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Full text of "Synthetic organic chemicals"

BOSTON 

PUBLIC 

LIBRARY 




'.J^: 



UNITED STATES TARIFF COMMISSION 



7^ 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1972 

TC Publication 681 




RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON 
SYNTHETIC ORGANIC CHEMICALS 

Synthetic Organic Chemicals, United States Production and Sales, 1967 (TC Publication 295, 

1969), $2.00 
♦Synthetic Organic Chemicals, United States Production and Sales, 1968 (TC Publication 327, 

1970), $2.00 
♦Synthetic Organic Chemicals, United States Production and Sales, 1969 (TC Publication 412, 

1971), $2.00 
♦Synthetic Organic Chemicals, United States Production and Sales, 1970 (TC Publication 479, 

1972), $2.00 
Synthetic Organic Chemicals, United States Production and Sales, 1971 (TC Publication 614, 

1973), $2.40 



NOTE.— The reports preceded by an asterisk (*) are out of print. The other reports listed above may 
purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20'! 
All U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in tb 
official depository libraries throughout the United States. 



4ol 



UNITED STATES TARIFF COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1972 



UNDER THE PROVISIONS OF 
SECTION 332 OF THE TARIFF 
ACT OF 1930, AS AMENDED 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1974 



TC PubUcation 681 



UNITED STATES TARIFF COMMISSION 

Catherine Bedell, Chairman 
Joseph O. Parker, Vice Chairman 
Will E. Leonard, Jr. 
George M. Moore 
J. Banks Young 
Italo H. Ablondi 

Kenneth R. Mason, Secretary 



Address all communications 

UNITED STATES TARIFF COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents. U.S. Government Printing Office, Washington. D.C. 20402 
Price $2.70 Stock Number 4900-00038 



CONTENTS 

Page 

Introduction 1 

Summary 3 

General 4 

Tar 7 

Tar crudes 7 

Crude products from petroleum and natural gas 

for chemical conversion 13 

Cyclic intermediates 19 

Dyes 55 

Organic pigments 91 

Medicinal chemicals 101 

Flavor and perfume materials 121 

Plastics and resin materials 133 

Rubber-processing chemicals 141 

Elastomers 149 

Plasticizers 153 

Surface-active agents 161 

Pesticides and related products 189 

Miscellaneous chemicals 199 

APPENDIXES 

A. Director of manufacturers 243 

B. U.S. imports of benzenoid chemicals 

and products 257 

C. Cyclic intermediates: Glossary of 

synonymous names 259 



INTRODUCTION 

This is the fifty-sixth annual report of the U.S. Tariff Commission on domestic production and sales of 
synthetic organic chemicals and the raw materials from which they are made. It is authorized under the provisions 
of section 332 of the Tariff .i^ct of 1930, as amended. The report consists of fourteen sections, each covering a 
specified group (based principally on use) of organic chemicals as follows: tar and tar crudes; crude products from 
petroleum and natural gas; intermediates; dyes; pigments; medicinal chemicals; flavor and perfume materials; plastics 
and resin materials; rubber-processing chemicals; elastomers; plasticizers; surface-active agents; pesticides and 
related products; and miscellaneous organic chemicals. Data have been supplied by approximately 800 producers. 

The first table in each section gives statistics on products and groups of products in as great detail as is 
possible without revealing the operations of individual producers. Statistics for an individual chemical or group 
of chemicals are given only when there are three or more producers, no one or two of which may be predominant. More- 
over, even when there are three or more producers, statistics are not given if there is any possibility that their 
publication would violate tlie statutory provisions relating to unlawful disclosure of information accepted in con- 
fidence by the Commission. ' 

"bata are reported by producers for only those items where the volume of production or sales exceeds 1,000 pounds 
or the value of sales exceeds $1,000. They are usually given in terms of undiluted materials; however, products of 
95 percent -or more purity are considered to be 100 percent pure. Commercial concentrations are applied to dyes, 
certain plastics and resins, and a few solvents; such concentrations are specifically noted. 

The statistics given in this report include data from all known domestic producers of the items covered and in- 
clude the total output of each company's plants, i.e., the quantities produced for consumption within the producing 
plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, there- 
fore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to 
changes in inventory. 

The second table in each section lists all items for which data on production or sales have been reported, by 
primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters 
which is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes 
of the manufacturers reporting in that section. Table I of the .A.ppendix is a directory, alphabetized by the names of 
the manufacturers reporting in all sections and includes their office addresses. 

Information on the synonymous names of the organic chemicals included in this report may be found in the SOCMA 
Handbook: Commevoial Organic Chemical Names, published by the Chemical Abstracts Service of the .(^erican Chemical 
Society, or the Colour Index (2d edition), published by the Society of Dyers and Colourists. 

Table 2 of the Appendix summarizes and gives the competitive status of U.S. general imports in 1972 of benzenoid 
intermediates and finished benzenoid products, entered under schedule 4, parts IB and IC, of the Tariff Schedules of 
the United States. 

As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise 
specified) are definf^d as follows: 

PEODUCTION is the total quantity pf a commodity made available 
by original manufacturers only. It is the sum — expressed in terms 
of 100% active ingredient unless othenrtse specified in the reporting 
instructions — of the quantities: 

Produced, separated, and consumed in the same plant or 
establishment. A commodity is considered separated 
when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured. 
This includes byproducts and ooproduats that are not 
classifiable as waste materials; 
Produced and transferred to other plants or establish- 
ments of the same firm; 
Produced and sold to other firms, including production 
for another under a toll agreement (i.e., an agreement, 
under which one firm furnishes the raw materials- and 
pays the processing costs and the other firm prepares 
the finished product and returns it to the first firm) 
Produced and held in stock. 



Title 18, U.S.C. 1905 and Title 44, U.S.C. 3508 



INTRODUCTION 



PRODUCTION EXCLUDES : 

Purification of a commodity^ unless inclusion of 
suck processing is specifically requested in 
the reporting instructions for individual 
sections'. 

Intermediate products which are formed in the 
manufacturing process, but are not isolated 
from the reaction system — that is, not 
weighed, analyzed, or otherwise measured; 

Materials that are used in the process but 
which are recovered for re-use or sale; 

Haste products having no economic significance. 

SALES are actual quantities of commodities sold by ORIGINAL 
MANUFACTURERS ONLY. Sales include the quantity and value of: 
Shipments of a commodity for domestic use and 
for export, or segregation in a warehouse 
when title has passed to the purchaser in a 
bona fide sale; 
Shipments of a commodity produced by others under 

toll agreements; 
Shipments to subsidiary or affiliated companies. 

SALES EXCLUDE: 



All intra-company transfers within a corporate entity; 
All sales of purchased commodities; 
All shipments of a commodity produced for others 
under toll agreements. 

VALUE OF SALES is the net selling value f.o.b. plant or 
warehouse, or delivered value, whichever represents the normal 
industry practice. 



SUMMARY 3 

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products from petroleum and 
natural gas in 1972 was 266,419 million pounds--an increase of 12.0 percent over the output in 1971 (see table 1). 
Sales of these materials in 1972, which totaled 150,818 million pounds, valued at $16,028 million, were 12.8 percent 
larger than in 1971 in terms of quantity and 13.5 percent larger in terras of value. These figures include data on pro- 
duction and sales of chemicals measured at several successive steps in the manufacturing process, and therefore they 
necessarily reflect some duplication. 

In 1972, production of all synthetic organic chemicals, including cyclic intermediates and finished chemical prod- 
ucts, totaled 164,218 million pounds, or 15.2 percent more than the output in 1971. Production increased in 1972 com- 
pared to 1971 for all subgroups of products. Among the groups with large volumes of production, plastics and resin 
materials (25,921 million pounds) lead with an increase of 23.0 percent and cyclic intermediates (34,967 million pounds) 
followed with an increase of 16.7 percent. Other groups in the large-volume production category increased as follows: 
plasticiiers (1,708 million pounds), 14.3 percent; miscellaneous chemicals (90,476 million pounds), 13.9 percent; 
elastomers (4,914 million pounds), 6.4 percent; surface-active agents (4,039 million pounds), 5.5 percent. In the groups 
with smaller quantities of production, flavor and perfume materials (110 million pounds) increased 14.6 percent; organic 
pigments (66 million pounds) rose 13.0 percent; rubber-processing chemicals (361 million pounds) was up 11.6 percent; 
dyes (263 million pounds) increased 8.0 percent. Smaller increases were shown by medicinal chemicals (234 million 
pounds), 5.0 percent and pesticides and related products (1,158 million pounds), 1.9 percent. 



TABLE 1, 



Synthetic organic chemicals and their raw materials; 
U.S. production and sales, 1971 and 1972 



Increase 

or 
decrease 
(-), 1972 

over 

1971' 



Increase 

or 
decrease 
(-), 1972 

over 

1971' 



Increase 

or 

decrease 

(-), 1972 

over 

1971' 



Grand total 

Tar 

Tar crudes 

Crude products from petroleum 
and natural gas 

Synthetic organic chemicals, 
total ^ 

Cyclic intermediates 

Dyes 

Organic pigments 

Medicinal chemicals 

Flavor and perfume materials- 
Plastics and resin materials- 
Rubber-processing chemicals-- 
Elastomers (synthetic 

rubbers) 

Plasticizers 

Surface-active agents 

Pesticides and related 

products 

Miscellaneous chemicals 



Million 
pounds 



Percent 
12.0 



Million \Million\ \ Million 

pounds \pounds \ Pereent dollars 



133,666 I 150,8181 



Million 
dollars 



6,794 
7,621 



142,503 



7,472 
7,937! 



10.0 
4.1 



3,341 
5,436 



3,409| 
5,304 i 



2.0 
-2.4 



164,218| 15.2 



45,752 1 47,900 



79,157 : 94,205; 



123 
1,078 

12,883 



40 
126 



1,177 



Percent 
13.5 



10.2 
2.4 



14,686 14.0 



29 


953 


34 


967 




244 




265 




58 




66 




223 




234 




96 




110 


21 


071 


25 


921 




323 




361 


4 


616 


4 


914 


1 


494 


1 


708 


3 


828 


4 


039 


1 


136 


1 


158 


79 


460 


90 


476 



12,971 


16,196 


24.9 


230 


255 


10.9 


47 


53 


13.1 


152 


163 


7.2 


85 


104 


22.7 


18,473 


22,946 


24.2 


246 


280 


13.9 


4,031 


4,136 


2.6 


1,404 


1,637 


16.6 


2,186 


2,258 


3.3 


946 


1,022 


8.0 


38,367 


45.155 


17.7 



1,252 

423 

130 

487 

84 

3,507 
159 

1,034 
258 
422 

979 
4,148 



1,434 

480 

149 

490 

88 

4,258 
178 

1,095 
291 

451 

1,092 
4,680 



5.3 

21.4 



11.5 
12.8 



1 Percentages calculated from figures rounded to thousands. 

2 Because of rounding, figures may not add to the totals shown. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
GENERAL 

In this report, synthetic organic chemicals are classified on the basis of their princip,al use as follows; cyclic 
intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, 
rubber-processing materials, elastomers, plasticizers , surface-active agents, pesticides and related products and miscel- 
laneous chemicals (acyclic intermediates and acyclic and cyclic finished products). Most of these groups are further 
subdivided either by use or by chemical composition. As intermediate chemicals are used in the manufacture of finished 
products, aggregate figures that cover both intermediates and finished products necessarily include considerable duplica- 
tion. 

Total production of synthetic organic chemicals (intermediates and finished products combined) in 1972 was 164,218 
million pounds, or 15.2 percent more than the output of 142,503 million pounds reported for 1971 and 56.8 percent more 
than the output of 104,711 million pounds reported for 1967 (see table 2). Sales of synthetic organic chemicals in 1972 
amounted to 94,205 million pounds, valued at Sl4,686 million, compared with 97,137 million pounds, valued at $12,883 
million in 1971 and 55,177 million pounds, valued at 510,438 million in 1967. Production of all cyclic products (inter- 
mediates and finished products combined) in 1972 totaled 53,637 million pounds or 15.9 percent more than the 46,273 mil- 
lion pounds reported for 1971 and 60.2 percent more than the 33,479 million pounds reported for 1967. Production of all 
acyclic products in 1971 totaled 110,580 million pounds, or 14.9 percent more than the 96,230 million pounds reported 
for 1971 and 55 . 2 percent more than the 71,232 nillion pounds reported for 1967. 

TABLE 2. --Synthetic organic chemicals; Summary of U.S. production and sales 
OF intermediates and finished products, 1967, 1971, and 1972 

[Production and sales in tliousands of pounds; sales value in thousands of dollars] 




Organic chemicals, cyclic and acyclic, 
grand total : 

Production 

Sales 

Sales value 

Cyclic, total: 

Production 

Sales 

Sales value 

Acyclic, total : 

Produc tion 

Sales 

Sales value 

1. Cijolic Intermediates 

Production 

Sales 

Sales value 

2. Dyes 

Production 

Sales 

Sales value 

2. Organic Pigments 

Production 

Sales 

Sales value 

4. Medicinal Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



,711,357 
,176,823 
,438,453 



,479,469 
,328,628 
,610,29' 



,2 31,888 
,848,195 
,828,160 



,793,132 
,461,180 
,000,359 



206,240 
198,592 
332,049 



53,322 
42,867 
108,354 



110,129 

70,120 

348,873 

69,941 
56,804 
36,402 



142,502,514 
79,136,628 
12,882,816 



46,272,717 
25,859,561 
5,793,591 



96,229,797 

55,277,067 



29,952,917 
12,970,553 
1,252,300 



243,729 
229,544 
422,627 



58,326 

47,052 

130,013 



132,582 
84,913 



90,636 
67,309 
54.856 



164,217,690 
94,205,254 
14,685,582 



53,637,371 

31,082,064 

6,516,824 



110,580,319 

63,123,190 

8,168,758 



34,967,181 
16,195,641 
1,433,855 



263,304 
254,536 
479,688 



65,897 
53,215 
149,343 



132 


586 


81 


082 


433 


259 


101 


747 


82 


128 


56 


878 



Increase, or decrease (- 



1972 over 
1967 


1972 over 
1971 


Percent 


Percent 


56.8 

70.7 
40.7 


15.2 
19.0 

14.0 


60.2 
60.8 
41.4 


15.9 

20.2 
12.5 


55.2 
76.1 
40.2 


14.9 
18.5 
15.2 


68.2 

71.2 
43.3 


16.7 
24.9 
14.5 


27.7 
28.2 
44.5 


8.0 
10.9 
13.5 


23.6 
24.1 
37.8 


13.0 
13.1 
14.9 


20.4 
15.6 
24.2 


(0 

-4.5 
.4 


45.5 
44.6 


12.3 
22.0 



See footnotes at end of table. 



GENERAL 
TABLE 2. --Synthetic organic chemicals: Summary of U.S. production and sales 

OF intermediates and finished products, 1967. 1971, AND 1972--C0NTINUED 



[Production and sales in thousands of pounds; sales value in thousands of dollars] 



5. Flavor and perfume Materials 



Cyclic: 

Product! on- - 

Sales 

Sales value- 
Acyclic: 

Production- - 

Sales 

Sales value- 



Cyclic : 

Production- - 

Sales 

Sales value- 
Acyclic: 

Product! on- - 

Sales 

Sales value- 



Cyclic: 

Product! on- - 

Sales 

Sales value- 
Acyclic : 

Production-- 

Sales 

Sales value- 



Cyclic: 

Production- 



Sale 



Sales value- 
Acyclic: 

Production- - 

Sales 

Sales value- 



9. Plastiai-zers 



Cyclic: 

Production-- 

Sales 

Sales value- 

Acyc lie: 

Product ion- - 

Sales 

Sales value- 



Plastics and Resin Materials 



Rubber-Proaessing Cherriaal 



8. Elastomers (Synthetic Rubbers) 



57,978 
47,285 
52,866 



5,033,497 
4,224,121 
1,036,940 

8,759,452 
7,753,242 
1,635,690 



220,139 
169,970 
116,318 

43,994 
30,878 
15,477 



2,297,637 

1 ,940,099 

439,580 

1,524 ,908 

1,321,945 

434,657 



929,871 
865,084 
167,827 

332,908 
296,767 
93,142 



49,682 
42,180 
52,884 

46,744 
42,585 
31,084 



7,266,038 
6,262,651 
1,400,553 

13,804,685 
12,210,359 
2,105,989 



276,146 
211,065 
142,541 



2,614,054 

2,239,804 

484,130 

2,002,046 

1,790,837 

550,315 



1,130,440 

1,074,541 

157,925 

363,598 
329,555 
99,840 



51 ,868 
48,212 
54,168 



58,605 
55,780 



8,946,997 
7,807,933 
1,715,579 

16,973,665 
15,138,142 
2,542,861 



309,930 
240,044 
157,944 

51,091 
40,199 



2,705,599 

2,177,303 

470,549 

2,208,360 

1,958,960 

624,257 



1,301 ,955 

1,273,191 

180,051 

406,358 
364,306 
110,513 



Increase, or decrease (-) 



1972 over 
1967 



2.0 
2.5 



77.8 
84.8 
65.5 

93.8 
95.3 
55.5 



16.1 
30.2 
27.3 



17.8 
12.2 
7.1 

44.8 
48.2 
43.6 



40.0 
47.2 



See footnote at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Synthetic organic chemicals: Summary of U,S, production and sales 

OF INTERMEDIATES AND FINISHED PRODUCTS, 1967, 197], AND 1972--CONTINUED 



[Production and sales in thousands of pounds; sales value in thousands of dollars] 



10. Surface-Aative Agents 

Cyclic: ' 

Production 

Sales 

Sales value-' 

Acyclic: 

Production 

Sales 

Sales value 

II. Pesticides and Related Products 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



12. Miscellaneous Chemicals 



Cyclic: 

Production-- 

Sales 

Sales value- 
Acyclic: 

Production-- 

Sales 

Sales value- 



1,418 


444 


852 


238 


95 


810 


2,060 


851 


897 


78h 


220 


877 



823,158 
681,532 
627,742 

226,505 
215,831 
159,301 



1,535,922 
775,540 
283,575 

58,159,771 

25,225,631 

3,192,119 



1,542,881 
995,580 
120,795 



1,190,110 
301,685 



827 


590 


669 


143 


819 


028 


308 


127 


277 


194 


160 


055 



1,032,535 
379,093 

77,281,270 

37,334,192 

3,768,587 



1,641,552 

1,053,240 

129,792 

2,397,235 

1,204,306 

320,976 



839,360 
719,707 
889,613 

318,338 
301,858 
202,095 



2,411,142 

1,177,960 

422,983 

88,064,920 
43,977,511 
4,257,239 



Increase, or decrease (- } 



33.4 



6.4 
5.8 

7.5 



1.4 
7.6 
8.6 

3.3 

8.9 
26.3 



14.1 
11.6 



Standard reference base period for Federal Government general-purpose inde.x numbers. 
Less than 0.05 percent. 
Includes Ligninsulfonates 

The following tabulation shows, by chemical groups, the number of companies that reported production in 1971 of 
one or more of the chemical included in the groups listed in table 2; 



Chemical 

Cyclic intermediates 

Dyes 

Organic pigments 

Medicinal chemicals 

Flavor and perfume materials- 
Plastics and resin materials- 



Ntmber 

of _ 

compcDiiee 



Chem-oal group 

Rubber-processing chemicals 

Elastomers (synthetic rubbers)- 
Plasticizers 

Surface- active agents 

Pesticides and related products- 
Miscellaneous chemicals 



of _ 

ciompani.es 



TAR AND TAR CRUDES 



Tar 



Coal tar is produced chiefly by the steel industry as a byproduct 
of the manufacture of coke; water-gas tar and oil-gas tar are produced 
by the fuel-gas industry. Production of coal tar, therefore, depends 
on the demand for steel; production of water-gas tar and oil-gas tar 
reflects the consumption of manufactured gas for industrial and house- 
hold use. Water-gas and oil -gas tars have properties intermediate be- 
tween those of petroleum asphalts and coal tars. Petroleum asphalts 
are not usually considered to be raw materials for chemicals. 

The quantity of tar produced in the United States in 1972 was al- 
most entirely coal tar which amounted to 747 million gallons (see table 1^). 
Production in 1972 was 10 percent more than the 679 million gallons of 
coal tar produced in 1971. Sales of coal tar in 1972 amounted to 341 
million gallons, valued at $40 million, compared with 334 million gallons, 
valued at $36 million, in 1971. U.S. production of water-gas and oil-gas 
tars was not reported to the Commission for 1971 or 1972; production of 
these tars in 1968 amounted to 21 million gallons, according to trade 
publications . 

Consumption of tar in 1972 amounted to 716 million gallons, of which 
82.8 percent was consumed in distillation. Tar used by the producers as 
fuel amounted to 119 million gallons. A lesser amount, 4.3 million gallons, 
was consumed by coke-oven operators in miscellaneous uses fsee table lA) . 

Tar Crudes 

Tar crudes are obtained from coke-oven gas and by distilling coal 
tar, water-gas tar, and oil-gas tar. The most important tar crudes are 
benzene, toluene, xylene, naphthalene, creosote oil, and pitch of tar. 
Some of these products are identical with those obtained from petroleum. 
Data for materials obtained from petroleum are included, for the most 
part, with the statistics for like materials obtained from coke-oven 
gas and tars, and are shown in tables 1 and IB. 



Domestic production of industrial and specification grades of 
benzene reported by coke-oven operators and petroleum refinery operators^ 
in 1972 amounted to 1,252 million gallons--16.4 percent more than the 

^ See also table 2 of this section which lists the products in table 1 
and identifies the manufacturers by code. These codes are given in table 

^ Statistics on production and sales of benzene, toluene, and xylene by 
tar distillers cannot be shown because publication would reveal the oper- 
ations of individual companies. 



SYNTHETIC ORGANIC CHEMICALS, 1972 



1,076 million gallons reported for 1971. These statistics include data 
for benzene produced from light oil and petroleum. Sales of benzene by- 
coke-oven operators and petroleum refiners in 1972 amounted to 679 mil- 
lion gallons, valued at $138 million, compared with 593 million gallons, 
valued at $119 million, in 1971. In 1972 the output of toluene^ (in- 
cluding material produced for use in blending in aviation fuel) amounted 
to 916 million gallons--4.5 percent more than the 876 million gallons 
reported for 1971. Sales of toluene in 1972 were 546 million gallons, 
valued at $92 million, compared with 484 million gallons, valued at 
$80 million, in 1971. The output of xylene^ in 1972 (including that 
produced for blending in motor fuels) was 739 million gallons, com- 
pared with 612 million gallons in 1971. Over 99 percent of the 739 
million gallons of xylene produced in 1972 was obtained from petroleum 
sources . 

Production of crude naphthalene in 1972 (including 231 million 
pounds of petroleum-derived naphthalene) amounted to 641 million pounds, 
compared with 619 million pounds in 1971. In 1972 the output of creosote 
oil for wood preservation was 139 million gallons (100 percent creosote 
basis), compared with 142 million gallons in 1971. Production of road 
tar in 1972 was 30 million gallons, compared with 40 million gallons in 
1971. 

Some of the products obtained from tars and included in the 
statistics in table 1 are obtained from other products for which data 
are also included in the table. The statistics, therefore, involve 
considerable duplication, and for this reason no group totals or grand 
totals are given. After duplication has been eliminated insofar as 
possible, the estimated net value of the output (from all sources) of 
these products and of tar burned as fuel was $698 million in 1972, 
compared with $617 million in 1971. The total value of sales of those 
products obtained from coke-oven gas and tars shown in table 1 (ex- 
clusive of coal tar itself), amounted to $126 million in 197.2, compared 
with $123 million in 1971. 

Data for 1972 tar crudes was supplied by 12 companies and company 
divisions. 



See footnote 2 on page 7, 



TAR 



TAR CRUDES 



TABLE 1,--Tar and tar crudes: U,S, production and sales> 1972 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders (...) 
are used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 2 lists separately all products for which data on production or sales were reported and identifies the manu- 
facturers reporting to the U.S. Tariff Commission] 



Production 



Quantity 



Tar: Coke-oven operators 

Crude light oil:^ Coke-oven operators 

Intermediate light oil: Coke-oven operators 
Light-oil distillates: 

Benzene, specification and industrial 

grades, total^ '* 

Coke-oven operators 

Petroleum refiners 

Toluene, all grades, total ^ ** 

Coke-oven operators 

Petroleum refiners 

Xylene, all grades' '* 

Coke-oven ope ra tors 

Petroleum refiners 

Solvent naphtha: Coke-oven operators' 

Naphthalene, crude (tar distillers and coke- 
oven operators), total^ 

Solidifying at-- 

Less than 74° C 

74° C. to less than 79° C 

Crude tar-acid oils:' Coke-oven operators-- 

Creosote oil (Dead Oil) (tar distillers and 
coke-oven operators) (100% creosote 

basis J , total ^ — 

Distillate as such (100° creosote basis)-- 
Creosote content of coal tar solution 
(100% creosote basis)' 

All other distillates, total 

Coke-oven operators, total 

From light oil 

Other" 

Tar distillers^ 

Tar, road 

Tar, refined, for other uses 

Pitch of tar (tar distillers and coke-oven 

operators) , total 

Soft (water softening point less than 

110° F.) 

Medium (water softening point 110° F. to 

160° F.) 

Hard (water softening point over 160° F.)^ 



1,000 gal- 
1,000 gal- 
1,000 gal- 



1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 



1,000 Ib- 
1,000 Ib- 



1,000 gal-- 



1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1 ,000 gal-- 

1 ,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1 ,000 tons 

1,000 tons 

1 ,000 tons 

1 ,000 tons 



747,186 

214,201 

3,704 



1,252,442 

79,849 

1,172,593 

915,872 

14,571 

901,301 

739,332 

3,351 

735,981 

2,815 



17,374 
392,701 



9,731 



25,213 



6,905 
3,898 
3,007 



29,807 
14,395 



1,568 



340,875 
86,915 

754 



679,235 

80,225 

599,010 

545,880 

13,954 

531,926 

560,432 

3,208 

557,224 

2,596 



1,000 
dollars 



39,634 
9,584 



138,478 

16,338 

122,140 

91,529 

2,501 

89,028 

94,128 

578 

93,550 

462 



9,627 
215,364 



144 
10,281 



22,956 



16,187 

' 6,769 

3,675 



2,520 
2,837 
14,507 

29,873 
13,082 

1,009 



1,060 
849 
211 

2,615 

5,493 
3,516 



(') 



.20 
.34 
.07 



177 
633 



10,035 
30,783 



56.69 
48.63 



Unit value per gallon, pound, or ton, as specified. 

^ Includes only data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines. Data on U.S. pro- 
duction of water-gas tar and oil-gas tar are not collected by the Tariff Commission, but according to trade publica- 
tions, production of these tars amounted to 21 million gallons in 1968. 

' Data reported by tar distillers are not included because publication would disclose the operations of individual 
companies. Production of benzene, toluene, and xylene by tar distillers decreased in 1972, compared with 1971. The 
annual production statistics for petroleum refiners on benzene, toluene, and xylene are not comparable with the com- 
bined monthly production figures, because of fiscal year revisions. 



Note. --Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Fossil Fuels, 
U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum refineries 
are compiled by the U.S. Tariff Commission. 



SYNTHETIC ORGANIC CHEMICALS, 1972 



Footnotes for table 1 — Continued 

'* Includes data for material produced for use in blending motor fuels. 

^ Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphthalene 
from one grade to another, the figures may include some duplication. 

' Statistics include data only for creosote oil sold for, or used in, wood preserving. 

' In 1972, production of coal-tar solution containing creosote (100% solution basis) amounted to 38,144 thousand gal- 
ons ; sales were 36,232 thousand gallons, valued at 6,769 thousand dollars, with a unit value of $0.19 per gallon. 

° Includes data for crude sodium phenolate. 

^ Includes data for crude light oil, benzene, toluene, xylene, solvent naphtha, ethylbenzene , rubber-reclaiming oils, 
pyridine crude bases, crude tar-acid oils, crude cresylic acid, neutral oils, methylnaphthalene , crude tar for other 
uses, and unspecified tar distillates. 
'° Includes hard pitch and pitch emulsion, along with a small amount of medium pitch produced by coke-oven operators. 



TABLE 1A.--TAR; U.S. production and consumption^ 1971 and 1972 

(In thousands of gallons) 



Product 


1971 


19 72 


PRODUCTION 


679,377 


747,186 




CONSUMPTION 


685,684 


715,823 






572,160 


592,507 






230,959 
341,201 

111,877 

1,647 


273,388 
319,119 








4,286 





Reported to the Division of Fossil Fuels, U.S. Bureau of Mine^. 

Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort 
plants and distilled by companies operating tar-distillation plants. Statistics also include tar consumed other than 
by distillation by tar distillers. 



TAR AND TAR CRUDES 



TABLE IB. --Tar and tar crudes; Summary of U.S. production of specified products, 

1967, 1971, and 1972 



Unit 

of 

quantit 



Increase, or 
decrease (-) 



1972 over 
1967 



1972 over 
1971 



Tar' 

Benzene : ' 

Coke-oven operators - 

Petroleum refiners-- 

Total 



1,000 gal- 



1,000 gal- 
1,000 gal- 



90,642 
878,704 



679,377 



72,147 
1,003,760 



Toluene : ^ 

Coke-oven operators- 
Petroleum refiners-- 
Total 



1,000 eal-- 



1,000 
1,000 gal- 



969,346 



19,357 
624,454 



79,849 
1,172,592 



Percent 
-4.2 



-11.9 
33.4 



Xylene:' 

Coke-oven operators- 
Petroleum refiners-- 
Total 



1,000 gal- 



1,000 gal- 
1,000 gal- 



643,811 



5,488 
449,349 



862,921 



1,252,442 



14,571 
901,301 



2,906 
609,419 



3,351 
735,981 



-38.9 
63.8 



Naphthalene : 

Crude ^ 

Petroleum naphthalene. 
Total 



ill grades- 



1,000 gal-- 



1,000 Ib- 
1,000 Ib- 



454,837 



520,991 
376,679 



612,325 



360,607 
258,312 



410,075 
230,643 



-21.3 
-38.8 



Creosote oil (Dead oil): 

Distillate as such (100% creosote 

basis) 

Creosote content of coal tar solution 

(100% creosote basis) 

Total 



1,000 gal- 
1,000 gal- 



108,832 
17,402 



115,669 
26,208 



114,095 
25,213 



1,000 gal-- 



126,234 



141,877 



139,308 



10.4 



Peyaent 
10.0 



15.3 
20.8 



-1.8 



Standard reference base period for Federal Government general -purpose index numbers. 
^ Includes only data for coal tar reported to the Division of Fossil Fuels, U.S. Bureau of Mines. 

Data reported by tar distillers are not included because publication would disclose the operations of individual 
companies. 

* Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly 
figures which included some o-xylene. 

5 Naphthalene solidifying at less than 79° C. Figures include production by tar distillers and coke-oven operators 
and represent combined data for the commercial grades of naphthalene. Because of conversion between grades, the figures 
may include some duplication. Statistics on naphthalene refined from domestic crudes are reported in the section on 
cyclic intermediates. 

Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserving. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Tar crudes for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 

[Tar crudes for which separate statistics are given in table 1 are marked with an asterisk (*) ; products not so 
marked do not appear in table 1 because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 3. Table 3 identifies all U.S. producers of 
tar crudes (except producers that report to the Division of Fossil Fuels, U.S. Bureau of Mines)] 



Manufacturers' identification codes 
(according to list in table 3) 



•Crude light oil 

Light-oil distillates; 

Benzene, specification grades' 

Toluene, specification grades' 

Xylene, all grades 

Solvent naphtha 

All other light-oil distillates' 

Pyridine crude bases 

'Naphthalene, crude, solidifying at-- 

*Less than 74° C' 

*74° C. to less than 79° C:' 

74° C. to less than 76° C 

76° C. to less than 79° C 

Methylnaphthalene 

Crude tar-acid oils:' 

Tar-acid content S% to less than 24"^ 

Tar-acid content 24*o to 50-6 

Cres\'lic acid, crude 

•Creosote oil (Dead oil); 

'Distillate as such' 

•Creosote in coal tar solution' 

•All other distillate products' 

•Tar, road 

Tar for other uses: 

Crude 

•Refined' 

•Pitch of tar: 

•Soft (water softening point less than 110° F.)'-- 
•Medium (water softening point 110° F. to 160° F.) 

•Hard (water softening point above 160° F.)' 

Pitch emulsion 



CBT. 

ACY, KPP. 

ACY, KPP. 

ACY. 

ACY, NEV, PAI. 

KPT, PAI. 

KPT. 

COP. 



KPT. 




ASC, 


KPT. 


KPT. 




KPT. 




ASC, 


WTC. 


KPT. 





ASC, CBT, COP, HUS, KPT, RIL, WTC. 
ASC, KPT, RIL, WTC. 
ASC, KPT, PAI. 
ASC, KPT, RIL. 

KPT, RIL. 
ASC, KPT, RIL. 

ASC, KPT, WTC. 

ASC, CBT, COP, KPT, RIL, WTC. 

ASC, HUS, KPT, RIL. 

JEN. 



Does not include manufacturers' identification codes for producers who report to the Division of Fossil Fuels, 
U.S. Bureau of Mines. Those producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, November 27, 
1973, entitled "Coke Producers in the U.S. in 1972". 



TABLE 3. --Tar and tar crudes: Directory of manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of tar and tar crudes to the U.S. Tariff Commission for 
1972 are listed below in the order of their identification codes as used in table 21 



Code 


Name of 


company 


Code 


Name of company 


ACY 


American Cyan amid Co. 




KPT 


Koppers Co., Inc., Organic Materials Div. 


ASC 


Allied Chemical Corp. , 


Semet-Solvay Div. 






CBT 


Samuel Cabot, Inc. 




NEV 


Neville Diemical Co. 


COP 


Coopers Creek Chemical 


Corp. 






HUS 


Husky Industries, Inc. 




PAI 


Pennsylvania Industrial Chemical Corp. 


JEN 


Jennison-Wright Corp. 




RIL 
WTC 


Reilly Tar 5 Chemical Corp. 
Witco Cnemical Co., Inc. 


KPP 


Sinclair-Koppers Co. 









Note. --Complete names and addresses of the above reporting companies are listed in Table 1, o*^ the Appendix. 



13 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR 
CHEMICAL CONVERSION 



Crude products that are derived from petroleum and natural gas ^ 
are related to the intermediates and finished products made from such 
crudes in much the same way that crude products derived from the dis- 
tillation of coal tar are related to their intermediates and finished 
products. Many of the crude products derived from petroleum are 
identical with those derived from coal tar (e.g., benzene, toluene, 
and xylene). Considerable duplication exists in the statistics on the 
production and sales of petroleum crudes because some of these crude 
chemicals are converted to other crude products derived from petroleum 
and because data on some production and sales are reported at succes- 
sive stages in the conversion process. The statistics are sufficiently 
accurate^ however, to indicate trends in the industry. Many of the 
crude products for which data are included in the statistics may be 
used either as fuel or as basic materials from which to derive other 
chemicals. In this report every effort has been made to exclude data on 
materials that are used as fuel; however, data are included on toluene 
and xylene which are used in blending aviation and motor fuel. 

The output of crude products derived from petroleum and natural gas 
as a group amounted to 86,792 million pounds in 1972, or 7.0 percent 
more than the 81,043 million pounds reported for 1971 (table 1).^ The 
larger output in 1972 is accounted for chiefly by increased production of 
ethylene, propylene and benzene. Sales of crude chemicals from 
petroleum in 1972 amounted to 47,900 million pounds, valued at $1,177 
million, compared with 45,752 million pounds, valued at $1,078 million, 
in 1971. 

The output of aromatic and naphthenic products from petroleum 
amounted to 23,753 million pounds in 1972, compared with 21,449 million 
pounds in 1971. Sales amounted to $351 million in 1972, and ^308 
million in 1971. The output of 1° and 2° benzene from petroleum in 1972 
(8,654 million pounds) was 17,1 percent more than the 7,388 million 
pounds produced in 1971. 

Production of all aliphatic hydrocarbons and derivatives from 
petroleum and natural gas was 63,039 million pounds in 1972, compared 
with 59,594 million pounds in 1971. Sales Of these products were 
valued at $825 million in 1972 compared with $769 million in 1971. 
Production of ethylene was 20,852 million pounds in 1972--13.0 percent 
more than the 18,450 million pounds produced in 1971. The output of 
1,3-butadiene in 1972 (3,527 million pounds) was the largest on record. 

Data for 19 72 crude products from petroleum and natural gas for 
chemical conversion was supplied by 73 companies and company divisions. 



^ Statistics on aromatic chemicals from coal tar are given in the re- 
port on "Tar and Tar Crudes". 

^ See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are given in table 3. 



SYNTHETIC ORGANIC CHEMICALS, 1972 ' 
TABLE 1. --Crude products from petroleum and natural gas for chemical conversion: 

U.S. production and SALESy 1972 



[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. {Leaders (...) are used where the reported data are accepted in confidence 
and may not be published or where no data were reported.) Table 2 lists separately all products from petroleum and 
natural gas for chemical conversion for which data on production or sales were reported and identifies the 
manufacturers of each] 



Quantity 



Grand total 

2 

aromatics and napiithenes 

Total 

Benzene (1° and 2°) 

Naphthalene, all grades 

Naplithenic acid 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2- 

Solvent grade, 90% 

All other 

Xylenes, mixed, total 

3° grade 

5'^ grade 

All other' 

All other aromatics and naphthenes"* 

ALIPHATIC HYDROCARBONS 

Total 

C hydrocarbons, total 

Acetylene 

Ethane 

Ethylene 

Cj and Cg hydrocarbons, mixed 

C3 hydrocarbons, total 

Propane 

Propylene' 

Cit hydrocarbons, total 

1 , 5- Butadiene, grade for rubbers (elastomers)- 

Butadiene and butylene fractions 

n- Butane 

1-Butene 

1-Butene and 2-butene mixtures' 

Isobutane 

Isobutylene 

All other* 

C5 hydrocarbons, total 

Isopentane (2-Methylbutane) 

Isoprene (2-Methyl-l ,3-butadiene) 

Pentenes, mixed 

All other' 



1,000 
pounds 

3,792,187 



,752,898 



8,653,736 
230,643 
33,190 

6,552,591 



4,877,029 
429,868 
152,401 

1,093,293 

5,306,422 



1,184,423 

383,384 

3,758,615 

2,976,316 



26,297,040 



5,136,540 

20,852,144 



133,062 
18,079,972 



9,608,315 
8,471,657 



10,610, 



3,527,422 
567,998 

2,331,119 

61,597 

752,791 

942,082 

600,184 

1,827,734 

962,223 



7,967 
372,663 
318,978 
262,615 



1,000 



47,899,859 



1,000 
do t tars 



1,176,609 



15,402,465 



4,420,693 
164,314 



3.867,231 



,828,364 
255,584 



783,283 
4,017,5.J5 



744,195 

401,381 

2,872,009 



3,995,766 
5,649,443 



8,620,910 
3,918,302 



2,230,009 

436,231 

443,707 

46.617 

782,157 

315,564 
1,397,859 



351,401 



122,140 

7,753 



66,662 
5,738 



16,628 
93,550 



16,539 
9,995 
67,016 



36,729 
168,252 



107,445 
111,765 



251,300 



173,844 
11,817 
4,367 
2,386 
21,681 

11,808 
25.397 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSIC:! 

TABLE 1,— Crude products from petroleum and natural gas for chemical conversion; 
U.S. production and sales, 1972 



Quantity 



Unit 
value' 



1,000 



1,000 



aliphatic HYDROCARBONS--Continued 

All other aliphatic hydrocarbons, derivatives, and 

mixtures, total 

Alpha olefins 

Heptenes, mixed 

Hexanes and other Cj. hydrocarbons 

Nonene (Tr ipropy lene) 

n-Paraffins, total 

Carbon chain length, C^-Cj^ 

Other 

Polybutene 

Tetrapropylene 

Hydrocarbon derivatives 

All other" 



956 


265 


517 


434 


83 


838 


339 


668 


341 


590 


063 


653 


279 


199 


784 


454 


198 


080 


210 


173 


114 


246 


087 


583 



4,134,378 



iini,084 

26,713 

299,807 

247,040 

747,744 

276,351 

471,393 

139,356 

57,322 

82,760 

2,132,552 



1,000 
dollars 



133.389 



Per 

pound 



21,946 
847 

8,621 

8,446 
23,151 

5.170 
17,981 
10,217 

2,034 
10,008 
48,119 



.055 
.032 
.029 
.034 
.031 
.019 
.038 
.073 
.035 
.121 
.023 



' Calculated from rounded figures. 

2 The chemical raw materials designated as aromatics are in some cases identical with those obtained from the 
distillation of coal tar; however, the statistics given in the table above related only to such materials as are de- 
rived from petroleum and natural gas. Statistics on production or sales of benzene, toluene, xylene, and naphthalene 
from all sources are given in tables 1 and IB of the report "Tar and Tar Crudes, 1972." 

5 Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. 

" Includes data for crude cresylic acid, alkyl aromatics, distillates, solvents , miscellaneous cyclic hydrocarbons 
and sales of naphthenic acid. 

5 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of 
the Census. 

' Includes data for propane-propylene mixture. 

' The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

8 Includes data for mixed butanes, 2-butene, mixed butylene, and mixed olefins. 

' Includes data for isopentane, pentenes, and C5 hydrocar^joi mixtures. 
'" Includes data for the following molecular weight ranfer.: Ce-C?; Ca-Cio; C,i-C,5; Cjj-Cn; C15-C20; and 

" Includes compounds having a molecular weight of 3,000 or less. 
'2 Includes data for butyl, ethyl, methyl, and miscellaneous mercaptans . 

" Includes data for di-isobutylene, methane-ethane-ethylene mixture, heptane, methane, octanes, hydrocarbon mixtures, 
sales of acetvlene and of mixed C- and C, hydrocarbons. 



SYNTHETIC ORGANIC CHEMICALS. 1972 

TABLE 2, --Crude products from petroleum and natural gas for chemical conversion for which 
U.S, production or sales were reported, identified by manufacturer, 1972 

[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in 
table 1 are marked below with an asterisk (*) ; products not so marked do not appear in table 1 because the reported 
data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken 
from table 3. An x signifies that the manufacturer did not consent to his identification with the designated product 



Manufacturers' identification codes 
(according to list in table 3) 



AROMATICS AND NAPHTHENES 

*Benzene (except motor grade) : 

'Benzene, 1° 

*Benzene, 2° 

Cresylic acid, crude 

♦Naphthalene, all grades- 

*Naphthenic acids: 

Acid number lower than 150 

Acid number 150-199 

Acid number 200-224 

Sodium carbolate and phenate, crude 

*Toluene: 

*Nitration grade, 1° 

*Pure commercial grade, 2° 

'Solvent grade, 90°i. 

All other 

'Xylenes, mixed: 

Aviation grade 

*3° grade 

*5° grade 

All other 

All other aromatics, naphthenes, distillates and solvents 

ALIPHATIC m'DROCARBGNS 

Ci hydrocarbon: Methane 

*C 2 hydrpcarbons: 

'Acetylene 

'Ethane 

'Ethylene 

*C 2 and C 3 hydrocarbons, mixed 

*C 3 hydrocarbons: 

'Propane 

'Propane-propylene mixture 

'Propylene 

*C 1, hydrocarbons : 

♦1,3-Butadiene, grade for rubbers (elastomers) 

'Butadiene and butylene fractions 

*n- Butane 

'1-Butene 

2-Butene 



ACU, AMO, APR, ASH, ATR, CCP, CSP, CSD, CSO, CSP, DLH, 
ENJ, GDC, GRS, MOC, MON, PLC, PPR, SHC, SHO, SKO, SM, 
SNT, SOG, SUN, TOG, TX, UCC, UOC. 

CPI, DOW, SHO, SOG. 

PRO. 

ASH. GOL, MON. SUN, TID. 

SOG, SUN, TX. 
ATR, PRO, SOG, SUN. 
ATR, PRD, see. 
ATR. 

ASH, ATR, CCP, CSD, CSP, DLH, ENJ, GOG, MOG, MON, PLC, 

PPR, SHC, SHO, SNT, SOG, SUN, TOG, TX, UCC, UOG. 
ATR, CPI, DOW, ENJ, MON, UCC. 
AGG, FG, SKO. 
ATR, CPI, CSD, ELP, GRS, GYR, PLC, PPR, SHO, SM, SOG. 

CSO. 

CSD, DLH, GOC, MOG, PPR, SHO, SUN, UOG. 

ASH, ATR, SOG. 

AMO, CCP, CPI, CSD, CSP, ENJ, HGR, MON, PPR, SHC, SNT, 

SOG, STY, SUN, TOG, UCC. 
AGG, ACU, ATR, CBN, CPX, DUP, ELP, ENJ, FG, GOG, JCG, 

MOC, MON, OMG, PLC, SHC, SOG, SOG, TX, UCC. 



DOW, DUP, MNO, RH, UCC. 

ACU, ATR, DOW, ENJ, MON, OMG, PAN, PLC, PUE, SHO, SM, 

TX, USI. 
ACU, ATR, BFG, CBN, GO, CPX, DOW, DUP, EKX, ELP, ENJ, 

FRO, GOC, JCG, KPP, MON, NWP, OMG, PLC, PUE, SHC, SM, 

SNO, UCC, USI. 
CCP, GO, CSO, PLC. 

AMO, ASH, ATR, COR, CPI, CSD, CSO, CSP, ENJ, GOG, 

GRS, MOG, OMG, PAN, PLC, PUE, SHO, SM, SNT, SOG, SUN, 
TX, UOC, USI. 

GOG. 

ACU, AMO, ASH, ATR, BFG, CBN, CCP, COR, CPX, CSO, DOW, 
DUP, EKX, KLP, ENJ, GOG, JCC, KPP, MOC, MON, NWP, 
PLC, PUE, SHC, SHO, SIO, SM, SNT, SOG, SUN, TX, UCC. 

ATR, BFG, GPY, DOW, ELP, ENJ, FRS, MON, PLC, PTT, PUE, 

SBI, SHC, SM, TID, TUS, UCC. 
ACU, ATR, CO, CPX, DOW, EKX, GOC, GYR, KPP, PLC, SHO, 

UCC. 
ATR, BFG, COR, CPI, CSD, CSP, GRS, OMC, PAN, PLC, SHO, 

SM, SNT, SUN, USI. 
GOC, PLC, PTT. 
MON, PLC. 



CRUDE PRODUCTS FRO^l PETROLEUM 



NATURAL GAS FOR CHEMICAL CONVERSION 



TABLE 2, --Crude products from petroleum and natural gas for chemical conversion for which 
U,S, production or sales were reported, identified by manufacturer, 1972--Continued 



Manufacturers' identification codes 
(according to list in table 3} 



ALIPHATIC HYDROCARBONS- -Continued 

*C^ hydrocarbons--Continued 

*1-Butene and 2-butene mixture 

*Isobutane 

*Isobutylene 

All other 

*C^ hydrocarbons: 

*lsopentane (2- Methyl butane) 

*lsoprene (2-Methyl-l , 3-butadiene) 

n-Pentane 

*Pentenes, mixed 

All other 

'Cf hydrocarbons: 

*Hexane 

Neohexane (2, 2-Dimethylbutane) 

All other 

Cj hydrocarbons: 

n-Heptane 

*Heptenes, mixed 

All other 

Cg hydrocarbons: 

Diisobutylene (Diisobutene) 

n-Octane 

All other 

Hydrocarbons, Cg and above: 

*Nonene CTripropylene) 

*Polybutene 

*Tetrapropylene 

Triisobutylene 

All other 

*A11 other aliphatic hydrocarbons, derivatives and 
mixtures; 
Hydrocarbons : 
*Alpha olefins--Molecular weight ranges: 

Cj.-C, 

Cj-'^io 

Ci,-Cl5 

All otner 

*n-Paraf fins--Carbon chain length: 

C^.C, 

♦C-c,, 

C,o-Ci6 

All other 

*Hydrocarbon derivatives: 

n- Amyl mercap tan 

tert-Amyl mercaptan (2-Methyl-2-butanethiol) — 

1- Butane thiol 

tcrt- Butyl -mercaptan (2-Methyl-2-propanethiol)- 

Cyclohexyl mercaptan 

Di-tert- butyl disulfide 

Di-tert-nonylpoly sulfide 

Ethyl mercaptan (Ethanethiol) 

n-Hexadecyl mercaptan 

I s opropy 1 mercaptan 

Methyl mercaptan (Methanethiol) 

tert-Nonyl mercaptan 

n-Propyl mercaptan (1-Propanethiol) 

All other 

Mixtures, not elsewhere classified 



AMD, ATR, CSO, ENJ, GDC, PLC, PIT, SHO, TX . 

AIR, CSP, ELP, GRS, CMC, PAN, PLC, SHO, USI. 

ENJ, PLC, SHC, SHO, x. 

APR, ATR, BFG, CBN," ENJ, GRS, JCC, MON, PLC, PUE, SM, 
USI. 

APR, PAN, PLC, SHO, SM. 

BFG, ENJ, GYR, MON, SHC. 

APR, PLC. 

GYR, MON, TX. 

CBN, ELP, MON, PLC, SHC, UCC. 

APR, ENJ, PLC, SOG, UOC. 

PLC. 

APR, BFG, PLC, SWC. 

EKX, PLC, SOG. 

AIP, ENJ, GOC, SOI, TID. 

ENJ, HCR, PLC, UOC. 

BFG, PTT, TX. 

SOG. 

ENJ, PLC. 

AIP, ATR, CSD, ENJ, SUN, UOC. 

ACC, CSD, SOC. 

ATR, CO, ENJ, SOC, SUN, TX, UOC. 

X. 

ACC, ATR. CO, CPI, ENJ, KPP, PLC, PUE, SOC, TID, TNA, 
UCC. 



GOC, GYR, SOC. 

GOC, SOC. 

GOC, SOC. 

EKX, GOC, SOC, TID, TNA. 

SOG. 

BFG, HCR, SOG. 

ENJ, SOG, UCC. 

CO. 

ATR, PUE, UCC. 

PAS. 

PLC. 

PAS, PLC. 

PAS. 

PAS. 

PLC. 

PAS. 

PAS, PLC. 

PAS. 

PAS. 

ACC, PAS. 

PAS. 

PAS, PLC. 

EKX, PAS, PLC, UCC. 

ATR, GYR, MON. 



SWHETIC ORG,AfHC CHB1ICALS. 1^72 

TABLE 3,— Crude products from petroleum and natural gas for chemical conversion: 
Directory of manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 



[Names of manufacturers that reported production or sales of crude products from petroleum and natural gas for 
chemical conversion to the U.S. Tariff Commission for 1972 are listed below in the order of their identification 
codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 




ACC 


Amoco Chemicals Corp. 


MNO 


Monochem, Inc. 




ACU 


Allied Chemical Corp. , Union Texas 


MOC 


Marathon Oil Co., Texas Refining Div. 






Petroleum Div. 


MON 


Monsanto Co. 




AIP 


Air Products 6 Chemicals, Inc. 








AMO 


American Oil Co. (Texas) 


NWP 


Northern Petrochemical Co. 




APR 


Atlas Processing Co. 








ASH 


Ashland Oil, Inc. 


OCC 


Oxirane Chemical Co. 




ATR 


Atlantic Richfield Co., ARCO Chemical Co. 
Div. 


OMC 


Olin Corp. 






PAN 


Amoco Production Co. 




BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


PAS 


Pennwalt Corp. 






Co. Div. 


PLC 
PPR 


Phillips Petroleum Co. 
Phillips Puerto Rico Core, Inc. 




CBN 


Cities Service Co., Petrochemical Div. 


PRO 


Productol Chemical Co., Inc. 




CCP 


Crown Central Petroleum Corp. 


PTT 


Petro-Tex Chemical Corp. 




CO 


Continental Oil Co. 


PUE 


Puerto Rico Olefins 




COL 


Collier Carbon 6 Chemical Corp. 








COR 


Commonwealth Oil 5 Refining Co., Inc. 


RH 


Rohm S Haas Co. 




CPI 


Commonwealth Petrochemicals, Inc. 








CPX 


Chemplex Co. 


SBI 


Standard Brands Chemical Inudstries, 


nc. 


CPY 


Copolymer Rubber 6 Chemical Corp. 


SHC 


Shell Oil Co., Shell Qiemical Co. Div 




CSD 


Cosden Oil 5 Chemical Corp. 


SHO 


Shell Oil Co. 




CSO 


Cities Service Oil Co. 


SIO 


Standard Oil Co. of Ohio 




CSP 


Coastal States Petrochemical Co. 


SKO 
SM 


Skelly Oil Co. 
Mobil Chemical Co. 




DLH 


Amerada Hess Corp. 


SM 


Mobil Oil Corp. 




DOW 


Dow Chemical Co. 


SNO 


SunOlin Chemical Co. 




DUP 


E. I. duPont de Nemours § Co., Inc. 


SNT 


Suntide Refining Co. 








SOC 


Standard Oil Co. of California, Chevron 


EKX 


Eastman Kodak Co. , Texas Eastman Co. Div. 




Chemical Co. 




ELP 


El Paso Products Co. 


SOG 


Charter International Oil Co. 




ENJ 


Exxon Chemical Co. U.S.A. 


SOI 
STY 


American Oil Co. (Maryland) 
Styrochera Corp. 




FG 


Foster Grant Co. , Inc. 


SUN 


Sun Oil Co. 




FRO 


Vulcan Materials Co., Chemicals Div. 


SWC 


Shell 6 Commonwealth Chemicals, Inc. 




FRS 


Firestone Tire 5 Rubber Co., Firestone 










Synthetic Rubber § Latex Co. Div. 


TID 
TNA 


Getty Oil Co. 
Ethyl Corp. 




GOC 


Gulf Oil Corp. , Gulf Oil Chemicals 


TOG 


Tenneco Oil Co. 






Co. - United States 


TUS 


Texas-U.S. Chemical Co. 




GRS 


Champlin Petroleum Co. 


TX 


Texaco, Inc. 




GYR 


Goodyear Tire ii Rubber Co. 


UCC 


Union Carbide Corp. 




HCR 


Hercor Chemical Corp. 


UOC 

US I 


Union Oil Co. of California 

National Distillers f, Qiemical Corp., 




JCC 


Jefferson Chemical Co. , Inc. 




U.S. Industrial Chemicals Co. Div. 




KPP 


Sinclair-Koppers Co. 








Note.- 


-Complete names and addresses of the above reporti 


ng compc 


inies are listed in Table 1, of the Anpe 


ndix. 



19 



CYCLIC INTERMEDIATES 

Cyclic intermediates are synthetic organic chemicals derived princi- 
pally from petroleum and natural gas and from coal-tar crudes produced by 
destructive distillation (pyrolysis) of coal. Most cyclic intermediates are 
used in the manufacture of more advanced synthetic organic chemicals and 
finished products, such as dyes, medicinal chemicals, elastomers (synthetic 
rubbers), pesticides, and plastics and resin materials. Some intermediates, 
however, are sold as end products without further processing. For example, 
refined naphthalene may be used as a raw material in the manufacture of 2- 
naphthol or of other more advanced intermediates, or it may be packaged and 
sold as a moth repellent or as a deodorant. In 1972 about 46 percent of 
the total output of cyclic intermediates was sold; the rest was consumed 
chiefly by the producing plants in the manufacture of more advanced interi- 
mediates and finished products. 

Total production of cyclic intermediates in 1972--34,967 million 
pounds--was the largest on record, and was 16.7 percent larger than the out- 
put of 29,953 million pounds reported for 1971. The larger output of cyclic 
intermediates in 1972 reflects the increased demand by the chemical products 
industries, particularly those industries that produce plastics materials, 
dyes, pigments, and plasticizers. Sales of cyclic intermediates in 1972 
were 16,196 million pounds, valued at $1,434 million, compared with 12,971 
million pounds, valued at $1,252 million, in 1971. 

Production of styrene in 1972 was 5,941 million pounds, or 26.9 percent 
more than the 4,682 million pounds produced in 1971. Output of ethylbenzene 
was 5,676 million pounds, an increase of 13.9 percent from the 4,984 million 
pounds produced in 1971. Other intermediates whose production exceeded 1 
billion pounds in 1972 were cyclohexane (2,298 million pounds), cumene 
(2,293 million pounds), p-xylene (2,208 million pounds), dimethyl tere- 
phthalate (2,167 million pounds), phenol (2,096 million pounds), and tere- 
phthalic acid (1,929 million pounds). Other large-volume intermediates 
produced in 1972 were phthalic anhydride (933 million pounds), o-xylene 
(832 million pounds), cyclohexanone (783 million pounds), isocyanates 
(702 million pounds), nitrobenzene (551 million pounds), straight chain 
alkylbenzenes (524 million pounds), 2,4 and 2,6-dinitrotoluenes (434 mil- 
lion pounds), aniline (410 million pounds), and monochlorobenzene (404 
million pounds). The above 17 chemicals accounted for 86 percent of the 
total output of cyclic intermediates in 1972. Production of 15 of the 
above chemicals increased in 1972 compared to 1971; the output of alkyl 
benzenes decreased by 4.7 percent and of monochlorobenzene by 1.3 percent. 



SYNTHETIC ORGANIC CHEHICALS. 1972 
TABLE 1.— Cyclic intermediates; U.S, production and sales, 1972 



[Listed below are all cyclic intermediates for which any reported data on production or sales may be published. 

(Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no date 
were reported.) Table 2 lists alphabetically all cyclic intermediates for which data on production or sales were 
reported and identifies the manufacturers of each] 



Production 



Quantity 



Total 

Acetanilide, tech 

Acetophenone, tech 

A Ikyl benzenes^ 

1-Aminoanthraquinone and salt 

7- (p-Aminobenzamido) -4 -hydroxy- 2-napht ha lenesulfonic acid- 

l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Araino-5-chloroanthraquinone 

l-Aniino-2,4-dibronioanthraquinone 

l-Amino-9, lO-dihydro-9, 10-dioxo-4-p-toluenesulfonamido-2- 
anthracenesulfonic acid, sodium salt 

N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon- 

amide 

p- [(p-Aminophenyl)azo]benzenesulfonic acid 

Aniline (Aniline oil) 

Anilinoraethanesulfonic acid and salt 

o-Anisidine 

o-Anisidinoraethanesulfonic acid 

Anisole, tech 

Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone) 

Benzaldehyde, tech 

7H-Benz[de]anthracen-7-one ( Ben zan throne) 

Benzoic acid, tech 

2-Benzothiazolethiol, sodium salt 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'- (2H, 2 'H)-dione 

(Pyrazoleanthrone yellow) 

[4,4'-Bi-7H-benz|de]anthracene]-7,7'-dione 

Biphenyl 

1 , 4- Bi s [ 1 - anthraquinony lamino ] anthraquinone 

3- Bromo-7H-benz[de] anthracene- 7-one (5- Bromobenzan throne) - 

2-Bromo-4 ,6-dinitro aniline 

1-Chloroanthraquinone 

Chlorobenzene, mono 

6-Chlororaetanilic acid 

l-Chloro-2-methyl anthraquinone 

1-Chloro-S-nitroanthraquinone 

4-Chloro-3-nitrobenzenesulfonaraide 

a-Chlorotoluene (Benzyl chloride) 

Cinnamoyl chloride 

Cresols, total' 

o-Cresol 

(m,p)-Cresol 

All other" 

Cresylic acid, refined' 

Cumen e 

Cyclohexane 

Cyclohexanone 

Cyclohexylamine 

1 ,4-Diaminoanthraquinone 

2, 6-Diaminoanthraquinone 

1 ,4-Diamino-2,3-dihydroanthraquinone 

4,4'-Diamino-2,2'-stilbenedisulfonic acid 



1,000 
pounds 
34,967,181 



524,009 
359 



724 

36 

1,014 





456 


409 


820 




686 


o 


106 




664 




195 




64 


4 


607 


1 


184 


155 


505 


9 


667 



149 

626 

114 

403,505 

6 

91 

40 

507 

80,357 



49,668 
28,292 
28,313 



54,981 

2,292,949 

2,298,394 

783,440 

104 



1,000 
pounds 

16,195,641 



1,000 
dollars 

1,433,855 



1,679 
502,995 



4,231 
14,273 



1,345,895 

2,018,404 

56,960 



1,443 
1,989 



7 


303 


4 


438 


8 


617 


7 


442 


46 


882 


60 


168 


7 


055 


1 


174 



See footnotes at end of table. 



CYCLIC INTERMEDIATES 



TABLE 1.— Cyclic intermediates: U.S. production and sales. 1972— Continued 



4,5'-Dibenzamido-l,r-iminodianthraquinone 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine base and salts 

Dicyclopentadiene (includes cyclopentadiene) 

N,N-Di ethyl aniline 

9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic acid and 

salt 

9, lO-Dihydro-9, lO-dioxo-l-anthracenesulfonic acid and salt 

(Gold salt) 

1 ,4-Dihydroxyanthraquinone (Quinizarin) 

l,8-Dihydroxyanthraquinone(Chryazin) 

1 ,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro 

chrysazin) 

16, 17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

N,N-Dimethylaniline 

N,N-Dimethylbenzyl amine 

2, 2- Dimethyl -1 , 1 ' -bianthraquinone 

4,4'-Dinitrostilbene-2,2'-disulfonic acid 

2, 4 (and 2, 6)-Dinitrotoluene 

Diphenyl amine 

1 ,4-Di-p-toluidinoanthraquinone 

Divinylbenzene- 

N- Ethyl aniline, refined 

2-(N-Ethylanilinc;)ethanol 

Ethylbenzene ^ 

N-Ethyl-N- phenyl benzyl amine 

Hydroquinone, tech 

3-Hydroxy-2-methylcinchoninic acid 

6-Hydroxy-2-naphthalenesulfonic acid, sodium salt 

1,1'- Iminobis [4-aminoanthraquinone] 

1,1 ' -Iminodianthraquinone (1, 1 ' -Dianthrimide) 

Isocyanic acid derivatives, total 

Toluene-2,4- and 2,6-diisocyanate (80/20 mixture) 

Other isocyanic acid derivatives 

4,4'-Isopropylidenediphenol (Bisphenol A) 

Leuco quinizarin (1 ,4, 9, 10-Anthratetrol) 

dl-p-Mentha-1 ,8-diene (Limonene) 

Metanilic acid (m-Aminobenzenesulfonic acid) 

4,4'-Methylenedianiline 

p- (5-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid 

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

a-Methylstyrene 

Nitrobenzene 

5-Nitro-o-toluenesulfonic acid [S03H=1] 

5-Nitro-o-toluidine [NH2=1] 

Nony 1 pheno 1 

1- [ (7-Oxo-7H-benz [de] ant hracene-3-yl) amino] anthra- 

quinone ■ 

Phenol, total' 

Natural, from coal tar and petroleum 

Synthetic, total 

From cumene ■ 

Other synthetic 

1- Phenyl -1,2-propanedione, 2-oxime 

Phthalic anhydride 

Picolines' 



Production 




Sales 












Quantity ' 


Value 


value' 


2,000 


1,000 


1,000 


Per 


pounds 


pounds 


dollars 


pound 


55 








166 








62,386 


62,389 


7,233 


$0.12 


77,317 


70,704 


6,285 


.09 


4,612 


4,618 


5,792 


1.25 


91,267 


71,673 


2,802 


.04 


3,556 


2,639 


1,417 


.54 


249 








997 








2,095 








107 








159 








141 










8,073 


1,671 


.21 


79 


59 


90 


1.53 


38 








9,230 








433,885 








33,845 


16,981 


3,957 


.23 


86 








3,367 


2,698 


1,720 


.64 


1,866 








218 








5,675,900 


447,259 


13,812 


.03 


478 








11,779 


11,616 


9,129 


.79 


430 








637 








44 








60 








701, M8 


508,847 


156,742 


.31 


419,404 


362,876 


101,516 


.28 


282,244 


145,971 


55,226 


.38 


255,189 


77,197 


11,957 


.15 


87 








9,273 




... 




1,082 










1,888 


830 


.44 


157 








61 


43 


61 


1.42 


37 398 


26 112 


1,317 


. .05 


551,169 


12,622 


804 


• .06 


8,017 








397 








100,295 


40,625 


4,648 


.11 


292 








2,096,125 


1,016,215 


65,944 


.07 


44,298 


25,687 


1,772 


.07 


2,051,827 


990,528 


64,172 


.07 


1,810,884 








240,943 








238 








932,978 


634,050 


44,274 


.07 


6,416 









See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS. F72 



TABLE 1, --Cyclic intermediates: U,S, production and sales, 1972--Continued 



Unit 
value' 



Piper id in e 

Prop i oph enone 

Salicylaldehyde 

Salicylic acid, tech 

Styrene, all grades 

Terephthalic acid 

Terephthalic acid, dimethyl ester 

1 ,4,5, 8-Tetrahydroxyanthraquinone, leuco derivative-- 

6,6'-Thiodimetanilic acid 

Toluene- 2, 4 -diamine (4-ni-Tolylenedianiine) 

4-(o-Tolyazo)-o-toluidine CCI. Solvent Yellow 3) 

1 , 2,4-Trichlorobenzene 

1,3, 3-Trimethyl-A^,a-indolineacetaldehyde 

1 ,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)- 
7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid 

(J Acid Urea) 

Violanthrone (Dibenzanthrone) 

o- Xylene 

p- Xylene 

All other cyclic intermediates 



1,000 

pOWlds 

477 

289 

4,468 

47,095 

5,940,729 

1,928,907 

2,167,332 

54 

175 

167,902 

395 

15,552 

338 

701 

237 

489 

831,782 

2,207,556 

3,391,402 



1,000 
pounds 



163 

3,547 

9,136 

2,810,182 



55,316 



675,700 
2,102,848 
1,973,680 



1,000 
dollars 



160 

3,577 

3,708 

160,568 

50,349 



16,195 

94,816 
434,790 



Per 
pound 



'^ Calculated from rounded figures. 

^ Includes straight-chain dodecylbenzene, tridecylbenzene and other straight-chain alkylbenzenes . Branched-chain 
alkylbenzenes are included in all other cyclic intermediates. 

' Includes data for coke ovens and gas-retort ovens, reported to the Division of Fossil Fuels, U.S. Bureau of Mines 
and for tar and petroleum refineries and other producers, reported to the U.S. Tariff Commission. 

'' Figures include (o,m,p)-cresol from coal tar and some m-cresol and p-cresol. 

^ Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture. 



CYCLIC INTERMEDIATES 
TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 

[Cyclic intermediates for which separate statistics are given in table 1 are marked with an asterisk (*); cyclic 
intermediates not so marked do not appear in table 1 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shoim below are taken from table 3. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



Acenaph thenequinone 

8-Acetamido-l- C4-acetamido-2-hydroxy-5-nitrophenylazo) - 
2-naphthol . 

5-Acetamido-2-aminobenzenesulfonic acid 

3-[ C2-Acetamido-4-aminophenyl)azo]-l ,5-naphthalene- 
disulfonic acid. 

2,2'- [(S-Acetamido-2-ethoxyphenyl)imino]diethanol 

2,2'- [ (5-Acetamido-2-methoxyphenyl) imino] diet hand 

4-Acetamido-2-hydroxybenzoic acid 

a- Acetamido-p- toluenes ulfonamide 

*Acetanilide, tech 

Acetic acid, phenyl ester 

Acetoacetani lide 

o-Acetoacetanisidide 

Acetoacet-2 ,5-dimethoxy-4-chloroani lide 

o-Acetoacetotoluidide 

2 ' ,4' -Acetoacetoxylidide 

1 ' -Acetonaphthone 

Acetone phenylhydrazone 

* Ace t ophenone , tech 

p-Acetotoluidide 

p- Ace tylbenzenes ulfonamide 

p-Acetylbenzenesulfonic acid, sodium salt 

p- Ace tylbenzenesulfony lure thane 

N-Acetylsulfanilyl chloride 

*Alkylbenzenes: 

Dodecylbenzene (including tridecylbenzene) : 

'Straight chain 

Other 

Alkylphenols , mixed 

Alkylpiperazines, mixed 

Alky 1 pyridines, mixed 

a-dl-5-Allyl-6-imino-l-nethyl-5- (l-methyl-2-nentynyll - 

barbituric acid. 
a-dl-5-Allyl -5- (1 -methyl -2-pcntynyn-l-methylbarbituric 
acid. 

3'-Aminoacetanilide 

4'-Aminoacetanilide (Acetyl-p-phenylenedi amine) 

2'-Aminoacetophenone 

3' -Aminoacetoplienone 

4'-Aminoacetophenone 

5 '-Amino- 2- (p-aminoanilino)benzenesulfonic acid 

1- Amino- 4- (3-amino-4-sulfoani lino)-9, lO-dihydro-9, 10- 
dioxo-2-anthracenesulfonic acid. 

2- (p-Aminoanilino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisanilide 

*1-Aminoanthraquinone and salt 

2-Aminoanthraquinone and salt 

N- (4-Amino-l-anthraquinonyl) anthrani lie acid 



BJL. 
TRC. 

GAF. 
IPX. 

TCH. 

TCH. 

SDW. 

SDW. 

CTN, EKT, MRK, SAL. 

UCC. 

FMP, HST. 

FMP, HST, UCC. 

FMP. 

FMP, HST, t'CC. 

HST. 

CIV. 

DUP. 

ACP, CLK. SKO, UCC. 

EK. 

LIL. 

LIL. 

LIL. 

ACY, CTN, MRK, SAL. 



BRP, CO, MON, I'CC, WTC. 

CO, SOC, UCC. UCC. 

PRD. 

AIP. 

UCC. 

LIL. 

LIL. 



AAP. 










CAP, 


TRC. 








EK. 










CTN. 










EK. 










TRC, 


YAW. 








TRC. 










TRC. 










PCW. 










AAP, 


ACY. 


MAY, 


SDC, 


TRC 


ACY, 


GAF. 








GAF. 











See footnotes at end of table 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972--CONT I NUED 



N-(5-Amino-l-anthraqiiinonyl)anthraniUc acid 

4-Aminoantipyrine '' 

6-Amino-3,4'-azodibenzenesulfonic rcid (C.I. Acid 

Yellow 9) . 
Aminoazoxylene toluene homologues 

p-Aminobenzamide 

1- Amino- 4-benzaiiiidoanthraquinone 

l-Amino-S-benzamidoanthraquinone 

7_ [p- (p-Aminobenzamido)benzamido]-4-hydroxy-2- 

naphthalenesulfonic acid. 
*7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic 

acid. 

2-Amino-p-benzenedisulfonic acid [SOjH^l] 

o-Aminobenzene thiol 

4-Aminobenzenethiosulfonic acid, sodium salt 

2 - Ami nobenz imidazole 

4-Aminobenzophenone 

2-Amino-6-benzothiazolecarhoxylic acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

N-(4-Amino-3-brorao-l-anthraquinonyl)-p-toluidine 

sulfonic acid. 
Stand 8)-Amino-8(and 5)-bromo-9,10-dihydro-9,10-dioxo- 
l,6(and 1 ,7)anthracenedisulfonic acid. 

*l-Amino-2-bromo-4-hydroxyanthraquinone 

1- Amino- 2-bromo-4-p-toluidinoanthraquinone 

*l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2 -Amino- 1 - ch 1 oroanth raquinone 

2-Amino-3-chloroanthraquinone 

4- Amino-6-chloro-m-benzenedi sulfonamide --- 

4-Amino-6-chloro-m-benzenedi sulfonamide hydrochloride 

2-Aiiiino-6-chlorobenzothiazole hydrochloride 

o-(3-Amino-4-chlorobenzoyl1benzoic acid 

1- Amino- 2 -chloro-4-hydroxyanthraqui none 

3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 

2-Amino-4-chlorophenol 

l-(2-Amino-5-chlorophenyl)-l-phenylmethylenimine 

2-Amino-6-chloropyrazine 

3-Amino-6-chloropyridazine 

2-Amino-5-chloro-p-toluenesulfonic acid [Sn3H=l] 

6-Amino-4-chloro-m-toluenesulfonic acid [S03H=1] 

2-Amino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

1- Amino- 2 , 4- di ch 1 oroanthraquinone 

2-Amino-4,6-dichloro-5-cresol 

4-Amino-2,6-dichorophenol hydrochloride 



Manufacturers' identification codes 
(according to list in table 31 



DUP. 




VPC. 




ACY, 


CMC 


ACS. 




ICC, 


SDH 


(lAY, 


TRC 


ACY, 


TRC 


CMC. 





CMC, GAP, TRC, VPC. 

DUP, TRC. 

PIS, FMT. 

SDC. 

EK. 

DUP. 

DUP. 

GAP. 

TRC. 

TRC. 

AAP, DUP, UN, VPC. 

ACS, TRC. 

ACY, HAY, TRC. 

DUP. 

DUP, ICI. 

GAP. 

ABB. 

ABB. 

DUP. 

AAP. 

TRC. 

TRC. 

SW. 

ABB. 

ACY. 

ACY. 

HSC. 

DUP, HSC. 

TRC. 

AAP, DUP, HN, TRC, VPC. 

TRC. 

EK. 

EK. 



CYCLIC INTERMEDIATES 
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported, 

IDENTIFIED EY MANUFACTURER, 1972— CONTINUED 



*l-Aiiiino-9,10-dihydro-9, 10-dioxo-4-p-toluenesulfonaiiiido- 

2-anthracenesulfonic acid, sodium salt. 
5-Amino-4,5 '-dihydroxy-3,4' - [(2-methoxy-5-raethyl-p- 

pheny lene )bis(azo)]-di- 2, 7-naphthalenedi sulfonic acid, 

5 ' -benzenesulf onate . 

3-Amino-9-ethylcarbazole 

N- C2-Aminoethyl)-N-ethyl-m-toluidine 

3-Amino-a-ethylhydrocinnamic acid 

N- [2- C4-Amino-N-ethyl-m-toluidino)ethyl]methane- 

sulfonamide, hemisulfate. 

N-Aminohexamethyleneimine 

4- Amino- 5-hydroxy- 2, 7-naphthalenedi sulfonic acid, 

benzenesulfonate. 
4-Amino-5-hydroxy-2 ,7-naphthalenedisulfonic acid 

(H acid), monosodium salt. 
4-Araino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4- 

acid) . 
6-Amino-4-hydroxy-2-naphthalenesulfonic acid CGarama 

acid], sodium salt. 
7-.iVmino-4-hydroxy-2-naphthalenesulfonic acid (,J acid) , 

sodium salt. 
2- (2- Amino- 5-hydroxy- 7-sulf 0-1 -naph thy lazo) -5 -nit ro- 

benzoic acid. 
4-Amino-3-(6-methanesulfoaminoethyl)-N,N-diethylaniline 

hydrochloride. 
*N- (4- Amino- 3- me thoxy-1-anth raquinonyl)-p- toluenes ulfon- 

amide. 

5-Amino-6-raethoxy-2-naphthalenesulfonic acid 

4-Amino-5-methoxy-o-toluene sulfonic acid 

m- [(4-Amino-3-methox\'phenyl)azo]benzenesulfonic acid 

8- Amino- 6-methoxyquino line 

4- [(4-AjTdno-5-methoxy-o-tolyl)azo]-5-hydroxy-2 ,7- 
naphthalenedisulfonic acid, benzenesulfonate. 
3- [ (4- Amino- 5 -methoxy-o-tolyl )azo]-l,5-naDh thalenedi sul- 
fonic acid. 
7- [ (4- Amino-S-methoxy-o-tolyl) azo] - 1 , 3-nanhthalenedi - 

sulfonic acid. 
4-.%nino-4'-(3-methyl-S-oxo-2-pyrazolin-l-yl)-2,2'-stil- 

benedisulfonic acid. 

2 -. Ami no- 3-me thy 1 pyridine 

2-Amino-6-methylpyridine 

2-Amino-4-methylpyrimidine C2-Amino-4-raethyl-l ,3- 

diazine) . 

2- Amino- 4- (methylsulfonyl) phenol . 

2-Amino-5-methyl-l ,3,4-thiadiazole 

4-Aminonaphth [2 ,3-c]acridan-5 ,8, 14-trione 

2 - Amino- 1 ,5 -naph thalenedi sulfonic acid 

3-Amino-l ,5-naphthalenedisulfonic acid (C acid) 

3-Amino-2 ,7-naphthalenedisulfonic acid 

6-Amino-l ,3-naphthalenedisulfonic acid (Amino I acid) 

7-Amino-l ,3-naphthalenedisulfonic acid (Amino G acid) 

l-Amino-2-naphthalenesulfonic acid (o-N'aphthionic acid)- 

2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

4-Amino-l-naphthalenesulfonic acid (Naphthionic acid) 

4-Amino-l-naphthalenesulfonic acid, sodium salt 

4(and 5)-Amino-l-naphthalenesulfonic acid 



Manufacturers' identification codes 
(according to list in table 3) 



AAP 


DUP, GAF. 


TRC 




SDC 




WAY 




SDW 




WAY 




F^^p 




TRC 




ACS 




ACY, 


GAF. TRC. 


TRC. 




HN, 


TRC. 


TRC. 




EKT. 




AAP, 


DUP, GAF. 


TRC. 




ACS. 




DUP, 


TRC. 


PD. 




TRC. 




TRC. 




TRC. 




TRC. 




RIL. 




RIL. 




ACY. 




TRC. 




ACY. 




DUP. 




ACY, 


SDH. 


TRC. 




TRC. 




UN, 


TRC. 


DUP, 


TRC. 


DUP. 




ACY, 


SW. 


ACY, 


DUP. 


ACY, 
TRC. 


DUP. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification code 
(according to list in table 5) 



-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

-Amino-l,3,6-naphthalenetrisulfonic acid 

-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid)- 

-Amino-2-naphthol 

- (4-Amino-l-naphthyla:o)-4- (1 , 1 ,3,3-tetramethylbutyl) 
phenol . 

-Amino-4-nitroacetani lide 

-Amino-5- (m-nitrobenzamido) -p-toluenesulfonic acid 

-Amino-5-nitroben2enesulfonic acid [S03H=1] 

- Amino -4'»n itro-3-niethoxyazobenzene 

- 2- Amino- 1- (p-nltrophenyl) -1 ,3-propanediol 

-2-Amino-l-(p-nitrophenyl)-l ,3-propanediol 

-Amino-4'-nitro-2,2'-stilbenedisulfonic acid 

- Amino- 5-nitrothia:ole 

' -Aminooxani lie acid 

'-Aminooxanilic acid 

-Arainopenicillanic acid 

-Aminophenol 

-(p-Aminophenoxy)ethanol hydrochloride 

- [ (p-Aminophenyl) azojbenzenesulfonic acid 

- [(p-Aminophenyl)azo]benzenesulfonic acid 

- [(4-Aminophenyl)azo]-l ,3-naph thai enedi sulfonic acid — 

-Amino- 8- (phenylazo)-2-naphthol 

-Amino-5-(phenylazo)-2-naphthol 

- [ (p-Aminophenyl )azo] - 1-naph thy 1 amine 

- [(p-Arainophenyl)azo] salicylic acid 

-[ (p-Aminophenyl) azojsalicylic acid, sodium salt 

,2 '-(m-Aminophenylimino)diethanol , diacetate ester 

- (p-Aminophenyl) -6 -me thy Ibenzothiazole 

- (p-Aminophenyl) -6-metliyl-7-ben20thia2olesulfonlc acid 
and salt. 

- (m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid-- 

- Amino- 2-propoxybenzoic acid 

- ( Ami nopropyl)cyclohexyl amine 

- Ami nopyri dine 

-Aminopyridine 

- Ami nopyrimi dine 

-Aminorhodanine 

-Aminosalicylic acid 

-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic acid 

-Ami no- 4- (1, 1,3,3- tetramethylbutyl ) phenol 

-Amino- 4- (1,1 ,3,3-tetramethylbutyl) phenol hydro- 
chloride. 

-Aminothiazole 

-Amino-p-toluamide 

-Amino-p-toluenesulfonamide 

-Amino-m-toluenesulfonic acid [SOjHsl] 

-.Amino-m-toluenesulfonic acid [SOjHsl] 

-'\mino-o-toluenesulfonic acid [50^11=1] 

- Amino- 2-p-toluidinobenzenesulfonic acid 

- (4-Amino-m-tolyla2o)benzenesulfonic acid 

- [ (4- Amino-o-tolyl)azo]-l,5-naphthalenedi sulfonic acid- 
- [ (4- Amino-o-tolyl)azo]-l,3-naphthalenedi sulfonic acid- 



SNA, 


TRC. 


DUP. 




ACS. 




TRC. 




r;AF. 




SDC. 




GAF. 




ACS, 


GAF, TRC 


SDC. 




PD. 




PD. 




UN, 


TRC. 


PCW. 




cun, 


TRC. 


DUP , 


VPC. 


TRD. 




•1AL. 




GAF. 




TRC. 




ACY, 


DUP, TRC 


TRC. 




ALL. 




ALL. 




ACS. 




TRC, 


VPC. 


ACS. 




DUP, 


TCH. 


DUP. 




DUP, 


TRC. 


TRC, 


VPC. 


SDW. 




ABB. 




NEP, 


RIL. 


RIL. 




ACY. 




EK. 




MLS, 


TRC. 


GAF. 




GAF. 




GAF. 




ACY, 


MRK. 


SDH, 


X. 


SDW. 




ACY, 


DUP. 


DUP. 




use. 




TRC. 




TRC. 




TRC. 




TRC. 





CYCLIC IiJTERMEDIATES 
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



2-Ainino-3,5-xylenesulfonic acid [S03H=1] 

5-Amino-2,4-xylenesulfonic acid 

•Aniline (Aniline oil) 

Aniline hydrochloride 

2 '-Anilino-6-diethylaniino-5-methylf luoran 

2-Anilinoethanol 

7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl 
J acid) . 

*Anilinomethane5Ulfonic acid and salt 

8-Anilino- 1-naphthalenesulfonic acid (Phenyl peri acid)- 

8-Ani lino- 1-naphthalenesulfonic acid, magnesium salt 

m-Ani linophenol 

D-Ani linophenol 

o-Anis aldehyde 

m-Anisidine 

*o-.Anisidine 

p-Anisidine 

*o-Anisidinoniethanesulfonic acid 

*Anisole, tech 

3- (o-Anisyla2o)benzenesulfonic acid, sodium salt 

Anthracene 

Anthranilic acid (o-Aminobenzoic acid)' 

*Anthra[l,9 cd]pyrazol-6(2H) -one (Pyrazoleanthrone) 

Anthraquinone , 100°s 

1 ,5-Anthraquinonedisulfonic acid 

1 , 8- Anthraquinonedi sulfonic acid 

1,1'- [1,5 (and 1 ,8) -Anthraquinonylenediaminolbis- 
naphth [2 ,3-c]acridan-5,8, 14-trione. 

N,N' - (1 ,5-Anthraquinonylene)dianthrani lie acid 

N,N'- (l,5-Anthraquinonylene)dioxamic acid 

(l-Anthraquinonyl)-l , 2 -hydrazinedi sulfonic acid, 
disodium salt. 

4' ,4' ' '-Azobis [4-biphenylcarboxylic acid] 

Barbituric acid, sodium derivative 

*Benzaldehyde, tech 

l-Benzamido-4-bromoanthraquinone 

1 - Ben z ami do- 4 -chloro anthraquinone 

1-Benzamido-S-chloroanthraquinone 

4-Benzamido-5-hydroxy-2,7-naphthalenedisulfonic acid 

7-Benzamido-4-hydroxy-2-naphthalenesulfonic acid 

Benzani lide 

Benz (a) anthracene- 7,1 2- di one 

*7H-Benz [de] anthracen-7-one (Benzathrone) 

m-Benzenedisulfonic acid 

Benzenesulfonamide 

Benzenes ulfonic acid 

Ben zenesu 1 f ony 1 chloride 

1,2,4 ,5-Ben2enetetracarboxylic- 1,2, : 4, 5 -di anhydride 

1,2,4-Benzenetricarboxylic acid, 1 ,2-anhydride (Tri- 
mellitic anhydride). 

Benzhydrol (Diphenylmethanol) 

Benzidine hydrochloride and sulfate 



SDH. 












DUP. 












ACS, 


ACY, 


DUP, 


FST, 


MAL, 


MOB, RUC, USR 


ACY, 


EK. 










SDH. 












TCH. 












CMC, 


TRC. 










ACS, 


ACY, 


ATL 


DUP, 


TRC, 


VPC. 


DUP, 


SDC. 










EK. 












GAP. 












SDC. 












ASL. 












EK. 












AAP, 


pi IP, 


x. 








DUP, 


MON. 










AAP, 


ATL, 


GAP 


TRC, 


VPC. 




CTN, 


DUP 


GIV 


LIL. 






ACS. 












EK. 












DUP, 


sw. 










DUP, 


GAP, 


TRC 








TRC. 












CMG. 












CMC. 












DUP. 












GAP, 


TRC. 










GAP, 


SW. 










DUP, 


GAP. 










DUP, 


TRC. 










ABB. 












BPC, 


m. 


MNR, 


VEL. 






AAP. 












GAP. 












MAY, 


TRC. 










TRC. 












TRC. 












DUP. 












EK. 












MP, 


ACY, 


DUP 


GAP, 


ICI, 


MAY, SDC, TRC 


KPT, 


UPF. 










NES. 












NES, 


UPF. 










NES. 












DUP, 


PCR 










ACC. 












PD, 


UOP. 










ACS, 


LAK. 











See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Benzidine sulfate, purified 

*Ben2oic acid, tech 

Benzoin 

Benzoinisobutyl ether 

a- Benzoin oxime 

Benzonitrile 

*2-Ben20thiazolethiol sodium salt 

p-Benzoquinonedi oxime 

IH-Benzotriazole 

2H-3,l-Benzoxazine-2,4(lH)-dione 

o-Benzoylbenzoic acid 

Benzoyl chloride 

N-Benzylacetamide 

Benzyl amine 

4- (Benzyl ami no) - 6- ch loro-m- ben zenedi sulfonic acid 

5- [4-N-Benzylaniino-N-methylphenylazo] -l,2,4-tria20le 

p- (Benzyl ami no) phenol 

Benzyl chloro formate 

4-Benzyl-6-chloro-3-keto-7-sulfamyl-l ,2 ,4-ben2ylthia- 
diazine-l,l-dioxide. 
1- Benzyl- 4 ,5-dimethyl-6- (p-methoxybenzyl) -1 ,2,3,6-tetra- 
hydropyridine oxalate. 

Benzyl disulfide 

5- ( Ben zy 1 ethyl amino) -o-toluenesulf on ic acid 

N-Benzyl-N-ethyl-m-toluidine 

3-Benzyl-l,2,3,4,5,6-hexahydro-8-hydroxy-cis-6, 11- 
dimethyl-2 ,6-methano-5-benza20cine hydrobromide . 
6-Benzylidineaminopenicillanic acid, tertiary 
octylamine salt. 

4,4'- Benzyl idenedi-o-toluidine 

4,4'-Benzylidinedi-2 ,5-xylidine 

Ben zyli dene phthalide 

p- (Ben zyloxy) phenol 

l-Benzyl-4-phenylisonipecotic acid 

l-Benzyl-4-phenylisonipecotonitrile 

Benzyltrimethylajnmonium chloride 

Ben zyltri methyl ammonium hydroxide 

Benzyltrimethylammonium methoxide 

*[3,3'-Bianthra[l,9-cd]pyra2ole]-6,6'-(2H,2'H)dione 
(Pyrazoleanthrone yellow) . 
[3,3'-Bi-7H-benz[de]anthracene]-7,7'-dione 

* [4,4 '-Bi-7H-ben-[de] anthracene] -7, 7 '-dione 

l,l'-Bi-2-naphthol 

*Biphenyl 

2,2'-Biquinoline 

Bis-p-aminocyclohexylme thane 

* 1,4- Bis [1- an thraquinonyl amino] anthraquinone 

1,4-Bis [l-anthraquinonylaminojanthraquinone and 1,4-Bis 
[5-chloro-l-anthraquinonylamino]anthraquinone (mixed) . 

2,6-Bis(p-azidobenzylidene)-4-methylcyclohexanone 

Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper 
derivative. 



UK, HN, KLM, HON, PFZ. VEL. 



BPC. 






BPC. 






RSA. 






VEL. 






ACY, 


GYR 


USR, X 


SDC. 






FHT 


SW. 




SW. 






ACY, 


GAP 




HK, 


GAP, 


VEL. 


SDW. 






ARS, 


MLS 




ABB. 






TRC. 







SDW. 

CCW. 
ACS. 

ACS, DUP. 
SDW. 

TRn. 

ACY. 

ACS. 

LIL. 

EK. 

SDW. 

SDW . 

MLS. 

MLS. 

MLS. 

DUP, GAP, TRC. 

DUP. 

ACY, DUP, ICI, MAY. 

EK. 

CUE, DOW, GOC, MON, SNT. 

EK. 

DUP. 

ACY, DUP, GAP, MAY, TRC. 

TRC. 

WAY . 
TRC. 



See footnotes at end of table. 



I 



CYCLIC INTERMEDIATES 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



4,4'-Bis [diethylaiiiino]benzhydrol salt, 2,7-naphthalene- 

disulfonic acid, mixture. 
4- Bis [ (p-diethylaininophenyl)meth\'l]-2 ,7-naphthalene- 

disulfonic acid, leuco fonn. 

4 ,4' -Bis [dimethylaminojbenzhydrol (Michler's hydrol) 

4,4 '-Bis (dime thy 1 amino) ben ihydrol ,disulfinate 

4,4'-Bis [dimethylamino]benzophenone (Michler's ketone)-- 
Bis [p- (diniethylamino)phenyl]methanesulfoni c acid and 

salt. 

3,3' -Bis [3' ,3'-(l'-ethyl-2'-niethyi;)indolyl]phthalide 

3'- [Bis (2-hydroxye thy 1) amino] acetanilide 

3' - [Bis (2-hydroxyethyl) amino] -p-acetoaniside 

3'- [Bis (2-hydroxyethyl) araino]benzanilide, diacetate 

ester. 
3'- [Bis (2-hydroxye thy 1) amino] methanesulfoanilide, 

diacetate ester. 

4,4 '-Bis (p-methoxyphenyl')-3-hexanone 

1,4-Bis [2- (4-methyl-5-phenyloxazolyl) jbenzene (Dimethyl 

POPOP) . 

Bis- (o-nitrophenyl) sulfide 

1,4-Bis [2-(5-phenyloxazolyl))benzene {P0P0P1 

2- Bromoace t ophenone 

p-Bromoaniline 

p-Bromoanisole 

* 3- Bromo-7H-benzfdel anthracene- 7- one (3-Bromo- 

benzan throne) . 

Bromobenzene, mono 

p-Bromobenzenesulfonyl chloride 

p-Bromobenzhydrol 

p-Bromobenzoic acid 

4- Bromob en z ophenone 

Bromoch 1 oroben zene 

6-Bromo-5-chlorobenzoxazolone 

*2-Bromo-4,6-dinitroaniline 

Bromof lucres ce in 

3-Bromo-2-hydroxy-4 ,4 ,5 ,5-tetramethyl-2-cyclopentene- 

1-one. 

l-Bromo-4-(methylajnino)anthraquinone 

6-Bromo-3-methyl-7H-dibenz[f ,ij ]isoquinoline-2,7- (3H)- 

dione. 

3- (Bromome thy 1 ) thi ophene 

l-Bromonaphthalene 

2-Bromo-4' -nitroacet ophenone 

p-Bromophenol 

(p - Bromoph eny 1) ace tonit rile 

4- Bromo- 1 -ph th alami dopen t ane 

a-Bromotoluene 

m-Bromotoluene 

p-Bromotoluene 

2 - Bromo- 1 , 3 , 5- 1 ri ethy Iben zene 

p-Butoxybenz aldehyde 

p-Butoxyphenol 

4- [3- (p-Butoxyphenoxy)propyl]morpholine 

1 - ( Buty 1 amino) an thraquinone 

p- Butyl aniline 

3- (N-Butylanilino)propionitrile 



SDH, 


SW. 




SW. 






DSC, 


DUP, 


SDH 


ACS. 






SDH. 






GAP. 






TCH. 






DUP, 


TCH. 





LIL. 

ARA. 



ARA. 
EK. 



OPC. 

ACY, DUP, GAP, MAY, TRC. 



PD. 
DOW. 



AAP, HST, SDC, TRC. 
ICC. 



AAP, EDO. 
AAP. 

SOW. 

EK. 

GAP. 

EK. 

BPC. 

PD. 

EK. 

EK. 

BPC, EK. 

DUP. 

EK. 

ABB. 

ABB. 

AAP. 

DUP. 

TCH. 



552-743 O - 74 - 3 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972~CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



2-tert-Butylanthraquinone 

p-tert-Butylhenzaldehyde 

n - Buty Ibenzene 

sec-Butylbenzene 

tert- Buty Ibenzene 

p-tert-Butylbenzoic acid 

2-tert-Butyl-p-cre5 0l 

6-tert-Butyl-iii-cresol 

Cn- Buty Icyclopentadienyl) eye lopentadienyl iron 

2 '-tert- Buty 1-4' ,6 '-dimethylacetophenone 

4 -Butyl -a- (dimethyl amino) -o-cresol 

2-tert-Butyl-4-ethylphenol 

N^- Buty l-4-methoxyiiiet anil amide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p- sec- Buty Iphenol 

o- 1 ert - But y Ipheno 1 

p- tert- Buty Iphenol 

tert- Buty Is tyrene 

p- tert - Buty Itoluene 

5- tert- Buty 1-1, 2, 3- trimethy Ibenzene 

5- tert- Buty 1-m- xylene 

6-tert-Butyl-2,4-xylenol 

d-10-Camphorsulfonic acid 

Camphosulfonic acid 

Carbazole , refined 

1- (4-Carbonyl-o-anisyl)-3-raethyl-3- (2-sulfoethyl) 
triazene . 

4,4'-Carbonylbis [phthalic anhydride] 

6 -Carboxy fluorescein 

[(o-Carboxyphenyl) thio]ethylmercury 

Cedrene 

2 '-Chloroacetoacetanilide 

2'-Chloroacetophenone 

3' -Chloroacetophenone 

4'-Chloroacetophenone 

4'-(Chloroacetyl)acetaniline 

2'-Chloroacetyl-2 , 6- dime thy ani line 

9-Chloroacridine 

m-Chloroani line 

o-Chloroaniline 

p-Chloroaniline 

3-(o-Chloroanilino)propionitrile 

5-Chloro-o-anisidine [NH2=1] (4-Chloro-o-anisidine 

[0CH3=1]). 
5-Chloro-o-anisidine hydrochloride 

*l-Chloroantliraquinone 

2-Chloroanthraquinone 

o-Chlorobenzaldehyde 

p-Qnlorobenzaldehyde 

4- (p-Chlorobenzamido)anthraquinone-l,2-acridone 

Chloro-7H-benz[de]anthracen-7-one (Chlorobenzanthrone) - 

*Ch 1 oroben zene , mono 

p-Chlorobenzenesulfinic acid 

p-Chlorobenzenesulf on amide 

p-Chlorobenzenesulfonic acid 

o-Chlorobenzoic acid 

2-Chlorobenzoxazole 

7-Chlorobenzo[b]thiophen- 3(210 -one 

5-Chloro-2-benzoxazolinone 

o-(p-Chlorobenzoyl) benzoic acid 



DUP. 
GIV. 
PLC. 
PLC. 
EK, MTR, PLC, UOP. 

sue. 

ACY. 

KPT, PRD. 

ARA. 

GIV. 

RH. 

ACY. 

ALL. 

GIV. 

DOW, IN A. 

DOW. 

IN A. 

DOW, PRD, SCN, UCC. 

DOW. 

GIV, SHC. 

GIV. 

GIV. 

PIT. 

OTC. 

KF. 

SDC. 

GAF. 

PCR. 
EK. 
LIL. 
GIV. 
FHP, HST. 



LIL. 

DUP. 

SDW. 

EK. 

DUP, GAF. 

DUP, MON, USR. 

DUP, MON. 

DUP, TCH. 

ALL. 



GAF. 

ACY, 

ACY, 

HN, [ 

HN. 

GAF. 

ACY, 

ACS, 

TRC. 

ACY. 

HTR, 

HN. 

EK. 

ACS. 

SW. 

ACY. 



GAF, MAY, TRC. 
GAF. 



DOW, DVC, HK, MON, MTO, PPG, SCC. 



CYCLIC INTERMEDIATES 
TABLE 2, —Cyclic intermediates for which U.S, production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



p-Chlorobenzoyl chloride 

4,4'- (o-Chlorobenz>'lidene)di-2,5-xylidine 

Chloro(p-chlorophenyl)pheny line thane 

Chlorocyclohexane 

4-Chloro-2-cyclopentylphenol 

l-Chloro-2 ,5-diethoxy-4-nitrobenzene 

2-Chloro-N,N-diethyl-4-nitro aniline 

2-Chloro-3' ,4'-dihydroxyacetophenone 

2-Chloro-l ,4-dihydroxyanthraquinone 

4' -Chloro-2 ' ,5 ' -dimethoxyacetoacetanilide 

5-Chloro-2 ,4-dimethoxyani line 

[(4-Chloro-2,5-diniethylphenyl)thio] acetic acid 

1- Chloro-2, 4- dinitrobenzene (Dinitrochlorobenzene) 

5-C]iloro-4,6-dinitrobenzenesulfonic acid 

4-Chloro-3, 5-dinitrobenzenesulfonic acid, potassium salt- 

4-Chloro-5,5-dinitrobenzoic acid 

3- Chlorodi phenyl amine 

Ch 1 o rod iphenylme thane 

5-Chloro-2,4-disulfonyl- (N-benzyl)ani line 

N-(2-Chloroethyl)-4- (2-chloro-4-nitrophenylazo)-N-ethyl- 
aniline. 

4- [ (2- Chloroethyl) ethyl amino] -o-tolualdehyde 

4- [ (2- Ch 1 oroe thy 1) ethyl amino ]-o-tolui dine 

p- [( 2- Chloroethyl) methyl amino] benzaldehyde 

l-Chloro-3-f luorobenzene 

Chloroformic acid, benzyl ester 

Chloroformic acid, phenyl ester 

3' -Chloro-4'-hydroxyacetophenone 

3-Chloro-4-hydrox>'phenylacetothiomorpholide 

7-Chloro-4-hydroxyquinidine 

7-Chloro-4-hydroxyquinidine hydrochloride 

3-Chloro-4-hydroxyquinoline-3,4-carbonic acid 

4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide 

4-Chlorometanilic acid 

5-Chlorometani lie acid 

*6-Chlororaetanilic acid 

N- [(S-Chloro-2-methoxyphenyl)azo]5arcosine 

p- (Chloromethyl)anisole 

*l-Chloro-2-methylanthraquinone 

6-Chloro-4-methylbenzo[b]thiophene-2-ol 

a-Chloromethylnaphthalene , crude 

4-Chloro-N-methyl-3-nitrobenzenesulfonamide 

Chloromethylphenyl ether 

2-Chloro-5- (N-methylsulfamoyl) sulfanilamide 

5-Chloro-2-CN-methylsulfonyl)-4-sulfarayl-N-benzylani line- 

Chloronaphthalenes 

2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline CP"Chloro-o-nitroaniline) 

*l-Chloro-5-nitroanthraquinone 

l-Chloro-2-nitrobenzene CChloro-o-nitrobenzene) 



HN. 

GAF. 

OPC, UOP. 

ACY. 

DOW. 

GAF. 

DUP. 

SDW. 

HSU. 

PCW. 

PCW. 

ACS. 

DUP, SDC. 

TRC. 

X. 

GAF. 



GAF. 

GAF. 
.WP. 
TRC. 
F.K. 
CTN. 
CTN. 
ABB. 
ABB. 
i PD 



PD. 

SDH. 

TRC. 

DUP. 

ACS. 

AAP, GAF, TRC. 

ATL. 

SDW. 

ACY, DUP. TRC. 

ACY. 

BPC. 

TRC. 

BPC. 

ABB. 

ABB. 

KPT. 

DUP. 

DUP. 

ACY, MAY, TRC. 

DUP, r!ON. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 51 



l-Chloro-3-nitrobenzene (Qiloro-m-nitrobenzene) 

l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene) 

2-Chloro-5-nitrobenzenesulfuric acid 

*4-Chloro-3-nitrobenzene sulfonamide 

4-Chloro-3-nitrobenzenesulfonanilide 

2-Chloro-5-nitrobenzenesulfonic acid 

2-Chloro-5-ni trobenzenesulfonic acid, sodium salt 

4-Chloro-3-nitrobenzenesulfonic acid 

4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-4-nitrobenzoic acid 

2-Chloro-5-nitrobenzoic acid 

2~Chloro-5-nitrophenyl methyl sulfone 

4-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-4-nitrotoluene 

4-Chloro-2-nitrotoluene 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazine 

(p-Chlorophenyl)acetonitrile 

4-Chloro-a-phenyl-o-cresol 

4-Chloro-o-phenylenediamine 

2-Chloro-l , 3-phenylenedi amine- S- sulfonic acid 

2,2 '- fn-Chlorophenylimino)diethanol 

2,2 ' - (m-Chlorophenyl imino)diethanol , diacetate ester 

2- (o-Chlorophenyl)-2- (methylamine)cyclohexanone 

3- to-Chlorophenyl) -S-methyl-4-isoxazolecarboxylic acid , 
acid chloride. 

1- (o-Chloropl"ienyi)-3-methyl-2-pyrazolin-5-one- 

1- (p-Chlorophenyl}-3-methyl-2-pyrazolin-S-one 

p-Chlorophenyl methyl sulfone 

2-Chloro-4-phenylphenol 

o-Chlorophenylphthalimide, potassium salt 

4-Chlorophthalic acid 

3-Chloropropenylbenzene CCinnamyl chloride-) 

1- (3-Chloropropyl)-4-methylpiperazine 

7-Chloro-4-quinolinol 

4-Chlororesorcinol 

5-Chlorosal icy aldehyde 

Chlorostyrene, mono 

2-Chloro-5-sulfamoylbenzoic acid 

2-Chlorothiophene 

p-Chlorothiophenol 

m-Chlorotoluene 

o-Chlorotoluene 

p-Chlorotoluene 

*a-Chlorotoluene (Benzyl chloride) 

3-Chloro-o-toluidine [NHj=l] 

3-Chloro-p-toluidine [NHj=l] 

4-Chloro-o-toluidine [NHj=l] and hydrochloride 

5-Chloro-o-toluidine [NH =1] (4-Chloro-o-toluidine 
[CH3 = 1]). 

5-Chloro-o-toluidine hydrochloride [Nllj = l] 

N- [ (5 -ailoro-o-tolyl)azo]sar cosine 



DUP. 






DUP, 


MON. 




TRC. 






MP, 


DUP, 


GAF, ICC, TRC 


TRC. 






ACS, 


TRC. 




DUP. 






ACS, 


GAF, 


TRC. 


AAP, 


SDC. 




RSA, 


SAL. 




TRC. 






TRC. 






TRC. 






DUP. 






DUP. 






DOW, 


MON. 




DOW, 


MON. 




SK. 






OPC, 


UOP. 




flON. 






FMT. 






SDC. 






TCH. 






SDC. 







HST. 




DUP 


HST, TRC 


TRC. 




DOW. 




PD. 




sw. 




SDW. 




SK. 




SDW. 




AAP, 


GAF. 


EK. 




DOW. 




TRC. 




FIS. 




SFA. 




HK, 


HN. 


UN. 




UN. 




BPC, 


MON, VEL 


DUP. 




DUP. 




BUC. 




DUP. 




ATL, 


SDH. 


ALL, 


ATL. 



CYCLIC INTERMEDIATES 
TABLE 2, --Cyclic intermediates for which U,S, production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED 




Manufacturers' identification codes 
(according to list in table 5) 



l-(6-Chloro-o-tolyl)-3-nethyl-2-pyrazolin-5-one 

[ (4- Chloro-o-tolyl)thio] acetic acid 

4-Chloro-a,a,a-trifluoro-3-nitrotoluene 

6-Chloro-a,a,a-trif luoro-m-toluidine 

Chlorotriphenylme thane 

a-Chloro-p- xylene 

2 -Chloro-p- xylene 

4-Chloro-2,5-xylenesulfonyl chloride 

Cholesteryl nonanoate 

Cholesteryl oleyl carbonate (Mesomorphic) 

Cholestyramine, pure 

Cholic acid 

•Cinnamoyl chloride 

*Cresols : ^ 

m-Cresol 

*o-Cresol : 

From coal tar 

From petroleum 

Synthetic 

p-Cresol 

Cresols , mixed: ' 
*(m,p)-Cresol ; 

From coal tar 

From petroleum 

(o,m,p)-Cresol : 

From coal tar 

From petroleum 

Other 

*Cresylic acid, refined:' 

From coal tar 

From petroleum 

Synthetic 

Cryptocyanine 

*Cumene 

2-[p-(Cyanoacetamido)nhenyl]-6-methyl-7-ben:othia:ole- 
sulfonic acid. 

Cyanoacetic acid, 2-ethylhexyl ester 

p-Cyanobenzaldehyde 

4- [(2-Cyanoethyl)ethylamino]-o-tolualdehyde 

P- [ (2-Cyanoethyl)methylamino]benzaldehyde 

:i-Cyano-B-methylcinnamic acid, ethyl ester 

*Cyclohexane — 

1 ,2-Cyclohexanedicarboxylic anhydride 

1 ,3-Cyclohexanedione 

Cyclohexanol 

*Cyclohexanone 

Cyclohexanone oxime 

Cyclohexene 

3-Cyclohexene-l-carboxaldehyde-l,2,3,6-tetrahydro- 
benzaldehyde. 



HST. 






(lAF. 






PCIV. 






HK, 


PCW. 




EK. 






BPC. 






DUP. 






ACS. 






EK. 






EK. 






MRK. 






WIL. 






ARS, 


imp, 


X. 


KPT, 


PRD. 




KPT. 






MER, 


fJPC, 


PRD, 


KPT, 


PIT. 




HPC, 


SW. 




Acr, 


KPT. 




HER, 


NPC, 


PRD. 


ACP 


KPT. 




NPC 






NPC 






KPT 






MER 


NPC, 


PRD. 


PIT 







ASH, CLK, CSP, DOW, GOC, MOC, MON, SIIC, SKO, SNT, 

SOC, TX, UCC. 
DUP. 



DUP, GAF. 
DUP, GAF. 

.A.Sll, CSD, EN.I, GOC, GRS, PI.C, PPR, SWC, TX , UOC. 

ACS . 

PD. 

ACP, CNP, DUP, HON. 

ACP, CEL, CNP, DBC, DUP, MON. 

ACP, CNP. 

EK, PLC, USR. 

UCC. 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2.— Cyclic intermediates for which U,S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



rianuf acturers ' identification codes 
(according to list in table 3) 



4-Cyclohexene- 1,2-dicarboximide 

4-Cyclohexene- 1 ,2-dicarboxylic anhydride 

Cyclohexene oxide 

"Cyclohexylamine 

N^-Cyclohexylmetanilamide 

Cyclohexyl-2-Tiropanone 

N-Cyclohexyltaurine, sodium salt 

Cy c 1 open tadienyl iron 

Cyclopentanol 

Cyclopentene 

p-Cymene 

De cab romobi phenyl 

Deoxycholic acid 

Diacenaphtho[l,2-j : 1 ,2 ' -il]f luoranthene (Decacvclene)-- 

l,5Cand 1,8) -Diacetamidoanthraquinone 

l,5-Diacetaiiiido-4,8-dibromoanthraquinone 

3,5-Diacetamido-2,4,6-triiodobenzoic acid 

3- (Diallylcarb;moyl)-l,2,2-trimethylcyclopentan- 

carboxylic acid. 

N^N^- Dial lylmel amine 

Diallylchlorendate 

*1 ,4-Diaminoanthraqiiinone 

1 ,5-Diaininoanthraquinone 

l,5(and 1,8) -Diaminoanthraquinone 

*2,6-Diaminoanthraquinone 

3,3' -Diaminobenzani lide 

3,4-Diaminobenzanilide 

2 ,4-Diaminobenzenesulfonic acid [SO H=l] 

2,5-Diaminobenzenesulfonic acid [50^11=1] 

3,5-Diaminobenzoic acid dihydrochloride 

4,4 ' -Diamino- 1,1' -bianthraquinone-3,3' -di sulfonic 

acid, disodium salts. 

4,4'-Diamino-2 ,2 '-biphenyldi sulfonic acid 

1 ,3-Daiminocyclohexane 

3, 7- Diamino- 4, 6 -dibenzothiophenedi sulfonic acid, 

5,5-dioxide, disodium salt. 

1 ,4- Diamino- 2 ,3-dichloroanthraquinone 

*1 ,4- Diamino- 2 ,3-dihydroanthraquinone 

4, 8- Diamino- 9,10- dlhydro- 1,5- dihydroxy -9,10 -dioxo- 2,6- 

anthracenedisulfonic acid. 
1 ,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedi- 

carboximide. 

1 ,5-Diamino-4,8-dihydroxyanthraquinone 

1 ,8-Diamino-4,5-dihydroxyanthraquinone 

4,5-Diamino-l ,8-dihydroxyanthraquinone 

1,4- Diamino- 5 -nitroanthraquinone 

2 ,4-Diamino-6-phenyl-s-triazine 

2,6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic acid 

3,5-Diamino-p-toluenesulfonic acid [Sn^H^l] 

3. 5- Diamino- 2 ,4 ,6-triiodobenzoic acid 

1,4: 3,6-Dianhydroglucitol 

2,5-Dianilinoterephthalic acid 

Diary Iguanidine 



SFC. 

PIT. 

USR. 

ABB, HON RBC, VGC. 

CMC. 

niv, LIL. 

r,AF. 

ARA. 

LIL. 

ARA, PLC. 

ACS, HN, HPC. 



IVIL. 






SDC. 






AAP. 






TRC. 






SDW . 






HTlT. 






ACY. 






SAR. 






CMC, 


DUP, 


GAF, SDC 


GAF, 


TRC. 




AAP, 


TRC. 




AAP, 


GAF, 


TRC. 


TRC. 






X. 






DUP, 
TRC. 


TRC. 





ACS, 


ACY 


DUP. 




ACY. 




CMG, 


DUP 


AAP, 
TRC. 


ACY 



VPC. 

,\AP. 

ICI. 

GAF. 

RU, 

NEP, 

ACY, 

GAF. 

SDW. 

ICI. 

X, X 

DUP. 



ATL, DUP, GAF,HSH , ICC, MAY, TRC. 



VEL. 
RIL, 
CGY, GAF, SDH, TRC, VPC. 



CYCLIC INTERflEDIATES 
TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



p-Diazo-N,N- dimethyl aniline- 1- amino- 8-naphthol- 3-siil- 
fonate-6-sulfonic acid, sodium salt. 

1,5-Dibenzamidoanthraquinone 

6, ll-Dibenzajiiido-16H-dinaphtho[2,3-a,2' ,3' -i] carbazole- 
5,10,15,17-tetrone. 

*4,5'-Dibenzamido-l ,1 '-iminodianthraquinone 

1,5-Dibenzoylnaphthalene 

2-(N,N-Dibenzyl)amino-4-acetamidoanisole 

Dibenzylazodicarboxylate 

N,N' -Dibenzyle thy lenedi amine 

N,N'-Dibenzylethylenediamine di acetate 

N,N'-Dibenzylidenetoluene-a,a-di amine 

5' ,4 ' -Dibenzyloxy-2-bromobutyrophenone 

3,4-Dibenzyloxybutyrophenone 

2 , 4 ' - Dib romoace tophenone 

*3,9-Dibromo-7H-benz[de]anthracen-7-one 

m-Dibromobenzene 

p-Dibromobenzene 

4,4'-Dibromobenzil 

ar-Dibromoethylbenzene 

2,6-Dibromo-4-nitroaniline 

2 ,6-Dibromo-4-ni trophenol 

a ,a-Dibromo-p-nitrotoluene 

5 , 13-Dibromo-8 , 16-pyranthrenedione 

3,5-Dibromo-3' -tri f luoTOmethylsalicylani lide 

p-Dibutoxybenzene (DBB) 

2,5-Dibutoxy-4-morpholinobenzenediazonium sulfate 

1 ,1 '-Di-n-butyldicyclopentadienyliron 

2,6-Di-tert-butyl-4-nonylphenol 

Dibutyltin bis(cyclohexylmaleate) 

3',4'-Dichloroacetophenone 

2,4-Dichloroaniline 

3,4-Dichloroaniline 

2,5-Dichloroaniline and hydrochloride [NH2=1] 

3-(2,4-Dichloroanilino)-l-(2,4,6-trichlorophenyl)-2- 
pyrazolin-5-one . 

1 ,5-Dichloroanthraquinone 

1 ,5 (and 1 ,8) -Dichloroanthraquinone 

Dichlorobenzanthrone 

m-Dichlorobenzene 

*o-Dichlorobenzene 

oCand p)-Dichlorobenzene 

*p-Dichlorobenzene 

4, 6 -Dichloro-m-benzenedi sulfonamide 

2,S-Dichlorobenzenesulfonyl chloride 

*3,3'-Dichlorobenzidine base and salts 

2,2'-DichIorobenzil 

2 ,4-Dichlorobenzoic acid 

4,7-Dichlorobenzo[b]thiophen-3(2H)-one 

2,4-Dichlorobenzoyl chloride 

Dichlorobenzyl chloride- 

4,4- C2,6-Dichlorobenzylidene)di-2,6-xylidine 

4,5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l ,2-dicarbo- 
nitrile. 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

2-C5,8-Dichloro-l-hydroxy-2-naphthylazol-l-phenol-4- 
sulfon amide. 



Manufacturers' identification code 
(according to list in table 3) 



TRC. 
TCI. 

ACY, GAF, MAY, TRC. 

GAP, TRC, VPC. 

SDC. 

KF, WTL. 

hfYT. 

mT. 

SDH. 

SDW. 

SDW. 

EK. 

DUP, GAF, MAY, TRC. 

EK. 

DOW. 

NES. 

DOW. 

SDC. 

SW. 

DUP. 

ICI. 

PCW. 

ALL. 

ALL. 

ARA. 

GAF. 

x. 

EK. 



DUP, MON. 
BUG, DUP. 



TRC. 

AAP. 

ACY. 

EK. 

ACS, 

DVC. 

ACS, 

ABB. 

ACS. 

ACS, 

flTO. 

HN. 



BPC. 
DUP. 
ARA. 

DCC. 
EK. 
TRC . 



DOW, DUP, MON, NEV, PPG, SCC, SVT. 
DOW. DVC, MON, PPG, SCC, SVT. 

CIVN, LAK, UPJ. 



SY'ITHETIC ORGAfllC CIIErilCALS, 197? 
TABLE 2. --Cyclic intermediates for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
faccording to list in table 3) 



5 ,14-Dichloroisoviolanthrone 

Di (chloromethyl)diphenyl oxide 

2,5-Dichloro-4- (3-niethyl-5-oxo-2-pyrazolin-l-yl)ben:ene 

sulfonic acid. 

2,6-Dichloro-4-ni troani line 

1 ,2-Dichloro-4-nitrobenzene 

1 , 4- Dichloro- 2 -nitrobenzene (Nitro-p-dichlorobenzene) 

2 ,4-Dichlorophenol 

3,4-Dichlorphenyl isocyanate 

3- (2' ,6'-Dichlorophenyl)-5-iriethyl-isoxazole-4-carbonyl 

chloride . 

[ (2,5-Dichlorophenyl)thio]acetic acid 

2,6-Dichloropyrazine 

5,6-Dichloropyridazine 

4,7-Dichloroquinoline 

2 ,3-Dichloroquinoxaline 

2,5-Dichlorosulfanilic acid [Sn3H=l] 

2,5-Dichloro-4-sulfobenzenediazonium sulfate 

p,a-Dichlorotoluene 

a,a-Dichlorotoluene (Benzal chloride) 

Di eye lohexy lamina 

N,N'-3-Dicyclohexy 1-2- thiourea 

*Dicyclopentadiene (includes cyclopentadiene) 

Dicyclopentadiene dioxide 

Didodecylbenzene 

3-Diethanolainine-4-ethoxyacetanilide 

p-Diethanolaminomethoxyacetanilide 

p-Diethoxybenzene 

p- (Diethylaniino)benzaldehyde 

p- (Diethylamino)benzenediazonium chloride, zinc chloride 

salt. 

3'- [2- (Diethylamino)ethyl]-4'-hydroxyacetanilide 

a- [ (2- Diethyl amino) ethyl ]-a-phenylcyclohexanemethanol , 

hydrochloride . 

7' -Diethylamino-4-methylcoumarin 

m- (Diethylamino)phenol (N ,N-Diethyl-3-aminophenol) 

3- [(4' -N, N- Die thy 1 amino) phenylazo]-lH-l ,2 ,4-triazole 

3-(Diethylamino)propiophenone 

4- (Die thy 1 amino) -o-tolualdehyde 

*N,N- Diethyl aniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

N, N - Di e thy Icyclohexyl amine 

a,a'-Diethyl-4 ,4 '-dimethoxystilbene 

N,N-Diethylmetanilic acid 

n' ,n' -Diethyl- 4-methoxymetanilamide 

N,N-Diethyl-4-nitroso-m-anisidine hydrochloride 

N, N- Die thy 1-4-nitroso-m-pheneti dine 

N, N - Di e thy 1-m-pheneti dine 

N,N-Diethyl-p-phenylenedi amine oxalate 

N ,N-Diethyl-m-toluidine 

N,N-Diethyl-p-toluidine 

Di f ur f ury 1 i di nepent ae rythri tol 

10,ll-Dihydro-5H-dibenzo[a,d]cycloheptan-5-one 



MON, VGC. 

HOC, MON, UCC, VEL. 



ICI. 
BPC. 
DCC, HST, TRC. 

CWN, SW. 

DlIP, MON. 
DIIP. 

DOW, MON. 

nic. 
nic. 

ACS. 

ACY. 

ACY. 

PD, SDW. 

EK. 

DUP. 

TRC. 

HN. 

BPC. 

ABB, 

ABB. 

EN J, 

VEL. 

cn. 

HST. 

H.ST. 

ALL, GAP. 

ACS, DUP, TRC. 

HST. 

PD. 
ACY. 

CAF. 

ACY. 

TRC. 

ACY. 

DUP. 

ACS, ACY, DSC, 

DUP. 

DOW, KPP. 

DUP. 

LIL. 

DUP. 

PCW. 

DUP. 

GAP. 

GAF. 

EK. 

DUP. 

RSA. 

SDC. 

LIL. 



CYCLIC INTERMEDIATES 
TABLE 2, --Cyclic intfirmediates for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



9 , 10-Dihydro- 1 , 4-dihydroxy-9 , Id-dioxo- 2- anthracene - 

sulfonic acid (2-Quinizarinsulfonic acid). 
9, 10-Dihydro- 9, 10 -dioxo- 1 ,5- anthracenedi sulfonic aci 



9,10-Dihvdro-9 



disodium salt. 



9,10-Dihydro-9 



disulfonic acid and salt 



10- dioxo- 1,5- anthracenedi sulfonic acid. 



10- dioxo- 1,5 (and l,f 



10- dioxo- 1 , 8- anthracene disulfonic acid. 



10 -dioxo- 2 ,6- anthracenedi sulfonic acid 



9,10-Dihydro-9 

potassium sa 
*9, 10-Dihydro- 9 

and salt. 
*9,10-Dihydro-9,10-dioxo- 1-anthracenesulfonic acid and 

salt (Gold salt). 
9,10-Dihydro-9, lO-dioxo-2-anthracenesulfonic acid and 

salt (Silver salt) . 
9,10-Dihydro-9,10-dioxo-2,7-anthraquinonedisulfonic 

acid. 
[Dihydrogen 3,3' ' -phthalocyaninedisulfonate(2-) ]copper- 
10, ll-Dihydro-5- [3- (methylaminopropyl) ]-5H-dibenzo[a,d] 

cyclohepten-5-ol . 
9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic 

acid. 

d-Dihydrophenylglycine 

*l,4-Dihydroxyanthraquinone (Quinizarin) 

1,5-Dihydroxyanthraquinone (Anthrarufin) 

1 ,5 (and 1,8) -Di hydroxy an thraquin one 

*l,8-Dihydroxyanthraquinone (Chrysazin) 

2,6-Dihydroxyanthraquinone (Anthraf lavic acid) 

2,4-Dihydroxybenzaldehyde 

2, 5-Dihydroxybenoic acid 

3,6-Dihydroxybenzonorbornane 

2,4-Dihydroxybenzophenone 

2,4-Dihydroxy-3,3-dimethylbutyrolactone 

l,5-Dihydroxy-4,8-dinitroanthraquinone 

*l,8-Dihydroxy-4,5-dinitroanthraquinone r4,5-Dinitro- 

chrysazin) . 
4,5-Dihydroxy-2 ,7-naphthalenedisulfonic acid (Chrono- 
tropic acid) . 

6 ,7-Dihydroxy-2-naphthalenesulfonic acid 

4 , 5- Dihydroxy- 3- (p- sulf opheny lazo) - 2 , 7-n aphtha lene- 

disulfonic acid, trisodium salt. 
* 16, 17- Dihydroxy viol an throne (Dihydroxydibenzanthrone)-- 

m-Diiodobenzene 

3,5-Diiodosalicylic acid, lithium salt 

Di i s opr opy Ibenzene 



MP, HSH, PAT. 



TRC. 
GAF, 



GAP, 


TRC. 






A'\P, 


GAF, 


TRC. 




AAP, 


ACY, 


MAY, 


TRC 


DUP. 








AAP. 








ICl. 








LIL. 









AAP, 


ACY, 


DUP, 


GAF, 


HSH, 


ICC, 


MAY, 


TRC 


DUP, 


GAF, 


TRC. 












ACY, 


TRC. 














CHG , 


GAF, 


TRC. 












GAF, 


TRC. 














EK. 
















ARS. 
















EK. 
















DUP, 


GAF. 














PD. 
TRC, 


VPC. 














DUP, 


GAF, 


ICl, 


TRC. 











ACY, DUP, ICl, MAY. 



EK. 
DOW. 



SY'lTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



2 ' ,5 '- Dime thoxy ace toacetani lide 

2, 5- Dime thoxy aniline 

1 ,5 (and 1,8) -Dimethoxyanthraquinone 

2, 5- Dime thoxybenz aldehyde 

m- D ime th oxyben zene 

3,3'-Dimethoxybenzidine (o-Dianisidine) 

3,3'-Dimethoxybenzidine hydrochloride 

2 ,6-Dimethoxybenzoic acid 

N,N'- [(3,3'-Dimethoxy-4,4'-biphenylylene)bis(azo) ]bis 
(N-methyltaurine) . 

2,5-Dimethoxy-B-methyl-S-nitrostyrene 

2,5-Diriethoxy-a-methylphenethylamine 

2,5-Dimethoxy-4'-nitrostilbene 

4- (2' ,5 '-Dimethoxyphenethyl) aniline hydrochloride 

(3,4-Dimethoxyphenyl) acetic acid 

1- (3,4 ' -Dimethox>'phenyl)-2-aminopropane 

2,5-Diraethoxytetrahydrofuran 

2,5-Dimethoxytoluene 

16, 17- Dime thoxy violanthrone 

p- (Dime thy lamino) ben zaldehyde 

p-Dimethylaminobenzenediazonium chloride, zinc cliloride 
salt. 

m- (Dime thy lamino) benzoic acid 

5- (p- Dime thy laminobenzylidenejrhodanine 

6-Dimethylamino-2- [2- (2,5-dimethyl-l-phenyl-3-pyrryl')- 
vinyl]-l-methyl-l-quinolinium methyl sulfate. 

m- (Dime thy lamino) phenol 

2,6-Dimethyl-4-aminophenol 

*N,N-Di methyl aniline 

7, 12- Dime thy Ibenz [a] anthracene 

2,5-Dimethylbenzenesulfonic acid 

3,3'-Dimethylbenzidine (o-Tolidine) 

3,3' - Dime thylbenzi dine hydrochloride 

*N,N- Dime thy Ibenzyl amine 

a,a-Dimethylbenzyl hydroperoxide 

*2,2'-Dimethyl-l ,1 '-bianthraquinone 

N,N-Dimethylcyclohexylamine 

5,5-Dimethylhydantoin 

1 ,l-Dimethyl-3- (m-hydroxyphenyl)urea 

2, 3- Dimethyl indole 

D,L-cis , trans -2, 2- Dimethyl -3- isobutenylcyc lop ropane- 

l-carboxylic acid, ethyl ester. 
2 ,5-Dimethyl-4(2)-morpholinylmethylphenol , hydro- 
chloride. 

N,N-Dimethyl-l-n aph thy 1 amine 

N,N- Dime thy 1-p-nitrosoani line 

6,6-Dimethyl-2-norpinene-2-ethanol 

2,4-Dimethylphenol 

N, N- Dime thy 1-p-phenylazoani line 

N,N- Dime thy 1-p-phenylenediamine 



HST. 

EKT, PCW. 
TRC. 

Cmi, UPJ. 
ACY, ARS. 
SDH. 
CIVN. 
ARS. 
GAF. 



PD, X. 

UPJ. 

LIL. 

LIL. 

HEX. 

EK. 

ICI. 

BJL, GAF. 



HST. 



ACS, ACY, DSC, DUP, SW . 



EK. 






CIVN. 






cm. 


EK. 




ARS, 


MLS, 


RH, SW. 


CLK. 






ACY, 


DUP, 


GAF, TRC 


ABB, 


DUP. 




GLY. 






CIWJ. 






DUP. 






BPC. 







IDC. 

EK. 

ACY, 

RDA. 

EK. 

EK. 

EKT. 



CYCLIC INTFR'lEDIATES 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1972--CoNT INUED 




Manufacturers' identification codes 
(according to list in table 3) 



N,N- Dime thy l-m-phenylenedi amine dihydrochloride 

N,N- Dime thy 1-p-phenylenedi amine dihydrochloride 

N,N- Dime thy 1-p-phenylenedi amine monohydrochloride 

N,N- Dime thy l-p-phenylenedi amine sulfate 

1,4- Dime thy Ipiperazine 

N,N-Dimethylsulfanilic acid 

Dime thy 1 - 5- sulfoi soph thai ate 

N,N-Dime thy 1-o-tolui dine 

N, N- Dime thy 1-m-tolui dine 

N,N-Dimethyl-p-toluidine 

2,4-Dinitroacetani lide 

2,4-Dinitroaniline 

p- (2,4-Dinitroanilino)phenol 

1,5 (and 1 ,8)-Dinitroanthraquinone 

N,N'- (2,4-Dinitro-l ,5-anthraquinonylene)dioxamic acid-- 

3,3' -Dinitrobenzanilide 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic acid 

2,4-Dinitrobenzenesulfonic acid, sodium salt 

3,S-Dinitrobenzoic acid 

3,5-Dinitrobenzoyl chloride 

10, 10' -Dinitro [3,3 '-bi-7H-benz[de] anthracene] -7,7' - 
dione. 

Dinitrocaprylphenol 

2 , 4- Din i t rocumene 

l-(3,5-Dinitro-2-hydroxphenylazo)-2-naphthol 

2,6-Dinitro-4-isopropylphenol 

2,4-Dinitrophenol , tech 

3,5-Dinitrosalicylic acid 

*4,4'-Dinitrostilbene-2,2 'di sulfonic acid 

2 ,4-Dinitrotoluene 

*2,4(and 2 ,6)-Dinitrotoluene 

3,5-Dinitro-p-toluenesulfonic acid 

Dinonylphenol 

Di-tert-pentylphenol 

Di-tert-amylphenoxyacetyl chloride 

2-(2,4-Di-tert-pentylphenoxy)butyric acid, tech 

1 ,5-Diphenoxyanthraquinone 

Diphenylacetoni tri le, tech 

*Diphenylamine 

2,8-Diphenylanthra[l,2-d:6,5-d']bisthiazole-6,12-dione- 

2,5-Diphenyl-p-benzoquinone 

Diphenyldecyl phosphite 

2 ,2'-Diphenyl-4-dimethylamine 

N,N' -Diphenylethylenedi amine 

Diphenylme thane 

2,5-Diphenyloxazole 

4,7-Diphenyl-l ,10-phenanthroline 

1, 3- Di phenyl-! ,3-propanedione 

4,4 '-Dithiodiani line 

2,2'-Dithiodibenzoic acid 

*l,4-Di-p-toIuidinoanthraquinone 

1,8-Di-p-toluidinoanthraquinone 

2,5-Di-p-toluidinoterephthalic acid 

p-Ditolylmercapto-2 ,5-diethoxybenzenediazonium chloridt 
zinc chloride salt. 



EK. 

.TCC. 

AAP. 



EK, 


RSA. 








SDC. 










AAP, 


SDC. 








GAP, 


SDC. 








AAP, 


TRC. 








TRC. 










TRC. 










DUP. 










EK, 


TRC. 








EK, 


NES. 








SAL. 










EK. 










DUP, 


MAY. 








RH. 










DUP. 










TRC. 










X. 










AAP, 


SDC. 








EK, 


SAL. 








ACY, 


CGY, 


DUP, 


GAP, HN, SDH, 


TRC 


ACS, 


DUP, 


RUC. 






AIP, 


DUP, 


MOB, 


UCC. 




GAP. 










GAP 


JCC. 








PAS. 










EK. 










EK. 










VPC. 










FIS 










ACY 


DUP, 


ORO, 


RUC, USR. 




GAP 










EK. 










X. 










LIL 










RPC 










PD. 










ARA 


EK. 








EK. 










EK. 










SDC 










LIL 


SW. 








ACS 


ATL, 


GAP 


TRC. 




ICI 











SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



*Divinylben2ene 

Uodecylbenzene. (See Alkylbenzenes . ) 

Dodecylbenzyl chloride 

Dodecylmethylbenzyl chloride 

p-Dodecylphenol 

2,2 '- (Ethanediylidenedinitrilo)diphenol 

l,2-Epoxy-3-(2-biphenylyl)propane 

p-EthoxybeHzaldehyde 

o- E thoxyben zoic acid 

p(p- (Ethoxybenzy li dene) amino] ben zonit rile 

N- (p-Ethoxybenzyli dene) -p-butyl aniline 

l-(4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3-inethyl- 
isoquinidine (Dioxyline base). 

2-Ethoxy-l-naphthoyl chloride 

m-Ethoxyphenol 

4-Ethoxy-o-phenylenediamine 

N'- (6- Ethoxy-3-pyridazinyl) sulfanilamide 

Ethyl -in- aminobenzoate methanesulfonate 

3-(Ethylamino)-p-cresol 

a- (N-Ethylamino)-p-toluenesulfonamide 

3- (Ethylamino)-p-toluenesulfonic acid [S03H=1] 

*N~ Ethyl aniline, refined 

*2-(N-Ethyanilino)ethanol 

[2-(N-Ethylanilino)ethyl]trimethylammonium chloride 

3- (N- E thy lanilino)propionit rile 

a-(N-Ethylanilino)-m-toluenesulfonic acid 

a- (N-Ethylanilino)-p-toluenesulfonic acid 

2-Ethylanthraquinone 

*Ethylbenzene 

Ethylbenzyl chloride 

2- (N-Ethyl-N-S-cyanoethyl)-4-acetaminoanisole 

N-Ethylcyclohexylamine 

1-Ethylcytosine 

3,3'-Ethylenedioxydiphenol 

Ethylene glycol dibenzenesulfonate 

3- Ethyl- 2- [5- (3-ethyl-2-benzothiazolinylidene) -1 , 

3-pentadienyl] -benzothiazolium iodide. 

Ethyl hydrocaffeate 

2- [N-Ethyl-p- [(6-methoxy-2-benzothiazolyl )azo]anilino] 

ethanol . 

N-Ethyl-N- (2-methylsulfonamidoethyl)-m-toluidine 

N-Ethyl- 1-naph thy 1 amine 

9-Ethyl-3-nitrocarbazole 

a-Ethyl-3-nitrocinnamic acid 

N- [2- (N-Ethyl-4-nitroso-m-toluidino)ethyl]methane- 

sulfonamide. 

Ethylphenylmalonic acid, diethylester 

*N-Ethyl-N-phenylbenzylamine 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP) — 

1-Ethylpiperidine 

6-Ethyl-l , 2,3, 4-tetrahydro- 1,1,4, 4-tetramethyl- 

naphthalene . 

N-Ethyl-p-toluenesulfonamide 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

2- (N-Ethyl-m-toluidino) ethanol 



DOW, FG, KPP. 



GAP, 

EK. 

NES. 



ACY. 
EK. 



BJL. 

TRC. 

ACY. 

EK. 

DUP. 

AAP. 

DUP. 

ACS, ACY, DUP. 

DUP, EKT, TCH. 

DUP. 

TCH. 

GAP, SDH, WJ. 

ACS, TRC. 

DUP. 

ATR, CSD, DOW, EN.7 , FG , KPP, MCB, MON , SHC, SKC, SNT, 

Snc, STY, TOC, UCC. 
BPC. 
SDC. 

ABB, USR. 
PD. 
IDC. 
NES. 



TRC. 

WAY. 

DSC, DUP. 
SDC. 
SDW. 
WAY. 

BPC, HAL. 

ACS, DUP, SDH. 

UCC. 

RIL. 

GIV. 

EK. 
DUP. 
DUP. 
TCH. 



CYCLIC INTERHEDIATES 
TAELE 2, --Cyclic intermediates for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
{according to list in table 3) 



3- (N-Ethyl-m-toluidino)propionitri le 

a- (N-Ethyl-m-toluidino) -m- toluene sulfonic acid 

1-Ethynyl-l-cyclohexanol 

Fluorescein (3' ,6 '-Dihydroxyfluoran) 

o-Fluoroben2oic acid 

l-Fluoro-2,4-dinitrobenzene 

d- 2- Formami do- 1 -phenyl - 1 , 3-propanedi o 1 

4-Formyl-m-benzenedisulfonic acid 

o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde) 

Furan 

Furfuryl alcohol 

Fur furyl amine 

N-Glycolylarsanilic acid, sodium salt 

Hexabromobenzene 

Hexabromobiphenyl 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

1,4 ,5,6,7,7-Hexachloro-5-norbornene-2 ,3-dicarboxylic 

acid. 
1 ,4,5,6,7,7-Hexachloro-5-norbomene-2 ,3-dicarbox>'lic 

anhydride . 

Hexadecachlorophthalocyanine copper complex 

Hexafluorobenzene 

1,2,3,4,5 ,6-Hexahydro-8-hydroxy-cis-6,ll-dimethyl-2,6- 

methano-2-benzazocine . 
Hexahydro- l-methyl-4-phenyl-lH-azepine-4-carbonitrile-- 

Hexamethylenimine 

Hippuric acid 

p-Hydrazinobenzenesulfonic acid 

2-Hydrazinobenzothiazole 

Hydroquinone, di (6-hydroxyethyl) ether 

*Hydroquinone , tech 

6-Hydroxy-p-acetophenetidide 

3 ' - Hydroxy ace t ophen one 

4* -Hydroxy ace tophenone 

6'-Hydroxy-m-acetotoluidide 

1- (p-Hydroxyanilino)-4-naphthol 

p-Hydroxybenzaldehyde 

p-Hydroxybenzenesulfonic acid 

p-Hydroxybenzoic acid 

3 '-Hydroxy- 2- (N-benzy 1-N-methyl amino) acetophen one 

4-Hydroxycoumarin 

2-Hydroxy-3,5-diiodobenzoic acid 

3- [N- (2-Hydroxyethyl)anilino]propionitrile, acetate 

3- [N-(2-Hydroxyethyl)anilino]propionitrile, benzoate 

N- (B-Hydroxyethyl)-2 ,4-dihydroxybenzamide 

N- fB-Hydroxyethyl)-2,5-dihydroxybenzamide 

N- (6-Hydroxyethyl)-3,5-dihydroxybenzamide 

3- [N- (2-Hydroxyethyl)-m-toluidino]propionitrile 

3-Hydroxy-N- (2-hydroxyethyl)-2-naphthamide 

N- [7-Hydroxy-8- [2-hydroxy-5- (methylsulfamoylphenyUazo] 

l-naphthyl]acetamide. 
6 ' -Hydroxy-5 '- [ C2-hydroxy-5-nitrophenyl) azo] -m-aceto- 

toluidide. 
N- [7-Hydroxy-8- [ (2-hydroxy-S-nitrophenyl) azol-l- 
naphthyllacetamide. 
7-Hydroxy-8- [ (4 ' - [ (p-hydroxyphenyl) azo] -3, 3' -dimethyl - 

4-biphenylyl)azo]-l ,3-naphthalenedi sulfonic acid. 



DUP, TCH. 

GAF. 

EKT. 

ICC. 

FIN. 

EK. 

PD. 

GAF. 

SDH. 

QKO. 

QKO. 

MLS. 

SDW. 

MCH, NES. 

MCH. 

DVC. 

MK, VEL. 

HK. 

VEL. 

TRC. 
WHC. 
SDW. 

IVYT. 

CEL. 

BPC. 

GAF, STG, WJ. 

FK. 

CTN. 

CRS, DA, EKT. 

GAF. 

CTN, SDH. 

BJL. 

TRC. 

TRC. 

DOW. 

DOW, PRD, UPF. 

HN. 

SDW. 

ABB. 

EK. 

TCH. 

DUP, x. 

IDC. 

ARS. 

IDC. 

TCH. 

IDC. 

TRC. 

TRC. 

TRC. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



4-Hydroxy-4-isopropylmetanilamido 

4- Hydroxymet anil amide 

4-Hydroxymetanilide 

3' -Hydroxy- 2- (raethy 1 amino) ace tophenone 

*3-Hydroxy-2-methylcinchoninic acid 

4-Hydroxy-N'-raethylmet anil amide 

5-Hydroxymethyl-2-norbornene 

N- (Hydroxymethyl)phthalimide 

3-Hydroxy-N- (3-N-morpholinopropyl)-2-naphthajnide 

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt- 
y-Hydro xy-1 , 5-naphthalenedisulfoni c acid 

7-Hydroxy-l ,3-naphthalenedisulfonic acid, disodium salt- 

4-Hydroxy-2-naphthalenesulfonamide 

4-Hydroxy-l-naphthalenesulfonic acid 

6-Hydroxy-2-naphthalenesulfonic acid 

8-Hydroxy-l-naphthalenesulfonic acid 

4-Hydroxy-2-naphthalenesulfonic acid, benzenesulfonate, 
sodium salt. 

*6-Hydroxy-2-naphthalenesulfonic acid, sodium salt 

8-Hydroxy-l-naphthalenesulfonic acid, y-sulfone 

3-Hydroxy-2-naphthanilide (Naphthol AS) 

l-Hydroxy-2-naphthoic acid, methyl ester 

3-Hydroxy-2-naphthoic acid (B.O.N.) 

5-Hydroxy-2-naphthoic acid, methyl ester 

3-Hydroxy-2-naphtho-o-toluidide 

N- (2- Hydroxy- 1-naph thy l)acet amide 

N- (7-Hydroxy- 1-naphthyl) ace t amide 

N- (7-Hydroxy-l-naphthyl)benzamide 

1- (2-Hydroxy- 1-naphthyl azo)-6-nitro- 2-naphtho 1-4- 
sulfonic acid. 

3- [ (7-Hydroxy-l-naphthyl)carbamoyl]acetanilide 

4-Hydroxv-7- (p-nitrobenzamido) -2-naphthalenesulfonic 
acid. 

2-Hydroxy-5-nitrometanilic acid 

1- (2-Hydroxy-4-nitrophenylazo)-2-naphthol 

2,2'- (2-Hydroxy- 4-nitropheny limine) die thanol 

2-Hydroxy-4-n-octoxybenzophenone 

0- [ (p-Hydroxyphenyl) azojbenzoic acid 

3- [ (4- (4-Hydroxyphenylazo)2,5-dimethoxyphenylazo) ]- 
benzenesulfonic acid. 

lla-Hydroxyprogesterone 

2 ' - Hydr oxyp rop i ophenone 

N- Hydroxys uccini mi de 

N-Hydroxysuccinimide, triethylamine salt 

2-Hydroxy- 4- sulfo-1-naphthalenediazonium hydroxide 
inner salt. 

1 -Hydroxy- 4- p-toluidinoanthraquinone 

2- Imidazolidinone 

2- Imidazolidinone modifications 

*1 ,1 ' -Iminobis [4-aminoanthraquinone] 

Ijl'-Iminobis [4-benzamidoanthraquinone] 

1 ,1 '-Iminobis [5-benzamidoanthraquinone] 

7,7'- Iminobis [ 4 -hydroxy-2-naphthalenesulfonic acid] 

1 ,1 '-Iminobis [4-nitroanthraquinone] 

*1, I'-Iminodianthraquinone (1 , 1 '-Dianthrimide) 

Indole- 2, 3- di one 

Indophenol, sodium salt 



GAF, ICC, SDC, IRC. 



TRC. 
TRC. 



TRC. 
DUP, 
TRC. 
CTN. 
DUP, 
TRC 
ARS. 
ACY. 
IDC. 
ACY, 
DUP, 
ACY. 
GAF. 
DUP. 
SNA, 
VPC. 
GAF. 



ACY, TRC, WJ. 

TRC. 

ATL. 

x. 

PCW. 

WAY. 

ATL. 

ACY. 

GAF, TRC. 

TRC. 

TRC. 

TRC. 
GAF. 

TRC. 
TRC. 
WAY. 

ACY, CCW. 
EK. 



TRC. 



UPJ. 






uor. 






BJL, 


EK. 




BJL. 






ACY. 






GAF, 


ICI. 




VAL. 






RH. 






ACY, 


GAF, 


TRC 


ACY. 






GAF, 


TRC. 




TRC. 






ACY, 


TRC. 




ACY, 


GAF, 


TRC 


TRC. 






EK. 







CYCLIC INTERMEDIATES 
TABLE 2.— Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



a- lodotoluene 

Isobutylbenzene 

*Isocyanic acid derivatives: 

Bitolylene diisocyanate CTODI) 

p-Chlorophenyl isocyanate 

Cyclohexylisocyanate 

Dianisidine diisocyanate (DADI) 

Diphenylmethane- 4,4 '-diisocyanate (MDI) 

Phenylisocyanate 

Polyisocyanates (complex) 

Pol>inethylene pol>-phenyl isocyanate 

Toluene 2, 4- diisocyanate 

Toluene 2,4- and 2 ,6-diisocyanate (65/35 mixture) 

♦Toluene 2,4- and 2 ,6-dii50cyanate (80/20 mixture) 

p-Toluenesulfonyl isocyanate 

Other 

Isoni cot inonit rile 

2-Isonitrosoacetanilide 

Isophthalic acid (Benzene- 1 ,3-dicarboxylic acid) 

Isophthalic acid, diallyl ester 

Isophthalic acid, dimethyl ester 

Isophthalic acid, dlphenyl ester 

Isophthaloyl chloride 

p- Isopropylbenzoic acid 

4,4'-Isopropylidenebis [2,6-dibromophenol] (Tetrabromo- 

bisphenol A) . 
4,4'-Isopropylidenebis [2,6-dichlorophenol] (Tetrachloro- 

bisphenol A) 
5,5'-Isopropyl 
*4,4 '-Isopropyl 
4,4' -Isopropyl 



denebis (2-hydroxy-m-xylene,a,a' -diol)- 

denediphenol (Bisphenol A) 

denediphenol , ethoxylated 

4,4'- I sop ropy li denediphenol , propoxylated 

o- Isopropylphenol 

Isopropylphenols, mixed 

4- I sop ropy 1-m-phenylenedi amine 

I sovio Ian throne (Isodibenzanthrone) 

Leuco quinizarin (1,4,9,10-Anthratetrol) 

2,4-Lutidine 

2,6-Lutidine 

3,4-Lutidine 

3,5- Luti dine 

Malonani lide 

Mandelonitrile 

Melamine 

p-Mentha-1 ,4(8)-diene 

dl-p-Mentha-l,8-diene (Limonene) 

p-Menth-1-ene 

o-Mercaptobenzoic acid (Thiosalicylic acid) 

Metanilic acid (m-Arainobenzenesulfonic acid) 

N- (p-Methoxybenzylidene)-p-butyl aniline 

6-Methoxymetanilic acid 

4'-Methoxy-2- (p-raethox\'phenyl)acetophenone 

Methoxymethyldiphenyl oxide" 

N- (2-Methoxy- 1-naph thy Dacet amide 

6-Methoxy-8-nitroquinoline 

(p-Methoxyphenyl) acetic acid 

6-Methoxy- 2- (phenyl thio)quinoline 

m-Methoxyphenolisocyanate 



EK. 

PLC, TNA. 



CIVN, 
MOB. 
OTC. 
CIVN, 
ACS, 
HOB, 
MOB. 
MOB, 
DUP, 
DUP, 
ACS, 
CITO. 
DUP, 
RIL. 
TRC, 
ACC. 
FMP. 
MTR. 
BJL. 
DUP. 



UPJ. 

MOB, UPJ. 
UPJ. 

RUC, UPJ. 

MOB. 

MOB. 

DUP, MOB, OMC, RUC, UGC, WYN. 

MOB, UCC, X. 



EK. 
DOW. 

DVC. 

ARK. 

DOW, GE, SHC, UCC. 

ICI. 

ICI. 

TNA. 

FMP, KPT. 

DUP. 

MAY, TRC. 

EKT, HSH, TRC. 

KPT, RIL. 

RIL. 

UCC. 

RIL. 

PCW. 

KF. 

ACY, PPC. 

GIV. 

ARZ, GIV, HN, NCI. 

GIV. 

AMB, LIL. 

ACY, DUP, TRC. 

EK. 

GAF. 

CTN. 

BPC. 

TRC. 

PD. 

UOP. 
EK. 
EK, OTC. 



SYNTHETIC ORGANIC CHEf^ICALS, 197.2 
TABLE 2,— Cyclic intermediates for which U.S, production or sales were reported; 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



4 ' -Me thoxNT) rop i ophenone 

1- (Methyl ami no) anthraquinone 

1- (Methylamiiio)-4-p-toluidinoanthraquinone 

N-Me thy 1 aniline 

2- (N-Methylanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine [NH2=1] 

m-Methylanisole 

2-Methyl anthraquinone 

3-Methylbenzo[f]quinoline 

2-Methylbenzothiazole 

N-Methylbenzyl amine 

Methylbenzyl ether 

5-(l-Methylbutyl)barbituric acid 

N-Methyl-N-carboxyanthranilic anhydride 

3-Methylcholanthrene 

Methylcyclohexane 

2-Methylcyclohexanone 

l-Methyl-4-cyclohexene-l,2-dicarboxylic anhydride 

Methyl eye lopentadiene 

N-Methyldicyclohexylamine 

4-Methyl-a,a-diphenyl-l-piperazineethanol, dihydro- 
chloride. 

N-Me thy leneani line 

4 ,4'-Methylenebi5[2-chloroaniline] 

4 ,4'-Methylenebis [N,N- diethyl aniline] 

4,4'-Methylenebis[N,N-dimethylaniline] (Methane base) 

4,4'-Methylenebis(3-hydroxy-2-naphthoic acid) disodium 

salt. 

2,2'-Methylenebis(4-methyl-6-nonyl-p-cresol) 

*4, 4 '-Methylenedi aniline 

S,5'-Methylenedisalicylic acid 

Methy Ihydroquinone 

2-Methyl indole 

2 -Methyl indole- 3- carboxaldehyde 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic 
acid. 

5-Methyl-4-nitro-o-anisidine 

4-Methyl-2-nitroanisole 

2-Methyl -5-nitroimidazole 

N-Me thy 1-N-nitroso-p-toluenesulfonamide 

2-Methyl-5-norbomene-2,3-dicarboxylic anhydride 

Methylnorbomene-2,3-dicarboxylic anhydride, isomers 

m- (3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonaiiiide — 
„. (3.Methyl-S-oxo-2-pyrazolin-l-yl)benzenesulfonic acid- 
*p_(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid- 
3- (3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalene- 

disulfonic acid. 
6-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l ,3-naphthalene- 

disulfonic acid. 
4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic 
acid 1S03H=1]. 

2-Methyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

l-Methyl-4-phenylisonipecotic acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydro- 
chloride. 
*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 



Manufacturers' identification codes 
(according to list in table 3) 



LIL. 






AAP, 


ACY, 


ICI 


BDO, 


GAP, 


ICI 


ACY, 


DUP. 




TCIL 






DUP. 






SW. 






GIV. 






ACY. 






ACY. 






FMT. 






MLS, 


SDW. 




UCC. 






LIL. 







UCC. 
EN .J. 



PCW. 








DUP. 








ACY, 


TRC. 






ACY, 


DUP, 


SDH. 




EK, 


PD. 






ACY. 








ACS 


DOW, 


MOB, 


RUC 


HN. 








ARS 


EKT. 






TRC 








GAP 








DUP 









RDA. 






ALD, 


EK. 




VEL. 






ACS. 






VPC. 






TRC. 






ACY, 


GAP, 


TRC. 


TRC. 






TRC. 






CMG, 


TRC. 





SDW. 
ARS. 
ARS. 

ACY, DUP, GAP, SDH. VPC. 



CYCLIC INTERMEDIATES 

TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported. 
Identified by manufacturer, 1972--Continued 




4-Methyl-l-piperazine acetic acid, methyl ester 

3-Methyl-2-pyrazolin-S-one 

1-Methylpyrrole 

*a-Methylstyrene 

ar-Methylstyrene (Vinyl toluene) 

2-(Methyl5ulfonyl)-4-nitroaniline 

4- [Methyl thio)-m-cresol 

3-Methylthiophene 

3-Methyl- 1- (thiosulfophenyl)-2-pyrazolin-5-one , sodium 

salt. 
3-Methyl -6 -r)-toluidino-7H-diben2[f,ij ]isoquinoline- 
2,7('3H)-dione. 

3-Methyl-l-n-tolyl-2-pyrazolin-5-one 

16-A-Methyltriene carbethoxylate 

Naphthalene, solidifying at 79° C. or above (refined 
flake) (from domestic canide) . 

1 ,4-Naphthalenediol 

1-Naphthalenesulfonic acid 

2-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalenesulfonyl chloride 

1 ,4,5,8-Naphthalenetetracarboxylic acid 

Naphthalimide 

1-Naphthol (a-Naphthol) 

2-Naphthol, tech. (6-Naphthol) ' 

p-Naphtholbenzein 

l-Naphthol-3,6-disulfonic acid, monosodium salt 

l-Naphthol-2-sulfonic acid, potassium salt 

1 ,2- Naphthoquinone 

l,2-Naphthoquinone-4-sulfonic acid, sodium salt 

Naphth[l ,2-d] [1,2 ,3]oxadiazole-S-sulfonic acid 

2-(2H-Naphth[l,2-d]triazol-2-yl)-4-(l,l,3,3-tetramethyl- 
butyl)phenol. 

1 - Naph thy 1 acetate 

1-Naphthyl amine (rt-Naph thy 1 amine) 

2- (l-Naphthylamino)ethanol 

p- (2-Naphthylamino)phenol (N- (p-Hyd^oxyphenyl)-2- 
naphthylamine) . 

N- (1- Naph thy l)ethylenedi amine dihydrochloride 

(2-Naphthyloxy) acetic acid 

(2-Naphthyloxy) acetic acid, sodium salt 

(2-Naph thy Ithio) acetic acid 

Nicotinonitrile (3-Cyanopyridine) 

4'-Nitroacetanilide 

2'-Nitro-Ti-acetanisiHirie 

4'-Nitro-o-acetanisidide 

2-Nitro-p-acetophenetidide 

3' -Nitroacetophenone 

m-Nitro aniline 

o-Nitroaniline 



DUP. 

DUP. 

.\CP, CLK, DOW, HPC, SKO, USS. 

DOIV. 

TRC. 

CRZ. 

SDW. 

SDC. 

ICI. 

HST. 

sen. 

KPT, IVTC. 

EK. 

TRC. 

ACY, EK, FIN, m. 

TRC 

ACY. 

DUP. 

TRC 

ACS. 

UCC 

ACY. 

EK. 

HN. 

EK. 

EK. 



EK. 
DUP. 
TCU. 
SDC. 

RSA. 

EK. 

BKL. 

ACY. 

NEP, RIL. 

GAP, TRC. 

DUP. 

DUP. 

AAP. 

SDH. 

X. 

MON. 



See footnotes at end of table. 



552-743 O - 74 - 4 



SYFITHETIC ORGANIC CIlEniCALS. 1972 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED EY MANUFACTURER, 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 5) 



P-Nitroaniline 

2-Nitro-p-anisidine [NHj=l] 

4-Nitro-o-anisidine [NH2=1] 

5-Nitro-o-anisidine [NH2=1] 

o-Nitroanisole 

p-Nitroanisole 

5-Nitroanthranilic acid 

1-Nitroanthraquinone 

2- (4-Nitro-2-anthraquinonyl)anthra[2,3-d]-oxazole-5 ,10- 

dione. 

m-Nitrobenzaldehyde 

p-Nitrobenzaraide 

3'-Nitrobenzanilide 

♦Nitrobenzene 

p-Nitrobenzenediazonium tetraf luoroborate 

m-Nitrobenzenesulfonic acid 

m-Nitrobenzenesulfonic acid, sodium salt 

p-Nitrobenzenesulfonyl chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic acid 

- Ni troben zoi c acid 

p-Nitrobenzoic acid 

m-Nitrobenzoic acid, sodium salt 

o-Nitrobenzoic acid, sodium salt 

2- (m-Nitrobenzoyl)-o-acetanisidide 

p-Ni troben zoyl azide 

m-Nitrobenzoyl chloride 

p-Nitrobenzoyl chloride 

p-Nitrobenzyl chloro formate 

4- (p-Nitrobenzyl) pyridine 

4 '-Nitro-4-biphenylcarboxylic acid 

4-Nitro-sec-butylbenzene 

2-Nitro-p-cresol 

2-Nitro-p-cymene 

Nitrodiphenylamine 

5-Nitro-2-furanmethanediol , di acetate 

5-Nitroisophthalic acid 

1-Nitronaphthalene 

3-Nitro-l ,5-naphthalenedisulfonic acid 

7 (and 8) -Nitronaphth [ 1 ,2-d] [1 ,2 , 3]oxadiazole- 5 -sulfonic 

acid- 

p-Nitrophenethyl alcohol 

o-Nitrophenol 

p-Nitrophenol 

p-Nitrophenol, sodium salt 

4 '- (p-Nitrophenyl)acetophenone 

4- [ (p-Nitrophenyl)azo]-o-anisidine 

4-Nitro-o-phenylenediamine 

2- (o-Nitrophenylazo)-p-cresol (nH=l) 

(p-Nitrophenyl) hydrazine 

2,2'-[(m-NitrophenylH''iino]diethanol 

p-Nitrophenyl isocyanate 

2-(p-Nitrophenyl)-2H-naphthol[l,2-d]triazole-6,8- 

disulfonic acid. 
l-(m-Nitropheny 1-5-0X0- 2-pyTazoline-3-carboxylic 

acid. 
3-Nitrophthalic acid 



AAP, 


HON. 






DUP. 








DUP. 








BUG. 








DUP, 


X. 






DUP. 








TRC. 








ACY, 


TRC. 






GAP. 








SDll. 








IGG. 








MP . 








AGS. 


ACY , 


niip. 


FST 


EK. 








ACY, 


DUP. 






GAP, 


MGN , 


MRA, 


SAL 


EK. 








DUP. 








SAL, 


SDU, 


WAY. 




SAL, 


WAY. 






DUP. 








SAL, 


WAY . 






WAY. 








GAP. 









EK. 




DUP, 


TRC. 


WAY. 




SW. 




EK. 




ACY, 


HON. 


NOR. 




PIS, 


MAL. 


DUP. 




TRC. 




ACS, 


GAP, TRC 



PCW. 

MON. 

DUP, MON, SDC, UOP. 

DUP. 

DUP, PIS. 

AAP. 

DUP, PMT. 

TRC. 

EK. 

DUP. 



CYCLIC INTERMEDIATES 
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972— CoNT INUED 



3-Nitrophthalic anhydride 

4-Nitrophthalimide 

--Nitroresorcinol 

5- Nitrosalicyl aldehyde 

l-Nitroso-2-naphthol 

p-Nitrosophenol 

4-Nitro5tilbene 

B-Nitrostyrene 

4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)- 
2,2'-stilbenedisulfonic acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

p-Nitrotoluenesulfonic acid 

*5-Nitro-o-toluenesulfonic acid [SO^Hsl] 

3-Nitro-p-toluenesulfonic acid [S03H=1] 

2-Nitro-iii-toluic acid 

3-Nitro-p-toluic acid, methyl ester 

*5-Nitro-o-toIuidine [NH2=1]- 

2-Nitro-p-toluidine [NH2=1] 

S-Nitro-2-p-toluidinobenzenesulfonic acid 

16-Nitroviolanthrone 

4- Nitrc-m- xylene 

*Nonylphenol 

5-Norbomene-2 ,3-dicarboxvlic anhydride 

Oxalacetic acid, diethylester, Cp-sulfophenyl) - 
hydrazone . 

Oxanilide 

*1- [ (7- Oxo-7H-benz[de] anthracene- 3-yl) amino] ant hra- 
quinone . 
l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]- 

dianthraquinone . 
S- 0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic acid 

(Pyrazolone T) . 
5-0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic acid, 
ethyl ester. 

4,4 '-Oxydi aniline 

Penicillin G, N-ethylpiperidine salt 

Pent achloropyri dine 

1,1,3,3,5-Pentamethylindan 

p-Pentyl aniline 

p-Pentyloxybenzoyl chloride 

o-Pentylphenol to-Amylphenol) 

p-tert-Pentylphenol 

3,4,9,10-Penylenetetracarboxylic-3,4:9,10-diimide 

Phenethylamine 

a-Phenethylamine 

Phenethylamine sulfate 

o-Phenethylbenzoic acid 

m-Phenetidine 

o-Phenetidine 

p-Phenetidine 

•Phenol : 
'Natural : 

*From coal tar:^ 

39°C., m.p 

82%- 84% 

All other 

*From petroleum 

See footnotes at end of table. 



Manufacturers' identification codes 
(according to list in table 3) 



EK. 

EK. 

EK. 

ACY, SDC. 

GAP. 

cm. 

TRC. 



DIJP 



FST. 



DUP 


FST. 








DUP, 


EST. 








DIIP, 


FST, 


HN. 






CGY. 










ACS, 


ACY. 


DUP. 


GAF 


SDH, TRC 


DIG. 


TRC. 








SAL. 










SDH. 










BUG, 


DUP, 


PCW, 


SDH 




DIIP, 


GAF, 


SW. 






TRC. 










ICI. 










DUP. 










GAF. 


JCC, 


MON, 


RH, 


UCC. 


VRL. 










TRC. 










EK. 










ACY, 


DUP, 


GAF, 


MAY, 


TRC. 


MAY, 


TRC. 








STG. 










STG. 











DOW. 

GIV. 

EK. 

EK. 

PAS. 

PAS. 

ACS. 

MLS. 

MLS. 

MLS. 

LIL. 

EK. 

MON. 

MON. 



KPT. 
AGP. 

ACP, KPT. 
MLR, NPC, PRD. 



SYNTHETIC ORGANIC CHEI^ICALS> 1972 
TABLE 2,— Cyclic intermediates for which U,S, production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



*Synthetic: 

By caustic fusion: U.S.P 

From chlorobenzene by liquid-pbase hydrolysis: 

U.S.P 

*Froin curaene by oxidation: U.S.P 

Other 

Phenolsulfonaphthalein, sodium salt 

Phenolsulfonic acid, lithium salt 

Phenoxyacetic acid, sodium salt 

2- Phen oxyprop i ony 1 chloride 

Phenylacetic acid (a-Toluic acid) 

Phenylacetic acid, ethyl ester, tech 

Phenylacetic acid, methyl ester 

Phenylacetic acid, potassium salt 

Phenylacetic acid, sodium salt 

Phenylacetonitrile (a-Tolunitrile) 

4'-Phenylacet ophenone 

Pheny 1 ace ty 1 chloride 

N-Phenylanthranilic acid 

Pheny larsine oxide 

p-Phenylazoaniline (C. 1. Solvent Yellow 1) and hydro- 
chloride . 

4- CPhenylazoJdiphenyl amine 

4- (Pheny lazo)-l-naph thy lamine 

5- (Pheny lazo) salicylic acid 

1- Pheny lb iguanide hydrochloride 

4-Phenyl-3-buten-2-one 

Phenyl chloro formate 

a-Phenyl-o-cresol 

1- Pheny Icyclopentanecarboxylic acid 

m- Pheny lenedi amine 

o- Pheny lenedi amine 

p- Pheny lenedi amine 

p- Pheny lenedi amine dihydrochloride 

d- Phenylephrine 

dl- Phenylephrine 

1- Pheny lethanol 

Phenyl ether (Diphenyl oxide) 

d(-) Pheny Iglycine 

dl- Pheny Iglycine (racemic) 

N- Pheny Iglycine 

Pheny Iglycol ethers 

df-)Phenylglycyl chloride hydrochloride 

5-Phenylhydantoin 

Phenyl hydrazine hydrochloride 

Pheny l-l-hydroxy-2-naphthoate 

2,2 '- [ (Phenyl )imino] die thanol (N- Pheny Idiethanol amine )- 

2,2'-[(Phenyl)imino]diethanol, diacetate ester 

3,3'- [ (Pheny l)imi no] dipropionitrile 

Phenylmalonic acid, diethyl ester 

3- Phenyl -5-methyli50xazole-4-carbonyl chloride 

Pheny 1-a-naph thy lamine 

o- Pheny Iphenol 

p-Phenylphenol 

o- Pheny Iphenol , chlorinated 

o-Phenylphenol, sodium salt 

N- Pheny 1-p-pheny lenedi amine 

Pheny Iphosphinic acid 

Pheny Iphosphonothioic di chloride 



•lAL, 


RCI. 






now. 








AGP, 


CLK, 


HON, 


SHC 


KLM. 








HK. 








SAL. 








BPC. 








ARS. 








BPC, 


GIV, 


MAL. 




BPC, 


HAL. 






BPC. 








BPC, 


OPC. 






npc. 








BPC, 


SDW, 


OPC, 


UOP 


DUP. 








B.JL. 








SDW. 








EK. 








ACS, 


ACY, 


nup. 





TRC. 

SDC. 

SDW. 

EK. 

RBC. 

SK. 

ACY, DUP. 

DUP, SW, TRC. 

ACY, DUP, SDC. 

EK. 

SDW. 

SDW. 

UCC. 

DOW . 

BKL, KF, QIC, UPJ. 

KF. 

EK. 

ncc. 

KF, OTC, x. 

ABB. 

EK. 

EK. 

TCH. 

SDC. 

DUP. 

BPC. 

AR.S. 

UCC. 

DOW, RCI. 

DOW. 

DOW. 

DOW. 

USR. 

SFA. 



CYCLIC INTERflEDIATES 
TABLE 2, --Cyclic intermediates for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972--CONTI NUED 



Manufacturers* identification codes 
(according to list in table 3) 



Pheny Iphosphorous di ch lori de 

*I-Phenyl-1 ,2-propanedione , 2-oxime 

Pheny 1-2-prop an one 

l-Phenyl-5-pyrazolone-3-carboxylic acid, ethyl estei- 

dl- Phenyl succinic acid 

Phenyl sulfide 

Pheny 1 sul f one 

1- Phenyl -2- thiourea 

Pheny lundecanoic acid 

Phloroglucinol 

l(2H]-Phthala2inone 

Phthalaldehyde 

Phthalic acid 

Phthalic acid, diallyl ester 

*Phthalic anhydride 

Phthalide 

Phthalimide 

Phthalimide, potassium salt 

[Phthalocyaninato(2-) ] copper 

Phthalocyanine, copper complex, di-(and tri-)chloro- 

methyl . 
Phthaloyl chloride (Phthalyl chloride) 

*Picolines : ^ 

2-Picoline (a-Picoline) 

3-Picoline (8-Picoline) 

4- Pi CO line CY-Picoline) 

Pi CO line (3,4-mixture) 

Picolinonitrile (2-Cyanopyridine) 

3- Pi CO lyl amine 

Picric acid (Trinitrophenol) 

2,5-Piperazinedione 

*Piperidine 

3-Piperidinopropiophenone hydrochloride 

Polyethylbenzene 

Poly-m-phenoxylene 

Potassium eye lohexanebuty rate 

Primuline base 

Primulinesulfonic acid 

'Propiophenone 

8 , 16 - Pyranthrenedi one 

Pyridine, refined:^ 

2" P\'ridine 

Other grades 

Pyridine hydrochloride 

3-Pyridinemethanol 

2(lH)-Pyridone 

2-Pyrimidinol 

2(lH)-Pyrimidinone 

2- Pyrrol idinone 

Quinaldine 



SFA. 

NEP, 
ORT. 



NES. 

EK. 

EK. 



EK. 

EK. 

FMP. 

AGP, 

ACS, 

DUP, 

EK. 

GAF. 

TRC. 



ENJ, KPT, MON, PTO, RCl, SOC , STP, UCC, USS, WYN. 

FMT. 

SW. 



KPT, 


NEP, 


RIL, UCC 


NEP, 


RIL. 




RIL, 


UCC. 




KPT. 






NEP. 






RIL. 






SDC. 






EK. 






ABB, 


DUP, 


RIL. 


ACY, 


SDW. 




UCC. 






EK. 






EK. 






DUP. 






ATL. 






ORT, 


PD, 


UCC, UOP. 


ICI, 


TRC 




KPT, 


NEP 


RIL. 


KPT, 


NEP 




EK. 






RIL. 






FMT. 






COY. 






VAL. 






GAF. 






ACS, 


ACY 





See footnotes at end of table. 



SYNTilETIC ORGANIC CHEMICALS. 197^ 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Quinoline ; 

1° and 2° Quinoline 

Quinoline (synthetic) 

Other grades 

2,4-Quinolinediol 

Quinophthalone (Quinoline yellow base) 

Resorcinol , tech' 

Resorcinol, raonoacetate (non-medicinal grade)' 

S-Resorcylic acid 

*Salicyl aldehyde 

Salicyl aldehyde oxime 

*Salicylic acid, tech 

Salicylic acid, airanonium chromium complex 

Salicylic -acid, sodium chromium complex 

*Styrene, all grades 

5 - Sul f amoy lanthranilic acid 

Sulfanilamide, tech 

Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt- 

4-Sulfoanthranilic acid 

5-Sulfoisophthalic acid, 1,3-dimethyl ester, sodium 
salt. 

5-Sulfoisophthalic acid, lithium salt 

5-Sulfoisophthalic acid, sodium salt 

2,4' and 4 ,4' -Sulfonyldiphenol 

4,4'-Sulfonyldiphenol (4,4'-Dihydroxydiphenylsulfone)-- 

4-Sulfophthalic acid ■---■_---■- 

*Tereph thalic acid 

*Terephthalic acid, dimethyl ester 

Terephthalic acid, diphenyl ester 

Terephthaloyldiacetic acid, diethyl ester 

Terpheny 1 (Pheny lb ipheny 1) 

3,3' ,4,4 '-Tetraaminobenzophenone 

3,3' ,4,4'-Tetraaminobiphenyl 

[4, 4', 4'', 4'' '-Tetraaminophthalocyaninato(21 ] copper 

3' ,3' ' ,5'5' '-Tetrabromophenolphthalein, ethyl ester 

Tetrabromoph thalic anhydride 

1 ,4,5,8-Tetrachloroanthraquinone 

1 ,2,4,S-Tetrachlorobenzene 

1,2,4 ,5-Tetrachloro-3-nitrobenzene 

Tetrachloroph thalic anhydride 

3,3' ,4' ,5-Tetrachlorosalicylanilide 

Tetrachloroviolanthrone 

Tetrahydrofuran 

Tetrahydrofurfuryl methacrylate 

*1 ,4 ,5 ,8-Tetrahydroxyanthraquinone, leuco derivative 

1 ,4 ,5,8-Tetrakis(l-anthraquinonylamino)anthraquinone 
(Pentanthrimide) . 

N,N,3,5-Tetramethylaniline 

1 ,2,4,5-Tetramethylbenzene (Durene) 

N,N,N',N'-Tet rame thylbenzidine 

p-(l,l,3,3-Tetramethylbutyl)phenol 

N,N,N' ,N'-Tetraraethyl-p-phenylenediamine dihydro- 

chloride. 
[4, 4', 4'', 4'' '-Tetranitrophthalocyaninato(2) ] copper 



KPT. 






EK. 






KPT. 






PCW. 






ACS. 






KPT, 


UPF 




AAP. 






KPT, 


UPF 




DOW , 


MTR 


RDA. 


EK. 






DOW , 


HN, 


HON, SDU. 


TRC. 






TRC. 






ACC, 


CSD 


DOW, ELP, FG, GOC, KPP, MCB, MON, SHC , SKC 


SNT, UCC. 


TRC. 






SAL. 






ACS, 


ACY, 


DUP. 


CMC, 


TRC. 




PCW. 






PCW. 






PCW. 






UPF. 






HON, 


UPF. 




ClfN, 


HSC. 




ACC, 


DUP, 


EKT, SM. 


ACC, 


DUP, 


EKT, UPC. 


BJL. 






PCW. 






MON. 






BJL. 






UPJ. 






.SDC. 






EK. 






MCH. 






DUP, 


GAP. 




DOW, 


UK. 




SDH. 






MON. 






EK. 






GAP. 






DUP, 


QKO. 




SAR. 






ACS, 


GAP, 


HN, TRC. 


GAP. 







» 



GAP, PRO, Rll, SCN. 



I 



CYCLIC INTERMEDIATES 
TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONT INUED 



3,3'-Thiobis [7H-benz[de] anthracen-7-one] 

2,2'-Thiobis [S-nitrobenzenesulfonic acid] 

4,4'-Thiodianiline 

*6,6'-Thiodinietanilic acid 

2-Thiophene acetic acid 

2-Thiopheneacetonitrile 

2-Thiophenecarboxaldehyde 

Thiophenol 

sym- Thymol 

*Toluene-2,4-diamine (4-m-Tolylenedi amine) 

Toluene- 2, 4- di sulfonic acid 

p-Toluenesulfinic acid, sodium salt 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

o(and p) -Toluenesulfonic acid 

p- Toluenes ulfonic acid 

p-Toluenesulfonic acid-2-chloroethyl ester 

p-Toluenesulfonic acid, methyl ester 

p-Toluenesulfonic acid, monohydrate 

p-Toluenesulfonyl chloride 

a-Toluenesulfonyl fluoride 

m-Toluic acid 

o-Toluic acid 

p-Toluic acid 

m-Toluidine 

o-Toluidine 

p-Toluidine 

o-Toluidine hydrochloride 

p-Toluidine hydrochloride 

To lui dines, mixed 

2-o-Toluidinoethanol 

m-Toluidinoraethanesulfonic acid 

o- To lui dinome thanes ulfonic acid 

0- (p-Toluoyl) ben zoic acid 

N-(p-Tolylazo)sarcosine 

*4-(o-Tolylazo)-o-toluidine (C. I. Solvent Yellow 3) • 

4- [o-Tolylazo)-o-toluidine hydrochloride 

1-p-Tolyldodecane 

2,2'- (m-Tolyliraino)diethanol 

2,2'-(m-Tolylimino)diethanol, diacetate ester 

o-Tolylisocyanate 

p-Tolylisocyanate 

p-Tolylmercuric chloride 

Tolyltriazole 

N,N,N-Tribenzyl amine 

1,2, 3 (and 1 ,2 ,4) -Trichlorobenzene 

*1 ,2, 4 -Trichlorobenzene 

N,2,6-Trichloro-p-benzoquinoneiraine 

1 ,1 ,l-Trichloro-2 , 2- diphenyl ethane 

Trichloromel amine 

l,2,4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

Trifluoropropylmethylsiloxane 

a,a,a,-Trichlorotoluene (Benzotri chloride) 

a,2,4-Trichlorotoluene 

2,4,6-Trichloro-s-triazine (Cyanuric chloride) 



Manufacturers ' 
(according 



identification codes 
:o list in table 3) 



HAY, 
GAF. 
ACY. 
ACS, 
BPC. 
BPC. 



ATL, GAF, LIL. 



KPT. 
ACY, 



SFA 

GIV 

ACS 

GAF. 

EK, NES, 

flON. 

MON. 

MON, NES, 

TEN, HON, 

GAF. 

ICI. 

NES. 

MON . 

EK. 

BPC. 

BPC. 

BPC. 

DUP. 

DUP, FST. 

DUP. 

.AAP, ACY. 

EK. 

DUP. 

TCH. 

VPC. 

GAF, TRC, 

ACY, DUP. 

BUC, GAF. 

ACY, ALL, DUP, GAF, 

GAF. 

X. 

EKT, TCU. 

SDC. 

EK. 

EK. 

EK. 

SN. 

MLS. 

PPG. 

DOW, DVC, HK, SVT. 

EK. 

aVN. 

IVTH. 

ALL. 

DCC, UCC. 

DCC. 

HK, VEL. 

HN. 

CGY, NIL. 



DUP. OMC, RUC, UCC. 



UPF. 
UPF. 



VPC. 



SYflTHETIC 0RG'\:JIC CHE'IICALS, P7? 
TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



1,3,5-Triethylbenzene 

a,a,c«-Trifluorotoluene 

1,2,4-Trihydroxyanthraquinone 

4,5,7-Trihydroxyisoflavone 

Trimellitic anhydride, acid chloride 

1 ,2,3-Trimethylbenzene (Hemimellitene) 

1,2,4-Trimethylbenzene (Pseudocumene) 

1,3,5-Triinethylbenzene (Mesitylene) 

2,3,3-Trimethyl-3H-indole 

♦1 ,3,3-Trimethyl-A^ ,a-indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)-- 

Trimethylphenyl ammonium chloride 

2,4,6-Trimethylpyridine 

l-(Trimethyls'ilylUmidazole 

2,4,6-Trinitrobenzenesulfonic acid 

2,4,7-Trinitrofluoren-9-one 

Triphenyl amine 

Triphenylme thane 

Triphenylmethanol 

a, a' ,a' ' -Tris (dime thy 1 amino )mesitol 

Tri5(2-methyl-l-aziridinyl)phosphine oxide 

Tris(l ,10-phenanthroline)iron(in sulfate 

*7,7' -Ureylenebis [4-hydroxy-2-naphthalenesulfonic acid] 
(J Acid Urea) . 

Verat raldehyde (3,4- Dimethoxyben zal dehyde ) 

p-Vinylbenzenesulfonic acid, sodium salt 

Vinyl eye lohexane 

2-Vinylcyclohexene 

5-Vinyl-2-picoline (M\'T) 

2-Vinylpyridine 

4-Vinylpyridine 

Vinyl toluene 

*Viol an throne (Dibenzanthrone) 

Xanthene-9-carboxylic acid 

m~ Xylene 

*o- Xylene 

*p- Xylene 

m-Xylenesulfonic acid 

Xylenol crystals 

2, 6 - Xylene I , synthetic 

Xylenols : 

Low b.p 

Medium b.p 

Xylidines : 

2,4-Xylidine 

2,6-Xylidine 

Original mixture 

4- (2,4-Xylylazo)-o-toluidine 

4-(2,5-Xylylazo)-o-toluidine 

4-(2,4-Xylylazo)-2,5-xylidine 

4- (Xylylazo) xylidines, mixed 

All other cyclic intermediates 



DUP. 

HK. 

GAP. 

EK. 

ARS. 

SNT. 

SNT. 

SNT. 

GAP. 

ACS, 

DUP, 

X. 

KPT. 

EK. 

EK. 

EK, 1 

EK. 

EK. 

EK. 

RH. 

ARS, 

EK. 

ATL, 



ATL, DUP, GAP, TRC, VPC. 
GAP, TRC, VPC. 



ICC. 

CTIG, GAP, TRC, VPC. 



GIV, SLV. 

DUP. 

BFG. 

UCC. 

PLC. 

MAY, RIL. 

RIL. 

FG. 

ACS, ACY, DUP, GAF, ICI, MAY, SDC, TRC. 

HAL. 

ATR, SNT. 

ATR, CCP, CPI, CSD, CSO, ENJ, MON, PPR, SHC, SHO, SNT, 

snc, TOC. 
ACC, ATR, CSO, ENJ, HCR, PPR, SHC, SHO, SNT, SOC, SOG, 

TOC. 
NES. 
NES. 
GE, KPT. 

NPC. 
NPC. 

DUP. 

DUP. 

DUP. 

ACS. 

ACY. 

ACS. 

GAF. 

'^AP, ABB, ALL, ALD, ARS, ATL, B,1L, BKL, BPC, CMC, CTN , 
DUP, EK, FMP, GAF, HEX, .ICC, KF , LIL, MRK, PCW, PD, 
PRD, RH, SW, TCH, TKL, UCC, UOP, WYT, x, x, x, x, ". 



See report on Medicinal Chemicals for data on medicinal grade of this item. 

Does not include manufacturers' identification codes for producers that renort to the Division of Fossil Fuels, 
U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers 
in the United States in 1972, Nov. 2?, 1973. 



CYCLIC IITERflEDIATES 
TABLE 3.— Cyclic intermediates: Directory of manufacturers, 1972 



ALPHABbTICAL UIRECTURY BY CUCIE 

[Names ot manufacturers that reported production or sales of cyclic intermediates to the U.S. Tariff Commission for 
1972 are listed below in the order of their identification codes as used in table 2] 



Loae 


Name of company 


Code 


Name of company 


MP 


American Aniline Products, Inc. 


FG 


Foster Grant Co. , Inc. 




ABB 


Abbott Laboratories 


FIN 


Fine Organics, Inc. 




ACC 


Amoco Chemical Corp. 


FIS 


Fisher Chemical Co., Inc. 






Allied Chemical Corp. : 


FMP 


FMC Corp., Industrial Chemical Div. 




ACF 


Plastics Division 




Business Croup 




ACS 


Specialty Chemicals Division 


fmt 


Fairmount Chemical Co., Inc. 




ACY 


American Cyanamid Co. 


fst 


First Chemical Corp. 




AlP 


Air Products f, Chemicals, Inc. 








ALD 


Aldrich Chemical Co., Inc. 


GAF 


GAF Corp., Chemical Division 




ALL 


Alliance Chemical, Inc. 


GE 


General Electric Co. 




AMB 


American Bio-Synthetics Corp. 


GIV 


Givaudan Corp. 




ARA 


Arapahoe Chemical Division of Syntex Corp. 


GLY 


Glyco Chemicals, Inc. 




AKK 


Armstrong Cork Co. 


GOC 


Gulf Oil Corp., Gulf Oil Lo. Chemical Co.- U 


S. 


ARS 


Arsynco, Inc. 


GRS 


Champlin Petroleum Co. 




ARZ 


Arizona Chemical Co. 


GYR 


Goodyear Tire i, Rubber Co. 




ASH 


Ashland Oil, Inc. 








ASL 


Ansul Chemical Co. 


HCR 


Hercor Chemical Corp. 




ATL 


Atlantic Chemical Corp. 


HEX 


Hexagon Laboratories, Inc. 




AIR 


Atlantic Richfield Co., ARCO Chemical Co. Div. 


HK 

HN 


Hooker Chemical Corp. 
Tenneco Chemicals, Inc. 




EDO 


Benzenoid Organlcs, Inc. 


HPC 


Hercules, Inc. 




BFG 


B.F, Goodrich Co., B.F. Goodrich Chemical Co. 


HSC 


Chemetron Corp., Pigments Division 






Div. 


HSH 


Harshaw Chemical (_o.. Division of Kewanee 




.^tl 


Atlantic Richfield Co., ARCO Chemical Co. Div. 


hst 


Oil Co. 
American Hoechst Corp. 




BLlO 


Benzenoid Organics, Inc. 








BJL 


Burdick 5 Jackson Laboratories, Inc. 


ICC 


Inmont Corp. 




BM 


Millmaster Onyx Corp., Millmaster Chemical 


ICI 


ICI America, Inc. 6 Specialty Chemicals Div. 






Division, Berkeley Chemical Dept. 


luc 


Industrial Dyestuff Co. 




BPC 


Stauffer Chemical Co., Specialty-Chemical Div., 










Benzol Products Dept. 


JCC 


Jefferson Chemical Co., Inc. 




BRP 


BP Oil Corp. 








BUC 


Blackman-Uhler Chemical Co. 


KF 
KLM 


Kay-Fries Chemicals, Inc. 
Kalana Chemical Co. 




CCP 


Crown Central Petroleum Corp. 


KPP 


iJinclair-Koppers Co. 




CCW 


Cincinnati Milacron Chemicals, Inc. 


KPi 


Koppers Co., Inc., Organic Materials Division 




CEL 


Celanese Corp., Celanese Chemical Co. 








CGY 


Ciba-Geigy Corp. 


LAK 


Lakeway Chemicals, Inc. 




CHL 


Chemol, Inc. 


LIL 


Ell Lilly 1, Co. S Puerto Rico 




CHP 


C. H. Patrick Co., Inc. 








CLK 


Clark Chemical Corp. 


MAL 


Mallinckrodt Chemical Works 




CMC 


Nyanza, Inc. 


MAY 


Otto B. May, Inc. 




CNP 


Nipro, Inc. 


MCB 


Borg-Warner Corp., Marbon Chemical Division 




CO 


Continental Oil Co. 


MCH 


Michigan Chemical Corp. 




CPI 


Commonwealth Petrochemicals, Inc. 


MER 


Merichem Co. 




CRS 


Carus Corp., Carus Chemical Co. 


MET 


M and T Chemicals, Inc. 




CRZ 


Crown iellerbach Corp., Chemical Products Div. 


MLS 


Miles Laboratories, Inc., Marschall Division 




CSD 


Cosden Oil f, Chemical Co. 


MNR 


Monroe Chemical Co. 




CSO 


Cities Service Oil Co. 


MOB 


Mobay Chemical to. 




CSP 


Coastal States Petrochemical Co. 


MOC 


Marathon Oil Co., Texas Refining Division 




ctn 


Chemetron Corp., Organic Chemical Division 


MCN 


Monsanto Co. 




CWN 


Upjohn Co., Fine Chemical Division 


MKA 
MRK 


Crown-Metro, Inc. 
Merck 6 Co. , Inc. 




DA 


Diamond Shamrock Corp. 


MRT 


Morton Chemical Co. Div. ot Morton-Norwich 




DBC 


Dow Badische Co. 




Products, Inc. 




DCC 


Dow Corning Corp. 


MTO 


Montrose Chemical Co. 




DOW 


Dow Chemical Co. 


MTR 


Sobin Chemicals, Inc., Montrose Chemical Division 


DSC 


Dye Specialties, Inc. 








DUP 


E.I. duPont de Nemours 6 Co. , Inc. 


NCI 


Union Camp Corp., Chemicals Division 




DVC 


Dover Chemical Corp. 


NtP 
NES 


Nepera Chemical Co., Inc. 
Nease Chemical Co., Inc. 




EK 


Eastman Kodak Co. : 


NEV 


Neville Chemical Co. 




EKT 


Tennessee Eastman Co. Division 


NIL 


Nilok Chemicals, Inc. 




ELF 


El Paso Products Co. 


NOR 


Norwich Pharmacal Co. 




ENJ 


Exxon Chemical Co. U.S.A. 


NPC 


Northwest Petrochemical Corp. 





SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3.— Cyclic intermediates; Directory of Manufacturers, 1972— Continued 



Code 


Name of company 


Code 


Name of company 


OMC 


Olin Corp. 


SKO 


Skelly Oil Co. 


UPC 


Urbis Products Corp. 


SLV 


Sterwm Chemicals, Inc. 


URO 


Chevron Chemical Co. 


SM 


Mobil Chemical Co. 


ORT 


Roehr Chemicals, Inc. 


SNA 


Sun Chemical Corp. 


ore 


Story Chemical Corp., Ott Div. 


SNT 


Suntide Refining Co. 






SOC 


Standard uil Co. of California, Chevron 


PAS 


Pennwalt Chemicals Corp. 




Chemical Co. 


PAT 


Morton Chemical Co. Div. of Morton-Norwich 


SOG 


Charter International uil Co. 




Products, Inc. 


stg 


Stange Co. 


PCK 


Princeton Chemical Research, Inc. 


stp 


Stepan Chemical Co. 


PCW 


Pfister Chemical, Inc. 


STY 


Styrochem Corp. 


PD 


Parke, Davis 5 Co. 


SVl 


Solvent Chemical Co., Inc. 


PFZ 


Pfizer, Inc. 


SW 


Sherwin-Williams Co. 


PIT 


Pitt-Consol Chemical Co. 


SWC 


Shell fi Commonwealth Chemicals, Inc. 


PLC 


Phillips Petroleum Co. 






PPC 


Premier Petrochemical Co. 


TCH 


Emery Industries, Inc., Trylon Chemical Div. 


PPG 


PPG Industries, Inc. 


TEN 


Cities Service Co., Copperhill Operations 


PPR 


Philllips Puerto Rico Core, Inc. 


TKL 


Thiokol Chemical Corp. 


PRD 


Productol Chemical Co., Inc. 


TMS 


Sterling Drug, Inc., Thomasset Color Division 


pto 


Puerto Rico Chemical Co., Inc. 


TNA 


Ethyl Corp. 


pit 


Petro-iex Chemical Corp. 


TOC 


Tenneco Oil Co. 






TRC 


Toms River Chemical Corp. 


QKU 


Quaker Oats Co. 


TRD 


Trade Enterprises, Inc. 






TX 


Texaco, Inc. 


RBC 


Fike Chemicals, Inc. 






RCI 


Reichhold Chemicals, Inc. 


DCC 


Union Carbide Corp. 


RDA 


Rhodia, Inc. 


UUC 


Union Oil Co. of California 


KM 


Khom 5 Haas Co. 


UOP 


Universal Oil Products Co., UOP Chemical Div. 


RIL 


Keilly lar t. Chemical Corp. 


UPF 


United States Pipe 6 Foundry Co. 


RPC 


Millnaster Unyx Corp., Refined-'Jnyx Division 


UPJ 


Upjohn Co. 


KSA 


R.S.A. Corp. 


USR 


Uniroyal, Inc., chemical Division 


RUC 


Rubicon Chemicals, Inc. 


USS 


USS Chemicals Div. of U.S. Steel Corp. 


SAL 


Salsbury Laboratories 


VAL 


Valchem Corp. 


SAR 


Sartomer Industries, Inc. 


VEL 


Velsicol Chemical Corp. 


sec 


Standard Chlorine of Delaware, Inc. 


vgc 


Virginia Chemicals, Inc. 


sen 


Schering Corp. 


VPC 


Baychem Corp., Verona Div. 


SCN 


Schenectady Chemicals, Inc. 






yDC 


Martin-Marietta Corp., Sodyeco Div. 


WAY 


Philip A. Hunt Chemical Corp., Wayland 




Sterling Drug, Inc. : 




Chemical Division 


SUH 


Hilton-Uavis Chemical Co. Division 


WCC 


Witco Chemical Corp., Witfield Chemical Div. 


SDW 


Winthrop Laboratories Division 


WHC 


Whittaker Corp., Research 5 Development 




Stauffer Chemical Co.: 


WIL 


Wilson g Co., Inc., Wilson Laboratories Div. 


SFA 


Agricultural Division 


WJ 


Warner- Jenkinson Manufacturing Co. 


SFC 


Calhio Chemicals, inc. 


WTC 


Witco Chemical Co., Inc. 


SFS 


Specialty Chemical Division 


WYN 


BASF-Wyandotte Corp. 


SHC 


Shell Oil Co., Shell Chemical Co. Division 


WYT 


Wyeth Laboratories, Inc., Wyeth Laboratories 


SHO 


Shell Oil Co. 




Div. of American Home Products Corp. 


SK 


Smith, Klein t, French Laboratories 






SKC 


Sinclair-Koppers Chemical Co. 


YAW 


Y.S. Young Co., Young Aniline Works Division 



Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix. 



55 
DYES 

Domestic synthetic dyes are derived in whole or in part from cyclic 
intermediates. Approximately two-thirds of the dyes consumed in the 
United States are used by the textile industry to dye natural and syn- 
thetic fibers or fabrics; about one-sixth is used for coloring paper; and 
the rest is used chiefly in the production of organic pigments and in 
dying of leather and plastics. Of the several thousand different synthe- 
tic dyes that are known, more than one thousand are manufactured by one or 
more domestic producers. The large number of dyes results from the many 
different types of materials to which dyes are applied, the different con- 
ditions of service for which dyes are required, and the costs that a 
particular use can bear. Dyes are sold as pastes, powders, lumps, and 
solutions; concentrations vary from 6 percent to 100 percent. The con- 
centration, form, and purity of a dye are determined largely by the use 
for which it is intended. 

Total domestic production of dyes in 1972 amounted to 263 million 
pounds, or 8.0 percent more than the 244 million pounds produced in 1971 
(table 1).^ Sales of dyes in 1972 amounted to 255 million pounds, valued 
at $480 million, compared with 230 million pounds, valued at $423 million, 
in 1971. In terms of quantity, sales of dyes in 1972 were 10.9 percent 
larger than in 1971 and in terms of value, 13.5 percent larger. The 
average unit value of sales of all dyes in 1972 was $1.88 per pound, com- 
pared with $1.84 per pound in 1971. 

For many important ayes, production was larger in 1972 than in 1971. 
Vat Yellow 2 production increased 49.4 percent from 2,211,000 pounds in 
1971 to 3,304,000 pounds in 1972. Basic Yellow 11 production increased 
by 45.5 percent from 1,174,000 pounds in 1971 to 1,708,000 pounds in 
1972. Other important dyes whose output in 1972 was substantially larger 
than in 1971 were Acid Red 88 (43.0 percent increase). Direct Yellow 44 
(28.0 percent increase). Disperse Yellow 54 (27.0 percent increase). 
Direct Black 38 (26.8 percent increase), and Disperse Red 60 (19.0 per- 
cent increase) . 

On the other hand, the production of several important dyes was 
smaller in 1972 than in 1971. Production of Vat Green 1 was 1,800,000 
pounds in 1972, or 54.6 percent less than the 3,966,000 pounds produced 
in 1971. Production of Vat Green 3 was 1,402,000 pounds in 1972, or 
32.3 percent less than the 2,070,000 pounds produced in 1971. The pro- 
duction of Disperse Blue 3 was 29.9 percent less in 1972 than in 1971; 
that of Disperse Yellow 23 was 29.3 percent smaller; that of FD§C Yellow 
No. 6 was 20.5 percent smaller; that of Direct Blue 2 was 19.8 percent 
smaller; and that of Vat Black 25 was 10.4 percent smaller. 

Table lA is a summary of production and sales of dyes in 1972 by 
class of application. Five application classes of dyes accounted for 
72.1 percent of all dyes produced in 1972. Vat dyes accounted for 20.9 

See also table 2 of this report which lists these products and 
identifies the manufacturers by codes. These codes are given in table 3. 



56 

SYNTHETIC ORGANIC CHEMICALS, 1972 . 

percent of the total; disperse dyes for 15.2 percent; direct dyes for 

14.3 percent; acid dyes for 11.3 percent; and fluorescent brighteners for 

10.4 percent. Of these five classes of dyes, the production of vat dyes 
was 8.3 percent larger in 1972 than in 1971; the production of disperse 
dyes was 14.5 percent larger; the production of acid dyes was 11.0 percent 
larger; the production of direct dyes was 8.5 percent larger; and the pro- 
duction of fluorescent brighteners was 8.4 percent smaller. 

1972 production of the remaining classes increased over that of 1971 
as follows: Food, drug and cosmetic colors (17.6 percent); solvent dyes 
(17.2 percent); mordant dyes (13.0 percent); basic dyes (8.6 percent). 
Production of two classes decreased: Azoic compositions (28.3 percent) and 
fiber-reactive dyes (0.4 percent). 

Table IB shows production and sales of dyes by chemical class. In 
1972, three chemical classes of dyes accounted for about two-thirds of all 
dyes produced. Azo dyes accounted for 35.0 percent of the total; anthra- 
quinone dyes for 17.7 percent of the total; and stilbene dyes for 11.7 
percent. The production of azo dyes was 12.2 percent larger in 1972 than 
in 1971, that of stilbene dyes was 3.9 percent smaller, and that of the 
anthraquinone dyes, 1.3 percent smaller. 

Of the remaining chemical classes of dyes for which statistics are 
published five exceeded 1971 production by the following percentages; 
methine (43.4), quinoline (20.9), triarylme thane (15.4), xanthene (10.1), 
and cyanine (5.2). Production of five other classes, however, fell below 
1971 levels; phthalocyanine (23.7), nitro (5.9), oxazine (5.7), thiazole 
(4.6) and azoic dyes and components (1.2). 



DYES 
TABLE L— Dyes: U.S, production and sales, 1972 

[Listed below are all dyes for which any reported data on production or sales may be published. (Leaders are used 
where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 2 lists all dyes for which data on production or sales were reported and identifies the manufacturer of each] 



Dye 



:,ooo 

pounds 



Grand total 

ACID DYES 

Total 

Acid yellow dyes, total 

Acid Yellow 11 

Acid Yellow 17 

Acid Yellow 23 

Acid Yellow .^6 

Acid Yellow 38 

Acid Yellow 40 

Acid Yellow 42 

Acid Yellow 54 

Acid Yellow 65 

Acid Yellow 76 

Acid Yellow 99 

Acid Yellow 151 

Acid Yellow 159 

All other 

Acid orange dyes, total 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 24 

Acid Orange 60 

Acid iirange 64 

Acid Orange 74 

Acid Orange 86 

Acid Orange 116 

All other 

Acid red dyes, total 

Acid Red 1 

Acid Red 4 

Acid Red 18 

Acid Red 26 

Acid Red 37 

Acid Red 73 

Acid Red 85 

Acid Red 88 

Acid Red 89 

Acid Red 99 

Acid Red 114 

Acid Red 115 

Acid Red 137 

Acid Red 151 

Acid Red 182 

Acid Red 186 

Acid Red 266 

Acid Red 337 

All other 



263,304 



470 
280 
164 

100 
88 
110 



1,322 

469 

3,641 



799 
1,096 



236 

126 

1,171 

42 

169 

424 

39 

200 

981 



268 

210 

1,412 



1,000 
pounds 



254,536 



1,000 
dollars 



549 
280 
176 

lis 

171 



1,231 

459 

3,026 



570 
315 
280 
870 
222 



182 

722 

1,014 



363 
102 
115 



246 
152 
975 

42 
144 
362 

53 
155 
926 
102 



207 
1,269 



1,224 
662 



545 
151 
179 

115 

170 

2,736 

1,285 

8,580 

8,464 



465 

415 

1,339 

645 

158 

229 

361 

1,656 

2,508 

14,478 



225 
151 

199 
789 
349 

1,552 
65 
514 
958 
130 
592 

2,014 
305 
69 

1,151 
843 

4,397 



See footnotes at end of table. 



SYNTHETIC ORfiANIC CHEMICALS^ 1^7'? 
TABLE 1,— Dyes; U.S. production and sales^ 1972— Continued 



Quantity Value 



ACID DYES--Continued 



1,000 
pounds 



Acid violet dyes, total- 
Acid Violet 1 

Acid Violet 5 

Acid Violet 7 

Acid Violet 12 

Acid Violet 17 

Acid Violet 43 

Acid Violet 49 

All other 



Acid blue dyes, total- 
Acid Blue 7 



Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
Acid B 
All other- 



ue 40- 
ue 41- 



ue 45- 
ue 62- 



ue 78 

ue 113 

ue 118 

ue 120 

ue 158 and 158A- 
ue 230 



Acid green dyes, total- 
Acid Green 3 

Acid Green 9 

Acid Green 16 

Acid Green 20 

Acid Green 25 

All other 



Acid brown dyes, total- 
Acid Brown 14 

All other 



Acid black dyes, 

Acid Black 1 

Acid Black 24-- 
Acid Black 52-- 
Acid Black 107- 
All other 



123 
136 



,535 
368 
126 
532 



AZOIC DYES AND COMPONENTS 

Azoic Compositions 

Total 

c Yellow 1 

c Yellow 2 

c Orange 3 

c Red 1 

c Red 2 

c Red 6 



984 

319 

1,798 



1,000 
pounds 



1,000 
do I lars 



5,021 



35 

1,441 

368 

119 

516 

27 



342 
179 



733 
729 



4,086 



828 

333 

1,962 



194 
156 



366 
248 



16,472 



130 

1,983 

1,979 

446 

2,253 

112 

204 

841 

517 

295 

1,834 



114 

1,155 

639 



1,473 
1,998 



1,632 

976 

4,235 



See footnotes at end of table. 



DYES 



TABLE 1.--DYES: U.S. production and sales> 1972~Continued 



Dye 



AZOIC DYES AND COMPONENTS- -Continued 
Azoic Compositions — Continued 



Azoic Blue 3 

Azoic green dyes- 



Azoic brown dyes, total - 

Azoic Brown 9 

All other 



Azoic black dyes 

All other azoic coinpositions- 



Azoia Diazo Components, 
(Fast Colop Bases) 



Total- 



Azoic Diazo Component 4, base 

Azoic Diazo Component 10, base 

Azoic Diazo Component 32, base 

All other azoic diazo components, bases- 



Azoia Diazo Components, Salts 
(Fast Colop Salts) 



Azoic Diazo 
Azoic Diazo 
Aozic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
Azoic Diazo 
All other a 



Component 1 , sa 

Component 3, sa 

Component S, sa 

Component 8, sa 

Component 9, sa 

Component 10, salt 

Component 1 1 

Component 12 

Component 13 

Component 28, salt 

Component 49, salt 

zoic diazo components, salts- 



salt- 
salt- 
salt- 



Asoia Coupling Components 
(Naphthol AS and Derivatives) 



Total- 



Azoic Coupling Component 14 

Azoic Coupling Component 15 

Azoic Coupling Component 18 

Azoic Coupling Component 19 

Azoic Coupling Component 21 

Azoic Coupling Component 29 

All other azoic coupling components- 



BASIC DYES 



Total- 



asic yellow dyes, 
Basic Yellow 2-- 
Basic Yellow 11- 
Basic Yellow 13- 
All other 



1,000 
pounds 



270 
118 



509 
451 



1,226 



251 

779 



5,395 



404 
1,708 

201 
3,082 



Quantity Value 



1,000 
pounds 



389 
1,009 



400 


369 


495 


604 


569 


473 


477 


453 


646 


103 


107 


113 


331 


308 


252 


27 


27 


41 




31 


56 


418 


358 


391 


452 


372 


531 




165 


193 


88 


84 


267 


669 


335 


553 



17,824 



4,930 



565 
1,506 

221 
2,638 



1,000 
dollars 



270 
344 



1,073 
1,218 



146 


353 


45 


299 


283 


410 



13,546 



1,179 

4,530 

541 

7,296 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1972" 
TABLE 1.~Dyes; U.S. production and sales, 1972— Continued 



Production 



Quantity Value 



BASIC DYES- -Continued 

Basic orange dyes, total 

Basic Orange 2 

Basic Orange 21 

All other 

Basic red dyes, total 

Basic Red 13 

Basic Red 14 

All other 

Basic violet dyes, total 

Basic Violet 1 

Basic Violet 16 

All other 

Basic blue dyes, total 

Basic Blue 5 

All other 

Basic Green 1 

Basic Brown 1 

Basic Brown 4 

All other basic dyes 

DIRECT DYES 

Total 

Direct yellow dyes, total 

Direct Yellow 4 

Direct Yellow 6 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 28 

Direct Yellow 29 

Direct Yellow 44 

Direct Yellow 50 

Direct Yellow 84 

Direct Yellow 105 

Direct Yellow 106 

All other 

Direct orange dyes, total 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange 29 

Direct Orange 54 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 81 

Direct Orange 102 

All other 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

See footnotes at end of tabic. 



1,000 
pounds 



446 
873 
381 



715 
1,765 



3,736 



1,224 

492 

2,020 



5,154 



147 
480 
781 



37.672 



11,595 



498 
494 

2,439 

201 

237 

32 

1,116 
504 
721 
268 

1,068 

4,017 

2,234 



102 
112 

26 
228 
325 
113 

80 
415 
366 



1,000 
pounds 



1,000 
dollars 



483 
917 
536 



664 
1,839 



930 

450 

2,094 



121 
144 
504 
931 



10,792 



497 
467 

2,348 
207 
234 
43 
911 
485 
720 
239 
893 

3,748 



117 
278 



154 
271 
102 

306 
356 



140 
220 



774 
2,398 
1,213 



1,649 
1,454 
5,256 



423 
259 
806 
,139 



19,448 



877 
844 

2,198 

673 

539 

98 

1,915 



554 
1,592 
8,101 



149 
363 
134 
228 
303 



842 
1,146 



278 
474 
176 



DYES 



TABLE 1,--Dyes: U.S. production and sales, 1972--Continued 



Dye 



Quantity Value 



DIRECT DYES--Continued 



Direct red dyes--Cont inued 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 

Direct Red 28 

Direct Red 31 

Direct Red 37 

Direct Red 39 

Direct Red 72 

Direct Red 75 

Direct Red 79 

Direct Red 80 

Direct Red 81 

Direct Red 83 

All other 

Direct violet dyes, total- 
Direct Violet 9 

Direct Violet 51 

All other 

Direct blue dyes, total — 
Direct 



Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 



lue 15 

22 

25 

lue 71 

lue 76 

lue 78 

lue 80 

lue 86 

lue 98 

lue 120 and 120A- 

lue 126 

lue 218 



Dii 

All other 

Direct green dyes, total 

Direct Green 1 -- 

Direct Green 6 

All other 

Direct brown dyes, total 

Direct Brown 2 

Direct Brown 31 

Direct Brown 74 

Direct Brown 95 

Direct Brown 111 

Direct Brown 154 

All other 

Direct black dyes, total 

Direct Black 4 

Direct Black 9 

Direct Black 22 

Direct Black 38 

Direct Black 51 

See footnotes at end of table. 



1,000 
pounds 



361 
105 

174 

107 
162 



378 
,025 
288 
234 
237 



133 
565 
618 
340 
146 
144 
,099 
,646 



234 
404 
216 

1,712 
258 
121 



391 
340 



853 

,701 

69 



1,000 
pounds 



210 
368 
135 



148 
297 
14 
169 
536 
552 
200 
1,111 

282 



320 

926 

298 

191 

158 

15 

56 

118 

65 

129 

476 

652 

268 

142 

121 

1,101 

1,584 

714 
199 
273 
242 



460 
361 



1,000 
dollars 



220 
636 
786 



344 

433 

716 

56 

518 

1,002 

1,350 



11,896 
751 
1,109 
276 
428 
293 
35 
159 
368 
102 
420 
879 



388 
,271 
,529 



282 

495 

1,011 

2,716 
444 
356 



470 
643 



485 

4,566 

203 



552-743 O - 74 - 5 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE L— Dyes: U.S. production and sales, 1972— Continued 



Dye 



Production 



Quantity 



DIRECT DYES- -Continued 

Direct black dyes--Continued 

Direct Black 80 

All other 

DISPERSE DYES 

Total 

Disperse yellow dyes, total 

Disperse Yellow 3 

Disperse Yellow S 

Disperse Yellow 23 

Disperse Yellow 33 

Disperse Yellow 34 

Disperse Yellow 42 

Disperse Yellow 54 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 5 

Disperse Orange 17 

Disperse Orange 25 

All other 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red 15 

Disperse Red 17 

Disperse Red 55 

Disperse Red 60 

Disperse Red 65 

All other 

Disperse violet dyes, total-7 

Disperse Violet 1 

Disperse Violet 4 

Disperse Violet 27 

All other 

Disperse blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 64 

Disperse Blue 95 

All other 

Disperse black dyes, total 

Disperse Black 1 

All other 

All other disperse dyes 



1,000 
pounds 



813 
595 



8,039 



2,810 

75 

820 

358 

158 

714 

1,030 

2,074 

4,746 



130 
492 
,962 



262 
105 
128 
76 
154 
444 

1,845 
230 

4,920 



233 
556 



351 

1,300 

385 



13,583 



335 
1,110 



1,000 
pounds 



403 
504 



1,000 
dollars 



8,293 



3,143 

1,010 

296 

160 

660 

1,048 

1,976 

4,039 



129 

470 

3,294 



70 

88 

89 

169 

489 

1,685 

219 

4,573 



96 

25 

230 

568 

15,665 



330 

1,289 

376 

491 

13,179 

1,268 



273 
995 



4,425 

1,473 
514 
276 
1,333 
4,076 
4,922 

8,632 



166 
914 

7,273 

26,254 



502 

99 

634 

280 

256 

3,016 

5,698 

490 

15,259 

3,503 



496 
2,541 



48,679 



1,641 

2,266 

2,892 

946 

40,934 

2,238 



465 
1,773 



See footnotes at 



if tablf 



DYES 



TABLE 1.--DYES: U.S. production and sales^ 1972— Continued 



Dye 



Quantity 



FIBER-REACTIVE DYES 

Fiber-reactive dyes, total 

Reactive yellow dyes 

Reactive blue dyes 

All other reactive dyes 

FLUORESCENT BRIGHTENING AGENTS 
Total 

Fluorescent Brightening Agent 28 

All other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Total 

Food, Drug, and Cosmetic Dyes 

Total 

FD5C Red No. 2 

FD5C Red No. 3 

FD5C Yellow No. 5 

FDSC Yellow No. 6 

All other food, drug, and cosmetic dyes 

Dpug and Cosmetic and External Drug 
and Cosmetic Dyes 

Total 

D6C Green dyes 

DSC Orange No. 4 

DSC red dyes, total 

DSC Red No. 7 

DSC Red No. 19 

DSC Red No. 21 

DSC Red 36 

All other 

All other drug 6 cosmetic and e.xternal drug S 
cosmetic dyes 

MORDANT DYES 

Total 

Mordant yellow dyes 

Mordant orange dyes 

Mordant red dyes 

Mordant brown dyes, total 

Mordant Brown 1 

Mordant Brown 33 

All other 

Mordant black dyes, total 

Mordant Black 11 --- 

Mordant Black 17 

All other 

See footnotes at end of table. 



1,000 
pounds 



5,699 



481 

749 

2,469 



4,644 



4,351 



971 
292 

1,109 
812 

1,167 



80 
217 



114 
895 



439 
151 
305 



1,000 
pounds 



3,562 



1,000 
dollars 



15,582 



482 

739 

2,341 



1,580 
25,862 



4,323 



1,088 
265 

1,167 
890 
913 



1,711 



6.S1 
139 
287 



2,010 
36,259 



17,752 



2,923 
2,356 
3,601 
2,376 
6,496 



102 
107 



1,027 



160 
353 
251 



857 
164 
215 



SYNTHETIC QR^AHK CHF^ICALS. 1972' 
TABLE 1.— Dyes: U.S. production and sales^ 1972— Continued 



Dye 



1,000 
pounds 



MORDANT DYES--Continued 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 14 

All other 

Solvent orange dyes, total 

Solvent Orange 5 

All other 

Solvent red dyes, total 

Solvent Red 26 

Solvent Red 49 

All other 

Solvent blue dyes, total 

Solvent Blue 38 

All other 

Solvent Green 3 

Solvent Brown 12 

All other solvent dyes 

VAT DYES 

Total 

Vat yellow dyes, total 

Vat Yellow 2, 8-1/2°, 

Vat Yellow 4, 12-1/2-i 

All other 

Vat orange dyes, total 

Vat Orange 1, 20«. 

Vat Orange 2, 12% 

Vat Orange 3, 13-1/2% 

Vat Orange 9, 12% 

Vat Orange 15, 10% 

All other 

Vat red dyes, total 

Vat Red 1, 13^ 

Vat Red 13, 11% 

All other 

Vat violet dyes, total 

Vat Violet 1, 11% 

Vat Violet 9, 12% 

Vat Violet 13, 6-1/4% 

All other 

Vat blue dyes, total 

Vat Blue 6, 8-1/3% 

Vat Blue 18, 13% 

All other 

See footnotes at end of table. 



121 
S19 



2,362 

1,691 

147 
1,544 



1,044 

2,671 
900 
328 



529 
417 
349 



177 
186 



2,911 

656 

28,471 



1,000 
pounds 



614 
965 



131 
1,531 



4,648 



218 
1,111 



999 
416 



267 
171 
504 
152 



1,000 
dollars 



22,319 



3,685 



154 
1,253 



669 
5,332 



9,017 

3,645 

904 

115 

249 

1,317 

2,787 

3,482 
1,028 
1,056 
1,398 



896 

784 
647 



DYES 
TABLE 1.~Dyes; U.S. production and sales, 1972— Continued 



Dye 



Quantity 



Unit 
value' 



1,000 
pounds 



VAT DYES- -Continued 

Vat green dyes, total 

Vat Green 1, 6% 

Vat Green 5, 10°> 

All other 

Vat brown dyes, total 

Vat Brown 1, 1 Ti 

Vat Brown 3, ll^j 

All other 

Vat black dyes, total 

Vat Black 25, 12-1/2% 

Vat Black 27, 12-1/2% 

All other 

All other dyes^ 



1,800 
1,402 
2,179 



826 

644 

3,348 



1,381 

606 

1,327 

23,015 



1,000 
pounds 



1,000 
dollars 



2,187 
1,887 
2,078 

4,986 



875 

808 

3,303 

5,602 



1,503 

688 

1,411 

21,931 



2,101 
2,307 



9,758 



1,549 
1,623 
6,586 



1,746 
1,024 
1,787 



Per 

pound 



1.11 

1.11 



1.77 
2.01 
1.99 



1.27 
1.16 
1.49 

1.27 



.74 



Calculated from rounded figures. 
' Includes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of 
dyes may not be published separately because publication would disclose information received in confidence. 



SYNTHETIC ORGANIC CHENICALS, 1972 
TABLE lA,— Dyes: U.S. production and sales^ by class of application^ 1972 



Class of application 



Quantity 



Unit 
value' 



1,000 
pounds 



Total 

Acid 

Azoic dyes and components: 

Azoic compos itions 

Azoic diazo components, bases (Fast color bases) — 
Azoic diazo components, salts (Fast color salts) — 
Azoic coupling components (Naphthol AS derivatives) 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Vat 

All other^ 



1,000 
:>ounds 

254,536 



1,000 
do I lavs 



29,739 

2,515 
1,226 
3,569 
2,905 
17,999 

39,927 
3,699 
27,321 
4,644 
1,465 
12,468 
55,140 
23,015 



28,039 

2,021 

743 

3,178 

2,360 

17,824 

34,519 

38,327 

3,562 

27,442 

4,609 

1,711 

11,959 

56,311 

21,931 



71,663 

3,397 

1,352 

3,811 

5,693 

48,876 

59,167 

107,576 

15,582 

38,269 

19,788 

2,567 

22,319 

63,312 

16,316 



Per 

pound 



1.68 
1.82 
1.20 
2.41 
2.74 
1.71 
2.81 
4.37 
1.39 
4.29 
1.50 
1.87 
1.12 
.74 



^Calculated from rounded figures. 
Ir.cludes oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. Statistics for these groups of dyes 
may not be published separately because publication would disclose information received in confidence. 



TABLE IB.— Dyes: U.S. production and sales^ by chemical class., 1972 



Chemical class 



Production 



Unit 
value' 



Aminoketone-- 
Anthraquinone 



Azo, total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not specified- 



Azoic 

Cyanine 

Ketone imine — 

Methine 

Nitro 

Oxazine 

Phthalocyanine- 

Quinoline 

Stilbene 

Thiazole 

Tr iaryl me thane - 

Xanthene 

All other^ 



1,000 
pounds 



263.304 



92,028 



39,018 
29,964 
10,540 
2,691 
9,815 

10,264 

916 

455 

5,576 

1,376 

480 

1,381 

2,705 

30,898 

352 

8,903 

1,167 

151 



1,000 
pounds 



254,536 



1,000 
dollars 



87,398 



60 



38,431 
28,403 
9,519 
2,270 
8,775 

8,365 

885 

611 

5,171 

1,253 

537 

1,474 

2,278 

30,538 

365 

8,443 

1,052 

58,032 



172 
,399 



191,561 



95,724 
57,988 
10,985 
3,641 
23,223 

14,316 
2,168 
1,318 

14,752 
2,429 
2,004 
3,365 
7,876 

38,122 
1,032 

20,386 
6,262 

48,526 



per 

pound 



$1.S8 



1.15 
1.60 

2.65 

1.71 
2.45 
2.16 
2.85 
1.94 
3.73 
2.28 
3.46 
1.25 
2.83 
2.41 
5.95 



Calculated from rounded figures. 
^ Includes production and sales of azine, coumarin, indigoid, nitroso, oxidation bases, sulfur, thiazine, and miscel- 
laneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose 
information received in confidence. 



DYES 
TABLE 2. --Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972 

[Dyes for which separate statistics are given in table 1 are marked below with an asterisk (*); dyes not so marked do 
not appear in table 1 because the reported data are accepted in confidence and may not be published. Manufacturers' 
identification codes shown below are taken from table 3. An x signifies that the manufacturer did not consent to 
his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



ACID DYES 



*Acid yellow dyes: 

Acid Yellow 1 I ACY 

Acid Yellow 3 ', ACS 

Acid Yellow 4 SDH 

*Acid Yellow 11 | ATL 

Acid Yellow 14 ' TRC 

*Acid Yellow 17 i ACS 

Acid Yellow 19 BAS 

*Acid Yellow 23 AAP 

Acid Yellow 25 GAP 

Acid Yellow 29 GAP 

*Acid Yellow 34 ACS 

*Acid Yellow 36 ACS 

*Acid Yellow 38 ACS 

*Acid Yellow 40 ALT 

•Acid Yellow 42 AAP 

Acid Yellow 44 AAP 

Acid Yellow 49 ! DUP 

*Acid Yellow 54 ACS 

Acid Yellow 59 VPC 

Acid Yellow 63 AAP 

•Acid Yellow 65 ALT 

Acid Yellow 73 ACS 

*Acid Yellow 76 ACS 

Acid Yellow 79 VPC 

*Acid Yellow 99 CMC 

Acid Yellow 114 TRC 

Acid Yellow 121 GAP 

Acid Yellow 124 ATL 

Acid Yellow 127 TRC 

Acid Yellow 128 ALT 

Acid Yellow 129 TRC 

Acid Yellow 135 GAP 

"Acid Yellow 151 ACY 

Acid Yellow 152 ACY 

*Acid Yellow 159 ACS 

Acid Yellow 174 DUP 

Acid Yellow 175 DUP 

Acid Yellow 190 HST 

Acid Yellow 198 DUP 

Other acid yellow dyes ACY 

*Acid orange dyes : 

Acid Orange 1 GAP 

Acid Orange 2 | ACS 

Acid Orange 5 i ACY 

Acid Orange 6 ACS 

•Acid Orange 7 AAP 

VI 

•Acid Orange 8 ACS 

•Acid Orange 10 ACS 

Acid Orange 12 ACS 

*Acid Orange 24 ACS 

Acid Orange 31 AAP 

Acid Orange 45 ACS 

Acid Orange 51 CMC 

Acid Orange 52 ACS 

Acid Orange 56 GAP 

•Acid Orange 60 ATL 

Acid Orange 62 TRC 



BDO, CMC, VPC. 

ATL, BDO, CMG, DUP, HN, PDC, SDH, TRC, VPC. 

CMC, YAW. 

ACS, ACY, GAP, MRX., PDC, TRC, VPC, WJ , YAW. 

TRC. 

ATL, PDC. 

DUP, GAP, TRC. 

ATL, GAP. 

ATL, DUP, TRC, VPC. 

ACY, GAP, VPC. 

GAP, VPC. 

VPC. 

ACY, HN, TRC, VPC. 

ACS. 

FAB, TRC, YAW. 

SDH. 

GAP, TRC. 

CAP, TRC, VPC. 



ATL, DUP, FAB, GAP, HN, TRC, VPC. 



ALT, FAB, GAP, HN, TRC, VPC. 
TRC, VPC. 



ALT, CMG, GAP, TRC, VPC. 



ACS, ACY, ATL, CPC, DUP, GAF, HN, PDC, TRC, 



ACY, AIL, DUP, 

ACY, ATL, DUP, 

PSC. 

ACY, DUP, GAP, TRC, YAW. 

YAW. 
TRC. 
ATL. 

DUP, GAF, HN, TRC, VPC. 



GAF, HN, TRC, VPC. 
GAF, TRC, VPC, YAW. 



SYNTHETIC 



iC CHEMICALS, 1972 



TABLE 2,— Dyes for which U.S, production or sales were reported, identified 

BY MANUFACTURER, 1972--CoNTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



aCID DYES- -Continued 

*Acid orange dyes--Continued 

Acid Orange 63 

*Acid Orange 64 

Acid Orange 69 

Acid Orange 72 

*Acid Orange 74 

Acid Orange 76 

*Acid Orange 86 

*Acid Orange 116 

Acid Orange 119 

Acid Orange 128 

Acid Orange 132 

Acid Orange 136 

Other acid orange dyes 

*Acid red dyes: 

*Acid Red 1 

*Acid Red 4 

Acid Red 14 

Acid Red 17 

*Acid Red 18 

*Acid Red 26 

Acid Red 27 

Acid Red 32 

Acid Red 35 

Acid Red 35 

•Acid Red 37 

Acid Red 52 

Acid Red 57 

Acid Red 66 

*Acid Red 73 

Acid Red 80 

*Acid Red 85 

Acid Red 87 

*Acid Red 88 

*Acid Red 89 

Acid Red 97 --■ 

*Acid Red 99 

Acid Red 106 

Acid Red 111 

*Acid Red 114 

*Acid Red US 

Acid Red 119 

Acid Red 133 

Acid Red 134 

*Acid Red 137 

Acid Red 138 

*Acid Red 151 

Acid Red 167 

Acid Red 175 

Acid Red 178 

Acid Red 179 

*Acid Red 182 

Acid Red 185 

*Acid Red 186 

Acid Red 191 

Acid Red 194 

Acid Red 201 

Acid Red 211 

Acid Red 212 

Acid Red 213 

*Acid Red 266 

Acid Red 277 

Acid Red 299 

Acid Red 509 



GAF, 


TRC. 














ACS, 


ACY, 


DUP. 












ACY. 
















GAF. 
















CMG, 


GAF, 


TRC . 












TRC. 
















ACS, 


ALT, 


CMG, 


IRC. 










ACS, 


ALT, 


CMG, 


FAB, 


GAF, 


TRC, 


VPC, 


YAW. 


TRC. 
















DUP. 
















DUP. 
















DUP. 
















ALT, 


GAF, 


TRC, 


VPC. 










ACS, 


ACY, 


ATL, 


BDO, 


DUP 


GAF, 


SDH, 


TRC, VPC, YAW 


AAP, 


ATL, 


BDO, 


GAF, 


PDC 


TRC, 


VPC, 


YAW. 


ACS, 


ATL, 


GAF, 


PDC, 


YAW 








ACS, 


ATL, 


TRC. 












ACS, 


ATL, 


BDO, 


GAF, 


TRC 








ACY, 


ATL, 


CPC. 












ACS. 
















GAF. 
















YAW. 
















AAP, 


GAF. 














ACS, 


ATL, 


DUP, 


GAF, 


HN, 


TRC. 






GAF. 
















AIL, 


TRC. 














AAP, 


ATL. 














ACS, 


ACY, 


ATL, 


DUP, 


GAF 


PSC 


TRC 


VPC, YAW. 


ATL, 


ICI. 














ACb, 


ALT, 


DUP, 


GAF, 


HN, 


VPC, 


YAW. 




SDH. 
















ACS, 


ACY, 


AIL, 


UUP, 


GAF 


TRC 


SDH 


YAW. 


AAP, 


ATL, 


BDO, 


GAF, 


HN. 








ATL, 


GAF. 














ATL, 


FAB, 


HN, 


TRC, 


YAW . 








YAW. 
















ATL. 
















ACS, 


ALT, 


.ATL 


DUP, 


GAF 


TRC 


VPC 




ACb, 


AIL, 


GAF 












ALT, 


ATL. 














GAF. 
















TRC. 
















ACS, 


ATL, 


DUP, 


GAF 


HN, 


TRC. 






ALT. 
















AAP, 


ACY, 


ALT 


ATL 


DUP 


HN, 


TRC, 


VPC, YAW. 


ACS, 


ATL, 


DUP, 


TRC 










DUP. 
















DUP. 
















TRC 
















ACS, 


ALT, 


ATL, 


BDO 


CMG 


DUP 


GAF 


HN. 


TRC 
















ATL 


CMG, 


GAF 


VPC 










TRC 
















TRC 
















TRC 
















DUP 
















TRC 
















TRC 
















DUP 


TRC 


VPC 












VPC 
















ALT 


TRC 














TRC 

















DYES 



TABLE 2. 



-Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



ACID DYES--Continued 



et dyes : 
olet 1-- 



t dye 



*Acid red dyes--Continued 

•Acid Red 337 

Acid Ked 350 

Other acid red dyes 

*Acid vio 
•Acid V 
*Acid V 
*Acid V 
*Acid V 
*Acid V 

Acid V 

Aciv V 

Acid V 
•Acid V 
•Acid V 

Acid V 

Acid V 

Acid V 

Other a 
•Acid blue 

Acid B 
•Acid B 
•Acid B 

Acid B 

Acid B 

Acid B 
•Acid B 
•Acid B 

Acid B 

Acid B 
•Acid B 
•Acid B 
*Acid B 
•Acid B 
•Acid B 

Acid B 

Acid B 

Acid B 
•Acid B 

Acid B 

Acid B 

Acid B 

Acid B 

Acid B: 

Acid B 

Acid B 
•Acid B 

•Acid B 

•Acid B 

Acid B 

Acid B 

Acid B 

•Acid B 

Acid B 

Acid B 

Acid B 

Acid B 

Acid B 

♦Acid B 

Acid B 



DUP, TRC, VPC. 
GAF. 

ALT, CMC, DUP, GAF, TRC, VPC. 



olet 3--- 
olet 7--- 
olet 12-- 
olet 17-- 
olet 29-- 
olet 34-- 
olet 41-- 
olet 43-- 
olet 49-- 
olet 56-- 
olet 58-- 
olet 76-- 
cid violf 
dyes : 

ue 1 

ue 7 

ue 9 

ue 15 

ue 20 

ue 23 

ue 25 

ue 27 

ue 29 

ue 34 

ue 40 

ue 41 

ue 43 

ue 45 

ue 62 



ue 74- 
ue 78- 



ue 104- 
ue 113- 



ue 118 

ue 120 

ue 122 

ue 127 

ue 145 

ue 158 and 158A- 

ue 165 

ue 179 

ue 198 

ue 203 

ue 221 

ue 230 

ue 231 



Other acid blue dyes- 



BDO 
ACS 
AAP 
BDO 
DUP 
HSH 
AIL 
CMG 
ATL 
ACS 
GAF 
GAF 
ACS 
CMG 

ACS 
ACS 
ACS 
GAF 
ACS 
TRC 
ACS 
ATL 
PDC 
ACS 
ACS 
ATL 
ACS 
ACY 
ACS 
CMG 
GAF 
ACS 
ACS 
ATL 
ICI 
GAF 
TRC 
ACS 
HSC 
ACS 
ACS 
Tl 
ACS 
ACS 
DUP 
CMG 
ACS 
BDO 
DUP 
GAF 
VPC 
VPC 
VPC 
ACS 
TRC 
ACY, ALT, ATL, GAF, HN, TRC, VPC. 



CMG, GAF. 

ACY, TRC, YAW. 

ACS, ATL, BDO, CMG, GAF, TRC, VPC. 

CMG, DUP, GAF. 

GAF, SDH. 

ICI. 

CMG, HSH, ICI. 

ACY, SDH, FRC. 



GAF. 

ACY, ATL, GAF, VPC. 

GAF, SDH. 



ATL, BDO, CMG, DUP, GAF, TRC, VPC. 

BDO, CMG, GAF. 

YAW. 

ALT, ATL, BDO, CMG, DUP, GAF, ICI, TRC, VPC. 

BDO, CMG. 

ICI, TRC. 

ATL, CMC, DUP, GAF, HN, TRC. 

ALT, BDO, CMG, GAF. 



DUP. 

ATL, BDO, DUP, GAF, ICI, IRC. 

TRC. 



ATL, YAW. 

GAF. 

ALT, ATL, BDO, CMG, UUP, FAB, GAF, HN, PDC, 
:, YAW. 
ATL, HN. 
ATL, GAF. 



DUP. 

CMG, GAF, HN, TRC, VPC. 



SYNTHETIC ORGANIC CHEMICALS, 1972 ■ 
TABLE 2. —Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972--CONTINUED 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



ACID DYES--Continued 

"Acid green dyes: 

Acid Green 1 

*Acid Green 3 

Acid Green 5 

*Acid Green 9 

Acid Green 12 

*Acid Green 16 

Acid Green 19 

*Acid Green 20 

Acid Green 22 

*Acid Green 25 

Acid Green 35 

Acid Green 41 

Acid Green 50 

Acid Green 58 

Acid Green 70 

Acid Green 84 

Other acid green dyes 

*Acid brown dyes: 

Acid Brown 1 

Acid Brown 6 

*Acid Brown 14 

Acid Brown 19 

Acid Brown 22 

Acid Brown 28 

Acid Brown 31 

Acid Brown 45 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 243 

Other acid brown dyes 

*Acid black dyes : 

*Acid Black 1 

Acid Black 2 

*Acid Black 24 

Acid Black 26, 26A and 26B 

Acid Black 29 

Acid Black 48 

*Acid Black 52 

Acid Black 53 

Acid Black 58 

Acid Black 60 

Acid Black 92 

*Acid Black 107 

Acid Black 108 

Acid Black 139 

Acid Black 140 

Acid Black 172 

Other acid black dyes 

AZOIC DYES AND COMPONENTS 

Azoic Compositions 

Azoic yellow dyes: 

'Azoic Yellow 1 

*Azoic Yellow 2 

Azoic Yellow 3 

Other azoic yellow dyes 



ACS 


ACY, 


DUP. 








ACS 


ACY, 


GAP, 


TRC 






CAP 












ACS 


ACY, 


GAP 








GAP 












ACS 


GAP, 


TRC. 








ALT 












ATL 


BDO, 


GAP, 


PDC 


TRC 




GAP 












ACS 


ATL, 


GAP, 


HSH 


ICI 


TRC, VPC 


TRC 












ICi 


VPC. 










ACY 


GAP. 










TRC 












TRC 












VPC 












ACY 


ALT, 


VPC. 








GAP 












GAP 












AAP 


ACY, 


DUP. 


GAP 


TRC 


YAW. 


TRC 












DUP 












TRC 












GAP 












TRC 












ACY 












ACY 












ACY 


TRC, 


YAW. 








GAP 












GAP 












GAP 












ACY 


ALT, 


DUP, 


GAP 


VPC 


YAW. 


AAP 


ACS, 


ACY, 


ATL 


DUP 


GAP, HN, 


ACS 


ACY. 










ACS 


DUP, 


GAP. 








ATL 


DUP, 


TRC 








GAP 


YAW. 










ACY 


TRC. 










ACS 


ATL, 


DUP, 


PAB 


GAP 


HN, TRC, 


PSC 












CMC 


TRC . 










BOO 


TRC. 










ACY 












ACS 


DUP, 


GAP, 


TRC 






GAP 












VPC 












CMC 












VPC 












ALT 


ATL, 


UN, 


PDC, 


VPC, 


YAW. 



ALL, ATL, SDH. 

ALL, ATL, BUC, 

ATL, BUC. 
ATL. 



DYES 

TABLE 2.— Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972~CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



AZOIC DYES AND COMPONENTS- -Continued 
Azoic Compositions- -Continued 

Azoic orange dyes: 

*Azoic Orange 3 

Azoic Orange 10 

Azoic red dyes: 

*Azoic Red 1 

*Azoic Red 2 

"Azoic Red 6 

Azoic Red 12 

Azoic Red 16 

Azoic Red 73 

Azoic Red 74 

Other azoic red dyes 

Azoic violet dyes: 

Azoic Violet 1 

Other azoic violet dyes 

Azoic blue dyes : 

Azoic Blue 2 

*Azoic Blue 3 

Azoic Blue 6 

Azoic Blue 7 

Other azoic blue dyes 

•Azoic green dyes: 

Azoic Green 1 

Other azoic green dyes 

Azoic brown dyes: 

Azoic Brown 3 

Azoic Brown 7 

•Azoic Brown 9 

Azoic Brown 10 

Azoic Brown 26 

Other azoic brown dyes 

*Azoic black dyes: 

Azoic Black 1 

Azoic Black 4 

Azoic Black 15 

Other azoic black dyes 

Azoic Diazo Components, Bases 
(Fast Color Bases) 

Azoic Diazo Component 2, base 

Azoic Diazo Component 3, base 

*Azoic Diazo Component 4, base 

Azoic Diazo Component 5, base 

Azoic Diazo Component 8, base 

*Azoic Diazo Component 10, base 

Azoic Diazo Component 11, base 

Azoic Diazo Component 12, base 

Azoic Diazo Component 13, base 

Azoic Diazo Component 14, base 

Azoic Diazo Component 28, base 

*Azoic Diazo Component 32, base 

Azoic Diazo Component 34, base 

Azoic Diazo Component 44, base 

Azoic Diazo Component 46, base 

Azoic Diazo Component 48, base 

Other azoic diazo components, base 



ALL, 


ATL, 


BUC, 


X. 






BUC. 












ALL, 


ATL, 


BUC, 


SDH, 


X. 




ALL, 


ATL, 


BUC, 


GAF, 


X. 




AIL, 


BUC, 


SDH, 


X. 






ATL. 












ATI. 












GAF. 












GAP. 












ALL, 


X. 










ATL, 


BUC. 










ALL. 












ATL. 












ALL, 


ATL, 


BUC, 


GAF, 


HST, 


SDH, X 


ATL. 












GAF. 












ATL, 


GAF. 










ATL. 












ALL, 


BUC. 










X. 












ATL, 


BUC. 










ALL, 


.ATL, 


BUC, 


GAF, 


HST, 


VPC, X 


ATL, 


BUC. 










GAF. 












ALL, 


ATL, 


GAF, 


VPC. 






HST. 












ATL, 


BUC, 


GAF. 








GAF. 












ALL, 


ATL, 


GAF. 









ATL, BUC. 

BUC. 

ALL, BUC, GAF, SDH. 

ATL, GAF. 

SDH. 

ATL, BUC, GAF. 

ATL. 

BUC, SDH. 

ATL, BUC. 

AAP. 

ALL, BUC, GAF. 

ALL, ATL, BUC. 

ALL. 

BUC. 

ATL. 

GAF. 

ALL. 



SYNTHETIC ORGANICAL CHEMICALS. 1°72 
TABLE 2,— Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER. 1972~CONTINUED 



Manufacturers' identification codes 
(according to list in table 3J 



AZOIC DYES AND COMPONENTS--Continued 



Azoic Diazo Components, Salts 
(Fast Colov Salts) 



*Azoic 
Azoic 
♦Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
Azoic 
Azoic 
*Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
*Azoic 
Azoic 
Other 



AZOIC 

Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 

*Azoic 

*Azoic 
Azoic 
Azoic 

*Azoic 

*Azoic 
Azoic 

*Azoic 
Azoic 

*Azoic 
Azoic 
Azoic 

*Azoic 
Azoic 
Other 



Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
azoic 



salt- 
salt- 
salt- 
salt- 
salt- 



salt-- 
salt- 
salt- 



Component 1 
Component 2 
Component 3 
Component 5 
Component 6 
Component 8 
Component 9 
Component 10 
Component 11 
Component 12, salt 
Component 13, salt 
Component 14, salt 
Component 
Component 
Component 32, salt 

14, salt 

15, salt 

16, salt 
;7, salt 



salt- 
salt- 



Component 
Component 
Component 
Component 

Component 41, salt 

Component 42, salt 

Component 44, salt 

Component 48, salt 

Component 49, salt 

Component 121, salt 

diazo components, salts 

Azoio Coupling Components 
(Naphthol AS and Derivatives ) 



Coupling Component 2 

Coupling Component 3 

Coupling Component 4 

Coupling Component 5 

Coupling Component 7 

Coupling Component 8 

Coupling Component 10 

Coupling Component 11 

Coupling Component 12 

Coupling Component 13 

Coupling Component 14 

Coupling Component IS 

Coupling Component 16 

Coupling Component 17 

Coupling Component 18 

Coupling Component 19 

Coupling Component 20 

Coupling Component 21 

Coupling Component 24 

Coupling Component 29 

Coupling Component 34 

Coupling Component 35 

Coupling Component 45 

Coupling Component 107 

azoic coupling components- 



AAP, ALL, 
BUC. 

AAP, ALL, 

AAP, ALL, 

AAP, BUC, 

AAP, ALL, 

AAP, ALL, 

ALL, BUC, 

AAP, ALL, 

AAP, ALL, 

AAP, ALL. 
AAP. 

ALL, BUC. 

ALL, BUC, 
ALL. 

ALL, GAP. 

BUC, GAP. 
GAP. 
GAP. 

ALL, BUC. 

ALL, GAP. 

ALL, BUC. 

BUC, SDH. 

AAP, ALL, 
GAP. 
ALL. 



BUC, GAP, SDH. 

BUC, GAP, SDH. 

BUC, GAP, SDH. 

GAP. 

BUC, GAP. 

BUC, GAP , SDH. 

GAP. 

BUC. 

BUC, GAP, SDH. 

BUC, GAP, SDH. 



GAP, SDH. 



AIL, 


BUC, 


GAP, 


PCW. 


ALL, 


BUC, 


PCW. 




ATL, 


BUC, 


GAP. 




BUC. 








BUC, 


HST, 


PCW, 


SDH. 


ATL, 


BUC, 


PCW. 




ATL, 


PCW. 






ATL, 


BUC, 


PCW. 




ATL, 


BUC, 


PCW . 




GAP, 


HST. 






ATL, 


BUC, 


PCW. 




ALL, 


BUC, 


GAP, 


PCW. 


BUC. 








ATL, 


BUC, 


PCW. 




ALL, 


ATL, 


BUC, 


GAP, PCW 


BUC, 


GAP, 


PCW. 




ATL, 


BUC, 


GAP, 


PCW. 


ATL, 


BUC, 


PCW. 




PCW. 








ATL, 


BUC, 


PCW. 




ATL, 


BUC, 


PCW. 




ALL, 


BUC, 


HST, 


PCW. 


ATL, 


BUC, 


GAP. 




HST. 








ATL, 


GAP, 


VPC. 





DYES 

TABLE 2,— Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURER^ 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



BASIC DYES 

*Basic yellow dyes: 

Basic Yellow 1 

*Basic Yellow 2 

*Basic Yellow 11 

*Basic Yellow 15 

Basic Yellow 15 

Basic Yellow 21 

Basic Yellow 28 

Basic Yellow 29 

Basic Yellow 51 

Basic Yellow 57 

Basic Yellow 41 

Basic Yellow 52 

Basic Yellow 53 

Other basic yellow dyes 

*Basic orange dyes: 

Basic Orange 1 

*Basic Orange 2 

*Basic Orange 21 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 27 

Basic Orange 28 

Basic Orange 51 

Basic Orange 39 

Other basic orange dyes 

*Basic red dyes: 

Basic Red 1 

Basic Red 2 

Basic Red 9 

Basic Red 12 

*Basic Red 13 

•Basic Red 14 

Basic Red 15 

Basic Red 16 

Basic Red 17 

Basic Red 18 

Basic Red 19 

Basic Red 22 

Basic Red 29 

Basic Red 30 

Basic Red 46 

Basic Red 49 

Basic Red 73 

Other basic red dyes 

*Basic violet dyes: 

•Basic Violet 1 

Basic Violet 2 

Basic Violet 3 

Basic Violet 4 

Basic Violet 7 

Basic Violet 10 

Basic Violet 11 

Basic Violet 13 

Basic Violet 14 

Basic Violet 15 

•Basic Violet 16 

Basic Violet 18 

Basic Violet 24 

Other basic violet dyes 



DUP 
ACS 
ACS 
ACS 
DUP 
ACS 
VPC 
DUP 
DUP 
ACY 
ACY 
DUP 
DUP 
AIL 

ACS 
ACS 
ACS 
DUP 
DUP 
DUP 
VPC 
VPC 
ACY 
DUP 
DUP 

BAS 
ACS 
DSC 
ACY 
ACS 
ACS 
ATL 
DUP 
DUP 
ATL 
DUP 
ACY 
BAS 
ACY 
ACS 
DUP 
DUP 
ATL 

ACS 
DSC 
DSC 
DSC 
ATL 
ACY 
ACY 
DSC 
DSC 
DUP 
ATL 
ACY 
DUP 
ACY 



ACY, DUP. 

ACY, ATL. DUP. GAF, TRC, VPC. 

.ATL, DUP, GAF, VPC. 



VPC. 
DUP. 



BAS, DUP, EKT, GAF. 

ACY, DUP, GAF, PSC, TRC. 

ACY, DSC, DUP, GAF, PSC, TRC. 

ALT, ATL, DUP, GAF, TRC, VPC. 



DUP. 

DUP. 

HSC. 

DUP. 

ATL, GAF, TRC, VPC. 

ACY, ATL, DUP, FAB, GAF, VPC. 

DUP, GAF, TRC. 



DUP, GAF, VPC. 
TRC. 



TRC. 
GAF. 



DUP, EKT, VPC. 

ACY, DSC, DUP, HSC. 

DUP. 
DUP. 
GAF. 
DUP, GAF. 



DUP. FAB, GAF, TRC, VPC. 



SYNTHETIC ORGANIC CHEfllCALS. Wl 



TABLE 2, 



-Dyes for which U,S, production or sales were reported, identified 
by manufacturer, 1972--c0ntinued 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



BASIC DYES--Continued 



*Basic blue dyes 
Basic B] 
Basic B] 
Basil 
Basic Bl 
*Basic 
Basic 
Basic Bl 
Basic Bl 
Basic Bl 
Basic Bl 
Basic Bl 
Basic B] 
Basic B] 
Basic Bl 



ue 



Basic B] 

Basic B] 

Basic B] 

Basic Bl 

Basic Bl 

Basic B] 
Basi 

Basic Bl 
Basil 
Basi( 



ue 11- 
ue 21- 
ue 22- 
ue 26- 
ue 3S- 
ue 41- 
ue 45- 
ue 47- 



ue 76- 
ue 77- 
ue 82- 



lue 87 

lue 97 

Other basic blue dyes-- 
Basic green dyes: 

*Basic Green 1 

Basic Green 3 

Basic Green 4 

Basic green 7 

Basic brown dyes; 

*Basic Brown 1 

Basic Brown 2 

*Basic Brown 4 

Other basic brown dyes- 
Basic black dyes : 

Basic Black 9 

Other basic black dyes- 



DIRECT DYES 



•Direct yellow dyes; 

'Direct Yellow 4-- 

Direct Yellow 5-- 

*Direct Yellow 6-- 

Direct Yellow 7-- 

Direct Yellow 8-- 

*Direct Yellow 11- 

•Direct Yellow 12- 

Direct Yellow 20- 

Direct Yellow 23- 

Direct Yellow 26- 

Direct Yellow 27- 

*Direct Yellow 28- 

*Direct Yellow 29- 

Direct Yellow 34- 

Direct Yellow 39- 

Direct Yellow 41- 

*Direct Yellow 44- 

*Direct Yellow 50- 

Direct Yellow 59- 



DSC, 


GAP, 


SDH, 


VPC. 


DSC. 








DUP, 


GAP, 


HST. 




DUP. 








DSC, 


SDH, 


VPC. 




ACY. 








DSC, 


DUP, 


SDH. 




ACS, 


ACY, 


DUP. 




DSC, 


SDH. 






DUP. 








ACS, 


DUP. 






DSC, 


DUP. 






DUP. 








IRC. 








VPC. 








VPC. 








ACY, 


BAS. 






GAP. 








VPC. 








EKT. 








ACY. 








DUP. 








DUP, 


TRC. 






DUP. 








DUP. 








ACS, 


ALT, 


BAS, 


EKT, VPC 


ACS, 


ACY, 


DSC, 


DUP. 


DUP. 








ACS, 


ACY, 


DSC, 


DUP, VPC 


DSC. 









ACS, ACY, DUP, GAP, PSC, TRC. 

GAP. 

ACS, ACY, DSC, DUP, GAP, PSC, TRC. 

DUP. 

VPC. 

ALT, DSC, VPC. 



ACS, 
ACS, 
ACS, 
ATL. 
ACS, 
ACS, 
ACS, 
TRC. 
DUP. 
ATL, 
GAP. 
ACS, 
ATL, 
ALT, 
TRC. 
ATL. 
ACS, 
ALT, 
ATL. 



ACY, ATL, DUP, GAP, 

ACY, GAP. 

ACY, DUP, GAP, TRC. 



HN, TRC, VPC. 



ATL, GAP. 

ACY, ALT, DUP, GAP, HN, SDH, TRC, VPC. 

ACY, ATL, CMC, DUP, FAB, GAP, HN, TRC. 



ATL, DUP, GAP, PDC, TRC. 
DUP, GAP. 



ATL, DUP, FAB, GAP, HN, HSH, TRC, VPC. 
■ATL, DUP, PAB, GAP, HN, HSH, TRC, VPC. 



DYES 

TABLE 2.--DVES for which U.S. production or sales were reported^ identified 
BY manufacturer, 1972--Continued 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES--Continued 

'Direct yellow dyes--Continued 

Direct Yellow 63 

Direct Yellow 81 

♦Direct Yellow 84- 

Direct Yellow 103 

♦Direct Yellow 105 

•Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 114 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 119 

Direct Yellow 120 

Direct Yellow 127 

Direct Yellow 131 

Direct Yellow 132 

Other direct yellow dyes 

♦Direct orange dyes: 

Direct Orange 1 

Direct Orange 6 

♦Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

♦Direct Orange 15 

♦Direct Orange 26 

♦Direct Orange 29 

♦Direct Orange 54 

♦Direct Orange 37 

♦Direct Orange 39 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

♦Direct Orange 72 

♦Direct Orange 73 

Direct Orange 74 

Direct Orange 78 

Direct Orange 79 

Direct Orange 80 

♦Direct Orange 81 

Direct Orange 83 

Direct Orange 88 

♦Direct Orange 102 

Direct Orange 110 

Other direct orange dyes 

♦Direct red dyes: 

♦Direct Red 1 

♦Direct Red 2 

♦Direct Red 4 

Direct Red 7 

Direct Red 10 

Direct Red 13 

♦Direct Red 16 

Direct Red 20 

♦Direct Red 23 

♦Direct Red 24 

♦Direct Red 26 

♦Direct Red 28 

♦Direct Red 31 

Direct Red 32 

♦Direct Red 37 



DUP. 
AIL. 
ATL, 
ACS. 
ALT, 
ACS, 
ACS, 
ACY. 
TRC. 
TRC. 
DUP. 
DUP. 
DUP, 
DUP. 
VPC . 
AAP, 

AAP, 
ACS. 
ACS, 
AAP. 
GAP. 
ACS, 
ACS, 
ATL, 
ACS, 
ACY, 
ACY, 
DUP, 
TRC. 
VPC. 
ACS, 
DUP, 
DUP, 
VPC. 
DUP. 
VPC. 
DUP, 
GAP. 
DUP. 
ACS, 
TRC. 
ALT, 

DUP, 
ACS, 
ACS. 
ATL. 
AAP. 
YAW. 
ACS, 
ATL, 
ACS, 
AAP, 
ACS, 
ACS, 
ACS, 
ACS. 
ACS, 



DUP, FAB, GAP, HN, TRC, VPC. 

HN, TRC. 

ALT, FAB, GAF, UN, TRC. 

TRC. 



ACY, ALT, ATL, DUP, FAB, GAF, HSH, TRC, VPC. 
ALT, ATL, BDO. 
DUP, FAB, GAF, YAW. 



ACY, DUP, GAF, HN, TRC. 

ATL, GAF, HSM, TRC. 

FAB, HN, TRC, VPC. 

ATL, CMG, DUP. GAF. 

ATL, CMG, GAF. 

ALT, ATL, CMG, DUP, FAB, GAF, UN. 

GAF. 



ATL, FAB, »i, HSH, IRC, VPC. 

GAF, TRC, VPC. 

HSH. 



ACY, ATL, DUP, GAF. 

ATL. 

FAB, GAF, TRC, YAW. 

ATL, DUP, FAB, HN, TRC. 

ATL, TRC, VPC. 



ATL, DUP, TRC. 

GAF. 

ATL, DUP, FAB, GAF, HN, TRC, VPC. 

ACS, ATL, FAB, HN, HSH, TRC, VPC. 

ATL, DUP, FAB, GAF, HN, HSH, TRC. 

DUP, FAB, YAW. 

ATL, GAF, HSH. 

DUP, GAF, YAW. 



SYNTHETIC ORG'\NIC CHEMICALS. 1972 
TABLE 2,— Dyes for which U.S. production or sales were reported, identified 

BY manufacturer. 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES--Continued 

*Direct red dyes--Continued 

♦Direct Red 39 

Direct Red 62 

♦Direct Red 72 

Direct Red 73 

♦Direct Red 75 

Direct Red 76 

♦Direct Red 79 

♦Direct Red 80 

♦Direct Red 81 

♦Direct Red 83 

Direct Red 84 

Direct Red 95 

Direct Red 100- 

Direct Red 117 

Direct Red 120 

Direct Red 122 

Direct Red 12i--=- 

Direct Red 127 and 127A 

Direct Red 139 

Direct Red 149 

Direct Red 152 

Direct Red 153 

Direct Red 209 

Direct Red 212 

Direct Red 236 

Other direct red dyes 

♦Direct violet dyes; 

Direct Violet 7 

♦Direct Violet 9 

Direct Violet 14 

Direct Violet 22 

Direct Violet 47 

Direct Violet 48 

♦Direct Violet 51 

Direct Violet 62 

Direct Violet 66 

Direct Violet 67 

Other direct violet dyes 

♦Direct blue dyes: 

♦Direct Blue 1 

♦Direct Blue 2 

♦Direct Blue 6 

♦Direct Blue 8 

Direct Blue 14 

♦Direct Blue 15 

♦Direct Blue 22 

Direct Blue 24 

♦Direct Blue 25 

Direct Blue 26 

Direct Blue 67 

♦Direct Blue 71 

Direct Blue 74 

Direct Blue 75 

♦Direct Blue 76 

♦Direct Blue 78 

♦Direct Blue 80 

Direct Blue 81 

♦Direct Blue 86 



ATL 
ATL 
ACS 
ACS 
ATL 
GAP 
ATL 
ACS 
ACS 

v: 

ACS 
ATL 
VPC 
ATL 
DUP 
CMC 
ATL 
ATL 
ATL 
VPC 
ATL 
CMC 
ATL 
TRC 
VPC 
DUP 
ALT 

ACS 
ACS 
AIL 
DUP 
GAP 
ACS 
ACS 
ACY 
ATL 
DUP 
ALT 



AAP 
AAP 
ACS 
ACS 
ACS 
ACS 
ATL 
ACS 
ATL 
ATL 
ACS 
DUP 
TRC 
ACS 
ACS 
ACS 
ATL 
ALT 



DUP, GAP, TRC, YAW. 

TRC. 

ATL, DUP, GAP, IRC. 

ATL. 

CMG, GAP. 

CMC, HN, TRC, VPC. 

ALT, ATL, FAB, HN, HSH, SDH, TRC, VPC. 

ACY, ALT, ATL, BDO, DUP, GAP, HN, HSH, PDC, TRC, 
PC, YAW. 

ALT, ATL, PAB, HN, HSH, TRC, VPC. 



TRC, VPC. 

GAP. 

CMG. 



CMG. 
VPC. 



ATL, DUP, GAP, HN, HSH, TRC, VPC. 



ATL. 

ATL, UUP, GAP, HN, TRC. 



ATL, DUP. 

TRC. 

VPC. 

ACS, ACY, ATL, CMG, DUP, PAB, GAP, HN, IRC, 
:, YAW. 

ACS, DUP, FAB, GAP, HN, HSH, TRC, VPC, YAW. 
ACS, ACY, DUP, GAP, HN, HSH, YAW. 
ALT, ATL, DUP, GAP. 
ATL, HN, TRC. 
ATL, DUP, GAP, VPC, YAW. 
ATL, CMG. 
YAW. 
ATL, GAP, TRC, YAW. 

TRC. 

ATL, GAP, TRC. 



ALT, ATL, GAP, HN, HSH, TRC, VPC. 

ATL, CMG, DUP, TRC. 

ALT, ATL, DUP, FAB, GAP, HN, HSH, TRC, VPC. 

ATL, DUP, PAB, GAP, HN, ICC, SDH, TRC. 



DYES 
TABLE 2.— Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES--Continued 



Direct Bl 

*Direct 

Direct Bl 

Direct Bl 

•Direct Bl 

♦Direct Bl 

Direct Bl 

Direct Bl 

Direct Bl 

Direct Bl 

Direct Bl 
Direc 

Direct Bl 

•Direct Bl 

Direct Bl 

Direct Bl 



•Direct blue dyes- -Continued 

Direct Blue 87 

lue 91 

lue 98 

lue 100 

lue 104 

lue 120 and 120A-- 

lue 126 

lue 136 

lue 143 

lue 151 

lue 160 

lue 189 

lue 191 

lue 199 

lue 218 

lue 224 

lue 263 

Other direct blue dyes 

•Direct green dyes : 

•Direct Green 1 

•Direct Green 6 

Direct Green 8 

Direct Green 26 

Direct Green 27 

Direct Green 28 

Direct Green 38 

Direct Green 39 

Direct Green 45 

Direct Green 47 

Direct Green 51 

Direct Green 69 

Other direct green dyes — 
•Direct brown dyes : 

Direct Brown 1 

Direct Brown lA 

*Direct Brown 2 

Direct Brown 6 

•Direct Brown 31 

Direct Brown 32 

Direct Brown 40 

Direct Brown 44 

Direct Brown 48 

Direct Brown 59 

•Direct Brown 74 

•Direct Brown 95 

Direct Brown 106 

•Direct Brown 111 

Direct Brown 112 

•Direct Brown 154 

Direct Brown 218 

Other direct brown dyes 

•Direct black dyes: 

•Direct Black 4 

Direct Black 8 

•Direct Black 9 

Direct Black 17 

Direct Black 19 

•Direct Black 22 

Direct Black 36 



ICI. 
















TRC. 
















ATL, 


GAF, 


TRC, 


VPC 










ALT, 


FAB, 


HN. 












DUP. 
















ATL. 


DUP, 


FAB, 


HN, 


TRC. 








ATL, 


UUP, 


HSH, 


TKC 


VPC. 








GAP. 
















DUP. 
















ATL, 


TRC. 














TRC. 
















FAB, 


TRC. 














AAP, 


ACS, 


GAF. 












DUP, 


GAF. 














ACS, 


ALT, 


ATL, 


DUP 


FAB 


GAF 


HN, 


TRC. VPC 


ATL. 
















DUP. 
















ALT, 


ATL, 


DUP, 


GAF 


VPC 








AAP, 


ACS, 


DUP, 


FAB 


GAF 


TRC 


YAW 




AAP, 


ACS, 


DUP, 


FAB 


GAF 


HN, 


TRC, 


YAW. 


TRC. 
















DUP, 


TRC. 














DUP, 


TRC. 














TRC. 
















DUP, 


GAF. 














GAF. 
















ATL, 


VPC. 














ATL, 


DUP, 


GAF. 












TRC. 
















TRC. 
















ACY, 


ALT, 


TRC. 












HN. 
















GAF, 


TRC, 


YAW. 












AAP, 


ACS, 


ACY, 


DUP 


FAB, 


GAF 


HN, 


HSH, TRC 


YAW. 
















AAP, 


ATL, 


DUP, 


GAF 


YAW 








GAF. 
















AAP. 
















GAF, 


YAW. 














AAP. 
















YAW 
















AAP, 


ACS, 


DUP. 












ACS, 


ATL, 


DUP, 


FAB 


GAF 


HN, 


HSH, 


TRC, YAW 


GAF. 
















DUP, 


GAF, 


TRC, 


VPC 










ATL. 
















ACS, 


DUP, 


FAB, 


YAW 










ACS. 
















ALT, 


HSH, 


VPC. 












ACS, 


FAB, 


GAF, 


HN, 


YAW. 








YAW. 
















ACS, 


ATL, 


DUP. 












GAF. 
















ATL, 


HN, 


TRC. 












ALT, 


ATL, 


GAF, 


HN, 


TKC, 


VPC, 


YAW. 




AAP. 

















552-743 O - 74 - 6 



SYNTHETIC nRfiflNIC CHEniCai.S, 1972 

TABLE 2. —Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 1972--Continued 



DIRECT DYES--Continued 

'Direct black dyes--Continued 

Direct Black 37 

♦Direct Black 38 

Direct Black 44 

•Direct Black 51 

Direct Black 56 

Direct Black 71 

Direct Black 75 

Direct Black 78 

♦Direct Black 80 

Direct Black 95 

Direct Black 190 

Other direct black dyes 

DISPERSE DYES 

♦Disperse yellow dyes: 

Disperse Yellow 1 

Disperse Yellow 2 

♦Disperse Yellow 3 

♦Disperse Yellow 5 

Disperse Yellow 8 

♦Disperse Yellow 23 

Disperse Yellow 31 

Disperse Yellow 32 

♦Disperse Yellow 33 

♦Disperse Yellow 34 

♦Disperse Yellow 42 

Disperse Yellow 50 

♦Disperse Yellow 54 

Disperse Yellow 58 

Disperse Yellow 64 

Disperse Yellow 67 

Disperse Yellow 68 

Disperse Yellow 69 

Disperse Yellow 77 

Disperse Yellow 85 

Disperse Yellow 86 

Disperse Yellow 87 

Disperse Yellow 88 

Disperse Yellow 89 

Disperse Yellow 93 

Disperse Yellow 95 

Disperse Yellow 96 

Disperse Yellow 118 

Disperse Yellow 125 

Other disperse yellow dyes 

♦Disperse orange dyes: 

♦Disperse Orange 5 

♦Disperse Orange 5 

Disperse Orange 16 

♦Disperse Orange 17 

Disperse Orange 21 

♦Disperse Orange 25 

Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 37 

Disperse Orange 38 

Disperse Orange 41 

Disperse Orange 44 

Disperse Orange 57 



Manufacturers' identi 
(according to list 



catioi 
table 



codes 
5) 



FAB, GAP, 
ATL, DUP, 



HSH, YAW. 



GAP, TRC. 



YAW. 



ICC, TRC. 



AAP. 

ACS, 

TRC. 

ACS, 

ACS. 

ATL. 

GAP. 

ACS, FAB, HN. 

ACS, ATL, FAB, HN, HSH, 

ACS. 

ACS, HN. 

ACY, ALT, ATL, HSH, TRC, YAW. 



GAP. 

DUP. 

AAP, ALT, DUP, GAP, HN, ICC, TRC. 

GAF, HN, ICC. 

TRC. 

AAP, ALT, DUP, EKl, GAF, 

GAP. 

DUP. 

AAP, EKT, GAF, ICC, TRC. 

AAP, EKT, ICC. 

AAP, BUC, DUP, EKT, GAF, HN, ICC, SDC, 

AAP, ATL, DUP, GAF, HN, ICC, SDL, TKC. 

HST. 

BUC, DUP. 

DUP. 

HST. 

ACY. 

VPC. 

EKT. 

AAP, EKT. 

EKT. 

EKT. 

EKT. 

VPC. 

VPC. 

VPC . 

AAP. 

SDC. 

ATL, BUC, 



EKT, GAF, MAY, SDC, TRC, VPC. 



DUP, 
BUC, 



GAF, HN, TRC. 
EKT, GAF, SDC. 



AAP 

AAP 

.AAP. 

AAP, EKT, GAF, HN, 

TRC. 

DUP, EKT, HN, TRC. 

AAP, GAF. 

ICC, TRC. 

TRC. 

TRC. 

DUP. 

DUP. 

EKT. 



DYES 
TABLE 2, —Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



DISPERSE DYES--Continued 

*Disperse orange dyes --Continued 

Disperse Orange 58 

Disperse Orange 59 

Disperse Orange 62 

Disperse Orange 65 

Disperse Orange 75 

Disperse Orange 78 

Disperse Orange 89 

Disperse Orange 90 

Disperse Orange 94 

Other disperse orange dyes 

*Disperse red dyes: 

*Disperse Red 1 

Disperse Red 4 

•Disperse Red 5 

Disperse Red 7 

Disperse Red 9 

'Disperse Red 11 

Disperse Red 13 

•Disperse Red 15 

•Disperse Red 17 

Disperse Red 21 

Disperse Red 30 

Disperse Red 51 

Disperse Red 35 

Disperse Red 54 

•Disperse Red 55 

Disperse Red 59 

•Disperse Red 60 

•Disperse Red 65 

Disperse Red 66 

Disperse Red 73 

Disperse Red 78 

Disperse Red 82 

Disperse Red 86 

Disperse Red 90 

Disperse Red 96 

Disperse Red 117 

Disperse Red 133 

Disperse Red 135 

Disperse Red 136 

Disperse Red 137 

Disperse Red 138 

Disperse Red 139 

Disperse Red 140 

Disperse Red 159 

Disperse Red 161 

Disperse Red 162 

Disperse Red 167 

Disperse Red 176 

Disperse Red 177 

Disperse Red 178 

Disperse Red 179 

Disperse Red 180 

Other disperse red dyes 

'Disperse violet dyes; 

'Disperse Violet 1 

•Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 17 



AAP 
EKT 
BUC 
VPC 
DUP 
IRC 
AAP 
AAP 
SDC 
ALT 

AAP 
BUC 
AAP 
MP 
AIL 
AAP 
GAF 
CMC 
AAP 
EKT 
EKT 
ICC 
EKT 
ICC 
DUP 
ACY 
AAP 
DUP 
AAP 
TRC 
ICC 
VPC 
EKT 
VPC 
ACY 
EKT 
VPC 
AAP 
EKT 
EKT 
EKT 
VPC 
AAP 
VPC 
DUP 
DUP 
GAF 
ICC 
ICC 
ICC 
ICC 
ICC 
DUP 

AAP 
AAP 
GAF 
DUP 



EKT. 
ICC. 
DUP. 



ATL, BUC, EKT, GAF, MAY, SDC. 

DUP, EKT, GAF, HN, ICC, TRC. 

GAF, TRC. 

EKT, GAF, ICC. 
GAF. 

BUC, DUP, GAF, ICC. 

ICC. 

GAF, HSH, ICC, TRC. 

DUP, EKT, GAF, ICC, TRC. 

TRC. 



GAF, HN, ICC, TRC. 

DUP, GAF. 

ATL, DUP, EKT, GAF, HN, SDC, TRC, VPC. 

EKT, ICC, TRC. 



TRC. 
GAF. 



EKT, GAF, MAY, SDC, TRC, VPC. 



GAF, HSH, ICC, TRC. 
GAF, ICC. 



SY^ITHETIC ORGA^JIC CHEMICALS. 1<^72 

TABLE 2,— Dyes for which U,S, production or sales were reported, identified 
BY manufacturer, 1972--Conti nued 



Manufacturers' identification codes 
{according to list in table 3) 



DISPERSE DYES- -Continued 

et dyes--Continued 

olet 2b 

olet 27 

olet 28 



olet 40 

olet 41 

olet 42 

olet 43 

olet 44 

olet 57 

rse violet dyes 
dyes: 

ue 1 

ue 3 

ue 7 



*Disperse vio 

Disperse V 
*Disperse V 

Disperse V 

Disperse V 

Disperse V 

Disperse V 

Disperse V 

Disperse V 

Disperse V 

Other dispe 
*Disperse blue 
*Disperse B 
*Disperse B 
*Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B, 

Disperse b 

Disperse B 
'Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse K. 

Disperse B 

Disperse b 
•Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Disperse B 

Other disperse blue dyes- 
Disperse green dyes 



ue 27-- 
ue 35-- 
ue 54-- 
ue 55-- 
ue 56-- 
ue 60-- 
ue 61-- 
ue 62-- 
ue 64-- 
ue 70-- 
ue 71-- 
ue 72-- 
ue 75-- 
ue 79-- 
ue 81-- 
ue 85-- 
ue 94-- 
ue 95-- 
ue 102- 
ue 109- 
ue 112- 
ue 116- 
ue 117- 
ue 118- 
ue 119- 
ue 120- 
ue 121- 
ue 123- 
ue 125- 
ue 132- 
ue 133- 
ue 138- 
ue 139- 
ue 150- 
ue 152- 
ue 165- 
ue 166- 
ue 172- 
ue 173- 



DUP. 














AAP, 


ACY, 


DUP, 


EKT, 


ICC 


TRC. 




DUP, 


TRC. 












VPC. 














EKT. 














EKT. 














EKT. 














EKT. 














trc. 














GAP, 


SDC. 












AAP, 


GAP, 


ICC, 


TRC 








AAP, 


DUP, 


EKT, 


GAP, 


HN, 


HSH, ICC, TRC. 




DUP, 


GAP, 


HN, 


ICC, 


TRC. 






HSU. 














GAP. 














EKT, 


ICC. 












ICI. 














ICC. 














TRC. 














DUP, 


ICC, 


TRC, 


VPC 








DUP. 














DUP. 














DUP, 


EKT, 


GAP, 


SDC 








DUP, 


EKT, 


GAP, 


TRC 








AAP. 














VPC. 














ICI. 














ACY, 


ICC, 


TRC. 










EKT, 


HST, 


TRC 










VPC. 














TRC. 














BAS. 














GAP, 


HST, 


ICC 










EKT. 














DUP. 














EKT. 














ACY. 














EKT. 














EKT. 














EKT. 














EKT, 


GAP. 












EKT. 














EKT. 














TRC. 














DUP. 














DUP. 














VPC. 














VPC. 














DUP. 














HST. 














VPC. 














ICC. 














DUP, 


ICC. 












AAP. 














ALT, 


ATL, 


DUP 


EKT 


GAP, 


HN, HSH, ICC, MAY, SDC 


TRC, VPC. 










GAP, 


VPC. 













DYES 

TABLE 2. --Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 1972--Continued 



Manufacturers' identification codes 
(according to list in table 3) 



DISPERSE DYES--Continued 

Disperse brown dyes; 

Disperse Brown 1 

Disperse Brown 2 

Disperse Brown 7 

Disperse Brown 8 

Disperse Brown 11 

Other disperse brown dyes 

♦Disperse black dyes r 

♦Disperse Black 1 

Disperse Black 2 

Disperse Black 9 

Disperse Black 33 

Disperse Black 34 

Other disperse black dyes 

FIBER-REACTIVE DYES 

♦Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow 4 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 13 

Reactive Yellow 15 

Reactive Yellow 17 

Reactive Yellow 18 

Reactive Yellow 24 

Reactive Yellow 25 

Reactive Yellow 31 

Reactive Yellow 37 

Reactive Yellow 42 

Reactive Yellow 62 

Reactive orange dyes: 

Reactive Orange 1 

Reactive Orange 4 

Reactive Orange 5 

Reactive Orange 12 

Reactive Orange 13 

Reactive Orange 14 

Reactive Orange 16 

Reactive Orange 49 

Reactive Orange 50 

Reactive red dyes: 

Reactive Red 1 

Reactive Red 2 

Reactive Red 4 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 

Reactive Red 21 

Reactive Red 29 

Reactive Red 31 

Reactive Red 33 

Reactive Red 40 

Reactive Red 41 

Reactive Red 58 

Reactive Red 94 

Reactive Red 105 



AAP, TRC. 

DUP, EKT, GAF. 

EKT. 

VPC . 

AAP. 

CAP, ICC, SDC. 

AAP, ATL, DUP, GAF, TRC. 

ATL, TRC. 

AAP, EKT. 

EKT. 

EKT. 

ALT, ATL, BUC, DUP, GAF, ICC. SDC. 



ICI. 
TRC. 
TRC. 
ICI. 
TRC. 
ICI. 
HST 
UST . 
HST. 
ICI. 
HST. 
VPC. 
HST. 
HST. 
ICI, 
ACY. 

ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
HST. 
ACY. 
HST. 

ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
HST. 
ICI. 
ICI. 
ICI. 
VPC. 
VPC. 
ICI. 
HST. 
HST. 



.SYNTHETIC nPGANIC CHEMICALS, W^. 
TABLE 2,— Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURERj 1972~CoNTINUED 



Dye 



Manufacturers' identification codes 
Caccording to list in table 3) 



FIBER- REACTIVE DYES--Continued 

Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 4 

Reactive Violet 5 

*Reactive blue dyes: 

Reactive Blue 2 

Reactive Blue 3 

Reactive Blue 4 

Reactive Blue 5 

Reactive Blue 7 

Reactive Blue 19 

Reactive Blue 21 

Reactive Blue 25 

Reactive Blue 29 

Reactive Blue 30 

Reactive Blue 38 

Reactive Blue 71 

Reactive Blue 89 

Reactive Blue 90 

Reactive Blue 91 

Reactive green dyes: Reactive Green 6 

Reactive brown dyes: 

Reactive Brown 9 

Reactive Brown 10 

Other reactive brown dyes 

Reactive black dyes: 

Reactive Black S 

Reactive Black 9 

FLUOROESCENT BRIGHTENING AGENTS 

Fluoroescent Brightening Agent 1 

Fluoroescent Brightening Agent 6 

Fluoroescent Brightening Agent 8 

Fluoroescent Brightening Agent 9 

Fluoroescent Brightening Agent 22 

Fluoroescent Brightening Agent 24 

Fluoroescent Brightening Agent 25 

*Fluoroescent Brightening Agent 28 

Fluoroescent Brightening Agent 30 

Fluoroescent Brightening Agent 33 

Fluoroescent Brightening Agent 45 

Fluoroescent Brightening Agent 46 

Fluoroescent Brightening Agent 49 

Fluoroescent Brightening Agent 52 

Fluoroescent Brightening Agent 54 

Fluoroescent Brightening Agent 59 

Fluoroescent Brightening Agent 61 

Fluoroescent Brightening Agent 68 

Fluoroescent Brightening Agent 71 

Fluoroescent Brightening Agent 75 

Fluoroescent Brightening Agent 102 

Fluoroescent Brightening Agent 108 

Fluoroescent Brightening Agent 109 

Fluoroescent Brightening Agent 114 

Fluoroescent Brightening Agent 125 

Fluoroescent Brightening Agent 126 

Fluoroescent Brightening Agent 128 

Fluoroescent Brightening Agent 130 



ICI. 
HST. 
HST. 

TRC. 

ICI. 

ICI. 

ICI, TRC. 

TRC. 

HST. 

HST. 

ICI. 

VPC. 

VPC. 

HST. 

ICI. 

HST. 

HST. 

HST. 

ICI. 

ICI. 
ICI. 
HST. 



CGY. 
ACY. 
ACY. 
ACY, 
CGY. 
CGY. 
GAF. 
ACY, 
GAF. 
GAF. 
GAF. 
CGY. 
S. 

s. 

CGY. 
CGY. 
ACY. 
CCW, 
ACY, 
GAF. 
DUP, 
GAF. 
GAF- 
VPC. 
ACY. 
SDH. 
SDH. 
ACY. 



GAF, SDH. 



CCW, DUP, SDH, VPC. 



GAF. 
GAF . 



DYES 

TABLE 2, —Dyes for which U.S, production or sales were reported^ identified 
BY manufacturer, 1972--Conti nued 



Manufacturers' identification codes 
faccording to list in table 3} 



FLUOROESCENT BRIGHTENING AGENTS--Continued 

Fluoroescent Brightening Agent 158 

Fluoroescent Brightening Agent 159 

Other fluoroescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

foody Drug, and Cosmetic Dyes 

FDSC Blue No. 1 

FD6C Blue No. 2 

FD5C Green No. 5 

*FDf,C Red No. 2 

*FD§C Red No. 3 

FD8C Red No. 4 

FD5C Red No. 40 

FD6C Violet No. 1 

*FD5C Yellow No. 5 

*FD5C Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyes 

D5C Blue No. 6 

D5C Green No. 5 

DiiC Green No. 6 

D6C Green No. 8 

*D5C Orange No. 4 

DSC Orange No. 5 

DSC Orange No. 10 

DSC Orange No. 17 

DSC Red No. 2 

DSC Red No. 3 

DSC Red No. 6 

*DSC Red No. 7 

DSC Red No. 8 

DSC Red No. 9 

DSC Red No. 10 

DSC Red No. 11 

DSC Red No. 12 

DSC Red No. 13 

DSC Red No. 17 

*D6C Red No. 19 

*DSC Red No. 21 

DSC Red No. 22 

DSC Red No. 27 

DSC Red No. 28 

DSC Red No. 30 

DSC Red No. 31 

DSC Red No. 33 

DSC Red No. 34 

*D6C Red No. 36 

DSC Red No. 37 

DSC Red No. 59 

DSC Violet No. 2 

DSC Yellow No. 5 

DSC Yellow No. 6 

DSC Yellow No. 7 

DSC Yellow No. 8 

DSC Yellow No. 10 

DSC Yellow No. 11 



ACY. 
ACY. 
ACY, CCW, CGY, GAF, PCW, 



ACS, 


ALT, 


KON, 


SDH, 


WJ. 


ACS, 


ALT, 


KON, 


SDH, 


WJ. 


WJ. 










ACS, 


ALT, 


KON, 


SDH, 


STG 


ACS, 


ALT, 


KON, 


SDH, 


STG 


ALT, 


KON 








ACS, 


WJ. 








ACS, 


SDH, 


WJ. 






ACS, 


ALT, 


KON, 


STG. 


WJ. 


ACS, 


ALT, 


KON, 


SDH, 


STG 


STG. 











ACS, 


KON. 




ACS, 


KON. 




ACS, 


KON. 




KON, 


SDH. 




ACS, 


KON, 


SNA, TMS 


SNA, 


TMS. 




TMS. 






SNA. 






KON. 






KON, 


TMS. 




KON, 


SNA, 


TMS. 


KON, 


SNA, 


TMS. 


KON, 


SNA. 




KON, 


SNA, 


TMS. 


KON, 


SNA. 




KON, 


SNA. 




SNA, 


TMS. 




SNA, 


TMS. 




KON. 






ACS, 


KON, 


SNA, TMS 


KON, 


SNA, 


TMS. 


ACS, 


KON, 


SDH. 


TMS. 






ACS, 


TOS. 




KON, 


TMS. 




KON. 






ACS, 


KON. 




KON. 






ALT, 


KON, 


TMS. 


.\CS. 






SDH. 






ACS. 






KON. 






KON. 






KON. 






KON. 






KON. 






ACS, 


KON. 





SYNTHETIC ORGVIIC CHEHICUS, 1972 

TABLE 2.— Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 1972— Conti nued 



Manufacturers' identification codes 
(according to list in table 3J 



FOOD, DRUG, AND COSMETIC COLORS--Cont inued 

Drug and Cosmetic Dyes, External 

Ext. D5C Green No. 1 

Ext. DSC Yellow No. 1 

Ext. D6C Yellow No. 7 

INGRAIN DYES 

Ingrain blue dyes: 

Ingrain Blue 1 

Ingrain Blue 2 

Ingrain Blue 3 

MORDANT DYES 

♦Mordant yellow dyes: 

Mordant Yellow 1 

Mordant Yellow 5 

Mordant Yellow 8 

Mordant Yellow 14 

Mordant Yellow 16 

Mordant Yellow 20 

Mordant Yellow 26 

Mordant Yellow 29 

Mordant Yellow 30 

Mordant Yellow 36 

*Mordant orange dyes : 

Mordant Orange 1 

Mordant Orange 4 

Mordant Orange 6 

Mordant Orange 8 

'Mordant red dyes : 

Mordant Red 3 

Mordant Red 7 

Mordant Red 9 

Mordant Red 11 

Mordant Red 64 

Mordant violet dyes: Mordant Violet S 

Mordant blue dyes: 

Mordant Blue 1 

Mordant Blue 3 

Mordant Blue 9 

Mordant Blue 19 

Mordant green dyes: Mordant Green 36 

•Mordant brown dyes : 

*Mordant Brown 1 

Mordant Brown 12 

Mordant Brown 13 

Mordant Brown 15 

Mordant Brown 18 

Mordant Brown 19 

Mordant Brown 21 

*Mordant Brown 33 

Mordant Brown 40 >- 

Mordant Brown 63 

Mordant Brown 70 

•Mordant black dyes: 

Mordant Black 3 

Mordant Black 8 

Mordant Black 9 

•Mordant Black 11 

Mordant Black 13 

•Mordant Black 17 

Mordant Black 19 

Mordant Black 26 

Other mordant black dyes 



ACS, KON. 
ACS, KON. 
KON. 



ICI. 
VPC. 
ICI. 



ATL 
TRC 
ACS 
ACS 
ACY 
ACS 
VPC 
GAP 
TRC 
PDC 

ACY 
GAP 
ATL 
TRC 

ACY 
ACY 
MRX 
ACY 
PDC 
PDC 



GAP 
GAP 
CMC 
PDC 

ACS 
PDC 
ACS 
GAP 
ACS 
GAP 
GAP 
ACS 
CMG 
TRC 
DUP 

TRC 
VPC 
ACS 
ACS 
HSH 
ACS 
PDC 
TRC 
CMG 



GAP, PDC. 

PDC. 
PDC. 

ATL. 
ATL. 



PDC, TRC. 

PDC. 

GAP, PDC, TRC. 



ATL, BDO, GAP, PDC, TRC. 
PDC, 



CMG, DUP, GAP, TRC, YAW. 



VPC. 

GAP, PDC, TRC. 

GAP. 



.^TL, VPC. 

ATL, GAP, TRC, VPC. 



ACY, GAP, TRC. 



DYES 
TABLE 2.— Dyes for which U.S. production or sales were reported, identified 

BY manufacturer, 1972— CONTINUED 




Manufacturers' identification codes 
(according to list in table 3) 



OXIDATION BASES 

Oxidation Base 8 and 8A 

Oxidation Base 21 

Oxidation Base 22 

Oxidation Base 25 

Other oxidation bases 

SOLVENT DYES 

'Solvent yellow dyes: 

Solvent Yellow 1 

Solvent Yellow 2 

Solvent Yellow 3 

Solvent Yellow 13 

♦Solvent Yellow 14 

Solvent Yellow 19 

Solvent Yellow 29 

Solvent Yellow 30 

Solvent Yellow 33 

Solvent Yellow 34 

Solvent Yellow 40 

Solvent Yellow 42 

Solvent Yellow 43 

Solvent Yellow 44 

Solvent Yellow 45 

Solvent Yellow 47 

Solvent Yellow 56 

Solvent Yellow 71 

Solvent Yellow 72 

Solvent Yellow 87 

Other solvent yellow dyes 

'Solvent orange dyes: 

Solvent Orange 2 

'Solvent Orange 3 

Solvent Orange 5 

Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes 

'Solvent red dyes: 

Solvent Red 1 

Solvent Red 8 

Solvent Red 22 

Solvent Red 24 

'Solvent Red 26 

Solvent Red 27 

Solvent Red 33 

Solvent Red 35 

Solvent Red 40 

Solvent Red 41 

'Solvent Red 49 

Solvent Red 52 



ACY. 
PDC. 
ACY. 
ACY. 
ACY. 



AAP. 








DUP, 


GAF, 


PSC. 




ACS, 


PSC. 






ACY, 


GAF. 






AAP, 


ACS, 


ACY, 


DUP, GAF, PSC 


GAF. 








GAP. 








ACS. 








AAP, 


ACS, 


ACY. 




DSC. 








ACS. 








ACS. 








GAF. 








ACS. 








ACS. 








ACY, 


DUP, 


GAF. 




AAP, 


ACS, 


ACY. 




ACY. 








ACY. 








ACY. 








AAP, 


ATL, 


DSC, 


PAT. 


PSC. 








AAP, 


.ACS, 


ACY, 


DSC, GAF, PSC 


GAF. 








ACS, 


ACY, 


GAF. 




ACY, 


GAF. 






ACS. 








DUP. 








ACY, 


DUP 






ACS. 








ACY. 








ACY. 








AAP, 


ACY, 


DSC, 


DUP. 


PSC. 








GAF. 








GAF. 








ACY, 


DUP 


GAF. 




AAP, 


ACS, 


ACY, 


PSC. 


ACS. 








DUP, 


GAF 






GAF. 








GAF. 








DSC. 








ACY, 


DSC, 


DUP, 


GAF. 


AAP, 


ICI 







SYNTHETIC ORGANIC CHEMICALS, 197? 
TABLE 2,— Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



SOLVENT UYES--Continued 



*Solvent red dye5--Continued 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 75 

Solvent Red 105 

Solvent Red 108 

Solvent Red 111 

Solvent Red 115 

Solvent Red 126 

Other solvent red dyes 

Solvent violet dyes: 

Solvent Violet 8 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet 14 

Solvent Violet 17 

Other solvent violet dyes- 
*Solvent blue dyes: 

Solvent Blue 3 

Solvent Blue 4 

Solvent Blue 5 

Solvent Blue 6 

Solvent Blue 7 

Solvent Blue 9 

Solvent Bl 
Solvent Bl 
Solvent Bl 
Solvent Bl 
Solvent Bl 
*Solvent Bl 
Solvent Bl 
Solvent Bl 
Solvent Bl 
Solvent Bl 

Solvent Blue 74 

Other solvent blue dyes-- 
Solvent green dyes: 

Solvent Green 1 

*Solvent Green 3 

Other solvent green dyes- 
Solvent brown dyes : 

Solvent Brown 11 

'Solvent Brown 12 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 22 

Solvent Brown 38 

Other solvent brown dyes- 
Solvent black dyes: 

Solvent Black 3 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13 

Solvent Black 17 

Solvent Black 26 

Other solvent black dyes- 



ue 


11 


ue 


12 


ue 


16 


ue 


36 


ue 


37 


ue 


38 


ue 


43 


ue 


57 


ue 


58 


ue 


59 



ACS. 










DSC, 


DUP. 








ACS. 










ACS. 










ACY. 










ACY. 










ACY. 










ACY. 










ACY. 










AAP, 


ACY, 


ATL, 


DSC, 


ICI, PAT 


ACY, 


DSC, 


DUP. 






DSC. 










AAP. 


ATL, 


HSH, 


ICl. 




AAP, 


ICI. 








ACS. 










AAP, 


DSC, 


PAT. 






ACY, 


SW. 








DSC, 


DUP. 








DSC. 










DSC. 










ACY. 










GAP. 










BDO, 


GAP, 


ICI. 






ACS, 


BDO. 








ACS. 










AAP, 


DUP. 








DUP. 










ACS, 


ACY, 


ATL, 


DUP, 


GAP. 


ACS. 










DUP. 










ACY. 










ACY. 










ACS. 










ACY, 


DSC, 


GAP, 


PAT, 


SDH. 


ACY, 


DSC. 








AAP, 


ACS, 


ATL, 


GAP, 


HSH, PAT 


DSC, 


GAP. 








GAP. 










ACY, 


DSC, 


GAP. 






DUP. 










ACY. 


DUP. 








DUP, 


PSC. 








ACY. 










DSC. 










ACS. 










ACS, 


ACY, 


DSC, 


DUP. 




ACS, 


ACY, 


DSC. 






ACS. 










ACS. 










DUP. 










ACY. 










ATL, 


DSC, 


GAP, 


PAT. 





DYES 
TABLE 2. —Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



SULFUR DYES 

Sulfur yellow dyes: 

Leuco Sulfur Yellow 1 

Leuco Sulfur Yellow 2 

Sulfur Yellow 4 

Leuco Sulfur Yellow 4 

Leuco Sulfur Yellow 9 

Leuco Sulfur Yellow 15 

Other sulfur yellow dyes 

Sulfur Orange 1 

Sulfur red dyes ; 

Leuco Sulfur Red S 

Other sulfur red dyes 

Sulfur blue dyes: 

Sulfur Blue 5 

Sulfur Blue 7 

Leuco Sulfur Blue 7 

Solubilized Sulfur Blue 7 

Sulfur Blue 8 

Leuco Sulfur Blue 8 

Sulfur Blue 9 

Leuco Sulfur Blue 11 

Leuco Sulfur Blue 13 

Other sulfur blue dyes 

Sulfur green dyes: 

Sulfur Green 2 

Leuco Sulfur Green 2 

Leuco Sulfur Green 3 

Sulfur Green 14 

Leuco Sulfur Green 16 

Other sulfur green dyes 

Sulfur brown dyes: 

Leuco Sulfur Brown 1 

Solubilized Sulfur Brown 1 

Leuco Sulfur Brown 3 

Sulfur Brown 10 

Leuco Sulfur Brown 10 

Solubilized Sulfur Brown 10 

Sulfur Brown 12 

Sulfur Brown 14 

Leuco Sulfur Brown 14 

Leuco Sulfur Brown 20 

Sulfur Brown 26 

Leuco Sulfur Brown 26 

Sulfur Brown 37 

Solubilized Sulfur Brown 37 

Leuco Sulfur Brown 81 

Leuco Sulfur Brown 82 

Other sulfur brown dyes 

Sulfur black dyes: 

Sulfur Black 1 

Leuco Sulfur Black 1 

Solubilized Sulfur Black 1 

Sulfur Black 2 

Leuco Sulfur Black 2 

Solubilized Sulfur Black 2 

Leuco Sulfur Black 10 

Sulfur Black 11 

Leuco Sulfur Black 11 

Other sulfur black dyes 



SDC. 

ACY, SDC. 
SDC. 
SDC. 
SIC. 
AC\ . 

ACY, SDC. 
SIC. 

SDC. 
SDC. 

ACY. 

ACY, SDC. 

ACY, SDC, SIC. 

SDC. 

SDC. 

SDC. 

SDC. 

SDC. 

ACY. 

SDC. 

SDC. 
SDC. 
SDC. 
SDC. 
SDC. 
ACY, SDC. 

SIC. 

SIC. 

SDC. 

SDC. 

SDC, STC. 

SDC. 

SDC. 

SDC. 

SDC. 

STC. 

ACY. 

STC. 

SDC. 

SDC. 

ACY. 

ACY. 

ACY, SDC. 

SDC. 

ACY, SDC, STC. 

STC. 

SDC. 

ACY, SDC. 

SDC. 

ACY. 

SDC. 

SDC. 

SDC. 



SYNTHETIC ORGANIC CHEMICALS. 1972 ' 

TABLE 2. --Dyes for which U.S. production or sales were reported, identified 
BY manufacturer. 1972--Continued 



Manufacturers' identification codes 
(according to list in table 3J 



VAT DYES 

*Vat yellow dyes: 

Vat Yellow 1, 12-1/2% 

*Vat Yellow 2. 8-1/2°. 

Vat Yellow 3, 12-l/2°6 

*Vat Yellow 4, 12-1/2% 

Solubilized Vat Yellow 4, 37-1/2°* 

Vat Yellow 10, 10% 

Vat Yellow 14, 12-1/2% 

Vat Yellow IS, 11-1/2% 

Vat Yellow 21, 9-1/2% 

Vat Yellow 22, 10% 

Vat Yellow 33, 15% 

Other vat yellow dyes 

*Vat orange dyes: 

*Vat Orange 1, 20% 

Solubilized Vat Orange 1, 26% 

*Vat Orange 2, 12% 

*Vat Orange 3, 13-1/2% 

Vat Orange 4, 6% 

Vat Orange 5, 10% 

Solubilized Vat Orange 5, 30% 

Vat Orange 7, 11% 

*Vat Orange 9, 12% 

Vat Orange 11, 6% 

*Vat Orange 15, 10% 

Other vat orange dyes 

*Vat red dyes: 

*Vat Red 1, 13% 

Solubilized Vat Red 1, 37% 

Vat Red 10, 18% 

Vat Red 12, 8-1/2% 

*Vat Red 13, 11% 

Vat Red 14, 10% 

Vat Red 15, 10% 

Vat Red 16, 11% 

Vat Red 23 

Vat Red 29, 18% 

Vat Red 32, 20% 

Vat Red 41, 20% 

Vat Red 52, 10% 

Other vat red dyes 

*Vat violet dyes: 

*Vat Violet 1, 11% 

Vat Violet 2, 20% 

Vat Violet 3, 15% 

*Vat Violet 9, 12% 

*Vat Violet 13, 6-1/4% 

Vat Violet 14, 12-1/2% 

Vat Violet 17, 12-1/2% 

Vat Violet 21 

Other vat violet dyes 

*Vat blue dyes: 

Vat Blue 1, 20% 

Vat Blue 4, 10% 

Vat Blue 5, 16% 

*Vat Blue 6, 8-1/3% 

Solubilized Vat Blue 6, 17-1/2%-- 

Vat Blue 12, 6-1/2% 

Vat Blue 14, 8-1/3% 

Vat Blue 16, 16-1/2% 



ACS 
AAP 
DUP 
ATL 
HST 
GAF 
IRC 
ACY 
ATL 
DUP 
TRC 
GAF 

ACY 
HST 
ACY 
DUP 
DUP 
HSi 
HST 
GAF 
ACY 
DUP 
AAP 
SDC 

AAP 
HST 
GAF 
DUP 
DUP 
GAF 
HST 
DUP 
DUP 
GAF 
DUP 
HST 
DUP 
TRC 

ACY 
ACY 
HST 
DUP 
ATL 
ATL 
DUP 
VPC 
GAF 

ACS 
ACY 
ATL 
ACY 
HST 
DUP 
DUP 
DUP 



ATL, GAF, ICI, TRC, VPC. 



GAF, HST, VPC. 
ICI. 



VPC. 
MAY, VPC. 



ATL, DUP, GAF, HST, ICl, IRC, VPC. 



DUP, GAF, ICI, TRC. 
GAF, HST. 



HST, TRC. 

DUP, GAF, ICl, TRC. 



ACS, ACY, GAF, ICI, TRC, VPC. 



ATL, ACY, HST, ICl. 



GAF, TRC. 

HST. 

TRC. 



ATL, DUP, GAF, ICI, MAY, TRC. 
HST. 



GAF, ICI, MAY, TRC. 
DUP, GAF, HST, ICI, TRC. 



DUP, GAF. 

HST. 

DUP, GAF, ICl, TRC. 



DYES 
TABLE 2.— Dyes for which U.S. production or sales were reported, identified 

BY manufacturer, 1972— CONTINUED 



VAT DYES--Continued 

"Vat blue dyes --Continued 

*Vat Blue 18, 13% 

Vat Blue 20, 14% 

Vat Blue 29 

Vat Blue 39, n"., 

Vat Blue 43 

Vat Blue 53, 20-1/2% 

Vat Blue 60 

Vat Blue 67 

Other vat blue dyes 

*Vat green dyes: 

*Vat Green 1, 6% 

Solubilized Vat Green 1, 12-1/2-0 

*Vat Green 3, lOi 

Solubilized Vat Green 3, 26% 

Vat Green 8, 8-1/2% 

Vat Green 9, 12-1/2% 

Vat Green 20, 6% 

Vat Green 32 

Other vat green dyes 

*Vat brown dyes: 

*Vat Brown 1, 11% 

*Vat Brown 3, 11% 

Vat Brown 5, 13% 

Vat Brown 11, 12% 

Vat Brown 12, 12-1/2% 

Vat Brown 13, 17% 

Vat Brown 20, 10-1/2% 

Vat Brown 28, 22% 

Vat Brown 29, 13% 

Vat Brown 40, 14% 

Vat Brown 57, 12.8% 

Other vat brown dyes 

*Vat black dyes: 

Solubilized Vat Black 1, 27-1/2% 

Vat Black 9, 16% 

Vat Black 13, 14% 

Vat Black 22, 19% 

*Vat Black 25, 12-1/2% 

*Vat Black 27, 12-1/2% 

Vat Black 34, 16% 

Vat Black 37 

Vat Black 38, 20% 

Vat Black 52, 18-1/2% 

Other vat black dyes 

All other dyes 



Manufacturers' identification codes 
[according to list in table 3J 



AAP, 


ACY 


.AAP. 


■ACS 


GAP. 




GAP. 




SDC. 




GAP. 




DUP. 




HST. 




CAF, 


MAY 


ACY, 


DUP 


ICI. 




AAP, 


ACY 


ICI. 




ATL, 


DUP 


ACY, 


ATL 


DUP. 




VPC. 




ACY, 


GAP 


ACY, 


DUP 


AAP, 


ACY 


ACY, 


HST 


MAY, 


TRC 


DUP. 




MAY. 




GAP. 




ICI. 




ACY. 




DUP. 




HST, 


TRC 


GAP, 


SDC 


HST. 




GAP, 


MAY 


DUP. 




ACY. 


TRC 


AAP, 


ACY 


ACY, 


BDO 


ICI. 




GAP. 




GAP. 




ACY. 




ATL, 


GAP 



ATL, DUP, GAP, MAY, TRC. 

ACY, ATL, DUP, GAP, MAY, SDC. TRC. 



GAP, ICI, MAY, TRC. 

ATL, DUP, GAP, ICI, MAY, TRC. 

GAP. 

GAP, HST, MAY, SDC, TRC. 



GAP, ICI, MAY, TRC. 
DUP, GAP, ICI, TRC, VPC. 



DUP, GAP, ICI, MAY, TRC. 
DUP, GAP, ICI, MAY, TRC. 



MAY, SDC, TRC. 



ACY, DUP, GAP, HSH, PAT, SDC. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3, --Dyes; Directory of manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 



[Names of dye manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are listed bela 
in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


AAP 


American Aniline Products, Inc. 


ICC 


Inmont Corp. 




ACS 


Allied Chemical Corp., Specialty Chemicals 
Div. 


ICI 


ICI America, Inc. 




ACY 


American Cyanamid Co. 








ALL 


Alliance Chemical, Inc. 








ALT 


Crompton 5 Knowles Corp., Dyes § Chemicals 

Div. 


KON 


H. Kohnstamm 6 Co., Inc. 




ATL 


Atlantic Chemical Corp. 


MAY 
MRX 


Otto B. May, Inc. 

Max Marx Color § Chemical Co. 




BAS 


BASF Wyandotte Corp. 








EDO 


Benzenoid Organics, Inc. 








sue 


Blackman-Uhler Chemical Co. 












PAT 


Morton-Norwich Products, Inc., Morton 
Co. Div. 


Chemical 






PCW 


Pfister Chemical Works 




CCW 


Cincinnati Malacron Chemicals, Inc. 


PDC 


Berncolors-Poughkeepsie, Inc. 




CGY 


Ciba-Geigy Corp. 


PSC 


Passaic Color g Chemical Co. 




CNG 


Nyanza, Inc. 








CPC 


Childs Pulp Colors, Inc. 












S 


Sandoz, Inc., Sandoz Color 6 Chemical 


5 Div. 






SDC 


Martin-Marietta Corp., Sodyeco Div. 




DSC 


Dye Specialties, Inc. 


SDH 


Sterling Drug, Inc., Hilton-Davis Ch 


smical 


DUP 


E. I. duPont de Nemours § Co., Inc. 


SNA 
STC 
STG 


Co. Div. 
Sun Chemical Corp. 
Sou-Tex Chemical Co., Inc. 
Stange Co. 




EKT 


Eastman Kodak Co. , Tennessee Eastman 
Co. Div. 


sw 


Sherwin-Williams Co. 




FAB 


Fabricolor Manufacturing Corp. 


TMS 
TRC 


Sterling Drug, Inc., Thomasset Colors 
Toms River Chemical Corp. 


Div. 


GAF 


GAF Corp., Chemical Div. 


VPC 


Baychem Corp., Verona Div. 




HN 


Tenneco Chemicals, Inc. 








use 


Chemetron Corp., Pigments Div. 


WJ 


Warner-Jenkinson Manufacturing Co. 




HSH 


Harshaw Chemical Co. Div. of Kewanee 
Oil Co. 








HST 


American Hoechst Corp. 


YAW 


Y. S. Young, Young Aniline Works Div. 





Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix 



91 



ORGANIC PIGMENTS 

As the terms are used in this report, organic pigments are toners 
and lakes derived in whole or in part from benzenoid chemicals and colors. 

Statistics on production and sales of all organic pigments in 1972 
are given in table 1. 1/ Statistics on sales of a few selected pigments 
by commercial forms (dry full-strength form, dry extended form, dry dis- 
persions, aqueous dispersions, and flushed colors) are given in table lA. 
Individual toners and lakes are identified in this report by the names 
used in the third edition of the Colour Index . 

Total production of organic pigments in 1972 was 65.9 million pounds-- 
13.0 percent more than the 58.3 million pounds produced in 1971 and 16.6 
percent more than the 56.5 million pounds produced in 1970. Total sales 
of organic pigments in 1972 amounted to 53.2 million pounds, valued at 
$149.3 million, compared with 47.1 million pounds, valued at $130.0 mil- 
lion, in 1971 and 47.2 million pounds, valued at $123.0 million, in 1970. 
In terms of quantity, sales of organic pigments in 1972 were 13.1 percent 
greater than in 1971 and 12.8 percent greater than in 1970; in terms of 
value, sales in 1972 were 14.9 percent greater than in 1971 and 21.5 per- 
cent greater than in 1970. 

Production of toners in 1972 amounted to 62.9 million pounds--14.1 
percent more than the 55.1 million pounds reported for 1971. Sales in 
1972 were 50.5 million pounds, valued at $145.9 million, compared with 
44.2 million pounds, valued at $126.6 million, in 1971. Sales in 1972 
were thus 14.1 percent more than those in 1971 in terms of quantity, 
and 15.3 percent more in terms of value. The individual toners listed 
in the report which were produced in the largest quantities in 1972 
were Pigment Yellow 12, 6.5 million pounds; Pigment Blue 15, beta form, 
6.0 million pounds; and Pigment Red 49, barium toner, 4.6 million pounds. 

Production of lakes totaled 3.0 million pounds in 1972--6.8 percent 
less than the 3,2 million pounds reported for 1971. Sales of lakes in 
1972 amounted to 2.7 million pounds, valued at $3.4 million, compared 
with sales in 1971 of 2.8 million pounds, valued at $3.4 million. Sales 
in 1972 were thus 3.4 percent less than those in 1971 in terms of quantity ^ 
and substantially unchanged in terms of value. 

For each of 15 selected pigments, or groups of pigments, table lA 
gives data on sales by commercial forms. Pigment Yellow 12, Pigment Red 
53, Pigment Blue 15, beta form, and Pigment Blue 19 were sold principally 
in the flushed form. The remaining 7 pigments, or groups of pigments, 
for which statistics are published were sold principally in the dry full- 
strength form. Statistics on sales by commercial forms could not be 
published for Pigment Red 49, calcium toner. Pigment Red 49, sodium toner. 
Pigment Red 90, and Pigment Violet 3, fugitive, without revealing the 
operations of individual companies. 

1/ See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are listed in table 3. 



SYNTHETIC ORGANIC CHEMICALS. 1972. 
TABLE 1,— Organic pigments: U.S. production and sales. 1972 

[Listed below are all organic pigments for which any reported data on production or sales may be published. (Leaders 
^ are used where the reported data are accepted in confidence and may not be published or where no data were reported.) 

Table 2 lists all organic pigments for which data on production or sales were reported and identifies the manufac- 

turers of each] 



Pigment 



Grand total - 



Total- 



Yellow toners, total 

Acetoacetarylide yellows; 

Pigment Yellow 1, C.I. 11 680-- 
Pigment Yellow 3, C.I. 11 710-- 
Pigment Yellow 74, C.I. 11 741- 

Benzidine yellows, total 

Pigment Yellow 12, C.I. 21 090- 
Pigment Yellow 14, C.I. 21 095- 
Pigment Yellow 17, C.I. 21 105- 
Other benzidine yellows 

AH other ^ 



Orange toners, total - 
Pigment Orange 5, C 
Pigment Orange 13, 
Pigment Orange 16, 
Pigment Orange 34, 
All other 



12 075-- 
. 21 110- 
. 21 160- 
. 21 115- 



Red toners, total 

Naphthol reds, total 

Pigment Red 2, C.l. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 17, C.I. 12 390 

Pigment Red 22, C.I. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, C.l. 12 070, light 

Pigment Red 3, C.I. 12 120 

Pigment Red 4, C.I. 12 085 

Pigment Red 38, C.I. 21 120 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.l. 15 630: 

Barium toner 

Calcium toner 

Sodium toner 

Pigment Red 52, C.I. 15 860 

Pigment Red 53, C.l. 15,585, barium toner-- 
Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, PMA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

Pigment Red 122 

All other 



1,000 
pounds 



14,110 



662 

297 

1,038 

10,442 

6,473 

2,139 

573 

1,257 

1,671 

1,593 



319 
124 
562 



Quantity 



1,000 
pounds 



141 
276 
477 
76 
108 
,051 
360 
185 



4,555 
1,328 



1,559 
2,799 



1,479 

52 

572 

131 

1,864 
115 

2,310 



10,239 



462 

163 

600 

7,477 

4,103 

1,961 

416 

997 

1,537 

1,463 



331 
177 
300 
117 
538 



105 

247 

322 

73 

91 

1,665 

360 

165 

2,816 

4,289 

1,297 

74 

1,477 

2,146 

81 

1,236 

45 

534 

107 

1,046 

105 

1,730 



1,000 
dollars 



28,982 



979 
391 
1,413 
18,682 
8,284 
4,698 
1,224 
4,476 
7,517 

5,795 



594 
620 
863 
452 
3,266 

43,790 



3,172 
124 
263 
187 
347 
839 

1,412 
110 
134 

2,949 
597 
727 

5,816 

4,880 
1,595 
88 
2,476 
3,237 



2,190 
1,418 
9,101 



See footnotes at end of table. 



ORGANIC PIGMENTS 
TABLE 1, --Organic pigments; U.S. production and sales, 1972--Continued 



Pigment 



Production 



Quantity 



Unit 
value' 



1,000 

pounds 



TONERS--Continued 



Violet toners, total 

Pigment Violet 1, C.I 
Pigment Violet 1 , C.I 
Pigment Violet 3, C.I 
Pigment Violet 3, C.I 
Pigment Violet 3, C.I 
Pigment Violet 23, C. 
All other 



45 170, PMA 

45 170, PTA 

42 535, fugitive- 

42 535, PMA 

42 535, PTA 

. 51 319 



Blue toners 
Pigment B 
Pigment B 
Pigment B 
Pigment B 
Pigment 
Pigment B 
All other 



total 

lue 1, C.I. 42 595, PMA 

lue 14, C.I. 42 600, PMA. 

lue 15, C.I. 74 160, alpha form- 

lue 15, C.I. 74 160, beta form-- 

lue 19, C.I. 42 750A 

lue 25, C.I. 21 180 



Green toners, total - 



Pigment Green 1, C.I. 42 040, PMA 

Pigment Green 2, C.I. 42 040 and 49 005, PMA- 
Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 7, C.I. 74 260 

Pigment Green 8, C.I. 10 006 

Pigment Green 36, C.I. 74 265 

All other 



Brown toners, total 

Pigment Brown 5, C.I. 15 800- 
AII other 



Black toners - 



LAKES 



Total 

Yellow lake: (Acid Yellow 23), C.I. 19 140- 
Orange lakes 



Red lakes: 

Pigment Red 60, C.I. 16 105- 
Pigment Red 83, C.l. 58 000- 



Violet lake: Pigment Violet 5, C.I. 58 055- 
AIl other lakes' 



225 
1,164 



184 

83 

4,394 

6,008 

4,484 

30 

335 

4.216 



62 
35 
3,305 
153 
263 
383 

132 



3,019 



296 
56 



127 
2,471 



1,000 
pounds 



1,000 
dollars 



74 
831 
359 

47 

215 

1,042 

12,066 



153 

116 

3,641 

4,523 

3,353 

280 

3,665 



64 
42 
2,956 
107 
271 
210 

112 



126 
2,044 



16,382 



506 
524 
1,021 
1,156 
222 
3,122 
9,831 

36,444 



749 

560 

11,466 

14,145 

8,022 

1,502 

14,122 



66 

348 

216 

10,991 

153 

1,122 

1,226 

218 



346 
40 



382 
201 



339 
2,094 



1 Calculated from rounded figures. 

2 Includes "all other" acetoacetarylide yellows. 

3 Includes all black, blue, brown, and green lakes, and "all other" red, violet, and yellow lakes. 

Note. --The C.I. (Coloui' Index) numbers shown in this report are the identifying numbers given in the third editic 
of the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic] 
acids, respectively. 



552-743 0-74-7 



SYNTHETIC ORGANIC CHENICALS. 1972 
TABLE lA.— U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, 

AQUEOUS dispersions, AND FLUSHED COLORS, 1972 



Selected pigments by commercial forms 



Quantity' 



Unit 
value 



Pigment Yellow 12, C.I. 21 090, total --■ 

Dry full- strength toner 

Aqueous dispersions 

Dry extended toner, dry dispersions, and flushed color 

Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other benzidine yellows, total 

Dry full -strength toner 

Dry extended toner and dry dispersions" 

Aqueous dispersions 

Flushed color 

Pigment Red 3, C.I. 12 120, total 

Dry full-strength toner and dry extended toner '*.-- -^ 

Aqueous dispersions^ 

Flushed color 

Pigment Red 48, C.l. 15 865, total 

Dry full-strength toner, dry extended toner, and dry dispersions'* 

Aqueous dispersions 'and flushed color" 

Pigment Red 49, C.l. 15 630, barium toner, total 

Dry full-strength toner, dry extended toner, and aqueous dispersions '' 
Flushed color 

Pigment Red 53, C.I. 15 585, barium toner, total 

Dry full-strength toner and dry dispersions ''• 

Aqueous dispersions 'and flushed color" 

Pigment Violet 3, C.l. 42 535, PMA and PTA, total 

Dry full -strength toner 

Dry extended toner and aqueous dispersions ' '* 

Flushed color 

Pigment Blue 15, C.I. 74 160, alpha form, total 

Dry full -strength toner 

Dry extended toner and dry dispersions" 

Aqueous dispersions 

Flushed color 

Pigment Blue 15, C.I. 74 160, beta form, total 

Dry full -strength toner 

Dry extended toner and dry dispersions '* 

Aqueous dispersions ^ 

Flushed color 



1,000 
pounds 



4,103 



2,978 



651 
224 



994 
118 



2,605 
211 



3,747 
542 



978 
,168 



3,641 



1,421 

1,085 

802 

333 

4,523 



1,410 
575 
961 

1,577 



1,000 
dollars 



2,240 

63 

6,327 

10,473 



8,064 
124 

1,659 
626 

3,061 



1,759 

211 

1,091 

5,816 



5,362 

434 



4,223 
770 



1,456 
1,825 



1,079 
112 



11,467 



5,025 

3,703 

1,903 

836 

14,231 



4,690 
2,061 
2,585 
4,895 



Per 
pound 



$2.10 



2.33 
2.12 



2.38 
2.55 



2.07 
2.06 



1.49 
1.56 



3.74 
3.57 
8.00 
3.66 



3.15 



See footnotes at end of table. 



ORGANIC PIGMENTS 
ABLE 1A.--U.S. SALES of selected dry full-strength colors, dry extended colors, dry dispersions, 

AQUEOUS dispersions, AND FLUSHED COLORS, 1972--CONTINUED 



Selected pigments by commercial forms 



Quantity' 



Unit 
value 



1,000 
pounds 



Pigment Blue 19, C.I. 45 750A, total 

Dry full-strength toner and aqueous dispersions 3 
Flushed color 

Pigment Green 7, C.I. 74 260, total 

Dry full-strength toner 

Dry extended toner 

Dry dispersion 

Aqueous disperions' and flushed color'* 



3,355 



1,000 
dollars 



S,022 



3,067 
2,956 



10,991 



1,264 
490 



4, 877' 

1,966 

275 

3,873 



Per 
pound 



$2.39 



2.72 
2.36 



3.86 
4.01 



' Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. 
^ Calculated from rounded figures. 
^ Includes presscake. 

'* Separate data on these commercial forms may not be published without revealing the operations of individual 
companies. 



Note. --The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the third edition 
of the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



S'iYTHETlC mMK CHEMICALS, 197'^ 
TABLE 2, --Organic pigments for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 

[Organic pigments for which separate statistics are given in table 1 are marked below with an asterisk (*) ; products 
not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be pub- 
lished. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufac- 
turer did not consent to his identification with the designated product] 



Pigment 



Manufacturers' identification codes 
(according to list in table 3^ 



*Yellow toners: 

Acetoacetarylide yellows: 
♦Pigment Yellow 1, C.I. 11 680- 



11 710 


11 665 


11 660 


11 670 


11 720 



♦Pigment Yellow 3, C.I. 
Pigment Yellow 4, C.I. 
Pigment Yellow 5, C.I. 
Pigment Yellow 6, C.I. 
Pigment Yellow 9, C.I. 

Pigment Yellow 49, C.I. 11 765 

Pigment Yellow 65 

Pigment Yellow 73, C.I. 11 738 

♦Pigment Yellow 74, C.I. 11 741 

Pigment Yellow 75, C.I. 11 770 

All otlier acetoacetarylide yellows- 
*Benzidine yellows: 

♦Pigment Yellow 12, C.I. 21 090 



Pigment Yellow 13, C.I. 21 100- 
♦Pigment Yellow 14, C.I. 21 095- 



♦Pigment Yellow 17, C.I. 21 105- 



Pigment Yellow 76 

Pigment Yellow 83 

All other benzidine yellows 

Pigment Yellow 10, C.I. 12 710 

Pigment Yellow 16, C.I. 20 040 

Pigment Yellow 24 

Pigment Yellow 97 

Pigment Yellow 108, C.I. 68 420 

Pigment Yellow 123 

(Basic Yellow 2), C.I. 41 000 fugitive- 
All other 

♦Orange toners : 

Pigment Orange 1, C.I. 11 725 

Pigment Orange 2, C.I. 12 060 

♦Pigment Orange 5, C.I. 12 075 

♦Pigment Orange 13, C.I. 21 110 

Pigment Orange 15, C.I. 21 130 

♦Pigment Orange 16, C.I. 21 160 

♦Pigment Orange 34, C.I. 21 IIS 

Pigment Orange 38 

Pigment Orange 43, C.I. 71 105 

(Vat Orange 3), C.I. 59 300 

(Vat Orange 4), C.I. 59 710 

All other 

♦Red toners : 
♦Naphthol reds: 

♦Pigment red 2, C.I. 12 310 

♦Pigment Red 5, C.I. 12 490 

Pigment Red 7, C.I. 12 420 

Pigment Red 9, C.I. 12 460 

Pigment Red 10, C.I. 12 440 

Pigment Red 13, C.I. 12 395 

Pigment Red 15, C.I. 12 465 

♦Pigment Red 17, C.I. 12 390 

Pigment Red 18, C.I. 12 350 



ACS, 
S, 
ACS, 
ACS, 
CIK, 
HPC. 
SNA. 
HPC, 
ACS. 
ACS, 
DUP, 
HPC. 
DUP, 



ACY, AMS, DUP, HPC, HSC, HSH, HST, ICI, KON, 

SDH, SNA, SW. 

HPC, HSH, HST, KCW, KON, PPG, SW. 

HSC. 

HPC. 



CIK, HPC, SNA. 

HPC, HSC, SDH, SNA, SW. 



KCW. 



ACS, ACY, AMS, APO, CIK, DUP, HPC, HSC, HSH, HST, 
ICC, KON. LVY, ROM, S, SDH, SNA, SW. 

APO, sue, GAP, HPC, HSH, HST, ICC, ROM, SDH, SNA. 

ACS, ACY, AMS, BUC, CIK, CPC, DUP, GAF, HPC, HSC, 
HSH, HST, ICC, ROM, S, SDH, SNA, x. 

ACS, AMS, BUC, GAF, HPC, HSC, HST, ICC, ROM, SDH, 
SNA, SW. 

HPC. 



ACS, 


HST. 








HSH, 


ICC, 


ROM, 


S. 




HST, 


SW. 








HST. 










ACS. 










HST. 










ACS. 










ACS. 










LVR, 


MRX 








ICC, 


LVR, 


S, TRC. 




ACS, 


HPC, 


KCW. 






HPC, 


SNA, 


UHL. 






ACY, 


HSC, 


HST, 


SNA, 


SW. 


ACS, 


ACY, 


AMS, 


HPC, 


KON, S, SNA 


ACS. 










ACS, 


DUP, 


GAF, 


HPC, 


HSH, HST, I 


BUC, 


ICC, 


ROM, 


SDH, 


SNA. 


HST. 










AGS, 


HST. 








ACS, 


HST, 


TRC. 






ACS. 










KON, 


LVR, 


S, SNA. 





ACS, HPC, HSH, KCW, SW. 

GAF, HPC, HSH, ICC, ROM, S, SDH. 

S. 

HPC. 

KCW. 

HPC, KCW. 

DUP. 

ACY, HPC, ICC, S, SNA, SW, UHL. 

ACS, HPC. 



ORGANIC PIGMENTS 
TABLE 2. --Organic pigments for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Pigment 



Manufacturers' identification codes 
(according to list in table 3) 



TONERS--Continued 

•Red toners--Continued 

*Naphthol reds--Continued 

•Pigment Red 22, C.I. 12 315 

'Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

Pigment Red 112, C.I. 12 370 

All other naphthol reds 

♦Pigment Red 1, C.I. 12 070, dark-- 
♦Pigment Red 1, C.I. 12 070, light- 
♦Pigment Red 3, C.I. 12 120 



•Pigment Red 4, 

Pigment Red 6, 

•Pigment Red 38 

Pigment Red 41 

•Pigment Red 48 



C.I. 12 085-- 

C.I. 12 090-- 

C.I. 21 120- 

C.I. 21 200- 

C.I. 15 865- 



Pigment Red 49, C.I . 
•Barium toner 



•Calcium toner 

•Sodium toner 

•Pigment Red 52, C.I. 15 860 

•Pigment Red 53, C.I. 15 585, barium toner- 



Pigment Red S3, C.I. 15 585, sodium toner-- 
•Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 55, C.I. 15 820 

•Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

•Pigment Red 63, C.I. 15 880 

Pigment Red 64, C.I. 15 800 

Pigment Red 79, PMA 

Pigment Red 81, C.I. 45 160, fugitive 

•Pigment Red 81, C.I. 45 160, PMA 

•Pigment Red 81, C.I. 45 160, PTA 



Pigment Red 87, C. I . 
Pigment Red 88 

•Pigment Red 90, C.I. 
Pigment Red 112 

•r-igment Red 122 

Pigment Red 123, C.I 

Pigment Red 146 

Pigment Red 149 

Pigment Red 170 

Pigment Red 176 

Pigment Red 177 

Pigment Red 179, C.I 
Pigment Red 181 , C.I 
Pigment Red 190, C.I 

Pigment Red 198 

(Vat Red 15) 

All other 

•Violet toners: 

Pigment Violet 1, C. 

•Pigment Violet 1, C. 

•Pigment Violet 1, C. 

•Pigment Violet 3, C. 

•Pigment Violet 3, C. 



71 130- 
73 360- 
71 140- 



45 170, fugitive- 

45 170, PMA 

45 170, PTA 

42 535, fugitive- 

42 535, PMA 



•Pigment Violet 3, C.I. 42 535, PTA- 

Pigment Violet 4, PMA 

Pigment Violet 19, C.I. 46 500 

•Pigment Violet 23, C.I. 51 319 



ACY, DUP, GAP, HPC, MRX, ROM, SNA. 

ACY, BUG, DUP, HPC, ROM, SDH, SNA, 

SNA. 

HPC. 

ICC, KOV, ROM, S, SDH, SNA. 

WS, HPC, HSC, HSH, SW. 

HPC, HSC, HSH, SDH, SW. 

ACY, CIK, CPC, DUP, HPC, HSC, HSH, 

SNA, SW, UHL. 

ACY, AiMS, HPC, HSC, KON, MRX, SDH, 

DUP, HSH, KCW, KON. 

ACS, DUP, GAP, ICC, SNA, SW. 

ACS, GAP. 

ACS, ACY, AMS, DUP, GAP, HPC, HSC, 

S, SNA, SW. 

ACV, AMS, APO, CIK, HSC, KON, UT, 

UHL. 
ACV, AMS, CIK, HSC, LVT, SDH, SNA, 
ACY, HSC, KON, SDH, SW. 
A^^S, CIK, HPC, HSC, HSH, SNA, SW . 
ACY, AMS, APO, CIK, HPC, HSC, KON, 

SNA, SW. 
KON. 
HPC, HSH, SDH. 



KCW, KON, PPG, SDH, 
SNA, UHL. 



ICC, IMP, LVY, 
SDH, SNA, SW, 



LVY, MGR, MRX, SDH, 



HSH . 
















AMS, 


CIK 


DUP, 


HPC 


HSC 


KON, LVY 


\CR, SDH 


SNA, SW. 


DUP, 


HPC 














ACS, 


HPC 


HSH 


KON 


SNA 








ACS. 
















GAP. 
















MGR. 
















CPC, 


DUP 


GAP 


HPC 


KON 


LVR, LVY 


MGR, MRX 


SNA, UHL 


ACY, 


AMS 


DUP 


GAP 


HN, 


HPC, HSC, 


KCW, KON, 


MGR, MRX, 


S, 


SNA 


UHL 












ACS. 
















ACS. 
















AMS, 


HN, 


HPC, 


ICC, 


LVT, 


SDH. 






HST. 
















ACS, 


ACY 


HST 


SNA 










ACS, 
















HST. 
















HST. 
















HST. 
















HST. 
















TRC. 
















ACS. 
















HST. 
















ACS, 


GAP 


HSC 












ACS. 
















RST. 
















DUP, 


GAP, 


HN, 


HSC, 


LVR, 


SW, X. 







UHL. 

GAP, HPC, MGR, MRX, SNA, UHL. 

AMS, DUP, GAP, HPC, MGR, MRX, SNA. 

ACY, AMS, HN, HPC, HSC, KON, MGR, 

AMS, CIK, DUP, GAP, HPC, HSC, KON^ 

SDH, SW, UHL. 

ACY, AMS, HN, HPC, HSC, KON, MRX. 
LVR. 

ACS, DUP, SNA. 

ACS, ACY, BUC, GAP, HSC, HST, SDC 



UHL. 
LVY, 



MGR, MRX, PPG, 



SYNTHETIC ORGANIC CHEMICALS. 1972 " 
TABLE 2.— Organic pigments for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED 



Pigment 



Manufacturers' identification codes 
taccording to list in table 3) 



TONERS--Continued 

*Violet toners--Continued 

Pigment Violet 31, C.I. 60 010 

Pigment Violet 36, C.I. 73 385 

Pigment Violet 38, C.I. 73 395 

(Basic Violet 2), C.l. 42 520 

All other 

*Blue toners; 

•Pigment Blue 1, C.l. 42 595, PMA 

Pigment Blue 1, C.I. 42 595, PTA 

Pigment Blue 2, C.I. 44 045, PMA 

Pigment Blue 2, C.I. 44 045, PTA 

Pigment Blue 7, PMA 

Pigment Blue 7, PTA 

Pigment Blue 9, C.I. 42 025, PTA 

Pigment Blue 10, C.I. 44 040, PMA 

Pigment Blue 10, C.I. 44 040, PTA 

♦Pigment Blue 14, C.I. 42 600, PMA 

Pigment Blue 14, C.I. 42 600, PTA 

♦Pigment Blue 15, C.I. 74 160, alpha form 

♦Pigment Blue 15, C.I. 74 160, Beta form 

♦Pigment Blue 19, C.I. 42 750A 

Pigment Blue 22, C.I. 69 810 

♦Pigment Blue 25, C.I. 21 180 

Pigment Blue 64, C.I. 69 825 

(Basic Blue 2) 

All other 

♦Green toners ; 

♦Pigment Green 1, C.I. 42 040, PMA 

Pigment Green 1, C.I. 42 040, PTA 

♦Pigment Green 2, C.I. 42 040 and 49 005, PMA 

♦Pigment Green 2, C.I. 42 040 and 49 005, PTA 

Pigment Green 4, C.I. 42 000, fugitive 

Pigment Green 4, C.I. 42 000, PMA 

Pigment Green 4, C.I. 42 000, PTA 

♦Pigment Green 7, C.I. 74 260 

♦Pigment Green 8, C.I. 10 006 

Pigment Green 10, C.I. 12 775 

♦Pigment Green 36, C.I. 74 265 

Pigment Green 38 

All other 

♦Brown toners : 

Pigment Brown 1, C.I. 12 480 

Pigment Brown 2, C.I. 12 071 

Pigment Brown 3, C.I. 21 010, PMA 

♦Pigment Brown 5, C.I. 15 800 

Pigment Brown 28, C.I. 69 015 

All other 

♦Black toners 



Yellow lakes: *(Acid Yellow 23), C.I. 19 140 
♦Orange lakes: 

Pigment Orange 7, C.I. 15 530 

Pigment Orange 17, C.I. 15 510 

Red lakes: 

♦Pigment Red 60, C.I. 16 105 

♦Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 

(Acid Red 26), C.I. 16 150 

All other 



ACS, DUP. 

ACS, HST. 

ACS. 

HN. 

BUC, ICC, HPC, ROM. 

DUP, GAF, HN, HPC, HSC, KON, LVY, MGR, MRX, SW, UHL. 

AMS, GAF, HPC, MGR. 

GAF. 

KON. 

LVR. 

LVR. 

GAF, HPC, MGR. 

SDH. 

HPC, LVR. 

DUP, GAF, HPC. 

DUP, GAF, 

ACS, ACY, APO, DUP, GAF, HPC, HSC, ICC, MGR, SNA, SW, 

TMS, TRC. 
ACS, ACY, AMS, BAS, BUC, CIK, DUP, GAF, HPC, HSC, ICC, 

LVY, ROM SDH, SNA, SW, TMS. 
AMS, HN, HSC, SW. 
ACS, DUP, HN. 
ACS, DUP, GAF, ICC, SNA. 
TRC. 
HPC. 
DUP, GAF, SDH, TNI. 



GAF, 


HPC, 


MRX, 


S, UHL. 






HPC, 


MGR. 












GAF, 


HPC, 


KON, 


MGR, 


MRX, 


UHL. 




ACY, 


AMS, 


DUP, 


GAF, 


HPC, 


KON, 


S. 


GAF, 


MRX. 












KON, 


MGR. 












ACY, 


AMS, 


KON, 


MGR. 








ACS, 
HPC, 


ACY, 
HSH, 


BAS, 
KCW. 


CIK, 


DUP, 


GAF, 


HPC, HSC, SNA, TMS, TRC 


DUP, 


HPC, 


SNA. 










ACS, 


ACY, 


GAF, 


SNA. 








DUP, 


SNA. 












HPC. 














S. 














KCW, 


KON. 












ACS, 


BUC, 


HSH, 


ICC, 


ROM, 


SNA. 




GAF. 














GAF, 


LVR, 


SDH. 










DUP, 


GAF, 


UHL. 











ACS, KON, MGR, MRX. 

CPC. 

HPC, KCW, KON. 

HSH, KON, MRX, SNA. 

HPC, HSH, KON, MRX, UHL. 

HPC. 

CPC, HPC, KCW. 

HPC. 



ORGANIC PIG^IENTS 
TABLE 2. --Organic pigments for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1972— CONTINUED 



Pigment 



Manufacturers' identification codes 
(according to list in table 5) 



LAKES — Continued 

'Violet lakes: 

•Pigment Violet 5, C.l. 58 055 

All other 

Blue lakes: 

Pigment Blue 17, C.I. 74 180 

Pigment Blue 24, C.I. 42 090 

(Acid Blue 93), C.I. 42 780 

(Acid Blue 104), C.I. 42 735 

Green lakes 

Brown lakes 

Black lakes: (Natural Black 3), C.I. 75 291 



ACS, DUP, HPC, HSH, KON, UHL. 
SW. 

CPC. 

AMS, KON, LVY, SDH. 

LVR. 

KCW, LVR. 

HPC. 

KON. 

CPC. 



Note. --The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the third edition 
of the Colour Index. 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acid, repectively. 



SYNTHETIC ORGANIC CHEMICALS. 1972. 
TAPLE ^.--Hrganic f^iGMFMTs: Directory of manufacturfrs, 1^72 



ALPHABETICAL DIRECTORY BY CODE 



[Names of organic pigment manufacturers that reported prod 
are listed below in the order of their identification co 



uction or sales to the U.S. Tariff Commission for 1972 
des as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACS 


Allied Chemical Corp., Specialty Chemicals 

Div. 


KON 


H. Kohnstamm 5 Co . , Inc. 




ACY 


American Cyanamid Co. 








AMS 


Ridgway Color 6 Chemical 








APO 


Apollo Colors, Inc. 


LVR 
LVY 


C. Lever Co ., Inc. 

Cities Service Co., Levey Div. 




BAS 


BASF Wyandotte Corp. 








BUC 


Blackman-Uhler Chemical Co. 


MGR 
MRX 


Magruder Color Co., Inc. 

Max Marx Color £, Chemical Co. 




CIK 


Tenneco Chemicals, Inc., Cal/Ink Div. 








CPC 


Childs Pulp Colors, Inc. 


PPG 


PPG Industries, Inc. 




DUP 


E. 1. duPont de Nemours ti Co., Inc. 


ROM 


United Merchants (j Manufacturers, Inc. 
Roma Chemical Div. 




GAP 


GAP Corp., Chemical Div. 


S 
SDC 


Sandoz, Inc., Sandoz Color 5 Chemicals 
Martin-Marietta Corp., Sodyeco 
Div. 


Div. 






SDH 


Sterling Drug, Inc., Hilton-Davis Chem 


ical 


HN 


Tenneco Chemicals, Inc. 




Co. Div. 




HPC 


Hercules, Inc. 


SNA 


Sun Chemical Corp. 




HSC 


Chemetron Corp., Pigments Div. 


SW 


The Sherwin-Williams Co. 




HSH 


Harshaw Chemical Co. Div. of Kewanee 
Oil Co. 








HST 


American Hoechst Corp. 


TMS 
TNI 


Sterling Drug, Inc., Thomasset 

Colors Div. 
Gillette Co., Gillette Chemical 




ICC 


Inmont Corp. 




Co. Div. 




ICI 


ICI America, Inc. 


TRC 


Toms River Chemical Corp. 




KCW 


Keystone Color Works, Inc. 


UllL 


Pi.ul Uhlich f, Co. , Inc. 





Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendi.x 



101 
MEDICINAL CHEMICALS 



Medicinal chemicals include the medicinal and feed grades of all 
organic chemicals having therapeutic value, whether obtained by chemical 
synthesis, by fermentaiton, by extraction from naturally occurring plant 
or animal substances, or by refining a technical grade product. They 
include antibiotics and other anti-infective agents, antihistamines., 
autonomic drugs, cardiovascular agents, central nervous system depres- 
sants and stimulants, hormones and synthetic substitutes, vitamins, and 
other therapeutic agents for human or veterinary use and for animal feed 
supplements . 

Table 1 shows statistics for production and sales of medicinal 
chemicals grouped by pharmacological class, while table 2 lists separately 
e.ach product for which data were reported and identifies the manufacturers.^ 
The statistics shown in table 1 are for bulk chemicals only; finished 
pharmaceutical preparations and products put up in pills, capsules, tablets, 
or other measured doses are excluded. ^ The difference between production 
and sales reflects inventory changes, processing losses, and captive con- 
sumption of medicinal chemicals processed into ethical and proprietary 
pharmacetuical products by the primary manufacturer. In some instances, 
the difference may also include quantities of medicinal grade products 
used as intermediates, e.g., penicillin G salts used as intermediates in 
the manufacture of semisynthetic penicillins. All quantities are given 
in terms of 100-percent content of the pure bulk drug. 

Total U.S. production of bulk medicinal chemicals in 1972 amounted 
to 234 million pounds, or 5.0 percent more than the 223 million pounds 
produced in 1971 and 9.3 percent more than the 214 million pounds produced 
in 1970. Total sales of bulk medicinal chemicals in 1972 amounted to 163 
million pounds, valued at $490 million, compared with sales in 1971 of 
152 million pounds, valued at $487 million, and sales in 1970 of 155 
million pounds, valued at $510 million. In terms of quantity, sales in 
1972 were thus 7.2 percent larger than in 1971 and 5.6 percent larger than 
in 1970. In terms of value, sales in 1972 were 0.7 percent larger than in 

1971 and 3.9 percent smaller than in 1970. 

Production of the more important groups of medicinal chemicals in 

1972 was as follows: Antibiotics, 16.6 million pounds (7.1 percent smal- 
ler than in 1971), of which 9.8 million pounds was for medicinal use and 
6.8 million pounds was for other uses; anti-infective agents other than 
antibiotics, 34.4 million pounds (8.3 percent larger than in 1971; central 

~~^ See table 3 for a list of manufacturers and their identification 
codes . 

^ Complementary statistics on the dollar value of manufacturers' 
Shipments of finished pharmaceutical preparations, except biologicals, 
are published annually by the U.S. Department of Commerce, Bureau of 
the Census, in Current Industrial Reports, Series MA-28G. Many pharma- 
ceutical manufacturers who report to the Bureau of the Census are ex- 
cluded from the lariff Commission report because they are not primary 
producers of medicinal chemicals, that is, they do not themselves pro- 
duce the bulk drugs which go into their pharmaceutical products but 
purchase their drug requirements from domestic or foreign producers. 



102 



SYNTHETIC ORGANIC CHEMICALS, 1972 



nervous system depressants and stimulants, 52.4 million pounds (,13.2 
percent larger}; gastreintestinal ageftts add therapeutic ntitrielit^, 99^9 
million pounds (10.6 percent larger}; and vitamins, 30.0 million pounds 
(15.1 percent larger). Production of some of the more important in- 
dividual products listed in table 1 was as follows: Choline chloride, 
54.5 million poimds (19.2 percent larger than in 1971); aspirin, 35.0 
million pounds (10.5 percent larger}; salicylic acid, 8.7 million pounds 
(52.9 percent smaller}; ascorbic acid, 12.3 million pounds (10.0 percent 
larger); anti-infective sulfonamides, 6.1 million pounds (0.2 percent 
larger); penicillins (except semi-synthetic), 3,827 trillion units (18.1 
percent smaller); tetracyclines, 1.8 million kilograms (19.0 percent 
smaller); vitamin A, 1,005 trillion units (4.5 percent smaller); and 
vitamin E, 1,502 billion units (53.0 percent larger). 



»1EDICINAL CHEMICALS 
TABLE 1. --Medicinal chemicals; U.S. production and sales^ 1972 



Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may 
be published. (Leaders are used where the reported data are accepted in confidence and may not be published or 
where no data were reported.) Table 2 lists all medicinal chemicals for which data on production or sales were 
reported and identifies the manufacturer of each] 



Production 



1,000 
pounds 



Grand total 

Acyclic 

Benzenoid^ 

Cy c 1 i c nonb en zenoi d* 

Antibiotics, total ^ 

Bacitracin, for medicinal use 

Erythromycin, for medicinal use 

Neomycin, for all uses 

Penicillins (except semisynthetic), total 

Penicillin G, potassium, for medicinal use 

Penicillin G, procaine, for medicinal use 

All other, for all uses 

Semisynthetic penicillins, for medicinal use, total- 

AmpiGillin 

Ampicillin, sodium 

All other 

Tetracyclines, for all uses 

Other antibiotics, total 

For medicinal use' 

For nonmedicinal uses 

Antihistamines, total 

Antinauseants 

Chlorpheniramine maleate 

All other 

Anti-infective agents (except antibiotics), total 

Anthelmintics, total 

Piperazine 

Piperazine dihydrochloride 

Piperazine hydrochloride 

All other 

Antifungal agents 

Antiprotozoan agents, total 

Arsenic and bismuth compounds 

All other 

Mercury compounds 

Sulfonamides 

Other anti-infective agents' 

Autonomic drugs, total 

Parasympatholytic (anticholinergic) tertiary amines 

Sympathomimetic (adrenergic) agents, total 

Epinephrine hydrochloride (racemic) 

Phenylephrine base and bitartrate 

Phenylephrine hydrochloride 

Phenylpropanolamine hydrochloride 

All other 

Other autonomic drugs 

Cardiovascular agents, total 

Vasodilators 

Other cardiovascular agents 



101,747 
111,444 



16,637 



2,174 

837 

2,887 

931 

779 

20 

132 

3,899 

5,249 

1,857 

3,392 

483 



30 
375 



34,364 



12,914 

3,581 

1,824 

352 

7,157 

875 

10,233 

6.077 

4,156 

14 

6,078 

4,250 



308 
172 
47 



1,000 
pounds 



163.210 



82,128 
68,279 
12,803 

5.384 



20 

250 

199 

2,545 



2,545 
332 
302 

30 

790 

1,248 

608 

640 

330 



9.464 

1,915 

240 

7.309 

7.292 
4,574 
2,718 
8 
1,928 
3,325 



276 
113 



1,000 
dollar's 



490.137 



56,878 
319.665 
113.594 

139.212 



1,390 
6,269 
2,473 
22,791 



22,791 
32,708 
29,226 

3.482 
17,735 
55,846 
47.315 

8.531 

7.878 



292 
7.586 



77.672 



43,591 

1,420 

165 

42,006 

16.380 
5,633 

10,747 

533 

7.664 

9.504 

9.540 



1,537 
6.268 



2.538 
1.611 
2.119 
1,735 

15.628 



15,628 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS. W2 ■ 
TABLE 1, --Medicinal chemicals; U.S. production and sales, 1972--Continued 



Production' 



Sales' 



Quantity 



Unit 
Value^ 



Central depressants and stimulants, total 

Amphetamines 

Analgesics and antipyretics, total 

Aspirin 

Meperidine hydroch loride 

Salicylates (except aspirin) 

All other 

Antidepressants 

Barbiturates, total 

Pentobarbital , sodium 

All other 

Hydrocodone bit art rate 

Hypnotics and sedatives (except barbiturates) 

Skeletal muscle relaxants 

Tranquilizers 

Other central depressants and stimulants^ 

Dermatological agents and local anesthetics, total 

Salicylic acid 

All other 

Diagnostic agents 

Expectorants and mucolytic agents, total 

E thy lenedi amine dihydriodide 

Guaiacol and its derivatives 

All other 

Gastrointestinal agents and therapeutic nutrients, total- 

Amino acids and salts 

Choleretics and hydrocholeretics 

Choline chloride (all grades) 

All other 

Hematological agents, total 

Sodium heparin 

All other 

Hormones and synthetic substitutes, total 

Antithyroid agents 

Corticosteroids 

Estrogens and progestogens 

Synthetic hypoglycemic agents 

All other 

Renal-acting and edema- reducing agents, total 

Benzothiadiazine derivatives 

Mercurial diuretics 

Theophylline derivatives 

All other 

Vitamins, total 

Vitamin A alcohol and esters, total'^ 

Vitamin A palmitate (feed grade) 

All other 

Vitamin B-complex, total 

Niacin and niacinamide (all grades) 

Pantothenic acid and derivatives, total 

Calcium pantothenate (racemic)-calcium chloride 
complex 

All other 

Riboflavin (all grades) 

Other B-complex vitamins 

Vitamin C, total 

Ascorbic acid 

All other 



1,000 
pounds 



52,430 



45 


950 


35 


007 




28 


3 


262 


7 


653 




110 




567 



567 

1 

246 

133 

1,126 

4,297 



10,426 



8,694 
1,732 



924 
2,960 



1,335 

1,625 

79.934 



1,346 

150 

54,450 

23,988 

91 



1,325 
209 



1,650 



115 
1,535 



30,030 



1,037 

443 

594 

10,344 

5,475 

3,049 



1,964 

1,085 

1,011 

809 

15,588 

12,312 

3.270 



1,000 



29,358 



1,000 
dollars 



55.558 



24,895 



2,541 
22,354 



97 
28,822 



577 
245 

904 
116 
788 
455 



9,296 
1,279 



1,322 
1,351 



42,793 
23,755 



CO 



23.399 



1,010 
552 
458 
9,019 
4,920 
2,475 

1,732 

743 

788 

836 

11,067 

8,293 

2,774 



464 
724 



017 
972 
838 



931 
082 
849 
574 
882 
599 

978 
621 
198 
895 
644 
006 
638 



Pep 
pound 

$1.89 



flEDICINAL CHEMICALS . 
TABLE 1,— Medicinal chemicals: U.S. production and sales> 1972— Continued 



Production 



Quantity 



Unit 
Value ^ 



Vitamins- -Continued 

Vitamin D'^ 

Vitamin E, total'^ 

d-and dl-Alpha tocopheryl acetate (all grades) 

All other 

Vitamin K 

Miscellaneous medicinal chemicals'' 



1,000 
pounds 



,905 
.268 
637 
143 



1,000 
pounds 



2,220 

1,623 

597 



1,000 
dollars 



1,404 

34,333 

20,336 

13,997 

548 



Per 
poimd 



$156.00 
15.47 
12.53 



5,721 



' The data on production and sales are for bulk medicinal chemicals only; they exclude finished preparations 
and dosage-form products, which are manufactured from bulk chemicals. All quantities are given in terms of 
lOO'o active ingredient. 

^ Calculated from rounded figures. 

' The term "ben:enoid," as used in this report, describes any cyclic medicinal chemical whose molecule con- 
tains either a six-membered carbocylic ring with conjugated double bonds (e.g., the benzene ring or the quinone 
ring) or a six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, e.xcept the 
pyrimidine ring (e.g., the pyridine ring or the pyrazine ring.) 

"* Includes antibiotics of unknown structure. 

^ With the exception of bacitracin, the penicillins (except semisynthetic), and a few other antibiotics which 
were reported in terms of U.S. P. units, all quantities for antibiotics were reported as grams of antibiotic base. 
(Thus production of 480,900 grams of tetracycline hydrodiloride, for example, would have been reported as 444,430 
grams of tetracycline base.) For inclusion in the main statistical table, all quantities were converted from 
grams of antibiotic base to pounds of antibiotic base (453.6 grams = 1 pound) or from U.S. P. units to pounds (22.7 
million units of bacitracin, 458 million units of procaine pencillin G, 723 million units of potassium peni- 
cillin G, etc. = 1 pound). The following tabulation shows statistics for all individually publishable antibiotics 
in terms of kilograms of antibiotic base (Kg) or billions of U.S. P. units (BU) : 



Antibiotic 



Unit of 
quantity 



Quantity 



Unit 
Value 



Bacitracin, for medicinal use — 
Erythromycin, for medicinal use- 
Neomycin, for all uses 



Penicillins (except semisynthetic), total 

Penicillin G, potassium, for medicinal use — 

Penicillin G, procaine, for medicinal use 

All other, for all uses 



Semisynthetic penicillins, for medicinal use 

total 

Ampicillin 

Ampicillin, sodium 

All other 



Tetracyclines, for all uses- 



-BU--- 
-BU--- 



437 
290,582 



3,827.078 

1,572,130 

383,202 

1,871,746 



422,353 

353.302 

8.852 

60,199 

1.768.797 



459 
113.424 
90,119 



150,448 
137,104 



13,344 
358,477 



1,000 
dollars 

1,390 
6,269 
2.473 

22,791 



32 


708 


29 


226 


3 


482 


17 


735 



53,028.32 
55.27 
27.44 

15.13 
15.13 



217.40 
213.17 



260.94 
49.47 



' Production of all antibiotics for medicinal use amounted to 9,817,000 pounds; sales amounted to 3.484.000 pounds, 
valued at $115,855,000. 

' Production of all antibiotics for animal feeds and other nonmedicinal uses amounted to 6.820.000 pounds; sales 
amounted to 1,900,000 pounds, valued at $23,357,000. 

^ Includes sales of antifungal agents. 

' Includes production of amphetamines and production and sales of anticonvulsants, antitussives, general anesthetics, 
and stimulants; also includes sales of antidepressants, hypnotics and sedatives (except barbiturates), skeletal 
muscle relaxants, and tranquilizers. 

'° Data published for 1971. and possibly for earlier years as well, includes some production and sales of technical 
grade salicylic acid erroneously reported as medicinal grade. 



SYNTHETIC ORGANIC CHEMICALS. 1972 

Footnotes for table l--Continued 

^^ Sales of mercurial diuretics amounted to 318 pounds. 

^^ All quantities for vitamin A, B12, D, and E were reported in terms of grams or units, but were converted to 
pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 billion units 
of vitamin A palmitate, 453.6 grams of vitamins B12, 18.14 billion units of vitamin D, 617,000 units of d-alpha 
tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). The following tabulation shows 
statistics for these vitamins, except for B12, which was not separately publishable, in terms of million of inter- 
national units (MU) or billion of U.S. P. units (BU) : 



Unit 

of 

quantity 



Quantity Value 



Unit 
value 



Vitamin A, total 

Vitamin A palmitate (faed grade) - 
All other 

Vitamin D 

Vitamin E, Total 

d-and dl-Alpha tocopheryl acetate 

(all grades) 

All other 



BU- 

BU- 



MU--- 



1,005,425 
365,303 
640,122 

233,391 

1,501,785 

1,131,189 
370,596 



944,556 
454,540 
490,016 

158,558 

1,168,840 

817,079 
351,761 



1,000 
dollars 

18,931 

7,082 

11,849 

1,404 

34,333 

20,336 
13,997 



$20.04 
15.58 
24.18 



24.89 
39.79 



Includes production and sales of antineoplastic agents, smooth-muscle relaxants, and unclassified medicinal 
chemicals; also includes sales of diagnostic agents and "all other" hematological agents. 



MEDICINAL CHEMICALS 

Table 2. --Medicinal chemicals for which U.S. production or sales were reported- 
identified BY MANI"^ACTURER, 1972 

[Medicinal chemicals tor which separate statistics are given in table 1 are marked below with an asterisk (*J ; medic- 
inal chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



'Antibiotics: ' 

'Bacitracin 

'Eryth romycin 

'Neomycin: 

For medicinal use 

For nonmedicinal uses 

'Penicillins (except semisynthetic): 

•Penicillin G, potassium 

'Penicillin G, procaine 

'All other: 

Penicillin G, benzathine 

Penicillin G, procaine, for nonmedicinal uses- 
Penicillin G, sodium 

Penicillin 0, sodium 

Phenoxymethylpenicillin (Penicillin V) 

Phenoxymethylpenici 11 in, benzathine 

Phenoxymethylpenicillin, hydrabamine 

Phenoxymethy Ipeni ci llin, potassium 

'Semisynthetic penicillins, for medicinal use: 

'Ampicillin 

'Ampicillin , sodium 

Carbenicillin 

Cloxacillin, sodium 

Die loxaci llin, sodium 

Hetacillin 

Methicillin, sodium 

Nafcillin, sodium 

Oxacillin, sodium 

Phenethicillin, potassium 

'Tetracyclines : 

Chlortetracycline 

Chlortetracycline, tor nonmedicinal uses 

Uemeclocycline 

Doxycycline 

Methacycline 

Minocycline 

Oxytetracycline 

Tetracycline 

'Other antibiotics: 
'For medicinal use: 

Amphotericin B 

Candicidin 

Cephalexin 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Clindamycin 

Cycloserine 

Dihydrostreptomycin 

Fumagillin 

. Gentamycin 

Gramicidin 

Kanamycin 

Lincomycin 

Novobiocin 

Nystatin 

Oleandomycin 

Paromomycin 

Pol\-myxin B 

Spectinomycin 

Streptomycin 

Thiostrepton 

Tro leandomy cin 

Vancomycin 

Viomycin 

See footnotes at end of table. 



COM, 


PEN, 


PFZ, 


PMP 


ABB, 


LIL, 


UPJ. 




OMS, 


PEN, 


PFZ, 


UPJ 


PFZ. 








LIL, 


OMS, 


PFZ, 


WYT 


LIL, 


OMS, 


PFZ, 


WYT 


WYT. 
MRK, 


OMS. 






OMS. 








PFZ. 








BRS, 
WYT. 


LIL, 


OMS. 





BEE 
BEE 
BEE 
BEE 
BEE 
BRS 
BEE 
WYT 
BEE 
BRS 

ACY 
ACY 
ACY 
PFZ 
PFZ 
ACY 
PFZ 
ACY 



OMS. 
PEN. 
LIL. 
LIL. 
LIL. 



COM. 
MKK, 
ABB. 
sen. 
PEN. 
BRS. 
UP.]. 
MRK, 
ACY, 
PFZ. 
MKK. 
PFZ. 
ABB, 
LIL, 
OMS. 
PFZ. 
LIL. 
PFZ. 



LIL. 

BOC, BRS, TRD, WYT. 

OMS, IVYT. 

PFZ. 

BRS. 

BRS, WYT. 

BRS. 

BRS. 



BRS, PFZ, RLS. 



UPJ. 
OMS. 



UPJ. 
MRK, PFZ. 



SYNTHETIC ORGANIC CHE.IICALS, 1972 



Table 2.- 



-MeDICINAL chemicals for which U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manutacturers' identification codes 
(according to list m table 3) 



•Antibiotics -rContinued 

*Other antibiotics--Continued 
*For nonmedicinal uses: 

Bacitracin 

Cy cloheximide 

Hygronycin B 

Li ncomy c in 

Monensinj sodium 

Novobiocin 

Nystatin 

Spectinomycin 

Streptomycin 

Tylosin 

•Antihistamines ; 
•Antinauseants : 

Cyclizine liydrociiloride 

Dimenhydrinate 

Meclizine hydrochloride 

Trimethobenzamide hydrochloride 

Bromodiphenhydrami ne hydroch loride 

Brompheniramine maleate 

Carbinoxamine 

Chlorcyclizine hydrochloride 

Chlorothen citrate 

•Chlorpheniramine maleate 

Chlorpheniramine tannate 

Cyprohept adine hydroch loride 

Dexbrompheniramine maleate 

Dexchlorphenirajnine maleate 

Dimethindene maleate 

Diphenhydramine hydrochloride 

Doxylamine succinate 

Methapyrilene fumarate 

Methapyrilene hybenzate 

Methapyrilene hydrochloride 

Methdilazine 

Methdilazine hydrochloride 

Phenindamine tartrate 

Pheniramine maleate 

Phenyltoloxamine citrate 

Pyrilamine maleate 

Pyrilamine resin adsorbate 

Pyri 1 amine t annate 

Pyrrobut amine phosphate 

Thenyldi amine hydrochloride 

Thonzylamine hydrochloride 

Tripelennamine 

Tripelennamine citrate 

Tripelennamine hydrochloride 

iriprolidine hydrochloride 

•Anti-infective agents (except antibiotics): 
•Anthelmintics: 

2,2-Dichlorovinyl dimethyl phosphate (DVPP)- 

Uiethylcarbamazine citrate 

2,6-Uiiodo-4-nitrophenol 

Gentian violet 

Hexylresorcinol 

Phenothiazine 

•Piperazine 

Piperazine citrate 

•Piperazine dihydroch loride 

Piperazine hexahydrate 

"Piperazine hydrochloride 

Piperazine phosphate 

Piperazine sulfate 



COM, 


GPR. 


PhN, PMP. 


UPJ. 






LIL. 






UPJ . 






LIL. 






UPJ. 






QMS. 






UPJ. 






MRK, 


PFZ. 




LIL. 






BUR. 






HEX, 


SRL. 




PF2. 






HOF. 






PD. 






SCH. 






SCH. 






ABB, 


BUR. 




ALY. 






HEX, 


HFT, 


SCH, SK. 


MAL. 






MRK. 






SCH. 






SCH. 






CGY. 






CAN, 


PD. 




BJL, 


BKC. 




ABB. 






LIL. 






ABB. 






BJL. 






BJL. 






HOF. 






HEX, 


HFT, 


SCH. 


BRS. 






HEX, 


MRK, 




MRK. 






MAL. 






LIL. 






SUW. 






NEP. 






CGY. 






CGY. 






CGY . 






BUR. 






SHC. 






ACY. 






RSA. 






SDH. 






NRK. 






WAG. 






DOW, 


FLM, 


JCC, UCC 


BUR. 






DOW, 


FLM, 


JCC, WIIL 


JCC. 






DUW, 


FLM, 


.ICC. 


BUR, 


JCC. 




JCC, 


SAL. 





^lEDICINAL CHEMICALS 



Table 2. 



-Medicinal chemicals for which U,S, production or sales were reported, 
identified by manufacturer, 1972— continued 



Manufacturers' identification codes 
(according to list in table 5) 



*Anti-infective agents (except antibioticsJ--Continued 
*Anthelniintics- -Continued 

Pyrvinium pamoate 

Thiabendazole 

'Antifungal agents: 

Benzoic acid 

Calcium undecylenate 

Fuchsin, basic 

Sodium caprylate 

Sodium undecylenate 

Undecylenic acid 

Zinc undecylenate 

*Antipropozoan agents: 

Aklomide 

Amodiaquin 

Amodiaquin hydrochloride 

Amprolium 

*Arsenic and bismuth compounds: 

Arsanilic acid 

Bismuth dipropylacetate 

Bismuth subsalicylate 

Carbarsone 

Glycobiarsol 

Nitarsone 

Roxarsone 

Roxarsonej sodium 

Sodium arsani late 

Chloroqulne phosphate 

Dimetridazole 

Diiodohydroxyquin 

3,S-Dinitro-o-toluaraide 

Furazolidone 

Hydroxy ch loroquine su 1 fate 

lodochlorhydroxyquin 

Metronidazole 

Nifuroxime 

Nifursol 

Nihydrazone 

Nithiazide 

Nitromide 

Nitrophenide 

Primaquine phosphate 

Pyrimethamine 

*Mercury compounds : 

Merbromin 

Mercuric salicylate 

Ni tromerso 1 

Phenylmer curie acetate 

Phenylmercuric borate 

Phenylmercuric chloride 

Phenylmercuric nitrate 

Thimerosal 

'Sulfonamides: 

Acetyl sulfamethoxypyridazine 

Acetyl sulfisoxazole 

Dinsed 

Mafenide acetate 

Mafenide hydrochloride 

Phthalylsul facet amide 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Sulfabenz amide 

Su 1 f aben z ami de , s odium 

Sulfabromomethazine, sodium 

Sulfacetamide 

Sulfacetamide, sodium 

Su 1 f ach loropyraz ine , sodium 



MRK. 

MON. 
WTL. 
ACS. 
LEM. 
NIL. 
NIL. 
NTL, IVIL. 

SAL. 
PU. 
PD. 
MRK. 

abb, flm, whl. 
nwl, nor, PBN. 

LIL, WHL. 

SDW. 

SAL. 

SAL. 

SAL. 

SAL. 

SDW. 

RDA. 

SKL. 

DUW. 

NUR. 

SDW. 

CGY. 

RDA. 

NOR. 

LEM. 

NOR. 

MRK. 

PEN, SAL. 

ALY. 

PD. 

BUR. 

HYN. 

MRK. 

ABB 

WRC. 

MRK. 

WRC. 

MRK, WRC. 

LIL. 

ACY. 

HOF. 

SAL. 

SDW. 

SDW. 

CTN. 

MRK . 

MRK. 

ACY. 

ACY. 

MRK. 

CIN. 

CTN. 

ACY. 



552-743 O - 74 . 



SYNTHETIC ORGANIC CHEMICALS, 1972 



Table 2. --Medicinal chemicals for which U.S. production or sales were reported- 
identified BY manufacturer. 1972— CONTINUED 



* Anti-infective agents (except antibiotics) --Continued 
*Sulfonamides--Continued 

Sulfachloropyridazine, sodium 

Sulfadiazine 

Sulfadiazine, sodium 

Sulfadimethoxine 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine, sodium 

Sulfamethazine 

Sulfamethazine, sodium 

Sulfamethizole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanitran 

Sulfapyridine 

Sulfapyridine, sodium 

Sulfaquinoxaline 

Sulfathiazole 

Sulfathiazole, sodium 

Sulfisoxazole 

Sulfisoxazole, sodium 

•Other anti-infective agents: 

Acriflavine 

Aminacrine 

Aminacrine hydrochloride 

Antileprotic and antitubercular agents; 

Aminosalicylic acid 

Ethionamide 

Isoniazid 

Sodium aminosalicylate 

Sodium sulfoxone 

Antiviral agent: Amantadine hydrochloride 

Benzalkonium chloride 

Bromoform 

Camphor , monobromated 

Garb adox 

Cetalkonium chloride 

Cetylpyridinium chloride 

Chlorobutanol 

Furamazone 

8-Hydroxy-S-quinolinesulfonic acid 

Iodoform^ 

Nalidixic acid 

Nitrofurathiazide 

Nitrofurazone 

Oxolinic acid 

Oxyquinoline 

Oxyquinoline benzoate 

Oxyquinoline citrate 

Oxyquinoline sulfate 

Phenolic antiseptics and disinfectants: 

Biothionol 

Chlorothymol 

Resorcinol' 

Thymol 

Thymol iodide 

Povidine - iodine complex 

Trimethoprim 

Urinary antiseptics: 

Mandelic acid 

Methenamine base and salts: 

Methenamine 

Methenamine hippurate 

Methenamine mandelate 

Methylene blue 

Nitrofurahtoin 

Phenazopyridine hydrochloride 



Manufacturers' identification codes 
(according to list in table 3) 



ACY. 

ACY. 

ACY. 

HOP. 

ACY, SAL. 

ACY. 

ACY. 

ACY, CTN. 

ACY. 

ACY, CTN. 

HOP. 

ACY. 
MRK, SAL. 

SAL. 

ACY, CTN. 

ACY, CTN. 

MRK. 

ACY, MRK. 

MRK, SAL. 

HOP. 

HOP. 

ACS. 
SDW. 
SDW. 

MLS. 

RDA. 

RIL. 

MLS. 

ABB. 

DUP. 

SDH. 

DOW. 

PEN. 

PF2. 

FIN, SDW. 

FIN, HEX. 

BPC, PD. 

NOR. 

MRK. 

MAL. 

SDH. 

SCH. 

NOR. 

NEP. 

FIS, MRK. 

FIS. 

FIS, MRK. 

FIS, MRK. 

SDH. 
ACY. 
KPT. 
GIV. 
MAL. 
GAF. 
BUR. 

MAL. 

ARN. 
RIK. 

MAL, NEP. 
ACY. 

NOR, RLS. 
HOP, NEP. 



See footnotes at end of table. 



MEDICINAL CIIE'^IICALS 



Table 2. 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 — CONTINUED 



Manufacturers' identification codes 
(according to list in table 3} 



* Autonomic drugs: 

'Parasympatholytic (anticholinergic) tertiary amines: 

Adiphenine hydrochloride 

Cycrimine hydrochloride 

Dicyclomine hydrochloride 

Orphenadrine citrate 

Orphenadrine hydroch loride 

Oxyphencyc limine hydrochloride 

Piperidolate hydrochloride 

Thiphenamil hydrochloride 

Trihexyphenidyl hydrochloride 

'Sympathomimetic (adrenergic) agents: 

Cinnamedrine hydrochloride 

Cyclopent amine hydrochloride 

Epinephrine bitartrate (levo) 

'Epinephrine hydrochloride (racemic) 

H- Isoproterenol bitartrate 

Isoproterenol i.)''roch loride 

I soprot ereno 1 sulfate 

Levarterenol bitartrate 

Me thoxyphen amine hydrochloride 

Naphazoline hydrochloride 

Nordefrin hydrochloride 

Nylidrin hydrochloride 

'Phenylephrine base and bitartrate: 

Phenylephrine 

Phenylephrine bitartrate 

'Phenylephrine hydrochloride 

•Phenylpropanolamine hydrochloride 

Propylhexedrine 

Protokylol hydrochloride- 

Pseudoephedrine hydrochloride 

Pseudoephedrine sulfate 

Tetrahydrozoline hydrochloride 

'Other autonomic drugs: 

Ganglionic blocking agents: 

Hexamethonium chloride 

Tetraethyl ammonium chloride 

Parasvinpatholytic (anticholinergic) quaternary 
ammonium compounds: 

Ambutonium bromide 

Diphemanil methyl sulfate 

Hexocyclium methyl sulfate 

Isopropamide iodide 

Mepenzolate bromide 

Pipenzolate bromide 

Tridihexethyl iodiue 

Parasympatholytic (anticholinergic) tropane 
derivatives : 

Anisotropine methyl bromide 

Benztropine mesylate 

Homatropine hydrobromide 

Homatropine methylbromide 

Homatropine terephthalate 

Parasympathomimetic (cholinergic) agents: 

Neostigmine bromide 

Neostigmine methyl sulfate 

Physostigmine salicylate 

Pyridostigmine bromide 

Sympatholytic (antiadrenergic) agent: Ergonovine 
maleate. 
'Cardiovascular agents: 
'Vasodilators: 

Amy I nitrite 

Clonitrate 

Cyclandelate 

Dioxyline phosphate 

Ethyl nitrite 

Isosorbide di nit rate 

Mannitol hexanitrate 

Nicotinyl alcohol tartrate 

Pentaerythritol tetranitrate 



CGY. 
LIL. 
BKC. 
RIK. 
RIK. 
PFZ. 
LKL. 
BJL. 
ACY, SDW. 

SDW. 

LIL. 

SDW. 

ECL, VB. X. 

SDW. 

SDW. 

ABB. 

SDW. 

X. 

CGY. 
SDW. 
BKL. 

CTN, CAN, SDW. 

GAN. 

CTN, GAN, HEX, SDW. 

ARS, BKL, GAN, HEX, NEP, ORT, PD. 

HEX, SK. 

LKL. 

BUR, GAN. 

GAN. 

PGZ. 



RSA. 
RSA. 



BJL. 

SCH. 

ABB. 

SK. 

LKL. 

LKL. 

ACY. 



CTN. 

CTN, HEX. 
EN. 

HEX, HOF. 

MOF. 

PEN. 

HOF. 

LIL. 



MAL. 
ICI. 
WYT. 
LIL. 
MAL. 
ICI. 
ICI. 
HOF. 
ICI. 



SYNTHETIC ORGANIC CHEMICALS. 1972 



Table 2. 



-Hedicinal chemicals for which U.S, production or sales were reported, 
identified by manufacturer, 1972 — continued 



*CardiovascuJar agents --Continued 

*Other cardiovascular agents: 

Antihypertensive agents: 

Guanethidme sulfate 

Hydralazine hydrochloride 

Methyldopa 

Pargyline hydrochloride 

Rauwolfia and veratrum alkaloids: 

Alkavervir 

Kaunormine 

Reserpine 

Bioflavonoids : 

Hesperidin 

Lemon bioflavonoids 

Naringin 

Cardiac drugs: 

Procainamide hydrochloride 

Quinidine sulfate 

Colestipol 

*Central depressants and stimulants: 
*Aiiiphetamines : 

Amphet amine (racemi c) 

Amphetamine sulfate (racemic) 

Dextroamphetamine hydrochloride 

Dextroamphetamine phosphate 

Dextroamphetamine sulfate 

Levamphet amine succinate 

Methamphetamine hydrochloride (dextro)- 

Methamphet amine saccharate 

•Analgesics and antipyretics: 

* Aspirin 

'Meperidine hydrochloride 

♦Salicylates (except aspirinj: 

Aluminum aspirin 

Phenyl salicylate 

Potassium salicylate 

Salicylamide 

Salicylsalicylic acid 

Sodium salicylate 

*Other analgesics and antipyretics: 

Acetaminophen 

p-Arainobenzoic acid and salts: 

Aminubenzoic acid 

Calcium aminobenzoate 

Potassium aminobenzoate 

Sodium aminobenzoate 

Anileridine hydrochloride 

Calcium succinate 

Dextropropoxyphene napsylate 

Ethoheptazine citrate 

Indome th acin 

Mefenamic acid 

Methadone hydrochloride 

Oxycodone hydrochloride 

Oxycodone tereph thai ate 

Oxyphenbutazone 

Pentazocine 

Pentazocine hydrochloride 

Phenacetin 

Phenylbutazone 

Propoxyphene hydrochloride 

'Antidepressants : 

Ami tripty line 

Desipramine hydrochloride 

Doxepin hydrochloride 

Imipramine hydrochloride 

Isocarboxazid 

Nialamide 

Nortriptyline 

Phenelzine sulfate 



Manufacturers' identification codes 
(according to list in table 3) 



CGY. 
CGY. 
MRK. 
ABB. 

RIK. 
PEN. 
PEN. 

SKG. 
bKG. 
SKG. 

QMS, 
HEX. 
UPJ. 



ORT. 
HEX. 
ARN. 
ARN. 
ARN, 
ARN. 
ARN. 
RSA. 



DOW, MLS, HON, NOR, SDG. 
PEN, SDW, WYT. 



DOW. 

HN. 

PEN. 



ATP, MAL, NEP, PEN. 

LEM, PD. 

GAN. 

GAN. 

GAN. 

MRK. 

LEM. 

LIL. 

WYT. 

MRK. 

PD. 

LIL. MAL, PEN. 

EN. 

EN. 

CGY. 

SDW. 

SDW. 

MON. 

CGY. 

LIL. KLS. 



MRK. 
CGY. 
PF2. 
CGY. 
HOP. 
PFZ. 
LIL. 
NEP. 



MEDICINAL CHEHICALS 



Table 2. --Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



■"Central depressants and stimulants — Continued 
*Barbiturates : 

Allylbarbituric acid, sodium 

5-Allyl-5- (2-cyclopenten-l-yl)barbituric acid 

Amobarbital 

Amobarbital , sodium 

Barbital 

Barbital, sodium 

But abarbi t al 

Butabarbital , sodium 

5-sec-Butyl-5-ethyl-2- thiobarbituric acid, sodium 

derivative 

Hexobarbital 

Mephobarbital 

Metharbital 

Methohexital , sodium 

Pentobarbital 

*Pentobarbital , sodium 

Phenobarbital 

Phenobarbital , sodium 

Secobarbital-- 

Secobarbital , sodium 

Thiamylal , sodium 

Thiopental, sodium 

Vinbarbital 

*Hydrocodone bit art rate 

*Hypnotics and sedatives (except barbiturates): 

Carbroma 1 

Bthchlorvynol 

Ethinamate 

Glutethimide 

Methypry I on 

*Skeletal muscle relaxants: 

Cari soprodo 1 

Chlorphenesin carbamate 

Mephenesin 

Phenaglycodol 

Succinyl choline chloride 

Tubocurarine 

■"Tranquilizers ; 

Buclizine hydrochloride 

Chlorazepate dipotassium 

Chlordiazepoxide hydrochloride 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethoxybutamoxane 

Hydroxyzine hydrochloride 

Hydroxy zine pamoat e 

Meprobamat e 

Methaqualone 

Molindone hydrochloride 

Oxazepam 

Phenothiazine derivatives: 

Acetophenazine maleate 

Chlorpromazine hydrochloride 

Fluphenazine hydrochloride 

Perphenazine 

Prochlorperazine edisylate 

Prochlorperazine maleate 

Promazine hydrochloride 

Promethazine hydrochloride 

Trif lupromazine hydrochloride 

Thiothixene hydrochloride 



GAM. 
CAN. 

GAN, LIL. 
GAM, LIL. 
GAN. 

ABB, GAN. 
ABB, GAN. 
ABB, GAN. 



GAN, bDW. 

GAN, SDW. 

ABB. 

LIL. 

ABB, GAN, PD. 

ABB, GAN, PD. 

GAN, MAL. 

GAN, MAL. 

GAN. 

GAN, LIL. 

GAN, PD. 

ABB, GAN. 

X. 

EN, MAL, MRK, PEN. 



LIL. 




BKL, 


CGY 


HOF. 




BKL. 




UPJ. 




HEX. 




LIL. 




ABB, 


BUR 


ABB, 


OMS 



PFZ. 
ABB. 
HOF. 
SDW. 
HOF. 
HOF. 
LIL. 
PFZ. 
PFZ. 
ABB, BKL. 

X. 

PD. 
WYT. 



OMS, SCH. 
SCH. 
SK. 
SK. 

WYT. 
WYT. 
OMS. 
PFZ. 



SYNTHETIC ORGANIC CHEMICALS, 1972 



Table 2, --Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 — CONTINUED 



*Central depressants and stimulants— Continued 
*Other central depressants and stimulants: 
Anticonvulsants : 

Diphenylhydantoin 

Diphenylhydantoin, sodium 

Ethosuximide 

Ethotoin 

Methsuximide 

Phenacemide 

Phensuximide 

Antitussives: 

Benzonatate 

Caramiphehen edisylate 

Carbetapentane citrate 

Codeine 

Dextromethorphan hydrobromide 

Ethylmorphine hydrochloride 

Thebaine 

General anesthetic: 

Ket amine hydrochloride 

Vinyl ether 

Stimulants: 

Benzphet amine hydrochloride 

Caffeine: 

Natural 

Synthetic 

Caffeine, citrated 

Caffeine^ sodium benzoate 

Chiorphentermine hydrochloride 

Deanol acetamidobenzoate 

Diethylpropion 

Naloxone hydrochloride 

Nikethamide 

Phent ermine 

*Uermatological agents and local anesthetics: 
Dermatological agents: 

Allantoin 

Aluminum pheno Isul f onat e 

Ammonium pheno Isu If onat e 

Bismuth subgallate 

Glycol salicylate 

'Salicylic acid ' 

Sodium phenol sulfonate 

Zinc phenol sulfonate 

Local anesthetics: 

Butacalne sulfate 

Butamben pi crate 

Butyl aminobenzoate (Butamben) 

Dibucaine 

Dibucaine hydrochloride 

Isobutyl aminobenzoate 

Lidocaine 

Oxethazaine 

Phenacaine hydrochloride 

Pramoxine hydrochloride 

Procaine hydrochloride 

Proparacaine hydroch loride 

Propoxycaine 

Tetracaine 

'Diagnostic agents: 

Roentgenographic contrast media: 

Acetrizoate, sodium 

Diatrizoate, meglumine 

Diatrizoate, sodium 

lodipamide, meglumine 



Manufacturers' identification codes 
(according to list in table 3) 



PU. 
ABB. 

py. 

ABB. 
PU. 

CGY. 

SK. 

PFZ. 

MRK. 

HOF. 

MAL, MRK. 

MRK 

PD. 



GNF. 




PFZ. 




MAL. 




GAN, 


MAL. 


NEP. 




RIK. 




BKC. 




MAL. 




CGY. 




HEX. 




HFT. 




MAL, 


SAL. 


SAL. 




MAL. 




RDA. 




DUW, 


HN, MON, 


SAL. 




MAL, 


SAL. 


ABB. 




ABB. 




ABB. 




CGY. 




CGY. 




RSA. 




AST, 


RLS, SDW. 


WYT. 




SDW. 




ABB. 




PFZ, 


UUP. 


QMS. 




SOW. 




SDW. 




MAL 




0Mb 


SUW. 


CMS, 


SDW. 


UMS 





See footnotes at end of table. 



MEDICINAL CHEMICALS 



Table 2. 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3J 



•Diagnostic agents--Continued 

Roentgenographic contrast media — Continued 

lodipamide, sodium 

lodohippurate, sodiujn 

lopanoic acid 

lophendylate 

lothalamate, meglumine 

lothalamate, sodium 

Methiodal, sodium 

Other diagnostic agents: 

Betazole hydrochloride 

Indocyanine green (cardiac output test) 

Metyrapone (pituitary function test) 

Phenolphthalein monophosphate, dicyclohexalamine salt- 

Phenolsulfonphthalein (kidney function test) 

•Expectorants and mucolytic agents: 

*Ethylenediamine dihydr iodide 

*Guaiacol and its derivatives: 

Glyceryl guaiacolate 

Guaiacol 

Potassium guaiacol sulfonate 

lodinated glycerol 

Lobe line sulfate 

Terpin hydrate 

■fhonzonium bromide 

•Gastrointestinal agents and therapeutic nutrients: 
•Amino acids and salts: 

Amino acid mixtures 

Aspartic acid 

Beta- alanine 

Glutamic acid and salts: 

Glutamic acid hydrochloride 

Potassium glutamate 

Lysine hydroch loride 

H-Tyrosine 

•Choleretics and liydrocholeretics: 

Bile acids, oxidized 

Uehydrocholic acid 

Florantyrone 

Iron bile salts 

Ox bile extracts 

Sodium dehydrocholate 

Tocamphyl 

•Choline chloride: 

Feed grade 

Medicinal grade 

•Other gastrointestinal agents and therapeutic 
nutrients : 
Gastrointestinal agents: 
Cathartics : 

Magnesium citrate 

Phenolphthalein 

Podophyllin 

Sodium tartrate 

Lipotropic agents: 

Betaine base 

Betaine hydrochloride 

Choline bicarbonate 

Choline bi tart rate 

Choline citrate (Iricholine citrate) 

Choline dihydrogen citrate 

Methionine, hydroxy analogue, calcium salt 

Sitosterols 



QMS. 

mal. 

SDW. 

x. 

MAL. 

MAL. 

SDW. 



CGY. 
NEP. 
EK. 



HFT, MAL, WAG, WHL. 



GAN, HEX, PEN. 
MON. 



PEN. 
NEP. 



MDJ. 
HEX. 
DA, HFT. 

LEM. 
LEM. 
MRK. 
MDJ. 

SRL. WIL. 
WIL. 
SRL. 

LIL, WIL. 
ABB, WIL. 
WIL. 

X. 

CUM, DA, DOW, HFT, TMH. 
HFT. 



MON. 




ABB, 


PEN 


MAL 




HFI. 




HFT. 




CUM. 




ACY, 


HFT 


ACY, 


HFT 


ACY, 


HFT 


DUP, 


MON 


LIL, 


UPJ 



SYNTHETIC ORGANIC CHE^ICUS. 197? 



Table 2- 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED 



♦Gastrointestinal agents and therapeutic 

nutrients- -Continued 

*Other gastrointestinal agents and therapeutic 

nutrients- -Continued 

Gastrointestinal agents — Continued 

Other gastrointestinal agents: 

Dihydroxyaluminum aminoacet at e 

Pectin 

Therapeutic nutrients: 

Calcium glucoheptonate 

Calcium gluconate 

Copper gluconate 

Ferrous gluconate 

Liver concentrate 

Liver, desiccated 

Magnesiun gluconate 

Manganese gluconate 

Potassium gluconate 

Zinc glucoheptonate 

'Hematological agents: 
Anticoagulants: 

Ammonium heparin 

Anisindione 

Bishydroxycoumarin 

Diphenadione 

* Sod ium heparin 

Warfarin 

*Other hematological agents: 

Cellulose, oxidized 

Dextran 

Protamine 

*Hormones and synthetic substitutes: 
•Antithyroid agents: 

Methimazole 

Propy 1 1 h iour ac i 1 

2-lhiouracil 

♦Corticosteroids : 

Betamethasone 

Betamethasone phosphate 

Betamethasone valerate 

Cortisone acetate 

Dexamethasone 

Dexamethasone phosphate 

Fludrocortisone acetate 

Fluorometholone 

9a-Fluoroprednisolone acetate 

Fluprednisolone 

Hydrocortisone 

Hydrocortisone acetate 

Medrysone 

Methylprednisolone 

Prednisolone 

Prednisolone acetate 

Prednisone 

Triamcinolone 

iriamcinolone acetonide 

♦Estrogens and progestogens: 

Chlorotrianisene 

Dienestrol diacetate 

Diethylstilbestrol 

Diethylstilbestrol diphosphate 



Manufacturers' identification codes 
(according to list in table 3) 



CHT. 
SKG. 

PFN 
PFZ, 
PFZ. 
PFZ. 

WIL. 
WIL. 
PFZ. 
PFZ. 
PFZ. 



ABB, 


WIL. 




SCH. 






ABB. 






UPS. 






ABB, 


RIK, 


WIL 


SDW. 






EKT. 






PHK. 






lil 






LIL. 






CTN. 






ACY . 






bCH. 






SCH. 






SCH. 






MRK, 


UPJ. 




MKK, 


SCH. 




MRK. 






UPJ. 






UPJ. 






UPJ. 






UPJ. 






MKK, 


PFZ, 


UPJ 


MRK, 


UPJ. 




UPJ. 






UPJ. 






MRK, 


UPJ. 




UPJ. 






MKK, 


SCH, 


UPJ 


ACY, 


UMS, 


X. 


OMS. 






BJL, 


BKC. 




SCH. 






CTN 


LIL. 





MEDICINAL CHEfllCALS 



Table 2,- 



-FIeDICINAL chemicals for which U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



*Horinones and synthetic substitutes — Continued 

'Estrogens and progestogens--Continued 

hstrogenic substances, conjugated 

MedroxvTirogesterone acetate 

Melengestrol acetate 

Natural estrogenic substance 

Norgestrel 

Progesterone 

'Synthetic hypoglycemic agents: 

Acetohexamide 

Chlorpropamide 

Phenformin hydrochloride 

Tolazamide 

I'D Ibut amide 

*Other hormones and synthetic substitutes: 
Anabolic agents and androgens: 

Fluoxymesterone 

Testosterone cypionate 

Zeranol 

Corticotropin (ACTH) 

Glucagon 

Insulin 

Ihyroid 

*Renal-acting and edema-reducing agents: 

*Benzothiadiazine derivatives: 

Bendrof lumethiazide 

Benzthiazide 

Chlorothiazide 

Cyclothiazide 

F lumethiazide 

Hydrochlorothiazide 

Hydroflumethiazide 

Met hyc loth lazide 

Polythiazide 

Irichlormethiazide 

'Mercurial diuretics: 

Meralluride 

Mersalyl acid 

Sodium mercaptomeri n 

'Theophylline derivatives: 

Aminophylline 

Oxtriphylline 

Theophylline sodium glycinate 

'Other renal-acting and edema- reducing agents: 

Acetazol amide 

Chlorthalidone 

Dichlorphenamide 

Ethacrynic acid 

Probenecid 

Triamterene 

'Vitamins : 

'Vitamin A alcohol and esters: 

Beta-carotene (Provitamin A) 

Vitamin A acetate (feed grade) 

Vitamin A acetate (medicinal gradej 

Vitamin A alcohol 

'Vitamin A palmitate (feed gradej 

Vitamin A palmitate (medicinal grade) 



ORG. 
UPJ. 
UPJ. 
OKG. 
WYT. 
UPJ. 

LIL. 
PFZ. 
BKL. 
UPJ. 
UPJ. 



UPJ. 
UPJ. 
COM. 
ORG. 
LIL. 
LIL. 
LIL. 



MKK. 
LIL. 
UMS. 
ABB, 



LGY, MRK. 



LKL. 






SUW. 






WYT. 






GAN, 


SRL. 




NEP. 






CHT. 






ACY. 






CGY. 






MRK. 






MRK. 






MRK. 






ACY, 


SK. 




EKT, 


HOF. 




HOF, 


PFZ. 




HOF, 


PFZ. 




HOF, 


PFZ. 




EKT, 


HDF, 


PF 


EKi, 


HUF, 


PF 



SYNTHETIC ORGANIC CHEMICALS, 1972 



Table 2. 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



'Vitamins --Continued 
*Vitamin B-complex: 

*Niacin and niacinamide (all grades) : 

Niacin (nicotinic acid) (feed grade) 

Niacin (nicotini'- acid) (medicinal grade) 

Niacinamide 

'Pantothenic acid and derivatives: 

Calcium pantothenate (dextro) 

Calcium pantothenate (racemic) (feed grade) 

Calcium pantothenate (racemic) (medicinal grade)-- 
*Calciuin pantothenate (racemic) - calcium chloride 
complex. 

Choline pantothenate 

Dexpanthenol 

Panthenol (racemic) 

Sodium pantothenate 

'Riboflavin (all grades): 

Riboflavin (feed grade) 

Riboflavin (medicinal grade) 

'Other B-complex vitamins: 

Biotin 

Cyanocobalamin (feed grade) 

Cyanocobalamln (medicinal grade) 

Cyanocobalamin (U.S. P. crystalline) 

Cyanocobalamin with intrinsic factor concentrate-- 

Inositol 

Ni acinami de hydrochloride 

Pyridoxine 

Riboflavin-5 -phosphate, sodium 

Thi amine hydroch loride 

Thiamine mononitrate 

'Vitamin C: 

'Ascorbic acid 

falcium ascorbate 

Sodium ascorbate 

'Vitamin D: 

Cholecalciferol (Vitamin D3) 

Ergocalciferol (Vitamin Dj) 

'Vitamin E: 

d- Alpha tocopherol 

dl -Alpha tocopherol 

*d- and dl-Alpha tocopheryl acetate (all grades) : 

d-Alpha tocopheryl acetate 

dl-Alpha tocopheryl acetate: 

Feed grade 

Medicinal grade 

Technical grade 

d-Alpha tocopheryl acid succinate 

'Vitamin K: 

Menadiol sodium diphosphate 

Menadione 

Menadione sodium bisulfite 

Phytonadione 

'Miscellaneous medicinal chemicals: 
Antineoplastic agents: 

Azathioprine 

Mercaptopurine 

Thioguanine 

Vinblastine sul fate 

Vincristine sulfate 

Smooth muscle relaxants: 

Alverine 

Alverine citrate 

Alverine hydrochloride 

Papaverine hydrochloride 

Sodium benzyl succinate 



DA, 


MRK, 


RIL. 




MRK 


RIL 


SCR. 




MRK 


NEP 


PD, RIL, 


SCR 


HFT 
CKL 


DA, 


HFT, PHF. 




DA, 


HFT. 






CKL 


DA, 


DLI, HFT. 




dli 








HFT 


HOF 






HOF 








PD. 









GPR, HOF, MRK, PMP. 
DA, HOF, MRK. 



HOF 






MRK 






MRK 






MRK 






WIL 






STA 






NEP 






HOF 


MRK 




HOF 






HOF 


MRK 




HOF 


MRK 




HOF 


MRK 


PFZ. 


PFZ 






HOF 


MRK 


PFZ. 


DA, 


DLI, 


PHF, VTM 


SCR 


VTM 




CW, 


EKT. 




HOF 






CW, 


EKT. 




HOF 






DA, 


EKT, 


HOF. 


DA. 






CW, 


EKT. 





HOF. 

ABB, HET, WHL. 

ABB, DA, DLI, HET, HFT, WHL. 

MRK. 



BUR. 
BUR. 
BUR. 
LIL. 
LIL. 



CTN. 

X. 

CTN. 

LIL, MAL, PEN. 

FIN. 



MEDICINAL CHEMICALS 
Table 2, --Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED 



Chemical 


Manufacturers' identification codes 
(according to list in table 3) 


Miscellaneous medicinal chemicals--Continued 
Unclassified medicinal chemicals: 


BUR. 

PEN. 

SOW. 

PEN. 

BID, HOF. 

MRK. 

ALD. 


Berberine hydrochloride 

Dopamine hydrochloride 

Hydras t ine hydroch lori de 


Penicillamine (copper chelating agent) 





All antibiotics listed are for medicinal use unless otherwise specified. 
Producers of technical grade are listed in "Miscellaneous chemicals." 
Producers of technical grade are listed in "Cyclic intermediates." 



SYNTHETIC ORGANIC CHEMICALS, 1972 



TABLE 3.— Medicinal Chemicals: Directory of Manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of medicinal chemicals to the U.S. Tariff Commission for 
1972 are listed below in the order of their identification codes as used in table 2] 



Name of company 



Name of company 



Abbott Laboratories 

Allied Chemical Corp., Specialty Chemicals Div. 

American Cyanamid Co, 

Aldrich Chemical Co., Inc. 

Arenol Chemical Corp. 

Arsynco, Inc. 

Astra Pharmaceutical Products, Inc. 

Northern Fine Chemicals, Inc. 

Beecham, Inc. 

Bio-Derivatives Corp. 

Burdick 5 Jackson Laboratories, Inc. 

J.T. Baker Chemical Co. 

Millmaster Onyx Corp., Millmaster Chemical Div. 

Berkeley Chemical Dept . 
Biocraft Laboratories, Inc. 
Stauffer Chemical Co., Specialty Chemical Div., 

Benzol Products 
Bristol-Myers Co., Bristol Laboratories Div. 
Burroughs-Wellcome Co. 

Ciba-Geigy Corp. and Ciba Pharmaceutical Co. 
Chattem Drug 5 Chemical Co., Chattem Chem- 
icals Div. 
Chemlek Laboratories, Inc. 
Commercial Solvents Corp. 
Chemetron Corp., Organic Chemical Div. 
General Mills Chemical, Inc. 

Diamond Shamrock Corp. 

Dawe's Laboratories, Inc. 

Dow Chemical Co. 

E.I. duPont de Nemours 5 Co. , Inc. 

Eastside Chemical Laboratory 
Eastman Kodak Co. : 

Tennessee Eastman Co. Div. 
Endo Laboratories, Inc. 

Fine Organics, Inc. 
Fisher Chemical Co., Inc. 
Fleming Laboratories, Inc. 

GAF Corp., Chemical Div. 

Cane's Chemical Works, Inc. 

Givaudan Corp. 

General Foods Corp., Maxwell House Div. 

Grain Processing Corp. 

Heterochemical Corp. 

Hexagon Laboratories, Inc. 

Hoffman-Taff, Inc. 

Tenneco Chemicals, Inc. 

Hoffmann- LaRoche, Inc. 

Hynson, Westcott 5 Dunning, Inc. 

ICI America, Inc., Atlas Chemical Div. 

Jefferson Chemical Co., Inc. 

Koppers Co., Inc., Organic Materials Div. 

Lemke Chemicals, Inc. 
Eli Lilly S Co. 



MAL 
MDJ 
MLS 
MON 
MRK 

NEP 
NES 
NOR 

NTL 

OMS 
ORG 
ORT 



PEN 
PFN 
PFZ 
PHF 
PHR 
PMP 

RDA 
RIK 
RIL 
RLS 
RSA 

SAL 
SCH 
SCR 

SDG 

SDH 

SDW 

SHC 

SK 

SKG 

SRL 

STA 

TMH 
TRD 

UCC 
HOP 
UPJ 



WAG 
WHL 
WIL 
WRC 
IVTL 



Lakeside Laboratories Div. of Colgate- 
Palmolive Co. 

Mallinckrodt Chemical Works 

Mead Jolinson 5 Co. 

Miles Laboratories, Inc., Marschall Div. 

Monsanto Co. 

Merck 5 Co. , Inc . 

Nepera Chemical Co., Inc. 
Nease Chemical Co., Inc. 
Norwich Pharmacal Co. 
NL Industries, Inc. 



E.R. Squibb S Sons, 
Organics, Inc. 
Roehr Chemicals, Inc 



Inc. 



Parke, Davis S Co. 

CPC International, Inc., 

Pfanstiehl Laboratories, 

Pfizer, Inc. 

Thompson-Hayward Chemical Co. 

Pharmachem Corp. 

Premier Malt Products, Inc. 



Peter Hand Div. 



Rhodia, Inc. 

Riker Laboratories, Inc., Sub. of 3M Co. 

Reilly Tar ^ Chemical Corp. 

Rachel le Laboratories, Inc. 

R.S.A. Corp. 

Salsbury Laboratories 
Schering Corp. 
R.P. Scherer Corp. 
Sterling Drug Corp. : 

Glenbrook Laboratories Div. 

Hilton-Davis Chemical Co. Div. 

Winthrop Laboratories Div. 
Shell Oil Co., Shell Chemical Co. Div. 
Smith, Kline 5 French Laboratories 
Sunkist Growers, Inc. 
G.D. Searle 5 Co. 
A.E. Staley Manufacturing Co. 

Thompson-Hayward Chemical Co. 
Trade Enterprises, Inc. 

Union Carbide Corp. 

Universal Oil Products Co., UOP Chemical Div. 

Upjohn Co. 

Vermi lye- Bell 
Vitamins, Inc. 

West Agro-Chemicals, Inc. 
Whitmoyer Laboratories, Inc. 
Wilson 6 Co., Inc., Wilson Laboratories Div. 
Ventron Corp., Ventron Chemical 
Pennwalt Corp., Lucidol Div. 
Wyeth Laboratories, Inc., Wyeth Laboratories 
Div. of American Home Products Corp. 



-Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix 



121 



FLAVOR ANB PERFUME MATERIALS 



Flavor and perfume materials are organic chemicals used to impart 
flavors and odors to foods, beverages, cosmetics and soaps. These 
aromatic chemicals are also utilized to neutralize or mask unpleasant 
odors in industrial processes and products as well as in consumer 
products. 

Total domestic production of flavor and perfume materials in 1972 
amounted to 110.5 million pounds--an increase of 14.6 percent compared 
to 96.4 million pounds produced in 1971 (table 1).^ Sales of these 
materials in 1972 amounted to 104.0 million pounds, valued at $88.4 
million, compared with 84.8 million pounds, valued at $84.0 million in 
1971. 

Production of cyclic flavor and perfume materials in 1972 amounted 
to 51.8 million pounds; sales amounted to 48.2 million pounds, valued 
at $54.1 million. The individual chemical in the cyclic group produced 
in the greatest volume in 1972 again was benzyl alcohol (10.4 million 
pounds) . 

U.S. output of acyclic flavor and perfume materials in 1972 amounted 
to 58.5 million pounds; sales of these materials amounted to 55.7 million 
pounds, valued at $34.1 million. Monosodium glutamate was by far the most 
important of the acyclic chemicals, and the individual flavor and perfume 
chemical produced in the greatest volume. 

Domestic production of essential oils, chemically modified, in 1972 
amounted to 119 thousand pounds; sales amounted to 93 thousand pounds and 
were valued at $220 thousand. Both cyclic and acyclic compounds were rep- 
resented among the group, however, the totals above for cyclic and acyclic 
flavor and perfume materials do not include items of this group. 



See also table 2 which lists these materials and identifies the 
manufacturers by codes. These codes are given in table 3. 



SY:JTHETIC organic chemicals, 1972 



TABLE 1. --Flavor and perfume materials; U.S. production and sales, 1972 

[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub- 
lished or where no data were reported.) Table 2 lists all flavor and perfume materials for which data on produc- 
tion or sales were reported and identifies the manufacturers of each] 



Quantity 



1,000 
pounds 



Grand total 

FLAVOR AND PERFUME MATERIALS, CYCLIC 

Total 

Benzenoid and Naphthalenoid 

Total 

4-Allyl-2-methoxyphenol (Eugenol) 

p-Anisaldehyde 

Ben zophenone 

Benzyl acetate 

Ben zyl al cohol ^ 

Ben zy 1 benzoate 

Benzyl but yr ate 

Benzyl cinnamate 

Benzyl propionate 

Benzyl salicylate 

Cinnamaldehyde 

Cinnamyl acetate 

Cinnamyl alcohol 

Cinnamyl an th rani late 

Ethyl phenylglycidate 

Hydrocoumarin 

Isobutyl phenyl acetate 

Isobutyl salicylate 

Isopentyl salicylate 

Methyl anthranilate 

a-Methylbenzyl acetate (Styralyl acetate) 

Methyl phenyl acetate 

Methyl salicylate 

Phenethyl acetate 

2-Phenethyl phenylacetate 

3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

Piperonal (He lio tropin) 

p-Propenylanisole (Anethole) 

p-Tolualdehyde 

All other benzenoid and naphthalenoid materials-- 

Terpenoid, Heteroayolio, and Aliayclic 

Total 

Cedryl acetate 

a-Ionone 

p-Menthan-3-one (Methone) 

Menthol, synthetic, u.S.P 

Methylionones 



51.809 



45,756 



473 
1,065 

449 

1,414 

10,440 

408 



419 
1,565 



5,828 



2,650 
17,944 



8,053 



48.166 



41,311 



380 

1,261 

300 

1,678 

13,444 

621 

11 

7 

34 

450 

1,127 

9 

277 

1 



453 
185 



124 
,540 



1,000 
dollars 



54,058 



41,134 



1,044 

1,683 

407 

657 

3,922 

350 

16 

30 

40 

411 

790 



21 

14 

313 

269 



48 
61 
337 
1,537 
103 
25,709 



497 

378 



1,874 
1,665 



See footnotes at end of table. 



FLAVOR A;1D PERFUIE '1ATER1ALS 
TABLE 1.— Flavor and perfume materials; U.S. production and sales. 



1972--CONTINUED 



Production 



Quantity 



Unit 
value' 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Terpenoid, Heteroayclia, and Alieyolio — Continued 

Terpineols 

a-Terpinyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic, and alicyclic materials- 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Total 

Allyl hexanoate 

Citronellyl acetate 

3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol) 

3,7-Dimethyl-trans-2,6-octadienal (Citral a; Geranial) 

3,7-Dimethyl-trans-2,6-octadien-l-oI (Geraniol) 

3,7-DimethyI-6-octen-l-ol (Citronellol) 

Ethyl butyrate 

Ethyl heptanoate 

Ethyl hexanoate (Ethyl caproate) 

Geranyl acetate 

Gerany 1 butyrate 

Geranyl formate 

Glutamic acid, monosodium salt (Monosodium glutamate) 

7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal) 

Isopentyl butyrate 

Isopentyl formate 

Isopentyl isovalerate 

Rhodinol 

All other acyclic materials 

ESSENTIAL OILS, CHEMICALLY MODIFIED 

Total 

Ethyl oxyhydrate 

Guaicwood acetate 

All other chemically modified essential oils 



1,000 
pounds 



3,017 
585 



18 
53 

1,196 

1,004 

532 



47,324 



1,000 
pounds 



!,778 
52-7 



876 
587 
468 



48,136 
442 



1,000 
dollars 



1,163 
403 
560 

6,485 



36 

119 

137 

1,473 

966 

302 

15 

10 

201 

11 

29 

21,646 

2,440 

70 



Per 

pound 



$0.42 

.77 

20.27 

2.70 



_.61_ 
2.46 

3.28 
4.67 
1.68 
1.65 

.65 
1.45 
1.98 
2.00 
2.98 
3.20 

.45 
5.52 

.78 
1.56 



.94 
2.72 
3.45 



'Calculated from the unrounded figures. 
^Includes some technical grade. 



SYNTHETIC ORGANIC CHEMICALS, 1972- 
TABLE 2. --Flavor and perfume materials for which U.S. production or sales were 

REPORTED, IDENTIFIED BY MANUFACTURER, 1972 



[Flavor and perfume materials for which separate statistics are given in table 1 are marked below with an asterisk 
(*); those not so marked do not appear in table 2 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes are taken from table 3. An x signifies that the manufac- 
turer did not consent to his identification with the designated product] 



Manufacturers' identification code 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 
Benzenoid and Naphthalenoid 



2' -Acetonaphthone 

Acet ophenone 

l-Acetoxy-2-sec-butyl-l-ethnylcyclohexane 

5-Acetyl-l,l,2,3,3,6-hexamethylindan 

p-Allylanisole 

Allyl cyclohexyl propionate 

4-Allyl-l,2-dimethoxybenzene (4-Allylveratrole) 

*4-Allyl-2-methoxyphenol (Eugenol) 

4-Allyl-2-methoxyphenoI acetate (Eugenol acetate) 

4- Allyl -1,2- (methylenedioxy) benzene (Safrole) 

Allyl phenoxyacetate 

p-tert-Amylcyclohexanone (Grivone) 

*p-Anis aldehyde 

Anisole (Methyl phenyl ether) 

Anisyl acetate 

*Benzophenone 

*Benzyl acetate 

'Benzyl alcohol 

*Benzyl benzoate 

*Benzyl butyrate 

*Benzyl cinnamate 

Benzyl ether 

Benzyl formate 

Benzyl glyceryl acetal 

Benzyl isobutyrate 

Benzyl isopentyl ether 

Benzyl isovalerate 

Benzyl laurate 

1- (Benzyloxy) -2-methoxy-4-propenylbenzene (Benzyl 
isoeugenyl ether). 

Benzyl phenylacetate 

*Benzyl propionate 

*Benzyl salicylate 

a-Bromostyrene 

2-5ec-Butylcyclohexanone 

p-tert-Butylcyclohexyl acetate 

4-tert-Butyl-2' ,6' -dimethyl- 3' ,5' -dinitroacetophenone 

(Musk ketone). 
6-tert-Butyl-3-methyl-2,4-dinitroanisole (Musk ambrette)- 

p-tert-Butyl-a-methylhydrocinnamaldehyde 

l-tert-Butyl-3,4,5-trimethyl-2,6-dinitrobenzene (Musk 
Tibetene) . 

5-tert-Butyl-2, 4, 6-trinitro-m- xylene (Musk .xylol) 

Carvacrol 

*Cinn amal dehy de 

Cinnami c acid 

*Cinnamyl acetate 

*Cinnamyl alcohol 

*Cinnamyl anthranilate 

Cinnamyl butyrate 

Cinnamyl cinnamate 

Cinnamyl propionate 

Cinnamyl tiglate 

Coumarin 



GIV. 




GIV. 




GIV. 




PFW. 




GIV, GLD. 




GIV. 




GIV, UOP. 




CI, FB, GIV, IFF, PEN, RT, UNG, UOP 


CI, GIV. 




FB, GIV. 




GIV. 




IFF. 




GIV, OPC, UOP. 




GIV. 




ELN, GIV, UOP. 




GAF, GIV, NEC, PD, UOP. 




GIV, MON, OPC, UOP. 




BPC, HN, MNR, UOP, VEL. 




MON, OPC, PFZ, UOP, VEL. 




ELN, FB, GIV. 




FB, GIV, UOP 




UOP, VEL. 




GIV, UOP. 




GIV. 




GIV. 




GIV. 




FB. 




GIV. 




GIV, UOP. 




ELN, GIV. 




ELN, FB, GIV, OPC. 




GIV, MON, UOP. 




UOP. 




GIV. 




CI, IFF. 




GIV. 




GIV. 




GIV, UOP. 




GIV, UOP. 




GIV. 




GIV. 




CI, FB, UOP. 




BPC. 




ELN, FB, GIV. 




FB, GIV, NEO, UOP. 




PEL, GIV, RT. 




FB. 





FLAVOR AND PERFUHE MATERIALS 



TABLE 2. --Flavor and perfume materials for which U.S. production or sales were 

REPORTED, IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Bemenoid and Naphthalenoid — Continued 



Cuminyl alcohol 

Cyclohexylcychohexanone 

trans- Decahydro-B-napht hoi 

2,4-Dibromo-6-nitro-meta-cresyl methyl ether 

1 ,2- Diiiiethoxy-4-propenylbenzene (4-Propenylveratrole) 

p-a-Dimethylbenzyl alcohol 

3,7-Dimethyl-l ,6-octadien-3-yl , anthranilate (Linalyl 

anthranilate) . 
3,7-Dimethyl-l,6-octadien-3-ol , benzoate (Linalyl 

benzoate) . 
3,7-Dimethyl-l ,6-octadien-3-ol , cinnamate (Linalyl 

cinnamate 
3, 7-Dimethyl-2 ,6-octadienylphenylacetate (Geranyl 

phenylacetate) . 
trans-3 ,7-Dimethyl-2 ,6-octadien-l-ol , benzoate (Geranyl 

benzoate) . 

a,a-Dimethylphenethyl acetate 

a,a-Dimethylphenethyl alcohol 

a,a-Dimethylphenethyl alcohol, butyrate 

a,a-Dimethylphenethyl alcohol, tech 

Diphenylme thane f Benzylbenzene) 

1 ,3-Diphenyl-2-propanone (Dibenzyl ketone) 

p-Ethoxy benzaldehyde 

2-Ethoxynaphthalene 

Ethyl anthranilate 

Ethyl benzoate 

Ethyl cinnamate 

Ethyl a,B-epoxy-B-methylhydrocinnamate 

2-Ethylhexyl salicylate 

Ethyl phenylacetate 

*Ethyl phenylg lye i date 

Ethyl salicylate 

3'-Ethyl-5' ,6' ,7' ,8' -tetrahydro-5' ,5' ,8' ,8' - 

tetramethyl-2'-acetonaphthone. 

Ethylvanillin (4-Hydroxy-3-ethoxybenzaldehyde) 

1 ,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethyl cyclopenta- 

gamma-2-henzopyran (Galaxolide 50). 

Hexyl benzoate 

a-Hexylcinnajnaldehyde 

Hydra tropaldehyde 

Hydratropaldehyde, dimethyl acetal 

Hydrocinnamic acid 

*Hydrocoumarin 

Hydroxycitronellalmethyl anthranilate 

4- (4-Hydroxy-3-methoxyphenyl)-2-butanone 

Indole 

Isoamyl phenylacetate 

Isobutyl benzoate 

p-Isobutyl-a-mathylhydrecinnamaldehyde (Rhodial) 

*Isobutyl phenylacetate 

Isobutylquinoline 

*lsobutyl salicylate 

Isohexenyl tetrahydrobenzaldehyde (Myrac aldehyde) 

Isopentyl benzoate 

'Isopentyl salicylate 



GIV. 

GIV. 

IFF. 

GIV. 

GIV, UOP. 

GIV. 

FMT. 

HOF. 

HOF. 

GIV. 

GIV. 

IFF. 

IFF. 

IFF. 

IFF. 

ARA, UOP. 

GIV. 

GIV. 

GIV. 

FB. 

ELN. 

ELN, GIV. 

ELN, GIV. 

FEL. 

GIV. 

GIV, PFW, UOP. 

FB. 

GIV, MOP. 

GIV, UOP. 

MON, SLV. 

IFF. 



IFF 
IFF. 
IFF. 



GIV. 

CI, 

GIV, 

GIV, 

ARS. 

ARS, 

GIV. 

GIV. 

GIV. 

GIV. 

ELN. 

RDA. 

ELN, 

IFF. 

FB, 

IFF. 

GIV. 

FB, GIV, MON, OPC, UOP. 



FB, GIV. 
GIV, UOP. 



552-743 0-74-9 



SYNTHETIC ORGANIC CliE"ICALS. 197'' 



TABLE 2,— Flavor and perfume materials for which U.S. production or sales were 

REPORTED. IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued 
Bemenoid and Naphthalenoid — Continued' 

p-Isopropyl benzaldehyde (Cumaldehyde) 

p-Isopropylcyclohexanol 

p-Isopropyl-a-methylhydrocinnamaldehyde 
(Cyc lamena Idehyde ) 

Isovanillin (3-Hydroxy-4-iiiethoxybenzaIdehyde) 

p-Mentha-l,8-diene (Limonene] 

Men thy 1 anthranilate 

4 ' -Methoxyacetophenone (Acetanisole) 

p-Methoxybenzyl alcohol [Anisyl alcohol) 

o-Methoxycinnamaldehyde 

2-Methoxynaphthalene 

l-(p-Methoxyphenyl)-l-penten-3-one 

2-Methoxy-4-propenylphenol (Isoeugenol) 

2-Methoxy-4-propenylphenol , acetate 

4 '-Methyl ace tophenone 

p-Methylanisole 

*Methyl anthranilate 

Methyl anthranilidene-p-isopropyl methylhydro- 
cinnamaldehyde (Orangeol N) . 

Methyl benzoate 

*a-Methylbenzyl acetate (Styralyl acetate) 

a-Methylcinnamaldehyde 

Methyl cinnamate 

6-Methylcoumarin 

Methylcyclohexyl propionate 

1 ,2- CMethylenedioxy)-4-propenylbenzene (Isosafrole) 

p-Methylhydratropaldehyde 

l-Methyl-4-isohexyl-hexahydrobenzaldehyde 
CVemaldehyde) . 

Methyl N-methy Ian thrani late 

*Methyl phenyl acetate 

*Methyl salicylate 

IH-Naphtho- [2 , 3-c] pyTan-3 , 4,6,7,8, 9-hexahydro-4 ,6,6,9,9- 
pentaraethyl (Musk 89) . 

1,1 ,3,3,5-Pentamethyl-4,6-dinitroindan 

a-Pentylcinnaraa Idehyde 

*Phenethyl acetate ^ 

Phenethyl alcohol 

Phenethyl formate 

Phenethyl Isobutyrate 

Phenethyl isovalerate 

*2-Phenethyl phenylacetate 

Phenethyl propionate 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate 

Phenylacet a Idehyde 

Phenylacetaldehyde, dimethyl acetal 

o-Phenylanisole (2 -Methoxybi phenyl) 

4-Phenyl-3-buten-2-one (Benzyl ideneacetone) 

Phenylethyl acetal 

Phenyl ethyl tig late 

*3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

3-Phenylpropyl acetate 

3-Phenylpropyl cinnamate 

*Piperonal (Heliotropin) 



Manufacturers' identification codes 
(according to list in table 3) 



GIV. 




GIV. 




GIV, RDA. 




SLV. 




SKG. 




PFW. 




GIV, UOP. 




GIV, UOP. 




CI. 




GIV. 




GIV. 




CI, GIV. 




UOP. 




GIV, UOP. 




GIV, UOP. 




FB, OPC, PFW, 


SW, UNG 


RDA. 




HN. 




CI, ELN, GIV, 


UNG. 


FB, GIV. 




CI, FB, UOP. 




GIV. 




GIV. 




GIV. 




GIV. 




GIV. 




GIV, OPC. 




ELN, GIV, OPC 




DOW, HN, MON. 




IFF, 




GIV. 




CI, FB, GIV, 


HOP. 


GIV, IFF, NEO 




IFF, NEO. 




ELN, IFF. 




ELN, GIV, IFF 




GIV, OPC. 




CI, ELN, GIV, 


IFF. 


GIV. 




GIV. 




GIV. 




GIV. 




GIV, UOP. 




GIV. 




FB, UOP. 




GIV. 




FB. 




ELN, FB, GIV. 


UOP. 


GIV. 





AMB, GIV, UOP. 



FLAVOR AND PERFUME MATERIALS 



TABLE 2. --Flavor and perfume materials for which U.S. production or sales were 

REPORTED, IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC — Continued 
Benzenoid and Naphthalenoid — Continued 



Piperonal bisulfite (Heliotropin bisulfite) 

*p-PropenyIanisole (Anethole) 

p-PropylanisoIe (Dihydroanethole) 

N-Propylphenylethyl alcohol 

Sweeteners, synthetic; 

Cyclohexanesulfamic acid 

Cyclohexanesulfamic acid, calcium salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin (1 ,2-Benzisothia2olin-3-one , 1 , 1-dioxide)- 

Saccharin, ammonium salt 

Saccharin, calcium salt 

Saccharin, sodium salt 

*p-Tolualdehyde 

p-Tolylacet aldehyde 

p-Tolyl acetate 

p-Tolyl phenylacetate 

a-CTrichloromethyl) benzyl acetate (Rosetone) 

Vanillin (4-Hydroxy-3-methoxybenzaldehyde) 

Terpenoid, Heteroayolia , and Alicyclic 

Acetyl cedrone fVertofix) 

Cadinene 

6-Caryophyllene 

Caryophyllene oxide 

a-Cedrene epoxide (Andrane) 

Cedrenol 

Cedrol 

*Cedryl acetate 

Cedryl formate 

Cycl open tan one 

Dihydronordicyclopentadienyl acetate 

D ih ydronordi cycl open t ad ienyl propionate 

Dihydroterpinyl acetate 

3-Hydroxy-2-ethyl-4-pyrone (Ethyl maltol) 

16-Hydroxyhexadecanoic acid, o-lactone 

(Hexadecanolide) . 
4- (4-Hydroxy-4-methylpentyl)-3-cyclohexene-10- 

carboxaldehyde (Lyral). 

3-Hydroxy-2-methyl-4-pyrone (Maltol) 

4-Hydrox)Tionanoic acid, Y-l3<^tone (y-Nonalactone) 

4-Hydroxyoctanoic acid, y-lactone (y-Octalactone) 

4-Hydroxyundecanoic acid, y-lactone (y-Undecalactone)- 
lonones : 
*ot-Ionone 

S-Ionone 

lonone (a-and 6-)' 

Isoborneol 

Isobomyl Acetate 

Isobomyl propionate 

Isojasmone 

Isomenthone 

4-Isopropylcyclohexanol 

Jasmal 

p-Mentha-6,8-dien-2-ol (£-Carveol) 

p-Mentha-6 ,8-dien-2-one (Carvone; CarVol) 



AMB. 

ARZ, GLD, 
FB, GIV. 
GIV. 

ABB. 



HON, SW. 
SW. 

MON, SW. 
HON, SW. 
GIV, HN, 
GIV. 

FB, GIV. 
GIV. 
NEO. 
MON, SLV. 



FB. 

CI, ( 

GIV. 

IFF. 

GIV. 

ELN, 

ELN, 

IFF. 

ARA. 

GIV, 

i;iv, 

GIV. 
PFZ. 
IFF. 



HN, HPC, NCI, UOP. 



GIV, IFF, NEO. 

GIV, IFF, NEO, UNG, UOP. 



IFF 
IFF 



IFF. 



PFZ- 








GIV, 


UOP 






GIV, 


RT, 


UOP. 




ELN, 


FB. 






GIV 


HOF 


IFF, 


MYW 


HOF 


MYW 






GIV 


MYW 


NEO, 


UNG 


RDA 








FB, 


OPC, 


RDA. 




GIV 


OPC 






FB. 








GIV 








UOP. 








IFF 









SYNTHETIC ORGAMIC CHEMICALS. 1972 



TABLE 2, --Flavor and perfume materials for which U.S. production or sales were 

REPORTED, identified BY MANUFACTURER. 1972--CONTI NUED 



Manufacturers' identification codes 
(according to list in table 5) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Terpenoid, Heteroayalic, and Aliayalio — Continued 

p-Mentha-6,8-dien-2-ol , acetate (K-carvyl acetate) 

p-Mentha-l,3-diene (oi-Terpinene) 

p-Mentha-l,4-diene [y-Terpinene) 

*p-Menthan-3-one (Menthone) 

p-Menth-l-en-3-one 

p-Menth-4C8)-en-5-one (d-Pulegone) 

p-Menth-8-en-3-ol (Isopulegol) 

1 , l-p-Menthen-6-yl-l-propanone 

Menthol, synthetic: 

Tech 

•U.S.P 

Menthyl acetate 

*Methylibnones: 

b-Methyl-ot-ionone 

Methylionone (a- and B-) 

Y-Me thy lion one 

Nopyl acetate 

3-Pentyl-tetrahydro-4-pyranol CJessemal) 

Santalol 

Santalyl acetate 

*Terpineols : 

a-Terpineol 

Terpineol (a- and B-) 

Terpinol hydrate (Terpin hydrate) , tech 

*a-Terpinyl acetate 

Terpinyl acetate Cmixed a- and B-) 

a-Terpinyl propionate 

Tetrahy drops eudo ion one 

l-(2 ,6,6-Trimethyl-2-cyclohexen-l -yl)-l ,6-heptadien- 
3-one (Allyl-a-ionone) . 

3,3,5-Triniethyl cyclohexanol (Horaomenthol) 

Vetivenol 

*Vetivenyl acetate 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Acetylbutyryl C2 ,3-Hexanedione) 

Acetylpropionyl 

Acetylvaleryl (2,3-Heptanedione) 

Allyl disulfide- 

Allyl hep tan oat e 

*Allyl hexanoate 

Allyl isothiocyanate (Synthetic mustard oil) 

Allyl octanoate (Allyl caprylate) 

Allyl sulfide 

Amyl propionate 

Butyl butyryl lactate 

l-Chloro-2-iiiethyl-butene-2 

Citral dimethyl acetal 

*Citronellyl acetate 

Citronellyl butyrate 

Citronellyl formate 

Citronellyl isobutyrate 

Citronellyl methyl acetal 

Citronellyl oxyacet aldehyde 

Citronellyl propionate 



GLD. 








GLD. 








CIV 


HN, 


NEO. 




GIV 








GIV 








GIV 








GIV. 








GIV, 


HN. 






GIV, 


GLD 


HN, 


NEO. 


GIV. 








GIV, 


MYW 






GIV, 


IFF 


MYW 


NEO, UNG 


GIV. 








CI, 


FEL, 


NEO, 


RDA. 


IFF. 








GIV. 








GIV. 








GLD, 


HPC 


NCI 




GIV. 


NEO 






HPC. 








GIV, 


NEC 


PFW 


UNG. 


RDA. 








ELN, 


GIV 







ARS. 

GIV, UOP. 

ELN, FB, GIV, IFF, NEO, UOP. 



ELN, 


FB, 


RT. 




RT. 




GIV. 




ARS. 




RDA. 




GIV, 


IFF 


ELN, 


GIV 


GIV. 




ELN, 


GIV 


ELN, 


GIV 


IFF. 




IFF. 




IFF. 





FLAVOR AND PERFUME NATERIALS 



TABLE 2. --Flavor and perfume materials for which U.S. production or sales were 

REPORTED^ identified BY MANUFACTURER, 1972— CONTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued 

Decanal (Capr aldehyde) 

Decen-9-ol-l (Rosalva) 

Decyl acetate- 

Diethyl acetal 

Diethyl sebacate 

Diethyl succinate 

Dihydromyrcenol 

Dihydromyrcenyl formate (Dimyrcetol) 

Dihydro safrol 

2,6-Dimethyl-5-hepten-l-al 

3,6-Dimethyl-5-hepten-2-ol and 7-Methyl-6-octen-3-ol 
(Brazinol) . 

3,7-Diinethyl-l ,6-nonadien-3-ol (Ethyl linalool) 

3,7-Dimethyl-l,6-nonadien-3-ol, acetate 

3,7-Dimethyl-2,6-nonadienenitrile 

3,7-Diniethyl-2,6-octadienal (Citral) 

*3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol) 

*3,7-Diraethyl-trans-2,6-octadienal (Citral a; Geranial)- 
3,7-Dimethyl-trans-2,6-octadienal dimethyl acetal 

*3,7-Dimethyl-trans-2, 6-octadien-l-ol (Geraniol) 

3,7-Diraethyl-trans-2,6-octadien-l-ol HP 

(Geraniol HP). 
3, 7-Dimethyl-l ,6-octadien-3-ol (Linalool; Linalyl 

alcohol) . 
3,7-Diiiiethyl-l ,6-octadien-3-ol acetate (Linalyl 

acetate) . 
3, 7-Dimethyl-l, 6-octadien-3-yl isobutyrate (Linalyl 

isobutyrate) . 
3, 7-Dimethyl-l ,6-octadien-3-yl propionate (Linalyl 
propionate) . 

3,7-Dimethyloctan-l-al 

3,7-Dimethyloctan-3-ol 

3,7-Dimethyl-l,7-octanediol 

3,7-Dimethyl-l-octanol (Dihydrocitronellol) 

3,7-Dimethyl-6-octen-l-al (Citronellal) 

*3,7-Dimethyl-6-octen-l-ol (Citronellol) 

3,7-Diraethyl-6-octen-l-ol, cis, trans mixture 

2,6-Dimethyl-2-octene-7-yne-6-ol 

3,7-Dimethyl-7-octenol and 6-octenol isomer 

*Ethyl Butyrate 

Ethyl cap rate 

Ethyl formate 

*Ethyl heptanoate 

*Ethyl hexanoate (Ethyl caproate) 

2-Ethyl-l-hexanol 

Ethyl isohexanoate 

Ethyl isovalerate 

Ethyl laurate 

Ethyl myristate 

Ethyl nonanoate 

Ethyl octanoate 

Ethyl propionate 

Ethyl valerate 

Geranic acid 

Geranonitrile 

*Geranyl acetate 

*Geranyl butyrate 

Geranyl dimethyl aery late 

*Geran;^l "formate 

Geranyl isobutyrate 



CI, GIV. IFF. 

IFF. 

GIV. 



ELN, 

UCC. 

IFF. 

IFF. 

CI. 

GIV. 

RDA. 

HOF. 
HOF. 
GIV. 
HOF. 
ELN, 



FB, GIV, GLD, IFF. 
FEL, GIV, UOP. 



CI, 
GIV, 



ELN, FB, FEL, GIV, GLD, IFF, NCI, NED, UOP. 



ELN, 
ELN, 



HOF. 

HOF. 

GIV. 

GIV. 

FB, 

CI, 

CI. 

RDA. 

GIV. 



FB, FEL, GIV, GLD, HOF, UNG. 
FB, GIV, GLD, HOF, NEO, UNG. 



GIV, IFF, NEO, UOP. 

ELN, FB, GIV, IFF, NEO, SCM. 



ELN 


FEL 


RT 


UOP 


ELN 


FB, 


NW, 


PFW, 


GIV 








PFW 








FB, 


PFW. 






ELN 








RT. 








FEL 


GIV 






FB, 


RT. 







CI, 


ELN, 


FEL, 


GIV 


CI, 


ELN, 


GIV. 




FMT. 








CI, 


ELN, 


GIV. 




IFF 









SYNTHETIC ORGANIC CHEMICALS, 1972 



TABLE 2.— Flavor and perfume materials for which U.S. production or sales were 

REPORTED, identified BY MANUFACTURER, 1972--CONTINUED 



FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued 

Geranyl isovalerate 

Geranyl neryl formate 

Geranyl propionate 

Geranyl tig late 

♦Glutamic acid, monosodium salt (Monosodium glutamate)- 

Y-Heptalactone 

Heptanal (Enanthaldehyde) ' 

Heptyl alcohol (1-Heptanol) 

Hexanoic acid (Caproic acid) 

2-Hexanol 

2-Hexenal 

cis-3-Hexen-l-ol 

cis-3-Hexen-l-yl acetate 

cis-3-Hexen-l-ol lactate 

3-Hydroxy-2-butanone (Acetoin) 

*7-Hydroxy-3,7-dimethyl-l-octanal (Hydroxycitronellal) • 
7-Hydroxy-3,7-diiiiethyl octanal, dimethyl acetal 
(Hydroxycitronellal, dimethyl acetal). 

Isoamyl propionate 

Isoamyl undecylenate 

Isobutyl acetate 

Isodihydro lavandulol 

Isodihydro lavandulylaldehyde 

Isodihydro lavandulyl acetate 

*Isopentyl butyrate 

*Isopentyl formate 

*lsopentyl isovalerate 

Lauraldehyde 

3-Methyl-5-heptanone oxime 

2-Methyl-2-hepten-6-one methyl hexenyl ketone and 
6-methyl-5-hepten-2-one. 

Methyl isobutyrate 

3-Methyl-2-(and 3) nonenitrile 

Methyl-2-nonenoate 

Methylol methyl hexyl ketone 

2-Methylundecanal 

Mugual and tetrahydro rauguol 

Myrcenyl acetate 

Myrist aldehyde 

Neryl acetate 

Nan anal 

Nonane diacetate 

Nonane-1 ,3-diol monoacetate 

Nonanol 

Nonyl acetate 

Ocimenol 

Ocimenyl acetate 

Octanal 

Octanal, tech 

3-Octanone (Ethyl amyl ketone) 

Octyl acetate 

n-Octyl acetate 

n-Octyl alcohol 

Pentyl acetate 

Propionic acid ethyl ester 

Pseudo linalyl acetate 

Pyrolysate ester 

*Rhodinol 



Manufacturers' identification codes 
(according to list in table 3) 



FB, 


IFF. 




FB. 






COM 


GRW, 


UDW 


FB. 






ntl. 






ntl 


UCC. 





GIV, 

GIV. 

RT. 

FMT. 

GIV, 

GIV, 



gld, iff, NEO, UOP. 
UOP. 



GIV, NW, PFW, UOP. 
, GIV, RT. 
, FB, PFW. 

GIV. 



GIV. 
RDA. 

PFW. 

GIV. 

GIV. 

GIV. 

GIV. 

IFF. 

IFF. 

GIV. 

GIV. 

GIV. 

CI. 

GIV. 

GIV. 

GIV. 

IFF. 

IFF. 

GIV, IFF. 

IFF. 

GIV. 

FB. 

GIV. 

GIV. 

UOP. 

UOP. 

IFF. 

GIV. 

FB, FEL, GIV, IFF, NEO. 



FLAVOR AND PERFUME MATERIALS 



TABLE 2, --Flavor and perfume materials for which U.S. production or sales were 

REPORTED, identified BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued 

Rhodinyl acetate 

Sodi'um allyl sulfonate 

Tepyl acetate 

3,7,8,8-Tetrainethyl-l ,6-nonadiene-3-ol (Isobutyl 
linalool) . 

3,7,ll-Trimethyl-l,6,10-dodecatriene-3-ol 

2,6, lO-Trimethyl-9-undecen-l-al 

3,6,10-Triraethyl-9-undecen-2-one and isomers 

Un decanal 

9-Undecenal 

Y-VaJerolactone 

ESSENTIAL OILS, CHEMICALLY MODIFIED 

.^jnyris acetate 

Clove leaf oil terpenes 

* Ethyl oxyhydrate 

*Guaiacwood acetate 

Guaiene 

Lavandin, acetylated 

Rose oxide 

Sassafrass oil, hydrogenated 



GIV. 
UOP. 
UOP. 
HOF. 

HOF. 
GIV. 
GIV. 
GIV, 
GIV. 
GIV. 



GIV. 

CI, UOP. 

FEL, FLO, PFW, RT, VND. 

ELN, FB, GIV, NEO. 

FB. 

FEL, UNG. 



SYNTHETIC ORGANIC CHEMICALS, 1972 



TABLE 3. --Flavor and perfume materials: Directory of manufacturers. 1972 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of flavor and perfume materials to the U.S. Tariff 
Commission for 1972 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of Company 


Code 


Name of Company 


ABB 


Abbott Laboratories 


MRT 


Morton Chemical Co., Div of 




AMB 


American Bio-Synthetics Corp. 




Morton-Norwich Products, Inc. 




ARA 


Arapahoe Chemicals Div. of Synte.x Corp. 


MYW 


Stepan Chemical Co. 




ARS 


Arsynco, Inc. 








ARZ 


Arizona Chemical Co. 


NCI 


Union Camp Corp. , Chemical Division 








NEC 


Norda Essential Oil 6 Chemical Co. , 


Inc. 


BPC 


Stauffer Chemical Co., Specialty Chemical 


NIL 


NL Industries, Inc. 






Division, Benzol Products 


NK 


Northwestern Chemical Co. 




CI 


Chem-Fleur, Inc. 


OPC 


Orbis Products Corp. 




COM 


Commercial Solvents Corp. 


PD 


Parke, Davis £ Co. 




DOW 


Dow Chemical Co. 


PEN 


CPC International, Inc., Penick Division 






PFW 


Polak's Frutal Works, Inc. 




ELN 


Elan Cheracial Co. 


PFZ 


Pfizer, Inc. 




FB 


Fritzsche, Dodge 6 Olcott, Inc. 


RDA 


Rhodia, Inc. 




FEL 


Felton International, Inc. 


RT 


F. Ritter 5 Co. 




FLO 


Florasynth, Inc. 








FMT 


Fairmount Chemical Co. , Inc. 


SKG 
SLV 


Sunkist Growers, Inc. 
Sterwin Chemicals, Inc. 




GAF 


GAF Corp., Chemical Division 


SW 


Sherwin-Williams Co. 




GIV 


Givaudan Corp. 








GLD 


SCM Corp., Glidden-Durkee Division 


TCC 


Tanatex Chemical Corp. 




GRW 


Great Western Sugar Co. 


UCC 


Union Carbide Corp. 




HN 


Tenneco Chemicals, Inc. 


now 


William Underwood Co. 




HOF 


Hoffman- LaRoche, Inc. 


UNG 


Ungerer 5 Co. 




HPC 


Hercules, Inc. 


■JOP 


Universal Oil Products Co., UOP 
Chemical Division 




IFF 


International Flavor & Fragrances, Inc. 








MNR 


Monroe Chemical Co. 


VEL 


Velsicol Chemical Corp. 




MON 


Monsanto Co. 


VNP 


Van Dyk 6 Co. , Inc. 





-Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix. 



133 



PLASTICS AND RESIN MATERIALS 



Plastics and resin materials are high molecular weight polymers 
which, at some stage in their manufacture, exist in such physical con- 
dition that they can be shaped or otherwise processed by the application 
of heat and pressure. Depending on the chemical composition, manufacturing 
process or intended use, the commercial products may contain plasticizers, 
fillers, extenders, stabilizers, coloring agents or other additives. 
Plastics materials may be molded, cast or extruded into semifinished or 
finished solid forms. Resin materials may be in the form of solutions, 
pastes or emulsions for applications such as protective coatings, adhesives, 
or paper and textile treatment. 

Statistics on U.S. production and sales of synthetic plastics and 
resin materials for 1972 are given in table 1.^ U.S. production of plastics 
and resin materials in 1972 totaled 25,921 million pounds, or 23.0 percent 
more than the 21,070 million pounds produced in 1971. Sales in 1972 totaled 
22,946 million pounds, valued at $4,258 million compared with 18,473 million 
pounds, valued at $3,507. 

Thermosetting materials are those which harden with a change in 
composition in the final treatment so that they cannot again be softened 
by heat or solvents. U.S. production of thermosetting materials totaled 
4,484 million pounds in 1972 compared with 3,615 million pounds in 1971. 
Production of the most important products in 1972 included phenolic resins 
(1,441 million pounds), amino (or urea and melamine) resins (929 million 
pounds), polyester resins (930 million pounds), and alkyd resins (636 
million pounds) . 

Thermoplastic materials are those which can be repeatedly softened by 
heat and shaped. U.S. production of thermoplastic materials totaled 21,437 
million pounds in 1972 compared with 17,455 million pounds in 1971. Produc- 
tion of the most important products in 1972 included polyethylene (7,656 
million pounds), vinyl resins (5,122 million pounds), and styrene type 
materials (4,890 million pounds). 



^ See also table 2 which lists these products and identifies the manu- 
facturers of each by codes. These codes are given in table 3. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 1, --Plastics and resin materials; U.S. production and sales, 1972 



[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials for which any reported data on production or sales may be published. (Leaders (.. .) are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 2 lists all plastics and resin materials for which data on production or sales were reported and identifies 
the manufacturers of each] 



Production 



Grand total 

Plastics and resin materials, benzenoid 

Plastics and resin materials, nonbenzenoid 

THERMOSETTING RESINS 
Total 

Alkyd resins, total 

Phthalic anhydride type 

Polybasic acid type 

Polyester resins, unsaturated 

Styrene alkyd polyesters 

Amino resins, total 

Mel amine- formaldehyde resins 

Urea- formaldehyde res ins 

Dicyandiamide resins 

Epoxy resins:^ 

Unmodified 

Modified and "advanced" 

Furfuryl type resins 

Phenolic and other tar acid resins 

^Polyurethane and diisocyanate resins (excluding foam and 

elastomers) 

Polyether and polyester polyols for urethanes 

Silicone resins 

Other thermosetting resins' 

thermoplastic resins 

Total 

Acrylic resins' 

Cellulosic plastics and resins'" 

Coumarone-indene resins 

Petroleum hydrocarbon resins 

Polyamide resins, nylon type'" 

Polyamide resins, non-nylon type 

Polyester resins, saturated 

Polyethylene and copolymers, total 

Density 0.940 and below" 

Density over 0.940 

Polypropylene resins 

Polytetrafluoroethylene (PTFE) 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums) 

Other " 



1,000 

pounds 

diry basis ^ 

25,920,662 



8,946,997 
16,973,665 



4,483,501 



597,181 
38,735 



930,384 
12,493 



199,473 
729,294 



179,000 
' (43,159) 

4,449 
1,440,513 

99,427 

149,191 

13,424 

87,835 



21,437,161 



758,589 
256,811 

49,024 
245,359 
122,987 

27,328 
114,969 



5,360,310 
2,295,939 



,730,857 
13,248 



35,981 
92,363 



1,000 

pounds 

dry basis^ 

22,946,075 



1,000 
dollars 



7,807,933 
15,138,142 



300,281 
22,969 



45,767 
5,109 



759,934 



152,831 
607,103 



' 179,000 
9 (26,554) 

2,683 
1,226,665 

48,546 
107,773 
10,856 
79,946 



19.354.466 



626,856 
251,538 

233,241 
119,009 
25,716 
43,496 

6,932,020 



,877,879 
,054,141 



1,684,507 
9,635 



121,399 



29,170 
92,229 



1,715,579 
2,542,861 



83,685 
6,154 



158,962 
1,786 



51,924 
101,627 



' 81,000 
'(21,466) 

719 
260,024 

22,331 
23,647 
20,314 
19,599 



3.425.327 



283,377 
132,071 

29,342 
97,043 
15,353 
26,373 

834,641 



594,050 
240,591 



265,539 
31,804 



7,684 
19,902 



See footnotes at end of table. 



PLASTICS AND RESIN MATERIALS 
TABLE 1. —Plastics and resin materials; U.S. production and sales^ 1972~Continued 



Production 



Quantity 



Unit 
value^ 



1,000 

pounds 

dry hasis^ 



THERMOPLASTIC RESINS--Continued 



Styrene plastics materials, total 

Acrylonitrile-butadiene-styrene (ABS) 

Styrene-acrylonitrile resins CSAN) 

Styrene and styrene copolymer resins-- 



Vinyl resins, total'^ 

Polyvinyl chloride and copolymers- 
Polyvinyl acetate ' ^ 

Polyvinyl alcohol 

Lther vinyl and vinylidene resins' 



),161 



863,725 
' 106,000 
3,920,436 



1,000 

pounds 

dry basis^ 



4,557,156 



1,000 
dollcws 



809,934 

100,838 

3,646,384 

4,434,989 



Per 

pound 



$0.18 



235,195 
22,888 
575,245 

657,610 



.29 
.23 
.16 



All other thermoplastic resins 



,322,000 

527,839 

78,564 

193,835 

320,997 



3,865,000 

404,481 

64,918 

100,590 

314,904 



503,048 
94,331 
20,407 
39,824 

191,260 



.31 
.40 



Starting with 1972, data is reported only by type of resin and is no longer broken down by end use. 
^ Calculated from rounded figures. 
' Dry weight basis unless otherwise specified. Dry weight basis is the total weight of the materials including resin 
and coloring agents, extenders, fillers, plasticizers , and other additives, but excluding water and other liquids di- 
luents unless they are an integral part of the materials. 

'' Includes benzenoid plastics and resin materials as defined in part I of schedule 4 of the Tariff Schedules of the 
United States. 

^ Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (such as styrene or methyl 
methacrylate) ; and polyallyl resins (such as diallyl phthalate and diglycol carbonate). Data are on an "as sold" basis, 
including monomer if part of the resin system. 

^ Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold in 
association with the resin as part of a two-component system. 
' Partially estimated. 

° Data shown for modified and "advanced" epoxy resins are that part of the unmodified epoxy resins which is further 
processed; therefore, the totals in parentheses are not included in the grand total. 

' Includes polycarbamate resins, toluenesulfonamide resins, acetone- formaldehyde resins, and other thermosetting resins 
and their precursors. 
'° Does not include production or sales for fiber use. 

" Includes data for ethylene copolymers. Sales do not include sales by primary producers to other primary producers; 
sales do include resales of purchased material by primary producers. 

'^ Data are on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers, coloring agents, 
stabilizers or impact modifiers, unless otherwise noted. 

" Data for polyvinyl acetate produced and sold in latex form include the weight of any protective colloids which are 
used as emulsion stabilizers and form an integral part of the resin system. Production does not include polyvinyl acetate 
used as a reactive intermediate for polyvinyl alcohol or other vinyl resins. 
'*■ Includes polyvinylidene chloride, polyvinyl butyral , polyvinyl formal, and other vinyl resins. 

'^ Includes acetal resins, fluorocarbon resins except PTFE, a-methylstyrene resins, polybutylene type resins, poly- 
carbonate resins, polyimide-type resins, polyphenylene oxide type resins, polyterpene resins, other thermoplastics, 
and sales of coumarone-indene resins. 

Note. --Data reported to the Tariff Commission does not necessarily coincide with that reported to the Society of the 
Plastics Industry due to differences in both the reporting instructions (e.g., polyvinyl alcohol) and in the coverage 
(e.g. phenolic resins). 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2,— Plastics and resin materials for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 

[Plastics and resin materials for which separate statistics are given in table 1 are marked below with an 
asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in con- 
fidence and may not be published. Manufacturers' identification codes shown below are taken from table 3. A 
X signifies that the manufacturer did not consent to his identification with the designated product] 



THERMOSETTING RESINS 

Acetone-formaldehyde resins 

*Alkyd resins, domestic: 

*Phthalic anhydride type 

*Polybasic acid type 

•Polyester resins, unsaturated 

*Styrene-alkyd polyesters 

*Amino resins: 
*Melamine- formaldehyde resins 

*U re a- formaldehyde resins 

*Dicyandi amide resins 

Epoxy resins: 
'Unmodified 

•Modified and "advanced" 

* Fur fury 1- type resins 

•Phenolic and other tar acid resins 



Po ly carb amate resins 

•Polyurethane and diisocyanate resins 

•Polyether and polyester polyols for urethi 

*Si 1 i cone resins 

All other thermosetting resins 



Manufacturers' identification codes 
(according to list in table 3) 



ACY, AMR. 

.\CY, APT, ASH, AZS. BAL, BEN, BRU, GEL, CGL, CM, COM, DAV, 
DEG, DSO, DUP, EW, FAR, FCD, FLW, FOC, FSH, GIL, GLD, 
GRV, HAN, IGF, IPC, JOB, JSC, JWL, KHC, KMP, KPT, MCC, 
MID, MNP, NCI, NPV, OBC, PER, PPG, PRT, PRX, RCI, RED, 
REL, RH, SCN, SED, SIP, SKT, SM, SW, x. 

ACY, ASH, BEN, COM, DEG, EW, FCD, FOC, GRV, HAN, ICF, 
IPC, KMC, KMP, MCC, MID, MOB, NPV, PFP, PPG, RCI, 
RED, REL, RH, SCN, SKT, SM, SW, WIG. 

ACP, ACR, ACY, APT, ASH, AZS, CGL, CPV, DA, DEG, DSO, 
ENJ, EPC, EW, FLW, FMP, FOM, FRE, GEI, GLD, GNT, 
GRG, HAN, HKD, ICF, ICI , IPC, KMC, KPT, MFC, MID, 
MMM, MRB, MRO, OCF, ORO, PFP, POL, PPG, PPL, RCI, 
REL, RH, SCN, SHA, SHC, SIC, SM, SW, TXT, WLN. 

APT, ASH, CGL, DSO, EW, FLW, GLD, GRV, HAN, MID, PPG, 
REL, SM. 

ACP, ACY, AMR, BOR, CBD, GEL, CGL, DAN, DSO, DUP, ENJ, 
FOM, GLD, GRV, HAN, JSC, KPT, MON, MRA, PMC, PPG, 
PPL, QCP, RCI, REL, RH, SBC, SED, SNW, STC, SW, VAL, 
WRD. 

ACP, ACY, AMR, APX, ASH, BOR, CBD, CEL, CGL, CMP, CPV, 
DAN, DUP, EFH, GAF, GLD, GP, GRV, HAN, HNC, HPC, 
HRT, IRI, JSC, KPT, MMM, MON, MRA, NTC, PC, PGU, 
PPG, PPL, RCI, REL, RH, RPC, SAC, SED, SM, SNW, SOR, 
SW, TXT, UNO, UPL, USO, VAL, WCL. 

CGY, ECC, JSC, MID, MRA, RPC, S, SBC, VAL, WIC. 

CEL, CGY, DOW, RCI, RSY, SHC, UCC. 

ACP, ASH, BEN, DSO, EW, FAR, GLD, GRV, HAN, HYC, ICF, 
JOB, MCC, MID, MMM, MRB, MRT, NPV, OCF, POL, PPG, 
PRX, RCI, REL, REZ, RSY, SCN, SED, SKT, SM. 

ACR, HVG, SM, TXT, UNO, WRD. 

ABS, ACP, ACR, AMR, ASH, BME, BOR, CBD, CBM, CD, CGL, 
CLK, DSO, ENJ, EW, FOM, GE, GEI, GLD, GP, GRG, HER, 
HKD, HVG, ICF, INL,-IRI, KPT, KYN. MCA, MID, MMM, MON, 
MRB, NCI, NTC, OCF, PAI , PGU, PLS, PPL, PRX, PYZ, 
RAB, RCD, RCI, REL, RGC , RH, RPC, SCN, SHA, SIM, 
SKT, SM, SPL, SW, UCC, UNO, UPL, USR, VSV, WCA, WRD. 

ASH, DAN, PPG. 

APT, ARK, ASH, BAL, CEL, CGL, DSO, DUP, EW, FAR, FRE, 
GLD, GPM, HAP, ICI, JOB, JWL, KMC, MCC, MID, MOB, 
mi, NPV, PEL, PPG, PVI, QUN, RCI, REZ, RUB, SCN, SKT, 
SW, UPJ, WLN. 

APT, DSO, ICI, HID, MOB, PFZ, PPG, RCI, UCC, UNO, UPJ, WLN, 
WTC. 

ASH, CGL, DCC, GLD, MCC, MID, PPG, SFS, SPD, UCC. 

ACP, AMR, ASH, CGY, DSO, ENJ, EW, FLW, GLD, HYC, IOC, 
MID, MON, PPG, RCD, S, SM, UCC, USR, VAL. 



PLASTICS AND RESIN MATERIALS 
TABLE 2, --Plastics and resin materials for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



THERMOPLASTIC RESINS 

Acetal resins 

* Acrylic resins 

*Cellulosic plastics and resins 

*Couinarone-indene resins 

Fluoro carbon resins 

'Petroleum hydrocarbon resins 

Polyamide resins: 
*Nylon type 

*Non-nylon t^'pe 

Polybutene and polyisobutylene resins 

Polycarbonate resins 

*Polyester resins, saturated 

'Polyethylene and copolymers: 

'Density 0.940 and below 

'Density over 0.940 

'Ethylene copolymers 

'Polypropylene resins 

Polyterpene resins 

'Polytetrafluoroethylene (PTFE) 

'Rosin modifications: 

'Rosin and rosin esters, unmodified Caster gums)- 
'All other 

'Styrene type plastics materials: 

•Acrylonitrile-butadiene-styrene (ABS) resins — - 
'Styrene-acrylonitrile resins (SAN) 

'Styrene and styrene copolymer resins other than 
ABS and SAN. 



a- Methyl styrene polymers 

Vinyl resins: 

'Polyvinyl chloride and copolymer resins- 

'Polyvinyl acetate resins 

•Polyvinyl alcohol resins 

Polyvinyl butyral resins 

Polyvinylidene chloride resins 

All other vinyl resins 

All other thermoplastic resins 



CEL, DUP, POL. 

ACY, ASH, BAS, CEL, DSO, DUP, EFH, FLH, GLC, GNM, GRV, 
HNC, HRT, IOC, JNS, JSC, MID, NPV, POL, PPG, PVI , 
QUN, REL, RH, RPC, SAR, SCO, SED, SEY, SM, UBS, UCC, 
VAL, VPC, WIC, X. 

CEL, DOW, DUP, EKT, ICF, POL, x. 

DUP, ICF, NEV, PAI, VEL. 

DUP, MMM, PAS. 

DSO, EKX, GYR, NEV, PAI, PPG, RCI, VEL, ZGL. 

ALF, AZS, BCM, CEL, DUP, EW, FG, GNM, MON, POL, RSN, 

SKP. 
CBY, COO, DUP, EMR, GNM, SCO, SM, SNW. 

ENJ, RH. 
GE, MOB, POL. 

CEL, COO, DSO, DUP, EKT, GE, GLD, GNM, MID, MRT, REL, 
RUB, SHA. 

ACP, CBN, CPX, DOW, DUP, EKX, ENJ, GOC, KPP, MON, NWP, 

PLC, RCC, UCC, USI. 
ACC, ACP, CEL, CPX, DOW, DUP, EKX, GOC, KPP, MON, PLC, 

UCC, USI, X. 
DUP, EKX, ENJ, USI. 

ACC, DA, EKX, ENJ, HPC, NVT, PLC, RCC, SHC. 
CBY, PAI, SCN. 
ACP, DUP, ICI. PAS. 

ASH, CBY, DPP, FAR, FCD, FRP , GIL, MCC, NCI, RCI, SED. 
ASH, CBY, DPP, EW, FAR, FCD, FLK, FRP, GIL, GLD, NCI, 
RCI, RH, SCF, SW, ZGL. 

BFG, DOW, GRD, KPP, MCB, MON, RCC, USR. 

BFG, DOW, DSO, MON, SBI, SKT, UCC. 

ACC, AEP, ATR, BAS, BFG, BOR, CSD, DOW, DPI, DUP, FCD, 
FG, FIR, GAF, GNT, GOR, GRD, GYR, HLM, ICF, IOC, 
JNS, JSC, KPP, MMM, MON, MRT, ONX, PAI, PLA, POL, 
PRX, PVI, RCC, RH, RPC, SBI, SHC, SKT, SOL, SPE, 
UBS, UCC, UOC, USR, USS, VEL, WIC. 

ACC, DOW, FCD. 

ACP, AIP, AME, BFG, BOR, CO, DA, FIR, GNT, GRA, GYR, 
HN, ICF, KYS, MON, NSC, OMC, PNT, RUB, SFP, TNA, 
UCC, USR. 

AIP, ASH, BAL, BEN, BLS, BOR, CEL, DAN, DAV, DSO, DUP, 
FAR, FLH, FLW, FSH, GLC, GLD, GRD, HNC, HRT, JSC, 
KMC, KMP, MCC, M»1, MNP, MON, NPV, NSC, OBC, OCF, 
ONX, PII, PPG, PRX, PVI, QCP, RCI, RPC, SBI, SCO, 
SEY, SPC, UBS, UCC, UOC, WIC, x. 

AIP, DUP, MON. 

DUP, MON, UCC. 

BAS, BFG, DOW, DUP, GLD, GRD, MRT, SM, UBS. 

DOW, DSO, EW, MCC, MON, SM, UCC. 

ACC, CEL, DSO, DUP, EW, GE, PLC, PPG, RH, RPC, SM, 
UCC. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 3, --Plastics and resin materials: Directory of manufacturers, 1972 

ALPHABETICAL DIKECI'ORV BY LODt 

[Names of manufacturers that reported production or sales of plastics and resin materials to the U.S. Tariff Commis- 
sion for ly72 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ABS 


Abex Corp., American Brakeblok Division 


ECC 


Eastern Color 5 Chemical Co. 


ACC 


Amoco Chemical Corp. 


tFH 


E.F. Houghton i, Co. 


ACP 


Allied Chemical Corp., Plastics Division 




Eastman Kodak Co. : 


ACR 


CPC International, Inc., Acme Resin Co. Div. 


EKT 


Tennessee Eastman Co. Division 


ACY 


American Cyanamid Co. 


EKX 


Texas Eastman Co. Division 


AEP 


A 6 t Plastics Pak Co., Inc. 


EMR 


Emery Industries, Inc. 


AIP 


Air Products is Chemicals, Inc. 


ENJ 


Exxon Corp., Exxon Chemical Co. USA 


ALF 


Allied Chemical Corp., Fibers Div. 


hPC 


tpoxylite Corp. 


AMh 


American Chemical Corp. 


EW 


Westinghouse Electric Corp., Industrial 


AMR 


Pacific Resins 8 Chemical Co. 




Plastics Uiv., Chemical Products Plant 


APT 


Whittaker Corp., Mol Kez Division 






APX 


Apex Chemical Co., Inc. 


FAR 


Famow, Inc. 


ARK 


Armstrong Cork Co. 


FCD 


France, Camnbell f, Darling, Inc. 


ASH 


Ashland Oil, Inc., Ashland Chemical Co. Div. 


FG 


Foster Grant Co., Inc. 


atr 


Atlantic Richfield Co., ARCO Chemical Co. Div. 


FIR 


Firestone Tire 8 Rubber Co., Firestone 


AZS 


AZS Corp., M Products Co. Div. 




Plastics Co. Div. 






FLH 


H.B. Fuller Co. 


HAL 


Baltimore Paint 8 Chemical Corp. 


FLW 


Fuller-O'Brien Corp. 


HAS 


BASF Wyandotte Corp. 


FMP 


FMC Corp., Industrial Chemical Div. Organic 


BCM 


Belding Chemical Industries 




Business Group 


BEN 


Bennett's 


FOC 


.Handschy Chemical Co., Farac Oil t, Chemical 


BFG 


B.F. Goodrich Co., B.F. Goodrich Chemical Co. 




Co. Div. 




Division 


FOM 


Formica Corp. 


BLS 


Beech-Nut, Inc. 


FRh 


Freeman Chemical Corp. 


BMt 


Bendix Corp., Friction Materials Division 


FRP 


FRP Company 


BOR 


Borden Co., Borden Chemical Co. Division 


FSH 


Frisch 6 Co. , Inc. 


BRU 


M.A. Bruder 6 Sons, Inc. 










GAF 


GAF Corp., Chemical Division 


CBD 


Chembond Corp. 


GE 


General Electric Co. : 


CBM 


Carborundum Co., Coated Abrasives Division 


GET 


Insulating Materials Dept. 


CBN 


Cities Service Co., Columbian Div. 


GIL 


Gilman Paint 5 Varnish Co. 


CBY 


Crosby Chemicals, Inc. 


GLC 


General Latex 5 Chemical Corp. 


CD 


Budd Co., Polychem Division 


GLD 


SCM Corp., Glidden-Durkee Division 


CEL 


Celanese Corp. : 


GLX 


Electro-Seal Glasflex Corp. 




Celanese Coatings Co. 


GNM 


General Mills Chemicals, Inc. 




Celanese Plastics Co. 


GNT 


General Tire 6 Rubber Co., Chemical Division 


CGL 


Cargill, Inc. 


GOC 


Gulf Oil Corp., Gulf Oil Co. Chemicals Dept . - 


CGY 


Ciba-Geigy Corp. 




United States 


CLK 


Clark Chemical Corp. 


GOR 


Gordon Chemical Co., Inc. 


CM 


Carpenter-Morton Co. 


GP 


Georgia-Pacific Corp. 


CMP 


Commercial Products Co., Inc. 


GPM 


General Plastics Manufacturing Co. 


CO 


Continental Oil Co. 


GRA 


Great American Chemical Corp. 


COM 


Commercial Solvents Corp. 


GRD 


W.R. Grace 5 Co., Polymers Chemicals Division 


COO 


Coopers Polymers, Inc. 


GRG 


P.D. George Co. 


CPV 


Cook Paint 5 Varnish Co. 


GRV 


Guardsman Chemical Coatings, Inc. 


CPX 


Chemplex Co. 


GYR 


Goodyear Tire 6 Rubber Co. 


CSD 


Cosden Oil 5 Chemical Co. 










HAN 


Hanna Chemical Coating Corp. 


DA 


Diamond Shamrock Corp. 


HAP 


Applied Plastics Co., Inc. 


DAN 


Dan River, Inc. 


HER 


Heresite S Chemical Co. 


DAV 


Conchemco, Inc., H.B. Davis Co. Division 


HKD 


Hooker Chemical Corp., Durez Division 


DCC 


Dow Coming Corp. 


HLM 


U.S. Industries, Inc., E. Helman Co. Division 


DEC 


Degan Oil 5 Chemical Co. 


HN 


Tenneco Chemicals, Inc. 


DOW 


Dow Chemical Co. 


HNC 


H 5 N Chemical Co. 


DPI 


Diamond Plastics, Inc. 


HPC 


Hercules, Inc. 


DPP 


Dixie Pine Products Co., Inc. 


HRT 


Hart Products Corp. 


DSO 


DeSoto, Inc. 


HVG 


Haveg Industries 


DUP 


E.I. duPont de Nemours b Co., Inc. 


HYC 


Dexter Corp., Hysol Co. Division 



PLASTICS AMD RESIN MATERIALS 
TABLE 3,— Plastics and resim materials; Directory of manufacturers, 1972~Continued 



Code 


Name of company 


Code 


Name of company 


ICF 


Inmont Corp. , ABI Div. 


pnt 


Pantasote Co. 


ICI 


ICI America, Inc. f, Specialty Chemicals 


POL 


Polymer Corp. 




Div. 


PPG 


PPG Industries, Inc. 


INL 


Inland Steel Co., Inland Steel Container Co. 


PPL 


Pioneer Plastics Corp. 




Division 


prt 


Pratt 5 Lambert, Inc. 


IOC 


lonac Chemical Co. Div. of Sybron Corp. 


PRX 


Purex Corp., Ltd., Washbum-Lanson Co. Div. 


IPC 


Interplastic Corp. 


PVI 


Polyvinyl Chemical Ind., Div. of Ceatrice 


IRI 


Ironsides Resins, Inc. 




Foods Co. 






PYZ 


Polyrez Co. , Inc. 


JNS 


S.C. Johnson 5 Son, Inc. 






JOB 


Jones-Blair Paint Co. 


QCP 


Quaker Chemical Corp. 


JSC 


Jersey State Chemical Co. 


QUN 


K.J. Qidnn 5 Co., Inc. 


JWL 


Jewel Paint 6 Varnish Co. 










RAB 


Raybestos-Manhattan, Inc., Raybestos Div. 


KMC 


Kohler-McLister Paint Co. 


RCC 


Dart Industries, Inc., Rexene Polymers Co. Div 


KMP 


Kelly-Moore Paint Co. 


RCD 


Richardson Co. 


KPP 


Sinclair- Koppers Co. 


RCI 


Reichhold Chemicals, Inc. 


KPT 


Koppers Co. , Organic Materials Division 


RED 


Red Spot Paint and Varnish Co., Inc. 


KYN 


Kyanize Paints, Inc. 


REL 


Reliance Universal, Inc. 5 Resin Div. 


KYS 


Keysor Chemical Corp. 


REZ 


Hexcel Corp., Rezolin Division 






RGC 


Rogers Corp. 


MCA 


Masonite Corp., Alpine Division 


RH 


Rohm ^ Haas Co . 


MCB 


Borg-Wamer Corp., Marbon Chemical Division 


RPC 


Millmaster Onyx Corp., Refined-Onyx Division 


MCC 


McCloskey Varnish Co. 


RSN 


Relsan Corp. 


MFC 


North American Rockwell Corp. 


RSY 


Resyn Corp. 


MID 


Dexter Corp. , Midland Division 


KUB 


Hooker Chemical Corp., Ruco Division 


MMM 


Minnesota Mining S Manufacturing Co. 






MNP 


Minnesota Paints, Inc. 


S 


Sandoz, Inc., Sandoz Color 5 Chemical Div. 


MOB 


Mobay Chemical Co. 


SAC 


Southeastern Adhesives Co. 


MON 


Monsanto Co. 


SAR 


Sartomer Industries, Inc. 


MR 


Benjamin Moore 6 Co. 


SBC 


Scher Bros . , Inc. 


MRA 


Crown Metro, Inc. 


SB! 


Standard Brands Chemical Industries, Inc. 


MRS 


Marblette Co. 


SCF 


Guardsman Chemical Coatings, Inc., 


MRO 


W.R. Grace 5 Co., Marco Chemical Division 




Louisville Division 


mrt 


Morton Chemical Co. Div. of Morton-Norwich 


SCN 


Schenectady Chemicals, Inc. 




Products, Inc. 


SCO 


Scholler Bros. , Inc. 






SED 


' Conchemco, Inc., Kansas City Division 


NCI 


Union Camp Corp., Chemical Division 


SEY 


Seydel-Woolley 5 Co., Inc. 


NEV 


Neville Chemical Co. 


SFP 


Stauffer Chemical Co., Plastics Div. 


NPV 


Norris Paint 5 Varnish Co., Inc. 


SHA 


Shanco Plastics 5 Chemicals, Inc. 


NSC 


National Starch 5 Chemical Corp. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


ntc 


National Casein Co. 


SIC 


Vistron Corp., Silmar Division 


NVT 


Novamont Corp., Neal Works 


SIM 


Simpson Timber Co. 






SIP 


Sipes Chemical Coatings Co. 


OBC 


O'Brien Corp. 


SKP 


Shakespeare Co., Industrial Products Division 


OCF 


Owens-Corning Fiberglas Corp. 


SKT 


Textron Inc., Spencer Kellogg Division 


omc 


01 in Corp. 


SM 


Mobil Oil Corp., Mobil Chemical Co., 


ONX 


Millmaster Onyx Corp., Onyx Chemical Corp. 




Chemical Coatings Div. 


ORO 


Chevron Chemical Co. 


SNW 


Sun Chemical Corp., Chemicals Division 






SOL 


Solar Chemical Corp. 


PA I 


Pennsylvania Industrial Chemical Corp. 


SOR 


Thomason Industries, Inc., Southern Resin Div. 


PC 


Proctor Chemical Co., Inc. 


SPC 


Sinclair Paint Co., Div. of Insilco Corp. 


PEL 


Pelron Corp. 


SPD 


General Electric Co., Silicone Products Dept. 


PER 


Perry 6 Derrick Co. 


SPE 


Petrochemical Investment Corp. 


PFP 


Midwest Manufacturing Corp. 


SPL 


Spaulding Fibre Co., Inc. 


PFZ 


Pfizer, Inc. 


stc 


Sou-Tex Chemical Co., Inc. 


PGU 


Gulf Oil Corp., Gulf Adhesives 


SW 


Sherwin-Williams Co. 


PII 


Polymer Industries, Inc. 






PLA 


Richardson Co. 


tna 


Ethyl Corp. 


PLC 


Phillips Petroleum Co. 


TX 


Texaco, Inc. 


PLS 


Plastics Engineering Co. 


TXT 


Text il ana Corp. 


PMC 


Plastics Manufacturing Co. 







SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3, --Plastics and resin materials: Directory of manufacturers, 1972--Continued 



Code 


Name of company 


Code 


Name of company 


UBS 


A.E. Staley Manufacturing Co., Staley 


VAL 


Valchem 






Chemicals Division 


VEL 


Veliscol Chemical Corp. 




ucr 


Union Carbide Corp. 


VPC 


Baychem Corp., Verona Div. 




UNO 


United-Erie, Inc. 


vsv 


Valentine Sugars, Inc. 




uoc 


Union Oil Co. of California 








UPJ 


Upjohn Co. 


WCA 


West Coast Adhesives Co. 




UPL 


U.S. Plywood, WCM Operations, Shasta Area 


WCL 


Wright Chemical Co. 




USI 


National Distillers 5 Chemical Corp., U.S. 


WIC 


Wica Chemical Inc. 






Industrial Chemicals Co. Div. 


WLN 


Wilmington Chemical Corp. 




US I 


National Petro Chemical Corp. 


WRD 


Weyerhaeuser Co., Wood Products D 


vision 


uso 


U.S. Oil Co. 


IVTC 


Witco Chemical Co., Inc. 




USR 


Uniroyal, Inc., Chemical Division 








USS 


USS Chemicals, Div. of U.S. Steel Corp. 


ZGL 


Carolina Processing Corp. 





Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendi 



141 



RUBBER- PROCESSING CHEMICALS 

Rubber-processing chemicals are organic compounds that are added 
to natural and synthetic rubbers to give them qualities necessary for 
their conversion into finished rubber goods. In this report, statis- 
tics are given for cyclic and acyclic compounds, by use — such as 
accelerators, antioxidants, blowing agents, and peptizers. Data on 
production and sales of rubber-processing chemicals in 1972 are given 
in table 1. 

Production of rubber-processing chemicals as a group in 1972 amounted 
to 361 million pounds, or 11.6 percent more than the 323 million pounds 
reported for 1971. Sales of rubber-processing chemicals in 1972 amounted 
to 280 million pounds, valued at $178 million, compared with 246 million 
pounds, valued at $159 million, in 1971. The increased production and 
sales of rubber-processing chemicals in 1972 is attributable principally 
to the increased production and sales of cyclic antioxidants, antiozonants , 
and stabilizers. 

The output of cyclic rubber-processing chemicals in 1972 amounted to 
310 million pounds, or about 12.2 percent more than was reported for 1971. 
Sales in 1972 were 240 million pounds, valued at $158 million, compared 
with 211 million pounds, valued at $143 million, in 1971. Of the total 
output of cyclic rubber-processing chemicals in 1972, accelerators ac- 
counted for 32.1 percent and antioxidants for 63.1 percent. Production 
of antioxidants, which amounted to 195.6 million pounds in 1972, included 

129.5 million pounds of amino compounds and 66.1 million pounds of 
phenolic and phosphite compounds. Sales of amino antioxidants in 1972 were 

100.6 million pounds, valued at $68.7 million; sales of phenolic and 
phosphite antioxidants were 47.9 million pounds, valued at $27.2 million. 

Production of acyclic rubber-processing chemicals in 1972 amounted 
to 51.1 million pounds, an increase if 8.0 percent from the 47.3 million 
pounds reported for 1971. Sales in 1972 totaled 40.2 million pounds, 
valued at $19.7 million, compared with 34.9 million pounds, valued at 
$16.8 million* in 1971. Accelerators accounted for 56.3 percent of the 
output of acyclic rubber-processing chemicals for 1972 and dodecyl mer- 
captans accounted for 29.8 percent. 



^ See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are given in table 3. 



552-743 O - 74 - 10 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 1.— Rubber-processing chemicals; U.S. production and sales, 1972 



[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 2 lists separately all rubber-processing chemicals for which data on production or sales were re- 
ported and identifies the manufacturers of each] 



Production 



Quantity 



Unit 
value' 



Grand total 

RUBBER- PROCESSING CHEMICALS, CYCLIC 

Total 

Accelerators, activators, and vulcanizing agents, total 

Aldehyde-amine reaction products 

Dithiocarbamic acid derivatives 

Thiazole derivatives, total 

N-Cyclohexyl-2-benzothiazolesulfenamide 

2, 2 '-Dithi obis (ben zo thiazole) 

2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole, zinc salt 

All other thiazole derivatives 

All other accelerators, activators, and vulcanizing agents 

Antioxidants, antiozonants, and stabilizers, total 

Amino compounds, total 

Substituted p-phenylenediamines , total 

N,N'-Bis (1 ,4-dimethylpentyl)-p-phenylenediamine 

N,N' -Diphenyl-p-phenylenediamine 

All other substituted p-phenylenediamines 

Oc t y Id i phenyl amine 

N-Phenyl-2-naphthyl amine 

All other amino compounds^ 

Phenolic and phosphite compounds, total 

Polyphenolics (including bisphenols) 

Phenol, alkylated 

Phenol, styrenated 

All other phenolic and phosphite compounds 

Retarder: N-Nitrosodiphenylamine 

All other cyclic rubber-processing chemicals'* 

RUBBER- processing CHEMICALS, ACYCLIC 

Total - - - - 

Accelerators, activators, and vulcanizing agents, total 

Dithiocarbamic acid derivatives, total 

Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, zinc salt 

All other dithiocarbamic acid derivatives 



1,000 
pounds 



av).484 



2,256 

419 

86,338 

8,819 
21,272 

6,030 

4,006 
46,211 
10,471 

195,642 



129,515 

70,537 

6,049 

1,790 

62,698 

3,614 

4,511 

50,853 

66,127 

15,314 

1,581 



2,018 
12,786 



10,042 
3,989 
1,887 



1,000 
pounds 



1,000 
dollars 



157,944 



78.i4o 



1,302 

236 

67,001 

5,241 
11,675 

4,682 

4,132 
41,271 
10,307 

148,444 



00 


584 


48 


502 


1 


761 


46 


741 


3 


300 


48 


782 


47 


860 


14 


481 


3 


031 


1 


601 


28 


747 


1 


108 


11 


646 



20.599 



3,644 
2,007 
2,067 



50.874 



1,266 
597 

40,150 
4,852 
6,221 
1,784 
2,192 

25,101 
8,861 



68,663 
42,646 



40,851 

1,751 

24,266 

27,159 
16,100 

1,569 
444 

9,046 

702 
10,546 



3,185 
1,132 



Per 
pound 

$0.63 



.57 
1.11 



See footnotes at end of table 



RUBBER-PROCESSING CHEI1ICALS 
TABLE 1, --Rubber-processing chemicals: U.S. production and Sales, 1972--Continued 



Quantity 



Unit 
value' 



RUBBER-PROCESSING CHEMICALS, ACYCLIC--Continued 

Accelerators, activators, and vulcanizing agents--Continued 

ThiuraTiis, total' 

Bis(dimethylthiocarbamoyl) disulfide 

Bis (dimethyl thiocarbamoyl) sulfide 

All other thiurams 

All other accelerators, activators, and vulcanizing agents' 



Polymerization regulators: Dodecyl raercaptans 

Shortstops; Dimethyldithiocarbamic acid, sodium salt- 
All other acyclic rubber-processing chemicals® 



13,079 
2,618 



15,243 
4,575 
2,494 



1,000 
pounds 



11,596 
8,476 
2,006 
1,114 
1,285 

14,750 
2,070 
2,780 



1,000 
dollars 



5,226 
3,050 
1,554 
642 
2,063 

5,322 

533 

1,287 



Per 
pound 



' Calculated from rounded figures. 

^ Includes guani dines. 

^ Includes aldehyde- and acetone-amine reaction products . 

'* Includes blowing agents, peptizers, and other uses not separately shown. 

^ Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and 
synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are included in the report 
"Pesticides and Related Products." 

' Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural 
and synthetic rubbers. 

' Includes xanthates, disulfides, other dithiocarbamic acid derivatives (sales only) and other thiurams (production 
only) . 

' Includes blowing agents, conditioning and lubricating agents, polymerization regulators, shortstops and physical 
property improvers. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2, --Rubber-processing chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 



[Rubber-processing chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*) ; 
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

♦Accelerators, activators, and vulcanizing agents: 
*Aldehyde-anine reaction products: 

Acetaldehyde-ani line condensate 

n- But yraldehyde- aniline condensate 

Butyr aldehyde -but ylideneani line condensate 

a-Ethyl-6-propylacrylanilide 

Hept aldehyde- aniline condensate 

Triethy Itrime thy lenetri amine 

*Dithiocarbamic acid derivatives: 

Dibenzyldithiocarbamic acid, sodium salt 

Dibenzyldithiocarbamic acid, zinc salt 

Dibutyldithiocarbamic acid, N,N-dimethylcyclohexyl- 
amine salt. 

Dibutyldithiocarbamic acid, diphenylguanidine salt 

2 ,4-ninitrophenyl dimethyldithiocarbamate 

Piperidinecarbodithioic acid, piperidinium-notassium 
salts, mixed. 
Guanidines : 

Dicatechol borate, di-o-tolylguanidine salt 

1,3-Diphenylguanidine 

1,3-Di-o-tolylguanidine 

Dodecyltetramethylguanidine 

1 ,2 ,3-Triphenylguanidine 

*Thiazole derivatives: 

2-Benzothiazyl N,.N-diethylthiocarbamoyl sulfide 

1 , 5-Bis (2-benzothiazolylmercaptomethyl) urea 

N-tert- Butyl- 2-benzothiazolesulfenamide 

*N-Cyclohexyl-2-benzothiazolesulfenamide 

N,N-Diisopropyl-2-benzothiazolesulfenaniide 

N- (2 ,6-nimethylmorpholino) -2-benzothiazolesulfen- 
amide. 

*2,2'-Dithiobis(benzothiazole1 

*2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole, copper salt 

2-Mercaptobenzothiazole, zinc chloride 

*2-Mercaptobenzothiazole, zinc salt 

4-Morpholinyl-2-benzothiazyl disulfide 

N-Oxydiethylene-2-benzothiazolesulfenaiiiide 

Thiazoline-2-thiol 

All other cyclic accelerators, activators, and vulcan- 
izing agents: 

p-Benzoquinonedioxime 

Bis (p-aminocyclohexy 15 methane carbamate 

Bis (morpholinothiocarbonyl) disulfide 

Dibenzoy 1 -p- quinonedi oxime 

Dibenzyl amine 

N,N' -Dicinnamylidene-1 ,6-hexanediainine 

Di-^J,N' -pent ame thy lenethiuram tetrasulfide 

4,4 ' -Dithiodimorpholine 

2- Imidazoline- 2- thiol 

m-Phenylenebismaleimide 

Poly-p-dinitrosobenzene 

Toluene-2,4-diisocyanate adduct of dimethylethanol- 
amine. 
*Antioxidants , antiozonants, and stabilizers: 
*Amino compounds: 

Aldehyde- and acetone-amine reaction products: 

Acetaldehyde-aniline hydrochloride condensate 

Aldol-a-naphthylamine condensate 

Butyr aldehyde- aniline condensate 



USR. 

DUP, MON, RCD, USR. 

MON. 

RCI. 

USR. 

USR. 

USR. 
USR. 
MON. 

RCI- 
USR. 
DUP. 



DUP. 
ACY. 
ACY. 
DUP. 
ACS. 

PAS. 

MON. 

ACY, MON. 

ACY. BFG, MON, USR. 

ACY. 

MON. 

ACY, BFG, GYR, MON, USR. 

ACY, BFG, GYR, MON, USR. 

ACY. 

DUP. 

ACY, BFG, GYR, USR. 

GYR. 

ACY, BFG, MON. 

ACY. 



CTN. 
DUP.' 
ACY. 

CTN, USR. 
MLS, USR. 
DUP. 

DUP, WC. 
•KDN, VNC. 
DUP, RBC. 
DUP. 
DUP. 
DUP. 



USR. 
BFG. 
DUP. 



I 



RUBBER-PROCESSING CHEMICALS 



TABLE 2.- 



-RUBBER-PROCESSING CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC — CONTINUED 

^.Antioxidants , antiozonants , and stabilizers--Continued 
*Aiiiino compounds --Continued 

Aldehyde- and acetone-amine reaction products-- 
Continued 

Di phenyl amine -ace tone condensate 

Phenyl-2-naphthylamine-acetone condensate 

*Substituted p-phenylenediamines : 

N,N'-Bis(l ,3-dimethylbutyl)-p-phenylenediamine 

*N,N'-Bis(l ,4-dimethylpentyl)-p-phenylenediamine 

N,N' -Bis{l-ethyl-3-methylpentyl)-p-phenylenediamine 

N,N'-Bis(l-methyIheptyl) -p-phenylenedi amine 

N-sec-Butyl-N' -phenyl-p- phenyl enedi amine 

N-Cyclohexyl-N'-phenyl-p-phenylenediamine 

Diarylaryl enedi amines , mixed 

N,N' -Dicyclohexyl-p-phenylenediamine 

N- (1 ,5-Dimethylbutyl} -N' -ph enyl-p- phenyl enedi amine -■ 

N,N' -1 ,4~Dimethylhexyl-p-phenylenediamine 

N,N ' -Di-2-naphthyl-p-phenylenediamine 

*N,N' -Diphenyl-p-phenylenediamine 

N- I sopropyl-N' -phenyl -p-phenylenediamine 

N- (1-Methylheptyl) -N' -phenyl-p -phenyl enedi amine 

N- (1-MetIiylpentyl) -N' -phenyl -p-phenylenedi amine 

Nit roso-N-phenyl -p-phenylenediamine 

All other substituted p-phenylenediamine 

Other amino compounds: 

p-Anilinophenol 

4'-Bis(a,a-dimethylbenzyl)diphenylamine 

1 ,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline 

1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

1 ,2-Dihydro~2,2,4-trimethylquinoline 

4,4'-Dimethoxydiphenylamine 

Dinonyldiplienyl amine 

N,N'-Diphenylethylenediamine 

N,N' -Diphenyl -1 , 5-propanediamine 

N,N' -Di-o-tolylethylenediamine 

p-Hydroxydi phenyl amine 

4,4'-Methylenedianiline 

Nonyldiphenylamine mixture (mono-, di-, and tri-) — 

*Octyldiphenyl amine 

Oc t y Id i phenyl amine, alkylated 

N-Phenyl-1-naphthylamine 

*N-Phenyl-2-naphthylamine 

p- (p-Toluenesulfonamide)diphenylamine 

All other 

'Phenolic and phosphite compounds: 
Phenolic compounds: 
*Polyphenolics (including bisphenols) : 

Bisphenol, hindered 

4,4' -Butyl ideneb is (6-tert-butyl-m-cresol) 

2,5-Di-sec-butyldecylhydroquinone 

2,5-Di-(l, l-dimethylpropyl)hydroquinone 

2,2' -Methylenebis (6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) 

2, 2 '-Methylenebis [6- (l-methylcyclohexyl) -p- 
cres 1 ] . 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thiobis(4,6-di-5ec-amylphenol) 

4, 4 '-Thiobi 5 (6-tert-butyl-m-cresol) 

Thiobisphenol , alkylated 

1, 1,3 -Tri (2 -methyl-4-hydroxy-5-tert -butyl phenyl )- 
butane. 



ACY 


BFG, 


USR. 


USR 






x. 






EKT 


USR, 


X. 


MON 


X. 




BFG 


MON, 


X. 


USR 






USR 


X. 




GYR. 






X. 






GYR, 


USR. 




X. 






BFG, 


DUP. 




BFG, 


DUP, 


SDC, USR 


USR. 






X. 






USR. 






USR. 






MON. 






BFG. 






WSN. 






MON. 






MON. 






BFG, 


MON. 




DUP. 






ACY. 






DA, 


RCI. 




RCI. 






RCI. 






USR. 






USR. 






USR. 






.ACY, 


NPI, 


USR. 


BFG. 






DUP, 


UCC. 




BFG, 


DUP, 


USR. 


USR. 






USR. 







GYR, USR. 

MON. 

USR. 

MON. 

ACY, A.SH. 

ACY. 

ICI. 

ACY. 
MON. 
MON. 
USR. 
ICI. 



SYNTHETIC ORGANIC CHEMICALS. 1972 



TABLE 2.--F 



3ER-PR0CESSING CHEMICALS FOR WHICH U.S, PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC--CONTINUED 

•Antioxidants, antiozonants, and stabilizers--Continued 
'Phenolic and phosphite coiiipounds--Continued 
Phenolic compounds--Continued 
Other phenolic compounds: 

p-Benzyloxyphenol 

o-Cresol, alkylated 

N-Lauroyl-p-aminophenol 

•Phenol, alkylated 

Phenol, hindered 

*Phenol , styrenated 

N-Stearoyl-p- aminopheno 1 

♦Phosphite compounds: 

Alkylaryl phosphites 

Nonyl phenyl phosphites, mixed 

Polymeric phosphite 

Polyphenolic phosphite, alkylated 

Tr iary 1 phosphates 

Blowing agents: 

N,N' -Dimethyl-N,N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-OxybisCbenzenesulfonhydrazide) 

p-Toluenesulfonylhydrazide 

p-Toluenesulfonylsemicarbazide 

Peptizers: 

2-Benzamidothiophene, zinc salt 

Dicresyl disulfide 

2' ,2' ' '-Dithiobis(benzanilide) 

Dixylyl disulfides, mixed 

2-Naphthalenethiol 

Pentachlorobenzenethiol 

Xylenethiol 

*Retarders: N-Nitrosodiphenylamine 

Other cyclic rubber-processing chemicals: 

p-tert-Amylphenol sulfide (tackifier) 

4-Chloro-2,6-bisC2,4-dihydroxybenzyl)phenol 

Phenol cyanurate complex 

All other 

RUBBER-PROCESSING CHEMICALS, ACYCLIC 

•Accelerators, activators, and vulcanizing agents: 
•Dithiocarbamic acid derivatives: 

Dibutyldithiocarbamic acid, nickel salt 

Dibutyldithiocarbamic acid, potassium salt 

Dibutyldithiocarbamic acid, sodium salt 

•Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, selenium salt 

Diethyldithiocarbamic acid, sodium salt 

Diethyldithiocarbamic acid, tellurium salt 

•Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, bismuth salt 

Dimethyldithiocarbamic acid, copper salt 

Dimethyldithiocarbamic acid, lead salt 

Dimethyldithiocarbamic acid, selenium salt 

Dimethyldithiocarbamic acid, sodium salt and sodium 
polysulfide. 

•Dimethyldithiocarbamic acid, zinc salt 

All other 

•Thiurams : 

Bis(dibutylthiocarbamoyl) sulfide 

Bisfdiethylthiocarbamoyl) disulfide 

•Bis (dimethyl thiocarbamoyl) disulfide 



BFG. 

PIT. 

MLS. 

ACY, BFG, GYR, NEV, PIT, RCI. 

DUP, GYR. 

BFG, GYR, NEV, USR. 

MLS. 

WES. 

NPI, USR. 
NPl. 
BFG. 
WES. 

DUP. 
NPI. 
USR. 
USR. 
USR. 

ACY. 
USR. 
ACY. 
PIT. 
DUP. 
SDC. 
DUP. 
ACY, BFG, CTN, GYR, NPI, USR. 

PAS. 
ICI. 
ICI. 
MON, RCI. 



DUP, USR, VNC. 

DUP, PAS, RBC, USR, VNC. 



PAS. 

GYR, PAS, USR, VNC. 



USR. 
VNC. 
ALC, 
ALC, 
VNC. 
ALC, 
VNC. 
ALC, 
VNC. 
VNC. 
VNC. 
VNC. 
BFG. 



ALC, DUP, FMN, GYR, PAS, RBC, USR, VNC, WRC. 
VNC. 

USR. 

DUP, GYR, PAS. 

DUP, GYR, PAS, VNC. 



RUBBER-PROCESSING CHEMICALS 



TABLE 2, 



-Rubber-processing chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, ACYCLIC--CnNTINUED 

'Accelerators, activators, and vulcanizing agents-- 
Continued 
*Thiurams - -Cont inued 

*Bis(dimethylthiocarbamoyl) sulfide 

Bis(ethylmethylthiocarbamoyl) sulfide 

Xanthates and sulfides: 

Bis(diisopropoxythiophosphoryl) disulfide 

Di-n-butylxantho disulfide 

Diisopropylxantho disulfide 

Zinc diisopropyl xanthate 

All other acyclic accelerators, activators, and 
vulcanizing agents: 

n-Butyraldhyde-butylamine condensate 

D i - n -but y 1 ammon ium oleate 

3-Ethyl-l ,1 -dimethyl -2 -thiourea 

Ethyl enediamine carbamate 

Tetramethyl thiourea 

1 ,l,3-Trimethyl-2-thiourea 

Blowing agents: Modified urea 

Conditioning and lubricating agents: 

Methyl stearyl-10-sulfonic acid, sodium salt 

Mono- and dialkyl acid phosphates, mixed 

Mono- and dialkyl phosphate ammonium salts, mixed — 

Other 

Polymerization regulators: 

Alkyl mercaptans, mixed 

*Dodecyl mercaptan 

n-Octyl mercaptan 

tert-Octyl mercaptan 

Tridecyl mercaptan 

Shortstops: 

Dimethyldithiocarbamic acid, potassium salt 

*Dimethyldithiocarbamic acid, sodium salt 

Other acyclic rubber-processing chemicals: 

Zinc laurate (activator, physical -property improver) 



DUP, GYR, USR. 
PAS. 

DUP. 
USR. 
BFG. 
VNC. 



DUP. 

DUP. 

VNC. 

DUP. 

DUP. 

RBC, VNC. 

DUP. 

DUP. 
DUP. 
DUP. 
DUP. 



HK, PAS, PLC. 

PAS. 

PAS. 

PAS. 

GYR, USR. 

ALC, DUP, GYR, PAS, USR, WRC. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3, —Rubber-processing chemicals; Directory of manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 



[Names o£ rubber-processing chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1972 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACS 


Allied Chemical Corp., Specialty Chemicals 


MLS 


Miles Laboratories, Inc., Marshall Div. 






Div. 


MON 


Monsanto Co. 




ACY 


American Cyanamid Co. 








ALC 


Alco Chemical Corp. 








ASH 


Ashland Oil, Inc., Ashland Chemical Co. 










' Div. 


NEV 


Neville Chemical Co. 








NPI 


Stepan Chemical Co., National Polychesiicals Di 


V- 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 


PAS 
PIT 
PLC 


Pennwalt Chemicals Corp. 
Pitt-Consol Chemical Co. 
Phillips Petroleum Co. 




CTN 


Chemetron Corp., Organic Chemical Div. 


RBC 
RCD 


Fike Chemicals, Inc. 
Richardson Co. 




DA 


Diamond Shamrock Corp. 


RCI 


Reichhold Chemicals, Inc. 




DUP 


E. I. duPont de Nemours 5 Co., Inc. 


SDC 


Martin-Marietta Corp., Sodyeco Div. 




EKT 


Eastman Kodak Co., Tennessee Eastman 
Co. Div. 


UCC 


Union Carbide Corp. 




FMN 


FMC Corp., Niagara Chemical Div. 


UPM 
USR 


Universal Oil Products Co. 
Uniroyal, Inc., Chemical Div. 




GYR 


Goodyear Tire 5 Rubber Co. 


VNC 


Vanderbilt Chemical Corp. 




HK 


Hooker Chemical Corp. 


WES 


Borg-Warner Corp., Weston Chemical Div. 




ICl 


ICI America, Inc. 


WRC 


Ventron Corp . , Wood Ridge Chemical 








WSN 


Mallinckrodt Chemical Works, Washine Div. 





Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix. 



149 

ELASTOMERS 

Elastomers (synthetic rubbers) are high polymeric materials with 
properties similar to those of natural rubber. The term "elastomers" as 
used in this report, means a substance, whether in bale, crumb, powder, 
latex, and other crude form, which can be vulcanized or similarly proc- 
essed into a material that can be stretched to at least twice its original 
length and, after having been so stretched and the stress removed, will 
return with force to approximately its original length. U.S. production 
and sales of elastomers in 1972 are shown in table 1.^ 

Total U.S. production of synthetic elastomers in 1972 was 4,914 mil- 
lion pounds, an increase of 6 percent from that produced in 1971. The 
sales of these elastomers amounted to 4,136 million pounds (valued at 
$1,095 million) in 1972, an increase of 3 percent over 1971. 

Styrene-butadiene rubber (SBR or S-type rubber) in 1972 continued to 
be the synthetic elastomer produced in the greatest quantity as it has been 
for more than 25 years. U.S. production of SBR, including 38 million 
pounds of its vinylpyridine sub-type, amounted to 2,648 million pounds in 
1972. Solution polymerized butadiene rubber, a stereo type elastomer, was 
produced domestically in 1972 in the next largest amount--666 million 
pounds; production of isoprene and ethylene-propylene rubbers, the other 
stereo types, amounted to 295 million and 200 million pounds, respectively. 
Total U.S. production of these stereo type elastomers amounted to 1,161 
million pounds in 1972--an increase of 8 percent over 1971. Other principal 
types of synthetic elastomers for which U.S. production and sales data are 
reported separately are isobutylene-isoprene (butyl) rubber, production of 
which was 290 million pounds in 1972, and acrylonitrile-butadiene (N-type) 
rubber, production of which was 160 million pounds. 

U.S. production and sales data on synthetic organic chemicals are 
reported in terms of cyclic and acyclic structured compounds for purposes 
of better correlation with other statistical reporting systems. In 1972, 
U.S. production of cyclic elastomers amounted to 2,706 million pounds, an 
increase of nearly 4 percent over 1971; sales of cyclic elastomers amounted 
to 2,177 million pounds (valued at $471 million^), a decrease in volume 
of 3 percent compared with 1971. U.S. production of acyclic elastomers in 
1972 amounted to 2,208 million pounds, an increase of 10 percent over 1971; 
sales of acyclic elastomers amounted to 1,959 million pounds (valued at 
$624 million), an increase in volume of 9 percent from the previous year. 



See also table 2 which lists these products and identifies the manu- 
facturers of each by code. These codes are given in table 3. 

^The value of sales in 1971 and 1972 for styrene-butadiene (S-type) rubber, 
which comprise about 90 percent of the sales value of cyclic elastomers, was 
calculated on a somewhat different basis than in previous years. The 
value of sales in 1971 for S-type elastomers is believed to have increased 
slightly over that in 1970, although the published figures showed a decrease. 



SYNTHETIC ORGAillC CHEMICALS, 1972 
TABLE 1.— Elastomers (synthetic rubbers):' U.S. production and sales- 1972 

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be published. 
(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 2 lists all elastomers for which data on production or sales were reported and identifies the 
manufacturers of each] 



Production 



Sales 



Quantity 



Unit 
value^ 



Grand total 

ELASTOMERS, CYCLIC 

Total 

Styrene-butadiene type (S-type)^ 

Styrene-butadiene-vinylpyridine type 

Urethane type 

ELASTOMERS, ACYCLIC 

Total 

Acrylonitrile-butadiene type (N-type) 

Isobutylene-isoprene type (Butyl) 

Silicone type 

Stereo elastomers, total 

Butadiene (solution polymerized) type-- 

Ethy lene-propy 1 ene type 

I soprene type 

All other acyclic elastomers^ 



1,000 
pounds 



4,915,959 



1,000 
pounds 



4,156,263 



1,000 
do I laps 



Per 
pound 



2,610,142 
38,161 
57,296 



2,208,560 



,118,686 
21,720 
56,897 



1,958,960 



'415,783 
11,829 
42,957 



624,257 



159,745 
289,746 
26,752 

1,160,849 



155,489 

27,214 

887,229 



59,884 
64,899 
176,402 



666,427 
199,558 
294,864 



466,315 
183,165 
237,749 



86,565 
47,795 
42,242 



The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be 
vulcanized or similarly processed into materials that can be stretched at 68°F. to at least twice their original 
length and, after having been so stretched and the stress removed, will return with force to approximately their 
original length. 

^ Calculated from rounded figures. 

' Elastomer-content basis. 

'* Partly estimated. 

^ Partly estimated. Includes the value of added oil. 

^ Includes production and sales data for acrylic ester, polysulfide, chloroprene, epichlorohydrin, and isobutylene 
elastomers, butadiene emulsion polymers, chlorosulfonated polyethylene, halogenated elastomers, thermoplastic rubber, 
miscellaneous elastomers and sales data for the isobutylene-isoprene type elastomer. Also includes miscellaneous 
cyclic elastomers, among which are carboxylated SBR latex, certain solution poljTners, and thermoplastic rubber. 

Note. — Statistics on the production of S-type, butyl, neoprene, and stereo elastomers were compiled in cooperation 
with the U.S. Bureau of the Census. 



TABLE 2.- 



ELASTOMERS 
-Elastomers (synthetic rubbers) for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER/ 1972 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 1 are marked below with an asterisk 
[*) ; products not so marked do not appear in table 1 because the reported data are accepted in confidence and 
may not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3] 



ELASTOMERS, CYCLIC 

*Styrene-butadiene type (S-t>'pe) 

*Styrene-butadiene-vinylpyridine type 

*Urethane t>'pe 

Other cyclic elastomers 

elastomers, ACYCLIC 

Acrylic ester type 

*Acrylonitrile-butadiene type (N-type) — 
Butadiene (emulsion polymerized) type — 

Chloroprene type (Neoprene) 

*Isobutylene-isoprene type (Butyl) 

Polysulf ide type 

Reaction products of natural rubber 

*Silicone type 

*Stereo elastomers: 

*Butadiene (solution polymerized) type- 

*Ethylene-propylene type 

*Isoprene type 

All other acyclic elastomers 



ASH, ASY, BFG, CPY, FIR, FRS, GNT, GYR, MCB, PLC, RUB, SBI, 

SHC, TUS, USR, WIC. 
BFG, FIR, FRS, GNT, GYR, USR. 
ACY, BFG, CNl, DA, DNS, DUP, EPl, GNT, INP, MOB, PFP, PLN, 

PRC, RUB, TKL, USR, WTC, x, x. 
ASY, DUP, PLC, PRC, SHC, UCC. 



ACY, BFG, DA, TKL. 

BFG, CPY, FRS, GYR, SBI, USR. 

BFG, FRS, GYR, TKL, TUS. 

DUP, PTT. 

CBN, ENJ. 

PRC, TKL. 

GYR, ICl, WAY, X. 

DCC, PRC, SPD, SWS, UCC. 

ASY, ATR, BFG, FRS, GNT, GYR, PLC, SHC, TUS. 

BFG, CPY, DUP, ENJ, USR. 

BFG, GYR, SHC. 

.ASY, BFG, DUP, ENJ, HDM, Mt»1, PLC, SHC. 



SYNTHETIC ORGANIC CHEMICALS. 1972 



TABLE 3. 



-Elastomers (synthetic rubbers): Directory of Manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 



[Names of elastomers manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are 
listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACY 


American Cyanamid Co. 


ICI 


ICI America, Inc. 


ASH 


Ashland Chemical Co. 


INP 


INDPOL 


ASY 


American Synthetic Rubber Corp. 






atr 


Atlantic Richfield Co., ARCO Chemical Co. 


MCB 


Borg-Warner Corp., Marbon Chemical Div. 




Div. 


MW1 


Minnesota Mining S Manufacturing Co. 






MOB 


Mobay Chemical Co. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 








Co. Div. 


PFP 


Midwest Manufacturing Corp. 






PLC 


Phillips Petroleum Co. 


CBN 


Cities Service Co., Columbian Group 


PLN 


Pellon Corp., Disogrin Industries, Div. 


CNl 


Conap, Inc. 


PRC 


Products Research 6 Chemical Corp. , 


CPY 


Copolymer Rubber 5 Chemical Corp. 




Chemical and Sealant Div. 






PTT 


Petro-Tex Chemical Corp. 


DA 


Diamond Shamrock Corp. 






DCC 


Dow Coming Corp. 


RUB 


Hooker Chemical Corp., Ruco Div. 


DNS 


Dennis Chemical Co. 






DUP 


E. I. duPont de Nemours 5 Co., Inc. 


SB I 


Standard Brands Chemical Industries, Inc. 






SHC 


Shell Oil Co., Shell Chemical Co. Div. 


ENJ 


Exxon Chemical Co., U.S.A. 


SPD 


General Electric Co., Silicone Products Dept . 


EPl 


Eagle Pitcher Industries, Inc., 
Rubber Products Div. 


SWS 


Stauffer Chemical Co., SWS Silicones Div. 






TKL 


Thiokol Chemical Corp. 




Firestone Tire 5 Rubber Co.: 


TUS 


Texas-U.S. Chemical Co. 


FIR 


Firestone Plastics Co. Div. 






FRS 


Firestone Synthetic Rubber 6 Latex 


UCC 


Union Carbide Corp. 




Co. Div. 


USR 


Uniroyal , Inc., Chemical Div. 


GNT 


General Tire 5 Rubber Co., Chemical Div. 


WAY 


Philip A. Hunt Chemical Corp., Wayland 


GYR 


Goodyear Tire S Rubber Co. 




Chemical Div. 






WIC 


Wica Chemicals, Inc. 


HDM 


Hardman, Inc. 


WTC 


Witco Chemical Co., Inc. 



Note. --Complete names and addresses of the above reporting companies 



listed in Table 1 of the Appendix. 



153 
PLASTIC IZERS 



Plasticizers are organic chemicals that are added to synthetic 
plastics and resin materials to (1) improve workability during fabri- 
cation, (2) extend or modify the natural properties of these materials, 
or (3) develop new improved properties not present in the original 
material. Table 1 presents statistics on U.S. production and sales of 
plasticizers in as great as detail as is possible without revealing the 
operations of individual producers . ^ 

U.S. production of plasticizers totaled 1,708 million pounds in 
1972, an increase of 14.3 percent from the 1,494 million pounds reported 
for 1971. Sales of plasticizers totaled 1,637 million pounds, valued at 
$291 million, in 1972, compared with 1,404 million pounds, valued at 
$258 million, in 1971. 

Production of cyclic plasticizers in 1972, which consisted chiefly 
of the esters of phthalic anhydride and phosphoric acid, amounted to 1,302 
million pounds, an increase of 15.2 percent from the 1,130 million pounds 
reported for 1971. Sales of cyclic plasticizers in 1972 totaled 1,273 
million pounds, valued at $180 million, compared with 1,075 million pounds, 
valued at $158 million, in 1971. The most important cyclic plasticizer was 
di(2-ethylhexyl) phthalate, with production of 435 million pounds, in 1972. 

Production of acyclic plasticizers in 1972 totaled 406 million pounds, 
an increase of 11.7 percent from the 364 million pounds reported for 1971. 
Sales of acyclic plasticizers totaled 364 million pounds, valued at $111 
million, in 1972, compared with 330 million pounds, valued at $100 million, 
in 1971. Epoxidized soya oils were the most important acyclic plasticizer 
in 1972, with production of 85 million pounds. 



See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are listed in table 3. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 1.~Plasticizers;' U.S. production and sales, 1972 

[Listed below are plasticizers for which any reported data on production or sales may be published. (Leaders are 
used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 2 lists all plasticizers for which data on production or sales were reported and identifies the manufac- 
turers of each] 



Quantity 



Grand total 

Benzenoid' 

Nonbenzenoid 

PLASTICIZERS, CYCLIC 

Total 

Phosphoric acid esters, total 

Cresyl diphenyl phosphate 

Tricresyl phosphate 

All other phosphoric acid esters 

Phthalic anhydride esters, total 

Butyl octyl phthalates (including butyl 2-ethylhexyl 
phthalate, isobutyl 2-ethylhexyl phthalate, and butyl 

n-octyl phthalate) 

Dibutyl phthalate 

Diethyl phthalate 

Diisodecyl phthalate 

Dimethyl phthalate 

Dioctyl phthalates: 

Di (2-ethylhexyl) phthalate 

Diiso-octyl phthalate-- 

n-Hexyl n-decyl phthalate 

All other phthalic anhydride esters 

Triraellitic acid esters, total 

Triiso-octyl trimellitate 

Tri-n-octyl n-decyl trimellitate 

Trioctyl trimellitate 

All other triraellitic acid esters 

All other cyclic plasticizers" 

PLASTiaZERS, ACYCLIC 

Total 

Adipic acid esters, total 

Di[2-(2-butoxyethoxy)ethyl] adipate 

Di (2-ethylhexyl) adipate 

Diisodecyl adipate 

Dioctyl adipates (including diiso-octyl adipate) 

n-Hexyl n-decyl adipate 

n-Octyl n-decyl adipate 

All other adipic acid esters 

Complex linear polyesters and polymeric plasticizers' 

Di (2-ethylhexyl) azelate 



1,000 
pounds 

1,708.313 



1,393,499 
314,814 



3,772 



14,556 
50,221 
23,995 



11,353 
29,080 
19,044 
153,270 
9,683 

435,032 
32,296 
16,048 

439,887 

12,122 



4,231 
2,165 
2,967 
2,759 

55,368 



406,358 



1,325 

44,857 

2,838 

1,504 
8,763 
4,569 

53,183 
11,334 



1,000 
pounds 



1,000 
dollars 



1,354,410 
283,087 



15,152 
51,982 



14,214 
33,562 

162,183 
8,766 

441,776 

29,774 

9,365 

438,853 

9,680 



3,281 
1,050 
2,848 
2,501 

57,884 



364,306 



57,068 



1,342 
39,716 
2,188 
1,364 
1,031 
8,912 
2,515 

46,306 



201,340 
89,224 



4,074 
17,042 



1,774 
5,418 

19,129 
1,594 

48,655 
3,506 
1,161 

57.001 

2,732 



320 
802 
722 



110,513 



12,029 



703 
7,509 
460 
308 
202 
1,932 
915 

17,442 



See footnotes at end of table. 



PLASTICIZERS 
TABLE 1.~Plasticizers; ' U.S. production and sales, 1972--Continued 



Quantity 



Unit 
value^ 



PLASTICIZERS, ACYCLIC— Continued 

Epoxidized esters: 

Epoxidized soya oils 

Octyl epoxytallates (including 2-ethylhexyl epoxy 

tallates) 

Glyceryl monoricinoleate 

Isopropyl myristate 

Isopropyl palmitate 

Oleic acid esters, total 

Butyl oleate 

Methyl oleate 

Propyl oleates (including n-propyl oleate and isopropyl 

oleate) 

All other oleic acid esters 

Phosphoric acid esters 

Sebacic acid esters, total 

Dibutyl sebacate 

Di(2-ethylhexyl) sebacate 

All other sebacic acid esters 

Stearic acid esters, total 

n- Butyl stearate 

All other stearic acid esters 

Triethylene glycol di(caprylate-caprate) 

All other acyclic plasticizers^ 



1,000 
pounds 



85,132 

31,348 

320 

4,843 

6,455 

11,564 



2,404 
3,057 



1,670 
4,433 



4,483 

3,520 

218 

13.556 



8,290 
5,266 



2,290 
84,895 



1,000 



1,000 
dollars 



75,028 

26,140 

306 

6,065 

5,192 

10,535 



18,236 

6,267 

129 

3,037 

1,998 

2,418 



2,501 
2,912 



1,052 
4,070 



577 
544 



248 
1,049 



3,029 

3,479 

215 



1,895 

1,971 

237 



7,732 
4,387 



2,133 
92,342 



1,995 
1,559 



717 
29,024 



Per 
pound 



1 Includes data for compounds used principally (but not exclusively) as primary plasticizers. Does not include 
clearly defined extenders or secondary plasticizers. 

2 Calculated from rounded figures. 

3 Includes benzenoid products as defined in part 1 of schedule 4 of the Tariff Schedules of the United States 
Annotated. 

■■ Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, isopropylidenediphenoxy 
propanol, all other phosphoric acid esters (sales only), toluenesulfonamides, tetrahydrofurfuryl oleate, and other 
cyclic plasticizers. 

5 Adipic acid polyesters account for most of the production of complex linear polyesters and polymeric plasticizers. 

6 Includes data for azelaic, citric and acetylcitric, lauric, myristic, palmitic, pelargonic, ricinoleic, and sebacic 
acid esters, glyceryl and glycol esters, and other acyclic plasticizers, not separately shown. 



SYNTHETIC ORGANIC CHEMICALS. 1972 ■ 
TABLE 2.— Plasticizers for which U.S. production or sales were reported, identified by 

MANUFACTURER, 1972 

[Plasticizers for which separate statistics are given in table 1 are marked below with an asterisk (*) ; products not 
so marked do not appear in table 1 because the reported data are accepted in confidence and may not be published. 
Manufacturers 's identification codes shown below are taken from table 3. An x signifies that the manufacturer did 
not consent to his identification with the designated product] 



Manufacturers' identification code 
(according to list in table 3) 



PLASTICIZERS, CYCLIC 

Coumarone-indene plasticizers 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl sebacate 

Diethylene glycol dibenzoate 

Di-tert-octylphenyl ether 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

'Phosphoric acid esters: 

'Cresyl diphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl octyl phosphate 

Methyl diphenyl phosphate 

*Tri cresyl phosphate 

Tri phenyl phosphate 

*Phthalic anhydride esters: 

Alkyl benzyl phthalates 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

•Butyl octyl phthalates: 

Butyl 2-ethylhexyl phthalate 

Butyl n-octyl phthalate 

Di(2-butoxyethyl) phthalate 

*Dibutyl phthalate 

Dicyclohexyl isodecyl phthalate 

Di cyclohexyl phthalate 

Diethyl isophthalate 

♦Diethyl phthalate 

Dihexyl phthalate 

*Di isodecyl phthalate 

Di-iso-hexyl phthalate 

Diisononyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl isophthalate 

"Dimethyl phthalate 

Dinonyl phthalate 

Dioctyl phthalates: 

Dicapryl phthalate 

Di (2-ethylhexyl) isophthalate 

*Di (2-ethylhexyl) phthalate 

*Diiso-octyl phthalate 

Di- n-octyl phthalate 

Mixed dioctyl phthalates 

Diphenyl phthalate 

*ni-tridecyl phthalate 

2- (Ethylhexyl)isobutyl phthalate 

Glycol phthalate esters: 

Butyl phthalyl butyl glycolate 

Ethyl (and methyl) phthalyl ethyl glycolate- 

Polypropylene glycol bis(amyl) phthalate 

All other glycol phthalate esters 



NEV. 














MON. 














WTH. 














VEL. 














DOIV. 














VEL. 














MON. 














DOW. 














ACC. 














FMP, 


MON, MTR 


SFS 










MON, 


ORO. 












MON. 














FMP, 


MON. 












FMP, 


MON, MTR 


SFS 










EK, 


MON, SFS. 












MON. 














MON. 














ACS, 


CPS. 












ACP, 


GRH, MON 


TEK 


UCC 








RCI, 


USS. 












ARC, 


FMP. 












.(^CP, 


COM, EKT 


GRH 


HAL 


MON, RCI, RUB, SW, 


UCC, 


USS 


WTC. 












GRH. 














FMP, 


MON, PFZ 












PFZ. 














EKT, 


KF, MON, 


PFZ. 










USS. 














ACP, 


CO, EKT, 


ENJ, 


GRH, 


MON, RCI, TEK, UCC, 


USS, 


WTC 


ENJ. 














ENJ, 


PFZ. 












EKT, 


FMP, SFS 












PFZ. 














EKT, 


KF, MON, 


TCC. 










RCI. 














WTH. 














UCC. 















ACP, BFG, CO, EKT, ENJ, GRH, MON, PFZ, RCI, RUB, TEK, 

UCC, USS, WTC. 
ACP, ENJ, GRH, MON, RCI, TEK, UCC, USS. 
EK. 
TEK. 
MON. 

ACP, CO, ENJ, GRH, MON, RCI, RUB, TEK, UCC, USS. 
GRH. 

MON . 
MON. 
UCC. 
HPC, WTC. 



PLASTICIZERS 
TABLE 2,~Plasticizers for which U,S, production or sales were reported, identified by 

MANUFACTURER, 1972~CONTINUED 



Manufacturers' identification codes 
(according to list in table 3] 



PLASTICIZERS, CYCLIC--Continued 

*Phthalic anhydride esters--Continued 

*n-Hexyl n-decyl phthalate 

Hexyl isodecyl phthalate 

Isodecyl tridecyl phthalate 

Iso-octyl isodecyl phthalate 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Polyethylene glycol dibenzoate 

Tetrahydrofurfuryl oleate 

Toluenesulfonainide o- , p- mixtures 

*Trimellitic acid esters: 

Tri(2-ethylhexyl3 trimellitate 

Tri-n-hexyl trimellitate 

Tri isodecyl trimellitate 

Triisononyl trimellitate 

*Tri iso-octyl trimellitate 

*Tri-n-octyl n-decyl trimellitate 

*Trioctyl trimellitate 

All other trimellitic acid esters 

Trimethylpentanediol dibenzoate 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

*Adipic acid esters: 

''Di[2-(butoxyethoxyJethyl] adipate 

*Di(2-ethylhexyl) adipate 

Diisobutyl adipate 

*Di isodecyl adipate 

Diisononyl adipate 

Diisopropyl adipate 

•Dioctyl adipates: 

Diiso-octyl adipate 

Di-n-octyl adipate 

Di- tridecyl adipate 

*n-Hexyl n-decyl adipate 

Iso-octyl isodecyl adipate 

*n-Octyl n-decyl adipate 

All other adipic acid esters 

Azelaic acid esters: 

*Di (2-ethylhexyl) azelate 

Diisobutyl azelate 

Diiso-octyl azelate 

All other azelaic acid esters 

1 ,4-Butanediol dicaprylate 

But oxy ethyl pelargonate 

Castor oil maleate 

Citric and acetylcitric acid esters 

•Complex linear polyesters and polymeric plasticizers- 

Di[(butoxyethoxy)ethoxy] methane 

Dibutyl tartrate 

Diethylene glycol dipelargonate (Dinonanoate) 

Diiso-octyl dig lyco late 



ACP, CO, ENJ, TEK, UCC . 

GRH. 

TEK. 

ACP, GRH. 

ACP, CO, GRH, MON, RCl, TEK, UCC, USS. 

ACP, FMP, PF2, RUB, TEK, UCC, USS. 

VEL. 

EMR. 

ACY, LAK, MON. 

GRH, PFZ, RCI. 

CO, RUB. 

PFZ. 

ENJ. 

ENJ, GRH, RCI, RUB, TEK, USS. 

GRH, PFZ, RCI, RUB, TEK, USS. 

CO, RUB, TEK, USS. 

X. 

VEL. 

MON, NEV, SFS. 



FMP, RCI, TKL, WTH. 

CO, DA, EKT, ENJ, GRH, MON, PFZ, RCI, RH, RUB, TEK, UCC, 

USS. 
GRH, HAL. 

ACP, ENJ, GRH, MON, PFZ, RCI, RH, RUB, UCC, USS. 
ENJ, RUB. 
SBC, VND. 



GRH, 


RH, 


RUB, 


USS. 






ACP. 












GRH. 












GRH, 


TEK 


USS 








GRH, 


PFZ 










ACP. 


CO, 


GRH, 


MON, 


RCI, 


RH, USS 


ARC, 


EK, 


GRH, 


PFZ, 


UCC, 


WTH. 


EKT, 


EMR 


PFZ 


RCI 


UCC 




HAL. 












EMR, 


PFZ 










EMR. 












RUB. 












HAL. 












RH. 












GLY, 


PFZ 










ASH, 


EKT 


EMR 


GRH 


HAL 


MON, P 


TKL. 












ARC. 












EMR. 












CCA. 













552-743 0-74-11 



SYNTHETIC ORGANIC CHEMICALS, 1972' 

table 2.--plastic1zers for which u.s. production or sales were reported, identified by 
Manufacturer, 1972— Continued 



Manuf actuiers ' identification codes 
(according to list in table 3) 



PLASTICIZERS, ACYCLIC--Continued 

Epoxidized esters: 

Butyl epoxytallate 

Epoxidized linseed oils 

*Epoxidized soya oils 

Epoxidized tall oils 

*2-Ethylhexyl epoxytallates 

Octyl epoxystearates 

*Octyl epoxytallates 

All other epoxidized esters 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Myristic acid esters: *Isopropyl myristate 

*01eic acid esters: 

2-Butoxyethyl oleate 

•Butyl oleate 

Decyl oleate 

Glyceryl trioleate (Triolein) 

Isobutyl oleate 

*Isopropyl oleate 

*Methyl oleate 

♦Propyl oleate 

Palmitic acid esters; 

2-Ethylhexyl palmitate 

Isobutyl palmitate 

Iso-octyl palmitate 

*lsopropyl palmitate 

*Phosphoric acid esters: 

Tri(2-butoxyethyl) phosphate 

Tri (2 - ch loroethy 1 ) phosphate 

Tri (2-chloropropyl) phosphate 

Triethyl phosphate 

Trioctyl phosphate 

All other phosphoric acid esters 

Ricinoleic and acetylricinoleic acid esters: 

n- Butyl acetylricinoleate 

Butyl ricinoleate r 

•Glyceryl monoricinoleate 

Glyceryl tri (acetyl ricinoleate) 

Methyl ricinoleate 

All other ricinoleic and acetylricinoleic acid esters- 
*Sebacic acid esters: 

Dibutoxyethyl sebacate 

•Dibutyl sebacate 

*Di(2-ethylhexyl) sebacate 

Di iso-octyl sebacate 

•Stearic acid esters: 

Butoxyethyl stearate 

•n- Butyl stearate 

Dimethyl ammonium stearate 

Dodecyl (lauryl) stearate 

2-Ethylhexyl stearate 

Glyceryl triacetyl stearate 

Hexadecyl stearate 

2-Hydroxypropyl stearate 

Isobutyl stearate 



ASH. 

ASH . 

ASH, 

RH. 

ASH, 

WTC. 

RH, 

EMR, 

EKT. 

EMR. 

EMR. 

ARC, 



FMP, NIL, RH, UCC, WRC, WTC. 
NTL, UCC. 



TEK, UCC, WTC. 
RH. 



SBC, TCH, WM, WTH. 



ARC, HAL. 

ARC, EMR, HAL, WM, WTC, WTH. 

VND. 

EMR, GLY, WM. 

DA. 



EMR, 


WM. 








CHL, 


DA, 


EMR, 


HUM. 




CHL, 


EMR 


WM. 






WTH. 










ARC, 


DA. 








RUB. 










ARC, 


SBC 


TCH 


WM, 


WTH. 


FMP. 










SFS 


UCC 








SFS. 










EKT. 










UCC 










SFS, 


SM 








NTL. 










NTL. 


RCI 








DA, 


GLY, 


HAL, 


NTL. 




NTL 










NTL 










NTL. 










HAL 


RCI 








EKT 


GRH 


RCI 


RH, 


USS, WTH 


GRH 


PFZ 


RCI 


RH, 


WTH. 


DA, 


RCI. 









ARC, ASH, CHL, DA, EMR, GRO, RUB, SCP, TCH, WM, WTH. 

RH. 

RCI. 

FMP, SCP. 

NTL. 

SCP. 

WTH. 

ARC, DA, WM. 



PLASTICIZERS 
TABLE 2,— Plasticizers for which U.S. production or sales were reported, identified by 

MANUFACTURER, 1972--CoNTINUED 



Chemical 


Manufacturers' identification codes 
(according to list in table 3} 


PLASTICIZERS, ACYCLIC--Continued 
♦Stearic acid esters--Continued 


HK. 

HK. 

CHL. 

ARC. DA, HPC, TCH, WM. 

ARC, EKT. 

UCC. 

RUB. 

HAL, PVO, RUB, WM. 

UCC. 

UCC. 

RUB. 

EKX. 

EMR, HAL, HPC, SCP, SM, WTH. 




th 1 r 


An ^th^ eara e 


S t r ' h t t 


< 


Triethylene glycol dicaprylate 


T ^ th^i^"^ & y^o ,^ J^^''^?' .ft^t'^^^t^l^ 


Triethylene glycol di (2-ethylhexanoate) 









SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3.--PLASTICIZERS; Directory of manufacturers^ 1972 

ALPHABETICAL DIRECTORY BY CODE 

[Names of plasticizers manufacturers that reported production or sales to the U.S. Tariff Commission for 1972 are 
listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACC 


Amoco Chemicals Corp. 


NEV 


Neville Chemical Co. 


ACP 


Allied Chemical Corp., Plastics Div. 


NTL 


NL Industries, Inc. 


ACY 


American Cyanamid Co. 






ARC 


Armak Co . 


ORO 


Chevron Chemical Co. 


ASH 


Ashland Oil, Inc., Ashland Chemical Co. Div. 










PFZ 


Pfizer, Inc. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 


PVO 


PVO International, Inc. 






RCI 


Reichhold Chemicals, Inc. 


CCA 


Cincinnati Milacron Chemicals, Inc. 


RH 


Rohm & Haas Co. 


CHL 


■ Chemol , Inc. 


RUB 


Hooker Chemical Corp. , Ruco Div. 


CO 


Continental Oil Co. 






COM 


Commercial Solvents Corp. 


SBC 


Scher Brothers, Inc. 


CPS 


CPS Chemical Co. 


SCP 


Henkel, Inc. 






SFS 


Stauffer Chemical Co., Specialty Chemical 


DA 


Diamond Shamrock Corp. 




Div. 


DOW 


Dow Chemical Co. 


SM 


Mobil Oil Corp., Mobil Chemical Co. Div., 
Industrial Chemical Div. 


EK 


Eastman Kodak Co. : 


SW 


Sherwin-Williams Co. 


EKT 


Tennessee Eastman Co. Div. 






EKX 


Texas Eastman Co. Div. 


TCC 


Tanatex Chemical Corp. 


EMR 


Emery Industries, Inc. 


TCH 


Emory Industries, Inc., Trylon Chemicals Div. 


ENJ 


Enjay Chemical Co. 


TEK 


Teknor Apex Co. 






TKL 


Thiokol Chemical Corp. 


FMP 


FMC Corp., Organic Chemicals Div. 










UCC 


Union Carbide Corp. 


GLY 


Glyco Chemicals, Inc. 


USS 


USS Chemicals Div. of U.S. Steel Corp. 


GRH 


W.R. Grace S Co., Hatco Chemical Div. 






GRO 


Millmaster Onyx Corp., A. Gross § Co., Div. 


VEL 


Velsicol Chemical Corp. 






VND 


Van Dyk 6 Co . , Inc. 


HAL 


C. P. Hall Co. of Illinois 






HK 


Hooker Chemical Corp. 


WM 


Wilson Pharmaceutical ti Chemical Corp., 


HPC 


Hercules, Inc. 




Wilson-Martin Div. 


HUM 


Kraftco Corp., Humko Plastics Div. 


WRC 


Ventron Corp., Wood Ridge Chemical 






WTC 


Witco Chemical Co., Inc. 


KF 


Kay-Fries Chemicals, Inc. 


WTH 


Union Camp Corp., Harchem Div. 


LAK 


Lakeway Chemicals, Inc. 






MON 


Monsanto Co. 






MTR 


Sobin Chemicals, Inc., Montrose Chemical Div. 






Not 


5. --Complete names and addresses of the above report 


ing comn 


inies are listed in Table 1 of the Aonendix. 



161 



SURFACE-ACTIVE AGENTS 



The surface-active agents included in this report are organic chemicals 
that reduce the surface tension of water or other solvents and are used 
chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or 
wetting agents in either aqueous or nonaqueous systems. Waxes and products 
used chiefly as plasticizers are excluded. Surface- active agents are pro- 
duced from natural fats and oils; from si Ivi chemicals such as lignin, rosin, 
and tall oil; and from chemical intermediates derived from coal tar and 
petroleum. A major part of the output of the bulk chemicals shown in this 
report is consumed in the form of packaged soaps and detergents for house- 
hold and industrial use. The remainder is used in the processing of textiles 
and leather, in ore flotation and oil-drilling operations, and in the manu- 
facture of agricultural sprays, cosmetics, elastomers, foods, lubricants, 
paints, pharmaceuticals, and many other products. 

Table 1 shows statistics for production and sales of surface-active 
agents grouped by ionic class and by chemical class and subclass; table 
2 lists these products and identifies the manufacturers.^ All quantities 
are reported in terms of 100-percent organic surface-active ingredient 
and thus exclude all inorganic salts, water, and other diluents. Sales 
statistics reflect sales of bulk surface-active agents only; sales of 
formulated products are excluded. 

Total U.S. production of surface-active agents in 1972 amounted to 
4";039 million pounds, or 5.5 percent greater than the 3,828 million pounds 
reported for 1971. Sales of bulk surface-active agents in 1972 amounted 
to 2,258 million pounds, valued at $451 million, compared with sales in 
1971 of 2,186 million pounds, valued at $422 million. In terms of quantity, 
sales in 1972 were thus 3.3 percent larger than in 1971; in terms of value, 
sales in 1972 were 6.7 percent larger than in 1971. 

Production of anionic surface-active agents in 1972 amounted to 2,747 
million pounds, or 68.0 percent of the total output reported for 1972 and 
5.9 percent greater than the anionic output reported for 1971. Sales of 
anionics in 1972 amounted to 1,274 million pounds, valued at $195 million. 
Of the total anionic output, 894 million pounds consisted of potassium and 
sodium salts of fatty, rosin, and tall oil acids, of which 466 million 
pounds was the sodium salt of tallow acids and 131 million pounds was the 
sodium salt of coconut oil acids; 688 million pounds consisted of alkyl- 
benzenesulfonates, of which 364 million pounds was sodium dodecylbenzene- 
sulfonate, 143 million pounds was dodecylbenzenesulfonic acid, and 150 
million pounds was sodium tridecylbenzenesulfonate; 522 million pounds 
consisted of ligninsulfonates, of which 327 million pounds was the calcium 
salt; and 207 million pounds consisted of sulfated ethers. 

Production of nonionic surface-active agents in 1972 amounted to 1,048 
million pounds, or 26.0 percent of the total output reported for 1972 and 



See table 3 for a list of manufacturers and their codes. 



162 

SYNTHETIC ORGANIC CHEMICALS, 1972 



2.7 percent more than the nonionic output reported for 1971. Sales of 
nonionics in 1972 amounted to 787 million pounds, valued at $174 million. 
Of the total nonionic output, 314 million pounds consisted of alkylphenol 
ethoxylates and other benzenoid ethers, of which 178 million pounds was 
nonylphenol ethoxylate; 423 million pounds consisted of alcohol ethoxylates 
and other nonbenzenoid ethers, of which 324 million pounds was mixed linear 
alcohol ethoxylate; 102 million pounds consisted of glycerol esters; and 
88 million pounds consisted of alkanol amides. 

Production of cationic surface-active agents in 1972 amounted to 229 
million pounds, or 5.7 percent of the total output reported for 1972 and 
12.9 percent greater than the cationic output reported for 1971. Sales of 
cationics in 1972 amounted to 183 million pounds, valued at $72 million. 
Of the total cationic output, 60 million pounds consisted of quaternary 
ammonium salts not containing oxygen, and 68 million pounds consisted of 
amines not containing oxygen. 

Production of amphoteric surface- active agents in 1972 amounted to 
14.4 million pounds, or 0.4 percent of the total output reported for 1972 
and 45.8 percent greater than the amphoteric output reported for 1971. Sales 
of amphoterics in 1972 amounted to 14.1 million pounds, valued at $9.4 
million. 

The difference between production and sales reflects inventory changes 
and captive consumption of soaps and surface- active agents by synthetic 
rubber producers, and by manufacturers of cosmetics, packaged detergents, 
bar soaps, and other formulated consumer products. In some instances the 
difference may also reflect quantities of surface- active agents used as 
chemical intermediates, e.g., nonionic alcohol and alkylphenol ethoxylates 
which may be converted to anionic surface- active agents by phosphation or 
sulfation. 



SURFACE-ACTIVE AGENTS 
TABLE 1,— Surface-active agents: U.S. production and sales. 1972 



[Listed below are all surface-active agents for which reported data on production or sales may be published. (Leaders 

(...3 are used where the reported data are accepted in confidence and may not be published or where no data were 

reported.) Table 2 lists all surface-active agents for which data on production or sales were reported and identi- 
fies the manufacturers of each] 



Production 



Sales^ 



Quantity' 



Grand total 

Benzenoid 

Nonbenzenoid 

Amphoteina Surface-Active Agents 

Total 

Anionic Surface-Active Agents 

Total 

Carboxylic acids (and salts thereof), total 

Amine salts of fatty rosin, and tall oil acids 

Carboxylic acids having amide, ester, or ether linkages 

total 

N-Lauroylsarcosine, sodium salt 

All other 

Potassium and sodium salts of fatty, rosin, and tall 

acids, total 

Castor oil acids, potassium salt 

Coconut oil acids, potassium and sodium salts, total- 
Potassium salt 

Sodium salt 

Corn oil acids, potassium and sodium salts 

Mixed vegetable oil acids, potassium salt 

Oleic acid, sodium salt 

Palm oil acids, sodium salt 

Soybean oil acids, potassium and sodium salts 

Stearic acid, potassium and sodium salts 

Tall oil acids, potassium salt 

Tall oil acids, sodium salt 

Tallow acids, sodium salt 

All other 

Phosphoric and polynhosphoric acid esters (and salts 

thereof^i total 

Alcohols ana phenols, ethoxylated and phosphated, total 

Dinonylphenol, ethoxylated and phosphated 

Mixed linear alcohols, ethoxylated and phosphated 

Nonylphenol, ethoxylated and phospnated 

Phenol, ethoxylated and phosphated 

Tridecyl alcohol, ethoxylated and phosphated 

All other 

Alcohols, phosphated or polyphosphated, total 

2-Ethylhexyl phosphate, sodium salt 

All other 

Sulfonic acids (and salts thereof), total 

Alkylbenzenesulfonates, total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, isopropylamine salt 



1,000 
pounds 



1,119,229 
2,919,558 



907,011 



12,711 
3,823 



142,944 

11,825 

131,119 

801 

2,814 

1,473 

714 

982 

19,543 

10,720 

465,550 

247,988 



26.514 



18,028 

759 

3,602 

7,410 

728 

1,412 

4,117 

8,486 

447 

8,039 



688,176 

143,391 

12,412 

2,221 



1,000 
pounds 



2.257.546 



1,000 
dollars 



4S0.768 



547,259 
1,710,287 



444 
9,300 
9,300 

48 



787 
2,841 

229 
643 
528 

16,782 
2,561 

10,258 



3,434 
6,101 

1,094 
4,197 
6,204 

6,204 

774,160 



174,613 

50,823 

9,500 

5,425 



111,093 
339,675 



148 
6,213 
6,213 

10 



287 
2,576 

37 
131 
162 

3,779 
348 

1,263 



9,509 



1,520 
1,923 

428 
2,319 
3,319 

3,319 

78,386 



32,317 
7,100 
4,098 
1,068 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE L— Surface-active agents; U.S, production and sales^ 1972--Continued 



Production ' 



Sales'^ 



Quantity 



Anionic Surface-Aative jJgents--Continued 

Sulfonic acids (and salts thereof ) --Continued 
A 1 ky 1 ben zenesulfonates- -Continued 

Dodecylbenzenesulfonic acid, (mixed alkyl)amine 

salt 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, triethanolamine salt 

Tridecylbenzenesulfonic acid, sodium salt 

All other 

Benzene-, cumene-, toluene-, and xylenesulfonates , 

total 

Cumenesulfonic acid, ammonium salt 

Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, sodium salt 

All other 

Ligninsulfonates, total 

Ligninsulfonic acid, calcium salt 

Ligninsulfonic acid, sodium salt 

All other 

Naphthalenesulfonates, total 

Butylnaphthalene sulfonic acid, sodium salt 

All other 

Sulfonic acids having amide li.ikages. total 

Sulfosuccinic acid derivatives 

Taurine derivatives 

Sulfonic acids having ester or ether linkages, total 

Sulfosuccinic acid esters, total 

Sulfosuccinic acid, bis(2,6.-dimethyl-4-heptyl) 

ester, sodium salt 

Sulfosuccinic acid, .bis (2-ethylhexyl) ester, sodium 

salt 

All other 

Other sulfonic acids having ester or ether linkages 

All other sulfonic acids 

Sulfuric acid esters (and salts thereof), total 

Acids, amides, and esters, sulfated, total 

Coconut oil acids - ethanolamine condensate, sulfated, 
potassium salt 

Esters of sulfated oleic acid, total 

Butyl oleate, sulfated, sodium salt 

Isopropyl oleate, sulfated, sodium salt 

Propyl oleate, sulfated, sodium salt 

All other 

■;leic acid, sulfated, disodium salt 

Other acids, amides, and esters, sulfated 

Alcohols, sulfated, total 

Decyl sulfate, sodium salt 

Dodecyl sulfate salts, total 

Dodecyl sulfate, ammonium salt 

Dodecyl sulfate, magnesium salt 

Dodecyl sulfate, sodium salt 

Dodecyl sulfate, triethanolamine salt 

All other 

Other alcohols sulfated 

Ethers, sulfated, total 

Alkylphenols, ethoxylated and sulfated, total 

Nonylphenol, ethoxylated and sulfated, sodium salt-- 
All other 

Dodecyl alcohol, ethoxylated and sulfated, ammonium 
salt 



pounds 



121 
364,067 

6,905 
149,870 

9,489 



64,009 

3,750 

4,962 

57,409 

17,908 

522.323 

526,626 

58,662 

157,055 

7,508 

501 

7,207 

4,954 
1,526 
5,428 
41,828 
16,060 

559 

12,387 
5,114 

25,768 
5,514 



5,015 

1,540 

520 

255 

2,718 

12,221 





545 


26 


841 


16 


050 


17 


552 


206 


980 



1,000 
pounds 



89,867 

7,795 



54,751 
5,714 

28,289 

22,728 

505,981 

507,655 

61,094 

137,232 

7,005 

297 

6,708 



1,132 

1,668 

23,781 

11,987 



2,757 
11,794 



18,571 

29 

4,824 

1,589 

434 

227 

2,574 

11,865 

1,855 

44,107 

192 

34,169 

2,670 

20,433 

11,066 
9,746 
125,790 
5,786 
311 
3,475 

2,657 



1,000 
dollars 



15,606 
1,725 



2,722 



5 


211 




425 


'2 


600 


2 


186 


18 


699 


7 


688 


6 


038 


4 


973 


2 


657 



1,393 
15,379 
6,935 



5,500 
1,435 
8,444 



4,379 



150 
101 



14,845 
1,551 

8,595 

4,917 
3,492 
21,404 
1,155 
71 
1,084 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE 1. --Surface-active agents: U.S. production and sales, 1972--Continued 



Anionic Sup face- Active ^^ewts- -Continued 

Sulfuric acid esters (and salts thereof) --Continued 
Ethers, sul f at ed--Cont inued 

Dodecyl alcohol, ethoxylated and sulfated, sodium 

salt 

Mixed linear alcohols, ethoxylated and sulfated, 

ammonium salt 

Mixed linear alcohols, ethoxylated and sulfated, sodium 

salt 

All other 

Natural fats and oils, sulfated, total 

Castor oil, sulfated, sodium salt 

Coconut oil, sulfated, sodium salt 

Cod oil, sulfated, sodium salt 

Herring oil, sulfated, sodium salt 

Lard oil, sulfated, sodium salt 

Mixed fish oils, sulfated, sodium salt 

Neat's-foot oil, sulfated, sodium salt 

Peanut oil, sulfated, sodium salt 

Ricebran oil, sulfated, sodium salt 

Soybean oil, sulfated, sodium salt 

Sperm oil, sulfated, sodium salt 

Tallow, sulfated, sodium salt 

All other 

Other anionic surface-active agents^ 

Cationio Surface-Active Agents 

Total 

Amine oxides and oxygen-containing amines (except those 

having amide linkages), total 

Acyclic, total 

(Coconut oil alkyl)amine, ethoxylated 

(Tallow alkyl)amine, ethoxylated 

All other 

Cyclic (except imidazoline and oxazoline derivatives) 

Imidazoline and oxazoline derivatives, total 

2-Heptadecyl-l- (2-hydroxyethyl)-2-imidazoline 

1- (2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2- 

imidazoline 

1- (2-Hydroxyethyl)-2-nor(tall oil alkyl)-2-imidazoline-- 
All other 

Amines and amine oxides having amide linkages, total 

Carboxylic acid - diamine and polyamine condensates , total- 
Mixed fatty acids - polyalkylenepolyamine condensate 

Tall oil acids - diethylenetriamine and polyalkylene 

polyamine condensate 

All other 

Other amines and amine oxides having amide linkages 

Amines, not containing oxygen (and salts thereof), total 

Amine salts 

Diamines and polyamines, total 

N- (Coconut oil alkyl)trimethylenediamine 

Imidazoline derivatives 

N- (9-0ctadecenyl)trimethylenediamine 

All other 

Primary monoamines, total 

(Hydrogenated tallow alkyl)amine 

9-Octadecenylaraine 

Octadecylamine 

(Tallow alkyl) amine 

All other 



Production i 



1,000 
pounds 



8 


965 


103 


763 


87 


358 


38 


526 


8 


271 


1 


023 


2 


028 




869 




255 


4 


256 



50,623 



45,731 
4,368 
2,191 

39,172 

1,778 

3,114 

266 

444 

791 

1,613 



22,839 
2,308 

17,764 
2,767 
4,830 

67,675 



3,112 

13,383 

430 

2,590 

2,342 

8,021 

27,910 

3,789 

4,866 

541 

5,225 

13,489 



1,000 



17.557 

93,732 

37,233 

8,311 

925 

2,001 

860 

245 

2,573 

69 

53 

141 

1,338 

10,000 

10,717 

204,887 



23,841 



19,113 
3,985 
1,913 

13,215 

1,964 

2,764 

235 

523 

337 

1,669 



22,006 



17,474 
4,532 
3,493 



2,102 
12,240 
465 
1,904 
2,243 
7,628 
27,708 
3,729 
4,113 

5,522 
14,344 



1,000 
do I laps 



3,068 



3,326 

13,298 

8,293 

2,654 

243 

289 

125 



1,538 
2,409 



10,229 



8,291 
1,362 

830 
6,099 

574 
1,364 

123 

269 
132 
840 



2,427 
2,640 
2,158 



782 

3,444 

220 

548 

868 

1,808 

9,742 

1,175 

1,565 

1,481 
5,521 



See footnotes at end of table 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 1. --Surface-active agents: U.S. ppoduction and sales, 1972--Continued 



Production 



Quantity 



Cationic Surface-Active /Ijents- -Continued 

Amines, not containing oxygen (and salts thereof)-- 
Continued 

Secondary and tertiary monoamines, total 

6is(hydrogenated tallow alkyljamine 

N,N-Dimethyldodecylamine 

N,N-Dimethylhexadecylamine 

N,N-Dimethyloctadecylamine 

N-Methylbis(hydrogenated tallow alkyljamine 

All other 

Oxygen-containing quaternary ammonium salts 

Quaternary ammonium salts, not containing oxygen, total 

Acyclic, total 

Bis (coconut oil alkyl}dimethylammonium chloride 

Bis (hydrogenated tallow alkyl)dimethylammonium chloride-- 

Hexadecyltrime thy 1 ammonium chloride 

Trimethyl (tallow alkyl) ammonium chloride 

All other 

Benzenoid, total 

Benzyl (coconut oil .alkyl)dimethylammonium chloride 

Benzyldimethvl (mixed alkyll ammonium chloride 

Benzy 1 dimethyl DC tad ecyl ammonium chloride 

Benzyl trimethyl ammonium chloride 

All other 

Groups listed above for which separate sales data may not be 
shown' 

Nonicmic Surface-Active Agents 

Total 

Carboxylic acid amides, total 

Diethanolamine condensates (amine/acid ratio=2/l), total — 

Capric acid 

Coconut oil acids 

Coconut oil and tallow acids 

Laurie acid 

Oleic acid 

Stearic acid 

Tall oil acids 

All other 

Diethanolamine condensates (other amine/acid ratios), 

total 

Coconut oil acids (amine/acid ratio=l/l) 

Laurie acid (amine/acid ratio=l/l) 

Oleic acid (amine/acid ratio=l/l) 

Stearic acid (amine/acid ratio=l/l) 

All other 

Ethanolamine and isopropanolamine condensates, total 

Coconut oil acids - ethanolamine condensate 

(amine/acid ratio=2/l) 

Coconut oil acids - ethanolamine condensate 

(amine/acid ratio=l/l) 

All other 

Carboxylic acid esters, total 

Anhydrosorbitol esters, total 

Anhydrosorbitol monoester of tall oil acids 

Anhydrosorbitol monolaurate 

Anhydrosorbitol monopa Imitate 

Anhydrosorbitol monostearate 

All other 



1,000 
pounds 



21, no 

586 

552 

1,513 

2,233 

18,386 

23,233 

59,876 



1,000 



45,451 

3,273 

31,383 

904 

866 

9,025 

14,425 

434 

6,068 

1,580 

6,343 



26,477 

84 

15,361 

3,029 

2,020 

932 

827 

413 

3,811 



11,359 

11,737 



24,667 
231 
5,926 
2,042 
7,946 
8,522 



454 

477 

588 

1,291 

2,150 



51,953 



39,708 

2,956 

28,322 

874 

780 

6,776 

12,245 

409 

6,098 

239 
5,499 



60,044 



21,043 

147 

13,643 

2,258 

417 

724 

781 

73 

3,000 



1,122 



3,298 
5,167 



193.630 



15,761 
149 
3,512 
1,536 
4,011 
6,553 



1,000 
do I lars 



112 
288 
332 
639 
598 



23,962 



14,039 

1,204 

7,004 

685 

409 

4,737 

9,923 

274 

5,233 



17,686 



6,444 

57 

4,206 

494 

160 

227 

359 

22 

919 



36,676 


29,414 


8,470 


21,462 


19,131 


4,786 


10,344 






424 


315 


96 


540 






3,906 


9,968 


3,588 


24,564 


9,587 


2,772 



5,538 
41 
1,335 
480 
1,332 
2,350 



SURFACE-ACTIVE AGENTS 
TABLE 1.— Surface-active agents: U.S. production and sales. 19/2— Continued 



Quantity ' 



1,000 



Nonionia Surface-Active Agents --Continuei 

Carboxylic acid esters--Continued 

Diethylene glycol esters, total 

Diethylene glycol distearate 

Diethylene glycol monolaurate 

Diethylene glycol monostearate 

Diethylene glycol sesqullaurate 

All other 

Ethoxylated anhydrosorbitol esters, total 

Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol tristearate 

All other 

Ethylene glycol esters 

Glyceral esters, total 

Complex glycerol esters 

Glycerol esters of chemically defined acids, total 

Glycerol monolaurate 

Glycerol mono-oleate 

Glycerol monoricinoleate 

Glycerol monostearate 

All other 

Glycerol esters of mixed acids, total 

Glycerol monoester of hydrogenated cottonseed oil 

aeids 

Glycerol monoester of hydrogenated soybean oil acids- 
All other 

Natural fats and oils, alkoxylated, total 

Castor oil, ethoxylated 

Hydrogenated castor oil, ethoxylated 

All other 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined acids, 

total 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of rosin and tall oil acids- 
Polyethylene glycol esters of other mixed acids, total- 
Polyethylene glycol sesquiester of coconut oil acids- 
All other 

Polyglycerol esters 

Propanediol esters, total 

1 , 2- Propanediol monostearate 

All other 

Other carboxylic acid esters 

Ethers, total 

Benzenoid ethers, total 

Alkylphenol - formaldehyde condensates, alkoxylated 

Dodecylphenol, ethoxylated 

Nonylphenol, ethoxylated 

All other 

Nonbenzenoid ethers, total 

Linear alcohols, alkoxylated, total 

Decyl alcohol, ethoxylated 

Dodecyl alcohol, ethoxylated 

Hexadecyl alcohol, ethoxylated 

Mixed linear alcohols, ethoxylated 

Mixed linear alcohols, ethoxylated and propoxylated-- 

9-Octadecenyl alcohol, ethoxylated 

Octadecyl alcohol, ethoxylated 

All other 



2.098 

452 

52 

450 

354 

790 

25,075 

7,023 

5,436 

2,536 

10,080 

4,786 

102,320 

6,376 

31,410 

60 

2,768 

83 

27,191 

1,308 

64,534 

4,176 

13,126 

47,232 

11,258 

5,668 

3,736 

1,854 

31,502 

23,435 
1,159 
4,402 
3,838 
3,630 
5,345 
5,061 
6,521 
1,546 
395 
1,151 
4,891 
3,573 
2,593 
980 

13,427 

736,911 



313,851 

9,429 

17,352 

177,897 

109,173 

423,060 

358,196 

1,293 

9,175 

1,152 

323,725 

14,687 

2,899 

1,336 

3,929 



1,000 
pounds 



2,002 

421 

54 

409 

347 

771 

21,367 

6,502 

4,609 

10,256 

4,610 

100,498 

5,312 

33,956 

52 

2,355 

75 

29,962 

1,512 

61,230 



14,174 
47,056 
10,169 
4,967 
3,508 
1,694 
23,320 

17,385 
944 
1,196 
3,475 
3,199 
4,680 
3,891 
4,505 
1,430 
414 
1,016 

1,909 

1,481 

428 

13,994 

533.185 



272,514 
3,032 

17,223 
163,099 

89,160 
260,671 
210,442 

7,722 

664 

183,363 

11,779 

2,485 

372 

4,057 



1,000 
dollar's 



653 

126 

19 

128 

110 

270 

8,143 

2,422 

1,856 

3,865 

1,296 

25,437 

1,846 

6,823 

22 

768 

44 

5,295 

694 

16,768 



4,124 
12,644 
2,908 
1,607 
835 
466 
8,231 

6,624 

336 

401 

1,257 

1,110 

1,990 

1,530 

1,122 

485 

179 

306 

678 

554 

124 

4,014 



99.823 
47,649 

722 
2,491 
24,857 
19,579 
52.174 
36,528 

1,667 

298 

28.451 

2,459 

1,661 
256 

1,736 



SYNTHETIC ORGANIC CHEMICALS- 1972 ■ 
TABLE 1, --Surface-active agents: U,S, production and sales. 1972 --Continued 



1,600 
dollars 



15,646 

974 



Unit 
value' 



Per 
povnd 



Nonionio Surface-Active Agents --Continued 

Ethers - -Cont inued 

Nonbenzenoid ethers — Continued 

Other ethers and thioethers, total 

Tridecyl alcohol, ethoxylated 

Trimethylnonyl alcohol, ethoxylated 

All other' 



1,000 
pounds 



64,864 
4,501 
2,145 



1,000 
pounds 



50,229 
3,569 



$0.31 
.27 



1 All quantities are given in terms of 100 percent organic surface-active ingredient. 

2 Sales include products sold as bulk surface-active agents only. 

3 Calculated from rounded figures. 

'' The term "benzenoid," used in this report, describes any surface-aciive agent, except lignin derivatives, whose 
molecular structure includes 1 or more 6-membered carbocyclic or heterocyclic rings with conjugated double bonds 
(e.g., the benzene ring or the pyridine ring). 

^ Includes ligninsulfonates. 

^ Includes production of ''all other" sulfated alcohols; also includes sales of "all other" potassium and sodiiun salts 
of fatty, rosin, and tall oil acids. 

' Includes "all other" secondary and tertiary monoamines not containing oxygen (and salts thereof) and all oxygen-con- 
taining quaternary ammonium salts. 

^ Includes ethoxylated sorbitol esters and miscellaneous esters 

' Includes "other" nonionic surface-active agents. 



SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972 

[Surface-active agents for which separate statistics are given in table 1 are marked with an asterisk (*) ; products 

not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be 

published. Manufacturers' identification codes shouTi belov; are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 31 



Amphoteric Surfaae-Aative Agents 

Acyclic: 

Alkylbetaine 

Cl-Carboxyheptadecyl) trimethylammonium hydroxide , 

inner salt. 
CCarboxymethyl) [3- (coconut oil araido)propyl]dimethyl- 

ammonium chloride, ammonium salt. 
(Carboxymethyl) [3- (coconut oil amido)propyl]di- 

me thy 1 ammonium chloride, sodium salt. 
(Carboxymethyl) [3- (coconut oil amido)r)ropyl]dimethyl- 

ammonium hydroxide, inner salt. 
(l-Carboxyundecyl)trimethylammonium hydroxide, inner 

salt. 

N-(Coconut oil alkyl)-6-alanine, sodium salt 

N-(Coconut oil alkyl)-6-alanine , partial sodium salt-- 
3-[ (Coconut oil alkyl)amino]butyric acid, sodium 

salt. 
N-(2-Coconut oil ajnidoethyl)-N-(2-hydroxyethyl)- 

glycine, sodium salt. 

N-(Dodecyl and tetradecyl)-8-alanine 

N-(Dodecyl and tetradecyl)-6-alanine, triethanolamine 

salt. 

N-Dodecyl-3-iminodipropionic acid 

N-Dodecyl-3-iminodipropionic acid, disodium salt 

Mixed acyclic primary amines, ethoxylated and 

sulfated, sodium salt. 

(Mixed alkyDsulfobetaine 

Mixed fatty betaines 

Oleic acid - ethylenediamine condensate, propoxylated 

and sulfated, sodium salt. 
N'-(Tallow alkyl)-3-iminodipropionic acid, disodium 

salt. 

All other acyclic 

Cyclic: 

1 , 1-Bis (carboxymethyl) -2-undecyl-2-imidazoliniura 

hydroxide, disodium salt. 
l-Carboxymethyl-2-heptadecyl-l- (2-hydroxyethyl) -2- 

imidazolinium hydroxide, sodium derivative, sodium 

salt. 
l-Carbox^ethyl-l- (2-hydroxyethyl) -2-nonyl-2-imid- 

azolinium hydroxide, sodium derivative, sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-imdecyl-2- 

imidazolinium hydroxide, sodium derivative, 

sodium salt. 
Heptadecylmethylbenzimidazolinesulfonic acid, 

sodium salt . 
3- [2- (2-Undecyl-2-imidazolin-l-yl}ethoxy] -propionic 

acid, sodium salt. 



DUP. 
DUP. 



VAC . 
DUP. 



CNM, VAC. 

GNU. 

ARC. 



GNU. 




GNM. 




GNU. 




GNM. 




RH. 




DUP, 


TXT. 


TXT. 




S. 




FNX, 


GNfl. 


SEY, 


X. 


MIR, 


live. 


MIR, 


m'c. 



MIR, TCII, UVC, VAC. 

CGY. 
UVC. 



SYNTHETIC ORGANIC CHEMICALS. 1972- 
TABLE 2. --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic; Surface-Active Agents 

*Carboxylic acids (and salts thereof): 

*Amine salts of fatty, rosin, and tall oil acids: 

Coconut oil acids, diethanolamine salt 

Coconut oil acids, triethanolainine salt 

Laurie, myristic, palmitic, and stearic acids, tri- 
ethanolamine salt. 

Oleic acid, n-butylamine salt 

Oleic acid, triethanolainine salt 

Stearic acid, N,N,N',N'-tetrakis (2-hydroxyethyl) - 
ethylenediamine salt. 

Stearic acid, triethanolainine salt 

Tall oil acids, diethanolamine salt 

Tallow acids, triethanolamine salt 

*Carboxylic acids having amide, ester, or ether 
linkages : 

Butoxyethoxypropi oni c aci d 

N-CCoconut oil acyl)sarcosine, sodium salt 

Diisobutylene - maleic anhydride copolymer, 
ammonium and sodium salts. 

Epoxidized oleic acid, ammonium salt 

*N-Lauroylsarcosine , sodium salt 

N-(Mixed alkylsulfonyl) glycine , sodium salt 

N-Oleoylpolypeptide, sodium salt 

N-Oleoylsarcosine, sodium salt 

Phthalic acid, octadecyl ester, potassium salt 

Stearoyl-2-lactylic acid 

Tridecyloxypoly(ethyleneoxy) acetic acid, sodium 
salt. 

Unspecified sarcosine derivatives 

All other 

*Potassium and sodium salts of fatty, rosin, and 
tall oil acids: 

Animal grease, sodium salt 

*Castor oil acid, potassium salt 

Castor oil acid, sodium salt 

Cocoa butter acids, sodium salt 

*Coconut oil acids, potassium and sodium salts: 
*Potassiura salt 

*Sodium salt 

Coconut oil and tallow acids, sodium salt 

*Com oil acids, potassium and sodium salts: 

Potassium salt 

Sodium salt , 

Laurie acid, potassium salt 

Laurie and myristic acids 

Mixed fish oil acids, sodium salt 

*Mixed vegetable oil acids, potassium salt 

Oleic acid, potassium salt 

*01eic acid, sodium salt 

Olive oil acids, sodium salt 

Palm kernel acids, sodium salt 

*Palm oil acids, sodium salt 

Peanut oil acids, potassium salt 

Peanut oil acids, sodium salt 

Rosin acids, potassium salt 

Rosin acids, sodium salt 



SOP. 
SEP. 
SEP. 



GLY. 

ACE, SOP. 
SEP. 



WC. 
FfflP. 

m. 

SCP. 

CP, IfllP, ONX. 

GAP. 

LUI, X. 

GAP. 

CGY. 

GLY. 

lA'C. 

IIHP. 



NMC. 

NTL, PEK, SEA. 

HEW, HRV, NTL. 

HEW. 



ACE, AES, CON, DA, DYS. ESS, GRC, GRL, HEW, HNT, 

JRG, MCP, NUC, PCH, PEK, PC, SOP, VAL. 
AGP, CON, CP, GRC, HEW, JRG, LEV, NMC, NPR, PG. 
BSW. 



GRC, 

GRC, 

USR. 

PG. 

DA. 

AES, 

AES, 

BSW, 

HEW. 

NMC. 

HEW, 

KAL, 

NMC. 

USR, 

CRT, 



HNT, NMC. 

NMC. 



DYS, GRC, GRL, LUR, PCH, PEK. 
ARL,, DA, DAN, GYR, HNT, SCP, SNW, USR, WEG. 
DA, LEV, LUR, MRV, NUC, USR, WBG, IVTC. 
HNT, LUR. 

LUR, NMC, PRX. 
SLC. 



PRX, SLM, X. 



SURFACE-ACTIVE AGENTS 
TABLE 2. --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic Surfaae- Active Agents — Continued 

*Carboxylic acids (and salts thereof) --Continued 
'Potassium and sodium salts of fatty, rosin, and 
tall oil acids--Continued 

'Soybean oil acids, potassium and sodium salts: 

Potassium salt 

Sodium salt 

'Stearic acid, potassium and sodium salts: 

Stearic acid, potassium salt 

Stearic acid, sodium salt 

•Tall oil acids, potassium salt 

*Tall oil acids, sodium salt 

Tallow acids, potassium salt 

'Tallow acids, sodium salt 

All other 

'Phosphoric and polyphosphoric acid esters (and salts 
thereof) : 
'Alcohols and phenols, ethoxylated and phosphated: 

Butyl alcohol, ethoxylated and phosphated 

'Dinonylphenol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and phosphated 

Dodecylphenol , ethoxylated and phosphated 

2-Ethylhexanol , ethoxylated and phosphated 

Hexylphenol, ethoxylated and phosphated 

Iso-pentyl alcohol, ethoxylated and phosphated 

'Mixed linear alcohols, ethoxylated and phosphated-- 
'Nonylphenol, ethoxylated and phosphated 

Nonylphenol , ethoxylated and phosphated, barium 

salt. 
9-Octadecenyl alcohol, ethoxylated and phosphated-- 

9-Octadecyl alcohol, ethoxylated and phosnhated 

Octylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosnhated. magnesium 
salt. 

'Phenol, ethoxylated and phosphated 

Polyhydric alcohol, ethoxylated and phosphated 

'Tridecyl alcohol, ethoxylated and phosphated 

All other 

'Alcohols, phosphated or polyphosphated: 

Decyl, dodecyl, and octyl phosphate, morpholine 
salt. 

Decyl and octyl phosphate 

Decyl polyphosphate, sodium salt 

2-Ethylhexyl phosphate 

*2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl phosphate, triethanolamine salt 

2-Ethylhexyl polyphosphate 

2-Ethylhexyl polyphosphate, sodium salt 

Hexyl phosphate 

Hexyl phosphate, potassium salt 

Hexyl polyphosphate, potassium salt 

Isooctyl phosphate 

Mixed alkyl phosphate 

Mixed alkyl phosphate, diethanolamine salt 

9-Octadecenyl phosphate 



CON, DYS, HEW, PCH. 
HEW, NHC. 

CON, DYS, HEW, SCO, IJSR, WTC. 

DA, HEW, JRG, IVTC. 

AES, ASY, CON, DYS, ESS, GAP, GRC, GYR, HNT, NMC, 

PEK, PNX, SOP, VAL, x. 
ASY, CON, GRC, GYR, MRV, PRX, SOP, UNP, x. 
AES, ASY, GYR, PG, USR. 
AGP, ASY, BSW, CON, CP, DA, GRC, GYR, HEW, JRG, 

LEV. LUR, NflC, NPR, PG, PRX. 
GYR. 



GAP. 






ARL, GAP 


NLC, TXT, WTC. 




GAP, WIG 


IVTC. 




GAP. 






FNX, WAY 






ICI. 






GAP. 






CHP, CRT 


CST, FNX, GAP, TCH, TXT, WTC, 


WYN. 


ARL, CHP, 


CRT, DEX, GAP, HDG, NLC, SCP, 


SEY, SNW 


SOP, TCC, TXN, TXT, VAC, WAY, WTC. 




GAP. 






GAP. 






GAP. 






ARL, Rll, 


WAY. 




FNX, GAP, 


WTC, X. 




NLC. 






ARL, FNX 


GAP, LUR, NLC, TCC, WAY, WTC. 




GAP, WTC 







DUP, 
WTC. 
WAY. 
CHP, 
SYL. 
TCC, 

X. 

ICI. 
ICI. 
DEX. 
GAF. 
CST, 
DUP. 
DUP. 



PNX, GAF, MRA, SEY, UCC, UVC. 
UVC, X. 



DUP, SFS, TCC. 



SYNTHETIC ORGANIC CHEMICALS. 1972. 
TABLE 2. --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic Surface- Active Agents — Continued 

*Phosphoric and polyphosphoric acid esters (and salts 
thereof) - -Continued 
♦Alcohols, phosphated or polyphosphated--Continued 

Octyl phosphate 

Octyl phosphate, alkylamine salt 

Octyl phosphate, potassium salt 

Octyl polyphosphate 

Octyl polyphosphate, potassium salt 

All other 

♦Sulfonic acids (and salts thereof) : 
*Alkylbenzenesulfonates: 
Dodecylbenzenesulfonates : 
*Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, ammonium salt 

Dodecylhenzenesulfonic acid, butylamine salt 

♦Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, diethanolamine salt- 

Dodecylbenzenesulfonic acid, dimethylamine salt-- 

Dodecylbenzenesulfonic acid, ethylenediamne 

salt. 

Dodecylbenzenesulfonic acid, isopropanolamine 
salt. 

♦Dodecylbenzenesulfonic acid, isopropyl amine salt- 

♦Dodecylbenzenesulfonic acid, (mixed alkyl)amine 
salt. 

Dodecylbenzenesulfonic acid, potassium salt 

♦Dodecylbenzenesulfonic acid, sodium salt 



♦Dodecylbenzenesulfonic acid, triethanolamine 
salt. 
Other alkylbenzenesulfonates : 

Decylbenzenesulfonic acid, sodium salt 

Di dodecylbenzenesulfonic acid 

Didodecylbenzenesulfonic acid, sodium salt 

Pentadecylbenzenesulfonic acid, potassium salt- 

Tridecylbenzenesulfonic acid 

♦Tridecylbenzenesulfonic acid, sodium salt 

Undecylbenzenesulfonic acid 

Undecylbenzenesulfonic acid, ammonium salt 

Undecylbenzenesulfonic acid, sodium salt 

Undecylbenzenesulfonic acid, triethanolamine 
salt. 

All other 

♦Benzene-, cumene- , toluene-, and xylenesulfonates: 

Benzenesulfonic acid, sodium salt 

♦Cumenesulfonic acid, ammonium salt 

Cumenesulfonic acid, sodium salt 

Hydroquinonesulfonic acid, potassium salt 

Toluenesulfonic acid 

Toluenesulfonic acid, potassium salt 

Toluenesulfonic acid, sodium salt 

Xylenesulfonic acid 



TXT. 

DUP, NLC, TXT. 

DUP, SN'W. 

DEX. 

X. 

DUP, TCH, X. 



ACS, ATR, CO, CRT, CTL, EMK, FNX, HLI, ICI, LAK, 

LEV, PIL, PLX, PRX, RCD, STP, TCI, TEN, TXT, WTC. 
ARL, FNX, TXN, IVTC. 
IVTC. 

ICI, NLC, RCD, RH, STP, TMI), IVTC. 
FNX, l^fTC. 
PIL. 
ICI. 

ARD, CTL, l*TC. 

AAC, CHP, CIN, CTL, FNX, ICI, RCD, SNW, STP. 
ECC, FNX, NLC, TCH, IVTC. 

RCD, SOP, STP, VAL. 

AAC, ACS, ARD, ARL, ATR, BLA, CHP, CO, CP, CRT, 
CTL, DA, ECC, HLI, HRT, LEV, NMC, PG, PIL, PLX, 
PRX, QCP, RCD, SOP, STP, TEN, TXT, UCC, WTC. 

AAC, ACS, ARD, ARL, ATR, CIN, CTL, ECC, ESS, FNX, HLI, 
PIL, RCD, SOP, SOS, STP, TXN, WTC. 

LAK. 

CO. 

ATR. 

STP. 

CO, RCD. 

BLA, CO, CP, NPR, PG, RCD, IVTC. 

TXT. 

TXT. 

TXT. 

TXT. 

LISR. 

NES. 

NES, PRX, STP, IVTC. 

NES. 

NES. 

RCD. 

NES, STP, TXN. 

CO, NES, PRX, iirrc. 

HLI. 



SURFACE-ACTIVE AGENTS 



TABLE 2.- 



-Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic Surface-Active Agents — Continued 

*Sulfonic acids (and salts thereof) --Continued 

*Ben2ene-, cumene-, toluene-, and xylenesulfonates — 
Continued 

*Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, potassium salt 

*Xylenesulfonic acid, sodium salt 

*Ligninsulfonates : 

Ligninsulfonic acid, aluminum salt 

Ligninsulfonic acid, ammonium salt 

*Ligninsulfonic acid, calcium salt 

Ligninsulfonic acid, chromium salt 

Ligninsulfonic acid, copper salt 

Ligninsulfonic acid, iron salt 

Ligninsulfonic acid, magnesium salt 

Ligninsulfonic acid, manganeses salt 

*Ligninsulfonic acid, sodium salt 

Ligninsulfonic acid, zinc salt 

All other 

*Naphthalenesulfonates : 

*Butylnaphthalenesulfonic acid, sodium salt 

Dibutylnaphthalenesulfonic acid 

Didodecylnaphthalenesulfonic acid, sodium salt 

Diisopropylnaphthalenesulfonic acid, sodium salt 

Dipentylnaphthalenesulfonic acid, (mixed alkyl)- 
amine salt. 

Dipentylnaphthalenesulfonic acid, sodium salt 

I sop ropy In aphthalene sulfonic acid 

Methylenebis (2 -naphthalene sulfonic acid) 

Methylnaphthalenesulfonic acid, soditim salt 

Methylnonylnaphthalenesulfonic acid, sodium salt 

Tetrahydronaphthalenesulfonic acid, sodium salt 

*Sulfonic acids having amide linkages: 
*Sulfosuccinic acid derivatives: 

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuccinamic 

acid, tetrasodium salt. 
N-(2-Hydroxyethyl)-N- (tallow alkyl)sulfo- 
succinamic acid, disodium salt. 

N-Octadecylsulfosuccinamic acid, disodium salt 

Sulfosuccinic acid, alkanolamide ester, sodium 

salt. 
Sulfosuccinic acid, alkanolamide ester, tri- 

ethanolamine salt. 
Sulfosuccinic acid, 2- (coconut oil amido)ethyl 
ester, disodium salt. 

All other 

*Taurine derivatives; 

N-(Coconut oil acyl)-N-methyltaurine, sodium salt- 

N-Cyclohexyl-N-palmitoyltaurine , sodium salt 

N-Methyl-N-oleoyltaurine, sodium salt 

N-Methyl-N-palmitoyltaurine, sodium salt 

N-Methyl-N- (tall oil acyl) taurine , sodium salt 

N-!lethyl-N- (tallow acyl) taurine, sodium salt 

*Sulfonic acids having ester or ether linkages: 
*Sulfosuccinic acid esters: 

*Sulfossuccinic acid, bis (2 ,6-dimethyl-4-heptyl) 

ester, sodium salt. 
'Sulfosuccinic acid, bis (2-ethylhexyl) ester, 
sodium salt. 



CO, 


HLI, 


NES, 


STP, 


TXN, 


WTC. 


NES 












AIR 


CO, 


HLI, 


ICI, 


NES, 


PIL, 


MAR 












CPP 


CRZ 


SPA 


WV'A 






CRZ 


CWP 


LKY 


MAR 


PSP 


WVA 


MAR 


RAY 










IWA 












CRZ 


m'A 










MAR 


W\'A 










IWA 












CRZ 


MAR 


RAY 


IWA 






IWA 












PSP 












DA, 


ECC, 


PFZ. 








GAP 


S. 










PFZ 












DA, 


GAP, 


PFZ. 









DA, 


DUP, 


GRD. 






DUP 










DA, 


UDI. 








LIDI 










DUP 










ACY, 


MOA 








SCP 










ACY 










HDG 


SCP 








SCP 










LAK 










ACT 










FNX 


GAF 


LIL 


TNI 




GAF 










DA, 


DEP, 


FNX, 


GAF, 


HRT, MCP. 


GAF 










CRT 


FNX 


GAF 


MRA 


WTC. 


GAF 











D/\N, GAF, MOA. 



ACY, CGY, CUP, CRT, CST, DA, DAN, ECC, EMK, FNX, HDG, 
HRT, MCP, MOA, MRA, PC, SBC, SCO, UVC . 



552-743 0-74-12 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 









Manufacturers' identification codes 


Chemical 






(accordi 


ng to list in table 3) 


Anionic Surface- Active Agents — Continued 










♦Sulfonic acids (and salts thereof) --Continued 










'Sulfonic acids having ester or ether linkages-- 










Continued 










*Sulfosuccinic acid esters--Continued 










Sulfosuccinic acid, bis (tallow monoglyceride) 


ACY. 








ester, sodium salt. 










Sulfosuccinic acid, dihexyl ester, sodium salt 


ACY, 


MOA 






Sulfosuccinic acid, diisobutyl ester, sodium 


MOA. 








salt. 










Sulfosuccinic acid, diisodecyl ester, sodium 


MCP. 








salt. 










Sulfosuccinic acid, diisooctyl ester, sodium 


RH. 








salt. 










Sulfosuccinic acid, dipentyl ester, sodium salt 


ACY. 








Sulfosuccinic acid, ditridecyl ester, sodium 


ACY, 


MOA 






salt. 










*Other sulfonic acids having ester or ether 










linkages : 










Coconut oil acids, 2-sulfoethyl ester, sodium 


GAF, 


LEV 


X. 




salt. 










Dodecyldiphenyloxidedisulfonic acid, disodium 


DOW. 








salt. 












ACS. 








uoaecy 1 suiroacetate 




Dodecyl sulfoacetate, sodium salt 


SIP. 










SLfl 








Herring oil, suironateu 

Iso-octylphenol, ethoxylated and sulfonated. 


CRT, 


RH. 






sodium salt. 












SLM. 








All other 

*A11 other sulfonic acids: 








Butylhydroxybiphenylsulfonic acid 


RBC. 








Mixed alkanesulfonic acid, sodium salt 


DUP. 










CP 


LAK, 


NLC, STP. 




Mixed linear aipna oienns, suironateci 

Petroleumsulfonic acid, water soluble (acid layer), 


WTC. 




sodium salt. 










All other 










•Sulfuric acid esters (and salts thereof): 










*Acids, amides, and esters, sulfated: 










•Coconut oil acids - ethanolamine condensate. 


DEX, 


B1K 


ONX. 




sulfated, potassium salt. 










•Esters of sulfated oleic acid: 










2-Butoxyethyl oleate, sulfated, sodium salt 


S. 








Butyl and propyl oleate, sulfated, sodium salt 


^ICP. 








•Butyl oleate, sulfated, sodium salt 


AKS, 


EFH 


ICI, MCP, 


ONX, PC, SEY. 


2-Ethylhexyl oleate, sulfated, sodium salt 


CHP. 








£^]-jyj oleate sulfated sodium salt 


GAF. 
LEA, 








Glyceryl trioleate, sulfated, sodium salt 


MRV 






Isobutyl oleate, sulfated, sodium salt 


DA. 








•Isopropyl oleate, sulfated, sodium salt 


CRT, 


DEX 


FNX, HRT, 


LEA, SCP. 


Methyl oleate, sulfated, sodium salt 


ICI. 








Mixed oleic acid esters, sulfated, sodium salt 


EFH. 








♦Propyl oleate, sulfated, sodium salt 


ACY, 


AKS, 


CHP, MRV. 




•Oleic acid, sulfated, disodium salt 


ACT, 


ACY 


CHP, CRT, 


DA, GAF, LEA, SCO, TEN, IVTC. 


Other acids, amides, and esters, sulfated: 










Castor oil and oleic acid, sulfated, ammonium salt- 


sen. 








Glycerol monoester of coconut oil acids, sulfated 


CP. 








sodium salt. 











SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972— CONT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic Surface- Ac live Agents — Continued 

'Sulfuric acid esters (and salts thereof)--Continued 
*Acid5, amides, and esters, sulfated--Continued 

*Other acids, amides, and esters sulfated--Continued 

9-Octadecenyl acetate, sulfated, sodium salt 

Oleic acid, sulfated, triethanolamine salt 

Tall oil, sulfated, sodium salt 

All other 

'Alcohols, sulfated: 

Coconut and sperm oil alkyl sulfate, sodium salt 

Decyl and octyl sulfate, sodium salt 

♦Decyl sulfate, sodium salt 

3,9-Diethyl-6-tridecyl sulfate, sodium salt 

*Dodecyl sulfate salts: 

2-Amino-2-methylpropanol salt 

'Ammonium salt 

Diethanol amine salt 

Diethylamine salt 

N,N-Diethylcyclohexylamine salt 

Isopropanolamine salt 

'Magnesium salt 

Potassium salt 

'Sodium salt 

'Triethanolamine salt 

2-Ethylhexyl sulfate, sodium salt 

Hexadecyl sulfate, sodium salt 

7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt 

Hexyl sulfate, potassium salt 

Mixed linear alcohol sulfate, ammonium salt 

Mixed linear alcohol sulfate, sodium salt 

Mixed linear alcohol sulfate, triethanolamine 
salt. 

Nonyl sulfate, sodium salt 

9-Octadecenyl sulfate, 2- (diethylamino)ethanol salt- 

Octadecyl sulfate, sodium salt 

Octadecyl sulfate, triethanolamine salt 

Octyl sulfate, sodium salt 

Tridecyl sulfate, sodium salt 

All other 

'Ethers, sulfated: 

'Alkylphenols, ethoxylated and sulfated: 

Nonylphenol, ethoxylated and sulfated, ammonium 
salt. 
'Nonylphenol, ethoxylated and sulfated, sodium 
salt. 
Nonylphenol, ethoxylated and sulfated, tri- 
ethanolamine salt. 
Octylphenol, ethoxylated and sulfated, sodium 
salt. 
'Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt. 
'Dodecyl alcohol, ethoxylated and sulfated, sodium 
salt. 
Dodecyl and tetradecyl alcohols, ethoxylated and 

sulfated, ammonium salt. 
2-Ethylhexanol, ethoxylated and sulfated, sodium 
salt. 

2-Hexyloxypropyl sulfate, sodium salt 

'Mixed linear alcohols, ethoxylated and sulfated 

ammonium salt. 
'Mixed linear alcohols, ethoxylated and sulfated, 
sodium salt. 



DUP. 

KAY. 

APX, BAO, DA, FNX, ICI, SEA, Iffll , IVHW. 

DA, eiR. 

DA, DUP, FNX. 

TCH, IVTC. 

APX, CTL, DUP, HLl, SCP. 

UCC. 

DUP. 

AAC, CTL, HLI, JRG, ONX, PG, RCD, SCP, STP, TCH, WTC. 

DUP, HLl, JRG, ONX, SCP, STP. 

AAC. 

DUP. 

JRG, TCH. 

AAC, HLI, ONX, STP. 

GYR, HLl, PG. 

AAC, CTL, DUP, HLI, JRG, ONX, PG, RCD, SCP, STP, TCH, 

WTC. 
AAC, CTL, DUP, HLI, ONX, PG, RCD, SCP, STP, TCH, TXT. 
AAC, SCP, TCH. UCC. 
AAC, DUP, SCP. 
UCC. 
DEX. 

CP, LAK, NTL, S, SCP, UCC. 
LAK, SCP, SEY, TXT. 
LAK, SCP. 

TEN, TXT. 

AAC. 

DUP, EHK, ONX, PG. 

DUP. 

AAC, DUP. 

AAC, SCP. 

LEV. 



CGY, GAP, .STP, TXT, WTC. 

CRT, DEX, GAF. 

ARL. 

RH. 

AAC, AKS, CTL, STP, TXT, WTC. 

AAC, CTL, HLI, ONX, RCD, SCP, STP, TCH, IVTC. 

LEV, TXN. 

UCC. 

S. 

CO, LAK, NLC, PG, PIL, RCD, SCP, SHC, STP, TXT. 

AAC, CO, DA, LAK, PG, PIL, RCD, SCP, SHC, STP, 
TCI, TXT. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2, --Surface-active agents for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 









Manufacturers ' 


identification codes 


Chemical 






(according to list in table 3) 


Anionic Surface-Aative Agents — Continued 










♦Sulfuric acid esters (and salts thereof) — Continued 










♦Ethers, 5ulfated--Continued 










Sperm oil alcohol, ethoxylated and sulfated, 


DUP, 


WAW 






sodium salt. 










Tridecyl alcohol, ethoxylated and sulfated, sodium 


AAC, 


ARL 


PRX, RCD. 




salt. 










All other 


DUP. 








♦Natural fats and oils, sulfated: 










•Castor oil, sulfated, sodium salt 


ACT, 


ACY 


AKS, APX, ARL 


BAO, BSW, CRT, DA, DEX, EFH, 




FNX, GAP, HRT, ICl, KAL, KNG, LEA, LUR, MCP, MRD, 




MRV, S 


SCO, SCP, SLC 


SLM, WHI, WHIM. 


♦Coconut oil, sulfated, sodium salt 


ACY, 


BAG 


DA, LUR, MRD, 


SEA, SLC, IVHW. 


♦Cod oil, sulfated, sodium salt 


ACT, 


BAO 


SEA, IVHI, WHIV 




Grease, other than wool, sulfated, sodium salt 


SEA, 


mil 






Herring oil, sulfated, ammonium salt 


SCP. 








♦Herring oil, sulfated, sodium salt 


ACT, 


DA, 


SLM, WHI, IVHW. 




♦Lard, sulfated, sodium salt 


CRT, 


FNX 


SLM, WAW. 




Mixed alpha olefins and vegetable oils, sulfated. 


SLM. 








sodium salt. 










Mixed animal and vegetable oils, sulfated, sodium 


SLU. 








salt. 










♦Mixed fish oils, sulfated, sodium salt 


ACT, 


DA, 


MRD, SLM. 




Mustard seed oil, sulfated, sodium salt 


DA, 


LUR. 






♦Neat's-foot oil, sulfated, sodium salt 


ACT, 


BAO 


CRT, DA, KAL, 


LUR, MRD, PC, SEA, SLM, WHW. 


♦Peanut oil, sulfated, sodium salt 


ACY, 


CUP 


DA, LEA, LUR. 




♦Ricebran oil, sulfated, sodium salt 


DA, 


EFH, 


KNG, LUR, SEA, 


WHI. 


♦Soybean oil, sulfated, sodium salt 


CRT, 


HRT 


KAL, MRD, ONX 


WHW. 


♦Sperm oil, sulfated, sodium salt 


ACT, 


CLD 


CRT, DA, FNX, 


KAL, ONX, SCO, SEA, WHI, WHW. 


♦Tallow, sulfated, sodium salt 


ACT, 


ACY, 


BSW, DA, ECC, 


LUR, MCP, MRD, PC, SCP, SID, 




SLM, SnS, IVHI. 




Other anionic surface-active agents: 










Lignin (non-sulfonated) and salts thereof 


1*VA. 








Mixed linear alcohols, ethoxylated and carbonated. 


S. 








sodium salt. 










Polyethylene-vinyl alcohol copolymer, potassium salt 


NLC. 








Tridecyl alcohol, ethoxylated and carbonated. 


S, SEY. 






sodium salt. 










All other 


QCP, 


STC 










Cationia Surface- Active Agents 










♦Amine oxides and oxygen- containing amines (except 










those having amide linkages): 










♦Acyclic: 










N,N-Bis(2-hydroxyethyl) (coconut oil alkyl) amine 


ARC. 








oxide. 












CTL. 














.ARC, 


FIN 


TCH. 








N N-Bis (2-hydroxyethyl) f tal low alkvDamine 


ARC. 












N,N-Bis(2-hydroxyethylKtallow alkyl)amine acetate--- 


PG. 








N,N-Bis(2-hydroxyethyl) (tallow alkyl)amine oxide 


ARC. 










AAC, 


ARC, 


ASH, BRD, ICI 


NLC, TCH, VAC. 




(Coconut oil alkyl)amine, ethoxylated, acetate 


RPC. 








(Coconut oil alkyl) amine, ethoxylated, maleate 


SDH. 








N,N-Dimethyl(coconut oil alkyl)amine oxide 


ARC. 








N,N-Dimethyldecylamine oxide 


BRD. 








N,N-Dimethyldodecylaraine oxide (Lauryl dimethylamine 


BRD, 


X. 






oxide) . 










N,N-Dimethylhexadecyl amine oxide 


ONX. 








N,N-Dimethyl(hydrogenated tallow alkyl)amine oxide — 


ARC. 








Ethylenedi amine, ethoxylated and propoxylated 


ICI. 









SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Catiowic Sui' face- Active Agents — Continued 

*Amine oxides and oxygen-containing amines (except those 
having amide linkages) --Continued 
*Acyclic- -Continued 

(Hydrogenated tallow alkyl) ajnine, ethoxylated 

N-(2-Hydroxyethyl)-N,N' ,N' -tris (2-hydroxypropyl) - 

ethylenediamine . 
N- (2-Hydroxyethyl1-N,N' ,N' -tris (2-hydroxypropyl) - 
ethylenediamine distearate, methyl sulfate. 

(Mixed alkyl)amine, ethoxylated 

(Mixed alkyl)poly (oxye thy lene) amine 

Mixed substituted oximes 

(9-Octadecenyl) amine , ethoxylated 

Octadecyl amine, ethoxylated 

Po lye thy lenepoly amine , alkoxylated 

(Soybean oil alkyl)amine, ethoxylated 

*(Tallow alkyl)amine, ethoxylated 

Tallow alkyl amine ethoxylated, sulfate 

N-(Tallow alkyl) trimethylenediamine, ethoxylated 

N,N,N' ,N'-Tetrakis (2-hydroxye thy 1) ethylenediamine — 
N,N,N' ,N'-Tetrakis (2-hydroxypropyl) ethylenediamine 

dioleate , methyl sulfate. 
N,N,N' ,N'-Tetrakis (2-hydrox\'propy 1) ethyl enedi amine , 
propoxylated and ethoxylated. 

Triethanol amine , ethoxylated 

All other 

*Cyclic (except imidazoline and oxazoline derivatives) : 

Aniline and m-toluidine , ethoxylated 

Lignin amine 

Rosin amine, ethoxylated 

Imidazoline and oxazoline derivatives: 

2- (8-Heptadecenyl)-4,4-bis(hydroxymethyl)-2- 

oxazoline. 
2-(8-Heptadecenyl)-l- (2-hydroxyethyl) -2- 

imidazoline. 
2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2- 
oxazoline. 

*2-(Heptadecyl)-l- (2 -Hydro xye thy 1) -2- imidazoline 

*l-(2-Hydroxyethyl)-2-nor(coconut oil alkyl)-2- 

imidazoline. 
*l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2- 
imidazoline. 
l-(2-Hydroxyethyl)-2-tridecyl-2-imidazoline 
hydrochloride. 

2-Hydrox\Tpropyl imidazoline 

*Amines and amine oxides having amide linkages: 

*Carboxylic acids - diamine and polyamine condensates: 
Caprylic acid - tetraethylenepentamine condensate — 
Coconut oil acids - diethylenetri amine condensate — 
Coconut oil acids - N,N-dimethyltrimethylene- 

diamine condensate. 
Mixed dicarboxylic acids - polyalkylenepolyamine 
condensate. 
*Mixed fatty acids - polyalkylenepolyamine 
condensate. 
Oleic acid - 1- (2-aminoethyl)piperazine condensate-- 

Oleic acid - diethylenetriamine condensate 

Oleic acid - N,N-dimethyltrimethylenediaraine 

condensate. 
Pelargonic acid - tetraethylenepentamine 

condensate . 
Stearic acid, diethanolamine condensate, 
methyl sulfate. 

Stearic acid - diethylenetriamine condensate 

Stearic acid - N,N-diethylethylenediamine 
condensate. 



CGY, 
NLC. 



CGY, 


DA, 


GAP, 


ICI, RH, T 


GAP. 








GNM. 








ARC, 


DA, 


TCH. 




ARC, 


TCH 






NLC, 


TCH 






.ARC, 


VAC 






ARC, 


CGY 


DUP 


GAP, TCH. 


DUP. 








ARC, 


IVTC 






NLC. 








DUP. 








ARC, 


IVTC 


IVYN 




TCH. 








ARC, 


GLY 


SCP 




TCH. 








IWA. 








HPC, 


NLC 


WTC 





DA, 


ONX, 


UVC. 




CGY, 


COM, 


uvc. 




CGY, 


CHP, 


MOA, 


UVC. 


CGY, 


HOA, 


UVC. 




HDG, 


MOA, 


NLC, 


TCH, UVC. 


CGY, 


IVTC. 






TCH. 








ICI. 








APX, 


TXT. 






JRG, 


TXT 


IVTC. 




TXT. 








GRD. 


NLC, 


QCP. 


TCH. 


TXT. 








ICI, 


TXT. 






CCW. 








ICI 








DUP. 








CHP, 


CST, 


PNX, 


ONX, S. 


CGY, 


S. 







SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Surface-active agents for which U.S, production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Cationic Surface- Active Agents — Continued 

♦Amines and amine oxides having amide linkages — Continued 
*Carboxylic acids - diamine and polyamine condensates-- 
Continued 

Stearic acid - tetraethylenepentamine condensate 

*Tall oil acids - diethylenetriamine and 
polyalkylene polyamine condensates : 

Tall oil acids - diethylenetriamine condensate 

Tall oil acids - polyalkylenepolyamine condensate- 
All other 

Other amines and amine oxides having amide linkages: 
Coconut oil acids - diethylenetriamine condensate, 
po lye th oxy 1 at ed . 

3-Lauramido-N,N-dimethylpropylamine oxide 

Mixed fatty acids - alky lenedi amine condensate, 

polyethoxylated. 
Oleic acid - ethy lenedi amine condensate, mono- 

ethoxylated. 
Palm oil acids - ethylenediamine condensate, mono- 
ethoxylated. 

Rosinpolyamidoimidazoline 

Stearic acid - diethylenetriamine condensate, poly- 
ethoxylated. 
♦Stearic acid - ethylenediamine condensate, mono- 
ethoxylated. 
Stearic acid - ethylenediamine condensate, poly- 
ethoxylated. 
Tall oil acids - ethylenediamine condensate, 
monoethoxylated. 
♦Amines, not containing oxygen [and salts thereof): 
♦Amine salts : 

(Coconut oil alkyl)amine acetate 

(Hydrogenated tallow alkyl)amine acetate 

(9-Octadecenyl) amine acetate 

Octadecyl amine acetate 

(Tallow alkyl)amine acetate 

N- (Tallow alkyl)trimethylenediamine acetate 

N- (Tallow alkyl)trimethylenedianiine oleate 

N- (Tallow alkyl)trimethylenediamine tallate 

All other 

♦Diamines and polyamines : 

♦N- (Coconut oil alkyl)trimethylenediamine 

N-(Docosyl- and eicosyl) trimethylenediaraine 

♦Imidazoline derivatives: 

1- [3-(2-Aminoethyl)naphth-l-yl]-2-(8-hepta- 

decenyl) -2- imidazoline. 
l-(2-Aminoethyl)-2-nor(tall oil alkyl)-2- 
imidazoline. 

2-Heptadecy 1-2- imidazoline 

Tall oil imidazoline 

N- (Mixed alkyljpolyethylenepolyamine 

♦N- (9-Octadecenyl) trimethylenediamine 

N- (Soybean oil alkyl) trimethylenediamine 

N-(Tall oil alkyl)trimenthylenediamine 

N- (Tallow alky l)dipropylenetri amine 

N- (Tallow alkyl) trimethylenediamine 

♦Primary monoamines : 

(Coconut oil alkyl)amine 

Dodecyl amine 

Docosyl- and eicosylamine 

Hexadecylaraine 

♦(Hydrogenated tallow alkyl)araine 

(Mixed alkyl) amine 

(Mixed tert- alkyl) amine 



AZS, 


DA, FNX, NCW, 


NLC, 


RTF, 


WTC 


AZS, 


QCP, OTC. 








NLC, 


VND. 









SNW. 
GAP. 

CLD, DA, DEX, SnC , TNA. 

APX. 

WC. 
TCC. 

CST, DA, DEX, ICI, MRV, S, SCP. 

ICI. 

SCP. 



ARC, IVTC. 
ARC, ASH. 
GNM. 

ACY, ARC. 
ARC. 

ARC, ASH. 
ARC, ASH. 
ARC. 
SM 

ARC, ENO, GNM. 
END. 



NLC, UVC, IVTC. 

BIR, SCO. 

AZS. 

CCW. 

ARC, ASH, GNM. 

ENO. 

ARC. 

ARC, GNfl. 

ARC, ASH, ENO, GNM. 

ARC, ENO, GNM. 

ARC, ASH, GNM. 

ENO. 

ARC, ENO. 

ARC, ASH, ENO, GNM. 

ARC. 

RH. 



SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Cationia Surface- Active Agents- -Contimied 

•Amines, not containing oxygen (and salts thereof) -- 
Continued 
'Primary monoamines: 

*9 -Oct adecenyl amine 

*Octadecyl amine 

Octylamine 

tert-Octylamine 

(Soybean oil alkyljamine 

(Tall oil alkyDamine 

'(Tallow alkyl) amine 

'Secondary and tertiary monoamines: 

Bis (coconut oil alkyl)amine 

'Bis (hydrogenated tallow alkyl)amine 

N,N-Dimethyl (coconut oil alkyl)amine 

N,N-Dirae thy Idecyl amine 

N,N-Dimethyl (Docosyl- and eicosyl)amine 

*N,N- Dime thy Idodecyl amine 

*N, N- Dime thy Ihexadecyl amine 

N,N-Dimethyl (hydrogenated tallow alkyl) amine 

N,N- Dimethyl (mixed alkyl) amine 

*N, N- Dime thy loctadecyl amine 

N,N- Dimethyl octylamine 

N,N-Dimethyl (soybean oil alkyl)amine 

N,N-Dirae thy Itetradecyl amine 

N-Methylbis (coconut oil alkyl)amine 

*N-Methy Ibis (hydrogenated tallow alkyl)amine 

N -Me thy Idi Oct adecyl amine 

Trioctyl amine 

'Oxygen-containing quaternary ammonium salts: 

Quaternary ammonium salts having amide linkages: 
Ethyldimethyl ( 3-pe 1 agonamidop ropy 1) ammonium 

ethyl sulfate. 
(2-Hydroxyethyl) dimethyl (3-stearamidop ropy 1)- 

ammonium dihydrogen phosphate. 
(2-Hydroxyethyl)dimethyl (3-stearamidopropyl) - 

ammonium nitrate. 
( 3- Lauramidopropyl)trimethyl ammonium methyl 

sulfate. 
2- (2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium 

chloride. 
Tall oil acid - polyalkylenepolyamine condensate, 

quaternary sulfate. 
Trimethyl (3-oleamidopropyl)ammonium methyl 
sulfate . 

All other 

Other oxygen-containing quaternary ammonium salts: 
(2-Aminoethyl) ethyl (hydrogenated tallow alkyl) (2- 

hydroxyethyl) ammonium ethyl sulfate. 
Benzyl (coconut oil alkyl)bis (2-hydroxyethyl)- 

ammonium chloride. 
Benzyl (coconut oil alkyl, ethoxylated)dimethyl- 

ammonium chloride. 
l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl) -2- 

imidazolinium chloride. 
1-Benzyl-l- (2-hydroxyethyl)-2-nor(tall oil alkyl)- 

2-imadazolinium chloride. 
Bis(2-hydroxyethyl, ethoxylated) ethyl (hydrogenated 

tallow alkyl) ammonium ethyl sulfate. 
Bis (2-hydroxyethyl, ethoxylated)methyl(9-octa- 

decenyl)ammonium chloride. 
Bis (2-hydroxyethyl , ethoxylated)methyloctadecyl- 
ammonium chloride. 



ARC, 


ASH, 


ENO, 


GNM. 


ARC, 


ASH, 


ENO, 


GNU. 


ARC. 








RH. 








ARC, 


ENO. 






ASH, 


nwL 






ARC, 


ASH, 


ENO, 


GNM. 


ARC. 








ARC, 


ASH, 


ENO. 




ARC, 


ASH, 


BRD, 


ENO. 


BRD. 








ENO. 








ARC, 


BRD, 


ENO, 


ONX. 


ARC, 


BRD, 


ONX. 




ARC, 


ASH, 


ENO. 




ARC, 


BRD, 


ONX. 




ARC, 


ASH, 


BRD, 


ENO. 


BRD. 








ARC, 


ENO. 






ARC, 


BRD, 


ONX. 




ENO, 


GNH. 






ARC, 


ASH, 


ENO, 


GNM, SCO 


ASH. 








BRD, 


GNU. 






TCH. 








ACY. 








ACY. 








ACY. 








IVTC. 








NLC. 








CCY. 








ARC, 


X. 






LUR. 








CGY, 


NLC. 






GAF. 








IWC. 








NLC, 


HOA. 






ICI. 








ARC. 








ARC. 









SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 









^lanufacturers ' identification codes 


Chemical 






(ac 


cording to list in table 3) 


Cationic Swff ace- Active Agents — Continued 










*Oxygen-containing quaternary ammonium salts :--Continued 










Other oxygen-containing quaternary ammonium 










salts--Continued 










(Coconut oil alkyl)bi5(2-hydroxyethyl, ethoxy- 


ARC, 


VAC. 






lated)methylammonium chloride. 










(Ethoxybeniy 1) dimethyl (octylphenoxy) ammonium 


RH. 








chloride. 










(Ethoxybenzyl)dimethyl(octyltolyloxy') ammonium 


RH. 








chloride. 










l-Ethyl-2-(8-heptadecenyl)-l- (2-hydroxyethyl)-2- 


ICI, 


UVC. 






imidazolinium ethyl sulfate. 










N-Ethyl-N-hexadecylmorpholinium ethyl sulfate 


BRD, 


ICI. 






N-Ethyl-N- (soybean oil alkyl)morpholinium ethyl 


ICI. 








sulfate . 










2-Hydroxytrimethylenebis[ (coconut oil alkyl]di- 


CGY. 








methyl ammonium chloride] . 












TCC. 








tjuaternari zed propoxyiatea stearyi amine 






ARC. 








(.juateman zea propoxyiatea taiiow aiamme 






ARC. 








Ail otner 

'Quaternary ammonium salts, not containing oxygen: 










*Acyclic: 










*Bis(coconut oil alkyl)dimethylammonium chloride 


ARC, 


ASH, 


END, 


GNM, VAC. 


Bi5(coconut oil alkyl)dimethylammonium nitrate 


ARC. 








*Bis(hydrogenated tallow alkyl)dimethylammonium 


ARC, 


ASH. 


END, 


GNM, VAC. 


chloride. 










Bis (hydrogenated tallow alkyl)dimethylammonium 


PR.X. 








methyl sulfate. 










(Coconut oil alkyl)trimethylammonium chloride 


ARC, 


ASH. 






Didecyldi methyl ammonium chloride 


BRD. 








Didodecyldimethylammonium bromide 


ONX. 








Dimethylbis (mixed alkyl) and trimethyl (mixed 


GNfl. 








alkyl)ammonium chloride. 










Dimethylbis (9 -octadecenyl) ammonium chloride 


GNM. 








Dimethylbis (soybean oil alkyl) ammonium chloride 


ARC. 








Dime thy Idioctadecyl ammonium chloride 


ASH, 


ONX, 


PG. 






ON.X. 








uimetnyiai octaaecyi ammonium metnyi suirate 




Dioctyldimethyl ammonium chloride 


BRD. 








Dodecyltrimetliyl ammonium bromide 


DUP. 








Dodecyltrimethylammonium chloride 


ARC, 


CHP, 


GNM, 


WTC. 


Ethyldimethyl (mixed alkyl)ammonium ethyl sulfate 


DEX, 


JOR, 


TCC. 




Ethyldime thy 1(9 -octadecenyl) ammonium bromide 


ONX. 








Ethylhexadecyldimethylammonium bromide 


FIN. 








Hexadecyl trimethyl ammonium bromide 


DUP, 


FIN. 






♦Hexadecyl trimethyl ammonium chloride 


ARC, 


BRD, 


VAC. 




Hexadecyl trimethyl ammonium p-toluenesulfonate 


FIN. 








(Hydrogenated tallow alkyl) trimethylammonium 


END. 








chloride. 










Me thyltrioctyl ammonium chloride 


GNM. 








N,N,N' ,N' ,N'-Pentamethyl-N-(tallow alkyl)tri- 


ARC, 


GNM. 






methylenebis [ammonium chloride]. 










Trimethyl (mixed alkyl) ammonium chloride 


NLC. 








Trimethyloctadecylammonium chloride 


ARC. 








Trimethyl (soybean oil alkyl) ammonium chloride 


ARC, 


END. 






♦Trimethyl (tallow alkyl) ammonium chloride 


ARC, 


ASH 


ENO, 


GNM. 


Trime thy Itetradecyl ammonium bromide 


FIN. 








All other 


BRD, 


GNM 


ICI, 


STC. 


♦Benzenoid: 


1- (2-Aminoethyl)-l-ethyl-2- (8-heptadecenyl-2- 


EFH. 








imidazolinium bromide. 










Benzylalkylpyridinium ammonium chloride 


KTC. 








♦Benzyl (coconut oil alkyl) dimethylammonium 


ARC, 


CRT, 


DEP, 


END, HLI, LUR, TXT, KTC. 


chloride. 










*Benzyldimethyl (mixed alkyl) ammonium chloride 


AAC, 


BRD 


FIN, 


ONX, RH, TXT, VAC. 



SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NT INUED 



Cationia Sicpfaae-Active Agents — Continued 

'Quaternary ammonium salts, not containing oxygen- - 
Continued 
*Benzenoid-- Continued 

* Benzyl dime thy loot adecylammonium chloride 

Benzyldimethyl (tallow alkyl)aiiunonium cliloride 

Benzyldime thy Itetradecyl ammonium chloride 

Benzyldodecyldi methyl ammonium chloride 

Ben zylhexadecy Id imethyl ammonium chloride 

Benzyl Chydrogenated tallow alkyl)dimethylammonium 
chloride. 

l-Benzyl-2-picolinium bromide 

1-Benzylpyridinium chloride 

*Benzyltrime thy 1 ammonium chloride 

(3, 4- Dichlorobenzyl)dodecyldimethyl ammonium 
chloride . 

(Dodecylbenzyl) triethylammonium chloride 

{Dodecylbenzyl)trimethylammoniura chloride 

2-Dodecylisoquinolinium bromide 

(Dodecylme thy Ihenzylltrime thy 1 ammonium chloride 

1-Dodecylpyridinium chloride 

(E thy Iben zy 1 ) dimethyl (mixed alky 1 ) ammonium 
chloride, 

1- (Mixed alkyl)quinolinlum ethylsulfate 

l-Phenethyl-2-picolinium bromide 

Nonionio Surface- Active Agents 

*Carboxylic acid amides : 

*Diethanolamine condensates (amine/acid ratio=2/l): 

*Capric acid 

Castor oil acids 

*Coconut oil acids 

*Coconut oil and tallow acids 

* Laurie acid 

Laurie and myristic acids 

Linoleic acid 

Mixed vegetable oil acids 

*01eic acid 

Pe 1 argoni c acid 

*Stearic acid 

*Tall oil acids 

Tallow acids 

*Diethanolamine condensates (other amine/acid 
ratios) : 
*Coconut oil acids (amine/acid ratio=l/l) 

Coconut oil acids (amine acid ratio unspecified)-- 
*Lauric acid (amine/acid ratio=l/l) 

Laurie and myristic acids (amine/acid ratio=l/l)-- 
Linoleic acid (amine/acid ratio=l/l) 

*01eic acid (amine/acid ratio=l/l) 

Palmitic and stearic acid (amine/acid ratio=l/l)-- 
Rapeseed oil acids (amine/acid ratio=2.6/l) 

•Stearic acid (amine/acid ratio=l/l) 

Stearic acid (amine/acid ratio=2.7/l) 



Manufacturers' identification codes 
(according to list in table 3) 



BRD, 


FIN, 


HLI, 


ONX, 


RH, 


TNI, 


VAC 


END. 














FIN, 


SNK. 












FIN, 


ONX, 


SDH. 










ONX. 














ENO, 


ONX. 












FIN. 














DEP. 














CHP, 


CIN, 


CRT, 


TCC. 








ONX, 


VAC. 












PC. 














\'AC , 


IVTC. 












ONX. 














RH. 














BRD, 


ONX. 













CCY, SCP, TCH. 

CLI, FNX, NTL. 

ACT, AKS, ARD, ARL, AZS, BSW, CHP. CLI, CTL, DA, DEP, 
EFH, FNX, HLI, HRT, JOR, KNP, LUR, MCP, MOA, MRV, 
ONX, PC, PG, PNX, PVO, SBC, SCP, SEY, STP, TCH, 
TXC, TXN, UNN, U\'C, VAC, VAL, VND, WTC, x. 

ACT, CLI, CRT, ECC, ESS, MOA, PC, PVO, SOS. 

ARD, CLI, DA, ECC, HLI, ONX, PG. WON. 

FNX, HLI, MOA, PVO, STP. 

VND. 

HLI. 

CCW, CLI, EMR. FNX. PVO, STP. 

EMR, TCH. 

CLI, DA, EMR, ECC. JOR, mV , ONX, SCO, TXC, VAL. 

EFH, MCP, MOA, MRV. SOS. 

SOS. 1«TC. 



ARD. AZS. CCL. CCY, CIN, CLI, CTL, FNX, HLI, JRG, MOA, 
MRV, ONX, PIL, SBC, SEY, STP, TCC, TCH, TXN, TXT, 
VAC, IVTC. 

CON, JRG. 

ARD, CLI, CTL, HIK, HLI, LEV, MOA. ONX. SBC, TCH, TXN, 
VAC, IVTC. 

CLI, TXT. 

MOA, SBC. 

CGY, HLI, SBC, SCP, TCC, TCH, TXT. 

MCP. 

EFH. 

CGY, ECC, EMR. FNX, MRV, RPC, m'C. 

EFH. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Surface-active agents for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionia Surface-Active Agents — Continued 

*Carboxylic acid amides--Continued 

*Diethanolainine condensates (other amine/acid 
ratios) --Continued 

Tall oil acids (amine/acid ratio=l/l) 

Tall oil acids (amine/acid ratio=2.7/l) 

Tallow acids (amine/acid ratio=l/l) 

All other 

*Ethanolamine and isopropanolamine condensates: 
♦Coconut oil acids - ethanolamine condensate 

(amine/acid ratio=2/l). 
•Coconut oil acids - ethanolamine condensate 
(amine/acid ratio=l/l). 
Coconut oil acids - ethanolamine condensate, 
ethoxylated. 

Coconut oil acids - isopropanolamine condensate 

Hydrogenated castor oil acids - ethanolamine 
■ condensate (amine/acid ratio=2/l). 
Hydrogenated tallow acids - ethanolamine 

condensate (amine/acid ratio=2/l) . 
Laurie acid - ethanolamine condensate (amine/acid 

ratio=2/l) . 
Laurie acid - ethanolamine condensate (amine/acid 
ratio=l/l) . 

Laurie acid - isopropanolamine condensate 

Laurie and myristie acids - ethanolamine 

condensate (amine/acid ratio=l/l) . 
Laurie and myristie acids - isopropanolamine 

condensate. 
Oleic acid - ethanolamine condensate (amine/acid 

ratio=l/l) . 
Oleic acid - ethanolamine condensate, ethoxylated-- 
Stearie acid - ethanolamine condensate (amine/acid 

ratio=2/l) . 
Stearic acid - ethanolamine condensate (amine/acid 

ratio=l/l) . 
Stearic acid - ethanolamine condensate (amine/acid 

ratio=l/2) . 
Tallow acids - ethanolamine condensate (amine/acid 
ratio=l/l) . 

All other 

*Carboxylic acid esters: 
*Anhydrosorbitol esters: 

Anhydrosorbitol dioleate 

*Anhydrosorbitol monoester of tall oil acids 

*Anhydrosorbitol monolaurate 

Anhydrosorbitol mono- ol eat e 

*Anhydrosorbitol raonopalmitate 

•Anhydrosorbitol monostearate 

Anhydrosorbitol sesquioleate 

Anhydrosorbitol triester of tall oil acids 

Anhydrosorbitol trioleate 

Anhydrosorbitol tristearate 

*Diethylene glycol esters: 

Diethylene glycol dioleate 

*Diethylene glycol distearate 

Diethylene glycol monoester of coconut oil acids — 

Diethylene glycol monoester of tallow acids 

•Diethylene glycol monolaurate 

Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

•Diethylene glycol monostearate 

Diethylene glycol sesquiester of tall oil acids 

•Diethylene glycol sesquilaurate 

Diethylene glycol sesquistearate 



ECC, 
EFH. 
RPC, 
ORO, 

CTL, 

ARD, 



TCH. 
STP. 

PRX, STP, TCH, VAC, VND, IVTC. 

CLI, HLI, HUH, MOA, PG, STP, UVC. 

STP. 



STP, 


MOA. 








GLY, 


NTL. 








GLY. 










ARC, 


CTL, 


PRX. 






ARD. 










CLI, 


MOA. 








MOA. 










LEV, 


TXT. 








VPC. 










ARD, 


DA, 


GAF. 






CLI. 










MOA, 


VND. 








HAL, 


SEY. 








SCP. 










ROB, 


MCP, 


TXN. 






ICl. 










GLY, 


HDG, 


ICI, 


TCH. 




GLY, 


HDG, 


ICI, 


SYL 


TCH 


GLY, 


HDG, 


ICI, 


PVO 


TCH 


GLY, 


HDG, 


ICI, 


TCH 




GLD, 


GLY, 


HDG. 


ICI 


PVO 


GLY, 


HDG. 








GLY. 










GLY, 


ICI, 


TCH. 






GLY, 


ICI, 


PVO. 






GLY. 










ARC, 


ECC, 


GLY, 


VAL 




AAC, 


DA. 








QCP. 










CCW, 


GLY, 


HAL, 


HDG 




ARC, 


EMR. 








GLY. 










ARC, 


CHP, 


CLI, 


DA, 


HAL, 


ECC, 


WTC. 








ARC, 


GLY, 


mi. 






IVM. 











SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionic Surface-Active Agents — Continued 

*Carboxylic acid esters — Continued 
*Ethoxylated anhydrosorbitol esters: 

Ethoxylated anhydrosorbitol monolaurate 

*Ethoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

'Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol monotallate 

Ethoxylated anhydrosorbitol triester of castor 

oil acids. 
Ethoxylated anhydrosorbitol triester of tall oil 
acids. 

Ethoxylated anhydrosorbitol trioleate 

•Ethoxylated anhydrosorbitol tristearate 

♦Ethoxylated sorbitol esters: 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol distearate 

Ethoxylated sorbitol heptaoleate 

Ethoxylated sorbitol hexaester of tall oil acids-- 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol monostearate 

Ethoxylated sorbitol oleate, acetylated 

Ethoxylated sorbitol nentaester of tall oil acids- 

Ethoxylated sorbitol nentalaurate 

Ethoxylated sorbitol pentaoleate 

Ethoxylated sorbitol tetraester of lauric and 

oleic acids. 
Ethoxylated sorbitol tetraester of tall oil acids- 

Ethoxylated sorbitol tetraoleate 

♦Ethylene glycol esters: 

Ethylene glycol distearate 

Ethylene glycol mono-oleate 

Ethylene glycol monostearate 

Ethylene glycol sesquistearate 

All other 

♦Glycerol esters: 

♦Complex glycerol esters: 

Glycerol ester ethoxylated 

Glycerol lactate esters of fatty acids 

Glycerol mannitan laurate 

Glycerol monoester of mixed fatty acids, 
acetylated. 

Glycerol mono-oleate, acetylated 

Glycerol monostearate, succinylated 

Glycerol trilaurate myristate 

♦Glycerol esters of chemically defined acids: 

Glycerol di oleate 

Glycerol di laurate 

Glycerol distearate 

Glycerol monocaprylate 

♦Glycerol monolaurate 

♦Glycerol mono-oleate 

♦Glycerol monoricinoleate 

♦Glycerol monostearate 

♦Glycerol esters of mixed acids: 

Glycerol monoester of coconut oil acids 

Glycerol monoester of cottonseed oil acids 



AAC, GLY, HDG, ICl, SYL, TCH. 

AAC, ARC, GLY, HDG, ICl , PVO, SYL, TCH. 

AAC, ICI, TC}1. 

AAC, GLY, HDG, ICI, PVO, TCH. 

1«TC. 

ARC. 

ICI, TCH. 

AAC, GLY, ICI, TCH. 

AAC, GLY, HDG, ICI, PVO, TCH. 

ICI. 

ICI. 

ICl. 

ICI, TCH. 

GLY, ICI, TCH. 

ICI. 

ICl. 

TCIK 

ICI. 

WTC. 

ICl. 

ICI. 

ICI. 

ICl. 
ICl. 

ARC, EMR, HUI1. 

EFH. 

ARC, CLI, GLY, HAL, HDG, KNP, TCH, VND, WM. 



GLY. 
GLD. 
GLY . 
EKT. 



EKT. 
GLY. 

ARC, HAL. 

VND. 

ARC, ICl, IVTC. 

ARC, pvn. 

ARC, GLY, HAL. 

ARC, CCW, CHP, DA, EFH, EMR, GLY, HAL, HDG, PVO, TCH, 

\m, \«TC. 
CCW, DA, HDG. 
ARC, ASH, BLS, CHL, DA, EFH, EMR, FNX, GLY, GRO, HAL, 

HDG, HRT, LUR, PG, PVO, SCP, SOS, TCC, TCH, VND, 

WM, WTC. 

PVO, WM. 
EKT. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3} 



Nonionic Surface- Active Agents — Continued 

*Carboxylic acid esters- -Continued 
♦Glycerol esters--Continued 

♦Glycerol esters of mixed acids--Continued 

♦Glycerol monoester of hydrogenated cottonseed 

oil acids. 
♦Glycerol monoester of hydrogenated soybean oil 
acids. 

Glycerol monoester of hydrogenated tallow acids 

Glycerol monoester of lard acids 

Glycerol monoester of peanut oil acids 

Glycerol monoester of tall oil acids 

Glycerol monoester of tallow acids 

Glycerol sesquiester of hydrogenated tallow acids- 

Glycerol sesquiester of tall oil acids 

All other 

♦Natural fats and oils, alkoxylated: 

♦Castor oil, ethoxylated 

Castor oil, propoxylated 

Com oil, ethoxylated 

♦Hydrogenated castor oil, ethoxylated 

Lanolin, ethoxylated 

All other 

♦Polyethylene glycol esters: 

♦Polyethylene glycol esters of chemically defined 
acids: 

•Polyethylene glycol dilaurate 

♦Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol methylcarbitol maleate 

Polyethylene glycol monoisostearate 

♦Polyethylene glycol monolaurate 

♦Polyethylene glycol mono-oleate 

Polyethylene glycol mono-oleate, etlioxylated 

Polyethylene glycol monopalmitate 

Polyethylene glycol monopelargonate 

♦Polyethylene glycol monostearate 

Polyethylene glycol sesquioleate 

All other 

♦Polyethylene glycol esters of rosin and tall oil 
acids ; 

Polyethylene glycol diester of tall oil acids 

Polyethylene glycol ester of tall oil acids 

Polyethylene glycol monoester of tall oil acids — 
Polyethylene glycol monoester of tall oil 

acids, ethoxylated. 

Polyethylene glycol sesquiester of rosin acids 

Polyethylene glycol sesquiester of tall oil 

acids. 
♦Polyethylene glycol esters of other mixed acids: 
Polyethylene glycol diester of trimerized castor 

oil acids. 
Polyethylene glycol ester of palmitic, stearic, 

and coconut oil acids. 
Polyethylene glycol monoester of coconut oil 

acids. 



GLD, LEV, Wi. 

A.SH, F.KT, GLD, NIV, PVn , TCH. 

TCH. 
EKT, GLD. 

pvn. 

EFH. 
BFP. 
JRG. 
SLM. 
EKT, GLD, ICI, LEV. 

AAC, DA, DUP, GAF, ICI, NLC, NIL, PVO, SYL, TCH, TMH, 

IVTC. 
TCH. 
TCH. 

DA, ICI, SYL, TCH. 
AAC, CRD, CRN, ICI, PR\, TCH. 
ARC, DA. 



ARC, DA, EFH, GLY, HAL, HDG, TCH, IVM. 

ARC, CGY, CLD, DA, EFH, GLY, HAL, HDG, NLC, TCH, UVC, 

VND, mi. 
ARC, EFH, FNX, GLY, HAL, HDG, TCH. 
CCA. 
TCH. 
AAC, ARC, CCA, CGY, DA, GLY, HAL, HDG, ICI, JOR, KNP, 

HCP, TCH, m'C. 
AAC, ARC, CCA, CGY, CHP, CLD, CRT, DA, DEX, EFH, GAF, 

GLY, HAL, HDG, ICI, ONX, PVn, SCP , TCH, UVC, VAC, 

Wl, IVTC. 
ICI. 
ICI. 

EUR, TCH. 
khC, AKS, ARC, CGY, CHP, CRT, DA, DEP, DEX, EFH, EMR, 

GAF, GLY, HAL, HDG, HRT, ICI, KNP, ONX, PC, PVO, 

TCC, TCH, VND. 
ICI, TCH, WTC. 
SEY. 



EFH, GLY. 
TCH. 
GLY. 
NLC, TCH. 

HPC. 

ARC, ICI, MON, PVn, SLH, SM, WTC. 



GLY. 

MCP. 
GLY. 



SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionia Surface- Active Agents — Continued 

*Carboxylic acid esters--Continued 

*Polyethylene glycol esters--Continued 

*Polyethylene glycol esters of other mixed acids-- 
Continued 
Polyethylene glycol monoester of coconut oil 

acids, ethoxylated. 
Polyethylene glycol sesquiester of castor oil 
acids. 
*Polyethylene glycol sesquiester of coconut oil 
acids. 

Polyethylene glycol sesquiester of tallow acids 

All other 

*Polyglycerol esters: 

Polyglycerol ester of tall oil acids 

Polyglycerol mono- ole ate 

Polyglycerol raonostearate 

*Propanediol esters: 

1,2 -Propanediol dioleate 

1,2- Propanediol distearate 

1,3-Propanediol monoester of coconut oil acids 

1,2- Propanediol monolaurate 

1,2- Propanediol monomyri state 

1,2 -Propanediol mono- ol eat e 

* 1,2- Propanediol monostearate 

1,2- Propanediol sesquiester of h\*drogenated tallow 
acids. 

All other 

Miscellaneous carboxylic acid esters: 

Anhydrosorbitol glycerol monolaurate 

Ethoxylated glycerol sesquiester of mixed fatty 
acids. 

Ethoxylated 1,2-propanediol monostearate 

2-Hydroxymethyl-2-butene-l,4-diol mononelargonate — 
Laurie acid esters of glycerol and ethoxylated 
nonylphenol . 

Methylglucoside 1 aur ate 

Mixed esters of stearic acid 

Mixed polyhydric alcohols triester of tall oil 
acids . 

Oleic acid esters of ethoxylated nonylphenol 

Pentaecrythritol distearate 

Polyalkylene glycol adipate 

Polyalkylene glycol di fumarate 

Polypropylene glycol monoester 

Poly-propylene glycol mono-oleate 

Polypropylene glycol raonostearate 

All other 

*Ethers : 

*Benzenoid ethers: 

*Alkylphenol - formaldehyde condensates, alkoxylated: 

Alkylphenol, ethoxylated 

(Mixed alkyl)phenol - formaldehyde, alkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

tert-flctylphenol - formaldehyde, ethoxylated 

All other 

Derivatives of ethoxylated phenols 

Diisobutylphenol , ethoxylated 

Dinonylphenol , ethoxylated 

*Dodecylphenol , ethoxylated 

Iso-octylphenol, ethoxylated 



AAC, 


ICI. 






CGY. 








ARL, 


MRT, 


PG, 


VND. 


sns. 








ACT, 


ECC, 


SIR 


SM, 


AZS. 








HDG, 


pvn, 


TCH 


VND. 


ASH, 


pvn. 


TCH 




X. 








ARC. 








Wl. 








ARC, 


HAL, 


PVO 


SBC. 


ICI. 








EFH, 


HAL. 






ARC, 


CCW, 


EKT 


GLD, 


JRG. 









ICI. 
ICI. 

ICI. 
ICI. 
TCC. 

HDG. 
EUR. 
ICI. 

EFH. 

GLY, QCP, VAL. 

NLC. 

WTC. 

sns. 

HDG. 
HDG. 
CCW, TCH, WM. 



IVTC. 

NLC, NTL. 

NLC, WTC. 

DA, SDW. 

PVO, WTC. 

RH. 

GAF. 

ARD, GAF, STP, TCH. 

ACC, GAF, HON, TCH, TMH, UCC. 

APX, DA, OHC, RH. 



SYNTHETIC ORGANIC CHEMICALS^ 1972 
TABLE 2. --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER^ 1°72--C0NT!NUED 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionic Surface- Active Agents — Continued 

*Ethers :- -Continued 

*Benzenoid ethers: --Continued 

(Mixed alkyl)phenol, ethoxylated 

(Mixed alkyl5phenoxypoly(ethyleneoxy) ethyl 
chloride. 
*Nonylphenol, ethoxylated 

Nony Iphenoxypoly (ethyleneoxy) ethyl iodide 

n- Oc ty Ipheno 1, ethoxylated 

Phenol, ethoxylated 

Styrenated phenol, ethoxylated 

Tetradecylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

Xylenol , ethoxylated 

All other 

*Nonbenzenoid ethers : 

*Linear alcohols, alkoxylated: 

Coconut oil alcohol, ethoxylated 

*Decyl alcohol, ethoxylated 

Decyl and octyl alcohols, ethoxylated 

Decyl and octyl alcohols, ethoxylated and 
propoxylated. 

Decyloxypoly (ethyleneoxy) ethyl chloride 

Derivative of ethoxylated primary alcohol 

*Dodecyl alcohol, ethoxylated 

*Hexadecyl alcohol, ethoxylated 

*Mixed linear alcohols, ethoxylated 

*Mixed linear alcohols, ethoxylated and 
propoxylated. 

*9-0ctadecenyl alcohol, ethoxylated 

*Octadecyl alcohol, ethoxylated 

Sperm oil alcohol, ethoxylated 

Tallow alcohol, ethoxylated 

Wool wax alcohols, ethoxylated 

*Other ethers and thioethers: 

*Poly(ethylene and propylene) glycols : 

Poly(mixed ethylene, propylene) glycol 

Polypropylene glycol, ethoxylated 

tert-Dodecyl mercaptan, ethoxylated 

Ethylhexanol, ethoxylated 

Glucose, ethoxylated 

Glycerol , alkoxylated 

Isodecyl alcohol, ethoxylated 

Iso-octyl alcohol, ethoxylated 

Methylglucoside, propoxylated 

Mixed alcohols, ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol, ethoxylated 

2,4,7,9-Tetramethyl-5-decyne-4,7-diol , 
ethoxylated. 
*Tridecyl alcohol, ethoxylated 

Tridecyl alcohol, propoxylated and ethoxylated- 

Trimethylheptanol , ethoxylated 

♦Trimethylnonyl alcohol, ethoxylated 

Trimethylolpropane , alkoxylated 

All other 

Other nonionic surface-active agents: 

Dodecylbenzenesulfonic acid - diethanolamine 
condensate, fatty acid monoester. 

Dodecyl alcohol, ethoxylated and phosphated 

Octyl phosphate, ethoxylated 

Tri(castor oil alkyl)phosphate 

All other 



NTL, PRX, TCH. 
GAP, NIC. 



, DA, GAP, HDG, ICl, JCC, MON, OMC, RH, STP, TCH, 
mi, UCC, VAC, WTC. 



DA, GAP, ICI, JCC, TCH, UCC. 



GAP. 

TCH. 

CLY, 

DA. 

ORn. 

TCH. 

NLC. 

GAP, 



GLY. 

GAP, ICl, TCH. 

GAP, GLY, TCH. 

GAP. 

GAP. 

RH. 

AAC, DUP, GAP, HDG, ICI, OMC, PVO, SNW, UCC, WTC. 

AAC, CGY, ICI, VAC, TCH. 

AAC, Cn, DA, GAP, HDG, JCC, NLC, RH, SHC, STP, TCH, 

UCC, WTC. 

JCC, STP, TCH, UCC, WYN. 

AAC, ABC, CGY, CRN, DA, DUP, GAP, GLY, ICI, TCH, VPC. 

CGY, DA, DUP, GAP, ICI, HDG. 

CRD, DUP. 

AAC. 

CRD. 



NLC, UCC. 

NLC, VAC, IVTC, IVYN. 

AAC, UCC. IVTC. 

TCH. 

RH. 

NLC. 

TCH. 

GAP. 

STP. 

CRN, PVO. 

NLC, VAC. 

TCH. 

GAP. 

AAC, DA, DUP, GAP, ICI, JCC, MON, NLC, OMC, PVO, SYL, 

TCH, UCC, IVTC. 

ICI, JCC. 
TCH. 

HDG, UCC, VAC. 

HDG, VAC, IVTC, IVYN . 
TCH. 

ACT. 

DUP. 
DUP. 
GLY. 
AIP, STC. 



SURFACE-ACTIVE AGENTS 
TABLE 3, --Surface-active agents; Directory of manufacturers, 1972 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of surface-active agents to the U.S. Tariff Commission for 
1972 are listed below in the order of their identifcation codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


AAC 


Alcolac Chemical Corp. 


FIN 


Fine Organics, Inc. 




ABC 


ARC Chemical Corp. 








ACE 


Acme Chemical Co. 


GAF 


GAF Corp., Chemical Div. 




ACS 


Allied Chemical Corp., Specialty Chemicals Div. 


GLD 


Glidden Durkee Famous Foods 




ACT 


Arthur C. Trask Co. 


GLY 


Glyco Chemicals, Inc. 




ACY 


American Cyanamid Co. 


GNM 


General Mills Chemicals, Inc. 




AES 


Amerace-Esna Corp., Penetone Div. 


GRC 


Chemed Corp., Dubois Chemicals Div. 




AGP 


Armour- Dial, Inc. 


CRD 


W.R. Grace 5 Co., Polymer § Chemicals Div. 




AIP 


Air Products 5 Chemicals, Inc. 


GRL 


Chemed Corp., Vestal Laboratories, Inc. 




AKS 


Arkansas Co. , Inc. 


GRO 


Millmaster Onyx Corp., A. Gross 5 Co. Div 




APX 


Apex Chemical Co., Inc. 


GYR 


Goodyear Tire 6 Rubber Co. 




ARC 


Armak Co. 








ARD 


Ardmore Chemical Co. 


HAL 


CP. Hall Co. of Illinois 




ARL 


Arol Chemical Products Co. 


HDG 


Hodag Chemical Corp. 




ASH 


Ashland Oil, Inc., Ashland Chemical Co. Div. 


HEW 


Hewitt Soap Co. , Inc. 




ASY 


American Synthetic Rubber Corp. 


HK 


Hooker Chemical Corp. 




ATR 


Atlantic Richfield Co., ARCO Chemical Co. 


HLI 


Haag Laboratories, Inc. 




AZS 


AZS Corp. : 

AZ Products Co. Div. 


HMP 


W.R. Grace 6 Co., Dewey 5 Almy Chemical Di 
Organic Chemicals 


V. , 




Lancaster Chemical Co. Div. 


HNT 
HPC 


Huntington Laboratories, Inc. 
Hercules, Inc. 




BAO 


Bayoil Co. , Inc. 


HRT 


Hart Products Corp. 




BFP 


Breddo Food Products Corp. 


HUM 


Kraftco Corp., Humko Products Div. 




BLA 


Astor Products, Inc., Blue Arrow Div. 








BLS 


Beech-Nut, Inc. 


ICl 


ICI America, Inc. and Specialty Chemicals 


Div. 


BRD 


Lonza, Inc. 








BSW 


Original Bradford Soap Works, Inc. 


JCC 
JOR 


Jefferson Chemical Co., Inc. 
Jordan Chemical Co. 




CCA 5 


Cincinnati Milacron Chemicals, Inc. 


JRG 


Andrew Jergens Co. 




CCW 










CCL 


A.E. Staley Manufacturing Co., Textile Div. 


KAL 


Kali Manufacturing Co. 




CGY 


Ciba-Geigy Corp. and Ciba Pharmaceutical Co. 


KNG 


Far-Best Corp., O.L. King Div. 




CHL 


Chemol, Inc. 


KNP 


Knapp Products, Inc. 




CHP 


C.H. Patrick f, Co., Inc. 








CIN 


Cindet Chemicals, Inc. 


LAK 


Lakeway Chemicals, Inc. 




CLD 


Colloids, Inc. 


LEA 


Leatex Chemical Co. 




CLI 


Clintwood Chemical Co. 


LEV 


Lever Brothers Co. 




CLY 


W.A. Cleary Corp. 


LIL 


Eli Lilly fi Co. 




CO 


Contirental Oil Co. 


LKY 


Lake States Div. of St. Regis Paper Co. 




COM 


Commercial Solvents Corp. 


LMI 


North American Chemical Co. 




CON 


Concord Chemical Co., Inc. 


LUR 


Laurel Products Corp. 




CP 


Colgate-Palmolive Co. 








CPP 


Charmin Paper Products Co. 


MAR 


American Can Co. 




CRD 


Croda, Inc. 


MCP 


Moretex Chemical Products, Inc. 




CRN 


CPC International, Inc. 


MIR 


Miranol Chemical Co., Inc. 




CRT 


Crest Chemical Corp. 


MOA 


Mona Industries, Inc. 




CRZ 


Crown Zellerbach Corp., Chemical Products Div. 


MON 


Monsanto Co. 




CST 


Charles S. Tanner Co. 


MRA 


Crown-Metro, Inc. 




CTL 


Continental Chemical Co. 


MRD 


Marden-Wild Corp. 




CWP 


Consolidated Papers, Inc. 


MRT 


Morton Chemical Co. Div. of Morton-Norwich 
ducts. Inc. 


Pro- 


DA 


Diamond Shamrock Corp. 


MRV 


Marlowe- Van Loan Corp. 




DAN 


Dan River, Inc. 


MYW 


Stepan Chemical Co., Maywood Div. 




DEP 


DePaul Chemical Co., Inc. 








DEX 


Dexter Chemical Corp. 


NCW 


Nostrip Chemical Works, Inc. 




DOW 


Dow Chemical Co. 


NES 


Nease Chemical Co., Inc. 




DUP 


E.I. duPont de Nemours 5 Co., Inc. 


NLC 


Nalco Chemical Co. 




DYS 


Davies- Young Co. 


NMC 
NPR 


National Milling 5 Chemical Co., Inc. 
Safeway Stores, Inc. 




ECC 


Eastern Color 5 Chemical Co. 


NTL 


NL Industries, Inc. 




EFH 


E.F. Houghton 6 Co. 


NW 


Northwestern Chemical Co. 




EKT 


Eastman Kodak Co., Tennessee Eastman Co. Div. 








EMK 


Emkay Chemical Co. 


OMC 


01 in Corp. 




EMR 


Emery Industries, Inc. 


ONX 


Millmaster Onyx Corp., Onyx Chemical Co. 




ENO 


Enenco, Inc. 


ORO 


Chevron Chemical Co. 




ESS 


Essential Chemicals Corp. 









SYNTHETIC ORGANIC CHEMICALS. 1972 • 
TABLE 3, --Surface-active agents; Directory of manufacturers, 1972--Continued 



Code 


Name of company 


Code 


Name of company 


PC 


Proctor Chemical Co., Inc. 


SOS 


Southern Sizing Co. 




PCH 


Peerless Chemical Co. 


SPA 


Scott Paper Co. 




PEK 


Peck's Products Co. 


stc 


Sou-Tex Chemical Co., Inc. 




PFZ 


Pfizer, Inc. 


stp 


Stepan Chemical Co. 




PC 


Procter 5 Gamble Co. 


SYL 


Magnolia Industries, Inc., Milliken Chemical 


PIL 


Pilot Chemical Co. 




Div. 




PLX 


Plex Chemical Corp. 








PNX 


Murphy-Phoenix Co. 


tcc 


Tanatex Chemical Corp. 




PRX 


Purex Corp. , Ltd. 


tch 


Emery Industries, Inc., Trylon Chemica 


Div. 


PSP 


Georgia-Pacific Corp., Bellingham Div. 


TCI 


Texize Chemicals, Inc. 




PVO 


PVO International, Inc. 


TEN 
TMH 


Cities Service Co., Copperhill Operatic 
Thompson -Hayward Chemical Co. 


ns 


QCP 


Quaker Chemical Corp. 


TNA 


Ethyl Corp. 








TNI 


Gillette Chemical Co. Div. of Gillette 


Co. 


RAY 


ITT Rayonier, Inc. 


TXC 


Tex Chem Co. 




RBC 


Fike Chemicals, Inc. 


TXN 


Textilana-Nease, Inc. 




RCD 


Richardson Co. 


TXT 


Textilana Corp. 




RH 


Rohm 5 Haas Co. 








ROB 


Robeco Chemicals, Inc. 


UCC 


Union Carbide Corp. 




RPC 


Millmaster Onyx Corp., Refined-Onyx Div. 


UDI 
UNN 


Petrochemicals Co., Inc. 

United Chemical Corp. of Norwood 




S 


Sandoz, Inc., Sandoz Colors § Chemical Div. 


IINP 


United Chemical Products Corp. 




SBC 


Scher Bros. Inc. 


USR 


Uniroyal, Inc., Chemical Div. 




SBP 


Sugar Beet Products Co. 


UVC 


Universal Chemicals Corp. 




SCO 


Scholler Bros. , Inc. 








SCP 


Henkel, Inc. 


VAC 


Northern Petrochemical Co. 




SDC 


Martin-Marietta Corp. , Sodyeco 


VAL 


Valchem 






Sterling Drug, Inc. : 


VND 


Van Dyk 5 Co. , Inc. 




SDH 


Hilton-Davis Chemical Co. Div. 


VPC 


Baychem Corp., Verona Div. 




SDW 


Winthrop Laboratories Div. 








SEA 


Seabroad Chemicals, Inc. 


WAW 


W.A. Wood Co. 




SEY 


Seydel-Woolley 5 Co. 


WAY 


Philip A. Hunt Chemical Corp., Kayland 


Chemical 


SFS 


Stauffer Chemical Co., Specialty Chemical Div. 




Div. 




SHC 


Shell Oil Co., Shell Chemical Co. Div. 


WBG 


White f, Bagley Co. 




SID 


George F. Siddall Co., Inc. 


WHI 


White § Hodges, Inc. 




SLC 


Soluol Chemical Co., Inc. 


WHW 


Whittemore-Wright Co., Inc. 




SLM 


Salem Oil 6 Grease Co. 


WIC 


Wica Chemicals, Inc. 




SM 


Mobil Oil Corp., Mobil Chemical Co., 
Chemical Coatings Div. 


WM 


Wilson Pharmaceutical 5 Chemical Corp. 
Wilson-Martin Div. 




SNW 


Sun Chemical Corp., Chemicals Div. 


WON 


Woonsocket Color 5 Chemical Co. 




SOC 


Standard Oil Co. of California, Chevron 


WTC 


Witco Chemical Co., Inc. 






Chemical Co. 


WVA 


Westvaco Corp., Chemicals Div., Polyche 


mical 


SOP 


Southern Chemical Products Co. 


WYN 


Dept. 
BASF-Wyandotte Chemicals Corp. 





Note. --Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix. 



189 



PESTICIDES AND RELATED PRODUCTS 



Pesticides and related products include fungicides, herbicides, 
insecticides, rodenticides , and related products such as plant hormones, 
seed disinfectants, soil conditioners, soil furaigants, and synergists. 
The data are given in terms of 100-percent active material; they thus 
exclude such materials as diluents, eraulsifiers, and wetting agents. 

U.S. production of pesticides and related products in 1972 amounted 
to 1,158 million pounds--!, 9 percent greater than the 1,136 million 
pounds reported for 1971 (table 1).^ Sales in 1972 were 1,Q22 million 
pounds, valued at $1,092 million, compared with 946 million pounds, valued 
at $979 million, in 1971. 

The output of cyclic pesticides and related products amounted to 
839 million pounds in 1972--1.4 percent greater than the 828 million pounds 
produced in 1971. Sales in 1972 were 7.20 million pounds, valued at $890 
million, compared with 669 million pounds, valued at $819 million, in 1971. 
Production of acyclic pesticides and related products in 1972 amounted to 
318 million pounds, compared with the 308 million pounds reported for 1971, 
an increase of 3.3 percent. Saxes in 1972 were 302 million pounds, an in- 
crease of abci't 8^ percent as compared to the 277 million pounds reported 
in 1971; the value of sales was $202 million in 1972, compared with $160 
million in 1971--an increase of 26.3 percent. 



1/ See also table 2 which lists these products and identifies the 
manufacturers by codes. These codes are given in table 3. 



552-743 O - 74 - 13 



.SYNTHETIC nPnANIC CMFfllCALS, 1972 
TARLE 1. —Pesticides and related products; U.S. production and sales, 1972 



[Listed below are all pesticides and related products for which any reported data on production or sales may be pub- 
lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 2 lists all pesticides and related products for which data on production or sales were 
reported and identifies the manufacturers of each] 



Production 



Sales 



Quantity 



Unit 
value' 



1,000 
pounds 



Grand total 

Benzenoid 

Nonbenzenoid 

pesticides and related products, cyclic 

Total 

Fungicides , total 

Mercury fungicides, total 

Phenylmercuric acetate (PMA) 

Phenyl mercuric oleate 

Other mercury fungicides 

Naphthenic acid, copper salt 

Pentachlorophenol (PCP) 

8-Quinolinol (S-Hydroxyquinoline) , copper salt 

All other cyclic fungicides" 

Herbicides and plant hormones, total 

l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH) 

2,4-Dichlorophenoxyacetic acid, dimethylaitiine salt 

All other cyclic herbicides and plant hormones- 

Insecticides and rodenticides, total 

Aldrin-toxaphene group'* 

Organophosphorus insecticides, total 

0,0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl 
parathion) 

All other organophosphorus insecticides^ 

All other cyclic insecticides and rodenticides^ 

PESTICIDES AND RELATED PRODUCTS, ACYCLIC 
Total 

Fungicides, total 

Dithiocarbamic acid salts' 

All other acyclic fungicides' 

Herbicides and plant hormones, total 

Methanearsonic acid salts' 

All other acyclic herbicides'" 



657,092 
500,606 



98,164 



854 

307 

279 

268 

2,206 

49,704 

40 

45,360 



4,472 

22,469 

344,789 



141,858 
95,461 



51,076 
44,385 



318,338 



30,698 
48,883 



liOOO 
pounds 

1,021,565 



1,000 
dollars 



581,107 

440,458 



88,530 



781 
284 
263 
234 
2,291 
48,355 

37,103 

282,094 



24,028 
258,066 



349,083 



140,150 
90,283 

52,438 
37,845 

118,650 



39,987 



34,857 
36,632 



681,768 
409,940 



58,192 



3,154 
1,382 

539 
1,233 

717 
6,783 

47,538 



9,311 
564,537 



65,919 
96,843 



23,576 
73,267 



202,095 



23,972 



17,382 
6,590 

55,110 



9,370 
45,740 



Per 
pound 



1.28 
2.03 



.27 
1.25 



See footnotes at end of table. 



PESTICIDES AND RELATED PRODUCTS 
TABLE 1,— Pesticides and related products: I'.S. production and sales^ T'^72— Continued 



Quantity 



Unit 
value' 



PESTICIDES AiND RELATED PRODUCTS, ACYCLIC--Continued 

Insecticides, rodenticides, soil conditioners and 

fumigants, total 

Methyl bromide (Bromomethane) 

Organophosphorus insecticides' ' 

1 ,2-Dibromo-3-chloropropane (DBCPJ 

All other acyclic insecticides, rodenticides, soil 

conditioners and fumigants 



1,000 
pounds 



7,000 
pounds 



1,000 
do t tars 



Per 

pound 



24,633 
65,181 



104,295 



23,930 
59,734 
15,228 

91,490 



9,349 
76,507 

6,275 

30,882 



.34 



1 Lalculated trom rounded tigures. 

2 Includes captafol , captan, dinocap, DMTT, folpet, pentachloronitrobenzene, 8-quinolinol (sales only), sodium 
pentachlorophenate, tri- and tetra-chlorophenols (including 2 ,4 ,5-trichlorophenol and its salts), and others. 

3 Includes acetanilide compounds, amiben esters and salts, barban, benefin, bensulide, 4-CPA potassium salt, 
2,4-D, acid, esters, and salts, 2,4-DB, dicamba, dimethylurea compounds, dinitrophenol compounds, isopropyl phenyl- 
carbamates (IPC and CIPC), MCPA, MH (sales only), molinate, NPA picloram, propanil, silvex and its esters, 2,4, 5-T 
acid esters and salts, triazines, trifluralin, uracils, and others. 

4 Includes aldrin, chlordan, dieldrin, endrin, heptachlor, and toxaphene. 

5 Includes azinphosmethyl , carbophenothion, coumaphos , diazinon, dioxathion, fensulfothion , parathion, ronnel, 
and other phosphorothioates and phosphorodithioates, and others. 

6 Includes carbaryl , carbofuran, chlorinated insecticides (BHC + lindane, chlorobenzilate, DDT, dicofol, endo- 
sulfan, methoxychlor, and others), insect attractants, DEET and other insect repellents, small amounts of rodenti- 
cides, piperonyl butoxide and other synergists, and others. 

7 Includes ferbam, maneb, nabam, and zineb, plus the remaining dithiocarbamates which are used chiefly as 
pesticides. 

8 Includes dodine, mercury compounds, PETD, and others. 

9 Includes the mono- and di-sodium salts, and the dodecyl- and octyl -ammonium salts of methanearsonic acid. 

10 Includes cacodylic acid, CDAA, dalapon, thiocarbamate, thiol carbamate, and organophosphorus herbicides, sodiuii 
TCA, and others. 

11 Includes DDVP, dimethoate, disulfoton, ethion, malathion, monocrotophos , naled, phorate, and other organo- 
phosphorus insecticides. 

12 Includes aldicarb, DBCP (production only), soil conditioners and fumigants, methomyl , small quantities of 
rodenticides, and others. 



Note. --Does not include data for the insect fumigant, p-dichlorobenzene nor the fungicide, o-phenylphenol. 
These data are included in the report on cyclic intermediates. 

To expedite publication of this report it was necessary to estimate data for two small companies. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972 



[Pesticides and related products for which separate statistics are given in table 1 are marked below with an 

asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 5. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3} 



PESTICIDES AND RELATED PRODUCTS, CYCLIC 

*Fungicides; 

Benzylbromo acetate-- 

2, 6 -Bis (dimethylamiTiomethyl)cvclohexanone 

2'-Rrorao-4'-hydroxyacetophenone 

5-Chloro-2-benzothiazolethiol , laurylpyridinium salt 

Cyanomethylthiobenzothiazole 

2,4-Dichloro-6-(o-chloroanilino)-s-triazine 

1 ,4-Dichloro-2,5-dimethoxybenzene (ChloronebJ 

1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline (Ethoxyquin)- 
3,5-Dimethyl-l,3,5-2H-tetrahydrothiadiazine-2-thione 
(DMTT) . 

Diphenylammonium propionate 

5-Ethoxy-3-trichloromethyl-l ,2,4-thiadiazole 

Hexahydro-1 .3,5-triethyl-s-triazine 

Hexahydro-1 ,3,5-tris (2-hydroxyethyl)-s-tri3zine 

2-Mercaptobenzothia2ole, monoethanolamine salt 

*Mercury fungicides: 

Dipheny Imercury dodeceny Isuccinate 

•Phenylmercuric acetate (PMA) 

Phenylmercuric ammonium acetate 

Phenylmercuric dimethyldithiocarbamate 

Phenylmercuric hydroxide 

Phenylmercuric lactate 

* Phenyl mercuric oleate 

Phenylmercuric propionate 

Phenylmercuric succinate 

All other mercury fungicides 

Methyl-N-benzimidazol-2-yl-N- (butylcarbomoyl) carbamate 

(Benomyl) . 
2- (l-Methyl-n-heptyl)-4,6-dinitrophenyl crotonate 

(Dinocap) . 
3- (2-Methylpiperidino) propyl- 3, 4-dichlorobenzoate 
(Piperalin) . 

*Naphthenic acid, copper salt 

Pentachloronitrobenzene (PCNB) 

*Pentachlorophenol (PCP) 

Pentachlorophenol , sodium salt 

*8-Quinolinol (8-Hydroxyquinoline) , copper salt 

N- CI ,1 ,2,l-Tetrachloro-ethylsulfenyl)-cis-'-4-cyclo- 
hexene-l,2-dicarboximide (Captafol) . 

2,4,5,6-Tetrachloroisophthalonitrile 

2,3,4,6-Tetrachlorophenol 

N-Trichloromethylthio-4-cyclohexene-l,2-dicarboximide 
(Captan) . 

N-Trichloromethylthiophthalimide (Folpet) 

2,4 ,5-Trichlorophenol acid and salts: 

2,4,S-Trichlorophenol 

2,4,5-Trichlorophenol, ethanolamine salt 

2,4,S-Trichlorophenol , sodium salt 

2,4,6-Trichlorophenol 

*Herbicides and plant hormones: 

4-Amino-3,5,6-trichloropicolinic acid (Picloram) 

2,4-Bis(isopropylamino)-6-methylthio-s-triazine 
(Prometryn) . 

5-Bromo-3-sec-butyl-6-methyluracil (Bromacil) 

3-tert-Butyl-S-chloro-6-methyluracil (Terbacil) 

N-Butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-p-toluidine 
(Benefin) . 

2-Butynyl-4-chloro-m-chlorocarbanilate (Barban) 

2-Chloro-4,6-bisCethylamino)-s-triazine (Simazine) 

2-Chloro-4,6-bis(isopropylamino)-s-triazine (Propazine) 



MRK. 
MRK. 
BKM. 
VNC. 
BKM. 
CHG. 
DUP. 
MON. 
BKM, MRK. 

MRK. 
OMC. 
VNC. 
EFH. 
VNC. 

TRO. 

CLY, MRK, TRO, WRC. 

TRO. 

WRC. 

WRC. 

WRC. 

CLY, HN, TRO, WRC. 

MRK. 

WRC. 

MAL. 

DUP. 

RH. 



CCA, 
OMC. 
DOW, 
DOW, 
FIS, 
ORO. 



DOW. 
SFC. 



DOW, 
GAF. 
DOW. 
DOW. 

DOW. 
CGY. 

ACN, 
DUP. 
LIL. 

GOC. 
CGY. 
CGY. 



FER, HN, MCI, SHP, VAL , WTTC . 

FRO, MON, RCI . 

RCI. 

HN, MRK. 



PESTICIDES AND RELATED PRODUCTS 
TABLE 2, --Pesticides and related products for which U,S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CyCLIC--Continued 

*Herbicides and plant hormones--Continued 

2-Chloro-2' ,6'-diethyl-N- (n-butoxyniethyl)acetanilide 

2-Chloro-2' ,6* -diethyl-N- (methoxymethyl)acetanilide 

(Alachlor] . 
2-Chloro-4-ethylamino-6-isopropylamino-s-triazine 

(Atrazine) . 

2-Chloro-N-isopropylacetanilide (Propachlor) 

4-Chloro-2-methylphenoxy butyric acid 

N' -(4-Chlorophenoxy 3 phenyl N,N-dimethylurea 

(Chloroxuron) . 

3- (p-Chlorophenyl)-l , 1-dimethylurea (Monuron) 

3- (p-Chlorophenyl)-l,l-diiiiethyIurea trichloroacetate 

2;5-Dichloro-5-aminoben2oic acid, ammonium salt 

2,5-Dichloro-5-aniinobenzoic acid, methyl ester 

3,6-Dichloro-2-anisic acid (Dicamba) 

2,4-Dichlorobenzyltributylphosphonium chloride 

2,5-Dichloro-6-nitrobenzoic acid, sodium salt 

4- (2,4-Dichlorophenoxy}butyric acid (2,4-DB) 

3- (3,4-Dichlorophenyl) -1 , 1-dimethylurea (Diuron) 

3- (3,4-Dichlorophenyl )-l-methoxy-l-methylurea (Linuron)-- 

2,4-Dichlorophenyl-4-nitrophenyl ether (Nitrofen) 

3' ,4'-Dichloropropionanilide (Propanil) 

*l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) (MH) 

N- (beta-0,0-Diisopropyl-dithiophosphorylethyl)benzene 

sulfonamide (Bensulide) . 

N,N-Dimethyl-2,2-diphenylacetamide (Diphenamid) 

Dimethyl -2, 3, 5,6 -tetrachloroterephthalate (DCPA) 

Dinitrobutylphenol (DNBP) 

Dinitrobutylphenol , aBBonium salt 

Dinitrobutylphenol, triethanolamine salt 

Dinitrocresol, sodium salt 

2-Ethylamino-4-isopropyla«lno-6-methylmercapto-s- 

triazine (Ametryne) . 

S- Ethyl (cyclohexyl)ethylthiocarbamate 

S-Ethyl hexahydro-lH-azepine-1-carbothioate (MolinateJ 

Gibberellic acid 

3-Indolebutyric acid 

Isopropyl N- (3-chlorophenyl)carbamate (CIPC) 

Isopropyl N-phenylcarbamate (IPC) 

1- (2-Methylcyclohexyl)-3-phenylurea (Siduron) 

4-(Methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline 

(Nitralin). 
1-Naphthaleneacetic acid and derivatives: 

1 -Naphtha leneacet amide 

1-Naphthaleneacetic acid (NAA) 

1-Naphthaleneacetic acid, sodium salt 

N-1-Naphthylphthalamic acid (NPA) 

7-Oxabicyclo[2.2. l]heptane-2,3-dicarboxylic acid, di- 

sodium salt (Endothall). 
Phenoxyacetic acid derivatives: 

4-Chloro-2-methylphenoxyacetic acid (MCPA) 

3,S-Dibrorao-4-hydroxybenzonitrile, octanoic acid ester 
(Bromoxynil octanoate) . 

2,4-Dichlorophenoxyacetic acid (2,4-D) 

2,4-Dichlorophenoxyacetic acid esters and salts: 

2,4-Dichlorophenoxyacetic acid, 2-butoxyethyl ester-- 
2,4-Dichlorophenoxyacetic acid, butoxypolypropylene- 
glycol ester. 

2,4-Dichlorophenoxyacetic acid, n-butyl ester 

2,4-Dichlorophenoxyacetic acid, sec-butyl ester 

•2,4-Dichlorophenoxyacetic acid, dimethylamine salt 



MON. 
MON 



MON. 
RDA. 
CGY. 

DUP. 

ACN. 

AMC, GAP. 

GAP. 

VEL. 

SM. 

GAP. 

RDA. 

DUP. 

DUP. 

Rll. 

EGR, MON, RH. 

ACY, ASL, FNfT, USR. 

SPA. 

CWN. 



DOW, 


EGR, 


PMN. 


DOW, 


PMN. 




DOW, 


FMN. 




FMN. 






CGV. 






SPA. 






SPA. 






ABB, 


MRK. 




ARA. 






PPG. 






PPG. 






DUP. 






SHC. 






AMC. 






■AMC. 






AMC, 


BKL. 




USR. 






PAS. 






CLY, 


RDA, 


RIV. 


RDA. 







DOW, MON, RDA. 

DOW, RIV. 
DOW. 

RIV. 
DOW, RDA. 

DOW, PBI, RDA, RIV, TMH . 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC- -Continued 

•Herbicides and plant horraones--Continued 
Phenoxyacetic acid derivatives--Continued 

2,4-Dichlorophenoxyacetic acid esters and salts-- 
Continued 
2,4-Dichlorophenoxyacetic acid, ethanolamine and 

isopropanolamine salt. 
2,4-Dichlorophenoxyacetic acid, iso-octyl ester — 

2,4-Dichlorophenoxyacetic acid, isopropyl ester 

2,4-Dichlorophenoxyacetic acid, lithium salt 

2,4-Dichlorophenoxyacetic acid, sodium salt 

2,4,S-Trichlorophenoxyacetic acid (2,4,5-T) 

2,4,5-Trichlorophenoxyacetic acid esters and salts: 
2,4,5-Trichlorophenoxyacetic acid, 2-butoxyethyl 

ester. 
2,4,5-Trichlorophenoxyacetic acid, butoxypoly- 

propyleneglycol ester. 
2,4,S-Trichlorophenoxyacetic acid, n-butyl ester-- 
2,4,S-Trichlorophenoxyacetic acid, sec-butyl ester 
2,4,5-Trichlorophenoxyacetic acid, iso-octyl ester 
2,4,5-Trichlorophenoxyacetic acid, triethylamine 
salt. 
Polychloro-tetrahydro-methanoindene (Polychlorodicyclo 
pentadiene) isomers. 

2- (2,4,5-Trichlorophenoxy)propionic acid (Silvex) 

2- (2,4,5-Trichlorophenoxy)propionic acid esters and 
salts: 
2- (2,4,5-Trichlorophenoxy)propionic acid, 2-butoxy- 
ethyl ester. 
2- (2,4,5-Trichlorophenoxy)propionic acid, iso-octyl 
ester. 
a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine 

(Trifluralin). 
3- (m-Trifluoromethylphenyl)-l ,1-dimethylurea 
(Fluometuron) . 

All other cyclic herbicides 

Insect attractants and repellents: 

tert-Butyl 4 (and 5)-chloro-2-methylcyclohexanecarboxy- 
late (Trimedlure] . 

2-(3,4-Dichlorophenyl)-l,2,4-oxadiazoline-4-methyl- 

3,5-dione. 
N,N-Diethyltoluamide (DEET) 

Di-n-propylisocinchomeronate 

•Insecticides: 

3-sec-Amylphenyl-N-methylcarbamate 

Bacillus thuringiensis 

2-sec-Butyl-4,6-dinitrophenyl-3,3-dimethylacrylate 

(Binapacryl) . 
2-(p-tert-Butylphenoxy)cyclohexyl-2'-propynyl sulfite-- 

o-sec-Butylphenyl-N-methylcarbamate 

Chlorinated insecticides: 
*Aldrin-toxaphene group: 

Heotachloro-tetrahydro-endo-methanoindene 

(Heptachlor) . 
Ilexachloro-epoxy-octahydro-endo , endo-dimethano- 

naphthalene (Endrin) . 
Hexachloro-epoxy-octahydro-endo, exo-dimethano 

naphthalene (Dieldrin). 
Hexachloro-hexahydro-endo, exo-dimethanonaphthalene 
(Aldrin). 

Octachloro-hexahydro-methanoindene (Chlordan) 

Toxaphene (Chlorinated camphene) 

2,2-Bis(p-chlorophenyl)-l,l-dichloroethane (DDD) (TDE)- 
a-Bis(p-chlorophenyl)B,6,6-trichloroethane (DDT) 



DOW, 


RDA, RIV 


DOW 


RIV. 


GTH. 




DOW, 


RIV. 


DOW. 




DOW, 


RIV. 


DOW. 




RIV. 




DOW. 




DOW, 


RIV, TMH 


DOW. 




VEL. 




DOW, 


TMH. 


RIV. 




RIV. 




LIL. 




CGY. 




CWN, 


LIL. 


UOP. 




NES, 


VEL. 


HPC, 


PF2. 


MGK. 




X. 




ABB, 


IMC. 


FMN. 




USR. 




OTC. 




VEL. 




VEL. 




SHC. 




SHC. 




VEL. 




HN, 


HPC. 



PESTICIDES AND RELATED PRODUCTS 
TABLE 2.— Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued 

'Insecticides --Continued 

Chlorinated insecticides- -Continued 

Chlorobenzilate 

o-Chlorophenyl-N-methylcarbamate 

p-Chlorophenyl 2,4,5-trichlorophenyl sulfone 

(Tetradifon) . 
Decachlorooctahydro-l,3,4-metheno-2H-cyclobuta- [cd] 

pentalen-2-one (Kepone) . 

l,l-Dichloro-2,2-bis (p-ethylphenyl) ethane 

4,4'-Dichloro-a-trichloromethylbenzhydrol (Dicofol) 

2 ,6-Dimethyl-3,5-dichloro-4-pyridinol 

Dodecachlorooctahydro-l ,3,4-metheno-2H-cyclobuta- [cd] 

pentalene (Mirex) . 

Hexachlorocyclohexane (Benzene hexachloride^ (BHC) 

Hexachlorocyclohexane, 100% Y-isomer (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepin 

3-oxide (Endosulfan) . 

Isopropyl 4,4' -dichlorobenzilate (Chloropropylate) 

1 ,1 ,1-Trichloro- 2, 2-bis(p-methoxyphenyl) ethane 

(Methoxychlor) . 
2,3-Dihydro-2,2-dimethyl-7-benzofuranly methyl - 

carbamate (Carbofuran) . 
m-[[(pimethylaiiiino)methylene]amino]phenyl methyl carbamate 
hydrochloride (Formetanate hydrochloride) . 

m- (1 -Ethyl propyl) phenyl methyl carbamate 

O-Isopropylphenyl N- methyl carbamate 

m- (I-Methylbutyl ) phenyl methyl carbamate 

1-Naphthyl N-methylcarbamate (Carbaryl) 

*Organophosphorus insecticides: 

0- (4-Bromo-2,5-dichlorophenyl)0-methyl phenylphosphono- 

thioate (Leptophos) . 
4-tert-Butyl-2-chlorophenylmethyl methylphos- 

phoramidite. 
S-[[(p-Chlorophenyl)thlo]methyl] 0,0-diethyl phos- 

phorodithioate (Carbophenothion) . 
0,0-Diethyl a-3-chloro-4-methyl-l-oxo-2H-l-benzo- 

pyran-7-yl-phosphorothioate (Coumaphos) . 
0,0-Diethyl 0- (2-isopropyl-4-methyl-6-pyrimidinyl)- 

phosphorothioate (Diazinon) . 
0,0-Diethyl 0- [p- (methylsulfinyl)phenyll phosphoro- 

thioate (Fensulfothion) . 
0,0-Diethyl 0-p-nitrophenyl phosphorothioate 

(Parathion) . 
0,0-Diethyl 0-3, S,6-trichloro-2 pyridyl phosphoro- 
thioate. 
,0-Dimethyl 0- [4- (methyl thio) -m- to 1/1] phosphoro- 
thioate (Fenthion) . 
*0,0-Dimethyl 0-p-nitrophenyl phosphorothioate (Methyl 

parathion) . 
0,0-Dimethyl S- [4-oxo-l ,2,3-benzotriazin-3(4H) - 

ylmethyl] phosphorodlthioate (Azinphosmethyl) . 

0,0-Dimethyl S-phthalimidomethyl phosphorodithioate 

Dimethyl 2,4 ,5-trichlorophenyl phosphorothionate 

(Ronnel) . 
2,3-p-Dioxane S,S-bis (0,0-diethylphosphorodithioate) 

(Dioxathion) . 

0-Ethyl S-phenylethylphosphonodithioate 

a-Methylbenzyl 3- (dimethoxyphosphinyloxy) -cis- 

crotonate. 
0,0,0' ,0'-Tetramethyl O,0'-thiodi-p-phenylene phosphoro 

thioate. 
All other organophosphorus insecticides 



CGY. 
OTC. 
FMN. 



DOW. 
ACN. 



CGY. 

CHF, DUP, NES. 

FMC. 

MRT. 

ORG. 
OTC. 
ORG. 
UCC. 

VEL. 

DOW. 

SFA. 

CHG. 

CGY. 

CHG. 

AMP, MON, SFA. 

DOW. 

CHG. 

AMP, MON, SFA, VEL. 

CHG. 

SFA. 
DOW. 



SFA. 
SHC. 



ACY. 

ACY, SHC, VEL. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued 

•Insecticides- -Continued 

N-(Phenyl-2-nitropropyI)piperidine 

m-ToIyl-N-methylcarbamate 

All other cyclic insecticides 

Nematocides : 

0,0-Diethyl 0- (2 ,4-dichlorophenyl) phosphorothioate 

(Dichlofenthion) . 
0,0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionazin)- 
*Rodenticides: 

3- (a-Acetonylbenzyl) -4-hydroxycoumarin (Warfarin) 

2-DiphenylacetyI-l,3-indandione and sodium salt 
(Diphacinone) . 

2-Pivaloyl-l ,3-indandione (Pindone) 

Synergists and adjuvants: 

a- [2- (2-m-Butoxyethoxy) -ethoxy] -4 ,5-methylenedioxy-2- 

propyltoluene (Piperonyl butoxide) . 
N-(2-Ethylhexyl)bicycIo) 2.2.1 )-S-heptene-2, 3-di- 

carboximide. 
l,2-Methylenedioxy-4-[2- (octylsulfinyl)propylJben7ene-- 
Piperonal bis [ 2- (2 ' -n-butoxyethoxy) ethyl ] acetal 
(Heliotropin acetal). 
All other cyclic pesticides and related products 

PESTICIDES AND RELATED PRODUCTS, ACYCLIC 

•Fungicides : 

Bis-1 ,4-bromoacetoxy-2-butene 

N,N-Bis (phosphonomethyl) glycine 

Cadmium succinate 

l-Chloro-2-nitropropane (Korax) 

Copper tall ate 

Dimethylthiocarbonyl disulfide 

Di sodium cyanodithioimidocarbamate 

•Dithiocarbamic acid fungicides: 

Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Dimethyldithiocarbamic acid, potassium salt 

Ethylene bis(dithiocarbaiiiic acid), diammonium salt — 
Ethylene bis(dithiocarbamic acid), disodiun salt 

(Nabam) . 
Ethylene bis (dithiocarbamic acid), manganese salt 

(Maneb) . 
Ethylene bis (dithiocarbamic acid), zinc salt (Zineb)- 

N-Methyldithiocarbamic acid, sodium salt (SW)C) 

All other dithiocarbamic acid fungicides 

n-Dodecylguanidine acetate (Dodine) 

2-HyJroxypropylmethanethiol sulfonate 

Chloromethoxypropylmercuric acetate 

Polyethylenethiuram disulfide (PETD) 

•Herbicides and plant hormones; 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

2-Chloro-N,N-diallylacet amide fCDAA) 

(2-Chloroethyl)phosphonic acid 

S-2,3-Dichloroallyl diisopropylthiolcarbamate 
(Diallate) . 

2,2-DichIoropropionic acid, sodium salt (Dalapon) 

N-Dimethylamino succinamic acid (DMSA) 

Dimethylarsinic acid (Cacodylic acid) 

Ethyl diisobutyl thiolcarbamated 

S-Ethyl N,N-dipropylthiolcarbamate (EPTC) 

Ethyl xanthogen disulfide (EXD) 



MRK. 
OTC. 
OTC. 



MOT, 


PEN. 






NES. 








MOT, 


PIC. 






ALP, 


BKL, 


FMN, 


FMP 


MGK. 








PEN. 








MGK. 








CHG. 


WSN. 







VIN. 
MON. 
MAL. 
FMN. 
AMP. 
CLY. 
BKM. 

FMN, MAL, VNC. 

FMN. 

BKM. 

RBC. 

ALC, FMN, HH, USR. 

DUP, RH. 

FMN, HH. 
SFA. 

MAL, VNC. 
ACY. 

TRO. 
FW<. 

MON. 
MON. 
GAF. 
MON. 

DOW. 
USR. 
ASL. 
SFA. 
SFA. 
RBC. 



PESTICIDES AND RELATED PRODUCTS 
TABLE 2, --Pesticides and related products for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNTI NUED 



Manufacturers' identification codes 
(according to list in table 5) 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC--Continued 

*Herbicides and plant hormones--Continued 

*Methanearsonic acid, disodium salt (DSMA) 

*Methanearsonic acid, dodecyl- and octylammonium salt- 

*Methanearsonic acid, monosodium salt [MSMA) 

S-Propyl butylethylthiocarbamate (Pebulate) 

S-Propyl dipropylthiocarbamate (Vernolate) 

S,S,S-Tributyl phosphorotrithioate 

Tributyl phosphorotrithioite 

Trichloroacetic acid, sodium salt (TCA) 

S-2,2,3-Trichloroallyl diisopropyl thiol carbamate 
(Triallate) . 

All other acyclic herbicides 

'Insecticides : 

2- (2-Butoxyethoxy)ethyl thiocyanate 

S-Methyl N- [ (methylcarbamoyl)oxy] thioacetimidate 
(Methomyl ) . 
•Organophosphorus insecticides : 

S-[1,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos- 

phorodithioate (Malathion) . 
2-Carbomethoxy-l-propen-2yl dimethyl phosphate 

(Mevinphos) . 
1 ,2-Dibromo-2,2-dichloroethyl dimethyl phosphate 

(Naled) . 
0,0-Diethyl S-2- (ethylthio)ethyl phosphorodithioate 

(Disulfoton) . 
0,0-Diethyl 0-2- (ethylthio)ethyl phosphorothioate 

(Demeton 0) . 
0,0-Diethyl S-(ethylthio)methyl phosphorodithioate 

(Phorate) . 
3- (Dimethoxyphosphinyloxy)-N,N-dimethyl-cis- 

crotonamide (Dicrotophos) . 
0,0-Dimethyl 2,2-dichlorovinyl phosphate (Di- 

chlorvos) . 
0,0-Dimethyl S- [2-ethylsulfinyl)ethyl]phosphoro- 

thioate (Oxydemetonmethyl) . 
0,0-Dimethyl S- CN-methylcarbajnoylmethyl)phosphoro- 

dithioate (Dimethoate) . 
Dimethyl phosphate of 3-hydroxy-N-methyl-cis- 
crotonamide (Monocrotophos) . 

0,S- Dimethyl phosphoramidothioate 

0,0,0' ,0'-Tetraethyl S,S' -methylene bisphosphoro- 
dithioate (Ethion) . 

Tetraethyl pyrophosphate (TEPP) 

0,0,0,0-Tetra-n-propyl dithiopyrophosphate 

All other ^cyclic insecticides 

Nematocides : 

0-Ethyl S,S-dipropyl phosphorodithioate 

2-Methyl-2(methylthio)propionaldehyde 0- (raethylcarba- 
moyl)oxime (Aldicarb) . 
Soil conditioners: Polyacrylonitri le, hydrolyzed, 

sodium salt 

Soil fumigants : 

*l,2-Dibromo-3-chloropropane CDBCP) 

1 ,3-Dichloropropene 

1,3-Dichloropropene, 1 ,2-dichloropropane 

*Methyl bromide (Bromomethane) 

Methyl isothiocyanate 

Trich loronitromethane (Chloropicrin) 

All other acyclic pesticides and related products 



ASL, CLY, DA, VIN. 

CLY, VIN. 

ASL, DA. 

SFA. 

SFA. 

PLC. 

SM. 

DOW. 

MON. 



RH. 
DUP. 



ACY. 

SHC. 

SHC. 

CHG. 

CHG. 

ACY . 

SHC. 

SHC. 

CHG. 

ACY. 

SHC. 

CHG. 
FNIN, FMP. 

AMP. 
SFA. 
BFG. 



ACY. 

BST, DOW, SHC. 

DOW. 

DOW, SHC. 

AMP, DOW, GTL, MCH. 

MRT. 

DOW. 

GAF, PCW, TRO. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TARLE 3,— Pesticides and related products: Hirectory of manufacturers^ 1'572 



ALPHABETICAL DIRECTORY BY CODE 

Names of manufacturers of pesticides and related products that reported production or sales to the U.S. Tariff 
Commission for 1972 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ABB 


Abbott Laboratories 


MAL 


Mallinckrodt Chemical Works 


ACN 


Allied Chemical Corp., Agricultural Div. 


MCH 


Michigan Chemical Corp. 


ACY 


American Cyanamid Co. 


MCI 


Mooney Chemical Corp. 


ALC 


Alco Chemical Corp. 


MGK 


McLaughlin, Gormley § King Co. 


ALP 


Alpha Laboratories, Inc. 


MON 


Monsanto Co. 


AMC 


Amchem Products, Inc., 


MOT 


Motomoco, Inc. 




Div. of Rorer-Amchem, Inc. 


MRK 


Merck 5 Co., Inc. 


AMP 


Kerr-McGee Chemical Corp. 


MRT 


Morton Chemical Co. Div. of Morton-Norwich Products 


ARA 


Arapahoe Chemical Div. of Syntex Corp. 




Products, Inc. 


ASL 


Ansul Chemical Co. 


MTO 


Montrose Chemical Corp. of California 






NES 


Nease Chemical Co., Inc. 


BKL 


Millmaster Onyx Corp., Millmaster Chemical 








Co. Div., Berkeley Chemical Dept. 


OMC 


Clin Mathieson Chemical Corp., Agricultural Div. 


BKM 


Buckman Labs., Inc. 


ORG 


Chevron Chemical Co. 


EST 


Occidental Chemical Co. 


OTC 


Story Chemical Corp., Ott Chemical Div. 


CCA 


Cincinnati Milacron Chemicals, Inc. 


PAS 


Pennwalt Chemicals Corp. 

Gordon Corp. 

Pfister Chemicals, Inc. 


CGY 


Ciba-Geigy Corp. and 


PBI 




Ciba Agricultural Co. 


PCW 


CHF 


Chemical Formulators, Inc. 


PEN 


CPC International, Inc., Penick Div. 


CHG 


Baychem Corp., Chemagro Div. 


PFZ 


Pfizer, Inc. 


CLY 


W. A. Cleary Corp. 


PIC 


Pierce Organics, Inc. 


CWN 


Upjohn Co., Fine Chemical Div. 


PLC 


Phillips Petroleum Co. 






PPG 


PPG Industries, Inc. 


DA 


Diamond Shamrock Corp. 






DOW 


Dow Chemical Co. 


RBC 


Fike Chemicals, Inc. 


DUP 


E. I. duPont de Nemours § Co., Inc. 


RCl 


Reichhold Chemicals, Inc. 






RDA 


Rhodia, Inc. 


EFH 


E. F. Houghton fi Co. 


RH 


Rohm § Haas Co. 


EGR 


Eagle River Chemical Corp. 


RIV 


Riverdale Chemical Co. 


FER 


Ferro Corp., Ferro Chemical Div. 




Stauffer Chemical Co.; 


FIS 


Fisher Chemical Co., Inc. 


SFA 


Agricultural Div. 




FMC Corp.: 


SFC 


Calhio Chemicals, Inc. Div. 


FNIN 


Niagara Chemical Div. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


FMP 


Industrial Chemical Div., 


SHP 


Shepherd Chemical Co. 




Organic Business Group 


SM 


Mobil Oil Corp., Mobil Chemical Co. Div., 


FMT 


Fairmount Chemical Co. 




Industrial Chemical Div. 


FRO 


Vulcan Materials, Co., Chemical Div. 










TMH 


Thompson -Hayward Chemical Co. 


GAF 


GAF Corp., Chemical Div. 


TRO 


Troy Chemical Co. 


GOC 


Gulf Oil Corp., Gulf Oil 








Chemical Co. -U.S. 


UCC 


Union Carbide Corp. 


GTH 


Guth Chemical Co. 


UOP 


Universal Oil Products Co., UOP Chemical Div. 


GTL 


Great Lakes Chemical Corp. 


USR 


Uniroyal, Inc., Chemical Div. 


IIK 


Hooker Chemical Corp. 


VAL 


Valchem 


HN 


Tenneco Chemicals, Inc. 


VEL 


Velsicol Chemical Corp. 
Vineland Chemical Co. 


HPC 


Hercules, Inc. 


VI N 






VNC 


Vanderbilt Chemical Corp. 


IMC 


International Minerals S Chemical Corp. 








WRC 


Ventron Corp., Ventron Chemicals 


LIL 


Eli Lilly 6 Co. 


WSN 


Mallinckrodt Chemical Works, Washine Div. 






WTC 


Witco Chemical Co., Inc. 



Note. -Complete names and addresses of the above reporting companies are listed in Table 1 of the Appendix. 



MISCELLANEOUS CHEMICALS 



The term miscellaneous chemicals comprises those synthetic organic 
products that are not included in the use groups covered by the other 
preliminary reports in the 1972 series. They include products that are 
employed in a great variety of uses. The number of chemicals used ex- 
clusively for only one purpose is not large. Among the products covered 
are those used for gasoline and lubricating oil additives, paint driers, 
photographic chemicals, tanning materials, flotation reagents, refriger- 
ants, textile polymers, sequestering agents, organic fertilizers, anti- 
freeze chemicals, solvents, and acyclic intermediates. Table 1 presents 
statistics on U.S. production and sales of miscellaneous chemicals in as 
great detail as is possible without revealing the operations of individual 
producers . ^ 

Production of miscellaneous cyclic and acyclic chemicals in 1972 
amounted to 90.5 billion pounds, or il3-.9. percent more than the output of 
79.5 billion pounds reported for 1971. Sales of miscellaneous chemicals 
in 1972 amounted to 45.2 billion pounds, valued at $4.7 billion, compared 
with 38.4 billion pounds, valued at $4.1 billion in 1971. 

The total output of miscellaneous cyclic chemicals in 1972 was 2.4 
billion pounds, or 10.7 percent more than the output of 2.2 billion pounds 
reported for 1971. Sales in 1972 totaled 1.2 billion pounds, valued at 
$423 million, compared with 1.0 billion pounds, valued at $379 million, 
in 1971. In 1972, the most important groups of cyclic compounds were the 
lubricating oil additives, the output of which was 388 million pounds, and 
synthetic tanning materials, the output of which was 53 million pounds. 

Total production of miscellaneous acyclic chemicals in 1972 was 88.1 
billion pounds, or 14.0 percent more than the output of 77.3 billion pounds 
reported for 1971. Sales in 1972 totaled 44.0 billion pounds, valued at 
$4.3 billion, compared with 37.3 billion poionds, valued at $3.8 billion, 
in 1971. The statistics for acyclic chemicals are grouped primarily by 
chemical function. The order of precedence of these functional groups is 
generally that used in naming and indexing chemical compounds by Chemtoal 
Ah s tracts , but other important considerations are comparability with other 
statistics and the need for groupings that will not reveal the operations 
of individual producers. 

In 1972, the most important groups of acyclic chemicals were the 
halogenated hydrocarbons, the nitrogenous compounds, monohydric alcohols, 
and aldehydes and ketones. Production of halogenated hydrocarbons, which 
are used as solvents, intermediates, refrigerants, and aerosol propellants, 
totaled 20.1 billion pounds. The most important chemicals in this group 
were dichloroe thane (production of 7.8 billion pounds in 1972 compared with 



^ See also table 2 which lists these products and identifies the manu- 
facturers by code. These codes are given in table 3. 



200 

SYNTHETIC ORGANIC CHEMICALS, 1972 



7.6 billion pounds in 1971) and vinyl chloride (5.1 billion pounds compared 
with 4.3 billion pounds). Output of nitrogenous compounds totaled 15.5 
billion pounds. The most important chemical in this group was urea (used 
principally in fertilizers and as a feed additive), production of which was 
6.9 billion pounds in 1972 and 6.2 billion pounds in 1971. 

Monohydric alcohols, which are used largely as solvents and inter- 
mediates, were the third largest group in 1972, with production of 12.8 
billion pounds. The most important items in the group in terms of pro- 
duction were synthetic methanol (6.5 billion pounds in 19 72, compared with 
4.9 billion pounds in 1971), synthetic ethyl alcohol (1.8 billion pounds 
in 1972, compared with 1.6 billion pounds in 1971) and isopropyl alcohol 
(1.8 billion pounds in 1972, compared with 1.7 billion pounds in 1971). 
Aldehydes and ketones, which are also used largely as solvents and inter- 
mediates, were the next largest group with production of 11.3 billion 
pounds. The most important items in this group in 1972 were formaldehyde 
(5.6 billion pounds), acetone (1.8 billion pounds) and acetaldehyde 
(1.4 billion pounds). 



MISCELLANEOUS CHEMICALS 
TABLE 1. --Miscellaneous chemicals; U.S. production and sales. 1972 



[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 2 lists all miscellaneous chemicals for which data on production or sales were re- 
ported and identifies the manufacturers of each] 



Production 



Quantity 



Grand total 

MISCELLANEOUS CHEMICALS, CYCLIC 
Total 

Benzoic acid, sodium salt 

Benzoyl peroxide 

Butyl benzoate 

tert- Butyl peroxy benzoate 

2,6-Di-tert-butyl-p-cresol: 

Food grade 

Tech 

Dioxane (1,4-Diethylene oxide) 

Enzymes 

4-Ethylmorpholine 

Flotation reagents 

Gasoline additives 

Hexamethylenetetramine, tech 

p-Hydroxybenzoic acid esters: 

Butyl p-hydroxybenzoate (Butylparaben) 

Methyl p-hydro.xybenzoate (Methylparaben) 

Propyl p-hydroxybenzoate (Propylparaben) 

Lubricating oil and grease additives, total 

Oil-soluble petroleum sulfonates, total 

Oil-soluble petroleum sulfonates, calcium salt 

Oil-soluble petroleum sulfonates, sodium salt 

All other 

Phenol salts 

All other lubricating oil and grease additives 

Morpholine 

Naphthenic acid salts, total^ 

Calcium naphthenate 

Cobalt naphthenate 

Iron naphthenate 

Lead naphthenate 

Manganese naphthenate 

line naphthenate 

All other 

Photographic chemicals: 

2,5-Diethoxy-4-morpholinobenzenedia2onium chloride- 

p-Diethylaminobenzenediazonium chloride 

N , N- Diethyl toluene- 2 , S-diamine , monohydroch loride- - 

p-Dimetnylaminobenzenediazonium chloride 

p- [Ethyl (2-hydro.xyethyl)amino]benzenediazonium 

chloride 

p- [ (2-Hydroxyethyl)methylamino]benzenediazonium 

chloride 



1,000 
pounds 



90.476.062 



2,411,142 



15,266 
7,570 
5,575 
1,542 

7,517 
17,838 
15,768 

(2) 

1,595 
15,979 
45,004 
95,156 



918 
391 



388,115 



228,162 
139 458 
42,032 
46,672 
76,092 
83,861 



1,434 
3,295 

11,448 

959 

905 

2,489 



168 
119 



1,000 
pounds 

45,155.471 



1,000 
do I lavs 



4.680.222 



pound 



1,177,960 



12,185 
7.443 
5.019 
1,513 

8,471 
18,151 
6,518 

(2) 

1,379 
13,432 

61,724 



879 
367 



80,555 
70,062 



68,765 
64,485 



1,366 
3,210 
105 
10,717 
967 
776 
930 



141 
119 
299 



3,664 

7,002 

779 

1,685 

4,166 
8,642 
2,159 
25,147 
1,102 
1,693 

7,498 

50 

1,392 

690 



16,169 
10,995 



14,120 
21,402 



6,976 
5,320 



1,738 
25 

1,892 
258 
199 
828 



801 
240 
898 

147 



See footnotes at end of table 



SYNTHETIC ORGANIC CHEMICALS. 1972 • 
TABLE 1. --Miscellaneous chemicals; U.S. production and sales. 1372— Continued 



Production 



Quantity 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

a-Pinene 

fi-Pinene 

Tall oil salts: 

Cobalt tallate 

Lead tallate 

Manganese tallate 

Tanning materials, s\'nthetic 

Textile chemicals 

All other miscellaneous cyclic chemicals 

MISCELLANEOUS CHEMICALS, ACYCLIC 

Total 

Cellulose Esters and Ethers 

Total 

Cellulose esters: Cellulose acetate 

Cellulose ethers: Sodium carboxyraethylcellulose, 
100% 

All other cellulose esters and ethers 

Lubricating Oil Additives 

Total 

Phosphorodithioates (Thiophosphates) 

Sulfur compounds: Sulfurized lard oil 

All other 

nitrogenous Compounds 

Total' 

Acrylonitrile 

Amines, total 

Butylamines: 

n-Butylamine, mono- 

Di-n-butylamine 

Diethyl en etriamine 

Ethyl amines , total 

Diethylamine 

All other 

Ethyl enediamine 

1 ,6-Hexanediamine (Hexamethylenediamine) 

Methylamines : 

Dime thy I amine 

Methylamine, mono- 

Trimethylamine 

Propylamines: 

Diisopropylaraine 

Di propyl amine 

Propylamine, mono- 

Tetrae thy lenepent amine 

Triethylenetetramine 

All other 

2- (2-Aminoethylamino) ethanol (Aminoethyl- 

ethanol amine) 

Capro lac tarn 

2-Dimethylaminoethanol 



1,000 
pounds 



38,095 

1,262 

2,002 

520 

53,040 

1,585 

1,681,482 



88.064,920 



1,000 



68,962 
156,030 



67,009 

3,316 

430,088 



1,114,749 
1,276,277 



4,017 
3,842 
32,390 

55,437 
11,079 
44,358 



95,973 
33,063 
28,815 



18,011 
133,622 



8,788 

640,045 

3,533 



19,814 
29,180 

1,256 

2,056 

542 

53,310 

504 

607,606 



43.977,511 



1,000 
dollars 



2,106 
4,638 

559 

406 

143 

11,207 

1,091 

259,995 



70,991 
254,021 



21,440 

3,128 

147,979 



459 


985 


345 


803 


2 


374 


3 


121 


30 


176 



48,610 
8,449 

51,522 
23,347 
23,948 

779 
14,389 

239 

12,779 

15,466 

105,137 



6,775 
546,486 



31.243 
116,431 



6,009 

674 

23,824 



786,963 



49,259 
68,768 



670 

748 

9,697 



9,696 
3,073 

4,702 
1.984 
2,189 

165 
3,501 

183 
6,105 
5,218 
19,853 



2,603 
96,615 



MISCELLANEOUS CHEMICALS 
TABLE 1. --Miscellaneous chemicals: U.S. production and sales. 1972— Continued 



Production 



1,000 



MISCELUNEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds- -Continued 

Ethanol amines, total 

2-Aininoethanol (Monoethanol amine) 

2,2'-Aniinodiethanol (Diethanol amine) 

2, 2' ,2' ' -Nitrilotriethanol (Triethanol amine) 

Hexamethylenediammonium adipate (Nylon salt) 

Nitriloacids and salts, total 

(Diethylenetrinitrilo)pentaacetic acid, pentasodiun 

salt 

tEthylenedinitrilo)tetraacetic acid 

CEthylenedinitrilo)tetraacetic acid, disodium salt- 
(Etliylenedinitrilo)tetraacetic acid, tetrasodium 

salt 

(N-Hydroxyethylethylenedinitrilo)triacetic acid, 

tri sodium salt 

All other 

Nylon 6 and 6/6 (polymers for fiber, only) 

Pentaerythritol tetranitrate 

Polyacrylamide 

Urea in compounds or mixtures (100% basis), total — 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

All other 

All other nitrogenous compounds 

Acids, Aoyl Halides and Anhydrides 

Total 

Acetic acid, synthetic, 100% 

Acetic anhydride, 100% 

Acrylic acid 

Adipic acid 

Dodecenyl succinic anhydride 

Formic acid, 90% 

Furaaric acid 

Lauroyl chloride 

Maleic anhydride 

Pivaloyl chloride 

Poly aery lie acid 

Propionic acid 

All other acids, acyl halides and anhydrides 

Salts of Organic Acids 

Total 

Acetic acid salts, total 

Copper acetate 

Potassium acetate 

Zinc acetate 

Zirconium acetate 

All other 



82,114 
101,075 
100,742 

719,550 



3,503 
1,292 



4,635 
48,068 

1,547,238 
4,099 
19,106 

6,933,470 



679,816 
2,531,235 
2,633,970 
1,088,449 

2,803,813 



6,668,458 



2,235,406 

1,572,928 

123,195 

1,491,405 

46,894 

51,455 

5,469 

274,435 

981 

1,023 

56,046 

809,223 



333,370 



282 

5,198 

457 



1,000 
pounds 



2 34,454 



1,000 
dollars 



71,788 
71,980 
90,686 



7,682 
8,058 
11,673 



3,062 
5,056 



3,658 
34,305 



3,404 
14,418 



5,999,440 



1,550 
9,734 



2,818 
12,377 



158,623 



611,680 
2,168,443 
2,489,488 

729,829 

77S.433 



15,418 
65,101 
64,208 
13,896 

344,764 



570,787 

30,211 
143,497 
2,485 
35,348 
35,915 

190,571 

927 
38,051 
733,516 



285,631 



28,903 

6,596 
20,039 
1,037 
3,574 
6,692 

25,024 

525 

3,331 

136,154 



472 

159 

25,826 



See footnotes at end of table. 



SYNTHETIC nRGflNlC CHE'IICALS, 1972 

TABLE l.--fllSCELLA»lEOUS CHEniCALS: U.S. PRODUCTION AND SALES, 1972" 



-CONTINUED 



Quantity 



1,000 



1,000 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Salts of OTgania Acids — Continued 

2-Ethylhexanoic acid (a-Ethylcaproic acid) salts, 

total 

Calcium 2-ethylhexanoate 

Cobalt 2-ethylhexanoate 

Lead 2- ethy Ihexanoat e 

Manganese 2-ethylhexanoate 

Zinc 2-ethylhe xanoat e 

All other 

Formic acid, sodium salt (tech.) 

Gluconic acid, sodium salt 

Lactic acid salts 

Mercaptoacetic (Thioglycolic) acid, ammonium mercapto- 
acetate salt 

Oleic acid salts 

Propionic acid salts: 

Calcium propionate 

Sodium propionate 

Stearic acid salts, total'" 

Aluminum stearates, total 

Aluminum distearate 

Aluminum monostearate and tristearate 

Barium stearate 

Calcium stearate 

Lithium stearate 

Magnesium stearate 

Zinc s t eara te 

All other 

All other salts of organic acids 

Aldehydes and Ketones 

Total 

Acetaldehyde 

Acetone, total 

From cumene 

All other 

2-Butanone (Methyl ethyl ketone) 

Butyraldehyde 

Formaldehyde (37'o by weight) 

4-Ilydroxy-4-methyl-2-pentanone (Diacetone alcohol) 

4-Methyl-2-pentanone (Methyl isobutyl ketone) 

All other aldehydes and ketones 

Alcohols, Monahydric, ynsubstituted 

Total 

Alcohols, C, or lower, unmixed, total 

Butyl alcohols: 

n-Butyl alcohol (n-Propylcarbinol) 

Isobutyl alcohol (Isopropylcarbinol) 

Ethyl alcohol, synthetic'' 

2-Ethyl-l-hexanol 



18.715 



1,792 
3,362 
3,469 
996 
1,233 
7,863 

31,992 
8,915 
1,901 

1,099 
1,286 

21,395 
4,114 

70,123 



5,914 

2,719 

1,195 

389 

37,793 

887 

4,767 

19,374 

2,999 

142,193 



1,447,566 
1,818,373 



1,086,012 
732,361 



509,025 
5,651,807 



208,263 
1,651,669 



12,833,473 



12,092,504 



590,228 

96,386 

1,850,651 

526,125 



789 
1,028 
10,308 

31,214 
10,765 



16,329 
3,616 



69,722 



4,006 
2,741 
1,265 



5 


288 


18 


798 


2 


332 


09 


140 



1,495,112 



929,400 

565,712 

470,010 

50,258 

1,820,047 

46,482 

177,013 

764,707 



7,627,636 



7,004,356 



354,720 

96,634 

1,395,655 

332,135 



1,000 
do I lars 



6,982 



2,017 

237 

498 

4,230 

1,034 

2,650 

818 



3,594 
789 



25,492 



1,690 
1,122 

568 

148 
12,570 

474 
2,211 
7,419 

980 

57,227 



23,346 

37,981 
4,870 

35,106 
5,670 

18,954 

60.414 



275,478 



24,513 
4,189 
74,912 
24,309 



MISCELLANEOUS CHE^IICALS 
TABLE 1.— Miscellaneous chemicals: U.S. production and sales, 1972— Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 



Alcohols, Monohydric, Unsubstituted- -Continued 

Alcohols, Cg or lower, unmixed--Continued 

Hexyl alcohol 

Iso-octyl alcohols 

Isopropyl alcohol 

Methanol, synthetic 

1- (and 2-)0ctanol 

Propyl alcohol (Propanol) 

All other 

Alcohols, C,i) and higher, unmixed, total 

Isodecyl alcohol 

Stearyl and other octadecyl ilccrfiols 

All other 

Mixtures of alcohols, total 

Cg and lower, only 

C,|, and higher, only 

Cj to Ci2 and others'^ 

PolyhydHc Aloohols and Their Esters and Ethers 

Totalis 

Polyhydric alcohols, total 

Ethylene glycol 

Glycerol, synthetic only 

2-Methyl-2,4-pentanediol CHexylene glycol) 

Pent aery thritol 

Propylene glycol (1,2-Propanediol) 

Sorbitol 

All other 

Polyhydric alcohol esters, total 

Ethylene glycol diacetate 

All other 

Polyhydric alcohol ethers, total 

2-Butoxyethanol (Ethylene glycol monobutyl 

ether) 

2-(2-Butoxyethoxy)ethanol (Diethylene glycol 

monoisobutyl ether) 

Diethylene glycol 

Dipropylene glycol 

2-Ethoxyethanol (Ethylene glycol monoethyl 

ether) 

2- (2-Ethoxyethoxy)ethanol (Diethylene glycol 

monoethyl ether) 

2- [2- (2-Ethoxyethoxy)etho(ty]eth«Bol (Triethylme 
glycol monoethyl ether) 

2-Methoxyethanol (Ethylene glycol monoinethyl 

ether) 

2-(2-Methoxyethoxy)ethanol (Diethylene glycol 

monomethy 1 ether) 

2- [2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene 

glycol monomethyl ether) 

Polyethylene glycol 

Polypropylene glycol 

Tetraethylene glycol 

Triethylene glycol 

Tripropylene glycol 

All other ethers of polyhydric alcohols 



1,000 



16,296 

63,227 

1,790,024 

6,471,605 

13,741 

83,095 

591,126 

204,444 



147,029 

8,005 

49,410 



44,928 
447,999 
43,598 



3,761,143 
199,216 

110,087 
562,583 
121,370 
317,214 

237,961 



237,961 
2,117,239 



133,305 

24,779 
245,492 
51,773 

205,413 
41,156 
28,181 

119,106 
12,666 

31,693 

52,353 
359,238 

11,813 
105,531 

694,740 



Quantity 



1,000 
pounds 



AT ,021 

911,733 

,542,260 

10,048 

77,036 

237,108 

117,346 



63,819 
13,349 
40,178 



39,763 
j6l,644 
104,527 



5,950,570 



,113,931 
187,999 
38,554 
94,058 
538,037 
91,586 
98,626 

222.192 



5,363 
216,829 



111,218 

16,917 
184,406 
50,348 

103,648 

31,366 



85,749 

9,862 

11,162 
49,276 

6,176 

84,716 

1,928 

818,815 



1,000 
dollars 



4,201 

50,753 

51.498 

1,856 

8,272 

30,975 

19.051 



5,564 
3,517 
9,970 



4,979 
62,114 
9,550 



596,329 



334,228 



186,135 
37,167 
5,408 
15,787 
43.746 
19,515 
26,470 

42,273 



41.285 
219,828 



2 


668 


11 


146 


4 


338 


11 


777 


4 


287 



9,352 

1,217 

1,560 
10,905 

899 

9,330 

300 

136,701 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 1.— Miscellaneous chemicals; U.S. production and sales. 1972— Continued 



Production 



Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Esters of Moriohydria Alcohols 

Total 

n-Butyl acetate, unmixed 

Isobutyl acetate, unmixed 

Butyl aery late 

tert- Butyl peroxypivalate 

Dibutyl maleate 

Dilauryl 3, 3'-thiodipropionate 

Dioctyl maleate 

Distearyl 3,3'-thiodipropionate 

Ethyl acetate (85%) 

Ethyl aery late 

2-EthyI-I-hexyI aery late 

Iso-oetyl mereaptoaeetate 

Isopropyl acetate 

Methyl acetate 

Methyl methacrylate, monomer 

Phosphorus acid esters, not elsewhere specified — 

Propyl acetate 

Vinyl acetate 

All other 

Halogenated Hydrocarbons 

Total 

Carbon tetrachloride 

Chlorinated paraffins, total 

35-64% chlorine 

Other 

Chi orodi f 1 uoromethane . 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

1,2-Dibromoethane (Ethylene dibromide) 

Diehlorodifluorome thane 

1,2-Dichloroethane (Ethylene dichloride) 

Dichloromethane (Methylene chloride] 

1,2-Dichloropropane (Propylene dichloride) 

lodomethane (Methyl iodide) 

Tetrachloroethylene (Perchloroethylene) 

1,1,1-Trichloroethane (Methylchloroform) 

Triehloroethylene 

Trichlorofluoromethane 

Vinyl chloride, monomer (Chloroethylene) 

All other halogenated hydrocarbons 

All Other MisaelZanecus Acyclic Chemicals 

Total 

2-Butanone peroxide 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Carbon disulfide-, 

Epoxides, ethers, and acetals, total 

Ethylene oxide 

Ethyl ether, tech 

Isopropyl ether 

Propylene oxide 

All other epoxides, ethers, and acetals 



1,000 
pounds 



3,221,170 



1,000 



125,598 

983 

9,554 

1,355 

6,295 

1,567 

221,983 

275,344 

45,524 

8,495 



598,992 

59,494 

32,439 

1,210,703 

527,180 



20.071. 1 91 



996,687 
63,453 



48,806 
14,647 



375,513 
234,677 
453,533 
315,523 
439,224 
7,808,938 
471,276 

18 
734,216 
440,681 
426,684 
299,583 
5,088,511 
1,722,674 



4,774 

1,822 

767,830 



,961,757 
69,379 



1,520,174 
677,782 



2,031,099 



89,359 

27,296 

69,224 

970 

10,161 

1,350 

5,652 

1,459 

181,148 

99,756 

39,452 

44,897 
2,176 

53,238 

32,517 

943,401 

429,043 



50,181 
15,057 

79,982 
194,021 
202,776 
208,020 
173,378 
418,537 
1,446,707 
443,334 

40,742 

723,427 
389,028 
441,180 
286,334 
3,343,209 
180,285 



2,940,623 



4,631 

1,775 

527,636 



9,848 
("•) 
688,026 



1,000 
dollars 



265,586 



8,740 

2,964 

11,809 

1,941 

1,608 

1,022 

946 

1,125 

13,833 

15,862 

7,980 

4,630 
177 

24,596 

3,844 

65,868 



698.471 



54,792 
9,112 



6,248 
2,864 

39,202 
11,654 
13,449 
10,661 
28,795 
101,561 
38,927 
29,474 
527 

41,565 
35.475 
29,458 
52,459 
132,601 
68,759 



4,597 
1,447 
21,002 

97,962 



30,087 

926 

66,949 



MISCELLANEOUS CHEMICALS 

TABLE l.-HlSCELLANEOUS CHEMICALS: U.S. PRODUCTION AND SALES. 1972— CONTINUED 



Quantity 



Unit 
value' 



1,000 



1,000 
pounds 



1,000 
dollars 



MISCELLANEOUS CHEMICALS, ACYCLIC— Continued 
All Other Miscellaneous Aayalio Chemicals — Continued 



Organo- silicon compounds, total- 
Silicon fluids 

Other organo-silicon compounds- 



Phosgene (Carbonyl chloride) 

Sodium methoxide (Sodium methylate)- 

Tetraethyllead 

Other organo-lead compounds 

All other 



74,722 
114,735 

637,043 
5,172 
302,371 
670,105 
407,190 



52,707 
31,096 

11,678 

8,177 

310,834 

650,439 

189,480 



53,167 
54,145 

1,423 

1,797 

165,463 

349,448 

54,858 



Per 
pound 



$1.28 



1.01 
1.74 



.53 
.54 



' Calculated from rounded figures. 
^ Not available. 

' Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given 
with "Plasticizers." 

"* Quantities are given on the basis of solid naphthenate, tallate, or linoleate content. 

' Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given 
with "Pesticides and Related Products." 

^ Ethylcellulose which was formerly included with cellulose ethers is now included with cellulosic plastics 
materials. 

' Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given with "Surface- 
Active Agents." 

° Production of urea in primary solution totaled 7,096,187 thousand pounds. 
' Includes estimated values for sales of urea in nitrogen compounds. 
'° Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 
included with "Surface-Active Agents." 

" Statistics en production of ethyl alcohol from natural sources by fermentation are issued by the Department of 
Treasury, Bureau of Alcohol, Tobacco, and Firearms. 

'^ Of the total production, about 45 percent consisted of alcohols lower than Cjo and about 55 percent consisted, 
of alcohols Cio and higher. 

'^ Some polyols which are used as intermediates for urethanes have been included with "Plastics and Resin 
Materials ." 
'" Sales quantity of propylene oxide in 1971 was 237,710,000 pounds (instead of 37,710,000 pounds). 



SYNTHETIC ORGANIC CHEniCALS, 1972 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972 

[Miscellaneous chemicals for which separate statistics are given in table 1 are marked with an asterisk (*) ; 
chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not 
be published. Hanufacturers ' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, CYCLIC 

6-Acetoxy-2,4-dimethyl-l ,3-dioxane 

Acetylcyclohexanesulfonyl peroxide 

Adenosine and derivatives 

3- t3"-Aminobenzamide)-l- (2' ,4' ,6'-trichlorophenyl) -5- 

pyrazole. 

2-Aminobenzothiazole 

1- (2-Aminoethyl)piperazine 

1- (3-Aminopropyl)morpholine 

Amyl p- dime thy laminobenzoate 

Benzatriazoles , substituted 

*Benzoic acid, sodium salt 

p- Benzoquinone (p-Quinone ) 

Benzothiazole 

♦Benzoyl peroxide 

Biological stains 

BisC2,4-dichloroben2oyl) peroxide 

1,8- Bis- faimethy 1 amino ^naphthalene 

Bis (a,a-dimethylbenzyl) peroxide 

2, 4- Bis (4-hydroxy-3,5-di-tert-butylphenoxy)-6-(n-octyl- 

thio)-l ,3,S-triazine. 
2, 4- Bis (n-octylthiol-6- (4 '-hydroxy- 3' ,5'-di-tert-butyl- 

anilino)-l ,3,S-triazine. 

Boron fluoride-phenol complex 

*Butyl benzoate 

p-tert-Butylbenzoic acid, barium bis-salt 

2 (and 3)-tert-Butyl-4-methoxyphenol 

*tert- Butyl peroxybenzoate 

4-tert-Butylpyrocatechol 

Camphene 

Cellulose acetate phthalate 

Centralite-1 (N,N'-Diethyl-N,N'-diphenylurea;'- 

Chemical indicators and reagents 

Chloramine B (Sodium derivative of N-chlorobenzenesulfon- 

amide) . 
l-(3-Chlorallyl)-3,S,7-triaza-l-a2oniaadamantane 

chloride. 

o-Chlorobenzamalononitrile 

Chlorophyllin, sodium-potassium- copper 

Cumene hydroperoxide 

Cyanuric acid 

1 ,3-Cyclohexadiene 

Cyclohexane sulfamic acid 

Cyclohexanone peroxide 

Cyclohexene-1 ,2-dicarboxylic acid (Tetrahydrophthalic 

acid) disubstituted, polyester salts: Barium and 

cadmium salts . 

Cyclohexyl chloride 

1 ,4-Cyclohexylenedimethanol 

Cyclopropane 

Cytidine and derivatives 

Decahydronaphthaie'-e (Decalinl 

Dehydroacetic acid or sodium salt 

2,5-Di-tert-amylhydroquinone 

l,4-Diazobicyclo(2.2.2)octane 

Diazodinitrophenol 

2,S-Di (benzoylperoxy)-2,5-dimethylhexane 

Di- and tribroraosalicylanilide 

Dibroraodimethylhydantoin 



CAD, NOC, RCI, IVTC, WTL. 
WTL. 



niv. 

WTL. 
PLB. 



PUT. 

UCC. 

JCC. 

VND. 

CGY. 

HN, MON, PFZ, VEL, WSN 

EKT. 

ACY. 

AZT 

ACS 

CAD 

ALD. 

WTL. 

CGY. 

CGY. 

ACS. 

CPS, PFZ, TCC, VEL. 

CCA. 

EKT. 

AZT, CAD, NOC, WTC, WTL. 

BKL, DOW. 

GLD, HN, HPC. 

OTC. 

ACS, EK, FIN, GFS, LAH, NEP. 

NES. 

DOW. 

FIS. 

KCH. 

ACP, HPC, RCI. 

FMB. 

ALD. 

ABB. 

AZT, NOC, WTL. 

RCI. 



X. 

EKT. 

OH, TAE. 

PLB. 

DUP. 

GAN, UCC. 

EKT. 

AIP. 

HPC. 

WTL. 

FIN. 

ARA. 



MISCELLANEOUS CHEMICALS 
TABLE 2.— Hiscellaneous cHEnicALS for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTI NUED 



Manufacturers' identification codes 
[according to list in table 3) 



HISCELLANEOUS CHEMICALS, CYCLlC--Continued 

2,6-Di-tert-butyl-p-cresol : 

*Food grade 

*Tech 

2,5-Di-tert-butylhydroquinone 

Di-tert -butyl diperoxyph thai ate 

1 ,3-Dichloro-5 ,5-dimethylhydantoin 

Dichloro-s-triazine-2,4,6ClH,3H,SH)trione (Dichloroiso- 
cyanuric acid), and salts. 

4,4' -Dichloro-3- (trifluoromethyl}carbanilide 

2,S-Dihydrothiophene- 1 ,1- dioxide (Sulfolene) 

2,2'-Dihydroxy-4,4'-dimethoxybenzophenone 

3,S-Dihydroxy-3,S-dimethyl-l,2-peroxycyclopentane 

2,6-Dihydroxyisonicotinic acid (2,6-Dihydroxy-4-carboxy- 
pyridine) . 

2,2'-Dihydroxy-4-methoxyben2ophenone 

Diiodomethyl-p-tolyl sul phone 

Diisopropyl benzene hydroperoxide 

Di i s opropy 1 ere sols 

Diketene 

p-Dimethoxybenzene (Dinethyl ether of hydroquinone) 

2,5-Dimethyl-2 ,4-hexadiene 

2 ,6-Dimethylmorpholine 

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyriiiiidinol 

Di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyphenyl phos 

phonate. 
1 ,2-Dioctylcyclobutane-3,4-bis(octaraethyleneisocyanate)-- 

*Dioxane (1,4-Diethylene oxide) 

1 , 3-Dioxolane 

Diphenylisodecyl phosphite 

Dipropylene glycol salicylate 

4 - (Dodecy loxy) - 2-hydroxybenzophenone 

*Enzymes : 

Hydrolytic: 

Amylases 

Proteases 

Other 

Nonh yd ro lytic 

1 ,2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether) 

Ethyl cellulose phthalate 

Ethyl-a-cyano-6-pentyl«innamate 

2-Ethylhexyl benzoate 

2-Ethylhexyl p- dime thy laminobenzoate 

Ethylidene norbomene 

*4-Ethylmorpholine 

*Flotation reagents: 

Dicresylphosphorodithioic acid (Dicresylthiophosphoric 
acid) . 

Dicresylphosphorodithioic acid, ammonium salt 

Dicresylphosphorodithioic acid, sodium salt 

2,2'-Dimethylthiocarbanilide (Di-o-tolyl thiourea) 

Rosin amines 

Tall oil derived 

Thiocarbanilide (Diphenyl thiourea) 

Furan derivatives: 

2-Furaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid 



ASH, HPC, KPT, SHC, USR. 

ASH, HPC, KPT, PRD, SHC, USR. 

EKT. 

WTL. 

GLY. 

FMB. 

CGY. 
PLC. 
GAF. 
WTL. 
EK. 

ACY. 

ABB. 

HPC. 

GIV. 

ALD, EKT, FMP. 

ASL, EKT, GAF. 

BPC. 

DOW, UCC. 

MRK. 

CGY. 



DOW, FER, UCC. 
FER. 



SBC. 
DUP, EKT. 



BAX, 
BAX, 
BAX, 
MLS, 

nup. 

EK. 
GAF. 

X. 

VND. 
UCC. 
BRD, 

ACY. 



ACY. 

KCU. 

DUP, RBC. 

HPC. 

HN. 

ACY. 



CRN, GPR, MLS, PFZ, mP , RH. 

CHH, DOL, MLS, PEN, PFZ, PMP, SPR. 

JFR, MLS, PFZ, RH, WBC. 

OMS, PLB, SPR. 



QKO. 
QKO. 



SY^ITHETIC ORri/\NIC CHEMICALS. 1972 

TABLE 2.--niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED^ 
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3] 



mSCELLANEOUS CHEMICALS, CYCLIC--Continued 

♦Gasoline additives: 

N,N'- Bis (1,4-dime thy lpentyl)-p-phenylenedi amine — 

Butylphenols, mixed 

N-sec-Butyl-N-phenylphenylenedi amine 

4,4'-Di-5ec-butylaminodiphenylmethane 

6-tert-Butyl-o-cresol 

2,6-Di-tert-butylphenol 

N,N'-Di-sec-butyl-p-phenylenediamine 

2,6-Di-tert-butyl-a-dimethylamino-p-cresol 

N,N'-Dicyclohexyl-p-phenylenediamine 

2, 6- Diethyl aniline 

N,N'-Diisopropyl-p-phenylenedi amine 

N,N'-Disalicylidene-1 ,2-propanediamine 

Methyl eye lopentadienylmanganese tricarbonyl 

4,4' -Methylenebis C2,6-di-tert-butylphenol) 

4,'4'-Thiobis C6-tert-butyl-o-cresol) 

2,2'-Thiobis(6-tert-butyl-p-cresol) 

l,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)- 
mesitylene. 

Other 

Glyceryl p-aminobenzoate 

Guanosine and derivatives 

N-Heptyl-p-hydroxybenzoate 

*Hexamethylenetetramine, tech 

Homomenthyl salicylate 

Hydrab amine hydrobromi de 

Hydrindan t in 

p-Hydroxybenzoic acid esters: 

Benzyl p-hydroxybenzoate 

*Butyl p-hydroxybenzoate CButylparaben) 

Ethyl p-hydroxybenzoate (Ethylparaben) 

n-Heptyl p-hydroxybenzoate [Heptylparaben) 

*Methyl p-hydroxybenzoate (Methylparaben) 

*Propyl p-hydroxybenzoate (Propylparaben) 

Other 

N-(Hydroxyethyl)piperazine 

2-Hydroxy-4-methoxybenzophenone 

Hydroxymethyl dimethyl-5 ,5-hydantoin 

2-Hydroxy-3-phenoxytiropane 

2- (2-Hydroxy-S-tert-octylphenyl)benzotriazole 

1 -Hydroxy- 2-Dyridine (Omadine) 

1 ,2,3-Indantrione monohydrate (Ninhydrin) 

Inosine and derivatives 

2-(p-Iodophenyl)-3- (p-nitrophenyl)-5-phenyl-2H- 
tetrazolium chloride. 

Isopropyl-o-cresols 

'Lubricating oil and grease additives: 
*Oil-soluble petroleum sulfonates: 

Oil-soluble petroleum sulfonate, ammonium salt-- 

Oil-soluble petroleum sulfonate, barium salt 

*Oil-soluble petroleum sulfonate, calcium salt — 
Oil-soluble netroleum sulfonate, magnesium salt- 

*Oil-soluble petroleum sulfonate, sodium salt 

•Other 

*Phenol salts : 

Barium alkylphenolates 

Calcium alkylphenolates 

Calcium salt of octylphenol-formaldehyde 

Other '- 

All other 

p-Menthane 

8-p-Menthyl hydroperoxide 

p-Methoxybenzylidenemalonic acid, diethyl and 
dimethyl esters. 



EKT 




DOW, 


TNA. 


X. 




X. 




TNA 




TNA 




DUP 


EKT. USR, X. 


TNA. 




X. 




TNA. 




DUP 


EKT, USR. 


DUP 


SM, TX. 


TNA. 




TNA. 




TNA. 




ASH. 




TNA. 




EKT, 


SM, TNA, X. 


VND. 




PLB. 




WSN. 




BOR, 


DUP, HKD, HN, HMP, PLS, UCC 


ARS. 




ABB. 




HEX. 




RSA. 




HN, 


LEU, WSN. 


UN, 


W.SN. 


WSN. 




ARS, 


HN, LEM, WSN. 


ARS, 


HN, LEM, WSN. 


WSN. 




UCC. 




ACY, 


GAP. 


GLY. 




TCH. 




ACY. 




OMC. 




HEX, 


PIC. 


PLB. 





MOR, NTL. 

CO, LUB. 

CO, ENJ, LUB, DRO, PAR, TX, WTC, x. 

CO, LUB. 

CO, ENJ, MOR, PAR, SHC, SOC, SOI, WTC. 

CO, LUB, TX. 

TX. 

ORO, TX. 

SHC. 

CCA, ENJ, GOC, ORO, TX, x. 

ATR, ENJ, GOC, LUB. ORO, PLC, SM, TX, UCC. 

HPC. 

HN, HPC. 

ACY. 



MISCELLANEOUS CHEMICALS 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table Z) 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

4-Methoxyphenol 

Methyl o-cresotinate 

2,2'-Methylenebis(4-chlorophenol) (Dichlorophene) 

Methylenebis(phenoxypropanol) 

2,2'-Methylenebis(3,4,6-trichlorophenol) (Hexachloro- 
phene) . 

Methyl gal late 

Methylglucoside 

4-Methylmorpholine 

Methyl phenyl phosphates 

4-Methylpiperazine 

l-Methyl-2-pyrrolidone, monomer 

*Morpholine 

Morpholine salt of p-toluenesulfonic acid 

*Naphthenic acid salts: 

Aluminum naphthenate 

Barium naphthenate 

Cadmium naphthenate 

*Calcium naphthenate 

Chromium naphthenate 

Cobalt lead manganese naphthenate 

*Cobalt naphthenate 

*Iron naphthenate 

Lead manganese naphthenate 

*Lead naphthenate 

Lithium naphthenate 

*Manganese naphthenate 

Nickel naphthenate 

Rare earths naphthenates 

Sodium naphthenate 

Strontium naphthenate 

*Zinc naphthenate 

1-Naphthenyl- 2- tallow diamine ^ 

Ninhydrin 

Norcamphor 

Octadecyl-3- (3,S-di-tert-butyl-4-hydroxyphenyl)- 
propionate. 

Organic mercury compounds: Phenylmercuric borate 

Phenetole ■■ 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2- (2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl 
ether) . 

2-Phenoxypropanol 

2,2'- (p-Phenylene)diethanol 

m-Phenylene isonaph thai amide 

Phenyl hydrogen phosphate 

5- Phosphorylribose-1 -pyrophosphate 

Photographic chemicals: 

N-(o-Acetamidophenethyl)-l-hydroxy-2-naphth amide 

N- [2- (4-Amino-N-ethyl-m-toluidino)ethyl]methane- 
sulfonamide. 

2- (4-Amino-N-ethyl-m-toluidino)ethyl sulfate 

3-Amino-l,2,4-triazole 

Benzotriazole 

a-Benzoyl-o-methoxyacetanilide 

p-Benzylaminophenol hydrochloride 

Catechol 

2 - Ch 1 oro- N, N- die thy 1-p-phenylene diamine hydrochloride- 
3-Chloro-4-diethylaminobenzenedia2onium salts (p- 
Diazo-2-chloro-N,N-diethylaniline salts) . 

Chlorohydroquinone 

2,4-Diaminophenol dihydrochloride (Amidol) 



ARS, ASL, EKT. 

TCC. 

GIV, GLY. 

JCC. 

GIV. 

HSH. 

CRN. 

JCC, UCC. 

TNA. 

UCC. 

GAP. 

DOW, JCC, UCC. 

AMB. 



WTC. 



CCC, FER, HN. MCI, SHP, TRO, IVTC. 



CCC, FER, HN, MCI, TRO, WTC. 

CCC, HN, MCI, TX, WTC. 

CCC, FER, MCI. SHP, TRO, TX, WTC. 

MCI. 

CCC, FER, HN, MCI, SHP, WTC. 



CCC, FER, HN, MCI, SHP, WTC. 



SHP, 

CCA. 

CCA. 

CCA, 

MCI. 

HN. 

CCA, 

CCA, 

CCA. 

CCA, 

CCA, 

CCA, 

CCA. 

CCA, 

CCA. 

CCA. 

CCA, 

,SM. 

HEX. 

ALD. 

CGY. 



TRO. 

RSA. 

DOW, JCC, TCH. 

DOW. 

JCC. 
EKT. 
DUP. 

HDG, SM. 
PLB. 

EKT. 
EKT. 

EKT. 

FHT. 

EK, FHT, MRT, SW. 

EKT. 

EK. 

RSA. 

IDC. 

ESA, FMT. 

EK. 
VPC. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972--C0NT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

Photographic chemicals--Continued 

2N-(2,4-Di-tert-amylphenoxyacetamido)-4,6-dichloro- 
m-cresol . 

4-Diazo-2,5-diethox>Tiiorpholinobenzene 

4-Diazo-3,5-diethoxythiocresol salts 

*2,5-Diethoxy-4-morpholinobenzenediazoniujn chloride- 



*p-Diethylaminoben2enediazonium chloride 

p-Diethylaminobenzenediazonium fluoborate 

p-Diethylaminobenzenediazoniiun fluophosphate 

N,N-Diethyl-p-phenylenedi amine hydrochloride 

*N,N-Diethyltoluene-2,5-diamine, monohydrochloride — 
2,5-Dihydroxy-p-benzenedisulfonic acid dipotassium 

salt. 

2,S-Dihydroxybenzenesulfonic acid 

*p- Dime thy 1 ami nobenzenediazonium chloride 

2(p-Dimethylaminostyryl)-5-methylthiadiazole-5- 

6-hydrox\'ethochloride. 

2,5-Dimethylbenzothiazole 

4N- (2' ,6 '- Dime thy lmorpholinyl)benzenediazoni urn 

chloride. 

p-Diphenylaniinediazonium sulfate 

p- (N-Ethylbenzimido)benzenediazonium chloride 

*p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium 

chloride. 
N-Ethyl-N-hydroxye thy 1-p-phenylenedi amine sulfate — 
3- (4'-Hexadecenylmonoamidosuccinic acid) -1-hydroxy- 

4-sulfo-2-N-n-octadecyl)naphthamide. 

Hy droquinone (Hydroquinol) 

*p[(2-Hydroxyethyl)inethylamino]benzenediazoniuiii 

chloride. 

N- C2-Hydroxyethyl)-6-resorcylamide 

2-Hydroxynaphthoic alky 1 amide 

1- (3-Hydroxyphenyl)urea 

4-Methoxy-l-naphthol 

p-Methylaminophenol sulfate 

5-Methylbenzotriazole 

5-Methyl-l,7-dihydroxy-l ,3,4-triazaindolizine 

4-Methy 1-2 (p-bis-hydroxyethyl aminos tyryl)thiazole- 3- 

B-hydroxye thoch lori de . 

4-Methyl-l-phenyl-3-pyrazolidinone 

2-Methylthiazoline 

4-Morpholinylbenzenediazonium salts 

p-Morpholinyl-2 ,5-dibutoxybenzenediazonium chloride- 

6-Nitrobenzimidazole 

Octylphenyl salicylate 

N-Phenyl- (p-phenylene}diamine monohydrochloride 

l-Phenyl-3-pyrazolidine 

l-Phenyl-3-pyrazolidone 

4-Phenylpyrocatechol 

1 -Phenyl- 2- tetrazoline-S-thi one 

2- (Phenyl thio)quinoline 

4N- (l-Pyrrolidyl)-ra-toluenediazonium chloride 

2-Resorcylic monoethanol amide 

2,2' ,4,4'-Tetrahydroxydiphenyl sulfide 

4,4'-Thiodiresorcinol 

l-(2,4,6-Trichlorophenyl)-3-(4-nitroanilino)-2- 

pyrazolin-5-one. 

All other 

Phthalic acid, lead salt, dibasic 

Picramic acid, sodium salt 

Pine oil, synthetic 



X. 

FMT. 

FMT. 

ALL, ESA, HST. 

ESA, FMT, IDC, MRT. 

IDC. 

IDC. 

EKT. 

EKT, FMT, IDC. 

EK. 



ESA, FMT, IDC. 



FMT. 
IDC. 

F^^T. 

FMT. 

ESA, FMT, IDC. 



EKT. 

ESA, FMT, IDC. 

MRT. 
FMT. 
FMT. 

X. 

EK. 
EK. 
FMT. 



WAY. 

FMT. 

IDC. 

IDC. 

EK, FMT. 

EKT. 

EK. 

CCY. 

WAY. 

X. 

EK. 

EK. 

IDC. 

FMT. 

FMT. 

BKC. 

EKT. 

EK, ESA, FMT, IDC, NES, x, x. 

NTL. 

SDC. 

GLD. 



niSCELLANEOUS CHEMICALS 

TABLE 2,--niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972 — CONT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



niSCELLANEOUS CHEMICALS, CYCLIC--Continued 

*a-Pinene 

*g-Pinene 

Pinene, sulfate 

Pinene, wood 

Piperazine, ethoxylated 

Poly-4- (2-acryIoxyethoxy)-2-hydroxybenzophenone 

Polydodecylbenzenesulfonic acid, calcium salt 

Polyethylene tereph thai ate 

Polyphenol esters 

Polyvinyl ph thai ate 

Propyl gall ate 

Pyrogallol (Pyrogallic acid) 

2- Pyrrol idinone 

Resorcinol monobenzoate 

Rosin acid salts : 

Aluminum resinate 

Calcium resinate 

Calcium zinc resinate 

Zinc resinate 

Salicylanilide 

Salicylic acid, lead salt 

Salvenol 

Sodium cresoxide (Cresylic acid, sodium salt) 

Styrene oxide 

Sucrose benzoate 

Sulfinol blends 

Sulfosalicylic acid 

Tall oil, chemically modified 

Tall oil salts (Linoleic- rosin acid salts): 

Calcium manganese tallate 

Calcium tallate 

♦Cobalt tallate 

Copper tallate 

Iron tallate 

Lead manganese tallate 

*Lead tallate 

•Manganese tallate 

Zinc tallate 

All other 

Tannic acid 

'Tanning materials, synthetic: 

Cresol phenol formaldehyde condensate 

Hydroxytoluenesulfonic acid, formaldehyde condensate 

(Cresol- formaldehyde sulfonate), sodium salt. 
1-Naphthalenesulfonic acid, formaldehyde condensate 

and salt. 
2-Naphthalenesulfonic acid, formaldehyde condensate 

and salt. 
l-Phenol-2-sulfonic acid, formaldehyde condensate 

(Phenol-formaldehyde, sulfonated) . 
Styrene-maleic anhydride interpolymer, partial sodium 
salt. 

All other 

Tetrabromobisphenol A 

2,3,5,6-Tetrachloro-4- (methylsulfonyl) pyridine 

1,2,3,4-Tetrahydronaphthalene (Tetralin) 

Tetrahydrothiophene 

Tetrahydrothiophene-1 ,1-dioxide (Sulfolane) 

Tetrakis [methylene-3- (3' ,5'-di-tert-butyl-4'-hydroxy- 
phenol) propionate] methane. 

1 ,3,6,8-Tetranitrocarbazole 

Tetraphenyltin 



ARZ, 

ARZ, 

HPC. 

HPC. 

GAF. 

ACY. 

CO. 

DUP, 

HON. 

EK. 

EKT, 

HSH, 

GAF. 

EKT. 



HN, NCI. 

CBY, GLD, HN, HPC, NCI. 



EK, EKT, GYR. 



HSH. 
MAL. 



JMS. 

CBY, HN. 

CBY. 

HN. 

FIN, PCW. 

NTL. 

HPC. 

DEX, GOC. 

UCC. 

VEL. 

PLC. 

MON, HRK. 

ZGL. 



CCC, HN, MCI, TRO, WTC. 

CCC, PER, HN, MCI, SMP, TRO, WTC. 

MCI, SHP. 



CCC, FER, HN, MCI, SHP, WTC. 
CCC, FER, HN, MCI, SHP, WTC. 



MCI. 
CCA, 
CCA, 
CCA, 
CCA. 
MCI. 
CCA, 
CCA, 
MCI. 
WTC. 
MAL. 



DA. 
CGY, DA. 

DA. 

AKS, GRD, HN, RH. 

RH. 

DUP. 

CGY, HN. 

GTL. 

DOW. 

DUP, UCC. 

PAS. 

PLC. 

CGY. 

SDC. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONT INUED 



Haoiufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

♦Textile chemicals, other than surface- active agents: 

Dimethyloldihydroxy ethylene urea 

1- [(Octadecyloxylmethyllpyridinium chloride 

Phenol, sulfurated 

Tetrahydro-3,5-bis(methoxyTnethyi;)-4H-l,3,5-oxadiazin- 
4-one (l,3-Bis(niethoxymethyl)uron) . 

2,2' ,4,4'-Tetrahydroxybenzophenone 

Tri(Phenyloxyme thy l)trimethyloxymethylmel amine 

2,2'-Thiobis(4,6-dichlororophenol) 

[2,2'-Thiobis(4-octylphenolate)]-n-butylamine nickel--- 

Thiophene 

Thymidine and derivatives 

o-Toluidine formaldehyde hydrochloride 

Trial lyl cyanurate 

3,4' ,5-Tribromosalicylanilide 

3,4, 4'-Trichlorocarbanilide 

Trimethylaminoethylpiperazine 

3,5,5-Trimethyl-2-cyclohexen-l-one (Isophorone) 

2,4,6-Trinitroresorcinol and lead derivative 

s-Trioxane 

Triphenyl phosphite 

Triphenyl sulfonium chloride 

Triphenyl tin 

Triphenyltin phosphine 

Uridine derivatives 

Vinyl norbornene 

l-Vinyl-2-pyrrolidinone, monomer and polymer 

l-Vinyl-2-pyrrolidinone - acr>'lic copolymers 

l-Vinyl-2-pyrrolidinone - ethylacrylate, copolymer 

l-Vinyl-2-pyrrolidinone - methylacrylic acid - 
dimethylamine ethyl ester, copolymer. 

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer 

l-Vinyl-2-pyrrolidinone - other copolymers 

MISCELLANEOUS CHEMICALS, ACYCLIC 

Cellulose Esters and Ethers 

♦Cellulose esters: 

♦Cellulose acetate 

Cellulose acetate butyrate 

Cellulose acetate propionate 

Cellulose propionate 

♦Cellulose ethers": 

Hydroxyethylcellulose 

Hydroxypropylcellulose 

Methylcellulose 

♦Sodium carboxymethylcellulose, 100% 

All other 



DUP. 
GAP. 
DEX. 

GAP. 

X. 

SDH. 

ACY. 

PAS. 

PLB. 

RBC. 

ACY. 

FIN, PCW, SW. 

MON. 

JCC. 

ENJ, UCC. 

RBI. 

CEL. 

MON. 

PIS. 

X. 
X. 

PLB. 
UCC. 
GAP. 
GAP. 
GAP. 
GAP. 

GAP. 
GAP. 



AV, CEL, DUP, EKT. 

EKT. 

EKT. 

CEL. 

UCC, X. 

X. 

DOW. 

BUK, DUP, KON, WMP, WYN, 

EK, UCC. 



MISCELLANEOUS CHEMICALS 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported 

IDENTIFIED BY MANUFACTURER^ 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Lubpioating Oil Additives 

*Phosphorodithioates (Thiophosphates) : 

Di-2-ethylhexylphosphorodithioic acid 

Di-N-propylphosphorodithioic acid 

Zinc alkyl dithiophosphate 

Zinc dialkyl phosphorodithioate 

Zinc di (butylhexyl) phosphorodithioate 

Zinc dihexyl phosphorodithioate 

Zinc diisopropyl dihexyl phosphorodithioate 

Zinc hydrocarbon dithiophosphate 

Polybutylene 

Sulfur compounds : 

Aliphatic hydrocarbon sulfides 

Chlorosulfurlzed sperm oil 

Phosphosulfurized polybutene 

*Sulfurized lard oil 

Sulfurized sperm oil and substitutes 

Other sulfur compounds 

All other 

NitTogenous Ccmpounds 

Acetamide 

Acetamidine hydrochloride 

Acetamidoethanol (N-Acetyl-ethanolamine) 

Acetonitrile 

Acrylomide monomer 

*Acrylonitrile 

Acyclic isocyanates (complex) 

Adiponitrile 

1-Allyl- 3- (2-hydroxyethyl) -2- thiourea 

Allyltriraethylaimnonium chloride 

'Amines: 

Allyl amines 

Butyl amines : 

*n-Butylamine, mono- 

*Di-n-butylamine 

Diisobutyl amine 

tert-Butylamine, mono- 

Tri-n-butyl amine 

n-Butylethyl amine 

Diethylaminoe thy 1 amine 

*Diethylenetri amine 

N' ,N '- Die thy 1-1, 4 -pent anedi amine (Novoldi amine) 

Die thy laminop ropy 1 amine 

Dimethylaminop ropy 1 amine 

1 ,3- Dime thy Ibutyl amine 

Dipropylenetri amine 

*Ethylamines : 

*Diethylamine 

Diethyl amine hydrochloride 

Ethylamine, mono 

Triethylamine 

•Ethylenedi amine 

Ethylenedi amine salts 

(2-Ethylhexyl) amine, mono- 

*1 ,6-Hexanedi amine (Hexamethylenediamine) 

3,3'- Imi nob ispropyl amine 



SFA. 

SFA. 

SM. 

EN J. 

ORG. 

ATR, MON. 

X. 

LUB. 
EN J. 

LUB. 

CCW. 

EN J. 

CCW, GOC, QCP, WBG. 

CCW. 

ATR, CCW, ENJ, HK, SM, TX. 

ALX, ATR, ENJ, GOC, LUB, MON, NLC, ORG, SM, SOI, UCC, 



ACS. 
HRK. 
RBC. 
EKX, 
ACY, 
ACY, 
MOB. 
DUP, 
FMT, 
VAC. 



MON, SOH. 

SOH. 

BFG, DUP, MON. SOH. 

MON. 
IDC. 



SHC. 

AIP, PAS, UCC, VGC. 

AIP, PAS, UCC, VGC. 

AIP, PAS, VGC. 

MON, RH. 

PAS, VGC. 

PAS. 

PD. 

DOW, JCC, UCC. 

SDH. 

UCC. 

JCC, UCC. 

PAS. 

UCC. 

AIP, PAS, UCC. 

BKL, EK. 

AIP, PAS, UCC. 

AIP, PAS. UCC. 

DOW. JCC, UCC. 

EK. 

VGC. 

CEL, DUP, ELP, MON. 

JCC. 



SYNTHETIC OPnANIC CHEMICALS. 1972 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Coripounds--Continued 

* Amines --Continued 
Isopropylamines : 

*Diisopropylajnine 

Isopropylainine , mono- 

Methylamines: 

*Dime thy 1 amine 

Dimethyl amine hydrochloride 

Dimethyl amine sulfate 

*Methylamine , mono- 

Methylamine hydrochloride 

*Trimethylamine 

n-Octylamine, mono- 

Oleylamine 

Pentaethylenehexamine 

Pentylamines (Amylamines) : 

Dipentylamine 

Pentylamine, mono- 

Tripentylamine 

Poly alky lene polyamines 

1 ,2-Propanedi amine (Propyl enediamine) 

1 , 3- Prop anedi amine (1,3-Diaminopropane) 

Propylamines : 

*Dipropyl amine 

*Propylamine , mono- 

Trip ropy lamine 

*Tetraethvlenepent amine 

N,N,N ,N -Tetramethyl- 1 ,3-butanediamine 

Tetramethyle thy lenedi amine 

*Triethylenetetramine 

Other amines 

2 - Amino- 1-butanol 

2-Aminoethanol (Monoethanolamine) sulfite 

Aminoethoxyethanol 

*2- (2-Aminoethylamino)ethanol (Aminoethylethanolamine) - 
2-Aminoethyl mercaptoacetate (Monoethanolamine thio- 
glycolate) . 

2-.'Vmino-2-ethyl-l ,3-propanediol 

.^minoguanidine bicarbonate 

2-Amino-2- (hydroxymethyl) -1 , 3-propanediol (Tris- 
(Hydroxymethyl'jaminomethane) . 

2 -Amino- 2- me thy 1-1, 3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Amino-2-methyl-l-propanol hydrochloride 

l.l'-Azobisformamide 

2,2'-Azobis[2-methylpropionitrile] (Azobisisobutyro- 
nitrile) . 

Bilirubin 

1,3-Bis (hydroxymethyl)urea (Dimethylolurea) 

N,0-Bis ( trimethy 1 si lyl)acet amide 

Biuret 

N-Bromoacet amide 

N-Bromosuccnimide (Succinibromimide) 

2-Butanone oxime 

But yldiethano lamine 

1- Butyl- 3- ethyl -2- thiourea 

Butyl Lsocyanate 

Butyraldehyde oxime 

n-Butyronitrile 

*Caprolactam (2-Oxohexamethylenimine) 



AIP, PAS, UCC. 
AIP, PAS, UCC. 

AIP, COM, DUP, GAP. 

EK, RSA. 

DUP, RH. 

AIP, COM, DUP, GAP. 

EK, RBC. 

AIP, COM, DUP, GAP. 

VGC. 

X. 

JCC, UCC. 



PAS, 


VGC. 




ALB, 


PAS. 




PAS. 






NLC. 






UCC. 






JCC, 


X. 




AIP, 


PAS, 


UCC, VGC. 


PAS, 


UCC, 


VGC. 


PAS, 


VGC. 




DOW, 


JCC, 


UCC. 


UCC. 






RH. 






DOW, 


JCC, 


UCC. 


ALB. 


ALD, 


BKL, CGY, DUP, EK, NES, NIL, ONX, PAS, PIC 


SNW, UCC, VGC, X. 


COfL 






EVN, 


VND. 




JCC. 






DOW, 


HDG, 


JCC, UCC. 


EVN, 


HAB. 




COM. 






COM. 






COM. 






COfL 






COM. 






VAL. 






FMT, 


NPI, 


USR. 


DUP. 






PFN. 






GLY, 


X. 




PIC. 






DOW. 






ARA. 






ARA, 


SDW. 




ACP. 






PAS. 






PAS. 






OWN, 


OTC, 


UPJ. 


ACP. 






EKX. 






ACP, 


CNP, 


DEC. 



MISCELLAMEOUS CHEMICALS 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 
Nitrogenous Compounds--Continued 

Chlorocholine chloride 

2 -Chloro-N,N- dimethyl ethyl amine (Dime thy laminue thy 1 
chloride) hydrochloride. 

3 - Ch 1 or o-N,N- dimethyl propyl amine 

2-Chloro-N,N-dimethylpropylamine hydrochloride 

3-Chloro-N ,N-dimethylpropylamine hydrochloride 

3-Chloro-2-hydroxypropyltrimethyl ammonium chloride-- 

Chloro-N- (2-hydroxyethyl)acet amide 

N-Chlorosuccinimide (Succinichlorimide) 

2-Chloro-N ,N-diethylethylamine hydrochloride 

Choline base 

Choline bicarbonate 

Choline bisulfite 

Coco nitrile 

Coconut oil acids - ammonium condensate 

Coconut oil amide 

Creatine and creatinine 

Crotononitrile 

Cyanoacetic acid 

2-Dibutylaminoethanol 

1 , 3- Dibuty 1-2- thiourea 

1,4-Dicyanobutene 

Diethanolamine polyoxypropylene ether 

2-DiethyIaminoethanol 

2- (2- Diethyl aminoethoxy)ethanol 

2-Diethylaminoethyl aery I ate 

2-Diethylaminoethyl methacrylate 

N,N-Diethyldodecanamide 

Diethylhydroxyl amine 

1 ,3- Die thy 1-2- thiourea 

Diisopropylaminoethanol 

N,N- Dimethyl ace t amide 

*2-Dimethylaminoethanol 

3-Dimethylaminopropionitrile 

Dime thy laminoe thy 1 methacrylate 

Dime thy 1 amino- 2- prop anol 

N,N-Dimethylformamide 

1,1- Dime thy Ihydrazine 

2,5-Dithiobiurea 

Eruc amide 

Erucamide - lauraraide 

*Ethanolamines : 

*2-Aminoethanol (Monoethanolamine) 

*2,2 '-Aminodiethanol (Diethanolamine) 

*2,2 '2' '-Nitrilotriethanol (Triethanolamine) 

Ethanolamine hydrochloride, (60%) 

Ethoxylated amides 

Ethoxymethoxyp ropy 1 amine 

3-Ethoxypropionitrile 

2- Ethy laminoe thanol (Ethylmonoethanolamine) 

Ethyl carbamate 

Ethyl carbodiimide hydrochloride 

Ethyl cyanoacetate 

N,N' -Ethylene bis (stearamide) 

Ethyleneimine, monomer 

Ethyleneimine, polymer 

Ethylenethiourea 

Ethyl isocyanate 

Ethy Iraonoethanol amide, mixed 

Ethyl thiourea 

Fish oil fatty acid amide 



ACY. 
HEX, HCH. 



MCH. 

MCH. 

OTC. 

KF. 

ARA. 

HEX, MCH. 

RH. 

TCH. 

WAY. 

ARC, ASH. 

PC. 

ARC. 

PFN. 

KF. 

KF. 

AAC, PAS. 

PAS, RBC. 

DUP. 

JCC. 

AAC, DUP, PAS, UCC. 

PAS. 

ABC, UCC. 

DUP. 

EK. 

PAS. 

PAS, RBC. 

PAS, UCC. 

DUP. 

AAC, PAS, RH, UCC. 

ACY. 

AAC, ABC. 

COM, PAS. 

AIP, DUP. 

FMP. 

ACY. 

ASH, FIN, HUH. 

FIN. 



DOW, 

DOW, 

DOW, 

WSN. 

ARC. 

JCC. 

ACY. 

PAS. 

FHP. 

OTC. 

KF. 

CTN. 

DOW. 

DOW. 

PAS. 

OTC. 

PAS. 

OTC. 

HUM. 



GLY, JCC, MAT, OMC, UCC. 
JCC, MAT, OMC, UCC. 
JCC, HAT, OMC, UCC. 



SYNTHETIC ORGANIC CHE1ICALS. 1Q7? 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CONT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELUVNEOUS CHEMICALS, ACYCLIC- -Continued 
Nitrogenous Compounds — Continued 

Formamide 

Formamidine disulfide dihydrochloride 

Glycine (Aminoacetic acid) 

Glycine ethyl ester hydrochloride 

Glycolonitrile 

4-Guanyl-l-nitrosoguanyl-l-tetrazine 

*Hexariethylenediajnnionium adipate (Nylon salt) 

Hydracrylonitrile (Ethylene cyanohydrin) 

2- (Hydroxyraethyl)-2-nitro-l ,3-propanediol (Tris- 
(hydroxymethyljnitrome thane) . 

N-Hydroxymethylstearamide 

12-Hydroxy5tearamide 

Imino diacetic acid 

Imino diacetic acid, disodium salt 

3, 3' -Irainodi- 1,2 -propanediol 

Isopropanolamines : 

l-Aiiiino-2-propanol (Monoisopropanolamine) 

1,1'- Iminodi-2-propanol (Diisopropanolamine) 

1 ,1' ,1 ' '-Nitrilotri-2-propanol (Triisopropanolamine)-- 

3-Isopropoxypropionitrile 

3-Isopropoxypropylamine 

2-Isopropylaiiiinoethanol 

Isopropyl ethyl thionocarbamate 

Isopropyl isocyanate 

Lactonitrile 

Lauronitrile (Dodecyl nitrile) 

Methacrylamide 

3-Methoxypropyl amine 

2-Methylaininoethanol (N-Methylethanol amine) 

Methyl carbamate 

Methyl cyanoacetate 

Methyl a-cyanoacrylate 

N,N'-Methylenebis (acrylamide) 

N,N'-Methylenebis (octadecan amide) 

Methyl isocyanate 

2,2'-(Methylimino)diethanol (Methyldiethanolamine) 

2-Methyllactonitrile (Acetone cyanohydrin) 

2-Methyl-2-nitro-l,3-propanediol 

2-Methyl-2-nitro-l-propanol 

Methylpo lye thanol amine 

N-Methyl taurine 

N-Methylurea 

*Nitriloacids and salts: 

(Diethylenetrinitrilo)pentaacetic acid 

{Diethylenetrinitrilo)pentaacetic acid, monosodium 
hydrogen ferric salt. 
*(Diethylenetrinitrilo)pentaacetic acid, pentasodiura 
salt. 
(Diethylenetrinitrilo)pentaacetic acid, soditim salt — 

N,N-Dihydroxyethylglycine, sodium salt 

Ethanoldiglycine, disodium salt 

*(Ethylenedinitrilo)tetraacetic acid (Ethylenediamine- 
tetraacetic acid). 
(Ethylenedinitrilo)tetraacetic acid, calcium disodium 

salt. 
(Ethylenedinitrilo)tetraacetic acid, diammoniuiii salt-- 

*(Ethylenedinitrilo)tetraacetic acid, disodium salt 

(Ethylenedinitrilo)tetraacetic acid, disodium copper 

salt, dihydrate. 
(Ethylenedinitrilo)tetraacetic acid, disodium zinc 
salt, dihydrate. 



DUP. 






WAY. 






CHT. 






BPC. 






ACY, 


KF. 




RBI. 






cel 


DUP, 


MON. 


AAE. 






COM. 






ICI. 






HUM 






HMP. 






HMP. 






DUP. 






DOW, 


UCC. 




DOW, 


UCC. 




DOW, 


UCC. 




DUP. 






DUP. 






PAS. 






DOW. 






OTC. 






MON. 






ASH. 






SOH, 


X. 




JCC. 






UCC. 






BKL, 


FMP. 




KF. 






EKT. 






ACY, 


SOH. 




ARC. 






UCC. 






PAS, 


UCC. 




RH, 


X. 




COM. 






COM. 






GAF. 






GAP. 






EK, 


lil. 




DAN, 


HMP. 




CGY. 






CGY, 


DOW, 


HMP. 


CGY, 


RPC. 




DOW, 


HMP. 




HMP. 






CGY, 


DOW, 


HMP. 


CGY, 


DOW. 




DOW. 






CGY, 


DOW, 


EK, HMP 


CGY, 


HMP. 




CGY, 


DOW, 


HUP. 



r^ISCELLANEOUS CHE!^ICALS 
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

*Nitriloacids and salts--Continued 

(Ethylenedinitrilo)tetraacetic acid, manganese salt 

(Ethylenedinitrilo)tetraacetic acid, monosodium iron 

salt. 
(Ethylenedinitrilo) tetraacetic acid, tetraajmnonium 

salt. 
(Ethylenedinitrilo)tetraacetic acid, tetrapotassium 
salt. 
*(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt-- 

(Ethylenedinitrilo)tetraacetic acid, trisodium salt 

(N-Hydroxye thy lethylenedinitrilo)tri acetic acid 

(N-Hydroxyethylethylenedinitrilo) triacetic acid, coppei 

salt. 
(N-Hydroxyethylethylenedinitrilo) triacetic acid, iron 

salt. 
(N-Hydroxye thy le thy lenedinitrilo) triacetic acid, 
manganese salt. 
*(i4-Hydroxyethylethylenedinitrilo)triacetic acid, tri- 
sodium salt. 

Nitrilotri acetic acid 

Nitrilotriacetic acid, disodium salt 

Nitrilotriacetic acid, trisodium salt 

Nitrilotriacetic acid, zinc salt 

Other 

2-Nitro-l-butanol 

Nitroe thane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

•Nylon, 6 and 6/6 polj-mer for fiber 

Octadecyl isocyanate 

Oleamide (Octadecene amide) 

Oleic acid - ethylenedi amine condensate (amine/acid 
ratio=l/2) . 

Oleic acid - methanolamine condensate, ethoxylated 

Oleonitrile (Octadecene nitrile) 

Oleoylhydroxamic acid 

Oleoylpalmitamide 

*Pentaerythritol tet rani t rate 

Pentyl nitrate (Amyl nitrate) 6 hexyl nitrate 

*Polyacr>-l amide 

Polyacrylamide polymers other than polyacrylamide 

Polyacrylonitrile 

Polyacrylonitrile, hydrolyzed 

Polyalkylene amine- 

Polyamide resin (flake)- 

Polyglycol amine 

Polyoxypropylenediamine 

n- Propyl carbamate 

Propyl isocyanate 

Ricinolamide 

Sarcosine (N-Methylaminoacetic acid) 

Semicarbazide base 

Serai carbazide hydrochloride 

Stearamide (Octadecane amide) 

Stearic acid - ethylenediamine condensate (amine/acid 

ration=l/2) . 
Stearonitrile (Octadecanenitrile) 



CGY, HMP. 
CGY, HUP. 



CGY, HMP. 

CGY, CRT, DAN, DOW, HMP, HRT, JOR, RPC. 

CGY, HMP. 

HMP. 

HMP. 

HMP. 



CGY, CRT, DAN, DOW, HMP, RPC. 



HMP. 








HMP. 








DOW, 


H^^p 


MON 




HUP. 








DOW, 


EK, 


HMP, 


WAY. 


COM. 








COM. 








COM. 








COM. 








COM. 








ALF, 


DBC 


DUP 


MON. 


CWN, 


MOB 


UPJ 




ARC, 


ASH 


FIN 


HUM. 


CCW, 


GLY 






GAF. 








ARC, 


ASH 






CTN. 








FIN. 








COM, 


DUP 


HPC 




TNA. 








ACY, 


DOW 


HPC 


NLC. 


ACY. 








DUP. 








NLC. 








NLC. 








MON. 








UCC. 








JCC. 








BKL. 








OTC. 








TKL. 








CGY, 


HMP 






FMT. 








FMT. 








ARC, 


FIN 


HUM 




CCW, 


DA, 


GLY, 


HUM, ICI 


ARC, 


ASH 







SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Ccmpounds — Continued 

Stearylerucamide 

Succinimide 

Tall oil diethylenetetramine and acetic acid 

Tallow amde, hydrogenated 

Tallow nitrile 

Tallow nitrile, hydrogenated 

Tetra functional ketimine 

N,N,N' ,N'-Tetrakis (2-hydroxypropyl)ethylenediaiiiine — 

Tetrame thy Iguani dine 

Tetramethylurea 

Thioacetamide 

3,3'-Thiodipropionitrile 

Thiosemicarbazide 

Trisodiumhydroxye thy lethylenedi amine triacetate 

*Urea in compounds or mixtures, ino% basis: 

*In feed compounds 

*In liquid fertilizer 

*In solid fertiiieer 

In plastics 

All other 

Urea ammonium nitrate solution 

Urea - urethane copolymer 

All other nitrogenous compounds 



Acids J A(yid Anhydrides ^ and Aayl Halides 

*Acetic acid, synthetic, 100% 

'Acetic anhydride, 100%: 

From acetic acid 

From ethylene 

*Acrylic acid 

*Adipic acid 

Azelaic acid 

Behenic acid 

Bromoacetic acid 

Bromobuty ri c acid 

2 - Bromodode canoi c acid 

a-Bromo (mixed^ luric stearic acid 

1,3-Butylene glycolbiborate hexylene glycol boric 
anhydride . 

tert-Butylperoxymaleic acid 

Butyric acid 

Butyric anhydride 

Castor oil fatty acids, dehydrated 

Chloroacetic acid, mono- 



FIN. 

ASH. 

ACY. 

ARC. 

ARC, ASH. 

ARC, ASH. 

CNM. 

VYN. 

ACY. 

OTC. 

EK, RBC. 

ACY. 

ACY, FHT. 

CGY. 

ACN, AGY, FTX, GCC, HKY, ICI, JDC, MSC, PPC, SOH, TER, 

TRI, VLN, WYC. 
ACN, AGY, AIP, AKL, CFA, CHN, CNC, FCA, FTX, GCC, HKY, 

HPC, ICI, JDC, MSC, CMC, PLC, PPC, SHC, SNI. SOH, 

TER, TRI, VLN, WYC 
ACN, AGY, AKL, ARM, COL, DUP, GCC, HPC, ICI, JDC, MSC, 

OMC, PPC, SHC, SNO, SOH, TER, TRI, VLN, WYC. 
ACN, BOR, DUP, TRI. 

ACN, AIP, DUP, HPC, SHC, SNO, TER, WYC. 
WYC. 
DUP. 
AAC, ALB, ALD, CGY, CHP, COM, CTN, DUP, EK, EVN, FIN, 

FIS, FMP, FMT, GAF, GNM, HEX, HUM, IDC, JCC, KF, 

LIL, MAL, MCH, MRK, NFS, NOR, PD, PEN, PFZ, 

PIL, RSA, S, SDW, SM, SNW, TNA, VND, WTH, x. 



GEL, 
UCC. 
BFG, 
AGP, 
EMR. 
ASH. 
MCH. 
GTL. 
DUP. 
DUP. 
USB. 

WTL. 
GEL, 
EKT. 



BOR, CEL, EKT, FMP, MON, PUB, UCC. 
EKT, FMP. 



CEL, DBC, UCC. 

CEL, DBC, DUP, ELP, MON, RH. 



NTL. 
, DOW, HPC. 



MISCELLANEOUS CHEMICALS 
TABLE 2,— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--CoNT INUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Acids, Acid Anhydrides, and Aery I Hatides — Continued 

Chloroacetyl chloride 

Citric acid 

Crotonic acid (2-Butenoic acid] 

Decanoyl chloride 

Dimer acid (C-36 aiphatic dibasic acid] 

Dime thy Ipropionic acid 

Di-n-propylacetic acid and chloride 

Dipropylma Ionic acid 

Dodecanedioic acid 

*Dodecenyl succinic anhydride 

Dodecyl succinic anhydride 

Erucic acid 

Ethyl 3- (Chlorofonnyl)propionate 

2-Ethylbutyric acid (Diethylacetic acid) 

2-Ethylhexanoic acid (a-Ethylcaproic acid) 

2-Ethylhexanoyl chloride 

'Formic acid, 90% 

*Fumar i c acid 

Gluconic acid, tech 

G lut ari c anhydr i de 

Glycolic acid (Hydroxyacetic acid) 

n-Hexadecenylsuccinic anhydride 

n-Hexanoic acid 

1 - Hydroxye thy 1 idene- 1,1- diphosphoni c acid 

Isethionic acid (2-Hydroxyethanesulfonic acid) 

Isoascorbic acid 

Isobutyric acid 

I s obuty ri c anh ydride 

Isobutyryl chloride 

Is o-octadecenyl succinic anhydride 

Iso-octanoic acid 

Itaconic acid (Methylenesuccinic acid) 

2-Keto-D-gluconic acid 

Lactic acid 

*Lauroyl chloride 

Levulinic acid 

Maleic acid 

*Maleic anhydride 

Malic acid 

Malonic acid 

Mercaptoacetic acid (Thioglycolic acid) 

3-Mer cap t op rop ionic acid 

Mercaptosuccinic acid (Thioraalic acid) 

Methacrylic acid 

Methanesulfonic acid 

Methane su If onyl chloride 

2-Methylvaleric acid C2-Methylpentanoic acid) 

Neodecanoic acid 

Neodecanoyl chloride 

Neoheptanoic acid 

Neopentanoic acid 

Nonanoic acid (Pelargonic acid) 

Nonenylsuccinic anhydride 

Octadecenyl succinic anhydride 

Octanoyl chloride 

Octenylsuccinic anhydride 

Oleoyl chloride 

Oxalic acid 

PalmitoyI chloride 

Peroxyacetic acid 



DOW, 


WTC. 






MLS, 


PFZ, WTC 






EKT. 








WTC, 


WTL. 






AZS. 








COM. 








CTN. 








CTN. 








DUP. 








ACS, 


HMY, MON. 






HN. 








ASH. 








ABB. 








UCC. 








EKT, 


UCC. 






WTC, 


WTL. 






CEL, 


DUP, UCC 






ACS, 


HN, MON, 


PFZ, 


USS. 


PFZ, 


PMP. 






UCC. 








DUP, 


SNW. 






HMY. 








UCC. 








WAY. 








GAF. 








MRK, 


PFZ. 






EKT. 








EKT. 








WTC, 


WTL. 






HMY. 








UCC. 








PFZ. 








MRK. 








CLN, 


MON. 






GAF, 


HK, ONX, 


TEK, 


UOP, WTC, WTL 


QKO. 








ACS, 


PEN, PFZ 






ACS, 


HN, KPT, 


MON, 


PTT, RIG, USS 


ACS, 


EK. 






KF. 








EVN, 


HAB. 






EVN. 








EVN. 








DUP, 


RH. 






EK, 


PAS. 






PAS. 








UCC. 








EN J. 








WTC, 


WTL. 






ENJ. 








EN J. 








EMR, 


GIV. 






HMY. 








HMY. 








HK. 








HMY. 








GAF, 


HRT, UOP 






ACS, 


PFZ. 






GAF, 


OPC, PD, 


UOP. 




FMB, 


UCC. 







552-743 O - 74 - 15 



SYNTHETIC ORGANIC CHEMICALS. 1972 



TABLE 2.-niSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED. 
IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Aoids, A<yid Anhydrides, and Aayl Halicfes— Continued 

•Pivaloyl chloride 

*Poly aery lie aeid 

Polygalacturonic acid 

♦Propionic acid 

Propionic anhydride 

Propionyl chloride 

Sebacic acid 

Stearoyl chloride 

Succinic acid 

Succinic anhydride 

Tetrahydroxysueeinic acid (Dioxytartaric acid) 

Tetrapropenylsuccinie acid 

Thioacetic acid 

Thiolactic acid 

3,3'-Thiodipropionic acid 

Trichloroacetic acid 

Valeric aeid 

All other 

Salts of Organic Adds 

♦Acetic acid salts: 

Aluminum acetate 

Anraionium acetate 

Barium acetate 

Cadmium acetate 

Calcium acetate 

Chromium acetate 

Cobalt acetate 

*Copper acetate 

Lead acetate 

Lead sub acetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Nickel acetate 

♦Potassium acetate 

Silver acetate 

Sodium acfttate 

Sodium di acetate 

Strontium acetate 

♦Zinc acetate 

♦Zirconium acetate 

Other acetic acid salts 

Acrylic acid, sodium salt 

Adipic acid, ammonium salt 

Allylsulfonic acid, sodium salt 

Chloroacetic acid, sodium salt 

Citric acid salts: 

Ammonium citrate 

Calcium citrate 

Disodium citrate-- 

Ferric ammonium citrate 

Ferric citrate 

Potassium citrate 

Sodium citrate 

Other citric acid salts 



Manufacturers' identification codes 
(according to list in table 3) 



AZT, WTC, 


WTL. 




AAE, DA, 


RH. 




SKG. 






CEL, COM, 


EKT, 


UCC. 


EKT, UCC. 






EK, UOP. 






RH, WTH. 






EK, UOP. 






ACS. 






ACS, ORO 






ACY. 






TX. 






EVN. 






EVN. 






CCW, EVN 






DOW. 






UCC. 






ALD, CTN 


EK, 


EN J, 



ACY, 


UCC. 










ACS, 


BKC, 


HAL. 








ACS, 


BKC, 


MAL. 








MAL, 


SHP. 










ACS, 


MAL. 










VAL. 












HSH, 


SHP. 










ACS, 


BKC, 


SHP, 


UCC. 






BKC, 


MAL. 










ACS, 


BKC, 


MAL. 








ARA. 












ACS, 


BKC. 










HSH, 


NES, 


SHP. 








HAL. 












BKC, 


HSH, 


SHP. 








ACS, 


BKC, 


MAL, 


SFI, 


UCC, 


WSN. 


MAL. 












ACS, 


BKC, 


DAN, 


EKT, 


MAL, 


UCC, WSN 


UCC. 












BKC. 












ACS, 


BKC, 


HSH, 


MAL, 


SHP, 


UCC. 


CHP, 


HSH, 


NTL, 


TZC. 






CCW, 


LIL, 


MHI. 








AAE. 












FIS. 












SAL, 


X. 










DOW 












MAL 


PFZ 










PFZ 












WSN 












PFZ 












MAL 












MLS 


PFZ 










MLS 


PFZ 


SNW 








CHP 


EK, 


HAL. 









MISCELLANEOUS CHEMICALS 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Salts of Ovganio ;l^£^--Continued 

Dibutyltin bisCisooctyl thioglycolate) 

*2-Ethylhexanoic acid (a-Ethylcaproic acid) salts: 

Aluminuin 2-ethylhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

*CaIcium 2-ethylhexanoate 

*Cobalt 2-ethylhexanoate 

Copper 2-ethylhexanoate 

Iron 2-ethyIhexanoate 

*Lead 2-ethylhexanoate 

*Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

*Zinc 2-ethylhexanoate 

Zirconium 2-ethylhexanoate 

Other 

Formic acid salts: 

Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Lead formate 

Sodium formate, refined 

*Sodium formate, tech 

Thallous formate 

Glucoheptonic acid salts: 

Sodium glucoheptonate 

Gluconic acids salts: 

Ammonium gluconate 

•Sodium gluconate 

Glycolic acid, sodium salt 

9H-Hexadecaf luorononanoic acid, ammonium salt 

Humic acids, sodium salt 

Isoascorbic acid, sodium salt 

*Lactic acid salts: 

Ammonium lactate 

Calcium lactate 

Sodium lactate 

Other 

Laurie acid salts : 

Barium cadmium laurate 

Dibutyltin di laurate 

Zinc laurate 

Linoleic acid salts: 

Calcium linoleate 

Cobalt linoleate 

Copper linoleate 

Lead manganese linoleate 

Manganese linoleate 

Maleic acid salts: 

Dibutyltin maleate 

Lead Ctribasic) maleate 

Other maleic acid salts 

*Mercaptoacetic acid (Thioglycolic acid) salts: 

Ammonium mercaptoacetate 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dibutyltin bis iso-octyl mercaptoacetate 

Dibutyltin mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 



PFZ, 
CCA, 


WTC. 
PFZ. 














CCA, 


PFZ. 














CCA, 


CCC, 


FER 


HN, 


MCI 


PFZ 


SW, 


TRO 


CCA, 


ccc. 


FER 


HN, 


MCI 


SW, 


TRO, 


WTC 


CCA. 
















CCA, 


HN. 














CCA, 


CCC, 


FER 


HN, 


MCI 


OTL 


SW, 


WTC 


CCA, 


CCC, 


HN, 


MCI, 


SW, 


WTC. 






MCI, 


SW. 














CCA. 
















CCA, 


FER, 


HN, 


MCI, 


SW, 


WTC. 






CCA, 


FER, 


HN, 


TRO. 










CCA. 


WTC, 


x. 












WSN. 
















ACS, 


RSA. 














COM. 
















GAF. 
















NTL. 
















ACS, 


BKC. 














COM, 


CEL, 


HPC 













PFZ. 
PFZ, 
PMP, 
DUP. 
NLC. 
MRK. 

TCC. 
SHF. 
REH, 
CCA, 

CCA. 
CCW, 

SNW. 

CCA. 
SHP. 
SHP. 
SHP. 
SHP. 



EVN. 
CCA. 
EVN. 

X. 

CCA. 
EVN. 
EVN. 



PMP, SFI. 
SAL. 



PFN. 



CCW, PFN, REH, SNIV. WTC. 



HAB. TNI. 



SYNTHETIC ORGANIC CHEMICALS. W72 

TABLE 2,--MlSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Ccintinued 
Salts of Organic Aaids — Continued 

Mercaptopropionic acid, dibutyltin salt 

Methacrylic acid, sodium salt 

Neodecanoic acid salts: 

Cadmium neodecanoate 

Calcium neodecanoate 

Cobalt manganese neodecanoate 

Cobalt neodecanoate 

Lead cobalt neodecanoate 

Lead neodecanoate 

Lithium neodecanoate 

Manganese neodecanoate 

Stannous neodecanoate 

Vanadium neodecanoate 

Zinc calcium cobalt neodecanoate 

Zinc neodecanoate 

Zirconium neodecanoate 

Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate 

Barium cadmium octanoate 

Stannous octanoate 

Zinc octanoate 

Other 

*01eic acid salts : 

Aluminum oleate 

Ammonium oleate 

Chromium oleate 

Copper oleate 

Lead oleate 

Stannous oleate 

Other oleic acid salts 

Oxalic acid salts : 

Ammonium oxalate 

Ferric ammonium oxalate 

Ferric oxalate 

Ferrous oxalate 

Potassium oxalate 

Sodium oxalate 

Palmitic acid salts: 

Aluminum pa Imitate 

Zinc palmitate 

other 

Phosphorodithioic acid salts (Dithiophosphates) : 

Potassium dihexyl phosphorQdithioate 

Sodium di-sec-butyl diethyl phosphorodithioate 

Sodium di-sec-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Polyacrylic acid salts: 

Ammonium poly aery late 

Sodium ammonium polyacrylate and copolyers 

Sodium polyacrylate 

Polymeth aery lie acid, sodium salt 

Propionic acid salts: 

*Calcium propionate 

* Sodium propionate 

Ricinoleic acid silts: 

Calcium ricinoleate 

Lithium ricinoleate 

Sodium ethyl oxalacetate 

Sodium polypectate 



CCA. 
AAE. 

CCA. 

CCA, MCI. 

MCI. 

MCI. 

MCI. 

CCA, MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

CCA, MCI. 

MCI. 

DA. 
CCA 

CCW, x. 
BKC. 

DA. 

KTC. 

ARS. 

SHP. 

SHP, WTC. 

NOC, SHP. 

CCW, X. 

CHP, TRO, WTC. 

ACS, PFZ. 

PFZ. 

PFZ. 

BKL. 

BKC, PFZ. 

BKC. 

DA, WTC. 
ACY, DA, WTC. 
DA. 

ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 

BFG. 

BFG. 

ALC, BFG, DA, JOR, RH. 

GRD. 

HFT, PFZ, UCC, WSN. 
HFT, PFZ, UCC, WSN. 

NIL. 
NTL. 
FMP. 
SKG. 



MISCELLANEOUS CHEMICALS 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Salts of Organic Acids — Continued 

Sodium soribitol borate 

♦Stearic acid salts: 
'Aluminum stearates: 

* Aluminum distearate 

♦Aluminum monostearate 

♦Aluminum tristearate 

Ammonium stearate 

♦Barium stearate 

Cadmium stearate 

♦Calcium stearate 

Copper stearate 

Ferrous stearate 

Lead stearate 

Lead stearate, dibasic 

♦Lithium stearate 

♦Magnesium stearate 

Nickel stearate 

Silver stearate 

♦Zinc stearate 

All other 

Succinic acid, sodium salt 

Sulfosuccinic acid, trisodium salt 

Tartaric acid salts: 

Antimony potassium tartrate 

Potassium sodium tartrate 

Sodi urn bit art rate 

Valeric acid, ammonium salt 

Xanthic acid salts: 

Potassium amylxanthate 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium isopropylxanthate 

Potassium pentylxanthate 

Sodium n-butylxanthate 

Sodium sec-butylxanthate 

Sodium ethylxanthate 

Sodium isobutylxanthate 

Sodium isopropylxanthate 

All other salts of organic acids 



Aldehydes and Ketones 

♦Acet aldehyde 

♦Acetone : 

♦From cumene 

From isopropyl alcohol 

Other 

Acetone, crude 

Acrolein (Acrylaldehyde) 

Aldol (Acetaldol) 

♦2-Butanone (Methyl ethyl ketone) 

♦Butyraldehyde 

Chloral (Trichloroacetaldehyde) 

5-Chloro-2-pentanone 

l-Chloro-l-penten-3-one (6-Chlorovinyl ethyl ketone) - 

Chloro-2-propanone (Chloroacetone) 

Crotonaldehvde 



DA, 

DA, 
NOC 
ACY 
NOC 
NOC 



, DA, JTC, MAL, NOC, PEN, SYP, WTC. 

JTC, HAL, NOC, SYP, WTC. 

JTC, MAL, NOC, PEN, SYP. 

NOC, WTC. 

NOC, PEN, SYP. 
, SYP, WTC. 

, DA, HN, JTC, MAL, NOC, PEN, SYP, WTC. 

. WTC. 
NOC, WTC. 

NOC, PEN, SYP, WTC. 
, DA, JTC, MAL, NOC, PEN, SYP, WTC. 



DA, HN, JTC, MAL, NOC, PEN, SYP, IVTC. 
NOC, SYP, VAL. 



ACY 

WTC 

PEN 

ACY 

DA, 

MAL. 

STP. 

PFZ. 
PFZ. 
PFZ. 
RSA. 



DOW. 
DOW. 
DOW. 
DOW. 
ACY. 

KCC, USR. 
DOW. 
DOW. 
DOW. 
DOW. 

ACY, AID, CCA, CHP, CRN, CTN, DA, DUP, EK, EVN, JCC, 
KCH, MCI, NTL, PFN, RSA, SFA, SYP, UCC, x. 



CEL, DlIP, EKT, EKX, PUB, SHC, UCC. 

ACP, CLK, DOW, GP, MON, SHC, SKO, SOC, UCC, USS. 

EKT, EN J, SHC, UCC. 

CEL, DIX, HPC. 

OCC. 

SHC, UCC. 

UCC. 

ATR, CEL, DIX, ENJ, SHC, UCC. 

CEL, EKX, UCC. 

DA, MTO. 

SDW. 

ABB. 

EK, MRK. 

CEL, EKT. UCC. 



SYNTHETIC ORGANIC CHEf^ICALS. 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3] 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Aldehydes and Ketones — Continued 

l,3-Dihydroxy-2-propanone (Dihydroxyacetone) 

Diisopropyl ketone (2,4-Diinethyl-3-pentanone] 

2-Ethylbutyraldehyde 

Ethyl crotonaldehyde 

2-Ethylhexanal (a-Ethylcaproaldehyde) 

•Formaldehyde (37% by weight) 

Glutaraldehyde 

Glyoxal 

2-Heptanone (Methyl amyl ketone) 

3-Heptanone (Ethyl butyl ketone) 

Hexaldehyde 

2,5-Hexanedione (Acetonylacetone) 

*4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) 

Isobutyraldehyde 

Isopentaldehyde, mixed isomers 

Isovalerone (Diisobutyl ketone) 

Lac tide (3,6-Dimethyl-2,5,p-dioxanedione) 

4-Methoxy-4-methyl-2-pentanone 

2-Methylbutyraldehyde 

5-Methyl-2-hexanone (Methyl isoamyl ketone) 

Methylhexenone 

*4-Methyl-2-pentanone (Methyl isobutyl ketone) 

Methylpentenal 

4-Methyl-3-penten-2-one (Mesityl oxide) 

2-Methylvaleraldehyde (2-Methylpentaldehyde) 

3-Octanone (Ethyl amyl ketone) 

Paraformaldehyde 

Paraldehyde (Paracet aldehyde) 

2,4-Pentanedione (Acetylacetone) 

2-Pentanone (Methyl propyl ketone) 

3-Pentanone (Diethyl ketone) 

Propionaldehyde 

Tetrahydropseudoionone 

2,6,8-Trimethyl-4-nonanone (Isobutyl heptyl ketone)-- 

Valeraldehyde 

All other 

Alcohols, Monohydria, Unsubstituted 

•Alcohols C or lower, unmixed: 

Allyl alcohol 

Amyl alcohols : 

2-Methyl-l-butanol 

2-Methyl-2-butanol (tert-Amyl alcohol) 

1-Pentanol 

Butyl alcohols: 
Primary : 

*Iso (Isopropylcarbinol) 

•Normal (n- Propylcarbinol) 

Secondary (Methylethylcarbinol) 

Tertiary (Trimethylcarbinol) 

2,6-Dimethyl-4-heptanol (Diisobutylcarbinol) 

•Ethyl alcohol, synthetic 

2-Ethyl-l-butanol 

*2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Ethyl-l-octyn-3-ol 



BAX. 

EKX. 

UCC. 

UCC. 

EKX, UCC. 

ACN, BOR, CBD, CEL, COM, DUP, GAP, GOC, GP, HKD, HN, 

HPC, MON, RCI, RH, UCC, WCL. 
UCC. 
UCC. 
UCC. 
UCC. 
UCC. 
ARS. 

CEL, SHC, UCC. 
EKX, UCC. 
UCC. 
UCC. 
CLN. 
SHC. 
UCC. 

EKT, UCC. 
UCC. 

EKT, ENJ, SHC, UCC. 
UCC. 

SHC, UCC. 
UCC. 
SHC. 

CEL, HN. 
UCC. 
UCC. 
UCC. 

HEX, CRT. 
EKX, UCC. 
CEL. 
UCC. 
UCC. 
ALD, ARC, EK, CRT, UCC. 



CPS, UCC. 
ENJ, SHC. 
UCC. 



CEL, DBC, EKX, OXC, SHC, UCC. 

CEL, CO, DBC, EKX, OXC, SHC, TNA, UCC. 

CEL, ENJ, SHC. 

SHC, X. 

UCC. 

EKX, ENJ, GP, HPC, PUB, SHC, UCC, USl. 

UCC. 

CEL, DBC, EKX, OXC, SHC, UCC. 

EKX. 

AIP. 



MISCELLANEOUS CHEMICALS 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Alcohols, Monohydpia, Unsuhstituted — Continued 

*Alcohols C or lower, unmixed--Continued 

Heptyl alcohol--- 

*Hexyl alcohol 

Hexynol 

Isononyl alcohol 

*l50-octyl alcohols 

* I sop ropy 1 alcohol 

*Meth anol , synthet i c 

Methyl «"yl alcohol 

3-Me'thyl-l-butanol 

2-Methyl-3-butyn-2-ol 

2-Methyl-l-pentanol 

4-Methyl-2-pentanol (l-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol (Methylparafynol) 

*1 -Oct anol 

*2-0ctanol (sec-Capryl alcohol) 

3-Pentanol 

'Propyl alcohol (Propanol) 

2-Propyn-l-ol 

1-Tetradecanol (Myristyl alcohol) 

All other 

'Alcohols, C,5 or higher, unmixed: 

1-Decanol 

Dodecyl alcohol (Lauryl alcohol) (95%) 

*l-Hexadecanol (Cetyl alcohol) (95%) 

Hexadecyl alcohols, other 

*Isodecyl alcohol 

*I-Octadecanol (Stearyl alcohol) (95%) 

cis-9-Octadecen-l-ol (Oleyl alcohol) 

1-Tridecanol 

2,6,8-Trimethyl-4-nonanol 

All other 

'Mixtures of alcohols: 
*C, and lower only: 

Amyl alcohols 

Other 

'Cjj and higher only 

'Cj to C,2 and others 

Polyhydria Alcohols and Their Esters and Ethers 

*Pclyhydric alcohols: 

1,2 (and l,3)-Butanediol 

1,4-Butanediol 

2-Butene-l,4-diol 

2-Butyne-l,4-diol 

3-Chloro-l,2-propanediol (Glycerol-a-chlorohydrin) 

1,10-Decanediol 

2,5-Dimethyl-2,5-hexanediol 

2,5-Dimethyl-3-hexyne-2,5-diol 

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol) 

'Ethylene glycol 

2-Ethyl-l,3-hexandiol 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol (Tri- 
methylol propane) . 
'Glycerol, synthetic- 



ENJ, TID, USS. 
EN J, SHC, UCC. 
AIP, BOR, CEL, DIJP, GP, HN, HPC, HON, RH, UCC. 



CO, EKX, ENJ, TNA, UCC. 

AIP. 

ENJ. 

AIP 

ATR 

ACN 

UCC 

UCC. 

AIP. 

UCC. 

SHC. 

AIP. 

CO, PG, WTH. 

RH. 

EK. 

CEL, EKX, UCC. 

GAP. 

CO, PG. 

ALD, EKX, GYR, LIL. 



CO, 


PG. 






CO, 


PG. 






ASH 


CO, 


GIV, 


PG. 


ENJ 








AIP 


ENJ 


TID 


, UCC, USS. 


ASH 


CO, 


PG. 




ASH 


DUP 






ENJ, 


UCC 






UCC. 








UCC. 








ENJ. 








CEL 


EKX 


PUB 


, UCC. 


ASH 


CO, 


ENJ, 


PG, SHC, TNA, UCC. 


CO, 


EKX, 


PG, 


SHC, TNA. 



CEL. 
GAP. 
GAP. 
GAP. 
EVN, 
FIS. 
AIP. 
AIP. 
EKX. 
CAU, CEL, DOW, DUP, EKX, GAP, JCC. MAT, NWP, OMC, PPG, 

SHC, UCC, IfYN. 
UCC. 
CEL. 

DOW, FMP, ICI, SHC. 



SYNTHETIC ORGANIC CHE^IICALS> 1972 
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Polyhydria Alcohols and their Esters 
and Ethers — Continued 

*Polyhydric alcohols--Continued 

1 ,6-Hexanediol 

2- (Hydroxymethyl)-2-methyl-l ,3-propanediol (Tri- 
methylolethane) . 

Mannitol 

3-Mercapto-l ,2-propanediol (Thioglycerol) 

*2-Methyl-2,4-pentaiiediol (Hexylene glycol) 

2-Methyl-2-propyl-l ,3-propanediol 

*Pentaerythritol 

1,5- Pent anediol 

♦Propylene glycol Cl,2-Propanediol) 

♦Sorbitol 

2,2,4-Triiiiethyl-l,3-pentanediol 

All other 

♦Polyhydric alcohol esters: 

1,3- But anediol dimethacrylate 

2, (2-Butoxyethoxy)ethyl acetate 

2-Butoxyethyl acetate 

Diethylene glycol, borated 

Diethylene glycol chlorofomate 

2-Diisopropylaiiiinoethyl me th aery late 

2- (2-Ethoxyethoxy)ethyl acetate 

2-Ethoxyethyl acetate 

♦Ethylene glycol diacetate — 

Ethylene glycol dimercaptoacetate 

Ethylene glycol dimethacrylate 

Ethylene glycol hydroxyacetate 

2-Ethyl-2- (hydroxymethyl)-i,3-propanediol tr- 
methacrylate. 

Glyceryl diacetate (Diacetin) 

Glyceryl monoacetate (Monoacetin) 

Glyceryl triacetate (Triacetin} 

Glyceryl trioleate 

Glycol adipate 

Hexylene glycol diacetate 

Lanolin acetate 

2-Methoxyethyl acetate 

2-Methoxyethyl carbonate 

Methoxytriethyleneglycol acetate 

Pen t aery thritol caprylatST 

Pentaerythritol pelargonate 

Pent aery thritol stearate 

Pentaerythritol tetrakis (3-mercaptopropionate) 

Polyethylene glycol dimethacrylate 

Sorbitol polyoxypropylene ether 

Sucrose oct a- acetate 

Tetraethylene glycol diacrylate 

Tetraethylene glycol dimethacrylate 

Triethylene glycol diacetate 

Triethylene glycol diacrylate 

Triethylene glycol dimethacrylate 

2,2,4-Trimethyl-l,3-pentanediol monoisobutyrate 

Trimethylolpropane tri aery late 

All other 

♦Polyhydric alcohol ethers: 

Allyloxypolyethylene glycol 

Bis (2-butoxyethyl) ether (Diethylene glycol di-n- 

butyl ether) . 
Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl 
ether) . 



CEL 
COM 

ICI 
EVN 
CEL 
BKL 
CEL 
UCC 
CEL 
BRD 
EKX 
EKX 

SAP 
EKT 
SAR 
GLY 
CTN 
DUP 
EKT 
DOW 
CPS 
EVN 
SAR 
CCA 
SAR 

ARC 
ARC 
ARC 
GRO 

X. 

UCC 
CRN 
UCC 
VAL 
RBC 
PVO 
PVO 
GLY 
EVN 
SAR 
JCC 
HFT 
AAE 
SAR 
UCC 
AAE 
SAR 
EKX 
AAE 
CCW 

UCC 
UCC 



SHC, UCC. 

COM, HN, HPC, PNA, RCI. 



DOW, JCC, OCC, OMC, UCC, IVYN. 
ICI, MRK, PFZ. 



GLY, ICI, PEN, PHR, PIC, RSA. 



UCC. 
UCC. 
JCC. 
PPG. 



UCC. 
UCC. 
EKT, UCC. 



HAL. 
HAL. 
EKT, UCC. 



EK, EKX, EVN, PEN, SAR SHC, UCC. 



MISCELLAHEHUS CHEMICALS 

TABLE 2,--MlSCELLANE0US CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Polyhydrio Alcohols and Their Esters 
and Ethers — Continued 

*Polyhydric alcohol ethers--Continued 

Bis (hydroxye thy 1) ether butynediol 

Bis[2- C2-methoxyethoxy)ethyl] ether (Tetraethylene 

glycol dimethyl ether) . 
BisC2-methoxyethyl) ether (Diethylene glycol dimethyl 
ether) . 

Butanol polyoxypropylene ether 

*2-Butoxyethanol (Ethylene glycol monobutyl ether) 

*2- (2-Butoxyethoxy)ethanol (Diethylene glycol monoiso- 
butyl ether) . 

2- [2- (2-Butoxyethoxy)ethoxy]ethaiiol (Triethylene 
glycol monobutyl ether). 

l-Butoxyethoxy-2-propanol 

'Diethylene glycol 

Diethylene glycol monobutyl ether 

Diethoxytetraglycol 

Dimethoxyethane (Ethylene glycol dimethyl ether) 

*Dipropylene glycol 

Di-tributyle there thy lene glycol 

Di-tri-isobutyl ether 

*2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

*2- (2-Ethoxyethoxy)ethanol (Diethylene glycol mono- 
ether) . 
*2- [2- (Ethoxyethoxy)ethoxy]ethaiiol (Triethylene 
glycol monoethyl ether) . 

Glycerol tri (polyoxypropylene) ether 

2- (Hexyloxy)ethanol 

2- [2- (Hexyloxy)ethoxy]ethanol 

2-Isobutoxyethanol 

2- (2-Isobutoxyethoxy)ethanol (Diethylene glycol 

monoisobutyl ether) . 
l-lsobutoxy-2-propanoi (Propylene glycol isobutyl 
ether) . 
*2-Methoxyethanol (Ethylene glycol monomethyl ether) — 
*2- (2-Methoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether) . 
*2- [2- (2-Methoxyethoxy)ethoxy]ethanol (Triethylene 
glycol monomethyl ether) . 
2- (2-Methoxyethoxy)ethyl-2-iiiethoxyethyl ether (Tri- 
ethylene glycol dimethyl ether) . 

Methoxypolyethylene glycol 

l-Methoxy-2-propanoI 

3- (3-Methoxypropoxy)propanol 

3- [3- (3-Methoxypropoxy)propoxy)pr»p»nel 

Polybutylene glycol 

Polyethoxyethyl glycerol 

Po lye thoxye thy I sorbitol 

Polyethoxylated-1 ,4-hutanediol 

'Polyethylene glycol 

Polyethylene glycol, unrefined 

Polypropoxy ethers: 

Glycerol tri (polyoxypropylene) ether 

Other 

'Polypropylene glycol 

Polytetramethylene ether glycol 

Sorbitol, ethoxylated 



GAP. 
ASL. 



JCC. 

DOW, EKX, one, SHC, UCC. 

DOW, EKX, JCC, OMC, SHC, UCC. 



DOW, o^c, 


UCC 


UCC. 




CAU, CEL, 


DOW 


WYN. 




OMC. 




UCC. 




ASL, UCC, 


IVYN 



EKX, JCC, HAT, NWP, PPG, SHC, UCC, 



CEL, DOW, JCC, OCC, OMC, UCC. 
EKX. 



DOW, EKX, JCC, OMC, SHC, UCC. 
DOW, EKX, JCC, OMC, SHC, UCC. 



DOW, 


one. 


UCC 


JCC, 


UCC, 


WYN 


UCC. 






UCC. 






EKX, 


UCC. 




EKX. 







DOW, EKX, JCC, OMC, PPG, SHC, UCC. 
DOH, EKX, JCC, OMC, PPG, SHC, UCC. 

DOW, CMC, UCC. 

ASL. 

.JCC, UCC. 

DOW, UCC. 

DOW, UCC. 

DOW. 

NLC. 

GLY. 

GLY. 

TCH. 

DA, DOW, DUP, GAF, HOG, JCC, MAT, NLC, OMC, TCH, UCC, 

WYN. 
WYN. 

JCC, UCC, IVYN. 

DA, JCC, ICI, NWP, UCC, VAL, WYN. 

DOW, JCC, HDG, NLC, OMC, UCC, W\'N. 

DUP, QKO. 

ICI. 



SYNTHETIC ORGANIC CHEf^ICALS.. 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Polyhydrio Alcohols and their Esters 
and Ethers — Continued 

*Polyhydric alcohol ethers--Continued 

*Tetraethylene glvxol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thiodiethanol (Thiodiglycol) 

*Triethylene glycol 

*Tri propylene glycol 

All other 

Esters of Monohydrio Alcohols 

Allyl raethacrylate 

Amyl acetates, 90%: 

Isopentyl acetate (Isoamyl acetate^ 

n-Pentyl acetate 

Ainyl-2-ethylhexyl hydrogen phosphate 

Bis (2-chloroethyl) (2-chloroethyl) phosphonate 

Butyl acetates : 

♦ ISO 

•Normal 

Secondary 

•Butyl aery late 

Butyl butyryl lactate 

Butyl chloroacetate 

n- Butyl chloroformate 

sec- Butyl chloroformate 7 

Butyl formate 

Butyl lactate 

Butyl maleate, mono- 

Butyl methacrylate 

tert- Butyl peroxy acetate 

tert- Butyl peroxy- 2 -ethylhexanoate 

tert- Butyl peroxyisobutyrate 

tert- Butyl peroxy isopropyl carbonate 

*tert- Butyl peroxypivalate 

Cetyl lactate 

Di allyl maleate 

Di (sec-butyl) chloroformate 

Dibutyl fumarate 

•Dibutyl maleate 

Di (sec-butyl) peroxydi carbonate 

Diethyl sec-butylethylmalonate 

Diethyl butylmalonate 

Diethyl sec-butylmalonate 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diallylmalonate 

Diethyl diethylmalonate (Diethyl malonic ester) 

Diethyl dip ropy Ima Ion ate 

Diethyl (ethoxymethylene)malonate 

Diethyl ethylmalonate (Ethyl malonic ester) 

Diethyl ethyl (l-methylbutyl)malonate 

Di (2-ethylhexyl) chloroformate 

Di (2-ethyl-l-hexyl) fumarate 

Di (2-ethyl-l-hexyl) maleate 

Di (2-ethyl-l-hexyl) peroxydi carbonate 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Diethyl (1-methylbutyl) malonate 

Diethyl oxalate (Ethyl oxalate) 

Diisobutyl maleate 



DOW, EKX, JCC, CMC, UCC. 

KF. 

HAB, UCC. 

CAU, CEL, DOW, EKX, JCC, MAT, PPG, SHC, UCC. 

DOW, HDG, CMC, UCC. 

ALD, DOW, EKX, GAP, JCC, PFN, SHC, UCC, x. 



PFW 
SM. 
GAF 



EKX 
CEL 
EKT 
CEL 
RT. 
MON 
CTN 
CTN 
CPS 
COM 
TCH 

AZT 
AZT 
AZT 
PPG 
AZT 
VND 
FHP 
WTL 
MON 
AIP 
IVTL 
ABB 
BPC 
ABB 
CTN 
CTN 
LIL 
CTN 



WTL 
RUB 
RUB 
IVTL 
ACY 
ABB 
ABB 
FHP 
RUB 



EN J, UCC. 

EKT, PUB, SHC, UCC. 

EN J, SHC. 

DBC, RH, UCC. 



USS. 



IVTL. 

WTC, WTL. 
WTC, WTL. 
IVTL. 
WTC, IVTL. 



PFZ, RCI, USS. 
MON, RCI, RUB, USS. 



UCC. 

KF, LIL. 
LIL. 



MISCELLANEOUS CHEHICALS 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 1972— CONTINUED 



miscellaneous chemicals, ACYCLIC--Continued 

Esters of Monohydrio Alcohols — Continued 

Diisodecyl maleate 

Di-iso-nonyl maleate 

Diisopropyl peroxydi carbonate (Isopropyl percarbonate)- 

Dilauryl maleate 

*Dilauryl 3,3'-thiodipropionate 

Dimethyl carbonate 

2,5-Dimethylhexane-2,5-diperoctoate 

Dimethyl maleate 

Dimethyl malonate 

Dimyristyl 3,3'-thiodipropionate 

*Dioctyl maleate 

Di-n-propyl peroxydi carbonate 

*Distearyl 3,3'-thiodipropionate 

Dithiobis(stearyl propionate) 

Ditridecyl maleate 

Di(tridecyl) 3,3'-thiodipropionate 

2-Ethoxyethyl acetate 

*Ethyl acetate 

Ethyl acetoacetate 

*Ethyl aery late 

Ethyl- 2-bromopropionate 

Ethyl chloroacetate 

Ethyl chloro formate 

Ethyl chlorothiolformate 

Ethylene carbonate 

2-Ethyl-l-hexyl acetate 

*2-Ethyl-l-hexyl aery late 

2-Ethyl-l-hexyl methacrylate 

Ethyl silicate (Tetraethoxysilane) 

Ethyl sulfate (Diethyl sulfate) 

Ethyl thioglycolate 

Fatty acid esters, not included with plasticizers or 
surface- active agents: 

Butyl palmitate 

tert-Butylperoxy neodecanoate -. 

Dimethyl brassylate 

Ethyl stearate 

2-Ethylhexyl palmitate 

Hexadecyl stearate 

Isopropyl linoleate 

Methyl esters of coconut oil 

Methyl esters of cottonseed oil 

Methyl esters of tallow 

Methyl 12-hydroxystearate 

Methyl myristate 

Methyl stearate 

Myristyl myristate 

All other 

Glycidyl aery late 

Glycidyl methacrylate 

Hexyl acetate 

Isobutyl acetate 5 isobutyl isobutyrate, mixture 

Isobutyl aery late 



Manufacturers' identification codes 
(according to list in table 3) 



RUB. 






RUB. 






PPG. 






EFH. 






ACY, CCW 


E\fN, HAB. 




CTN. 






WTC. 






AAC, ABC 






KF. 






CCW, EVN 






MON, RCI 


USS. 




wtl. 






ACY, CCW, 


EVN, HAB. 




EVN. 






RUB. 






ACY, EVN 






EN J. 






CEL, EKT, 


EKX, ENJ, MON, PUB, UCC 


EKT, UCC. 






CEL, DBC, 


RH, SNW, UCC. 




BAX. 






DOW. KF, 


MON. 




CTN, FMP, 


OTC. 




SFA. 






JCC. 






EKT, UCC. 






CEL, DBC. 


UCC. 




X. 






SFS, UCC. 






UCC. 






EVN. 






AAE, CBY. 






WTC. 






EMR. 






ARS. 






VND. 






ICI. 






VND. 






PG. 






BFR. 






CHL, HUM, 


PG. 




HUM, NTL. 






HUM, PG. 






DA. 






VND. 






CRN, ROB, 


VND. 




AAE. 






CPS, ENJ. 






EKX. 






DBC, RH, 


UCC. 





SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Hanufacturers ' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

EsteTS of Mcnohydrio Alcohols — Continued 

Isobutyl chloro formate 

Isobutyl isobutyrate 

Isodecyl aery late 

*Iso-octyl mercaptoacetate 

Iso-octyl 3-ine re apt ©propionate 

*Isopropyl acetate 

Isopropyl chloro formate 

Lauryl lactate 

Lauryl methacrylate 

Lauryl stearyl thiodipropionate 

Maleic esters and copolymers 

Methallylidene di acetate 

*Methyl acetate 

Methyl acetoacetate 

Methyl acrylate, monomer 

Methyl borate 

Methyl chloroacetate 

Methyl chloro formate 

Methyl di chloro acetate 

Methyl formate 

*Methyl methacrylate, monomer 

4-Methyl-2-pentyl acetate 

Methyl sulfate CDimethyl sulfate) 

Methyl vinyl acetate 

Myristyl lactate 

Octadecyl 3-mercaptopropionate 

'Phosphorus acid esters: 

Bis [2-ethylhexyl) hydrogen phosphate 

Bis (2-ethylhexyl} hydrogen phosphite 

Butyl hydrogen phosphates 

Dibutyl butylphosphonate 

Dibutyl hydrogen phosphite 

Didodecyl hydrogen phosphate 

Diethyl ethylphosphonate 

Diethyl hydrogen phosphite 

Diethyl phosphorochloridothionate 

Dimethyl hydrogen phosphite 

Dimethyl methylphosphonate 

Dimethyl phosphorochloridothionate 

Dioleyl hydrogen phosphite 

2-Ethylhexyl hydrogen phosphate 

Iso-octyl hydrogen phosphate 

Oleyl hydrogen phosphate 

Trialkyl phosphites 

Tr i (b utoxye thyl)phosphate 

Tributyl phosphate 

Tri ethyl phosphite 

Triiso-octyl phosphite 

Tri i s op ropy 1 phosphi te 

Trimethyl phosphite 

Tris(2-chloroethyl) phosphite 

Tris (chloroisopropyl) thionophosphate 



CTN, OTC. 

EKX. 

UCC. 

CCW, EVM, IIAB. 

EVN. 

EKT, EN J, UCC. 

CTN, PPG. 

VND. 

X. 

EVN. 

GAP, USS. 

UCC. 

EK, GRD, MON, UCC. 

EKT, UCC. 

CEL, DBC, RH. 

SFS. 

DOW, KF. 

CTN, FMP. 

PD. 

CEL, DUP. 

ACY, DUP, RH. 

PUB, SHC, UCC. 

DUP. 

UCC. 

VND. 

EVN. 

SM, UCC. 

SM. 

SM. 

SM. 

SM. 

DUP. 

SH. 

SM. 

SPA. 

SM. 

SM. 

SPA. 



COM, FMP, HN. 
SPA, SFS, SM. 



SM. 

SFA, SFS, SM. 



MISCELLANEOUS CHEMICALS 
TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3] 



MISCELLANEOUS CHEMICALS, ACYCYLIC--Continued 

Esters of Monohydrio Alcohols — Continued 

♦Phosphorus acid esters--Continued 

Tris(2,3-dibromopropyl) phosphate 

Tris (l,3-dichloro-2-propyl) phosphorothioate 

All other 

Poly (methylvinyl ether/monoethyl maleate) 

♦Propyl acetate 

Propylene carbonate 

Stear>'l methacrylate 

Tetraethyl silicate 

1 ,1,3,3-TetramethylbutyI peroxy-2-ethylhexanoate 

Tetraoctyl orthosilicate 

Titanic acid esters: 

Bis (2- [bis (2-hydroxyethyl) amino] ethyl) diisopropyl 

titanate . 
Bis(l-methyl-3-oxo-l-butenyl) diisopropyl titanate-- 

Tetrabutyl titanate 

Tetraisopropyl titanate 

Tetrakis(2-ethylhexyl) titanate 

Other 

Triethyl orthoacetate 

Trie thy 1 orthoformate 

Triethyl orthopropionate 

Triisodecyl orthoformate 

Trimethyl orthoformate 

*Vinyl acetate, monomer 

All other 

Halogenated Hydrooarbons 

1-Bromobutane Cn-Butyl bromide) 

2-Bromobutane (sec-Butyl bromide) 

Bromochlorome thane 

l-Bromo-3-chloropropane (Trimethylenechlorobromide) — 

2-Bromo-2-chloro-l,l ,1-trifluoroe thane 

Bromoethane (Ethyl bromide) 

1-Bromohexane (n-Hexyl bromide) 

l-Bromo-3-methylbutane 

l-Bromo-3-methyl-2-butene 

1-Bromo-octadecane 

1-Bromo-octane (n-Octyl bromide) 

2-Bromopentane (1-Methylbutyl bromide) 

1-Bromopropane (n-Propyl bromide) 

Bromotrichlorome thane 

Bromotrifluorome thane 

n- Butyl chloride 

♦Carbon tetrachloride 

Carbon tetrachloride crude 

♦Chlorinated paraffins: 

Less than 35% chlorine 

♦35%-64% chlorine 

bS't. or more chlorine 

2-Chloro-l,3-butadiene 

1-Chlorobutane (n-Butyl chloride) 

2-Chlorobutane (sec-Butyl chloride) 

l-Chloro-l,l-difluoroethane 

♦Chlorodifluorome thane 



HN, 

SM. 

ALD, 

TNI. 

CEL, 

JCC. 

X. 

ucc. 

WTL. 
MON. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

KF. 

KF. 

KF. 

KF. 

KF. 

BOR, 

ALD, 



DOW. 

MCH. 

ICI. 

DOW, 

HMY. 

LIL. 

SDW. 

DUP. 

MCH. 

LIL. 

EK, 

MCH. 

DUP. 

BRD. 

ACS, 

TNA. 



MCH. 
DUP, MON, SM, TNA, WES. 
EKT, PUB, UCC. 



CEL, NSC, UCC, USI. 

CEL, CTN, DUP, EFH, EK, EMR, ENJ, EVN, GAF, HUM, 
PIC, RH, UCC, WTL, ZGL. 



DA, DOW, FMB, FRO, PPG, SFI . 



DA, HK. 

CCH, DA, DVC, HPC, ICI, NEV. 

DA, DVC, NEV. 

DUP. 

PUB, UCC. 

EK, PLC. 

DUP, PAS. 

ACS, DUP, KAI, PAS, RCN. 



SYNTHETIC ORGANIC CHEMICALS, 1972 
TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported 

IDENTIFIED BY MANUFACTURER, 1972— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued 

Halogenated Hydrocarbons — Continued 

*Chloroethane (Ethyl chloride) 

*Chloroform 

*Chloromethane (Methyl chloride) 

2-Chloro-2-methylpropane (tert-Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

Ch 1 oropent af luoroe th ane 

3-Chloropropene (Allyl chloride) 

Chlorotrifluoroethylene (Trifluorovinyl chloride) 

Ch lorotrif luoroe thy lene, polymerized 

Chlorotrifluorome thane 

*1 ,2-Dibromoethane (Ethylene dibromide) 

Dibromomethane (Methylene bromide) 

l,2-Dibromo-l,l ,2 ,2-tetrafluroethane 

Dichlorobutadiene 

l,3-Dichloro-2-butene 

1 ,4-Dichlorobutene 

*Dichlorodifluorome thane 

*l,2-Dichloroethane (Ethylene dichloride) 

*Dichloromethane (Methylene chloride) 

*l,2-Dichloropropane (Propylene dichloride) 

2 ,3-Dichloropropene 

Dichlorotetraf luoroethane 

1 ,1-Dif luoroethane 

Diiodomethane (Methylene iodide) 

Fluronated ethylene propylene 

Hexadecyl chloride 

Hexaf luoro-2-propane 

Hexafluoropropylene, monomer 

lodoethane (Ethyl iodide) , tech 

Iodoform (Triiodome thane) 

*Iodomethane (Methyl iodide) 

1 - 1 odoperf luorohexane 

Lauryl chlorides 

Octafluorocyclobutane 

Octyl chloride 

1 ,1,2,2-Tetrabromoethane (Acetylene tetrabromide) — 
1 ,1,2,2-Tetrachloroethane (Acetylene tetrachloride) - 

*Tetrachloroethylene (Perch loroe thy lene) 

Tetraf luoroethylene , monomer 

Tetrafluorome thane 

*l,l,l-Trichloroethane (Methyl chloroform) 

1 ,1,2-Trichloroethane (Vinyl trichloride) 

*Trich loroe thy lene 

*Trichlorofluoromethane 

1 ,2,3-Trichloropropane 

1 ,2,3-Trichloropropene 

Trich lorotrif luoroethane 

Vinyl bromide (Bromoethylene) 

*Vinyl chloride, monomer (Chloroethylene) 



AME, DOW, DUP, HPC, PPG, SHC, TNA. 

ACS, DA, DOW, DUP, FRO, SFI. 

ACS, CO, DCC, DOW, DUP, FRO, TNA, UCC. 

EK. 

FMP. 

DUP. 

DOW, SHC. 

ACS, MMH. 

MHM. 

DUP. 

DOW, GIL, MCH, PPG, TNA. 

DOW. 

DUP. 

DUP. 

DUP. 

DUP. 

ACS, DUP, KAI, PAS, RCN, UCC. 

ACS, AME, BFG, CO, DA, DOW, FRO, JCC, OMC, PPG, 

TNA, UCC, IVYN. 
ACS, DA, DOW, DUP, FRO, SFI. 
DOW, JCC, UCC. 
DOW. 

ACS, DUP. 
ACS, DUP. 
NTS, SDW. 
DUP. 

BRD. 

DUP. 

DUP. 

EK, FMT, RSA. 
NTB. 

EK, FMT, RSA. 

DUP, TKL. 

AZT, BRD. 

DUP. 

BRD. 

DOW. 

TTX. 

DA, DOW, DUP, FRO, HK, PPG, SFI, TNA. 

DUP, PAS, TKL. 

DUP. 

DOW, FRO, PPG, TNA. 

DOW, UCC. 

DOW, DUP, HK, PPG, TNA, TTX. 

ACS, DUP, KAI, PAS, RCN, UCC. 

DOW, SHC. 

DOW, PAS. 

ACS, DUP. 

DOW, TNA. 

ACS, AME, BFG, 



CO, DOW, HN, MNO, PPG, SHC, TNA. 



MISCELLAflEOUS CHEMICALS 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Halogenated Hydrocarbons — Continued 

Vinyl fluoride 

Vinylidene chloride, monomer (1,1-Dichloroethylene) 

Vi ny 1 i dene f luori de 

All other 

All Othev Miscellaneous Acyclic Chemicals 

Acetyl peroxide 

Aluminum isopropoxide (Aluminum isopropylate) 

*2-Butanone peroxide 

tert- Butyl hydroperoxide 

*tert-Butyl peroxide (Di-tert-butyl peroxide) 

Butyrolactone 

Caprolactone 

*Carbon disulfide 

2-Chloroethanol (Ethylene chlorohydrin) 

Decanoyl peroxide 

Di aldehyde starch 

2 , 3- Dib romop ropanol 

2,5-Dimethyl-2,5-bis (2-ethyl-l-hexanoylperoxy)hexane — 

2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexane 

2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexyne-3 

*Epoxides, ethers, and acetals: 

Acetone dimethylacetal (2,2-Dimethoxypropane) 

1- (Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)- 

Bis(2-chloroethoxy)methane (Dichloroethylformal) 

Bis(2-chloroethyl) ether (Dichlorodiethyl ether) 

Bis(2-chloro-l-methylethyl) ether (Dichloroisopropyl 
ether) . 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butyl vinyl ether 

2-Chloroethyl vinyl ether 

Chloromethyl methyl ether 

2,2-Dichloro-l,l-difluoroethyl methyl ether 

Dimercaptodiethyl ether 

Epi chlorohydrin 

'Ethylene oxide 

Ethyl ether: 

Absolute 

*Tech 

U.S.P 

Ethyl vinyl ether 

Glycidol (2,3-Epoxy-l-propanol) 

Isobutyl vinyl ether 

* Is opropy 1 ether 

Methyl ether (Dimethyl ether) 

Methyl vinyl ether 

'Propylene oxide 

Triglycol di chloride 

Vinyl methoxytriglycol 

Other 



DUP. 












DOW, 


FRO. 










DUP. 












ALD, 


BRD, 


DUP, 


EK, 


HMY, 


LIL, RSA, SDW. 


AZT, 


WTL. 










CHT, 


KCH. 










AZT, 


CAD, 


NOC, 


RCl 


WTC 


WTL. 


AZT, 


CAD, 


OCC, 


WTC 


WTL 




AZT, 


CAD, 


NOC, 


SHC 


WTC 


WTL. 


GAP. 












IICC. 












ACS, 


RIB, 


PAS, 


PPG 


SFI 




UCC. 












WTC, 


WTL. 










ULS. 












GTL, 


MCH. 










WTL. 












IVTL. 












WTL. 












DOW. 












AAC, 


SHC. 










TKL. 












DOW. 












DOW, 


MOB. 










DOW. 












DOW. 












PUB, 


UCC. 










GAP, 
AAC, 


UCC. 
UCC. 











RH. 
DOW. 

F.VN, USR. 
DOW, SHC, X. 

CAU, CEL, DOW, EKX, JCC, MAT, NWP, OMC, PPG, SHC, SNO, 
UCC, WYN. 



MAL. 

EN J, 

MAL, 

GAP, 

DIX. 

GAF. 

EN J, 

DUP, 

GAF. 

CEL, DOW, JCC, OCC, OMC, UCC, WYN. 

RH. 

UCC. 

EK, ICI, SHC, UCC. 



HPC, USI. 

OMS. 

UCC. 



SHC, UCC. 
UCC. 



SYNTHETIC ORGANIC CHEMICALS/ W72 
TABLE 2.— Miscellaneous chemicals for which US. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1972--C0NTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

All Other Misaellaneous Aayolio Chemicals— Contirmei 

Epoxy curing agents . — — . 

2- (Ethylmercapto)ethanol 

Fats and oils, chemically modified 

Glucono- delta- lac tone 

Glutaraldehyde bis(5odium bisulfite) 

Hexachlorodimethyl sulfone 

n-Hexadecyl disulfide 

Hydrocarbons : 

1-Butyne (Ethylacetylene) 

n-Decane 

n-Dodecane 

1-Dodecene 

Hexadecane 

n-Hexane 

Myrcene 

1-Octadecene 

n-Octane 

I (and 2)-0ctene 

Tri-decane 

Other 

Hydrogenated tallow glycerides 

Lauroyl peroxide 

Magnesium me thy late 

Methane thiol (methyl mercaptan) 

Methyl al (Dimethoxymethane) 

Methyl sulfide (Dimethyl sulfide) 

Methyl sulfoxide 

Organo- aluminum compounds: 

Diethyl aluminum chloride 

Diethylalumi num iodide 

Diisobutyl aluminum chloride 

Diisobutylaluminum hydride 

Ethylaluminum chlorides 

Ethyl aluminum sesqui chloride 

Isopropenylaluminum 

Methyl aluminum sesqui chloride 

Tri e thy 1 a luminum 

Triisobutyl aluminum 

Trimethylaluminum 

Other 

Organo-boron compounds : 

Boron fluoride - ethyl ether complex 

Trie thy lb or ane 

Trimethoxyboroxine 

Trimethyl borate 

Organo- lead compounds: 

*Tetraethyllead 

Tetrame thy Head 

Tetra (methyl -ethyl) lead 

Other 

n- Butyl lithium 

sec- Butyl lithium 

Organo-magnesium halides 

Organo-mercury compounds 

*0rgano-silicon compounds: 

Chlorotrimethylsilane 

Dichlorodimethylsilane 

Dichloromethylsilane 

Dichloromethylvinylsilane 



Manufacturers' identification codes 
(according to list in table 3) 



SHC. 
PLC. 

ABB, DOM. 
PFZ. 
IDC. 

PAS. 



AIP. 




HMY, 


PLC. 


HMY, 


PLC. 


HMY. 




HMY. 




HMY. 




IFF, 


NCI. 


HMY'. 




HMY, 


PLC. 


HMY, 


PLC. 


BLK, 


HMY. 


ALD, 


CBY, HMY. 


CHL. 




AZT, 


WTL. 


MRT. 




DOW. 




CEL. 




CRZ. 




CRZ. 




TNA, 


TSA. 


ISA. 




TNA, 


TSA. 


TSA. 




TNA, 


TSA. 


TNA, 


TSA. 


TSA. 




TNA. 




TNA, 


TSA. 


TNA, 


TSA. 


TNA. 




TSA. 




ACS. 




TSA. 




SFS. 




»1HI. 




DUP 


NLC, PPC, TNA 


DUP, 


NLC, TNA. 


DUP 


PPG. 


TNA 




FTH 


GAF. 


FTE 




ARA 




EK, 


NTB. 


DCC 


UCC. 


DCC 


UCC. 


DCC 


UCC. 


UCC 





MISCELLANEOUS CHEMICALS 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1972--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

All Other Misaellaneous Aayolia Chemicals — Continued 

*Organo- silicon compounds --Continued 

Trichlorobutylsilane 

Trichloroethylsilane 

Trichloromethylsilane 

Trichlorovinylsilane 

Silicone greased 

Other organo- silicon compounds 

Organo-tin compounds: 

Bis(tributyltin) oxide 

Dibutyltin bis lauryl mercaptide 

Dibutyltin di chloride 

Dibutyltin oxide 

Dioctyltin oxide 

Organotin mercaptide 

Tributyltin chloride 

Tributyltin fluoride 

Other 

Organo- zinc compounds 

Oxidized hydrocarbon mixtures 

Perchloromethanethio (Perchloromethyl raercaptan) 

*PhosgenB (Carbonyl chloride) 

Pine oil, synthetic 

S-Propiolactone 

Rare sugars 

Sodium ethoxide 

Sodium formaldehyde bisulfite 

Sodium formaldehyde sulfoxylate 

*Sodium methoxide (Sodium methylate) 

Sodium succinaldehyde bisulfite 

Succinyl peroxide 

Trioctylphosphine oxide 

Zinc formaldehyde 'sulfoxylate 

Other 



DCC. 
DCC. 
DCC. 
UCC. 
SPD. 
DCC, SFS, UCC. 

CCW, X. 



CCW. 
PCW, 



X. 

TSA. 
ALX. 
SFC. 

ACS, CTN, DUP, MOB, OMC , OTC, PPG, RUC, UPJ, VDM. 
CBY, NCI. 
CEL. 
PEN. 
FMP . 

EK, IDC. 
DA, RH. 
DA, OMC, RBC, 
HEX. 
OTL. 
EK. 

DA, RH. 

ABB, ALD, ALX, CEL, EK, GNM, HMY, NLC, NTB, NIL, PIC, 
PLC, RSA, SDW, SFS, SHC, TCH, TNA, UCC, WTL, x, x. 



552-743 O - 74 - 16 



SYNTHETIC ORGANIC CHEfllCALS, 1972 
TABLE 3.— Miscellaneous chemicals: Directory of Manufacturers, 1972 



ALPHABETICAL DIRECTORY BY CODE 

[Names of miscellaneous chemical manufacturers that reported production or sales to the U.S. Tariff Commission for 
1972 are listed below in the order of their identification codes as used in table 2] 



Name of company 



Name of company 



Alcolac Chemical Corp. 

American Aniline § E.xtract Co., Inc. 

Abbott Laboratories 

Arc Chemical Corp. 

Allied Chemical Corp.: 

Agricultural Div. 

Plastics Div. 

Specialty Chemicals Div. 
American Cyanamid Co. 
Agway, Inc., Olean Nitrogen Complex 
Air Products 6 Chemicals, Inc. 
Ark la Chemical Corp. 
Arkansas Co. , Inc. 
Ames Laboratories, Inc. 
Alco Chemical Corp. 
Aldrich Chemical Co., Inc. 
Allied Chemical Corp., Fibers Div. 
Alox Corp. 

American Bio- Synthetic Corp. 
American Chemical Corp. 
Arapahoe Chemicals Div. of Syntex Corp. 
Armak Co. 

Ardmore Chemical Co. , Inc. 

USS Agri- Chemicals, Div. of U. S. Steel Corp. 
Arsynco, Inc. 
Arizona Chemical Co. 

Ashland Oil, Inc., Ashland Chemical Co. Div. 
Ansul Chemical Co. 
Atlantic Richfield Co., ARCO Div. 
PMC Corp. , Fiber Div. 
AZ Products Co. Div. of A2S Corp. 
Dart Industries, Inc., Aztec Chemicals Div. 



Goodrich Chemical 



Baxter Laboratories, Inc. 
B. F. Goodrich Co. , 

Co. Div. 
Pace National Corp. 
J. T. Baker Chemical Co. 
Hillmaster Onyx Corp., Millmaster Chemical 

Co. Div., Berkeley Chemical Dept. 
Borden Co., Borden Chemical Co. Div. 
Stauffer Chemical Co., Specialty Qiemical 

Div., Benzol Products 
Lonza, Inc. 
Buckeye Cellulose Corp. 

Noury Chemical Corp. 

Calcasieu Qiemical Corp. 

Qiembond Corp. 

Crosby Chemicals, Inc. 

Cincinnati Milacron Chemicals, Inc. 

Chase Chemical Corp. 

Pears all Chemical Co. 

Cincinnati Milacron Chemicals, Inc. 

Celanese Corp. : 

Celanese Chemical Co. 

Celanese Fibers Co. 

Celanese Plastics Co. 
Cooperative Farm Chemicals Association 
Ciba-Geigy Corp. 5 

Ciba Pharmaceutical Co. 



CHH 
CHL 
CHN 
CHP 
CHT 

CLK 
CLN 

CNC 

CNP 

CO 

COL 

COM 

CP 

CPS 

CRN 

CRT 

CRZ 

CTN 
CWN 



DAN 
DBC 
DCC 
DEX 
DIX 
DLI 
DOL 
DOM 
DOW 
DUP 
DVC 



EKT 
EKX 
ELP 
01R 
ENJ 
ESA 
EVN 

FCA 
FER 



FIN 
FIS 

FMB 
FMP 

FMT 
FRO 
FTE 
FTX 



Charles Hansen's Laboratory, Inc. 

Chemol, Inc. 

Cherokee Nitrogen Co. 

C. H. Patrick § Co . , Inc. 

Chattem Drug 5 Chemical Co., Chattem 

Chemicals Div. 
Clark Chemical Corp. 
Standard Brands, Inc., Clinton Corp. 

Processing Co. Div. 
Columbia Nitrogen Corp. 
Nipro Inc. 
Continental Oil Co. 
Collier Carbon 5 Chemical Corp. 
Commercial Solvents Corp. 
Colgate-Palmolive Co. 
CPS Chemical Co. 
CPC International, Inc. 
Crest Chemical Corp. 
Crown Zellerbach Corp., Chemical Products 

Div. 
Chemetron Corp., Organic Chemical Div. 
Upjohn Co., Fine Chemical Div. 

Diamond Shamrock Corp. 

Dan River, Inc. 

Dow Badische Co. 

Dow Coming Corp. 

Dexter Chemical Corp. 

Dixie Chemical Co. 

Dawe's Laboratories, Inc. 

Dole Co., Div. of Castle 6 Cook, Inc. 

Dominion Products, Inc. 

Dow Chemical Co. 

E. I. DuPont de Nemours 5 Co., Inc. 

Dover Chemical Corp. 

E. F. Houghton S Co. 
Eastman Kodak Co.: 

Tennessee Eastman Co. Div. 

Texas Eastman Co. Div. 
El Paso Products Co. 
Emery Industries, Inc. 
Exxon Chemical Co. U.S.A. 
East Shore Chemical Co., Inc. 
Evans Chemetics, Inc. 



C. F. Industries Inc. 
Ferro Corp . : 

Ferro Chemical Div. 

Grant Chemical Div. 
Fine Organics, Inc. 
Fisher Chemical Co., Inc. 
FMC Corp . : 

Industrial Chemical Div. 

Industrial Chemical Div. 
Group 



Organic Business 



Fairmount Chemical Co., Inc. 
Vulcan Materials Co., Chemicals Div. 
Foote Mineral Co. 

CF Industries, Inc., Fremont Nitrogen 
Complex 



MISCELLANEOUS CHE^IICALS 
TABLE 3, --Miscellaneous chemicals: Directory of manufacturers, 1972--Continued 



Name of company 



GAF Corp., Chemical Div. 

Gane's Chemical Works, Inc. 

W. R. Grace 5 Co., Agricultural Chem. Group 

G. Frederick Smith Chemical Co. 

Givaudan Corp. 

SCM Corp. Glidden-Durkee Div. 

Glyco Chemicals, Inc. 

General Mills Chemicals, Inc. 

Gulf Oil Corp., Gulf Oil Chemicals Co. -U.S. 

Georgia-Pacific Corp. 

Grain Processing Corp. 

W. R. Grace 5 Co., Polymers 5 Chemicals Div. 

W. R. Grace 5 Co., Hatco Chemical Div. 

Millmaster Onyx Corp., A. Gross 6 Co. Div. 

Great Lakes Chemcal Corp. 

Goodyear Tire & Rubber Co. 

Halby Products Co., Inc. 
C.P. Hall Co. of Illinois 
Hodag Chemical Corp. 
Hexagon Laboratories, Inc. 
Hoffman-Taff, Inc. 
Hooker Chemical Corp.: 

Dure: Plastics Div. 
Hawkeye Chemical Co. 
W. R. Grace 5 Co., Dewey 6 Almy Chemical 

Div. , Organic Chemical 
Humphrey Chemical Co. 
Tenneco Chemicals, Inc. 
Hercules, Inc. 
Hart Products Corp. 
Harshaw Chemical Co., Div. of Kewanee Oil 

Co. 
Kraftco Corp., Humko Products Chemical Div. 

ICI America, Inc. fi Specialty Chemicals Div. 
Industrial Dyestuff Co. 
International Flavors § Fragrances, Inc. 
lonac Chemical Co. 

Jefferson Chemical Co., Inc. 

Nipak , Inc. 

George A. Jeffrey's 5 Co., Inc. 

Jordan Chemical Co. 

Joseph Turner 6 Co. 

Kaiser Aluminum § Chemical Corp., Kaiser 

Chemicals Div. 
Kennecott Copper Corp., Chino Mines Div. 
Keystone Chemurgic Corp. 
Kennecott Copper Corp., Utah Copper Div. 
Kay-Fries Chemicals, Inc. 
H. Kohnstamm 6 Co., Inc. 
Koppers Co., Inc., Organic Materials Div. 

LaMotte Chemical Products Co. 
Lemke Chemicals, Inc. 
Eli Lilly f, Co., Inc. 
Lubrizol Corp. 

Mallinckrodt Chemical Works 

Koch Chemical Co. 

Michigan Chemical Corp. 

Mooney Chemicals, Inc. 

Ventron Corp. 

Miles Laboratories, Inc., Marschall Div. 

Minnesota Mining 6 Manufacturing Co. 

Monochem, Inc. 

Mob ay Chemical Co. 



MON 
MOR 
MRK 
MRT 

MSC 
MTO 

NCI 
NEP 
NES 
NEV 
NLC 
NOC 
NOR 
NPI 

NSC 
NIB 

NTL 



OMC 
OUS 
ONX 
OPC 
ORO 
ORT 
OTC 
OXC 

PAR 

PAS 

PCW 

PD 

PEN 

PEN 

PFW 

PFZ 

PG 

PHR 

PIC 

PLB 

PLC 

PLS 
PUP 
PPC 
PPG 
PRD 
PTT 
PUB 
PVO 

QCP 
QKO 

RBC 
RCI 

RCN 
RBH 



Monsanto Co. 
Marathon Morco, Co. 
Merck 5 Co. , Inc. 

Morton Chemical Co., Div. of Morton- 
Norwich Products, Inc. 
Mississippi Chemical Corp. 
Montrose Chemical Corp. of California 

Union Camp Corp., Chemical Div. 

Nepera Chemical Co. 

Nease Chemical Co., Inc. 

Neville Chemical Co. 

Nalco Chemical Co. 

Norac Co., Inc. and Mathe Chemical Co. Div. 

Norwich Pharmacal Co. 

Stepan Chemicals Co., National Polychemicals 

Div. 
National Starch 6 Chemical Corp. 
National Biochemical Co. 
NL Industries, Inc. 
Northwestern Chemical Co. 
Northern Petrochemicals Co. 

Oxirane Chemical Co. 

Airco, Inc., Ohio Medical Product Div. 

Olin Corp. 

E. R. Squibb 6 Sons, Inc. 

Millmaster Onyx Corp., Onyx Chemical Co. 

Orbis Products Corp. 

Chevron Chemical Co. 

Roehr Chemicals, Inc. 

Ott Chemical Co. 

Oxochem Enterprises 

Pennsylvania Refining Co. 

Pennwalt Corp. 

Pfister Chemical Works 

Parke, Davis 5 Co. 

CPC International, Inc., S. B. Penick Div. 

Pfanstiehl Laboratories, Inc. 

Polak's Frutal Works, Inc. 

Pfizer, Inc. 

Procter 5 Gamble Co. 

Pharmachem Corp. 

Pierce Chemical, Inc. 

P-L Biochemicals , Inc. 

Phillips Petroleum Co. 5 Phillips Pacific 

Chemical Co. 
Plastics Engineering Co. 
Premier Malt Products, Inc. 
Premier Petrochemical Co. 
Pittsburgh Plate Glass Co. 
Productol Chemical Co., Inc. 
Petro-Tex Chemical 
Publicker Industries, Inc. 
PVO International, Inc. 

Quaker Chemical Corp. 
Quaker Oats Co. 

Fike Chemicals, Inc. 

Reichhold Chemicals, Inc. 

Racon, Inc. 

Reheis Chemical Co. Div. of Armour 

Pharmaceutical Co. 
Remington Arms Co., Inc. 
Rohm § Haas Co. 
Robeco Chemicals, Inc. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3.— Miscellaneous chemicals: Directory of manufacturers. 1972— Continued 



Code 


Name of company 


Code 


Name of company 


RPC 


Millmaster Onyx Corp., Refined-Onyx Div. 


TEK 


Teknor Apex Co. 


RSA 


R.S.A. Corp. 


TER 


Terra Chemicals International, Inc. 


RT 


F. Ritter S Co. 


TID 


Getty Oil Co. 


RUB 


Hooker Chemical Corp, , Ruco Div. 


TKL 


Thiokol Chemical Corp. 


RUC 


Rubicon Chemicals, Inc. 


TNA 


Ethyl Corp. 






TNI 


Gillette Chemical Co., Div. of Gillette Co. 


S 


Sandoz, Inc., Sandoz Colors 6 Chemical 


tri 


Triad Chemicals 




Div. 


TRO 


Troy Chemical Co. 


SAL 


Salsbury Laboratories 


TSA 


Texas Alky Is, Inc. 


SAR 


Sartomer Industries, Inc. 


ttx 


Detrex Chemical Industries, Inc. 


SBC 


Scher Bros. 


TX 


Texaco, Inc. 


SCH 


Schering Corp. 


TZC 


Tizon Chemical Corp. 


SDC 


Martin-Marietta Corp., Sodeyco Div. 








Sterling Drug, Inc.: 


UCC 


Union Carbide Corp. 


SDH 


Hilton-Davis Chemical Co. Div. 


UOP 


Universal Oil Products Co., UOP Chemical Di 


SDW 


Winthrop Laboratories Div. 


UPJ 


Upjohn Co. 




Stauffer Chemical Co.: 


UPM 


Universal Oil Products Co. 


SPA 


Agricultural Div. 


USB 


U.S. Borax Research Corp. 


SFC 


Calhio Chemicals, Inc. Div. 


US I 


National Distillers 6 Chemical Corp., U.S. 


SFI 


Industrial Div. 




Industrial Chemicals Co. Div. 


SFS 


Specialty Chemical Div. 


USS 


USS Chemicals Div. of U.S. Steel Corp. 


SHA 


Shanco Plastics 5 Chemical Co. 


USR 


Uniroyal, Inc., Chemical Div. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 






SHF 


Kraftco Corp., Sheffield Chemical Div. 


VAC 


Northern Petrochemical Co. 


SHP 


Shepherd Chemical Co. 


VAL 


Valchem 


SK 


Smith, Kline 5 French Laboratories 


VDM 


Van De Mark Chemical Co. 


SKG 


Sunkist Growers, Inc. 


VEL 


Velsicol Chemical Corp., Inc. 


SKO 


Skelly Oil Co. 


VGC 


Virginia Chemicals, Inc. 


SM 


Mobil Oil Corp., Mobil Qiemical Co., 


VLN 


Valley Nitrogen Producers, Inc. 




Chemical Coatings Div. 


™d 


Van Dyk 5 Co. , Inc. 




Industrial Chemical Div. 


VPC 


Verona Corp . 


SNI 


Kaiser Aluminum 5 Chemical Corp., Kaiser 








Agricultural Chemicals Div. 


WAY 


Phillip A. Hunt Chemical Corp., Wayland 


SNO 


SunOlin Chemical Co. 




Chemical Div. 


SNW 


Sun Chemical Corp., Chemical Div. 


WBC 


Worthington Biochemical Corp. 


SOC 


Standard Oil Co. of California, Chevron 


WBG 


White 5 Bagley Co. 




Chemical Co. 


WCL 


Wright Chemical Co. 


SOH 


Vistron Corp. 


WES 


Borg-Warner Corp., Weston Chemical Div. 


SOI 


American Oil Co. CMaryland) 


mi 


Wilson Pharmaceutical 5 Chemical Corp., 


SPD 


General Electric Co., Silcon Products 




Wilson-Martin Div. 




Dept. 


WMP 


Essex International, Inc., Electro- 


SPR 


Scientific Protein Laboratories 




Mechanical Div. 


SIP 


Stepan Chemical Co. 


WSN 


Mallinckrodt Chemical Works, Washine Div. 


SW 


Sherwin-Williams Co. 


wtc 


Witco Chemical Co., Inc. 


SYP 


Dart Industries, Inc., Synthetic Products 


WTH 


Union Camp Corp., Harchem Div. 




Co. Div. 


WTL 


Pennwalt Corp., Lucidal Div. 






WYC 


Wycon Chemical Co. 


tae 


Chemetron Corp., Medical Products 

Div. 
Tanatex Chemical Corp 


WYN 


Wyandotte Chemicals Corp. 


TCC 


ZGL 


Carolina Processing Corp. 


TCH 


Emery Trylon Chemicals Div. Industries 








Inc. 







Note. — Complete name= and addresses of the above reporting companies 



listed in Table 1 of the Appendix. 



APPENDIXES 



APPENDIX A 
DIRECTORY OF HANUFACTURERS 

TABLE 1.— Synthetic organic chemicals; Alphabetical Directory of manufacturers, by company. 1972 

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission 
for 1972 are listed below alphabetically, together with their identification codes as used in table 2 of the 14 
individual sections of this report] 




Office address 



A 5 E Plastic Pak Co., Inc 

AZS Corp . : 

AZ Products Co. Div 

Lancaster Chemcial Co. Div 

Abbott Laboratories 

Abex Corp. , .American Brakelok Div 

Acme Chemical Co 

Acme Resin Co 

Agway, Inc. , Olean Nitrogen Div 

Airco, Inc., Ohio Medical Products Div 

Air Products S Chemicals, Inc., Chemicals 
Group 

Alco Chemical Corp. 

Alcolac, Inc 

Aldrich Chemical Co. , Inc 

Alliance Chemical Co., Inc 

Allied Chemical Corp.: 

Fibers Div 

Plastics Div 

Seme t- Sol vay Div 

Specialty Chemicals Div 

Union Texas Petroleum Div 

Agr i cu 1 tural Dep t 

Alox Corp 

Alpha Laboratories, Inc 

Amchem Products, Inc., Div. of Rorer- 
Amchem, Inc. 

Amerace-Esna Corp. , Penetone Div 

Amerada Hess Corp 

American Aniline 5 Extract Co., Inc 

American Aniline Products, Inc 

American Bio-Synthetics Corp 

American Can Co 

American Chemical Corp 

.American Cyanamid Co 

.American Hoechst Corp 

American Oil Co. (Maryland) 

American Oil Co. (Texas) 

.American Synthetic Rubber Corp 

Ames Laboratories, Inc 

Amoco Chemical Corp 

.Amoco Production Co 

Ansul Chemical Co 

Apex Chemical Co. , Inc 

Apollo Colors, Inc 

Applied Plastics Co. , Inc 

Arapahoe Chemicals Div. of Syntex Corp 

Arc Chemical Corp 

Ardmore Chemical Co. , Inc 

Arenol Chemical Corp 

Argus Chemical Corp., Halby Div 

Arizona Chemical Co 

.Arkansas Co. , Inc 

Arkla Chemical Corp 

Armak Co 



14505 E. Proctor .Ave. , Industry, CA 91747. 

2525 So. Combee Rd., Eaton Park, FL 33840. 

Broad 6 13th St., Carlstadt, NJ 07072. 

14th St. and Sheridan Rd., N. Chicago, IL 60664. 

2401 S. Loudoun St., Winchester, VA 22601. 

2S06 N. 32d St., Milwaukee, WI 53245. 

1401 S. Circle Ave., Forest Park, IL 60130. 

1446 Buffalo St., Olean, NY 14760. 

3030 Airco Dr., P.O. Box 1319, Madison, KI 53701. 

5 Executive Mall, Swedesford Rd. , Wayne, PA 19087. 

Trenton Ave. and William St., Philadelphia, PA 191 
3440 Fairfield Rd. , Baltimore, MD 21226. 
940 W. St. Paul Ave., Milwaukee, WI 53233. 
33 Avenue P, Newark, NJ 07105. 

1 Times Square, New York, NY 10036. 
P. 0. Box 2365R, Morristown, NJ 07960. 
P. 0. Box 1013R, Morristown, NJ 07960. 
P. 0. Box 1219R, Morristown, NJ 07960. 
P. 0. BOX 2120, Houston, TX 77001. 
P. 0. Box 2120, Houston, TX 77001. 
3943 Buffalo .Ave., Niagara Falls, NY 14302. 
1685 S. Fairfax St., Denver, CO 80222. 
Brookside Ave., Ambler, PA 19002. 

74 Hudson Ave., Tenafly, NJ 07670. 

1 Hess Plaza, Woolridge, NJ 07095. 

Venango and F Sts., Philadelphia, PA 19134. 

P. 0. Box 3063, Paterson, NJ 07509. 

710 W. National Ave., Milwaukee, WI 53204. 

American Lane, Greenwich, CT 06830. 

2112 E. 223d St., P. 0. Box 1110, Long Beach, CA 9 

Wayne, NJ 07470. 

129 Quidnick St., Coventry, RI 
910 S. Michigan Ave., Chicago, 
910 S. Michigan Ave., Chicago, 
P. 0. Box 360, Louisville, KY 
200 Rock Lane, Milford, CT 06460. 

130 E. Randolph Dr., Chicago, IL 60601. 
P. n. Box 591, Tulsa, OK 74102. 
1 Stanton St., Marinette, WI 54143. 
200 S. 1st St., Elizabethport, NJ 07206. 
899 Skokie Blvd., Northbrook, IL 60062. 
612 E. Franklin Ave., El Segundo, CA 90245. 
2855 Walnut St., Boulder, CO 80302. 
P. 0. Box 175, Slate Hill, NY 10923. 
840 Valley Brook Ave., Lyndhurst, NJ 07071. 
40-33 23d St., Long Island City, NY 11101. 
600 Terminal Ave., New Castle, DE 19720. 
Wayne, NJ 07470. 

185 Foundry St., Newark, NJ 07105. 
P. 0. Box 825, Helena, AK 72342. 
300 S. Wacker Dr., Chicago, IL 60601. 



02816. 
IL 60680. 
IL 60680. 
40201. 



SYNTHETIC ORGANIC CHEMICALS. B72 
TABLE L— Synthetic organic chemicals; Alphabetical directory of manufacturers. 

BY COMPANY. 1972— CONTINUED 




Armour- Dial, Inc 

Armstrong Cork Co 

Arol Chemical Products Co 

Arsynco, Inc 

Ashland nil, Inc 

Ashland Chemical Co. Div 

Astor Products, Inc., Blue Arrow Div 

Astra Pharmaceutical Products, Inc 

Atlantic Chemical Corp 

Atlantic Richfield Co., ARCO Chemical Co. 

Div. 
Atlas Processing Co 

BASF Wyandotte Corp 

BP Oil Corp 

J. T. Baker Chemical Co 

Baltimore Paint 5 Chemical Corp 

Baxter Laboratories, Inc 

Baychera Corp. : 

Chemagro Div 

Verona Div 

Bayoil Co., Inc 

Beecham, Inc 

Beech- Nut, Inc 

Belding Chemical Industries 

Bendix Corp., Friction Materials Div 

Bennett's 

Benzenoid Organics, Inc 

Bemcolors-Poughkeepsie , Inc 

Biocraft Laboratories, Inc 

Bio- Derivatives Corp 

Blackman Uhler Chemical Co 

Borden, Inc., Borden Chemical Div 

Borg-Wamer Corp., Marbon Chemical Div — 
Borg-Wamer Corp., Weston Chemical Div — 

Breddo Food Products Corp 

Bristol-Meyers Co. , Bristol Laboratories 
Div. 

M. A. Bruder fi Sons, Inc 

Buckeye Cellulose Corp 

Buckman Laboratories, Inc 

Budd Co., Polychem Div 

Burdick f, Jackson Laboratories, Inc 

Burroughs S Wellcome Co 

CF Industries, Inc 

Fremont Nitrogen Complex 

CPC International, Inc 

S. B. Penick Co 

CPS Chemical Co 

Samuel Cabot, Inc 

Calcasieu Chemical Corp 

Carborundum Co. , Coated Abrasives Div 

Car gill , Inc 

Carolina Processing Corp 

Carpenter-Morton Co 

Carus Corp., Carus Chemical Co. Div 

Castle 5 Cook, Inc., Hawaii Region 



Office address 



P. 0. Box 4309, Chicago, IL 60680. 

Liberty and Charlotte Sts . , Lancaster, PA 17604. 

649 Ferry St., Newark, NJ 07105. 

P. 0. Box 8, Carls tadt, NJ 07072. 

1401 Winchester Ave., Ashland, KY 41101 and 

P. n. Box 2458, Columbus, OH 43216. 
5200 Blazer Blvd., Dublin, OH 43215. 
5244 Edgewood Ct . , Jacksonville, FL 32203. 
7-1/2 Neponset St., Worcester, MA 01606. 
10 Kingsland Rd., Nutley, NJ 07110. 
260 S. Broad St., Philadelphia, PA 19101. 

P. 0. Box 9389, 3546 Midway St., Shreveport, LA 71109. 

100 Cherry Hill Rd . , Parsippany, NJ 07054. 

398 Midland Bldg. , Cleveland, OH 44115. 
222 Red School Lane, Philipsburg, NJ 08865. 
2325 Hollins Ferry Rd., Baltimore, MD 21230. 
6301 Lincoln Ave., Morton Grove, IL 60053. 

P. 0. Box 4913, Station "F", Kansas City, MO 64120. 

lorio Ct., Union, NJ 07083. 

2 Union St., Peabody, MA 01960. 

65 Industrial S., Clifton, NJ 07012. 

Church St., Canajorharie , NY 13317. 

1430 Broadway, New York, NY 10018. 

P. 0. Box 238, Troy, NY 12180. 

65 W. 1st S. St., Salt Lake City, UT 84110. 

P. 0. Box 157, Bellingham, MA 02019. 

75 N. Water St., Poughkeepsie , NY 12602. 

12 Industrial Way, Waldrich, NJ 07463. 

174 E. Industry Ct . , Deer Park, NY 11729. 

P. 0. Box 5627, Spartanburg, SC 29301. 

50 W. Broad St., Columbus, OH 43215. 

P. 0. Box 68, Washington, WV 26181. 

103 Spring Valley Rd., Montvale, NJ 07645. 

18th and Kansas, Kansas City, KS 66105. 

P. 0. Box 657, E. Syracuse, NY 13257. 

52d St. and Grays Ave., Philadelphia, PA 19143. 

2899 Jackson Ave., Memphis, TN 38108. 

1256 N. McLean Blvd., Memphis, TN 38108. 

70 S. Chapel St., Newark, DE 19711. 

1953 S. Harvey St., Muskegon, MI 49442. 

3030 Comwallis Rd., Research Triangle Park, NC 27709 

P. 0. Box 87, Harrison, TN 37341. 

P. 0. Box 68, RFDH3, Fremont, NB 68025. 

International Plaza, Englewood Cliffs, NJ 07632. 

100 Church St., New York, NY 10007. 

P. 0. Box 162, Old Bridge, NJ 08857. 

One Union St., Boston, MA 02108. 

P. 0. Box 1522, Lake Charles, LA 70601. 

Walmore Rd. , P. 0. Box 477, Niagara Falls, NY 14302. 

Cargill Bldg., Minneapolis, m 55402. 

P.O. Box 161, Severn, NC 27877. 

376 3d St., Everett, MA 02149. 

1500 8th St., LaSalle, IL 61301. 

P. 0. Box 338, Honolulu, HI 96801. 



APPENDIX A 

TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, 
BY company, 1'^7?--Continued 



Name of company 



Office address 



Celanese Corp. : 

Celanese Chemical Co 

Celanese Coatings Co 

Celanese Fibers Co 

Celanese Plastics Co 

Champlin Petroleum Co 

Charrain Paper Products Co 

Charter International Oil Co 

Chase Chemical Corp 

Chattem Drug § Chemical Co., Chattara 
Chemicals Div. 

Chembond Corp 

Chemed Corp . : 

Dubois Chemicals Div 

Vestal Laboratories Div 

Chemetron Corp. : 

Medical Products Div 

Organic Chemical Div 

Pigments Div 

Chem-Fleur, Inc 

Chemical Formulators, Inc 

Chemlek Laboratories, Inc 

Chemol, Inc 

Chemplex Co 

Cherokee Nitrogen Co 

Chevron Chemical Co 

Childs Pulp Colors, Inc 

CHR Hansen's Laboratory, Inc ^.- 

Ciba-Geigy Corp 

Ciba Agrochemical Co 

Ciba Pharmaceutical Co 

Cincinnati Milacron Chemicals, Inc 

Cindet Chemicals, Inc 

Cities Service Co. : 

Columbia Div 

Copperhill Operations 

Levey Div 

Petrochemicals Group 

Cities Service Oil Co 

Clark Chemical Corp 

W. A. Cleary Corp 

Clintwood Chemical Co 

Coastal States Petrochemical Co 

Colgate-Palmolive Co 

Collier Carbon 5 Chemical Corp 

Colloids, Inc 

Columbia Nitrogen Corp 

Commercial Products Co. , Inc 

Commercial Solvents Corp 

Commonwealth Oil Refining Co. , Inc 

Commonwealth Petrochemicals, Inc 

Conap, Inc 

Conchemco, Inc. : 

Kansas City Div 

Concord Chemical Co., Inc 

Consolidated Papers, Inc 

Continental Chemical Co 

Continental Oil Co 

Cook Paint 5 Varnish Co 

Cooperative Farm Chemicals Association- 
Cooper Polymers, Inc 



245 Park Ave., New York, NY 10017. 
1495 S. nth St., Louisville, KY 40208. 
P. 0. Box 1414, Charlotte, NC 28201. 
5S0 Broad St., Newark, NJ 07102. 
P. 0. Box 9176, Corpus Christi, TX 78408. 
800 Hoberg St., Green Bay, WI 54305. 
P. 0. Box 5008, Houston, TX 77012. 
3527 Smallman St., Pittsburgh, PA 15201. 
1715 W. 38th St., Chattanooga, TN 37409. 

P. 0. Box 270, Springfield, OR 97477. 

Dubois Tower, Cincinnati, OH 45202. 

4963 Manchester Ave., St. Louis, MO 63110. 

1801 Lilly St., St. Louis, MO 63110. 

P. 0. Box 480, Newport, TN 37821. 

491 Columbia Ave., Holland, MI 49423. 

200 Pulaski St., Newark, NJ 07105. 

P. 0. Box 26, Nitro, WV 25143. 

4040 W. 123d St., Alsip, IL 60658. 

P. 0. Box 20687, Greensboro, NC 27420. 

3100 Golf Rd., Rolling Meadows, IL 60008. 

P. 0. Box 429, Pryor, OK 74361. 

200 Bush St., San Francisco, CA 94120. 

5 Albany St., Springfield, MA 01101. 

9015 IV. Maple St., Milwaukee, WI 53214. 

444 Saw Mill River Rd. , Ardsley, NY 10502. 

P. 0. Box 1142, Greensboro, NC 27409. 

556 Morris Ave., Summit, NJ 07901. 

500 Jersey Ave., New Brunswick, NJ 08903 and West St. 

Reading, OH 45215. 
2408 Doyle St., Greensboro, NC 27406. 

P. 0. Box 1522, Lake Charles, LA 70601. 

Copperhill, TN 37317. 

630 Glendale-Milford Rd., Cincinnati, OH 45215. 

60 Wall St., New York, NY 10005. 

P. 0. Box 300, Tulsa, OK 74102. 

131st St. f, Kedzie Ave., Blue Island, IL 60406. 

P. 0. Box 710, Somerset, NJ 08873. 

4342 S. Wolcoth Ave., Chicago, IL 60609. 

P. 0. Drawer 521, Corpus Christi, TX 78403. 

300 Park Ave., New York, NY 10022. 

461 S. Boyston, Los Angeles, CA 90017. 

394 Frelinghuysen Ave., Newark, NJ 07114. 

P. 0. Box 1483, Augusta, GA 30903. 

117 Ethel Ave., Hawthorne, NJ 07641. 

245 Park Ave., New York, NY 10017. 

Petrochemical Complex, Ponce, PR 00731. 

Petrochemical Complex, Ponce, PR 00731. 

184 E. Union St., Allegany, NY 14706. 

10000 Marshall Dr., Lenoxa, KS 66215. 

18th 5 Garfield Sts., Kansas City, MO 64127. 

17th f, Federal Sts., Camden, NJ 08105. 

Wisconsin Rapids, WI 54494. 

270 Clifton Blvd., Clifton, NJ 07015. 

Park Eighty Plaza East, Saddle Brook, NJ 07662. 

P. 0. Box 389. Kansas City, MO 64141. 

P. 0. Box 308, Lawrence, KS 66044. 

820 Woburn St., Wilmington, MA 01887. 



SYNTHETIC OTiflNIC CHEHICALS, P7? 



TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers^ 

BY COMPANY, 197?— CONTINUED 



Name of company 



Coopers Creek Chemical Corp 

Copolymer Rubber 6 Chemical Corp 

Cosden Oil § Chemical Co 

Crest Chemical Corp 

Croda, Inc 

Crompton 5 Knowles Corp., Dyes 6 Chemical 

Div. 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Metro, Inc 

Crown Zellerbach Corp., Chemical Products 

Div. 

Dan River, Inc 

Dart Industries, Inc.: 

Azetec Chemicals Div 

Rexene Polymers Co. Div 

Synthetic Products Co. Div 

Davies- Young Co 

Dawe's Laboratories, Inc 

Degen Oil f, Chemical Co 

Dennis Chemical Co 

Depaul Chemical Co., Inc 

DeSoto, Inc 

Detrex Chemical Industries, Inc 

Dexter Chemical Corp 

Hysol Div 

Midland Div 

Diamond Plastics, Inc 

Diamond Shamrock Corp 

Dixie Chemical Co 

Dixie Pine Products Co., Inc 

Dominion Products, Inc 

Dover Chemical Co 

Dow Badische Chemical Co 

Dow Chemical Co 

Dow Coming Corp 

E. I. duPont de Nemours 5 Co., Inc 

Dye Specialties, Inc 

Eagle Pitcher Industries, Inc., Rubber 
Products Div. 

Eagle River Chemical Corp 

Eastern Color 5 Chemical Co 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

East Shore Chemical Co., Inc 

Eastside Chemical Laboratory 

Elan Chemical Co 

Electro-Seal Glasflex Corp 

El Paso Products Co 

Emery Industries, Inc 

Trylon Chemicals Div 

Emkay Chemical Co 

Endo Laboratories, Inc 

Enenco, Inc 

Epoxylite Corp 

Essential Chemicals Group 

Essex International, Inc., Electro- 
Mechanical Div. 

Ethyl Corp 

Evans Chemetics, Inc 



Office address 



River Rd. , W. Conshohocken, PA 19428. 
P. 0. Box 2591, Baton Rouge, LA 70821. 
P. 0. Box 1311, Big Spring, Tx 79720. 
225 Emmet St., Newark, NJ 07114. 
51 Madison Ave., New York, NY 10010. 
500 Pear St., Reading, PA 19603. 

P. 0. Box 460, Picayune, LA 39466. 
1 No. Charlis St., Baltimore, MD 21201. 
12 Dudley St., Providence, RI 02901. 
Camas, WA 98607. 



Danville, VA 24541. 

555 Garden St., Elyria, OH 44035. 

W. lis Century Rd. , Paramus , NJ 07657. 

1636 Wayside Rd., Cleveland, OH 44112. 

2700 Wagner Place, Maryland Heights, MO 63043. 
450 State St., Chicago Heights, IL 60411. 

200 Kellogg St., Jersey City, NJ 07305. 

2701 Papin St., St. Louis, MO 63103. 

44-27 Purvis St., Long Island City, NY 11101. 

1700 S. Mt. Prospect Ave., Des Plaines, IL 60018. 

14 331 Woodrow Wilson, Detroit, MI 48232. 

845 Edgewater Rd. , Bronx, NY 10474. 

211 Franklin St., Olean, NY 14760. 

E. Water St., P. 0. Box 620, Waukegan, IL 60085. 

6421 Paramount Blvd., Long Beach, CA 90805. 

100 Superior Ave., Cleveland, OH 44114. 

3635 W. Dallas Ave., Houston, TX 77019. 

P. 0. Box 470, Hattiesburg, MS 39401. 

882 3d Ave., Brooklyn, NY 11232. 

W. 15th and Davis Sts . , Dover, OH 44622. 

P. 0. Drawer "D", Williamsburg, VA 23605. 

Hopkins Bldg. , Midland, MI 48640. 

P. 0. Box 1592, Midland, MI 48640. 

DuPont Bldg., Wilmington, DE 19898. 

26 Journal Sq., Jersey City, NJ 07306. 

P. 0. Box 755, Denton, TX 76201. 

P. 0. Box 665, Marinette, WI 54143. 

35 Livingston St., Providence, RI 02904. 

343 State St., Rochester, NY 14650. 

P. n. Box 511, Kingsport, TN 37662. 

P. 0. Box 7444, Longview, TX 75601. 

1221 E. Barney Ave., Muskegon, HI 49443. 

12880 NE Bellevue-Redmond Rd., Bellevue, WA 98005 

268 Doremus Ave., Newark, NJ 07105. 

Stirling, NJ 07980. 

P. 0. Box 3986, Odessa, TX 79760. 

4300 Carew Tower, Cincinnati, OH 45202. 

P. 0. Box 628, Mauldin, SC 29662. 

319 2d St., Elizabeth, NJ 07206. 

1000 Stewart Ave., Garden City, NY 11530. 

P. 0. Box 398, Memphis, TN 38101. 

1901 Via Buxton, Anaheim, CA 92806. 

28391 Essential Rd. , Merton, WI 53056. 

1601 Wall St., Fort Wayne, IN 46804. 

330 S. 4th St., Richmond, VA 23217. 
90 Tokeneke Rd., Darien, CT 06820. 



APPENDIX A 



TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY, 1972— CONTINUED 



Name of company 



Office address 



Exxon Corp., Exxon Chemical Co. U.S.A. 

FMC Corp . : 

Fibers Div 

Industrial Chemical Div 

Industrial Chemical Div., Organic 
Business Group 

Niagara Chemical Div 

FRP Co 

Fabricolor Manufacturing Corp 

Fairmount-Chemical Co., Inc 

Far-Best Corp., 0. L. King Div 

Famow, Inc 

Felton International, Inc 

Ferro Chemical Corp. : 

Ferro Chemical Div 

Grant Chemical Div 

Fike Chemicals, Inc 

Fine Organics, Inc 

Finetex Corp 

Firestone Tire 5 Rubber Co.: 

Firestone Plastics Co. Div 

Firestone SyTithetic Rubber 5 Latex Co. 
Div. 

First Chemical Corp 

Fisher Chemical Co., Inc 

Fleming Laboratories, Inc 

Florasynth Laboratories, Inc 

Foote Mineral Co 

Formica Corp 

Foster Grant Co. , Inc 

France, Campbell 6 Darling, Inc 

Freeman Chemical Corp 

Frisch 6 Co., Inc 

Fritzsche Dodge § Olcott, Inc 

H. B. Fuller Co r 

Fuller- O'Brien Corp 

GAF Corp 

Chemical Div 

Gane's Chemical Works, Inc 

Genera] Electric Co 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div 

General Latex § Chemical Corp 

General Mills Chemicals, Inc 

General Plastics Manufacturing Co 

General Tire § Rubber Co., Chemical Div 

P. D. George Co 

George A. Jeffreys § Co 

Georgia-Pacific Corp 

Bellingham Div 

Getty Oil Co 

Gillette Chemical Co. Div. of Gillette Co. 
Gilman Paint § Varnish Co 



P. 0. Box 32 72, Houston, TX 77001 and Odenton, 
MD 21113. 



1617 John F. Kennedy Blvd., Philadelphia, PA 19103. 
633 3d Ave., New York, NY 10017 and Sawyer Ave. § 

River Rd., Town of Tonawanda, NY 14150. 
635 3d Ave., New York, NY 10017. 

100 Niagara St., Middleport, NY 14105. 

P. 0. Box 349, Baxley, GA 31513. 

24-1/2 Van Houten St., P. 0. Box 2398, Paterson. 

NJ 07505. 
117 Blanchard St., Newark, NJ 07105. 
640 Gilman St., Berkeley, CA 94710. 
77 Jacobus Ave., S. Kearney, NJ 07032. 
599 Johnson Ave., Brooklyn, NY 11237. 

P. 0. Box 46-349, 7050 Krick Rd. , Bedford, OH 44146. 

P. 0. Box 263, Baton Rouge, LA 70821. 

P. 0. Box 546, Nitro, WV 25143. 

205 Main St., Lodi , NJ 07644. 

418 Falmouth Ave., Elmwood Park, NJ 07407. 

P. n. Box 699, Pottstown, PA 19464. 
381 W. Wilbeth Rd., Akron, OH 44301. 

P. 0. Box 1427, Pascagoula, MS 39567. 

5200 Paul G. Blazer Memorial Pkwy., Dublin, OH 43216. 

P. 0. Box 10373, Charlotte, NC 28201. 

900 Van Nest Ave., Bronx, NY 10462. 

Route 100, Exton, PA 19341. 

120 E. 4th St., Cincinnati, OH 45202. 

289 N. Main St., Leominster, MA 01453. 

209 N. Michigan Ave., Kenilworth, NJ 07033. 

222 E. Main St., Port Washington, WI 53074. 

88 E. 11th St., Paterson, NJ 07524. 

76 9th Ave., New York, NY 10011. 

2400 Kasota Ave., St. Paul, MN 5S108. 

450 E. Grand Ave., S. San Francisco, CA 94080. 

1228 Chestnut St., Chattanooga, TN 37402. 

P. 0. Box 12, Linden, NJ 07036. 

535 5th Ave., New York, NY 10017. 

1 Plastics Ave., Pittsfield, MA 01201 and 135 So. 

Second St., Coshocton, OH 43812. 
1 Campbell Rd. , Schenectady, NY 12306. 
Waterford, NY 12188. 
1125 Hudson St., Hoboken, NJ 07030. 
666 Main St., Cambridge, MA 02139. 
4620 W. 77th St., Mann, MN 55435 

3481 S. 35th St., Tacoraa, WA 98409. 

1 General St., Akron, OH 44309. 

5200 N. 2d St., St. Louis, MO 63147. 

P. 0. Box 709, Salem, VA 24153. 

900 S.W. 5th Ave., Portland, OR 97240. 

P. 0. Box 1236, Bellingham, WA 98225. 

Delaware, DE 19706. 

3500 W. 16th St., N. Chicago, IL 60064. 

W. 8th and Pine Sts., Chattanooga, TN 37401. 



SYNTHETIC ORGflNlC CHEMICALS. 1972. 



TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers, 
BY company. 1972— Continued 



Name of company 



Givaudan Corp 

Glidden Durkee Famous Foods 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 

Goodyear Tire 5 Rubber Co 

Gordon Corp 

Gordon Chemical Co., Inc 

W. R. Grace 5 Co. : 

Agricultural Chemical Group 

Dewey 5 Almy Chemical Div. Organic 
Chemicals 

Hatco Chemical Div 

Marco Chemical Div 

Polymers S Chemicals Div 

Grain Processing Corp 

Great American Chemical Corp 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Guardsman Chemical Coatings, Inc 

Gulf Oil Corp. ; 

Gulf Adhesives 

Gulf Oil Chemicals Co. - U. S. 

Guth Corp 

H 6 N Chemical Co 

Haag Laboratories, Inc 

C. P. Hall Co. of Illinois 

Handschy Chemical Co., Farac Oil and 

Chemical Div. 

Hanna Chemical Coatings Corp 

Hardman, Inc 

Harshaw Chemical Co. Div. of Kewanee Oil 

Co. 

Hart Products Corp 

Haveg Industries, Inc 

Hawkeye Chemical Co 

Henkel , Inc 

Hercor Chemical Corp 

Hercules, Inc 

Heresite 5 Chemical Co 

Heterochemical Corp 

Hewitt Soap Co., Inc 

Hexagon Laboratories, Inc 

Hexcel Corp., Rezolin Div 

Hodag Chemical Corp 

Hoffmann- LaRoche, Inc 

Hoffman-Taff, Inc 

Hooker Chemical Corp 

Durex Div 

Ruco Div 

E. F. Houghton 6 Co 

Humphrey Chemical Co 

Philip A. Hunt Chemical Corp., Wayland 

Chemical Div. 

Huntington Laboratories, Inc 

Husky Industries, Inc 

Hynson, Westcott § Dunning, Inc 

ICI America, Inc 

ITT Rayonier, Inc 

INDPOL- 



Office address 



ino Delawanna Ave., Clifton, NJ 07014. 
2333 Logan Blvd., Chicago, IL 60647. 
51 Weaver St., Greenwich, CT 06830. 
6100 Oak Tree Blvd., Cleveland, OH 44131. 

1144 E. Market St., Akron, OH 44313. 
300 S. 3d St., Kansas City, KS 66118. 
88 Webster St., Worcester, MA 01603. 

P. 0. Box 277, Memphis, TN 38101. 
Poisson Ave., Nashua, NH 03060. 



King George Post Rd., Fords, NJ 
1711 W. Elizabeth Ave., Linden, 
62 Whittemore Ave., Cambridge 
1600 Oregon St., Muscatine, L 



08863. 
J 07036. 
02140. 
52761. 



MA 



650 Water St., Fitchburg, MA 01420. 
P. 0. Box 2200, West Lafayette, IN 47906. 
P. 0. Box 5308, Terminal Annex, Denver, CO 80217. 
1350 Steele Ave., S.W. , Grand Rapids, MI 49502, and 
1350 S. 15th St., Louisville, KY 40210. 

632 No. Cannon Ave., Lansdale, PA 19446. 
P. 0. Box 2100, Houston, TX 77001. 
P. 0. Box 302, Naperville, IL 60540. 

90 Maltese Dr., Totowa, NJ 07512. 
14010 S. Seeley Ave., Blue Island, IL 60406. 
7300 S. Central Ave., Chicago, IL 60638. 
13601 S. Ashland Ave., Riverdale, IL 60627. 

P. 0. Box 147, Columbus, OH 43216. 

600 Cortlandt St., Belleville, NJ 07109. 

1945 E. 97th St., Cleveland, OH 44106. 

173 Sussex St., Jersey City, NJ 07302. 

900 Greenback Rd., Wilmington, DE 19808. 

P. 0. Box 899, Clinton, LA 52733. 

1301 Jefferson St., Hoboken, NJ 07030. 

Petrochemical Complex, Ponce, PR 00731. 

910 Market St., Wilmington, DE 19899. 

822 S. 14th St., Manitowoc, WI 54220. 

Ill E. Hawthorne Ave., Valley Stream, NY 11580. 

333 Linden Ave., Dayton, OH 45403. 

3536 Peartree Ave.. Bronx, NY 10475. 

20701 Nordhoff St., Chatsworth, CA 91311. 

7247 N. Central Park Ave., Skokie, IL 60076. 

324-424 Kingsland St., Nutley, NJ 07110. 

P. 0. Box 1246 SSS, Springfield, MO 65805. 

MPO Box 8, Niagara Falls, NY 14302. 

Walck Rd. , N. Tonawanda, NY 14121. 

P. 0. Box 456, Burlington, NJ 08016. 

303 W. Lehigh Ave., Philadelphia, PA 19133. 

Devine St., North Haven, CT 0647 3. 

P. 0. Box 0, Lincoln, RI 02865. 

P. 0. Box 710, Huntington, IN 46750. 

62 Perimeter Center E. , Atlanta, GA 30346. 

Charles and Chase Sts . , Baltimore, MD 21201. 

Concord Pike § Murphy Rd., Wilmington, DE 19899. 

161 E. 42d St., New York, NY 10017. 

8434 Rochester Ave., Cucamonga, CA 91730. 



APPENDIX A 



T'iBLE 1. --Synthetic organic CHEf^icALs; Alphabetical directory of manufacturers, 

BY COMPANY, 197?— CONTINUED 




Office address 



Industrial Dyestuff Co 

Inland Steel Co. , Inland Steel Container 

Co. 
Inmont Corp 

ABI Div 

International Flavors § Fragrances, Inc-- 
Intemational Minerals § Chemical Corp — 

Interplastic Corp '■ 

lonac Chemical Co. Div. of Sybron Corp — 
Ironsides Resins, Inc 

Jefferson Chemical Co., Inc 

Jenni son- Wright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

Jewel Paint S Varnish Co 1 

S. C. Johnson 5 Son, Inc 

Jones -Blair Co 

Jordan Chemical Co 

Kaiser Aluminum 6 Chemical Corp. : 

Kaiser Agricultural Chemicals Div 

Kaiser Chemical 

Kalama Chemical Co 

Kali Manufacturing Co 

Kay-Fries Chemicals, Inc 

Kelly-Moore Paint Co 

Kennecott Copper Corp.: 

Chino Mines Div 

Utah Copper Div 

Kerr-McGee Chemical Corp 

Keysor Century Corp 

Keystone Chemurgic Corp 

Keystone Color Works, Inc 

Knapp Products, Inc 

Koch Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstamm G Co., Inc 

Koppers Co., Inc 

Organic Material Div 

Roads Materials Div 

Krafto Corp. : 

Humko Products Div 

Sheffield Chemicals Div 

Kyanize Paints, Inc 

Lakeside Laboratories Div. of Colgate- 
Palmolive Co. 
Lake States Div. of St. Regis Paper Co--- 

Lakeway Chemicals Inc 

LaMotte Chemical Products Co 

Laurel Products Corp 

Leatex Chemical Co 

Lemke Chemicals, Inc 

Lever Brothers Co 

C. Lever Co., Inc 

Eli Lilly 5 Co 

Lonza, Inc 

Lubrizol Corp 

M and T Chemicals, Inc 

Magnolis Industries, Inc., Milliken 
Chemical Div. 



P. 0. Box 4249, E. Providence, RI 02914. 
4300 W. 130th St., Chicago, IL 60658. 

609 Lafayette Ave., Hawthorne, NJ 07506. 

5935 Milford Ave., Detroit, MI 48210. 

521 W. 57th St., New York, NY 10019. 

IMC Plaza, Libertyville, IL 60948. 

2015 NE. Broadway St., Minneapolis, MN 55413. 

Birmingham, NJ 08011. 

270 W. Mound St., Columbus, OH 43216. 

P. 0. Box 53300, Houston, TX 77052. 

P. 0. Box 691, Toledo, OH 43694. 

2535 Spring Grove Ave., Cincinnati, OH 45214. 

59 Lee Ave., Haledon, NJ 07508. 

345 N. Western Ave., Chicago, IL 60612. 

1525 Howe St., Racine, WI 53403. 

2728 Proctor, Dallas, TX 75235. 

1830 Columbia Ave., Folcraft, PA 19032. 

P. 0. Box 246, Savannah, GA 31402. 

P. 0. Box 337, Gramercy, LA 70052. 

P. 0. Box 427, Kalama, WA 98625. 

427 Moyer St., Philadelphia, PA 19125. 

360 Lexington Ave., New York, NY 10017. 

1015 Commercial St., San Carlos, CA 94070. 

Hurley, MN 88043. 

P. 0. Box 11299, Salt Lake City, UT 84111. 

P. 0. Box 25861, Oklahoma, OK 73125. 

P. 0. Box 308, Saugus, CA 91350. 

R. D. 2, Bethlehem, PA 18017. 

151 W. Gay Ave., York, PA 17403. 

187 Garibaldi Ave., Lodi , NJ 07644. 

P. 0. Box 2256, Wichita, KS 67201. 

1201 Osage St., Denver, CO 80201. 

161 Avenue of the Americas, New York, NY 10013. 

Koppers Bldg., Pittsburgh, PA 15219. 

Koppers Bldg., Pittsburgh, PA 15219. 

Koppers Bldg., Pittsburgh, PA 15219. 

P. 0. Box 398, Memphis, TN 38101. 

2400 Morris Ave., Union. NJ 07083. 

2d and Boston Sts . , Everett, MA 02149. 

1707 E. North Ave., Milwaukee, WI 53201. 

603 W. Davenport St., Rhinelander, WI 54501. 

S025 Evanston Ave., Muskegon, MI 49443. 

Chestertown, MD 21620. 

2600 E. Tioga St., Philadelphia, PA 19134. 

2722 N. Hancock St., Philadelphia, PA 19133. 

195-203 Main St., Lodi, NJ 07644. 

390 Park Ave., New York, NY 10022. 

736 Dunks Ferry Rd., Comwells Hgts, PA 19020. 

307 E. McCarty St., Indianapolis, IN 46206 and G.P.O. 

Box 4388, San Juan, PR 00936. 
22-10 Route 208, Fair Lawn, NJ 07410. 
29400 Lakeland Blvd., Wickliffe, OH 44092. 

Woodridge Rd. f, Randolph Ave., P. 0. Box 1104, 

Rahway, NJ 07065. 
P. 0. Box 817, Inman, SC 29349. 



SYNTHETIC ORGANIC CHEMICALS, 1P7? 



TABLE 1. --Synthetic organic chemicals; Alphabetical directory of manufacturers, 

BY COMPANY, 197?— CONTINUED 



Name of company 



Office address 



Magruder Color Co., Inc 

Mallinckrodt Chemical Works 

Washlne Div 

Marathon Horco Co 

Marathon Oil Co., Texas Refining Div 

Marblette Co 

Harden- Wi Id Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp.: 

Sodyeco Div 

Max Marx Color 5 Chemical Co 

Masonite Corp., Alpine Chemical Div 

Otto B. May, Inc 

McCloskey Varnish Co 

McLaughlin normley King Co 

Mead Johnson 6 Co 

Merck 5 Co., Inc 

Merichem Co 

Michigan Chemical Corp 

Midwest Manufacturing Corp 

Miles Laboratories, Inc., Marschall Div 

Millmaster Onyx Corp.: 

A. Gross 6 Co. Div 

Millmaster Chemical Div. , Berkely 
Chemical Dept. 

Onyx Chemical Co. Div 

Refined- Onyx Div 

Minnesota Mining 5 Manufacturing Co 

Minnesota Paints, Inc 

Miranol Chemical Co., Inc 

Mississippi Chemical Corp 

Mobay Giemical Co 

Mobil nil Com 

Mobil Chemical Co.: 

Chemical Coatings Div 

Industrial Chemicals Div 

Mona Industries, Inc 

Monochem, Inc 

Monroe Chemical Co 

Monsanto Co 

Bircham Bend Plant 

Chocolate Bayou Plant 

Plastics Div 

Textiles Div 

Montrose Chemical Corp. of California 

Mooney Chemicals, Inc 

Moretex Chemical Products, Inc 

Morton Chemical Co. Div. of Morton-Norwich 
Products, Inc. 

Motomco, Inc 

Murphy- Ph oenix Co 

NL Industries, Inc 

Nalco Chemical Co 

National Biochemical Co 

National Casein Co 

National Distillers 5 Chemical Corp., U.S. 
Industrial Chemicals Co. Div. 



1 Virginia St., Newark, NJ 07114. 

3600 N. 2d St., St. Louis, MO 6?>147. 

165 Main St., Lodi , NJ 07644. 

P. 0. Drawer C, Dickinson, TX 77539. 

P. 0. Box 1191, Texas City, TX 77590. 

37-31 30th St., Long Island City, NY 11101. 

500 Columbia St., Somerville, MA 02143. 

1511 Joshua Circle, High Point, NC 27261. 



P. 0. Box 10098 

192 Coit St. , I: 

P. 0. Box 2392, 

52 Amsterdam St 

7600 State Rd. , 

1715 SE. 5th St 

2404 Penna. St. 

126 E. Lincoln Ave., Railway 

1914 Haden Rd. , Houston, TX 



Charlotte, NC 28201. 
vington, NJ 07111. 
Gulfport, MS 39503. 
, Newark, NJ 07105. 
Philadelphia, PA 19136. 
, Minneapolis, MN 55414. 
Evansville, IN 47721. 
NJ 07065 . 
77015. 



351 E. Ohio St., Chicago, XL 60611. 

Oak St. and Bluff Rd. , Burlington, lA 52601. 

1127 Myrtle St., Elkhart, IN 46514. 

652 Doremus Ave., Newark, NJ 07105. 
99 Park Ave., New York, NY 10016. 

190 Warren St., Jersey City, NJ 07302. 

624 Schuyler Ave., Lyndliurst, NJ 07071. 

3M Center, St. Paul, MN 55101. 

1101 S. 3d St., Minneapolis, MN 55415. 

277 Coit St., Irvington, NJ 07111. 

P. 0. Box 388, Yazoo City, MS 39194. 

Penn Lincoln Parkway, W. Pittsburgh, PA 15205. 

P. 0. Box 900, Dallas, TX 75221. 

1024 South Ave., Plainfield, NJ 07062. 

P. 0. Box 26683, Richmond, VA 23261. 

65 E. 23d St., Paterson, NJ 07524. 

P. 0. Box 488, Geismar, LA 70734. 

Saville Ave. at 4th St., Eddystone, PA 19013. 

2710 Lafayette St., Santa Clara, CA 95052 and 

Lindbergh Blvd., St. Louis, MO 63166. 
190 Grochraal Ave., Indian Orchard, MA 01051. 
P. 0. Box 711, Alvin, TX 77511. 
730 Worcester St., Indian Orchard, MA 01101; 

5100 W. Jefferson Ave., Trenton, MI 48183; 

River Rd., Addyston, OH 45001 and P. 0. Box 

Texas City, TX 77591. 
800 N. Lindbergh Blvd., St. Louis, MO 63156. 
500 S. Virgil Ave,, Los Agneles, CA 90005. 
2301 Scranton Rd. , Cleveland, OH 44113. 
314 W. Henry St., P. 0. 1799, Spartanbury, SC 

110 N. Wacker Dr., Chicago, XL 60606. 

89 Terminal Ave., Clark, NJ 07066. 
9505 Cassius Ave., Cleveland, OH 44105. 

111 Broadway, New York, NY 10006. 

180 N. Michigan Ave., Chicago, IL 60601. 
3127 W. Lake St., Chicago, IL 60612. 
601 W. 80th St., Chicago, IL 60620. 
99 Park Ave., New York, NY 10016. 



APPEmiX A 



TABLE 1.— Synthetic organic chemicals; Alphabetical directory of manufacturers. 
BY company. 1972--Continued 



Name of company 



Office address 



National Hilling § Chemical Co 

National Petro Chemical Corp 

National Starch 6 Chemical Corp 

Nease Chemical Co., Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Nilok Chemicals, Inc 

Ninak, Inc 

Nipro, Inc 

Norac Co. , Inc 

Mathe Chemical Co. Div 

Norda, Inc 

Norris Paint 5 Varnish Co 

North American Chemical Co 

North American Rockwell Corp 

Northern Fine Chemicals, Inc 

Northern Petrochemical Co 

Northwestern Chemical Co 

Northwest Petrochemical Corp 

Norwich Pharmacal Co 

Nostrip Chemical Works, Inc 

Noury Chemical Corp 

Novamont Corp., Neal Works 

Nyanza, Inc 

' Bri en Corp 

Occidental Chemical Co 

01 in Corp 

Agricultural Chemicals Div 

Orbis Products Corp 

Organics , Inc 

Original Bradford Soap Works, Inc 

Owens-Coming Fiberglas Corp 

Oxirane Chemical Co 

Oxochem Enterpri se 

P-L Biochemicals, Inc 

PPG Industries, Inc 

PVO International, Inc., Chemical 

Specialties Div. 

Pace National Corp 

Pacific Resins 5 Chemicals, Inc 

Pantasote Co. of New York, Inc 

Parke Davis § Co 

Passaic Color f, Chemical Co 

C. H. Patrick 5 Co., Inc 

Pears all Corp 

Peck's Products Co 

Peerless Oiemical Co 

Pellon Corp., Disogrin Industries Div- 

Pelron Corp 

Pennsylvania Industrial Chemical Corp- 

Pennsylvania Refining Co 

Pennwalt Corp 

Lucidol Div -- 

Perry 5 Derrick Co., Inc 

Petrochemical Investment Corp 

Petrochemicals Co., Inc 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Inc 

Pfister Chemical, Inc 

Pfizer, Inc 



4601 Flat Rock Rd. , Philadelphia, PA 19127. 

99 Park Ave., New York, NY 10016. 

750 3d Ave., New York, NY 10017. 

P. 0. Box 221, State College, PA 16801. 

Route 32, Harriman, NY 10926. 

Neville Island, P. 0., Pittsburgh, PA 15225. 

2235 Langdon Farm Rd., Cincinnati, OH 45230. 

301 S. Harwood St., Dallas, TX 75221. 

P. 0. Box 1483, Augusta, GA 30903. 

405 S. Motor Ave., Azusa, CA 91703. 

169 Kennedy Dr., Lodi , NJ 07644. 

475 inth Ave., New York, NY 10001. 

P. 0. Box 2023, Salem, OR 97308. 

19 Chestnut St., Cambridge, MA 02139. 

4501 Benefit Ave., Ashtabula, OH 44004. 

93 Main St., Franklin, NJ 07416. 

2.350 E. Devon Ave., Des Plaines, IL 60018. 

120 N. Aurora St., W. Chicago, IL 60185. 

P. 0. Box 99, Anacortes, WA 98221. 

17 Eaton Ave., Norwich, NY 13815. 

P. 0. Box 160, Pedrichtown, NJ 08067. 

2153 Lockport-Olcott Rd. , Burt, NY 14028. 

P. 0. Box 189, Kenova, WV 25530. 

Maguno Rd. , Ashland, MA 01721. 

2001 W. Washington Ave., South Bend, IN 46627. 

P. 0. Box 198, Lathrop, CA 95330. 

120 Long Ridge Rd., Stamford, CT 06904. 

1120 Marshall St., P. 0. Box 991, Little Rock, AR 72203 

475 10th Ave., New York, NY 10008. 

7125 N. Clark St., Chicago, IL 60628. 

200 Providence St., W. Wartdck, RI 02893. 

Fiberglas Tower, Toledo, OH 43659. 

10801 Choate Rd., Houston, TX 77062. 

P. 0. Box 27, King George Post Rd., Fords, NJ 08863. 

1037 W. McKinley Ave., Milwaukee, WI 53205. 
1 Gateway Center, Pittsburgh, PA 15222. 
416 Division St., Boonton, NJ 07005. 

500 7th Ave., S., Kirland, WA 98033. 

1754 Thome Rd., Tacoma, WA 93421. 

26 Jefferson St., Passaic, NJ 07055. 

Jos. Carapau at the River, Detroit, MI 48232. 

28-36 Paterson St., Paterson, NJ 07501. 

P. 0. Box 2526, Greensville, SC 29602. 

P. 0. Box 437, Houston, TX 77025. 

610 E. Clarence Ave., St. Louis, MO 63147. 

12416 Cloverdale Ave., Detroit, MI 48204. 

Perimeter Rd., Municipal Airport, Manchaster, NH 07103. 

7847 W. 47th St., Lyons, IL 60534. 

120 State St., Clairton, PA 15025. 

Union Bank Bldg. , Butler, PA 16001. 

Three Penn Center, Philadelphia, PA 19102. 

1740 Militar\' Rd., Buffalo, NY 14240. 

2510 Highland Ave., Norh'ood, OH 45212. 

P. 0. Drawer F, Channelview, TX 77530. 

P. 0. Box 2199, Fort Worth, TX 76101. 

P. n. Box 25 84, Houston, TX 77001. 

1219 Glen Rock Ave., Waukegan, IL 60085. 

Linden Ave., Ridgefield, NJ 07657. 

235 E. 42d St., New York, NY 10017. 



SYNTHETIC 0PG/\NIC CHEi'iICALS. 1°72 



TABLE 1.— Synthi^tic organic chemicals: Alphabetical directory of manufacturers, 

BY company. 1972--CONTINUED 




Pharmachem Corp 

Phillips Petroleum Co 

Phillips Puerto Rico Core, Inc 

Pierce Chemical Co 

Pilot Chemical Co 

Pioneer Plastics Corp 

Pitt-Consol Chemical Co 

Plastics Engineering Co 

Plastics Manufacturing Co 

Plex Chemical Corp 

Polak's Frutal Works, Inc 

Polymer Corp 

Polymer Industries, Inc 

Polyrez Co., Inc 

Polyvinyl Chemical Ind. Div. of 

Beatrice Foods Co. 

Pratt 5 Lambert, Inc 

Premier Malt Products, Inc 

Premier Petrochemicl Co 

Princeton Chemical Research, Inc 

Proctor 5 Gamble Co., Proctor fi Gamble 

Mfg. Co. 
Products Research 5 Chemical Corp., 

Chemical S Sealants Div. 

Proctor Chemical Co., Inc 

Productol Chemical Co., Inc 

Publicker Industries, Inc 

Puerto Rico Chemical Co., Inc 

Puerto Rico Olefins 

Purex Corp., Ltd 

Washburn- Lans on Co. Div 



Office address 



Quaker Oats Co 
K. J. Quinn 5 Co 



719 Stefko Blvd., Bethlehem, PA 18018. 
7472 Frank Phillips Bldg., Bartlesville, 
GPn Box 4129, San Juan, PR 00936. 
P. 0. Box 117, Rockford, IL 61105. 
11756 Burke St., Santa Fe Springs, CA 906 
Pionite Rd. , Auburn, HE 04210. 
Park Eighty Plaza East, Saddle Brook, NJ 
1607 Geele Ave., Sheboygan, WI 53081. 
2700 S. Westmoreland Ave., Dallas, TX 752 
1205 Atlantic St., Union City, CA 94487. 
33 Sprague Ave., Hiddletown, NY 10940. 
2120 Fairmont Ave., Reading, PA 19603. 
Viaduct Rd., Springdale, CT 06879. 
S. Columbia St., Woodbury, NJ 08096. 
730 Main St., Wilmington, HA 01887. 

P. n. Box 22, Buffalo, NY 14240. 

917 W. Juneau Ave., Milwaukee, WI 53201. 

530 N. Witter, Pasadena, TX 77501. 

P. 0. Box 651, Princeton, NJ 08540. 

301 E. 6th St., Cincinnati, OH 45202. 

2912 Empire Ave., Burbank, CA 91504. 

P. 0. Box 399, Salisbury, NC 28144. 
13215 E. Penn St., IVhittier, CA 90602. 
1429 Walnut St., Philadelphia, PA 19102. 
P. 0. Box 496, Arecibo, PR 00613. 
Firm Delivery, Ponce, PR 00731. 
5101 Clark Ave., Lakewood, CA 90712. 
2258 Elston Ave., Chicago, IL 60614. 



Quaker Chemical Corp Lime 5 Elm Sts . , Conshohocken, PA 19428. 

345 Merchandise Mart Plaza, Chicago, IL 60654. 
195 Canal St., Maiden, MA 02148. 



Inc- 



Inc- 



R.S.A. Corp 

Rachel le Laboratories, 

Racon, Inc 

Raybestos-Manhattan, Inc., Raybestos Div- 

Red Spot Paint 5 Varnish Co., Inc 

Reheis Chemical Co. Div. of Armour 
Pharmaceutical Co. 

Reichhold Chemicals, Inc 

Reilly Tar § Chemical Corp 



Reliance Universal, 

Resin Div 

Remington Arms Co., 

Resyn Co3rp 

Rhodia, Inc 

Richardson Co 



Inc. of Texas- 



Ridgway Color 5 Chemical- 
Riker Laboratories, Inc., 

Rilsan Corp 

F. Ritter 5 Co 

Riverdale Chemical Co 

Robeco Chemicals, Inc 

Roehr Chemicals, Inc 

Rogers Corp 

Rohm 5 Haas Co 



Sub. of 3M Co- 



690 Sawmill River Rd. , Ardsley, NY 10502. 

700 Henry Ford Ave., Long Beach, CA 90801. 

P. 0. Box 198, 6040 S. Ridge Rd. , Witchita, KS 67201. 

74 E. Main St., Stratford, CT 06497. 

966 E. Columbia St., Evansville, IN 47708. 
325 Snyder Ave., Berkeley Heights, NJ 07922. 

525 N. Broadway, White Plains, NY 10602. 

1615 Merchants Bank, 11 S. Meridan St. Indianapolis, 

IN 46204. 
6901 Cavalcade St., Houston, TX 77001. 
4730 Crittenden Dr., Louisville, KY 40221. 
939 Bamum Ave., Bridgeport, CT 06602. 
1401 W. Blancke St., Linden, NJ 07036. 
120 Jersey Ave., New Brunswick, NJ 08903. 
2708 Lake St., Melrose Park, IL 60160 and 345 Morgan 

Lane, West Haven, CT 06516. 

75 Front St., Ridgway, PA 15853. 

19901 Nordhoff St., Northridge, CA 91324. 

139 Harristown Rd. , Glen Roc, NJ 07452. 

4001 Goodwin Ave., Los Angeles, CA 90039. 

220 E. 17th St., Chicago Heights, IL 60411. 

51 Madison Ave., New York, NY 10010. 

52-20 37th St., Long Island City, NY 11101. 

Main St., Rogers, CT 06263. 

Independence Mall West, Philadelphia, PA 19105. 



rtPf'ENDIX A 



TABLE 1. —Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY, .T^Z?— CONTINUED 



Name of company 



Office address 



Rubicon Chemicals, Inc 

SCM Corp., Glidden-Durkee Div 

Safeway Stores, Inc 

Salem Oil 5 Grease Co 

Salsbury Laboratories 

Sandoz, Inc., Sandoz Color 5 Chemical Di\ 

Sartomer Industries, Inc 

Schenectady Chemicals, Inc 

Scher Bros., Inc 

R. P. Scherer Com 

Schering Corp 

Scholler Bros., Inc 

Scientific Protein Labs., Inc 

Scott Paper Co 

Seaboard Chemicals, Inc 

G. D. Searle 5 Co 

Seydel-Woolley § Co., Inc 

Shakespeake Co. , Industrial Products Div- 

Shanco Plastics 5 Chemicals, Inc 

Shell 5 Commonwealth Chemicals, Inc 

Shell nil Co 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Sherwin-Williams Co 

George F. Siddall Co., Inc 

Simpson Timber Co 

Sinclair- Koppers Co 

Sinclair- Koppers Chemical Co 

Sinclair Paint Co., Div. of Insilco Corp- 

Sipers Chemical Coatings Co 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline 5 French Laboratories 

Sobin Chemicals, Inc., Montrose Chemical 

Div. 

Solar Chemical Corp 

Soluol Chemical Co., Inc 

Solvent Chemical Co., Inc 

Sou-Tex Chemical Co., Inc 

Southeastern Adhesives 

Southern Chemical Products Co 

Southern Sizing Co 

Spaulding Fibre Co., Inc 

E. R. Squibb 6 Sons, Inc 

A. E. Staley Manufacturing Co 

Staley Chemicals Div 

Textile Div 

Stamford Chemical Industries 

Standard Brands, Inc., Clinton Com 

Processing Co. Div. 
Standard Brands Chemical Industries, Inc- 

Standard Chlorine of Delaware, Inc 

Standard Oil Co. of California, Chevron 

Chemical Co. 

Standard Oil Co. of Ohio 

Stange Co 



P. 0. Box 517, Geismar, LA 70734. 

900 Union Commerce Bldg. , Cleveland, OH 44115. 

8390 Capwell Dr., Oakland, CA 94604. 

60 Grove St., Salem, MA 01970. 

2000 Rockford Rd. , Charles City, lA S0616. 

P. 0. Box 357, Fair Lawn, NJ 07410 and Route No. 10, 

P. 0. Box 11, E. Hanover, NJ 07936. 
P. 0. Box 56, Essington, PA 19029. 
P. 0. Box 1046, Schenectady, NY 12301. 
P. 0. Box 538, Allwood Station, Clifton, NJ 07012. 
9425 Grinnell Ave., Detroit, MI 48213. 
1011 Morris Ave., Union, NJ 07083. 

Collins and Westmoreland Sts . , Philadelphia, PA 1913 
P. 0. Box 1409, Madison, WI 53701. 
Oconto Falls, WI 54154. 
30 Foster St., Salem, MA 01970. 
P. 0. Box 5110, Chicago, IL 60680. 
762 Marietta Blvd., NW., Atlanta, GA 30318. 
P. 0. Box 246, Columbia, SC 29202. 
Ill Wales St., Tonawanda, NY 14150. 
Petrochemical Complex, Ponce, PR 00731. 
P. 0. Box 2463, Houston, TX 77001. 

One Shell Plaza, P. 0. Box 2463, Houston, TX 77001. 
4900 Beech St., Cincinnati, OH 45212. 
101 Prospect Ave., NW Cleveland, OH 44101. 
P. 0. Box 925, Spartanburg, SC 29301. 
2301 N. Columbia Blvd., Portland, OR 97217. 
900 Koppers Bldg., Pittsburgh, PA 15219. 
9822 La Porte Freeway, Houston, TX 77012. 
3960 E. Washington Blvd., Los Angeles, CA 90023. 
P. 0. Box 13090, Pittsburgh, PA 15243. 
P. 0. Box 1650, Tulsa, OK 74102. 
867 McKinley Ave., Columbus, OH 43223. 
1500 Spring Garden St., Philadelphia, PA 19101. 
100 Listen Ave., Newark, NJ 07105. 

P. 0. Box 90, Leominster, MA 01453. 

Green Hill and Market Sts., W. Warwick, RI 02893. 

335-341 Commercial St., Maiden, MA 02148. 

E. Cataivba Ave., Mount Holly, NC 28120. 

P. 0. Box 791, Lenoir, NC 28645. 

P. 0. Box 205, Macon, GA 31202. 

P. 0. Box 90987, East Point, GA 30344. 

310 Wheeler St., Tonawanda, NY 14150. 

Georges Rd., Brunswick, NJ 08903. 

2200 Elorado St., Decatur, IL 62525. 

320 Schu>'ler Ave., Kearny, NJ 07032. 

6301 St. John Lane, Charlotte, NC 28210. 

4300 Carew Towers, Cincinnatti , OH 45202. 

1251 Beaver Channel Parkway, Clinton, lA 52733. 

P. 0. Drawer K, Dover, DE 19901. 

1035 Belleville Turnpike, Kearny, NJ 07032. 

200 Bush St., San Francisco, CA 94120. 

Midland Bldg., Cleveland, OH 44115. 
342 N. Western Ave., Chicago, IL 60612. 



552-743 0-74-17 



SYNTHETIC nRG'\NIC CHE^IICALS, 1972- 



TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers 
BY company. 1972— Continued 



Name of company 



Stauffer Chemical Co.: 

Agricultural Div 

Calhio Chemicals, Inc. Div 

Industrial Div 

Plastics Div 

Specialty Chemical Div 

Specialty Chemical Div. , Benzol 

Products. 
SWS Silicones Div 

Stepan Chemical Co 

National Polycheraicals Div 

Sterling Drug, Inc. : 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Thomasset Colors Div 

Winthrop Laboratories Div-"- 

Sterwin Chemicals, Inc 

Story Chemical Corp., Ott Div 

Styrochem Corp 

Sugar Beet Products Co 

Sun Chemical Corp 

Sunkist Growers, Inc 

Sun Oil Co 

Sun Olin Chemicl Co 

Suntide Refining Co 

Tanatex Chemical Corp 

Charles S. Tanner Co 

Teknor Apex Co 

Tenneco Chemicals, Inc 

Cal/Ink Div 

Tenneco Oil Co 

Terra Chemicals International, Inc 

Texaco, Inc 

Texas Alkyls, Inc 

Texas-U.S. Chemical Co 

Tex Chem Co., Inc 

Texize Chemicals, Inc 

Text il ana Corp 

Textllana Nease, Inc 

Textron, Inc., Spencer Kellogg Div 

Thiokol Chemical Corp 

Thomason Industries, Inc., Southern Resin 

Div. 
Thompson-Hayward Chemical Co 

Tizon Chemical Corp 

Toms River Chemical Corp 

Trade Enterprises, Inc 

Arthur C. Trask Co 



Office address 



636 California St. 

636 California St. 

636 California St. 

636 California St., San Francisco 

636 California St., San Francisco 

Meadow Rd., Edison 



San Francisco, CA 
San Francisco, CA 
San Francisco, CA 



08817. 



94119 
94119 
94119 
94119 
94119 



636 California St., San Francisco, CA 94119. 

RR #1, Elwood, IL 60421 and 100 West Hunter Ave., 

Maywood, NJ 07607. 
51 Eames St., Wilmington, MA 01887. 

90 Park Ave., New York, NY 10016. 

2233 Langdon Farm Rd. , Cincinnati, OH 45237. 

120 Lister Ave., Newark, NJ 07105. 

90 Park Ave., New York, NY 10016. 

Military Rd. , Rothschild, WI 54474. 

500 Agard Rd., Muskegon, MI 49945. 

Petrochemical Complex, Ponce, PR 00731. 

P. 0. Box 1387, Saginaw, MI 48605. 

441 Tompkins Ave., Staten Island, NY 10305 and 

P. 0. Box 70, Chester, SC 29706. 
P. 0. Box 7888, Valley Annex, Van Nuys , CA 91409. 
240 Radnor-Chester Rd. , St. Davids, PA 19087. 
P. 0. Box F, Claymount, DE 19703. 
P. 0. Box 2608, Corpus Christi , TX 78403. 

P. 0. Box 388, Lyndhurst, NJ 07071. 

1305 Barcelona Dr., Donaldson Center, Greensville, SC 

29606. 
505 Central Ave., Pawtucket, RI 02662. 
Park Eighty Plaza West-One, Saddle Brook, NJ 07662. 
711 Camelia St., Berkeley, CA 94710. 
P. 0. Box 2511, Houston, TX 77001. 
507 6th St., Sioux City, lA 51121. 
135 E. 42d St., New York, NY 10017. 
P. 0. Box 600, Deer Park, TX 77536. 
P. 0. Box 667, Port Neches, TX 77651. 
20-21 IVagaraw Rd. , Fair Lawn, NJ 07410. 
P. 0. Box 368, Greenville, SC 29602. 
12607 Cerise Ave., Hawthorne, CA 90250. 
12607 Cerise Ave., Hawthorne, CA 90250. 
120 Delaware Ave., Buffalo, NY 14240. 
P. 0. Box 27, Bristol, PA 19007. 
P. 0. Drawer 1600, Fayetteville. NC 29302. 

5200 Speaker Rd. , Kansas City, MO 66110 and 

2 E. Madison St., Waukegan, IL 60085. 
Locktown Rd., Flemington, NJ 08822. 
P. 0. Box 71, Toms River, NJ 08753. 

Ketometer 77.5, P. 0. Box 296, Humacao, 



State Road 3, 

PR 00661. 
P. 0. Box 134 



Argo, IL 60501. 



APPEmiX A 



TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers^ 
BY company, 1972--CoNTinuED 



Name of company 



Office address 



Triad Chemical 

Troy Chemical Co 

Joseph Turner S Co 

USS Agri- Chemicals Div of U.S. Steel Corp- 

USS Chemicals Div. of U.S. Steel Corp 

Paul Hulich 6 Co., Inc 

Ungerer S Co 

Union-Camp Corp 

Harchem Div 

Union Carbide Corp 

Union Oil Co. of California 

Uniroyal, Inc., Chemical Div 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United- Erie, Inc 

United Merchants 5 Manufacturers, Inc., 

Roma Chemical Div. 

U.S. Borax Research Corp 

U.S. Industries, Inc., E. Helman Co. Div-- 

U.S. Oil Co 

U.S. Pipe § Foundry Co 

U.S. Plywood WCM Operations, Shasta Area-- 

Universal Chemicals Corp 

Universal Oil Products Co 

UOP Chemical Div 

Upjohn Co 

Fine Chemical Div 

Valchem Chemical Div. of United Merchants 

§ Manufacturers, Inc. 

Valentine Sugars, Inc 

Valley Nitrogen Producers, Inc 

Van De Mark Chemical Co., Inc 

Vanderbilt Chemical Corp 

Van Dyk 5 Co., Inc 

Velsicol Chemical Corp 

Ventron Corp 

Wood Ridge Chemical 

Vermilye-Bell 

Vineland Chemical Co 

Virginia Chemicals, Inc 

Vistron Corp 

Silraar Div 

Vitamins , Inc 

Vulcan Materials Co., Chemicals Div 

Wamer-Jenkinson Manufacturing Co 

West Agro-Chemicals, Inc 

West Coast Adhesives Co 

Westinghouse Electric Corp., Industrial 
Plastics Div., Chemical Products Plant. 

Westvaco Corp., Polychemicals Dept 

Weyerhaeuser Co 

White 8 Bagley Co 



P. 0. Box 310, Donaldsonville, LA 70346. 

One Avenue L, Newark, NJ 07105. 

P. 0. Box 88, Ridgefield, NJ 07657. 

30 Pryor St. S.W. Atlanta, GA 30301. 

600 Grant St., Rm. 2880, Pittsburgh, PA 1S219. 

90 West St., New York, NY 10006. 

161 Avenue of the Americas, New York, NY 10013. 

P. 0. Box 6170, Jacksonville, Fl 32205. 

P. 0. Box 220, Dover, NJ 44622. 

270 Park Ave., New York, NY 10017. 

P. 0. Box 7600, Los Angeles, CA 90051. 

Emic Bldg., Naugatuck, CT 06770. 

P. n. Box 367, Endicott St., Norwood, MA 02062. 

York and Colgate Sts., Jersey City, NJ 07302. 

438 Huron SE., Erie, PA 16512. 

749 Quequechan St., Fall River, MA 02721. 

3075 Wilshire Blvd., Los Angeles, CA 90005. 

P. 0. Box 5129, Akron, OH 44313. 

P. 0. Box 4228, E. Providence, RI 02914. 

3300 1st Ave., N. , Birmingham, AL 35202. 

P. 0. Box 2713, Redding, CA 96001. 

1224 Mendon Rd. , Ashton, RI 02864. 

70 UOP Plaza, Algonquin 8 Mt . Prospect, 

Des Plains, IL 60018. 
State Highway 17, E. Rutherford, NJ 07073. 
7000 Portage Rd. , Kalamazoo, MI 49001. 
410 Sackett Point Rd., North Haven, CT 06473. 

1407 Broadway, New York, NY 10018. 

726 IVhitney Bldg., New Orleans, LA 70130. 

1221 Van Ness Ave., Fresno, CA 93721. 

N. Transit Rd. , Lockport , NY 14094. 

33 Taylor Ave., Bethel, CT 06801. 

Main 5 Williams Sts., Belleville, NJ 07109. 

341 E. Ohio St., Chicago, IL 60611. 

12-16 Congress St. Beverly, MA 01915. 

Park Place East, Wood Ridge, NJ 07075. 

21707 Bothell Way, Bothell, WA 98011. 

W. tVheat Rd. , Vineland, NJ 08360. 

3340 W. Norfolk Rd., Portsmouth, VA 23703. 

Midland Bldg., Cleveland, OH 44115. 

12333 S. Van Ness Ave., Hawthorne, CA 90250. 

401 N. Michigan Ave., Suite 2730, Chicago, IL 60611. 

P. 0. Box 545, Wichita, KS 67201. 

2526 Baldwin St., St. Louis, MO 63106. 
501 Santa Fe, Kansas City, HO 64105. 
11104 NW. Front .Ave., Portland, OR 97231. 
Manor, PA 15665. 

P. 0. Box 5207, N. Charleston, SC 29406. 
118 S. Palmetto Ave., Marshfield, WI 54449. 
P. 0. Box 706. Worcester, MA 01613. 



SYNTHETIC ORGANIC CHEMICALS. 1972 



TABLE 1,--Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY, 1972--CoNTINUED 



Identi- 
fication 
code 


Name o£ company 


Office address 


IVHI 
l«HL 

APT 
IfflC 
IWW 
WIG 
WLN 

WIL 

WM 

WTC 

WAW 

WON 

WBC 

WCL 

mc 
\m 

YAW 


White 6 Hodges, Inc 


576 Lawrence St., Lowell, MA 01852. 

19 N. Railroad St., Myerstovm, PA 17067. 

3134 California St., NE., Minneapolis, MN 55426. 
3540 Aero Ct., San Diego, CA 92123. 
62 Alford St., Boston, MA 02129. 
P. 0. Box 506, Charlotte, NC 28201. 
P. 0. Box 66, Wilmington, DE 19 899. 

4221 S. Western Blvd., Chicago, IL 60609. 

Jackson and Swanson Sts., Philadelphia, PA 19148. 

P. 0. Box 305, Paramus, NJ 07652. 

108 Spring St., Everett, MA. 02149. 

176 Sunnyside Ave., Woonsocket, RI 02895. 

Halls Mills Rd., Freehold, NJ 07728. 

Acme Station, Riegelwood, NC 28456. 

P. 0. Box 1087, Colorado Springs, CO 80901. 

P. 0. Box 8299, Paoli, PA 19101. 

2731 Boston St., Baltimore, MD 21224. 


Iftiittaker Corp. : 

Mol Rez Div 




Wica Chemicals, Inc 


Wilson Pharmaceutical f, Chemical Corp.: 
Wilson Laboratories Div 


Witco Chemical Co., Inc 

W. A. Wood Co 

Woonsocket Color 5 Chemical Co 


Wright Chemical Co 

Wycon Chemical Co 

Wyeth Laboratories, Inc., Wyeth Laboratories 
Div. of American Home Products Corp. 

J. S. Young Co., Young Aniline Works Div 



257 



APPENDIX B 



U.S. IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS 

U.S. general imports of benzenoid chemicals and products entered under 
the Tariff Schedules of the United States (TSUS) , schedule 4, part 1, subparts 
B and C are analyzed by the Tariff Commission annually and published in detail 
in a separate report.^ General imports of benzenoid items entered in parts 
IB and IC totaled 322.0 million pounds with a foreign invoice value of $246.7 
million in 1972 compared with 219.5 million pounds with a foreign invoice 
value of $185.0 million in 1971. 

Benzenoid products that are "competitive" with similar domestic products, 
because they accomplish results substantially equal to those accomplished by 
the similar domestic product when used in substantially the same manner, are 
subject to a special basis of valuation for customs purposes known as the 
"American selling price." If "noncompetitive," the benzenoid products are 
valued for customs purposes on the basis of the "United States value." The 
essential difference between these two values is that "American selling price" 
is based on the wholesale price in the United States of the "competitive" 
domestic product, whereas "United States value" is based on the wholesale price 
in the United States of the imported product less most of the expenses incurred 
in bringing the product to the United States and selling it. When neither of 
these two valuation bases applies, then the "export value," "foreign value," or 
"constructed value" is used as the valuation basis under section 402 or 402a 
Tariff Act of 1930, as amended. The competitive status of benzenoid imports in 
1972 is shown in table 2. 

Industrial organic chemicals that are entered under part IB consist chiefly 
of benzenoid intermediates and small quantities of acyclic compounds which are 
derived in whole or in part from benzenoid compounds. Also included are mixtures 
and small quantities of finished products not specially provided for in part IC 
(e.g., rubber-processing chemicals). In terms of value, 45.0 percent of all the 
benzenoid imports under part IB in 1972 came from West Germany; 21.2 percent, 
from Japan; 9.6 percent, from Switzerland; and 6.6 percent from Italy. 

Finished organic chemical products entered under part IC include dyes, 
pigments, medicinals, flavor and perfume materials, pesticides, plastics materials, 
and certain other specified products. In terms of value, 37.2 percent of all 
finished benzenoid imports under part IC in 1971 came from West Germany; 19.6 
percent, from Switzerland: 15.7 percent, from the United Kingdom; and 11.5 percent 
from Japan. 

^ Imports of Benzenoid Chemicals and Products, 1972, TC Publication 601, 1973 
[processed] . 



SYNTHETIC ORGANIC CHEMICALS, 1972 



TABLE 2.— Benzenoid chemicals and products; Summary of U,S, general imports entered under 
Schedule ^j Parts IB and IC of the TSUS. and analysis by competitive status. 1972 



Part and competitive status 



Number 
of 
items 



Quantity 



Percent 
of total 
quantity 



Foreign 
invoice 
value 



Percent of 
foreign 
value 



Unit 
foreign 
value 



Schedule 4, Part IB 

Total' 

Competitive: 

Duty based on ASP^ 

Noncompetitive: 

Duty based on U.S. value 

Duty based on export value 

Competitive status not available 

Schedule 4, Part IC 

Total' 

Competitive: 

Duty based on ASP^ 

Noncompetitive: 

Duty based on U.S. value 

Duty based on export value 

Competitive status not available 

Summary (Schedule 4, Parts IB and IC) 

Total' 

Competitive : 

Duty based on ASP^ 

Noncompetitive: 

Duty based on U.S. value 

Duty based on export value 

Competitive status not available 



1,258 
131 



1,50.S 
183 



1,000 
pounds 



19,583 
28,423 



135,838 



33,011 
17,135 



52,594 
45,558 



1,000 
dollars 



10.5 
15.3 



21,272 
11,556 



155,271 



58,256 



71,775 
20,078 



114,859 



93,047 
31,634 



46.2 
12.9 



Per 
pound 



1.09 
.41 



2.17 
1.17 



' Detail may not add to total due to rounding. 
American selling price. 

Source: Compiled by the U.S. Tariff Commission from records of the U.S. Bureau of Customs. 

Note;--The totals shown in this table differ from those given in the official statistics of the U.S. Department 

of Commerce chiefly because of differences in coverage and in the methods used in compiling the data. In general, 

the statistical coverage in 1972 varies from a low of 74 percent for drugs and flavors and perfumes to almost 
complete coverage for intermediates, dyes, and pigments. 



APPEND IX C 
TABLE 3.— Cyclic intermediates; Glossary of synonymous names 



Common name 



Standard (Chemical Abstracts) na 



1,2, 4- Acid 

Acid yellow 9 

p-Aminobenzenesulfonic acid — 

Amino G acid 

Amino I acid 

Amino R salt 

Aniline oil 

Anthraflavic acid 

Anthrarufin 

Benzal chloride 

Benzan throne 

Benzotrichoride 

Bisphenol A 

B.O.N 

Bromobenz an throne 

Broenner's acid 

C acid 

Chlorobenzanthrone 

Chromotropic acid 

Chrysazin 

2-Cyanopyridine 

3-Cyanopyridine 

Cyanuric chloride 

DADl 

DBB 

Decacyclene 

Developer Z 

o-Dianisidine 

l,l'-Dianthrimide 

Dibenzan throne 

4 ,4 ' -Dihydroxydiphenylsulfone- 

Dimethyl POPo'p 

4,5-Dinitrochrysazin 

Durene 

Fast Red G base 

Fast Scarlet R base 

G salt 

Gamma acid 

Gold salt 

H acid 

Hellimellitene 

J acid 

J acid urea 

Koch's acid 

MEP 

Mesitylene 

Methane base 

Michler's hydrol 

Michler's ketone 



4-Amino-3-hydroxy-l-naphthalenesulfonic acid. 

6-Ainino-3,4 '-azodibenzenesulfonic acid. 

Sulfanilic acid and salt. 

7-Amino-l ,3-naphthalenedisulfonic acid. 

6-Amino-l,3-naphthalenedisulfonic acid. 

3-Amino-2,7-naphthalenedisulfonic acid. 

Aniline. 

2 , 6-Dihydroxyanthraquinone . 

1 ,5-Dihydroxyanthraquinone . 

a,a-Dichlorotoluene. 
7H-Benz [de]anthracen-7-one . 
ct,a,a,-Trichlorotoluene . 
4,4'-lsopronylidenediphenol . 
3-Hydroxy-2-naphthoic acid. 
3-Bromo-7H-benz[de]anthracene-7-one . 
6- Amino- 2 -naphthalene sulfonic acid. 

3-Amino-l,5-naphthalenedisulfonic acid. 

Chloro-7H-benz[de]anthracen-7-one . 

4, 5 -Dihydroxy-2,7-naphthalenedi sulfonic acid. 

1 , 8-Dihydroxyanthraquinone . 

Picolinonitrile. 

Nicotinonitrile. 

2,4,6-Trichloro-s-triazine . 

Dianisidine diisocyanate. 

p-Dibutoxybenzene. 

Diacenaphtho[l,2-j :1,2 '-Jl]fluoranthene. 

3-Methyl-l-phenyl-2-pyrazolin-5-one . 

3,3 '- Dime thoxybenzi dine. 

1 ,1 '-Iminodianthraquinone . 

Violan throne. 

4 ,4'-Sulfonyldiphenol . 

1 ,4- Bis [2- (4-methyl-5-phenyloxazoly 1) ] benzene . 

1 ,8-Dihydroxy-4,5-dinitroanthraquinone . 

1,2,4,5-Tetramethylbenzene. 

2-Nitro-p-toluidine [NH2=1] . 
5-Nitro-o-anisidine [NH2=1]. 

7-Hydroxy-l,3-naphthalenedisulfonic acid. 
6-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodiu 

salt. 
9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid 

and salt. 
4-Amino-5-hydroxy-2, 7 -naphthalenedi sulfonic acid. 
1 , 2 ,3-Trimethylbenzene . 

7-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodiu 

salt. 
7,7'-Ureylenebis(4-hydroxy-2-naphthalenesulfonic 

acid] . 

8-Amino-l ,3,6-napthalenetrisulfonic acid. 

5-Ethyl-2-picoline 

1,3,5-Trimethylben2ene. 

4,4' -Methylenebis [N ,N-dimethy lani 1 ine] . 

4, 4 '-Bis [dime thy lamino]benzhydrol. 

4,4'-Bis[dimethylamino]benzophenone. 



SYNTHETIC ORGANIC CHEMICALS. 1972 
TABLE 3,— Cyclic intermediates: Glossary of synonymous names--Continued 



Common name 



Standard (Chemical Abstracts) name 



Naphthionic acid 

o-Naphthionic acid 

6-Naphthol 

Naphthol AS 

a-Naphthylamine 

Neville5 IVinther's acid — 

Pentaanthrimide 

Phenylbiphenyl 

N-Phenyldiethanol amine 

Phenyl J acid 

Phenyl peri acid 

POPOP 

Ps eudocumene 

Pyrazolean throne 

Pyrazoleanthrone yellow — 
Pyrazolone T 

Quini zarin 

2-Quinizarinsulfonic acid- 

Quinoline yellow base 

R salt 

Schaffer's acid 

Silver salt 

Solvent Yellow 1 

Solvent Yellow 3 

o-Sulfobenzaldehyde 

Thiosalicylic acid 

Tobias acid 

TODI 

o-Tolidine 

a-Toluic acid 

a-Tolunitrile 

4-m-Tolylenediamine 

Trimellitic anhydride 

Trimethyl base 

Trinitrophenol 

Vinyl toluene 



4-Amino-l-naphthalenesulfonic acid. 
1- Amino- 2 -naphthalene sulfonic acid. 
2-Naphthol, tech. 
3-Hydroxy-2-naphthanilide. 
1 -Naphthyl amine . 
4-Hydroxy-l-naphthalene sulfonic acid. 

1,4,5,8-Tetrakis Cl-anthraquinonylaminolanthraquinone. 
Ternhenyl . 

2,2'- [ CPhenyl)imino]diethanol . 

7 -Anilino-4-hydroxy-2 -naphthalene sulfonic acid. 
8-Anilino-l-naphthalenesulfonic acid. 
1 ,4-Bis [2- (S-phenyloxazolyl) ]benzene . 
1 ,2 ,4-Trimethylbenzene . 
Anthra[l,? cd]pyrazol-6(2H)-one . 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione. 
S-Oxo-l- (p-sulfophenyl)-2-pyrazoline-3-carboxylic 
acid. 

1 ,4-Dihydro.\yanthraquinone . 

9 ,10-Dihydro-l ,4-dihydrox>'-9,in-dioxo-2-anthracene- 

sulfonic acid. 
Quinophth alone . 

3-Hydroxy-2 ,7-naphthalenedisulfonic acid, disodium 
salt. 

6-Hydroxy-2-naphthalenesulfonic acid. 
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonic acid 

and salt. 
p-Phenylazoaniline and hydrochloride. 
4- (o-Tolylazo)-o-toluidine . 
o-Formylbenzenesulfonic acid. 

o-Mercaptobenzoic acid. 

2-Amino-l-naphthalenesulfonic acid. 

Bitolylene diisocyanate. 

3,3' -Dinethylbenzidine . 

Phenylacetic acid. 

Phenyl ace tonit rile. 

Toluene-2 ,4-di amine . 

1 ,2,4-Benzenetricarboxylic acid, 1,2 -anhydride. 

l,3,3-Triniethyl-2-methyleneindoline. 

Picric acid. 

ar-Methvlstvrene.