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BOSTON 

PUBLIC 

LIBRARY 


'.J^: 


UNITED      STATES      TARIFF      COMMISSION 


7^ 


SYNTHETIC 
ORGANIC     CHEMICALS 

United  States  Production 
and  Sales,  1972 

TC  Publication  681 


RECENT  REPORTS  OF  THE  UNITED  STATES  TARIFF  COMMISSION  ON 
SYNTHETIC  ORGANIC  CHEMICALS 

Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1967  (TC  Publication  295, 

1969),  $2.00 
♦Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1968  (TC  Publication  327, 

1970),  $2.00 
♦Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1969  (TC  Publication  412, 

1971),  $2.00 
♦Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1970  (TC  Publication  479, 

1972),  $2.00 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales,  1971  (TC  Publication  614, 

1973),  $2.40 


NOTE.— The  reports  preceded  by  an  asterisk  (*)  are  out  of  print.  The  other   reports   listed   above   may 
purchased  from  the  Superintendent  of  Documents,  U.S.  Government  Printing  Office,  Washington,  D.C.  20'! 
All  U.S.  Tariff  Commission  reports  reproduced  by  the   Government  Printing  Office  may   be  consulted   in  tb 
official  depository  libraries  throughout  the  United  States. 


4ol 


UNITED  STATES  TARIFF  COMMISSION 


SYNTHETIC 
ORGANIC    CHEMICALS 

United  States  Production 
and  Sales,  1972 


UNDER  THE  PROVISIONS  OF 
SECTION  332  OF  THE  TARIFF 
ACT  OF  1930,  AS   AMENDED 


U.S.  GOVERNMENT  PRINTING  OFFICE 
WASHINGTON  :   1974 


TC  PubUcation  681 


UNITED  STATES  TARIFF  COMMISSION 

Catherine  Bedell,  Chairman 
Joseph  O.  Parker,  Vice  Chairman 
Will  E.  Leonard,  Jr. 
George  M.  Moore 
J.  Banks  Young 
Italo  H.  Ablondi 

Kenneth  R.  Mason,  Secretary 


Address  all  communications 

UNITED  STATES  TARIFF  COMMISSION 

Washington,  D.C.     20436 


For  sale  by  the  Superintendent  of  Documents.  U.S.  Government  Printing  Office,  Washington.  D.C.  20402 
Price  $2.70         Stock  Number  4900-00038 


CONTENTS 

Page 

Introduction 1 

Summary 3 

General 4 

Tar 7 

Tar  crudes 7 

Crude  products  from  petroleum  and  natural  gas 

for  chemical  conversion 13 

Cyclic  intermediates 19 

Dyes 55 

Organic  pigments 91 

Medicinal  chemicals 101 

Flavor  and  perfume  materials 121 

Plastics  and  resin  materials 133 

Rubber-processing  chemicals 141 

Elastomers 149 

Plasticizers 153 

Surface-active  agents 161 

Pesticides  and  related  products 189 

Miscellaneous  chemicals 199 

APPENDIXES 

A.  Director  of  manufacturers 243 

B.  U.S.  imports  of  benzenoid  chemicals 

and  products 257 

C.  Cyclic  intermediates:   Glossary  of 

synonymous  names 259 


INTRODUCTION 

This  is  the  fifty-sixth  annual  report  of  the  U.S.  Tariff  Commission  on  domestic  production  and  sales  of 
synthetic  organic  chemicals  and  the  raw  materials  from  which  they  are  made.   It  is  authorized  under  the  provisions 
of  section  332  of  the  Tariff  .i^ct  of  1930,  as  amended.   The  report  consists  of  fourteen  sections,  each  covering  a 
specified  group  (based  principally  on  use)  of  organic  chemicals  as  follows:  tar  and  tar  crudes;  crude  products  from 
petroleum  and  natural  gas;  intermediates;  dyes;  pigments;  medicinal  chemicals;  flavor  and  perfume  materials;  plastics 
and  resin  materials;  rubber-processing  chemicals;  elastomers;  plasticizers;  surface-active  agents;  pesticides  and 
related  products;  and  miscellaneous  organic  chemicals.   Data  have  been  supplied  by  approximately  800  producers. 

The  first  table  in  each  section  gives  statistics  on  products  and  groups  of  products  in  as  great  detail  as  is 
possible  without  revealing  the  operations  of  individual  producers.   Statistics  for  an  individual  chemical  or  group 
of  chemicals  are  given  only  when  there  are  three  or  more  producers,  no  one  or  two  of  which  may  be  predominant.   More- 
over, even  when  there  are  three  or  more  producers,  statistics  are  not  given  if  there  is  any  possibility  that  their 
publication  would  violate  tlie  statutory  provisions  relating  to  unlawful  disclosure  of  information  accepted  in  con- 
fidence by  the  Commission.  ' 

"bata  are  reported  by  producers  for  only  those  items  where  the  volume  of  production  or  sales  exceeds  1,000  pounds 
or  the  value  of  sales  exceeds  $1,000.   They  are  usually  given  in  terms  of  undiluted  materials;  however,  products  of 
95  percent -or  more  purity  are  considered  to  be  100  percent  pure.   Commercial  concentrations  are  applied  to  dyes, 
certain  plastics  and  resins,  and  a  few  solvents;  such  concentrations  are  specifically  noted. 

The  statistics  given  in  this  report  include  data  from  all  known  domestic  producers  of  the  items  covered  and  in- 
clude the  total  output  of  each  company's  plants,  i.e.,   the  quantities  produced  for  consumption  within  the  producing 
plant,  as  well  as  the  quantities  produced  for  domestic  and  foreign  sale.   The  quantities  reported  as  produced,  there- 
fore, generally  exceed  the  quantities  reported  as  sold.   Some  of  these  differences,  however,  are  attributable  to 
changes  in  inventory. 

The  second  table  in  each  section  lists  all  items  for  which  data  on  production  or  sales  have  been  reported,  by 
primary  manufacturers,  identified  by  manufacturers'  codes.   Each  code  consists  of  not  more  than  three  capital  letters 
which  is  assigned  on  a  permanent  basis.  The  third  table  in  each  section  is  a  directory,  alphabetized  by  the  codes 
of  the  manufacturers  reporting  in  that  section.   Table  I  of  the  .A.ppendix  is  a  directory,  alphabetized  by  the  names  of 
the  manufacturers  reporting  in  all  sections  and  includes  their  office  addresses. 

Information  on  the  synonymous  names  of  the  organic  chemicals  included  in  this  report  may  be  found  in  the  SOCMA 
Handbook:  Commevoial  Organic  Chemical  Names,  published  by  the  Chemical  Abstracts  Service  of  the  .(^erican  Chemical 
Society,  or  the  Colour  Index   (2d  edition),  published  by  the  Society  of  Dyers  and  Colourists. 

Table  2  of  the  Appendix  summarizes  and  gives  the  competitive  status  of  U.S.  general  imports  in  1972  of  benzenoid 
intermediates  and  finished  benzenoid  products,  entered  under  schedule  4,  parts  IB  and  IC,  of  the  Tariff  Schedules  of 
the  United  States. 

As  specified  in  the  reporting  instructions  sent  to  manufacturers,  production  and  sales  (unless  otherwise 
specified)  are  definf^d  as  follows: 

PEODUCTION  is  the  total  quantity  pf  a  commodity  made  available 
by  original  manufacturers  only.     It  is  the  sum — expressed  in  terms 
of  100%  active  ingredient  unless  othenrtse  specified  in  the  reporting 
instructions — of  the  quantities: 

Produced,    separated,   and  consumed  in  the  same  plant  or 
establishment.     A  commodity  is  considered  separated 
when  it  is  isolated  from  the  reaction  system  and/or 
when  it  is  weighed,   analyzed,   or  otherwise  measured. 
This  includes  byproducts  and  ooproduats  that  are  not 
classifiable  as  waste  materials; 
Produced  and  transferred  to  other  plants  or  establish- 
ments of  the  same  firm; 
Produced  and  sold  to  other  firms,   including  production 
for  another  under  a  toll  agreement   (i.e.,   an  agreement, 
under  which  one  firm  furnishes  the  raw  materials-  and 
pays  the  processing  costs  and  the  other  firm  prepares 
the  finished  product  and  returns  it  to  the  first  firm) 
Produced  and  held  in  stock. 


Title  18,  U.S.C.  1905  and  Title  44,  U.S.C.  3508 


INTRODUCTION 


PRODUCTION  EXCLUDES: 

Purification  of  a  commodity^   unless  inclusion  of 
suck  processing  is  specifically  requested  in 
the  reporting  instructions  for  individual 
sections'. 

Intermediate  products  which  are  formed  in  the 
manufacturing  process,   but  are  not  isolated 
from  the  reaction  system — that  is,   not 
weighed,   analyzed,   or  otherwise  measured; 

Materials  that  are  used  in  the  process  but 
which  are  recovered  for  re-use  or  sale; 

Haste  products  having  no  economic  significance. 

SALES  are  actual  quantities  of  commodities  sold  by  ORIGINAL 
MANUFACTURERS  ONLY.     Sales  include  the  quantity  and  value  of: 
Shipments  of  a  commodity  for  domestic  use  and 
for  export,   or  segregation  in  a  warehouse 
when  title  has  passed  to  the  purchaser  in  a 
bona  fide  sale; 
Shipments  of  a  commodity  produced  by  others  under 

toll  agreements; 
Shipments   to  subsidiary  or  affiliated  companies. 

SALES  EXCLUDE: 


All  intra-company  transfers  within  a  corporate  entity; 
All  sales  of  purchased  commodities; 
All  shipments  of  a  commodity  produced  for  others 
under  toll  agreements. 

VALUE  OF  SALES  is  the  net  selling  value  f.o.b.   plant  or 
warehouse,   or  delivered  value,   whichever  represents  the  normal 
industry  practice. 


SUMMARY  3 

Combined  production  of  all  synthetic  organic  chemicals,  tars,  tar  crudes,  and  crude  products  from  petroleum  and 
natural  gas  in  1972  was  266,419  million  pounds--an  increase  of  12.0  percent  over  the  output  in  1971  (see  table  1). 
Sales  of  these  materials  in  1972,  which  totaled  150,818  million  pounds,  valued  at  $16,028  million,  were  12.8  percent 
larger  than  in  1971  in  terms  of  quantity  and  13.5  percent  larger  in  terras  of  value.   These  figures  include  data  on  pro- 
duction and  sales  of  chemicals  measured  at  several  successive  steps  in  the  manufacturing  process,  and  therefore  they 
necessarily  reflect  some  duplication. 

In  1972,  production  of  all  synthetic  organic  chemicals,  including  cyclic  intermediates  and  finished  chemical  prod- 
ucts, totaled  164,218  million  pounds,  or  15.2  percent  more  than  the  output  in  1971.   Production  increased  in  1972  com- 
pared to  1971  for  all  subgroups  of  products.   Among  the  groups  with  large  volumes  of  production,  plastics  and  resin 
materials  (25,921  million  pounds)  lead  with  an  increase  of  23.0  percent  and  cyclic  intermediates  (34,967  million  pounds) 
followed  with  an  increase  of  16.7  percent.   Other  groups  in  the  large-volume  production  category  increased  as  follows: 
plasticiiers  (1,708  million  pounds),  14.3  percent;  miscellaneous  chemicals  (90,476  million  pounds),  13.9  percent; 
elastomers  (4,914  million  pounds),  6.4  percent;  surface-active  agents  (4,039  million  pounds),  5.5  percent.   In  the  groups 
with  smaller  quantities  of  production,  flavor  and  perfume  materials  (110  million  pounds)  increased  14.6  percent;  organic 
pigments  (66  million  pounds)  rose  13.0  percent;  rubber-processing  chemicals  (361  million  pounds)  was  up  11.6  percent; 
dyes  (263  million  pounds)  increased  8.0  percent.   Smaller  increases  were  shown  by  medicinal  chemicals  (234  million 
pounds),  5.0  percent  and  pesticides  and  related  products  (1,158  million  pounds),  1.9  percent. 


TABLE  1, 


Synthetic  organic  chemicals  and  their  raw  materials; 
U.S.  production  and  sales,  1971  and  1972 


Increase 

or 
decrease 
(-),  1972 

over 

1971' 


Increase 

or 
decrease 
(-),  1972 

over 

1971' 


Increase 

or 

decrease 

(-),  1972 

over 

1971' 


Grand  total 

Tar 

Tar  crudes 

Crude  products  from  petroleum 
and  natural  gas 

Synthetic  organic  chemicals, 
total ^ 

Cyclic  intermediates 

Dyes 

Organic  pigments 

Medicinal  chemicals 

Flavor  and  perfume  materials- 
Plastics  and  resin  materials- 
Rubber-processing  chemicals-- 
Elastomers  (synthetic 

rubbers) 

Plasticizers 

Surface-active  agents 

Pesticides  and  related 

products 

Miscellaneous  chemicals 


Million 
pounds 


Percent 
12.0 


Million   \Million\  \  Million 

pounds     \pounds    \  Pereent       dollars 


133,666  I  150,8181 


Million 
dollars 


6,794 
7,621 


142,503 


7,472 
7,937! 


10.0 
4.1 


3,341 
5,436 


3,409| 
5,304 i 


2.0 
-2.4 


164,218|   15.2 


45,752  1  47,900 


79,157  :  94,205; 


123 
1,078 

12,883 


40 
126 


1,177 


Percent 
13.5 


10.2 
2.4 


14,686    14.0 


29 

953 

34 

967 

244 

265 

58 

66 

223 

234 

96 

110 

21 

071 

25 

921 

323 

361 

4 

616 

4 

914 

1 

494 

1 

708 

3 

828 

4 

039 

1 

136 

1 

158 

79 

460 

90 

476 

12,971 

16,196 

24.9 

230 

255 

10.9 

47 

53 

13.1 

152 

163 

7.2 

85 

104 

22.7 

18,473 

22,946 

24.2 

246 

280 

13.9 

4,031 

4,136 

2.6 

1,404 

1,637 

16.6 

2,186 

2,258 

3.3 

946 

1,022 

8.0 

38,367 

45.155 

17.7 

1,252 

423 

130 

487 

84 

3,507 
159 

1,034 
258 
422 

979 
4,148 


1,434 

480 

149 

490 

88 

4,258 
178 

1,095 
291 

451 

1,092 
4,680 


5.3 

21.4 


11.5 
12.8 


1  Percentages  calculated  from  figures  rounded  to  thousands. 

2  Because  of  rounding,  figures  may  not  add  to  the  totals  shown. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
GENERAL 

In  this   report,    synthetic   organic   chemicals    are   classified  on   the  basis  of  their  princip,al   use   as    follows;      cyclic 
intermediates,    dyes,   organic  pigments,   medicinal   chemicals,    flavor  and  perfume  materials,   plastics    and  resin  materials, 
rubber-processing  materials,    elastomers,    plasticizers ,    surface-active   agents,   pesticides    and  related  products    and  miscel- 
laneous   chemicals    (acyclic   intermediates    and  acyclic  and  cyclic   finished  products).      Most   of  these   groups   are   further 
subdivided  either  by  use   or  by   chemical    composition.      As    intermediate   chemicals   are  used  in   the  manufacture   of  finished 
products,    aggregate   figures   that   cover  both   intermediates   and   finished  products  necessarily   include  considerable  duplica- 
tion. 

Total  production  of  synthetic  organic  chemicals    (intermediates  and  finished  products   combined)   in  1972  was   164,218 
million  pounds,    or   15.2  percent  more  than  the  output   of  142,503  million  pounds   reported  for  1971   and  56.8  percent   more 
than  the  output   of   104,711   million  pounds   reported   for  1967    (see  table   2).      Sales   of  synthetic  organic   chemicals   in    1972 
amounted   to  94,205  million  pounds,    valued  at   Sl4,686  million,    compared  with  97,137  million  pounds,    valued   at   $12,883 
million   in    1971    and  55,177  million  pounds,    valued  at   510,438  million   in   1967.      Production  of  all    cyclic  products    (inter- 
mediates   and   finished  products    combined)    in    1972  totaled  53,637  million  pounds   or   15.9  percent  more   than  the   46,273  mil- 
lion pounds   reported   for   1971    and  60.2  percent   more   than  the   33,479  million  pounds   reported  for  1967.      Production  of  all 
acyclic  products    in   1971    totaled   110,580  million  pounds,    or   14.9  percent   more   than  the   96,230  million  pounds   reported 
for   1971    and   55 . 2  percent   more   than   the   71,232   nillion  pounds    reported   for   1967. 

TABLE  2. --Synthetic  organic  chemicals;     Summary  of  U.S.  production  and  sales 
OF  intermediates  and  finished  products,  1967,  1971,  and  1972 

[Production  and  sales  in  tliousands  of  pounds;  sales  value  in  thousands  of  dollars] 


Organic  chemicals,  cyclic  and  acyclic, 
grand  total : 

Production 

Sales 

Sales  value 

Cyclic,  total: 

Production 

Sales 

Sales  value 

Acyclic,  total : 

Produc  tion 

Sales 

Sales  value 

1.      Cijolic  Intermediates 

Production 

Sales 

Sales  value 

2.  Dyes 

Production 

Sales 

Sales  value 

2.      Organic  Pigments 

Production 

Sales 

Sales  value 

4.     Medicinal  Chemicals 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 


,711,357 
,176,823 
,438,453 


,479,469 
,328,628 
,610,29' 


,2  31,888 
,848,195 
,828,160 


,793,132 
,461,180 
,000,359 


206,240 
198,592 
332,049 


53,322 
42,867 
108,354 


110,129 

70,120 

348,873 

69,941 
56,804 
36,402 


142,502,514 
79,136,628 
12,882,816 


46,272,717 
25,859,561 
5,793,591 


96,229,797 

55,277,067 


29,952,917 
12,970,553 
1,252,300 


243,729 
229,544 
422,627 


58,326 

47,052 

130,013 


132,582 
84,913 


90,636 
67,309 
54.856 


164,217,690 
94,205,254 
14,685,582 


53,637,371 

31,082,064 

6,516,824 


110,580,319 

63,123,190 

8,168,758 


34,967,181 
16,195,641 
1,433,855 


263,304 
254,536 
479,688 


65,897 
53,215 
149,343 


132 

586 

81 

082 

433 

259 

101 

747 

82 

128 

56 

878 

Increase,  or  decrease  (- 


1972  over 
1967 

1972  over 
1971 

Percent 

Percent 

56.8 

70.7 
40.7 

15.2 
19.0 

14.0 

60.2 
60.8 
41.4 

15.9 

20.2 
12.5 

55.2 
76.1 
40.2 

14.9 
18.5 
15.2 

68.2 

71.2 
43.3 

16.7 
24.9 
14.5 

27.7 
28.2 
44.5 

8.0 
10.9 
13.5 

23.6 
24.1 
37.8 

13.0 
13.1 
14.9 

20.4 
15.6 
24.2 

(0 

-4.5 
.4 

45.5 
44.6 

12.3 
22.0 

See  footnotes  at  end  of  table. 


GENERAL 
TABLE  2. --Synthetic  organic  chemicals:     Summary  of  U.S.  production  and  sales 

OF    intermediates    and    finished    products,    1967.    1971,  AND    1972--C0NTINUED 


[Production   and   sales    in   thousands   of  pounds;    sales  value   in   thousands   of  dollars] 


5.      Flavor  and  perfume  Materials 


Cyclic: 

Product! on- - 

Sales 

Sales  value- 
Acyclic: 

Production- - 

Sales 

Sales  value- 


Cyclic  : 

Production- - 

Sales 

Sales  value- 
Acyclic: 

Product! on- - 

Sales 

Sales  value- 


Cyclic: 

Product! on- - 

Sales 

Sales  value- 
Acyclic  : 

Production-- 

Sales 

Sales  value- 


Cyclic: 

Production- 


Sale 


Sales  value- 
Acyclic: 

Production- - 

Sales 

Sales  value- 


9.      Plastiai-zers 


Cyclic: 

Production-- 

Sales 

Sales  value- 

Acyc lie: 

Product  ion- - 

Sales 

Sales  value- 


Plastics  and  Resin  Materials 


Rubber-Proaessing  Cherriaal 


8.     Elastomers   (Synthetic  Rubbers) 


57,978 
47,285 
52,866 


5,033,497 
4,224,121 
1,036,940 

8,759,452 
7,753,242 
1,635,690 


220,139 
169,970 
116,318 

43,994 
30,878 
15,477 


2,297,637 

1 ,940,099 

439,580 

1,524 ,908 

1,321,945 

434,657 


929,871 
865,084 
167,827 

332,908 
296,767 
93,142 


49,682 
42,180 
52,884 

46,744 
42,585 
31,084 


7,266,038 
6,262,651 
1,400,553 

13,804,685 
12,210,359 
2,105,989 


276,146 
211,065 
142,541 


2,614,054 

2,239,804 

484,130 

2,002,046 

1,790,837 

550,315 


1,130,440 

1,074,541 

157,925 

363,598 
329,555 
99,840 


51  ,868 
48,212 
54,168 


58,605 
55,780 


8,946,997 
7,807,933 
1,715,579 

16,973,665 
15,138,142 
2,542,861 


309,930 
240,044 
157,944 

51,091 
40,199 


2,705,599 

2,177,303 

470,549 

2,208,360 

1,958,960 

624,257 


1,301 ,955 

1,273,191 

180,051 

406,358 
364,306 
110,513 


Increase,  or  decrease  (-) 


1972  over 
1967 


2.0 
2.5 


77.8 
84.8 
65.5 

93.8 
95.3 
55.5 


16.1 
30.2 
27.3 


17.8 
12.2 
7.1 

44.8 
48.2 
43.6 


40.0 
47.2 


See  footnote  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Synthetic  organic  chemicals:     Summary  of  U,S,  production  and  sales 

OF    INTERMEDIATES   AND    FINISHED    PRODUCTS,    1967,    197],  AND    1972--CONTINUED 


[Production   and  sales   in   thousands   of  pounds;    sales   value   in  thousands   of  dollars] 


10.     Surface-Aative  Agents 

Cyclic: ' 

Production 

Sales 

Sales  value-' 

Acyclic: 

Production 

Sales 

Sales  value 

II.      Pesticides  and  Related  Products 

Cyclic: 

Production 

Sales 

Sales  value 

Acyclic: 

Production 

Sales 

Sales  value 


12.     Miscellaneous  Chemicals 


Cyclic: 

Production-- 

Sales 

Sales  value- 
Acyclic: 

Production-- 

Sales 

Sales  value- 


1,418 

444 

852 

238 

95 

810 

2,060 

851 

897 

78h 

220 

877 

823,158 
681,532 
627,742 

226,505 
215,831 
159,301 


1,535,922 
775,540 
283,575 

58,159,771 

25,225,631 

3,192,119 


1,542,881 
995,580 
120,795 


1,190,110 
301,685 


827 

590 

669 

143 

819 

028 

308 

127 

277 

194 

160 

055 

1,032,535 
379,093 

77,281,270 

37,334,192 

3,768,587 


1,641,552 

1,053,240 

129,792 

2,397,235 

1,204,306 

320,976 


839,360 
719,707 
889,613 

318,338 
301,858 
202,095 


2,411,142 

1,177,960 

422,983 

88,064,920 
43,977,511 
4,257,239 


Increase,  or  decrease   (- } 


33.4 


6.4 
5.8 

7.5 


1.4 
7.6 
8.6 

3.3 

8.9 
26.3 


14.1 
11.6 


Standard  reference  base  period   for   Federal   Government   general-purpose   inde.x  numbers. 
Less   than  0.05   percent. 
Includes    Ligninsulfonates 

The   following   tabulation  shows,    by  chemical   groups,    the  number  of  companies   that   reported  production   in    1971   of 
one  or  more   of  the   chemical   included  in   the   groups    listed  in   table   2; 


Chemical 

Cyclic  intermediates 

Dyes 

Organic  pigments 

Medicinal  chemicals 

Flavor  and  perfume  materials- 
Plastics  and  resin  materials- 


Ntmber 

of   _ 

compcDiiee 


Chem-oal  group 

Rubber-processing  chemicals 

Elastomers      (synthetic  rubbers)- 
Plasticizers 

Surface- active   agents 

Pesticides   and   related  products- 
Miscellaneous   chemicals 


of    _ 

ciompani.es 


TAR  AND  TAR  CRUDES 


Tar 


Coal  tar  is  produced  chiefly  by  the  steel  industry  as  a  byproduct 
of  the  manufacture  of  coke;  water-gas  tar  and  oil-gas  tar  are  produced 
by  the  fuel-gas  industry.   Production  of  coal  tar,  therefore,  depends 
on  the  demand  for  steel;  production  of  water-gas  tar  and  oil-gas  tar 
reflects  the  consumption  of  manufactured  gas  for  industrial  and  house- 
hold use.   Water-gas  and  oil -gas  tars  have  properties  intermediate  be- 
tween those  of  petroleum  asphalts  and  coal  tars.   Petroleum  asphalts 
are  not  usually  considered  to  be  raw  materials  for  chemicals. 

The  quantity  of  tar  produced  in  the  United  States  in  1972  was  al- 
most entirely  coal  tar  which  amounted  to  747  million  gallons  (see  table  1^). 
Production  in  1972  was  10  percent  more  than  the  679  million  gallons  of 
coal  tar  produced  in  1971.   Sales  of  coal  tar  in  1972  amounted  to  341 
million  gallons,  valued  at  $40  million,  compared  with  334  million  gallons, 
valued  at  $36  million,  in  1971.   U.S.  production  of  water-gas  and  oil-gas 
tars  was  not  reported  to  the  Commission  for  1971  or  1972;  production  of 
these  tars  in  1968  amounted  to  21  million  gallons,  according  to  trade 
publications . 

Consumption  of  tar  in  1972  amounted  to  716  million  gallons,  of  which 
82.8  percent  was  consumed  in  distillation.   Tar  used  by  the  producers  as 
fuel  amounted  to  119  million  gallons.  A  lesser  amount,  4.3  million  gallons, 
was  consumed  by  coke-oven  operators  in  miscellaneous  uses  fsee  table  lA) . 

Tar  Crudes 

Tar  crudes  are  obtained  from  coke-oven  gas  and  by  distilling  coal 
tar,  water-gas  tar,  and  oil-gas  tar.   The  most  important  tar  crudes  are 
benzene,  toluene,  xylene,  naphthalene,  creosote  oil,  and  pitch  of  tar. 
Some  of  these  products  are  identical  with  those  obtained  from  petroleum. 
Data  for  materials  obtained  from  petroleum  are  included,  for  the  most 
part,  with  the  statistics  for  like  materials  obtained  from  coke-oven 
gas  and  tars,  and  are  shown  in  tables  1  and  IB. 


Domestic  production  of  industrial  and  specification  grades  of 
benzene  reported  by  coke-oven  operators  and  petroleum  refinery  operators^ 
in  1972  amounted  to  1,252  million  gallons--16.4  percent  more  than  the 

^  See  also  table  2  of  this  section  which  lists  the  products  in  table  1 
and  identifies  the  manufacturers  by  code.   These  codes  are  given  in  table 

^  Statistics  on  production  and  sales  of  benzene,  toluene,  and  xylene  by 
tar  distillers  cannot  be  shown  because  publication  would  reveal  the  oper- 
ations of  individual  companies. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


1,076  million  gallons  reported  for  1971.   These  statistics  include  data 
for  benzene  produced  from  light  oil  and  petroleum.   Sales  of  benzene  by- 
coke-oven  operators  and  petroleum  refiners  in  1972  amounted  to  679  mil- 
lion gallons,  valued  at  $138  million,  compared  with  593  million  gallons, 
valued  at  $119  million,  in  1971.   In  1972  the  output  of  toluene^  (in- 
cluding material  produced  for  use  in  blending  in  aviation  fuel)  amounted 
to  916  million  gallons--4.5  percent  more  than  the  876  million  gallons 
reported  for  1971.   Sales  of  toluene  in  1972  were  546  million  gallons, 
valued  at  $92  million,  compared  with  484  million  gallons,  valued  at 
$80  million,  in  1971.   The  output  of  xylene^  in  1972  (including  that 
produced  for  blending  in  motor  fuels)  was  739  million  gallons,  com- 
pared with  612  million  gallons  in  1971.   Over  99  percent  of  the  739 
million  gallons  of  xylene  produced  in  1972  was  obtained  from  petroleum 
sources . 

Production  of  crude  naphthalene  in  1972  (including  231  million 
pounds  of  petroleum-derived  naphthalene)  amounted  to  641  million  pounds, 
compared  with  619  million  pounds  in  1971.   In  1972  the  output  of  creosote 
oil  for  wood  preservation  was  139  million  gallons  (100  percent  creosote 
basis),  compared  with  142  million  gallons  in  1971.   Production  of  road 
tar  in  1972  was  30  million  gallons,  compared  with  40  million  gallons  in 
1971. 

Some  of  the  products  obtained  from  tars  and  included  in  the 
statistics  in  table  1  are  obtained  from  other  products  for  which  data 
are  also  included  in  the  table.  The  statistics,  therefore,  involve 
considerable  duplication,  and  for  this  reason  no  group  totals  or  grand 
totals  are  given.  After  duplication  has  been  eliminated  insofar  as 
possible,  the  estimated  net  value  of  the  output  (from  all  sources)  of 
these  products  and  of  tar  burned  as  fuel  was  $698  million  in  1972, 
compared  with  $617  million  in  1971.  The  total  value  of  sales  of  those 
products  obtained  from  coke-oven  gas  and  tars  shown  in  table  1  (ex- 
clusive of  coal  tar  itself),  amounted  to  $126  million  in  197.2,  compared 
with  $123  million  in  1971. 

Data  for  1972  tar  crudes  was  supplied  by  12  companies  and  company 
divisions. 


See  footnote  2  on  page  7, 


TAR 


TAR  CRUDES 


TABLE  1,--Tar  and  tar  crudes:     U,S,   production  and  sales>  1972 

[Listed  below  are  all  tar  crudes  for  which  any  reported  data  on  production  or  sales  may  be  published.   (Leaders  (...) 
are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  2  lists  separately  all  products  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manu- 
facturers reporting  to  the  U.S.  Tariff  Commission] 


Production 


Quantity 


Tar:   Coke-oven  operators 

Crude  light  oil:^   Coke-oven  operators 

Intermediate  light  oil:   Coke-oven  operators 
Light-oil  distillates: 

Benzene,  specification  and  industrial 

grades,  total^  '* 

Coke-oven  operators 

Petroleum  refiners 

Toluene,  all  grades,  total  ^  ** 

Coke-oven  operators 

Petroleum  refiners 

Xylene,  all  grades'  '* 

Coke-oven  ope ra tors 

Petroleum  refiners 

Solvent  naphtha:  Coke-oven  operators' 

Naphthalene,  crude  (tar  distillers  and  coke- 
oven  operators),  total^ 

Solidifying  at-- 

Less  than  74°  C 

74°  C.  to  less  than  79°  C 

Crude  tar-acid  oils:'  Coke-oven  operators-- 

Creosote  oil  (Dead  Oil)  (tar  distillers  and 
coke-oven  operators)  (100%  creosote 

basis  J ,  total  ^ — 

Distillate  as  such  (100°  creosote  basis)-- 
Creosote  content  of  coal  tar  solution 
(100%  creosote  basis)' 

All  other  distillates,  total 

Coke-oven  operators,  total  

From  light  oil 

Other" 

Tar  distillers^ 

Tar,   road 

Tar,   refined,    for  other  uses 

Pitch  of  tar   (tar  distillers   and   coke-oven 

operators) ,   total 

Soft    (water  softening  point   less   than 

110°   F.) 

Medium  (water  softening  point  110°  F.  to 

160°  F.) 

Hard  (water  softening  point  over  160°  F.)^ 


1,000  gal- 
1,000  gal- 
1,000  gal- 


1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 

1,000  gal- 


1,000  Ib- 
1,000  Ib- 


1,000  gal-- 


1,000  gal-- 

1,000  gal-- 

1,000  gal-- 

1,000  gal-- 

1,000  gal-- 

1  ,000  gal-- 

1  ,000  gal-- 

1,000  gal-- 

1,000  gal-- 

1,000  gal-- 

1 ,000  tons 

1,000  tons 

1 ,000  tons 

1 ,000  tons 


747,186 

214,201 

3,704 


1,252,442 

79,849 

1,172,593 

915,872 

14,571 

901,301 

739,332 

3,351 

735,981 

2,815 


17,374 
392,701 


9,731 


25,213 


6,905 
3,898 
3,007 


29,807 
14,395 


1,568 


340,875 
86,915 

754 


679,235 

80,225 

599,010 

545,880 

13,954 

531,926 

560,432 

3,208 

557,224 

2,596 


1,000 
dollars 


39,634 
9,584 


138,478 

16,338 

122,140 

91,529 

2,501 

89,028 

94,128 

578 

93,550 

462 


9,627 
215,364 


144 
10,281 


22,956 


16,187 

'  6,769 

3,675 


2,520 
2,837 
14,507 

29,873 
13,082 

1,009 


1,060 
849 
211 

2,615 

5,493 
3,516 


(') 


.20 
.34 
.07 


177 
633 


10,035 
30,783 


56.69 
48.63 


Unit  value  per  gallon,  pound,  or  ton,  as  specified. 

^  Includes  only  data  for  coal  tar  reported  to  the  Division  of  Fossil  Fuels,  U.S.  Bureau  of  Mines.   Data  on  U.S.  pro- 
duction of  water-gas  tar  and  oil-gas  tar  are  not  collected  by  the  Tariff  Commission,  but  according  to  trade  publica- 
tions, production  of  these  tars  amounted  to  21  million  gallons  in  1968. 

'  Data  reported  by  tar  distillers  are  not  included  because  publication  would  disclose  the  operations  of  individual 
companies.  Production  of  benzene,  toluene,  and  xylene  by  tar  distillers  decreased  in  1972,  compared  with  1971.  The 
annual  production  statistics  for  petroleum  refiners  on  benzene,  toluene,  and  xylene  are  not  comparable  with  the  com- 
bined monthly  production  figures,  because  of  fiscal  year  revisions. 


Note. --Statistics  for  materials  produced  in  coke  and  gas-retort  ovens  are  compiled  by  the  Division  of  Fossil  Fuels, 
U.S.  Bureau  of  Mines,  Department  of  the  Interior.  Statistics  for  materials  produced  in  tar  and  petroleum  refineries 
are  compiled  by  the  U.S.  Tariff  Commission. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


Footnotes  for  table  1 — Continued 

'*  Includes  data  for  material  produced  for  use  in  blending  motor  fuels. 

^  Statistics  represent  combined  data  for  the  commercial  grades  of  naphthalene.   Because  of  conversion  of  naphthalene 
from  one  grade  to  another,  the  figures  may  include  some  duplication. 

'  Statistics  include  data  only  for  creosote  oil  sold  for,  or  used  in,  wood  preserving. 

'  In  1972,  production  of  coal-tar  solution  containing  creosote  (100%  solution  basis)  amounted  to  38,144  thousand  gal- 
ons ;  sales  were  36,232  thousand  gallons,  valued  at  6,769  thousand  dollars,  with  a  unit  value  of  $0.19  per  gallon. 

°  Includes  data  for  crude  sodium  phenolate. 

^  Includes  data  for  crude  light  oil,  benzene,  toluene,  xylene,  solvent  naphtha,  ethylbenzene ,  rubber-reclaiming  oils, 
pyridine  crude  bases,  crude  tar-acid  oils,  crude  cresylic  acid,  neutral  oils,  methylnaphthalene ,  crude  tar  for  other 
uses,  and  unspecified  tar  distillates. 
'°  Includes  hard  pitch  and  pitch  emulsion,  along  with  a  small  amount  of  medium  pitch  produced  by  coke-oven  operators. 


TABLE  1A.--TAR;     U.S.  production  and  consumption^  1971  and  1972 

(In  thousands  of  gallons) 


Product 

1971 

19  72 

PRODUCTION 

679,377 

747,186 

CONSUMPTION 

685,684 

715,823 

572,160 

592,507 

230,959 
341,201 

111,877 

1,647 

273,388 
319,119 

4,286 

Reported  to  the  Division  of  Fossil  Fuels,  U.S.  Bureau  of  Mine^. 

Reported  to  U.S.  Tariff  Commission.  Represents  tar  purchased  from  companies  operating  coke  ovens  and  gas-retort 
plants  and  distilled  by  companies  operating  tar-distillation  plants.  Statistics  also  include  tar  consumed  other  than 
by  distillation  by  tar  distillers. 


TAR  AND  TAR  CRUDES 


TABLE  IB. --Tar  and  tar  crudes;     Summary  of  U.S.  production  of  specified  products, 

1967,  1971,  and  1972 


Unit 

of 

quantit 


Increase,  or 
decrease  (-) 


1972  over 
1967 


1972  over 
1971 


Tar' 

Benzene : ' 

Coke-oven  operators - 

Petroleum  refiners-- 

Total 


1,000  gal- 


1,000  gal- 
1,000  gal- 


90,642 
878,704 


679,377 


72,147 
1,003,760 


Toluene : ^ 

Coke-oven  operators- 
Petroleum  refiners-- 
Total 


1,000  eal-- 


1,000 
1,000  gal- 


969,346 


19,357 
624,454 


79,849 
1,172,592 


Percent 
-4.2 


-11.9 
33.4 


Xylene:' 

Coke-oven  operators- 
Petroleum  refiners-- 
Total 


1,000  gal- 


1,000  gal- 
1,000  gal- 


643,811 


5,488 
449,349 


862,921 


1,252,442 


14,571 
901,301 


2,906 
609,419 


3,351 
735,981 


-38.9 
63.8 


Naphthalene : 

Crude  ^ 

Petroleum  naphthalene. 
Total 


ill  grades- 


1,000  gal-- 


1,000  Ib- 
1,000  Ib- 


454,837 


520,991 
376,679 


612,325 


360,607 
258,312 


410,075 
230,643 


-21.3 
-38.8 


Creosote  oil  (Dead  oil): 

Distillate  as  such  (100%  creosote 

basis) 

Creosote  content  of  coal  tar  solution 

(100%  creosote  basis) 

Total 


1,000  gal- 
1,000  gal- 


108,832 
17,402 


115,669 
26,208 


114,095 
25,213 


1,000  gal-- 


126,234 


141,877 


139,308 


10.4 


Peyaent 
10.0 


15.3 
20.8 


-1.8 


Standard  reference  base  period  for  Federal  Government  general -purpose  index  numbers. 
^  Includes  only  data  for  coal  tar  reported  to  the  Division  of  Fossil  Fuels,  U.S.  Bureau  of  Mines. 

Data  reported  by  tar  distillers  are  not  included  because  publication  would  disclose  the  operations  of  individual 
companies. 

*  Includes  data  for  material  produced  for  use  in  blending  motor  fuels.  Statistics  are  not  comparable  with  monthly 
figures  which  included  some  o-xylene. 

5  Naphthalene  solidifying  at  less  than  79°  C.   Figures  include  production  by  tar  distillers  and  coke-oven  operators 
and  represent  combined  data  for  the  commercial  grades  of  naphthalene.   Because  of  conversion  between  grades,  the  figures 
may  include  some  duplication.   Statistics  on  naphthalene  refined  from  domestic  crudes  are  reported  in  the  section  on 
cyclic  intermediates. 

Includes  data  for  creosote  oil  produced  by  tar  distillers  and  coke-oven  operators  and  used  only  in  wood  preserving. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Tar  crudes  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972 

[Tar  crudes  for  which  separate  statistics  are  given  in  table  1  are  marked  with  an  asterisk  (*) ;   products  not  so 
marked  do  not  appear  in  table  1  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published. 
Manufacturers'  identification  codes  shown  below  are  taken  from  table  3.   Table  3  identifies  all  U.S.  producers  of 
tar  crudes  (except  producers  that  report  to  the  Division  of  Fossil  Fuels,  U.S.  Bureau  of  Mines)] 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


•Crude  light  oil 

Light-oil  distillates; 

Benzene,  specification  grades' 

Toluene,  specification  grades' 

Xylene,  all  grades  

Solvent  naphtha  

All  other  light-oil  distillates' 

Pyridine  crude  bases  

'Naphthalene,  crude,  solidifying  at-- 

*Less  than  74°  C' 

*74°  C.  to  less  than  79°  C:' 

74°  C.  to  less  than  76°  C 

76°  C.  to  less  than  79°  C 

Methylnaphthalene 

Crude  tar-acid  oils:' 

Tar-acid  content  S%   to  less  than  24"^ 

Tar-acid  content  24*o  to  50-6 

Cres\'lic  acid,  crude 

•Creosote  oil  (Dead  oil); 

'Distillate  as  such' 

•Creosote  in  coal  tar  solution' 

•All  other  distillate  products' 

•Tar,  road 

Tar  for  other  uses: 

Crude 

•Refined' 

•Pitch  of  tar: 

•Soft  (water  softening  point  less  than  110°  F.)'-- 
•Medium  (water  softening  point  110°  F.  to  160°  F.) 

•Hard  (water  softening  point  above  160°  F.)' 

Pitch  emulsion 


CBT. 

ACY,  KPP. 

ACY,  KPP. 

ACY. 

ACY,  NEV,  PAI. 

KPT,  PAI. 

KPT. 

COP. 


KPT. 

ASC, 

KPT. 

KPT. 

KPT. 

ASC, 

WTC. 

KPT. 

ASC,  CBT,  COP,  HUS,  KPT,  RIL,  WTC. 
ASC,  KPT,  RIL,  WTC. 
ASC,  KPT,  PAI. 
ASC,  KPT,  RIL. 

KPT,  RIL. 
ASC,  KPT,  RIL. 

ASC,  KPT,  WTC. 

ASC,  CBT,  COP,  KPT,  RIL,  WTC. 

ASC,  HUS,  KPT,  RIL. 

JEN. 


Does  not  include  manufacturers'  identification  codes  for  producers  who  report  to  the  Division  of  Fossil  Fuels, 
U.S.  Bureau  of  Mines.  Those  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey,  November  27, 
1973,  entitled  "Coke  Producers  in  the  U.S.  in  1972". 


TABLE  3. --Tar  and  tar  crudes:     Directory  of  manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 

[Names  of  manufacturers  that  reported  production  or  sales  of  tar  and  tar  crudes  to  the  U.S.  Tariff  Commission  for 
1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  21 


Code 

Name  of 

company 

Code 

Name   of  company 

ACY 

American   Cyan amid  Co. 

KPT 

Koppers   Co.,    Inc.,    Organic  Materials    Div. 

ASC 

Allied   Chemical    Corp. , 

Semet-Solvay   Div. 

CBT 

Samuel    Cabot,    Inc. 

NEV 

Neville   Diemical    Co. 

COP 

Coopers   Creek   Chemical 

Corp. 

HUS 

Husky   Industries,    Inc. 

PAI 

Pennsylvania   Industrial    Chemical    Corp. 

JEN 

Jennison-Wright   Corp. 

RIL 
WTC 

Reilly  Tar  5  Chemical   Corp. 
Witco   Cnemical    Co.,    Inc. 

KPP 

Sinclair-Koppers    Co. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1,  o*^  the  Appendix. 


13 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS  FOR 
CHEMICAL  CONVERSION 


Crude  products  that  are  derived  from  petroleum  and  natural  gas ^ 
are  related  to  the  intermediates  and  finished  products  made  from  such 
crudes  in  much  the  same  way  that  crude  products  derived  from  the  dis- 
tillation of  coal  tar  are  related  to  their  intermediates  and  finished 
products.   Many  of  the  crude  products  derived  from  petroleum  are 
identical  with  those  derived  from  coal  tar  (e.g.,  benzene,  toluene, 
and  xylene).   Considerable  duplication  exists  in  the  statistics  on  the 
production  and  sales  of  petroleum  crudes  because  some  of  these  crude 
chemicals  are  converted  to  other  crude  products  derived  from  petroleum 
and  because  data  on  some  production  and  sales  are  reported  at  succes- 
sive stages  in  the  conversion  process.   The  statistics  are  sufficiently 
accurate^  however,  to  indicate  trends  in  the  industry.  Many  of  the 
crude  products  for  which  data  are  included  in  the  statistics  may  be 
used  either  as  fuel  or  as  basic  materials  from  which  to  derive  other 
chemicals.   In  this  report  every  effort  has  been  made  to  exclude  data  on 
materials  that  are  used  as  fuel;  however,  data  are  included  on  toluene 
and  xylene  which  are  used  in  blending  aviation  and  motor  fuel. 

The  output  of  crude  products  derived  from  petroleum  and  natural  gas 
as  a  group  amounted  to  86,792  million  pounds  in  1972,  or  7.0  percent 
more  than  the  81,043  million  pounds  reported  for  1971  (table  1).^  The 
larger  output  in  1972  is  accounted  for  chiefly  by  increased  production  of 
ethylene,  propylene  and  benzene.   Sales  of  crude  chemicals  from 
petroleum  in  1972  amounted  to  47,900  million  pounds,  valued  at  $1,177 
million,  compared  with  45,752  million  pounds,  valued  at  $1,078  million, 
in  1971. 

The  output  of  aromatic  and  naphthenic  products  from  petroleum 
amounted  to  23,753  million  pounds  in  1972,  compared  with  21,449  million 
pounds  in  1971.   Sales  amounted  to  $351  million  in  1972,  and  ^308 
million  in  1971.   The  output  of  1°  and  2°   benzene  from  petroleum  in  1972 
(8,654  million  pounds)  was  17,1  percent  more  than  the  7,388  million 
pounds  produced  in  1971. 

Production  of  all  aliphatic  hydrocarbons  and  derivatives  from 
petroleum  and  natural  gas  was  63,039  million  pounds  in  1972,  compared 
with  59,594  million  pounds  in  1971.   Sales  Of  these  products  were 
valued  at  $825  million  in  1972  compared  with  $769  million  in  1971. 
Production  of  ethylene  was  20,852  million  pounds  in  1972--13.0  percent 
more  than  the  18,450  million  pounds  produced  in  1971.  The  output  of 
1,3-butadiene  in  1972  (3,527  million  pounds)  was  the  largest  on  record. 

Data  for  19  72  crude  products  from  petroleum  and  natural  gas  for 
chemical  conversion  was  supplied  by  73  companies  and  company  divisions. 


^  Statistics  on  aromatic  chemicals  from  coal  tar  are  given  in  the  re- 
port on  "Tar  and  Tar  Crudes". 

^  See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers by  codes.   These  codes  are  given  in  table  3. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972  ' 
TABLE  1. --Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion: 

U.S.  production  and  SALESy  1972 


[Listed  below  are  the  crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  any  reported 
data  on  production  or  sales  may  be  published.  {Leaders  (...)  are  used  where  the  reported  data  are  accepted  in  confidence 
and  may  not  be  published  or  where  no  data  were  reported.)   Table  2  lists  separately  all  products  from  petroleum  and 
natural  gas  for  chemical  conversion  for  which  data  on  production  or  sales  were  reported  and  identifies  the 
manufacturers  of  each] 


Quantity 


Grand  total 

2 

aromatics  and  napiithenes 

Total 

Benzene    (1°   and   2°) 

Naphthalene,    all    grades 

Naplithenic   acid 

Toluene,  all  grades,  total 

Nitration  grade,  1° 

Pure  commercial  grade,  2- 

Solvent  grade,  90% 

All  other 

Xylenes,  mixed,  total 

3°  grade 

5'^  grade 

All  other' 

All  other  aromatics  and  naphthenes"* 

ALIPHATIC  HYDROCARBONS 

Total 

C  hydrocarbons,  total 

Acetylene  

Ethane 

Ethylene 

Cj  and  Cg  hydrocarbons,  mixed 

C3  hydrocarbons,  total 

Propane 

Propylene' 

Cit    hydrocarbons,    total 

1 , 5- Butadiene,  grade  for  rubbers  (elastomers)- 

Butadiene  and  butylene  fractions 

n- Butane 

1-Butene 

1-Butene  and  2-butene  mixtures' 

Isobutane 

Isobutylene 

All  other* 

C5  hydrocarbons,  total 

Isopentane  (2-Methylbutane) 

Isoprene  (2-Methyl-l ,3-butadiene) 

Pentenes,  mixed 

All   other' 


1,000 
pounds 

3,792,187 


,752,898 


8,653,736 
230,643 
33,190 

6,552,591 


4,877,029 
429,868 
152,401 

1,093,293 

5,306,422 


1,184,423 

383,384 

3,758,615 

2,976,316 


26,297,040 


5,136,540 

20,852,144 


133,062 
18,079,972 


9,608,315 
8,471,657 


10,610, 


3,527,422 
567,998 

2,331,119 

61,597 

752,791 

942,082 

600,184 

1,827,734 

962,223 


7,967 
372,663 
318,978 
262,615 


1,000 


47,899,859 


1,000 
do  t  tars 


1,176,609 


15,402,465 


4,420,693 
164,314 


3.867,231 


,828,364 
255,584 


783,283 
4,017,5.J5 


744,195 

401,381 

2,872,009 


3,995,766 
5,649,443 


8,620,910 
3,918,302 


2,230,009 

436,231 

443,707 

46.617 

782,157 

315,564 
1,397,859 


351,401 


122,140 

7,753 


66,662 
5,738 


16,628 
93,550 


16,539 
9,995 
67,016 


36,729 
168,252 


107,445 
111,765 


251,300 


173,844 
11,817 
4,367 
2,386 
21,681 

11,808 
25.397 


CRUDE  PRODUCTS  FROM  PETROLEUM  AND  NATURAL  GAS  FOR  CHEMICAL  CONVERSIC:! 

TABLE  1,— Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion; 
U.S.  production  and  sales,  1972 


Quantity 


Unit 
value' 


1,000 


1,000 


aliphatic  HYDROCARBONS--Continued 

All  other  aliphatic  hydrocarbons,  derivatives,  and 

mixtures,  total 

Alpha  olefins   

Heptenes,  mixed 

Hexanes  and  other  Cj.  hydrocarbons 

Nonene  (Tr ipropy lene) 

n-Paraffins,  total 

Carbon  chain  length,  C^-Cj^ 

Other 

Polybutene  

Tetrapropylene 

Hydrocarbon  derivatives  

All  other" 


956 

265 

517 

434 

83 

838 

339 

668 

341 

590 

063 

653 

279 

199 

784 

454 

198 

080 

210 

173 

114 

246 

087 

583 

4,134,378 


iini,084 

26,713 

299,807 

247,040 

747,744 

276,351 

471,393 

139,356 

57,322 

82,760 

2,132,552 


1,000 
dollars 


133.389 


Per 

pound 


21,946 
847 

8,621 

8,446 
23,151 

5.170 
17,981 
10,217 

2,034 
10,008 
48,119 


.055 
.032 
.029 
.034 
.031 
.019 
.038 
.073 
.035 
.121 
.023 


'  Calculated  from  rounded  figures. 

2  The  chemical  raw  materials  designated  as  aromatics  are  in  some  cases  identical  with  those  obtained  from  the 
distillation  of  coal  tar;  however,  the  statistics  given  in  the  table  above  related  only  to  such  materials  as  are  de- 
rived from  petroleum  and  natural  gas.   Statistics  on  production  or  sales  of  benzene,  toluene,  xylene,  and  naphthalene 
from  all  sources  are  given  in  tables  1  and  IB  of  the  report  "Tar  and  Tar  Crudes,  1972." 

5  Includes  toluene  and  xylene  used  as  solvents,  as  well  as  that  which  is  blended  in  aviation  and  motor  gasolines. 

"  Includes  data  for  crude  cresylic  acid,  alkyl  aromatics,  distillates,  solvents  ,  miscellaneous  cyclic  hydrocarbons 
and  sales  of  naphthenic  acid. 

5  Production  figures  on  acetylene  from  calcium  carbide  for  chemical  synthesis  are  collected  by  the  U.S.  Bureau  of 
the  Census. 

'  Includes  data  for  propane-propylene  mixture. 

'  The  statistics  represent  principally  the  butene  content  of  crude  refinery  gases  from  which  butadiene  is  manu- 
factured. 

8  Includes  data  for  mixed  butanes,  2-butene,  mixed  butylene,  and  mixed  olefins. 

'  Includes  data  for  isopentane,  pentenes,  and  C5  hydrocar^joi  mixtures. 
'"  Includes  data  for  the  following  molecular  weight  ranfer.:   Ce-C?;  Ca-Cio;  C,i-C,5;  Cjj-Cn;  C15-C20;  and 

"  Includes  compounds  having  a  molecular  weight  of  3,000  or  less. 
'2  Includes  data  for  butyl,  ethyl,  methyl,  and  miscellaneous  mercaptans . 

"  Includes  data  for  di-isobutylene,  methane-ethane-ethylene  mixture,  heptane,  methane,  octanes,  hydrocarbon  mixtures, 
sales  of  acetvlene  and  of  mixed  C-  and  C,  hydrocarbons. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 

TABLE  2, --Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which 
U.S,   production  or  sales  were  reported,   identified  by  manufacturer,  1972 

[Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  separate  statistics  are  given  in 
table  1  are  marked  below  with  an  asterisk  (*) ;  products  not  so  marked  do  not  appear  in  table  1  because  the  reported 
data  are  accepted  in  confidence  and  may  not  be  published.   Manufacturers'  identification  codes  shown  below  are  taken 
from  table  3.   An  x  signifies  that  the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


AROMATICS  AND  NAPHTHENES 

*Benzene  (except  motor  grade) : 

'Benzene,  1° 

*Benzene,  2° 

Cresylic  acid,  crude 

♦Naphthalene,  all  grades- 

*Naphthenic  acids: 

Acid  number  lower  than  150 

Acid  number  150-199 

Acid  number  200-224 

Sodium  carbolate  and  phenate,  crude 

*Toluene: 

*Nitration  grade,  1° 

*Pure  commercial  grade,  2° 

'Solvent  grade,  90°i. 

All  other 

'Xylenes,  mixed: 

Aviation  grade 

*3°  grade 

*5°  grade 

All  other 

All  other  aromatics,  naphthenes,  distillates  and  solvents 

ALIPHATIC  m'DROCARBGNS 

Ci  hydrocarbon:   Methane 

*C 2  hydrpcarbons: 

'Acetylene 

'Ethane 

'Ethylene 

*C 2  and  C 3  hydrocarbons,  mixed 

*C  3  hydrocarbons: 

'Propane 

'Propane-propylene  mixture 

'Propylene 

*C  1,  hydrocarbons : 

♦1,3-Butadiene,  grade  for  rubbers  (elastomers) 

'Butadiene  and  butylene  fractions 

*n- Butane 

'1-Butene 

2-Butene 


ACU,  AMO,  APR,  ASH,  ATR,  CCP,  CSP,  CSD,  CSO,  CSP,  DLH, 
ENJ,  GDC,  GRS,  MOC,  MON,  PLC,  PPR,  SHC,  SHO,  SKO,  SM, 
SNT,  SOG,  SUN,  TOG,  TX,  UCC,  UOC. 

CPI,  DOW,  SHO,  SOG. 

PRO. 

ASH.  GOL,  MON.  SUN,  TID. 

SOG,  SUN,  TX. 
ATR,  PRO,  SOG,  SUN. 
ATR,  PRD,  see. 
ATR. 

ASH,  ATR,  CCP,  CSD,  CSP,  DLH,  ENJ,  GOG,  MOG,  MON,  PLC, 

PPR,  SHC,  SHO,  SNT,  SOG,  SUN,  TOG,  TX,  UCC,  UOG. 
ATR,  CPI,  DOW,  ENJ,  MON,  UCC. 
AGG,  FG,  SKO. 
ATR,  CPI,  CSD,  ELP,  GRS,  GYR,  PLC,  PPR,  SHO,  SM,  SOG. 

CSO. 

CSD,  DLH,  GOC,  MOG,  PPR,  SHO,  SUN,  UOG. 

ASH,  ATR,  SOG. 

AMO,  CCP,  CPI,  CSD,  CSP,  ENJ,  HGR,  MON,  PPR,  SHC,  SNT, 

SOG,  STY,  SUN,  TOG,  UCC. 
AGG,  ACU,  ATR,  CBN,  CPX,  DUP,  ELP,  ENJ,  FG,  GOG,  JCG, 

MOC,  MON,  OMG,  PLC,  SHC,  SOG,  SOG,  TX,  UCC. 


DOW,  DUP,  MNO,  RH,  UCC. 

ACU,  ATR,  DOW,  ENJ,  MON,  OMG,  PAN,  PLC,  PUE,  SHO,  SM, 

TX,  USI. 
ACU,  ATR,  BFG,  CBN,  GO,  CPX,  DOW,  DUP,  EKX,  ELP,  ENJ, 

FRO,  GOC,  JCG,  KPP,  MON,  NWP,  OMG,  PLC,  PUE,  SHC,  SM, 

SNO,  UCC,  USI. 
CCP,  GO,  CSO,  PLC. 

AMO,  ASH,  ATR,  COR,  CPI,  CSD,  CSO,  CSP,  ENJ,  GOG, 

GRS,  MOG,  OMG,  PAN,  PLC,  PUE,  SHO,  SM,  SNT,  SOG,  SUN, 
TX,  UOC,  USI. 

GOG. 

ACU,  AMO,  ASH,  ATR,  BFG,  CBN,  CCP,  COR,  CPX,  CSO,  DOW, 
DUP,  EKX,  KLP,  ENJ,  GOG,  JCC,  KPP,  MOC,  MON,  NWP, 
PLC,  PUE,  SHC,  SHO,  SIO,  SM,  SNT,  SOG,  SUN,  TX,  UCC. 

ATR,  BFG,  GPY,  DOW,  ELP,  ENJ,  FRS,  MON,  PLC,  PTT,  PUE, 

SBI,  SHC,  SM,  TID,  TUS,  UCC. 
ACU,  ATR,  CO,  CPX,  DOW,  EKX,  GOC,  GYR,  KPP,  PLC,  SHO, 

UCC. 
ATR,  BFG,  COR,  CPI,  CSD,  CSP,  GRS,  OMC,  PAN,  PLC,  SHO, 

SM,  SNT,  SUN,  USI. 
GOC,  PLC,  PTT. 
MON,  PLC. 


CRUDE  PRODUCTS  FRO^l  PETROLEUM 


NATURAL  GAS  FOR  CHEMICAL  CONVERSION 


TABLE  2, --Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which 
U,S,   production  or  sales  were  reported,   identified  by  manufacturer,  1972--Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  3} 


ALIPHATIC  HYDROCARBONS- -Continued 

*C^  hydrocarbons--Continued 

*1-Butene  and  2-butene  mixture 

*Isobutane 

*Isobutylene 

All  other 

*C^   hydrocarbons: 

*lsopentane  (2- Methyl butane) 

*lsoprene  (2-Methyl-l , 3-butadiene) 

n-Pentane 

*Pentenes,  mixed 

All  other 

'Cf  hydrocarbons: 

*Hexane 

Neohexane  (2, 2-Dimethylbutane) 

All  other 

Cj  hydrocarbons: 

n-Heptane 

*Heptenes,  mixed 

All  other 

Cg  hydrocarbons: 

Diisobutylene  (Diisobutene) 

n-Octane 

All  other 

Hydrocarbons,  Cg  and  above: 

*Nonene  CTripropylene) 

*Polybutene 

*Tetrapropylene 

Triisobutylene 

All  other 

*A11  other  aliphatic  hydrocarbons,  derivatives  and 
mixtures; 
Hydrocarbons : 
*Alpha  olefins--Molecular  weight  ranges: 

Cj.-C, 

Cj-'^io 

Ci,-Cl5  

All  otner 

*n-Paraf fins--Carbon  chain  length: 

C^.C, 

♦C-c,, 

C,o-Ci6 

All  other 

*Hydrocarbon  derivatives: 

n- Amyl  mercap tan 

tert-Amyl  mercaptan  (2-Methyl-2-butanethiol) — 

1- Butane  thiol 

tcrt- Butyl -mercaptan  (2-Methyl-2-propanethiol)- 

Cyclohexyl  mercaptan 

Di-tert- butyl  disulfide 

Di-tert-nonylpoly sulfide 

Ethyl  mercaptan  (Ethanethiol) 

n-Hexadecyl  mercaptan 

I s  opropy 1  mercaptan 

Methyl  mercaptan  (Methanethiol) 

tert-Nonyl  mercaptan 

n-Propyl  mercaptan  (1-Propanethiol) 

All  other 

Mixtures,  not  elsewhere  classified 


AMD,  ATR,  CSO,  ENJ,  GDC,  PLC,  PIT,  SHO,  TX . 

AIR,  CSP,  ELP,  GRS,  CMC,  PAN,  PLC,  SHO,  USI. 

ENJ,  PLC,  SHC,  SHO,  x. 

APR,  ATR,  BFG,  CBN,"  ENJ,  GRS,  JCC,  MON,  PLC,  PUE,  SM, 
USI. 

APR,  PAN,  PLC,  SHO,  SM. 

BFG,  ENJ,  GYR,  MON,  SHC. 

APR,  PLC. 

GYR,  MON,  TX. 

CBN,  ELP,  MON,  PLC,  SHC,  UCC. 

APR,  ENJ,  PLC,  SOG,  UOC. 

PLC. 

APR,  BFG,  PLC,  SWC. 

EKX,  PLC,  SOG. 

AIP,  ENJ,  GOC,  SOI,  TID. 

ENJ,  HCR,  PLC,  UOC. 

BFG,  PTT,  TX. 

SOG. 

ENJ,  PLC. 

AIP,  ATR,  CSD,  ENJ,  SUN,  UOC. 

ACC,  CSD,  SOC. 

ATR,  CO,  ENJ,  SOC,  SUN,  TX,  UOC. 

X. 

ACC,  ATR.  CO,  CPI,  ENJ,  KPP,  PLC,  PUE,  SOC,  TID,  TNA, 
UCC. 


GOC,  GYR,  SOC. 

GOC,  SOC. 

GOC,  SOC. 

EKX,  GOC,  SOC,  TID,  TNA. 

SOG. 

BFG,  HCR,  SOG. 

ENJ,  SOG,  UCC. 

CO. 

ATR,  PUE,  UCC. 

PAS. 

PLC. 

PAS,  PLC. 

PAS. 

PAS. 

PLC. 

PAS. 

PAS,  PLC. 

PAS. 

PAS. 

ACC,  PAS. 

PAS. 

PAS,  PLC. 

EKX,  PAS,  PLC,  UCC. 

ATR,  GYR,  MON. 


SWHETIC  ORG,AfHC  CHB1ICALS.  1^72 

TABLE  3,— Crude  products  from  petroleum  and  natural  gas  for  chemical  conversion: 
Directory  of  manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 


[Names  of  manufacturers  that  reported  production  or  sales  of  crude  products  from  petroleum  and  natural  gas  for 
chemical  conversion  to  the  U.S.  Tariff  Commission  for  1972  are  listed  below  in  the  order  of  their  identification 
codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ACC 

Amoco  Chemicals  Corp. 

MNO 

Monochem,    Inc. 

ACU 

Allied  Chemical   Corp. ,   Union  Texas 

MOC 

Marathon   Oil    Co.,   Texas   Refining   Div. 

Petroleum  Div. 

MON 

Monsanto  Co. 

AIP 

Air  Products   6  Chemicals,    Inc. 

AMO 

American  Oil   Co.    (Texas) 

NWP 

Northern   Petrochemical  Co. 

APR 

Atlas  Processing  Co. 

ASH 

Ashland  Oil,    Inc. 

OCC 

Oxirane  Chemical  Co. 

ATR 

Atlantic  Richfield  Co.,    ARCO  Chemical   Co. 
Div. 

OMC 

Olin  Corp. 

PAN 

Amoco  Production  Co. 

BFG 

B.    F.    Goodrich  Co.,    B.    F.    Goodrich  Chemical 

PAS 

Pennwalt   Corp. 

Co.    Div. 

PLC 
PPR 

Phillips   Petroleum  Co. 
Phillips   Puerto  Rico  Core,    Inc. 

CBN 

Cities   Service  Co.,    Petrochemical   Div. 

PRO 

Productol   Chemical  Co.,    Inc. 

CCP 

Crown  Central   Petroleum  Corp. 

PTT 

Petro-Tex  Chemical  Corp. 

CO 

Continental  Oil   Co. 

PUE 

Puerto  Rico  Olefins 

COL 

Collier  Carbon  6  Chemical   Corp. 

COR 

Commonwealth  Oil   5  Refining  Co.,    Inc. 

RH 

Rohm  S  Haas   Co. 

CPI 

Commonwealth   Petrochemicals,    Inc. 

CPX 

Chemplex  Co. 

SBI 

Standard   Brands   Chemical    Inudstries, 

nc. 

CPY 

Copolymer  Rubber  6  Chemical  Corp. 

SHC 

Shell  Oil   Co.,   Shell   Qiemical   Co.    Div 

CSD 

Cosden  Oil   5  Chemical  Corp. 

SHO 

Shell  Oil   Co. 

CSO 

Cities  Service  Oil  Co. 

SIO 

Standard  Oil   Co.    of  Ohio 

CSP 

Coastal   States   Petrochemical  Co. 

SKO 
SM 

Skelly  Oil   Co. 
Mobil   Chemical  Co. 

DLH 

Amerada  Hess   Corp. 

SM 

Mobil   Oil   Corp. 

DOW 

Dow  Chemical  Co. 

SNO 

SunOlin   Chemical    Co. 

DUP 

E.    I.    duPont   de   Nemours    §  Co.,    Inc. 

SNT 

Suntide  Refining  Co. 

SOC 

Standard  Oil    Co.    of  California,    Chevron 

EKX 

Eastman  Kodak  Co. ,   Texas   Eastman  Co.    Div. 

Chemical   Co. 

ELP 

El   Paso  Products   Co. 

SOG 

Charter  International  Oil   Co. 

ENJ 

Exxon  Chemical  Co.    U.S.A. 

SOI 
STY 

American  Oil   Co.    (Maryland) 
Styrochera  Corp. 

FG 

Foster  Grant  Co. ,    Inc. 

SUN 

Sun  Oil   Co. 

FRO 

Vulcan  Materials   Co.,    Chemicals   Div. 

SWC 

Shell    6  Commonwealth  Chemicals,    Inc. 

FRS 

Firestone  Tire   5   Rubber  Co.,    Firestone 

Synthetic  Rubber  §   Latex  Co.    Div. 

TID 
TNA 

Getty  Oil   Co. 
Ethyl   Corp. 

GOC 

Gulf  Oil    Corp. ,   Gulf  Oil   Chemicals 

TOG 

Tenneco  Oil   Co. 

Co.    -   United  States 

TUS 

Texas-U.S.    Chemical   Co. 

GRS 

Champlin  Petroleum  Co. 

TX 

Texaco,    Inc. 

GYR 

Goodyear  Tire  ii  Rubber  Co. 

UCC 

Union  Carbide  Corp. 

HCR 

Hercor  Chemical   Corp. 

UOC 

US  I 

Union  Oil   Co.    of  California 

National  Distillers   f,  Qiemical   Corp., 

JCC 

Jefferson   Chemical   Co. ,    Inc. 

U.S.    Industrial   Chemicals   Co.    Div. 

KPP 

Sinclair-Koppers    Co. 

Note.- 

-Complete  names   and  addresses   of  the  above   reporti 

ng  compc 

inies    are    listed   in  Table    1,    of  the   Anpe 

ndix. 

19 


CYCLIC  INTERMEDIATES 

Cyclic  intermediates  are  synthetic  organic  chemicals  derived  princi- 
pally from  petroleum  and  natural  gas  and  from  coal-tar  crudes  produced  by 
destructive  distillation  (pyrolysis)  of  coal.  Most  cyclic  intermediates  are 
used  in  the  manufacture  of  more  advanced  synthetic  organic  chemicals  and 
finished  products,  such  as  dyes,  medicinal  chemicals,  elastomers  (synthetic 
rubbers),  pesticides,  and  plastics  and  resin  materials.   Some  intermediates, 
however,  are  sold  as  end  products  without  further  processing.   For  example, 
refined  naphthalene  may  be  used  as  a  raw  material  in  the  manufacture  of  2- 
naphthol  or  of  other  more  advanced  intermediates,  or  it  may  be  packaged  and 
sold  as  a  moth  repellent  or  as  a  deodorant.   In  1972  about  46  percent  of 
the  total  output  of  cyclic  intermediates  was  sold;  the  rest  was  consumed 
chiefly  by  the  producing  plants  in  the  manufacture  of  more  advanced  interi- 
mediates  and  finished  products. 

Total  production  of  cyclic  intermediates  in  1972--34,967  million 
pounds--was  the  largest  on  record,  and  was  16.7  percent  larger  than  the  out- 
put of  29,953  million  pounds  reported  for  1971.   The  larger  output  of  cyclic 
intermediates  in  1972  reflects  the  increased  demand  by  the  chemical  products 
industries,  particularly  those  industries  that  produce  plastics  materials, 
dyes,  pigments,  and  plasticizers.   Sales  of  cyclic  intermediates  in  1972 
were  16,196  million  pounds,  valued  at  $1,434  million,  compared  with  12,971 
million  pounds,  valued  at  $1,252  million,  in  1971. 

Production  of  styrene  in  1972  was  5,941  million  pounds,  or  26.9  percent 
more  than  the  4,682  million  pounds  produced  in  1971.   Output  of  ethylbenzene 
was  5,676  million  pounds,  an  increase  of  13.9  percent  from  the  4,984  million 
pounds  produced  in  1971.   Other  intermediates  whose  production  exceeded  1 
billion  pounds  in  1972  were  cyclohexane  (2,298  million  pounds),  cumene 
(2,293  million  pounds),  p-xylene  (2,208  million  pounds),  dimethyl  tere- 
phthalate  (2,167  million  pounds),  phenol  (2,096  million  pounds),  and  tere- 
phthalic  acid  (1,929  million  pounds).   Other  large-volume  intermediates 
produced  in  1972  were  phthalic  anhydride  (933  million  pounds),  o-xylene 
(832  million  pounds),  cyclohexanone  (783  million  pounds),  isocyanates 
(702  million  pounds),  nitrobenzene  (551  million  pounds),  straight  chain 
alkylbenzenes  (524  million  pounds),  2,4  and  2,6-dinitrotoluenes  (434  mil- 
lion pounds),  aniline  (410  million  pounds),  and  monochlorobenzene  (404 
million  pounds).   The  above  17  chemicals  accounted  for  86  percent  of  the 
total  output  of  cyclic  intermediates  in  1972.   Production  of  15  of  the 
above  chemicals  increased  in  1972  compared  to  1971;  the  output  of  alkyl 
benzenes  decreased  by  4.7  percent  and  of  monochlorobenzene  by  1.3  percent. 


SYNTHETIC  ORGANIC  CHEHICALS.  1972 
TABLE  1.— Cyclic  intermediates;     U.S,  production  and  sales,  1972 


[Listed  below  are  all  cyclic  intermediates  for  which  any  reported  data  on  production  or  sales  may  be  published. 

(Leaders  (...)  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  date 
were  reported.)   Table  2  lists  alphabetically  all  cyclic  intermediates  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturers  of  each] 


Production 


Quantity 


Total 

Acetanilide,  tech 

Acetophenone,  tech 

A Ikyl benzenes^  

1-Aminoanthraquinone  and  salt 

7- (p-Aminobenzamido) -4 -hydroxy- 2-napht ha lenesulfonic  acid- 

l-Amino-2-bromo-4-hydroxyanthraquinone 

l-Araino-5-chloroanthraquinone 

l-Aniino-2,4-dibronioanthraquinone 

l-Amino-9, lO-dihydro-9, 10-dioxo-4-p-toluenesulfonamido-2- 
anthracenesulfonic  acid,    sodium  salt 

N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon- 

amide 

p- [(p-Aminophenyl)azo]benzenesulfonic  acid 

Aniline  (Aniline  oil) 

Anilinoraethanesulfonic  acid  and  salt 

o-Anisidine 

o-Anisidinoraethanesulfonic  acid 

Anisole,  tech 

Anthra[l,9-cd]pyrazol-6(2H)-one  (Pyrazoleanthrone) 

Benzaldehyde,  tech 

7H-Benz[de]anthracen-7-one  ( Ben zan throne) 

Benzoic  acid,  tech 

2-Benzothiazolethiol,  sodium  salt 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'- (2H, 2 'H)-dione 

(Pyrazoleanthrone  yellow) 

[4,4'-Bi-7H-benz|de]anthracene]-7,7'-dione 

Biphenyl 

1 , 4- Bi  s [ 1 - anthraquinony lamino ] anthraquinone 

3- Bromo-7H-benz[de] anthracene- 7-one  (5- Bromobenzan throne) - 

2-Bromo-4 ,6-dinitro aniline 

1-Chloroanthraquinone 

Chlorobenzene,  mono 

6-Chlororaetanilic  acid 

l-Chloro-2-methyl anthraquinone 

1-Chloro-S-nitroanthraquinone 

4-Chloro-3-nitrobenzenesulfonaraide 

a-Chlorotoluene  (Benzyl  chloride) 

Cinnamoyl  chloride 

Cresols,  total' 

o-Cresol 

(m,p)-Cresol 

All  other" 

Cresylic  acid,  refined' 

Cumen  e 

Cyclohexane 

Cyclohexanone 

Cyclohexylamine 

1 ,4-Diaminoanthraquinone 

2, 6-Diaminoanthraquinone 

1 ,4-Diamino-2,3-dihydroanthraquinone 

4,4'-Diamino-2,2'-stilbenedisulfonic  acid 


1,000 
pounds 
34,967,181 


524,009 
359 


724 

36 

1,014 


456 

409 

820 

686 

o 

106 

664 

195 

64 

4 

607 

1 

184 

155 

505 

9 

667 

149 

626 

114 

403,505 

6 

91 

40 

507 

80,357 


49,668 
28,292 
28,313 


54,981 

2,292,949 

2,298,394 

783,440 

104 


1,000 
pounds 

16,195,641 


1,000 
dollars 

1,433,855 


1,679 
502,995 


4,231 
14,273 


1,345,895 

2,018,404 

56,960 


1,443 
1,989 


7 

303 

4 

438 

8 

617 

7 

442 

46 

882 

60 

168 

7 

055 

1 

174 

See  footnotes  at  end  of  table. 


CYCLIC  INTERMEDIATES 


TABLE  1.— Cyclic  intermediates:     U.S.  production  and  sales.  1972— Continued 


4,5'-Dibenzamido-l,r-iminodianthraquinone 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

o-Dichlorobenzene 

p-Dichlorobenzene 

3,3'-Dichlorobenzidine  base  and  salts 

Dicyclopentadiene  (includes  cyclopentadiene) 

N,N-Di ethyl  aniline 

9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic  acid  and 

salt 

9, lO-Dihydro-9, lO-dioxo-l-anthracenesulfonic  acid  and  salt 

(Gold  salt) 

1 ,4-Dihydroxyanthraquinone  (Quinizarin) 

l,8-Dihydroxyanthraquinone(Chryazin) 

1 ,8-Dihydroxy-4,5-dinitroanthraquinone  (4,5-Dinitro 

chrysazin) 

16, 17-Dihydroxyviolanthrone  (Dihydroxydibenzanthrone) 

N,N-Dimethylaniline 

N,N-Dimethylbenzyl amine 

2, 2- Dimethyl -1 , 1 ' -bianthraquinone 

4,4'-Dinitrostilbene-2,2'-disulfonic  acid 

2, 4 (and  2, 6)-Dinitrotoluene 

Diphenyl amine 

1 ,4-Di-p-toluidinoanthraquinone 

Divinylbenzene-  

N- Ethyl aniline,  refined 

2-(N-Ethylanilinc;)ethanol 

Ethylbenzene  ^ 

N-Ethyl-N- phenyl benzyl amine 

Hydroquinone,  tech 

3-Hydroxy-2-methylcinchoninic  acid 

6-Hydroxy-2-naphthalenesulfonic  acid,  sodium  salt 

1,1'- Iminobis [4-aminoanthraquinone] 

1,1 ' -Iminodianthraquinone  (1, 1 ' -Dianthrimide) 

Isocyanic  acid  derivatives,  total 

Toluene-2,4-  and  2,6-diisocyanate  (80/20  mixture) 

Other  isocyanic  acid  derivatives 

4,4'-Isopropylidenediphenol  (Bisphenol  A) 

Leuco  quinizarin  (1 ,4, 9, 10-Anthratetrol) 

dl-p-Mentha-1 ,8-diene    (Limonene) 

Metanilic   acid (m-Aminobenzenesulfonic  acid) 

4,4'-Methylenedianiline 

p- (5-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic  acid 

3-Methyl-l-phenyl-2-pyrazolin-5-one  (Developer  Z) 

a-Methylstyrene 

Nitrobenzene 

5-Nitro-o-toluenesulfonic  acid  [S03H=1] 

5-Nitro-o-toluidine  [NH2=1] 

Nony 1 pheno 1 

1- [ (7-Oxo-7H-benz [de] ant hracene-3-yl) amino] anthra- 

quinone ■ 

Phenol,  total' 

Natural,  from  coal  tar  and  petroleum 

Synthetic,  total 

From  cumene ■ 

Other  synthetic 

1- Phenyl -1,2-propanedione,  2-oxime 

Phthalic  anhydride 

Picolines' 


Production 

Sales 

Quantity   ' 

Value 

value' 

2,000 

1,000 

1,000 

Per 

pounds 

pounds 

dollars 

pound 

55 

166 

62,386 

62,389 

7,233 

$0.12 

77,317 

70,704 

6,285 

.09 

4,612 

4,618 

5,792 

1.25 

91,267 

71,673 

2,802 

.04 

3,556 

2,639 

1,417 

.54 

249 

997 

2,095 

107 

159 

141 

8,073 

1,671 

.21 

79 

59 

90 

1.53 

38 

9,230 

433,885 

33,845 

16,981 

3,957 

.23 

86 

3,367 

2,698 

1,720 

.64 

1,866 

218 

5,675,900 

447,259 

13,812 

.03 

478 

11,779 

11,616 

9,129 

.79 

430 

637 

44 

60 

701, M8 

508,847 

156,742 

.31 

419,404 

362,876 

101,516 

.28 

282,244 

145,971 

55,226 

.38 

255,189 

77,197 

11,957 

.15 

87 

9,273 

... 

1,082 

1,888 

830 

.44 

157 

61 

43 

61 

1.42 

37  398 

26  112 

1,317 

.  .05 

551,169 

12,622 

804 

•  .06 

8,017 

397 

100,295 

40,625 

4,648 

.11 

292 

2,096,125 

1,016,215 

65,944 

.07 

44,298 

25,687 

1,772 

.07 

2,051,827 

990,528 

64,172 

.07 

1,810,884 

240,943 

238 

932,978 

634,050 

44,274 

.07 

6,416 

See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS.  F72 


TABLE  1, --Cyclic  intermediates:     U,S,  production  and  sales,  1972--Continued 


Unit 
value' 


Piper id in e 

Prop  i  oph  enone 

Salicylaldehyde 

Salicylic  acid,  tech 

Styrene,  all  grades 

Terephthalic  acid 

Terephthalic  acid,  dimethyl  ester 

1 ,4,5, 8-Tetrahydroxyanthraquinone,  leuco  derivative-- 

6,6'-Thiodimetanilic  acid 

Toluene- 2, 4 -diamine  (4-ni-Tolylenedianiine) 

4-(o-Tolyazo)-o-toluidine  CCI.  Solvent  Yellow  3) 

1 , 2,4-Trichlorobenzene 

1,3, 3-Trimethyl-A^,a-indolineacetaldehyde 

1 ,3,3-Trimethyl-2-methyleneindoline  (Trimethyl  base)- 
7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic  acid 

(J  Acid  Urea) 

Violanthrone  (Dibenzanthrone) 

o- Xylene 

p- Xylene 

All  other  cyclic  intermediates 


1,000 

pOWlds 

477 

289 

4,468 

47,095 

5,940,729 

1,928,907 

2,167,332 

54 

175 

167,902 

395 

15,552 

338 

701 

237 

489 

831,782 

2,207,556 

3,391,402 


1,000 
pounds 


163 

3,547 

9,136 

2,810,182 


55,316 


675,700 
2,102,848 
1,973,680 


1,000 
dollars 


160 

3,577 

3,708 

160,568 

50,349 


16,195 

94,816 
434,790 


Per 
pound 


'^      Calculated  from  rounded  figures. 

^   Includes  straight-chain  dodecylbenzene,  tridecylbenzene  and  other  straight-chain  alkylbenzenes .   Branched-chain 
alkylbenzenes  are  included  in  all  other  cyclic  intermediates. 

'      Includes  data  for  coke  ovens  and  gas-retort  ovens,  reported  to  the  Division  of  Fossil  Fuels,  U.S.  Bureau  of  Mines 
and  for  tar  and  petroleum  refineries  and  other  producers,  reported  to  the  U.S.  Tariff  Commission. 

''  Figures  include  (o,m,p)-cresol  from  coal  tar  and  some  m-cresol  and  p-cresol. 

^  Does  not  include  ethylbenzene  produced  and  consumed  in  continuous-process  styrene  manufacture. 


CYCLIC  INTERMEDIATES 
TABLE  2. --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972 

[Cyclic   intermediates   for  which   separate   statistics   are  given  in   table   1    are  marked  with   an  asterisk    (*);   cyclic 
intermediates  not  so  marked  do  not   appear  in  table   1   because   the   reported  data  are  accepted  in  confidence   and  may 
not  be  published.      Manufacturers'    identification  codes   shoim  below   are  taken   from  table   3.     An  x  signifies   that 
the  manufacturer  did  not   consent   to  his   identification  with  the  designated  product] 


Manufacturers'    identification    codes 
(according  to   list   in   table   3) 


Acenaph  thenequinone 

8-Acetamido-l- C4-acetamido-2-hydroxy-5-nitrophenylazo) - 
2-naphthol . 

5-Acetamido-2-aminobenzenesulfonic   acid 

3-[ C2-Acetamido-4-aminophenyl)azo]-l ,5-naphthalene- 
disulfonic   acid. 

2,2'- [(S-Acetamido-2-ethoxyphenyl)imino]diethanol 

2,2'- [ (5-Acetamido-2-methoxyphenyl) imino] diet hand 

4-Acetamido-2-hydroxybenzoic   acid 

a- Acetamido-p- toluenes ulfonamide 

*Acetanilide,   tech 

Acetic  acid,   phenyl   ester 

Acetoacetani lide 

o-Acetoacetanisidide 

Acetoacet-2 ,5-dimethoxy-4-chloroani lide 

o-Acetoacetotoluidide 

2 ' ,4' -Acetoacetoxylidide 

1 ' -Acetonaphthone 

Acetone  phenylhydrazone 

* Ace t ophenone ,   tech 

p-Acetotoluidide 

p- Ace tylbenzenes ulfonamide 

p-Acetylbenzenesulfonic   acid,   sodium  salt 

p- Ace tylbenzenesulfony lure thane 

N-Acetylsulfanilyl   chloride 

*Alkylbenzenes: 

Dodecylbenzene    (including  tridecylbenzene) : 

'Straight   chain 

Other 

Alkylphenols ,   mixed 

Alkylpiperazines,    mixed 

Alky 1 pyridines,   mixed 

a-dl-5-Allyl-6-imino-l-nethyl-5- (l-methyl-2-nentynyll  - 

barbituric  acid. 
a-dl-5-Allyl -5- (1 -methyl -2-pcntynyn-l-methylbarbituric 
acid. 

3'-Aminoacetanilide 

4'-Aminoacetanilide    (Acetyl-p-phenylenedi amine) 

2'-Aminoacetophenone 

3'  -Aminoacetoplienone 

4'-Aminoacetophenone 

5 '-Amino- 2- (p-aminoanilino)benzenesulfonic  acid 

1- Amino- 4- (3-amino-4-sulfoani lino)-9, lO-dihydro-9, 10- 
dioxo-2-anthracenesulfonic  acid. 

2- (p-Aminoanilino)-5-nitrobenzenesulfonic   acid 

3-Amino-p-anisanilide 

*1-Aminoanthraquinone   and  salt 

2-Aminoanthraquinone  and  salt 

N- (4-Amino-l-anthraquinonyl) anthrani lie  acid 


BJL. 
TRC. 

GAF. 
IPX. 

TCH. 

TCH. 

SDW. 

SDW. 

CTN,    EKT,    MRK,    SAL. 

UCC. 

FMP,    HST. 

FMP,    HST,    UCC. 

FMP. 

FMP,   HST,    t'CC. 

HST. 

CIV. 

DUP. 

ACP,    CLK.   SKO,   UCC. 

EK. 

LIL. 

LIL. 

LIL. 

ACY,    CTN,   MRK,    SAL. 


BRP,    CO,   MON,    I'CC,    WTC. 

CO,    SOC,    UCC.    UCC. 

PRD. 

AIP. 

UCC. 

LIL. 

LIL. 


AAP. 

CAP, 

TRC. 

EK. 

CTN. 

EK. 

TRC, 

YAW. 

TRC. 

TRC. 

PCW. 

AAP, 

ACY. 

MAY, 

SDC, 

TRC 

ACY, 

GAF. 

GAF. 

See    footnotes    at   end  of  table 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2. --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported. 

IDENTIFIED  BY  MANUFACTURER,  1972--CONT I NUED 


N-(5-Amino-l-anthraqiiinonyl)anthraniUc   acid 

4-Aminoantipyrine '' 

6-Amino-3,4'-azodibenzenesulfonic   rcid    (C.I.    Acid 

Yellow  9) . 
Aminoazoxylene  toluene  homologues   

p-Aminobenzamide 

1- Amino- 4-benzaiiiidoanthraquinone 

l-Amino-S-benzamidoanthraquinone 

7_ [p- (p-Aminobenzamido)benzamido]-4-hydroxy-2- 

naphthalenesulfonic   acid. 
*7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic 

acid. 

2-Amino-p-benzenedisulfonic   acid   [SOjH^l] 

o-Aminobenzene thiol 

4-Aminobenzenethiosulfonic   acid,    sodium  salt 

2 - Ami nobenz imidazole 

4-Aminobenzophenone 

2-Amino-6-benzothiazolecarhoxylic   acid 

2-(m-Aminobenzoyl)-o-acetanisidide 

N-(4-Amino-3-brorao-l-anthraquinonyl)-p-toluidine 

sulfonic   acid. 
Stand  8)-Amino-8(and  5)-bromo-9,10-dihydro-9,10-dioxo- 
l,6(and  1 ,7)anthracenedisulfonic   acid. 

*l-Amino-2-bromo-4-hydroxyanthraquinone 

1- Amino- 2-bromo-4-p-toluidinoanthraquinone 

*l-Amino-5-chloroanthraquinone 

l-Amino-8-chloroanthraquinone 

2 -Amino- 1 - ch 1 oroanth  raquinone 

2-Amino-3-chloroanthraquinone 

4- Amino-6-chloro-m-benzenedi  sulfonamide --- 

4-Amino-6-chloro-m-benzenedi sulfonamide  hydrochloride 

2-Aiiiino-6-chlorobenzothiazole  hydrochloride 

o-(3-Amino-4-chlorobenzoyl1benzoic   acid 

1- Amino- 2 -chloro-4-hydroxyanthraqui none 

3-Amino-5-chloro-2-hydroxybenzenesulfonic   acid 

2-Amino-4-chlorophenol 

l-(2-Amino-5-chlorophenyl)-l-phenylmethylenimine 

2-Amino-6-chloropyrazine 

3-Amino-6-chloropyridazine 

2-Amino-5-chloro-p-toluenesulfonic   acid    [Sn3H=l] 

6-Amino-4-chloro-m-toluenesulfonic   acid    [S03H=1] 

2-Amino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

1- Amino- 2 , 4- di  ch 1 oroanthraquinone 

2-Amino-4,6-dichloro-5-cresol 

4-Amino-2,6-dichorophenol  hydrochloride 


Manufacturers'    identification   codes 
(according  to   list    in   table   31 


DUP. 

VPC. 

ACY, 

CMC 

ACS. 

ICC, 

SDH 

(lAY, 

TRC 

ACY, 

TRC 

CMC. 

CMC,    GAP,    TRC,   VPC. 

DUP,    TRC. 

PIS,    FMT. 

SDC. 

EK. 

DUP. 

DUP. 

GAP. 

TRC. 

TRC. 

AAP,    DUP,    UN,    VPC. 

ACS,   TRC. 

ACY,    HAY,    TRC. 

DUP. 

DUP,    ICI. 

GAP. 

ABB. 

ABB. 

DUP. 

AAP. 

TRC. 

TRC. 

SW. 

ABB. 

ACY. 

ACY. 

HSC. 

DUP,    HSC. 

TRC. 

AAP,    DUP,    HN,   TRC,   VPC. 

TRC. 

EK. 

EK. 


CYCLIC  INTERMEDIATES 
TABLE  2,— Cyclic  intermediates  for  which  U,S,   production  or  sales  were  reported, 

IDENTIFIED  EY  MANUFACTURER,  1972— CONTINUED 


*l-Aiiiino-9,10-dihydro-9, 10-dioxo-4-p-toluenesulfonaiiiido- 

2-anthracenesulfonic  acid,   sodium  salt. 
5-Amino-4,5 '-dihydroxy-3,4' - [(2-methoxy-5-raethyl-p- 

pheny lene )bis(azo)]-di- 2, 7-naphthalenedi sulfonic  acid, 

5 ' -benzenesulf onate . 

3-Amino-9-ethylcarbazole 

N- C2-Aminoethyl)-N-ethyl-m-toluidine 

3-Amino-a-ethylhydrocinnamic  acid 

N- [2- C4-Amino-N-ethyl-m-toluidino)ethyl]methane- 

sulfonamide,   hemisulfate. 

N-Aminohexamethyleneimine 

4- Amino- 5-hydroxy- 2, 7-naphthalenedi sulfonic   acid, 

benzenesulfonate. 
4-Amino-5-hydroxy-2 ,7-naphthalenedisulfonic  acid 

(H  acid),   monosodium  salt. 
4-Araino-3-hydroxy-l-naphthalenesulfonic  acid    (1,2,4- 

acid) . 
6-Amino-4-hydroxy-2-naphthalenesulfonic  acid   CGarama 

acid],    sodium  salt. 
7-.iVmino-4-hydroxy-2-naphthalenesulfonic   acid    (,J   acid)  , 

sodium  salt. 
2- (2- Amino- 5-hydroxy- 7-sulf 0-1 -naph thy lazo) -5 -nit ro- 

benzoic  acid. 
4-Amino-3-(6-methanesulfoaminoethyl)-N,N-diethylaniline 

hydrochloride. 
*N- (4- Amino- 3- me thoxy-1-anth raquinonyl)-p- toluenes ulfon- 

amide. 

5-Amino-6-raethoxy-2-naphthalenesulfonic  acid 

4-Amino-5-methoxy-o-toluene  sulfonic  acid 

m-  [(4-Amino-3-methox\'phenyl)azo]benzenesulfonic  acid 

8- Amino- 6-methoxyquino line 

4-  [(4-AjTdno-5-methoxy-o-tolyl)azo]-5-hydroxy-2  ,7- 
naphthalenedisulfonic  acid,  benzenesulfonate. 
3- [ (4- Amino- 5 -methoxy-o-tolyl )azo]-l,5-naDh thalenedi sul- 
fonic  acid. 
7- [ (4- Amino-S-methoxy-o-tolyl) azo] -  1 , 3-nanhthalenedi - 

sulfonic   acid. 
4-.%nino-4'-(3-methyl-S-oxo-2-pyrazolin-l-yl)-2,2'-stil- 

benedisulfonic   acid. 

2 -. Ami no- 3-me thy 1 pyridine 

2-Amino-6-methylpyridine 

2-Amino-4-methylpyrimidine    C2-Amino-4-raethyl-l ,3- 

diazine) . 

2- Amino- 4-  (methylsulfonyl) phenol . 

2-Amino-5-methyl-l ,3,4-thiadiazole 

4-Aminonaphth [2 ,3-c]acridan-5 ,8, 14-trione 

2 - Amino- 1 ,5 -naph thalenedi sulfonic  acid 

3-Amino-l ,5-naphthalenedisulfonic   acid    (C  acid) 

3-Amino-2 ,7-naphthalenedisulfonic   acid 

6-Amino-l ,3-naphthalenedisulfonic  acid    (Amino   I    acid) 

7-Amino-l ,3-naphthalenedisulfonic   acid    (Amino  G   acid) 

l-Amino-2-naphthalenesulfonic   acid    (o-N'aphthionic   acid)- 

2-Amino-l-naphthalenesulfonic   acid    (Tobias    acid) 

4-Amino-l-naphthalenesulfonic  acid    (Naphthionic   acid) 

4-Amino-l-naphthalenesulfonic  acid,    sodium  salt 

4(and  5)-Amino-l-naphthalenesulfonic  acid 


Manufacturers'    identification  codes 
(according  to  list   in  table   3) 


AAP 

DUP,  GAF. 

TRC 

SDC 

WAY 

SDW 

WAY 

F^^p 

TRC 

ACS 

ACY, 

GAF.  TRC. 

TRC. 

HN, 

TRC. 

TRC. 

EKT. 

AAP, 

DUP,  GAF. 

TRC. 

ACS. 

DUP, 

TRC. 

PD. 

TRC. 

TRC. 

TRC. 

TRC. 

RIL. 

RIL. 

ACY. 

TRC. 

ACY. 

DUP. 

ACY, 

SDH. 

TRC. 

TRC. 

UN, 

TRC. 

DUP, 

TRC. 

DUP. 

ACY, 

SW. 

ACY, 

DUP. 

ACY, 
TRC. 

DUP. 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2. --Cyclic  intermediates  for  which  U.S,   production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  code 
(according  to   list   in   table   5) 


-Amino-2-naphthalenesulfonic    acid    (Broenner's   acid) 

-Amino-l,3,6-naphthalenetrisulfonic   acid 

-Amino-l,3,6-naphthalenetrisulfonic   acid    (Koch's   acid)- 

-Amino-2-naphthol 

- (4-Amino-l-naphthyla:o)-4- (1 , 1 ,3,3-tetramethylbutyl) 
phenol . 

-Amino-4-nitroacetani lide 

-Amino-5- (m-nitrobenzamido) -p-toluenesulfonic   acid 

-Amino-5-nitroben2enesulfonic   acid    [S03H=1] 

-  Amino  -4'»n  itro-3-niethoxyazobenzene 

-  2- Amino- 1- (p-nltrophenyl) -1 ,3-propanediol 

-2-Amino-l-(p-nitrophenyl)-l ,3-propanediol 

-Amino-4'-nitro-2,2'-stilbenedisulfonic   acid 

- Amino- 5-nitrothia:ole 

' -Aminooxani lie  acid 

'-Aminooxanilic   acid 

-Arainopenicillanic  acid 

-Aminophenol 

-(p-Aminophenoxy)ethanol   hydrochloride 

- [ (p-Aminophenyl) azojbenzenesulfonic   acid 

- [(p-Aminophenyl)azo]benzenesulfonic   acid 

- [(4-Aminophenyl)azo]-l ,3-naph thai enedi sulfonic  acid — 

-Amino- 8- (phenylazo)-2-naphthol 

-Amino-5-(phenylazo)-2-naphthol 

- [ (p-Aminophenyl )azo] - 1-naph thy 1  amine 

- [(p-Arainophenyl)azo] salicylic  acid 

-[ (p-Aminophenyl) azojsalicylic   acid,    sodium  salt 

,2 '-(m-Aminophenylimino)diethanol ,   diacetate  ester 

- (p-Aminophenyl) -6 -me thy Ibenzothiazole 

-  (p-Aminophenyl)  -6-metliyl-7-ben20thia2olesulfonlc  acid 
and  salt. 

- (m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic   acid-- 

- Amino- 2-propoxybenzoic  acid 

- ( Ami nopropyl)cyclohexyl amine 

- Ami nopyri dine 

-Aminopyridine 

- Ami nopyrimi dine 

-Aminorhodanine 

-Aminosalicylic  acid 

-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic  acid 

-Ami no- 4- (1, 1,3,3- tetramethylbutyl ) phenol 

-Amino- 4- (1,1 ,3,3-tetramethylbutyl) phenol  hydro- 
chloride. 

-Aminothiazole 

-Amino-p-toluamide 

-Amino-p-toluenesulfonamide 

-Amino-m-toluenesulfonic   acid    [SOjHsl] 

-.Amino-m-toluenesulfonic   acid    [SOjHsl] 

-'\mino-o-toluenesulfonic   acid    [50^11=1] 

- Amino- 2-p-toluidinobenzenesulfonic   acid 

- (4-Amino-m-tolyla2o)benzenesulfonic  acid 

- [ (4- Amino-o-tolyl)azo]-l,5-naphthalenedi sulfonic  acid- 
- [ (4- Amino-o-tolyl)azo]-l,3-naphthalenedi sulfonic   acid- 


SNA, 

TRC. 

DUP. 

ACS. 

TRC. 

r;AF. 

SDC. 

GAF. 

ACS, 

GAF,   TRC 

SDC. 

PD. 

PD. 

UN, 

TRC. 

PCW. 

cun, 

TRC. 

DUP , 

VPC. 

TRD. 

•1AL. 

GAF. 

TRC. 

ACY, 

DUP,    TRC 

TRC. 

ALL. 

ALL. 

ACS. 

TRC, 

VPC. 

ACS. 

DUP, 

TCH. 

DUP. 

DUP, 

TRC. 

TRC, 

VPC. 

SDW. 

ABB. 

NEP, 

RIL. 

RIL. 

ACY. 

EK. 

MLS, 

TRC. 

GAF. 

GAF. 

GAF. 

ACY, 

MRK. 

SDH, 

X. 

SDW. 

ACY, 

DUP. 

DUP. 

use. 

TRC. 

TRC. 

TRC. 

TRC. 

CYCLIC  IiJTERMEDIATES 
TABLE  2. --Cyclic  intermediates  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to  list   in  table  3) 


2-Ainino-3,5-xylenesulfonic   acid    [S03H=1] 

5-Amino-2,4-xylenesulfonic   acid 

•Aniline    (Aniline  oil) 

Aniline  hydrochloride 

2  '-Anilino-6-diethylaniino-5-methylf  luoran 

2-Anilinoethanol 

7-Anilino-4-hydroxy-2-naphthalenesulfonic   acid    (Phenyl 
J    acid) . 

*Anilinomethane5Ulfonic   acid  and  salt 

8-Anilino- 1-naphthalenesulfonic  acid   (Phenyl  peri   acid)- 

8-Ani lino- 1-naphthalenesulfonic   acid,    magnesium  salt 

m-Ani linophenol 

D-Ani linophenol 

o-Anis aldehyde 

m-Anisidine 

*o-.Anisidine 

p-Anisidine 

*o-Anisidinoniethanesulfonic  acid 

*Anisole,    tech 

3- (o-Anisyla2o)benzenesulfonic  acid,   sodium  salt 

Anthracene 

Anthranilic  acid   (o-Aminobenzoic  acid)' 

*Anthra[l,9   cd]pyrazol-6(2H) -one    (Pyrazoleanthrone) 

Anthraquinone  ,    100°s 

1 ,5-Anthraquinonedisulfonic  acid 

1 , 8- Anthraquinonedi sulfonic   acid 

1,1'-  [1,5 (and    1 ,8) -Anthraquinonylenediaminolbis- 
naphth  [2 ,3-c]acridan-5,8, 14-trione. 

N,N' - (1 ,5-Anthraquinonylene)dianthrani lie  acid 

N,N'- (l,5-Anthraquinonylene)dioxamic   acid 

(l-Anthraquinonyl)-l , 2 -hydrazinedi sulfonic  acid, 
disodium  salt. 

4' ,4' ' '-Azobis [4-biphenylcarboxylic   acid] 

Barbituric  acid,    sodium  derivative 

*Benzaldehyde,   tech 

l-Benzamido-4-bromoanthraquinone 

1 -  Ben z ami  do- 4 -chloro anthraquinone 

1-Benzamido-S-chloroanthraquinone 

4-Benzamido-5-hydroxy-2,7-naphthalenedisulfonic  acid 

7-Benzamido-4-hydroxy-2-naphthalenesulfonic   acid 

Benzani lide 

Benz (a) anthracene- 7,1 2- di one 

*7H-Benz [de] anthracen-7-one    (Benzathrone) 

m-Benzenedisulfonic   acid 

Benzenesulfonamide 

Benzenes ulfonic   acid 

Ben  zenesu 1 f ony 1   chloride 

1,2,4 ,5-Ben2enetetracarboxylic- 1,2, : 4, 5 -di anhydride 

1,2,4-Benzenetricarboxylic   acid,    1 ,2-anhydride    (Tri- 
mellitic  anhydride). 

Benzhydrol    (Diphenylmethanol) 

Benzidine  hydrochloride   and  sulfate 


SDH. 

DUP. 

ACS, 

ACY, 

DUP, 

FST, 

MAL, 

MOB,  RUC,  USR 

ACY, 

EK. 

SDH. 

TCH. 

CMC, 

TRC. 

ACS, 

ACY, 

ATL 

DUP, 

TRC, 

VPC. 

DUP, 

SDC. 

EK. 

GAP. 

SDC. 

ASL. 

EK. 

AAP, 

pi  IP, 

x. 

DUP, 

MON. 

AAP, 

ATL, 

GAP 

TRC, 

VPC. 

CTN, 

DUP 

GIV 

LIL. 

ACS. 

EK. 

DUP, 

sw. 

DUP, 

GAP, 

TRC 

TRC. 

CMG. 

CMC. 

DUP. 

GAP, 

TRC. 

GAP, 

SW. 

DUP, 

GAP. 

DUP, 

TRC. 

ABB. 

BPC, 

m. 

MNR, 

VEL. 

AAP. 

GAP. 

MAY, 

TRC. 

TRC. 

TRC. 

DUP. 

EK. 

MP, 

ACY, 

DUP 

GAP, 

ICI, 

MAY,  SDC,  TRC 

KPT, 

UPF. 

NES. 

NES, 

UPF. 

NES. 

DUP, 

PCR 

ACC. 

PD, 

UOP. 

ACS, 

LAK. 

See   footnotes    at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2,— Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--CoNTINUED 


Manufacturers'    identification   codes 
(according  to    list   in   table   3) 


Benzidine   sulfate,   purified 

*Ben2oic   acid,    tech   

Benzoin 

Benzoinisobutyl   ether 

a- Benzoin  oxime 

Benzonitrile 

*2-Ben20thiazolethiol   sodium  salt 

p-Benzoquinonedi oxime 

IH-Benzotriazole 

2H-3,l-Benzoxazine-2,4(lH)-dione 

o-Benzoylbenzoic   acid 

Benzoyl    chloride 

N-Benzylacetamide 

Benzyl amine 

4- (Benzyl ami no) - 6- ch loro-m- ben zenedi sulfonic  acid 

5-  [4-N-Benzylaniino-N-methylphenylazo]  -l,2,4-tria20le 

p- (Benzyl  ami no) phenol 

Benzyl    chloro formate 

4-Benzyl-6-chloro-3-keto-7-sulfamyl-l ,2 ,4-ben2ylthia- 
diazine-l,l-dioxide. 
1- Benzyl- 4 ,5-dimethyl-6- (p-methoxybenzyl) -1 ,2,3,6-tetra- 
hydropyridine   oxalate. 

Benzyl  disulfide 

5- ( Ben zy 1 ethyl amino) -o-toluenesulf on ic   acid 

N-Benzyl-N-ethyl-m-toluidine 

3-Benzyl-l,2,3,4,5,6-hexahydro-8-hydroxy-cis-6, 11- 
dimethyl-2 ,6-methano-5-benza20cine  hydrobromide . 
6-Benzylidineaminopenicillanic   acid,    tertiary 
octylamine   salt. 

4,4'- Benzyl idenedi-o-toluidine 

4,4'-Benzylidinedi-2 ,5-xylidine 

Ben zyli dene  phthalide 

p- (Ben zyloxy) phenol 

l-Benzyl-4-phenylisonipecotic   acid 

l-Benzyl-4-phenylisonipecotonitrile 

Benzyltrimethylajnmonium   chloride 

Ben zyltri methyl  ammonium  hydroxide 

Benzyltrimethylammonium  methoxide 

*[3,3'-Bianthra[l,9-cd]pyra2ole]-6,6'-(2H,2'H)dione 
(Pyrazoleanthrone  yellow) . 
[3,3'-Bi-7H-benz[de]anthracene]-7,7'-dione 

* [4,4 '-Bi-7H-ben-[de] anthracene] -7, 7 '-dione 

l,l'-Bi-2-naphthol 

*Biphenyl 

2,2'-Biquinoline 

Bis-p-aminocyclohexylme thane 

*  1,4- Bis [1- an thraquinonyl amino] anthraquinone 

1,4-Bis [l-anthraquinonylaminojanthraquinone   and    1,4-Bis 
[5-chloro-l-anthraquinonylamino]anthraquinone    (mixed) . 

2,6-Bis(p-azidobenzylidene)-4-methylcyclohexanone 

Bis(chlorosulfonyl)phthalocyaninedisulfonic  acid,   copper 
derivative. 


UK,  HN,  KLM,  HON,  PFZ.  VEL. 


BPC. 

BPC. 

RSA. 

VEL. 

ACY, 

GYR 

USR,    X 

SDC. 

FHT 

SW. 

SW. 

ACY, 

GAP 

HK, 

GAP, 

VEL. 

SDW. 

ARS, 

MLS 

ABB. 

TRC. 

SDW. 

CCW. 
ACS. 

ACS,  DUP. 
SDW. 

TRn. 

ACY. 

ACS. 

LIL. 

EK. 

SDW. 

SDW . 

MLS. 

MLS. 

MLS. 

DUP,  GAP,  TRC. 

DUP. 

ACY,  DUP,  ICI,  MAY. 

EK. 

CUE,  DOW,  GOC,  MON,  SNT. 

EK. 

DUP. 

ACY,  DUP,  GAP,  MAY,  TRC. 

TRC. 

WAY . 
TRC. 


See  footnotes  at  end  of  table. 


I 


CYCLIC  INTERMEDIATES 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED    BY   MANUFACTURER^    1972--CoNTINUED 


Manufacturers'   identification  codes 
(according  to   list    in   table   3) 


4,4'-Bis  [diethylaiiiino]benzhydrol   salt,   2,7-naphthalene- 

disulfonic  acid,   mixture. 
4- Bis  [  (p-diethylaininophenyl)meth\'l]-2  ,7-naphthalene- 

disulfonic   acid,    leuco   fonn. 

4 ,4' -Bis [dimethylaminojbenzhydrol    (Michler's  hydrol) 

4,4 '-Bis (dime thy 1  amino) ben ihydrol ,disulfinate 

4,4'-Bis [dimethylamino]benzophenone    (Michler's   ketone)-- 
Bis  [p- (diniethylamino)phenyl]methanesulfoni  c   acid   and 

salt. 

3,3' -Bis  [3'  ,3'-(l'-ethyl-2'-niethyi;)indolyl]phthalide 

3'- [Bis (2-hydroxye thy 1) amino] acetanilide 

3' - [Bis (2-hydroxyethyl) amino] -p-acetoaniside 

3'- [Bis (2-hydroxyethyl) araino]benzanilide,  diacetate 

ester. 
3'- [Bis (2-hydroxye thy 1) amino] methanesulfoanilide, 

diacetate  ester. 

4,4 '-Bis  (p-methoxyphenyl')-3-hexanone 

1,4-Bis [2- (4-methyl-5-phenyloxazolyl) jbenzene  (Dimethyl 

POPOP) . 

Bis- (o-nitrophenyl) sulfide 

1,4-Bis [2-(5-phenyloxazolyl))benzene    {P0P0P1 

2- Bromoace t  ophenone 

p-Bromoaniline 

p-Bromoanisole 

* 3- Bromo-7H-benzfdel anthracene- 7- one    (3-Bromo- 

benzan throne) . 

Bromobenzene,   mono 

p-Bromobenzenesulfonyl   chloride 

p-Bromobenzhydrol 

p-Bromobenzoic   acid 

4- Bromob  en  z  ophenone 

Bromoch 1 oroben  zene 

6-Bromo-5-chlorobenzoxazolone 

*2-Bromo-4,6-dinitroaniline 

Bromof lucres  ce  in 

3-Bromo-2-hydroxy-4 ,4 ,5 ,5-tetramethyl-2-cyclopentene- 

1-one. 

l-Bromo-4-(methylajnino)anthraquinone 

6-Bromo-3-methyl-7H-dibenz[f ,ij ]isoquinoline-2,7- (3H)- 

dione. 

3- (Bromome thy 1 ) thi  ophene 

l-Bromonaphthalene 

2-Bromo-4' -nitroacet ophenone 

p-Bromophenol 

(p - Bromoph eny 1) ace tonit rile 

4- Bromo- 1 -ph  th  alami  dopen t ane 

a-Bromotoluene 

m-Bromotoluene 

p-Bromotoluene 

2 - Bromo- 1 , 3 , 5- 1  ri  ethy Iben  zene 

p-Butoxybenz aldehyde 

p-Butoxyphenol 

4- [3- (p-Butoxyphenoxy)propyl]morpholine 

1 - ( Buty 1  amino) an thraquinone 

p- Butyl  aniline 

3- (N-Butylanilino)propionitrile 


SDH, 

SW. 

SW. 

DSC, 

DUP, 

SDH 

ACS. 

SDH. 

GAP. 

TCH. 

DUP, 

TCH. 

LIL. 

ARA. 


ARA. 
EK. 


OPC. 

ACY,    DUP,   GAP,   MAY,   TRC. 


PD. 
DOW. 


AAP,    HST,    SDC,  TRC. 
ICC. 


AAP,    EDO. 
AAP. 

SOW. 

EK. 

GAP. 

EK. 

BPC. 

PD. 

EK. 

EK. 

BPC,    EK. 

DUP. 

EK. 

ABB. 

ABB. 

AAP. 

DUP. 

TCH. 


552-743  O  -  74  -  3 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2. --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972~CoNTINUED 


Manufacturers'    identification   codes 
(according   to   list   in   table   3) 


2-tert-Butylanthraquinone 

p-tert-Butylhenzaldehyde 

n - Buty Ibenzene 

sec-Butylbenzene 

tert- Buty Ibenzene 

p-tert-Butylbenzoic   acid 

2-tert-Butyl-p-cre5  0l 

6-tert-Butyl-iii-cresol 

Cn- Buty Icyclopentadienyl) eye lopentadienyl iron 

2 '-tert- Buty 1-4' ,6 '-dimethylacetophenone 

4 -Butyl -a- (dimethyl  amino) -o-cresol 

2-tert-Butyl-4-ethylphenol 

N^- Buty  l-4-methoxyiiiet  anil  amide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol 

p- sec- Buty Iphenol 

o- 1  ert - But y Ipheno 1 

p- tert- Buty Iphenol 

tert- Buty Is tyrene 

p- tert - Buty Itoluene 

5- tert- Buty 1-1, 2, 3- trimethy Ibenzene 

5- tert- Buty 1-m- xylene 

6-tert-Butyl-2,4-xylenol 

d-10-Camphorsulfonic  acid 

Camphosulfonic  acid 

Carbazole ,   refined 

1- (4-Carbonyl-o-anisyl)-3-raethyl-3- (2-sulfoethyl) 
triazene . 

4,4'-Carbonylbis    [phthalic  anhydride] 

6 -Carboxy fluorescein 

[(o-Carboxyphenyl) thio]ethylmercury 

Cedrene 

2 '-Chloroacetoacetanilide 

2'-Chloroacetophenone 

3' -Chloroacetophenone 

4'-Chloroacetophenone 

4'-(Chloroacetyl)acetaniline 

2'-Chloroacetyl-2 , 6- dime thy ani line 

9-Chloroacridine 

m-Chloroani line 

o-Chloroaniline 

p-Chloroaniline 

3-(o-Chloroanilino)propionitrile 

5-Chloro-o-anisidine    [NH2=1]    (4-Chloro-o-anisidine 

[0CH3=1]). 
5-Chloro-o-anisidine  hydrochloride 

*l-Chloroantliraquinone 

2-Chloroanthraquinone 

o-Chlorobenzaldehyde 

p-Qnlorobenzaldehyde 

4- (p-Chlorobenzamido)anthraquinone-l,2-acridone 

Chloro-7H-benz[de]anthracen-7-one    (Chlorobenzanthrone) - 

*Ch 1 oroben  zene ,   mono 

p-Chlorobenzenesulfinic  acid 

p-Chlorobenzenesulf on amide 

p-Chlorobenzenesulfonic  acid 

o-Chlorobenzoic   acid 

2-Chlorobenzoxazole 

7-Chlorobenzo[b]thiophen- 3(210 -one 

5-Chloro-2-benzoxazolinone 

o-(p-Chlorobenzoyl) benzoic  acid 


DUP. 
GIV. 
PLC. 
PLC. 
EK,   MTR,    PLC,    UOP. 

sue. 

ACY. 

KPT,    PRD. 

ARA. 

GIV. 

RH. 

ACY. 

ALL. 

GIV. 

DOW,   IN A. 

DOW. 

IN  A. 

DOW,    PRD,    SCN,    UCC. 

DOW. 

GIV,    SHC. 

GIV. 

GIV. 

PIT. 

OTC. 

KF. 

SDC. 

GAF. 

PCR. 
EK. 
LIL. 
GIV. 
FHP,    HST. 


LIL. 

DUP. 

SDW. 

EK. 

DUP,    GAF. 

DUP,   MON,   USR. 

DUP,   MON. 

DUP,   TCH. 

ALL. 


GAF. 

ACY, 

ACY, 

HN,    [ 

HN. 

GAF. 

ACY, 

ACS, 

TRC. 

ACY. 

HTR, 

HN. 

EK. 

ACS. 

SW. 

ACY. 


GAF,   MAY,   TRC. 
GAF. 


DOW,    DVC,   HK,   MON,   MTO,    PPG,    SCC. 


CYCLIC  INTERMEDIATES 
TABLE  2, —Cyclic  intermediates  for  which  U.S,  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list   in  table   3) 


p-Chlorobenzoyl   chloride 

4,4'-  (o-Chlorobenz>'lidene)di-2,5-xylidine 

Chloro(p-chlorophenyl)pheny  line  thane 

Chlorocyclohexane 

4-Chloro-2-cyclopentylphenol 

l-Chloro-2 ,5-diethoxy-4-nitrobenzene 

2-Chloro-N,N-diethyl-4-nitro aniline 

2-Chloro-3' ,4'-dihydroxyacetophenone 

2-Chloro-l ,4-dihydroxyanthraquinone 

4' -Chloro-2 ' ,5 ' -dimethoxyacetoacetanilide 

5-Chloro-2 ,4-dimethoxyani line 

[(4-Chloro-2,5-diniethylphenyl)thio]  acetic  acid 

1- Chloro-2, 4- dinitrobenzene    (Dinitrochlorobenzene) 

5-C]iloro-4,6-dinitrobenzenesulfonic  acid 

4-Chloro-3, 5-dinitrobenzenesulfonic   acid,    potassium  salt- 

4-Chloro-5,5-dinitrobenzoic   acid 

3- Chlorodi phenyl amine 

Ch 1 o rod iphenylme thane 

5-Chloro-2,4-disulfonyl- (N-benzyl)ani line 

N-(2-Chloroethyl)-4- (2-chloro-4-nitrophenylazo)-N-ethyl- 
aniline. 

4- [ (2- Chloroethyl) ethyl amino] -o-tolualdehyde 

4- [ (2- Ch 1 oroe thy 1) ethyl  amino ]-o-tolui dine 

p- [( 2- Chloroethyl) methyl  amino] benzaldehyde 

l-Chloro-3-f luorobenzene 

Chloroformic  acid,   benzyl   ester 

Chloroformic  acid,   phenyl   ester 

3' -Chloro-4'-hydroxyacetophenone 

3-Chloro-4-hydrox>'phenylacetothiomorpholide 

7-Chloro-4-hydroxyquinidine 

7-Chloro-4-hydroxyquinidine  hydrochloride 

3-Chloro-4-hydroxyquinoline-3,4-carbonic   acid 

4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide 

4-Chlorometanilic   acid 

5-Chlorometani lie   acid 

*6-Chlororaetanilic   acid 

N- [(S-Chloro-2-methoxyphenyl)azo]5arcosine 

p- (Chloromethyl)anisole 

*l-Chloro-2-methylanthraquinone 

6-Chloro-4-methylbenzo[b]thiophene-2-ol 

a-Chloromethylnaphthalene ,   crude 

4-Chloro-N-methyl-3-nitrobenzenesulfonamide 

Chloromethylphenyl    ether 

2-Chloro-5- (N-methylsulfamoyl) sulfanilamide 

5-Chloro-2-CN-methylsulfonyl)-4-sulfarayl-N-benzylani line- 

Chloronaphthalenes 

2-Chloro-4-nitroaniline    (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline    CP"Chloro-o-nitroaniline) 

*l-Chloro-5-nitroanthraquinone 

l-Chloro-2-nitrobenzene    CChloro-o-nitrobenzene) 


HN. 

GAF. 

OPC,   UOP. 

ACY. 

DOW. 

GAF. 

DUP. 

SDW. 

HSU. 

PCW. 

PCW. 

ACS. 

DUP,    SDC. 

TRC. 

X. 

GAF. 


GAF. 

GAF. 
.WP. 
TRC. 
F.K. 
CTN. 
CTN. 
ABB. 
ABB. 
i       PD 


PD. 

SDH. 

TRC. 

DUP. 

ACS. 

AAP,    GAF,   TRC. 

ATL. 

SDW. 

ACY,    DUP.   TRC. 

ACY. 

BPC. 

TRC. 

BPC. 

ABB. 

ABB. 

KPT. 

DUP. 

DUP. 

ACY,    MAY,    TRC. 

DUP,    r!ON. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification   codes 
(according   to   list    in   table    51 


l-Chloro-3-nitrobenzene    (Qiloro-m-nitrobenzene) 

l-Chloro-4-nitrobenzene    (Chloro-p-nitrobenzene) 

2-Chloro-5-nitrobenzenesulfuric   acid 

*4-Chloro-3-nitrobenzene sulfonamide 

4-Chloro-3-nitrobenzenesulfonanilide 

2-Chloro-5-nitrobenzenesulfonic  acid 

2-Chloro-5-ni trobenzenesulfonic  acid,    sodium  salt 

4-Chloro-3-nitrobenzenesulfonic   acid 

4-Chloro-3-nitrobenzenesulfonyl   chloride 

2-Chloro-4-nitrobenzoic  acid 

2-Chloro-5-nitrobenzoic  acid 

2~Chloro-5-nitrophenyl  methyl   sulfone 

4-Chloro-3-nitrophenyl  methyl   sulfone 

2-Chloro-4-nitrotoluene 

4-Chloro-2-nitrotoluene 

o-Chlorophenol 

p-Chlorophenol 

2-Chlorophenothiazine 

(p-Chlorophenyl)acetonitrile 

4-Chloro-a-phenyl-o-cresol 

4-Chloro-o-phenylenediamine 

2-Chloro-l , 3-phenylenedi amine- S- sulfonic  acid 

2,2 '- fn-Chlorophenylimino)diethanol 

2,2 ' - (m-Chlorophenyl imino)diethanol ,    diacetate   ester 

2- (o-Chlorophenyl)-2- (methylamine)cyclohexanone 

3- to-Chlorophenyl) -S-methyl-4-isoxazolecarboxylic  acid , 
acid  chloride. 

1-  (o-Chloropl"ienyi)-3-methyl-2-pyrazolin-5-one- 

1-  (p-Chlorophenyl}-3-methyl-2-pyrazolin-S-one 

p-Chlorophenyl   methyl   sulfone 

2-Chloro-4-phenylphenol 

o-Chlorophenylphthalimide,    potassium  salt 

4-Chlorophthalic  acid 

3-Chloropropenylbenzene    CCinnamyl    chloride-) 

1- (3-Chloropropyl)-4-methylpiperazine 

7-Chloro-4-quinolinol 

4-Chlororesorcinol 

5-Chlorosal icy aldehyde 

Chlorostyrene,   mono 

2-Chloro-5-sulfamoylbenzoic   acid 

2-Chlorothiophene 

p-Chlorothiophenol 

m-Chlorotoluene 

o-Chlorotoluene 

p-Chlorotoluene 

*a-Chlorotoluene    (Benzyl   chloride) 

3-Chloro-o-toluidine    [NHj=l] 

3-Chloro-p-toluidine    [NHj=l] 

4-Chloro-o-toluidine    [NHj=l]    and  hydrochloride 

5-Chloro-o-toluidine    [NH   =1]    (4-Chloro-o-toluidine 
[CH3  =  1]). 

5-Chloro-o-toluidine  hydrochloride    [Nllj  =  l] 

N-  [  (5 -ailoro-o-tolyl)azo]sar cosine 


DUP. 

DUP, 

MON. 

TRC. 

MP, 

DUP, 

GAF,    ICC,   TRC 

TRC. 

ACS, 

TRC. 

DUP. 

ACS, 

GAF, 

TRC. 

AAP, 

SDC. 

RSA, 

SAL. 

TRC. 

TRC. 

TRC. 

DUP. 

DUP. 

DOW, 

MON. 

DOW, 

MON. 

SK. 

OPC, 

UOP. 

flON. 

FMT. 

SDC. 

TCH. 

SDC. 

HST. 

DUP 

HST,    TRC 

TRC. 

DOW. 

PD. 

sw. 

SDW. 

SK. 

SDW. 

AAP, 

GAF. 

EK. 

DOW. 

TRC. 

FIS. 

SFA. 

HK, 

HN. 

UN. 

UN. 

BPC, 

MON,    VEL 

DUP. 

DUP. 

BUC. 

DUP. 

ATL, 

SDH. 

ALL, 

ATL. 

CYCLIC  INTERMEDIATES 
TABLE  2, --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER^    1972--CoNTINUED 


Manufacturers'    identification   codes 
(according   to   list    in   table   5) 


l-(6-Chloro-o-tolyl)-3-nethyl-2-pyrazolin-5-one 

[ (4- Chloro-o-tolyl)thio] acetic   acid 

4-Chloro-a,a,a-trifluoro-3-nitrotoluene 

6-Chloro-a,a,a-trif luoro-m-toluidine 

Chlorotriphenylme thane 

a-Chloro-p- xylene 

2 -Chloro-p- xylene 

4-Chloro-2,5-xylenesulfonyl    chloride 

Cholesteryl   nonanoate 

Cholesteryl   oleyl   carbonate    (Mesomorphic) 

Cholestyramine,   pure 

Cholic   acid 

•Cinnamoyl  chloride 

*Cresols  :  ^ 

m-Cresol 

*o-Cresol : 

From  coal  tar 

From  petroleum 

Synthetic 

p-Cresol 

Cresols ,  mixed: ' 
*(m,p)-Cresol ; 

From  coal  tar 

From  petroleum 

(o,m,p)-Cresol : 

From  coal  tar 

From  petroleum 

Other 

*Cresylic  acid,  refined:' 

From  coal  tar 

From  petroleum 

Synthetic 

Cryptocyanine 

*Cumene 

2-[p-(Cyanoacetamido)nhenyl]-6-methyl-7-ben:othia:ole- 
sulfonic  acid. 

Cyanoacetic   acid,   2-ethylhexyl  ester 

p-Cyanobenzaldehyde 

4- [(2-Cyanoethyl)ethylamino]-o-tolualdehyde 

P- [ (2-Cyanoethyl)methylamino]benzaldehyde 

:i-Cyano-B-methylcinnamic  acid,   ethyl  ester 

*Cyclohexane  — 

1 ,2-Cyclohexanedicarboxylic   anhydride 

1 ,3-Cyclohexanedione 

Cyclohexanol 

*Cyclohexanone 

Cyclohexanone  oxime 

Cyclohexene 

3-Cyclohexene-l-carboxaldehyde-l,2,3,6-tetrahydro- 
benzaldehyde. 


HST. 

(lAF. 

PCIV. 

HK, 

PCW. 

EK. 

BPC. 

DUP. 

ACS. 

EK. 

EK. 

MRK. 

WIL. 

ARS, 

imp, 

X. 

KPT, 

PRD. 

KPT. 

MER, 

fJPC, 

PRD, 

KPT, 

PIT. 

HPC, 

SW. 

Acr, 

KPT. 

HER, 

NPC, 

PRD. 

ACP 

KPT. 

NPC 

NPC 

KPT 

MER 

NPC, 

PRD. 

PIT 

ASH,  CLK,  CSP,  DOW,  GOC,  MOC,  MON,  SIIC,  SKO,  SNT, 

SOC,  TX,  UCC. 
DUP. 


DUP,  GAF. 
DUP,  GAF. 

.A.Sll,  CSD,  EN.I,  GOC,  GRS,  PI.C,  PPR,  SWC,  TX ,  UOC. 

ACS . 

PD. 

ACP,  CNP,  DUP,  HON. 

ACP,  CEL,  CNP,  DBC,  DUP,  MON. 

ACP,  CNP. 

EK,  PLC,  USR. 

UCC. 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2.— Cyclic  intermediates  for  which  U,S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--CONTINUED 


rianuf acturers '    identification   codes 
(according  to   list    in   table   3) 


4-Cyclohexene- 1,2-dicarboximide 

4-Cyclohexene- 1 ,2-dicarboxylic    anhydride 

Cyclohexene   oxide 

"Cyclohexylamine 

N^-Cyclohexylmetanilamide 

Cyclohexyl-2-Tiropanone 

N-Cyclohexyltaurine,   sodium  salt 

Cy c 1 open tadienyl iron 

Cyclopentanol 

Cyclopentene 

p-Cymene 

De cab romobi phenyl 

Deoxycholic   acid 

Diacenaphtho[l,2-j  :  1 ,2  ' -il]f  luoranthene    (Decacvclene)-- 

l,5Cand   1,8) -Diacetamidoanthraquinone 

l,5-Diacetaiiiido-4,8-dibromoanthraquinone 

3,5-Diacetamido-2,4,6-triiodobenzoic   acid 

3- (Diallylcarb;moyl)-l,2,2-trimethylcyclopentan- 

carboxylic  acid. 

N^N^- Dial  lylmel amine 

Diallylchlorendate 

*1 ,4-Diaminoanthraqiiinone 

1 ,5-Diaininoanthraquinone 

l,5(and    1,8) -Diaminoanthraquinone 

*2,6-Diaminoanthraquinone 

3,3' -Diaminobenzani lide 

3,4-Diaminobenzanilide 

2 ,4-Diaminobenzenesulfonic   acid    [SO  H=l] 

2,5-Diaminobenzenesulfonic   acid   [50^11=1] 

3,5-Diaminobenzoic   acid  dihydrochloride 

4,4 ' -Diamino- 1,1' -bianthraquinone-3,3' -di sulfonic 

acid,   disodium  salts. 

4,4'-Diamino-2 ,2 '-biphenyldi sulfonic   acid 

1 ,3-Daiminocyclohexane 

3, 7- Diamino- 4, 6 -dibenzothiophenedi sulfonic   acid, 

5,5-dioxide,    disodium  salt. 

1 ,4- Diamino- 2 ,3-dichloroanthraquinone 

*1 ,4- Diamino- 2 ,3-dihydroanthraquinone 

4, 8- Diamino- 9,10- dlhydro- 1,5- dihydroxy -9,10 -dioxo- 2,6- 

anthracenedisulfonic  acid. 
1 ,4-Diamino-9,10-dihydro-9,10-dioxo-2,3-anthracenedi- 

carboximide. 

1 ,5-Diamino-4,8-dihydroxyanthraquinone 

1 ,8-Diamino-4,5-dihydroxyanthraquinone 

4,5-Diamino-l ,8-dihydroxyanthraquinone 

1,4- Diamino- 5 -nitroanthraquinone 

2 ,4-Diamino-6-phenyl-s-triazine 

2,6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic   acid 

3,5-Diamino-p-toluenesulfonic   acid    [Sn^H^l] 

3. 5- Diamino- 2 ,4 ,6-triiodobenzoic   acid 

1,4: 3,6-Dianhydroglucitol 

2,5-Dianilinoterephthalic  acid 

Diary Iguanidine 


SFC. 

PIT. 

USR. 

ABB,  HON  RBC,  VGC. 

CMC. 

niv,  LIL. 

r,AF. 

ARA. 

LIL. 

ARA,  PLC. 

ACS,  HN,  HPC. 


IVIL. 

SDC. 

AAP. 

TRC. 

SDW . 

HTlT. 

ACY. 

SAR. 

CMC, 

DUP, 

GAF,    SDC 

GAF, 

TRC. 

AAP, 

TRC. 

AAP, 

GAF, 

TRC. 

TRC. 

X. 

DUP, 
TRC. 

TRC. 

ACS, 

ACY 

DUP. 

ACY. 

CMG, 

DUP 

AAP, 
TRC. 

ACY 

VPC. 

,\AP. 

ICI. 

GAF. 

RU, 

NEP, 

ACY, 

GAF. 

SDW. 

ICI. 

X,  X 

DUP. 


ATL,  DUP,  GAF,HSH  ,  ICC,  MAY,  TRC. 


VEL. 
RIL, 
CGY,  GAF,  SDH,  TRC,  VPC. 


CYCLIC  INTERflEDIATES 
TABLE  2,— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972— CONTINUED 


p-Diazo-N,N- dimethyl  aniline- 1- amino- 8-naphthol- 3-siil- 
fonate-6-sulfonic   acid,    sodium  salt. 

1,5-Dibenzamidoanthraquinone 

6,  ll-Dibenzajiiido-16H-dinaphtho[2,3-a,2'  ,3'  -i]  carbazole- 
5,10,15,17-tetrone. 

*4,5'-Dibenzamido-l ,1 '-iminodianthraquinone 

1,5-Dibenzoylnaphthalene 

2-(N,N-Dibenzyl)amino-4-acetamidoanisole 

Dibenzylazodicarboxylate 

N,N' -Dibenzyle thy lenedi amine 

N,N'-Dibenzylethylenediamine   di acetate 

N,N'-Dibenzylidenetoluene-a,a-di amine 

5' ,4 ' -Dibenzyloxy-2-bromobutyrophenone 

3,4-Dibenzyloxybutyrophenone 

2 , 4 ' - Dib  romoace  tophenone 

*3,9-Dibromo-7H-benz[de]anthracen-7-one 

m-Dibromobenzene 

p-Dibromobenzene 

4,4'-Dibromobenzil 

ar-Dibromoethylbenzene 

2,6-Dibromo-4-nitroaniline 

2 ,6-Dibromo-4-ni trophenol 

a ,a-Dibromo-p-nitrotoluene 

5  ,  13-Dibromo-8  ,  16-pyranthrenedione 

3,5-Dibromo-3' -tri  f luoTOmethylsalicylani lide 

p-Dibutoxybenzene    (DBB) 

2,5-Dibutoxy-4-morpholinobenzenediazonium  sulfate 

1 ,1 '-Di-n-butyldicyclopentadienyliron 

2,6-Di-tert-butyl-4-nonylphenol 

Dibutyltin  bis(cyclohexylmaleate) 

3',4'-Dichloroacetophenone 

2,4-Dichloroaniline 

3,4-Dichloroaniline 

2,5-Dichloroaniline   and  hydrochloride    [NH2=1] 

3-(2,4-Dichloroanilino)-l-(2,4,6-trichlorophenyl)-2- 
pyrazolin-5-one . 

1 ,5-Dichloroanthraquinone 

1 ,5 (and    1 ,8) -Dichloroanthraquinone 

Dichlorobenzanthrone 

m-Dichlorobenzene 

*o-Dichlorobenzene 

oCand  p)-Dichlorobenzene 

*p-Dichlorobenzene 

4, 6 -Dichloro-m-benzenedi sulfonamide 

2,S-Dichlorobenzenesulfonyl    chloride 

*3,3'-Dichlorobenzidine  base   and  salts 

2,2'-DichIorobenzil 

2 ,4-Dichlorobenzoic   acid 

4,7-Dichlorobenzo[b]thiophen-3(2H)-one 

2,4-Dichlorobenzoyl   chloride 

Dichlorobenzyl    chloride- 

4,4- C2,6-Dichlorobenzylidene)di-2,6-xylidine 

4,5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l ,2-dicarbo- 
nitrile. 

Dichlorodiphenylsilane 

2',7'-Dichlorofluorescein 

2-C5,8-Dichloro-l-hydroxy-2-naphthylazol-l-phenol-4- 
sulfon amide. 


Manufacturers'  identification  code 
(according  to  list  in  table  3) 


TRC. 
TCI. 

ACY,    GAF,    MAY,    TRC. 

GAP,    TRC,    VPC. 

SDC. 

KF,    WTL. 

hfYT. 

mT. 

SDH. 

SDW. 

SDW. 

EK. 

DUP,    GAF,   MAY,    TRC. 

EK. 

DOW. 

NES. 

DOW. 

SDC. 

SW. 

DUP. 

ICI. 

PCW. 

ALL. 

ALL. 

ARA. 

GAF. 

x. 

EK. 


DUP,    MON. 
BUG,   DUP. 


TRC. 

AAP. 

ACY. 

EK. 

ACS, 

DVC. 

ACS, 

ABB. 

ACS. 

ACS, 

flTO. 

HN. 


BPC. 
DUP. 
ARA. 

DCC. 
EK. 
TRC . 


DOW,    DUP,   MON,    NEV,    PPG,    SCC,    SVT. 
DOW.    DVC,   MON,    PPG,    SCC,   SVT. 

CIVN,    LAK,    UPJ. 


SY'ITHETIC  ORGAfllC  CIIErilCALS,  197? 
TABLE  2. --Cyclic  intermediates  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
faccording   to   list    in   table   3) 


5 ,14-Dichloroisoviolanthrone 

Di (chloromethyl)diphenyl    oxide 

2,5-Dichloro-4-  (3-niethyl-5-oxo-2-pyrazolin-l-yl)ben:ene 

sulfonic   acid. 

2,6-Dichloro-4-ni troani line 

1 ,2-Dichloro-4-nitrobenzene 

1 , 4- Dichloro- 2 -nitrobenzene    (Nitro-p-dichlorobenzene) 

2 ,4-Dichlorophenol 

3,4-Dichlorphenyl   isocyanate 

3-  (2'  ,6'-Dichlorophenyl)-5-iriethyl-isoxazole-4-carbonyl 

chloride . 

[  (2,5-Dichlorophenyl)thio]acetic   acid 

2,6-Dichloropyrazine 

5,6-Dichloropyridazine 

4,7-Dichloroquinoline 

2 ,3-Dichloroquinoxaline 

2,5-Dichlorosulfanilic   acid    [Sn3H=l] 

2,5-Dichloro-4-sulfobenzenediazonium  sulfate 

p,a-Dichlorotoluene 

a,a-Dichlorotoluene    (Benzal   chloride) 

Di eye lohexy lamina 

N,N'-3-Dicyclohexy 1-2- thiourea 

*Dicyclopentadiene    (includes    cyclopentadiene) 

Dicyclopentadiene  dioxide 

Didodecylbenzene 

3-Diethanolainine-4-ethoxyacetanilide 

p-Diethanolaminomethoxyacetanilide 

p-Diethoxybenzene 

p-  (Diethylaniino)benzaldehyde 

p- (Diethylamino)benzenediazonium  chloride,    zinc   chloride 

salt. 

3'- [2- (Diethylamino)ethyl]-4'-hydroxyacetanilide 

a- [ (2- Diethyl amino) ethyl ]-a-phenylcyclohexanemethanol , 

hydrochloride . 

7' -Diethylamino-4-methylcoumarin 

m- (Diethylamino)phenol    (N ,N-Diethyl-3-aminophenol) 

3- [(4' -N, N- Die thy 1 amino) phenylazo]-lH-l ,2 ,4-triazole 

3-(Diethylamino)propiophenone 

4- (Die thy 1 amino) -o-tolualdehyde 

*N,N- Diethyl aniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

N, N - Di e thy Icyclohexyl amine 

a,a'-Diethyl-4 ,4 '-dimethoxystilbene 

N,N-Diethylmetanilic  acid 

n' ,n' -Diethyl- 4-methoxymetanilamide 

N,N-Diethyl-4-nitroso-m-anisidine  hydrochloride 

N, N- Die thy 1-4-nitroso-m-pheneti dine 

N, N - Di e thy 1-m-pheneti dine 

N,N-Diethyl-p-phenylenedi amine   oxalate 

N ,N-Diethyl-m-toluidine 

N,N-Diethyl-p-toluidine 

Di  f ur  f ury 1 i  di  nepent  ae  rythri  tol 

10,ll-Dihydro-5H-dibenzo[a,d]cycloheptan-5-one 


MON,    VGC. 

HOC,   MON,    UCC,    VEL. 


ICI. 
BPC. 
DCC,    HST,   TRC. 

CWN,  SW. 

DlIP,  MON. 
DIIP. 

DOW,  MON. 

nic. 
nic. 

ACS. 

ACY. 

ACY. 

PD,    SDW. 

EK. 

DUP. 

TRC. 

HN. 

BPC. 

ABB, 

ABB. 

EN  J, 

VEL. 

cn. 

HST. 

H.ST. 

ALL,    GAP. 

ACS,    DUP,    TRC. 

HST. 

PD. 
ACY. 

CAF. 

ACY. 

TRC. 

ACY. 

DUP. 

ACS,    ACY,    DSC, 

DUP. 

DOW,    KPP. 

DUP. 

LIL. 

DUP. 

PCW. 

DUP. 

GAP. 

GAF. 

EK. 

DUP. 

RSA. 

SDC. 

LIL. 


CYCLIC  INTERMEDIATES 
TABLE  2, --Cyclic   intfirmediates  for  which  U,S,   production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according   to    list   in   table   3) 


9 , 10-Dihydro- 1 , 4-dihydroxy-9 , Id-dioxo- 2- anthracene - 

sulfonic   acid    (2-Quinizarinsulfonic   acid). 
9, 10-Dihydro- 9, 10 -dioxo- 1 ,5- anthracenedi sulfonic   aci 


9,10-Dihvdro-9 


disodium  salt. 


9,10-Dihydro-9 


disulfonic  acid  and  salt 


10- dioxo- 1,5- anthracenedi sulfonic  acid. 


10- dioxo- 1,5 (and  l,f 


10- dioxo- 1 , 8- anthracene disulfonic   acid. 


10 -dioxo- 2 ,6- anthracenedi sulfonic   acid 


9,10-Dihydro-9 

potassium  sa 
*9, 10-Dihydro- 9 

and  salt. 
*9,10-Dihydro-9,10-dioxo- 1-anthracenesulfonic  acid  and 

salt    (Gold   salt). 
9,10-Dihydro-9, lO-dioxo-2-anthracenesulfonic  acid  and 

salt    (Silver  salt) . 
9,10-Dihydro-9,10-dioxo-2,7-anthraquinonedisulfonic 

acid. 
[Dihydrogen  3,3' ' -phthalocyaninedisulfonate(2-) ]copper- 
10, ll-Dihydro-5- [3- (methylaminopropyl) ]-5H-dibenzo[a,d] 

cyclohepten-5-ol . 
9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic 

acid. 

d-Dihydrophenylglycine 

*l,4-Dihydroxyanthraquinone    (Quinizarin) 

1,5-Dihydroxyanthraquinone    (Anthrarufin) 

1 ,5 (and    1,8) -Di hydroxy an thraquin one 

*l,8-Dihydroxyanthraquinone    (Chrysazin) 

2,6-Dihydroxyanthraquinone    (Anthraf lavic   acid) 

2,4-Dihydroxybenzaldehyde 

2, 5-Dihydroxybenoic   acid 

3,6-Dihydroxybenzonorbornane 

2,4-Dihydroxybenzophenone 

2,4-Dihydroxy-3,3-dimethylbutyrolactone 

l,5-Dihydroxy-4,8-dinitroanthraquinone 

*l,8-Dihydroxy-4,5-dinitroanthraquinone    r4,5-Dinitro- 

chrysazin) . 
4,5-Dihydroxy-2 ,7-naphthalenedisulfonic   acid   (Chrono- 
tropic acid) . 

6  ,7-Dihydroxy-2-naphthalenesulfonic  acid 

4 , 5- Dihydroxy- 3- (p- sulf opheny lazo) -  2 , 7-n aphtha lene- 

disulfonic  acid,    trisodium  salt. 
*  16, 17- Dihydroxy viol an throne    (Dihydroxydibenzanthrone)-- 

m-Diiodobenzene 

3,5-Diiodosalicylic  acid,    lithium  salt 

Di  i  s  opr opy Ibenzene 


MP,    HSH,    PAT. 


TRC. 
GAF, 


GAP, 

TRC. 

A'\P, 

GAF, 

TRC. 

AAP, 

ACY, 

MAY, 

TRC 

DUP. 

AAP. 

ICl. 

LIL. 

AAP, 

ACY, 

DUP, 

GAF, 

HSH, 

ICC, 

MAY, 

TRC 

DUP, 

GAF, 

TRC. 

ACY, 

TRC. 

CHG , 

GAF, 

TRC. 

GAF, 

TRC. 

EK. 

ARS. 

EK. 

DUP, 

GAF. 

PD. 
TRC, 

VPC. 

DUP, 

GAF, 

ICl, 

TRC. 

ACY,    DUP,    ICl,   MAY. 


EK. 
DOW. 


SY'lTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Cyclic  intermediates  for  which  U.S.   production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972--CoNTINUED 


Manufacturers'    identification    codes 
(according  to    list    in   table   3) 


2 ' ,5 '- Dime thoxy ace toacetani lide 

2, 5- Dime thoxy aniline 

1 ,5 (and    1,8) -Dimethoxyanthraquinone 

2, 5- Dime thoxybenz aldehyde 

m- D  ime  th  oxyben  zene 

3,3'-Dimethoxybenzidine    (o-Dianisidine) 

3,3'-Dimethoxybenzidine  hydrochloride 

2 ,6-Dimethoxybenzoic   acid 

N,N'- [(3,3'-Dimethoxy-4,4'-biphenylylene)bis(azo) ]bis 
(N-methyltaurine) . 

2,5-Dimethoxy-B-methyl-S-nitrostyrene 

2,5-Diriethoxy-a-methylphenethylamine 

2,5-Dimethoxy-4'-nitrostilbene 

4- (2' ,5 '-Dimethoxyphenethyl) aniline  hydrochloride 

(3,4-Dimethoxyphenyl) acetic   acid 

1-  (3,4  '  -Dimethox>'phenyl)-2-aminopropane 

2,5-Diraethoxytetrahydrofuran 

2,5-Dimethoxytoluene 

16, 17- Dime thoxy violanthrone 

p- (Dime thy lamino) ben zaldehyde 

p-Dimethylaminobenzenediazonium  chloride,    zinc   cliloride 
salt. 

m- (Dime thy lamino) benzoic  acid 

5- (p- Dime thy laminobenzylidenejrhodanine 

6-Dimethylamino-2-  [2-  (2,5-dimethyl-l-phenyl-3-pyrryl')- 
vinyl]-l-methyl-l-quinolinium  methyl   sulfate. 

m- (Dime thy lamino) phenol 

2,6-Dimethyl-4-aminophenol 

*N,N-Di methyl aniline 

7, 12- Dime thy Ibenz [a] anthracene 

2,5-Dimethylbenzenesulfonic   acid 

3,3'-Dimethylbenzidine    (o-Tolidine) 

3,3' - Dime thylbenzi dine  hydrochloride 

*N,N- Dime thy Ibenzyl amine 

a,a-Dimethylbenzyl  hydroperoxide 

*2,2'-Dimethyl-l ,1 '-bianthraquinone 

N,N-Dimethylcyclohexylamine 

5,5-Dimethylhydantoin 

1 ,l-Dimethyl-3- (m-hydroxyphenyl)urea 

2, 3- Dimethyl indole 

D,L-cis ,    trans -2, 2- Dimethyl -3- isobutenylcyc lop ropane- 

l-carboxylic  acid,   ethyl  ester. 
2 ,5-Dimethyl-4(2)-morpholinylmethylphenol ,   hydro- 
chloride. 

N,N-Dimethyl-l-n  aph  thy 1 amine 

N,N- Dime thy 1-p-nitrosoani line 

6,6-Dimethyl-2-norpinene-2-ethanol 

2,4-Dimethylphenol 

N, N- Dime thy 1-p-phenylazoani line 

N,N- Dime thy 1-p-phenylenediamine 


HST. 

EKT,    PCW. 
TRC. 

Cmi,   UPJ. 
ACY,    ARS. 
SDH. 
CIVN. 
ARS. 
GAF. 


PD,    X. 

UPJ. 

LIL. 

LIL. 

HEX. 

EK. 

ICI. 

BJL,    GAF. 


HST. 


ACS,    ACY,    DSC,    DUP,    SW . 


EK. 

CIVN. 

cm. 

EK. 

ARS, 

MLS, 

RH,    SW. 

CLK. 

ACY, 

DUP, 

GAF,   TRC 

ABB, 

DUP. 

GLY. 

CIWJ. 

DUP. 

BPC. 

IDC. 

EK. 

ACY, 

RDA. 

EK. 

EK. 

EKT. 


CYCLIC  INTFR'lEDIATES 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER,    1972--CoNT INUED 


Manufacturers'    identification   codes 
(according  to   list   in  table   3) 


N,N- Dime thy l-m-phenylenedi amine  dihydrochloride 

N,N- Dime thy 1-p-phenylenedi amine  dihydrochloride 

N,N- Dime thy 1-p-phenylenedi amine  monohydrochloride 

N,N- Dime thy l-p-phenylenedi amine   sulfate 

1,4- Dime thy Ipiperazine 

N,N-Dimethylsulfanilic   acid 

Dime thy 1 -  5- sulfoi soph thai  ate 

N,N-Dime thy 1-o-tolui dine 

N, N- Dime thy 1-m-tolui dine 

N,N-Dimethyl-p-toluidine 

2,4-Dinitroacetani lide 

2,4-Dinitroaniline 

p-  (2,4-Dinitroanilino)phenol 

1,5 (and    1 ,8)-Dinitroanthraquinone 

N,N'- (2,4-Dinitro-l ,5-anthraquinonylene)dioxamic   acid-- 

3,3' -Dinitrobenzanilide 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic  acid 

2,4-Dinitrobenzenesulfonic  acid,    sodium  salt 

3,S-Dinitrobenzoic   acid 

3,5-Dinitrobenzoyl   chloride 

10, 10' -Dinitro [3,3 '-bi-7H-benz[de] anthracene] -7,7' - 
dione. 

Dinitrocaprylphenol 

2 , 4- Din  i  t rocumene 

l-(3,5-Dinitro-2-hydroxphenylazo)-2-naphthol 

2,6-Dinitro-4-isopropylphenol 

2,4-Dinitrophenol ,  tech 

3,5-Dinitrosalicylic  acid 

*4,4'-Dinitrostilbene-2,2 'di sulfonic  acid 

2 ,4-Dinitrotoluene 

*2,4(and  2 ,6)-Dinitrotoluene 

3,5-Dinitro-p-toluenesulfonic  acid 

Dinonylphenol 

Di-tert-pentylphenol 

Di-tert-amylphenoxyacetyl  chloride 

2-(2,4-Di-tert-pentylphenoxy)butyric  acid,  tech 

1 ,5-Diphenoxyanthraquinone 

Diphenylacetoni tri le,  tech 

*Diphenylamine 

2,8-Diphenylanthra[l,2-d:6,5-d']bisthiazole-6,12-dione- 

2,5-Diphenyl-p-benzoquinone 

Diphenyldecyl   phosphite 

2 ,2'-Diphenyl-4-dimethylamine 

N,N' -Diphenylethylenedi amine 

Diphenylme  thane 

2,5-Diphenyloxazole 

4,7-Diphenyl-l ,10-phenanthroline 

1, 3- Di phenyl-! ,3-propanedione 

4,4 '-Dithiodiani line 

2,2'-Dithiodibenzoic   acid 

*l,4-Di-p-toIuidinoanthraquinone 

1,8-Di-p-toluidinoanthraquinone 

2,5-Di-p-toluidinoterephthalic  acid 

p-Ditolylmercapto-2 ,5-diethoxybenzenediazonium  chloridt 
zinc  chloride   salt. 


EK. 

.TCC. 

AAP. 


EK, 

RSA. 

SDC. 

AAP, 

SDC. 

GAP, 

SDC. 

AAP, 

TRC. 

TRC. 

TRC. 

DUP. 

EK, 

TRC. 

EK, 

NES. 

SAL. 

EK. 

DUP, 

MAY. 

RH. 

DUP. 

TRC. 

X. 

AAP, 

SDC. 

EK, 

SAL. 

ACY, 

CGY, 

DUP, 

GAP,  HN,  SDH, 

TRC 

ACS, 

DUP, 

RUC. 

AIP, 

DUP, 

MOB, 

UCC. 

GAP. 

GAP 

JCC. 

PAS. 

EK. 

EK. 

VPC. 

FIS 

ACY 

DUP, 

ORO, 

RUC,  USR. 

GAP 

EK. 

X. 

LIL 

RPC 

PD. 

ARA 

EK. 

EK. 

EK. 

SDC 

LIL 

SW. 

ACS 

ATL, 

GAP 

TRC. 

ICI 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2,— Cyclic  intermediates  for  which  U.S.   production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER.    1972--CoNTINUED 


Manufacturers'    identification   codes 
(according   to   list   in   table   3) 


*Divinylben2ene 

Uodecylbenzene.    (See  Alkylbenzenes . ) 

Dodecylbenzyl    chloride 

Dodecylmethylbenzyl    chloride 

p-Dodecylphenol 

2,2 '-  (Ethanediylidenedinitrilo)diphenol 

l,2-Epoxy-3-(2-biphenylyl)propane 

p-EthoxybeHzaldehyde 

o- E thoxyben zoic  acid 

p(p-  (Ethoxybenzy li dene) amino] ben zonit rile 

N- (p-Ethoxybenzyli dene) -p-butyl aniline 

l-(4-Ethoxy-3-methoxybenzyl)-6,7-dimethoxy-3-inethyl- 
isoquinidine    (Dioxyline  base). 

2-Ethoxy-l-naphthoyl   chloride 

m-Ethoxyphenol 

4-Ethoxy-o-phenylenediamine 

N'- (6- Ethoxy-3-pyridazinyl) sulfanilamide 

Ethyl -in- aminobenzoate  methanesulfonate 

3-(Ethylamino)-p-cresol 

a- (N-Ethylamino)-p-toluenesulfonamide 

3- (Ethylamino)-p-toluenesulfonic  acid    [S03H=1] 

*N~ Ethyl aniline,    refined 

*2-(N-Ethyanilino)ethanol 

[2-(N-Ethylanilino)ethyl]trimethylammonium  chloride 

3- (N- E thy lanilino)propionit rile 

a-(N-Ethylanilino)-m-toluenesulfonic   acid 

a- (N-Ethylanilino)-p-toluenesulfonic  acid 

2-Ethylanthraquinone 

*Ethylbenzene 

Ethylbenzyl   chloride 

2- (N-Ethyl-N-S-cyanoethyl)-4-acetaminoanisole 

N-Ethylcyclohexylamine 

1-Ethylcytosine 

3,3'-Ethylenedioxydiphenol 

Ethylene  glycol  dibenzenesulfonate 

3- Ethyl- 2- [5- (3-ethyl-2-benzothiazolinylidene) -1 , 

3-pentadienyl] -benzothiazolium  iodide. 

Ethyl  hydrocaffeate 

2- [N-Ethyl-p- [(6-methoxy-2-benzothiazolyl )azo]anilino] 

ethanol . 

N-Ethyl-N- (2-methylsulfonamidoethyl)-m-toluidine 

N-Ethyl- 1-naph thy 1  amine 

9-Ethyl-3-nitrocarbazole 

a-Ethyl-3-nitrocinnamic   acid 

N- [2- (N-Ethyl-4-nitroso-m-toluidino)ethyl]methane- 

sulfonamide. 

Ethylphenylmalonic  acid,   diethylester 

*N-Ethyl-N-phenylbenzylamine 

5-Ethyl-2-picoline    (2-Methyl-5-ethylpyridine)    (MEP) — 

1-Ethylpiperidine 

6-Ethyl-l , 2,3, 4-tetrahydro- 1,1,4, 4-tetramethyl- 

naphthalene . 

N-Ethyl-p-toluenesulfonamide 

N-Ethyl-m-toluidine 

N-Ethyl-o-toluidine 

2- (N-Ethyl-m-toluidino) ethanol 


DOW,  FG,  KPP. 


GAP, 

EK. 

NES. 


ACY. 
EK. 


BJL. 

TRC. 

ACY. 

EK. 

DUP. 

AAP. 

DUP. 

ACS,  ACY,  DUP. 

DUP,  EKT,  TCH. 

DUP. 

TCH. 

GAP,  SDH,  WJ. 

ACS,  TRC. 

DUP. 

ATR,  CSD,  DOW,  EN.7 ,  FG ,  KPP,  MCB,  MON ,  SHC,  SKC,  SNT, 

Snc,  STY,  TOC,  UCC. 
BPC. 
SDC. 

ABB,  USR. 
PD. 
IDC. 
NES. 


TRC. 

WAY. 

DSC,  DUP. 
SDC. 
SDW. 
WAY. 

BPC,  HAL. 

ACS,  DUP,  SDH. 

UCC. 

RIL. 

GIV. 

EK. 
DUP. 
DUP. 
TCH. 


CYCLIC  INTERHEDIATES 
TAELE  2, --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
{according  to   list   in   table   3) 


3- (N-Ethyl-m-toluidino)propionitri le 

a- (N-Ethyl-m-toluidino) -m- toluene sulfonic   acid 

1-Ethynyl-l-cyclohexanol 

Fluorescein    (3' ,6 '-Dihydroxyfluoran) 

o-Fluoroben2oic  acid 

l-Fluoro-2,4-dinitrobenzene 

d- 2- Formami  do- 1 -phenyl - 1 , 3-propanedi  o 1 

4-Formyl-m-benzenedisulfonic   acid 

o-Formylbenzenesulfonic  acid   (o-Sulfobenzaldehyde) 

Furan 

Furfuryl    alcohol 

Fur furyl amine 

N-Glycolylarsanilic   acid,   sodium  salt 

Hexabromobenzene 

Hexabromobiphenyl 

Hexachlorobenzene 

Hexachlorocyclopentadiene 

1,4 ,5,6,7,7-Hexachloro-5-norbornene-2 ,3-dicarboxylic 

acid. 
1 ,4,5,6,7,7-Hexachloro-5-norbomene-2 ,3-dicarbox>'lic 

anhydride . 

Hexadecachlorophthalocyanine  copper  complex 

Hexafluorobenzene 

1,2,3,4,5 ,6-Hexahydro-8-hydroxy-cis-6,ll-dimethyl-2,6- 

methano-2-benzazocine . 
Hexahydro- l-methyl-4-phenyl-lH-azepine-4-carbonitrile-- 

Hexamethylenimine 

Hippuric   acid 

p-Hydrazinobenzenesulfonic   acid 

2-Hydrazinobenzothiazole 

Hydroquinone,    di (6-hydroxyethyl)    ether 

*Hydroquinone ,    tech 

6-Hydroxy-p-acetophenetidide 

3 ' - Hydroxy ace  t  ophen  one 

4* -Hydroxy ace tophenone 

6'-Hydroxy-m-acetotoluidide 

1- (p-Hydroxyanilino)-4-naphthol 

p-Hydroxybenzaldehyde 

p-Hydroxybenzenesulfonic   acid 

p-Hydroxybenzoic  acid 

3 '-Hydroxy- 2- (N-benzy 1-N-methyl amino) acetophen one 

4-Hydroxycoumarin 

2-Hydroxy-3,5-diiodobenzoic   acid 

3- [N- (2-Hydroxyethyl)anilino]propionitrile,   acetate 

3- [N-(2-Hydroxyethyl)anilino]propionitrile,   benzoate 

N- (B-Hydroxyethyl)-2 ,4-dihydroxybenzamide 

N- fB-Hydroxyethyl)-2,5-dihydroxybenzamide 

N- (6-Hydroxyethyl)-3,5-dihydroxybenzamide 

3- [N- (2-Hydroxyethyl)-m-toluidino]propionitrile 

3-Hydroxy-N- (2-hydroxyethyl)-2-naphthamide 

N-  [7-Hydroxy-8-  [2-hydroxy-5- (methylsulfamoylphenyUazo] 

l-naphthyl]acetamide. 
6 ' -Hydroxy-5 '- [ C2-hydroxy-5-nitrophenyl) azo] -m-aceto- 

toluidide. 
N- [7-Hydroxy-8- [ (2-hydroxy-S-nitrophenyl) azol-l- 
naphthyllacetamide. 
7-Hydroxy-8- [ (4 ' - [ (p-hydroxyphenyl) azo] -3, 3' -dimethyl - 

4-biphenylyl)azo]-l ,3-naphthalenedi sulfonic  acid. 


DUP,    TCH. 

GAF. 

EKT. 

ICC. 

FIN. 

EK. 

PD. 

GAF. 

SDH. 

QKO. 

QKO. 

MLS. 

SDW. 

MCH,   NES. 

MCH. 

DVC. 

MK,   VEL. 

HK. 

VEL. 

TRC. 
WHC. 
SDW. 

IVYT. 

CEL. 

BPC. 

GAF,    STG,    WJ. 

FK. 

CTN. 

CRS,    DA,    EKT. 

GAF. 

CTN,   SDH. 

BJL. 

TRC. 

TRC. 

DOW. 

DOW,    PRD,    UPF. 

HN. 

SDW. 

ABB. 

EK. 

TCH. 

DUP,    x. 

IDC. 

ARS. 

IDC. 

TCH. 

IDC. 

TRC. 

TRC. 

TRC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
(according  to   list    in   table   3) 


4-Hydroxy-4-isopropylmetanilamido 

4- Hydroxymet anil amide 

4-Hydroxymetanilide 

3' -Hydroxy- 2- (raethy 1 amino) ace tophenone 

*3-Hydroxy-2-methylcinchoninic   acid 

4-Hydroxy-N'-raethylmet anil amide 

5-Hydroxymethyl-2-norbornene 

N- (Hydroxymethyl)phthalimide 

3-Hydroxy-N-  (3-N-morpholinopropyl)-2-naphthajnide 

3-Hydroxy-2,7-naphthalenedisulfonic   acid,    disodium  salt- 
y-Hydro xy-1  , 5-naphthalenedisulfoni  c  acid 

7-Hydroxy-l ,3-naphthalenedisulfonic   acid,    disodium  salt- 

4-Hydroxy-2-naphthalenesulfonamide 

4-Hydroxy-l-naphthalenesulfonic  acid 

6-Hydroxy-2-naphthalenesulfonic   acid 

8-Hydroxy-l-naphthalenesulfonic   acid 

4-Hydroxy-2-naphthalenesulfonic  acid,  benzenesulfonate, 
sodium  salt. 

*6-Hydroxy-2-naphthalenesulfonic  acid,   sodium  salt 

8-Hydroxy-l-naphthalenesulfonic  acid,   y-sulfone 

3-Hydroxy-2-naphthanilide   (Naphthol   AS) 

l-Hydroxy-2-naphthoic   acid,    methyl   ester 

3-Hydroxy-2-naphthoic  acid    (B.O.N.) 

5-Hydroxy-2-naphthoic  acid,    methyl   ester 

3-Hydroxy-2-naphtho-o-toluidide 

N- (2- Hydroxy- 1-naph thy l)acet amide 

N- (7-Hydroxy- 1-naphthyl) ace t amide 

N- (7-Hydroxy-l-naphthyl)benzamide 

1- (2-Hydroxy- 1-naphthyl azo)-6-nitro- 2-naphtho 1-4- 
sulfonic   acid. 

3- [ (7-Hydroxy-l-naphthyl)carbamoyl]acetanilide 

4-Hydroxv-7- (p-nitrobenzamido) -2-naphthalenesulfonic 
acid. 

2-Hydroxy-5-nitrometanilic  acid 

1- (2-Hydroxy-4-nitrophenylazo)-2-naphthol 

2,2'- (2-Hydroxy- 4-nitropheny limine) die thanol 

2-Hydroxy-4-n-octoxybenzophenone 

0- [ (p-Hydroxyphenyl) azojbenzoic   acid 

3- [ (4- (4-Hydroxyphenylazo)2,5-dimethoxyphenylazo) ]- 
benzenesulfonic   acid. 

lla-Hydroxyprogesterone 

2 ' - Hydr oxyp  rop  i  ophenone 

N- Hydroxys uccini mi de 

N-Hydroxysuccinimide,    triethylamine   salt 

2-Hydroxy- 4- sulfo-1-naphthalenediazonium  hydroxide 
inner   salt. 

1 -Hydroxy- 4- p-toluidinoanthraquinone 

2- Imidazolidinone 

2- Imidazolidinone  modifications 

*1 ,1 ' -Iminobis [4-aminoanthraquinone] 

Ijl'-Iminobis [4-benzamidoanthraquinone] 

1 ,1 '-Iminobis [5-benzamidoanthraquinone] 

7,7'- Iminobis [ 4 -hydroxy-2-naphthalenesulfonic   acid] 

1 ,1 '-Iminobis [4-nitroanthraquinone] 

*1, I'-Iminodianthraquinone    (1 , 1 '-Dianthrimide) 

Indole- 2, 3- di one 

Indophenol,  sodium  salt 


GAF,  ICC,  SDC,  IRC. 


TRC. 
TRC. 


TRC. 
DUP, 
TRC. 
CTN. 
DUP, 
TRC 
ARS. 
ACY. 
IDC. 
ACY, 
DUP, 
ACY. 
GAF. 
DUP. 
SNA, 
VPC. 
GAF. 


ACY,  TRC,  WJ. 

TRC. 

ATL. 

x. 

PCW. 

WAY. 

ATL. 

ACY. 

GAF,  TRC. 

TRC. 

TRC. 

TRC. 
GAF. 

TRC. 
TRC. 
WAY. 

ACY,  CCW. 
EK. 


TRC. 


UPJ. 

uor. 

BJL, 

EK. 

BJL. 

ACY. 

GAF, 

ICI. 

VAL. 

RH. 

ACY, 

GAF, 

TRC 

ACY. 

GAF, 

TRC. 

TRC. 

ACY, 

TRC. 

ACY, 

GAF, 

TRC 

TRC. 

EK. 

CYCLIC  INTERMEDIATES 
TABLE  2.— Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER^    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to  list  in  table  3) 


a- lodotoluene 

Isobutylbenzene 

*Isocyanic  acid  derivatives: 

Bitolylene  diisocyanate    CTODI) 

p-Chlorophenyl   isocyanate 

Cyclohexylisocyanate 

Dianisidine   diisocyanate    (DADI) 

Diphenylmethane- 4,4 '-diisocyanate    (MDI) 

Phenylisocyanate 

Polyisocyanates    (complex) 

Pol>inethylene  pol>-phenyl isocyanate 

Toluene   2, 4- diisocyanate 

Toluene  2,4-   and  2 ,6-diisocyanate    (65/35  mixture) 

♦Toluene   2,4-    and   2 ,6-dii50cyanate    (80/20  mixture) 

p-Toluenesulfonyl   isocyanate 

Other 

Isoni cot inonit rile 

2-Isonitrosoacetanilide 

Isophthalic   acid   (Benzene- 1 ,3-dicarboxylic  acid) 

Isophthalic   acid,   diallyl    ester 

Isophthalic  acid,   dimethyl   ester 

Isophthalic  acid,   dlphenyl   ester 

Isophthaloyl   chloride 

p- Isopropylbenzoic   acid 

4,4'-Isopropylidenebis    [2,6-dibromophenol]    (Tetrabromo- 

bisphenol   A) . 
4,4'-Isopropylidenebis [2,6-dichlorophenol]    (Tetrachloro- 

bisphenol  A) 
5,5'-Isopropyl 
*4,4 '-Isopropyl 
4,4' -Isopropyl 


denebis (2-hydroxy-m-xylene,a,a' -diol)- 

denediphenol  (Bisphenol  A) 

denediphenol ,  ethoxylated 

4,4'- I sop ropy li denediphenol ,  propoxylated 

o- Isopropylphenol 

Isopropylphenols,  mixed 

4- I sop ropy 1-m-phenylenedi amine 

I sovio Ian throne  (Isodibenzanthrone) 

Leuco  quinizarin  (1,4,9,10-Anthratetrol) 

2,4-Lutidine 

2,6-Lutidine 

3,4-Lutidine 

3,5- Luti dine 

Malonani lide 

Mandelonitrile 

Melamine 

p-Mentha-1 ,4(8)-diene 

dl-p-Mentha-l,8-diene    (Limonene) 

p-Menth-1-ene 

o-Mercaptobenzoic  acid   (Thiosalicylic  acid) 

Metanilic   acid    (m-Arainobenzenesulfonic   acid) 

N- (p-Methoxybenzylidene)-p-butyl aniline 

6-Methoxymetanilic  acid 

4'-Methoxy-2-  (p-raethox\'phenyl)acetophenone 

Methoxymethyldiphenyl  oxide" 

N-  (2-Methoxy- 1-naph thy Dacet amide 

6-Methoxy-8-nitroquinoline 

(p-Methoxyphenyl) acetic  acid 

6-Methoxy- 2- (phenyl thio)quinoline 

m-Methoxyphenolisocyanate 


EK. 

PLC,   TNA. 


CIVN, 
MOB. 
OTC. 
CIVN, 
ACS, 
HOB, 
MOB. 
MOB, 
DUP, 
DUP, 
ACS, 
CITO. 
DUP, 
RIL. 
TRC, 
ACC. 
FMP. 
MTR. 
BJL. 
DUP. 


UPJ. 

MOB,    UPJ. 
UPJ. 

RUC,    UPJ. 

MOB. 

MOB. 

DUP,  MOB,   OMC,    RUC,    UGC,    WYN. 

MOB,   UCC,    X. 


EK. 
DOW. 

DVC. 

ARK. 

DOW,    GE,    SHC,   UCC. 

ICI. 

ICI. 

TNA. 

FMP,    KPT. 

DUP. 

MAY,    TRC. 

EKT,   HSH,   TRC. 

KPT,   RIL. 

RIL. 

UCC. 

RIL. 

PCW. 

KF. 

ACY,    PPC. 

GIV. 

ARZ,   GIV,    HN,   NCI. 

GIV. 

AMB,    LIL. 

ACY,    DUP,   TRC. 

EK. 

GAF. 

CTN. 

BPC. 

TRC. 

PD. 

UOP. 
EK. 
EK,   OTC. 


SYNTHETIC  ORGANIC  CHEf^ICALS,  197.2 
TABLE  2,— Cyclic  intermediates  for  which  U.S,  production  or  sales  were  reported; 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


4 '  -Me  thoxNT)  rop  i  ophenone 

1- (Methyl ami no) anthraquinone 

1-  (Methylamiiio)-4-p-toluidinoanthraquinone 

N-Me thy  1 aniline 

2- (N-Methylanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine    [NH2=1] 

m-Methylanisole 

2-Methyl anthraquinone 

3-Methylbenzo[f]quinoline 

2-Methylbenzothiazole 

N-Methylbenzyl amine 

Methylbenzyl  ether 

5-(l-Methylbutyl)barbituric   acid 

N-Methyl-N-carboxyanthranilic   anhydride 

3-Methylcholanthrene 

Methylcyclohexane 

2-Methylcyclohexanone 

l-Methyl-4-cyclohexene-l,2-dicarboxylic  anhydride 

Methyl eye lopentadiene 

N-Methyldicyclohexylamine 

4-Methyl-a,a-diphenyl-l-piperazineethanol,    dihydro- 
chloride. 

N-Me thy leneani line 

4 ,4'-Methylenebi5[2-chloroaniline] 

4 ,4'-Methylenebis [N,N- diethyl aniline] 

4,4'-Methylenebis[N,N-dimethylaniline]    (Methane  base) 

4,4'-Methylenebis(3-hydroxy-2-naphthoic   acid)    disodium 

salt. 

2,2'-Methylenebis(4-methyl-6-nonyl-p-cresol) 

*4, 4 '-Methylenedi aniline 

S,5'-Methylenedisalicylic   acid 

Methy Ihydroquinone 

2-Methyl indole 

2 -Methyl indole- 3- carboxaldehyde 

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic 
acid. 

5-Methyl-4-nitro-o-anisidine 

4-Methyl-2-nitroanisole 

2-Methyl -5-nitroimidazole 

N-Me thy 1-N-nitroso-p-toluenesulfonamide 

2-Methyl-5-norbomene-2,3-dicarboxylic  anhydride 

Methylnorbomene-2,3-dicarboxylic  anhydride,    isomers 

m-  (3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonaiiiide — 
„. (3.Methyl-S-oxo-2-pyrazolin-l-yl)benzenesulfonic  acid- 
*p_(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic  acid- 
3- (3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalene- 

disulfonic   acid. 
6-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l ,3-naphthalene- 

disulfonic  acid. 
4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic 
acid    1S03H=1]. 

2-Methyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

l-Methyl-4-phenylisonipecotic   acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic  acid 

5-Methyl-3-phenyl-4-isoxazolecarboxylic  acid  hydro- 
chloride. 
*3-Methyl-l-phenyl-2-pyrazolin-5-one    (Developer  Z) 


Manufacturers'    identification  codes 
(according  to   list    in  table   3) 


LIL. 

AAP, 

ACY, 

ICI 

BDO, 

GAP, 

ICI 

ACY, 

DUP. 

TCIL 

DUP. 

SW. 

GIV. 

ACY. 

ACY. 

FMT. 

MLS, 

SDW. 

UCC. 

LIL. 

UCC. 
EN  .J. 


PCW. 

DUP. 

ACY, 

TRC. 

ACY, 

DUP, 

SDH. 

EK, 

PD. 

ACY. 

ACS 

DOW, 

MOB, 

RUC 

HN. 

ARS 

EKT. 

TRC 

GAP 

DUP 

RDA. 

ALD, 

EK. 

VEL. 

ACS. 

VPC. 

TRC. 

ACY, 

GAP, 

TRC. 

TRC. 

TRC. 

CMG, 

TRC. 

SDW. 
ARS. 
ARS. 

ACY,    DUP,    GAP,    SDH.   VPC. 


CYCLIC  INTERMEDIATES 

TABLE  2,— Cyclic  intermediates  for  which  U,S,   production  or  sales  were  reported. 
Identified  by  manufacturer,  1972--Continued 


4-Methyl-l-piperazine  acetic  acid,  methyl  ester 

3-Methyl-2-pyrazolin-S-one 

1-Methylpyrrole 

*a-Methylstyrene 

ar-Methylstyrene  (Vinyl toluene) 

2-(Methyl5ulfonyl)-4-nitroaniline 

4- [Methyl thio)-m-cresol 

3-Methylthiophene 

3-Methyl- 1- (thiosulfophenyl)-2-pyrazolin-5-one ,  sodium 

salt. 
3-Methyl -6 -r)-toluidino-7H-diben2[f,ij  ]isoquinoline- 
2,7('3H)-dione. 

3-Methyl-l-n-tolyl-2-pyrazolin-5-one 

16-A-Methyltriene  carbethoxylate 

Naphthalene,    solidifying   at   79°    C.    or  above    (refined 
flake)    (from  domestic  canide) . 

1 ,4-Naphthalenediol 

1-Naphthalenesulfonic   acid 

2-Naphthalenesulfonic   acid 

1-Naphthalenesulfonic   acid,    sodium  salt 

2-Naphthalenesulfonic   acid,    sodium  salt 

2-Naphthalenesulfonyl   chloride 

1 ,4,5,8-Naphthalenetetracarboxylic  acid 

Naphthalimide 

1-Naphthol    (a-Naphthol) 

2-Naphthol,    tech.    (6-Naphthol) ' 

p-Naphtholbenzein 

l-Naphthol-3,6-disulfonic   acid,    monosodium  salt 

l-Naphthol-2-sulfonic  acid,   potassium  salt 

1 ,2- Naphthoquinone 

l,2-Naphthoquinone-4-sulfonic  acid,   sodium  salt 

Naphth[l ,2-d] [1,2 ,3]oxadiazole-S-sulfonic   acid 

2-(2H-Naphth[l,2-d]triazol-2-yl)-4-(l,l,3,3-tetramethyl- 
butyl)phenol. 

1 - Naph thy 1   acetate 

1-Naphthyl amine    (rt-Naph thy  1  amine) 

2-  (l-Naphthylamino)ethanol 

p- (2-Naphthylamino)phenol    (N- (p-Hyd^oxyphenyl)-2- 
naphthylamine)  . 

N- (1- Naph thy l)ethylenedi amine   dihydrochloride 

(2-Naphthyloxy) acetic   acid 

(2-Naphthyloxy) acetic  acid,   sodium  salt 

(2-Naph thy Ithio) acetic   acid 

Nicotinonitrile   (3-Cyanopyridine) 

4'-Nitroacetanilide 

2'-Nitro-Ti-acetanisiHirie 

4'-Nitro-o-acetanisidide 

2-Nitro-p-acetophenetidide 

3' -Nitroacetophenone 

m-Nitro aniline 

o-Nitroaniline 


DUP. 

DUP. 

.\CP,    CLK,    DOW,    HPC,    SKO,    USS. 

DOIV. 

TRC. 

CRZ. 

SDW. 

SDC. 

ICI. 

HST. 

sen. 

KPT,    IVTC. 

EK. 

TRC. 

ACY,    EK,    FIN,   m. 

TRC 

ACY. 

DUP. 

TRC 

ACS. 

UCC 

ACY. 

EK. 

HN. 

EK. 

EK. 


EK. 
DUP. 
TCU. 
SDC. 

RSA. 

EK. 

BKL. 

ACY. 

NEP,    RIL. 

GAP,   TRC. 

DUP. 

DUP. 

AAP. 

SDH. 

X. 

MON. 


See   footnotes   at  end  of  table. 


552-743  O  -  74  -  4 


SYFITHETIC  ORGANIC  CIlEniCALS.  1972 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  EY  MANUFACTURER,  1972--CoNTINUED 


Manufacturers'    identification   codes 
(according   to   list   in  table   5) 


P-Nitroaniline 

2-Nitro-p-anisidine    [NHj=l] 

4-Nitro-o-anisidine    [NH2=1] 

5-Nitro-o-anisidine    [NH2=1] 

o-Nitroanisole 

p-Nitroanisole 

5-Nitroanthranilic  acid 

1-Nitroanthraquinone 

2-  (4-Nitro-2-anthraquinonyl)anthra[2,3-d]-oxazole-5 ,10- 

dione. 

m-Nitrobenzaldehyde 

p-Nitrobenzaraide 

3'-Nitrobenzanilide 

♦Nitrobenzene 

p-Nitrobenzenediazonium  tetraf luoroborate 

m-Nitrobenzenesulfonic   acid 

m-Nitrobenzenesulfonic   acid,    sodium  salt 

p-Nitrobenzenesulfonyl   chloride 

5-Nitro-2-benzimidazolinone 

m-Nitrobenzoic   acid 

0 - Ni troben zoi c   acid 

p-Nitrobenzoic  acid 

m-Nitrobenzoic   acid,    sodium  salt 

o-Nitrobenzoic  acid,   sodium  salt 

2- (m-Nitrobenzoyl)-o-acetanisidide 

p-Ni troben zoyl   azide 

m-Nitrobenzoyl    chloride 

p-Nitrobenzoyl   chloride 

p-Nitrobenzyl    chloro formate 

4-  (p-Nitrobenzyl) pyridine 

4 '-Nitro-4-biphenylcarboxylic   acid 

4-Nitro-sec-butylbenzene 

2-Nitro-p-cresol 

2-Nitro-p-cymene 

Nitrodiphenylamine 

5-Nitro-2-furanmethanediol ,    di acetate 

5-Nitroisophthalic   acid 

1-Nitronaphthalene 

3-Nitro-l ,5-naphthalenedisulfonic   acid 

7 (and   8) -Nitronaphth [ 1 ,2-d] [1 ,2 , 3]oxadiazole- 5 -sulfonic 

acid- 

p-Nitrophenethyl    alcohol 

o-Nitrophenol 

p-Nitrophenol 

p-Nitrophenol,    sodium  salt 

4 '- (p-Nitrophenyl)acetophenone 

4- [ (p-Nitrophenyl)azo]-o-anisidine 

4-Nitro-o-phenylenediamine 

2- (o-Nitrophenylazo)-p-cresol    (nH=l) 

(p-Nitrophenyl) hydrazine 

2,2'-[(m-NitrophenylH''iino]diethanol 

p-Nitrophenyl    isocyanate 

2-(p-Nitrophenyl)-2H-naphthol[l,2-d]triazole-6,8- 

disulfonic   acid. 
l-(m-Nitropheny 1-5-0X0- 2-pyTazoline-3-carboxylic 

acid. 
3-Nitrophthalic   acid 


AAP, 

HON. 

DUP. 

DUP. 

BUG. 

DUP, 

X. 

DUP. 

TRC. 

ACY, 

TRC. 

GAP. 

SDll. 

IGG. 

MP . 

AGS. 

ACY , 

niip. 

FST 

EK. 

ACY, 

DUP. 

GAP, 

MGN , 

MRA, 

SAL 

EK. 

DUP. 

SAL, 

SDU, 

WAY. 

SAL, 

WAY. 

DUP. 

SAL, 

WAY . 

WAY. 

GAP. 

EK. 

DUP, 

TRC. 

WAY. 

SW. 

EK. 

ACY, 

HON. 

NOR. 

PIS, 

MAL. 

DUP. 

TRC. 

ACS, 

GAP,    TRC 

PCW. 

MON. 

DUP,    MON,    SDC,    UOP. 

DUP. 

DUP,    PIS. 

AAP. 

DUP,    PMT. 

TRC. 

EK. 

DUP. 


CYCLIC  INTERMEDIATES 
TABLE  2. --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER,    1972— CoNT INUED 


3-Nitrophthalic  anhydride 

4-Nitrophthalimide 

--Nitroresorcinol 

5- Nitrosalicyl aldehyde 

l-Nitroso-2-naphthol 

p-Nitrosophenol 

4-Nitro5tilbene 

B-Nitrostyrene 

4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)- 
2,2'-stilbenedisulfonic   acid. 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene  mixtures 

p-Nitrotoluenesulfonic  acid 

*5-Nitro-o-toluenesulfonic   acid    [SO^Hsl] 

3-Nitro-p-toluenesulfonic   acid    [S03H=1] 

2-Nitro-iii-toluic  acid 

3-Nitro-p-toluic   acid,    methyl    ester 

*5-Nitro-o-toIuidine    [NH2=1]- 

2-Nitro-p-toluidine    [NH2=1] 

S-Nitro-2-p-toluidinobenzenesulfonic   acid 

16-Nitroviolanthrone 

4- Nitrc-m- xylene 

*Nonylphenol 

5-Norbomene-2  ,3-dicarboxvlic  anhydride 

Oxalacetic   acid,    diethylester,    Cp-sulfophenyl) - 
hydrazone . 

Oxanilide 

*1- [ (7- Oxo-7H-benz[de] anthracene- 3-yl) amino] ant hra- 
quinone . 
l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]- 

dianthraquinone . 
S- 0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic  acid 

(Pyrazolone   T) . 
5-0x0-1- (p-sulfophenyl)-2-pyrazoline-3-carboxylic   acid, 
ethyl   ester. 

4,4 '-Oxydi aniline 

Penicillin  G,   N-ethylpiperidine   salt 

Pent achloropyri dine 

1,1,3,3,5-Pentamethylindan 

p-Pentyl aniline 

p-Pentyloxybenzoyl   chloride 

o-Pentylphenol    to-Amylphenol) 

p-tert-Pentylphenol 

3,4,9,10-Penylenetetracarboxylic-3,4:9,10-diimide 

Phenethylamine 

a-Phenethylamine 

Phenethylamine   sulfate 

o-Phenethylbenzoic   acid 

m-Phenetidine 

o-Phenetidine 

p-Phenetidine 

•Phenol : 
'Natural : 

*From  coal   tar:^ 

39°C.,   m.p   

82%- 84% 

All   other 

*From  petroleum 

See   footnotes   at  end  of  table. 


Manufacturers'    identification   codes 
(according   to   list    in   table    3) 


EK. 

EK. 

EK. 

ACY,    SDC. 

GAP. 

cm. 

TRC. 


DIJP 


FST. 


DUP 

FST. 

DUP, 

EST. 

DIIP, 

FST, 

HN. 

CGY. 

ACS, 

ACY. 

DUP. 

GAF 

SDH,   TRC 

DIG. 

TRC. 

SAL. 

SDH. 

BUG, 

DUP, 

PCW, 

SDH 

DIIP, 

GAF, 

SW. 

TRC. 

ICI. 

DUP. 

GAF. 

JCC, 

MON, 

RH, 

UCC. 

VRL. 

TRC. 

EK. 

ACY, 

DUP, 

GAF, 

MAY, 

TRC. 

MAY, 

TRC. 

STG. 

STG. 

DOW. 

GIV. 

EK. 

EK. 

PAS. 

PAS. 

ACS. 

MLS. 

MLS. 

MLS. 

LIL. 

EK. 

MON. 

MON. 


KPT. 
AGP. 

ACP,    KPT. 
MLR,    NPC,    PRD. 


SYNTHETIC  ORGANIC  CHEI^ICALS>  1972 
TABLE  2,— Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER,    1972~C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list   in   table    3) 


*Synthetic: 

By  caustic   fusion:      U.S.P 

From   chlorobenzene  by   liquid-pbase  hydrolysis: 

U.S.P 

*Froin  curaene  by  oxidation:      U.S.P 

Other 

Phenolsulfonaphthalein,    sodium  salt 

Phenolsulfonic   acid,    lithium  salt 

Phenoxyacetic   acid,    sodium  salt 

2- Phen  oxyprop  i  ony 1   chloride 

Phenylacetic  acid   (a-Toluic  acid) 

Phenylacetic   acid,    ethyl    ester,    tech 

Phenylacetic   acid,   methyl   ester 

Phenylacetic   acid,    potassium  salt 

Phenylacetic   acid,    sodium  salt 

Phenylacetonitrile    (a-Tolunitrile) 

4'-Phenylacet  ophenone 

Pheny 1  ace ty 1   chloride 

N-Phenylanthranilic  acid 

Pheny larsine   oxide 

p-Phenylazoaniline    (C.    1.    Solvent   Yellow   1)    and  hydro- 
chloride . 

4- CPhenylazoJdiphenyl amine 

4- (Pheny lazo)-l-naph thy lamine 

5- (Pheny lazo) salicylic   acid 

1- Pheny lb iguanide  hydrochloride 

4-Phenyl-3-buten-2-one 

Phenyl   chloro formate 

a-Phenyl-o-cresol 

1- Pheny Icyclopentanecarboxylic   acid 

m- Pheny lenedi amine 

o- Pheny lenedi amine 

p- Pheny lenedi amine 

p- Pheny lenedi amine   dihydrochloride 

d- Phenylephrine 

dl- Phenylephrine 

1- Pheny lethanol 

Phenyl    ether    (Diphenyl   oxide) 

d(-) Pheny Iglycine 

dl- Pheny Iglycine    (racemic) 

N- Pheny Iglycine 

Pheny Iglycol  ethers 

df-)Phenylglycyl   chloride  hydrochloride 

5-Phenylhydantoin 

Phenyl hydrazine  hydrochloride 

Pheny l-l-hydroxy-2-naphthoate 

2,2  '- [ (Phenyl )imino] die thanol    (N- Pheny Idiethanol amine )- 

2,2'-[(Phenyl)imino]diethanol,   diacetate   ester 

3,3'- [ (Pheny l)imi no] dipropionitrile 

Phenylmalonic   acid,    diethyl    ester 

3- Phenyl -5-methyli50xazole-4-carbonyl    chloride 

Pheny 1-a-naph thy lamine 

o- Pheny Iphenol 

p-Phenylphenol 

o- Pheny Iphenol ,    chlorinated 

o-Phenylphenol,   sodium  salt 

N- Pheny 1-p-pheny lenedi amine 

Pheny Iphosphinic   acid 

Pheny Iphosphonothioic  di chloride 


•lAL, 

RCI. 

now. 

AGP, 

CLK, 

HON, 

SHC 

KLM. 

HK. 

SAL. 

BPC. 

ARS. 

BPC, 

GIV, 

MAL. 

BPC, 

HAL. 

BPC. 

BPC, 

OPC. 

npc. 

BPC, 

SDW, 

OPC, 

UOP 

DUP. 

B.JL. 

SDW. 

EK. 

ACS, 

ACY, 

nup. 

TRC. 

SDC. 

SDW. 

EK. 

RBC. 

SK. 

ACY,    DUP. 

DUP,    SW,    TRC. 

ACY,    DUP,    SDC. 

EK. 

SDW. 

SDW. 

UCC. 

DOW . 

BKL,    KF,    QIC,    UPJ. 

KF. 

EK. 

ncc. 

KF,    OTC,    x. 

ABB. 

EK. 

EK. 

TCH. 

SDC. 

DUP. 

BPC. 

AR.S. 

UCC. 

DOW,    RCI. 

DOW. 

DOW. 

DOW. 

USR. 

SFA. 


CYCLIC  INTERflEDIATES 
TABLE  2, --Cyclic  intermediates  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER.    1972--CONTI NUED 


Manufacturers*    identification   codes 
(according  to   list   in  table   3) 


Pheny Iphosphorous  di ch lori de 

*I-Phenyl-1 ,2-propanedione ,    2-oxime 

Pheny 1-2-prop an one 

l-Phenyl-5-pyrazolone-3-carboxylic  acid,  ethyl  estei- 

dl- Phenyl succinic  acid 

Phenyl  sulfide 

Pheny 1  sul f one 

1- Phenyl -2- thiourea 

Pheny lundecanoic   acid 

Phloroglucinol 

l(2H]-Phthala2inone 

Phthalaldehyde 

Phthalic   acid 

Phthalic   acid,    diallyl    ester 

*Phthalic   anhydride 

Phthalide 

Phthalimide 

Phthalimide,   potassium  salt 

[Phthalocyaninato(2-) ] copper 

Phthalocyanine,    copper  complex,   di-(and  tri-)chloro- 

methyl . 
Phthaloyl   chloride    (Phthalyl   chloride) 

*Picolines : ^ 

2-Picoline    (a-Picoline) 

3-Picoline    (8-Picoline) 

4- Pi CO line    CY-Picoline) 

Pi  CO line   (3,4-mixture) 

Picolinonitrile  (2-Cyanopyridine) 

3- Pi  CO lyl amine 

Picric  acid  (Trinitrophenol) 

2,5-Piperazinedione 

*Piperidine 

3-Piperidinopropiophenone  hydrochloride 

Polyethylbenzene 

Poly-m-phenoxylene 

Potassium  eye lohexanebuty rate 

Primuline  base 

Primulinesulfonic  acid 

'Propiophenone 

8 ,  16 - Pyranthrenedi  one 

Pyridine,  refined:^ 

2"  P\'ridine 

Other  grades 

Pyridine  hydrochloride 

3-Pyridinemethanol 

2(lH)-Pyridone 

2-Pyrimidinol 

2(lH)-Pyrimidinone 

2- Pyrrol idinone 

Quinaldine 


SFA. 

NEP, 
ORT. 


NES. 

EK. 

EK. 


EK. 

EK. 

FMP. 

AGP, 

ACS, 

DUP, 

EK. 

GAF. 

TRC. 


ENJ,  KPT,  MON,  PTO,  RCl,  SOC ,  STP,  UCC,  USS,  WYN. 

FMT. 

SW. 


KPT, 

NEP, 

RIL,   UCC 

NEP, 

RIL. 

RIL, 

UCC. 

KPT. 

NEP. 

RIL. 

SDC. 

EK. 

ABB, 

DUP, 

RIL. 

ACY, 

SDW. 

UCC. 

EK. 

EK. 

DUP. 

ATL. 

ORT, 

PD, 

UCC,   UOP. 

ICI, 

TRC 

KPT, 

NEP 

RIL. 

KPT, 

NEP 

EK. 

RIL. 

FMT. 

COY. 

VAL. 

GAF. 

ACS, 

ACY 

See  footnotes  at  end  of  table. 


SYNTilETIC  ORGANIC  CHEMICALS.  197^ 
TABLE  2, --Cyclic  intermediates  for  which  U.S.   production  or  sales  were  reported 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according   to   list    in   table   3) 


Quinoline ; 

1°   and  2°   Quinoline 

Quinoline    (synthetic) 

Other  grades 

2,4-Quinolinediol 

Quinophthalone    (Quinoline  yellow  base) 

Resorcinol ,    tech' 

Resorcinol,   raonoacetate    (non-medicinal   grade)' 

S-Resorcylic  acid 

*Salicyl aldehyde 

Salicyl aldehyde  oxime 

*Salicylic  acid,    tech 

Salicylic  acid,   airanonium  chromium  complex 

Salicylic -acid,    sodium  chromium   complex 

*Styrene,    all   grades 

5 - Sul f amoy lanthranilic   acid 

Sulfanilamide,    tech  

Sulfanilic  acid    (p-Aminobenzenesulfonic  acid)    and  salt- 

4-Sulfoanthranilic  acid 

5-Sulfoisophthalic   acid,    1,3-dimethyl   ester,    sodium 
salt. 

5-Sulfoisophthalic   acid,    lithium  salt 

5-Sulfoisophthalic   acid,    sodium  salt 

2,4'    and  4 ,4' -Sulfonyldiphenol 

4,4'-Sulfonyldiphenol    (4,4'-Dihydroxydiphenylsulfone)-- 

4-Sulfophthalic  acid ■---■_---■- 

*Tereph thalic  acid 

*Terephthalic  acid,   dimethyl  ester 

Terephthalic  acid,   diphenyl  ester 

Terephthaloyldiacetic   acid,    diethyl   ester 

Terpheny 1    (Pheny lb  ipheny 1) 

3,3' ,4,4 '-Tetraaminobenzophenone 

3,3' ,4,4'-Tetraaminobiphenyl 

[4, 4', 4'', 4'' '-Tetraaminophthalocyaninato(21 ] copper 

3' ,3' ' ,5'5' '-Tetrabromophenolphthalein,    ethyl    ester 

Tetrabromoph thalic  anhydride 

1 ,4,5,8-Tetrachloroanthraquinone 

1 ,2,4,S-Tetrachlorobenzene 

1,2,4 ,5-Tetrachloro-3-nitrobenzene 

Tetrachloroph thalic   anhydride 

3,3' ,4' ,5-Tetrachlorosalicylanilide 

Tetrachloroviolanthrone 

Tetrahydrofuran 

Tetrahydrofurfuryl   methacrylate 

*1 ,4 ,5 ,8-Tetrahydroxyanthraquinone,    leuco  derivative 

1 ,4 ,5,8-Tetrakis(l-anthraquinonylamino)anthraquinone 
(Pentanthrimide) . 

N,N,3,5-Tetramethylaniline 

1 ,2,4,5-Tetramethylbenzene    (Durene) 

N,N,N',N'-Tet  rame  thylbenzidine 

p-(l,l,3,3-Tetramethylbutyl)phenol 

N,N,N' ,N'-Tetraraethyl-p-phenylenediamine  dihydro- 

chloride. 
[4, 4', 4'', 4'' '-Tetranitrophthalocyaninato(2) ] copper 


KPT. 

EK. 

KPT. 

PCW. 

ACS. 

KPT, 

UPF 

AAP. 

KPT, 

UPF 

DOW , 

MTR 

RDA. 

EK. 

DOW , 

HN, 

HON,    SDU. 

TRC. 

TRC. 

ACC, 

CSD 

DOW,    ELP,    FG,    GOC,    KPP,   MCB,   MON,    SHC ,    SKC 

SNT,    UCC. 

TRC. 

SAL. 

ACS, 

ACY, 

DUP. 

CMC, 

TRC. 

PCW. 

PCW. 

PCW. 

UPF. 

HON, 

UPF. 

ClfN, 

HSC. 

ACC, 

DUP, 

EKT,    SM. 

ACC, 

DUP, 

EKT,    UPC. 

BJL. 

PCW. 

MON. 

BJL. 

UPJ. 

.SDC. 

EK. 

MCH. 

DUP, 

GAP. 

DOW, 

UK. 

SDH. 

MON. 

EK. 

GAP. 

DUP, 

QKO. 

SAR. 

ACS, 

GAP, 

HN,    TRC. 

GAP. 

» 


GAP,    PRO,    Rll,    SCN. 


I 


CYCLIC  INTERMEDIATES 
TABLE  2. --Cyclic  intermediates  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972— CONT INUED 


3,3'-Thiobis [7H-benz[de] anthracen-7-one] 

2,2'-Thiobis [S-nitrobenzenesulfonic  acid] 

4,4'-Thiodianiline 

*6,6'-Thiodinietanilic   acid 

2-Thiophene acetic   acid 

2-Thiopheneacetonitrile 

2-Thiophenecarboxaldehyde 

Thiophenol 

sym- Thymol 

*Toluene-2,4-diamine  (4-m-Tolylenedi amine) 

Toluene- 2, 4- di sulfonic  acid 

p-Toluenesulfinic  acid,  sodium  salt 

o-Toluenesulfonamide 

p-Toluenesulfonamide 

o(and  p) -Toluenesulfonic  acid 

p- Toluenes ulfonic  acid 

p-Toluenesulfonic  acid-2-chloroethyl  ester 

p-Toluenesulfonic  acid,  methyl  ester 

p-Toluenesulfonic  acid,  monohydrate 

p-Toluenesulfonyl  chloride 

a-Toluenesulfonyl  fluoride 

m-Toluic  acid 

o-Toluic  acid 

p-Toluic  acid 

m-Toluidine 

o-Toluidine 

p-Toluidine 

o-Toluidine  hydrochloride 

p-Toluidine  hydrochloride 

To lui dines,  mixed 

2-o-Toluidinoethanol 

m-Toluidinoraethanesulfonic  acid 

o- To lui dinome thanes ulfonic  acid 

0- (p-Toluoyl) ben zoic  acid 

N-(p-Tolylazo)sarcosine 

*4-(o-Tolylazo)-o-toluidine    (C.    I.    Solvent  Yellow   3)  • 

4- [o-Tolylazo)-o-toluidine  hydrochloride 

1-p-Tolyldodecane 

2,2'- (m-Tolyliraino)diethanol 

2,2'-(m-Tolylimino)diethanol,    diacetate   ester 

o-Tolylisocyanate 

p-Tolylisocyanate 

p-Tolylmercuric  chloride 

Tolyltriazole 

N,N,N-Tribenzyl amine 

1,2, 3 (and   1 ,2 ,4) -Trichlorobenzene 

*1 ,2, 4 -Trichlorobenzene 

N,2,6-Trichloro-p-benzoquinoneiraine 

1 ,1 ,l-Trichloro-2 , 2- diphenyl ethane 

Trichloromel amine 

l,2,4-Trichloro-5-nitrobenzene 

Trichlorophenylsilane 

Trifluoropropylmethylsiloxane 

a,a,a,-Trichlorotoluene    (Benzotri chloride) 

a,2,4-Trichlorotoluene 

2,4,6-Trichloro-s-triazine    (Cyanuric  chloride) 


Manufacturers  ' 
(according 


identification   codes 
:o   list   in   table   3) 


HAY, 
GAF. 
ACY. 
ACS, 
BPC. 
BPC. 


ATL,    GAF,    LIL. 


KPT. 
ACY, 


SFA 

GIV 

ACS 

GAF. 

EK,   NES, 

flON. 

MON. 

MON,    NES, 

TEN,    HON, 

GAF. 

ICI. 

NES. 

MON . 

EK. 

BPC. 

BPC. 

BPC. 

DUP. 

DUP,    FST. 

DUP. 

.AAP,    ACY. 

EK. 

DUP. 

TCH. 

VPC. 

GAF,   TRC, 

ACY,    DUP. 

BUC,   GAF. 

ACY,    ALL,    DUP,    GAF, 

GAF. 

X. 

EKT,   TCU. 

SDC. 

EK. 

EK. 

EK. 

SN. 

MLS. 

PPG. 

DOW,    DVC,    HK,   SVT. 

EK. 

aVN. 

IVTH. 

ALL. 

DCC,    UCC. 

DCC. 

HK,    VEL. 

HN. 

CGY,    NIL. 


DUP.    OMC,   RUC,   UCC. 


UPF. 
UPF. 


VPC. 


SYflTHETIC  0RG'\:JIC  CHE'IICALS,   P7? 
TABLE  2, --Cyclic  intermediates  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--CONT INUED 


Manufacturers'    identification  codes 
(according  to  list  in  table  3) 


1,3,5-Triethylbenzene 

a,a,c«-Trifluorotoluene 

1,2,4-Trihydroxyanthraquinone 

4,5,7-Trihydroxyisoflavone 

Trimellitic   anhydride,    acid  chloride 

1 ,2,3-Trimethylbenzene    (Hemimellitene) 

1,2,4-Trimethylbenzene    (Pseudocumene) 

1,3,5-Triinethylbenzene   (Mesitylene) 

2,3,3-Trimethyl-3H-indole 

♦1 ,3,3-Trimethyl-A^ ,a-indolineacetaldehyde 

*l,3,3-Trimethyl-2-methyleneindoline    (Trimethyl   base)-- 

Trimethylphenyl ammonium  chloride 

2,4,6-Trimethylpyridine 

l-(Trimethyls'ilylUmidazole 

2,4,6-Trinitrobenzenesulfonic  acid 

2,4,7-Trinitrofluoren-9-one 

Triphenyl amine 

Triphenylme thane 

Triphenylmethanol 

a, a' ,a' ' -Tris (dime thy 1 amino )mesitol 

Tri5(2-methyl-l-aziridinyl)phosphine   oxide 

Tris(l  ,10-phenanthroline)iron(in    sulfate 

*7,7' -Ureylenebis [4-hydroxy-2-naphthalenesulfonic  acid] 
(J  Acid  Urea) . 

Verat raldehyde    (3,4- Dimethoxyben zal dehyde ) 

p-Vinylbenzenesulfonic  acid,   sodium  salt 

Vinyl eye lohexane 

2-Vinylcyclohexene 

5-Vinyl-2-picoline    (M\'T) 

2-Vinylpyridine 

4-Vinylpyridine 

Vinyl   toluene 

*Viol an throne   (Dibenzanthrone) 

Xanthene-9-carboxylic  acid 

m~ Xylene 

*o- Xylene 

*p- Xylene 

m-Xylenesulfonic  acid 

Xylenol  crystals 

2, 6 -  Xylene I ,  synthetic 

Xylenols : 

Low  b.p 

Medium  b.p 

Xylidines : 

2,4-Xylidine 

2,6-Xylidine 

Original  mixture 

4- (2,4-Xylylazo)-o-toluidine 

4-(2,5-Xylylazo)-o-toluidine 

4-(2,4-Xylylazo)-2,5-xylidine 

4- (Xylylazo) xylidines,  mixed 

All  other  cyclic  intermediates 


DUP. 

HK. 

GAP. 

EK. 

ARS. 

SNT. 

SNT. 

SNT. 

GAP. 

ACS, 

DUP, 

X. 

KPT. 

EK. 

EK. 

EK,  1 

EK. 

EK. 

EK. 

RH. 

ARS, 

EK. 

ATL, 


ATL,  DUP,  GAP,  TRC,  VPC. 
GAP,  TRC,  VPC. 


ICC. 

CTIG,  GAP,  TRC,  VPC. 


GIV,  SLV. 

DUP. 

BFG. 

UCC. 

PLC. 

MAY,  RIL. 

RIL. 

FG. 

ACS,  ACY,  DUP,  GAF,  ICI,  MAY,  SDC,  TRC. 

HAL. 

ATR,  SNT. 

ATR,  CCP,  CPI,  CSD,  CSO,  ENJ,  MON,  PPR,  SHC,  SHO,  SNT, 

snc,  TOC. 
ACC,  ATR,  CSO,  ENJ,  HCR,  PPR,  SHC,  SHO,  SNT,  SOC,  SOG, 

TOC. 
NES. 
NES. 
GE,  KPT. 

NPC. 
NPC. 

DUP. 

DUP. 

DUP. 

ACS. 

ACY. 

ACS. 

GAF. 

'^AP,  ABB,  ALL,  ALD,  ARS,  ATL,  B,1L,  BKL,  BPC,  CMC,  CTN , 
DUP,  EK,  FMP,  GAF,  HEX,  .ICC,  KF ,  LIL,  MRK,  PCW,  PD, 
PRD,  RH,  SW,  TCH,  TKL,  UCC,  UOP,  WYT,  x,  x,  x,  x,  ". 


See  report  on  Medicinal  Chemicals  for  data  on  medicinal  grade  of  this  item. 

Does  not  include  manufacturers'  identification  codes  for  producers  that  renort  to  the  Division  of  Fossil  Fuels, 
U.S.  Bureau  of  Mines.   These  producers  are  listed  in  the  U.S.  Bureau  of  Mines  Mineral  Industry  Survey  Coke  Producers 
in  the  United  States  in  1972,  Nov.    2?,    1973. 


CYCLIC  IITERflEDIATES 
TABLE  3.— Cyclic  intermediates:     Directory  of  manufacturers,  1972 


ALPHABbTICAL  UIRECTURY  BY  CUCIE 

[Names  ot  manufacturers  that  reported  production  or  sales  of  cyclic  intermediates  to  the  U.S.  Tariff  Commission  for 
1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Loae 

Name  of  company 

Code 

Name  of  company 

MP 

American  Aniline  Products,  Inc. 

FG 

Foster  Grant  Co. ,  Inc. 

ABB 

Abbott  Laboratories 

FIN 

Fine  Organics,  Inc. 

ACC 

Amoco  Chemical  Corp. 

FIS 

Fisher  Chemical  Co.,  Inc. 

Allied  Chemical  Corp. : 

FMP 

FMC  Corp.,  Industrial  Chemical  Div. 

ACF 

Plastics  Division 

Business  Croup 

ACS 

Specialty  Chemicals  Division 

fmt 

Fairmount  Chemical  Co.,  Inc. 

ACY 

American  Cyanamid  Co. 

fst 

First  Chemical  Corp. 

AlP 

Air  Products  f,   Chemicals,  Inc. 

ALD 

Aldrich  Chemical  Co.,  Inc. 

GAF 

GAF  Corp.,  Chemical  Division 

ALL 

Alliance  Chemical,  Inc. 

GE 

General  Electric  Co. 

AMB 

American  Bio-Synthetics  Corp. 

GIV 

Givaudan  Corp. 

ARA 

Arapahoe  Chemical  Division  of  Syntex  Corp. 

GLY 

Glyco  Chemicals,  Inc. 

AKK 

Armstrong  Cork  Co. 

GOC 

Gulf  Oil  Corp.,  Gulf  Oil  Lo.  Chemical  Co.-  U 

S. 

ARS 

Arsynco,  Inc. 

GRS 

Champlin  Petroleum  Co. 

ARZ 

Arizona  Chemical  Co. 

GYR 

Goodyear  Tire  i,  Rubber  Co. 

ASH 

Ashland  Oil,  Inc. 

ASL 

Ansul  Chemical  Co. 

HCR 

Hercor  Chemical  Corp. 

ATL 

Atlantic  Chemical  Corp. 

HEX 

Hexagon  Laboratories,  Inc. 

AIR 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co.  Div. 

HK 

HN 

Hooker  Chemical  Corp. 
Tenneco  Chemicals,  Inc. 

EDO 

Benzenoid  Organlcs,  Inc. 

HPC 

Hercules,  Inc. 

BFG 

B.F,  Goodrich  Co.,  B.F.  Goodrich  Chemical  Co. 

HSC 

Chemetron  Corp.,  Pigments  Division 

Div. 

HSH 

Harshaw  Chemical  (_o..  Division  of  Kewanee 

.^tl 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co.  Div. 

hst 

Oil  Co. 
American  Hoechst  Corp. 

BLlO 

Benzenoid  Organics,  Inc. 

BJL 

Burdick  5  Jackson  Laboratories,  Inc. 

ICC 

Inmont  Corp. 

BM 

Millmaster  Onyx  Corp.,  Millmaster  Chemical 

ICI 

ICI  America,  Inc.  6  Specialty  Chemicals  Div. 

Division,  Berkeley  Chemical  Dept. 

luc 

Industrial  Dyestuff  Co. 

BPC 

Stauffer  Chemical  Co.,  Specialty-Chemical  Div., 

Benzol  Products  Dept. 

JCC 

Jefferson  Chemical  Co.,  Inc. 

BRP 

BP  Oil  Corp. 

BUC 

Blackman-Uhler  Chemical  Co. 

KF 
KLM 

Kay-Fries  Chemicals,  Inc. 
Kalana  Chemical  Co. 

CCP 

Crown  Central  Petroleum  Corp. 

KPP 

iJinclair-Koppers  Co. 

CCW 

Cincinnati  Milacron  Chemicals,  Inc. 

KPi 

Koppers  Co.,  Inc.,  Organic  Materials  Division 

CEL 

Celanese  Corp.,  Celanese  Chemical  Co. 

CGY 

Ciba-Geigy  Corp. 

LAK 

Lakeway  Chemicals,  Inc. 

CHL 

Chemol,  Inc. 

LIL 

Ell  Lilly  1,  Co.  S  Puerto  Rico 

CHP 

C.  H.  Patrick  Co.,  Inc. 

CLK 

Clark  Chemical  Corp. 

MAL 

Mallinckrodt  Chemical  Works 

CMC 

Nyanza,  Inc. 

MAY 

Otto  B.  May,  Inc. 

CNP 

Nipro,  Inc. 

MCB 

Borg-Warner  Corp.,  Marbon  Chemical  Division 

CO 

Continental  Oil  Co. 

MCH 

Michigan  Chemical  Corp. 

CPI 

Commonwealth  Petrochemicals,  Inc. 

MER 

Merichem  Co. 

CRS 

Carus  Corp.,  Carus  Chemical  Co. 

MET 

M  and  T  Chemicals,  Inc. 

CRZ 

Crown  iellerbach  Corp.,  Chemical  Products  Div. 

MLS 

Miles  Laboratories,  Inc.,  Marschall  Division 

CSD 

Cosden  Oil  f,   Chemical  Co. 

MNR 

Monroe  Chemical  Co. 

CSO 

Cities  Service  Oil  Co. 

MOB 

Mobay  Chemical  to. 

CSP 

Coastal  States  Petrochemical  Co. 

MOC 

Marathon  Oil  Co.,  Texas  Refining  Division 

ctn 

Chemetron  Corp.,  Organic  Chemical  Division 

MCN 

Monsanto  Co. 

CWN 

Upjohn  Co.,  Fine  Chemical  Division 

MKA 
MRK 

Crown-Metro,  Inc. 
Merck  6  Co. ,  Inc. 

DA 

Diamond  Shamrock  Corp. 

MRT 

Morton  Chemical  Co.  Div.  ot  Morton-Norwich 

DBC 

Dow  Badische  Co. 

Products,  Inc. 

DCC 

Dow  Corning  Corp. 

MTO 

Montrose  Chemical  Co. 

DOW 

Dow  Chemical  Co. 

MTR 

Sobin  Chemicals,  Inc.,  Montrose  Chemical  Division 

DSC 

Dye  Specialties,  Inc. 

DUP 

E.I.  duPont  de  Nemours  6  Co. ,  Inc. 

NCI 

Union  Camp  Corp.,  Chemicals  Division 

DVC 

Dover  Chemical  Corp. 

NtP 
NES 

Nepera  Chemical  Co.,  Inc. 
Nease  Chemical  Co.,  Inc. 

EK 

Eastman  Kodak  Co.  : 

NEV 

Neville  Chemical  Co. 

EKT 

Tennessee  Eastman  Co.  Division 

NIL 

Nilok  Chemicals,  Inc. 

ELF 

El  Paso  Products  Co. 

NOR 

Norwich  Pharmacal  Co. 

ENJ 

Exxon  Chemical  Co.  U.S.A. 

NPC 

Northwest  Petrochemical  Corp. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3.— Cyclic  intermediates;  Directory  of  Manufacturers,  1972— Continued 


Code 

Name  of  company 

Code 

Name  of  company 

OMC 

Olin  Corp. 

SKO 

Skelly  Oil  Co. 

UPC 

Urbis  Products  Corp. 

SLV 

Sterwm  Chemicals,  Inc. 

URO 

Chevron  Chemical  Co. 

SM 

Mobil  Chemical  Co. 

ORT 

Roehr  Chemicals,  Inc. 

SNA 

Sun  Chemical  Corp. 

ore 

Story  Chemical  Corp.,  Ott  Div. 

SNT 

Suntide  Refining  Co. 

SOC 

Standard  uil  Co.  of  California,  Chevron 

PAS 

Pennwalt  Chemicals  Corp. 

Chemical  Co. 

PAT 

Morton  Chemical  Co.  Div.  of  Morton-Norwich 

SOG 

Charter  International  uil  Co. 

Products,  Inc. 

stg 

Stange  Co. 

PCK 

Princeton  Chemical  Research,  Inc. 

stp 

Stepan  Chemical  Co. 

PCW 

Pfister  Chemical,  Inc. 

STY 

Styrochem  Corp. 

PD 

Parke,  Davis  5  Co. 

SVl 

Solvent  Chemical  Co.,  Inc. 

PFZ 

Pfizer,  Inc. 

SW 

Sherwin-Williams  Co. 

PIT 

Pitt-Consol  Chemical  Co. 

SWC 

Shell  fi  Commonwealth  Chemicals,  Inc. 

PLC 

Phillips  Petroleum  Co. 

PPC 

Premier  Petrochemical  Co. 

TCH 

Emery  Industries,  Inc.,  Trylon  Chemical  Div. 

PPG 

PPG  Industries,  Inc. 

TEN 

Cities  Service  Co.,  Copperhill  Operations 

PPR 

Philllips  Puerto  Rico  Core,  Inc. 

TKL 

Thiokol  Chemical  Corp. 

PRD 

Productol  Chemical  Co.,  Inc. 

TMS 

Sterling  Drug,  Inc.,  Thomasset  Color  Division 

pto 

Puerto  Rico  Chemical  Co.,  Inc. 

TNA 

Ethyl  Corp. 

pit 

Petro-iex  Chemical  Corp. 

TOC 

Tenneco  Oil  Co. 

TRC 

Toms  River  Chemical  Corp. 

QKU 

Quaker  Oats  Co. 

TRD 

Trade  Enterprises,  Inc. 

TX 

Texaco,  Inc. 

RBC 

Fike  Chemicals,  Inc. 

RCI 

Reichhold  Chemicals,  Inc. 

DCC 

Union  Carbide  Corp. 

RDA 

Rhodia,  Inc. 

UUC 

Union  Oil  Co.  of  California 

KM 

Khom  5  Haas  Co. 

UOP 

Universal  Oil  Products  Co.,  UOP  Chemical  Div. 

RIL 

Keilly  lar  t.   Chemical  Corp. 

UPF 

United  States  Pipe  6  Foundry  Co. 

RPC 

Millnaster  Unyx  Corp.,  Refined-'Jnyx  Division 

UPJ 

Upjohn  Co. 

KSA 

R.S.A.  Corp. 

USR 

Uniroyal,  Inc.,  chemical  Division 

RUC 

Rubicon  Chemicals,  Inc. 

USS 

USS  Chemicals  Div.  of  U.S.  Steel  Corp. 

SAL 

Salsbury  Laboratories 

VAL 

Valchem  Corp. 

SAR 

Sartomer  Industries,  Inc. 

VEL 

Velsicol  Chemical  Corp. 

sec 

Standard  Chlorine  of  Delaware,  Inc. 

vgc 

Virginia  Chemicals,  Inc. 

sen 

Schering  Corp. 

VPC 

Baychem  Corp.,  Verona  Div. 

SCN 

Schenectady  Chemicals,  Inc. 

yDC 

Martin-Marietta  Corp.,  Sodyeco  Div. 

WAY 

Philip  A.  Hunt  Chemical  Corp.,  Wayland 

Sterling  Drug,  Inc. : 

Chemical  Division 

SUH 

Hilton-Uavis  Chemical  Co.  Division 

WCC 

Witco  Chemical  Corp.,  Witfield  Chemical  Div. 

SDW 

Winthrop  Laboratories  Division 

WHC 

Whittaker  Corp.,  Research  5  Development 

Stauffer  Chemical  Co.: 

WIL 

Wilson  g  Co.,  Inc.,  Wilson  Laboratories  Div. 

SFA 

Agricultural  Division 

WJ 

Warner- Jenkinson  Manufacturing  Co. 

SFC 

Calhio  Chemicals,  inc. 

WTC 

Witco  Chemical  Co.,  Inc. 

SFS 

Specialty  Chemical  Division 

WYN 

BASF-Wyandotte  Corp. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Division 

WYT 

Wyeth  Laboratories,  Inc.,  Wyeth  Laboratories 

SHO 

Shell  Oil  Co. 

Div.  of  American  Home  Products  Corp. 

SK 

Smith,  Klein  t,   French  Laboratories 

SKC 

Sinclair-Koppers  Chemical  Co. 

YAW 

Y.S.  Young  Co.,  Young  Aniline  Works  Division 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix. 


55 
DYES 

Domestic  synthetic  dyes  are  derived  in  whole  or  in  part  from  cyclic 
intermediates.   Approximately  two-thirds  of  the  dyes  consumed  in  the 
United  States  are  used  by  the  textile  industry  to  dye  natural  and  syn- 
thetic fibers  or  fabrics;  about  one-sixth  is  used  for  coloring  paper;  and 
the  rest  is  used  chiefly  in  the  production  of  organic  pigments  and  in 
dying  of  leather  and  plastics.   Of  the  several  thousand  different  synthe- 
tic dyes  that  are  known,  more  than  one  thousand  are  manufactured  by  one  or 
more  domestic  producers.   The  large  number  of  dyes  results  from  the  many 
different  types  of  materials  to  which  dyes  are  applied,  the  different  con- 
ditions of  service  for  which  dyes  are  required,  and  the  costs  that  a 
particular  use  can  bear.   Dyes  are  sold  as  pastes,  powders,  lumps,  and 
solutions;  concentrations  vary  from  6  percent  to  100  percent.  The  con- 
centration, form,  and  purity  of  a  dye  are  determined  largely  by  the  use 
for  which  it  is  intended. 

Total  domestic  production  of  dyes  in  1972  amounted  to  263  million 
pounds,  or  8.0  percent  more  than  the  244  million  pounds  produced  in  1971 
(table  1).^  Sales  of  dyes  in  1972  amounted  to  255  million  pounds,  valued 
at  $480  million,  compared  with  230  million  pounds,  valued  at  $423  million, 
in  1971.   In  terms  of  quantity,  sales  of  dyes  in  1972  were  10.9  percent 
larger  than  in  1971  and  in  terms  of  value,  13.5  percent  larger.   The 
average  unit  value  of  sales  of  all  dyes  in  1972  was  $1.88  per  pound,  com- 
pared with  $1.84  per  pound  in  1971. 

For  many  important  ayes,  production  was  larger  in  1972  than  in  1971. 
Vat  Yellow  2  production  increased  49.4  percent  from  2,211,000  pounds  in 
1971  to  3,304,000  pounds  in  1972.   Basic  Yellow  11  production  increased 
by  45.5  percent  from  1,174,000  pounds  in  1971  to  1,708,000  pounds  in 
1972.   Other  important  dyes  whose  output  in  1972  was  substantially  larger 
than  in  1971  were  Acid  Red  88  (43.0  percent  increase).  Direct  Yellow  44 
(28.0  percent  increase).  Disperse  Yellow  54  (27.0  percent  increase). 
Direct  Black  38  (26.8  percent  increase),  and  Disperse  Red  60  (19.0  per- 
cent increase) . 

On  the  other  hand,  the  production  of  several  important  dyes  was 
smaller  in  1972  than  in  1971.   Production  of  Vat  Green  1  was  1,800,000 
pounds  in  1972,  or  54.6  percent  less  than  the  3,966,000  pounds  produced 
in  1971.   Production  of  Vat  Green  3  was  1,402,000  pounds  in  1972,  or 
32.3  percent  less  than  the  2,070,000  pounds  produced  in  1971.  The  pro- 
duction of  Disperse  Blue  3  was  29.9  percent  less  in  1972  than  in  1971; 
that  of  Disperse  Yellow  23  was  29.3  percent  smaller;  that  of  FD§C  Yellow 
No.  6  was  20.5  percent  smaller;  that  of  Direct  Blue  2  was  19.8  percent 
smaller;  and  that  of  Vat  Black  25  was  10.4  percent  smaller. 

Table  lA  is  a  summary  of  production  and  sales  of  dyes  in  1972  by 
class  of  application.   Five  application  classes  of  dyes  accounted  for 
72.1  percent  of  all  dyes  produced  in  1972.   Vat  dyes  accounted  for  20.9 

See  also  table  2  of  this  report  which  lists  these  products  and 
identifies  the  manufacturers  by  codes.   These  codes  are  given  in  table  3. 


56 

SYNTHETIC  ORGANIC  CHEMICALS,  1972  . 

percent  of  the  total;  disperse  dyes  for  15.2  percent;  direct  dyes  for 

14.3  percent;  acid  dyes  for  11.3  percent;  and  fluorescent  brighteners  for 

10.4  percent.   Of  these  five  classes  of  dyes,  the  production  of  vat  dyes 
was  8.3  percent  larger  in  1972  than  in  1971;  the  production  of  disperse 
dyes  was  14.5  percent  larger;  the  production  of  acid  dyes  was  11.0  percent 
larger;  the  production  of  direct  dyes  was  8.5  percent  larger;  and  the  pro- 
duction of  fluorescent  brighteners  was  8.4  percent  smaller. 

1972  production  of  the  remaining  classes  increased  over  that  of  1971 
as  follows:   Food,  drug  and  cosmetic  colors  (17.6  percent);  solvent  dyes 
(17.2  percent);  mordant  dyes  (13.0  percent);  basic  dyes  (8.6  percent). 
Production  of  two  classes  decreased:  Azoic  compositions  (28.3  percent)  and 
fiber-reactive  dyes  (0.4  percent). 

Table  IB  shows  production  and  sales  of  dyes  by  chemical  class.  In 
1972,  three  chemical  classes  of  dyes  accounted  for  about  two-thirds  of  all 
dyes  produced.   Azo  dyes  accounted  for  35.0  percent  of  the  total;  anthra- 
quinone  dyes  for  17.7  percent  of  the  total;  and  stilbene  dyes  for  11.7 
percent.   The  production  of  azo  dyes  was  12.2  percent  larger  in  1972  than 
in  1971,  that  of  stilbene  dyes  was  3.9  percent  smaller,  and  that  of  the 
anthraquinone  dyes,  1.3  percent  smaller. 

Of  the  remaining  chemical  classes  of  dyes  for  which  statistics  are 
published  five  exceeded  1971  production  by  the  following  percentages; 
methine  (43.4),  quinoline  (20.9),  triarylme thane  (15.4),  xanthene  (10.1), 
and  cyanine  (5.2).   Production  of  five  other  classes,  however,  fell  below 
1971  levels;  phthalocyanine  (23.7),  nitro  (5.9),  oxazine  (5.7),  thiazole 
(4.6)  and  azoic  dyes  and  components  (1.2). 


DYES 
TABLE  L— Dyes:     U.S,  production  and  sales,  1972 

[Listed  below  are  all  dyes  for  which  any  reported  data  on  production  or  sales  may  be  published.   (Leaders  are  used 
where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  2  lists  all  dyes  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufacturer  of  each] 


Dye 


:,ooo 

pounds 


Grand  total 

ACID  DYES 

Total 

Acid  yellow  dyes,  total 

Acid  Yellow  11 

Acid  Yellow  17 

Acid  Yellow  23 

Acid  Yellow  .^6 

Acid  Yellow  38 

Acid  Yellow  40 

Acid  Yellow  42 

Acid  Yellow  54 

Acid  Yellow  65 

Acid  Yellow  76 

Acid  Yellow  99 

Acid  Yellow  151 

Acid  Yellow  159 

All  other 

Acid  orange  dyes,  total 

Acid  Orange  7 

Acid  Orange  8 

Acid  Orange  10 

Acid  Orange  24 

Acid  Orange  60 

Acid  iirange  64 

Acid  Orange  74 

Acid  Orange  86 

Acid  Orange  116 

All  other 

Acid  red  dyes,  total 

Acid  Red  1 

Acid  Red  4 

Acid  Red  18 

Acid  Red  26 

Acid  Red  37 

Acid  Red  73 

Acid  Red  85 

Acid  Red  88 

Acid  Red  89 

Acid  Red  99 

Acid  Red  114 

Acid  Red  115 

Acid  Red  137 

Acid  Red  151 

Acid  Red  182 

Acid  Red  186 

Acid  Red  266 

Acid  Red  337 

All  other 


263,304 


470 
280 
164 

100 
88 
110 


1,322 

469 

3,641 


799 
1,096 


236 

126 

1,171 

42 

169 

424 

39 

200 

981 


268 

210 

1,412 


1,000 
pounds 


254,536 


1,000 
dollars 


549 
280 
176 

lis 

171 


1,231 

459 

3,026 


570 
315 
280 
870 
222 


182 

722 

1,014 


363 
102 
115 


246 
152 
975 

42 
144 
362 

53 
155 
926 
102 


207 
1,269 


1,224 
662 


545 
151 
179 

115 

170 

2,736 

1,285 

8,580 

8,464 


465 

415 

1,339 

645 

158 

229 

361 

1,656 

2,508 

14,478 


225 
151 

199 
789 
349 

1,552 
65 
514 
958 
130 
592 

2,014 
305 
69 

1,151 
843 

4,397 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORfiANIC  CHEMICALS^  1^7'? 
TABLE  1,— Dyes;     U.S.   production  and  sales^  1972— Continued 


Quantity      Value 


ACID  DYES--Continued 


1,000 
pounds 


Acid  violet  dyes,  total- 
Acid  Violet  1 

Acid  Violet  5 

Acid  Violet  7 

Acid  Violet  12 

Acid  Violet  17 

Acid  Violet  43 

Acid  Violet  49 

All  other 


Acid  blue  dyes,  total- 
Acid  Blue  7 


Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
Acid  B 
All  other- 


ue  40- 
ue  41- 


ue  45- 
ue  62- 


ue  78 

ue  113 

ue  118 

ue  120 

ue  158  and  158A- 
ue  230 


Acid  green  dyes,  total- 
Acid  Green  3 

Acid  Green  9 

Acid  Green  16 

Acid  Green  20 

Acid  Green  25 

All  other 


Acid  brown  dyes,  total- 
Acid  Brown  14 

All  other 


Acid  black  dyes, 

Acid  Black  1 

Acid  Black  24-- 
Acid  Black  52-- 
Acid  Black  107- 
All  other 


123 
136 


,535 
368 
126 
532 


AZOIC  DYES  AND  COMPONENTS 

Azoic  Compositions 

Total 

c  Yellow  1 

c  Yellow  2 

c  Orange  3 

c  Red  1 

c  Red  2 

c  Red  6 


984 

319 

1,798 


1,000 
pounds 


1,000 
do  I lars 


5,021 


35 

1,441 

368 

119 

516 

27 


342 
179 


733 
729 


4,086 


828 

333 

1,962 


194 
156 


366 
248 


16,472 


130 

1,983 

1,979 

446 

2,253 

112 

204 

841 

517 

295 

1,834 


114 

1,155 

639 


1,473 
1,998 


1,632 

976 

4,235 


See  footnotes  at  end  of  table. 


DYES 


TABLE  1.--DYES:     U.S.  production  and  sales>  1972~Continued 


Dye 


AZOIC  DYES  AND  COMPONENTS- -Continued 
Azoic  Compositions — Continued 


Azoic  Blue  3 

Azoic  green  dyes- 


Azoic  brown  dyes,  total - 

Azoic  Brown  9 

All  other 


Azoic  black  dyes 

All  other  azoic  coinpositions- 


Azoia  Diazo  Components, 
(Fast  Colop  Bases) 


Total- 


Azoic  Diazo  Component  4,  base 

Azoic  Diazo  Component  10,  base 

Azoic  Diazo  Component  32,  base 

All  other  azoic  diazo  components,  bases- 


Azoia  Diazo  Components,   Salts 
(Fast  Colop  Salts) 


Azoic  Diazo 
Azoic  Diazo 
Aozic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
Azoic  Diazo 
All  other  a 


Component  1 ,  sa 

Component  3,  sa 

Component  S,  sa 

Component  8,  sa 

Component  9,  sa 

Component  10,  salt 

Component  1 1 

Component  12 

Component  13 

Component  28,  salt 

Component  49,  salt 

zoic  diazo  components,  salts- 


salt- 
salt- 
salt- 


Asoia  Coupling  Components 
(Naphthol  AS  and  Derivatives) 


Total- 


Azoic  Coupling  Component  14 

Azoic  Coupling  Component  15 

Azoic  Coupling  Component  18 

Azoic  Coupling  Component  19 

Azoic  Coupling  Component  21 

Azoic  Coupling  Component  29 

All  other  azoic  coupling  components- 


BASIC  DYES 


Total- 


asic  yellow  dyes, 
Basic  Yellow  2-- 
Basic  Yellow  11- 
Basic  Yellow  13- 
All  other 


1,000 
pounds 


270 
118 


509 
451 


1,226 


251 

779 


5,395 


404 
1,708 

201 
3,082 


Quantity      Value 


1,000 
pounds 


389 
1,009 


400 

369 

495 

604 

569 

473 

477 

453 

646 

103 

107 

113 

331 

308 

252 

27 

27 

41 

31 

56 

418 

358 

391 

452 

372 

531 

165 

193 

88 

84 

267 

669 

335 

553 

17,824 


4,930 


565 
1,506 

221 
2,638 


1,000 
dollars 


270 
344 


1,073 
1,218 


146 

353 

45 

299 

283 

410 

13,546 


1,179 

4,530 

541 

7,296 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972" 
TABLE  1.~Dyes;     U.S.  production  and  sales,  1972— Continued 


Production 


Quantity     Value 


BASIC  DYES- -Continued 

Basic  orange  dyes,  total 

Basic  Orange  2 

Basic  Orange  21 

All  other 

Basic  red  dyes,  total 

Basic  Red  13 

Basic  Red  14 

All  other 

Basic  violet  dyes,  total 

Basic  Violet  1 

Basic  Violet  16 

All  other 

Basic  blue  dyes,  total 

Basic  Blue  5 

All  other 

Basic  Green  1 

Basic  Brown  1 

Basic  Brown  4 

All  other  basic  dyes 

DIRECT  DYES 

Total 

Direct  yellow  dyes,  total 

Direct  Yellow  4 

Direct  Yellow  6 

Direct  Yellow  11 

Direct  Yellow  12 

Direct  Yellow  28 

Direct  Yellow  29 

Direct  Yellow  44 

Direct  Yellow  50 

Direct  Yellow  84 

Direct  Yellow  105 

Direct  Yellow  106 

All  other 

Direct  orange  dyes,  total 

Direct  Orange  8 

Direct  Orange  15 

Direct  Orange  26 

Direct  Orange  29 

Direct  Orange  54 

Direct  Orange  37 

Direct  Orange  39 

Direct  Orange  72 

Direct  Orange  73 

Direct  Orange  81 

Direct  Orange  102 

All  other 

Direct  red  dyes,  total 

Direct  Red  1 

Direct  Red  2 

Direct  Red  4 

See  footnotes  at  end  of  tabic. 


1,000 
pounds 


446 
873 
381 


715 
1,765 


3,736 


1,224 

492 

2,020 


5,154 


147 
480 
781 


37.672 


11,595 


498 
494 

2,439 

201 

237 

32 

1,116 
504 
721 
268 

1,068 

4,017 

2,234 


102 
112 

26 
228 
325 
113 

80 
415 
366 


1,000 
pounds 


1,000 
dollars 


483 
917 
536 


664 
1,839 


930 

450 

2,094 


121 
144 
504 
931 


10,792 


497 
467 

2,348 
207 
234 
43 
911 
485 
720 
239 
893 

3,748 


117 
278 


154 
271 
102 

306 
356 


140 
220 


774 
2,398 
1,213 


1,649 
1,454 
5,256 


423 
259 
806 
,139 


19,448 


877 
844 

2,198 

673 

539 

98 

1,915 


554 
1,592 
8,101 


149 
363 
134 
228 
303 


842 
1,146 


278 
474 
176 


DYES 


TABLE  1,--Dyes:     U.S.  production  and  sales,  1972--Continued 


Dye 


Quantity       Value 


DIRECT  DYES--Continued 


Direct  red  dyes--Cont inued 

Direct  Red  16 

Direct  Red  23 

Direct  Red  24 

Direct  Red  26 

Direct  Red  28 

Direct  Red  31 

Direct  Red  37 

Direct  Red  39 

Direct  Red  72 

Direct  Red  75 

Direct  Red  79 

Direct  Red  80 

Direct  Red  81 

Direct  Red  83 

All  other 

Direct  violet  dyes,  total- 
Direct  Violet  9 

Direct  Violet  51 

All  other 

Direct  blue  dyes,  total  — 
Direct 


Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 
Direct 


lue  15 

22 

25 

lue  71 

lue  76 

lue  78 

lue  80 

lue  86 

lue  98 

lue  120  and  120A- 

lue  126 

lue  218 


Dii 

All  other 

Direct  green  dyes,  total 

Direct  Green  1 -- 

Direct  Green  6 

All  other 

Direct  brown  dyes,  total 

Direct  Brown  2 

Direct  Brown  31 

Direct  Brown  74 

Direct  Brown  95 

Direct  Brown  111 

Direct  Brown  154 

All  other 

Direct  black  dyes,  total 

Direct  Black  4 

Direct  Black  9 

Direct  Black  22 

Direct  Black  38 

Direct  Black  51 

See  footnotes  at  end  of  table. 


1,000 
pounds 


361 
105 

174 

107 
162 


378 
,025 
288 
234 
237 


133 
565 
618 
340 
146 
144 
,099 
,646 


234 
404 
216 

1,712 
258 
121 


391 
340 


853 

,701 

69 


1,000 
pounds 


210 
368 
135 


148 
297 
14 
169 
536 
552 
200 
1,111 

282 


320 

926 

298 

191 

158 

15 

56 

118 

65 

129 

476 

652 

268 

142 

121 

1,101 

1,584 

714 
199 
273 
242 


460 
361 


1,000 
dollars 


220 
636 
786 


344 

433 

716 

56 

518 

1,002 

1,350 


11,896 
751 
1,109 
276 
428 
293 
35 
159 
368 
102 
420 
879 


388 
,271 
,529 


282 

495 

1,011 

2,716 
444 
356 


470 
643 


485 

4,566 

203 


552-743  O  -  74  -  5 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  L— Dyes:     U.S.  production  and  sales,  1972— Continued 


Dye 


Production 


Quantity 


DIRECT  DYES- -Continued 

Direct  black  dyes--Continued 

Direct  Black  80 

All  other 

DISPERSE  DYES 

Total 

Disperse  yellow  dyes,  total 

Disperse  Yellow  3 

Disperse  Yellow  S 

Disperse  Yellow  23 

Disperse  Yellow  33 

Disperse  Yellow  34 

Disperse  Yellow  42 

Disperse  Yellow  54 

All  other 

Disperse  orange  dyes,  total 

Disperse  Orange  3 

Disperse  Orange  5 

Disperse  Orange  17 

Disperse  Orange  25 

All  other 

Disperse  red  dyes,  total 

Disperse  Red  1 

Disperse  Red  5 

Disperse  Red  11 

Disperse  Red  15 

Disperse  Red  17 

Disperse  Red  55 

Disperse  Red  60 

Disperse  Red  65 

All  other 

Disperse  violet  dyes,  total-7 

Disperse  Violet  1 

Disperse  Violet  4 

Disperse  Violet  27 

All  other 

Disperse  blue  dyes,  total 

Disperse  Blue  1 

Disperse  Blue  3 

Disperse  Blue  7 

Disperse  Blue  64 

Disperse  Blue  95 

All  other 

Disperse  black  dyes,  total 

Disperse  Black  1 

All  other 

All  other  disperse  dyes 


1,000 
pounds 


813 
595 


8,039 


2,810 

75 

820 

358 

158 

714 

1,030 

2,074 

4,746 


130 
492 
,962 


262 
105 
128 
76 
154 
444 

1,845 
230 

4,920 


233 
556 


351 

1,300 

385 


13,583 


335 
1,110 


1,000 
pounds 


403 
504 


1,000 
dollars 


8,293 


3,143 

1,010 

296 

160 

660 

1,048 

1,976 

4,039 


129 

470 

3,294 


70 

88 

89 

169 

489 

1,685 

219 

4,573 


96 

25 

230 

568 

15,665 


330 

1,289 

376 

491 

13,179 

1,268 


273 
995 


4,425 

1,473 
514 
276 
1,333 
4,076 
4,922 

8,632 


166 
914 

7,273 

26,254 


502 

99 

634 

280 

256 

3,016 

5,698 

490 

15,259 

3,503 


496 
2,541 


48,679 


1,641 

2,266 

2,892 

946 

40,934 

2,238 


465 
1,773 


See  footnotes  at 


if  tablf 


DYES 


TABLE  1.--DYES:  U.S.  production  and  sales^  1972— Continued 


Dye 


Quantity 


FIBER-REACTIVE  DYES 

Fiber-reactive  dyes,  total 

Reactive  yellow  dyes 

Reactive  blue  dyes 

All  other  reactive  dyes 

FLUORESCENT  BRIGHTENING  AGENTS 
Total 

Fluorescent  Brightening  Agent  28 

All  other  fluorescent  brightening  agents 

FOOD,  DRUG,  AND  COSMETIC  COLORS 

Total 

Food,   Drug,   and  Cosmetic  Dyes 

Total 

FD5C  Red  No.  2 

FD5C  Red  No.  3 

FD5C  Yellow  No.  5 

FDSC  Yellow  No.  6 

All  other  food,  drug,  and  cosmetic  dyes 

Dpug  and  Cosmetic  and  External  Drug 
and  Cosmetic  Dyes 

Total 

D6C  Green  dyes 

DSC  Orange  No.  4 

DSC  red  dyes,  total 

DSC  Red  No.  7 

DSC  Red  No.  19 

DSC  Red  No.  21 

DSC  Red  36 

All  other 

All  other  drug  6  cosmetic  and  e.xternal  drug  S 
cosmetic  dyes 

MORDANT  DYES 

Total 

Mordant  yellow  dyes 

Mordant  orange  dyes 

Mordant  red  dyes 

Mordant  brown  dyes,  total 

Mordant  Brown  1 

Mordant  Brown  33 

All  other 

Mordant  black  dyes,  total 

Mordant  Black  11 --- 

Mordant  Black  17 

All  other 

See  footnotes  at  end  of  table. 


1,000 
pounds 


5,699 


481 

749 

2,469 


4,644 


4,351 


971 
292 

1,109 
812 

1,167 


80 
217 


114 
895 


439 
151 
305 


1,000 
pounds 


3,562 


1,000 
dollars 


15,582 


482 

739 

2,341 


1,580 
25,862 


4,323 


1,088 
265 

1,167 
890 
913 


1,711 


6.S1 
139 
287 


2,010 
36,259 


17,752 


2,923 
2,356 
3,601 
2,376 
6,496 


102 
107 


1,027 


160 
353 
251 


857 
164 
215 


SYNTHETIC  QR^AHK   CHF^ICALS.  1972' 
TABLE  1.— Dyes:     U.S.  production  and  sales^  1972— Continued 


Dye 


1,000 
pounds 


MORDANT  DYES--Continued 

All  other  mordant  dyes 

SOLVENT  DYES 

Total 

Solvent  yellow  dyes,  total 

Solvent  Yellow  14 

All  other 

Solvent  orange  dyes,  total 

Solvent  Orange  5 

All  other 

Solvent  red  dyes,  total 

Solvent  Red  26 

Solvent  Red  49 

All  other 

Solvent  blue  dyes,  total 

Solvent  Blue  38 

All  other 

Solvent  Green  3 

Solvent  Brown  12 

All  other  solvent  dyes 

VAT  DYES 

Total 

Vat  yellow  dyes,  total 

Vat  Yellow  2,  8-1/2°, 

Vat  Yellow  4,  12-1/2-i 

All  other 

Vat  orange  dyes,  total 

Vat  Orange  1,  20«. 

Vat  Orange  2,  12% 

Vat  Orange  3,  13-1/2% 

Vat  Orange  9,  12% 

Vat  Orange  15,  10% 

All  other 

Vat  red  dyes,  total 

Vat  Red  1,  13^ 

Vat  Red  13,  11% 

All  other 

Vat  violet  dyes,  total 

Vat  Violet  1,  11% 

Vat  Violet  9,  12% 

Vat  Violet  13,  6-1/4% 

All  other 

Vat  blue  dyes,  total 

Vat  Blue  6,  8-1/3% 

Vat  Blue  18,  13% 

All  other 

See  footnotes  at  end  of  table. 


121 
S19 


2,362 

1,691 

147 
1,544 


1,044 

2,671 
900 
328 


529 
417 
349 


177 
186 


2,911 

656 

28,471 


1,000 
pounds 


614 
965 


131 
1,531 


4,648 


218 
1,111 


999 
416 


267 
171 
504 
152 


1,000 
dollars 


22,319 


3,685 


154 
1,253 


669 
5,332 


9,017 

3,645 

904 

115 

249 

1,317 

2,787 

3,482 
1,028 
1,056 
1,398 


896 

784 
647 


DYES 
TABLE  1.~Dyes;     U.S.  production  and  sales,  1972— Continued 


Dye 


Quantity 


Unit 
value' 


1,000 
pounds 


VAT  DYES- -Continued 

Vat  green  dyes,  total 

Vat  Green  1,  6% 

Vat  Green  5,  10°> 

All  other 

Vat  brown  dyes,  total 

Vat  Brown  1,  1  Ti 

Vat  Brown  3,  ll^j 

All  other 

Vat  black  dyes,  total 

Vat  Black  25,  12-1/2% 

Vat  Black  27,  12-1/2% 

All  other 

All  other  dyes^ 


1,800 
1,402 
2,179 


826 

644 

3,348 


1,381 

606 

1,327 

23,015 


1,000 
pounds 


1,000 
dollars 


2,187 
1,887 
2,078 

4,986 


875 

808 

3,303 

5,602 


1,503 

688 

1,411 

21,931 


2,101 
2,307 


9,758 


1,549 
1,623 
6,586 


1,746 
1,024 
1,787 


Per 

pound 


1.11 

1.11 


1.77 
2.01 
1.99 


1.27 
1.16 
1.49 

1.27 


.74 


Calculated  from  rounded  figures. 
'  Includes  oxidation  bases,  ingrain  dyes,  sulfur  dyes,  and  miscellaneous  dyes.  Statistics  for  these  groups  of 
dyes  may  not  be  published  separately  because  publication  would  disclose  information  received  in  confidence. 


SYNTHETIC  ORGANIC  CHENICALS,  1972 
TABLE  lA,— Dyes:     U.S.  production  and  sales^  by  class  of  application^  1972 


Class  of  application 


Quantity 


Unit 
value' 


1,000 
pounds 


Total 

Acid 

Azoic  dyes  and  components: 

Azoic  compos itions 

Azoic  diazo  components,  bases  (Fast  color  bases) — 
Azoic  diazo  components,  salts  (Fast  color  salts) — 
Azoic  coupling  components  (Naphthol  AS  derivatives) 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent  brightening  agents 

Food,  drug,  and  cosmetic  colors 

Mordant 

Solvent 

Vat 

All  other^ 


1,000 
:>ounds 

254,536 


1,000 
do  I  lavs 


29,739 

2,515 
1,226 
3,569 
2,905 
17,999 

39,927 
3,699 
27,321 
4,644 
1,465 
12,468 
55,140 
23,015 


28,039 

2,021 

743 

3,178 

2,360 

17,824 

34,519 

38,327 

3,562 

27,442 

4,609 

1,711 

11,959 

56,311 

21,931 


71,663 

3,397 

1,352 

3,811 

5,693 

48,876 

59,167 

107,576 

15,582 

38,269 

19,788 

2,567 

22,319 

63,312 

16,316 


Per 

pound 


1.68 
1.82 
1.20 
2.41 
2.74 
1.71 
2.81 
4.37 
1.39 
4.29 
1.50 
1.87 
1.12 
.74 


^Calculated  from  rounded  figures. 
Ir.cludes  oxidation  bases,  ingrain  dyes,  sulfur  dyes,  and  miscellaneous  dyes.  Statistics  for  these  groups  of  dyes 
may  not  be  published  separately  because  publication  would  disclose  information  received  in  confidence. 


TABLE  IB.— Dyes:     U.S.  production  and  sales^  by  chemical  class.,  1972 


Chemical  class 


Production 


Unit 
value' 


Aminoketone-- 
Anthraquinone 


Azo,  total 

Monoazo 

Disazo 

Trisazo 

Polyazo 

Not  specified- 


Azoic 

Cyanine 

Ketone  imine — 

Methine 

Nitro 

Oxazine 

Phthalocyanine- 

Quinoline 

Stilbene 

Thiazole 

Tr iaryl me thane - 

Xanthene 

All  other^ 


1,000 
pounds 


263.304 


92,028 


39,018 
29,964 
10,540 
2,691 
9,815 

10,264 

916 

455 

5,576 

1,376 

480 

1,381 

2,705 

30,898 

352 

8,903 

1,167 

151 


1,000 
pounds 


254,536 


1,000 
dollars 


87,398 


60 


38,431 
28,403 
9,519 
2,270 
8,775 

8,365 

885 

611 

5,171 

1,253 

537 

1,474 

2,278 

30,538 

365 

8,443 

1,052 

58,032 


172 
,399 


191,561 


95,724 
57,988 
10,985 
3,641 
23,223 

14,316 
2,168 
1,318 

14,752 
2,429 
2,004 
3,365 
7,876 

38,122 
1,032 

20,386 
6,262 

48,526 


per 

pound 


$1.S8 


1.15 
1.60 

2.65 

1.71 
2.45 
2.16 
2.85 
1.94 
3.73 
2.28 
3.46 
1.25 
2.83 
2.41 
5.95 


Calculated  from  rounded  figures. 
^  Includes  production  and  sales  of  azine,  coumarin,  indigoid,  nitroso,  oxidation  bases,  sulfur,  thiazine,  and  miscel- 
laneous dyes.   Statistics  for  these  groups  of  dyes  may  not  be  published  separately  because  publication  would  disclose 
information  received  in  confidence. 


DYES 
TABLE  2. --Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 

BY  MANUFACTURER,  1972 

[Dyes  for  which  separate  statistics  are  given  in  table  1  are  marked  below  with  an  asterisk  (*);  dyes  not  so  marked  do 
not  appear  in  table  1  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published.   Manufacturers' 
identification  codes  shown  below  are  taken  from  table  3.  An  x  signifies  that  the  manufacturer  did  not  consent  to 
his  identification  with  the  designated  product] 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


ACID  DYES 


*Acid  yellow  dyes: 

Acid  Yellow  1 I  ACY 

Acid  Yellow  3 ',  ACS 

Acid  Yellow  4 SDH 

*Acid  Yellow  11 |  ATL 

Acid  Yellow  14 '  TRC 

*Acid  Yellow  17 i  ACS 

Acid  Yellow  19 BAS 

*Acid  Yellow  23 AAP 

Acid  Yellow  25 GAP 

Acid  Yellow  29 GAP 

*Acid  Yellow  34 ACS 

*Acid  Yellow  36 ACS 

*Acid  Yellow  38 ACS 

*Acid  Yellow  40 ALT 

•Acid  Yellow  42 AAP 

Acid  Yellow  44 AAP 

Acid  Yellow  49 !  DUP 

*Acid  Yellow  54 ACS 

Acid  Yellow  59 VPC 

Acid  Yellow  63 AAP 

•Acid  Yellow  65 ALT 

Acid  Yellow  73 ACS 

*Acid  Yellow  76 ACS 

Acid  Yellow  79 VPC 

*Acid  Yellow  99 CMC 

Acid  Yellow  114 TRC 

Acid  Yellow  121 GAP 

Acid  Yellow  124 ATL 

Acid  Yellow  127 TRC 

Acid  Yellow  128 ALT 

Acid  Yellow  129 TRC 

Acid  Yellow  135 GAP 

"Acid  Yellow  151 ACY 

Acid  Yellow  152 ACY 

*Acid  Yellow  159 ACS 

Acid  Yellow  174 DUP 

Acid  Yellow  175 DUP 

Acid  Yellow  190 HST 

Acid  Yellow  198 DUP 

Other  acid  yellow  dyes ACY 

*Acid  orange  dyes : 

Acid  Orange  1 GAP 

Acid  Orange  2 |  ACS 

Acid  Orange  5 i  ACY 

Acid  Orange  6 ACS 

•Acid  Orange  7 AAP 

VI 

•Acid  Orange  8 ACS 

•Acid  Orange  10 ACS 

Acid  Orange  12 ACS 

*Acid  Orange  24 ACS 

Acid  Orange  31 AAP 

Acid  Orange  45 ACS 

Acid  Orange  51 CMC 

Acid  Orange  52 ACS 

Acid  Orange  56 GAP 

•Acid  Orange  60 ATL 

Acid  Orange  62 TRC 


BDO,  CMC,  VPC. 

ATL,  BDO,  CMG,  DUP,  HN,  PDC,  SDH,  TRC,  VPC. 

CMC,  YAW. 

ACS,  ACY,  GAP,  MRX.,  PDC,  TRC,  VPC,  WJ ,  YAW. 

TRC. 

ATL,  PDC. 

DUP,  GAP,  TRC. 

ATL,  GAP. 

ATL,  DUP,  TRC,  VPC. 

ACY,  GAP,  VPC. 

GAP,  VPC. 

VPC. 

ACY,  HN,  TRC,  VPC. 

ACS. 

FAB,  TRC,  YAW. 

SDH. 

GAP,  TRC. 

CAP,  TRC,  VPC. 


ATL,  DUP,  FAB,  GAP,  HN,  TRC,  VPC. 


ALT,  FAB,  GAP,  HN,  TRC,  VPC. 
TRC,  VPC. 


ALT,  CMG,  GAP,  TRC,  VPC. 


ACS,  ACY,  ATL,  CPC,  DUP,  GAF,  HN,  PDC,  TRC, 


ACY,  AIL,  DUP, 

ACY,  ATL,  DUP, 

PSC. 

ACY,  DUP,  GAP,  TRC,  YAW. 

YAW. 
TRC. 
ATL. 

DUP,  GAF,  HN,  TRC,  VPC. 


GAF,  HN,  TRC,  VPC. 
GAF,  TRC,  VPC,  YAW. 


SYNTHETIC 


iC  CHEMICALS,  1972 


TABLE  2,— Dyes  for  which  U.S,   production  or  sales  were  reported,   identified 

BY   MANUFACTURER,    1972--CoNTI NUED 


Manufacturers'    identification   codes 
(according   to    list   in   table   3) 


aCID  DYES- -Continued 

*Acid  orange  dyes--Continued 

Acid  Orange  63 

*Acid  Orange  64 

Acid  Orange  69 

Acid  Orange   72 

*Acid  Orange   74 

Acid  Orange   76 

*Acid  Orange  86 

*Acid  Orange  116 

Acid  Orange  119 

Acid  Orange  128 

Acid  Orange  132 

Acid  Orange  136 

Other  acid  orange  dyes 

*Acid  red  dyes: 

*Acid  Red  1 

*Acid  Red  4 

Acid  Red  14 

Acid  Red  17 

*Acid  Red  18 

*Acid  Red  26 

Acid  Red  27 

Acid  Red  32 

Acid  Red  35 

Acid  Red  35 

•Acid  Red  37 

Acid  Red  52 

Acid  Red  57 

Acid  Red  66 

*Acid  Red  73 

Acid  Red  80 

*Acid  Red  85 

Acid  Red  87 

*Acid  Red  88 

*Acid  Red  89 

Acid  Red  97 --■ 

*Acid  Red  99 

Acid  Red  106 

Acid  Red  111 

*Acid  Red  114 

*Acid  Red  US 

Acid  Red  119 

Acid  Red  133 

Acid  Red  134 

*Acid  Red  137 

Acid  Red  138 

*Acid  Red  151 

Acid  Red  167 

Acid  Red  175 

Acid  Red  178 

Acid  Red  179 

*Acid  Red  182 

Acid  Red  185 

*Acid  Red  186 

Acid  Red  191 

Acid  Red  194 

Acid  Red  201 

Acid  Red  211 

Acid  Red  212 

Acid  Red  213 

*Acid  Red  266 

Acid  Red  277 

Acid  Red  299 

Acid  Red  509 


GAF, 

TRC. 

ACS, 

ACY, 

DUP. 

ACY. 

GAF. 

CMG, 

GAF, 

TRC . 

TRC. 

ACS, 

ALT, 

CMG, 

IRC. 

ACS, 

ALT, 

CMG, 

FAB, 

GAF, 

TRC, 

VPC, 

YAW. 

TRC. 

DUP. 

DUP. 

DUP. 

ALT, 

GAF, 

TRC, 

VPC. 

ACS, 

ACY, 

ATL, 

BDO, 

DUP 

GAF, 

SDH, 

TRC,  VPC,  YAW 

AAP, 

ATL, 

BDO, 

GAF, 

PDC 

TRC, 

VPC, 

YAW. 

ACS, 

ATL, 

GAF, 

PDC, 

YAW 

ACS, 

ATL, 

TRC. 

ACS, 

ATL, 

BDO, 

GAF, 

TRC 

ACY, 

ATL, 

CPC. 

ACS. 

GAF. 

YAW. 

AAP, 

GAF. 

ACS, 

ATL, 

DUP, 

GAF, 

HN, 

TRC. 

GAF. 

AIL, 

TRC. 

AAP, 

ATL. 

ACS, 

ACY, 

ATL, 

DUP, 

GAF 

PSC 

TRC 

VPC,  YAW. 

ATL, 

ICI. 

ACb, 

ALT, 

DUP, 

GAF, 

HN, 

VPC, 

YAW. 

SDH. 

ACS, 

ACY, 

AIL, 

UUP, 

GAF 

TRC 

SDH 

YAW. 

AAP, 

ATL, 

BDO, 

GAF, 

HN. 

ATL, 

GAF. 

ATL, 

FAB, 

HN, 

TRC, 

YAW . 

YAW. 

ATL. 

ACS, 

ALT, 

.ATL 

DUP, 

GAF 

TRC 

VPC 

ACb, 

AIL, 

GAF 

ALT, 

ATL. 

GAF. 

TRC. 

ACS, 

ATL, 

DUP, 

GAF 

HN, 

TRC. 

ALT. 

AAP, 

ACY, 

ALT 

ATL 

DUP 

HN, 

TRC, 

VPC,  YAW. 

ACS, 

ATL, 

DUP, 

TRC 

DUP. 

DUP. 

TRC 

ACS, 

ALT, 

ATL, 

BDO 

CMG 

DUP 

GAF 

HN. 

TRC 

ATL 

CMG, 

GAF 

VPC 

TRC 

TRC 

TRC 

DUP 

TRC 

TRC 

DUP 

TRC 

VPC 

VPC 

ALT 

TRC 

TRC 

DYES 


TABLE  2. 


-Dyes  for  which  U.S.  production  or  sales  were  reported^  identified 

BY   MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification   codes 
(according  to   list    in   table   3) 


ACID  DYES--Continued 


et  dyes : 
olet   1-- 


t  dye 


*Acid  red  dyes--Continued 

•Acid   Red   337 

Acid   Ked   350 

Other  acid  red  dyes 

*Acid  vio 
•Acid  V 
*Acid  V 
*Acid  V 
*Acid  V 
*Acid  V 

Acid  V 

Aciv  V 

Acid  V 
•Acid  V 
•Acid  V 

Acid  V 

Acid  V 

Acid  V 

Other  a 
•Acid  blue 

Acid  B 
•Acid  B 
•Acid  B 

Acid  B 

Acid  B 

Acid  B 
•Acid  B 
•Acid  B 

Acid  B 

Acid  B 
•Acid  B 
•Acid  B 
*Acid  B 
•Acid  B 
•Acid  B 

Acid  B 

Acid  B 

Acid  B 
•Acid  B 

Acid  B 

Acid  B 

Acid  B 

Acid  B 

Acid  B: 

Acid  B 

Acid  B 
•Acid  B 

•Acid  B 

•Acid  B 

Acid  B 

Acid  B 

Acid  B 

•Acid  B 

Acid  B 

Acid  B 

Acid  B 

Acid  B 

Acid  B 

♦Acid  B 

Acid  B 


DUP,  TRC,  VPC. 
GAF. 

ALT,  CMC,  DUP,  GAF,  TRC,  VPC. 


olet  3--- 
olet  7--- 
olet  12-- 
olet  17-- 
olet  29-- 
olet  34-- 
olet  41-- 
olet  43-- 
olet  49-- 
olet  56-- 
olet  58-- 
olet  76-- 
cid  violf 
dyes : 

ue  1 

ue  7 

ue  9 

ue  15 

ue  20 

ue  23 

ue  25 

ue  27 

ue  29 

ue  34 

ue  40 

ue  41 

ue  43 

ue  45 

ue  62 


ue  74- 
ue  78- 


ue  104- 
ue  113- 


ue  118 

ue  120 

ue  122 

ue  127 

ue  145 

ue  158  and  158A- 

ue  165 

ue  179 

ue  198 

ue  203 

ue  221 

ue  230 

ue  231 


Other  acid  blue  dyes- 


BDO 
ACS 
AAP 
BDO 
DUP 
HSH 
AIL 
CMG 
ATL 
ACS 
GAF 
GAF 
ACS 
CMG 

ACS 
ACS 
ACS 
GAF 
ACS 
TRC 
ACS 
ATL 
PDC 
ACS 
ACS 
ATL 
ACS 
ACY 
ACS 
CMG 
GAF 
ACS 
ACS 
ATL 
ICI 
GAF 
TRC 
ACS 
HSC 
ACS 
ACS 
Tl 
ACS 
ACS 
DUP 
CMG 
ACS 
BDO 
DUP 
GAF 
VPC 
VPC 
VPC 
ACS 
TRC 
ACY,  ALT,  ATL,  GAF,  HN,  TRC,  VPC. 


CMG,  GAF. 

ACY,  TRC,  YAW. 

ACS,  ATL,  BDO,  CMG,  GAF,  TRC,  VPC. 

CMG,  DUP,  GAF. 

GAF,  SDH. 

ICI. 

CMG,  HSH,  ICI. 

ACY,  SDH,  FRC. 


GAF. 

ACY,  ATL,  GAF,  VPC. 

GAF,  SDH. 


ATL,  BDO,  CMG,  DUP,  GAF,  TRC,  VPC. 

BDO,  CMG,  GAF. 

YAW. 

ALT,  ATL,  BDO,  CMG,  DUP,  GAF,  ICI,  TRC,  VPC. 

BDO,  CMG. 

ICI,  TRC. 

ATL,  CMC,  DUP,  GAF,  HN,  TRC. 

ALT,  BDO,  CMG,  GAF. 


DUP. 

ATL,  BDO,  DUP,  GAF,  ICI,  IRC. 

TRC. 


ATL,  YAW. 

GAF. 

ALT,  ATL,  BDO,  CMG,  UUP,  FAB,  GAF,  HN,  PDC, 
:,  YAW. 
ATL,  HN. 
ATL,  GAF. 


DUP. 

CMG,  GAF,  HN,  TRC,  VPC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972   ■ 
TABLE  2. —Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 

BY  MANUFACTURER,  1972--CONTINUED 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


ACID  DYES--Continued 

"Acid  green  dyes: 

Acid  Green  1 

*Acid  Green  3 

Acid  Green  5 

*Acid  Green  9 

Acid  Green  12 

*Acid  Green  16 

Acid  Green  19 

*Acid  Green  20 

Acid  Green  22 

*Acid  Green  25 

Acid  Green  35 

Acid  Green  41 

Acid  Green  50 

Acid  Green  58 

Acid  Green  70 

Acid  Green  84 

Other  acid  green  dyes 

*Acid  brown  dyes: 

Acid  Brown  1 

Acid  Brown  6 

*Acid  Brown  14 

Acid  Brown  19 

Acid  Brown  22 

Acid  Brown  28 

Acid  Brown  31 

Acid  Brown  45 

Acid  Brown  96 

Acid  Brown  97 

Acid  Brown  98 

Acid  Brown  152 

Acid  Brown  158 

Acid  Brown  243 

Other  acid  brown  dyes 

*Acid  black  dyes : 

*Acid  Black  1 

Acid  Black  2 

*Acid  Black  24 

Acid  Black  26,  26A  and  26B 

Acid  Black  29 

Acid  Black  48 

*Acid  Black  52 

Acid  Black  53 

Acid  Black  58 

Acid  Black  60 

Acid  Black  92 

*Acid  Black  107 

Acid  Black  108 

Acid  Black  139 

Acid  Black  140 

Acid  Black  172 

Other  acid  black  dyes 

AZOIC  DYES  AND  COMPONENTS 

Azoic  Compositions 

Azoic  yellow  dyes: 

'Azoic  Yellow  1 

*Azoic  Yellow  2 

Azoic  Yellow  3 

Other  azoic  yellow  dyes 


ACS 

ACY, 

DUP. 

ACS 

ACY, 

GAP, 

TRC 

CAP 

ACS 

ACY, 

GAP 

GAP 

ACS 

GAP, 

TRC. 

ALT 

ATL 

BDO, 

GAP, 

PDC 

TRC 

GAP 

ACS 

ATL, 

GAP, 

HSH 

ICI 

TRC,  VPC 

TRC 

ICi 

VPC. 

ACY 

GAP. 

TRC 

TRC 

VPC 

ACY 

ALT, 

VPC. 

GAP 

GAP 

AAP 

ACY, 

DUP. 

GAP 

TRC 

YAW. 

TRC 

DUP 

TRC 

GAP 

TRC 

ACY 

ACY 

ACY 

TRC, 

YAW. 

GAP 

GAP 

GAP 

ACY 

ALT, 

DUP, 

GAP 

VPC 

YAW. 

AAP 

ACS, 

ACY, 

ATL 

DUP 

GAP,  HN, 

ACS 

ACY. 

ACS 

DUP, 

GAP. 

ATL 

DUP, 

TRC 

GAP 

YAW. 

ACY 

TRC. 

ACS 

ATL, 

DUP, 

PAB 

GAP 

HN,  TRC, 

PSC 

CMC 

TRC . 

BOO 

TRC. 

ACY 

ACS 

DUP, 

GAP, 

TRC 

GAP 

VPC 

CMC 

VPC 

ALT 

ATL, 

UN, 

PDC, 

VPC, 

YAW. 

ALL,  ATL,  SDH. 

ALL,  ATL,  BUC, 

ATL,  BUC. 
ATL. 


DYES 

TABLE  2.— Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 

BY  MANUFACTURER,  1972~CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


AZOIC  DYES  AND  COMPONENTS- -Continued 
Azoic  Compositions- -Continued 

Azoic  orange  dyes: 

*Azoic  Orange  3 

Azoic  Orange  10 

Azoic  red  dyes: 

*Azoic  Red  1 

*Azoic  Red  2 

"Azoic  Red  6 

Azoic  Red  12 

Azoic  Red  16 

Azoic  Red  73 

Azoic  Red  74 

Other  azoic  red  dyes 

Azoic  violet  dyes: 

Azoic  Violet  1 

Other  azoic  violet  dyes 

Azoic  blue  dyes : 

Azoic  Blue  2 

*Azoic  Blue  3 

Azoic  Blue  6 

Azoic  Blue  7 

Other  azoic  blue  dyes 

•Azoic  green  dyes: 

Azoic  Green  1 

Other  azoic  green  dyes 

Azoic  brown  dyes: 

Azoic  Brown  3 

Azoic  Brown  7 

•Azoic  Brown  9 

Azoic  Brown  10 

Azoic  Brown  26 

Other  azoic  brown  dyes 

*Azoic  black  dyes: 

Azoic  Black  1 

Azoic  Black  4 

Azoic  Black  15 

Other  azoic  black  dyes 

Azoic  Diazo  Components,   Bases 
(Fast  Color  Bases) 

Azoic  Diazo  Component  2,  base 

Azoic  Diazo  Component  3,  base 

*Azoic  Diazo  Component  4,  base 

Azoic  Diazo  Component  5,  base 

Azoic  Diazo  Component  8,  base 

*Azoic  Diazo  Component  10,  base 

Azoic  Diazo  Component  11,  base 

Azoic  Diazo  Component  12,  base 

Azoic  Diazo  Component  13,  base 

Azoic  Diazo  Component  14,  base 

Azoic  Diazo  Component  28,  base 

*Azoic  Diazo  Component  32,  base 

Azoic  Diazo  Component  34,  base 

Azoic  Diazo  Component  44,  base 

Azoic  Diazo  Component  46,  base 

Azoic  Diazo  Component  48,  base 

Other  azoic  diazo  components,  base 


ALL, 

ATL, 

BUC, 

X. 

BUC. 

ALL, 

ATL, 

BUC, 

SDH, 

X. 

ALL, 

ATL, 

BUC, 

GAF, 

X. 

AIL, 

BUC, 

SDH, 

X. 

ATL. 

ATI. 

GAF. 

GAP. 

ALL, 

X. 

ATL, 

BUC. 

ALL. 

ATL. 

ALL, 

ATL, 

BUC, 

GAF, 

HST, 

SDH,    X 

ATL. 

GAF. 

ATL, 

GAF. 

ATL. 

ALL, 

BUC. 

X. 

ATL, 

BUC. 

ALL, 

.ATL, 

BUC, 

GAF, 

HST, 

VPC,    X 

ATL, 

BUC. 

GAF. 

ALL, 

ATL, 

GAF, 

VPC. 

HST. 

ATL, 

BUC, 

GAF. 

GAF. 

ALL, 

ATL, 

GAF. 

ATL,  BUC. 

BUC. 

ALL,  BUC,  GAF,  SDH. 

ATL,  GAF. 

SDH. 

ATL,  BUC,  GAF. 

ATL. 

BUC,  SDH. 

ATL,  BUC. 

AAP. 

ALL,  BUC,  GAF. 

ALL,  ATL,  BUC. 

ALL. 

BUC. 

ATL. 

GAF. 

ALL. 


SYNTHETIC  ORGANICAL  CHEMICALS.  1°72 
TABLE  2,— Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 

BY   MANUFACTURER.    1972~CONTINUED 


Manufacturers'    identification   codes 
(according   to    list    in  table    3J 


AZOIC  DYES  AND  COMPONENTS--Continued 


Azoic  Diazo  Components,   Salts 
(Fast  Colov  Salts) 


*Azoic 
Azoic 
♦Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
*Azoic 
Azoic 
Azoic 
*Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
*Azoic 
Azoic 
Other 


AZOIC 

Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 
Azoic 

*Azoic 

*Azoic 
Azoic 
Azoic 

*Azoic 

*Azoic 
Azoic 

*Azoic 
Azoic 

*Azoic 
Azoic 
Azoic 

*Azoic 
Azoic 
Other 


Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
Diazo 
azoic 


salt- 
salt- 
salt- 
salt- 
salt- 


salt-- 
salt- 
salt- 


Component  1 
Component  2 
Component  3 
Component  5 
Component  6 
Component  8 
Component  9 
Component  10 
Component  11 
Component  12,  salt 
Component  13,  salt 
Component  14,  salt 
Component 
Component 
Component  32,  salt 

14,  salt 

15,  salt 

16,  salt 
;7,  salt 


salt- 
salt- 


Component 
Component 
Component 
Component 

Component  41,  salt 

Component  42,  salt 

Component  44,  salt 

Component  48,  salt 

Component  49,  salt 

Component  121,  salt 

diazo  components,  salts 

Azoio  Coupling  Components 
(Naphthol  AS  and  Derivatives ) 


Coupling  Component  2 

Coupling  Component  3 

Coupling  Component  4 

Coupling  Component  5 

Coupling  Component  7 

Coupling  Component  8 

Coupling  Component  10 

Coupling  Component  11 

Coupling  Component  12 

Coupling  Component  13 

Coupling  Component  14 

Coupling  Component  IS 

Coupling  Component  16 

Coupling  Component  17 

Coupling  Component  18 

Coupling  Component  19 

Coupling  Component  20 

Coupling  Component  21 

Coupling  Component  24 

Coupling  Component  29 

Coupling  Component  34 

Coupling  Component  35 

Coupling  Component  45 

Coupling  Component  107 

azoic  coupling  components- 


AAP,  ALL, 
BUC. 

AAP,  ALL, 

AAP,  ALL, 

AAP,  BUC, 

AAP,  ALL, 

AAP,  ALL, 

ALL,  BUC, 

AAP,  ALL, 

AAP,  ALL, 

AAP,  ALL. 
AAP. 

ALL,  BUC. 

ALL,  BUC, 
ALL. 

ALL,  GAP. 

BUC,  GAP. 
GAP. 
GAP. 

ALL,  BUC. 

ALL,  GAP. 

ALL,  BUC. 

BUC,  SDH. 

AAP,  ALL, 
GAP. 
ALL. 


BUC,  GAP,  SDH. 

BUC,  GAP,  SDH. 

BUC,  GAP,  SDH. 

GAP. 

BUC,  GAP. 

BUC,  GAP ,  SDH. 

GAP. 

BUC. 

BUC,  GAP,  SDH. 

BUC,  GAP,  SDH. 


GAP,  SDH. 


AIL, 

BUC, 

GAP, 

PCW. 

ALL, 

BUC, 

PCW. 

ATL, 

BUC, 

GAP. 

BUC. 

BUC, 

HST, 

PCW, 

SDH. 

ATL, 

BUC, 

PCW. 

ATL, 

PCW. 

ATL, 

BUC, 

PCW. 

ATL, 

BUC, 

PCW . 

GAP, 

HST. 

ATL, 

BUC, 

PCW. 

ALL, 

BUC, 

GAP, 

PCW. 

BUC. 

ATL, 

BUC, 

PCW. 

ALL, 

ATL, 

BUC, 

GAP,    PCW 

BUC, 

GAP, 

PCW. 

ATL, 

BUC, 

GAP, 

PCW. 

ATL, 

BUC, 

PCW. 

PCW. 

ATL, 

BUC, 

PCW. 

ATL, 

BUC, 

PCW. 

ALL, 

BUC, 

HST, 

PCW. 

ATL, 

BUC, 

GAP. 

HST. 

ATL, 

GAP, 

VPC. 

DYES 

TABLE  2,— Dyes  for  which  U.S.  production  or  sales  were  reported^  identified 

BY   MANUFACTURER^    1972— CONTINUED 


Manufacturers'    identification   codes 
(according   to   list    in   table   3) 


BASIC  DYES 

*Basic  yellow  dyes: 

Basic  Yellow  1 

*Basic  Yellow  2 

*Basic  Yellow  11 

*Basic  Yellow  15 

Basic  Yellow  15 

Basic  Yellow  21 

Basic  Yellow  28 

Basic  Yellow  29 

Basic  Yellow  51 

Basic  Yellow  57 

Basic  Yellow  41 

Basic  Yellow  52 

Basic  Yellow  53 

Other  basic  yellow  dyes 

*Basic  orange  dyes: 

Basic  Orange  1 

*Basic  Orange  2 

*Basic  Orange  21 

Basic  Orange  24 

Basic  Orange  25 

Basic  Orange  26 

Basic  Orange  27 

Basic  Orange  28 

Basic  Orange  51 

Basic  Orange  39 

Other  basic  orange  dyes 

*Basic  red  dyes: 

Basic  Red  1 

Basic  Red  2 

Basic  Red  9 

Basic  Red  12 

*Basic  Red  13 

•Basic  Red  14 

Basic  Red  15 

Basic  Red  16 

Basic  Red  17 

Basic  Red  18 

Basic  Red  19 

Basic  Red  22 

Basic  Red  29 

Basic  Red  30 

Basic  Red  46 

Basic  Red  49 

Basic  Red  73 

Other  basic  red  dyes 

*Basic  violet  dyes: 

•Basic  Violet  1 

Basic  Violet  2 

Basic  Violet  3 

Basic  Violet  4 

Basic  Violet  7 

Basic  Violet  10 

Basic  Violet  11 

Basic  Violet  13 

Basic  Violet  14 

Basic  Violet  15 

•Basic  Violet  16 

Basic  Violet  18 

Basic  Violet  24 

Other  basic  violet  dyes 


DUP 
ACS 
ACS 
ACS 
DUP 
ACS 
VPC 
DUP 
DUP 
ACY 
ACY 
DUP 
DUP 
AIL 

ACS 
ACS 
ACS 
DUP 
DUP 
DUP 
VPC 
VPC 
ACY 
DUP 
DUP 

BAS 
ACS 
DSC 
ACY 
ACS 
ACS 
ATL 
DUP 
DUP 
ATL 
DUP 
ACY 
BAS 
ACY 
ACS 
DUP 
DUP 
ATL 

ACS 
DSC 
DSC 
DSC 
ATL 
ACY 
ACY 
DSC 
DSC 
DUP 
ATL 
ACY 
DUP 
ACY 


ACY,  DUP. 

ACY,  ATL.  DUP.  GAF,  TRC,  VPC. 

.ATL,  DUP,  GAF,  VPC. 


VPC. 
DUP. 


BAS,  DUP,  EKT,  GAF. 

ACY,  DUP,  GAF,  PSC,  TRC. 

ACY,  DSC,  DUP,  GAF,  PSC,  TRC. 

ALT,  ATL,  DUP,  GAF,  TRC,  VPC. 


DUP. 

DUP. 

HSC. 

DUP. 

ATL,  GAF,  TRC,  VPC. 

ACY,  ATL,  DUP,  FAB,  GAF,  VPC. 

DUP,  GAF,  TRC. 


DUP,  GAF,  VPC. 
TRC. 


TRC. 
GAF. 


DUP,  EKT,  VPC. 

ACY,  DSC,  DUP,  HSC. 

DUP. 
DUP. 
GAF. 
DUP,  GAF. 


DUP.  FAB,  GAF,  TRC,  VPC. 


SYNTHETIC  ORGANIC  CHEfllCALS.  Wl 


TABLE  2, 


-Dyes  for  which  U,S,  production  or  sales  were  reported,   identified 
by  manufacturer,  1972--c0ntinued 


Dye 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


BASIC  DYES--Continued 


*Basic  blue  dyes 
Basic  B] 
Basic  B] 
Basil 
Basic  Bl 
*Basic 
Basic 
Basic  Bl 
Basic  Bl 
Basic  Bl 
Basic  Bl 
Basic  Bl 
Basic  B] 
Basic  B] 
Basic  Bl 


ue 


Basic  B] 

Basic  B] 

Basic  B] 

Basic  Bl 

Basic  Bl 

Basic  B] 
Basi 

Basic  Bl 
Basil 
Basi( 


ue  11- 
ue  21- 
ue  22- 
ue  26- 
ue  3S- 
ue  41- 
ue  45- 
ue  47- 


ue  76- 
ue  77- 
ue  82- 


lue  87 

lue  97 

Other  basic  blue  dyes-- 
Basic  green  dyes: 

*Basic  Green  1 

Basic  Green  3 

Basic  Green  4 

Basic  green  7 

Basic  brown  dyes; 

*Basic  Brown  1 

Basic  Brown  2 

*Basic  Brown  4 

Other  basic  brown  dyes- 
Basic  black  dyes : 

Basic  Black  9 

Other  basic  black  dyes- 


DIRECT  DYES 


•Direct  yellow  dyes; 

'Direct  Yellow  4-- 

Direct  Yellow  5-- 

*Direct  Yellow  6-- 

Direct  Yellow  7-- 

Direct  Yellow  8-- 

*Direct  Yellow  11- 

•Direct  Yellow  12- 

Direct  Yellow  20- 

Direct  Yellow  23- 

Direct  Yellow  26- 

Direct  Yellow  27- 

*Direct  Yellow  28- 

*Direct  Yellow  29- 

Direct  Yellow  34- 

Direct  Yellow  39- 

Direct  Yellow  41- 

*Direct  Yellow  44- 

*Direct  Yellow  50- 

Direct  Yellow  59- 


DSC, 

GAP, 

SDH, 

VPC. 

DSC. 

DUP, 

GAP, 

HST. 

DUP. 

DSC, 

SDH, 

VPC. 

ACY. 

DSC, 

DUP, 

SDH. 

ACS, 

ACY, 

DUP. 

DSC, 

SDH. 

DUP. 

ACS, 

DUP. 

DSC, 

DUP. 

DUP. 

IRC. 

VPC. 

VPC. 

ACY, 

BAS. 

GAP. 

VPC. 

EKT. 

ACY. 

DUP. 

DUP, 

TRC. 

DUP. 

DUP. 

ACS, 

ALT, 

BAS, 

EKT,    VPC 

ACS, 

ACY, 

DSC, 

DUP. 

DUP. 

ACS, 

ACY, 

DSC, 

DUP,    VPC 

DSC. 

ACS,  ACY,  DUP,  GAP,  PSC,  TRC. 

GAP. 

ACS,  ACY,  DSC,  DUP,  GAP,  PSC,  TRC. 

DUP. 

VPC. 

ALT,  DSC,  VPC. 


ACS, 
ACS, 
ACS, 
ATL. 
ACS, 
ACS, 
ACS, 
TRC. 
DUP. 
ATL, 
GAP. 
ACS, 
ATL, 
ALT, 
TRC. 
ATL. 
ACS, 
ALT, 
ATL. 


ACY,  ATL,  DUP,  GAP, 

ACY,  GAP. 

ACY,  DUP,  GAP,  TRC. 


HN,  TRC,  VPC. 


ATL,  GAP. 

ACY,  ALT,  DUP,  GAP,  HN,  SDH,  TRC,  VPC. 

ACY,  ATL,  CMC,  DUP,  FAB,  GAP,  HN,  TRC. 


ATL,  DUP,  GAP,  PDC,  TRC. 
DUP,  GAP. 


ATL,  DUP,  FAB,  GAP,  HN,  HSH,  TRC,  VPC. 
■ATL,  DUP,  PAB,  GAP,  HN,  HSH,  TRC,  VPC. 


DYES 

TABLE  2.--DVES  for  which  U.S.  production  or  sales  were  reported^   identified 
BY  manufacturer,  1972--Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


DIRECT  DYES--Continued 

'Direct  yellow  dyes--Continued 

Direct  Yellow  63 

Direct  Yellow  81 

♦Direct  Yellow  84- 

Direct  Yellow  103 

♦Direct  Yellow  105 

•Direct  Yellow  106 

Direct  Yellow  107 

Direct  Yellow  114 

Direct  Yellow  117 

Direct  Yellow  118 

Direct  Yellow  119 

Direct  Yellow  120 

Direct  Yellow  127 

Direct  Yellow  131 

Direct  Yellow  132 

Other  direct  yellow  dyes 

♦Direct  orange  dyes: 

Direct  Orange  1 

Direct  Orange  6 

♦Direct  Orange  8 

Direct  Orange  10 

Direct  Orange  11 

♦Direct  Orange  15 

♦Direct  Orange  26 

♦Direct  Orange  29 

♦Direct  Orange  54 

♦Direct  Orange  37 

♦Direct  Orange  39 

Direct  Orange  59 

Direct  Orange  61 

Direct  Orange  67 

♦Direct  Orange  72 

♦Direct  Orange  73 

Direct  Orange  74 

Direct  Orange  78 

Direct  Orange  79 

Direct  Orange  80 

♦Direct  Orange  81 

Direct  Orange  83 

Direct  Orange  88 

♦Direct  Orange  102 

Direct  Orange  110 

Other  direct  orange  dyes 

♦Direct  red  dyes: 

♦Direct  Red  1 

♦Direct  Red  2 

♦Direct  Red  4 

Direct  Red  7 

Direct  Red  10 

Direct  Red  13 

♦Direct  Red  16 

Direct  Red  20 

♦Direct  Red  23 

♦Direct  Red  24 

♦Direct  Red  26 

♦Direct  Red  28 

♦Direct  Red  31 

Direct  Red  32 

♦Direct  Red  37 


DUP. 
AIL. 
ATL, 
ACS. 
ALT, 
ACS, 
ACS, 
ACY. 
TRC. 
TRC. 
DUP. 
DUP. 
DUP, 
DUP. 
VPC . 
AAP, 

AAP, 
ACS. 
ACS, 
AAP. 
GAP. 
ACS, 
ACS, 
ATL, 
ACS, 
ACY, 
ACY, 
DUP, 
TRC. 
VPC. 
ACS, 
DUP, 
DUP, 
VPC. 
DUP. 
VPC. 
DUP, 
GAP. 
DUP. 
ACS, 
TRC. 
ALT, 

DUP, 
ACS, 
ACS. 
ATL. 
AAP. 
YAW. 
ACS, 
ATL, 
ACS, 
AAP, 
ACS, 
ACS, 
ACS, 
ACS. 
ACS, 


DUP,  FAB,  GAP,  HN,  TRC,  VPC. 

HN,  TRC. 

ALT,  FAB,  GAF,  UN,  TRC. 

TRC. 


ACY,  ALT,  ATL,  DUP,  FAB,  GAF,  HSH,  TRC,  VPC. 
ALT,  ATL,  BDO. 
DUP,  FAB,  GAF,  YAW. 


ACY,  DUP,  GAF,  HN,  TRC. 

ATL,  GAF,  HSM,  TRC. 

FAB,  HN,  TRC,  VPC. 

ATL,  CMG,  DUP.  GAF. 

ATL,  CMG,  GAF. 

ALT,  ATL,  CMG,  DUP,  FAB,  GAF,  UN. 

GAF. 


ATL,  FAB,  »i,    HSH,  IRC,  VPC. 

GAF,  TRC,  VPC. 

HSH. 


ACY,  ATL,  DUP,  GAF. 

ATL. 

FAB,  GAF,  TRC,  YAW. 

ATL,  DUP,  FAB,  HN,  TRC. 

ATL,  TRC,  VPC. 


ATL,  DUP,  TRC. 

GAF. 

ATL,  DUP,  FAB,  GAF,  HN,  TRC,  VPC. 

ACS,  ATL,  FAB,  HN,  HSH,  TRC,  VPC. 

ATL,  DUP,  FAB,  GAF,  HN,  HSH,  TRC. 

DUP,  FAB,  YAW. 

ATL,  GAF,  HSH. 

DUP,  GAF,  YAW. 


SYNTHETIC  ORG'\NIC  CHEMICALS.  1972 
TABLE  2,— Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 

BY   manufacturer.    1972— CONTINUED 


Manufacturers'    identification  codes 
(according   to    list    in  table   3) 


DIRECT  DYES--Continued 

*Direct   red  dyes--Continued 

♦Direct   Red   39 

Direct  Red  62 

♦Direct  Red  72 

Direct  Red  73 

♦Direct  Red  75 

Direct  Red  76 

♦Direct  Red  79 

♦Direct  Red  80 

♦Direct  Red  81 

♦Direct  Red  83 

Direct  Red  84 

Direct  Red  95 

Direct  Red  100- 

Direct  Red  117 

Direct  Red  120 

Direct  Red  122 

Direct  Red  12i--=- 

Direct  Red  127  and  127A 

Direct  Red  139 

Direct  Red  149 

Direct  Red  152 

Direct  Red  153 

Direct  Red  209 

Direct  Red  212 

Direct  Red  236 

Other  direct  red  dyes 

♦Direct  violet  dyes; 

Direct  Violet  7 

♦Direct  Violet  9 

Direct  Violet  14 

Direct  Violet  22 

Direct  Violet  47 

Direct  Violet  48 

♦Direct  Violet  51 

Direct  Violet  62 

Direct  Violet  66 

Direct  Violet  67 

Other  direct  violet  dyes 

♦Direct  blue  dyes: 

♦Direct  Blue  1 

♦Direct  Blue  2 

♦Direct  Blue  6 

♦Direct  Blue  8 

Direct  Blue  14 

♦Direct  Blue  15 

♦Direct  Blue  22 

Direct  Blue  24 

♦Direct  Blue  25 

Direct  Blue  26 

Direct  Blue  67 

♦Direct  Blue  71 

Direct  Blue  74 

Direct  Blue  75 

♦Direct  Blue  76 

♦Direct  Blue  78 

♦Direct  Blue  80 

Direct  Blue  81 

♦Direct  Blue  86 


ATL 
ATL 
ACS 
ACS 
ATL 
GAP 
ATL 
ACS 
ACS 

v: 

ACS 
ATL 
VPC 
ATL 
DUP 
CMC 
ATL 
ATL 
ATL 
VPC 
ATL 
CMC 
ATL 
TRC 
VPC 
DUP 
ALT 

ACS 
ACS 
AIL 
DUP 
GAP 
ACS 
ACS 
ACY 
ATL 
DUP 
ALT 


AAP 
AAP 
ACS 
ACS 
ACS 
ACS 
ATL 
ACS 
ATL 
ATL 
ACS 
DUP 
TRC 
ACS 
ACS 
ACS 
ATL 
ALT 


DUP,  GAP,  TRC,  YAW. 

TRC. 

ATL,  DUP,  GAP,  IRC. 

ATL. 

CMG,  GAP. 

CMC,  HN,  TRC,  VPC. 

ALT,  ATL,  FAB,  HN,  HSH,  SDH,  TRC,  VPC. 

ACY,  ALT,  ATL,  BDO,  DUP,  GAP,  HN,  HSH,  PDC,  TRC, 
PC,  YAW. 

ALT,  ATL,  PAB,  HN,  HSH,  TRC,  VPC. 


TRC,  VPC. 

GAP. 

CMG. 


CMG. 
VPC. 


ATL,  DUP,  GAP,  HN,  HSH,  TRC,  VPC. 


ATL. 

ATL,  UUP,  GAP,  HN,  TRC. 


ATL,  DUP. 

TRC. 

VPC. 

ACS,  ACY,  ATL,  CMG,  DUP,  PAB,  GAP,  HN,  IRC, 
:,  YAW. 

ACS,  DUP,  FAB,  GAP,  HN,  HSH,  TRC,  VPC,  YAW. 
ACS,  ACY,  DUP,  GAP,  HN,  HSH,  YAW. 
ALT,  ATL,  DUP,  GAP. 
ATL,  HN,  TRC. 
ATL,  DUP,  GAP,  VPC,  YAW. 
ATL,  CMG. 
YAW. 
ATL,  GAP,  TRC,  YAW. 

TRC. 

ATL,  GAP,  TRC. 


ALT,  ATL,  GAP,  HN,  HSH,  TRC,  VPC. 

ATL,  CMG,  DUP,  TRC. 

ALT,  ATL,  DUP,  FAB,  GAP,  HN,  HSH,  TRC,  VPC. 

ATL,  DUP,  PAB,  GAP,  HN,  ICC,  SDH,  TRC. 


DYES 
TABLE  2.— Dyes  for  which  U.S.  production  or  sales  were  reported^   identified 

BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


DIRECT  DYES--Continued 


Direct  Bl 

*Direct 

Direct  Bl 

Direct  Bl 

•Direct  Bl 

♦Direct  Bl 

Direct  Bl 

Direct  Bl 

Direct  Bl 

Direct  Bl 

Direct  Bl 
Direc 

Direct  Bl 

•Direct  Bl 

Direct  Bl 

Direct  Bl 


•Direct  blue  dyes- -Continued 

Direct  Blue  87 

lue  91 

lue  98 

lue  100 

lue  104 

lue  120  and  120A-- 

lue  126 

lue  136 

lue  143 

lue  151 

lue  160 

lue  189 

lue  191 

lue  199 

lue  218 

lue  224 

lue  263 

Other  direct  blue  dyes 

•Direct  green  dyes : 

•Direct  Green  1 

•Direct  Green  6 

Direct  Green  8 

Direct  Green  26 

Direct  Green  27 

Direct  Green  28 

Direct  Green  38 

Direct  Green  39 

Direct  Green  45 

Direct  Green  47 

Direct  Green  51 

Direct  Green  69 

Other  direct  green  dyes — 
•Direct  brown  dyes : 

Direct  Brown  1 

Direct  Brown  lA 

*Direct  Brown  2 

Direct  Brown  6 

•Direct  Brown  31 

Direct  Brown  32 

Direct  Brown  40 

Direct  Brown  44 

Direct  Brown  48 

Direct  Brown  59 

•Direct  Brown  74 

•Direct  Brown  95 

Direct  Brown  106 

•Direct  Brown  111 

Direct  Brown  112 

•Direct  Brown  154 

Direct  Brown  218 

Other  direct  brown  dyes 

•Direct  black  dyes: 

•Direct  Black  4 

Direct  Black  8 

•Direct  Black  9 

Direct  Black  17 

Direct  Black  19 

•Direct  Black  22 

Direct  Black  36 


ICI. 

TRC. 

ATL, 

GAF, 

TRC, 

VPC 

ALT, 

FAB, 

HN. 

DUP. 

ATL. 

DUP, 

FAB, 

HN, 

TRC. 

ATL, 

UUP, 

HSH, 

TKC 

VPC. 

GAP. 

DUP. 

ATL, 

TRC. 

TRC. 

FAB, 

TRC. 

AAP, 

ACS, 

GAF. 

DUP, 

GAF. 

ACS, 

ALT, 

ATL, 

DUP 

FAB 

GAF 

HN, 

TRC.  VPC 

ATL. 

DUP. 

ALT, 

ATL, 

DUP, 

GAF 

VPC 

AAP, 

ACS, 

DUP, 

FAB 

GAF 

TRC 

YAW 

AAP, 

ACS, 

DUP, 

FAB 

GAF 

HN, 

TRC, 

YAW. 

TRC. 

DUP, 

TRC. 

DUP, 

TRC. 

TRC. 

DUP, 

GAF. 

GAF. 

ATL, 

VPC. 

ATL, 

DUP, 

GAF. 

TRC. 

TRC. 

ACY, 

ALT, 

TRC. 

HN. 

GAF, 

TRC, 

YAW. 

AAP, 

ACS, 

ACY, 

DUP 

FAB, 

GAF 

HN, 

HSH,  TRC 

YAW. 

AAP, 

ATL, 

DUP, 

GAF 

YAW 

GAF. 

AAP. 

GAF, 

YAW. 

AAP. 

YAW 

AAP, 

ACS, 

DUP. 

ACS, 

ATL, 

DUP, 

FAB 

GAF 

HN, 

HSH, 

TRC,  YAW 

GAF. 

DUP, 

GAF, 

TRC, 

VPC 

ATL. 

ACS, 

DUP, 

FAB, 

YAW 

ACS. 

ALT, 

HSH, 

VPC. 

ACS, 

FAB, 

GAF, 

HN, 

YAW. 

YAW. 

ACS, 

ATL, 

DUP. 

GAF. 

ATL, 

HN, 

TRC. 

ALT, 

ATL, 

GAF, 

HN, 

TKC, 

VPC, 

YAW. 

AAP. 

552-743  O  -  74  -  6 


SYNTHETIC  nRfiflNIC  CHEniCai.S,  1972 

TABLE  2. —Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 
BY  manufacturer,  1972--Continued 


DIRECT  DYES--Continued 

'Direct  black  dyes--Continued 

Direct  Black  37 

♦Direct  Black  38 

Direct  Black  44 

•Direct  Black  51 

Direct  Black  56 

Direct  Black  71 

Direct  Black  75 

Direct  Black  78 

♦Direct  Black  80 

Direct  Black  95 

Direct  Black  190 

Other  direct  black  dyes 

DISPERSE  DYES 

♦Disperse  yellow  dyes: 

Disperse  Yellow  1 

Disperse  Yellow  2 

♦Disperse  Yellow  3 

♦Disperse  Yellow  5 

Disperse  Yellow  8 

♦Disperse  Yellow  23 

Disperse  Yellow  31 

Disperse  Yellow  32 

♦Disperse  Yellow  33 

♦Disperse  Yellow  34 

♦Disperse  Yellow  42 

Disperse  Yellow  50 

♦Disperse  Yellow  54 

Disperse  Yellow  58 

Disperse  Yellow  64 

Disperse  Yellow  67 

Disperse  Yellow  68 

Disperse  Yellow  69 

Disperse  Yellow  77 

Disperse  Yellow  85 

Disperse  Yellow  86 

Disperse  Yellow  87 

Disperse  Yellow  88 

Disperse  Yellow  89 

Disperse  Yellow  93 

Disperse  Yellow  95 

Disperse  Yellow  96 

Disperse  Yellow  118 

Disperse  Yellow  125 

Other  disperse  yellow  dyes 

♦Disperse  orange  dyes: 

♦Disperse  Orange  5 

♦Disperse  Orange  5 

Disperse  Orange  16 

♦Disperse  Orange  17 

Disperse  Orange  21 

♦Disperse  Orange  25 

Disperse  Orange  29 

Disperse  Orange  30 

Disperse  Orange  37 

Disperse  Orange  38 

Disperse  Orange  41 

Disperse  Orange  44 

Disperse  Orange  57 


Manufacturers'  identi 
(according  to  list 


catioi 
table 


codes 
5) 


FAB,  GAP, 
ATL,  DUP, 


HSH,  YAW. 


GAP,  TRC. 


YAW. 


ICC,  TRC. 


AAP. 

ACS, 

TRC. 

ACS, 

ACS. 

ATL. 

GAP. 

ACS,  FAB,  HN. 

ACS,  ATL,  FAB,  HN,  HSH, 

ACS. 

ACS,  HN. 

ACY,  ALT,  ATL,  HSH,  TRC,  YAW. 


GAP. 

DUP. 

AAP,  ALT,  DUP,  GAP,  HN,  ICC,  TRC. 

GAF,  HN,  ICC. 

TRC. 

AAP,  ALT,  DUP,  EKl,  GAF, 

GAP. 

DUP. 

AAP,  EKT,  GAF,  ICC,  TRC. 

AAP,  EKT,  ICC. 

AAP,  BUC,  DUP,  EKT,  GAF,  HN,  ICC,  SDC, 

AAP,  ATL,  DUP,  GAF,  HN,  ICC,  SDL,  TKC. 

HST. 

BUC,  DUP. 

DUP. 

HST. 

ACY. 

VPC. 

EKT. 

AAP,  EKT. 

EKT. 

EKT. 

EKT. 

VPC. 

VPC. 

VPC . 

AAP. 

SDC. 

ATL,  BUC, 


EKT,  GAF,  MAY,  SDC,  TRC,  VPC. 


DUP, 
BUC, 


GAF,  HN,  TRC. 
EKT,  GAF,  SDC. 


AAP 

AAP 

.AAP. 

AAP,  EKT,  GAF,  HN, 

TRC. 

DUP,  EKT,  HN,  TRC. 

AAP,  GAF. 

ICC,  TRC. 

TRC. 

TRC. 

DUP. 

DUP. 

EKT. 


DYES 
TABLE  2, —Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 

BY  MANUFACTURER,  1972— CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


DISPERSE  DYES--Continued 

*Disperse  orange  dyes --Continued 

Disperse  Orange  58 

Disperse  Orange  59 

Disperse  Orange  62 

Disperse  Orange  65 

Disperse  Orange  75 

Disperse  Orange  78 

Disperse  Orange  89 

Disperse  Orange  90 

Disperse  Orange  94 

Other  disperse  orange  dyes 

*Disperse  red  dyes: 

*Disperse  Red  1 

Disperse  Red  4 

•Disperse  Red  5 

Disperse  Red  7 

Disperse  Red  9 

'Disperse  Red  11 

Disperse  Red  13 

•Disperse  Red  15 

•Disperse  Red  17 

Disperse  Red  21 

Disperse  Red  30 

Disperse  Red  51 

Disperse  Red  35 

Disperse  Red  54 

•Disperse  Red  55 

Disperse  Red  59 

•Disperse  Red  60 

•Disperse  Red  65 

Disperse  Red  66 

Disperse  Red  73 

Disperse  Red  78 

Disperse  Red  82 

Disperse  Red  86 

Disperse  Red  90 

Disperse  Red  96 

Disperse  Red  117 

Disperse  Red  133 

Disperse  Red  135 

Disperse  Red  136 

Disperse  Red  137 

Disperse  Red  138 

Disperse  Red  139 

Disperse  Red  140 

Disperse  Red  159 

Disperse  Red  161 

Disperse  Red  162 

Disperse  Red  167 

Disperse  Red  176 

Disperse  Red  177 

Disperse  Red  178 

Disperse  Red  179 

Disperse  Red  180 

Other  disperse  red  dyes 

'Disperse  violet  dyes; 

'Disperse  Violet  1 

•Disperse  Violet  4 

Disperse  Violet  8 

Disperse  Violet  17 


AAP 
EKT 
BUC 
VPC 
DUP 
IRC 
AAP 
AAP 
SDC 
ALT 

AAP 
BUC 
AAP 
MP 
AIL 
AAP 
GAF 
CMC 
AAP 
EKT 
EKT 
ICC 
EKT 
ICC 
DUP 
ACY 
AAP 
DUP 
AAP 
TRC 
ICC 
VPC 
EKT 
VPC 
ACY 
EKT 
VPC 
AAP 
EKT 
EKT 
EKT 
VPC 
AAP 
VPC 
DUP 
DUP 
GAF 
ICC 
ICC 
ICC 
ICC 
ICC 
DUP 

AAP 
AAP 
GAF 
DUP 


EKT. 
ICC. 
DUP. 


ATL,  BUC,  EKT,  GAF,  MAY,  SDC. 

DUP,  EKT,  GAF,  HN,  ICC,  TRC. 

GAF,  TRC. 

EKT,  GAF,  ICC. 
GAF. 

BUC,  DUP,  GAF,  ICC. 

ICC. 

GAF,  HSH,  ICC,  TRC. 

DUP,  EKT,  GAF,  ICC,  TRC. 

TRC. 


GAF,  HN,  ICC,  TRC. 

DUP,  GAF. 

ATL,  DUP,  EKT,  GAF,  HN,  SDC,  TRC,  VPC. 

EKT,  ICC,  TRC. 


TRC. 
GAF. 


EKT,  GAF,  MAY,  SDC,  TRC,  VPC. 


GAF,  HSH,  ICC,  TRC. 
GAF,  ICC. 


SY^ITHETIC  ORGA^JIC  CHEMICALS.  1<^72 

TABLE  2,— Dyes  for  which  U,S,  production  or  sales  were  reported,   identified 
BY  manufacturer,  1972--Conti nued 


Manufacturers'  identification  codes 
{according  to  list  in  table  3) 


DISPERSE  DYES- -Continued 

et  dyes--Continued 

olet  2b 

olet  27 

olet  28 


olet  40 

olet  41 

olet  42 

olet  43 

olet  44 

olet  57 

rse  violet  dyes 
dyes: 

ue  1 

ue  3 

ue  7 


*Disperse  vio 

Disperse  V 
*Disperse  V 

Disperse  V 

Disperse  V 

Disperse  V 

Disperse  V 

Disperse  V 

Disperse  V 

Disperse  V 

Other  dispe 
*Disperse  blue 
*Disperse  B 
*Disperse  B 
*Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B, 

Disperse  b 

Disperse  B 
'Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  K. 

Disperse  B 

Disperse  b 
•Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Disperse  B 

Other  disperse  blue  dyes- 
Disperse  green  dyes 


ue  27-- 
ue  35-- 
ue  54-- 
ue  55-- 
ue  56-- 
ue  60-- 
ue  61-- 
ue  62-- 
ue  64-- 
ue  70-- 
ue  71-- 
ue  72-- 
ue  75-- 
ue  79-- 
ue  81-- 
ue  85-- 
ue  94-- 
ue  95-- 
ue  102- 
ue  109- 
ue  112- 
ue  116- 
ue  117- 
ue  118- 
ue  119- 
ue  120- 
ue  121- 
ue  123- 
ue  125- 
ue  132- 
ue  133- 
ue  138- 
ue  139- 
ue  150- 
ue  152- 
ue  165- 
ue  166- 
ue  172- 
ue  173- 


DUP. 

AAP, 

ACY, 

DUP, 

EKT, 

ICC 

TRC. 

DUP, 

TRC. 

VPC. 

EKT. 

EKT. 

EKT. 

EKT. 

trc. 

GAP, 

SDC. 

AAP, 

GAP, 

ICC, 

TRC 

AAP, 

DUP, 

EKT, 

GAP, 

HN, 

HSH,  ICC,  TRC. 

DUP, 

GAP, 

HN, 

ICC, 

TRC. 

HSU. 

GAP. 

EKT, 

ICC. 

ICI. 

ICC. 

TRC. 

DUP, 

ICC, 

TRC, 

VPC 

DUP. 

DUP. 

DUP, 

EKT, 

GAP, 

SDC 

DUP, 

EKT, 

GAP, 

TRC 

AAP. 

VPC. 

ICI. 

ACY, 

ICC, 

TRC. 

EKT, 

HST, 

TRC 

VPC. 

TRC. 

BAS. 

GAP, 

HST, 

ICC 

EKT. 

DUP. 

EKT. 

ACY. 

EKT. 

EKT. 

EKT. 

EKT, 

GAP. 

EKT. 

EKT. 

TRC. 

DUP. 

DUP. 

VPC. 

VPC. 

DUP. 

HST. 

VPC. 

ICC. 

DUP, 

ICC. 

AAP. 

ALT, 

ATL, 

DUP 

EKT 

GAP, 

HN,  HSH,  ICC,  MAY,  SDC 

TRC,  VPC. 

GAP, 

VPC. 

DYES 

TABLE  2. --Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 
BY  manufacturer,  1972--Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


DISPERSE  DYES--Continued 

Disperse  brown  dyes; 

Disperse  Brown  1 

Disperse  Brown  2 

Disperse  Brown  7 

Disperse  Brown  8 

Disperse  Brown  11 

Other  disperse  brown  dyes 

♦Disperse  black  dyes r 

♦Disperse  Black  1 

Disperse  Black  2 

Disperse  Black  9 

Disperse  Black  33 

Disperse  Black  34 

Other  disperse  black  dyes 

FIBER-REACTIVE  DYES 

♦Reactive  yellow  dyes: 

Reactive  Yellow  1 

Reactive  Yellow  2 

Reactive  Yellow  3 

Reactive  Yellow  4 

Reactive  Yellow  6 

Reactive  Yellow  7 

Reactive  Yellow  13 

Reactive  Yellow  15 

Reactive  Yellow  17 

Reactive  Yellow  18 

Reactive  Yellow  24 

Reactive  Yellow  25 

Reactive  Yellow  31 

Reactive  Yellow  37 

Reactive  Yellow  42 

Reactive  Yellow  62 

Reactive  orange  dyes: 

Reactive  Orange  1 

Reactive  Orange  4 

Reactive  Orange  5 

Reactive  Orange  12 

Reactive  Orange  13 

Reactive  Orange  14 

Reactive  Orange  16 

Reactive  Orange  49 

Reactive  Orange  50 

Reactive  red  dyes: 

Reactive  Red  1 

Reactive  Red  2 

Reactive  Red  4 

Reactive  Red  5 

Reactive  Red  8 

Reactive  Red  11 

Reactive  Red  21 

Reactive  Red  29 

Reactive  Red  31 

Reactive  Red  33 

Reactive  Red  40 

Reactive  Red  41 

Reactive  Red  58 

Reactive  Red  94 

Reactive  Red  105 


AAP,  TRC. 

DUP,  EKT,  GAF. 

EKT. 

VPC . 

AAP. 

CAP,  ICC,  SDC. 

AAP,  ATL,  DUP,  GAF,  TRC. 

ATL,  TRC. 

AAP,  EKT. 

EKT. 

EKT. 

ALT,  ATL,  BUC,  DUP,  GAF,  ICC.  SDC. 


ICI. 
TRC. 
TRC. 
ICI. 
TRC. 
ICI. 
HST 
UST . 
HST. 
ICI. 
HST. 
VPC. 
HST. 
HST. 
ICI, 
ACY. 

ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
HST. 
ACY. 
HST. 

ICI. 
ICI. 
TRC. 
ICI. 
ICI. 
ICI. 
HST. 
ICI. 
ICI. 
ICI. 
VPC. 
VPC. 
ICI. 
HST. 
HST. 


.SYNTHETIC  nPGANIC  CHEMICALS,  W^. 
TABLE  2,— Dyes  for  which  U.S.   production  or  sales  were  reported,   identified 

BY   MANUFACTURERj    1972~CoNTINUED 


Dye 


Manufacturers'  identification  codes 
Caccording  to  list  in  table  3) 


FIBER- REACTIVE  DYES--Continued 

Reactive  violet  dyes: 

Reactive  Violet  1 

Reactive  Violet  4 

Reactive  Violet  5 

*Reactive  blue  dyes: 

Reactive  Blue  2 

Reactive  Blue  3 

Reactive  Blue  4 

Reactive  Blue  5 

Reactive  Blue  7 

Reactive  Blue  19 

Reactive  Blue  21 

Reactive  Blue  25 

Reactive  Blue  29 

Reactive  Blue  30 

Reactive  Blue  38 

Reactive  Blue  71 

Reactive  Blue  89 

Reactive  Blue  90 

Reactive  Blue  91 

Reactive  green  dyes:   Reactive  Green  6 

Reactive  brown  dyes: 

Reactive  Brown  9 

Reactive  Brown  10 

Other  reactive  brown  dyes 

Reactive  black  dyes: 

Reactive  Black  S 

Reactive  Black  9 

FLUOROESCENT  BRIGHTENING  AGENTS 

Fluoroescent  Brightening  Agent  1 

Fluoroescent  Brightening  Agent  6 

Fluoroescent  Brightening  Agent  8 

Fluoroescent  Brightening  Agent  9 

Fluoroescent  Brightening  Agent  22 

Fluoroescent  Brightening  Agent  24 

Fluoroescent  Brightening  Agent  25 

*Fluoroescent  Brightening  Agent  28 

Fluoroescent  Brightening  Agent  30 

Fluoroescent  Brightening  Agent  33 

Fluoroescent  Brightening  Agent  45 

Fluoroescent  Brightening  Agent  46 

Fluoroescent  Brightening  Agent  49 

Fluoroescent  Brightening  Agent  52 

Fluoroescent  Brightening  Agent  54 

Fluoroescent  Brightening  Agent  59 

Fluoroescent  Brightening  Agent  61 

Fluoroescent  Brightening  Agent  68 

Fluoroescent  Brightening  Agent  71 

Fluoroescent  Brightening  Agent  75 

Fluoroescent  Brightening  Agent  102 

Fluoroescent  Brightening  Agent  108 

Fluoroescent  Brightening  Agent  109 

Fluoroescent  Brightening  Agent  114 

Fluoroescent  Brightening  Agent  125 

Fluoroescent  Brightening  Agent  126 

Fluoroescent  Brightening  Agent  128 

Fluoroescent  Brightening  Agent  130 


ICI. 
HST. 
HST. 

TRC. 

ICI. 

ICI. 

ICI,  TRC. 

TRC. 

HST. 

HST. 

ICI. 

VPC. 

VPC. 

HST. 

ICI. 

HST. 

HST. 

HST. 

ICI. 

ICI. 
ICI. 
HST. 


CGY. 
ACY. 
ACY. 
ACY, 
CGY. 
CGY. 
GAF. 
ACY, 
GAF. 
GAF. 
GAF. 
CGY. 
S. 

s. 

CGY. 
CGY. 
ACY. 
CCW, 
ACY, 
GAF. 
DUP, 
GAF. 
GAF- 
VPC. 
ACY. 
SDH. 
SDH. 
ACY. 


GAF,  SDH. 


CCW,  DUP,  SDH,  VPC. 


GAF. 
GAF . 


DYES 

TABLE  2, —Dyes  for  which  U.S,  production  or  sales  were  reported^   identified 
BY  manufacturer,  1972--Conti nued 


Manufacturers'  identification  codes 
faccording  to  list  in  table  3} 


FLUOROESCENT  BRIGHTENING  AGENTS--Continued 

Fluoroescent  Brightening  Agent  158 

Fluoroescent  Brightening  Agent  159 

Other  fluoroescent  brightening  agents 

FOOD,  DRUG,  AND  COSMETIC  COLORS 

foody   Drug,   and  Cosmetic  Dyes 

FDSC  Blue  No.  1 

FD6C  Blue  No.  2 

FD5C  Green  No. 5 

*FDf,C  Red  No.  2 

*FD§C  Red  No.  3 

FD8C  Red  No.  4 

FD5C  Red  No.  40 

FD6C  Violet  No.  1 

*FD5C  Yellow  No.  5 

*FD5C  Yellow  No.  6 

Other  food,  drug,  and  cosmetic  dyes 

Drug  and  Cosmetic  Dyes 

D5C  Blue  No.  6 

D5C  Green  No.  5 

DiiC  Green  No.  6 

D6C  Green  No.  8 

*D5C  Orange  No.  4 

DSC  Orange  No.  5 

DSC  Orange  No.  10 

DSC  Orange  No.  17 

DSC  Red  No.  2 

DSC  Red  No.  3 

DSC  Red  No.  6 

*DSC  Red  No.  7 

DSC  Red  No.  8 

DSC  Red  No.  9 

DSC  Red  No.  10 

DSC  Red  No.  11 

DSC  Red  No.  12 

DSC  Red  No.  13 

DSC  Red  No.  17 

*D6C  Red  No.  19 

*DSC  Red  No.  21 

DSC  Red  No.  22 

DSC  Red  No.  27 

DSC  Red  No.  28 

DSC  Red  No.  30 

DSC  Red  No.  31 

DSC  Red  No.  33 

DSC  Red  No.  34 

*D6C  Red  No.  36 

DSC  Red  No.  37 

DSC  Red  No.  59 

DSC  Violet  No.  2 

DSC  Yellow  No.  5 

DSC  Yellow  No.  6 

DSC  Yellow  No.  7 

DSC  Yellow  No.  8 

DSC  Yellow  No.  10 

DSC  Yellow  No.  11 


ACY. 
ACY. 
ACY,  CCW,  CGY,  GAF,  PCW, 


ACS, 

ALT, 

KON, 

SDH, 

WJ. 

ACS, 

ALT, 

KON, 

SDH, 

WJ. 

WJ. 

ACS, 

ALT, 

KON, 

SDH, 

STG 

ACS, 

ALT, 

KON, 

SDH, 

STG 

ALT, 

KON 

ACS, 

WJ. 

ACS, 

SDH, 

WJ. 

ACS, 

ALT, 

KON, 

STG. 

WJ. 

ACS, 

ALT, 

KON, 

SDH, 

STG 

STG. 

ACS, 

KON. 

ACS, 

KON. 

ACS, 

KON. 

KON, 

SDH. 

ACS, 

KON, 

SNA,  TMS 

SNA, 

TMS. 

TMS. 

SNA. 

KON. 

KON, 

TMS. 

KON, 

SNA, 

TMS. 

KON, 

SNA, 

TMS. 

KON, 

SNA. 

KON, 

SNA, 

TMS. 

KON, 

SNA. 

KON, 

SNA. 

SNA, 

TMS. 

SNA, 

TMS. 

KON. 

ACS, 

KON, 

SNA,  TMS 

KON, 

SNA, 

TMS. 

ACS, 

KON, 

SDH. 

TMS. 

ACS, 

TOS. 

KON, 

TMS. 

KON. 

ACS, 

KON. 

KON. 

ALT, 

KON, 

TMS. 

.\CS. 

SDH. 

ACS. 

KON. 

KON. 

KON. 

KON. 

KON. 

ACS, 

KON. 

SYNTHETIC  ORGVIIC  CHEHICUS,  1972 

TABLE  2.— Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 
BY  manufacturer,  1972— Conti nued 


Manufacturers'  identification  codes 
(according  to  list  in  table  3J 


FOOD,  DRUG,  AND  COSMETIC  COLORS--Cont inued 

Drug  and  Cosmetic  Dyes,   External 

Ext.  D5C  Green  No.  1 

Ext.  DSC  Yellow  No.  1 

Ext.  D6C  Yellow  No.  7 

INGRAIN  DYES 

Ingrain  blue  dyes: 

Ingrain  Blue  1 

Ingrain  Blue  2 

Ingrain  Blue  3 

MORDANT  DYES 

♦Mordant  yellow  dyes: 

Mordant  Yellow  1 

Mordant  Yellow  5 

Mordant  Yellow  8 

Mordant  Yellow  14 

Mordant  Yellow  16 

Mordant  Yellow  20 

Mordant  Yellow  26 

Mordant  Yellow  29 

Mordant  Yellow  30 

Mordant  Yellow  36 

*Mordant  orange  dyes : 

Mordant  Orange  1 

Mordant  Orange  4 

Mordant  Orange  6 

Mordant  Orange  8 

'Mordant  red  dyes : 

Mordant  Red  3 

Mordant  Red  7 

Mordant  Red  9 

Mordant  Red  11 

Mordant  Red  64 

Mordant  violet  dyes:  Mordant  Violet  S 

Mordant  blue  dyes: 

Mordant  Blue  1 

Mordant  Blue  3 

Mordant  Blue  9 

Mordant  Blue  19 

Mordant  green  dyes:   Mordant  Green  36 

•Mordant  brown  dyes : 

*Mordant  Brown  1 

Mordant  Brown  12 

Mordant  Brown  13 

Mordant  Brown  15 

Mordant  Brown  18 

Mordant  Brown  19 

Mordant  Brown  21 

*Mordant  Brown  33 

Mordant  Brown  40 >- 

Mordant  Brown  63 

Mordant  Brown  70 

•Mordant  black  dyes: 

Mordant  Black  3 

Mordant  Black  8 

Mordant  Black  9 

•Mordant  Black  11 

Mordant  Black  13 

•Mordant  Black  17 

Mordant  Black  19 

Mordant  Black  26 

Other  mordant  black  dyes 


ACS,  KON. 
ACS,  KON. 
KON. 


ICI. 
VPC. 
ICI. 


ATL 
TRC 
ACS 
ACS 
ACY 
ACS 
VPC 
GAP 
TRC 
PDC 

ACY 
GAP 
ATL 
TRC 

ACY 
ACY 
MRX 
ACY 
PDC 
PDC 


GAP 
GAP 
CMC 
PDC 

ACS 
PDC 
ACS 
GAP 
ACS 
GAP 
GAP 
ACS 
CMG 
TRC 
DUP 

TRC 
VPC 
ACS 
ACS 
HSH 
ACS 
PDC 
TRC 
CMG 


GAP,  PDC. 

PDC. 
PDC. 

ATL. 
ATL. 


PDC,  TRC. 

PDC. 

GAP,  PDC,  TRC. 


ATL,  BDO,  GAP,  PDC,  TRC. 
PDC, 


CMG,  DUP,  GAP,  TRC,  YAW. 


VPC. 

GAP,  PDC,  TRC. 

GAP. 


.^TL,  VPC. 

ATL,  GAP,  TRC,  VPC. 


ACY,  GAP,  TRC. 


DYES 
TABLE  2.— Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 

BY  manufacturer,  1972— CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


OXIDATION  BASES 

Oxidation  Base  8  and  8A 

Oxidation  Base  21 

Oxidation  Base  22 

Oxidation  Base  25 

Other  oxidation  bases 

SOLVENT  DYES 

'Solvent  yellow  dyes: 

Solvent  Yellow  1 

Solvent  Yellow  2 

Solvent  Yellow  3 

Solvent  Yellow  13 

♦Solvent  Yellow  14 

Solvent  Yellow  19 

Solvent  Yellow  29 

Solvent  Yellow  30 

Solvent  Yellow  33 

Solvent  Yellow  34 

Solvent  Yellow  40 

Solvent  Yellow  42 

Solvent  Yellow  43 

Solvent  Yellow  44 

Solvent  Yellow  45 

Solvent  Yellow  47 

Solvent  Yellow  56 

Solvent  Yellow  71 

Solvent  Yellow  72 

Solvent  Yellow  87 

Other  solvent  yellow  dyes 

'Solvent  orange  dyes: 

Solvent  Orange  2 

'Solvent  Orange  3 

Solvent  Orange  5 

Solvent  Orange  7 

Solvent  Orange  20 

Solvent  Orange  23 

Solvent  Orange  24 

Solvent  Orange  25 

Solvent  Orange  31 

Solvent  Orange  48 

Solvent  Orange  51 

Other  solvent  orange  dyes 

'Solvent  red  dyes: 

Solvent  Red  1 

Solvent  Red  8 

Solvent  Red  22 

Solvent  Red  24 

'Solvent  Red  26 

Solvent  Red  27 

Solvent  Red  33 

Solvent  Red  35 

Solvent  Red  40 

Solvent  Red  41 

'Solvent  Red  49 

Solvent  Red  52 


ACY. 
PDC. 
ACY. 
ACY. 
ACY. 


AAP. 

DUP, 

GAF, 

PSC. 

ACS, 

PSC. 

ACY, 

GAF. 

AAP, 

ACS, 

ACY, 

DUP,  GAF,  PSC 

GAF. 

GAP. 

ACS. 

AAP, 

ACS, 

ACY. 

DSC. 

ACS. 

ACS. 

GAF. 

ACS. 

ACS. 

ACY, 

DUP, 

GAF. 

AAP, 

ACS, 

ACY. 

ACY. 

ACY. 

ACY. 

AAP, 

ATL, 

DSC, 

PAT. 

PSC. 

AAP, 

.ACS, 

ACY, 

DSC,  GAF,  PSC 

GAF. 

ACS, 

ACY, 

GAF. 

ACY, 

GAF. 

ACS. 

DUP. 

ACY, 

DUP 

ACS. 

ACY. 

ACY. 

AAP, 

ACY, 

DSC, 

DUP. 

PSC. 

GAF. 

GAF. 

ACY, 

DUP 

GAF. 

AAP, 

ACS, 

ACY, 

PSC. 

ACS. 

DUP, 

GAF 

GAF. 

GAF. 

DSC. 

ACY, 

DSC, 

DUP, 

GAF. 

AAP, 

ICI 

SYNTHETIC  ORGANIC  CHEMICALS,  197? 
TABLE  2,— Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 

BY  MANUFACTURER,  1972— CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


SOLVENT  UYES--Continued 


*Solvent  red  dye5--Continued 

Solvent  Red  68 

Solvent  Red  69 

Solvent  Red  74 

Solvent  Red  75 

Solvent  Red  105 

Solvent  Red  108 

Solvent  Red  111 

Solvent  Red  115 

Solvent  Red  126 

Other  solvent  red  dyes 

Solvent  violet  dyes: 

Solvent  Violet  8 

Solvent  Violet  9 

Solvent  Violet  13 

Solvent  Violet  14 

Solvent  Violet  17 

Other  solvent  violet  dyes- 
*Solvent  blue  dyes: 

Solvent  Blue  3 

Solvent  Blue  4 

Solvent  Blue  5 

Solvent  Blue  6 

Solvent  Blue  7 

Solvent  Blue  9 

Solvent  Bl 
Solvent  Bl 
Solvent  Bl 
Solvent  Bl 
Solvent  Bl 
*Solvent  Bl 
Solvent  Bl 
Solvent  Bl 
Solvent  Bl 
Solvent  Bl 

Solvent  Blue  74 

Other  solvent  blue  dyes-- 
Solvent  green  dyes: 

Solvent  Green  1 

*Solvent  Green  3 

Other  solvent  green  dyes- 
Solvent  brown  dyes : 

Solvent  Brown  11 

'Solvent  Brown  12 

Solvent  Brown  19 

Solvent  Brown  20 

Solvent  Brown  22 

Solvent  Brown  38 

Other  solvent  brown  dyes- 
Solvent  black  dyes: 

Solvent  Black  3 

Solvent  Black  5 

Solvent  Black  7 

Solvent  Black  12 

Solvent  Black  13 

Solvent  Black  17 

Solvent  Black  26 

Other  solvent  black  dyes- 


ue 

11 

ue 

12 

ue 

16 

ue 

36 

ue 

37 

ue 

38 

ue 

43 

ue 

57 

ue 

58 

ue 

59 

ACS. 

DSC, 

DUP. 

ACS. 

ACS. 

ACY. 

ACY. 

ACY. 

ACY. 

ACY. 

AAP, 

ACY, 

ATL, 

DSC, 

ICI,  PAT 

ACY, 

DSC, 

DUP. 

DSC. 

AAP. 

ATL, 

HSH, 

ICl. 

AAP, 

ICI. 

ACS. 

AAP, 

DSC, 

PAT. 

ACY, 

SW. 

DSC, 

DUP. 

DSC. 

DSC. 

ACY. 

GAP. 

BDO, 

GAP, 

ICI. 

ACS, 

BDO. 

ACS. 

AAP, 

DUP. 

DUP. 

ACS, 

ACY, 

ATL, 

DUP, 

GAP. 

ACS. 

DUP. 

ACY. 

ACY. 

ACS. 

ACY, 

DSC, 

GAP, 

PAT, 

SDH. 

ACY, 

DSC. 

AAP, 

ACS, 

ATL, 

GAP, 

HSH,  PAT 

DSC, 

GAP. 

GAP. 

ACY, 

DSC, 

GAP. 

DUP. 

ACY. 

DUP. 

DUP, 

PSC. 

ACY. 

DSC. 

ACS. 

ACS, 

ACY, 

DSC, 

DUP. 

ACS, 

ACY, 

DSC. 

ACS. 

ACS. 

DUP. 

ACY. 

ATL, 

DSC, 

GAP, 

PAT. 

DYES 
TABLE  2. —Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 

BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
(according  to  list  in  table   3) 


SULFUR   DYES 

Sulfur  yellow  dyes: 

Leuco  Sulfur  Yellow  1 

Leuco  Sulfur  Yellow  2 

Sulfur  Yellow  4 

Leuco  Sulfur  Yellow  4 

Leuco  Sulfur  Yellow  9 

Leuco  Sulfur  Yellow  15 

Other  sulfur  yellow  dyes 

Sulfur  Orange  1 

Sulfur  red  dyes ; 

Leuco  Sulfur  Red  S 

Other  sulfur  red  dyes 

Sulfur  blue  dyes: 

Sulfur  Blue  5 

Sulfur  Blue  7 

Leuco  Sulfur  Blue  7 

Solubilized  Sulfur  Blue  7 

Sulfur  Blue  8 

Leuco  Sulfur  Blue  8 

Sulfur  Blue  9 

Leuco  Sulfur  Blue  11 

Leuco  Sulfur  Blue  13 

Other  sulfur  blue  dyes 

Sulfur  green  dyes: 

Sulfur  Green  2 

Leuco  Sulfur  Green  2 

Leuco  Sulfur  Green  3 

Sulfur  Green  14 

Leuco  Sulfur  Green  16 

Other  sulfur  green  dyes 

Sulfur  brown  dyes: 

Leuco  Sulfur  Brown  1 

Solubilized  Sulfur  Brown  1 

Leuco  Sulfur  Brown  3 

Sulfur  Brown  10 

Leuco  Sulfur  Brown  10 

Solubilized  Sulfur  Brown  10 

Sulfur  Brown  12 

Sulfur  Brown  14 

Leuco  Sulfur  Brown  14 

Leuco  Sulfur  Brown  20 

Sulfur  Brown  26 

Leuco  Sulfur  Brown  26 

Sulfur  Brown  37 

Solubilized  Sulfur  Brown  37 

Leuco  Sulfur  Brown  81 

Leuco  Sulfur  Brown  82 

Other  sulfur  brown  dyes 

Sulfur  black  dyes: 

Sulfur  Black  1 

Leuco  Sulfur  Black  1 

Solubilized  Sulfur  Black  1 

Sulfur  Black  2 

Leuco  Sulfur  Black  2 

Solubilized  Sulfur  Black  2 

Leuco  Sulfur  Black  10 

Sulfur  Black  11 

Leuco  Sulfur  Black  11 

Other  sulfur  black  dyes 


SDC. 

ACY,  SDC. 
SDC. 
SDC. 
SIC. 
AC\ . 

ACY,  SDC. 
SIC. 

SDC. 
SDC. 

ACY. 

ACY,  SDC. 

ACY,  SDC,  SIC. 

SDC. 

SDC. 

SDC. 

SDC. 

SDC. 

ACY. 

SDC. 

SDC. 
SDC. 
SDC. 
SDC. 
SDC. 
ACY,  SDC. 

SIC. 

SIC. 

SDC. 

SDC. 

SDC,  STC. 

SDC. 

SDC. 

SDC. 

SDC. 

STC. 

ACY. 

STC. 

SDC. 

SDC. 

ACY. 

ACY. 

ACY,  SDC. 

SDC. 

ACY,  SDC,  STC. 

STC. 

SDC. 

ACY,  SDC. 

SDC. 

ACY. 

SDC. 

SDC. 

SDC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972  ' 

TABLE  2. --Dyes  for  which  U.S.  production  or  sales  were  reported,  identified 
BY  manufacturer.  1972--Continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  3J 


VAT  DYES 

*Vat  yellow  dyes: 

Vat  Yellow  1,  12-1/2% 

*Vat  Yellow  2.  8-1/2°. 

Vat  Yellow  3,  12-l/2°6 

*Vat  Yellow  4,  12-1/2% 

Solubilized  Vat  Yellow  4,  37-1/2°* 

Vat  Yellow  10,  10% 

Vat  Yellow  14,  12-1/2% 

Vat  Yellow  IS,  11-1/2% 

Vat  Yellow  21,  9-1/2% 

Vat  Yellow  22,  10% 

Vat  Yellow  33,  15% 

Other  vat  yellow  dyes 

*Vat  orange  dyes: 

*Vat  Orange  1,  20% 

Solubilized  Vat  Orange  1,  26% 

*Vat  Orange  2,  12% 

*Vat  Orange  3,  13-1/2% 

Vat  Orange  4,  6% 

Vat  Orange  5,  10% 

Solubilized  Vat  Orange  5,  30% 

Vat  Orange  7,  11% 

*Vat  Orange  9,  12% 

Vat  Orange  11,  6% 

*Vat  Orange  15,  10% 

Other  vat  orange  dyes 

*Vat  red  dyes: 

*Vat  Red  1,  13% 

Solubilized  Vat  Red  1,  37% 

Vat  Red  10,  18% 

Vat  Red  12,  8-1/2% 

*Vat  Red  13,  11% 

Vat  Red  14,  10% 

Vat  Red  15,  10% 

Vat  Red  16,  11% 

Vat  Red  23 

Vat  Red  29,  18% 

Vat  Red  32,  20% 

Vat  Red  41,  20% 

Vat  Red  52,  10% 

Other  vat  red  dyes 

*Vat  violet  dyes: 

*Vat  Violet  1,  11% 

Vat  Violet  2,  20% 

Vat  Violet  3,  15% 

*Vat  Violet  9,  12% 

*Vat  Violet  13,  6-1/4% 

Vat  Violet  14,  12-1/2% 

Vat  Violet  17,  12-1/2% 

Vat  Violet  21 

Other  vat  violet  dyes 

*Vat  blue  dyes: 

Vat  Blue  1,  20% 

Vat  Blue  4,  10% 

Vat  Blue  5,  16% 

*Vat  Blue  6,  8-1/3% 

Solubilized  Vat  Blue  6,  17-1/2%-- 

Vat  Blue  12,  6-1/2% 

Vat  Blue  14,  8-1/3% 

Vat  Blue  16,  16-1/2% 


ACS 
AAP 
DUP 
ATL 
HST 
GAF 
IRC 
ACY 
ATL 
DUP 
TRC 
GAF 

ACY 
HST 
ACY 
DUP 
DUP 
HSi 
HST 
GAF 
ACY 
DUP 
AAP 
SDC 

AAP 
HST 
GAF 
DUP 
DUP 
GAF 
HST 
DUP 
DUP 
GAF 
DUP 
HST 
DUP 
TRC 

ACY 
ACY 
HST 
DUP 
ATL 
ATL 
DUP 
VPC 
GAF 

ACS 
ACY 
ATL 
ACY 
HST 
DUP 
DUP 
DUP 


ATL,  GAF,  ICI,  TRC,  VPC. 


GAF,  HST,  VPC. 
ICI. 


VPC. 
MAY,  VPC. 


ATL,  DUP,  GAF,  HST,  ICl,  IRC,  VPC. 


DUP,  GAF,  ICI,  TRC. 
GAF,  HST. 


HST,  TRC. 

DUP,  GAF,  ICl,  TRC. 


ACS,  ACY,  GAF,  ICI,  TRC,  VPC. 


ATL,  ACY,  HST,  ICl. 


GAF,  TRC. 

HST. 

TRC. 


ATL,  DUP,  GAF,  ICI,  MAY,  TRC. 
HST. 


GAF,  ICI,  MAY,  TRC. 
DUP,  GAF,  HST,  ICI,  TRC. 


DUP,  GAF. 

HST. 

DUP,  GAF,  ICl,  TRC. 


DYES 
TABLE  2.— Dyes  for  which  U.S.  production  or  sales  were  reported,   identified 

BY   manufacturer,    1972— CONTINUED 


VAT  DYES--Continued 

"Vat  blue  dyes --Continued 

*Vat    Blue   18,    13% 

Vat    Blue  20,    14% 

Vat   Blue  29 

Vat    Blue   39,    n"., 

Vat   Blue  43 

Vat   Blue  53,    20-1/2% 

Vat    Blue  60 

Vat    Blue  67 

Other  vat  blue  dyes 

*Vat  green  dyes: 

*Vat  Green   1,   6% 

Solubilized  Vat  Green   1,    12-1/2-0 

*Vat   Green  3,    lOi 

Solubilized  Vat  Green  3,  26% 

Vat  Green  8,  8-1/2% 

Vat  Green  9,  12-1/2% 

Vat  Green  20,  6% 

Vat  Green  32 

Other  vat  green  dyes 

*Vat  brown  dyes: 

*Vat  Brown  1,  11% 

*Vat  Brown  3,  11% 

Vat  Brown  5,  13% 

Vat  Brown  11,  12% 

Vat  Brown  12,  12-1/2% 

Vat  Brown  13,  17% 

Vat  Brown  20,  10-1/2% 

Vat  Brown  28,  22% 

Vat  Brown  29,  13% 

Vat  Brown  40,  14% 

Vat  Brown  57,  12.8% 

Other  vat  brown  dyes 

*Vat  black  dyes: 

Solubilized  Vat  Black  1,  27-1/2% 

Vat  Black  9,  16% 

Vat  Black  13,  14% 

Vat  Black  22,  19% 

*Vat  Black  25,  12-1/2% 

*Vat  Black  27,  12-1/2% 

Vat  Black  34,  16% 

Vat  Black  37 

Vat  Black  38,  20% 

Vat  Black  52,  18-1/2% 

Other  vat  black  dyes 

All  other  dyes 


Manufacturers'  identification  codes 
[according  to  list  in  table  3J 


AAP, 

ACY 

.AAP. 

■ACS 

GAP. 

GAP. 

SDC. 

GAP. 

DUP. 

HST. 

CAF, 

MAY 

ACY, 

DUP 

ICI. 

AAP, 

ACY 

ICI. 

ATL, 

DUP 

ACY, 

ATL 

DUP. 

VPC. 

ACY, 

GAP 

ACY, 

DUP 

AAP, 

ACY 

ACY, 

HST 

MAY, 

TRC 

DUP. 

MAY. 

GAP. 

ICI. 

ACY. 

DUP. 

HST, 

TRC 

GAP, 

SDC 

HST. 

GAP, 

MAY 

DUP. 

ACY. 

TRC 

AAP, 

ACY 

ACY, 

BDO 

ICI. 

GAP. 

GAP. 

ACY. 

ATL, 

GAP 

ATL,  DUP,  GAP,  MAY,  TRC. 

ACY,  ATL,  DUP,  GAP,  MAY,  SDC.  TRC. 


GAP,  ICI,  MAY,  TRC. 

ATL,  DUP,  GAP,  ICI,  MAY,  TRC. 

GAP. 

GAP,  HST,  MAY,  SDC,  TRC. 


GAP,  ICI,  MAY,  TRC. 
DUP,  GAP,  ICI,  TRC,  VPC. 


DUP,  GAP,  ICI,  MAY,  TRC. 
DUP,  GAP,  ICI,  MAY,  TRC. 


MAY,  SDC,  TRC. 


ACY,  DUP,  GAP,  HSH,  PAT,  SDC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3, --Dyes;     Directory  of  manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 


[Names  of  dye  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission  for  1972  are  listed  bela 
in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

AAP 

American  Aniline  Products,  Inc. 

ICC 

Inmont  Corp. 

ACS 

Allied  Chemical  Corp.,  Specialty  Chemicals 
Div. 

ICI 

ICI  America,  Inc. 

ACY 

American  Cyanamid  Co. 

ALL 

Alliance  Chemical,  Inc. 

ALT 

Crompton  5  Knowles  Corp.,  Dyes  §  Chemicals 

Div. 

KON 

H.  Kohnstamm  6  Co.,  Inc. 

ATL 

Atlantic  Chemical  Corp. 

MAY 
MRX 

Otto  B.  May,  Inc. 

Max  Marx  Color  §  Chemical  Co. 

BAS 

BASF  Wyandotte  Corp. 

EDO 

Benzenoid  Organics,  Inc. 

sue 

Blackman-Uhler  Chemical  Co. 

PAT 

Morton-Norwich  Products,  Inc.,  Morton 
Co.  Div. 

Chemical 

PCW 

Pfister  Chemical  Works 

CCW 

Cincinnati  Malacron  Chemicals,  Inc. 

PDC 

Berncolors-Poughkeepsie,  Inc. 

CGY 

Ciba-Geigy  Corp. 

PSC 

Passaic  Color  g  Chemical  Co. 

CNG 

Nyanza,  Inc. 

CPC 

Childs  Pulp  Colors,  Inc. 

S 

Sandoz,  Inc.,  Sandoz  Color  6  Chemical 

5  Div. 

SDC 

Martin-Marietta  Corp.,  Sodyeco  Div. 

DSC 

Dye  Specialties,  Inc. 

SDH 

Sterling  Drug,  Inc.,  Hilton-Davis  Ch 

smical 

DUP 

E.  I.  duPont  de  Nemours  §  Co.,  Inc. 

SNA 
STC 
STG 

Co.  Div. 
Sun  Chemical  Corp. 
Sou-Tex  Chemical  Co.,  Inc. 
Stange  Co. 

EKT 

Eastman  Kodak  Co. ,  Tennessee  Eastman 
Co.  Div. 

sw 

Sherwin-Williams  Co. 

FAB 

Fabricolor  Manufacturing  Corp. 

TMS 
TRC 

Sterling  Drug,  Inc.,  Thomasset  Colors 
Toms  River  Chemical  Corp. 

Div. 

GAF 

GAF  Corp.,  Chemical  Div. 

VPC 

Baychem  Corp.,  Verona  Div. 

HN 

Tenneco  Chemicals,  Inc. 

use 

Chemetron  Corp.,  Pigments  Div. 

WJ 

Warner-Jenkinson  Manufacturing  Co. 

HSH 

Harshaw  Chemical  Co.  Div.  of  Kewanee 
Oil  Co. 

HST 

American  Hoechst  Corp. 

YAW 

Y.  S.  Young,  Young  Aniline  Works  Div. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix 


91 


ORGANIC  PIGMENTS 

As  the  terms  are  used  in  this  report,  organic  pigments  are  toners 
and  lakes  derived  in  whole  or  in  part  from  benzenoid  chemicals  and  colors. 

Statistics  on  production  and  sales  of  all  organic  pigments  in  1972 
are  given  in  table  1.  1/     Statistics  on  sales  of  a  few  selected  pigments 
by  commercial  forms  (dry  full-strength  form,  dry  extended  form,  dry  dis- 
persions, aqueous  dispersions,  and  flushed  colors)  are  given  in  table  lA. 
Individual  toners  and  lakes  are  identified  in  this  report  by  the  names 
used  in  the  third  edition  of  the  Colour  Index. 

Total  production  of  organic  pigments  in  1972  was  65.9  million  pounds-- 
13.0  percent  more  than  the  58.3  million  pounds  produced  in  1971  and  16.6 
percent  more  than  the  56.5  million  pounds  produced  in  1970.  Total  sales 
of  organic  pigments  in  1972  amounted  to  53.2  million  pounds,  valued  at 
$149.3  million,  compared  with  47.1  million  pounds,  valued  at  $130.0  mil- 
lion, in  1971  and  47.2  million  pounds,  valued  at  $123.0  million,  in  1970. 
In  terms  of  quantity,  sales  of  organic  pigments  in  1972  were  13.1  percent 
greater  than  in  1971  and  12.8  percent  greater  than  in  1970;  in  terms  of 
value,  sales  in  1972  were  14.9  percent  greater  than  in  1971  and  21.5  per- 
cent greater  than  in  1970. 

Production  of  toners  in  1972  amounted  to  62.9  million  pounds--14.1 
percent  more  than  the  55.1  million  pounds  reported  for  1971.  Sales  in 
1972  were  50.5  million  pounds,  valued  at  $145.9  million,  compared  with 
44.2  million  pounds,  valued  at  $126.6  million,  in  1971.   Sales  in  1972 
were  thus  14.1  percent  more  than  those  in  1971  in  terms  of  quantity, 
and  15.3  percent  more  in  terms  of  value.  The  individual  toners  listed 
in  the  report  which  were  produced  in  the  largest  quantities  in  1972 
were  Pigment  Yellow  12,  6.5  million  pounds;  Pigment  Blue  15,  beta  form, 
6.0  million  pounds;  and  Pigment  Red  49,  barium  toner,  4.6  million  pounds. 

Production  of  lakes  totaled  3.0  million  pounds  in  1972--6.8  percent 
less  than  the  3,2  million  pounds  reported  for  1971.   Sales  of  lakes  in 
1972  amounted  to  2.7  million  pounds,  valued  at  $3.4  million,  compared 
with  sales  in  1971  of  2.8  million  pounds,  valued  at  $3.4  million.   Sales 
in  1972  were  thus  3.4  percent  less  than  those  in  1971  in  terms  of  quantity ^ 
and  substantially  unchanged  in  terms  of  value. 

For  each  of  15  selected  pigments,  or  groups  of  pigments,  table  lA 
gives  data  on  sales  by  commercial  forms.   Pigment  Yellow  12,  Pigment  Red 
53,  Pigment  Blue  15,  beta  form,  and  Pigment  Blue  19  were  sold  principally 
in  the  flushed  form.   The  remaining  7  pigments,  or  groups  of  pigments, 
for  which  statistics  are  published  were  sold  principally  in  the  dry  full- 
strength  form.   Statistics  on  sales  by  commercial  forms  could  not  be 
published  for  Pigment  Red  49,  calcium  toner.  Pigment  Red  49,  sodium  toner. 
Pigment  Red  90,  and  Pigment  Violet  3,  fugitive,  without  revealing  the 
operations  of  individual  companies. 

1/   See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers by  codes.  These  codes  are  listed  in  table  3. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972. 
TABLE  1,— Organic  pigments:     U.S.  production  and  sales.  1972 

[Listed  below  are  all  organic  pigments  for  which  any  reported  data  on  production  or  sales  may  be  published.   (Leaders 
^  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 

Table  2  lists  all  organic  pigments  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufac- 

turers  of  each] 


Pigment 


Grand  total - 


Total- 


Yellow  toners,  total 

Acetoacetarylide  yellows; 

Pigment  Yellow  1,  C.I.  11  680-- 
Pigment  Yellow  3,  C.I.  11  710-- 
Pigment  Yellow  74,  C.I.  11  741- 

Benzidine  yellows,  total 

Pigment  Yellow  12,  C.I.  21  090- 
Pigment  Yellow  14,  C.I.  21  095- 
Pigment  Yellow  17,  C.I.  21  105- 
Other  benzidine  yellows 

AH  other ^ 


Orange  toners,  total - 
Pigment  Orange  5,  C 
Pigment  Orange  13, 
Pigment  Orange  16, 
Pigment  Orange  34, 
All  other 


12  075-- 
.  21  110- 
.  21  160- 
.  21  115- 


Red  toners,  total 

Naphthol  reds,  total 

Pigment  Red  2,  C.l.  12  310 

Pigment  Red  5,  C.I.  12  490 

Pigment  Red  17,  C.I.  12  390 

Pigment  Red  22,  C.I.  12  315 

Pigment  Red  23,  C.I.  12  355 

Other  naphthol  reds 

Pigment  Red  1,  C.I.  12  070,  dark 

Pigment  Red  1,  C.l.  12  070,  light 

Pigment  Red  3,  C.I.  12  120 

Pigment  Red  4,  C.I.  12  085 

Pigment  Red  38,  C.I.  21  120 

Pigment  Red  48,  C.I.  15  865 

Pigment  Red  49,  C.l.  15  630: 

Barium  toner 

Calcium  toner 

Sodium  toner 

Pigment  Red  52,  C.I.  15  860 

Pigment  Red  53,  C.l.  15,585,  barium  toner-- 
Pigment  Red  54,  C.I.  14  830,  calcium  toner- 
Pigment  Red  57,  C.I.  15  850,  calcium  toner- 
Pigment  Red  63,  C.I.  15  880 

Pigment  Red  81,  C.I.  45  160,  PMA 

Pigment  Red  81,  C.I.  45  160,  PTA 

Pigment  Red  90,  C.I.  45  380 

Pigment  Red  122 

All  other 


1,000 
pounds 


14,110 


662 

297 

1,038 

10,442 

6,473 

2,139 

573 

1,257 

1,671 

1,593 


319 
124 
562 


Quantity 


1,000 
pounds 


141 
276 
477 
76 
108 
,051 
360 
185 


4,555 
1,328 


1,559 
2,799 


1,479 

52 

572 

131 

1,864 
115 

2,310 


10,239 


462 

163 

600 

7,477 

4,103 

1,961 

416 

997 

1,537 

1,463 


331 
177 
300 
117 
538 


105 

247 

322 

73 

91 

1,665 

360 

165 

2,816 

4,289 

1,297 

74 

1,477 

2,146 

81 

1,236 

45 

534 

107 

1,046 

105 

1,730 


1,000 
dollars 


28,982 


979 
391 
1,413 
18,682 
8,284 
4,698 
1,224 
4,476 
7,517 

5,795 


594 
620 
863 
452 
3,266 

43,790 


3,172 
124 
263 
187 
347 
839 

1,412 
110 
134 

2,949 
597 
727 

5,816 

4,880 
1,595 
88 
2,476 
3,237 


2,190 
1,418 
9,101 


See   footnotes   at   end   of  table. 


ORGANIC  PIGMENTS 
TABLE  1, --Organic  pigments;     U.S.  production  and  sales,  1972--Continued 


Pigment 


Production 


Quantity 


Unit 
value' 


1,000 

pounds 


TONERS--Continued 


Violet  toners,  total 

Pigment  Violet  1,  C.I 
Pigment  Violet  1 ,  C.I 
Pigment  Violet  3,  C.I 
Pigment  Violet  3,  C.I 
Pigment  Violet  3,  C.I 
Pigment  Violet  23,  C. 
All  other 


45  170,  PMA  

45  170,  PTA 

42  535,  fugitive- 

42  535,  PMA 

42  535,  PTA 

.  51  319 


Blue  toners 
Pigment  B 
Pigment  B 
Pigment  B 
Pigment  B 
Pigment 
Pigment  B 
All  other 


total 

lue  1,  C.I.  42  595,  PMA 

lue  14,  C.I.  42  600,  PMA. 

lue  15,  C.I.  74  160,  alpha  form- 

lue  15,  C.I.  74  160,  beta  form-- 

lue  19,  C.I.  42  750A 

lue  25,  C.I.  21  180 


Green  toners,  total - 


Pigment  Green  1,  C.I.  42  040,  PMA 

Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA- 
Pigment  Green  2,  C.I.  42  040  and  49  005,  PTA- 

Pigment  Green  7,  C.I.  74  260 

Pigment  Green  8,  C.I.  10  006 

Pigment  Green  36,  C.I.  74  265 

All  other 


Brown  toners,  total 

Pigment  Brown  5,  C.I.  15  800- 
AII  other 


Black  toners - 


LAKES 


Total 

Yellow  lake:   (Acid  Yellow  23),  C.I.  19  140- 
Orange  lakes 


Red  lakes: 

Pigment  Red  60,  C.I.  16  105- 
Pigment  Red  83,  C.l.  58  000- 


Violet  lake:   Pigment  Violet  5,  C.I.  58  055- 
AIl  other  lakes' 


225 
1,164 


184 

83 

4,394 

6,008 

4,484 

30 

335 

4.216 


62 
35 
3,305 
153 
263 
383 

132 


3,019 


296 
56 


127 
2,471 


1,000 
pounds 


1,000 
dollars 


74 
831 
359 

47 

215 

1,042 

12,066 


153 

116 

3,641 

4,523 

3,353 

280 

3,665 


64 
42 
2,956 
107 
271 
210 

112 


126 
2,044 


16,382 


506 
524 
1,021 
1,156 
222 
3,122 
9,831 

36,444 


749 

560 

11,466 

14,145 

8,022 

1,502 

14,122 


66 

348 

216 

10,991 

153 

1,122 

1,226 

218 


346 
40 


382 
201 


339 
2,094 


1  Calculated  from  rounded  figures. 

2  Includes  "all  other"  acetoacetarylide  yellows. 

3  Includes  all  black,  blue,  brown,  and  green  lakes,  and  "all  other"  red,  violet,  and  yellow  lakes. 

Note. --The  C.I.  (Coloui'  Index)   numbers  shown  in  this  report  are  the  identifying  numbers  given  in  the  third  editic 
of  the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  (including  phosphotungstomolybdic] 
acids,  respectively. 


552-743  0-74-7 


SYNTHETIC  ORGANIC  CHENICALS.  1972 
TABLE  lA.— U.S.  sales  of  selected  dry  full-strength  colors,  dry  extended  colors,  dry  dispersions, 

AQUEOUS  dispersions,  AND  FLUSHED  COLORS,  1972 


Selected  pigments  by  commercial  forms 


Quantity' 


Unit 
value 


Pigment  Yellow  12,  C.I.  21  090,  total --■ 

Dry  full- strength  toner 

Aqueous  dispersions  

Dry  extended  toner,  dry  dispersions,  and  flushed  color  

Pigment  Yellow  13,  C.I.  21  100;  Pigment  Yellow  14,  C.I.  21  095;  Pigment 

Yellow  17,  C.I.  21  105;  and  other  benzidine  yellows,  total 

Dry  full -strength  toner 

Dry  extended  toner  and  dry  dispersions" 

Aqueous  dispersions  

Flushed  color 

Pigment  Red  3,  C.I.  12  120,  total 

Dry  full-strength  toner  and  dry  extended  toner  '*.-- -^ 

Aqueous  dispersions^ 

Flushed  color 

Pigment  Red  48,  C.l.  15  865,  total 

Dry  full-strength  toner,  dry  extended  toner,  and  dry  dispersions'* 

Aqueous  dispersions 'and  flushed  color" 

Pigment  Red  49,  C.l.  15  630,  barium  toner,  total 

Dry  full-strength  toner,  dry  extended  toner,  and  aqueous  dispersions  '' 
Flushed  color 

Pigment  Red  53,  C.I.  15  585,  barium  toner,  total 

Dry  full-strength  toner  and  dry  dispersions  ''• 

Aqueous  dispersions  'and  flushed  color" 

Pigment  Violet  3,  C.l.  42  535,  PMA  and  PTA,  total 

Dry  full -strength  toner 

Dry  extended  toner  and  aqueous  dispersions  '  '* 

Flushed  color 

Pigment  Blue  15,  C.I.  74  160,  alpha  form,  total 

Dry  full -strength  toner 

Dry  extended  toner  and  dry  dispersions" 

Aqueous  dispersions  

Flushed  color 

Pigment  Blue  15,  C.I.  74  160,  beta  form,  total 

Dry  full -strength  toner 

Dry  extended  toner  and  dry  dispersions  '* 

Aqueous  dispersions  ^ 

Flushed  color 


1,000 
pounds 


4,103 


2,978 


651 
224 


994 
118 


2,605 
211 


3,747 
542 


978 
,168 


3,641 


1,421 

1,085 

802 

333 

4,523 


1,410 
575 
961 

1,577 


1,000 
dollars 


2,240 

63 

6,327 

10,473 


8,064 
124 

1,659 
626 

3,061 


1,759 

211 

1,091 

5,816 


5,362 

434 


4,223 
770 


1,456 
1,825 


1,079 
112 


11,467 


5,025 

3,703 

1,903 

836 

14,231 


4,690 
2,061 
2,585 
4,895 


Per 
pound 


$2.10 


2.33 
2.12 


2.38 
2.55 


2.07 
2.06 


1.49 
1.56 


3.74 
3.57 
8.00 
3.66 


3.15 


See  footnotes  at  end  of  table. 


ORGANIC  PIGMENTS 
ABLE  1A.--U.S.  SALES  of  selected  dry  full-strength  colors,  dry  extended  colors,  dry  dispersions, 

AQUEOUS   dispersions,    AND   FLUSHED   COLORS,    1972--CONTINUED 


Selected  pigments  by  commercial   forms 


Quantity' 


Unit 
value 


1,000 
pounds 


Pigment   Blue  19,  C.I.    45   750A,   total 

Dry  full-strength   toner  and  aqueous  dispersions  3 
Flushed  color 

Pigment   Green   7,   C.I.    74   260,    total 

Dry  full-strength  toner 

Dry   extended  toner 

Dry  dispersion 

Aqueous   disperions'   and    flushed   color'* 


3,355 


1,000 
dollars 


S,022 


3,067 
2,956 


10,991 


1,264 
490 


4, 877' 

1,966 

275 

3,873 


Per 
pound 


$2.39 


2.72 
2.36 


3.86 
4.01 


'  Quantity  of  the  various  commercial  forms  is  given  in  terms  of  dry  full-strength  toner  (or  dry  lake)  content. 
^  Calculated  from  rounded  figures. 
^  Includes  presscake. 

'*  Separate  data  on  these  commercial  forms  may  not  be  published  without  revealing  the  operations  of  individual 
companies. 


Note. --The  C.I.  (Colour  Index)   numbers  shown  in  this  report  are  the  identifying  numbers  given  in  the  third  edition 
of  the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  (including  phosphotungstomolybdic) 
acids,  respectively. 


S'iYTHETlC  mMK  CHEMICALS,   197'^ 
TABLE  2, --Organic  pigments  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972 

[Organic  pigments    for  which   separate  statistics   are  given   in   table    1    are  marked  below  with   an    asterisk    (*) ;    products 
not   so  marked  do  not   appear  in   table   1   because   the  reported  data  are   accepted   in    confidence   and  may  not  be  pub- 
lished.     Manufacturers'    identification  codes   shown  below  are  taken  from  table   3.      An  x  signifies   that  the  manufac- 
turer did  not   consent   to  his    identification  with   the  designated  product] 


Pigment 


Manufacturers'  identification  codes 
(according  to  list  in  table  3^ 


*Yellow  toners: 

Acetoacetarylide  yellows: 
♦Pigment  Yellow  1,  C.I.  11  680- 


11  710 

11  665 

11  660 

11  670 

11  720 

♦Pigment  Yellow  3,  C.I. 
Pigment  Yellow  4,  C.I. 
Pigment  Yellow  5,  C.I. 
Pigment  Yellow  6,  C.I. 
Pigment  Yellow  9,  C.I. 

Pigment  Yellow  49,  C.I.  11  765 

Pigment  Yellow  65 

Pigment  Yellow  73,  C.I.  11  738 

♦Pigment  Yellow  74,  C.I.  11  741 

Pigment  Yellow  75,  C.I.  11  770 

All  otlier  acetoacetarylide  yellows- 
*Benzidine  yellows: 

♦Pigment  Yellow  12,  C.I.  21  090 


Pigment  Yellow  13,  C.I.  21  100- 
♦Pigment  Yellow  14,  C.I.  21  095- 


♦Pigment  Yellow  17,  C.I.  21  105- 


Pigment  Yellow  76 

Pigment  Yellow  83 

All  other  benzidine  yellows 

Pigment  Yellow  10,  C.I.  12  710 

Pigment  Yellow  16,  C.I.  20  040 

Pigment  Yellow  24 

Pigment  Yellow  97 

Pigment  Yellow  108,  C.I.  68  420 

Pigment  Yellow  123 

(Basic  Yellow  2),  C.I.  41  000  fugitive- 
All  other 

♦Orange  toners : 

Pigment  Orange  1,  C.I.  11  725 

Pigment  Orange  2,  C.I.  12  060 

♦Pigment  Orange  5,  C.I.  12  075 

♦Pigment  Orange  13,  C.I.  21  110 

Pigment  Orange  15,  C.I.  21  130 

♦Pigment  Orange  16,  C.I.  21  160 

♦Pigment  Orange  34,  C.I.  21  IIS 

Pigment  Orange  38 

Pigment  Orange  43,  C.I.  71  105 

(Vat  Orange  3),  C.I.  59  300 

(Vat  Orange  4),  C.I.  59  710 

All  other 

♦Red  toners  : 
♦Naphthol  reds: 

♦Pigment  red  2,  C.I.  12  310 

♦Pigment  Red  5,  C.I.  12  490 

Pigment  Red  7,  C.I.  12  420 

Pigment  Red  9,  C.I.  12  460 

Pigment  Red  10,  C.I.  12  440 

Pigment  Red  13,  C.I.  12  395 

Pigment  Red  15,  C.I.  12  465 

♦Pigment  Red  17,  C.I.  12  390 

Pigment  Red  18,  C.I.  12  350 


ACS, 
S, 
ACS, 
ACS, 
CIK, 
HPC. 
SNA. 
HPC, 
ACS. 
ACS, 
DUP, 
HPC. 
DUP, 


ACY,  AMS,  DUP,  HPC,  HSC,  HSH,  HST,  ICI,  KON, 

SDH,  SNA,  SW. 

HPC,  HSH,  HST,  KCW,  KON,  PPG,  SW. 

HSC. 

HPC. 


CIK,  HPC,  SNA. 

HPC,  HSC,  SDH,  SNA,  SW. 


KCW. 


ACS,  ACY,  AMS,  APO,  CIK,  DUP,  HPC,  HSC,  HSH,  HST, 
ICC,  KON.  LVY,  ROM,  S,  SDH,  SNA,  SW. 

APO,  sue,  GAP,  HPC,  HSH,  HST,  ICC,  ROM,  SDH,  SNA. 

ACS,  ACY,  AMS,  BUC,  CIK,  CPC,  DUP,  GAF,  HPC,  HSC, 
HSH,  HST,  ICC,  ROM,  S,  SDH,  SNA,  x. 

ACS,  AMS,  BUC,  GAF,  HPC,  HSC,  HST,  ICC,  ROM,  SDH, 
SNA,  SW. 

HPC. 


ACS, 

HST. 

HSH, 

ICC, 

ROM, 

S. 

HST, 

SW. 

HST. 

ACS. 

HST. 

ACS. 

ACS. 

LVR, 

MRX 

ICC, 

LVR, 

S,  TRC. 

ACS, 

HPC, 

KCW. 

HPC, 

SNA, 

UHL. 

ACY, 

HSC, 

HST, 

SNA, 

SW. 

ACS, 

ACY, 

AMS, 

HPC, 

KON,  S,  SNA 

ACS. 

ACS, 

DUP, 

GAF, 

HPC, 

HSH,  HST,  I 

BUC, 

ICC, 

ROM, 

SDH, 

SNA. 

HST. 

AGS, 

HST. 

ACS, 

HST, 

TRC. 

ACS. 

KON, 

LVR, 

S,  SNA. 

ACS,  HPC,  HSH,  KCW,  SW. 

GAF,  HPC,  HSH,  ICC,  ROM,  S,  SDH. 

S. 

HPC. 

KCW. 

HPC,  KCW. 

DUP. 

ACY,  HPC,  ICC,  S,  SNA,  SW,  UHL. 

ACS,  HPC. 


ORGANIC  PIGMENTS 
TABLE  2. --Organic  pigments  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--C0NTINUED 


Pigment 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


TONERS--Continued 

•Red  toners--Continued 

*Naphthol  reds--Continued 

•Pigment  Red  22,  C.I.  12  315 

'Pigment  Red  23,  C.I.  12  355 

Pigment  Red  31,  C.I.  12  360 

Pigment  Red  112,  C.I.  12  370 

All  other  naphthol  reds 

♦Pigment  Red  1,  C.I.  12  070,  dark-- 
♦Pigment  Red  1,  C.I.  12  070,  light- 
♦Pigment  Red  3,  C.I.  12  120 


•Pigment  Red  4, 

Pigment  Red  6, 

•Pigment  Red  38 

Pigment  Red  41 

•Pigment  Red  48 


C.I.  12  085-- 

C.I.  12  090-- 

C.I.  21  120- 

C.I.  21  200- 

C.I.  15  865- 


Pigment  Red  49,  C.I . 
•Barium  toner 


•Calcium  toner 

•Sodium  toner 

•Pigment  Red  52,  C.I.  15  860 

•Pigment  Red  53,  C.I.  15  585,  barium  toner- 


Pigment  Red  S3,  C.I.  15  585,  sodium  toner-- 
•Pigment  Red  54,  C.I.  14  830,  calcium  toner- 
Pigment  Red  55,  C.I.  15  820 

•Pigment  Red  57,  C.I.  15  850,  calcium  toner- 
Pigment  Red  58,  C.I.  15  825 

•Pigment  Red  63,  C.I.  15  880 

Pigment  Red  64,  C.I.  15  800 

Pigment  Red  79,  PMA 

Pigment  Red  81,  C.I.  45  160,  fugitive 

•Pigment  Red  81,  C.I.  45  160,  PMA 

•Pigment  Red  81,  C.I.  45  160,  PTA 


Pigment  Red  87,  C. I . 
Pigment  Red  88 

•Pigment  Red  90,  C.I. 
Pigment  Red  112 

•r-igment  Red  122 

Pigment  Red  123,  C.I 

Pigment  Red  146 

Pigment  Red  149 

Pigment  Red  170 

Pigment  Red  176 

Pigment  Red  177 

Pigment  Red  179,  C.I 
Pigment  Red  181 ,  C.I 
Pigment  Red  190,  C.I 

Pigment  Red  198 

(Vat  Red  15) 

All  other 

•Violet  toners: 

Pigment  Violet  1,  C. 

•Pigment  Violet  1,  C. 

•Pigment  Violet  1,  C. 

•Pigment  Violet  3,  C. 

•Pigment  Violet  3,  C. 


71  130- 
73  360- 
71  140- 


45  170,  fugitive- 

45  170,  PMA 

45  170,  PTA 

42  535,  fugitive- 

42  535,  PMA 


•Pigment  Violet  3,  C.I.  42  535,  PTA- 

Pigment  Violet  4,  PMA 

Pigment  Violet  19,  C.I.  46  500 

•Pigment  Violet  23,  C.I.  51  319 


ACY,  DUP,  GAP,  HPC,  MRX,  ROM,  SNA. 

ACY,  BUG,  DUP,  HPC,  ROM,  SDH,  SNA, 

SNA. 

HPC. 

ICC,  KOV,  ROM,  S,  SDH,  SNA. 

WS,  HPC,  HSC,  HSH,  SW. 

HPC,  HSC,  HSH,  SDH,  SW. 

ACY,  CIK,  CPC,  DUP,  HPC,  HSC,  HSH, 

SNA,  SW,  UHL. 

ACY,  AiMS,  HPC,  HSC,  KON,  MRX,  SDH, 

DUP,  HSH,  KCW,  KON. 

ACS,  DUP,  GAP,  ICC,  SNA,  SW. 

ACS,  GAP. 

ACS,  ACY,  AMS,  DUP,  GAP,  HPC,  HSC, 

S,  SNA,  SW. 

ACV,  AMS,  APO,  CIK,  HSC,  KON,  UT, 

UHL. 
ACV,  AMS,  CIK,  HSC,  LVT,  SDH,  SNA, 
ACY,  HSC,  KON,  SDH,  SW. 
A^^S,  CIK,  HPC,  HSC,  HSH,  SNA,  SW . 
ACY,  AMS,  APO,  CIK,  HPC,  HSC,  KON, 

SNA,  SW. 
KON. 
HPC,  HSH,  SDH. 


KCW,  KON,  PPG,  SDH, 
SNA,  UHL. 


ICC,  IMP,  LVY, 
SDH,  SNA,  SW, 


LVY,  MGR,  MRX,  SDH, 


HSH . 

AMS, 

CIK 

DUP, 

HPC 

HSC 

KON,  LVY 

\CR,  SDH 

SNA,  SW. 

DUP, 

HPC 

ACS, 

HPC 

HSH 

KON 

SNA 

ACS. 

GAP. 

MGR. 

CPC, 

DUP 

GAP 

HPC 

KON 

LVR,  LVY 

MGR,  MRX 

SNA,  UHL 

ACY, 

AMS 

DUP 

GAP 

HN, 

HPC,  HSC, 

KCW,  KON, 

MGR,  MRX, 

S, 

SNA 

UHL 

ACS. 

ACS. 

AMS, 

HN, 

HPC, 

ICC, 

LVT, 

SDH. 

HST. 

ACS, 

ACY 

HST 

SNA 

ACS, 

HST. 

HST. 

HST. 

HST. 

TRC. 

ACS. 

HST. 

ACS, 

GAP 

HSC 

ACS. 

RST. 

DUP, 

GAP, 

HN, 

HSC, 

LVR, 

SW,  X. 

UHL. 

GAP,  HPC,  MGR,  MRX,  SNA,  UHL. 

AMS,  DUP,  GAP,  HPC,  MGR,  MRX,  SNA. 

ACY,  AMS,  HN,  HPC,  HSC,  KON,  MGR, 

AMS,  CIK,  DUP,  GAP,  HPC,  HSC,  KON^ 

SDH,  SW,  UHL. 

ACY,  AMS,  HN,  HPC,  HSC,  KON,  MRX. 
LVR. 

ACS,  DUP,  SNA. 

ACS,  ACY,  BUC,  GAP,  HSC,  HST,  SDC 


UHL. 
LVY, 


MGR,  MRX,  PPG, 


SYNTHETIC  ORGANIC  CHEMICALS.  1972  " 
TABLE  2.— Organic  pigments  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--C0NTI NUED 


Pigment 


Manufacturers'  identification  codes 
taccording  to  list  in  table  3) 


TONERS--Continued 

*Violet  toners--Continued 

Pigment  Violet  31,  C.I.  60  010 

Pigment  Violet  36,  C.I.  73  385 

Pigment  Violet  38,  C.I.  73  395 

(Basic  Violet  2),   C.l.  42  520 

All  other 

*Blue  toners; 

•Pigment  Blue  1,  C.l.  42  595,  PMA 

Pigment  Blue  1,  C.I.  42  595,  PTA 

Pigment  Blue  2,  C.I.  44  045,  PMA 

Pigment  Blue  2,  C.I.  44  045,  PTA 

Pigment  Blue  7,  PMA 

Pigment  Blue  7,  PTA 

Pigment  Blue  9,  C.I.  42  025,  PTA 

Pigment  Blue  10,  C.I.  44  040,  PMA 

Pigment  Blue  10,  C.I.  44  040,  PTA 

♦Pigment  Blue  14,  C.I.  42  600,  PMA 

Pigment  Blue  14,  C.I.  42  600,  PTA 

♦Pigment  Blue  15,  C.I.  74  160,  alpha  form 

♦Pigment  Blue  15,  C.I.  74  160,  Beta  form 

♦Pigment  Blue  19,  C.I.  42  750A 

Pigment  Blue  22,  C.I.  69  810 

♦Pigment  Blue  25,  C.I.  21  180 

Pigment  Blue  64,  C.I.  69  825 

(Basic  Blue  2) 

All  other 

♦Green  toners ; 

♦Pigment  Green  1,  C.I.  42  040,  PMA 

Pigment  Green  1,  C.I.  42  040,  PTA 

♦Pigment  Green  2,  C.I.  42  040  and  49  005,  PMA 

♦Pigment  Green  2,  C.I.  42  040  and  49  005,  PTA 

Pigment  Green  4,  C.I.  42  000,  fugitive 

Pigment  Green  4,  C.I.  42  000,  PMA 

Pigment  Green  4,  C.I.  42  000,  PTA 

♦Pigment  Green  7,  C.I.  74  260 

♦Pigment  Green  8,  C.I.  10  006 

Pigment  Green  10,  C.I.  12  775 

♦Pigment  Green  36,  C.I.  74  265 

Pigment  Green  38 

All  other 

♦Brown  toners  : 

Pigment  Brown  1,  C.I.  12  480 

Pigment  Brown  2,  C.I.  12  071 

Pigment  Brown  3,  C.I.  21  010,  PMA 

♦Pigment  Brown  5,  C.I.  15  800 

Pigment  Brown  28,  C.I.  69  015 

All  other 

♦Black  toners 


Yellow  lakes:  *(Acid  Yellow  23),  C.I.  19  140 
♦Orange  lakes: 

Pigment  Orange  7,  C.I.  15  530 

Pigment  Orange  17,  C.I.  15  510 

Red  lakes: 

♦Pigment  Red  60,  C.I.  16  105 

♦Pigment  Red  83,  C.I.  58  000 

(Acid  Red  17),  C.I.  16  180 

(Acid  Red  26),  C.I.  16  150 

All  other 


ACS,  DUP. 

ACS,  HST. 

ACS. 

HN. 

BUC,  ICC,  HPC,  ROM. 

DUP,  GAF,  HN,  HPC,  HSC,  KON,  LVY,  MGR,  MRX,  SW,  UHL. 

AMS,  GAF,  HPC,  MGR. 

GAF. 

KON. 

LVR. 

LVR. 

GAF,  HPC,  MGR. 

SDH. 

HPC,  LVR. 

DUP,  GAF,  HPC. 

DUP,  GAF, 

ACS,  ACY,  APO,  DUP,  GAF,  HPC,  HSC,  ICC,  MGR,  SNA,  SW, 

TMS,  TRC. 
ACS,  ACY,  AMS,  BAS,  BUC,  CIK,  DUP,  GAF,  HPC,  HSC,  ICC, 

LVY,  ROM  SDH,  SNA,  SW,  TMS. 
AMS,  HN,  HSC,  SW. 
ACS,  DUP,  HN. 
ACS,  DUP,  GAF,  ICC,  SNA. 
TRC. 
HPC. 
DUP,  GAF,  SDH,  TNI. 


GAF, 

HPC, 

MRX, 

S,    UHL. 

HPC, 

MGR. 

GAF, 

HPC, 

KON, 

MGR, 

MRX, 

UHL. 

ACY, 

AMS, 

DUP, 

GAF, 

HPC, 

KON, 

S. 

GAF, 

MRX. 

KON, 

MGR. 

ACY, 

AMS, 

KON, 

MGR. 

ACS, 
HPC, 

ACY, 
HSH, 

BAS, 
KCW. 

CIK, 

DUP, 

GAF, 

HPC,   HSC,   SNA,   TMS,   TRC 

DUP, 

HPC, 

SNA. 

ACS, 

ACY, 

GAF, 

SNA. 

DUP, 

SNA. 

HPC. 

S. 

KCW, 

KON. 

ACS, 

BUC, 

HSH, 

ICC, 

ROM, 

SNA. 

GAF. 

GAF, 

LVR, 

SDH. 

DUP, 

GAF, 

UHL. 

ACS,  KON,  MGR,  MRX. 

CPC. 

HPC,  KCW,  KON. 

HSH,  KON,  MRX,  SNA. 

HPC,  HSH,  KON,  MRX,  UHL. 

HPC. 

CPC,  HPC,  KCW. 

HPC. 


ORGANIC  PIG^IENTS 
TABLE  2. --Organic  pigments  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED  BY  MANUFACTURER^  1972— CONTINUED 


Pigment 


Manufacturers'  identification  codes 
(according  to  list  in  table  5) 


LAKES — Continued 

'Violet  lakes: 

•Pigment  Violet  5,  C.l.  58  055 

All  other 

Blue  lakes: 

Pigment  Blue  17,  C.I.  74  180 

Pigment  Blue  24,  C.I.  42  090 

(Acid  Blue  93),  C.I.  42  780 

(Acid  Blue  104),  C.I.  42  735 

Green  lakes 

Brown  lakes 

Black  lakes:   (Natural  Black  3),  C.I.  75  291 


ACS,  DUP,  HPC,  HSH,  KON,  UHL. 
SW. 

CPC. 

AMS,  KON,  LVY,  SDH. 

LVR. 

KCW,  LVR. 

HPC. 

KON. 

CPC. 


Note. --The  C.I.  (Colour  Index)   numbers  shown  in  this  report  are  the  identifying  codes  given  in  the  third  edition 
of  the  Colour  Index. 

When  the  name  of  a  color  is  enclosed  in  parentheses,  it  indicates  that  this  name  is  that  of  the  dye  from  which  the 
pigment  can  be  made  and  that  no  name  for  the  pigment  itself  is  given  in  the  Colour  Index. 

The  abbreviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstic  (including  phosphotungstomolybdic) 
acid,  repectively. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972. 
TAPLE  ^.--Hrganic  f^iGMFMTs:     Directory  of  manufacturfrs,  1^72 


ALPHABETICAL  DIRECTORY  BY  CODE 


[Names  of  organic  pigment  manufacturers  that  reported  prod 
are  listed  below  in  the  order  of  their  identification  co 


uction  or  sales  to  the  U.S.  Tariff  Commission  for  1972 
des  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ACS 

Allied  Chemical  Corp.,  Specialty  Chemicals 

Div. 

KON 

H.  Kohnstamm  5  Co . ,  Inc. 

ACY 

American  Cyanamid  Co. 

AMS 

Ridgway  Color  6  Chemical 

APO 

Apollo  Colors,  Inc. 

LVR 
LVY 

C.  Lever  Co  .,  Inc. 

Cities  Service  Co.,  Levey  Div. 

BAS 

BASF  Wyandotte  Corp. 

BUC 

Blackman-Uhler  Chemical  Co. 

MGR 
MRX 

Magruder  Color  Co.,  Inc. 

Max  Marx  Color  £,  Chemical  Co. 

CIK 

Tenneco  Chemicals,  Inc.,  Cal/Ink  Div. 

CPC 

Childs  Pulp  Colors,  Inc. 

PPG 

PPG  Industries,  Inc. 

DUP 

E.  1.  duPont  de  Nemours  ti  Co.,  Inc. 

ROM 

United  Merchants  (j  Manufacturers,  Inc. 
Roma  Chemical  Div. 

GAP 

GAP  Corp.,  Chemical  Div. 

S 
SDC 

Sandoz,  Inc.,  Sandoz  Color  5  Chemicals 
Martin-Marietta  Corp.,  Sodyeco 
Div. 

Div. 

SDH 

Sterling  Drug,  Inc.,  Hilton-Davis  Chem 

ical 

HN 

Tenneco  Chemicals,  Inc. 

Co.  Div. 

HPC 

Hercules,  Inc. 

SNA 

Sun  Chemical  Corp. 

HSC 

Chemetron  Corp.,  Pigments  Div. 

SW 

The  Sherwin-Williams  Co. 

HSH 

Harshaw  Chemical  Co.  Div.  of  Kewanee 
Oil  Co. 

HST 

American  Hoechst  Corp. 

TMS 
TNI 

Sterling  Drug,  Inc.,  Thomasset 

Colors  Div. 
Gillette  Co.,  Gillette  Chemical 

ICC 

Inmont  Corp. 

Co.  Div. 

ICI 

ICI  America,  Inc. 

TRC 

Toms  River  Chemical  Corp. 

KCW 

Keystone  Color  Works,  Inc. 

UllL 

Pi.ul  Uhlich  f,  Co.  ,  Inc. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendi.x 


101 
MEDICINAL  CHEMICALS 


Medicinal  chemicals  include  the  medicinal  and  feed  grades  of  all 
organic  chemicals  having  therapeutic  value,  whether  obtained  by  chemical 
synthesis,  by  fermentaiton,  by  extraction  from  naturally  occurring  plant 
or  animal  substances,  or  by  refining  a  technical  grade  product.   They 
include  antibiotics  and  other  anti-infective  agents,  antihistamines., 
autonomic  drugs,  cardiovascular  agents,  central  nervous  system  depres- 
sants and  stimulants,  hormones  and  synthetic  substitutes,  vitamins,  and 
other  therapeutic  agents  for  human  or  veterinary  use  and  for  animal  feed 
supplements . 

Table  1  shows  statistics  for  production  and  sales  of  medicinal 
chemicals  grouped  by  pharmacological  class,  while  table  2  lists  separately 
e.ach  product  for  which  data  were  reported  and  identifies  the  manufacturers.^ 
The  statistics  shown  in  table  1  are  for  bulk  chemicals  only;  finished 
pharmaceutical  preparations  and  products  put  up  in  pills,  capsules,  tablets, 
or  other  measured  doses  are  excluded.  ^  The  difference  between  production 
and  sales  reflects  inventory  changes,  processing  losses,  and  captive  con- 
sumption of  medicinal  chemicals  processed  into  ethical  and  proprietary 
pharmacetuical  products  by  the  primary  manufacturer.   In  some  instances, 
the  difference  may  also  include  quantities  of  medicinal  grade  products 
used  as  intermediates,  e.g.,  penicillin  G  salts  used  as  intermediates  in 
the  manufacture  of  semisynthetic  penicillins.  All  quantities  are  given 
in  terms  of  100-percent  content  of  the  pure  bulk  drug. 

Total  U.S.  production  of  bulk  medicinal  chemicals  in  1972  amounted 
to  234  million  pounds,  or  5.0  percent  more  than  the  223  million  pounds 
produced  in  1971  and  9.3  percent  more  than  the  214  million  pounds  produced 
in  1970.   Total  sales  of  bulk  medicinal  chemicals  in  1972  amounted  to  163 
million  pounds,  valued  at  $490  million,  compared  with  sales  in  1971  of 
152  million  pounds,  valued  at  $487  million,  and  sales  in  1970  of  155 
million  pounds,  valued  at  $510  million.   In  terms  of  quantity,  sales  in 
1972  were  thus  7.2  percent  larger  than  in  1971  and  5.6  percent  larger  than 
in  1970.   In  terms  of  value,  sales  in  1972  were  0.7  percent  larger  than  in 

1971  and  3.9  percent  smaller  than  in  1970. 

Production  of  the  more  important  groups  of  medicinal  chemicals  in 

1972  was  as  follows:  Antibiotics,  16.6  million  pounds  (7.1  percent  smal- 
ler than  in  1971),  of  which  9.8  million  pounds  was  for  medicinal  use  and 
6.8  million  pounds  was  for  other  uses;  anti-infective  agents  other  than 
antibiotics,  34.4  million  pounds  (8.3  percent  larger  than  in  1971;  central 

~~^       See  table  3  for  a  list  of  manufacturers  and  their  identification 
codes . 

^   Complementary  statistics  on  the  dollar  value  of  manufacturers' 
Shipments  of  finished  pharmaceutical  preparations,  except  biologicals, 
are  published  annually  by  the  U.S.  Department  of  Commerce,  Bureau  of 
the  Census,  in  Current  Industrial  Reports,  Series  MA-28G.  Many  pharma- 
ceutical manufacturers  who  report  to  the  Bureau  of  the  Census  are  ex- 
cluded from  the  lariff  Commission  report  because  they  are  not  primary 
producers  of  medicinal  chemicals,  that  is,  they  do  not  themselves  pro- 
duce the  bulk  drugs  which  go  into  their  pharmaceutical  products  but 
purchase  their  drug  requirements  from  domestic  or  foreign  producers. 


102 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


nervous  system  depressants  and  stimulants,  52.4  million  pounds  (,13.2 
percent  larger};  gastreintestinal  ageftts  add  therapeutic  ntitrielit^,  99^9 
million  pounds  (10.6  percent  larger};  and  vitamins,  30.0  million  pounds 
(15.1  percent  larger).   Production  of  some  of  the  more  important  in- 
dividual products  listed  in  table  1  was  as  follows:   Choline  chloride, 
54.5  million  poimds  (19.2  percent  larger  than  in  1971);  aspirin,  35.0 
million  pounds  (10.5  percent  larger};  salicylic  acid,  8.7  million  pounds 
(52.9  percent  smaller};  ascorbic  acid,  12.3  million  pounds  (10.0  percent 
larger);  anti-infective  sulfonamides,  6.1  million  pounds  (0.2  percent 
larger);  penicillins  (except  semi-synthetic),  3,827  trillion  units  (18.1 
percent  smaller);  tetracyclines,  1.8  million  kilograms  (19.0  percent 
smaller);  vitamin  A,  1,005  trillion  units  (4.5  percent  smaller);  and 
vitamin  E,  1,502  billion  units  (53.0  percent  larger). 


»1EDICINAL  CHEMICALS 
TABLE  1. --Medicinal  chemicals;     U.S.  production  and  sales^  1972 


Listed  below  are  all  synthetic  organic  medicinal  chemicals  for  which  any  reported  data  on  production  or  sales  may 
be  published.   (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or 
where  no  data  were  reported.)  Table  2  lists  all  medicinal  chemicals  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturer  of  each] 


Production 


1,000 
pounds 


Grand  total 

Acyclic 

Benzenoid^ 

Cy c 1 i c  nonb en  zenoi d* 

Antibiotics,    total ^ 

Bacitracin,   for  medicinal   use 

Erythromycin,   for  medicinal   use 

Neomycin,   for  all  uses 

Penicillins    (except  semisynthetic),   total 

Penicillin  G,   potassium,   for  medicinal   use 

Penicillin  G,  procaine,   for  medicinal  use 

All  other,    for  all   uses 

Semisynthetic  penicillins,    for  medicinal   use,   total- 

AmpiGillin 

Ampicillin,    sodium 

All   other 

Tetracyclines,    for  all   uses 

Other  antibiotics,    total 

For  medicinal  use' 

For  nonmedicinal    uses    

Antihistamines,    total 

Antinauseants 

Chlorpheniramine  maleate 

All   other 

Anti-infective  agents  (except  antibiotics),  total 

Anthelmintics,  total 

Piperazine 

Piperazine  dihydrochloride 

Piperazine  hydrochloride 

All  other 

Antifungal  agents 

Antiprotozoan  agents,  total 

Arsenic  and  bismuth  compounds 

All  other 

Mercury  compounds 

Sulfonamides 

Other  anti-infective  agents' 

Autonomic  drugs,    total 

Parasympatholytic   (anticholinergic)   tertiary  amines 

Sympathomimetic   (adrenergic)   agents,   total 

Epinephrine  hydrochloride    (racemic) 

Phenylephrine  base   and  bitartrate 

Phenylephrine  hydrochloride 

Phenylpropanolamine  hydrochloride 

All   other 

Other  autonomic  drugs 

Cardiovascular  agents,   total 

Vasodilators 

Other  cardiovascular  agents 


101,747 
111,444 


16,637 


2,174 

837 

2,887 

931 

779 

20 

132 

3,899 

5,249 

1,857 

3,392 

483 


30 
375 


34,364 


12,914 

3,581 

1,824 

352 

7,157 

875 

10,233 

6.077 

4,156 

14 

6,078 

4,250 


308 
172 
47 


1,000 
pounds 


163.210 


82,128 
68,279 
12,803 

5.384 


20 

250 

199 

2,545 


2,545 
332 
302 

30 

790 

1,248 

608 

640 

330 


9.464 

1,915 

240 

7.309 

7.292 
4,574 
2,718 
8 
1,928 
3,325 


276 
113 


1,000 
dollar's 


490.137 


56,878 
319.665 
113.594 

139.212 


1,390 
6,269 
2,473 
22,791 


22,791 
32,708 
29,226 

3.482 
17,735 
55,846 
47.315 

8.531 

7.878 


292 
7.586 


77.672 


43,591 

1,420 

165 

42,006 

16.380 
5,633 

10,747 

533 

7.664 

9.504 

9.540 


1,537 
6.268 


2.538 
1.611 
2.119 
1,735 

15.628 


15,628 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS.  W2    ■ 
TABLE  1, --Medicinal  chemicals;  U.S.  production  and  sales,  1972--Continued 


Production' 


Sales' 


Quantity 


Unit 
Value^ 


Central  depressants  and  stimulants,  total 

Amphetamines 

Analgesics  and  antipyretics,  total 

Aspirin 

Meperidine  hydroch loride 

Salicylates  (except  aspirin) 

All  other 

Antidepressants 

Barbiturates,  total 

Pentobarbital ,  sodium 

All  other 

Hydrocodone  bit art rate 

Hypnotics  and  sedatives  (except  barbiturates) 

Skeletal  muscle  relaxants 

Tranquilizers 

Other  central  depressants  and  stimulants^ 

Dermatological  agents  and  local  anesthetics,  total 

Salicylic  acid 

All  other 

Diagnostic  agents 

Expectorants  and  mucolytic  agents,  total 

E thy lenedi amine  dihydriodide 

Guaiacol  and  its  derivatives 

All  other 

Gastrointestinal    agents   and  therapeutic  nutrients,    total- 

Amino  acids   and  salts 

Choleretics   and  hydrocholeretics 

Choline   chloride   (all   grades) 

All  other 

Hematological   agents,   total 

Sodium  heparin 

All  other 

Hormones    and  synthetic  substitutes,    total 

Antithyroid  agents 

Corticosteroids 

Estrogens   and  progestogens 

Synthetic  hypoglycemic   agents 

All  other 

Renal-acting   and  edema- reducing  agents,    total 

Benzothiadiazine  derivatives 

Mercurial   diuretics 

Theophylline   derivatives 

All    other 

Vitamins,    total 

Vitamin  A  alcohol   and  esters,   total'^ 

Vitamin  A  palmitate   (feed  grade) 

All   other 

Vitamin  B-complex,   total 

Niacin  and  niacinamide   (all   grades) 

Pantothenic  acid  and  derivatives,   total 

Calcium  pantothenate    (racemic)-calcium  chloride 
complex 

All   other 

Riboflavin    (all   grades) 

Other  B-complex  vitamins 

Vitamin  C,   total 

Ascorbic  acid 

All  other 


1,000 
pounds 


52,430 


45 

950 

35 

007 

28 

3 

262 

7 

653 

110 

567 

567 

1 

246 

133 

1,126 

4,297 


10,426 


8,694 
1,732 


924 
2,960 


1,335 

1,625 

79.934 


1,346 

150 

54,450 

23,988 

91 


1,325 
209 


1,650 


115 
1,535 


30,030 


1,037 

443 

594 

10,344 

5,475 

3,049 


1,964 

1,085 

1,011 

809 

15,588 

12,312 

3.270 


1,000 


29,358 


1,000 
dollars 


55.558 


24,895 


2,541 
22,354 


97 
28,822 


577 
245 

904 
116 
788 
455 


9,296 
1,279 


1,322 
1,351 


42,793 
23,755 


CO 


23.399 


1,010 
552 
458 
9,019 
4,920 
2,475 

1,732 

743 

788 

836 

11,067 

8,293 

2,774 


464 
724 


017 
972 
838 


931 
082 
849 
574 
882 
599 

978 
621 
198 
895 
644 
006 
638 


Pep 
pound 

$1.89 


flEDICINAL  CHEMICALS  . 
TABLE  1,— Medicinal  chemicals:  U.S.  production  and  sales>  1972— Continued 


Production 


Quantity 


Unit 
Value ^ 


Vitamins- -Continued 

Vitamin  D'^ 

Vitamin  E,  total'^ 

d-and  dl-Alpha  tocopheryl   acetate    (all    grades) 

All  other 

Vitamin  K 

Miscellaneous   medicinal   chemicals'' 


1,000 
pounds 


,905 
.268 
637 
143 


1,000 
pounds 


2,220 

1,623 

597 


1,000 
dollars 


1,404 

34,333 

20,336 

13,997 

548 


Per 
poimd 


$156.00 
15.47 
12.53 


5,721 


'  The  data  on  production  and  sales   are  for  bulk  medicinal   chemicals  only;   they  exclude  finished  preparations 
and  dosage-form  products,   which   are  manufactured  from  bulk  chemicals.     All  quantities   are  given  in  terms   of 
lOO'o  active  ingredient. 

^   Calculated  from  rounded  figures. 

'   The  term  "ben:enoid,"   as   used  in   this    report,    describes   any  cyclic   medicinal   chemical  whose  molecule   con- 
tains  either  a  six-membered   carbocylic   ring  with   conjugated   double  bonds    (e.g.,   the  benzene   ring  or  the  quinone 
ring)   or  a  six-membered  heterocyclic  ring  with   1   or  2  hetero  atoms   and  conjugated  double  bonds,   e.xcept  the 
pyrimidine  ring    (e.g.,    the  pyridine   ring  or  the  pyrazine  ring.) 

"*    Includes   antibiotics   of  unknown  structure. 

^  With   the  exception   of  bacitracin,   the  penicillins    (except   semisynthetic),    and  a  few  other  antibiotics  which 
were  reported  in  terms  of  U.S. P.   units,   all   quantities   for  antibiotics  were  reported  as   grams  of  antibiotic  base. 
(Thus  production  of  480,900  grams  of  tetracycline  hydrodiloride,   for  example,  would  have  been  reported  as   444,430 
grams  of  tetracycline  base.)      For  inclusion   in  the  main  statistical   table,    all   quantities  were   converted   from 
grams   of  antibiotic  base  to  pounds   of  antibiotic  base    (453.6  grams   =    1   pound)    or  from  U.S. P.   units   to  pounds    (22.7 
million  units   of  bacitracin,   458  million  units  of  procaine  pencillin  G,   723  million  units  of  potassium  peni- 
cillin G,   etc.   =   1  pound).     The  following  tabulation  shows   statistics   for  all   individually  publishable  antibiotics 
in  terms  of  kilograms  of  antibiotic  base   (Kg)   or  billions  of  U.S. P.  units   (BU) : 


Antibiotic 


Unit  of 
quantity 


Quantity 


Unit 
Value 


Bacitracin,  for  medicinal  use — 
Erythromycin,  for  medicinal  use- 
Neomycin,    for  all   uses 


Penicillins    (except  semisynthetic),    total 

Penicillin  G,   potassium,    for  medicinal   use — 

Penicillin   G,    procaine,    for  medicinal   use 

All   other,    for  all  uses 


Semisynthetic  penicillins,    for  medicinal  use 

total 

Ampicillin 

Ampicillin,  sodium 

All  other 


Tetracyclines,    for   all  uses- 


-BU--- 
-BU--- 


437 
290,582 


3,827.078 

1,572,130 

383,202 

1,871,746 


422,353 

353.302 

8.852 

60,199 

1.768.797 


459 
113.424 
90,119 


150,448 
137,104 


13,344 
358,477 


1,000 
dollars 

1,390 
6,269 
2.473 

22,791 


32 

708 

29 

226 

3 

482 

17 

735 

53,028.32 
55.27 
27.44 

15.13 
15.13 


217.40 
213.17 


260.94 
49.47 


'    Production  of  all   antibiotics    for  medicinal   use   amounted  to  9,817,000  pounds;    sales   amounted  to   3.484.000  pounds, 
valued  at  $115,855,000. 

'  Production  of  all   antibiotics   for  animal   feeds   and  other  nonmedicinal   uses   amounted  to  6.820.000  pounds;   sales 
amounted   to    1,900,000  pounds,   valued   at  $23,357,000. 

^    Includes   sales   of  antifungal    agents. 

'    Includes   production  of  amphetamines   and  production  and  sales  of  anticonvulsants,   antitussives,   general   anesthetics, 
and  stimulants;    also  includes  sales   of  antidepressants,  hypnotics  and  sedatives    (except  barbiturates),   skeletal 
muscle   relaxants,    and  tranquilizers. 

'°   Data  published  for  1971.    and  possibly  for  earlier  years  as  well,   includes   some  production   and  sales   of  technical 
grade  salicylic  acid  erroneously   reported  as  medicinal   grade. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 

Footnotes  for  table  l--Continued 

^^    Sales   of  mercurial   diuretics   amounted  to  318  pounds. 

^^   All   quantities    for  vitamin  A,    B12,    D,    and  E  were   reported  in  terms  of  grams   or  units,   but  were   converted  to 
pounds   for  inclusion  in  the  main  statistical   table    (1.317  billion  units  of  vitamin  A  acetate,   0.824  billion  units 
of  vitamin  A  palmitate,   453.6  grams  of  vitamins   B12,    18.14  billion  units  of  vitamin  D,   617,000  units  of  d-alpha 
tocopheryl   acetate,   454,000  units   of  dl-alpha  tocopheryl   acetate,   etc.   =   1  pound).     The  following  tabulation  shows 
statistics   for  these  vitamins,   except  for  B12,  which  was  not   separately  publishable,   in  terms   of  million  of  inter- 
national units    (MU)   or  billion  of  U.S. P.   units    (BU) : 


Unit 

of 

quantity 


Quantity  Value 


Unit 
value 


Vitamin  A,  total 

Vitamin  A  palmitate  (faed  grade) - 
All  other 

Vitamin  D 

Vitamin  E,   Total 

d-and  dl-Alpha  tocopheryl   acetate 

(all   grades) 

All   other 


BU- 

BU- 


MU--- 


1,005,425 
365,303 
640,122 

233,391 

1,501,785 

1,131,189 
370,596 


944,556 
454,540 
490,016 

158,558 

1,168,840 

817,079 
351,761 


1,000 
dollars 

18,931 

7,082 

11,849 

1,404 

34,333 

20,336 
13,997 


$20.04 
15.58 
24.18 


24.89 
39.79 


Includes  production  and  sales  of  antineoplastic  agents,   smooth-muscle  relaxants,    and  unclassified  medicinal 
chemicals;   also  includes  sales  of  diagnostic  agents   and  "all  other"  hematological   agents. 


MEDICINAL  CHEMICALS 

Table  2. --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported- 
identified  BY  MANI"^ACTURER,  1972 

[Medicinal  chemicals  tor  which  separate  statistics  are  given  in  table  1  are  marked  below  with  an  asterisk  (*J ;  medic- 
inal chemicals  not  so  marked  do  not  appear  in  table  1  because  the  reported  data  are  accepted  in  confidence  and  may 
not  be  published.  Manufacturers'  identification  codes  shown  below  are  taken  from  table  3.  An  x  signifies  that  the 
manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


'Antibiotics:  ' 

'Bacitracin 

'Eryth  romycin 

'Neomycin: 

For  medicinal  use 

For  nonmedicinal  uses 

'Penicillins  (except  semisynthetic): 

•Penicillin  G,  potassium 

'Penicillin  G,  procaine 

'All  other: 

Penicillin  G,  benzathine 

Penicillin  G,  procaine,  for  nonmedicinal  uses- 
Penicillin  G,  sodium 

Penicillin  0,  sodium 

Phenoxymethylpenicillin  (Penicillin  V) 

Phenoxymethylpenici 11  in,  benzathine 

Phenoxymethylpenicillin,  hydrabamine 

Phenoxymethy Ipeni ci llin,  potassium 

'Semisynthetic  penicillins,  for  medicinal  use: 

'Ampicillin 

'Ampicillin ,  sodium 

Carbenicillin 

Cloxacillin,  sodium 

Die loxaci llin,  sodium 

Hetacillin 

Methicillin,  sodium 

Nafcillin,  sodium 

Oxacillin,  sodium 

Phenethicillin,  potassium 

'Tetracyclines : 

Chlortetracycline 

Chlortetracycline,  tor  nonmedicinal  uses 

Uemeclocycline 

Doxycycline 

Methacycline 

Minocycline 

Oxytetracycline 

Tetracycline 

'Other  antibiotics: 
'For  medicinal  use: 

Amphotericin  B 

Candicidin 

Cephalexin 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Clindamycin 

Cycloserine 

Dihydrostreptomycin 

Fumagillin 

.  Gentamycin 

Gramicidin 

Kanamycin 

Lincomycin 

Novobiocin 

Nystatin 

Oleandomycin 

Paromomycin 

Pol\-myxin    B 

Spectinomycin 

Streptomycin 

Thiostrepton 

Tro leandomy cin 

Vancomycin 

Viomycin 

See  footnotes  at  end  of  table. 


COM, 

PEN, 

PFZ, 

PMP 

ABB, 

LIL, 

UPJ. 

OMS, 

PEN, 

PFZ, 

UPJ 

PFZ. 

LIL, 

OMS, 

PFZ, 

WYT 

LIL, 

OMS, 

PFZ, 

WYT 

WYT. 
MRK, 

OMS. 

OMS. 

PFZ. 

BRS, 
WYT. 

LIL, 

OMS. 

BEE 
BEE 
BEE 
BEE 
BEE 
BRS 
BEE 
WYT 
BEE 
BRS 

ACY 
ACY 
ACY 
PFZ 
PFZ 
ACY 
PFZ 
ACY 


OMS. 
PEN. 
LIL. 
LIL. 
LIL. 


COM. 
MKK, 
ABB. 
sen. 
PEN. 
BRS. 
UP.]. 
MRK, 
ACY, 
PFZ. 
MKK. 
PFZ. 
ABB, 
LIL, 
OMS. 
PFZ. 
LIL. 
PFZ. 


LIL. 

BOC,  BRS,  TRD,  WYT. 

OMS,  IVYT. 

PFZ. 

BRS. 

BRS,  WYT. 

BRS. 

BRS. 


BRS,  PFZ,  RLS. 


UPJ. 
OMS. 


UPJ. 
MRK,  PFZ. 


SYNTHETIC  ORGANIC  CHE.IICALS,  1972 


Table  2.- 


-MeDICINAL    chemicals    for    which    U.S.    PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED   BY    MANUFACTURER,    1972— CONTINUED 


Manutacturers'    identification  codes 
(according   to    list    m   table   3) 


•Antibiotics   -rContinued 

*Other  antibiotics--Continued 
*For  nonmedicinal  uses: 

Bacitracin 

Cy cloheximide 

Hygronycin   B 

Li  ncomy c in 

Monensinj  sodium 

Novobiocin 

Nystatin 

Spectinomycin 

Streptomycin 

Tylosin 

•Antihistamines ; 
•Antinauseants : 

Cyclizine  liydrociiloride 

Dimenhydrinate 

Meclizine  hydrochloride 

Trimethobenzamide  hydrochloride 

Bromodiphenhydrami ne  hydroch loride 

Brompheniramine  maleate 

Carbinoxamine 

Chlorcyclizine  hydrochloride 

Chlorothen  citrate 

•Chlorpheniramine  maleate 

Chlorpheniramine  tannate 

Cyprohept adine  hydroch loride 

Dexbrompheniramine  maleate 

Dexchlorphenirajnine  maleate 

Dimethindene  maleate 

Diphenhydramine  hydrochloride 

Doxylamine  succinate 

Methapyrilene  fumarate 

Methapyrilene  hybenzate 

Methapyrilene  hydrochloride 

Methdilazine 

Methdilazine  hydrochloride 

Phenindamine  tartrate 

Pheniramine  maleate 

Phenyltoloxamine  citrate 

Pyrilamine  maleate 

Pyrilamine  resin  adsorbate 

Pyri 1 amine  t annate 

Pyrrobut amine  phosphate 

Thenyldi amine  hydrochloride 

Thonzylamine  hydrochloride 

Tripelennamine 

Tripelennamine  citrate 

Tripelennamine  hydrochloride 

iriprolidine  hydrochloride 

•Anti-infective  agents  (except  antibiotics): 
•Anthelmintics: 

2,2-Dichlorovinyl  dimethyl  phosphate  (DVPP)- 

Uiethylcarbamazine  citrate 

2,6-Uiiodo-4-nitrophenol 

Gentian  violet 

Hexylresorcinol 

Phenothiazine 

•Piperazine 

Piperazine  citrate 

•Piperazine  dihydroch loride 

Piperazine  hexahydrate 

"Piperazine  hydrochloride 

Piperazine  phosphate 

Piperazine  sulfate 


COM, 

GPR. 

PhN,    PMP. 

UPJ. 

LIL. 

UPJ . 

LIL. 

UPJ. 

QMS. 

UPJ. 

MRK, 

PFZ. 

LIL. 

BUR. 

HEX, 

SRL. 

PF2. 

HOF. 

PD. 

SCH. 

SCH. 

ABB, 

BUR. 

ALY. 

HEX, 

HFT, 

SCH,    SK. 

MAL. 

MRK. 

SCH. 

SCH. 

CGY. 

CAN, 

PD. 

BJL, 

BKC. 

ABB. 

LIL. 

ABB. 

BJL. 

BJL. 

HOF. 

HEX, 

HFT, 

SCH. 

BRS. 

HEX, 

MRK, 

MRK. 

MAL. 

LIL. 

SUW. 

NEP. 

CGY. 

CGY. 

CGY . 

BUR. 

SHC. 

ACY. 

RSA. 

SDH. 

NRK. 

WAG. 

DOW, 

FLM, 

JCC,    UCC 

BUR. 

DOW, 

FLM, 

JCC,    WIIL 

JCC. 

DUW, 

FLM, 

.ICC. 

BUR, 

JCC. 

JCC, 

SAL. 

^lEDICINAL  CHEMICALS 


Table  2. 


-Medicinal  chemicals  for  which  U,S,  production  or  sales  were  reported, 
identified  by  manufacturer,  1972— continued 


Manufacturers'  identification  codes 
(according  to  list  in  table  5) 


*Anti-infective  agents  (except  antibioticsJ--Continued 
*Anthelniintics- -Continued 

Pyrvinium  pamoate 

Thiabendazole 

'Antifungal  agents: 

Benzoic  acid 

Calcium  undecylenate 

Fuchsin,  basic 

Sodium  caprylate 

Sodium  undecylenate 

Undecylenic  acid 

Zinc  undecylenate 

*Antipropozoan  agents: 

Aklomide 

Amodiaquin 

Amodiaquin  hydrochloride 

Amprolium 

*Arsenic  and  bismuth  compounds: 

Arsanilic  acid 

Bismuth  dipropylacetate 

Bismuth  subsalicylate 

Carbarsone 

Glycobiarsol 

Nitarsone 

Roxarsone 

Roxarsonej  sodium 

Sodium  arsani late 

Chloroqulne  phosphate 

Dimetridazole 

Diiodohydroxyquin 

3,S-Dinitro-o-toluaraide 

Furazolidone 

Hydroxy ch loroquine  su 1  fate 

lodochlorhydroxyquin 

Metronidazole 

Nifuroxime 

Nifursol 

Nihydrazone 

Nithiazide 

Nitromide 

Nitrophenide 

Primaquine  phosphate 

Pyrimethamine 

*Mercury  compounds : 

Merbromin 

Mercuric  salicylate 

Ni tromerso 1 

Phenylmer curie  acetate 

Phenylmercuric  borate  

Phenylmercuric  chloride 

Phenylmercuric  nitrate 

Thimerosal 

'Sulfonamides: 

Acetyl  sulfamethoxypyridazine 

Acetyl  sulfisoxazole 

Dinsed 

Mafenide  acetate 

Mafenide  hydrochloride 

Phthalylsul facet amide 

Phthalylsulfathiazole 

Succinylsulfathiazole 

Sulfabenz amide 

Su 1 f aben  z ami de ,  s odium 

Sulfabromomethazine,  sodium 

Sulfacetamide 

Sulfacetamide,  sodium 

Su 1 f ach loropyraz ine ,  sodium 


MRK. 

MON. 
WTL. 
ACS. 
LEM. 
NIL. 
NIL. 
NTL,  IVIL. 

SAL. 
PU. 
PD. 
MRK. 

abb,  flm,  whl. 
nwl,  nor,  PBN. 

LIL,  WHL. 

SDW. 

SAL. 

SAL. 

SAL. 

SAL. 

SDW. 

RDA. 

SKL. 

DUW. 

NUR. 

SDW. 

CGY. 

RDA. 

NOR. 

LEM. 

NOR. 

MRK. 

PEN,  SAL. 

ALY. 

PD. 

BUR. 

HYN. 

MRK. 

ABB 

WRC. 

MRK. 

WRC. 

MRK,  WRC. 

LIL. 

ACY. 

HOF. 

SAL. 

SDW. 

SDW. 

CTN. 

MRK  . 

MRK. 

ACY. 

ACY. 

MRK. 

CIN. 

CTN. 

ACY. 


552-743  O  -  74  . 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


Table  2. --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported- 
identified  BY  manufacturer.  1972— CONTINUED 


* Anti-infective  agents  (except  antibiotics) --Continued 
*Sulfonamides--Continued 

Sulfachloropyridazine,  sodium 

Sulfadiazine 

Sulfadiazine,  sodium 

Sulfadimethoxine 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine,  sodium 

Sulfamethazine 

Sulfamethazine,  sodium 

Sulfamethizole 

Sulfamethoxazole 

Sulfamethoxypyridazine 

Sulfanilamide 

Sulfanitran 

Sulfapyridine 

Sulfapyridine,  sodium 

Sulfaquinoxaline 

Sulfathiazole 

Sulfathiazole,  sodium 

Sulfisoxazole 

Sulfisoxazole,  sodium 

•Other  anti-infective  agents: 

Acriflavine 

Aminacrine 

Aminacrine  hydrochloride 

Antileprotic  and  antitubercular  agents; 

Aminosalicylic  acid 

Ethionamide 

Isoniazid 

Sodium  aminosalicylate 

Sodium  sulfoxone 

Antiviral  agent:  Amantadine  hydrochloride 

Benzalkonium  chloride 

Bromoform 

Camphor ,  monobromated 

Garb  adox 

Cetalkonium  chloride 

Cetylpyridinium  chloride 

Chlorobutanol 

Furamazone 

8-Hydroxy-S-quinolinesulfonic  acid 

Iodoform^ 

Nalidixic  acid 

Nitrofurathiazide 

Nitrofurazone 

Oxolinic  acid 

Oxyquinoline 

Oxyquinoline  benzoate 

Oxyquinoline  citrate 

Oxyquinoline  sulfate 

Phenolic  antiseptics  and  disinfectants: 

Biothionol 

Chlorothymol 

Resorcinol' 

Thymol 

Thymol  iodide 

Povidine  -  iodine  complex 

Trimethoprim 

Urinary  antiseptics: 

Mandelic  acid 

Methenamine  base  and  salts: 

Methenamine 

Methenamine  hippurate 

Methenamine  mandelate 

Methylene  blue 

Nitrofurahtoin 

Phenazopyridine  hydrochloride 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


ACY. 

ACY. 

ACY. 

HOP. 

ACY,  SAL. 

ACY. 

ACY. 

ACY,  CTN. 

ACY. 

ACY,  CTN. 

HOP. 

ACY. 
MRK,  SAL. 

SAL. 

ACY,  CTN. 

ACY,  CTN. 

MRK. 

ACY,  MRK. 

MRK,  SAL. 

HOP. 

HOP. 

ACS. 
SDW. 
SDW. 

MLS. 

RDA. 

RIL. 

MLS. 

ABB. 

DUP. 

SDH. 

DOW. 

PEN. 

PF2. 

FIN,  SDW. 

FIN,  HEX. 

BPC,  PD. 

NOR. 

MRK. 

MAL. 

SDH. 

SCH. 

NOR. 

NEP. 

FIS,  MRK. 

FIS. 

FIS,  MRK. 

FIS,  MRK. 

SDH. 
ACY. 
KPT. 
GIV. 
MAL. 
GAF. 
BUR. 

MAL. 

ARN. 
RIK. 

MAL,  NEP. 
ACY. 

NOR,  RLS. 
HOP,  NEP. 


See  footnotes   at  end  of  table. 


MEDICINAL  CIIE'^IICALS 


Table  2. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972  — CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3} 


* Autonomic  drugs: 

'Parasympatholytic  (anticholinergic)  tertiary  amines: 

Adiphenine  hydrochloride 

Cycrimine  hydrochloride 

Dicyclomine  hydrochloride 

Orphenadrine  citrate 

Orphenadrine  hydroch loride 

Oxyphencyc limine  hydrochloride 

Piperidolate  hydrochloride 

Thiphenamil  hydrochloride 

Trihexyphenidyl  hydrochloride 

'Sympathomimetic  (adrenergic)  agents: 

Cinnamedrine  hydrochloride 

Cyclopent amine  hydrochloride 

Epinephrine  bitartrate  (levo) 

'Epinephrine  hydrochloride  (racemic) 

H- Isoproterenol  bitartrate 

Isoproterenol  i.)''roch loride 

I soprot ereno 1  sulfate 

Levarterenol  bitartrate 

Me thoxyphen amine  hydrochloride 

Naphazoline  hydrochloride 

Nordefrin  hydrochloride 

Nylidrin  hydrochloride 

'Phenylephrine  base  and  bitartrate: 

Phenylephrine 

Phenylephrine  bitartrate 

'Phenylephrine  hydrochloride 

•Phenylpropanolamine  hydrochloride 

Propylhexedrine 

Protokylol  hydrochloride-  

Pseudoephedrine  hydrochloride 

Pseudoephedrine  sulfate 

Tetrahydrozoline  hydrochloride 

'Other  autonomic  drugs: 

Ganglionic  blocking  agents: 

Hexamethonium  chloride 

Tetraethyl ammonium  chloride 

Parasvinpatholytic  (anticholinergic)  quaternary 
ammonium  compounds: 

Ambutonium  bromide 

Diphemanil  methyl sulfate 

Hexocyclium  methyl sulfate 

Isopropamide  iodide 

Mepenzolate  bromide 

Pipenzolate  bromide 

Tridihexethyl  iodiue 

Parasympatholytic  (anticholinergic)  tropane 
derivatives : 

Anisotropine  methyl bromide 

Benztropine  mesylate 

Homatropine  hydrobromide 

Homatropine  methylbromide  

Homatropine  terephthalate 

Parasympathomimetic  (cholinergic)  agents: 

Neostigmine  bromide 

Neostigmine  methyl  sulfate 

Physostigmine  salicylate 

Pyridostigmine  bromide 

Sympatholytic  (antiadrenergic)  agent:   Ergonovine 
maleate. 
'Cardiovascular  agents: 
'Vasodilators: 

Amy  I  nitrite 

Clonitrate 

Cyclandelate 

Dioxyline  phosphate 

Ethyl  nitrite 

Isosorbide  di nit rate 

Mannitol  hexanitrate 

Nicotinyl  alcohol  tartrate 

Pentaerythritol  tetranitrate 


CGY. 
LIL. 
BKC. 
RIK. 
RIK. 
PFZ. 
LKL. 
BJL. 
ACY,  SDW. 

SDW. 

LIL. 

SDW. 

ECL,  VB.  X. 

SDW. 

SDW. 

ABB. 

SDW. 

X. 

CGY. 
SDW. 
BKL. 

CTN,  CAN,  SDW. 

GAN. 

CTN,  GAN,  HEX,  SDW. 

ARS,  BKL,  GAN,  HEX,  NEP,  ORT,  PD. 

HEX,  SK. 

LKL. 

BUR,  GAN. 

GAN. 

PGZ. 


RSA. 
RSA. 


BJL. 

SCH. 

ABB. 

SK. 

LKL. 

LKL. 

ACY. 


CTN. 

CTN,  HEX. 
EN. 

HEX,  HOF. 

MOF. 

PEN. 

HOF. 

LIL. 


MAL. 
ICI. 
WYT. 
LIL. 
MAL. 
ICI. 
ICI. 
HOF. 
ICI. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 


Table  2. 


-Hedicinal  chemicals  for  which  U.S,  production  or  sales  were  reported, 
identified  by  manufacturer,  1972  — continued 


*CardiovascuJar  agents --Continued 

*Other  cardiovascular  agents: 

Antihypertensive  agents: 

Guanethidme  sulfate 

Hydralazine  hydrochloride 

Methyldopa 

Pargyline  hydrochloride 

Rauwolfia  and  veratrum  alkaloids: 

Alkavervir 

Kaunormine 

Reserpine 

Bioflavonoids : 

Hesperidin 

Lemon  bioflavonoids 

Naringin 

Cardiac  drugs: 

Procainamide  hydrochloride 

Quinidine  sulfate 

Colestipol 

*Central  depressants  and  stimulants: 
*Aiiiphetamines : 

Amphet amine  (racemi c) 

Amphetamine  sulfate  (racemic) 

Dextroamphetamine  hydrochloride 

Dextroamphetamine  phosphate 

Dextroamphetamine  sulfate 

Levamphet amine  succinate 

Methamphetamine  hydrochloride  (dextro)- 

Methamphet amine  saccharate 

•Analgesics  and  antipyretics: 

* Aspirin 

'Meperidine  hydrochloride 

♦Salicylates  (except  aspirinj: 

Aluminum  aspirin 

Phenyl  salicylate 

Potassium  salicylate 

Salicylamide 

Salicylsalicylic  acid 

Sodium  salicylate 

*Other  analgesics  and  antipyretics: 

Acetaminophen 

p-Arainobenzoic  acid  and  salts: 

Aminubenzoic  acid 

Calcium  aminobenzoate 

Potassium  aminobenzoate 

Sodium  aminobenzoate 

Anileridine  hydrochloride 

Calcium  succinate 

Dextropropoxyphene  napsylate 

Ethoheptazine  citrate 

Indome th  acin 

Mefenamic  acid 

Methadone  hydrochloride 

Oxycodone  hydrochloride 

Oxycodone  tereph thai ate 

Oxyphenbutazone 

Pentazocine 

Pentazocine  hydrochloride 

Phenacetin 

Phenylbutazone 

Propoxyphene  hydrochloride 

'Antidepressants : 

Ami tripty line 

Desipramine  hydrochloride 

Doxepin  hydrochloride 

Imipramine  hydrochloride 

Isocarboxazid 

Nialamide 

Nortriptyline 

Phenelzine  sulfate 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


CGY. 
CGY. 
MRK. 
ABB. 

RIK. 
PEN. 
PEN. 

SKG. 
bKG. 
SKG. 

QMS, 
HEX. 
UPJ. 


ORT. 
HEX. 
ARN. 
ARN. 
ARN, 
ARN. 
ARN. 
RSA. 


DOW,  MLS,  HON,  NOR,  SDG. 
PEN,  SDW,  WYT. 


DOW. 

HN. 

PEN. 


ATP,  MAL,  NEP,  PEN. 

LEM,  PD. 

GAN. 

GAN. 

GAN. 

MRK. 

LEM. 

LIL. 

WYT. 

MRK. 

PD. 

LIL.  MAL,  PEN. 

EN. 

EN. 

CGY. 

SDW. 

SDW. 

MON. 

CGY. 

LIL.  KLS. 


MRK. 
CGY. 
PF2. 
CGY. 
HOP. 
PFZ. 
LIL. 
NEP. 


MEDICINAL  CHEHICALS 


Table  2. --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to   list    in  table   3) 


■"Central    depressants   and  stimulants  —  Continued 
*Barbiturates : 

Allylbarbituric   acid,    sodium 

5-Allyl-5- (2-cyclopenten-l-yl)barbituric  acid 

Amobarbital 

Amobarbital ,    sodium 

Barbital 

Barbital,  sodium 

But  abarbi t  al 

Butabarbital ,  sodium 

5-sec-Butyl-5-ethyl-2- thiobarbituric  acid,  sodium 

derivative  

Hexobarbital 

Mephobarbital 

Metharbital 

Methohexital ,  sodium 

Pentobarbital 

*Pentobarbital ,  sodium 

Phenobarbital 

Phenobarbital ,  sodium 

Secobarbital-- 

Secobarbital ,  sodium 

Thiamylal ,  sodium 

Thiopental,  sodium 

Vinbarbital 

*Hydrocodone  bit art rate 

*Hypnotics  and  sedatives  (except  barbiturates): 

Carbroma 1 

Bthchlorvynol 

Ethinamate 

Glutethimide 

Methypry I  on 

*Skeletal  muscle  relaxants: 

Cari  soprodo 1 

Chlorphenesin  carbamate 

Mephenesin 

Phenaglycodol 

Succinyl choline  chloride 

Tubocurarine 

■"Tranquilizers ; 

Buclizine  hydrochloride 

Chlorazepate  dipotassium 

Chlordiazepoxide  hydrochloride 

Chlormezanone 

Chlorprothixene 

Diazepam 

Ethoxybutamoxane 

Hydroxyzine  hydrochloride 

Hydroxy zine  pamoat e 

Meprobamat  e 

Methaqualone 

Molindone  hydrochloride 

Oxazepam 

Phenothiazine  derivatives: 

Acetophenazine  maleate 

Chlorpromazine  hydrochloride 

Fluphenazine  hydrochloride 

Perphenazine 

Prochlorperazine  edisylate 

Prochlorperazine  maleate 

Promazine  hydrochloride 

Promethazine  hydrochloride 

Trif lupromazine  hydrochloride 

Thiothixene  hydrochloride 


GAM. 
CAN. 

GAN,  LIL. 
GAM,  LIL. 
GAN. 

ABB,  GAN. 
ABB,  GAN. 
ABB,  GAN. 


GAN,  bDW. 

GAN,  SDW. 

ABB. 

LIL. 

ABB,  GAN,  PD. 

ABB,  GAN,  PD. 

GAN,  MAL. 

GAN,  MAL. 

GAN. 

GAN,  LIL. 

GAN,  PD. 

ABB,  GAN. 

X. 

EN,  MAL,  MRK,  PEN. 


LIL. 

BKL, 

CGY 

HOF. 

BKL. 

UPJ. 

HEX. 

LIL. 

ABB, 

BUR 

ABB, 

OMS 

PFZ. 
ABB. 
HOF. 
SDW. 
HOF. 
HOF. 
LIL. 
PFZ. 
PFZ. 
ABB,  BKL. 

X. 

PD. 
WYT. 


OMS,  SCH. 
SCH. 
SK. 
SK. 

WYT. 
WYT. 
OMS. 
PFZ. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


Table  2, --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972  — CONTINUED 


*Central  depressants  and  stimulants— Continued 
*Other  central  depressants   and  stimulants: 
Anticonvulsants : 

Diphenylhydantoin 

Diphenylhydantoin,   sodium 

Ethosuximide 

Ethotoin 

Methsuximide 

Phenacemide 

Phensuximide 

Antitussives: 

Benzonatate 

Caramiphehen  edisylate 

Carbetapentane  citrate 

Codeine 

Dextromethorphan  hydrobromide 

Ethylmorphine  hydrochloride 

Thebaine 

General  anesthetic: 

Ket amine  hydrochloride 

Vinyl  ether 

Stimulants: 

Benzphet amine  hydrochloride 

Caffeine: 

Natural 

Synthetic 

Caffeine,  citrated 

Caffeine^  sodium  benzoate 

Chiorphentermine  hydrochloride 

Deanol  acetamidobenzoate 

Diethylpropion 

Naloxone  hydrochloride 

Nikethamide 

Phent ermine 

*Uermatological  agents  and  local  anesthetics: 
Dermatological  agents: 

Allantoin 

Aluminum  pheno Isul f onat e 

Ammonium  pheno Isu If onat e 

Bismuth  subgallate 

Glycol  salicylate 

'Salicylic  acid  ' 

Sodium  phenol sulfonate 

Zinc  phenol sulfonate 

Local  anesthetics: 

Butacalne  sulfate 

Butamben  pi crate 

Butyl  aminobenzoate  (Butamben) 

Dibucaine 

Dibucaine  hydrochloride 

Isobutyl  aminobenzoate 

Lidocaine 

Oxethazaine 

Phenacaine  hydrochloride 

Pramoxine  hydrochloride 

Procaine  hydrochloride 

Proparacaine  hydroch loride 

Propoxycaine 

Tetracaine 

'Diagnostic  agents: 

Roentgenographic  contrast  media: 

Acetrizoate,  sodium 

Diatrizoate,  meglumine 

Diatrizoate,  sodium 

lodipamide,  meglumine 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


PU. 
ABB. 

py. 

ABB. 
PU. 

CGY. 

SK. 

PFZ. 

MRK. 

HOF. 

MAL,  MRK. 

MRK 

PD. 


GNF. 

PFZ. 

MAL. 

GAN, 

MAL. 

NEP. 

RIK. 

BKC. 

MAL. 

CGY. 

HEX. 

HFT. 

MAL, 

SAL. 

SAL. 

MAL. 

RDA. 

DUW, 

HN,    MON, 

SAL. 

MAL, 

SAL. 

ABB. 

ABB. 

ABB. 

CGY. 

CGY. 

RSA. 

AST, 

RLS,    SDW. 

WYT. 

SDW. 

ABB. 

PFZ, 

UUP. 

QMS. 

SOW. 

SDW. 

MAL 

0Mb 

SUW. 

CMS, 

SDW. 

UMS 

See  footnotes  at  end  of  table. 


MEDICINAL  CHEMICALS 


Table  2. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY    MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list   in  table  3J 


•Diagnostic  agents--Continued 

Roentgenographic  contrast  media — Continued 

lodipamide,    sodium 

lodohippurate,    sodiujn 

lopanoic  acid 

lophendylate 

lothalamate,   meglumine 

lothalamate,    sodium 

Methiodal,    sodium 

Other  diagnostic  agents: 

Betazole  hydrochloride 

Indocyanine  green    (cardiac  output   test) 

Metyrapone    (pituitary  function   test) 

Phenolphthalein  monophosphate,   dicyclohexalamine  salt- 

Phenolsulfonphthalein    (kidney  function  test) 

•Expectorants   and  mucolytic  agents: 

*Ethylenediamine  dihydr iodide 

*Guaiacol   and   its   derivatives: 

Glyceryl   guaiacolate 

Guaiacol 

Potassium  guaiacol sulfonate 

lodinated  glycerol 

Lobe  line  sulfate 

Terpin  hydrate 

■fhonzonium  bromide 

•Gastrointestinal  agents  and  therapeutic  nutrients: 
•Amino  acids  and  salts: 

Amino  acid  mixtures 

Aspartic  acid 

Beta- alanine 

Glutamic  acid  and  salts: 

Glutamic  acid  hydrochloride 

Potassium  glutamate 

Lysine  hydroch loride 

H-Tyrosine 

•Choleretics  and  liydrocholeretics: 

Bile  acids,  oxidized 

Uehydrocholic  acid 

Florantyrone 

Iron  bile  salts 

Ox  bile  extracts 

Sodium  dehydrocholate 

Tocamphyl 

•Choline  chloride: 

Feed  grade 

Medicinal  grade 

•Other  gastrointestinal  agents  and  therapeutic 
nutrients : 
Gastrointestinal  agents: 
Cathartics : 

Magnesium  citrate 

Phenolphthalein 

Podophyllin 

Sodium  tartrate 

Lipotropic  agents: 

Betaine  base 

Betaine  hydrochloride 

Choline  bicarbonate 

Choline  bi tart rate 

Choline  citrate  (Iricholine  citrate) 

Choline  dihydrogen  citrate 

Methionine,  hydroxy  analogue,  calcium  salt 

Sitosterols 


QMS. 

mal. 

SDW. 

x. 

MAL. 

MAL. 

SDW. 


CGY. 
NEP. 
EK. 


HFT,  MAL,  WAG,  WHL. 


GAN,  HEX,  PEN. 
MON. 


PEN. 
NEP. 


MDJ. 
HEX. 
DA,  HFT. 

LEM. 
LEM. 
MRK. 
MDJ. 

SRL.  WIL. 
WIL. 
SRL. 

LIL,  WIL. 
ABB,  WIL. 
WIL. 

X. 

CUM,  DA,  DOW,  HFT,  TMH. 
HFT. 


MON. 

ABB, 

PEN 

MAL 

HFI. 

HFT. 

CUM. 

ACY, 

HFT 

ACY, 

HFT 

ACY, 

HFT 

DUP, 

MON 

LIL, 

UPJ 

SYNTHETIC  ORGANIC  CHE^ICUS.  197? 


Table  2- 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY    MANUFACTURER,    1972--CoNTINUED 


♦Gastrointestinal   agents   and  therapeutic 

nutrients- -Continued 

*Other  gastrointestinal   agents   and  therapeutic 

nutrients- -Continued 

Gastrointestinal   agents — Continued 

Other  gastrointestinal    agents: 

Dihydroxyaluminum  aminoacet at e 

Pectin 

Therapeutic  nutrients: 

Calcium  glucoheptonate 

Calcium  gluconate 

Copper  gluconate 

Ferrous  gluconate 

Liver  concentrate 

Liver,  desiccated 

Magnesiun  gluconate 

Manganese  gluconate 

Potassium  gluconate 

Zinc  glucoheptonate 

'Hematological  agents: 
Anticoagulants: 

Ammonium  heparin 

Anisindione 

Bishydroxycoumarin 

Diphenadione 

*  Sod  ium  heparin 

Warfarin 

*Other  hematological  agents: 

Cellulose,  oxidized 

Dextran 

Protamine 

*Hormones  and  synthetic  substitutes: 
•Antithyroid  agents: 

Methimazole 

Propy 1 1 h  iour ac  i 1 

2-lhiouracil 

♦Corticosteroids : 

Betamethasone 

Betamethasone  phosphate 

Betamethasone  valerate 

Cortisone  acetate 

Dexamethasone 

Dexamethasone  phosphate 

Fludrocortisone  acetate 

Fluorometholone 

9a-Fluoroprednisolone  acetate 

Fluprednisolone 

Hydrocortisone 

Hydrocortisone  acetate 

Medrysone 

Methylprednisolone 

Prednisolone 

Prednisolone  acetate 

Prednisone 

Triamcinolone 

iriamcinolone  acetonide 

♦Estrogens  and  progestogens: 

Chlorotrianisene 

Dienestrol  diacetate 

Diethylstilbestrol 

Diethylstilbestrol  diphosphate 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


CHT. 
SKG. 

PFN 
PFZ, 
PFZ. 
PFZ. 

WIL. 
WIL. 
PFZ. 
PFZ. 
PFZ. 


ABB, 

WIL. 

SCH. 

ABB. 

UPS. 

ABB, 

RIK, 

WIL 

SDW. 

EKT. 

PHK. 

lil 

LIL. 

CTN. 

ACY . 

bCH. 

SCH. 

SCH. 

MRK, 

UPJ. 

MKK, 

SCH. 

MRK. 

UPJ. 

UPJ. 

UPJ. 

UPJ. 

MKK, 

PFZ, 

UPJ 

MRK, 

UPJ. 

UPJ. 

UPJ. 

MRK, 

UPJ. 

UPJ. 

MKK, 

SCH, 

UPJ 

ACY, 

UMS, 

X. 

OMS. 

BJL, 

BKC. 

SCH. 

CTN 

LIL. 

MEDICINAL  CHEfllCALS 


Table  2,- 


-FIeDICINAL   chemicals    for    which    U.S.    PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
(according  to   list   in  table  3) 


*Horinones   and  synthetic  substitutes  —  Continued 

'Estrogens   and  progestogens--Continued 

hstrogenic   substances,    conjugated 

MedroxvTirogesterone   acetate 

Melengestrol   acetate 

Natural   estrogenic   substance 

Norgestrel 

Progesterone 

'Synthetic  hypoglycemic  agents: 

Acetohexamide 

Chlorpropamide 

Phenformin   hydrochloride 

Tolazamide 

I'D  Ibut  amide 

*Other  hormones  and  synthetic  substitutes: 
Anabolic  agents  and  androgens: 

Fluoxymesterone 

Testosterone  cypionate 

Zeranol 

Corticotropin  (ACTH) 

Glucagon 

Insulin 

Ihyroid 

*Renal-acting  and  edema-reducing  agents: 

*Benzothiadiazine  derivatives: 

Bendrof lumethiazide 

Benzthiazide 

Chlorothiazide 

Cyclothiazide 

F lumethiazide 

Hydrochlorothiazide 

Hydroflumethiazide 

Met hyc loth lazide 

Polythiazide 

Irichlormethiazide 

'Mercurial  diuretics: 

Meralluride 

Mersalyl  acid 

Sodium  mercaptomeri n 

'Theophylline  derivatives: 

Aminophylline 

Oxtriphylline 

Theophylline  sodium  glycinate 

'Other  renal-acting  and  edema- reducing  agents: 

Acetazol amide 

Chlorthalidone 

Dichlorphenamide 

Ethacrynic  acid 

Probenecid 

Triamterene 

'Vitamins : 

'Vitamin  A  alcohol  and  esters: 

Beta-carotene  (Provitamin  A) 

Vitamin  A  acetate  (feed  grade) 

Vitamin  A  acetate  (medicinal  gradej 

Vitamin  A  alcohol 

'Vitamin  A  palmitate  (feed  gradej 

Vitamin  A  palmitate  (medicinal  grade) 


ORG. 
UPJ. 
UPJ. 
OKG. 
WYT. 
UPJ. 

LIL. 
PFZ. 
BKL. 
UPJ. 
UPJ. 


UPJ. 
UPJ. 
COM. 
ORG. 
LIL. 
LIL. 
LIL. 


MKK. 
LIL. 
UMS. 
ABB, 


LGY,  MRK. 


LKL. 

SUW. 

WYT. 

GAN, 

SRL. 

NEP. 

CHT. 

ACY. 

CGY. 

MRK. 

MRK. 

MRK. 

ACY, 

SK. 

EKT, 

HOF. 

HOF, 

PFZ. 

HOF, 

PFZ. 

HOF, 

PFZ. 

EKT, 

HDF, 

PF 

EKi, 

HUF, 

PF 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 


Table  2. 


-Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


'Vitamins --Continued 
*Vitamin   B-complex: 

*Niacin  and  niacinamide   (all   grades) : 

Niacin   (nicotinic  acid)    (feed  grade) 

Niacin    (nicotini'-  acid)    (medicinal   grade) 

Niacinamide 

'Pantothenic  acid  and  derivatives: 

Calcium  pantothenate   (dextro) 

Calcium  pantothenate   (racemic)    (feed  grade) 

Calcium  pantothenate    (racemic)    (medicinal   grade)-- 
*Calciuin  pantothenate    (racemic)    -   calcium  chloride 
complex. 

Choline  pantothenate 

Dexpanthenol 

Panthenol    (racemic) 

Sodium  pantothenate 

'Riboflavin  (all  grades): 

Riboflavin  (feed  grade) 

Riboflavin  (medicinal  grade) 

'Other  B-complex  vitamins: 

Biotin 

Cyanocobalamin  (feed  grade) 

Cyanocobalamln  (medicinal  grade) 

Cyanocobalamin  (U.S. P.  crystalline) 

Cyanocobalamin  with  intrinsic  factor  concentrate-- 

Inositol 

Ni acinami de  hydrochloride 

Pyridoxine 

Riboflavin-5 -phosphate,    sodium 

Thi amine  hydroch loride 

Thiamine  mononitrate 

'Vitamin  C: 

'Ascorbic  acid 

falcium  ascorbate 

Sodium  ascorbate 

'Vitamin  D: 

Cholecalciferol  (Vitamin  D3) 

Ergocalciferol  (Vitamin  Dj) 

'Vitamin  E: 

d- Alpha  tocopherol 

dl -Alpha  tocopherol 

*d-  and  dl-Alpha  tocopheryl  acetate  (all  grades) : 

d-Alpha  tocopheryl  acetate 

dl-Alpha  tocopheryl  acetate: 

Feed  grade 

Medicinal  grade 

Technical  grade 

d-Alpha  tocopheryl  acid  succinate 

'Vitamin  K: 

Menadiol  sodium  diphosphate 

Menadione 

Menadione  sodium  bisulfite 

Phytonadione 

'Miscellaneous  medicinal  chemicals: 
Antineoplastic  agents: 

Azathioprine 

Mercaptopurine 

Thioguanine 

Vinblastine  sul fate 

Vincristine  sulfate 

Smooth  muscle  relaxants: 

Alverine 

Alverine  citrate 

Alverine  hydrochloride 

Papaverine  hydrochloride 

Sodium  benzyl  succinate 


DA, 

MRK, 

RIL. 

MRK 

RIL 

SCR. 

MRK 

NEP 

PD,  RIL, 

SCR 

HFT 
CKL 

DA, 

HFT,  PHF. 

DA, 

HFT. 

CKL 

DA, 

DLI,  HFT. 

dli 

HFT 

HOF 

HOF 

PD. 

GPR,  HOF,  MRK,  PMP. 
DA,  HOF,  MRK. 


HOF 

MRK 

MRK 

MRK 

WIL 

STA 

NEP 

HOF 

MRK 

HOF 

HOF 

MRK 

HOF 

MRK 

HOF 

MRK 

PFZ. 

PFZ 

HOF 

MRK 

PFZ. 

DA, 

DLI, 

PHF,  VTM 

SCR 

VTM 

CW, 

EKT. 

HOF 

CW, 

EKT. 

HOF 

DA, 

EKT, 

HOF. 

DA. 

CW, 

EKT. 

HOF. 

ABB,  HET,  WHL. 

ABB,  DA,  DLI,  HET,  HFT,  WHL. 

MRK. 


BUR. 
BUR. 
BUR. 
LIL. 
LIL. 


CTN. 

X. 

CTN. 

LIL,  MAL,  PEN. 

FIN. 


MEDICINAL  CHEMICALS 
Table  2, --Medicinal  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972--C0NTI NUED 


Chemical 

Manufacturers'    identification  codes 
(according  to  list   in  table   3) 

Miscellaneous  medicinal   chemicals--Continued 
Unclassified  medicinal   chemicals: 

BUR. 

PEN. 

SOW. 

PEN. 

BID,   HOF. 

MRK. 

ALD. 

Berberine  hydrochloride 

Dopamine  hydrochloride 

Hydras t ine  hydroch lori de 

Penicillamine    (copper  chelating   agent) 

All   antibiotics   listed  are   for  medicinal   use  unless  otherwise  specified. 
Producers   of  technical   grade  are   listed  in  "Miscellaneous   chemicals." 
Producers  of  technical   grade  are   listed  in  "Cyclic  intermediates." 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


TABLE  3.— Medicinal  Chemicals:     Directory  of  Manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 

[Names  of  manufacturers  that  reported  production  or  sales  of  medicinal  chemicals  to  the  U.S.  Tariff  Commission  for 
1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Name  of  company 


Name  of  company 


Abbott  Laboratories 

Allied  Chemical  Corp.,  Specialty  Chemicals  Div. 

American  Cyanamid  Co, 

Aldrich  Chemical  Co.,  Inc. 

Arenol  Chemical  Corp. 

Arsynco,  Inc. 

Astra  Pharmaceutical  Products,  Inc. 

Northern  Fine  Chemicals,  Inc. 

Beecham,  Inc. 

Bio-Derivatives  Corp. 

Burdick  5  Jackson  Laboratories,  Inc. 

J.T.  Baker  Chemical  Co. 

Millmaster  Onyx  Corp.,  Millmaster  Chemical  Div. 

Berkeley  Chemical  Dept . 
Biocraft  Laboratories,  Inc. 
Stauffer  Chemical  Co.,  Specialty  Chemical  Div., 

Benzol  Products 
Bristol-Myers  Co.,  Bristol  Laboratories  Div. 
Burroughs-Wellcome  Co. 

Ciba-Geigy  Corp.  and  Ciba  Pharmaceutical  Co. 
Chattem  Drug  5  Chemical  Co.,  Chattem  Chem- 
icals Div. 
Chemlek  Laboratories,  Inc. 
Commercial  Solvents  Corp. 
Chemetron  Corp.,  Organic  Chemical  Div. 
General  Mills  Chemical,  Inc. 

Diamond  Shamrock  Corp. 

Dawe's  Laboratories,  Inc. 

Dow  Chemical  Co. 

E.I.  duPont  de  Nemours  5  Co. ,  Inc. 

Eastside  Chemical  Laboratory 
Eastman  Kodak  Co. : 

Tennessee  Eastman  Co.  Div. 
Endo  Laboratories,  Inc. 

Fine  Organics,  Inc. 
Fisher  Chemical  Co.,  Inc. 
Fleming  Laboratories,  Inc. 

GAF  Corp.,  Chemical  Div. 

Cane's  Chemical  Works,  Inc. 

Givaudan  Corp. 

General  Foods  Corp.,  Maxwell  House  Div. 

Grain  Processing  Corp. 

Heterochemical  Corp. 

Hexagon  Laboratories,  Inc. 

Hoffman-Taff,  Inc. 

Tenneco  Chemicals,  Inc. 

Hoffmann- LaRoche,  Inc. 

Hynson,  Westcott  5  Dunning,  Inc. 

ICI  America,  Inc.,  Atlas  Chemical  Div. 

Jefferson  Chemical  Co.,  Inc. 

Koppers  Co.,  Inc.,  Organic  Materials  Div. 

Lemke  Chemicals,  Inc. 
Eli  Lilly  S  Co. 


MAL 
MDJ 
MLS 
MON 
MRK 

NEP 
NES 
NOR 

NTL 

OMS 
ORG 
ORT 


PEN 
PFN 
PFZ 
PHF 
PHR 
PMP 

RDA 
RIK 
RIL 
RLS 
RSA 

SAL 
SCH 
SCR 

SDG 

SDH 

SDW 

SHC 

SK 

SKG 

SRL 

STA 

TMH 
TRD 

UCC 
HOP 
UPJ 


WAG 
WHL 
WIL 
WRC 
IVTL 


Lakeside  Laboratories  Div.  of  Colgate- 
Palmolive  Co. 

Mallinckrodt  Chemical  Works 

Mead  Jolinson  5  Co. 

Miles  Laboratories,  Inc.,  Marschall  Div. 

Monsanto  Co. 

Merck  5  Co.  ,  Inc . 

Nepera  Chemical  Co.,  Inc. 
Nease  Chemical  Co.,  Inc. 
Norwich  Pharmacal  Co. 
NL  Industries,  Inc. 


E.R.  Squibb  S  Sons, 
Organics,  Inc. 
Roehr  Chemicals,  Inc 


Inc. 


Parke,  Davis  S  Co. 

CPC  International,  Inc., 

Pfanstiehl  Laboratories, 

Pfizer,  Inc. 

Thompson-Hayward  Chemical  Co. 

Pharmachem  Corp. 

Premier  Malt  Products,  Inc. 


Peter  Hand  Div. 


Rhodia,  Inc. 

Riker  Laboratories,  Inc.,  Sub.  of  3M  Co. 

Reilly  Tar  ^   Chemical  Corp. 

Rachel le  Laboratories,  Inc. 

R.S.A.  Corp. 

Salsbury  Laboratories 
Schering  Corp. 
R.P.  Scherer  Corp. 
Sterling  Drug  Corp. : 

Glenbrook  Laboratories  Div. 

Hilton-Davis  Chemical  Co.  Div. 

Winthrop  Laboratories  Div. 
Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 
Smith,  Kline  5  French  Laboratories 
Sunkist  Growers,  Inc. 
G.D.  Searle  5  Co. 
A.E.  Staley  Manufacturing  Co. 

Thompson-Hayward  Chemical  Co. 
Trade  Enterprises,  Inc. 

Union  Carbide  Corp. 

Universal  Oil  Products  Co.,  UOP  Chemical  Div. 

Upjohn  Co. 

Vermi lye- Bell 
Vitamins,  Inc. 

West  Agro-Chemicals,  Inc. 
Whitmoyer  Laboratories,  Inc. 
Wilson  6  Co.,  Inc.,  Wilson  Laboratories  Div. 
Ventron  Corp.,  Ventron  Chemical 
Pennwalt  Corp.,  Lucidol  Div. 
Wyeth  Laboratories,  Inc.,  Wyeth  Laboratories 
Div.  of  American  Home  Products  Corp. 


-Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix 


121 


FLAVOR  ANB  PERFUME  MATERIALS 


Flavor  and  perfume  materials  are  organic  chemicals  used  to  impart 
flavors  and  odors  to  foods,  beverages,  cosmetics  and  soaps.   These 
aromatic  chemicals  are  also  utilized  to  neutralize  or  mask  unpleasant 
odors  in  industrial  processes  and  products  as  well  as  in  consumer 
products. 

Total  domestic  production  of  flavor  and  perfume  materials  in  1972 
amounted  to  110.5  million  pounds--an  increase  of  14.6  percent  compared 
to  96.4  million  pounds  produced  in  1971  (table  1).^   Sales  of  these 
materials  in  1972  amounted  to  104.0  million  pounds,  valued  at  $88.4 
million,  compared  with  84.8  million  pounds,  valued  at  $84.0  million  in 
1971. 

Production  of  cyclic  flavor  and  perfume  materials  in  1972  amounted 
to  51.8  million  pounds;  sales  amounted  to  48.2  million  pounds,  valued 
at  $54.1  million.  The  individual  chemical  in  the  cyclic  group  produced 
in  the  greatest  volume  in  1972  again  was  benzyl  alcohol  (10.4  million 
pounds) . 

U.S.  output  of  acyclic  flavor  and  perfume  materials  in  1972  amounted 
to  58.5  million  pounds;  sales  of  these  materials  amounted  to  55.7  million 
pounds,  valued  at  $34.1  million.  Monosodium  glutamate  was  by  far  the  most 
important  of  the  acyclic  chemicals,  and  the  individual  flavor  and  perfume 
chemical  produced  in  the  greatest  volume. 

Domestic  production  of  essential  oils,  chemically  modified,  in  1972 
amounted  to  119  thousand  pounds;  sales  amounted  to  93  thousand  pounds  and 
were  valued  at  $220  thousand.   Both  cyclic  and  acyclic  compounds  were  rep- 
resented among  the  group,  however,  the  totals  above  for  cyclic  and  acyclic 
flavor  and  perfume  materials  do  not  include  items  of  this  group. 


See  also  table  2  which  lists  these  materials  and  identifies  the 
manufacturers  by  codes.  These  codes  are  given  in  table  3. 


SY:JTHETIC  organic  chemicals,  1972 


TABLE  1. --Flavor  and  perfume  materials;  U.S.  production  and  sales,  1972 

[Listed  below  are  all  synthetic  organic  flavor  and  perfume  materials  for  which  any  reported  data  on  production  or 
sales  may  be  published.  (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  pub- 
lished or  where  no  data  were  reported.)  Table  2  lists  all  flavor  and  perfume  materials  for  which  data  on  produc- 
tion or  sales  were  reported  and  identifies  the  manufacturers  of  each] 


Quantity 


1,000 
pounds 


Grand  total 

FLAVOR  AND  PERFUME  MATERIALS,    CYCLIC 

Total 

Benzenoid  and  Naphthalenoid 

Total 

4-Allyl-2-methoxyphenol    (Eugenol) 

p-Anisaldehyde 

Ben  zophenone 

Benzyl    acetate 

Ben zyl    al cohol ^ 

Ben  zy  1  benzoate 

Benzyl  but yr ate 

Benzyl   cinnamate 

Benzyl  propionate 

Benzyl   salicylate 

Cinnamaldehyde 

Cinnamyl  acetate 

Cinnamyl   alcohol 

Cinnamyl    an th rani  late 

Ethyl  phenylglycidate 

Hydrocoumarin 

Isobutyl   phenyl  acetate 

Isobutyl   salicylate 

Isopentyl   salicylate 

Methyl   anthranilate 

a-Methylbenzyl    acetate    (Styralyl    acetate) 

Methyl   phenyl acetate 

Methyl   salicylate 

Phenethyl    acetate 

2-Phenethyl  phenylacetate 

3-Phenyl-l-propanol    (Hydrocinnamic   alcohol) 

Piperonal    (He lio tropin) 

p-Propenylanisole    (Anethole) 

p-Tolualdehyde 

All  other  benzenoid  and  naphthalenoid  materials-- 

Terpenoid,   Heteroayolio,   and  Aliayclic 

Total 

Cedryl    acetate 

a-Ionone 

p-Menthan-3-one    (Methone) 

Menthol,    synthetic,  u.S.P 

Methylionones 


51.809 


45,756 


473 
1,065 

449 

1,414 

10,440 

408 


419 
1,565 


5,828 


2,650 
17,944 


8,053 


48.166 


41,311 


380 

1,261 

300 

1,678 

13,444 

621 

11 

7 

34 

450 

1,127 

9 

277 

1 


453 
185 


124 
,540 


1,000 
dollars 


54,058 


41,134 


1,044 

1,683 

407 

657 

3,922 

350 

16 

30 

40 

411 

790 


21 

14 

313 

269 


48 
61 
337 
1,537 
103 
25,709 


497 

378 


1,874 
1,665 


See   footnotes   at   end  of  table. 


FLAVOR  A;1D  PERFUIE  '1ATER1ALS 
TABLE  1.— Flavor  and  perfume  materials;  U.S.  production  and  sales. 


1972--CONTINUED 


Production 


Quantity 


Unit 
value' 


FLAVOR  AND  PERFUME  MATERIALS,    CYCLIC--Continued 

Terpenoid,   Heteroayclia,   and  Alieyolio — Continued 

Terpineols 

a-Terpinyl    acetate 

Vetivenyl    acetate 

All   other  terpenoid,   heterocyclic,   and  alicyclic  materials- 

FLAVOR  AND   PERFUME  MATERIALS,    ACYCLIC 

Total 

Allyl  hexanoate 

Citronellyl   acetate 

3,7-Dimethyl-cis-2,6-octadien-l-ol    (Nerol) 

3,7-Dimethyl-trans-2,6-octadienal    (Citral   a;   Geranial) 

3,7-Dimethyl-trans-2,6-octadien-l-oI    (Geraniol) 

3,7-DimethyI-6-octen-l-ol  (Citronellol) 

Ethyl  butyrate 

Ethyl  heptanoate 

Ethyl  hexanoate  (Ethyl  caproate) 

Geranyl  acetate 

Gerany 1  butyrate 

Geranyl  formate 

Glutamic  acid,  monosodium  salt  (Monosodium  glutamate) 

7-Hydroxy-3,7-dimethyl-l-octanal  (Hydroxycitronellal) 

Isopentyl  butyrate 

Isopentyl  formate 

Isopentyl  isovalerate 

Rhodinol 

All  other  acyclic  materials 

ESSENTIAL  OILS,  CHEMICALLY  MODIFIED 

Total 

Ethyl   oxyhydrate 

Guaicwood  acetate 

All   other  chemically  modified  essential   oils 


1,000 
pounds 


3,017 
585 


18 
53 

1,196 

1,004 

532 


47,324 


1,000 
pounds 


!,778 
52-7 


876 
587 
468 


48,136 
442 


1,000 
dollars 


1,163 
403 
560 

6,485 


36 

119 

137 

1,473 

966 

302 

15 

10 

201 

11 

29 

21,646 

2,440 

70 


Per 

pound 


$0.42 

.77 

20.27 

2.70 


_.61_ 
2.46 

3.28 
4.67 
1.68 
1.65 

.65 
1.45 
1.98 
2.00 
2.98 
3.20 

.45 
5.52 

.78 
1.56 


.94 
2.72 
3.45 


'Calculated  from  the  unrounded  figures. 
^Includes   some  technical  grade. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972- 
TABLE  2. --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED,     IDENTIFIED    BY    MANUFACTURER,    1972 


[Flavor  and  perfume  materials   for  which  separate  statistics   are  given   in  table   1  are  marked  below  with   an   asterisk 
(*);    those  not   so  marked  do  not   appear  in  table  2  because  the  reported   data  are   accepted  in   confidence   and  may 
not  be  published.      Manufacturers'    identification   codes   are  taken   from  table   3.      An   x  signifies   that   the  manufac- 
turer did  not   consent   to  his    identification  with   the  designated  product] 


Manufacturers'    identification   code 
(according  to   list  in  table   3) 


FLAVOR  AND   PERFUME  MATERIALS,    CYCLIC 
Benzenoid  and  Naphthalenoid 


2' -Acetonaphthone 

Acet  ophenone 

l-Acetoxy-2-sec-butyl-l-ethnylcyclohexane 

5-Acetyl-l,l,2,3,3,6-hexamethylindan 

p-Allylanisole 

Allyl   cyclohexyl  propionate 

4-Allyl-l,2-dimethoxybenzene    (4-Allylveratrole) 

*4-Allyl-2-methoxyphenol  (Eugenol) 

4-Allyl-2-methoxyphenoI   acetate   (Eugenol   acetate) 

4- Allyl -1,2- (methylenedioxy) benzene   (Safrole) 

Allyl  phenoxyacetate 

p-tert-Amylcyclohexanone    (Grivone) 

*p-Anis aldehyde 

Anisole    (Methyl  phenyl   ether) 

Anisyl   acetate 

*Benzophenone 

*Benzyl   acetate 

'Benzyl   alcohol 

*Benzyl  benzoate 

*Benzyl  butyrate 

*Benzyl  cinnamate 

Benzyl  ether 

Benzyl    formate 

Benzyl   glyceryl   acetal 

Benzyl    isobutyrate 

Benzyl   isopentyl  ether 

Benzyl   isovalerate 

Benzyl    laurate 

1- (Benzyloxy) -2-methoxy-4-propenylbenzene   (Benzyl 
isoeugenyl   ether). 

Benzyl  phenylacetate 

*Benzyl   propionate 

*Benzyl   salicylate 

a-Bromostyrene 

2-5ec-Butylcyclohexanone 

p-tert-Butylcyclohexyl   acetate 

4-tert-Butyl-2' ,6' -dimethyl- 3' ,5' -dinitroacetophenone 

(Musk  ketone). 
6-tert-Butyl-3-methyl-2,4-dinitroanisole    (Musk   ambrette)- 

p-tert-Butyl-a-methylhydrocinnamaldehyde 

l-tert-Butyl-3,4,5-trimethyl-2,6-dinitrobenzene   (Musk 
Tibetene) . 

5-tert-Butyl-2, 4, 6-trinitro-m- xylene  (Musk  .xylol) 

Carvacrol 

*Cinn  amal dehy de 

Cinnami c  acid 

*Cinnamyl  acetate 

*Cinnamyl  alcohol 

*Cinnamyl  anthranilate 

Cinnamyl  butyrate 

Cinnamyl  cinnamate 

Cinnamyl  propionate 

Cinnamyl  tiglate 

Coumarin 


GIV. 

GIV. 

GIV. 

PFW. 

GIV,   GLD. 

GIV. 

GIV,    UOP. 

CI,   FB,    GIV,    IFF,    PEN,    RT,    UNG,    UOP 

CI,    GIV. 

FB,    GIV. 

GIV. 

IFF. 

GIV,   OPC,    UOP. 

GIV. 

ELN,    GIV,    UOP. 

GAF,    GIV,    NEC,    PD,    UOP. 

GIV,   MON,    OPC,    UOP. 

BPC,    HN,   MNR,    UOP,   VEL. 

MON,   OPC,    PFZ,   UOP,    VEL. 

ELN,    FB,   GIV. 

FB,    GIV,    UOP 

UOP,    VEL. 

GIV,    UOP. 

GIV. 

GIV. 

GIV. 

FB. 

GIV. 

GIV,    UOP. 

ELN,    GIV. 

ELN,    FB,    GIV,    OPC. 

GIV,   MON,    UOP. 

UOP. 

GIV. 

CI,    IFF. 

GIV. 

GIV. 

GIV,    UOP. 

GIV,    UOP. 

GIV. 

GIV. 

CI,    FB,    UOP. 

BPC. 

ELN,    FB,    GIV. 

FB,    GIV,    NEO,   UOP. 

PEL,   GIV,    RT. 

FB. 

FLAVOR  AND  PERFUHE  MATERIALS 


TABLE  2. --Flavor  and  perfume  materials  for  which  U.S.   production  or  sales  were 

REPORTED,     IDENTIFIED    BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification   codes 
(according   to    list    in  table   3) 


FLAVOR  AND   PERFUME  MATERIALS,    CYCLIC— Continued 
Bemenoid  and  Naphthalenoid — Continued 


Cuminyl   alcohol 

Cyclohexylcychohexanone 

trans- Decahydro-B-napht hoi 

2,4-Dibromo-6-nitro-meta-cresyl  methyl   ether 

1 ,2-  Diiiiethoxy-4-propenylbenzene    (4-Propenylveratrole) 

p-a-Dimethylbenzyl   alcohol 

3,7-Dimethyl-l ,6-octadien-3-yl ,    anthranilate    (Linalyl 

anthranilate) . 
3,7-Dimethyl-l,6-octadien-3-ol ,    benzoate    (Linalyl 

benzoate) . 
3,7-Dimethyl-l ,6-octadien-3-ol ,    cinnamate    (Linalyl 

cinnamate 
3, 7-Dimethyl-2 ,6-octadienylphenylacetate    (Geranyl 

phenylacetate) . 
trans-3 ,7-Dimethyl-2 ,6-octadien-l-ol ,   benzoate    (Geranyl 

benzoate) . 

a,a-Dimethylphenethyl  acetate 

a,a-Dimethylphenethyl  alcohol 

a,a-Dimethylphenethyl  alcohol,  butyrate 

a,a-Dimethylphenethyl  alcohol,  tech 

Diphenylme thane  f Benzylbenzene) 

1 ,3-Diphenyl-2-propanone  (Dibenzyl  ketone) 

p-Ethoxy  benzaldehyde 

2-Ethoxynaphthalene 

Ethyl  anthranilate 

Ethyl  benzoate 

Ethyl  cinnamate 

Ethyl  a,B-epoxy-B-methylhydrocinnamate 

2-Ethylhexyl  salicylate 

Ethyl  phenylacetate 

*Ethyl  phenylg lye i date 

Ethyl  salicylate 

3'-Ethyl-5' ,6' ,7' ,8' -tetrahydro-5' ,5' ,8' ,8' - 

tetramethyl-2'-acetonaphthone. 

Ethylvanillin  (4-Hydroxy-3-ethoxybenzaldehyde) 

1 ,3,4,6,7,8-Hexahydro-4,6,6,7,8,8-hexamethyl  cyclopenta- 

gamma-2-henzopyran  (Galaxolide  50). 

Hexyl  benzoate 

a-Hexylcinnajnaldehyde 

Hydra tropaldehyde 

Hydratropaldehyde,  dimethyl  acetal 

Hydrocinnamic  acid 

*Hydrocoumarin 

Hydroxycitronellalmethyl  anthranilate 

4- (4-Hydroxy-3-methoxyphenyl)-2-butanone 

Indole 

Isoamyl  phenylacetate 

Isobutyl  benzoate 

p-Isobutyl-a-mathylhydrecinnamaldehyde  (Rhodial) 

*Isobutyl  phenylacetate 

Isobutylquinoline 

*lsobutyl  salicylate 

Isohexenyl  tetrahydrobenzaldehyde  (Myrac  aldehyde) 

Isopentyl  benzoate 

'Isopentyl  salicylate 


GIV. 

GIV. 

IFF. 

GIV. 

GIV,  UOP. 

GIV. 

FMT. 

HOF. 

HOF. 

GIV. 

GIV. 

IFF. 

IFF. 

IFF. 

IFF. 

ARA,  UOP. 

GIV. 

GIV. 

GIV. 

FB. 

ELN. 

ELN,  GIV. 

ELN,  GIV. 

FEL. 

GIV. 

GIV,  PFW,  UOP. 

FB. 

GIV,  MOP. 

GIV,  UOP. 

MON,  SLV. 

IFF. 


IFF 
IFF. 
IFF. 


GIV. 

CI, 

GIV, 

GIV, 

ARS. 

ARS, 

GIV. 

GIV. 

GIV. 

GIV. 

ELN. 

RDA. 

ELN, 

IFF. 

FB, 

IFF. 

GIV. 

FB,  GIV,  MON,  OPC,  UOP. 


FB,  GIV. 
GIV,  UOP. 


552-743  0-74-9 


SYNTHETIC  ORGANIC  CliE"ICALS.  197'' 


TABLE  2,— Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED.    IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC— Continued 
Bemenoid  and  Naphthalenoid — Continued' 

p-Isopropyl  benzaldehyde    (Cumaldehyde) 

p-Isopropylcyclohexanol 

p-Isopropyl-a-methylhydrocinnamaldehyde 
(Cyc lamena Idehyde ) 

Isovanillin    (3-Hydroxy-4-iiiethoxybenzaIdehyde) 

p-Mentha-l,8-diene    (Limonene] 

Men thy  1   anthranilate 

4 ' -Methoxyacetophenone    (Acetanisole) 

p-Methoxybenzyl   alcohol    [Anisyl  alcohol) 

o-Methoxycinnamaldehyde 

2-Methoxynaphthalene 

l-(p-Methoxyphenyl)-l-penten-3-one 

2-Methoxy-4-propenylphenol  (Isoeugenol) 

2-Methoxy-4-propenylphenol ,  acetate 

4 '-Methyl ace tophenone 

p-Methylanisole 

*Methyl  anthranilate 

Methyl  anthranilidene-p-isopropyl  methylhydro- 
cinnamaldehyde  (Orangeol  N) . 

Methyl  benzoate 

*a-Methylbenzyl  acetate  (Styralyl  acetate) 

a-Methylcinnamaldehyde 

Methyl  cinnamate 

6-Methylcoumarin 

Methylcyclohexyl  propionate 

1 ,2- CMethylenedioxy)-4-propenylbenzene  (Isosafrole) 

p-Methylhydratropaldehyde 

l-Methyl-4-isohexyl-hexahydrobenzaldehyde 
CVemaldehyde) . 

Methyl  N-methy Ian thrani late 

*Methyl  phenyl  acetate 

*Methyl  salicylate 

IH-Naphtho- [2 , 3-c] pyTan-3 , 4,6,7,8, 9-hexahydro-4 ,6,6,9,9- 
pentaraethyl  (Musk  89) . 

1,1 ,3,3,5-Pentamethyl-4,6-dinitroindan 

a-Pentylcinnaraa Idehyde 

*Phenethyl  acetate ^ 

Phenethyl  alcohol 

Phenethyl  formate 

Phenethyl  Isobutyrate 

Phenethyl  isovalerate 

*2-Phenethyl  phenylacetate 

Phenethyl  propionate 

Phenethyl  salicylate 

2-Phenoxyethyl    isobutyrate 

Phenylacet a Idehyde 

Phenylacetaldehyde,  dimethyl  acetal 

o-Phenylanisole  (2 -Methoxybi phenyl) 

4-Phenyl-3-buten-2-one  (Benzyl ideneacetone) 

Phenylethyl  acetal 

Phenyl ethyl  tig late 

*3-Phenyl-l-propanol  (Hydrocinnamic  alcohol) 

3-Phenylpropyl  acetate 

3-Phenylpropyl  cinnamate 

*Piperonal  (Heliotropin) 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


GIV. 

GIV. 

GIV,   RDA. 

SLV. 

SKG. 

PFW. 

GIV,   UOP. 

GIV,   UOP. 

CI. 

GIV. 

GIV. 

CI,   GIV. 

UOP. 

GIV,   UOP. 

GIV,   UOP. 

FB,   OPC,    PFW, 

SW,   UNG 

RDA. 

HN. 

CI,    ELN,    GIV, 

UNG. 

FB,    GIV. 

CI,    FB,   UOP. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV,   OPC. 

ELN,    GIV,   OPC 

DOW,    HN,    MON. 

IFF, 

GIV. 

CI,    FB,   GIV, 

HOP. 

GIV,    IFF,    NEO 

IFF,   NEO. 

ELN,    IFF. 

ELN,   GIV,    IFF 

GIV,   OPC. 

CI,   ELN,    GIV, 

IFF. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV,   UOP. 

GIV. 

FB,   UOP. 

GIV. 

FB. 

ELN,    FB,   GIV. 

UOP. 

GIV. 

AMB,  GIV,  UOP. 


FLAVOR  AND  PERFUME  MATERIALS 


TABLE  2. --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED,    IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to    list    in  table   3) 


FLAVOR  AND  PERFUME  MATERIALS,   CYCLIC  — Continued 
Benzenoid  and  Naphthalenoid — Continued 


Piperonal  bisulfite    (Heliotropin  bisulfite) 

*p-PropenyIanisole    (Anethole) 

p-PropylanisoIe    (Dihydroanethole) 

N-Propylphenylethyl   alcohol 

Sweeteners,    synthetic; 

Cyclohexanesulfamic   acid 

Cyclohexanesulfamic   acid,    calcium  salt 

Cyclohexanesulfamic   acid,    sodium  salt 

Saccharin    (1 ,2-Benzisothia2olin-3-one ,    1 , 1-dioxide)- 

Saccharin,    ammonium  salt 

Saccharin,    calcium  salt 

Saccharin,    sodium  salt 

*p-Tolualdehyde 

p-Tolylacet aldehyde 

p-Tolyl   acetate 

p-Tolyl  phenylacetate 

a-CTrichloromethyl)   benzyl  acetate    (Rosetone) 

Vanillin    (4-Hydroxy-3-methoxybenzaldehyde) 

Terpenoid,   Heteroayolia ,  and  Alicyclic 

Acetyl   cedrone   fVertofix) 

Cadinene 

6-Caryophyllene 

Caryophyllene  oxide 

a-Cedrene  epoxide  (Andrane) 

Cedrenol 

Cedrol 

*Cedryl  acetate 

Cedryl  formate 

Cycl open tan one 

Dihydronordicyclopentadienyl  acetate 

D ih ydronordi cycl open t ad ienyl  propionate 

Dihydroterpinyl  acetate 

3-Hydroxy-2-ethyl-4-pyrone  (Ethyl  maltol) 

16-Hydroxyhexadecanoic  acid,  o-lactone 

(Hexadecanolide) . 
4- (4-Hydroxy-4-methylpentyl)-3-cyclohexene-10- 

carboxaldehyde  (Lyral). 

3-Hydroxy-2-methyl-4-pyrone  (Maltol) 

4-Hydrox)Tionanoic  acid,  Y-l3<^tone  (y-Nonalactone) 

4-Hydroxyoctanoic  acid,  y-lactone  (y-Octalactone) 

4-Hydroxyundecanoic  acid,  y-lactone  (y-Undecalactone)- 
lonones : 
*ot-Ionone 

S-Ionone 

lonone  (a-and  6-)' 

Isoborneol 

Isobomyl    Acetate 

Isobomyl   propionate 

Isojasmone 

Isomenthone 

4-Isopropylcyclohexanol 

Jasmal 

p-Mentha-6,8-dien-2-ol  (£-Carveol) 

p-Mentha-6 ,8-dien-2-one  (Carvone;  CarVol) 


AMB. 

ARZ,  GLD, 
FB,  GIV. 
GIV. 

ABB. 


HON,  SW. 
SW. 

MON,  SW. 
HON,  SW. 
GIV,  HN, 
GIV. 

FB,  GIV. 
GIV. 
NEO. 
MON,  SLV. 


FB. 

CI,  ( 

GIV. 

IFF. 

GIV. 

ELN, 

ELN, 

IFF. 

ARA. 

GIV, 

i;iv, 

GIV. 
PFZ. 
IFF. 


HN,  HPC,  NCI,  UOP. 


GIV,  IFF,  NEO. 

GIV,  IFF,  NEO,  UNG,  UOP. 


IFF 
IFF 


IFF. 


PFZ- 

GIV, 

UOP 

GIV, 

RT, 

UOP. 

ELN, 

FB. 

GIV 

HOF 

IFF, 

MYW 

HOF 

MYW 

GIV 

MYW 

NEO, 

UNG 

RDA 

FB, 

OPC, 

RDA. 

GIV 

OPC 

FB. 

GIV 

UOP. 

IFF 

SYNTHETIC  ORGAMIC  CHEMICALS.  1972 


TABLE  2, --Flavor  and  perfume  materials  for  which  U.S.   production  or  sales  were 

REPORTED,     identified    BY    MANUFACTURER.    1972--CONTI NUED 


Manufacturers'    identification   codes 
(according   to    list    in   table    5) 


FLAVOR  AND  PERFUME  MATERIALS,    CYCLIC--Continued 

Terpenoid,   Heteroayalic,   and  Aliayalio — Continued 

p-Mentha-6,8-dien-2-ol ,    acetate    (K-carvyl    acetate) 

p-Mentha-l,3-diene    (oi-Terpinene) 

p-Mentha-l,4-diene    [y-Terpinene) 

*p-Menthan-3-one    (Menthone) 

p-Menth-l-en-3-one 

p-Menth-4C8)-en-5-one   (d-Pulegone) 

p-Menth-8-en-3-ol  (Isopulegol) 

1 , l-p-Menthen-6-yl-l-propanone 

Menthol,  synthetic: 

Tech 

•U.S.P  

Menthyl  acetate 

*Methylibnones: 

b-Methyl-ot-ionone 

Methylionone  (a-  and  B-) 

Y-Me thy lion one 

Nopyl   acetate 

3-Pentyl-tetrahydro-4-pyranol    CJessemal) 

Santalol 

Santalyl  acetate 

*Terpineols : 

a-Terpineol 

Terpineol  (a-  and  B-) 

Terpinol  hydrate  (Terpin  hydrate) ,  tech 

*a-Terpinyl  acetate 

Terpinyl  acetate  Cmixed  a-  and  B-) 

a-Terpinyl  propionate 

Tetrahy drops eudo  ion one 

l-(2 ,6,6-Trimethyl-2-cyclohexen-l -yl)-l ,6-heptadien- 
3-one  (Allyl-a-ionone) . 

3,3,5-Triniethyl    cyclohexanol    (Horaomenthol) 

Vetivenol 

*Vetivenyl  acetate 

FLAVOR  AND  PERFUME  MATERIALS,  ACYCLIC 

Acetylbutyryl  C2 ,3-Hexanedione) 

Acetylpropionyl 

Acetylvaleryl  (2,3-Heptanedione) 

Allyl  disulfide- 

Allyl  hep tan oat e 

*Allyl  hexanoate 

Allyl  isothiocyanate  (Synthetic  mustard  oil) 

Allyl  octanoate  (Allyl  caprylate) 

Allyl  sulfide 

Amyl  propionate 

Butyl  butyryl  lactate 

l-Chloro-2-iiiethyl-butene-2 

Citral  dimethyl  acetal 

*Citronellyl  acetate 

Citronellyl  butyrate 

Citronellyl  formate 

Citronellyl  isobutyrate 

Citronellyl  methyl  acetal 

Citronellyl  oxyacet aldehyde 

Citronellyl  propionate 


GLD. 

GLD. 

CIV 

HN, 

NEO. 

GIV 

GIV 

GIV 

GIV. 

GIV, 

HN. 

GIV, 

GLD 

HN, 

NEO. 

GIV. 

GIV, 

MYW 

GIV, 

IFF 

MYW 

NEO,  UNG 

GIV. 

CI, 

FEL, 

NEO, 

RDA. 

IFF. 

GIV. 

GIV. 

GLD, 

HPC 

NCI 

GIV. 

NEO 

HPC. 

GIV, 

NEC 

PFW 

UNG. 

RDA. 

ELN, 

GIV 

ARS. 

GIV,  UOP. 

ELN,  FB,  GIV,  IFF,  NEO,  UOP. 


ELN, 

FB, 

RT. 

RT. 

GIV. 

ARS. 

RDA. 

GIV, 

IFF 

ELN, 

GIV 

GIV. 

ELN, 

GIV 

ELN, 

GIV 

IFF. 

IFF. 

IFF. 

FLAVOR  AND  PERFUME  NATERIALS 


TABLE  2. --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED^     identified   BY   MANUFACTURER,    1972— CONTI NUED 


Manufacturers'    identification   codes 
(according  to   list  in  table   3) 


FLAVOR  AND   PERFUME  MATERIALS,    ACYCLIC— Continued 

Decanal    (Capr aldehyde) 

Decen-9-ol-l    (Rosalva) 

Decyl  acetate- 

Diethyl  acetal 

Diethyl  sebacate 

Diethyl  succinate 

Dihydromyrcenol 

Dihydromyrcenyl  formate  (Dimyrcetol) 

Dihydro  safrol 

2,6-Dimethyl-5-hepten-l-al 

3,6-Dimethyl-5-hepten-2-ol   and   7-Methyl-6-octen-3-ol 
(Brazinol) . 

3,7-Diinethyl-l  ,6-nonadien-3-ol    (Ethyl    linalool) 

3,7-Dimethyl-l,6-nonadien-3-ol,    acetate 

3,7-Dimethyl-2,6-nonadienenitrile 

3,7-Diniethyl-2,6-octadienal    (Citral) 

*3,7-Dimethyl-cis-2,6-octadien-l-ol    (Nerol) 

*3,7-Diraethyl-trans-2,6-octadienal    (Citral    a;    Geranial)- 
3,7-Dimethyl-trans-2,6-octadienal    dimethyl   acetal 

*3,7-Dimethyl-trans-2, 6-octadien-l-ol    (Geraniol) 

3,7-Diraethyl-trans-2,6-octadien-l-ol   HP 

(Geraniol   HP). 
3, 7-Dimethyl-l ,6-octadien-3-ol    (Linalool;    Linalyl 

alcohol) . 
3,7-Diiiiethyl-l  ,6-octadien-3-ol    acetate    (Linalyl 

acetate) . 
3, 7-Dimethyl-l, 6-octadien-3-yl    isobutyrate    (Linalyl 

isobutyrate) . 
3, 7-Dimethyl-l ,6-octadien-3-yl   propionate    (Linalyl 
propionate) . 

3,7-Dimethyloctan-l-al 

3,7-Dimethyloctan-3-ol 

3,7-Dimethyl-l,7-octanediol 

3,7-Dimethyl-l-octanol    (Dihydrocitronellol) 

3,7-Dimethyl-6-octen-l-al    (Citronellal) 

*3,7-Dimethyl-6-octen-l-ol    (Citronellol) 

3,7-Diraethyl-6-octen-l-ol,  cis,    trans  mixture 

2,6-Dimethyl-2-octene-7-yne-6-ol 

3,7-Dimethyl-7-octenol  and  6-octenol  isomer 

*Ethyl  Butyrate 

Ethyl  cap rate 

Ethyl  formate 

*Ethyl  heptanoate 

*Ethyl  hexanoate  (Ethyl  caproate) 

2-Ethyl-l-hexanol 

Ethyl  isohexanoate 

Ethyl  isovalerate 

Ethyl  laurate 

Ethyl  myristate 

Ethyl   nonanoate 

Ethyl  octanoate 

Ethyl  propionate 

Ethyl  valerate 

Geranic  acid 

Geranonitrile 

*Geranyl  acetate 

*Geranyl  butyrate 

Geranyl  dimethyl aery late 

*Geran;^l  "formate 

Geranyl  isobutyrate 


CI,  GIV.  IFF. 

IFF. 

GIV. 


ELN, 

UCC. 

IFF. 

IFF. 

CI. 

GIV. 

RDA. 

HOF. 
HOF. 
GIV. 
HOF. 
ELN, 


FB,  GIV,  GLD,  IFF. 
FEL,  GIV,  UOP. 


CI, 
GIV, 


ELN,  FB,  FEL,  GIV,  GLD,  IFF,  NCI,  NED,  UOP. 


ELN, 
ELN, 


HOF. 

HOF. 

GIV. 

GIV. 

FB, 

CI, 

CI. 

RDA. 

GIV. 


FB,  FEL,  GIV,  GLD,  HOF,  UNG. 
FB,  GIV,  GLD,  HOF,  NEO,  UNG. 


GIV,  IFF,  NEO,  UOP. 

ELN,  FB,  GIV,  IFF,  NEO,  SCM. 


ELN 

FEL 

RT 

UOP 

ELN 

FB, 

NW, 

PFW, 

GIV 

PFW 

FB, 

PFW. 

ELN 

RT. 

FEL 

GIV 

FB, 

RT. 

CI, 

ELN, 

FEL, 

GIV 

CI, 

ELN, 

GIV. 

FMT. 

CI, 

ELN, 

GIV. 

IFF 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 


TABLE  2.— Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED,     identified    BY    MANUFACTURER,    1972--CONTINUED 


FLAVOR  AND  PERFUME  MATERIALS,   ACYCLIC--Continued 

Geranyl   isovalerate 

Geranyl  neryl  formate 

Geranyl  propionate 

Geranyl  tig late 

♦Glutamic   acid,   monosodium  salt    (Monosodium  glutamate)- 

Y-Heptalactone 

Heptanal    (Enanthaldehyde) ' 

Heptyl   alcohol    (1-Heptanol) 

Hexanoic  acid   (Caproic  acid) 

2-Hexanol 

2-Hexenal 

cis-3-Hexen-l-ol 

cis-3-Hexen-l-yl   acetate 

cis-3-Hexen-l-ol   lactate 

3-Hydroxy-2-butanone    (Acetoin) 

*7-Hydroxy-3,7-dimethyl-l-octanal    (Hydroxycitronellal)  • 
7-Hydroxy-3,7-diiiiethyl   octanal,    dimethyl    acetal 
(Hydroxycitronellal,    dimethyl    acetal). 

Isoamyl  propionate 

Isoamyl  undecylenate 

Isobutyl   acetate 

Isodihydro   lavandulol 

Isodihydro  lavandulylaldehyde 

Isodihydro   lavandulyl   acetate 

*Isopentyl  butyrate 

*Isopentyl   formate 

*lsopentyl   isovalerate 

Lauraldehyde 

3-Methyl-5-heptanone  oxime 

2-Methyl-2-hepten-6-one  methyl  hexenyl   ketone  and 
6-methyl-5-hepten-2-one. 

Methyl   isobutyrate 

3-Methyl-2-(and  3)   nonenitrile 

Methyl-2-nonenoate 

Methylol  methyl  hexyl  ketone 

2-Methylundecanal 

Mugual   and  tetrahydro  rauguol 

Myrcenyl  acetate 

Myrist aldehyde 

Neryl   acetate 

Nan anal 

Nonane  diacetate 

Nonane-1 ,3-diol  monoacetate 

Nonanol 

Nonyl   acetate 

Ocimenol 

Ocimenyl  acetate 

Octanal 

Octanal,  tech 

3-Octanone  (Ethyl  amyl  ketone) 

Octyl  acetate 

n-Octyl  acetate 

n-Octyl  alcohol 

Pentyl  acetate 

Propionic  acid  ethyl  ester 

Pseudo  linalyl  acetate 

Pyrolysate  ester 

*Rhodinol 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


FB, 

IFF. 

FB. 

COM 

GRW, 

UDW 

FB. 

ntl. 

ntl 

UCC. 

GIV, 

GIV. 

RT. 

FMT. 

GIV, 

GIV, 


gld,  iff,  NEO,  UOP. 
UOP. 


GIV,  NW,  PFW,  UOP. 
,  GIV,  RT. 
,  FB,  PFW. 

GIV. 


GIV. 
RDA. 

PFW. 

GIV. 

GIV. 

GIV. 

GIV. 

IFF. 

IFF. 

GIV. 

GIV. 

GIV. 

CI. 

GIV. 

GIV. 

GIV. 

IFF. 

IFF. 

GIV,  IFF. 

IFF. 

GIV. 

FB. 

GIV. 

GIV. 

UOP. 

UOP. 

IFF. 

GIV. 

FB,  FEL,  GIV,  IFF,  NEO. 


FLAVOR  AND  PERFUME  MATERIALS 


TABLE  2, --Flavor  and  perfume  materials  for  which  U.S.  production  or  sales  were 

REPORTED,     identified    BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
(according  to   list  in  table  3) 


FLAVOR  AND   PERFUME  MATERIALS,    ACYCLIC--Continued 

Rhodinyl   acetate 

Sodi'um  allyl   sulfonate 

Tepyl  acetate 

3,7,8,8-Tetrainethyl-l  ,6-nonadiene-3-ol    (Isobutyl 
linalool) . 

3,7,ll-Trimethyl-l,6,10-dodecatriene-3-ol 

2,6,  lO-Trimethyl-9-undecen-l-al 

3,6,10-Triraethyl-9-undecen-2-one  and  isomers 

Un decanal 

9-Undecenal 

Y-VaJerolactone 

ESSENTIAL  OILS,    CHEMICALLY  MODIFIED 

.^jnyris  acetate 

Clove  leaf  oil  terpenes 

* Ethyl  oxyhydrate 

*Guaiacwood  acetate 

Guaiene 

Lavandin,  acetylated 

Rose  oxide 

Sassafrass  oil,  hydrogenated 


GIV. 
UOP. 
UOP. 
HOF. 

HOF. 
GIV. 
GIV. 
GIV, 
GIV. 
GIV. 


GIV. 

CI,  UOP. 

FEL,  FLO,  PFW,  RT,  VND. 

ELN,  FB,  GIV,  NEO. 

FB. 

FEL,  UNG. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


TABLE  3. --Flavor  and  perfume  materials:     Directory  of  manufacturers.  1972 

ALPHABETICAL   DIRECTORY    BY    CODE 

[Names  of  manufacturers   that  reported  production  or  sales  of  flavor  and  perfume  materials  to  the  U.S.   Tariff 
Commission   for   1972   are    listed  below   in   the  order  of  their  identification   codes    as   used   in  table   2] 


Code 

Name  of  Company 

Code 

Name   of  Company 

ABB 

Abbott    Laboratories 

MRT 

Morton   Chemical  Co.,    Div  of 

AMB 

American  Bio-Synthetics  Corp. 

Morton-Norwich   Products,    Inc. 

ARA 

Arapahoe  Chemicals   Div.    of  Synte.x  Corp. 

MYW 

Stepan   Chemical    Co. 

ARS 

Arsynco,    Inc. 

ARZ 

Arizona  Chemical   Co. 

NCI 

Union   Camp  Corp. ,   Chemical   Division 

NEC 

Norda  Essential   Oil    6  Chemical    Co. , 

Inc. 

BPC 

Stauffer  Chemical  Co.,   Specialty  Chemical 

NIL 

NL   Industries,    Inc. 

Division,    Benzol   Products 

NK 

Northwestern  Chemical   Co. 

CI 

Chem-Fleur,    Inc. 

OPC 

Orbis   Products  Corp. 

COM 

Commercial  Solvents  Corp. 

PD 

Parke,    Davis    £  Co. 

DOW 

Dow  Chemical   Co. 

PEN 

CPC    International,    Inc.,    Penick   Division 

PFW 

Polak's   Frutal   Works,    Inc. 

ELN 

Elan   Cheracial    Co. 

PFZ 

Pfizer,    Inc. 

FB 

Fritzsche,    Dodge   6  Olcott,    Inc. 

RDA 

Rhodia,    Inc. 

FEL 

Felton   International,    Inc. 

RT 

F.    Ritter  5   Co. 

FLO 

Florasynth,    Inc. 

FMT 

Fairmount  Chemical   Co. ,    Inc. 

SKG 
SLV 

Sunkist   Growers,    Inc. 
Sterwin  Chemicals,    Inc. 

GAF 

GAF  Corp.,   Chemical   Division 

SW 

Sherwin-Williams   Co. 

GIV 

Givaudan  Corp. 

GLD 

SCM  Corp.,    Glidden-Durkee   Division 

TCC 

Tanatex  Chemical   Corp. 

GRW 

Great  Western  Sugar  Co. 

UCC 

Union  Carbide  Corp. 

HN 

Tenneco  Chemicals,    Inc. 

now 

William  Underwood  Co. 

HOF 

Hoffman- LaRoche,    Inc. 

UNG 

Ungerer  5  Co. 

HPC 

Hercules,    Inc. 

■JOP 

Universal   Oil    Products   Co.,    UOP 
Chemical    Division 

IFF 

International    Flavor  &   Fragrances,    Inc. 

MNR 

Monroe  Chemical  Co. 

VEL 

Velsicol   Chemical    Corp. 

MON 

Monsanto  Co. 

VNP 

Van   Dyk   6   Co. ,    Inc. 

-Complete  names   and   addresses   of  the   above  reporting   companies   are    listed    in  Table   1    of  the   Appendix. 


133 


PLASTICS  AND  RESIN  MATERIALS 


Plastics  and  resin  materials  are  high  molecular  weight  polymers 
which,  at  some  stage  in  their  manufacture,  exist  in  such  physical  con- 
dition that  they  can  be  shaped  or  otherwise  processed  by  the  application 
of  heat  and  pressure.   Depending  on  the  chemical  composition,  manufacturing 
process  or  intended  use,  the  commercial  products  may  contain  plasticizers, 
fillers,  extenders,  stabilizers,  coloring  agents  or  other  additives. 
Plastics  materials  may  be  molded,  cast  or  extruded  into  semifinished  or 
finished  solid  forms.   Resin  materials  may  be  in  the  form  of  solutions, 
pastes  or  emulsions  for  applications  such  as  protective  coatings,  adhesives, 
or  paper  and  textile  treatment. 

Statistics  on  U.S.  production  and  sales  of  synthetic  plastics  and 
resin  materials  for  1972  are  given  in  table  1.^  U.S.  production  of  plastics 
and  resin  materials  in  1972  totaled  25,921  million  pounds,  or  23.0  percent 
more  than  the  21,070  million  pounds  produced  in  1971.   Sales  in  1972  totaled 
22,946  million  pounds,  valued  at  $4,258  million  compared  with  18,473  million 
pounds,  valued  at  $3,507. 

Thermosetting  materials  are  those  which  harden  with  a  change  in 
composition  in  the  final  treatment  so  that  they  cannot  again  be  softened 
by  heat  or  solvents.   U.S.  production  of  thermosetting  materials  totaled 
4,484  million  pounds  in  1972  compared  with  3,615  million  pounds  in  1971. 
Production  of  the  most  important  products  in  1972  included  phenolic  resins 
(1,441  million  pounds),  amino  (or  urea  and  melamine)  resins  (929  million 
pounds),  polyester  resins  (930  million  pounds),  and  alkyd  resins  (636 
million  pounds) . 

Thermoplastic  materials  are  those  which  can  be  repeatedly  softened  by 
heat  and  shaped.   U.S.  production  of  thermoplastic  materials  totaled  21,437 
million  pounds  in  1972  compared  with  17,455  million  pounds  in  1971.   Produc- 
tion of  the  most  important  products  in  1972  included  polyethylene  (7,656 
million  pounds),  vinyl  resins  (5,122  million  pounds),  and  styrene  type 
materials  (4,890  million  pounds). 


^  See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers of  each  by  codes.   These  codes  are  given  in  table  3. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  1, --Plastics  and  resin  materials;     U.S.  production  and  sales,  1972 


[Quantities  and  values  are  given  in  terms  of  the  total  weight  of  the  materials  (dry  basis).   Listed  below  are  all 
plastics  and  resin  materials  for  which  any  reported  data  on  production  or  sales  may  be  published.  (Leaders  (.. .)  are 
used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  2  lists  all  plastics  and  resin  materials  for  which  data  on  production  or  sales  were  reported  and  identifies 
the  manufacturers  of  each] 


Production 


Grand  total 

Plastics  and  resin  materials,  benzenoid  

Plastics  and  resin  materials,  nonbenzenoid 

THERMOSETTING  RESINS 
Total 

Alkyd  resins,  total 

Phthalic  anhydride  type 

Polybasic  acid  type 

Polyester  resins,  unsaturated  

Styrene  alkyd  polyesters 

Amino  resins,  total 

Mel amine- formaldehyde  resins 

Urea- formaldehyde  res  ins 

Dicyandiamide  resins  

Epoxy  resins:^ 

Unmodified  

Modified  and  "advanced" 

Furfuryl  type  resins 

Phenolic  and  other  tar  acid  resins 

^Polyurethane  and  diisocyanate  resins  (excluding  foam  and 

elastomers) 

Polyether  and  polyester  polyols  for  urethanes 

Silicone  resins 

Other  thermosetting  resins' 

thermoplastic  resins 

Total 

Acrylic  resins'  

Cellulosic  plastics  and  resins'" 

Coumarone-indene  resins 

Petroleum  hydrocarbon  resins 

Polyamide  resins,  nylon  type'" 

Polyamide  resins,   non-nylon  type 

Polyester  resins,   saturated 

Polyethylene  and  copolymers,   total 

Density  0.940   and  below" 

Density  over  0.940 

Polypropylene  resins 

Polytetrafluoroethylene  (PTFE)  

Rosin  modifications,   total 

Rosin  and  rosin  esters,   unmodified   (ester  gums) 

Other " 


1,000 

pounds 

diry  basis  ^ 

25,920,662 


8,946,997 
16,973,665 


4,483,501 


597,181 
38,735 


930,384 
12,493 


199,473 
729,294 


179,000 
'    (43,159) 

4,449 
1,440,513 

99,427 

149,191 

13,424 

87,835 


21,437,161 


758,589 
256,811 

49,024 
245,359 
122,987 

27,328 
114,969 


5,360,310 
2,295,939 


,730,857 
13,248 


35,981 
92,363 


1,000 

pounds 

dry  basis^ 

22,946,075 


1,000 
dollars 


7,807,933 
15,138,142 


300,281 
22,969 


45,767 
5,109 


759,934 


152,831 
607,103 


'    179,000 
9    (26,554) 

2,683 
1,226,665 

48,546 
107,773 
10,856 
79,946 


19.354.466 


626,856 
251,538 

233,241 
119,009 
25,716 
43,496 

6,932,020 


,877,879 
,054,141 


1,684,507 
9,635 


121,399 


29,170 
92,229 


1,715,579 
2,542,861 


83,685 
6,154 


158,962 
1,786 


51,924 
101,627 


'  81,000 
'(21,466) 

719 
260,024 

22,331 
23,647 
20,314 
19,599 


3.425.327 


283,377 
132,071 

29,342 
97,043 
15,353 
26,373 

834,641 


594,050 
240,591 


265,539 
31,804 


7,684 
19,902 


See  footnotes  at  end  of  table. 


PLASTICS  AND  RESIN  MATERIALS 
TABLE  1. —Plastics  and  resin  materials;     U.S.  production  and  sales^  1972~Continued 


Production 


Quantity 


Unit 
value^ 


1,000 

pounds 

dry  hasis^ 


THERMOPLASTIC  RESINS--Continued 


Styrene  plastics  materials,   total 

Acrylonitrile-butadiene-styrene   (ABS) 

Styrene-acrylonitrile  resins    CSAN) 

Styrene  and  styrene  copolymer  resins-- 


Vinyl  resins,  total'^ 

Polyvinyl  chloride  and  copolymers- 
Polyvinyl  acetate '  ^ 

Polyvinyl  alcohol 

Lther  vinyl  and  vinylidene  resins' 


),161 


863,725 
'  106,000 
3,920,436 


1,000 

pounds 

dry  basis^ 


4,557,156 


1,000 
dollcws 


809,934 

100,838 

3,646,384 

4,434,989 


Per 

pound 


$0.18 


235,195 
22,888 
575,245 

657,610 


.29 
.23 
.16 


All  other  thermoplastic  resins 


,322,000 

527,839 

78,564 

193,835 

320,997 


3,865,000 

404,481 

64,918 

100,590 

314,904 


503,048 
94,331 
20,407 
39,824 

191,260 


.31 
.40 


Starting  with   1972,   data  is   reported  only  by  type  of  resin  and  is  no  longer  broken  down  by  end  use. 
^  Calculated  from  rounded  figures. 
'  Dry  weight  basis   unless  otherwise  specified.      Dry  weight  basis   is   the  total  weight  of  the  materials   including  resin 
and  coloring  agents,   extenders,   fillers,   plasticizers ,   and  other  additives,  but  excluding  water  and  other  liquids   di- 
luents  unless    they   are   an   integral  part  of  the   materials. 

''  Includes  benzenoid  plastics  and  resin  materials  as  defined  in  part  I  of  schedule  4  of  the  Tariff  Schedules  of  the 
United  States. 

^  Polyester  resins  are  unsaturated  alkyd  resins,   later  to  be   copolymerized  with   a  monomer   (such   as  styrene  or  methyl 
methacrylate) ;    and  polyallyl  resins    (such  as   diallyl  phthalate  and  diglycol   carbonate).      Data  are  on  an  "as   sold"  basis, 
including  monomer  if  part  of  the  resin  system. 

^   Includes   reactive  diluents  which   are  an   integral  part  of  the  resin.      Excludes  the  weight  of  hardeners   sold  in 
association  with  the  resin  as  part  of  a  two-component  system. 
'    Partially  estimated. 

°  Data  shown  for  modified  and  "advanced"  epoxy  resins  are  that  part  of  the  unmodified  epoxy  resins  which  is  further 
processed;    therefore,   the  totals   in  parentheses  are  not  included   in  the  grand  total. 

'    Includes  polycarbamate  resins,   toluenesulfonamide  resins,   acetone- formaldehyde  resins,   and  other  thermosetting  resins 
and  their  precursors. 
'°   Does  not   include  production  or  sales   for  fiber  use. 

"    Includes   data  for  ethylene   copolymers.      Sales   do  not   include  sales  by  primary  producers   to  other  primary  producers; 
sales   do  include  resales  of  purchased  material  by  primary  producers. 

'^   Data  are  on  the  basis  of  dry  resin   content,   excluding  the  weight  of  plasticizers,   extenders,   fillers,    coloring  agents, 
stabilizers   or  impact  modifiers,    unless   otherwise  noted. 

"   Data  for  polyvinyl   acetate  produced  and  sold  in  latex  form  include  the  weight  of  any  protective  colloids  which  are 
used  as  emulsion  stabilizers   and  form  an   integral  part   of  the  resin  system.      Production  does  not  include  polyvinyl   acetate 
used  as   a  reactive   intermediate   for  polyvinyl   alcohol    or  other  vinyl    resins. 
'*■    Includes  polyvinylidene   chloride,   polyvinyl  butyral ,  polyvinyl    formal,    and  other  vinyl   resins. 

'^   Includes   acetal  resins,    fluorocarbon  resins   except  PTFE,   a-methylstyrene  resins,  polybutylene  type  resins,   poly- 
carbonate resins,   polyimide-type  resins,   polyphenylene  oxide  type  resins,   polyterpene  resins,   other  thermoplastics, 
and  sales  of  coumarone-indene  resins. 

Note. --Data  reported  to  the  Tariff  Commission  does  not  necessarily  coincide  with  that  reported  to  the  Society  of  the 
Plastics  Industry  due  to  differences  in  both  the  reporting  instructions  (e.g.,  polyvinyl  alcohol)  and  in  the  coverage 
(e.g.   phenolic  resins). 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2,— Plastics  and  resin  materials  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972 

[Plastics    and   resin  materials    for  which   separate  statistics    are   given   in   table   1    are  marked  below  with   an 
asterisk    (*);    chemicals  not  so  marked  do  not  appear  in  table   1  because  the  reported  data  are  accepted  in   con- 
fidence and  may  not  be  published.     Manufacturers'    identification  codes  shown  below  are  taken  from  table  3.      A 
X  signifies   that  the  manufacturer  did  not   consent  to  his  identification  with  the  designated  product] 


THERMOSETTING  RESINS 

Acetone-formaldehyde  resins 

*Alkyd  resins,    domestic: 

*Phthalic  anhydride  type 

*Polybasic   acid  type 

•Polyester  resins,   unsaturated 

*Styrene-alkyd  polyesters 

*Amino  resins: 
*Melamine- formaldehyde  resins 

*U re a- formaldehyde  resins 

*Dicyandi amide  resins 

Epoxy  resins: 
'Unmodified 

•Modified  and  "advanced" 

* Fur fury 1- type  resins 

•Phenolic  and  other  tar  acid  resins 


Po ly carb amate  resins 

•Polyurethane   and  diisocyanate  resins 

•Polyether  and  polyester  polyols    for  urethi 

*Si 1 i cone  resins 

All  other  thermosetting  resins 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


ACY,  AMR. 

.\CY,  APT,  ASH,  AZS.  BAL,  BEN,  BRU,  GEL,  CGL,  CM,  COM,  DAV, 
DEG,  DSO,  DUP,  EW,  FAR,  FCD,  FLW,  FOC,  FSH,  GIL,  GLD, 
GRV,  HAN,  IGF,  IPC,  JOB,  JSC,  JWL,  KHC,  KMP,  KPT,  MCC, 
MID,  MNP,  NCI,  NPV,  OBC,  PER,  PPG,  PRT,  PRX,  RCI,  RED, 
REL,  RH,  SCN,  SED,  SIP,  SKT,  SM,  SW,  x. 

ACY,  ASH,  BEN,  COM,  DEG,  EW,  FCD,  FOC,  GRV,  HAN,  ICF, 
IPC,  KMC,  KMP,  MCC,  MID,  MOB,  NPV,  PFP,  PPG,  RCI, 
RED,  REL,  RH,  SCN,  SKT,  SM,  SW,  WIG. 

ACP,  ACR,  ACY,  APT,  ASH,  AZS,  CGL,  CPV,  DA,  DEG,  DSO, 
ENJ,  EPC,  EW,  FLW,  FMP,  FOM,  FRE,  GEI,  GLD,  GNT, 
GRG,  HAN,  HKD,  ICF,  ICI ,  IPC,  KMC,  KPT,  MFC,  MID, 
MMM,  MRB,  MRO,  OCF,  ORO,  PFP,  POL,  PPG,  PPL,  RCI, 
REL,  RH,  SCN,  SHA,  SHC,  SIC,  SM,  SW,  TXT,  WLN. 

APT,  ASH,  CGL,  DSO,  EW,  FLW,  GLD,  GRV,  HAN,  MID,  PPG, 
REL,  SM. 

ACP,  ACY,  AMR,  BOR,  CBD,  GEL,  CGL,  DAN,  DSO,  DUP,  ENJ, 
FOM,  GLD,  GRV,  HAN,  JSC,  KPT,  MON,  MRA,  PMC,  PPG, 
PPL,  QCP,  RCI,  REL,  RH,  SBC,  SED,  SNW,  STC,  SW,  VAL, 
WRD. 

ACP,  ACY,  AMR,  APX,  ASH,  BOR,  CBD,  CEL,  CGL,  CMP,  CPV, 
DAN,  DUP,  EFH,  GAF,  GLD,  GP,  GRV,  HAN,  HNC,  HPC, 
HRT,  IRI,  JSC,  KPT,  MMM,  MON,  MRA,  NTC,  PC,  PGU, 
PPG,  PPL,  RCI,  REL,  RH,  RPC,  SAC,  SED,  SM,  SNW,  SOR, 
SW,  TXT,  UNO,  UPL,  USO,  VAL,  WCL. 

CGY,  ECC,  JSC,  MID,  MRA,  RPC,  S,  SBC,  VAL,  WIC. 

CEL,  CGY,  DOW,  RCI,  RSY,  SHC,  UCC. 

ACP,  ASH,  BEN,  DSO,  EW,  FAR,  GLD,  GRV,  HAN,  HYC,  ICF, 
JOB,  MCC,  MID,  MMM,  MRB,  MRT,  NPV,  OCF,  POL,  PPG, 
PRX,  RCI,  REL,  REZ,  RSY,  SCN,  SED,  SKT,  SM. 

ACR,  HVG,  SM,  TXT,  UNO,  WRD. 

ABS,  ACP,  ACR,  AMR,  ASH,  BME,  BOR,  CBD,  CBM,  CD,  CGL, 
CLK,  DSO,  ENJ,  EW,  FOM,  GE,  GEI,  GLD,  GP,  GRG,  HER, 
HKD,  HVG,  ICF,  INL,-IRI,  KPT,  KYN.  MCA,  MID,  MMM,  MON, 
MRB,  NCI,  NTC,  OCF,  PAI ,  PGU,  PLS,  PPL,  PRX,  PYZ, 
RAB,  RCD,  RCI,  REL,  RGC ,  RH,  RPC,  SCN,  SHA,  SIM, 
SKT,  SM,  SPL,  SW,  UCC,  UNO,  UPL,  USR,  VSV,  WCA,  WRD. 

ASH,  DAN,  PPG. 

APT,  ARK,  ASH,  BAL,  CEL,  CGL,  DSO,  DUP,  EW,  FAR,  FRE, 
GLD,  GPM,  HAP,  ICI,  JOB,  JWL,  KMC,  MCC,  MID,  MOB, 
mi,   NPV,  PEL,  PPG,  PVI,  QUN,  RCI,  REZ,  RUB,  SCN,  SKT, 
SW,  UPJ,  WLN. 

APT,  DSO,  ICI,  HID,  MOB,  PFZ,  PPG,  RCI,  UCC,  UNO,  UPJ,  WLN, 
WTC. 

ASH,  CGL,  DCC,  GLD,  MCC,  MID,  PPG,  SFS,  SPD,  UCC. 

ACP,  AMR,  ASH,  CGY,  DSO,  ENJ,  EW,  FLW,  GLD,  HYC,  IOC, 
MID,  MON,  PPG,  RCD,  S,  SM,  UCC,  USR,  VAL. 


PLASTICS  AND  RESIN  MATERIALS 
TABLE  2, --Plastics  and  resin  materials  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list    in  table   3) 


THERMOPLASTIC  RESINS 

Acetal   resins 

* Acrylic  resins 

*Cellulosic  plastics   and   resins 

*Couinarone-indene  resins 

Fluoro carbon  resins 

'Petroleum  hydrocarbon   resins 

Polyamide  resins: 
*Nylon  type 

*Non-nylon   t^'pe 

Polybutene  and  polyisobutylene  resins 

Polycarbonate  resins 

*Polyester  resins,   saturated 

'Polyethylene  and  copolymers: 

'Density  0.940  and  below 

'Density  over  0.940 

'Ethylene   copolymers 

'Polypropylene  resins 

Polyterpene   resins 

'Polytetrafluoroethylene  (PTFE) 

'Rosin  modifications: 

'Rosin   and  rosin  esters,   unmodified    Caster  gums)- 
'All   other 

'Styrene   type  plastics   materials: 

•Acrylonitrile-butadiene-styrene    (ABS)    resins  — - 
'Styrene-acrylonitrile   resins    (SAN) 

'Styrene   and  styrene   copolymer  resins   other  than 
ABS  and  SAN. 


a- Methyl styrene  polymers 

Vinyl   resins: 

'Polyvinyl    chloride   and  copolymer  resins- 

'Polyvinyl    acetate   resins 

•Polyvinyl   alcohol   resins 

Polyvinyl  butyral   resins 

Polyvinylidene   chloride  resins 

All   other  vinyl    resins 

All  other  thermoplastic  resins 


CEL,   DUP,    POL. 

ACY,   ASH,    BAS,   CEL,   DSO,   DUP,    EFH,   FLH,   GLC,    GNM,    GRV, 
HNC,   HRT,    IOC,   JNS,    JSC,   MID,   NPV,    POL,    PPG,    PVI , 
QUN,    REL,   RH,    RPC,    SAR,    SCO,    SED,    SEY,    SM,   UBS,   UCC, 
VAL,   VPC,    WIC,    X. 

CEL,    DOW,    DUP,    EKT,    ICF,    POL,    x. 

DUP,    ICF,   NEV,    PAI,   VEL. 

DUP,   MMM,    PAS. 

DSO,    EKX,    GYR,   NEV,    PAI,    PPG,    RCI,   VEL,    ZGL. 

ALF,    AZS,    BCM,    CEL,    DUP,    EW,    FG,    GNM,   MON,    POL,    RSN, 

SKP. 
CBY,    COO,    DUP,    EMR,    GNM,    SCO,    SM,    SNW. 

ENJ,  RH. 
GE,   MOB,    POL. 

CEL,   COO,    DSO,    DUP,    EKT,    GE,    GLD,    GNM,   MID,   MRT,    REL, 
RUB,    SHA. 

ACP,    CBN,    CPX,   DOW,    DUP,   EKX,    ENJ,    GOC,    KPP,   MON,    NWP, 

PLC,    RCC,   UCC,   USI. 
ACC,   ACP,    CEL,    CPX,    DOW,    DUP,    EKX,    GOC,    KPP,   MON,    PLC, 

UCC,   USI,   X. 
DUP,    EKX,    ENJ,   USI. 

ACC,    DA,    EKX,    ENJ,    HPC,    NVT,    PLC,    RCC,    SHC. 
CBY,    PAI,    SCN. 
ACP,   DUP,    ICI.    PAS. 

ASH,   CBY,   DPP,    FAR,    FCD,    FRP ,   GIL,   MCC,   NCI,    RCI,    SED. 
ASH,   CBY,    DPP,    EW,   FAR,    FCD,    FLK,    FRP,    GIL,    GLD,   NCI, 
RCI,    RH,    SCF,    SW,    ZGL. 

BFG,    DOW,    GRD,    KPP,   MCB,  MON,    RCC,   USR. 

BFG,    DOW,    DSO,   MON,    SBI,    SKT,    UCC. 

ACC,   AEP,   ATR,    BAS,    BFG,    BOR,    CSD,    DOW,    DPI,    DUP,    FCD, 
FG,    FIR,   GAF,    GNT,   GOR,    GRD,    GYR,    HLM,    ICF,    IOC, 
JNS,   JSC,    KPP,   MMM,   MON,   MRT,   ONX,    PAI,    PLA,    POL, 
PRX,    PVI,    RCC,    RH,    RPC,    SBI,   SHC,    SKT,    SOL,    SPE, 
UBS,    UCC,   UOC,   USR,   USS,    VEL,    WIC. 

ACC,   DOW,    FCD. 

ACP,   AIP,   AME,    BFG,    BOR,    CO,   DA,   FIR,   GNT,    GRA,    GYR, 
HN,    ICF,    KYS,   MON,   NSC,   OMC,    PNT,    RUB,   SFP,   TNA, 
UCC,   USR. 

AIP,   ASH,    BAL,    BEN,    BLS,    BOR,   CEL,    DAN,    DAV,    DSO,    DUP, 
FAR,    FLH,    FLW,    FSH,    GLC,    GLD,    GRD,   HNC,    HRT,   JSC, 
KMC,    KMP,   MCC,   M»1,    MNP,   MON,   NPV,    NSC,   OBC,   OCF, 
ONX,    PII,    PPG,    PRX,    PVI,    QCP,    RCI,    RPC,    SBI,    SCO, 
SEY,    SPC,   UBS,   UCC,    UOC,    WIC,    x. 

AIP,   DUP,   MON. 

DUP,   MON,   UCC. 

BAS,    BFG,    DOW,    DUP,   GLD,    GRD,   MRT,    SM,   UBS. 

DOW,    DSO,    EW,   MCC,   MON,    SM,    UCC. 

ACC,    CEL,    DSO,    DUP,    EW,    GE,    PLC,    PPG,    RH,    RPC,    SM, 
UCC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  3, --Plastics  and  resin  materials:     Directory  of  manufacturers,  1972 

ALPHABETICAL  DIKECI'ORV  BY  LODt 

[Names  of  manufacturers  that  reported  production  or  sales  of  plastics  and  resin  materials  to  the  U.S.  Tariff  Commis- 
sion for  ly72  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ABS 

Abex  Corp.,  American  Brakeblok  Division 

ECC 

Eastern  Color  5  Chemical  Co. 

ACC 

Amoco  Chemical  Corp. 

tFH 

E.F.  Houghton  i,  Co. 

ACP 

Allied  Chemical  Corp.,  Plastics  Division 

Eastman  Kodak  Co. : 

ACR 

CPC  International,  Inc.,  Acme  Resin  Co.  Div. 

EKT 

Tennessee  Eastman  Co.  Division 

ACY 

American  Cyanamid  Co. 

EKX 

Texas  Eastman  Co.  Division 

AEP 

A  6  t  Plastics  Pak  Co.,  Inc. 

EMR 

Emery  Industries,  Inc. 

AIP 

Air  Products  is  Chemicals,  Inc. 

ENJ 

Exxon  Corp.,  Exxon  Chemical  Co. USA 

ALF 

Allied  Chemical  Corp.,  Fibers  Div. 

hPC 

tpoxylite  Corp. 

AMh 

American  Chemical  Corp. 

EW 

Westinghouse  Electric  Corp.,  Industrial 

AMR 

Pacific  Resins  8  Chemical  Co. 

Plastics  Uiv.,  Chemical  Products  Plant 

APT 

Whittaker  Corp.,  Mol  Kez  Division 

APX 

Apex  Chemical  Co.,  Inc. 

FAR 

Famow,  Inc. 

ARK 

Armstrong  Cork  Co. 

FCD 

France,  Camnbell  f,   Darling,  Inc. 

ASH 

Ashland  Oil,  Inc.,  Ashland  Chemical  Co.  Div. 

FG 

Foster  Grant  Co.,  Inc. 

atr 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co.  Div. 

FIR 

Firestone  Tire  8  Rubber  Co.,  Firestone 

AZS 

AZS  Corp.,  M   Products  Co.  Div. 

Plastics  Co.  Div. 

FLH 

H.B.  Fuller  Co. 

HAL 

Baltimore  Paint  8  Chemical  Corp. 

FLW 

Fuller-O'Brien  Corp. 

HAS 

BASF  Wyandotte  Corp. 

FMP 

FMC  Corp.,  Industrial  Chemical  Div.  Organic 

BCM 

Belding  Chemical  Industries 

Business  Group 

BEN 

Bennett's 

FOC 

.Handschy  Chemical  Co.,  Farac  Oil  t,   Chemical 

BFG 

B.F.  Goodrich  Co.,  B.F.  Goodrich  Chemical  Co. 

Co.  Div. 

Division 

FOM 

Formica  Corp. 

BLS 

Beech-Nut,  Inc. 

FRh 

Freeman  Chemical  Corp. 

BMt 

Bendix  Corp.,  Friction  Materials  Division 

FRP 

FRP  Company 

BOR 

Borden  Co.,  Borden  Chemical  Co.  Division 

FSH 

Frisch  6  Co. ,  Inc. 

BRU 

M.A.  Bruder  6  Sons,  Inc. 

GAF 

GAF  Corp.,  Chemical  Division 

CBD 

Chembond  Corp. 

GE 

General  Electric  Co. : 

CBM 

Carborundum  Co.,  Coated  Abrasives  Division 

GET 

Insulating  Materials  Dept. 

CBN 

Cities  Service  Co.,  Columbian  Div. 

GIL 

Gilman  Paint  5  Varnish  Co. 

CBY 

Crosby  Chemicals,  Inc. 

GLC 

General  Latex  5  Chemical  Corp. 

CD 

Budd  Co.,  Polychem  Division 

GLD 

SCM  Corp.,  Glidden-Durkee  Division 

CEL 

Celanese  Corp. : 

GLX 

Electro-Seal  Glasflex  Corp. 

Celanese  Coatings  Co. 

GNM 

General  Mills  Chemicals,  Inc. 

Celanese  Plastics  Co. 

GNT 

General  Tire  6  Rubber  Co.,  Chemical  Division 

CGL 

Cargill,  Inc. 

GOC 

Gulf  Oil  Corp.,  Gulf  Oil  Co.  Chemicals  Dept . - 

CGY 

Ciba-Geigy  Corp. 

United  States 

CLK 

Clark  Chemical  Corp. 

GOR 

Gordon  Chemical  Co.,  Inc. 

CM 

Carpenter-Morton  Co. 

GP 

Georgia-Pacific  Corp. 

CMP 

Commercial  Products  Co.,   Inc. 

GPM 

General  Plastics  Manufacturing  Co. 

CO 

Continental  Oil  Co. 

GRA 

Great  American  Chemical  Corp. 

COM 

Commercial  Solvents  Corp. 

GRD 

W.R.  Grace  5  Co.,  Polymers  Chemicals  Division 

COO 

Coopers  Polymers,  Inc. 

GRG 

P.D.  George  Co. 

CPV 

Cook  Paint  5  Varnish  Co. 

GRV 

Guardsman  Chemical  Coatings,  Inc. 

CPX 

Chemplex  Co. 

GYR 

Goodyear  Tire  6  Rubber  Co. 

CSD 

Cosden  Oil  5  Chemical  Co. 

HAN 

Hanna  Chemical  Coating  Corp. 

DA 

Diamond  Shamrock  Corp. 

HAP 

Applied  Plastics  Co.,  Inc. 

DAN 

Dan  River,  Inc. 

HER 

Heresite  S  Chemical  Co. 

DAV 

Conchemco,  Inc.,   H.B.  Davis  Co.  Division 

HKD 

Hooker  Chemical  Corp.,  Durez  Division 

DCC 

Dow  Coming  Corp. 

HLM 

U.S.  Industries,  Inc.,  E.  Helman  Co.  Division 

DEC 

Degan  Oil  5  Chemical  Co. 

HN 

Tenneco  Chemicals,  Inc. 

DOW 

Dow  Chemical  Co. 

HNC 

H  5  N  Chemical  Co. 

DPI 

Diamond  Plastics,  Inc. 

HPC 

Hercules,  Inc. 

DPP 

Dixie  Pine  Products  Co.,  Inc. 

HRT 

Hart  Products  Corp. 

DSO 

DeSoto,  Inc. 

HVG 

Haveg  Industries 

DUP 

E.I.  duPont  de  Nemours  b  Co.,  Inc. 

HYC 

Dexter  Corp.,  Hysol  Co.  Division 

PLASTICS  AMD  RESIN  MATERIALS 
TABLE  3,— Plastics  and  resim  materials;     Directory  of  manufacturers,  1972~Continued 


Code 

Name  of  company 

Code 

Name  of  company 

ICF 

Inmont  Corp. ,  ABI  Div. 

pnt 

Pantasote  Co. 

ICI 

ICI  America,  Inc.  f,   Specialty  Chemicals 

POL 

Polymer  Corp. 

Div. 

PPG 

PPG  Industries,  Inc. 

INL 

Inland  Steel  Co.,  Inland  Steel  Container  Co. 

PPL 

Pioneer  Plastics  Corp. 

Division 

prt 

Pratt  5  Lambert,  Inc. 

IOC 

lonac  Chemical  Co.  Div.  of  Sybron  Corp. 

PRX 

Purex  Corp.,  Ltd.,  Washbum-Lanson  Co.  Div. 

IPC 

Interplastic  Corp. 

PVI 

Polyvinyl  Chemical  Ind.,  Div.  of  Ceatrice 

IRI 

Ironsides  Resins,  Inc. 

Foods  Co. 

PYZ 

Polyrez  Co. ,  Inc. 

JNS 

S.C.  Johnson  5  Son,  Inc. 

JOB 

Jones-Blair  Paint  Co. 

QCP 

Quaker  Chemical  Corp. 

JSC 

Jersey  State  Chemical  Co. 

QUN 

K.J.  Qidnn  5  Co.,  Inc. 

JWL 

Jewel  Paint  6  Varnish  Co. 

RAB 

Raybestos-Manhattan,  Inc.,  Raybestos  Div. 

KMC 

Kohler-McLister  Paint  Co. 

RCC 

Dart  Industries,  Inc.,  Rexene  Polymers  Co.  Div 

KMP 

Kelly-Moore  Paint  Co. 

RCD 

Richardson  Co. 

KPP 

Sinclair- Koppers  Co. 

RCI 

Reichhold  Chemicals,  Inc. 

KPT 

Koppers  Co. ,  Organic  Materials  Division 

RED 

Red  Spot  Paint  and  Varnish  Co.,  Inc. 

KYN 

Kyanize  Paints,  Inc. 

REL 

Reliance  Universal,  Inc.  5  Resin  Div. 

KYS 

Keysor  Chemical  Corp. 

REZ 

Hexcel  Corp.,  Rezolin  Division 

RGC 

Rogers  Corp. 

MCA 

Masonite  Corp.,  Alpine  Division 

RH 

Rohm  ^   Haas  Co . 

MCB 

Borg-Wamer  Corp.,  Marbon  Chemical  Division 

RPC 

Millmaster  Onyx  Corp.,  Refined-Onyx  Division 

MCC 

McCloskey  Varnish  Co. 

RSN 

Relsan  Corp. 

MFC 

North  American  Rockwell  Corp. 

RSY 

Resyn  Corp. 

MID 

Dexter  Corp. ,  Midland  Division 

KUB 

Hooker  Chemical  Corp.,  Ruco  Division 

MMM 

Minnesota  Mining  S  Manufacturing  Co. 

MNP 

Minnesota  Paints,  Inc. 

S 

Sandoz,  Inc.,  Sandoz  Color  5  Chemical  Div. 

MOB 

Mobay  Chemical  Co. 

SAC 

Southeastern  Adhesives  Co. 

MON 

Monsanto  Co. 

SAR 

Sartomer  Industries,  Inc. 

MR 

Benjamin  Moore  6  Co. 

SBC 

Scher  Bros . ,  Inc. 

MRA 

Crown  Metro,  Inc. 

SB! 

Standard  Brands  Chemical  Industries,  Inc. 

MRS 

Marblette  Co. 

SCF 

Guardsman  Chemical  Coatings,  Inc., 

MRO 

W.R.  Grace  5  Co.,  Marco  Chemical  Division 

Louisville  Division 

mrt 

Morton  Chemical  Co.  Div.  of  Morton-Norwich 

SCN 

Schenectady  Chemicals,  Inc. 

Products,  Inc. 

SCO 

Scholler  Bros. ,  Inc. 

SED 

'  Conchemco,  Inc.,  Kansas  City  Division 

NCI 

Union  Camp  Corp.,  Chemical  Division 

SEY 

Seydel-Woolley  5  Co.,   Inc. 

NEV 

Neville  Chemical  Co. 

SFP 

Stauffer  Chemical  Co.,  Plastics  Div. 

NPV 

Norris  Paint  5  Varnish  Co.,  Inc. 

SHA 

Shanco  Plastics  5  Chemicals,  Inc. 

NSC 

National  Starch  5  Chemical  Corp. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

ntc 

National  Casein  Co. 

SIC 

Vistron  Corp.,  Silmar  Division 

NVT 

Novamont  Corp.,  Neal  Works 

SIM 

Simpson  Timber  Co. 

SIP 

Sipes  Chemical  Coatings  Co. 

OBC 

O'Brien  Corp. 

SKP 

Shakespeare  Co.,  Industrial  Products  Division 

OCF 

Owens-Corning  Fiberglas  Corp. 

SKT 

Textron  Inc.,  Spencer  Kellogg  Division 

omc 

01  in  Corp. 

SM 

Mobil  Oil  Corp.,  Mobil  Chemical  Co., 

ONX 

Millmaster  Onyx  Corp.,  Onyx  Chemical  Corp. 

Chemical  Coatings  Div. 

ORO 

Chevron  Chemical  Co. 

SNW 

Sun  Chemical  Corp.,  Chemicals  Division 

SOL 

Solar  Chemical  Corp. 

PA  I 

Pennsylvania  Industrial  Chemical  Corp. 

SOR 

Thomason  Industries,  Inc.,  Southern  Resin  Div. 

PC 

Proctor  Chemical  Co.,  Inc. 

SPC 

Sinclair  Paint  Co.,  Div.  of  Insilco  Corp. 

PEL 

Pelron  Corp. 

SPD 

General  Electric  Co.,  Silicone  Products  Dept. 

PER 

Perry  6  Derrick  Co. 

SPE 

Petrochemical  Investment  Corp. 

PFP 

Midwest  Manufacturing  Corp. 

SPL 

Spaulding  Fibre  Co.,  Inc. 

PFZ 

Pfizer,  Inc. 

stc 

Sou-Tex  Chemical  Co.,  Inc. 

PGU 

Gulf  Oil  Corp.,  Gulf  Adhesives 

SW 

Sherwin-Williams  Co. 

PII 

Polymer  Industries,  Inc. 

PLA 

Richardson  Co. 

tna 

Ethyl  Corp. 

PLC 

Phillips  Petroleum  Co. 

TX 

Texaco,  Inc. 

PLS 

Plastics  Engineering  Co. 

TXT 

Text il ana  Corp. 

PMC 

Plastics  Manufacturing  Co. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3, --Plastics  and  resin  materials:     Directory  of  manufacturers,  1972--Continued 


Code 

Name  of  company 

Code 

Name  of  company 

UBS 

A.E.  Staley  Manufacturing  Co.,  Staley 

VAL 

Valchem 

Chemicals  Division 

VEL 

Veliscol  Chemical  Corp. 

ucr 

Union  Carbide  Corp. 

VPC 

Baychem  Corp.,  Verona  Div. 

UNO 

United-Erie,  Inc. 

vsv 

Valentine  Sugars,  Inc. 

uoc 

Union  Oil  Co.  of  California 

UPJ 

Upjohn  Co. 

WCA 

West  Coast  Adhesives  Co. 

UPL 

U.S.  Plywood,  WCM  Operations,  Shasta  Area 

WCL 

Wright  Chemical  Co. 

USI 

National  Distillers  5  Chemical  Corp.,  U.S. 

WIC 

Wica  Chemical  Inc. 

Industrial  Chemicals  Co.  Div. 

WLN 

Wilmington  Chemical  Corp. 

US  I 

National  Petro  Chemical  Corp. 

WRD 

Weyerhaeuser  Co.,  Wood  Products  D 

vision 

uso 

U.S.  Oil  Co. 

IVTC 

Witco  Chemical  Co.,  Inc. 

USR 

Uniroyal,  Inc.,  Chemical  Division 

USS 

USS  Chemicals,  Div.  of  U.S.  Steel  Corp. 

ZGL 

Carolina  Processing  Corp. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendi 


141 


RUBBER- PROCESSING  CHEMICALS 

Rubber-processing  chemicals  are  organic  compounds  that  are  added 
to  natural  and  synthetic  rubbers  to  give  them  qualities  necessary  for 
their  conversion  into  finished  rubber  goods.  In  this  report,  statis- 
tics are  given  for  cyclic  and  acyclic  compounds,  by  use — such  as 
accelerators,  antioxidants,  blowing  agents,  and  peptizers.  Data  on 
production  and  sales  of  rubber-processing  chemicals  in  1972  are  given 
in  table  1. 

Production  of  rubber-processing  chemicals  as  a  group  in  1972  amounted 
to  361  million  pounds,  or  11.6  percent  more  than  the  323  million  pounds 
reported  for  1971.   Sales  of  rubber-processing  chemicals  in  1972  amounted 
to  280  million  pounds,  valued  at  $178  million,  compared  with  246  million 
pounds,  valued  at  $159  million,  in  1971.   The  increased  production  and 
sales  of  rubber-processing  chemicals  in  1972  is  attributable  principally 
to  the  increased  production  and  sales  of  cyclic  antioxidants,  antiozonants , 
and  stabilizers. 

The  output  of  cyclic  rubber-processing  chemicals  in  1972  amounted  to 
310  million  pounds,  or  about  12.2  percent  more  than  was  reported  for  1971. 
Sales  in  1972  were  240  million  pounds,  valued  at  $158  million,  compared 
with  211  million  pounds,  valued  at  $143  million,  in  1971.  Of  the  total 
output  of  cyclic  rubber-processing  chemicals  in  1972,  accelerators  ac- 
counted for  32.1  percent  and  antioxidants  for  63.1  percent.   Production 
of  antioxidants,  which  amounted  to  195.6  million  pounds  in  1972,  included 

129.5  million  pounds  of  amino  compounds  and  66.1  million  pounds  of 
phenolic  and  phosphite  compounds.   Sales  of  amino  antioxidants  in  1972  were 

100.6  million  pounds,  valued  at  $68.7  million;  sales  of  phenolic  and 
phosphite  antioxidants  were  47.9  million  pounds,  valued  at  $27.2  million. 

Production  of  acyclic  rubber-processing  chemicals  in  1972  amounted 
to  51.1  million  pounds,  an  increase  if  8.0  percent  from  the  47.3  million 
pounds  reported  for  1971.   Sales  in  1972  totaled  40.2  million  pounds, 
valued  at  $19.7  million,  compared  with  34.9  million  pounds,  valued  at 
$16.8  million*  in  1971.  Accelerators  accounted  for  56.3  percent  of  the 
output  of  acyclic  rubber-processing  chemicals  for  1972  and  dodecyl  mer- 
captans  accounted  for  29.8  percent. 


^  See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers  by  codes.   These  codes  are  given  in  table  3. 


552-743  O  -  74  -  10 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  1.— Rubber-processing  chemicals;     U.S.  production  and  sales,  1972 


[Listed  below  are  all  rubber-processing  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  2  lists  separately  all  rubber-processing  chemicals  for  which  data  on  production  or  sales  were  re- 
ported and  identifies  the  manufacturers  of  each] 


Production 


Quantity 


Unit 
value' 


Grand  total 

RUBBER- PROCESSING  CHEMICALS,  CYCLIC 

Total 

Accelerators,  activators,  and  vulcanizing  agents,  total 

Aldehyde-amine  reaction  products 

Dithiocarbamic  acid  derivatives 

Thiazole  derivatives,  total 

N-Cyclohexyl-2-benzothiazolesulfenamide 

2, 2 '-Dithi obis (ben zo thiazole) 

2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole,  zinc  salt 

All  other  thiazole  derivatives 

All  other  accelerators,  activators,  and  vulcanizing  agents 

Antioxidants,  antiozonants,  and  stabilizers,  total 

Amino  compounds,  total 

Substituted  p-phenylenediamines ,  total 

N,N'-Bis (1 ,4-dimethylpentyl)-p-phenylenediamine 

N,N' -Diphenyl-p-phenylenediamine 

All  other  substituted  p-phenylenediamines 

Oc t y Id i phenyl amine 

N-Phenyl-2-naphthyl amine 

All  other  amino  compounds^ 

Phenolic  and  phosphite  compounds,  total 

Polyphenolics  (including  bisphenols) 

Phenol,  alkylated 

Phenol,  styrenated 

All  other  phenolic  and  phosphite  compounds 

Retarder:   N-Nitrosodiphenylamine 

All  other  cyclic  rubber-processing  chemicals'* 

RUBBER- processing  CHEMICALS,  ACYCLIC 

Total - - - - 

Accelerators,  activators,  and  vulcanizing  agents,  total 

Dithiocarbamic  acid  derivatives,  total 

Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  zinc  salt 

All  other  dithiocarbamic  acid  derivatives 


1,000 
pounds 


av).484 


2,256 

419 

86,338 

8,819 
21,272 

6,030 

4,006 
46,211 
10,471 

195,642 


129,515 

70,537 

6,049 

1,790 

62,698 

3,614 

4,511 

50,853 

66,127 

15,314 

1,581 


2,018 
12,786 


10,042 
3,989 
1,887 


1,000 
pounds 


1,000 
dollars 


157,944 


78.i4o 


1,302 

236 

67,001 

5,241 
11,675 

4,682 

4,132 
41,271 
10,307 

148,444 


00 

584 

48 

502 

1 

761 

46 

741 

3 

300 

48 

782 

47 

860 

14 

481 

3 

031 

1 

601 

28 

747 

1 

108 

11 

646 

20.599 


3,644 
2,007 
2,067 


50.874 


1,266 
597 

40,150 
4,852 
6,221 
1,784 
2,192 

25,101 
8,861 


68,663 
42,646 


40,851 

1,751 

24,266 

27,159 
16,100 

1,569 
444 

9,046 

702 
10,546 


3,185 
1,132 


Per 
pound 

$0.63 


.57 
1.11 


See  footnotes  at  end  of  table 


RUBBER-PROCESSING  CHEI1ICALS 
TABLE  1, --Rubber-processing  chemicals:  U.S.  production  and  Sales,  1972--Continued 


Quantity 


Unit 
value' 


RUBBER-PROCESSING  CHEMICALS,    ACYCLIC--Continued 

Accelerators,   activators,   and  vulcanizing  agents--Continued 

ThiuraTiis,   total' 

Bis(dimethylthiocarbamoyl)    disulfide 

Bis (dimethyl thiocarbamoyl)    sulfide 

All   other   thiurams 

All   other  accelerators,   activators,  and  vulcanizing  agents' 


Polymerization  regulators:      Dodecyl  raercaptans 

Shortstops;      Dimethyldithiocarbamic  acid,   sodium  salt- 
All  other  acyclic  rubber-processing  chemicals® 


13,079 
2,618 


15,243 
4,575 
2,494 


1,000 
pounds 


11,596 
8,476 
2,006 
1,114 
1,285 

14,750 
2,070 
2,780 


1,000 
dollars 


5,226 
3,050 
1,554 
642 
2,063 

5,322 

533 

1,287 


Per 
pound 


'  Calculated  from  rounded  figures. 

^  Includes  guani dines. 

^   Includes  aldehyde-  and  acetone-amine  reaction  products . 

'*  Includes  blowing  agents,  peptizers,  and  other  uses  not  separately  shown. 

^  Data  on  dithiocarbamates  included  in  this  table  are  for  materials  used  chiefly  in  the  processing  of  natural  and 
synthetic  rubbers.  Data  on  dithiocarbamates  which  are  used  chiefly  as  fungicides  are  included  in  the  report 
"Pesticides  and  Related  Products." 

'  Includes  data  for  small  amounts  of  tetramethylthiuram  sulfides  for  uses  other  than  in  the  processing  of  natural 
and  synthetic  rubbers. 

'   Includes  xanthates,  disulfides,  other  dithiocarbamic  acid  derivatives  (sales  only)  and  other  thiurams  (production 
only) . 

'  Includes  blowing  agents,  conditioning  and  lubricating  agents,  polymerization  regulators,  shortstops  and  physical 
property  improvers. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2, --Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972 


[Rubber-processing   chemicals    for  which   separate    statistics   are   given   in   table    1    are  marked  below  with   an   asterisk  (*) ; 
chemicals   not    so  marked  do  not    appear   in   table    1  because   the   reported  data  are   accepted   in   confidence   and  may  not 
be   published.      Manufacturers'    identification   codes    shown  below   are   taken   from  table   3.      An   x  signifies   that   the 
manufacturer  did  not    consent   to  his    identification  with   the   designated  product] 


Manufacturers'    identification   codes 
(according  to   list    in   table   3) 


RUBBER-PROCESSING   CHEMICALS,    CYCLIC 

♦Accelerators,    activators,    and  vulcanizing   agents: 
*Aldehyde-anine   reaction  products: 

Acetaldehyde-ani line  condensate 

n- But yraldehyde- aniline   condensate 

Butyr aldehyde -but ylideneani line   condensate 

a-Ethyl-6-propylacrylanilide 

Hept aldehyde- aniline   condensate 

Triethy Itrime thy lenetri amine 

*Dithiocarbamic   acid  derivatives: 

Dibenzyldithiocarbamic  acid,   sodium  salt 

Dibenzyldithiocarbamic  acid,    zinc  salt 

Dibutyldithiocarbamic  acid,   N,N-dimethylcyclohexyl- 
amine   salt. 

Dibutyldithiocarbamic   acid,    diphenylguanidine    salt 

2  ,4-ninitrophenyl   dimethyldithiocarbamate 

Piperidinecarbodithioic   acid,   piperidinium-notassium 
salts,   mixed. 
Guanidines : 

Dicatechol   borate,    di-o-tolylguanidine   salt 

1,3-Diphenylguanidine 

1,3-Di-o-tolylguanidine 

Dodecyltetramethylguanidine 

1 ,2 ,3-Triphenylguanidine 

*Thiazole   derivatives: 

2-Benzothiazyl  N,.N-diethylthiocarbamoyl   sulfide 

1 , 5-Bis (2-benzothiazolylmercaptomethyl)    urea 

N-tert- Butyl- 2-benzothiazolesulfenamide 

*N-Cyclohexyl-2-benzothiazolesulfenamide 

N,N-Diisopropyl-2-benzothiazolesulfenaniide 

N- (2 ,6-nimethylmorpholino) -2-benzothiazolesulfen- 
amide. 

*2,2'-Dithiobis(benzothiazole1 

*2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole,    copper  salt 

2-Mercaptobenzothiazole,    zinc   chloride 

*2-Mercaptobenzothiazole,    zinc  salt 

4-Morpholinyl-2-benzothiazyl   disulfide 

N-Oxydiethylene-2-benzothiazolesulfenaiiiide 

Thiazoline-2-thiol 

All  other  cyclic  accelerators,    activators,   and  vulcan- 
izing agents: 

p-Benzoquinonedioxime 

Bis (p-aminocyclohexy 15 methane   carbamate 

Bis (morpholinothiocarbonyl)    disulfide 

Dibenzoy 1 -p- quinonedi  oxime 

Dibenzyl amine 

N,N'  -Dicinnamylidene-1 ,6-hexanediainine 

Di-^J,N' -pent ame thy lenethiuram  tetrasulfide 

4,4 ' -Dithiodimorpholine 

2- Imidazoline- 2- thiol 

m-Phenylenebismaleimide 

Poly-p-dinitrosobenzene 

Toluene-2,4-diisocyanate  adduct  of  dimethylethanol- 
amine. 
*Antioxidants ,  antiozonants,  and  stabilizers: 
*Amino  compounds: 

Aldehyde-  and  acetone-amine  reaction  products: 

Acetaldehyde-aniline  hydrochloride  condensate 

Aldol-a-naphthylamine  condensate 

Butyr aldehyde- aniline  condensate 


USR. 

DUP,  MON,  RCD,  USR. 

MON. 

RCI. 

USR. 

USR. 

USR. 
USR. 
MON. 

RCI- 
USR. 
DUP. 


DUP. 
ACY. 
ACY. 
DUP. 
ACS. 

PAS. 

MON. 

ACY,  MON. 

ACY.  BFG,  MON,  USR. 

ACY. 

MON. 

ACY,  BFG,  GYR,  MON,  USR. 

ACY,  BFG,  GYR,  MON,  USR. 

ACY. 

DUP. 

ACY,  BFG,  GYR,  USR. 

GYR. 

ACY,  BFG,  MON. 

ACY. 


CTN. 
DUP.' 
ACY. 

CTN,  USR. 
MLS,  USR. 
DUP. 

DUP,  WC. 
•KDN,  VNC. 
DUP,  RBC. 
DUP. 
DUP. 
DUP. 


USR. 
BFG. 
DUP. 


I 


RUBBER-PROCESSING  CHEMICALS 


TABLE  2.- 


-RUBBER-PROCESSING    CHEMICALS    FOR    WHICH    U.S.    PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED    BY   MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification   codes 
(according  to    list    in  table   3) 


RUBBER-PROCESSING   CHEMICALS,    CYCLIC  — CONTINUED 

^.Antioxidants  ,   antiozonants  ,    and  stabilizers--Continued 
*Aiiiino  compounds --Continued 

Aldehyde-   and  acetone-amine   reaction  products-- 
Continued 

Di phenyl amine -ace tone   condensate 

Phenyl-2-naphthylamine-acetone    condensate 

*Substituted  p-phenylenediamines : 

N,N'-Bis(l ,3-dimethylbutyl)-p-phenylenediamine 

*N,N'-Bis(l ,4-dimethylpentyl)-p-phenylenediamine 

N,N' -Bis{l-ethyl-3-methylpentyl)-p-phenylenediamine 

N,N'-Bis(l-methyIheptyl) -p-phenylenedi amine 

N-sec-Butyl-N' -phenyl-p- phenyl enedi amine 

N-Cyclohexyl-N'-phenyl-p-phenylenediamine 

Diarylaryl enedi amines ,    mixed 

N,N' -Dicyclohexyl-p-phenylenediamine 

N- (1 ,5-Dimethylbutyl} -N' -ph enyl-p- phenyl enedi amine -■ 

N,N' -1 ,4~Dimethylhexyl-p-phenylenediamine 

N,N ' -Di-2-naphthyl-p-phenylenediamine 

*N,N' -Diphenyl-p-phenylenediamine 

N- I sopropyl-N' -phenyl -p-phenylenediamine 

N- (1-Methylheptyl) -N' -phenyl-p -phenyl enedi amine 

N-  (1-MetIiylpentyl)  -N'  -phenyl -p-phenylenedi amine 

Nit roso-N-phenyl -p-phenylenediamine 

All   other  substituted  p-phenylenediamine 

Other  amino  compounds: 

p-Anilinophenol 

4'-Bis(a,a-dimethylbenzyl)diphenylamine 

1 ,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline 

1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

1 ,2-Dihydro~2,2,4-trimethylquinoline 

4,4'-Dimethoxydiphenylamine 

Dinonyldiplienyl  amine 

N,N'-Diphenylethylenediamine 

N,N' -Diphenyl -1 , 5-propanediamine 

N,N' -Di-o-tolylethylenediamine 

p-Hydroxydi phenyl amine 

4,4'-Methylenedianiline 

Nonyldiphenylamine  mixture    (mono-,    di-,    and   tri-) — 

*Octyldiphenyl amine 

Oc t y Id i phenyl amine,    alkylated 

N-Phenyl-1-naphthylamine 

*N-Phenyl-2-naphthylamine 

p- (p-Toluenesulfonamide)diphenylamine 

All   other 

'Phenolic  and  phosphite  compounds: 
Phenolic  compounds: 
*Polyphenolics  (including  bisphenols) : 

Bisphenol,  hindered 

4,4' -Butyl ideneb is (6-tert-butyl-m-cresol) 

2,5-Di-sec-butyldecylhydroquinone 

2,5-Di-(l, l-dimethylpropyl)hydroquinone 

2,2' -Methylenebis (6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol) 

2, 2 '-Methylenebis [6- (l-methylcyclohexyl) -p- 
cres  0 1  ] . 

2,2'-Methylenebis(6-tert-octyl-p-cresol) 

2,2'-Thiobis(4,6-di-5ec-amylphenol) 

4, 4 '-Thiobi 5 (6-tert-butyl-m-cresol) 

Thiobisphenol ,  alkylated 

1, 1,3 -Tri (2 -methyl-4-hydroxy-5-tert -butyl phenyl )- 
butane. 


ACY 

BFG, 

USR. 

USR 

x. 

EKT 

USR, 

X. 

MON 

X. 

BFG 

MON, 

X. 

USR 

USR 

X. 

GYR. 

X. 

GYR, 

USR. 

X. 

BFG, 

DUP. 

BFG, 

DUP, 

SDC,  USR 

USR. 

X. 

USR. 

USR. 

MON. 

BFG. 

WSN. 

MON. 

MON. 

BFG, 

MON. 

DUP. 

ACY. 

DA, 

RCI. 

RCI. 

RCI. 

USR. 

USR. 

USR. 

.ACY, 

NPI, 

USR. 

BFG. 

DUP, 

UCC. 

BFG, 

DUP, 

USR. 

USR. 

USR. 

GYR,  USR. 

MON. 

USR. 

MON. 

ACY,  A.SH. 

ACY. 

ICI. 

ACY. 
MON. 
MON. 
USR. 
ICI. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 


TABLE  2.--F 


3ER-PR0CESSING    CHEMICALS    FOR    WHICH    U.S,    PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED   BY   MANUFACTURER,    1972--CONTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table   3) 


RUBBER-PROCESSING  CHEMICALS,    CYCLIC--CONTINUED 

•Antioxidants,   antiozonants,   and  stabilizers--Continued 
'Phenolic  and  phosphite  coiiipounds--Continued 
Phenolic  compounds--Continued 
Other  phenolic   compounds: 

p-Benzyloxyphenol 

o-Cresol,   alkylated 

N-Lauroyl-p-aminophenol 

•Phenol,  alkylated 

Phenol,  hindered 

*Phenol ,  styrenated 

N-Stearoyl-p- aminopheno 1 

♦Phosphite  compounds: 

Alkylaryl  phosphites 

Nonyl  phenyl  phosphites,  mixed 

Polymeric  phosphite 

Polyphenolic  phosphite,  alkylated 

Tr iary 1  phosphates 

Blowing  agents: 

N,N' -Dimethyl-N,N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-OxybisCbenzenesulfonhydrazide) 

p-Toluenesulfonylhydrazide 

p-Toluenesulfonylsemicarbazide 

Peptizers: 

2-Benzamidothiophene,  zinc  salt 

Dicresyl  disulfide 

2' ,2' ' '-Dithiobis(benzanilide) 

Dixylyl  disulfides,  mixed 

2-Naphthalenethiol 

Pentachlorobenzenethiol 

Xylenethiol 

*Retarders:  N-Nitrosodiphenylamine 

Other  cyclic  rubber-processing  chemicals: 

p-tert-Amylphenol  sulfide  (tackifier) 

4-Chloro-2,6-bisC2,4-dihydroxybenzyl)phenol 

Phenol  cyanurate  complex 

All  other 

RUBBER-PROCESSING  CHEMICALS,  ACYCLIC 

•Accelerators,  activators,  and  vulcanizing  agents: 
•Dithiocarbamic  acid  derivatives: 

Dibutyldithiocarbamic  acid,  nickel  salt 

Dibutyldithiocarbamic  acid,  potassium  salt 

Dibutyldithiocarbamic  acid,  sodium  salt 

•Dibutyldithiocarbamic  acid,  zinc  salt 

Diethyldithiocarbamic  acid,  selenium  salt 

Diethyldithiocarbamic  acid,  sodium  salt 

Diethyldithiocarbamic  acid,  tellurium  salt 

•Diethyldithiocarbamic  acid,  zinc  salt 

Dimethyldithiocarbamic  acid,  bismuth  salt 

Dimethyldithiocarbamic  acid,  copper  salt 

Dimethyldithiocarbamic  acid,  lead  salt 

Dimethyldithiocarbamic  acid,  selenium  salt 

Dimethyldithiocarbamic  acid,  sodium  salt  and  sodium 
polysulfide. 

•Dimethyldithiocarbamic  acid,  zinc  salt 

All  other 

•Thiurams : 

Bis(dibutylthiocarbamoyl)  sulfide 

Bisfdiethylthiocarbamoyl)  disulfide 

•Bis (dimethyl thiocarbamoyl)  disulfide 


BFG. 

PIT. 

MLS. 

ACY,  BFG,  GYR,  NEV,  PIT,  RCI. 

DUP,  GYR. 

BFG,  GYR,  NEV,  USR. 

MLS. 

WES. 

NPI,  USR. 
NPl. 
BFG. 
WES. 

DUP. 
NPI. 
USR. 
USR. 
USR. 

ACY. 
USR. 
ACY. 
PIT. 
DUP. 
SDC. 
DUP. 
ACY,  BFG,  CTN,  GYR,  NPI,  USR. 

PAS. 
ICI. 
ICI. 
MON,  RCI. 


DUP,  USR,  VNC. 

DUP,  PAS,  RBC,  USR,  VNC. 


PAS. 

GYR,  PAS,  USR,  VNC. 


USR. 
VNC. 
ALC, 
ALC, 
VNC. 
ALC, 
VNC. 
ALC, 
VNC. 
VNC. 
VNC. 
VNC. 
BFG. 


ALC,  DUP,  FMN,  GYR,  PAS,  RBC,  USR,  VNC,  WRC. 
VNC. 

USR. 

DUP,  GYR,  PAS. 

DUP,  GYR,  PAS,  VNC. 


RUBBER-PROCESSING  CHEMICALS 


TABLE  2, 


-Rubber-processing  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--C0NTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


RUBBER-PROCESSING  CHEMICALS,  ACYCLIC--CnNTINUED 

'Accelerators,  activators,  and  vulcanizing  agents-- 
Continued 
*Thiurams - -Cont  inued 

*Bis(dimethylthiocarbamoyl)  sulfide 

Bis(ethylmethylthiocarbamoyl)  sulfide 

Xanthates  and  sulfides: 

Bis(diisopropoxythiophosphoryl)  disulfide 

Di-n-butylxantho  disulfide 

Diisopropylxantho  disulfide 

Zinc  diisopropyl  xanthate 

All  other  acyclic  accelerators,  activators,  and 
vulcanizing  agents: 

n-Butyraldhyde-butylamine  condensate 

D i - n -but y 1 ammon ium  oleate 

3-Ethyl-l ,1 -dimethyl -2 -thiourea 

Ethyl enediamine  carbamate 

Tetramethyl thiourea 

1  ,l,3-Trimethyl-2-thiourea 

Blowing  agents:   Modified  urea 

Conditioning  and  lubricating  agents: 

Methyl  stearyl-10-sulfonic  acid,  sodium  salt 

Mono-  and  dialkyl  acid  phosphates,  mixed 

Mono-  and  dialkyl  phosphate  ammonium  salts,  mixed — 

Other 

Polymerization  regulators: 

Alkyl  mercaptans,  mixed 

*Dodecyl  mercaptan 

n-Octyl  mercaptan 

tert-Octyl  mercaptan 

Tridecyl  mercaptan 

Shortstops: 

Dimethyldithiocarbamic  acid,  potassium  salt 

*Dimethyldithiocarbamic  acid,  sodium  salt 

Other  acyclic  rubber-processing  chemicals: 

Zinc  laurate  (activator,  physical -property  improver) 


DUP,  GYR,  USR. 
PAS. 

DUP. 
USR. 
BFG. 
VNC. 


DUP. 

DUP. 

VNC. 

DUP. 

DUP. 

RBC,  VNC. 

DUP. 

DUP. 
DUP. 
DUP. 
DUP. 


HK,  PAS,  PLC. 

PAS. 

PAS. 

PAS. 

GYR,  USR. 

ALC,  DUP,  GYR,  PAS,  USR,  WRC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3, —Rubber-processing  chemicals;     Directory  of  manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 


[Names  o£  rubber-processing  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission 
for  1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ACS 

Allied  Chemical  Corp.,  Specialty  Chemicals 

MLS 

Miles  Laboratories,  Inc.,  Marshall  Div. 

Div. 

MON 

Monsanto  Co. 

ACY 

American  Cyanamid  Co. 

ALC 

Alco  Chemical  Corp. 

ASH 

Ashland  Oil,  Inc.,  Ashland  Chemical  Co. 

'  Div. 

NEV 

Neville  Chemical  Co. 

NPI 

Stepan  Chemical  Co.,  National  Polychesiicals  Di 

V- 

BFG 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical 
Co.  Div. 

PAS 
PIT 
PLC 

Pennwalt  Chemicals  Corp. 
Pitt-Consol  Chemical  Co. 
Phillips  Petroleum  Co. 

CTN 

Chemetron  Corp.,  Organic  Chemical  Div. 

RBC 
RCD 

Fike  Chemicals,  Inc. 
Richardson  Co. 

DA 

Diamond  Shamrock  Corp. 

RCI 

Reichhold  Chemicals,  Inc. 

DUP 

E.  I.  duPont  de  Nemours  5  Co.,  Inc. 

SDC 

Martin-Marietta  Corp.,  Sodyeco  Div. 

EKT 

Eastman  Kodak  Co.,  Tennessee  Eastman 
Co.  Div. 

UCC 

Union  Carbide  Corp. 

FMN 

FMC  Corp.,  Niagara  Chemical  Div. 

UPM 
USR 

Universal  Oil  Products  Co. 
Uniroyal,  Inc.,  Chemical  Div. 

GYR 

Goodyear  Tire  5  Rubber  Co. 

VNC 

Vanderbilt  Chemical  Corp. 

HK 

Hooker  Chemical  Corp. 

WES 

Borg-Warner  Corp.,  Weston  Chemical  Div. 

ICl 

ICI  America,  Inc. 

WRC 

Ventron  Corp . ,  Wood  Ridge  Chemical 

WSN 

Mallinckrodt  Chemical  Works,  Washine  Div. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix. 


149 

ELASTOMERS 

Elastomers    (synthetic  rubbers)    are  high  polymeric  materials  with 
properties   similar  to  those  of  natural  rubber.      The  term  "elastomers"  as 
used  in  this   report,   means   a  substance,  whether  in  bale,    crumb,  powder, 
latex,    and  other  crude  form,   which   can  be  vulcanized  or  similarly  proc- 
essed into  a  material   that   can  be  stretched  to  at  least  twice  its  original 
length   and,    after  having  been  so  stretched  and  the  stress  removed,  will 
return  with  force  to  approximately  its  original   length.      U.S.   production 
and  sales   of  elastomers   in   1972  are  shown   in  table  1.^ 

Total  U.S.    production  of  synthetic  elastomers   in   1972  was  4,914  mil- 
lion pounds,    an  increase  of  6  percent   from  that  produced  in  1971.      The 
sales   of  these  elastomers   amounted  to  4,136  million  pounds    (valued  at 
$1,095  million)    in   1972,    an  increase  of  3  percent  over  1971. 

Styrene-butadiene  rubber   (SBR  or  S-type  rubber)    in   1972   continued  to 
be  the  synthetic  elastomer  produced  in  the  greatest  quantity  as   it  has  been 
for  more  than  25  years.      U.S.    production  of  SBR,    including  38  million 
pounds  of  its   vinylpyridine  sub-type,    amounted  to  2,648  million  pounds   in 
1972.      Solution  polymerized  butadiene  rubber,    a  stereo  type  elastomer,  was 
produced  domestically  in   1972  in  the  next  largest   amount--666  million 
pounds;   production  of  isoprene   and  ethylene-propylene  rubbers,    the  other 
stereo  types,    amounted  to  295  million   and  200  million  pounds,    respectively. 
Total  U.S.    production  of  these  stereo  type  elastomers   amounted  to   1,161 
million  pounds   in   1972--an  increase  of  8  percent  over  1971.      Other  principal 
types  of  synthetic  elastomers   for  which  U.S.    production   and  sales  data  are 
reported  separately  are  isobutylene-isoprene    (butyl)    rubber,   production  of 
which  was   290  million  pounds   in   1972,    and  acrylonitrile-butadiene   (N-type) 
rubber,   production  of  which  was   160  million  pounds. 

U.S.    production   and  sales   data  on  synthetic  organic  chemicals   are 
reported  in  terms  of  cyclic  and  acyclic  structured  compounds   for  purposes 
of  better  correlation  with  other  statistical  reporting  systems.      In   1972, 
U.S.    production  of  cyclic  elastomers   amounted  to  2,706  million  pounds,    an 
increase  of  nearly  4  percent  over  1971;    sales  of  cyclic  elastomers   amounted 
to  2,177  million  pounds    (valued  at  $471  million^),    a  decrease  in  volume 
of  3  percent  compared  with   1971.      U.S.    production  of  acyclic  elastomers   in 
1972   amounted  to  2,208  million  pounds,    an  increase  of  10  percent   over  1971; 
sales  of  acyclic  elastomers   amounted  to   1,959  million  pounds    (valued  at 
$624  million),    an   increase   in   volume  of  9  percent  from  the  previous  year. 


See   also  table  2  which   lists  these  products   and  identifies  the  manu- 
facturers of  each  by   code.      These  codes   are  given  in   table  3. 

^The  value  of  sales   in   1971   and  1972   for  styrene-butadiene    (S-type)    rubber, 
which   comprise   about  90  percent  of  the  sales  value  of  cyclic  elastomers,  was 
calculated  on  a  somewhat   different  basis   than  in  previous  years.      The 
value  of  sales   in  1971   for  S-type  elastomers   is  believed  to  have  increased 
slightly  over  that  in   1970,    although  the  published  figures  showed  a  decrease. 


SYNTHETIC  ORGAillC  CHEMICALS,  1972 
TABLE  1.— Elastomers  (synthetic  rubbers):'  U.S.  production  and  sales-  1972 

[Listed  below  are  all  elastomers  (synthetic  rubbers)  for  which  reported  data  on  production  or  sales  may  be  published. 
(Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 
reported.)  Table  2  lists  all  elastomers  for  which  data  on  production  or  sales  were  reported  and  identifies  the 
manufacturers  of  each] 


Production 


Sales 


Quantity 


Unit 
value^ 


Grand  total 

ELASTOMERS,  CYCLIC 

Total 

Styrene-butadiene  type  (S-type)^ 

Styrene-butadiene-vinylpyridine  type 

Urethane  type 

ELASTOMERS,  ACYCLIC 

Total 

Acrylonitrile-butadiene  type  (N-type) 

Isobutylene-isoprene  type  (Butyl) 

Silicone  type 

Stereo  elastomers,  total 

Butadiene  (solution  polymerized)  type-- 

Ethy lene-propy 1 ene  type 

I soprene  type 

All  other  acyclic  elastomers^ 


1,000 
pounds 


4,915,959 


1,000 
pounds 


4,156,263 


1,000 
do  I  laps 


Per 
pound 


2,610,142 
38,161 
57,296 


2,208,560 


,118,686 
21,720 
56,897 


1,958,960 


'415,783 
11,829 
42,957 


624,257 


159,745 
289,746 
26,752 

1,160,849 


155,489 

27,214 

887,229 


59,884 
64,899 
176,402 


666,427 
199,558 
294,864 


466,315 
183,165 
237,749 


86,565 
47,795 
42,242 


The  term  "elastomers"  is  defined  as  substances  in  bale,  crumb,  powder,  latex,  and  other  crude  forms  which  can  be 
vulcanized  or  similarly  processed  into  materials  that  can  be  stretched  at  68°F.  to  at  least  twice  their  original 
length  and,  after  having  been  so  stretched  and  the  stress  removed,  will  return  with  force  to  approximately  their 
original  length. 

^  Calculated  from  rounded  figures. 

'  Elastomer-content  basis. 

'*  Partly  estimated. 

^  Partly  estimated.   Includes  the  value  of  added  oil. 

^  Includes  production  and  sales  data  for  acrylic  ester,  polysulfide,  chloroprene,  epichlorohydrin,  and  isobutylene 
elastomers,  butadiene  emulsion  polymers,  chlorosulfonated  polyethylene,  halogenated  elastomers,  thermoplastic  rubber, 
miscellaneous  elastomers  and  sales  data  for  the  isobutylene-isoprene  type  elastomer.  Also  includes  miscellaneous 
cyclic  elastomers,  among  which  are  carboxylated  SBR  latex,  certain  solution  poljTners,  and  thermoplastic  rubber. 

Note. — Statistics  on  the  production  of  S-type,  butyl,  neoprene,  and  stereo  elastomers  were  compiled  in  cooperation 
with  the  U.S.  Bureau  of  the  Census. 


TABLE  2.- 


ELASTOMERS 
-Elastomers  (synthetic  rubbers)  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER/  1972 


[Elastomers  (synthetic  rubbers)  for  which  separate  statistics  are  given  in  table  1  are  marked  below  with  an  asterisk 
[*) ;   products  not  so  marked  do  not  appear  in  table  1  because  the  reported  data  are  accepted  in  confidence  and 
may  not  be  published.  Manufacturers'  identification  codes  shown  below  are  taken  from  table  3.  An  x  signifies  that 
the  manufacturer  did  not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'  identification  codes 
(according  to  list  in  table  3] 


ELASTOMERS,  CYCLIC 

*Styrene-butadiene  type  (S-t>'pe) 

*Styrene-butadiene-vinylpyridine  type 

*Urethane  t>'pe 

Other  cyclic  elastomers 

elastomers,  ACYCLIC 

Acrylic  ester  type 

*Acrylonitrile-butadiene  type  (N-type) — 
Butadiene  (emulsion  polymerized)  type — 

Chloroprene  type  (Neoprene) 

*Isobutylene-isoprene  type  (Butyl) 

Polysulf ide  type 

Reaction  products  of  natural  rubber 

*Silicone  type 

*Stereo  elastomers: 

*Butadiene  (solution  polymerized)  type- 

*Ethylene-propylene  type 

*Isoprene  type 

All  other  acyclic  elastomers 


ASH,  ASY,  BFG,  CPY,  FIR,  FRS,  GNT,  GYR,  MCB,  PLC,  RUB,  SBI, 

SHC,  TUS,  USR,  WIC. 
BFG,  FIR,  FRS,  GNT,  GYR,  USR. 
ACY,  BFG,  CNl,  DA,  DNS,  DUP,  EPl,  GNT,  INP,  MOB,  PFP,  PLN, 

PRC,  RUB,  TKL,  USR,  WTC,  x,  x. 
ASY,  DUP,  PLC,  PRC,  SHC,  UCC. 


ACY,  BFG,  DA,  TKL. 

BFG,  CPY,  FRS,  GYR,  SBI,  USR. 

BFG,  FRS,  GYR,  TKL,  TUS. 

DUP,  PTT. 

CBN,  ENJ. 

PRC,  TKL. 

GYR,  ICl,  WAY,  X. 

DCC,  PRC,  SPD,  SWS,  UCC. 

ASY,  ATR,  BFG,  FRS,  GNT,  GYR,  PLC,  SHC,  TUS. 

BFG,  CPY,  DUP,  ENJ,  USR. 

BFG,  GYR,  SHC. 

.ASY,  BFG,  DUP,  ENJ,  HDM,  Mt»1,  PLC,  SHC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 


TABLE  3. 


-Elastomers  (synthetic  rubbers):     Directory  of  Manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 


[Names  of  elastomers  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission  for  1972  are 
listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ACY 

American  Cyanamid  Co. 

ICI 

ICI  America,  Inc. 

ASH 

Ashland  Chemical  Co. 

INP 

INDPOL 

ASY 

American  Synthetic  Rubber  Corp. 

atr 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co. 

MCB 

Borg-Warner  Corp.,  Marbon  Chemical  Div. 

Div. 

MW1 

Minnesota  Mining  S  Manufacturing  Co. 

MOB 

Mobay  Chemical  Co. 

BFG 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical 

Co.  Div. 

PFP 

Midwest  Manufacturing  Corp. 

PLC 

Phillips  Petroleum  Co. 

CBN 

Cities  Service  Co.,  Columbian  Group 

PLN 

Pellon  Corp.,  Disogrin  Industries,  Div. 

CNl 

Conap,  Inc. 

PRC 

Products  Research  6  Chemical  Corp. , 

CPY 

Copolymer  Rubber  5  Chemical  Corp. 

Chemical  and  Sealant  Div. 

PTT 

Petro-Tex  Chemical  Corp. 

DA 

Diamond  Shamrock  Corp. 

DCC 

Dow  Coming  Corp. 

RUB 

Hooker  Chemical  Corp.,  Ruco  Div. 

DNS 

Dennis  Chemical  Co. 

DUP 

E.  I.  duPont  de  Nemours  5  Co.,  Inc. 

SB  I 

Standard  Brands  Chemical  Industries,  Inc. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

ENJ 

Exxon  Chemical  Co.,  U.S.A. 

SPD 

General  Electric  Co.,  Silicone  Products  Dept . 

EPl 

Eagle  Pitcher  Industries,  Inc., 
Rubber  Products  Div. 

SWS 

Stauffer  Chemical  Co.,  SWS  Silicones  Div. 

TKL 

Thiokol  Chemical  Corp. 

Firestone  Tire  5  Rubber  Co.: 

TUS 

Texas-U.S.  Chemical  Co. 

FIR 

Firestone  Plastics  Co.  Div. 

FRS 

Firestone  Synthetic  Rubber  6  Latex 

UCC 

Union  Carbide  Corp. 

Co.  Div. 

USR 

Uniroyal ,  Inc.,  Chemical  Div. 

GNT 

General  Tire  5  Rubber  Co.,  Chemical  Div. 

WAY 

Philip  A.  Hunt  Chemical  Corp.,  Wayland 

GYR 

Goodyear  Tire  S  Rubber  Co. 

Chemical  Div. 

WIC 

Wica  Chemicals,  Inc. 

HDM 

Hardman,  Inc. 

WTC 

Witco  Chemical  Co.,  Inc. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies 


listed  in  Table  1  of  the  Appendix. 


153 
PLASTIC IZERS 


Plasticizers  are  organic  chemicals  that  are  added  to  synthetic 
plastics  and  resin  materials  to  (1)  improve  workability  during  fabri- 
cation, (2)  extend  or  modify  the  natural  properties  of  these  materials, 
or  (3)  develop  new  improved  properties  not  present  in  the  original 
material.   Table  1  presents  statistics  on  U.S.  production  and  sales  of 
plasticizers  in  as  great  as  detail  as  is  possible  without  revealing  the 
operations  of  individual  producers . ^ 

U.S.  production  of  plasticizers  totaled  1,708  million  pounds  in 
1972,   an  increase  of  14.3  percent  from  the  1,494  million  pounds  reported 
for  1971.   Sales  of  plasticizers  totaled  1,637  million  pounds,  valued  at 
$291  million,  in  1972,  compared  with  1,404  million  pounds,  valued  at 
$258  million,  in  1971. 

Production  of  cyclic  plasticizers  in  1972,  which  consisted  chiefly 
of  the  esters  of  phthalic  anhydride  and  phosphoric  acid,  amounted  to  1,302 
million  pounds,  an  increase  of  15.2  percent  from  the  1,130  million  pounds 
reported  for  1971.   Sales  of  cyclic  plasticizers  in  1972  totaled  1,273 
million  pounds,  valued  at  $180  million,  compared  with  1,075  million  pounds, 
valued  at  $158  million,  in  1971.   The  most  important  cyclic  plasticizer  was 
di(2-ethylhexyl)  phthalate,  with  production  of  435  million  pounds,  in  1972. 

Production  of  acyclic  plasticizers  in  1972  totaled  406  million  pounds, 
an  increase  of  11.7  percent  from  the  364  million  pounds  reported  for  1971. 
Sales  of  acyclic  plasticizers  totaled  364  million  pounds,  valued  at  $111 
million,  in  1972,  compared  with  330  million  pounds,  valued  at  $100  million, 
in  1971.   Epoxidized  soya  oils  were  the  most  important  acyclic  plasticizer 
in  1972,  with  production  of  85  million  pounds. 


See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers by  codes.   These  codes  are  listed  in  table  3. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  1.~Plasticizers;'  U.S.  production  and  sales,  1972 

[Listed  below  are  plasticizers  for  which  any  reported  data  on  production  or  sales  may  be  published.   (Leaders  are 
used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were  reported.) 
Table  2  lists  all  plasticizers  for  which  data  on  production  or  sales  were  reported  and  identifies  the  manufac- 
turers of  each] 


Quantity 


Grand  total 

Benzenoid' 

Nonbenzenoid 

PLASTICIZERS,  CYCLIC 

Total 

Phosphoric  acid  esters,  total 

Cresyl  diphenyl  phosphate 

Tricresyl  phosphate 

All  other  phosphoric  acid  esters 

Phthalic  anhydride  esters,  total 

Butyl  octyl  phthalates  (including  butyl  2-ethylhexyl 
phthalate,  isobutyl  2-ethylhexyl  phthalate,  and  butyl 

n-octyl  phthalate) 

Dibutyl  phthalate 

Diethyl  phthalate 

Diisodecyl  phthalate 

Dimethyl  phthalate 

Dioctyl  phthalates: 

Di (2-ethylhexyl)  phthalate 

Diiso-octyl  phthalate-- 

n-Hexyl  n-decyl  phthalate 

All  other  phthalic  anhydride  esters 

Triraellitic  acid  esters,  total 

Triiso-octyl  trimellitate 

Tri-n-octyl  n-decyl  trimellitate 

Trioctyl  trimellitate 

All  other  triraellitic  acid  esters 

All  other  cyclic  plasticizers" 

PLASTiaZERS,  ACYCLIC 

Total 

Adipic  acid  esters,  total 

Di[2-(2-butoxyethoxy)ethyl]  adipate 

Di (2-ethylhexyl)  adipate 

Diisodecyl  adipate 

Dioctyl  adipates  (including  diiso-octyl  adipate) 

n-Hexyl  n-decyl  adipate 

n-Octyl  n-decyl  adipate 

All  other  adipic  acid  esters 

Complex  linear  polyesters  and  polymeric  plasticizers' 

Di  (2-ethylhexyl)  azelate 


1,000 
pounds 

1,708.313 


1,393,499 
314,814 


3,772 


14,556 
50,221 
23,995 


11,353 
29,080 
19,044 
153,270 
9,683 

435,032 
32,296 
16,048 

439,887 

12,122 


4,231 
2,165 
2,967 
2,759 

55,368 


406,358 


1,325 

44,857 

2,838 

1,504 
8,763 
4,569 

53,183 
11,334 


1,000 
pounds 


1,000 
dollars 


1,354,410 
283,087 


15,152 
51,982 


14,214 
33,562 

162,183 
8,766 

441,776 

29,774 

9,365 

438,853 

9,680 


3,281 
1,050 
2,848 
2,501 

57,884 


364,306 


57,068 


1,342 
39,716 
2,188 
1,364 
1,031 
8,912 
2,515 

46,306 


201,340 
89,224 


4,074 
17,042 


1,774 
5,418 

19,129 
1,594 

48,655 
3,506 
1,161 

57.001 

2,732 


320 
802 
722 


110,513 


12,029 


703 
7,509 
460 
308 
202 
1,932 
915 

17,442 


See  footnotes  at  end  of  table. 


PLASTICIZERS 
TABLE  1.~Plasticizers;  '    U.S.  production  and  sales,  1972--Continued 


Quantity 


Unit 
value^ 


PLASTICIZERS,  ACYCLIC— Continued 

Epoxidized  esters: 

Epoxidized  soya  oils 

Octyl  epoxytallates  (including  2-ethylhexyl  epoxy 

tallates) 

Glyceryl  monoricinoleate 

Isopropyl  myristate 

Isopropyl  palmitate 

Oleic  acid  esters,  total 

Butyl  oleate 

Methyl  oleate 

Propyl  oleates  (including  n-propyl  oleate  and  isopropyl 

oleate) 

All  other  oleic  acid  esters 

Phosphoric  acid  esters 

Sebacic  acid  esters,  total 

Dibutyl  sebacate 

Di(2-ethylhexyl)  sebacate 

All  other  sebacic  acid  esters 

Stearic  acid  esters,  total 

n- Butyl  stearate 

All  other  stearic  acid  esters 

Triethylene  glycol  di(caprylate-caprate) 

All  other  acyclic  plasticizers^ 


1,000 
pounds 


85,132 

31,348 

320 

4,843 

6,455 

11,564 


2,404 
3,057 


1,670 
4,433 


4,483 

3,520 

218 

13.556 


8,290 
5,266 


2,290 
84,895 


1,000 


1,000 
dollars 


75,028 

26,140 

306 

6,065 

5,192 

10,535 


18,236 

6,267 

129 

3,037 

1,998 

2,418 


2,501 
2,912 


1,052 
4,070 


577 
544 


248 
1,049 


3,029 

3,479 

215 


1,895 

1,971 

237 


7,732 
4,387 


2,133 
92,342 


1,995 
1,559 


717 
29,024 


Per 
pound 


1  Includes  data  for  compounds  used  principally  (but  not  exclusively)  as  primary  plasticizers.  Does  not  include 
clearly  defined  extenders  or  secondary  plasticizers. 

2  Calculated  from  rounded  figures. 

3  Includes  benzenoid  products  as  defined  in  part  1  of  schedule  4  of  the  Tariff  Schedules  of  the  United  States 
Annotated. 

■■  Includes  data  for  alkylated  naphthalene,  glycol  dibenzoates,  hydrogenated  terphenyls,  isopropylidenediphenoxy 
propanol,  all  other  phosphoric  acid  esters  (sales  only),  toluenesulfonamides,  tetrahydrofurfuryl  oleate,  and  other 
cyclic  plasticizers. 

5  Adipic  acid  polyesters  account  for  most  of  the  production  of  complex  linear  polyesters  and  polymeric  plasticizers. 

6  Includes  data  for  azelaic,  citric  and  acetylcitric,  lauric,  myristic,  palmitic,  pelargonic,  ricinoleic,  and  sebacic 
acid  esters,  glyceryl  and  glycol  esters,  and  other  acyclic  plasticizers,  not  separately  shown. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972  ■ 
TABLE  2.— Plasticizers  for  which  U.S.  production  or  sales  were  reported,   identified  by 

MANUFACTURER,  1972 

[Plasticizers  for  which  separate  statistics  are  given  in  table  1  are  marked  below  with  an  asterisk  (*) ;  products  not 
so  marked  do  not  appear  in  table  1  because  the  reported  data  are  accepted  in  confidence  and  may  not  be  published. 
Manufacturers 's  identification  codes  shown  below  are  taken  from  table  3.   An  x  signifies  that  the  manufacturer  did 
not  consent  to  his  identification  with  the  designated  product] 


Manufacturers'  identification  code 
(according  to  list  in  table  3) 


PLASTICIZERS,  CYCLIC 

Coumarone-indene  plasticizers 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl  sebacate 

Diethylene  glycol  dibenzoate 

Di-tert-octylphenyl  ether 

Dipropanediol  dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Isopropylidenediphenoxypropanol 

Naphthalene,  alkylated 

'Phosphoric  acid  esters: 

'Cresyl  diphenyl  phosphate 

Dibutyl  phenyl  phosphate 

Diphenyl  octyl  phosphate 

Methyl  diphenyl  phosphate 

*Tri cresyl  phosphate 

Tri phenyl  phosphate 

*Phthalic  anhydride  esters: 

Alkyl  benzyl  phthalates 

Butyl  benzyl  phthalate 

Butyl  cyclohexyl  phthalate 

•Butyl  octyl  phthalates: 

Butyl  2-ethylhexyl  phthalate 

Butyl  n-octyl  phthalate 

Di(2-butoxyethyl)  phthalate 

*Dibutyl  phthalate 

Dicyclohexyl  isodecyl  phthalate 

Di cyclohexyl  phthalate 

Diethyl  isophthalate 

♦Diethyl  phthalate 

Dihexyl  phthalate 

*Di isodecyl  phthalate 

Di-iso-hexyl  phthalate 

Diisononyl  phthalate 

Di(2-methoxyethyl)  phthalate 

Dimethyl  isophthalate 

"Dimethyl  phthalate 

Dinonyl  phthalate 

Dioctyl  phthalates: 

Dicapryl  phthalate 

Di (2-ethylhexyl)  isophthalate 

*Di (2-ethylhexyl)  phthalate 

*Diiso-octyl  phthalate 

Di- n-octyl  phthalate 

Mixed  dioctyl  phthalates 

Diphenyl  phthalate 

*ni-tridecyl  phthalate 

2- (Ethylhexyl)isobutyl  phthalate 

Glycol  phthalate  esters: 

Butyl  phthalyl  butyl  glycolate 

Ethyl  (and  methyl)  phthalyl  ethyl  glycolate- 

Polypropylene  glycol  bis(amyl)  phthalate 

All  other  glycol  phthalate  esters 


NEV. 

MON. 

WTH. 

VEL. 

DOIV. 

VEL. 

MON. 

DOW. 

ACC. 

FMP, 

MON,  MTR 

SFS 

MON, 

ORO. 

MON. 

FMP, 

MON. 

FMP, 

MON,  MTR 

SFS 

EK, 

MON,  SFS. 

MON. 

MON. 

ACS, 

CPS. 

ACP, 

GRH,  MON 

TEK 

UCC 

RCI, 

USS. 

ARC, 

FMP. 

.(^CP, 

COM,  EKT 

GRH 

HAL 

MON,  RCI,  RUB,  SW, 

UCC, 

USS 

WTC. 

GRH. 

FMP, 

MON,  PFZ 

PFZ. 

EKT, 

KF,  MON, 

PFZ. 

USS. 

ACP, 

CO,  EKT, 

ENJ, 

GRH, 

MON,  RCI,  TEK,  UCC, 

USS, 

WTC 

ENJ. 

ENJ, 

PFZ. 

EKT, 

FMP,  SFS 

PFZ. 

EKT, 

KF,  MON, 

TCC. 

RCI. 

WTH. 

UCC. 

ACP,  BFG,  CO,  EKT,  ENJ,  GRH,  MON,  PFZ,  RCI,  RUB,  TEK, 

UCC,  USS,  WTC. 
ACP,  ENJ,  GRH,  MON,  RCI,  TEK,  UCC,  USS. 
EK. 
TEK. 
MON. 

ACP,  CO,  ENJ,  GRH,  MON,  RCI,  RUB,  TEK,  UCC,  USS. 
GRH. 

MON . 
MON. 
UCC. 
HPC,  WTC. 


PLASTICIZERS 
TABLE  2,~Plasticizers  for  which  U,S,  production  or  sales  were  reported,   identified  by 

MANUFACTURER,  1972~CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3] 


PLASTICIZERS,  CYCLIC--Continued 

*Phthalic  anhydride  esters--Continued 

*n-Hexyl  n-decyl  phthalate 

Hexyl  isodecyl  phthalate 

Isodecyl  tridecyl  phthalate 

Iso-octyl  isodecyl  phthalate 

n-Octyl  n-decyl  phthalate 

All  other  phthalic  anhydride  esters 

Polyethylene  glycol  dibenzoate 

Tetrahydrofurfuryl  oleate 

Toluenesulfonainide  o- ,  p-  mixtures 

*Trimellitic  acid  esters: 

Tri(2-ethylhexyl3  trimellitate 

Tri-n-hexyl  trimellitate 

Tri isodecyl  trimellitate 

Triisononyl  trimellitate 

*Tri iso-octyl  trimellitate 

*Tri-n-octyl  n-decyl  trimellitate 

*Trioctyl  trimellitate 

All  other  trimellitic  acid  esters 

Trimethylpentanediol  dibenzoate 

All  other  cyclic  plasticizers 

PLASTICIZERS,  ACYCLIC 

*Adipic  acid  esters: 

''Di[2-(butoxyethoxyJethyl]  adipate 

*Di(2-ethylhexyl)  adipate 

Diisobutyl  adipate 

*Di isodecyl  adipate 

Diisononyl  adipate 

Diisopropyl  adipate 

•Dioctyl  adipates: 

Diiso-octyl  adipate 

Di-n-octyl  adipate 

Di- tridecyl  adipate 

*n-Hexyl  n-decyl  adipate 

Iso-octyl  isodecyl  adipate 

*n-Octyl  n-decyl  adipate 

All  other  adipic  acid  esters 

Azelaic  acid  esters: 

*Di (2-ethylhexyl)  azelate 

Diisobutyl  azelate 

Diiso-octyl  azelate 

All  other  azelaic  acid  esters 

1 ,4-Butanediol  dicaprylate 

But oxy ethyl  pelargonate 

Castor  oil  maleate 

Citric  and  acetylcitric  acid  esters 

•Complex  linear  polyesters  and  polymeric  plasticizers- 

Di[(butoxyethoxy)ethoxy] methane 

Dibutyl  tartrate 

Diethylene  glycol  dipelargonate  (Dinonanoate) 

Diiso-octyl  dig lyco late 


ACP,  CO,  ENJ,  TEK,  UCC . 

GRH. 

TEK. 

ACP,  GRH. 

ACP,  CO,  GRH,  MON,  RCl,  TEK,  UCC,  USS. 

ACP,  FMP,  PF2,  RUB,  TEK,  UCC,  USS. 

VEL. 

EMR. 

ACY,  LAK,  MON. 

GRH,  PFZ,  RCI. 

CO,  RUB. 

PFZ. 

ENJ. 

ENJ,  GRH,  RCI,  RUB,  TEK,  USS. 

GRH,  PFZ,  RCI,  RUB,  TEK,  USS. 

CO,  RUB,  TEK,  USS. 

X. 

VEL. 

MON,  NEV,  SFS. 


FMP,  RCI,  TKL,  WTH. 

CO,  DA,  EKT,  ENJ,  GRH,  MON,  PFZ,  RCI,  RH,  RUB,  TEK,  UCC, 

USS. 
GRH,  HAL. 

ACP,  ENJ,  GRH,  MON,  PFZ,  RCI,  RH,  RUB,  UCC,  USS. 
ENJ,  RUB. 
SBC,  VND. 


GRH, 

RH, 

RUB, 

USS. 

ACP. 

GRH. 

GRH, 

TEK 

USS 

GRH, 

PFZ 

ACP. 

CO, 

GRH, 

MON, 

RCI, 

RH,  USS 

ARC, 

EK, 

GRH, 

PFZ, 

UCC, 

WTH. 

EKT, 

EMR 

PFZ 

RCI 

UCC 

HAL. 

EMR, 

PFZ 

EMR. 

RUB. 

HAL. 

RH. 

GLY, 

PFZ 

ASH, 

EKT 

EMR 

GRH 

HAL 

MON,  P 

TKL. 

ARC. 

EMR. 

CCA. 

552-743  0-74-11 


SYNTHETIC  ORGANIC  CHEMICALS,  1972' 

table  2.--plastic1zers  for  which  u.s.  production  or  sales  were  reported,  identified  by 
Manufacturer,  1972— Continued 


Manuf actuiers '  identification  codes 
(according  to  list  in  table  3) 


PLASTICIZERS,  ACYCLIC--Continued 

Epoxidized  esters: 

Butyl  epoxytallate 

Epoxidized  linseed  oils 

*Epoxidized  soya  oils 

Epoxidized  tall  oils 

*2-Ethylhexyl  epoxytallates 

Octyl  epoxystearates 

*Octyl  epoxytallates 

All  other  epoxidized  esters 

Glyceryl  tributyrate  and  tripropionate 

Glycol  pelargonate 

Isodecyl  nonanoate  (Isodecyl  pelargonate) 

Myristic  acid  esters:   *Isopropyl  myristate 

*01eic  acid  esters: 

2-Butoxyethyl  oleate 

•Butyl  oleate 

Decyl  oleate 

Glyceryl  trioleate  (Triolein) 

Isobutyl  oleate 

*Isopropyl  oleate 

*Methyl  oleate 

♦Propyl  oleate 

Palmitic  acid  esters; 

2-Ethylhexyl  palmitate 

Isobutyl  palmitate 

Iso-octyl  palmitate 

*lsopropyl  palmitate 

*Phosphoric  acid  esters: 

Tri(2-butoxyethyl)  phosphate 

Tri (2 - ch loroethy 1 )  phosphate 

Tri (2-chloropropyl)  phosphate 

Triethyl  phosphate 

Trioctyl  phosphate 

All  other  phosphoric  acid  esters 

Ricinoleic  and  acetylricinoleic  acid  esters: 

n- Butyl  acetylricinoleate 

Butyl  ricinoleate r 

•Glyceryl  monoricinoleate 

Glyceryl  tri (acetyl ricinoleate) 

Methyl  ricinoleate 

All  other  ricinoleic  and  acetylricinoleic  acid  esters- 
*Sebacic  acid  esters: 

Dibutoxyethyl  sebacate 

•Dibutyl  sebacate 

*Di(2-ethylhexyl)  sebacate 

Di iso-octyl  sebacate 

•Stearic  acid  esters: 

Butoxyethyl  stearate 

•n- Butyl  stearate 

Dimethyl  ammonium  stearate 

Dodecyl  (lauryl)  stearate 

2-Ethylhexyl  stearate 

Glyceryl  triacetyl  stearate 

Hexadecyl  stearate 

2-Hydroxypropyl  stearate 

Isobutyl  stearate 


ASH. 

ASH  . 

ASH, 

RH. 

ASH, 

WTC. 

RH, 

EMR, 

EKT. 

EMR. 

EMR. 

ARC, 


FMP,  NIL,  RH,  UCC,  WRC,  WTC. 
NTL,  UCC. 


TEK,  UCC,  WTC. 
RH. 


SBC,  TCH,  WM,  WTH. 


ARC,  HAL. 

ARC,  EMR,  HAL,  WM,  WTC,  WTH. 

VND. 

EMR,  GLY,  WM. 

DA. 


EMR, 

WM. 

CHL, 

DA, 

EMR, 

HUM. 

CHL, 

EMR 

WM. 

WTH. 

ARC, 

DA. 

RUB. 

ARC, 

SBC 

TCH 

WM, 

WTH. 

FMP. 

SFS 

UCC 

SFS. 

EKT. 

UCC 

SFS, 

SM 

NTL. 

NTL. 

RCI 

DA, 

GLY, 

HAL, 

NTL. 

NTL 

NTL 

NTL. 

HAL 

RCI 

EKT 

GRH 

RCI 

RH, 

USS,  WTH 

GRH 

PFZ 

RCI 

RH, 

WTH. 

DA, 

RCI. 

ARC,  ASH,  CHL,  DA,  EMR,  GRO,  RUB,  SCP,  TCH,  WM,  WTH. 

RH. 

RCI. 

FMP,  SCP. 

NTL. 

SCP. 

WTH. 

ARC,  DA,  WM. 


PLASTICIZERS 
TABLE  2,— Plasticizers  for  which  U.S.  production  or  sales  were  reported,   identified  by 

MANUFACTURER,  1972--CoNTINUED 


Chemical 

Manufacturers'  identification  codes 
(according  to  list  in  table  3} 

PLASTICIZERS,  ACYCLIC--Continued 
♦Stearic  acid  esters--Continued 

HK. 

HK. 

CHL. 

ARC.  DA,  HPC,  TCH,  WM. 

ARC,  EKT. 

UCC. 

RUB. 

HAL,  PVO,  RUB,  WM. 

UCC. 

UCC. 

RUB. 

EKX. 

EMR,  HAL,  HPC,  SCP,  SM,  WTH. 

th  1   r 

An  ^th^  eara  e 

S         t  r   '   h  t   t 

< 

Triethylene  glycol  dicaprylate 

T  ^  th^i^"^  &   y^o       ,^  J^^''^?'  .ft^t'^^^t^l^ 

Triethylene  glycol  di (2-ethylhexanoate) 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3.--PLASTICIZERS;     Directory  of  manufacturers^  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 

[Names  of  plasticizers  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission  for  1972  are 
listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ACC 

Amoco  Chemicals  Corp. 

NEV 

Neville  Chemical  Co. 

ACP 

Allied  Chemical  Corp.,  Plastics  Div. 

NTL 

NL  Industries,  Inc. 

ACY 

American  Cyanamid  Co. 

ARC 

Armak  Co . 

ORO 

Chevron  Chemical  Co. 

ASH 

Ashland  Oil,  Inc.,  Ashland  Chemical  Co.  Div. 

PFZ 

Pfizer,  Inc. 

BFG 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical 
Co.  Div. 

PVO 

PVO  International,  Inc. 

RCI 

Reichhold  Chemicals,  Inc. 

CCA 

Cincinnati  Milacron  Chemicals,  Inc. 

RH 

Rohm  &  Haas  Co. 

CHL 

■  Chemol ,  Inc. 

RUB 

Hooker  Chemical  Corp.  ,  Ruco  Div. 

CO 

Continental  Oil  Co. 

COM 

Commercial  Solvents  Corp. 

SBC 

Scher  Brothers,  Inc. 

CPS 

CPS  Chemical  Co. 

SCP 

Henkel,  Inc. 

SFS 

Stauffer  Chemical  Co.,  Specialty  Chemical 

DA 

Diamond  Shamrock  Corp. 

Div. 

DOW 

Dow  Chemical  Co. 

SM 

Mobil  Oil  Corp.,  Mobil  Chemical  Co.  Div., 
Industrial  Chemical  Div. 

EK 

Eastman  Kodak  Co. : 

SW 

Sherwin-Williams  Co. 

EKT 

Tennessee  Eastman  Co.  Div. 

EKX 

Texas  Eastman  Co.  Div. 

TCC 

Tanatex  Chemical  Corp. 

EMR 

Emery  Industries,  Inc. 

TCH 

Emory  Industries,  Inc.,  Trylon  Chemicals  Div. 

ENJ 

Enjay  Chemical  Co. 

TEK 

Teknor  Apex  Co. 

TKL 

Thiokol  Chemical  Corp. 

FMP 

FMC  Corp.,  Organic  Chemicals  Div. 

UCC 

Union  Carbide  Corp. 

GLY 

Glyco  Chemicals,  Inc. 

USS 

USS  Chemicals  Div.  of  U.S.  Steel  Corp. 

GRH 

W.R.  Grace  S  Co.,  Hatco  Chemical  Div. 

GRO 

Millmaster  Onyx  Corp.,  A.  Gross  §  Co.,  Div. 

VEL 

Velsicol  Chemical  Corp. 

VND 

Van  Dyk  6  Co . ,  Inc. 

HAL 

C.  P.  Hall  Co.  of  Illinois 

HK 

Hooker  Chemical  Corp. 

WM 

Wilson  Pharmaceutical  ti  Chemical  Corp., 

HPC 

Hercules,  Inc. 

Wilson-Martin  Div. 

HUM 

Kraftco  Corp.,  Humko  Plastics  Div. 

WRC 

Ventron  Corp.,  Wood  Ridge  Chemical 

WTC 

Witco  Chemical  Co.,  Inc. 

KF 

Kay-Fries  Chemicals,  Inc. 

WTH 

Union  Camp  Corp.,  Harchem  Div. 

LAK 

Lakeway  Chemicals,  Inc. 

MON 

Monsanto  Co. 

MTR 

Sobin  Chemicals,  Inc.,  Montrose  Chemical  Div. 

Not 

5. --Complete  names  and  addresses  of  the  above  report 

ing  comn 

inies  are  listed  in  Table  1  of  the  Aonendix. 

161 


SURFACE-ACTIVE  AGENTS 


The  surface-active  agents   included  in  this   report  are  organic  chemicals 
that  reduce  the  surface  tension  of  water  or  other  solvents   and  are  used 
chiefly  as   detergents,    dispersing  agents,   emulsifiers,    foaming  agents,   or 
wetting  agents   in  either  aqueous   or  nonaqueous   systems.      Waxes   and  products 
used  chiefly  as  plasticizers   are  excluded.      Surface- active   agents    are  pro- 
duced from  natural   fats   and  oils;    from  si Ivi chemicals  such  as   lignin,    rosin, 
and  tall   oil;    and  from  chemical  intermediates   derived  from  coal   tar  and 
petroleum.      A  major  part  of  the   output  of  the  bulk  chemicals   shown  in  this 
report  is   consumed  in   the  form  of  packaged  soaps   and  detergents   for  house- 
hold and  industrial   use.      The  remainder  is  used  in  the  processing  of  textiles 
and  leather,    in  ore  flotation  and  oil-drilling  operations,    and  in  the  manu- 
facture of  agricultural  sprays,    cosmetics,    elastomers,    foods,    lubricants, 
paints,   pharmaceuticals,    and  many  other  products. 

Table   1  shows   statistics   for  production  and  sales   of  surface-active 
agents   grouped  by  ionic  class   and  by  chemical   class   and  subclass;   table 
2   lists   these  products    and  identifies   the  manufacturers.^     All  quantities 
are  reported  in   terms  of  100-percent   organic  surface-active   ingredient 
and  thus   exclude   all   inorganic  salts,   water,    and  other  diluents.      Sales 
statistics   reflect  sales  of  bulk  surface-active  agents  only;   sales  of 
formulated  products   are  excluded. 

Total  U.S.    production  of  surface-active  agents   in   1972   amounted  to 
4";039  million  pounds,    or  5.5  percent  greater  than   the  3,828  million  pounds 
reported  for   1971.      Sales   of  bulk  surface-active  agents   in   1972   amounted 
to  2,258  million  pounds,   valued  at  $451  million,    compared  with  sales   in 
1971   of  2,186  million  pounds,   valued  at  $422  million.      In  terms   of  quantity, 
sales   in  1972  were   thus    3.3  percent   larger  than  in   1971;    in  terms   of  value, 
sales   in   1972  were  6.7  percent   larger  than  in   1971. 

Production  of  anionic  surface-active  agents   in  1972   amounted  to  2,747 
million  pounds,    or  68.0  percent  of  the  total  output  reported  for  1972   and 
5.9  percent  greater  than  the   anionic  output  reported  for  1971.      Sales  of 
anionics   in   1972   amounted  to  1,274  million  pounds,   valued  at  $195  million. 
Of  the  total   anionic  output,    894  million  pounds   consisted  of  potassium  and 
sodium  salts   of  fatty,    rosin,    and  tall   oil   acids,   of  which  466  million 
pounds  was   the  sodium  salt  of  tallow  acids   and  131  million  pounds  was   the 
sodium  salt  of  coconut   oil   acids;    688  million  pounds   consisted  of  alkyl- 
benzenesulfonates,   of  which   364  million  pounds  was   sodium  dodecylbenzene- 
sulfonate,    143  million  pounds  was   dodecylbenzenesulfonic  acid,    and   150 
million  pounds  was   sodium  tridecylbenzenesulfonate;    522  million  pounds 
consisted  of  ligninsulfonates,   of  which  327  million  pounds  was  the  calcium 
salt;    and  207  million  pounds   consisted  of  sulfated  ethers. 

Production  of  nonionic  surface-active  agents   in   1972   amounted  to   1,048 
million  pounds,   or  26.0  percent  of  the  total   output  reported  for  1972  and 


See  table   3  for  a  list  of  manufacturers   and  their  codes. 


162 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 


2.7  percent  more  than  the  nonionic  output  reported  for  1971.   Sales  of 
nonionics  in  1972  amounted  to  787  million  pounds,  valued  at  $174  million. 
Of  the  total  nonionic  output,  314  million  pounds  consisted  of  alkylphenol 
ethoxylates  and  other  benzenoid  ethers,  of  which  178  million  pounds  was 
nonylphenol  ethoxylate;  423  million  pounds  consisted  of  alcohol  ethoxylates 
and  other  nonbenzenoid  ethers,  of  which  324  million  pounds  was  mixed  linear 
alcohol  ethoxylate;  102  million  pounds  consisted  of  glycerol  esters;  and 
88  million  pounds  consisted  of  alkanol amides. 

Production  of  cationic  surface-active  agents  in  1972  amounted  to  229 
million  pounds,  or  5.7  percent  of  the  total  output  reported  for  1972  and 
12.9  percent  greater  than  the  cationic  output  reported  for  1971.   Sales  of 
cationics  in  1972  amounted  to  183  million  pounds,  valued  at  $72  million. 
Of  the  total  cationic  output,  60  million  pounds  consisted  of  quaternary 
ammonium  salts  not  containing  oxygen,  and  68  million  pounds  consisted  of 
amines  not  containing  oxygen. 

Production  of  amphoteric  surface- active  agents  in  1972  amounted  to 
14.4  million  pounds,  or  0.4  percent  of  the  total  output  reported  for  1972 
and  45.8  percent  greater  than  the  amphoteric  output  reported  for  1971.   Sales 
of  amphoterics  in  1972  amounted  to  14.1  million  pounds,  valued  at  $9.4 
million. 

The  difference  between  production  and  sales  reflects  inventory  changes 
and  captive  consumption  of  soaps  and  surface- active  agents  by  synthetic 
rubber  producers,  and  by  manufacturers  of  cosmetics,  packaged  detergents, 
bar  soaps,  and  other  formulated  consumer  products.   In  some  instances  the 
difference  may  also  reflect  quantities  of  surface- active  agents  used  as 
chemical  intermediates,  e.g.,  nonionic  alcohol  and  alkylphenol  ethoxylates 
which  may  be  converted  to  anionic  surface- active  agents  by  phosphation  or 
sulfation. 


SURFACE-ACTIVE  AGENTS 
TABLE  1,— Surface-active  agents:     U.S.  production  and  sales.  1972 


[Listed  below  are  all  surface-active  agents  for  which  reported  data  on  production  or  sales  may  be  published.   (Leaders 

(...3  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no  data  were 

reported.)  Table  2  lists  all  surface-active  agents  for  which  data  on  production  or  sales  were  reported  and  identi- 
fies the  manufacturers  of  each] 


Production 


Sales^ 


Quantity' 


Grand  total 

Benzenoid  

Nonbenzenoid  

Amphoteina  Surface-Active  Agents 

Total 

Anionic  Surface-Active  Agents 

Total 

Carboxylic  acids  (and  salts  thereof),  total 

Amine  salts  of  fatty  rosin,  and  tall  oil  acids 

Carboxylic  acids  having  amide,  ester,  or  ether  linkages 

total 

N-Lauroylsarcosine,  sodium  salt 

All  other 

Potassium  and  sodium  salts  of  fatty,  rosin,  and  tall 

acids,  total 

Castor  oil  acids,  potassium  salt 

Coconut  oil  acids,  potassium  and  sodium  salts,  total- 
Potassium  salt 

Sodium  salt 

Corn  oil  acids,  potassium  and  sodium  salts 

Mixed  vegetable  oil  acids,  potassium  salt 

Oleic  acid,  sodium  salt 

Palm  oil  acids,  sodium  salt 

Soybean  oil  acids,  potassium  and  sodium  salts 

Stearic  acid,  potassium  and  sodium  salts 

Tall  oil  acids,  potassium  salt 

Tall  oil  acids,  sodium  salt 

Tallow  acids,  sodium  salt 

All  other 

Phosphoric  and  polynhosphoric  acid  esters  (and  salts 

thereof^i  total  

Alcohols  ana  phenols,  ethoxylated  and  phosphated,  total 

Dinonylphenol,  ethoxylated  and  phosphated 

Mixed  linear  alcohols,  ethoxylated  and  phosphated 

Nonylphenol,  ethoxylated  and  phospnated 

Phenol,  ethoxylated  and  phosphated 

Tridecyl  alcohol,  ethoxylated  and  phosphated 

All  other 

Alcohols,  phosphated  or  polyphosphated,  total 

2-Ethylhexyl  phosphate,  sodium  salt 

All  other 

Sulfonic  acids  (and  salts  thereof),  total 

Alkylbenzenesulfonates,  total 

Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  isopropylamine  salt 


1,000 
pounds 


1,119,229 
2,919,558 


907,011 


12,711 
3,823 


142,944 

11,825 

131,119 

801 

2,814 

1,473 

714 

982 

19,543 

10,720 

465,550 

247,988 


26.514 


18,028 

759 

3,602 

7,410 

728 

1,412 

4,117 

8,486 

447 

8,039 


688,176 

143,391 

12,412 

2,221 


1,000 
pounds 


2.257.546 


1,000 
dollars 


4S0.768 


547,259 
1,710,287 


444 
9,300 
9,300 

48 


787 
2,841 

229 
643 
528 

16,782 
2,561 

10,258 


3,434 
6,101 

1,094 
4,197 
6,204 

6,204 

774,160 


174,613 

50,823 

9,500 

5,425 


111,093 
339,675 


148 
6,213 
6,213 

10 


287 
2,576 

37 
131 
162 

3,779 
348 

1,263 


9,509 


1,520 
1,923 

428 
2,319 
3,319 

3,319 

78,386 


32,317 
7,100 
4,098 
1,068 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  L— Surface-active  agents;     U.S,  production  and  sales^  1972--Continued 


Production  ' 


Sales'^ 


Quantity 


Anionic  Surface-Aative   jJgents--Continued 

Sulfonic  acids  (and  salts  thereof ) --Continued 
A 1 ky 1 ben zenesulfonates- -Continued 

Dodecylbenzenesulfonic  acid,  (mixed  alkyl)amine 

salt 

Dodecylbenzenesulfonic  acid,  sodium  salt 

Dodecylbenzenesulfonic  acid,  triethanolamine  salt 

Tridecylbenzenesulfonic  acid,  sodium  salt 

All  other 

Benzene-,  cumene-,  toluene-,  and  xylenesulfonates , 

total 

Cumenesulfonic  acid,  ammonium  salt 

Xylenesulfonic  acid,  ammonium  salt 

Xylenesulfonic  acid,  sodium  salt 

All  other 

Ligninsulfonates,  total 

Ligninsulfonic  acid,  calcium  salt 

Ligninsulfonic  acid,  sodium  salt 

All  other 

Naphthalenesulfonates,  total 

Butylnaphthalene  sulfonic  acid,  sodium  salt 

All  other 

Sulfonic  acids  having  amide  li.ikages.  total 

Sulfosuccinic  acid  derivatives 

Taurine  derivatives 

Sulfonic  acids  having  ester  or  ether  linkages,  total 

Sulfosuccinic  acid  esters,  total 

Sulfosuccinic  acid,  bis(2,6.-dimethyl-4-heptyl) 

ester,  sodium  salt 

Sulfosuccinic  acid,  .bis (2-ethylhexyl)  ester,  sodium 

salt 

All  other 

Other  sulfonic  acids  having  ester  or  ether  linkages 

All  other  sulfonic  acids 

Sulfuric  acid  esters  (and  salts  thereof),  total 

Acids,  amides,  and  esters,  sulfated,  total 

Coconut  oil  acids  -  ethanolamine  condensate,  sulfated, 
potassium  salt 

Esters  of  sulfated  oleic  acid,  total 

Butyl  oleate,  sulfated,  sodium  salt 

Isopropyl  oleate,  sulfated,  sodium  salt 

Propyl  oleate,  sulfated,  sodium  salt 

All  other 

■;leic  acid,  sulfated,  disodium  salt 

Other  acids,  amides,  and  esters,  sulfated 

Alcohols,  sulfated,  total 

Decyl  sulfate,  sodium  salt 

Dodecyl  sulfate  salts,  total 

Dodecyl  sulfate,  ammonium  salt 

Dodecyl  sulfate,  magnesium  salt 

Dodecyl  sulfate,  sodium  salt 

Dodecyl  sulfate,  triethanolamine  salt 

All  other 

Other  alcohols   sulfated 

Ethers,  sulfated,  total 

Alkylphenols,  ethoxylated  and  sulfated,  total 

Nonylphenol,  ethoxylated  and  sulfated,  sodium  salt-- 
All  other 

Dodecyl  alcohol,  ethoxylated  and  sulfated,  ammonium 
salt 


pounds 


121 
364,067 

6,905 
149,870 

9,489 


64,009 

3,750 

4,962 

57,409 

17,908 

522.323 

526,626 

58,662 

157,055 

7,508 

501 

7,207 

4,954 
1,526 
5,428 
41,828 
16,060 

559 

12,387 
5,114 

25,768 
5,514 


5,015 

1,540 

520 

255 

2,718 

12,221 


545 

26 

841 

16 

050 

17 

552 

206 

980 

1,000 
pounds 


89,867 

7,795 


54,751 
5,714 

28,289 

22,728 

505,981 

507,655 

61,094 

137,232 

7,005 

297 

6,708 


1,132 

1,668 

23,781 

11,987 


2,757 
11,794 


18,571 

29 

4,824 

1,589 

434 

227 

2,574 

11,865 

1,855 

44,107 

192 

34,169 

2,670 

20,433 

11,066 
9,746 
125,790 
5,786 
311 
3,475 

2,657 


1,000 
dollars 


15,606 
1,725 


2,722 


5 

211 

425 

'2 

600 

2 

186 

18 

699 

7 

688 

6 

038 

4 

973 

2 

657 

1,393 
15,379 
6,935 


5,500 
1,435 
8,444 


4,379 


150 
101 


14,845 
1,551 

8,595 

4,917 
3,492 
21,404 
1,155 
71 
1,084 


See  footnotes  at  end  of  table. 


SURFACE-ACTIVE  AGENTS 
TABLE  1. --Surface-active  agents:  U.S.  production  and  sales,  1972--Continued 


Anionic  Sup  face- Active   ^^ewts- -Continued 

Sulfuric  acid  esters  (and  salts  thereof) --Continued 
Ethers,  sul f at ed--Cont inued 

Dodecyl  alcohol,  ethoxylated  and  sulfated,  sodium 

salt 

Mixed  linear  alcohols,  ethoxylated  and  sulfated, 

ammonium  salt 

Mixed  linear  alcohols,  ethoxylated  and  sulfated,  sodium 

salt 

All  other 

Natural  fats  and  oils,  sulfated,  total 

Castor  oil,  sulfated,  sodium  salt 

Coconut  oil,  sulfated,  sodium  salt 

Cod  oil,  sulfated,  sodium  salt 

Herring  oil,  sulfated,  sodium  salt 

Lard  oil,  sulfated,  sodium  salt 

Mixed  fish  oils,  sulfated,  sodium  salt 

Neat's-foot  oil,  sulfated,  sodium  salt 

Peanut  oil,  sulfated,  sodium  salt 

Ricebran  oil,  sulfated,  sodium  salt 

Soybean  oil,  sulfated,  sodium  salt 

Sperm  oil,  sulfated,  sodium  salt 

Tallow,  sulfated,  sodium  salt 

All  other 

Other  anionic  surface-active  agents^ 

Cationio  Surface-Active  Agents 

Total 

Amine  oxides  and  oxygen-containing  amines  (except  those 

having  amide  linkages),  total 

Acyclic,  total 

(Coconut  oil  alkyl)amine,  ethoxylated 

(Tallow  alkyl)amine,  ethoxylated 

All  other 

Cyclic  (except  imidazoline  and  oxazoline  derivatives) 

Imidazoline  and  oxazoline  derivatives,  total 

2-Heptadecyl-l- (2-hydroxyethyl)-2-imidazoline 

1- (2-Hydroxyethyl)-2-nor(coconut  oil  alkyl)-2- 

imidazoline 

1- (2-Hydroxyethyl)-2-nor(tall  oil  alkyl)-2-imidazoline-- 
All  other 

Amines  and  amine  oxides  having  amide  linkages,  total 

Carboxylic  acid  -  diamine  and  polyamine  condensates , total- 
Mixed  fatty  acids  -  polyalkylenepolyamine  condensate 

Tall  oil  acids  -  diethylenetriamine  and  polyalkylene 

polyamine  condensate 

All  other 

Other  amines  and  amine  oxides  having  amide  linkages 

Amines,  not  containing  oxygen  (and  salts  thereof),  total 

Amine  salts 

Diamines  and  polyamines,  total 

N- (Coconut  oil  alkyl)trimethylenediamine 

Imidazoline  derivatives 

N-  (9-0ctadecenyl)trimethylenediamine 

All  other 

Primary  monoamines,  total 

(Hydrogenated  tallow  alkyl)amine 

9-Octadecenylaraine 

Octadecylamine 

(Tallow  alkyl) amine 

All  other 


Production    i 


1,000 
pounds 


8 

965 

103 

763 

87 

358 

38 

526 

8 

271 

1 

023 

2 

028 

869 

255 

4 

256 

50,623 


45,731 
4,368 
2,191 

39,172 

1,778 

3,114 

266 

444 

791 

1,613 


22,839 
2,308 

17,764 
2,767 
4,830 

67,675 


3,112 

13,383 

430 

2,590 

2,342 

8,021 

27,910 

3,789 

4,866 

541 

5,225 

13,489 


1,000 


17.557 

93,732 

37,233 

8,311 

925 

2,001 

860 

245 

2,573 

69 

53 

141 

1,338 

10,000 

10,717 

204,887 


23,841 


19,113 
3,985 
1,913 

13,215 

1,964 

2,764 

235 

523 

337 

1,669 


22,006 


17,474 
4,532 
3,493 


2,102 
12,240 
465 
1,904 
2,243 
7,628 
27,708 
3,729 
4,113 

5,522 
14,344 


1,000 
do  I  laps 


3,068 


3,326 

13,298 

8,293 

2,654 

243 

289 

125 


1,538 
2,409 


10,229 


8,291 
1,362 

830 
6,099 

574 
1,364 

123 

269 
132 
840 


2,427 
2,640 
2,158 


782 

3,444 

220 

548 

868 

1,808 

9,742 

1,175 

1,565 

1,481 
5,521 


See  footnotes  at  end  of  table 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  1. --Surface-active  agents:  U.S.  ppoduction  and  sales,  1972--Continued 


Production 


Quantity 


Cationic  Surface-Active   /Ijents- -Continued 

Amines,  not  containing  oxygen  (and  salts  thereof)-- 
Continued 

Secondary  and  tertiary  monoamines,  total 

6is(hydrogenated  tallow  alkyljamine 

N,N-Dimethyldodecylamine 

N,N-Dimethylhexadecylamine 

N,N-Dimethyloctadecylamine 

N-Methylbis(hydrogenated  tallow  alkyljamine 

All  other 

Oxygen-containing  quaternary  ammonium  salts 

Quaternary  ammonium  salts,  not  containing  oxygen,  total 

Acyclic,  total 

Bis (coconut  oil  alkyl}dimethylammonium  chloride 

Bis (hydrogenated  tallow  alkyl)dimethylammonium  chloride-- 

Hexadecyltrime thy 1 ammonium  chloride 

Trimethyl (tallow  alkyl) ammonium  chloride 

All  other 

Benzenoid,  total 

Benzyl  (coconut  oil .alkyl)dimethylammonium  chloride 

Benzyldimethvl (mixed  alkyll ammonium  chloride 

Benzy 1 dimethyl DC tad ecyl ammonium  chloride 

Benzyl trimethyl ammonium  chloride 

All  other 

Groups   listed  above  for  which  separate  sales  data  may  not  be 
shown' 

Nonicmic  Surface-Active  Agents 

Total 

Carboxylic  acid  amides,  total 

Diethanolamine  condensates  (amine/acid  ratio=2/l),  total — 

Capric  acid 

Coconut  oil  acids 

Coconut  oil  and  tallow  acids 

Laurie  acid 

Oleic  acid 

Stearic  acid 

Tall  oil  acids 

All  other 

Diethanolamine  condensates  (other  amine/acid  ratios), 

total 

Coconut  oil  acids  (amine/acid  ratio=l/l) 

Laurie  acid  (amine/acid  ratio=l/l) 

Oleic  acid  (amine/acid  ratio=l/l) 

Stearic  acid  (amine/acid  ratio=l/l) 

All  other 

Ethanolamine  and  isopropanolamine  condensates,  total 

Coconut  oil  acids  -  ethanolamine  condensate 

(amine/acid  ratio=2/l) 

Coconut  oil  acids  -  ethanolamine  condensate 

(amine/acid  ratio=l/l) 

All  other 

Carboxylic  acid  esters,  total 

Anhydrosorbitol  esters,  total 

Anhydrosorbitol  monoester  of  tall  oil  acids 

Anhydrosorbitol  monolaurate 

Anhydrosorbitol  monopa Imitate 

Anhydrosorbitol  monostearate 

All  other 


1,000 
pounds 


21, no 

586 

552 

1,513 

2,233 

18,386 

23,233 

59,876 


1,000 


45,451 

3,273 

31,383 

904 

866 

9,025 

14,425 

434 

6,068 

1,580 

6,343 


26,477 

84 

15,361 

3,029 

2,020 

932 

827 

413 

3,811 


11,359 

11,737 


24,667 
231 
5,926 
2,042 
7,946 
8,522 


454 

477 

588 

1,291 

2,150 


51,953 


39,708 

2,956 

28,322 

874 

780 

6,776 

12,245 

409 

6,098 

239 
5,499 


60,044 


21,043 

147 

13,643 

2,258 

417 

724 

781 

73 

3,000 


1,122 


3,298 
5,167 


193.630 


15,761 
149 
3,512 
1,536 
4,011 
6,553 


1,000 
do  I lars 


112 
288 
332 
639 
598 


23,962 


14,039 

1,204 

7,004 

685 

409 

4,737 

9,923 

274 

5,233 


17,686 


6,444 

57 

4,206 

494 

160 

227 

359 

22 

919 


36,676 

29,414 

8,470 

21,462 

19,131 

4,786 

10,344 

424 

315 

96 

540 

3,906 

9,968 

3,588 

24,564 

9,587 

2,772 

5,538 
41 
1,335 
480 
1,332 
2,350 


SURFACE-ACTIVE  AGENTS 
TABLE  1.— Surface-active  agents:  U.S.  production  and  sales.  19/2— Continued 


Quantity  ' 


1,000 


Nonionia  Surface-Active  Agents --Continuei 

Carboxylic  acid  esters--Continued 

Diethylene  glycol  esters,  total 

Diethylene  glycol  distearate 

Diethylene  glycol  monolaurate 

Diethylene  glycol  monostearate 

Diethylene  glycol  sesqullaurate 

All  other 

Ethoxylated  anhydrosorbitol  esters,  total 

Ethoxylated  anhydrosorbitol  mono-oleate 

Ethoxylated  anhydrosorbitol  monostearate 

Ethoxylated  anhydrosorbitol  tristearate 

All  other 

Ethylene  glycol  esters 

Glyceral  esters,  total 

Complex  glycerol  esters 

Glycerol  esters  of  chemically  defined  acids,  total 

Glycerol  monolaurate 

Glycerol  mono-oleate 

Glycerol  monoricinoleate 

Glycerol  monostearate 

All  other 

Glycerol  esters  of  mixed  acids,  total 

Glycerol  monoester  of  hydrogenated  cottonseed  oil 

aeids 

Glycerol  monoester  of  hydrogenated  soybean  oil  acids- 
All  other 

Natural  fats  and  oils,  alkoxylated,  total 

Castor  oil,  ethoxylated 

Hydrogenated  castor  oil,  ethoxylated 

All  other 

Polyethylene  glycol  esters,  total 

Polyethylene  glycol  esters  of  chemically  defined  acids, 

total 

Polyethylene  glycol  dilaurate 

Polyethylene  glycol  dioleate 

Polyethylene  glycol  monolaurate 

Polyethylene  glycol  mono-oleate 

Polyethylene  glycol  monostearate 

All  other 

Polyethylene  glycol  esters  of  rosin  and  tall  oil  acids- 
Polyethylene  glycol  esters  of  other  mixed  acids,  total- 
Polyethylene  glycol  sesquiester  of  coconut  oil  acids- 
All  other 

Polyglycerol  esters 

Propanediol  esters,  total 

1 , 2- Propanediol  monostearate 

All  other 

Other  carboxylic  acid  esters  

Ethers,  total 

Benzenoid  ethers,  total 

Alkylphenol  -  formaldehyde  condensates,  alkoxylated 

Dodecylphenol,  ethoxylated 

Nonylphenol,  ethoxylated 

All  other 

Nonbenzenoid  ethers,  total 

Linear  alcohols,  alkoxylated,  total 

Decyl  alcohol,  ethoxylated 

Dodecyl  alcohol,  ethoxylated 

Hexadecyl  alcohol,  ethoxylated 

Mixed  linear  alcohols,  ethoxylated 

Mixed  linear  alcohols,  ethoxylated  and  propoxylated-- 

9-Octadecenyl  alcohol,  ethoxylated 

Octadecyl  alcohol,  ethoxylated 

All  other 


2.098 

452 

52 

450 

354 

790 

25,075 

7,023 

5,436 

2,536 

10,080 

4,786 

102,320 

6,376 

31,410 

60 

2,768 

83 

27,191 

1,308 

64,534 

4,176 

13,126 

47,232 

11,258 

5,668 

3,736 

1,854 

31,502 

23,435 
1,159 
4,402 
3,838 
3,630 
5,345 
5,061 
6,521 
1,546 
395 
1,151 
4,891 
3,573 
2,593 
980 

13,427 

736,911 


313,851 

9,429 

17,352 

177,897 

109,173 

423,060 

358,196 

1,293 

9,175 

1,152 

323,725 

14,687 

2,899 

1,336 

3,929 


1,000 
pounds 


2,002 

421 

54 

409 

347 

771 

21,367 

6,502 

4,609 

10,256 

4,610 

100,498 

5,312 

33,956 

52 

2,355 

75 

29,962 

1,512 

61,230 


14,174 
47,056 
10,169 
4,967 
3,508 
1,694 
23,320 

17,385 
944 
1,196 
3,475 
3,199 
4,680 
3,891 
4,505 
1,430 
414 
1,016 

1,909 

1,481 

428 

13,994 

533.185 


272,514 
3,032 

17,223 
163,099 

89,160 
260,671 
210,442 

7,722 

664 

183,363 

11,779 

2,485 

372 

4,057 


1,000 
dollar's 


653 

126 

19 

128 

110 

270 

8,143 

2,422 

1,856 

3,865 

1,296 

25,437 

1,846 

6,823 

22 

768 

44 

5,295 

694 

16,768 


4,124 
12,644 
2,908 
1,607 
835 
466 
8,231 

6,624 

336 

401 

1,257 

1,110 

1,990 

1,530 

1,122 

485 

179 

306 

678 

554 

124 

4,014 


99.823 
47,649 

722 
2,491 
24,857 
19,579 
52.174 
36,528 

1,667 

298 

28.451 

2,459 

1,661 
256 

1,736 


SYNTHETIC  ORGANIC  CHEMICALS-  1972  ■ 
TABLE  1, --Surface-active  agents:  U,S,  production  and  sales.  1972 --Continued 


1,600 
dollars 


15,646 

974 


Unit 
value' 


Per 
povnd 


Nonionio  Surface-Active  Agents --Continued 

Ethers - -Cont  inued 

Nonbenzenoid  ethers — Continued 

Other  ethers  and  thioethers,  total 

Tridecyl  alcohol,  ethoxylated 

Trimethylnonyl  alcohol,  ethoxylated 

All  other' 


1,000 
pounds 


64,864 
4,501 
2,145 


1,000 
pounds 


50,229 
3,569 


$0.31 
.27 


1  All  quantities  are  given  in  terms  of  100  percent  organic  surface-active  ingredient. 

2  Sales  include  products  sold  as  bulk  surface-active  agents  only. 

3  Calculated  from  rounded  figures. 

''  The  term  "benzenoid,"  used  in  this  report,  describes  any  surface-aciive  agent,  except  lignin  derivatives,  whose 
molecular  structure  includes  1  or  more  6-membered  carbocyclic  or  heterocyclic  rings  with  conjugated  double  bonds 
(e.g.,  the  benzene  ring  or  the  pyridine  ring). 

^  Includes  ligninsulfonates. 

^  Includes  production  of  ''all  other"  sulfated  alcohols;  also  includes  sales  of  "all  other"  potassium  and  sodiiun  salts 
of  fatty,  rosin,  and  tall  oil  acids. 

'  Includes  "all  other"  secondary  and  tertiary  monoamines  not  containing  oxygen  (and  salts  thereof)  and  all  oxygen-con- 
taining quaternary  ammonium  salts. 

^  Includes  ethoxylated  sorbitol  esters  and  miscellaneous  esters 

'  Includes  "other"  nonionic  surface-active  agents. 


SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED  BY  MANUFACTURER,  1972 

[Surface-active   agents    for  which   separate   statistics   are   given   in   table   1    are  marked  with   an   asterisk  (*) ;   products 

not  so  marked  do  not   appear  in  table   1  because   the  reported  data  are   accepted  in  confidence  and  may  not  be 

published.     Manufacturers'    identification   codes   shouTi  belov;   are  taken  from  table  3.     An  x  signifies  that  the 
manufacturer  did  not    consent   to  his    identification  with   the  designated  product] 


Manufacturers'    identification   codes 
(according  to  list   in  table   31 


Amphoteric  Surfaae-Aative  Agents 

Acyclic: 

Alkylbetaine 

Cl-Carboxyheptadecyl) trimethylammonium  hydroxide , 

inner  salt. 
CCarboxymethyl) [3- (coconut   oil   araido)propyl]dimethyl- 

ammonium  chloride,   ammonium  salt. 
(Carboxymethyl) [3- (coconut   oil   amido)propyl]di- 

me thy 1 ammonium  chloride,   sodium  salt. 
(Carboxymethyl)  [3- (coconut   oil    amido)r)ropyl]dimethyl- 

ammonium  hydroxide,   inner  salt. 
(l-Carboxyundecyl)trimethylammonium  hydroxide,   inner 

salt. 

N-(Coconut  oil  alkyl)-6-alanine,  sodium  salt 

N-(Coconut  oil  alkyl)-6-alanine ,  partial  sodium  salt-- 
3-[ (Coconut  oil  alkyl)amino]butyric  acid,  sodium 

salt. 
N-(2-Coconut  oil  ajnidoethyl)-N-(2-hydroxyethyl)- 

glycine,  sodium  salt. 

N-(Dodecyl  and  tetradecyl)-8-alanine 

N-(Dodecyl  and  tetradecyl)-6-alanine,  triethanolamine 

salt. 

N-Dodecyl-3-iminodipropionic  acid 

N-Dodecyl-3-iminodipropionic   acid,    disodium  salt 

Mixed   acyclic  primary   amines,    ethoxylated  and 

sulfated,   sodium  salt. 

(Mixed  alkyDsulfobetaine 

Mixed  fatty  betaines 

Oleic  acid   -   ethylenediamine   condensate,   propoxylated 

and  sulfated,   sodium  salt. 
N'-(Tallow  alkyl)-3-iminodipropionic    acid,    disodium 

salt. 

All  other  acyclic 

Cyclic: 

1 , 1-Bis  (carboxymethyl) -2-undecyl-2-imidazoliniura 

hydroxide,  disodium  salt. 
l-Carboxymethyl-2-heptadecyl-l- (2-hydroxyethyl) -2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 

salt. 
l-Carbox^ethyl-l-  (2-hydroxyethyl)  -2-nonyl-2-imid- 

azolinium  hydroxide,  sodium  derivative,  sodium 

salt. 
l-Carboxymethyl-l-(2-hydroxyethyl)-2-imdecyl-2- 

imidazolinium  hydroxide,    sodium  derivative, 

sodium  salt. 
Heptadecylmethylbenzimidazolinesulfonic  acid, 

sodium  salt . 
3- [2- (2-Undecyl-2-imidazolin-l-yl}ethoxy] -propionic 

acid,   sodium  salt. 


DUP. 
DUP. 


VAC . 
DUP. 


CNM,    VAC. 

GNU. 

ARC. 


GNU. 

GNM. 

GNU. 

GNM. 

RH. 

DUP, 

TXT. 

TXT. 

S. 

FNX, 

GNfl. 

SEY, 

X. 

MIR, 

live. 

MIR, 

m'c. 

MIR,   TCII,    UVC,   VAC. 

CGY. 
UVC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972- 
TABLE  2. --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'   identification  codes 
(according  to   list   in  table   3) 


Anionic;  Surface-Active  Agents 

*Carboxylic   acids    (and  salts    thereof): 

*Amine  salts   of  fatty,    rosin,    and  tall   oil   acids: 

Coconut   oil   acids,   diethanolamine  salt 

Coconut   oil   acids,    triethanolainine  salt 

Laurie,    myristic,   palmitic,    and  stearic   acids,    tri- 
ethanolamine   salt. 

Oleic  acid,   n-butylamine  salt 

Oleic   acid,    triethanolainine   salt 

Stearic   acid,   N,N,N',N'-tetrakis  (2-hydroxyethyl) - 
ethylenediamine   salt. 

Stearic  acid,   triethanolainine  salt 

Tall   oil   acids,    diethanolamine   salt 

Tallow   acids,    triethanolamine   salt 

*Carboxylic  acids  having  amide,   ester,   or  ether 
linkages : 

Butoxyethoxypropi  oni  c   aci  d 

N-CCoconut  oil   acyl)sarcosine,   sodium  salt 

Diisobutylene   -   maleic   anhydride   copolymer, 
ammonium  and  sodium  salts. 

Epoxidized  oleic   acid,    ammonium  salt 

*N-Lauroylsarcosine ,    sodium  salt 

N-(Mixed  alkylsulfonyl) glycine ,   sodium  salt 

N-Oleoylpolypeptide,    sodium  salt 

N-Oleoylsarcosine,   sodium  salt 

Phthalic  acid,   octadecyl   ester,   potassium  salt 

Stearoyl-2-lactylic   acid 

Tridecyloxypoly(ethyleneoxy) acetic  acid,    sodium 
salt. 

Unspecified  sarcosine  derivatives 

All  other 

*Potassium  and  sodium  salts  of  fatty,  rosin,  and 
tall  oil  acids: 

Animal  grease,  sodium  salt 

*Castor  oil  acid,  potassium  salt 

Castor  oil  acid,  sodium  salt 

Cocoa  butter  acids,  sodium  salt 

*Coconut  oil  acids,  potassium  and  sodium  salts: 
*Potassiura  salt 

*Sodium  salt 

Coconut  oil  and  tallow  acids,  sodium  salt 

*Com  oil  acids,  potassium  and  sodium  salts: 

Potassium  salt 

Sodium  salt , 

Laurie  acid,  potassium  salt 

Laurie  and  myristic  acids 

Mixed  fish  oil  acids,  sodium  salt 

*Mixed  vegetable  oil  acids,  potassium  salt 

Oleic  acid,  potassium  salt 

*01eic  acid,  sodium  salt 

Olive  oil  acids,  sodium  salt 

Palm  kernel  acids,  sodium  salt 

*Palm  oil  acids,  sodium  salt 

Peanut  oil  acids,  potassium  salt 

Peanut  oil  acids,  sodium  salt 

Rosin  acids,  potassium  salt 

Rosin  acids,  sodium  salt 


SOP. 
SEP. 
SEP. 


GLY. 

ACE,    SOP. 
SEP. 


WC. 
FfflP. 

m. 

SCP. 

CP,    IfllP,    ONX. 

GAP. 

LUI,    X. 

GAP. 

CGY. 

GLY. 

lA'C. 

IIHP. 


NMC. 

NTL,    PEK,    SEA. 

HEW,    HRV,    NTL. 

HEW. 


ACE,   AES,    CON,    DA,    DYS.    ESS,    GRC,   GRL,    HEW,    HNT, 

JRG,   MCP,    NUC,    PCH,    PEK,    PC,    SOP,   VAL. 
AGP,    CON,    CP,    GRC,   HEW,   JRG,    LEV,   NMC,   NPR,    PG. 
BSW. 


GRC, 

GRC, 

USR. 

PG. 

DA. 

AES, 

AES, 

BSW, 

HEW. 

NMC. 

HEW, 

KAL, 

NMC. 

USR, 

CRT, 


HNT,   NMC. 

NMC. 


DYS,    GRC,   GRL,    LUR,    PCH,    PEK. 
ARL,,    DA,    DAN,    GYR,    HNT,    SCP,    SNW,    USR,    WEG. 
DA,    LEV,    LUR,   MRV,    NUC,   USR,    WBG,    IVTC. 
HNT,    LUR. 

LUR,    NMC,    PRX. 
SLC. 


PRX,    SLM,    X. 


SURFACE-ACTIVE  AGENTS 
TABLE  2. --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to   list   in  table   3) 


Anionic  Surfaae- Active  Agents — Continued 

*Carboxylic  acids    (and  salts   thereof) --Continued 
'Potassium  and  sodium  salts  of  fatty,   rosin,   and 
tall  oil   acids--Continued 

'Soybean  oil   acids,  potassium  and  sodium  salts: 

Potassium  salt 

Sodium  salt 

'Stearic  acid,  potassium  and  sodium  salts: 

Stearic  acid,  potassium  salt 

Stearic  acid,  sodium  salt 

•Tall  oil  acids,  potassium  salt 

*Tall  oil  acids,  sodium  salt 

Tallow  acids,  potassium  salt 

'Tallow  acids,  sodium  salt 

All  other 

'Phosphoric  and  polyphosphoric   acid  esters    (and  salts 
thereof) : 
'Alcohols   and  phenols,   ethoxylated  and  phosphated: 

Butyl   alcohol,   ethoxylated  and  phosphated 

'Dinonylphenol,    ethoxylated  and  phosphated 

Dodecyl   alcohol,    ethoxylated  and  phosphated 

Dodecylphenol ,   ethoxylated  and  phosphated 

2-Ethylhexanol ,   ethoxylated   and  phosphated 

Hexylphenol,   ethoxylated  and  phosphated 

Iso-pentyl   alcohol,   ethoxylated  and  phosphated 

'Mixed  linear  alcohols,   ethoxylated  and  phosphated-- 
'Nonylphenol,   ethoxylated  and  phosphated 

Nonylphenol ,   ethoxylated  and  phosphated,   barium 

salt. 
9-Octadecenyl   alcohol,   ethoxylated  and  phosphated-- 

9-Octadecyl   alcohol,   ethoxylated  and  phosnhated 

Octylphenol,   ethoxylated  and  phosphated 

Octylphenol,   ethoxylated  and  phosnhated.   magnesium 
salt. 

'Phenol,   ethoxylated  and  phosphated 

Polyhydric   alcohol,   ethoxylated  and  phosphated 

'Tridecyl   alcohol,   ethoxylated  and  phosphated 

All   other 

'Alcohols,   phosphated  or  polyphosphated: 

Decyl,   dodecyl,   and  octyl  phosphate,   morpholine 
salt. 

Decyl   and  octyl  phosphate 

Decyl   polyphosphate,   sodium  salt 

2-Ethylhexyl   phosphate 

*2-Ethylhexyl   phosphate,   sodium  salt 

2-Ethylhexyl  phosphate,   triethanolamine  salt 

2-Ethylhexyl   polyphosphate 

2-Ethylhexyl   polyphosphate,    sodium  salt 

Hexyl  phosphate 

Hexyl  phosphate,   potassium  salt 

Hexyl  polyphosphate,   potassium  salt 

Isooctyl  phosphate 

Mixed  alkyl  phosphate 

Mixed  alkyl  phosphate,   diethanolamine  salt 

9-Octadecenyl  phosphate 


CON,    DYS,    HEW,    PCH. 
HEW,    NHC. 

CON,   DYS,    HEW,    SCO,   IJSR,    WTC. 

DA,   HEW,   JRG,   IVTC. 

AES,   ASY,    CON,   DYS,    ESS,    GAP,    GRC,   GYR,   HNT,    NMC, 

PEK,    PNX,    SOP,    VAL,    x. 
ASY,    CON,    GRC,   GYR,   MRV,    PRX,    SOP,    UNP,    x. 
AES,   ASY,    GYR,    PG,   USR. 
AGP,    ASY,    BSW,   CON,   CP,    DA,    GRC,    GYR,   HEW,    JRG, 

LEV.    LUR,    NflC,   NPR,    PG,    PRX. 
GYR. 


GAP. 

ARL,  GAP 

NLC,  TXT,  WTC. 

GAP,  WIG 

IVTC. 

GAP. 

FNX,  WAY 

ICI. 

GAP. 

CHP,  CRT 

CST,  FNX,  GAP,  TCH,  TXT,  WTC, 

WYN. 

ARL,  CHP, 

CRT,  DEX,  GAP,  HDG,  NLC,  SCP, 

SEY,  SNW 

SOP,  TCC,  TXN,  TXT,  VAC,  WAY,  WTC. 

GAP. 

GAP. 

GAP. 

ARL,  Rll, 

WAY. 

FNX,  GAP, 

WTC,  X. 

NLC. 

ARL,  FNX 

GAP,  LUR,  NLC,  TCC,  WAY,  WTC. 

GAP,  WTC 

DUP, 
WTC. 
WAY. 
CHP, 
SYL. 
TCC, 

X. 

ICI. 
ICI. 
DEX. 
GAF. 
CST, 
DUP. 
DUP. 


PNX,    GAF,    MRA,    SEY,   UCC,   UVC. 
UVC,    X. 


DUP,    SFS,   TCC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972. 
TABLE  2. --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list   in  table   3) 


Anionic  Surface- Active  Agents — Continued 

*Phosphoric   and  polyphosphoric   acid  esters    (and   salts 
thereof) - -Continued 
♦Alcohols,   phosphated  or  polyphosphated--Continued 

Octyl  phosphate 

Octyl  phosphate,   alkylamine  salt 

Octyl  phosphate,   potassium  salt 

Octyl  polyphosphate 

Octyl  polyphosphate,  potassium  salt 

All   other 

♦Sulfonic  acids  (and  salts  thereof) : 
*Alkylbenzenesulfonates: 
Dodecylbenzenesulfonates : 
*Dodecylbenzenesulfonic  acid 

Dodecylbenzenesulfonic  acid,  ammonium  salt 

Dodecylhenzenesulfonic  acid,  butylamine  salt 

♦Dodecylbenzenesulfonic  acid,  calcium  salt 

Dodecylbenzenesulfonic  acid,  diethanolamine  salt- 

Dodecylbenzenesulfonic  acid,  dimethylamine  salt-- 

Dodecylbenzenesulfonic  acid,  ethylenediamne 

salt. 

Dodecylbenzenesulfonic  acid,  isopropanolamine 
salt. 

♦Dodecylbenzenesulfonic  acid,  isopropyl amine  salt- 

♦Dodecylbenzenesulfonic  acid,  (mixed  alkyl)amine 
salt. 

Dodecylbenzenesulfonic  acid,  potassium  salt 

♦Dodecylbenzenesulfonic  acid,  sodium  salt 


♦Dodecylbenzenesulfonic  acid,  triethanolamine 
salt. 
Other  alkylbenzenesulfonates : 

Decylbenzenesulfonic  acid,  sodium  salt 

Di dodecylbenzenesulfonic  acid 

Didodecylbenzenesulfonic  acid,  sodium  salt 

Pentadecylbenzenesulfonic  acid,  potassium  salt- 

Tridecylbenzenesulfonic  acid 

♦Tridecylbenzenesulfonic  acid,  sodium  salt 

Undecylbenzenesulfonic  acid 

Undecylbenzenesulfonic  acid,  ammonium  salt 

Undecylbenzenesulfonic  acid,  sodium  salt 

Undecylbenzenesulfonic  acid,  triethanolamine 
salt. 

All  other 

♦Benzene-,  cumene- ,  toluene-,  and  xylenesulfonates: 

Benzenesulfonic  acid,  sodium  salt 

♦Cumenesulfonic  acid,  ammonium  salt 

Cumenesulfonic  acid,  sodium  salt 

Hydroquinonesulfonic  acid,  potassium  salt 

Toluenesulfonic  acid 

Toluenesulfonic  acid,  potassium  salt 

Toluenesulfonic  acid,  sodium  salt 

Xylenesulfonic  acid 


TXT. 

DUP,    NLC,    TXT. 

DUP,    SN'W. 

DEX. 

X. 

DUP,   TCH,    X. 


ACS,    ATR,    CO,   CRT,   CTL,    EMK,   FNX,    HLI,    ICI,    LAK, 

LEV,    PIL,    PLX,    PRX,    RCD,    STP,   TCI,   TEN,   TXT,    WTC. 
ARL,    FNX,   TXN,    IVTC. 
IVTC. 

ICI,    NLC,    RCD,    RH,    STP,   TMI),    IVTC. 
FNX,    l^fTC. 
PIL. 
ICI. 

ARD,    CTL,    l*TC. 

AAC,    CHP,    CIN,    CTL,    FNX,    ICI,    RCD,    SNW,    STP. 
ECC,    FNX,    NLC,   TCH,    IVTC. 

RCD,    SOP,    STP,    VAL. 

AAC,    ACS,    ARD,   ARL,   ATR,    BLA,    CHP,    CO,    CP,    CRT, 
CTL,    DA,    ECC,   HLI,    HRT,    LEV,    NMC,    PG,    PIL,    PLX, 
PRX,    QCP,    RCD,    SOP,    STP,    TEN,   TXT,   UCC,    WTC. 

AAC,    ACS,    ARD,    ARL,   ATR,    CIN,   CTL,    ECC,    ESS,    FNX,    HLI, 
PIL,    RCD,    SOP,    SOS,    STP,   TXN,   WTC. 

LAK. 

CO. 

ATR. 

STP. 

CO,    RCD. 

BLA,    CO,    CP,    NPR,    PG,    RCD,    IVTC. 

TXT. 

TXT. 

TXT. 

TXT. 

LISR. 

NES. 

NES,    PRX,    STP,    IVTC. 

NES. 

NES. 

RCD. 

NES,    STP,    TXN. 

CO,  NES,  PRX,  iirrc. 

HLI. 


SURFACE-ACTIVE  AGENTS 


TABLE  2.- 


-Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification   codes 
(according  to   list    in   table   3) 


Anionic  Surface-Active  Agents — Continued 

*Sulfonic   acids    (and  salts    thereof) --Continued 

*Ben2ene-,    cumene-,    toluene-,    and  xylenesulfonates — 
Continued 

*Xylenesulfonic  acid,   ammonium  salt 

Xylenesulfonic   acid,   potassium  salt 

*Xylenesulfonic   acid,    sodium  salt 

*Ligninsulfonates : 

Ligninsulfonic   acid,    aluminum  salt 

Ligninsulfonic   acid,    ammonium  salt 

*Ligninsulfonic  acid,   calcium  salt 

Ligninsulfonic  acid,    chromium  salt 

Ligninsulfonic  acid,   copper  salt 

Ligninsulfonic  acid,    iron  salt 

Ligninsulfonic   acid,    magnesium  salt 

Ligninsulfonic  acid,   manganeses   salt 

*Ligninsulfonic  acid,   sodium  salt 

Ligninsulfonic  acid,    zinc  salt 

All   other 

*Naphthalenesulfonates : 

*Butylnaphthalenesulfonic   acid,    sodium  salt 

Dibutylnaphthalenesulfonic   acid 

Didodecylnaphthalenesulfonic   acid,    sodium  salt 

Diisopropylnaphthalenesulfonic  acid,   sodium  salt 

Dipentylnaphthalenesulfonic   acid,    (mixed  alkyl)- 
amine  salt. 

Dipentylnaphthalenesulfonic   acid,    sodium  salt 

I sop ropy  In aphthalene sulfonic   acid 

Methylenebis (2 -naphthalene sulfonic  acid) 

Methylnaphthalenesulfonic   acid,    soditim  salt 

Methylnonylnaphthalenesulfonic   acid,    sodium  salt 

Tetrahydronaphthalenesulfonic   acid,    sodium  salt 

*Sulfonic  acids  having  amide   linkages: 
*Sulfosuccinic   acid  derivatives: 

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuccinamic 

acid,   tetrasodium  salt. 
N-(2-Hydroxyethyl)-N- (tallow  alkyl)sulfo- 
succinamic  acid,   disodium  salt. 

N-Octadecylsulfosuccinamic   acid,    disodium  salt 

Sulfosuccinic  acid,    alkanolamide  ester,    sodium 

salt. 
Sulfosuccinic   acid,    alkanolamide   ester,    tri- 

ethanolamine  salt. 
Sulfosuccinic  acid,   2- (coconut  oil   amido)ethyl 
ester,    disodium  salt. 

All  other 

*Taurine  derivatives; 

N-(Coconut  oil  acyl)-N-methyltaurine,  sodium  salt- 

N-Cyclohexyl-N-palmitoyltaurine ,  sodium  salt 

N-Methyl-N-oleoyltaurine,  sodium  salt 

N-Methyl-N-palmitoyltaurine,  sodium  salt 

N-Methyl-N- (tall  oil  acyl) taurine ,  sodium  salt 

N-!lethyl-N- (tallow  acyl)  taurine,  sodium  salt 

*Sulfonic  acids  having  ester  or  ether  linkages: 
*Sulfosuccinic  acid  esters: 

*Sulfossuccinic  acid,  bis (2 ,6-dimethyl-4-heptyl) 

ester,  sodium  salt. 
'Sulfosuccinic  acid,  bis (2-ethylhexyl)  ester, 
sodium  salt. 


CO, 

HLI, 

NES, 

STP, 

TXN, 

WTC. 

NES 

AIR 

CO, 

HLI, 

ICI, 

NES, 

PIL, 

MAR 

CPP 

CRZ 

SPA 

WV'A 

CRZ 

CWP 

LKY 

MAR 

PSP 

WVA 

MAR 

RAY 

IWA 

CRZ 

m'A 

MAR 

W\'A 

IWA 

CRZ 

MAR 

RAY 

IWA 

IWA 

PSP 

DA, 

ECC, 

PFZ. 

GAP 

S. 

PFZ 

DA, 

GAP, 

PFZ. 

DA, 

DUP, 

GRD. 

DUP 

DA, 

UDI. 

LIDI 

DUP 

ACY, 

MOA 

SCP 

ACY 

HDG 

SCP 

SCP 

LAK 

ACT 

FNX 

GAF 

LIL 

TNI 

GAF 

DA, 

DEP, 

FNX, 

GAF, 

HRT,  MCP. 

GAF 

CRT 

FNX 

GAF 

MRA 

WTC. 

GAF 

D/\N,    GAF,    MOA. 


ACY,    CGY,    CUP,    CRT,   CST,    DA,    DAN,    ECC,    EMK,    FNX,    HDG, 
HRT,    MCP,   MOA,   MRA,    PC,    SBC,    SCO,    UVC . 


552-743  0-74-12 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED  BY  MANUFACTURER.  1972— CONTINUED 


Manufacturers'   identification  codes 

Chemical 

(accordi 

ng  to   list   in   table   3) 

Anionic  Surface- Active  Agents — Continued 

♦Sulfonic   acids    (and  salts   thereof) --Continued 

'Sulfonic  acids  having  ester  or  ether  linkages-- 

Continued 

*Sulfosuccinic  acid  esters--Continued 

Sulfosuccinic  acid,  bis (tallow  monoglyceride) 

ACY. 

ester,   sodium  salt. 

Sulfosuccinic  acid,   dihexyl   ester,   sodium  salt 

ACY, 

MOA 

Sulfosuccinic  acid,   diisobutyl   ester,   sodium 

MOA. 

salt. 

Sulfosuccinic  acid,   diisodecyl  ester,   sodium 

MCP. 

salt. 

Sulfosuccinic   acid,   diisooctyl   ester,   sodium 

RH. 

salt. 

Sulfosuccinic  acid,   dipentyl   ester,   sodium  salt 

ACY. 

Sulfosuccinic  acid,   ditridecyl   ester,   sodium 

ACY, 

MOA 

salt. 

*Other  sulfonic   acids  having  ester  or  ether 

linkages : 

Coconut  oil   acids,    2-sulfoethyl   ester,    sodium 

GAF, 

LEV 

X. 

salt. 

Dodecyldiphenyloxidedisulfonic   acid,    disodium 

DOW. 

salt. 

ACS. 

uoaecy 1   suiroacetate 

Dodecyl   sulfoacetate,   sodium  salt 

SIP. 

SLfl 

Herring  oil,   suironateu 

Iso-octylphenol,   ethoxylated  and  sulfonated. 

CRT, 

RH. 

sodium  salt. 

SLM. 

All   other 

*A11   other  sulfonic   acids: 

Butylhydroxybiphenylsulfonic  acid 

RBC. 

Mixed   alkanesulfonic   acid,    sodium  salt 

DUP. 

CP 

LAK, 

NLC,    STP. 

Mixed   linear  aipna  oienns,   suironateci 

Petroleumsulfonic   acid,   water  soluble    (acid   layer), 

WTC. 

sodium  salt. 

All   other 

•Sulfuric   acid  esters    (and   salts   thereof): 

*Acids,   amides,    and   esters,    sulfated: 

•Coconut  oil   acids   -   ethanolamine  condensate. 

DEX, 

B1K 

ONX. 

sulfated,   potassium  salt. 

•Esters  of  sulfated  oleic  acid: 

2-Butoxyethyl   oleate,    sulfated,    sodium  salt 

S. 

Butyl   and  propyl   oleate,   sulfated,   sodium  salt 

^ICP. 

•Butyl    oleate,    sulfated,    sodium  salt 

AKS, 

EFH 

ICI,   MCP, 

ONX,    PC,    SEY. 

2-Ethylhexyl  oleate,   sulfated,   sodium  salt 

CHP. 

£^]-jyj   oleate     sulfated     sodium  salt 

GAF. 
LEA, 

Glyceryl    trioleate,    sulfated,    sodium  salt 

MRV 

Isobutyl   oleate,   sulfated,   sodium  salt 

DA. 

•Isopropyl  oleate,   sulfated,   sodium  salt 

CRT, 

DEX 

FNX,    HRT, 

LEA,    SCP. 

Methyl  oleate,   sulfated,   sodium  salt 

ICI. 

Mixed  oleic  acid  esters,   sulfated,   sodium  salt 

EFH. 

♦Propyl    oleate,    sulfated,    sodium  salt 

ACY, 

AKS, 

CHP,    MRV. 

•Oleic  acid,    sulfated,   disodium  salt 

ACT, 

ACY 

CHP,    CRT, 

DA,   GAF,    LEA,    SCO,   TEN,   IVTC. 

Other  acids,   amides,   and  esters,   sulfated: 

Castor  oil   and  oleic   acid,    sulfated,    ammonium  salt- 

sen. 

Glycerol  monoester  of  coconut  oil   acids,   sulfated 

CP. 

sodium  salt. 

SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER.    1972— CONT INUED 


Manufacturers'    identification  codes 
(according  to  list   in  table  3) 


Anionic  Surface- Ac  live  Agents — Continued 

'Sulfuric   acid  esters    (and  salts   thereof)--Continued 
*Acid5,    amides,    and  esters,    sulfated--Continued 

*Other  acids,    amides,   and  esters   sulfated--Continued 

9-Octadecenyl   acetate,   sulfated,   sodium  salt 

Oleic   acid,    sulfated,    triethanolamine   salt 

Tall   oil,    sulfated,    sodium  salt 

All  other 

'Alcohols,   sulfated: 

Coconut   and  sperm  oil   alkyl   sulfate,   sodium  salt 

Decyl   and  octyl   sulfate,   sodium  salt 

♦Decyl   sulfate,   sodium  salt 

3,9-Diethyl-6-tridecyl  sulfate,   sodium  salt 

*Dodecyl   sulfate  salts: 

2-Amino-2-methylpropanol   salt 

'Ammonium  salt 

Diethanol amine   salt 

Diethylamine   salt 

N,N-Diethylcyclohexylamine   salt 

Isopropanolamine   salt 

'Magnesium  salt 

Potassium  salt 

'Sodium  salt 

'Triethanolamine  salt 

2-Ethylhexyl   sulfate,   sodium  salt 

Hexadecyl   sulfate,   sodium  salt 

7-Ethyl-2-methyl-4-undecyl   sulfate,   sodium  salt 

Hexyl   sulfate,   potassium  salt 

Mixed   linear  alcohol   sulfate,   ammonium  salt 

Mixed   linear  alcohol   sulfate,   sodium  salt 

Mixed  linear  alcohol   sulfate,   triethanolamine 
salt. 

Nonyl   sulfate,   sodium  salt 

9-Octadecenyl  sulfate,   2- (diethylamino)ethanol  salt- 

Octadecyl    sulfate,    sodium  salt 

Octadecyl   sulfate,   triethanolamine  salt 

Octyl   sulfate,   sodium  salt 

Tridecyl   sulfate,   sodium  salt 

All   other 

'Ethers,   sulfated: 

'Alkylphenols,   ethoxylated  and  sulfated: 

Nonylphenol,   ethoxylated  and  sulfated,   ammonium 
salt. 
'Nonylphenol,   ethoxylated  and  sulfated,    sodium 
salt. 
Nonylphenol,   ethoxylated  and  sulfated,   tri- 
ethanolamine salt. 
Octylphenol,   ethoxylated  and  sulfated,   sodium 
salt. 
'Dodecyl    alcohol,    ethoxylated  and  sulfated,    ammonium 

salt. 
'Dodecyl   alcohol,   ethoxylated  and  sulfated,   sodium 
salt. 
Dodecyl  and  tetradecyl   alcohols,   ethoxylated  and 

sulfated,   ammonium  salt. 
2-Ethylhexanol,   ethoxylated  and  sulfated,   sodium 
salt. 

2-Hexyloxypropyl   sulfate,   sodium  salt 

'Mixed   linear  alcohols,   ethoxylated  and  sulfated 

ammonium  salt. 
'Mixed  linear  alcohols,   ethoxylated  and  sulfated, 
sodium  salt. 


DUP. 

KAY. 

APX,    BAO,    DA,    FNX,    ICI,    SEA,    Iffll ,    IVHW. 

DA,    eiR. 

DA,    DUP,   FNX. 

TCH,   IVTC. 

APX,    CTL,   DUP,    HLl,    SCP. 

UCC. 

DUP. 

AAC,    CTL,    HLI,   JRG,   ONX,    PG,    RCD,    SCP,    STP,   TCH,    WTC. 

DUP,   HLl,   JRG,   ONX,    SCP,    STP. 

AAC. 

DUP. 

JRG,    TCH. 

AAC,    HLI,   ONX,    STP. 

GYR,    HLl,    PG. 

AAC,    CTL,    DUP,    HLI,   JRG,   ONX,    PG,    RCD,   SCP,    STP,   TCH, 

WTC. 
AAC,    CTL,   DUP,    HLI,    ONX,   PG,    RCD,    SCP,    STP,   TCH,   TXT. 
AAC,    SCP,   TCH.   UCC. 
AAC,    DUP,    SCP. 
UCC. 
DEX. 

CP,    LAK,    NTL,    S,    SCP,    UCC. 
LAK,    SCP,    SEY,    TXT. 
LAK,   SCP. 

TEN,   TXT. 

AAC. 

DUP,    EHK,   ONX,    PG. 

DUP. 

AAC,   DUP. 

AAC,    SCP. 

LEV. 


CGY,   GAP,    .STP,    TXT,   WTC. 

CRT,   DEX,    GAF. 

ARL. 

RH. 

AAC,   AKS,    CTL,    STP,    TXT,    WTC. 

AAC,   CTL,   HLI,    ONX,   RCD,    SCP,    STP,   TCH,   IVTC. 

LEV,   TXN. 

UCC. 

S. 

CO,    LAK,   NLC,    PG,    PIL,   RCD,    SCP,    SHC,    STP,   TXT. 

AAC,   CO,    DA,    LAK,    PG,    PIL,    RCD,    SCP,    SHC,    STP, 
TCI,   TXT. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2, --Surface-active  agents  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER.  1972— CONTINUED 


Manufacturers ' 

identification  codes 

Chemical 

(according  to   list   in   table   3) 

Anionic  Surface-Aative  Agents — Continued 

♦Sulfuric  acid   esters    (and   salts    thereof) — Continued 

♦Ethers,   5ulfated--Continued 

Sperm  oil    alcohol,    ethoxylated  and  sulfated, 

DUP, 

WAW 

sodium  salt. 

Tridecyl    alcohol,    ethoxylated   and  sulfated,    sodium 

AAC, 

ARL 

PRX,    RCD. 

salt. 

All   other 

DUP. 

♦Natural   fats   and  oils,    sulfated: 

•Castor  oil,   sulfated,   sodium  salt 

ACT, 

ACY 

AKS,   APX,  ARL 

BAO,    BSW,    CRT,    DA,    DEX,    EFH, 

FNX,    GAP,    HRT,    ICl,    KAL,    KNG,    LEA,    LUR,   MCP,   MRD, 

MRV,    S 

SCO,    SCP,    SLC 

SLM,    WHI,    WHIM. 

♦Coconut   oil,    sulfated,    sodium  salt 

ACY, 

BAG 

DA,    LUR,   MRD, 

SEA,    SLC,    IVHW. 

♦Cod  oil,    sulfated,    sodium  salt 

ACT, 

BAO 

SEA,    IVHI,    WHIV 

Grease,   other  than  wool,   sulfated,    sodium  salt 

SEA, 

mil 

Herring  oil,   sulfated,    ammonium  salt 

SCP. 

♦Herring  oil,   sulfated,   sodium  salt 

ACT, 

DA, 

SLM,    WHI,    IVHW. 

♦Lard,   sulfated,   sodium  salt 

CRT, 

FNX 

SLM,    WAW. 

Mixed  alpha  olefins   and  vegetable  oils,   sulfated. 

SLM. 

sodium  salt. 

Mixed  animal   and  vegetable  oils,   sulfated,   sodium 

SLU. 

salt. 

♦Mixed   fish   oils,    sulfated,    sodium  salt 

ACT, 

DA, 

MRD,    SLM. 

Mustard  seed  oil,    sulfated,    sodium  salt 

DA, 

LUR. 

♦Neat's-foot  oil,   sulfated,   sodium  salt 

ACT, 

BAO 

CRT,   DA,    KAL, 

LUR,   MRD,    PC,    SEA,    SLM,    WHW. 

♦Peanut   oil,    sulfated,    sodium  salt 

ACY, 

CUP 

DA,    LEA,    LUR. 

♦Ricebran  oil,   sulfated,   sodium  salt 

DA, 

EFH, 

KNG,    LUR,    SEA, 

WHI. 

♦Soybean  oil,   sulfated,   sodium  salt 

CRT, 

HRT 

KAL,   MRD,   ONX 

WHW. 

♦Sperm  oil,    sulfated,    sodium  salt 

ACT, 

CLD 

CRT,    DA,    FNX, 

KAL,    ONX,    SCO,    SEA,   WHI,   WHW. 

♦Tallow,    sulfated,    sodium  salt 

ACT, 

ACY, 

BSW,    DA,    ECC, 

LUR,   MCP,   MRD,    PC,    SCP,    SID, 

SLM,    SnS,    IVHI. 

Other  anionic  surface-active   agents: 

Lignin   (non-sulfonated)    and  salts   thereof 

1*VA. 

Mixed   linear  alcohols,   ethoxylated  and  carbonated. 

S. 

sodium  salt. 

Polyethylene-vinyl   alcohol  copolymer,   potassium  salt 

NLC. 

Tridecyl    alcohol,    ethoxylated   and  carbonated. 

S,    SEY. 

sodium  salt. 

All  other 

QCP, 

STC 

Cationia  Surface- Active  Agents 

♦Amine  oxides  and  oxygen- containing  amines    (except 

those  having  amide   linkages): 

♦Acyclic: 

N,N-Bis(2-hydroxyethyl) (coconut  oil   alkyl) amine 

ARC. 

oxide. 

CTL. 

.ARC, 

FIN 

TCH. 

N  N-Bis  (2-hydroxyethyl)  f  tal  low   alkvDamine 

ARC. 

N,N-Bis(2-hydroxyethylKtallow   alkyl)amine   acetate--- 

PG. 

N,N-Bis(2-hydroxyethyl) (tallow   alkyl)amine   oxide 

ARC. 

AAC, 

ARC, 

ASH,    BRD,    ICI 

NLC,    TCH,    VAC. 

(Coconut    oil    alkyl)amine,    ethoxylated,    acetate 

RPC. 

(Coconut   oil   alkyl) amine,   ethoxylated,   maleate 

SDH. 

N,N-Dimethyl(coconut   oil    alkyl)amine   oxide 

ARC. 

N,N-Dimethyldecylamine   oxide 

BRD. 

N,N-Dimethyldodecylaraine  oxide    (Lauryl   dimethylamine 

BRD, 

X. 

oxide) . 

N,N-Dimethylhexadecyl amine  oxide 

ONX. 

N,N-Dimethyl(hydrogenated  tallow  alkyl)amine  oxide — 

ARC. 

Ethylenedi amine,   ethoxylated  and  propoxylated 

ICI. 

SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER.    1972--C0NTINUED 


Manufacturers'    identification   codes 
(according  to   list    in  table   3) 


Catiowic  Sui' face- Active  Agents — Continued 

*Amine  oxides   and  oxygen-containing  amines (except   those 
having   amide   linkages) --Continued 
*Acyclic- -Continued 

(Hydrogenated   tallow   alkyl)  ajnine,    ethoxylated 

N-(2-Hydroxyethyl)-N,N' ,N' -tris (2-hydroxypropyl) - 

ethylenediamine . 
N- (2-Hydroxyethyl1-N,N' ,N' -tris (2-hydroxypropyl) - 
ethylenediamine  distearate,   methyl   sulfate. 

(Mixed   alkyl)amine,    ethoxylated 

(Mixed   alkyl)poly (oxye thy lene) amine 

Mixed   substituted  oximes 

(9-Octadecenyl) amine ,   ethoxylated 

Octadecyl amine,    ethoxylated 

Po lye thy lenepoly amine ,    alkoxylated 

(Soybean   oil   alkyl)amine,    ethoxylated 

*(Tallow   alkyl)amine,    ethoxylated 

Tallow   alkyl   amine   ethoxylated,    sulfate 

N-(Tallow   alkyl) trimethylenediamine,   ethoxylated 

N,N,N' ,N'-Tetrakis (2-hydroxye thy 1) ethylenediamine — 
N,N,N' ,N'-Tetrakis (2-hydroxypropyl) ethylenediamine 

dioleate ,   methyl   sulfate. 
N,N,N'  ,N'-Tetrakis  (2-hydrox\'propy  1) ethyl enedi amine  , 
propoxylated  and  ethoxylated. 

Triethanol amine ,    ethoxylated 

All   other 

*Cyclic  (except  imidazoline  and  oxazoline  derivatives) : 

Aniline  and  m-toluidine ,  ethoxylated 

Lignin  amine 

Rosin  amine,  ethoxylated 

Imidazoline  and  oxazoline  derivatives: 

2- (8-Heptadecenyl)-4,4-bis(hydroxymethyl)-2- 

oxazoline. 
2-(8-Heptadecenyl)-l- (2-hydroxyethyl) -2- 

imidazoline. 
2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2- 
oxazoline. 

*2-(Heptadecyl)-l- (2 -Hydro xye thy 1) -2- imidazoline 

*l-(2-Hydroxyethyl)-2-nor(coconut  oil  alkyl)-2- 

imidazoline. 
*l-(2-Hydroxyethyl)-2-nor(tall   oil    alkyl)-2- 
imidazoline. 
l-(2-Hydroxyethyl)-2-tridecyl-2-imidazoline 
hydrochloride. 

2-Hydrox\Tpropyl    imidazoline 

*Amines   and   amine   oxides  having   amide   linkages: 

*Carboxylic  acids   -  diamine  and  polyamine  condensates: 
Caprylic  acid  -   tetraethylenepentamine   condensate — 
Coconut  oil   acids   -   diethylenetri amine   condensate — 
Coconut  oil   acids   -   N,N-dimethyltrimethylene- 

diamine   condensate. 
Mixed  dicarboxylic   acids    -   polyalkylenepolyamine 
condensate. 
*Mixed  fatty  acids   -  polyalkylenepolyamine 
condensate. 
Oleic  acid   -   1- (2-aminoethyl)piperazine  condensate-- 

Oleic  acid  -   diethylenetriamine   condensate 

Oleic  acid   -   N,N-dimethyltrimethylenediaraine 

condensate. 
Pelargonic  acid  -   tetraethylenepentamine 

condensate . 
Stearic   acid,    diethanolamine   condensate, 
methyl  sulfate. 

Stearic  acid   -   diethylenetriamine  condensate 

Stearic  acid  -   N,N-diethylethylenediamine 
condensate. 


CGY, 
NLC. 


CGY, 

DA, 

GAP, 

ICI,    RH,    T 

GAP. 

GNM. 

ARC, 

DA, 

TCH. 

ARC, 

TCH 

NLC, 

TCH 

.ARC, 

VAC 

ARC, 

CGY 

DUP 

GAP,    TCH. 

DUP. 

ARC, 

IVTC 

NLC. 

DUP. 

ARC, 

IVTC 

IVYN 

TCH. 

ARC, 

GLY 

SCP 

TCH. 

IWA. 

HPC, 

NLC 

WTC 

DA, 

ONX, 

UVC. 

CGY, 

COM, 

uvc. 

CGY, 

CHP, 

MOA, 

UVC. 

CGY, 

HOA, 

UVC. 

HDG, 

MOA, 

NLC, 

TCH,    UVC. 

CGY, 

IVTC. 

TCH. 

ICI. 

APX, 

TXT. 

JRG, 

TXT 

IVTC. 

TXT. 

GRD. 

NLC, 

QCP. 

TCH. 

TXT. 

ICI, 

TXT. 

CCW. 

ICI 

DUP. 

CHP, 

CST, 

PNX, 

ONX,    S. 

CGY, 

S. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Surface-active  agents  for  which  U.S,  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to   list    in    table   3) 


Cationic  Surface- Active  Agents — Continued 

♦Amines   and  amine  oxides  having  amide  linkages — Continued 
*Carboxylic  acids   -  diamine  and  polyamine  condensates-- 
Continued 

Stearic  acid  -  tetraethylenepentamine  condensate 

*Tall  oil   acids   -   diethylenetriamine   and 
polyalkylene  polyamine  condensates : 

Tall   oil   acids   -   diethylenetriamine   condensate 

Tall   oil   acids   -  polyalkylenepolyamine  condensate- 
All  other 

Other  amines   and  amine  oxides  having  amide   linkages: 
Coconut  oil   acids   -  diethylenetriamine  condensate, 
po lye th oxy 1  at ed . 

3-Lauramido-N,N-dimethylpropylamine  oxide 

Mixed  fatty  acids  -   alky lenedi amine  condensate, 

polyethoxylated. 
Oleic  acid  -   ethy lenedi amine  condensate,   mono- 

ethoxylated. 
Palm  oil    acids   -    ethylenediamine   condensate,    mono- 
ethoxylated. 

Rosinpolyamidoimidazoline 

Stearic  acid  -  diethylenetriamine  condensate,  poly- 
ethoxylated. 
♦Stearic  acid  -   ethylenediamine  condensate,   mono- 
ethoxylated. 
Stearic  acid  -   ethylenediamine  condensate,   poly- 
ethoxylated. 
Tall   oil   acids   -  ethylenediamine   condensate, 
monoethoxylated. 
♦Amines,  not   containing  oxygen    [and  salts  thereof): 
♦Amine  salts  : 

(Coconut  oil  alkyl)amine  acetate 

(Hydrogenated  tallow   alkyl)amine  acetate 

(9-Octadecenyl) amine  acetate 

Octadecyl amine  acetate 

(Tallow  alkyl)amine   acetate 

N- (Tallow  alkyl)trimethylenediamine  acetate 

N- (Tallow   alkyl)trimethylenedianiine   oleate 

N- (Tallow   alkyl)trimethylenediamine   tallate 

All   other 

♦Diamines  and  polyamines : 

♦N- (Coconut  oil  alkyl)trimethylenediamine 

N-(Docosyl-  and  eicosyl) trimethylenediaraine 

♦Imidazoline  derivatives: 

1- [3-(2-Aminoethyl)naphth-l-yl]-2-(8-hepta- 

decenyl) -2- imidazoline. 
l-(2-Aminoethyl)-2-nor(tall  oil  alkyl)-2- 
imidazoline. 

2-Heptadecy 1-2- imidazoline 

Tall  oil  imidazoline 

N- (Mixed  alkyljpolyethylenepolyamine 

♦N- (9-Octadecenyl) trimethylenediamine 

N- (Soybean  oil  alkyl) trimethylenediamine 

N-(Tall  oil  alkyl)trimenthylenediamine 

N- (Tallow  alky l)dipropylenetri amine 

N- (Tallow  alkyl) trimethylenediamine 

♦Primary  monoamines : 

(Coconut  oil  alkyl)amine 

Dodecyl amine 

Docosyl-   and  eicosylamine 

Hexadecylaraine 

♦(Hydrogenated  tallow  alkyl)araine 

(Mixed  alkyl) amine 

(Mixed  tert- alkyl) amine 


AZS, 

DA,    FNX,   NCW, 

NLC, 

RTF, 

WTC 

AZS, 

QCP,    OTC. 

NLC, 

VND. 

SNW. 
GAP. 

CLD,    DA,    DEX,    SnC ,   TNA. 

APX. 

WC. 
TCC. 

CST,   DA,    DEX,    ICI,   MRV,   S,    SCP. 

ICI. 

SCP. 


ARC,  IVTC. 
ARC,  ASH. 
GNM. 

ACY,  ARC. 
ARC. 

ARC,   ASH. 
ARC,   ASH. 
ARC. 
SM 

ARC,    ENO,    GNM. 
END. 


NLC,   UVC,   IVTC. 

BIR,    SCO. 

AZS. 

CCW. 

ARC,   ASH,    GNM. 

ENO. 

ARC. 

ARC,   GNfl. 

ARC,   ASH,    ENO,    GNM. 

ARC,    ENO,    GNM. 

ARC,   ASH,   GNM. 

ENO. 

ARC,    ENO. 

ARC,   ASH,    ENO,   GNM. 

ARC. 

RH. 


SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to  list   in  table   3) 


Cationia  Surface- Active  Agents- -Contimied 

•Amines,  not   containing  oxygen    (and  salts   thereof) -- 
Continued 
'Primary  monoamines: 

*9 -Oct adecenyl amine 

*Octadecyl amine 

Octylamine 

tert-Octylamine 

(Soybean  oil  alkyljamine 

(Tall  oil  alkyDamine 

'(Tallow  alkyl) amine 

'Secondary   and   tertiary  monoamines: 

Bis (coconut   oil    alkyl)amine 

'Bis  (hydrogenated  tallow  alkyl)amine 

N,N-Dimethyl (coconut  oil   alkyl)amine 

N,N-Dirae thy Idecyl amine 

N,N-Dimethyl    (Docosyl-    and  eicosyl)amine 

*N,N- Dime thy Idodecyl amine 

*N, N- Dime thy Ihexadecyl amine 

N,N-Dimethyl (hydrogenated  tallow  alkyl) amine 

N,N- Dimethyl (mixed   alkyl) amine 

*N, N- Dime thy loctadecyl amine 

N,N- Dimethyl octylamine 

N,N-Dimethyl (soybean  oil    alkyl)amine 

N,N-Dirae thy Itetradecyl amine 

N-Methylbis (coconut   oil    alkyl)amine 

*N-Methy Ibis (hydrogenated  tallow  alkyl)amine 

N -Me thy Idi Oct adecyl amine 

Trioctyl amine 

'Oxygen-containing  quaternary  ammonium  salts: 

Quaternary   ammonium  salts  having   amide    linkages: 
Ethyldimethyl ( 3-pe 1 agonamidop ropy 1) ammonium 

ethyl   sulfate. 
(2-Hydroxyethyl) dimethyl (3-stearamidop ropy 1)- 

ammonium  dihydrogen  phosphate. 
(2-Hydroxyethyl)dimethyl (3-stearamidopropyl) - 

ammonium  nitrate. 
( 3- Lauramidopropyl)trimethyl ammonium  methyl 

sulfate. 
2- (2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium 

chloride. 
Tall  oil   acid  -  polyalkylenepolyamine   condensate, 

quaternary  sulfate. 
Trimethyl (3-oleamidopropyl)ammonium  methyl 
sulfate . 

All   other 

Other  oxygen-containing  quaternary  ammonium  salts: 
(2-Aminoethyl) ethyl (hydrogenated  tallow  alkyl)  (2- 

hydroxyethyl) ammonium  ethyl  sulfate. 
Benzyl (coconut  oil  alkyl)bis (2-hydroxyethyl)- 

ammonium  chloride. 
Benzyl (coconut  oil  alkyl,  ethoxylated)dimethyl- 

ammonium  chloride. 
l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl) -2- 

imidazolinium  chloride. 
1-Benzyl-l- (2-hydroxyethyl)-2-nor(tall  oil  alkyl)- 

2-imadazolinium  chloride. 
Bis(2-hydroxyethyl,  ethoxylated) ethyl (hydrogenated 

tallow  alkyl) ammonium  ethyl  sulfate. 
Bis  (2-hydroxyethyl,  ethoxylated)methyl(9-octa- 

decenyl)ammonium  chloride. 
Bis (2-hydroxyethyl ,  ethoxylated)methyloctadecyl- 
ammonium  chloride. 


ARC, 

ASH, 

ENO, 

GNM. 

ARC, 

ASH, 

ENO, 

GNU. 

ARC. 

RH. 

ARC, 

ENO. 

ASH, 

nwL 

ARC, 

ASH, 

ENO, 

GNM. 

ARC. 

ARC, 

ASH, 

ENO. 

ARC, 

ASH, 

BRD, 

ENO. 

BRD. 

ENO. 

ARC, 

BRD, 

ENO, 

ONX. 

ARC, 

BRD, 

ONX. 

ARC, 

ASH, 

ENO. 

ARC, 

BRD, 

ONX. 

ARC, 

ASH, 

BRD, 

ENO. 

BRD. 

ARC, 

ENO. 

ARC, 

BRD, 

ONX. 

ENO, 

GNH. 

ARC, 

ASH, 

ENO, 

GNM,    SCO 

ASH. 

BRD, 

GNU. 

TCH. 

ACY. 

ACY. 

ACY. 

IVTC. 

NLC. 

CCY. 

ARC, 

X. 

LUR. 

CGY, 

NLC. 

GAF. 

IWC. 

NLC, 

HOA. 

ICI. 

ARC. 

ARC. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972— CONTINUED 


^lanufacturers  '    identification   codes 

Chemical 

(ac 

cording  to   list    in   table    3) 

Cationic  Swff ace- Active  Agents — Continued 

*Oxygen-containing  quaternary  ammonium  salts :--Continued 

Other  oxygen-containing  quaternary  ammonium 

salts--Continued 

(Coconut  oil   alkyl)bi5(2-hydroxyethyl,   ethoxy- 

ARC, 

VAC. 

lated)methylammonium  chloride. 

(Ethoxybeniy 1) dimethyl (octylphenoxy) ammonium 

RH. 

chloride. 

(Ethoxybenzyl)dimethyl(octyltolyloxy')  ammonium 

RH. 

chloride. 

l-Ethyl-2-(8-heptadecenyl)-l- (2-hydroxyethyl)-2- 

ICI, 

UVC. 

imidazolinium  ethyl   sulfate. 

N-Ethyl-N-hexadecylmorpholinium  ethyl    sulfate 

BRD, 

ICI. 

N-Ethyl-N- (soybean   oil    alkyl)morpholinium  ethyl 

ICI. 

sulfate . 

2-Hydroxytrimethylenebis[ (coconut   oil   alkyl]di- 

CGY. 

methyl ammonium  chloride] . 

TCC. 

tjuaternari zed  propoxyiatea  stearyi   amine 

ARC. 

(.juateman zea  propoxyiatea  taiiow  aiamme 

ARC. 

Ail   otner 

'Quaternary  ammonium  salts,   not   containing  oxygen: 

*Acyclic: 

*Bis(coconut   oil   alkyl)dimethylammonium  chloride 

ARC, 

ASH, 

END, 

GNM,    VAC. 

Bi5(coconut  oil   alkyl)dimethylammonium  nitrate 

ARC. 

*Bis(hydrogenated  tallow   alkyl)dimethylammonium 

ARC, 

ASH. 

END, 

GNM,    VAC. 

chloride. 

Bis (hydrogenated  tallow   alkyl)dimethylammonium 

PR.X. 

methyl    sulfate. 

(Coconut  oil   alkyl)trimethylammonium  chloride 

ARC, 

ASH. 

Didecyldi methyl ammonium  chloride 

BRD. 

Didodecyldimethylammonium  bromide 

ONX. 

Dimethylbis (mixed   alkyl)    and   trimethyl (mixed 

GNfl. 

alkyl)ammonium  chloride. 

Dimethylbis (9 -octadecenyl) ammonium  chloride 

GNM. 

Dimethylbis (soybean   oil    alkyl) ammonium  chloride 

ARC. 

Dime thy Idioctadecyl ammonium  chloride 

ASH, 

ONX, 

PG. 

ON.X. 

uimetnyiai octaaecyi ammonium  metnyi    suirate 

Dioctyldimethyl ammonium  chloride 

BRD. 

Dodecyltrimetliyl ammonium  bromide 

DUP. 

Dodecyltrimethylammonium  chloride 

ARC, 

CHP, 

GNM, 

WTC. 

Ethyldimethyl (mixed   alkyl)ammonium  ethyl   sulfate 

DEX, 

JOR, 

TCC. 

Ethyldime thy 1(9 -octadecenyl) ammonium  bromide 

ONX. 

Ethylhexadecyldimethylammonium  bromide 

FIN. 

Hexadecyl trimethyl ammonium  bromide 

DUP, 

FIN. 

♦Hexadecyl trimethyl ammonium  chloride 

ARC, 

BRD, 

VAC. 

Hexadecyl trimethyl ammonium  p-toluenesulfonate 

FIN. 

(Hydrogenated  tallow  alkyl) trimethylammonium 

END. 

chloride. 

Me thyltrioctyl ammonium  chloride 

GNM. 

N,N,N' ,N' ,N'-Pentamethyl-N-(tallow    alkyl)tri- 

ARC, 

GNM. 

methylenebis [ammonium  chloride]. 

Trimethyl (mixed   alkyl) ammonium  chloride 

NLC. 

Trimethyloctadecylammonium  chloride 

ARC. 

Trimethyl (soybean   oil    alkyl) ammonium  chloride 

ARC, 

END. 

♦Trimethyl (tallow   alkyl) ammonium  chloride 

ARC, 

ASH 

ENO, 

GNM. 

Trime thy Itetradecyl ammonium  bromide 

FIN. 

All   other 

BRD, 

GNM 

ICI, 

STC. 

♦Benzenoid: 

1-  (2-Aminoethyl)-l-ethyl-2- (8-heptadecenyl-2- 

EFH. 

imidazolinium  bromide. 

Benzylalkylpyridinium  ammonium  chloride 

KTC. 

♦Benzyl (coconut   oil   alkyl) dimethylammonium 

ARC, 

CRT, 

DEP, 

END,    HLI,    LUR,    TXT,    KTC. 

chloride. 

*Benzyldimethyl (mixed  alkyl) ammonium  chloride 

AAC, 

BRD 

FIN, 

ONX,    RH,    TXT,    VAC. 

SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--C0NT INUED 


Cationia  Sicpfaae-Active  Agents — Continued 

'Quaternary  ammonium  salts,    not   containing  oxygen- - 
Continued 
*Benzenoid-- Continued 

*  Benzyl  dime  thy  loot adecylammonium  chloride 

Benzyldimethyl  (tallow   alkyl)aiiunonium  cliloride 

Benzyldime thy Itetradecyl ammonium  chloride 

Benzyldodecyldi methyl  ammonium   chloride 

Ben zylhexadecy Id imethyl ammonium  chloride 

Benzyl Chydrogenated  tallow  alkyl)dimethylammonium 
chloride. 

l-Benzyl-2-picolinium  bromide 

1-Benzylpyridinium  chloride 

*Benzyltrime thy 1 ammonium  chloride 

(3, 4- Dichlorobenzyl)dodecyldimethyl ammonium 
chloride . 

(Dodecylbenzyl) triethylammonium  chloride 

{Dodecylbenzyl)trimethylammoniura  chloride 

2-Dodecylisoquinolinium  bromide 

(Dodecylme thy Ihenzylltrime thy 1 ammonium  chloride 

1-Dodecylpyridinium  chloride 

(E thy Iben zy 1 ) dimethyl (mixed  alky 1 ) ammonium 
chloride, 

1- (Mixed   alkyl)quinolinlum  ethylsulfate 

l-Phenethyl-2-picolinium  bromide 

Nonionio  Surface- Active  Agents 

*Carboxylic   acid  amides : 

*Diethanolamine  condensates    (amine/acid  ratio=2/l): 

*Capric  acid 

Castor   oil   acids 

*Coconut  oil   acids 

*Coconut  oil   and  tallow  acids 

* Laurie  acid 

Laurie  and  myristic  acids 

Linoleic  acid 

Mixed  vegetable  oil   acids 

*01eic   acid 

Pe 1 argoni c  acid 

*Stearic  acid 

*Tall   oil   acids 

Tallow    acids 

*Diethanolamine  condensates    (other  amine/acid 
ratios) : 
*Coconut  oil   acids    (amine/acid  ratio=l/l) 

Coconut   oil   acids    (amine   acid  ratio  unspecified)-- 
*Lauric  acid   (amine/acid  ratio=l/l) 

Laurie  and  myristic  acids  (amine/acid  ratio=l/l)-- 
Linoleic  acid   (amine/acid  ratio=l/l) 

*01eic  acid   (amine/acid  ratio=l/l) 

Palmitic  and  stearic  acid  (amine/acid  ratio=l/l)-- 
Rapeseed  oil   acids    (amine/acid  ratio=2.6/l) 

•Stearic  acid   (amine/acid  ratio=l/l) 

Stearic   acid    (amine/acid  ratio=2.7/l) 


Manufacturers'    identification   codes 
(according   to   list    in   table   3) 


BRD, 

FIN, 

HLI, 

ONX, 

RH, 

TNI, 

VAC 

END. 

FIN, 

SNK. 

FIN, 

ONX, 

SDH. 

ONX. 

ENO, 

ONX. 

FIN. 

DEP. 

CHP, 

CIN, 

CRT, 

TCC. 

ONX, 

VAC. 

PC. 

\'AC , 

IVTC. 

ONX. 

RH. 

BRD, 

ONX. 

CCY,    SCP,   TCH. 

CLI,    FNX,   NTL. 

ACT,   AKS,   ARD,   ARL,   AZS,    BSW,    CHP.   CLI,    CTL,    DA,    DEP, 
EFH,    FNX,    HLI,   HRT,   JOR,    KNP,    LUR,   MCP,   MOA,   MRV, 
ONX,    PC,    PG,    PNX,   PVO,    SBC,    SCP,    SEY,    STP,   TCH, 
TXC,   TXN,    UNN,   U\'C,   VAC,   VAL,   VND,   WTC,    x. 

ACT,   CLI,    CRT,    ECC,    ESS,    MOA,    PC,    PVO,    SOS. 

ARD,   CLI,    DA,    ECC,   HLI,    ONX,    PG.   WON. 

FNX,    HLI,   MOA,    PVO,    STP. 

VND. 

HLI. 

CCW,    CLI,    EMR.    FNX.    PVO,    STP. 

EMR,    TCH. 

CLI,    DA,    EMR,    ECC.   JOR,   mV ,   ONX,    SCO,    TXC,   VAL. 

EFH,   MCP,   MOA,   MRV.    SOS. 

SOS.    1«TC. 


ARD.   AZS.    CCL.   CCY,    CIN,   CLI,    CTL,    FNX,    HLI,   JRG,    MOA, 
MRV,    ONX,    PIL,    SBC,    SEY,    STP,   TCC,   TCH,    TXN,   TXT, 
VAC,    IVTC. 

CON,   JRG. 

ARD,    CLI,    CTL,    HIK,   HLI,    LEV,   MOA.   ONX.    SBC,    TCH,   TXN, 
VAC,   IVTC. 

CLI,    TXT. 

MOA,    SBC. 

CGY,    HLI,    SBC,    SCP,   TCC,   TCH,   TXT. 

MCP. 

EFH. 

CGY,    ECC,    EMR.    FNX,    MRV,   RPC,    m'C. 

EFH. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Surface-active  agents  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to   list   in   table   3) 


Nonionia  Surface-Active  Agents — Continued 

*Carboxylic  acid  amides--Continued 

*Diethanolainine  condensates    (other  amine/acid 
ratios) --Continued 

Tall   oil   acids    (amine/acid  ratio=l/l) 

Tall  oil  acids    (amine/acid  ratio=2.7/l) 

Tallow  acids    (amine/acid  ratio=l/l) 

All  other 

*Ethanolamine  and  isopropanolamine  condensates: 
♦Coconut  oil   acids   -   ethanolamine  condensate 

(amine/acid  ratio=2/l). 
•Coconut  oil  acids   -   ethanolamine  condensate 
(amine/acid  ratio=l/l). 
Coconut   oil   acids    -   ethanolamine   condensate, 
ethoxylated. 

Coconut   oil   acids   -   isopropanolamine  condensate 

Hydrogenated   castor  oil   acids   -   ethanolamine 
■    condensate    (amine/acid  ratio=2/l). 
Hydrogenated  tallow  acids   -   ethanolamine 

condensate    (amine/acid  ratio=2/l) . 
Laurie  acid  -   ethanolamine   condensate    (amine/acid 

ratio=2/l) . 
Laurie  acid  -   ethanolamine   condensate   (amine/acid 
ratio=l/l) . 

Laurie  acid  -   isopropanolamine   condensate 

Laurie  and   myristie   acids   -   ethanolamine 

condensate    (amine/acid  ratio=l/l) . 
Laurie  and  myristie  acids   -   isopropanolamine 

condensate. 
Oleic  acid  -  ethanolamine   condensate    (amine/acid 

ratio=l/l) . 
Oleic   acid   -   ethanolamine   condensate,    ethoxylated-- 
Stearie  acid  -  ethanolamine   condensate    (amine/acid 

ratio=2/l) . 
Stearic  acid  -   ethanolamine  condensate   (amine/acid 

ratio=l/l) . 
Stearic  acid  -   ethanolamine  condensate   (amine/acid 

ratio=l/2) . 
Tallow   acids   -   ethanolamine  condensate    (amine/acid 
ratio=l/l) . 

All   other 

*Carboxylic  acid  esters: 
*Anhydrosorbitol  esters: 

Anhydrosorbitol  dioleate 

*Anhydrosorbitol  monoester  of  tall  oil  acids 

*Anhydrosorbitol  monolaurate 

Anhydrosorbitol  mono- ol eat e 

*Anhydrosorbitol  raonopalmitate 

•Anhydrosorbitol  monostearate 

Anhydrosorbitol  sesquioleate 

Anhydrosorbitol  triester  of  tall  oil  acids 

Anhydrosorbitol  trioleate 

Anhydrosorbitol  tristearate 

*Diethylene  glycol  esters: 

Diethylene  glycol  dioleate 

*Diethylene  glycol  distearate 

Diethylene  glycol  monoester  of  coconut  oil  acids — 

Diethylene  glycol  monoester  of  tallow  acids 

•Diethylene  glycol  monolaurate 

Diethylene  glycol  mono-oleate 

Diethylene  glycol  monoricinoleate 

•Diethylene  glycol  monostearate 

Diethylene  glycol  sesquiester  of  tall  oil  acids 

•Diethylene  glycol  sesquilaurate 

Diethylene  glycol  sesquistearate 


ECC, 
EFH. 
RPC, 
ORO, 

CTL, 

ARD, 


TCH. 
STP. 

PRX,  STP,  TCH,  VAC,  VND,  IVTC. 

CLI,  HLI,  HUH,  MOA,  PG,  STP,  UVC. 

STP. 


STP, 

MOA. 

GLY, 

NTL. 

GLY. 

ARC, 

CTL, 

PRX. 

ARD. 

CLI, 

MOA. 

MOA. 

LEV, 

TXT. 

VPC. 

ARD, 

DA, 

GAF. 

CLI. 

MOA, 

VND. 

HAL, 

SEY. 

SCP. 

ROB, 

MCP, 

TXN. 

ICl. 

GLY, 

HDG, 

ICI, 

TCH. 

GLY, 

HDG, 

ICI, 

SYL 

TCH 

GLY, 

HDG, 

ICI, 

PVO 

TCH 

GLY, 

HDG, 

ICI, 

TCH 

GLD, 

GLY, 

HDG. 

ICI 

PVO 

GLY, 

HDG. 

GLY. 

GLY, 

ICI, 

TCH. 

GLY, 

ICI, 

PVO. 

GLY. 

ARC, 

ECC, 

GLY, 

VAL 

AAC, 

DA. 

QCP. 

CCW, 

GLY, 

HAL, 

HDG 

ARC, 

EMR. 

GLY. 

ARC, 

CHP, 

CLI, 

DA, 

HAL, 

ECC, 

WTC. 

ARC, 

GLY, 

mi. 

IVM. 

SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--CoNTINUED 


Manufacturers'    identification  codes 
(according  to  list   in   table   3) 


Nonionic  Surface-Active  Agents — Continued 

*Carboxylic  acid  esters — Continued 
*Ethoxylated  anhydrosorbitol  esters: 

Ethoxylated   anhydrosorbitol   monolaurate 

*Ethoxylated   anhydrosorbitol  mono-oleate 

Ethoxylated   anhydrosorbitol   monopalmitate 

'Ethoxylated  anhydrosorbitol   monostearate 

Ethoxylated   anhydrosorbitol   monotallate 

Ethoxylated   anhydrosorbitol   triester  of  castor 

oil   acids. 
Ethoxylated   anhydrosorbitol    triester  of  tall   oil 
acids. 

Ethoxylated   anhydrosorbitol    trioleate 

•Ethoxylated  anhydrosorbitol   tristearate 

♦Ethoxylated  sorbitol   esters: 

Ethoxylated   sorbitol  beeswax  ester 

Ethoxylated   sorbitol   distearate 

Ethoxylated  sorbitol  heptaoleate 

Ethoxylated   sorbitol  hexaester  of  tall    oil    acids-- 

Ethoxylated   sorbitol  hexaoleate 

Ethoxylated  sorbitol   lanolin  ester 

Ethoxylated   sorbitol   mono-oleate 

Ethoxylated  sorbitol   monostearate 

Ethoxylated  sorbitol   oleate,    acetylated 

Ethoxylated   sorbitol  nentaester  of  tall   oil    acids- 

Ethoxylated  sorbitol  nentalaurate 

Ethoxylated   sorbitol   pentaoleate 

Ethoxylated   sorbitol    tetraester  of   lauric   and 

oleic   acids. 
Ethoxylated   sorbitol   tetraester  of  tall   oil    acids- 

Ethoxylated  sorbitol   tetraoleate 

♦Ethylene   glycol   esters: 

Ethylene   glycol  distearate 

Ethylene   glycol  mono-oleate 

Ethylene  glycol  monostearate 

Ethylene  glycol   sesquistearate 

All   other 

♦Glycerol  esters: 

♦Complex  glycerol   esters: 

Glycerol   ester  ethoxylated 

Glycerol    lactate   esters   of  fatty  acids 

Glycerol  mannitan   laurate 

Glycerol  monoester  of  mixed  fatty  acids, 
acetylated. 

Glycerol   mono-oleate,   acetylated 

Glycerol   monostearate,    succinylated 

Glycerol   trilaurate  myristate 

♦Glycerol   esters   of  chemically  defined  acids: 

Glycerol   di oleate 

Glycerol   di laurate 

Glycerol   distearate 

Glycerol  monocaprylate 

♦Glycerol   monolaurate 

♦Glycerol   mono-oleate 

♦Glycerol  monoricinoleate 

♦Glycerol  monostearate 

♦Glycerol  esters   of  mixed  acids: 

Glycerol  monoester  of  coconut  oil   acids 

Glycerol  monoester  of  cottonseed  oil   acids 


AAC,  GLY,    HDG,    ICl,    SYL,   TCH. 

AAC,  ARC,    GLY,    HDG,    ICl ,    PVO,    SYL,   TCH. 

AAC,  ICI,    TC}1. 

AAC,  GLY,    HDG,    ICI,    PVO,    TCH. 

1«TC. 

ARC. 

ICI,    TCH. 

AAC,    GLY,    ICI,    TCH. 

AAC,    GLY,    HDG,    ICI,    PVO,   TCH. 

ICI. 

ICI. 

ICl. 

ICI,    TCH. 

GLY,    ICI,    TCH. 

ICI. 

ICl. 

TCIK 

ICI. 

WTC. 

ICl. 

ICI. 

ICI. 

ICl. 
ICl. 

ARC,    EMR,    HUI1. 

EFH. 

ARC,    CLI,    GLY,    HAL,   HDG,    KNP,   TCH,    VND,   WM. 


GLY. 
GLD. 
GLY . 
EKT. 


EKT. 
GLY. 

ARC,    HAL. 

VND. 

ARC,    ICl,    IVTC. 

ARC,  pvn. 

ARC,    GLY,    HAL. 

ARC,    CCW,    CHP,    DA,    EFH,    EMR,    GLY,    HAL,    HDG,    PVO,    TCH, 

\m,   \«TC. 
CCW,    DA,    HDG. 
ARC,    ASH,    BLS,    CHL,    DA,    EFH,    EMR,    FNX,    GLY,    GRO,    HAL, 

HDG,    HRT,    LUR,    PG,    PVO,    SCP,    SOS,   TCC,   TCH,    VND, 

WM,    WTC. 

PVO,   WM. 
EKT. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER.    1972--CoNTINUED 


Manufacturers'    identification   codes 
(according  to   list    in   table   3} 


Nonionic  Surface- Active  Agents — Continued 

*Carboxylic   acid   esters- -Continued 
♦Glycerol   esters--Continued 

♦Glycerol   esters   of  mixed   acids--Continued 

♦Glycerol   monoester  of  hydrogenated   cottonseed 

oil   acids. 
♦Glycerol   monoester  of  hydrogenated  soybean  oil 
acids. 

Glycerol   monoester  of  hydrogenated  tallow   acids 

Glycerol   monoester  of   lard   acids 

Glycerol  monoester  of  peanut   oil   acids 

Glycerol  monoester  of  tall  oil   acids 

Glycerol  monoester  of  tallow   acids 

Glycerol    sesquiester  of  hydrogenated  tallow   acids- 

Glycerol   sesquiester  of  tall   oil   acids 

All   other 

♦Natural  fats  and  oils,  alkoxylated: 

♦Castor  oil,  ethoxylated 

Castor  oil,  propoxylated 

Com  oil,  ethoxylated 

♦Hydrogenated  castor  oil,  ethoxylated 

Lanolin,  ethoxylated 

All  other 

♦Polyethylene  glycol  esters: 

♦Polyethylene  glycol  esters  of  chemically  defined 
acids: 

•Polyethylene  glycol  dilaurate 

♦Polyethylene  glycol  dioleate 

Polyethylene  glycol  distearate 

Polyethylene  glycol  methylcarbitol  maleate 

Polyethylene  glycol  monoisostearate 

♦Polyethylene  glycol  monolaurate 

♦Polyethylene  glycol  mono-oleate 

Polyethylene  glycol  mono-oleate,  etlioxylated 

Polyethylene  glycol  monopalmitate 

Polyethylene  glycol  monopelargonate 

♦Polyethylene  glycol  monostearate 

Polyethylene  glycol  sesquioleate 

All  other 

♦Polyethylene  glycol  esters  of  rosin  and  tall  oil 
acids ; 

Polyethylene  glycol  diester  of  tall  oil  acids 

Polyethylene  glycol  ester  of  tall  oil  acids 

Polyethylene  glycol  monoester  of  tall  oil  acids — 
Polyethylene  glycol  monoester  of  tall  oil 

acids,  ethoxylated. 

Polyethylene  glycol  sesquiester  of  rosin  acids 

Polyethylene  glycol  sesquiester  of  tall  oil 

acids. 
♦Polyethylene  glycol  esters  of  other  mixed  acids: 
Polyethylene  glycol  diester  of  trimerized  castor 

oil  acids. 
Polyethylene  glycol  ester  of  palmitic,  stearic, 

and  coconut  oil  acids. 
Polyethylene  glycol  monoester  of  coconut  oil 

acids. 


GLD,  LEV,  Wi. 

A.SH,  F.KT,  GLD,  NIV,  PVn ,  TCH. 

TCH. 
EKT,  GLD. 

pvn. 

EFH. 
BFP. 
JRG. 
SLM. 
EKT,  GLD,  ICI,  LEV. 

AAC,  DA,  DUP,  GAF,  ICI,  NLC,  NIL,  PVO,  SYL,  TCH,  TMH, 

IVTC. 
TCH. 
TCH. 

DA,  ICI,  SYL,  TCH. 
AAC,  CRD,  CRN,  ICI,  PR\,  TCH. 
ARC,  DA. 


ARC,  DA,  EFH,  GLY,  HAL,  HDG,  TCH,  IVM. 

ARC,  CGY,  CLD,  DA,  EFH,  GLY,  HAL,  HDG,  NLC,  TCH,  UVC, 

VND,  mi. 
ARC,  EFH,  FNX,  GLY,  HAL,  HDG,  TCH. 
CCA. 
TCH. 
AAC,  ARC,  CCA,  CGY,  DA,  GLY,  HAL,  HDG,  ICI,  JOR,  KNP, 

HCP,  TCH,  m'C. 
AAC,  ARC,  CCA,  CGY,  CHP,  CLD,  CRT,  DA,  DEX,  EFH,  GAF, 

GLY,  HAL,  HDG,  ICI,  ONX,  PVn,  SCP ,  TCH,  UVC,  VAC, 

Wl,  IVTC. 
ICI. 
ICI. 

EUR,  TCH. 
khC,   AKS,  ARC,  CGY,  CHP,  CRT,  DA,  DEP,  DEX,  EFH,  EMR, 

GAF,  GLY,  HAL,  HDG,  HRT,  ICI,  KNP,  ONX,  PC,  PVO, 

TCC,  TCH,  VND. 
ICI,  TCH,  WTC. 
SEY. 


EFH,  GLY. 
TCH. 
GLY. 
NLC,  TCH. 

HPC. 

ARC,  ICI,  MON,  PVn,  SLH,  SM,  WTC. 


GLY. 

MCP. 
GLY. 


SURFACE-ACTIVE  AGENTS 
TABLE  2, --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to   list    in   table   3) 


Nonionia  Surface- Active  Agents — Continued 

*Carboxylic  acid  esters--Continued 

*Polyethylene   glycol   esters--Continued 

*Polyethylene   glycol  esters   of  other  mixed  acids-- 
Continued 
Polyethylene  glycol  monoester  of  coconut  oil 

acids,    ethoxylated. 
Polyethylene   glycol   sesquiester  of   castor  oil 
acids. 
*Polyethylene    glycol    sesquiester  of  coconut   oil 
acids. 

Polyethylene   glycol   sesquiester  of  tallow   acids 

All   other 

*Polyglycerol  esters: 

Polyglycerol  ester  of  tall  oil  acids 

Polyglycerol  mono- ole ate 

Polyglycerol  raonostearate 

*Propanediol  esters: 

1,2 -Propanediol  dioleate 

1,2- Propanediol  distearate 

1,3-Propanediol  monoester  of  coconut  oil  acids 

1,2- Propanediol  monolaurate 

1,2- Propanediol  monomyri state 

1,2 -Propanediol  mono- ol eat e 

* 1,2- Propanediol  monostearate 

1,2- Propanediol  sesquiester  of  h\*drogenated  tallow 
acids. 

All  other 

Miscellaneous   carboxylic  acid  esters: 

Anhydrosorbitol   glycerol  monolaurate 

Ethoxylated  glycerol  sesquiester  of  mixed  fatty 
acids. 

Ethoxylated   1,2-propanediol  monostearate 

2-Hydroxymethyl-2-butene-l,4-diol   mononelargonate — 
Laurie   acid  esters   of  glycerol    and  ethoxylated 
nonylphenol . 

Methylglucoside   1 aur  ate 

Mixed  esters   of  stearic   acid 

Mixed  polyhydric  alcohols   triester  of  tall  oil 
acids . 

Oleic  acid  esters  of  ethoxylated  nonylphenol 

Pentaecrythritol   distearate 

Polyalkylene   glycol   adipate 

Polyalkylene   glycol   di fumarate 

Polypropylene   glycol    monoester 

Poly-propylene  glycol  mono-oleate 

Polypropylene  glycol  raonostearate 

All   other 

*Ethers : 

*Benzenoid  ethers: 

*Alkylphenol    -    formaldehyde   condensates,    alkoxylated: 

Alkylphenol,    ethoxylated 

(Mixed   alkyl)phenol    -    formaldehyde,    alkoxylated 

Nonylphenol    -    formaldehyde,    alkoxylated 

tert-flctylphenol   -   formaldehyde,   ethoxylated 

All   other 

Derivatives   of  ethoxylated  phenols 

Diisobutylphenol ,   ethoxylated 

Dinonylphenol ,   ethoxylated 

*Dodecylphenol ,    ethoxylated 

Iso-octylphenol,   ethoxylated 


AAC, 

ICI. 

CGY. 

ARL, 

MRT, 

PG, 

VND. 

sns. 

ACT, 

ECC, 

SIR 

SM, 

AZS. 

HDG, 

pvn, 

TCH 

VND. 

ASH, 

pvn. 

TCH 

X. 

ARC. 

Wl. 

ARC, 

HAL, 

PVO 

SBC. 

ICI. 

EFH, 

HAL. 

ARC, 

CCW, 

EKT 

GLD, 

JRG. 

ICI. 
ICI. 

ICI. 
ICI. 
TCC. 

HDG. 
EUR. 
ICI. 

EFH. 

GLY,    QCP,   VAL. 

NLC. 

WTC. 

sns. 

HDG. 
HDG. 
CCW,    TCH,    WM. 


IVTC. 

NLC,  NTL. 

NLC,  WTC. 

DA,    SDW. 

PVO,  WTC. 

RH. 

GAF. 

ARD,  GAF,    STP,   TCH. 

ACC,  GAF,   HON,   TCH,   TMH,    UCC. 

APX,  DA,   OHC,    RH. 


SYNTHETIC  ORGANIC  CHEMICALS^  1972 
TABLE  2. --Surface-active  agents  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY  MANUFACTURER^    1°72--C0NT!NUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


Nonionic  Surface- Active  Agents — Continued 

*Ethers :- -Continued 

*Benzenoid  ethers: --Continued 

(Mixed  alkyl)phenol,   ethoxylated 

(Mixed  alkyl5phenoxypoly(ethyleneoxy) ethyl 
chloride. 
*Nonylphenol,   ethoxylated 

Nony Iphenoxypoly (ethyleneoxy) ethyl   iodide 

n- Oc ty Ipheno 1,   ethoxylated 

Phenol,   ethoxylated 

Styrenated  phenol,   ethoxylated 

Tetradecylphenol,   ethoxylated 

Tridecylphenol,   ethoxylated 

Xylenol ,   ethoxylated 

All  other 

*Nonbenzenoid  ethers : 

*Linear  alcohols,   alkoxylated: 

Coconut  oil   alcohol,   ethoxylated 

*Decyl   alcohol,   ethoxylated 

Decyl   and  octyl   alcohols,   ethoxylated 

Decyl   and  octyl   alcohols,   ethoxylated  and 
propoxylated. 

Decyloxypoly (ethyleneoxy) ethyl   chloride 

Derivative  of  ethoxylated  primary  alcohol 

*Dodecyl   alcohol,   ethoxylated 

*Hexadecyl    alcohol,    ethoxylated 

*Mixed   linear  alcohols,   ethoxylated 

*Mixed   linear  alcohols,   ethoxylated  and 
propoxylated. 

*9-0ctadecenyl   alcohol,   ethoxylated 

*Octadecyl   alcohol,   ethoxylated 

Sperm  oil   alcohol,   ethoxylated 

Tallow   alcohol,   ethoxylated 

Wool  wax  alcohols,   ethoxylated 

*Other  ethers   and   thioethers: 

*Poly(ethylene   and  propylene) glycols : 

Poly(mixed  ethylene,   propylene) glycol 

Polypropylene   glycol,    ethoxylated 

tert-Dodecyl  mercaptan,   ethoxylated 

Ethylhexanol,   ethoxylated 

Glucose,    ethoxylated 

Glycerol ,   alkoxylated 

Isodecyl   alcohol,   ethoxylated 

Iso-octyl   alcohol,   ethoxylated 

Methylglucoside,   propoxylated 

Mixed   alcohols,    ethoxylated 

Rosin  alcohol,   ethoxylated 

Sorbitol,   ethoxylated 

2,4,7,9-Tetramethyl-5-decyne-4,7-diol , 
ethoxylated. 
*Tridecyl   alcohol,   ethoxylated 

Tridecyl   alcohol,  propoxylated  and  ethoxylated- 

Trimethylheptanol ,    ethoxylated 

♦Trimethylnonyl   alcohol,   ethoxylated 

Trimethylolpropane ,   alkoxylated 

All   other 

Other  nonionic  surface-active  agents: 

Dodecylbenzenesulfonic  acid  -  diethanolamine 
condensate,   fatty  acid  monoester. 

Dodecyl  alcohol,   ethoxylated  and  phosphated 

Octyl  phosphate,   ethoxylated 

Tri(castor  oil  alkyl)phosphate 

All   other 


NTL,    PRX,   TCH. 
GAP,    NIC. 


,    DA,    GAP,    HDG,    ICl,   JCC,   MON,    OMC,    RH,    STP,    TCH, 
mi,   UCC,   VAC,    WTC. 


DA,    GAP,    ICI,   JCC,   TCH,    UCC. 


GAP. 

TCH. 

CLY, 

DA. 

ORn. 

TCH. 

NLC. 

GAP, 


GLY. 

GAP,    ICl,    TCH. 

GAP,    GLY,    TCH. 

GAP. 

GAP. 

RH. 

AAC,  DUP,    GAP,    HDG,    ICI,   OMC,    PVO,    SNW,    UCC,   WTC. 

AAC,  CGY,    ICI,    VAC,   TCH. 

AAC,  Cn,    DA,    GAP,    HDG,   JCC,    NLC,    RH,    SHC,    STP,    TCH, 

UCC,    WTC. 

JCC,  STP,    TCH,    UCC,    WYN. 

AAC,   ABC,   CGY,    CRN,   DA,    DUP,    GAP,    GLY,    ICI,   TCH,    VPC. 

CGY,    DA,    DUP,    GAP,    ICI,   HDG. 

CRD,   DUP. 

AAC. 

CRD. 


NLC,   UCC. 

NLC,    VAC,   IVTC,   IVYN. 

AAC,   UCC.   IVTC. 

TCH. 

RH. 

NLC. 

TCH. 

GAP. 

STP. 

CRN,    PVO. 

NLC,   VAC. 

TCH. 

GAP. 

AAC,  DA,    DUP,    GAP,    ICI,   JCC,   MON,   NLC,   OMC,    PVO,    SYL, 

TCH,   UCC,   IVTC. 

ICI,  JCC. 
TCH. 

HDG,  UCC,   VAC. 

HDG,  VAC,   IVTC,    IVYN . 
TCH. 

ACT. 

DUP. 
DUP. 
GLY. 
AIP,    STC. 


SURFACE-ACTIVE  AGENTS 
TABLE  3, --Surface-active  agents;  Directory  of  manufacturers,  1972 

ALPHABETICAL  DIRECTORY  BY  CODE 

[Names  of  manufacturers  that  reported  production  or  sales  of  surface-active  agents  to  the  U.S.  Tariff  Commission  for 
1972  are  listed  below  in  the  order  of  their  identifcation  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

AAC 

Alcolac  Chemical  Corp. 

FIN 

Fine  Organics,  Inc. 

ABC 

ARC  Chemical  Corp. 

ACE 

Acme  Chemical  Co. 

GAF 

GAF  Corp.,  Chemical  Div. 

ACS 

Allied  Chemical  Corp.,  Specialty  Chemicals  Div. 

GLD 

Glidden  Durkee  Famous  Foods 

ACT 

Arthur  C.  Trask  Co. 

GLY 

Glyco  Chemicals,  Inc. 

ACY 

American  Cyanamid  Co. 

GNM 

General  Mills  Chemicals,  Inc. 

AES 

Amerace-Esna  Corp.,  Penetone  Div. 

GRC 

Chemed  Corp.,  Dubois  Chemicals  Div. 

AGP 

Armour- Dial,  Inc. 

CRD 

W.R.  Grace  5  Co.,  Polymer  §  Chemicals  Div. 

AIP 

Air  Products  5  Chemicals,  Inc. 

GRL 

Chemed  Corp.,  Vestal  Laboratories,  Inc. 

AKS 

Arkansas  Co. ,  Inc. 

GRO 

Millmaster  Onyx  Corp.,  A.  Gross  5  Co.  Div 

APX 

Apex  Chemical  Co.,  Inc. 

GYR 

Goodyear  Tire  6  Rubber  Co. 

ARC 

Armak  Co. 

ARD 

Ardmore  Chemical  Co. 

HAL 

CP.  Hall  Co.  of  Illinois 

ARL 

Arol  Chemical  Products  Co. 

HDG 

Hodag  Chemical  Corp. 

ASH 

Ashland  Oil,  Inc.,  Ashland  Chemical  Co.  Div. 

HEW 

Hewitt  Soap  Co. ,  Inc. 

ASY 

American  Synthetic  Rubber  Corp. 

HK 

Hooker  Chemical  Corp. 

ATR 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co. 

HLI 

Haag  Laboratories,  Inc. 

AZS 

AZS  Corp. : 

AZ  Products  Co.  Div. 

HMP 

W.R.  Grace  6  Co.,  Dewey  5  Almy  Chemical  Di 
Organic  Chemicals 

V.  , 

Lancaster  Chemical  Co.  Div. 

HNT 
HPC 

Huntington  Laboratories,  Inc. 
Hercules,  Inc. 

BAO 

Bayoil  Co. ,  Inc. 

HRT 

Hart  Products  Corp. 

BFP 

Breddo  Food  Products  Corp. 

HUM 

Kraftco  Corp.,  Humko  Products  Div. 

BLA 

Astor  Products,  Inc.,  Blue  Arrow  Div. 

BLS 

Beech-Nut,  Inc. 

ICl 

ICI  America,  Inc.  and  Specialty  Chemicals 

Div. 

BRD 

Lonza,  Inc. 

BSW 

Original  Bradford  Soap  Works,  Inc. 

JCC 
JOR 

Jefferson  Chemical  Co.,  Inc. 
Jordan  Chemical  Co. 

CCA  5 

Cincinnati  Milacron  Chemicals,  Inc. 

JRG 

Andrew  Jergens  Co. 

CCW 

CCL 

A.E.  Staley  Manufacturing  Co.,  Textile  Div. 

KAL 

Kali  Manufacturing  Co. 

CGY 

Ciba-Geigy  Corp.  and  Ciba  Pharmaceutical  Co. 

KNG 

Far-Best  Corp.,  O.L.  King  Div. 

CHL 

Chemol,  Inc. 

KNP 

Knapp  Products,  Inc. 

CHP 

C.H.  Patrick  f,  Co.,  Inc. 

CIN 

Cindet  Chemicals,  Inc. 

LAK 

Lakeway  Chemicals,  Inc. 

CLD 

Colloids,  Inc. 

LEA 

Leatex  Chemical  Co. 

CLI 

Clintwood  Chemical  Co. 

LEV 

Lever  Brothers  Co. 

CLY 

W.A.  Cleary  Corp. 

LIL 

Eli  Lilly  fi  Co. 

CO 

Contirental  Oil  Co. 

LKY 

Lake  States  Div.  of  St.  Regis  Paper  Co. 

COM 

Commercial  Solvents  Corp. 

LMI 

North  American  Chemical  Co. 

CON 

Concord  Chemical  Co.,  Inc. 

LUR 

Laurel  Products  Corp. 

CP 

Colgate-Palmolive  Co. 

CPP 

Charmin  Paper  Products  Co. 

MAR 

American  Can  Co. 

CRD 

Croda,  Inc. 

MCP 

Moretex  Chemical  Products,  Inc. 

CRN 

CPC  International,  Inc. 

MIR 

Miranol  Chemical  Co.,  Inc. 

CRT 

Crest  Chemical  Corp. 

MOA 

Mona  Industries,  Inc. 

CRZ 

Crown  Zellerbach  Corp.,  Chemical  Products  Div. 

MON 

Monsanto  Co. 

CST 

Charles  S.  Tanner  Co. 

MRA 

Crown-Metro,  Inc. 

CTL 

Continental  Chemical  Co. 

MRD 

Marden-Wild  Corp. 

CWP 

Consolidated  Papers,  Inc. 

MRT 

Morton  Chemical  Co.  Div.  of  Morton-Norwich 
ducts.  Inc. 

Pro- 

DA 

Diamond  Shamrock  Corp. 

MRV 

Marlowe- Van  Loan  Corp. 

DAN 

Dan  River,  Inc. 

MYW 

Stepan  Chemical  Co.,  Maywood  Div. 

DEP 

DePaul  Chemical  Co.,  Inc. 

DEX 

Dexter  Chemical  Corp. 

NCW 

Nostrip  Chemical  Works,  Inc. 

DOW 

Dow  Chemical  Co. 

NES 

Nease  Chemical  Co.,  Inc. 

DUP 

E.I.  duPont  de  Nemours  5  Co.,  Inc. 

NLC 

Nalco  Chemical  Co. 

DYS 

Davies- Young  Co. 

NMC 
NPR 

National  Milling  5  Chemical  Co.,  Inc. 
Safeway  Stores,  Inc. 

ECC 

Eastern  Color  5  Chemical  Co. 

NTL 

NL  Industries,  Inc. 

EFH 

E.F.  Houghton  6  Co. 

NW 

Northwestern  Chemical  Co. 

EKT 

Eastman  Kodak  Co.,  Tennessee  Eastman  Co.  Div. 

EMK 

Emkay  Chemical  Co. 

OMC 

01  in  Corp. 

EMR 

Emery  Industries,  Inc. 

ONX 

Millmaster  Onyx  Corp.,  Onyx  Chemical  Co. 

ENO 

Enenco,  Inc. 

ORO 

Chevron  Chemical  Co. 

ESS 

Essential  Chemicals  Corp. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972   • 
TABLE  3, --Surface-active  agents;     Directory  of  manufacturers,  1972--Continued 


Code 

Name  of  company 

Code 

Name  of  company 

PC 

Proctor  Chemical  Co.,  Inc. 

SOS 

Southern  Sizing  Co. 

PCH 

Peerless  Chemical  Co. 

SPA 

Scott  Paper  Co. 

PEK 

Peck's  Products  Co. 

stc 

Sou-Tex  Chemical  Co.,  Inc. 

PFZ 

Pfizer,  Inc. 

stp 

Stepan  Chemical  Co. 

PC 

Procter  5  Gamble  Co. 

SYL 

Magnolia  Industries,  Inc.,  Milliken  Chemical 

PIL 

Pilot  Chemical  Co. 

Div. 

PLX 

Plex  Chemical  Corp. 

PNX 

Murphy-Phoenix  Co. 

tcc 

Tanatex  Chemical  Corp. 

PRX 

Purex  Corp. ,  Ltd. 

tch 

Emery  Industries,  Inc.,  Trylon  Chemica 

Div. 

PSP 

Georgia-Pacific  Corp.,  Bellingham  Div. 

TCI 

Texize  Chemicals,  Inc. 

PVO 

PVO  International,  Inc. 

TEN 
TMH 

Cities  Service  Co.,  Copperhill  Operatic 
Thompson -Hayward  Chemical  Co. 

ns 

QCP 

Quaker  Chemical  Corp. 

TNA 

Ethyl  Corp. 

TNI 

Gillette  Chemical  Co.  Div.  of  Gillette 

Co. 

RAY 

ITT  Rayonier,  Inc. 

TXC 

Tex  Chem  Co. 

RBC 

Fike  Chemicals,  Inc. 

TXN 

Textilana-Nease,  Inc. 

RCD 

Richardson  Co. 

TXT 

Textilana  Corp. 

RH 

Rohm  5  Haas  Co. 

ROB 

Robeco  Chemicals,  Inc. 

UCC 

Union  Carbide  Corp. 

RPC 

Millmaster  Onyx  Corp.,  Refined-Onyx  Div. 

UDI 
UNN 

Petrochemicals  Co.,  Inc. 

United  Chemical  Corp.  of  Norwood 

S 

Sandoz,  Inc.,  Sandoz  Colors  §  Chemical  Div. 

IINP 

United  Chemical  Products  Corp. 

SBC 

Scher  Bros.  Inc. 

USR 

Uniroyal,  Inc.,  Chemical  Div. 

SBP 

Sugar  Beet  Products  Co. 

UVC 

Universal  Chemicals  Corp. 

SCO 

Scholler  Bros. ,  Inc. 

SCP 

Henkel,  Inc. 

VAC 

Northern  Petrochemical  Co. 

SDC 

Martin-Marietta  Corp. ,  Sodyeco 

VAL 

Valchem 

Sterling  Drug,  Inc. : 

VND 

Van  Dyk  5  Co. ,  Inc. 

SDH 

Hilton-Davis  Chemical  Co.  Div. 

VPC 

Baychem  Corp.,  Verona  Div. 

SDW 

Winthrop  Laboratories  Div. 

SEA 

Seabroad  Chemicals,  Inc. 

WAW 

W.A.  Wood  Co. 

SEY 

Seydel-Woolley  5  Co. 

WAY 

Philip  A.  Hunt  Chemical  Corp.,  Kayland 

Chemical 

SFS 

Stauffer  Chemical  Co.,  Specialty  Chemical  Div. 

Div. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

WBG 

White  f,  Bagley  Co. 

SID 

George  F.  Siddall  Co.,  Inc. 

WHI 

White  §  Hodges,  Inc. 

SLC 

Soluol  Chemical  Co.,  Inc. 

WHW 

Whittemore-Wright  Co.,  Inc. 

SLM 

Salem  Oil  6  Grease  Co. 

WIC 

Wica  Chemicals,  Inc. 

SM 

Mobil  Oil  Corp.,  Mobil  Chemical  Co., 
Chemical  Coatings  Div. 

WM 

Wilson  Pharmaceutical  5  Chemical  Corp. 
Wilson-Martin  Div. 

SNW 

Sun  Chemical  Corp.,  Chemicals  Div. 

WON 

Woonsocket  Color  5  Chemical  Co. 

SOC 

Standard  Oil  Co.  of  California,  Chevron 

WTC 

Witco  Chemical  Co.,  Inc. 

Chemical  Co. 

WVA 

Westvaco  Corp.,  Chemicals  Div.,  Polyche 

mical 

SOP 

Southern  Chemical  Products  Co. 

WYN 

Dept. 
BASF-Wyandotte  Chemicals  Corp. 

Note. --Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix. 


189 


PESTICIDES  AND  RELATED  PRODUCTS 


Pesticides  and  related  products  include  fungicides,  herbicides, 
insecticides,  rodenticides ,  and  related  products  such  as  plant  hormones, 
seed  disinfectants,  soil  conditioners,  soil  furaigants,  and  synergists. 
The  data  are  given  in  terms  of  100-percent  active  material;  they  thus 
exclude  such  materials  as  diluents,  eraulsifiers,  and  wetting  agents. 

U.S.  production  of  pesticides  and  related  products  in  1972  amounted 
to  1,158  million  pounds--!, 9  percent  greater  than  the  1,136  million 
pounds  reported  for  1971  (table  1).^  Sales  in  1972  were  1,Q22  million 
pounds,  valued  at  $1,092  million,  compared  with  946  million  pounds,  valued 
at  $979  million,  in  1971. 

The  output  of  cyclic  pesticides  and  related  products  amounted  to 
839  million  pounds  in  1972--1.4  percent  greater  than  the  828  million  pounds 
produced  in  1971.   Sales  in  1972  were  7.20  million  pounds,  valued  at  $890 
million,  compared  with  669  million  pounds,  valued  at  $819  million,  in  1971. 
Production  of  acyclic  pesticides  and  related  products  in  1972  amounted  to 
318  million  pounds,  compared  with  the  308  million  pounds  reported  for  1971, 
an  increase  of  3.3  percent.   Saxes  in  1972  were  302  million  pounds,  an  in- 
crease of  abci't  8^  percent  as  compared  to  the  277  million  pounds  reported 
in  1971;  the  value  of  sales  was  $202  million  in  1972,  compared  with  $160 
million  in  1971--an  increase  of  26.3  percent. 


1/  See  also  table  2  which  lists  these  products  and  identifies  the 
manufacturers  by  codes.  These  codes  are  given  in  table  3. 


552-743  O  -  74  -  13 


.SYNTHETIC  nPnANIC  CMFfllCALS,  1972 
TARLE  1. —Pesticides  and  related  products;     U.S.  production  and  sales,  1972 


[Listed  below  are  all  pesticides  and  related  products  for  which  any  reported  data  on  production  or  sales  may  be  pub- 
lished. (Leaders  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no 
data  were  reported.)  Table  2  lists  all  pesticides  and  related  products  for  which  data  on  production  or  sales  were 
reported  and  identifies  the  manufacturers  of  each] 


Production 


Sales 


Quantity 


Unit 
value' 


1,000 
pounds 


Grand  total 

Benzenoid 

Nonbenzenoid 

pesticides  and  related  products,  cyclic 

Total 

Fungicides ,  total 

Mercury  fungicides,  total 

Phenylmercuric  acetate  (PMA) 

Phenyl mercuric  oleate 

Other  mercury  fungicides 

Naphthenic  acid,  copper  salt 

Pentachlorophenol  (PCP) 

8-Quinolinol  (S-Hydroxyquinoline) ,  copper  salt 

All  other  cyclic  fungicides" 

Herbicides  and  plant  hormones,  total 

l,2-Dihydropyridazine-3,6-dione  (Maleic  hydrazide)  (MH) 

2,4-Dichlorophenoxyacetic  acid,  dimethylaitiine  salt 

All  other  cyclic  herbicides  and  plant  hormones- 

Insecticides  and  rodenticides,  total 

Aldrin-toxaphene  group'* 

Organophosphorus  insecticides,  total 

0,0-Dimethyl  O-p-nitrophenyl  phosphorothioate  (Methyl 
parathion) 

All  other  organophosphorus  insecticides^ 

All  other  cyclic  insecticides  and  rodenticides^ 

PESTICIDES  AND  RELATED  PRODUCTS,  ACYCLIC 
Total 

Fungicides,  total 

Dithiocarbamic  acid  salts' 

All  other  acyclic  fungicides' 

Herbicides  and  plant  hormones,  total 

Methanearsonic  acid  salts' 

All  other  acyclic  herbicides'" 


657,092 
500,606 


98,164 


854 

307 

279 

268 

2,206 

49,704 

40 

45,360 


4,472 

22,469 

344,789 


141,858 
95,461 


51,076 
44,385 


318,338 


30,698 
48,883 


liOOO 
pounds 

1,021,565 


1,000 
dollars 


581,107 

440,458 


88,530 


781 
284 
263 
234 
2,291 
48,355 

37,103 

282,094 


24,028 
258,066 


349,083 


140,150 
90,283 

52,438 
37,845 

118,650 


39,987 


34,857 
36,632 


681,768 
409,940 


58,192 


3,154 
1,382 

539 
1,233 

717 
6,783 

47,538 


9,311 
564,537 


65,919 
96,843 


23,576 
73,267 


202,095 


23,972 


17,382 
6,590 

55,110 


9,370 
45,740 


Per 
pound 


1.28 
2.03 


.27 
1.25 


See  footnotes  at  end  of  table. 


PESTICIDES  AND  RELATED  PRODUCTS 
TABLE  1,— Pesticides  and  related  products:     I'.S.  production  and  sales^  T'^72— Continued 


Quantity 


Unit 
value' 


PESTICIDES  AiND  RELATED  PRODUCTS,  ACYCLIC--Continued 

Insecticides,  rodenticides,  soil  conditioners  and 

fumigants,  total 

Methyl  bromide  (Bromomethane) 

Organophosphorus  insecticides' ' 

1 ,2-Dibromo-3-chloropropane  (DBCPJ 

All  other  acyclic  insecticides,  rodenticides,  soil 

conditioners  and  fumigants   


1,000 
pounds 


7,000 
pounds 


1,000 
do t tars 


Per 

pound 


24,633 
65,181 


104,295 


23,930 
59,734 
15,228 

91,490 


9,349 
76,507 

6,275 

30,882 


.34 


1  Lalculated  trom  rounded  tigures. 

2  Includes  captafol ,  captan,  dinocap,  DMTT,  folpet,  pentachloronitrobenzene,  8-quinolinol  (sales  only),  sodium 
pentachlorophenate,  tri-  and  tetra-chlorophenols  (including  2 ,4 ,5-trichlorophenol  and  its  salts),  and  others. 

3  Includes  acetanilide  compounds,  amiben  esters  and  salts,  barban,  benefin,  bensulide,  4-CPA  potassium  salt, 
2,4-D,  acid,  esters,  and  salts,  2,4-DB,  dicamba,  dimethylurea  compounds,  dinitrophenol  compounds,  isopropyl  phenyl- 
carbamates  (IPC  and  CIPC),  MCPA,  MH  (sales  only),  molinate,  NPA  picloram,  propanil,  silvex  and  its  esters,  2,4, 5-T 
acid  esters  and  salts,  triazines,  trifluralin,  uracils,  and  others. 

4  Includes  aldrin,  chlordan,  dieldrin,  endrin,  heptachlor,  and  toxaphene. 

5  Includes  azinphosmethyl ,  carbophenothion,  coumaphos ,  diazinon,  dioxathion,  fensulfothion ,  parathion,  ronnel, 
and  other  phosphorothioates  and  phosphorodithioates,  and  others. 

6  Includes  carbaryl ,  carbofuran,  chlorinated  insecticides  (BHC  +  lindane,  chlorobenzilate,  DDT,  dicofol,  endo- 
sulfan,  methoxychlor,  and  others),  insect  attractants,  DEET  and  other  insect  repellents,  small  amounts  of  rodenti- 
cides, piperonyl  butoxide  and  other  synergists,  and  others. 

7  Includes  ferbam,  maneb,  nabam,  and  zineb,  plus  the  remaining  dithiocarbamates  which  are  used  chiefly  as 
pesticides. 

8  Includes  dodine,  mercury  compounds,  PETD,  and  others. 

9  Includes  the  mono-  and  di-sodium  salts,  and  the  dodecyl-  and  octyl -ammonium  salts  of  methanearsonic  acid. 

10  Includes  cacodylic  acid,  CDAA,  dalapon,  thiocarbamate,  thiol  carbamate,  and  organophosphorus  herbicides,  sodiuii 
TCA,  and  others. 

11  Includes  DDVP,  dimethoate,  disulfoton,  ethion,  malathion,  monocrotophos ,  naled,  phorate,  and  other  organo- 
phosphorus insecticides. 

12  Includes  aldicarb,  DBCP  (production  only),  soil  conditioners  and  fumigants,  methomyl ,  small  quantities  of 
rodenticides,  and  others. 


Note. --Does  not  include  data  for  the  insect  fumigant,  p-dichlorobenzene  nor  the  fungicide,  o-phenylphenol. 
These  data  are  included  in  the  report  on  cyclic  intermediates. 

To  expedite  publication  of  this  report  it  was  necessary  to  estimate  data  for  two  small  companies. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2. --Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972 


[Pesticides   and  related  products   for  which  separate  statistics   are  given  in  table   1   are  marked  below  with  an 

asterisk    (*);    chemicals  not   so  marked  do  not   appear  in  table   1  because  the   reported  data  are  accepted   in  confidence 
and  may  not  be  published.      Manufacturers'    identification  codes   shown  below   are  taken   from  table   5.      An   x  signifies 
that   the  manufacturer  did  not   consent   to  his    identification  with  the  designated  product] 


Manufacturers'    identification  codes 
(according  to   list   in  table  3} 


PESTICIDES  AND  RELATED   PRODUCTS,    CYCLIC 

*Fungicides; 

Benzylbromo   acetate-- 

2, 6 -Bis  (dimethylamiTiomethyl)cvclohexanone 

2'-Rrorao-4'-hydroxyacetophenone 

5-Chloro-2-benzothiazolethiol ,    laurylpyridinium  salt 

Cyanomethylthiobenzothiazole 

2,4-Dichloro-6-(o-chloroanilino)-s-triazine 

1 ,4-Dichloro-2,5-dimethoxybenzene    (ChloronebJ 

1 ,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline  (Ethoxyquin)- 
3,5-Dimethyl-l,3,5-2H-tetrahydrothiadiazine-2-thione 
(DMTT) . 

Diphenylammonium  propionate 

5-Ethoxy-3-trichloromethyl-l ,2,4-thiadiazole 

Hexahydro-1 .3,5-triethyl-s-triazine 

Hexahydro-1 ,3,5-tris (2-hydroxyethyl)-s-tri3zine 

2-Mercaptobenzothia2ole,  monoethanolamine  salt 

*Mercury  fungicides: 

Dipheny Imercury  dodeceny Isuccinate 

•Phenylmercuric  acetate  (PMA) 

Phenylmercuric  ammonium  acetate 

Phenylmercuric  dimethyldithiocarbamate 

Phenylmercuric  hydroxide 

Phenylmercuric  lactate 

* Phenyl mercuric  oleate 

Phenylmercuric  propionate 

Phenylmercuric  succinate 

All  other  mercury  fungicides 

Methyl-N-benzimidazol-2-yl-N- (butylcarbomoyl)  carbamate 

(Benomyl) . 
2- (l-Methyl-n-heptyl)-4,6-dinitrophenyl  crotonate 

(Dinocap) . 
3- (2-Methylpiperidino) propyl- 3, 4-dichlorobenzoate 
(Piperalin) . 

*Naphthenic  acid,  copper  salt 

Pentachloronitrobenzene  (PCNB) 

*Pentachlorophenol  (PCP) 

Pentachlorophenol ,  sodium  salt 

*8-Quinolinol  (8-Hydroxyquinoline) ,  copper  salt 

N- CI ,1 ,2,l-Tetrachloro-ethylsulfenyl)-cis-'-4-cyclo- 
hexene-l,2-dicarboximide  (Captafol) . 

2,4,5,6-Tetrachloroisophthalonitrile 

2,3,4,6-Tetrachlorophenol 

N-Trichloromethylthio-4-cyclohexene-l,2-dicarboximide 
(Captan)  . 

N-Trichloromethylthiophthalimide  (Folpet) 

2,4 ,5-Trichlorophenol  acid  and  salts: 

2,4,S-Trichlorophenol 

2,4,5-Trichlorophenol,  ethanolamine  salt 

2,4,S-Trichlorophenol ,  sodium  salt 

2,4,6-Trichlorophenol 

*Herbicides  and  plant  hormones: 

4-Amino-3,5,6-trichloropicolinic  acid  (Picloram) 

2,4-Bis(isopropylamino)-6-methylthio-s-triazine 
(Prometryn) . 

5-Bromo-3-sec-butyl-6-methyluracil  (Bromacil) 

3-tert-Butyl-S-chloro-6-methyluracil  (Terbacil) 

N-Butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-p-toluidine 
(Benefin) . 

2-Butynyl-4-chloro-m-chlorocarbanilate    (Barban) 

2-Chloro-4,6-bisCethylamino)-s-triazine    (Simazine) 

2-Chloro-4,6-bis(isopropylamino)-s-triazine   (Propazine) 


MRK. 
MRK. 
BKM. 
VNC. 
BKM. 
CHG. 
DUP. 
MON. 
BKM,   MRK. 

MRK. 
OMC. 
VNC. 
EFH. 
VNC. 

TRO. 

CLY,   MRK,   TRO,    WRC. 

TRO. 

WRC. 

WRC. 

WRC. 

CLY,    HN,   TRO,    WRC. 

MRK. 

WRC. 

MAL. 

DUP. 

RH. 


CCA, 
OMC. 
DOW, 
DOW, 
FIS, 
ORO. 


DOW. 
SFC. 


DOW, 
GAF. 
DOW. 
DOW. 

DOW. 
CGY. 

ACN, 
DUP. 
LIL. 

GOC. 
CGY. 
CGY. 


FER,    HN,    MCI,    SHP,    VAL ,    WTTC . 

FRO,    MON,    RCI . 

RCI. 

HN,    MRK. 


PESTICIDES  AND  RELATED  PRODUCTS 
TABLE  2, --Pesticides  and  related  products  for  which  U,S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to   list    in  table   3) 


PESTICIDES  AND  RELATED  PRODUCTS,   CyCLIC--Continued 

*Herbicides  and  plant  hormones--Continued 

2-Chloro-2'  ,6'-diethyl-N-  (n-butoxyniethyl)acetanilide 

2-Chloro-2' ,6* -diethyl-N- (methoxymethyl)acetanilide 

(Alachlor] . 
2-Chloro-4-ethylamino-6-isopropylamino-s-triazine 

(Atrazine) . 

2-Chloro-N-isopropylacetanilide    (Propachlor) 

4-Chloro-2-methylphenoxy  butyric   acid 

N' -(4-Chlorophenoxy 3 phenyl   N,N-dimethylurea 

(Chloroxuron) . 

3- (p-Chlorophenyl)-l , 1-dimethylurea    (Monuron) 

3-  (p-Chlorophenyl)-l,l-diiiiethyIurea  trichloroacetate 

2;5-Dichloro-5-aminoben2oic  acid,    ammonium  salt 

2,5-Dichloro-5-aniinobenzoic   acid,   methyl   ester 

3,6-Dichloro-2-anisic   acid    (Dicamba) 

2,4-Dichlorobenzyltributylphosphonium  chloride 

2,5-Dichloro-6-nitrobenzoic  acid,    sodium  salt 

4- (2,4-Dichlorophenoxy}butyric  acid    (2,4-DB) 

3- (3,4-Dichlorophenyl) -1 , 1-dimethylurea    (Diuron) 

3- (3,4-Dichlorophenyl )-l-methoxy-l-methylurea    (Linuron)-- 

2,4-Dichlorophenyl-4-nitrophenyl  ether  (Nitrofen) 

3' ,4'-Dichloropropionanilide  (Propanil) 

*l,2-Dihydropyridazine-3,6-dione  (Maleic  hydrazide) (MH) 

N- (beta-0,0-Diisopropyl-dithiophosphorylethyl)benzene 

sulfonamide  (Bensulide) . 

N,N-Dimethyl-2,2-diphenylacetamide  (Diphenamid) 

Dimethyl -2, 3, 5,6 -tetrachloroterephthalate  (DCPA) 

Dinitrobutylphenol  (DNBP) 

Dinitrobutylphenol ,  aBBonium  salt 

Dinitrobutylphenol,  triethanolamine  salt 

Dinitrocresol,  sodium  salt 

2-Ethylamino-4-isopropyla«lno-6-methylmercapto-s- 

triazine  (Ametryne) . 

S- Ethyl (cyclohexyl)ethylthiocarbamate 

S-Ethyl  hexahydro-lH-azepine-1-carbothioate  (MolinateJ 

Gibberellic  acid 

3-Indolebutyric  acid 

Isopropyl  N- (3-chlorophenyl)carbamate  (CIPC) 

Isopropyl  N-phenylcarbamate  (IPC) 

1- (2-Methylcyclohexyl)-3-phenylurea  (Siduron) 

4-(Methylsulfonyl)-2,6-dinitro-N,N-dipropylaniline 

(Nitralin). 
1-Naphthaleneacetic  acid  and  derivatives: 

1 -Naphtha leneacet amide 

1-Naphthaleneacetic  acid  (NAA) 

1-Naphthaleneacetic  acid,  sodium  salt 

N-1-Naphthylphthalamic  acid  (NPA) 

7-Oxabicyclo[2.2. l]heptane-2,3-dicarboxylic  acid,  di- 

sodium  salt  (Endothall). 
Phenoxyacetic  acid  derivatives: 

4-Chloro-2-methylphenoxyacetic  acid  (MCPA) 

3,S-Dibrorao-4-hydroxybenzonitrile,  octanoic  acid  ester 
(Bromoxynil  octanoate) . 

2,4-Dichlorophenoxyacetic  acid  (2,4-D) 

2,4-Dichlorophenoxyacetic  acid  esters  and  salts: 

2,4-Dichlorophenoxyacetic  acid,  2-butoxyethyl  ester-- 
2,4-Dichlorophenoxyacetic  acid,  butoxypolypropylene- 
glycol  ester. 

2,4-Dichlorophenoxyacetic  acid,  n-butyl  ester 

2,4-Dichlorophenoxyacetic  acid,  sec-butyl  ester 

•2,4-Dichlorophenoxyacetic  acid,  dimethylamine  salt 


MON. 
MON 


MON. 
RDA. 
CGY. 

DUP. 

ACN. 

AMC,  GAP. 

GAP. 

VEL. 

SM. 

GAP. 

RDA. 

DUP. 

DUP. 

Rll. 

EGR,  MON,  RH. 

ACY,  ASL,  FNfT,  USR. 

SPA. 

CWN. 


DOW, 

EGR, 

PMN. 

DOW, 

PMN. 

DOW, 

FMN. 

FMN. 

CGV. 

SPA. 

SPA. 

ABB, 

MRK. 

ARA. 

PPG. 

PPG. 

DUP. 

SHC. 

AMC. 

■AMC. 

AMC, 

BKL. 

USR. 

PAS. 

CLY, 

RDA, 

RIV. 

RDA. 

DOW,  MON,  RDA. 

DOW,  RIV. 
DOW. 

RIV. 
DOW,  RDA. 

DOW,  PBI,  RDA,  RIV,  TMH . 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


PESTICIDES  AND  RELATED  PRODUCTS,   CYCLIC- -Continued 

•Herbicides   and  plant  horraones--Continued 
Phenoxyacetic   acid  derivatives--Continued 

2,4-Dichlorophenoxyacetic   acid  esters   and  salts-- 
Continued 
2,4-Dichlorophenoxyacetic  acid,   ethanolamine  and 

isopropanolamine  salt. 
2,4-Dichlorophenoxyacetic  acid,   iso-octyl   ester — 

2,4-Dichlorophenoxyacetic  acid,    isopropyl   ester 

2,4-Dichlorophenoxyacetic   acid,    lithium  salt 

2,4-Dichlorophenoxyacetic   acid,    sodium  salt 

2,4,S-Trichlorophenoxyacetic   acid    (2,4,5-T) 

2,4,5-Trichlorophenoxyacetic  acid  esters   and  salts: 
2,4,5-Trichlorophenoxyacetic   acid,    2-butoxyethyl 

ester. 
2,4,5-Trichlorophenoxyacetic  acid,   butoxypoly- 

propyleneglycol   ester. 
2,4,S-Trichlorophenoxyacetic  acid,   n-butyl   ester-- 
2,4,S-Trichlorophenoxyacetic   acid,    sec-butyl   ester 
2,4,5-Trichlorophenoxyacetic  acid,    iso-octyl   ester 
2,4,5-Trichlorophenoxyacetic  acid,    triethylamine 
salt. 
Polychloro-tetrahydro-methanoindene    (Polychlorodicyclo 
pentadiene)    isomers. 

2- (2,4,5-Trichlorophenoxy)propionic   acid    (Silvex) 

2- (2,4,5-Trichlorophenoxy)propionic  acid  esters   and 
salts: 
2- (2,4,5-Trichlorophenoxy)propionic   acid,    2-butoxy- 
ethyl  ester. 
2- (2,4,5-Trichlorophenoxy)propionic  acid,   iso-octyl 
ester. 
a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine 

(Trifluralin). 
3- (m-Trifluoromethylphenyl)-l ,1-dimethylurea 
(Fluometuron) . 

All   other  cyclic  herbicides 

Insect  attractants  and  repellents: 

tert-Butyl   4 (and  5)-chloro-2-methylcyclohexanecarboxy- 
late    (Trimedlure] . 

2-(3,4-Dichlorophenyl)-l,2,4-oxadiazoline-4-methyl- 

3,5-dione. 
N,N-Diethyltoluamide  (DEET) 

Di-n-propylisocinchomeronate 

•Insecticides: 

3-sec-Amylphenyl-N-methylcarbamate 

Bacillus  thuringiensis 

2-sec-Butyl-4,6-dinitrophenyl-3,3-dimethylacrylate 

(Binapacryl) . 
2-(p-tert-Butylphenoxy)cyclohexyl-2'-propynyl  sulfite-- 

o-sec-Butylphenyl-N-methylcarbamate 

Chlorinated  insecticides: 
*Aldrin-toxaphene  group: 

Heotachloro-tetrahydro-endo-methanoindene 

(Heptachlor) . 
Ilexachloro-epoxy-octahydro-endo ,  endo-dimethano- 

naphthalene  (Endrin) . 
Hexachloro-epoxy-octahydro-endo,  exo-dimethano 

naphthalene  (Dieldrin). 
Hexachloro-hexahydro-endo,  exo-dimethanonaphthalene 
(Aldrin). 

Octachloro-hexahydro-methanoindene  (Chlordan) 

Toxaphene  (Chlorinated  camphene) 

2,2-Bis(p-chlorophenyl)-l,l-dichloroethane  (DDD)  (TDE)- 
a-Bis(p-chlorophenyl)B,6,6-trichloroethane  (DDT) 


DOW, 

RDA,    RIV 

DOW 

RIV. 

GTH. 

DOW, 

RIV. 

DOW. 

DOW, 

RIV. 

DOW. 

RIV. 

DOW. 

DOW, 

RIV,   TMH 

DOW. 

VEL. 

DOW, 

TMH. 

RIV. 

RIV. 

LIL. 

CGY. 

CWN, 

LIL. 

UOP. 

NES, 

VEL. 

HPC, 

PF2. 

MGK. 

X. 

ABB, 

IMC. 

FMN. 

USR. 

OTC. 

VEL. 

VEL. 

SHC. 

SHC. 

VEL. 

HN, 

HPC. 

PESTICIDES  AND  RELATED  PRODUCTS 
TABLE  2.— Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification   codes 
(according  to    list    in  table   3) 


PESTICIDES  AND  RELATED  PRODUCTS,   CYCLIC--Continued 

'Insecticides --Continued 

Chlorinated  insecticides- -Continued 

Chlorobenzilate 

o-Chlorophenyl-N-methylcarbamate 

p-Chlorophenyl    2,4,5-trichlorophenyl    sulfone 

(Tetradifon) . 
Decachlorooctahydro-l,3,4-metheno-2H-cyclobuta- [cd] 

pentalen-2-one    (Kepone) . 

l,l-Dichloro-2,2-bis (p-ethylphenyl) ethane 

4,4'-Dichloro-a-trichloromethylbenzhydrol    (Dicofol) 

2 ,6-Dimethyl-3,5-dichloro-4-pyridinol 

Dodecachlorooctahydro-l ,3,4-metheno-2H-cyclobuta- [cd] 

pentalene    (Mirex) . 

Hexachlorocyclohexane  (Benzene  hexachloride^  (BHC) 

Hexachlorocyclohexane,  100%  Y-isomer  (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepin 

3-oxide  (Endosulfan) . 

Isopropyl  4,4' -dichlorobenzilate  (Chloropropylate) 

1 ,1 ,1-Trichloro- 2, 2-bis(p-methoxyphenyl) ethane 

(Methoxychlor) . 
2,3-Dihydro-2,2-dimethyl-7-benzofuranly  methyl - 

carbamate  (Carbofuran) . 
m-[[(pimethylaiiiino)methylene]amino]phenyl  methyl  carbamate 
hydrochloride  (Formetanate  hydrochloride) . 

m-  (1 -Ethyl propyl) phenyl  methyl carbamate 

O-Isopropylphenyl  N- methyl carbamate 

m- (I-Methylbutyl ) phenyl  methyl carbamate 

1-Naphthyl  N-methylcarbamate  (Carbaryl) 

*Organophosphorus  insecticides: 

0-  (4-Bromo-2,5-dichlorophenyl)0-methyl  phenylphosphono- 

thioate  (Leptophos) . 
4-tert-Butyl-2-chlorophenylmethyl  methylphos- 

phoramidite. 
S-[[(p-Chlorophenyl)thlo]methyl]  0,0-diethyl  phos- 

phorodithioate  (Carbophenothion) . 
0,0-Diethyl  a-3-chloro-4-methyl-l-oxo-2H-l-benzo- 

pyran-7-yl-phosphorothioate  (Coumaphos) . 
0,0-Diethyl  0- (2-isopropyl-4-methyl-6-pyrimidinyl)- 

phosphorothioate  (Diazinon) . 
0,0-Diethyl  0- [p- (methylsulfinyl)phenyll  phosphoro- 

thioate  (Fensulfothion) . 
0,0-Diethyl  0-p-nitrophenyl  phosphorothioate 

(Parathion) . 
0,0-Diethyl  0-3, S,6-trichloro-2  pyridyl  phosphoro- 
thioate. 
0 ,0-Dimethyl  0- [4- (methyl thio) -m- to 1/1] phosphoro- 
thioate (Fenthion) . 
*0,0-Dimethyl  0-p-nitrophenyl  phosphorothioate  (Methyl 

parathion) . 
0,0-Dimethyl  S- [4-oxo-l ,2,3-benzotriazin-3(4H) - 

ylmethyl]  phosphorodlthioate  (Azinphosmethyl) . 

0,0-Dimethyl  S-phthalimidomethyl  phosphorodithioate 

Dimethyl  2,4 ,5-trichlorophenyl  phosphorothionate 

(Ronnel) . 
2,3-p-Dioxane  S,S-bis (0,0-diethylphosphorodithioate) 

(Dioxathion) . 

0-Ethyl  S-phenylethylphosphonodithioate 

a-Methylbenzyl  3- (dimethoxyphosphinyloxy) -cis- 

crotonate. 
0,0,0' ,0'-Tetramethyl  O,0'-thiodi-p-phenylene  phosphoro 

thioate. 
All  other  organophosphorus  insecticides 


CGY. 
OTC. 
FMN. 


DOW. 
ACN. 


CGY. 

CHF,  DUP,  NES. 

FMC. 

MRT. 

ORG. 
OTC. 
ORG. 
UCC. 

VEL. 

DOW. 

SFA. 

CHG. 

CGY. 

CHG. 

AMP,  MON,  SFA. 

DOW. 

CHG. 

AMP,  MON,  SFA,  VEL. 

CHG. 

SFA. 
DOW. 


SFA. 
SHC. 


ACY. 

ACY,  SHC,  VEL. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2. --Pesticides  and  related  products  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972— CONTINUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


PESTICIDES  AND  RELATED  PRODUCTS,  CYCLIC--Continued 

•Insecticides- -Continued 

N-(Phenyl-2-nitropropyI)piperidine 

m-ToIyl-N-methylcarbamate 

All  other  cyclic  insecticides 

Nematocides : 

0,0-Diethyl  0- (2 ,4-dichlorophenyl)  phosphorothioate 

(Dichlofenthion) . 
0,0-Diethyl  0-2-pyrazinyl  phosphorothioate  (Thionazin)- 
*Rodenticides: 

3- (a-Acetonylbenzyl) -4-hydroxycoumarin  (Warfarin) 

2-DiphenylacetyI-l,3-indandione  and  sodium  salt 
(Diphacinone) . 

2-Pivaloyl-l ,3-indandione  (Pindone) 

Synergists  and  adjuvants: 

a- [2- (2-m-Butoxyethoxy) -ethoxy] -4 ,5-methylenedioxy-2- 

propyltoluene  (Piperonyl  butoxide) . 
N-(2-Ethylhexyl)bicycIo) 2.2.1 )-S-heptene-2, 3-di- 

carboximide. 
l,2-Methylenedioxy-4-[2- (octylsulfinyl)propylJben7ene-- 
Piperonal  bis [ 2- (2 ' -n-butoxyethoxy) ethyl ] acetal 
(Heliotropin  acetal). 
All  other  cyclic  pesticides  and  related  products 

PESTICIDES  AND  RELATED  PRODUCTS,  ACYCLIC 

•Fungicides : 

Bis-1 ,4-bromoacetoxy-2-butene 

N,N-Bis (phosphonomethyl) glycine 

Cadmium  succinate 

l-Chloro-2-nitropropane  (Korax) 

Copper  tall ate 

Dimethylthiocarbonyl  disulfide 

Di sodium  cyanodithioimidocarbamate 

•Dithiocarbamic  acid  fungicides: 

Dimethyldithiocarbamic  acid,  ferric  salt  (Ferbam) 

Dimethyldithiocarbamic  acid,  manganese  salt 

Dimethyldithiocarbamic  acid,  potassium  salt 

Ethylene  bis(dithiocarbaiiiic  acid),  diammonium  salt  — 
Ethylene  bis(dithiocarbamic  acid),  disodiun  salt 

(Nabam)  . 
Ethylene  bis (dithiocarbamic  acid),  manganese  salt 

(Maneb) . 
Ethylene  bis (dithiocarbamic  acid),  zinc  salt  (Zineb)- 

N-Methyldithiocarbamic  acid,  sodium  salt  (SW)C) 

All  other  dithiocarbamic  acid  fungicides 

n-Dodecylguanidine  acetate  (Dodine) 

2-HyJroxypropylmethanethiol  sulfonate 

Chloromethoxypropylmercuric  acetate 

Polyethylenethiuram  disulfide  (PETD) 

•Herbicides  and  plant  hormones; 

2-Chloroallyl  diethyldithiocarbamate  (CDEC) 

2-Chloro-N,N-diallylacet amide  fCDAA) 

(2-Chloroethyl)phosphonic  acid 

S-2,3-Dichloroallyl  diisopropylthiolcarbamate 
(Diallate) . 

2,2-DichIoropropionic  acid,  sodium  salt  (Dalapon) 

N-Dimethylamino  succinamic  acid  (DMSA) 

Dimethylarsinic  acid  (Cacodylic  acid) 

Ethyl  diisobutyl  thiolcarbamated 

S-Ethyl  N,N-dipropylthiolcarbamate  (EPTC) 

Ethyl  xanthogen  disulfide  (EXD) 


MRK. 
OTC. 
OTC. 


MOT, 

PEN. 

NES. 

MOT, 

PIC. 

ALP, 

BKL, 

FMN, 

FMP 

MGK. 

PEN. 

MGK. 

CHG. 

WSN. 

VIN. 
MON. 
MAL. 
FMN. 
AMP. 
CLY. 
BKM. 

FMN,  MAL,  VNC. 

FMN. 

BKM. 

RBC. 

ALC,  FMN,  HH,  USR. 

DUP,  RH. 

FMN,  HH. 
SFA. 

MAL,  VNC. 
ACY. 

TRO. 
FW<. 

MON. 
MON. 
GAF. 
MON. 

DOW. 
USR. 
ASL. 
SFA. 
SFA. 
RBC. 


PESTICIDES  AND  RELATED  PRODUCTS 
TABLE  2, --Pesticides  and  related  products  for  which  U,S,  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972--CoNTI NUED 


Manufacturers'  identification  codes 
(according  to  list  in  table  5) 


PESTICIDES  AND  RELATED  PRODUCTS,  ACYCLIC--Continued 

*Herbicides  and  plant  hormones--Continued 

*Methanearsonic  acid,  disodium  salt  (DSMA) 

*Methanearsonic  acid,  dodecyl-  and  octylammonium  salt- 

*Methanearsonic  acid,  monosodium  salt  [MSMA) 

S-Propyl  butylethylthiocarbamate  (Pebulate) 

S-Propyl  dipropylthiocarbamate  (Vernolate) 

S,S,S-Tributyl  phosphorotrithioate 

Tributyl  phosphorotrithioite 

Trichloroacetic  acid,  sodium  salt  (TCA) 

S-2,2,3-Trichloroallyl  diisopropyl thiol carbamate 
(Triallate) . 

All  other  acyclic  herbicides 

'Insecticides : 

2- (2-Butoxyethoxy)ethyl  thiocyanate 

S-Methyl  N- [ (methylcarbamoyl)oxy] thioacetimidate 
(Methomyl ) . 
•Organophosphorus  insecticides : 

S-[1,2-Bis(ethoxycarbonyl)ethyl]  0,0-dimethyl  phos- 

phorodithioate  (Malathion) . 
2-Carbomethoxy-l-propen-2yl  dimethyl  phosphate 

(Mevinphos) . 
1 ,2-Dibromo-2,2-dichloroethyl  dimethyl  phosphate 

(Naled) . 
0,0-Diethyl  S-2- (ethylthio)ethyl  phosphorodithioate 

(Disulfoton) . 
0,0-Diethyl  0-2- (ethylthio)ethyl  phosphorothioate 

(Demeton  0) . 
0,0-Diethyl  S-(ethylthio)methyl  phosphorodithioate 

(Phorate) . 
3- (Dimethoxyphosphinyloxy)-N,N-dimethyl-cis- 

crotonamide  (Dicrotophos) . 
0,0-Dimethyl  2,2-dichlorovinyl  phosphate  (Di- 

chlorvos) . 
0,0-Dimethyl  S- [2-ethylsulfinyl)ethyl]phosphoro- 

thioate  (Oxydemetonmethyl) . 
0,0-Dimethyl  S-  CN-methylcarbajnoylmethyl)phosphoro- 

dithioate  (Dimethoate) . 
Dimethyl  phosphate  of  3-hydroxy-N-methyl-cis- 
crotonamide  (Monocrotophos) . 

0,S- Dimethyl  phosphoramidothioate 

0,0,0' ,0'-Tetraethyl  S,S' -methylene  bisphosphoro- 
dithioate  (Ethion) . 

Tetraethyl  pyrophosphate  (TEPP) 

0,0,0,0-Tetra-n-propyl  dithiopyrophosphate 

All  other  ^cyclic  insecticides 

Nematocides : 

0-Ethyl  S,S-dipropyl  phosphorodithioate 

2-Methyl-2(methylthio)propionaldehyde  0- (raethylcarba- 
moyl)oxime  (Aldicarb) . 
Soil  conditioners:   Polyacrylonitri le,  hydrolyzed, 

sodium  salt 

Soil  fumigants : 

*l,2-Dibromo-3-chloropropane    CDBCP) 

1 ,3-Dichloropropene 

1,3-Dichloropropene,  1 ,2-dichloropropane 

*Methyl  bromide  (Bromomethane) 

Methyl  isothiocyanate 

Trich loronitromethane  (Chloropicrin) 

All  other  acyclic  pesticides  and  related  products 


ASL,  CLY,  DA,  VIN. 

CLY,  VIN. 

ASL,  DA. 

SFA. 

SFA. 

PLC. 

SM. 

DOW. 

MON. 


RH. 
DUP. 


ACY. 

SHC. 

SHC. 

CHG. 

CHG. 

ACY . 

SHC. 

SHC. 

CHG. 

ACY. 

SHC. 

CHG. 
FNIN,  FMP. 

AMP. 
SFA. 
BFG. 


ACY. 

BST,  DOW,  SHC. 

DOW. 

DOW,  SHC. 

AMP,  DOW,  GTL,  MCH. 

MRT. 

DOW. 

GAF,  PCW,  TRO. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TARLE  3,— Pesticides  and  related  products:     Hirectory  of  manufacturers^  1'572 


ALPHABETICAL  DIRECTORY  BY  CODE 

Names  of  manufacturers  of  pesticides  and  related  products  that  reported  production  or  sales  to  the  U.S.  Tariff 
Commission  for  1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Code 

Name  of  company 

Code 

Name  of  company 

ABB 

Abbott  Laboratories 

MAL 

Mallinckrodt  Chemical  Works 

ACN 

Allied  Chemical  Corp.,  Agricultural  Div. 

MCH 

Michigan  Chemical  Corp. 

ACY 

American  Cyanamid  Co. 

MCI 

Mooney  Chemical  Corp. 

ALC 

Alco  Chemical  Corp. 

MGK 

McLaughlin,  Gormley  §  King  Co. 

ALP 

Alpha  Laboratories,  Inc. 

MON 

Monsanto  Co. 

AMC 

Amchem  Products,  Inc., 

MOT 

Motomoco,  Inc. 

Div.  of  Rorer-Amchem,  Inc. 

MRK 

Merck  5  Co.,  Inc. 

AMP 

Kerr-McGee  Chemical  Corp. 

MRT 

Morton  Chemical  Co.  Div.  of  Morton-Norwich  Products 

ARA 

Arapahoe  Chemical  Div.  of  Syntex  Corp. 

Products,  Inc. 

ASL 

Ansul  Chemical  Co. 

MTO 

Montrose  Chemical  Corp.  of  California 

NES 

Nease  Chemical  Co.,  Inc. 

BKL 

Millmaster  Onyx  Corp.,  Millmaster  Chemical 

Co.  Div.,  Berkeley  Chemical  Dept. 

OMC 

Clin  Mathieson  Chemical  Corp.,  Agricultural  Div. 

BKM 

Buckman  Labs.,  Inc. 

ORG 

Chevron  Chemical  Co. 

EST 

Occidental  Chemical  Co. 

OTC 

Story  Chemical  Corp.,  Ott  Chemical  Div. 

CCA 

Cincinnati  Milacron  Chemicals,  Inc. 

PAS 

Pennwalt  Chemicals  Corp. 

Gordon  Corp. 

Pfister  Chemicals,  Inc. 

CGY 

Ciba-Geigy  Corp.  and 

PBI 

Ciba  Agricultural  Co. 

PCW 

CHF 

Chemical  Formulators,  Inc. 

PEN 

CPC  International,  Inc.,  Penick  Div. 

CHG 

Baychem  Corp.,  Chemagro  Div. 

PFZ 

Pfizer,  Inc. 

CLY 

W.  A.  Cleary  Corp. 

PIC 

Pierce  Organics,  Inc. 

CWN 

Upjohn  Co.,  Fine  Chemical  Div. 

PLC 

Phillips  Petroleum  Co. 

PPG 

PPG  Industries,  Inc. 

DA 

Diamond  Shamrock  Corp. 

DOW 

Dow  Chemical  Co. 

RBC 

Fike  Chemicals,  Inc. 

DUP 

E.  I.  duPont  de  Nemours  §  Co.,  Inc. 

RCl 

Reichhold  Chemicals,  Inc. 

RDA 

Rhodia,  Inc. 

EFH 

E.  F.  Houghton  fi  Co. 

RH 

Rohm  §  Haas  Co. 

EGR 

Eagle  River  Chemical  Corp. 

RIV 

Riverdale  Chemical  Co. 

FER 

Ferro  Corp.,  Ferro  Chemical  Div. 

Stauffer  Chemical  Co.; 

FIS 

Fisher  Chemical  Co.,  Inc. 

SFA 

Agricultural  Div. 

FMC  Corp.: 

SFC 

Calhio  Chemicals,  Inc.  Div. 

FNIN 

Niagara  Chemical  Div. 

SHC 

Shell  Oil  Co.,  Shell  Chemical  Co.  Div. 

FMP 

Industrial  Chemical  Div., 

SHP 

Shepherd  Chemical  Co. 

Organic  Business  Group 

SM 

Mobil  Oil  Corp.,  Mobil  Chemical  Co.  Div., 

FMT 

Fairmount  Chemical  Co. 

Industrial  Chemical  Div. 

FRO 

Vulcan  Materials,  Co.,  Chemical  Div. 

TMH 

Thompson -Hayward  Chemical  Co. 

GAF 

GAF  Corp.,  Chemical  Div. 

TRO 

Troy  Chemical  Co. 

GOC 

Gulf  Oil  Corp.,  Gulf  Oil 

Chemical  Co. -U.S. 

UCC 

Union  Carbide  Corp. 

GTH 

Guth  Chemical  Co. 

UOP 

Universal  Oil  Products  Co.,  UOP  Chemical  Div. 

GTL 

Great  Lakes  Chemical  Corp. 

USR 

Uniroyal,  Inc.,  Chemical  Div. 

IIK 

Hooker  Chemical  Corp. 

VAL 

Valchem 

HN 

Tenneco  Chemicals,  Inc. 

VEL 

Velsicol  Chemical  Corp. 
Vineland  Chemical  Co. 

HPC 

Hercules,  Inc. 

VI N 

VNC 

Vanderbilt  Chemical  Corp. 

IMC 

International  Minerals  S  Chemical  Corp. 

WRC 

Ventron  Corp.,  Ventron  Chemicals 

LIL 

Eli  Lilly  6  Co. 

WSN 

Mallinckrodt  Chemical  Works,  Washine  Div. 

WTC 

Witco  Chemical  Co.,  Inc. 

Note. -Complete  names  and  addresses  of  the  above  reporting  companies  are  listed  in  Table  1  of  the  Appendix. 


MISCELLANEOUS  CHEMICALS 


The  term  miscellaneous  chemicals  comprises  those  synthetic  organic 
products  that  are  not  included  in  the  use  groups  covered  by  the  other 
preliminary  reports  in  the  1972  series.  They  include  products  that  are 
employed  in  a  great  variety  of  uses.   The  number  of  chemicals  used  ex- 
clusively for  only  one  purpose  is  not  large.  Among  the  products  covered 
are  those  used  for  gasoline  and  lubricating  oil  additives,  paint  driers, 
photographic  chemicals,  tanning  materials,  flotation  reagents,  refriger- 
ants, textile  polymers,  sequestering  agents,  organic  fertilizers,  anti- 
freeze chemicals,  solvents,  and  acyclic  intermediates.   Table  1  presents 
statistics  on  U.S.  production  and  sales  of  miscellaneous  chemicals  in  as 
great  detail  as  is  possible  without  revealing  the  operations  of  individual 
producers . ^ 

Production  of  miscellaneous  cyclic  and  acyclic  chemicals  in  1972 
amounted  to  90.5  billion  pounds,  or  il3-.9.  percent  more  than  the  output  of 
79.5  billion  pounds  reported  for  1971.   Sales  of  miscellaneous  chemicals 
in  1972  amounted  to  45.2  billion  pounds,  valued  at  $4.7  billion,  compared 
with  38.4  billion  pounds,  valued  at  $4.1  billion  in  1971. 

The  total  output  of  miscellaneous  cyclic  chemicals  in  1972  was  2.4 
billion  pounds,  or  10.7  percent  more  than  the  output  of  2.2  billion  pounds 
reported  for  1971.   Sales  in  1972  totaled  1.2  billion  pounds,  valued  at 
$423  million,  compared  with  1.0  billion  pounds,  valued  at  $379  million, 
in  1971.   In  1972,  the  most  important  groups  of  cyclic  compounds  were  the 
lubricating  oil  additives,  the  output  of  which  was  388  million  pounds,  and 
synthetic  tanning  materials,  the  output  of  which  was  53  million  pounds. 

Total  production  of  miscellaneous  acyclic  chemicals  in  1972  was  88.1 
billion  pounds,  or  14.0  percent  more  than  the  output  of  77.3  billion  pounds 
reported  for  1971.   Sales  in  1972  totaled  44.0  billion  pounds,  valued  at 
$4.3  billion,  compared  with  37.3  billion  poionds,  valued  at  $3.8  billion, 
in  1971.  The  statistics  for  acyclic  chemicals  are  grouped  primarily  by 
chemical  function.  The  order  of  precedence  of  these  functional  groups  is 
generally  that  used  in  naming  and  indexing  chemical  compounds  by  Chemtoal 
Ah s tracts  ,   but  other  important  considerations  are  comparability  with  other 
statistics  and  the  need  for  groupings  that  will  not  reveal  the  operations 
of  individual  producers. 

In  1972,  the  most  important  groups  of  acyclic  chemicals  were  the 
halogenated  hydrocarbons,  the  nitrogenous  compounds,  monohydric  alcohols, 
and  aldehydes  and  ketones.   Production  of  halogenated  hydrocarbons,  which 
are  used  as  solvents,  intermediates,  refrigerants,  and  aerosol  propellants, 
totaled  20.1  billion  pounds.   The  most  important  chemicals  in  this  group 
were  dichloroe thane  (production  of  7.8  billion  pounds  in  1972  compared  with 


^  See  also  table  2  which  lists  these  products  and  identifies  the  manu- 
facturers by  code.  These  codes  are  given  in  table  3. 


200 

SYNTHETIC  ORGANIC  CHEMICALS,  1972 


7.6  billion  pounds  in  1971)  and  vinyl  chloride  (5.1  billion  pounds  compared 
with  4.3  billion  pounds).   Output  of  nitrogenous  compounds  totaled  15.5 
billion  pounds.  The  most  important  chemical  in  this  group  was  urea  (used 
principally  in  fertilizers  and  as  a  feed  additive),  production  of  which  was 
6.9  billion  pounds  in  1972  and  6.2  billion  pounds  in  1971. 

Monohydric  alcohols,  which  are  used  largely  as  solvents  and  inter- 
mediates, were  the  third  largest  group  in  1972,  with  production  of  12.8 
billion  pounds.  The  most  important  items  in  the  group  in  terms  of  pro- 
duction were  synthetic  methanol  (6.5  billion  pounds  in  19  72,  compared  with 
4.9  billion  pounds  in  1971),  synthetic  ethyl  alcohol  (1.8  billion  pounds 
in  1972,  compared  with  1.6  billion  pounds  in  1971)  and  isopropyl  alcohol 
(1.8  billion  pounds  in  1972,  compared  with  1.7  billion  pounds  in  1971). 
Aldehydes  and  ketones,  which  are  also  used  largely  as  solvents  and  inter- 
mediates, were  the  next  largest  group  with  production  of  11.3  billion 
pounds.  The  most  important  items  in  this  group  in  1972  were  formaldehyde 
(5.6  billion  pounds),  acetone  (1.8  billion  pounds)  and  acetaldehyde 
(1.4  billion  pounds). 


MISCELLANEOUS  CHEMICALS 
TABLE  1. --Miscellaneous  chemicals;     U.S.  production  and  sales.  1972 


[Listed  below  are  all  miscellaneous  chemicals  for  which  any  reported  data  on  production  or  sales  may  be  published. 
(Leaders  (...)  are  used  where  the  reported  data  are  accepted  in  confidence  and  may  not  be  published  or  where  no 
data  were  reported.)  Table  2  lists  all  miscellaneous  chemicals  for  which  data  on  production  or  sales  were  re- 
ported and  identifies  the  manufacturers  of  each] 


Production 


Quantity 


Grand  total 

MISCELLANEOUS  CHEMICALS,  CYCLIC 
Total 

Benzoic  acid,  sodium  salt 

Benzoyl  peroxide 

Butyl  benzoate 

tert- Butyl  peroxy benzoate 

2,6-Di-tert-butyl-p-cresol: 

Food  grade 

Tech 

Dioxane  (1,4-Diethylene  oxide) 

Enzymes 

4-Ethylmorpholine 

Flotation  reagents 

Gasoline  additives  

Hexamethylenetetramine,  tech 

p-Hydroxybenzoic  acid  esters: 

Butyl  p-hydroxybenzoate  (Butylparaben) 

Methyl  p-hydro.xybenzoate  (Methylparaben) 

Propyl  p-hydroxybenzoate  (Propylparaben) 

Lubricating  oil  and  grease  additives,  total 

Oil-soluble  petroleum  sulfonates,  total 

Oil-soluble  petroleum  sulfonates,  calcium  salt 

Oil-soluble  petroleum  sulfonates,  sodium  salt 

All  other 

Phenol  salts 

All  other  lubricating  oil  and  grease  additives 

Morpholine 

Naphthenic  acid  salts,  total^  

Calcium  naphthenate 

Cobalt  naphthenate 

Iron  naphthenate 

Lead  naphthenate 

Manganese  naphthenate 

line  naphthenate 

All  other 

Photographic  chemicals: 

2,5-Diethoxy-4-morpholinobenzenedia2onium  chloride- 

p-Diethylaminobenzenediazonium  chloride 

N , N- Diethyl toluene- 2 , S-diamine ,  monohydroch loride- - 

p-Dimetnylaminobenzenediazonium  chloride 

p-  [Ethyl  (2-hydro.xyethyl)amino]benzenediazonium 

chloride 

p- [ (2-Hydroxyethyl)methylamino]benzenediazonium 

chloride 


1,000 
pounds 


90.476.062 


2,411,142 


15,266 
7,570 
5,575 
1,542 

7,517 
17,838 
15,768 

(2) 

1,595 
15,979 
45,004 
95,156 


918 
391 


388,115 


228,162 
139  458 
42,032 
46,672 
76,092 
83,861 


1,434 
3,295 

11,448 

959 

905 

2,489 


168 
119 


1,000 
pounds 

45,155.471 


1,000 
do  I  lavs 


4.680.222 


pound 


1,177,960 


12,185 
7.443 
5.019 
1,513 

8,471 
18,151 
6,518 

(2) 

1,379 
13,432 

61,724 


879 
367 


80,555 
70,062 


68,765 
64,485 


1,366 
3,210 
105 
10,717 
967 
776 
930 


141 
119 
299 


3,664 

7,002 

779 

1,685 

4,166 
8,642 
2,159 
25,147 
1,102 
1,693 

7,498 

50 

1,392 

690 


16,169 
10,995 


14,120 
21,402 


6,976 
5,320 


1,738 
25 

1,892 
258 
199 
828 


801 
240 
898 

147 


See  footnotes  at  end  of  table 


SYNTHETIC  ORGANIC  CHEMICALS.  1972      • 
TABLE  1. --Miscellaneous  chemicals;     U.S.   production  and  sales.  1372— Continued 


Production 


Quantity 


MISCELLANEOUS  CHEMICALS,  CYCLIC--Continued 

a-Pinene 

fi-Pinene 

Tall  oil  salts: 

Cobalt  tallate 

Lead  tallate 

Manganese  tallate 

Tanning  materials,  s\'nthetic 

Textile  chemicals 

All  other  miscellaneous  cyclic  chemicals 

MISCELLANEOUS  CHEMICALS,  ACYCLIC 

Total 

Cellulose  Esters  and  Ethers 

Total 

Cellulose  esters:   Cellulose  acetate 

Cellulose  ethers:  Sodium  carboxyraethylcellulose, 
100% 

All  other  cellulose  esters  and  ethers  

Lubricating  Oil  Additives 

Total 

Phosphorodithioates  (Thiophosphates) 

Sulfur  compounds:   Sulfurized  lard  oil 

All  other 

nitrogenous  Compounds 

Total' 

Acrylonitrile 

Amines,  total 

Butylamines: 

n-Butylamine,  mono-  

Di-n-butylamine 

Diethyl en etriamine 

Ethyl amines ,  total 

Diethylamine 

All  other 

Ethyl enediamine 

1 ,6-Hexanediamine  (Hexamethylenediamine) 

Methylamines : 

Dime thy  I amine 

Methylamine,  mono-  

Trimethylamine 

Propylamines: 

Diisopropylaraine 

Di propyl amine 

Propylamine,  mono-  

Tetrae thy lenepent amine 

Triethylenetetramine 

All  other 

2- (2-Aminoethylamino) ethanol  (Aminoethyl- 

ethanol amine) 

Capro lac tarn 

2-Dimethylaminoethanol 


1,000 
pounds 


38,095 

1,262 

2,002 

520 

53,040 

1,585 

1,681,482 


88.064,920 


1,000 


68,962 
156,030 


67,009 

3,316 

430,088 


1,114,749 
1,276,277 


4,017 
3,842 
32,390 

55,437 
11,079 
44,358 


95,973 
33,063 
28,815 


18,011 
133,622 


8,788 

640,045 

3,533 


19,814 
29,180 

1,256 

2,056 

542 

53,310 

504 

607,606 


43.977,511 


1,000 
dollars 


2,106 
4,638 

559 

406 

143 

11,207 

1,091 

259,995 


70,991 
254,021 


21,440 

3,128 

147,979 


459 

985 

345 

803 

2 

374 

3 

121 

30 

176 

48,610 
8,449 

51,522 
23,347 
23,948 

779 
14,389 

239 

12,779 

15,466 

105,137 


6,775 
546,486 


31.243 
116,431 


6,009 

674 

23,824 


786,963 


49,259 
68,768 


670 

748 

9,697 


9,696 
3,073 

4,702 
1.984 
2,189 

165 
3,501 

183 
6,105 
5,218 
19,853 


2,603 
96,615 


MISCELLANEOUS  CHEMICALS 
TABLE  1. --Miscellaneous  chemicals:  U.S.  production  and  sales.  1972— Continued 


Production 


1,000 


MISCELUNEOUS  CHEMICALS,  ACYCLIC--Continued 

Nitrogenous  Compounds- -Continued 

Ethanol amines,  total 

2-Aininoethanol  (Monoethanol amine) 

2,2'-Aniinodiethanol  (Diethanol amine) 

2, 2' ,2' ' -Nitrilotriethanol  (Triethanol amine) 

Hexamethylenediammonium  adipate  (Nylon  salt) 

Nitriloacids  and  salts,  total 

(Diethylenetrinitrilo)pentaacetic  acid,  pentasodiun 

salt 

tEthylenedinitrilo)tetraacetic  acid 

CEthylenedinitrilo)tetraacetic   acid,   disodium  salt- 
(Etliylenedinitrilo)tetraacetic  acid,   tetrasodium 

salt 

(N-Hydroxyethylethylenedinitrilo)triacetic  acid, 

tri sodium  salt 

All  other 

Nylon  6  and  6/6  (polymers  for  fiber,  only) 

Pentaerythritol  tetranitrate 

Polyacrylamide 

Urea  in  compounds  or  mixtures  (100%  basis),  total — 

In  feed  compounds 

In  liquid  fertilizer 

In  solid  fertilizer 

All  other 

All   other  nitrogenous   compounds 

Acids,   Aoyl  Halides  and  Anhydrides 

Total 

Acetic  acid,  synthetic,  100% 

Acetic  anhydride,  100% 

Acrylic  acid 

Adipic  acid 

Dodecenyl succinic  anhydride 

Formic  acid,  90% 

Furaaric  acid 

Lauroyl  chloride 

Maleic  anhydride 

Pivaloyl  chloride 

Poly aery lie  acid 

Propionic  acid 

All  other  acids,  acyl  halides  and  anhydrides 

Salts  of  Organic  Acids 

Total 

Acetic  acid  salts,  total 

Copper  acetate 

Potassium  acetate 

Zinc  acetate 

Zirconium  acetate 

All  other 


82,114 
101,075 
100,742 

719,550 


3,503 
1,292 


4,635 
48,068 

1,547,238 
4,099 
19,106 

6,933,470 


679,816 
2,531,235 
2,633,970 
1,088,449 

2,803,813 


6,668,458 


2,235,406 

1,572,928 

123,195 

1,491,405 

46,894 

51,455 

5,469 

274,435 

981 

1,023 

56,046 

809,223 


333,370 


282 

5,198 

457 


1,000 
pounds 


234,454 


1,000 
dollars 


71,788 
71,980 
90,686 


7,682 
8,058 
11,673 


3,062 
5,056 


3,658 
34,305 


3,404 
14,418 


5,999,440 


1,550 
9,734 


2,818 
12,377 


158,623 


611,680 
2,168,443 
2,489,488 

729,829 

77S.433 


15,418 
65,101 
64,208 
13,896 

344,764 


570,787 

30,211 
143,497 
2,485 
35,348 
35,915 

190,571 

927 
38,051 
733,516 


285,631 


28,903 

6,596 
20,039 
1,037 
3,574 
6,692 

25,024 

525 

3,331 

136,154 


472 

159 

25,826 


See  footnotes  at  end  of  table. 


SYNTHETIC  nRGflNlC  CHE'IICALS,   1972 

TABLE    l.--fllSCELLA»lEOUS    CHEniCALS:       U.S.    PRODUCTION    AND    SALES,    1972" 


-CONTINUED 


Quantity 


1,000 


1,000 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 
Salts  of  OTgania  Acids — Continued 

2-Ethylhexanoic  acid    (a-Ethylcaproic   acid)    salts, 

total 

Calcium  2-ethylhexanoate 

Cobalt  2-ethylhexanoate 

Lead  2- ethy Ihexanoat e 

Manganese  2-ethylhexanoate 

Zinc  2-ethylhe xanoat e 

All  other 

Formic  acid,  sodium  salt  (tech.) 

Gluconic  acid,  sodium  salt 

Lactic  acid  salts 

Mercaptoacetic  (Thioglycolic)  acid,  ammonium  mercapto- 
acetate  salt 

Oleic  acid  salts 

Propionic  acid  salts: 

Calcium  propionate 

Sodium  propionate 

Stearic  acid  salts,  total'" 

Aluminum  stearates,  total 

Aluminum  distearate 

Aluminum  monostearate  and  tristearate 

Barium  stearate 

Calcium  stearate 

Lithium  stearate 

Magnesium  stearate 

Zinc  s t eara te 

All  other 

All  other  salts  of  organic  acids 

Aldehydes  and  Ketones 

Total 

Acetaldehyde 

Acetone,  total 

From  cumene 

All  other 

2-Butanone  (Methyl  ethyl  ketone) 

Butyraldehyde 

Formaldehyde  (37'o  by  weight) 

4-Ilydroxy-4-methyl-2-pentanone  (Diacetone  alcohol) 

4-Methyl-2-pentanone  (Methyl  isobutyl  ketone) 

All  other  aldehydes  and  ketones 

Alcohols,   Monahydric,    ynsubstituted 

Total 

Alcohols,  C,  or  lower,  unmixed,  total 

Butyl  alcohols: 

n-Butyl  alcohol  (n-Propylcarbinol) 

Isobutyl  alcohol  (Isopropylcarbinol) 

Ethyl  alcohol,  synthetic'' 

2-Ethyl-l-hexanol 


18.715 


1,792 
3,362 
3,469 
996 
1,233 
7,863 

31,992 
8,915 
1,901 

1,099 
1,286 

21,395 
4,114 

70,123 


5,914 

2,719 

1,195 

389 

37,793 

887 

4,767 

19,374 

2,999 

142,193 


1,447,566 
1,818,373 


1,086,012 
732,361 


509,025 
5,651,807 


208,263 
1,651,669 


12,833,473 


12,092,504 


590,228 

96,386 

1,850,651 

526,125 


789 
1,028 
10,308 

31,214 
10,765 


16,329 
3,616 


69,722 


4,006 
2,741 
1,265 


5 

288 

18 

798 

2 

332 

09 

140 

1,495,112 


929,400 

565,712 

470,010 

50,258 

1,820,047 

46,482 

177,013 

764,707 


7,627,636 


7,004,356 


354,720 

96,634 

1,395,655 

332,135 


1,000 
do  I lars 


6,982 


2,017 

237 

498 

4,230 

1,034 

2,650 

818 


3,594 
789 


25,492 


1,690 
1,122 

568 

148 
12,570 

474 
2,211 
7,419 

980 

57,227 


23,346 

37,981 
4,870 

35,106 
5,670 

18,954 

60.414 


275,478 


24,513 
4,189 
74,912 
24,309 


MISCELLANEOUS  CHE^IICALS 
TABLE  1.— Miscellaneous  chemicals:  U.S.  production  and  sales,  1972— Continued 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 


Alcohols,   Monohydric,    Unsubstituted- -Continued 

Alcohols,   Cg   or  lower,   unmixed--Continued 

Hexyl   alcohol 

Iso-octyl  alcohols 

Isopropyl  alcohol 

Methanol,   synthetic 

1-  (and  2-)0ctanol 

Propyl  alcohol  (Propanol) 

All  other 

Alcohols,  C,i)  and  higher,  unmixed,  total 

Isodecyl  alcohol 

Stearyl  and  other  octadecyl  ilccrfiols 

All  other 

Mixtures  of  alcohols,  total 

Cg  and  lower,  only 

C,|,  and  higher,  only 

Cj  to  Ci2   and  others'^ 

PolyhydHc  Aloohols  and  Their  Esters  and  Ethers 

Totalis 

Polyhydric  alcohols,  total 

Ethylene  glycol 

Glycerol,  synthetic  only 

2-Methyl-2,4-pentanediol  CHexylene  glycol) 

Pent aery thritol 

Propylene  glycol  (1,2-Propanediol) 

Sorbitol 

All  other 

Polyhydric  alcohol  esters,  total 

Ethylene  glycol  diacetate 

All  other 

Polyhydric  alcohol  ethers,  total 

2-Butoxyethanol  (Ethylene  glycol  monobutyl 

ether) 

2-(2-Butoxyethoxy)ethanol  (Diethylene  glycol 

monoisobutyl  ether) 

Diethylene  glycol 

Dipropylene  glycol 

2-Ethoxyethanol  (Ethylene  glycol  monoethyl 

ether) 

2- (2-Ethoxyethoxy)ethanol  (Diethylene  glycol 

monoethyl  ether) 

2-  [2-  (2-Ethoxyethoxy)etho(ty]eth«Bol    (Triethylme 
glycol     monoethyl   ether) 

2-Methoxyethanol    (Ethylene  glycol   monoinethyl 

ether) 

2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol 

monomethy 1  ether) 

2- [2- (2-Methoxyethoxy)ethoxy]ethanol  (Triethylene 

glycol  monomethyl  ether) 

Polyethylene  glycol 

Polypropylene  glycol 

Tetraethylene  glycol 

Triethylene  glycol 

Tripropylene  glycol 

All  other  ethers  of  polyhydric  alcohols 


1,000 


16,296 

63,227 

1,790,024 

6,471,605 

13,741 

83,095 

591,126 

204,444 


147,029 

8,005 

49,410 


44,928 
447,999 
43,598 


3,761,143 
199,216 

110,087 
562,583 
121,370 
317,214 

237,961 


237,961 
2,117,239 


133,305 

24,779 
245,492 
51,773 

205,413 
41,156 
28,181 

119,106 
12,666 

31,693 

52,353 
359,238 

11,813 
105,531 

694,740 


Quantity 


1,000 
pounds 


AT ,021 

911,733 

,542,260 

10,048 

77,036 

237,108 

117,346 


63,819 
13,349 
40,178 


39,763 
j6l,644 
104,527 


5,950,570 


,113,931 
187,999 
38,554 
94,058 
538,037 
91,586 
98,626 

222.192 


5,363 
216,829 


111,218 

16,917 
184,406 
50,348 

103,648 

31,366 


85,749 

9,862 

11,162 
49,276 

6,176 

84,716 

1,928 

818,815 


1,000 
dollars 


4,201 

50,753 

51.498 

1,856 

8,272 

30,975 

19.051 


5,564 
3,517 
9,970 


4,979 
62,114 
9,550 


596,329 


334,228 


186,135 
37,167 
5,408 
15,787 
43.746 
19,515 
26,470 

42,273 


41.285 
219,828 


2 

668 

11 

146 

4 

338 

11 

777 

4 

287 

9,352 

1,217 

1,560 
10,905 

899 

9,330 

300 

136,701 


See  footnotes  at  end  of  table. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  1.— Miscellaneous  chemicals;  U.S.  production  and  sales.  1972— Continued 


Production 


Quantity 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Esters  of  Moriohydria  Alcohols 

Total 

n-Butyl  acetate,  unmixed 

Isobutyl  acetate,  unmixed 

Butyl  aery late 

tert- Butyl  peroxypivalate 

Dibutyl  maleate 

Dilauryl  3, 3'-thiodipropionate 

Dioctyl  maleate 

Distearyl   3,3'-thiodipropionate 

Ethyl  acetate  (85%) 

Ethyl  aery late 

2-EthyI-I-hexyI  aery late 

Iso-oetyl  mereaptoaeetate 

Isopropyl  acetate 

Methyl  acetate 

Methyl  methacrylate,  monomer 

Phosphorus  acid  esters,  not  elsewhere  specified — 

Propyl  acetate 

Vinyl  acetate 

All  other 

Halogenated  Hydrocarbons 

Total 

Carbon  tetrachloride 

Chlorinated  paraffins,   total 

35-64%  chlorine 

Other 

Chi  orodi  f  1  uoromethane . 

Chloroethane  (Ethyl  chloride) 

Chloroform 

Chloromethane  (Methyl  chloride) 

1,2-Dibromoethane  (Ethylene  dibromide) 

Diehlorodifluorome thane 

1,2-Dichloroethane  (Ethylene  dichloride) 

Dichloromethane  (Methylene  chloride] 

1,2-Dichloropropane  (Propylene  dichloride) 

lodomethane  (Methyl  iodide) 

Tetrachloroethylene  (Perchloroethylene) 

1,1,1-Trichloroethane  (Methylchloroform) 

Triehloroethylene 

Trichlorofluoromethane 

Vinyl  chloride,  monomer  (Chloroethylene) 

All  other  halogenated  hydrocarbons 

All  Other  MisaelZanecus  Acyclic  Chemicals 

Total 

2-Butanone  peroxide 

tert-Butyl  peroxide  (Di-tert-butyl  peroxide) 

Carbon  disulfide-, 

Epoxides,  ethers,  and  acetals,  total 

Ethylene  oxide 

Ethyl  ether,  tech 

Isopropyl  ether 

Propylene  oxide 

All  other  epoxides,  ethers,  and  acetals 


1,000 
pounds 


3,221,170 


1,000 


125,598 

983 

9,554 

1,355 

6,295 

1,567 

221,983 

275,344 

45,524 

8,495 


598,992 

59,494 

32,439 

1,210,703 

527,180 


20.071.191 


996,687 
63,453 


48,806 
14,647 


375,513 
234,677 
453,533 
315,523 
439,224 
7,808,938 
471,276 

18 
734,216 
440,681 
426,684 
299,583 
5,088,511 
1,722,674 


4,774 

1,822 

767,830 


,961,757 
69,379 


1,520,174 
677,782 


2,031,099 


89,359 

27,296 

69,224 

970 

10,161 

1,350 

5,652 

1,459 

181,148 

99,756 

39,452 

44,897 
2,176 

53,238 

32,517 

943,401 

429,043 


50,181 
15,057 

79,982 
194,021 
202,776 
208,020 
173,378 
418,537 
1,446,707 
443,334 

40,742 

723,427 
389,028 
441,180 
286,334 
3,343,209 
180,285 


2,940,623 


4,631 

1,775 

527,636 


9,848 
("•) 
688,026 


1,000 
dollars 


265,586 


8,740 

2,964 

11,809 

1,941 

1,608 

1,022 

946 

1,125 

13,833 

15,862 

7,980 

4,630 
177 

24,596 

3,844 

65,868 


698.471 


54,792 
9,112 


6,248 
2,864 

39,202 
11,654 
13,449 
10,661 
28,795 
101,561 
38,927 
29,474 
527 

41,565 
35.475 
29,458 
52,459 
132,601 
68,759 


4,597 
1,447 
21,002 

97,962 


30,087 

926 

66,949 


MISCELLANEOUS  CHEMICALS 

TABLE  l.-HlSCELLANEOUS  CHEMICALS:   U.S.  PRODUCTION  AND  SALES.  1972— CONTINUED 


Quantity 


Unit 
value' 


1,000 


1,000 
pounds 


1,000 
dollars 


MISCELLANEOUS  CHEMICALS,  ACYCLIC— Continued 
All  Other  Miscellaneous  Aayalio  Chemicals — Continued 


Organo- silicon  compounds,  total- 
Silicon  fluids 

Other  organo-silicon  compounds- 


Phosgene  (Carbonyl  chloride) 

Sodium  methoxide  (Sodium  methylate)- 

Tetraethyllead 

Other  organo-lead  compounds 

All  other 


74,722 
114,735 

637,043 
5,172 
302,371 
670,105 
407,190 


52,707 
31,096 

11,678 

8,177 

310,834 

650,439 

189,480 


53,167 
54,145 

1,423 

1,797 

165,463 

349,448 

54,858 


Per 
pound 


$1.28 


1.01 
1.74 


.53 
.54 


'  Calculated  from  rounded  figures. 
^  Not  available. 

'  Statistics  exclude  production  and  sales  of  tricresyl  phosphate.  Statistics  on  tricresyl  phosphate  are  given 
with  "Plasticizers." 

"*  Quantities  are  given  on  the  basis  of  solid  naphthenate,  tallate,  or  linoleate  content. 

'  Statistics  exclude  production  and  sales  of  copper  naphthenate.  Statistics  on  copper  naphthenate  are  given 
with  "Pesticides  and  Related  Products." 

^  Ethylcellulose  which  was  formerly  included  with  cellulose  ethers  is  now  included  with  cellulosic  plastics 
materials. 

'  Statistics  exclude  production  and  sales  of  fatty  amines.  Statistics  on  fatty  amines  are  given  with  "Surface- 
Active  Agents." 

°  Production  of  urea  in  primary  solution  totaled  7,096,187  thousand  pounds. 
'  Includes  estimated  values  for  sales  of  urea  in  nitrogen  compounds. 
'°  Statistics  exclude  production  and  sales  of  potassium  and  sodium  stearates.  Statistics  on  these  stearates  are 
included  with  "Surface-Active  Agents." 

"  Statistics  en  production  of  ethyl  alcohol  from  natural  sources  by  fermentation  are  issued  by  the  Department  of 
Treasury,  Bureau  of  Alcohol,  Tobacco,  and  Firearms. 

'^  Of  the  total  production,  about  45  percent  consisted  of  alcohols  lower  than  Cjo  and  about  55  percent  consisted, 
of  alcohols  Cio  and  higher. 

'^  Some  polyols  which  are  used  as  intermediates  for  urethanes  have  been  included  with  "Plastics  and  Resin 
Materials ." 
'"  Sales  quantity  of  propylene  oxide  in  1971  was  237,710,000  pounds  (instead  of  37,710,000  pounds). 


SYNTHETIC  ORGANIC  CHEniCALS,  1972 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED    BY    MANUFACTURER.    1972 

[Miscellaneous   chemicals   for  which  separate  statistics   are  given  in  table  1   are  marked  with  an  asterisk    (*) ; 
chemicals  not   so  marked  do  not   appear  in  table  1  because  the  reported  data  are   accepted  in  confidence   and  may  not 
be  published.      Hanufacturers '    identification   codes   shown  below   are   taken  from  table    3.      An   x   signifies   that   the 
manufacturer  did  not   consent   to  his    identification  with   the   designated  product] 


Manufacturers'    identification   codes 
(according  to   list   in   table   3) 


MISCELLANEOUS  CHEMICALS,    CYCLIC 

6-Acetoxy-2,4-dimethyl-l ,3-dioxane 

Acetylcyclohexanesulfonyl  peroxide 

Adenosine  and  derivatives 

3- t3"-Aminobenzamide)-l- (2' ,4' ,6'-trichlorophenyl) -5- 

pyrazole. 

2-Aminobenzothiazole 

1- (2-Aminoethyl)piperazine 

1- (3-Aminopropyl)morpholine 

Amyl  p- dime thy laminobenzoate 

Benzatriazoles ,   substituted 

*Benzoic   acid,    sodium  salt 

p- Benzoquinone    (p-Quinone ) 

Benzothiazole 

♦Benzoyl  peroxide 

Biological    stains 

BisC2,4-dichloroben2oyl)   peroxide 

1,8- Bis- faimethy 1 amino ^naphthalene 

Bis (a,a-dimethylbenzyl)    peroxide 

2, 4- Bis (4-hydroxy-3,5-di-tert-butylphenoxy)-6-(n-octyl- 

thio)-l ,3,S-triazine. 
2, 4- Bis  (n-octylthiol-6- (4 '-hydroxy- 3' ,5'-di-tert-butyl- 

anilino)-l ,3,S-triazine. 

Boron  fluoride-phenol   complex 

*Butyl  benzoate 

p-tert-Butylbenzoic  acid,  barium  bis-salt 

2 (and  3)-tert-Butyl-4-methoxyphenol 

*tert- Butyl  peroxybenzoate 

4-tert-Butylpyrocatechol 

Camphene 

Cellulose   acetate  phthalate 

Centralite-1    (N,N'-Diethyl-N,N'-diphenylurea;'-   

Chemical   indicators   and  reagents 

Chloramine   B   (Sodium  derivative  of  N-chlorobenzenesulfon- 

amide) . 
l-(3-Chlorallyl)-3,S,7-triaza-l-a2oniaadamantane 

chloride. 

o-Chlorobenzamalononitrile 

Chlorophyllin,   sodium-potassium- copper 

Cumene  hydroperoxide 

Cyanuric  acid 

1 ,3-Cyclohexadiene 

Cyclohexane   sulfamic  acid 

Cyclohexanone  peroxide 

Cyclohexene-1 ,2-dicarboxylic  acid   (Tetrahydrophthalic 

acid)   disubstituted,  polyester  salts:      Barium  and 

cadmium  salts . 

Cyclohexyl    chloride 

1 ,4-Cyclohexylenedimethanol 

Cyclopropane 

Cytidine  and  derivatives 

Decahydronaphthaie'-e    (Decalinl 

Dehydroacetic   acid  or  sodium  salt 

2,5-Di-tert-amylhydroquinone 

l,4-Diazobicyclo(2.2.2)octane 

Diazodinitrophenol 

2,S-Di (benzoylperoxy)-2,5-dimethylhexane 

Di-   and   tribroraosalicylanilide 

Dibroraodimethylhydantoin 


CAD,    NOC,    RCI,    IVTC,    WTL. 
WTL. 


niv. 

WTL. 
PLB. 


PUT. 

UCC. 

JCC. 

VND. 

CGY. 

HN,   MON,    PFZ,    VEL,    WSN 

EKT. 

ACY. 

AZT 

ACS 

CAD 

ALD. 

WTL. 

CGY. 

CGY. 

ACS. 

CPS,    PFZ,   TCC,   VEL. 

CCA. 

EKT. 

AZT,    CAD,    NOC,    WTC,    WTL. 

BKL,    DOW. 

GLD,    HN,    HPC. 

OTC. 

ACS,    EK,    FIN,   GFS,    LAH,   NEP. 

NES. 

DOW. 

FIS. 

KCH. 

ACP,   HPC,    RCI. 

FMB. 

ALD. 

ABB. 

AZT,    NOC,    WTL. 

RCI. 


X. 

EKT. 

OH,   TAE. 

PLB. 

DUP. 

GAN,    UCC. 

EKT. 

AIP. 

HPC. 

WTL. 

FIN. 

ARA. 


MISCELLANEOUS  CHEMICALS 
TABLE  2.— Hiscellaneous  cHEnicALS  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972--C0NTI NUED 


Manufacturers'    identification   codes 
[according  to  list   in  table   3) 


HISCELLANEOUS  CHEMICALS,    CYCLlC--Continued 

2,6-Di-tert-butyl-p-cresol : 

*Food  grade 

*Tech 

2,5-Di-tert-butylhydroquinone 

Di-tert -butyl   diperoxyph thai ate 

1 ,3-Dichloro-5 ,5-dimethylhydantoin 

Dichloro-s-triazine-2,4,6ClH,3H,SH)trione    (Dichloroiso- 
cyanuric  acid),   and  salts. 

4,4' -Dichloro-3- (trifluoromethyl}carbanilide 

2,S-Dihydrothiophene- 1 ,1- dioxide    (Sulfolene) 

2,2'-Dihydroxy-4,4'-dimethoxybenzophenone 

3,S-Dihydroxy-3,S-dimethyl-l,2-peroxycyclopentane 

2,6-Dihydroxyisonicotinic   acid   (2,6-Dihydroxy-4-carboxy- 
pyridine) . 

2,2'-Dihydroxy-4-methoxyben2ophenone 

Diiodomethyl-p-tolyl   sul phone 

Diisopropyl benzene  hydroperoxide 

Di  i  s  opropy 1   ere  sols 

Diketene 

p-Dimethoxybenzene   (Dinethyl   ether  of  hydroquinone) 

2,5-Dimethyl-2 ,4-hexadiene 

2 ,6-Dimethylmorpholine 

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyriiiiidinol 

Di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyphenyl  phos 

phonate. 
1 ,2-Dioctylcyclobutane-3,4-bis(octaraethyleneisocyanate)-- 

*Dioxane  (1,4-Diethylene  oxide) 

1 , 3-Dioxolane 

Diphenylisodecyl  phosphite 

Dipropylene  glycol  salicylate 

4 - (Dodecy loxy) - 2-hydroxybenzophenone 

*Enzymes : 

Hydrolytic: 

Amylases 

Proteases 

Other 

Nonh yd ro lytic 

1 ,2-Epoxy-3-phenoxypropane    (Glycidyl  phenyl   ether) 

Ethyl   cellulose  phthalate 

Ethyl-a-cyano-6-pentyl«innamate 

2-Ethylhexyl  benzoate 

2-Ethylhexyl   p- dime thy laminobenzoate 

Ethylidene  norbomene 

*4-Ethylmorpholine 

*Flotation  reagents: 

Dicresylphosphorodithioic  acid   (Dicresylthiophosphoric 
acid) . 

Dicresylphosphorodithioic  acid,    ammonium  salt 

Dicresylphosphorodithioic  acid,   sodium  salt 

2,2'-Dimethylthiocarbanilide    (Di-o-tolyl thiourea) 

Rosin  amines 

Tall   oil   derived 

Thiocarbanilide    (Diphenyl thiourea) 

Furan  derivatives: 

2-Furaldehyde    (Furfural) 

Tetrahydrofurfuryl   alcohol 

Gallic  acid 


ASH,    HPC,    KPT,    SHC,   USR. 

ASH,    HPC,    KPT,    PRD,    SHC,    USR. 

EKT. 

WTL. 

GLY. 

FMB. 

CGY. 
PLC. 
GAF. 
WTL. 
EK. 

ACY. 

ABB. 

HPC. 

GIV. 

ALD,    EKT,   FMP. 

ASL,    EKT,   GAF. 

BPC. 

DOW,    UCC. 

MRK. 

CGY. 


DOW,    FER,    UCC. 
FER. 


SBC. 
DUP,    EKT. 


BAX, 
BAX, 
BAX, 
MLS, 

nup. 

EK. 
GAF. 

X. 

VND. 
UCC. 
BRD, 

ACY. 


ACY. 

KCU. 

DUP,    RBC. 

HPC. 

HN. 

ACY. 


CRN,  GPR,  MLS,  PFZ,   mP ,   RH. 

CHH,  DOL,  MLS,  PEN,    PFZ,   PMP,    SPR. 

JFR,  MLS,  PFZ,  RH,   WBC. 

OMS,  PLB,  SPR. 


QKO. 
QKO. 


SY^ITHETIC  ORri/\NIC  CHEMICALS.  1972 

TABLE   2.--niSCELLANE0US    CHEMICALS    FOR    WHICH    U.S.     PRODUCTION    OR    SALES    WERE    REPORTED^ 
IDENTIFIED    BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'   identification  codes 
(according  to   list   in  table   3] 


mSCELLANEOUS  CHEMICALS,    CYCLIC--Continued 

♦Gasoline   additives: 

N,N'- Bis (1,4-dime thy lpentyl)-p-phenylenedi amine — 

Butylphenols,   mixed 

N-sec-Butyl-N-phenylphenylenedi amine 

4,4'-Di-5ec-butylaminodiphenylmethane 

6-tert-Butyl-o-cresol 

2,6-Di-tert-butylphenol 

N,N'-Di-sec-butyl-p-phenylenediamine 

2,6-Di-tert-butyl-a-dimethylamino-p-cresol 

N,N'-Dicyclohexyl-p-phenylenediamine 

2, 6- Diethyl aniline 

N,N'-Diisopropyl-p-phenylenedi amine 

N,N'-Disalicylidene-1 ,2-propanediamine 

Methyl eye lopentadienylmanganese  tricarbonyl 

4,4' -Methylenebis  C2,6-di-tert-butylphenol) 

4,'4'-Thiobis  C6-tert-butyl-o-cresol) 

2,2'-Thiobis(6-tert-butyl-p-cresol) 

l,3,5-Tris(3,5-di-tert-butyl-4-hydroxybenzyl)- 
mesitylene. 

Other 

Glyceryl  p-aminobenzoate 

Guanosine  and  derivatives 

N-Heptyl-p-hydroxybenzoate 

*Hexamethylenetetramine,  tech 

Homomenthyl  salicylate 

Hydrab amine  hydrobromi  de 

Hydrindan t  in 

p-Hydroxybenzoic  acid  esters: 

Benzyl  p-hydroxybenzoate 

*Butyl  p-hydroxybenzoate    CButylparaben) 

Ethyl  p-hydroxybenzoate    (Ethylparaben) 

n-Heptyl  p-hydroxybenzoate    [Heptylparaben) 

*Methyl  p-hydroxybenzoate    (Methylparaben) 

*Propyl  p-hydroxybenzoate    (Propylparaben) 

Other 

N-(Hydroxyethyl)piperazine 

2-Hydroxy-4-methoxybenzophenone 

Hydroxymethyl  dimethyl-5 ,5-hydantoin 

2-Hydroxy-3-phenoxytiropane 

2- (2-Hydroxy-S-tert-octylphenyl)benzotriazole 

1 -Hydroxy- 2-Dyridine  (Omadine) 

1 ,2,3-Indantrione  monohydrate   (Ninhydrin) 

Inosine  and  derivatives 

2-(p-Iodophenyl)-3- (p-nitrophenyl)-5-phenyl-2H- 
tetrazolium  chloride. 

Isopropyl-o-cresols 

'Lubricating  oil   and  grease   additives: 
*Oil-soluble  petroleum  sulfonates: 

Oil-soluble  petroleum  sulfonate,   ammonium  salt-- 

Oil-soluble  petroleum  sulfonate,   barium  salt 

*Oil-soluble  petroleum  sulfonate,    calcium  salt — 
Oil-soluble  netroleum  sulfonate,   magnesium  salt- 

*Oil-soluble  petroleum  sulfonate,   sodium  salt 

•Other 

*Phenol   salts : 

Barium  alkylphenolates 

Calcium  alkylphenolates 

Calcium  salt  of  octylphenol-formaldehyde 

Other '- 

All   other 

p-Menthane 

8-p-Menthyl   hydroperoxide 

p-Methoxybenzylidenemalonic   acid,    diethyl    and 
dimethyl  esters. 


EKT 

DOW, 

TNA. 

X. 

X. 

TNA 

TNA 

DUP 

EKT.  USR,  X. 

TNA. 

X. 

TNA. 

DUP 

EKT,  USR. 

DUP 

SM,  TX. 

TNA. 

TNA. 

TNA. 

ASH. 

TNA. 

EKT, 

SM,  TNA,  X. 

VND. 

PLB. 

WSN. 

BOR, 

DUP,  HKD,  HN,  HMP,  PLS,  UCC 

ARS. 

ABB. 

HEX. 

RSA. 

HN, 

LEU,  WSN. 

UN, 

W.SN. 

WSN. 

ARS, 

HN,  LEM,  WSN. 

ARS, 

HN,  LEM,  WSN. 

WSN. 

UCC. 

ACY, 

GAP. 

GLY. 

TCH. 

ACY. 

OMC. 

HEX, 

PIC. 

PLB. 

MOR,    NTL. 

CO,    LUB. 

CO,    ENJ,    LUB,    DRO,    PAR,  TX,    WTC,    x. 

CO,    LUB. 

CO,    ENJ,   MOR,    PAR,    SHC,    SOC,    SOI,    WTC. 

CO,    LUB,    TX. 

TX. 

ORO,   TX. 

SHC. 

CCA,    ENJ,    GOC,   ORO,   TX,   x. 

ATR,    ENJ,    GOC,    LUB.   ORO,    PLC,    SM,   TX,   UCC. 

HPC. 

HN,    HPC. 

ACY. 


MISCELLANEOUS  CHEMICALS 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to  list  in  table  Z) 


MISCELLANEOUS  CHEMICALS,    CYCLIC--Continued 

4-Methoxyphenol 

Methyl   o-cresotinate 

2,2'-Methylenebis(4-chlorophenol)    (Dichlorophene) 

Methylenebis(phenoxypropanol) 

2,2'-Methylenebis(3,4,6-trichlorophenol)    (Hexachloro- 
phene) . 

Methyl   gal  late 

Methylglucoside 

4-Methylmorpholine 

Methyl  phenyl  phosphates 

4-Methylpiperazine 

l-Methyl-2-pyrrolidone,   monomer 

*Morpholine 

Morpholine  salt  of  p-toluenesulfonic  acid 

*Naphthenic   acid  salts: 

Aluminum  naphthenate 

Barium  naphthenate 

Cadmium  naphthenate 

*Calcium  naphthenate 

Chromium  naphthenate 

Cobalt   lead  manganese  naphthenate 

*Cobalt  naphthenate 

*Iron  naphthenate 

Lead  manganese  naphthenate 

*Lead  naphthenate 

Lithium  naphthenate 

*Manganese  naphthenate 

Nickel  naphthenate 

Rare  earths   naphthenates 

Sodium  naphthenate 

Strontium  naphthenate 

*Zinc  naphthenate 

1-Naphthenyl- 2- tallow  diamine ^ 

Ninhydrin 

Norcamphor 

Octadecyl-3- (3,S-di-tert-butyl-4-hydroxyphenyl)- 
propionate. 

Organic  mercury  compounds:      Phenylmercuric  borate 

Phenetole ■■ 

2-Phenoxyethanol    (Ethylene  glycol  monophenyl  ether) 

2- (2-Phenoxyethoxy)ethanol    (Diethylene  glycol  phenyl 
ether) . 

2-Phenoxypropanol 

2,2'-  (p-Phenylene)diethanol 

m-Phenylene  isonaph thai  amide 

Phenyl  hydrogen  phosphate 

5- Phosphorylribose-1 -pyrophosphate 

Photographic   chemicals: 

N-(o-Acetamidophenethyl)-l-hydroxy-2-naphth amide 

N- [2- (4-Amino-N-ethyl-m-toluidino)ethyl]methane- 
sulfonamide. 

2- (4-Amino-N-ethyl-m-toluidino)ethyl   sulfate 

3-Amino-l,2,4-triazole 

Benzotriazole 

a-Benzoyl-o-methoxyacetanilide 

p-Benzylaminophenol  hydrochloride 

Catechol 

2 - Ch 1 oro- N, N- die thy 1-p-phenylene diamine  hydrochloride- 
3-Chloro-4-diethylaminobenzenedia2onium  salts    (p- 
Diazo-2-chloro-N,N-diethylaniline  salts) . 

Chlorohydroquinone 

2,4-Diaminophenol  dihydrochloride   (Amidol) 


ARS,    ASL,    EKT. 

TCC. 

GIV,    GLY. 

JCC. 

GIV. 

HSH. 

CRN. 

JCC,    UCC. 

TNA. 

UCC. 

GAP. 

DOW,   JCC,   UCC. 

AMB. 


WTC. 


CCC,    FER,    HN.   MCI,    SHP,   TRO,    IVTC. 


CCC,  FER,    HN,   MCI,    TRO,    WTC. 

CCC,  HN,   MCI,   TX,   WTC. 

CCC,  FER,   MCI.   SHP,   TRO,  TX,   WTC. 

MCI. 

CCC,  FER,   HN,   MCI,   SHP,   WTC. 


CCC,   FER,    HN,   MCI,   SHP,   WTC. 


SHP, 

CCA. 

CCA. 

CCA, 

MCI. 

HN. 

CCA, 

CCA, 

CCA. 

CCA, 

CCA, 

CCA, 

CCA. 

CCA, 

CCA. 

CCA. 

CCA, 

,SM. 

HEX. 

ALD. 

CGY. 


TRO. 

RSA. 

DOW,   JCC,   TCH. 

DOW. 

JCC. 
EKT. 
DUP. 

HDG,    SM. 
PLB. 

EKT. 
EKT. 

EKT. 

FHT. 

EK,   FHT,  MRT,   SW. 

EKT. 

EK. 

RSA. 

IDC. 

ESA,    FMT. 

EK. 
VPC. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED    BY    MANUFACTURER.    1972--C0NT INUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


MISCELLANEOUS  CHEMICALS,    CYCLIC--Continued 

Photographic  chemicals--Continued 

2N-(2,4-Di-tert-amylphenoxyacetamido)-4,6-dichloro- 
m-cresol . 

4-Diazo-2,5-diethox>Tiiorpholinobenzene 

4-Diazo-3,5-diethoxythiocresol   salts 

*2,5-Diethoxy-4-morpholinobenzenediazoniujn  chloride- 


*p-Diethylaminoben2enediazonium  chloride 

p-Diethylaminobenzenediazonium    fluoborate 

p-Diethylaminobenzenediazoniiun   fluophosphate 

N,N-Diethyl-p-phenylenedi amine  hydrochloride 

*N,N-Diethyltoluene-2,5-diamine,   monohydrochloride — 
2,5-Dihydroxy-p-benzenedisulfonic  acid  dipotassium 

salt. 

2,S-Dihydroxybenzenesulfonic   acid 

*p- Dime thy  1 ami nobenzenediazonium  chloride 

2(p-Dimethylaminostyryl)-5-methylthiadiazole-5- 

6-hydrox\'ethochloride. 

2,5-Dimethylbenzothiazole 

4N- (2' ,6 '- Dime thy lmorpholinyl)benzenediazoni urn 

chloride. 

p-Diphenylaniinediazonium  sulfate 

p- (N-Ethylbenzimido)benzenediazonium  chloride 

*p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium 

chloride. 
N-Ethyl-N-hydroxye thy 1-p-phenylenedi amine   sulfate — 
3- (4'-Hexadecenylmonoamidosuccinic   acid) -1-hydroxy- 

4-sulfo-2-N-n-octadecyl)naphthamide. 

Hy droquinone    (Hydroquinol) 

*p[(2-Hydroxyethyl)inethylamino]benzenediazoniuiii 

chloride. 

N- C2-Hydroxyethyl)-6-resorcylamide 

2-Hydroxynaphthoic  alky 1 amide 

1- (3-Hydroxyphenyl)urea 

4-Methoxy-l-naphthol 

p-Methylaminophenol  sulfate 

5-Methylbenzotriazole 

5-Methyl-l,7-dihydroxy-l ,3,4-triazaindolizine 

4-Methy 1-2 (p-bis-hydroxyethyl aminos tyryl)thiazole- 3- 

B-hydroxye  thoch lori  de . 

4-Methyl-l-phenyl-3-pyrazolidinone 

2-Methylthiazoline 

4-Morpholinylbenzenediazonium  salts 

p-Morpholinyl-2 ,5-dibutoxybenzenediazonium  chloride- 

6-Nitrobenzimidazole 

Octylphenyl   salicylate 

N-Phenyl- (p-phenylene}diamine  monohydrochloride 

l-Phenyl-3-pyrazolidine 

l-Phenyl-3-pyrazolidone 

4-Phenylpyrocatechol 

1 -Phenyl- 2- tetrazoline-S-thi one 

2- (Phenyl thio)quinoline 

4N- (l-Pyrrolidyl)-ra-toluenediazonium  chloride 

2-Resorcylic  monoethanol amide 

2,2' ,4,4'-Tetrahydroxydiphenyl   sulfide 

4,4'-Thiodiresorcinol 

l-(2,4,6-Trichlorophenyl)-3-(4-nitroanilino)-2- 

pyrazolin-5-one. 

All  other 

Phthalic  acid,  lead  salt,  dibasic 

Picramic  acid,  sodium  salt 

Pine  oil,  synthetic 


X. 

FMT. 

FMT. 

ALL,  ESA,  HST. 

ESA,  FMT,  IDC,  MRT. 

IDC. 

IDC. 

EKT. 

EKT,  FMT,  IDC. 

EK. 


ESA,  FMT,  IDC. 


FMT. 
IDC. 

F^^T. 

FMT. 

ESA,  FMT,  IDC. 


EKT. 

ESA,  FMT,  IDC. 

MRT. 
FMT. 
FMT. 

X. 

EK. 
EK. 
FMT. 


WAY. 

FMT. 

IDC. 

IDC. 

EK,  FMT. 

EKT. 

EK. 

CCY. 

WAY. 

X. 

EK. 

EK. 

IDC. 

FMT. 

FMT. 

BKC. 

EKT. 

EK,  ESA,  FMT,  IDC,  NES,  x,  x. 

NTL. 

SDC. 

GLD. 


niSCELLANEOUS  CHEMICALS 

TABLE    2,--niSCELLANE0US    CHEMICALS    FOR    WHICH    U.S.     PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED    BY   MANUFACTURER,    1972  — CONT INUED 


Manufacturers'    identification   codes 
(according  to  list   in  table   3) 


niSCELLANEOUS  CHEMICALS,    CYCLIC--Continued 

*a-Pinene 

*g-Pinene 

Pinene,  sulfate 

Pinene,  wood 

Piperazine,  ethoxylated 

Poly-4- (2-acryIoxyethoxy)-2-hydroxybenzophenone 

Polydodecylbenzenesulfonic  acid,  calcium  salt 

Polyethylene  tereph thai ate 

Polyphenol  esters 

Polyvinyl  ph thai ate 

Propyl  gall  ate 

Pyrogallol  (Pyrogallic  acid) 

2- Pyrrol idinone 

Resorcinol  monobenzoate 

Rosin  acid  salts : 

Aluminum  resinate 

Calcium  resinate 

Calcium  zinc  resinate 

Zinc  resinate 

Salicylanilide 

Salicylic  acid,  lead  salt 

Salvenol 

Sodium  cresoxide   (Cresylic  acid,    sodium  salt) 

Styrene  oxide 

Sucrose  benzoate 

Sulfinol  blends 

Sulfosalicylic   acid 

Tall  oil,   chemically  modified 

Tall  oil   salts    (Linoleic- rosin  acid  salts): 

Calcium  manganese   tallate 

Calcium  tallate 

♦Cobalt  tallate 

Copper  tallate 

Iron   tallate 

Lead  manganese   tallate 

*Lead   tallate 

•Manganese   tallate 

Zinc   tallate 

All   other 

Tannic  acid 

'Tanning  materials,   synthetic: 

Cresol  phenol   formaldehyde   condensate 

Hydroxytoluenesulfonic  acid,   formaldehyde  condensate 

(Cresol- formaldehyde   sulfonate),    sodium  salt. 
1-Naphthalenesulfonic   acid,    formaldehyde   condensate 

and  salt. 
2-Naphthalenesulfonic   acid,    formaldehyde   condensate 

and  salt. 
l-Phenol-2-sulfonic   acid,    formaldehyde   condensate 

(Phenol-formaldehyde,   sulfonated) . 
Styrene-maleic   anhydride   interpolymer,   partial   sodium 
salt. 

All   other 

Tetrabromobisphenol  A 

2,3,5,6-Tetrachloro-4- (methylsulfonyl) pyridine 

1,2,3,4-Tetrahydronaphthalene    (Tetralin) 

Tetrahydrothiophene 

Tetrahydrothiophene-1 ,1-dioxide    (Sulfolane) 

Tetrakis [methylene-3- (3' ,5'-di-tert-butyl-4'-hydroxy- 
phenol) propionate] methane. 

1 ,3,6,8-Tetranitrocarbazole 

Tetraphenyltin 


ARZ, 

ARZ, 

HPC. 

HPC. 

GAF. 

ACY. 

CO. 

DUP, 

HON. 

EK. 

EKT, 

HSH, 

GAF. 

EKT. 


HN,    NCI. 

CBY,    GLD,    HN,    HPC,    NCI. 


EK,    EKT,   GYR. 


HSH. 
MAL. 


JMS. 

CBY,    HN. 

CBY. 

HN. 

FIN,    PCW. 

NTL. 

HPC. 

DEX,    GOC. 

UCC. 

VEL. 

PLC. 

MON,   HRK. 

ZGL. 


CCC,    HN,   MCI,   TRO,   WTC. 

CCC,    PER,    HN,   MCI,    SMP,   TRO,    WTC. 

MCI,    SHP. 


CCC,    FER,    HN,   MCI,    SHP,    WTC. 
CCC,   FER,    HN,   MCI,    SHP,    WTC. 


MCI. 
CCA, 
CCA, 
CCA, 
CCA. 
MCI. 
CCA, 
CCA, 
MCI. 
WTC. 
MAL. 


DA. 
CGY,    DA. 

DA. 

AKS,    GRD,    HN,    RH. 

RH. 

DUP. 

CGY,    HN. 

GTL. 

DOW. 

DUP,   UCC. 

PAS. 

PLC. 

CGY. 

SDC. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY  MANUFACTURER,  1972— CONT INUED 


Haoiufacturers'   identification  codes 
(according  to  list   in  table  3) 


MISCELLANEOUS  CHEMICALS,    CYCLIC--Continued 

♦Textile  chemicals,   other  than  surface- active  agents: 

Dimethyloldihydroxy  ethylene  urea 

1-  [(Octadecyloxylmethyllpyridinium  chloride 

Phenol,   sulfurated 

Tetrahydro-3,5-bis(methoxyTnethyi;)-4H-l,3,5-oxadiazin- 
4-one  (l,3-Bis(niethoxymethyl)uron) . 

2,2' ,4,4'-Tetrahydroxybenzophenone 

Tri(Phenyloxyme thy l)trimethyloxymethylmel amine 

2,2'-Thiobis(4,6-dichlororophenol) 

[2,2'-Thiobis(4-octylphenolate)]-n-butylamine  nickel--- 

Thiophene 

Thymidine  and  derivatives 

o-Toluidine   formaldehyde  hydrochloride 

Trial lyl   cyanurate 

3,4' ,5-Tribromosalicylanilide 

3,4,  4'-Trichlorocarbanilide 

Trimethylaminoethylpiperazine 

3,5,5-Trimethyl-2-cyclohexen-l-one    (Isophorone) 

2,4,6-Trinitroresorcinol   and   lead  derivative 

s-Trioxane 

Triphenyl  phosphite 

Triphenyl   sulfonium  chloride 

Triphenyl tin 

Triphenyltin   phosphine 

Uridine  derivatives 

Vinyl  norbornene 

l-Vinyl-2-pyrrolidinone,   monomer  and  polymer 

l-Vinyl-2-pyrrolidinone   -   acr>'lic  copolymers 

l-Vinyl-2-pyrrolidinone  -   ethylacrylate,   copolymer 

l-Vinyl-2-pyrrolidinone  -  methylacrylic  acid  - 
dimethylamine  ethyl   ester,   copolymer. 

l-Vinyl-2-pyrrolidinone  -  vinyl   acetate  copolymer 

l-Vinyl-2-pyrrolidinone  -   other  copolymers 

MISCELLANEOUS  CHEMICALS,   ACYCLIC 

Cellulose  Esters  and  Ethers 

♦Cellulose  esters: 

♦Cellulose   acetate 

Cellulose   acetate  butyrate 

Cellulose   acetate  propionate 

Cellulose  propionate 

♦Cellulose    ethers": 

Hydroxyethylcellulose 

Hydroxypropylcellulose 

Methylcellulose 

♦Sodium  carboxymethylcellulose,    100% 

All   other 


DUP. 
GAP. 
DEX. 

GAP. 

X. 

SDH. 

ACY. 

PAS. 

PLB. 

RBC. 

ACY. 

FIN,    PCW,    SW. 

MON. 

JCC. 

ENJ,    UCC. 

RBI. 

CEL. 

MON. 

PIS. 

X. 
X. 

PLB. 
UCC. 
GAP. 
GAP. 
GAP. 
GAP. 

GAP. 
GAP. 


AV,    CEL,    DUP,    EKT. 

EKT. 

EKT. 

CEL. 

UCC,    X. 

X. 

DOW. 

BUK,   DUP,    KON,    WMP,    WYN, 

EK,   UCC. 


MISCELLANEOUS  CHEMICALS 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported 

IDENTIFIED   BY   MANUFACTURER^    1972--CoNTINUED 


Manufacturers'   identification  codes 
(according  to  list   in  table  3) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC--Continued 

Lubpioating  Oil  Additives 

*Phosphorodithioates    (Thiophosphates) : 

Di-2-ethylhexylphosphorodithioic  acid 

Di-N-propylphosphorodithioic   acid 

Zinc  alkyl   dithiophosphate 

Zinc  dialkyl  phosphorodithioate 

Zinc  di (butylhexyl)   phosphorodithioate 

Zinc  dihexyl  phosphorodithioate 

Zinc  diisopropyl  dihexyl  phosphorodithioate 

Zinc  hydrocarbon  dithiophosphate 

Polybutylene 

Sulfur  compounds : 

Aliphatic  hydrocarbon  sulfides 

Chlorosulfurlzed  sperm  oil 

Phosphosulfurized  polybutene 

*Sulfurized    lard   oil 

Sulfurized  sperm  oil   and  substitutes 

Other  sulfur  compounds 

All   other 

NitTogenous  Ccmpounds 

Acetamide 

Acetamidine  hydrochloride 

Acetamidoethanol    (N-Acetyl-ethanolamine) 

Acetonitrile 

Acrylomide  monomer 

*Acrylonitrile 

Acyclic  isocyanates    (complex) 

Adiponitrile 

1-Allyl- 3- (2-hydroxyethyl) -2- thiourea 

Allyltriraethylaimnonium  chloride 

'Amines: 

Allyl amines 

Butyl amines  : 

*n-Butylamine,  mono-  

*Di-n-butylamine 

Diisobutyl amine 

tert-Butylamine,  mono-  

Tri-n-butyl amine 

n-Butylethyl amine 

Diethylaminoe thy 1 amine 

*Diethylenetri amine 

N'  ,N '- Die thy 1-1, 4 -pent anedi amine  (Novoldi amine) 

Die  thy  laminop  ropy  1  amine 

Dimethylaminop ropy 1 amine 

1 ,3- Dime thy Ibutyl amine 

Dipropylenetri amine 

*Ethylamines : 

*Diethylamine 

Diethyl amine  hydrochloride 

Ethylamine,  mono 

Triethylamine 

•Ethylenedi amine 

Ethylenedi amine  salts 

(2-Ethylhexyl) amine,  mono-  

*1 ,6-Hexanedi amine   (Hexamethylenediamine) 

3,3'- Imi nob ispropyl amine 


SFA. 

SFA. 

SM. 

EN  J. 

ORG. 

ATR,   MON. 

X. 

LUB. 
EN  J. 

LUB. 

CCW. 

EN  J. 

CCW,    GOC,   QCP,   WBG. 

CCW. 

ATR,    CCW,    ENJ,    HK,   SM,  TX. 

ALX,   ATR,    ENJ,    GOC,    LUB,   MON,    NLC,   ORG,    SM,    SOI,    UCC, 


ACS. 
HRK. 
RBC. 
EKX, 
ACY, 
ACY, 
MOB. 
DUP, 
FMT, 
VAC. 


MON,    SOH. 

SOH. 

BFG,    DUP,   MON.   SOH. 

MON. 
IDC. 


SHC. 

AIP,    PAS,   UCC,   VGC. 

AIP,    PAS,    UCC,  VGC. 

AIP,    PAS,   VGC. 

MON,   RH. 

PAS,   VGC. 

PAS. 

PD. 

DOW,   JCC,  UCC. 

SDH. 

UCC. 

JCC,   UCC. 

PAS. 

UCC. 

AIP,    PAS,   UCC. 

BKL,    EK. 

AIP,    PAS,   UCC. 

AIP,    PAS.    UCC. 

DOW.   JCC,   UCC. 

EK. 

VGC. 

CEL,   DUP,    ELP,   MON. 

JCC. 


SYNTHETIC  OPnANIC  CHEMICALS.  1972 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.   production  or  sales  were  reported. 

IDENTIFIED    BY    MANUFACTURER.    1972--CONTINUED 


Manufacturers'   identification  codes 
(according  to   list   in   table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Nitrogenous   Coripounds--Continued 

* Amines --Continued 
Isopropylamines : 

*Diisopropylajnine 

Isopropylainine ,    mono-    

Methylamines: 

*Dime thy 1  amine 

Dimethyl amine  hydrochloride 

Dimethyl amine  sulfate 

*Methylamine ,   mono-    

Methylamine  hydrochloride 

*Trimethylamine 

n-Octylamine,   mono-   

Oleylamine 

Pentaethylenehexamine 

Pentylamines    (Amylamines) : 

Dipentylamine 

Pentylamine,   mono-   

Tripentylamine 

Poly alky lene  polyamines 

1 ,2-Propanedi amine    (Propyl enediamine) 

1 , 3- Prop anedi amine    (1,3-Diaminopropane) 

Propylamines : 

*Dipropyl amine 

*Propylamine ,   mono-   

Trip  ropy lamine 

*Tetraethvlenepent amine 

N,N,N   ,N  -Tetramethyl- 1 ,3-butanediamine 

Tetramethyle thy lenedi amine 

*Triethylenetetramine 

Other  amines 

2 - Amino- 1-butanol 

2-Aminoethanol    (Monoethanolamine)    sulfite 

Aminoethoxyethanol 

*2-  (2-Aminoethylamino)ethanol    (Aminoethylethanolamine) - 
2-Aminoethyl  mercaptoacetate    (Monoethanolamine  thio- 
glycolate) . 

2-.'Vmino-2-ethyl-l  ,3-propanediol 

.^minoguanidine  bicarbonate 

2-Amino-2- (hydroxymethyl) -1 , 3-propanediol    (Tris- 
(Hydroxymethyl'jaminomethane)  . 

2 -Amino- 2- me thy 1-1, 3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Amino-2-methyl-l-propanol  hydrochloride 

l.l'-Azobisformamide 

2,2'-Azobis[2-methylpropionitrile]    (Azobisisobutyro- 
nitrile) . 

Bilirubin 

1,3-Bis (hydroxymethyl)urea  (Dimethylolurea) 

N,0-Bis ( trimethy 1 si lyl)acet amide 

Biuret 

N-Bromoacet amide 

N-Bromosuccnimide    (Succinibromimide) 

2-Butanone   oxime 

But  yldiethano lamine 

1- Butyl- 3- ethyl -2- thiourea 

Butyl    Lsocyanate 

Butyraldehyde   oxime 

n-Butyronitrile 

*Caprolactam   (2-Oxohexamethylenimine) 


AIP,    PAS,    UCC. 
AIP,    PAS,    UCC. 

AIP,    COM,    DUP,    GAP. 

EK,    RSA. 

DUP,    RH. 

AIP,    COM,    DUP,    GAP. 

EK,    RBC. 

AIP,    COM,    DUP,    GAP. 

VGC. 

X. 

JCC,   UCC. 


PAS, 

VGC. 

ALB, 

PAS. 

PAS. 

NLC. 

UCC. 

JCC, 

X. 

AIP, 

PAS, 

UCC,    VGC. 

PAS, 

UCC, 

VGC. 

PAS, 

VGC. 

DOW, 

JCC, 

UCC. 

UCC. 

RH. 

DOW, 

JCC, 

UCC. 

ALB. 

ALD, 

BKL,   CGY,    DUP,    EK,   NES,   NIL,   ONX,    PAS,    PIC 

SNW,    UCC,    VGC,    X. 

COfL 

EVN, 

VND. 

JCC. 

DOW, 

HDG, 

JCC,   UCC. 

EVN, 

HAB. 

COM. 

COM. 

COM. 

COfL 

COM. 

VAL. 

FMT, 

NPI, 

USR. 

DUP. 

PFN. 

GLY, 

X. 

PIC. 

DOW. 

ARA. 

ARA, 

SDW. 

ACP. 

PAS. 

PAS. 

OWN, 

OTC, 

UPJ. 

ACP. 

EKX. 

ACP, 

CNP, 

DEC. 

MISCELLAMEOUS  CHEMICALS 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER,    1972~C0NTINUED 


Manufacturers'   identification  codes 
(according  to  list   in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 
Nitrogenous  Compounds--Continued 

Chlorocholine   chloride 

2 -Chloro-N,N- dimethyl ethyl  amine    (Dime thy laminue thy 1 
chloride)    hydrochloride. 

3 - Ch 1 or o-N,N- dimethyl propyl  amine 

2-Chloro-N,N-dimethylpropylamine  hydrochloride 

3-Chloro-N ,N-dimethylpropylamine  hydrochloride 

3-Chloro-2-hydroxypropyltrimethyl    ammonium  chloride-- 

Chloro-N- (2-hydroxyethyl)acet amide 

N-Chlorosuccinimide    (Succinichlorimide) 

2-Chloro-N ,N-diethylethylamine  hydrochloride 

Choline  base 

Choline  bicarbonate 

Choline  bisulfite 

Coco  nitrile 

Coconut   oil   acids   -   ammonium  condensate 

Coconut  oil   amide 

Creatine  and   creatinine 

Crotononitrile 

Cyanoacetic  acid 

2-Dibutylaminoethanol 

1 , 3- Dibuty 1-2- thiourea 

1,4-Dicyanobutene 

Diethanolamine  polyoxypropylene  ether 

2-DiethyIaminoethanol 

2- (2- Diethyl aminoethoxy)ethanol 

2-Diethylaminoethyl   aery I ate 

2-Diethylaminoethyl  methacrylate 

N,N-Diethyldodecanamide 

Diethylhydroxyl amine 

1 ,3- Die thy 1-2- thiourea 

Diisopropylaminoethanol 

N,N- Dimethyl ace t amide 

*2-Dimethylaminoethanol 

3-Dimethylaminopropionitrile 

Dime thy laminoe thy 1  methacrylate 

Dime thy 1 amino- 2- prop anol 

N,N-Dimethylformamide 

1,1- Dime thy Ihydrazine 

2,5-Dithiobiurea 

Eruc amide 

Erucamide    -    lauraraide 

*Ethanolamines : 

*2-Aminoethanol    (Monoethanolamine) 

*2,2 '-Aminodiethanol    (Diethanolamine) 

*2,2 '2'  '-Nitrilotriethanol    (Triethanolamine) 

Ethanolamine  hydrochloride,    (60%) 

Ethoxylated  amides 

Ethoxymethoxyp ropy 1 amine 

3-Ethoxypropionitrile 

2- Ethy laminoe thanol    (Ethylmonoethanolamine) 

Ethyl   carbamate 

Ethyl   carbodiimide  hydrochloride 

Ethyl    cyanoacetate 

N,N' -Ethylene  bis (stearamide) 

Ethyleneimine,   monomer 

Ethyleneimine,  polymer 

Ethylenethiourea 

Ethyl    isocyanate 

Ethy Iraonoethanol amide,    mixed 

Ethyl   thiourea 

Fish  oil    fatty  acid  amide 


ACY. 
HEX,   HCH. 


MCH. 

MCH. 

OTC. 

KF. 

ARA. 

HEX,   MCH. 

RH. 

TCH. 

WAY. 

ARC,   ASH. 

PC. 

ARC. 

PFN. 

KF. 

KF. 

AAC,    PAS. 

PAS,    RBC. 

DUP. 

JCC. 

AAC,   DUP,    PAS,    UCC. 

PAS. 

ABC,    UCC. 

DUP. 

EK. 

PAS. 

PAS,    RBC. 

PAS,    UCC. 

DUP. 

AAC,    PAS,    RH,   UCC. 

ACY. 

AAC,    ABC. 

COM,    PAS. 

AIP,    DUP. 

FMP. 

ACY. 

ASH,   FIN,   HUH. 

FIN. 


DOW, 

DOW, 

DOW, 

WSN. 

ARC. 

JCC. 

ACY. 

PAS. 

FHP. 

OTC. 

KF. 

CTN. 

DOW. 

DOW. 

PAS. 

OTC. 

PAS. 

OTC. 

HUM. 


GLY,   JCC,   MAT,   OMC,   UCC. 
JCC,   MAT,   OMC,    UCC. 
JCC,  HAT,   OMC,   UCC. 


SYNTHETIC  ORGANIC  CHE1ICALS.  1Q7? 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED    BY   MANUFACTURER,    1972--CONT INUED 


Manufacturers'   identification  codes 
(according  to  list  in  table  3) 


MISCELUVNEOUS  CHEMICALS,    ACYCLIC- -Continued 
Nitrogenous  Compounds — Continued 

Formamide 

Formamidine  disulfide  dihydrochloride 

Glycine  (Aminoacetic  acid) 

Glycine  ethyl  ester  hydrochloride 

Glycolonitrile 

4-Guanyl-l-nitrosoguanyl-l-tetrazine 

*Hexariethylenediajnnionium  adipate    (Nylon  salt) 

Hydracrylonitrile    (Ethylene    cyanohydrin) 

2- (Hydroxyraethyl)-2-nitro-l ,3-propanediol    (Tris- 
(hydroxymethyljnitrome thane) . 

N-Hydroxymethylstearamide 

12-Hydroxy5tearamide 

Imino  diacetic  acid 

Imino  diacetic  acid,   disodium  salt 

3, 3' -Irainodi- 1,2 -propanediol 

Isopropanolamines : 

l-Aiiiino-2-propanol    (Monoisopropanolamine) 

1,1'- Iminodi-2-propanol    (Diisopropanolamine) 

1 ,1' ,1 ' '-Nitrilotri-2-propanol    (Triisopropanolamine)-- 

3-Isopropoxypropionitrile 

3-Isopropoxypropylamine 

2-Isopropylaiiiinoethanol 

Isopropyl  ethyl thionocarbamate 

Isopropyl   isocyanate 

Lactonitrile 

Lauronitrile    (Dodecyl   nitrile) 

Methacrylamide 

3-Methoxypropyl amine 

2-Methylaininoethanol    (N-Methylethanol amine) 

Methyl  carbamate 

Methyl   cyanoacetate 

Methyl  a-cyanoacrylate 

N,N'-Methylenebis (acrylamide) 

N,N'-Methylenebis (octadecan amide) 

Methyl   isocyanate 

2,2'-(Methylimino)diethanol    (Methyldiethanolamine) 

2-Methyllactonitrile    (Acetone   cyanohydrin) 

2-Methyl-2-nitro-l,3-propanediol 

2-Methyl-2-nitro-l-propanol 

Methylpo lye thanol amine 

N-Methyl taurine 

N-Methylurea 

*Nitriloacids   and  salts: 

(Diethylenetrinitrilo)pentaacetic  acid 

{Diethylenetrinitrilo)pentaacetic  acid,   monosodium 
hydrogen  ferric  salt. 
*(Diethylenetrinitrilo)pentaacetic  acid,  pentasodiura 
salt. 
(Diethylenetrinitrilo)pentaacetic   acid,   soditim  salt — 

N,N-Dihydroxyethylglycine,   sodium  salt 

Ethanoldiglycine,   disodium  salt 

*(Ethylenedinitrilo)tetraacetic  acid   (Ethylenediamine- 
tetraacetic  acid). 
(Ethylenedinitrilo)tetraacetic  acid,    calcium  disodium 

salt. 
(Ethylenedinitrilo)tetraacetic  acid,   diammoniuiii  salt-- 

*(Ethylenedinitrilo)tetraacetic  acid,   disodium  salt 

(Ethylenedinitrilo)tetraacetic  acid,   disodium  copper 

salt,   dihydrate. 
(Ethylenedinitrilo)tetraacetic  acid,   disodium  zinc 
salt,    dihydrate. 


DUP. 

WAY. 

CHT. 

BPC. 

ACY, 

KF. 

RBI. 

cel 

DUP, 

MON. 

AAE. 

COM. 

ICI. 

HUM 

HMP. 

HMP. 

DUP. 

DOW, 

UCC. 

DOW, 

UCC. 

DOW, 

UCC. 

DUP. 

DUP. 

PAS. 

DOW. 

OTC. 

MON. 

ASH. 

SOH, 

X. 

JCC. 

UCC. 

BKL, 

FMP. 

KF. 

EKT. 

ACY, 

SOH. 

ARC. 

UCC. 

PAS, 

UCC. 

RH, 

X. 

COM. 

COM. 

GAF. 

GAP. 

EK, 

lil. 

DAN, 

HMP. 

CGY. 

CGY, 

DOW, 

HMP. 

CGY, 

RPC. 

DOW, 

HMP. 

HMP. 

CGY, 

DOW, 

HMP. 

CGY, 

DOW. 

DOW. 

CGY, 

DOW, 

EK,   HMP 

CGY, 

HMP. 

CGY, 

DOW, 

HUP. 

r^ISCELLANEOUS  CHE!^ICALS 
TABLE  2, --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to  list   in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Nitrogenous  Compounds — Continued 

*Nitriloacids   and  salts--Continued 

(Ethylenedinitrilo)tetraacetic  acid,  manganese  salt 

(Ethylenedinitrilo)tetraacetic  acid,   monosodium  iron 

salt. 
(Ethylenedinitrilo) tetraacetic   acid,    tetraajmnonium 

salt. 
(Ethylenedinitrilo)tetraacetic  acid,   tetrapotassium 
salt. 
*(Ethylenedinitrilo)tetraacetic  acid,    tetrasodium  salt-- 

(Ethylenedinitrilo)tetraacetic  acid,   trisodium  salt 

(N-Hydroxye thy lethylenedinitrilo)tri acetic  acid 

(N-Hydroxyethylethylenedinitrilo) triacetic   acid,    coppei 

salt. 
(N-Hydroxyethylethylenedinitrilo) triacetic  acid,   iron 

salt. 
(N-Hydroxye thy le thy lenedinitrilo) triacetic  acid, 
manganese  salt. 
*(i4-Hydroxyethylethylenedinitrilo)triacetic  acid,   tri- 
sodium salt. 

Nitrilotri acetic  acid 

Nitrilotriacetic  acid,   disodium  salt 

Nitrilotriacetic  acid,   trisodium  salt 

Nitrilotriacetic  acid,    zinc  salt 

Other 

2-Nitro-l-butanol 

Nitroe thane 

Nitromethane 

1-Nitropropane 

2-Nitropropane 

•Nylon,   6  and  6/6  polj-mer  for  fiber 

Octadecyl    isocyanate 

Oleamide    (Octadecene  amide) 

Oleic  acid  -   ethylenedi amine   condensate   (amine/acid 
ratio=l/2) . 

Oleic  acid  -  methanolamine   condensate,   ethoxylated 

Oleonitrile   (Octadecene  nitrile) 

Oleoylhydroxamic  acid 

Oleoylpalmitamide 

*Pentaerythritol   tet rani t rate 

Pentyl  nitrate    (Amyl  nitrate)    6  hexyl  nitrate 

*Polyacr>-l  amide 

Polyacrylamide  polymers   other  than  polyacrylamide 

Polyacrylonitrile 

Polyacrylonitrile,  hydrolyzed 

Polyalkylene  amine- 

Polyamide  resin    (flake)- 

Polyglycol amine 

Polyoxypropylenediamine 

n- Propyl   carbamate 

Propyl    isocyanate 

Ricinolamide 

Sarcosine    (N-Methylaminoacetic   acid) 

Semicarbazide  base 

Serai carbazide  hydrochloride 

Stearamide   (Octadecane  amide) 

Stearic  acid  -   ethylenediamine  condensate   (amine/acid 

ration=l/2) . 
Stearonitrile   (Octadecanenitrile) 


CGY,    HMP. 
CGY,    HUP. 


CGY,    HMP. 

CGY,    CRT,    DAN,   DOW,    HMP,    HRT,  JOR,   RPC. 

CGY,    HMP. 

HMP. 

HMP. 

HMP. 


CGY,    CRT,   DAN,   DOW,    HMP,   RPC. 


HMP. 

HMP. 

DOW, 

H^^p 

MON 

HUP. 

DOW, 

EK, 

HMP, 

WAY. 

COM. 

COM. 

COM. 

COM. 

COM. 

ALF, 

DBC 

DUP 

MON. 

CWN, 

MOB 

UPJ 

ARC, 

ASH 

FIN 

HUM. 

CCW, 

GLY 

GAF. 

ARC, 

ASH 

CTN. 

FIN. 

COM, 

DUP 

HPC 

TNA. 

ACY, 

DOW 

HPC 

NLC. 

ACY. 

DUP. 

NLC. 

NLC. 

MON. 

UCC. 

JCC. 

BKL. 

OTC. 

TKL. 

CGY, 

HMP 

FMT. 

FMT. 

ARC, 

FIN 

HUM 

CCW, 

DA, 

GLY, 

HUM,  ICI 

ARC, 

ASH 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED    BY    MANUFACTURER.    1972--CONTINUED 


Manufacturers'    identification   codes 
(according  to   list   in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Nitrogenous  Ccmpounds — Continued 

Stearylerucamide 

Succinimide 

Tall  oil   diethylenetetramine   and   acetic  acid 

Tallow  amde,  hydrogenated 

Tallow  nitrile 

Tallow  nitrile,   hydrogenated 

Tetra functional   ketimine 

N,N,N'  ,N'-Tetrakis  (2-hydroxypropyl)ethylenediaiiiine — 

Tetrame thy Iguani dine 

Tetramethylurea 

Thioacetamide 

3,3'-Thiodipropionitrile 

Thiosemicarbazide 

Trisodiumhydroxye thy lethylenedi amine  triacetate 

*Urea  in  compounds   or  mixtures,    ino%  basis: 

*In  feed  compounds 

*In   liquid  fertilizer 

*In  solid   fertiiieer 

In  plastics 

All  other 

Urea  ammonium  nitrate   solution 

Urea  -  urethane  copolymer 

All   other  nitrogenous    compounds 


Acids  J  A(yid  Anhydrides  ^   and  Aayl  Halides 

*Acetic  acid,   synthetic,    100% 

'Acetic  anhydride,    100%: 

From   acetic   acid 

From  ethylene 

*Acrylic   acid 

*Adipic   acid 

Azelaic  acid 

Behenic  acid 

Bromoacetic  acid 

Bromobuty ri c  acid 

2 - Bromodode canoi c  acid 

a-Bromo   (mixed^    luric  stearic  acid 

1,3-Butylene   glycolbiborate  hexylene   glycol  boric 
anhydride . 

tert-Butylperoxymaleic  acid 

Butyric   acid 

Butyric  anhydride 

Castor   oil    fatty   acids,    dehydrated 

Chloroacetic  acid,   mono-   


FIN. 

ASH. 

ACY. 

ARC. 

ARC,   ASH. 

ARC,   ASH. 

CNM. 

VYN. 

ACY. 

OTC. 

EK,   RBC. 

ACY. 

ACY,   FHT. 

CGY. 

ACN,   AGY,    FTX,    GCC,   HKY,    ICI,    JDC,   MSC,    PPC,    SOH,   TER, 

TRI,    VLN,   WYC. 
ACN,   AGY,    AIP,   AKL,   CFA,    CHN,   CNC,    FCA,    FTX,    GCC,   HKY, 

HPC,    ICI,    JDC,   MSC,   CMC,    PLC,    PPC,    SHC,    SNI.    SOH, 

TER,   TRI,    VLN,   WYC 
ACN,   AGY,    AKL,   ARM,    COL,   DUP,   GCC,    HPC,    ICI,    JDC,   MSC, 

OMC,    PPC,   SHC,    SNO,    SOH,   TER,   TRI,    VLN,    WYC. 
ACN,    BOR,    DUP,    TRI. 

ACN,    AIP,   DUP,    HPC,    SHC,    SNO,   TER,    WYC. 
WYC. 
DUP. 
AAC,   ALB,    ALD,   CGY,    CHP,   COM,    CTN,   DUP,    EK,    EVN,   FIN, 

FIS,    FMP,    FMT,    GAF,    GNM,    HEX,    HUM,    IDC,    JCC,    KF, 

LIL,    MAL,    MCH,   MRK,    NFS,    NOR,    PD,    PEN,    PFZ, 

PIL,    RSA,    S,    SDW,    SM,   SNW,   TNA,    VND,    WTH,    x. 


GEL, 
UCC. 
BFG, 
AGP, 
EMR. 
ASH. 
MCH. 
GTL. 
DUP. 
DUP. 
USB. 

WTL. 
GEL, 
EKT. 


BOR,    CEL,    EKT,    FMP,    MON,    PUB,    UCC. 
EKT,    FMP. 


CEL,    DBC,   UCC. 

CEL,   DBC,    DUP,    ELP,   MON,    RH. 


NTL. 
,    DOW,    HPC. 


MISCELLANEOUS  CHEMICALS 
TABLE  2,— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--CoNT INUED 


Manufacturers'   identification  codes 
(according  to   list  in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Acids,   Acid  Anhydrides,   and  Aery  I  Hatides — Continued 

Chloroacetyl  chloride 

Citric   acid 

Crotonic  acid    (2-Butenoic  acid] 

Decanoyl   chloride 

Dimer  acid    (C-36  aiphatic  dibasic  acid] 

Dime thy Ipropionic   acid 

Di-n-propylacetic  acid  and   chloride 

Dipropylma Ionic  acid 

Dodecanedioic   acid 

*Dodecenyl succinic  anhydride 

Dodecyl succinic  anhydride 

Erucic  acid 

Ethyl   3- (Chlorofonnyl)propionate 

2-Ethylbutyric  acid   (Diethylacetic  acid) 

2-Ethylhexanoic  acid   (a-Ethylcaproic  acid) 

2-Ethylhexanoyl   chloride 

'Formic  acid,   90% 

*Fumar i c  acid 

Gluconic   acid,    tech 

G lut  ari  c    anhydr i  de 

Glycolic   acid    (Hydroxyacetic  acid) 

n-Hexadecenylsuccinic  anhydride 

n-Hexanoic  acid 

1 - Hydroxye thy 1 idene- 1,1- diphosphoni c   acid 

Isethionic  acid   (2-Hydroxyethanesulfonic  acid) 

Isoascorbic  acid 

Isobutyric  acid 

I s obuty ri c  anh ydride 

Isobutyryl   chloride 

Is o-octadecenyl succinic  anhydride 

Iso-octanoic  acid 

Itaconic  acid    (Methylenesuccinic  acid) 

2-Keto-D-gluconic   acid 

Lactic  acid 

*Lauroyl  chloride 

Levulinic  acid 

Maleic  acid 

*Maleic  anhydride 

Malic  acid 

Malonic  acid 

Mercaptoacetic  acid   (Thioglycolic   acid) 

3-Mer cap t op rop ionic  acid 

Mercaptosuccinic  acid   (Thioraalic  acid) 

Methacrylic   acid 

Methanesulfonic  acid 

Methane su If onyl    chloride 

2-Methylvaleric   acid    C2-Methylpentanoic  acid) 

Neodecanoic   acid 

Neodecanoyl    chloride 

Neoheptanoic  acid 

Neopentanoic   acid 

Nonanoic  acid   (Pelargonic  acid) 

Nonenylsuccinic  anhydride 

Octadecenyl succinic   anhydride 

Octanoyl   chloride 

Octenylsuccinic  anhydride 

Oleoyl   chloride 

Oxalic   acid 

PalmitoyI  chloride 

Peroxyacetic  acid 


DOW, 

WTC. 

MLS, 

PFZ,  WTC 

EKT. 

WTC, 

WTL. 

AZS. 

COM. 

CTN. 

CTN. 

DUP. 

ACS, 

HMY,  MON. 

HN. 

ASH. 

ABB. 

UCC. 

EKT, 

UCC. 

WTC, 

WTL. 

CEL, 

DUP,  UCC 

ACS, 

HN,  MON, 

PFZ, 

USS. 

PFZ, 

PMP. 

UCC. 

DUP, 

SNW. 

HMY. 

UCC. 

WAY. 

GAF. 

MRK, 

PFZ. 

EKT. 

EKT. 

WTC, 

WTL. 

HMY. 

UCC. 

PFZ. 

MRK. 

CLN, 

MON. 

GAF, 

HK,  ONX, 

TEK, 

UOP,  WTC,  WTL 

QKO. 

ACS, 

PEN,  PFZ 

ACS, 

HN,  KPT, 

MON, 

PTT,  RIG,  USS 

ACS, 

EK. 

KF. 

EVN, 

HAB. 

EVN. 

EVN. 

DUP, 

RH. 

EK, 

PAS. 

PAS. 

UCC. 

EN  J. 

WTC, 

WTL. 

ENJ. 

EN  J. 

EMR, 

GIV. 

HMY. 

HMY. 

HK. 

HMY. 

GAF, 

HRT,  UOP 

ACS, 

PFZ. 

GAF, 

OPC,  PD, 

UOP. 

FMB, 

UCC. 

552-743  O  -  74  -  15 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 


TABLE   2.-niSCELLANE0US   CHEMICALS    FOR   WHICH   U.S.    PRODUCTION   OR    SALES   WERE   REPORTED. 
IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Aoids,   A<yid  Anhydrides,   and  Aayl  Halicfes— Continued 

•Pivaloyl  chloride 

*Poly aery lie   aeid 

Polygalacturonic  acid 

♦Propionic  acid 

Propionic  anhydride 

Propionyl  chloride 

Sebacic  acid 

Stearoyl   chloride 

Succinic   acid 

Succinic  anhydride 

Tetrahydroxysueeinic  acid   (Dioxytartaric  acid) 

Tetrapropenylsuccinie  acid 

Thioacetic  acid 

Thiolactic  acid 

3,3'-Thiodipropionic   acid 

Trichloroacetic  acid 

Valeric  aeid 

All   other 

Salts  of  Organic  Adds 

♦Acetic  acid  salts: 

Aluminum  acetate 

Anraionium  acetate 

Barium  acetate 

Cadmium  acetate 

Calcium  acetate 

Chromium  acetate 

Cobalt   acetate 

*Copper  acetate 

Lead  acetate 

Lead  sub acetate 

Lead  tetraacetate 

Magnesium  acetate 

Manganese  acetate 

Mercuric  acetate 

Nickel   acetate 

♦Potassium  acetate 

Silver  acetate 

Sodium  acfttate 

Sodium  di acetate 

Strontium  acetate 

♦Zinc  acetate 

♦Zirconium  acetate 

Other  acetic  acid  salts 

Acrylic  acid,    sodium  salt 

Adipic  acid,   ammonium  salt 

Allylsulfonic  acid,   sodium  salt 

Chloroacetic  acid,   sodium  salt 

Citric  acid  salts: 

Ammonium  citrate 

Calcium  citrate 

Disodium  citrate-- 

Ferric  ammonium  citrate 

Ferric  citrate 

Potassium  citrate 

Sodium  citrate 

Other  citric  acid  salts 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


AZT,  WTC, 

WTL. 

AAE,  DA, 

RH. 

SKG. 

CEL,  COM, 

EKT, 

UCC. 

EKT,  UCC. 

EK,  UOP. 

RH,  WTH. 

EK,  UOP. 

ACS. 

ACS,  ORO 

ACY. 

TX. 

EVN. 

EVN. 

CCW,  EVN 

DOW. 

UCC. 

ALD,  CTN 

EK, 

EN  J, 

ACY, 

UCC. 

ACS, 

BKC, 

HAL. 

ACS, 

BKC, 

MAL. 

MAL, 

SHP. 

ACS, 

MAL. 

VAL. 

HSH, 

SHP. 

ACS, 

BKC, 

SHP, 

UCC. 

BKC, 

MAL. 

ACS, 

BKC, 

MAL. 

ARA. 

ACS, 

BKC. 

HSH, 

NES, 

SHP. 

HAL. 

BKC, 

HSH, 

SHP. 

ACS, 

BKC, 

MAL, 

SFI, 

UCC, 

WSN. 

MAL. 

ACS, 

BKC, 

DAN, 

EKT, 

MAL, 

UCC,  WSN 

UCC. 

BKC. 

ACS, 

BKC, 

HSH, 

MAL, 

SHP, 

UCC. 

CHP, 

HSH, 

NTL, 

TZC. 

CCW, 

LIL, 

MHI. 

AAE. 

FIS. 

SAL, 

X. 

DOW 

MAL 

PFZ 

PFZ 

WSN 

PFZ 

MAL 

MLS 

PFZ 

MLS 

PFZ 

SNW 

CHP 

EK, 

HAL. 

MISCELLANEOUS  CHEMICALS 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 
Salts  of  Ovganio  ;l^£^--Continued 

Dibutyltin  bisCisooctyl   thioglycolate) 

*2-Ethylhexanoic  acid   (a-Ethylcaproic  acid)   salts: 

Aluminuin  2-ethylhexanoate 

Barium  2-ethylhexanoate 

Cadmium  2-ethylhexanoate 

*CaIcium  2-ethylhexanoate 

*Cobalt   2-ethylhexanoate 

Copper  2-ethylhexanoate 

Iron  2-ethyIhexanoate 

*Lead  2-ethylhexanoate 

*Manganese   2-ethylhexanoate 

Nickel   2-ethylhexanoate 

Rare  earths   2-ethylhexanoate 

*Zinc  2-ethylhexanoate 

Zirconium  2-ethylhexanoate 

Other 

Formic  acid  salts: 

Aluminum  formate 

Ammonium  formate 

Calcium  formate 

Chromic  formate 

Lead  formate 

Sodium  formate,  refined 

*Sodium  formate,  tech 

Thallous  formate 

Glucoheptonic  acid  salts: 

Sodium  glucoheptonate 

Gluconic  acids  salts: 

Ammonium  gluconate 

•Sodium  gluconate 

Glycolic  acid,  sodium  salt 

9H-Hexadecaf luorononanoic  acid,  ammonium  salt 

Humic  acids,  sodium  salt 

Isoascorbic  acid,  sodium  salt 

*Lactic  acid  salts: 

Ammonium  lactate 

Calcium  lactate 

Sodium  lactate 

Other 

Laurie  acid  salts : 

Barium  cadmium  laurate 

Dibutyltin  di laurate 

Zinc  laurate 

Linoleic  acid  salts: 

Calcium  linoleate 

Cobalt  linoleate 

Copper  linoleate 

Lead  manganese  linoleate 

Manganese  linoleate 

Maleic  acid  salts: 

Dibutyltin  maleate 

Lead  Ctribasic)  maleate 

Other  maleic  acid  salts 

*Mercaptoacetic  acid  (Thioglycolic  acid)  salts: 

Ammonium  mercaptoacetate 

Antimony  mercaptoacetate 

Calcium  mercaptoacetate 

Dibutyltin  bis  iso-octyl  mercaptoacetate 

Dibutyltin  mercaptoacetate 

Potassium  mercaptoacetate 

Sodium  mercaptoacetate 


PFZ, 
CCA, 

WTC. 
PFZ. 

CCA, 

PFZ. 

CCA, 

CCC, 

FER 

HN, 

MCI 

PFZ 

SW, 

TRO 

CCA, 

ccc. 

FER 

HN, 

MCI 

SW, 

TRO, 

WTC 

CCA. 

CCA, 

HN. 

CCA, 

CCC, 

FER 

HN, 

MCI 

OTL 

SW, 

WTC 

CCA, 

CCC, 

HN, 

MCI, 

SW, 

WTC. 

MCI, 

SW. 

CCA. 

CCA, 

FER, 

HN, 

MCI, 

SW, 

WTC. 

CCA, 

FER, 

HN, 

TRO. 

CCA. 

WTC, 

x. 

WSN. 

ACS, 

RSA. 

COM. 

GAF. 

NTL. 

ACS, 

BKC. 

COM, 

CEL, 

HPC 

PFZ. 
PFZ, 
PMP, 
DUP. 
NLC. 
MRK. 

TCC. 
SHF. 
REH, 
CCA, 

CCA. 
CCW, 

SNW. 

CCA. 
SHP. 
SHP. 
SHP. 
SHP. 


EVN. 
CCA. 
EVN. 

X. 

CCA. 
EVN. 
EVN. 


PMP,  SFI. 
SAL. 


PFN. 


CCW,  PFN,  REH,  SNIV.  WTC. 


HAB.  TNI. 


SYNTHETIC  ORGANIC  CHEMICALS.  W72 

TABLE  2,--MlSCELLANE0US  CHEMICALS  FOR  WHICH  U.S.  PRODUCTION  OR  SALES  WERE  REPORTED, 
IDENTIFIED  BY  MANUFACTURER,  1972--CoNTINUED 


Manufacturers'    identification   codes 
(according  to  list   in  table   3) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC--Ccintinued 
Salts  of  Organic  Aaids — Continued 

Mercaptopropionic  acid,   dibutyltin  salt 

Methacrylic  acid,   sodium  salt 

Neodecanoic  acid  salts: 

Cadmium  neodecanoate 

Calcium  neodecanoate 

Cobalt  manganese  neodecanoate 

Cobalt  neodecanoate 

Lead  cobalt  neodecanoate 

Lead  neodecanoate 

Lithium  neodecanoate 

Manganese  neodecanoate 

Stannous  neodecanoate 

Vanadium  neodecanoate 

Zinc  calcium  cobalt  neodecanoate 

Zinc  neodecanoate 

Zirconium  neodecanoate 

Octanoic  acid   (Caprylic  acid)    salts: 

Aluminum  octanoate 

Barium  cadmium  octanoate 

Stannous   octanoate 

Zinc  octanoate 

Other 

*01eic  acid  salts : 

Aluminum  oleate 

Ammonium  oleate 

Chromium  oleate 

Copper  oleate 

Lead  oleate 

Stannous  oleate 

Other  oleic  acid  salts 

Oxalic  acid  salts : 

Ammonium  oxalate 

Ferric  ammonium  oxalate 

Ferric  oxalate 

Ferrous  oxalate 

Potassium  oxalate 

Sodium  oxalate 

Palmitic  acid  salts: 

Aluminum  pa Imitate 

Zinc  palmitate 

other 

Phosphorodithioic  acid  salts  (Dithiophosphates) : 

Potassium  dihexyl  phosphorQdithioate 

Sodium  di-sec-butyl  diethyl  phosphorodithioate 

Sodium  di-sec-butyl  phosphorodithioate 

Sodium  diethyl  phosphorodithioate 

Sodium  dihexyl  phosphorodithioate 

Sodium  diisopropyl  phosphorodithioate 

Polyacrylic  acid  salts: 

Ammonium  poly aery late 

Sodium  ammonium  polyacrylate  and  copolyers 

Sodium  polyacrylate 

Polymeth aery lie  acid,  sodium  salt 

Propionic  acid  salts: 

*Calcium  propionate 

* Sodium  propionate 

Ricinoleic  acid  silts: 

Calcium  ricinoleate 

Lithium  ricinoleate 

Sodium  ethyl  oxalacetate 

Sodium  polypectate 


CCA. 
AAE. 

CCA. 

CCA,  MCI. 

MCI. 

MCI. 

MCI. 

CCA,  MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

CCA,  MCI. 

MCI. 

DA. 
CCA 

CCW,  x. 
BKC. 

DA. 

KTC. 

ARS. 

SHP. 

SHP,  WTC. 

NOC,  SHP. 

CCW,  X. 

CHP,  TRO,  WTC. 

ACS,  PFZ. 

PFZ. 

PFZ. 

BKL. 

BKC,  PFZ. 

BKC. 

DA,  WTC. 
ACY,  DA,  WTC. 
DA. 

ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 

BFG. 

BFG. 

ALC,  BFG,  DA,  JOR,  RH. 

GRD. 

HFT,  PFZ,  UCC,  WSN. 
HFT,  PFZ,  UCC,  WSN. 

NIL. 
NTL. 
FMP. 
SKG. 


MISCELLANEOUS  CHEMICALS 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'    identification  codes 
(according  to   list   in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

Salts   of  Organic  Acids  —  Continued 

Sodium  soribitol  borate 

♦Stearic   acid  salts: 
'Aluminum  stearates: 

* Aluminum  distearate 

♦Aluminum  monostearate 

♦Aluminum  tristearate 

Ammonium  stearate 

♦Barium  stearate 

Cadmium  stearate 

♦Calcium  stearate 

Copper  stearate 

Ferrous   stearate 

Lead  stearate 

Lead  stearate,    dibasic 

♦Lithium  stearate 

♦Magnesium  stearate 

Nickel   stearate 

Silver  stearate 

♦Zinc  stearate 

All  other 

Succinic  acid,   sodium  salt 

Sulfosuccinic   acid,   trisodium  salt 

Tartaric   acid  salts: 

Antimony  potassium  tartrate 

Potassium  sodium  tartrate 

Sodi urn  bit art rate 

Valeric   acid,    ammonium  salt 

Xanthic   acid   salts: 

Potassium  amylxanthate 

Potassium  ethylxanthate 

Potassium  hexylxanthate 

Potassium  isopropylxanthate 

Potassium  pentylxanthate 

Sodium  n-butylxanthate 

Sodium  sec-butylxanthate 

Sodium  ethylxanthate 

Sodium  isobutylxanthate 

Sodium  isopropylxanthate 

All  other  salts   of  organic  acids 


Aldehydes  and  Ketones 

♦Acet aldehyde 

♦Acetone : 

♦From  cumene 

From  isopropyl  alcohol 

Other 

Acetone,   crude 

Acrolein   (Acrylaldehyde) 

Aldol    (Acetaldol) 

♦2-Butanone    (Methyl   ethyl  ketone) 

♦Butyraldehyde 

Chloral    (Trichloroacetaldehyde) 

5-Chloro-2-pentanone 

l-Chloro-l-penten-3-one    (6-Chlorovinyl   ethyl   ketone) - 

Chloro-2-propanone    (Chloroacetone) 

Crotonaldehvde 


DA, 

DA, 
NOC 
ACY 
NOC 
NOC 


,   DA,  JTC,   MAL,    NOC,   PEN,   SYP,    WTC. 

JTC,  HAL,    NOC,   SYP,    WTC. 

JTC,  MAL,    NOC,   PEN,    SYP. 

NOC,  WTC. 

NOC,  PEN,   SYP. 
,    SYP,    WTC. 

,    DA,  HN,   JTC,   MAL,   NOC,    PEN,    SYP,    WTC. 

.   WTC. 
NOC,    WTC. 

NOC,    PEN,   SYP,   WTC. 
,    DA,   JTC,   MAL,    NOC,    PEN,    SYP,    WTC. 


DA,    HN,   JTC,   MAL,   NOC,    PEN,    SYP,    IVTC. 
NOC,    SYP,    VAL. 


ACY 

WTC 

PEN 

ACY 

DA, 

MAL. 

STP. 

PFZ. 
PFZ. 
PFZ. 
RSA. 


DOW. 
DOW. 
DOW. 
DOW. 
ACY. 

KCC,   USR. 
DOW. 
DOW. 
DOW. 
DOW. 

ACY,   AID,   CCA,   CHP,   CRN,   CTN,    DA,    DUP,    EK,    EVN,   JCC, 
KCH,   MCI,    NTL,    PFN,   RSA,    SFA,    SYP,    UCC,   x. 


CEL,    DlIP,    EKT,   EKX,   PUB,    SHC,   UCC. 

ACP,    CLK,   DOW,    GP,   MON,    SHC,    SKO,    SOC,    UCC,    USS. 

EKT,    EN J,    SHC,   UCC. 

CEL,   DIX,    HPC. 

OCC. 

SHC,    UCC. 

UCC. 

ATR,    CEL,    DIX,    ENJ,    SHC,   UCC. 

CEL,    EKX,   UCC. 

DA,   MTO. 

SDW. 

ABB. 

EK,   MRK. 

CEL,    EKT.   UCC. 


SYNTHETIC  ORGANIC  CHEf^ICALS.  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'    identification  codes 
(according  to  list  in  table   3] 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

Aldehydes  and  Ketones — Continued 

l,3-Dihydroxy-2-propanone   (Dihydroxyacetone) 

Diisopropyl  ketone   (2,4-Diinethyl-3-pentanone] 

2-Ethylbutyraldehyde 

Ethyl   crotonaldehyde 

2-Ethylhexanal    (a-Ethylcaproaldehyde) 

•Formaldehyde   (37%  by  weight) 

Glutaraldehyde 

Glyoxal 

2-Heptanone    (Methyl  amyl  ketone) 

3-Heptanone   (Ethyl  butyl  ketone) 

Hexaldehyde 

2,5-Hexanedione    (Acetonylacetone) 

*4-Hydroxy-4-methyl-2-pentanone   (Diacetone  alcohol) 

Isobutyraldehyde 

Isopentaldehyde,   mixed  isomers 

Isovalerone    (Diisobutyl  ketone) 

Lac tide    (3,6-Dimethyl-2,5,p-dioxanedione) 

4-Methoxy-4-methyl-2-pentanone 

2-Methylbutyraldehyde 

5-Methyl-2-hexanone    (Methyl   isoamyl  ketone) 

Methylhexenone 

*4-Methyl-2-pentanone    (Methyl   isobutyl  ketone) 

Methylpentenal 

4-Methyl-3-penten-2-one    (Mesityl  oxide) 

2-Methylvaleraldehyde    (2-Methylpentaldehyde) 

3-Octanone    (Ethyl   amyl  ketone) 

Paraformaldehyde 

Paraldehyde    (Paracet aldehyde) 

2,4-Pentanedione    (Acetylacetone) 

2-Pentanone    (Methyl  propyl  ketone) 

3-Pentanone    (Diethyl  ketone) 

Propionaldehyde 

Tetrahydropseudoionone 

2,6,8-Trimethyl-4-nonanone   (Isobutyl  heptyl  ketone)-- 

Valeraldehyde 

All  other 

Alcohols,  Monohydria,    Unsubstituted 

•Alcohols  C     or   lower,   unmixed: 

Allyl   alcohol 

Amyl   alcohols : 

2-Methyl-l-butanol 

2-Methyl-2-butanol    (tert-Amyl   alcohol) 

1-Pentanol 

Butyl   alcohols: 
Primary : 

*Iso   (Isopropylcarbinol) 

•Normal    (n- Propylcarbinol) 

Secondary   (Methylethylcarbinol) 

Tertiary   (Trimethylcarbinol) 

2,6-Dimethyl-4-heptanol    (Diisobutylcarbinol) 

•Ethyl   alcohol,   synthetic 

2-Ethyl-l-butanol 

*2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

4-Ethyl-l-octyn-3-ol 


BAX. 

EKX. 

UCC. 

UCC. 

EKX,   UCC. 

ACN,    BOR,    CBD,   CEL,   COM,    DUP,   GAP,    GOC,    GP,    HKD,   HN, 

HPC,  MON,  RCI,  RH,  UCC,  WCL. 
UCC. 
UCC. 
UCC. 
UCC. 
UCC. 
ARS. 

CEL,  SHC,  UCC. 
EKX,  UCC. 
UCC. 
UCC. 
CLN. 
SHC. 
UCC. 

EKT,   UCC. 
UCC. 

EKT,    ENJ,    SHC,    UCC. 
UCC. 

SHC,   UCC. 
UCC. 
SHC. 

CEL,   HN. 
UCC. 
UCC. 
UCC. 

HEX,   CRT. 
EKX,   UCC. 
CEL. 
UCC. 
UCC. 
ALD,   ARC,    EK,   CRT,   UCC. 


CPS,  UCC. 
ENJ,  SHC. 
UCC. 


CEL,   DBC,    EKX,   OXC,   SHC,   UCC. 

CEL,    CO,    DBC,    EKX,   OXC,   SHC,   TNA,    UCC. 

CEL,    ENJ,   SHC. 

SHC,    X. 

UCC. 

EKX,    ENJ,    GP,    HPC,    PUB,    SHC,   UCC,    USl. 

UCC. 

CEL,   DBC,    EKX,    OXC,   SHC,   UCC. 

EKX. 

AIP. 


MISCELLANEOUS  CHEMICALS 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972~C0NTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Alcohols,   Monohydpia,    Unsuhstituted — Continued 

*Alcohols   C     or  lower,   unmixed--Continued 

Heptyl  alcohol--- 

*Hexyl  alcohol 

Hexynol 

Isononyl  alcohol 

*l50-octyl  alcohols 

* I sop ropy 1  alcohol 

*Meth anol ,  synthet i c 

Methyl  «"yl  alcohol 

3-Me'thyl-l-butanol 

2-Methyl-3-butyn-2-ol 

2-Methyl-l-pentanol 

4-Methyl-2-pentanol    (l-Methylisobutylcarbinol) 

3-Methyl-l-pentyn-3-ol    (Methylparafynol) 

*1 -Oct  anol 

*2-0ctanol    (sec-Capryl   alcohol) 

3-Pentanol 

'Propyl  alcohol  (Propanol) 

2-Propyn-l-ol 

1-Tetradecanol  (Myristyl  alcohol) 

All  other 

'Alcohols,   C,5   or  higher,   unmixed: 

1-Decanol 

Dodecyl   alcohol    (Lauryl   alcohol)    (95%) 

*l-Hexadecanol    (Cetyl   alcohol) (95%) 

Hexadecyl   alcohols,    other 

*Isodecyl   alcohol 

*I-Octadecanol    (Stearyl   alcohol)    (95%) 

cis-9-Octadecen-l-ol    (Oleyl   alcohol) 

1-Tridecanol 

2,6,8-Trimethyl-4-nonanol 

All   other 

'Mixtures  of  alcohols: 
*C,  and  lower  only: 

Amyl  alcohols 

Other 

'Cjj   and  higher  only 

'Cj   to  C,2   and  others 

Polyhydria  Alcohols  and  Their  Esters  and  Ethers 

*Pclyhydric   alcohols: 

1,2 (and   l,3)-Butanediol 

1,4-Butanediol 

2-Butene-l,4-diol 

2-Butyne-l,4-diol 

3-Chloro-l,2-propanediol    (Glycerol-a-chlorohydrin) 

1,10-Decanediol 

2,5-Dimethyl-2,5-hexanediol 

2,5-Dimethyl-3-hexyne-2,5-diol 

2,2-Dimethyl-l,3-propanediol    (Neopentyl   glycol) 

'Ethylene  glycol 

2-Ethyl-l,3-hexandiol 

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol   (Tri- 
methylol  propane) . 
'Glycerol,   synthetic- 


ENJ,  TID,  USS. 
EN J,  SHC,  UCC. 
AIP,    BOR,   CEL,    DIJP,   GP,    HN,    HPC,   HON,   RH,   UCC. 


CO,    EKX,    ENJ,   TNA,   UCC. 

AIP. 

ENJ. 

AIP 

ATR 

ACN 

UCC 

UCC. 

AIP. 

UCC. 

SHC. 

AIP. 

CO,    PG,    WTH. 

RH. 

EK. 

CEL,    EKX,    UCC. 

GAP. 

CO,    PG. 

ALD,    EKX,    GYR,    LIL. 


CO, 

PG. 

CO, 

PG. 

ASH 

CO, 

GIV, 

PG. 

ENJ 

AIP 

ENJ 

TID 

,  UCC,  USS. 

ASH 

CO, 

PG. 

ASH 

DUP 

ENJ, 

UCC 

UCC. 

UCC. 

ENJ. 

CEL 

EKX 

PUB 

,  UCC. 

ASH 

CO, 

ENJ, 

PG,  SHC,  TNA,  UCC. 

CO, 

EKX, 

PG, 

SHC,  TNA. 

CEL. 
GAP. 
GAP. 
GAP. 
EVN, 
FIS. 
AIP. 
AIP. 
EKX. 
CAU,    CEL,    DOW,   DUP,    EKX,    GAP,   JCC.   MAT,    NWP,   OMC,    PPG, 

SHC,   UCC,   IfYN. 
UCC. 
CEL. 

DOW,    FMP,    ICI,    SHC. 


SYNTHETIC  ORGANIC  CHE^IICALS>  1972 
TABLE  2, --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

Polyhydria  Alcohols  and  their  Esters 
and  Ethers — Continued 

*Polyhydric   alcohols--Continued 

1 ,6-Hexanediol 

2- (Hydroxymethyl)-2-methyl-l ,3-propanediol    (Tri- 
methylolethane) . 

Mannitol 

3-Mercapto-l ,2-propanediol    (Thioglycerol) 

*2-Methyl-2,4-pentaiiediol    (Hexylene   glycol) 

2-Methyl-2-propyl-l ,3-propanediol 

*Pentaerythritol 

1,5- Pent anediol 

♦Propylene  glycol    Cl,2-Propanediol) 

♦Sorbitol 

2,2,4-Triiiiethyl-l,3-pentanediol 

All   other 

♦Polyhydric   alcohol   esters: 

1,3- But anediol  dimethacrylate 

2, (2-Butoxyethoxy)ethyl   acetate 

2-Butoxyethyl   acetate 

Diethylene   glycol,   borated 

Diethylene  glycol   chlorofomate 

2-Diisopropylaiiiinoethyl   me  th  aery  late 

2- (2-Ethoxyethoxy)ethyl  acetate 

2-Ethoxyethyl   acetate 

♦Ethylene  glycol  diacetate — 

Ethylene   glycol  dimercaptoacetate 

Ethylene   glycol   dimethacrylate 

Ethylene  glycol  hydroxyacetate 

2-Ethyl-2- (hydroxymethyl)-i,3-propanediol   tr- 
methacrylate. 

Glyceryl  diacetate    (Diacetin) 

Glyceryl   monoacetate    (Monoacetin) 

Glyceryl   triacetate    (Triacetin} 

Glyceryl   trioleate 

Glycol    adipate 

Hexylene   glycol  diacetate 

Lanolin   acetate 

2-Methoxyethyl   acetate 

2-Methoxyethyl   carbonate 

Methoxytriethyleneglycol    acetate 

Pen t aery thritol   caprylatST 

Pentaerythritol  pelargonate 

Pent aery thritol    stearate 

Pentaerythritol   tetrakis (3-mercaptopropionate) 

Polyethylene   glycol  dimethacrylate 

Sorbitol  polyoxypropylene   ether 

Sucrose   oct a- acetate 

Tetraethylene   glycol   diacrylate 

Tetraethylene   glycol   dimethacrylate 

Triethylene   glycol   diacetate 

Triethylene   glycol  diacrylate 

Triethylene   glycol   dimethacrylate 

2,2,4-Trimethyl-l,3-pentanediol  monoisobutyrate 

Trimethylolpropane   tri aery late 

All  other 

♦Polyhydric  alcohol  ethers: 

Allyloxypolyethylene  glycol 

Bis (2-butoxyethyl)  ether  (Diethylene  glycol  di-n- 

butyl  ether) . 
Bis(2-ethoxyethyl)  ether  (Diethylene  glycol  diethyl 
ether) . 


CEL 
COM 

ICI 
EVN 
CEL 
BKL 
CEL 
UCC 
CEL 
BRD 
EKX 
EKX 

SAP 
EKT 
SAR 
GLY 
CTN 
DUP 
EKT 
DOW 
CPS 
EVN 
SAR 
CCA 
SAR 

ARC 
ARC 
ARC 
GRO 

X. 

UCC 
CRN 
UCC 
VAL 
RBC 
PVO 
PVO 
GLY 
EVN 
SAR 
JCC 
HFT 
AAE 
SAR 
UCC 
AAE 
SAR 
EKX 
AAE 
CCW 

UCC 
UCC 


SHC,   UCC. 

COM,    HN,    HPC,    PNA,    RCI. 


DOW,   JCC,   OCC,   OMC,   UCC,    IVYN. 
ICI,   MRK,    PFZ. 


GLY,    ICI,    PEN,    PHR,    PIC,    RSA. 


UCC. 
UCC. 
JCC. 
PPG. 


UCC. 
UCC. 
EKT,   UCC. 


HAL. 
HAL. 
EKT,   UCC. 


EK,    EKX,    EVN,    PEN,    SAR   SHC,    UCC. 


MISCELLAHEHUS  CHEMICALS 

TABLE   2,--MlSCELLANE0US    CHEMICALS    FOR    WHICH    U.S.     PRODUCTION    OR    SALES    WERE    REPORTED, 
IDENTIFIED   BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'    identification  codes 
(according  to   list   in   table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

Polyhydrio  Alcohols  and  Their  Esters 
and  Ethers — Continued 

*Polyhydric  alcohol   ethers--Continued 

Bis (hydroxye thy 1) ether  butynediol 

Bis[2- C2-methoxyethoxy)ethyl]    ether   (Tetraethylene 

glycol   dimethyl   ether) . 
BisC2-methoxyethyl)    ether    (Diethylene   glycol   dimethyl 
ether) . 

Butanol  polyoxypropylene   ether 

*2-Butoxyethanol    (Ethylene   glycol   monobutyl  ether) 

*2- (2-Butoxyethoxy)ethanol    (Diethylene  glycol  monoiso- 
butyl   ether) . 

2-  [2-  (2-Butoxyethoxy)ethoxy]ethaiiol    (Triethylene 
glycol   monobutyl   ether). 

l-Butoxyethoxy-2-propanol 

'Diethylene  glycol 

Diethylene   glycol   monobutyl   ether 

Diethoxytetraglycol 

Dimethoxyethane    (Ethylene   glycol   dimethyl   ether) 

*Dipropylene   glycol 

Di-tributyle there thy lene   glycol 

Di-tri-isobutyl    ether 

*2-Ethoxyethanol    (Ethylene    glycol   monoethyl   ether) 

*2- (2-Ethoxyethoxy)ethanol    (Diethylene  glycol  mono- 
ether)  . 
*2-  [2-  (Ethoxyethoxy)ethoxy]ethaiiol    (Triethylene 
glycol   monoethyl   ether) . 

Glycerol   tri (polyoxypropylene)   ether 

2- (Hexyloxy)ethanol 

2- [2- (Hexyloxy)ethoxy]ethanol 

2-Isobutoxyethanol 

2- (2-Isobutoxyethoxy)ethanol    (Diethylene  glycol 

monoisobutyl   ether) . 
l-lsobutoxy-2-propanoi    (Propylene    glycol    isobutyl 
ether) . 
*2-Methoxyethanol    (Ethylene   glycol   monomethyl   ether) — 
*2- (2-Methoxyethoxy)ethanol    (Diethylene   glycol  mono- 
methyl   ether) . 
*2- [2- (2-Methoxyethoxy)ethoxy]ethanol    (Triethylene 
glycol   monomethyl    ether) . 
2- (2-Methoxyethoxy)ethyl-2-iiiethoxyethyl   ether    (Tri- 
ethylene   glycol   dimethyl   ether) . 

Methoxypolyethylene   glycol 

l-Methoxy-2-propanoI 

3-  (3-Methoxypropoxy)propanol 

3- [3- (3-Methoxypropoxy)propoxy)pr»p»nel 

Polybutylene   glycol 

Polyethoxyethyl    glycerol 

Po lye thoxye thy  I sorbitol 

Polyethoxylated-1 ,4-hutanediol 

'Polyethylene  glycol 

Polyethylene  glycol,   unrefined 

Polypropoxy  ethers: 

Glycerol   tri (polyoxypropylene)    ether 

Other 

'Polypropylene  glycol 

Polytetramethylene  ether  glycol 

Sorbitol,  ethoxylated 


GAP. 
ASL. 


JCC. 

DOW,  EKX,  one,  SHC,  UCC. 

DOW,  EKX,  JCC,  OMC,  SHC,  UCC. 


DOW,  o^c, 

UCC 

UCC. 

CAU,    CEL, 

DOW 

WYN. 

OMC. 

UCC. 

ASL,    UCC, 

IVYN 

EKX,  JCC,  HAT,  NWP,  PPG,  SHC,  UCC, 


CEL,  DOW,  JCC,  OCC,  OMC,  UCC. 
EKX. 


DOW,  EKX,  JCC,  OMC,  SHC,  UCC. 
DOW,  EKX,  JCC,  OMC,  SHC,  UCC. 


DOW, 

one. 

UCC 

JCC, 

UCC, 

WYN 

UCC. 

UCC. 

EKX, 

UCC. 

EKX. 

DOW,  EKX,  JCC,  OMC,  PPG,  SHC,  UCC. 
DOH,  EKX,  JCC,  OMC,  PPG,  SHC,  UCC. 

DOW,  CMC,  UCC. 

ASL. 

.JCC,  UCC. 

DOW,  UCC. 

DOW,  UCC. 

DOW. 

NLC. 

GLY. 

GLY. 

TCH. 

DA,  DOW,  DUP,  GAF,  HOG,  JCC,  MAT,  NLC,  OMC,  TCH,  UCC, 

WYN. 
WYN. 

JCC,  UCC,  IVYN. 

DA,  JCC,  ICI,  NWP,  UCC,  VAL,  WYN. 

DOW,  JCC,  HDG,  NLC,  OMC,  UCC,  W\'N. 

DUP,  QKO. 

ICI. 


SYNTHETIC  ORGANIC  CHEf^ICALS..  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED  BY   MANUFACTURER,    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Polyhydrio  Alcohols  and  their  Esters 
and  Ethers — Continued 

*Polyhydric  alcohol  ethers--Continued 

*Tetraethylene  glvxol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thiodiethanol    (Thiodiglycol) 

*Triethylene   glycol 

*Tri propylene  glycol 

All  other 

Esters  of  Monohydrio  Alcohols 

Allyl  raethacrylate 

Amyl   acetates,   90%: 

Isopentyl   acetate    (Isoamyl   acetate^ 

n-Pentyl   acetate 

Ainyl-2-ethylhexyl  hydrogen  phosphate 

Bis (2-chloroethyl) (2-chloroethyl)  phosphonate 

Butyl   acetates : 

♦  ISO 

•Normal 

Secondary 

•Butyl   aery late 

Butyl  butyryl   lactate 

Butyl   chloroacetate 

n- Butyl   chloroformate 

sec- Butyl  chloroformate 7 

Butyl   formate 

Butyl    lactate 

Butyl   maleate,   mono-   

Butyl  methacrylate 

tert- Butyl  peroxy acetate 

tert- Butyl  peroxy- 2 -ethylhexanoate 

tert- Butyl  peroxyisobutyrate 

tert- Butyl  peroxy isopropyl carbonate 

*tert- Butyl  peroxypivalate 

Cetyl   lactate 

Di allyl  maleate 

Di (sec-butyl)    chloroformate 

Dibutyl   fumarate 

•Dibutyl  maleate 

Di (sec-butyl)   peroxydi carbonate 

Diethyl   sec-butylethylmalonate 

Diethyl  butylmalonate 

Diethyl   sec-butylmalonate 

Diethyl   carbonate   (Ethyl   carbonate) 

Diethyl  diallylmalonate 

Diethyl  diethylmalonate    (Diethyl  malonic  ester) 

Diethyl   dip ropy Ima Ion ate 

Diethyl    (ethoxymethylene)malonate 

Diethyl  ethylmalonate   (Ethyl  malonic  ester) 

Diethyl   ethyl (l-methylbutyl)malonate 

Di  (2-ethylhexyl)    chloroformate 

Di (2-ethyl-l-hexyl)    fumarate 

Di (2-ethyl-l-hexyl)   maleate 

Di  (2-ethyl-l-hexyl)   peroxydi carbonate 

Diethyl   maleate 

Diethyl  malonate    (Malonic  ester) 

Diethyl    (1-methylbutyl) malonate 

Diethyl  oxalate    (Ethyl   oxalate) 

Diisobutyl  maleate 


DOW,  EKX,  JCC,  CMC,   UCC. 

KF. 

HAB,  UCC. 

CAU,  CEL,  DOW,  EKX,  JCC,   MAT,    PPG,    SHC,   UCC. 

DOW,  HDG,  CMC,  UCC. 

ALD,  DOW,  EKX,  GAP,   JCC,    PFN,    SHC,   UCC,    x. 


PFW 
SM. 
GAF 


EKX 
CEL 
EKT 
CEL 
RT. 
MON 
CTN 
CTN 
CPS 
COM 
TCH 

AZT 
AZT 
AZT 
PPG 
AZT 
VND 
FHP 
WTL 
MON 
AIP 
IVTL 
ABB 
BPC 
ABB 
CTN 
CTN 
LIL 
CTN 


WTL 
RUB 
RUB 
IVTL 
ACY 
ABB 
ABB 
FHP 
RUB 


EN J,  UCC. 

EKT,  PUB,    SHC,   UCC. 

EN J,  SHC. 

DBC,  RH,   UCC. 


USS. 


IVTL. 

WTC,    WTL. 
WTC,   WTL. 
IVTL. 
WTC,   IVTL. 


PFZ,    RCI,   USS. 
MON,    RCI,    RUB,   USS. 


UCC. 

KF,    LIL. 
LIL. 


MISCELLANEOUS  CHEHICALS 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER.    1972— CONTINUED 


miscellaneous  chemicals,    ACYCLIC--Continued 

Esters  of  Monohydrio  Alcohols — Continued 

Diisodecyl  maleate 

Di-iso-nonyl  maleate 

Diisopropyl  peroxydi carbonate   (Isopropyl  percarbonate)- 

Dilauryl   maleate 

*Dilauryl   3,3'-thiodipropionate 

Dimethyl   carbonate 

2,5-Dimethylhexane-2,5-diperoctoate 

Dimethyl  maleate 

Dimethyl  malonate 

Dimyristyl   3,3'-thiodipropionate 

*Dioctyl  maleate 

Di-n-propyl  peroxydi carbonate 

*Distearyl   3,3'-thiodipropionate 

Dithiobis(stearyl  propionate) 

Ditridecyl  maleate 

Di(tridecyl)    3,3'-thiodipropionate 

2-Ethoxyethyl   acetate 

*Ethyl  acetate 

Ethyl   acetoacetate 

*Ethyl   aery late 

Ethyl- 2-bromopropionate 

Ethyl   chloroacetate 

Ethyl   chloro formate 

Ethyl   chlorothiolformate 

Ethylene  carbonate 

2-Ethyl-l-hexyl   acetate 

*2-Ethyl-l-hexyl   aery late 

2-Ethyl-l-hexyl  methacrylate 

Ethyl   silicate    (Tetraethoxysilane) 

Ethyl   sulfate   (Diethyl  sulfate) 

Ethyl   thioglycolate 

Fatty  acid  esters,  not  included  with  plasticizers  or 
surface- active  agents: 

Butyl  palmitate 

tert-Butylperoxy  neodecanoate -. 

Dimethyl  brassylate 

Ethyl   stearate 

2-Ethylhexyl  palmitate 

Hexadecyl  stearate 

Isopropyl    linoleate 

Methyl  esters  of  coconut   oil 

Methyl   esters  of  cottonseed  oil 

Methyl   esters   of  tallow 

Methyl   12-hydroxystearate 

Methyl  myristate 

Methyl   stearate 

Myristyl  myristate 

All  other 

Glycidyl  aery late 

Glycidyl  methacrylate 

Hexyl  acetate 

Isobutyl  acetate  5  isobutyl  isobutyrate,  mixture 

Isobutyl  aery late 


Manufacturers'  identification  codes 
(according  to  list  in  table  3) 


RUB. 

RUB. 

PPG. 

EFH. 

ACY,    CCW 

E\fN,   HAB. 

CTN. 

WTC. 

AAC,   ABC 

KF. 

CCW,    EVN 

MON,   RCI 

USS. 

wtl. 

ACY,    CCW, 

EVN,   HAB. 

EVN. 

RUB. 

ACY,    EVN 

EN  J. 

CEL,    EKT, 

EKX,   ENJ,   MON,   PUB,    UCC 

EKT,   UCC. 

CEL,   DBC, 

RH,    SNW,   UCC. 

BAX. 

DOW.    KF, 

MON. 

CTN,    FMP, 

OTC. 

SFA. 

JCC. 

EKT,   UCC. 

CEL,   DBC. 

UCC. 

X. 

SFS,    UCC. 

UCC. 

EVN. 

AAE,    CBY. 

WTC. 

EMR. 

ARS. 

VND. 

ICI. 

VND. 

PG. 

BFR. 

CHL,    HUM, 

PG. 

HUM,   NTL. 

HUM,    PG. 

DA. 

VND. 

CRN,    ROB, 

VND. 

AAE. 

CPS,    ENJ. 

EKX. 

DBC,   RH, 

UCC. 

SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Hanufacturers '    identification  codes 
(according  to   list   in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

EsteTS  of  Mcnohydrio  Alcohols — Continued 

Isobutyl   chloro formate 

Isobutyl   isobutyrate 

Isodecyl   aery late 

*Iso-octyl  mercaptoacetate 

Iso-octyl    3-ine  re  apt  ©propionate 

*Isopropyl   acetate 

Isopropyl   chloro formate 

Lauryl    lactate 

Lauryl  methacrylate 

Lauryl  stearyl   thiodipropionate 

Maleic  esters   and  copolymers 

Methallylidene  di acetate 

*Methyl   acetate 

Methyl   acetoacetate 

Methyl   acrylate,   monomer 

Methyl   borate 

Methyl   chloroacetate 

Methyl    chloro formate 

Methyl   di chloro acetate 

Methyl   formate 

*Methyl  methacrylate,   monomer 

4-Methyl-2-pentyl   acetate 

Methyl   sulfate    CDimethyl   sulfate) 

Methyl   vinyl   acetate 

Myristyl    lactate 

Octadecyl   3-mercaptopropionate 

'Phosphorus   acid  esters: 

Bis [2-ethylhexyl)    hydrogen  phosphate 

Bis  (2-ethylhexyl}   hydrogen  phosphite 

Butyl  hydrogen  phosphates 

Dibutyl  butylphosphonate 

Dibutyl   hydrogen  phosphite 

Didodecyl  hydrogen  phosphate 

Diethyl   ethylphosphonate 

Diethyl  hydrogen  phosphite 

Diethyl  phosphorochloridothionate 

Dimethyl   hydrogen  phosphite 

Dimethyl   methylphosphonate 

Dimethyl   phosphorochloridothionate 

Dioleyl  hydrogen  phosphite 

2-Ethylhexyl   hydrogen  phosphate 

Iso-octyl  hydrogen  phosphate 

Oleyl  hydrogen  phosphate 

Trialkyl   phosphites 

Tr i  (b utoxye thyl)phosphate 

Tributyl   phosphate 

Tri ethyl  phosphite 

Triiso-octyl  phosphite 

Tri  i  s  op ropy 1   phosphi  te 

Trimethyl  phosphite 

Tris(2-chloroethyl)   phosphite 

Tris (chloroisopropyl)    thionophosphate 


CTN,   OTC. 

EKX. 

UCC. 

CCW,    EVM,   IIAB. 

EVN. 

EKT,    EN J,   UCC. 

CTN,    PPG. 

VND. 

X. 

EVN. 

GAP,    USS. 

UCC. 

EK,    GRD,   MON,   UCC. 

EKT,   UCC. 

CEL,   DBC,    RH. 

SFS. 

DOW,    KF. 

CTN,    FMP. 

PD. 

CEL,   DUP. 

ACY,    DUP,    RH. 

PUB,    SHC,   UCC. 

DUP. 

UCC. 

VND. 

EVN. 

SM,   UCC. 

SM. 

SM. 

SM. 

SM. 

DUP. 

SH. 

SM. 

SPA. 

SM. 

SM. 

SPA. 


COM,    FMP,    HN. 
SPA,    SFS,    SM. 


SM. 

SFA,    SFS,    SM. 


MISCELLANEOUS  CHEMICALS 
TABLE  2, --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported^ 

IDENTIFIED   BY   MANUFACTURER,    1972--C0NTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table   3] 


MISCELLANEOUS  CHEMICALS,   ACYCYLIC--Continued 

Esters  of  Monohydrio  Alcohols — Continued 

♦Phosphorus   acid  esters--Continued 

Tris(2,3-dibromopropyl)   phosphate 

Tris (l,3-dichloro-2-propyl)   phosphorothioate 

All   other 

Poly (methylvinyl    ether/monoethyl   maleate) 

♦Propyl   acetate 

Propylene   carbonate 

Stear>'l   methacrylate 

Tetraethyl   silicate 

1 ,1,3,3-TetramethylbutyI   peroxy-2-ethylhexanoate 

Tetraoctyl   orthosilicate 

Titanic   acid  esters: 

Bis (2- [bis (2-hydroxyethyl) amino] ethyl)    diisopropyl 

titanate . 
Bis(l-methyl-3-oxo-l-butenyl)    diisopropyl   titanate-- 

Tetrabutyl   titanate 

Tetraisopropyl   titanate 

Tetrakis(2-ethylhexyl)   titanate 

Other 

Triethyl  orthoacetate 

Trie  thy  1  orthoformate 

Triethyl  orthopropionate 

Triisodecyl  orthoformate 

Trimethyl  orthoformate 

*Vinyl  acetate,  monomer 

All  other 

Halogenated  Hydrooarbons 

1-Bromobutane    Cn-Butyl  bromide) 

2-Bromobutane   (sec-Butyl  bromide) 

Bromochlorome thane 

l-Bromo-3-chloropropane    (Trimethylenechlorobromide) — 

2-Bromo-2-chloro-l,l ,1-trifluoroe thane 

Bromoethane    (Ethyl  bromide) 

1-Bromohexane    (n-Hexyl  bromide) 

l-Bromo-3-methylbutane 

l-Bromo-3-methyl-2-butene 

1-Bromo-octadecane 

1-Bromo-octane   (n-Octyl  bromide) 

2-Bromopentane    (1-Methylbutyl  bromide) 

1-Bromopropane    (n-Propyl  bromide) 

Bromotrichlorome thane 

Bromotrifluorome thane 

n- Butyl    chloride 

♦Carbon  tetrachloride 

Carbon  tetrachloride  crude 

♦Chlorinated  paraffins: 

Less   than   35%   chlorine 

♦35%-64%  chlorine 

bS't.  or  more   chlorine 

2-Chloro-l,3-butadiene 

1-Chlorobutane    (n-Butyl   chloride) 

2-Chlorobutane    (sec-Butyl   chloride) 

l-Chloro-l,l-difluoroethane 

♦Chlorodifluorome thane 


HN, 

SM. 

ALD, 

TNI. 

CEL, 

JCC. 

X. 

ucc. 

WTL. 
MON. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

KF. 

KF. 

KF. 

KF. 

KF. 

BOR, 

ALD, 


DOW. 

MCH. 

ICI. 

DOW, 

HMY. 

LIL. 

SDW. 

DUP. 

MCH. 

LIL. 

EK, 

MCH. 

DUP. 

BRD. 

ACS, 

TNA. 


MCH. 
DUP,   MON,    SM,    TNA,   WES. 
EKT,    PUB,   UCC. 


CEL,    NSC,    UCC,   USI. 

CEL,   CTN,   DUP,    EFH,    EK,    EMR,    ENJ,    EVN,    GAF,    HUM, 
PIC,   RH,    UCC,   WTL,    ZGL. 


DA,    DOW,    FMB,    FRO,    PPG,   SFI . 


DA,    HK. 

CCH,   DA,    DVC,    HPC,    ICI,    NEV. 

DA,    DVC,   NEV. 

DUP. 

PUB,   UCC. 

EK,   PLC. 

DUP,    PAS. 

ACS,    DUP,    KAI,    PAS,   RCN. 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 
TABLE  2.— Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported 

IDENTIFIED   BY    MANUFACTURER,    1972— CONTINUED 


Manufacturers'   identification  codes 
(according  to  list   in  table   3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC- -Continued 

Halogenated  Hydrocarbons — Continued 

*Chloroethane   (Ethyl   chloride) 

*Chloroform 

*Chloromethane    (Methyl   chloride) 

2-Chloro-2-methylpropane    (tert-Butyl  chloride) 

3-Chloro-2-methylpropene    (Methallyl   chloride) 

Ch 1 oropent  af luoroe  th  ane 

3-Chloropropene   (Allyl  chloride) 

Chlorotrifluoroethylene    (Trifluorovinyl  chloride) 

Ch lorotrif luoroe thy lene,   polymerized 

Chlorotrifluorome  thane 

*1 ,2-Dibromoethane    (Ethylene   dibromide) 

Dibromomethane    (Methylene  bromide) 

l,2-Dibromo-l,l ,2 ,2-tetrafluroethane 

Dichlorobutadiene 

l,3-Dichloro-2-butene 

1 ,4-Dichlorobutene 

*Dichlorodifluorome thane 

*l,2-Dichloroethane   (Ethylene  dichloride) 

*Dichloromethane    (Methylene  chloride) 

*l,2-Dichloropropane    (Propylene  dichloride) 

2 ,3-Dichloropropene 

Dichlorotetraf luoroethane 

1 ,1-Dif  luoroethane 

Diiodomethane    (Methylene   iodide) 

Fluronated  ethylene  propylene 

Hexadecyl   chloride 

Hexaf luoro-2-propane 

Hexafluoropropylene,   monomer 

lodoethane   (Ethyl   iodide)  ,   tech 

Iodoform   (Triiodome thane) 

*Iodomethane    (Methyl   iodide) 

1 - 1 odoperf luorohexane 

Lauryl   chlorides 

Octafluorocyclobutane 

Octyl   chloride 

1 ,1,2,2-Tetrabromoethane  (Acetylene  tetrabromide) — 
1 ,1,2,2-Tetrachloroethane    (Acetylene   tetrachloride) - 

*Tetrachloroethylene    (Perch loroe thy lene) 

Tetraf luoroethylene ,   monomer 

Tetrafluorome thane 

*l,l,l-Trichloroethane    (Methyl   chloroform) 

1 ,1,2-Trichloroethane    (Vinyl  trichloride) 

*Trich loroe thy lene 

*Trichlorofluoromethane 

1 ,2,3-Trichloropropane 

1 ,2,3-Trichloropropene 

Trich lorotrif luoroethane 

Vinyl  bromide    (Bromoethylene) 

*Vinyl   chloride,  monomer   (Chloroethylene) 


AME,   DOW,    DUP,   HPC,    PPG,   SHC,   TNA. 

ACS,    DA,    DOW,    DUP,    FRO,    SFI. 

ACS,    CO,    DCC,   DOW,    DUP,    FRO,   TNA,   UCC. 

EK. 

FMP. 

DUP. 

DOW,    SHC. 

ACS,    MMH. 

MHM. 

DUP. 

DOW,    GIL,    MCH,    PPG,   TNA. 

DOW. 

DUP. 

DUP. 

DUP. 

DUP. 

ACS,    DUP,    KAI,    PAS,    RCN,   UCC. 

ACS,    AME,    BFG,   CO,   DA,    DOW,    FRO,   JCC,   OMC,    PPG, 

TNA,   UCC,   IVYN. 
ACS,   DA,    DOW,    DUP,    FRO,    SFI. 
DOW,    JCC,    UCC. 
DOW. 

ACS,  DUP. 
ACS,  DUP. 
NTS,  SDW. 
DUP. 

BRD. 

DUP. 

DUP. 

EK,    FMT,    RSA. 
NTB. 

EK,    FMT,   RSA. 

DUP,   TKL. 

AZT,    BRD. 

DUP. 

BRD. 

DOW. 

TTX. 

DA,    DOW,    DUP,    FRO,    HK,   PPG,   SFI,   TNA. 

DUP,    PAS,   TKL. 

DUP. 

DOW,    FRO,    PPG,   TNA. 

DOW,    UCC. 

DOW,    DUP,   HK,    PPG,   TNA,   TTX. 

ACS,    DUP,    KAI,    PAS,    RCN,   UCC. 

DOW,    SHC. 

DOW,    PAS. 

ACS,  DUP. 

DOW,   TNA. 

ACS,   AME,    BFG, 


CO,    DOW,    HN,   MNO,    PPG,    SHC,   TNA. 


MISCELLAflEOUS  CHEMICALS 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported, 

IDENTIFIED   BY    MANUFACTURER,    1972~C0NTINUED 


Manufacturers'   identification  codes 
(according  to  list  in  table  3) 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

Halogenated  Hydrocarbons — Continued 

Vinyl   fluoride 

Vinylidene  chloride,   monomer   (1,1-Dichloroethylene) 

Vi  ny 1 i  dene   f luori  de 

All   other 

All  Othev  Miscellaneous  Acyclic  Chemicals 

Acetyl  peroxide 

Aluminum  isopropoxide  (Aluminum  isopropylate) 

*2-Butanone  peroxide 

tert- Butyl  hydroperoxide 

*tert-Butyl  peroxide  (Di-tert-butyl  peroxide) 

Butyrolactone 

Caprolactone 

*Carbon  disulfide 

2-Chloroethanol    (Ethylene   chlorohydrin) 

Decanoyl  peroxide 

Di aldehyde  starch 

2 , 3- Dib  romop  ropanol 

2,5-Dimethyl-2,5-bis (2-ethyl-l-hexanoylperoxy)hexane — 

2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexane 

2, 5- Dime thy 1-2, 5- di (tert-butylperoxy)hexyne-3 

*Epoxides,   ethers,    and  acetals: 

Acetone  dimethylacetal    (2,2-Dimethoxypropane) 

1- (Allyloxy)-2,3-epoxypropane    (Allyl   glycidyl   ether)- 

Bis(2-chloroethoxy)methane    (Dichloroethylformal) 

Bis(2-chloroethyl)    ether    (Dichlorodiethyl   ether) 

Bis(2-chloro-l-methylethyl)   ether   (Dichloroisopropyl 
ether) . 

l-Butoxy-2,3-epoxypropane   (Butyl   glycidyl   ether) 

Butylene  oxide 

Butyl  ether    (Di-n-butyl   ether) 

Butyl   vinyl   ether 

2-Chloroethyl  vinyl  ether 

Chloromethyl  methyl   ether 

2,2-Dichloro-l,l-difluoroethyl   methyl   ether 

Dimercaptodiethyl  ether 

Epi chlorohydrin 

'Ethylene  oxide 

Ethyl  ether: 

Absolute 

*Tech 

U.S.P 

Ethyl  vinyl  ether 

Glycidol  (2,3-Epoxy-l-propanol) 

Isobutyl  vinyl  ether 

*  Is opropy 1  ether 

Methyl  ether  (Dimethyl  ether) 

Methyl  vinyl  ether 

'Propylene  oxide 

Triglycol  di chloride 

Vinyl  methoxytriglycol 

Other 


DUP. 

DOW, 

FRO. 

DUP. 

ALD, 

BRD, 

DUP, 

EK, 

HMY, 

LIL,   RSA,   SDW. 

AZT, 

WTL. 

CHT, 

KCH. 

AZT, 

CAD, 

NOC, 

RCl 

WTC 

WTL. 

AZT, 

CAD, 

OCC, 

WTC 

WTL 

AZT, 

CAD, 

NOC, 

SHC 

WTC 

WTL. 

GAP. 

IICC. 

ACS, 

RIB, 

PAS, 

PPG 

SFI 

UCC. 

WTC, 

WTL. 

ULS. 

GTL, 

MCH. 

WTL. 

IVTL. 

WTL. 

DOW. 

AAC, 

SHC. 

TKL. 

DOW. 

DOW, 

MOB. 

DOW. 

DOW. 

PUB, 

UCC. 

GAP, 
AAC, 

UCC. 
UCC. 

RH. 
DOW. 

F.VN,  USR. 
DOW,  SHC,  X. 

CAU,  CEL,  DOW,  EKX,  JCC,  MAT,  NWP,  OMC,  PPG,  SHC,  SNO, 
UCC,  WYN. 


MAL. 

EN  J, 

MAL, 

GAP, 

DIX. 

GAF. 

EN  J, 

DUP, 

GAF. 

CEL,  DOW,  JCC,  OCC,  OMC,  UCC,  WYN. 

RH. 

UCC. 

EK,  ICI,  SHC,  UCC. 


HPC,  USI. 

OMS. 

UCC. 


SHC,  UCC. 
UCC. 


SYNTHETIC  ORGANIC  CHEMICALS/ W72 
TABLE  2.— Miscellaneous  chemicals  for  which  US.   production  or  sales  were  reported, 

IDENTIFIED    BY    MANUFACTURER,    1972--C0NTINUED 


MISCELLANEOUS  CHEMICALS,    ACYCLIC--Continued 

All  Other  Misaellaneous  Aayolio  Chemicals— Contirmei 

Epoxy  curing  agents . — — . 

2- (Ethylmercapto)ethanol 

Fats    and  oils,    chemically  modified 

Glucono- delta- lac tone 

Glutaraldehyde  bis(5odium  bisulfite) 

Hexachlorodimethyl   sulfone 

n-Hexadecyl   disulfide 

Hydrocarbons : 

1-Butyne   (Ethylacetylene) 

n-Decane 

n-Dodecane 

1-Dodecene 

Hexadecane 

n-Hexane 

Myrcene 

1-Octadecene 

n-Octane 

I (and   2)-0ctene 

Tri-decane 

Other 

Hydrogenated   tallow   glycerides 

Lauroyl   peroxide 

Magnesium  me thy late 

Methane thiol (methyl  mercaptan) 

Methyl al    (Dimethoxymethane) 

Methyl   sulfide    (Dimethyl   sulfide) 

Methyl    sulfoxide 

Organo- aluminum  compounds: 

Diethyl aluminum  chloride 

Diethylalumi num  iodide 

Diisobutyl aluminum   chloride 

Diisobutylaluminum  hydride 

Ethylaluminum  chlorides 

Ethyl  aluminum  sesqui chloride 

Isopropenylaluminum 

Methyl  aluminum  sesqui chloride 

Tri  e  thy 1 a luminum 

Triisobutyl aluminum 

Trimethylaluminum 

Other 

Organo-boron   compounds : 

Boron   fluoride   -    ethyl   ether  complex 

Trie thy lb or ane 

Trimethoxyboroxine 

Trimethyl  borate 

Organo- lead   compounds: 

*Tetraethyllead 

Tetrame  thy  Head 

Tetra (methyl -ethyl) lead 

Other 

n- Butyl  lithium 

sec- Butyl  lithium 

Organo-magnesium  halides 

Organo-mercury   compounds 

*0rgano-silicon   compounds: 

Chlorotrimethylsilane 

Dichlorodimethylsilane 

Dichloromethylsilane 

Dichloromethylvinylsilane 


Manufacturers'   identification  codes 
(according  to  list   in  table   3) 


SHC. 
PLC. 

ABB,   DOM. 
PFZ. 
IDC. 

PAS. 


AIP. 

HMY, 

PLC. 

HMY, 

PLC. 

HMY. 

HMY. 

HMY. 

IFF, 

NCI. 

HMY'. 

HMY, 

PLC. 

HMY, 

PLC. 

BLK, 

HMY. 

ALD, 

CBY,  HMY. 

CHL. 

AZT, 

WTL. 

MRT. 

DOW. 

CEL. 

CRZ. 

CRZ. 

TNA, 

TSA. 

ISA. 

TNA, 

TSA. 

TSA. 

TNA, 

TSA. 

TNA, 

TSA. 

TSA. 

TNA. 

TNA, 

TSA. 

TNA, 

TSA. 

TNA. 

TSA. 

ACS. 

TSA. 

SFS. 

»1HI. 

DUP 

NLC,  PPC,  TNA 

DUP, 

NLC,  TNA. 

DUP 

PPG. 

TNA 

FTH 

GAF. 

FTE 

ARA 

EK, 

NTB. 

DCC 

UCC. 

DCC 

UCC. 

DCC 

UCC. 

UCC 

MISCELLANEOUS  CHEMICALS 
TABLE  2. --Miscellaneous  chemicals  for  which  U.S.  production  or  sales  were  reported. 

IDENTIFIED   BY    MANUFACTURER,    1972--CONTINUED 


Manufacturers'   identification  codes 
(according  to   list   in  table   3) 


MISCELLANEOUS  CHEMICALS,   ACYCLIC--Continued 

All  Other  Misaellaneous  Aayolia  Chemicals — Continued 

*Organo- silicon  compounds --Continued 

Trichlorobutylsilane 

Trichloroethylsilane 

Trichloromethylsilane 

Trichlorovinylsilane 

Silicone  greased 

Other  organo- silicon  compounds 

Organo-tin  compounds: 

Bis(tributyltin)   oxide 

Dibutyltin  bis    lauryl   mercaptide 

Dibutyltin  di chloride 

Dibutyltin   oxide 

Dioctyltin  oxide 

Organotin  mercaptide 

Tributyltin  chloride 

Tributyltin  fluoride 

Other 

Organo- zinc  compounds 

Oxidized  hydrocarbon  mixtures 

Perchloromethanethio   (Perchloromethyl  raercaptan) 

*PhosgenB  (Carbonyl   chloride) 

Pine  oil,   synthetic 

S-Propiolactone 

Rare   sugars 

Sodium  ethoxide 

Sodium  formaldehyde  bisulfite 

Sodium  formaldehyde  sulfoxylate 

*Sodium  methoxide  (Sodium  methylate) 

Sodium  succinaldehyde  bisulfite 

Succinyl  peroxide 

Trioctylphosphine  oxide 

Zinc  formaldehyde  'sulfoxylate 

Other 


DCC. 
DCC. 
DCC. 
UCC. 
SPD. 
DCC,  SFS,  UCC. 

CCW,  X. 


CCW. 
PCW, 


X. 

TSA. 
ALX. 
SFC. 

ACS,  CTN,  DUP,  MOB,  OMC ,  OTC,  PPG,  RUC,  UPJ,  VDM. 
CBY,  NCI. 
CEL. 
PEN. 
FMP . 

EK,  IDC. 
DA,  RH. 
DA,  OMC,  RBC, 
HEX. 
OTL. 
EK. 

DA,  RH. 

ABB,  ALD,  ALX,  CEL,  EK,  GNM,  HMY,  NLC,  NTB,  NIL,  PIC, 
PLC,  RSA,  SDW,  SFS,  SHC,  TCH,  TNA,  UCC,  WTL,  x,  x. 


552-743  O  -  74  -  16 


SYNTHETIC  ORGANIC  CHEfllCALS,  1972 
TABLE  3.— Miscellaneous  chemicals:  Directory  of  Manufacturers,  1972 


ALPHABETICAL  DIRECTORY  BY  CODE 

[Names  of  miscellaneous  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission  for 
1972  are  listed  below  in  the  order  of  their  identification  codes  as  used  in  table  2] 


Name  of  company 


Name  of  company 


Alcolac  Chemical  Corp. 

American  Aniline  §  E.xtract  Co.,  Inc. 

Abbott  Laboratories 

Arc  Chemical  Corp. 

Allied  Chemical  Corp.: 

Agricultural  Div. 

Plastics  Div. 

Specialty  Chemicals  Div. 
American  Cyanamid  Co. 
Agway,  Inc.,  Olean  Nitrogen  Complex 
Air  Products  6  Chemicals,  Inc. 
Ark  la  Chemical  Corp. 
Arkansas  Co. ,  Inc. 
Ames  Laboratories,  Inc. 
Alco  Chemical  Corp. 
Aldrich  Chemical  Co.,  Inc. 
Allied  Chemical  Corp.,  Fibers  Div. 
Alox  Corp. 

American  Bio- Synthetic  Corp. 
American  Chemical  Corp. 
Arapahoe  Chemicals  Div.  of  Syntex  Corp. 
Armak  Co. 

Ardmore  Chemical  Co. ,  Inc. 

USS  Agri- Chemicals,  Div.  of  U.  S.  Steel  Corp. 
Arsynco,  Inc. 
Arizona  Chemical  Co. 

Ashland  Oil,  Inc.,  Ashland  Chemical  Co.  Div. 
Ansul  Chemical  Co. 
Atlantic  Richfield  Co.,  ARCO  Div. 
PMC  Corp. ,  Fiber  Div. 
AZ  Products  Co.  Div.  of  A2S  Corp. 
Dart  Industries,  Inc.,  Aztec  Chemicals  Div. 


Goodrich  Chemical 


Baxter  Laboratories,  Inc. 
B.  F.  Goodrich  Co. , 

Co.  Div. 
Pace  National  Corp. 
J.  T.  Baker  Chemical  Co. 
Hillmaster  Onyx  Corp.,  Millmaster  Chemical 

Co.  Div.,  Berkeley  Chemical  Dept. 
Borden  Co.,  Borden  Chemical  Co.  Div. 
Stauffer  Chemical  Co.,  Specialty  Qiemical 

Div.,  Benzol  Products 
Lonza,  Inc. 
Buckeye  Cellulose  Corp. 

Noury  Chemical  Corp. 

Calcasieu  Qiemical  Corp. 

Qiembond  Corp. 

Crosby  Chemicals,  Inc. 

Cincinnati  Milacron  Chemicals,  Inc. 

Chase  Chemical  Corp. 

Pears  all  Chemical  Co. 

Cincinnati  Milacron  Chemicals,  Inc. 

Celanese  Corp. : 

Celanese  Chemical  Co. 

Celanese  Fibers  Co. 

Celanese  Plastics  Co. 
Cooperative  Farm  Chemicals  Association 
Ciba-Geigy  Corp.  5 

Ciba  Pharmaceutical  Co. 


CHH 
CHL 
CHN 
CHP 
CHT 

CLK 
CLN 

CNC 

CNP 

CO 

COL 

COM 

CP 

CPS 

CRN 

CRT 

CRZ 

CTN 
CWN 


DAN 
DBC 
DCC 
DEX 
DIX 
DLI 
DOL 
DOM 
DOW 
DUP 
DVC 


EKT 
EKX 
ELP 
01R 
ENJ 
ESA 
EVN 

FCA 
FER 


FIN 
FIS 

FMB 
FMP 

FMT 
FRO 
FTE 
FTX 


Charles  Hansen's    Laboratory,    Inc. 

Chemol,    Inc. 

Cherokee  Nitrogen  Co. 

C.  H.  Patrick  §  Co . ,  Inc. 

Chattem  Drug  5  Chemical   Co.,    Chattem 

Chemicals  Div. 
Clark  Chemical  Corp. 
Standard  Brands,    Inc.,   Clinton  Corp. 

Processing  Co.   Div. 
Columbia  Nitrogen  Corp. 
Nipro   Inc. 
Continental  Oil  Co. 
Collier  Carbon  5  Chemical   Corp. 
Commercial   Solvents   Corp. 
Colgate-Palmolive  Co. 
CPS  Chemical   Co. 
CPC   International,    Inc. 
Crest  Chemical  Corp. 
Crown   Zellerbach  Corp.,   Chemical   Products 

Div. 
Chemetron  Corp.,   Organic  Chemical   Div. 
Upjohn  Co.,    Fine   Chemical  Div. 

Diamond  Shamrock  Corp. 

Dan  River,    Inc. 

Dow   Badische  Co. 

Dow  Coming  Corp. 

Dexter  Chemical  Corp. 

Dixie   Chemical   Co. 

Dawe's   Laboratories,    Inc. 

Dole  Co.,   Div.   of  Castle   6  Cook,    Inc. 

Dominion  Products,    Inc. 

Dow  Chemical  Co. 

E.    I.   DuPont  de  Nemours   5  Co.,    Inc. 

Dover  Chemical   Corp. 

E.    F.   Houghton   S  Co. 
Eastman   Kodak  Co.: 

Tennessee   Eastman  Co.    Div. 

Texas   Eastman  Co.    Div. 
El   Paso  Products    Co. 
Emery   Industries,    Inc. 
Exxon  Chemical  Co.   U.S.A. 
East  Shore   Chemical   Co.,    Inc. 
Evans   Chemetics,    Inc. 


C.    F.    Industries   Inc. 
Ferro  Corp . : 

Ferro   Chemical   Div. 

Grant  Chemical  Div. 
Fine  Organics,    Inc. 
Fisher  Chemical  Co.,    Inc. 
FMC  Corp . : 

Industrial   Chemical   Div. 

Industrial   Chemical   Div. 
Group 


Organic  Business 


Fairmount  Chemical  Co.,    Inc. 
Vulcan  Materials  Co.,   Chemicals   Div. 
Foote  Mineral   Co. 

CF   Industries,    Inc.,   Fremont  Nitrogen 
Complex 


MISCELLANEOUS  CHE^IICALS 
TABLE  3, --Miscellaneous  chemicals:     Directory  of  manufacturers,  1972--Continued 


Name  of  company 


GAF  Corp.,    Chemical   Div. 

Gane's   Chemical  Works,    Inc. 

W.    R.    Grace   5  Co.,    Agricultural   Chem.    Group 

G.    Frederick   Smith   Chemical   Co. 

Givaudan  Corp. 

SCM  Corp.    Glidden-Durkee   Div. 

Glyco  Chemicals,    Inc. 

General   Mills   Chemicals,    Inc. 

Gulf  Oil   Corp.,   Gulf  Oil   Chemicals   Co. -U.S. 

Georgia-Pacific  Corp. 

Grain  Processing  Corp. 

W.    R.   Grace   5  Co.,   Polymers   5  Chemicals  Div. 

W.    R.    Grace    5  Co.,   Hatco  Chemical    Div. 

Millmaster  Onyx  Corp.,   A.   Gross   6  Co.   Div. 

Great   Lakes   Chemcal   Corp. 

Goodyear  Tire   &  Rubber  Co. 

Halby  Products   Co.,    Inc. 
C.P.   Hall   Co.    of  Illinois 
Hodag  Chemical   Corp. 
Hexagon   Laboratories,    Inc. 
Hoffman-Taff,    Inc. 
Hooker  Chemical   Corp.: 

Dure:  Plastics  Div. 
Hawkeye  Chemical  Co. 
W.   R.   Grace   5  Co.,   Dewey  6  Almy  Chemical 

Div. ,   Organic  Chemical 
Humphrey  Chemical  Co. 
Tenneco  Chemicals,    Inc. 
Hercules,    Inc. 
Hart  Products  Corp. 
Harshaw  Chemical   Co.,   Div.   of  Kewanee  Oil 

Co. 
Kraftco  Corp.,   Humko  Products  Chemical   Div. 

ICI  America,    Inc.    fi  Specialty  Chemicals   Div. 
Industrial   Dyestuff  Co. 
International   Flavors   §  Fragrances,    Inc. 
lonac  Chemical   Co. 

Jefferson  Chemical   Co.,    Inc. 

Nipak ,    Inc. 

George  A.  Jeffrey's  5  Co.,  Inc. 

Jordan  Chemical  Co. 

Joseph  Turner  6  Co. 

Kaiser  Aluminum  §  Chemical  Corp.,  Kaiser 

Chemicals  Div. 
Kennecott  Copper  Corp.,  Chino  Mines  Div. 
Keystone  Chemurgic  Corp. 
Kennecott  Copper  Corp.,  Utah  Copper  Div. 
Kay-Fries  Chemicals,  Inc. 
H.  Kohnstamm  6  Co.,  Inc. 
Koppers  Co.,  Inc.,  Organic  Materials  Div. 

LaMotte  Chemical  Products  Co. 
Lemke  Chemicals,  Inc. 
Eli  Lilly  f,  Co.,  Inc. 
Lubrizol  Corp. 

Mallinckrodt  Chemical  Works 

Koch  Chemical  Co. 

Michigan  Chemical  Corp. 

Mooney  Chemicals,  Inc. 

Ventron  Corp. 

Miles  Laboratories,  Inc.,  Marschall  Div. 

Minnesota  Mining  6  Manufacturing  Co. 

Monochem,  Inc. 

Mob ay  Chemical  Co. 


MON 
MOR 
MRK 
MRT 

MSC 
MTO 

NCI 
NEP 
NES 
NEV 
NLC 
NOC 
NOR 
NPI 

NSC 
NIB 

NTL 


OMC 
OUS 
ONX 
OPC 
ORO 
ORT 
OTC 
OXC 

PAR 

PAS 

PCW 

PD 

PEN 

PEN 

PFW 

PFZ 

PG 

PHR 

PIC 

PLB 

PLC 

PLS 
PUP 
PPC 
PPG 
PRD 
PTT 
PUB 
PVO 

QCP 
QKO 

RBC 
RCI 

RCN 
RBH 


Monsanto  Co. 
Marathon  Morco,  Co. 
Merck  5  Co. ,  Inc. 

Morton  Chemical  Co.,  Div.  of  Morton- 
Norwich  Products,  Inc. 
Mississippi  Chemical  Corp. 
Montrose  Chemical  Corp.  of  California 

Union  Camp  Corp.,  Chemical  Div. 

Nepera  Chemical  Co. 

Nease  Chemical  Co.,  Inc. 

Neville  Chemical  Co. 

Nalco  Chemical  Co. 

Norac  Co.,  Inc.  and  Mathe  Chemical  Co.  Div. 

Norwich  Pharmacal  Co. 

Stepan  Chemicals  Co.,  National  Polychemicals 

Div. 
National  Starch  6  Chemical  Corp. 
National  Biochemical  Co. 
NL  Industries,  Inc. 
Northwestern  Chemical  Co. 
Northern  Petrochemicals  Co. 

Oxirane  Chemical  Co. 

Airco,  Inc.,  Ohio  Medical  Product  Div. 

Olin  Corp. 

E.  R.  Squibb  6  Sons,  Inc. 

Millmaster  Onyx  Corp.,  Onyx  Chemical  Co. 

Orbis  Products  Corp. 

Chevron  Chemical  Co. 

Roehr  Chemicals,  Inc. 

Ott  Chemical  Co. 

Oxochem  Enterprises 

Pennsylvania  Refining  Co. 

Pennwalt  Corp. 

Pfister  Chemical  Works 

Parke,  Davis  5  Co. 

CPC   International,    Inc.,   S.    B.    Penick  Div. 

Pfanstiehl   Laboratories,   Inc. 

Polak's   Frutal  Works,   Inc. 

Pfizer,    Inc. 

Procter  5  Gamble  Co. 

Pharmachem  Corp. 

Pierce  Chemical,    Inc. 

P-L  Biochemicals ,    Inc. 

Phillips  Petroleum  Co.    5  Phillips  Pacific 

Chemical   Co. 
Plastics  Engineering  Co. 
Premier  Malt  Products,    Inc. 
Premier  Petrochemical  Co. 
Pittsburgh   Plate  Glass  Co. 
Productol  Chemical  Co.,    Inc. 
Petro-Tex  Chemical 
Publicker  Industries,    Inc. 
PVO   International,    Inc. 

Quaker  Chemical  Corp. 
Quaker  Oats  Co. 

Fike  Chemicals,    Inc. 

Reichhold  Chemicals,    Inc. 

Racon,    Inc. 

Reheis  Chemical  Co.  Div.  of  Armour 

Pharmaceutical  Co. 
Remington  Arms  Co.,  Inc. 
Rohm  §  Haas  Co. 
Robeco  Chemicals,  Inc. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3.— Miscellaneous  chemicals:  Directory  of  manufacturers.  1972— Continued 


Code 

Name   of  company 

Code 

Name   of  company 

RPC 

Millmaster  Onyx  Corp.,   Refined-Onyx  Div. 

TEK 

Teknor  Apex  Co. 

RSA 

R.S.A.   Corp. 

TER 

Terra  Chemicals   International,    Inc. 

RT 

F.    Ritter  S  Co. 

TID 

Getty  Oil  Co. 

RUB 

Hooker  Chemical   Corp, ,   Ruco  Div. 

TKL 

Thiokol   Chemical   Corp. 

RUC 

Rubicon  Chemicals,    Inc. 

TNA 

Ethyl  Corp. 

TNI 

Gillette  Chemical  Co.,   Div.   of  Gillette  Co. 

S 

Sandoz,    Inc.,   Sandoz  Colors   6  Chemical 

tri 

Triad  Chemicals 

Div. 

TRO 

Troy  Chemical  Co. 

SAL 

Salsbury  Laboratories 

TSA 

Texas   Alky Is,    Inc. 

SAR 

Sartomer   Industries,    Inc. 

ttx 

Detrex  Chemical   Industries,    Inc. 

SBC 

Scher  Bros. 

TX 

Texaco,   Inc. 

SCH 

Schering  Corp. 

TZC 

Tizon  Chemical  Corp. 

SDC 

Martin-Marietta  Corp.,    Sodeyco  Div. 

Sterling  Drug,    Inc.: 

UCC 

Union  Carbide  Corp. 

SDH 

Hilton-Davis   Chemical   Co.    Div. 

UOP 

Universal   Oil   Products   Co.,   UOP  Chemical    Di 

SDW 

Winthrop    Laboratories    Div. 

UPJ 

Upjohn  Co. 

Stauffer  Chemical   Co.: 

UPM 

Universal   Oil    Products   Co. 

SPA 

Agricultural    Div. 

USB 

U.S.   Borax  Research  Corp. 

SFC 

Calhio  Chemicals,    Inc.    Div. 

US  I 

National  Distillers   6  Chemical  Corp.,   U.S. 

SFI 

Industrial   Div. 

Industrial   Chemicals   Co.    Div. 

SFS 

Specialty  Chemical   Div. 

USS 

USS  Chemicals   Div.   of  U.S.   Steel  Corp. 

SHA 

Shanco  Plastics   5  Chemical   Co. 

USR 

Uniroyal,    Inc.,   Chemical  Div. 

SHC 

Shell  Oil   Co.,   Shell  Chemical  Co.    Div. 

SHF 

Kraftco  Corp.,   Sheffield  Chemical   Div. 

VAC 

Northern  Petrochemical  Co. 

SHP 

Shepherd  Chemical   Co. 

VAL 

Valchem 

SK 

Smith,    Kline   5  French   Laboratories 

VDM 

Van  De  Mark  Chemical  Co. 

SKG 

Sunkist  Growers,    Inc. 

VEL 

Velsicol  Chemical  Corp.,    Inc. 

SKO 

Skelly  Oil  Co. 

VGC 

Virginia  Chemicals,    Inc. 

SM 

Mobil   Oil  Corp.,   Mobil   Qiemical   Co., 

VLN 

Valley  Nitrogen  Producers,    Inc. 

Chemical   Coatings   Div. 

™d 

Van  Dyk   5  Co. ,   Inc. 

Industrial   Chemical   Div. 

VPC 

Verona  Corp . 

SNI 

Kaiser  Aluminum  5  Chemical  Corp.,    Kaiser 

Agricultural   Chemicals   Div. 

WAY 

Phillip  A.   Hunt  Chemical  Corp.,   Wayland 

SNO 

SunOlin  Chemical   Co. 

Chemical   Div. 

SNW 

Sun  Chemical   Corp.,    Chemical   Div. 

WBC 

Worthington  Biochemical  Corp. 

SOC 

Standard  Oil   Co.    of  California,   Chevron 

WBG 

White  5   Bagley  Co. 

Chemical   Co. 

WCL 

Wright  Chemical  Co. 

SOH 

Vistron  Corp. 

WES 

Borg-Warner  Corp.,   Weston  Chemical   Div. 

SOI 

American  Oil  Co.    CMaryland) 

mi 

Wilson  Pharmaceutical    5  Chemical    Corp., 

SPD 

General    Electric   Co.,    Silcon   Products 

Wilson-Martin  Div. 

Dept. 

WMP 

Essex  International,    Inc.,   Electro- 

SPR 

Scientific   Protein   Laboratories 

Mechanical  Div. 

SIP 

Stepan  Chemical   Co. 

WSN 

Mallinckrodt  Chemical  Works,   Washine   Div. 

SW 

Sherwin-Williams   Co. 

wtc 

Witco  Chemical  Co.,    Inc. 

SYP 

Dart   Industries,    Inc.,   Synthetic  Products 

WTH 

Union  Camp   Corp.,   Harchem  Div. 

Co.    Div. 

WTL 

Pennwalt  Corp.,    Lucidal   Div. 

WYC 

Wycon  Chemical  Co. 

tae 

Chemetron  Corp.,   Medical   Products 

Div. 
Tanatex  Chemical   Corp 

WYN 

Wyandotte  Chemicals   Corp. 

TCC 

ZGL 

Carolina  Processing  Corp. 

TCH 

Emery  Trylon  Chemicals   Div.    Industries 

Inc. 

Note. — Complete  name=  and  addresses  of  the  above  reporting  companies 


listed  in  Table  1  of  the  Appendix. 


APPENDIXES 


APPENDIX  A 
DIRECTORY  OF  HANUFACTURERS 

TABLE  1.— Synthetic  organic  chemicals;  Alphabetical  Directory  of  manufacturers,  by  company.  1972 

[Names  of  synthetic  organic  chemical  manufacturers  that  reported  production  or  sales  to  the  U.S.  Tariff  Commission 
for  1972  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  table  2  of  the  14 
individual  sections  of  this  report] 


Office  address 


A  5  E  Plastic  Pak  Co.,  Inc 

AZS  Corp . : 

AZ  Products  Co.  Div 

Lancaster  Chemcial  Co.  Div 

Abbott  Laboratories 

Abex  Corp. ,  .American  Brakelok  Div 

Acme  Chemical  Co 

Acme  Resin  Co 

Agway,  Inc. ,  Olean  Nitrogen  Div 

Airco,  Inc.,  Ohio  Medical  Products  Div 

Air  Products  S  Chemicals,  Inc.,  Chemicals 
Group 

Alco  Chemical  Corp. 

Alcolac,  Inc 

Aldrich  Chemical  Co. ,  Inc 

Alliance  Chemical  Co.,  Inc 

Allied  Chemical  Corp.: 

Fibers  Div 

Plastics  Div 

Seme t- Sol vay  Div 

Specialty  Chemicals  Div 

Union  Texas  Petroleum  Div 

Agr i  cu 1 tural  Dep t 

Alox  Corp 

Alpha  Laboratories,    Inc 

Amchem  Products,    Inc.,    Div.    of  Rorer- 
Amchem,    Inc. 

Amerace-Esna  Corp. ,    Penetone  Div 

Amerada  Hess   Corp 

American  Aniline   5  Extract  Co.,    Inc 

American  Aniline  Products,    Inc 

American   Bio-Synthetics   Corp 

American  Can  Co 

American  Chemical   Corp 

.American  Cyanamid  Co 

.American  Hoechst  Corp 

American  Oil   Co.    (Maryland) 

American  Oil   Co.    (Texas) 

.American  Synthetic   Rubber  Corp 

Ames    Laboratories,    Inc 

Amoco  Chemical  Corp 

.Amoco  Production  Co 

Ansul   Chemical  Co 

Apex  Chemical   Co. ,    Inc 

Apollo  Colors,    Inc 

Applied   Plastics   Co. ,    Inc 

Arapahoe  Chemicals  Div.    of  Syntex  Corp 

Arc  Chemical  Corp 

Ardmore  Chemical  Co. ,    Inc 

Arenol  Chemical  Corp 

Argus   Chemical   Corp.,   Halby  Div 

Arizona  Chemical   Co 

.Arkansas   Co.  ,    Inc 

Arkla  Chemical  Corp 

Armak  Co 


14505  E.  Proctor  .Ave. ,  Industry,  CA  91747. 

2525  So.  Combee  Rd.,  Eaton  Park,  FL  33840. 

Broad  6  13th  St.,  Carlstadt,  NJ  07072. 

14th  St.  and  Sheridan  Rd.,  N.  Chicago,  IL  60664. 

2401  S.  Loudoun  St.,  Winchester,  VA  22601. 

2S06  N.  32d  St.,  Milwaukee,  WI  53245. 

1401  S.  Circle  Ave.,  Forest  Park,  IL  60130. 

1446  Buffalo  St.,  Olean,  NY  14760. 

3030  Airco  Dr.,  P.O.  Box  1319,  Madison,  KI  53701. 

5  Executive  Mall,  Swedesford  Rd. ,  Wayne,  PA  19087. 

Trenton  Ave.  and  William  St.,  Philadelphia,  PA  191 
3440  Fairfield  Rd. ,  Baltimore,  MD  21226. 
940  W.  St.  Paul  Ave.,  Milwaukee,  WI   53233. 
33  Avenue  P,  Newark,  NJ  07105. 

1  Times  Square,  New  York,  NY  10036. 
P.  0.  Box  2365R,  Morristown,  NJ  07960. 
P.  0.  Box  1013R,  Morristown,  NJ  07960. 
P.  0.  Box  1219R,  Morristown,  NJ  07960. 
P.  0.  BOX  2120,  Houston,  TX  77001. 
P.  0.  Box  2120,  Houston,  TX  77001. 
3943  Buffalo  .Ave.,  Niagara  Falls,  NY  14302. 
1685  S.  Fairfax  St.,  Denver,  CO  80222. 
Brookside  Ave.,  Ambler,  PA  19002. 

74  Hudson  Ave.,  Tenafly,  NJ  07670. 

1  Hess  Plaza,  Woolridge,  NJ  07095. 

Venango  and  F  Sts.,  Philadelphia,  PA  19134. 

P.  0.  Box  3063,  Paterson,  NJ   07509. 

710  W.  National  Ave.,  Milwaukee,  WI   53204. 

American  Lane,  Greenwich,  CT  06830. 

2112  E.  223d  St.,  P.  0.  Box  1110,  Long  Beach,  CA  9 

Wayne,  NJ  07470. 

129  Quidnick  St.,  Coventry,  RI 
910  S.  Michigan  Ave.,  Chicago, 
910  S.  Michigan  Ave.,  Chicago, 
P.  0.  Box  360,  Louisville,  KY 
200  Rock  Lane,  Milford,  CT  06460. 

130  E.  Randolph  Dr.,  Chicago,  IL  60601. 
P.  n.  Box  591,  Tulsa,  OK  74102. 
1  Stanton  St.,  Marinette,  WI  54143. 
200  S.  1st  St.,  Elizabethport,  NJ  07206. 
899  Skokie  Blvd.,  Northbrook,  IL  60062. 
612  E.  Franklin  Ave.,  El  Segundo,  CA  90245. 
2855  Walnut  St.,  Boulder,  CO  80302. 
P.  0.  Box  175,  Slate  Hill,  NY  10923. 
840  Valley  Brook  Ave.,  Lyndhurst,  NJ  07071. 
40-33  23d  St.,  Long  Island  City,  NY   11101. 
600  Terminal  Ave.,  New  Castle,  DE  19720. 
Wayne,  NJ  07470. 

185  Foundry  St.,  Newark,  NJ  07105. 
P.  0.  Box  825,  Helena,  AK  72342. 
300  S.  Wacker  Dr.,  Chicago,  IL  60601. 


02816. 
IL  60680. 
IL  60680. 
40201. 


SYNTHETIC  ORGANIC  CHEMICALS.  B72 
TABLE  L— Synthetic  organic  chemicals;  Alphabetical  directory  of  manufacturers. 

BY  COMPANY.  1972— CONTINUED 


Armour- Dial,  Inc 

Armstrong  Cork  Co 

Arol  Chemical  Products  Co 

Arsynco,  Inc 

Ashland  nil,  Inc 

Ashland  Chemical  Co.  Div 

Astor  Products,  Inc.,  Blue  Arrow  Div 

Astra  Pharmaceutical  Products,  Inc 

Atlantic  Chemical  Corp 

Atlantic  Richfield  Co.,  ARCO  Chemical  Co. 

Div. 
Atlas  Processing  Co 

BASF  Wyandotte  Corp 

BP  Oil   Corp 

J.   T.    Baker  Chemical  Co 

Baltimore  Paint   5  Chemical  Corp 

Baxter  Laboratories,    Inc 

Baychera  Corp. : 

Chemagro  Div 

Verona  Div 

Bayoil  Co.,    Inc 

Beecham,    Inc 

Beech- Nut,    Inc 

Belding  Chemical   Industries 

Bendix  Corp.,   Friction  Materials   Div 

Bennett's 

Benzenoid  Organics,    Inc 

Bemcolors-Poughkeepsie ,    Inc 

Biocraft   Laboratories,    Inc 

Bio- Derivatives   Corp 

Blackman  Uhler  Chemical  Co 

Borden,    Inc.,   Borden  Chemical   Div 

Borg-Wamer  Corp.,   Marbon  Chemical   Div — 
Borg-Wamer  Corp.,   Weston  Chemical   Div — 

Breddo  Food  Products  Corp 

Bristol-Meyers  Co. ,   Bristol   Laboratories 
Div. 

M.   A.    Bruder  fi  Sons,    Inc 

Buckeye  Cellulose  Corp 

Buckman  Laboratories,    Inc 

Budd  Co.,   Polychem  Div 

Burdick   f,  Jackson  Laboratories,    Inc 

Burroughs   S  Wellcome  Co 

CF   Industries,   Inc 

Fremont  Nitrogen  Complex 

CPC   International,    Inc 

S.    B.    Penick  Co 

CPS  Chemical  Co 

Samuel  Cabot,  Inc 

Calcasieu  Chemical  Corp 

Carborundum  Co. ,  Coated  Abrasives  Div 

Car gill ,  Inc 

Carolina  Processing  Corp 

Carpenter-Morton  Co 

Carus  Corp.,  Carus  Chemical  Co.  Div 

Castle  5  Cook,  Inc.,  Hawaii  Region 


Office  address 


P.  0.  Box  4309,  Chicago,  IL  60680. 

Liberty  and  Charlotte  Sts . ,  Lancaster,  PA  17604. 

649  Ferry  St.,  Newark,  NJ  07105. 

P.  0.  Box  8,  Carls tadt,  NJ  07072. 

1401  Winchester  Ave.,  Ashland,  KY  41101  and 

P.  n.  Box  2458,  Columbus,  OH  43216. 
5200  Blazer  Blvd.,  Dublin,  OH  43215. 
5244  Edgewood  Ct . ,  Jacksonville,  FL  32203. 
7-1/2  Neponset  St.,  Worcester,  MA  01606. 
10  Kingsland  Rd.,  Nutley,  NJ  07110. 
260  S.  Broad  St.,  Philadelphia,  PA  19101. 

P.  0.  Box  9389,  3546  Midway  St.,  Shreveport,  LA  71109. 

100  Cherry  Hill  Rd . ,  Parsippany,  NJ  07054. 

398  Midland  Bldg. ,  Cleveland,  OH  44115. 
222  Red  School  Lane,  Philipsburg,  NJ  08865. 
2325  Hollins  Ferry  Rd.,  Baltimore,  MD  21230. 
6301  Lincoln  Ave.,  Morton  Grove,  IL  60053. 

P.  0.  Box  4913,  Station  "F",  Kansas  City,  MO  64120. 

lorio  Ct.,  Union,  NJ  07083. 

2  Union  St.,  Peabody,  MA  01960. 

65  Industrial  S.,  Clifton,  NJ  07012. 

Church  St.,  Canajorharie ,  NY  13317. 

1430  Broadway,  New  York,  NY  10018. 

P.  0.  Box  238,  Troy,  NY  12180. 

65  W.  1st  S.  St.,  Salt  Lake  City,  UT  84110. 

P.  0.  Box  157,  Bellingham,  MA  02019. 

75  N.  Water  St.,  Poughkeepsie ,  NY  12602. 

12  Industrial  Way,  Waldrich,  NJ  07463. 

174  E.  Industry  Ct . ,  Deer  Park,  NY   11729. 

P.  0.  Box  5627,  Spartanburg,  SC  29301. 

50  W.  Broad  St.,  Columbus,  OH  43215. 

P.  0.  Box  68,  Washington,  WV  26181. 

103  Spring  Valley  Rd.,  Montvale,  NJ  07645. 

18th  and  Kansas,  Kansas  City,  KS  66105. 

P.  0.  Box  657,  E.  Syracuse,  NY   13257. 

52d  St.  and  Grays  Ave.,  Philadelphia,  PA  19143. 

2899  Jackson  Ave.,  Memphis,  TN  38108. 

1256  N.  McLean  Blvd.,  Memphis,  TN  38108. 

70  S.  Chapel  St.,  Newark,  DE  19711. 

1953  S.  Harvey  St.,  Muskegon,  MI  49442. 

3030  Comwallis  Rd.,  Research  Triangle  Park,  NC  27709 

P.  0.  Box  87,  Harrison,  TN  37341. 

P.  0.  Box  68,  RFDH3,  Fremont,  NB  68025. 

International  Plaza,  Englewood  Cliffs,  NJ  07632. 

100  Church  St.,  New  York,  NY   10007. 

P.  0.  Box  162,  Old  Bridge,  NJ  08857. 

One  Union  St.,  Boston,  MA  02108. 

P.  0.  Box  1522,  Lake  Charles,  LA  70601. 

Walmore  Rd. ,  P.  0.  Box  477,  Niagara  Falls,  NY  14302. 

Cargill  Bldg.,  Minneapolis,  m     55402. 

P.O.  Box  161,  Severn,  NC  27877. 

376  3d  St.,  Everett,  MA  02149. 

1500  8th  St.,  LaSalle,  IL  61301. 

P.  0.  Box  338,  Honolulu,  HI  96801. 


APPENDIX  A 

TABLE  1. --Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers, 
BY  company,  1'^7?--Continued 


Name   of   company 


Office  address 


Celanese  Corp. : 

Celanese  Chemical   Co 

Celanese  Coatings   Co 

Celanese   Fibers   Co 

Celanese   Plastics   Co 

Champlin  Petroleum  Co 

Charrain   Paper  Products   Co 

Charter  International  Oil  Co 

Chase  Chemical   Corp 

Chattem  Drug   §  Chemical   Co.,    Chattara 
Chemicals   Div. 

Chembond  Corp 

Chemed   Corp . : 

Dubois  Chemicals  Div 

Vestal  Laboratories  Div 

Chemetron  Corp. : 

Medical  Products  Div 

Organic  Chemical  Div 

Pigments  Div 

Chem-Fleur,  Inc 

Chemical  Formulators,  Inc 

Chemlek  Laboratories,  Inc 

Chemol,  Inc 

Chemplex  Co 

Cherokee  Nitrogen  Co 

Chevron  Chemical  Co 

Childs  Pulp  Colors,  Inc 

CHR  Hansen's  Laboratory,  Inc ^.- 

Ciba-Geigy  Corp 

Ciba  Agrochemical  Co 

Ciba  Pharmaceutical  Co 

Cincinnati  Milacron  Chemicals,  Inc 

Cindet  Chemicals,  Inc 

Cities  Service  Co.  : 

Columbia  Div 

Copperhill  Operations 

Levey  Div 

Petrochemicals  Group 

Cities  Service  Oil  Co 

Clark  Chemical  Corp 

W.  A.  Cleary  Corp 

Clintwood  Chemical  Co 

Coastal  States  Petrochemical  Co 

Colgate-Palmolive  Co 

Collier  Carbon  5  Chemical  Corp 

Colloids,  Inc 

Columbia  Nitrogen  Corp 

Commercial  Products  Co. ,  Inc 

Commercial  Solvents  Corp 

Commonwealth  Oil  Refining  Co. ,  Inc 

Commonwealth  Petrochemicals,  Inc 

Conap,  Inc 

Conchemco,  Inc. : 

Kansas  City  Div 

Concord  Chemical  Co.,  Inc 

Consolidated  Papers,  Inc 

Continental  Chemical  Co 

Continental  Oil  Co 

Cook  Paint  5  Varnish  Co 

Cooperative  Farm  Chemicals  Association- 
Cooper  Polymers,  Inc 


245  Park  Ave.,  New  York,  NY  10017. 
1495  S.  nth  St.,  Louisville,  KY  40208. 
P.  0.  Box  1414,  Charlotte,  NC  28201. 
5S0  Broad  St.,  Newark,  NJ  07102. 
P.  0.  Box  9176,  Corpus  Christi,  TX  78408. 
800  Hoberg  St.,  Green  Bay,  WI  54305. 
P.  0.  Box  5008,  Houston,  TX  77012. 
3527  Smallman  St.,  Pittsburgh,  PA  15201. 
1715  W.  38th  St.,  Chattanooga,  TN   37409. 

P.  0.  Box  270,  Springfield,  OR  97477. 

Dubois  Tower,  Cincinnati,  OH  45202. 

4963  Manchester  Ave.,  St.  Louis,  MO  63110. 

1801  Lilly  St.,  St.  Louis,  MO  63110. 

P.  0.  Box  480,  Newport,  TN  37821. 

491  Columbia  Ave.,  Holland,  MI  49423. 

200  Pulaski  St.,  Newark,  NJ  07105. 

P.  0.  Box  26,  Nitro,  WV  25143. 

4040  W.  123d  St.,  Alsip,  IL  60658. 

P.  0.  Box  20687,  Greensboro,  NC  27420. 

3100  Golf  Rd.,  Rolling  Meadows,  IL  60008. 

P.  0.  Box  429,  Pryor,  OK  74361. 

200  Bush  St.,  San  Francisco,  CA  94120. 

5  Albany  St.,  Springfield,  MA  01101. 

9015  IV.  Maple  St.,  Milwaukee,  WI   53214. 

444  Saw  Mill  River  Rd. ,  Ardsley,  NY   10502. 

P.  0.  Box  1142,  Greensboro,  NC  27409. 

556  Morris  Ave.,  Summit,  NJ  07901. 

500  Jersey  Ave.,  New  Brunswick,  NJ  08903  and  West  St. 

Reading,  OH  45215. 
2408  Doyle  St.,  Greensboro,  NC  27406. 

P.  0.  Box  1522,  Lake  Charles,  LA  70601. 

Copperhill,  TN  37317. 

630  Glendale-Milford  Rd.,  Cincinnati,  OH  45215. 

60  Wall  St.,  New  York,  NY   10005. 

P.  0.  Box  300,  Tulsa,  OK  74102. 

131st  St.  f,  Kedzie  Ave.,  Blue  Island,  IL  60406. 

P.  0.  Box  710,  Somerset,  NJ  08873. 

4342  S.  Wolcoth  Ave.,  Chicago,  IL  60609. 

P.  0.  Drawer  521,  Corpus  Christi,  TX  78403. 

300  Park  Ave.,  New  York,  NY   10022. 

461  S.  Boyston,  Los  Angeles,  CA  90017. 

394  Frelinghuysen  Ave.,  Newark,  NJ  07114. 

P.  0.  Box  1483,  Augusta,  GA  30903. 

117  Ethel  Ave.,  Hawthorne,  NJ  07641. 

245  Park  Ave.,  New  York,  NY   10017. 

Petrochemical  Complex,  Ponce,  PR  00731. 

Petrochemical  Complex,  Ponce,  PR  00731. 

184  E.  Union  St.,  Allegany,  NY  14706. 

10000  Marshall  Dr.,  Lenoxa,  KS  66215. 

18th  5  Garfield  Sts.,  Kansas  City,  MO  64127. 

17th  f,  Federal  Sts.,  Camden,  NJ  08105. 

Wisconsin  Rapids,  WI  54494. 

270  Clifton  Blvd.,  Clifton,  NJ  07015. 

Park  Eighty  Plaza  East,  Saddle  Brook,  NJ  07662. 

P.  0.  Box  389.  Kansas  City,  MO  64141. 

P.  0.  Box  308,  Lawrence,  KS  66044. 

820  Woburn  St.,  Wilmington,  MA  01887. 


SYNTHETIC  OTiflNIC  CHEHICALS,  P7? 


TABLE  1.— Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers^ 

BY  COMPANY,  197?— CONTINUED 


Name  of  company 


Coopers  Creek  Chemical  Corp 

Copolymer  Rubber  6  Chemical  Corp 

Cosden  Oil  §  Chemical  Co 

Crest  Chemical  Corp 

Croda,  Inc 

Crompton   5  Knowles  Corp.,   Dyes   6  Chemical 

Div. 

Crosby  Chemicals,  Inc 

Crown  Central  Petroleum  Corp 

Crown  Metro,  Inc 

Crown  Zellerbach  Corp.,  Chemical  Products 

Div. 

Dan  River,  Inc 

Dart   Industries,    Inc.: 

Azetec  Chemicals  Div 

Rexene   Polymers   Co.    Div 

Synthetic  Products   Co.    Div 

Davies- Young  Co 

Dawe's    Laboratories,    Inc 

Degen   Oil   f,  Chemical    Co 

Dennis   Chemical  Co 

Depaul  Chemical  Co.,    Inc 

DeSoto,    Inc 

Detrex  Chemical   Industries,    Inc 

Dexter  Chemical   Corp 

Hysol   Div 

Midland  Div 

Diamond  Plastics,    Inc 

Diamond  Shamrock  Corp 

Dixie  Chemical   Co 

Dixie  Pine   Products  Co.,    Inc 

Dominion  Products,    Inc 

Dover  Chemical   Co 

Dow  Badische  Chemical  Co 

Dow  Chemical   Co 

Dow  Coming  Corp 

E.    I.   duPont  de  Nemours   5  Co.,    Inc 

Dye  Specialties,    Inc 

Eagle  Pitcher  Industries,    Inc.,   Rubber 
Products   Div. 

Eagle  River  Chemical  Corp 

Eastern  Color  5  Chemical  Co 

Eastman   Kodak  Co 

Tennessee  Eastman  Co.   Div 

Texas   Eastman  Co.    Div 

East  Shore  Chemical  Co.,    Inc 

Eastside  Chemical    Laboratory 

Elan  Chemical  Co 

Electro-Seal   Glasflex  Corp 

El  Paso  Products  Co 

Emery  Industries,  Inc 

Trylon  Chemicals  Div 

Emkay  Chemical  Co 

Endo  Laboratories,  Inc 

Enenco,  Inc 

Epoxylite  Corp 

Essential  Chemicals  Group 

Essex  International,  Inc.,  Electro- 
Mechanical  Div. 

Ethyl  Corp 

Evans  Chemetics,  Inc 


Office  address 


River  Rd. ,  W.  Conshohocken,  PA  19428. 
P.  0.  Box  2591,  Baton  Rouge,  LA  70821. 
P.  0.  Box  1311,  Big  Spring,  Tx  79720. 
225  Emmet  St.,  Newark,  NJ  07114. 
51  Madison  Ave.,  New  York,  NY  10010. 
500  Pear  St.,  Reading,  PA  19603. 

P.  0.  Box  460,  Picayune,  LA  39466. 
1  No.  Charlis  St.,  Baltimore,  MD  21201. 
12  Dudley  St.,  Providence,  RI  02901. 
Camas,  WA  98607. 


Danville,  VA  24541. 

555  Garden  St.,  Elyria,  OH  44035. 

W.  lis  Century  Rd. ,  Paramus ,  NJ  07657. 

1636  Wayside  Rd.,  Cleveland,  OH  44112. 

2700  Wagner  Place,  Maryland  Heights,  MO  63043. 
450  State  St.,  Chicago  Heights,  IL  60411. 

200  Kellogg  St.,  Jersey  City,  NJ  07305. 

2701  Papin  St.,  St.  Louis,  MO  63103. 

44-27  Purvis  St.,  Long  Island  City,  NY  11101. 

1700  S.  Mt.  Prospect  Ave.,  Des  Plaines,  IL  60018. 

14  331  Woodrow  Wilson,  Detroit,  MI  48232. 

845  Edgewater  Rd. ,  Bronx,  NY   10474. 

211  Franklin  St.,  Olean,  NY  14760. 

E.  Water  St.,  P.  0.  Box  620,  Waukegan,  IL  60085. 

6421  Paramount  Blvd.,  Long  Beach,  CA  90805. 

100  Superior  Ave.,  Cleveland,  OH  44114. 

3635  W.  Dallas  Ave.,  Houston,  TX  77019. 

P.  0.  Box  470,  Hattiesburg,  MS  39401. 

882  3d  Ave.,  Brooklyn,  NY  11232. 

W.  15th  and  Davis  Sts . ,  Dover,  OH  44622. 

P.  0.  Drawer  "D",  Williamsburg,  VA  23605. 

Hopkins  Bldg. ,  Midland,  MI   48640. 

P.  0.  Box  1592,  Midland,  MI  48640. 

DuPont  Bldg.,  Wilmington,  DE   19898. 

26  Journal  Sq.,  Jersey  City,  NJ  07306. 

P.  0.  Box  755,  Denton,  TX  76201. 

P.  0.  Box  665,  Marinette,  WI   54143. 

35  Livingston  St.,  Providence,  RI  02904. 

343  State  St.,  Rochester,  NY   14650. 

P.  n.  Box  511,  Kingsport,  TN  37662. 

P.  0.  Box  7444,  Longview,  TX  75601. 

1221  E.  Barney  Ave.,  Muskegon,  HI   49443. 

12880  NE  Bellevue-Redmond  Rd.,  Bellevue,  WA  98005 

268  Doremus  Ave.,  Newark,  NJ  07105. 

Stirling,  NJ  07980. 

P.  0.  Box  3986,  Odessa,  TX  79760. 

4300  Carew  Tower,  Cincinnati,  OH  45202. 

P.  0.  Box  628,  Mauldin,  SC  29662. 

319  2d  St.,  Elizabeth,  NJ  07206. 

1000  Stewart  Ave.,  Garden  City,  NY  11530. 

P.  0.  Box  398,  Memphis,  TN  38101. 

1901  Via  Buxton,  Anaheim,  CA  92806. 

28391  Essential  Rd. ,  Merton,  WI   53056. 

1601  Wall  St.,  Fort  Wayne,  IN  46804. 

330  S.  4th  St.,  Richmond,  VA  23217. 
90  Tokeneke  Rd.,  Darien,  CT  06820. 


APPENDIX  A 


TABLE  1.— Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers, 

BY    COMPANY,    1972— CONTINUED 


Name  of  company 


Office  address 


Exxon  Corp.,    Exxon  Chemical   Co.    U.S.A. 

FMC   Corp . : 

Fibers   Div 

Industrial  Chemical  Div 

Industrial  Chemical   Div.,   Organic 
Business  Group 

Niagara  Chemical   Div 

FRP  Co 

Fabricolor  Manufacturing  Corp 

Fairmount-Chemical  Co.,    Inc 

Far-Best  Corp.,   0.    L.    King  Div 

Famow,    Inc 

Felton  International,  Inc 

Ferro  Chemical  Corp. : 

Ferro  Chemical  Div 

Grant  Chemical  Div 

Fike  Chemicals,  Inc 

Fine  Organics,  Inc 

Finetex  Corp 

Firestone  Tire  5  Rubber  Co.: 

Firestone  Plastics  Co.  Div 

Firestone  SyTithetic  Rubber  5  Latex  Co. 
Div. 

First  Chemical  Corp 

Fisher  Chemical  Co.,  Inc 

Fleming  Laboratories,  Inc 

Florasynth  Laboratories,  Inc 

Foote  Mineral  Co 

Formica  Corp 

Foster  Grant  Co.  ,  Inc 

France,  Campbell  6  Darling,  Inc 

Freeman  Chemical  Corp 

Frisch  6  Co.,  Inc 

Fritzsche  Dodge  §  Olcott,  Inc 

H.  B.  Fuller  Co r 

Fuller- O'Brien  Corp 

GAF  Corp 

Chemical  Div 

Gane's  Chemical  Works,  Inc 

Genera]  Electric  Co 

Insulating  Materials  Dept 

Silicone  Products  Dept 

General  Foods  Corp.,  Maxwell  House  Div 

General  Latex  §  Chemical  Corp 

General  Mills  Chemicals,  Inc 

General  Plastics  Manufacturing  Co 

General  Tire  §  Rubber  Co.,  Chemical  Div 

P.  D.  George  Co 

George  A.   Jeffreys   §  Co 

Georgia-Pacific  Corp 

Bellingham  Div 

Getty  Oil  Co 

Gillette  Chemical  Co.  Div.  of  Gillette  Co. 
Gilman  Paint  §  Varnish  Co 


P.  0.  Box  32  72,  Houston,  TX  77001  and  Odenton, 
MD  21113. 


1617  John  F.  Kennedy  Blvd.,  Philadelphia,  PA  19103. 
633  3d  Ave.,  New  York,  NY  10017  and  Sawyer  Ave.  § 

River  Rd.,  Town  of  Tonawanda,  NY  14150. 
635  3d  Ave.,  New  York,  NY  10017. 

100  Niagara  St.,  Middleport,  NY  14105. 

P.  0.  Box  349,  Baxley,  GA  31513. 

24-1/2  Van  Houten  St.,  P.  0.  Box  2398,  Paterson. 

NJ  07505. 
117  Blanchard  St.,  Newark,  NJ  07105. 
640  Gilman  St.,  Berkeley,  CA  94710. 
77  Jacobus  Ave.,  S.  Kearney,  NJ  07032. 
599  Johnson  Ave.,  Brooklyn,  NY  11237. 

P.  0.  Box  46-349,  7050  Krick  Rd. ,  Bedford,  OH  44146. 

P.  0.  Box  263,  Baton  Rouge,  LA  70821. 

P.  0.  Box  546,  Nitro,  WV  25143. 

205  Main  St.,  Lodi ,  NJ  07644. 

418  Falmouth  Ave.,  Elmwood  Park,  NJ  07407. 

P.  n.  Box  699,  Pottstown,  PA  19464. 
381  W.  Wilbeth  Rd.,  Akron,  OH  44301. 

P.  0.  Box  1427,  Pascagoula,  MS  39567. 

5200  Paul  G.  Blazer  Memorial  Pkwy.,  Dublin,  OH  43216. 

P.  0.  Box  10373,  Charlotte,  NC  28201. 

900  Van  Nest  Ave.,  Bronx,  NY  10462. 

Route  100,  Exton,  PA  19341. 

120  E.  4th  St.,  Cincinnati,  OH  45202. 

289  N.  Main  St.,  Leominster,  MA  01453. 

209  N.  Michigan  Ave.,  Kenilworth,  NJ  07033. 

222  E.  Main  St.,  Port  Washington,  WI  53074. 

88  E.  11th  St.,  Paterson,  NJ  07524. 

76  9th  Ave.,  New  York,  NY  10011. 

2400  Kasota  Ave.,  St.  Paul,  MN  5S108. 

450  E.  Grand  Ave.,  S.  San  Francisco,  CA  94080. 

1228  Chestnut  St.,  Chattanooga,  TN  37402. 

P.  0.  Box  12,  Linden,  NJ  07036. 

535  5th  Ave.,  New  York,  NY  10017. 

1  Plastics  Ave.,  Pittsfield,  MA  01201  and  135  So. 

Second  St.,  Coshocton,  OH  43812. 
1  Campbell  Rd. ,  Schenectady,  NY  12306. 
Waterford,  NY  12188. 
1125  Hudson  St.,  Hoboken,  NJ  07030. 
666  Main  St.,  Cambridge,  MA  02139. 
4620  W.  77th  St.,  Mann,  MN  55435 

3481  S.  35th  St.,  Tacoraa,  WA  98409. 

1  General  St.,  Akron,  OH  44309. 

5200  N.  2d  St.,  St.  Louis,  MO  63147. 

P.  0.  Box  709,  Salem,  VA  24153. 

900  S.W.  5th  Ave.,  Portland,  OR  97240. 

P.  0.  Box  1236,  Bellingham,  WA  98225. 

Delaware,  DE  19706. 

3500  W.  16th  St.,  N.  Chicago,  IL  60064. 

W.  8th  and  Pine  Sts.,  Chattanooga,  TN  37401. 


SYNTHETIC  ORGflNlC  CHEMICALS.  1972. 


TABLE  1.— Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers, 
BY  company.  1972— Continued 


Name  of  company 


Givaudan  Corp 

Glidden  Durkee  Famous  Foods 

Glyco  Chemicals,  Inc 

B.  F.  Goodrich  Co.,  B.  F.  Goodrich  Chemical 
Co.  Div. 

Goodyear  Tire  5  Rubber  Co 

Gordon  Corp 

Gordon  Chemical  Co.,  Inc 

W.  R.  Grace  5  Co. : 

Agricultural  Chemical  Group 

Dewey  5  Almy  Chemical  Div.  Organic 
Chemicals 

Hatco  Chemical  Div 

Marco  Chemical  Div 

Polymers  S  Chemicals  Div 

Grain  Processing  Corp 

Great  American  Chemical  Corp 

Great  Lakes  Chemical  Corp 

Great  Western  Sugar  Co 

Guardsman  Chemical  Coatings,  Inc 

Gulf  Oil  Corp. ; 

Gulf  Adhesives 

Gulf  Oil  Chemicals  Co.  -  U.  S. 

Guth  Corp 

H  6  N  Chemical  Co 

Haag  Laboratories,  Inc 

C.  P.  Hall  Co.  of  Illinois 

Handschy  Chemical  Co.,  Farac  Oil  and 

Chemical  Div. 

Hanna  Chemical  Coatings  Corp 

Hardman,  Inc 

Harshaw  Chemical  Co.    Div.   of  Kewanee  Oil 

Co. 

Hart  Products  Corp 

Haveg  Industries,  Inc 

Hawkeye  Chemical  Co 

Henkel ,  Inc 

Hercor  Chemical  Corp 

Hercules,  Inc 

Heresite  5  Chemical  Co 

Heterochemical  Corp 

Hewitt  Soap  Co.,  Inc 

Hexagon  Laboratories,  Inc 

Hexcel  Corp.,  Rezolin  Div 

Hodag  Chemical  Corp 

Hoffmann- LaRoche,  Inc 

Hoffman-Taff,  Inc 

Hooker  Chemical  Corp 

Durex  Div 

Ruco  Div 

E.  F.  Houghton  6  Co 

Humphrey  Chemical  Co 

Philip  A.  Hunt  Chemical  Corp.,  Wayland 

Chemical  Div. 

Huntington  Laboratories,  Inc 

Husky  Industries,  Inc 

Hynson,  Westcott  §  Dunning,  Inc 

ICI  America,  Inc 

ITT  Rayonier,  Inc 

INDPOL- 


Office  address 


ino  Delawanna  Ave.,  Clifton,  NJ   07014. 
2333  Logan  Blvd.,  Chicago,  IL  60647. 
51  Weaver  St.,  Greenwich,  CT  06830. 
6100  Oak  Tree  Blvd.,  Cleveland,  OH  44131. 

1144  E.  Market  St.,  Akron,  OH  44313. 
300  S.  3d  St.,  Kansas  City,  KS  66118. 
88  Webster  St.,  Worcester,  MA  01603. 

P.  0.  Box  277,  Memphis,  TN  38101. 
Poisson  Ave.,  Nashua,  NH  03060. 


King  George  Post  Rd.,  Fords,  NJ 
1711  W.  Elizabeth  Ave.,  Linden, 
62  Whittemore  Ave.,  Cambridge 
1600  Oregon  St.,  Muscatine,  L 


08863. 
J  07036. 
02140. 
52761. 


MA 


650  Water  St.,  Fitchburg,  MA  01420. 
P.  0.  Box  2200,  West  Lafayette,  IN  47906. 
P.  0.  Box  5308,  Terminal  Annex,  Denver,  CO  80217. 
1350  Steele  Ave.,  S.W. ,  Grand  Rapids,  MI   49502,  and 
1350  S.  15th  St.,  Louisville,  KY  40210. 

632  No.  Cannon  Ave.,  Lansdale,  PA  19446. 
P.  0.  Box  2100,  Houston,  TX  77001. 
P.  0.  Box  302,  Naperville,  IL  60540. 

90  Maltese  Dr.,  Totowa,  NJ  07512. 
14010  S.  Seeley  Ave.,  Blue  Island,  IL  60406. 
7300  S.  Central  Ave.,  Chicago,  IL  60638. 
13601  S.  Ashland  Ave.,  Riverdale,  IL  60627. 

P.  0.  Box  147,  Columbus,  OH  43216. 

600  Cortlandt  St.,  Belleville,  NJ  07109. 

1945  E.  97th  St.,  Cleveland,  OH  44106. 

173  Sussex  St.,  Jersey  City,  NJ  07302. 

900  Greenback  Rd.,  Wilmington,  DE  19808. 

P.  0.  Box  899,  Clinton,  LA  52733. 

1301  Jefferson  St.,  Hoboken,  NJ  07030. 

Petrochemical  Complex,  Ponce,  PR  00731. 

910  Market  St.,  Wilmington,  DE   19899. 

822  S.  14th  St.,  Manitowoc,  WI   54220. 

Ill  E.  Hawthorne  Ave.,  Valley  Stream,  NY  11580. 

333  Linden  Ave.,  Dayton,  OH  45403. 

3536  Peartree  Ave..  Bronx,  NY   10475. 

20701  Nordhoff  St.,  Chatsworth,  CA  91311. 

7247  N.  Central  Park  Ave.,  Skokie,  IL  60076. 

324-424  Kingsland  St.,  Nutley,  NJ  07110. 

P.  0.  Box  1246  SSS,  Springfield,  MO  65805. 

MPO  Box  8,  Niagara  Falls,  NY   14302. 

Walck  Rd. ,  N.  Tonawanda,  NY  14121. 

P.  0.  Box  456,  Burlington,  NJ  08016. 

303  W.  Lehigh  Ave.,   Philadelphia,  PA  19133. 

Devine  St.,  North  Haven,  CT  0647  3. 

P.  0.  Box  0,  Lincoln,  RI   02865. 

P.  0.  Box  710,  Huntington,  IN  46750. 

62  Perimeter  Center  E. ,  Atlanta,  GA  30346. 

Charles  and  Chase  Sts . ,  Baltimore,  MD  21201. 

Concord  Pike  §  Murphy  Rd.,  Wilmington,  DE  19899. 

161  E.  42d  St.,  New  York,  NY   10017. 

8434  Rochester  Ave.,  Cucamonga,  CA  91730. 


APPENDIX  A 


T'iBLE  1. --Synthetic  organic  CHEf^icALs;  Alphabetical  directory  of  manufacturers, 

BY    COMPANY,    197?— CONTINUED 


Office  address 


Industrial  Dyestuff  Co 

Inland  Steel   Co. ,    Inland  Steel   Container 

Co. 
Inmont  Corp 

ABI   Div 

International   Flavors   §  Fragrances,    Inc-- 
Intemational  Minerals   §  Chemical  Corp — 

Interplastic  Corp '■ 

lonac  Chemical   Co.    Div.   of  Sybron  Corp — 
Ironsides   Resins,    Inc 

Jefferson  Chemical   Co.,    Inc 

Jenni son- Wright  Corp 

Andrew  Jergens  Co 

Jersey  State  Chemical  Co 

Jewel   Paint   S  Varnish  Co 1 

S.    C.   Johnson   5  Son,    Inc 

Jones -Blair  Co 

Jordan  Chemical  Co 

Kaiser  Aluminum  6  Chemical  Corp. : 

Kaiser  Agricultural   Chemicals   Div 

Kaiser  Chemical 

Kalama  Chemical   Co 

Kali  Manufacturing  Co 

Kay-Fries   Chemicals,    Inc 

Kelly-Moore   Paint   Co 

Kennecott  Copper  Corp.: 

Chino  Mines   Div 

Utah  Copper  Div 

Kerr-McGee  Chemical  Corp 

Keysor  Century  Corp 

Keystone  Chemurgic  Corp 

Keystone  Color  Works,    Inc 

Knapp  Products,    Inc 

Koch  Chemical   Co 

Kohler-McLister  Paint  Co 

H.    Kohnstamm  G  Co.,    Inc 

Koppers   Co.,    Inc 

Organic  Material  Div 

Roads  Materials  Div 

Krafto  Corp. : 

Humko  Products  Div 

Sheffield  Chemicals  Div 

Kyanize  Paints,  Inc 

Lakeside  Laboratories  Div.  of  Colgate- 
Palmolive  Co. 
Lake  States  Div.  of  St.  Regis  Paper  Co--- 

Lakeway  Chemicals  Inc 

LaMotte  Chemical  Products  Co 

Laurel  Products  Corp 

Leatex  Chemical  Co 

Lemke  Chemicals,  Inc 

Lever  Brothers  Co 

C.  Lever  Co.,  Inc 

Eli  Lilly  5  Co 

Lonza,  Inc 

Lubrizol  Corp 

M  and  T  Chemicals,  Inc 

Magnolis  Industries,  Inc.,  Milliken 
Chemical  Div. 


P.  0.  Box  4249,  E.  Providence,  RI   02914. 
4300  W.  130th  St.,  Chicago,  IL  60658. 

609  Lafayette  Ave.,  Hawthorne,  NJ  07506. 

5935  Milford  Ave.,  Detroit,  MI  48210. 

521  W.  57th  St.,  New  York,  NY  10019. 

IMC  Plaza,  Libertyville,  IL  60948. 

2015  NE.  Broadway  St.,  Minneapolis,  MN  55413. 

Birmingham,  NJ  08011. 

270  W.  Mound  St.,  Columbus,  OH  43216. 

P.  0.  Box  53300,  Houston,  TX  77052. 

P.  0.  Box  691,  Toledo,  OH  43694. 

2535  Spring  Grove  Ave.,  Cincinnati,  OH  45214. 

59  Lee  Ave.,  Haledon,  NJ  07508. 

345  N.  Western  Ave.,  Chicago,  IL  60612. 

1525  Howe  St.,  Racine,  WI  53403. 

2728  Proctor,  Dallas,  TX  75235. 

1830  Columbia  Ave.,  Folcraft,  PA  19032. 

P.  0.  Box  246,  Savannah,  GA  31402. 

P.  0.  Box  337,  Gramercy,  LA  70052. 

P.  0.  Box  427,  Kalama,  WA  98625. 

427  Moyer  St.,  Philadelphia,  PA  19125. 

360  Lexington  Ave.,  New  York,  NY  10017. 

1015  Commercial  St.,  San  Carlos,  CA  94070. 

Hurley,  MN  88043. 

P.  0.  Box  11299,  Salt  Lake  City,  UT  84111. 

P.  0.  Box  25861,  Oklahoma,  OK  73125. 

P.  0.  Box  308,  Saugus,  CA  91350. 

R.  D.  2,  Bethlehem,  PA  18017. 

151  W.  Gay  Ave.,  York,  PA  17403. 

187  Garibaldi  Ave.,  Lodi ,  NJ  07644. 

P.  0.  Box  2256,  Wichita,  KS  67201. 

1201  Osage  St.,  Denver,  CO  80201. 

161  Avenue  of  the  Americas,  New  York,  NY  10013. 

Koppers  Bldg.,  Pittsburgh,  PA  15219. 

Koppers  Bldg.,  Pittsburgh,  PA  15219. 

Koppers  Bldg.,  Pittsburgh,  PA  15219. 

P.  0.  Box  398,  Memphis,  TN  38101. 

2400  Morris  Ave.,  Union.  NJ  07083. 

2d  and  Boston  Sts . ,  Everett,  MA  02149. 

1707  E.  North  Ave.,  Milwaukee,  WI   53201. 

603  W.  Davenport  St.,  Rhinelander,  WI   54501. 

S025  Evanston  Ave.,  Muskegon,  MI  49443. 

Chestertown,  MD  21620. 

2600  E.  Tioga  St.,  Philadelphia,  PA  19134. 

2722  N.  Hancock  St.,  Philadelphia,  PA  19133. 

195-203  Main  St.,  Lodi,  NJ  07644. 

390  Park  Ave.,  New  York,  NY  10022. 

736  Dunks  Ferry  Rd.,  Comwells  Hgts,  PA  19020. 

307  E.  McCarty  St.,  Indianapolis,  IN  46206  and  G.P.O. 

Box  4388,  San  Juan,  PR  00936. 
22-10  Route  208,  Fair  Lawn,  NJ  07410. 
29400  Lakeland  Blvd.,  Wickliffe,  OH  44092. 

Woodridge  Rd.  f,  Randolph  Ave.,  P.  0.  Box  1104, 

Rahway,  NJ  07065. 
P.  0.  Box  817,  Inman,  SC  29349. 


SYNTHETIC  ORGANIC  CHEMICALS,  1P7? 


TABLE  1. --Synthetic  organic  chemicals;     Alphabetical  directory  of  manufacturers, 

BY    COMPANY,    197?— CONTINUED 


Name   of   company 


Office   address 


Magruder  Color  Co.,    Inc 

Mallinckrodt  Chemical  Works 

Washlne   Div 

Marathon  Horco  Co 

Marathon  Oil   Co.,   Texas   Refining  Div 

Marblette  Co 

Harden- Wi Id  Corp 

Marlowe-Van  Loan  Corp 

Martin-Marietta  Corp.: 

Sodyeco   Div 

Max  Marx  Color  5  Chemical  Co 

Masonite  Corp.,  Alpine  Chemical  Div 

Otto  B.  May,  Inc 

McCloskey  Varnish  Co 

McLaughlin  normley  King  Co 

Mead  Johnson  6  Co 

Merck  5  Co.,  Inc 

Merichem  Co 

Michigan  Chemical  Corp 

Midwest  Manufacturing  Corp 

Miles  Laboratories,  Inc.,  Marschall  Div 

Millmaster  Onyx  Corp.: 

A.  Gross  6  Co.  Div 

Millmaster  Chemical  Div. ,  Berkely 
Chemical  Dept. 

Onyx  Chemical  Co.  Div 

Refined- Onyx  Div 

Minnesota  Mining  5  Manufacturing  Co 

Minnesota  Paints,  Inc 

Miranol  Chemical  Co.,  Inc 

Mississippi  Chemical  Corp 

Mobay  Giemical  Co 

Mobil  nil  Com 

Mobil  Chemical  Co.: 

Chemical  Coatings  Div 

Industrial  Chemicals  Div 

Mona  Industries,  Inc 

Monochem,  Inc 

Monroe  Chemical  Co 

Monsanto  Co 

Bircham  Bend   Plant 

Chocolate   Bayou  Plant 

Plastics   Div 

Textiles   Div 

Montrose  Chemical   Corp.    of  California 

Mooney  Chemicals,    Inc 

Moretex  Chemical   Products,    Inc 

Morton   Chemical   Co.    Div.    of  Morton-Norwich 
Products,    Inc. 

Motomco,    Inc 

Murphy- Ph oenix  Co 

NL  Industries,  Inc 

Nalco  Chemical  Co 

National  Biochemical  Co 

National  Casein  Co 

National  Distillers  5  Chemical  Corp.,  U.S. 
Industrial  Chemicals  Co.  Div. 


1  Virginia  St.,  Newark,  NJ  07114. 

3600  N.  2d  St.,  St.  Louis,  MO  6?>147. 

165  Main  St.,  Lodi ,  NJ   07644. 

P.  0.  Drawer  C,  Dickinson,  TX  77539. 

P.  0.  Box  1191,  Texas  City,  TX  77590. 

37-31  30th  St.,  Long  Island  City,  NY  11101. 

500  Columbia  St.,  Somerville,  MA  02143. 

1511  Joshua  Circle,  High  Point,  NC  27261. 


P.  0.  Box  10098 

192  Coit  St.  ,  I: 

P.  0.  Box  2392, 

52  Amsterdam  St 

7600  State  Rd. , 

1715  SE.  5th  St 

2404  Penna.  St. 

126  E.  Lincoln  Ave.,  Railway 

1914  Haden  Rd. ,  Houston,  TX 


Charlotte,  NC  28201. 
vington,  NJ  07111. 
Gulfport,  MS  39503. 
,  Newark,  NJ  07105. 
Philadelphia,  PA  19136. 
,  Minneapolis,  MN  55414. 
Evansville,  IN  47721. 
NJ  07065 . 
77015. 


351  E.  Ohio  St.,  Chicago,  XL  60611. 

Oak  St.  and  Bluff  Rd. ,  Burlington,  lA  52601. 

1127  Myrtle  St.,  Elkhart,  IN  46514. 

652  Doremus  Ave.,  Newark,  NJ  07105. 
99  Park  Ave.,  New  York,  NY   10016. 

190  Warren  St.,  Jersey  City,  NJ  07302. 

624  Schuyler  Ave.,  Lyndliurst,  NJ  07071. 

3M  Center,  St.  Paul,  MN  55101. 

1101  S.  3d  St.,  Minneapolis,  MN  55415. 

277  Coit  St.,  Irvington,  NJ  07111. 

P.  0.  Box  388,  Yazoo  City,  MS  39194. 

Penn  Lincoln  Parkway,  W.  Pittsburgh,  PA  15205. 

P.  0.  Box  900,  Dallas,  TX  75221. 

1024  South  Ave.,  Plainfield,  NJ  07062. 

P.  0.  Box  26683,  Richmond,  VA  23261. 

65  E.  23d  St.,  Paterson,  NJ  07524. 

P.  0.  Box  488,  Geismar,  LA  70734. 

Saville  Ave.  at  4th  St.,  Eddystone,  PA  19013. 

2710  Lafayette  St.,  Santa  Clara,  CA  95052  and 

Lindbergh  Blvd.,  St.  Louis,  MO  63166. 
190  Grochraal  Ave.,  Indian  Orchard,  MA  01051. 
P.  0.  Box  711,  Alvin,  TX  77511. 
730  Worcester  St.,  Indian  Orchard,  MA  01101; 

5100  W.  Jefferson  Ave.,  Trenton,  MI  48183; 

River  Rd.,  Addyston,  OH  45001  and  P.  0.  Box 

Texas  City,  TX  77591. 
800  N.  Lindbergh  Blvd.,  St.  Louis,  MO  63156. 
500  S.  Virgil  Ave,,  Los  Agneles,  CA  90005. 
2301  Scranton  Rd.  ,  Cleveland,  OH  44113. 
314  W.  Henry  St.,  P.  0.  1799,  Spartanbury,  SC 

110  N.  Wacker  Dr.,  Chicago,  XL  60606. 

89  Terminal  Ave.,  Clark,  NJ   07066. 
9505  Cassius  Ave.,  Cleveland,  OH  44105. 

111  Broadway,  New  York,  NY  10006. 

180  N.  Michigan  Ave.,  Chicago,  IL  60601. 
3127  W.  Lake  St.,  Chicago,  IL  60612. 
601  W.  80th  St.,  Chicago,  IL  60620. 
99  Park  Ave.,  New  York,  NY   10016. 


APPEmiX  A 


TABLE  1.— Synthetic  organic  chemicals;  Alphabetical  directory  of  manufacturers. 
BY  company.  1972--Continued 


Name  of  company 


Office  address 


National  Hilling  §  Chemical  Co 

National  Petro  Chemical  Corp 

National  Starch  6  Chemical  Corp 

Nease  Chemical  Co.,  Inc 

Nepera  Chemical  Co.,  Inc 

Neville  Chemical  Co 

Nilok  Chemicals,  Inc 

Ninak,  Inc 

Nipro,  Inc 

Norac  Co. ,  Inc 

Mathe  Chemical  Co.  Div 

Norda,  Inc 

Norris  Paint  5  Varnish  Co 

North  American  Chemical  Co 

North  American  Rockwell  Corp 

Northern  Fine  Chemicals,  Inc 

Northern  Petrochemical  Co 

Northwestern  Chemical  Co 

Northwest  Petrochemical  Corp 

Norwich  Pharmacal  Co 

Nostrip  Chemical  Works,  Inc 

Noury  Chemical  Corp 

Novamont  Corp.,  Neal  Works 

Nyanza,  Inc 

0 ' Bri  en  Corp 

Occidental  Chemical  Co 

01 in  Corp 

Agricultural   Chemicals   Div 

Orbis   Products   Corp 

Organics ,    Inc 

Original   Bradford  Soap  Works,    Inc 

Owens-Coming  Fiberglas  Corp 

Oxirane  Chemical   Co 

Oxochem  Enterpri  se 

P-L  Biochemicals,    Inc 

PPG   Industries,    Inc 

PVO    International,    Inc.,    Chemical 

Specialties   Div. 

Pace  National   Corp 

Pacific   Resins    5  Chemicals,    Inc 

Pantasote  Co.    of  New  York,    Inc 

Parke  Davis   §  Co 

Passaic  Color  f,  Chemical   Co 

C.   H.    Patrick  5  Co.,    Inc 

Pears all  Corp 

Peck's  Products  Co 

Peerless  Oiemical  Co 

Pellon  Corp.,  Disogrin  Industries  Div- 

Pelron  Corp 

Pennsylvania  Industrial  Chemical  Corp- 

Pennsylvania  Refining  Co 

Pennwalt  Corp 

Lucidol  Div -- 

Perry  5  Derrick  Co.,    Inc 

Petrochemical   Investment  Corp 

Petrochemicals  Co.,    Inc 

Petro-Tex  Chemical   Corp 

Pfanstiehl   Laboratories,    Inc 

Pfister  Chemical,    Inc 

Pfizer,  Inc 


4601  Flat  Rock  Rd. ,  Philadelphia,  PA  19127. 

99  Park  Ave.,  New  York,  NY  10016. 

750  3d  Ave.,  New  York,  NY  10017. 

P.  0.  Box  221,  State  College,  PA  16801. 

Route  32,  Harriman,  NY  10926. 

Neville  Island,  P.  0.,  Pittsburgh,  PA  15225. 

2235  Langdon  Farm  Rd.,  Cincinnati,  OH  45230. 

301  S.  Harwood  St.,  Dallas,  TX  75221. 

P.  0.  Box  1483,  Augusta,  GA  30903. 

405  S.  Motor  Ave.,  Azusa,  CA  91703. 

169  Kennedy  Dr.,  Lodi ,  NJ  07644. 

475  inth  Ave.,  New  York,  NY  10001. 

P.  0.  Box  2023,  Salem,  OR  97308. 

19  Chestnut  St.,  Cambridge,  MA  02139. 

4501  Benefit  Ave.,  Ashtabula,  OH  44004. 

93  Main  St.,  Franklin,  NJ  07416. 

2.350  E.  Devon  Ave.,  Des  Plaines,  IL  60018. 

120  N.  Aurora  St.,  W.  Chicago,  IL  60185. 

P.  0.  Box  99,  Anacortes,  WA  98221. 

17  Eaton  Ave.,  Norwich,  NY  13815. 

P.  0.  Box  160,  Pedrichtown,  NJ  08067. 

2153  Lockport-Olcott  Rd. ,  Burt,  NY  14028. 

P.  0.  Box  189,  Kenova,  WV  25530. 

Maguno  Rd. ,  Ashland,  MA  01721. 

2001  W.  Washington  Ave.,  South  Bend,  IN  46627. 

P.  0.  Box  198,  Lathrop,  CA  95330. 

120  Long  Ridge  Rd.,  Stamford,  CT  06904. 

1120  Marshall  St.,  P.  0.  Box  991,  Little  Rock,  AR  72203 

475  10th  Ave.,  New  York,  NY  10008. 

7125  N.  Clark  St.,  Chicago,  IL  60628. 

200  Providence  St.,  W.  Wartdck,  RI  02893. 

Fiberglas  Tower,  Toledo,  OH  43659. 

10801  Choate  Rd.,  Houston,  TX  77062. 

P.  0.  Box  27,  King  George  Post  Rd.,  Fords,  NJ  08863. 

1037  W.  McKinley  Ave.,  Milwaukee,  WI  53205. 
1  Gateway  Center,  Pittsburgh,  PA  15222. 
416  Division  St.,  Boonton,  NJ  07005. 

500  7th  Ave.,  S.,  Kirland,  WA  98033. 

1754  Thome  Rd.,  Tacoma,  WA  93421. 

26  Jefferson  St.,  Passaic,  NJ  07055. 

Jos.  Carapau  at  the  River,  Detroit,  MI  48232. 

28-36  Paterson  St.,  Paterson,  NJ  07501. 

P.  0.  Box  2526,  Greensville,  SC  29602. 

P.  0.  Box  437,  Houston,  TX  77025. 

610  E.  Clarence  Ave.,  St.  Louis,  MO  63147. 

12416  Cloverdale  Ave.,  Detroit,  MI  48204. 

Perimeter  Rd.,  Municipal  Airport,  Manchaster,  NH  07103. 

7847  W.  47th  St.,  Lyons,  IL  60534. 

120  State  St.,  Clairton,  PA  15025. 

Union  Bank  Bldg. ,  Butler,  PA  16001. 

Three  Penn  Center,  Philadelphia,  PA  19102. 

1740  Militar\'  Rd.,  Buffalo,  NY  14240. 

2510  Highland  Ave.,  Norh'ood,  OH  45212. 

P.  0.  Drawer  F,  Channelview,  TX  77530. 

P.  0.  Box  2199,  Fort  Worth,  TX  76101. 

P.  n.  Box  25  84,  Houston,  TX  77001. 

1219  Glen  Rock  Ave.,  Waukegan,  IL  60085. 

Linden  Ave.,  Ridgefield,  NJ  07657. 

235  E.  42d  St.,  New  York,  NY   10017. 


SYNTHETIC  0PG/\NIC  CHEi'iICALS.  1°72 


TABLE  1.— Synthi^tic  organic  chemicals:     Alphabetical  directory  of  manufacturers, 

BY   company.    1972--CONTINUED 


Pharmachem  Corp 

Phillips   Petroleum  Co 

Phillips   Puerto  Rico  Core,    Inc 

Pierce  Chemical   Co 

Pilot  Chemical  Co 

Pioneer  Plastics  Corp 

Pitt-Consol  Chemical   Co 

Plastics   Engineering  Co 

Plastics   Manufacturing  Co 

Plex  Chemical   Corp 

Polak's   Frutal   Works,    Inc 

Polymer  Corp 

Polymer  Industries,    Inc 

Polyrez  Co.,    Inc 

Polyvinyl   Chemical   Ind.    Div.   of 

Beatrice  Foods   Co. 

Pratt   5  Lambert,    Inc 

Premier  Malt  Products,    Inc 

Premier  Petrochemicl   Co 

Princeton  Chemical   Research,    Inc 

Proctor  5  Gamble  Co.,   Proctor  fi  Gamble 

Mfg.    Co. 
Products  Research  5  Chemical   Corp., 

Chemical   S  Sealants   Div. 

Proctor  Chemical  Co.,    Inc 

Productol   Chemical   Co.,    Inc 

Publicker   Industries,    Inc 

Puerto  Rico  Chemical  Co.,    Inc 

Puerto  Rico  Olefins 

Purex  Corp.,    Ltd 

Washburn- Lans on  Co.  Div 


Office  address 


Quaker  Oats  Co 
K.  J.  Quinn  5  Co 


719  Stefko  Blvd.,  Bethlehem,  PA  18018. 
7472  Frank  Phillips  Bldg.,  Bartlesville,  0 
GPn  Box  4129,  San  Juan,  PR  00936. 
P.  0.  Box  117,  Rockford,  IL  61105. 
11756  Burke  St.,  Santa  Fe  Springs,  CA  906 
Pionite  Rd. ,  Auburn,  HE  04210. 
Park  Eighty  Plaza  East,  Saddle  Brook,  NJ 
1607  Geele  Ave.,  Sheboygan,  WI   53081. 
2700  S.  Westmoreland  Ave.,  Dallas,  TX  752 
1205  Atlantic  St.,  Union  City,  CA  94487. 
33  Sprague  Ave.,  Hiddletown,  NY   10940. 
2120  Fairmont  Ave.,  Reading,  PA  19603. 
Viaduct  Rd.,  Springdale,  CT  06879. 
S.  Columbia  St.,  Woodbury,  NJ  08096. 
730  Main  St.,  Wilmington,  HA  01887. 

P.  n.  Box  22,  Buffalo,  NY  14240. 

917  W.  Juneau  Ave.,  Milwaukee,  WI   53201. 

530  N.  Witter,  Pasadena,  TX  77501. 

P.  0.  Box  651,  Princeton,  NJ   08540. 

301  E.  6th  St.,  Cincinnati,  OH  45202. 

2912  Empire  Ave.,  Burbank,  CA  91504. 

P.  0.  Box  399,  Salisbury,  NC  28144. 
13215  E.  Penn  St.,  IVhittier,  CA  90602. 
1429  Walnut  St.,  Philadelphia,  PA  19102. 
P.  0.  Box  496,  Arecibo,  PR  00613. 
Firm  Delivery,  Ponce,  PR  00731. 
5101  Clark  Ave.,  Lakewood,  CA  90712. 
2258  Elston  Ave.,  Chicago,  IL  60614. 


Quaker  Chemical  Corp Lime  5  Elm  Sts .  ,  Conshohocken,  PA  19428. 

345  Merchandise  Mart  Plaza,  Chicago,  IL  60654. 
195  Canal  St.,  Maiden,  MA  02148. 


Inc- 


Inc- 


R.S.A.  Corp 

Rachel le  Laboratories, 

Racon,  Inc 

Raybestos-Manhattan,    Inc.,   Raybestos   Div- 

Red  Spot  Paint   5  Varnish  Co.,    Inc 

Reheis   Chemical   Co.    Div.    of  Armour 
Pharmaceutical  Co. 

Reichhold  Chemicals,    Inc 

Reilly  Tar  §  Chemical   Corp 


Reliance  Universal, 

Resin   Div 

Remington  Arms  Co., 

Resyn   Co3rp 

Rhodia,    Inc 

Richardson  Co 


Inc.  of  Texas- 


Ridgway  Color  5  Chemical- 
Riker  Laboratories,  Inc., 

Rilsan  Corp 

F.  Ritter  5  Co 

Riverdale  Chemical  Co 

Robeco  Chemicals,  Inc 

Roehr  Chemicals,  Inc 

Rogers  Corp 

Rohm  5  Haas  Co 


Sub.  of  3M  Co- 


690  Sawmill  River  Rd. ,  Ardsley,  NY  10502. 

700  Henry  Ford  Ave.,  Long  Beach,  CA  90801. 

P.  0.  Box  198,  6040  S.  Ridge  Rd. ,  Witchita,  KS  67201. 

74  E.  Main  St.,  Stratford,  CT  06497. 

966  E.  Columbia  St.,  Evansville,  IN  47708. 
325  Snyder  Ave.,  Berkeley  Heights,  NJ  07922. 

525  N.  Broadway,  White  Plains,  NY  10602. 

1615  Merchants  Bank,  11  S.  Meridan  St.  Indianapolis, 

IN  46204. 
6901  Cavalcade  St.,  Houston,  TX  77001. 
4730  Crittenden  Dr.,  Louisville,  KY  40221. 
939  Bamum  Ave.,  Bridgeport,  CT  06602. 
1401  W.  Blancke  St.,  Linden,  NJ  07036. 
120  Jersey  Ave.,  New  Brunswick,  NJ  08903. 
2708  Lake  St.,  Melrose  Park,  IL  60160  and  345  Morgan 

Lane,  West  Haven,  CT  06516. 

75  Front  St.,  Ridgway,  PA  15853. 

19901  Nordhoff  St.,  Northridge,  CA  91324. 

139  Harristown  Rd. ,  Glen  Roc,  NJ  07452. 

4001  Goodwin  Ave.,  Los  Angeles,  CA  90039. 

220  E.  17th  St.,  Chicago  Heights,  IL  60411. 

51  Madison  Ave.,  New  York,  NY   10010. 

52-20  37th  St.,  Long  Island  City,  NY  11101. 

Main  St.,  Rogers,  CT  06263. 

Independence  Mall  West,  Philadelphia,  PA  19105. 


rtPf'ENDIX  A 


TABLE  1. —Synthetic  organic  chemicals:     Alphabetical  directory  of  manufacturers, 

BY    COMPANY,    .T^Z?— CONTINUED 


Name  of  company 


Office   address 


Rubicon  Chemicals,    Inc 

SCM  Corp.,   Glidden-Durkee  Div 

Safeway  Stores,    Inc 

Salem  Oil   5  Grease  Co 

Salsbury  Laboratories 

Sandoz,    Inc.,   Sandoz  Color  5  Chemical   Di\ 

Sartomer  Industries,    Inc 

Schenectady  Chemicals,    Inc 

Scher  Bros.,    Inc 

R.    P.   Scherer  Com 

Schering  Corp 

Scholler  Bros.,    Inc 

Scientific  Protein   Labs.,    Inc 

Scott   Paper  Co 

Seaboard  Chemicals,    Inc 

G.    D.   Searle  5  Co 

Seydel-Woolley  §  Co.,    Inc 

Shakespeake  Co. ,    Industrial   Products   Div- 

Shanco  Plastics   5  Chemicals,    Inc 

Shell   5  Commonwealth  Chemicals,    Inc 

Shell   nil   Co 

Shell   Chemical   Co.    Div 

Shepherd  Chemical   Co 

Sherwin-Williams  Co 

George  F.   Siddall  Co.,    Inc 

Simpson  Timber  Co 

Sinclair- Koppers   Co 

Sinclair- Koppers   Chemical  Co 

Sinclair  Paint  Co.,   Div.    of  Insilco  Corp- 

Sipers   Chemical   Coatings   Co 

Skelly  Oil  Co 

G.  Frederick  Smith  Chemical  Co 

Smith,  Kline  5  French  Laboratories 

Sobin  Chemicals,  Inc.,  Montrose  Chemical 

Div. 

Solar  Chemical  Corp 

Soluol  Chemical   Co.,    Inc 

Solvent   Chemical   Co.,    Inc 

Sou-Tex  Chemical  Co.,    Inc 

Southeastern  Adhesives 

Southern  Chemical   Products   Co 

Southern  Sizing  Co 

Spaulding  Fibre  Co.,    Inc 

E.    R.    Squibb   6   Sons,    Inc 

A.    E.   Staley  Manufacturing  Co 

Staley  Chemicals  Div 

Textile  Div 

Stamford  Chemical  Industries 

Standard  Brands,  Inc.,  Clinton  Com 

Processing  Co.  Div. 
Standard  Brands  Chemical  Industries,  Inc- 

Standard  Chlorine  of  Delaware,  Inc 

Standard  Oil  Co.  of  California,  Chevron 

Chemical  Co. 

Standard  Oil  Co.  of  Ohio 

Stange  Co 


P.  0.  Box  517,  Geismar,  LA  70734. 

900  Union  Commerce  Bldg. ,  Cleveland,  OH  44115. 

8390  Capwell  Dr.,  Oakland,  CA  94604. 

60  Grove  St.,  Salem,  MA  01970. 

2000  Rockford  Rd. ,  Charles  City,  lA  S0616. 

P.  0.  Box  357,  Fair  Lawn,  NJ  07410  and  Route  No.  10, 

P.  0.  Box  11,  E.  Hanover,  NJ  07936. 
P.  0.  Box  56,  Essington,  PA  19029. 
P.  0.  Box  1046,  Schenectady,  NY  12301. 
P.  0.  Box  538,  Allwood  Station,  Clifton,  NJ  07012. 
9425  Grinnell  Ave.,  Detroit,  MI  48213. 
1011  Morris  Ave.,  Union,  NJ  07083. 

Collins  and  Westmoreland  Sts . ,  Philadelphia,  PA  1913 
P.  0.  Box  1409,  Madison,  WI   53701. 
Oconto  Falls,  WI  54154. 
30  Foster  St.,  Salem,  MA  01970. 
P.  0.  Box  5110,  Chicago,  IL  60680. 
762  Marietta  Blvd.,  NW.,  Atlanta,  GA  30318. 
P.  0.  Box  246,  Columbia,  SC  29202. 
Ill  Wales  St.,  Tonawanda,  NY  14150. 
Petrochemical  Complex,  Ponce,  PR  00731. 
P.  0.  Box  2463,  Houston,  TX  77001. 

One  Shell  Plaza,  P.  0.  Box  2463,  Houston,  TX  77001. 
4900  Beech  St.,  Cincinnati,  OH  45212. 
101  Prospect  Ave.,  NW  Cleveland,  OH  44101. 
P.  0.  Box  925,  Spartanburg,  SC  29301. 
2301  N.  Columbia  Blvd.,  Portland,  OR  97217. 
900  Koppers  Bldg.,  Pittsburgh,  PA  15219. 
9822  La  Porte  Freeway,  Houston,  TX  77012. 
3960  E.  Washington  Blvd.,  Los  Angeles,  CA  90023. 
P.  0.  Box  13090,  Pittsburgh,  PA  15243. 
P.  0.  Box  1650,  Tulsa,  OK  74102. 
867  McKinley  Ave.,  Columbus,  OH  43223. 
1500  Spring  Garden  St.,  Philadelphia,  PA  19101. 
100  Listen  Ave.,  Newark,  NJ  07105. 

P.  0.  Box  90,  Leominster,  MA  01453. 

Green  Hill  and  Market  Sts.,  W.  Warwick,  RI  02893. 

335-341  Commercial  St.,  Maiden,  MA  02148. 

E.  Cataivba  Ave.,  Mount  Holly,  NC  28120. 

P.  0.  Box  791,  Lenoir,  NC  28645. 

P.  0.  Box  205,  Macon,  GA  31202. 

P.  0.  Box  90987,  East  Point,  GA  30344. 

310  Wheeler  St.,  Tonawanda,  NY  14150. 

Georges  Rd.,  Brunswick,  NJ  08903. 

2200  Elorado  St.,  Decatur,  IL  62525. 

320  Schu>'ler  Ave.,  Kearny,  NJ  07032. 

6301  St.  John  Lane,  Charlotte,  NC  28210. 

4300  Carew  Towers,  Cincinnatti ,  OH  45202. 

1251  Beaver  Channel  Parkway,  Clinton,  lA  52733. 

P.  0.  Drawer  K,  Dover,  DE  19901. 

1035  Belleville  Turnpike,  Kearny,  NJ  07032. 

200  Bush  St.,  San  Francisco,  CA  94120. 

Midland  Bldg.,  Cleveland,  OH  44115. 
342  N.  Western  Ave.,  Chicago,  IL  60612. 


552-743  0-74-17 


SYNTHETIC  nRG'\NIC  CHE^IICALS,  1972- 


TABLE  1.— Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers 
BY  company.  1972— Continued 


Name  of  company 


Stauffer  Chemical   Co.: 

Agricultural  Div 

Calhio  Chemicals,  Inc.  Div 

Industrial  Div 

Plastics  Div 

Specialty  Chemical  Div 

Specialty  Chemical  Div. ,  Benzol 

Products. 
SWS  Silicones  Div 

Stepan  Chemical  Co 

National  Polycheraicals  Div 

Sterling  Drug,  Inc. : 

Glenbrook  Laboratories  Div 

Hilton-Davis  Chemical  Co.  Div 

Thomasset  Colors  Div 

Winthrop  Laboratories  Div-"- 

Sterwin  Chemicals,  Inc 

Story  Chemical  Corp.,  Ott  Div 

Styrochem  Corp 

Sugar  Beet  Products  Co 

Sun  Chemical  Corp 

Sunkist  Growers,  Inc 

Sun  Oil  Co 

Sun  Olin  Chemicl  Co 

Suntide  Refining  Co 

Tanatex  Chemical  Corp 

Charles  S.  Tanner  Co 

Teknor  Apex  Co 

Tenneco  Chemicals,  Inc 

Cal/Ink  Div 

Tenneco  Oil  Co 

Terra  Chemicals  International,  Inc 

Texaco,  Inc 

Texas  Alkyls,    Inc 

Texas-U.S.   Chemical  Co 

Tex  Chem  Co.,   Inc 

Texize  Chemicals,    Inc 

Text il ana  Corp 

Textllana  Nease,    Inc 

Textron,    Inc.,   Spencer  Kellogg  Div 

Thiokol   Chemical   Corp 

Thomason    Industries,    Inc.,    Southern  Resin 

Div. 
Thompson-Hayward  Chemical   Co 

Tizon  Chemical   Corp 

Toms   River  Chemical   Corp 

Trade   Enterprises,    Inc 

Arthur  C.   Trask  Co 


Office  address 


636   California  St. 

636   California  St. 

636  California  St. 

636  California  St.,   San  Francisco 

636  California  St.,    San  Francisco 

Meadow   Rd.,    Edison 


San  Francisco,  CA 
San  Francisco,  CA 
San  Francisco,   CA 


08817. 


94119 
94119 
94119 
94119 
94119 


636  California  St.,  San  Francisco,  CA  94119. 

RR  #1,  Elwood,  IL  60421  and  100  West  Hunter  Ave., 

Maywood,  NJ  07607. 
51  Eames  St.,  Wilmington,  MA  01887. 

90  Park  Ave.,  New  York,  NY  10016. 

2233  Langdon  Farm  Rd. ,  Cincinnati,  OH  45237. 

120  Lister  Ave.,  Newark,  NJ  07105. 

90  Park  Ave.,  New  York,  NY   10016. 

Military  Rd. ,  Rothschild,  WI   54474. 

500  Agard  Rd.,  Muskegon,  MI  49945. 

Petrochemical  Complex,  Ponce,  PR  00731. 

P.  0.  Box  1387,  Saginaw,  MI   48605. 

441  Tompkins  Ave.,  Staten  Island,  NY  10305  and 

P.  0.  Box  70,  Chester,  SC  29706. 
P.  0.  Box  7888,  Valley  Annex,  Van  Nuys ,  CA  91409. 
240  Radnor-Chester  Rd. ,  St.  Davids,  PA  19087. 
P.  0.  Box  F,  Claymount,  DE   19703. 
P.  0.  Box  2608,  Corpus  Christi ,  TX  78403. 

P.  0.  Box  388,  Lyndhurst,  NJ  07071. 

1305  Barcelona  Dr.,  Donaldson  Center,  Greensville,  SC 

29606. 
505  Central  Ave.,  Pawtucket,  RI  02662. 
Park  Eighty  Plaza  West-One,  Saddle  Brook,  NJ  07662. 
711  Camelia  St.,  Berkeley,  CA  94710. 
P.  0.  Box  2511,  Houston,  TX  77001. 
507  6th  St.,  Sioux  City,  lA  51121. 
135  E.  42d  St.,  New  York,  NY  10017. 
P.  0.  Box  600,  Deer  Park,  TX  77536. 
P.  0.  Box  667,  Port  Neches,  TX  77651. 
20-21  IVagaraw  Rd.  ,  Fair  Lawn,  NJ  07410. 
P.  0.  Box  368,  Greenville,  SC  29602. 
12607  Cerise  Ave.,  Hawthorne,  CA  90250. 
12607  Cerise  Ave.,  Hawthorne,  CA  90250. 
120  Delaware  Ave.,  Buffalo,  NY  14240. 
P.  0.  Box  27,  Bristol,  PA  19007. 
P.  0.  Drawer  1600,  Fayetteville.  NC  29302. 

5200  Speaker  Rd. ,  Kansas  City,  MO  66110  and 

2  E.  Madison  St.,  Waukegan,  IL  60085. 
Locktown  Rd.,  Flemington,  NJ  08822. 
P.  0.  Box  71,  Toms  River,  NJ  08753. 

Ketometer  77.5,  P.  0.  Box  296,  Humacao, 


State  Road  3, 

PR  00661. 
P.  0.  Box  134 


Argo,  IL  60501. 


APPEmiX  A 


TABLE  1. --Synthetic  organic  chemicals:  Alphabetical  directory  of  manufacturers^ 
BY  company,  1972--CoNTinuED 


Name  of  company 


Office  address 


Triad  Chemical 

Troy  Chemical  Co 

Joseph  Turner  S  Co 

USS  Agri- Chemicals  Div  of  U.S.  Steel  Corp- 

USS  Chemicals  Div.  of  U.S.  Steel  Corp 

Paul  Hulich  6  Co.,  Inc 

Ungerer  S  Co 

Union-Camp  Corp 

Harchem  Div 

Union  Carbide  Corp 

Union  Oil  Co.  of  California 

Uniroyal,  Inc.,  Chemical  Div 

United  Chemical  Corp.  of  Norwood 

United  Chemical  Products  Corp 

United- Erie,  Inc 

United  Merchants  5  Manufacturers,  Inc., 

Roma  Chemical  Div. 

U.S.  Borax  Research  Corp 

U.S.  Industries,  Inc.,  E.  Helman  Co.  Div-- 

U.S.  Oil  Co 

U.S.  Pipe  §  Foundry  Co 

U.S.  Plywood  WCM  Operations,  Shasta  Area-- 

Universal  Chemicals  Corp 

Universal  Oil  Products  Co 

UOP  Chemical  Div 

Upjohn  Co 

Fine  Chemical  Div 

Valchem  Chemical  Div.  of  United  Merchants 

§  Manufacturers,  Inc. 

Valentine  Sugars,  Inc 

Valley  Nitrogen  Producers,  Inc 

Van  De  Mark  Chemical  Co.,  Inc 

Vanderbilt  Chemical  Corp 

Van  Dyk  5  Co.,  Inc 

Velsicol  Chemical  Corp 

Ventron  Corp 

Wood  Ridge  Chemical 

Vermilye-Bell 

Vineland  Chemical  Co 

Virginia  Chemicals,    Inc 

Vistron  Corp 

Silraar  Div 

Vitamins ,  Inc 

Vulcan  Materials  Co.,  Chemicals  Div 

Wamer-Jenkinson  Manufacturing  Co 

West  Agro-Chemicals,  Inc 

West  Coast  Adhesives  Co 

Westinghouse  Electric  Corp.,  Industrial 
Plastics  Div.,  Chemical  Products  Plant. 

Westvaco  Corp.,  Polychemicals  Dept 

Weyerhaeuser  Co 

White  8  Bagley  Co 


P.  0.  Box  310,  Donaldsonville,  LA  70346. 

One  Avenue  L,  Newark,  NJ  07105. 

P.  0.  Box  88,  Ridgefield,  NJ  07657. 

30  Pryor  St.  S.W.  Atlanta,  GA  30301. 

600  Grant  St.,  Rm.  2880,  Pittsburgh,  PA  1S219. 

90  West  St.,  New  York,  NY  10006. 

161  Avenue  of  the  Americas,  New  York,  NY   10013. 

P.  0.  Box  6170,  Jacksonville,  Fl  32205. 

P.  0.  Box  220,  Dover,  NJ  44622. 

270  Park  Ave.,  New  York,  NY   10017. 

P.  0.  Box  7600,  Los  Angeles,  CA  90051. 

Emic  Bldg.,  Naugatuck,  CT  06770. 

P.  n.  Box  367,  Endicott  St.,  Norwood,  MA  02062. 

York  and  Colgate  Sts.,  Jersey  City,  NJ  07302. 

438  Huron  SE.,  Erie,  PA  16512. 

749  Quequechan  St.,  Fall  River,  MA  02721. 

3075  Wilshire  Blvd.,  Los  Angeles,  CA  90005. 

P.  0.  Box  5129,  Akron,  OH  44313. 

P.  0.  Box  4228,  E.  Providence,  RI  02914. 

3300  1st  Ave.,  N. ,  Birmingham,  AL  35202. 

P.  0.  Box  2713,  Redding,  CA  96001. 

1224  Mendon  Rd. ,  Ashton,  RI  02864. 

70  UOP  Plaza,  Algonquin  8  Mt .  Prospect, 

Des  Plains,  IL  60018. 
State  Highway  17,  E.  Rutherford,  NJ  07073. 
7000  Portage  Rd. ,  Kalamazoo,  MI  49001. 
410  Sackett  Point  Rd.,  North  Haven,  CT  06473. 

1407  Broadway,  New  York,  NY  10018. 

726  IVhitney  Bldg.,  New  Orleans,  LA  70130. 

1221  Van  Ness  Ave.,  Fresno,  CA  93721. 

N.  Transit  Rd.  ,  Lockport ,  NY  14094. 

33  Taylor  Ave.,  Bethel,  CT  06801. 

Main  5  Williams  Sts.,  Belleville,  NJ  07109. 

341  E.  Ohio  St.,  Chicago,  IL  60611. 

12-16  Congress  St.  Beverly,  MA  01915. 

Park  Place  East,  Wood  Ridge,  NJ  07075. 

21707  Bothell  Way,  Bothell,  WA  98011. 

W.  tVheat  Rd.  ,  Vineland,  NJ  08360. 

3340  W.  Norfolk  Rd.,  Portsmouth,  VA  23703. 

Midland  Bldg.,  Cleveland,  OH  44115. 

12333  S.  Van  Ness  Ave.,  Hawthorne,  CA  90250. 

401  N.  Michigan  Ave.,  Suite  2730,  Chicago,  IL  60611. 

P.  0.  Box  545,  Wichita,  KS  67201. 

2526  Baldwin  St.,  St.  Louis,  MO  63106. 
501  Santa  Fe,  Kansas  City,  HO  64105. 
11104  NW.  Front  .Ave.,  Portland,  OR  97231. 
Manor,  PA  15665. 

P.  0.  Box  5207,  N.  Charleston,  SC  29406. 
118  S.  Palmetto  Ave.,  Marshfield,  WI  54449. 
P.  0.  Box  706.  Worcester,  MA  01613. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 


TABLE  1,--Synthetic  organic  chemicals:     Alphabetical  directory  of  manufacturers, 

BY  COMPANY,  1972--CoNTINUED 


Identi- 
fication 
code 

Name  o£  company 

Office  address 

IVHI 
l«HL 

APT 
IfflC 
IWW 
WIG 
WLN 

WIL 

WM 

WTC 

WAW 

WON 

WBC 

WCL 

mc 
\m 

YAW 

White  6  Hodges,  Inc 

576  Lawrence  St.,  Lowell,  MA  01852. 

19  N.  Railroad  St.,  Myerstovm,  PA  17067. 

3134  California  St.,  NE.,  Minneapolis,  MN  55426. 
3540  Aero  Ct.,  San  Diego,  CA  92123. 
62  Alford  St.,  Boston,  MA  02129. 
P.  0.  Box  506,  Charlotte,  NC  28201. 
P.  0.  Box  66,  Wilmington,  DE   19  899. 

4221  S.  Western  Blvd.,  Chicago,  IL  60609. 

Jackson  and  Swanson  Sts.,  Philadelphia,  PA  19148. 

P.  0.  Box  305,  Paramus,  NJ  07652. 

108  Spring  St.,  Everett,  MA.   02149. 

176  Sunnyside  Ave.,  Woonsocket,  RI  02895. 

Halls  Mills  Rd.,  Freehold,  NJ  07728. 

Acme  Station,  Riegelwood,  NC  28456. 

P.  0.  Box  1087,  Colorado  Springs,  CO  80901. 

P.  0.  Box  8299,  Paoli,  PA  19101. 

2731  Boston  St.,  Baltimore,  MD  21224. 

Iftiittaker  Corp. : 

Mol  Rez  Div 

Wica  Chemicals,  Inc 

Wilson  Pharmaceutical  f,  Chemical  Corp.: 
Wilson  Laboratories  Div 

Witco  Chemical  Co.,  Inc 

W.  A.  Wood  Co 

Woonsocket  Color  5  Chemical  Co 

Wright  Chemical  Co 

Wycon  Chemical  Co 

Wyeth  Laboratories,  Inc.,  Wyeth  Laboratories 
Div.  of  American  Home  Products  Corp. 

J.  S.  Young  Co.,  Young  Aniline  Works  Div 

257 


APPENDIX  B 


U.S.  IMPORTS  OF  BENZENOID  CHEMICALS  AND  PRODUCTS 

U.S.  general  imports  of  benzenoid  chemicals  and  products  entered  under 
the  Tariff  Schedules  of  the  United  States  (TSUS) ,  schedule  4,  part  1,  subparts 
B  and  C  are  analyzed  by  the  Tariff  Commission  annually  and  published  in  detail 
in  a  separate  report.^   General  imports  of  benzenoid  items  entered  in  parts 
IB  and  IC  totaled  322.0  million  pounds  with  a  foreign  invoice  value  of  $246.7 
million  in  1972  compared  with  219.5  million  pounds  with  a  foreign  invoice 
value  of  $185.0  million  in  1971. 

Benzenoid  products  that  are  "competitive"  with  similar  domestic  products, 
because  they  accomplish  results  substantially  equal  to  those  accomplished  by 
the  similar  domestic  product  when  used  in  substantially  the  same  manner,  are 
subject  to  a  special  basis  of  valuation  for  customs  purposes  known  as  the 
"American  selling  price."  If  "noncompetitive,"  the  benzenoid  products  are 
valued  for  customs  purposes  on  the  basis  of  the  "United  States  value."  The 
essential  difference  between  these  two  values  is  that  "American  selling  price" 
is  based  on  the  wholesale  price  in  the  United  States  of  the  "competitive" 
domestic  product,  whereas  "United  States  value"  is  based  on  the  wholesale  price 
in  the  United  States  of  the  imported  product  less  most  of  the  expenses  incurred 
in  bringing  the  product  to  the  United  States  and  selling  it.   When  neither  of 
these  two  valuation  bases  applies,  then  the  "export  value,"  "foreign  value,"  or 
"constructed  value"  is  used  as  the  valuation  basis  under  section  402  or  402a 
Tariff  Act  of  1930,  as  amended.   The  competitive  status  of  benzenoid  imports  in 
1972  is  shown  in  table  2. 

Industrial  organic  chemicals  that  are  entered  under  part  IB  consist  chiefly 
of  benzenoid  intermediates  and  small  quantities  of  acyclic  compounds  which  are 
derived  in  whole  or  in  part  from  benzenoid  compounds.  Also  included  are  mixtures 
and  small  quantities  of  finished  products  not  specially  provided  for  in  part  IC 
(e.g.,  rubber-processing  chemicals).   In  terms  of  value,  45.0  percent  of  all  the 
benzenoid  imports  under  part  IB  in  1972  came  from  West  Germany;  21.2  percent, 
from  Japan;  9.6  percent,  from  Switzerland;  and  6.6  percent  from  Italy. 

Finished  organic  chemical  products  entered  under  part  IC  include  dyes, 
pigments,  medicinals,  flavor  and  perfume  materials,  pesticides,  plastics  materials, 
and  certain  other  specified  products.   In  terms  of  value,  37.2  percent  of  all 
finished  benzenoid  imports  under  part  IC  in  1971  came  from  West  Germany;  19.6 
percent,  from  Switzerland:  15.7  percent,  from  the  United  Kingdom;  and  11.5  percent 
from  Japan. 

^  Imports  of  Benzenoid  Chemicals  and  Products,    1972,   TC  Publication  601,  1973 
[processed] . 


SYNTHETIC  ORGANIC  CHEMICALS,  1972 


TABLE  2.— Benzenoid  chemicals  and  products;     Summary  of  U,S,  general  imports  entered  under 
Schedule  ^j  Parts  IB  and  IC  of  the  TSUS.  and  analysis  by  competitive  status.  1972 


Part   and  competitive  status 


Number 
of 
items 


Quantity 


Percent 
of  total 
quantity 


Foreign 
invoice 
value 


Percent  of 
foreign 
value 


Unit 
foreign 
value 


Schedule  4,  Part  IB 

Total' 

Competitive: 

Duty  based  on  ASP^ 

Noncompetitive: 

Duty  based  on  U.S.    value 

Duty  based  on  export   value 

Competitive  status  not    available 

Schedule  4,    Part   IC 

Total' 

Competitive: 

Duty  based  on  ASP^ 

Noncompetitive: 

Duty  based  on  U.S.    value 

Duty  based  on  export  value 

Competitive  status  not   available 

Summary   (Schedule  4,   Parts   IB  and  IC) 

Total' 

Competitive : 

Duty  based  on  ASP^ 

Noncompetitive: 

Duty  based  on  U.S.   value 

Duty  based  on  export  value 

Competitive  status  not   available 


1,258 
131 


1,50.S 
183 


1,000 
pounds 


19,583 
28,423 


135,838 


33,011 
17,135 


52,594 
45,558 


1,000 
dollars 


10.5 
15.3 


21,272 
11,556 


155,271 


58,256 


71,775 
20,078 


114,859 


93,047 
31,634 


46.2 
12.9 


Per 
pound 


1.09 
.41 


2.17 
1.17 


'   Detail  may  not  add  to  total  due  to  rounding. 
American  selling  price. 

Source:     Compiled  by  the  U.S.   Tariff  Commission  from  records   of  the  U.S.    Bureau  of  Customs. 

Note;--The  totals   shown   in  this   table  differ  from  those  given  in  the  official  statistics  of  the  U.S.  Department 

of  Commerce   chiefly  because   of  differences   in   coverage  and  in  the  methods   used  in  compiling  the  data.  In  general, 

the  statistical   coverage  in  1972  varies   from  a  low  of  74  percent  for  drugs   and  flavors   and  perfumes  to  almost 
complete   coverage  for  intermediates,    dyes,   and  pigments. 


APPEND IX  C 
TABLE  3.— Cyclic  intermediates;  Glossary  of  synonymous  names 


Common  name 


Standard  (Chemical  Abstracts)  na 


1,2, 4- Acid 

Acid  yellow  9 

p-Aminobenzenesulfonic  acid — 

Amino  G   acid 

Amino   I   acid 

Amino  R  salt 

Aniline  oil 

Anthraflavic  acid 

Anthrarufin 

Benzal   chloride 

Benzan  throne 

Benzotrichoride 

Bisphenol  A 

B.O.N 

Bromobenz an throne 

Broenner's    acid 

C  acid 

Chlorobenzanthrone 

Chromotropic  acid 

Chrysazin 

2-Cyanopyridine 

3-Cyanopyridine 

Cyanuric  chloride 

DADl 

DBB 

Decacyclene 

Developer  Z 

o-Dianisidine 

l,l'-Dianthrimide 

Dibenzan throne 

4 ,4 ' -Dihydroxydiphenylsulfone- 

Dimethyl   POPo'p 

4,5-Dinitrochrysazin 

Durene 

Fast  Red  G  base 

Fast  Scarlet  R  base 

G  salt 

Gamma  acid 

Gold  salt 

H  acid 

Hellimellitene 

J  acid 

J   acid   urea 

Koch's    acid 

MEP 

Mesitylene 

Methane  base 

Michler's  hydrol 

Michler's  ketone 


4-Amino-3-hydroxy-l-naphthalenesulfonic  acid. 

6-Ainino-3,4  '-azodibenzenesulfonic  acid. 

Sulfanilic   acid  and  salt. 

7-Amino-l ,3-naphthalenedisulfonic  acid. 

6-Amino-l,3-naphthalenedisulfonic   acid. 

3-Amino-2,7-naphthalenedisulfonic   acid. 

Aniline. 

2 , 6-Dihydroxyanthraquinone . 

1 ,5-Dihydroxyanthraquinone . 

a,a-Dichlorotoluene. 
7H-Benz [de]anthracen-7-one . 
ct,a,a,-Trichlorotoluene . 
4,4'-lsopronylidenediphenol . 
3-Hydroxy-2-naphthoic  acid. 
3-Bromo-7H-benz[de]anthracene-7-one . 
6- Amino- 2 -naphthalene sulfonic   acid. 

3-Amino-l,5-naphthalenedisulfonic  acid. 

Chloro-7H-benz[de]anthracen-7-one . 

4, 5 -Dihydroxy-2,7-naphthalenedi sulfonic  acid. 

1 , 8-Dihydroxyanthraquinone . 

Picolinonitrile. 

Nicotinonitrile. 

2,4,6-Trichloro-s-triazine . 

Dianisidine  diisocyanate. 

p-Dibutoxybenzene. 

Diacenaphtho[l,2-j  :1,2  '-Jl]fluoranthene. 

3-Methyl-l-phenyl-2-pyrazolin-5-one . 

3,3 '- Dime thoxybenzi dine. 

1 ,1  '-Iminodianthraquinone . 

Violan throne. 

4 ,4'-Sulfonyldiphenol . 

1 ,4- Bis [2- (4-methyl-5-phenyloxazoly 1) ] benzene . 

1 ,8-Dihydroxy-4,5-dinitroanthraquinone . 

1,2,4,5-Tetramethylbenzene. 

2-Nitro-p-toluidine   [NH2=1] . 
5-Nitro-o-anisidine   [NH2=1]. 

7-Hydroxy-l,3-naphthalenedisulfonic  acid. 
6-Amino-4-hydroxy-2-naphthalenesulfonic  acid,   sodiu 

salt. 
9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic  acid 

and  salt. 
4-Amino-5-hydroxy-2, 7 -naphthalenedi sulfonic  acid. 
1 , 2 ,3-Trimethylbenzene . 

7-Amino-4-hydroxy-2-naphthalenesulfonic  acid,   sodiu 

salt. 
7,7'-Ureylenebis(4-hydroxy-2-naphthalenesulfonic 

acid] . 

8-Amino-l ,3,6-napthalenetrisulfonic  acid. 

5-Ethyl-2-picoline 

1,3,5-Trimethylben2ene. 

4,4' -Methylenebis [N ,N-dimethy lani 1 ine] . 

4, 4 '-Bis [dime thy lamino]benzhydrol. 

4,4'-Bis[dimethylamino]benzophenone. 


SYNTHETIC  ORGANIC  CHEMICALS.  1972 
TABLE  3,— Cyclic  intermediates:  Glossary  of  synonymous  names--Continued 


Common  name 


Standard    (Chemical   Abstracts)    name 


Naphthionic   acid 

o-Naphthionic   acid 

6-Naphthol 

Naphthol  AS 

a-Naphthylamine 

Neville5  IVinther's   acid — 

Pentaanthrimide 

Phenylbiphenyl 

N-Phenyldiethanol  amine 

Phenyl  J  acid 

Phenyl  peri  acid 

POPOP 

Ps  eudocumene 

Pyrazolean throne 

Pyrazoleanthrone  yellow — 
Pyrazolone  T 

Quini  zarin 

2-Quinizarinsulfonic  acid- 

Quinoline  yellow  base 

R  salt 

Schaffer's   acid 

Silver  salt 

Solvent  Yellow  1 

Solvent  Yellow  3 

o-Sulfobenzaldehyde 

Thiosalicylic  acid 

Tobias  acid 

TODI 

o-Tolidine 

a-Toluic  acid 

a-Tolunitrile 

4-m-Tolylenediamine 

Trimellitic  anhydride 

Trimethyl  base 

Trinitrophenol 

Vinyl toluene 


4-Amino-l-naphthalenesulfonic  acid. 
1- Amino- 2 -naphthalene sulfonic  acid. 
2-Naphthol,    tech. 
3-Hydroxy-2-naphthanilide. 
1 -Naphthyl amine . 
4-Hydroxy-l-naphthalene sulfonic   acid. 

1,4,5,8-Tetrakis  Cl-anthraquinonylaminolanthraquinone. 
Ternhenyl . 

2,2'- [ CPhenyl)imino]diethanol . 

7 -Anilino-4-hydroxy-2 -naphthalene sulfonic   acid. 
8-Anilino-l-naphthalenesulfonic  acid. 
1 ,4-Bis [2- (S-phenyloxazolyl) ]benzene . 
1 ,2 ,4-Trimethylbenzene . 
Anthra[l,?   cd]pyrazol-6(2H)-one . 

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione. 
S-Oxo-l- (p-sulfophenyl)-2-pyrazoline-3-carboxylic 
acid. 

1 ,4-Dihydro.\yanthraquinone . 

9  ,10-Dihydro-l  ,4-dihydrox>'-9,in-dioxo-2-anthracene- 

sulfonic  acid. 
Quinophth alone . 

3-Hydroxy-2 ,7-naphthalenedisulfonic   acid,    disodium 
salt. 

6-Hydroxy-2-naphthalenesulfonic  acid. 
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonic  acid 

and  salt. 
p-Phenylazoaniline  and  hydrochloride. 
4- (o-Tolylazo)-o-toluidine . 
o-Formylbenzenesulfonic  acid. 

o-Mercaptobenzoic  acid. 

2-Amino-l-naphthalenesulfonic  acid. 

Bitolylene  diisocyanate. 

3,3' -Dinethylbenzidine . 

Phenylacetic  acid. 

Phenyl ace tonit rile. 

Toluene-2 ,4-di amine . 

1 ,2,4-Benzenetricarboxylic  acid,    1,2 -anhydride. 

l,3,3-Triniethyl-2-methyleneindoline. 

Picric   acid. 

ar-Methvlstvrene.