists these products and identifies the manu-
facturers by codes. These codes are listed in table 3.
SYNTHETIC ORGANIC CHEMICALS. 1972.
TABLE 1,— Organic pigments: U.S. production and sales. 1972
[Listed below are all organic pigments for which any reported data on production or sales may be published. (Leaders
^ are used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all organic pigments for which data on production or sales were reported and identifies the manufac-
turers of each]
Pigment
Grand total -
Total-
Yellow toners, total
Acetoacetarylide yellows;
Pigment Yellow 1, C.I. 11 680--
Pigment Yellow 3, C.I. 11 710--
Pigment Yellow 74, C.I. 11 741-
Benzidine yellows, total
Pigment Yellow 12, C.I. 21 090-
Pigment Yellow 14, C.I. 21 095-
Pigment Yellow 17, C.I. 21 105-
Other benzidine yellows
AH other ^
Orange toners, total -
Pigment Orange 5, C
Pigment Orange 13,
Pigment Orange 16,
Pigment Orange 34,
All other
12 075--
. 21 110-
. 21 160-
. 21 115-
Red toners, total
Naphthol reds, total
Pigment Red 2, C.l. 12 310
Pigment Red 5, C.I. 12 490
Pigment Red 17, C.I. 12 390
Pigment Red 22, C.I. 12 315
Pigment Red 23, C.I. 12 355
Other naphthol reds
Pigment Red 1, C.I. 12 070, dark
Pigment Red 1, C.l. 12 070, light
Pigment Red 3, C.I. 12 120
Pigment Red 4, C.I. 12 085
Pigment Red 38, C.I. 21 120
Pigment Red 48, C.I. 15 865
Pigment Red 49, C.l. 15 630:
Barium toner
Calcium toner
Sodium toner
Pigment Red 52, C.I. 15 860
Pigment Red 53, C.l. 15,585, barium toner--
Pigment Red 54, C.I. 14 830, calcium toner-
Pigment Red 57, C.I. 15 850, calcium toner-
Pigment Red 63, C.I. 15 880
Pigment Red 81, C.I. 45 160, PMA
Pigment Red 81, C.I. 45 160, PTA
Pigment Red 90, C.I. 45 380
Pigment Red 122
All other
1,000
pounds
14,110
662
297
1,038
10,442
6,473
2,139
573
1,257
1,671
1,593
319
124
562
Quantity
1,000
pounds
141
276
477
76
108
,051
360
185
4,555
1,328
1,559
2,799
1,479
52
572
131
1,864
115
2,310
10,239
462
163
600
7,477
4,103
1,961
416
997
1,537
1,463
331
177
300
117
538
105
247
322
73
91
1,665
360
165
2,816
4,289
1,297
74
1,477
2,146
81
1,236
45
534
107
1,046
105
1,730
1,000
dollars
28,982
979
391
1,413
18,682
8,284
4,698
1,224
4,476
7,517
5,795
594
620
863
452
3,266
43,790
3,172
124
263
187
347
839
1,412
110
134
2,949
597
727
5,816
4,880
1,595
88
2,476
3,237
2,190
1,418
9,101
See footnotes at end of table.
ORGANIC PIGMENTS
TABLE 1, --Organic pigments; U.S. production and sales, 1972--Continued
Pigment
Production
Quantity
Unit
value'
1,000
pounds
TONERS--Continued
Violet toners, total
Pigment Violet 1, C.I
Pigment Violet 1 , C.I
Pigment Violet 3, C.I
Pigment Violet 3, C.I
Pigment Violet 3, C.I
Pigment Violet 23, C.
All other
45 170, PMA
45 170, PTA
42 535, fugitive-
42 535, PMA
42 535, PTA
. 51 319
Blue toners
Pigment B
Pigment B
Pigment B
Pigment B
Pigment
Pigment B
All other
total
lue 1, C.I. 42 595, PMA
lue 14, C.I. 42 600, PMA.
lue 15, C.I. 74 160, alpha form-
lue 15, C.I. 74 160, beta form--
lue 19, C.I. 42 750A
lue 25, C.I. 21 180
Green toners, total -
Pigment Green 1, C.I. 42 040, PMA
Pigment Green 2, C.I. 42 040 and 49 005, PMA-
Pigment Green 2, C.I. 42 040 and 49 005, PTA-
Pigment Green 7, C.I. 74 260
Pigment Green 8, C.I. 10 006
Pigment Green 36, C.I. 74 265
All other
Brown toners, total
Pigment Brown 5, C.I. 15 800-
AII other
Black toners -
LAKES
Total
Yellow lake: (Acid Yellow 23), C.I. 19 140-
Orange lakes
Red lakes:
Pigment Red 60, C.I. 16 105-
Pigment Red 83, C.l. 58 000-
Violet lake: Pigment Violet 5, C.I. 58 055-
AIl other lakes'
225
1,164
184
83
4,394
6,008
4,484
30
335
4.216
62
35
3,305
153
263
383
132
3,019
296
56
127
2,471
1,000
pounds
1,000
dollars
74
831
359
47
215
1,042
12,066
153
116
3,641
4,523
3,353
280
3,665
64
42
2,956
107
271
210
112
126
2,044
16,382
506
524
1,021
1,156
222
3,122
9,831
36,444
749
560
11,466
14,145
8,022
1,502
14,122
66
348
216
10,991
153
1,122
1,226
218
346
40
382
201
339
2,094
1 Calculated from rounded figures.
2 Includes "all other" acetoacetarylide yellows.
3 Includes all black, blue, brown, and green lakes, and "all other" red, violet, and yellow lakes.
Note. --The C.I. (Coloui' Index) numbers shown in this report are the identifying numbers given in the third editic
of the Colour Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic]
acids, respectively.
552-743 0-74-7
SYNTHETIC ORGANIC CHENICALS. 1972
TABLE lA.— U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions,
AQUEOUS dispersions, AND FLUSHED COLORS, 1972
Selected pigments by commercial forms
Quantity'
Unit
value
Pigment Yellow 12, C.I. 21 090, total --■
Dry full- strength toner
Aqueous dispersions
Dry extended toner, dry dispersions, and flushed color
Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment
Yellow 17, C.I. 21 105; and other benzidine yellows, total
Dry full -strength toner
Dry extended toner and dry dispersions"
Aqueous dispersions
Flushed color
Pigment Red 3, C.I. 12 120, total
Dry full-strength toner and dry extended toner '*.-- -^
Aqueous dispersions^
Flushed color
Pigment Red 48, C.l. 15 865, total
Dry full-strength toner, dry extended toner, and dry dispersions'*
Aqueous dispersions 'and flushed color"
Pigment Red 49, C.l. 15 630, barium toner, total
Dry full-strength toner, dry extended toner, and aqueous dispersions ''
Flushed color
Pigment Red 53, C.I. 15 585, barium toner, total
Dry full-strength toner and dry dispersions ''•
Aqueous dispersions 'and flushed color"
Pigment Violet 3, C.l. 42 535, PMA and PTA, total
Dry full -strength toner
Dry extended toner and aqueous dispersions ' '*
Flushed color
Pigment Blue 15, C.I. 74 160, alpha form, total
Dry full -strength toner
Dry extended toner and dry dispersions"
Aqueous dispersions
Flushed color
Pigment Blue 15, C.I. 74 160, beta form, total
Dry full -strength toner
Dry extended toner and dry dispersions '*
Aqueous dispersions ^
Flushed color
1,000
pounds
4,103
2,978
651
224
994
118
2,605
211
3,747
542
978
,168
3,641
1,421
1,085
802
333
4,523
1,410
575
961
1,577
1,000
dollars
2,240
63
6,327
10,473
8,064
124
1,659
626
3,061
1,759
211
1,091
5,816
5,362
434
4,223
770
1,456
1,825
1,079
112
11,467
5,025
3,703
1,903
836
14,231
4,690
2,061
2,585
4,895
Per
pound
$2.10
2.33
2.12
2.38
2.55
2.07
2.06
1.49
1.56
3.74
3.57
8.00
3.66
3.15
See footnotes at end of table.
ORGANIC PIGMENTS
ABLE 1A.--U.S. SALES of selected dry full-strength colors, dry extended colors, dry dispersions,
AQUEOUS dispersions, AND FLUSHED COLORS, 1972--CONTINUED
Selected pigments by commercial forms
Quantity'
Unit
value
1,000
pounds
Pigment Blue 19, C.I. 45 750A, total
Dry full-strength toner and aqueous dispersions 3
Flushed color
Pigment Green 7, C.I. 74 260, total
Dry full-strength toner
Dry extended toner
Dry dispersion
Aqueous disperions' and flushed color'*
3,355
1,000
dollars
S,022
3,067
2,956
10,991
1,264
490
4, 877'
1,966
275
3,873
Per
pound
$2.39
2.72
2.36
3.86
4.01
' Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content.
^ Calculated from rounded figures.
^ Includes presscake.
'* Separate data on these commercial forms may not be published without revealing the operations of individual
companies.
Note. --The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the third edition
of the Colour Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic)
acids, respectively.
S'iYTHETlC mMK CHEMICALS, 197'^
TABLE 2, --Organic pigments for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Organic pigments for which separate statistics are given in table 1 are marked below with an asterisk (*) ; products
not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be pub-
lished. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufac-
turer did not consent to his identification with the designated product]
Pigment
Manufacturers' identification codes
(according to list in table 3^
*Yellow toners:
Acetoacetarylide yellows:
♦Pigment Yellow 1, C.I. 11 680-
11 710
11 665
11 660
11 670
11 720
♦Pigment Yellow 3, C.I.
Pigment Yellow 4, C.I.
Pigment Yellow 5, C.I.
Pigment Yellow 6, C.I.
Pigment Yellow 9, C.I.
Pigment Yellow 49, C.I. 11 765
Pigment Yellow 65
Pigment Yellow 73, C.I. 11 738
♦Pigment Yellow 74, C.I. 11 741
Pigment Yellow 75, C.I. 11 770
All otlier acetoacetarylide yellows-
*Benzidine yellows:
♦Pigment Yellow 12, C.I. 21 090
Pigment Yellow 13, C.I. 21 100-
♦Pigment Yellow 14, C.I. 21 095-
♦Pigment Yellow 17, C.I. 21 105-
Pigment Yellow 76
Pigment Yellow 83
All other benzidine yellows
Pigment Yellow 10, C.I. 12 710
Pigment Yellow 16, C.I. 20 040
Pigment Yellow 24
Pigment Yellow 97
Pigment Yellow 108, C.I. 68 420
Pigment Yellow 123
(Basic Yellow 2), C.I. 41 000 fugitive-
All other
♦Orange toners :
Pigment Orange 1, C.I. 11 725
Pigment Orange 2, C.I. 12 060
♦Pigment Orange 5, C.I. 12 075
♦Pigment Orange 13, C.I. 21 110
Pigment Orange 15, C.I. 21 130
♦Pigment Orange 16, C.I. 21 160
♦Pigment Orange 34, C.I. 21 IIS
Pigment Orange 38
Pigment Orange 43, C.I. 71 105
(Vat Orange 3), C.I. 59 300
(Vat Orange 4), C.I. 59 710
All other
♦Red toners :
♦Naphthol reds:
♦Pigment red 2, C.I. 12 310
♦Pigment Red 5, C.I. 12 490
Pigment Red 7, C.I. 12 420
Pigment Red 9, C.I. 12 460
Pigment Red 10, C.I. 12 440
Pigment Red 13, C.I. 12 395
Pigment Red 15, C.I. 12 465
♦Pigment Red 17, C.I. 12 390
Pigment Red 18, C.I. 12 350
ACS,
S,
ACS,
ACS,
CIK,
HPC.
SNA.
HPC,
ACS.
ACS,
DUP,
HPC.
DUP,
ACY, AMS, DUP, HPC, HSC, HSH, HST, ICI, KON,
SDH, SNA, SW.
HPC, HSH, HST, KCW, KON, PPG, SW.
HSC.
HPC.
CIK, HPC, SNA.
HPC, HSC, SDH, SNA, SW.
KCW.
ACS, ACY, AMS, APO, CIK, DUP, HPC, HSC, HSH, HST,
ICC, KON. LVY, ROM, S, SDH, SNA, SW.
APO, sue, GAP, HPC, HSH, HST, ICC, ROM, SDH, SNA.
ACS, ACY, AMS, BUC, CIK, CPC, DUP, GAF, HPC, HSC,
HSH, HST, ICC, ROM, S, SDH, SNA, x.
ACS, AMS, BUC, GAF, HPC, HSC, HST, ICC, ROM, SDH,
SNA, SW.
HPC.
ACS,
HST.
HSH,
ICC,
ROM,
S.
HST,
SW.
HST.
ACS.
HST.
ACS.
ACS.
LVR,
MRX
ICC,
LVR,
S, TRC.
ACS,
HPC,
KCW.
HPC,
SNA,
UHL.
ACY,
HSC,
HST,
SNA,
SW.
ACS,
ACY,
AMS,
HPC,
KON, S, SNA
ACS.
ACS,
DUP,
GAF,
HPC,
HSH, HST, I
BUC,
ICC,
ROM,
SDH,
SNA.
HST.
AGS,
HST.
ACS,
HST,
TRC.
ACS.
KON,
LVR,
S, SNA.
ACS, HPC, HSH, KCW, SW.
GAF, HPC, HSH, ICC, ROM, S, SDH.
S.
HPC.
KCW.
HPC, KCW.
DUP.
ACY, HPC, ICC, S, SNA, SW, UHL.
ACS, HPC.
ORGANIC PIGMENTS
TABLE 2. --Organic pigments for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Pigment
Manufacturers' identification codes
(according to list in table 3)
TONERS--Continued
•Red toners--Continued
*Naphthol reds--Continued
•Pigment Red 22, C.I. 12 315
'Pigment Red 23, C.I. 12 355
Pigment Red 31, C.I. 12 360
Pigment Red 112, C.I. 12 370
All other naphthol reds
♦Pigment Red 1, C.I. 12 070, dark--
♦Pigment Red 1, C.I. 12 070, light-
♦Pigment Red 3, C.I. 12 120
•Pigment Red 4,
Pigment Red 6,
•Pigment Red 38
Pigment Red 41
•Pigment Red 48
C.I. 12 085--
C.I. 12 090--
C.I. 21 120-
C.I. 21 200-
C.I. 15 865-
Pigment Red 49, C.I .
•Barium toner
•Calcium toner
•Sodium toner
•Pigment Red 52, C.I. 15 860
•Pigment Red 53, C.I. 15 585, barium toner-
Pigment Red S3, C.I. 15 585, sodium toner--
•Pigment Red 54, C.I. 14 830, calcium toner-
Pigment Red 55, C.I. 15 820
•Pigment Red 57, C.I. 15 850, calcium toner-
Pigment Red 58, C.I. 15 825
•Pigment Red 63, C.I. 15 880
Pigment Red 64, C.I. 15 800
Pigment Red 79, PMA
Pigment Red 81, C.I. 45 160, fugitive
•Pigment Red 81, C.I. 45 160, PMA
•Pigment Red 81, C.I. 45 160, PTA
Pigment Red 87, C. I .
Pigment Red 88
•Pigment Red 90, C.I.
Pigment Red 112
•r-igment Red 122
Pigment Red 123, C.I
Pigment Red 146
Pigment Red 149
Pigment Red 170
Pigment Red 176
Pigment Red 177
Pigment Red 179, C.I
Pigment Red 181 , C.I
Pigment Red 190, C.I
Pigment Red 198
(Vat Red 15)
All other
•Violet toners:
Pigment Violet 1, C.
•Pigment Violet 1, C.
•Pigment Violet 1, C.
•Pigment Violet 3, C.
•Pigment Violet 3, C.
71 130-
73 360-
71 140-
45 170, fugitive-
45 170, PMA
45 170, PTA
42 535, fugitive-
42 535, PMA
•Pigment Violet 3, C.I. 42 535, PTA-
Pigment Violet 4, PMA
Pigment Violet 19, C.I. 46 500
•Pigment Violet 23, C.I. 51 319
ACY, DUP, GAP, HPC, MRX, ROM, SNA.
ACY, BUG, DUP, HPC, ROM, SDH, SNA,
SNA.
HPC.
ICC, KOV, ROM, S, SDH, SNA.
WS, HPC, HSC, HSH, SW.
HPC, HSC, HSH, SDH, SW.
ACY, CIK, CPC, DUP, HPC, HSC, HSH,
SNA, SW, UHL.
ACY, AiMS, HPC, HSC, KON, MRX, SDH,
DUP, HSH, KCW, KON.
ACS, DUP, GAP, ICC, SNA, SW.
ACS, GAP.
ACS, ACY, AMS, DUP, GAP, HPC, HSC,
S, SNA, SW.
ACV, AMS, APO, CIK, HSC, KON, UT,
UHL.
ACV, AMS, CIK, HSC, LVT, SDH, SNA,
ACY, HSC, KON, SDH, SW.
A^^S, CIK, HPC, HSC, HSH, SNA, SW .
ACY, AMS, APO, CIK, HPC, HSC, KON,
SNA, SW.
KON.
HPC, HSH, SDH.
KCW, KON, PPG, SDH,
SNA, UHL.
ICC, IMP, LVY,
SDH, SNA, SW,
LVY, MGR, MRX, SDH,
HSH .
AMS,
CIK
DUP,
HPC
HSC
KON, LVY
\CR, SDH
SNA, SW.
DUP,
HPC
ACS,
HPC
HSH
KON
SNA
ACS.
GAP.
MGR.
CPC,
DUP
GAP
HPC
KON
LVR, LVY
MGR, MRX
SNA, UHL
ACY,
AMS
DUP
GAP
HN,
HPC, HSC,
KCW, KON,
MGR, MRX,
S,
SNA
UHL
ACS.
ACS.
AMS,
HN,
HPC,
ICC,
LVT,
SDH.
HST.
ACS,
ACY
HST
SNA
ACS,
HST.
HST.
HST.
HST.
TRC.
ACS.
HST.
ACS,
GAP
HSC
ACS.
RST.
DUP,
GAP,
HN,
HSC,
LVR,
SW, X.
UHL.
GAP, HPC, MGR, MRX, SNA, UHL.
AMS, DUP, GAP, HPC, MGR, MRX, SNA.
ACY, AMS, HN, HPC, HSC, KON, MGR,
AMS, CIK, DUP, GAP, HPC, HSC, KON^
SDH, SW, UHL.
ACY, AMS, HN, HPC, HSC, KON, MRX.
LVR.
ACS, DUP, SNA.
ACS, ACY, BUC, GAP, HSC, HST, SDC
UHL.
LVY,
MGR, MRX, PPG,
SYNTHETIC ORGANIC CHEMICALS. 1972 "
TABLE 2.— Organic pigments for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED
Pigment
Manufacturers' identification codes
taccording to list in table 3)
TONERS--Continued
*Violet toners--Continued
Pigment Violet 31, C.I. 60 010
Pigment Violet 36, C.I. 73 385
Pigment Violet 38, C.I. 73 395
(Basic Violet 2), C.l. 42 520
All other
*Blue toners;
•Pigment Blue 1, C.l. 42 595, PMA
Pigment Blue 1, C.I. 42 595, PTA
Pigment Blue 2, C.I. 44 045, PMA
Pigment Blue 2, C.I. 44 045, PTA
Pigment Blue 7, PMA
Pigment Blue 7, PTA
Pigment Blue 9, C.I. 42 025, PTA
Pigment Blue 10, C.I. 44 040, PMA
Pigment Blue 10, C.I. 44 040, PTA
♦Pigment Blue 14, C.I. 42 600, PMA
Pigment Blue 14, C.I. 42 600, PTA
♦Pigment Blue 15, C.I. 74 160, alpha form
♦Pigment Blue 15, C.I. 74 160, Beta form
♦Pigment Blue 19, C.I. 42 750A
Pigment Blue 22, C.I. 69 810
♦Pigment Blue 25, C.I. 21 180
Pigment Blue 64, C.I. 69 825
(Basic Blue 2)
All other
♦Green toners ;
♦Pigment Green 1, C.I. 42 040, PMA
Pigment Green 1, C.I. 42 040, PTA
♦Pigment Green 2, C.I. 42 040 and 49 005, PMA
♦Pigment Green 2, C.I. 42 040 and 49 005, PTA
Pigment Green 4, C.I. 42 000, fugitive
Pigment Green 4, C.I. 42 000, PMA
Pigment Green 4, C.I. 42 000, PTA
♦Pigment Green 7, C.I. 74 260
♦Pigment Green 8, C.I. 10 006
Pigment Green 10, C.I. 12 775
♦Pigment Green 36, C.I. 74 265
Pigment Green 38
All other
♦Brown toners :
Pigment Brown 1, C.I. 12 480
Pigment Brown 2, C.I. 12 071
Pigment Brown 3, C.I. 21 010, PMA
♦Pigment Brown 5, C.I. 15 800
Pigment Brown 28, C.I. 69 015
All other
♦Black toners
Yellow lakes: *(Acid Yellow 23), C.I. 19 140
♦Orange lakes:
Pigment Orange 7, C.I. 15 530
Pigment Orange 17, C.I. 15 510
Red lakes:
♦Pigment Red 60, C.I. 16 105
♦Pigment Red 83, C.I. 58 000
(Acid Red 17), C.I. 16 180
(Acid Red 26), C.I. 16 150
All other
ACS, DUP.
ACS, HST.
ACS.
HN.
BUC, ICC, HPC, ROM.
DUP, GAF, HN, HPC, HSC, KON, LVY, MGR, MRX, SW, UHL.
AMS, GAF, HPC, MGR.
GAF.
KON.
LVR.
LVR.
GAF, HPC, MGR.
SDH.
HPC, LVR.
DUP, GAF, HPC.
DUP, GAF,
ACS, ACY, APO, DUP, GAF, HPC, HSC, ICC, MGR, SNA, SW,
TMS, TRC.
ACS, ACY, AMS, BAS, BUC, CIK, DUP, GAF, HPC, HSC, ICC,
LVY, ROM SDH, SNA, SW, TMS.
AMS, HN, HSC, SW.
ACS, DUP, HN.
ACS, DUP, GAF, ICC, SNA.
TRC.
HPC.
DUP, GAF, SDH, TNI.
GAF,
HPC,
MRX,
S, UHL.
HPC,
MGR.
GAF,
HPC,
KON,
MGR,
MRX,
UHL.
ACY,
AMS,
DUP,
GAF,
HPC,
KON,
S.
GAF,
MRX.
KON,
MGR.
ACY,
AMS,
KON,
MGR.
ACS,
HPC,
ACY,
HSH,
BAS,
KCW.
CIK,
DUP,
GAF,
HPC, HSC, SNA, TMS, TRC
DUP,
HPC,
SNA.
ACS,
ACY,
GAF,
SNA.
DUP,
SNA.
HPC.
S.
KCW,
KON.
ACS,
BUC,
HSH,
ICC,
ROM,
SNA.
GAF.
GAF,
LVR,
SDH.
DUP,
GAF,
UHL.
ACS, KON, MGR, MRX.
CPC.
HPC, KCW, KON.
HSH, KON, MRX, SNA.
HPC, HSH, KON, MRX, UHL.
HPC.
CPC, HPC, KCW.
HPC.
ORGANIC PIG^IENTS
TABLE 2. --Organic pigments for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER^ 1972— CONTINUED
Pigment
Manufacturers' identification codes
(according to list in table 5)
LAKES — Continued
'Violet lakes:
•Pigment Violet 5, C.l. 58 055
All other
Blue lakes:
Pigment Blue 17, C.I. 74 180
Pigment Blue 24, C.I. 42 090
(Acid Blue 93), C.I. 42 780
(Acid Blue 104), C.I. 42 735
Green lakes
Brown lakes
Black lakes: (Natural Black 3), C.I. 75 291
ACS, DUP, HPC, HSH, KON, UHL.
SW.
CPC.
AMS, KON, LVY, SDH.
LVR.
KCW, LVR.
HPC.
KON.
CPC.
Note. --The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the third edition
of the Colour Index.
When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the
pigment can be made and that no name for the pigment itself is given in the Colour Index.
The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic)
acid, repectively.
SYNTHETIC ORGANIC CHEMICALS. 1972.
TAPLE ^.--Hrganic f^iGMFMTs: Directory of manufacturfrs, 1^72
ALPHABETICAL DIRECTORY BY CODE
[Names of organic pigment manufacturers that reported prod
are listed below in the order of their identification co
uction or sales to the U.S. Tariff Commission for 1972
des as used in table 2]
Code
Name of company
Code
Name of company
ACS
Allied Chemical Corp., Specialty Chemicals
Div.
KON
H. Kohnstamm 5 Co . , Inc.
ACY
American Cyanamid Co.
AMS
Ridgway Color 6 Chemical
APO
Apollo Colors, Inc.
LVR
LVY
C. Lever Co ., Inc.
Cities Service Co., Levey Div.
BAS
BASF Wyandotte Corp.
BUC
Blackman-Uhler Chemical Co.
MGR
MRX
Magruder Color Co., Inc.
Max Marx Color £, Chemical Co.
CIK
Tenneco Chemicals, Inc., Cal/Ink Div.
CPC
Childs Pulp Colors, Inc.
PPG
PPG Industries, Inc.
DUP
E. 1. duPont de Nemours ti Co., Inc.
ROM
United Merchants (j Manufacturers, Inc.
Roma Chemical Div.
GAP
GAP Corp., Chemical Div.
S
SDC
Sandoz, Inc., Sandoz Color 5 Chemicals
Martin-Marietta Corp., Sodyeco
Div.
Div.
SDH
Sterling Drug, Inc., Hilton-Davis Chem
ical
HN
Tenneco Chemicals, Inc.
Co. Div.
HPC
Hercules, Inc.
SNA
Sun Chemical Corp.
HSC
Chemetron Corp., Pigments Div.
SW
The Sherwin-Williams Co.
HSH
Harshaw Chemical Co. Div. of Kewanee
Oil Co.
HST
American Hoechst Corp.
TMS
TNI
Sterling Drug, Inc., Thomasset
Colors Div.
Gillette Co., Gillette Chemical
ICC
Inmont Corp.
Co. Div.
ICI
ICI America, Inc.
TRC
Toms River Chemical Corp.
KCW
Keystone Color Works, Inc.
UllL
Pi.ul Uhlich f, Co. , Inc.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendi.x
101
MEDICINAL CHEMICALS
Medicinal chemicals include the medicinal and feed grades of all
organic chemicals having therapeutic value, whether obtained by chemical
synthesis, by fermentaiton, by extraction from naturally occurring plant
or animal substances, or by refining a technical grade product. They
include antibiotics and other anti-infective agents, antihistamines.,
autonomic drugs, cardiovascular agents, central nervous system depres-
sants and stimulants, hormones and synthetic substitutes, vitamins, and
other therapeutic agents for human or veterinary use and for animal feed
supplements .
Table 1 shows statistics for production and sales of medicinal
chemicals grouped by pharmacological class, while table 2 lists separately
e.ach product for which data were reported and identifies the manufacturers.^
The statistics shown in table 1 are for bulk chemicals only; finished
pharmaceutical preparations and products put up in pills, capsules, tablets,
or other measured doses are excluded. ^ The difference between production
and sales reflects inventory changes, processing losses, and captive con-
sumption of medicinal chemicals processed into ethical and proprietary
pharmacetuical products by the primary manufacturer. In some instances,
the difference may also include quantities of medicinal grade products
used as intermediates, e.g., penicillin G salts used as intermediates in
the manufacture of semisynthetic penicillins. All quantities are given
in terms of 100-percent content of the pure bulk drug.
Total U.S. production of bulk medicinal chemicals in 1972 amounted
to 234 million pounds, or 5.0 percent more than the 223 million pounds
produced in 1971 and 9.3 percent more than the 214 million pounds produced
in 1970. Total sales of bulk medicinal chemicals in 1972 amounted to 163
million pounds, valued at $490 million, compared with sales in 1971 of
152 million pounds, valued at $487 million, and sales in 1970 of 155
million pounds, valued at $510 million. In terms of quantity, sales in
1972 were thus 7.2 percent larger than in 1971 and 5.6 percent larger than
in 1970. In terms of value, sales in 1972 were 0.7 percent larger than in
1971 and 3.9 percent smaller than in 1970.
Production of the more important groups of medicinal chemicals in
1972 was as follows: Antibiotics, 16.6 million pounds (7.1 percent smal-
ler than in 1971), of which 9.8 million pounds was for medicinal use and
6.8 million pounds was for other uses; anti-infective agents other than
antibiotics, 34.4 million pounds (8.3 percent larger than in 1971; central
~~^ See table 3 for a list of manufacturers and their identification
codes .
^ Complementary statistics on the dollar value of manufacturers'
Shipments of finished pharmaceutical preparations, except biologicals,
are published annually by the U.S. Department of Commerce, Bureau of
the Census, in Current Industrial Reports, Series MA-28G. Many pharma-
ceutical manufacturers who report to the Bureau of the Census are ex-
cluded from the lariff Commission report because they are not primary
producers of medicinal chemicals, that is, they do not themselves pro-
duce the bulk drugs which go into their pharmaceutical products but
purchase their drug requirements from domestic or foreign producers.
102
SYNTHETIC ORGANIC CHEMICALS, 1972
nervous system depressants and stimulants, 52.4 million pounds (,13.2
percent larger}; gastreintestinal ageftts add therapeutic ntitrielit^, 99^9
million pounds (10.6 percent larger}; and vitamins, 30.0 million pounds
(15.1 percent larger). Production of some of the more important in-
dividual products listed in table 1 was as follows: Choline chloride,
54.5 million poimds (19.2 percent larger than in 1971); aspirin, 35.0
million pounds (10.5 percent larger}; salicylic acid, 8.7 million pounds
(52.9 percent smaller}; ascorbic acid, 12.3 million pounds (10.0 percent
larger); anti-infective sulfonamides, 6.1 million pounds (0.2 percent
larger); penicillins (except semi-synthetic), 3,827 trillion units (18.1
percent smaller); tetracyclines, 1.8 million kilograms (19.0 percent
smaller); vitamin A, 1,005 trillion units (4.5 percent smaller); and
vitamin E, 1,502 billion units (53.0 percent larger).
»1EDICINAL CHEMICALS
TABLE 1. --Medicinal chemicals; U.S. production and sales^ 1972
Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may
be published. (Leaders are used where the reported data are accepted in confidence and may not be published or
where no data were reported.) Table 2 lists all medicinal chemicals for which data on production or sales were
reported and identifies the manufacturer of each]
Production
1,000
pounds
Grand total
Acyclic
Benzenoid^
Cy c 1 i c nonb en zenoi d*
Antibiotics, total ^
Bacitracin, for medicinal use
Erythromycin, for medicinal use
Neomycin, for all uses
Penicillins (except semisynthetic), total
Penicillin G, potassium, for medicinal use
Penicillin G, procaine, for medicinal use
All other, for all uses
Semisynthetic penicillins, for medicinal use, total-
AmpiGillin
Ampicillin, sodium
All other
Tetracyclines, for all uses
Other antibiotics, total
For medicinal use'
For nonmedicinal uses
Antihistamines, total
Antinauseants
Chlorpheniramine maleate
All other
Anti-infective agents (except antibiotics), total
Anthelmintics, total
Piperazine
Piperazine dihydrochloride
Piperazine hydrochloride
All other
Antifungal agents
Antiprotozoan agents, total
Arsenic and bismuth compounds
All other
Mercury compounds
Sulfonamides
Other anti-infective agents'
Autonomic drugs, total
Parasympatholytic (anticholinergic) tertiary amines
Sympathomimetic (adrenergic) agents, total
Epinephrine hydrochloride (racemic)
Phenylephrine base and bitartrate
Phenylephrine hydrochloride
Phenylpropanolamine hydrochloride
All other
Other autonomic drugs
Cardiovascular agents, total
Vasodilators
Other cardiovascular agents
101,747
111,444
16,637
2,174
837
2,887
931
779
20
132
3,899
5,249
1,857
3,392
483
30
375
34,364
12,914
3,581
1,824
352
7,157
875
10,233
6.077
4,156
14
6,078
4,250
308
172
47
1,000
pounds
163.210
82,128
68,279
12,803
5.384
20
250
199
2,545
2,545
332
302
30
790
1,248
608
640
330
9.464
1,915
240
7.309
7.292
4,574
2,718
8
1,928
3,325
276
113
1,000
dollar's
490.137
56,878
319.665
113.594
139.212
1,390
6,269
2,473
22,791
22,791
32,708
29,226
3.482
17,735
55,846
47.315
8.531
7.878
292
7.586
77.672
43,591
1,420
165
42,006
16.380
5,633
10,747
533
7.664
9.504
9.540
1,537
6.268
2.538
1.611
2.119
1,735
15.628
15,628
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS. W2 ■
TABLE 1, --Medicinal chemicals; U.S. production and sales, 1972--Continued
Production'
Sales'
Quantity
Unit
Value^
Central depressants and stimulants, total
Amphetamines
Analgesics and antipyretics, total
Aspirin
Meperidine hydroch loride
Salicylates (except aspirin)
All other
Antidepressants
Barbiturates, total
Pentobarbital , sodium
All other
Hydrocodone bit art rate
Hypnotics and sedatives (except barbiturates)
Skeletal muscle relaxants
Tranquilizers
Other central depressants and stimulants^
Dermatological agents and local anesthetics, total
Salicylic acid
All other
Diagnostic agents
Expectorants and mucolytic agents, total
E thy lenedi amine dihydriodide
Guaiacol and its derivatives
All other
Gastrointestinal agents and therapeutic nutrients, total-
Amino acids and salts
Choleretics and hydrocholeretics
Choline chloride (all grades)
All other
Hematological agents, total
Sodium heparin
All other
Hormones and synthetic substitutes, total
Antithyroid agents
Corticosteroids
Estrogens and progestogens
Synthetic hypoglycemic agents
All other
Renal-acting and edema- reducing agents, total
Benzothiadiazine derivatives
Mercurial diuretics
Theophylline derivatives
All other
Vitamins, total
Vitamin A alcohol and esters, total'^
Vitamin A palmitate (feed grade)
All other
Vitamin B-complex, total
Niacin and niacinamide (all grades)
Pantothenic acid and derivatives, total
Calcium pantothenate (racemic)-calcium chloride
complex
All other
Riboflavin (all grades)
Other B-complex vitamins
Vitamin C, total
Ascorbic acid
All other
1,000
pounds
52,430
45
950
35
007
28
3
262
7
653
110
567
567
1
246
133
1,126
4,297
10,426
8,694
1,732
924
2,960
1,335
1,625
79.934
1,346
150
54,450
23,988
91
1,325
209
1,650
115
1,535
30,030
1,037
443
594
10,344
5,475
3,049
1,964
1,085
1,011
809
15,588
12,312
3.270
1,000
29,358
1,000
dollars
55.558
24,895
2,541
22,354
97
28,822
577
245
904
116
788
455
9,296
1,279
1,322
1,351
42,793
23,755
CO
23.399
1,010
552
458
9,019
4,920
2,475
1,732
743
788
836
11,067
8,293
2,774
464
724
017
972
838
931
082
849
574
882
599
978
621
198
895
644
006
638
Pep
pound
$1.89
flEDICINAL CHEMICALS .
TABLE 1,— Medicinal chemicals: U.S. production and sales> 1972— Continued
Production
Quantity
Unit
Value ^
Vitamins- -Continued
Vitamin D'^
Vitamin E, total'^
d-and dl-Alpha tocopheryl acetate (all grades)
All other
Vitamin K
Miscellaneous medicinal chemicals''
1,000
pounds
,905
.268
637
143
1,000
pounds
2,220
1,623
597
1,000
dollars
1,404
34,333
20,336
13,997
548
Per
poimd
$156.00
15.47
12.53
5,721
' The data on production and sales are for bulk medicinal chemicals only; they exclude finished preparations
and dosage-form products, which are manufactured from bulk chemicals. All quantities are given in terms of
lOO'o active ingredient.
^ Calculated from rounded figures.
' The term "ben:enoid," as used in this report, describes any cyclic medicinal chemical whose molecule con-
tains either a six-membered carbocylic ring with conjugated double bonds (e.g., the benzene ring or the quinone
ring) or a six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, e.xcept the
pyrimidine ring (e.g., the pyridine ring or the pyrazine ring.)
"* Includes antibiotics of unknown structure.
^ With the exception of bacitracin, the penicillins (except semisynthetic), and a few other antibiotics which
were reported in terms of U.S. P. units, all quantities for antibiotics were reported as grams of antibiotic base.
(Thus production of 480,900 grams of tetracycline hydrodiloride, for example, would have been reported as 444,430
grams of tetracycline base.) For inclusion in the main statistical table, all quantities were converted from
grams of antibiotic base to pounds of antibiotic base (453.6 grams = 1 pound) or from U.S. P. units to pounds (22.7
million units of bacitracin, 458 million units of procaine pencillin G, 723 million units of potassium peni-
cillin G, etc. = 1 pound). The following tabulation shows statistics for all individually publishable antibiotics
in terms of kilograms of antibiotic base (Kg) or billions of U.S. P. units (BU) :
Antibiotic
Unit of
quantity
Quantity
Unit
Value
Bacitracin, for medicinal use —
Erythromycin, for medicinal use-
Neomycin, for all uses
Penicillins (except semisynthetic), total
Penicillin G, potassium, for medicinal use —
Penicillin G, procaine, for medicinal use
All other, for all uses
Semisynthetic penicillins, for medicinal use
total
Ampicillin
Ampicillin, sodium
All other
Tetracyclines, for all uses-
-BU---
-BU---
437
290,582
3,827.078
1,572,130
383,202
1,871,746
422,353
353.302
8.852
60,199
1.768.797
459
113.424
90,119
150,448
137,104
13,344
358,477
1,000
dollars
1,390
6,269
2.473
22,791
32
708
29
226
3
482
17
735
53,028.32
55.27
27.44
15.13
15.13
217.40
213.17
260.94
49.47
' Production of all antibiotics for medicinal use amounted to 9,817,000 pounds; sales amounted to 3.484.000 pounds,
valued at $115,855,000.
' Production of all antibiotics for animal feeds and other nonmedicinal uses amounted to 6.820.000 pounds; sales
amounted to 1,900,000 pounds, valued at $23,357,000.
^ Includes sales of antifungal agents.
' Includes production of amphetamines and production and sales of anticonvulsants, antitussives, general anesthetics,
and stimulants; also includes sales of antidepressants, hypnotics and sedatives (except barbiturates), skeletal
muscle relaxants, and tranquilizers.
'° Data published for 1971. and possibly for earlier years as well, includes some production and sales of technical
grade salicylic acid erroneously reported as medicinal grade.
SYNTHETIC ORGANIC CHEMICALS. 1972
Footnotes for table l--Continued
^^ Sales of mercurial diuretics amounted to 318 pounds.
^^ All quantities for vitamin A, B12, D, and E were reported in terms of grams or units, but were converted to
pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 billion units
of vitamin A palmitate, 453.6 grams of vitamins B12, 18.14 billion units of vitamin D, 617,000 units of d-alpha
tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). The following tabulation shows
statistics for these vitamins, except for B12, which was not separately publishable, in terms of million of inter-
national units (MU) or billion of U.S. P. units (BU) :
Unit
of
quantity
Quantity Value
Unit
value
Vitamin A, total
Vitamin A palmitate (faed grade) -
All other
Vitamin D
Vitamin E, Total
d-and dl-Alpha tocopheryl acetate
(all grades)
All other
BU-
BU-
MU---
1,005,425
365,303
640,122
233,391
1,501,785
1,131,189
370,596
944,556
454,540
490,016
158,558
1,168,840
817,079
351,761
1,000
dollars
18,931
7,082
11,849
1,404
34,333
20,336
13,997
$20.04
15.58
24.18
24.89
39.79
Includes production and sales of antineoplastic agents, smooth-muscle relaxants, and unclassified medicinal
chemicals; also includes sales of diagnostic agents and "all other" hematological agents.
MEDICINAL CHEMICALS
Table 2. --Medicinal chemicals for which U.S. production or sales were reported-
identified BY MANI"^ACTURER, 1972
[Medicinal chemicals tor which separate statistics are given in table 1 are marked below with an asterisk (*J ; medic-
inal chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
'Antibiotics: '
'Bacitracin
'Eryth romycin
'Neomycin:
For medicinal use
For nonmedicinal uses
'Penicillins (except semisynthetic):
•Penicillin G, potassium
'Penicillin G, procaine
'All other:
Penicillin G, benzathine
Penicillin G, procaine, for nonmedicinal uses-
Penicillin G, sodium
Penicillin 0, sodium
Phenoxymethylpenicillin (Penicillin V)
Phenoxymethylpenici 11 in, benzathine
Phenoxymethylpenicillin, hydrabamine
Phenoxymethy Ipeni ci llin, potassium
'Semisynthetic penicillins, for medicinal use:
'Ampicillin
'Ampicillin , sodium
Carbenicillin
Cloxacillin, sodium
Die loxaci llin, sodium
Hetacillin
Methicillin, sodium
Nafcillin, sodium
Oxacillin, sodium
Phenethicillin, potassium
'Tetracyclines :
Chlortetracycline
Chlortetracycline, tor nonmedicinal uses
Uemeclocycline
Doxycycline
Methacycline
Minocycline
Oxytetracycline
Tetracycline
'Other antibiotics:
'For medicinal use:
Amphotericin B
Candicidin
Cephalexin
Cephaloridine
Cephalothin
Chloramphenicol
Clindamycin
Cycloserine
Dihydrostreptomycin
Fumagillin
. Gentamycin
Gramicidin
Kanamycin
Lincomycin
Novobiocin
Nystatin
Oleandomycin
Paromomycin
Pol\-myxin B
Spectinomycin
Streptomycin
Thiostrepton
Tro leandomy cin
Vancomycin
Viomycin
See footnotes at end of table.
COM,
PEN,
PFZ,
PMP
ABB,
LIL,
UPJ.
OMS,
PEN,
PFZ,
UPJ
PFZ.
LIL,
OMS,
PFZ,
WYT
LIL,
OMS,
PFZ,
WYT
WYT.
MRK,
OMS.
OMS.
PFZ.
BRS,
WYT.
LIL,
OMS.
BEE
BEE
BEE
BEE
BEE
BRS
BEE
WYT
BEE
BRS
ACY
ACY
ACY
PFZ
PFZ
ACY
PFZ
ACY
OMS.
PEN.
LIL.
LIL.
LIL.
COM.
MKK,
ABB.
sen.
PEN.
BRS.
UP.].
MRK,
ACY,
PFZ.
MKK.
PFZ.
ABB,
LIL,
OMS.
PFZ.
LIL.
PFZ.
LIL.
BOC, BRS, TRD, WYT.
OMS, IVYT.
PFZ.
BRS.
BRS, WYT.
BRS.
BRS.
BRS, PFZ, RLS.
UPJ.
OMS.
UPJ.
MRK, PFZ.
SYNTHETIC ORGANIC CHE.IICALS, 1972
Table 2.-
-MeDICINAL chemicals for which U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manutacturers' identification codes
(according to list m table 3)
•Antibiotics -rContinued
*Other antibiotics--Continued
*For nonmedicinal uses:
Bacitracin
Cy cloheximide
Hygronycin B
Li ncomy c in
Monensinj sodium
Novobiocin
Nystatin
Spectinomycin
Streptomycin
Tylosin
•Antihistamines ;
•Antinauseants :
Cyclizine liydrociiloride
Dimenhydrinate
Meclizine hydrochloride
Trimethobenzamide hydrochloride
Bromodiphenhydrami ne hydroch loride
Brompheniramine maleate
Carbinoxamine
Chlorcyclizine hydrochloride
Chlorothen citrate
•Chlorpheniramine maleate
Chlorpheniramine tannate
Cyprohept adine hydroch loride
Dexbrompheniramine maleate
Dexchlorphenirajnine maleate
Dimethindene maleate
Diphenhydramine hydrochloride
Doxylamine succinate
Methapyrilene fumarate
Methapyrilene hybenzate
Methapyrilene hydrochloride
Methdilazine
Methdilazine hydrochloride
Phenindamine tartrate
Pheniramine maleate
Phenyltoloxamine citrate
Pyrilamine maleate
Pyrilamine resin adsorbate
Pyri 1 amine t annate
Pyrrobut amine phosphate
Thenyldi amine hydrochloride
Thonzylamine hydrochloride
Tripelennamine
Tripelennamine citrate
Tripelennamine hydrochloride
iriprolidine hydrochloride
•Anti-infective agents (except antibiotics):
•Anthelmintics:
2,2-Dichlorovinyl dimethyl phosphate (DVPP)-
Uiethylcarbamazine citrate
2,6-Uiiodo-4-nitrophenol
Gentian violet
Hexylresorcinol
Phenothiazine
•Piperazine
Piperazine citrate
•Piperazine dihydroch loride
Piperazine hexahydrate
"Piperazine hydrochloride
Piperazine phosphate
Piperazine sulfate
COM,
GPR.
PhN, PMP.
UPJ.
LIL.
UPJ .
LIL.
UPJ.
QMS.
UPJ.
MRK,
PFZ.
LIL.
BUR.
HEX,
SRL.
PF2.
HOF.
PD.
SCH.
SCH.
ABB,
BUR.
ALY.
HEX,
HFT,
SCH, SK.
MAL.
MRK.
SCH.
SCH.
CGY.
CAN,
PD.
BJL,
BKC.
ABB.
LIL.
ABB.
BJL.
BJL.
HOF.
HEX,
HFT,
SCH.
BRS.
HEX,
MRK,
MRK.
MAL.
LIL.
SUW.
NEP.
CGY.
CGY.
CGY .
BUR.
SHC.
ACY.
RSA.
SDH.
NRK.
WAG.
DOW,
FLM,
JCC, UCC
BUR.
DOW,
FLM,
JCC, WIIL
JCC.
DUW,
FLM,
.ICC.
BUR,
JCC.
JCC,
SAL.
^lEDICINAL CHEMICALS
Table 2.
-Medicinal chemicals for which U,S, production or sales were reported,
identified by manufacturer, 1972— continued
Manufacturers' identification codes
(according to list in table 5)
*Anti-infective agents (except antibioticsJ--Continued
*Anthelniintics- -Continued
Pyrvinium pamoate
Thiabendazole
'Antifungal agents:
Benzoic acid
Calcium undecylenate
Fuchsin, basic
Sodium caprylate
Sodium undecylenate
Undecylenic acid
Zinc undecylenate
*Antipropozoan agents:
Aklomide
Amodiaquin
Amodiaquin hydrochloride
Amprolium
*Arsenic and bismuth compounds:
Arsanilic acid
Bismuth dipropylacetate
Bismuth subsalicylate
Carbarsone
Glycobiarsol
Nitarsone
Roxarsone
Roxarsonej sodium
Sodium arsani late
Chloroqulne phosphate
Dimetridazole
Diiodohydroxyquin
3,S-Dinitro-o-toluaraide
Furazolidone
Hydroxy ch loroquine su 1 fate
lodochlorhydroxyquin
Metronidazole
Nifuroxime
Nifursol
Nihydrazone
Nithiazide
Nitromide
Nitrophenide
Primaquine phosphate
Pyrimethamine
*Mercury compounds :
Merbromin
Mercuric salicylate
Ni tromerso 1
Phenylmer curie acetate
Phenylmercuric borate
Phenylmercuric chloride
Phenylmercuric nitrate
Thimerosal
'Sulfonamides:
Acetyl sulfamethoxypyridazine
Acetyl sulfisoxazole
Dinsed
Mafenide acetate
Mafenide hydrochloride
Phthalylsul facet amide
Phthalylsulfathiazole
Succinylsulfathiazole
Sulfabenz amide
Su 1 f aben z ami de , s odium
Sulfabromomethazine, sodium
Sulfacetamide
Sulfacetamide, sodium
Su 1 f ach loropyraz ine , sodium
MRK.
MON.
WTL.
ACS.
LEM.
NIL.
NIL.
NTL, IVIL.
SAL.
PU.
PD.
MRK.
abb, flm, whl.
nwl, nor, PBN.
LIL, WHL.
SDW.
SAL.
SAL.
SAL.
SAL.
SDW.
RDA.
SKL.
DUW.
NUR.
SDW.
CGY.
RDA.
NOR.
LEM.
NOR.
MRK.
PEN, SAL.
ALY.
PD.
BUR.
HYN.
MRK.
ABB
WRC.
MRK.
WRC.
MRK, WRC.
LIL.
ACY.
HOF.
SAL.
SDW.
SDW.
CTN.
MRK .
MRK.
ACY.
ACY.
MRK.
CIN.
CTN.
ACY.
552-743 O - 74 .
SYNTHETIC ORGANIC CHEMICALS, 1972
Table 2. --Medicinal chemicals for which U.S. production or sales were reported-
identified BY manufacturer. 1972— CONTINUED
* Anti-infective agents (except antibiotics) --Continued
*Sulfonamides--Continued
Sulfachloropyridazine, sodium
Sulfadiazine
Sulfadiazine, sodium
Sulfadimethoxine
Sulfaguanidine
Sulfamerazine
Sulfamerazine, sodium
Sulfamethazine
Sulfamethazine, sodium
Sulfamethizole
Sulfamethoxazole
Sulfamethoxypyridazine
Sulfanilamide
Sulfanitran
Sulfapyridine
Sulfapyridine, sodium
Sulfaquinoxaline
Sulfathiazole
Sulfathiazole, sodium
Sulfisoxazole
Sulfisoxazole, sodium
•Other anti-infective agents:
Acriflavine
Aminacrine
Aminacrine hydrochloride
Antileprotic and antitubercular agents;
Aminosalicylic acid
Ethionamide
Isoniazid
Sodium aminosalicylate
Sodium sulfoxone
Antiviral agent: Amantadine hydrochloride
Benzalkonium chloride
Bromoform
Camphor , monobromated
Garb adox
Cetalkonium chloride
Cetylpyridinium chloride
Chlorobutanol
Furamazone
8-Hydroxy-S-quinolinesulfonic acid
Iodoform^
Nalidixic acid
Nitrofurathiazide
Nitrofurazone
Oxolinic acid
Oxyquinoline
Oxyquinoline benzoate
Oxyquinoline citrate
Oxyquinoline sulfate
Phenolic antiseptics and disinfectants:
Biothionol
Chlorothymol
Resorcinol'
Thymol
Thymol iodide
Povidine - iodine complex
Trimethoprim
Urinary antiseptics:
Mandelic acid
Methenamine base and salts:
Methenamine
Methenamine hippurate
Methenamine mandelate
Methylene blue
Nitrofurahtoin
Phenazopyridine hydrochloride
Manufacturers' identification codes
(according to list in table 3)
ACY.
ACY.
ACY.
HOP.
ACY, SAL.
ACY.
ACY.
ACY, CTN.
ACY.
ACY, CTN.
HOP.
ACY.
MRK, SAL.
SAL.
ACY, CTN.
ACY, CTN.
MRK.
ACY, MRK.
MRK, SAL.
HOP.
HOP.
ACS.
SDW.
SDW.
MLS.
RDA.
RIL.
MLS.
ABB.
DUP.
SDH.
DOW.
PEN.
PF2.
FIN, SDW.
FIN, HEX.
BPC, PD.
NOR.
MRK.
MAL.
SDH.
SCH.
NOR.
NEP.
FIS, MRK.
FIS.
FIS, MRK.
FIS, MRK.
SDH.
ACY.
KPT.
GIV.
MAL.
GAF.
BUR.
MAL.
ARN.
RIK.
MAL, NEP.
ACY.
NOR, RLS.
HOP, NEP.
See footnotes at end of table.
MEDICINAL CIIE'^IICALS
Table 2.
-Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972 — CONTINUED
Manufacturers' identification codes
(according to list in table 3}
* Autonomic drugs:
'Parasympatholytic (anticholinergic) tertiary amines:
Adiphenine hydrochloride
Cycrimine hydrochloride
Dicyclomine hydrochloride
Orphenadrine citrate
Orphenadrine hydroch loride
Oxyphencyc limine hydrochloride
Piperidolate hydrochloride
Thiphenamil hydrochloride
Trihexyphenidyl hydrochloride
'Sympathomimetic (adrenergic) agents:
Cinnamedrine hydrochloride
Cyclopent amine hydrochloride
Epinephrine bitartrate (levo)
'Epinephrine hydrochloride (racemic)
H- Isoproterenol bitartrate
Isoproterenol i.)''roch loride
I soprot ereno 1 sulfate
Levarterenol bitartrate
Me thoxyphen amine hydrochloride
Naphazoline hydrochloride
Nordefrin hydrochloride
Nylidrin hydrochloride
'Phenylephrine base and bitartrate:
Phenylephrine
Phenylephrine bitartrate
'Phenylephrine hydrochloride
•Phenylpropanolamine hydrochloride
Propylhexedrine
Protokylol hydrochloride-
Pseudoephedrine hydrochloride
Pseudoephedrine sulfate
Tetrahydrozoline hydrochloride
'Other autonomic drugs:
Ganglionic blocking agents:
Hexamethonium chloride
Tetraethyl ammonium chloride
Parasvinpatholytic (anticholinergic) quaternary
ammonium compounds:
Ambutonium bromide
Diphemanil methyl sulfate
Hexocyclium methyl sulfate
Isopropamide iodide
Mepenzolate bromide
Pipenzolate bromide
Tridihexethyl iodiue
Parasympatholytic (anticholinergic) tropane
derivatives :
Anisotropine methyl bromide
Benztropine mesylate
Homatropine hydrobromide
Homatropine methylbromide
Homatropine terephthalate
Parasympathomimetic (cholinergic) agents:
Neostigmine bromide
Neostigmine methyl sulfate
Physostigmine salicylate
Pyridostigmine bromide
Sympatholytic (antiadrenergic) agent: Ergonovine
maleate.
'Cardiovascular agents:
'Vasodilators:
Amy I nitrite
Clonitrate
Cyclandelate
Dioxyline phosphate
Ethyl nitrite
Isosorbide di nit rate
Mannitol hexanitrate
Nicotinyl alcohol tartrate
Pentaerythritol tetranitrate
CGY.
LIL.
BKC.
RIK.
RIK.
PFZ.
LKL.
BJL.
ACY, SDW.
SDW.
LIL.
SDW.
ECL, VB. X.
SDW.
SDW.
ABB.
SDW.
X.
CGY.
SDW.
BKL.
CTN, CAN, SDW.
GAN.
CTN, GAN, HEX, SDW.
ARS, BKL, GAN, HEX, NEP, ORT, PD.
HEX, SK.
LKL.
BUR, GAN.
GAN.
PGZ.
RSA.
RSA.
BJL.
SCH.
ABB.
SK.
LKL.
LKL.
ACY.
CTN.
CTN, HEX.
EN.
HEX, HOF.
MOF.
PEN.
HOF.
LIL.
MAL.
ICI.
WYT.
LIL.
MAL.
ICI.
ICI.
HOF.
ICI.
SYNTHETIC ORGANIC CHEMICALS. 1972
Table 2.
-Hedicinal chemicals for which U.S, production or sales were reported,
identified by manufacturer, 1972 — continued
*CardiovascuJar agents --Continued
*Other cardiovascular agents:
Antihypertensive agents:
Guanethidme sulfate
Hydralazine hydrochloride
Methyldopa
Pargyline hydrochloride
Rauwolfia and veratrum alkaloids:
Alkavervir
Kaunormine
Reserpine
Bioflavonoids :
Hesperidin
Lemon bioflavonoids
Naringin
Cardiac drugs:
Procainamide hydrochloride
Quinidine sulfate
Colestipol
*Central depressants and stimulants:
*Aiiiphetamines :
Amphet amine (racemi c)
Amphetamine sulfate (racemic)
Dextroamphetamine hydrochloride
Dextroamphetamine phosphate
Dextroamphetamine sulfate
Levamphet amine succinate
Methamphetamine hydrochloride (dextro)-
Methamphet amine saccharate
•Analgesics and antipyretics:
* Aspirin
'Meperidine hydrochloride
♦Salicylates (except aspirinj:
Aluminum aspirin
Phenyl salicylate
Potassium salicylate
Salicylamide
Salicylsalicylic acid
Sodium salicylate
*Other analgesics and antipyretics:
Acetaminophen
p-Arainobenzoic acid and salts:
Aminubenzoic acid
Calcium aminobenzoate
Potassium aminobenzoate
Sodium aminobenzoate
Anileridine hydrochloride
Calcium succinate
Dextropropoxyphene napsylate
Ethoheptazine citrate
Indome th acin
Mefenamic acid
Methadone hydrochloride
Oxycodone hydrochloride
Oxycodone tereph thai ate
Oxyphenbutazone
Pentazocine
Pentazocine hydrochloride
Phenacetin
Phenylbutazone
Propoxyphene hydrochloride
'Antidepressants :
Ami tripty line
Desipramine hydrochloride
Doxepin hydrochloride
Imipramine hydrochloride
Isocarboxazid
Nialamide
Nortriptyline
Phenelzine sulfate
Manufacturers' identification codes
(according to list in table 3)
CGY.
CGY.
MRK.
ABB.
RIK.
PEN.
PEN.
SKG.
bKG.
SKG.
QMS,
HEX.
UPJ.
ORT.
HEX.
ARN.
ARN.
ARN,
ARN.
ARN.
RSA.
DOW, MLS, HON, NOR, SDG.
PEN, SDW, WYT.
DOW.
HN.
PEN.
ATP, MAL, NEP, PEN.
LEM, PD.
GAN.
GAN.
GAN.
MRK.
LEM.
LIL.
WYT.
MRK.
PD.
LIL. MAL, PEN.
EN.
EN.
CGY.
SDW.
SDW.
MON.
CGY.
LIL. KLS.
MRK.
CGY.
PF2.
CGY.
HOP.
PFZ.
LIL.
NEP.
MEDICINAL CHEHICALS
Table 2. --Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
■"Central depressants and stimulants — Continued
*Barbiturates :
Allylbarbituric acid, sodium
5-Allyl-5- (2-cyclopenten-l-yl)barbituric acid
Amobarbital
Amobarbital , sodium
Barbital
Barbital, sodium
But abarbi t al
Butabarbital , sodium
5-sec-Butyl-5-ethyl-2- thiobarbituric acid, sodium
derivative
Hexobarbital
Mephobarbital
Metharbital
Methohexital , sodium
Pentobarbital
*Pentobarbital , sodium
Phenobarbital
Phenobarbital , sodium
Secobarbital--
Secobarbital , sodium
Thiamylal , sodium
Thiopental, sodium
Vinbarbital
*Hydrocodone bit art rate
*Hypnotics and sedatives (except barbiturates):
Carbroma 1
Bthchlorvynol
Ethinamate
Glutethimide
Methypry I on
*Skeletal muscle relaxants:
Cari soprodo 1
Chlorphenesin carbamate
Mephenesin
Phenaglycodol
Succinyl choline chloride
Tubocurarine
■"Tranquilizers ;
Buclizine hydrochloride
Chlorazepate dipotassium
Chlordiazepoxide hydrochloride
Chlormezanone
Chlorprothixene
Diazepam
Ethoxybutamoxane
Hydroxyzine hydrochloride
Hydroxy zine pamoat e
Meprobamat e
Methaqualone
Molindone hydrochloride
Oxazepam
Phenothiazine derivatives:
Acetophenazine maleate
Chlorpromazine hydrochloride
Fluphenazine hydrochloride
Perphenazine
Prochlorperazine edisylate
Prochlorperazine maleate
Promazine hydrochloride
Promethazine hydrochloride
Trif lupromazine hydrochloride
Thiothixene hydrochloride
GAM.
CAN.
GAN, LIL.
GAM, LIL.
GAN.
ABB, GAN.
ABB, GAN.
ABB, GAN.
GAN, bDW.
GAN, SDW.
ABB.
LIL.
ABB, GAN, PD.
ABB, GAN, PD.
GAN, MAL.
GAN, MAL.
GAN.
GAN, LIL.
GAN, PD.
ABB, GAN.
X.
EN, MAL, MRK, PEN.
LIL.
BKL,
CGY
HOF.
BKL.
UPJ.
HEX.
LIL.
ABB,
BUR
ABB,
OMS
PFZ.
ABB.
HOF.
SDW.
HOF.
HOF.
LIL.
PFZ.
PFZ.
ABB, BKL.
X.
PD.
WYT.
OMS, SCH.
SCH.
SK.
SK.
WYT.
WYT.
OMS.
PFZ.
SYNTHETIC ORGANIC CHEMICALS, 1972
Table 2, --Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972 — CONTINUED
*Central depressants and stimulants— Continued
*Other central depressants and stimulants:
Anticonvulsants :
Diphenylhydantoin
Diphenylhydantoin, sodium
Ethosuximide
Ethotoin
Methsuximide
Phenacemide
Phensuximide
Antitussives:
Benzonatate
Caramiphehen edisylate
Carbetapentane citrate
Codeine
Dextromethorphan hydrobromide
Ethylmorphine hydrochloride
Thebaine
General anesthetic:
Ket amine hydrochloride
Vinyl ether
Stimulants:
Benzphet amine hydrochloride
Caffeine:
Natural
Synthetic
Caffeine, citrated
Caffeine^ sodium benzoate
Chiorphentermine hydrochloride
Deanol acetamidobenzoate
Diethylpropion
Naloxone hydrochloride
Nikethamide
Phent ermine
*Uermatological agents and local anesthetics:
Dermatological agents:
Allantoin
Aluminum pheno Isul f onat e
Ammonium pheno Isu If onat e
Bismuth subgallate
Glycol salicylate
'Salicylic acid '
Sodium phenol sulfonate
Zinc phenol sulfonate
Local anesthetics:
Butacalne sulfate
Butamben pi crate
Butyl aminobenzoate (Butamben)
Dibucaine
Dibucaine hydrochloride
Isobutyl aminobenzoate
Lidocaine
Oxethazaine
Phenacaine hydrochloride
Pramoxine hydrochloride
Procaine hydrochloride
Proparacaine hydroch loride
Propoxycaine
Tetracaine
'Diagnostic agents:
Roentgenographic contrast media:
Acetrizoate, sodium
Diatrizoate, meglumine
Diatrizoate, sodium
lodipamide, meglumine
Manufacturers' identification codes
(according to list in table 3)
PU.
ABB.
py.
ABB.
PU.
CGY.
SK.
PFZ.
MRK.
HOF.
MAL, MRK.
MRK
PD.
GNF.
PFZ.
MAL.
GAN,
MAL.
NEP.
RIK.
BKC.
MAL.
CGY.
HEX.
HFT.
MAL,
SAL.
SAL.
MAL.
RDA.
DUW,
HN, MON,
SAL.
MAL,
SAL.
ABB.
ABB.
ABB.
CGY.
CGY.
RSA.
AST,
RLS, SDW.
WYT.
SDW.
ABB.
PFZ,
UUP.
QMS.
SOW.
SDW.
MAL
0Mb
SUW.
CMS,
SDW.
UMS
See footnotes at end of table.
MEDICINAL CHEMICALS
Table 2.
-Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3J
•Diagnostic agents--Continued
Roentgenographic contrast media — Continued
lodipamide, sodium
lodohippurate, sodiujn
lopanoic acid
lophendylate
lothalamate, meglumine
lothalamate, sodium
Methiodal, sodium
Other diagnostic agents:
Betazole hydrochloride
Indocyanine green (cardiac output test)
Metyrapone (pituitary function test)
Phenolphthalein monophosphate, dicyclohexalamine salt-
Phenolsulfonphthalein (kidney function test)
•Expectorants and mucolytic agents:
*Ethylenediamine dihydr iodide
*Guaiacol and its derivatives:
Glyceryl guaiacolate
Guaiacol
Potassium guaiacol sulfonate
lodinated glycerol
Lobe line sulfate
Terpin hydrate
■fhonzonium bromide
•Gastrointestinal agents and therapeutic nutrients:
•Amino acids and salts:
Amino acid mixtures
Aspartic acid
Beta- alanine
Glutamic acid and salts:
Glutamic acid hydrochloride
Potassium glutamate
Lysine hydroch loride
H-Tyrosine
•Choleretics and liydrocholeretics:
Bile acids, oxidized
Uehydrocholic acid
Florantyrone
Iron bile salts
Ox bile extracts
Sodium dehydrocholate
Tocamphyl
•Choline chloride:
Feed grade
Medicinal grade
•Other gastrointestinal agents and therapeutic
nutrients :
Gastrointestinal agents:
Cathartics :
Magnesium citrate
Phenolphthalein
Podophyllin
Sodium tartrate
Lipotropic agents:
Betaine base
Betaine hydrochloride
Choline bicarbonate
Choline bi tart rate
Choline citrate (Iricholine citrate)
Choline dihydrogen citrate
Methionine, hydroxy analogue, calcium salt
Sitosterols
QMS.
mal.
SDW.
x.
MAL.
MAL.
SDW.
CGY.
NEP.
EK.
HFT, MAL, WAG, WHL.
GAN, HEX, PEN.
MON.
PEN.
NEP.
MDJ.
HEX.
DA, HFT.
LEM.
LEM.
MRK.
MDJ.
SRL. WIL.
WIL.
SRL.
LIL, WIL.
ABB, WIL.
WIL.
X.
CUM, DA, DOW, HFT, TMH.
HFT.
MON.
ABB,
PEN
MAL
HFI.
HFT.
CUM.
ACY,
HFT
ACY,
HFT
ACY,
HFT
DUP,
MON
LIL,
UPJ
SYNTHETIC ORGANIC CHE^ICUS. 197?
Table 2-
-Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED
♦Gastrointestinal agents and therapeutic
nutrients- -Continued
*Other gastrointestinal agents and therapeutic
nutrients- -Continued
Gastrointestinal agents — Continued
Other gastrointestinal agents:
Dihydroxyaluminum aminoacet at e
Pectin
Therapeutic nutrients:
Calcium glucoheptonate
Calcium gluconate
Copper gluconate
Ferrous gluconate
Liver concentrate
Liver, desiccated
Magnesiun gluconate
Manganese gluconate
Potassium gluconate
Zinc glucoheptonate
'Hematological agents:
Anticoagulants:
Ammonium heparin
Anisindione
Bishydroxycoumarin
Diphenadione
* Sod ium heparin
Warfarin
*Other hematological agents:
Cellulose, oxidized
Dextran
Protamine
*Hormones and synthetic substitutes:
•Antithyroid agents:
Methimazole
Propy 1 1 h iour ac i 1
2-lhiouracil
♦Corticosteroids :
Betamethasone
Betamethasone phosphate
Betamethasone valerate
Cortisone acetate
Dexamethasone
Dexamethasone phosphate
Fludrocortisone acetate
Fluorometholone
9a-Fluoroprednisolone acetate
Fluprednisolone
Hydrocortisone
Hydrocortisone acetate
Medrysone
Methylprednisolone
Prednisolone
Prednisolone acetate
Prednisone
Triamcinolone
iriamcinolone acetonide
♦Estrogens and progestogens:
Chlorotrianisene
Dienestrol diacetate
Diethylstilbestrol
Diethylstilbestrol diphosphate
Manufacturers' identification codes
(according to list in table 3)
CHT.
SKG.
PFN
PFZ,
PFZ.
PFZ.
WIL.
WIL.
PFZ.
PFZ.
PFZ.
ABB,
WIL.
SCH.
ABB.
UPS.
ABB,
RIK,
WIL
SDW.
EKT.
PHK.
lil
LIL.
CTN.
ACY .
bCH.
SCH.
SCH.
MRK,
UPJ.
MKK,
SCH.
MRK.
UPJ.
UPJ.
UPJ.
UPJ.
MKK,
PFZ,
UPJ
MRK,
UPJ.
UPJ.
UPJ.
MRK,
UPJ.
UPJ.
MKK,
SCH,
UPJ
ACY,
UMS,
X.
OMS.
BJL,
BKC.
SCH.
CTN
LIL.
MEDICINAL CHEfllCALS
Table 2,-
-FIeDICINAL chemicals for which U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
*Horinones and synthetic substitutes — Continued
'Estrogens and progestogens--Continued
hstrogenic substances, conjugated
MedroxvTirogesterone acetate
Melengestrol acetate
Natural estrogenic substance
Norgestrel
Progesterone
'Synthetic hypoglycemic agents:
Acetohexamide
Chlorpropamide
Phenformin hydrochloride
Tolazamide
I'D Ibut amide
*Other hormones and synthetic substitutes:
Anabolic agents and androgens:
Fluoxymesterone
Testosterone cypionate
Zeranol
Corticotropin (ACTH)
Glucagon
Insulin
Ihyroid
*Renal-acting and edema-reducing agents:
*Benzothiadiazine derivatives:
Bendrof lumethiazide
Benzthiazide
Chlorothiazide
Cyclothiazide
F lumethiazide
Hydrochlorothiazide
Hydroflumethiazide
Met hyc loth lazide
Polythiazide
Irichlormethiazide
'Mercurial diuretics:
Meralluride
Mersalyl acid
Sodium mercaptomeri n
'Theophylline derivatives:
Aminophylline
Oxtriphylline
Theophylline sodium glycinate
'Other renal-acting and edema- reducing agents:
Acetazol amide
Chlorthalidone
Dichlorphenamide
Ethacrynic acid
Probenecid
Triamterene
'Vitamins :
'Vitamin A alcohol and esters:
Beta-carotene (Provitamin A)
Vitamin A acetate (feed grade)
Vitamin A acetate (medicinal gradej
Vitamin A alcohol
'Vitamin A palmitate (feed gradej
Vitamin A palmitate (medicinal grade)
ORG.
UPJ.
UPJ.
OKG.
WYT.
UPJ.
LIL.
PFZ.
BKL.
UPJ.
UPJ.
UPJ.
UPJ.
COM.
ORG.
LIL.
LIL.
LIL.
MKK.
LIL.
UMS.
ABB,
LGY, MRK.
LKL.
SUW.
WYT.
GAN,
SRL.
NEP.
CHT.
ACY.
CGY.
MRK.
MRK.
MRK.
ACY,
SK.
EKT,
HOF.
HOF,
PFZ.
HOF,
PFZ.
HOF,
PFZ.
EKT,
HDF,
PF
EKi,
HUF,
PF
SYNTHETIC ORGANIC CHEMICALS, 1972
Table 2.
-Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
'Vitamins --Continued
*Vitamin B-complex:
*Niacin and niacinamide (all grades) :
Niacin (nicotinic acid) (feed grade)
Niacin (nicotini'- acid) (medicinal grade)
Niacinamide
'Pantothenic acid and derivatives:
Calcium pantothenate (dextro)
Calcium pantothenate (racemic) (feed grade)
Calcium pantothenate (racemic) (medicinal grade)--
*Calciuin pantothenate (racemic) - calcium chloride
complex.
Choline pantothenate
Dexpanthenol
Panthenol (racemic)
Sodium pantothenate
'Riboflavin (all grades):
Riboflavin (feed grade)
Riboflavin (medicinal grade)
'Other B-complex vitamins:
Biotin
Cyanocobalamin (feed grade)
Cyanocobalamln (medicinal grade)
Cyanocobalamin (U.S. P. crystalline)
Cyanocobalamin with intrinsic factor concentrate--
Inositol
Ni acinami de hydrochloride
Pyridoxine
Riboflavin-5 -phosphate, sodium
Thi amine hydroch loride
Thiamine mononitrate
'Vitamin C:
'Ascorbic acid
falcium ascorbate
Sodium ascorbate
'Vitamin D:
Cholecalciferol (Vitamin D3)
Ergocalciferol (Vitamin Dj)
'Vitamin E:
d- Alpha tocopherol
dl -Alpha tocopherol
*d- and dl-Alpha tocopheryl acetate (all grades) :
d-Alpha tocopheryl acetate
dl-Alpha tocopheryl acetate:
Feed grade
Medicinal grade
Technical grade
d-Alpha tocopheryl acid succinate
'Vitamin K:
Menadiol sodium diphosphate
Menadione
Menadione sodium bisulfite
Phytonadione
'Miscellaneous medicinal chemicals:
Antineoplastic agents:
Azathioprine
Mercaptopurine
Thioguanine
Vinblastine sul fate
Vincristine sulfate
Smooth muscle relaxants:
Alverine
Alverine citrate
Alverine hydrochloride
Papaverine hydrochloride
Sodium benzyl succinate
DA,
MRK,
RIL.
MRK
RIL
SCR.
MRK
NEP
PD, RIL,
SCR
HFT
CKL
DA,
HFT, PHF.
DA,
HFT.
CKL
DA,
DLI, HFT.
dli
HFT
HOF
HOF
PD.
GPR, HOF, MRK, PMP.
DA, HOF, MRK.
HOF
MRK
MRK
MRK
WIL
STA
NEP
HOF
MRK
HOF
HOF
MRK
HOF
MRK
HOF
MRK
PFZ.
PFZ
HOF
MRK
PFZ.
DA,
DLI,
PHF, VTM
SCR
VTM
CW,
EKT.
HOF
CW,
EKT.
HOF
DA,
EKT,
HOF.
DA.
CW,
EKT.
HOF.
ABB, HET, WHL.
ABB, DA, DLI, HET, HFT, WHL.
MRK.
BUR.
BUR.
BUR.
LIL.
LIL.
CTN.
X.
CTN.
LIL, MAL, PEN.
FIN.
MEDICINAL CHEMICALS
Table 2, --Medicinal chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED
Chemical
Manufacturers' identification codes
(according to list in table 3)
Miscellaneous medicinal chemicals--Continued
Unclassified medicinal chemicals:
BUR.
PEN.
SOW.
PEN.
BID, HOF.
MRK.
ALD.
Berberine hydrochloride
Dopamine hydrochloride
Hydras t ine hydroch lori de
Penicillamine (copper chelating agent)
All antibiotics listed are for medicinal use unless otherwise specified.
Producers of technical grade are listed in "Miscellaneous chemicals."
Producers of technical grade are listed in "Cyclic intermediates."
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 3.— Medicinal Chemicals: Directory of Manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of medicinal chemicals to the U.S. Tariff Commission for
1972 are listed below in the order of their identification codes as used in table 2]
Name of company
Name of company
Abbott Laboratories
Allied Chemical Corp., Specialty Chemicals Div.
American Cyanamid Co,
Aldrich Chemical Co., Inc.
Arenol Chemical Corp.
Arsynco, Inc.
Astra Pharmaceutical Products, Inc.
Northern Fine Chemicals, Inc.
Beecham, Inc.
Bio-Derivatives Corp.
Burdick 5 Jackson Laboratories, Inc.
J.T. Baker Chemical Co.
Millmaster Onyx Corp., Millmaster Chemical Div.
Berkeley Chemical Dept .
Biocraft Laboratories, Inc.
Stauffer Chemical Co., Specialty Chemical Div.,
Benzol Products
Bristol-Myers Co., Bristol Laboratories Div.
Burroughs-Wellcome Co.
Ciba-Geigy Corp. and Ciba Pharmaceutical Co.
Chattem Drug 5 Chemical Co., Chattem Chem-
icals Div.
Chemlek Laboratories, Inc.
Commercial Solvents Corp.
Chemetron Corp., Organic Chemical Div.
General Mills Chemical, Inc.
Diamond Shamrock Corp.
Dawe's Laboratories, Inc.
Dow Chemical Co.
E.I. duPont de Nemours 5 Co. , Inc.
Eastside Chemical Laboratory
Eastman Kodak Co. :
Tennessee Eastman Co. Div.
Endo Laboratories, Inc.
Fine Organics, Inc.
Fisher Chemical Co., Inc.
Fleming Laboratories, Inc.
GAF Corp., Chemical Div.
Cane's Chemical Works, Inc.
Givaudan Corp.
General Foods Corp., Maxwell House Div.
Grain Processing Corp.
Heterochemical Corp.
Hexagon Laboratories, Inc.
Hoffman-Taff, Inc.
Tenneco Chemicals, Inc.
Hoffmann- LaRoche, Inc.
Hynson, Westcott 5 Dunning, Inc.
ICI America, Inc., Atlas Chemical Div.
Jefferson Chemical Co., Inc.
Koppers Co., Inc., Organic Materials Div.
Lemke Chemicals, Inc.
Eli Lilly S Co.
MAL
MDJ
MLS
MON
MRK
NEP
NES
NOR
NTL
OMS
ORG
ORT
PEN
PFN
PFZ
PHF
PHR
PMP
RDA
RIK
RIL
RLS
RSA
SAL
SCH
SCR
SDG
SDH
SDW
SHC
SK
SKG
SRL
STA
TMH
TRD
UCC
HOP
UPJ
WAG
WHL
WIL
WRC
IVTL
Lakeside Laboratories Div. of Colgate-
Palmolive Co.
Mallinckrodt Chemical Works
Mead Jolinson 5 Co.
Miles Laboratories, Inc., Marschall Div.
Monsanto Co.
Merck 5 Co. , Inc .
Nepera Chemical Co., Inc.
Nease Chemical Co., Inc.
Norwich Pharmacal Co.
NL Industries, Inc.
E.R. Squibb S Sons,
Organics, Inc.
Roehr Chemicals, Inc
Inc.
Parke, Davis S Co.
CPC International, Inc.,
Pfanstiehl Laboratories,
Pfizer, Inc.
Thompson-Hayward Chemical Co.
Pharmachem Corp.
Premier Malt Products, Inc.
Peter Hand Div.
Rhodia, Inc.
Riker Laboratories, Inc., Sub. of 3M Co.
Reilly Tar ^ Chemical Corp.
Rachel le Laboratories, Inc.
R.S.A. Corp.
Salsbury Laboratories
Schering Corp.
R.P. Scherer Corp.
Sterling Drug Corp. :
Glenbrook Laboratories Div.
Hilton-Davis Chemical Co. Div.
Winthrop Laboratories Div.
Shell Oil Co., Shell Chemical Co. Div.
Smith, Kline 5 French Laboratories
Sunkist Growers, Inc.
G.D. Searle 5 Co.
A.E. Staley Manufacturing Co.
Thompson-Hayward Chemical Co.
Trade Enterprises, Inc.
Union Carbide Corp.
Universal Oil Products Co., UOP Chemical Div.
Upjohn Co.
Vermi lye- Bell
Vitamins, Inc.
West Agro-Chemicals, Inc.
Whitmoyer Laboratories, Inc.
Wilson 6 Co., Inc., Wilson Laboratories Div.
Ventron Corp., Ventron Chemical
Pennwalt Corp., Lucidol Div.
Wyeth Laboratories, Inc., Wyeth Laboratories
Div. of American Home Products Corp.
-Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix
121
FLAVOR ANB PERFUME MATERIALS
Flavor and perfume materials are organic chemicals used to impart
flavors and odors to foods, beverages, cosmetics and soaps. These
aromatic chemicals are also utilized to neutralize or mask unpleasant
odors in industrial processes and products as well as in consumer
products.
Total domestic production of flavor and perfume materials in 1972
amounted to 110.5 million pounds--an increase of 14.6 percent compared
to 96.4 million pounds produced in 1971 (table 1).^ Sales of these
materials in 1972 amounted to 104.0 million pounds, valued at $88.4
million, compared with 84.8 million pounds, valued at $84.0 million in
1971.
Production of cyclic flavor and perfume materials in 1972 amounted
to 51.8 million pounds; sales amounted to 48.2 million pounds, valued
at $54.1 million. The individual chemical in the cyclic group produced
in the greatest volume in 1972 again was benzyl alcohol (10.4 million
pounds) .
U.S. output of acyclic flavor and perfume materials in 1972 amounted
to 58.5 million pounds; sales of these materials amounted to 55.7 million
pounds, valued at $34.1 million. Monosodium glutamate was by far the most
important of the acyclic chemicals, and the individual flavor and perfume
chemical produced in the greatest volume.
Domestic production of essential oils, chemically modified, in 1972
amounted to 119 thousand pounds; sales amounted to 93 thousand pounds and
were valued at $220 thousand. Both cyclic and acyclic compounds were rep-
resented among the group, however, the totals above for cyclic and acyclic
flavor and perfume materials do not include items of this group.
See also table 2 which lists these materials and identifies the
manufacturers by codes. These codes are given in table 3.
SY:JTHETIC organic chemicals, 1972
TABLE 1. --Flavor and perfume materials; U.S. production and sales, 1972
[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub-
lished or where no data were reported.) Table 2 lists all flavor and perfume materials for which data on produc-
tion or sales were reported and identifies the manufacturers of each]
Quantity
1,000
pounds
Grand total
FLAVOR AND PERFUME MATERIALS, CYCLIC
Total
Benzenoid and Naphthalenoid
Total
4-Allyl-2-methoxyphenol (Eugenol)
p-Anisaldehyde
Ben zophenone
Benzyl acetate
Ben zyl al cohol ^
Ben zy 1 benzoate
Benzyl but yr ate
Benzyl cinnamate
Benzyl propionate
Benzyl salicylate
Cinnamaldehyde
Cinnamyl acetate
Cinnamyl alcohol
Cinnamyl an th rani late
Ethyl phenylglycidate
Hydrocoumarin
Isobutyl phenyl acetate
Isobutyl salicylate
Isopentyl salicylate
Methyl anthranilate
a-Methylbenzyl acetate (Styralyl acetate)
Methyl phenyl acetate
Methyl salicylate
Phenethyl acetate
2-Phenethyl phenylacetate
3-Phenyl-l-propanol (Hydrocinnamic alcohol)
Piperonal (He lio tropin)
p-Propenylanisole (Anethole)
p-Tolualdehyde
All other benzenoid and naphthalenoid materials--
Terpenoid, Heteroayolio, and Aliayclic
Total
Cedryl acetate
a-Ionone
p-Menthan-3-one (Methone)
Menthol, synthetic, u.S.P
Methylionones
51.809
45,756
473
1,065
449
1,414
10,440
408
419
1,565
5,828
2,650
17,944
8,053
48.166
41,311
380
1,261
300
1,678
13,444
621
11
7
34
450
1,127
9
277
1
453
185
124
,540
1,000
dollars
54,058
41,134
1,044
1,683
407
657
3,922
350
16
30
40
411
790
21
14
313
269
48
61
337
1,537
103
25,709
497
378
1,874
1,665
See footnotes at end of table.
FLAVOR A;1D PERFUIE '1ATER1ALS
TABLE 1.— Flavor and perfume materials; U.S. production and sales.
1972--CONTINUED
Production
Quantity
Unit
value'
FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued
Terpenoid, Heteroayclia, and Alieyolio — Continued
Terpineols
a-Terpinyl acetate
Vetivenyl acetate
All other terpenoid, heterocyclic, and alicyclic materials-
FLAVOR AND PERFUME MATERIALS, ACYCLIC
Total
Allyl hexanoate
Citronellyl acetate
3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol)
3,7-Dimethyl-trans-2,6-octadienal (Citral a; Geranial)
3,7-Dimethyl-trans-2,6-octadien-l-oI (Geraniol)
3,7-DimethyI-6-octen-l-ol (Citronellol)
Ethyl butyrate
Ethyl heptanoate
Ethyl hexanoate (Ethyl caproate)
Geranyl acetate
Gerany 1 butyrate
Geranyl formate
Glutamic acid, monosodium salt (Monosodium glutamate)
7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal)
Isopentyl butyrate
Isopentyl formate
Isopentyl isovalerate
Rhodinol
All other acyclic materials
ESSENTIAL OILS, CHEMICALLY MODIFIED
Total
Ethyl oxyhydrate
Guaicwood acetate
All other chemically modified essential oils
1,000
pounds
3,017
585
18
53
1,196
1,004
532
47,324
1,000
pounds
!,778
52-7
876
587
468
48,136
442
1,000
dollars
1,163
403
560
6,485
36
119
137
1,473
966
302
15
10
201
11
29
21,646
2,440
70
Per
pound
$0.42
.77
20.27
2.70
_.61_
2.46
3.28
4.67
1.68
1.65
.65
1.45
1.98
2.00
2.98
3.20
.45
5.52
.78
1.56
.94
2.72
3.45
'Calculated from the unrounded figures.
^Includes some technical grade.
SYNTHETIC ORGANIC CHEMICALS, 1972-
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
REPORTED, IDENTIFIED BY MANUFACTURER, 1972
[Flavor and perfume materials for which separate statistics are given in table 1 are marked below with an asterisk
(*); those not so marked do not appear in table 2 because the reported data are accepted in confidence and may
not be published. Manufacturers' identification codes are taken from table 3. An x signifies that the manufac-
turer did not consent to his identification with the designated product]
Manufacturers' identification code
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, CYCLIC
Benzenoid and Naphthalenoid
2' -Acetonaphthone
Acet ophenone
l-Acetoxy-2-sec-butyl-l-ethnylcyclohexane
5-Acetyl-l,l,2,3,3,6-hexamethylindan
p-Allylanisole
Allyl cyclohexyl propionate
4-Allyl-l,2-dimethoxybenzene (4-Allylveratrole)
*4-Allyl-2-methoxyphenol (Eugenol)
4-Allyl-2-methoxyphenoI acetate (Eugenol acetate)
4- Allyl -1,2- (methylenedioxy) benzene (Safrole)
Allyl phenoxyacetate
p-tert-Amylcyclohexanone (Grivone)
*p-Anis aldehyde
Anisole (Methyl phenyl ether)
Anisyl acetate
*Benzophenone
*Benzyl acetate
'Benzyl alcohol
*Benzyl benzoate
*Benzyl butyrate
*Benzyl cinnamate
Benzyl ether
Benzyl formate
Benzyl glyceryl acetal
Benzyl isobutyrate
Benzyl isopentyl ether
Benzyl isovalerate
Benzyl laurate
1- (Benzyloxy) -2-methoxy-4-propenylbenzene (Benzyl
isoeugenyl ether).
Benzyl phenylacetate
*Benzyl propionate
*Benzyl salicylate
a-Bromostyrene
2-5ec-Butylcyclohexanone
p-tert-Butylcyclohexyl acetate
4-tert-Butyl-2' ,6' -dimethyl- 3' ,5' -dinitroacetophenone
(Musk ketone).
6-tert-Butyl-3-methyl-2,4-dinitroanisole (Musk ambrette)-
p-tert-Butyl-a-methylhydrocinnamaldehyde
l-tert-Butyl-3,4,5-trimethyl-2,6-dinitrobenzene (Musk
Tibetene) .
5-tert-Butyl-2, 4, 6-trinitro-m- xylene (Musk .xylol)
Carvacrol
*Cinn amal dehy de
Cinnami c acid
*Cinnamyl acetate
*Cinnamyl alcohol
*Cinnamyl anthranilate
Cinnamyl butyrate
Cinnamyl cinnamate
Cinnamyl propionate
Cinnamyl tiglate
Coumarin
GIV.
GIV.
GIV.
PFW.
GIV, GLD.
GIV.
GIV, UOP.
CI, FB, GIV, IFF, PEN, RT, UNG, UOP
CI, GIV.
FB, GIV.
GIV.
IFF.
GIV, OPC, UOP.
GIV.
ELN, GIV, UOP.
GAF, GIV, NEC, PD, UOP.
GIV, MON, OPC, UOP.
BPC, HN, MNR, UOP, VEL.
MON, OPC, PFZ, UOP, VEL.
ELN, FB, GIV.
FB, GIV, UOP
UOP, VEL.
GIV, UOP.
GIV.
GIV.
GIV.
FB.
GIV.
GIV, UOP.
ELN, GIV.
ELN, FB, GIV, OPC.
GIV, MON, UOP.
UOP.
GIV.
CI, IFF.
GIV.
GIV.
GIV, UOP.
GIV, UOP.
GIV.
GIV.
CI, FB, UOP.
BPC.
ELN, FB, GIV.
FB, GIV, NEO, UOP.
PEL, GIV, RT.
FB.
FLAVOR AND PERFUHE MATERIALS
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
REPORTED, IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued
Bemenoid and Naphthalenoid — Continued
Cuminyl alcohol
Cyclohexylcychohexanone
trans- Decahydro-B-napht hoi
2,4-Dibromo-6-nitro-meta-cresyl methyl ether
1 ,2- Diiiiethoxy-4-propenylbenzene (4-Propenylveratrole)
p-a-Dimethylbenzyl alcohol
3,7-Dimethyl-l ,6-octadien-3-yl , anthranilate (Linalyl
anthranilate) .
3,7-Dimethyl-l,6-octadien-3-ol , benzoate (Linalyl
benzoate) .
3,7-Dimethyl-l ,6-octadien-3-ol , cinnamate (Linalyl
cinnamate
3, 7-Dimethyl-2 ,6-octadienylphenylacetate (Geranyl
phenylacetate) .
trans-3 ,7-Dimethyl-2 ,6-octadien-l-ol , benzoate (Geranyl
benzoate) .
a,a-Dimethylphenethyl acetate
a,a-Dimethylphenethyl alcohol
a,a-Dimethylphenethyl alcohol, butyrate
a,a-Dimethylphenethyl alcohol, tech
Diphenylme thane f Benzylbenzene)
1 ,3-Diphenyl-2-propanone (Dibenzyl ketone)
p-Ethoxy benzaldehyde
2-Ethoxynaphthalene
Ethyl anthranilate
Ethyl benzoate
Ethyl cinnamate
Ethyl a,B-epoxy-B-methylhydrocinnamate
2-Ethylhexyl salicylate
Ethyl phenylacetate
*Ethyl phenylg lye i date
Ethyl salicylate
3'-Ethyl-5' ,6' ,7' ,8' -tetrahydro-5' ,5' ,8' ,8' -
tetramethyl-2'-acetonaphthone.
Ethylvanillin (4-Hydroxy-3-ethoxybenzaldehyde)
1 ,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethyl cyclopenta-
gamma-2-henzopyran (Galaxolide 50).
Hexyl benzoate
a-Hexylcinnajnaldehyde
Hydra tropaldehyde
Hydratropaldehyde, dimethyl acetal
Hydrocinnamic acid
*Hydrocoumarin
Hydroxycitronellalmethyl anthranilate
4- (4-Hydroxy-3-methoxyphenyl)-2-butanone
Indole
Isoamyl phenylacetate
Isobutyl benzoate
p-Isobutyl-a-mathylhydrecinnamaldehyde (Rhodial)
*Isobutyl phenylacetate
Isobutylquinoline
*lsobutyl salicylate
Isohexenyl tetrahydrobenzaldehyde (Myrac aldehyde)
Isopentyl benzoate
'Isopentyl salicylate
GIV.
GIV.
IFF.
GIV.
GIV, UOP.
GIV.
FMT.
HOF.
HOF.
GIV.
GIV.
IFF.
IFF.
IFF.
IFF.
ARA, UOP.
GIV.
GIV.
GIV.
FB.
ELN.
ELN, GIV.
ELN, GIV.
FEL.
GIV.
GIV, PFW, UOP.
FB.
GIV, MOP.
GIV, UOP.
MON, SLV.
IFF.
IFF
IFF.
IFF.
GIV.
CI,
GIV,
GIV,
ARS.
ARS,
GIV.
GIV.
GIV.
GIV.
ELN.
RDA.
ELN,
IFF.
FB,
IFF.
GIV.
FB, GIV, MON, OPC, UOP.
FB, GIV.
GIV, UOP.
552-743 0-74-9
SYNTHETIC ORGANIC CliE"ICALS. 197''
TABLE 2,— Flavor and perfume materials for which U.S. production or sales were
REPORTED. IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued
Bemenoid and Naphthalenoid — Continued'
p-Isopropyl benzaldehyde (Cumaldehyde)
p-Isopropylcyclohexanol
p-Isopropyl-a-methylhydrocinnamaldehyde
(Cyc lamena Idehyde )
Isovanillin (3-Hydroxy-4-iiiethoxybenzaIdehyde)
p-Mentha-l,8-diene (Limonene]
Men thy 1 anthranilate
4 ' -Methoxyacetophenone (Acetanisole)
p-Methoxybenzyl alcohol [Anisyl alcohol)
o-Methoxycinnamaldehyde
2-Methoxynaphthalene
l-(p-Methoxyphenyl)-l-penten-3-one
2-Methoxy-4-propenylphenol (Isoeugenol)
2-Methoxy-4-propenylphenol , acetate
4 '-Methyl ace tophenone
p-Methylanisole
*Methyl anthranilate
Methyl anthranilidene-p-isopropyl methylhydro-
cinnamaldehyde (Orangeol N) .
Methyl benzoate
*a-Methylbenzyl acetate (Styralyl acetate)
a-Methylcinnamaldehyde
Methyl cinnamate
6-Methylcoumarin
Methylcyclohexyl propionate
1 ,2- CMethylenedioxy)-4-propenylbenzene (Isosafrole)
p-Methylhydratropaldehyde
l-Methyl-4-isohexyl-hexahydrobenzaldehyde
CVemaldehyde) .
Methyl N-methy Ian thrani late
*Methyl phenyl acetate
*Methyl salicylate
IH-Naphtho- [2 , 3-c] pyTan-3 , 4,6,7,8, 9-hexahydro-4 ,6,6,9,9-
pentaraethyl (Musk 89) .
1,1 ,3,3,5-Pentamethyl-4,6-dinitroindan
a-Pentylcinnaraa Idehyde
*Phenethyl acetate ^
Phenethyl alcohol
Phenethyl formate
Phenethyl Isobutyrate
Phenethyl isovalerate
*2-Phenethyl phenylacetate
Phenethyl propionate
Phenethyl salicylate
2-Phenoxyethyl isobutyrate
Phenylacet a Idehyde
Phenylacetaldehyde, dimethyl acetal
o-Phenylanisole (2 -Methoxybi phenyl)
4-Phenyl-3-buten-2-one (Benzyl ideneacetone)
Phenylethyl acetal
Phenyl ethyl tig late
*3-Phenyl-l-propanol (Hydrocinnamic alcohol)
3-Phenylpropyl acetate
3-Phenylpropyl cinnamate
*Piperonal (Heliotropin)
Manufacturers' identification codes
(according to list in table 3)
GIV.
GIV.
GIV, RDA.
SLV.
SKG.
PFW.
GIV, UOP.
GIV, UOP.
CI.
GIV.
GIV.
CI, GIV.
UOP.
GIV, UOP.
GIV, UOP.
FB, OPC, PFW,
SW, UNG
RDA.
HN.
CI, ELN, GIV,
UNG.
FB, GIV.
CI, FB, UOP.
GIV.
GIV.
GIV.
GIV.
GIV.
GIV, OPC.
ELN, GIV, OPC
DOW, HN, MON.
IFF,
GIV.
CI, FB, GIV,
HOP.
GIV, IFF, NEO
IFF, NEO.
ELN, IFF.
ELN, GIV, IFF
GIV, OPC.
CI, ELN, GIV,
IFF.
GIV.
GIV.
GIV.
GIV.
GIV, UOP.
GIV.
FB, UOP.
GIV.
FB.
ELN, FB, GIV.
UOP.
GIV.
AMB, GIV, UOP.
FLAVOR AND PERFUME MATERIALS
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
REPORTED, IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, CYCLIC — Continued
Benzenoid and Naphthalenoid — Continued
Piperonal bisulfite (Heliotropin bisulfite)
*p-PropenyIanisole (Anethole)
p-PropylanisoIe (Dihydroanethole)
N-Propylphenylethyl alcohol
Sweeteners, synthetic;
Cyclohexanesulfamic acid
Cyclohexanesulfamic acid, calcium salt
Cyclohexanesulfamic acid, sodium salt
Saccharin (1 ,2-Benzisothia2olin-3-one , 1 , 1-dioxide)-
Saccharin, ammonium salt
Saccharin, calcium salt
Saccharin, sodium salt
*p-Tolualdehyde
p-Tolylacet aldehyde
p-Tolyl acetate
p-Tolyl phenylacetate
a-CTrichloromethyl) benzyl acetate (Rosetone)
Vanillin (4-Hydroxy-3-methoxybenzaldehyde)
Terpenoid, Heteroayolia , and Alicyclic
Acetyl cedrone fVertofix)
Cadinene
6-Caryophyllene
Caryophyllene oxide
a-Cedrene epoxide (Andrane)
Cedrenol
Cedrol
*Cedryl acetate
Cedryl formate
Cycl open tan one
Dihydronordicyclopentadienyl acetate
D ih ydronordi cycl open t ad ienyl propionate
Dihydroterpinyl acetate
3-Hydroxy-2-ethyl-4-pyrone (Ethyl maltol)
16-Hydroxyhexadecanoic acid, o-lactone
(Hexadecanolide) .
4- (4-Hydroxy-4-methylpentyl)-3-cyclohexene-10-
carboxaldehyde (Lyral).
3-Hydroxy-2-methyl-4-pyrone (Maltol)
4-Hydrox)Tionanoic acid, Y-l3<^tone (y-Nonalactone)
4-Hydroxyoctanoic acid, y-lactone (y-Octalactone)
4-Hydroxyundecanoic acid, y-lactone (y-Undecalactone)-
lonones :
*ot-Ionone
S-Ionone
lonone (a-and 6-)'
Isoborneol
Isobomyl Acetate
Isobomyl propionate
Isojasmone
Isomenthone
4-Isopropylcyclohexanol
Jasmal
p-Mentha-6,8-dien-2-ol (£-Carveol)
p-Mentha-6 ,8-dien-2-one (Carvone; CarVol)
AMB.
ARZ, GLD,
FB, GIV.
GIV.
ABB.
HON, SW.
SW.
MON, SW.
HON, SW.
GIV, HN,
GIV.
FB, GIV.
GIV.
NEO.
MON, SLV.
FB.
CI, (
GIV.
IFF.
GIV.
ELN,
ELN,
IFF.
ARA.
GIV,
i;iv,
GIV.
PFZ.
IFF.
HN, HPC, NCI, UOP.
GIV, IFF, NEO.
GIV, IFF, NEO, UNG, UOP.
IFF
IFF
IFF.
PFZ-
GIV,
UOP
GIV,
RT,
UOP.
ELN,
FB.
GIV
HOF
IFF,
MYW
HOF
MYW
GIV
MYW
NEO,
UNG
RDA
FB,
OPC,
RDA.
GIV
OPC
FB.
GIV
UOP.
IFF
SYNTHETIC ORGAMIC CHEMICALS. 1972
TABLE 2, --Flavor and perfume materials for which U.S. production or sales were
REPORTED, identified BY MANUFACTURER. 1972--CONTI NUED
Manufacturers' identification codes
(according to list in table 5)
FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued
Terpenoid, Heteroayalic, and Aliayalio — Continued
p-Mentha-6,8-dien-2-ol , acetate (K-carvyl acetate)
p-Mentha-l,3-diene (oi-Terpinene)
p-Mentha-l,4-diene [y-Terpinene)
*p-Menthan-3-one (Menthone)
p-Menth-l-en-3-one
p-Menth-4C8)-en-5-one (d-Pulegone)
p-Menth-8-en-3-ol (Isopulegol)
1 , l-p-Menthen-6-yl-l-propanone
Menthol, synthetic:
Tech
•U.S.P
Menthyl acetate
*Methylibnones:
b-Methyl-ot-ionone
Methylionone (a- and B-)
Y-Me thy lion one
Nopyl acetate
3-Pentyl-tetrahydro-4-pyranol CJessemal)
Santalol
Santalyl acetate
*Terpineols :
a-Terpineol
Terpineol (a- and B-)
Terpinol hydrate (Terpin hydrate) , tech
*a-Terpinyl acetate
Terpinyl acetate Cmixed a- and B-)
a-Terpinyl propionate
Tetrahy drops eudo ion one
l-(2 ,6,6-Trimethyl-2-cyclohexen-l -yl)-l ,6-heptadien-
3-one (Allyl-a-ionone) .
3,3,5-Triniethyl cyclohexanol (Horaomenthol)
Vetivenol
*Vetivenyl acetate
FLAVOR AND PERFUME MATERIALS, ACYCLIC
Acetylbutyryl C2 ,3-Hexanedione)
Acetylpropionyl
Acetylvaleryl (2,3-Heptanedione)
Allyl disulfide-
Allyl hep tan oat e
*Allyl hexanoate
Allyl isothiocyanate (Synthetic mustard oil)
Allyl octanoate (Allyl caprylate)
Allyl sulfide
Amyl propionate
Butyl butyryl lactate
l-Chloro-2-iiiethyl-butene-2
Citral dimethyl acetal
*Citronellyl acetate
Citronellyl butyrate
Citronellyl formate
Citronellyl isobutyrate
Citronellyl methyl acetal
Citronellyl oxyacet aldehyde
Citronellyl propionate
GLD.
GLD.
CIV
HN,
NEO.
GIV
GIV
GIV
GIV.
GIV,
HN.
GIV,
GLD
HN,
NEO.
GIV.
GIV,
MYW
GIV,
IFF
MYW
NEO, UNG
GIV.
CI,
FEL,
NEO,
RDA.
IFF.
GIV.
GIV.
GLD,
HPC
NCI
GIV.
NEO
HPC.
GIV,
NEC
PFW
UNG.
RDA.
ELN,
GIV
ARS.
GIV, UOP.
ELN, FB, GIV, IFF, NEO, UOP.
ELN,
FB,
RT.
RT.
GIV.
ARS.
RDA.
GIV,
IFF
ELN,
GIV
GIV.
ELN,
GIV
ELN,
GIV
IFF.
IFF.
IFF.
FLAVOR AND PERFUME NATERIALS
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were
REPORTED^ identified BY MANUFACTURER, 1972— CONTI NUED
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued
Decanal (Capr aldehyde)
Decen-9-ol-l (Rosalva)
Decyl acetate-
Diethyl acetal
Diethyl sebacate
Diethyl succinate
Dihydromyrcenol
Dihydromyrcenyl formate (Dimyrcetol)
Dihydro safrol
2,6-Dimethyl-5-hepten-l-al
3,6-Dimethyl-5-hepten-2-ol and 7-Methyl-6-octen-3-ol
(Brazinol) .
3,7-Diinethyl-l ,6-nonadien-3-ol (Ethyl linalool)
3,7-Dimethyl-l,6-nonadien-3-ol, acetate
3,7-Dimethyl-2,6-nonadienenitrile
3,7-Diniethyl-2,6-octadienal (Citral)
*3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol)
*3,7-Diraethyl-trans-2,6-octadienal (Citral a; Geranial)-
3,7-Dimethyl-trans-2,6-octadienal dimethyl acetal
*3,7-Dimethyl-trans-2, 6-octadien-l-ol (Geraniol)
3,7-Diraethyl-trans-2,6-octadien-l-ol HP
(Geraniol HP).
3, 7-Dimethyl-l ,6-octadien-3-ol (Linalool; Linalyl
alcohol) .
3,7-Diiiiethyl-l ,6-octadien-3-ol acetate (Linalyl
acetate) .
3, 7-Dimethyl-l, 6-octadien-3-yl isobutyrate (Linalyl
isobutyrate) .
3, 7-Dimethyl-l ,6-octadien-3-yl propionate (Linalyl
propionate) .
3,7-Dimethyloctan-l-al
3,7-Dimethyloctan-3-ol
3,7-Dimethyl-l,7-octanediol
3,7-Dimethyl-l-octanol (Dihydrocitronellol)
3,7-Dimethyl-6-octen-l-al (Citronellal)
*3,7-Dimethyl-6-octen-l-ol (Citronellol)
3,7-Diraethyl-6-octen-l-ol, cis, trans mixture
2,6-Dimethyl-2-octene-7-yne-6-ol
3,7-Dimethyl-7-octenol and 6-octenol isomer
*Ethyl Butyrate
Ethyl cap rate
Ethyl formate
*Ethyl heptanoate
*Ethyl hexanoate (Ethyl caproate)
2-Ethyl-l-hexanol
Ethyl isohexanoate
Ethyl isovalerate
Ethyl laurate
Ethyl myristate
Ethyl nonanoate
Ethyl octanoate
Ethyl propionate
Ethyl valerate
Geranic acid
Geranonitrile
*Geranyl acetate
*Geranyl butyrate
Geranyl dimethyl aery late
*Geran;^l "formate
Geranyl isobutyrate
CI, GIV. IFF.
IFF.
GIV.
ELN,
UCC.
IFF.
IFF.
CI.
GIV.
RDA.
HOF.
HOF.
GIV.
HOF.
ELN,
FB, GIV, GLD, IFF.
FEL, GIV, UOP.
CI,
GIV,
ELN, FB, FEL, GIV, GLD, IFF, NCI, NED, UOP.
ELN,
ELN,
HOF.
HOF.
GIV.
GIV.
FB,
CI,
CI.
RDA.
GIV.
FB, FEL, GIV, GLD, HOF, UNG.
FB, GIV, GLD, HOF, NEO, UNG.
GIV, IFF, NEO, UOP.
ELN, FB, GIV, IFF, NEO, SCM.
ELN
FEL
RT
UOP
ELN
FB,
NW,
PFW,
GIV
PFW
FB,
PFW.
ELN
RT.
FEL
GIV
FB,
RT.
CI,
ELN,
FEL,
GIV
CI,
ELN,
GIV.
FMT.
CI,
ELN,
GIV.
IFF
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2.— Flavor and perfume materials for which U.S. production or sales were
REPORTED, identified BY MANUFACTURER, 1972--CONTINUED
FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued
Geranyl isovalerate
Geranyl neryl formate
Geranyl propionate
Geranyl tig late
♦Glutamic acid, monosodium salt (Monosodium glutamate)-
Y-Heptalactone
Heptanal (Enanthaldehyde) '
Heptyl alcohol (1-Heptanol)
Hexanoic acid (Caproic acid)
2-Hexanol
2-Hexenal
cis-3-Hexen-l-ol
cis-3-Hexen-l-yl acetate
cis-3-Hexen-l-ol lactate
3-Hydroxy-2-butanone (Acetoin)
*7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal) •
7-Hydroxy-3,7-diiiiethyl octanal, dimethyl acetal
(Hydroxycitronellal, dimethyl acetal).
Isoamyl propionate
Isoamyl undecylenate
Isobutyl acetate
Isodihydro lavandulol
Isodihydro lavandulylaldehyde
Isodihydro lavandulyl acetate
*Isopentyl butyrate
*Isopentyl formate
*lsopentyl isovalerate
Lauraldehyde
3-Methyl-5-heptanone oxime
2-Methyl-2-hepten-6-one methyl hexenyl ketone and
6-methyl-5-hepten-2-one.
Methyl isobutyrate
3-Methyl-2-(and 3) nonenitrile
Methyl-2-nonenoate
Methylol methyl hexyl ketone
2-Methylundecanal
Mugual and tetrahydro rauguol
Myrcenyl acetate
Myrist aldehyde
Neryl acetate
Nan anal
Nonane diacetate
Nonane-1 ,3-diol monoacetate
Nonanol
Nonyl acetate
Ocimenol
Ocimenyl acetate
Octanal
Octanal, tech
3-Octanone (Ethyl amyl ketone)
Octyl acetate
n-Octyl acetate
n-Octyl alcohol
Pentyl acetate
Propionic acid ethyl ester
Pseudo linalyl acetate
Pyrolysate ester
*Rhodinol
Manufacturers' identification codes
(according to list in table 3)
FB,
IFF.
FB.
COM
GRW,
UDW
FB.
ntl.
ntl
UCC.
GIV,
GIV.
RT.
FMT.
GIV,
GIV,
gld, iff, NEO, UOP.
UOP.
GIV, NW, PFW, UOP.
, GIV, RT.
, FB, PFW.
GIV.
GIV.
RDA.
PFW.
GIV.
GIV.
GIV.
GIV.
IFF.
IFF.
GIV.
GIV.
GIV.
CI.
GIV.
GIV.
GIV.
IFF.
IFF.
GIV, IFF.
IFF.
GIV.
FB.
GIV.
GIV.
UOP.
UOP.
IFF.
GIV.
FB, FEL, GIV, IFF, NEO.
FLAVOR AND PERFUME MATERIALS
TABLE 2, --Flavor and perfume materials for which U.S. production or sales were
REPORTED, identified BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued
Rhodinyl acetate
Sodi'um allyl sulfonate
Tepyl acetate
3,7,8,8-Tetrainethyl-l ,6-nonadiene-3-ol (Isobutyl
linalool) .
3,7,ll-Trimethyl-l,6,10-dodecatriene-3-ol
2,6, lO-Trimethyl-9-undecen-l-al
3,6,10-Triraethyl-9-undecen-2-one and isomers
Un decanal
9-Undecenal
Y-VaJerolactone
ESSENTIAL OILS, CHEMICALLY MODIFIED
.^jnyris acetate
Clove leaf oil terpenes
* Ethyl oxyhydrate
*Guaiacwood acetate
Guaiene
Lavandin, acetylated
Rose oxide
Sassafrass oil, hydrogenated
GIV.
UOP.
UOP.
HOF.
HOF.
GIV.
GIV.
GIV,
GIV.
GIV.
GIV.
CI, UOP.
FEL, FLO, PFW, RT, VND.
ELN, FB, GIV, NEO.
FB.
FEL, UNG.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 3. --Flavor and perfume materials: Directory of manufacturers. 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of flavor and perfume materials to the U.S. Tariff
Commission for 1972 are listed below in the order of their identification codes as used in table 2]
Code
Name of Company
Code
Name of Company
ABB
Abbott Laboratories
MRT
Morton Chemical Co., Div of
AMB
American Bio-Synthetics Corp.
Morton-Norwich Products, Inc.
ARA
Arapahoe Chemicals Div. of Synte.x Corp.
MYW
Stepan Chemical Co.
ARS
Arsynco, Inc.
ARZ
Arizona Chemical Co.
NCI
Union Camp Corp. , Chemical Division
NEC
Norda Essential Oil 6 Chemical Co. ,
Inc.
BPC
Stauffer Chemical Co., Specialty Chemical
NIL
NL Industries, Inc.
Division, Benzol Products
NK
Northwestern Chemical Co.
CI
Chem-Fleur, Inc.
OPC
Orbis Products Corp.
COM
Commercial Solvents Corp.
PD
Parke, Davis £ Co.
DOW
Dow Chemical Co.
PEN
CPC International, Inc., Penick Division
PFW
Polak's Frutal Works, Inc.
ELN
Elan Cheracial Co.
PFZ
Pfizer, Inc.
FB
Fritzsche, Dodge 6 Olcott, Inc.
RDA
Rhodia, Inc.
FEL
Felton International, Inc.
RT
F. Ritter 5 Co.
FLO
Florasynth, Inc.
FMT
Fairmount Chemical Co. , Inc.
SKG
SLV
Sunkist Growers, Inc.
Sterwin Chemicals, Inc.
GAF
GAF Corp., Chemical Division
SW
Sherwin-Williams Co.
GIV
Givaudan Corp.
GLD
SCM Corp., Glidden-Durkee Division
TCC
Tanatex Chemical Corp.
GRW
Great Western Sugar Co.
UCC
Union Carbide Corp.
HN
Tenneco Chemicals, Inc.
now
William Underwood Co.
HOF
Hoffman- LaRoche, Inc.
UNG
Ungerer 5 Co.
HPC
Hercules, Inc.
■JOP
Universal Oil Products Co., UOP
Chemical Division
IFF
International Flavor & Fragrances, Inc.
MNR
Monroe Chemical Co.
VEL
Velsicol Chemical Corp.
MON
Monsanto Co.
VNP
Van Dyk 6 Co. , Inc.
-Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix.
133
PLASTICS AND RESIN MATERIALS
Plastics and resin materials are high molecular weight polymers
which, at some stage in their manufacture, exist in such physical con-
dition that they can be shaped or otherwise processed by the application
of heat and pressure. Depending on the chemical composition, manufacturing
process or intended use, the commercial products may contain plasticizers,
fillers, extenders, stabilizers, coloring agents or other additives.
Plastics materials may be molded, cast or extruded into semifinished or
finished solid forms. Resin materials may be in the form of solutions,
pastes or emulsions for applications such as protective coatings, adhesives,
or paper and textile treatment.
Statistics on U.S. production and sales of synthetic plastics and
resin materials for 1972 are given in table 1.^ U.S. production of plastics
and resin materials in 1972 totaled 25,921 million pounds, or 23.0 percent
more than the 21,070 million pounds produced in 1971. Sales in 1972 totaled
22,946 million pounds, valued at $4,258 million compared with 18,473 million
pounds, valued at $3,507.
Thermosetting materials are those which harden with a change in
composition in the final treatment so that they cannot again be softened
by heat or solvents. U.S. production of thermosetting materials totaled
4,484 million pounds in 1972 compared with 3,615 million pounds in 1971.
Production of the most important products in 1972 included phenolic resins
(1,441 million pounds), amino (or urea and melamine) resins (929 million
pounds), polyester resins (930 million pounds), and alkyd resins (636
million pounds) .
Thermoplastic materials are those which can be repeatedly softened by
heat and shaped. U.S. production of thermoplastic materials totaled 21,437
million pounds in 1972 compared with 17,455 million pounds in 1971. Produc-
tion of the most important products in 1972 included polyethylene (7,656
million pounds), vinyl resins (5,122 million pounds), and styrene type
materials (4,890 million pounds).
^ See also table 2 which lists these products and identifies the manu-
facturers of each by codes. These codes are given in table 3.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 1, --Plastics and resin materials; U.S. production and sales, 1972
[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all
plastics and resin materials for which any reported data on production or sales may be published. (Leaders (.. .) are
used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all plastics and resin materials for which data on production or sales were reported and identifies
the manufacturers of each]
Production
Grand total
Plastics and resin materials, benzenoid
Plastics and resin materials, nonbenzenoid
THERMOSETTING RESINS
Total
Alkyd resins, total
Phthalic anhydride type
Polybasic acid type
Polyester resins, unsaturated
Styrene alkyd polyesters
Amino resins, total
Mel amine- formaldehyde resins
Urea- formaldehyde res ins
Dicyandiamide resins
Epoxy resins:^
Unmodified
Modified and "advanced"
Furfuryl type resins
Phenolic and other tar acid resins
^Polyurethane and diisocyanate resins (excluding foam and
elastomers)
Polyether and polyester polyols for urethanes
Silicone resins
Other thermosetting resins'
thermoplastic resins
Total
Acrylic resins'
Cellulosic plastics and resins'"
Coumarone-indene resins
Petroleum hydrocarbon resins
Polyamide resins, nylon type'"
Polyamide resins, non-nylon type
Polyester resins, saturated
Polyethylene and copolymers, total
Density 0.940 and below"
Density over 0.940
Polypropylene resins
Polytetrafluoroethylene (PTFE)
Rosin modifications, total
Rosin and rosin esters, unmodified (ester gums)
Other "
1,000
pounds
diry basis ^
25,920,662
8,946,997
16,973,665
4,483,501
597,181
38,735
930,384
12,493
199,473
729,294
179,000
' (43,159)
4,449
1,440,513
99,427
149,191
13,424
87,835
21,437,161
758,589
256,811
49,024
245,359
122,987
27,328
114,969
5,360,310
2,295,939
,730,857
13,248
35,981
92,363
1,000
pounds
dry basis^
22,946,075
1,000
dollars
7,807,933
15,138,142
300,281
22,969
45,767
5,109
759,934
152,831
607,103
' 179,000
9 (26,554)
2,683
1,226,665
48,546
107,773
10,856
79,946
19.354.466
626,856
251,538
233,241
119,009
25,716
43,496
6,932,020
,877,879
,054,141
1,684,507
9,635
121,399
29,170
92,229
1,715,579
2,542,861
83,685
6,154
158,962
1,786
51,924
101,627
' 81,000
'(21,466)
719
260,024
22,331
23,647
20,314
19,599
3.425.327
283,377
132,071
29,342
97,043
15,353
26,373
834,641
594,050
240,591
265,539
31,804
7,684
19,902
See footnotes at end of table.
PLASTICS AND RESIN MATERIALS
TABLE 1. —Plastics and resin materials; U.S. production and sales^ 1972~Continued
Production
Quantity
Unit
value^
1,000
pounds
dry hasis^
THERMOPLASTIC RESINS--Continued
Styrene plastics materials, total
Acrylonitrile-butadiene-styrene (ABS)
Styrene-acrylonitrile resins CSAN)
Styrene and styrene copolymer resins--
Vinyl resins, total'^
Polyvinyl chloride and copolymers-
Polyvinyl acetate ' ^
Polyvinyl alcohol
Lther vinyl and vinylidene resins'
),161
863,725
' 106,000
3,920,436
1,000
pounds
dry basis^
4,557,156
1,000
dollcws
809,934
100,838
3,646,384
4,434,989
Per
pound
$0.18
235,195
22,888
575,245
657,610
.29
.23
.16
All other thermoplastic resins
,322,000
527,839
78,564
193,835
320,997
3,865,000
404,481
64,918
100,590
314,904
503,048
94,331
20,407
39,824
191,260
.31
.40
Starting with 1972, data is reported only by type of resin and is no longer broken down by end use.
^ Calculated from rounded figures.
' Dry weight basis unless otherwise specified. Dry weight basis is the total weight of the materials including resin
and coloring agents, extenders, fillers, plasticizers , and other additives, but excluding water and other liquids di-
luents unless they are an integral part of the materials.
'' Includes benzenoid plastics and resin materials as defined in part I of schedule 4 of the Tariff Schedules of the
United States.
^ Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (such as styrene or methyl
methacrylate) ; and polyallyl resins (such as diallyl phthalate and diglycol carbonate). Data are on an "as sold" basis,
including monomer if part of the resin system.
^ Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold in
association with the resin as part of a two-component system.
' Partially estimated.
° Data shown for modified and "advanced" epoxy resins are that part of the unmodified epoxy resins which is further
processed; therefore, the totals in parentheses are not included in the grand total.
' Includes polycarbamate resins, toluenesulfonamide resins, acetone- formaldehyde resins, and other thermosetting resins
and their precursors.
'° Does not include production or sales for fiber use.
" Includes data for ethylene copolymers. Sales do not include sales by primary producers to other primary producers;
sales do include resales of purchased material by primary producers.
'^ Data are on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers, coloring agents,
stabilizers or impact modifiers, unless otherwise noted.
" Data for polyvinyl acetate produced and sold in latex form include the weight of any protective colloids which are
used as emulsion stabilizers and form an integral part of the resin system. Production does not include polyvinyl acetate
used as a reactive intermediate for polyvinyl alcohol or other vinyl resins.
'*■ Includes polyvinylidene chloride, polyvinyl butyral , polyvinyl formal, and other vinyl resins.
'^ Includes acetal resins, fluorocarbon resins except PTFE, a-methylstyrene resins, polybutylene type resins, poly-
carbonate resins, polyimide-type resins, polyphenylene oxide type resins, polyterpene resins, other thermoplastics,
and sales of coumarone-indene resins.
Note. --Data reported to the Tariff Commission does not necessarily coincide with that reported to the Society of the
Plastics Industry due to differences in both the reporting instructions (e.g., polyvinyl alcohol) and in the coverage
(e.g. phenolic resins).
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2,— Plastics and resin materials for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Plastics and resin materials for which separate statistics are given in table 1 are marked below with an
asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in con-
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 3. A
X signifies that the manufacturer did not consent to his identification with the designated product]
THERMOSETTING RESINS
Acetone-formaldehyde resins
*Alkyd resins, domestic:
*Phthalic anhydride type
*Polybasic acid type
•Polyester resins, unsaturated
*Styrene-alkyd polyesters
*Amino resins:
*Melamine- formaldehyde resins
*U re a- formaldehyde resins
*Dicyandi amide resins
Epoxy resins:
'Unmodified
•Modified and "advanced"
* Fur fury 1- type resins
•Phenolic and other tar acid resins
Po ly carb amate resins
•Polyurethane and diisocyanate resins
•Polyether and polyester polyols for urethi
*Si 1 i cone resins
All other thermosetting resins
Manufacturers' identification codes
(according to list in table 3)
ACY, AMR.
.\CY, APT, ASH, AZS. BAL, BEN, BRU, GEL, CGL, CM, COM, DAV,
DEG, DSO, DUP, EW, FAR, FCD, FLW, FOC, FSH, GIL, GLD,
GRV, HAN, IGF, IPC, JOB, JSC, JWL, KHC, KMP, KPT, MCC,
MID, MNP, NCI, NPV, OBC, PER, PPG, PRT, PRX, RCI, RED,
REL, RH, SCN, SED, SIP, SKT, SM, SW, x.
ACY, ASH, BEN, COM, DEG, EW, FCD, FOC, GRV, HAN, ICF,
IPC, KMC, KMP, MCC, MID, MOB, NPV, PFP, PPG, RCI,
RED, REL, RH, SCN, SKT, SM, SW, WIG.
ACP, ACR, ACY, APT, ASH, AZS, CGL, CPV, DA, DEG, DSO,
ENJ, EPC, EW, FLW, FMP, FOM, FRE, GEI, GLD, GNT,
GRG, HAN, HKD, ICF, ICI , IPC, KMC, KPT, MFC, MID,
MMM, MRB, MRO, OCF, ORO, PFP, POL, PPG, PPL, RCI,
REL, RH, SCN, SHA, SHC, SIC, SM, SW, TXT, WLN.
APT, ASH, CGL, DSO, EW, FLW, GLD, GRV, HAN, MID, PPG,
REL, SM.
ACP, ACY, AMR, BOR, CBD, GEL, CGL, DAN, DSO, DUP, ENJ,
FOM, GLD, GRV, HAN, JSC, KPT, MON, MRA, PMC, PPG,
PPL, QCP, RCI, REL, RH, SBC, SED, SNW, STC, SW, VAL,
WRD.
ACP, ACY, AMR, APX, ASH, BOR, CBD, CEL, CGL, CMP, CPV,
DAN, DUP, EFH, GAF, GLD, GP, GRV, HAN, HNC, HPC,
HRT, IRI, JSC, KPT, MMM, MON, MRA, NTC, PC, PGU,
PPG, PPL, RCI, REL, RH, RPC, SAC, SED, SM, SNW, SOR,
SW, TXT, UNO, UPL, USO, VAL, WCL.
CGY, ECC, JSC, MID, MRA, RPC, S, SBC, VAL, WIC.
CEL, CGY, DOW, RCI, RSY, SHC, UCC.
ACP, ASH, BEN, DSO, EW, FAR, GLD, GRV, HAN, HYC, ICF,
JOB, MCC, MID, MMM, MRB, MRT, NPV, OCF, POL, PPG,
PRX, RCI, REL, REZ, RSY, SCN, SED, SKT, SM.
ACR, HVG, SM, TXT, UNO, WRD.
ABS, ACP, ACR, AMR, ASH, BME, BOR, CBD, CBM, CD, CGL,
CLK, DSO, ENJ, EW, FOM, GE, GEI, GLD, GP, GRG, HER,
HKD, HVG, ICF, INL,-IRI, KPT, KYN. MCA, MID, MMM, MON,
MRB, NCI, NTC, OCF, PAI , PGU, PLS, PPL, PRX, PYZ,
RAB, RCD, RCI, REL, RGC , RH, RPC, SCN, SHA, SIM,
SKT, SM, SPL, SW, UCC, UNO, UPL, USR, VSV, WCA, WRD.
ASH, DAN, PPG.
APT, ARK, ASH, BAL, CEL, CGL, DSO, DUP, EW, FAR, FRE,
GLD, GPM, HAP, ICI, JOB, JWL, KMC, MCC, MID, MOB,
mi, NPV, PEL, PPG, PVI, QUN, RCI, REZ, RUB, SCN, SKT,
SW, UPJ, WLN.
APT, DSO, ICI, HID, MOB, PFZ, PPG, RCI, UCC, UNO, UPJ, WLN,
WTC.
ASH, CGL, DCC, GLD, MCC, MID, PPG, SFS, SPD, UCC.
ACP, AMR, ASH, CGY, DSO, ENJ, EW, FLW, GLD, HYC, IOC,
MID, MON, PPG, RCD, S, SM, UCC, USR, VAL.
PLASTICS AND RESIN MATERIALS
TABLE 2, --Plastics and resin materials for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
THERMOPLASTIC RESINS
Acetal resins
* Acrylic resins
*Cellulosic plastics and resins
*Couinarone-indene resins
Fluoro carbon resins
'Petroleum hydrocarbon resins
Polyamide resins:
*Nylon type
*Non-nylon t^'pe
Polybutene and polyisobutylene resins
Polycarbonate resins
*Polyester resins, saturated
'Polyethylene and copolymers:
'Density 0.940 and below
'Density over 0.940
'Ethylene copolymers
'Polypropylene resins
Polyterpene resins
'Polytetrafluoroethylene (PTFE)
'Rosin modifications:
'Rosin and rosin esters, unmodified Caster gums)-
'All other
'Styrene type plastics materials:
•Acrylonitrile-butadiene-styrene (ABS) resins — -
'Styrene-acrylonitrile resins (SAN)
'Styrene and styrene copolymer resins other than
ABS and SAN.
a- Methyl styrene polymers
Vinyl resins:
'Polyvinyl chloride and copolymer resins-
'Polyvinyl acetate resins
•Polyvinyl alcohol resins
Polyvinyl butyral resins
Polyvinylidene chloride resins
All other vinyl resins
All other thermoplastic resins
CEL, DUP, POL.
ACY, ASH, BAS, CEL, DSO, DUP, EFH, FLH, GLC, GNM, GRV,
HNC, HRT, IOC, JNS, JSC, MID, NPV, POL, PPG, PVI ,
QUN, REL, RH, RPC, SAR, SCO, SED, SEY, SM, UBS, UCC,
VAL, VPC, WIC, X.
CEL, DOW, DUP, EKT, ICF, POL, x.
DUP, ICF, NEV, PAI, VEL.
DUP, MMM, PAS.
DSO, EKX, GYR, NEV, PAI, PPG, RCI, VEL, ZGL.
ALF, AZS, BCM, CEL, DUP, EW, FG, GNM, MON, POL, RSN,
SKP.
CBY, COO, DUP, EMR, GNM, SCO, SM, SNW.
ENJ, RH.
GE, MOB, POL.
CEL, COO, DSO, DUP, EKT, GE, GLD, GNM, MID, MRT, REL,
RUB, SHA.
ACP, CBN, CPX, DOW, DUP, EKX, ENJ, GOC, KPP, MON, NWP,
PLC, RCC, UCC, USI.
ACC, ACP, CEL, CPX, DOW, DUP, EKX, GOC, KPP, MON, PLC,
UCC, USI, X.
DUP, EKX, ENJ, USI.
ACC, DA, EKX, ENJ, HPC, NVT, PLC, RCC, SHC.
CBY, PAI, SCN.
ACP, DUP, ICI. PAS.
ASH, CBY, DPP, FAR, FCD, FRP , GIL, MCC, NCI, RCI, SED.
ASH, CBY, DPP, EW, FAR, FCD, FLK, FRP, GIL, GLD, NCI,
RCI, RH, SCF, SW, ZGL.
BFG, DOW, GRD, KPP, MCB, MON, RCC, USR.
BFG, DOW, DSO, MON, SBI, SKT, UCC.
ACC, AEP, ATR, BAS, BFG, BOR, CSD, DOW, DPI, DUP, FCD,
FG, FIR, GAF, GNT, GOR, GRD, GYR, HLM, ICF, IOC,
JNS, JSC, KPP, MMM, MON, MRT, ONX, PAI, PLA, POL,
PRX, PVI, RCC, RH, RPC, SBI, SHC, SKT, SOL, SPE,
UBS, UCC, UOC, USR, USS, VEL, WIC.
ACC, DOW, FCD.
ACP, AIP, AME, BFG, BOR, CO, DA, FIR, GNT, GRA, GYR,
HN, ICF, KYS, MON, NSC, OMC, PNT, RUB, SFP, TNA,
UCC, USR.
AIP, ASH, BAL, BEN, BLS, BOR, CEL, DAN, DAV, DSO, DUP,
FAR, FLH, FLW, FSH, GLC, GLD, GRD, HNC, HRT, JSC,
KMC, KMP, MCC, M»1, MNP, MON, NPV, NSC, OBC, OCF,
ONX, PII, PPG, PRX, PVI, QCP, RCI, RPC, SBI, SCO,
SEY, SPC, UBS, UCC, UOC, WIC, x.
AIP, DUP, MON.
DUP, MON, UCC.
BAS, BFG, DOW, DUP, GLD, GRD, MRT, SM, UBS.
DOW, DSO, EW, MCC, MON, SM, UCC.
ACC, CEL, DSO, DUP, EW, GE, PLC, PPG, RH, RPC, SM,
UCC.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 3, --Plastics and resin materials: Directory of manufacturers, 1972
ALPHABETICAL DIKECI'ORV BY LODt
[Names of manufacturers that reported production or sales of plastics and resin materials to the U.S. Tariff Commis-
sion for ly72 are listed below in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
ABS
Abex Corp., American Brakeblok Division
ECC
Eastern Color 5 Chemical Co.
ACC
Amoco Chemical Corp.
tFH
E.F. Houghton i, Co.
ACP
Allied Chemical Corp., Plastics Division
Eastman Kodak Co. :
ACR
CPC International, Inc., Acme Resin Co. Div.
EKT
Tennessee Eastman Co. Division
ACY
American Cyanamid Co.
EKX
Texas Eastman Co. Division
AEP
A 6 t Plastics Pak Co., Inc.
EMR
Emery Industries, Inc.
AIP
Air Products is Chemicals, Inc.
ENJ
Exxon Corp., Exxon Chemical Co. USA
ALF
Allied Chemical Corp., Fibers Div.
hPC
tpoxylite Corp.
AMh
American Chemical Corp.
EW
Westinghouse Electric Corp., Industrial
AMR
Pacific Resins 8 Chemical Co.
Plastics Uiv., Chemical Products Plant
APT
Whittaker Corp., Mol Kez Division
APX
Apex Chemical Co., Inc.
FAR
Famow, Inc.
ARK
Armstrong Cork Co.
FCD
France, Camnbell f, Darling, Inc.
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
FG
Foster Grant Co., Inc.
atr
Atlantic Richfield Co., ARCO Chemical Co. Div.
FIR
Firestone Tire 8 Rubber Co., Firestone
AZS
AZS Corp., M Products Co. Div.
Plastics Co. Div.
FLH
H.B. Fuller Co.
HAL
Baltimore Paint 8 Chemical Corp.
FLW
Fuller-O'Brien Corp.
HAS
BASF Wyandotte Corp.
FMP
FMC Corp., Industrial Chemical Div. Organic
BCM
Belding Chemical Industries
Business Group
BEN
Bennett's
FOC
.Handschy Chemical Co., Farac Oil t, Chemical
BFG
B.F. Goodrich Co., B.F. Goodrich Chemical Co.
Co. Div.
Division
FOM
Formica Corp.
BLS
Beech-Nut, Inc.
FRh
Freeman Chemical Corp.
BMt
Bendix Corp., Friction Materials Division
FRP
FRP Company
BOR
Borden Co., Borden Chemical Co. Division
FSH
Frisch 6 Co. , Inc.
BRU
M.A. Bruder 6 Sons, Inc.
GAF
GAF Corp., Chemical Division
CBD
Chembond Corp.
GE
General Electric Co. :
CBM
Carborundum Co., Coated Abrasives Division
GET
Insulating Materials Dept.
CBN
Cities Service Co., Columbian Div.
GIL
Gilman Paint 5 Varnish Co.
CBY
Crosby Chemicals, Inc.
GLC
General Latex 5 Chemical Corp.
CD
Budd Co., Polychem Division
GLD
SCM Corp., Glidden-Durkee Division
CEL
Celanese Corp. :
GLX
Electro-Seal Glasflex Corp.
Celanese Coatings Co.
GNM
General Mills Chemicals, Inc.
Celanese Plastics Co.
GNT
General Tire 6 Rubber Co., Chemical Division
CGL
Cargill, Inc.
GOC
Gulf Oil Corp., Gulf Oil Co. Chemicals Dept . -
CGY
Ciba-Geigy Corp.
United States
CLK
Clark Chemical Corp.
GOR
Gordon Chemical Co., Inc.
CM
Carpenter-Morton Co.
GP
Georgia-Pacific Corp.
CMP
Commercial Products Co., Inc.
GPM
General Plastics Manufacturing Co.
CO
Continental Oil Co.
GRA
Great American Chemical Corp.
COM
Commercial Solvents Corp.
GRD
W.R. Grace 5 Co., Polymers Chemicals Division
COO
Coopers Polymers, Inc.
GRG
P.D. George Co.
CPV
Cook Paint 5 Varnish Co.
GRV
Guardsman Chemical Coatings, Inc.
CPX
Chemplex Co.
GYR
Goodyear Tire 6 Rubber Co.
CSD
Cosden Oil 5 Chemical Co.
HAN
Hanna Chemical Coating Corp.
DA
Diamond Shamrock Corp.
HAP
Applied Plastics Co., Inc.
DAN
Dan River, Inc.
HER
Heresite S Chemical Co.
DAV
Conchemco, Inc., H.B. Davis Co. Division
HKD
Hooker Chemical Corp., Durez Division
DCC
Dow Coming Corp.
HLM
U.S. Industries, Inc., E. Helman Co. Division
DEC
Degan Oil 5 Chemical Co.
HN
Tenneco Chemicals, Inc.
DOW
Dow Chemical Co.
HNC
H 5 N Chemical Co.
DPI
Diamond Plastics, Inc.
HPC
Hercules, Inc.
DPP
Dixie Pine Products Co., Inc.
HRT
Hart Products Corp.
DSO
DeSoto, Inc.
HVG
Haveg Industries
DUP
E.I. duPont de Nemours b Co., Inc.
HYC
Dexter Corp., Hysol Co. Division
PLASTICS AMD RESIN MATERIALS
TABLE 3,— Plastics and resim materials; Directory of manufacturers, 1972~Continued
Code
Name of company
Code
Name of company
ICF
Inmont Corp. , ABI Div.
pnt
Pantasote Co.
ICI
ICI America, Inc. f, Specialty Chemicals
POL
Polymer Corp.
Div.
PPG
PPG Industries, Inc.
INL
Inland Steel Co., Inland Steel Container Co.
PPL
Pioneer Plastics Corp.
Division
prt
Pratt 5 Lambert, Inc.
IOC
lonac Chemical Co. Div. of Sybron Corp.
PRX
Purex Corp., Ltd., Washbum-Lanson Co. Div.
IPC
Interplastic Corp.
PVI
Polyvinyl Chemical Ind., Div. of Ceatrice
IRI
Ironsides Resins, Inc.
Foods Co.
PYZ
Polyrez Co. , Inc.
JNS
S.C. Johnson 5 Son, Inc.
JOB
Jones-Blair Paint Co.
QCP
Quaker Chemical Corp.
JSC
Jersey State Chemical Co.
QUN
K.J. Qidnn 5 Co., Inc.
JWL
Jewel Paint 6 Varnish Co.
RAB
Raybestos-Manhattan, Inc., Raybestos Div.
KMC
Kohler-McLister Paint Co.
RCC
Dart Industries, Inc., Rexene Polymers Co. Div
KMP
Kelly-Moore Paint Co.
RCD
Richardson Co.
KPP
Sinclair- Koppers Co.
RCI
Reichhold Chemicals, Inc.
KPT
Koppers Co. , Organic Materials Division
RED
Red Spot Paint and Varnish Co., Inc.
KYN
Kyanize Paints, Inc.
REL
Reliance Universal, Inc. 5 Resin Div.
KYS
Keysor Chemical Corp.
REZ
Hexcel Corp., Rezolin Division
RGC
Rogers Corp.
MCA
Masonite Corp., Alpine Division
RH
Rohm ^ Haas Co .
MCB
Borg-Wamer Corp., Marbon Chemical Division
RPC
Millmaster Onyx Corp., Refined-Onyx Division
MCC
McCloskey Varnish Co.
RSN
Relsan Corp.
MFC
North American Rockwell Corp.
RSY
Resyn Corp.
MID
Dexter Corp. , Midland Division
KUB
Hooker Chemical Corp., Ruco Division
MMM
Minnesota Mining S Manufacturing Co.
MNP
Minnesota Paints, Inc.
S
Sandoz, Inc., Sandoz Color 5 Chemical Div.
MOB
Mobay Chemical Co.
SAC
Southeastern Adhesives Co.
MON
Monsanto Co.
SAR
Sartomer Industries, Inc.
MR
Benjamin Moore 6 Co.
SBC
Scher Bros . , Inc.
MRA
Crown Metro, Inc.
SB!
Standard Brands Chemical Industries, Inc.
MRS
Marblette Co.
SCF
Guardsman Chemical Coatings, Inc.,
MRO
W.R. Grace 5 Co., Marco Chemical Division
Louisville Division
mrt
Morton Chemical Co. Div. of Morton-Norwich
SCN
Schenectady Chemicals, Inc.
Products, Inc.
SCO
Scholler Bros. , Inc.
SED
' Conchemco, Inc., Kansas City Division
NCI
Union Camp Corp., Chemical Division
SEY
Seydel-Woolley 5 Co., Inc.
NEV
Neville Chemical Co.
SFP
Stauffer Chemical Co., Plastics Div.
NPV
Norris Paint 5 Varnish Co., Inc.
SHA
Shanco Plastics 5 Chemicals, Inc.
NSC
National Starch 5 Chemical Corp.
SHC
Shell Oil Co., Shell Chemical Co. Div.
ntc
National Casein Co.
SIC
Vistron Corp., Silmar Division
NVT
Novamont Corp., Neal Works
SIM
Simpson Timber Co.
SIP
Sipes Chemical Coatings Co.
OBC
O'Brien Corp.
SKP
Shakespeare Co., Industrial Products Division
OCF
Owens-Corning Fiberglas Corp.
SKT
Textron Inc., Spencer Kellogg Division
omc
01 in Corp.
SM
Mobil Oil Corp., Mobil Chemical Co.,
ONX
Millmaster Onyx Corp., Onyx Chemical Corp.
Chemical Coatings Div.
ORO
Chevron Chemical Co.
SNW
Sun Chemical Corp., Chemicals Division
SOL
Solar Chemical Corp.
PA I
Pennsylvania Industrial Chemical Corp.
SOR
Thomason Industries, Inc., Southern Resin Div.
PC
Proctor Chemical Co., Inc.
SPC
Sinclair Paint Co., Div. of Insilco Corp.
PEL
Pelron Corp.
SPD
General Electric Co., Silicone Products Dept.
PER
Perry 6 Derrick Co.
SPE
Petrochemical Investment Corp.
PFP
Midwest Manufacturing Corp.
SPL
Spaulding Fibre Co., Inc.
PFZ
Pfizer, Inc.
stc
Sou-Tex Chemical Co., Inc.
PGU
Gulf Oil Corp., Gulf Adhesives
SW
Sherwin-Williams Co.
PII
Polymer Industries, Inc.
PLA
Richardson Co.
tna
Ethyl Corp.
PLC
Phillips Petroleum Co.
TX
Texaco, Inc.
PLS
Plastics Engineering Co.
TXT
Text il ana Corp.
PMC
Plastics Manufacturing Co.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3, --Plastics and resin materials: Directory of manufacturers, 1972--Continued
Code
Name of company
Code
Name of company
UBS
A.E. Staley Manufacturing Co., Staley
VAL
Valchem
Chemicals Division
VEL
Veliscol Chemical Corp.
ucr
Union Carbide Corp.
VPC
Baychem Corp., Verona Div.
UNO
United-Erie, Inc.
vsv
Valentine Sugars, Inc.
uoc
Union Oil Co. of California
UPJ
Upjohn Co.
WCA
West Coast Adhesives Co.
UPL
U.S. Plywood, WCM Operations, Shasta Area
WCL
Wright Chemical Co.
USI
National Distillers 5 Chemical Corp., U.S.
WIC
Wica Chemical Inc.
Industrial Chemicals Co. Div.
WLN
Wilmington Chemical Corp.
US I
National Petro Chemical Corp.
WRD
Weyerhaeuser Co., Wood Products D
vision
uso
U.S. Oil Co.
IVTC
Witco Chemical Co., Inc.
USR
Uniroyal, Inc., Chemical Division
USS
USS Chemicals, Div. of U.S. Steel Corp.
ZGL
Carolina Processing Corp.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendi
141
RUBBER- PROCESSING CHEMICALS
Rubber-processing chemicals are organic compounds that are added
to natural and synthetic rubbers to give them qualities necessary for
their conversion into finished rubber goods. In this report, statis-
tics are given for cyclic and acyclic compounds, by use — such as
accelerators, antioxidants, blowing agents, and peptizers. Data on
production and sales of rubber-processing chemicals in 1972 are given
in table 1.
Production of rubber-processing chemicals as a group in 1972 amounted
to 361 million pounds, or 11.6 percent more than the 323 million pounds
reported for 1971. Sales of rubber-processing chemicals in 1972 amounted
to 280 million pounds, valued at $178 million, compared with 246 million
pounds, valued at $159 million, in 1971. The increased production and
sales of rubber-processing chemicals in 1972 is attributable principally
to the increased production and sales of cyclic antioxidants, antiozonants ,
and stabilizers.
The output of cyclic rubber-processing chemicals in 1972 amounted to
310 million pounds, or about 12.2 percent more than was reported for 1971.
Sales in 1972 were 240 million pounds, valued at $158 million, compared
with 211 million pounds, valued at $143 million, in 1971. Of the total
output of cyclic rubber-processing chemicals in 1972, accelerators ac-
counted for 32.1 percent and antioxidants for 63.1 percent. Production
of antioxidants, which amounted to 195.6 million pounds in 1972, included
129.5 million pounds of amino compounds and 66.1 million pounds of
phenolic and phosphite compounds. Sales of amino antioxidants in 1972 were
100.6 million pounds, valued at $68.7 million; sales of phenolic and
phosphite antioxidants were 47.9 million pounds, valued at $27.2 million.
Production of acyclic rubber-processing chemicals in 1972 amounted
to 51.1 million pounds, an increase if 8.0 percent from the 47.3 million
pounds reported for 1971. Sales in 1972 totaled 40.2 million pounds,
valued at $19.7 million, compared with 34.9 million pounds, valued at
$16.8 million* in 1971. Accelerators accounted for 56.3 percent of the
output of acyclic rubber-processing chemicals for 1972 and dodecyl mer-
captans accounted for 29.8 percent.
^ See also table 2 which lists these products and identifies the manu-
facturers by codes. These codes are given in table 3.
552-743 O - 74 - 10
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 1.— Rubber-processing chemicals; U.S. production and sales, 1972
[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were
reported.) Table 2 lists separately all rubber-processing chemicals for which data on production or sales were re-
ported and identifies the manufacturers of each]
Production
Quantity
Unit
value'
Grand total
RUBBER- PROCESSING CHEMICALS, CYCLIC
Total
Accelerators, activators, and vulcanizing agents, total
Aldehyde-amine reaction products
Dithiocarbamic acid derivatives
Thiazole derivatives, total
N-Cyclohexyl-2-benzothiazolesulfenamide
2, 2 '-Dithi obis (ben zo thiazole)
2-Mercaptobenzothiazole
2-Mercaptobenzothiazole, zinc salt
All other thiazole derivatives
All other accelerators, activators, and vulcanizing agents
Antioxidants, antiozonants, and stabilizers, total
Amino compounds, total
Substituted p-phenylenediamines , total
N,N'-Bis (1 ,4-dimethylpentyl)-p-phenylenediamine
N,N' -Diphenyl-p-phenylenediamine
All other substituted p-phenylenediamines
Oc t y Id i phenyl amine
N-Phenyl-2-naphthyl amine
All other amino compounds^
Phenolic and phosphite compounds, total
Polyphenolics (including bisphenols)
Phenol, alkylated
Phenol, styrenated
All other phenolic and phosphite compounds
Retarder: N-Nitrosodiphenylamine
All other cyclic rubber-processing chemicals'*
RUBBER- processing CHEMICALS, ACYCLIC
Total - - - -
Accelerators, activators, and vulcanizing agents, total
Dithiocarbamic acid derivatives, total
Dibutyldithiocarbamic acid, zinc salt
Diethyldithiocarbamic acid, zinc salt
Dimethyldithiocarbamic acid, zinc salt
All other dithiocarbamic acid derivatives
1,000
pounds
av).484
2,256
419
86,338
8,819
21,272
6,030
4,006
46,211
10,471
195,642
129,515
70,537
6,049
1,790
62,698
3,614
4,511
50,853
66,127
15,314
1,581
2,018
12,786
10,042
3,989
1,887
1,000
pounds
1,000
dollars
157,944
78.i4o
1,302
236
67,001
5,241
11,675
4,682
4,132
41,271
10,307
148,444
00
584
48
502
1
761
46
741
3
300
48
782
47
860
14
481
3
031
1
601
28
747
1
108
11
646
20.599
3,644
2,007
2,067
50.874
1,266
597
40,150
4,852
6,221
1,784
2,192
25,101
8,861
68,663
42,646
40,851
1,751
24,266
27,159
16,100
1,569
444
9,046
702
10,546
3,185
1,132
Per
pound
$0.63
.57
1.11
See footnotes at end of table
RUBBER-PROCESSING CHEI1ICALS
TABLE 1, --Rubber-processing chemicals: U.S. production and Sales, 1972--Continued
Quantity
Unit
value'
RUBBER-PROCESSING CHEMICALS, ACYCLIC--Continued
Accelerators, activators, and vulcanizing agents--Continued
ThiuraTiis, total'
Bis(dimethylthiocarbamoyl) disulfide
Bis (dimethyl thiocarbamoyl) sulfide
All other thiurams
All other accelerators, activators, and vulcanizing agents'
Polymerization regulators: Dodecyl raercaptans
Shortstops; Dimethyldithiocarbamic acid, sodium salt-
All other acyclic rubber-processing chemicals®
13,079
2,618
15,243
4,575
2,494
1,000
pounds
11,596
8,476
2,006
1,114
1,285
14,750
2,070
2,780
1,000
dollars
5,226
3,050
1,554
642
2,063
5,322
533
1,287
Per
pound
' Calculated from rounded figures.
^ Includes guani dines.
^ Includes aldehyde- and acetone-amine reaction products .
'* Includes blowing agents, peptizers, and other uses not separately shown.
^ Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are included in the report
"Pesticides and Related Products."
' Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural
and synthetic rubbers.
' Includes xanthates, disulfides, other dithiocarbamic acid derivatives (sales only) and other thiurams (production
only) .
' Includes blowing agents, conditioning and lubricating agents, polymerization regulators, shortstops and physical
property improvers.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2, --Rubber-processing chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Rubber-processing chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*) ;
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
RUBBER-PROCESSING CHEMICALS, CYCLIC
♦Accelerators, activators, and vulcanizing agents:
*Aldehyde-anine reaction products:
Acetaldehyde-ani line condensate
n- But yraldehyde- aniline condensate
Butyr aldehyde -but ylideneani line condensate
a-Ethyl-6-propylacrylanilide
Hept aldehyde- aniline condensate
Triethy Itrime thy lenetri amine
*Dithiocarbamic acid derivatives:
Dibenzyldithiocarbamic acid, sodium salt
Dibenzyldithiocarbamic acid, zinc salt
Dibutyldithiocarbamic acid, N,N-dimethylcyclohexyl-
amine salt.
Dibutyldithiocarbamic acid, diphenylguanidine salt
2 ,4-ninitrophenyl dimethyldithiocarbamate
Piperidinecarbodithioic acid, piperidinium-notassium
salts, mixed.
Guanidines :
Dicatechol borate, di-o-tolylguanidine salt
1,3-Diphenylguanidine
1,3-Di-o-tolylguanidine
Dodecyltetramethylguanidine
1 ,2 ,3-Triphenylguanidine
*Thiazole derivatives:
2-Benzothiazyl N,.N-diethylthiocarbamoyl sulfide
1 , 5-Bis (2-benzothiazolylmercaptomethyl) urea
N-tert- Butyl- 2-benzothiazolesulfenamide
*N-Cyclohexyl-2-benzothiazolesulfenamide
N,N-Diisopropyl-2-benzothiazolesulfenaniide
N- (2 ,6-nimethylmorpholino) -2-benzothiazolesulfen-
amide.
*2,2'-Dithiobis(benzothiazole1
*2-Mercaptobenzothiazole
2-Mercaptobenzothiazole, copper salt
2-Mercaptobenzothiazole, zinc chloride
*2-Mercaptobenzothiazole, zinc salt
4-Morpholinyl-2-benzothiazyl disulfide
N-Oxydiethylene-2-benzothiazolesulfenaiiiide
Thiazoline-2-thiol
All other cyclic accelerators, activators, and vulcan-
izing agents:
p-Benzoquinonedioxime
Bis (p-aminocyclohexy 15 methane carbamate
Bis (morpholinothiocarbonyl) disulfide
Dibenzoy 1 -p- quinonedi oxime
Dibenzyl amine
N,N' -Dicinnamylidene-1 ,6-hexanediainine
Di-^J,N' -pent ame thy lenethiuram tetrasulfide
4,4 ' -Dithiodimorpholine
2- Imidazoline- 2- thiol
m-Phenylenebismaleimide
Poly-p-dinitrosobenzene
Toluene-2,4-diisocyanate adduct of dimethylethanol-
amine.
*Antioxidants , antiozonants, and stabilizers:
*Amino compounds:
Aldehyde- and acetone-amine reaction products:
Acetaldehyde-aniline hydrochloride condensate
Aldol-a-naphthylamine condensate
Butyr aldehyde- aniline condensate
USR.
DUP, MON, RCD, USR.
MON.
RCI.
USR.
USR.
USR.
USR.
MON.
RCI-
USR.
DUP.
DUP.
ACY.
ACY.
DUP.
ACS.
PAS.
MON.
ACY, MON.
ACY. BFG, MON, USR.
ACY.
MON.
ACY, BFG, GYR, MON, USR.
ACY, BFG, GYR, MON, USR.
ACY.
DUP.
ACY, BFG, GYR, USR.
GYR.
ACY, BFG, MON.
ACY.
CTN.
DUP.'
ACY.
CTN, USR.
MLS, USR.
DUP.
DUP, WC.
•KDN, VNC.
DUP, RBC.
DUP.
DUP.
DUP.
USR.
BFG.
DUP.
I
RUBBER-PROCESSING CHEMICALS
TABLE 2.-
-RUBBER-PROCESSING CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
RUBBER-PROCESSING CHEMICALS, CYCLIC — CONTINUED
^.Antioxidants , antiozonants , and stabilizers--Continued
*Aiiiino compounds --Continued
Aldehyde- and acetone-amine reaction products--
Continued
Di phenyl amine -ace tone condensate
Phenyl-2-naphthylamine-acetone condensate
*Substituted p-phenylenediamines :
N,N'-Bis(l ,3-dimethylbutyl)-p-phenylenediamine
*N,N'-Bis(l ,4-dimethylpentyl)-p-phenylenediamine
N,N' -Bis{l-ethyl-3-methylpentyl)-p-phenylenediamine
N,N'-Bis(l-methyIheptyl) -p-phenylenedi amine
N-sec-Butyl-N' -phenyl-p- phenyl enedi amine
N-Cyclohexyl-N'-phenyl-p-phenylenediamine
Diarylaryl enedi amines , mixed
N,N' -Dicyclohexyl-p-phenylenediamine
N- (1 ,5-Dimethylbutyl} -N' -ph enyl-p- phenyl enedi amine -■
N,N' -1 ,4~Dimethylhexyl-p-phenylenediamine
N,N ' -Di-2-naphthyl-p-phenylenediamine
*N,N' -Diphenyl-p-phenylenediamine
N- I sopropyl-N' -phenyl -p-phenylenediamine
N- (1-Methylheptyl) -N' -phenyl-p -phenyl enedi amine
N- (1-MetIiylpentyl) -N' -phenyl -p-phenylenedi amine
Nit roso-N-phenyl -p-phenylenediamine
All other substituted p-phenylenediamine
Other amino compounds:
p-Anilinophenol
4'-Bis(a,a-dimethylbenzyl)diphenylamine
1 ,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline
1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline
1 ,2-Dihydro~2,2,4-trimethylquinoline
4,4'-Dimethoxydiphenylamine
Dinonyldiplienyl amine
N,N'-Diphenylethylenediamine
N,N' -Diphenyl -1 , 5-propanediamine
N,N' -Di-o-tolylethylenediamine
p-Hydroxydi phenyl amine
4,4'-Methylenedianiline
Nonyldiphenylamine mixture (mono-, di-, and tri-) —
*Octyldiphenyl amine
Oc t y Id i phenyl amine, alkylated
N-Phenyl-1-naphthylamine
*N-Phenyl-2-naphthylamine
p- (p-Toluenesulfonamide)diphenylamine
All other
'Phenolic and phosphite compounds:
Phenolic compounds:
*Polyphenolics (including bisphenols) :
Bisphenol, hindered
4,4' -Butyl ideneb is (6-tert-butyl-m-cresol)
2,5-Di-sec-butyldecylhydroquinone
2,5-Di-(l, l-dimethylpropyl)hydroquinone
2,2' -Methylenebis (6-tert-butyl-p-cresol)
2,2'-Methylenebis(6-tert-butyl-4-ethylphenol)
2, 2 '-Methylenebis [6- (l-methylcyclohexyl) -p-
cres 0 1 ] .
2,2'-Methylenebis(6-tert-octyl-p-cresol)
2,2'-Thiobis(4,6-di-5ec-amylphenol)
4, 4 '-Thiobi 5 (6-tert-butyl-m-cresol)
Thiobisphenol , alkylated
1, 1,3 -Tri (2 -methyl-4-hydroxy-5-tert -butyl phenyl )-
butane.
ACY
BFG,
USR.
USR
x.
EKT
USR,
X.
MON
X.
BFG
MON,
X.
USR
USR
X.
GYR.
X.
GYR,
USR.
X.
BFG,
DUP.
BFG,
DUP,
SDC, USR
USR.
X.
USR.
USR.
MON.
BFG.
WSN.
MON.
MON.
BFG,
MON.
DUP.
ACY.
DA,
RCI.
RCI.
RCI.
USR.
USR.
USR.
.ACY,
NPI,
USR.
BFG.
DUP,
UCC.
BFG,
DUP,
USR.
USR.
USR.
GYR, USR.
MON.
USR.
MON.
ACY, A.SH.
ACY.
ICI.
ACY.
MON.
MON.
USR.
ICI.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.--F
3ER-PR0CESSING CHEMICALS FOR WHICH U.S, PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
RUBBER-PROCESSING CHEMICALS, CYCLIC--CONTINUED
•Antioxidants, antiozonants, and stabilizers--Continued
'Phenolic and phosphite coiiipounds--Continued
Phenolic compounds--Continued
Other phenolic compounds:
p-Benzyloxyphenol
o-Cresol, alkylated
N-Lauroyl-p-aminophenol
•Phenol, alkylated
Phenol, hindered
*Phenol , styrenated
N-Stearoyl-p- aminopheno 1
♦Phosphite compounds:
Alkylaryl phosphites
Nonyl phenyl phosphites, mixed
Polymeric phosphite
Polyphenolic phosphite, alkylated
Tr iary 1 phosphates
Blowing agents:
N,N' -Dimethyl-N,N'-dinitrosoterephthalamide
Dinitrosopentamethylenetetramine
p,p'-OxybisCbenzenesulfonhydrazide)
p-Toluenesulfonylhydrazide
p-Toluenesulfonylsemicarbazide
Peptizers:
2-Benzamidothiophene, zinc salt
Dicresyl disulfide
2' ,2' ' '-Dithiobis(benzanilide)
Dixylyl disulfides, mixed
2-Naphthalenethiol
Pentachlorobenzenethiol
Xylenethiol
*Retarders: N-Nitrosodiphenylamine
Other cyclic rubber-processing chemicals:
p-tert-Amylphenol sulfide (tackifier)
4-Chloro-2,6-bisC2,4-dihydroxybenzyl)phenol
Phenol cyanurate complex
All other
RUBBER-PROCESSING CHEMICALS, ACYCLIC
•Accelerators, activators, and vulcanizing agents:
•Dithiocarbamic acid derivatives:
Dibutyldithiocarbamic acid, nickel salt
Dibutyldithiocarbamic acid, potassium salt
Dibutyldithiocarbamic acid, sodium salt
•Dibutyldithiocarbamic acid, zinc salt
Diethyldithiocarbamic acid, selenium salt
Diethyldithiocarbamic acid, sodium salt
Diethyldithiocarbamic acid, tellurium salt
•Diethyldithiocarbamic acid, zinc salt
Dimethyldithiocarbamic acid, bismuth salt
Dimethyldithiocarbamic acid, copper salt
Dimethyldithiocarbamic acid, lead salt
Dimethyldithiocarbamic acid, selenium salt
Dimethyldithiocarbamic acid, sodium salt and sodium
polysulfide.
•Dimethyldithiocarbamic acid, zinc salt
All other
•Thiurams :
Bis(dibutylthiocarbamoyl) sulfide
Bisfdiethylthiocarbamoyl) disulfide
•Bis (dimethyl thiocarbamoyl) disulfide
BFG.
PIT.
MLS.
ACY, BFG, GYR, NEV, PIT, RCI.
DUP, GYR.
BFG, GYR, NEV, USR.
MLS.
WES.
NPI, USR.
NPl.
BFG.
WES.
DUP.
NPI.
USR.
USR.
USR.
ACY.
USR.
ACY.
PIT.
DUP.
SDC.
DUP.
ACY, BFG, CTN, GYR, NPI, USR.
PAS.
ICI.
ICI.
MON, RCI.
DUP, USR, VNC.
DUP, PAS, RBC, USR, VNC.
PAS.
GYR, PAS, USR, VNC.
USR.
VNC.
ALC,
ALC,
VNC.
ALC,
VNC.
ALC,
VNC.
VNC.
VNC.
VNC.
BFG.
ALC, DUP, FMN, GYR, PAS, RBC, USR, VNC, WRC.
VNC.
USR.
DUP, GYR, PAS.
DUP, GYR, PAS, VNC.
RUBBER-PROCESSING CHEMICALS
TABLE 2,
-Rubber-processing chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
RUBBER-PROCESSING CHEMICALS, ACYCLIC--CnNTINUED
'Accelerators, activators, and vulcanizing agents--
Continued
*Thiurams - -Cont inued
*Bis(dimethylthiocarbamoyl) sulfide
Bis(ethylmethylthiocarbamoyl) sulfide
Xanthates and sulfides:
Bis(diisopropoxythiophosphoryl) disulfide
Di-n-butylxantho disulfide
Diisopropylxantho disulfide
Zinc diisopropyl xanthate
All other acyclic accelerators, activators, and
vulcanizing agents:
n-Butyraldhyde-butylamine condensate
D i - n -but y 1 ammon ium oleate
3-Ethyl-l ,1 -dimethyl -2 -thiourea
Ethyl enediamine carbamate
Tetramethyl thiourea
1 ,l,3-Trimethyl-2-thiourea
Blowing agents: Modified urea
Conditioning and lubricating agents:
Methyl stearyl-10-sulfonic acid, sodium salt
Mono- and dialkyl acid phosphates, mixed
Mono- and dialkyl phosphate ammonium salts, mixed —
Other
Polymerization regulators:
Alkyl mercaptans, mixed
*Dodecyl mercaptan
n-Octyl mercaptan
tert-Octyl mercaptan
Tridecyl mercaptan
Shortstops:
Dimethyldithiocarbamic acid, potassium salt
*Dimethyldithiocarbamic acid, sodium salt
Other acyclic rubber-processing chemicals:
Zinc laurate (activator, physical -property improver)
DUP, GYR, USR.
PAS.
DUP.
USR.
BFG.
VNC.
DUP.
DUP.
VNC.
DUP.
DUP.
RBC, VNC.
DUP.
DUP.
DUP.
DUP.
DUP.
HK, PAS, PLC.
PAS.
PAS.
PAS.
GYR, USR.
ALC, DUP, GYR, PAS, USR, WRC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3, —Rubber-processing chemicals; Directory of manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names o£ rubber-processing chemical manufacturers that reported production or sales to the U.S. Tariff Commission
for 1972 are listed below in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
ACS
Allied Chemical Corp., Specialty Chemicals
MLS
Miles Laboratories, Inc., Marshall Div.
Div.
MON
Monsanto Co.
ACY
American Cyanamid Co.
ALC
Alco Chemical Corp.
ASH
Ashland Oil, Inc., Ashland Chemical Co.
' Div.
NEV
Neville Chemical Co.
NPI
Stepan Chemical Co., National Polychesiicals Di
V-
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
PAS
PIT
PLC
Pennwalt Chemicals Corp.
Pitt-Consol Chemical Co.
Phillips Petroleum Co.
CTN
Chemetron Corp., Organic Chemical Div.
RBC
RCD
Fike Chemicals, Inc.
Richardson Co.
DA
Diamond Shamrock Corp.
RCI
Reichhold Chemicals, Inc.
DUP
E. I. duPont de Nemours 5 Co., Inc.
SDC
Martin-Marietta Corp., Sodyeco Div.
EKT
Eastman Kodak Co., Tennessee Eastman
Co. Div.
UCC
Union Carbide Corp.
FMN
FMC Corp., Niagara Chemical Div.
UPM
USR
Universal Oil Products Co.
Uniroyal, Inc., Chemical Div.
GYR
Goodyear Tire 5 Rubber Co.
VNC
Vanderbilt Chemical Corp.
HK
Hooker Chemical Corp.
WES
Borg-Warner Corp., Weston Chemical Div.
ICl
ICI America, Inc.
WRC
Ventron Corp . , Wood Ridge Chemical
WSN
Mallinckrodt Chemical Works, Washine Div.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix.
149
ELASTOMERS
Elastomers (synthetic rubbers) are high polymeric materials with
properties similar to those of natural rubber. The term "elastomers" as
used in this report, means a substance, whether in bale, crumb, powder,
latex, and other crude form, which can be vulcanized or similarly proc-
essed into a material that can be stretched to at least twice its original
length and, after having been so stretched and the stress removed, will
return with force to approximately its original length. U.S. production
and sales of elastomers in 1972 are shown in table 1.^
Total U.S. production of synthetic elastomers in 1972 was 4,914 mil-
lion pounds, an increase of 6 percent from that produced in 1971. The
sales of these elastomers amounted to 4,136 million pounds (valued at
$1,095 million) in 1972, an increase of 3 percent over 1971.
Styrene-butadiene rubber (SBR or S-type rubber) in 1972 continued to
be the synthetic elastomer produced in the greatest quantity as it has been
for more than 25 years. U.S. production of SBR, including 38 million
pounds of its vinylpyridine sub-type, amounted to 2,648 million pounds in
1972. Solution polymerized butadiene rubber, a stereo type elastomer, was
produced domestically in 1972 in the next largest amount--666 million
pounds; production of isoprene and ethylene-propylene rubbers, the other
stereo types, amounted to 295 million and 200 million pounds, respectively.
Total U.S. production of these stereo type elastomers amounted to 1,161
million pounds in 1972--an increase of 8 percent over 1971. Other principal
types of synthetic elastomers for which U.S. production and sales data are
reported separately are isobutylene-isoprene (butyl) rubber, production of
which was 290 million pounds in 1972, and acrylonitrile-butadiene (N-type)
rubber, production of which was 160 million pounds.
U.S. production and sales data on synthetic organic chemicals are
reported in terms of cyclic and acyclic structured compounds for purposes
of better correlation with other statistical reporting systems. In 1972,
U.S. production of cyclic elastomers amounted to 2,706 million pounds, an
increase of nearly 4 percent over 1971; sales of cyclic elastomers amounted
to 2,177 million pounds (valued at $471 million^), a decrease in volume
of 3 percent compared with 1971. U.S. production of acyclic elastomers in
1972 amounted to 2,208 million pounds, an increase of 10 percent over 1971;
sales of acyclic elastomers amounted to 1,959 million pounds (valued at
$624 million), an increase in volume of 9 percent from the previous year.
See also table 2 which lists these products and identifies the manu-
facturers of each by code. These codes are given in table 3.
^The value of sales in 1971 and 1972 for styrene-butadiene (S-type) rubber,
which comprise about 90 percent of the sales value of cyclic elastomers, was
calculated on a somewhat different basis than in previous years. The
value of sales in 1971 for S-type elastomers is believed to have increased
slightly over that in 1970, although the published figures showed a decrease.
SYNTHETIC ORGAillC CHEMICALS, 1972
TABLE 1.— Elastomers (synthetic rubbers):' U.S. production and sales- 1972
[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be published.
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were
reported.) Table 2 lists all elastomers for which data on production or sales were reported and identifies the
manufacturers of each]
Production
Sales
Quantity
Unit
value^
Grand total
ELASTOMERS, CYCLIC
Total
Styrene-butadiene type (S-type)^
Styrene-butadiene-vinylpyridine type
Urethane type
ELASTOMERS, ACYCLIC
Total
Acrylonitrile-butadiene type (N-type)
Isobutylene-isoprene type (Butyl)
Silicone type
Stereo elastomers, total
Butadiene (solution polymerized) type--
Ethy lene-propy 1 ene type
I soprene type
All other acyclic elastomers^
1,000
pounds
4,915,959
1,000
pounds
4,156,263
1,000
do I laps
Per
pound
2,610,142
38,161
57,296
2,208,560
,118,686
21,720
56,897
1,958,960
'415,783
11,829
42,957
624,257
159,745
289,746
26,752
1,160,849
155,489
27,214
887,229
59,884
64,899
176,402
666,427
199,558
294,864
466,315
183,165
237,749
86,565
47,795
42,242
The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be
vulcanized or similarly processed into materials that can be stretched at 68°F. to at least twice their original
length and, after having been so stretched and the stress removed, will return with force to approximately their
original length.
^ Calculated from rounded figures.
' Elastomer-content basis.
'* Partly estimated.
^ Partly estimated. Includes the value of added oil.
^ Includes production and sales data for acrylic ester, polysulfide, chloroprene, epichlorohydrin, and isobutylene
elastomers, butadiene emulsion polymers, chlorosulfonated polyethylene, halogenated elastomers, thermoplastic rubber,
miscellaneous elastomers and sales data for the isobutylene-isoprene type elastomer. Also includes miscellaneous
cyclic elastomers, among which are carboxylated SBR latex, certain solution poljTners, and thermoplastic rubber.
Note. — Statistics on the production of S-type, butyl, neoprene, and stereo elastomers were compiled in cooperation
with the U.S. Bureau of the Census.
TABLE 2.-
ELASTOMERS
-Elastomers (synthetic rubbers) for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER/ 1972
[Elastomers (synthetic rubbers) for which separate statistics are given in table 1 are marked below with an asterisk
[*) ; products not so marked do not appear in table 1 because the reported data are accepted in confidence and
may not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that
the manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3]
ELASTOMERS, CYCLIC
*Styrene-butadiene type (S-t>'pe)
*Styrene-butadiene-vinylpyridine type
*Urethane t>'pe
Other cyclic elastomers
elastomers, ACYCLIC
Acrylic ester type
*Acrylonitrile-butadiene type (N-type) —
Butadiene (emulsion polymerized) type —
Chloroprene type (Neoprene)
*Isobutylene-isoprene type (Butyl)
Polysulf ide type
Reaction products of natural rubber
*Silicone type
*Stereo elastomers:
*Butadiene (solution polymerized) type-
*Ethylene-propylene type
*Isoprene type
All other acyclic elastomers
ASH, ASY, BFG, CPY, FIR, FRS, GNT, GYR, MCB, PLC, RUB, SBI,
SHC, TUS, USR, WIC.
BFG, FIR, FRS, GNT, GYR, USR.
ACY, BFG, CNl, DA, DNS, DUP, EPl, GNT, INP, MOB, PFP, PLN,
PRC, RUB, TKL, USR, WTC, x, x.
ASY, DUP, PLC, PRC, SHC, UCC.
ACY, BFG, DA, TKL.
BFG, CPY, FRS, GYR, SBI, USR.
BFG, FRS, GYR, TKL, TUS.
DUP, PTT.
CBN, ENJ.
PRC, TKL.
GYR, ICl, WAY, X.
DCC, PRC, SPD, SWS, UCC.
ASY, ATR, BFG, FRS, GNT, GYR, PLC, SHC, TUS.
BFG, CPY, DUP, ENJ, USR.
BFG, GYR, SHC.
.ASY, BFG, DUP, ENJ, HDM, Mt»1, PLC, SHC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3.
-Elastomers (synthetic rubbers): Directory of Manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of elastomers manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are
listed below in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
ACY
American Cyanamid Co.
ICI
ICI America, Inc.
ASH
Ashland Chemical Co.
INP
INDPOL
ASY
American Synthetic Rubber Corp.
atr
Atlantic Richfield Co., ARCO Chemical Co.
MCB
Borg-Warner Corp., Marbon Chemical Div.
Div.
MW1
Minnesota Mining S Manufacturing Co.
MOB
Mobay Chemical Co.
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
PFP
Midwest Manufacturing Corp.
PLC
Phillips Petroleum Co.
CBN
Cities Service Co., Columbian Group
PLN
Pellon Corp., Disogrin Industries, Div.
CNl
Conap, Inc.
PRC
Products Research 6 Chemical Corp. ,
CPY
Copolymer Rubber 5 Chemical Corp.
Chemical and Sealant Div.
PTT
Petro-Tex Chemical Corp.
DA
Diamond Shamrock Corp.
DCC
Dow Coming Corp.
RUB
Hooker Chemical Corp., Ruco Div.
DNS
Dennis Chemical Co.
DUP
E. I. duPont de Nemours 5 Co., Inc.
SB I
Standard Brands Chemical Industries, Inc.
SHC
Shell Oil Co., Shell Chemical Co. Div.
ENJ
Exxon Chemical Co., U.S.A.
SPD
General Electric Co., Silicone Products Dept .
EPl
Eagle Pitcher Industries, Inc.,
Rubber Products Div.
SWS
Stauffer Chemical Co., SWS Silicones Div.
TKL
Thiokol Chemical Corp.
Firestone Tire 5 Rubber Co.:
TUS
Texas-U.S. Chemical Co.
FIR
Firestone Plastics Co. Div.
FRS
Firestone Synthetic Rubber 6 Latex
UCC
Union Carbide Corp.
Co. Div.
USR
Uniroyal , Inc., Chemical Div.
GNT
General Tire 5 Rubber Co., Chemical Div.
WAY
Philip A. Hunt Chemical Corp., Wayland
GYR
Goodyear Tire S Rubber Co.
Chemical Div.
WIC
Wica Chemicals, Inc.
HDM
Hardman, Inc.
WTC
Witco Chemical Co., Inc.
Note. --Complete names and addresses of the above reporting companies
listed in Table 1 of the Appendix.
153
PLASTIC IZERS
Plasticizers are organic chemicals that are added to synthetic
plastics and resin materials to (1) improve workability during fabri-
cation, (2) extend or modify the natural properties of these materials,
or (3) develop new improved properties not present in the original
material. Table 1 presents statistics on U.S. production and sales of
plasticizers in as great as detail as is possible without revealing the
operations of individual producers . ^
U.S. production of plasticizers totaled 1,708 million pounds in
1972, an increase of 14.3 percent from the 1,494 million pounds reported
for 1971. Sales of plasticizers totaled 1,637 million pounds, valued at
$291 million, in 1972, compared with 1,404 million pounds, valued at
$258 million, in 1971.
Production of cyclic plasticizers in 1972, which consisted chiefly
of the esters of phthalic anhydride and phosphoric acid, amounted to 1,302
million pounds, an increase of 15.2 percent from the 1,130 million pounds
reported for 1971. Sales of cyclic plasticizers in 1972 totaled 1,273
million pounds, valued at $180 million, compared with 1,075 million pounds,
valued at $158 million, in 1971. The most important cyclic plasticizer was
di(2-ethylhexyl) phthalate, with production of 435 million pounds, in 1972.
Production of acyclic plasticizers in 1972 totaled 406 million pounds,
an increase of 11.7 percent from the 364 million pounds reported for 1971.
Sales of acyclic plasticizers totaled 364 million pounds, valued at $111
million, in 1972, compared with 330 million pounds, valued at $100 million,
in 1971. Epoxidized soya oils were the most important acyclic plasticizer
in 1972, with production of 85 million pounds.
See also table 2 which lists these products and identifies the manu-
facturers by codes. These codes are listed in table 3.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 1.~Plasticizers;' U.S. production and sales, 1972
[Listed below are plasticizers for which any reported data on production or sales may be published. (Leaders are
used where the reported data are accepted in confidence and may not be published or where no data were reported.)
Table 2 lists all plasticizers for which data on production or sales were reported and identifies the manufac-
turers of each]
Quantity
Grand total
Benzenoid'
Nonbenzenoid
PLASTICIZERS, CYCLIC
Total
Phosphoric acid esters, total
Cresyl diphenyl phosphate
Tricresyl phosphate
All other phosphoric acid esters
Phthalic anhydride esters, total
Butyl octyl phthalates (including butyl 2-ethylhexyl
phthalate, isobutyl 2-ethylhexyl phthalate, and butyl
n-octyl phthalate)
Dibutyl phthalate
Diethyl phthalate
Diisodecyl phthalate
Dimethyl phthalate
Dioctyl phthalates:
Di (2-ethylhexyl) phthalate
Diiso-octyl phthalate--
n-Hexyl n-decyl phthalate
All other phthalic anhydride esters
Triraellitic acid esters, total
Triiso-octyl trimellitate
Tri-n-octyl n-decyl trimellitate
Trioctyl trimellitate
All other triraellitic acid esters
All other cyclic plasticizers"
PLASTiaZERS, ACYCLIC
Total
Adipic acid esters, total
Di[2-(2-butoxyethoxy)ethyl] adipate
Di (2-ethylhexyl) adipate
Diisodecyl adipate
Dioctyl adipates (including diiso-octyl adipate)
n-Hexyl n-decyl adipate
n-Octyl n-decyl adipate
All other adipic acid esters
Complex linear polyesters and polymeric plasticizers'
Di (2-ethylhexyl) azelate
1,000
pounds
1,708.313
1,393,499
314,814
3,772
14,556
50,221
23,995
11,353
29,080
19,044
153,270
9,683
435,032
32,296
16,048
439,887
12,122
4,231
2,165
2,967
2,759
55,368
406,358
1,325
44,857
2,838
1,504
8,763
4,569
53,183
11,334
1,000
pounds
1,000
dollars
1,354,410
283,087
15,152
51,982
14,214
33,562
162,183
8,766
441,776
29,774
9,365
438,853
9,680
3,281
1,050
2,848
2,501
57,884
364,306
57,068
1,342
39,716
2,188
1,364
1,031
8,912
2,515
46,306
201,340
89,224
4,074
17,042
1,774
5,418
19,129
1,594
48,655
3,506
1,161
57.001
2,732
320
802
722
110,513
12,029
703
7,509
460
308
202
1,932
915
17,442
See footnotes at end of table.
PLASTICIZERS
TABLE 1.~Plasticizers; ' U.S. production and sales, 1972--Continued
Quantity
Unit
value^
PLASTICIZERS, ACYCLIC— Continued
Epoxidized esters:
Epoxidized soya oils
Octyl epoxytallates (including 2-ethylhexyl epoxy
tallates)
Glyceryl monoricinoleate
Isopropyl myristate
Isopropyl palmitate
Oleic acid esters, total
Butyl oleate
Methyl oleate
Propyl oleates (including n-propyl oleate and isopropyl
oleate)
All other oleic acid esters
Phosphoric acid esters
Sebacic acid esters, total
Dibutyl sebacate
Di(2-ethylhexyl) sebacate
All other sebacic acid esters
Stearic acid esters, total
n- Butyl stearate
All other stearic acid esters
Triethylene glycol di(caprylate-caprate)
All other acyclic plasticizers^
1,000
pounds
85,132
31,348
320
4,843
6,455
11,564
2,404
3,057
1,670
4,433
4,483
3,520
218
13.556
8,290
5,266
2,290
84,895
1,000
1,000
dollars
75,028
26,140
306
6,065
5,192
10,535
18,236
6,267
129
3,037
1,998
2,418
2,501
2,912
1,052
4,070
577
544
248
1,049
3,029
3,479
215
1,895
1,971
237
7,732
4,387
2,133
92,342
1,995
1,559
717
29,024
Per
pound
1 Includes data for compounds used principally (but not exclusively) as primary plasticizers. Does not include
clearly defined extenders or secondary plasticizers.
2 Calculated from rounded figures.
3 Includes benzenoid products as defined in part 1 of schedule 4 of the Tariff Schedules of the United States
Annotated.
■■ Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, isopropylidenediphenoxy
propanol, all other phosphoric acid esters (sales only), toluenesulfonamides, tetrahydrofurfuryl oleate, and other
cyclic plasticizers.
5 Adipic acid polyesters account for most of the production of complex linear polyesters and polymeric plasticizers.
6 Includes data for azelaic, citric and acetylcitric, lauric, myristic, palmitic, pelargonic, ricinoleic, and sebacic
acid esters, glyceryl and glycol esters, and other acyclic plasticizers, not separately shown.
SYNTHETIC ORGANIC CHEMICALS. 1972 ■
TABLE 2.— Plasticizers for which U.S. production or sales were reported, identified by
MANUFACTURER, 1972
[Plasticizers for which separate statistics are given in table 1 are marked below with an asterisk (*) ; products not
so marked do not appear in table 1 because the reported data are accepted in confidence and may not be published.
Manufacturers 's identification codes shown below are taken from table 3. An x signifies that the manufacturer did
not consent to his identification with the designated product]
Manufacturers' identification code
(according to list in table 3)
PLASTICIZERS, CYCLIC
Coumarone-indene plasticizers
N-Cyclohexyl-p-toluenesulfonamide
Dibenzyl sebacate
Diethylene glycol dibenzoate
Di-tert-octylphenyl ether
Dipropanediol dibenzoate
N-Ethyl-p-toluenesulfonamide
Isopropylidenediphenoxypropanol
Naphthalene, alkylated
'Phosphoric acid esters:
'Cresyl diphenyl phosphate
Dibutyl phenyl phosphate
Diphenyl octyl phosphate
Methyl diphenyl phosphate
*Tri cresyl phosphate
Tri phenyl phosphate
*Phthalic anhydride esters:
Alkyl benzyl phthalates
Butyl benzyl phthalate
Butyl cyclohexyl phthalate
•Butyl octyl phthalates:
Butyl 2-ethylhexyl phthalate
Butyl n-octyl phthalate
Di(2-butoxyethyl) phthalate
*Dibutyl phthalate
Dicyclohexyl isodecyl phthalate
Di cyclohexyl phthalate
Diethyl isophthalate
♦Diethyl phthalate
Dihexyl phthalate
*Di isodecyl phthalate
Di-iso-hexyl phthalate
Diisononyl phthalate
Di(2-methoxyethyl) phthalate
Dimethyl isophthalate
"Dimethyl phthalate
Dinonyl phthalate
Dioctyl phthalates:
Dicapryl phthalate
Di (2-ethylhexyl) isophthalate
*Di (2-ethylhexyl) phthalate
*Diiso-octyl phthalate
Di- n-octyl phthalate
Mixed dioctyl phthalates
Diphenyl phthalate
*ni-tridecyl phthalate
2- (Ethylhexyl)isobutyl phthalate
Glycol phthalate esters:
Butyl phthalyl butyl glycolate
Ethyl (and methyl) phthalyl ethyl glycolate-
Polypropylene glycol bis(amyl) phthalate
All other glycol phthalate esters
NEV.
MON.
WTH.
VEL.
DOIV.
VEL.
MON.
DOW.
ACC.
FMP,
MON, MTR
SFS
MON,
ORO.
MON.
FMP,
MON.
FMP,
MON, MTR
SFS
EK,
MON, SFS.
MON.
MON.
ACS,
CPS.
ACP,
GRH, MON
TEK
UCC
RCI,
USS.
ARC,
FMP.
.(^CP,
COM, EKT
GRH
HAL
MON, RCI, RUB, SW,
UCC,
USS
WTC.
GRH.
FMP,
MON, PFZ
PFZ.
EKT,
KF, MON,
PFZ.
USS.
ACP,
CO, EKT,
ENJ,
GRH,
MON, RCI, TEK, UCC,
USS,
WTC
ENJ.
ENJ,
PFZ.
EKT,
FMP, SFS
PFZ.
EKT,
KF, MON,
TCC.
RCI.
WTH.
UCC.
ACP, BFG, CO, EKT, ENJ, GRH, MON, PFZ, RCI, RUB, TEK,
UCC, USS, WTC.
ACP, ENJ, GRH, MON, RCI, TEK, UCC, USS.
EK.
TEK.
MON.
ACP, CO, ENJ, GRH, MON, RCI, RUB, TEK, UCC, USS.
GRH.
MON .
MON.
UCC.
HPC, WTC.
PLASTICIZERS
TABLE 2,~Plasticizers for which U,S, production or sales were reported, identified by
MANUFACTURER, 1972~CONTINUED
Manufacturers' identification codes
(according to list in table 3]
PLASTICIZERS, CYCLIC--Continued
*Phthalic anhydride esters--Continued
*n-Hexyl n-decyl phthalate
Hexyl isodecyl phthalate
Isodecyl tridecyl phthalate
Iso-octyl isodecyl phthalate
n-Octyl n-decyl phthalate
All other phthalic anhydride esters
Polyethylene glycol dibenzoate
Tetrahydrofurfuryl oleate
Toluenesulfonainide o- , p- mixtures
*Trimellitic acid esters:
Tri(2-ethylhexyl3 trimellitate
Tri-n-hexyl trimellitate
Tri isodecyl trimellitate
Triisononyl trimellitate
*Tri iso-octyl trimellitate
*Tri-n-octyl n-decyl trimellitate
*Trioctyl trimellitate
All other trimellitic acid esters
Trimethylpentanediol dibenzoate
All other cyclic plasticizers
PLASTICIZERS, ACYCLIC
*Adipic acid esters:
''Di[2-(butoxyethoxyJethyl] adipate
*Di(2-ethylhexyl) adipate
Diisobutyl adipate
*Di isodecyl adipate
Diisononyl adipate
Diisopropyl adipate
•Dioctyl adipates:
Diiso-octyl adipate
Di-n-octyl adipate
Di- tridecyl adipate
*n-Hexyl n-decyl adipate
Iso-octyl isodecyl adipate
*n-Octyl n-decyl adipate
All other adipic acid esters
Azelaic acid esters:
*Di (2-ethylhexyl) azelate
Diisobutyl azelate
Diiso-octyl azelate
All other azelaic acid esters
1 ,4-Butanediol dicaprylate
But oxy ethyl pelargonate
Castor oil maleate
Citric and acetylcitric acid esters
•Complex linear polyesters and polymeric plasticizers-
Di[(butoxyethoxy)ethoxy] methane
Dibutyl tartrate
Diethylene glycol dipelargonate (Dinonanoate)
Diiso-octyl dig lyco late
ACP, CO, ENJ, TEK, UCC .
GRH.
TEK.
ACP, GRH.
ACP, CO, GRH, MON, RCl, TEK, UCC, USS.
ACP, FMP, PF2, RUB, TEK, UCC, USS.
VEL.
EMR.
ACY, LAK, MON.
GRH, PFZ, RCI.
CO, RUB.
PFZ.
ENJ.
ENJ, GRH, RCI, RUB, TEK, USS.
GRH, PFZ, RCI, RUB, TEK, USS.
CO, RUB, TEK, USS.
X.
VEL.
MON, NEV, SFS.
FMP, RCI, TKL, WTH.
CO, DA, EKT, ENJ, GRH, MON, PFZ, RCI, RH, RUB, TEK, UCC,
USS.
GRH, HAL.
ACP, ENJ, GRH, MON, PFZ, RCI, RH, RUB, UCC, USS.
ENJ, RUB.
SBC, VND.
GRH,
RH,
RUB,
USS.
ACP.
GRH.
GRH,
TEK
USS
GRH,
PFZ
ACP.
CO,
GRH,
MON,
RCI,
RH, USS
ARC,
EK,
GRH,
PFZ,
UCC,
WTH.
EKT,
EMR
PFZ
RCI
UCC
HAL.
EMR,
PFZ
EMR.
RUB.
HAL.
RH.
GLY,
PFZ
ASH,
EKT
EMR
GRH
HAL
MON, P
TKL.
ARC.
EMR.
CCA.
552-743 0-74-11
SYNTHETIC ORGANIC CHEMICALS, 1972'
table 2.--plastic1zers for which u.s. production or sales were reported, identified by
Manufacturer, 1972— Continued
Manuf actuiers ' identification codes
(according to list in table 3)
PLASTICIZERS, ACYCLIC--Continued
Epoxidized esters:
Butyl epoxytallate
Epoxidized linseed oils
*Epoxidized soya oils
Epoxidized tall oils
*2-Ethylhexyl epoxytallates
Octyl epoxystearates
*Octyl epoxytallates
All other epoxidized esters
Glyceryl tributyrate and tripropionate
Glycol pelargonate
Isodecyl nonanoate (Isodecyl pelargonate)
Myristic acid esters: *Isopropyl myristate
*01eic acid esters:
2-Butoxyethyl oleate
•Butyl oleate
Decyl oleate
Glyceryl trioleate (Triolein)
Isobutyl oleate
*Isopropyl oleate
*Methyl oleate
♦Propyl oleate
Palmitic acid esters;
2-Ethylhexyl palmitate
Isobutyl palmitate
Iso-octyl palmitate
*lsopropyl palmitate
*Phosphoric acid esters:
Tri(2-butoxyethyl) phosphate
Tri (2 - ch loroethy 1 ) phosphate
Tri (2-chloropropyl) phosphate
Triethyl phosphate
Trioctyl phosphate
All other phosphoric acid esters
Ricinoleic and acetylricinoleic acid esters:
n- Butyl acetylricinoleate
Butyl ricinoleate r
•Glyceryl monoricinoleate
Glyceryl tri (acetyl ricinoleate)
Methyl ricinoleate
All other ricinoleic and acetylricinoleic acid esters-
*Sebacic acid esters:
Dibutoxyethyl sebacate
•Dibutyl sebacate
*Di(2-ethylhexyl) sebacate
Di iso-octyl sebacate
•Stearic acid esters:
Butoxyethyl stearate
•n- Butyl stearate
Dimethyl ammonium stearate
Dodecyl (lauryl) stearate
2-Ethylhexyl stearate
Glyceryl triacetyl stearate
Hexadecyl stearate
2-Hydroxypropyl stearate
Isobutyl stearate
ASH.
ASH .
ASH,
RH.
ASH,
WTC.
RH,
EMR,
EKT.
EMR.
EMR.
ARC,
FMP, NIL, RH, UCC, WRC, WTC.
NTL, UCC.
TEK, UCC, WTC.
RH.
SBC, TCH, WM, WTH.
ARC, HAL.
ARC, EMR, HAL, WM, WTC, WTH.
VND.
EMR, GLY, WM.
DA.
EMR,
WM.
CHL,
DA,
EMR,
HUM.
CHL,
EMR
WM.
WTH.
ARC,
DA.
RUB.
ARC,
SBC
TCH
WM,
WTH.
FMP.
SFS
UCC
SFS.
EKT.
UCC
SFS,
SM
NTL.
NTL.
RCI
DA,
GLY,
HAL,
NTL.
NTL
NTL
NTL.
HAL
RCI
EKT
GRH
RCI
RH,
USS, WTH
GRH
PFZ
RCI
RH,
WTH.
DA,
RCI.
ARC, ASH, CHL, DA, EMR, GRO, RUB, SCP, TCH, WM, WTH.
RH.
RCI.
FMP, SCP.
NTL.
SCP.
WTH.
ARC, DA, WM.
PLASTICIZERS
TABLE 2,— Plasticizers for which U.S. production or sales were reported, identified by
MANUFACTURER, 1972--CoNTINUED
Chemical
Manufacturers' identification codes
(according to list in table 3}
PLASTICIZERS, ACYCLIC--Continued
♦Stearic acid esters--Continued
HK.
HK.
CHL.
ARC. DA, HPC, TCH, WM.
ARC, EKT.
UCC.
RUB.
HAL, PVO, RUB, WM.
UCC.
UCC.
RUB.
EKX.
EMR, HAL, HPC, SCP, SM, WTH.
th 1 r
An ^th^ eara e
S t r ' h t t
<
Triethylene glycol dicaprylate
T ^ th^i^"^ & y^o ,^ J^^''^?' .ft^t'^^^t^l^
Triethylene glycol di (2-ethylhexanoate)
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3.--PLASTICIZERS; Directory of manufacturers^ 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of plasticizers manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are
listed below in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
ACC
Amoco Chemicals Corp.
NEV
Neville Chemical Co.
ACP
Allied Chemical Corp., Plastics Div.
NTL
NL Industries, Inc.
ACY
American Cyanamid Co.
ARC
Armak Co .
ORO
Chevron Chemical Co.
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
PFZ
Pfizer, Inc.
BFG
B. F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
PVO
PVO International, Inc.
RCI
Reichhold Chemicals, Inc.
CCA
Cincinnati Milacron Chemicals, Inc.
RH
Rohm & Haas Co.
CHL
■ Chemol , Inc.
RUB
Hooker Chemical Corp. , Ruco Div.
CO
Continental Oil Co.
COM
Commercial Solvents Corp.
SBC
Scher Brothers, Inc.
CPS
CPS Chemical Co.
SCP
Henkel, Inc.
SFS
Stauffer Chemical Co., Specialty Chemical
DA
Diamond Shamrock Corp.
Div.
DOW
Dow Chemical Co.
SM
Mobil Oil Corp., Mobil Chemical Co. Div.,
Industrial Chemical Div.
EK
Eastman Kodak Co. :
SW
Sherwin-Williams Co.
EKT
Tennessee Eastman Co. Div.
EKX
Texas Eastman Co. Div.
TCC
Tanatex Chemical Corp.
EMR
Emery Industries, Inc.
TCH
Emory Industries, Inc., Trylon Chemicals Div.
ENJ
Enjay Chemical Co.
TEK
Teknor Apex Co.
TKL
Thiokol Chemical Corp.
FMP
FMC Corp., Organic Chemicals Div.
UCC
Union Carbide Corp.
GLY
Glyco Chemicals, Inc.
USS
USS Chemicals Div. of U.S. Steel Corp.
GRH
W.R. Grace S Co., Hatco Chemical Div.
GRO
Millmaster Onyx Corp., A. Gross § Co., Div.
VEL
Velsicol Chemical Corp.
VND
Van Dyk 6 Co . , Inc.
HAL
C. P. Hall Co. of Illinois
HK
Hooker Chemical Corp.
WM
Wilson Pharmaceutical ti Chemical Corp.,
HPC
Hercules, Inc.
Wilson-Martin Div.
HUM
Kraftco Corp., Humko Plastics Div.
WRC
Ventron Corp., Wood Ridge Chemical
WTC
Witco Chemical Co., Inc.
KF
Kay-Fries Chemicals, Inc.
WTH
Union Camp Corp., Harchem Div.
LAK
Lakeway Chemicals, Inc.
MON
Monsanto Co.
MTR
Sobin Chemicals, Inc., Montrose Chemical Div.
Not
5. --Complete names and addresses of the above report
ing comn
inies are listed in Table 1 of the Aonendix.
161
SURFACE-ACTIVE AGENTS
The surface-active agents included in this report are organic chemicals
that reduce the surface tension of water or other solvents and are used
chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or
wetting agents in either aqueous or nonaqueous systems. Waxes and products
used chiefly as plasticizers are excluded. Surface- active agents are pro-
duced from natural fats and oils; from si Ivi chemicals such as lignin, rosin,
and tall oil; and from chemical intermediates derived from coal tar and
petroleum. A major part of the output of the bulk chemicals shown in this
report is consumed in the form of packaged soaps and detergents for house-
hold and industrial use. The remainder is used in the processing of textiles
and leather, in ore flotation and oil-drilling operations, and in the manu-
facture of agricultural sprays, cosmetics, elastomers, foods, lubricants,
paints, pharmaceuticals, and many other products.
Table 1 shows statistics for production and sales of surface-active
agents grouped by ionic class and by chemical class and subclass; table
2 lists these products and identifies the manufacturers.^ All quantities
are reported in terms of 100-percent organic surface-active ingredient
and thus exclude all inorganic salts, water, and other diluents. Sales
statistics reflect sales of bulk surface-active agents only; sales of
formulated products are excluded.
Total U.S. production of surface-active agents in 1972 amounted to
4";039 million pounds, or 5.5 percent greater than the 3,828 million pounds
reported for 1971. Sales of bulk surface-active agents in 1972 amounted
to 2,258 million pounds, valued at $451 million, compared with sales in
1971 of 2,186 million pounds, valued at $422 million. In terms of quantity,
sales in 1972 were thus 3.3 percent larger than in 1971; in terms of value,
sales in 1972 were 6.7 percent larger than in 1971.
Production of anionic surface-active agents in 1972 amounted to 2,747
million pounds, or 68.0 percent of the total output reported for 1972 and
5.9 percent greater than the anionic output reported for 1971. Sales of
anionics in 1972 amounted to 1,274 million pounds, valued at $195 million.
Of the total anionic output, 894 million pounds consisted of potassium and
sodium salts of fatty, rosin, and tall oil acids, of which 466 million
pounds was the sodium salt of tallow acids and 131 million pounds was the
sodium salt of coconut oil acids; 688 million pounds consisted of alkyl-
benzenesulfonates, of which 364 million pounds was sodium dodecylbenzene-
sulfonate, 143 million pounds was dodecylbenzenesulfonic acid, and 150
million pounds was sodium tridecylbenzenesulfonate; 522 million pounds
consisted of ligninsulfonates, of which 327 million pounds was the calcium
salt; and 207 million pounds consisted of sulfated ethers.
Production of nonionic surface-active agents in 1972 amounted to 1,048
million pounds, or 26.0 percent of the total output reported for 1972 and
See table 3 for a list of manufacturers and their codes.
162
SYNTHETIC ORGANIC CHEMICALS, 1972
2.7 percent more than the nonionic output reported for 1971. Sales of
nonionics in 1972 amounted to 787 million pounds, valued at $174 million.
Of the total nonionic output, 314 million pounds consisted of alkylphenol
ethoxylates and other benzenoid ethers, of which 178 million pounds was
nonylphenol ethoxylate; 423 million pounds consisted of alcohol ethoxylates
and other nonbenzenoid ethers, of which 324 million pounds was mixed linear
alcohol ethoxylate; 102 million pounds consisted of glycerol esters; and
88 million pounds consisted of alkanol amides.
Production of cationic surface-active agents in 1972 amounted to 229
million pounds, or 5.7 percent of the total output reported for 1972 and
12.9 percent greater than the cationic output reported for 1971. Sales of
cationics in 1972 amounted to 183 million pounds, valued at $72 million.
Of the total cationic output, 60 million pounds consisted of quaternary
ammonium salts not containing oxygen, and 68 million pounds consisted of
amines not containing oxygen.
Production of amphoteric surface- active agents in 1972 amounted to
14.4 million pounds, or 0.4 percent of the total output reported for 1972
and 45.8 percent greater than the amphoteric output reported for 1971. Sales
of amphoterics in 1972 amounted to 14.1 million pounds, valued at $9.4
million.
The difference between production and sales reflects inventory changes
and captive consumption of soaps and surface- active agents by synthetic
rubber producers, and by manufacturers of cosmetics, packaged detergents,
bar soaps, and other formulated consumer products. In some instances the
difference may also reflect quantities of surface- active agents used as
chemical intermediates, e.g., nonionic alcohol and alkylphenol ethoxylates
which may be converted to anionic surface- active agents by phosphation or
sulfation.
SURFACE-ACTIVE AGENTS
TABLE 1,— Surface-active agents: U.S. production and sales. 1972
[Listed below are all surface-active agents for which reported data on production or sales may be published. (Leaders
(...3 are used where the reported data are accepted in confidence and may not be published or where no data were
reported.) Table 2 lists all surface-active agents for which data on production or sales were reported and identi-
fies the manufacturers of each]
Production
Sales^
Quantity'
Grand total
Benzenoid
Nonbenzenoid
Amphoteina Surface-Active Agents
Total
Anionic Surface-Active Agents
Total
Carboxylic acids (and salts thereof), total
Amine salts of fatty rosin, and tall oil acids
Carboxylic acids having amide, ester, or ether linkages
total
N-Lauroylsarcosine, sodium salt
All other
Potassium and sodium salts of fatty, rosin, and tall
acids, total
Castor oil acids, potassium salt
Coconut oil acids, potassium and sodium salts, total-
Potassium salt
Sodium salt
Corn oil acids, potassium and sodium salts
Mixed vegetable oil acids, potassium salt
Oleic acid, sodium salt
Palm oil acids, sodium salt
Soybean oil acids, potassium and sodium salts
Stearic acid, potassium and sodium salts
Tall oil acids, potassium salt
Tall oil acids, sodium salt
Tallow acids, sodium salt
All other
Phosphoric and polynhosphoric acid esters (and salts
thereof^i total
Alcohols ana phenols, ethoxylated and phosphated, total
Dinonylphenol, ethoxylated and phosphated
Mixed linear alcohols, ethoxylated and phosphated
Nonylphenol, ethoxylated and phospnated
Phenol, ethoxylated and phosphated
Tridecyl alcohol, ethoxylated and phosphated
All other
Alcohols, phosphated or polyphosphated, total
2-Ethylhexyl phosphate, sodium salt
All other
Sulfonic acids (and salts thereof), total
Alkylbenzenesulfonates, total
Dodecylbenzenesulfonic acid
Dodecylbenzenesulfonic acid, calcium salt
Dodecylbenzenesulfonic acid, isopropylamine salt
1,000
pounds
1,119,229
2,919,558
907,011
12,711
3,823
142,944
11,825
131,119
801
2,814
1,473
714
982
19,543
10,720
465,550
247,988
26.514
18,028
759
3,602
7,410
728
1,412
4,117
8,486
447
8,039
688,176
143,391
12,412
2,221
1,000
pounds
2.257.546
1,000
dollars
4S0.768
547,259
1,710,287
444
9,300
9,300
48
787
2,841
229
643
528
16,782
2,561
10,258
3,434
6,101
1,094
4,197
6,204
6,204
774,160
174,613
50,823
9,500
5,425
111,093
339,675
148
6,213
6,213
10
287
2,576
37
131
162
3,779
348
1,263
9,509
1,520
1,923
428
2,319
3,319
3,319
78,386
32,317
7,100
4,098
1,068
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE L— Surface-active agents; U.S, production and sales^ 1972--Continued
Production '
Sales'^
Quantity
Anionic Surface-Aative jJgents--Continued
Sulfonic acids (and salts thereof ) --Continued
A 1 ky 1 ben zenesulfonates- -Continued
Dodecylbenzenesulfonic acid, (mixed alkyl)amine
salt
Dodecylbenzenesulfonic acid, sodium salt
Dodecylbenzenesulfonic acid, triethanolamine salt
Tridecylbenzenesulfonic acid, sodium salt
All other
Benzene-, cumene-, toluene-, and xylenesulfonates ,
total
Cumenesulfonic acid, ammonium salt
Xylenesulfonic acid, ammonium salt
Xylenesulfonic acid, sodium salt
All other
Ligninsulfonates, total
Ligninsulfonic acid, calcium salt
Ligninsulfonic acid, sodium salt
All other
Naphthalenesulfonates, total
Butylnaphthalene sulfonic acid, sodium salt
All other
Sulfonic acids having amide li.ikages. total
Sulfosuccinic acid derivatives
Taurine derivatives
Sulfonic acids having ester or ether linkages, total
Sulfosuccinic acid esters, total
Sulfosuccinic acid, bis(2,6.-dimethyl-4-heptyl)
ester, sodium salt
Sulfosuccinic acid, .bis (2-ethylhexyl) ester, sodium
salt
All other
Other sulfonic acids having ester or ether linkages
All other sulfonic acids
Sulfuric acid esters (and salts thereof), total
Acids, amides, and esters, sulfated, total
Coconut oil acids - ethanolamine condensate, sulfated,
potassium salt
Esters of sulfated oleic acid, total
Butyl oleate, sulfated, sodium salt
Isopropyl oleate, sulfated, sodium salt
Propyl oleate, sulfated, sodium salt
All other
■;leic acid, sulfated, disodium salt
Other acids, amides, and esters, sulfated
Alcohols, sulfated, total
Decyl sulfate, sodium salt
Dodecyl sulfate salts, total
Dodecyl sulfate, ammonium salt
Dodecyl sulfate, magnesium salt
Dodecyl sulfate, sodium salt
Dodecyl sulfate, triethanolamine salt
All other
Other alcohols sulfated
Ethers, sulfated, total
Alkylphenols, ethoxylated and sulfated, total
Nonylphenol, ethoxylated and sulfated, sodium salt--
All other
Dodecyl alcohol, ethoxylated and sulfated, ammonium
salt
pounds
121
364,067
6,905
149,870
9,489
64,009
3,750
4,962
57,409
17,908
522.323
526,626
58,662
157,055
7,508
501
7,207
4,954
1,526
5,428
41,828
16,060
559
12,387
5,114
25,768
5,514
5,015
1,540
520
255
2,718
12,221
545
26
841
16
050
17
552
206
980
1,000
pounds
89,867
7,795
54,751
5,714
28,289
22,728
505,981
507,655
61,094
137,232
7,005
297
6,708
1,132
1,668
23,781
11,987
2,757
11,794
18,571
29
4,824
1,589
434
227
2,574
11,865
1,855
44,107
192
34,169
2,670
20,433
11,066
9,746
125,790
5,786
311
3,475
2,657
1,000
dollars
15,606
1,725
2,722
5
211
425
'2
600
2
186
18
699
7
688
6
038
4
973
2
657
1,393
15,379
6,935
5,500
1,435
8,444
4,379
150
101
14,845
1,551
8,595
4,917
3,492
21,404
1,155
71
1,084
See footnotes at end of table.
SURFACE-ACTIVE AGENTS
TABLE 1. --Surface-active agents: U.S. production and sales, 1972--Continued
Anionic Sup face- Active ^^ewts- -Continued
Sulfuric acid esters (and salts thereof) --Continued
Ethers, sul f at ed--Cont inued
Dodecyl alcohol, ethoxylated and sulfated, sodium
salt
Mixed linear alcohols, ethoxylated and sulfated,
ammonium salt
Mixed linear alcohols, ethoxylated and sulfated, sodium
salt
All other
Natural fats and oils, sulfated, total
Castor oil, sulfated, sodium salt
Coconut oil, sulfated, sodium salt
Cod oil, sulfated, sodium salt
Herring oil, sulfated, sodium salt
Lard oil, sulfated, sodium salt
Mixed fish oils, sulfated, sodium salt
Neat's-foot oil, sulfated, sodium salt
Peanut oil, sulfated, sodium salt
Ricebran oil, sulfated, sodium salt
Soybean oil, sulfated, sodium salt
Sperm oil, sulfated, sodium salt
Tallow, sulfated, sodium salt
All other
Other anionic surface-active agents^
Cationio Surface-Active Agents
Total
Amine oxides and oxygen-containing amines (except those
having amide linkages), total
Acyclic, total
(Coconut oil alkyl)amine, ethoxylated
(Tallow alkyl)amine, ethoxylated
All other
Cyclic (except imidazoline and oxazoline derivatives)
Imidazoline and oxazoline derivatives, total
2-Heptadecyl-l- (2-hydroxyethyl)-2-imidazoline
1- (2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2-
imidazoline
1- (2-Hydroxyethyl)-2-nor(tall oil alkyl)-2-imidazoline--
All other
Amines and amine oxides having amide linkages, total
Carboxylic acid - diamine and polyamine condensates , total-
Mixed fatty acids - polyalkylenepolyamine condensate
Tall oil acids - diethylenetriamine and polyalkylene
polyamine condensate
All other
Other amines and amine oxides having amide linkages
Amines, not containing oxygen (and salts thereof), total
Amine salts
Diamines and polyamines, total
N- (Coconut oil alkyl)trimethylenediamine
Imidazoline derivatives
N- (9-0ctadecenyl)trimethylenediamine
All other
Primary monoamines, total
(Hydrogenated tallow alkyl)amine
9-Octadecenylaraine
Octadecylamine
(Tallow alkyl) amine
All other
Production i
1,000
pounds
8
965
103
763
87
358
38
526
8
271
1
023
2
028
869
255
4
256
50,623
45,731
4,368
2,191
39,172
1,778
3,114
266
444
791
1,613
22,839
2,308
17,764
2,767
4,830
67,675
3,112
13,383
430
2,590
2,342
8,021
27,910
3,789
4,866
541
5,225
13,489
1,000
17.557
93,732
37,233
8,311
925
2,001
860
245
2,573
69
53
141
1,338
10,000
10,717
204,887
23,841
19,113
3,985
1,913
13,215
1,964
2,764
235
523
337
1,669
22,006
17,474
4,532
3,493
2,102
12,240
465
1,904
2,243
7,628
27,708
3,729
4,113
5,522
14,344
1,000
do I laps
3,068
3,326
13,298
8,293
2,654
243
289
125
1,538
2,409
10,229
8,291
1,362
830
6,099
574
1,364
123
269
132
840
2,427
2,640
2,158
782
3,444
220
548
868
1,808
9,742
1,175
1,565
1,481
5,521
See footnotes at end of table
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 1. --Surface-active agents: U.S. ppoduction and sales, 1972--Continued
Production
Quantity
Cationic Surface-Active /Ijents- -Continued
Amines, not containing oxygen (and salts thereof)--
Continued
Secondary and tertiary monoamines, total
6is(hydrogenated tallow alkyljamine
N,N-Dimethyldodecylamine
N,N-Dimethylhexadecylamine
N,N-Dimethyloctadecylamine
N-Methylbis(hydrogenated tallow alkyljamine
All other
Oxygen-containing quaternary ammonium salts
Quaternary ammonium salts, not containing oxygen, total
Acyclic, total
Bis (coconut oil alkyl}dimethylammonium chloride
Bis (hydrogenated tallow alkyl)dimethylammonium chloride--
Hexadecyltrime thy 1 ammonium chloride
Trimethyl (tallow alkyl) ammonium chloride
All other
Benzenoid, total
Benzyl (coconut oil .alkyl)dimethylammonium chloride
Benzyldimethvl (mixed alkyll ammonium chloride
Benzy 1 dimethyl DC tad ecyl ammonium chloride
Benzyl trimethyl ammonium chloride
All other
Groups listed above for which separate sales data may not be
shown'
Nonicmic Surface-Active Agents
Total
Carboxylic acid amides, total
Diethanolamine condensates (amine/acid ratio=2/l), total —
Capric acid
Coconut oil acids
Coconut oil and tallow acids
Laurie acid
Oleic acid
Stearic acid
Tall oil acids
All other
Diethanolamine condensates (other amine/acid ratios),
total
Coconut oil acids (amine/acid ratio=l/l)
Laurie acid (amine/acid ratio=l/l)
Oleic acid (amine/acid ratio=l/l)
Stearic acid (amine/acid ratio=l/l)
All other
Ethanolamine and isopropanolamine condensates, total
Coconut oil acids - ethanolamine condensate
(amine/acid ratio=2/l)
Coconut oil acids - ethanolamine condensate
(amine/acid ratio=l/l)
All other
Carboxylic acid esters, total
Anhydrosorbitol esters, total
Anhydrosorbitol monoester of tall oil acids
Anhydrosorbitol monolaurate
Anhydrosorbitol monopa Imitate
Anhydrosorbitol monostearate
All other
1,000
pounds
21, no
586
552
1,513
2,233
18,386
23,233
59,876
1,000
45,451
3,273
31,383
904
866
9,025
14,425
434
6,068
1,580
6,343
26,477
84
15,361
3,029
2,020
932
827
413
3,811
11,359
11,737
24,667
231
5,926
2,042
7,946
8,522
454
477
588
1,291
2,150
51,953
39,708
2,956
28,322
874
780
6,776
12,245
409
6,098
239
5,499
60,044
21,043
147
13,643
2,258
417
724
781
73
3,000
1,122
3,298
5,167
193.630
15,761
149
3,512
1,536
4,011
6,553
1,000
do I lars
112
288
332
639
598
23,962
14,039
1,204
7,004
685
409
4,737
9,923
274
5,233
17,686
6,444
57
4,206
494
160
227
359
22
919
36,676
29,414
8,470
21,462
19,131
4,786
10,344
424
315
96
540
3,906
9,968
3,588
24,564
9,587
2,772
5,538
41
1,335
480
1,332
2,350
SURFACE-ACTIVE AGENTS
TABLE 1.— Surface-active agents: U.S. production and sales. 19/2— Continued
Quantity '
1,000
Nonionia Surface-Active Agents --Continuei
Carboxylic acid esters--Continued
Diethylene glycol esters, total
Diethylene glycol distearate
Diethylene glycol monolaurate
Diethylene glycol monostearate
Diethylene glycol sesqullaurate
All other
Ethoxylated anhydrosorbitol esters, total
Ethoxylated anhydrosorbitol mono-oleate
Ethoxylated anhydrosorbitol monostearate
Ethoxylated anhydrosorbitol tristearate
All other
Ethylene glycol esters
Glyceral esters, total
Complex glycerol esters
Glycerol esters of chemically defined acids, total
Glycerol monolaurate
Glycerol mono-oleate
Glycerol monoricinoleate
Glycerol monostearate
All other
Glycerol esters of mixed acids, total
Glycerol monoester of hydrogenated cottonseed oil
aeids
Glycerol monoester of hydrogenated soybean oil acids-
All other
Natural fats and oils, alkoxylated, total
Castor oil, ethoxylated
Hydrogenated castor oil, ethoxylated
All other
Polyethylene glycol esters, total
Polyethylene glycol esters of chemically defined acids,
total
Polyethylene glycol dilaurate
Polyethylene glycol dioleate
Polyethylene glycol monolaurate
Polyethylene glycol mono-oleate
Polyethylene glycol monostearate
All other
Polyethylene glycol esters of rosin and tall oil acids-
Polyethylene glycol esters of other mixed acids, total-
Polyethylene glycol sesquiester of coconut oil acids-
All other
Polyglycerol esters
Propanediol esters, total
1 , 2- Propanediol monostearate
All other
Other carboxylic acid esters
Ethers, total
Benzenoid ethers, total
Alkylphenol - formaldehyde condensates, alkoxylated
Dodecylphenol, ethoxylated
Nonylphenol, ethoxylated
All other
Nonbenzenoid ethers, total
Linear alcohols, alkoxylated, total
Decyl alcohol, ethoxylated
Dodecyl alcohol, ethoxylated
Hexadecyl alcohol, ethoxylated
Mixed linear alcohols, ethoxylated
Mixed linear alcohols, ethoxylated and propoxylated--
9-Octadecenyl alcohol, ethoxylated
Octadecyl alcohol, ethoxylated
All other
2.098
452
52
450
354
790
25,075
7,023
5,436
2,536
10,080
4,786
102,320
6,376
31,410
60
2,768
83
27,191
1,308
64,534
4,176
13,126
47,232
11,258
5,668
3,736
1,854
31,502
23,435
1,159
4,402
3,838
3,630
5,345
5,061
6,521
1,546
395
1,151
4,891
3,573
2,593
980
13,427
736,911
313,851
9,429
17,352
177,897
109,173
423,060
358,196
1,293
9,175
1,152
323,725
14,687
2,899
1,336
3,929
1,000
pounds
2,002
421
54
409
347
771
21,367
6,502
4,609
10,256
4,610
100,498
5,312
33,956
52
2,355
75
29,962
1,512
61,230
14,174
47,056
10,169
4,967
3,508
1,694
23,320
17,385
944
1,196
3,475
3,199
4,680
3,891
4,505
1,430
414
1,016
1,909
1,481
428
13,994
533.185
272,514
3,032
17,223
163,099
89,160
260,671
210,442
7,722
664
183,363
11,779
2,485
372
4,057
1,000
dollar's
653
126
19
128
110
270
8,143
2,422
1,856
3,865
1,296
25,437
1,846
6,823
22
768
44
5,295
694
16,768
4,124
12,644
2,908
1,607
835
466
8,231
6,624
336
401
1,257
1,110
1,990
1,530
1,122
485
179
306
678
554
124
4,014
99.823
47,649
722
2,491
24,857
19,579
52.174
36,528
1,667
298
28.451
2,459
1,661
256
1,736
SYNTHETIC ORGANIC CHEMICALS- 1972 ■
TABLE 1, --Surface-active agents: U,S, production and sales. 1972 --Continued
1,600
dollars
15,646
974
Unit
value'
Per
povnd
Nonionio Surface-Active Agents --Continued
Ethers - -Cont inued
Nonbenzenoid ethers — Continued
Other ethers and thioethers, total
Tridecyl alcohol, ethoxylated
Trimethylnonyl alcohol, ethoxylated
All other'
1,000
pounds
64,864
4,501
2,145
1,000
pounds
50,229
3,569
$0.31
.27
1 All quantities are given in terms of 100 percent organic surface-active ingredient.
2 Sales include products sold as bulk surface-active agents only.
3 Calculated from rounded figures.
'' The term "benzenoid," used in this report, describes any surface-aciive agent, except lignin derivatives, whose
molecular structure includes 1 or more 6-membered carbocyclic or heterocyclic rings with conjugated double bonds
(e.g., the benzene ring or the pyridine ring).
^ Includes ligninsulfonates.
^ Includes production of ''all other" sulfated alcohols; also includes sales of "all other" potassium and sodiiun salts
of fatty, rosin, and tall oil acids.
' Includes "all other" secondary and tertiary monoamines not containing oxygen (and salts thereof) and all oxygen-con-
taining quaternary ammonium salts.
^ Includes ethoxylated sorbitol esters and miscellaneous esters
' Includes "other" nonionic surface-active agents.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972
[Surface-active agents for which separate statistics are given in table 1 are marked with an asterisk (*) ; products
not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be
published. Manufacturers' identification codes shouTi belov; are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 31
Amphoteric Surfaae-Aative Agents
Acyclic:
Alkylbetaine
Cl-Carboxyheptadecyl) trimethylammonium hydroxide ,
inner salt.
CCarboxymethyl) [3- (coconut oil araido)propyl]dimethyl-
ammonium chloride, ammonium salt.
(Carboxymethyl) [3- (coconut oil amido)propyl]di-
me thy 1 ammonium chloride, sodium salt.
(Carboxymethyl) [3- (coconut oil amido)r)ropyl]dimethyl-
ammonium hydroxide, inner salt.
(l-Carboxyundecyl)trimethylammonium hydroxide, inner
salt.
N-(Coconut oil alkyl)-6-alanine, sodium salt
N-(Coconut oil alkyl)-6-alanine , partial sodium salt--
3-[ (Coconut oil alkyl)amino]butyric acid, sodium
salt.
N-(2-Coconut oil ajnidoethyl)-N-(2-hydroxyethyl)-
glycine, sodium salt.
N-(Dodecyl and tetradecyl)-8-alanine
N-(Dodecyl and tetradecyl)-6-alanine, triethanolamine
salt.
N-Dodecyl-3-iminodipropionic acid
N-Dodecyl-3-iminodipropionic acid, disodium salt
Mixed acyclic primary amines, ethoxylated and
sulfated, sodium salt.
(Mixed alkyDsulfobetaine
Mixed fatty betaines
Oleic acid - ethylenediamine condensate, propoxylated
and sulfated, sodium salt.
N'-(Tallow alkyl)-3-iminodipropionic acid, disodium
salt.
All other acyclic
Cyclic:
1 , 1-Bis (carboxymethyl) -2-undecyl-2-imidazoliniura
hydroxide, disodium salt.
l-Carboxymethyl-2-heptadecyl-l- (2-hydroxyethyl) -2-
imidazolinium hydroxide, sodium derivative, sodium
salt.
l-Carbox^ethyl-l- (2-hydroxyethyl) -2-nonyl-2-imid-
azolinium hydroxide, sodium derivative, sodium
salt.
l-Carboxymethyl-l-(2-hydroxyethyl)-2-imdecyl-2-
imidazolinium hydroxide, sodium derivative,
sodium salt.
Heptadecylmethylbenzimidazolinesulfonic acid,
sodium salt .
3- [2- (2-Undecyl-2-imidazolin-l-yl}ethoxy] -propionic
acid, sodium salt.
DUP.
DUP.
VAC .
DUP.
CNM, VAC.
GNU.
ARC.
GNU.
GNM.
GNU.
GNM.
RH.
DUP,
TXT.
TXT.
S.
FNX,
GNfl.
SEY,
X.
MIR,
live.
MIR,
m'c.
MIR, TCII, UVC, VAC.
CGY.
UVC.
SYNTHETIC ORGANIC CHEMICALS. 1972-
TABLE 2. --Surface-active agents for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
Anionic; Surface-Active Agents
*Carboxylic acids (and salts thereof):
*Amine salts of fatty, rosin, and tall oil acids:
Coconut oil acids, diethanolamine salt
Coconut oil acids, triethanolainine salt
Laurie, myristic, palmitic, and stearic acids, tri-
ethanolamine salt.
Oleic acid, n-butylamine salt
Oleic acid, triethanolainine salt
Stearic acid, N,N,N',N'-tetrakis (2-hydroxyethyl) -
ethylenediamine salt.
Stearic acid, triethanolainine salt
Tall oil acids, diethanolamine salt
Tallow acids, triethanolamine salt
*Carboxylic acids having amide, ester, or ether
linkages :
Butoxyethoxypropi oni c aci d
N-CCoconut oil acyl)sarcosine, sodium salt
Diisobutylene - maleic anhydride copolymer,
ammonium and sodium salts.
Epoxidized oleic acid, ammonium salt
*N-Lauroylsarcosine , sodium salt
N-(Mixed alkylsulfonyl) glycine , sodium salt
N-Oleoylpolypeptide, sodium salt
N-Oleoylsarcosine, sodium salt
Phthalic acid, octadecyl ester, potassium salt
Stearoyl-2-lactylic acid
Tridecyloxypoly(ethyleneoxy) acetic acid, sodium
salt.
Unspecified sarcosine derivatives
All other
*Potassium and sodium salts of fatty, rosin, and
tall oil acids:
Animal grease, sodium salt
*Castor oil acid, potassium salt
Castor oil acid, sodium salt
Cocoa butter acids, sodium salt
*Coconut oil acids, potassium and sodium salts:
*Potassiura salt
*Sodium salt
Coconut oil and tallow acids, sodium salt
*Com oil acids, potassium and sodium salts:
Potassium salt
Sodium salt ,
Laurie acid, potassium salt
Laurie and myristic acids
Mixed fish oil acids, sodium salt
*Mixed vegetable oil acids, potassium salt
Oleic acid, potassium salt
*01eic acid, sodium salt
Olive oil acids, sodium salt
Palm kernel acids, sodium salt
*Palm oil acids, sodium salt
Peanut oil acids, potassium salt
Peanut oil acids, sodium salt
Rosin acids, potassium salt
Rosin acids, sodium salt
SOP.
SEP.
SEP.
GLY.
ACE, SOP.
SEP.
WC.
FfflP.
m.
SCP.
CP, IfllP, ONX.
GAP.
LUI, X.
GAP.
CGY.
GLY.
lA'C.
IIHP.
NMC.
NTL, PEK, SEA.
HEW, HRV, NTL.
HEW.
ACE, AES, CON, DA, DYS. ESS, GRC, GRL, HEW, HNT,
JRG, MCP, NUC, PCH, PEK, PC, SOP, VAL.
AGP, CON, CP, GRC, HEW, JRG, LEV, NMC, NPR, PG.
BSW.
GRC,
GRC,
USR.
PG.
DA.
AES,
AES,
BSW,
HEW.
NMC.
HEW,
KAL,
NMC.
USR,
CRT,
HNT, NMC.
NMC.
DYS, GRC, GRL, LUR, PCH, PEK.
ARL,, DA, DAN, GYR, HNT, SCP, SNW, USR, WEG.
DA, LEV, LUR, MRV, NUC, USR, WBG, IVTC.
HNT, LUR.
LUR, NMC, PRX.
SLC.
PRX, SLM, X.
SURFACE-ACTIVE AGENTS
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
Anionic Surfaae- Active Agents — Continued
*Carboxylic acids (and salts thereof) --Continued
'Potassium and sodium salts of fatty, rosin, and
tall oil acids--Continued
'Soybean oil acids, potassium and sodium salts:
Potassium salt
Sodium salt
'Stearic acid, potassium and sodium salts:
Stearic acid, potassium salt
Stearic acid, sodium salt
•Tall oil acids, potassium salt
*Tall oil acids, sodium salt
Tallow acids, potassium salt
'Tallow acids, sodium salt
All other
'Phosphoric and polyphosphoric acid esters (and salts
thereof) :
'Alcohols and phenols, ethoxylated and phosphated:
Butyl alcohol, ethoxylated and phosphated
'Dinonylphenol, ethoxylated and phosphated
Dodecyl alcohol, ethoxylated and phosphated
Dodecylphenol , ethoxylated and phosphated
2-Ethylhexanol , ethoxylated and phosphated
Hexylphenol, ethoxylated and phosphated
Iso-pentyl alcohol, ethoxylated and phosphated
'Mixed linear alcohols, ethoxylated and phosphated--
'Nonylphenol, ethoxylated and phosphated
Nonylphenol , ethoxylated and phosphated, barium
salt.
9-Octadecenyl alcohol, ethoxylated and phosphated--
9-Octadecyl alcohol, ethoxylated and phosnhated
Octylphenol, ethoxylated and phosphated
Octylphenol, ethoxylated and phosnhated. magnesium
salt.
'Phenol, ethoxylated and phosphated
Polyhydric alcohol, ethoxylated and phosphated
'Tridecyl alcohol, ethoxylated and phosphated
All other
'Alcohols, phosphated or polyphosphated:
Decyl, dodecyl, and octyl phosphate, morpholine
salt.
Decyl and octyl phosphate
Decyl polyphosphate, sodium salt
2-Ethylhexyl phosphate
*2-Ethylhexyl phosphate, sodium salt
2-Ethylhexyl phosphate, triethanolamine salt
2-Ethylhexyl polyphosphate
2-Ethylhexyl polyphosphate, sodium salt
Hexyl phosphate
Hexyl phosphate, potassium salt
Hexyl polyphosphate, potassium salt
Isooctyl phosphate
Mixed alkyl phosphate
Mixed alkyl phosphate, diethanolamine salt
9-Octadecenyl phosphate
CON, DYS, HEW, PCH.
HEW, NHC.
CON, DYS, HEW, SCO, IJSR, WTC.
DA, HEW, JRG, IVTC.
AES, ASY, CON, DYS, ESS, GAP, GRC, GYR, HNT, NMC,
PEK, PNX, SOP, VAL, x.
ASY, CON, GRC, GYR, MRV, PRX, SOP, UNP, x.
AES, ASY, GYR, PG, USR.
AGP, ASY, BSW, CON, CP, DA, GRC, GYR, HEW, JRG,
LEV. LUR, NflC, NPR, PG, PRX.
GYR.
GAP.
ARL, GAP
NLC, TXT, WTC.
GAP, WIG
IVTC.
GAP.
FNX, WAY
ICI.
GAP.
CHP, CRT
CST, FNX, GAP, TCH, TXT, WTC,
WYN.
ARL, CHP,
CRT, DEX, GAP, HDG, NLC, SCP,
SEY, SNW
SOP, TCC, TXN, TXT, VAC, WAY, WTC.
GAP.
GAP.
GAP.
ARL, Rll,
WAY.
FNX, GAP,
WTC, X.
NLC.
ARL, FNX
GAP, LUR, NLC, TCC, WAY, WTC.
GAP, WTC
DUP,
WTC.
WAY.
CHP,
SYL.
TCC,
X.
ICI.
ICI.
DEX.
GAF.
CST,
DUP.
DUP.
PNX, GAF, MRA, SEY, UCC, UVC.
UVC, X.
DUP, SFS, TCC.
SYNTHETIC ORGANIC CHEMICALS. 1972.
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
Anionic Surface- Active Agents — Continued
*Phosphoric and polyphosphoric acid esters (and salts
thereof) - -Continued
♦Alcohols, phosphated or polyphosphated--Continued
Octyl phosphate
Octyl phosphate, alkylamine salt
Octyl phosphate, potassium salt
Octyl polyphosphate
Octyl polyphosphate, potassium salt
All other
♦Sulfonic acids (and salts thereof) :
*Alkylbenzenesulfonates:
Dodecylbenzenesulfonates :
*Dodecylbenzenesulfonic acid
Dodecylbenzenesulfonic acid, ammonium salt
Dodecylhenzenesulfonic acid, butylamine salt
♦Dodecylbenzenesulfonic acid, calcium salt
Dodecylbenzenesulfonic acid, diethanolamine salt-
Dodecylbenzenesulfonic acid, dimethylamine salt--
Dodecylbenzenesulfonic acid, ethylenediamne
salt.
Dodecylbenzenesulfonic acid, isopropanolamine
salt.
♦Dodecylbenzenesulfonic acid, isopropyl amine salt-
♦Dodecylbenzenesulfonic acid, (mixed alkyl)amine
salt.
Dodecylbenzenesulfonic acid, potassium salt
♦Dodecylbenzenesulfonic acid, sodium salt
♦Dodecylbenzenesulfonic acid, triethanolamine
salt.
Other alkylbenzenesulfonates :
Decylbenzenesulfonic acid, sodium salt
Di dodecylbenzenesulfonic acid
Didodecylbenzenesulfonic acid, sodium salt
Pentadecylbenzenesulfonic acid, potassium salt-
Tridecylbenzenesulfonic acid
♦Tridecylbenzenesulfonic acid, sodium salt
Undecylbenzenesulfonic acid
Undecylbenzenesulfonic acid, ammonium salt
Undecylbenzenesulfonic acid, sodium salt
Undecylbenzenesulfonic acid, triethanolamine
salt.
All other
♦Benzene-, cumene- , toluene-, and xylenesulfonates:
Benzenesulfonic acid, sodium salt
♦Cumenesulfonic acid, ammonium salt
Cumenesulfonic acid, sodium salt
Hydroquinonesulfonic acid, potassium salt
Toluenesulfonic acid
Toluenesulfonic acid, potassium salt
Toluenesulfonic acid, sodium salt
Xylenesulfonic acid
TXT.
DUP, NLC, TXT.
DUP, SN'W.
DEX.
X.
DUP, TCH, X.
ACS, ATR, CO, CRT, CTL, EMK, FNX, HLI, ICI, LAK,
LEV, PIL, PLX, PRX, RCD, STP, TCI, TEN, TXT, WTC.
ARL, FNX, TXN, IVTC.
IVTC.
ICI, NLC, RCD, RH, STP, TMI), IVTC.
FNX, l^fTC.
PIL.
ICI.
ARD, CTL, l*TC.
AAC, CHP, CIN, CTL, FNX, ICI, RCD, SNW, STP.
ECC, FNX, NLC, TCH, IVTC.
RCD, SOP, STP, VAL.
AAC, ACS, ARD, ARL, ATR, BLA, CHP, CO, CP, CRT,
CTL, DA, ECC, HLI, HRT, LEV, NMC, PG, PIL, PLX,
PRX, QCP, RCD, SOP, STP, TEN, TXT, UCC, WTC.
AAC, ACS, ARD, ARL, ATR, CIN, CTL, ECC, ESS, FNX, HLI,
PIL, RCD, SOP, SOS, STP, TXN, WTC.
LAK.
CO.
ATR.
STP.
CO, RCD.
BLA, CO, CP, NPR, PG, RCD, IVTC.
TXT.
TXT.
TXT.
TXT.
LISR.
NES.
NES, PRX, STP, IVTC.
NES.
NES.
RCD.
NES, STP, TXN.
CO, NES, PRX, iirrc.
HLI.
SURFACE-ACTIVE AGENTS
TABLE 2.-
-Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
Anionic Surface-Active Agents — Continued
*Sulfonic acids (and salts thereof) --Continued
*Ben2ene-, cumene-, toluene-, and xylenesulfonates —
Continued
*Xylenesulfonic acid, ammonium salt
Xylenesulfonic acid, potassium salt
*Xylenesulfonic acid, sodium salt
*Ligninsulfonates :
Ligninsulfonic acid, aluminum salt
Ligninsulfonic acid, ammonium salt
*Ligninsulfonic acid, calcium salt
Ligninsulfonic acid, chromium salt
Ligninsulfonic acid, copper salt
Ligninsulfonic acid, iron salt
Ligninsulfonic acid, magnesium salt
Ligninsulfonic acid, manganeses salt
*Ligninsulfonic acid, sodium salt
Ligninsulfonic acid, zinc salt
All other
*Naphthalenesulfonates :
*Butylnaphthalenesulfonic acid, sodium salt
Dibutylnaphthalenesulfonic acid
Didodecylnaphthalenesulfonic acid, sodium salt
Diisopropylnaphthalenesulfonic acid, sodium salt
Dipentylnaphthalenesulfonic acid, (mixed alkyl)-
amine salt.
Dipentylnaphthalenesulfonic acid, sodium salt
I sop ropy In aphthalene sulfonic acid
Methylenebis (2 -naphthalene sulfonic acid)
Methylnaphthalenesulfonic acid, soditim salt
Methylnonylnaphthalenesulfonic acid, sodium salt
Tetrahydronaphthalenesulfonic acid, sodium salt
*Sulfonic acids having amide linkages:
*Sulfosuccinic acid derivatives:
N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuccinamic
acid, tetrasodium salt.
N-(2-Hydroxyethyl)-N- (tallow alkyl)sulfo-
succinamic acid, disodium salt.
N-Octadecylsulfosuccinamic acid, disodium salt
Sulfosuccinic acid, alkanolamide ester, sodium
salt.
Sulfosuccinic acid, alkanolamide ester, tri-
ethanolamine salt.
Sulfosuccinic acid, 2- (coconut oil amido)ethyl
ester, disodium salt.
All other
*Taurine derivatives;
N-(Coconut oil acyl)-N-methyltaurine, sodium salt-
N-Cyclohexyl-N-palmitoyltaurine , sodium salt
N-Methyl-N-oleoyltaurine, sodium salt
N-Methyl-N-palmitoyltaurine, sodium salt
N-Methyl-N- (tall oil acyl) taurine , sodium salt
N-!lethyl-N- (tallow acyl) taurine, sodium salt
*Sulfonic acids having ester or ether linkages:
*Sulfosuccinic acid esters:
*Sulfossuccinic acid, bis (2 ,6-dimethyl-4-heptyl)
ester, sodium salt.
'Sulfosuccinic acid, bis (2-ethylhexyl) ester,
sodium salt.
CO,
HLI,
NES,
STP,
TXN,
WTC.
NES
AIR
CO,
HLI,
ICI,
NES,
PIL,
MAR
CPP
CRZ
SPA
WV'A
CRZ
CWP
LKY
MAR
PSP
WVA
MAR
RAY
IWA
CRZ
m'A
MAR
W\'A
IWA
CRZ
MAR
RAY
IWA
IWA
PSP
DA,
ECC,
PFZ.
GAP
S.
PFZ
DA,
GAP,
PFZ.
DA,
DUP,
GRD.
DUP
DA,
UDI.
LIDI
DUP
ACY,
MOA
SCP
ACY
HDG
SCP
SCP
LAK
ACT
FNX
GAF
LIL
TNI
GAF
DA,
DEP,
FNX,
GAF,
HRT, MCP.
GAF
CRT
FNX
GAF
MRA
WTC.
GAF
D/\N, GAF, MOA.
ACY, CGY, CUP, CRT, CST, DA, DAN, ECC, EMK, FNX, HDG,
HRT, MCP, MOA, MRA, PC, SBC, SCO, UVC .
552-743 0-74-12
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2, --Surface-active agents for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers' identification codes
Chemical
(accordi
ng to list in table 3)
Anionic Surface- Active Agents — Continued
♦Sulfonic acids (and salts thereof) --Continued
'Sulfonic acids having ester or ether linkages--
Continued
*Sulfosuccinic acid esters--Continued
Sulfosuccinic acid, bis (tallow monoglyceride)
ACY.
ester, sodium salt.
Sulfosuccinic acid, dihexyl ester, sodium salt
ACY,
MOA
Sulfosuccinic acid, diisobutyl ester, sodium
MOA.
salt.
Sulfosuccinic acid, diisodecyl ester, sodium
MCP.
salt.
Sulfosuccinic acid, diisooctyl ester, sodium
RH.
salt.
Sulfosuccinic acid, dipentyl ester, sodium salt
ACY.
Sulfosuccinic acid, ditridecyl ester, sodium
ACY,
MOA
salt.
*Other sulfonic acids having ester or ether
linkages :
Coconut oil acids, 2-sulfoethyl ester, sodium
GAF,
LEV
X.
salt.
Dodecyldiphenyloxidedisulfonic acid, disodium
DOW.
salt.
ACS.
uoaecy 1 suiroacetate
Dodecyl sulfoacetate, sodium salt
SIP.
SLfl
Herring oil, suironateu
Iso-octylphenol, ethoxylated and sulfonated.
CRT,
RH.
sodium salt.
SLM.
All other
*A11 other sulfonic acids:
Butylhydroxybiphenylsulfonic acid
RBC.
Mixed alkanesulfonic acid, sodium salt
DUP.
CP
LAK,
NLC, STP.
Mixed linear aipna oienns, suironateci
Petroleumsulfonic acid, water soluble (acid layer),
WTC.
sodium salt.
All other
•Sulfuric acid esters (and salts thereof):
*Acids, amides, and esters, sulfated:
•Coconut oil acids - ethanolamine condensate.
DEX,
B1K
ONX.
sulfated, potassium salt.
•Esters of sulfated oleic acid:
2-Butoxyethyl oleate, sulfated, sodium salt
S.
Butyl and propyl oleate, sulfated, sodium salt
^ICP.
•Butyl oleate, sulfated, sodium salt
AKS,
EFH
ICI, MCP,
ONX, PC, SEY.
2-Ethylhexyl oleate, sulfated, sodium salt
CHP.
£^]-jyj oleate sulfated sodium salt
GAF.
LEA,
Glyceryl trioleate, sulfated, sodium salt
MRV
Isobutyl oleate, sulfated, sodium salt
DA.
•Isopropyl oleate, sulfated, sodium salt
CRT,
DEX
FNX, HRT,
LEA, SCP.
Methyl oleate, sulfated, sodium salt
ICI.
Mixed oleic acid esters, sulfated, sodium salt
EFH.
♦Propyl oleate, sulfated, sodium salt
ACY,
AKS,
CHP, MRV.
•Oleic acid, sulfated, disodium salt
ACT,
ACY
CHP, CRT,
DA, GAF, LEA, SCO, TEN, IVTC.
Other acids, amides, and esters, sulfated:
Castor oil and oleic acid, sulfated, ammonium salt-
sen.
Glycerol monoester of coconut oil acids, sulfated
CP.
sodium salt.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972— CONT INUED
Manufacturers' identification codes
(according to list in table 3)
Anionic Surface- Ac live Agents — Continued
'Sulfuric acid esters (and salts thereof)--Continued
*Acid5, amides, and esters, sulfated--Continued
*Other acids, amides, and esters sulfated--Continued
9-Octadecenyl acetate, sulfated, sodium salt
Oleic acid, sulfated, triethanolamine salt
Tall oil, sulfated, sodium salt
All other
'Alcohols, sulfated:
Coconut and sperm oil alkyl sulfate, sodium salt
Decyl and octyl sulfate, sodium salt
♦Decyl sulfate, sodium salt
3,9-Diethyl-6-tridecyl sulfate, sodium salt
*Dodecyl sulfate salts:
2-Amino-2-methylpropanol salt
'Ammonium salt
Diethanol amine salt
Diethylamine salt
N,N-Diethylcyclohexylamine salt
Isopropanolamine salt
'Magnesium salt
Potassium salt
'Sodium salt
'Triethanolamine salt
2-Ethylhexyl sulfate, sodium salt
Hexadecyl sulfate, sodium salt
7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt
Hexyl sulfate, potassium salt
Mixed linear alcohol sulfate, ammonium salt
Mixed linear alcohol sulfate, sodium salt
Mixed linear alcohol sulfate, triethanolamine
salt.
Nonyl sulfate, sodium salt
9-Octadecenyl sulfate, 2- (diethylamino)ethanol salt-
Octadecyl sulfate, sodium salt
Octadecyl sulfate, triethanolamine salt
Octyl sulfate, sodium salt
Tridecyl sulfate, sodium salt
All other
'Ethers, sulfated:
'Alkylphenols, ethoxylated and sulfated:
Nonylphenol, ethoxylated and sulfated, ammonium
salt.
'Nonylphenol, ethoxylated and sulfated, sodium
salt.
Nonylphenol, ethoxylated and sulfated, tri-
ethanolamine salt.
Octylphenol, ethoxylated and sulfated, sodium
salt.
'Dodecyl alcohol, ethoxylated and sulfated, ammonium
salt.
'Dodecyl alcohol, ethoxylated and sulfated, sodium
salt.
Dodecyl and tetradecyl alcohols, ethoxylated and
sulfated, ammonium salt.
2-Ethylhexanol, ethoxylated and sulfated, sodium
salt.
2-Hexyloxypropyl sulfate, sodium salt
'Mixed linear alcohols, ethoxylated and sulfated
ammonium salt.
'Mixed linear alcohols, ethoxylated and sulfated,
sodium salt.
DUP.
KAY.
APX, BAO, DA, FNX, ICI, SEA, Iffll , IVHW.
DA, eiR.
DA, DUP, FNX.
TCH, IVTC.
APX, CTL, DUP, HLl, SCP.
UCC.
DUP.
AAC, CTL, HLI, JRG, ONX, PG, RCD, SCP, STP, TCH, WTC.
DUP, HLl, JRG, ONX, SCP, STP.
AAC.
DUP.
JRG, TCH.
AAC, HLI, ONX, STP.
GYR, HLl, PG.
AAC, CTL, DUP, HLI, JRG, ONX, PG, RCD, SCP, STP, TCH,
WTC.
AAC, CTL, DUP, HLI, ONX, PG, RCD, SCP, STP, TCH, TXT.
AAC, SCP, TCH. UCC.
AAC, DUP, SCP.
UCC.
DEX.
CP, LAK, NTL, S, SCP, UCC.
LAK, SCP, SEY, TXT.
LAK, SCP.
TEN, TXT.
AAC.
DUP, EHK, ONX, PG.
DUP.
AAC, DUP.
AAC, SCP.
LEV.
CGY, GAP, .STP, TXT, WTC.
CRT, DEX, GAF.
ARL.
RH.
AAC, AKS, CTL, STP, TXT, WTC.
AAC, CTL, HLI, ONX, RCD, SCP, STP, TCH, IVTC.
LEV, TXN.
UCC.
S.
CO, LAK, NLC, PG, PIL, RCD, SCP, SHC, STP, TXT.
AAC, CO, DA, LAK, PG, PIL, RCD, SCP, SHC, STP,
TCI, TXT.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2, --Surface-active agents for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers '
identification codes
Chemical
(according to list in table 3)
Anionic Surface-Aative Agents — Continued
♦Sulfuric acid esters (and salts thereof) — Continued
♦Ethers, 5ulfated--Continued
Sperm oil alcohol, ethoxylated and sulfated,
DUP,
WAW
sodium salt.
Tridecyl alcohol, ethoxylated and sulfated, sodium
AAC,
ARL
PRX, RCD.
salt.
All other
DUP.
♦Natural fats and oils, sulfated:
•Castor oil, sulfated, sodium salt
ACT,
ACY
AKS, APX, ARL
BAO, BSW, CRT, DA, DEX, EFH,
FNX, GAP, HRT, ICl, KAL, KNG, LEA, LUR, MCP, MRD,
MRV, S
SCO, SCP, SLC
SLM, WHI, WHIM.
♦Coconut oil, sulfated, sodium salt
ACY,
BAG
DA, LUR, MRD,
SEA, SLC, IVHW.
♦Cod oil, sulfated, sodium salt
ACT,
BAO
SEA, IVHI, WHIV
Grease, other than wool, sulfated, sodium salt
SEA,
mil
Herring oil, sulfated, ammonium salt
SCP.
♦Herring oil, sulfated, sodium salt
ACT,
DA,
SLM, WHI, IVHW.
♦Lard, sulfated, sodium salt
CRT,
FNX
SLM, WAW.
Mixed alpha olefins and vegetable oils, sulfated.
SLM.
sodium salt.
Mixed animal and vegetable oils, sulfated, sodium
SLU.
salt.
♦Mixed fish oils, sulfated, sodium salt
ACT,
DA,
MRD, SLM.
Mustard seed oil, sulfated, sodium salt
DA,
LUR.
♦Neat's-foot oil, sulfated, sodium salt
ACT,
BAO
CRT, DA, KAL,
LUR, MRD, PC, SEA, SLM, WHW.
♦Peanut oil, sulfated, sodium salt
ACY,
CUP
DA, LEA, LUR.
♦Ricebran oil, sulfated, sodium salt
DA,
EFH,
KNG, LUR, SEA,
WHI.
♦Soybean oil, sulfated, sodium salt
CRT,
HRT
KAL, MRD, ONX
WHW.
♦Sperm oil, sulfated, sodium salt
ACT,
CLD
CRT, DA, FNX,
KAL, ONX, SCO, SEA, WHI, WHW.
♦Tallow, sulfated, sodium salt
ACT,
ACY,
BSW, DA, ECC,
LUR, MCP, MRD, PC, SCP, SID,
SLM, SnS, IVHI.
Other anionic surface-active agents:
Lignin (non-sulfonated) and salts thereof
1*VA.
Mixed linear alcohols, ethoxylated and carbonated.
S.
sodium salt.
Polyethylene-vinyl alcohol copolymer, potassium salt
NLC.
Tridecyl alcohol, ethoxylated and carbonated.
S, SEY.
sodium salt.
All other
QCP,
STC
Cationia Surface- Active Agents
♦Amine oxides and oxygen- containing amines (except
those having amide linkages):
♦Acyclic:
N,N-Bis(2-hydroxyethyl) (coconut oil alkyl) amine
ARC.
oxide.
CTL.
.ARC,
FIN
TCH.
N N-Bis (2-hydroxyethyl) f tal low alkvDamine
ARC.
N,N-Bis(2-hydroxyethylKtallow alkyl)amine acetate---
PG.
N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine oxide
ARC.
AAC,
ARC,
ASH, BRD, ICI
NLC, TCH, VAC.
(Coconut oil alkyl)amine, ethoxylated, acetate
RPC.
(Coconut oil alkyl) amine, ethoxylated, maleate
SDH.
N,N-Dimethyl(coconut oil alkyl)amine oxide
ARC.
N,N-Dimethyldecylamine oxide
BRD.
N,N-Dimethyldodecylaraine oxide (Lauryl dimethylamine
BRD,
X.
oxide) .
N,N-Dimethylhexadecyl amine oxide
ONX.
N,N-Dimethyl(hydrogenated tallow alkyl)amine oxide —
ARC.
Ethylenedi amine, ethoxylated and propoxylated
ICI.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER. 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
Catiowic Sui' face- Active Agents — Continued
*Amine oxides and oxygen-containing amines (except those
having amide linkages) --Continued
*Acyclic- -Continued
(Hydrogenated tallow alkyl) ajnine, ethoxylated
N-(2-Hydroxyethyl)-N,N' ,N' -tris (2-hydroxypropyl) -
ethylenediamine .
N- (2-Hydroxyethyl1-N,N' ,N' -tris (2-hydroxypropyl) -
ethylenediamine distearate, methyl sulfate.
(Mixed alkyl)amine, ethoxylated
(Mixed alkyl)poly (oxye thy lene) amine
Mixed substituted oximes
(9-Octadecenyl) amine , ethoxylated
Octadecyl amine, ethoxylated
Po lye thy lenepoly amine , alkoxylated
(Soybean oil alkyl)amine, ethoxylated
*(Tallow alkyl)amine, ethoxylated
Tallow alkyl amine ethoxylated, sulfate
N-(Tallow alkyl) trimethylenediamine, ethoxylated
N,N,N' ,N'-Tetrakis (2-hydroxye thy 1) ethylenediamine —
N,N,N' ,N'-Tetrakis (2-hydroxypropyl) ethylenediamine
dioleate , methyl sulfate.
N,N,N' ,N'-Tetrakis (2-hydrox\'propy 1) ethyl enedi amine ,
propoxylated and ethoxylated.
Triethanol amine , ethoxylated
All other
*Cyclic (except imidazoline and oxazoline derivatives) :
Aniline and m-toluidine , ethoxylated
Lignin amine
Rosin amine, ethoxylated
Imidazoline and oxazoline derivatives:
2- (8-Heptadecenyl)-4,4-bis(hydroxymethyl)-2-
oxazoline.
2-(8-Heptadecenyl)-l- (2-hydroxyethyl) -2-
imidazoline.
2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2-
oxazoline.
*2-(Heptadecyl)-l- (2 -Hydro xye thy 1) -2- imidazoline
*l-(2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2-
imidazoline.
*l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2-
imidazoline.
l-(2-Hydroxyethyl)-2-tridecyl-2-imidazoline
hydrochloride.
2-Hydrox\Tpropyl imidazoline
*Amines and amine oxides having amide linkages:
*Carboxylic acids - diamine and polyamine condensates:
Caprylic acid - tetraethylenepentamine condensate —
Coconut oil acids - diethylenetri amine condensate —
Coconut oil acids - N,N-dimethyltrimethylene-
diamine condensate.
Mixed dicarboxylic acids - polyalkylenepolyamine
condensate.
*Mixed fatty acids - polyalkylenepolyamine
condensate.
Oleic acid - 1- (2-aminoethyl)piperazine condensate--
Oleic acid - diethylenetriamine condensate
Oleic acid - N,N-dimethyltrimethylenediaraine
condensate.
Pelargonic acid - tetraethylenepentamine
condensate .
Stearic acid, diethanolamine condensate,
methyl sulfate.
Stearic acid - diethylenetriamine condensate
Stearic acid - N,N-diethylethylenediamine
condensate.
CGY,
NLC.
CGY,
DA,
GAP,
ICI, RH, T
GAP.
GNM.
ARC,
DA,
TCH.
ARC,
TCH
NLC,
TCH
.ARC,
VAC
ARC,
CGY
DUP
GAP, TCH.
DUP.
ARC,
IVTC
NLC.
DUP.
ARC,
IVTC
IVYN
TCH.
ARC,
GLY
SCP
TCH.
IWA.
HPC,
NLC
WTC
DA,
ONX,
UVC.
CGY,
COM,
uvc.
CGY,
CHP,
MOA,
UVC.
CGY,
HOA,
UVC.
HDG,
MOA,
NLC,
TCH, UVC.
CGY,
IVTC.
TCH.
ICI.
APX,
TXT.
JRG,
TXT
IVTC.
TXT.
GRD.
NLC,
QCP.
TCH.
TXT.
ICI,
TXT.
CCW.
ICI
DUP.
CHP,
CST,
PNX,
ONX, S.
CGY,
S.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Surface-active agents for which U.S, production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
Cationic Surface- Active Agents — Continued
♦Amines and amine oxides having amide linkages — Continued
*Carboxylic acids - diamine and polyamine condensates--
Continued
Stearic acid - tetraethylenepentamine condensate
*Tall oil acids - diethylenetriamine and
polyalkylene polyamine condensates :
Tall oil acids - diethylenetriamine condensate
Tall oil acids - polyalkylenepolyamine condensate-
All other
Other amines and amine oxides having amide linkages:
Coconut oil acids - diethylenetriamine condensate,
po lye th oxy 1 at ed .
3-Lauramido-N,N-dimethylpropylamine oxide
Mixed fatty acids - alky lenedi amine condensate,
polyethoxylated.
Oleic acid - ethy lenedi amine condensate, mono-
ethoxylated.
Palm oil acids - ethylenediamine condensate, mono-
ethoxylated.
Rosinpolyamidoimidazoline
Stearic acid - diethylenetriamine condensate, poly-
ethoxylated.
♦Stearic acid - ethylenediamine condensate, mono-
ethoxylated.
Stearic acid - ethylenediamine condensate, poly-
ethoxylated.
Tall oil acids - ethylenediamine condensate,
monoethoxylated.
♦Amines, not containing oxygen [and salts thereof):
♦Amine salts :
(Coconut oil alkyl)amine acetate
(Hydrogenated tallow alkyl)amine acetate
(9-Octadecenyl) amine acetate
Octadecyl amine acetate
(Tallow alkyl)amine acetate
N- (Tallow alkyl)trimethylenediamine acetate
N- (Tallow alkyl)trimethylenedianiine oleate
N- (Tallow alkyl)trimethylenediamine tallate
All other
♦Diamines and polyamines :
♦N- (Coconut oil alkyl)trimethylenediamine
N-(Docosyl- and eicosyl) trimethylenediaraine
♦Imidazoline derivatives:
1- [3-(2-Aminoethyl)naphth-l-yl]-2-(8-hepta-
decenyl) -2- imidazoline.
l-(2-Aminoethyl)-2-nor(tall oil alkyl)-2-
imidazoline.
2-Heptadecy 1-2- imidazoline
Tall oil imidazoline
N- (Mixed alkyljpolyethylenepolyamine
♦N- (9-Octadecenyl) trimethylenediamine
N- (Soybean oil alkyl) trimethylenediamine
N-(Tall oil alkyl)trimenthylenediamine
N- (Tallow alky l)dipropylenetri amine
N- (Tallow alkyl) trimethylenediamine
♦Primary monoamines :
(Coconut oil alkyl)amine
Dodecyl amine
Docosyl- and eicosylamine
Hexadecylaraine
♦(Hydrogenated tallow alkyl)araine
(Mixed alkyl) amine
(Mixed tert- alkyl) amine
AZS,
DA, FNX, NCW,
NLC,
RTF,
WTC
AZS,
QCP, OTC.
NLC,
VND.
SNW.
GAP.
CLD, DA, DEX, SnC , TNA.
APX.
WC.
TCC.
CST, DA, DEX, ICI, MRV, S, SCP.
ICI.
SCP.
ARC, IVTC.
ARC, ASH.
GNM.
ACY, ARC.
ARC.
ARC, ASH.
ARC, ASH.
ARC.
SM
ARC, ENO, GNM.
END.
NLC, UVC, IVTC.
BIR, SCO.
AZS.
CCW.
ARC, ASH, GNM.
ENO.
ARC.
ARC, GNfl.
ARC, ASH, ENO, GNM.
ARC, ENO, GNM.
ARC, ASH, GNM.
ENO.
ARC, ENO.
ARC, ASH, ENO, GNM.
ARC.
RH.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
Cationia Surface- Active Agents- -Contimied
•Amines, not containing oxygen (and salts thereof) --
Continued
'Primary monoamines:
*9 -Oct adecenyl amine
*Octadecyl amine
Octylamine
tert-Octylamine
(Soybean oil alkyljamine
(Tall oil alkyDamine
'(Tallow alkyl) amine
'Secondary and tertiary monoamines:
Bis (coconut oil alkyl)amine
'Bis (hydrogenated tallow alkyl)amine
N,N-Dimethyl (coconut oil alkyl)amine
N,N-Dirae thy Idecyl amine
N,N-Dimethyl (Docosyl- and eicosyl)amine
*N,N- Dime thy Idodecyl amine
*N, N- Dime thy Ihexadecyl amine
N,N-Dimethyl (hydrogenated tallow alkyl) amine
N,N- Dimethyl (mixed alkyl) amine
*N, N- Dime thy loctadecyl amine
N,N- Dimethyl octylamine
N,N-Dimethyl (soybean oil alkyl)amine
N,N-Dirae thy Itetradecyl amine
N-Methylbis (coconut oil alkyl)amine
*N-Methy Ibis (hydrogenated tallow alkyl)amine
N -Me thy Idi Oct adecyl amine
Trioctyl amine
'Oxygen-containing quaternary ammonium salts:
Quaternary ammonium salts having amide linkages:
Ethyldimethyl ( 3-pe 1 agonamidop ropy 1) ammonium
ethyl sulfate.
(2-Hydroxyethyl) dimethyl (3-stearamidop ropy 1)-
ammonium dihydrogen phosphate.
(2-Hydroxyethyl)dimethyl (3-stearamidopropyl) -
ammonium nitrate.
( 3- Lauramidopropyl)trimethyl ammonium methyl
sulfate.
2- (2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium
chloride.
Tall oil acid - polyalkylenepolyamine condensate,
quaternary sulfate.
Trimethyl (3-oleamidopropyl)ammonium methyl
sulfate .
All other
Other oxygen-containing quaternary ammonium salts:
(2-Aminoethyl) ethyl (hydrogenated tallow alkyl) (2-
hydroxyethyl) ammonium ethyl sulfate.
Benzyl (coconut oil alkyl)bis (2-hydroxyethyl)-
ammonium chloride.
Benzyl (coconut oil alkyl, ethoxylated)dimethyl-
ammonium chloride.
l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl) -2-
imidazolinium chloride.
1-Benzyl-l- (2-hydroxyethyl)-2-nor(tall oil alkyl)-
2-imadazolinium chloride.
Bis(2-hydroxyethyl, ethoxylated) ethyl (hydrogenated
tallow alkyl) ammonium ethyl sulfate.
Bis (2-hydroxyethyl, ethoxylated)methyl(9-octa-
decenyl)ammonium chloride.
Bis (2-hydroxyethyl , ethoxylated)methyloctadecyl-
ammonium chloride.
ARC,
ASH,
ENO,
GNM.
ARC,
ASH,
ENO,
GNU.
ARC.
RH.
ARC,
ENO.
ASH,
nwL
ARC,
ASH,
ENO,
GNM.
ARC.
ARC,
ASH,
ENO.
ARC,
ASH,
BRD,
ENO.
BRD.
ENO.
ARC,
BRD,
ENO,
ONX.
ARC,
BRD,
ONX.
ARC,
ASH,
ENO.
ARC,
BRD,
ONX.
ARC,
ASH,
BRD,
ENO.
BRD.
ARC,
ENO.
ARC,
BRD,
ONX.
ENO,
GNH.
ARC,
ASH,
ENO,
GNM, SCO
ASH.
BRD,
GNU.
TCH.
ACY.
ACY.
ACY.
IVTC.
NLC.
CCY.
ARC,
X.
LUR.
CGY,
NLC.
GAF.
IWC.
NLC,
HOA.
ICI.
ARC.
ARC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
^lanufacturers ' identification codes
Chemical
(ac
cording to list in table 3)
Cationic Swff ace- Active Agents — Continued
*Oxygen-containing quaternary ammonium salts :--Continued
Other oxygen-containing quaternary ammonium
salts--Continued
(Coconut oil alkyl)bi5(2-hydroxyethyl, ethoxy-
ARC,
VAC.
lated)methylammonium chloride.
(Ethoxybeniy 1) dimethyl (octylphenoxy) ammonium
RH.
chloride.
(Ethoxybenzyl)dimethyl(octyltolyloxy') ammonium
RH.
chloride.
l-Ethyl-2-(8-heptadecenyl)-l- (2-hydroxyethyl)-2-
ICI,
UVC.
imidazolinium ethyl sulfate.
N-Ethyl-N-hexadecylmorpholinium ethyl sulfate
BRD,
ICI.
N-Ethyl-N- (soybean oil alkyl)morpholinium ethyl
ICI.
sulfate .
2-Hydroxytrimethylenebis[ (coconut oil alkyl]di-
CGY.
methyl ammonium chloride] .
TCC.
tjuaternari zed propoxyiatea stearyi amine
ARC.
(.juateman zea propoxyiatea taiiow aiamme
ARC.
Ail otner
'Quaternary ammonium salts, not containing oxygen:
*Acyclic:
*Bis(coconut oil alkyl)dimethylammonium chloride
ARC,
ASH,
END,
GNM, VAC.
Bi5(coconut oil alkyl)dimethylammonium nitrate
ARC.
*Bis(hydrogenated tallow alkyl)dimethylammonium
ARC,
ASH.
END,
GNM, VAC.
chloride.
Bis (hydrogenated tallow alkyl)dimethylammonium
PR.X.
methyl sulfate.
(Coconut oil alkyl)trimethylammonium chloride
ARC,
ASH.
Didecyldi methyl ammonium chloride
BRD.
Didodecyldimethylammonium bromide
ONX.
Dimethylbis (mixed alkyl) and trimethyl (mixed
GNfl.
alkyl)ammonium chloride.
Dimethylbis (9 -octadecenyl) ammonium chloride
GNM.
Dimethylbis (soybean oil alkyl) ammonium chloride
ARC.
Dime thy Idioctadecyl ammonium chloride
ASH,
ONX,
PG.
ON.X.
uimetnyiai octaaecyi ammonium metnyi suirate
Dioctyldimethyl ammonium chloride
BRD.
Dodecyltrimetliyl ammonium bromide
DUP.
Dodecyltrimethylammonium chloride
ARC,
CHP,
GNM,
WTC.
Ethyldimethyl (mixed alkyl)ammonium ethyl sulfate
DEX,
JOR,
TCC.
Ethyldime thy 1(9 -octadecenyl) ammonium bromide
ONX.
Ethylhexadecyldimethylammonium bromide
FIN.
Hexadecyl trimethyl ammonium bromide
DUP,
FIN.
♦Hexadecyl trimethyl ammonium chloride
ARC,
BRD,
VAC.
Hexadecyl trimethyl ammonium p-toluenesulfonate
FIN.
(Hydrogenated tallow alkyl) trimethylammonium
END.
chloride.
Me thyltrioctyl ammonium chloride
GNM.
N,N,N' ,N' ,N'-Pentamethyl-N-(tallow alkyl)tri-
ARC,
GNM.
methylenebis [ammonium chloride].
Trimethyl (mixed alkyl) ammonium chloride
NLC.
Trimethyloctadecylammonium chloride
ARC.
Trimethyl (soybean oil alkyl) ammonium chloride
ARC,
END.
♦Trimethyl (tallow alkyl) ammonium chloride
ARC,
ASH
ENO,
GNM.
Trime thy Itetradecyl ammonium bromide
FIN.
All other
BRD,
GNM
ICI,
STC.
♦Benzenoid:
1- (2-Aminoethyl)-l-ethyl-2- (8-heptadecenyl-2-
EFH.
imidazolinium bromide.
Benzylalkylpyridinium ammonium chloride
KTC.
♦Benzyl (coconut oil alkyl) dimethylammonium
ARC,
CRT,
DEP,
END, HLI, LUR, TXT, KTC.
chloride.
*Benzyldimethyl (mixed alkyl) ammonium chloride
AAC,
BRD
FIN,
ONX, RH, TXT, VAC.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NT INUED
Cationia Sicpfaae-Active Agents — Continued
'Quaternary ammonium salts, not containing oxygen- -
Continued
*Benzenoid-- Continued
* Benzyl dime thy loot adecylammonium chloride
Benzyldimethyl (tallow alkyl)aiiunonium cliloride
Benzyldime thy Itetradecyl ammonium chloride
Benzyldodecyldi methyl ammonium chloride
Ben zylhexadecy Id imethyl ammonium chloride
Benzyl Chydrogenated tallow alkyl)dimethylammonium
chloride.
l-Benzyl-2-picolinium bromide
1-Benzylpyridinium chloride
*Benzyltrime thy 1 ammonium chloride
(3, 4- Dichlorobenzyl)dodecyldimethyl ammonium
chloride .
(Dodecylbenzyl) triethylammonium chloride
{Dodecylbenzyl)trimethylammoniura chloride
2-Dodecylisoquinolinium bromide
(Dodecylme thy Ihenzylltrime thy 1 ammonium chloride
1-Dodecylpyridinium chloride
(E thy Iben zy 1 ) dimethyl (mixed alky 1 ) ammonium
chloride,
1- (Mixed alkyl)quinolinlum ethylsulfate
l-Phenethyl-2-picolinium bromide
Nonionio Surface- Active Agents
*Carboxylic acid amides :
*Diethanolamine condensates (amine/acid ratio=2/l):
*Capric acid
Castor oil acids
*Coconut oil acids
*Coconut oil and tallow acids
* Laurie acid
Laurie and myristic acids
Linoleic acid
Mixed vegetable oil acids
*01eic acid
Pe 1 argoni c acid
*Stearic acid
*Tall oil acids
Tallow acids
*Diethanolamine condensates (other amine/acid
ratios) :
*Coconut oil acids (amine/acid ratio=l/l)
Coconut oil acids (amine acid ratio unspecified)--
*Lauric acid (amine/acid ratio=l/l)
Laurie and myristic acids (amine/acid ratio=l/l)--
Linoleic acid (amine/acid ratio=l/l)
*01eic acid (amine/acid ratio=l/l)
Palmitic and stearic acid (amine/acid ratio=l/l)--
Rapeseed oil acids (amine/acid ratio=2.6/l)
•Stearic acid (amine/acid ratio=l/l)
Stearic acid (amine/acid ratio=2.7/l)
Manufacturers' identification codes
(according to list in table 3)
BRD,
FIN,
HLI,
ONX,
RH,
TNI,
VAC
END.
FIN,
SNK.
FIN,
ONX,
SDH.
ONX.
ENO,
ONX.
FIN.
DEP.
CHP,
CIN,
CRT,
TCC.
ONX,
VAC.
PC.
\'AC ,
IVTC.
ONX.
RH.
BRD,
ONX.
CCY, SCP, TCH.
CLI, FNX, NTL.
ACT, AKS, ARD, ARL, AZS, BSW, CHP. CLI, CTL, DA, DEP,
EFH, FNX, HLI, HRT, JOR, KNP, LUR, MCP, MOA, MRV,
ONX, PC, PG, PNX, PVO, SBC, SCP, SEY, STP, TCH,
TXC, TXN, UNN, U\'C, VAC, VAL, VND, WTC, x.
ACT, CLI, CRT, ECC, ESS, MOA, PC, PVO, SOS.
ARD, CLI, DA, ECC, HLI, ONX, PG. WON.
FNX, HLI, MOA, PVO, STP.
VND.
HLI.
CCW, CLI, EMR. FNX. PVO, STP.
EMR, TCH.
CLI, DA, EMR, ECC. JOR, mV , ONX, SCO, TXC, VAL.
EFH, MCP, MOA, MRV. SOS.
SOS. 1«TC.
ARD. AZS. CCL. CCY, CIN, CLI, CTL, FNX, HLI, JRG, MOA,
MRV, ONX, PIL, SBC, SEY, STP, TCC, TCH, TXN, TXT,
VAC, IVTC.
CON, JRG.
ARD, CLI, CTL, HIK, HLI, LEV, MOA. ONX. SBC, TCH, TXN,
VAC, IVTC.
CLI, TXT.
MOA, SBC.
CGY, HLI, SBC, SCP, TCC, TCH, TXT.
MCP.
EFH.
CGY, ECC, EMR. FNX, MRV, RPC, m'C.
EFH.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Surface-active agents for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
Nonionia Surface-Active Agents — Continued
*Carboxylic acid amides--Continued
*Diethanolainine condensates (other amine/acid
ratios) --Continued
Tall oil acids (amine/acid ratio=l/l)
Tall oil acids (amine/acid ratio=2.7/l)
Tallow acids (amine/acid ratio=l/l)
All other
*Ethanolamine and isopropanolamine condensates:
♦Coconut oil acids - ethanolamine condensate
(amine/acid ratio=2/l).
•Coconut oil acids - ethanolamine condensate
(amine/acid ratio=l/l).
Coconut oil acids - ethanolamine condensate,
ethoxylated.
Coconut oil acids - isopropanolamine condensate
Hydrogenated castor oil acids - ethanolamine
■ condensate (amine/acid ratio=2/l).
Hydrogenated tallow acids - ethanolamine
condensate (amine/acid ratio=2/l) .
Laurie acid - ethanolamine condensate (amine/acid
ratio=2/l) .
Laurie acid - ethanolamine condensate (amine/acid
ratio=l/l) .
Laurie acid - isopropanolamine condensate
Laurie and myristie acids - ethanolamine
condensate (amine/acid ratio=l/l) .
Laurie and myristie acids - isopropanolamine
condensate.
Oleic acid - ethanolamine condensate (amine/acid
ratio=l/l) .
Oleic acid - ethanolamine condensate, ethoxylated--
Stearie acid - ethanolamine condensate (amine/acid
ratio=2/l) .
Stearic acid - ethanolamine condensate (amine/acid
ratio=l/l) .
Stearic acid - ethanolamine condensate (amine/acid
ratio=l/2) .
Tallow acids - ethanolamine condensate (amine/acid
ratio=l/l) .
All other
*Carboxylic acid esters:
*Anhydrosorbitol esters:
Anhydrosorbitol dioleate
*Anhydrosorbitol monoester of tall oil acids
*Anhydrosorbitol monolaurate
Anhydrosorbitol mono- ol eat e
*Anhydrosorbitol raonopalmitate
•Anhydrosorbitol monostearate
Anhydrosorbitol sesquioleate
Anhydrosorbitol triester of tall oil acids
Anhydrosorbitol trioleate
Anhydrosorbitol tristearate
*Diethylene glycol esters:
Diethylene glycol dioleate
*Diethylene glycol distearate
Diethylene glycol monoester of coconut oil acids —
Diethylene glycol monoester of tallow acids
•Diethylene glycol monolaurate
Diethylene glycol mono-oleate
Diethylene glycol monoricinoleate
•Diethylene glycol monostearate
Diethylene glycol sesquiester of tall oil acids
•Diethylene glycol sesquilaurate
Diethylene glycol sesquistearate
ECC,
EFH.
RPC,
ORO,
CTL,
ARD,
TCH.
STP.
PRX, STP, TCH, VAC, VND, IVTC.
CLI, HLI, HUH, MOA, PG, STP, UVC.
STP.
STP,
MOA.
GLY,
NTL.
GLY.
ARC,
CTL,
PRX.
ARD.
CLI,
MOA.
MOA.
LEV,
TXT.
VPC.
ARD,
DA,
GAF.
CLI.
MOA,
VND.
HAL,
SEY.
SCP.
ROB,
MCP,
TXN.
ICl.
GLY,
HDG,
ICI,
TCH.
GLY,
HDG,
ICI,
SYL
TCH
GLY,
HDG,
ICI,
PVO
TCH
GLY,
HDG,
ICI,
TCH
GLD,
GLY,
HDG.
ICI
PVO
GLY,
HDG.
GLY.
GLY,
ICI,
TCH.
GLY,
ICI,
PVO.
GLY.
ARC,
ECC,
GLY,
VAL
AAC,
DA.
QCP.
CCW,
GLY,
HAL,
HDG
ARC,
EMR.
GLY.
ARC,
CHP,
CLI,
DA,
HAL,
ECC,
WTC.
ARC,
GLY,
mi.
IVM.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
Nonionic Surface-Active Agents — Continued
*Carboxylic acid esters — Continued
*Ethoxylated anhydrosorbitol esters:
Ethoxylated anhydrosorbitol monolaurate
*Ethoxylated anhydrosorbitol mono-oleate
Ethoxylated anhydrosorbitol monopalmitate
'Ethoxylated anhydrosorbitol monostearate
Ethoxylated anhydrosorbitol monotallate
Ethoxylated anhydrosorbitol triester of castor
oil acids.
Ethoxylated anhydrosorbitol triester of tall oil
acids.
Ethoxylated anhydrosorbitol trioleate
•Ethoxylated anhydrosorbitol tristearate
♦Ethoxylated sorbitol esters:
Ethoxylated sorbitol beeswax ester
Ethoxylated sorbitol distearate
Ethoxylated sorbitol heptaoleate
Ethoxylated sorbitol hexaester of tall oil acids--
Ethoxylated sorbitol hexaoleate
Ethoxylated sorbitol lanolin ester
Ethoxylated sorbitol mono-oleate
Ethoxylated sorbitol monostearate
Ethoxylated sorbitol oleate, acetylated
Ethoxylated sorbitol nentaester of tall oil acids-
Ethoxylated sorbitol nentalaurate
Ethoxylated sorbitol pentaoleate
Ethoxylated sorbitol tetraester of lauric and
oleic acids.
Ethoxylated sorbitol tetraester of tall oil acids-
Ethoxylated sorbitol tetraoleate
♦Ethylene glycol esters:
Ethylene glycol distearate
Ethylene glycol mono-oleate
Ethylene glycol monostearate
Ethylene glycol sesquistearate
All other
♦Glycerol esters:
♦Complex glycerol esters:
Glycerol ester ethoxylated
Glycerol lactate esters of fatty acids
Glycerol mannitan laurate
Glycerol monoester of mixed fatty acids,
acetylated.
Glycerol mono-oleate, acetylated
Glycerol monostearate, succinylated
Glycerol trilaurate myristate
♦Glycerol esters of chemically defined acids:
Glycerol di oleate
Glycerol di laurate
Glycerol distearate
Glycerol monocaprylate
♦Glycerol monolaurate
♦Glycerol mono-oleate
♦Glycerol monoricinoleate
♦Glycerol monostearate
♦Glycerol esters of mixed acids:
Glycerol monoester of coconut oil acids
Glycerol monoester of cottonseed oil acids
AAC, GLY, HDG, ICl, SYL, TCH.
AAC, ARC, GLY, HDG, ICl , PVO, SYL, TCH.
AAC, ICI, TC}1.
AAC, GLY, HDG, ICI, PVO, TCH.
1«TC.
ARC.
ICI, TCH.
AAC, GLY, ICI, TCH.
AAC, GLY, HDG, ICI, PVO, TCH.
ICI.
ICI.
ICl.
ICI, TCH.
GLY, ICI, TCH.
ICI.
ICl.
TCIK
ICI.
WTC.
ICl.
ICI.
ICI.
ICl.
ICl.
ARC, EMR, HUI1.
EFH.
ARC, CLI, GLY, HAL, HDG, KNP, TCH, VND, WM.
GLY.
GLD.
GLY .
EKT.
EKT.
GLY.
ARC, HAL.
VND.
ARC, ICl, IVTC.
ARC, pvn.
ARC, GLY, HAL.
ARC, CCW, CHP, DA, EFH, EMR, GLY, HAL, HDG, PVO, TCH,
\m, \«TC.
CCW, DA, HDG.
ARC, ASH, BLS, CHL, DA, EFH, EMR, FNX, GLY, GRO, HAL,
HDG, HRT, LUR, PG, PVO, SCP, SOS, TCC, TCH, VND,
WM, WTC.
PVO, WM.
EKT.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2, --Surface-active agents for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3}
Nonionic Surface- Active Agents — Continued
*Carboxylic acid esters- -Continued
♦Glycerol esters--Continued
♦Glycerol esters of mixed acids--Continued
♦Glycerol monoester of hydrogenated cottonseed
oil acids.
♦Glycerol monoester of hydrogenated soybean oil
acids.
Glycerol monoester of hydrogenated tallow acids
Glycerol monoester of lard acids
Glycerol monoester of peanut oil acids
Glycerol monoester of tall oil acids
Glycerol monoester of tallow acids
Glycerol sesquiester of hydrogenated tallow acids-
Glycerol sesquiester of tall oil acids
All other
♦Natural fats and oils, alkoxylated:
♦Castor oil, ethoxylated
Castor oil, propoxylated
Com oil, ethoxylated
♦Hydrogenated castor oil, ethoxylated
Lanolin, ethoxylated
All other
♦Polyethylene glycol esters:
♦Polyethylene glycol esters of chemically defined
acids:
•Polyethylene glycol dilaurate
♦Polyethylene glycol dioleate
Polyethylene glycol distearate
Polyethylene glycol methylcarbitol maleate
Polyethylene glycol monoisostearate
♦Polyethylene glycol monolaurate
♦Polyethylene glycol mono-oleate
Polyethylene glycol mono-oleate, etlioxylated
Polyethylene glycol monopalmitate
Polyethylene glycol monopelargonate
♦Polyethylene glycol monostearate
Polyethylene glycol sesquioleate
All other
♦Polyethylene glycol esters of rosin and tall oil
acids ;
Polyethylene glycol diester of tall oil acids
Polyethylene glycol ester of tall oil acids
Polyethylene glycol monoester of tall oil acids —
Polyethylene glycol monoester of tall oil
acids, ethoxylated.
Polyethylene glycol sesquiester of rosin acids
Polyethylene glycol sesquiester of tall oil
acids.
♦Polyethylene glycol esters of other mixed acids:
Polyethylene glycol diester of trimerized castor
oil acids.
Polyethylene glycol ester of palmitic, stearic,
and coconut oil acids.
Polyethylene glycol monoester of coconut oil
acids.
GLD, LEV, Wi.
A.SH, F.KT, GLD, NIV, PVn , TCH.
TCH.
EKT, GLD.
pvn.
EFH.
BFP.
JRG.
SLM.
EKT, GLD, ICI, LEV.
AAC, DA, DUP, GAF, ICI, NLC, NIL, PVO, SYL, TCH, TMH,
IVTC.
TCH.
TCH.
DA, ICI, SYL, TCH.
AAC, CRD, CRN, ICI, PR\, TCH.
ARC, DA.
ARC, DA, EFH, GLY, HAL, HDG, TCH, IVM.
ARC, CGY, CLD, DA, EFH, GLY, HAL, HDG, NLC, TCH, UVC,
VND, mi.
ARC, EFH, FNX, GLY, HAL, HDG, TCH.
CCA.
TCH.
AAC, ARC, CCA, CGY, DA, GLY, HAL, HDG, ICI, JOR, KNP,
HCP, TCH, m'C.
AAC, ARC, CCA, CGY, CHP, CLD, CRT, DA, DEX, EFH, GAF,
GLY, HAL, HDG, ICI, ONX, PVn, SCP , TCH, UVC, VAC,
Wl, IVTC.
ICI.
ICI.
EUR, TCH.
khC, AKS, ARC, CGY, CHP, CRT, DA, DEP, DEX, EFH, EMR,
GAF, GLY, HAL, HDG, HRT, ICI, KNP, ONX, PC, PVO,
TCC, TCH, VND.
ICI, TCH, WTC.
SEY.
EFH, GLY.
TCH.
GLY.
NLC, TCH.
HPC.
ARC, ICI, MON, PVn, SLH, SM, WTC.
GLY.
MCP.
GLY.
SURFACE-ACTIVE AGENTS
TABLE 2, --Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
Nonionia Surface- Active Agents — Continued
*Carboxylic acid esters--Continued
*Polyethylene glycol esters--Continued
*Polyethylene glycol esters of other mixed acids--
Continued
Polyethylene glycol monoester of coconut oil
acids, ethoxylated.
Polyethylene glycol sesquiester of castor oil
acids.
*Polyethylene glycol sesquiester of coconut oil
acids.
Polyethylene glycol sesquiester of tallow acids
All other
*Polyglycerol esters:
Polyglycerol ester of tall oil acids
Polyglycerol mono- ole ate
Polyglycerol raonostearate
*Propanediol esters:
1,2 -Propanediol dioleate
1,2- Propanediol distearate
1,3-Propanediol monoester of coconut oil acids
1,2- Propanediol monolaurate
1,2- Propanediol monomyri state
1,2 -Propanediol mono- ol eat e
* 1,2- Propanediol monostearate
1,2- Propanediol sesquiester of h\*drogenated tallow
acids.
All other
Miscellaneous carboxylic acid esters:
Anhydrosorbitol glycerol monolaurate
Ethoxylated glycerol sesquiester of mixed fatty
acids.
Ethoxylated 1,2-propanediol monostearate
2-Hydroxymethyl-2-butene-l,4-diol mononelargonate —
Laurie acid esters of glycerol and ethoxylated
nonylphenol .
Methylglucoside 1 aur ate
Mixed esters of stearic acid
Mixed polyhydric alcohols triester of tall oil
acids .
Oleic acid esters of ethoxylated nonylphenol
Pentaecrythritol distearate
Polyalkylene glycol adipate
Polyalkylene glycol di fumarate
Polypropylene glycol monoester
Poly-propylene glycol mono-oleate
Polypropylene glycol raonostearate
All other
*Ethers :
*Benzenoid ethers:
*Alkylphenol - formaldehyde condensates, alkoxylated:
Alkylphenol, ethoxylated
(Mixed alkyl)phenol - formaldehyde, alkoxylated
Nonylphenol - formaldehyde, alkoxylated
tert-flctylphenol - formaldehyde, ethoxylated
All other
Derivatives of ethoxylated phenols
Diisobutylphenol , ethoxylated
Dinonylphenol , ethoxylated
*Dodecylphenol , ethoxylated
Iso-octylphenol, ethoxylated
AAC,
ICI.
CGY.
ARL,
MRT,
PG,
VND.
sns.
ACT,
ECC,
SIR
SM,
AZS.
HDG,
pvn,
TCH
VND.
ASH,
pvn.
TCH
X.
ARC.
Wl.
ARC,
HAL,
PVO
SBC.
ICI.
EFH,
HAL.
ARC,
CCW,
EKT
GLD,
JRG.
ICI.
ICI.
ICI.
ICI.
TCC.
HDG.
EUR.
ICI.
EFH.
GLY, QCP, VAL.
NLC.
WTC.
sns.
HDG.
HDG.
CCW, TCH, WM.
IVTC.
NLC, NTL.
NLC, WTC.
DA, SDW.
PVO, WTC.
RH.
GAF.
ARD, GAF, STP, TCH.
ACC, GAF, HON, TCH, TMH, UCC.
APX, DA, OHC, RH.
SYNTHETIC ORGANIC CHEMICALS^ 1972
TABLE 2. --Surface-active agents for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER^ 1°72--C0NT!NUED
Manufacturers' identification codes
(according to list in table 3)
Nonionic Surface- Active Agents — Continued
*Ethers :- -Continued
*Benzenoid ethers: --Continued
(Mixed alkyl)phenol, ethoxylated
(Mixed alkyl5phenoxypoly(ethyleneoxy) ethyl
chloride.
*Nonylphenol, ethoxylated
Nony Iphenoxypoly (ethyleneoxy) ethyl iodide
n- Oc ty Ipheno 1, ethoxylated
Phenol, ethoxylated
Styrenated phenol, ethoxylated
Tetradecylphenol, ethoxylated
Tridecylphenol, ethoxylated
Xylenol , ethoxylated
All other
*Nonbenzenoid ethers :
*Linear alcohols, alkoxylated:
Coconut oil alcohol, ethoxylated
*Decyl alcohol, ethoxylated
Decyl and octyl alcohols, ethoxylated
Decyl and octyl alcohols, ethoxylated and
propoxylated.
Decyloxypoly (ethyleneoxy) ethyl chloride
Derivative of ethoxylated primary alcohol
*Dodecyl alcohol, ethoxylated
*Hexadecyl alcohol, ethoxylated
*Mixed linear alcohols, ethoxylated
*Mixed linear alcohols, ethoxylated and
propoxylated.
*9-0ctadecenyl alcohol, ethoxylated
*Octadecyl alcohol, ethoxylated
Sperm oil alcohol, ethoxylated
Tallow alcohol, ethoxylated
Wool wax alcohols, ethoxylated
*Other ethers and thioethers:
*Poly(ethylene and propylene) glycols :
Poly(mixed ethylene, propylene) glycol
Polypropylene glycol, ethoxylated
tert-Dodecyl mercaptan, ethoxylated
Ethylhexanol, ethoxylated
Glucose, ethoxylated
Glycerol , alkoxylated
Isodecyl alcohol, ethoxylated
Iso-octyl alcohol, ethoxylated
Methylglucoside, propoxylated
Mixed alcohols, ethoxylated
Rosin alcohol, ethoxylated
Sorbitol, ethoxylated
2,4,7,9-Tetramethyl-5-decyne-4,7-diol ,
ethoxylated.
*Tridecyl alcohol, ethoxylated
Tridecyl alcohol, propoxylated and ethoxylated-
Trimethylheptanol , ethoxylated
♦Trimethylnonyl alcohol, ethoxylated
Trimethylolpropane , alkoxylated
All other
Other nonionic surface-active agents:
Dodecylbenzenesulfonic acid - diethanolamine
condensate, fatty acid monoester.
Dodecyl alcohol, ethoxylated and phosphated
Octyl phosphate, ethoxylated
Tri(castor oil alkyl)phosphate
All other
NTL, PRX, TCH.
GAP, NIC.
, DA, GAP, HDG, ICl, JCC, MON, OMC, RH, STP, TCH,
mi, UCC, VAC, WTC.
DA, GAP, ICI, JCC, TCH, UCC.
GAP.
TCH.
CLY,
DA.
ORn.
TCH.
NLC.
GAP,
GLY.
GAP, ICl, TCH.
GAP, GLY, TCH.
GAP.
GAP.
RH.
AAC, DUP, GAP, HDG, ICI, OMC, PVO, SNW, UCC, WTC.
AAC, CGY, ICI, VAC, TCH.
AAC, Cn, DA, GAP, HDG, JCC, NLC, RH, SHC, STP, TCH,
UCC, WTC.
JCC, STP, TCH, UCC, WYN.
AAC, ABC, CGY, CRN, DA, DUP, GAP, GLY, ICI, TCH, VPC.
CGY, DA, DUP, GAP, ICI, HDG.
CRD, DUP.
AAC.
CRD.
NLC, UCC.
NLC, VAC, IVTC, IVYN.
AAC, UCC. IVTC.
TCH.
RH.
NLC.
TCH.
GAP.
STP.
CRN, PVO.
NLC, VAC.
TCH.
GAP.
AAC, DA, DUP, GAP, ICI, JCC, MON, NLC, OMC, PVO, SYL,
TCH, UCC, IVTC.
ICI, JCC.
TCH.
HDG, UCC, VAC.
HDG, VAC, IVTC, IVYN .
TCH.
ACT.
DUP.
DUP.
GLY.
AIP, STC.
SURFACE-ACTIVE AGENTS
TABLE 3, --Surface-active agents; Directory of manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of manufacturers that reported production or sales of surface-active agents to the U.S. Tariff Commission for
1972 are listed below in the order of their identifcation codes as used in table 2]
Code
Name of company
Code
Name of company
AAC
Alcolac Chemical Corp.
FIN
Fine Organics, Inc.
ABC
ARC Chemical Corp.
ACE
Acme Chemical Co.
GAF
GAF Corp., Chemical Div.
ACS
Allied Chemical Corp., Specialty Chemicals Div.
GLD
Glidden Durkee Famous Foods
ACT
Arthur C. Trask Co.
GLY
Glyco Chemicals, Inc.
ACY
American Cyanamid Co.
GNM
General Mills Chemicals, Inc.
AES
Amerace-Esna Corp., Penetone Div.
GRC
Chemed Corp., Dubois Chemicals Div.
AGP
Armour- Dial, Inc.
CRD
W.R. Grace 5 Co., Polymer § Chemicals Div.
AIP
Air Products 5 Chemicals, Inc.
GRL
Chemed Corp., Vestal Laboratories, Inc.
AKS
Arkansas Co. , Inc.
GRO
Millmaster Onyx Corp., A. Gross 5 Co. Div
APX
Apex Chemical Co., Inc.
GYR
Goodyear Tire 6 Rubber Co.
ARC
Armak Co.
ARD
Ardmore Chemical Co.
HAL
CP. Hall Co. of Illinois
ARL
Arol Chemical Products Co.
HDG
Hodag Chemical Corp.
ASH
Ashland Oil, Inc., Ashland Chemical Co. Div.
HEW
Hewitt Soap Co. , Inc.
ASY
American Synthetic Rubber Corp.
HK
Hooker Chemical Corp.
ATR
Atlantic Richfield Co., ARCO Chemical Co.
HLI
Haag Laboratories, Inc.
AZS
AZS Corp. :
AZ Products Co. Div.
HMP
W.R. Grace 6 Co., Dewey 5 Almy Chemical Di
Organic Chemicals
V. ,
Lancaster Chemical Co. Div.
HNT
HPC
Huntington Laboratories, Inc.
Hercules, Inc.
BAO
Bayoil Co. , Inc.
HRT
Hart Products Corp.
BFP
Breddo Food Products Corp.
HUM
Kraftco Corp., Humko Products Div.
BLA
Astor Products, Inc., Blue Arrow Div.
BLS
Beech-Nut, Inc.
ICl
ICI America, Inc. and Specialty Chemicals
Div.
BRD
Lonza, Inc.
BSW
Original Bradford Soap Works, Inc.
JCC
JOR
Jefferson Chemical Co., Inc.
Jordan Chemical Co.
CCA 5
Cincinnati Milacron Chemicals, Inc.
JRG
Andrew Jergens Co.
CCW
CCL
A.E. Staley Manufacturing Co., Textile Div.
KAL
Kali Manufacturing Co.
CGY
Ciba-Geigy Corp. and Ciba Pharmaceutical Co.
KNG
Far-Best Corp., O.L. King Div.
CHL
Chemol, Inc.
KNP
Knapp Products, Inc.
CHP
C.H. Patrick f, Co., Inc.
CIN
Cindet Chemicals, Inc.
LAK
Lakeway Chemicals, Inc.
CLD
Colloids, Inc.
LEA
Leatex Chemical Co.
CLI
Clintwood Chemical Co.
LEV
Lever Brothers Co.
CLY
W.A. Cleary Corp.
LIL
Eli Lilly fi Co.
CO
Contirental Oil Co.
LKY
Lake States Div. of St. Regis Paper Co.
COM
Commercial Solvents Corp.
LMI
North American Chemical Co.
CON
Concord Chemical Co., Inc.
LUR
Laurel Products Corp.
CP
Colgate-Palmolive Co.
CPP
Charmin Paper Products Co.
MAR
American Can Co.
CRD
Croda, Inc.
MCP
Moretex Chemical Products, Inc.
CRN
CPC International, Inc.
MIR
Miranol Chemical Co., Inc.
CRT
Crest Chemical Corp.
MOA
Mona Industries, Inc.
CRZ
Crown Zellerbach Corp., Chemical Products Div.
MON
Monsanto Co.
CST
Charles S. Tanner Co.
MRA
Crown-Metro, Inc.
CTL
Continental Chemical Co.
MRD
Marden-Wild Corp.
CWP
Consolidated Papers, Inc.
MRT
Morton Chemical Co. Div. of Morton-Norwich
ducts. Inc.
Pro-
DA
Diamond Shamrock Corp.
MRV
Marlowe- Van Loan Corp.
DAN
Dan River, Inc.
MYW
Stepan Chemical Co., Maywood Div.
DEP
DePaul Chemical Co., Inc.
DEX
Dexter Chemical Corp.
NCW
Nostrip Chemical Works, Inc.
DOW
Dow Chemical Co.
NES
Nease Chemical Co., Inc.
DUP
E.I. duPont de Nemours 5 Co., Inc.
NLC
Nalco Chemical Co.
DYS
Davies- Young Co.
NMC
NPR
National Milling 5 Chemical Co., Inc.
Safeway Stores, Inc.
ECC
Eastern Color 5 Chemical Co.
NTL
NL Industries, Inc.
EFH
E.F. Houghton 6 Co.
NW
Northwestern Chemical Co.
EKT
Eastman Kodak Co., Tennessee Eastman Co. Div.
EMK
Emkay Chemical Co.
OMC
01 in Corp.
EMR
Emery Industries, Inc.
ONX
Millmaster Onyx Corp., Onyx Chemical Co.
ENO
Enenco, Inc.
ORO
Chevron Chemical Co.
ESS
Essential Chemicals Corp.
SYNTHETIC ORGANIC CHEMICALS. 1972 •
TABLE 3, --Surface-active agents; Directory of manufacturers, 1972--Continued
Code
Name of company
Code
Name of company
PC
Proctor Chemical Co., Inc.
SOS
Southern Sizing Co.
PCH
Peerless Chemical Co.
SPA
Scott Paper Co.
PEK
Peck's Products Co.
stc
Sou-Tex Chemical Co., Inc.
PFZ
Pfizer, Inc.
stp
Stepan Chemical Co.
PC
Procter 5 Gamble Co.
SYL
Magnolia Industries, Inc., Milliken Chemical
PIL
Pilot Chemical Co.
Div.
PLX
Plex Chemical Corp.
PNX
Murphy-Phoenix Co.
tcc
Tanatex Chemical Corp.
PRX
Purex Corp. , Ltd.
tch
Emery Industries, Inc., Trylon Chemica
Div.
PSP
Georgia-Pacific Corp., Bellingham Div.
TCI
Texize Chemicals, Inc.
PVO
PVO International, Inc.
TEN
TMH
Cities Service Co., Copperhill Operatic
Thompson -Hayward Chemical Co.
ns
QCP
Quaker Chemical Corp.
TNA
Ethyl Corp.
TNI
Gillette Chemical Co. Div. of Gillette
Co.
RAY
ITT Rayonier, Inc.
TXC
Tex Chem Co.
RBC
Fike Chemicals, Inc.
TXN
Textilana-Nease, Inc.
RCD
Richardson Co.
TXT
Textilana Corp.
RH
Rohm 5 Haas Co.
ROB
Robeco Chemicals, Inc.
UCC
Union Carbide Corp.
RPC
Millmaster Onyx Corp., Refined-Onyx Div.
UDI
UNN
Petrochemicals Co., Inc.
United Chemical Corp. of Norwood
S
Sandoz, Inc., Sandoz Colors § Chemical Div.
IINP
United Chemical Products Corp.
SBC
Scher Bros. Inc.
USR
Uniroyal, Inc., Chemical Div.
SBP
Sugar Beet Products Co.
UVC
Universal Chemicals Corp.
SCO
Scholler Bros. , Inc.
SCP
Henkel, Inc.
VAC
Northern Petrochemical Co.
SDC
Martin-Marietta Corp. , Sodyeco
VAL
Valchem
Sterling Drug, Inc. :
VND
Van Dyk 5 Co. , Inc.
SDH
Hilton-Davis Chemical Co. Div.
VPC
Baychem Corp., Verona Div.
SDW
Winthrop Laboratories Div.
SEA
Seabroad Chemicals, Inc.
WAW
W.A. Wood Co.
SEY
Seydel-Woolley 5 Co.
WAY
Philip A. Hunt Chemical Corp., Kayland
Chemical
SFS
Stauffer Chemical Co., Specialty Chemical Div.
Div.
SHC
Shell Oil Co., Shell Chemical Co. Div.
WBG
White f, Bagley Co.
SID
George F. Siddall Co., Inc.
WHI
White § Hodges, Inc.
SLC
Soluol Chemical Co., Inc.
WHW
Whittemore-Wright Co., Inc.
SLM
Salem Oil 6 Grease Co.
WIC
Wica Chemicals, Inc.
SM
Mobil Oil Corp., Mobil Chemical Co.,
Chemical Coatings Div.
WM
Wilson Pharmaceutical 5 Chemical Corp.
Wilson-Martin Div.
SNW
Sun Chemical Corp., Chemicals Div.
WON
Woonsocket Color 5 Chemical Co.
SOC
Standard Oil Co. of California, Chevron
WTC
Witco Chemical Co., Inc.
Chemical Co.
WVA
Westvaco Corp., Chemicals Div., Polyche
mical
SOP
Southern Chemical Products Co.
WYN
Dept.
BASF-Wyandotte Chemicals Corp.
Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix.
189
PESTICIDES AND RELATED PRODUCTS
Pesticides and related products include fungicides, herbicides,
insecticides, rodenticides , and related products such as plant hormones,
seed disinfectants, soil conditioners, soil furaigants, and synergists.
The data are given in terms of 100-percent active material; they thus
exclude such materials as diluents, eraulsifiers, and wetting agents.
U.S. production of pesticides and related products in 1972 amounted
to 1,158 million pounds--!, 9 percent greater than the 1,136 million
pounds reported for 1971 (table 1).^ Sales in 1972 were 1,Q22 million
pounds, valued at $1,092 million, compared with 946 million pounds, valued
at $979 million, in 1971.
The output of cyclic pesticides and related products amounted to
839 million pounds in 1972--1.4 percent greater than the 828 million pounds
produced in 1971. Sales in 1972 were 7.20 million pounds, valued at $890
million, compared with 669 million pounds, valued at $819 million, in 1971.
Production of acyclic pesticides and related products in 1972 amounted to
318 million pounds, compared with the 308 million pounds reported for 1971,
an increase of 3.3 percent. Saxes in 1972 were 302 million pounds, an in-
crease of abci't 8^ percent as compared to the 277 million pounds reported
in 1971; the value of sales was $202 million in 1972, compared with $160
million in 1971--an increase of 26.3 percent.
1/ See also table 2 which lists these products and identifies the
manufacturers by codes. These codes are given in table 3.
552-743 O - 74 - 13
.SYNTHETIC nPnANIC CMFfllCALS, 1972
TARLE 1. —Pesticides and related products; U.S. production and sales, 1972
[Listed below are all pesticides and related products for which any reported data on production or sales may be pub-
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no
data were reported.) Table 2 lists all pesticides and related products for which data on production or sales were
reported and identifies the manufacturers of each]
Production
Sales
Quantity
Unit
value'
1,000
pounds
Grand total
Benzenoid
Nonbenzenoid
pesticides and related products, cyclic
Total
Fungicides , total
Mercury fungicides, total
Phenylmercuric acetate (PMA)
Phenyl mercuric oleate
Other mercury fungicides
Naphthenic acid, copper salt
Pentachlorophenol (PCP)
8-Quinolinol (S-Hydroxyquinoline) , copper salt
All other cyclic fungicides"
Herbicides and plant hormones, total
l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH)
2,4-Dichlorophenoxyacetic acid, dimethylaitiine salt
All other cyclic herbicides and plant hormones-
Insecticides and rodenticides, total
Aldrin-toxaphene group'*
Organophosphorus insecticides, total
0,0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl
parathion)
All other organophosphorus insecticides^
All other cyclic insecticides and rodenticides^
PESTICIDES AND RELATED PRODUCTS, ACYCLIC
Total
Fungicides, total
Dithiocarbamic acid salts'
All other acyclic fungicides'
Herbicides and plant hormones, total
Methanearsonic acid salts'
All other acyclic herbicides'"
657,092
500,606
98,164
854
307
279
268
2,206
49,704
40
45,360
4,472
22,469
344,789
141,858
95,461
51,076
44,385
318,338
30,698
48,883
liOOO
pounds
1,021,565
1,000
dollars
581,107
440,458
88,530
781
284
263
234
2,291
48,355
37,103
282,094
24,028
258,066
349,083
140,150
90,283
52,438
37,845
118,650
39,987
34,857
36,632
681,768
409,940
58,192
3,154
1,382
539
1,233
717
6,783
47,538
9,311
564,537
65,919
96,843
23,576
73,267
202,095
23,972
17,382
6,590
55,110
9,370
45,740
Per
pound
1.28
2.03
.27
1.25
See footnotes at end of table.
PESTICIDES AND RELATED PRODUCTS
TABLE 1,— Pesticides and related products: I'.S. production and sales^ T'^72— Continued
Quantity
Unit
value'
PESTICIDES AiND RELATED PRODUCTS, ACYCLIC--Continued
Insecticides, rodenticides, soil conditioners and
fumigants, total
Methyl bromide (Bromomethane)
Organophosphorus insecticides' '
1 ,2-Dibromo-3-chloropropane (DBCPJ
All other acyclic insecticides, rodenticides, soil
conditioners and fumigants
1,000
pounds
7,000
pounds
1,000
do t tars
Per
pound
24,633
65,181
104,295
23,930
59,734
15,228
91,490
9,349
76,507
6,275
30,882
.34
1 Lalculated trom rounded tigures.
2 Includes captafol , captan, dinocap, DMTT, folpet, pentachloronitrobenzene, 8-quinolinol (sales only), sodium
pentachlorophenate, tri- and tetra-chlorophenols (including 2 ,4 ,5-trichlorophenol and its salts), and others.
3 Includes acetanilide compounds, amiben esters and salts, barban, benefin, bensulide, 4-CPA potassium salt,
2,4-D, acid, esters, and salts, 2,4-DB, dicamba, dimethylurea compounds, dinitrophenol compounds, isopropyl phenyl-
carbamates (IPC and CIPC), MCPA, MH (sales only), molinate, NPA picloram, propanil, silvex and its esters, 2,4, 5-T
acid esters and salts, triazines, trifluralin, uracils, and others.
4 Includes aldrin, chlordan, dieldrin, endrin, heptachlor, and toxaphene.
5 Includes azinphosmethyl , carbophenothion, coumaphos , diazinon, dioxathion, fensulfothion , parathion, ronnel,
and other phosphorothioates and phosphorodithioates, and others.
6 Includes carbaryl , carbofuran, chlorinated insecticides (BHC + lindane, chlorobenzilate, DDT, dicofol, endo-
sulfan, methoxychlor, and others), insect attractants, DEET and other insect repellents, small amounts of rodenti-
cides, piperonyl butoxide and other synergists, and others.
7 Includes ferbam, maneb, nabam, and zineb, plus the remaining dithiocarbamates which are used chiefly as
pesticides.
8 Includes dodine, mercury compounds, PETD, and others.
9 Includes the mono- and di-sodium salts, and the dodecyl- and octyl -ammonium salts of methanearsonic acid.
10 Includes cacodylic acid, CDAA, dalapon, thiocarbamate, thiol carbamate, and organophosphorus herbicides, sodiuii
TCA, and others.
11 Includes DDVP, dimethoate, disulfoton, ethion, malathion, monocrotophos , naled, phorate, and other organo-
phosphorus insecticides.
12 Includes aldicarb, DBCP (production only), soil conditioners and fumigants, methomyl , small quantities of
rodenticides, and others.
Note. --Does not include data for the insect fumigant, p-dichlorobenzene nor the fungicide, o-phenylphenol.
These data are included in the report on cyclic intermediates.
To expedite publication of this report it was necessary to estimate data for two small companies.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972
[Pesticides and related products for which separate statistics are given in table 1 are marked below with an
asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence
and may not be published. Manufacturers' identification codes shown below are taken from table 5. An x signifies
that the manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3}
PESTICIDES AND RELATED PRODUCTS, CYCLIC
*Fungicides;
Benzylbromo acetate--
2, 6 -Bis (dimethylamiTiomethyl)cvclohexanone
2'-Rrorao-4'-hydroxyacetophenone
5-Chloro-2-benzothiazolethiol , laurylpyridinium salt
Cyanomethylthiobenzothiazole
2,4-Dichloro-6-(o-chloroanilino)-s-triazine
1 ,4-Dichloro-2,5-dimethoxybenzene (ChloronebJ
1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline (Ethoxyquin)-
3,5-Dimethyl-l,3,5-2H-tetrahydrothiadiazine-2-thione
(DMTT) .
Diphenylammonium propionate
5-Ethoxy-3-trichloromethyl-l ,2,4-thiadiazole
Hexahydro-1 .3,5-triethyl-s-triazine
Hexahydro-1 ,3,5-tris (2-hydroxyethyl)-s-tri3zine
2-Mercaptobenzothia2ole, monoethanolamine salt
*Mercury fungicides:
Dipheny Imercury dodeceny Isuccinate
•Phenylmercuric acetate (PMA)
Phenylmercuric ammonium acetate
Phenylmercuric dimethyldithiocarbamate
Phenylmercuric hydroxide
Phenylmercuric lactate
* Phenyl mercuric oleate
Phenylmercuric propionate
Phenylmercuric succinate
All other mercury fungicides
Methyl-N-benzimidazol-2-yl-N- (butylcarbomoyl) carbamate
(Benomyl) .
2- (l-Methyl-n-heptyl)-4,6-dinitrophenyl crotonate
(Dinocap) .
3- (2-Methylpiperidino) propyl- 3, 4-dichlorobenzoate
(Piperalin) .
*Naphthenic acid, copper salt
Pentachloronitrobenzene (PCNB)
*Pentachlorophenol (PCP)
Pentachlorophenol , sodium salt
*8-Quinolinol (8-Hydroxyquinoline) , copper salt
N- CI ,1 ,2,l-Tetrachloro-ethylsulfenyl)-cis-'-4-cyclo-
hexene-l,2-dicarboximide (Captafol) .
2,4,5,6-Tetrachloroisophthalonitrile
2,3,4,6-Tetrachlorophenol
N-Trichloromethylthio-4-cyclohexene-l,2-dicarboximide
(Captan) .
N-Trichloromethylthiophthalimide (Folpet)
2,4 ,5-Trichlorophenol acid and salts:
2,4,S-Trichlorophenol
2,4,5-Trichlorophenol, ethanolamine salt
2,4,S-Trichlorophenol , sodium salt
2,4,6-Trichlorophenol
*Herbicides and plant hormones:
4-Amino-3,5,6-trichloropicolinic acid (Picloram)
2,4-Bis(isopropylamino)-6-methylthio-s-triazine
(Prometryn) .
5-Bromo-3-sec-butyl-6-methyluracil (Bromacil)
3-tert-Butyl-S-chloro-6-methyluracil (Terbacil)
N-Butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-p-toluidine
(Benefin) .
2-Butynyl-4-chloro-m-chlorocarbanilate (Barban)
2-Chloro-4,6-bisCethylamino)-s-triazine (Simazine)
2-Chloro-4,6-bis(isopropylamino)-s-triazine (Propazine)
MRK.
MRK.
BKM.
VNC.
BKM.
CHG.
DUP.
MON.
BKM, MRK.
MRK.
OMC.
VNC.
EFH.
VNC.
TRO.
CLY, MRK, TRO, WRC.
TRO.
WRC.
WRC.
WRC.
CLY, HN, TRO, WRC.
MRK.
WRC.
MAL.
DUP.
RH.
CCA,
OMC.
DOW,
DOW,
FIS,
ORO.
DOW.
SFC.
DOW,
GAF.
DOW.
DOW.
DOW.
CGY.
ACN,
DUP.
LIL.
GOC.
CGY.
CGY.
FER, HN, MCI, SHP, VAL , WTTC .
FRO, MON, RCI .
RCI.
HN, MRK.
PESTICIDES AND RELATED PRODUCTS
TABLE 2, --Pesticides and related products for which U,S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CyCLIC--Continued
*Herbicides and plant hormones--Continued
2-Chloro-2' ,6'-diethyl-N- (n-butoxyniethyl)acetanilide
2-Chloro-2' ,6* -diethyl-N- (methoxymethyl)acetanilide
(Alachlor] .
2-Chloro-4-ethylamino-6-isopropylamino-s-triazine
(Atrazine) .
2-Chloro-N-isopropylacetanilide (Propachlor)
4-Chloro-2-methylphenoxy butyric acid
N' -(4-Chlorophenoxy 3 phenyl N,N-dimethylurea
(Chloroxuron) .
3- (p-Chlorophenyl)-l , 1-dimethylurea (Monuron)
3- (p-Chlorophenyl)-l,l-diiiiethyIurea trichloroacetate
2;5-Dichloro-5-aminoben2oic acid, ammonium salt
2,5-Dichloro-5-aniinobenzoic acid, methyl ester
3,6-Dichloro-2-anisic acid (Dicamba)
2,4-Dichlorobenzyltributylphosphonium chloride
2,5-Dichloro-6-nitrobenzoic acid, sodium salt
4- (2,4-Dichlorophenoxy}butyric acid (2,4-DB)
3- (3,4-Dichlorophenyl) -1 , 1-dimethylurea (Diuron)
3- (3,4-Dichlorophenyl )-l-methoxy-l-methylurea (Linuron)--
2,4-Dichlorophenyl-4-nitrophenyl ether (Nitrofen)
3' ,4'-Dichloropropionanilide (Propanil)
*l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH)
N- (beta-0,0-Diisopropyl-dithiophosphorylethyl)benzene
sulfonamide (Bensulide) .
N,N-Dimethyl-2,2-diphenylacetamide (Diphenamid)
Dimethyl -2, 3, 5,6 -tetrachloroterephthalate (DCPA)
Dinitrobutylphenol (DNBP)
Dinitrobutylphenol , aBBonium salt
Dinitrobutylphenol, triethanolamine salt
Dinitrocresol, sodium salt
2-Ethylamino-4-isopropyla«lno-6-methylmercapto-s-
triazine (Ametryne) .
S- Ethyl (cyclohexyl)ethylthiocarbamate
S-Ethyl hexahydro-lH-azepine-1-carbothioate (MolinateJ
Gibberellic acid
3-Indolebutyric acid
Isopropyl N- (3-chlorophenyl)carbamate (CIPC)
Isopropyl N-phenylcarbamate (IPC)
1- (2-Methylcyclohexyl)-3-phenylurea (Siduron)
4-(Methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline
(Nitralin).
1-Naphthaleneacetic acid and derivatives:
1 -Naphtha leneacet amide
1-Naphthaleneacetic acid (NAA)
1-Naphthaleneacetic acid, sodium salt
N-1-Naphthylphthalamic acid (NPA)
7-Oxabicyclo[2.2. l]heptane-2,3-dicarboxylic acid, di-
sodium salt (Endothall).
Phenoxyacetic acid derivatives:
4-Chloro-2-methylphenoxyacetic acid (MCPA)
3,S-Dibrorao-4-hydroxybenzonitrile, octanoic acid ester
(Bromoxynil octanoate) .
2,4-Dichlorophenoxyacetic acid (2,4-D)
2,4-Dichlorophenoxyacetic acid esters and salts:
2,4-Dichlorophenoxyacetic acid, 2-butoxyethyl ester--
2,4-Dichlorophenoxyacetic acid, butoxypolypropylene-
glycol ester.
2,4-Dichlorophenoxyacetic acid, n-butyl ester
2,4-Dichlorophenoxyacetic acid, sec-butyl ester
•2,4-Dichlorophenoxyacetic acid, dimethylamine salt
MON.
MON
MON.
RDA.
CGY.
DUP.
ACN.
AMC, GAP.
GAP.
VEL.
SM.
GAP.
RDA.
DUP.
DUP.
Rll.
EGR, MON, RH.
ACY, ASL, FNfT, USR.
SPA.
CWN.
DOW,
EGR,
PMN.
DOW,
PMN.
DOW,
FMN.
FMN.
CGV.
SPA.
SPA.
ABB,
MRK.
ARA.
PPG.
PPG.
DUP.
SHC.
AMC.
■AMC.
AMC,
BKL.
USR.
PAS.
CLY,
RDA,
RIV.
RDA.
DOW, MON, RDA.
DOW, RIV.
DOW.
RIV.
DOW, RDA.
DOW, PBI, RDA, RIV, TMH .
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Pesticides and related products for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC- -Continued
•Herbicides and plant horraones--Continued
Phenoxyacetic acid derivatives--Continued
2,4-Dichlorophenoxyacetic acid esters and salts--
Continued
2,4-Dichlorophenoxyacetic acid, ethanolamine and
isopropanolamine salt.
2,4-Dichlorophenoxyacetic acid, iso-octyl ester —
2,4-Dichlorophenoxyacetic acid, isopropyl ester
2,4-Dichlorophenoxyacetic acid, lithium salt
2,4-Dichlorophenoxyacetic acid, sodium salt
2,4,S-Trichlorophenoxyacetic acid (2,4,5-T)
2,4,5-Trichlorophenoxyacetic acid esters and salts:
2,4,5-Trichlorophenoxyacetic acid, 2-butoxyethyl
ester.
2,4,5-Trichlorophenoxyacetic acid, butoxypoly-
propyleneglycol ester.
2,4,S-Trichlorophenoxyacetic acid, n-butyl ester--
2,4,S-Trichlorophenoxyacetic acid, sec-butyl ester
2,4,5-Trichlorophenoxyacetic acid, iso-octyl ester
2,4,5-Trichlorophenoxyacetic acid, triethylamine
salt.
Polychloro-tetrahydro-methanoindene (Polychlorodicyclo
pentadiene) isomers.
2- (2,4,5-Trichlorophenoxy)propionic acid (Silvex)
2- (2,4,5-Trichlorophenoxy)propionic acid esters and
salts:
2- (2,4,5-Trichlorophenoxy)propionic acid, 2-butoxy-
ethyl ester.
2- (2,4,5-Trichlorophenoxy)propionic acid, iso-octyl
ester.
a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine
(Trifluralin).
3- (m-Trifluoromethylphenyl)-l ,1-dimethylurea
(Fluometuron) .
All other cyclic herbicides
Insect attractants and repellents:
tert-Butyl 4 (and 5)-chloro-2-methylcyclohexanecarboxy-
late (Trimedlure] .
2-(3,4-Dichlorophenyl)-l,2,4-oxadiazoline-4-methyl-
3,5-dione.
N,N-Diethyltoluamide (DEET)
Di-n-propylisocinchomeronate
•Insecticides:
3-sec-Amylphenyl-N-methylcarbamate
Bacillus thuringiensis
2-sec-Butyl-4,6-dinitrophenyl-3,3-dimethylacrylate
(Binapacryl) .
2-(p-tert-Butylphenoxy)cyclohexyl-2'-propynyl sulfite--
o-sec-Butylphenyl-N-methylcarbamate
Chlorinated insecticides:
*Aldrin-toxaphene group:
Heotachloro-tetrahydro-endo-methanoindene
(Heptachlor) .
Ilexachloro-epoxy-octahydro-endo , endo-dimethano-
naphthalene (Endrin) .
Hexachloro-epoxy-octahydro-endo, exo-dimethano
naphthalene (Dieldrin).
Hexachloro-hexahydro-endo, exo-dimethanonaphthalene
(Aldrin).
Octachloro-hexahydro-methanoindene (Chlordan)
Toxaphene (Chlorinated camphene)
2,2-Bis(p-chlorophenyl)-l,l-dichloroethane (DDD) (TDE)-
a-Bis(p-chlorophenyl)B,6,6-trichloroethane (DDT)
DOW,
RDA, RIV
DOW
RIV.
GTH.
DOW,
RIV.
DOW.
DOW,
RIV.
DOW.
RIV.
DOW.
DOW,
RIV, TMH
DOW.
VEL.
DOW,
TMH.
RIV.
RIV.
LIL.
CGY.
CWN,
LIL.
UOP.
NES,
VEL.
HPC,
PF2.
MGK.
X.
ABB,
IMC.
FMN.
USR.
OTC.
VEL.
VEL.
SHC.
SHC.
VEL.
HN,
HPC.
PESTICIDES AND RELATED PRODUCTS
TABLE 2.— Pesticides and related products for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued
'Insecticides --Continued
Chlorinated insecticides- -Continued
Chlorobenzilate
o-Chlorophenyl-N-methylcarbamate
p-Chlorophenyl 2,4,5-trichlorophenyl sulfone
(Tetradifon) .
Decachlorooctahydro-l,3,4-metheno-2H-cyclobuta- [cd]
pentalen-2-one (Kepone) .
l,l-Dichloro-2,2-bis (p-ethylphenyl) ethane
4,4'-Dichloro-a-trichloromethylbenzhydrol (Dicofol)
2 ,6-Dimethyl-3,5-dichloro-4-pyridinol
Dodecachlorooctahydro-l ,3,4-metheno-2H-cyclobuta- [cd]
pentalene (Mirex) .
Hexachlorocyclohexane (Benzene hexachloride^ (BHC)
Hexachlorocyclohexane, 100% Y-isomer (Lindane)
Hexachloro-hexahydro-methano-benzodioxathiepin
3-oxide (Endosulfan) .
Isopropyl 4,4' -dichlorobenzilate (Chloropropylate)
1 ,1 ,1-Trichloro- 2, 2-bis(p-methoxyphenyl) ethane
(Methoxychlor) .
2,3-Dihydro-2,2-dimethyl-7-benzofuranly methyl -
carbamate (Carbofuran) .
m-[[(pimethylaiiiino)methylene]amino]phenyl methyl carbamate
hydrochloride (Formetanate hydrochloride) .
m- (1 -Ethyl propyl) phenyl methyl carbamate
O-Isopropylphenyl N- methyl carbamate
m- (I-Methylbutyl ) phenyl methyl carbamate
1-Naphthyl N-methylcarbamate (Carbaryl)
*Organophosphorus insecticides:
0- (4-Bromo-2,5-dichlorophenyl)0-methyl phenylphosphono-
thioate (Leptophos) .
4-tert-Butyl-2-chlorophenylmethyl methylphos-
phoramidite.
S-[[(p-Chlorophenyl)thlo]methyl] 0,0-diethyl phos-
phorodithioate (Carbophenothion) .
0,0-Diethyl a-3-chloro-4-methyl-l-oxo-2H-l-benzo-
pyran-7-yl-phosphorothioate (Coumaphos) .
0,0-Diethyl 0- (2-isopropyl-4-methyl-6-pyrimidinyl)-
phosphorothioate (Diazinon) .
0,0-Diethyl 0- [p- (methylsulfinyl)phenyll phosphoro-
thioate (Fensulfothion) .
0,0-Diethyl 0-p-nitrophenyl phosphorothioate
(Parathion) .
0,0-Diethyl 0-3, S,6-trichloro-2 pyridyl phosphoro-
thioate.
0 ,0-Dimethyl 0- [4- (methyl thio) -m- to 1/1] phosphoro-
thioate (Fenthion) .
*0,0-Dimethyl 0-p-nitrophenyl phosphorothioate (Methyl
parathion) .
0,0-Dimethyl S- [4-oxo-l ,2,3-benzotriazin-3(4H) -
ylmethyl] phosphorodlthioate (Azinphosmethyl) .
0,0-Dimethyl S-phthalimidomethyl phosphorodithioate
Dimethyl 2,4 ,5-trichlorophenyl phosphorothionate
(Ronnel) .
2,3-p-Dioxane S,S-bis (0,0-diethylphosphorodithioate)
(Dioxathion) .
0-Ethyl S-phenylethylphosphonodithioate
a-Methylbenzyl 3- (dimethoxyphosphinyloxy) -cis-
crotonate.
0,0,0' ,0'-Tetramethyl O,0'-thiodi-p-phenylene phosphoro
thioate.
All other organophosphorus insecticides
CGY.
OTC.
FMN.
DOW.
ACN.
CGY.
CHF, DUP, NES.
FMC.
MRT.
ORG.
OTC.
ORG.
UCC.
VEL.
DOW.
SFA.
CHG.
CGY.
CHG.
AMP, MON, SFA.
DOW.
CHG.
AMP, MON, SFA, VEL.
CHG.
SFA.
DOW.
SFA.
SHC.
ACY.
ACY, SHC, VEL.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued
•Insecticides- -Continued
N-(Phenyl-2-nitropropyI)piperidine
m-ToIyl-N-methylcarbamate
All other cyclic insecticides
Nematocides :
0,0-Diethyl 0- (2 ,4-dichlorophenyl) phosphorothioate
(Dichlofenthion) .
0,0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionazin)-
*Rodenticides:
3- (a-Acetonylbenzyl) -4-hydroxycoumarin (Warfarin)
2-DiphenylacetyI-l,3-indandione and sodium salt
(Diphacinone) .
2-Pivaloyl-l ,3-indandione (Pindone)
Synergists and adjuvants:
a- [2- (2-m-Butoxyethoxy) -ethoxy] -4 ,5-methylenedioxy-2-
propyltoluene (Piperonyl butoxide) .
N-(2-Ethylhexyl)bicycIo) 2.2.1 )-S-heptene-2, 3-di-
carboximide.
l,2-Methylenedioxy-4-[2- (octylsulfinyl)propylJben7ene--
Piperonal bis [ 2- (2 ' -n-butoxyethoxy) ethyl ] acetal
(Heliotropin acetal).
All other cyclic pesticides and related products
PESTICIDES AND RELATED PRODUCTS, ACYCLIC
•Fungicides :
Bis-1 ,4-bromoacetoxy-2-butene
N,N-Bis (phosphonomethyl) glycine
Cadmium succinate
l-Chloro-2-nitropropane (Korax)
Copper tall ate
Dimethylthiocarbonyl disulfide
Di sodium cyanodithioimidocarbamate
•Dithiocarbamic acid fungicides:
Dimethyldithiocarbamic acid, ferric salt (Ferbam)
Dimethyldithiocarbamic acid, manganese salt
Dimethyldithiocarbamic acid, potassium salt
Ethylene bis(dithiocarbaiiiic acid), diammonium salt —
Ethylene bis(dithiocarbamic acid), disodiun salt
(Nabam) .
Ethylene bis (dithiocarbamic acid), manganese salt
(Maneb) .
Ethylene bis (dithiocarbamic acid), zinc salt (Zineb)-
N-Methyldithiocarbamic acid, sodium salt (SW)C)
All other dithiocarbamic acid fungicides
n-Dodecylguanidine acetate (Dodine)
2-HyJroxypropylmethanethiol sulfonate
Chloromethoxypropylmercuric acetate
Polyethylenethiuram disulfide (PETD)
•Herbicides and plant hormones;
2-Chloroallyl diethyldithiocarbamate (CDEC)
2-Chloro-N,N-diallylacet amide fCDAA)
(2-Chloroethyl)phosphonic acid
S-2,3-Dichloroallyl diisopropylthiolcarbamate
(Diallate) .
2,2-DichIoropropionic acid, sodium salt (Dalapon)
N-Dimethylamino succinamic acid (DMSA)
Dimethylarsinic acid (Cacodylic acid)
Ethyl diisobutyl thiolcarbamated
S-Ethyl N,N-dipropylthiolcarbamate (EPTC)
Ethyl xanthogen disulfide (EXD)
MRK.
OTC.
OTC.
MOT,
PEN.
NES.
MOT,
PIC.
ALP,
BKL,
FMN,
FMP
MGK.
PEN.
MGK.
CHG.
WSN.
VIN.
MON.
MAL.
FMN.
AMP.
CLY.
BKM.
FMN, MAL, VNC.
FMN.
BKM.
RBC.
ALC, FMN, HH, USR.
DUP, RH.
FMN, HH.
SFA.
MAL, VNC.
ACY.
TRO.
FW<.
MON.
MON.
GAF.
MON.
DOW.
USR.
ASL.
SFA.
SFA.
RBC.
PESTICIDES AND RELATED PRODUCTS
TABLE 2, --Pesticides and related products for which U,S, production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNTI NUED
Manufacturers' identification codes
(according to list in table 5)
PESTICIDES AND RELATED PRODUCTS, ACYCLIC--Continued
*Herbicides and plant hormones--Continued
*Methanearsonic acid, disodium salt (DSMA)
*Methanearsonic acid, dodecyl- and octylammonium salt-
*Methanearsonic acid, monosodium salt [MSMA)
S-Propyl butylethylthiocarbamate (Pebulate)
S-Propyl dipropylthiocarbamate (Vernolate)
S,S,S-Tributyl phosphorotrithioate
Tributyl phosphorotrithioite
Trichloroacetic acid, sodium salt (TCA)
S-2,2,3-Trichloroallyl diisopropyl thiol carbamate
(Triallate) .
All other acyclic herbicides
'Insecticides :
2- (2-Butoxyethoxy)ethyl thiocyanate
S-Methyl N- [ (methylcarbamoyl)oxy] thioacetimidate
(Methomyl ) .
•Organophosphorus insecticides :
S-[1,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos-
phorodithioate (Malathion) .
2-Carbomethoxy-l-propen-2yl dimethyl phosphate
(Mevinphos) .
1 ,2-Dibromo-2,2-dichloroethyl dimethyl phosphate
(Naled) .
0,0-Diethyl S-2- (ethylthio)ethyl phosphorodithioate
(Disulfoton) .
0,0-Diethyl 0-2- (ethylthio)ethyl phosphorothioate
(Demeton 0) .
0,0-Diethyl S-(ethylthio)methyl phosphorodithioate
(Phorate) .
3- (Dimethoxyphosphinyloxy)-N,N-dimethyl-cis-
crotonamide (Dicrotophos) .
0,0-Dimethyl 2,2-dichlorovinyl phosphate (Di-
chlorvos) .
0,0-Dimethyl S- [2-ethylsulfinyl)ethyl]phosphoro-
thioate (Oxydemetonmethyl) .
0,0-Dimethyl S- CN-methylcarbajnoylmethyl)phosphoro-
dithioate (Dimethoate) .
Dimethyl phosphate of 3-hydroxy-N-methyl-cis-
crotonamide (Monocrotophos) .
0,S- Dimethyl phosphoramidothioate
0,0,0' ,0'-Tetraethyl S,S' -methylene bisphosphoro-
dithioate (Ethion) .
Tetraethyl pyrophosphate (TEPP)
0,0,0,0-Tetra-n-propyl dithiopyrophosphate
All other ^cyclic insecticides
Nematocides :
0-Ethyl S,S-dipropyl phosphorodithioate
2-Methyl-2(methylthio)propionaldehyde 0- (raethylcarba-
moyl)oxime (Aldicarb) .
Soil conditioners: Polyacrylonitri le, hydrolyzed,
sodium salt
Soil fumigants :
*l,2-Dibromo-3-chloropropane CDBCP)
1 ,3-Dichloropropene
1,3-Dichloropropene, 1 ,2-dichloropropane
*Methyl bromide (Bromomethane)
Methyl isothiocyanate
Trich loronitromethane (Chloropicrin)
All other acyclic pesticides and related products
ASL, CLY, DA, VIN.
CLY, VIN.
ASL, DA.
SFA.
SFA.
PLC.
SM.
DOW.
MON.
RH.
DUP.
ACY.
SHC.
SHC.
CHG.
CHG.
ACY .
SHC.
SHC.
CHG.
ACY.
SHC.
CHG.
FNIN, FMP.
AMP.
SFA.
BFG.
ACY.
BST, DOW, SHC.
DOW.
DOW, SHC.
AMP, DOW, GTL, MCH.
MRT.
DOW.
GAF, PCW, TRO.
SYNTHETIC ORGANIC CHEMICALS. 1972
TARLE 3,— Pesticides and related products: Hirectory of manufacturers^ 1'572
ALPHABETICAL DIRECTORY BY CODE
Names of manufacturers of pesticides and related products that reported production or sales to the U.S. Tariff
Commission for 1972 are listed below in the order of their identification codes as used in table 2]
Code
Name of company
Code
Name of company
ABB
Abbott Laboratories
MAL
Mallinckrodt Chemical Works
ACN
Allied Chemical Corp., Agricultural Div.
MCH
Michigan Chemical Corp.
ACY
American Cyanamid Co.
MCI
Mooney Chemical Corp.
ALC
Alco Chemical Corp.
MGK
McLaughlin, Gormley § King Co.
ALP
Alpha Laboratories, Inc.
MON
Monsanto Co.
AMC
Amchem Products, Inc.,
MOT
Motomoco, Inc.
Div. of Rorer-Amchem, Inc.
MRK
Merck 5 Co., Inc.
AMP
Kerr-McGee Chemical Corp.
MRT
Morton Chemical Co. Div. of Morton-Norwich Products
ARA
Arapahoe Chemical Div. of Syntex Corp.
Products, Inc.
ASL
Ansul Chemical Co.
MTO
Montrose Chemical Corp. of California
NES
Nease Chemical Co., Inc.
BKL
Millmaster Onyx Corp., Millmaster Chemical
Co. Div., Berkeley Chemical Dept.
OMC
Clin Mathieson Chemical Corp., Agricultural Div.
BKM
Buckman Labs., Inc.
ORG
Chevron Chemical Co.
EST
Occidental Chemical Co.
OTC
Story Chemical Corp., Ott Chemical Div.
CCA
Cincinnati Milacron Chemicals, Inc.
PAS
Pennwalt Chemicals Corp.
Gordon Corp.
Pfister Chemicals, Inc.
CGY
Ciba-Geigy Corp. and
PBI
Ciba Agricultural Co.
PCW
CHF
Chemical Formulators, Inc.
PEN
CPC International, Inc., Penick Div.
CHG
Baychem Corp., Chemagro Div.
PFZ
Pfizer, Inc.
CLY
W. A. Cleary Corp.
PIC
Pierce Organics, Inc.
CWN
Upjohn Co., Fine Chemical Div.
PLC
Phillips Petroleum Co.
PPG
PPG Industries, Inc.
DA
Diamond Shamrock Corp.
DOW
Dow Chemical Co.
RBC
Fike Chemicals, Inc.
DUP
E. I. duPont de Nemours § Co., Inc.
RCl
Reichhold Chemicals, Inc.
RDA
Rhodia, Inc.
EFH
E. F. Houghton fi Co.
RH
Rohm § Haas Co.
EGR
Eagle River Chemical Corp.
RIV
Riverdale Chemical Co.
FER
Ferro Corp., Ferro Chemical Div.
Stauffer Chemical Co.;
FIS
Fisher Chemical Co., Inc.
SFA
Agricultural Div.
FMC Corp.:
SFC
Calhio Chemicals, Inc. Div.
FNIN
Niagara Chemical Div.
SHC
Shell Oil Co., Shell Chemical Co. Div.
FMP
Industrial Chemical Div.,
SHP
Shepherd Chemical Co.
Organic Business Group
SM
Mobil Oil Corp., Mobil Chemical Co. Div.,
FMT
Fairmount Chemical Co.
Industrial Chemical Div.
FRO
Vulcan Materials, Co., Chemical Div.
TMH
Thompson -Hayward Chemical Co.
GAF
GAF Corp., Chemical Div.
TRO
Troy Chemical Co.
GOC
Gulf Oil Corp., Gulf Oil
Chemical Co. -U.S.
UCC
Union Carbide Corp.
GTH
Guth Chemical Co.
UOP
Universal Oil Products Co., UOP Chemical Div.
GTL
Great Lakes Chemical Corp.
USR
Uniroyal, Inc., Chemical Div.
IIK
Hooker Chemical Corp.
VAL
Valchem
HN
Tenneco Chemicals, Inc.
VEL
Velsicol Chemical Corp.
Vineland Chemical Co.
HPC
Hercules, Inc.
VI N
VNC
Vanderbilt Chemical Corp.
IMC
International Minerals S Chemical Corp.
WRC
Ventron Corp., Ventron Chemicals
LIL
Eli Lilly 6 Co.
WSN
Mallinckrodt Chemical Works, Washine Div.
WTC
Witco Chemical Co., Inc.
Note. -Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix.
MISCELLANEOUS CHEMICALS
The term miscellaneous chemicals comprises those synthetic organic
products that are not included in the use groups covered by the other
preliminary reports in the 1972 series. They include products that are
employed in a great variety of uses. The number of chemicals used ex-
clusively for only one purpose is not large. Among the products covered
are those used for gasoline and lubricating oil additives, paint driers,
photographic chemicals, tanning materials, flotation reagents, refriger-
ants, textile polymers, sequestering agents, organic fertilizers, anti-
freeze chemicals, solvents, and acyclic intermediates. Table 1 presents
statistics on U.S. production and sales of miscellaneous chemicals in as
great detail as is possible without revealing the operations of individual
producers . ^
Production of miscellaneous cyclic and acyclic chemicals in 1972
amounted to 90.5 billion pounds, or il3-.9. percent more than the output of
79.5 billion pounds reported for 1971. Sales of miscellaneous chemicals
in 1972 amounted to 45.2 billion pounds, valued at $4.7 billion, compared
with 38.4 billion pounds, valued at $4.1 billion in 1971.
The total output of miscellaneous cyclic chemicals in 1972 was 2.4
billion pounds, or 10.7 percent more than the output of 2.2 billion pounds
reported for 1971. Sales in 1972 totaled 1.2 billion pounds, valued at
$423 million, compared with 1.0 billion pounds, valued at $379 million,
in 1971. In 1972, the most important groups of cyclic compounds were the
lubricating oil additives, the output of which was 388 million pounds, and
synthetic tanning materials, the output of which was 53 million pounds.
Total production of miscellaneous acyclic chemicals in 1972 was 88.1
billion pounds, or 14.0 percent more than the output of 77.3 billion pounds
reported for 1971. Sales in 1972 totaled 44.0 billion pounds, valued at
$4.3 billion, compared with 37.3 billion poionds, valued at $3.8 billion,
in 1971. The statistics for acyclic chemicals are grouped primarily by
chemical function. The order of precedence of these functional groups is
generally that used in naming and indexing chemical compounds by Chemtoal
Ah s tracts , but other important considerations are comparability with other
statistics and the need for groupings that will not reveal the operations
of individual producers.
In 1972, the most important groups of acyclic chemicals were the
halogenated hydrocarbons, the nitrogenous compounds, monohydric alcohols,
and aldehydes and ketones. Production of halogenated hydrocarbons, which
are used as solvents, intermediates, refrigerants, and aerosol propellants,
totaled 20.1 billion pounds. The most important chemicals in this group
were dichloroe thane (production of 7.8 billion pounds in 1972 compared with
^ See also table 2 which lists these products and identifies the manu-
facturers by code. These codes are given in table 3.
200
SYNTHETIC ORGANIC CHEMICALS, 1972
7.6 billion pounds in 1971) and vinyl chloride (5.1 billion pounds compared
with 4.3 billion pounds). Output of nitrogenous compounds totaled 15.5
billion pounds. The most important chemical in this group was urea (used
principally in fertilizers and as a feed additive), production of which was
6.9 billion pounds in 1972 and 6.2 billion pounds in 1971.
Monohydric alcohols, which are used largely as solvents and inter-
mediates, were the third largest group in 1972, with production of 12.8
billion pounds. The most important items in the group in terms of pro-
duction were synthetic methanol (6.5 billion pounds in 19 72, compared with
4.9 billion pounds in 1971), synthetic ethyl alcohol (1.8 billion pounds
in 1972, compared with 1.6 billion pounds in 1971) and isopropyl alcohol
(1.8 billion pounds in 1972, compared with 1.7 billion pounds in 1971).
Aldehydes and ketones, which are also used largely as solvents and inter-
mediates, were the next largest group with production of 11.3 billion
pounds. The most important items in this group in 1972 were formaldehyde
(5.6 billion pounds), acetone (1.8 billion pounds) and acetaldehyde
(1.4 billion pounds).
MISCELLANEOUS CHEMICALS
TABLE 1. --Miscellaneous chemicals; U.S. production and sales. 1972
[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published.
(Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no
data were reported.) Table 2 lists all miscellaneous chemicals for which data on production or sales were re-
ported and identifies the manufacturers of each]
Production
Quantity
Grand total
MISCELLANEOUS CHEMICALS, CYCLIC
Total
Benzoic acid, sodium salt
Benzoyl peroxide
Butyl benzoate
tert- Butyl peroxy benzoate
2,6-Di-tert-butyl-p-cresol:
Food grade
Tech
Dioxane (1,4-Diethylene oxide)
Enzymes
4-Ethylmorpholine
Flotation reagents
Gasoline additives
Hexamethylenetetramine, tech
p-Hydroxybenzoic acid esters:
Butyl p-hydroxybenzoate (Butylparaben)
Methyl p-hydro.xybenzoate (Methylparaben)
Propyl p-hydroxybenzoate (Propylparaben)
Lubricating oil and grease additives, total
Oil-soluble petroleum sulfonates, total
Oil-soluble petroleum sulfonates, calcium salt
Oil-soluble petroleum sulfonates, sodium salt
All other
Phenol salts
All other lubricating oil and grease additives
Morpholine
Naphthenic acid salts, total^
Calcium naphthenate
Cobalt naphthenate
Iron naphthenate
Lead naphthenate
Manganese naphthenate
line naphthenate
All other
Photographic chemicals:
2,5-Diethoxy-4-morpholinobenzenedia2onium chloride-
p-Diethylaminobenzenediazonium chloride
N , N- Diethyl toluene- 2 , S-diamine , monohydroch loride- -
p-Dimetnylaminobenzenediazonium chloride
p- [Ethyl (2-hydro.xyethyl)amino]benzenediazonium
chloride
p- [ (2-Hydroxyethyl)methylamino]benzenediazonium
chloride
1,000
pounds
90.476.062
2,411,142
15,266
7,570
5,575
1,542
7,517
17,838
15,768
(2)
1,595
15,979
45,004
95,156
918
391
388,115
228,162
139 458
42,032
46,672
76,092
83,861
1,434
3,295
11,448
959
905
2,489
168
119
1,000
pounds
45,155.471
1,000
do I lavs
4.680.222
pound
1,177,960
12,185
7.443
5.019
1,513
8,471
18,151
6,518
(2)
1,379
13,432
61,724
879
367
80,555
70,062
68,765
64,485
1,366
3,210
105
10,717
967
776
930
141
119
299
3,664
7,002
779
1,685
4,166
8,642
2,159
25,147
1,102
1,693
7,498
50
1,392
690
16,169
10,995
14,120
21,402
6,976
5,320
1,738
25
1,892
258
199
828
801
240
898
147
See footnotes at end of table
SYNTHETIC ORGANIC CHEMICALS. 1972 •
TABLE 1. --Miscellaneous chemicals; U.S. production and sales. 1372— Continued
Production
Quantity
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
a-Pinene
fi-Pinene
Tall oil salts:
Cobalt tallate
Lead tallate
Manganese tallate
Tanning materials, s\'nthetic
Textile chemicals
All other miscellaneous cyclic chemicals
MISCELLANEOUS CHEMICALS, ACYCLIC
Total
Cellulose Esters and Ethers
Total
Cellulose esters: Cellulose acetate
Cellulose ethers: Sodium carboxyraethylcellulose,
100%
All other cellulose esters and ethers
Lubricating Oil Additives
Total
Phosphorodithioates (Thiophosphates)
Sulfur compounds: Sulfurized lard oil
All other
nitrogenous Compounds
Total'
Acrylonitrile
Amines, total
Butylamines:
n-Butylamine, mono-
Di-n-butylamine
Diethyl en etriamine
Ethyl amines , total
Diethylamine
All other
Ethyl enediamine
1 ,6-Hexanediamine (Hexamethylenediamine)
Methylamines :
Dime thy I amine
Methylamine, mono-
Trimethylamine
Propylamines:
Diisopropylaraine
Di propyl amine
Propylamine, mono-
Tetrae thy lenepent amine
Triethylenetetramine
All other
2- (2-Aminoethylamino) ethanol (Aminoethyl-
ethanol amine)
Capro lac tarn
2-Dimethylaminoethanol
1,000
pounds
38,095
1,262
2,002
520
53,040
1,585
1,681,482
88.064,920
1,000
68,962
156,030
67,009
3,316
430,088
1,114,749
1,276,277
4,017
3,842
32,390
55,437
11,079
44,358
95,973
33,063
28,815
18,011
133,622
8,788
640,045
3,533
19,814
29,180
1,256
2,056
542
53,310
504
607,606
43.977,511
1,000
dollars
2,106
4,638
559
406
143
11,207
1,091
259,995
70,991
254,021
21,440
3,128
147,979
459
985
345
803
2
374
3
121
30
176
48,610
8,449
51,522
23,347
23,948
779
14,389
239
12,779
15,466
105,137
6,775
546,486
31.243
116,431
6,009
674
23,824
786,963
49,259
68,768
670
748
9,697
9,696
3,073
4,702
1.984
2,189
165
3,501
183
6,105
5,218
19,853
2,603
96,615
MISCELLANEOUS CHEMICALS
TABLE 1. --Miscellaneous chemicals: U.S. production and sales. 1972— Continued
Production
1,000
MISCELUNEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Compounds- -Continued
Ethanol amines, total
2-Aininoethanol (Monoethanol amine)
2,2'-Aniinodiethanol (Diethanol amine)
2, 2' ,2' ' -Nitrilotriethanol (Triethanol amine)
Hexamethylenediammonium adipate (Nylon salt)
Nitriloacids and salts, total
(Diethylenetrinitrilo)pentaacetic acid, pentasodiun
salt
tEthylenedinitrilo)tetraacetic acid
CEthylenedinitrilo)tetraacetic acid, disodium salt-
(Etliylenedinitrilo)tetraacetic acid, tetrasodium
salt
(N-Hydroxyethylethylenedinitrilo)triacetic acid,
tri sodium salt
All other
Nylon 6 and 6/6 (polymers for fiber, only)
Pentaerythritol tetranitrate
Polyacrylamide
Urea in compounds or mixtures (100% basis), total —
In feed compounds
In liquid fertilizer
In solid fertilizer
All other
All other nitrogenous compounds
Acids, Aoyl Halides and Anhydrides
Total
Acetic acid, synthetic, 100%
Acetic anhydride, 100%
Acrylic acid
Adipic acid
Dodecenyl succinic anhydride
Formic acid, 90%
Furaaric acid
Lauroyl chloride
Maleic anhydride
Pivaloyl chloride
Poly aery lie acid
Propionic acid
All other acids, acyl halides and anhydrides
Salts of Organic Acids
Total
Acetic acid salts, total
Copper acetate
Potassium acetate
Zinc acetate
Zirconium acetate
All other
82,114
101,075
100,742
719,550
3,503
1,292
4,635
48,068
1,547,238
4,099
19,106
6,933,470
679,816
2,531,235
2,633,970
1,088,449
2,803,813
6,668,458
2,235,406
1,572,928
123,195
1,491,405
46,894
51,455
5,469
274,435
981
1,023
56,046
809,223
333,370
282
5,198
457
1,000
pounds
234,454
1,000
dollars
71,788
71,980
90,686
7,682
8,058
11,673
3,062
5,056
3,658
34,305
3,404
14,418
5,999,440
1,550
9,734
2,818
12,377
158,623
611,680
2,168,443
2,489,488
729,829
77S.433
15,418
65,101
64,208
13,896
344,764
570,787
30,211
143,497
2,485
35,348
35,915
190,571
927
38,051
733,516
285,631
28,903
6,596
20,039
1,037
3,574
6,692
25,024
525
3,331
136,154
472
159
25,826
See footnotes at end of table.
SYNTHETIC nRGflNlC CHE'IICALS, 1972
TABLE l.--fllSCELLA»lEOUS CHEniCALS: U.S. PRODUCTION AND SALES, 1972"
-CONTINUED
Quantity
1,000
1,000
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Salts of OTgania Acids — Continued
2-Ethylhexanoic acid (a-Ethylcaproic acid) salts,
total
Calcium 2-ethylhexanoate
Cobalt 2-ethylhexanoate
Lead 2- ethy Ihexanoat e
Manganese 2-ethylhexanoate
Zinc 2-ethylhe xanoat e
All other
Formic acid, sodium salt (tech.)
Gluconic acid, sodium salt
Lactic acid salts
Mercaptoacetic (Thioglycolic) acid, ammonium mercapto-
acetate salt
Oleic acid salts
Propionic acid salts:
Calcium propionate
Sodium propionate
Stearic acid salts, total'"
Aluminum stearates, total
Aluminum distearate
Aluminum monostearate and tristearate
Barium stearate
Calcium stearate
Lithium stearate
Magnesium stearate
Zinc s t eara te
All other
All other salts of organic acids
Aldehydes and Ketones
Total
Acetaldehyde
Acetone, total
From cumene
All other
2-Butanone (Methyl ethyl ketone)
Butyraldehyde
Formaldehyde (37'o by weight)
4-Ilydroxy-4-methyl-2-pentanone (Diacetone alcohol)
4-Methyl-2-pentanone (Methyl isobutyl ketone)
All other aldehydes and ketones
Alcohols, Monahydric, ynsubstituted
Total
Alcohols, C, or lower, unmixed, total
Butyl alcohols:
n-Butyl alcohol (n-Propylcarbinol)
Isobutyl alcohol (Isopropylcarbinol)
Ethyl alcohol, synthetic''
2-Ethyl-l-hexanol
18.715
1,792
3,362
3,469
996
1,233
7,863
31,992
8,915
1,901
1,099
1,286
21,395
4,114
70,123
5,914
2,719
1,195
389
37,793
887
4,767
19,374
2,999
142,193
1,447,566
1,818,373
1,086,012
732,361
509,025
5,651,807
208,263
1,651,669
12,833,473
12,092,504
590,228
96,386
1,850,651
526,125
789
1,028
10,308
31,214
10,765
16,329
3,616
69,722
4,006
2,741
1,265
5
288
18
798
2
332
09
140
1,495,112
929,400
565,712
470,010
50,258
1,820,047
46,482
177,013
764,707
7,627,636
7,004,356
354,720
96,634
1,395,655
332,135
1,000
do I lars
6,982
2,017
237
498
4,230
1,034
2,650
818
3,594
789
25,492
1,690
1,122
568
148
12,570
474
2,211
7,419
980
57,227
23,346
37,981
4,870
35,106
5,670
18,954
60.414
275,478
24,513
4,189
74,912
24,309
MISCELLANEOUS CHE^IICALS
TABLE 1.— Miscellaneous chemicals: U.S. production and sales, 1972— Continued
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Alcohols, Monohydric, Unsubstituted- -Continued
Alcohols, Cg or lower, unmixed--Continued
Hexyl alcohol
Iso-octyl alcohols
Isopropyl alcohol
Methanol, synthetic
1- (and 2-)0ctanol
Propyl alcohol (Propanol)
All other
Alcohols, C,i) and higher, unmixed, total
Isodecyl alcohol
Stearyl and other octadecyl ilccrfiols
All other
Mixtures of alcohols, total
Cg and lower, only
C,|, and higher, only
Cj to Ci2 and others'^
PolyhydHc Aloohols and Their Esters and Ethers
Totalis
Polyhydric alcohols, total
Ethylene glycol
Glycerol, synthetic only
2-Methyl-2,4-pentanediol CHexylene glycol)
Pent aery thritol
Propylene glycol (1,2-Propanediol)
Sorbitol
All other
Polyhydric alcohol esters, total
Ethylene glycol diacetate
All other
Polyhydric alcohol ethers, total
2-Butoxyethanol (Ethylene glycol monobutyl
ether)
2-(2-Butoxyethoxy)ethanol (Diethylene glycol
monoisobutyl ether)
Diethylene glycol
Dipropylene glycol
2-Ethoxyethanol (Ethylene glycol monoethyl
ether)
2- (2-Ethoxyethoxy)ethanol (Diethylene glycol
monoethyl ether)
2- [2- (2-Ethoxyethoxy)etho(ty]eth«Bol (Triethylme
glycol monoethyl ether)
2-Methoxyethanol (Ethylene glycol monoinethyl
ether)
2-(2-Methoxyethoxy)ethanol (Diethylene glycol
monomethy 1 ether)
2- [2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene
glycol monomethyl ether)
Polyethylene glycol
Polypropylene glycol
Tetraethylene glycol
Triethylene glycol
Tripropylene glycol
All other ethers of polyhydric alcohols
1,000
16,296
63,227
1,790,024
6,471,605
13,741
83,095
591,126
204,444
147,029
8,005
49,410
44,928
447,999
43,598
3,761,143
199,216
110,087
562,583
121,370
317,214
237,961
237,961
2,117,239
133,305
24,779
245,492
51,773
205,413
41,156
28,181
119,106
12,666
31,693
52,353
359,238
11,813
105,531
694,740
Quantity
1,000
pounds
AT ,021
911,733
,542,260
10,048
77,036
237,108
117,346
63,819
13,349
40,178
39,763
j6l,644
104,527
5,950,570
,113,931
187,999
38,554
94,058
538,037
91,586
98,626
222.192
5,363
216,829
111,218
16,917
184,406
50,348
103,648
31,366
85,749
9,862
11,162
49,276
6,176
84,716
1,928
818,815
1,000
dollars
4,201
50,753
51.498
1,856
8,272
30,975
19.051
5,564
3,517
9,970
4,979
62,114
9,550
596,329
334,228
186,135
37,167
5,408
15,787
43.746
19,515
26,470
42,273
41.285
219,828
2
668
11
146
4
338
11
777
4
287
9,352
1,217
1,560
10,905
899
9,330
300
136,701
See footnotes at end of table.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 1.— Miscellaneous chemicals; U.S. production and sales. 1972— Continued
Production
Quantity
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Esters of Moriohydria Alcohols
Total
n-Butyl acetate, unmixed
Isobutyl acetate, unmixed
Butyl aery late
tert- Butyl peroxypivalate
Dibutyl maleate
Dilauryl 3, 3'-thiodipropionate
Dioctyl maleate
Distearyl 3,3'-thiodipropionate
Ethyl acetate (85%)
Ethyl aery late
2-EthyI-I-hexyI aery late
Iso-oetyl mereaptoaeetate
Isopropyl acetate
Methyl acetate
Methyl methacrylate, monomer
Phosphorus acid esters, not elsewhere specified —
Propyl acetate
Vinyl acetate
All other
Halogenated Hydrocarbons
Total
Carbon tetrachloride
Chlorinated paraffins, total
35-64% chlorine
Other
Chi orodi f 1 uoromethane .
Chloroethane (Ethyl chloride)
Chloroform
Chloromethane (Methyl chloride)
1,2-Dibromoethane (Ethylene dibromide)
Diehlorodifluorome thane
1,2-Dichloroethane (Ethylene dichloride)
Dichloromethane (Methylene chloride]
1,2-Dichloropropane (Propylene dichloride)
lodomethane (Methyl iodide)
Tetrachloroethylene (Perchloroethylene)
1,1,1-Trichloroethane (Methylchloroform)
Triehloroethylene
Trichlorofluoromethane
Vinyl chloride, monomer (Chloroethylene)
All other halogenated hydrocarbons
All Other MisaelZanecus Acyclic Chemicals
Total
2-Butanone peroxide
tert-Butyl peroxide (Di-tert-butyl peroxide)
Carbon disulfide-,
Epoxides, ethers, and acetals, total
Ethylene oxide
Ethyl ether, tech
Isopropyl ether
Propylene oxide
All other epoxides, ethers, and acetals
1,000
pounds
3,221,170
1,000
125,598
983
9,554
1,355
6,295
1,567
221,983
275,344
45,524
8,495
598,992
59,494
32,439
1,210,703
527,180
20.071.191
996,687
63,453
48,806
14,647
375,513
234,677
453,533
315,523
439,224
7,808,938
471,276
18
734,216
440,681
426,684
299,583
5,088,511
1,722,674
4,774
1,822
767,830
,961,757
69,379
1,520,174
677,782
2,031,099
89,359
27,296
69,224
970
10,161
1,350
5,652
1,459
181,148
99,756
39,452
44,897
2,176
53,238
32,517
943,401
429,043
50,181
15,057
79,982
194,021
202,776
208,020
173,378
418,537
1,446,707
443,334
40,742
723,427
389,028
441,180
286,334
3,343,209
180,285
2,940,623
4,631
1,775
527,636
9,848
("•)
688,026
1,000
dollars
265,586
8,740
2,964
11,809
1,941
1,608
1,022
946
1,125
13,833
15,862
7,980
4,630
177
24,596
3,844
65,868
698.471
54,792
9,112
6,248
2,864
39,202
11,654
13,449
10,661
28,795
101,561
38,927
29,474
527
41,565
35.475
29,458
52,459
132,601
68,759
4,597
1,447
21,002
97,962
30,087
926
66,949
MISCELLANEOUS CHEMICALS
TABLE l.-HlSCELLANEOUS CHEMICALS: U.S. PRODUCTION AND SALES. 1972— CONTINUED
Quantity
Unit
value'
1,000
1,000
pounds
1,000
dollars
MISCELLANEOUS CHEMICALS, ACYCLIC— Continued
All Other Miscellaneous Aayalio Chemicals — Continued
Organo- silicon compounds, total-
Silicon fluids
Other organo-silicon compounds-
Phosgene (Carbonyl chloride)
Sodium methoxide (Sodium methylate)-
Tetraethyllead
Other organo-lead compounds
All other
74,722
114,735
637,043
5,172
302,371
670,105
407,190
52,707
31,096
11,678
8,177
310,834
650,439
189,480
53,167
54,145
1,423
1,797
165,463
349,448
54,858
Per
pound
$1.28
1.01
1.74
.53
.54
' Calculated from rounded figures.
^ Not available.
' Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given
with "Plasticizers."
"* Quantities are given on the basis of solid naphthenate, tallate, or linoleate content.
' Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given
with "Pesticides and Related Products."
^ Ethylcellulose which was formerly included with cellulose ethers is now included with cellulosic plastics
materials.
' Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given with "Surface-
Active Agents."
° Production of urea in primary solution totaled 7,096,187 thousand pounds.
' Includes estimated values for sales of urea in nitrogen compounds.
'° Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are
included with "Surface-Active Agents."
" Statistics en production of ethyl alcohol from natural sources by fermentation are issued by the Department of
Treasury, Bureau of Alcohol, Tobacco, and Firearms.
'^ Of the total production, about 45 percent consisted of alcohols lower than Cjo and about 55 percent consisted,
of alcohols Cio and higher.
'^ Some polyols which are used as intermediates for urethanes have been included with "Plastics and Resin
Materials ."
'" Sales quantity of propylene oxide in 1971 was 237,710,000 pounds (instead of 37,710,000 pounds).
SYNTHETIC ORGANIC CHEniCALS, 1972
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972
[Miscellaneous chemicals for which separate statistics are given in table 1 are marked with an asterisk (*) ;
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not
be published. Hanufacturers ' identification codes shown below are taken from table 3. An x signifies that the
manufacturer did not consent to his identification with the designated product]
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC
6-Acetoxy-2,4-dimethyl-l ,3-dioxane
Acetylcyclohexanesulfonyl peroxide
Adenosine and derivatives
3- t3"-Aminobenzamide)-l- (2' ,4' ,6'-trichlorophenyl) -5-
pyrazole.
2-Aminobenzothiazole
1- (2-Aminoethyl)piperazine
1- (3-Aminopropyl)morpholine
Amyl p- dime thy laminobenzoate
Benzatriazoles , substituted
*Benzoic acid, sodium salt
p- Benzoquinone (p-Quinone )
Benzothiazole
♦Benzoyl peroxide
Biological stains
BisC2,4-dichloroben2oyl) peroxide
1,8- Bis- faimethy 1 amino ^naphthalene
Bis (a,a-dimethylbenzyl) peroxide
2, 4- Bis (4-hydroxy-3,5-di-tert-butylphenoxy)-6-(n-octyl-
thio)-l ,3,S-triazine.
2, 4- Bis (n-octylthiol-6- (4 '-hydroxy- 3' ,5'-di-tert-butyl-
anilino)-l ,3,S-triazine.
Boron fluoride-phenol complex
*Butyl benzoate
p-tert-Butylbenzoic acid, barium bis-salt
2 (and 3)-tert-Butyl-4-methoxyphenol
*tert- Butyl peroxybenzoate
4-tert-Butylpyrocatechol
Camphene
Cellulose acetate phthalate
Centralite-1 (N,N'-Diethyl-N,N'-diphenylurea;'-
Chemical indicators and reagents
Chloramine B (Sodium derivative of N-chlorobenzenesulfon-
amide) .
l-(3-Chlorallyl)-3,S,7-triaza-l-a2oniaadamantane
chloride.
o-Chlorobenzamalononitrile
Chlorophyllin, sodium-potassium- copper
Cumene hydroperoxide
Cyanuric acid
1 ,3-Cyclohexadiene
Cyclohexane sulfamic acid
Cyclohexanone peroxide
Cyclohexene-1 ,2-dicarboxylic acid (Tetrahydrophthalic
acid) disubstituted, polyester salts: Barium and
cadmium salts .
Cyclohexyl chloride
1 ,4-Cyclohexylenedimethanol
Cyclopropane
Cytidine and derivatives
Decahydronaphthaie'-e (Decalinl
Dehydroacetic acid or sodium salt
2,5-Di-tert-amylhydroquinone
l,4-Diazobicyclo(2.2.2)octane
Diazodinitrophenol
2,S-Di (benzoylperoxy)-2,5-dimethylhexane
Di- and tribroraosalicylanilide
Dibroraodimethylhydantoin
CAD, NOC, RCI, IVTC, WTL.
WTL.
niv.
WTL.
PLB.
PUT.
UCC.
JCC.
VND.
CGY.
HN, MON, PFZ, VEL, WSN
EKT.
ACY.
AZT
ACS
CAD
ALD.
WTL.
CGY.
CGY.
ACS.
CPS, PFZ, TCC, VEL.
CCA.
EKT.
AZT, CAD, NOC, WTC, WTL.
BKL, DOW.
GLD, HN, HPC.
OTC.
ACS, EK, FIN, GFS, LAH, NEP.
NES.
DOW.
FIS.
KCH.
ACP, HPC, RCI.
FMB.
ALD.
ABB.
AZT, NOC, WTL.
RCI.
X.
EKT.
OH, TAE.
PLB.
DUP.
GAN, UCC.
EKT.
AIP.
HPC.
WTL.
FIN.
ARA.
MISCELLANEOUS CHEMICALS
TABLE 2.— Hiscellaneous cHEnicALS for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED
Manufacturers' identification codes
[according to list in table 3)
HISCELLANEOUS CHEMICALS, CYCLlC--Continued
2,6-Di-tert-butyl-p-cresol :
*Food grade
*Tech
2,5-Di-tert-butylhydroquinone
Di-tert -butyl diperoxyph thai ate
1 ,3-Dichloro-5 ,5-dimethylhydantoin
Dichloro-s-triazine-2,4,6ClH,3H,SH)trione (Dichloroiso-
cyanuric acid), and salts.
4,4' -Dichloro-3- (trifluoromethyl}carbanilide
2,S-Dihydrothiophene- 1 ,1- dioxide (Sulfolene)
2,2'-Dihydroxy-4,4'-dimethoxybenzophenone
3,S-Dihydroxy-3,S-dimethyl-l,2-peroxycyclopentane
2,6-Dihydroxyisonicotinic acid (2,6-Dihydroxy-4-carboxy-
pyridine) .
2,2'-Dihydroxy-4-methoxyben2ophenone
Diiodomethyl-p-tolyl sul phone
Diisopropyl benzene hydroperoxide
Di i s opropy 1 ere sols
Diketene
p-Dimethoxybenzene (Dinethyl ether of hydroquinone)
2,5-Dimethyl-2 ,4-hexadiene
2 ,6-Dimethylmorpholine
4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyriiiiidinol
Di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyphenyl phos
phonate.
1 ,2-Dioctylcyclobutane-3,4-bis(octaraethyleneisocyanate)--
*Dioxane (1,4-Diethylene oxide)
1 , 3-Dioxolane
Diphenylisodecyl phosphite
Dipropylene glycol salicylate
4 - (Dodecy loxy) - 2-hydroxybenzophenone
*Enzymes :
Hydrolytic:
Amylases
Proteases
Other
Nonh yd ro lytic
1 ,2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether)
Ethyl cellulose phthalate
Ethyl-a-cyano-6-pentyl«innamate
2-Ethylhexyl benzoate
2-Ethylhexyl p- dime thy laminobenzoate
Ethylidene norbomene
*4-Ethylmorpholine
*Flotation reagents:
Dicresylphosphorodithioic acid (Dicresylthiophosphoric
acid) .
Dicresylphosphorodithioic acid, ammonium salt
Dicresylphosphorodithioic acid, sodium salt
2,2'-Dimethylthiocarbanilide (Di-o-tolyl thiourea)
Rosin amines
Tall oil derived
Thiocarbanilide (Diphenyl thiourea)
Furan derivatives:
2-Furaldehyde (Furfural)
Tetrahydrofurfuryl alcohol
Gallic acid
ASH, HPC, KPT, SHC, USR.
ASH, HPC, KPT, PRD, SHC, USR.
EKT.
WTL.
GLY.
FMB.
CGY.
PLC.
GAF.
WTL.
EK.
ACY.
ABB.
HPC.
GIV.
ALD, EKT, FMP.
ASL, EKT, GAF.
BPC.
DOW, UCC.
MRK.
CGY.
DOW, FER, UCC.
FER.
SBC.
DUP, EKT.
BAX,
BAX,
BAX,
MLS,
nup.
EK.
GAF.
X.
VND.
UCC.
BRD,
ACY.
ACY.
KCU.
DUP, RBC.
HPC.
HN.
ACY.
CRN, GPR, MLS, PFZ, mP , RH.
CHH, DOL, MLS, PEN, PFZ, PMP, SPR.
JFR, MLS, PFZ, RH, WBC.
OMS, PLB, SPR.
QKO.
QKO.
SY^ITHETIC ORri/\NIC CHEMICALS. 1972
TABLE 2.--niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED^
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3]
mSCELLANEOUS CHEMICALS, CYCLIC--Continued
♦Gasoline additives:
N,N'- Bis (1,4-dime thy lpentyl)-p-phenylenedi amine —
Butylphenols, mixed
N-sec-Butyl-N-phenylphenylenedi amine
4,4'-Di-5ec-butylaminodiphenylmethane
6-tert-Butyl-o-cresol
2,6-Di-tert-butylphenol
N,N'-Di-sec-butyl-p-phenylenediamine
2,6-Di-tert-butyl-a-dimethylamino-p-cresol
N,N'-Dicyclohexyl-p-phenylenediamine
2, 6- Diethyl aniline
N,N'-Diisopropyl-p-phenylenedi amine
N,N'-Disalicylidene-1 ,2-propanediamine
Methyl eye lopentadienylmanganese tricarbonyl
4,4' -Methylenebis C2,6-di-tert-butylphenol)
4,'4'-Thiobis C6-tert-butyl-o-cresol)
2,2'-Thiobis(6-tert-butyl-p-cresol)
l,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)-
mesitylene.
Other
Glyceryl p-aminobenzoate
Guanosine and derivatives
N-Heptyl-p-hydroxybenzoate
*Hexamethylenetetramine, tech
Homomenthyl salicylate
Hydrab amine hydrobromi de
Hydrindan t in
p-Hydroxybenzoic acid esters:
Benzyl p-hydroxybenzoate
*Butyl p-hydroxybenzoate CButylparaben)
Ethyl p-hydroxybenzoate (Ethylparaben)
n-Heptyl p-hydroxybenzoate [Heptylparaben)
*Methyl p-hydroxybenzoate (Methylparaben)
*Propyl p-hydroxybenzoate (Propylparaben)
Other
N-(Hydroxyethyl)piperazine
2-Hydroxy-4-methoxybenzophenone
Hydroxymethyl dimethyl-5 ,5-hydantoin
2-Hydroxy-3-phenoxytiropane
2- (2-Hydroxy-S-tert-octylphenyl)benzotriazole
1 -Hydroxy- 2-Dyridine (Omadine)
1 ,2,3-Indantrione monohydrate (Ninhydrin)
Inosine and derivatives
2-(p-Iodophenyl)-3- (p-nitrophenyl)-5-phenyl-2H-
tetrazolium chloride.
Isopropyl-o-cresols
'Lubricating oil and grease additives:
*Oil-soluble petroleum sulfonates:
Oil-soluble petroleum sulfonate, ammonium salt--
Oil-soluble petroleum sulfonate, barium salt
*Oil-soluble petroleum sulfonate, calcium salt —
Oil-soluble netroleum sulfonate, magnesium salt-
*Oil-soluble petroleum sulfonate, sodium salt
•Other
*Phenol salts :
Barium alkylphenolates
Calcium alkylphenolates
Calcium salt of octylphenol-formaldehyde
Other '-
All other
p-Menthane
8-p-Menthyl hydroperoxide
p-Methoxybenzylidenemalonic acid, diethyl and
dimethyl esters.
EKT
DOW,
TNA.
X.
X.
TNA
TNA
DUP
EKT. USR, X.
TNA.
X.
TNA.
DUP
EKT, USR.
DUP
SM, TX.
TNA.
TNA.
TNA.
ASH.
TNA.
EKT,
SM, TNA, X.
VND.
PLB.
WSN.
BOR,
DUP, HKD, HN, HMP, PLS, UCC
ARS.
ABB.
HEX.
RSA.
HN,
LEU, WSN.
UN,
W.SN.
WSN.
ARS,
HN, LEM, WSN.
ARS,
HN, LEM, WSN.
WSN.
UCC.
ACY,
GAP.
GLY.
TCH.
ACY.
OMC.
HEX,
PIC.
PLB.
MOR, NTL.
CO, LUB.
CO, ENJ, LUB, DRO, PAR, TX, WTC, x.
CO, LUB.
CO, ENJ, MOR, PAR, SHC, SOC, SOI, WTC.
CO, LUB, TX.
TX.
ORO, TX.
SHC.
CCA, ENJ, GOC, ORO, TX, x.
ATR, ENJ, GOC, LUB. ORO, PLC, SM, TX, UCC.
HPC.
HN, HPC.
ACY.
MISCELLANEOUS CHEMICALS
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table Z)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
4-Methoxyphenol
Methyl o-cresotinate
2,2'-Methylenebis(4-chlorophenol) (Dichlorophene)
Methylenebis(phenoxypropanol)
2,2'-Methylenebis(3,4,6-trichlorophenol) (Hexachloro-
phene) .
Methyl gal late
Methylglucoside
4-Methylmorpholine
Methyl phenyl phosphates
4-Methylpiperazine
l-Methyl-2-pyrrolidone, monomer
*Morpholine
Morpholine salt of p-toluenesulfonic acid
*Naphthenic acid salts:
Aluminum naphthenate
Barium naphthenate
Cadmium naphthenate
*Calcium naphthenate
Chromium naphthenate
Cobalt lead manganese naphthenate
*Cobalt naphthenate
*Iron naphthenate
Lead manganese naphthenate
*Lead naphthenate
Lithium naphthenate
*Manganese naphthenate
Nickel naphthenate
Rare earths naphthenates
Sodium naphthenate
Strontium naphthenate
*Zinc naphthenate
1-Naphthenyl- 2- tallow diamine ^
Ninhydrin
Norcamphor
Octadecyl-3- (3,S-di-tert-butyl-4-hydroxyphenyl)-
propionate.
Organic mercury compounds: Phenylmercuric borate
Phenetole ■■
2-Phenoxyethanol (Ethylene glycol monophenyl ether)
2- (2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl
ether) .
2-Phenoxypropanol
2,2'- (p-Phenylene)diethanol
m-Phenylene isonaph thai amide
Phenyl hydrogen phosphate
5- Phosphorylribose-1 -pyrophosphate
Photographic chemicals:
N-(o-Acetamidophenethyl)-l-hydroxy-2-naphth amide
N- [2- (4-Amino-N-ethyl-m-toluidino)ethyl]methane-
sulfonamide.
2- (4-Amino-N-ethyl-m-toluidino)ethyl sulfate
3-Amino-l,2,4-triazole
Benzotriazole
a-Benzoyl-o-methoxyacetanilide
p-Benzylaminophenol hydrochloride
Catechol
2 - Ch 1 oro- N, N- die thy 1-p-phenylene diamine hydrochloride-
3-Chloro-4-diethylaminobenzenedia2onium salts (p-
Diazo-2-chloro-N,N-diethylaniline salts) .
Chlorohydroquinone
2,4-Diaminophenol dihydrochloride (Amidol)
ARS, ASL, EKT.
TCC.
GIV, GLY.
JCC.
GIV.
HSH.
CRN.
JCC, UCC.
TNA.
UCC.
GAP.
DOW, JCC, UCC.
AMB.
WTC.
CCC, FER, HN. MCI, SHP, TRO, IVTC.
CCC, FER, HN, MCI, TRO, WTC.
CCC, HN, MCI, TX, WTC.
CCC, FER, MCI. SHP, TRO, TX, WTC.
MCI.
CCC, FER, HN, MCI, SHP, WTC.
CCC, FER, HN, MCI, SHP, WTC.
SHP,
CCA.
CCA.
CCA,
MCI.
HN.
CCA,
CCA,
CCA.
CCA,
CCA,
CCA,
CCA.
CCA,
CCA.
CCA.
CCA,
,SM.
HEX.
ALD.
CGY.
TRO.
RSA.
DOW, JCC, TCH.
DOW.
JCC.
EKT.
DUP.
HDG, SM.
PLB.
EKT.
EKT.
EKT.
FHT.
EK, FHT, MRT, SW.
EKT.
EK.
RSA.
IDC.
ESA, FMT.
EK.
VPC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972--C0NT INUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
Photographic chemicals--Continued
2N-(2,4-Di-tert-amylphenoxyacetamido)-4,6-dichloro-
m-cresol .
4-Diazo-2,5-diethox>Tiiorpholinobenzene
4-Diazo-3,5-diethoxythiocresol salts
*2,5-Diethoxy-4-morpholinobenzenediazoniujn chloride-
*p-Diethylaminoben2enediazonium chloride
p-Diethylaminobenzenediazonium fluoborate
p-Diethylaminobenzenediazoniiun fluophosphate
N,N-Diethyl-p-phenylenedi amine hydrochloride
*N,N-Diethyltoluene-2,5-diamine, monohydrochloride —
2,5-Dihydroxy-p-benzenedisulfonic acid dipotassium
salt.
2,S-Dihydroxybenzenesulfonic acid
*p- Dime thy 1 ami nobenzenediazonium chloride
2(p-Dimethylaminostyryl)-5-methylthiadiazole-5-
6-hydrox\'ethochloride.
2,5-Dimethylbenzothiazole
4N- (2' ,6 '- Dime thy lmorpholinyl)benzenediazoni urn
chloride.
p-Diphenylaniinediazonium sulfate
p- (N-Ethylbenzimido)benzenediazonium chloride
*p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium
chloride.
N-Ethyl-N-hydroxye thy 1-p-phenylenedi amine sulfate —
3- (4'-Hexadecenylmonoamidosuccinic acid) -1-hydroxy-
4-sulfo-2-N-n-octadecyl)naphthamide.
Hy droquinone (Hydroquinol)
*p[(2-Hydroxyethyl)inethylamino]benzenediazoniuiii
chloride.
N- C2-Hydroxyethyl)-6-resorcylamide
2-Hydroxynaphthoic alky 1 amide
1- (3-Hydroxyphenyl)urea
4-Methoxy-l-naphthol
p-Methylaminophenol sulfate
5-Methylbenzotriazole
5-Methyl-l,7-dihydroxy-l ,3,4-triazaindolizine
4-Methy 1-2 (p-bis-hydroxyethyl aminos tyryl)thiazole- 3-
B-hydroxye thoch lori de .
4-Methyl-l-phenyl-3-pyrazolidinone
2-Methylthiazoline
4-Morpholinylbenzenediazonium salts
p-Morpholinyl-2 ,5-dibutoxybenzenediazonium chloride-
6-Nitrobenzimidazole
Octylphenyl salicylate
N-Phenyl- (p-phenylene}diamine monohydrochloride
l-Phenyl-3-pyrazolidine
l-Phenyl-3-pyrazolidone
4-Phenylpyrocatechol
1 -Phenyl- 2- tetrazoline-S-thi one
2- (Phenyl thio)quinoline
4N- (l-Pyrrolidyl)-ra-toluenediazonium chloride
2-Resorcylic monoethanol amide
2,2' ,4,4'-Tetrahydroxydiphenyl sulfide
4,4'-Thiodiresorcinol
l-(2,4,6-Trichlorophenyl)-3-(4-nitroanilino)-2-
pyrazolin-5-one.
All other
Phthalic acid, lead salt, dibasic
Picramic acid, sodium salt
Pine oil, synthetic
X.
FMT.
FMT.
ALL, ESA, HST.
ESA, FMT, IDC, MRT.
IDC.
IDC.
EKT.
EKT, FMT, IDC.
EK.
ESA, FMT, IDC.
FMT.
IDC.
F^^T.
FMT.
ESA, FMT, IDC.
EKT.
ESA, FMT, IDC.
MRT.
FMT.
FMT.
X.
EK.
EK.
FMT.
WAY.
FMT.
IDC.
IDC.
EK, FMT.
EKT.
EK.
CCY.
WAY.
X.
EK.
EK.
IDC.
FMT.
FMT.
BKC.
EKT.
EK, ESA, FMT, IDC, NES, x, x.
NTL.
SDC.
GLD.
niSCELLANEOUS CHEMICALS
TABLE 2,--niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972 — CONT INUED
Manufacturers' identification codes
(according to list in table 3)
niSCELLANEOUS CHEMICALS, CYCLIC--Continued
*a-Pinene
*g-Pinene
Pinene, sulfate
Pinene, wood
Piperazine, ethoxylated
Poly-4- (2-acryIoxyethoxy)-2-hydroxybenzophenone
Polydodecylbenzenesulfonic acid, calcium salt
Polyethylene tereph thai ate
Polyphenol esters
Polyvinyl ph thai ate
Propyl gall ate
Pyrogallol (Pyrogallic acid)
2- Pyrrol idinone
Resorcinol monobenzoate
Rosin acid salts :
Aluminum resinate
Calcium resinate
Calcium zinc resinate
Zinc resinate
Salicylanilide
Salicylic acid, lead salt
Salvenol
Sodium cresoxide (Cresylic acid, sodium salt)
Styrene oxide
Sucrose benzoate
Sulfinol blends
Sulfosalicylic acid
Tall oil, chemically modified
Tall oil salts (Linoleic- rosin acid salts):
Calcium manganese tallate
Calcium tallate
♦Cobalt tallate
Copper tallate
Iron tallate
Lead manganese tallate
*Lead tallate
•Manganese tallate
Zinc tallate
All other
Tannic acid
'Tanning materials, synthetic:
Cresol phenol formaldehyde condensate
Hydroxytoluenesulfonic acid, formaldehyde condensate
(Cresol- formaldehyde sulfonate), sodium salt.
1-Naphthalenesulfonic acid, formaldehyde condensate
and salt.
2-Naphthalenesulfonic acid, formaldehyde condensate
and salt.
l-Phenol-2-sulfonic acid, formaldehyde condensate
(Phenol-formaldehyde, sulfonated) .
Styrene-maleic anhydride interpolymer, partial sodium
salt.
All other
Tetrabromobisphenol A
2,3,5,6-Tetrachloro-4- (methylsulfonyl) pyridine
1,2,3,4-Tetrahydronaphthalene (Tetralin)
Tetrahydrothiophene
Tetrahydrothiophene-1 ,1-dioxide (Sulfolane)
Tetrakis [methylene-3- (3' ,5'-di-tert-butyl-4'-hydroxy-
phenol) propionate] methane.
1 ,3,6,8-Tetranitrocarbazole
Tetraphenyltin
ARZ,
ARZ,
HPC.
HPC.
GAF.
ACY.
CO.
DUP,
HON.
EK.
EKT,
HSH,
GAF.
EKT.
HN, NCI.
CBY, GLD, HN, HPC, NCI.
EK, EKT, GYR.
HSH.
MAL.
JMS.
CBY, HN.
CBY.
HN.
FIN, PCW.
NTL.
HPC.
DEX, GOC.
UCC.
VEL.
PLC.
MON, HRK.
ZGL.
CCC, HN, MCI, TRO, WTC.
CCC, PER, HN, MCI, SMP, TRO, WTC.
MCI, SHP.
CCC, FER, HN, MCI, SHP, WTC.
CCC, FER, HN, MCI, SHP, WTC.
MCI.
CCA,
CCA,
CCA,
CCA.
MCI.
CCA,
CCA,
MCI.
WTC.
MAL.
DA.
CGY, DA.
DA.
AKS, GRD, HN, RH.
RH.
DUP.
CGY, HN.
GTL.
DOW.
DUP, UCC.
PAS.
PLC.
CGY.
SDC.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONT INUED
Haoiufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, CYCLIC--Continued
♦Textile chemicals, other than surface- active agents:
Dimethyloldihydroxy ethylene urea
1- [(Octadecyloxylmethyllpyridinium chloride
Phenol, sulfurated
Tetrahydro-3,5-bis(methoxyTnethyi;)-4H-l,3,5-oxadiazin-
4-one (l,3-Bis(niethoxymethyl)uron) .
2,2' ,4,4'-Tetrahydroxybenzophenone
Tri(Phenyloxyme thy l)trimethyloxymethylmel amine
2,2'-Thiobis(4,6-dichlororophenol)
[2,2'-Thiobis(4-octylphenolate)]-n-butylamine nickel---
Thiophene
Thymidine and derivatives
o-Toluidine formaldehyde hydrochloride
Trial lyl cyanurate
3,4' ,5-Tribromosalicylanilide
3,4, 4'-Trichlorocarbanilide
Trimethylaminoethylpiperazine
3,5,5-Trimethyl-2-cyclohexen-l-one (Isophorone)
2,4,6-Trinitroresorcinol and lead derivative
s-Trioxane
Triphenyl phosphite
Triphenyl sulfonium chloride
Triphenyl tin
Triphenyltin phosphine
Uridine derivatives
Vinyl norbornene
l-Vinyl-2-pyrrolidinone, monomer and polymer
l-Vinyl-2-pyrrolidinone - acr>'lic copolymers
l-Vinyl-2-pyrrolidinone - ethylacrylate, copolymer
l-Vinyl-2-pyrrolidinone - methylacrylic acid -
dimethylamine ethyl ester, copolymer.
l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer
l-Vinyl-2-pyrrolidinone - other copolymers
MISCELLANEOUS CHEMICALS, ACYCLIC
Cellulose Esters and Ethers
♦Cellulose esters:
♦Cellulose acetate
Cellulose acetate butyrate
Cellulose acetate propionate
Cellulose propionate
♦Cellulose ethers":
Hydroxyethylcellulose
Hydroxypropylcellulose
Methylcellulose
♦Sodium carboxymethylcellulose, 100%
All other
DUP.
GAP.
DEX.
GAP.
X.
SDH.
ACY.
PAS.
PLB.
RBC.
ACY.
FIN, PCW, SW.
MON.
JCC.
ENJ, UCC.
RBI.
CEL.
MON.
PIS.
X.
X.
PLB.
UCC.
GAP.
GAP.
GAP.
GAP.
GAP.
GAP.
AV, CEL, DUP, EKT.
EKT.
EKT.
CEL.
UCC, X.
X.
DOW.
BUK, DUP, KON, WMP, WYN,
EK, UCC.
MISCELLANEOUS CHEMICALS
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported
IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Lubpioating Oil Additives
*Phosphorodithioates (Thiophosphates) :
Di-2-ethylhexylphosphorodithioic acid
Di-N-propylphosphorodithioic acid
Zinc alkyl dithiophosphate
Zinc dialkyl phosphorodithioate
Zinc di (butylhexyl) phosphorodithioate
Zinc dihexyl phosphorodithioate
Zinc diisopropyl dihexyl phosphorodithioate
Zinc hydrocarbon dithiophosphate
Polybutylene
Sulfur compounds :
Aliphatic hydrocarbon sulfides
Chlorosulfurlzed sperm oil
Phosphosulfurized polybutene
*Sulfurized lard oil
Sulfurized sperm oil and substitutes
Other sulfur compounds
All other
NitTogenous Ccmpounds
Acetamide
Acetamidine hydrochloride
Acetamidoethanol (N-Acetyl-ethanolamine)
Acetonitrile
Acrylomide monomer
*Acrylonitrile
Acyclic isocyanates (complex)
Adiponitrile
1-Allyl- 3- (2-hydroxyethyl) -2- thiourea
Allyltriraethylaimnonium chloride
'Amines:
Allyl amines
Butyl amines :
*n-Butylamine, mono-
*Di-n-butylamine
Diisobutyl amine
tert-Butylamine, mono-
Tri-n-butyl amine
n-Butylethyl amine
Diethylaminoe thy 1 amine
*Diethylenetri amine
N' ,N '- Die thy 1-1, 4 -pent anedi amine (Novoldi amine)
Die thy laminop ropy 1 amine
Dimethylaminop ropy 1 amine
1 ,3- Dime thy Ibutyl amine
Dipropylenetri amine
*Ethylamines :
*Diethylamine
Diethyl amine hydrochloride
Ethylamine, mono
Triethylamine
•Ethylenedi amine
Ethylenedi amine salts
(2-Ethylhexyl) amine, mono-
*1 ,6-Hexanedi amine (Hexamethylenediamine)
3,3'- Imi nob ispropyl amine
SFA.
SFA.
SM.
EN J.
ORG.
ATR, MON.
X.
LUB.
EN J.
LUB.
CCW.
EN J.
CCW, GOC, QCP, WBG.
CCW.
ATR, CCW, ENJ, HK, SM, TX.
ALX, ATR, ENJ, GOC, LUB, MON, NLC, ORG, SM, SOI, UCC,
ACS.
HRK.
RBC.
EKX,
ACY,
ACY,
MOB.
DUP,
FMT,
VAC.
MON, SOH.
SOH.
BFG, DUP, MON. SOH.
MON.
IDC.
SHC.
AIP, PAS, UCC, VGC.
AIP, PAS, UCC, VGC.
AIP, PAS, VGC.
MON, RH.
PAS, VGC.
PAS.
PD.
DOW, JCC, UCC.
SDH.
UCC.
JCC, UCC.
PAS.
UCC.
AIP, PAS, UCC.
BKL, EK.
AIP, PAS, UCC.
AIP, PAS. UCC.
DOW. JCC, UCC.
EK.
VGC.
CEL, DUP, ELP, MON.
JCC.
SYNTHETIC OPnANIC CHEMICALS. 1972
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Coripounds--Continued
* Amines --Continued
Isopropylamines :
*Diisopropylajnine
Isopropylainine , mono-
Methylamines:
*Dime thy 1 amine
Dimethyl amine hydrochloride
Dimethyl amine sulfate
*Methylamine , mono-
Methylamine hydrochloride
*Trimethylamine
n-Octylamine, mono-
Oleylamine
Pentaethylenehexamine
Pentylamines (Amylamines) :
Dipentylamine
Pentylamine, mono-
Tripentylamine
Poly alky lene polyamines
1 ,2-Propanedi amine (Propyl enediamine)
1 , 3- Prop anedi amine (1,3-Diaminopropane)
Propylamines :
*Dipropyl amine
*Propylamine , mono-
Trip ropy lamine
*Tetraethvlenepent amine
N,N,N ,N -Tetramethyl- 1 ,3-butanediamine
Tetramethyle thy lenedi amine
*Triethylenetetramine
Other amines
2 - Amino- 1-butanol
2-Aminoethanol (Monoethanolamine) sulfite
Aminoethoxyethanol
*2- (2-Aminoethylamino)ethanol (Aminoethylethanolamine) -
2-Aminoethyl mercaptoacetate (Monoethanolamine thio-
glycolate) .
2-.'Vmino-2-ethyl-l ,3-propanediol
.^minoguanidine bicarbonate
2-Amino-2- (hydroxymethyl) -1 , 3-propanediol (Tris-
(Hydroxymethyl'jaminomethane) .
2 -Amino- 2- me thy 1-1, 3-propanediol
2-Amino-2-methyl-l-propanol
2-Amino-2-methyl-l-propanol hydrochloride
l.l'-Azobisformamide
2,2'-Azobis[2-methylpropionitrile] (Azobisisobutyro-
nitrile) .
Bilirubin
1,3-Bis (hydroxymethyl)urea (Dimethylolurea)
N,0-Bis ( trimethy 1 si lyl)acet amide
Biuret
N-Bromoacet amide
N-Bromosuccnimide (Succinibromimide)
2-Butanone oxime
But yldiethano lamine
1- Butyl- 3- ethyl -2- thiourea
Butyl Lsocyanate
Butyraldehyde oxime
n-Butyronitrile
*Caprolactam (2-Oxohexamethylenimine)
AIP, PAS, UCC.
AIP, PAS, UCC.
AIP, COM, DUP, GAP.
EK, RSA.
DUP, RH.
AIP, COM, DUP, GAP.
EK, RBC.
AIP, COM, DUP, GAP.
VGC.
X.
JCC, UCC.
PAS,
VGC.
ALB,
PAS.
PAS.
NLC.
UCC.
JCC,
X.
AIP,
PAS,
UCC, VGC.
PAS,
UCC,
VGC.
PAS,
VGC.
DOW,
JCC,
UCC.
UCC.
RH.
DOW,
JCC,
UCC.
ALB.
ALD,
BKL, CGY, DUP, EK, NES, NIL, ONX, PAS, PIC
SNW, UCC, VGC, X.
COfL
EVN,
VND.
JCC.
DOW,
HDG,
JCC, UCC.
EVN,
HAB.
COM.
COM.
COM.
COfL
COM.
VAL.
FMT,
NPI,
USR.
DUP.
PFN.
GLY,
X.
PIC.
DOW.
ARA.
ARA,
SDW.
ACP.
PAS.
PAS.
OWN,
OTC,
UPJ.
ACP.
EKX.
ACP,
CNP,
DEC.
MISCELLAMEOUS CHEMICALS
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Nitrogenous Compounds--Continued
Chlorocholine chloride
2 -Chloro-N,N- dimethyl ethyl amine (Dime thy laminue thy 1
chloride) hydrochloride.
3 - Ch 1 or o-N,N- dimethyl propyl amine
2-Chloro-N,N-dimethylpropylamine hydrochloride
3-Chloro-N ,N-dimethylpropylamine hydrochloride
3-Chloro-2-hydroxypropyltrimethyl ammonium chloride--
Chloro-N- (2-hydroxyethyl)acet amide
N-Chlorosuccinimide (Succinichlorimide)
2-Chloro-N ,N-diethylethylamine hydrochloride
Choline base
Choline bicarbonate
Choline bisulfite
Coco nitrile
Coconut oil acids - ammonium condensate
Coconut oil amide
Creatine and creatinine
Crotononitrile
Cyanoacetic acid
2-Dibutylaminoethanol
1 , 3- Dibuty 1-2- thiourea
1,4-Dicyanobutene
Diethanolamine polyoxypropylene ether
2-DiethyIaminoethanol
2- (2- Diethyl aminoethoxy)ethanol
2-Diethylaminoethyl aery I ate
2-Diethylaminoethyl methacrylate
N,N-Diethyldodecanamide
Diethylhydroxyl amine
1 ,3- Die thy 1-2- thiourea
Diisopropylaminoethanol
N,N- Dimethyl ace t amide
*2-Dimethylaminoethanol
3-Dimethylaminopropionitrile
Dime thy laminoe thy 1 methacrylate
Dime thy 1 amino- 2- prop anol
N,N-Dimethylformamide
1,1- Dime thy Ihydrazine
2,5-Dithiobiurea
Eruc amide
Erucamide - lauraraide
*Ethanolamines :
*2-Aminoethanol (Monoethanolamine)
*2,2 '-Aminodiethanol (Diethanolamine)
*2,2 '2' '-Nitrilotriethanol (Triethanolamine)
Ethanolamine hydrochloride, (60%)
Ethoxylated amides
Ethoxymethoxyp ropy 1 amine
3-Ethoxypropionitrile
2- Ethy laminoe thanol (Ethylmonoethanolamine)
Ethyl carbamate
Ethyl carbodiimide hydrochloride
Ethyl cyanoacetate
N,N' -Ethylene bis (stearamide)
Ethyleneimine, monomer
Ethyleneimine, polymer
Ethylenethiourea
Ethyl isocyanate
Ethy Iraonoethanol amide, mixed
Ethyl thiourea
Fish oil fatty acid amide
ACY.
HEX, HCH.
MCH.
MCH.
OTC.
KF.
ARA.
HEX, MCH.
RH.
TCH.
WAY.
ARC, ASH.
PC.
ARC.
PFN.
KF.
KF.
AAC, PAS.
PAS, RBC.
DUP.
JCC.
AAC, DUP, PAS, UCC.
PAS.
ABC, UCC.
DUP.
EK.
PAS.
PAS, RBC.
PAS, UCC.
DUP.
AAC, PAS, RH, UCC.
ACY.
AAC, ABC.
COM, PAS.
AIP, DUP.
FMP.
ACY.
ASH, FIN, HUH.
FIN.
DOW,
DOW,
DOW,
WSN.
ARC.
JCC.
ACY.
PAS.
FHP.
OTC.
KF.
CTN.
DOW.
DOW.
PAS.
OTC.
PAS.
OTC.
HUM.
GLY, JCC, MAT, OMC, UCC.
JCC, MAT, OMC, UCC.
JCC, HAT, OMC, UCC.
SYNTHETIC ORGANIC CHE1ICALS. 1Q7?
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CONT INUED
Manufacturers' identification codes
(according to list in table 3)
MISCELUVNEOUS CHEMICALS, ACYCLIC- -Continued
Nitrogenous Compounds — Continued
Formamide
Formamidine disulfide dihydrochloride
Glycine (Aminoacetic acid)
Glycine ethyl ester hydrochloride
Glycolonitrile
4-Guanyl-l-nitrosoguanyl-l-tetrazine
*Hexariethylenediajnnionium adipate (Nylon salt)
Hydracrylonitrile (Ethylene cyanohydrin)
2- (Hydroxyraethyl)-2-nitro-l ,3-propanediol (Tris-
(hydroxymethyljnitrome thane) .
N-Hydroxymethylstearamide
12-Hydroxy5tearamide
Imino diacetic acid
Imino diacetic acid, disodium salt
3, 3' -Irainodi- 1,2 -propanediol
Isopropanolamines :
l-Aiiiino-2-propanol (Monoisopropanolamine)
1,1'- Iminodi-2-propanol (Diisopropanolamine)
1 ,1' ,1 ' '-Nitrilotri-2-propanol (Triisopropanolamine)--
3-Isopropoxypropionitrile
3-Isopropoxypropylamine
2-Isopropylaiiiinoethanol
Isopropyl ethyl thionocarbamate
Isopropyl isocyanate
Lactonitrile
Lauronitrile (Dodecyl nitrile)
Methacrylamide
3-Methoxypropyl amine
2-Methylaininoethanol (N-Methylethanol amine)
Methyl carbamate
Methyl cyanoacetate
Methyl a-cyanoacrylate
N,N'-Methylenebis (acrylamide)
N,N'-Methylenebis (octadecan amide)
Methyl isocyanate
2,2'-(Methylimino)diethanol (Methyldiethanolamine)
2-Methyllactonitrile (Acetone cyanohydrin)
2-Methyl-2-nitro-l,3-propanediol
2-Methyl-2-nitro-l-propanol
Methylpo lye thanol amine
N-Methyl taurine
N-Methylurea
*Nitriloacids and salts:
(Diethylenetrinitrilo)pentaacetic acid
{Diethylenetrinitrilo)pentaacetic acid, monosodium
hydrogen ferric salt.
*(Diethylenetrinitrilo)pentaacetic acid, pentasodiura
salt.
(Diethylenetrinitrilo)pentaacetic acid, soditim salt —
N,N-Dihydroxyethylglycine, sodium salt
Ethanoldiglycine, disodium salt
*(Ethylenedinitrilo)tetraacetic acid (Ethylenediamine-
tetraacetic acid).
(Ethylenedinitrilo)tetraacetic acid, calcium disodium
salt.
(Ethylenedinitrilo)tetraacetic acid, diammoniuiii salt--
*(Ethylenedinitrilo)tetraacetic acid, disodium salt
(Ethylenedinitrilo)tetraacetic acid, disodium copper
salt, dihydrate.
(Ethylenedinitrilo)tetraacetic acid, disodium zinc
salt, dihydrate.
DUP.
WAY.
CHT.
BPC.
ACY,
KF.
RBI.
cel
DUP,
MON.
AAE.
COM.
ICI.
HUM
HMP.
HMP.
DUP.
DOW,
UCC.
DOW,
UCC.
DOW,
UCC.
DUP.
DUP.
PAS.
DOW.
OTC.
MON.
ASH.
SOH,
X.
JCC.
UCC.
BKL,
FMP.
KF.
EKT.
ACY,
SOH.
ARC.
UCC.
PAS,
UCC.
RH,
X.
COM.
COM.
GAF.
GAP.
EK,
lil.
DAN,
HMP.
CGY.
CGY,
DOW,
HMP.
CGY,
RPC.
DOW,
HMP.
HMP.
CGY,
DOW,
HMP.
CGY,
DOW.
DOW.
CGY,
DOW,
EK, HMP
CGY,
HMP.
CGY,
DOW,
HUP.
r^ISCELLANEOUS CHE!^ICALS
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Compounds — Continued
*Nitriloacids and salts--Continued
(Ethylenedinitrilo)tetraacetic acid, manganese salt
(Ethylenedinitrilo)tetraacetic acid, monosodium iron
salt.
(Ethylenedinitrilo) tetraacetic acid, tetraajmnonium
salt.
(Ethylenedinitrilo)tetraacetic acid, tetrapotassium
salt.
*(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt--
(Ethylenedinitrilo)tetraacetic acid, trisodium salt
(N-Hydroxye thy lethylenedinitrilo)tri acetic acid
(N-Hydroxyethylethylenedinitrilo) triacetic acid, coppei
salt.
(N-Hydroxyethylethylenedinitrilo) triacetic acid, iron
salt.
(N-Hydroxye thy le thy lenedinitrilo) triacetic acid,
manganese salt.
*(i4-Hydroxyethylethylenedinitrilo)triacetic acid, tri-
sodium salt.
Nitrilotri acetic acid
Nitrilotriacetic acid, disodium salt
Nitrilotriacetic acid, trisodium salt
Nitrilotriacetic acid, zinc salt
Other
2-Nitro-l-butanol
Nitroe thane
Nitromethane
1-Nitropropane
2-Nitropropane
•Nylon, 6 and 6/6 polj-mer for fiber
Octadecyl isocyanate
Oleamide (Octadecene amide)
Oleic acid - ethylenedi amine condensate (amine/acid
ratio=l/2) .
Oleic acid - methanolamine condensate, ethoxylated
Oleonitrile (Octadecene nitrile)
Oleoylhydroxamic acid
Oleoylpalmitamide
*Pentaerythritol tet rani t rate
Pentyl nitrate (Amyl nitrate) 6 hexyl nitrate
*Polyacr>-l amide
Polyacrylamide polymers other than polyacrylamide
Polyacrylonitrile
Polyacrylonitrile, hydrolyzed
Polyalkylene amine-
Polyamide resin (flake)-
Polyglycol amine
Polyoxypropylenediamine
n- Propyl carbamate
Propyl isocyanate
Ricinolamide
Sarcosine (N-Methylaminoacetic acid)
Semicarbazide base
Serai carbazide hydrochloride
Stearamide (Octadecane amide)
Stearic acid - ethylenediamine condensate (amine/acid
ration=l/2) .
Stearonitrile (Octadecanenitrile)
CGY, HMP.
CGY, HUP.
CGY, HMP.
CGY, CRT, DAN, DOW, HMP, HRT, JOR, RPC.
CGY, HMP.
HMP.
HMP.
HMP.
CGY, CRT, DAN, DOW, HMP, RPC.
HMP.
HMP.
DOW,
H^^p
MON
HUP.
DOW,
EK,
HMP,
WAY.
COM.
COM.
COM.
COM.
COM.
ALF,
DBC
DUP
MON.
CWN,
MOB
UPJ
ARC,
ASH
FIN
HUM.
CCW,
GLY
GAF.
ARC,
ASH
CTN.
FIN.
COM,
DUP
HPC
TNA.
ACY,
DOW
HPC
NLC.
ACY.
DUP.
NLC.
NLC.
MON.
UCC.
JCC.
BKL.
OTC.
TKL.
CGY,
HMP
FMT.
FMT.
ARC,
FIN
HUM
CCW,
DA,
GLY,
HUM, ICI
ARC,
ASH
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Nitrogenous Ccmpounds — Continued
Stearylerucamide
Succinimide
Tall oil diethylenetetramine and acetic acid
Tallow amde, hydrogenated
Tallow nitrile
Tallow nitrile, hydrogenated
Tetra functional ketimine
N,N,N' ,N'-Tetrakis (2-hydroxypropyl)ethylenediaiiiine —
Tetrame thy Iguani dine
Tetramethylurea
Thioacetamide
3,3'-Thiodipropionitrile
Thiosemicarbazide
Trisodiumhydroxye thy lethylenedi amine triacetate
*Urea in compounds or mixtures, ino% basis:
*In feed compounds
*In liquid fertilizer
*In solid fertiiieer
In plastics
All other
Urea ammonium nitrate solution
Urea - urethane copolymer
All other nitrogenous compounds
Acids J A(yid Anhydrides ^ and Aayl Halides
*Acetic acid, synthetic, 100%
'Acetic anhydride, 100%:
From acetic acid
From ethylene
*Acrylic acid
*Adipic acid
Azelaic acid
Behenic acid
Bromoacetic acid
Bromobuty ri c acid
2 - Bromodode canoi c acid
a-Bromo (mixed^ luric stearic acid
1,3-Butylene glycolbiborate hexylene glycol boric
anhydride .
tert-Butylperoxymaleic acid
Butyric acid
Butyric anhydride
Castor oil fatty acids, dehydrated
Chloroacetic acid, mono-
FIN.
ASH.
ACY.
ARC.
ARC, ASH.
ARC, ASH.
CNM.
VYN.
ACY.
OTC.
EK, RBC.
ACY.
ACY, FHT.
CGY.
ACN, AGY, FTX, GCC, HKY, ICI, JDC, MSC, PPC, SOH, TER,
TRI, VLN, WYC.
ACN, AGY, AIP, AKL, CFA, CHN, CNC, FCA, FTX, GCC, HKY,
HPC, ICI, JDC, MSC, CMC, PLC, PPC, SHC, SNI. SOH,
TER, TRI, VLN, WYC
ACN, AGY, AKL, ARM, COL, DUP, GCC, HPC, ICI, JDC, MSC,
OMC, PPC, SHC, SNO, SOH, TER, TRI, VLN, WYC.
ACN, BOR, DUP, TRI.
ACN, AIP, DUP, HPC, SHC, SNO, TER, WYC.
WYC.
DUP.
AAC, ALB, ALD, CGY, CHP, COM, CTN, DUP, EK, EVN, FIN,
FIS, FMP, FMT, GAF, GNM, HEX, HUM, IDC, JCC, KF,
LIL, MAL, MCH, MRK, NFS, NOR, PD, PEN, PFZ,
PIL, RSA, S, SDW, SM, SNW, TNA, VND, WTH, x.
GEL,
UCC.
BFG,
AGP,
EMR.
ASH.
MCH.
GTL.
DUP.
DUP.
USB.
WTL.
GEL,
EKT.
BOR, CEL, EKT, FMP, MON, PUB, UCC.
EKT, FMP.
CEL, DBC, UCC.
CEL, DBC, DUP, ELP, MON, RH.
NTL.
, DOW, HPC.
MISCELLANEOUS CHEMICALS
TABLE 2,— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--CoNT INUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Acids, Acid Anhydrides, and Aery I Hatides — Continued
Chloroacetyl chloride
Citric acid
Crotonic acid (2-Butenoic acid]
Decanoyl chloride
Dimer acid (C-36 aiphatic dibasic acid]
Dime thy Ipropionic acid
Di-n-propylacetic acid and chloride
Dipropylma Ionic acid
Dodecanedioic acid
*Dodecenyl succinic anhydride
Dodecyl succinic anhydride
Erucic acid
Ethyl 3- (Chlorofonnyl)propionate
2-Ethylbutyric acid (Diethylacetic acid)
2-Ethylhexanoic acid (a-Ethylcaproic acid)
2-Ethylhexanoyl chloride
'Formic acid, 90%
*Fumar i c acid
Gluconic acid, tech
G lut ari c anhydr i de
Glycolic acid (Hydroxyacetic acid)
n-Hexadecenylsuccinic anhydride
n-Hexanoic acid
1 - Hydroxye thy 1 idene- 1,1- diphosphoni c acid
Isethionic acid (2-Hydroxyethanesulfonic acid)
Isoascorbic acid
Isobutyric acid
I s obuty ri c anh ydride
Isobutyryl chloride
Is o-octadecenyl succinic anhydride
Iso-octanoic acid
Itaconic acid (Methylenesuccinic acid)
2-Keto-D-gluconic acid
Lactic acid
*Lauroyl chloride
Levulinic acid
Maleic acid
*Maleic anhydride
Malic acid
Malonic acid
Mercaptoacetic acid (Thioglycolic acid)
3-Mer cap t op rop ionic acid
Mercaptosuccinic acid (Thioraalic acid)
Methacrylic acid
Methanesulfonic acid
Methane su If onyl chloride
2-Methylvaleric acid C2-Methylpentanoic acid)
Neodecanoic acid
Neodecanoyl chloride
Neoheptanoic acid
Neopentanoic acid
Nonanoic acid (Pelargonic acid)
Nonenylsuccinic anhydride
Octadecenyl succinic anhydride
Octanoyl chloride
Octenylsuccinic anhydride
Oleoyl chloride
Oxalic acid
PalmitoyI chloride
Peroxyacetic acid
DOW,
WTC.
MLS,
PFZ, WTC
EKT.
WTC,
WTL.
AZS.
COM.
CTN.
CTN.
DUP.
ACS,
HMY, MON.
HN.
ASH.
ABB.
UCC.
EKT,
UCC.
WTC,
WTL.
CEL,
DUP, UCC
ACS,
HN, MON,
PFZ,
USS.
PFZ,
PMP.
UCC.
DUP,
SNW.
HMY.
UCC.
WAY.
GAF.
MRK,
PFZ.
EKT.
EKT.
WTC,
WTL.
HMY.
UCC.
PFZ.
MRK.
CLN,
MON.
GAF,
HK, ONX,
TEK,
UOP, WTC, WTL
QKO.
ACS,
PEN, PFZ
ACS,
HN, KPT,
MON,
PTT, RIG, USS
ACS,
EK.
KF.
EVN,
HAB.
EVN.
EVN.
DUP,
RH.
EK,
PAS.
PAS.
UCC.
EN J.
WTC,
WTL.
ENJ.
EN J.
EMR,
GIV.
HMY.
HMY.
HK.
HMY.
GAF,
HRT, UOP
ACS,
PFZ.
GAF,
OPC, PD,
UOP.
FMB,
UCC.
552-743 O - 74 - 15
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.-niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED.
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Aoids, A<yid Anhydrides, and Aayl Halicfes— Continued
•Pivaloyl chloride
*Poly aery lie aeid
Polygalacturonic acid
♦Propionic acid
Propionic anhydride
Propionyl chloride
Sebacic acid
Stearoyl chloride
Succinic acid
Succinic anhydride
Tetrahydroxysueeinic acid (Dioxytartaric acid)
Tetrapropenylsuccinie acid
Thioacetic acid
Thiolactic acid
3,3'-Thiodipropionic acid
Trichloroacetic acid
Valeric aeid
All other
Salts of Organic Adds
♦Acetic acid salts:
Aluminum acetate
Anraionium acetate
Barium acetate
Cadmium acetate
Calcium acetate
Chromium acetate
Cobalt acetate
*Copper acetate
Lead acetate
Lead sub acetate
Lead tetraacetate
Magnesium acetate
Manganese acetate
Mercuric acetate
Nickel acetate
♦Potassium acetate
Silver acetate
Sodium acfttate
Sodium di acetate
Strontium acetate
♦Zinc acetate
♦Zirconium acetate
Other acetic acid salts
Acrylic acid, sodium salt
Adipic acid, ammonium salt
Allylsulfonic acid, sodium salt
Chloroacetic acid, sodium salt
Citric acid salts:
Ammonium citrate
Calcium citrate
Disodium citrate--
Ferric ammonium citrate
Ferric citrate
Potassium citrate
Sodium citrate
Other citric acid salts
Manufacturers' identification codes
(according to list in table 3)
AZT, WTC,
WTL.
AAE, DA,
RH.
SKG.
CEL, COM,
EKT,
UCC.
EKT, UCC.
EK, UOP.
RH, WTH.
EK, UOP.
ACS.
ACS, ORO
ACY.
TX.
EVN.
EVN.
CCW, EVN
DOW.
UCC.
ALD, CTN
EK,
EN J,
ACY,
UCC.
ACS,
BKC,
HAL.
ACS,
BKC,
MAL.
MAL,
SHP.
ACS,
MAL.
VAL.
HSH,
SHP.
ACS,
BKC,
SHP,
UCC.
BKC,
MAL.
ACS,
BKC,
MAL.
ARA.
ACS,
BKC.
HSH,
NES,
SHP.
HAL.
BKC,
HSH,
SHP.
ACS,
BKC,
MAL,
SFI,
UCC,
WSN.
MAL.
ACS,
BKC,
DAN,
EKT,
MAL,
UCC, WSN
UCC.
BKC.
ACS,
BKC,
HSH,
MAL,
SHP,
UCC.
CHP,
HSH,
NTL,
TZC.
CCW,
LIL,
MHI.
AAE.
FIS.
SAL,
X.
DOW
MAL
PFZ
PFZ
WSN
PFZ
MAL
MLS
PFZ
MLS
PFZ
SNW
CHP
EK,
HAL.
MISCELLANEOUS CHEMICALS
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Salts of Ovganio ;l^£^--Continued
Dibutyltin bisCisooctyl thioglycolate)
*2-Ethylhexanoic acid (a-Ethylcaproic acid) salts:
Aluminuin 2-ethylhexanoate
Barium 2-ethylhexanoate
Cadmium 2-ethylhexanoate
*CaIcium 2-ethylhexanoate
*Cobalt 2-ethylhexanoate
Copper 2-ethylhexanoate
Iron 2-ethyIhexanoate
*Lead 2-ethylhexanoate
*Manganese 2-ethylhexanoate
Nickel 2-ethylhexanoate
Rare earths 2-ethylhexanoate
*Zinc 2-ethylhexanoate
Zirconium 2-ethylhexanoate
Other
Formic acid salts:
Aluminum formate
Ammonium formate
Calcium formate
Chromic formate
Lead formate
Sodium formate, refined
*Sodium formate, tech
Thallous formate
Glucoheptonic acid salts:
Sodium glucoheptonate
Gluconic acids salts:
Ammonium gluconate
•Sodium gluconate
Glycolic acid, sodium salt
9H-Hexadecaf luorononanoic acid, ammonium salt
Humic acids, sodium salt
Isoascorbic acid, sodium salt
*Lactic acid salts:
Ammonium lactate
Calcium lactate
Sodium lactate
Other
Laurie acid salts :
Barium cadmium laurate
Dibutyltin di laurate
Zinc laurate
Linoleic acid salts:
Calcium linoleate
Cobalt linoleate
Copper linoleate
Lead manganese linoleate
Manganese linoleate
Maleic acid salts:
Dibutyltin maleate
Lead Ctribasic) maleate
Other maleic acid salts
*Mercaptoacetic acid (Thioglycolic acid) salts:
Ammonium mercaptoacetate
Antimony mercaptoacetate
Calcium mercaptoacetate
Dibutyltin bis iso-octyl mercaptoacetate
Dibutyltin mercaptoacetate
Potassium mercaptoacetate
Sodium mercaptoacetate
PFZ,
CCA,
WTC.
PFZ.
CCA,
PFZ.
CCA,
CCC,
FER
HN,
MCI
PFZ
SW,
TRO
CCA,
ccc.
FER
HN,
MCI
SW,
TRO,
WTC
CCA.
CCA,
HN.
CCA,
CCC,
FER
HN,
MCI
OTL
SW,
WTC
CCA,
CCC,
HN,
MCI,
SW,
WTC.
MCI,
SW.
CCA.
CCA,
FER,
HN,
MCI,
SW,
WTC.
CCA,
FER,
HN,
TRO.
CCA.
WTC,
x.
WSN.
ACS,
RSA.
COM.
GAF.
NTL.
ACS,
BKC.
COM,
CEL,
HPC
PFZ.
PFZ,
PMP,
DUP.
NLC.
MRK.
TCC.
SHF.
REH,
CCA,
CCA.
CCW,
SNW.
CCA.
SHP.
SHP.
SHP.
SHP.
EVN.
CCA.
EVN.
X.
CCA.
EVN.
EVN.
PMP, SFI.
SAL.
PFN.
CCW, PFN, REH, SNIV. WTC.
HAB. TNI.
SYNTHETIC ORGANIC CHEMICALS. W72
TABLE 2,--MlSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Ccintinued
Salts of Organic Aaids — Continued
Mercaptopropionic acid, dibutyltin salt
Methacrylic acid, sodium salt
Neodecanoic acid salts:
Cadmium neodecanoate
Calcium neodecanoate
Cobalt manganese neodecanoate
Cobalt neodecanoate
Lead cobalt neodecanoate
Lead neodecanoate
Lithium neodecanoate
Manganese neodecanoate
Stannous neodecanoate
Vanadium neodecanoate
Zinc calcium cobalt neodecanoate
Zinc neodecanoate
Zirconium neodecanoate
Octanoic acid (Caprylic acid) salts:
Aluminum octanoate
Barium cadmium octanoate
Stannous octanoate
Zinc octanoate
Other
*01eic acid salts :
Aluminum oleate
Ammonium oleate
Chromium oleate
Copper oleate
Lead oleate
Stannous oleate
Other oleic acid salts
Oxalic acid salts :
Ammonium oxalate
Ferric ammonium oxalate
Ferric oxalate
Ferrous oxalate
Potassium oxalate
Sodium oxalate
Palmitic acid salts:
Aluminum pa Imitate
Zinc palmitate
other
Phosphorodithioic acid salts (Dithiophosphates) :
Potassium dihexyl phosphorQdithioate
Sodium di-sec-butyl diethyl phosphorodithioate
Sodium di-sec-butyl phosphorodithioate
Sodium diethyl phosphorodithioate
Sodium dihexyl phosphorodithioate
Sodium diisopropyl phosphorodithioate
Polyacrylic acid salts:
Ammonium poly aery late
Sodium ammonium polyacrylate and copolyers
Sodium polyacrylate
Polymeth aery lie acid, sodium salt
Propionic acid salts:
*Calcium propionate
* Sodium propionate
Ricinoleic acid silts:
Calcium ricinoleate
Lithium ricinoleate
Sodium ethyl oxalacetate
Sodium polypectate
CCA.
AAE.
CCA.
CCA, MCI.
MCI.
MCI.
MCI.
CCA, MCI.
MCI.
MCI.
MCI.
MCI.
MCI.
CCA, MCI.
MCI.
DA.
CCA
CCW, x.
BKC.
DA.
KTC.
ARS.
SHP.
SHP, WTC.
NOC, SHP.
CCW, X.
CHP, TRO, WTC.
ACS, PFZ.
PFZ.
PFZ.
BKL.
BKC, PFZ.
BKC.
DA, WTC.
ACY, DA, WTC.
DA.
ACY.
ACY.
ACY.
ACY.
ACY.
ACY.
BFG.
BFG.
ALC, BFG, DA, JOR, RH.
GRD.
HFT, PFZ, UCC, WSN.
HFT, PFZ, UCC, WSN.
NIL.
NTL.
FMP.
SKG.
MISCELLANEOUS CHEMICALS
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Salts of Organic Acids — Continued
Sodium soribitol borate
♦Stearic acid salts:
'Aluminum stearates:
* Aluminum distearate
♦Aluminum monostearate
♦Aluminum tristearate
Ammonium stearate
♦Barium stearate
Cadmium stearate
♦Calcium stearate
Copper stearate
Ferrous stearate
Lead stearate
Lead stearate, dibasic
♦Lithium stearate
♦Magnesium stearate
Nickel stearate
Silver stearate
♦Zinc stearate
All other
Succinic acid, sodium salt
Sulfosuccinic acid, trisodium salt
Tartaric acid salts:
Antimony potassium tartrate
Potassium sodium tartrate
Sodi urn bit art rate
Valeric acid, ammonium salt
Xanthic acid salts:
Potassium amylxanthate
Potassium ethylxanthate
Potassium hexylxanthate
Potassium isopropylxanthate
Potassium pentylxanthate
Sodium n-butylxanthate
Sodium sec-butylxanthate
Sodium ethylxanthate
Sodium isobutylxanthate
Sodium isopropylxanthate
All other salts of organic acids
Aldehydes and Ketones
♦Acet aldehyde
♦Acetone :
♦From cumene
From isopropyl alcohol
Other
Acetone, crude
Acrolein (Acrylaldehyde)
Aldol (Acetaldol)
♦2-Butanone (Methyl ethyl ketone)
♦Butyraldehyde
Chloral (Trichloroacetaldehyde)
5-Chloro-2-pentanone
l-Chloro-l-penten-3-one (6-Chlorovinyl ethyl ketone) -
Chloro-2-propanone (Chloroacetone)
Crotonaldehvde
DA,
DA,
NOC
ACY
NOC
NOC
, DA, JTC, MAL, NOC, PEN, SYP, WTC.
JTC, HAL, NOC, SYP, WTC.
JTC, MAL, NOC, PEN, SYP.
NOC, WTC.
NOC, PEN, SYP.
, SYP, WTC.
, DA, HN, JTC, MAL, NOC, PEN, SYP, WTC.
. WTC.
NOC, WTC.
NOC, PEN, SYP, WTC.
, DA, JTC, MAL, NOC, PEN, SYP, WTC.
DA, HN, JTC, MAL, NOC, PEN, SYP, IVTC.
NOC, SYP, VAL.
ACY
WTC
PEN
ACY
DA,
MAL.
STP.
PFZ.
PFZ.
PFZ.
RSA.
DOW.
DOW.
DOW.
DOW.
ACY.
KCC, USR.
DOW.
DOW.
DOW.
DOW.
ACY, AID, CCA, CHP, CRN, CTN, DA, DUP, EK, EVN, JCC,
KCH, MCI, NTL, PFN, RSA, SFA, SYP, UCC, x.
CEL, DlIP, EKT, EKX, PUB, SHC, UCC.
ACP, CLK, DOW, GP, MON, SHC, SKO, SOC, UCC, USS.
EKT, EN J, SHC, UCC.
CEL, DIX, HPC.
OCC.
SHC, UCC.
UCC.
ATR, CEL, DIX, ENJ, SHC, UCC.
CEL, EKX, UCC.
DA, MTO.
SDW.
ABB.
EK, MRK.
CEL, EKT. UCC.
SYNTHETIC ORGANIC CHEf^ICALS. 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3]
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Aldehydes and Ketones — Continued
l,3-Dihydroxy-2-propanone (Dihydroxyacetone)
Diisopropyl ketone (2,4-Diinethyl-3-pentanone]
2-Ethylbutyraldehyde
Ethyl crotonaldehyde
2-Ethylhexanal (a-Ethylcaproaldehyde)
•Formaldehyde (37% by weight)
Glutaraldehyde
Glyoxal
2-Heptanone (Methyl amyl ketone)
3-Heptanone (Ethyl butyl ketone)
Hexaldehyde
2,5-Hexanedione (Acetonylacetone)
*4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol)
Isobutyraldehyde
Isopentaldehyde, mixed isomers
Isovalerone (Diisobutyl ketone)
Lac tide (3,6-Dimethyl-2,5,p-dioxanedione)
4-Methoxy-4-methyl-2-pentanone
2-Methylbutyraldehyde
5-Methyl-2-hexanone (Methyl isoamyl ketone)
Methylhexenone
*4-Methyl-2-pentanone (Methyl isobutyl ketone)
Methylpentenal
4-Methyl-3-penten-2-one (Mesityl oxide)
2-Methylvaleraldehyde (2-Methylpentaldehyde)
3-Octanone (Ethyl amyl ketone)
Paraformaldehyde
Paraldehyde (Paracet aldehyde)
2,4-Pentanedione (Acetylacetone)
2-Pentanone (Methyl propyl ketone)
3-Pentanone (Diethyl ketone)
Propionaldehyde
Tetrahydropseudoionone
2,6,8-Trimethyl-4-nonanone (Isobutyl heptyl ketone)--
Valeraldehyde
All other
Alcohols, Monohydria, Unsubstituted
•Alcohols C or lower, unmixed:
Allyl alcohol
Amyl alcohols :
2-Methyl-l-butanol
2-Methyl-2-butanol (tert-Amyl alcohol)
1-Pentanol
Butyl alcohols:
Primary :
*Iso (Isopropylcarbinol)
•Normal (n- Propylcarbinol)
Secondary (Methylethylcarbinol)
Tertiary (Trimethylcarbinol)
2,6-Dimethyl-4-heptanol (Diisobutylcarbinol)
•Ethyl alcohol, synthetic
2-Ethyl-l-butanol
*2-Ethyl-l-hexanol
2-Ethyl-4-methyl-l-pentanol
4-Ethyl-l-octyn-3-ol
BAX.
EKX.
UCC.
UCC.
EKX, UCC.
ACN, BOR, CBD, CEL, COM, DUP, GAP, GOC, GP, HKD, HN,
HPC, MON, RCI, RH, UCC, WCL.
UCC.
UCC.
UCC.
UCC.
UCC.
ARS.
CEL, SHC, UCC.
EKX, UCC.
UCC.
UCC.
CLN.
SHC.
UCC.
EKT, UCC.
UCC.
EKT, ENJ, SHC, UCC.
UCC.
SHC, UCC.
UCC.
SHC.
CEL, HN.
UCC.
UCC.
UCC.
HEX, CRT.
EKX, UCC.
CEL.
UCC.
UCC.
ALD, ARC, EK, CRT, UCC.
CPS, UCC.
ENJ, SHC.
UCC.
CEL, DBC, EKX, OXC, SHC, UCC.
CEL, CO, DBC, EKX, OXC, SHC, TNA, UCC.
CEL, ENJ, SHC.
SHC, X.
UCC.
EKX, ENJ, GP, HPC, PUB, SHC, UCC, USl.
UCC.
CEL, DBC, EKX, OXC, SHC, UCC.
EKX.
AIP.
MISCELLANEOUS CHEMICALS
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Alcohols, Monohydpia, Unsuhstituted — Continued
*Alcohols C or lower, unmixed--Continued
Heptyl alcohol---
*Hexyl alcohol
Hexynol
Isononyl alcohol
*l50-octyl alcohols
* I sop ropy 1 alcohol
*Meth anol , synthet i c
Methyl «"yl alcohol
3-Me'thyl-l-butanol
2-Methyl-3-butyn-2-ol
2-Methyl-l-pentanol
4-Methyl-2-pentanol (l-Methylisobutylcarbinol)
3-Methyl-l-pentyn-3-ol (Methylparafynol)
*1 -Oct anol
*2-0ctanol (sec-Capryl alcohol)
3-Pentanol
'Propyl alcohol (Propanol)
2-Propyn-l-ol
1-Tetradecanol (Myristyl alcohol)
All other
'Alcohols, C,5 or higher, unmixed:
1-Decanol
Dodecyl alcohol (Lauryl alcohol) (95%)
*l-Hexadecanol (Cetyl alcohol) (95%)
Hexadecyl alcohols, other
*Isodecyl alcohol
*I-Octadecanol (Stearyl alcohol) (95%)
cis-9-Octadecen-l-ol (Oleyl alcohol)
1-Tridecanol
2,6,8-Trimethyl-4-nonanol
All other
'Mixtures of alcohols:
*C, and lower only:
Amyl alcohols
Other
'Cjj and higher only
'Cj to C,2 and others
Polyhydria Alcohols and Their Esters and Ethers
*Pclyhydric alcohols:
1,2 (and l,3)-Butanediol
1,4-Butanediol
2-Butene-l,4-diol
2-Butyne-l,4-diol
3-Chloro-l,2-propanediol (Glycerol-a-chlorohydrin)
1,10-Decanediol
2,5-Dimethyl-2,5-hexanediol
2,5-Dimethyl-3-hexyne-2,5-diol
2,2-Dimethyl-l,3-propanediol (Neopentyl glycol)
'Ethylene glycol
2-Ethyl-l,3-hexandiol
2-Ethyl-2-(hydroxymethyl)-l,3-propanediol (Tri-
methylol propane) .
'Glycerol, synthetic-
ENJ, TID, USS.
EN J, SHC, UCC.
AIP, BOR, CEL, DIJP, GP, HN, HPC, HON, RH, UCC.
CO, EKX, ENJ, TNA, UCC.
AIP.
ENJ.
AIP
ATR
ACN
UCC
UCC.
AIP.
UCC.
SHC.
AIP.
CO, PG, WTH.
RH.
EK.
CEL, EKX, UCC.
GAP.
CO, PG.
ALD, EKX, GYR, LIL.
CO,
PG.
CO,
PG.
ASH
CO,
GIV,
PG.
ENJ
AIP
ENJ
TID
, UCC, USS.
ASH
CO,
PG.
ASH
DUP
ENJ,
UCC
UCC.
UCC.
ENJ.
CEL
EKX
PUB
, UCC.
ASH
CO,
ENJ,
PG, SHC, TNA, UCC.
CO,
EKX,
PG,
SHC, TNA.
CEL.
GAP.
GAP.
GAP.
EVN,
FIS.
AIP.
AIP.
EKX.
CAU, CEL, DOW, DUP, EKX, GAP, JCC. MAT, NWP, OMC, PPG,
SHC, UCC, IfYN.
UCC.
CEL.
DOW, FMP, ICI, SHC.
SYNTHETIC ORGANIC CHE^IICALS> 1972
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Polyhydria Alcohols and their Esters
and Ethers — Continued
*Polyhydric alcohols--Continued
1 ,6-Hexanediol
2- (Hydroxymethyl)-2-methyl-l ,3-propanediol (Tri-
methylolethane) .
Mannitol
3-Mercapto-l ,2-propanediol (Thioglycerol)
*2-Methyl-2,4-pentaiiediol (Hexylene glycol)
2-Methyl-2-propyl-l ,3-propanediol
*Pentaerythritol
1,5- Pent anediol
♦Propylene glycol Cl,2-Propanediol)
♦Sorbitol
2,2,4-Triiiiethyl-l,3-pentanediol
All other
♦Polyhydric alcohol esters:
1,3- But anediol dimethacrylate
2, (2-Butoxyethoxy)ethyl acetate
2-Butoxyethyl acetate
Diethylene glycol, borated
Diethylene glycol chlorofomate
2-Diisopropylaiiiinoethyl me th aery late
2- (2-Ethoxyethoxy)ethyl acetate
2-Ethoxyethyl acetate
♦Ethylene glycol diacetate —
Ethylene glycol dimercaptoacetate
Ethylene glycol dimethacrylate
Ethylene glycol hydroxyacetate
2-Ethyl-2- (hydroxymethyl)-i,3-propanediol tr-
methacrylate.
Glyceryl diacetate (Diacetin)
Glyceryl monoacetate (Monoacetin)
Glyceryl triacetate (Triacetin}
Glyceryl trioleate
Glycol adipate
Hexylene glycol diacetate
Lanolin acetate
2-Methoxyethyl acetate
2-Methoxyethyl carbonate
Methoxytriethyleneglycol acetate
Pen t aery thritol caprylatST
Pentaerythritol pelargonate
Pent aery thritol stearate
Pentaerythritol tetrakis (3-mercaptopropionate)
Polyethylene glycol dimethacrylate
Sorbitol polyoxypropylene ether
Sucrose oct a- acetate
Tetraethylene glycol diacrylate
Tetraethylene glycol dimethacrylate
Triethylene glycol diacetate
Triethylene glycol diacrylate
Triethylene glycol dimethacrylate
2,2,4-Trimethyl-l,3-pentanediol monoisobutyrate
Trimethylolpropane tri aery late
All other
♦Polyhydric alcohol ethers:
Allyloxypolyethylene glycol
Bis (2-butoxyethyl) ether (Diethylene glycol di-n-
butyl ether) .
Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl
ether) .
CEL
COM
ICI
EVN
CEL
BKL
CEL
UCC
CEL
BRD
EKX
EKX
SAP
EKT
SAR
GLY
CTN
DUP
EKT
DOW
CPS
EVN
SAR
CCA
SAR
ARC
ARC
ARC
GRO
X.
UCC
CRN
UCC
VAL
RBC
PVO
PVO
GLY
EVN
SAR
JCC
HFT
AAE
SAR
UCC
AAE
SAR
EKX
AAE
CCW
UCC
UCC
SHC, UCC.
COM, HN, HPC, PNA, RCI.
DOW, JCC, OCC, OMC, UCC, IVYN.
ICI, MRK, PFZ.
GLY, ICI, PEN, PHR, PIC, RSA.
UCC.
UCC.
JCC.
PPG.
UCC.
UCC.
EKT, UCC.
HAL.
HAL.
EKT, UCC.
EK, EKX, EVN, PEN, SAR SHC, UCC.
MISCELLAHEHUS CHEMICALS
TABLE 2,--MlSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED,
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Polyhydrio Alcohols and Their Esters
and Ethers — Continued
*Polyhydric alcohol ethers--Continued
Bis (hydroxye thy 1) ether butynediol
Bis[2- C2-methoxyethoxy)ethyl] ether (Tetraethylene
glycol dimethyl ether) .
BisC2-methoxyethyl) ether (Diethylene glycol dimethyl
ether) .
Butanol polyoxypropylene ether
*2-Butoxyethanol (Ethylene glycol monobutyl ether)
*2- (2-Butoxyethoxy)ethanol (Diethylene glycol monoiso-
butyl ether) .
2- [2- (2-Butoxyethoxy)ethoxy]ethaiiol (Triethylene
glycol monobutyl ether).
l-Butoxyethoxy-2-propanol
'Diethylene glycol
Diethylene glycol monobutyl ether
Diethoxytetraglycol
Dimethoxyethane (Ethylene glycol dimethyl ether)
*Dipropylene glycol
Di-tributyle there thy lene glycol
Di-tri-isobutyl ether
*2-Ethoxyethanol (Ethylene glycol monoethyl ether)
*2- (2-Ethoxyethoxy)ethanol (Diethylene glycol mono-
ether) .
*2- [2- (Ethoxyethoxy)ethoxy]ethaiiol (Triethylene
glycol monoethyl ether) .
Glycerol tri (polyoxypropylene) ether
2- (Hexyloxy)ethanol
2- [2- (Hexyloxy)ethoxy]ethanol
2-Isobutoxyethanol
2- (2-Isobutoxyethoxy)ethanol (Diethylene glycol
monoisobutyl ether) .
l-lsobutoxy-2-propanoi (Propylene glycol isobutyl
ether) .
*2-Methoxyethanol (Ethylene glycol monomethyl ether) —
*2- (2-Methoxyethoxy)ethanol (Diethylene glycol mono-
methyl ether) .
*2- [2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene
glycol monomethyl ether) .
2- (2-Methoxyethoxy)ethyl-2-iiiethoxyethyl ether (Tri-
ethylene glycol dimethyl ether) .
Methoxypolyethylene glycol
l-Methoxy-2-propanoI
3- (3-Methoxypropoxy)propanol
3- [3- (3-Methoxypropoxy)propoxy)pr»p»nel
Polybutylene glycol
Polyethoxyethyl glycerol
Po lye thoxye thy I sorbitol
Polyethoxylated-1 ,4-hutanediol
'Polyethylene glycol
Polyethylene glycol, unrefined
Polypropoxy ethers:
Glycerol tri (polyoxypropylene) ether
Other
'Polypropylene glycol
Polytetramethylene ether glycol
Sorbitol, ethoxylated
GAP.
ASL.
JCC.
DOW, EKX, one, SHC, UCC.
DOW, EKX, JCC, OMC, SHC, UCC.
DOW, o^c,
UCC
UCC.
CAU, CEL,
DOW
WYN.
OMC.
UCC.
ASL, UCC,
IVYN
EKX, JCC, HAT, NWP, PPG, SHC, UCC,
CEL, DOW, JCC, OCC, OMC, UCC.
EKX.
DOW, EKX, JCC, OMC, SHC, UCC.
DOW, EKX, JCC, OMC, SHC, UCC.
DOW,
one.
UCC
JCC,
UCC,
WYN
UCC.
UCC.
EKX,
UCC.
EKX.
DOW, EKX, JCC, OMC, PPG, SHC, UCC.
DOH, EKX, JCC, OMC, PPG, SHC, UCC.
DOW, CMC, UCC.
ASL.
.JCC, UCC.
DOW, UCC.
DOW, UCC.
DOW.
NLC.
GLY.
GLY.
TCH.
DA, DOW, DUP, GAF, HOG, JCC, MAT, NLC, OMC, TCH, UCC,
WYN.
WYN.
JCC, UCC, IVYN.
DA, JCC, ICI, NWP, UCC, VAL, WYN.
DOW, JCC, HDG, NLC, OMC, UCC, W\'N.
DUP, QKO.
ICI.
SYNTHETIC ORGANIC CHEf^ICALS.. 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Polyhydrio Alcohols and their Esters
and Ethers — Continued
*Polyhydric alcohol ethers--Continued
*Tetraethylene glvxol
1,1,3,3-Tetramethoxypropane
2,2'-Thiodiethanol (Thiodiglycol)
*Triethylene glycol
*Tri propylene glycol
All other
Esters of Monohydrio Alcohols
Allyl raethacrylate
Amyl acetates, 90%:
Isopentyl acetate (Isoamyl acetate^
n-Pentyl acetate
Ainyl-2-ethylhexyl hydrogen phosphate
Bis (2-chloroethyl) (2-chloroethyl) phosphonate
Butyl acetates :
♦ ISO
•Normal
Secondary
•Butyl aery late
Butyl butyryl lactate
Butyl chloroacetate
n- Butyl chloroformate
sec- Butyl chloroformate 7
Butyl formate
Butyl lactate
Butyl maleate, mono-
Butyl methacrylate
tert- Butyl peroxy acetate
tert- Butyl peroxy- 2 -ethylhexanoate
tert- Butyl peroxyisobutyrate
tert- Butyl peroxy isopropyl carbonate
*tert- Butyl peroxypivalate
Cetyl lactate
Di allyl maleate
Di (sec-butyl) chloroformate
Dibutyl fumarate
•Dibutyl maleate
Di (sec-butyl) peroxydi carbonate
Diethyl sec-butylethylmalonate
Diethyl butylmalonate
Diethyl sec-butylmalonate
Diethyl carbonate (Ethyl carbonate)
Diethyl diallylmalonate
Diethyl diethylmalonate (Diethyl malonic ester)
Diethyl dip ropy Ima Ion ate
Diethyl (ethoxymethylene)malonate
Diethyl ethylmalonate (Ethyl malonic ester)
Diethyl ethyl (l-methylbutyl)malonate
Di (2-ethylhexyl) chloroformate
Di (2-ethyl-l-hexyl) fumarate
Di (2-ethyl-l-hexyl) maleate
Di (2-ethyl-l-hexyl) peroxydi carbonate
Diethyl maleate
Diethyl malonate (Malonic ester)
Diethyl (1-methylbutyl) malonate
Diethyl oxalate (Ethyl oxalate)
Diisobutyl maleate
DOW, EKX, JCC, CMC, UCC.
KF.
HAB, UCC.
CAU, CEL, DOW, EKX, JCC, MAT, PPG, SHC, UCC.
DOW, HDG, CMC, UCC.
ALD, DOW, EKX, GAP, JCC, PFN, SHC, UCC, x.
PFW
SM.
GAF
EKX
CEL
EKT
CEL
RT.
MON
CTN
CTN
CPS
COM
TCH
AZT
AZT
AZT
PPG
AZT
VND
FHP
WTL
MON
AIP
IVTL
ABB
BPC
ABB
CTN
CTN
LIL
CTN
WTL
RUB
RUB
IVTL
ACY
ABB
ABB
FHP
RUB
EN J, UCC.
EKT, PUB, SHC, UCC.
EN J, SHC.
DBC, RH, UCC.
USS.
IVTL.
WTC, WTL.
WTC, WTL.
IVTL.
WTC, IVTL.
PFZ, RCI, USS.
MON, RCI, RUB, USS.
UCC.
KF, LIL.
LIL.
MISCELLANEOUS CHEHICALS
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED
miscellaneous chemicals, ACYCLIC--Continued
Esters of Monohydrio Alcohols — Continued
Diisodecyl maleate
Di-iso-nonyl maleate
Diisopropyl peroxydi carbonate (Isopropyl percarbonate)-
Dilauryl maleate
*Dilauryl 3,3'-thiodipropionate
Dimethyl carbonate
2,5-Dimethylhexane-2,5-diperoctoate
Dimethyl maleate
Dimethyl malonate
Dimyristyl 3,3'-thiodipropionate
*Dioctyl maleate
Di-n-propyl peroxydi carbonate
*Distearyl 3,3'-thiodipropionate
Dithiobis(stearyl propionate)
Ditridecyl maleate
Di(tridecyl) 3,3'-thiodipropionate
2-Ethoxyethyl acetate
*Ethyl acetate
Ethyl acetoacetate
*Ethyl aery late
Ethyl- 2-bromopropionate
Ethyl chloroacetate
Ethyl chloro formate
Ethyl chlorothiolformate
Ethylene carbonate
2-Ethyl-l-hexyl acetate
*2-Ethyl-l-hexyl aery late
2-Ethyl-l-hexyl methacrylate
Ethyl silicate (Tetraethoxysilane)
Ethyl sulfate (Diethyl sulfate)
Ethyl thioglycolate
Fatty acid esters, not included with plasticizers or
surface- active agents:
Butyl palmitate
tert-Butylperoxy neodecanoate -.
Dimethyl brassylate
Ethyl stearate
2-Ethylhexyl palmitate
Hexadecyl stearate
Isopropyl linoleate
Methyl esters of coconut oil
Methyl esters of cottonseed oil
Methyl esters of tallow
Methyl 12-hydroxystearate
Methyl myristate
Methyl stearate
Myristyl myristate
All other
Glycidyl aery late
Glycidyl methacrylate
Hexyl acetate
Isobutyl acetate 5 isobutyl isobutyrate, mixture
Isobutyl aery late
Manufacturers' identification codes
(according to list in table 3)
RUB.
RUB.
PPG.
EFH.
ACY, CCW
E\fN, HAB.
CTN.
WTC.
AAC, ABC
KF.
CCW, EVN
MON, RCI
USS.
wtl.
ACY, CCW,
EVN, HAB.
EVN.
RUB.
ACY, EVN
EN J.
CEL, EKT,
EKX, ENJ, MON, PUB, UCC
EKT, UCC.
CEL, DBC,
RH, SNW, UCC.
BAX.
DOW. KF,
MON.
CTN, FMP,
OTC.
SFA.
JCC.
EKT, UCC.
CEL, DBC.
UCC.
X.
SFS, UCC.
UCC.
EVN.
AAE, CBY.
WTC.
EMR.
ARS.
VND.
ICI.
VND.
PG.
BFR.
CHL, HUM,
PG.
HUM, NTL.
HUM, PG.
DA.
VND.
CRN, ROB,
VND.
AAE.
CPS, ENJ.
EKX.
DBC, RH,
UCC.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Hanufacturers ' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
EsteTS of Mcnohydrio Alcohols — Continued
Isobutyl chloro formate
Isobutyl isobutyrate
Isodecyl aery late
*Iso-octyl mercaptoacetate
Iso-octyl 3-ine re apt ©propionate
*Isopropyl acetate
Isopropyl chloro formate
Lauryl lactate
Lauryl methacrylate
Lauryl stearyl thiodipropionate
Maleic esters and copolymers
Methallylidene di acetate
*Methyl acetate
Methyl acetoacetate
Methyl acrylate, monomer
Methyl borate
Methyl chloroacetate
Methyl chloro formate
Methyl di chloro acetate
Methyl formate
*Methyl methacrylate, monomer
4-Methyl-2-pentyl acetate
Methyl sulfate CDimethyl sulfate)
Methyl vinyl acetate
Myristyl lactate
Octadecyl 3-mercaptopropionate
'Phosphorus acid esters:
Bis [2-ethylhexyl) hydrogen phosphate
Bis (2-ethylhexyl} hydrogen phosphite
Butyl hydrogen phosphates
Dibutyl butylphosphonate
Dibutyl hydrogen phosphite
Didodecyl hydrogen phosphate
Diethyl ethylphosphonate
Diethyl hydrogen phosphite
Diethyl phosphorochloridothionate
Dimethyl hydrogen phosphite
Dimethyl methylphosphonate
Dimethyl phosphorochloridothionate
Dioleyl hydrogen phosphite
2-Ethylhexyl hydrogen phosphate
Iso-octyl hydrogen phosphate
Oleyl hydrogen phosphate
Trialkyl phosphites
Tr i (b utoxye thyl)phosphate
Tributyl phosphate
Tri ethyl phosphite
Triiso-octyl phosphite
Tri i s op ropy 1 phosphi te
Trimethyl phosphite
Tris(2-chloroethyl) phosphite
Tris (chloroisopropyl) thionophosphate
CTN, OTC.
EKX.
UCC.
CCW, EVM, IIAB.
EVN.
EKT, EN J, UCC.
CTN, PPG.
VND.
X.
EVN.
GAP, USS.
UCC.
EK, GRD, MON, UCC.
EKT, UCC.
CEL, DBC, RH.
SFS.
DOW, KF.
CTN, FMP.
PD.
CEL, DUP.
ACY, DUP, RH.
PUB, SHC, UCC.
DUP.
UCC.
VND.
EVN.
SM, UCC.
SM.
SM.
SM.
SM.
DUP.
SH.
SM.
SPA.
SM.
SM.
SPA.
COM, FMP, HN.
SPA, SFS, SM.
SM.
SFA, SFS, SM.
MISCELLANEOUS CHEMICALS
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported^
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
Manufacturers' identification codes
(according to list in table 3]
MISCELLANEOUS CHEMICALS, ACYCYLIC--Continued
Esters of Monohydrio Alcohols — Continued
♦Phosphorus acid esters--Continued
Tris(2,3-dibromopropyl) phosphate
Tris (l,3-dichloro-2-propyl) phosphorothioate
All other
Poly (methylvinyl ether/monoethyl maleate)
♦Propyl acetate
Propylene carbonate
Stear>'l methacrylate
Tetraethyl silicate
1 ,1,3,3-TetramethylbutyI peroxy-2-ethylhexanoate
Tetraoctyl orthosilicate
Titanic acid esters:
Bis (2- [bis (2-hydroxyethyl) amino] ethyl) diisopropyl
titanate .
Bis(l-methyl-3-oxo-l-butenyl) diisopropyl titanate--
Tetrabutyl titanate
Tetraisopropyl titanate
Tetrakis(2-ethylhexyl) titanate
Other
Triethyl orthoacetate
Trie thy 1 orthoformate
Triethyl orthopropionate
Triisodecyl orthoformate
Trimethyl orthoformate
*Vinyl acetate, monomer
All other
Halogenated Hydrooarbons
1-Bromobutane Cn-Butyl bromide)
2-Bromobutane (sec-Butyl bromide)
Bromochlorome thane
l-Bromo-3-chloropropane (Trimethylenechlorobromide) —
2-Bromo-2-chloro-l,l ,1-trifluoroe thane
Bromoethane (Ethyl bromide)
1-Bromohexane (n-Hexyl bromide)
l-Bromo-3-methylbutane
l-Bromo-3-methyl-2-butene
1-Bromo-octadecane
1-Bromo-octane (n-Octyl bromide)
2-Bromopentane (1-Methylbutyl bromide)
1-Bromopropane (n-Propyl bromide)
Bromotrichlorome thane
Bromotrifluorome thane
n- Butyl chloride
♦Carbon tetrachloride
Carbon tetrachloride crude
♦Chlorinated paraffins:
Less than 35% chlorine
♦35%-64% chlorine
bS't. or more chlorine
2-Chloro-l,3-butadiene
1-Chlorobutane (n-Butyl chloride)
2-Chlorobutane (sec-Butyl chloride)
l-Chloro-l,l-difluoroethane
♦Chlorodifluorome thane
HN,
SM.
ALD,
TNI.
CEL,
JCC.
X.
ucc.
WTL.
MON.
DUP.
DUP.
DUP.
DUP.
DUP.
DUP.
KF.
KF.
KF.
KF.
KF.
BOR,
ALD,
DOW.
MCH.
ICI.
DOW,
HMY.
LIL.
SDW.
DUP.
MCH.
LIL.
EK,
MCH.
DUP.
BRD.
ACS,
TNA.
MCH.
DUP, MON, SM, TNA, WES.
EKT, PUB, UCC.
CEL, NSC, UCC, USI.
CEL, CTN, DUP, EFH, EK, EMR, ENJ, EVN, GAF, HUM,
PIC, RH, UCC, WTL, ZGL.
DA, DOW, FMB, FRO, PPG, SFI .
DA, HK.
CCH, DA, DVC, HPC, ICI, NEV.
DA, DVC, NEV.
DUP.
PUB, UCC.
EK, PLC.
DUP, PAS.
ACS, DUP, KAI, PAS, RCN.
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued
Halogenated Hydrocarbons — Continued
*Chloroethane (Ethyl chloride)
*Chloroform
*Chloromethane (Methyl chloride)
2-Chloro-2-methylpropane (tert-Butyl chloride)
3-Chloro-2-methylpropene (Methallyl chloride)
Ch 1 oropent af luoroe th ane
3-Chloropropene (Allyl chloride)
Chlorotrifluoroethylene (Trifluorovinyl chloride)
Ch lorotrif luoroe thy lene, polymerized
Chlorotrifluorome thane
*1 ,2-Dibromoethane (Ethylene dibromide)
Dibromomethane (Methylene bromide)
l,2-Dibromo-l,l ,2 ,2-tetrafluroethane
Dichlorobutadiene
l,3-Dichloro-2-butene
1 ,4-Dichlorobutene
*Dichlorodifluorome thane
*l,2-Dichloroethane (Ethylene dichloride)
*Dichloromethane (Methylene chloride)
*l,2-Dichloropropane (Propylene dichloride)
2 ,3-Dichloropropene
Dichlorotetraf luoroethane
1 ,1-Dif luoroethane
Diiodomethane (Methylene iodide)
Fluronated ethylene propylene
Hexadecyl chloride
Hexaf luoro-2-propane
Hexafluoropropylene, monomer
lodoethane (Ethyl iodide) , tech
Iodoform (Triiodome thane)
*Iodomethane (Methyl iodide)
1 - 1 odoperf luorohexane
Lauryl chlorides
Octafluorocyclobutane
Octyl chloride
1 ,1,2,2-Tetrabromoethane (Acetylene tetrabromide) —
1 ,1,2,2-Tetrachloroethane (Acetylene tetrachloride) -
*Tetrachloroethylene (Perch loroe thy lene)
Tetraf luoroethylene , monomer
Tetrafluorome thane
*l,l,l-Trichloroethane (Methyl chloroform)
1 ,1,2-Trichloroethane (Vinyl trichloride)
*Trich loroe thy lene
*Trichlorofluoromethane
1 ,2,3-Trichloropropane
1 ,2,3-Trichloropropene
Trich lorotrif luoroethane
Vinyl bromide (Bromoethylene)
*Vinyl chloride, monomer (Chloroethylene)
AME, DOW, DUP, HPC, PPG, SHC, TNA.
ACS, DA, DOW, DUP, FRO, SFI.
ACS, CO, DCC, DOW, DUP, FRO, TNA, UCC.
EK.
FMP.
DUP.
DOW, SHC.
ACS, MMH.
MHM.
DUP.
DOW, GIL, MCH, PPG, TNA.
DOW.
DUP.
DUP.
DUP.
DUP.
ACS, DUP, KAI, PAS, RCN, UCC.
ACS, AME, BFG, CO, DA, DOW, FRO, JCC, OMC, PPG,
TNA, UCC, IVYN.
ACS, DA, DOW, DUP, FRO, SFI.
DOW, JCC, UCC.
DOW.
ACS, DUP.
ACS, DUP.
NTS, SDW.
DUP.
BRD.
DUP.
DUP.
EK, FMT, RSA.
NTB.
EK, FMT, RSA.
DUP, TKL.
AZT, BRD.
DUP.
BRD.
DOW.
TTX.
DA, DOW, DUP, FRO, HK, PPG, SFI, TNA.
DUP, PAS, TKL.
DUP.
DOW, FRO, PPG, TNA.
DOW, UCC.
DOW, DUP, HK, PPG, TNA, TTX.
ACS, DUP, KAI, PAS, RCN, UCC.
DOW, SHC.
DOW, PAS.
ACS, DUP.
DOW, TNA.
ACS, AME, BFG,
CO, DOW, HN, MNO, PPG, SHC, TNA.
MISCELLAflEOUS CHEMICALS
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
Halogenated Hydrocarbons — Continued
Vinyl fluoride
Vinylidene chloride, monomer (1,1-Dichloroethylene)
Vi ny 1 i dene f luori de
All other
All Othev Miscellaneous Acyclic Chemicals
Acetyl peroxide
Aluminum isopropoxide (Aluminum isopropylate)
*2-Butanone peroxide
tert- Butyl hydroperoxide
*tert-Butyl peroxide (Di-tert-butyl peroxide)
Butyrolactone
Caprolactone
*Carbon disulfide
2-Chloroethanol (Ethylene chlorohydrin)
Decanoyl peroxide
Di aldehyde starch
2 , 3- Dib romop ropanol
2,5-Dimethyl-2,5-bis (2-ethyl-l-hexanoylperoxy)hexane —
2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexane
2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexyne-3
*Epoxides, ethers, and acetals:
Acetone dimethylacetal (2,2-Dimethoxypropane)
1- (Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)-
Bis(2-chloroethoxy)methane (Dichloroethylformal)
Bis(2-chloroethyl) ether (Dichlorodiethyl ether)
Bis(2-chloro-l-methylethyl) ether (Dichloroisopropyl
ether) .
l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether)
Butylene oxide
Butyl ether (Di-n-butyl ether)
Butyl vinyl ether
2-Chloroethyl vinyl ether
Chloromethyl methyl ether
2,2-Dichloro-l,l-difluoroethyl methyl ether
Dimercaptodiethyl ether
Epi chlorohydrin
'Ethylene oxide
Ethyl ether:
Absolute
*Tech
U.S.P
Ethyl vinyl ether
Glycidol (2,3-Epoxy-l-propanol)
Isobutyl vinyl ether
* Is opropy 1 ether
Methyl ether (Dimethyl ether)
Methyl vinyl ether
'Propylene oxide
Triglycol di chloride
Vinyl methoxytriglycol
Other
DUP.
DOW,
FRO.
DUP.
ALD,
BRD,
DUP,
EK,
HMY,
LIL, RSA, SDW.
AZT,
WTL.
CHT,
KCH.
AZT,
CAD,
NOC,
RCl
WTC
WTL.
AZT,
CAD,
OCC,
WTC
WTL
AZT,
CAD,
NOC,
SHC
WTC
WTL.
GAP.
IICC.
ACS,
RIB,
PAS,
PPG
SFI
UCC.
WTC,
WTL.
ULS.
GTL,
MCH.
WTL.
IVTL.
WTL.
DOW.
AAC,
SHC.
TKL.
DOW.
DOW,
MOB.
DOW.
DOW.
PUB,
UCC.
GAP,
AAC,
UCC.
UCC.
RH.
DOW.
F.VN, USR.
DOW, SHC, X.
CAU, CEL, DOW, EKX, JCC, MAT, NWP, OMC, PPG, SHC, SNO,
UCC, WYN.
MAL.
EN J,
MAL,
GAP,
DIX.
GAF.
EN J,
DUP,
GAF.
CEL, DOW, JCC, OCC, OMC, UCC, WYN.
RH.
UCC.
EK, ICI, SHC, UCC.
HPC, USI.
OMS.
UCC.
SHC, UCC.
UCC.
SYNTHETIC ORGANIC CHEMICALS/ W72
TABLE 2.— Miscellaneous chemicals for which US. production or sales were reported,
IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
All Other Misaellaneous Aayolio Chemicals— Contirmei
Epoxy curing agents . — — .
2- (Ethylmercapto)ethanol
Fats and oils, chemically modified
Glucono- delta- lac tone
Glutaraldehyde bis(5odium bisulfite)
Hexachlorodimethyl sulfone
n-Hexadecyl disulfide
Hydrocarbons :
1-Butyne (Ethylacetylene)
n-Decane
n-Dodecane
1-Dodecene
Hexadecane
n-Hexane
Myrcene
1-Octadecene
n-Octane
I (and 2)-0ctene
Tri-decane
Other
Hydrogenated tallow glycerides
Lauroyl peroxide
Magnesium me thy late
Methane thiol (methyl mercaptan)
Methyl al (Dimethoxymethane)
Methyl sulfide (Dimethyl sulfide)
Methyl sulfoxide
Organo- aluminum compounds:
Diethyl aluminum chloride
Diethylalumi num iodide
Diisobutyl aluminum chloride
Diisobutylaluminum hydride
Ethylaluminum chlorides
Ethyl aluminum sesqui chloride
Isopropenylaluminum
Methyl aluminum sesqui chloride
Tri e thy 1 a luminum
Triisobutyl aluminum
Trimethylaluminum
Other
Organo-boron compounds :
Boron fluoride - ethyl ether complex
Trie thy lb or ane
Trimethoxyboroxine
Trimethyl borate
Organo- lead compounds:
*Tetraethyllead
Tetrame thy Head
Tetra (methyl -ethyl) lead
Other
n- Butyl lithium
sec- Butyl lithium
Organo-magnesium halides
Organo-mercury compounds
*0rgano-silicon compounds:
Chlorotrimethylsilane
Dichlorodimethylsilane
Dichloromethylsilane
Dichloromethylvinylsilane
Manufacturers' identification codes
(according to list in table 3)
SHC.
PLC.
ABB, DOM.
PFZ.
IDC.
PAS.
AIP.
HMY,
PLC.
HMY,
PLC.
HMY.
HMY.
HMY.
IFF,
NCI.
HMY'.
HMY,
PLC.
HMY,
PLC.
BLK,
HMY.
ALD,
CBY, HMY.
CHL.
AZT,
WTL.
MRT.
DOW.
CEL.
CRZ.
CRZ.
TNA,
TSA.
ISA.
TNA,
TSA.
TSA.
TNA,
TSA.
TNA,
TSA.
TSA.
TNA.
TNA,
TSA.
TNA,
TSA.
TNA.
TSA.
ACS.
TSA.
SFS.
»1HI.
DUP
NLC, PPC, TNA
DUP,
NLC, TNA.
DUP
PPG.
TNA
FTH
GAF.
FTE
ARA
EK,
NTB.
DCC
UCC.
DCC
UCC.
DCC
UCC.
UCC
MISCELLANEOUS CHEMICALS
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported.
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED
Manufacturers' identification codes
(according to list in table 3)
MISCELLANEOUS CHEMICALS, ACYCLIC--Continued
All Other Misaellaneous Aayolia Chemicals — Continued
*Organo- silicon compounds --Continued
Trichlorobutylsilane
Trichloroethylsilane
Trichloromethylsilane
Trichlorovinylsilane
Silicone greased
Other organo- silicon compounds
Organo-tin compounds:
Bis(tributyltin) oxide
Dibutyltin bis lauryl mercaptide
Dibutyltin di chloride
Dibutyltin oxide
Dioctyltin oxide
Organotin mercaptide
Tributyltin chloride
Tributyltin fluoride
Other
Organo- zinc compounds
Oxidized hydrocarbon mixtures
Perchloromethanethio (Perchloromethyl raercaptan)
*PhosgenB (Carbonyl chloride)
Pine oil, synthetic
S-Propiolactone
Rare sugars
Sodium ethoxide
Sodium formaldehyde bisulfite
Sodium formaldehyde sulfoxylate
*Sodium methoxide (Sodium methylate)
Sodium succinaldehyde bisulfite
Succinyl peroxide
Trioctylphosphine oxide
Zinc formaldehyde 'sulfoxylate
Other
DCC.
DCC.
DCC.
UCC.
SPD.
DCC, SFS, UCC.
CCW, X.
CCW.
PCW,
X.
TSA.
ALX.
SFC.
ACS, CTN, DUP, MOB, OMC , OTC, PPG, RUC, UPJ, VDM.
CBY, NCI.
CEL.
PEN.
FMP .
EK, IDC.
DA, RH.
DA, OMC, RBC,
HEX.
OTL.
EK.
DA, RH.
ABB, ALD, ALX, CEL, EK, GNM, HMY, NLC, NTB, NIL, PIC,
PLC, RSA, SDW, SFS, SHC, TCH, TNA, UCC, WTL, x, x.
552-743 O - 74 - 16
SYNTHETIC ORGANIC CHEfllCALS, 1972
TABLE 3.— Miscellaneous chemicals: Directory of Manufacturers, 1972
ALPHABETICAL DIRECTORY BY CODE
[Names of miscellaneous chemical manufacturers that reported production or sales to the U.S. Tariff Commission for
1972 are listed below in the order of their identification codes as used in table 2]
Name of company
Name of company
Alcolac Chemical Corp.
American Aniline § E.xtract Co., Inc.
Abbott Laboratories
Arc Chemical Corp.
Allied Chemical Corp.:
Agricultural Div.
Plastics Div.
Specialty Chemicals Div.
American Cyanamid Co.
Agway, Inc., Olean Nitrogen Complex
Air Products 6 Chemicals, Inc.
Ark la Chemical Corp.
Arkansas Co. , Inc.
Ames Laboratories, Inc.
Alco Chemical Corp.
Aldrich Chemical Co., Inc.
Allied Chemical Corp., Fibers Div.
Alox Corp.
American Bio- Synthetic Corp.
American Chemical Corp.
Arapahoe Chemicals Div. of Syntex Corp.
Armak Co.
Ardmore Chemical Co. , Inc.
USS Agri- Chemicals, Div. of U. S. Steel Corp.
Arsynco, Inc.
Arizona Chemical Co.
Ashland Oil, Inc., Ashland Chemical Co. Div.
Ansul Chemical Co.
Atlantic Richfield Co., ARCO Div.
PMC Corp. , Fiber Div.
AZ Products Co. Div. of A2S Corp.
Dart Industries, Inc., Aztec Chemicals Div.
Goodrich Chemical
Baxter Laboratories, Inc.
B. F. Goodrich Co. ,
Co. Div.
Pace National Corp.
J. T. Baker Chemical Co.
Hillmaster Onyx Corp., Millmaster Chemical
Co. Div., Berkeley Chemical Dept.
Borden Co., Borden Chemical Co. Div.
Stauffer Chemical Co., Specialty Qiemical
Div., Benzol Products
Lonza, Inc.
Buckeye Cellulose Corp.
Noury Chemical Corp.
Calcasieu Qiemical Corp.
Qiembond Corp.
Crosby Chemicals, Inc.
Cincinnati Milacron Chemicals, Inc.
Chase Chemical Corp.
Pears all Chemical Co.
Cincinnati Milacron Chemicals, Inc.
Celanese Corp. :
Celanese Chemical Co.
Celanese Fibers Co.
Celanese Plastics Co.
Cooperative Farm Chemicals Association
Ciba-Geigy Corp. 5
Ciba Pharmaceutical Co.
CHH
CHL
CHN
CHP
CHT
CLK
CLN
CNC
CNP
CO
COL
COM
CP
CPS
CRN
CRT
CRZ
CTN
CWN
DAN
DBC
DCC
DEX
DIX
DLI
DOL
DOM
DOW
DUP
DVC
EKT
EKX
ELP
01R
ENJ
ESA
EVN
FCA
FER
FIN
FIS
FMB
FMP
FMT
FRO
FTE
FTX
Charles Hansen's Laboratory, Inc.
Chemol, Inc.
Cherokee Nitrogen Co.
C. H. Patrick § Co . , Inc.
Chattem Drug 5 Chemical Co., Chattem
Chemicals Div.
Clark Chemical Corp.
Standard Brands, Inc., Clinton Corp.
Processing Co. Div.
Columbia Nitrogen Corp.
Nipro Inc.
Continental Oil Co.
Collier Carbon 5 Chemical Corp.
Commercial Solvents Corp.
Colgate-Palmolive Co.
CPS Chemical Co.
CPC International, Inc.
Crest Chemical Corp.
Crown Zellerbach Corp., Chemical Products
Div.
Chemetron Corp., Organic Chemical Div.
Upjohn Co., Fine Chemical Div.
Diamond Shamrock Corp.
Dan River, Inc.
Dow Badische Co.
Dow Coming Corp.
Dexter Chemical Corp.
Dixie Chemical Co.
Dawe's Laboratories, Inc.
Dole Co., Div. of Castle 6 Cook, Inc.
Dominion Products, Inc.
Dow Chemical Co.
E. I. DuPont de Nemours 5 Co., Inc.
Dover Chemical Corp.
E. F. Houghton S Co.
Eastman Kodak Co.:
Tennessee Eastman Co. Div.
Texas Eastman Co. Div.
El Paso Products Co.
Emery Industries, Inc.
Exxon Chemical Co. U.S.A.
East Shore Chemical Co., Inc.
Evans Chemetics, Inc.
C. F. Industries Inc.
Ferro Corp . :
Ferro Chemical Div.
Grant Chemical Div.
Fine Organics, Inc.
Fisher Chemical Co., Inc.
FMC Corp . :
Industrial Chemical Div.
Industrial Chemical Div.
Group
Organic Business
Fairmount Chemical Co., Inc.
Vulcan Materials Co., Chemicals Div.
Foote Mineral Co.
CF Industries, Inc., Fremont Nitrogen
Complex
MISCELLANEOUS CHE^IICALS
TABLE 3, --Miscellaneous chemicals: Directory of manufacturers, 1972--Continued
Name of company
GAF Corp., Chemical Div.
Gane's Chemical Works, Inc.
W. R. Grace 5 Co., Agricultural Chem. Group
G. Frederick Smith Chemical Co.
Givaudan Corp.
SCM Corp. Glidden-Durkee Div.
Glyco Chemicals, Inc.
General Mills Chemicals, Inc.
Gulf Oil Corp., Gulf Oil Chemicals Co. -U.S.
Georgia-Pacific Corp.
Grain Processing Corp.
W. R. Grace 5 Co., Polymers 5 Chemicals Div.
W. R. Grace 5 Co., Hatco Chemical Div.
Millmaster Onyx Corp., A. Gross 6 Co. Div.
Great Lakes Chemcal Corp.
Goodyear Tire & Rubber Co.
Halby Products Co., Inc.
C.P. Hall Co. of Illinois
Hodag Chemical Corp.
Hexagon Laboratories, Inc.
Hoffman-Taff, Inc.
Hooker Chemical Corp.:
Dure: Plastics Div.
Hawkeye Chemical Co.
W. R. Grace 5 Co., Dewey 6 Almy Chemical
Div. , Organic Chemical
Humphrey Chemical Co.
Tenneco Chemicals, Inc.
Hercules, Inc.
Hart Products Corp.
Harshaw Chemical Co., Div. of Kewanee Oil
Co.
Kraftco Corp., Humko Products Chemical Div.
ICI America, Inc. fi Specialty Chemicals Div.
Industrial Dyestuff Co.
International Flavors § Fragrances, Inc.
lonac Chemical Co.
Jefferson Chemical Co., Inc.
Nipak , Inc.
George A. Jeffrey's 5 Co., Inc.
Jordan Chemical Co.
Joseph Turner 6 Co.
Kaiser Aluminum § Chemical Corp., Kaiser
Chemicals Div.
Kennecott Copper Corp., Chino Mines Div.
Keystone Chemurgic Corp.
Kennecott Copper Corp., Utah Copper Div.
Kay-Fries Chemicals, Inc.
H. Kohnstamm 6 Co., Inc.
Koppers Co., Inc., Organic Materials Div.
LaMotte Chemical Products Co.
Lemke Chemicals, Inc.
Eli Lilly f, Co., Inc.
Lubrizol Corp.
Mallinckrodt Chemical Works
Koch Chemical Co.
Michigan Chemical Corp.
Mooney Chemicals, Inc.
Ventron Corp.
Miles Laboratories, Inc., Marschall Div.
Minnesota Mining 6 Manufacturing Co.
Monochem, Inc.
Mob ay Chemical Co.
MON
MOR
MRK
MRT
MSC
MTO
NCI
NEP
NES
NEV
NLC
NOC
NOR
NPI
NSC
NIB
NTL
OMC
OUS
ONX
OPC
ORO
ORT
OTC
OXC
PAR
PAS
PCW
PD
PEN
PEN
PFW
PFZ
PG
PHR
PIC
PLB
PLC
PLS
PUP
PPC
PPG
PRD
PTT
PUB
PVO
QCP
QKO
RBC
RCI
RCN
RBH
Monsanto Co.
Marathon Morco, Co.
Merck 5 Co. , Inc.
Morton Chemical Co., Div. of Morton-
Norwich Products, Inc.
Mississippi Chemical Corp.
Montrose Chemical Corp. of California
Union Camp Corp., Chemical Div.
Nepera Chemical Co.
Nease Chemical Co., Inc.
Neville Chemical Co.
Nalco Chemical Co.
Norac Co., Inc. and Mathe Chemical Co. Div.
Norwich Pharmacal Co.
Stepan Chemicals Co., National Polychemicals
Div.
National Starch 6 Chemical Corp.
National Biochemical Co.
NL Industries, Inc.
Northwestern Chemical Co.
Northern Petrochemicals Co.
Oxirane Chemical Co.
Airco, Inc., Ohio Medical Product Div.
Olin Corp.
E. R. Squibb 6 Sons, Inc.
Millmaster Onyx Corp., Onyx Chemical Co.
Orbis Products Corp.
Chevron Chemical Co.
Roehr Chemicals, Inc.
Ott Chemical Co.
Oxochem Enterprises
Pennsylvania Refining Co.
Pennwalt Corp.
Pfister Chemical Works
Parke, Davis 5 Co.
CPC International, Inc., S. B. Penick Div.
Pfanstiehl Laboratories, Inc.
Polak's Frutal Works, Inc.
Pfizer, Inc.
Procter 5 Gamble Co.
Pharmachem Corp.
Pierce Chemical, Inc.
P-L Biochemicals , Inc.
Phillips Petroleum Co. 5 Phillips Pacific
Chemical Co.
Plastics Engineering Co.
Premier Malt Products, Inc.
Premier Petrochemical Co.
Pittsburgh Plate Glass Co.
Productol Chemical Co., Inc.
Petro-Tex Chemical
Publicker Industries, Inc.
PVO International, Inc.
Quaker Chemical Corp.
Quaker Oats Co.
Fike Chemicals, Inc.
Reichhold Chemicals, Inc.
Racon, Inc.
Reheis Chemical Co. Div. of Armour
Pharmaceutical Co.
Remington Arms Co., Inc.
Rohm § Haas Co.
Robeco Chemicals, Inc.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3.— Miscellaneous chemicals: Directory of manufacturers. 1972— Continued
Code
Name of company
Code
Name of company
RPC
Millmaster Onyx Corp., Refined-Onyx Div.
TEK
Teknor Apex Co.
RSA
R.S.A. Corp.
TER
Terra Chemicals International, Inc.
RT
F. Ritter S Co.
TID
Getty Oil Co.
RUB
Hooker Chemical Corp, , Ruco Div.
TKL
Thiokol Chemical Corp.
RUC
Rubicon Chemicals, Inc.
TNA
Ethyl Corp.
TNI
Gillette Chemical Co., Div. of Gillette Co.
S
Sandoz, Inc., Sandoz Colors 6 Chemical
tri
Triad Chemicals
Div.
TRO
Troy Chemical Co.
SAL
Salsbury Laboratories
TSA
Texas Alky Is, Inc.
SAR
Sartomer Industries, Inc.
ttx
Detrex Chemical Industries, Inc.
SBC
Scher Bros.
TX
Texaco, Inc.
SCH
Schering Corp.
TZC
Tizon Chemical Corp.
SDC
Martin-Marietta Corp., Sodeyco Div.
Sterling Drug, Inc.:
UCC
Union Carbide Corp.
SDH
Hilton-Davis Chemical Co. Div.
UOP
Universal Oil Products Co., UOP Chemical Di
SDW
Winthrop Laboratories Div.
UPJ
Upjohn Co.
Stauffer Chemical Co.:
UPM
Universal Oil Products Co.
SPA
Agricultural Div.
USB
U.S. Borax Research Corp.
SFC
Calhio Chemicals, Inc. Div.
US I
National Distillers 6 Chemical Corp., U.S.
SFI
Industrial Div.
Industrial Chemicals Co. Div.
SFS
Specialty Chemical Div.
USS
USS Chemicals Div. of U.S. Steel Corp.
SHA
Shanco Plastics 5 Chemical Co.
USR
Uniroyal, Inc., Chemical Div.
SHC
Shell Oil Co., Shell Chemical Co. Div.
SHF
Kraftco Corp., Sheffield Chemical Div.
VAC
Northern Petrochemical Co.
SHP
Shepherd Chemical Co.
VAL
Valchem
SK
Smith, Kline 5 French Laboratories
VDM
Van De Mark Chemical Co.
SKG
Sunkist Growers, Inc.
VEL
Velsicol Chemical Corp., Inc.
SKO
Skelly Oil Co.
VGC
Virginia Chemicals, Inc.
SM
Mobil Oil Corp., Mobil Qiemical Co.,
VLN
Valley Nitrogen Producers, Inc.
Chemical Coatings Div.
™d
Van Dyk 5 Co. , Inc.
Industrial Chemical Div.
VPC
Verona Corp .
SNI
Kaiser Aluminum 5 Chemical Corp., Kaiser
Agricultural Chemicals Div.
WAY
Phillip A. Hunt Chemical Corp., Wayland
SNO
SunOlin Chemical Co.
Chemical Div.
SNW
Sun Chemical Corp., Chemical Div.
WBC
Worthington Biochemical Corp.
SOC
Standard Oil Co. of California, Chevron
WBG
White 5 Bagley Co.
Chemical Co.
WCL
Wright Chemical Co.
SOH
Vistron Corp.
WES
Borg-Warner Corp., Weston Chemical Div.
SOI
American Oil Co. CMaryland)
mi
Wilson Pharmaceutical 5 Chemical Corp.,
SPD
General Electric Co., Silcon Products
Wilson-Martin Div.
Dept.
WMP
Essex International, Inc., Electro-
SPR
Scientific Protein Laboratories
Mechanical Div.
SIP
Stepan Chemical Co.
WSN
Mallinckrodt Chemical Works, Washine Div.
SW
Sherwin-Williams Co.
wtc
Witco Chemical Co., Inc.
SYP
Dart Industries, Inc., Synthetic Products
WTH
Union Camp Corp., Harchem Div.
Co. Div.
WTL
Pennwalt Corp., Lucidal Div.
WYC
Wycon Chemical Co.
tae
Chemetron Corp., Medical Products
Div.
Tanatex Chemical Corp
WYN
Wyandotte Chemicals Corp.
TCC
ZGL
Carolina Processing Corp.
TCH
Emery Trylon Chemicals Div. Industries
Inc.
Note. — Complete name= and addresses of the above reporting companies
listed in Table 1 of the Appendix.
APPENDIXES
APPENDIX A
DIRECTORY OF HANUFACTURERS
TABLE 1.— Synthetic organic chemicals; Alphabetical Directory of manufacturers, by company. 1972
[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission
for 1972 are listed below alphabetically, together with their identification codes as used in table 2 of the 14
individual sections of this report]
Office address
A 5 E Plastic Pak Co., Inc
AZS Corp . :
AZ Products Co. Div
Lancaster Chemcial Co. Div
Abbott Laboratories
Abex Corp. , .American Brakelok Div
Acme Chemical Co
Acme Resin Co
Agway, Inc. , Olean Nitrogen Div
Airco, Inc., Ohio Medical Products Div
Air Products S Chemicals, Inc., Chemicals
Group
Alco Chemical Corp.
Alcolac, Inc
Aldrich Chemical Co. , Inc
Alliance Chemical Co., Inc
Allied Chemical Corp.:
Fibers Div
Plastics Div
Seme t- Sol vay Div
Specialty Chemicals Div
Union Texas Petroleum Div
Agr i cu 1 tural Dep t
Alox Corp
Alpha Laboratories, Inc
Amchem Products, Inc., Div. of Rorer-
Amchem, Inc.
Amerace-Esna Corp. , Penetone Div
Amerada Hess Corp
American Aniline 5 Extract Co., Inc
American Aniline Products, Inc
American Bio-Synthetics Corp
American Can Co
American Chemical Corp
.American Cyanamid Co
.American Hoechst Corp
American Oil Co. (Maryland)
American Oil Co. (Texas)
.American Synthetic Rubber Corp
Ames Laboratories, Inc
Amoco Chemical Corp
.Amoco Production Co
Ansul Chemical Co
Apex Chemical Co. , Inc
Apollo Colors, Inc
Applied Plastics Co. , Inc
Arapahoe Chemicals Div. of Syntex Corp
Arc Chemical Corp
Ardmore Chemical Co. , Inc
Arenol Chemical Corp
Argus Chemical Corp., Halby Div
Arizona Chemical Co
.Arkansas Co. , Inc
Arkla Chemical Corp
Armak Co
14505 E. Proctor .Ave. , Industry, CA 91747.
2525 So. Combee Rd., Eaton Park, FL 33840.
Broad 6 13th St., Carlstadt, NJ 07072.
14th St. and Sheridan Rd., N. Chicago, IL 60664.
2401 S. Loudoun St., Winchester, VA 22601.
2S06 N. 32d St., Milwaukee, WI 53245.
1401 S. Circle Ave., Forest Park, IL 60130.
1446 Buffalo St., Olean, NY 14760.
3030 Airco Dr., P.O. Box 1319, Madison, KI 53701.
5 Executive Mall, Swedesford Rd. , Wayne, PA 19087.
Trenton Ave. and William St., Philadelphia, PA 191
3440 Fairfield Rd. , Baltimore, MD 21226.
940 W. St. Paul Ave., Milwaukee, WI 53233.
33 Avenue P, Newark, NJ 07105.
1 Times Square, New York, NY 10036.
P. 0. Box 2365R, Morristown, NJ 07960.
P. 0. Box 1013R, Morristown, NJ 07960.
P. 0. Box 1219R, Morristown, NJ 07960.
P. 0. BOX 2120, Houston, TX 77001.
P. 0. Box 2120, Houston, TX 77001.
3943 Buffalo .Ave., Niagara Falls, NY 14302.
1685 S. Fairfax St., Denver, CO 80222.
Brookside Ave., Ambler, PA 19002.
74 Hudson Ave., Tenafly, NJ 07670.
1 Hess Plaza, Woolridge, NJ 07095.
Venango and F Sts., Philadelphia, PA 19134.
P. 0. Box 3063, Paterson, NJ 07509.
710 W. National Ave., Milwaukee, WI 53204.
American Lane, Greenwich, CT 06830.
2112 E. 223d St., P. 0. Box 1110, Long Beach, CA 9
Wayne, NJ 07470.
129 Quidnick St., Coventry, RI
910 S. Michigan Ave., Chicago,
910 S. Michigan Ave., Chicago,
P. 0. Box 360, Louisville, KY
200 Rock Lane, Milford, CT 06460.
130 E. Randolph Dr., Chicago, IL 60601.
P. n. Box 591, Tulsa, OK 74102.
1 Stanton St., Marinette, WI 54143.
200 S. 1st St., Elizabethport, NJ 07206.
899 Skokie Blvd., Northbrook, IL 60062.
612 E. Franklin Ave., El Segundo, CA 90245.
2855 Walnut St., Boulder, CO 80302.
P. 0. Box 175, Slate Hill, NY 10923.
840 Valley Brook Ave., Lyndhurst, NJ 07071.
40-33 23d St., Long Island City, NY 11101.
600 Terminal Ave., New Castle, DE 19720.
Wayne, NJ 07470.
185 Foundry St., Newark, NJ 07105.
P. 0. Box 825, Helena, AK 72342.
300 S. Wacker Dr., Chicago, IL 60601.
02816.
IL 60680.
IL 60680.
40201.
SYNTHETIC ORGANIC CHEMICALS. B72
TABLE L— Synthetic organic chemicals; Alphabetical directory of manufacturers.
BY COMPANY. 1972— CONTINUED
Armour- Dial, Inc
Armstrong Cork Co
Arol Chemical Products Co
Arsynco, Inc
Ashland nil, Inc
Ashland Chemical Co. Div
Astor Products, Inc., Blue Arrow Div
Astra Pharmaceutical Products, Inc
Atlantic Chemical Corp
Atlantic Richfield Co., ARCO Chemical Co.
Div.
Atlas Processing Co
BASF Wyandotte Corp
BP Oil Corp
J. T. Baker Chemical Co
Baltimore Paint 5 Chemical Corp
Baxter Laboratories, Inc
Baychera Corp. :
Chemagro Div
Verona Div
Bayoil Co., Inc
Beecham, Inc
Beech- Nut, Inc
Belding Chemical Industries
Bendix Corp., Friction Materials Div
Bennett's
Benzenoid Organics, Inc
Bemcolors-Poughkeepsie , Inc
Biocraft Laboratories, Inc
Bio- Derivatives Corp
Blackman Uhler Chemical Co
Borden, Inc., Borden Chemical Div
Borg-Wamer Corp., Marbon Chemical Div —
Borg-Wamer Corp., Weston Chemical Div —
Breddo Food Products Corp
Bristol-Meyers Co. , Bristol Laboratories
Div.
M. A. Bruder fi Sons, Inc
Buckeye Cellulose Corp
Buckman Laboratories, Inc
Budd Co., Polychem Div
Burdick f, Jackson Laboratories, Inc
Burroughs S Wellcome Co
CF Industries, Inc
Fremont Nitrogen Complex
CPC International, Inc
S. B. Penick Co
CPS Chemical Co
Samuel Cabot, Inc
Calcasieu Chemical Corp
Carborundum Co. , Coated Abrasives Div
Car gill , Inc
Carolina Processing Corp
Carpenter-Morton Co
Carus Corp., Carus Chemical Co. Div
Castle 5 Cook, Inc., Hawaii Region
Office address
P. 0. Box 4309, Chicago, IL 60680.
Liberty and Charlotte Sts . , Lancaster, PA 17604.
649 Ferry St., Newark, NJ 07105.
P. 0. Box 8, Carls tadt, NJ 07072.
1401 Winchester Ave., Ashland, KY 41101 and
P. n. Box 2458, Columbus, OH 43216.
5200 Blazer Blvd., Dublin, OH 43215.
5244 Edgewood Ct . , Jacksonville, FL 32203.
7-1/2 Neponset St., Worcester, MA 01606.
10 Kingsland Rd., Nutley, NJ 07110.
260 S. Broad St., Philadelphia, PA 19101.
P. 0. Box 9389, 3546 Midway St., Shreveport, LA 71109.
100 Cherry Hill Rd . , Parsippany, NJ 07054.
398 Midland Bldg. , Cleveland, OH 44115.
222 Red School Lane, Philipsburg, NJ 08865.
2325 Hollins Ferry Rd., Baltimore, MD 21230.
6301 Lincoln Ave., Morton Grove, IL 60053.
P. 0. Box 4913, Station "F", Kansas City, MO 64120.
lorio Ct., Union, NJ 07083.
2 Union St., Peabody, MA 01960.
65 Industrial S., Clifton, NJ 07012.
Church St., Canajorharie , NY 13317.
1430 Broadway, New York, NY 10018.
P. 0. Box 238, Troy, NY 12180.
65 W. 1st S. St., Salt Lake City, UT 84110.
P. 0. Box 157, Bellingham, MA 02019.
75 N. Water St., Poughkeepsie , NY 12602.
12 Industrial Way, Waldrich, NJ 07463.
174 E. Industry Ct . , Deer Park, NY 11729.
P. 0. Box 5627, Spartanburg, SC 29301.
50 W. Broad St., Columbus, OH 43215.
P. 0. Box 68, Washington, WV 26181.
103 Spring Valley Rd., Montvale, NJ 07645.
18th and Kansas, Kansas City, KS 66105.
P. 0. Box 657, E. Syracuse, NY 13257.
52d St. and Grays Ave., Philadelphia, PA 19143.
2899 Jackson Ave., Memphis, TN 38108.
1256 N. McLean Blvd., Memphis, TN 38108.
70 S. Chapel St., Newark, DE 19711.
1953 S. Harvey St., Muskegon, MI 49442.
3030 Comwallis Rd., Research Triangle Park, NC 27709
P. 0. Box 87, Harrison, TN 37341.
P. 0. Box 68, RFDH3, Fremont, NB 68025.
International Plaza, Englewood Cliffs, NJ 07632.
100 Church St., New York, NY 10007.
P. 0. Box 162, Old Bridge, NJ 08857.
One Union St., Boston, MA 02108.
P. 0. Box 1522, Lake Charles, LA 70601.
Walmore Rd. , P. 0. Box 477, Niagara Falls, NY 14302.
Cargill Bldg., Minneapolis, m 55402.
P.O. Box 161, Severn, NC 27877.
376 3d St., Everett, MA 02149.
1500 8th St., LaSalle, IL 61301.
P. 0. Box 338, Honolulu, HI 96801.
APPENDIX A
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers,
BY company, 1'^7?--Continued
Name of company
Office address
Celanese Corp. :
Celanese Chemical Co
Celanese Coatings Co
Celanese Fibers Co
Celanese Plastics Co
Champlin Petroleum Co
Charrain Paper Products Co
Charter International Oil Co
Chase Chemical Corp
Chattem Drug § Chemical Co., Chattara
Chemicals Div.
Chembond Corp
Chemed Corp . :
Dubois Chemicals Div
Vestal Laboratories Div
Chemetron Corp. :
Medical Products Div
Organic Chemical Div
Pigments Div
Chem-Fleur, Inc
Chemical Formulators, Inc
Chemlek Laboratories, Inc
Chemol, Inc
Chemplex Co
Cherokee Nitrogen Co
Chevron Chemical Co
Childs Pulp Colors, Inc
CHR Hansen's Laboratory, Inc ^.-
Ciba-Geigy Corp
Ciba Agrochemical Co
Ciba Pharmaceutical Co
Cincinnati Milacron Chemicals, Inc
Cindet Chemicals, Inc
Cities Service Co. :
Columbia Div
Copperhill Operations
Levey Div
Petrochemicals Group
Cities Service Oil Co
Clark Chemical Corp
W. A. Cleary Corp
Clintwood Chemical Co
Coastal States Petrochemical Co
Colgate-Palmolive Co
Collier Carbon 5 Chemical Corp
Colloids, Inc
Columbia Nitrogen Corp
Commercial Products Co. , Inc
Commercial Solvents Corp
Commonwealth Oil Refining Co. , Inc
Commonwealth Petrochemicals, Inc
Conap, Inc
Conchemco, Inc. :
Kansas City Div
Concord Chemical Co., Inc
Consolidated Papers, Inc
Continental Chemical Co
Continental Oil Co
Cook Paint 5 Varnish Co
Cooperative Farm Chemicals Association-
Cooper Polymers, Inc
245 Park Ave., New York, NY 10017.
1495 S. nth St., Louisville, KY 40208.
P. 0. Box 1414, Charlotte, NC 28201.
5S0 Broad St., Newark, NJ 07102.
P. 0. Box 9176, Corpus Christi, TX 78408.
800 Hoberg St., Green Bay, WI 54305.
P. 0. Box 5008, Houston, TX 77012.
3527 Smallman St., Pittsburgh, PA 15201.
1715 W. 38th St., Chattanooga, TN 37409.
P. 0. Box 270, Springfield, OR 97477.
Dubois Tower, Cincinnati, OH 45202.
4963 Manchester Ave., St. Louis, MO 63110.
1801 Lilly St., St. Louis, MO 63110.
P. 0. Box 480, Newport, TN 37821.
491 Columbia Ave., Holland, MI 49423.
200 Pulaski St., Newark, NJ 07105.
P. 0. Box 26, Nitro, WV 25143.
4040 W. 123d St., Alsip, IL 60658.
P. 0. Box 20687, Greensboro, NC 27420.
3100 Golf Rd., Rolling Meadows, IL 60008.
P. 0. Box 429, Pryor, OK 74361.
200 Bush St., San Francisco, CA 94120.
5 Albany St., Springfield, MA 01101.
9015 IV. Maple St., Milwaukee, WI 53214.
444 Saw Mill River Rd. , Ardsley, NY 10502.
P. 0. Box 1142, Greensboro, NC 27409.
556 Morris Ave., Summit, NJ 07901.
500 Jersey Ave., New Brunswick, NJ 08903 and West St.
Reading, OH 45215.
2408 Doyle St., Greensboro, NC 27406.
P. 0. Box 1522, Lake Charles, LA 70601.
Copperhill, TN 37317.
630 Glendale-Milford Rd., Cincinnati, OH 45215.
60 Wall St., New York, NY 10005.
P. 0. Box 300, Tulsa, OK 74102.
131st St. f, Kedzie Ave., Blue Island, IL 60406.
P. 0. Box 710, Somerset, NJ 08873.
4342 S. Wolcoth Ave., Chicago, IL 60609.
P. 0. Drawer 521, Corpus Christi, TX 78403.
300 Park Ave., New York, NY 10022.
461 S. Boyston, Los Angeles, CA 90017.
394 Frelinghuysen Ave., Newark, NJ 07114.
P. 0. Box 1483, Augusta, GA 30903.
117 Ethel Ave., Hawthorne, NJ 07641.
245 Park Ave., New York, NY 10017.
Petrochemical Complex, Ponce, PR 00731.
Petrochemical Complex, Ponce, PR 00731.
184 E. Union St., Allegany, NY 14706.
10000 Marshall Dr., Lenoxa, KS 66215.
18th 5 Garfield Sts., Kansas City, MO 64127.
17th f, Federal Sts., Camden, NJ 08105.
Wisconsin Rapids, WI 54494.
270 Clifton Blvd., Clifton, NJ 07015.
Park Eighty Plaza East, Saddle Brook, NJ 07662.
P. 0. Box 389. Kansas City, MO 64141.
P. 0. Box 308, Lawrence, KS 66044.
820 Woburn St., Wilmington, MA 01887.
SYNTHETIC OTiflNIC CHEHICALS, P7?
TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers^
BY COMPANY, 197?— CONTINUED
Name of company
Coopers Creek Chemical Corp
Copolymer Rubber 6 Chemical Corp
Cosden Oil § Chemical Co
Crest Chemical Corp
Croda, Inc
Crompton 5 Knowles Corp., Dyes 6 Chemical
Div.
Crosby Chemicals, Inc
Crown Central Petroleum Corp
Crown Metro, Inc
Crown Zellerbach Corp., Chemical Products
Div.
Dan River, Inc
Dart Industries, Inc.:
Azetec Chemicals Div
Rexene Polymers Co. Div
Synthetic Products Co. Div
Davies- Young Co
Dawe's Laboratories, Inc
Degen Oil f, Chemical Co
Dennis Chemical Co
Depaul Chemical Co., Inc
DeSoto, Inc
Detrex Chemical Industries, Inc
Dexter Chemical Corp
Hysol Div
Midland Div
Diamond Plastics, Inc
Diamond Shamrock Corp
Dixie Chemical Co
Dixie Pine Products Co., Inc
Dominion Products, Inc
Dover Chemical Co
Dow Badische Chemical Co
Dow Chemical Co
Dow Coming Corp
E. I. duPont de Nemours 5 Co., Inc
Dye Specialties, Inc
Eagle Pitcher Industries, Inc., Rubber
Products Div.
Eagle River Chemical Corp
Eastern Color 5 Chemical Co
Eastman Kodak Co
Tennessee Eastman Co. Div
Texas Eastman Co. Div
East Shore Chemical Co., Inc
Eastside Chemical Laboratory
Elan Chemical Co
Electro-Seal Glasflex Corp
El Paso Products Co
Emery Industries, Inc
Trylon Chemicals Div
Emkay Chemical Co
Endo Laboratories, Inc
Enenco, Inc
Epoxylite Corp
Essential Chemicals Group
Essex International, Inc., Electro-
Mechanical Div.
Ethyl Corp
Evans Chemetics, Inc
Office address
River Rd. , W. Conshohocken, PA 19428.
P. 0. Box 2591, Baton Rouge, LA 70821.
P. 0. Box 1311, Big Spring, Tx 79720.
225 Emmet St., Newark, NJ 07114.
51 Madison Ave., New York, NY 10010.
500 Pear St., Reading, PA 19603.
P. 0. Box 460, Picayune, LA 39466.
1 No. Charlis St., Baltimore, MD 21201.
12 Dudley St., Providence, RI 02901.
Camas, WA 98607.
Danville, VA 24541.
555 Garden St., Elyria, OH 44035.
W. lis Century Rd. , Paramus , NJ 07657.
1636 Wayside Rd., Cleveland, OH 44112.
2700 Wagner Place, Maryland Heights, MO 63043.
450 State St., Chicago Heights, IL 60411.
200 Kellogg St., Jersey City, NJ 07305.
2701 Papin St., St. Louis, MO 63103.
44-27 Purvis St., Long Island City, NY 11101.
1700 S. Mt. Prospect Ave., Des Plaines, IL 60018.
14 331 Woodrow Wilson, Detroit, MI 48232.
845 Edgewater Rd. , Bronx, NY 10474.
211 Franklin St., Olean, NY 14760.
E. Water St., P. 0. Box 620, Waukegan, IL 60085.
6421 Paramount Blvd., Long Beach, CA 90805.
100 Superior Ave., Cleveland, OH 44114.
3635 W. Dallas Ave., Houston, TX 77019.
P. 0. Box 470, Hattiesburg, MS 39401.
882 3d Ave., Brooklyn, NY 11232.
W. 15th and Davis Sts . , Dover, OH 44622.
P. 0. Drawer "D", Williamsburg, VA 23605.
Hopkins Bldg. , Midland, MI 48640.
P. 0. Box 1592, Midland, MI 48640.
DuPont Bldg., Wilmington, DE 19898.
26 Journal Sq., Jersey City, NJ 07306.
P. 0. Box 755, Denton, TX 76201.
P. 0. Box 665, Marinette, WI 54143.
35 Livingston St., Providence, RI 02904.
343 State St., Rochester, NY 14650.
P. n. Box 511, Kingsport, TN 37662.
P. 0. Box 7444, Longview, TX 75601.
1221 E. Barney Ave., Muskegon, HI 49443.
12880 NE Bellevue-Redmond Rd., Bellevue, WA 98005
268 Doremus Ave., Newark, NJ 07105.
Stirling, NJ 07980.
P. 0. Box 3986, Odessa, TX 79760.
4300 Carew Tower, Cincinnati, OH 45202.
P. 0. Box 628, Mauldin, SC 29662.
319 2d St., Elizabeth, NJ 07206.
1000 Stewart Ave., Garden City, NY 11530.
P. 0. Box 398, Memphis, TN 38101.
1901 Via Buxton, Anaheim, CA 92806.
28391 Essential Rd. , Merton, WI 53056.
1601 Wall St., Fort Wayne, IN 46804.
330 S. 4th St., Richmond, VA 23217.
90 Tokeneke Rd., Darien, CT 06820.
APPENDIX A
TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers,
BY COMPANY, 1972— CONTINUED
Name of company
Office address
Exxon Corp., Exxon Chemical Co. U.S.A.
FMC Corp . :
Fibers Div
Industrial Chemical Div
Industrial Chemical Div., Organic
Business Group
Niagara Chemical Div
FRP Co
Fabricolor Manufacturing Corp
Fairmount-Chemical Co., Inc
Far-Best Corp., 0. L. King Div
Famow, Inc
Felton International, Inc
Ferro Chemical Corp. :
Ferro Chemical Div
Grant Chemical Div
Fike Chemicals, Inc
Fine Organics, Inc
Finetex Corp
Firestone Tire 5 Rubber Co.:
Firestone Plastics Co. Div
Firestone SyTithetic Rubber 5 Latex Co.
Div.
First Chemical Corp
Fisher Chemical Co., Inc
Fleming Laboratories, Inc
Florasynth Laboratories, Inc
Foote Mineral Co
Formica Corp
Foster Grant Co. , Inc
France, Campbell 6 Darling, Inc
Freeman Chemical Corp
Frisch 6 Co., Inc
Fritzsche Dodge § Olcott, Inc
H. B. Fuller Co r
Fuller- O'Brien Corp
GAF Corp
Chemical Div
Gane's Chemical Works, Inc
Genera] Electric Co
Insulating Materials Dept
Silicone Products Dept
General Foods Corp., Maxwell House Div
General Latex § Chemical Corp
General Mills Chemicals, Inc
General Plastics Manufacturing Co
General Tire § Rubber Co., Chemical Div
P. D. George Co
George A. Jeffreys § Co
Georgia-Pacific Corp
Bellingham Div
Getty Oil Co
Gillette Chemical Co. Div. of Gillette Co.
Gilman Paint § Varnish Co
P. 0. Box 32 72, Houston, TX 77001 and Odenton,
MD 21113.
1617 John F. Kennedy Blvd., Philadelphia, PA 19103.
633 3d Ave., New York, NY 10017 and Sawyer Ave. §
River Rd., Town of Tonawanda, NY 14150.
635 3d Ave., New York, NY 10017.
100 Niagara St., Middleport, NY 14105.
P. 0. Box 349, Baxley, GA 31513.
24-1/2 Van Houten St., P. 0. Box 2398, Paterson.
NJ 07505.
117 Blanchard St., Newark, NJ 07105.
640 Gilman St., Berkeley, CA 94710.
77 Jacobus Ave., S. Kearney, NJ 07032.
599 Johnson Ave., Brooklyn, NY 11237.
P. 0. Box 46-349, 7050 Krick Rd. , Bedford, OH 44146.
P. 0. Box 263, Baton Rouge, LA 70821.
P. 0. Box 546, Nitro, WV 25143.
205 Main St., Lodi , NJ 07644.
418 Falmouth Ave., Elmwood Park, NJ 07407.
P. n. Box 699, Pottstown, PA 19464.
381 W. Wilbeth Rd., Akron, OH 44301.
P. 0. Box 1427, Pascagoula, MS 39567.
5200 Paul G. Blazer Memorial Pkwy., Dublin, OH 43216.
P. 0. Box 10373, Charlotte, NC 28201.
900 Van Nest Ave., Bronx, NY 10462.
Route 100, Exton, PA 19341.
120 E. 4th St., Cincinnati, OH 45202.
289 N. Main St., Leominster, MA 01453.
209 N. Michigan Ave., Kenilworth, NJ 07033.
222 E. Main St., Port Washington, WI 53074.
88 E. 11th St., Paterson, NJ 07524.
76 9th Ave., New York, NY 10011.
2400 Kasota Ave., St. Paul, MN 5S108.
450 E. Grand Ave., S. San Francisco, CA 94080.
1228 Chestnut St., Chattanooga, TN 37402.
P. 0. Box 12, Linden, NJ 07036.
535 5th Ave., New York, NY 10017.
1 Plastics Ave., Pittsfield, MA 01201 and 135 So.
Second St., Coshocton, OH 43812.
1 Campbell Rd. , Schenectady, NY 12306.
Waterford, NY 12188.
1125 Hudson St., Hoboken, NJ 07030.
666 Main St., Cambridge, MA 02139.
4620 W. 77th St., Mann, MN 55435
3481 S. 35th St., Tacoraa, WA 98409.
1 General St., Akron, OH 44309.
5200 N. 2d St., St. Louis, MO 63147.
P. 0. Box 709, Salem, VA 24153.
900 S.W. 5th Ave., Portland, OR 97240.
P. 0. Box 1236, Bellingham, WA 98225.
Delaware, DE 19706.
3500 W. 16th St., N. Chicago, IL 60064.
W. 8th and Pine Sts., Chattanooga, TN 37401.
SYNTHETIC ORGflNlC CHEMICALS. 1972.
TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers,
BY company. 1972— Continued
Name of company
Givaudan Corp
Glidden Durkee Famous Foods
Glyco Chemicals, Inc
B. F. Goodrich Co., B. F. Goodrich Chemical
Co. Div.
Goodyear Tire 5 Rubber Co
Gordon Corp
Gordon Chemical Co., Inc
W. R. Grace 5 Co. :
Agricultural Chemical Group
Dewey 5 Almy Chemical Div. Organic
Chemicals
Hatco Chemical Div
Marco Chemical Div
Polymers S Chemicals Div
Grain Processing Corp
Great American Chemical Corp
Great Lakes Chemical Corp
Great Western Sugar Co
Guardsman Chemical Coatings, Inc
Gulf Oil Corp. ;
Gulf Adhesives
Gulf Oil Chemicals Co. - U. S.
Guth Corp
H 6 N Chemical Co
Haag Laboratories, Inc
C. P. Hall Co. of Illinois
Handschy Chemical Co., Farac Oil and
Chemical Div.
Hanna Chemical Coatings Corp
Hardman, Inc
Harshaw Chemical Co. Div. of Kewanee Oil
Co.
Hart Products Corp
Haveg Industries, Inc
Hawkeye Chemical Co
Henkel , Inc
Hercor Chemical Corp
Hercules, Inc
Heresite 5 Chemical Co
Heterochemical Corp
Hewitt Soap Co., Inc
Hexagon Laboratories, Inc
Hexcel Corp., Rezolin Div
Hodag Chemical Corp
Hoffmann- LaRoche, Inc
Hoffman-Taff, Inc
Hooker Chemical Corp
Durex Div
Ruco Div
E. F. Houghton 6 Co
Humphrey Chemical Co
Philip A. Hunt Chemical Corp., Wayland
Chemical Div.
Huntington Laboratories, Inc
Husky Industries, Inc
Hynson, Westcott § Dunning, Inc
ICI America, Inc
ITT Rayonier, Inc
INDPOL-
Office address
ino Delawanna Ave., Clifton, NJ 07014.
2333 Logan Blvd., Chicago, IL 60647.
51 Weaver St., Greenwich, CT 06830.
6100 Oak Tree Blvd., Cleveland, OH 44131.
1144 E. Market St., Akron, OH 44313.
300 S. 3d St., Kansas City, KS 66118.
88 Webster St., Worcester, MA 01603.
P. 0. Box 277, Memphis, TN 38101.
Poisson Ave., Nashua, NH 03060.
King George Post Rd., Fords, NJ
1711 W. Elizabeth Ave., Linden,
62 Whittemore Ave., Cambridge
1600 Oregon St., Muscatine, L
08863.
J 07036.
02140.
52761.
MA
650 Water St., Fitchburg, MA 01420.
P. 0. Box 2200, West Lafayette, IN 47906.
P. 0. Box 5308, Terminal Annex, Denver, CO 80217.
1350 Steele Ave., S.W. , Grand Rapids, MI 49502, and
1350 S. 15th St., Louisville, KY 40210.
632 No. Cannon Ave., Lansdale, PA 19446.
P. 0. Box 2100, Houston, TX 77001.
P. 0. Box 302, Naperville, IL 60540.
90 Maltese Dr., Totowa, NJ 07512.
14010 S. Seeley Ave., Blue Island, IL 60406.
7300 S. Central Ave., Chicago, IL 60638.
13601 S. Ashland Ave., Riverdale, IL 60627.
P. 0. Box 147, Columbus, OH 43216.
600 Cortlandt St., Belleville, NJ 07109.
1945 E. 97th St., Cleveland, OH 44106.
173 Sussex St., Jersey City, NJ 07302.
900 Greenback Rd., Wilmington, DE 19808.
P. 0. Box 899, Clinton, LA 52733.
1301 Jefferson St., Hoboken, NJ 07030.
Petrochemical Complex, Ponce, PR 00731.
910 Market St., Wilmington, DE 19899.
822 S. 14th St., Manitowoc, WI 54220.
Ill E. Hawthorne Ave., Valley Stream, NY 11580.
333 Linden Ave., Dayton, OH 45403.
3536 Peartree Ave.. Bronx, NY 10475.
20701 Nordhoff St., Chatsworth, CA 91311.
7247 N. Central Park Ave., Skokie, IL 60076.
324-424 Kingsland St., Nutley, NJ 07110.
P. 0. Box 1246 SSS, Springfield, MO 65805.
MPO Box 8, Niagara Falls, NY 14302.
Walck Rd. , N. Tonawanda, NY 14121.
P. 0. Box 456, Burlington, NJ 08016.
303 W. Lehigh Ave., Philadelphia, PA 19133.
Devine St., North Haven, CT 0647 3.
P. 0. Box 0, Lincoln, RI 02865.
P. 0. Box 710, Huntington, IN 46750.
62 Perimeter Center E. , Atlanta, GA 30346.
Charles and Chase Sts . , Baltimore, MD 21201.
Concord Pike § Murphy Rd., Wilmington, DE 19899.
161 E. 42d St., New York, NY 10017.
8434 Rochester Ave., Cucamonga, CA 91730.
APPENDIX A
T'iBLE 1. --Synthetic organic CHEf^icALs; Alphabetical directory of manufacturers,
BY COMPANY, 197?— CONTINUED
Office address
Industrial Dyestuff Co
Inland Steel Co. , Inland Steel Container
Co.
Inmont Corp
ABI Div
International Flavors § Fragrances, Inc--
Intemational Minerals § Chemical Corp —
Interplastic Corp '■
lonac Chemical Co. Div. of Sybron Corp —
Ironsides Resins, Inc
Jefferson Chemical Co., Inc
Jenni son- Wright Corp
Andrew Jergens Co
Jersey State Chemical Co
Jewel Paint S Varnish Co 1
S. C. Johnson 5 Son, Inc
Jones -Blair Co
Jordan Chemical Co
Kaiser Aluminum 6 Chemical Corp. :
Kaiser Agricultural Chemicals Div
Kaiser Chemical
Kalama Chemical Co
Kali Manufacturing Co
Kay-Fries Chemicals, Inc
Kelly-Moore Paint Co
Kennecott Copper Corp.:
Chino Mines Div
Utah Copper Div
Kerr-McGee Chemical Corp
Keysor Century Corp
Keystone Chemurgic Corp
Keystone Color Works, Inc
Knapp Products, Inc
Koch Chemical Co
Kohler-McLister Paint Co
H. Kohnstamm G Co., Inc
Koppers Co., Inc
Organic Material Div
Roads Materials Div
Krafto Corp. :
Humko Products Div
Sheffield Chemicals Div
Kyanize Paints, Inc
Lakeside Laboratories Div. of Colgate-
Palmolive Co.
Lake States Div. of St. Regis Paper Co---
Lakeway Chemicals Inc
LaMotte Chemical Products Co
Laurel Products Corp
Leatex Chemical Co
Lemke Chemicals, Inc
Lever Brothers Co
C. Lever Co., Inc
Eli Lilly 5 Co
Lonza, Inc
Lubrizol Corp
M and T Chemicals, Inc
Magnolis Industries, Inc., Milliken
Chemical Div.
P. 0. Box 4249, E. Providence, RI 02914.
4300 W. 130th St., Chicago, IL 60658.
609 Lafayette Ave., Hawthorne, NJ 07506.
5935 Milford Ave., Detroit, MI 48210.
521 W. 57th St., New York, NY 10019.
IMC Plaza, Libertyville, IL 60948.
2015 NE. Broadway St., Minneapolis, MN 55413.
Birmingham, NJ 08011.
270 W. Mound St., Columbus, OH 43216.
P. 0. Box 53300, Houston, TX 77052.
P. 0. Box 691, Toledo, OH 43694.
2535 Spring Grove Ave., Cincinnati, OH 45214.
59 Lee Ave., Haledon, NJ 07508.
345 N. Western Ave., Chicago, IL 60612.
1525 Howe St., Racine, WI 53403.
2728 Proctor, Dallas, TX 75235.
1830 Columbia Ave., Folcraft, PA 19032.
P. 0. Box 246, Savannah, GA 31402.
P. 0. Box 337, Gramercy, LA 70052.
P. 0. Box 427, Kalama, WA 98625.
427 Moyer St., Philadelphia, PA 19125.
360 Lexington Ave., New York, NY 10017.
1015 Commercial St., San Carlos, CA 94070.
Hurley, MN 88043.
P. 0. Box 11299, Salt Lake City, UT 84111.
P. 0. Box 25861, Oklahoma, OK 73125.
P. 0. Box 308, Saugus, CA 91350.
R. D. 2, Bethlehem, PA 18017.
151 W. Gay Ave., York, PA 17403.
187 Garibaldi Ave., Lodi , NJ 07644.
P. 0. Box 2256, Wichita, KS 67201.
1201 Osage St., Denver, CO 80201.
161 Avenue of the Americas, New York, NY 10013.
Koppers Bldg., Pittsburgh, PA 15219.
Koppers Bldg., Pittsburgh, PA 15219.
Koppers Bldg., Pittsburgh, PA 15219.
P. 0. Box 398, Memphis, TN 38101.
2400 Morris Ave., Union. NJ 07083.
2d and Boston Sts . , Everett, MA 02149.
1707 E. North Ave., Milwaukee, WI 53201.
603 W. Davenport St., Rhinelander, WI 54501.
S025 Evanston Ave., Muskegon, MI 49443.
Chestertown, MD 21620.
2600 E. Tioga St., Philadelphia, PA 19134.
2722 N. Hancock St., Philadelphia, PA 19133.
195-203 Main St., Lodi, NJ 07644.
390 Park Ave., New York, NY 10022.
736 Dunks Ferry Rd., Comwells Hgts, PA 19020.
307 E. McCarty St., Indianapolis, IN 46206 and G.P.O.
Box 4388, San Juan, PR 00936.
22-10 Route 208, Fair Lawn, NJ 07410.
29400 Lakeland Blvd., Wickliffe, OH 44092.
Woodridge Rd. f, Randolph Ave., P. 0. Box 1104,
Rahway, NJ 07065.
P. 0. Box 817, Inman, SC 29349.
SYNTHETIC ORGANIC CHEMICALS, 1P7?
TABLE 1. --Synthetic organic chemicals; Alphabetical directory of manufacturers,
BY COMPANY, 197?— CONTINUED
Name of company
Office address
Magruder Color Co., Inc
Mallinckrodt Chemical Works
Washlne Div
Marathon Horco Co
Marathon Oil Co., Texas Refining Div
Marblette Co
Harden- Wi Id Corp
Marlowe-Van Loan Corp
Martin-Marietta Corp.:
Sodyeco Div
Max Marx Color 5 Chemical Co
Masonite Corp., Alpine Chemical Div
Otto B. May, Inc
McCloskey Varnish Co
McLaughlin normley King Co
Mead Johnson 6 Co
Merck 5 Co., Inc
Merichem Co
Michigan Chemical Corp
Midwest Manufacturing Corp
Miles Laboratories, Inc., Marschall Div
Millmaster Onyx Corp.:
A. Gross 6 Co. Div
Millmaster Chemical Div. , Berkely
Chemical Dept.
Onyx Chemical Co. Div
Refined- Onyx Div
Minnesota Mining 5 Manufacturing Co
Minnesota Paints, Inc
Miranol Chemical Co., Inc
Mississippi Chemical Corp
Mobay Giemical Co
Mobil nil Com
Mobil Chemical Co.:
Chemical Coatings Div
Industrial Chemicals Div
Mona Industries, Inc
Monochem, Inc
Monroe Chemical Co
Monsanto Co
Bircham Bend Plant
Chocolate Bayou Plant
Plastics Div
Textiles Div
Montrose Chemical Corp. of California
Mooney Chemicals, Inc
Moretex Chemical Products, Inc
Morton Chemical Co. Div. of Morton-Norwich
Products, Inc.
Motomco, Inc
Murphy- Ph oenix Co
NL Industries, Inc
Nalco Chemical Co
National Biochemical Co
National Casein Co
National Distillers 5 Chemical Corp., U.S.
Industrial Chemicals Co. Div.
1 Virginia St., Newark, NJ 07114.
3600 N. 2d St., St. Louis, MO 6?>147.
165 Main St., Lodi , NJ 07644.
P. 0. Drawer C, Dickinson, TX 77539.
P. 0. Box 1191, Texas City, TX 77590.
37-31 30th St., Long Island City, NY 11101.
500 Columbia St., Somerville, MA 02143.
1511 Joshua Circle, High Point, NC 27261.
P. 0. Box 10098
192 Coit St. , I:
P. 0. Box 2392,
52 Amsterdam St
7600 State Rd. ,
1715 SE. 5th St
2404 Penna. St.
126 E. Lincoln Ave., Railway
1914 Haden Rd. , Houston, TX
Charlotte, NC 28201.
vington, NJ 07111.
Gulfport, MS 39503.
, Newark, NJ 07105.
Philadelphia, PA 19136.
, Minneapolis, MN 55414.
Evansville, IN 47721.
NJ 07065 .
77015.
351 E. Ohio St., Chicago, XL 60611.
Oak St. and Bluff Rd. , Burlington, lA 52601.
1127 Myrtle St., Elkhart, IN 46514.
652 Doremus Ave., Newark, NJ 07105.
99 Park Ave., New York, NY 10016.
190 Warren St., Jersey City, NJ 07302.
624 Schuyler Ave., Lyndliurst, NJ 07071.
3M Center, St. Paul, MN 55101.
1101 S. 3d St., Minneapolis, MN 55415.
277 Coit St., Irvington, NJ 07111.
P. 0. Box 388, Yazoo City, MS 39194.
Penn Lincoln Parkway, W. Pittsburgh, PA 15205.
P. 0. Box 900, Dallas, TX 75221.
1024 South Ave., Plainfield, NJ 07062.
P. 0. Box 26683, Richmond, VA 23261.
65 E. 23d St., Paterson, NJ 07524.
P. 0. Box 488, Geismar, LA 70734.
Saville Ave. at 4th St., Eddystone, PA 19013.
2710 Lafayette St., Santa Clara, CA 95052 and
Lindbergh Blvd., St. Louis, MO 63166.
190 Grochraal Ave., Indian Orchard, MA 01051.
P. 0. Box 711, Alvin, TX 77511.
730 Worcester St., Indian Orchard, MA 01101;
5100 W. Jefferson Ave., Trenton, MI 48183;
River Rd., Addyston, OH 45001 and P. 0. Box
Texas City, TX 77591.
800 N. Lindbergh Blvd., St. Louis, MO 63156.
500 S. Virgil Ave,, Los Agneles, CA 90005.
2301 Scranton Rd. , Cleveland, OH 44113.
314 W. Henry St., P. 0. 1799, Spartanbury, SC
110 N. Wacker Dr., Chicago, XL 60606.
89 Terminal Ave., Clark, NJ 07066.
9505 Cassius Ave., Cleveland, OH 44105.
111 Broadway, New York, NY 10006.
180 N. Michigan Ave., Chicago, IL 60601.
3127 W. Lake St., Chicago, IL 60612.
601 W. 80th St., Chicago, IL 60620.
99 Park Ave., New York, NY 10016.
APPEmiX A
TABLE 1.— Synthetic organic chemicals; Alphabetical directory of manufacturers.
BY company. 1972--Continued
Name of company
Office address
National Hilling § Chemical Co
National Petro Chemical Corp
National Starch 6 Chemical Corp
Nease Chemical Co., Inc
Nepera Chemical Co., Inc
Neville Chemical Co
Nilok Chemicals, Inc
Ninak, Inc
Nipro, Inc
Norac Co. , Inc
Mathe Chemical Co. Div
Norda, Inc
Norris Paint 5 Varnish Co
North American Chemical Co
North American Rockwell Corp
Northern Fine Chemicals, Inc
Northern Petrochemical Co
Northwestern Chemical Co
Northwest Petrochemical Corp
Norwich Pharmacal Co
Nostrip Chemical Works, Inc
Noury Chemical Corp
Novamont Corp., Neal Works
Nyanza, Inc
0 ' Bri en Corp
Occidental Chemical Co
01 in Corp
Agricultural Chemicals Div
Orbis Products Corp
Organics , Inc
Original Bradford Soap Works, Inc
Owens-Coming Fiberglas Corp
Oxirane Chemical Co
Oxochem Enterpri se
P-L Biochemicals, Inc
PPG Industries, Inc
PVO International, Inc., Chemical
Specialties Div.
Pace National Corp
Pacific Resins 5 Chemicals, Inc
Pantasote Co. of New York, Inc
Parke Davis § Co
Passaic Color f, Chemical Co
C. H. Patrick 5 Co., Inc
Pears all Corp
Peck's Products Co
Peerless Oiemical Co
Pellon Corp., Disogrin Industries Div-
Pelron Corp
Pennsylvania Industrial Chemical Corp-
Pennsylvania Refining Co
Pennwalt Corp
Lucidol Div --
Perry 5 Derrick Co., Inc
Petrochemical Investment Corp
Petrochemicals Co., Inc
Petro-Tex Chemical Corp
Pfanstiehl Laboratories, Inc
Pfister Chemical, Inc
Pfizer, Inc
4601 Flat Rock Rd. , Philadelphia, PA 19127.
99 Park Ave., New York, NY 10016.
750 3d Ave., New York, NY 10017.
P. 0. Box 221, State College, PA 16801.
Route 32, Harriman, NY 10926.
Neville Island, P. 0., Pittsburgh, PA 15225.
2235 Langdon Farm Rd., Cincinnati, OH 45230.
301 S. Harwood St., Dallas, TX 75221.
P. 0. Box 1483, Augusta, GA 30903.
405 S. Motor Ave., Azusa, CA 91703.
169 Kennedy Dr., Lodi , NJ 07644.
475 inth Ave., New York, NY 10001.
P. 0. Box 2023, Salem, OR 97308.
19 Chestnut St., Cambridge, MA 02139.
4501 Benefit Ave., Ashtabula, OH 44004.
93 Main St., Franklin, NJ 07416.
2.350 E. Devon Ave., Des Plaines, IL 60018.
120 N. Aurora St., W. Chicago, IL 60185.
P. 0. Box 99, Anacortes, WA 98221.
17 Eaton Ave., Norwich, NY 13815.
P. 0. Box 160, Pedrichtown, NJ 08067.
2153 Lockport-Olcott Rd. , Burt, NY 14028.
P. 0. Box 189, Kenova, WV 25530.
Maguno Rd. , Ashland, MA 01721.
2001 W. Washington Ave., South Bend, IN 46627.
P. 0. Box 198, Lathrop, CA 95330.
120 Long Ridge Rd., Stamford, CT 06904.
1120 Marshall St., P. 0. Box 991, Little Rock, AR 72203
475 10th Ave., New York, NY 10008.
7125 N. Clark St., Chicago, IL 60628.
200 Providence St., W. Wartdck, RI 02893.
Fiberglas Tower, Toledo, OH 43659.
10801 Choate Rd., Houston, TX 77062.
P. 0. Box 27, King George Post Rd., Fords, NJ 08863.
1037 W. McKinley Ave., Milwaukee, WI 53205.
1 Gateway Center, Pittsburgh, PA 15222.
416 Division St., Boonton, NJ 07005.
500 7th Ave., S., Kirland, WA 98033.
1754 Thome Rd., Tacoma, WA 93421.
26 Jefferson St., Passaic, NJ 07055.
Jos. Carapau at the River, Detroit, MI 48232.
28-36 Paterson St., Paterson, NJ 07501.
P. 0. Box 2526, Greensville, SC 29602.
P. 0. Box 437, Houston, TX 77025.
610 E. Clarence Ave., St. Louis, MO 63147.
12416 Cloverdale Ave., Detroit, MI 48204.
Perimeter Rd., Municipal Airport, Manchaster, NH 07103.
7847 W. 47th St., Lyons, IL 60534.
120 State St., Clairton, PA 15025.
Union Bank Bldg. , Butler, PA 16001.
Three Penn Center, Philadelphia, PA 19102.
1740 Militar\' Rd., Buffalo, NY 14240.
2510 Highland Ave., Norh'ood, OH 45212.
P. 0. Drawer F, Channelview, TX 77530.
P. 0. Box 2199, Fort Worth, TX 76101.
P. n. Box 25 84, Houston, TX 77001.
1219 Glen Rock Ave., Waukegan, IL 60085.
Linden Ave., Ridgefield, NJ 07657.
235 E. 42d St., New York, NY 10017.
SYNTHETIC 0PG/\NIC CHEi'iICALS. 1°72
TABLE 1.— Synthi^tic organic chemicals: Alphabetical directory of manufacturers,
BY company. 1972--CONTINUED
Pharmachem Corp
Phillips Petroleum Co
Phillips Puerto Rico Core, Inc
Pierce Chemical Co
Pilot Chemical Co
Pioneer Plastics Corp
Pitt-Consol Chemical Co
Plastics Engineering Co
Plastics Manufacturing Co
Plex Chemical Corp
Polak's Frutal Works, Inc
Polymer Corp
Polymer Industries, Inc
Polyrez Co., Inc
Polyvinyl Chemical Ind. Div. of
Beatrice Foods Co.
Pratt 5 Lambert, Inc
Premier Malt Products, Inc
Premier Petrochemicl Co
Princeton Chemical Research, Inc
Proctor 5 Gamble Co., Proctor fi Gamble
Mfg. Co.
Products Research 5 Chemical Corp.,
Chemical S Sealants Div.
Proctor Chemical Co., Inc
Productol Chemical Co., Inc
Publicker Industries, Inc
Puerto Rico Chemical Co., Inc
Puerto Rico Olefins
Purex Corp., Ltd
Washburn- Lans on Co. Div
Office address
Quaker Oats Co
K. J. Quinn 5 Co
719 Stefko Blvd., Bethlehem, PA 18018.
7472 Frank Phillips Bldg., Bartlesville, 0
GPn Box 4129, San Juan, PR 00936.
P. 0. Box 117, Rockford, IL 61105.
11756 Burke St., Santa Fe Springs, CA 906
Pionite Rd. , Auburn, HE 04210.
Park Eighty Plaza East, Saddle Brook, NJ
1607 Geele Ave., Sheboygan, WI 53081.
2700 S. Westmoreland Ave., Dallas, TX 752
1205 Atlantic St., Union City, CA 94487.
33 Sprague Ave., Hiddletown, NY 10940.
2120 Fairmont Ave., Reading, PA 19603.
Viaduct Rd., Springdale, CT 06879.
S. Columbia St., Woodbury, NJ 08096.
730 Main St., Wilmington, HA 01887.
P. n. Box 22, Buffalo, NY 14240.
917 W. Juneau Ave., Milwaukee, WI 53201.
530 N. Witter, Pasadena, TX 77501.
P. 0. Box 651, Princeton, NJ 08540.
301 E. 6th St., Cincinnati, OH 45202.
2912 Empire Ave., Burbank, CA 91504.
P. 0. Box 399, Salisbury, NC 28144.
13215 E. Penn St., IVhittier, CA 90602.
1429 Walnut St., Philadelphia, PA 19102.
P. 0. Box 496, Arecibo, PR 00613.
Firm Delivery, Ponce, PR 00731.
5101 Clark Ave., Lakewood, CA 90712.
2258 Elston Ave., Chicago, IL 60614.
Quaker Chemical Corp Lime 5 Elm Sts . , Conshohocken, PA 19428.
345 Merchandise Mart Plaza, Chicago, IL 60654.
195 Canal St., Maiden, MA 02148.
Inc-
Inc-
R.S.A. Corp
Rachel le Laboratories,
Racon, Inc
Raybestos-Manhattan, Inc., Raybestos Div-
Red Spot Paint 5 Varnish Co., Inc
Reheis Chemical Co. Div. of Armour
Pharmaceutical Co.
Reichhold Chemicals, Inc
Reilly Tar § Chemical Corp
Reliance Universal,
Resin Div
Remington Arms Co.,
Resyn Co3rp
Rhodia, Inc
Richardson Co
Inc. of Texas-
Ridgway Color 5 Chemical-
Riker Laboratories, Inc.,
Rilsan Corp
F. Ritter 5 Co
Riverdale Chemical Co
Robeco Chemicals, Inc
Roehr Chemicals, Inc
Rogers Corp
Rohm 5 Haas Co
Sub. of 3M Co-
690 Sawmill River Rd. , Ardsley, NY 10502.
700 Henry Ford Ave., Long Beach, CA 90801.
P. 0. Box 198, 6040 S. Ridge Rd. , Witchita, KS 67201.
74 E. Main St., Stratford, CT 06497.
966 E. Columbia St., Evansville, IN 47708.
325 Snyder Ave., Berkeley Heights, NJ 07922.
525 N. Broadway, White Plains, NY 10602.
1615 Merchants Bank, 11 S. Meridan St. Indianapolis,
IN 46204.
6901 Cavalcade St., Houston, TX 77001.
4730 Crittenden Dr., Louisville, KY 40221.
939 Bamum Ave., Bridgeport, CT 06602.
1401 W. Blancke St., Linden, NJ 07036.
120 Jersey Ave., New Brunswick, NJ 08903.
2708 Lake St., Melrose Park, IL 60160 and 345 Morgan
Lane, West Haven, CT 06516.
75 Front St., Ridgway, PA 15853.
19901 Nordhoff St., Northridge, CA 91324.
139 Harristown Rd. , Glen Roc, NJ 07452.
4001 Goodwin Ave., Los Angeles, CA 90039.
220 E. 17th St., Chicago Heights, IL 60411.
51 Madison Ave., New York, NY 10010.
52-20 37th St., Long Island City, NY 11101.
Main St., Rogers, CT 06263.
Independence Mall West, Philadelphia, PA 19105.
rtPf'ENDIX A
TABLE 1. —Synthetic organic chemicals: Alphabetical directory of manufacturers,
BY COMPANY, .T^Z?— CONTINUED
Name of company
Office address
Rubicon Chemicals, Inc
SCM Corp., Glidden-Durkee Div
Safeway Stores, Inc
Salem Oil 5 Grease Co
Salsbury Laboratories
Sandoz, Inc., Sandoz Color 5 Chemical Di\
Sartomer Industries, Inc
Schenectady Chemicals, Inc
Scher Bros., Inc
R. P. Scherer Com
Schering Corp
Scholler Bros., Inc
Scientific Protein Labs., Inc
Scott Paper Co
Seaboard Chemicals, Inc
G. D. Searle 5 Co
Seydel-Woolley § Co., Inc
Shakespeake Co. , Industrial Products Div-
Shanco Plastics 5 Chemicals, Inc
Shell 5 Commonwealth Chemicals, Inc
Shell nil Co
Shell Chemical Co. Div
Shepherd Chemical Co
Sherwin-Williams Co
George F. Siddall Co., Inc
Simpson Timber Co
Sinclair- Koppers Co
Sinclair- Koppers Chemical Co
Sinclair Paint Co., Div. of Insilco Corp-
Sipers Chemical Coatings Co
Skelly Oil Co
G. Frederick Smith Chemical Co
Smith, Kline 5 French Laboratories
Sobin Chemicals, Inc., Montrose Chemical
Div.
Solar Chemical Corp
Soluol Chemical Co., Inc
Solvent Chemical Co., Inc
Sou-Tex Chemical Co., Inc
Southeastern Adhesives
Southern Chemical Products Co
Southern Sizing Co
Spaulding Fibre Co., Inc
E. R. Squibb 6 Sons, Inc
A. E. Staley Manufacturing Co
Staley Chemicals Div
Textile Div
Stamford Chemical Industries
Standard Brands, Inc., Clinton Com
Processing Co. Div.
Standard Brands Chemical Industries, Inc-
Standard Chlorine of Delaware, Inc
Standard Oil Co. of California, Chevron
Chemical Co.
Standard Oil Co. of Ohio
Stange Co
P. 0. Box 517, Geismar, LA 70734.
900 Union Commerce Bldg. , Cleveland, OH 44115.
8390 Capwell Dr., Oakland, CA 94604.
60 Grove St., Salem, MA 01970.
2000 Rockford Rd. , Charles City, lA S0616.
P. 0. Box 357, Fair Lawn, NJ 07410 and Route No. 10,
P. 0. Box 11, E. Hanover, NJ 07936.
P. 0. Box 56, Essington, PA 19029.
P. 0. Box 1046, Schenectady, NY 12301.
P. 0. Box 538, Allwood Station, Clifton, NJ 07012.
9425 Grinnell Ave., Detroit, MI 48213.
1011 Morris Ave., Union, NJ 07083.
Collins and Westmoreland Sts . , Philadelphia, PA 1913
P. 0. Box 1409, Madison, WI 53701.
Oconto Falls, WI 54154.
30 Foster St., Salem, MA 01970.
P. 0. Box 5110, Chicago, IL 60680.
762 Marietta Blvd., NW., Atlanta, GA 30318.
P. 0. Box 246, Columbia, SC 29202.
Ill Wales St., Tonawanda, NY 14150.
Petrochemical Complex, Ponce, PR 00731.
P. 0. Box 2463, Houston, TX 77001.
One Shell Plaza, P. 0. Box 2463, Houston, TX 77001.
4900 Beech St., Cincinnati, OH 45212.
101 Prospect Ave., NW Cleveland, OH 44101.
P. 0. Box 925, Spartanburg, SC 29301.
2301 N. Columbia Blvd., Portland, OR 97217.
900 Koppers Bldg., Pittsburgh, PA 15219.
9822 La Porte Freeway, Houston, TX 77012.
3960 E. Washington Blvd., Los Angeles, CA 90023.
P. 0. Box 13090, Pittsburgh, PA 15243.
P. 0. Box 1650, Tulsa, OK 74102.
867 McKinley Ave., Columbus, OH 43223.
1500 Spring Garden St., Philadelphia, PA 19101.
100 Listen Ave., Newark, NJ 07105.
P. 0. Box 90, Leominster, MA 01453.
Green Hill and Market Sts., W. Warwick, RI 02893.
335-341 Commercial St., Maiden, MA 02148.
E. Cataivba Ave., Mount Holly, NC 28120.
P. 0. Box 791, Lenoir, NC 28645.
P. 0. Box 205, Macon, GA 31202.
P. 0. Box 90987, East Point, GA 30344.
310 Wheeler St., Tonawanda, NY 14150.
Georges Rd., Brunswick, NJ 08903.
2200 Elorado St., Decatur, IL 62525.
320 Schu>'ler Ave., Kearny, NJ 07032.
6301 St. John Lane, Charlotte, NC 28210.
4300 Carew Towers, Cincinnatti , OH 45202.
1251 Beaver Channel Parkway, Clinton, lA 52733.
P. 0. Drawer K, Dover, DE 19901.
1035 Belleville Turnpike, Kearny, NJ 07032.
200 Bush St., San Francisco, CA 94120.
Midland Bldg., Cleveland, OH 44115.
342 N. Western Ave., Chicago, IL 60612.
552-743 0-74-17
SYNTHETIC nRG'\NIC CHE^IICALS, 1972-
TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers
BY company. 1972— Continued
Name of company
Stauffer Chemical Co.:
Agricultural Div
Calhio Chemicals, Inc. Div
Industrial Div
Plastics Div
Specialty Chemical Div
Specialty Chemical Div. , Benzol
Products.
SWS Silicones Div
Stepan Chemical Co
National Polycheraicals Div
Sterling Drug, Inc. :
Glenbrook Laboratories Div
Hilton-Davis Chemical Co. Div
Thomasset Colors Div
Winthrop Laboratories Div-"-
Sterwin Chemicals, Inc
Story Chemical Corp., Ott Div
Styrochem Corp
Sugar Beet Products Co
Sun Chemical Corp
Sunkist Growers, Inc
Sun Oil Co
Sun Olin Chemicl Co
Suntide Refining Co
Tanatex Chemical Corp
Charles S. Tanner Co
Teknor Apex Co
Tenneco Chemicals, Inc
Cal/Ink Div
Tenneco Oil Co
Terra Chemicals International, Inc
Texaco, Inc
Texas Alkyls, Inc
Texas-U.S. Chemical Co
Tex Chem Co., Inc
Texize Chemicals, Inc
Text il ana Corp
Textllana Nease, Inc
Textron, Inc., Spencer Kellogg Div
Thiokol Chemical Corp
Thomason Industries, Inc., Southern Resin
Div.
Thompson-Hayward Chemical Co
Tizon Chemical Corp
Toms River Chemical Corp
Trade Enterprises, Inc
Arthur C. Trask Co
Office address
636 California St.
636 California St.
636 California St.
636 California St., San Francisco
636 California St., San Francisco
Meadow Rd., Edison
San Francisco, CA
San Francisco, CA
San Francisco, CA
08817.
94119
94119
94119
94119
94119
636 California St., San Francisco, CA 94119.
RR #1, Elwood, IL 60421 and 100 West Hunter Ave.,
Maywood, NJ 07607.
51 Eames St., Wilmington, MA 01887.
90 Park Ave., New York, NY 10016.
2233 Langdon Farm Rd. , Cincinnati, OH 45237.
120 Lister Ave., Newark, NJ 07105.
90 Park Ave., New York, NY 10016.
Military Rd. , Rothschild, WI 54474.
500 Agard Rd., Muskegon, MI 49945.
Petrochemical Complex, Ponce, PR 00731.
P. 0. Box 1387, Saginaw, MI 48605.
441 Tompkins Ave., Staten Island, NY 10305 and
P. 0. Box 70, Chester, SC 29706.
P. 0. Box 7888, Valley Annex, Van Nuys , CA 91409.
240 Radnor-Chester Rd. , St. Davids, PA 19087.
P. 0. Box F, Claymount, DE 19703.
P. 0. Box 2608, Corpus Christi , TX 78403.
P. 0. Box 388, Lyndhurst, NJ 07071.
1305 Barcelona Dr., Donaldson Center, Greensville, SC
29606.
505 Central Ave., Pawtucket, RI 02662.
Park Eighty Plaza West-One, Saddle Brook, NJ 07662.
711 Camelia St., Berkeley, CA 94710.
P. 0. Box 2511, Houston, TX 77001.
507 6th St., Sioux City, lA 51121.
135 E. 42d St., New York, NY 10017.
P. 0. Box 600, Deer Park, TX 77536.
P. 0. Box 667, Port Neches, TX 77651.
20-21 IVagaraw Rd. , Fair Lawn, NJ 07410.
P. 0. Box 368, Greenville, SC 29602.
12607 Cerise Ave., Hawthorne, CA 90250.
12607 Cerise Ave., Hawthorne, CA 90250.
120 Delaware Ave., Buffalo, NY 14240.
P. 0. Box 27, Bristol, PA 19007.
P. 0. Drawer 1600, Fayetteville. NC 29302.
5200 Speaker Rd. , Kansas City, MO 66110 and
2 E. Madison St., Waukegan, IL 60085.
Locktown Rd., Flemington, NJ 08822.
P. 0. Box 71, Toms River, NJ 08753.
Ketometer 77.5, P. 0. Box 296, Humacao,
State Road 3,
PR 00661.
P. 0. Box 134
Argo, IL 60501.
APPEmiX A
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers^
BY company, 1972--CoNTinuED
Name of company
Office address
Triad Chemical
Troy Chemical Co
Joseph Turner S Co
USS Agri- Chemicals Div of U.S. Steel Corp-
USS Chemicals Div. of U.S. Steel Corp
Paul Hulich 6 Co., Inc
Ungerer S Co
Union-Camp Corp
Harchem Div
Union Carbide Corp
Union Oil Co. of California
Uniroyal, Inc., Chemical Div
United Chemical Corp. of Norwood
United Chemical Products Corp
United- Erie, Inc
United Merchants 5 Manufacturers, Inc.,
Roma Chemical Div.
U.S. Borax Research Corp
U.S. Industries, Inc., E. Helman Co. Div--
U.S. Oil Co
U.S. Pipe § Foundry Co
U.S. Plywood WCM Operations, Shasta Area--
Universal Chemicals Corp
Universal Oil Products Co
UOP Chemical Div
Upjohn Co
Fine Chemical Div
Valchem Chemical Div. of United Merchants
§ Manufacturers, Inc.
Valentine Sugars, Inc
Valley Nitrogen Producers, Inc
Van De Mark Chemical Co., Inc
Vanderbilt Chemical Corp
Van Dyk 5 Co., Inc
Velsicol Chemical Corp
Ventron Corp
Wood Ridge Chemical
Vermilye-Bell
Vineland Chemical Co
Virginia Chemicals, Inc
Vistron Corp
Silraar Div
Vitamins , Inc
Vulcan Materials Co., Chemicals Div
Wamer-Jenkinson Manufacturing Co
West Agro-Chemicals, Inc
West Coast Adhesives Co
Westinghouse Electric Corp., Industrial
Plastics Div., Chemical Products Plant.
Westvaco Corp., Polychemicals Dept
Weyerhaeuser Co
White 8 Bagley Co
P. 0. Box 310, Donaldsonville, LA 70346.
One Avenue L, Newark, NJ 07105.
P. 0. Box 88, Ridgefield, NJ 07657.
30 Pryor St. S.W. Atlanta, GA 30301.
600 Grant St., Rm. 2880, Pittsburgh, PA 1S219.
90 West St., New York, NY 10006.
161 Avenue of the Americas, New York, NY 10013.
P. 0. Box 6170, Jacksonville, Fl 32205.
P. 0. Box 220, Dover, NJ 44622.
270 Park Ave., New York, NY 10017.
P. 0. Box 7600, Los Angeles, CA 90051.
Emic Bldg., Naugatuck, CT 06770.
P. n. Box 367, Endicott St., Norwood, MA 02062.
York and Colgate Sts., Jersey City, NJ 07302.
438 Huron SE., Erie, PA 16512.
749 Quequechan St., Fall River, MA 02721.
3075 Wilshire Blvd., Los Angeles, CA 90005.
P. 0. Box 5129, Akron, OH 44313.
P. 0. Box 4228, E. Providence, RI 02914.
3300 1st Ave., N. , Birmingham, AL 35202.
P. 0. Box 2713, Redding, CA 96001.
1224 Mendon Rd. , Ashton, RI 02864.
70 UOP Plaza, Algonquin 8 Mt . Prospect,
Des Plains, IL 60018.
State Highway 17, E. Rutherford, NJ 07073.
7000 Portage Rd. , Kalamazoo, MI 49001.
410 Sackett Point Rd., North Haven, CT 06473.
1407 Broadway, New York, NY 10018.
726 IVhitney Bldg., New Orleans, LA 70130.
1221 Van Ness Ave., Fresno, CA 93721.
N. Transit Rd. , Lockport , NY 14094.
33 Taylor Ave., Bethel, CT 06801.
Main 5 Williams Sts., Belleville, NJ 07109.
341 E. Ohio St., Chicago, IL 60611.
12-16 Congress St. Beverly, MA 01915.
Park Place East, Wood Ridge, NJ 07075.
21707 Bothell Way, Bothell, WA 98011.
W. tVheat Rd. , Vineland, NJ 08360.
3340 W. Norfolk Rd., Portsmouth, VA 23703.
Midland Bldg., Cleveland, OH 44115.
12333 S. Van Ness Ave., Hawthorne, CA 90250.
401 N. Michigan Ave., Suite 2730, Chicago, IL 60611.
P. 0. Box 545, Wichita, KS 67201.
2526 Baldwin St., St. Louis, MO 63106.
501 Santa Fe, Kansas City, HO 64105.
11104 NW. Front .Ave., Portland, OR 97231.
Manor, PA 15665.
P. 0. Box 5207, N. Charleston, SC 29406.
118 S. Palmetto Ave., Marshfield, WI 54449.
P. 0. Box 706. Worcester, MA 01613.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 1,--Synthetic organic chemicals: Alphabetical directory of manufacturers,
BY COMPANY, 1972--CoNTINUED
Identi-
fication
code
Name o£ company
Office address
IVHI
l«HL
APT
IfflC
IWW
WIG
WLN
WIL
WM
WTC
WAW
WON
WBC
WCL
mc
\m
YAW
White 6 Hodges, Inc
576 Lawrence St., Lowell, MA 01852.
19 N. Railroad St., Myerstovm, PA 17067.
3134 California St., NE., Minneapolis, MN 55426.
3540 Aero Ct., San Diego, CA 92123.
62 Alford St., Boston, MA 02129.
P. 0. Box 506, Charlotte, NC 28201.
P. 0. Box 66, Wilmington, DE 19 899.
4221 S. Western Blvd., Chicago, IL 60609.
Jackson and Swanson Sts., Philadelphia, PA 19148.
P. 0. Box 305, Paramus, NJ 07652.
108 Spring St., Everett, MA. 02149.
176 Sunnyside Ave., Woonsocket, RI 02895.
Halls Mills Rd., Freehold, NJ 07728.
Acme Station, Riegelwood, NC 28456.
P. 0. Box 1087, Colorado Springs, CO 80901.
P. 0. Box 8299, Paoli, PA 19101.
2731 Boston St., Baltimore, MD 21224.
Iftiittaker Corp. :
Mol Rez Div
Wica Chemicals, Inc
Wilson Pharmaceutical f, Chemical Corp.:
Wilson Laboratories Div
Witco Chemical Co., Inc
W. A. Wood Co
Woonsocket Color 5 Chemical Co
Wright Chemical Co
Wycon Chemical Co
Wyeth Laboratories, Inc., Wyeth Laboratories
Div. of American Home Products Corp.
J. S. Young Co., Young Aniline Works Div
257
APPENDIX B
U.S. IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS
U.S. general imports of benzenoid chemicals and products entered under
the Tariff Schedules of the United States (TSUS) , schedule 4, part 1, subparts
B and C are analyzed by the Tariff Commission annually and published in detail
in a separate report.^ General imports of benzenoid items entered in parts
IB and IC totaled 322.0 million pounds with a foreign invoice value of $246.7
million in 1972 compared with 219.5 million pounds with a foreign invoice
value of $185.0 million in 1971.
Benzenoid products that are "competitive" with similar domestic products,
because they accomplish results substantially equal to those accomplished by
the similar domestic product when used in substantially the same manner, are
subject to a special basis of valuation for customs purposes known as the
"American selling price." If "noncompetitive," the benzenoid products are
valued for customs purposes on the basis of the "United States value." The
essential difference between these two values is that "American selling price"
is based on the wholesale price in the United States of the "competitive"
domestic product, whereas "United States value" is based on the wholesale price
in the United States of the imported product less most of the expenses incurred
in bringing the product to the United States and selling it. When neither of
these two valuation bases applies, then the "export value," "foreign value," or
"constructed value" is used as the valuation basis under section 402 or 402a
Tariff Act of 1930, as amended. The competitive status of benzenoid imports in
1972 is shown in table 2.
Industrial organic chemicals that are entered under part IB consist chiefly
of benzenoid intermediates and small quantities of acyclic compounds which are
derived in whole or in part from benzenoid compounds. Also included are mixtures
and small quantities of finished products not specially provided for in part IC
(e.g., rubber-processing chemicals). In terms of value, 45.0 percent of all the
benzenoid imports under part IB in 1972 came from West Germany; 21.2 percent,
from Japan; 9.6 percent, from Switzerland; and 6.6 percent from Italy.
Finished organic chemical products entered under part IC include dyes,
pigments, medicinals, flavor and perfume materials, pesticides, plastics materials,
and certain other specified products. In terms of value, 37.2 percent of all
finished benzenoid imports under part IC in 1971 came from West Germany; 19.6
percent, from Switzerland: 15.7 percent, from the United Kingdom; and 11.5 percent
from Japan.
^ Imports of Benzenoid Chemicals and Products, 1972, TC Publication 601, 1973
[processed] .
SYNTHETIC ORGANIC CHEMICALS, 1972
TABLE 2.— Benzenoid chemicals and products; Summary of U,S, general imports entered under
Schedule ^j Parts IB and IC of the TSUS. and analysis by competitive status. 1972
Part and competitive status
Number
of
items
Quantity
Percent
of total
quantity
Foreign
invoice
value
Percent of
foreign
value
Unit
foreign
value
Schedule 4, Part IB
Total'
Competitive:
Duty based on ASP^
Noncompetitive:
Duty based on U.S. value
Duty based on export value
Competitive status not available
Schedule 4, Part IC
Total'
Competitive:
Duty based on ASP^
Noncompetitive:
Duty based on U.S. value
Duty based on export value
Competitive status not available
Summary (Schedule 4, Parts IB and IC)
Total'
Competitive :
Duty based on ASP^
Noncompetitive:
Duty based on U.S. value
Duty based on export value
Competitive status not available
1,258
131
1,50.S
183
1,000
pounds
19,583
28,423
135,838
33,011
17,135
52,594
45,558
1,000
dollars
10.5
15.3
21,272
11,556
155,271
58,256
71,775
20,078
114,859
93,047
31,634
46.2
12.9
Per
pound
1.09
.41
2.17
1.17
' Detail may not add to total due to rounding.
American selling price.
Source: Compiled by the U.S. Tariff Commission from records of the U.S. Bureau of Customs.
Note;--The totals shown in this table differ from those given in the official statistics of the U.S. Department
of Commerce chiefly because of differences in coverage and in the methods used in compiling the data. In general,
the statistical coverage in 1972 varies from a low of 74 percent for drugs and flavors and perfumes to almost
complete coverage for intermediates, dyes, and pigments.
APPEND IX C
TABLE 3.— Cyclic intermediates; Glossary of synonymous names
Common name
Standard (Chemical Abstracts) na
1,2, 4- Acid
Acid yellow 9
p-Aminobenzenesulfonic acid —
Amino G acid
Amino I acid
Amino R salt
Aniline oil
Anthraflavic acid
Anthrarufin
Benzal chloride
Benzan throne
Benzotrichoride
Bisphenol A
B.O.N
Bromobenz an throne
Broenner's acid
C acid
Chlorobenzanthrone
Chromotropic acid
Chrysazin
2-Cyanopyridine
3-Cyanopyridine
Cyanuric chloride
DADl
DBB
Decacyclene
Developer Z
o-Dianisidine
l,l'-Dianthrimide
Dibenzan throne
4 ,4 ' -Dihydroxydiphenylsulfone-
Dimethyl POPo'p
4,5-Dinitrochrysazin
Durene
Fast Red G base
Fast Scarlet R base
G salt
Gamma acid
Gold salt
H acid
Hellimellitene
J acid
J acid urea
Koch's acid
MEP
Mesitylene
Methane base
Michler's hydrol
Michler's ketone
4-Amino-3-hydroxy-l-naphthalenesulfonic acid.
6-Ainino-3,4 '-azodibenzenesulfonic acid.
Sulfanilic acid and salt.
7-Amino-l ,3-naphthalenedisulfonic acid.
6-Amino-l,3-naphthalenedisulfonic acid.
3-Amino-2,7-naphthalenedisulfonic acid.
Aniline.
2 , 6-Dihydroxyanthraquinone .
1 ,5-Dihydroxyanthraquinone .
a,a-Dichlorotoluene.
7H-Benz [de]anthracen-7-one .
ct,a,a,-Trichlorotoluene .
4,4'-lsopronylidenediphenol .
3-Hydroxy-2-naphthoic acid.
3-Bromo-7H-benz[de]anthracene-7-one .
6- Amino- 2 -naphthalene sulfonic acid.
3-Amino-l,5-naphthalenedisulfonic acid.
Chloro-7H-benz[de]anthracen-7-one .
4, 5 -Dihydroxy-2,7-naphthalenedi sulfonic acid.
1 , 8-Dihydroxyanthraquinone .
Picolinonitrile.
Nicotinonitrile.
2,4,6-Trichloro-s-triazine .
Dianisidine diisocyanate.
p-Dibutoxybenzene.
Diacenaphtho[l,2-j :1,2 '-Jl]fluoranthene.
3-Methyl-l-phenyl-2-pyrazolin-5-one .
3,3 '- Dime thoxybenzi dine.
1 ,1 '-Iminodianthraquinone .
Violan throne.
4 ,4'-Sulfonyldiphenol .
1 ,4- Bis [2- (4-methyl-5-phenyloxazoly 1) ] benzene .
1 ,8-Dihydroxy-4,5-dinitroanthraquinone .
1,2,4,5-Tetramethylbenzene.
2-Nitro-p-toluidine [NH2=1] .
5-Nitro-o-anisidine [NH2=1].
7-Hydroxy-l,3-naphthalenedisulfonic acid.
6-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodiu
salt.
9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid
and salt.
4-Amino-5-hydroxy-2, 7 -naphthalenedi sulfonic acid.
1 , 2 ,3-Trimethylbenzene .
7-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodiu
salt.
7,7'-Ureylenebis(4-hydroxy-2-naphthalenesulfonic
acid] .
8-Amino-l ,3,6-napthalenetrisulfonic acid.
5-Ethyl-2-picoline
1,3,5-Trimethylben2ene.
4,4' -Methylenebis [N ,N-dimethy lani 1 ine] .
4, 4 '-Bis [dime thy lamino]benzhydrol.
4,4'-Bis[dimethylamino]benzophenone.
SYNTHETIC ORGANIC CHEMICALS. 1972
TABLE 3,— Cyclic intermediates: Glossary of synonymous names--Continued
Common name
Standard (Chemical Abstracts) name
Naphthionic acid
o-Naphthionic acid
6-Naphthol
Naphthol AS
a-Naphthylamine
Neville5 IVinther's acid —
Pentaanthrimide
Phenylbiphenyl
N-Phenyldiethanol amine
Phenyl J acid
Phenyl peri acid
POPOP
Ps eudocumene
Pyrazolean throne
Pyrazoleanthrone yellow —
Pyrazolone T
Quini zarin
2-Quinizarinsulfonic acid-
Quinoline yellow base
R salt
Schaffer's acid
Silver salt
Solvent Yellow 1
Solvent Yellow 3
o-Sulfobenzaldehyde
Thiosalicylic acid
Tobias acid
TODI
o-Tolidine
a-Toluic acid
a-Tolunitrile
4-m-Tolylenediamine
Trimellitic anhydride
Trimethyl base
Trinitrophenol
Vinyl toluene
4-Amino-l-naphthalenesulfonic acid.
1- Amino- 2 -naphthalene sulfonic acid.
2-Naphthol, tech.
3-Hydroxy-2-naphthanilide.
1 -Naphthyl amine .
4-Hydroxy-l-naphthalene sulfonic acid.
1,4,5,8-Tetrakis Cl-anthraquinonylaminolanthraquinone.
Ternhenyl .
2,2'- [ CPhenyl)imino]diethanol .
7 -Anilino-4-hydroxy-2 -naphthalene sulfonic acid.
8-Anilino-l-naphthalenesulfonic acid.
1 ,4-Bis [2- (S-phenyloxazolyl) ]benzene .
1 ,2 ,4-Trimethylbenzene .
Anthra[l,? cd]pyrazol-6(2H)-one .
[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione.
S-Oxo-l- (p-sulfophenyl)-2-pyrazoline-3-carboxylic
acid.
1 ,4-Dihydro.\yanthraquinone .
9 ,10-Dihydro-l ,4-dihydrox>'-9,in-dioxo-2-anthracene-
sulfonic acid.
Quinophth alone .
3-Hydroxy-2 ,7-naphthalenedisulfonic acid, disodium
salt.
6-Hydroxy-2-naphthalenesulfonic acid.
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonic acid
and salt.
p-Phenylazoaniline and hydrochloride.
4- (o-Tolylazo)-o-toluidine .
o-Formylbenzenesulfonic acid.
o-Mercaptobenzoic acid.
2-Amino-l-naphthalenesulfonic acid.
Bitolylene diisocyanate.
3,3' -Dinethylbenzidine .
Phenylacetic acid.
Phenyl ace tonit rile.
Toluene-2 ,4-di amine .
1 ,2,4-Benzenetricarboxylic acid, 1,2 -anhydride.
l,3,3-Triniethyl-2-methyleneindoline.
Picric acid.
ar-Methvlstvrene.