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Full text of "Synthetic organic chemicals"

77^ 



UNITED STATES INTERNATIONAL TRADE COMMISSION 

SYNTHETIC 
ORGANIC CHEMICALS 

United States Production 
and Sales, 1974 



USITC Publication 776 




RECENT REPORTS OF THE LOTTED STATES INTERNATIONAL TRADE COMMISSION ON 
S^TSTHETIC ORGANIC CHEMICALS 



*Synthetic Organic Chemicals, United States Production and Sales, 1969 (TC Publication 412, 

1971), .S2.00 
*Syntlietic Organic Chemicals, Lnited States Production and Sales, 1970 (TC Publication 479, 

1972), S2.00 1 

Synthetic Organic Chemicals, Lnited States Production and Sales, 1971 (TC Publication 614, 

1973), 82.70 
Synthetic Organic Chemicals, United States Production and Sales, 1972 (TC Publication 681, 

1974), 82.70 
*Synthetic Organic Chemicals, United States Production and Sales, 1973 (ITC Publication 728, 

1975), S3.25 



NOTE. — The reports preceded by an asterisk (*) are out of print. The other reports listed above may be 
purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. 
All U.S. International Trade Commission reports reproduced by the Government Printing Office may be 
consulted in the official depository libraries throughout the Lnited States. 



UNITED STATES INTERNATIONAL TRADE COMMISSION 



SYNTHETIC 
ORGANIC CHEMICALS 



United States Production 
and Sales, 1974 



U.S. GOVERNMENT PRINTING OFFICE 
WASHINGTON : 1976 



USITC Publication 776 



UNITED STATES INTERNATIONAL TRADE COMMISSION 



COMMISSIONERS 

Will E. Leonard, Jr. 
Chairman 

Daniel Minchew 
Vice Chairman 

George M. Moore 

Catherine Bedell 

Joseph O. Parker 

Italo H. Ablondi 



Kenneth R. Mason 

Secretary to the Commission 



Please address all communications to 

UNITED STATES INTERNATIONAL TRADE COMMISSION 

Washington, D.C. 20436 



For sale by the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402 - Price $3.20 

Stock No. 049-000-00042-1 



CONTENTS 



Page 



Introduction 1 

Summary 3 

General 4 

Tar 7 

Tar crudes 7 

Crude products from petroleum and natural gas 

for chemical conversion 13 

Cyclic intermediates 20 

Dyes 49 

Organic pigments 84 

Medicinal chemicals 93 

Flavor and perfume materials 114 

Plastics and resin materials 126 

Rubber-processing chemicals 135 

Elastomers -: 143 

Plasticizers 147 

Surface- active agents 155 

Pesticides and related products 184 

Miscellaneous chemicals 195 

APPENDIX 



Directory of manufacturers 239 

U.S. imports of benzenoid chemicals and products 253 

Cyclic intermediates: Glossary of synonymous names 255 



INTRODUCTION 

This is the fifty-eighth annual report of the U.S. International Trade Commission (formerly the U.S. Tariff 
Commission) on domestic production and sales of synthetic organic chemicals and the raw materials from which they are 
made. The report consists of fourteen sections, each covering a specified group (based principally on use) of organic 
chemicals as follows: Tar and tar crudes; crude products from petroleum and natural gas; intermediates; dyes; pig- 
ments; medicinal chemicals; flavor and perfume materials; plastics and resin materials; rubber-processing chemicals; 
elastomers; plasticizers; surface-active agents; pesticides and related products; and miscellaneous organic chemicals. 
Data have been supplied by approximately 800 producers. 

The first table in each section gives statistics on products and groups of products in as great detail as is 
possible without revealing the operations of individual producers. Statistics for an individual chemical or group 
of chemicals are given only when there are three or more producers, no one or two of which may be predominant. More- 
over, even when there are three or more producers, statistics are not given if there is any possibility that their 
publication would violate the statutory provisions relating to unlawful disclosure of information accepted in con- 
fidence by the Commission. ' 

Data are reported by producers for only tnose items where the volume of production or sales exceeds 1,000 pounds 
or the value of sales exceeds $1,000. They are usually given in terms of undiluted materials; however, products of 
95 percent or more purity are considered to be 100 percent pure. Commercial concentrations are applied to dyes, 
certain plastics and resins, and a few solvents; such concentrations are specifically noted. 

The statistics given in this report include data from all known domestic producers of the items covered and in- 
clude the total output of each company's plants, i.e., the quantities produced for consumption within the producing 
plant, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, there- 
fore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to 
changes in inventory. 

The second table in each section lists all items for which data on production or sales have been reported, by 
primary manufacturers, identified by manufacturers' codes. Each code consists of not more than three capital letters 
which is assigned on a permanent basis. The third table in each section is a directory, alphabetized by the codes 
of the manufacturers reporting in that section. Table 1 of the Appendix is a directory, alphabetized by the names of 
the manufacturers reporting in all sections and includes their office addresses. 

Information on the synonymous names of the organic chemicals included in this report may be found in the SOCMA 
Handbook: Commercial Organic Chemical Names, published by the Chemical Abstracts Service of the American Chemical 
Society, or the Colour Index (2d edition), published by the Society of Dyers and Colourists. 

Table 2 of the Appendix summarizes and gives the competitive status of U.S. general imports in 1974 of benzenoid 
intermediates and finished benzenoid products, entered under schedule 4, parts IB and IC, of the Tariff Schedules of 
the United States. 

As specified in the reporting instructions sent to manufacturers, production and sales (unless otherwise 
specified) are define^ as follows: 

PRODUCTION is the total quantity of a commodity made available 
by original manufacturers only. It is the sum — expressed in terms 
of 100% active ingredient unless otherwise specified in the reporting 
instructions — of the quantities: 

Produced, separated, and consumed in the same plant or 
establishment. A commodity is considered separated 
when it is isolated from the reaction system and/or 
when it is weighed, analyzed, or otherwise measured. 
This includes byproducts and coproducts that are not 
classifiable as waste materials^ 
Produced and transferred to other plants or establish- 
ments of the same firm; 
Produced and sold to other firms, including production 
for another under a toll agreement (i.e., an agreement, 
under which one firm furnishes the raw materials^ and 
pays the processing costs and the other firm prepares 
the finished product and returns it to the first firm). 
Produced and held in stock. 



^ Title 18, U.S.C. 1905 and Title 44, U.S.C. 3508 



INTRODUCTION 



PRODUCTION EXCLUDES : 

Pwnfiaation of a commodity, unless inalusion of 
such processing is specifically requested in 
the reporting instructions for individual 
sections; 

Intermediate products which are formed in the 
manufacturing process, hut are not isolated 
from the reaction system — that is, not 
weighed, analyzed, or otherwise measured; 

Materials that are used in the process but 
which are recovered for re-use or sale; 

Waste products having no economic significance. 

SALES are actual quantities of commodities sold by ORIGINAL 
MANUFACTURERS ONLY. Sales include the quantity and value of: 
Shipments of a commodity for domestic use and 
for export, or segregation in a warehouse 
when title has passed to the purchaser in a 
bona fide sale; 
Shipments of a commodity produced by others under 

toll agreements; 
Shipments to subsidiary or affiliated companies. 

SALES EXCLUDE: 

All intra-company transfers within a corporate entity; 
All sales of purchased commodities; 
All shipments of a commodity produced for others 
under toll agreements. 

VALUE OF SALES is the net selling value f.o.b. plant or 
warehouse, or delivered value, whichever represents the normal 
industry practice. 



SUMMARY 3 

Combined production of all synthetic organic chemicals, tar, tar crudes, and crude products from petroleum and 
natural gas in 1974 was 293,578 million pounds--an increase of 2.6 percent over the output in 1973 (see table 1). 
Sales of these materials in 1974 which totaled 160,591 million pounds valued at $30,284 million, were 2.3 percent 
smaller than in 1973 in terms of quantity and 57.2 percent larger in terms of value. These figures include data on 
production and sales of chemicals measured at several successive steps in the manufacturing process, and therefore, 
they necessarily reflect some duplication. 

In 1974 production of all synthetic organic chemicals, including cyclic intermediates and finished products 
totaled 183,869 million pounds, or 2.3 percent more than the output in 1973. Production of flavor and perfume 
materials (135 million pounds) was 15.7 percent larger in 1974 than in 1973; that of pesticides and related products 
(1,417 million pounds) was 10.0 percent larger; that of surface-active agents (4,696 million pounds) was 7.4 percent 
larger; that of cyclic intermediates (38,147 million pounds) was 6.4 percent larger; and that of medicinal chemicals 
(246 million pounds) was 5.5 percent larger. The output of most other groups of synthetic organic chemicals also 
increased in 1974 compared with 1973, with miscellaneous chemicals showing an increase of 1.6 percent and plasticizers 
showing an increase of 1.0 percent. Plastics and resin materials and organic pigments showed increases of less than 
one percent. Production of elastomers (synthetic rubbers) (5,654 million pounds) was 5.6 percent less in 1974 than 
in 1973; and that of dyes (275 million pounds) was 3.2 percent less. 



TABLE 1, --Synthetic organic chemicals and their raw materials; 
U.S. production and sales, 1973 and 1974 



Production 



Mill-ion 
pounds 



286,092 



Million 
pounds 



293,578 



Increase 

or 

decrease 

(-), 1974 

over 

1973' 



Quantity 



Incr 



ise 



decrease 

(-), 1974 

over 

1973' 



Million 
dollars 



Incre. 
or 
decrease 
(-), 1974 

over 

1973' 



Grand total 

Tar 

Tar crudes^ 

Crude products from petroleum 
and natural gas 

SyTithetic organic chemicals, 
total ^ 

Cyclic intermediates 

Dyes 

Organic pigments 

Medicinal chemicals 

Flavor and perfume 

materials 

Plastics and resin 

materials 

Rubber-processing chemicals- 
Elastomers (synthetic 

rubbers) 

Plasticizers 

Surface-active agents 

Pesticides and related 

products 

Miscellaneous chemicals 



Percent 
2.6 



Million 
pounds 



Million 
pounds 



Percent 
-2.3 



Million 
dollaFS 



7,325 
7,802 



91,250 



179,717 



6,774 
8,582 



183,869 



-7.5 
10.0 



3,363 
5,151 



106,17; 



3,336 
4,768 



102,265 



-0.8 

-7.4 



128 
1,4.S1 

17,638 



104 
273 



35,863 
284 



30,251 
401 

5,990 
1,873 
4,372 

1,289 
98,974 



38,147 



30,348 
384 

5,654 
1,892 
4,696 

1,417 
100,604 



6.4 

-3.2 

0.6 

5.5 

15.7 

0.3 
-4.3 

-5.6 
1.0 

7.4 

10.0 
1.6 



17,915 
266 



27,018 
312 



5,159 
1,708 
2,580 



1,199 
49,667 



17,638 
263 
58 

178 

107 
26,128 



4,601 
1,707 
2,502 

1,365 
47,431 



-10. 



519 
182 
582 

108 



199 

1,297 
341 
532 

1 , 344 
5,287 



,514 
556 
228 
815 



,529 
535 
746 

,815 
,815 



Percent 
57.2 



149.0 
112.0 



46.5 



85.1 

7.2 

25.1 

39.9 

53.7 

47.5 
18.4 

17.8 
56.8 
40.3 

35.1 
47.8 



Percentages calculated from figures rounded to thousands. 
Because of rounding, figures may not add to the totals shown. 
Estimated in part to avoid disclosing individual company operations. 
Less than 0.05 percent. 



SYNTHETIC ORGANIC CHEMICALS. 1974 
GENERAL 

In this report, synthetic organic chemicals are classified on the basis of their principal use as follows: cyclic 
intermediates, dyes, organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, 
rubber-processing materials, elastomers, plasticizers, surface-active agents, pesticides and related products and miscel- 
laneous chemicals (acyclic intermediates and acyclic and cyclic finished products). Most of these groups are further 
subdivided either by use or by chemical composition. As intermediate chemicals are used in the manufacture of finished 
products, aggregate figures that cover both intermediates and finished products necessarily include considerable dupli- 
cation. 

Total production of synthetic organic chemicals (intermediates and finished products combined) in 1974 was 183,869 
million pounds or 2.5 percent more than the output of 179,717 million pounds reported for 1973 and 75.6 percent more 
than the output of 104,711 million pounds reported for 1967 (see table 2). Sales of synthetic organic chemicals in 1974 
amounted to 102,265 million pounds, valued at $25,845 million, compared with 106,173 million pounds, valued at $17,638 
million in 1973 and 55,177 million pounds, valued at $10,438 million in 1967. Production of all cyclic products (inter- 
mediates and finished products combined) in 1974 totaled 60,331 million pounds or 4.6 percent more than the 57,672 mil- 
lion pounds reported for 1973 and 80.2 percent more than the 33,479 million pounds reported for 1967. Production of all 
acyclic products in 1974 totaled 123,537 million pounds, or 1.2 percent more than the 122,045 million pounds reported 
for 1973 and 73.4 percent more than the 71,232 million pounds reported for 1967. 

TABLE 2,— Synthetic organic chemicals: Summary of U.S. production and sales 

OF INTERMEDIATES AND FINISHED PRODUCTS, 1967, 1973, AND 1974 



[Production and sales in thousands of pounds; sales value in thousands of dollars] 



Increase, or decrease (-) 



1974 over 1974 over 
1967 1973 



Organic chemicals, cyclic and acyclic, 
grand total : 

Production 

Sales -- 

Sales value 

Cyclic, total: 

Production 

Sales 

Sales value 

Acyclic, total: 

Production 

Sales 

Sales value 

1. Cyolio Intermediates 

Production 

Sales 

Sales value 

2. Dyes 

Production 

Sales 

Sales value 

3. Organic Pigments 

Production 

Sales - 

Sales value 

i. Medicinal Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 



104,711,357 
55,176,823 
10,438,453 



33,479,469 
19,328,628 
4,610,293 



71,231,888 

35,848,195 

5,828,160 



20,793,132 
9,461,180 
1,000,359 



206,240 
198,592 
332,049 



53,322 
42,867 
108,354 



110,129 

70,120 

348.873 

69,941 
56,804 
36,402 



179,717,077 

106,173,335 

17,638,472 



57,671,745 
'35,560,162 
^8,113,736 



122,045,332 

'70,613,173 

^9,524,736 



35,863,052 

17,915,149 

1,898,756 



284,226 
266,199 
518,621 



69,395 
61,464 
182,166 



134,065 
87,129 
510,677 

99,518 
92,049 
71,675 



183,868,858 
102,264,717 
25,844,900 



60,331,380 
34,339,420 
12,014,301 



123,537,478 
67,925,297 
13,830,599 



38,146,699 
17,638,158 
3,514,211 



275,036 
263,143 
556,226 



69,798 

58,481 

227,812 



143,646 
93,588 
713,452 

102,807 
83,927 
101,315 



85.3 

147.6 



77.7 
160.6 



33.4 
32.5 
67.5 



33.5 
104.5 

47.0 
47.8 
178.3 



2.3 
-3.7 



-3.4 
48.1 



7.2 

7.4 

39.7 

3.3 
-8.8 
41.4 



See footnotes at end of table. 



GENERAL 



TABLE 2. —Synthetic organic chemicals: Summary of U.S. production and sales 
OF intermediates and finished PRODUCTSy 1967^ 1973^ AND 1974— Continued 

[Production and sales in thousands of pounds; sales value in thousands of dollars] 



5. Flavor and Pepfime Materials 

Cyclic: 

Produc t ion 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

6. Plastics and Resin Materials 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value- 

7. Rubber-Processing Chemicals 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 

8. Elastomers (Synthetic Rubbers) 

Cyclic: 

Produc tion 

Sales 

Sales value 

Acyclic: 

Produc t ion 

Sales 

Sales value 

9. Plasticizers 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic: 

Production 

Sales 

Sales value 

10. Surface-Active 

Cyclic: 

Production 

Sales 

Sales value 

Acyclic : 

Production 

Sales 

Sales value 



57,978 
47,285 
52,866 

53,558 
49,311 
40,495 



5,033,497 
4,224,121 
1,036,940 

8,759,452 
7,753,242 
1,635,690 



220,139 
169,970 
116,318 

43,994 
30,878 
15,477 



2,297,637 

1,940,099 

439,580 

1,524,908 

1,321,945 

434,657 



929,871 
865,084 
167,827 

332,908 
296,767 
93,142 



1,418,444 

852,238 

95,810 

2,060,851 
897,786 
220,877 



52,928 
45,553 
66,150 

64,072 
62,774 
42,339 



9,903,150 
8,813,959 
2,179,687 

20,347,467 
18,204,270 
3,167,741 



338,368 
263,833 
y75,825 

62,557 
48,136 
23,664 



3,517,739 

3,018,006 

571,902 

2,472,272 

2,141,245 

725,535 



1,502,160 

1,389,714 

233,556 

371,223 
318,699 
107,829 



1,872,378 

1,368,796 

161,829 

2,500,038 

1,210,868 

370,011 



55,729 
42,721 
100,922 

79,592 
64,726 
65,804 



9,767,809 
8,341,509 
3,243,405 

20,580,321 
17,786,597 
4,643,953 



324,643 
238,732 
206,474 

59,215 
47,603 
29,773 



,209,876 
,558,478 
641,507 



443,969 
042,076 
887,481 



1,411,437 

1,305,983 

338,356 

480,248 
401,142 
196,891 



2,333,967 

1,468,753 

329,529 

2,362,533 

1,032,919 

416.869 



Increase, or decrease (-) 



1974 over 
1967 



-3.9 
-9.6 
90.9 



31.3 
62.5 



94.1 
97.5 
212.8 



129.4 
183.9 



47.5 
40.5 



34.6 
54.2 
92.4 



39.7 
31.9 
45.9 

60.3 
54. 5 
104.2 



51.8 
51.0 
101.6 

44.3 
35.2 
111.4 



64.5 

72.3 

243.9 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2.— Synthetic organic chemicals; Summary of U.S. production and sales 

OF INTERMEDIATES AND FINISHED PRODUCTS^ 1967, 1973, AND 1974~C0NTINUED 
[Production and sales in thousands of pounds; sales value in thousands of dollars] 



1967' 



Increase, or decrease (-) 



1974 ov 
1967 



1974 over 
1973 



11. Pesticides and Related Products 



Cyclic: 

Production-- 

Sales 

Sales value- 
Acyclic: 

Product ion- - 

Sales 

Sales value- 



12. Miscellaneous chemicals 



Cyclic: 

Production-- 

Sales 

Sales value- 
Acyclic: 

Production-- 

Sales 

Sales value- 



823,158 
681,532 
627,742 

226,505 
215,831 
159,301 



1,535,922 
775,540 
283,575 

58,159,771 

25,225,631 

3,192,119 



^900,901 

^851,568 

'1,091,211 

^379,051 
^347,000 
^252,370 



3,224,383 

1,478,792 

523,356 

95,749,134 

48,188,132 

4,763,572 



1,025,547 

971,078 

1,468,494 

391,611 
394,136 
346,939 



3,567,193 

1,358,796 

673,913 

97,037,182 

46,072,171 

7,141,574 



24.6 
42.5 
133.9 

72.9 
82.6 
117.8 



13.6 
37.5 



-8.1 
28.8 



' Includes ligninsulfonates. 



The following tabulation shows, by chemical groups, the number of companies that reported production in 1974 of one 
or more of the chemicals included in the groups listed in table 2: 



Chemical groug 

Cyclic intermediates 

Dyes 

Organic pigments 

Medicinal chemicals 

Flavor and perfume materials- 
Plastics and resin materials- 



Nvmber 

of 

companies 



Chemical group 

Rubber-processing chemicals 

Elastomers (synthetic rubbers) - - 
Plasticizers 

Surface-active agents 

Pesticides and related products- 
Miscellaneous chemicals 



Number 

of 
companies 



59 
185 



TAR AND TAR CRUDES 



Tar 



Coal tar is produced chiefly by the steel industry as a byproduct 
of the manufacture of coke; water-gas tar and oil-gas tar are produced 
by the fuel -gas industry. Production of coal tar, therefore, depends 
on the demand for steel; production of water-gas tar and oil-gas tar re- 
flects the consumption of manufactured gas for industrial and household 
use. Water-gas and oil-gas tars have properties intermediate between 
those of petroleum asphalts and coal tar. Petroleum asphalts are not 
usually considered to be raw materials for chemicals. 

The quantity of tar produced in the United States in 1974 was al- 
most entirely coal tar which amounted to 677 million gallons (see table 1). 
Production in 1974 was 8 percent less than the 732 million gallons of 
coal tar produced in 1973. Sales of coal tar in 1974 amounted to 334 
million gallons, valued at $104 million, compared with 336 million gallons, 
valued at $42 million, in 1973. U.S. production of water-gas and oil-gas 
tars was not reported to the Commission for 1973 or 1974; production of 
these tars in 1948 amounted to 21 million gallons, according to trade 
publications . 

Consumption of tar in 1974 amounted to an estimated 687 million 
gallons, of which 73 percent was consumed in distillation. Tar used by 
the producers as fuel amounted to 181 million gallons; a lesser amount, 3.6 
million gallons, was consumed by coke-oven operators in miscellaneous 
uses (see table lA) . 

Tar Crudes 

Tar crudes are obtained from coke-oven gas and by distilling coal 
tar, water-gas tar, and oil-gas tar. The most important tar crudes are 
benzene, toluene, xylene, creosote oil, and pitch of tar. Some of 
these products are identical with those obtained from petroleum. Data 
for materials obtained from petroleum are included, for the most part, 
with the statistics for like materials obtained from coke-oven gas and 
tars, and are shown in table 1 and IB. 

Domestic production of industrial and specification grades of benzene 
reported by coke-oven operators and petroleum refinery operators^ in 1974 
amounted to 1,488 million gallons--2.4 percent more than the 1,453 million 



^Statistics on production and sales of benzene, toluene, and xylene by 
tar distillers cannot be shown because publication would reveal the oper- 
ations of individual companies. 



g SYNTHETIC ORGANIC CHEMICALS^ 1974 

gallons reported for 1973. These statistics include data for benzene 
produced from light oil and petroleum. Sales of benzene by coke-oven 
operators and petroleum refiners in 1974 amounted to 788 million gallons, 
valued at $528 million, compared with 719 million gallons, valued at 
$207 million, in 1973. In 1974 the output of toluene^ (including material 
produced for use in blending in aviation fuel) amounted to 922 million 
gallons--3.8 percent less than the 958 million gallons reported for 1973. 
Sales of toluene in 1974 were 454 million gallons, valued at $239 million, 
compared with 513 million gallons, valued at $115 million, in 1973. The 
output of xylene^ in 1974 (including that produced for blending in motor 
fuels) was 802 million gallons, compared with 785 million gallons in 1973. 
Over 99 percent of the 802 million gallons of xylene produced in 1974 
was obtained from petroleum sources. 

Production (or sales) figures on crude naphthalene from coal-tar oils 
in 1974 could not be published without disclosing the operations of 
individual companies. Production of petroleum-derived naphthalene in 1974 
amounted to 201 million pounds, compared with 240 million pounds in 1973. 
In 1974 the output of creosote oil for wood preservation was 141 million 
gallons (100 percent creosote basis), compared with 111 million gallons 
in 1973. Production figures on road tar for 1974 cannot be published; in 
1972 production amounted to 30 million gallons. 

Some of the products obtained from tar and included in the statistics 
in table 1 are obtained from other products for which data are also in- 
cluded in the table. The statistics, therefore, involve considerable 
duplication, and for this reason no group totals or grand totals are given. 
After duplication has been eliminated insofar as possible, the estimated 
net value of the output (from all sources) of these products and of tar 
burned as fuel was $2,213 million in 1974, compared with $962 million in 
1973. The total value of sales of those products obtained from coke-oven 
gas and tars shown in table 1 (exclusive of coal tar itself), amounted to 
$273 million in 1974, compared with $128 million in 1973. 

Data for 1973 tar crudes were supplied by 15 companies and company 
divisions . 



See footnote 1 on page 1. 



TAR AND TAR CRUDES s 

TABLE 1,--Tar and tar crudes; U.S. production and sales. 1974 

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders (...) 
are used where the reported data are accepted in confidence and may not be published or where no data were re- 
ported.) Table 2 lists separately all products for which data on production and/or sales were reported and identi- 
fies the manufacturers of each] 



Quantity 



Unit J 
vfalue 



Tar: Coke-oven operators 

Crude light oil: Coke-oven 

operators 

Intermediate light oil: Coke-oven 

operators 

Light-oil distillates: 

Benzene, specification and industrial 

grades, total 

Coke-oven operators 

Petrol eum refiners 

Toluene, all grades, total 

Coke-oven operators 

Petrol eum refiners 

Xylene, all grades 

Coke-oven operators 

Petroleum refiners 

Solvent naphtha: Coke-oven 

operators 

Crude tar-acid oils : Coke-oven 

operators 

Creosote oil (Dead Oil) (tar distillers 
and coke-oven operators) (100% 
creosote basis), total 

Distillate- as such (100% creosote 
basis) 

Creosote content of coal tar solution 
(100% creosote basis) 

All other distillates, total 

Coke-oven operators, total 

From light oil 

Other' 

Tar distillers 

Tar, refined, for uses other than road 

tar 

Pitch of tar (tar distillers and coke- 
oven operators'), total 

Soft (water softening point less 
than 100° F.): Coke-oven 

operators 

Other' 



1,000 gal- 
1,000 gal- 
1,000 gal- 



1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 

1,000 gal- 



1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 

1,000 gal-- 
1 ,000 tons 



1,000 tons 
1,000 tons 



677,447 

338,779 

5,070 



1,488,264 

82,149 

1,406,115 

921,959 

13,567 

908,392 

802,111 

3,135 

798,976 

2,736 



140,993 



114,574 
26,419 
110,086 



6,451 

3,855 

2,596 

103,fa35 



15,902 
1.240 



464 
776 







1,000 






do I lars 


333 


623 


103,830 


95 


439 


39,761 


1 


811 


384 


788 


393 


527,771 


83 


114 


63,442 


705 


279 


464,329 


454 


376 


238,765 


13 


105 


6,981 


441 


271 


231,784 


634 


219 


331,173 


3 


050 


1,677 


631 


169 


329,496 



94,455 



41.241 



70,370 
24,085 
37,463 



5,155 

2,640 

2,515 

32,308 



11,292 
882 



28,136 
13,105 
13,805 



1,102 

853 

249 

12,703 



6,225 
83.623 



171 
711 



14,047 
69,576 



.311 
.417 
.212 



.669 
.763 
.658 
.526 
.533 
.525 
.522 
.550 
.522 



.400 
(') 
.368 



.214 
.323 
.099 
.393 



.551 
94.811 



82.146 
97.857 



' Unit value per gallon, pound, or ton, as specified. 

^ Includes only data for coal tar reported to the Division of Fuels Data, U.S. Bureau of Mines. Data on U.S. 
production of water-gas tar and oil-gas tar are not collected by the U.S. International Trade Commission, but acc( 
to trade publications, production of these tars amounted to 21 million gallons in 1968. 

' Data reported by tar distillers are not included because publication would disclose the operations of 
individual companies. Production of benzene and toluene by tar distillers decreased in 1974, compared with 1973. 
Production of xylene by tar distillers increased slightly in 1974, compared with 1973. The annual production 
statistics for petroleum refiners on benzene, toluene, and xylene are not comparable with the combined monthly 
production figures, because of fiscal year revisions. 

(Continued) 



rding 



SYIJTHETIC ORGANIC CHE.'IICALS, igZ^^ 



Footnotes fov table 2 — Continued 

'* Includes data for material produced for use in blending motor fuels. 

^ Statistics include data only for creosote oil sold for, or used in, wood preserving. 

" In 1974, production of coal-tar solution containing creosote (100% solution basis) amounted to 44,747 thousand 

gallons; sales were 32,050 thousand gallons, valued at 13,105 thousand dollars, with a unit value of $0,409 per 

gallon. 

' Includes data for crude sodium phenolate. 

^ Includes data for crude light oil, benzene, toluene, solvent naphtha, rubber-reclaiming oils, pyridine crude 

bases, crude tar-acid oils, crude cresylic acid, neutral oils, methylnaphthalene, crude tar for other uses, 

unspecified tar distillates, road tar, and a small amount of ethylbenzene. U.S. production and sales of two other 

distillates could not be published without disclosing the operations of individual companies; combined sales of 

crude naphthalene and soft pitch of tar in 1974 amounted to over $7.5 million. 

' Includes hard pitch and pitch emulsion along with a small amount of medium pitch produced by coke-oven operators. 

Note. --Statistics for materials produced in coke and gas-retort ovens are compiled by the Division of Fuels 
Data, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum 
refineries are compiled by the U.S. International Trade Commission. 



TABLE 1A.--TAR: U.S. production and consumption^ 1973 and 197^1 

(In thousands of gallons) 



Product 


1973 


1974 


PRODUCTION 


732,455 


677,447 




CONSUMPTION 


718,235 


687,146 












553,574 


502,683 






225,801 
327,773 

163,736 
925 


185,476 
317,207 

180,907 
3,556 


Coal tar and water-gas tar distilled by tar distillers ^ 


Coal tar consumed at coke-oven plants in miscellaneous uses' 



^ Reported to the Division of Fuels Data, U.S. Bureau of Mines 

Reported to the US. International Trade Commission. Represents tar purchased from companies operating coke 
ovens and gas-retort plants and distilled by companies operating tar-distillation plants. Statisticsllso include 
tar consumed other than by distillation by tar distillers. mciuae 



TAR AND TAR CRUDES 



TABLE IB,— Tar and tar crudes: Summary of U.S. production of specified products 
1967. 1973. AND 197i* 

[Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no data 

were reported] 



Unit 
of 
quantity 



Increase, or 
decrease (-) 



1974 over 
1967 



1974 over 
1973 



Tar 

Benzene: 

Coke-oven operators 

Petroleum refiners 

Total 

Toluene: ' 

Coke-oven operators 

Petroleum refiners 

Total 

Xylene:' 

Coke-oven operators 

Petroleum refiners 

Total 

Naphthalene: 

Crude 

Petroleum naphthalene, all 

grades 

Total 

Creosote oil (Dead oil): 
Distillate as such (100% 

creosote basis) 

Creosote content of coal tar 
solution (100% creosote 

basis) 

Total 



1,000 gal-- 



1,000 gal- 
1,000 gal- 



90,642 
878,704 



85,876 
1,367,385 



82,149 
1,406,115 



Peyaent 
-13.2 



-9.4 
60.0 



Fercent 
-7.5 



-4.3 
2.8 



1,000 gal- 



1,000 gal- 
1,000 gal- 



19,357 
624,454 



14,496 
943,699 



13,567 
908,392 



1,000 gal-- 



1,000 gal- 
1,000 gal- 



643,811 



5,488 
449,349 



958,195 



3,104 
782,028 



3,135 
798,976 



-42.9 
77.8 



1,000 gal- 

1,000 Ib-- 
1,000 Ib-- 



520,991 
376,679 



240,486 



802,111 

(«) 
200,842 



1,000 gal- 



1,000 gal-- 



17,402 



87,679 



22,933 



1,000 gal- 



140,993 



1 Standard reference base period for Federal Government general-purpose index numbers, 

2 Includes only data for coal tar reported to the Division of Fuels Data, U.S. Bureau of Mines. 

' Data reported by tar distillers are not included because publication would disclose the operations of 
individual companies. 

^ Includes data for material produced for use in blending motor fuels. Statistics are not comparable with 
monthly figures which included some o-xylene. 

* Naphthalene solidifying at less than 79° C. Figures include production by tar distillers and coke-oven 
operators and represent combined data for the commercial grades of naphthalene. Because of conversion between 
grades, the figures may include some duplication. Statistics on naphthalene refined from domestic crudes are re- 
ported in the section on cyclic intermediates. 

' Statistics on crude naphthalene cannot be published; to do so would disclose the operations of individual 
companies. Production of crude naphthalene in 1974, however, did not equal the low of 360 million pounds in 1971. 

' Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood 
preserving. 



L2 SYNTHETIC ORGANIC CHEMICALS, 1974 

TABLE 2, --Tar crudes for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1974 

[Tar crudes for which separate statistics are given in table 1 are marked with an asterisk (*); products not so 
marked do not appear in table 1 because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 3. Table 3 identifies all U.S. producers of 
tar crudes (e.xcept producers that report to the Division of Fuels Data, U.S. Bureau of Mines)] 



Product 



•Crude light oil' 

Light-oil distillates:' 

Benzene, specification grades 

Toluene, specification grades 

♦Solvent naphtha 

All other light-oil distillates 

Pyridine crude bases' 

Naphthalene, crude, solidifying at:' 

Less than 74° C 

74° C. to less than 79° C: 

74° C. to less than 76° C 

76° C. to less than 79° C 

Methylnaphthalene 

*Crude tar-acid oils: 

Tar-acid content 5% to less than 24% 

Tar-acid content 24% to 50% 

Cresylic acid, crude 

•Creosote oil (Dead oil): 

•Distillate as such 

•Creosote in coal tar solution 

•All other distillate products 

Tar, road 

Tar for other uses: 

Crude 

•Refined' 

•Pitch of tar: ' 

•Soft (water softening point less than 110° F.) 

Medium (water softening point 110° F. to 160° F.)- 

Hard (water softening point above 160° F.) 

Pitch emulsion 



Manufacturers ' identification codes 
(according to list in table 3) 



CBT. 

KPP. 

KPP 

HFC, NEV. 

HPC, KPT. 

KPT 

COP. 

KPT. 

ASC, KPT. 
KPT. 

KPT. 
ASC. 
KPT, PRO. 

ASC, CBT, COP, HUS, KPT, RIL, WTC . 
ASC, KPT, RIL, WTC. 
ASC, KPT, WTC. 
ASC, KPT, RIL. 

KPT. 
ASC, KPT. 

ASC, KPT. 

ASC, CBT, COP, KPT. 

ASC, HYS, KPT, WTC. 

JEN. 



Does not include manufacturers' identification codes for producers who report to the Division of Fuels Data, U.S. 
Bureau of Mines. Those producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, November 6, 1975, 
entitled "Coke Producers in the U.S. in 1974. 

TABLE 3. --Tar and tar crudes; Directory of manufacturers, 1974 



ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of tar and tar crudes to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 21 



Code 


Name of company 


Code 


Name of company 


ASC 


Allied Chemical Corp. 


KPT 


Koppers Co. , Inc. : 

Organic Materials Div. 




CBT 


Samuel Cabot, Inc. 




Roads Materials Div. 




COP 


Coopers Creek Chemical Corp. 


' NEV 


Neville Chemical Co. 




HPC 


Hercules, Inc., Picco Div. 








HUS 


Husky Industries, Inc. 


PA I 
PRO 


Pennsylvania Industrial Chemical 
Productol Chemical Co . , Inc . 


Corp. 


JEN 


Jennison-Wright Cojrp 


RIL 


Reilly Tar S Chemical Corp. 




KPP 


Arco/Polymers, Inc. 


; WTC 


Witco Chemical Co., Inc. 





Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR 13 

CHEMICAL COMVEI^SION 

CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR 
CHEMICAL CONVERSION 

Crude products that are derived from petroleum and natural gas are 
related to the intermediates and finished products made from such crudes 
in much the same way that crude products derived from the distillation 
of coal tar are related to their intermediates and finished products. 
Many of the crude products derived from petroleum are identical with those 
derived from coal tar [e.g., benzene, toluene, and xylene). Considerable 
duplication exists in the statistics on the production and sales of 
petroleum crudes because some of these crude chemicals are converted to 
other crude products derived from petroleum and because data on some pro- 
duction and sales are reported at successive stages in the conversion 
process. The statistics are sufficiently accurate, however, to indicate 
trends in the industry. Many of the crude products for which data are 
included in the statistics may be used either as fuel or as basic materials 
from which to derive other chemicals. In this report every effort has 
been made to exclude data on materials that are used as fuel; however, data 
are included on toluene and xylene which are used in blending aviation and 
motor fuel . 

The output of crude products derived from petroleum and natural gas 
as a group amounted to 94,353 million pounds in 1974, or 3.4 percent more 
than the 91,250 million pounds reported for 1973 (table 1). The larger 
output in 19 74 is accounted for chiefly by increased production of ethylene, 
propylene, and benzene. Sales of crude chemicals from petroleum in 1974 
amounted to 50,222 million pounds, valued at $4,062 million, compared with 
49,625 million pounds, valued at $1,451 million, in 1973. 

The output of aromatic and naphthenic products from petroleum amounted 
to 26,579 million pounds in 1974, compared with 24,774 million pounds in 
1973. Sales amounted to $1,165 million in 1974 and $458 million in 1973. 
The output of 1° and 2° benzene from petroleum in 1974 (10,293 million pounds) 
was 2.8 percent more than the 10,009 million pounds produced in 1973. 

Production of all aliphatic hydrocarbons and derivatives from petroleum 
and natural gas was 67,774 million pounds in 1974, compared with 66,475 
million pounds in 1973. Sales of these products were valued at $2,897 
million in 1974 compared with $993 million in 1973. Production of ethylene 
was 23,891 million pounds in 1974--7.0 percent more than the 22,329 million 
pounds produced in 1973. The output of 1 , 3-butadiene in 1974 (3,682 
million pounds) was the largest on record. 

Data for 1974 crude products from petroleum and natural gas for chemical 
conversion were supplied by 74 companies and company divisions. 

1 Statistics on aromatic chemicals from coal tar are given in the report 
on "Tar and Tar Crudes." 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSI 



TABLE 1,- 



-Crude products from petroleum and natural gas for chemical conversion; 
II, S, production and sales, 197^1 



[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported 
data on production or sales may be published. (Leaders (...) are used where the reported data are accepted in con- 
fidence and may not be published or where no data were reported.) Table 2 lists separately all products from 
petroleum and natural gas for chemical conversion for which data on production and/or sales were reported and identi- 
fies the manufacturers of each] 



Production 



1,UUU 



Grand total 

aromatics and NAPHTHENES^ 

Total 

Benzene (1° and 2") 

Naphthalene, all grades 

Naphthenic acid 

Toluene, all grades, total 

Nitration grade, 1° 

Pure commercial grade, 2° 

Solvent grade, 90% 

All other 

Xylenes, mixed, total 

3° grade 

5° grade 

All other' 

All other aromatics and naphthenes 

ALIPHATIC HYDROCARBONS 

Total 

Cj hydrocarbons, total 

Acetylene 

Ethane 

tthylene 

Cj hydrocarbons, total 

Propane 

Propylene 

Ci+ hydrocarbons, total 

1,3-Butadiene, grade for rubbers (elastomers) 

Butadiene and butylene fractions 

n- Butane 

1-Butene and 2-butene mixture - 

1 sobutane 

I sobu ty lene 

All other 

Cs hydrocarbons, total 

Isoprene (2 -Methyl -1,3- butadiene) 

All other" 

See footnotes at end of table. 



26,579,097 



10,292,762 
200,842 
52,072 

6,549,506 



4,816,157 
449,039 
196,617 

1,087,693 

6,072,218 



626,711 
1,119,602 
4,325,905 



67,773,957 



325,490 
6,381,853 
23,891,459 



7,390,760 
10,474,948 



10,701,665 



3,682,119 

757,666 

2,185,487 

1,086,976 

994,395 

1,995,022 



329,260 
736,867 



1,000 
pounds 



50,221,517 



1,000 
dollars 



1,165,126 



5,162,642 

121,607 

19,891 



464,329 

14,473 

2,430 

231,784 



,376,553 
134,849 



670,162 
4,796,885 



177,521 
12,035 



42,228 
329,496 



589,973 
1,034,372 
3,172,340 



33,932,307 



44,222 
75,000 
210,274 



2,897,053 



5,357,121 
7,058,126 



109,451 
529,024 



6,260,145 
4,332,838 



5,729,417 



226,481 
300,475 



536,310 



2,500,826 
362,100 
653,483 
550,534 
326,981 
211,672 

1,123,821 

609.074 



363,932 
21,337 
37,714 
41,099 
10,460 
20,683 
41,085 

39,875 



113,350 
495,724 



10,965 
28,910 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 1. --Crude products from petroleum and natural gas for chemical conversion; 

U.S. production and sales. 1974--CONTINUED 



Production 



Quantity 



Net 

, 1 

value 



ALIPHATIC HYDROCARBONS--Continued 

All other aliphatic hydrocarbons, derivatives, and 

mixtures, total 

Alpha olefins, total 

Molecular weight ranges, Cs-C? 

All other'" 

Heptenes, mixed 

Hexanes and other C6 hydrocarbons 

Nonene (Tripropylene] 

n- Paraffins, total 

Carbon chain length, C9-C15 

Other 

Polybutene 

Tetrapropylene 

Hydrocarbon derivatives 

All other" 



1,000 
pounds 



7,541,655 



1,000 
pounds 



1,000 
dollars 



Per 

pound 



441,131 

37,471 

403,660 

66,020 

358,341 

437,817 

1,257,329 

351,042 

906,287 

183,978 

302,040 

64,233 

4,430,746 



406,955 

32,279 

374,676 

329,542 
239,367 
721, 43S 



106,438 

53,655 

2,728,191 



51,733 
3,210 

48,523 

20,985 
6,486 

41,721 



6,882 
10,270 
1,007,360 



.127 
.099 
.130 

.064 
.069 



.065 
.191 
.369 



1 Calculated from rounded figures. 

2 The chemical raw materials designated as aromatics are in some cases identical with those obtained from the 
distillation of coal tar; however, the statistics given in the table above related only to such materials as are de- 
rived from petroleum and natural gas. Statistics on production or sales of benzene, toluene, and xylene from all 
sources are given in tables 1 and IB of the report "Tar and Tar Crudes, 1974." 

3 Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. 
•* Includes data for crude cresylic acid, alkyl aromatics, distillates, solvents, and miscellaneous cyclic hydro- 
carbons . 

5 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of 
the Census . 

' Includes data for propane-propylene mixture. 

' The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- 
factured. 

8 Includes data for mixed butanes, 1-butene, 2-butene, mixed butylene, mixed olefins and sales of isobutylene. 
' Includes data for isopentane, pentenes, and C5 hydrocarbon mixtures. 
'» Includes data for the following molecular weight ranges: Cs-Cio; Cs-Cio; Cio-Cie; C11-C15; Ci2-Cn; Cn-Cie; 
C15-C20; C16-C18: and C16-C30. 
" Includes compounds having a molecular weight of 3,000 or less. 

12 Includes data for butyl, ethyl, methyl, and miscellaneous mercaptans and other hydrocarbon derivatives. The 
decrease in output in 1974 compared to 1973 and 1972 is due to a decrease in production of most of the items grouped 
in these years. In addition, several items were produced in quantities too low to be reported by the companies for 
1974. 

15 Includes data for di-isobutylene, methane-ethane-ethylene mixture, heptanes, methane, octanes, mixtures of C2 
and C3 hydrocarbons and of other hydrocarbons, and sales of acetylene, heptenes, C^-Cjj hydrocarbons, and of polybutene. 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSION 17 

TABLE 2. --Crude products from petroleum and natural gas for chemical conversion for which 

U.S. PRODUCTION OR SALES WERE REPORTED, IDENTIFIED BY MANUFACTURER. 1974 

[Crude products from netroleum and natural gas for chemical conversion for which separate statistics are given in 
table 1 are marked below with an asterisk (*) ; products not so marked do not appear in table 1 because the reported 
data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken 
from table 3. An x signifies that the manufacturer did not consent to his identification with the designated 
product] 



Manufacturers' identification codes 
(according to list in table 3) 



AROMATICS AND NAPHTHENES 

*Benzene (except motor grade): 

♦Benzene, 1° 

* Benzene, 2° 

Cresylic acid, crude 

♦Naphthalene, all grades 

♦Naphthenic acids: 

Acid number lower than 150 

Acid number 151-199 

Acid number 200-224 

Sodium carbolate and nhenate, crude 

♦Toluene : 

♦Nitration grade, 1° 

♦Pure commercial grade, 2° 

♦Solvent grade, 90% 

All other 

♦Xylenes, mixed: 

Avi at ion grade 

♦3° grade 

♦ 5 ° grade 

All other 

All other aromatics, naphthenes, distillates and 
solvents 



ALIPHATIC HYDROCARBONS 

Ci hydrocarbon: Methane 

*C2 hydrocarbons : 

♦Acetylene 

♦Ethane 

♦Ethylene 

C2 and C3 hydrocarbons, mixed 

♦C3 hydrocarbons: 

♦ Propane 

♦Propylene 

*Cit hydrocarbons: 

♦1,3-Butadiene, grade for rubbers (elastomers) 

♦Butadiene and butylene fractions 

♦n- Butane 

1- Butene 

2-Butene 



ACU, AMO, APF, APR, ASH, ATR, CCP, CSD, CSC, CSP, EKX, 
ENJ, GOC, GRS, HES, MOC, MON, PLC, PPR, SHC, SKO, 
SM, SNT, SOG, SUN, TOC, TX, UCC, UOC. 

CPI, DOW, SOC. 

PRD. 

ASH, COL, MON, SUN, TID. 

ATR, SUN, TX. 

ATR, PRD, SOC, SUN. 

ATR, PRD, SOC. 
ATR. 

A^^0, APF, ASH, ATR, CCP, CSD, ENJ, GOC, GRS, HES, MOC, 

MON, PLC, PPR, SHC, SNT, SOG, SUN, TOC, TX, UCC, UOC. 
ATR, CPI, CSP, DOW, MON, UCC. 
ACC, FG, SKO. 
ATR, CPI, ELP, GOC, PLC, SHO, SH, SOC. 

CSO. 

APF, CSD, MOC, PPR, UOC. 
ASH, ATR, GOC, HES, SOG. 

AMO, CCP, CPI, CSD, CSP, ENJ, GRS, HCR, MON, PPR, SHC, 
SNT, SOC, STY, SUN, TOC, UCC. 

ACC, ACU, APR, CBN, CPX , DUP, EKX, ENJ, FG, GOC, JCC, 
MOG, MON, .NWP, OMC, PLC, PRD, PUE, SHC, SOC, SOG, 
TX, UCC. 



MON, NWP. 

DOW, MNO, PJI, UCC. 

ACU, ATR, DOW, ENJ, MON, OMC, PAN, PLC, PUE, SM, TX, 

US I. 
ACU, AMO, ATR, BAS, BFG, CBN, CO, CPX, DOW, DUP, EKX, 

ELP, ENJ, GOC, JCC, KPP, MON, NWP, OMC, PLC, PUE, 

SHC, SM, SNO, TX, UCC, USI . 
ATR, CSO. 

AMO, APR, ASH, ATR, CCP, COR, CPI, CSD, CSO, CSP, ENJ, 
GRS, MOC, OMC, PAN, PLC, PUE, SHO, SM, SNT, SOG, SOI, 
SUN, TX, UOC, USI. 

ACC, ACU, AMO, ATR, BFG, BRP, CBN, CO, CPX, CSD, CSO, 
DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, MOC, MON, 
NWP, PLC, PUE, SHC, SIO, SM, SNT, SOG, SOI, SUN, 
TX, UCC. 

ATR, BFG, CPY, DOW, ELP, ENJ, FRS, MON, PLC, PTT, PUE, 

SHC, SM, Tin, TUS, UCC. 
ACU, ATR, BFG, CO, CPX, DOW, EKX, GOC, GYR, NWP, SHC, 

UCC. 
ATR, BFG, COP, CSP, OMC, PLC, PUE, SHO, SM, SNT, SUN, 

USI. 
GOC, PLC. 
ATR, MON, PLC. 



SYNTHETIC ORGANIC CHEMICALS. 19m 



TABLE 2.— Crude products from petroleum and natural gas for chemical conversion for which 
U.S. production or sales were reported, identified by manufacturer. 1974— Continued 



Manufacturers' identification codes 
(according to list in table 3) 



ALIPHATIC HYDROCARBONS--Continued 

*Ci, hydrocarbons--Continued 

*I-Butene and 2-butene mixture 

*Isobutane 

*Isobutylene 

All other 

*C5 hydrocarbons: 

Isopentane (2-Methylbutane5 

*Isoprene (2-Methyl-l ,3-butadiene) 

n-Pentane 

Pentenes, mixed 

All other 

*C6 hydrocarbons: 

*Hexane 

Neohexane C2,2-Dimethylbutane] 

All other 

C7 hydrocarbons: 

n-Heptane 

*Heptenes, mixed 

All other 

Ca hydrocarbons : 

Diisobutylene (Diisobutene) 

n- Octane 

All other 

Hydrocarbons, C9 and above: 

*Nonene CTripropy lene) 

*Polybutene 

*Tetrapropylene 

Triisobutylene 

All other 

*A11 other aliphatic hydrocarbons, derivatives and 
mixtures : 
Hydrocarbons : 
*Alpha olefins--Molecular weight ranges: 

*C6-C7 

Cs-Cio 

C11-C15 

All other 

*n-Paraffins--Carhon chain length: 

C5-C9 

*C9-Cl5 

C10-C14 

C10-C16 

All other 

♦Hydrocarbon derivatives: 

tert- Butyl -mercaptan (2-'1ethyl-2-nrooanethiol)-- 

Cyclohexyl mercaptan 

Di-tert-butyl disulfide 

Ethyl mercaptan CEthanethiol) 

n-Hexadecyl mercaptan 

Methyl mercaptan (Methanethiol^ 

tert-Nonyl mercaptan 

n-Octyl mercaptan 

n-Propyl mercaptan (l-Propanethiol] 

All other 

Mixtures, not elsewhere classified 



AMO, ATR, BFG, CSC, DOW, ENJ , GOC, PLC, PTT, SOI, TX. 

ATR, BFG, CSP, ELP, ENJ, OMC, PLC, SHO, SUN, TX, USI . 
ENJ, MON, OCC, PTT. 

APR, BFG, CBN, CSD, ENJ, JCC, MON, PUE, SM. 

PAN, PLC. 

BFG, ENJ, GYR, MON, SHC. 

APR, ATR, PLC. 

GYR, MON, TX. 

BFG, CBN, MON, PLC, SHC, SOC , UCC. 

APR, ENJ, PLC, SOG, UOC. 

PLC. 

PLC, SWC. 

EKX, PLC, SOG. 
ENJ, GOC, SOI, TID. 
ENJ, HCR, UOC. 

BFG, CSD, PTT, TX. 

SOG. 

ENJ, PLC. 

ATR, CSD. ENJ, SUN, UOC. 

ACC, CSD, SOC. 

ATR, CO, ENJ, SOC, SUN, TX , UOC. 



ACC, ATR, CO, CPI, ENJ, 
TNA, UOC, UCC. 



GOC, GYR, SOC. 
GOC, SOC. 
GOC, SOC. 
GOC, SOC, TNA. 

SOG, UCC. 

BFG, HCR, SOG, UCC. 

ENJ, SOG. 

CO. 

ATR, CO, ENJ, PUE, UCC. 

PAS. 

PAS. 

PLC. 

PAS. 

PAS. 

ACC, DOW, PAS. 

PAS. 

PLC. 

PLC. 

ATR, EKX, PAS, PLC. 

GYR, MON. 



KPP, PLC, PPR, PUE, SOC, TID, 



CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS FOR CHEMICAL CONVERSI 



TABLE 3." 



-CrUDE products FROn PETROLEUM AND NATURAL GAS FOR CHEfllCAL CONVERSION: 

Directory of manufacturers, 1974 



ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of crude products from petroleum and natural gas for 
chemical conversion to the U.S. International Trade Commission for 1974 are listed below in the order of their 
identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACC 


Amoco Chemicals Corp. 


MNO 


Monochem, Inc. 




ACU 


Allied Chemical Corp., Union Texas 


MOC 


Marathon Oil Co., Texas Refinir 


g Div. 




Petroleum Div. 


MON 


Monsanto Co . 




AMO 


American Oil Co. (Texas) 








APF 


American Petrofina Co. of Texas 


NWP 


Northern Petrochemical Co. 




APR 


Atlas Processing Co. 








ASH 


Ashland Oil, Inc. 


OCC 


Oxirane Chemical Co. 




atr 


Atlantic Richfield Co. 


one 


Olin Corp. 




BAS 


BASF Wyandotte Corp. 


PAN 


Amoco Production Co. 




BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


PAS 


Pennwalt Corp. 






Co. Div. 


PLC 


Phillips Petroleum Co. 




BRP 


BP Oil, Inc. 


PPR 
PRD 


Phillips Puerto Rico Core, Inc 
Productol Chemical Co., Inc. 




CBN 


Cities Service Co., Petrochemical Div. 


PTT 


Petro-Tex Chemical Corp. 




CCP 


Crown Central Petroleum Corp. 


PUE 


Puerto Rico Olefins 




CO 


Continental Oil Co. 








COL 


Collier Carbon 6 Chemical Corp. 


RH 


Rohm 5 Haas Co. 




COR 


Commonwealth Oil S Refining Co., Inc. 








CPI 


Commonwealth Petrochemicals, Inc. 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


CPX 


Chemplex Co. 


SHO 


Shell Oil Co. 




CPY 


Copolymer Rubber 6 Chemical Corp. 


SIO 


Standard Oil Co. of Ohio 




CSD 


Cos den Oil S Chemical Corp. 


SKO 


Skelly Oil Co. 




CSO 


Cities Service Oil Co. 


SM 


Mobil Chemical Co. 




CSP 


Coastal States Petrochemical Co. 


SM 
SNO 


Mobil Oil Corp. 
SunOlin Chemical Co. 




DOW 


Dow Chemical Co. 


SNT 


Suntide Refining Co. 




DUP 


E. I. duPont de Nemours 6 Co., Inc. 


SOC 


Standard Oil Co. of California 
Chemical Co. 


Chevron 


EKX 


Eastman Kodak Co., Texas Eastman Co. Div. 


SOG 


Charter International Oil Co. 




ELP 


El Paso Products Co. 


SOI 


Amoco Oil Co. (Maryland) 




ENJ 


Exxon Chemical Co. U.S.A. 


STY 
SUN 


Styrochem Corp. 
Sun Oil Co. 




FG 


Foster Grant Co. , Inc. 


SWC 


Corco Cyclohexane, Inc. 




frs 


Firestone Tire 5 Rubber Co. , Firestone 










Synthetic Rubber & Latex Co. Div. 


TID 


Getty Oil Co. (Eastern Operators, Inc.) 






TNA 


Ethyl Corp. 




GOC 


Gulf Oil Corp., Gulf Oil Chemicals 


TOC 


Tenneco Oil Co. 






Co. - United States 


TUS 


Texas-U.S. Chemical Co. 




GRS 


Champlin Petroleum Co. 


TX 


Texaco, Inc. 




GYR 


Goodyear Tire S Rubber Co. 


UCC 


Union Carbide Corp. 




HCR 


Hercor Chemical Corp. 


UOC 


Union Oil Co. of California 




HES 


Hess Oil Virgin Islands Corp. 


USI 


National Distillers 6 Chemical 
U.S. Industrial Chemicals Co 


Corp. , 
Div. 


JCC 


Jefferson Chemical Co., Inc. 








KPP 


Arco/Polymers, Inc. 








Note. --Co 


mnlete names and addresses of the above reporting 


companies 


are listed in table 1 of the appe 


ndix. 



SYNTHETIC ORGANIC CHEMICALS^ 1974 
Cyclic Intermediates 

Cyclic intermediates are synthetic organic chemicals derived princi- 
pally from petroleum and natural gas and from coal-tar crudes produced by 
destructive distillation (pyrolysis) of coal. Most cyclic intermediates 
are used in the manufacture of more advanced synthetic organic chemicals 
and finished products, such as dyes, medicinal chemicals, elastomers 
(synthetic rubbers), pesticides, and plastics and resin materials. Some 
intermediates, however, are sold as end products without further processing. 
For example, refined naphthalene may be used as a raw material in the manu- 
facture of 2-naphthol or of other more advanced intermediates, or may be 
packaged and sold as a moth repellent or as a deodorant. In 1974 about 46 
percent of the total output of cyclic intermediates was sold; the rest was 
consumed chiefly by the producing plants in the manufacture of more advanced 
intermediates and finished products. 

Total production of cyclic intermediates in 1974--38,147 million pounds- 
was the largest on record, and was 6.4 percent larger than the output of 
35,863 million pounds reported for 1973. The larger output of cyclic inter- 
mediates in 1974 is accounted for principally by increases in production 
of cumene, p-xylene, ethylbenzene, cyclohexane, nitrobenzene, and aniline. 
Sales of cyclic intermediates in 1974 were 17,638 million pounds, valued 
at $3,514 million, compared with 17,915 million pounds, valued at $1,899 
million, in 1973. 

Production of ethylbenzene in 1974 was 6,048 million pounds, or 6.3 
percent more than the 5,688 million pounds produced in 1973. Output of 
styrene was 5,956 million pounds, a slight decrease from the 5,975 million 
pounds produced in 1973. Other intermediates whose production exceeded 
1 billion pounds in 1974 were dimethyl terephthalate (4,262 million pounds), 
cumene (2;906 million pounds), p-xylene (2,707 million pounds), cyclohexane 
(2,352 million pounds), phenol (2,329 million pounds), and o-xylene (1,056 
million pounds). Other large-volume intermediates produced in 1974 were 
phthalic anhydride (977 million pounds), isocyanates (886 million pounds), 
cyclohexanone (651 million pounds), aniline (551 million pounds), straight- 
chain alkylbenzenes (533 million pounds), 2,4(and 2 ,6) -dinitrotoluenes 
(523 million pounds), nitrobenzene (507 million pounds), monochlorobeazene 
(379 million pounds), and Bisphenol A (370 million pounds). Tlie above 17 
chemicals accounted for 85 percent of the total output of intermediates 
in 1974. Production of 13 of the above chemicals increased in 1974 com- 
pared with 1973. The output of four, however, decreased in 1974 from that 
in 1973, as follows: phthalic anhydride (4.5 percent), monochlorobenzene 
(4,5 percent), o-xylene (1.1 percent), and styrene (0.3 percent). 



CYCLIC INTERMEDIATES 
TABLE 1.— Cyclic intermediates; U.S. production and sales, 197^^ 



[Listed below are all c>xUc intermediates for which any reported data on production and/or sales may be published. 
(Leaders (...) are used where the reported data are accepted in confidence and may not be published or where no 
data were reported.) Table 2 lists alphabetically all cyclic intermediates for which data on production and/or 
sales were reported and identifies the manufacturers of each] 



Unit 
value' 



1,000 
pounds 



Total 

Acetanilide, tech 

Acetophenone, tech 

N-Acetylsulfanilyl chloride 

Alkylbenzenes^ 

l-Aminoanthraquinone and salt 

l-Amino-4-ben2amidoanthraquinone 

7- (p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic 

acid 

1 -Ami no- 2 -bronio-4 -hydroxy an thraqui none 

l-Amino-2,4-dibromoanthraquinone 

4-Amino-4'-nitro-2,2'-stilbenedisulfonic acid 

p-[(p-Aminophenyl)azo]benzenesulfonic acid 

Aniline (Aniline oil) 

Anilinomethanesulfonic acid and salt 

o-Anisidinomethanesulfonic acid 

7H-Benz [de]anthracen-7-one ( Ben zan throne) 

Benzoic acid, tech 

2-Benzothiazolethiol , sodium salt-- 

[4,4'-Bi-7H-benz[de]anthracene]-7,7'-dione 

Biphenyl 

4 , 4 ' -B i s [dimethyl amino ] ben zophenone (Michler ' s 

ketone) 

3-Bromo-7H-benz[de]anthracen-7-one (3-Bromobenz- 

an throne) 

2-Bromo-4,6-dinitroaniline 

Chlorobenzene, mono 

4-Chloro-3-nitrobenzenesulfonamide 

Cresols, total ' 

o-Cresol 

All other ** 

Cresylic acid, refined' 

Cumene 

Cyclohexane 

Cyclohexanone 

1,4-Diaminoanthraquinone 

l,4-Diamino-2,3-dihydroanthraquinone 

4,4'-Diamino-2,2'-stilbenedisulfonic acid 

Uicyclopentadiene (includes cyclopentadiene) -• 

N, N-Die thy lani line 

9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and 

salt (Gold salt) 

1,4-Dihydroxyanthraquinone (Quinizarin) 

16, 17-Dihydroxyvio Ian throne (Dihydroxydibenzanthrone)- 

p- (Dimethyl amino) benzaldehyde 

N,N-Dimethy lani line 

N,N-Dimethylbenzyl amine 

2,4-Dinitroaniline 

4,4'-Dinitrostilbene-2,2'-disulfonic acid 

2, 4 (and 2,6)-Dinitrotoluene 

Diphenyl amine 

N-Ethyl aniline, refined 

2-(N-Ethylanilino)ethanol 

Gthylbenzene^ 



See footnotes at end of table. 



3,730 

2,684 

5,628 

532,829 

702 

43 

12 

533 

857 

186 

434 

551,178 

466 

816 

838 

78,466 

13,189 

263 

84,622 

112 

128 

2,055 

379,181 

808 

114,015 



23,354 
90,661 

77,271 

2,905,629 

2,351,508 

650,619 

70 

834 

8,843 

95,875 

3,295 

1,142 

2,311 

249 

15 

19,407 

204 

577 

5,489 

522,842 

39,890 

2,399 

360 

6,048,342 



1,000 
pounds 



17,638,158 



1,000 
dollars 



2,489 
484,881 



30,252 
7,204 



27,885 



71,683 



23,432 
90,234 

48,053 
1,416,014 
1,961,936 

33,279 



59,466 
1,731 



8,539 
146 



20,604 
2,792 



881 
100,464 



6,299 
2,677 



3,531 



7,640 
36,978 

13,750 

144,410 

243,304 

9,083 



4,491 
1,290 



3,566 

233 



8,472 
1,293 



75,730 



SYNTHETIC ORGANIC CHEMICALS, 197'1 
TABLE 1, --Cyclic intermediates: U.S. production and sales^ 1974--Continued 



Quantity 



Unit 
value ^ 



N- Ethyl -N-phenylbenzyl amine 

3-CN-Ethyl-m-toluidino)propionitrile 

Hydroquinone, tech 

3-Hydroxy-2-methylcinchoninic acid 

Isocyanic acid derivatives, total 

Polymethylene polyphenylisocyanate 

Toluene-2,4- and 2,6-diisocyanate (80/20 mixture)--' 
Other isocyanic acid derivatives 

4,4 '-Isopropylidenediphenol (Bisphenol A) 

Leuco quinizarin (1,4,9,10-Anthratetrol) 

Mel amine 

Metanilic acid Cm-Aminobenzenesulfonic acid) 

4,4'-Methylenebis [N,N-dimethylaniline] (Methane base)' 

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

a-Methylstyrene 

Nitrobenzene 

5-Nitro-o-toluenesulfonic acid [S03H=1] 

Nonyl phenol 

1 [ ( 7-0x0- 7H-benz [de] anthracene- 3-yl ) amino ] anthra- 
quinone 

Phenol, total' 

Natural, from coal tar and petroleum 

Synthetic, total 

From cumene 

Other synthetic 

p-Phenylazoaniline (C.I. Solvent Yellow 1) and hydro- 
chloride 

Phthal ic anhydride 

Propiophenone 

Salicylaldehyde 

Salicylic acid, tech 

Styrene, all grades 

Terephthalic acid, dimethyl ester^ 

Toluene-2,4 -diamine (4-m-Tolylenediamine) 

4-(o-Tolyazo)-o-toluidine (CI. Solvent Yellow 3) 

Violanthrone (Dibenzanthrone) 

o-Xylene 

p-Xylene 

All other cyclic intermediates 



1,000 
pounds 



22,101 
429 



298,390 
514,619 

72,912 

370,388 
177 

130,721 
1,304 
1,862 

57,240 

506,646 

7,564 

110,439 

329 

,328,723 



30,514 

2,298,209 

2,087,765 

210,444 



326 

977,149 

786 

5,251 

43,722 

5,955,647 

4,261,589 

200,674 

264 

288 

1,055,874 

2,707,206 

4,002,651 



1,000 
pounds 



1,000 
dollars 



Per 

pound 



719,073 



229,452 

438,213 

51,408 



45,315 
12,616 



37,975 



1,434,403 



19,536 
1,414,867 
1,350,389 

64,478 



3,990 

12,666 

2,835,049 



836,963 
1,880,955 
4,201,950 



283,358 



160,169 
36,818 



28,633 



5,194 
1,753 



11,327 



314,555 



4,614 

309,941 

287,876 

22,065 



8,437 

8,326 

488,788 



95,405 
276,906 
1,137,022 



$1,082 
1.394 



.376 
.366 
.716 



3.647 
.US 
.139 



.219 



.236 
.219 
.213 
.342 



Calculated from rounded figures. 

Includes straight-chain dodecylbenzene, tridecylbenzene and other straight-chain alkylbenzenes. Branched-chain 
alkylbenzenes are included in "all other cyclic intermediates". 

' Includes data for coke ovens and gas-retort ovens, reported to the Division of Fuels Data, U.S. Bureau of Mines 
and for tar and petroleum refineries and other producers, reported to the U.S. International Trade Commission. 
'* Figures include (o,m,p) -cresol from coal tar and some m-cresol and p-cresol. 

Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture. 

The figures for terephthalic acid, dimethyl ester (DMT) include both the acid itself and the dimethyl ester 
without double counting. The acid production and sales quantity figures were multiplied by the factor 1.16 to convert 
them to equivalent DMT. 



CYCLIC INTERHEDIATES 23 

TABLE 2. --Cyclic intermediates for which U,S, production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 197^ 

[Cyclic intermediates for which separate statistics are given in table 1 are marked with an asterisk (*) ; cyclic 
intermediates not so marked do not appear in table 1 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that 
the manufacturer did not consent to his identification with the designated product] 



Manufacturers ' identification codes 
Caccording to list in table 3) 



3- [ f2-Acetamido-4-aminophenyl)azo]-l ,5-naphthalene- 

disulfonic acid. 

2-Acetamido-3-chloroanthraquinone 

2,2' -[ (S-Acetamido-S-ethoxyphenylHiiinoldiethanol 

2,2' -[ (5-Acetamido-2-ethoxyphenyl)imino] diethanol 

4-Acetaniido-2-hydroxybenzoic acid 

2,2 '-[ (3 -Acetamido-6-methoxyphenyl 3 imino] diethanol 

*Acetanilide, tech 

Acetanilide, N.F. 

Acetic acid, phenyl ester 

Acetoacetanilide 

o-Acetoacetanisidide 

o-Acetoacetotoluidide 

2' ,4 ' -Acetoacetoxylidide 

1 ' - Ace t onaph thone 

Acetone phenylhydrazone 

*Acetophenone, tech 

p-Acetotoluidide 

a-*cetylamLdo-p -t oluenesul f on amide 

N-Acetvlanthranilic acid 

p-Acetylbenzenesulfonamide 

p-Acetvlbenienesulfonic acid, sodium salt 

p-Acetylhenzenesulfonvlurethane 

*N-Acetylsulfanilvl chloride 

Acyloin 

*Alkylbenzenes : 

Podecylbenzene (including tridecylbenzene) : 

•Straight chain 

nther 

Alkylpyridines, mixed 

a-dl-5-Allyl-6-imino-l-methyl-5- (l-iiiethyl-2-pentynyl) 

barbituric acid. 
a-dl-5-Allyl-5- (l-methyl-2-pentynyl5-l-methylbarbituric 

acid. 

3'-Arainoacetanilide 

4'-Aminoacetanilide (Acetyl-p-phenylenedi amine) 

2 ' - Aminoacetophenone 

3'-Aminoacetophenone 

5' -Amino-2- (D-aminoanilino)benzenesulfonic acid 

l-Amino-4-(3-amino-4-sulfoanilino)-9,10-dihydTO-9,in- 

dioxo-2-anthracenesulfonic acid. 
l-Amino-4- (4-amino-3-sulfoanilino) -9,10-dihydro-9, 10- 

dioxo-2-anthracenesulfonic acid. 

l-Amino-4-anilino-2-methoxyanthraquinone 

2- (p-Aminoanilino)-5-nitrobenzenesulfonic acid 

3-Amino-p-anisanilide 

*l-Aminoanthraguinone and salt 

2-Aminoanthraquinone and salt 

5(and 8) -Amino-1-anthraquinonesulfonic acid 

N- (;4-Amino-l-anthraquinonyl)anthranilic acid 

N- (5-Amino-l-anthraquinonyl)anthranilic acid 

4-Aminoantipyrine and hydrochloride 

6-Amino-3,4'-azodibenzenesulfonic acid (CI. Acid 

Yellow 9). 

p-Aminohenz amide 

*l-Amino-4-benzamidoanthraquinone 

1- Amino- 5-benzaraidoanthraquinone 

7- (ra-Aminobenzamido) -4-hydroxy-2-naphthalenesulfonic 

acid. 
* 7- (p-Aminobenzamido)-4-hydroxy-2-naphthalene sulfonic 

acid. 

3'-Aminobenzanilide 

2-Amino-p-benzenedisulfonic acid [SOjHsl] 

o-Aminobenzene thiol 

p-Aminobenzoic acid, tech 



TRC. 

AC. 

HST. 

TCH. 

SDW. 

HST. 

ARA, MRK, SAL. 

SAL. 

UCC. 

FMP, HST. 

FMP, HST. 

FMP, HST. 

HST. 

GIV. 

DUP. 

CLK, SKO, UCC. 

EK. 

SDW. 

SW. 

LIL. 

LIL. 

LIL. 

ACY, ARA, MRK. 

.^RA. 



Cn, MON, UCC, WTC. 

cn, soc. 

UCC. 
LIL. 

LIL. 

AC, DUP, TRC. 

GAF, TRC. 

EK. 

ARA. 

TRC. 

TRC. 



TRC. 



ACS. 






TRC. 






PCW. 






AC, 


ACY, 


^^AY, 


ACY. 






TRC 






GAF 






DUP. 






EK, 


SDW. 




ACY 


TRC 




SAL 


SDH 




ACY 


MAY 


TRC 


TRC 






TRC 






GAF 


TRC 


VPC 


X. 






DUP 


GAF 




ASH 


FMT 




DUP 







SYNTHETIC ORGAfllC CHEMICALS, 197 1^ 



TABLE 2.— Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY. MANUFACTURER, 1974— CONTINUED 



4 - Aminobenzonhenone 

2-Amino-6-benzothiazolecarhoxvlic acid 

2- (m-Aminohenzoyl) -o-acetanisidide 

N- (4-Amino-.'5-broi'io-l-anthTaquinonyl)-p-toluidine 

sulfonic acid. 
5(and 8) -Amino-8(and 5)-bromo-9,in-dihvdro-9,10- 

dioxo-1 ,6(and 1,7) -anthracenedisulfonic acid. 
l-Amino-4-hronio-'',in-r'ihydro-9,10-dioxo-2-anthracene- 
sulfonic acid and sodium salt. 

*l-Aiiiino-2-hromo-4-hydroxyanthraquinone 

2-Amino-5-bromo-5-nitrobenzonitrile 

l-Amino-2-bronio-4-p-toluidinoanthraquinone 

7-Aminocephalosporanic acid 

1- Amino- 5 -chloroanthraqui none 

2-Amino-l-chloroanthraquinone 

4- Amino-6-chloro-m-benzenedi sulfonamide 

4- Amino-6-chloro-m-benienedi sulfonamide hydrochloride 

2-Araino-6-chlorobenzothiazole hydrochloride 

o- (3-Amino-4-chIorobenzoyl)benzoic acid 

2-Amino-5-chloro-4-ethylbenzenesulfonic acid 

1 - Amino- 2 -chloro- 4 -hydroxy ant hraqui none 

3-Amino-5-chloro-2-hydroxybenzenesulfonic acid 

2-Amino-4-chlorophenol 

2-Amino-6-chloropyrazine 

3-Amino-6-chloronyridazine 

2-Amino-5-chloro-p-toluenesulfonic acid [S03H=1] 

6-Amino-4-chloro-m-toluenesulfonic acid [Sn3H=l] 

2-Aiiiino-p-cresol 

*l-Amino-2,4-dibromoanthraquinone 

l-Araino-2,4-dichloroanthraquinone 

5-Amino-l,4-dichloroanthraquinone 

2-Amino-5,6-dichlorobenzothiazole 

2 -Amino- 4 ,6-dichloro-5-cresol 

4 '-Amino- 2' ,5'-diethoxybenzanilide 

l-Amino-9,in-dihydro-P,in-dioxo-4-D-toluenesulfonamido- 

2-anthracenesulfonic acid, sodium salt. 
5-Amino-4,.^'-dihydroxv-3,4'-r(2-methoxy-5-methyl-D- 

phenylene)bis Cazo)]-di- 2, 7-naphthalenedi sulfonic acid, 

S ' -benzenesul fonate . 

3-Amino-9-ethylcarbazole 

3-Amino-a-ethylhydrocinnamic acid 

4-Amino-N-ethyl-N-(8-methylsulfonamidoethyl)-m- 

toluidine phosphate. 

p-Amino-N-ethyl-N-1-naphthylbenzamide 

N-Aminoethylpiperazine 

N- Aminohexamethy 1 eneimine 

4- Amino- 5-hydroxy- 2, 7-naphthalenedi sulfonic acid, 

benzene sulfonate. 
4-Amino-5-hydroxy-2 ,7-naphthalenedisulfonic acid 

(H acid), monosodium salt. 
4-Araino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4- 

acid) . 
6-Amino-4-hydroxy-2-naphthalenesulfonic acid (r,amma 

acid), sodium salt. 
7-Araino-4-hydroxy-2-naphthalenesulfonic acid (J acid), 

sodium salt. 
2- C2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nitro- 

benzoic acid. 

3-Amino-2-nercaT)tobenzoic acid 

4- Amino- 3- C8-methanesulfonamidoethvl)-N,N-diethyl aniline 

hydrochloride. 
N-(4-Amino-3-methoxy-l-anthraquinonyl) -o-toluenesulfon- 

amide. 

5-Amino-6-methoxv-2-naphthalenesulfonic acid 

m- [ (4-Amino-3-methoxyphenyl)azo]benzenesulfonic acid 



Manufacturers' identification codes 
(according to list in table 3) 



DUP. 
DUP. 
GAP. 
TRC. 

TRC. 



AC, 


TRC. 




AC, 


DUP, 


VPC. 


TRC 






ACS 


TRC 




LIL 






TRC 






DUP 






ABB 






ABB 






DUP 






AC. 






ACY 






TRC 






TRC 






SW. 






ACY 






ACY. 






ACY, 


HSC 




DUP. 


HSC 




TRC. 






AC, 


DUP, 


TRC, VPC 


TRC. 






DUP. 






SAL. 






EK. 






ALL. 






AC, 


X. 





SDC 






SDW 






WAY 






GAP 






UCC 






PMP 






TRC 






ACS 






ACY 


TRC 


, VPC 


TRC 






AC, 


TRC. 




TRC 






X. 






EKT 






AC, 


DUP. 




TRC 






AC, 


DUP, 


TRC. 



CYCLIC INTERRED I ATES 



TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1974— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



4- [ (4-Amino-5-methoxy-o-tolyl)azo] -4-hydroxy-2 ,7- 

naphthalenedisulfonic acid, benzenesulfonate. 
7- [ (4-Amino-5-methoxy-o-tolyl)azo] -1,3-naphthalenedi- 

sulfonic acid. 
4-Amino-4'-(3-iiiethyl-5-oxo-2-pyrazolin-l-yl)-2,2'-stil- 

benedisulfonic acid. 
4' - C4' '-Amino- 2' ' -methylphenylazo)-7-phenylazona- 

phthalene-1 ,3-disulfonic acid, disodium salt. 
2-Amino-4-methylpyTimidine (2-Amino-4-methyl-l ,3- 

diazine) . 

2- Amino- 4- (methylsulfonyl) phenol 

2-Amino-5-methyl-l ,3,4-thiadiazole 

7-Amino-3- [1- (S-methyl-l ,3,4-thiodiazol-2-yl)thio-7] -3- 

cephem-4-carboxylic acid hydrochloride. 

2- Amino- 1 , 5 -nanh thai enedi sulfonic acid 

3-Amino-l ,5-naphthalenedisulfonic acid (C acid) 

4- Amino- 1 ,6- naphtha 1 enedi sulfonic acid 

6-Amino-l,3-naohthalenedisulfonic acid (Amino I acid) 

7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid) 

l-Amino-2-nanhthalenesulfonic acid (o-Naphthionic acid)- 

2-Amino-l-naphthalenesulfonic acid (Tobias acid) 

4-Amino- 1-naphthalenesulfonic acid, sodium salt 

S-Amino-l-naohthalenesulfonic acid (Laurent's acid) 

6-Amino-2-naphthalenesulfonic acid (Broenner's acid) 

7-Amino-l ,3,6-naphthalenetrisulfonic acid 

S-Amino-l ,3,6-naphthalenetrisulfonic acid (Koch's acid)- 

8-Amino-2-nanhthol 

2-Amino-4-nitroacetanilide 

2-Amino-5-nitrobenzenesulfonic acid [Sri3H=l] 

2-Amino-6-nitrobenzothiazole 

*4-Amino-4'-nitro-2,2'-stilbenedisulfonic acid 

2-Amino-5-nitrothiazole 

3-Amino-2-oxazolidinone 

6-Aminopenicillanic acid 

o-Aminophenol 

p - Aminopheno 1 

2- (n-AminoDhenoxv)ethanol hydrochloride 

m-[ (p-Aminophenyl)azo]benzenesulfonic acid 

*p-i (p-Aminophenyl)azo]benzenesulfonic acid 

7- [ (4- Aminophenyl)azo]-l,3-naphthalenedi sulfonic acid 

8- Ami no- 5- (phenylazo) -2-naohthol 

5- [ (p-Aminoohenyl)azo] salicylic acid 

2,2'- (m-Arainoohenylimino)diethanol , diacetate ester 

2- (p-Aminophenyl)-6-methylbenzothiazole 

2- (p-Aminophenyl)-6-methyl-7-benzothiazolesulfonic acid 

and salt. 
l-(m-Aminophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid-- 

3- (Aminopropyl)cyclohexyl amine 

4'-Aminopronionhenone 

2-Aminopvridine 

2-Aminopyrimidine 

5- Aminosalicylic acid 

2-Aminothiazole 

3-Amino-p-toluaraide 

a- Amino-p -toluene sulfonamide 

4-Amino-m-toluenesulfonic acid [SOjH=l] 

6-Amino-m-toluenesulfonic acid [S03H=1] 

5-Amino-o-toluenesulfonic acid [Sn3H=l] 

m- (4-Amino-3-tolylazo)benzenesulfonic acid 

7-[(4-Amino-o-tolyl)azo]-l,3-naphthalenedisulfonic acid- 

5-Amino-2,4-xylenesulfonic acid 

*Aniline (Aniline oil) 

Aniline hydrochloride 



TRC. 
TRC. 



TRC. 






ACY. 






LIL. 
ACY, 


SDH. 




TRC. 






DUP. 






AC, 


TRC. 




AC, 


DUP, TRC. 




DUP. 






ACY, 


SW. 




DUP. 






DUP. 






TRC. 






AC, 


DUP-. 




.iVCS, 


DUP. 




TRC. 






SDC. 






TRC. 






SAL. 






AC, 


ACS, GAP, TRC. 




PCW. 






NOR. 






TRD. 






SDC, 


TRC. 




MAL, 


SDC. 




GAP. 






TRC. 






ACY, 


DUP, TRC. 




TRC. 






ALL. 






TRC. 






nup. 






DUP. 






DUP, 


TRC. 




TRC, 


VPC. 




ABB. 






F.K. 






NEP. 






ACY. 






TRC 






"RK 






SDH. 






SDW. 






ACY, 


DUP. 




DUP, 


HSC. 




TRC 






TRC 






TRC 






DUP 






ACY 


DUP, FST, MAL, MOB, 


RUC, USR 


ACY 


EK. 





SYNTHETIC ORGANIC CHEMICALS, 197^^ 



TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974— CONTINUED 



2'-Anilino-6-diethylamino-3-methylfluoran 

2- (N-Anilino)diethanol 

2-Anilinoethanol 

7-Anilino-4-hydroxy-2-nachthalenesulfonic acid (Phenyl 
J acid) . 

*Anilinomethane5ulfonic acid and salt 

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)- 

m-Anilinophenol 

n-Anilinophenol 

3-Anilinopropionitrile 

o-Anisaldehyde 

o-Anisidine 

p-Anisidine 

l-p-Anisidino-4-hydroxyanthraquinone 

*o-Anisidinomethanesulfonic acid 

m-Anisil 

Anisole, tech 

3- (o-Anisylazo)benzenesulfonic acid, sodium salt 

Anthracene 

Anthranilic acid (o-Aminobenzoic acid)' 

Anthranilic acid, methyl ester 

Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone) 

Anthraquinone, 100% 

N,N'-(l,S-Anthraquinonylene)dianthranilic acid 

N,N'-(l,5-Anthraquinonylene)dioxamic acid 

4' ,4' ' ' -Azobis[4-biphenylcarboxylic acid] 

Benzaldehyde, tech 

Benzamide hydrochloride (p-Nitro-n-2-diethylaminoethyl)- 

l-Benzamido-4-bromoanthraquinone 

1 - Ben z ami do- 5 -chloro anthraquinone 

4- Benzamido-5 -hydroxy- 2, 7-naphthalenedi sulfonic acid 

7-Benzamido-4-hydroxy-2-naphthalenesulfonic acid 

Benzanilide 

*7H-Benz[de]anthracen-7-one (Benzanthrone) 

Benzenesulfonamide 

Benzene sulfonic acid 

Benzenesulfonyl chloride 

1,2,4,5-Benzenetetracarboxylic-l ,2, :4,5-dianhydride 

1,2,4-Benzenetricarboxylic acid, 1,2-anhydride (Tri- 
mellitic anhydride) . 

Benzhydrol (Diphenylmethanol) 

Benzidine base 

Benzidine hydrochloride and sulfate 

Benzilic acid, methyl ester 

2-Benzimidazolethiol 

*Benzoic acid, tech' 

Benzoic acid, 3- [N- (2-hydroxyethyl)anilino]propio- 
nitrile ester. 

Benzoin 

Benzonitrile 

p-Benzoquinonedioxime 

2-Benzothiazolethiol 

*2-Benzothiazolethiol sodium salt 

IH-Benzotriazole 

2H-3,l-Benzoxazine-2,4(lH)-dione (Isatoic anhydride) 

0-Benzoylbenzoic acid 

Benzoyl chloride 

2-Benzoyl-N-l-naphthylacetamide 

N-Benzylacet amide 

Benzyl amine 

1- Benzyl -4, 5- dimethyl -6- (p-methoxybenzyl)-l,2,3,6-tetra- 
hydropyridine oxalate. 

Benzyl disulfide 

Benzyl ether (Dibenzyl ether) 

N-Benzyl-N-ethyl-m-toluidine 



Manufacturers' identification codes 
(according to list in table 3) 



MIL. 




MIL, TCH, USR. 




DUP, TRC. 




AC, ACS, ACY, DUP, 


TRC, VPC 


DUP, SDC. 




GAF. 




SDC. 




TCH. 




ASL. 




AC, DUP. 




DUP. 




AC. 




AC, DUP, GAF, TRC, 


VPC. 


DUP. 




DUP, GIV. 




ACS. 




EK. 




DUP, SIV. 




x. 




TRC. 




DUP, TRC. 




TRC. 




SW. 




DUP. 




HN, MNR, UOP. 




PD. 




AC. 




TRC. 




TRC. 




TRC. 




DUP. 




AC, ACY, DUP, MAY, 


TRC. 


EK, NES. 




NES. 




NES, 'uSR. 




DUP. 




ACC. 




UOP. 




ACS. 




LAK. 




LEM. 





HN, KLM, PFZ, VEL. 



BPC 






VEL 






SDC 






USR. 






ACY 


GYR, 


USR, X. 


SW. 






x. 






ACY, 


DUP, 


GAF. 


HK, 


VEL. 




DUP. 






SDW. 






ARS, 


X. 




SDW. 






CCW. 






ACS, 


nup. 





CYCLIC INTERMEDIATES 



TABLE 1. --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



3- Benzyl - 1,2,3' ,4,5, 6-hexahydro- 8-hydroxy- ci s- 6 ,11- 

dimethyl-2 ,6-methano-6-benzazocine hydrobromide. 

6-Benzylidineaminopenicillanic acid 

4,4 '-Benzylidenedi-o-toluidine 

Benzyl idene phthalide 

p- (Ben zyloxy) phenol 

l-Benzyl-4-phenylisonipecotic acid 

N-Benzyl-4-phenylisonipecotonitrile 

Benzyltrimethyl ammonium chloride 

Benzyl trimethylammonium hydroxide 

Benzyltrimethyl ammonium methoxide 

[3,3'-Bianthra[l,9-cd]pyTazole]-6,6'-(2H,2'H)dione 

(Pyrazoleanthrone yellow). 

[3,3' -Bi -7H-benz[de] anthracene] -7, 7 '-di one 

*[4,4'-Bi-7H-ben2[de]anthracene]-7,7'-dione 

*Biphenyl 

(1, 1-Biphenyl) -4, 4 -diamine dihydrochloride 

3' -[Bis(2-acetoxyethyl)amino]-p-acetoanisidide 

Bis-p-aminocyclohexylme thane 

Bis (2-aminophenyl) disulfide 

1,4 -Bis [l-anthraquinonylamino]anthraquinone 

1 ,4-Bis [l-anthraquinonylamino]anthraquinone and 1,4-Bis 

[5-chloro-l-anthraquinonylamino]anthraquinone (mixed) . 

1 ,5- Bis [1-anthraquinonylamino] anthraquinone 

2, 6- Bis (p-azidobenzylidene)-4-methylcyclohexanone 

a^ ,a'-Bis [5-tert-butyl-6-hydroxy-ra-tolyl]mesitol 

4,4 '-Bi5[diethylamino]henzhydrol salt, 2,7-naphthalene- 

disulfonic acid, mixture. 
4,4 ' -Bis [diethylamino]benzophenone (Ethyl ketone base) — 
4-Bis [ (p-diethylaminophenyl)methyl] -2 , 7-naphthalene- 

disulfonic acid, leuco form. 

4,4' -Bis[dimethylamino]benzhydrol (Michler's hydrol) 

*4,4'-Bis[dimethylamino]benzophenone (Michler's ketone) — 

3, 3' -Bis [3' ,3'- (l'-ethyl-2' -methyl )indolyl] phthalide 

3' -[Bis (2-hydroxyethyl)amino]acetanilide 

5- [Bis (2-hydroxyethyl) amino] -2,2'-chloro-4-nitro- 

phenylazobenzanilide. 
3' -[ Bis (2-hydroxyethyl) amino] methanesulfoanilide, 

diacetate ester. 
4,4' -Bis[(p-hydroxyphenyl)azo] -2,2'-stilbenedisulfonic 

acid (C.I. Direct Yellow 4). 
4, 4 '-Bis [4-methoxy-3-methylbenzamido] -2,2'-stil- 

benedisulfonic acid. 
1 ,4-Bis [2- (4-methyl-5-phenyloxazolyl) ]beniene (Dimethyl 

POPOP) . 

Bis- (o-nitrophenyl) sulfide 

1,4-Bis[2- (5-phenyloxazolyl)]benzene (POPOP) 

2,4-Bis(xylazo)resorcinol 

3' -Bromoacetophenone 

p-Bromoaniline 

p-Bromoanisole 

*3-Bromo-7H-benz[de]anthracen-7-one (3-Bromobenzanthrone)- 

Bromoben zene , mono 

p-Bromobenzhydrol 

o-Bromobenzoic acid 

4-Bromobenzophenone 

Bromochlorobenzene 

6-Bromo-5-chlorobenzoxazolone 

2-Bromo-6-chloro-4-nitroaniline 

*2-Bromo-4,6-dinitroaniline 

l-Bromo-4- (methyl amino) anthraquinone 

1 - Bromonaphthal ene 

2-Bromo-4'-nitroacetophenone 



TRD. 

ACY. 

LIL. 

EK. 

SDW. 

SDW. 



DUP. 

ACY, DUP, MAY. 

CHL, DOW, GOC, MON, SNT. 

XI 

TCH. 

DUP. 

SDC. 

ACY, DUP, TRC. 

TRC. 



DUP. 



ACY. 
TRC. 



DSC, SDH. 
TRC. 



DSC, DUP, X. 

X. 

GAP. 
DUP. 

DUP. 

TRC. 

DUP. 

ARA. 



ARA. 

DUP. 

LIL. 

EK. 

OPC. 

ACY, DUP, MAY TRC. 

DOW. 

PD. 

PD, RSA. 

PD. 

DOW. 

SW. 

AC, DUP. 

AC, HST, SDC, TRC. 

BDO. 

EK. 

GAP. 



SYNTHETIC ORGANIC CHEMICALS, WL\ 



TABLE 2.— Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 197'|--C0NTINUED 



a- Bromo-p-nitro toluene 

p-Bromophenol 

(p-Bromophenyl)acetonitrile 

4- Bromo- 1 -phthal imi dopent ane 

4-Bromoresorcylic acid 

p-Bromotoluene 

l-Bromo-2,4,6-triethylbenzene 

p-Butoxvphenol 

N- Butyl aniline 

p- Butyl aniline 

2- (N-Butylanilino)Dropionitrile 

3- (N-Butylanilino)pronionitrile 

2-tert-Butylanthraquinone 

p-tert-Butylbenzaldehyde 

n-Butylbeniene 

sec-Butvlbenzene 

tert-Butylbenzene 

p-tert-Butylbenzoic acid 

o- (p-tert-Butylbenzoyl} benzoic acid 

2-tert-Butyl-p-cresol 

6-tert-Butyl-m-cresol 

p-(n-Butylcyclopentadienyl) eye lopentadienyl iron 

2 ' - tert - Buty 1 -4 ' , 6 ' - dimethy lacetophenone 

Butyl dimethy Icresol 

2-tert-Butyl-4-ethylphenol 

tert- Buty Ihydroquinone 

4,4' -Butylidenebi5[6-tert-butyl-m-cresol] 

N'-Butyl-4-methoxyraetanilamide 

2-tert-Butyl-5-methylanisole 

o-sec-Butylphenol ■ --^-- .- ^. 

o- tert- Buty Iphenol 

p- tert- Buty Iphenol 

Butylphenols, mixed 

p -tert- Butyl toluene 

5- tert- Buty 1-1 ,2,3-trimethylbenzene 

5-tert-Butyl-m-xylene 

6-tert-Butyl-2,4-xylenol 

d-10-Camphorsulfonic acid 

Camphosulfonic acid 

Carbazole, refined 

4,4' -Carbonylbis [phthalic anhydride] 

6-Carboxy fluorescein 

3-Carboxy-4-hydroxy-4 * -aminoazobenzene, sodium salt- 
2- (p-Carboxyphenoxy) -2-pivaloyl-2 , (4) -dichloroaeet- 
anilide. 

Cedrene 

2 ' -Chloroacetoacetanilide 

2'-Chloroacetophenone 

3'-Chloroacetophenone 

4 ' - Ch 1 oroacetophenone 

4'- CChloroacetyl)acetanilide 

9-Chloroacridine 

m-Chloroani line 

o-Chloroaniline 

p-Chloro aniline 

2- (m-Chloroanilino)diethanol 

3- (o-Chloroanilino)propionitrile 

5-Chloro-o-anisidine hydrochloride 

1-Chloroanthraquinone 

2-Chloroanthraquinone 

o-Chlorobenzaldehyde 



Manufacturers' identification codes 
(according to list in table 3) 



BPC. 

EK. 

BPC. 

pn. 

PCW. 

BPC, EK. 

DUP. 

ARB. 

DUP. 

DUP. 

MIL. 

TCH. 

DUP. 

GIV. 

EK, PLC. 

PLC. 

EK, PLC, UOP. 

SHC. 

DUP. 

ACY. 

KPT, PRD. 

ARA. 

GIV. 



DUP. 




ALL. 




GIV. 




TNA.- 




tna. 




DOW, PRD, SCN, UCC 


DOW, SCN. 




GIV, SHC. 




GIV. 




GIV. 




PIT. 




OTC. 




KF, LIL. 




SDC. 




PCR. 




EK. 




ACS. 




EK. 




GIV. 




HST. 




EK. 




EK. 




LIL. 




DUP. 




EK. 




DUP, GAP. 




DUP, MON. 




DUP, MON. 




MIL. 




DUP, TCH. 




ALL, GAP. 




DUP, TRC. 




ACY. 




HN. 





CYCLIC INTERflEDIATES 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1974--CONTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



p-Chlorobenzaldehyde 

o-Chlorobenzajnide 

Chloro-7H-benz[de]anthracen-7-one CChlorobenzanthrone)- 

*Ch 1 oroben zene , mono 

p-Chlorobenzenesulfinic acid 

p-Chlorobenzenesulfonamide 

p-Chlorobenzenesul£onic acid and sodium salt 

o-Chlorobenzoic acid 

o-Chlorobenzonitrile 

2- Chi oroben zoxazole 

o- (p-Chl oroben zoyl) benzoic acid 

-Ch 1 oroben z oyl chloride 

p -Ch 1 oroben z oyl chloride 

4,4'-(o-Chlorobenzylidene)di-2,5-xylidine 

a- (p-Chlorobenzyl)-a-phenyl-l-pyrrolidine propanol 
hydrochloride. 

Chloro(p-chlorophenyl)phenylme thane 

Chlorocyclohexane 

Chlorocyclopentane 

4-Chloro-2-cyclopentylphenol 

l-Chloro-2 ,5-diethoxy-4-nitrobenzene 

2-Chloro-N,N-diethyl-4-nitroaniline 

2-Chloro-3' ,4 ' -dihydroxyacetophenone 

2-Chloro-l ,4-dihydroxyanthraquinone 

4'-Chloro-2' ,5' -dimethoxyacetoacetanilide 

4-Chloro-2,5-dimethoxyaniline 

5-Chloro-2,4-dimethoxyaniline 

l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene) 

3-Chloro-4,6-dinitrobenzenesulfonic acid 

4-Chloro-3, 5-dinitrobenzenesulfonic acid, potassium 
salt. 

4-Chloro-3,5-dinitrobenzoic acid 

3-Chlorodiphenylamine 

5-Chloro-2,4-di5ulfamylaniline 

3-Chloro-4-hydroxyquinoline-3,4-carbonic acid 

7-Chloro-4-hydroxyquinoline hydrochloride 

4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide 

4-Chlorometani lie acid 

6-Chlorometanilic acid 

p - (Ch lororae thy l)ani sole 

l-Chloro-2-methylanthraquinone 

6-Chloro-4-methylbenzo[b]thiophene-2-ol 

a-Chloromethylnaphthalene, crude 

4-Chloro-N-methyl-3-nitrobenzene5Ulfonamide 

Ch loromethy Ipheny 1 ether 

5-Chloro-2-(N-methylsulfamoyl)-4-sulfamyl-N-benzyl- 
aniline. 

2-Chloro- 5- (N-methylsulfamoyl) sulfanilamide 

Chloronaphthalenes 

2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline) 

4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline) 

l-Chloro-5-nitroanthraquinone 

l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene) 

l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene) 

l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene) 

2-Chloro-5-nitrobenzenesulfinic acid 

*4-Chloro-3-nitrobenzenesulfonamide 

4-Chloro-3-nitrobenzenesulfonanilide 

2-Chloro-5-nitrobenzenesulfonic acid 



PD. 
ACY 
ACS 
TRC 
ACY 
EK, 
HN. 



, TRC. 

, DOW, MON, MTO, PPG. 



NES. 
MTR, NES. 



HN. 

GAF. 

LIL. 

OPC, UOP. 

ACY. 

PD. 

DOW. 

GAF. 

DUP. 

SDW. 

HSH. 

PCW. 

PCW. 

PCW. 

AC, SDC. 

TRC. 



GAF. 

SK. 

NES. 

SDH. 

PD. 

TRC. 

ACS, DUP. 

AC. 

SDW. 

ACY, DUP, TRC. 

ACY. 

BPC. 

TRC. 

BPC. 

ABB. 



ABB. 

KPT. 

DUP. 

DUP. 

TRC. 

DUP, 

DUP. 

DUP, 

TRC. 

AC, 

TRC. 

ACS, 



MON. 
MON. 
DUP, GAF, ICC, TRC. 
TRC. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2.— Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 197'<--CONTINUED 



2-Chloro-5-nitrobenzenesulfonic acid, sodiun salt 

4-Chloro-3-nitroben2enesulfonic acid 

4-Chloro-3-nitrobenzenesulfonyl chloride 

2-Chloro-4-nitrobenzoic acid 

2-Chloro-4-nitrobenzoic acid, potassium salt 

2-Chloro-5-nitroben2oic acid 

2-Chloro-5-nitrophenyl methyl sulfone 

4-Chloro-3-nitrophenyl methyl sulfone 

2-Chloro-4-nitrotoluene 

2-Chloro-6-nitrotoluene 

4-Chloro-2-nitrotoluene 

4-Chloro-3-nitrotoluene 

o-Chlorophenol 

p-Chlorophenol 

2-ChloTophenothiazine 

(p-Chlorophenyl)acetonitrile 

4-Chloro-a-phenyl-o-cresol 

4-Chloro-o-phenylenedi amine 

2,2'-[Cm-Chlorophenyl)imino]diethanol 

2,2'-[(m-Chlorophenyl)iiiiino]diethanol, diacetate ester-- 
3-Co-Chlorophenyl)-5-methyl-4-isoxa2ole carbonyl 
chloride. 

l-(iii-Chlorophenyl)-3-iaethyl-2-pyrozolin-5-one 

l-(o-Chlorophenyl)-3-methyl-2-pyrazolin-5-one 

l-(p-Chlorophenyl)-3-methyl-2-p>Tazolin-5-one 

p-Chlorophenyl methyl sulfone 

2-Chloro-4-phenylphenol 

4-Chlorophthalic acid 

4-Chlorophthalic acid, monosodium salt 

3-Chloropropenylbenzene (Cinnaml chloride) 

l-(3-Chloropropyl)-4-raethylpiperazine 

7-Chloro-4-quinolinol 

4-Chlororesorcinol 

5-ChloTosalicylaldehyde 

2-Chloro-5-sulfainoylbenzoic acid 

p-Chlorothiophenol 

m-Chlorotoluene 

p-Chlorotoluene 

a-Chlorotoluene (Benzyl chloride) 

3-Chloro-o-toluidine [>«H2=1] 

3-Chloro-p-toluidine [NH2=li 

S-Chloip-o-toluidine [NH2=1] C4-Chloro-o-toluidine 
[CH3=1]). 

N-[(5-Chloro-o-tolyl)azo]saxcosine 

l-(Chloro-o-tolyl)-3-iaethyl-2-pyTazolin-5-one 

l-(6-Chloro-o-tolyl)-3-methyl-2-p\-razolin-5-one 

p-Chloro-3,3,a-trifluorotoluene 

Chlorotriphenylme thane 

a-Chloro-o-x>'lene 

2-Chloro-p-x>-lene 

4-Chloro-5,5-x>lenol 

Cholester>l nonanoate 

Cholest>Timine resin 

Cholic acid 

Cinnamic acid 

CinnaiBoyl chloride 

♦Cresols:^ 

m-Cresol 

*o-Cresol: 

From coal tar 

From petroleum 

p-Cresol 



Manufacturers' identification codes 
(according to list in table 3) 



DUP. 

ACS, TRC. 

AC, SDC. 

SAL. 

SAL. 

TRC. 

TRC. 

TRC. 

DUP. 

DUP. 

DUP. 

DUP. 

DOW. 

DOK, MON. 

SK. 

OPC, UOP. 

MON. 

FMT. 

TCH. 

SDC. 

.ARS. 

TRC. 

HST. 

HST, TRC. 

TRC. 

DOK. 

SW. 

HSC. 

SDK. 

SK. 

SDK. 

AC. EK, a^F. 

EK. 

TRC. 

SFA. 

HK, HN. 

HN. 

BPC, MON, VEL. 

DUP. 

DUP. 

DUP. 

ALL. 

TRC. 

HST. 

HK. 

EK. 

BPC. 

DUP. 

FER. 

EK. 

MRK. 

hlL. 

BPC. 

EK, UOP. 

KPT. 

EKT. PRD, SK. 
MER, PRD. 
SK. 



CYCLIC IfJTERflEDIATES 



TABLE 2, --Cyclic intermediates for which U.S. 

IDENTIFIED BY MANUFACTURER. 



PRODUCTION OR SALES WERE REPORTED. 
197'|--CONTINUED 



*Cresols --Continued 

Cresols, mixed: ^ 

*(m,p)-Cresol: 

From coal tar 

From petroleum 

(o,m,p)-Cresol: 

From coal tar 

Other 

*Cresylic acid, refined:' 

From coal tar 

From petro leum 

*Cumene 

Cumene hydroperoxi de 

2-[p-CCyanoacetamido)phenyl]-6-methyl-7-benzothiazole- 
sulfonic acid. 

Cyanoacetic acid, 2-ethylhexyl ester 

4- [(2-Cyanoethyl) ethyl amino ]-o-tolualdehyde 

p-[(2-Cyanoe thy 1) methyl ami no] benzaldehyde 

*Cy cl ohexane 

1,2-Cyclohexanedicarboxylic anhydride 

1,3-Cyclohexanedione 

Cy cl ohexano 1 

*Cy c 1 ohexanone 

Cyclohexanone oxime 

Cyclohexene 

4-Cyclohexene-l,2-dicarboximide 

4-Cyclohexene-l,2-dicarboxylic anhydride 

Cyclohexene oxide 

8-(l-Cyclohexenyl)ethylainine 

Cyclohexyl amine 

p-(Cyclohexyloxy) benzoic acid 

Cyclohexyl-2-propanone 

N-Cyclohexyltaurine, sodium salt 

Cy cl opent ad ieny liron 

Cyclopentamine base 

Cy c lopent ene 

(2-Cyclopenten-l-yl) -2-propanone 

p -Cymene 

Decachlorodicyclopentadiene 

Deoxycholic acid 

Diacenaphtho [ 1 , 2- j : 1 , 2 ' - !,] f luoranthene (Decacyclene) — 

1,5 (and 1 ,8)-Diacetamidoanthraquinone 

3,5-Diacetamido-2,4,6-triiodobenzoic acid 

3-[Di-(2-acetoxyethyl)amine]-p-acetophenetidide 

N',N^ -Dial lylmel amine 

Diallylchlorendate 

*1 ,4-Diaminoanthraquinone 

1,5-Diaminoanthraquinone 

1 ,5 (and 1,8)-Diaminoanthraquinone 

2,6-Diaminoanthraquinone 

2,4-Diaminobenzenesulfonic acid [S03H=1] 

2,5-Diaminobenzenesulfonic acid [S03H=1] 

4,4'-Diamino-2,2'-biphenyldisulfonic acid 

1 ,4-Diamino-2,3-dichloroanthraquinone 

*1 ,4-Diamino-2,3-dihydroanthraquinone 

4 ,8-Diamino-9 , 10-dihydro- 1 ,5-dihydroxy-9 , lO-dioxo-2 ,6- 

anthracenedisulfonic acid. 
1 ,4-Diamino-9 , lO-dihydro-9 , lO-dioxo-2 ,3-anthracenedi- 
carboximide. 

l,S-Diamino-4,8-dihydroxyanthraquinone 

2,4-Diamino-6-phenyl-s-triazine 

2,6-Diaminopyridine 

*4,4'-Diamino-2,2'-stilbenedisulfonic acid 



Manufacturers' identification codes 
(according to list in table 3) 



KPT, PRD. 






MER, PRD. 






KPT. 






PIT. 






KPT, PRD. 






MER, NPC, PRD, SHO. 






ASH, CLK, CSP, DOW, GOC 


MOC, 


MON, SKO, SNT 


see, TX, UCC. 






USS. 






DUP. 






GAF. 






DUP, GAF. 






DUP, GAF. 






CSD, ENJ, GOC, GRS, PLC 


PPR, 


SWC, TX, UOC. 


ACS. 






PD. 






ALF, CNP, DUP, MON. 






ALF, CEL, CNP, DBC, DUP 


MON, 


.UCC. 


CNP. 






EK, PLC, USR. 






SFC. 






PTT. 






USR. 






X. 






ABB, MON, RBC, VGC . 






LIL. 




•- 


GIV. 






GAF. 






ARA. 






LIL. 






ARA. 






LIL. 






HPC. 






X. 






WIL. 






SDC. 






AC. 






SOW. 






TRC. 






ACY. 






SAR. 






DUP, SDC, TRC. 






ACY. 






AC. 






AC, TRC. 






DUP, TRC. 






TRC. 






ACY. 






DUP. 






AC, ACY, DUP, HSH. MAY, 


TRC. 




TRC. 







DUP. 

VPC. 

RH, VEL. 

NEP, RIL. 

ACY, CGY, DUP, GAF, SDH, TRC. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2,--Cyclic intermediates for which U.S. production -or sales were reported^ 

IDENTIFIED BY MANUFACTURERy 1971--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



3,S-Diamino-2,4,6-triiodobenzoic acid 

l,4:3,6-Dianhydroglucitol 

2,5-Dianilinoterephthalic acid 

1,5-Dibenzainidoanthraquinone 

4,5' - Diben zami do- 1 , 1 ' - iminodianthraquinone 

Dibenzothiophene 

1 ,S-Dibenzoylnaphthalene 

2- (N,N-Diben2yl)amino-4-acetaiiiidoanisole 

Dibenzylazodicarboxylate 

N,N'-Dibenzylethylenediamine 

N,N'-Dibenzyle thy lenedi amine diacetate 

N.N'-Dibenzylidenetoluene-a.a-di amine 

3 , 4- Dibenzy loxybutyrophenone 

3,9-Dibromo-7H-benz[de]anthracen-7-one 

p-Dibromobenzene 

l,3-Dibromo-5,5-dimethylhydantoin 

ar- Dibromoethy Ibenzene 

2,6-Dibromo-4-nitroaniline 

2,6-Dibromo-4-nitrophenol 

a,a-Dibromo-p-nitrotoluene 

3,5-Dibromo-3'-trifluoromethylsalicylanilide 
(Fluorophene) . 

p-Dibutoxybenzene (DBB) 

2,S-Dibutoxy-4-morpholinobenzenediazonium sulfate 

l,l'-Di-n-butyldicyclopentadienyliron 

2,6-Di-tert-butyl-4-nonylphenol 

2,4-Di-tert-butylph end 

2,4-Dichloroaniline 

3,4-Dichloroaniline 

2,5-Dichloroaniline and hydrochloride [NH2=1] 

3-C2,4-Dichloroanilino)-l- C2,4,6-trichlorophenyl)-2- 
pyrazolin-5-one . 

1,5-Dichloroanthraquinone 

1,5 (and 1 ,8)-Dichloroanthraquinone 

2,6-Dichlorobenzal chloride 

Dichlorobenzanthrone 

o-Dichlorobenzene 

(and p) - Di ch lorobenzene 

p-Dichlorobenzene 

4,6-Dichloro-m-benzenedisulfonaraide 

4,6-Dichloro-m-benzenedisulfonyl chloride 

3,3'-Dichlorobenzidine base and salts 

2,2'-Dichlorobenzil 

2,4-Dichlorobenzoic acid 

2,4-Dichlorobenzoyl chloride 

Dichlorobenzyl chloride 

2,3-Dichloro-5,6-dicyanobenzoquinone 

2,4-Dichloro-3,5-dinitro-a,a,a-trifluorotoluene 

Dichlorodiphenylsilane 

2,5-Dichloro-4-hydrazinobenzenesulfonic acid 

2- (5,8-Dichloro-l-hydroxy-2-naphthylazo5-l-hydroxy- 
benzene- 4- sulfonamide. 

5,14-Dichloroisoviolanthrone 

Di (chloromethyl)diphenyl oxide 

2,5-Dichloro-4- (3-methyl-5-oxo-2-pyrazolin- l-yljbenzene- 
sulfonic acid. 

Dichloromethylphenylsilane 

2, 6-Dichloro-4-nitro aniline 

1 , 2- Dichloro- 4 -nitrobenzene 

1 ,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene) — 

2 , 4-Di ch 1 oropheno 1 

3- (2' ,6'-Dichlorophenyl)-5-raethyl-isoxazole-4-carbonyl 
chloride. 



SDW. 
ICI. 
x. 

trc. 

ACY, TRC. 

EK. 

TRC. 

SDC. 

WTL. 

WYT. 

WYT. 

SDH. 

SDW. 

DUP, MAY, TRC. 

DOW. 

ARA. 

DOW. 

HST, SDC. 

SW. 

DUP. 

PCW. 

ALL. 

ALL. 

ARA. 

GAF. 

DUP, PIT. 

EK. 

DUP, MON. 

DUP. 

EK. 



TRC. 

AC. 

DUP. 

ACY. 

ACS, 

MTO. 

ACS, 

ABB. 

ABB. 

CWN, 

MTO. 

HN. 

HN. 



DOW, MON, PPG. 
DOW, DVC, MON, PPG. 



BPC. 

ARA. 

GAF. 

DCC, UCC. 

CMG. 

TRC. 

CMG. 
BPC. 
ACY, HST, TRC. 

DCC. 

CWN, SW. 

DUP, EGR, MON. 

DUP. 

DOW, MON. 

OTC. 



CYCLIC INTERMEDIATES 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 197'!— CONTINUED 



2,6-Dichloropyra2ine 

3,6-Dichloropyridazine 

4,7-Dichloroquinoline 

2,5-Dichlorosulfanilic acid [S03H=1] 

2,5-Dichloro-4-sulfobenzenedia2oniuin sulfate 

p , a- Di ch loroto luene 

a,a-DichIorotoluene (Benzal chloride) 

2,6-Dichlorotoluene 

Dicyclohexylamine 

N,N'-3-Dicyclohexyl- 2- thiourea 

*Dicyclopentadiene (includes cyclopentadiene) 

Dicyclopentadiene dioxide 

Didodecylbenzene 

p-Diethoxybenzene 

Z-Diethylaminoacetanilide 

p-(Diethylaiiiino)benzaldehyde 

p-(Diethylamino)benzenediazonium chloride, zinc chloride 

salt. 

3'- [2- (Diethylaiiiino)ethyl]-4'-hydroxyacetanilide 

a-[ C2-Diethylaini no) ethyl] -a-phenylcyclohexanemethanol, 

hydrochloride. 

o-(Diethylamino)-4'-hydroxy-ni-acetotoluidide 

7 '-Diethyl amino- 4-me thy Icoumar in 

m-(Diethylaiiiino) phenol (N,N-Diethyl-3-aminophenol) 

3-[(4'-N,N-Diethylaraino)phenylazo]-lH-l,2,4-triazole 

3- (Diethyl amino) propiophenone 

4- (Diethylamino)-o-tolualdehyde 

*N,N-Diethyl aniline 

N,N-Diethyl-m-anisidine 

Diethylbenzene 

p-Diethylbenzene 

N,N-Diethylcyclohexyl amine 

1,1 -Diethyl -3- (m-hydroxyphenyl)urea 

n' ,N' -Diethyl -4-methoxymetanilamide 

N,N-Diethyl-p-nitrosoaniline 

N,N-Diethyl-4-nitroso-m-anisidine hydrochloride 

N,N-Diethyl-4-nitroso-m-phenetidine 

N,N-Diethyl-m-phenetidine- 

N,N-Diethyl-m-toluidine 

N,N-Diethyl-p-toluidine 

Di fur fury lidinepentaerythritol 

10, ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one 

2,3-Dihydro-l ,4-dihydroxyanthraquinone 

9, 10-Dihydro-l,4-dihydroxy-9, lO-dioxo-2-anthracene- 
sulfonic acid (2-Quinizarinsulfonic acid). 

9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid 

9 , lO-Dihydro-9 , 10-dioxo-l ,5-anthracenedisulfonic acid , 

disodium salt. 
9,10-Dihydro-9,10-dioxo-l,5(and l,8)-anthracene- 

disulfonic acid and salt. 
9 , lO-Dihydro-9 , 10-dioxo- 1 ,8- anthracenedi sulfonic acid, 

potassium salt. 
9,10-Dihydro-9,10-dioxo-2 ,6-anthracenedisulfonic acid 

and salt. 
9,10-Dihydro-9,10-dioxo-2,7-anthracenedisulfonic acid 

and salt. 
*9, lO-Dihydro-9, 10-dioxo- 1-anthracenesulfonic acid and 

salt (Gold salt) . 
9, 10-Dihydro-N- (3-hydroxy-2-anthraquinonly)-l-nitro- 

9, lO-dioxo-2-anthramide. 
9, 10 -Dihydro-5-nitro-9, 10-dioxo- 1-anthracenesulfonic 

acid. 
9,10-Dihydro-5(and 8 )-nitro-9, 10-dioxo- 1-anthracene- 
sulfonic acid. 



Manufacturers' identification codes 
(according to list in table 3) 



ACY 






ACY 






PD, 


SDW. 




CMG 


DUP 




TRC 






HN. 






BPC 






DUP 






ABB 


MON 


VGC. 


ABB 






ENJ 


GOC 


MON, UCC, VEL 


VEL 






CO. 






ALL 






DUP 






DUP 


EK, 


TRC. 


HST 






PD. 






ACY 






AC 






EK, 


GAF. 




ACY 


DUP 




TRC 






ACY 






DUP 






ACS 


ACY 


DSC, DUP. 


DUP 






DOW, 


DUP 


KPP. 


DOW. 






DUP. 






CWN. 






PCW. 






GAP. 






DUP. 






GAP. 






GAF. 






DUP. 






RSA. 






SDC. 






LIL. 






DUP. 






AC, 


HSH, 


MRT. 


ACY, 


TRC 




TRC. 






TRC. 






TRC. 






AC, 


TRC. 




TRC. 






AC, 


ACY, 


TRC. 


GAF. 






TRC. 






TRC. 







SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1974--CONTINUED 



Manufacturers ' identification codes 
(according to list in table 3) 



*1 ,4-Dihydroxyarthraquinone (Quinizarin) 

1,5-Dihydroxyanthraquinone (Anthrarufin) 

1,5 (and 1 ,8)-Dihydroxyanthraquinone 

1,8-Dihydroxyanthraquinone (Chrysazin) 

2,6-Dihydroxyanthraquinone (Anthraf lavic acid) 

2,4-Dihydroxybenzaldehyde 

2,5-Dihydroxybenzenesulfonic acid 

2,4-Dihydroxyb en zophenone 

3 , 4-Dihydroxybutyrophenone 

l,5-Dihydroxy-4,8-dinitroanthraquinone 

l,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro- 

chrysazin) . 

2,5-Dihydroxybenzenesulfonic acid, potassium salt* 

2,3-Dihydroxynaphthalene 

6,7-Dihydroxy-2-naphthalenesulfonic acid 

3,3' - Dihydroxy- 2-naphthani lide 

4,S-Dihydroxy-3- (p-sulfophenylazo) -2,7-naphthalene- 

disulfonic acid, trisodium salt. 

*16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone) 

m-Diiodobenzene 

Dii sop ropy Ibenzene 

2' ,5'-Diraethoxyacetoacetanilide 

2,4-Dimethoxyaniline 

2,5-Dimethoxyaniline 

1,5 (and 1 ,8) -Dimethoxyanthraquinone 

2,5-Dimethoxybenzaldehyde 

m-Dimethoxybenzene 

3,3'-Dimethoxybenzidine (o-Dianisidine) 

3,3' -Dimethoxybenzidine hydrochloride 

2,6-Dimethoxybenzoic acid 

N,N'- [(3,3' -Dime thoxy-4,4'-biphenylylene)bis(azo)]bis 

[N-methyltaurine] . 

Dimethoxyhydrazobenzene 

2,5-Dimethoxy-a-methylphenethylamine 

N-(3,4-Dimethoxy-a-methylphenethyl)-2-(3-methyl-4- 

ethoxypheny 1 ) acet amide . 

2,5-Dimethoxy-4' -nitrostilbene 

3,4-Dimethoxyphenethylamine (Homoveratryl amine) 

1- (3' ,4'-Dimethoxyphenyl)-2-nitropropene 

2,5-Dimethoxytetrahydrofuran 

2,5-Dimethoxytoluene 

16,17-Dimethoxyvi ol anthrone 

*p- (Dimethyl ami no) benzaldehyde 

m- (Dimethyl ami no)benzoic acid 

5- (p-Dimethylaminobenzylidene)rhodanine 

6-Dimethylamino-2-[2-(2,5-dimethyl-l-phenyl-3-pyrryl)- 

vinyl] -1-methyl-l-quinolinium methyl sulfate. 

6-Dimethylamino-l-methylquinaldinium methyl sulfate 

2- [ [2- (Dimethy 1 amino) ethyl] -2- thenylamino] -pyridine 

m- (Dimethyl amino) phenol 

11- [3- (Dimethylamino)propyl]-ll-hydroxy-dibenz(b,e) 

oxepin. 

6-Dimethlyaminoquinaldine 

2- (4 ' -Dimethylaminostyryl) -3-6-hydroxyethyl-5-methyl- 

thiadiazolium chloride. 

*N, N-Dime thy 1 aniline 

7, 12-Dime thy Ibenz [a] anthracene 

3,3'-Dimethylbenzidine hydrochloride 

*N, N-Dime thy Ibenzylamine 

a,a-Dimethylbenzyl hydroperoxide 

4-(a,a-Dimethylbenzyl)-2-phenol azophenol 



AC, 


ACY, DUP, HSH, ICC, MAY, TRC 


ACY, 


TRC. 


ACY, 


TRC. 


GAP, 


TRC. 


GAP, 


TRC. 


EK. 




EK. 




DUP, 


GAP. 


SDW. 




TRC, 


VPC. 


DUP. 




EK, 


NES. 


WAY. 




WAY. 




WAY. 




EK. 




ACY 


DUP, MAY. 


EK. 




DOW 


GYR. 


HST 




DUP 




EKT 


PCW. 


TRC 




CWN 


UPJ. 


ACY 


ARS. 


SDH 


UOP. 


CWN 




ARS 




GAP 





x. 

LIL. 

LIL. 

HEX. 

EK. 

MAY. 

ACS, DUP, GAP, TRC. 

SDH, SDW. 

EK. 



ABB. 
ACY. 
SK. 

EK. 
WAY. 

ACS 
EK. 



ACY, DSC, DUP. 



ARS, RH, 

CLK. 

TRC. 



CYCLIC INTERHEDIATES 



TABLE 2. 



-Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 197i|~CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



2,2'- Dimethyl - 1 , 1 ' -b i anthraquinone 

N,N-Dimethylcyclohexyl amine 

N,N-Dimethyl-dibenz(b,c5oxepin-A"(6H)a-propyl amine 

5,5-Dimethylhydantoin 

2, 3-Di methyl indole 

D,L-cis, trans -2, 2- Dimethyl -3- isobutenyl eye lopropane- 

1-carboxylic acid, ethyl ester. 
2 ,5-Diraethyl-4 (2) -morpholinylmethylphenol , hydrochloride- 

N,N-Dimethyl-l-naphthylamine 

N,N-Dimethyl-p-nitrosoaniline 

N,N-Dimethyl-p-phenylenedi amine 

N, N- Dime thy 1-p-phenylenedi amine monohydrochloride 

N,N-Dime thy 1-p-phenylenedi amine sulfate 

2,5-Dimethyl-l-phenylpyrrole 

2,5-Dimethyl-l-phenyl-3-pyrrolecarboxaldehyde 

1,4-Dimethylpiperazine 

N,N-Dimethylsulfanilic acid 

N,N-Dimethyl-o-toluidine 

N,N- Dime thy 1-p-toluidine 

2,4-Dinitroacetanilide 

*2,4-Dinitro aniline 

p-C2,4-Dinitroanilino)phenol 

1 ,5 (and 1,8) -Dinitroanthraquinone 

N,N'-(2,4-Dinitro-l ,5-anthraquinonylene)dioxamic acid 

m-Dinitrobenzene 

2,4-Dinitrobenzenesulfonic acid 

2,4-Dinitrobenzenesulfonic acid, sodium salt 

3,5-Dinitrobenzoic acid 

3,5-Dinitrobenzoyl chloride 

10, 10' -Dinitro[3,3'-bi-7H-benz[de] anthracene] -7,7'- 
dione. 

Dinitrocaprylphenol 

2,4-Dinitrocumene 

3,5-Dinitro-N'' ,N'*-diisopropylsulf anil amide 

l-(3,5-Dinitro-2-hydroxphenylazo)-2-hydroxynaphthalene — 

2,6-Dinitro-4-isopropylphenol 

2,4-Dinitrophenol , tech 

3,5-Dinitrosalicylic acid 

*4,4'-Dinitrostilbene-2 ,2'-disulfonic acid 

Dinitrostilbenedi sulfonic acid 

2,4-Dinitrotoluene 

* 2, 4 (and 2,6)-Dinitrotoluene 

D inony Iphenol 

Di-tert-pentylphenol 

Di-tert-pentylphenoxyacetyl chloride 

1 , 5- Diphenoxyanthraquinone 

1 , S (and 1,8) - Diphenoxyanthraquinone 

Diphenylacetonitrile, tech 

*Diphenylamine 

2,5-Diphenyl-p-benzoquinone 

2, 2 '-Dipheny 1-4- dimethyl amine 

N,N'-Diphenylethylenedi amine 

2 , 5-Dipheny Ihydroquinone 

Dipheny Imethane 

2,5-Diphenyloxazole 

4,7-Diphenyl-l,10-phenanthroline 

1,3- Dipheny 1-1,3-propanedione 

2,2'-Dithiodibenzoic acid 

1,4-Di-p-toluidinoanthraquinone 

p-Ditolylmercapto-2 ,5-diethoxybenzenediazonium chloride, 

zinc chloride salt, 
Divinylbenzene 



ACY, DUP, TRC. 

ABB, DUP, JCC. 

SK. 

GLY. 

DUP. 

BPC. 

WAY. 

EK. 

ACY. 

EK, EKT. 

EK. 

EK. 

EK. 

EK. 

JCC. 



RSA 






EK, 


RSA, 


SAR 


SDC 






AC, 


HST, 


SDC 


GAP 


SDC 




AC, 


TRC. 




AC, 


TRC. 




DUP 






EK, 


TRC. 




EK, 


NES. 




SAL 






EK. 






DUP 


MAY 




RH. 






DUP 







SDC, 


VPC. 






EK, 


SAL. 






AC, 


ACY, 


DUP, 


GAP, SDH, TRC 


CGY. 








ACS, 


DUP 


RUC 




AIP, 


DUP, 


MOB 


UCC. 


GAP, 


JCC. 






PAS. 








EK. 








AC. 








ASH. 








ACY, 


DUP 


ORO 


RUC, USR. 


EK. 








LIL. 








RPC. 








EK. 








PD. 








ARA 


EK. 






EK. 








EK. 








LIL 


SW. 






TRC 








HST 








DOW 


EG. 







SYNTHETIC ORGANIC CHEMICALS. 197^' 



TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--C0NTINUED 



Dodecylbeniene. (See Alkylbenzenes. ) 

Dodecylbenzyl chloride 

Dodecy Imethy Ibenzy 1 chlori de 

Dodecyl nitrobenzene 

p-Dodecylphenol 

1,2- Epoxy- 3-phenoxypropane 

o-Ethoxybenzoic acid 

N-(p-Ethoxybenzylidene)-p-butyl aniline 

4-Ethoxy-3-methoxybenzaldehyde 

4-Ethoxy-3-iiiethoxybenzyl alcohol 

(4-Ethoxy-3-methoxyphenyl) acetic acid 

2-Ethoxy-l-naphthoyl chloride 

n' - (6-Ethoxy-3-pyridazinyl)sulfanilamide 

3- (E thy 1 amino) -p-cresol 

N-Ethyl-N- (g-aminoethyl)-m-toluidine 

3- (Ethylaniino)-p-toluenesulfonic acid [SOsH^l] 

*N-Ethylaniline, refined 

*2-(N-Ethylanilino)ethanol 

[2- (N-Ethylanilino)ethyl]trimethylammonium chlori de--- 

3-(N-Ethylanilino)propionitrile 

a- (N-Ethylanilino)-m-toluenesulfonic acid 

a- (N- Ethylani lino) -p- toluene sulfonic acid 

*Ethy Ibenzene 

Ethy Ibenzy 1 chloride 

N-Ethy 1 -N-( 2- chloroethyl) aniline 

2- (N-Ethyl-N- 6- cyanoethyl) -4- acetarainoani sole 

N-Ethylcyclohexylamine 

3,3'-Ethylenedioxydiphenol 

3-Ethyl-2-[5-(3-ethyl-2-benzothiazolinylidene)-l, 

3-pentadienyl] -benzothiazolium iodide. 
N- Ethy 1-N-glycerol-m-tolui dine 

2-[N-Ethyl-p-[(6-iiiethoxy-2-benzothiazolyl)azo]anilino] 

ethanol. 

N-Ethyl-N- (8-methylsulfonamidoethyl) -m-toluidine 

N- Ethy Imorpho line 

N-Ethyl-l-naphthylamine 

a-Ethyl-3-nitrocinnamic acid 

p-Ethylphenol 

Ethylphenylmalonic acid, diethyl ester 

•N-Ethyl-N-pheny Ibenzy 1 amine 

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MEP)--- 
6- Ethy 1-1, 2,3, 4-tetrahydro- 1,1,4, 4-tetramethyl- 
naphthalene. 

N-Ethyl-p-toluenesulfonamide 

N- Ethyl -m-toluidine 

N - Ethy 1-o-tolui dine 

2- (N- Ethy 1-m-toluidino) ethanol 

*3- (N-Ethyl-m-toluidino)propionitrile 

a- (N-Ethyl-m-toluidino) -m-toluenesulfonic acid 

l-Fluoro-2,4-dinitrobenzene 

d-2-Formamido-l-phenyl-l,3-propanediol 

4- Formyl-m-benzenedi sulfonic acid 

o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde) 

Furan 

Fur fury 1 alcohol 

Furfurylamine 

N-Glycolylarsanilic acid, sodium salt 

Glyoxanilide-2-oxime 

Hexab romoben zene 

Hexabromobipheny 1 

Hexachlorobenzene 

Hexachlorocyclopentadiene 



Manufacturers' identification codes 
(according to list in table 3) 



GAP, 


MON, 


X. 


DUP. 






ACY. 






EK. 






LIL. 






LIL. 






LIL. 






\m. 






ACY. 






DUP. 






x. 






DUP. 






ACS, 


ACY, 


DUP. 


DUP, 


MIL, 


TCH. 


DUP. 






MIL, 


TCH. 




GAP, 


SDH. 




ACS, 


TRC. 




ATR, 


CSD, 


DOW, LLP, FG, KPP, MCB, MON, PLC, SKC, SNT 


SOG, STY, TOC, UCC. 


BPC. 






DUP. 






SDC. 






ABB. 






WAY. 






EK. 






EK. 






TRC. 






X. 






UCC. 






DUP. 






SDW. 






ACY. 






MAL. 






ACS, 


DUP, 


SDH. 


UCC. 






GIV. 






NES. 






DUP. 






DUP. 






TCH. 






DUP, 


MIL, 


TCH. 


ACS, 


GAF. 




EK. 






PD. 






GAF 






SDH 






PLC 


QKO 




QKO 






X. 






SDW 






DUP 






MCH 


NES 




MCH 






DVC 






HK, 


VEL. 





CYCLIC INTERMEDIATES 



TABLE 2. 



-Cyclic intermediates for which U.S, production or sales were reported, 
identified by manufacturer. 197'|--conti nued 



Manufacturers' identification codes 
(according to list in table 3) 



l,4,5,6,7,7-Hexachloro-5-norbomene-2,3-dicarboxylic 

acid. 
l,4,5,6,7,7-Hexachloro-S-norbornene-2,3-dicarboxylic 

anhydride. 

Hexafluorobenzene 

1,2,3,4, 5 ,6-Hexahydro-8-hydroxy-cis-6 , 1 l-dimethyl-2 ,6- 

inethano-2-benzazocine. 

Hexahydro-l-methyl-4-phenyl-lH-azepine-4-carbonitrile 

Hexamethylenimine 

Hippuric acid 

p-Hydrazinobenzenesulfonic acid 

p-Hydrazinobenzoic acid 

Hydrazobenzene 

*Hy droquinone , tech 

3'-Hydroxyacetophenone 

p-Hydroxybenzaldehyde 

p-Hydroxybenzenesulfonic acid 

p-Hydroxybenzoic acid 

3'-Hydroxy-2- (N-benzyl-N-methylaraino)acetophenone 

hydrochloride. 

4-Hydroxycoumarin 

2-Hydroxy-3,5-diiodobenzoic acid 

4- (2-Hydroxyethoxy)acetanilide 

m- ( g-Hydroxye thoxy ) pheno 1 

3- [N-(2-Hydroxyethyl)anilino]propionitrile 

3- [N- (2-Hydroxyethyl)anilino]propionitrile, acetate 

3- [N- (2-Hydroxyethyl)anilino]propionitrile, benzoate 

N- (6-Hydroxyethyl)-2,4-dihydroxybenzaniide 

N-(B-Hydroxyethyl]-3,5-dihydroxybenzainide 

N-6-Hydroxyethyl-3-hydroxy-2-naphthainide 

N-(2-Hydroxyethyl)piperazine 

N- [7-Hydroxy-8- [ (2-hydroxy-5-nitrophenyl)azo] -1- 

naphthyl ] ace t amide . 

4-Hydroxy-4-i sop ropy Imetanilaraide 

4-Hydrox>'met anil amide 

4 -Hy droxyme t an ilanilide 

4-Hydroxymetanilic acid 

3' -Hydroxy -2 -(methyl amino) acetophenone 

*3-Hydroxy-2-methylcinchoninic acid 

4-Hydroxy-N'-niethy Imetanilaraide 

N- (Hydroxymethyljphthalimide 

3-Hydroxy-N- (3-N-morpholinopropyl)-2-naphthamide 

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodiura salt-- 

7-Hydroxy-l ,3-naphthalenedisulfonic acid 

7-Hydroxy-l ,3-naphthalenedisulfonic acid, disodiura salt-- 

8 - Hydroxy- 1 -naphthalene sulfonic acid 

8-Hydroxy-l-naphthalenesulfonic acid, Y-sultone 

6-Hydroxy-2-naphthalenesulfonic acid, and sodium salt 

3-Hydroxy-2-naphthoic acid (B.O.N.) 

3-Hydroxy-2-naphthoic acid, methyl ester 

N-(7-Hydroxy-l-naph thy l)acet amide 

1- (2-Hydroxy-l-naphthylazo) -6-nitro-2-hydroxynaphthalene- 

4-sulfonic acid. 
4-Hydroxy-7- (p-nitrobenzamido) -2-naphthalenesulfonic 

acid. 

2-Hydroxy-5-nitrometanilic acid 

1- (2-Hydroxy-4-nitrophenylazo)-2-hydroxynaphthalene 

2-Hydroxy-4-n-octoxybenzophenone 

o-[ (p-Hydroxyphenyl)azo] benzoic acid 

3-[ (4-(4-Hydroxyphenylazo)2,5-dimethoxyphenylazo) ]- 

benzenesulfamic acid. 

Hydroxypyridines 

N-Hydroxysuccinimide 

2-Hydroxy-4-sulfo-l-naphthalenediazonium hydroxide, 

inner salt. 



WHC. 






SDW. 






WYT. 






CEL, 


DUP. 




BPC. 






GAF, 


STG, 


WJ. 


EK. 






UK. 






CRS, 


EKT, 


GYR 


ARA, 


SDH, 


SDW 


DOW. 






PRD, 


UPF. 





EK. 






GAF. 






BJL. 






TCH. 






TCH. 






DUP. 






WAY. 






WAY. 






WAY. 






JCC. 






TRC. 






TRC. 






DUP, 


TRC. 




TRC. 






TRC. 






CTN. 






DUP, 


GAF, 


TRC. 


TRC. 






ACY. 






WAY. 






ACY, 


TRC. 




DL'P, 


TRC. 




ACY. 






VPC. 






TRC. 






ACY, 


TMS, 


TRC, WJ 


sue. 


PCW. 




PCW. 






GAF, 


TRC. 




TRC. 







GAF. 

TRC. 
TRC. 

ACY, CCW. 
EK. 
TRC. 

OMC. 



SYNTHETIC ORGANIC CHEMICALS. 197^1 



TABLE 2, --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--C0NTI NUED 



Manufacturers ' identification codes 
(according to list in table 3") 



2-Imidazolidinone 

2-Iiiiidazolidinone modifications 

l,l'-Iminobis[4-aminoanthraquinone] 

l,l'-Iminobis[4-henzainidoanthraquinone] 

l,l'-Iniinobis[5-benzamidoanthraquinone] 

7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid] 

l,l'-Iminobis[4-nitroanthraquinone] 

1,1 '-Iminodianthraquinone (1,1 '-Dianthrimide) 

Indole- 2 ,3-dione 

Isobutylbenzene 

♦Isocyanic acid derivatives: 

Bitolylene diisocyanate (TODI) 

p-Chlorophenyl isocyanate 

Dianisidine diisocyanate (DADl) 

Diphenylmethane-4, 4 '-diisocyanate (MDI) 

Phenyl isocyanate 

Polyisocyanates (complex) 

•Polymethylene polyphenyl isocyanate 

Toluene 2 ,4- diisocyanate 

Toluene 2,4- and 2,6-diisocyanate (65/35 mixture) — 
♦Toluene 2,4- and 2,6-diisocyanate (80/20 mixture)--- 

p-Toluenesulfonyl isocyanate 

Other 

2-lsonitrosoacetanilide 

Isophthalic acid (Benzene-1 ,3-dicarboxylic acid) 

Isophthalic acid, diallyl ester 

Isophthalic acid, dimethyl ester 

Isophthalic acid, diphenyl ester 

Isophthalonitrile 

Isophthaloyl chloride 

4,4' - Isopropylidenebis [2 ,6-dibromophenol] (Tetrabromo- 

hisphenol A) . 
5, 5'- Isopropylidenebis (2-hydroxy-ra-xylene, a, a' -diol) -- 

*4,4'-Isopropylidenediphenol (Bisohenol A) 

4 , 4 ' - 1 sopropy 1 idenediphenol , ethoxy 1 at ed 

4,4'-IsopropylidenediDhenol, propoxylated 

o- I sopropy Iphenol 

I s op ropv Ipheno Is, mixed 

4-Isopropyl-m-phenylenediajiiine 

I sovio Ian throne (Isodibenzanthrone) 

*Leuco quinizarin (1 ,4 ,9, 10-Anthratetrol) 

2,4-Lutidine 

3,4-Lutidine 

Malonanilide 

Mandelonitrile 

* Mel amine 

p-Mentha-1 ,4(8)-diene 

dl-p-Mentha-l,8-diene (Limonene) 

p-Menth-1-ene 

*Metanilic acid (m-Aminobenzenesulfonic acid) 

N-(p-Hethoxybenzylidene)-p-butylaniline 

6-Methoxymetanilic acid 

4 ' -Methoxy- 2- (p-methoxyphenyl) acetoohenone 

Methoxymethy Idipheny 1 oxi de 

N-(2-Methoxy-l-naph thy l)acet amide 

6-Methoxy-8-nitroquinoline 

m-Methoxypheno 1 

l-Methoxy-3-phenoxybenzene 

(p-Methoxyphenyl) acetic acid 

6-Methoxyquinoline 

1- (Methyl amino) anthraquinone 

1- (Methylamino)-4-p-toluidinoanthraquinone 



VAL. 

RH. 

ACY, TRC. 

ACY. 

TRC. 

GAP, TRC. 

TRC. 

TRC. 

DUP, TRC. 

PLC. 



UPJ. 



UPJ. 
UPJ. 

MOB, RUC, UPJ. 

MOB. 

MOB. 

BAS, DUP, GNT, MOB, OMC , RUC, UCC. 

UPJ. 

MOB, UCC. 



CWN, 

MOB. 

UPJ. 

MOB, 

MOB, 

MOB. 

JCC, 

DUP, 

DUP, 

ACS, 

CWN, 

DUP, 

TRC. 

ACC. 

FMP. 

MTR. 

BJL. 

SW. 

DUP. 

DOW. 



ARK. 

DOW, GE, SHC, UCC. 

ICI. 

ICI. 

TNA. 

FMP. 

DUP. 

TRC. 

AC, EKT, HSH, ICC, TRC. 

KPT. 

UCC. 

PCW. 



KF. 

ACS, 

GIV. 

ARZ, 

GIV. 

ACY, 

EK. 

GAF. 

ARA. 

BPC. 

TRC. 

PD. 

EK. 

EK. 

UOP. 

DUP. 

AC, / 

BDO. 



ACY, MLC. 
HPC, NCI. 
DUP, TRC. 



CYCLIC LNTERNEDIATES 



TABLE 2, —Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197^1— CONTI NUED 



N-Methy 1 ani line 

2- (N-Methy lanilino)ethanol 

3-(N-Methylanilino)propionitrile 

5-Methyl-o-anisidine [NH2=1] 

5-Methyl-o-anisidinesulfonic acid 

m-Me thy lani sole 

N-Methy lanthrani lie acid 

2-Methylanthraquinone 

2-Methylbenzothiazole 

N-Methy Ibenzylamine 

Methylbiphenyl 

N-Methy 1-N-carboxyanthrani lie anhydride 

3-Methylcholanthrene 

Methyl cyclohexane 

4-Methylcyclohexanone 

N-Methylcyclohexyl amine 

Methyl eye lepent ad iene 

N-Methyldicyelohexylamine 

N-Me thy leneani line 

5,5'-Methylenebis [anthranilie acid, dimethyl ester] 

4,4'-Methylenebis [2-chloroaniline] 

4,4'-Methylenebis [N,N-diethy lani line] 

*4,4'-Methylenebis [N,N-dimethylaniline] (Methane base) 

4,4'-Methylenebis(3-hydroxy-2-naphthoie acid) disodium 

salt. 

2,2'-Methylenebis(4-methyl-6-nonylphenol) 

4,4'-Methylenediamine salt complex 

4,4'-Methylenedianiline 

1 ,2-Methylenedioxybenzene 

l,2-Methylenedioxy-4-nitrobenzene 

5,5'-Methylenedisalicylie acid 

Methy Ihydroquinone 

2-Methyl indole 

2-Me thy 1 indole- 3- carboxaldehyde 

6-Methyl-2- (2-methyl-6-quinolyl) -7-benzothiazolesulfonic 

acid. 

N-Me thy 1-p-nitro ani line 

5-Methyl-4-nitro-o-anisidine 

4-Methyl-2-nitroanisole 

2-Methyl-S-nitroimidazole 

N-Methy 1-N-nitroso-p-toluenesulfonamide 

2-Methyl-S-norbomene-2 ,3-dicarboxylic anhydride 

5-Methyl-5-norbomene-2 ,3-dicarboxylic anhydride 

m- (3-Methyl-S-oxo-2-pyTazolin-l-yl)benzenesulfonairiide 

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonie aeid-- 
3-(3-Methyl-5-oxo-2-pyrazolin-l-yl) -1,5-naphthalenedi- 

sulfonic acid. 
6-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,3-naphthalenedi- 

sulfonie acid. 

2-Methyl-5-phenylbenzoxazole 

1-Methyl-l-phenylhydrazine 

l-Methyl-4-phenylisonipecotic acid 

4-Methyl-l-phenyl-3-pyrazolidinone 

*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z) 

1-Methylpiperazine 

3-Methyl-2-pyrazolin-5-one 

1 -Methy Ipyrrole 

*a-Methylstyrene 

ar-Methylstyrene (Vinyl toluene) 

2- (Methylsulfonyl) -4-nitroaniline 

3-Methylthiophene 

p-Methylthiophenol 

3-Methyl-l-p-tolyl-2-pyrazolin-5-one 

Naphthalene, solidifying at 79° C. or above (refined 

flake) (from domestic crude). 



Manufacturers' identification codes 
(according to list in table 3) 



ACY. 

MIL, TCH. 

DUP, MIL, TCH. 

SW. 

ACS. 

GIV. 

GIV. 

ACY. 

EK, FMT. 

SDW, X. 

DOW. 

X. 

EK. 

PLC. 

EK. 

ABB. 

ENJ. 

ABB. 

PCW. 

DUP. 

ACY, TRC. 
ACY, DUP, SDH. 
EK, PD. 

ACY. 

DUP. 

ACS, DOW, MOB, RUC. 

PD. 

PD. 

HN. 

EKT. 

TRC. 

GAP. 

DUP. 

ACY, EK. 

PCW. 

SW. 

RDA. 

EK. 

VEL. 

ACS. 

TRC, VPC. 

ACY, GAP, TRC. 

TRC. 

TRC. 



SDW. 

EK. 

ACY, 

JCC, 

DUP. 

DUP. 

ACS, 

DOW, 

TRC. 

SDW. 

CRZ. 

HST. 

KPT. 



DUP, SDH, VPC. 
UCC. 



CLK, DOW, GP, SKO, UCC, USS. 
FG. 



SYNTHETIC ORGANIC CHEMICALS, 1971 



TABLE 2. 



-Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. IG/il— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



2,7-Naphthalenedisulfonic acid 

1-Naphthalenesulfonic acid 

2-Naphthalenesulfonic acid 

1-Naphthalenesulfonic acid, sodium salt 

2-Naphthalene sulfonic acid formaldehyde condensate 

2-Naphthalenesulfonic acid, sodium salt 

2-Naphthalene sulfonyl chloride 

1 ,4,5,8-Naphthalenetetracarhoxylic acid 

Naphtha limide 

1-Naphthol (a-Naphthol) 

2-Naphthol, tech. (B-Naphthol) ' ; 

p-Naphtholbenzein 

Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid 

2-(2H-Naphth[l,2-d]triazol-2-yl5-4-(l,l,3,3-tetramethyl- 

butyl)phenol . 

1-Naphthylamine (a-Naphthyl amine) 

p- (2-Naphthylaraino)phenol (N- (p-Hydroxyphenyl)-2- 

naphthylamine) . 

(2-Naphthylthio) acetic acid 

Ni cot inonit rile (3-Cyanopyridine) 

3'-Nitroacetanilide 

4'-Nitroacetanilide 

2'-Nitro-p-acetanisidide -• 

4 '-Nitro-o-acetanisidide 

3 ' -Ni t roacetophenone 

4'-Nitro-4-amino-3-methoxyazobenzene 

m- Nit ro aniline 

o-Nitroaniline 

p-Nitroaniline 

2-Nitro-p-anisidine [NH2=1] 

4-Nitro-o-anisidine [NH2=1] 

o-Nitroanisole 

n-Nitroanisole 

5-Nitroanthranilic acid 

1-Nitroanthraquinone 

2- C4-Nitro-2-anthraquinonyl)anthra[2,3-d]-oxazole-5,10- 

dione. 

m-Nitrobenzaldehyde 

*Ni troben zene 

3'-Nitrobenzenesulfonanilide 

m- Ni troben zenesu If onic acid 

m-Nitrobenzenesulfonic acid, sodium salt 

p-Nitrobenzenesulfonyl chloride 

m-Nitrobenzoic acid 

o-Nitrobenzoic acid 

p-Ni troben zoic acid 

m-Nitrobenzoic acid, sodium salt 

2- (m-Nitrobenzoyl)-o-acetanisidide 

p-Nitrobenzoyl azide 

m-Nitrobenzoyl chloride 

m-Nitrobenzyl alcohol 

4- (p- Ni troben zyl) pyridine 

4'-Nitro-4-hiphenylcarboxylic acid 

2-Nitro-p-cresol 

2-Nitro-p- cymene 

Nitrodiphenyl amine 

5-Nitro-2-furanmethanediol, diacetate 

1-Nitronaphthalene 

3-Nitro-l ,5-naphthalenedisulfonic acid 

7 (and 8) -Nitronaphth[l ,2-d] [1 ,2,3]oxadiazole-5-sulfonic 

acid. 

p-Nitrophenethyl alcohol 

o-Nitrophenol 



IRC. 

TRC. 

ACY, EK. 

TRC. 

AC 

ACY. 

AC 

TRC. 

ACS. 

DUP, UCC 

ACY, DUP. 

EK. 

TRC, VPC. 



DUP. 
SDC. 



ACY. 

NEP. 

AC, DUP, TRC 

GAP, TRC. 

DUP. 

DUP. 

ARA, SDH. 

SDC. 

X. 

MON. 

AC, DUP, MON. 

DUP. 

DUP. 

DUP, MON. 

DUP. 

TRC. 

ACY, TRC 

GAP. 



SDH. 

ACY, 

AC. 

ACY, 

MON, 

EK. 

SAL. 

SAL. 

DUP. 

SAL. 

GAP. 

EK. 

ARS. 

DUP. 



DUP, FST, MOB, MON, RUC 



DUP, EK. 
MRA. 



DUP. 








sw. 








EK. 








ACY, 


MON. 






NOR. 








DUP. 








TRC. 








ACS, 


GAP, 


TRC, 


VPC 


PCW. 








DUP, 


MON. 







CYCLIC INTERMEDIATES 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported 

IDENTIFIED BY MANUFACTURER^ 1974— CONTINUED 



Manufacturers ' identification codes 
(according to list in table 3) 



p-Nitrophenol 

p-Nitrophenol , sodium salt 

4'- Cp-Nitrophenyl)acetophenone 

4-Nitro-o-phenylenediaiiiine 

2- (o-Nitrophenylazo)-p-cresol (0H=1) 

2- (o-Nitrophenylazo)-4,6-di-tert-amylphenol (0H=1) 

(p-Nitrophenyl) hydrazine 

2,2'- [ Cm-Nitrophenyl)iniino]diethanol 

p-Nitrophenyl isocyanate 

1- (m-Nitrophenyl) -5-oxo-2-pyrazoline-3-carboxylic 

acid. 

3-Nitrophthalic acid 

3-Nitrophthalic anhydride 

4-Nitrophthaliniide 

5-Nitrosalicylaldehyde 

4-Nitroso-2 ,6-di-tert-butylphenol 

4-Nitroso-N-ethyl-N- (g^methylsulfonamidoethyl) -m- 

toluidine . 

l-Nitroso-2-naphthol 

p-Nitrosophenol 

6-Nitrostyrene 

4-Nitro-4'-(5-sulfo-2H-naphtho[l ,2-d] tria^ol-2-yl)- 
2 ,2' -stilbenedisulfonic acid. 

3-Nitro-p-toluainide 

m-Nitrotoluene 

o-Nitrotoluene 

p-Nitrotoluene 

Nitrotoluene mixtures 

p-Nitroto luenesu 1 fonic acid 

*5-Nitro-o-toluenesulfonic acid [S03H=1] 

3-Nitro-p-toluenesulfonic acid 

2-Nitro-m-toluic acid 

3-Nitro-p-toluic acid, methyl ester 

2-Nitro-p-toluidine [NH2=1] 

5-Nitro-o-toluidine [NH2=1] 

4 -Nitro-m- xylene 

*Nonylphenol 

Oxalacetic acid, diethylester, (p-sulfophenyl) - 

hydrazone . 

Oxanilide 

*1- [(7-0xo-7H-benz[de] anthracene- 3-yl famine ]anthra- 

quinone. 
1,1' - [(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]- 

dianthraquinone . 
S-Oxo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl 

ester. 
5-0x0-1- (p-sulfophenyl) -2-pyrazoline-3-carboxylic acid 

(Pyrazolone T) . 

4,4'-0xydianiline 

Pentabromochlorocyclohexane 

Pentachloropyridine 

Pentamethylljenzene 

1,1,3,3,5-Pentamethylindan 

tert-Pentylbenzene 

o-,p-tert-Pentylbenzoylbenzoic acid 

p-Pentyloxybenzoyl chloride 

o-Pentylphenol (o-Amylphenol) 

p-Pentylphenol 

p-tert-Pentylphenol 

3,4,9 ,10-Perylenetetracarboxylic-3,4:9,10-diimide 

Phene thy 1 amine 

a-Phenethyl amine 

Phenethyl amine sulfate 

o-Phenethylbenzoic acid 



DUP, 


HON 


DUP. 




ASH 


DUP 


FMT. 




TRC. 




TRC. 




EK, 


RSA. 


DUP. 




EK. 




DUP, 


VPC 


EK. 




EK. 




SDC. 





ACY, 


SDC 






CWN. 








TRC. 








X. 








DUP, 


FST 






DUP, 


FST. 






DUP, 


FST 






AC, 


DUP, 


FST. 




CGY. 








ACY, 


DUP 


GAF, 


SDH 


TRC. 








SAL. 








SDH 








SW. 








PCW 


SDH 






DUP. 








GAF, 


JCC 


MCB, 


MON 


TRC. 








EK. 








ACY, 


DUP 


MAY, 


TRC 


MAY, 


TRC 







STG, VPC. 

DUP. 

DOW. 

DOW. 

SNT. 

GIV. 

DUP. 

DUP. 

EK. 

PAS. 

EK. 

PAS. 

ACS. 



SYNTHETIC ORGANIC CHEMICALS, 197^ 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 197i|--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



p-Phenetidine 

* Phenol : 
♦Natural : 

*From coal tar:^ 

39°C., m.p. 

All other 

*From petroleum 

•Synthetic : 

By caustic fusion: U.S.P 

From chlorobenzene by liquid-phase hydrolysis: 
U.S.P 

*From cumene by oxidation; U.S.P 

Other 

Phenolsulfonaphthalein, sodium salt 

Phenolsulfonic acid, lithium salt 

Phenolsulfonic acid, sodium salt 

Phenoxyacetic acid, sodium salt 

3'-Phenoxyacetophenone 

2- CPhenoxymethyl)benzoic acid 

1 - ( 3- Phenoxypheny l)ethanol 

Phenylacetic acid (a-Toluic acid) 

Phenylacetic acid, ethyl ester, tech 

Phenylacetic acid, methyl ester 

Phenylacetic acid, potassium salt 

Phenylacetic acid, sodium salt 

Phenylacetonitrile (a-Tolunitrile) 

4 ' - Pheny 1 acet ophenone 

Phenylacetyl chloride 

N - Pheny 1 an th rani lie acid 

Phenyl arsine oxide 

*p-Phenylazoaniline (C. I. Solvent Yellow 1) and hydro- 
chloride. 

4-(Phenylazo)diphenylamine 

4-(Phenylazo)-l-naphthylamine 

2-Phenylbenzimidazole 

Phenyl -p -ben zoquinone 

4-Phenyl-3-buten-2-one 

Phenyl chloroformate 

a-Phenyl-o-cresol 

m- Pheny 1 ened i amine 

o- Pheny lenedi amine 

p- Pheny lenedi amine 

p- Pheny lenedi amine dihydrochloride 

d- Phenylephrine 

dl- Phenylephrine 

1- Pheny lethanol 

Phenyl ether (Diphenyl oxide) 

d(-)- 2- Phenyl glycine 

d 1-2- Phenyl glycine 

N- Phenyl glycine 

N-Phenylglycine, sodium and potassium salts 

Pheny Iglycol ethers 

d(-)-2-Phenylglycylchloride hydrochloride 

5-Phenylhydantoin 

Pheny Ihydrazine hydrochloride 

2 ,2 ' - [ (Phenyl) imino]diethanol (N-Phenyldiethanolamine) - 

2,2'- [ (Phenyl) imino]diethanol , diacetate ester 

3,3' -[ (Phenyl) iminojdipropionitrile 

Phenylmalonic acid, diethyl ester 

l-Phenyl-3-methyl-4-(2-carboxyphenylazo)-5-pyrazolone-- 

3-Phenyl-5-methylisoxazole-4-carbonyl chloride 

N- Phenyl -2 -naph thy lamine 

o- Pheny Iphenol 



KPT, PRD. X 

KPT. 

MER, PRD, SW. 

RCl. 

DOW. 

ACS, CLK, DOW, GP, MON, SHC, SKO, SOC, UCC, USS . 

KLM. 

EK. 

SAL. 

SAL. 

BPC, LIL. 

LIL. 

SK. 

LIL. 

BPC, GIV. 

BPC. 

BPC. 

BPC, OPC. 

OPC. 

BPC, UOP. 

DUP, NES. 

BJL. 

SDW. 

EK. 

ACS, ACY, Cup. 



EK. 

EK. 

SAL. 

EK. 

SDW. 

EK. 

RBC. 

DUP. 

DUP, EK. SW, TRC. 

DUP, SDC. 

EK. 

SDW. 

SDW. 

UCC. 

DOW. 

KF, OTC, UPJ. 

KF, OTC. 

EK. 

ACS. 

UCC. 

KF, OTC, UPJ. 

ABB. 

EK. 

TCH. 

SDC. 

DUP. 

BPC. 

ACS. 

ARS. 

DUP. 

DOW, RCI. 



CYCLIC INTERMEDIATES 



TABLE 2. --Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1974— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



p-Phenylphenol 

o-Phenylphenol , chlorinated 

o-Phenylphenol , sodium salt 

N-Phenyl-p-phenylenediamine 

Phenylphosphinic acid 

Phenylphosphonothioic di chloride 

Phenylphosphorous di chloride 

1-Phenylpiperazine 

1-Phenyl-l ,2-propanedione, 2-oxiine 

Phenyl- 2-propanone 

l-Phenyl-3-pyrazolidinone 

dl- Phenyl succinic acid 

1- Phenyl- 2 -thiourea 

Phenylundecanoic acid 

Phloroglucinol 

Phthalaldehyde 

lC2H)-Phthalazinone 

Phthalic acid 

Phthalic acid, diallyl ester 

* Phthalic anhydride 

Phthalide 

Phthalimide 

Phthalimide, potassium salt 

[Phthalocyaninato(2-) ] copper 

[Phthalocyaninato(2-)]iron 

Phthalocyaninetetrasulfonyl chloride-copper derivative- 

Phthaloyl chloride (Phthalyl chloride) 

Picolines :^ 

2-Picoline (a-Picoline) 

3-Picoline (6-Picoline) 

4- Pi CO line (y-Picoline) 

Pi CO line (3,4-mixture} 

Picolinic acid, ethyl ester 

Picolinonitrile (2-Cyanopyridine) 

Picric acid (Trinitrophenol) 

2-Pipecoline 

Piperidine 

3-Piperidinopropiophenone hydrochloride 

Polychlorobenzene 

Polychlorobiphenyl 

Polyethylbenzene 

Potassium cyclohexanebutyrate 

Potassium ph thai amide 

Primuline base 

*Propiophenone 

N- Propyl aniline 

8, 16-Pyranthrenedione 

Pyridine, refined:^ 

2° Pyridine 

Other grades 

Pyridine hydrochloride 

Pyridinium bromide perbromide 

a-Pyridyl-a-thenylamine 

2-Pyrimidinol 

Pyrrolidine 

2- Pyrrol idinone 

3- (1- Pyrrol idinyl)propiophenone hydrochloride 

Quinaldine 

Quinhydrone 

Quinoline: 

1° and 2° Quinoline 

Quinoline (synthetic) 

Other grades 



BAS, ENJ, KPT, MON, PTO, RCI , SOC, STP, UCC, USS. 



SW. 



DOW. 

DOW. 

DOW. 

USR. 

SFS. 

SFA. 

SFA. 

RSA. 

EK, 

ORT. 

EK. 

PD. 

EK. 

EK. 

MRT. 

EK. 



FMP. 

ACS, 

FMT. 

DUP, 

EK. 

DUP,n 

DUP. 

DUP. 

MON. 



KPT, NEP, UCC. 

NEP. 

UCC. 

KPT, NEP. 

NEP. 

NEP. 

SDC. 

LIL. 

ABB, DUP. 

ACY, SDW. 

DOW. 

MON. 

UCC. 

EK. 

PD. 

DUP. 

ORT, PD, UCC, UOP. 

EK. 

TRC. 

KPT, NEP. 

KPT, NEP. 

EK. 

ARA. 

ABB. 

CGY. 

DUP. 

GAF. 

LIL. 

ACS, ACY. 

EK. 



KPT. 



SYflTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2, 



-Cyclic intermediates for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--CONTINUED 



2,4-Quinolinediol 

Resorcinol, tech' -- 

Resorcinol, monoacetate (non-medicinal grade) - 
8-Resorcylic acid 

*Salicylaldehyde 

Salicylaldehyde oxime 

'Salicylic acid, tech 

Salicylic acid, ammonium chromium complex 

Salicylic acid, phenyl ester 

Salicylic acid, sodium chromium complex 

Salicylideneaminoguanidine oleate 

*Styrene, all grades 



Styrene oxide 

5-Sulfamoylanthranilic acid 

Sulfanilamide, tech 

Sulfanilic acid (p-Arainobenzenesulfonic acid) and salt- 

o-Sulfobenzoic acid, cyclic anhydride 

Sulfodiphenols, mixed 

5-Sulfoisophthalic acid, 1,3-dimethyl ester 

5-Sulfoisophthalic acid, lithium salt 

5-Sulfoisophthalic acid, sodium salt 

4,4'-Sulfonyldianiline 

4,4'-Sul£onyldiphenol (4,4'-Dihydroxydiphenylsulfone)-- 

4-Sulfophth'alic acid 

Terephthalic acid 

*Terephthalic acid, dimethyl ester 

Terephthaloyl chloride 

Terephthaloyldiacetic acid, diethyl ester 

Terphenyl CPhenylbiphenyl) 

3,3' ,4,4'-Tetraaminobenzophenone 

3' ,3' ' ,5'S' '-Tetrabromophenolphthalein, ethyl ester 

Tetrabromophthalic anhydride 

l,4,S,8-Tetrachloroanthraquinone 

1,2,4,5-Tetrachlorobenzene 

l,2,4,5-Tetrachloro-3-nitrobenzene 

Tetrahy dro fur an 

Tetrahydrofurfuryl dimethacrylate 

Tetrahydro-2-pyrimidone 

1,2,3 , 4-Tetrahydroquinoxal ine 

1 ,4,S,8-Tetrahydroxyanthraquinone, leuco derivative 

l,4,5,8-Tetrakis(l-anthraquinonylamino)anthraquinone 

(Pentanthrimide) . 

1,2,3,4-Tetramethylbenzene CPrehnitine) 

1 ,2,3,S-Tetramethylbenzene (Isodurene) 

1 ,2,4,5-Tetramethylbenzene (Durene) 

p-( 1,1, 3, 3-Tetramethylbutyl) phenol 

N,N,N' ,N'-Tetramethyl-p-phenylenediamine dihydro- 

chloride. 
[4,4' ,4' ' ,4' ' '-Tetranitrophthalocyaninato(2-)]copper--- 

l(H)-Tetrazole-l-acetic acid 

3,3'-Thiobis[7H-benz[de]anthracen-7-one] 

4,4'-Thiodianiline 

2-Thiophene acetic acid 

Thiophene- 2- acetyl chloride 

2-Thiophenecarboxaldehyde 

Thiopheno 1 

Thiosalicylic acid 

sym-Thymol 

♦Toluene- 2, 4-diamine (4-m-Tolylenediamine) 

Toluene-2 ,4-disulfonic acid 

p-Toluenesulfinic acid, sodium salt 



Manufacturers ' identification codes 
(according to list in table 3) 



PCW. 

KPT. 

EK. 

KPT. 

DOW, DUP, MTR, RDA. 

EK. 

DOW, HN, HON, SDH. 

TRC. 

DOW. 

TRC. 

DUP. 

ACC, CSD, DOW, ELP, FG, GOC, KPP, MCB, MON, NWP, SHC, 

SKC, SNT, UCC. 
UCC. 
TRC. 
SAL. 

ACS, ACY, DUP, SAL. 
EK. 
UPF. 
x. 

PCW. 
PCW. 
RSA. 
UPF. 

CWN, HSC. 

ACC, DUP, HFC, SDH. 
ACC, DUP, EKT, HPC. 
DUP. 
PCW. 
MON. 
BJL. 
EK. 
MCH. 

AC, DUP. 
DOW. 
SDH. 

DUP, QKO. 
SAR. 
VAL. 
DUP. 

AC, ICC, TRC. 
GAF. 

SNT. 

SNT. 

SNT. 

GAF, PRD, RH, SCN. 

EK. 



SDC. 










LIL. 










MAY, TRC. 










ACY. 










BPC. 










LIL. 










ABB. 










SFA. 










4MB. 










Giv, KPT. 










ACS, ACY, 


DUP. 


mc. 


RUC, 


UCC 


GAF, SDH. 










EK, NES. 











CYCLIC INTERMEDIATES 



TABLE 2,— Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'l— CONTINUED 



o-Toluenesulfonamide 

p-Toluenesulfonamide 

o(and p5-Toluenesulfonic acid 

p-Toluenesulfonic acid 

p-Toluenesulfonic acid, monohydrate 

o-Toluenesulfonyl chloride 

p-Toluenesulfonyl chloride 

a-Toluenesulfonyl fluoride 

a-Toluene thiol 

m-Toluic acid 

o-Toluic acid 

p-Toluic acid 

m-Toluidine 

o-Toluidine 

p-Toluidine 

o-Toluidine hydrochloride 

p-Toluidine hydrochloride 

Toluidines, mixed 

2-o-Toluidinoethanol 

m-Toluidinomethanesulfonic acid 

o-Toluidinomethanesulfonic acid 

o- (p-Toluoyl] ben zoic acid 

N-(p-Tolylazo)sarcosine 

*4-(o-Tolylazo)-o-toluidine (C. 1. Solvent Yellow 3)- 

4-(o-Tolylazo)-o-toluidlne hydrochloride 

1-p-Tolyldodecane 

2,2'-Cm-Tolylimino)diethanol 

2,2'- (o-Tolylimino)diethanol 

2,2'-(m-Tolyliinino)diethanol, diacetate ester 

Tolyltriazole 

N,N,N-Tribenzylamine 

3,4' ,5-Tribromosalicylanilide 

1,2, 3 (and l,2,4)-Trichlorobenzene 

1 , 2 , 4-Tri ch 1 orobenzene 

N,2,6-Trichloro-p-benzoquinoneimine 

1,1, l-Trichloro-2,2-diphenylethane . 

Trichloromelamine 

1 , 2, 4-Trichloro-5 -nitrobenzene 

Tri ch 1 oropheny Isilane 

a,a,a,-Trichlorotoluene (Benzotrichloride) 

a,2,4-Trichlorotoluene 

2,4,6-Trichloro-5-triazine (Cyanuric chloride) 

1,3,5-Triethylbenzene 

a,a,a,-Trifluorotoluene 

Trimesic acid (1,3,5-Benzenetricarboxylic acid) 

Trimellitic anhydride, acid chloride 

1,2,3-Trimethylbenzene (Hemellitene) 

1,2,4-Trimethylbenzene (Pseudocumene) 

1,3,5-Trimethylbenzene (Mesitylene) 

3,5,5-Trimethylcyclohexanol CHomomenthol) 

2,3,3-Trimethyl-3H-indole 

1 ,3,3-Triinethyl-A^ ,a-indolineacetaldehyde 

l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)- 

Trime thy Iphenyl ammonium chloride 

Trimethylphenyl ammonium iodi de 

2,4,6-Trimethylpyridine 

2,4,6-Trinitrobenzenesulfonic acid 

Triphenylme thane 

Triphenylmethanol 

2,4,6-Tripropoxybenzaldehyde 

a, a' ,a' '-Tris(dimethylamino)mesitol 

TrisC2-methyl-l-aziridinyl)phosphine oxide 



Manufacturers' identification codes 
(according to list in table 3) 



MON. 

HON. 

MON, NES, UPF. 

TEN, UPF. 

NES. 

MON. 

MON. 

EK. 

EK. 

BPC. 

BPC. 

BPC, EK. 

DUP. 

DUP, FST. 

DUP. 

AC. 

EK. 

DUP. 

TCH. 

TRC, VPC. 

TRC. 

ACY. 

BUC, GAF. 

ACY, ALL, DUP, 

GAF. 

X. 

MIL, TCH. 

TCH. 

SDC. 



GAF, SDH. 



PCW 




PPG. 




DOW, 


HK. 


EK. 




CWN 




WTH 




ALL, 


PCW. 


DCC, 


UCC. 


HK, 


VEL. 


HN. 




CGY, 


NIL. 


DUP. 




HK. 




AMB. 




ARS. 




SNT. 




SNT. 




SNT. 




ARS. 




GAF. 




ACS, 


DUP, GAF 


DUP, 


GAF. 


X. 




EK, 


TRC. 


KPT. 




EK. 





SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2. —Cyclic intermediates for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'1--C0NTI NUED 



7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] 
(J Acid Urea) . 

Veratraldehyde (3,4-Dimethoxybenzaldehyde) 

p-Vinylbenzenesulfonic acid, sodium salt 

4-Vinylcyclohexene 

5-Vinyl-2-picoline (MVP) 

'Violanthrone (Dibenzanthrone) 

Xanthene-9-carboxylic acid 

m- Xylene 

*o- Xylene 

*p- Xylene 

m-Xylenesulfonic acid 

2,6-Xylenol, synthetic 

Xyli dines : 

2,4-Xylidine Cm-4-Xylidine) 

2,6-Xylidine (p-Xylidine) 

Original mixture 

4- (2,5-Xylylazo)-o-toluidine 

All other cyclic intermediates 



Manufacturers ' identification codes 
(according to list in table 3) 



GAF, IRC. 

GIV, SLV. 

DUP. 

UCC. 

PLC. 

ACS, ACY, DUP, GAF, MAY, SDC , TRC . 

MAL. 

SNT. 

ATR, CCP, CPI, CSD, CSO, ENJ , MON, PPR, SHC , SNT, 

SOC, TOC. 
ACC, ATR, CSD, CSO, ENJ, HCR , PPR, SHC, SNT, SOC, SOG, 

TOC. 
NES. 
GE, KPT. 

DUP. 

DUP. 

DUP. 

ACY. 

ABB, ACC, ACS, ACY, ALD, ALL, BJL, DUP, EK, FMP, GAF, 
HST, ICI, JCC, LIL, MRK, PCW, PD, PRD, RH, SAR, 
SDC, SK, STC, TCH, UCC, x, x, x, x, x. 



' See report on Medicinal Chemicals for data on medicinal grade of this item. 

^ Does not include manufacturers' identification codes for producers that report to the Division of Fossil Fuels, 
U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers 
in the United States in 1974, November 6, 1975. 



CYCLIC INTERflEDIATES 
TABLE 3.— Cyclic intermediates: Directory of manufacturers^ 1974 



ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of cyclic intermediates to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Name of company 



Name of company 



Abbott Laboratories 

American Color 5 Chemical Corp. 

Amoco Chemical Corp. 

Allied Chemical Corp. : 

Specialty Chemicals Division 
American Cyanamid Co. 
Air Products 5 Chemicals, Inc. 
Aldrich Chemical Co., Inc. 
Allied Chemical Corp., Fibers Div. 
Alliance Chemicals, Inc. 
American Bio-Synthetics Corp. 
Arapahoe Chemical, Inc. Sub/Syntex 

Corp. (U.S.A.) 
Armstrong Cork Co. 
Arsynco, Inc. 
Arizona Chemical Co. 

Ashland Oil, Inc. and Ashland Chemical Co. 
Ansul Chemical Co. 
Atlantic Richfield Co. 

BASF Wyandotte Corp. 

Benzenoid Organics, Inc. 

Burdick 5 Jackson Laboratories, Inc. 

Stauffer Chemical Co., Specialty-Chemical 

Division, Benzol Products Dept. 
Synalloy Corp., Blackman-Uhler 

Chemical Div. 

Crown Central Petroleum Corp. 

Cincinnati Milacron Chemicals, Inc. 

Celanese Corp., Celanese Chemical Co. 

Ciba-Geigy Corp. 

Chemol, Inc. 

Clark Chemical Corp. 

Nyanza, Inc. 

Nipro, Inc. 

Continental Oil Co. 

Commonwealth Petrochemicals, Inc. 

Carus Corp., Carus Chemical Co. 

Crown Zellerbach Corp., Chemical 

Products Div. 
Cosden Oil 5 Chemical Co. 
Cities Service Oil Co. 
Coastal States Petrochemical Co. 
Upjohn Co., Fine Chemicals Division 

Dow Badische Co. 

Dow Corning Corp. 

Dow Chemical Co. 

Dye Specialties, Inc. 

E.I. duPont dc Nemours 5 Co., Inc. 

Dover Chemical Co. 

Eagle River Chemical Corp. 
Eastman Kodak Co . : 

Tennessee Eastman Co. Division 
El Paso Products Co. 
Exxon Chemical Co. U.S.A. 

Ferro Corp., Ottawa Chemical Div. 

Foster Grant Co., Inc. 

FMC Corp. , Industrial Chemical Division 

Fairmount Chemical Co. , Inc. 

First Chemical Corp. 



GIV 

GLY 

GNT 

GOC 

GP 

GRS 

GYR 

HCR 
HEX 



HPC 
HSC 
HSH 
HST 

ICC 
ICI 



KLM 
KPP 
KPT 



LAK 
LIL 

MAL 
MAY 
MCB 
HCH 
tIER 
MIL 

MLC 
MNR 
MOB 
MOC 
MON 
MRA 
MRK 
MRT 

MTO 
MTR 



NCI 
NEP 
NES 
NIL 
NOR 
NPC 
NWP 



GAF Corp., Chemical Division 
General Electric Co. 
Givaudan Corp. 
Glyco Chemicals, Inc. 
General Tire 5 Rubber Co. 
Gulf Oil Corp., Gulf Oil Co., 
Georgia-Pacific Corp., Rebecc 
Champlin Petroleum Co. 
Goodyear Tire 5 Rubber Co. 



Chemical Co. -U.S. 
1 Chemical Division 



Hercor Chemical Corp. 

Hexagon Laboratories, Inc. 

Hooker Chemicals 5 Plastics Corp. 

Tenneco Chemicals, Inc. 

Hercules, Inc. 

Chemetron Corp., Pigments Division 

Harshaw Chemical Co., Div. of Kewanee Oil Co 

American Hoechst Corp. 

Inmont Corp. 

ICI United States, Inc., Specialty 
Chemicals Group 

Jefferson Chemical Co., Inc. 

Kay-Fries Chemicals, Inc. 
Kalama Chemical Co. 
Arco/Polymers, Inc. 
Koppers Co., Inc., Organic Materials 
Division 

Lakeway Chemicals, Inc. 

Eli Lilly 6 Co. and Puerto Rico 

Mallinckrodt Chemical Works 

Otto B. May, Inc. 

Borg-Warner Corp., Marbon Chemical Division 

Michigan Chemical Corp. 

Merichem Co. 

Deering Milliken, Inc., Milliken 

Chemical Div. 
Melamine CHemicals, Inc. 
Monroe Chemical Co. 
Mobay Chemical Co. 

Marathon Oil Co., Texas Refining Division 
Monsanto Co. 
Crown-Metro, Inc. 
Merck 6 Co. , Inc. 
Morton Chemical Co. Div. of Morton-Norwich 

Products, Inc. 
Montrose Chemical Corp. of California 
Sobin Chemicals, Inc., Montrose Chemical 

Division 

Union Camp Corp., Chemicals Division 

Nepera Chemical Co., Inc. 

Nease Chemical Co., Inc. 

Nilok Chemicals, Inc. 

Norwich Pharmacal Co. 

Northwest Petrochemical Corp. 

Northern Petrochemical Co. 



SYNTHETIC ORGAFIIC CHEHICALS. 197i< 
TABLE 3. --Cyclic intermediates: Directory of manufacturers^ 197ij--CoNTiNUED 



Name of company 



Name of company 



OMC 01 in Corp. 

OPC Orbis Products Corp. 

ORO Chevron Chemical Co. 

ORT Roehr Chemicals, Inc. 

OTC Story Chemical Corp., Ott Division 

PAS Pennwalt Corp. 

PCR Princeton Chemical Research, Inc. 

PCW Pfister Chemical, Inc. 

PD Parke, Davis § Co. 

PFZ Pfizer, Inc. 

PIT Pitt-Consol Chemical Co. 

PLC Phillips Petroleum Co. 

PPG PPG Industries, Inc. 

PPR Phillips Puerto Rico Core, Inc. 

PRO : Productol Chemical Co., Inc. 

PTO Puerto Rico Chemical Co., Inc. 

PTT Petro-Tex Chemical Corp. 

QKO Quaker Oats Co. 

RBC Fike Chemicals, Inc. 

RCl Reichhold Chemicals, Inc. 

RDA Rhodia, Inc. 

RH Rohm S Haas Co. 

RPC Millmaster Onyx Corp., Refined-Onyx Division 

RSA R.S.A. Corp. 

RUC Rubicon Chemicals, Inc. 

SAL I Salsbury Laboratories 

SAR Sartomer Industries, Inc. 

SCN I Schenectady Chemicals, Inc. 

SDC ! Martin-Marietta Corp., Sodyeco Division 

Sterling Drug, Inc.: 
SDH Hilton-Davis Chemical Co. Division 
SDW Winthrop Laboratories Division 

Stauffer Chemical Co.: 
SPA Agricultural Division 
SFC Calhio Chemicals, Inc. 
SFS Specialty Chemical Division 

SHC Shell Oil Co., Shell Chemical Co. Division 

SHO Shell Oil Co. 

SK Smith, Klein § French Laboratories 

SKC Sinclair- Koppers Chemical Co. 

SKO Skelly Oil Co. 

SLV Sterwin Chemicals, Inc. 



SNT 
SOC 

SOG 
STC 
STG 
STP 
STY 



TCH 
TEN 
TMS 
TNA 
TOC 
TRC 
TRD 



UCC 
UOC 
UOP 
UPF 
UPJ 
USR 
USS 

VAL 
VEL 
VGC 
VPC 



WHC 

WIL 

WJ 

WTC 

WTH 

WTL 

WYT 



Suntide Refining Co. 

Standard Oil Co. of California, Chevron 

Chemical Co. 
Charter International Oil Co. 
Sou-Tex Chemical Co., Inc. 
Stange Co. 
Stepan Chemical Co. 
Styrochem Corp. 
Sherwin-Williams Co. 
Corco Cyclohexane, Inc. 

Emery Industries, Inc., Trylon Chemical Division 

Cities Service Co., Copperhill Operations 

Sterling Drug, Inc., Thomasset Color Division 

Ethyl Corp . 

Tenneco Oil Co, 

Toms River Chemical Corp. 

Manufacturing Enterprises, Inc., Squibb 

Manufacturing, Inc., Trade Enterprise, Inc. 
Texaco, Inc. 

Union Carbide Corp. 

Union Oil Co. of California 

Universal Oil Products Co., UOP Chemical Division 

United States Pipe 5 Foundry Co. 

Upjohn Co. 

Uniroyal, Inc., Chemical Division 

USS Chemicals Div. of U.S. Steel Corp. 



Valchem Corp. 

Velsicol Chemical Corp. 

Virginia Chemicals, Inc. 

Mobay Chemical Corp., Verona Division 



I 



Philip A. Hunt Chemical Corp., Wayland Chemical 

Division 
Whittaker Corp. , Research S Development Division 
Inolex Corp., Inolex Pharmaceutical Division 
Warner-Jenkinson Manufacturing Co. 
Witco Chemical Co., Inc. 
Union Camp Corp., Harchem Division 
Pennwalt Corp., Lucidol Division 
Wyeth Laboratories, Inc., Wyeth Laboratories 

Div. of American Home Products Corp. 



Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix. 



DYES 49 

Dyes 

Synthetic dyes are derived in whole or in part from cyclic inter- 
mediates. Approximately two-thirds of the dyes consumed in the United 
States are used by the textile industry to dye natural and synthetic 
fibers or fabrics; about one-sixth is used for coloring paper; and the 
rest is used chiefly in the production of organic pigments and in the 
dyeing of leather and plastics. Of the several thousand different 
synthetic dyes that are known, more than one thousand are manufactured 
by one or more domestic producers. The large number of dyes results 
from the many different types of materials to which dyes are applied, 
the different conditions of service for which dyes are required, and 
the costs that a particular use can bear. Dyes are sold as pastes, 
powders, lumps, and solutions; concentrations vary from 6 percent to 
100 percent. The concentration, form, and purity of a dye are deter- 
mined largely by the use for which it is intended. 

Total domestic production of dyes in 1974 amounted to 275 million 
pounds, or 3.2 percent less than the 284 million pounds produced in 1973 
(table 1). Sales of dyes in 1974 amounted to 263 million pounds, valued 
at $556 million, compared with 266 million pounds, valued at $519 million, 
in 1973. In terms of quantity, sales of dyes in 1974 were 1.1 percent 
smaller than in 1973 and in terms of value, 7.1 percent larger. The 
average unit value of sales of all dyes in 1974 was $2.11 per pound, com- 
pared with $1.95 per pound in 1973. 

For a few important dyes, production was larger in 1974 than in 1973. 
Vat Yellow 2 production increased 8.5 percent from 3,732,000 pounds in 
1973 to 4,050,000 pounds in 1974. Disperse Blue 79 production increased 
35.7 percent from 3,619,000 pounds in 1973 to 4,910,000 pounds in 1974. 
Other important dyes whose production in 1974 was substantially larger than 
in 1973 were Disperse Blue 3 (25.3 percent increase). Fluorescent Brightening 
Agent 28 (46.0 percent increase), FD§C Yellow No. 5 (10.7 percent increase), 
and FD§C Yellow No. 6 (11.3 percent increase). 

On the other hand, the production of several important dyes was smaller 
in 1974 than in 1973. Disperse Yellow 3 production decreased 23.4 percent 
from 3,748,000 pounds in 1973 to 2,870,000 pounds in 1974. Direct Yellow 
11 production decreased 20.6 percent from 2,685,000 pounds in 1973 to 
2,132,000 pounds in 1974. Acid Blue 9 production decreased 9.3 percent 
from 2,316,000 pounds in 1973 to 1,937,000 pounds in 1974. Other important 
dyes whose production in 1974 was substantially smaller than in 1973 were 
Acid Red 88 (93.5 percent decrease). Acid Red 151 (28.2 percent decrease), 
Basic Yellow 11 (34.0 percent decrease), Direct Yellow 44 (50.5 percent 
decrease). Direct Blue 86 (40.3 percent decrease), FD§C Red No. 2 (36.6 
percent decrease), and Vat Green 1, 6% (12.1 percent decrease). 

Table lA is a summary of production and sales of dyes in 1974 by 
class of application. Six application classes of dyes accounted for 81.7 
percent of all dyes produced in 1974. Vat dyes accounted for 19.7 percent 



50 SYNTHETIC ORGANIC CHEMICALS^ 1974 



of total production; disperse dyes for 18.5 percent; fluorescent brightening 
agents for 14.9 percent; direct dyes for 11.7 percent; acid dyes for 9.6 
percent; and basic dyes for 7.3 percent. Of these six classes of dyes, 
the production of vat dyes decreased 3.8 percent from 1973 to 1974; 
disperse dyes production increased 1.4 percent; fluorescent brightening 
agents production increased 26.6 percent; direct dyes production de- 
creased 18.0 percent; acid dyes production decreased 17.8 percent; and 
basic dyes production decreased 6.1 percent. 

As compared with 1973 data, the 1974 production of the remaining 
dye classes changed in the following manner: Fiber-reactive dyes 
decreased by 7.5 percent; food, drug, and cosmetic colors increased by 
9.2 percent; and solvent dyes increased by 17.7 percaent. 



DYES 



TABLE 1,— Dyes: U.S. production and sales^ 197'1 



[Listed below are all dyes for which any reported data on production or sales nay be published. (Leaders (...) are 
used where the reported data are accepted in confidence and nay not be published or where no data were reported.) 
Table 2 lists all dyes for which data on production and/or sales were reported and identifies the manufacturers 
of each] 



Quantity 



Unit 
value' 



Grand total 

ACID DYES 

Total 

Acid yellow dyes, total 

Acid Yellow 11 

Acid Yellow 17 

Acid Yellow 19 

Acid Yellow 23 

Acid Yellow 34 

Acid Yellow 36 

Acid Yellow 38 

Acid Yellow 40 

Acid Yellow 42 

Acid Yellow 54 

Acid Yellow 65 

Acid Yellow 99 

Acid Yellow 151 

Acid Yellow 159 

All other 

Acid orange dyes, total 

Acid Orange 7 

Acid Orange 8 

Acid Orange 10 

Acid Orange 24 

Acid Orange 60 

Acid Orange 64 

Acid Orange 74 

Acid Orange 116 

All other 

Acid red dyes, total 

Acid Red 1 

Acid Red 4 

Acid Red 18 

Acid Red 37 

Acid Red 73 

Acid Red 88 

Acid Red 89 

Acid Red 99 

Acid Red 114 

Acid Red 115 

Acid Red 137 

Acid Red 151 

Acid Red 182 -- 

Acid Red 186 

Acid Red 266 

Acid Red 337 

All other 



See footnotes at end of table. 



1,000 
pounds 



275,036 



184 
382 
336 



1,786 

397 

4,152 

3,953 



609 
252 
213 
567 
269 



531 
1,466 



233 
134 



101 
834 



316 

419 

1,632 



1,000 
pounds 



263,143 



1,000 
dollars 



24,443 



180 
325 
346 

76 
236 

52 



1,603 

397 
3,486 



481 
242 
262 
522 
246 



433 
1,179 



4,588 



265 

134 

129 

36 

526 

182 

12 

55 

299 

28 

138 

669 

62 

11 

236 

356 

1,450 



71,507 



455 

654 

956 

186 

520 

130 

342 

74 

85 

180 

116 

3,587 

1,298 

10,524 

8,167 



446 
839 
764 



1,210 
3,641 



14,946 



373 

286 

226 

141 

1,799 

326 

19 

128 

784 

73 

552 

1,546 

229 

56 

1,121 

1,621 

5,666 



SYNTHETIC ORGANIC CHEMICALS, 197^^ 
TABLE L— Dyes; U.S, production and sales, 197't--CoNTiNUED 



Dye 



Production 



ACID DYES--Continued 

Acid violet dyes, total 

Acid Violet 1 

Acid Violet 3 

Acid Violet 7 

Acid Violet 12 

Acid Violet 17 

Acid Violet 49 

All other 

Acid blue dyes, total 

Acid Blue 7 

Acid Blue 9 

Acid Blue 25^ 

Acid Blue 27 - 

Acid Blue 40 ■ 

Acid Blue 41 --■ 

Acid Blue 45 ■ 

Acid Blue 78-, 

Acid Blue 113 

Acid Blue 118- --- 

Acid Blue 158 and 158A 

All other 

Acid green dyes, total 

Acid Green 3 

Acid Green 20 

Acid Green 25 

All other 

Acid brown dyes, total 

Acid Brown 14 

All other 

Acid black dyes, total 

Acid Black 1 --- 

Acid Black 52 

Acid Black 107— 

All other 

AZOIC DYES AND COMPONENTS 

Azoic Diazo Components , Bases 
(Fast Color Bases) 

Azoic Diazo Components, Bases (Fast Color Bases), 
Total 

Azoic Diazo Components, Salts 
(Fast Color- Salts) 

Total 

Azoic Diazo Component 1, salt 

Azoic Diazo Component 3, salt 

Azoic Diazo Component S, salt 

Azoic Diazo Component 8, salt 



See footnotes at end of table. 



1,000 
pounds 



4.898 



1,937 
495 



115 
1,012 



338 
362 



217 
570 



363 
1,611 



Quantity 



1,000 
pounds 



105 
32 



4,614 



28 

1,497 

523 

129 

599 

28 
113 

28 
648 

57 

71 
893 



1,000 
dollars 



352 
169 



243 
578 



2,975 



506 
669 

358 
1,442 



171 
132 
46 



148 
94 
34 
102 
320 
245 

16,000 



117 

2,318 

2,645 

527 

2,582 

'141 

553 

344 

1,680 

142 

241 

4,710 

2,592 



1,432 



;,474 



1,889 

7,173 



1,176 
1,665 
1,012 
3,320 



1,926 



167 
159 



DYES 



TABLE 1.— Dyes: U.S. production and sales> 1974— Continued 



Dye 



AZOIC DYES AND COMPONENTS--Continued 

Azoic Diazo Components, Salts — Continued 
(Fast Color Salts) 

Azoic Diazo Component 9, salt 

Azoic Diazo Component 10, salt 

Azoic Diazo Component 12, salt 

Azoic Diazo Component 13, salt 

Azoic Diazo Component 14, salt 

Azoic Diazo Component 49, salt 

All other azoic diazo components, salts 

Azoic Coupling Components 
(Naphthol AS and Derivatives) 

Azoic Coupling Coupling Components (Naphthol AS and 
Derivatives) , Total 

BASIC DYES 

Total 

Basic yellow dyes, total 

Basic Yellow II 

Basic Yellow 13 

All other 

Basic orange dyes, total 

Basic Orange 1 

Basic Orange 2 

Basic Orange 21 

All other 

Basic red dyes, total 

Basic Red 13 

Basic Red 14 

Basic Red IS 

Basic Red 18 

Basic Red 49 

All other 

Basic violet dyes, total 

Basic Violet 1 

Baisc Violet 16 

All other 

Basic blue dyes, total 

Basic Blue 3 

Basic Blue 5 

Basic Blue 7 

Basic Blue 22 

All other 

Basic Brown 1 

Basic Brown 4 

Basic black dyes 

All other basic dyes 



See footnotes at end of table. 



1,000 
pounds 



216 
288 
184 



1,816 



20,074 



5,646 



1,097 
4,549 
2,096 



290 

403 

1,163 

240 

3,211 



619 
365 

725 

72 

1,430 

3,666 



1,188 

406 

2,072 



474 
174 
824 



Quantity 



1,000 
pounds 



1,000 
dollars 



212 


243 


284 


297 


206 


256 


40 


124 


146 


291 



1,643 



1,156 

303 

4,029 



384 
468 
897 

275 



609 
339 
660 



1,201 

363 

2,106 

3,281 



6,492 



53,818 



3,016 
. 685 
9,878 



666 

959 

2,224 

947 

9,901 



1,286 
942 

1,407 
191 

5,986 

10.235 



1,212 
6,540 



169 


942 


78 


346 


025 


10,639 


104 


196 


482 


851 


180 


511 


787 


1,761 



SYNTHETIC ORGANIC CHEfUCALS. 1974 
TABLE 1.— Dyes: U.S. production and sales, 1974— Continued 



Dye 



Production 



Quantity j Value 



Unit 
value' 



1,000 



DIRECT DYES 

Total 

Direct yellow dyes, total 

Direct Yellow 4 

Direct Yellow 6 

Direct Yellow 8 

Direct Yellow 11 

Direct Yellow 12 

Direct Yellow 28 

Direct Yellow 44 

Direct Yellow 50^ - 

Direct Yellow 84 

Direct Yellow 105 

Direct Yellow 106 

All other 

Direct orange dyes, total 

Direct Orange 8 

Direct Orange 15 

Direct Orange 26 

Direct Orange 29 

Direct Orange 34 

Direct Orange 37 

Direct Orange 39 

Direct Orange 72 

Direct Orange 73 

Direct Orange 102 

All other 

Direct red dyes, total 

Direct Red 1 

Direct Red 2 

Direct Red 4 

Direct Red 16 

Direct Red 23 

Direct Red 24 

Direct Red 26 

Direct Red 31 

Direct Red 37 

Direct Red 39 

Direct Red 72 

Direct Red 75 

Direct Red 79 

Direct Red 80 

Direct Red 81 

Direct Red 83 

All other 

Direct violet dyes, total 

Direct Violet 9 

All other 



See footnotes at end of table. 



634 
485 

2,132 
116 
211 
503 
998 
705 

692 
4,913 

1,577 



416 
121 
101 



234 
151 



424 
665 



1,000 



1,000 
dollars 



31,314 



20,317 



556 

511 

14 

2,347 
131 
179 
663 
878 
701 
118 
632 

4,505 

1,547 



231 

243 



3,620 



230 
202 



57 

404 

738 

121 

1,076 

224 



1,005 

1,024 

52 

2,307 

512 

453 

1,553 

1,369 

1,295 

341 

1,229 

9,177 

3,774 



111 
500 
222 
362 
207 
54 
255 
386 
222 
706 
749 

10,241 



262 
387 
134 
213 
753 
483 
211 
88 
272 
161 
586 
37 
300 
974 

1,909 
314 

3,157 

604 



DYES 



TABLE 1.— Dyes; U.S, production and sales, 1974— Continued 



Dye 



DIRECT DYES— Continued 

Direct blue dyes, total 

Direct Blue 1 

Direct Blue 8 

Direct Blue IS 

Direct Blue 25 

Direct Blue 76 

Direct Blue 78 

Direct Blue 80 

Direct Blue 86 

Direct Blue 98 

Direct Blue 126 

Direct Blue 191 

Direct Blue 218 

All other 

Direct green dyes, total 

Direct Green 1 

Direct Green 6 

All other 

Direct brown dyes, total 

Direct Brovm 31 ' 

Direct Brown 95' 

All other 

Direct black dyes, total 

Direct Black 4 

Direct Black 9 

Direct Black 22 

All other 

DISPERSE DYES 

Total 

Disperse yellow dyes, total 

Disperse Yellow 3 

Disperse Yellow 5 

Disperse Yellow 23 

Disperse Yellow 33 

Disperse Yellow 34 

Disperse Yellow 42 

Disperse Yellow 54 

All other 

Disperse orange dyes, total 

Disperse Orange 3 

Disperse Orange 17 

Disperse Orange 25 

Disperse Orange 29 

Disperse Orange 37 

All other 



See footnotes at end of table. 



1,000 
pounds 



5,989 



333 
548 
205 



1,206 
3,202 



1,053 



341 
712 



50,793 



9,370 



2,870 

797 
315 
110 
897 
1,304 
3,077 

6,896 



177 
581 
694 
379 
,876 



Quantity Value 



1,000 
pounds 



207 

42 

224 



388 
580 
170 
49 
120 
1,155 
2,796 



109 
107 



1,000 
dollars 



111 

497 

105 

99 

115 

913 

1,550 

389 

210 

212 

3,115 

5,442 

1,800 



343 
701 



7,345 



259 
7,037 



2,919 

50 

713 

305 

98 

947 

1,207 

2,652 

5,909 



123 
118 
472 
551 
386 
4,259 



183 

267 

1,350 



145 

510 

1,085 



261 
8,642 



22,175 



5,850 

154 

1,427 

579 

175 

1,917 

4,864 

7,209 

10,308 



270 

167 

1,139 

1,322 

736 

6,674 



SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 1,--Dyes; U.S, production and sales, 197^--Continued 



Dye 



Quantity Value 



DISPERSE DYES--Continued 

Disperse red dyes, total 

Disperse Red 1 

Disperse Red 5 

Disperse Red 11 

Disperse Red IS 

Disperse Red 17 

Disperse Red 50 

Disperse Red 55 

Disperse Red 59 

Disperse Red 60 

Disperse Red 65 

Disperse Red 86 

Disperse Red 177 

AH other 

Disperse violet dyes, total 

Disperse Violet 1 

Disperse Violet 4 

Disperse Violet 27 

All other 

Disperse blue dyes, total 

Disperse Blue 1 

Disperse Blue 3 

Disperse Blue 7 

Disperse Blue 64 

Disperse Blue 79 

All other 

Disperse brown 1 

Disperse black dyes, total 

Disperse Black 1 

All other 

All other disperse dyes 

FIBER-REACTIVE DYES 

Fiber-reactive dyes, total 

Reactive yellow dyes 

Reactive blue dyes 

All other reactive dyes'* 

FLUORESCENT BRIGHTENING AGENTS 

Total 

Fluorescent Brightening Agent 28 

All other fluorescent brightening agents 



1,000 
pounds 



417 
130 
42 
102 
304 
142 



1,943 



105 
558 



21,673 



192 

1,678 

496 

579 

4,910 

13,818 

570 

1,095 



1,995 
339 



3,416 



2,777 



1,681 
39,410 



1,000 
pounds 



8,754 



2,039 
159 



4,910 
666 



19,351 



199 

1,375 

480 

629 

4,593 

12,075 

590 

1,755 



1,666 
312 



678 
1,862 



1,655 
40,128 



1,000 
do I lews 



31,461 



709 
118 
301 
353 
671 

3,930 

7,706 

478 

125 

945 

16,125 



274 
2,240 



68,240 



1,344 
3,127 
3,682 
1,297 
12,759 
46,031 

1,565 

3,158 



206 
2,952 



3,005 
3,832 
8,037 



2,576 
50.678 



See footnotes at end of table. 



DYES 



TABLE 1.--DYES; U.S. production and sales, 1974— Continued 



Dye 



FOOD, DRUG, AND COSMETIC COLORS 

Total 

Food, Drug, and Coametia Dyes 

Total 

FD5C Red No. 2 

FD5C Red No. 3 

FD6C Yellow No. 5 -- - 

FD5C Yellow No. 6 

All other food, drug, and cosmetic dyes 

Drug and Cosmetic and External Drug 
and Cosmetic Dyes 

Total 

D5C green dyes 

D6C Orange No. 4 - 

D5C red dyes, total 

D5C Red No. 7 

DSC Red No. 19-- 

DSC Red No. 34- - 

D5C Red No. 36 

All other 

All other drug § cosmetic and external drug 6 
cosmetic dyes^ 

HORDANT DYES 

Total 

Mordant yellow dyes 

Mordant orange dyes 

Mordant brown dyes, total 

Mordant Brown 1 

Mordant Brown 33 

All other 

Mordant black dyes, total 

Mordant Black 11 

All other 

All other mordant dyes 

SOLVENT DYES 

Total 

Solvent yellow dyes, total 

Solvent Yellow 2 

Solvent Yellow 14 

Solvent Yellow 56 

All other 

Solvent orange dyes 

Solvent red dyes, total 

Solvent Red 26 

Solvent Red 49 

All other 

See footnotes at end of table. 



1,000 
pounds 



5,286 



803 

443 

1,525 

1,1S8 

1,357 



125 
487 



487 
156 



16,459 



1,531 



511 

77 

943 

1,098 

3,050 



102 
2,948 



1,000 
pounds 



1,000 
dollars 



5,318 



4,919 



720 

412 

1.392 

1,073 

1,322 



103 

154 



364 
174 



1,605 



11 
562 

79 
953 

1,051 

3,166 



128 

98 

2,940 



29,494 



3,524 
4,004 
6,005 
4,164 
11,797 



3,428 



691 
62 



1,718 



205 
125 



1,298 



143 
206 

452 



323 
1,388 



1,027 
361 



30,437 



1,021 

167 

2,935 

2,415 

6,301 



349 

701 

5,251 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 1,— Dyes; U.S. production and sales. IQ/'J-'Continued 



Dye 



Quantity 



Unit 
value' 



SOLVENT DYES--Continued 

Solvent blue dyes 

Solvent green dyes 

Solvent brown dyes, total 

Solvent Brovm 12 

All other 

All other solvent dyes' 

VAT DYES 

Total 

Vat yellow dyes, total 

Vat Yellow 2, 8-1/2% 

All other 

Vat orange dyes, total 

Vat Orange 1, 20% 

Vat Orange 2, 12% 

Vat Orange 15, 10% 

All other 

Vat red dyes, total 

Vat Red 1, 13% - 

Vat Red 13, 11% - 

All other 

Vat violet dyes, total 

Vat Violet 1, 11% 

All other 

Vat blue dyes, total 

Vat Blue 14, 8-1/3% 

All other 

Vat green dyes, total 

Vat Green 1, 6% 

Vat Green 3, 10% 

All other 

Vat brown dyes, total 

Vat Brown 1, 11% 

Vat Brown 3, 11% 

All other 

Vat black dyes, total 

Vat Black 25, 12-1/2% - 

Vat Black 27, 12-1/2% - 

All other 

All other vat dyes' 

All other dyes^ 

See footnotes on following page. 



1,000 
pounds 



4,523 



54,196 



4,956 



4,050 
906 



326 
2,006 



172 
336 
495 



5,139 



1,325 
1,518 
1,796 



3,717 



2,317 

299 

1,101 

37,049 

19,980 



1,000 
pounds 



1,977 
191 



1,000 
dollars 



10,320 
644 



79 
4,500 



55,565 



401 
6,153 



67,030 



4,40 



10,077 



,475 
933 



,925 
4,152 



8,773 



749 
407 
384 



2,543 
1,096 
1,322 
3,812 

1,922 



165 
117 
181 



635 
540 
747 

1,697 



212 
323 



806 
891 



34,874 
5,480 



1,908 
1,547 
2,025 

3,332 



706 

340 

2,286 



2,167 

472 

1,241 



19,109 



124 
22,339 



2,387 
2,326 
2,542 



1,873 

998 

5,180 

6,792 



3,979 

855 

1,958 



Per 
pound 



DYES 



Footnotes for table 1 



' Calculated from rounded figures. 

The production data for Acid Blue 45 in 1974 cannot be published separately because publication would disclose 
information received in confidence. The 1972 and 1973 production data for Acid Blue 45 have been revised. For 1972 
the revised data are 259,000 pounds produced and 245,000 pounds sold, valued at 927,000 dollars. For 1973, the 
revised production data are 159,000 pounds with the sales of 137,000 pounds as previously reported. 

' The data include dyes which are similar to but not chemically identical with the indicated Colour Index name. 

The data include sales of reactive orange, red, violet, green, brown, and black dyes. 
' The data include D§C blue, D5C violet, DSC yellow, "all other" D5C orange, and all other external drug and 
cosmetic dyes. 

The production data include solvent green, violet, and black dyes while the sales data include solvent violet and 
black dyes. 

The data include vat blue dyes (production only) and vat brown dyes (production only). 

The data include azoic compositions, oxidation bases, ingrain dyes, sulfur dyes, and miscellaneous dyes. 
Statistics for these groups of dyes may not be published separately because publication would disclose information 
received in confidence. 



TABLE 1A.--DYES: U.S. production and sales^ by class of application^ 197'1 



Class of applicati 



Production 



Quantity 



Unit 
value' 



Total - 



Acid 

Azoic dyes and components: 

Azoic diazo components, bases (Fast color bases) - 
Azoic diazo components, salts (Fast color salts)- 
Azoic coupling components (Naphthol AS 6 

derivatives) 

Basic 

Direct 

Disperse 

Fiber-reactive 

Fluorescent brightening agents 

Food, drug, and cosmetic colors 

Mordant 

Solvent 

Vat 

All other ^ 



1,000 
pounds 



275,036 



26,330 

662 
1,373 

1,816 
20,074 
32,266 
50,793 

3,416 
41,091 

5,725 
855 
16,459 
54,196 
19,980 



1,000 
pounds 



1,000 
dollars 



609 
1,510 

1,643 
19,014 
31,314 
46,228 

3,126 
41,783 

5,313 

894 

12,587 

55,565 

19,109 



71,507 

1,388 
1,926 

6,492 
53,818 
60,895 
140,488 
14,874 
53,254 
32,922 
2,366 
30,437 
67,030 
18,829 



Per 
pound 



$2.11 



2.28 
1.28 

3.95 
2.83 
1.94 
3.04 
4.76 
1.27 
6.19 
2.65 
2.42 
1.21 
.99 



Calculated from rounded figures. 

The data includes azoic composition, oxidation base, ingrain dyes, sulfur dyes, and miscellaneous dyes. 
Statistics for these groups of dyes may not be published separately because publication would disclose information 
received in confidence. 



SYiJTHETIC ORGANIC CHEniCALS. 1974 



TABLE 2, --Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURERy 1974 
[Dyes for which separate statistics are given in table 1 are marked below with an asterisk (*) ; dyes not so marked do 
not appear in table 1 because the reported data are accepted in confidence and may not be published. Manufacturers' 
identification codes shown below are taken from table 3. An x signifies that the manufacturer- did not consent to 
his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



ACID DYES 

*Acid yellow dyes: 

Acid Yellow 1 

Acid Yellow 3 

*Acid Yellow 11 

Acid Yellow 12 

Acid Yellow 14 

*Acid Yellow 17 

*Acid Yellow 19 

*Acid Yellow 23 

Acid Yellow 25 

Acid Yellow 29 

*Acid Yellow 34 

♦Acid Yellow 36 

*Acid Yellow 38 

*Acid Yellow 4n 

*Acid Yellow 42 

Acid Yellow 44 

Acid Yellow 49 

*Acid Yellow 54 

Acid Yellow 59 

Acid Yellow 63 

*Acid Yellow 65 

Acid Yellow 73 

Acid Yellow 76 

Acid Yellow 79 

*Acid Yellow 99 

Acid Yellow 114 

Acid Yellow 121 

Acid Yellow 124 

Acid Yellow 127 

Acid Yellow 128 

Acid Yellow 129 

Acid Yellow 135 

*Acid Yellow 151 

Acid Yellow 152 

*Acid Yellow 159 

Acid Yellow 174 

Acid Yellow 175 

Acid Yellow 179 

Acid Yellow 190 

Acid Yellow 198 

Acid Yellow 200 

Other acid yellow dyes 

*Acid orange dyes: 

Acid Orange 1 

Acid f^range 2 

Acid "range 3 

Acid Orange 6 

*Acid Orange 7 

*Acid Orange 8 

*Acid Orange 10 

Acid Orange 12 

*Acid Orange 24 

Acid Orange 31 

Acid Orange 45 

Acid Orange 50 

Acid Orange 51 

Acid Orange 56 

*Acid Orange 60 

Acid Orange 62 



ALT, BAS, CMC, ICI , VPC. 

ACY, ALT, GAF, MRX, PDC, TRC, VPC. 



ATL, PDC. 

GAF, TRC. 

GAF. 

ALT, ATL, TRC, VPC. 
GAF, VPC. 



ACY. 

ACS, ACY. 

ATL, EDO, CMG, VPC. 

VPC. 

TRC. 

AC, ACS, ALT, ATL, BDO, CT1G, DUP, HSH, PDC, SDH, TRC, 

VPC. 
AC, ACS, 
AC, ACS, 
GAF. 

GAF, TRC. 
AC, ACS, 
ACS, DUP, 
ACS, ATL, 
ACS, ACY, 
AC, ACY, 
AC, GAF. 
DUP, VPC. 

AC, ACS, TRC, VPC. 
VPC. 

AC, ACS. 

ALT, ATL, FAB, TRC. 
ACS, SDH. 
GAF, TRC. 
VPC. 

CMG, GAF, TPC, VPC. 
TRC. 
GAF. 

AC, ACS. 
TRC. 
TRC. 
TRC. 
GAF. 

AC, ACY, ALT, DUP, FAB, GAF, TRC, VPC. 
ACY. 

AC, ACS, 
AC, CMG, 
DUP. 
TRC. 
HST. 
DUP. 
DUP. 
AC, ALT, ATL, FAB, GAF, TRC, VPC. 



AC, GAF. 

ACS. 

CMG. 

ACS. 

.'iC, ACS, 

AC, ACS, 

AC, ACS, 

PSC. 

ACS, ACY. 

AC. 

ACS. 



ALT, FAB, GAF, TRC, VPC. 
DUP, VPC. 



AC. 
TRC. 
GAF. 

AC, ATL, 
TRC. 



ACY, ATL, BDO, GAF, PDC, TRC, VPC. 

ACY, ATL, DUP, GAF, TRC, VPC. 

ACY, ATL, DUP, GAF, PDC, TRC, VPC. 

DUP, GAF, TRC. 



CMG, DUP, GAF, TRC, VPC. 



DYES 



TABLE 2.- 



-Dyes for which U,S, production or sales were reported, identified 
BY manufacturer, 1974--Continued 



Manufacturers' identification codes 
(according to list in table 3) 



ACID DYES--Continued 

*Acid orange dyes--Continued 

Acid Orange 63 

*Acid Orange 64 

Acid Orange 69 

*Acid Orange 74 

Acid Orange 76 

Acid Orange 85 

Acid Orange 86 

Acid Orange 87 

*Acid Orange 116 

Acid Orange 119 

Acid Orange 128 

Acid Orange 132 

Acid Orange 136 

Other acid orange dyes 

•Acid red dyes : 

•Acid Red 1 

•Acid Red 4 

Acid Red 14 

Acid Red 17 

•Acid Red 18 

Acid Red 26 

Acid Red 27 

Acid Red 32 

Acid Red 35--- 

•Acid Red 37 

Acid Red 52 

Acid Red 57 

Acid Red 66 

•Acid Red 73 

Acid Red 80 

Acid Red 85 

Acid Red 87 

•Acid Red 88 

•Acid Ped 89 

Acid Red 97 

•Acid Red 99 

Acid Red 102 

Acid Red 111 

•Acid Red 114 

•Acid Red 115 

Acid Red 119 

Acid Red 133 

Acid Red 134 

•Acid Red 137 

•Acid Red 151 

Acid Red 167 

Acid Red 178 

Acid Red 179 

•Acid Red 182 

Acid Red 183 

•Acid Red 186 

Acid Red 194 

Acid Red 213 

Acid Red 225 

•Acid Red 266 

Acid Red 277 

Acid Red 278 

Acid Red 299 

Acid Red 309 



AIL 


GAP 


TRC 










AC? 


ACY 


DUP 










ACY 














CMC 


GAP 


TRC 










TRC. 














ACS 














ACS 


ALT 


TRC 










ALT 














AC, 


ACS, 


ALT, 


CMG, 


FAB, 


GAP. 




TRC. 














DUP 














DUP 














DUP 














ALT 


ATL 


GAP 


TRC 


VPC 






ACS 


ACY 


ATL 


EDO 


GAP 


HSU 


SDH. TRC. VPC 


ATL 


EDO 


CMG 


GAP 


PDC 


TRC 


VPC. 


ACS 


ATL 


GAP 


PDC 








ACS 


ATL 












ACS 


GAP 


PDC 


TRC 








ACY 














ACS 














GAP 














GAP. 














AC. 


ACS, 


ATL, 


DUP. 


GAP. 


TRC. 




GAP 














ATL 


CMG 


TRC 










AC, 


ATL. 












ACS 


ACY 


ATL 


DUP 


GAP 


HSH 


PSC, TRC. VPC 


AC, 


ICI. 












ACS 


GAP 












SDH 














ACS 


ACY 


ATL 


GAP 


PDC 


SDH 


TRC. 


AC, 


EDO, 


GAP. 










ATL 


GAP 












AC, 


ATL, 


PAE. 










VPC 














VPC 














ACS 


ALT 


ATL 


DUP 


GAP 


TRC 


VPC. 


ACS 


ATL 


GAP 










ALF 


ATL 












GAP 














TRC 














AC, 


ACS, 


ATL, 


DUP, 


GAP, 


TPC. 




AC, 


ACY, 


ATL. 


DUP, 


HSH, 


TPC. 


VPC. 


ATL 


TRC 












DUP 














TRC 














AC, 


ACS, 


ALT. 


ATL. 


CMG, 


DUP. 


GAP. 


TRC 














CMG 


GAP 


VPC 










CMG 


TRC 












TRC 














VPC 














AC, 


DUP, 


TRC. 


VPC. 








VPC 














VPC 















AC, ALT. FAB. 



SYNTHETIC ORGANIC CHEniCALS, 197^ 



TABLE 2,— Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURER^ IGJ^l— CONTINUED 



Dye 



ACID DYFS--Continued 

*Acid red dyes--Continued 

*Acid Red 337 

Acid Red 350 

Acid Red 388 

Other acid red dyes 

*Acid violet dyes: 

*Acid Violet 1 

*Acid Violet 3 

*Acid Violet 7 

*Acid Violet 12 

•Acid Violet 17 

Acid Violet 29 

Acid Violet 34 

Acid Violet 43 

*Acid Violet 49 

Acid Violet 56 

Acid Violet 58 

Acid Violet 76 

Other acid violet dyes 

*Acid blue dyes : 

Acid Blue 1 

*Acid Blue 7 

•Acid Blue 9 

Acid Blue 15 

Acid Blue 20 

Acid Blue 22 

Acid Blue 23 

♦Acid Blue 25 

•Acid Blue 27 

Acid Blue 29 

•Acid Blue 40 

♦Acid Blue 41 

Acid Blue 43 

•Acid Blue 45 

Acid Blue 54 

Acid Blue 62 

Acid Blue 72 

Acid Blue 74 

•Acid Blue 78 

Acid Blue 80 

Acid Blue 81 

Acid Blue 83 

Acid Blue 92 

Acid Blue 93 

Acid Blue 104 

•Acid Blue 113 

•Acid Blue 118 

Acid Blue 120 

Acid Blue 122 

Acid Blue 145 

•Acid Blue 158 and 158A 

Acid Blue 165 

Acid Blue 179 

Acid Blue 203 ^^-- 

Acid Blue 221 

Acid Blue 230 

Acid Blue 231 

Acid Blue 298 -- 

Other acid blue dyes 



Manufacturers' identification codes 
[according to list in table 3) 



AC, DUP, TRC, \TC. 






GAF. 






DUP. 






AC, ALT, ATL, DUP, GAF, 


TRC, 


VPC. 


BDO, CMC, GAF. 






ACS, ACY, TRC. 






ACS, ATL, BDO, 0(G, GAF, 


TRC 


VPC. 


BDO, C!G, DUP, GAF. 






DUP, GAF, SDH. 






HSH. 






ATL. 






ATL, HSH, ICI. 






ACS, ACY, SDH, TRC. 






GAF. 






GAF. 






ACS. 






TRC. 






ACS, GAF. 






.^CS, ACY, GAF, SDH. 






ACS, GAF, SDH. 






GAF. 






ACS. 






AC. 






TRC. 






AC, ACS, ATL, BDO, 0(G, 


DUP, 


FAB, GAF, HSH, ICI, 


VPC. 






ATL, BDO, CMG, GAF, TRC 


VPC 




PDC. 






ACS, ALT, ATL, BDO, OIG 


DUP 


, GAF, ICI, TRC, VPC. 


ATL, BDO. CMG, GAF. 






TRC. 






AC, ACS, ACY, ATL, OIG, 


GAF, 


TRC. 


OIG. 






ALT, BDO, GAF, VPC. 






ALT. 






ACS, DUP. 






ACS, ATL, BDO, ICI, TRC 






TRC. 






ICI. 






GAF. 






ACS, ATL. 






HSC. 






ACS, GAF. 






AC, ACS, ALT, ATL, CMG, 


DUP, 


FAB, GAF, PDC. 


AC, ACS, ATL. 






ACS, ATL, GAF. 






DUP. 






ACS, DUP. 






AC, EDO, CMG, GAF, TRC, 


VPC. 




DUP. 






GAF. 






VPC . ■ 






VPC. 






ACS, DUP, TRC. 






TRC. 






DUP. 






ALT, ATL, CMG, GAF, TRC 







DYES 



TABLE 2, 



-Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER. 197'(— CONTINUED 



Dye 



Manufacturers* identification codes 
(according to list in table 3) 



ACID DYES--Continued 

•Acid green dyes : 

Acid Green 1 

*Acid Green 3 

Acid Green 5 

Acid Green 9 

Acid Green 12 

Acid Green 16 

Acid Green 19 

*Acid Green 20 

Acid Green 22 

*Acid Green 25 

Acid Green 35 

Acid Green 41 

Acid Green 50 

Acid Green 70 

Acid Green 84 

Other acid green dyes 

*Acid brown dyes: 

Acid Brown 1 

Acid Brown 6 

*Acid Brown 14 

Acid Brown 19 

Acid Brown 28 

Acid Brown 31 

Acid Brown 45 

Acid Brown 96 

Acid Brown 97 

Acid Brown 98 

Acid Brown 152 

Acid Brown 158 

Acid Brown 354 

Other acid brown dyes 

*Acid black dyes : 

*Acid Black 1 

Acid Black 2 

Acid Black 24 

Acid'Black 26, 26A and 26B 

Acid Black 29 

*Acid Black 52 

Acid Black 58 

Acid Black 60 

Acid Black 92 

*Acid Black 107 

Acid Black 108- 

Acid Black 139 

Acid Black 140 

Acid Black 172 

Acid Black 186 

Other acid black dyes 

AZOIC DYES AND COMPONENTS 

Azoio Compositions 

Azoic yellow dyes: 

Azoic Yellow 1 

Azoic Yellow 2 

Azoic Yellow 3 



ACS, ACY. 






ACS, ACY, GAP, TRC. 






WJ. 






ACS, GAP. 






ACS, GAP. 






ACS, SDH, TRC. 






ALT. 






ATL, BDO, GAP, PDC, TRC 






GAP. 






AC, ACS, ATL, GAP, HSH, 


TRC, 


VPC. 


TRC. 






VPC. 






ACY, GAP. 






TRC. 






VPC. 






ALT, VPC. 






GAP. 






GAP. 






AC, ACS, ACY, DUP, GAP, 


TRC. 




TRC. 






TRC. 






GAP. 






TRC. 






ACY. 






ACY. 






ACY, TRC. 






GAP. 






GAP. 






ACY. 






ALT, DUP, GAP, VPC. 






AC, ACS, ACY, ATL, BDO, 


DUP, 


GAP, HSH, PDC, TRC 


ACS, ACY. 






AC, ACS, GAP. 






ATL. 






GAP. 






AC, ACS, ATL, PAB, GAP, 


TRC, 


VPC. 


CMG, DUP, TRC. 






BDO, TRC. 






ACY. 






ACS, ATL, GAP, TRC. 






GAP. 






VPC. 






CMC. 






VPC. 






ACY. 







AC, ALT, ATL, DUP, PDC, VPC. 



ATL, SDH. 
ALL, ATL, 
ATL, BUC. 



SYNTHETIC ORGANIC CHEMICALS, 1971 



TABLE 2.- 



-Dyes for which U.S, production or sales were reported. 

BY manufacturer. 1974— CONTINUED 



identified 



Dye 



Azoic Dyes and Components--Continued 
Azoic CoMpositvons -'CQntinw&d 



Azoic orange dyes: 

Azoic Orange 3 

Azoic Orange 10 

Azoic red dyes : 

Azoic Red 1 

Azoic Red 2 

Azoic Red 6 

Azoic Red 74 

Other azoic red dyes 

Azoic violet dyes: Azoic Violet 1- 

Azoic blue dyes : 

Azoic Blue 2 

Azoic Blue 3 

Azoic Blue 7 

Other azoic blue dyes 

Azoic green dyes 

Azoic brown dyes : 

Azoic Brovm 7 

Azoic Brown 9 

Azoic Brown 26 

Azoic black dyes : 

Azoic Black 1 

Azoic Black 4 

Azoic Black 15 

Other azoic black dyes 



Azoic Diazo Components, Bases 
(Fast Color Bases) 



Azoic Diazo Component 2, base 

Azoic Diazo Component 4, base 

Azoic Diazo Component 5, base 

Azoic Diazo Component 8, base 

Azoic Diazo Component 10, base 

Azoic Diazo Component 11, base 

Azoic Diazo Component 12, base 

Azoic Diazo Component 13, base 

Azoic Diazo Component 14, base (includes Azoic Diazo 
Component 28, base). 

Azoic Diazo Component 32, base 

Azoic Diazo Component 44, base 

Azoic Diazo Component 48, base 



Azoic Diazo Components, Salts 
(Fast Color Salts) 



*Azoic Diazo Component 1, salt' 
Azoic Diazo Component 2, salt 
*Azoic Diazo Component 3, salt 
*Azoic Diazo Component 5, salt 
Azoic Diazo Component 6, salt 
* Azoic Diazo Component 8, salt 
*Azoic Diazo Component 9, 
*Azoic Diazo component 10 
Azoic Diazo Component 11 
*Azoic Diazo Component 12 
*Azoic Diazo Component 13 
*Azoic Diazo Component 14 
Component 28, salt) . 
Azoic Diazo Component 20, salt 
Azoic Diazo Component 32, salt 



alt 

salt 

salt 

salt 

salt 

salt (including Azoic Diazo 



Manufacturers' identification codes 
(according to list in table 3) 



ALL, 


BUC, 


X. 




BUC. 








ALL, 


BUC, 


X. 




ALL, 


BUC, 


GAP. 




ALL, 


BUC, 


SDH, 


X. 


GAP. 








ALL. 








BUC. 








VPC. 








ALL, 


BUC, 


GAP, 


HST, SDH 


GAP. 








ALL. 


GAP. 






ALL, 


BUC, 


VPC. 




BUC. 








ALL, 


BUC, 


GAP, 


HST, X. 


GAP. 








HST. 








BUC, 


GAP. 






GAP. 








ALL, 


GAP. 







BUC. 


GAP, SDH 


GAP. 




SDH. 




BUC. 


GAP. 


PCW. 




BUC, 


SDH. 


BUC. 




AC, 


BUC. 


ALL. 




BUC 




GAP. 





AC, ALL, BUC, GAP, SDH. 

BUC. 

AC, ALL, BUC, GAP, SDH. 

AC, ALL, BUC, GAP, SDH. 

AC, BUC, GAP. 

AC, ALL, BUC. 

AC, ALL, BUC, GAP, SDH. 

ALL, BUC, GAP. 

AC, ALL. 

AC, ALL, BUC, SDH. 

AC, ALL, BUC, GAP, SDH. 

AC. ALL, BUC, GAP. 

ALL. 
ALL. 



DYES 



TABLE 2,— Dyes for which U,S. production or sales were reported, identified 

BY MANUFACTURER, 197'4— CONTINUED 



AZniC DYES AND COMPONENTS- -Continued 



Azoio Diazo Components, f!rrl* 
(Fast Color Salts) 



Azoic Diazo Component 34, salt- 
Azoic Diazo Component 35, salt- 
Azoic Diazo Component 36, salt- 
Azoic Diazo Component 41, salt- 
Azoic Diazo Component 42, salt- 
Azoic Diazo Component 44, salt- 
•Azoic Diazo Component 49, salt- 



Azoic Coupling Component 2 

Azoic Coupling Component 3 

Azoic Coupling Component 4 

Azoic Coupling Component 5 

Azoic Coupling Component 7 

Azoic Coupling Component 8 

Azoic Coupling Component 10 

Azoic Coupling Component 11 

Azoic Coupling Component 12 

Azoic Coupling Component 13 

Azoic Coupling Component 14 

Azoic Coupling Component 15 

Azoic Coupling Component 16 

Azoic Coupling Component 17 

Azoic Coupling Component 18 

Azoic Coupling Component 19 

Azoic Coupling Component 20 

Azoic Coupling Component 21 

Azoic Coupling Component 23 

Azoic Coupling Component 24 

Azoic Coupling Component 29 

Azoic Coupling Component 34 

Azoic Coupling Component 35 

Azoic Coupling Component 41 

Azoic Coupling Component 43 

Other azoic coupling components- 



RASIC DYFS 



*Basic yellow dyes: 
Basic Yellow 1-- 
Basic Yellow 2-- 
♦Rasic Yellow 11- 
•Basic Yellow 13- 
Basic Yellow 15- 
Basic Yellow 21- 
Basic Yellow 23- 
Basic Yellow 24- 
Basic Yellow 25- 
Basic Yellow 28- 
Basic Yellow 29- 
Basic Yellow 31- 
Basic Yellow 37- 
Basic Yellow 41- 
Basic Yellow 50- 
Basic Yellow 52- 
Basic Yellow 53- 
Basic Yellow 58- 



Manuf acturers ' identification codes 
(according to list in table 3) 



Azoic Diazo Component 121, salt GAP 

Azoia Coupling Components 
(Naphthol AS and DeHvatives) 



ALL. 

BUC, GAP. 
GAP. 

ALL, BUC. 
ALL. 
ALL, BUC. 

ALL. BUC, GAP, 



ATL 


BUC 


PCW 


BUC 


PCW 




BUC. 






BUC. 






BUC, 


PCW, 


SDH 


BUC, 


PCW. 




PCW. 






BUC, 


PCI". 




BUC, 


PCW. 




GAP, 


HST. 




BUC, 


PCW. 




BUC, 


GAP. 




BUC. 






BUC, 


PCW. 




BUC, 


GAP, 


PCW. 


BUC, 


GAP, 


PCW. 


BUC, 


GAP, 


PCW. 


BUC, 


PCW. 




PCW. 






PCW. 






BUC, 


PCW. 




BUC, 


PCW. 




BUC, 


PCW. 




HST. 






ATL, 


BUC, 


GAP. 


ALL, 


ATL, 


VPC. 



Other basic yellow dyes | aTL, DUP, GAP, JDH. 



DUP. 

ACS, ACY. 

ACS, ACY, ALT, ATL, DUP, EKT, GAP, TPC, VPC. 

ACS, ALT, ATL, DUP, GAP, VPC. 

DUP. 

ALT, VPC. 

BAS. 

ACY, BAS. 

BAS. 

VPC. 

DUP, VPC. 

DUP. 

ACY. 

ACY. 

EKT. 

DUP. 

DUP. 

DUP. 



SYNTHETIC ORGANIC CHEMICALS, 197^) 



TABLE 2, --Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, IQZ'J— CONTINUED 



Rye 



BA^IC DYRS--Continued 



•Basic orange dyes: 

•Basic Orange 1 

•Basic Orange 2 

•Basic Orange 21 

Basic Orange 24 

Basic Orange 25 

Basic Orange 26 

Basic Orange 28 

Basic Orange 31 

Basic Orange 39 

Basic Orange 40 

Basic Orange 41 

Other basic orange dyes- 
'Basic red dyes: 

Basic Red 1 

Basic Red 2 

Basic Red 9 

Basic Red 12 

•Basic Red 13 

•Basic Red 14 

•Basic Red 15 

Basic Red 16 

Basic Red 17 

•Basic Red 18 

Basic Red 22 

Basic Red 23 

Basic Red 29 

Basic Red 30 

Basic Red 46 

•Basic Red 49 

Basic Red 51 

Basic Red 65 

Basic Red 66 

Basic Red 73 

Other basic red dyes 

Basic violet dyes: 

•Basic Violet 1 

Basic Violet 2 

Basic Violet 3 

Basic Violet 4 

Basic Violet 7 

Basic Violet 10 

Basic Violet 11 

Basic Violet 13 

Basic Violet 14 

Basic Violet 15 

•Basic Violet 16 

Basic Violet 18 

Basic Violet 24 

Basic Violet 66 

Other basic violet dyes-- 
Basic blue dyes : 

Basic Blue 1 

Basic Blue 2 

•Basic Blue 3 

•Basic Blue 5 



Manufacturers' identification codes 
(according to list in table 3) 



ACS, 
ACS, 
ACS, 
DUP. 
DUP. 
DUP. 
VPC. 
ACY. 
DUP. 
BAS. 
BAS. 
DUP. 

BAS, 
ACS, 
DSC, 
DUP, 
ACS, 
ACS, 
ATL, 
DUP. 
DUP. 
ATL, 
TRC. 
VPC. 
BAS. 
ACY. 
ALT, 
DUP, 
BAS. 
EKT. 
EKT. 
DUP. 
ATL, 



ACY, GAP, PSC, TRC. 

ACY, DSC, DUP, GAP, PSC, TPC. 

ACY, ALT, ATL, DUP, GAP, TRC. VPC. 



DUP. 
DUP. 
HSC. 
VPC. 
GAP, 
ACY, 
DUP, 



TRC, VPC. 

ALT, ATL, DUP, GAP. VPC. 

GAP, HSH, TRC. 



DUP, GAP, VPC. 



TRC. 
GAP, VPC. 



BAS. 



ACY, DSC, HSC. 

DUP. 

DUP, SDH. 

DUP. 

GAP. 

DUP, GAP. 



ACS, 

DSC, 

DSC, 

DSC, 

ATL, 

ACY, 

DUP. 

DSC. 

DSC. 

DUP. 

ALT, ATL, DUP, GAP, TRC, VPC. 

ACY. 

DUP. 

VPC. 

ACY, 



DSC, 
DSC. 
ALT, 
DSC, 



DUP. 

GAP, SDH, VPC. 



DUP, GAP, HST. 
SDH, VPC. 



DYES 



TABLE 2. 



-Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 1974--Conti nued 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



BASIC DYES--Continued 



JSIC 



'Basic blue dyes- 
Basic Blue 6-- 
lue 7-- 
9-- 
lue 11- 
lue 21- 
lue 22- 
lue 26- 
lue 35- 
lue 41- 
lue 45- 
lue 47- 
lue 54- 
lue 60- 
lue 69- 
lue 75- 
lue 76- 
lue 77- 
lue 78- 
lue 82- 
lue 87- 
lue 90- 
lue 94- 



Basic Bl 

Basic Bl 

Basic Bl 
•Basic Bl 

Basic Bl 

Basic Bl 

Basic Bl 

Basic Bl 

Basic Bl 

Basic Bl 

Basic Bl 

Basic 

Basic Bl 

Basic 

Basic Bl 

Basic Bl 

Basic 

Basic Bl 

Basic 

Basic 

Basic Blue 97 

Other basic blue dyes-- 
Basic green dyes : 

Basic Green 1 

Basic Green 3 

Basic Green 4 

Basic Green 7 

Basic brown dyes : 
*Basic Brown 1 

Basic Brown 2 

•Basic Brown 4 

Other basic brown dyes- 
*Basic black dyes: 

Basic Black 9 

Other basic black dyes- 



direct dyes 



'Direct yellow dyes: 

*Direct Yellow 4-- 

Direct Yellow 5-- 

*Direct Yellow 6-- 

Direct Yellow 7-- 

*Direct Yellow 8-- 

Direct Yellow 9-- 

*Direct Yellow 11- 

*Direct Yellow 12- 

nirect Yellow 26- 

*Direct Yellow 28- 

Direct Yellow 29- 

Direct Yellow 34- 

Direct Yellow 39- 

Direct Yellow 41- 

*Direct Yellow 44- 

*Direct Yellow 50- 

Direct Yellow 59- 



ACY. 
DSC, 
ACS, 
DSC, 
ACS, 
ACS, 
DSC, 
DUP. 
BAS, 
VPC. 
VPC. 
ACY, 
GAP. 
VPC. 
EKT. 
ACY. 
DUP. 
BAS. 
DUP. 
DUP. 
EKT. 
DUP. 
DUP. 
ACS, 



DUP, SDH. 

ACY. 

SDH. 

DUP. 

ALT, DUP, VPC. 

DUP. 

TRC. 



ATL, BAS, DUP, EKT, SDH, VPC. 



ACS, DSC, DUP. 

DUP. 

ACS, ACY, DSC, VPC. 

DSC. 

ACS, ACY, DUP, GAP, PSC, TRC. 

GAP. 

ACS, ACY, DSC, DUP, GAP, PSC, TRC. 

DUP. 

VPC. 

ALT, BAS, DSC, VPC. 



ACY, 
ACS, 
ATL, 
ACS, 
ATL, 
AC, 
ACS, 
AC, 
ACS, 
ATL, 
AC, 
TRC 
ATL 
AC, 



ACS, ACY, ATL, DUP, GAP, SDH, TRC, VPC. 

GAP. 
, ACY, DUP, GAP, TRC. 

, ATL, GAP. 

ACS, ACY, DUP, GAP, SDH, TRC, VPC. 
ACY, ATL, DUP, FAB, GAP, TRC. 

•ATL. 

, ATL, DUP, GAP, PDC, TRC. 
, GAP. 

ALT. 



ACS, ATL, DUP, PAR, GAP, HSH, TRC, VPC. 
ALT, ATL, DUP, PAB, GAP, HSH, TRC, VPC. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2,- 



-Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 1974— Conti nued 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES --Continued 

♦Direct yellow dyes- -Continued 

Direct Yellow 81 

♦Direct Yellow 84 

Direct Yellow 103 

•Direct Yellow 105 

•Direct Yellow 106 

Direct Yellow 107 

Direct Yellow 117 

Direct Yellow 118 

Direct Yellow 119 

Direct Yellow 127 

Direct Yellow 131 

Direct Yellow 132 

Direct Yellow 133 

Direct Yellow 137 

Other direct yellow dyes 

•Direct orange dyes: 

Direct Orange 1 

Direct Orange 6 

•Direct Orange 8 

Direct Orange 10 

Direct Orange 11 

•Direct Orange 15 

•Direct Orange 26 

•Direct Orange 29 

•Direct Orange 34 

•Direct Orange 37 

•Direct Orange 39 

Direct Orange 59 

Direct Orange 61 

Direct Orange 67 

•Direct Orange 72 

•Driect Orange 73 

Direct Orange 74 

Direct Orange 78 

Direct Orange 80 

Direct Orange 81 

Direct Orange 83 

Direct Orange 88 

•Direct Orange 102 

Other direct orange dyes 

•Direct red dyes: 

•Direct Red 1 

•Direct Red 2 

•Direct Red 4 

Direct Red 7 

Direct Red 10 

Direct Red 13 

•Direct Red 16 

•Direct Red 23 

•Direct Red 24 

•Direct Red 26 

Direct Red 28 

•Direct Red 31 

•Direct Red 37 



ATL. 

AC, ACS, ATL, FAB, GAP, TRC. 

ACS. 

AC, 

AC, 

ACS, 

TRC. 

TRC. 

DUP. 

DUP, 

DUP. 

TRC, 

TRC. 

DUP. 

AC, ALT, ATL, DUP, FAB, GAF, TRC, VPC. 



ACS. 
, FAB, GAF. 



ALT, TRC. 

ACS, ALT, FAB, GAF, HSH, TRC. 
ATL, GAF, TRC. 



TRC. 
VPC. 



ACS 
ATL 
ATL 
ACS 
ACS 
AC, 
AC, 
AC, 
ACS 
ACS 
ACS 



ACS, ACY, DUP, GAF, TRC. 
, ATL, GAF, HSH, TRC. 

ATL, FAB, TRC, VPC. 
, ACY, ATL, CMG, DUP, GAF, HSH. 
,- ATL, CMG, GAF. 

ALT, CMG, DUP, FAB, GAF. 
, GAF. 



ACS, ATL, FAB, HSH, TRC, VPC. 
, GAF, TRC, VPC. 



ACY, ATL, DUP, GAF, SDH. 
ATL, TRC. 

FAB, GAF. 
ACS, ATL, DUP, FAB, TRC. 
ATL, TRC. 



ATL, DUP, TRC. 
ACS, ACY, ATL, DUP, FAB, GAF, HSH, TRC, VPC. 
ACS, ATL, HSH, TRC, VPC. 
ACS, ATL, DUP, GAF, TRC, VPC. 

FAB. 

ATL, GAF, TRC. 

ACY, GAF. 



DYES 



TABLE 2,— Dyes for which U.S. production or sales were reported, identified 
By manufacturer. 1974— Continued 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES --Continued 

•Direct red dyes--Continued 

♦Direct Red 39 

Direct Red 62 

•Direct Red 72 

Direct Red 73 

•Direct Red 75 

Direct Red 76 

•Direct Red 79 

•Direct Red 80 

•Direct Red 81 

•Direct Red 83 

Direct Red 95 

Direct Red 100 

Direct Red 111 

Direct Red 117 

Direct Red 122 

Direct Red 123 

Direct Red 127 and 127A 

Direct Red 139 

Direct Red 149 

Direct Red 152 

Direct Red 153 

Direct Red 209 

Direct Red 212 

Direct Red 236 

Direct Red 238 

Other direct red dyes 

•Direct violet dyes: 

Direct Violet 1 

Direct Violet 7 

•Direct Violet 9 

Direct Violet 14 

Direct Violet 47 

Direct Violet 48 

Direct Violet 51 

Direct Violet 66 

Direct Violet 67 

Direct Violet 99 

Other direct violet dyes 

•Direct blue dyes : 

•Direct Blue 1 

Direct Blue 2 

Direct Blue 6 

•Direct Blue 8 

Direct Blue 14 

•Direct Blue 15 

Direct Blue 22 

•Direct Blue 25 

Direct Blue 67 

Direct Blue 71 

Direct Blue 75 

•Direct Blue 76 

•Direct Blue 78 

•Direct Blue 80 

Direct Blue 81 

•Direct Blue 86 



ATL, 
ATL, 
ACS, 
ACS, 
ATL, 
GAF. 
AC, 
AC, 
AC, 



GAF, 
TRC. 
ATL, 
ATL. 
CMC, 

ATL, 
ACS, 
ACS, 
ACS, 



TRC. 

DUP, GAF, TRC. 

GAF. 

CMC, TRC, VPC. 

ALT, ATL, EDO, CMG, FAB, HSH, SDH, TRC, VPC. 

ACY, ATL, BDO, CMG, DUP, GAF, HSH, TRC, VPC. 

ALT, ATL, FAB, HSH, TRC. 



VPC. 

ATL. 

GAF. 

DUP. 

TRC, VPC. 

GAF. 

ATL, 01G. 

ATL. 

ATL, CMG. 

CMG. 

ATL. 

TRC, VPC. 

VPC. 

DUP. 

DUP. 

AC, ALT, ATL, GAF, HSH, TRC. 



ATL. 
ACS, 
ACS, 
ATL. 
GAF. 
ACS. 
ACS, 
TRC. 
DUP. 
DUP. 
ALT, 



ATL. 
ATL, 



DUP, GAF, TRC. 



ATL. 

ACS, 
ACS, 
GAF 
ATL 
ATL 
ATL 
ATL 
ATL 
. TRC 
ATL 

ACS, 

ATL 

ACS, 



ACY, ATL, DUP, GAF, TRC. VPC. 
FAB, GAF. 

DUP, GAF. 
TRC. 
, DUP, CAP, SDH, VPC. 



ACS 

ACS 

ACS 

ACS 

ACS 

ACS 

ATL 

ACS 

TRC 

AC, 

ACS 

AC, 

ATL. 

AC, ALT, ATL, DUP, FAB, GAF, ICC, TRC, VPC. 



ALT, ATL, GAF, TRC, VPC. 

, CMG. 

ALT, ATL, DUP, FAB, GAF, HSH, TRC, VPC. 



SYHTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2.- 



-Dyes for v-jhich U.S. production or sales were reported^ identified 
BY manufacturer, 1974— Conti nued 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES--Continued 



*Direct blue dyes--Continued 



Direct B 
Direct B 

•Direct B 
Direct B 
Direct B 
Direct B 

•Direct B 
Direct B 
Direct B 
Direct B 
Direct B 
Direct B 

•Direct B 
Direct B 



ue 91 

ue 93 

ue 98 

ue 100 

ue 104 

120 and 120A- 

ue 126 

ue 136 

ue 143 

ue 151 

ue 160 



ct blue dyes- 



lue 191- 
lue 199- 

♦Direct Blue 218- 
Direct Blue 263- 
Other dir 
•Direct green dyes : 

•Direct Green 1 

•Direct Green 6 

Direct Green 26 

Direct Green 27 

Direct Green 28 

Direct Green 38 

Direct Green 45 

Direct Green 47 

Direct Green 51 

Direct Green 69 

Other direct green dyes- 
•Direct brown dyes: 

Direct Brown 1 

Direct Brown lA 

Direct Brown 2 

Direct Brown 27 

•Direct Brown 31 

Direct Brown 32 

Direct Brown 44 

Direct Brown 74 

•Direct Brown 95 

Direct Brown 106 

Direct Brown 111 

Direct Brown 112 

Direct Brown 154 

Other direct brown dyes- 
•Direct black dyes: 

Direct Black 2 

•Direct Black 4 

•Direct Black 9 

Direct Black 17 

Direct Black 19 



trc. 








ALT, ATL, 


GAF 


TRC 


VPC. 


alt, fab 








DUP. 








AC, ATL, 


FAB, 


TRC. 




ATL, HSH 


TRC 


VPC 




GAF. 








DUP. 








ATL, TPC 








TRC. 








TRC. 








ACS, ALT 


GAF 






DUP, GAF 








AC, ACS, 


ALT, 


ATL, 


DUP, FAB 


DUP. 








AC, ALT, 


ATL, 


DUP, 


GAF, HSH 


AC, ACS, 


FAB, 


GAF. 




AC, ACS, 


ACY, 


FAB, 


GAF. 


DUP, TRC 








DUP, TRC 








TRC. 








GAF. 








VPC. 








DUP, GAF 








TRC. 








TRC. 








DUP, TRC 








AC. 








GAF. 








AC, ACS, 


GAF. 






GAF. 








ACS, ATL 


GAF 






GAF. 








GAF. 








ACS. 








AC, ACS, 


ATL, 


FAB, 


GAF. 


GAF. 








DUP, GAF 


TRC 


. VPC 




ATL. 








ACS, FAB 








AC, ALT, 


ATL, 


HN, 


VPC. 


ACS. 








ACS, FAB 


GAF 






AC, ACS, 


ATL, 


DUP. 




GAF. 








ATL, TRC 









DYES 



TABLE 2, 



--Dyes for which U,S. production or sales were reported, identified 
BY manufacturer, 197^)— Conti nued 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



DIRECT DYES--Continued 

*Direct black dyes--Continued 

♦Direct Black 22 

Direct Black 29 

Direct Black 38 

Direct Black 51 

Direct Black 56 

Direct Black 75 

Direct Black 78 

Direct Black 80 

Direct Black 95 

Direct Black 190 

Other direct black dyes 

DISPERSE DYES 

♦Disperse yellow dyes: 

Disperse Yellow 1 

♦Disperse Yellow 3 

♦Disperse Yellow 5 

Disperse Yellow 8 

♦Disperse Yellow 23 

Disperse Yellow 31 

♦Disperse Yellow 33 

♦Disperse Yellow 34 

♦Disperse Yellow 42 

Disperse Yellow 50 

♦Disperse Yellow 54 

Disperse Yellow 56 

Disperse Yellow 58 

Disperse Yellow 64 

Disperse Yellow 67 

Disperse Yellow 68 

Disperse Yellow 69 

Disperse Yellow 74 

Disperse Yellow 77 

Disperse Yellow 85 

Disperse Yellow 86 

Disperse Yellow 87 

Disperse Yellow 88 

Disperse Yellow 89 

Disperse Yellow 93 

Disperse Yellow 95 

Disperse Yellow 96 

Disperse Yellow 108 

Disperse Yellow 118 

Disperse Yellow 123 

Disperse Yellow 125 

Disperse Yellow 131 

Disperse Yellow 136 

Disperse Yellow 137 

Disperse Yellow 138 

Other disperse yellow dyes 

♦Disperse orange dyes: 

♦Disperse Orange 3 

Disperse Orange 5 

♦Disperse Orange 17 

Disperse Orange 21 

♦Disperse Orange 25 

♦Disperse Orange 29 

Disperse Orange 30 

Disperse Orange 33 

♦Disperse Orange 37 

Disperse Orange 41 

Disperse Orange 42 

Disperse Orange 44 

Disperse Orange 57 



atl, gap, TRC, VPC. 



ACS, ALT, FAB, GAP. 
, DUP, GAP, TRC 



ALT, 

AC 

AC, 

ACS, 

ACS. 

GAF. 

AC. 

AC, ACS, ATL, FAB, HSH. 



ACS. 

ALT, ATL, TRC. 



GAF. 
AC, 
HAS, 
ATL 



AC, 
AC, 
TRC 



ATL, DUP, FAB, GAF, HSH, ICC, TRC. 

, GAF, ICC. 

, TRC. 

ALT, DUP, EKT, GAF, HSH, ICC, TRC. 

EKT, GAF, ICC, TRC. 

EKT, ICC. 

BUC, DUP, EKT, GAF, ICC, SDC, TRC. 



AC, ALT, BAS, DUP, GAF, ICC, SDC, TRC, VPC. 

BAS. 

HST. 

BAS, DUP. 

DUP. 

HST. 

ACY. 

VPC. 

VPC. 

EKT. 



EKT. 

EKT. 

EKT. 

VPC. 

VPC. 

VPC. 

EKT. 

AC. 

ACY. 

SDC. 

DUP. 

DUP. 

DUP. 

DUP. 

ALT, ATL, BUC, EKT, GAF, MAY, SDC, VPC. 



ATL 
AC, 
TRC 
AC, 
AC 



GAF, HSH, ICC, TRC. 
, BUC, EKT, GAF. 
EKT, FAB, GAF, HSH, ICC. 

ATL, DUP, EKT, TPC 
FAB, GAF, HSH, VPC. 
TRC. 



ICC, 

BAS. 

AC, ACY, EKT, HSH, ICC, TRC. 

DUP. 

HST. 

DUP. 

EKT. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2. --Dyes for which U,S. production or sales were reported, identified 

BY MANUFACTURER, 197i)--CONTINUED 



DISPERSE DYES--Continued 

'Disperse orange dyes--Continued 

Disperse Orange 58 

Disperse Orange 62 

Disperse Orange 65 

Disperse Orange 66 

Disperse Orange 67 

Disperse Orange 75 

Disperse Orange 77 

Disperse Orange 78 

Disperse Orange 79 

Disperse Orange 80 

Disperse Orange 8P 

Disperse Orange 91 

Disperse Orange 94 

Disperse Orange 95 

Disperse Orange 98 

Disperse Orange 101 

Disperse Orange 103 

Disperse Orange 125 

Other disperse orange dyes 

♦Disperse red dyes: 

'Disperse Red 1 

Disperse Red 4 

'Disperse Red 5 

Disperse Red 7 

Disperse Red 9 

'Disperse Red 11 

Disperse Red 13 

'Disperse Red 15 

'Disperse Red 17 

Disperse Red 21 

Disperse Red 30 

Disperse Red 31 

Disperse Red 35 

'Disperse Red 50 

Disperse Red 54 

'Disperse Red 55 

'Disperse Red 59 

'Disperse Red 60 

'Disperse Red 65 

Disperse Red 73 

Disperse Red 82 

'Disperse Red 86 

Disperse Red 88 

Disperse Red 90 

Disperse Red 91 

Disperse Red 92 

Disperse Red 96 

Disperse Red 105 

Disperse Red 117 

Disperse Red 133 

Disperse Red 135 

Disperse Red 136 

Disperse Red 138 

Disperse Red 140 

Disperse Red 159 

Disperse Red 161 

Disperse Red 162 

Disperse Red 163 

Disperse Red 167 

Disperse Red 176 



Manufacturers' identification codes 
(according to list in tahle 3) 



EKT. 

BUC, 

VPC. 

VPC. 

VPC. 

DUP. 

MAY. 

MAY, 

MAY. 

MAY. 

AC. 

AC. 

SDd. 

DUP. 

DUP. 

DUP. 

ACY. 

DUP. 

ALT, 

AC, 



AC, 

ATL. 

AC, 

AC, 

CMC, 

AC, 

EKT. 

TRC. 

ICC. 

EKT. 

ALT, 

BAS. 

AC, 

ACY, 

AC, 

ALT, 

TRC, 

MAY, 

EKT 

ACY, 

VPC. 

BAS. 

BAS. 

ACY. 

VPC. 

EKT. 

VPC. 

AC, 

EKT. 

EKT. 

AC, 

VPC. 

DUP. 

DUP. 

EKT. 

GAP. 

ICC. 



ATL, BUC, DUP, GAP, HSH , SDC. 

ATL, DUP, EKT, GAP, HSH, ICC, TRC. 

TRC. 
EKT, GAP, HSH, ICC. 
GAP. 

BAS, DUP, GAP, HSH, ICC. 
ATL, GAP. 

, GAP, HSH, ICC, TRC. 
EKT, PAB, GAP, HSH, ICC, TRC. 



FAB, ICC, TRC. 

DUP, GAP, TRC, VPC. 

DUP, GAP. 
BAS, DUP, EKT, GAP, SDC, TRC, VPC. 
, DUP, EKT, ICC, TRC. 

, VPC. 

, GAP, HSH. 

, EKT. 



DYES 



TABLE 2.- 



-Dyes for which U.S. production or sales were reported^ identified 
BY manufacturer. 1974--Continued 




Manufacturers' identification codes 
{according to list in table 3) 



niSPERSE DYES- -Continued 

♦Disperse red dyes- -Continued 

'Disperse Red 177 

Disperse Red 178 

Disperse Red 179 

Disperse Red 180 

Disperse Red 187 

Disperse Red 211 

Disperse Red 217 

Disperse Red 218 

Disperse Red 219 

Disperse Red 220 

Other disperse red dyes 

'Disperse violet dyes: 

'Disperse Violet 1 

'Disperse Violet 4 

Disperse Violet 8 

Disperse Violet 26 

'Disperse Violet 27 

Disperse Violet 28 

Disperse Violet 40 

Disperse Violet 41 

Disperse Violet 42 

Disperse Violet 43 

Disperse Violet 44 

Disperse Violet 64 

Other disperse violet dyes 

'Disperse blue dyes: 

'Disperse Rlue 1 

'Disperse Blue 3 

'Disperse Blue 7 

Disperse Blue 27 

Disoerse Blue 31 

Disperse Blue 55 

Disperse Blue 56(includes Disperse Blue 71)- 

Disperse Blue 60 

Disperse Blue 61 

Disperse Blue 62 

'Disperse Blue 64 

Disperse Blue 73 

Disperse Blue 77 (includes Disperse Blue 120) 

'Disperse Blue 79 

Disperse Blue 81 

Disperse Blue 85 

Disperse Blue 87 

Disperse Blue 94 

Disperse Blue 95 

Disperse Blue 102 

Disperse Blue 109 

Disperse Blue 117 

Disperse Blue 118 

Disperse Blue 119 

Disperse Blue 121 

Disperse Blue 123 

Disperse Blue 125 

Disperse Blue 132 

Disperse Blue 133 

Disperse Blue 138 

Disperse Blue 139 

Disperse Blue 152 

Disperse Blue 165 

Disperse Blue 172 

Disperse Blue 173 

Disperse Blue 191 

Disperse Blue 192 

Disperse Blue 193 

Disperse Blue 194 

Other disperse blue dyes 



ALT, 

ICC. 

ICC. 

ICC. 

AC. 

DUP. 

DUP. 

DUP. 

DUP. 

DUP. 

ALT, BUC, 



ICC, SPC, VPC. 



DUP, FAB, GAP, HSH, ICC, MAY, SDC, TRC. 



TRC. 
TRC. 



AC, GAP, HSH, ICC, TRC. 

AC, GAP, ICC. 

GAP, ICC. 

DUP. 

AC, ACY, DUP, EKT, ICC, 

ALT, DUP, TRC. 

VPC. 

EKT. 

EKT. 

EKT. 

EKT. 

DUP. 

GAP, SDC, UPC. 

AC, GAP, ICC, TRC. 
AC, EKT, GAP, HSH, ICC, 
AC, DUP, GAP, HSH, ICC, 
EKT. 

MAY, UPC. 
TRC. 

ALT, ICC, VPC. 
ALT, DUP. 
DUP. 

DUP, EKT, GAP. 
AC, ATL, DUP, EKT, GAP, TRC 
ACY, TRC. 
EKT, GAP. 

AC, ALT, EKT, ICC, MAY, TRC 
VPC. 
TRC. 
BAS. 
BAS. 

GAP, HST. 
EKT. 

DUP, MAY. 
EKT. 
EKT. 
EKT. 
EKT. 
EKT. 
TRC. 
DUP. 
DUP. 
VPC. 
VPC. 
HST. 

DUP, VPC. 
DUP. 
AC. 
DUP. 
DUP. 
DUP. 
DUP. 

ALT, ATL, BAS, 
VPC. 



BUC, DUP, FAB, GAP, HSH, MAY, SDC, TRC, 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2.- 



-Dyes for which U.S. production or sales were reported, idpntified 

BY MANUFACTURER. 1974--C0NTI NUED 



Dye 



DISPERSE DYES--Continued 

Disperse green dyes: 

Disperse Green 7 

Disperse Green 8 

Other disperse green dyes 

Disperse brown dyes : 

*Disperse Brown 1 

Disperse Brown 2 

Disperse Brown 8 

Disperse Brown 11 

Disperse Brown 14 

Disperse Brown 15 

Other disperse brown dyes 

'Disperse Black dyes: 

♦Disperse Black 1 

Disperse Black 2 

Disperse Black 6 

Disperse Black 9 

Disperse Black 33 

Disperse Black 34 

Other disperse black dyes 

FIBER-REACTI\fE DYES 

♦Reactive yellow dyes: 

Reactive Yellow 1 

Reactive Yellow 2 

Reactive Yellow 3 

Reactive Yellow 4 

Reactive Yellow 6 

Reactive Yellow 7 

Reactive Yellow 13 

Reactive Yellow 15 

Reactive Yellow 17 

Reactive Yellow 18 

Reactive Yellow 24 

Reactive Yellow 25 

Reactive Yellow 27 

Reactive Yellow 31 

Reactive Yellow 37 

Reactive Yellow 42 

Reactive Yellow 86 

Other reactive yellow dyes 

Reactive orange dyes: 

Reactive Orange 1 

Reactive Orange 4 

Reactive Orange 11 

Reactive Orange 12 

Reactive Orange 13 

Reactive Orange 14 

Reactive Orange 16 

Reactive Orange 50 

Other reactive orange dyes 

Reactive red dyes : 

Reactive Red 1 

Reactive Red 2 

Reactive Red 4 

Reactive Red 5 

Reactive Red 8 

Reactive Red 11 

Reactive Red 21 

Reactive Red 29 

Reactive Red 31 

Reactive Red 33 



Manufacturers' identification codes 
(according to list in table 3) 



DUP. 
DUP. 
GAP, 

AC, 

DUP, 

VPC. 

AC. 

DUP. 

DUP. 

ALT, 

AC, 

ATL, 

ATL. 

AC, 

EKT. 

EKT. 

ATL, 



ALT, SDC, TRC. 
, EKT. 



ATL, BAS, DUP, GAF, HSH, ICC, SDC, VPC. 



ATL, DUP, G^F, TRC. 
, TRC. 



BAS, BUC, DUP, GAF, HSH, ICC, SDC, VPC. 



ICI. 

TRC. 

TRC. 

ICI. 

TRC. 

ICI. 

HST. 

HST. 

HST. 

ICI. 

HST. 

VPC. 

VPC. 

HST. 

HST. 

ICI, HST. 

ICI. 

HST, ICI. 

FAB, ICI. 

ICI. 

TRC. 

ICI. 

ICI. 

ICI. 

HST. 

HST. 

HST. 

ICI. 

FAB, ICI. 

TRC. 

ICI. 

ICI. 

FAB, ICI. 

HST. 

ICI. 

ICI. 

ICI. 



DYES 



TABLE 2, 



-Dyes for which U,S. production or sales were reported, identified 
BY manufacturer, 1974— Continued 



Manufacturers' identification codes 
(according to list in table 3) 



FIBER-REACTIVE DYES--Cont inued 



Reactive red dyes- -Continued 

Reactive Red 40 

Reactive Red 41 

Reactive Red 43 

Reactive Red 55 

Reactive Red 58 

Reactive Red 94 

Reactive Red 105 



ue 19 

ue 21 

ue 25 

ue 29 

ue 36(includes Acid Blue 215)- 



Reactive violet dyes: 

Reactive Violet 1 

Reactive Violet 4 

Reactive Violet 5 

Other reactive violet dyes 
*Reactive blue dyes : 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Reactive B 

Other reac 

Reactive green dyes 

Reactive brown dyes: 

Reactive Brown 9 

Reactive Brown in 

Reactive Brown 17 

other reactive brown dyes 
Reactive black dyes : 

Reactive Black 1 

Reactive Black 5 

Reactive Black 9 



ue 71 

ue 89 

ue 90 

ue 109 

ive blue dves- 



FLUORESCENT BRIGHTENING AGENTS 



Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
'Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 
Fluorescent 



Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 
Brightening 



Agent 6 — 
Agent 8--- 

Agent 9 

Agent 22-- 
Agent 25-- 
Agent 28-- 
Agent 30-- 
Agent 33-- 
Agent 45-- 
Agent 46-- 
Agent 49-- 
Agent 52-- 
Agent 54-- 
Agent 59-- 
Agent 6 1 - - 
Agent 68-- 
Agent 71-- 
Agent 75-- 
Agent 102- 
Agent 108- 
Agent 109- 
Agent 125- 
Agent 126- 
Agent 128- 
Agent 130- 



VPC. 
VPC. 

icr. 

TRC. 
ICI. 
HST. 

hst. 

ICI. 

hst. 

HST. 
HST. 

ICI. 

ICI. 

ICI, TRC. 

HST. 

HST. 

ICI. 

VPC. 

HST. 

HST. 

ICI. 

HST. 

HST. 

ICI. 

HST, ICI. 

HST. 

ICI. 
ICI. 
ICI. 
HST. 

TRC. 
HST. 
ICI. 



ACY. 
ACY. 
GAF, 
CGY. 
CGY, 
ACY, 
GAF. 
GAF, 
TRC. 
CGY. 



GAF. 

CCW, DUP, SDH, VPC. 



S. 

S. 

CGY. 

CGY. 

ACY. 

CCW, 

ACY, 

GAF. 

VPC. 

GAF. 

GAF. 

ACY. 

SDH. 

SDH. 

ACY, 



GAF. 
CGY. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2, 



—Dyes for which U.S, production or sales were reported, identified 
by manufacturer. 1974--c0ntinued 



FLUORESCENT BRIGHTENING AGENTS--Continued 

Fluorescent Brightening Agent 134 

Fluorescent Brightening Agent 159 

Other fluorescent brightening agents 

FOOD, DRUG, AND COSMETIC COLORS 

Food, Drug, and Cosmetic Dyes 

FD6C Blue No. I 

FDSC Blue No. 2 

FD5C Green No. 3 

♦FD&C Red No. 2 

*FD&C Red No. 3 

FD5C Red No. 4 

FD6C Red No. 40 

FD5C Violet No. 1 

*FDSC Yellow No. 5 

*FDSC Yellow No. 6 

Other food, drug, and cosmetic dyes 

Drug and Cosmetic Dyes 

D6C Blue No. 1 

DSC Blue No. 6 

D6C Green No. 5 

D5C Green No. 6 

D6C Green No. 8 

*D5C Orange No. 4 

D6C Orange No. S 

D5C Orange No. 10 

DSC Orange No. 17 

DSC Red No. 2 

DSC Red No. 3 

DSC Red No. 6 

*DSC Red No. 7 

DSC Red No. 8 

DSC Red No. 9 

DSC Red No. 10 

DSC Red No. 11 

DSC Red No. 12 

DSC Red No. 13 

*DSC Red No. 19 

DSC Red No. 21 

DSC Red No. 22 

DSC Red No. 27 

DSC Red No. 28 

DSC Red No. 30 

DSC Red No. 31 

DSC Red No. 33 

*DSC Red No. 34 

*DSC Red No. 36 

DSC Red No. 37 

DSC Violet No. 2 

DSC Yellow No. 5 

DSC Yellow No. 6 

DSC Yellow No. 7 

DSC Yellow No. 10 

DSC Yellow No. 11 



Manufacturers' identification codes 
(according to list in table 3) 



CGY. 
ACY. 
ACY, CCW, CGY, DGO, GAF , PCW, S, VPC. 



ACS, 

ACS, 

WJ. 

ACS, 

ACS, 

ALT, 

ACS, 

ACS. 

ACS, 

ACS, 

STG. 



ALT, RON, SDH, WJ . 
ALT, KON, SDH, WJ. 

ALT, KHN, .SDH, STG, WJ. 
ALT, KON, SDH, STG, WJ. 
KON, STG, WJ. 
KON, WJ. 

ALT, KON, SDH, STG, WJ. 
ALT, KON, SDH, STG, WJ . 



KON. 






ACS, 


KON. 




ACS, 


KON. 




ACS, 


KON. 




KON, 


SDH. 




ACS, 


KON, 


TMS. 


SNA, 


TMS. 




TMS. 






SNA. 






KON. 






KON, 


TMS. 




SNA, 


TMS. 




KON, 


SNA, 


TMS. 


KON, 


SNA. 




KON, 


SNA, 


TMS. 


KON, 


SNA. 




KON, 


SNA. 




KON, 


SNA, 


T^'S. 


SNA, 


TMS. 




ACS, 


KON, 


SNA, T><S 


SNA, 


TMS. 




KON, 


SDH. 




TMS. 






ACS. 






KON, 


SNA. 




KON. 






ACS, 


KON. 




KON, 


SNA, 


TMS. 


ALT, 


KON, 


TMS. 


ACS. 






ACS 


SDH. 




KON 


TMS. 




KON 






ALT. 






KON 






ACS, 


KON. 





DYES 



TABLE 2. 



-Dyes for which U.S. production or sales were reported, identified 

BY MANUFACTURER, 1974— CONTINUED 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



FOOD, DRUG, AND CnSMKTIC COLORS- -Continued 

Drug and Cosmetic Dyes, External 

Ext. D6C Green No. 1 

Ext. DSC Violet No. 2 

Ext. DSC Yellow No. 1 

Ext. DSC Yellow No. 7 

INGRAIN DYES 

Ingrain blue dyes: 

Ingrain Blue 3 



ACS, KON. 
KON. 

ACS, KON. 
KON. 



MORDANT DYES 

*Mordant yellow dyes: 

Mordant Yellow 1 

Mordant Yellow 5 

Mordant Yellow 8 

Mordant Yellow 14 

Mordant Yellow 16 

Mordant Yellow 20 

Mordant Yellow 26 

Mordant Yellow 29 ■-- 

Mordant Yellow 30 

'Mordant orange dyes: 

Mordant Orange 1 

Mordant Orange 4 

Mordant Orange 6 

Mordant Orange 8 

Mordant red dyes : 

Mordant Red 3 

Mordant Red 7 

Mordant Red 9 

Mordant Red 11 

Mordant Red 60 

Mordant violet dyes: Mordant Violet 5- 
Mordant blue dyes : 

Mordant Blue 1 

Mordant Blue 3 

Mordant Blue 9 

Mordant Blue 13 

* Mordant brown dyes : 

"Mordant Brown 1 

Mordant Brown 12 

Mordant Brown 13 

Mordant Brown 15 

Mordant Brown 18 

Mordant Brown 21 

'Mordant Brown 33 

Mordant Brown 40 

Mordant Brown 50 

Mordant Brown 63 

Mordant Brown 70 

•Mordant black dyes : 

Mordant Black 8 

Mordant Black 9 

•Mordant Black 11 

Mordant Black 13 

Mordant Black 17 

Mordant Black 19 

Mordant Black 26 

Mordant Black 38 



GAP, 


PDC. 




TRC. 






ACS, 


PDC. 




ACS, 


PDC. 




ACY. 






ACS. 






VPC. 






GAF. 






TRC. 






ACY, 


PDC, 


TRC. 


GAF. 






ATL, 


CMG, 


GAF, PDC, TRC 


TRC. 






ACY. 






BDO, 


GAF. 




ACY. 






SDH. 






PDC. 






GAF. 






GAF. 






GAF, 


PDC. 




HSH. 






ACS, 


DUP, 


GAF, TRC. 


PDC. 






ACS. 






GAF. 






ACS, 


DUP, 


PDC. 


GAF. 






ACS, 


GAF, 


TRC. 


GAF. 






TRC. 






TRC. 






DUP, 


PDC. 




VPC. 






ACS, 


CMG, 


\TC. 


GAF, 


TRC, 


VPC. 


HSH. 






GAF, 


TRC. 




PDC. 






TRC. 






PDC. 







SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2.- 



-Dyes for which U.S. production or sales were reported, identified 
BY manufacturer. 1974--Conti nued 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



nxiDATinN BASES 
Oxidation bases 

SOLVFNT DYES 

'Solvent yellow dyes: 

•Solvent Yellow 2 

Solvent Yellow 3 

Solvent Yellow 13 

•Solvent Yellow 14 

Solvent Yellow 19 

Solvent Yellow 29 

Solvent Yellow 30 

Solvent Yellow 33 

Solvent Yellow 34 

Solvent Yellow 40 

Solvent Yellow 42 

Solvent Yellow 43 

Solvent Yellow 45 

Solvent Yellow 47 

♦Solvent Yellow 56 

Solvent Yellow 71 

Solvent Yellow 72 

Solvent Yellow 87 

Solvent Yellow 107 

Other solvent yellow dyes 

•Solvent orange dyes : 

Solvent firange 2 

Solvent Orange 3 

Solvent Orange 5 

Solvent Orange 7 

Solvent Orange 20 

Solvent Orange 23 

Solvent Orange 24 

Solvent Orange 25 

Solvent Orange 31 

Solvent Orange 48 

Solvent Orange 51 

Other solvent orange dyes 

•Solvent red dyes : 

Solvent Red 1 

Solvent Red 8 

Solvent Red 22 

Solvent Red 24 

•Solvent Red 26 

Solvent Red 27 

Solvent Red 33 

Solvent Red 35 

Solvent Red 40 

Solvent Red 41 

•Solvent Red 49 

Solvent Red 52 



ACY, DUP, GAP 






ACS, psr. 






ACY, GAP. 






AC, ACS, ACY, 


DUP, 


GAP, PSC 


GAP. 






GAP. 






ACS, PSC. 






AC, ACS, ACY. 






ACY, D'^C. 






ACS. 






ACS. 






GAP. 






ACS. 






ACY, DIIP. 






AC, ACS, Ary, 


PSC. 




ACY. 






ACY. 






ACY. 






URT. 






AC, ATL, DSC, 


N(RT. 




PSC. 






ACS, ACY, DSC 


GAP 


PSC. 


GAP. 






ACS, ACY, DUP 


GAP 


PSC. 


ACY, GAP. 






ACS. 






DUP. 






ACY, DUP. 






ACS. 






ACY. 






ACY. 






AC, ACY, DSC, 


DUP. 




PSC. 






GAP. 






GAP. 






ACS, ACY, DUP 


GAP 


PSC. 


AC, ACS, ACY, 


PSC. 




ACS, PSC. 






DUP, GAP. 






GAP. 






GAP. 






DSC. 






ACY, DSC, DUP 


, GAP 





DYES 



TABLE 2.— Dyes for which U.S. production or sales were reported, identified 
BY manufacturer, 197^~Continued 



Dye 



Manufacturers' identification codes 
(according to list in table 3) 



SOLVENT DYES- -Continued 

'Solvent red dyes- -Continued 

Solvent Red 68 

Solvent Red 69 

Solvent Red 74 

Solvent Red 105 

Solvent Red 106 

Solvent Red 108 

Solvent Red 111 

Solvent Red 126 

Solvent Red 164 

Solvent Red 166 

"ther solvent red dyes 

Solvent violet dyes : 

Solvent Violet 8 

Solvent Violet 9 

Solvent Violet 13 

Solvent Violet 14 

other solvent violet dyes 

♦Solvent blue dyes: 

Solvent Blue 3 

Solvent Blue 4 

Solvent Blue S 

Solvent Blue 6 

Solvent Blue 7 

Solvent Blue 9 

Solvent Blue 11 

Solvent Blue 12 

Solvent Blue 13 

Solvent Blue 16 

Solvent Blue 23 

Solvent Blue 36 

Solvent Blue 37 

Solvent Blue 38 

Solvent Blue 43 

Solvent Blue 57 

Solvent, Blue 58 

Solvent Blue 59 

Solvent Blue 74 

Solvent Blue 89 

Solvent Blue 98 

Solvent Blue 100 

Other solvent blue dyes 

•Solvent ?reen dyes: 

Solvent Green 1 

Solvent tireen 2 

Solvent Green 3 

Other solvent green dyes 

♦Solvent brown dyes; 

Solvent Brown 11 

•Solvent Brown 12 

Solvent Brown 19 

Solvent Brown 20 

Solvent Brown 22 

Solvent Brown 36 

Other solvent brown dyes 

Solvent black dyes: 

Solvent Black 5 

Solvent Black 7 

Solvent Black 12 

Solvent Black 13 

Solvent Black 17 

Solvent Black 26 

Other solvent black dyes 



ACS. 
DSC, 
ACS. 
ACY. 
ACY. 
ACY. 
ACY. 
ACY. 
MRT. 
MRT. 



ACY 
DSC 
AC, 
AC, 
AC, 

ACY, 

DSC, 

DSC. 

DSC. 

ACY. 

GAP. 

BOO, 

ACS. 

ACY. 

ACS. 

HSC. 

AC, 

DUP 

ACS 

ACS 

DUP 

ACY 

ACY 

ACS 

ACY 

MRT 

hrt 

kC, 

ACY 
GAP 
AC, 
DSC, 

GAP. 
DSC, 
DUP. 
ACY, 
DUP, 
ACY. 
DSC. 

ACS, 
ACS, 
ACS. 
ACS. 
DUP. 
ACY. 
ATL, 



ACY, ATL, DSC, MRT. 

, DSC. 

ATL, HSH. 
MRT. 
DSC, MRT. 



DUP. 
, ACY, ATL, DUP, GAP. 



DSC, GAP, X. 
DSC. 



ACS, ATL, GAP. HSH. 
GAP. 



DUP. 
PSC. 



ACY, DSC. 
ACY, DSC, PSC. 



DSC, GAP, MRT. 



SYNTHETIC ORGANIC CHEMICALS, WH 



TABLE 2, --Dyes for which U.S. production or sales were reported^ identified 

BY MANUFACTURER, 197^--C0NTINUED 



SULFUR DYES 

Sulfur yellow dyes: 

Leuco Sulfur Yellow 1 

Leuco Sulfur Yellow 2 

Leuco Sulfur Yellow 4 

Leuco Sulfur Yellow 9 

Other sulfur yellow dyes 

Sulfur orange dyes: 

Leuco Sulfur Orange 1 

Other sulfur orange dyes 

Sulfur red dyes : 

Leuco Sulfur Red 5 

Leuco Sulfur Red 10 

Other sulfur red dyes 

Sulfur blue dyes : 

Sulfur Blue 7 

Leuco Sulfur Blue 7 

Sulfur Blue 8 

Leuco Sulfur Blue 8 

Leuco Sulfur Blue 11 

Leuco Sulfur Blue 13 

Other sulfur blue dyes 

Sulfur green dyes: 

Leuco Sulfur Green 2 

Leuco Sulfur Green 3 

Sulfur Green 14 

Leuco Sulfur Green 16 

Other sulfur green dyes 

Sulfur brown dyes: 

Leuco Sulfur Brown 1 

Solubilized Sulfur Brown 1 — 

Leuco Sulfur Brown 3 

Leuco Sulfur Brown 10 

Sulfur Brown 14 

Leuco Sulfur Brown 14 

Leuco Sulfur Brown 20 

Leuco Sulfur Brown 26 

Sulfur Brown 52 

Other sulfur brown dyes 

Sulfur black dyes: 

Sulfur Black 1 

Leuco Sulfur Black 1 

Sulfur Black 2 

Leuco Sulfur Black 2 

Solubilizer Sulfur Black 2--- 

Leuco Sulfur Black 10 

Sulfur Black 11 

Leuco Sulfur Black 11 

Other sulfur black dyes 

VAT DYES 

*Vat yellow dyes : 

*Vat Yellow 2, 8-1/2'i. 

Vat Yellow 3, 12-l/2i 

Vat Yellow 4, 12-1/2% 

Vat Yellow 33, 15% 

Other vat yellow dyes 



Manufacturers' identification codes 
(according to list in table 3) 



SDC. 
ACY, SDC. 

snc. 

STC. 
SDC. 

STC. 
SDC. 

STC. 
SDC. 
SDC. 

SDC. 

ACY, SDC. 

SDC. 

SDC. 

SDC. 

ACY. 

SDC. 

SDC. 
SDC. 
SDC. 
SDC. 
SDC. 

STC. 
STC. 
SDC. 
SDC. 
SDC. 
SDC. 
STC. 
STC. 
SDC. 
ACY, SDC. 

SDC. 

ACY, SDC. 

SDC. 

ACY, SDC. 

SDC. 

ACY. 

SDC. 

SDC. 

SDC. 



AC, ACY, ATL, GAP, TRC, VPC. 

DUP. 

GAP, HST, VPC. 

TRC, VPC. 

VPC. 



DYES 



TABLE 2. --Dyes for which U.S. production or sales were reported^ 
BY manufacturer, 1974--Continued 



identified 



Dye 



VAT DYES --Continued 

*Vat yellow dyes--Continued 

Vat Yellow 10, 10% 

Vat Yellow 14, 12-1/2% 

Vat Yellow 15, 11-1/2% 

Vat Yellow 22, 10% 

Vat Yellow 33, 15% 

Other vat yellow dyes 

*Vat orange dyes : 

*Vat Orange 1, 20% 

*Vat Orange 2, 12% 

Vat Orange 3, 13-1/2% 

Vat Orange 4, 6% 

Vat Orange 5, 10% 

Vat Orange 7, 11% 

Vat Orange 9, 12% 

Vat Orange 11, 6% 

*Vat Orange 15, 10% 

Other vat orange dyes 

*Vat red dyes : 

*Vat Red 1, 13% 

Solubilized Vat Red 1, 37% 

Vat Red 10, 18% 

Vat Red 12, 8-1/2% 

*Vat Red 13, 11% 

Vat Red 14, 10% 

Vat Red 15, 10% 

Vat Red 16, 11% 

Vat Red 29, 18% 

Vat Red 32, 20% 

Vat Red 41, 20% 

Vat Red 52, 10% 

*Vat violet dyes : 

*Vat Violet 1, 11% 

Vat Violet 2, 20% 

Vat Violet 3, 15% 

Vat Violet 9, 12% 

Vat Violet 13, 6-1/4% 

Vat Violet 21 

Other vat violet dyes 

*Vat blue dyes : 

Vat Blue 1, 20% 

Vat Blue 4, 10% 

Vat Blue 5, 16% 

Vat Blue 6, 8-1/3% 

Vat Blue 12, 6-1/2% 

*Vat Blue 14, 8-1/3% 

Vat Blue 16, 16-1/2% 

Vat Blue 18, 13%-- 

Vat Blue 20, 14% 

Vat Blue 39, 12% 

Vat Blue 43 

Vat Blue 60 

Vat Blue 67 

Other vat blue dyes 

*Vat green dyes : 

*Vat Green 1, 6% 

*Vat Green 3, 10% 

Vat Green 8, 8-1/2% 



Manufacturers' identification codes 
f according to list in table 3) 



GAF. 












trc. 












ACY. 












DUP 












TRC 


VPC 










VPC 












ACY 


ATL 


DUP 


GAF 


HST 


, TRC, VPC 


ACY 


BAS 


DUP 


GAF 


TRC 




DUP 


GAF 


HST 








DUP 












DUP 


HST 










hst 


TRC 










ACY 


TRC 










DUP 












AC, 


ACY. 


ATI,, 


GAF, 


TRC, 


VPC. 


SDC 












AC, 


ACY, 


ATL, 


HST. 






HST 












HAS 


GAF 










DUP 












DUP 


GAF 


TRC 








GAF 


HST 










HST, 


TRC 










DUP 












GAF 












DUP 


GAF 










HST 












DUP 












ACY 


ATL 


DUP 


GAF 


TRC 




ACY 


HST 










HST 












DUP 


GAF 


TRC 








BAS. 


GAF 


HST 


TRC 






VPC. 












GAF, 


MAY 










ACS 












DUP 


GAF 










ATL, 


HST 










ACY, 


BAS 


DUP 


GAF 


TRC 




DUP. 












DUP 


GAF 


-TRC 








BAS 


DUP 










AC, 


ACY, 


ATL. 


DUP, 


GAF, 


MAY, TRC. 


AC, 


ACY, 


ATL, 


DUP, 


GAF. 


MAY, TRC. 


GAF. 












SDC. 












DUP. 












HST. 












GAF. 












ACY, 


ATL 


DUP 


MAY 






AC, 


ACY, 


ATL, 


DUP, 


GAF, 


MAY, TRC. 


ATL, 


DUP 


GAF 









SYNTHETIC ORGANIC CHEMICALS. 197^1 

TABLE 2. --Dyes for which U.S. production or sales were reported, identified 
BY manufacturer. 1974--Conti nued 



Manufacturers' identification codes 
(according to list in table 3) 



VAT DYES--Continued 

*Vat green dyes --Continued 

Vat Green 9, 12-1/2% 

Vat Green 20, 6% 

Vat Green 32 

Other vat green dyes 

*Vat brown dyes: 

*Vat Brovm 1, 11% 

*Vat Brown 3, 11% 

Vat Brown 5, 13% 

Vat Brown 11, 12% 

Vat Brown 12, 12-1/2% 

Vat Brown 13, 17% 

Vat Brown 20, 10-1/2% 

Vat Brown 31, 28% 

Vat Brown 40, 14% 

Vat Brown 57, 12.8% 

Other vat brown dyes 

*Vat black dyes : 

Solubilized Vat Black 1, 27-1/2% 

Vat Black 9, 16% 

Vat Black 13, 14% 

Vat Black 16 

Vat Black 22,-19% 

*Vat Black 25, 12-1/2% 

*Vat Black 27, 12-1/2% 

Vat Black 38, 20% 

Other vat black dyes 

All other dyes 



GAP 


HST 


MAY 


TRC 




DUP 










VPC 










SDC 










ACY 


DUP 


GAP 


TRC 




AC, 


ACY, 


DUP, 


GAP, 


TRC, VPC 


ACY 


HST 








MAY 


TRC 








DUP 










MAY 










GAP 










AC. 










DUP 










HST 


TRC 








SDC 


VPC 








HST 










MAY 










DUP 










ACS 










ACY 


TRC 








AC, 


ACY, 


DUP, 


MAY, 


TRC. 


ACY, 


EDO 


DUP 


GAP 


TRC. 


GAP. 










ATL, 


BAS, 


GAP 


SDC 


TRC. 



ACY, DUP, GAP, HSH, MRT, SDC. 



DYES 



TABLE 3, --Dyes: Directory of manufacturers^ 1974 



ALPHABETICAL DIRECTORY BY CODE 



[Names of dye manufacturers that reported production or sales to 
are listed below in order of their identific 



the U.S. International Trade Commission for 1974 
ation codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


AC 


American Color 5 Chemical Corp. 


ICC 


Inmont Corp. 


ACS 


Allied Chemical Corp., Specialty 
Chemicals Div. 


ICI 


ICI United States, Inc. 


ACY 


American Cyanamid Co. 






ALL 


Alliance Chemical, Inc. 


KON 


H. Kohnstamm 6 Co., Inc. 


ALT 


Crompton 5 Knowles Corp., Dyes 5 
Chomicals Div. 






ATL 


Atlantic Chemical Corp. 


MAY 


Otto B. May, Inc. 






MRT 


Morton Norwich Products, Morton Chemical 
Co., Div. 


BAS 


BASF Wyandotte Corp. 


MRX 


Max Marx Color 5 Chemical Co. 


BDO 


Benzenoid Organics, Inc. 






BUC 


Synalloy Corp., Blackman-Uhler Chemical 








Div. 


PCW 


Pfister Chemical Works 






PDC 


Berncolors-Poughkeepsie, Inc. 






PSC 


P&ssaic Color 5 Chemical Co. 


CCW 


Cincinnati Milacron Chemicals, Inc. 






CGY 


Ciba-Geigy Corp. 






CMC 


Nyanza, Inc. 


S 


Sandoz, Inc. 


CPC 


Childs Pulp Colors, Inc. 


SDC 


Martin-Marietta Corp., Sodyeco Div. 






SDH 


Sterling Drug, Inc., Hilton-Davis 
Chemical Co. Div. 


DGO 


Day-Glo Color Corp. 


SNA 


Sun Chemical Corp. 


DSC 


Dye Specialties, Inc. 


STC 


Sou-Tex Chemical Co., Inc. 


DUP 


E. I. duPont de Nemours 6 Co., Inc. 


STG 


Stange Co. 






SW 


Sherwin-Williams Co. 


EKT 


Eastman Kodak Co., Tennessee Eastman 








Co. Div. 


TMS 


Sterling Drug, Inc., Thomasset Colors Div. 






TRC 


Toms River Chemical Corp. 


FAB 


Fabricolor Manufacturing Corp. 










VPC 


Mobay Chemical Corp, Verona Div. 


GAP 


GAF Corp., Chemical Div. 










WJ 


Warner-Jenkinson Manufacturing Co. 


HSC 


Chemetron Corp., Pigments Div. 






HSH 


Harshaw Chemical Co., Div. of Kewanee 
Oil Co. 






HST 


American Hoechst Corp. 







Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix 



84, SYNTHETIC ORGANIC CHEMICALS, 1974 

ORGANIC PIGMENTS 

Organic pigments are toners and lakes derived in whole or in part from benzenoid 
chemicals and colors. 

Statistics on production and sales of all organic pigments in 1974 are given 
in table 1.^ Statistics on sales of a few selected pigments by commercial 
forms (dry full-strength form, dry extended form, dry dispersions, aqueous 
dispersions, and flushed colors) are given in table lA. Individual toners and 
lakes are identified in this report by the names used in the third edition of 
the Colour Index . 

Total production of organic pigments in 1974 was 69.8 million pounds--0.6 
percent more than the 69.4 million pounds produced in 1973 and 5.9 percent 
more than the 65.9 million pounds produced in 1972. Total sales of organic 
pigments in 1974 amounted to 58.5 million pounds, valued at $227.8 million, 
compared with 61.5 million pounds, valued at $182.2 million, in 1973 and 53.2 
million pounds, valued at $149.3 million, in 1972. In terms of quantity, sales 
of organic pigments in 1974 were 4.9 percent smaller than in 1973 and 9.9 
percent greater than in 1972; in terms of value, sales in 1974 were 25.1 
percent greater than in 1973 and 52.5 percent greater than in 1972. 

Production of toners in 1974 amounted to 67.5 million pounds--0.8 percent more 
than the 66.9 million pounds reported for 1973. Sales in 1974 were 56.3 million 
pounds, valued at $222.8 million, compared with 59.0 million pounds, valued at 
$178.6 million, in 1973. Sales in 1974 were 4.5 percent smaller than those in 
1973 in terms of quantity, and 24.8 percent more in terms of value. The 
individual toners listed in the report which were produced in the largest quantities 
in 1974 were Pigment Yellow 12, 8.0 million pounds; Pigment Blue 15, beta form, 
6.0 million pounds; Pigment Blue 15, alpha form, 5.1 million pounds; and Pigment 
Red 49, barium toner, 4.8 million pounds. 

Production of lakes totaled 2.3 million pounds in 1974--4.6 percent less than the 
2.4 million pounds reported for 1973. SAles of lakes in 1974 amounted to 2.2 
million pounds, valued at $5.0 million, compared with sales in 1973 of 2.5 million 
pounds, valued at $3.6 million. Sales in 1974 were 12.5 percent less than those 
in 1973 in terms of quantity, and 39.7 percent more in terms of value. 

For each of 9 selected pigments, or groups of pigments, table lA gives data on 
sales by commercial forms. Pigment Yellow 12 and Pigment Red 53, barium toner, 
were sold principally in the flushed form. The remaining 7 pigments, or groups 
of pigments, for which statistics are published were sold principally in the dry 
full-strength form. Statistics on sales by commercial forms could not be published 
for Pigment Red 49, barium toner. Pigment Red 49, calcium toner. Pigment Red 49, 
sodium toner. Pigment Red 90, Pigment Violet 3, fugitive, Pigment Blue 19, and 
Pigment Blue 24, without revealing the operations of individual companies. 



See also table 2 which lists these products and identifies the manufacturers 
by codes. These codes are listed in table 3. 



ORGANIC PIGMENTS ss 

TABLE 1,— Organic pigments; U.S. production and sales, 197^ 

[Listed below are all organic pigments for which any reported data on production or sales may be published. (Leaders 
(,,,) are used where the reported data are accepted in confidence and may not be published or where no data were 
reported.) Table 2 lists separately all organic pigments for which data on production and/or sales were reported and 
identifies the manufacturers of each] 



Pigment 



Production 



Quantity 



Unit 
value^ 



Grand total 

TONERS 
Total 

Yellow toners, total 

Acetoacetarylide yellows: 

Pigment Yellow 1, C.I. 11 680 

Pigment Yellow 3, C.l. 11 710 

Pigment Yellow 73, C.I. 11 738 

Pigment Yellow 74, C.l. 11 741 

Benzidine yellows, total 

Pigment Yellow 12, C.l. 21 090 - — 

Pigment Yellow 14, C.l. 21 095 

Pigment Yellow 17, C.l. 21 105 

Pigment Yellow 83 

All other 

All other 

Orange toners, total 

Pigment Orange 5, C.I. 12 075 

Pigment Orange 13, C.I. 21 110 

Pigment Orange 16, C.l. 21 160 

Pigment Orange 34, C.I. 21 115 

All other 

Red toners, total 

Naphthol reds, total 

Pigment Red 2, C.I. 12 310 

Pigment Red 5, C.I. 12 490 

Pigment Red 17, C.I. 12 390 

Pigment Red 22, C.l. 12 315 

Pigment Red 23, C.I. 12 355 

Other naphthol reds 

Pigment Red 3, C.I. 12 120 

Pigment Red 4, C.I. 12 085 

Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. IS 630: 

Barium toner 

Calcium toner 

Pigment Red 52, C.I. 15 860 

Pigment Red 53, C.I. 15 585, barium toner- 
Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.l. 45 160, PMA 

Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 90, C.I. 45 380 

Pigment Red 122 

All other 



1,000 
pounds 
69,798 



18,755 



301 
1,170 
1,295 
13.943 
8,019 
3,604 

834 

1,486 
1,382 



757 
434 
358 



24,243 



1,084 
90 
83 
58 
115 
240 
498 
2,240 
364 
2,554 

4,787 
1,257 
1,730 
3,656 
1,553 



1,633 



1,000 
pounds 
58,481 



428 
205 

1,041 

10,031 

5,468 

2,927 

472 

9 

1,155 

1,812 

1,470 



614 
256 
296 



22,101 



817 

39 

31 

48 

100 

198 

401 

1,807 

364 

2,296 



1,294 
1,552 
3,466 
1,323 

579 
80 



5,759 



1,000 
io I lars 
227,812 



49,564 



1,344 
627 

4,319 
33,627 
16,432 
9,246 
1,789 
60 
6,100 
9,647 

7,190 



1,876 
1,209 
1,234 
265 
2.606 

71,805 



4,775 

152 

250 

247 

506 

1,270 

2,350 

5,348 

846 

7,560 

7,811 
2,469 
5,346 
7,715 
4,619 

4,232 
663 

1,178 
19,243 



Per 

pound 

$3.90 



3,14 
3.06 

4.15 
3,-35 
3,01 
3.16 
3.79 
6.67 
5.28 
5.32 



5.76 
10.10 



3.25 



3.90 
8.06 
5. IS 
5.06 
6.41 
5.86 
2.96 
2.32 
3.29 

1.67 
1.91 
3.44 



7.31 
8.29 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEHICALS, 197'l 



TABLE 1, --Organic pigments: U.S. production and sales. 1974--Continued 



Pigments 



Production 



Unit 
lvalue ^ 



TONERS--Continued 

Violet toners, total 

Pigment Violet 1, C.I. 45 170, PTA 

Pigment Violet 3, C.I. 42 535, fugitive 

Pigment Violet 3, C.I. 42 535, PNIA 

Pigment Violet 3, C.I. 42 535, PTA- 

Pigment Violet 23, C.I. 51 319 — 

All other 

Blue toners, total 

Pigment Blue 14, C.I. 42 600, PMA . 

Pigment Blue 15, C.I. 74 160, alpha form 

Pigment Blue 15, C.I. 74 160, beta form 

All other 

Green toners, total 

Pigment Green 1, C.I. 42 040, PMA 

Pigment Green 2, C.I. 42 040 and 49 005, PHA- 
Pigment Green 2, C.I. 42 040 and 49 005, PTA- 

Pigment Green 7, C.I. 74 260 

Pigment Green 36, C.I. 74 265 

All other 

Brown and black toners, total 

Pigment Brown 5, C.I. 15 800 

All other 

LAKES 

Total 

Red lakes: 

Pigment Red 60, C.I. 16 105 

Pigment Red 83, C.I. 58 000 

(Acid Red 26), C.I. 16 150 

Violet lake: Pigment Violet 5, C.I. 58 055 

All other lakes 



1,000 
pounds 



2,859 



122 
534 
424 
59 
225 
1,445 

15,478 



284 
5,137 
6,032 
4,025 

3,960 



52 

38 

3,272 

228 
362 

285 



4 74 
52 



174 
1,563 



1,000 
pounds 



103 
531 
370 
49 
217 
1,191 

12,845 



265 
3,958 
5,144 
3,478 

3,719 



3,114 
253 
258 



2,163 



456 
51 
57 

124 

1,475 



1,000 
dollar's 



22,177 



Per 

pound 



932 
1,197 
1,752 

305 
3,618 
14,373 

51,574 



15,977 
23,494 
11,135 

20,015 



36 

479 

246 

16,217 

1,491 

1,546 



1,385 

259 

87 

441 

2,835 



16.67 
12.07 



4.57 
3.20 



3.04 
5.08 
1.53 

3.56 

1.92 



Calculated from rounded figures. 

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the third edition 
of the Colour Index, 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acids, respectively. 



ORGANIC PIGMENTS 



TABLE 1A.-U,S. 



SALES OF SELECTED DRY FULL-STRENGTH COLORS, DRY EXTENDED COLORS, DRY DISPERSIONS, 
AQUEOUS DISPERSIONS, AND FLUSHED COLORS, 197^ 



Selected pigments by commercial forms 



Quantity 



Unit 
value^ 



Pigment Yellow 12, C.I. 21 090, total 

Dry full-strength toner 

Flushed color 

Aqueous dispersions ' and dry dispersions**- 



Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.l. 21 095; Pigment 

Yellow 17, C.I. 21 105; and other benzidine yellows, total 

Dry full -strength toner 

Aqueous dispersions' 

Flushed color 

Dry extended toner and dry dispersions'* 



Pigment Red 3, C.I. 12 120, total 

Dry full-strength toner 

Dry extended toner, aqueous dispersions', and flushed color'*- 



Pigment Red 48, C.I. 15 865, total 

Dry full-strength toner 

Dry extended toner, dry dispersions, and aqueous dispersions'-' 
Flushed color 



Pigment Red 53, C.I. IS 585, barium toner, total- 
Dry full-strength toner 

Flushed color 

Dry dispersion and aqueous dispersions'' '" 



Pigment Violet 3, C.I. 42 535, PMA and PTA, total- 
Dry full-strength toner 

Flushed color 

Dry extended toner and aqueous dispersions'"'' — 



Pigment Blue 15, C.I. 74 160, alpha form, total- 
Dry full-strength toner 

Aqueous dispersions ' 

Flushed color 

Dry dispersion and dry extended toner'* 



Pigment Blue 15, C.I. 74 160, beta form, total- 
Dry full-strength toner 

Dry extended toner and dry dispersions'* 

Aqueous dispersions' 

Flushed color 



Pigment Green 7, C.I. 74 260, total- 
Dry full-strength toner 

Dry extended toner 

Flushed color and dry dispersion '*- 
Aqueous dispersions ' 



1,000 
pounds 



1,680 
3,379 



4,563 



2,554 
1,091 



1,109 
698 



,010 
126 
160 



1,845 
333 



3,958 



1,656 

1,175 

449 

678 

5,144 



1,220 
1,728 



3,114 



1,493 
280 
294 

1,047 



1,000 
dollars 



4,872 

10,932 

1,199 



17,400 



10,104 

3,998 

3,192 

106 

5.569 



3,120 
2,449 



,576 
444 
541 



2,716 

4,360 

716 



1,520 
388 
164 

15,977 



8,041 
3,454 
1,307 
3,175 

23,888 



9,586 

567 

4,967 

8,768 

16,381 



8,372 
1,299 
1,910 



Per 

pound 

$3.11 



3.66 
3.59 
3.53 



3.52 
3.38 



2.11 
2.36 
2.15 



4.81 
6.47 
3.81 

4.04 



4.86 
2.94 
2.91 
4.68 

4.64 



4.50 
4.07 
5.07 



4.64 
6.50 

4.58 



Quantity of the various commercial forms is given in terms of dry full-strength toner content, 
^ Calculated from rounded figures. 
Includes presscake. 

Separate data on these commercial forms may not be published without revealing the operations of individual 
companies. 

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the third edition 
of the Colour Index, 

The abbreviations PN1A and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstoraolybdic) 
acids, respectively. 



SYNTHETIC ORGANIC CHEMICALS. 197^! 
TABLE 2. --Organic pigments for which D.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1^7^ 



[Organic pigments for which separate statistics are given in table 1 are marked below with an asterisk C*); products 
not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be pub- 
lished. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufac- 
turer did not consent to his identification with the designated product] 



Pigment 



Manufacturers' identification code 
(according to list in table 3) 



TONERS 

♦Yellow toners: 

Acetoacetarylide yellows: 
♦Pigment Yellow 1, C.I. 11 680 

♦Pigment Yellow 3, C.l. 11 710 

Pigment Yellow 4, CI. 11 665 

Pigment Yellow 5, CI. 11 660 

Pigment Yellow 6, CI. 11 670 

Pigment Yellow 60, CI. 12 705 

Pigment Yellow 65 

♦Pigment Yellow 73, CI. 11 738 

♦Pigment Yellow 74, CI. 11 741 

Pigment Yellow 75, CI. 11 770 

Pigment Yellow (17 

All other acetoacetarylide yellows 

'Benzidine yellows: 

♦Pigment Yellow 12, CI. 21 090 

Pigment Yellow 13, CI. 21 100 

♦Pigment Yellow 14, CI. 21 095 

♦Pigment Yellow 17, CI. 21 105 

Pigment Yellow 55 (includes Pigment Yellow 76), CI 

21 096 

♦Pigment Yellow 83 

(Vat Yellow 83) 

All other benzidine yellows 

Pigment Yellow 16, C.l. 20 040 

Pigment Yellow 108, CI. 68 420 

Pigment Yellow 'l09 

Pigment Yellow 110 

Pigment Yellow 112 (Vat Yellow 1), CI. 70 600 

(Basic Yellow 2), CI. 41 000, fugitive 

(Basic Yellow 37), CI. 41 001 

(Direct Yellow 4), CI. 24 890 

(Direct Yellow 6), CI. 40 001 

(Direct Yellow 11), CI. 40 000 

(Vat Yellow 97) 

All other 

♦Orange toners : 

Pigment Orange 1, CI. 11 725 

Pigment Orange 2, CI. 12 060 

♦Pigment Orange 5, C.l. 12 075 

♦Pigment Orange 13, CI. 21 110 

Pigment Orange 14, CI. 21 165 

Pigment Orange 15, CI. 21 130 

♦Pigment Orange 16, CI. 21 160 

♦Pigment Orange 34, CI. 21 115 

Pigment Orange 43 (Vat Orange 7), C.l. 71 105 

Pigment Orange 46, CI. 15 602 

All other 

♦Red toners: 

♦Naphthol reds: 

♦Pigment Red 2, CI. 12 310 

♦Pigment Red 5, CI. 12 490 

Pigment Red 7, CI. 12 420 



ACS, ACY, AMS, CPC, DUP, HPC, HSC, HSH, HST, KON, S, 

SDll, SNA. 
ACS, HPC, HSC, HSH, HST, KCW, KON, PPG. SNA. 
ACS 
HPC 
CIK 
KON 
ACS 
ACS 
ACS 
HPC 
ACS 
DUP 



APO 
ACS 



HPC 
ACS 
HST 
HSH 
HST 
ACS 
ACS 
ACS 
ACS 
LVR 
LVR 
LVR 
LVR 
LVR 
HST 
BAS 

ACS 
HPC 
ACY 
ACS 
ROM 
ACS 
ACS 
BUC 
ACS 
HSC 
KON 



HPC. 

CIK, HPC, SNA. 

DUP, HPC, HSC, SDH, SNA. 



KCW. 



AUS, APO, BOR, HPC, HSC, HSH, HST, ICC, KON, 

1, S, SDH, SNA. 

BUC, GAP, HPC, HSH, HST, ICC, MRA, ROM, SDH, SNA. 

AMS, BUC, GAP, HPC, HSC, HSH, HST, ICC, MRA, ROM, 

SDH, SNA, X. 

AMS, BUC, HPC, HSC, HST, ICC, MRA, ROM, SDH, SNA. 



HSC, SNA. 

ICC, ROM, S. 

ICC 

ICC. 



ICC, s. 

KCW. 

UHL. 

HPC, HSC, HST, SDH, SNA. 

AMS, HPC, HSC, ICC, KON, HRX, S, SNA. 



GAP, HPC, HSC, HSH, HST, ICC, 

ICC, MRA, SDH. 

HST. 



MRA, ROM, SDH, SNA. 



ACS, HPC. HSH, KCW, KON, S. 
GAP, HPC, HSH, ICC, ROM, S, SDH. 

HST, S. 



ORGANIC PIGMENTS 



TABLE 2. --Organic pigments for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197il--CONTINUED 



Pigment 



Manufacturers' identification codes 
(according^ to list in table 3] 



TONERS - -Conti nued 

*Red toners --Continued 

♦Naphthol reds --Continued 

Pigment Red 9, C.I. 12 460 

Pigment Red 13, C.I. 12 395 

Pigment Red 15, C.I. 12 465 

*Pigment Red 17, C.I. 12 390 

♦Pigment Red 22, C.I. 12 315 

♦Pigment Red 23, C.I. 12 355 

Pigment Red 31, C.I. 12 360 

Pigment Red 112, C.I. 12 370 

All other naphthol reds 

Pigment Red 1, C.I. 12 070, dark 

Pigment Red 1, C.I. 12 070, light 

♦Pigment Red 3, C.I. 12 120 

♦Pigment Red 4, C.I. 12 085 

Pigment Red 6, C.I. 12 090 

Pigment Red 19, C.I. 46 500 

Pigment Red 38, C.I. 21 120 

Pigment Red 40, C.I. 12 170 

Pigment Red 41, C.I. 21 200 

♦Pigment Red 48, C.I. 15 865 

Pigment Red 49, C.I. 15 630: 

♦Barium toner 

♦Calcium toner 

Sodium toner 

♦Pigment Red 52, C.I. 15 860 

♦Pigment Red 53, C.I. 15 585, barium toner-- 
Pigraent Red 53, C.I. 15 585, sodium toner-- 
Pigment Red 54, C.I. 14 830, calcium toner- 
Pigment Red 55, C.I. 15 820 

♦Pigment Red 57, C.I. 15 850, calcium toner- 
Pigment Red 58, C.I. 15 825 

♦Pigment Red 63, C.I. 15 880 

Pigment Red 81, C.I. 45 160, fugitive 

♦Pigment Red 81, C.I. 45 160, PMA 

♦Pigment Red 81, C.I. 45 160, PTA 

Pigment Red 87, C.I. 73 310 

Pigment Red 88, C.I. 73 312 

♦Pigment Red 90, C.I. 45 380 

♦Pigment Red 122 

Pigment Red 123, C.I. 71 140 (similar to)-- 

Pigment Red 146 

Pigment Red 149 

Pigment Red 168 (Vat Orange 3), C.I. 59 300 

Pigment Red 170 

Pigment Red 176 

Pigment Red 177 

Pigment Red 179, C.I. 71 130 

Pigment Red 181 (Vat Red 1), C.I. 73 360—- 

Pigment Red 185 

Pigment Red 190 (Vat Red 29), C.I. 71 140 — 
Pigment Red 194 (Vat Red 15), C.I. 71 100 — 
Pigment Red 197 (Vat Orange 4), C.I. 59 710 

Pigment Red 198, C.I. 73 390 

(Direct Red 81), C.I. 28 160 

(Vat Red 41), C.I. 73 300 

All other 



HST, MRX. 
KCW. 



HPC, 

HPC, 

DUP. 

ACY, HPC, ICC, 

ACY, DUP, GAP, 

ACY. BUC, DUP, 

MRA. 

HPC, HST. 

ICC, KCW. ROM, 

AflS, HPC, HSH, 

HPC, HSH, SDH. 

ACY, CIK, CPC, 

SNA, UHL. 

ACY, AMS, HPC, 

DUP, HSH, KCW, 
URA. 

ACS, GAP, SNA. 
HSH. 
ACS. 

ACS, ACY, AMS, 

SNA. 

ACY, AMS, BOR, 

ACY, AUS. BOR, 

HSC. KON, SDH. 

APO, HPC, HSC, 

ACY, AJ1S, BOR, 

HSC, KON. 

HPC, HSH, SDH. 

HSH. 

AMS, APn, BOR, 

DUP, HPC. 

HSH, KON, SNA. 

MGR. 

BOR, CPC, DUP, 

AMS, DUP, GAP, 

ACS. 

ACS, HST. 

AHS, BOR, SDH. 

ACS, HST, SNA. 

ACS, HSC. 

HST. 

HST. 

ACS, HST. 

HST. 

HST. 

TRC. 

ACS. 

HST. 

HST. 

ACS, HSC. 

HST. 

ACS. 

ACS. 

LVR. 

HST. 

DUP, ICC, X. 



S. SNA, UHL. 

HPC, MRX, S, SNA. 

HPC, ICC, ROM, SDH, S, UHL. 



S, SDH. 
KON. 



DUP, HPC, HSC, HSH, KCW, KON, PPG, SDH, 



HSC, KON, MRX, SDH, UHL. 
KON. 



BOR, DUP, GAP, HPC, HSC, HSH, ICC, S, 



CIK, HSC, KON, SDH, SNA, UHL. 
HSC, SDH. 



HSH. SNA. 

CIK, HPC, HSC, KON, MGR, MRX, SDH, SNA. 



CIK, DUP, HPC, HSC, KON, MGR, SDH, SNA. 



GAP, HPC, KON, MGR, MRX, SNA, UHL. 
HPC, HSC, KON, MGR, MRX, SNA, UHL. 



SYNTHETIC ORGANIC CHEMICALS. 197'! 



TABLE 2.— Organic pigments for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'!— CONTINUED 



Pigment 



TONERS--Continued 

•Violet toners; 

Pigment Violet 1, C.I. 45 170, fugitive 

Pigment Violet 1, CI. 45 170, PMA 

♦Pigment Violet 1, C.I. 45 170, PTA 

CI. 42 535, fugitive 

CI. 42 535, PMA 

CI. 42 535, PTA 

, CI. 46 500 

, CI. 51 319 

.1. 60 010- 
.1. 73 385- 



*Pigment Violet 3, 
♦Pigment Violet 3, 
♦Pigment Violet 3, 
Pigment Violet 19 
♦Pigment Violet 23 
Pigment Violet 31 (Vat Violet 1) 
Pigment Violet 36 (Vat Violet 2) 
Pigment Violet 38, CI. 73 395-- 

All other 

♦Blue toners : 

lue 1 , 
lue 1 , 



Pigment B 

Pigment B 

Pigment B 

Pigment B 

Pigment B 

Pigment B 

Pigment B 

Pigment B 

'Pigment B 

Pigment B 

♦Pigment B 

♦Pigment B 



ue 2, CI. 
ue 2, CI. 
ue 9, CI. 
ue 9, CI. 
ue 10, CI 
ue 10, 
ue 14, 



PMA- 
PTA- 



C.I 
CI 

14, CI 



42 595, PMA- 

42 595, PTA- 

44 045, 

44 045, 

42 025, PMA-- 

42 025, PTA-- 

44 040, PMA- 

44 040, PTA- 

42 600, PHA- 

42 600, PTA- 



ue 15, CI. 74 160, alpha form- 



IS, CI. 74 160, beta form- 



ue 19, CI. 

ue 22, CI. 

.ue 25, CI. 

ue 27, CI. 



Pigment B] 

Pigment B] 

Pigment B! 

Pigment B] 

All other 

♦Green toners; 

♦Pigment Green 1, CI. 

Pigment Green 1, CI. 

♦Pigment Green 2, CI. 

♦Pigment Green 2, CI. 

Pigment Green 4, CI. 

Pigment Green 4, CI. 

Pigment Green 4, CI. 

♦Pigment Green 7, CI. 



42 750A- 
69 810 — 
21 180-- 
77 510-- 



42 040, PMA 

42 040, PTA 

42 040 and 49 005, PMA- 
42 040 and 49 005, PTA- 

42 000, fugitive 

42 000, PMA 

42 000, PTA— 

74 260 



Pigment Green 8, CI. 10 006 

Pigment Green 10, CI. 12 775 

•Pigment Green 36 (including Pigment Green 38), CI. 
74 265 

Pigment Green 40- 



♦Brown and Black toners: 

Pigment Brown 2, CI. 

Pigment Brown 3, CI 

♦Pigment Brown 5, 

Pigment Brown 26, 



12 071 

21 010, PMA- 
I. 15 800 

71 129 



Manufacturers' identification codes 
(according to list in table 3) 



UllL. 
GAP, 
DUP, 
ACY, 
AMS, 
ACY, 
ACS, 
ACS, 
DUP. 
HST. 
ACS. 
ACY, 



HPC, MGR, MRX, SNA, UHL. 

GAP, HPC, HSC, MGR, MRX, SNA. 

AMS, HSC, KON, MGR, UHL. 

CIK, DUP, GAP, HPC, HSC, KON, MGR, MRX, SDH, UHL. 

HPC, HSC, KON, MRX. 

DUP, SNA. 

BUC, GAP, HSC, HST, MRA, SDC, SNA. 



BUC, HPC, ICC, LVR, ROM. 



DUP, GAP, HPC, KON, MGR, MRX, UHL. 

GAP, KON, MRX. 

GAP, HSC. 

KON. 

KON, UHL. 

GAP. 

SDH. 

LVR. 

DUP, GAP, HPC, LVR. 

DUP, GAP, LVR. 

ACS, ACY, APn, DUP, GAP, HPC, HSC, ICC, MGR, MRA, SNA, 

TMS. 
ACS, ACY, A.MS, BAS, BOR, BUC, DUP, GAP, HPC, HSC, ICC, 

POP, SDH, SNA, TMS. 
AfIS, HSC, SW. 
ACS, DUP. 
ICC, S. 
CPC 
DUP, GAP, SDH, TNI, UHL. 

MRX, S, UHL. 

MGR. 

GAP, KON, MGR, MRX, UHL. 

ACY, DUP, HPC, KON, MRX. 

GAP. 

KON, MGR. 

ACY. 

ACS, ACY, BAS, CIK, DUP, GAP, HPC, HSC, POP, SDH, SNA, 

TMS. 
HPC, HSH, KCW. 
DUP, HPC. 

ACS, ACY, DUP, GAP, SNA. 
HST. 



KCW, KON. 

ACS, BUC, ICC, ROM. 

ACS. 



ORGANIC PIGFiEIJTS 



TABLE 2. 



-Organic pigments fok which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 197'|--CONTINUED 



Manufacturers' identification codes 
Taccording to list in table 31 



TONERS- -Continued 

•Brown and Black toners--Continued 

Pigment Brown 32 

(Acid Brown 14), C.I. 20 195 

Pigment Black 7, C.I. 77 266 

All other 



HST. 
LVR. 
GAP. 
DUP, SDH, UHL. 



LAKES 



(Acid Yellow 23) , 



19 140- 



I. 15 530-- 
.1. 15 510- 



Yellow lakes: 
Orange lakes: 

Pigment Orange 7, C. 

Pigment Orange 17, C 
Red lakes: 
♦Pigment Red 60, C.I. 16 105 --- 

Pigment Red 81, C.I. 45 160, PMA--- 

♦Pigment Red 83, C.I. 58 000 

(Acid Red 17), C.I. 16 180 

*(Acid Red 26), C.I. 16 150 - 

All other 

Violet lakes: *Pigment Violet 5, C.l. 58 055- 
Blue lakes: 

Pigment Blue 17, C.I. 74 180 

Pigment Blue 24, C.I. 42 090 

Brown lakes 



KON, 


HRX. 












CPC. 














KCW. 


KON. 












HSH, 


KON, 


HRX, 


SDH, 


SNA. 






LVR. 














HPC, 


HSH, 


KON, 


MRX, 


UHL. 






HPC. 














CPC, 


HPC. 


KCW. 










LVR. 














ACS, 


DUP, 


HPC, 


HSH, 


KON, 


MRX, 


S, UHL 


CPC, 


GAP. 












AHS, 


BOR, 


KON, 


SDH. 








KON. 















Note. — The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the third edition 
of the Colour Index. 

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the 
pigment can be made and that no name for the pigment itself is given in the Colour Index. 

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) 
acid, respectively. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 3.— Organic pigments; Directory of manufacturers, 197'l 



ALPHABETICAL DIRECTORY BY CODE 

[Names of organic pigment manufacturers that reported production or sales to the U.S. International Trade Commission 
for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACS 


Allied Chemical Corp., Specialty Chemicals 
Div. 


KON 


H. Kohnstamm 5 Co., Inc. 


ACY 


American Cyanamid Co. 






AMS 


Sinclair 6 Valentine Co., Inc., 








Ridgway Color 5 Chemical 


LVR 


C. Lever Co., Inc. 


APO 


Apollo Colors, Inc. 










MGR 


Magruder Color Co., Inc. 


BAS 


BASF Wyandotte Corp. 


MRA 


Crown Metro, Inc., 


BOR 


Borden, Inc., Printing Ink Div. 


MRX 


Max Marx Color 5 Chemical Co. 


BUC 


Synalloy Corp. , Blackman-Uhler 
Chemical Div. 










POP 


Pope Chemical Corp. 






PPG 


PPG Industries, Inc. 


CIK 


Tenneco Chemicals, Inc., Cal/Ink Div. 






CPC 


Childs Pulp Colors, Inc. 










ROM 


United Merchants S Manufacturers, Inc., 
Roma Chemical Div. 


DUP 


E. I. duPont de Nemours 6 Co., Inc. 










S 


Sandoz, Inc., Color S Chemicals Div. 


GAP 


GAP Corp., Chemical Div. 


SDC 


Martin-Marietta Corp., Southern Dyestuff Co. 
Div. 






SDH 


Sterling Drug, Inc., Hilton-Davis Chemical 


HPC 


Hercules, Inc. 




Co. Div. 


HSC 


Chemetron Corp., Pigments Div. 


SNA 


Sun Chemical Corp. 


HSH 


Harshaw Chemical Co., Div. of Kewanee 
Oil Co. 


SW 


The Sherwin-Williams Co. 


hst 


American Hoechst Corp. 










TMS 


Sterling Drug, Inc., Thomasset Colors Div. 






TNI 


Gillette Co., Gillette Chemical Co. Div. 


ICC 


Inmont Corp. 


TRC 


Toms River Chemical Corp. 


KCW 


Keystone Color Works, Inc. 


UHL 


Paul Uhlich 5 Co. , Inc. 



Note. — Complete names and addresses of the above reporting companies are listed in table 1 of the appendix. 



MEDICIMAL CHEMICALS 93 

Medicinal Chemicals 

Medicinal chemicals include the medicinal and feed grades of all 
organic chemicals having therapeutic value, whether obtained by chemical 
synthesis, by fermentation, by extraction from naturally occurring plant 
or animal substances, or by refining a technical grade product. They 
include antibiotics and other anti-infective agents, antihistamines, 
autonomic drugs, cardiovascular agents, central nervous system depres- 
sants and stimulants, hormones and synthetic substitutes, vitamins, and 
other therapeutic agents for human or veterinary use and for animal feed 
supplements . 

The table shows statistics for production and sales of medicinal 
chemicals grouped by pharmacological class. The statistics shown are for 
bulk chemicals only; finished pharmaceutical preparations and products put 
up in pills, capsules, tablets, or other measured doses are excluded.^ The 
difference between production and sales reflects inventory changes, pro- 
cessing losses, and captive consumption of medicinal chemicals processed 
into ethical and proprietary pharmaceutical products by the primary manu- 
facturer. In some instances, the difference may also include quantities 
of medicinal grade products used as intermediates, e.g., penicillin G 
salts used as intermediates in the manufacture of semi-synthetic peni- 
cillins. All quantities are given in terms of 100-percent content of the 
pure bulk drug. 

Total U.S. production of bulk medicinal chemicals in 1974 amounted 
to 246.5 million pounds, or 5.5 percent more than the 233.6 million pounds 
produced in 1973 and 5.2 percent more than the 234.3 million pounds pro- 
duced in 1972. Total sales of bulk medicinal chemicals in 1974 amounted to 
177.5 million pounds, valued at $814.8 million, compared with sales in 1973 
of 179.2 million pounds, valued at $582 .4 million, and sales in 1972 of 
163.2 million pounds, valued at $490.1 million. In terms of quantity, sales 
in 1974 were thus 1 percent less than in 1973 and 8.8 percent larger than 
in 19 72. In terms of value, however, sales in 1974 were 39.9 percent 
larger than in 19 73 and 66.3 percent larger than in 19 72. 

Production of the more important groups of medicinal chemicals in 1974 
was as follows: Antibiotics, 20.5 million pounds (1.4 percent less than in 
1973), of which 13.2 million pounds was for medicinal use and 7.4 
million pounds was for other uses; anti-infective agents other than anti- 

^ Complementary statistics on the dollar value of manufacturers' ship- 
ments of finished pharmaceutical preparations, except biologicals, are 
published annually by the U.S. Department of Commerce, Bureau of the Census, 
in Current Industrial Reports, Series MA-28G. Many pharmaceutical manu- 
facturers who report to the Bureau of the Census are excluded from the U.S. 
International Trade Commission report because they are not primary pro- 
ducers of medicinal chemicals, that is, they do not themselves produce the 
bulk drugs which go into their pharmaceutical products but purchase their 
drug requirements from domestic or foreign producers. 



.94 SYNTHETIC ORGANIC CHEMICALS, 1974 



biotics, 39.3 million pounds (18.2 percent greater than in 1973); central 
nervous system depressants and stimulants, 52.8 million pounds (8.6 per- 
cent larger); and vitamins, 40.9 million pounds (20.2 percent larger). 

Production of some of the more important individual products listed in 
the table was as follows: Choline chloride, 39.8 million pounds (14.6 
percent smaller than in 1973); aspirin, 33.3 million pounds (3.5 percent 
larger); ascorbic acid, 22.2 million pounds (43.8 percent larger); peni- 
cillins (except semi-synthetic), 5,240 trillion units (6 percent larger); 
tetracyclines, 2.5 million kilograms (11.6 percent larger); and vitamin E, 
1,849 billion units (6.8 percent larger). 



flEDICINAL CHEHICALS 
TABLE 1.— Medicinal chemicals; U.S. production and sales, 1974 



[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may 
be published, (Leaders( . . . ) are used where the reported data are accepted in confidence and may not be published or 
where no data were reported.) Table 2 lists all medicinal chemicals for which data on production and/or sales were 
reported and identifies the manufacturer of each] 



Grand total 

Acyclic 

Benzenoid' 

Cyclic nonbenzenoid* 

Antibiotics, total* 

Antifungal and antitubercular antibiotics, for 

medicinal use 

Neomycin, for medicinal use 

Penicillins (except semisynthetic), total 

Penicillin G, potassium for medicinal use 

All other, for all uses 

Semisynthetic penicillins, for medicinal use, total 

Ampicillin 

Arapicillin, sodium 

All other 

Tetracyclines, for all uses 

Other antibiotics, total 

For medicinal use^ 

For nonmedicinal uses' 

Antihistamines, total 

Antinauseants 

Chlorpheniramine maleate 

All other 

Anti-infective agents (except antibiotics), total 

Anthelmintics, total 

Piperazine 

Piperazine dihydrochloride 

Piperazine hydrochloride 

All other 

Antifungal agents 

Antiprotozoan agents, total 

Arsenic and bismuth compounds 

All other 

Mercury compounds 

Oxyquinoline sulfate 

Sulfonamides 

Urinary antiseptics 

Other anti-infective agents* 

Autonomic drugs, total 

Parasympatholytic (anticholinergic) tertiary amines 

(except tropane derivatives) 

Sympathomimetic (adrenergic) agents, total 

Phenylephrine base, bitartrate, and tannate 

Phenylpropanolamine hydrochloride 

All other 

Other autonomic drugs 

Cardiovascular agents 



See footnotes at end of table. 



Production 



1,000 
pounds 



102,807 
119,014 
24,632 



1,238 

7,812 
5,130 
4,682 
1,454 
1,057 
47 
350 
5,579 
4,466 
2,266 
2,200 



39,258 



Quantity 



12,677 

4,582 

1,932 

603 

5,560 

989 

13,352 

5,932 

7,420 

12 

9 

7,104 

497 

4,618 



372 
476 



3,098 



1,000 
pounds 



177.515 



83,927 
76,565 
17,023 



821 
132 
,149 

,149 
312 



56 
795 

2,041 
881 

1,160 



27,243 



8,444 
1,553 
1,945 
350 
4,596 

12,619 

12,619 
12 

n 

2,650 

3,507 

764 



1,000 
dollars 



101,315 
466,099 
247,353 



24,009 
2,997 



47,656 
27,461 
23,070 

4,391 
21,313 
131,041 
109,954 
21,087 

13,951 



13,951 
104,242 



46 

696 

9 

353 



1,461 



34,822 
1,435 



31,326 

40,602 

40,602 

681 

55 

13,921 

14,161 

16,404 



2,316 
12,421 
466 
2,322 
9,633 
1,667 

22,223 



SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 1.— Medicinal chemicals; U.S. production and sales, 197^1— Continued 



Production 



Quantity 



Central depressants and stimulants, total 

Amphetamines 

Analgesics and antipyretics, total 

Acetanilide derivatives 

Aspirin 

Meperidine hydrochloride 

Methadone hydrochloride 

All other 

Antidepressants 

Barbiturates 

Hypnotics and sedatives (except barbiturates) 

Skeletal muscle relaxants and tranquilizers 

Other central depressants and stimulants' 

Dermatological agents (except salicylic acid) and local 
anesthetics 

Diagnostic agents, total 

Roentgenographic contrast media 

All other 

Expectorants and mucolytic agents, total 

Ethyl enediamine dihydriodide 

All other 

Gastrointestinal agents (except methionine, hydroxy 

analog) , total 

Choleretics and hydrocholeretics 

Choline chloride (all grades) 

All other 

Hematological agents, total 

Sodium heparin 

All other 

Hormones and synthetic substitutes, total 

Corticosteroids 

Estrogens and progestogens 

Synthetic hypoglycemic agents 

Thyroii hormone and antithyroid agents 

All other 

Renal-acting and edema-reducing agents, total 

Benzothiadiazine derivatives 

Mercurial diuretics 

Theophylline derivatives 

All other 

Therapeutic nutrients 

Vitamins, total 

Ascorbic acid 

Niacin and niacinamide (all grades) 

Pantothenic acid and derivatives, total 

Calcium pantothenate (racemic) -calcium chloride 

complex 

All other 



See footnotes at end of table. 



1,000 
pounds 

52,810 



43,680 

7,769 

33,290 

35 

4 

2,532 

196 

587 

336 

1,085 

6,915 



1,490 



1,297 
597 



39,788 
1,216 



157 
2,128 



1,895 



22,166 
5,150 
3,382 

2,056 
1,326 



1,000 
vounds 



1,000 
dollars 



35,824 
1,062 



130 
('") 

205 

1,430 
29,506 



5,245 
2,349 



2,349 



63,362 
14,534 



48,828 



4,262 
170 



39,988 



7,195 



4,446 
2,749 



11,966 
2,909 



3,412 
61,224 



44,356 
5,130 



11,738 
7,949 



10 

2,956 

4,337 

158,704 



9,053 



MEDICINAL CHEMICALS 
TABLE 1. --Medicinal chemicals; U.S. production and sales. 197iJ--CoNTiNUED 



Production' 



Quant ity 



Unit 
value^ 



Vitamins- -Continued 

Vitamin D" 

Vitamin e" • 

Vitamin K 

All other vitamins 

Miscellaneous medicinal chemicals'^- 



1,000 
pounds 



3,672 

225 

6,256 

37,572 



1,000 
pounds 



11 
3,229 

18,672 

29,271 



1,000 
dollars 



3,360 
52,456 



88,997 
35,552 



Per 
pound 



$305.45 
16.25 



4.77 
1.21 



' The data on production and sales are for bulk medicinal chemicals only; they exclude finished preparations and 
dosage-form products, which are manufactured from bulk chemicals. All quantities are given in terms of 100% active 
ingredient. 

Calculated from rounded figures. 

' The term "benzenoid," as used in this report, describes any cyclic medicinal chemical whose molecule contains 
either a six-membered carbocyclic ring with conjugated double bonds (e.g., the benzene ring or the quinone ring) or a 
six-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the pyrimidine ring Ce.g- 
the pyridine ring or the pyrazine ring.) 

* Includes antibiotics of unknown structure. 

^ With the exception of bacitracin, the penicillins (except semisynthetic), and a few other antibiotics which were 
reported in terms of U.S. P. units, all quantities for antibiotics were reported as grams of antibiotic base. (Thus 
production of 480,900 grams of tetracycline hydrochloride, for example, would have been reported as 444,430 grams 
of tetracycline base.) For inclusion in the main statistical table, all quantities were converted from grams of 
antibiotic base to pounds of antibiotic base (453.6 grams = 1 pound) or from U.S. P. units to pounds (22.7 million 
units of bacitracin, 458 million units of procaine penciUin G, 723 million units of potassium penicillin G, etc. = 
1 pound). The following tabulation shows statistics for all individually publishable antibiotics in terms of kilo- 
grams of antibiotic base (Kg) or billions of U.S. P. units (BU) : 



Antibiotic 



Unit of 
quantity 



Production 



Sales 



Unit 
value 



Antifungal and antitubercular anti- 
biotics, for medicinal use 

Neomycin, for medicinal use 

Penicillins (except semisynthetic), 

total 

Penicillin G, potassium, for medicinal 
use 

All other, for all uses 

Semisynthetic penicillins, for 

medicinal use, total 

Ampicillin 

Ampicillin, sodium 

All other 

Tetracyclines, for all uses 



5,239,625 



372,492 
60,007 



2,602,451 



1,000 
do I lars 



24,009 
2,997 



$64.46 
49.94 



2,262,934 
2,976,691 



2,602,451 
141,426 



47,656 



27,461 



194.17 



479,260 

21,475 

158,683 

2,530,725 



116,154 
25,272 
360,515 



23,070 
4,391 
21,313 



198.62 
173.75 
59.12 



' Production of all antibiotics for medicinal use amounted to 13,172,000 pounds, sales amounted to 5,308,000 
pounds, valued at $211,834,000. 

' Production of all antibiotics for animal feeds and other nonmedicinal uses amounted to 7,377,000 pounds, sales 
amounted to 2,943,000 pounds, valued at $42,643,000. 

° Includes sales of antifungal agents and urinary antiseptics. 

' Includes production and sales of anticonvulsants, antitussives, general anesthetics, and stimulants; also includes 
sales of amphetamines, antidepressants, skeletal muscle relaxants, and tranquilizers. 

(Continued) 



SYNTHETIC ORGANIC CHEHICALS, 1974 

Footnotes for' table 1 — Continued 



'" Sales of mercurial diuretics amounted to 160 pounds. 

'' All quantities for vitamins A, B12, D, and E were reported in terms of grams or units, but were converted to 
pounds for inclusion in the main statistical table (1.317 billion units of vitamin A acetate, 0.824 billion units 
of vitamin A palmitate, 453.6 grams of vitamins B12, 18.14 billion units of vitamin D, 617,000 units of d-alpha 
tocopheryl acetate, 454,000 units of dl-alpha tocopheryl acetate, etc. = 1 pound). The following tabulation shows 
statistics for vitamins D and E (vitamins A and B12 were not separately publishable) in terms of millions of inter- 
national units (MU) or billions of U.S. P. units (BU), as appropriate: 



Unit of 
quantity 



Production 



Sales 



Quantity 



Unit 
value 



Vitamin D- 
Vitamin E- 



312,873 
1,849,300 



199,066 
1,631,480 



1,000 

dollars 

3,360 

52,456 



$16.88 
32.15 



'^ Includes production and sales of antineoplastic agents, methionine, hydroxy analog, calcium salt, salicylic 
acid, smooth muscle relaxants, and unclassified medicinal chemicals; also includes sales of diagnostic agents. 



MEDICINAL CHEMICALS 

TABLE 2,— nEDICINAL CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED^ 
IDENTIFIED BY MANUFACTURER, 197^ 



[Medicinal chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*); medic- 
inal chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



•Antibiotics : 

'Antifungal and ant i tubercular antibiotics: 
Antifungal antibiotics: 

Amphotericin B 

Candicidin 

Nystatin 

Antitubercular antibiotics: 

Cycloserine 

Dihydrostreptomycin 

Streptomycin 

Viomycin 

'Neomycin 

'Penicillins (except semisynthetic): 

Penicillin G, benzathine 

'Penicillin G, potassium 

Penicillin G, procaine 

Penicillin G, procaine, for nonmedicinal uses- 
Penicillin G, sodium 

Penicillin 0, sodium 

Phenoxymethylpenicillin (Penicillin V) 

Phenoxymethylpenicillin, benzathine 

Phenoxymethylpenicillin, hydrabamine 

Phenoxymethylpenicillin, potassium 

'Semisynthetic penicillins: 

'Ampicillin 

'Ampicillin , sodium 

Amoxicillin 

Carbenicillin, disodium 

Cloxacillin, sodium 

Did oxacillin , sodium --- 

Hetacillin 

Methicillin, sodium 

Nafcillin, sodium 

Oxacillin, sodium 

Phenethicillin, potassium 

'Tetracyclines : 

Chlortetracycline 

Chlortetracycline, for nonmedicinal uses 

Demeclocycline 

Doxycycline 

Methacycline 

Minocycline 

Oxytetracycline 

Oxytetracycline, for nonmedicinal uses 

Tetracycline 

'Other antibiotics ; 
'For medicinal use: 

Bacitracin 

Cefazolin 

Cephalexin 

Cephaloridine 

Cephalothin 

Chloramphenicol 

Clindamycin 

Dihydrocephalexin 

Erythromycin 

Fumagillin 

Gentamycin 

Kanamycin 



See footnotes at end of table. 



OMS, 


TRD. 




PEN 






ACY, 


OMS, 


TRD. 


COM 






MRK, 


PFZ. 




MRK, 


PFZ. 




PFZ 






OMS, 


PEN, 


PFZ, UPJ. 


WYT. 






OMS, 


PFZ, 


WYT. 


OMS, 


PFZ, 


Wi'T. 


MRK, 


OMS. 




BRS, 


OMS. 




PFZ. 






BRS, 


LIL, 


OMS. 


WYT. 






ABB. 






ABB, 


LIL. 




BEE, 


BOC, 


BRS, TRD, WYT 


BEE, 


OMS, 


WYT. 


BEE. 






BEE, 


PFZ. 




BEE, 


BRS. 




BEE, 


BRS, 


WYT. 


BRS. 






BEE, 


BRS. 




WYT. 






BEE, 


BRS. 




BRS. 






ACY, 


RLS. 




ACY. 






ACY. 






PFZ. 






PFZ. 






ACY. 






PFZ. 






PFZ. 






ACY, 


BRS, 


PFZ. RLS. 


COM, 


PEN. 




LIL. 






LIL. 






LIL. 






LIL. 






PD, 


RLS. 




UPJ. 






SK. 






ABB. 


LIL, 


UPJ. 


ABB. 






SCH. 






BRS. 







SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2,— Medicinal chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, ]97'^ — CONTI NUED 



'Antibiotics --Continued 

♦Other antibiotics--Continued 
*For medicinal use--Continued 

Lincomycin 

Novobiocin 

Oleandomycin 

Paromomycin 

Polymyxin B 

Spectinomycin 

Streptozocin 

Thiostrepton 

Troleandomycin 

Tyrothricin 

Vancomycin 

*For nonmedicinal uses: 

Bacitracin 

Cycloheximide 

Hygromycin B 

Lincomycin 

Monensin, sodium 

Neomycin 

Novobiocin 

Nystatin 

Spectinomycin 

Streptomycin 

Tylosin 

♦Antihistamines : 
*Antinauseants : 

Cyclizine hydrochloride 

Dimenhydr in ate 

Meclizine hydrochloride 

Trimethobenzamide hydrochloride-- 
Bromodiphenhydramine hydrochloride- 
Brompheniramine maleate 

Carbinoxamine 

Chlorcyclizine hydrochloride 

Chlorothen citrate 

♦Chlorpheniramine maleate 

Chlorpheniramine t annate 

Cyproheptadine hydrochloride 

Dexbromphen i ramine ma leate 

Dexchlorpheni ramine meal eate 

Dimethindene maleate 

Diphenhydramine hydrochloride 

Doxy 1 amine succinate 

Methapyrilene fumarate 

Methapyrilene hybenzate 

Methapyrilene hydrochloride 

Methdilazine 

Methdilazine hydrochloride 

Phenindamine tartrate 

Pheniramine maleate 

Phenyl toloxamine citrate 

Pyrilamine 

Pyrilamine maleate 

Pyrilamine resin adsorbate 

Pyrilamine tannate 

Pyrrobutamine phosphate 

Thonzylamine hydrochloride 

Tripe lenn amine 

Tripe lennamine citrate 

Tripe lennamine hydrochloride 

Triprolidine hydrochloride 

Zolamine hydrochloride 

See footnotes at end of table. 



Manufacturers' identification codes 
(according to list in table 3) 



UPJ. 

MRK, UPJ. 

PFZ. 

MRK. 

PFZ. 

ABB, UPJ. 

PFN, UPJ. 

OMS. 

PFZ. 

PEN. 

LIL. 

COM, PEN. 

UPJ. 

LIL. 

UPJ. 

LIL 

PFZ. 

UPJ 

OMS. 

UPJ. 

MRK, PFZ. 

COM, LIL. 



BUR. 
SRL. 
PFZ. 
HOF. 



PD. 

SCH. 

SCH. 

BUR. 

ACY. 

HEX, SCH, SK. 

MAL. 

MRK. 

SCH. 

SCH. 

CGY. 

CAN, PD. 

BJL, BKC. 

ABB. 

LIL. 

ABB, MON. 

BJL. 

BJL. 

HOF. 

HEX, SCH. 

BRS. 

HEX. 

HEX, MRK. 

MRK. 

MAL. 

LIL. 

NEP. 

CGY. 

CGY. 

CGY. 

BUR. 

SCH. 



MEDICINAL CHEMICALS 



TABLE 2.— Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--CONTINUED 



*Anti-infective agents (except antibiotics) 
•Anthelmintics : 

Dichlorvos 

Diethyl carbamazine citrate 

Gentian violet 

Hexylresorcinol 

Phenothiazine 

*Piperazine 

Piperazine citrate ■* 

*Piperazine dihydrochloride 

Piperazine hexahydrate 

* Piperazine hydrochloride 

Piperazine phosphate 

Piperazine sulfate 

Pyrvinium pamoate 

Thiabendazole 

•Antifungal agents: 

Benzoic acid 

Calcium undecylenate 

Chlordantoin 

Sodium caprylate 

Undecylenic acid 

Zinc undecylenate 

•Antipropozoan agents : 

Aklomide 

Amodiaquin 

Amodiaquin hydrochloride 

Amprolium 

•Arsenic and bismuth compounds: 

Arsanilic acid 

Bismuth dipropylacetate 

Bismuth subsalicylate 

Carbarsone 

Glycobiarsol 

Nitarsone 

Roxarsone 

Roxarsone, sodium 

Chloroquine phosphate 

Clop idol 

Diiodohydroxyquin 

Dimetridazole 

3,5-Dinitro-o-toluamide 

Furazolidone 

Hyd roxych 1 oroquine sul fate 

lodochlorhydroxyquin 

Ipronidazole 

Metronidazole 

Nifuroxime 

Nifursol 

Nitrophenide 

Primaquine phosphate 

Pyrimethamine 

*Mercury compounds : 

Merbromin 

Nitromersol 

Phenylmercuric borate 

Thimerosal 

•Oxyquinoline sulfate 

•Sulfonamides : 

Acetyl sulfamethoxypyridazine 

Acetyl sulfisoxazole 

Azosu If amide 



Manufacturers' identification codes 
(according to list in table 3) 



SHC. 

ACY. 

SDH. 

MRK. 

WAG. 

DOW, JCC, UCC. 

BUR. 

DOW, FLM, JCC, WHL. 

JCC. 

DOW, FLM, JCC. 

BUR, JCC. 

JCC. 

X. 

MRK. 

MON. 
WTL. 
ARA. 
LEM. 

NTL. 
NTL, WTL. 

SAL. 
PD. 
PD. 
MRK. 

ABB, FLM, WHL. 

ARA. 

MAL, NOR, PEN. 

LIL, WHL. 

SDW. 

SAL. 

SAL. 

SAL. 

SDW. 

DOW. 

RSA, SRL. 

RDA. 

DOW. 

NOR. 

SDW 

CGY. 

HOF. 

RDA. 

NOR. 

LEM. 

ACY. 

PD, SDW. 

BUR. 

HYN. 
ABB. 
MRK. 
LIL. 
ASH, LEM, MRK, RSA. 

ACY. 
HOF. 
SDW. 



-102 



SYNTHETIC ORGANIC CHEMICALS, 197'! 



TABLE 2.- 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, IQZ^i'-CoNTI NUED 



*Anti-infective agents (except antibiotics) --Continued 
*Sulf on amides --Continued 

Dinsed 

Mafenide acetate 

Mafenide hydrochloride 

Phthalyl sulfacetamide 

Phthalylsulfathiazole 

Sulfabenzamide 

Sulfabenzaniide, sodium 

Sulfabromomethazine, sodium 

Sulfacetamide 

Sulfacetamide, sodium 

Sulfachloropyrazine, sodium 

Sulfachloropyridazine, sodium 

Sulfadiazine 

Sulfadiazine, sodium 

Sulfadimethoxine 

Sulfaguanidine 

Sulfamerazine 

Sulfamerazine, sodium 

Sulfamethazine 

Sulfamethazine , sodium 

Sulfamethizole 

Sulfamethoxazole 

Sulfanilamide 

Sulfanitran 

Sulfapyridine 

Sulfapyridine, sodium 

Sulfaquinoxaline 

Sulfaquinoxaline, sodium 

Sulfasalazine (salicylazosulfapyridine) 

Sulfathiazole 

Sulfathiazole, sodium 

Sulfisoxazole 

Sulfisoxazole, sodium 

*Urinary antiseptics: 

Mandelic acid 

Methenamine hippurate 

Me then amine mandelate 

Methenamine sulfosal icy late 

Methylene blue 

Nitrofurantoin 

Phenazopyridine hydrochloride 

*Other anti- infective agents: 

Aminacrine 

Aminacrine hydrochloride 

Antileprotic and antitubercular agents: 

Aminosalicylic acid 

Isoniazid 

Sodium aminosalicylate 

Sodium sulfoxone 

Antiviral agent: Amantadine 

Betanaphthol 

Bromoform 

Cetalkonium chloride 

Cetylpyridinium chloride 

Chlorobutanol 

Furamazone 

8-Hydroxy-5-quinolinesulfonic acid 

Iodoform^ 



Manufacturers' identification codes 
(according to list in table 3) 



SAL. 

SDW. 

SDW. 

LEM. 

MRK. 

ACY, LEM. 

ACY. 

MRK. 

LEM. 

LEM. 

ACY. 

ACY. 

ACY. 

ACY. 

HOP. 

ACY, SAL. 

ACY. 

ACY. 

ACY, LEM, MRK. 

ACY, LEM. 

ACY. 

HOP. 

MRK, SAL. 

SAL. 

ACY. 

ACY. 

LEM, MRK. 

LEM. 

SAL. 

MRK. 

MRK. 

HOF. 

HOP. 

MAL. 

RIK. 

ARN, MAL, NEP. 

CAN. 

ACY. 

NOR. 

HOF, NEP. 

SDW. 
SDW. 



RIL. 

X. 

ABB. 
ALD. 
ACY. 
DOW. 

FIN, SDW. 
FIN, HEX. 
BPC, PD. 
NOR. 
MRK. 
^'J\L, PEN. 



MEDICINAL CHEMICALS 



TABLE 2. 



-Medicinal chemicals for which U.S, production or sales were reported, 
identified by manufacturer, 1974--cont! nued 



Manufacturers' identification codes 
(according to list in table 3) 



*Anti- infective agents (except antibiotics) --Continued 
*Other anti-infective agents — Continued 

Nalidixic acid 

Nitrofura thiazide 

Nitrofurazone 

Ormetoprim 

Oxolinic acid 

Oxyquinoline 

Oxyquinoline benzoate 

Oxyquinoline citrate 

Povidone - iodine complex 

Resorcinol' 

Thymol 

Thymol iodide 

Trimethoprim 

'Autonomic drugs: 

♦Parasympatholytic (anticholinergic) tertiary amines 
(except tropane derivatives) : 

Adiphenine hydrochloride 

Cycrimine hydrochloride 

Dicyclomine hydrochloride 

Orphenadrine citrate 

Oxyphencyc limine hydrochloride 

Piperidolate hydrochloride 

Thiphenamil hydrochloride 

Trihexphenidyl hydrochloride 

♦Sympathomimetic (adrenergic) agents: 

Cinnamedrine hydrochloride 

Clorprenaline hydrochloride 

Cyclopent amine hydrochloride 

Ephedrine 

Epinephrine (levo) 

Epinephrine bitartrate (dextro) 

Epinephrine bitartrate (levo) 

Epinephrine hydrochloride (levo) 

Epinephrine hydrochloride (racemic) 

Isoproterenol hydrochloride 

Isoproterenol sulfate 

Levarterenol bitartrate 

Mephentermine 

Mephentermine sulfate 

Methoxyphenamine hydrochloride 

Naphazoline hydrochloride 

Nordefrin hydrochloride 

Nylidrin hydrochloride 

'Phenylephrine base, bitartrate, and tannate : 

Phenylephrine 

Phenylephrine bitartrate 

Phenylephrine tannate 

Phenylephrine hydrochloride 

'Phenylpropanolamine hydrochloride 

Propylhexedrine 

Protokylol hydrochloride 

Pseudoephedrine 

Pseudoephedrine hydrochloride 

Pseudoephedrine sulfate 

Tetrahydrozoline hydrochloride 

'Other autonomic drugs: 

Ganglionic blocking agents: 

Hexamethonium bromide 

Tetraethylammonium chloride 



SDH. 

SCH. 

NOR. 

HOP. 

NEP. 

ASH. MRK. 

ASH. LEM. 

ASH, MRK. 

GAF. 

KPT. 

GIV. 

MAL. 

BUR. 



CGY. 
LIL. 
BKC. 
RIK. 
PFZ. 
LKL. 
BJL. 
ACY. SDW. 

SDW. 

LIL. 

LIL. 

UP J. 

BLP. 

SDW. 

BLP, SDW. 

BLP. 

BLP, ECL. 

LIL. SDW. 

ABB. 

SDW. 

ARA. 

ARA. 

X. 

CGY. 
SDW 
BKL. 

GAN, 
GAN, 

X. 

GAN. 
ARS, 
SK. 
LKL. 

GAN. 
BUR, 
GAN. 
PFZ. 



SDW. 
SDW. 



HEX. SDW. 

GAN, NEP. CRT. PD. 



RSA. 
RSA. 



SYNTHETIC ORGANIC CHLMICALS, W^ 



TABLE 2.- 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'<--CONTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



'Autonomic drugs--Continued 

*Other autonomic drugs--Continued 

Parasympatholytic (anticholinergic] quaternary 
ammonium compounds (except tropane 
derivatives) : 

Diphemanil methyl sulfate 

Hexocyclium methyl sulfate 

Isopropamide iodide 

Mepenzolate bromide 

Pipenzolate bromide 

Tridihexethyl iodide 

Parasympatholytic (anticholinergic) tropane 
derivatives : 

Anisotropine methylbromide 

Benztropine mesylate 

Homatropine 

Homatropine hydrobromide 

Homatropine methylbromide 

Parasympathomimetic (cholinergic) agents: 

Carbachol 

Neostigmine bromide 

Neostigmine methyl sulfate 

Pyridostigmine Bromide 

♦Cardiovascular agents: 
Antihypertensive agents: 

Alkavervir 

Guanethidine sulfate 

Hydralazine hydrochloride 

Methyldopa 

Pargyline hydrochloride 

Reserpine 

Antilipemic agents: 

Colestipol hydrochloride 

Dextrothyroxine, sodium 

Sitosterols 

Bioflavonoids : 

Hesperidin 

Lemon bioflavonoid complex 

Naringin 

Vasodilators : 

Amyl nitrite 

Dioxyline phosphate 

Ethyl nitrite 

Trolnitrate phosphate 

Other cardiovascular agents : 

Procainamide hydrochloride 

Quinidine polygalacturonate 

♦Central depressants and stimulants: 
♦Amphetamines : 

Amphetamine (racemic) 

Amphetamine sulfate (racemic) 

Dextroamphetamine 

Dextroamphetamine sulfate 

Me thamphet amine (levo) 

Methamphetamine hydrochloride (dextro) 

♦Analgesics and antipyretics: 
♦Acetanilide derivatives: 

Acetaminophen . 

Phenacetin 

♦Aspirin 

♦Meperidine hydrochloride 

♦Methadone hydrochloride 



SCH. 






SK. 






LKL. 






LKL. 






ACY. 






ARA. 
ARA. 






ARA. 
ARA. 






ARA. 






RSA. 






HOP. 






HOP. 






HOP. 






RIK. 






CGY. 






CGY. 






MRK. 






ABB. 






PEN. 






X. 






BAX. 






LIL, 


UPJ. 




SKG. 






SKG. 






SKG. 






MAL. 






LIL. 






MAL. 






PFZ. 






OMS, 


PD. 




LEM. 






ARN. 






ARN. 






ARN. 






ARN, 


SK. 




GAN. 






ARN. 






ATP, 


MAL, 


NOR, PEN. 


MON. 






DOW, 


MON, 


NOR, SDG, X 


PEN, 


SDW, 


WYT. 


LIL, 


MAL, 


PEN. 



MEDIC IiWL CHEniCALS 



TABLE 2, --Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 197'!~CoNTINUED 



♦Central depressants and stimulants--Continued 
♦Analgesics and antipyretics--Continued 
•Other analgesics and antipyretics: 
p-Arainobenzoic acid and salts: 

Aminobenzoic acid 

Potassium auiinobenzoate 

Sodium aminobenzoate 

Anileridine hydrochloride 

Aurothioglucose 

Calcium succinate 

Dextropropoxyphene napsylate 

Ethoheptazine citrate 

Indomethacin 

Mefenamic acid 

Naproxen [racemic) 

Oxycodone hydrochloride 

Oxyphenbutazone 

Pentazocine 

Pentazocine hydrochloride 

Phenylbutazone 

Propoxyphene hydrochloride 

Salicylates : 

Aluminum aspirin 

Phenyl salicylate 

Potassium salicylate 

Sal icyl amide 

Salicylate meglumine 

Salicylic acid, 2-acetamidophenyl ester 

Salsalate (salicylsalicylic acid) 

Sodium salicylate 

♦Antidepressants : 

Ami tripty line 

Desipraraine hydrochloride 

Doxepin hydrochloride 

Imipramine hydrochloride 

Nialamide 

Nortriptyline 

Phenelzine sulfate 

Protriptyline 

♦Barbiturates : 

Allylbarbituric acid 

Allylbarbituric acid, sodium 

Amobarbital 

Amobarbital , sodium 

Barbital 

Barbital , sodium 

Butabarbital 

Butabarbital, sodium 

5-sec-Butyl-5-ethyl-2-thiobarbituric acid, sodium 

derivative 

Hexobarbital 

Hexobarbital , sodium 

Mephobarbital 

Metharbital 

Methohexital, sodium 

Pentobarbital-.--. ^ 

Pentobarbital, sodium ' 

Phenobarbital 

Phenobarbital, sodium r 



Manufacturers' identification codes 
(according to list in table 3) 



GAN, 

CAN. 

GAN. 

NIRK. 

SCH. 

LEM. 

LIL. 

WYT. 

MRK. 

PD. 

ARA. 

EN. 

CGY. 

SDK. 

SDW. 

CGY. 

LEM, 



PEN 




LEM 




SDW 




PD. 




HN. 




MRK. 




lkl. 




PFZ, 


SK. 


CGY. 




PFZ. 




LIL. 




NEP. 




MRK. 




GAN. 




GAN. 




GAN, 


HL 


GAN, 


LIL 


GAN. 




GAN. 




ABB, 


GAN 


ABB, 


GAN 


ABB. 




GAN. 




SDW. 




GAN, 


SDW 


ABB. 




LIL. 




ABB. 


GAN 


ABB, 


GAN 


GAN. 


MAL 


GAN, 


MAL. 



SYNTHETIC ORGANIC CHEMICALS, 197^) 



TABLE 2.— Medicinal chemicals for which U.S. production' or sales were reported, 

IDENTIFIED BY MANUFACTURER. 197'|--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



*Central depressants and stimulants- -Continued 
•Barbiturates- -Continued 

Secobarbital 

Secobarbital , sodium 

Thiamylal , sodium 

Thiopental, sodium 

♦Hypnotics and sedatives (except barbiturates^ : 

Carbromal 

Ethchlorvynol 

Ethinamate 

Glutethimide 

Methyprylon 

•Skeletal muscle relaxants and tranquilizers: 
Skeletal muscle relaxants: 

Carisoprodol 

Chlorphenesin carbamate 

Phenaglycodol 

Succinyl choline chloride 

Tubocurarine 

•Tranquilizers: 

Buclizine hydrochloride 

Chlorazepate dipotassium 

Chlordiazepoxide hydrochloride 

Chlormezanone 

Diazepam 

Ethoxybutamoxane 

Flurazepam hydrochloride 

Hydroxyzine hydrochloride 

Hydroxyzine pamoate 

Meprobamate 

Oxazepam 

Phenothiazine derivatives: 

Acetophenazine maleate 

Chlorpromazine hydrochloride 

Fltiphenazine hydrochloride 

Perphenazine 

Prochlorperazine edisylate 

Prochlorperazine maleate 

Promazine hydrochloride 

Promethazine hydrochloride 

Prazepam 

Thiothixene hydrochloride 

•Other central depressants and stimulants: 
Anticonvulsants : 

Diphenylhydantoin 

Diphenylhydantoin, sodium 

Ethosuxiraide 

Ethotoin 

Methsuximide 

Phenacemide 

Phensuximide 

Antitussives: 

Benzonatate 

Caramiphehen edisylate 

Carbetapentane citrate 

Chlophedianol hydrochloride 

Codeine 

Dextromethorphan hydrobromide 

Ethy Imorphine hydrochl ori de 

Hydrocodone bitartrate 

Noscapine 

Thebaine 

General anesthetic: Ketamine hydrochloride- 



GAN. 
GAN, LIL. 



LIL. 

BKL, CGY, GAN. 

HOF. 



BKL. 
UPJ. 
LIL. 

ABB, BUR. 
ABB. 

PFZ. 

ABB. 

HOF. 

SDW. 

HOF. 

LIL. 

HOF. 

PFZ. 

PFZ. 

ABB, BKL. 

WYT. 

SCH. 

SK. 

SCH. 

SCH. 

SK. 

SK. 

mj. 

IVYT. 
NEP. 
PFZ. 



PD. 

CGY. 

SK. 

PFZ. 

RIK. 

MRK. 

HOF. 

NWL. MRK. 

MAL, PEN. 

MRK. 

MRK. 

PD. 



MEDICINAL CHEHICALS 



TABLE 2.- 



-Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974— CONTINUED 



Manufacturers' identification codes 
[according to list in table 3) 



'Central depressants and stimulants — Continued 

*Other central depressants and stimulants — Continued 
Stimulants : 

Benzphetamine hydrochloride 

Caffeine: 

Natural 

Synthetic 

Caffeine, citrated 

Chlorphent ermine hydrochloride 

Deanol acetamidobenzoate 

Diethylpropion hydrochloride 

Nikethamide 

Pemoline 

Phendimetrazine tartrate 

Phentermine 

*Dermatological agents (except salicylic acid) 
and local anesthetics: 
Dermatological agents: 

Allantoin 

Aluminum phenolsulfonate 

Ammonium phenolsulfonate 

Bismuth subgallate 

Glycol salicylate 

Podophyllum resin 

Zinc phenolsulfonate 

Local anesthetics: 

Butamben pi crate 

Butyl aminobenzoate (Butamben) 

p-Butylarainobenzoic acid, ethyl ester 

Dibucaine 

Dibucaine hydrochloride 

Ethyl aminobenzoate (Benzocaine) 

Isobutyl aminobenzoate 

Lidocaine 

Lidocaine hydrochloride 

Mepivacaine hydrochloride 

Oxethazaine 

Phenacaine hydrochloride 

Pramoxine hydrochloride 

Procaine hydrochloride 

Proparacaine hydrochloride 

Tetracaine 

'Diagnostic agents: 

*Roentgenographic contrast media: 

Acetrizoate, sodium 

Diatrizoate, meglumine 

Diatrizoate, sodium 

lodipamide , meglumine 

lodohippurate, sodium 

lopanoic acid 

lophendylate 

lothalamate, meglumine 

lothalamate, sodium 

Methiodal , sodium 

Trypanoate, sodium 

*Other diagnostic agents: 

Betazole hydrochloride (gastric secretion test) 

Fluorescein, sodium (corneal trauma indicator) 

Indocyanine green (cardiac output test) 

Ketodase 

Metyrapone (pituitary function test) 

Phenolphthalein monophosphate, dicyclohexylamine salt-- 

Phenolsulfonphthalein (kidney function test) 

Sulfobromophthalein, sodium (liver function test) 



UPJ. 

CPR. GNF. 

PFZ. 

MAL. 

NEP. 

RIK. 

BKC. 

CGY. 

ABB. 

BAX. 

HEX. 



HFT. 

SAL. 

SAL. 

MAL, PEN. 

RDA. 

PEN. 

MAL, SAL. 

ABB. 

ABB. 

GAN. 

CGY. 

CGY. 

PD. 

RSA. 

AST, RLS, SDW. 

SDW. 

ARA. 

WYT. 

SDW. 

ABB. 

PFZ. UOP. 

CMS. 

SDW. 



MAL. 

OMS. SDW. 
OMS, SDW. 
OMS. 
MAL. 
SDW. 

X. 

MAL. 
MAL. 
SDW. 
SDW. 

LIL. 

SDH. 

HYN, x. 

NEP. 

CGY. 

NEP. 

HYN, 

HYN. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2,— Medicinal chemicals for which U,S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974~CONTINUED 



♦Expectorants and mucolytic agents: 

*Ethylenediairiine dihydr iodide 

Glyceryl guaiacolate 

lodinated glycerol 

Lobeline sulfate 

Potassium guaiacol sulfonate 

Terpin hydrate 

Thonzonium bromide 

♦Gastrointestinal agents (except methionine, hydroxy 
analog) : 
♦Choleretics and hydrocholeretics : 

Bile acids, oxidized 

Dehydrocholic acid 

Florantyrone 

Iron bile salts 

Ox bile extract 

Sodium dehydrocholate 

Tocamphyl 

♦Choline chloride: 

Feed grade 

Medicinal grade 

Technical grade 

♦Other gastrointestinal agents: 

Betaine base 

Betaine hydrochloride 

Calcium polycarbophil 

Choline bicarbonate 

Choline bi tartrate 

Choline citrate (Tricholine citrate) 

Choline dihydrogen citrate 

Dihydroxyaluminum aminoacetate 

Magnesium citrate 

Pectin 

Phenolphthalein 

Podophyllin 

Sodium tartrate 

♦Hematological agents: 
Anticoagulants : 

Ammonium heparin 

Anisindione 

Bishydroxycoumarin 

Calcium heparin 

Diphenadione 

Lithium heparin 

♦Sodium heparin 

Warfarin 

Other hematological agents: 

Aminocaproic acid 

Cellulose, oxidized 

Dextran 

Protamine 

♦Hormones and synthetic substitutes: 
♦Corticosteroids : 

Betamethasone alcohol and acetate 

Betamethasone benzoate 

Betamethasone phosphate--- 

Betamethasone valerate 

Cortisone acetate-- '-- 

Dexamethasone 

Dexamethasone sodium phosphate • — 

Fludrocortisone acetate 



Manufacturers' identification codes 
(according to list in table 3) 



MAL, WAG, WHL. 
PEN. 



HN. 

PEN. 

NEP. 



SRL, 


WIL. 




WIL. 






SRL. 






LIL, 


WIL. 




ABB, 


WIL. 




WIL. 






ARA. 






COM, 


DA, 


DOW, HFT, TMH 


HFT. 






HFT. 






HFT. 






HFT. 






SCH. 






COM. 






ACY, 


HFT. 




ACY, 


HFT. 




ACY, 


HFT. 




CHT. 






MAL. 






SKG. 






SCH. 






ABB. 






MAL. 






ABB, 


RIK, 


WIL. 


SCH. 






ABB. 






RIK. 






UPJ. 






RIK. 






ABB, 


RIK 


WIL. 


SDW. 






ACY. 






EKT. 






PHR. 






LIL. 







SCH. 

X. 

SCH. 
SCH. 

MRK, UPJ. 
.MRK, SCH. 
MRK. 
UPJ. 



MEDICINAL CHEMICALS 



TABLE 2. --Medicinal chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197')--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



'Hormones and synthetic substitutes — Continued 
'Corticosteroids- -Continued 

Fluorometholone 

9a-Fluoroprednisolone acetate 

9-Fluoro-llB,16a, 17, 21- tetrahydroxypregna- 1,4- 

diene-3,20-dione 16, 2 1-di acetate 

Fluprednisolone 

Halcinonide 

Hydrocortisone 

Hydrocortisone acetate 

Medrysone 

Methylprednisolone 

Prednisolone 

Prednisolone acetate 

Prednisone 

Triamcinolone 

Triamcinolone acetonide 

Triamcinolone di acetate 

'Estrogens and progestogens : 
Estrogens : 

Chlorotrianisene 

Diethylstilbestrol 

Diethylsti Ibestrol diphosphate 

Estradiol cypionate 

Estogenic substances, conjugated 

Natural estrogenic substance 

Piperazine estrone sulfate 

Potassium estrone sulfate 

Progestogens : 

Medroxyprogesterone acetate 

Melengestrol acetate 

Norgestrel 

Progesterone 

'Synthetic hypoglycemic agents: 

Acetohexamide 

Chlorpropamide 

Glyburide 

Phen f rmin hy droch loride 

Tolazamide 

Tolbutamide 

'Thyroid hormone and antithyroid agents: 

Levothyroxine, sodium 

Methimazole 

Propy Ithiouracil 

2-Thiouracil 

Thyroglobulin 

Thyroid hormone 

'Other hormones and synthetic substitutes: 
Anabolic agents and androgens: 

Fluoxymesterone 

Testosterone cypionate 

Zeranol 

Corticotropin (ACTH) 

Insulin 

'Renal-acting and edema-reducing agents: 
'Benzothiadiazine derivatives: 

Bendroflumethiazide 

Benzthiazide 

Chlorothiazide 

Flumethiazide 



UPJ. 
UPJ. 

TRD. 

UPJ. 

TRD. 

MRK, PFZ, UPJ. 

MRK, UPJ. 

UPJ. 

UPJ. 

MRK, SCH, UPJ. 

UPJ. 

MRK, SCH, UPJ. 

TRD, X. 

QMS. 

QMS. 



BJL, BKC. 

ARA, DLI. LIL. 

ARA. 

UPJ. 

ORG. 

ORG. 

ABB. 

PEN. 

UPJ. 
UPJ. 
WYT. 
UPJ. 

LIL. 
PFZ. 

X. 

bkl. 

UPJ. 
UPJ. 

bax. 

LIL. 
ARA. 
ACY. 
NEP. 
LIL. 



UPJ. 
UPJ. 
COM. 

ARP, ORG. 
ARP, LIL. 



OMS. 
PFZ. 

LEM, MRK. 
OMS. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



lABLE 2,--Nedicinal chemicals for which U.S.. production or sales were reported, 

IDENTIFIED BY MANUFACTURER^ ISZ^t— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



•Renal-acting and edema- reducing agents — Continued 

*Benzothiadiazine derivatives --Continued 

Hydrochlorothiazide 

Hydroflumethiazide 

Methyclothiazide 

Polythiazide 

Trichlormethiazide 

•Mercurial diuretics: 

Moral luride 

Mersalyl acid 

Sodium mercaptomerin 

•Theophylline derivatives: 

Aminophylline 

8-Bromotheophyl line , 2-amino-2-methyl- 1- 

propanol salt 

Oxtriphylline 

Theophylline sodium glycinate 

•Other renal-acting and edema- reducing agents: 

Ace tazol amide 

Chlorthalidone 

Dichlorphenamide 

Ethacrynic acid 

Ethoxzol amide 

Probenecid 

Triamterene 

•Therapeutic nutrients: 
Amino acids: 

Amino acid mixtures 

Arginine aspartic acid 

Glutamic acid and salts: 

Glutamic acid 

Glutamic acid hydrochloride 

Potassium glutamate 

L-Tyrosine 

Other therapeutic nutrients: 

Calcium glucoheptonate 

Calcium gluconate 

Copper gluconate 

Ferrous gluconate 

Magnesium gluconate 

Manganese gluconate 

Potassium gluconate 

Zinc glucoheptonate 

•Vitamins : 

•Ascorbic acid 

•Niacin and niacinamide (all grades): 

Niacin (nicotinic acid) (feed grade) 

Niacin (nicotinic acid) (medicinal grade) 

Niacinamide 

•Pantothenic acid and derivatives: 

Calcium pantothenate (dextro) 

Calcium pantothenate (racemic) (feed grade) 

Calcium pantothenate (racemic) (medicinal grade) -- 
•Calcium pantothenate (racemic) - calcium chloride 

complex 

Dexpanthenol '■ 

Panthenol (racemic) 

Pantothenic acid 

Sodium pantothenate 



ABB, 


CGY, 


MRK. 


X. 






ABB. 






PFZ. 






SCH. 






LKL. 






SDW. 






WYT. 






CAN, 


SRL. 




GAN. 






NEP. 






CHT. 






ACY. 






CGY. 






MRK. 






MRK. 






ARA. 






MRK. 






ACY, 


SK. 




MDJ. 






LEM. 






LEM. 






LEM. 






LEM. 






MDJ. 






PFN. 






PFZ. 






PFZ. 






PFZ, 


SDW 




PFZ. 






PFZ. 






PFZ. 






PFN. 






HOP, 


MRK 


PFZ. 


MRK, 


NEP 


RIL. 


MRK, 


RIL 




MRK, 


NEP 


PD, RIL 


HFT. 






CKL, 


DA, 


HFT. TMH 


HFT. 






CKL, 


DA, 


DLI, HFT 


HOF. 






HOF. 






PD. 







MEDICINAL CHEMICALS 
TABLE 2,— Medicinal chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'<--CONTINUED 



Manufacturers' identification codes 
(according to list in table 5) 



♦Vitamins --Continued 
*Vitamin D: 

Cholecalciferol (Vitamin DO 

7-Dehydrocholesterol (Provitamin Dj) 

Ergocalciferol (Vitamin D2) 

'Vitamin E: 

d- Alpha tocopherol 

dl- Alpha tocopherol 

d-Alpha tocopheryl acetate 

dl-Alpha tocopheryl acetate 

dl-Alpha tocopheryl acetate (feed grade)- 

d-Alpha tocopheryl acid succinate 

*Vitamin K: 

Menadiol sodium diphosphate 

Menadione 

Menadione sodium bisulfite 

Phytonadione 

•Other Vitamins : 

Ascorbic acid salts: 

Calcium ascorbate 

Sodium ascorbate 

Biotin 

Cyanocobalamin (feed grade) 

Cyanocobalamin (medicinal grade) 

Cyanocobalamin (U.S. P. crystalline) 

Inositol 

Magnesium nicotinate 

Niacinamide hydrochloride 

Pyridoxine 

Riboflavin (feed grade) 

Riboflavin (medicinal grade) 

Riboflavin- 5- phosphate, sodium 

Thiamine hydrochloride 

Thiamine mononitrate 

Vitamin A: 

Beta-carotene (Provitamin A) 

Vitamin A acetate: 

Feed grade 

Medicinal grade 

Vitamin A acid 

Vitamin A alcohol 

Vitamin A palmitate: 

Feed grade 

Medicinal grade 

•Miscellaneous medicinal chemicals: 
Antineoplastic agents: 

Azathioprine 

Calusterone 

Mercaptopurine 

Thioguanine 

Vinblastine sulfate 

Vincristine sulfate 

Methionine, hydroxy analog, calcium salt--- 

Salicylic acid' 

Smooth muscle relaxants: 

Alverine citrate 

Alverine hydrochloride 

Papaverine hydroch lor i de 



DA, 


DLI, 


TMH, 


VTM. 


JUL. 








SCR, 


VTM. 






EKT, 


GNM. 






GNM, 


HOF. 






EKT, 


GNM. 






DA, 


EKT, 


GNM, 


HOF. 


HOF. 








EKT, 


GNM 






HOF. 








ABB, 


HET 


WHL 




ABB 


HET 


HFT 


WHL 


MRK 








PFZ 








HOF 


MRK 


PFZ 




HOF 








MRK 








MRK 








MRK 








STA 








MRK 








NEP 








HOF 








GPR 


HOF 


MRK 




HOF 


MRK 






HOF 








HOF 


MRK 






HOF 


MRK 







EKT, HOF. 
HOF. 



HOF. 




EKT, 


HOF 


BUR. 




UPJ. 




BUR. 




BUR. 




lil. 




lil. 




DUP, 


MON 


DOW, 


HN. 


ARA. 




ARA. 




LIL, 


PEN 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2.- 



-Medicinal chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER^ 1974--C0NTINUED 



Chemical 


Manufacturers' identification codes 
(according to list in table 3] 


'Miscellaneous medicinal chemicals — Continued 
Unclassified medicinal chemicals: 


BUR. 
PEN. 

X. 

LEM. 
PEN. 
HOP. 
MRK. 


Berberine hydrochloride 




Hydrastine hydrochloride 







All antibiotics listed are for medicinal use unless otherwise specified. 
Producers of technical grade are listed in "Miscellaneous chemicals." 
Producers of technical grade are listed in "Cyclic intermediates." 



MEDICINAL CHEMICALS us 

TABLE 3.— Medicinal chemicals; Directory of manufacturers. 1974 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of medicinal chemicals to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ABB 


Abbott Laboratories 


LEM 


Napp Chemicals, Inc. 




ACY 


American Cyanamid Co. 


LIL 


Eli Lilly 5 Co. and Puerto Rico 




ALD 


Aldrich Chemical Co. 


LKL 


Lakeside Laboratories Div. of 




ARA 


Arapahoe Chemicals, Inc. 




Richardson-Merrill, Inc. 




ARN 


Arenol Chemical Corp. 








ARP 


Armour Pharmaceutical Co. 


MAL 


Mallinckrodt Chemical Works 




ARS 


ArsvTico, Inc. 


MDJ 


Mead Johnson 5 Co. 




ASH 


Ashland Oil, Inc., Ashland Chemical 




Div. 






Co. Div. 


MON 


Monsanto Co. 




AST 


Astra Pharmaceutical Products, Inc. 


MRK 


Merck 5 Co. , Inc. 




ATP 


Northern Fine Chemicals, Inc. 


NEP 


Nepera Chemical Co., Inc. 




BAX 


Baxter Laboratories, Inc. 


NES 


Nease Chemical Co., Inc. 




BEE 


Beecham, Inc. 


NOR 


Norwich Pharmacal Co. 




BJL 


Burdick S Jackson Laboratories, Inc. 


NTL 


NL Industries, Inc. 




BKC 


J.T. Baker Chemical Co. 








BKL 


Millmaster Onyx Corp., Millmaster Chemical 


OMS 


E.R. Squibb 5 Sons, Inc. 






Div., Berkeley Chemical Dept. 


ORG 


Organics, Inc. 




BLP 


Belport Co. , Inc. 


ORT 


Roehr Chemicals, Inc. 




Bnc 


Biocraft Laboratories, Inc. 








BPC 


Stauffer Chemical Co., Specialty Chemical 


PD 


Parke, Daivs 5 Co. 






Div., Benzol Products 


PEN 


CPC International, Inc., S.B. Penick Co. 




BRS 


Bristol-Myers Co., Bristol Laboratories Div. 


PFN 


Pfanstiehl Laboratories, Inc. 




BUR 


Burroughs-Wellcorae Co. 


PFZ 


Pfizer, Inc. and Pfizer Pharmaceuticals, 




CGY 


Ciba-Geigy Corp. and Ciba Pharmaceutical Co. 


PHR 


Inc . 
Pharmachem Corp. 




CHT 


Chattem Drug 6 Chemical Co., Chattem Chem- 










icals Div. 


RDA 


Rhodia, Inc. 




CKL 


Chemlek Laboratories, Inc. 


RIK 


Riker Laboratories, Inc., Sub. of 3M Co. 




COM 


Commercial Solvents Corp. 


RIL 


Reilly Tar 5 Chemical Corp. 




CPR 


Certified Processing Corp. 


RLS 
RSA 


Rachel le Laboratories, Inc. 
R.S.A. Corp. 




DA 


Diamond Shamrock Corp. 








DLI 


Dawe's Laboratories, Inc. 


SAL 


Salsbury Laboratories 




DOW 


Dow Chemical Co. 


SCH 


Sobering Corp. 




DUP 


E.I. duPont de Nemours 5 Co., Inc. 


SCR 


R.P. Scherer Corp. 
Sterling Drug Corp.: 




ECL 


Eastside Chemical Laboratory 


SDG 


Glenbrook Laboratories Div. 




EK 


Eastman Kodak Co.; 


SDH 


Hilton-Davis Chemical Co. Div. 




EKT 


Tennessee Eastman Co. Div. 


SDW 


Winthrop Laboratories Div. 




EN 


Endo Laboratories, Inc. 


SHC 
SK 


Shell Oil Co., Shell Chemical Co. Div. 
Smith, Kline f, French Laboratories 




FIN 


Fine Organics, Inc. 


SKG 


Sunkist Growers, Inc. 




FLM 


Fleming Laboratories, Inc. 


SRL 
STA 


G.D. Searle 6 Co. 

A.E. Staley Manufacturing Co. 




GAP 


GAP Corp., Chemical Div. 








CAN 


Gane's Chemical Works, Inc. 


TMH 


Thompson-Hayward Chemical Co. 




GIV 


Givaudan Corp. 


TRD 


Manufacturing Enterprises, Inc., Squibb 




GNF 


General Foods Corp., Maxwell House Div. 




Manufacturing Inc., Trade Enterprises, 


Inc 


GNM 


General "ius Chemicals, Inc. 








GPR 


Grain Processing Corp. 


ucc 


Union Carbide Corp. 








UOP 


Universal Oil Products Co., UOP Chemical 


Div 


HET 


Heterochemical Corp. 


UPJ 


Upjohn Co. 




HEX 


Hexagon Laboratories, Inc. 








HFT 


Syntex Agribusiness, Inc., Nutrition 6 
Chemical Div. 


VTM 


Vitamins, Inc. 




HN 


Tenneco Chemicals, Inc. 


WAG 


West Agro-Chemicals, Inc. 




HOP 


Hoffmann- LaRoche, Inc. 


WHL 


Whitmoyer Laboratories, Inc. 




HYN 


Hynson, Westcott 6 Dunning, Inc. 


WIL 
WTL 


Inolex Corp., Inolix Pharmaceutical Div. 
Pennwalt Corp., Lucidol Div. 




JCC 


Jefferson Chemical Co., Inc. 


WYT 


Wyeth Laboratories, Inc., Wyeth Laboratories 


JUL 


Julian Associates, Inc. 




Div. of American Home Products Corp. 




KPT 


Koppers Co., Inc., Organic Material Div. 









Note. --Complete names and addresses of the above reporting companies, are listed in table 1 of the appendix. 



114 SYNTHETIC ORGANIC CHEMICALS^ 1974 



FLAVOR AND PERFUME MATERIALS 



Flavor and perfume materials are organic chemicals used to impart 
flavors and odors to foods, beverages, cosmetics and soaps. These 
aromatic chemicals are also utilized to neutralize or mask unpleasant 
odors in industrial processes and products as well as in consumer 
products . 

Total domestic production of flavor and perfume materials in 1974 
amounted to 135.3 million pounds (table 1].^ Sales of these materials 
in 1974 amounted to 107.4 million pounds, valued at $166.7 million com- 
pared with 108.3 million pounds, valued at $108.5 million in 1973. These 
totals do not include benzyl alcohol, which was, before 1973, included in 
flavor and perfume materials but is shown in the miscellaneous cyclic 
section of this series. U.S. production of flavor and perfume materials 
in 1974 increased 15.7 percent over 1973 but the quantity of sales de- 
clined slightly, by 0.8 percent. 

Production of cyclic flavor and perfume materials in 1974 amounted 
to 55.7 million pounds; sales amounted to 42.7 million pounds, valued at 
$100.9 million. The individual chemical in the cyclic group produced in 
the greatest volume in 1974 was methyl salicylate (7 million pounds). 

U.S. output of acyclic flavor and perfume materials in 1974 amounted 
to 79.6 million pounds; sales of these materials amounted to 64.7 million 
pounds, valued at $65.8 million. Monosodium glutamate was by far the 
most important of the acyclic chemicals, and the individual flavor and 
perfume chemical produced in the greatest volume (47.2 million pounds). 

The report for 1974 has eliminated the separate section for 
"Essential oils, chemically modified", included prior to 1973. Chemicals 
previously listed under this heading have been distributed throughout 
the cyclic and acyclic groups. 



' See also table 2 which lists these materials and identifies the manu- 
facturers by codes. These codes are given in table 3. 



FLAVOR A;1D PERFUf'lE MATERIALS iis 

TABLE 1. --Flavor and perfume materials: U.S. production and sales> 1974 

(Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or 
sales may be published. (Leaders (...) are used where the reported data are accepted in confidence and may not 
published or where no data were reported.) Table 2 lists separately all flavor and perfume materials for which 
. data on production and/or sales were reported and identifies manufacturers of each] 



Unit 
value' 



Grand total 

FLAVOR AND PERFUME MATERIALS, CYCLIC 

Total 

Bemenoid and Naphthalenoid 

Total 

4-Allyl-2-methoxyphenol (Eugenol) 

p-Anisaldehyde 

Anisyl acetate 

Benzophenone^ 

Benzyl acetate 

Benzyl benzoate 

Benzyl butyrate 

Benzyl cinnamate 

Benzyl propionate 

Benzyl salicylate 

Cinnamyl acetate 

Cinnamyl alcohol 

Cinnamyl anthranilate 

Cinnamyl propionate 

Ethyl phenyl glycidate 

liydrocoumarin 

Isobutyl pheny lace tat e 

Isobutyl Salicylate 

Isopentyl salicylate 

a-Methylcinnamaldehyde 

Methyl phenyl acetate 

Methyl salicylate 

a-Pentylcinnamaldehyde 

Phenethyl acetate 

Phenethyl isobutyrate 

Phenethyl isovalerate 

2-Phenethyl phenyl acetate 

3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

p-Propenylanisole (Anethole) 

All other benzenoid and naphthalenoid materials- 



See footnotes at end of table. 



1,000 
pounds 



135.321 



44,793 



422 
1,103 

959 

2,092 

1,426 

13 

9 

41 



7,012 
901 
129 



2,235 
26,258 



1,000 
pounds 



1.000 
dollars 



166.726 



100.922 



330 

1,065 

8 

466 
2,002 
1,195 



6,256 
769 



2,383 
18,293 



78,133 



2,130 

3,326 

49 

892 
1.264 

758 

42 



4,341 

1,275 

224 



12,189 
48,462 



Per 
pound 



$1.55 



2.23 



6.46 
3.12 
6.26 
1.92 
.63 
.63 

4.45 
1.38 
1.39 
4.11 
2.35 
18.45 
8.87 

6.31 
1.77 
1.10 

.85 
2.29 
2.47 

.69 
1.66 
2.54 

3.32 
3.97 



SYNTHETIC ORGANIC CHEfllCALS, 1974 
TABLE 1. --Flavor and perfume materials: U.S. production and sales^ 1974--Continued 



Quantity 



FLAVOR AND PERFUME MATERIALS, CYCLIC—Continued 

Terpenoid, Heterocyclic, and Alioyalio 

Total 

Cedryl acetate 

a-Ionone 

lonone (a-and 6-) 

Lavandin, acetyl at ed 

Menthol, synthetic, U.S. P. and tech 

Methyl ionones 

Terpineols 

a-Terpinyl acetate 

Vetivenyl acetate 

All other terpenoid, heterocyclic, and alicyclic 
materials 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

Total 

Allyl hexanoate 

Butyl butyryl lactate 

Citronellyl acetate 

Citronellyl formate 

Citronellyl isobutyrate 

3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol) 

3,7-Dimethyl-trans-2,6-octadien-l-ol (Geraniol) 

3,7-Dimethyl-l,6-octadien-3-ol (Linalool; Linalyl 

alcohol) 

3,7-Dimethyl-6-octen-l-al (Citronellal) 

3,7-Dimethyl-6-octen-l-ol (Citronellol) 

Ethyl butyrate 

Ethyl heptanoate 

Ethyl hexanoate (Ethyl caproate) 

Ethyl nonanoate 

Ethyl octanoate 

Ethyl oxyhydrate 

Ethyl propionate 

Geranyl acetate 

Geranyl formate 

Glutamic acid, monosodium salt (Monosodium glutamate) 
7-Hydroxy-3,7-dimethyl-l-octanal (Hydro xyc i tronel lal) 

Isopentyl butyrate 

Isopentyl formate 

Isopentyl isovalerate 

Octanal 

Rhodinol 

All other acyclic materials 



1,000 
pounds 



427 
106 
82 
4 
285 
790 
,080 
804 



111 
125 
11 
47,185 
857 
102 



1,000 
pounds 



281 

453 

3,236 



37 


35 


127 




39 


201 


35 


28 


177 


5 






70 


53 


269 


3,551 


2,824 


4,930 


2,666 






1,379 






1,280 


1,022 


2,997 


569 


454 


353 



1,000 
dollars 



873 

524 

414 

43 

1,570 

3,031 



658 
13,948 



30,135 
4,931 



Calculated from the unrounded figures. 
^ Includes significant quantities having other end uses 



FLAVOR AiJD PERFUflE MATERIALS 



TABLE 2,- 



-Flavor and perfume materials for which U.S. production or sales were 

REPORTED. IDENTIFIED BY MANUFACTURER, 197'4 



[Flavor and perfume materials for which separate statistics are given in table 1 are marked below with an asterisk 
(*) ; those not so marked do not appear in table 1 because the reported data are accepted in confidence and may 
not be published. Manufacturers' identification codes are taken from table 3. An x signifies that the manufac- 
turer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC 

Benzenoid and Naphthalenoid 

2'-Acetonaphthone 

l-Acetoxy-2-sec-butyl-l-ethenylcyclohexane 

5- Acetyl- 1 ,1,2,3,3,6-hexamethylindan 

p-Allylanisole 

Allyl cyclohexyl propionate 

4-Allyl-l ,2-dimethoxybenzene C4-Allylveratrole) 

*4-Allyl-2-methoxyphenol (Eugenol) 

4-Allyl-2-raethoxyphenol acetate (Eugenol acetate) 

4- Ally 1-1, 2- (methylenedioxy) benzene (Safrole) 

Allyl phenoxyacetate 

p-tert-Amylcyclohexanone (Orivone) 

*p-Anisaldehyde 

*Anisyl acetate 

Benzaldehyde 

*Benzophenone 

*Benzyl acetate 

*Benzyl benzoate 

*Benzyl butyrate 

'Benzyl cinnamate 

2-Benzyl-l,3-dioxolane 

Benzyl ether 

Benzyl formate 

Benzyl glyceryl acetal 

Benzyl isobutyrate 

Benzyl isopentyl ether 

Benzyl isovalerate 

Benzyl laurate 

1- (Benzyloxy)-2-methoxy-4-propenylbenzene (Benzyl 
isoeugenyl ether) . 

Benzyl phenylacetate 

*Benzyl propionate 

*Benzyl salicylate 

a-Bromostyrene 

2-sec-Butylcyclohexanone 

p-tert-Butylcyclohexanone 

p-tert- Butyl cyclohexyl acetate 

4-tert-Butyl-2' ,6' -dimethyl- 3' ,5'-dinitroacetophenone 

(Musk ketone) . 
6-tert-Butyl-3-raethyl-2,4-dinitroaniSole (Musk anbrette)- 

p-tert- Butyl-a-methylhydrocinnamaldehyde 

Butyl phenylacetate 

l-tert-Butyl-3,4,S-trimethyl-2,6-dinitrobenzene (Musk 
Tibetene) . 

5-tert-Butyl-2, 4, 6-trinitro-m- xylene (Musk xylol) 

Carvacrol 

Cinnamaldehyde 

*Cinnamyl acetate 

*Cinnamyl alcohol 

*Cinnamyl anthranilate 

Cinnamyl butyrate 

Cinnamyl cinnamate 



GIV. 




GIV. 




PFW. 




GIV, GLD. 




GIV. 




GIV, UOP. 




CI, FB, GIV, IFF, PEN, RT, UNG, UOP 


CI, GIV. 




FB, GIV. 




GIV. 




CI, IFF. 




GIV, OPC, UOP. 




ELN, GIV, UOP. 




FB. 




GAF, NEO, PD, UOP. 




GIV, MON, OPC, UOP. 




MON, OPC, PFZ, UOP, VEL. 




ELN, FB, GIV. 




FB, GIV, UOP. 




GIV. 




VEL. 




GIV, UOP. 




GIV. 




GIV. 




GIV. 




FB. 




GIV. 




GIV, UOP. 




ELN, GIV. 




ELN, FB, GIV, OPC. 




GIV, MON, UNG, UOP. 




UOP. 




GIV. 




CI. 




CI, IFF. 




GIV. 




GIV. 




GIV, UOP. 




GIV. 




GIV, UOP. 




GIV. 




GIV. 




CI, FB, UOP. 




ELN, FB, GIV. 




FB, GIV, NEO, UOP. 




FEL, GIV, RT. 




FB. 





SYNTHETIC ORGA.JIC CHEhlCALS, 1974 



TABLE 2, 



-Flavor and perfume materials for which ''.S, production or sales were 
^eported^ identified by manufacturer, 197'i--c0nti nued 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Bemenoid and Naphthalenoid — Continued 

*Cinnaniyl propionate 

Cinnamyl tiglate 

Coumarin 

Cuminyl alcohol 

Cyclohexylcyclohexanone 

trans -Decahydro-6-naphthol 

2,4-Dibronio-6-nitro-m-cresyl methyl ether 

1 , 2-Dimethoxy-4-propenylbenzene (4-Propenylveratrole] — 
3,7-Dimethyl-l,6-octadien-3-yl, anthranilate (Linalyl 

anthranilate) . 
trans-3,7-Dimethyl-2,6-octadien-l-ol, benzoate (Geranyl 

benzoate) . 
3,7-Diiiiethyl-l,6-octadien-3-ol, benzoate (Linalyl 

benzoate) . 
3,7-Dimethyl-l,6-octadien-3-ol, cinnamate (Linalyl 

cinnamate) . 
3,7-Dimethyl-l,6-octadien-3-ol, formate (Linalyl 

formate) . 
3,7-Dimethyl-2,6-octadienylphenylacetate (Geranyl 

phenylacetate) . 

a,a-Dimethylphenethyl acetate 

a,a-Dimethylphenethyl alcohol 

a,a-Dimethylphenethyl alcohol, tech 

a,a-Dimethylphenethyl butyrate 

Diphenylme thane (Benzylbenzene) 

1 ,3-Diphenyl-2-propanone (Dibenzyl ketone) 

p-Ethoxybenzaldehyde 

3-Ethoxy-4-hydroxyhenzaldehyde (Ethylvanillin) 

2-Ethoxynaphthalene 

Ethyl anthranilate 

Ethyl benzoate 

Ethyl butylcyclohexanol 

Ethyl cinnamate 

Ethyl a,6-epoxy-6-methylhydrocinnamate 

2-Ethylhexyl salicylate 

Ethyl phenylacetate 

*Ethyl phenyl glycidate 

Ethyl salicylate 

3'-Ethyl-5' ,6 ',7' ,8'-tetrahydro-5 ' ,5',8' ,8'- 

tetramethyl-2 '-acetonaphthone. 
1,3,4,6,7 , 8-Hexahydro-4 ,6,6,7,8 , 8-hexamethyl eye lopent a- 

Y-2-benzopyran (Galaxolide) . 

Hexyl benzoate 

a-Hexylcinnamaldehyde 

Hydratropaldehyde 

Hydratropaldehyde, dimethyl acetal 

Hydro cinnamic acid 

*Hydro coumarin 

Hydroxycitronellalmethyl anthranilate 

3-Hydroxy-4-methoxybenzaldehyde (Isovanillin) 

4-Hydroxy-3-methoxybenzaldehyde (Vanillin) 

4- (4-Hydroxy-3-methoxyphenyl) -2-butanone 

Indole 

I so amy 1 phenylacetate 

Isobutyl benzoate 

p-Isobutyl-a-methylhydrocinnamaldehyde 

* Isobutyl phenylacetate 

Isobutylquinoline 

'Isobutyl salicylate 

Isohexenyl tetrahydrobenzaldehyde-2,3,7,8 (Myrac 

aldehyde) . 
Isononyl acetate 



ELN, FB, GIV. 

FB. 

DOW, RDA. 

GIV. 

GIV. 

IFF. 

GIV. 

GIV, UOP. 

FMT. 

GIV. 



HOF. 
HOF. 



IFF. 




IFF. 




IFF. 




IFF. 




UOP. 




GIV. 




GIV. 




MON, 


SLV. 


GIV. 




FB. 




ELN. 




HOF. 




ELN, 


GIV. 


ELN. 




FEL. 




GIV. 




GIV, 


PFW, UOP 


FB. 




GIV, 


UOP. 



IFF. 

GIV. 

CI, IFF. 

GIV, IFF. 

GIV, IFF. 

ARS. 

ARS, GIV, UOP. 

GIV. 

SLV. 

MON, SLV. 

GIV. 

GIV. 

GIV. 

ELN. 

RDA. 

ELN, FB, GIV. 

IFF. 

FB, GIV, UOP. 

IFF. 

CI. 



FLAVOR AND PERFUME I'lATERIALS 



TABLE 2.— Flavor and perfume materials for which U.S. production or sales were 

REPORTED^ identified BY MANUFACTURER, 1974--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Bensenoid and Naphthalenoid — Continued 

Isopentyl benzoate 

*Isopentyl salicylate 

p-Isopropylbenzaldehyde (Cumaldehyde) 

p-Isopropylcyclohexanol 

p-Isopropyl-a-methylhydrocinnamaldehyde 
(Cyclamen aldehyde) . 

p-Mentha-1 ,8-diene (Limonene) 

Menthyl anthranilate 

4'-Methoxyacetophenone (Acetanisole) 

p-Methoxybenzyl alcohol (Anisyl alcohol) 

o-Methoxycinnamaldehyde 

2-Methoxyn aphtha lene 

1- (p-Methoxyphenyl)-l-penten-3-one 

2-Methoxy-4-propenylphenol (Isoeugenol) 

2-Methoxy-4-propenylphenol, acetate 

4'-Methylacetophenone 

p-Methylanisole 

Methyl anthranilate 

Methyl benzoate 

a-Methylbenzyl acetate (Styralyl acetate) 

a-Methylbenzyl alcohol (Styralyl alcohol) 

*a-Methylcinnamaldehyde 

Methyl cinnamate 

6-Methylcoumarin 

Methylcyclohexyl propionate 

1,2- (Methylenedioxy) -4-propenylbenzene (Isosafrole) 

4-Methyl-7-ethoxycoumarin 

p-Methylhydratropaldehyde 

1 -Methyl- 4- isohexyl-hexahydrobenzaldehyde 
(Vernaldehyde) . 

2-Methyl-5-isopropylphenol (Carvacrol) 

Methyl -N-rae thy 1 anthranilate 

2-Methyl-6-(4-methyl-3-cyclohexanylidene)-2-heptene, 
and Ci5 hydrocarbon isomers. 

*Methyl phenyl acetate 

*Methyl salicylate 

lH-Naphtho-[2,3-c]pyran-3,4,6,7,8,9-hexahydro-4,6,6,9,9- 
pentamethyl (Musk 89) . 

l,l,3,3,5-Pentamethyl-4,6-dinitroindan 

*a-Pentylcinnamaldehyde 

*Phenethyl acetate 

Phenethyl alcohol 

Phenethyl anthranilate 

Phenethyl formate 

♦Phenethyl isobutyrate 

♦Phenethyl isovalerate 

*2- Phenethyl phenyl acetate 

Phenethyl propionate 

Phenethyl salicylate 

2-Phenoxyethyl isobutyrate 

Phenylacet aldehyde 

Phenylacetaldehyde, dimethyl acetal 

o-Phenylanisole (2-Methoxybiphenyl) 

4-Phenyl-3-buten-2-one (Benzylideneacetone) 

Phenyl ethyl acetal 

Phenylethyl tiglate 

*3-Phenyl-l-propanol (Hydrocinnamic alcohol) 

3-Phenylpropyl acetate 



GIV. 

FB, GIV, MON, OPC, UOP. 

GIV. 

CI, GIV. 

GIV, RDA. 

SKG. 

PFW. 

GIV, UOP. 

GIV, UOP. 

CI. 

GIV. 

GIV. 

CI, FB, GIV, UOP. 

UOP. 

GIV, UOP. 

GIV, OPC, SW. 

FB, PFW, UNG. 

HN. 

CI, ELN, GIV. 

CI. 

CI, FB, GIV. 

CI, FB, UOP. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV. 

GIV. 



GIV. 






GIV. 






HOF. 






ELN, 


GIV, OPC 




DOW, 


HN, MON. 




IFF. 






GIV. 






CI, 


=B, GIV, IFF, 


GIV, 


IFF, NEO 




IFF, 


NEO. 




RT. 






ELN. 


IFF. 




ELN, 


GIV, IFF 




ELN, 


FB, GIV, 


OPC. 


ELN, 


FB, GIV, 


IFF. 


ELN, 


GIV, IFF 




GIV. 






ELN, 


GIV, IFF 




GIV. 






GIV, 


UOP. 




GIV. 






FB, 


UOP. 




GIV. 






FB. 






ELN 


FB, GIV, 


UOP. 


ELN 


GIV. 





SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2, 



-FlAVok and PEKFUME materials for which U.S. PRODUCTION OR SALES WERE 
REPORTED, IDENTIFIED BY MANUFACTURER, 1974--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued 

Benzenoid and Naphthalenoid — Continued 

3-Phenylpropyl cinnamate 

Piperonal (Heliotropin) 

Piperonal bisulfite (Heliotropin bisulfite) 

*p-Propenylanisole (Ane thole) 

p- Propyl ani sole (Dihydroanethole) 

N-Propylphenylethyl alcohol 

Sassafrass oil, hydrogenated 

Sweeteners, synthetic: 

Cyclohexanesulfamic acid 

Cyclohexanesulfamic acid, calcium salt 

Cyclohexanesulfamic acid, sodium salt 

Saccharin (l,2-Benzisothiazolin-3-one, 1,1-dioxide)- 

Saccharin, calcium salt 

Saccharin, sodium salt 

p-Tolualdehyde 

p-Tolylacetaldehyde 

p-Tolyl acetate 

p-Tolyl phenyl acetate 

a-(Trichlororaethyl)benzyl acetate (Rosetone) 

Terpenoid, Heteroayclio, and Alicyclic 

Acetyl cedrene (Vertofix) 

Amyris acetate 

B-Caryophyllene 

Caryophyllene acetate 

Caryophyllene alcohol 

L-Carvyl acetate 

Caryophyllene oxide 

a-Cedrene epoxide (Andrane) 

Cedrene- 8-0I 

Cedrenol 

Cedrol 

*Cedryl acetate 

Cedryl formate 

Cedryl methyl ether (Cedramber) 

Chemically modified butter oil 

Clove leaf oil terpenes 

Cyclopentanone 

Dihydronordicyclobutyrate (Cyclabute) 

Dihydronordicyclopentadienyl acetate 

Dihydronordicyclopentadienyl propionate 

Dihydroterpinyl acetate 

Ethyl furoate 

Ethynlcyclohexanol 

Furfuryl acrolein (Furfural acrolein) 

4- (2-Furyl)-3-buten-2-one (Furfural acetone) 

Guaicwood acetate 

Guaiene 

3,4,5,8,9, lO-Hexahydro-4-isopropyl-l ,6-dimethyl- 
naphthalene (Cadinene) . 

2-Hexyl-2-cyclopenten-l-one (Isojasmone) 

3-Hydroxy-2-ethyl-4-pyrone (Ethyl maltol) 

4- (4-Hydroxy-4-methylpentyl)-3-cyclohexene-10- 
carboxaldehyde (Lyral) . 



FB. 

AMB, GIV. 

AMB. 

ARZ, GLD, HN, HPC, NCI, RSA. 

FB, GIV. 

GIV. 

GIV. 

ABB. 

ABB. 

ABB. 

SW. 

SW. 

SW. 

GIV, TCC. 

GIV. 

ELN, GIV. 

GIV. 

NEC. 



IFF. 

GIV. 

CI, ( 

CI. 

FB. 

FB. 

GIV. 

IFF. 

IFF. 

GIV. 

ELN, 

ELN, 

IFF. 

IFF. 

RT. 

CI. 

ARA. 

IFF. 

GIV, 

GIV, 

GIV. 

RT. 



GIV, IFF, NEC. 
GIV, IFF, NEO, UOP. 



IFF. 
IFF. 



RT. 

ELN, GIV, NEO. 

FB. 



FB. 

PFZ. 

IFF. 



FLAVOR AND PERFUilE MATERIALS 
TABLE 2, --Flavor and perfume materials for which U.S. production or sales were 

REPORTED^ IDENTIFIED BY MANUFACTURER^ 197^--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, CYCLlC--Continued 

Terpenoid, Heterooyolio, and Aliay die- -Continued 

3-Hydroxy-2-methyl-4-pyrone (Maltol) 

4-Hydroxynonanoic acid, y-lactone (y-Nonalactone) 

4-Hydroxyoctanoic acid, y-lactone (y-Octalactone) 

4-Hydroxyundecanoic acid, y-lactone (y-Undecalactone)- 
lonones : 

*a-Ionone 

6- Ion one 

*Ionone (a- and 6-) 

Isobomyl acetate 

Isobomyl propionate 

Isocamphyl cyclohexanols (Terpinyl cyclohexanol's) 

Isomenthone 

5-Isopropenyl-2-methylcyclohexanol (Dihydrocarveol) — 
5-Isopropenyl-2-methylcyclohexanone (Dihydrocarvone)-- 

4- Isopropyli dene- 1 -methyl eye lohexene (Terpinolene) 

Jasmal 

*Lavandin, acetylated 

p-Mentha-6,8-dien-2-ol (L-Carveol) 

p-Mentha-6,8-dien-2-one (Carvone; Carvol) 

p-Mentha-1 ,3-diene (a-Terpinene) 

p-Mentha-1 ,4-diene (.y-Terpinene) 

p-Menthan-3-one (Menthone) 

p-Menth-l-en-3-one 

p-Menth-4(80-en-3-one (d-Pulegone) 

p-Menth-8-en-3-ol (Isopulegol) 

l,l-p-Menthen-6-yl-l-propanone 

*Menthol, synthetic: 

Tech 

U.S.P 

Menthyl acetate 

*Methylionones : 

6-Methyl-a-ionone 

Methylionone (a- and B-) 

y-Me thy 1 i onone 

Nopyl acetate 

3-Pentyl-tetrahydro-4-pyranol (Jessemal) 

Rose oxide 

Santalol 

Santalyl acetate 

Terpin hydrate, tech 

*Terpineols ; 

a-Terpineol 

Terpineol (a- and 6-) 

*a-terpinyl acetate 

Terpinyl acetate (mixed a- and 6-) 

a-Terpinyl propionate 

Tetrahydropseudoi onone 

Tricyclodecenyl propionate 

Tricyclononyl acetate 

3,3,5-Trimethyl cyclohexanol (Horaomenthol) 

l-(2,6,6-Trimethyl-2-cyclohexen-l-yl]-l,6-heptadien- 
3-one (Allyl-a-ionone) . 

Vetivenol 

*Vet i veny 1 acet ate 

FLAVOR AND PERFUME MATERIALS, ACYCLIC 

AcetylbutyTyl-2,3-hexanedione 

Acetylisovalery 1-5 -methyl- 2, 3-hexanedione 

3-Acetylnonyl acetate 

Acetylpropionyl-2,3-pentanedione 

Allyl disulfide 



GIV, 


UOP. 






GIV, 


RT, UOP. 






ELN, 


FB. 






GIV, 


HOF, IFF, 


MYW. 




HOF, 


MYW. 






GIV, 


MYW, NEO. 






FB, 


RDA. 






GIV. 








GIV. 








GIV. 








GLD. 








GLD. 








GLD. 








IFF. 








FEL, 


GIV, UNG. 






FB. 








NEO. 








GLD. 








GLD. 








GIV, 


NEO. 






GIV. 








GIV. 








GIV. 








GIV. 








GIV. 








CIV, 


GLD, NEO. 






GIV. 








GIV, 


MYIV. 






GIV, 


IFF, MYW, 


NEO 


UNG. 


GIV. 








CI, 


FEL, NEO. 






IFF. 








FB. 








GIV, 


IFF. 






GIV. 








HPC. 








GLD, 


HPC, NCI 






GIV, 


NEO. 






GIV, 


NCI, NEO, 


PFW 


UNG. 


RDA. 








ELN, 


GIV. 






CI. 








CI. 








CI. 








ARS 








IFF 








GIV 


UOP. 






ELN 


FB, GIV, 


IFF, 


NEO, UOP 



CI. 
FB. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2.- 



-FlAVOR and perfume materials for which U.S. PRODUCTION OR SALES WERE 
REPORTED. IDENTIFIED BY MANUFACTURER, 197'i--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3] 



FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued 

Allyl heptanoate 

*Allyl hexanoate 

Allyl isovalerate . 

Allyl octanoate (Allyl caprylate) 

Allyl sulfide 

Ainyl propionate 

Butyl butyrate 

*Butyl butyryl lactate 

Butyl undecylenate 

1-Butyne 

Citral dimethyl acetal 

*Citronellyl acetate 

Citronellyl butyrate 

*Citronellyl formate 

*Citronellyl isobutyrate 

Citronellyl oxyacet aldehyde 

Citronellyl propionate 

Decanal (Capraldehyde) 

Decen-9-ol-l (Rosalva) 

Decyl acetate 

Diethyl acetal 

Diethyl sebacate 

Diethyl succinate 

Dihydromyrcenol 

Dihydromyrcenyl formate (Dimyrcetol) 

2,6-Dimethyl-5-hepten-l-al 

Dimethylhexanediol 

Dimethylhexynediol 

3,7-Dimethyl-3-methoxy-l ,6-octadiene (Linalyl methyl 
ether) . 

3,7-Dimethyl-l ,6-nonadien-3-ol (Ethyl linolool) 

3,7-Dimethyl-l ,6-nonadien-3-ol , acetate (Ethyl linalyl 

acetate) . 
3,7-Dimethyl-2 ,6-nonadienenitrile 

*3,7-Dimethyl-cis-2,6-octadien-l-ol (Nerol) 

3,7-Dimethyl-trans-2,6-octadienal (Citral a; Geranial)- 
3,7-Dimethyl-2 ,6-octadienal (mixture of cis and trans 

isomers) . 
3,7-Dimethyl-trans-2,6-octadienal dimethyl acetate 

*3,7-Dimethyl-trans-2,6-octadien-l-ol (Geraniol) 

*3,7-Dimethyl-l ,6-octadien-3-ol (Linalool; Linalyl 
alcohol) . 
3,7-Dimethyl-l ,6-octadien-3-ol acetate (Linalyl 

acetate) . 
3,7-Dimethyl-l ,6-octadien-3-yl isobutyrate (Linalyl 

isobutyrate) . 
3,7-Dimethyl-l ,6-octadien-3-ol propionate (Linalyl 
propionate) . 

3,7-Dimethyl-l,7-octanediol 

3,7-Dimethyloctan-3-ol (Tetrahydrolinalool) 

3,7-Dimethyl-l-octanol (Dihydrocitronellol) 

*3,7-Dimethyl-6-octen-l-al (Citronellal) 

*3,7-Dimethyl-6-octen-l-ol (Citronellol) 

2,6-Dimethyl-2-octene-7-yne-6-ol 

3,7-Dimethyl-7-octenol and 6-octenol isomer 

Dime thy loctynol 

♦Ethyl butyrate 

Ethyl caprate 

Ethyl formate 

*Ethyl heptanoate 



FB, 


RT. 




ELN 


FB, 


GIV, PFW. 


RT. 






RT. 






RT. 






GIV 






FB. 






ARS 


BJL 


RT. 


CI. 






X. 






GIV 


IFF 




ELN 


GIV 


IFF. 


GIV 






ELN 


GIV 


IFF, NEO. 


ELN 


GIV 


IFF. 


IFF 






GIV 


IFF 




CI, 


GIV, 


IFF. 


IFF 






GIV. 






FB. 






ELN 


FEL 


UOP. 


ELN 


UCC 




IFF. 






IFF 






GIV. 







HOF. 
HOF. 



GIV. 
ELN, 



CI, 
ELN, 



FB, GIV, GLD, IFF. 
FEL, GIV, GLD, NCI, RDA, UOP. 



ELN, FB, FEL, GIV, GLD, IFF, NCI, NEO, UOP. 
FB, FEL, GIV, GLD, HOF, NCI, UNG. 



ELN, FB, GIV, HOF, IFF, NEO, UNG. 



GIV. 

HOF, 

GIV, 

CI, 

CI, 

RDA. 

GIV. 



ELN, FB, GIV, GLD, IFF, NEO, RDA, UOP. 
ELN, FB, GIV, GLD. IFF, NCI. NEO. 



FB, NW, UOP. 



ELN, FB, FEL, RT, UOP. 



FLAVOR AND PERFUME MATERIALS 



TABLE 2,- 



-Flavor and perfume materials for which U,S, production or sales were 
reported, identified by manufacturer, 197'4— continued 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC- -Continued 

6- Ethyl -5 hep ten- 2 -one 

*Ethyl hexanoate (Ethyl caproate) 

Ethyl isohexanoate 

Ethyl i so valerate 

Ethyl laurate 

Ethyl 2-methylbutyrate 

Ethyl myristate 

*Ethyl nonanoate 

*Ethyl octanoate 

*Ethyl oxyhydrate 

*Ethyl propionate 

Ethyl valerate 

Geranic acid 

*Geranyl acetate 

Geranyl butyrate 

*Geranyl formate 

Geranyl isobutyrate 

Geranyl isovalerate 

Geranyl neryl formate 

Geranyl nitrile (Geranonitrile) 

Geranyl propionate 

Geranyl tiglate (Geranyl diraethylacrylate) 

'Glutamic acid, monosodium salt (Monosodium glutamate) • 

Glyceryl trihexanoate (Caproic acid triglyceride) 

Y-Heptalactone 

Heptyl alcohol (1-Heptanol) 

Hexanoic acid (Caproic acid) 

Hexenal 

2-Hexenal 

2-Hexenoic acid 

2-Hexenol 

trans-2-Hexenol 

cis-3-Hexen-l-ol 

cis-3-Hexen-l-ol lactate 

cis-3-Hexen-l-yl acetate 

cis-3-Hexenyl 2-methylbutyrate 

3-Hexyn-l-'Dl 

3-Hydroxy-2-butanone (Acetoin) 

*7-Hydroxy-3,7-dimethyl-l-octanaI (Hydroxycitronellal)- 
7-Hydroxy-3,7-dimethyl octanal , dimethyl acetal 
(Hydroxycitronellal, dimethyl acetal). 

Isoamyl acetate 

Isoamyl geranate 

Isoamyl propionate 

Isoamyl undecylenate 

Isobutyl acetate 

Isobutyl hexanoate 

Isodihydro lavandulol 

Isodihydro lavandulyl acetate 

Isodihydro lavandulyl aldehyde 

Isopentyl acetate 

*Isopentyl butyrate 

*lsopentyl formate 

* Isopentyl isovalerate 

Laura Idehyde 

Methyl butenol 

Methyl butynol 

Methyl heptadienone 

3-Methyl-5-heptanone oxime 

2-Methyl-2-hepten-6-one 

2-Methyl-2-hepten-7-one 

6-Methyl-5-hepten-2-one 



HOF. 






ELN, FB, NW, 


PFW, 


RT. 


PFW. 






FB, PFW. 






ELN. 






GLD. 






RT. 






ELN, FB, EEL, 


GIV 




ELN, FB, RT. 






FB, FEL, FLO 


MON 


PFW, RT 


FB, NW, UOP. 






PFW. 






FB. 






CI, ELN, FEL, 


GIV 


IFF. 


ELN, GIV. 






ELN, CI, GIV 






IFF. 







COM 
CI. 
FB. 
UCC 



GLD. 
GIV, 
RT. 
GIV. 
GLD, 
HOF, 
FMT, 
CI, 
GIV 



FMT. 
GRW, SFF. 



GIV, GLD, IFF, NEO, RDA, UOP. 
UOP. 



FB. 

FB. 

GIV. 

FB. 

GIV. 

FB. 

FB. 

FB. 

NW. 

FB, GIV, NW, PFW, UOP. 

ELN, FB, GIV, RT. 

ELN, FB, PFW, RT. 

CI, GIV. 

X. 

HOF. 
GIV. 
RDA. 
RDA. 
HOF. 



SYNTHETIC ORGANIC CHEMICALS, 197^) 
TABLE 2, --Flavor and perfume materials for which U.S. production or sales were 

REPORTED^ IDENTIFIED BY MANUFACTURER, 1974~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



FLAVOR AND PERFUME MATERIALS, ACYCLIC--Continued 

Methyl hexyl ether 

Methyl isobutyrate 

Methyl 2-nethyl butyrate 

3-Methyl-2-(and 3^ nonenitrile 

Methyl-2-nonenoate 

Methylol methyl hexyl ketone 

3-Methyl-3-pentenyl-l- isobutyrate 

Methyl pentynol 

6-Methylthiopropionaldehyde 

2-Methylundecanal 

Muguol (Alloocimenol) 

Myrcenyl acetate 

Myrist aldehyde 

Neryl acetate 

Nonanal 

Nonane-l,3-diol monoacetate 

Nonanol 

2-Nonanone 

Nonyl acetate 

Ocimenol 

Ocimenyl acetate 

*Octanal 

3-Octanol 

3-Octanone (Ethyl amyl ketone) 

n-Octyl acetate 

Octyl alcohol (1-Octanol) 

Octyl isovalerate 

Pentyl acetate 

Propyne 

Pseudolinalyl acetate 

Pyrolysate ester (Aconitic ester) 

*Rhodinol 

Rhodinyl acetate 

Tepyl acetate 

Tetrahydromuguol (T. H. alloocimenol) 

3,7,11-Trimethyl-l ,6, lO-dodecatriene-3-ol 

2,6,10-Trimethyl-9-undecen-l-al 

3,6,10-Trimethyl-9-undecen-2-one and isomers 

2,6,6-Trimethyl-2-vinyl-5-hydroxytetrahydropyrane 
(Linalool oxide) . 

Undecanal 

9-Undecenal 

Y- Valero lac tone 



GLD. 
PFW. 
GLD. 
GIV. 
GIV. 
GIV. 
HOF. 

X. 

RT. 

GIV. 

IFF. 

IFF. 

GIV. 

FB, 

GIV. 

CI, 

GIV. 

HOF. 

GIV. 

IFF. 

IFF. 

CI, 

GIV 

GIV 

FB, 

GIV 



GIV. 
GIV. 



GIV, IFF. 
GIV. 



IFF. 
GIV. 



FEL, GIV, IFF, NEO. 
IFF. 



FB, 

GIV, 

UOP. 

IFF. 

HOF. 

GIV. 

GIV. 

HOF. 



GIV, IFF. 

GIV. 

GIV. 



FLAVOR AND PERFUME MATERIALS 
TABLE 3.— Flavor and perfume materials: Directory of manufacturers^ 1974 



ALPHABETICAL DIRECTORY BY CODE 



[Names of manufacturers that reported production or sales of flavor and perfume materials to the U.S. International 
Trade Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of Company 


Code 


Name of Company 


ABB 


Abbott Laboratories 


MNR 


Monroe Chemical Co. 




AIP 


Air Products § Chemicals, Inc. 


HON 


Monsanto Co. 




AMB 


American Bio-Synthetics Corp. 


WW 


Stepan Chemical Co. 




ARA 


Arapahoe Chemical Inc., 










Sub/Syntex (U.S.A.), Inc. 


NCI 


Union Camp Corp., Chemical 


Division 


ARS 


Arsynco, Inc. 


NEO 


Norda Inc. 




ARZ 


Arizona Chemical Co. 


NW 


Northwestern Chemical Co. 




BJL 


Burdick 5 Jackson Labs., Inc. 


npc 


Orbis Products Corp. 




CI 


Chem-Fleur, Inc. 


PD 


Parke, Davis 6 Co. 




COM 


Commercial Solvents Corp. 


PEN 
PFW 


CPC International, Inc., P 
Polak's Frutal Works, Inc. 


jnick Division 


DOW 


Dow Chemical Co. 


PFZ 


Pfizer, Inc. 




ELN 


Elan Chemical Co. 


RDA 
RSA 


Rhodia, Inc. 
R.S.A. Corp. 




FB 


Fritzsche, Dodge 5 Olcott, Inc. 


RT 


F. Ritter 5 Co. 




FEL 


Felton International, Inc. 








FLO 


Florasynth, Inc. 


SFF 


Stauffer Chemical Co., 




fmt 


Fairmount Chemical Co., Inc. 


SKG 


Food Ingredients Div. 
Sunkist Growers, Inc. 




GAF 


GAF Corp., Chemical Division 


SLV 


Sterwin Chemicals, Inc. 




GIV 


Givaudan Corp. 


SW 


Sherwin-Williams Co. 




GLD 


SCM Corp., Glidden-Durkee Division 








GRW 


Great Western .Sugar Co. 


TCC 


Tanatex Chemical Corp. 




HN 


Tenneco Chemicals, Inc. 


UCC 


Union Carbide Corp. 




HOF 


Hoffman-LaRoche , Inc. 


UMG 


Ungerer 6 Co. 




HPC 


Hercules, Inc. 


UOP 


Universal Oil Products Co. 
Chemical Division 


UOP 


IFF 


International Flavor f, Fragrances, Inc. 


VEL 


Velsicol Chemical Corp. 





Note. --Complete 



es and addresses of the above reporting companies are listed in table 1 of the appendix. 



126 SYNTHETIC ORGANIC CHEMICALS. 197^ 

PLASTICS AND RESIN MATERIALS 



Plastics and resin materials are high molecular weight polymers 
which, at some stage in their manufacture, exist in such physical con- 
dition that they can be shaped or otherwise processed by the application 
of heat and pressure. Depending on the chemical composition, manufac- 
turing process or intended use, the commercial products may contain 
plasticizers , fillers, extenders, stabilizers, coloring agents or other 
additives. Plastics materials may be molded, cast or extruded into simi- 
finished or finished solid forms. Resin materials may be in the form of 
solutions, pastes or emulsions for applications such as protective 
coatings, adhesives, or paper and textile treatment. These statistics 
also cover polyether and polyester polyols for urethanes which are not 
plastics materials themselves, but are precursors. 

Statistics covering urethane type elastomers are reported for the 
first time in this section; through 1973, these data were reported 
under the elastomers [synthetic rubbers) section. 

Statistics on U.S. production and sales of synthetic plastic and 
resin materials for 1974 are given in table 1.^ U.S. production of 
plastics and resin materials in 1974 totaled 30,348 million pounds, or 
less than one percent more than the 30,251 million pounds produced in 
1973. Sales in 1974 totaled 26,128 million pounds, valued at $7,887 
million compared with 27,018 million pounds, valued at $5,347 million 
in 1973. 

Thermosetting materials are those which harden with a change in 
composition in the final treatment so that they cannot again be 
softened by heat or solvents. U.S. production of thermosetting materials 
totaled 6,119 million pounds in 1974 compared with 6,394 million pounds 
in 1973. Production of the most important products in 1974 included 
phenolic resins (1,598 million pounds), amino (or urea and melamine) resins 
(1,236 million pounds), polyester resins, (unsaturated) (838 million 
pounds) and alkyd resins (726 million pounds). 

Thermoplastic materials are those which can be repeatedly softened 
by heat and shaped. U.S. production of thermoplastic materials totaled 
24,229 million pounds in 19 74 compared with 23,856 million pounds in 
1973. Production of the most important products in 1974 included poly- 
ethylene (8,826 million pounds), vinyl resins (5,669 million pounds), and 
styrene type materials (5,060 million pounds). 



See also table 2 which lists these products and identifies the manu- 
facturers of each by codes. These codes are given in table 3. 



PLASTICS AND RESIN flATERIALS 
TABLE 1. --Plastics and resin materials; U,S, production and sales, 197^ 



(Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all 
plastics and resin materials, urethane type elastomers and certain precursors for which any reported data on 
production or sales may be published. (Leaders (...) are used where the reported data are accepted in confidence 
and may not be published and/or where no data were reported.) Table 2 lists all products for which data on pro- 
duction and/or sales were reported and identifies the manufacturers of each] 



Grand total 

Plastics and resin materials, benzenoid' 

Plastics and resin materials, nonbenzenoid 

THERMOSETTING RESINS 

Total 

Alkyd resins, total'' 

Phthalic anhydride type 

Polybasic acid type 

Styrene alkyd polyesters* 

Polyester resins, unsaturated 

Amino resins, total 

Melamine-formaldehyde resins 

Urea-formaldehyde resins 

Dicyandi amide resins 

Epoxy resins :' ' 

Unmodified 

Advanced 

Furfuryl type resins 

Phenolic and other tar acid resins 

Polyurethane and diisocyanate resins (excluding foam) 

and urethane type elastomers', total 

Polyurethane and diisocyanate resins 

Urethane type elastomers'" 

Polyether and polyester polyols for urethanes 

Silicone resins 

Other thermosetting resins'^ 

THERMOPLASTIC RESINS 

Total 

Acrylic resins'' '" 

Cellulosic plastics and resins" '* 

Coumarone-indene resins 

Engineering plastics'* 

Petroleum hydrocarbon resins 

Polyamide resins, nylon type^ ' '- 

Polyamide resins, non-nylon type 

Polyester resins, saturated" ' 

Polyethylene and copolymers resins, total 

Density 0.940 and below^" 

Density over 0.940 



See footnotes at end of table. 



1,000 

pounds 

dry basis'^ 

30,548,130 



9,767,809 
20,580,321 



6,118,815 



726,057 



662,370 
31,458 
32,229 



204,338 
1,031,543 

1,991 

270,251 
(41,722) 
4,249 
1,598,438 



Quantity 



192,552 
88,050 

1,112,306 
17,749 
32,864 



24,229,315 



889,747 
224,469 

80,594 
398,404 
325,824 
172,586 

47,632 
106,455 

8,826,399 



6,027,117 
,799,282 



1,000 

pounds 

dry basis^ 

26,128,106 



8,341,509 
17,786,597 



4,976,462 



402,808 



365,938 
19,344 
17,526 

722,513 

1,058,584 



150,753 
907,831 

1,808 

234,657 

(24,844 

3,900 

1,375,553 



1,000 
dollars 



7.887.358 



3,243,405 
4,643,953 



1,778,014 



186,500 



169,874 
10,001 
6,625 



133,309 
66,089 

944,956 
13,327 
18,958 



21.151.644 



675,954 
198,699 

331,288 
310,177 
137,768 
41,052 
95,471 



68,735 
135,803 

1,584 

144,988 

(25,102) 

1,518 

486,696 



Unit 
value' 



pound 



74,655 
78,814 

264,317 
29,248 
14,089 



6,109,344 



5,377,227 
2,567,950 



364,013 
140,625 

266,550 
50,376 

130,994 
36,280 
85,882 

1,751,575 



1,212,699 
538,876 



.389 
.261 



.464 
.517 
.378 



.456 
.150 

.876 

.618 

1.010 

.389 

.354 



.560 
1.193 

.280 

2.195 

.743 



.539 
.708 

.805 
.162 
.951 



.226 
.210 



SYNTHETIC ORGANIC CHEMICAIS, 197t 
TABLE 1. --Plastics and resin materials: U,S, production and sales, 1974~Continued 



Quantity 



Unit 
value' 



ljO"0 



thermoplastic resins— Continued 

Polypropylene resins 

Polyterpene resins 

Polytetrafluroethylene (PTFE) 

Rosin modifications, total 

Rosin and rosin esters, unmodified (ester gums) 
Rosin and rosin esters, modified 

Styrene plastics materials, total 

Acrylonitrile-butadiene-styrene (ABS) resins 

Styrene-acrylonitrile resins (SAN) 

Styrene and other styrene copolymer resins 

Vinyl resins, total^' 

Polyvinyl chloride and copolyiners 

Polyvinyl acetate^ ^ 

Polyvinyl alcohol^' 

Other vinyl and vinylidene resins^" 

All other thermoplastic resins^^ 



dry basis 

2,248,718 
18,326 
18,370 

122,606 



1,000 

pounds 
dry basis^ 

1,944,844 
18,546 
14,823 

109,246 



1.000 
dollars 

460,839 

9,055 

44,257 

37,808 



Per 
pound 



to. 237 

.488 

2.986 



31,815 
90,791 

5,059,578 



21,136 

88,110 

4,555,865 



8,162 
29,646 

1,489,635 



.386 
.336 



898,344 

110,741 

4,050,493 



,744,007 
543,009 
141,064 
241,083 

20,444 



828,700 

109,199 

3,615,966 

4,692,529 



339,973 

35,681 

1,113,979 



.410 
.327 
.308 



3,955,273 
438,994 
123,035 
175,027 

82,405 



907,815 
138,543 
51,947 
106,880 

36,272 



.230 
.316 
.422 
.611 



Calculated from rounded figures, 

^ Dry weight basis unless otherwise specified. Dry weight basis is the total weight of the materials including 
resin and coloring agents, extenders, fillers, plasticizers, and other additives, but excluding water and other 
liquid diluents unless they are an integral part of the materials. 

' Includes benzenoid plastics and resin materials as defined in part 1 of schedule 4 of the Tariff Schedules 
of the United States; also includes urethane type elastomers which are not defined in part 1 of schedule 4 of the TSUS. 

'* The total now includes data for styrene alkyd polyesters. 

^ "Alkyd copolymers", "styrene polyesters", and "styrenated alkyds" have been suggested as alternative names by 
industry sources. 

' Polyester resins are unsaturated alkyd resins, later to be copolymerized with a monomer (such as styrene 
or methyl methacrylate) ; and polyallyl resins (such as diallyl phthalate and diglycol carbonate). Data are on 
an "as sold" basis, including monomer if part of the resin system. 

^ Includes reactive diluents which are an integral part of the resin. Excludes the weight of hardeners sold 
in association with the resin as part of a two-component system. 

* Data shown for advanced epoxy resins are that part of the unmodified epoxy resins which is further processed; 
therefore, the totals in parentheses are not included in the grand total. 

' In view of the very large number of producers of both flexible and rigid urethane foams, these data are not 
collected as such by the U.S. International Trade Commission. 

Data for urethane type elastomers are now included in this section of the Synthetic Organic Chemicals report; 
these statistics previously were reported under the elastomers (synthetic rubbers) section. The data on urethane 
elastomers are believed to be not fully representative of the total urethane market in view of the very large number 
of urethane elastomer producers. 

" In addition to the polyols, the other principal starting materials used in the production of urethane products 
are the isocyanic acid derivatives, mainly the 80/20 mixture of toluene-2,4- and 2,6-diisocyanate. Statistics 
for the isocyanic acid derivatives are reported in the cyclic intermediates section of the Synthetic Organic 
Chemicals report, 

'^ Includes acetone formaldehyde resins, glyoxal resins, polybutadiene resins, toluenesulfonamide resins, triazone 
resins, and other thermosetting resins. 

^ Does not include production or sales for fiber use. 
'" Includes data for acrylic resins reported to the U.S. International Trade Commission as thermosetting resins. 
" Now includes data on certain cellulosic plastics and resins which were transferred from the miscellaneous 
acyclic chemicals and chemical products section of the Synthetic Organic Chemicals report. 

" Engineering plastics: Acetals, polycarbonate, polyimide, polyphenylene sulfide (added in 1974), polysulfone, 
and polyphenylene oxide. Engineering plastics are defined in Whittington ' s Dictionary of Plastics , (First edition, 
published by Technomic Publishing Co., Inc.), as "Those [plastics] which have mechanical, chemical and thermal 
properties suitable for use in construction, machine components and chemical processing equipment". The above list 
of plastics (all of which are thermoplastic) was selected from a larger group in this source. The other plastics 
named in Whittington' s Dictionary as engineering plastics, ABS resins and nylon resins, are not included in the above 



(Continued) 



PLASTICS AND RESIN MATERIALS 129 

Footnotes for table 1 — Continued 
list as they are published separately. 

" Includes data for petroleum hydrocarbon resins reported to the U.S. International Trade Commission as thermo- 
setting resins. 

" Statistics for nylon 6 and nylon 6/6 which are used in plastic applications (e.g., molding etc.) are included 
here. 

Statistics for polyethylene terephthalate which is used in plastics applications (e.g., molding, etc.) are 
included here. 

^° Includes data for ethylene copolymers which were collected in the aggregate and which could not be published 
separately, these data were combined with statistics for low density polyethylene resins as the copolymers are 
predominately low density materials. 

Ethylene accounts for 50 percent or more (by weight) of these copolymers. The low-density polyethylene 
copolymers includes those produced from ethylene and other non-hydrocarbon co-monomers (e.g., vinyl acetate, ethyl 
acetate, and acrylic acid); while the high-density copolymers includes those products from ethylene and other 
hydrocarbon monomers (e.g., butene or hexene) , 

^' Data are on the basis of dry resin content, excluding the weight of plasticizers, extenders, fillers, coloring 
agents, stabilizers or impact modifiers, unless otherwise noted. 

Data for polyvinyl acetate produced and sold in latex form includes the weight of any protective colloids which 
are used as emulsion stabilizers and form an integral part of the resin system. Production and sales do not include 
polyvinyl acetate used as a reactive intermediate for polyvinyl alcohol or other vinyl resins. 

^' Production and sales do not include polyvinyl alcohol used as a reactive intermediate for polyvinyl butyral 
or other vinyl resins, 

^^ Includes polyvinyl butyral, polyvinyl formal, polyvinyl idene chloride and other vinyl resins. 

^^ Includes coumarone-indene resins (sales only), fluorocarbon resins except PTFE, phenoxy resins, polybutylene 
type resins, and other thermoplastics materials. 

Note. — Data reported to the U.S. International Trade Commission do not necessarily coincide with that reported to 
the Society of the Plastics Industry (i.e., SPI) owing to differences in both the reporting instructions (e.g., 
polyamide resins, nylon type) and in the coverage (e.g., phenolic resins). 



SYNTHETIC ORGANIC CHEHICALS, 1974 



TABLE 2.— Plastics and resin materials for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'l 

[Plastics and resin materials for which separate statistics are given in table 1 are marked below with an 
asterisk (*) as are the urethane elastomers and certain precursors; chemicals not so marked do not appear in 
table 1 because the reported data are accepted in confidence and may not be published. Manufacturers' identi- 
fication codes shown below are taken from table 3. An x signifies that the manufacturer did not consent to his 
identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



THERMOSETTING RESINS 

Ace tone -formaldehyde resins 

*Alkyd resins; 

*Phthalic anhydride type 

*Polybasic acid type 

*Styrene-alkyd polyesters 

♦Polyester resins, unsaturated 



*Amino resins : 

*Mel amine- formaldehyde resins 

*Urea- formaldehyde resins 

*Dicyandiamide resins 

Epoxy resins: 

♦Unmodified 

•Modified 

*Furfuryl-type resins 

Glyoxal resins 

♦Phenolic and other tar acid resinS' 



♦Polyurethane and diisocyanate resins (excluding foam) 
and urethane type elastomers: 
♦Polyurethane and diisocyanate resins 

♦Urethane type elastomers 

♦Polyether and polyester polyols for urethanes 

♦Silicone resins 

Toluenesulfonamide resins 

Triazone resins 

All other thermosetting resins 



ACY, AMR, MCC, SNW . 

ACY, APT, ASH, AZS, BAL, BEN, BRU, GEL, CGL, CNE, COM, 
CPV, DAV, DEG, DSO, DUP, EW, FAR, FCD, FLW, FOG, FRE, 
FSH, GIL, GLD, GRV, HAN, IGF, JOB, JSC, KMG, KMP, 
KPT, MGG, MID, MNP, NCI, NPV, OBG, PER, PFP, PPG, PRT, 
RGI, RED, REL, RH, SCN, SED, SEY, SKT, SM, SW, x, x. 

AGY, ASH, BEN, COM, DEG, EW, FAR, FCD, FOG, GRV, 
HAN, ICF, KMG, KMP, MCC, MID, MNP, MOB, PPG, RGI, 
RED, REL, RH, SCN, SKT, SM, SW. 

APT, ASH, GEL, CGL, CPV, DSO, EW, FLW, GLD, GRV, HAN, ICF, 
JOB, MCC, MID, PPG, REL, SM, SW. 

AGS, ACY, APT, ASH, AZS, CGL, CPV, DA, DEG, DOW, DSO, 
EPC, EW, FAR, FLW, FMP, FOM, FRE, GEI , GLD, 
GRG, HAN, HKD, ICF, ICI, IPC, KMG, KPT, MGG, MFC, 
MMM, MRB, MRO, OBG, OCF, ORO, POL, PPG, PPL, RCI, 
RH, SCN. SIC, SM, SW, WLN. 

ACS, AGY, AMR, BOR, CBD, GEL, CGL, CPV, DAN, DGO, DSO, 
DUP, ENJ, FOM, GLD, GRV, HAN, ICF, JSC, KPT, MID, MON, 
MRA, PMC, PPG, PPL, QCP, RGI, REL, RH, SED, SNW, STC, 
SW, USO, VAL, WRD. 

ACS, ACY, AMR, APX, ASH, BOR, CBD, GEL, CGL, CMP, CPV, 
DAN, DUP, EFH, GAF, GLD, GOC, GP, GRV, HAN, HNC, HPC, 
HRT, JSC, KPT, MMM, MON, MRA, NTC, PC, PMC, PPG, PPL, 
RGI, REL, RH, RFC, SAC, SED, SM, SNW, SOR, SW, UNO, 
UPL, USO, VAL, X. 

GGY, ECC, JSC, MRA, RFC, S, SNW, STC, VAL. 

CEL, GGY, DOW, RCI, RSY, SHC, UCC, WLN. 

AGS, ASH, BEN, DSO, EW, GLD, GRV, HAN, HYG, ICF, JOB, 
MCC, MID, MMM, MRT, NPV, OCF, POL, PPG, RGI, REL, REZ, 
RSY, SCN, SED, SKT, SM, WLN. 

ACR, HVG, NTC, PTT, UNO, WRD. 

USO, VAL. 

ABS, ACR, ACS, AMR, ASH, BME, BOR, CBD, GBM, CGL, CLK, 
DSO, ENJ, EW, FAR, FOM, GE , GEI, GIL, GOC, GP, GRG, HER, 
HKD, HPC, HVG, ICF, INL, IRI , KND, KPT, KYN, MCA, MID, 
MMM, MON, MRB, NCI, NTC, OCF, PLS, PPG, PPL, 
PYZ, RAB, RCI, RGC, RH, RPC, SCN, SHA. SIM, SKT, 
SM, SPL, STC, SW, UCC, UNO, UPL, USR, VSV, WCA, WRD. 



APT, ARK, ASH, BAS, CEL, CGL, CPV, DSO, DUP, EW, FAR, 
FRE, GLD, GPM, ICF, ICI, JOB, KMG, MCC, MID, NfNP, MOB, 
MRT, OMC, PEL, PFP, PPG, PRT, QUN, RCI, REZ, SCN, SKT, 
SLG, SM, SW, UCC, UPJ, WTC. 

ACY, BAS, BFG, CNI , DA, DNS, DUP, EPI, HMP, INP, MMM, 
MOB, PFP, PLN. PRC, RUB, TKL, UPJ, USR, WTC. 

APT, BAS, CPV, DOW, DSO, DUP, ICI, JCG, MOB, 
OMC, RCI, UCC, UNO, UPJ, OTC, x. 

ASH, CGL, DCC, GLD, IGF, MCC, MID, PPG, SPD, SWS, UCC, VPC. 

DGO, MON. 

USO, VAL. 

CEL, GGY, DSO, EW, MCC, MID, NLC, PPG, S, SHC, SM, SNW, 
USR, VAL. 



PLASTICS 



RESIN MATERIALS 



TABLE 2.— Plastics and resin materials for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 197'I--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



THERMOPLASTIC RESINS 
♦Acrylic resins 

*Cellulosic plastics and resins 

*Coumarone-indene resins 

♦Engineering plastics: 

Acetal resins 

Polycarbonate resins 

Polyimides and amide-imide polymers 

Pol>'phenylene oxide type resins 

Polyphenylene sulfide resins 

Polysulfone resins 

Fluorocarbon resins (except PTFE) 

♦Petroleum hydrocarbon resins 

Phenoxy resins 

Polyaraide resins: 
♦Nylon type 

♦Non-nylon type 

Polybutylene and polyisobutylene resins 

♦Polyester resins, saturated 

♦Polyethylene and copolymers resins : 

♦Density 0.940 and below 

♦Density over 0.940 

♦Ethylene copolymers 

♦Polypropylene resins 

♦Polyterpene resins 

♦Poly tetrafluoroe thy lene (PTFE) 

♦Rosin modifications; 

♦Rosin and rosin esters, unmodified (ester gums)- 
♦Rosin and rosin esters, modified 

♦Styrene type plastics materials: 

♦Acrylonitrile-butadiene-styrene (ABS) resins 

♦Styrene-acrylonitrile resins (SAN) 

♦Styrene and styrene copolymer resins other than 
ABS and SAN.' 

a-Methyl styrene polymers 

Vinyl resins: 
♦Polyvinyl chloride and copolymer resins 

♦Polyvinyl acetate resins 

♦Polyvinyl alcohol resins 

Polyvinyl butyral resins 

Polyvinylidene chloride resins 

All other vinyl resins 

All other thermoplastic resins 



ACY, ASH, BAS, CHP, CPV, DSO, DUP, EFH, FLH, GLC, GLD, 
GNM, GRD, GRV, ICF, IOC, JNS, JOB, JSC, KMC, MID, 
NPV, PPG, PVI, QUN, RH, RPC, SAR, SCO, SED, SEY, SM, 
SNW, UBS, VAL, VPC, x. 

DOW, DUP, EKT, HPC, ICF. 

DUP, HPC, ICF, NEV, VEL. 

CEL, DUP. 

GE, MOB. 

ACC, DUP. 

EW, GE. 

PLC. 

UCC, VPC. 

ACS, DUP, MMM. 

DSO, EKX, ENJ, GYR, HPC, ICF, NEV, NPV, PPG, RCI, SM, 

VEL, ZGL. 
UCC, WTC. 

ACS, ALF, BCM, CEL, CTR. DBC, DGO, DUP, FG, GNM, MON, 

POL, RSN, SKP. 
AMR, CBY, COO, DSO, EMR, GNM, MCC, MON. SM, SNW. 
ENJ, WTC. 
CEL, COO, DSO, DUP, EKT, GE, GLD, GNM, ICF, ICI, MID, 

MRT, REL, RUB, VEL. 

ACS, CBN, CPX, DOW, DUP, EKX, ENJ, GOC, KPP, MON, NH'P, 

PLC, RCC, SLT, UCC, USI , UPC. 
ACC, ACS, CEL, CPX, DOW, DUP, GOC, HPC, KPP, MON, NWP, 

PLC, SLT, UCC, USI. 
DUP, EKX, USI, VPC. 

ACC, DA, EKX, ENJ, HPC, NVT, PLC, RCC, SBI, SHC. 
CBY, HPC, SCN. 
ACS, DUP, ICI. 

ASH, CBY, DPP, BM, FRP , MCC, NCI, RCI. 
ASH, CBY, DPP, FAR, FLW, FRP, GRV, ICF, MCC, NCI, RCI, 
SM, STC, SW, ZGL. 

BFG, DOW, FG, FRS, GRD, MCB, MON, RCC, USR. 
BFG, DOW, MON, SKT, UCC. 

ACC, AEP, ATR, BAS, BFG, BOR, CEL, CSD, DOW, DSO, DUP, 
FG, FIR, GAF, GNT, GOR, GRD, GYR, HLM, HPC, ICF, IOC, 

JNS, JSC, KPP, M^^^, mon, mrt, plc, pvi, rcc, rcd, rh, 

SHC, SKT, SOL, UBS, UCC, UOC, USR, USS, VEL, x. 
ACC, DOW. 

AIP, AME, BFG, BOR, CO, DA, FIR, GNT, GP, GRA, GYR, 
HN, ICF, KYS, MON, NSC, CMC, PNT, RBT, RUB, SFP, TNA, 
UCC, USR. 

AIP, BLA, BEN, BLS, BOR, CEL, CNE, DAN, DSO, DUP, FAR, 
FLH, FLW, FSH, GLC, GLD, GRD, JOB, JSC, mC, KMP, 
MCC, MMM, MNP, MON, NPV, NSC, OBC, QCP, RCI, RPC, SBI, 
SCO, SED, SH, SEY, SPC, UBS, UCC, UOC, x. 

AIP, DUP, MON. 

DUP, MON, UCC. 

BAS, BFG, DOW, GRD, MRT, UBS. 

DSO, DUP, EW, MCC, MON, RH, UCC. 

EKX, ENJ, RPC, WTC. 



132 SYNTHETIC ORGANIC CHEMICALS. 197^1 

TABLE 3.— Plastics and resin materials: Directory of manufacturers, 1974 

ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers that reported production or sales of plastics and resin materials to the U.S. International 
Trade Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ABS 


Abex Corp., Friction Products Group 


DPP 


Dixie Pine Products Co., Inc. 


ACC 


Amoco Chemical Corp. 


DSO 


DeSoto, Inc. 


ACS 


Allied Chemical Corp., Specialty Chemical Div. 


DUP 


E.I. duPont de Nemours 5 Co., Inc. 


ACR 


CPC International, Inc., Acme Resin Co. Div. 






ACY 


American Cyanamid Co. 


ECC 


Eastern Color f, Chemical Co. 


AEP 


A 5 E Plastics Pak Co., Inc. 


EFH 


E.F. Houghton 5 Co. 


AIP 


Air Products 6 Chemicals, Inc. 




Eastman Kodak Co. : 


A LP 


Allied Chemical Corp., Fibers Div. 


EKT 


Tennessee Eastman Co. Division 


AME 


Stauffer Chemical Co., Polymer West 


EKX 


Texas Eastman Co. Division 


AMR 


Pacific Resins § Chemical Co. 


EMR 


Emery Industries, Inc. 


APT 


lifhittaker Corp., Whittaker Coatings S 


ENJ 


Exxon Chemical Co. U.S.A. 




Chemical, Mol Rez Resins 


EPC 


Epoxylite Corp. 


APX 


Apex Chemical Co., Inc. 


EPI 


Eagle Richer Industries, Inc., 


ARK 


Armstrong Cork Co. 




Ohio Rubber Co. 


ASH 


Ashland Oil, Inc., Ashland Chemical Co. Div. 


EW 


Westinghouse Electric Corp., Industrial 


ATR 


Atlantic Richfield Co. 




Plastics Div., Chemical Products Plant 


AZS 


AZS Corp., AZ Products Co. Div. 










FAR 


Syncon, Inc., Farnow Div. 


BAL 


Baltimore Paint § Chemical Corp. 


FCD 


Synres Chemical Corp. 


BAS 


BASF Wyandotte Corp. 


FG 


Foster Grant Co., Inc. 


BCM 


Belding Chemical Industries 


FIR 


Firestone Tire 6 Rubber Co., Firestone 


BEN 


Bennett's 




Plastics Co. Div. 


BFG 


B.F. Goodrich Co., B.F. Goodrich Chemical 


FLH 


H.B. Fuller Co. 




Co. Division 


FLW 


Fuller-O'Brien Corp. 


BIS 


Dobbs-Life Savers, Inc. 


FMP 


PMC Corp., Industrial Chemical Div. 


BME 


Bendix Corp., Friction Materials Division 


FOC 


Handschy Chemical Co., Farac Oil 5 Chemical 


BOR 


Borden Co., Borden Chemical Co. Division 




Co. Div. 


BRU 


M.A. Bruder S Sons, Inc. 


POM 


Formica Corp. 






PRE 


Freeman Chemical Corp. 


CBD 


Chembond Corp. 


FRP 


FRP Company 


CBM 


Carborundum Co. 


FRS 


Firestone Tire § Rubber Co., Firestone 


CBN 


Cities Service Co., Plastics Div. 




Synthetic Rubber § Latex Co. Div. 


CBY 


Crosby Chemicals, Inc. 


FSH 


Insilco Inc., Frisch & Co. Div. 


CEL 


Celanese Corp. : 








Celanese Coatings 6 Specialties Co. 


GAP 


GAP Corp., Chemical Division 




Celanese Plastics Co. 


GE 


General Electric Co. ; 


CGL 


Cargill, Inc. 


GEI 


Insulating Materials Dept. 


CGY 


Ciba-Geigy Corp. 


GIL 


Gilman Paint § Varnish Co. 


CHP 


> C.H. Patrick 6 Co. 


GLC 


General Latex 6 Chemical Corp. 


CLK 


Clark Chemical Corp. 


GLD 


SCM Corp., Glidden-Durkee Division 


CMP 


Commercial Products Co., Inc. 


GNM 


General Mills Chemicals, Inc. 


CNE 


Conchemco, Inc., Chemical Coatings 


GNT 


General Tire S Rubber Co., Chemical Div. 


CNI 


Conap, Inc. 


GOG 


Gulf Oil Corp., Gulf Oil Chemicals 


CO 


Continental Oil Co. 




Co. -U.S. 


COM 


Commercial Solvents Corn. 


GOR 


Carl Gordon Indsutries, Inc., Gordon 


COO 


Coopers Polymers, Inc. 




Chemical Co. Div. 


CPV 


Cook Paint 5 Varnish Co. 


GP 


Georgia-Pacific Corp., and Rebecca Chemical 


CPX 


Chemplex Co. 




Div. 


CSD 


Cosden Oil 6 Chemical Co. 


GPM 


General Plastics Manufacturing Co. 


CTR 


Customs Resins, Inc. 


GRA 


Great American Chemical Corp. 






GRD 


W.R. Grace 5 Co., Polymers Chemicals 


DA 


Diamond Shamrock Corp. 




Division 


DAN 


Dan River, Inc. 


GRG 


P.D. George Co. 


DBC 


Dow Badische Co. 


GRV 


Guardsman Chemical Coatings, Inc. 


DCC 


Dow Coming Corp. 


GYR 


Goodyear Tire § Rubber Co. 


DEC 


Degan Oil S Chemical Co. 






DGO 


Day-Glo Color Corp. 


HAN 


Banna Chemical Coating Corp. 


DNS 


Dennis Chemical Co. 


HER 


Heresite 6 Chemical Co. 


DOW 


Dow Chemical Co. 


HKD 


Hooker Chemical Corp., Durez Division 






HLM 


U.S. Industries, Inc., E. Helman Co. Div. 






HMP 


W.R. Grace § Co., Dewey S Alray Chemical Div 



PLASTICS AND RESIN MATERIALS i^: 

TABLE 3.— Plastics and resin materials; Directory of manufacturers. 197'<— Continued 



Code 


Name of company 


Code 


Name of company 


HN 


Tenneco Chemicals, Inc. 


PLN 


Disogrin Industries Corp. 


HNC 


H 6 N Chemical Co. 


PLS 


Plastics Engineering Co. 


HPC 


Hercules, Inc. and Picco Div. 


PMC 


Plastics Manufacturing Co. 


HRT 


Hart Products Corp. 


pnt 


Pantasote Co. 


HVG 


Haveg Industries 


POL 


Polymer Corp. 


HYC 


Dexter Corp., Hysol Co. Division 


PPG 


PPG Industries, Inc. 






PPL 


Pioneer Plastics Corp. 


ICF 


Inmont Corp., ABI Div. 


PRC 


Products Research 5 Chemical Corp. , 


ICI 


ICI United States Inc. 5 Specialty Chemicals 




Chemical 5 Sealant Div. 




Div. 


prt 


Pratt 6 Lambert, Inc. 


INP 


INDOPOL 


ptt 


Petro-Tex Corp. 


INL 


Inland Steel Co., Inland Steel Container 


PVI 


Polyvinyl Chemical Ind. Div. of Beatrice 




Co. Division 




Foods Co. 


IOC 


lonac Chemical Co. Div. of Sybron Corp. 


PYZ 


Polyrez Co. , Inc. 


IPC 


Interplastic Corp. 






IRI 


Ironsides Resins, Inc. 


QCP 


Quaker Chemical Corp. 






qun 


K.J. Quinn & Co., Inc. 


JCC 


Jefferson Chemical Co. 






JNS 


S.C. Johnson S Son, Inc. 


RAB 


Rayhestos -Manhattan, Inc., Raybestos Div. 


JOB 


Jones-Blair Paint Co. 


rbt 


Robintech, Inc. 


JSC 


Jersey State Chemical Co. 


RCC 


Dart Industries, Inc., Rexene Polymers Co. 

Div. 
Richardson Co., Polymeric Septems Div. 


KMC 


Kohler-McLister Paint Co. 


RCD 


KMP 


Kelly-Moore Paint Co. 


RCI 


Reichhold Chemicals, Inc. 


KND 


Knoedler Chemical Co. 


RED 


Red Spot Paint and Varnish Co., Inc. 


KPP 


Arco/Polymers, Inc. 


REL 


Reliance Universal, Inc. S Resin Div. 


KPT 


Koppers Co., Organic Materials Division 


REZ 


Hexcel Corp., Rezolin Division 


KYN 


Kyanize Paints, Inc. 


RGC 


Rogers Corp. 


KYS 


Keysor Chemical Corp. 


RH 


Rohm § Haas Co. 






RPC 


Millmaster Onyx Corp., Refined-Onyx Division 


MCA 


Masonite Corp., Alpine Division 


rsn 


Rilsan Corp. 


MCB 


Borg-Warner Corp., Borg-Warner Chemicals 


RSY 


Resyn Corp. 


MCC 


McCloskey Varnish Co. 


RUB 


Hooker Chemical Corp., Ruco Division 


MFC 


Rockwell International Corp., Automotive 








Products Group, Resin Plant 


S 


Sandoz, Inc. 


MID 


Dexter Corp., Midland Division 


SAC 


Southeastern Adhesives Co. 


MMM 


Minnesota Mining 5 Manufacturing Co. 


SAR 


Sartomer Industries, Inc. 


MNP 


The Valspar Corp. 


SBI 


Standard Brands Chemical Industries, Inc. 


MOB 


Mobay Chemical Co. 


SCN 


Schenectady Chemicals, Inc. 


MON 


Monsanto Corp. 


SCO 


Scholler Bros., Inc. 


MRA 


Crown Metro, Inc. 


SED 


Conchemco, Inc., Colony Paint 


MRB 


Marble tte Co. 


SEY 


Seydel-Woolley 6 Co., Inc. 


MRO 


W.R. Grace f, Co., Marco Chemical Division 


SFP 


Stauffer Chemical Co., Plastics Div. 


MRT 


Morton Chemical Co. Div. of Morton-Norwich 


SH 


Stein Hall 6 Co., Inc. 




Products, Inc. 


SHA 


Shanco Plastics § Chemicals, Inc. 






SHC 


Shell Oil Co., .Shell Chemical Co. Div. 


NCI 


Union Camp Corp., Chemical Division 


SIC 


Vistron Corp., Silmar Division 


NEV 


Neville Chemical Co. 


SIM 


Simpson Timber Co., Chemical Div. 


NLC 


Nalco Chemical Co. 


SKP 


Shakespeare Co., Monofilament Division 


NPV 


Norris Paint S Varnish Co., Inc. 


SKT 


Textron Inc., Spencer Kellogg Division 


NSC 


National Starch 5 Chemical Corp. 


SLC 


Soluol Chemical Co., Inc. 


ntc 


National Casein Co. 


slt 


Soltex Polymer Corp. 


nvt 


Novamont Corp., Neal Works 


SM 


Mobil Oil Corp., Mobil Chemical Co., 


NWP 


Northern Petrochemical Co. 




Chemical Coatings Div. 






SNIV 


Sun Chemical Corp., Chemicals Division 


OBC 


O'Brien Corp. 


SOL 


Solar Chemical Corp. 


OCF 


Owens-Corning Fiberglas Corp. 


SOR 


Thomason Industries, Inc., Southern Resin 


OMC 


01 in Corp. 




Div. 


ORO 


Chevron Chemical Co. 


SPC 


Sinclair Paint Co. Div. of Insilco Corp. 






SPD 


General Electric Co., Silicone Products 


PC 


Proctor Chemical Co., Inc. 




Dept. 


PEL 


Pelron Corp. 


SPL 


Spaulding Fibre Co., Inc. 


PER 


Perry 5 Derrick Co. 






PFP 


Midwest Manufacturing Corp. 






PLC 


Phillips Petroleum Co. 







SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 3. —Plastics and resin materials: Directory of manufacturers. 1974--Continued 



Code 


Name of company 


Code 


Name of company 


STC 


Sou-Tex Chemical Co., Inc. 


USO 


U.S. Oil Co. 




SW 


Sherwin-Williams Co. 


USR 


Uniroyal, Inc., Chemical Divisior 




SWS 


Stauffer Chemical Co., SWS Silicones 


USS 


USS Chemicals Div. of U.S. Steel 


Corp. 




Division 


VAL 
VEL 


Valchem 

Veliscol Chemical Corp. 




TKL 


Thiokol Corp. 


VPC 


Mobay Chemical Corp., Verona Div 




TNA 


Ethyl Corp. 


VSV 


Valentine Sugars, Inc. 




UBS 


A.E. Staley Manufacturing Co., Staley 


WCA 


West Coast Adhesives Co. 






Chemicals Division 


WLN 


Wilmington Chemical Corp. 




UCC 


Union Carbide Corp. 


WRD 


Weyerhaeuser Co. 




UNO 


United-Erie, Inc. 


WTC 


Witco Chemical Co., Inc. 




UOC 


Union Oil Co. of California 








UPJ 


Upjohn Co. 


ZGL 


Carolina Processing Corp. 




UPL 


U.S. Plywood 








US I 


National Distillers § Chemical Corp., U.S. 
Industrial Chemicals Co. Div. 








US I 


National Petro Chemical Corp 









Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix. 



135 



RUBBER-PROCESSING^ CHEMICALS 
RUBBER-PROCESSING CHEMICALS 



Rubber-processing chemicals are organic compounds that are added 
to natural and synthetic rubbers to give them qualities necessary for 
their conversion into finished rubber goods. In this report, statis- 
tics are given for cyclic and acyclic compounds by use--such as 
accelerators, antioxidants, blowing agents, and peptizers. Data on 
production and sales of rubber-processing chemicals in 1974 are given 
in table 1. ^ 

Production of rubber-processing chemicals as a group in 1974 amounted 
to 384 million pounds, or 4.3 percent less than the 401 million pounds 
reported for 1973. Sales of rubber-processing chemicals in 1974 amounted 
to 286 million pounds, valued at $236 million, compared with 312 million 
pounds, valued at $199 million, in 1973. The decreased production of 
rubber-processing chemicals in 1974 is attributable principally to the 
decreased production of cyclic accelerators, activators, and vulcanizing 
agents. 

The production of cyclic rubber-processing chemicals in 1974 was 
325 million pounds, or about 4.1 percent less than the 338 million pounds 
reported for 1973. Sales in 1974 were 239 million pounds, valued at $206 
million, compared with 264 million pounds, valued at $176 million, in 

1973. Of the total production of cyclic rubber-processing chemicals in 

1974, accelerators, activators, and vulcanizing agents accounted for 29.6 
percent and antioxidants, antiozonants , and stabilizers for 64.4 per- 
cent. Production of antioxidants, antiozonants, and stabilizers, which 
amounted to 209.2 million pounds in 1974, included 143.8 million pounds 
of amino compounds and 65.4 million pounds of phenolic and phosphite 
compounds. Sales of amino antioxidants, antiozonants, and stabilizers 

in 1974 were 101.9 million pounds, valued at $86.5 million; sales of 
phenolic and phosphite antioxidants, antiozonants, and stabilizers, were 
43.1 million pounds, valued at $34.0 million. 

Production of acyclic rubber-processing chemicals in 1974 amounted 
to 59.2 million pounds, a decrease of 5.3 percent from the 62.6 million pounds 
reported for 1973. Sales in 1974 totaled 47.6 million pounds, valued at 
$29.8 million, compared with 48.1 million pounds, valued at $23.7 million, 
in 1973. Accelerators, activators, and vulcanizing agents accounted for 
49.6 percent of the production of acyclic rubber-processing chemicals in 
1974 and dodecyl mercaptans accounted for 39.0 percent. 



^ See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are given in table 3. 



SYNTHETIC ORGANIC CHEMICALS. 197^1 
TABLE 1, --Rubber-processing chemicals: U.S. production and sales, 1974 



[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be published. 
(Leaders (...) are used where the reported data are accepted in confidence and nay not be published or where no data 
were reported.) Table 2 lists separately all rubber-processing chemicals for which data on production and/or 
sales were reported and identifies the manufacturers of each] 



Production 



Quantity 



Grand total 

RUBBER-PROCESSING CHEMICALS, CYCLIC 



Total- 



Accelerators, activators, and vulcanizing agents, total- 

Aldehyde-amine reaction products 

Dithiocarbanic acid derivatives 

Thiazole derivatives, total 

N-Cyclohexyl-2-benzothia2olesulfenamide 

2,2'-Dithiobis(benzothiazole) 

2-Mercaptobenzothiazole 

All other thiazole derivatives 

All other accelerators, activators, and vulcanizing 
agents^ 



Antioxidants, antiozonants, and stabilizers, total 

Amino compounds, total 

Aldehyde- and acetone-amine reaction products 

Substituted p-phenylenediamines, total 

N,N'-Bis(l,4-dimethylpentyl)-p-phenylenediamine- 
N- ( 1 , 3-Dimethyl butyl ) -N ' -phenyl -p-phenyl ene- 

di amine 

N,N'-Diphenyl -p-phenyl enediamine 

All other substituted p-phenylenediaraines 

N- Phenyl -2-naphthyl amine 

All other amino compounds' 

Phenolic and phosphite compounds, total ^^- 

Phenolic compounds, total 

Polyphenolics (including bisphenols) 

Phenol , alkylated 

Phenol , styrenated 

Other 

Phosphite compounds 

Peptizers 

Retarder: N-Nitrosodiphenylamine 

All other cyclic rubber-processing chemicals" 



RUBBER-PROCESSING CHEMICALS, ACYCLIC 



Total - 



Accelerators, activators, and vulcanizing agents, total- 

Dithiocarbanic acid derivatives, total 

Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, zinc salt 

Dimethyldithiocarbamic acid, zinc salt 

All other dithiocarbamic acid derivatives 



1,000 
pounds 

383,858 



324,643 



96,175 

336 
83,518 

4,637 
20,696 

6,077 
52,108 

12,321 

209,183 



143,794 
8,727 
73,965 
6,058 

37,459 

1,796 

28,652 

3,009 

58,093 

65,389 

25,663 

13,386 

7,998 

2,094 

2,185 

39,726 

3,685 

3,496 

12,104 



29,381 



9,501 
3.849 
1,397 
2,218 
2,037 



1,000 
■pounds 

286,335 



1,000 
dollars 



236,247 



238,732 



206,474 



76,366 

1,551 

237 

65,290 
3,429 

11,519 
5,305 

45,037 

9,288 
145,008 



101,902 

7,027 

47,738 

4,997 

24,047 

1,684 

17,010 

47,137 

43,106 

18,234 

11,552 

3,727 

1,159 

1,796 

24,872 

3,536 

2,711 

11,111 



22,958 



8,061 
3,274 
1,305 
2,451 
1,031 



62,426 

2,005 

652 

47,600 
2,941 
7,507 
2,754 

34,398 

12,169 
120,437 



86,480 
4,486 

51,414 
3,682 

24,648 

2,086 

20,998 

30,580 
33,957 
21,682 
16,742 

2,373 
856 

1,711 
12,275 

2,701 

2,425 
18,485 



18,572 



8,294 
3,435 
983 
1,821 
2,055 



See footnotes at end of table. 



RUBBER-PROCESSING CflEMICALS 
TABLE 1. --Rubber-processing chemicals; U.S. production and sales^ 1974--Continued 



Product 


Production 


Sales 


Quantity 


Value 


Unit 
value' 


RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued 

Accelerators, activators, and vulcanizing agents — Con. 
Bis (dimethylthiocarbamoyl) disulfide --- 


1,000 
pounds 

12,810 
1,926 

5,144 

23,065 
3,364 

3,405 


1,000 
pounds 

10,217 
2,094 


1,000 
dollars 

5,994 
2,344 


Per 
pound 

$0.59 
1.12 


All other accelerators, activators, and vulcanizing 




20,256 8,780 


.43 
.55 


Shortstops: Dimethyldithiocarbamic acid, sodium salt 









' Calculated from rounded figures. 

^ Includes aldehyde-amine reaction products (production only), guanidines, and other uses not separately shown. 

' Includes N-phenyl-2-naphthylaniine (sales only). 

"* Includes blowing agents and other uses not separately shown. 

^ Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and 
s)'Tithetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are included in the report 
"Pesticides and Related Products," 

^ Includes xanthates, disulfides, and other thiurams. Includes data for small amounts of tetramethylthiuram 
sulfides for uses other than in the processing of natural and synthetic rubbers. 

' Includes conditioning and lubricating agents, polymerization regulators, other shortstops and physical property 
improvers . 



SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 2. --Rubber-processing chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1974 



[Rubber-processing chemicals for which separate statistics are given in table 1 are marked below with an asterisk (*) . 
Chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC 

•Accelerators, activators, and vulcanizing agents: 
•Aldehyde-amine reaction products: 

Acet aldehyde-aniline condensate 

n-Butyraldehyde-aniline condensate 

Hept aldehyde- ani line condensate 

Triethyltrimethylenetriamine 

*Dithiocarbamic acid derivatives: 

Dibenzyldithiocarbajnic acid, sodium salt 

Dibenzyldithiocarbamic acid, zinc salt 

Dibutyldithiocarbamic acid, N,N-dimethylcyclohexyl- 
amine salt. 

2,4-Dinitrophenyl dimethyldithiocarbamate 

Piperidinecarbodithioic acid, piperidinium-potassium 
salts, mixed. 
Guanidines : 

Dicatechol borate, di-o-tolylguanidine salt 

1 ,3-Diphenylguanidine 

1,3-Di-o-tolylguanidine 

*Thiazole derivatives: 

2-Benzothiazyl N,N-diethylthiocarbamoyl sulfide 

l,3-Bi5(2-benzothiazolylmercaptomethyl) urea 

N-tert-Butyl-2-benzothiazolesulfenamide 

'*N-Cyclohexyl-2-benzothiazolesulfenamide 

N,N-Diisopropyl-2-benzothiazolesulfenamide 

*2,2 '-Dithiobis(benzothiazole} 

*2-Mercaptobenzothiazole 

2-Mercaptobenzothiazole, copper salt 

2-Mercaptobenzothiazole, zinc chloride 

2-Mercaptobenzothiazole, zinc salt 

4-Moi-pholinyl-2-benzothiazyl disulfide 

N-Oxydiethylene-2-benzothiazolesulfenamide 

All other cyclic accelerators, activators, and vulcan- 
izing agents: 

p-Benzoquinonedioxime 

Bis(p-aiiiinocyclohexyl) methane carbamate 

BisCmorpholinothiocarbonyl) disulfide 

Dibenzoyl-p-quinonedioxime 

Dibenzyl amine 

N, N'-Dicinnamyli dene- 1,6-hexanedi amine 

Di-N,N'-pentaiiiethylenethiuraJn tetrasulfide 

4,4'-Dithiodimorpholine 

2-Imidazoline-2-thiol(2-lmidazolidinethione) 

m-Phenylenebismaleimide 

Poly-p-dinitrosobenzene 

Toluene-2,4-diisocyanate adduct of dimethylethanol- 

amine. 
Zinc p-toluene sulfonate 



USR. 

DUP, RCD, USR. 

USR. 

USR. 

USR. 
USR. 
MON. 

USR. 
DUP. 



DUP. 
ACY. 
ACY. 

PAS. 
LAK. 
ACY, 
ACY, 
ACY. 
ACY, 
ACY, 
ACY. 
DUP. 
ACY, 
ACY, 
ACY, 



BFG, USR, X. 
BFG, MON, USR. 



BFG, GYR, MON, USR. 
BFG, GYR, MON, USR. 



BFG, USR. 

GYR. 

BFG. 



ARA. 

DUP. 

ACY. 

ARA. 

USR, X. 

DUP. 

DUP, VNC. 

VNC, X. 

DUP, PAS, RBC. 

DUP. 

DUP. 

DUP. 

USR. 



RUBBER-PROCESSING CHEMICALS 
TABLE 2.— Rubber-processing chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197^--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC- -Continued 

* Antioxidants , antiozonants, and stabilizers: 
'Amino compounds : 

'Aldehyde- and acetone-amine reaction products: 

Aldol-a-naphthyl amine condensate 

But yraldehyde-ani line condensate 

Diphenyl amine -acetone condensate 

Phenyl- 2 -naphthyl amine- acetone condensate 

'Substituted p-phenylenediamines: 

Antidegradant 64 

Antidegradant 66 

Antidegradant 67 

*N,N' -Bi5(l,4-dimethylpentyl)-p-phenylenediamine — 
N,N'-Bis(l-ethyI-3-methylpentyl)-p-phenylene- 
diamine. 

N,N'-Bis Cl-raethylheptyl)-p-phenylenedi amine 

N-sec-Butyl-N' -phenyl -p-phenylenediamine 

N-Cyclohexyl-N'-phenyl-p-phenylenedi amine 

Diary larylenedi amines, mixed 

Diaryl -p-phenylenediamine 

N,N'-Dicyclohexyl-p-phenylenediamine 

*N-( 1,3- Dimethyl butyl)-N' -phenyl -p-phenylene- 
diamine. 

N,N'-Di-2-naphthyl-p-phenylenediamine 

*N,N'- Diphenyl -p-phenylenediamine 

N- I sopropyl-N' -phenyl -p-phenylenediamine 

N-(1-Methylheptyl)-N' -phenyl -p-phenylenediamine — 
N- (l-Methylpentyl)-N' -phenyl -p-phenylenediamine — 

Nitroso-n-phenyl -p-phenylenediamine 

All other substituted p-phenylenediamine 

Other amino compounds: 

p-Anilinophenol 

1 ,2-Dihydro-6-dodecyl-2 ,2,4-trimethylquinoline 

l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

l,2-Dihydro-2 ,2,4-trimethylquinoline 

4,4'-Dimethoxydiphenylamine 

N,N'-Diphenyle thy lenedi amine 

N,N'-Diphenyl-1 ,3-propanediamine 

N,N'-Di-o-tolylethylenediamine 

p -Hydro xydi phenyl amine 

4- Isopropoxydiphenylamine 

4, 4 '-Methy lenedi aniline 

Nonyldiphenylamine mixture (mono-, di-, and tri-)- 

Octyl diphenyl amine 

Octyl diphenyl amine, alkylated 

Octyldiphenylamine mixture (mono-, nonyl- and 
di-). 

N-Phenyl-1-naphthylamine 

*N-Phenyl-2-naphthylamine 

p- (p-Toluenesulfonaraidol)diphenylamine 

All other 

'Phenolic and phosphite compounds: 
'Phenolic compounds: 
'Polyphenolics (including bisphenols): 

Bisphenol , hindered 

4,4'-Butylidenebis{6-tert-butyl-m-cresol) 

2,5-Di-sec-butyldecylhydroquinone 

2,S-Di-(1 ,l-dimethylpropyl)hydroquinone 

3,7-Dioctylphenothiazine 

2,2'-Methylenebis(6-tert-butyl-p-cresol) 

2,2'-Methylenebis(6-tert-butyl-4-ethyl-phenol)- 
2,2'-Methylenebis[6-(l-methylcyclohexyl)-p- 
cresol] . 



BFG. 

DUP. 

ACY, BFG, USR. 

USR. 



EKT, 


USR, 


X, x. 


x. 






BFG, 


X. 




USR. 






USR, 


x. 




GYR. 






DUP. 






x. 






GYR, 


USR, 


X, X. 


BFG. 






BFG, 


DUP, 


SDC, USR 


USR. 






x. 






USR. 






USR. 







BFG, 


X. 




DUP. 






ACY, 


DA, 


RCI. 


RCI. 






Rcr. 






USR. 






BFG. 






USR. 






USR. 






ACY, 


USR 




BFG. 






DUP. 






DUP, 


UCC 




BFG, 


DUP 


USR 


USR. 






USR. 







GYR, USR. 

MON. 

USR. 

X. 

USR. 

ACY, ASH. 
ACY. 
ICI. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2. 



-Rubber-processing chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, CYCLIC--Continued 

•Antioxidants, antiozonants , and stabilizers--Continued 
•Phenolic and phosphite compounds--Continued 
• Phenolic coinpounds--Continued 

•Polyphenol ics (including bisphenols) --Continued 

2,2'-Methylenebis(6-tert-octyl-p-cre5ol) 

4,4'-Thiobis(6-tert-butyl-m-cresol) 

Thiobisphenol, alkylated 

1,1, 3-Tri (2-methyl-4-hydroxy-5-tert-butylphenyl) 

butane. 
Tris(3,5-di-t-butyl-4-hydroxybenzyl) 
isocyanurate. 
Other phenolic compounds: 

o-Cresol, alkylated 

•Phenol, alkylated 

Phenol , hindered 

•Phenol , styrenated 

N-Stearoyl-p-aminophenol 

•Phosphite compounds: 

Alkylaryl phosphites, mixed 

Nonyl phenyl phosphites, mixed 

Polymeric phosphite 

Polyphenolic phosphite, polyalkylated 

Triaryl phosphites 

Blowing agents : 

4,4' Biphenyl disulfone chloride 

4,4' Biphenyl disulfonylhydrazide 

N,N'-Dimethyl-N,N'-dinitrosoterephthalamide 

Dinitrosopentamethylenetetramine 

p,p'-Oxybis(benzenesulfonhydrazide;) 

p-Toluenesulfonylhydrazide 

p-Toluenesulfonylsemicarbazide 

•Peptizers : 

2-Benzamidothiophene, zinc salt 

2' ,2" ' -Di thi obis (ben zanilide) 

Dixylyl disulfides, mixed 

Pentachlorobenzenethiol and zinc salt 

Xylenethiol 

•Retarders : N-Nitrosodiphenylamine 

Other cyclic rubber-processing chemicals: 

p-tert-Amyl phenol sulfide (tackifier) 

4-Chloro-2,6-bis (2, 4-dihydroxybenzyl) phenol 

N-(Cyclohexyl thio)phthalimide 

Diphenyl-4,4'-diphenyl-methylene dicarbomate 

N-(2-Methyl-2-nitropropyl)-4-nitroso aniline 

Phenol cyanurate complex 

All other 

RUBBER-PROCESSING CHEMICALS, ACYCLIC 

•Accelerators, activators, and vulcanizing agents: 
•Dithiocarbaraic acid derivatives: 

Dibutyldithiocarbamic acid, nickel salt 

Dibutyldithiocarbamic acid, potassium salt 

Dibutyldithiocarbamic acid, sodium salt 

•Dibutyldithiocarbamic acid, zinc salt 

Diethyldithiocarbamic acid, cadmium salt and bis 
(diethylthiocarbamoyl) disulfide, mixture. 

Diethyldithiocarbamic acid, selenium salt 

Diethyldithiocarbamic acid, sodium salt 

Diethyldithiocarbamic acid, tellurium salt 

•Diethyldithiocarbamic acid, zinc salt 

Dimethyl ammonium- dimethyldithiocarbamate 

Dimethyldithiocarbamic acid, bismuth salt 

Dimethyldithiocarbamic acid, copper salt 



ACY. 
MON. 
USR. 
ICI. 

BFG. 



PIT. 

ACY, BFG, GYR, NEV, RCI . 

DUP, GYR, USR. 

BFG, GYR, NEV, USR. 

DA, x. 

MCB. 

NPI, USR. 
NPI. 
BFG. 
MCB. 

USR. 
USR. 
DUP. 
NPI. 
USR. 
USR. 
USR. 

ACY. 
ACY. 
PIT. 
SDC. 
DUP. 
ACY, ARA, BFG, GYR, NPI, USR. 

PAS. 
ICI. 



ICI. 
DUP, RCI. 



USR. 

VNC. 

ALC, DUP, USR, VNC. 

ALC, DUP, PAS, USR, VNC. 

VNC. 

VNC. 

PAS. 

VNC. 

ALC, GYR, PAS, USR, VNC. 

USR. 

VNC. 

VNC. 



RUBBER-PROCESSING CHEMICALS 



TABLE 2, 



-Rubber-processing chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, IQ/'J-'CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



RUBBER-PROCESSING CHEMICALS, ACYCLIC--Continued 

* Accelerators, activators, and vulcanizing agents--Con. 
*Dithiocarbamic acid derivatives — Continued 

Dimethyldithiocarbamic acid, lead salt 

Dimethyldithiocarbamic acid, selenium salt 

Dimethyldithiocarbamic acid, sodium salt and sodium 
polysulfide. 

♦Dimethyldithiocarbamic acid, zinc salt 

All other 

Thiurams : 

Bis(diethylthiocarbamoyl) disulfide 

*Bis (dimethyl thiocarbamoyl) disulfide 

*Bis (dimethyl thiocarbaraoyl 5 sulfide 

All other 

Xanthates and sulfides: 

Bis(diisopropoxythiophosphoryl) disulfide 

Di-n- butyl xantho disulfide 

Diisopropylxantho disulfide 

Zinc diisopropyl xanthate 

All other acyclic accelerators, activators, and 
vulcanizing agents: 

n-Butyraldhyde-butylamine condensate 

Di-n-butyl ammonium oleate 

3-Ethyl-l,l-dimethyl-2-thiourea 

Ethyl enediamine carbamate 

Methacrylic acid, monobasic zinc salt 

1,1,3-Trimethy 1-2 -thiourea 

Zinc o,o-di-N-butylphosphorodithioate 

Urea, modified 

All other 

Conditioning and lubricating agents: 

Alkyl alcohols, mixed 

Methyl stearyl-IO-sulfonic acid, sodium salt 

Mono- and dialkyl acid phosphates, mixed 

Mono- and dialkyl phosphate ammonium salts, mixed 

Polymerization regulators: 

Alkyl mercaptans, mixed 

*Dodecyl mercaptans 

t-Hexadecyl me reap tan 

n-Octyl mercaptan 

tert-Octyl mercaptan 

Tetradecyl mercaptan 

Tridecyl mercaptan 

Shortstops : 

Dimethyldithiocarbamic acid, potassium salt 

•Dimethyldithiocarbamic acid, sodium salt 

Other acyclic rubber-processing chemicals: 

Zinc laurate (activator, physical-property improver 
and processing auxiliary). 



VNC. 
VNC. 
BFG. 

ALC, DUP, FMN, GYR, PAS, USR, VNC. 
PAS. 

DUP, GYR, PAS. 

DUP, GYR, PAS. VNC. 

DUP, GYR, USR. 
PAS. 

DUP. 
USR. 
BFG. 
VNC. 



DUP. 

DUP. 

VNC. 

DUP. 

USR. 

RBC, VNC. 

x. 

DUP. 

MON. 

DUP. 
DUP. 
DUP. 
DUP. 

PLC. 

HK, PAS, PLC. 

PLC. 

PAS. 

PAS. 

PAS, PLC. 

PAS. PLC. 



USR. 
ALC, 



DUP, GYR, PAS, USR. 



142 SYNTHETIC ORGANIC CHEMICALS. 1974 

TABLE 3, --Rubber-processing chemicals; Directory of manufacturers^ 1974 

ALPIiABhllCAL directory BY CODE 

[Names of rubber-processing chemical manufacturers that reported production or sales to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACY 


American Cyanamid Co. 


LAK 


Lakeway Chemicals, Inc. 


ALC 


AIco Chemical Corp. 






ARA 


Arapahoe Chemicals, Inc. 






ASH 


Ashland nil. Inc., Ashland Chemical Co. 








Div. 


HCB 


Borg-Warner Corp., Borg-Wamer Chemicals 

Div. 
Monsanto Co. 






HON 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 










NEV 


Neville Chemical Co. 






NPI 


Stepan Chemical Co., Polychem Dept. 


DA 


Diamond Shamrock Corp. 






DUP 


E. 1. duPont de Nemours f, Co., Inc. 










PAS 


Pennwalt Chemicals Corp. 






PIT 


Pitt-Consol Chemical Co. 






PLC 


Phillips Petroleum Co. 


EKT 


Eastman Kodak Co., Tennessee Eastman 
Co. Div. 










RBC 


Fike Chemicals, Inc. 






Rcn 


Richardson Co. 


FMN 


FMC Corp., Agricultural Chemical Div. 


RCI 


Reichhold Chemicals, Inc. 


GYR 


Goodyear Tire 6 Rubber Co. 


SDC 


Hartin-Harietta Corp., Sodyeco Div. 


HK 


Hooker Chemicals & Plastics Corp. 


UCC 


Union Carbide Corp. 






USR 


Uniroyal, Inc., Chemical Div. 


ICI 


ICI America, Inc. 










VNC 


Vanderbilt Chemical Corp. 


Note. --Com 


plete names and addresses of the above reporting 


companies 


are listed in table 1 of the appendix.^ 



ELASTOMERS 143 



ELASTOMERS 



Elastomers (synthetic rubbers) are high polymeric materials with 
properties similar to those of natural rubber. The term "elastomers" as 
used in this report, means a substance, whether in bale, crumb, powder, 
latex, and other crude form, which can be vulcanized or similarly 
processed into a material that can be stretched to at least twice its orig- 
inal length and, after having been so stretched and the stress removed, will 
return with force to approximately its original length. U.S. production and 
sales of elastomers in 1974 are shown in table 1.^ 

Total U.S. production^ of synthetic rubber in 1974 amounted to 5,654 
million pounds, a decrease of 4 percent from that produced in 1973. Total 
sales^ of elastomers in 1974 amounted to 4,601 million pounds, a decrease of 
10 percent from that produced in 19 73. 

Styrene-butadiene rubber (SBR, or S-type rubber) in 1974 continued to 
be the elastomer produced in the greatest quantity as it has been for more 
than a quarter of a century. U.S. production of S-type rubber, including 
34 million pounds of its vinylpyridine sub-type, amounted to 3,169 million 
pounds in 1974, a decrease of 5 percent from that reported for 1973. Solu- 
tion polymerized butadiene rubber, a stereo type elastomer, was produced 
domestically in 1974 in the next largest amount--793 million pounds; pro- 
duction of isoprene and ethylene-propylene rubbers, the other stereo types, 
amounted to 188 million and 279 million pounds, respectively. Total U.S. 
production of these stereo type elastomers amounted to 1,260 million pounds 
in 19 74--a decrease of 4 percent from 1973. Other principal types of 
synthetic elastomers for which U.S. production data are reported separately 
are isobutylene-isoprene (butyl) rubber, production of which was 354 million 
pounds in 19 74, and acrylonitrile-butadiene (N-type) rubber, production of 
which was 206 million pounds. 

Sales of S-type rubber by U.S. producers in 1974 (including its vinyl- 
pyridine sub-type) amounted to 2,512 million pounds, a decrease of 12 per- 
cent from sales reported for 1973. Sales of solution polymerized butadiene 
rubber amounted to 561 million pounds, and those of ethylene-propylene 
rubber to 241 million pounds. Sales of N-type rubber in 1974 amounted to 
171 million pounds. The increase in 1974 sales over those of 1973 for the 
stereo- and N-type rubbers ranged from 3 percent for N-type to 9 percent for 
the butadiene type; the increase for the ethylene-propylene type was 6 percent. 



^ See also table 2 which lists these products and indicates the manu- 
facturers of each by code. The codes are identified by company name in 
table 3. 

^ No longer includes urethane type elastomers; for comparison purposes, 
19 73 totals were adjusted to exclude the urethane types. 



SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 1.— EusTOMERs (synthetic rubbers):' U.S. production and sales. W^ 



[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be 
published. (Leaders (...) are used where the reported data are accepted in confidence and may not be 
published or where no data were reported.) Table 2 lists all elastomers for which data on production 
and/or sales were reported and identifies the manufacturers of each] 



Grand total 

Cyclic 

Acyclic 

Acrylonitrile-butadiene type (N-type)--- 

Isobutylene-isoprene type (Butyl) 

Silicone type 

Stereo elastomers, total 

Butadiene (solution polymerized) type 

Ethylene-propylene type 

Isoprene type 

Styrene-butadiene type (S-type) 

Styrene-butadiene-vinylpyridine type 

Urethane type 

All other elastomers^ 



Production 



1,000 
Bounds 

5,655,845 



3,209,876 
2,443,969 

206,401 

353,854 

44,322 



792,886 
279,451 
187,900 

3,134,707 
34,266 

(') 



Quantity 



1,000 
pounds 

4,600,554 



2,558,478 
2,042,076 



170,596 
39,026 



561,129 
241,141 



2,491,134 
20,507 

C) 

1,077,021 



1,000 
dollars 



641,507 
887,481 



84,607 
96,858 



150,258 
81,824 



609,282 

13,090 

C") 



Unit 
value' 



pound 
$0.33 



C) 



' The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms 
which can be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least 
twice their original length and, after having been stretched and the stress removed, will return with force 
to approximately their original length. 

^ Includes oil content of oil-extended elastomers. 

' Calculated from rounded figures. 

" The data on production and sales of urethane elastomers are reported in the section Plastics and Resin 
Materials with urethane plastics and polyols. 

^ Includes production and sales data for acrylic ester, polysulfide, chloroprene, epichlorohydrin, iso- 
butylene, and butadiene emulsion elastomers, certain solution elastomers, carboxylated SBR latex, chloro- 
sulfonated polyethylene, fluorinated elastomers, thermoplastic rubber, miscellaneous elastomers, and sales 
data for the isobutylene-isoprene type and the isoprene type elastomers. 



ELASTOMERS 

TABLE 2.— Elastomers (synthetic rubbers) for which U.S. production or sales 

WERE reported, IDENTIFIED BY MANUFACTURER, W^ 



[Elastomers (synthetic rubbers) for which separate statistics are given in table 1 are marked with an asterisk 

(*}; products not so marked do not appear in table 1 because the reported data are accepted in confidence 

and may not be published. Manufacturers' identification codes shown below are taken from table 3. An x 

signifies that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



Acrylic ester type 

*Acrylonitrile-butadiene type (N-type) — 
Butadiene (emulsion polymerized) type — 

Chloroprene type (Neoprene) 

Chlorosulfonated polyethylene 

•Isobutylene-isoprene type (Butyl) 

Polyisobutylene 

Poly sulfide type 

Reaction products of natural rubber 

•Silicone tj-pe 

♦Stereo elastomers: 

♦Butadiene (solution polymerized) type- 

•Ethylene-propylene type 

*Isoprene type 

*Styrene-butadiene type (S-type) 

*Styrene-butadiene-vinylpyridine type 

All other elastomers 



ACY, 


BGF, 


DA, 


TKL. 






BFG, 


CPY, 


FRS 


GYR, 


SBI, 


USR 


BFG, 


FRS, 


GYR 


TKL, 


TUS. 




DUP, 


PTT. 










DUP. 












CBN, 


ENJ. 










EN J. 












TKL. 












GYR, 


ICI, 


X. 








DCC, 


SPD, 


sws 


UCC. 







ASY, ATR, BFG, FRS, GNT, GYR, PLC, TUS. 

BFG, CPY, DUP, ENJ, USR. 

BFG, GYR, SHC. 

ASH, ASY, BFG, CPY, FIR, FRS, GNT, GRD, GYR, 

PLC, SBI, TUS, USR. 
BFG, FIR, FRS, GNT, GYR, USR. 
ASY, BFG, DUP, HDM, MMM, PLC, PRC, SHC, UCC, WAY. 



SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 3.— Elastomers (synthetic rubbers): Directory of manufacturers. 1974 



ALPHABETICAL DIRECTORY BY CODE 

[Names of elastomers manufacturers that reported production or sales to the U.S. International Trade Commission for 
1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ACY 


American Cyanamid Co. 


ICI 


ICI United States, Inc., Specialty 


ASH 


Ashland Oil Co., Inc. 




Chemicals Group 


ASY 


American Synthetic Rubber Corp. 






ATR 


Atlantic Richfield Co. 










MMM 


Minnesota Mining and Manufacturing Co. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 










PLC 


Phillips Petroleum Co. 






PRC 


Products Research 6 Chemical Corp. 


CBN 


Cities Service Co., Columbian Group 




Chemical and Sealant Div. 


CPY 


Copolymer Rubber 5 Chemical Corp. 


PTT 


Petro-Tex Chemical Corp. 


DA 


Diamond Shamrock Corp. 


SBI 


Standard Brands Chemical Industries, Inc. 


DCC 


Dow Coming Corp. 


SHC 


Shell Oil Co.. Shell Chemical Co. Div. 


DUP 


E. I. duPont de Nemours § Co., Inc. 


SPD 


General Electric Co., Silicone Products 
Dept. 






SWS 


Stauffer Chemical Co., SWS Silicones Div. 


ENJ 


Exxon Chemical Co., U.S.A. 










TKL 


Thiokol Chemical Corp. 




Firestone Tire S Rubber Co.: 


TUS 


Texas-U.S. Chemical Co. 


FIR 


Firestone Plastics Co. Div. 






FRS 


Firestone Synthetic Rubber S Latex 








Co. Div. 


UCC 


Union Carbide Corp. 






USR 


Uniroyal, Inc., Chemical Div. 


GNT 


General Tire f, Rubber Co., Chemical Div. 






GRD 


W. R. Grace 5 Co., Polymers § Chemicals Div. 


WAY 


Philip A. Hunt Chemical Corp., Wayland 


GYR 


Goodyear Tire and Rubber 




Chemical Div. 


HDM 


Hardman, Inc. 







Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix. 



PLASTICIZERS ^'''^ 



PLASTICIZERS 



Plasticizers are organic chemicals that are added to synthetic 
plastics and resin materials to (1) improve workability during fabri- 
cation, (2) extend or modify the natural properties of these materials, 
or (3) develop new improved properties not present in the original 
material. Table 1 presents statistics on U.S. production and sales of 
plasticizers in as great a detail as is possible without revealing the 
operations of individual producers.^ 

U.S. production of plasticizers totaled 1,892 million pounds in 
1974, an increase of 1.0 percent from the 1,873 million pounds reported 
for 1973. Sales of plasticizers totaled 1,707 million pounds, valued at 
$535 million, in 1974, compared with 1,708 million pounds, valued at 
$341 million, in 1973. 

Production of cyclic plasticizers in 1974, which consisted chiefly 
of the esters of phthalic anhydride, phosphoric acid, and trimellitic 
acid, amounted to 1,411 million pounds, an increase of 1.9 percent from 
the 1,385 million pounds reported for 1973. Sales of cyclic plasticizers 
in 1974 totaled 1,306 million pounds, valued at $338 million, compared with 
1,290 million pounds, valued at $205 million, in 1973. The most important 
cyclic plasticizer was di (2-ethylhexyl) phthalate, with production of 390 
million pounds, in 1974. 

Production of acyclic plasticizers in 1974 totaled 480 million 
pounds, a decrease of 1.6 percent from the 488 million pounds reported 
for 1973. Sales of acyclic plasticizers totaled 401 million pounds, 
valued at $197 million, in 1974, compared with 419 million pounds, valued 
at $136 million, in 1973. Epoxidized soya oils were the most important 
acyclic plasticizer in 1974, with production of 127 million pounds. 



^ See also table 2 which lists these products and identifies the manu- 
facturers by codes. These codes are listed in table 3. 



1^8 SYNTHETIC ORGANIC CHEMICALS, 197^1 

TABLE 1.--Plasticizers: ' U.S, production and sales, 1974 

[Listed below are plasticizers for which any reported data on production and/or sales may be published. (Leaders (...) 
are used where the reported data are accepted in confidence and may not be published or where no data were reported.) 
Table 2 lists separately all plasticizers chemicals for which data on production and/or sales were reported and 
'identifies the manufacturers of each] 



Production 



1,000 
pounds 



Grand total 

Benzenoid 

Nonbenzenoid 

PLASTICIZERS, CYCLIC 

Total 

Phosphoric acid esters, total 

Cresyl diphenyl phosphate 

All other phosphoric acid esters'* 

Phthalic anhydride esters, total 

Dibutyl phthalate 

Diethyl phthalate 

Diisodecyl phthalate 

Dimethyl phthalate 

Dioctyl phthalates, total 

Di (2-ethylhexyl) phthalate 

Other dioctyl phthalates 

Di-tridecyl phthalate 

n-Hexyl n-decyl phthalate 

All other phthalic anhydride esters 

Trimellitic acid esters, total 

Tri-n-octyl trimellitate 

All other trimellitic acid esters 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

Total 

Adipic acid esters, total 

Di (2-ethylhexyl) adipate 

Diisodecyl adipate 

All other adipic acid esters 

Complex linear polyesters and polymeric plasticizers' 

Epoxidized esters, total 

Epoxidized linseed oil 

Epoxidized soya oils 

Octyl epoxytallates (including 2-ethyIhexyI epoxy- 

tallates) 

All other epoxidized esters 

Glyceryl monoricinoleate 

I sopropy 1 rayristate 

Isopropyl palmitate 

See footnotes at end of table. 



1,000 
pounds 

1,707,125 



1,000 
dollars 



535,247 



1,509,779 
381,906 



1,411,437 



1,389,650 
317,475 



376,968 
158,279 



338,356 



94,762 



11,084 
83,678 



1,207,331 



266,911 



35,490 
19,655 

146,662 
9,961 

395,161 

389,690 
5,471 
27,154 
10,172 

563,076 

26,250 



37,850 

14,350 

141,678 

8,931 

391,826 

386,338 

5,488 

17,581 

2,557 

509,612 

20,904 



12,430 
4,730 

32,265 
2,460 

86,579 

84,999 

1,580 

5,671 

550 

122,226 

8,816 



10,640 
15,610 



83,094 



480,248 



8,345 
12,559 



401,142 



3,507 
5,309 



22,278 



196,891 



57,807 



23,928 



40,642 

2,751 

20,784 



35,558 
2,880 
19,369 

52,544 

123,184 



13,698 
1,118 
9,112 

30,683 



5,504 
126,946 

14,937 
6,536 
108 
4.997 
7,444 



101,48 



14,117 
7,581 



7,001 
5,380 



5,694 
4,518 



5,241 
3,650 



PLASTICIZERS 
TABLE 1.--PLASTICIZERS: ' U.S, production and sales, 197^--Continued 



Quantity 



Unit 
value^ 



1,000 



PLASTICIZERS, ACYCLIC--Continued 



1,000 
poimds 



1,000 
dollars 



Oleic acid esters, total 

Butyl oleate 

Methyl oleate 

Propyl oleates (including n-propyl oleate and isopropyl 

oleate) 

All other oleic acid esters 



12,628 



Phosphoric acid esters- 
Sebacic acid esters 



Stearic acid esters, total 

n-Butyl stearate 

All other stearic acid esters- 



899 
5,811 

28,475 

7,665 

15,164 



2,865 
2,316 



431 
4,421 



Triethylene glycol di (caprylate-caprate)- 
All other acyclic plasticizers' 



7,769 
7,395 



122,583 



6,884 
6,268 



2,028 
107,849 



1,540 
1,039 



203 
2,285 



6,675 



3,057 
3,618 



1,506 
52,363 



Pey 

pound 



$0.505 



.538 
.449 



.471 
.517 



.444 
.577 



' Includes data for compounds used principally (but not exclusively) as primary plasticizers. Does not include 
clearly defined extenders or secondary plasticizers. 

^ Calculated from rounded figures. 

Includes benzenoid products as defined in part 1 of schedule 4 of the Tariff Schedules of the United States 
Annotated. 

"* Includes sales data for cresyl diphenyl phosphate, among other phosphate esters. 

^ Includes data for alkylated naphthalene, glycol dibenzoates, hydrogenated terphenyls, isopropylidenediphenoxy- 
propanol, toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. 

' Adipic acid polyesters accounted for most of the production of complex linear polyesters and polymeric 
plasticizers. 

' Includes data for azelaic, citric and acetylcitric, lauric, myristic, palmitic, polargonic, ricinoleic, and sebacic 
acid esters (sales only), glyceryl and glycol esters, and other acyclic plasticizers, not separately shown. 



SYNTHETIC ORGANIC CIIEMICALS, 1974 
TABLE 2.— Plasticizers for which [l,S, production or sales were reporteDj identified by 

MANUFACTURER, 1974 



[Plasticizers for which separate statistics are given in table 1 are marked below with an asterisk (*) ; products not 
so marked do not appear in table 1 because the reported data are accepted in confidence and may not be published. 
Manufacturers' identification codes shown below are taken from table 3. An x signifies that the manufacturer did 
not consent to his identification with the designated product] 



Manufacturers' identification code 
(according to list in table 3) 



PLASTICIZERS, CYCLIC 

Coumarone-indene plasticizers 

N-Cyclohexyl-p-toluenesulfonamide 

Dibenzyl azelate 

Dibenzyl sebacate 

Diethylene glycol dibenzoate 

Di-tert-octylphenyl ether 

Dipropanediol dibenzoate 

N-Ethyl-p-toluenesulfonamide 

Hydrogenated terphenyls 

Isopropylidenediphenoxypropanol 

Naphthalene, alkylated 

Petroleum hydrocarbon 

*Phosphoric acid esters : 

*Cresyl diphenyl phosphate 

Dibutyl phenyl phosphate 

Diphenyl octyl phosphate 

Tricresyl phosphate 

Triphenyl phosphate 

*Phthalic anhydride esters: 

Butyl benzyl phthalate 

Butyl cyclohexyl phthalate 

n-Butyl n-octyl phthalate 

Di (2-butoxyethyl) phthalate 

*Dibutyl phthalate 

Dicyclohexyl 2-ethylhexyl phthalate 

Dicyclohexyl isodecyl phthalate 

Dicyclohexyl phthalate 

Diethyl isophthalate 

'Diethyl phthalate 

Di(heptyl, nonyl) phthalate 

Difheptyl, nonyl, undecyH phthalate 

Dihexyl phthalate 

*Di isodecyl phthalate 

Diisohexyl phthalate 

Diisononyl phthalate 

Di(2-methoxyethyl) phthalate 

Dimethyl isonhthalate 

•Dimethyl phthalate 

Dinonyl phthalate 

*Dioctyl phthalates: 

Dicapryl phthalate 

Di (2-ethylhexyl) isophthalate 

*Di C2-ethylhexyl) phthalate 

Diiso-octyl phthalate 

Di -n-octyl phthalate 

Diphenyl phthalate 

*Di-tridecyl phthalate 

Diundecyl phthalate 

Glycol phthalate esters: 

Butyl phthalyl butyl glycolate 

Ethyl phthalyl ethyl glycolate 

Methyl phthalyl ethyl glycolate 

Polyester of triethylene glycol (Phthalic 

anhydride) . 
All other glycol phthalate esters 



HAL. 








WTH. 








VEL. 








DOW. 








VEL. 








MON. 








MON. 








DOW. 








ACC. 








MON. 








FMP, 


MON 


MTR 


SFS. 


MON, 


ORO 






MON. 








FMP, 


MON 


MTR 


SFS. 


EK, 


MON. 






MON. 








CPS. 








RCI, 


USS 






ARC 


HAL 






COM, 


EKT 


GRH 


MON, RUB, SW, UCC, USS. 


GRM. 








GRH. 








MON, 


PFZ 






X. 








EKT 


KF, 


MON, 


PFZ. 


MON 








MON 








USS. 








CO, 


EKT, 


ENJ, 


GRH, HN, MON, RCI, RUB, TEK, UCC, USS 


ENJ 








ENJ 


PFZ 






EKT 








PFZ. 








EKT 


KF, 


MON, 


PFZ, TCC. 


RCI 








WTH 








UCC 









BAS, BFG, CHP, CO, EKT, ENJ, GRH, HN, MON, PPL, RCI, 

TEK, UCC, USS. 
CO, ENJ, GRH, RCI, RUB, TEK, UCC, USS. 



ENJ, GRH, HN, RCI, RUB, TEK, UCC, USS. 
MON, TEK. 

MON. 
MON. 
MON. 
UCC. 

HPC. 



PLASTICIZERS 
TABLE 2.— Plasticizers for which U.S, production or sales were reported^ identified by 

MANUFACTURER^ 1974— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PUSTICIZERS, CYCLIC--Continued 

*Phthalic anhydride esters--Continued 

n-Hexyl n-decyl phthalate 

Hexyl iso-octyl phthalate 

Isobutyl cyclohexyl phthalate 

n-Octyl n-decyl phthalate 

All other phthalic anhydride esters 

Polyethylene glycol dibenzoate 

Tetrahydrofurfuryl oleate 

Toluenesulfonamide o- , p- mixtures 

*Trimellitic acid esters: 

Tri (2-ethylhexyl) trimellitate 

Tri-n-heptyl n-nonyl trimellitate 

Tri-n-hexyl n-decyl trimellitate 

Tri-n-hexyl trimellitate 

Tri-n-hexyl n-decyl trimellitate 

Triisodecyl trimellitate 

Triisononyl trimellitate 

Tri iso-octyl trimellitate 

Tri-n-octyl n-decyl trimellitate 

*Tri-octyl trimellitate 

All other trimellitic acid esters 

Trimethylpentanediol dibenzoate 

All other cyclic plasticizers 

PLASTICIZERS, ACYCLIC 

*Adipic acid esters: 

Di[2- (but oxyethoxy) ethyl] adipate 

Di(butoxyethyl) adipate 

Dicapryl adipate 

*Di (2-ethylhexyl) adipate 

Dihexyl adipate 

Diisobutyl adipate 

*Diisodecyl adipate 

Diisononyl adipate 

Diisopropyl adipate 

Dinonyl adipate 

Di iso-octyl adipate 

Dipropyl adipate 

Di-tridecyl adipate 

2- (Ethylhexyl) butoxyethyl adipate 

n-Hexyl n-decyl adipate 

n-Hexyl isodecyl adipate 

Iso-octyl isodecyl adipate 

n-Octyl n-decyl adipate 

All other adipic acid esters 

Azelaic acid esters: 

Di (2-ethylhexyl) azelate 

Di-n- hexyl azelate 

Di iso-octyl azelate 

All other azelaic acid esters 

Castor oil maleate 

Citric and acetylcitric acid esters: 

Tributyl acetyl citrate 

Trie thy 1 acetyl citrate 

Trie thy 1 citrate 

Tristearyl citrate 

Other citric and acetylcitric acid esters 

'Complex linear polyesters and polymeric plasticizers- 

Di [ (butoxyethoxy)ethoxy] methane 

Dibutyl tartrate 

Diethylene glycol dipelargonate (Dinonanoate) 

Di iso-octyl diglycolate 



CO, HN, TEK, UCC. 

PFZ. 

HON. 

RCI, TEK, UCC, USS. 

EKT, HN, MON, RUB, UCC, USS. 

VEL. 

EMR. 

MON. 

GRH, PFZ, RCI. 

MON. 

TEK. 

CO. 

TEK. 

PFZ. 

EN J. 

RCI, RUB, USS. 

GRH, RCI, RUB. 

EKT, HN, RUB, USS. 

WTH, X. 

VEL. 

HN. 



RCI, TKL. 

HAL. 

OTH. 

CO, DA, EKT, GRH, HN, MON, PFZ, PPL, RCI, RH, RUB, TEK, 

UCC, USS, WTH. 
MON. 

GRH, HAL. 

GRH, HN, PFZ, RCI, RH, RUB, UCC, USS. 
ENJ. 

VND, WTH. 
WTH. 

HN, RCI, RH. 
GRH. 
GRH. 
HAL. 

TEK, USS. 
GRH. 
GRH. 

GRH, MON, RCI, RH, RUB, USS. 
EK. 

EKT, EMR, PFZ, UCC. 

EMR. 

EMR. 

EMR. 

RH. 

PFZ. 
PFZ. 
PFZ. 
ICI. 
PPZ. 
ASH, EKT, EKX, EMR. GRH, HAL, HN, MON, PFZ, RCI, RH, 

RUB, SCP, TEK, UCC, WTC, WTH. 
TKL. 
ARC. 
EMR. 
CCA. 



SYNTHETIC ORGANIC CHEMICALS. 197^) 



TABLE 2,— Plasticizers for which U.S. production or sales were reported, identified by 

MANUFACTURER. 1974— CONTINUED 



PLASTICIZERS, ACYCLIC- -Continued 

*Epoxidized esters: 

*Epoxidized linseed oils 

*Epoxidized soya oils 

Epoxidized tall oils 

*Octyl epoxytallates : 

2-Ethylhexyl epoxytallates 

n-Octyl epoxytallates 

Octyl epoxystearates 

All other epoxidized esters 

Glyceryl tributyrate and tripropionate 

Glycol pelargonate 

Isodecyl nonanoate (Isodecyl pelargonate) 

Myristic acid esters: 

*Isopropyl myristate 

All other myristic acid esters 

♦Oleic acid esters : 

2-Butoxyethyl oleate 

*Butyl oleate 

Decyl oleate 

Glyceryl trioleate (Triolein) 

Isobutyl oleate 

*Methyl oleate 

•Propyl oleates: 

n-propyl oleate 

Isopropyl oleate 

Palmitic acid esters: 

2-Ethylhexyl palmitate 

Isobutyl palmitate 

Isohexyl palmitate 

* Isopropyl palmitate 

Pentaerythritol diisopentanoate 

•Phosphoric acid esters: 

Tri (2-butoxyethyl) phosphate 

Tri(2-chloroethyl) phosphate 

Tri C2-chloropropyl) phosphate 

Trie thy 1 phosphate 

Tri octyl phosphate 

All other phosphoric acid esters 

Ricinoleic and acetylricinoleic acid esters: 

n- Butyl acetylricinoleate 

Butyl ricinoleate 

•Glyceryl monoricinoleate 

Glyceryl tri {12-acetoxy5tearate) 

Glyceryl tri (acetylricinoleate) 

Methyl acetylricinoleat# 

Methyl ricinoleate 

All other ricinoleic and acetylricinoleic acid esters 
•Sebacic acid esters: 

Dibutoxyethyl sebacate 

Dibuty 1 sebacate 

Di(2-ethylhexyl) sebacate 

Diiso-octyl sebacate 

Di isopropyl sebacate 

Dimethyl sebacate 

•Stearic acid esters : 

Butoxyethyl stearate 

*n- Butyl stearate 

Dimethyl ammonium stearate 

Dodecyl (lauryl) stearate 

2-Ethylhexyl stearate 

Hexadecyl stearate 

2-Hydroxypropyl stearate 



Manufacturers' identification codes 
(according to list in table 3) 



ASH, SWT, VIK. 

ASH, FMP, NTL, RH, UCC , VIK, OTC. 

RH. 

UCC. 

RH, WTC. 
WTC. 

NTL, UCC. 
EKT. 

EMR, HAL. 
EMR. 

ARC, TCH, WM, IVTH. 
SBC, SCP, WTH. 

ARC, HAL. 

ARC, EMR, GRO, HAL, IVM. WTH. 

SCP, VND. 

CHL, EMR, GLY, GRO, HAL. 

DA. 

DA, EFH, EMR, GRO, HUM. 

CHL, EMR, GRO, WM. 
EMR, WM. 



™d, WTH. 






ARC. 






SBC. 






ARC, TCH, 


WM, 


WTH. 


SM. 






FMP. 






SFS. 






SFS. 






EKT. 






HN, UCC. 






SFS, UCC 






NTL. 






NTL. 






DA, GLY, 


HAL, 


NTL. 


NTL. 






NTL. 






NTL. 






NTL. 






NTL. 






HAL, RCI 






EKT, GRH 


RH, 


uss, mn. 


GRH, RCI 


RH, 


WTH. 


DA, HAL. 






WTH. 






WTH. 







ARC, ASH, CHL, DA, EMR, GRO, SCP, TCH, WM, WTH. 

RH. 

RCI. 

HAL, SCP. 

SCP. 

IVTH . 



PLASTICIZERS 



TABLE 2." 



-PlASTICIZERS for which U.S. PRODUCTION OR SALES WERE REPORTED, IDENTIFIED BY 
MANUFACTURER, 197^— CONTINUED 



Chemical 


Manufacturers' identification codes 
(according to list in table 3) 


PLASTICIZERS, ACYCLIC--Continued 
'Stearic acid e5ters--Continued 


ARC, DA. mu 

TCH. 

IVTH. 

WK. 

CHL. 

DA, SBC, SCP, WM, X. 

ARC, EKT. 

UCC. 

H.\L, PVO, RUB, m. 

UCC. 

UCC. 

EKX. 

ARC, EMR, HPC, RH, SBC, SM. 


1 - 




M th 1 






C »,■!,-.,. 


Tetraethylene glycol diC2-ethylhexanoate) 


Triethylene glycol di (2-ethylbutyrate) 


774T' rh1l^ t H'ld'' hf 


«ii' n, ^^ T ' 1 »-^-- ^° ^^^° " '^^ ^ 





^^^ SYNTHETIC ORGANIC CHEfllCALS^ 1974 

TABLE 3.--PLASTICIZERS: Directory of manufacturers, 197'I 

ALPHABETICAL DIRECTORY BY CODE 

[Names of plasticizers manufacturers that reported production or sales to the U.S. International Trade Commissi 
1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of comnany 


Code 


Name of Company 


ACC 


Amoco Chemicals Corp. : 


NEV 


Neville Chemical Co. 


ARC 


Arraak Co. i 


NTL 


NL Industries, Inc. 


ASH 


Ashland Oil, Inc., Ashland Chemical Co. Div. - 










ORG 


Chevron Chemical Co. 


HAS 


BASF Wyandotte Corp. 






BFC 


R. F. Goodrich Co., B. F. Goodrich Chemical 


PFZ 


Pfizer, Inc. 




Co. Div. 


PPL 


Pioneer Plastics Corp. 






PVO 


PVO International, Inc. 


CCA 


Interstab Chemical, Inc. 






CHL 


Chemol, Inc. 


RCI 


Reichhold Chemicals, Inc. 


CHP 


C.H. Patrick 5 Co. , Inc. 


RH 


Rohm § Haas Co . 


cn 


Continental oil Co. 


RUB 


Hooker Chemical Corp., Puco Div. 


COM 


Commercial Solvents Corp. 






CPS 


Chemical fi Pollution Sciences, Inc. 


SBC 


Scher Brothers, Inc. 






SCP 


Henkel, Inc. 


DA 


Diamond Shamrock Corp. 


SFS 


Stauffer Chemical Co., Specialty Chemical 


nnw 


Dow Chemical Co. 




Div. 






SM 


Mohil Oil Corp., Mobil Chemical Co. Div., 


EFH 


E. F. Houghton 5 Co. 




Chemical Coatings Div. 


EK 


Eastman Kodak Co. : 


SW 


Sherwin-Williams Co. 


EKT 


Tennessee Eastman Co. Div. 


SIVT 


Swift Specialty Cehmicals, Products of 


EKX 


Texas Eastman Co. Div. 




Unitech Chemical, Inc. 


EMR 


Emery Industries, Inc. 






ENJ 


Exxon Chemical Co. 


TCC 


Tanatex Chemical Corp. 






TCH 


Emory Industries, Inc., Trylon Chemicals 


FMP 


FMC Corp., Industrial Chemical Div. 




Div. 


GLY 


Glyco Chemicals, Inc. 


TEK 


Teknor Apex Co. 


GRH 


W. R. Grace S Co., Hatco Chemical Div. 


TKL 


Thiokol Chemical Corp. 


GRO 


Millmaster Onyx Corp., A. Gross 5 Co., Div. 










UCC 


Union Carbide Corp. 


HAL 


C. P. Hall Co. of Illinois 


USS 


USS Chemicals Div. of U.S. Steel Corp. 


HK 


Hooker Chemicals 5 Plastic Corp. 






m 


Tenneco Chemicals, Inc. 


VEL 


Velsicol Chemical Corp. 


UPC 


Hercules, Inc. 


VIK 


Viking Chemical Co. 


Hir 


Kraftco Corp., Humko Plastics Div. 


■ WD 


Van Dyk 5 Co. , Inc. 


ICI 


ICI United States, Inc., Specialty Chemicals 


\1\t 


Inolex Corp. 




Group 


WTC 


Witco Chemical Co., Inc. 






WTH 


Union Camp Corp., Harchem Div. 


KF 


Kay-Fries Chemicals, Inc. 






MON 


Monsanto Co. 






«1TR 


Sohin Chemicals, Inc., Montrose Chemical 
Div. 







Note . --Coinplete 



Ties and addresses of the above reporting companies are listed in table 1 of the appendix 



SURFACE-ACTIVE AGENTS ^55 

SURFACE-ACTIVE AGENTS 



The surface-active agents included in this report are organic chemicals 
that reduce the surface tension of water or other solvents and are used 
chiefly as detergents, dispersing agents, emulsifiers, foaming agents, or 
wetting agents in either aqueous or nonaqueous systems. Waxes and products 
used chiefly as plasticizers are excluded. Surface-active agents are pro- 
duced from natural fats and oils; from silvichemicals such as lignin, rosin, 
and tall oil; and from chemical intermediates derived from coal tar and 
petroleum. A major part of the output of the bulk chemicals shown in this 
report is consumed in the form of packaged soaps and detergents for house- 
hold and industrial use. The remainder is used in the processing of 
textiles and leather, in ore flotation and oil-drilling operations and in 
the manufacture of agricultural sprays, cosmetics, elastomers, foods lubri- 
cants, paints, pharmaceuticals, and many other products. 

The statistics for production and sales of surface-active agents are 
grouped by ionic class and by chemical class and subclass. All quantities 
are reported in terms of 100-percent organic surface-active ingredient and 
thus exclude all inorganic salts, water, and other diluents. Sales statis- 
tics reflect sales of bulk surface-active agents only; sales of formulated 
products are excluded. 

Total U.S. production of surface-active agents in 1974 amounted to 
4,696 million pounds, or 7.4 percent more than the 4,372 million pounds 
reported for 1973. Sales of bulk surface-active agents in 1974 amounted 
to 2,502 million pounds, valued at $746 million, compared with sales in 
1973 of 2,580 million pounds, valued at $532 million. In terms of quantity, 
sales in 1974 were thus 3.0 percent smaller than in 1973; in terms of value 
sales in 1974 were 40.3 percent larger than in 1973. 

Production of anionic surface-active agents in 1974 amounted to 3,176 
million pounds, or 67.6 percent of the total output reported for 1974 and 
7.0 percent greater than the anionic output reported for 1973. Sales of 
anionics in 1974 amounted to 1,452 million pounds, valued at $289 million. 
Of the total anionic output, 820 million pounds consisted of potassium and 
sodium salts of fatty, rosin, and tall oil acids; 693 million pounds con- 
sisted of alkylbenzenesulfonates; 994 million pounds consisted of lignin- 
sulfonates; and 234 million pounds consisted of sulfated ethers. 

Production of nonionic surface-active agents in 19 74 amounted to 
1,218 million pounds, or 25.9 percent of the total output reported for 1974 
and 8.4 percent more than the nonionic output reported for 1973. Sales of 
nonionics in 1974 amounted to 833 million pounds valued at $315 million. 
Of the total nonionic output, 261 million pounds consisted of benzenoid 
ethers; 606 million pounds consisted of alcohol ethoxylates and other non- 
benzenoid ethers; and 108 million pounds consisted of glycerol esters. 



156 



SYNTHETIC ORGANIC CHEMICALS^ 197^ 



Production of cationic surface-active agents in 1974 amounted to 284 
million pounds, or 6.0 percent of the total output reported for 1974 and 
9.0 percent greater than the cationic output reported for 1973. Sales of 
cationics in 1974 amounted to 198 million pounds, valued at $124 million. 
Of the total cationic output, 86 million pounds consisted of quaternary 
ammonium salts not containing oxygen, and 113 million pounds consisted of 
amines not containing oxygen. 

Production of amphoteric surface- active agents in 19 74 amounted to 
19.4 million pounds, or 0.4 percent of the total output reported for 19 74 
and 8.1 percent smaller than the amphoteric putput reported for 1973. 
Sales of amphoterics in 19 74 amounted to 19.2 million pounds, valued at 
$17.4 million. 

The difference between production and sales reflects inventory changes 
and captive consumption of soaps and surface-active agents by synthetic 
rubber producers, and by manufacturers of cosmetics, packaged detergents, 
bar soaps, and other formulated consumer products. In some instances the 
difference may also reflect quantities of surface-active agents used as 
chemical intermediates, e.g., nonionic alcohol and alkylphenol ethoxylates 
which may be converted to anionic surface-active agents by phosphation or 
sulfation. 



SURFACb-ACTlVE AGEIITS 
TABLE 1, --Surface-active agents; U.S, production and sales. 1974 



[Listed below are all surface-active agents for which reported data on production or sales may be published. (Leaders 

(...) are used where the reported data are accepted in confidence and may not be published or where no data were 

reported.) Table 2 lists all surface-active agents for which data on production and/or sales were reported and 
identifies the manufacturers of each] 



Production 



Quantity 



Grand total 

Benzenoid"* 

Nonbenzenoid^ 

Amphotepta Surface-Active Agents 

Total 

Anionia Surface-Active Agents 

Total 

Carboxylic acids (and salts thereof), total 

Carboxylic acids having amide, ester, or ether 

linkages 

Potassium and sodium salts of fatty, rosin, and tall 

acids, total 

Castor oil acids, potassium salt 

Castor oil acid, sodium salt 

Coconut oil acid, potassium salt 

Coconut oil acid, sodium salt 

Corn oil acid, potassium salt 

Mixed vegetable oil acids, potassium salt 

Oleic acid, potassium salt 

Oleic acid, sodium salt 

Stearic acid, potassium salt 

Tall oil acids, potassium and sodium salts 

Tallow acids, sodium salt 

All other 

Phosphoric and polyphosphoric acid esters (and salts 

thereof) , total 

Alcohols and phenol, ethoxylated and phosphated, 

total 

Mixed linear alcohols, ethoxylated and phosphated-- 

Nonylphenol, ethoxylated and phosphated 

Tridecyl alcohol, ethoxylated and phosphated 

All other 

Alcohols, phosphated or polyphosphated, total 

2-Ethylhexyl phosphate, sodium salt 

All other 

Sulfonic acids (and salts thereof), total 

Alkylbenzenesulfonates, total 

Dodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, isopropylamine salt-- 

Dodecylbenzenesulfonic acid, sodium salt 

Dodecylbenzenesulfonic acid, trietlianolamine salt- 
All other 



1,000 
pounds 



4.696.500 



1,080,767 
3,615,733 



3,175,508 



838,655 



18,965 

819,690 

130 

55 

9,851 

127,277 

246 

3,893 

1,056 

690 

18,426 

367,248 

290,818 



30,642 



21,266 
4,947 
7,443 
774 
8,102 
9,376 
182 
9,194 

1,831,610 



692,779 
165,179 

11,006 

4,249 

367,385 

10,701 
134,259 



1,000 
pounds 



;. 501. 672 



1,000 
do I lays 



625,768 
1,875,904 



19,162 



180,158 
566,240 



1,452,319 



177,384 



163,458 
126 

1,74 3 
803 
246 

3,221 
286 
396 
435 

7,514 



23,812 



54,250 



1,245 
443 
127 

3,140 
158 
207 
204 

2,944 

45,756 



13,935 



16,550 
4,660 
5,300 
666 
5,924 
7,262 
161 
7,101 

1,038,636 



9,551 
2,703 
3,022 

333 
3,493 
4,384 

103 
4,281 

131,687 



207,165 
76,051 
10,472 

5,361 
96,504 
11,504 

7,273 



55,519 
17,117 
6,661 
2,294 
24,779 
2,540 
2,128 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 1. --Surface-active agents: U.S. production and sales^ 1974--Continued 



Anionic Surfaoe-Aative Agents- -Contir\ued 

Sulfonic acids (and salts thereof) — Continued 

Benzene-, cumene-, toluene-, and xylenesulfonates, 

total 

Toluenesulfonic acid, potassium and sodium salts 

Xylenesulfonic acid, ammonium salt 

Xylenesulfonic acid, sodium salt 

All other 

Ligninsulfonates, total 

Ligninsulfonic acid, calcium salt 

All other 

Naphtha lenesulfonates 

Sulfonic acids having amide linkages, total 

Sulfosuccinic acid derivatives 

Taurine derivatives 

Sulfonic acids having ester or ether linkages, 

total 

Sulfosuccinic acid esters, total 

Sulfosuccinic acid, bis (2,6-dimethyl-4-heptyl) 

ester, sodium salt 

Sulfosuccinic acid, bis(2-ethylhexyl)ester, 

sodium salt 

All other 

Other sulfonic acids having ester or ether 

linkages 

All other sulfonic acids 

Sulfuric acid esters (and salts thereof), total 

Acids, amides, and esters, sulfated, total 

Esters of sulfated oleic acid, total 

Butyl oleate, sulfated, sodium salt 

Isopropyl oleate, sulfated, sodium salt 

Propyl oleate, sulfated, sodium salt 

All other 

Tall oil, sulfated, sodium salt 

Other acids, amides, and esters, sulfated 

Alcohols, sulfated, total 

Decyl sulfate, sodium salt 

Dodecyl sulfate salts, total 

Dodecyl sulfate, ammonium salt 

Dodecyl sulfate, sodium salt 

Dodecyl sulfate, triethanolamine salt 

All other 

Mixed linear alcohols, sulfated, ammoniimi salt 

Mixed linear alcohols, sulfated, sodium salt 

Octyl sulfate, sodium salt 

Other alcohols, sulfated 

Ethers, sulfated, total 

Alkylphenols, ethoxylated and sulfated 

Dodecyl alcohol, ethoxylated and sulfated, ammonium 

salt 

Dodecyl alcohol, ethoxylated and sulfated, sodium 

salt 

Mixed linear alcohols, ethoxylated and sulfated, 

ammonium salt 

Mixed linear alcohols, ethoxylated and sulfated, 

sodium salt 

All other 



1,000 
pounds 

70,860 

16,129 

15,107 

37,185 

2,439 

993,829 

500,165 

493,664 

7,036 

7,046 

1,989 

5,057 

48,357 
17,117 



14,374 
2,120 



31,240 
11,703 



5,121 
1,436 
213 
789 
2,633 
1,828 



20,234 

7,732 

26,023 



Quantity' Value 



33 


850 


3 


658 


2 


207 


11 


250 


98 


353 



1,000 
pounds 

57,153 

16,032 

15,142 

23,626 

2,353 

732,351 

470,914 

261,437 

6,138 

3,816 

1,666 

2,150 

26,921 
12,429 



9,996 
1,923 



14,492 
5,092 



212,487 



13,881 
4,995 
1,296 
160 
794 
2,745 
1,026 
7,860 

45,103 
360 

34,952 
5,771 

18,917 
7,656 
2,608 
1,577 

377 

7,837 

123,944 

3,523 

2,195 

11,232 



88,628 



1,000 
dollars 

10,778 

2,770 

2,618 

4,783 

607 ■ 

31,824 

12,054 

19,770 

3,202 

3,972 

1,595 

2,377 

24,340 
10,461 



13,879 
2,052 



5,658 

2,348 

479 

98 

356 

1,415 

332 

2,978 

30,012 

241 

24,173 

4,353 

12,539 

4,878 

2,403 

681 

374 

4,543 

33,295 

1,809 

615 

6,793 



5,136 
18,942 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE 1, --Surface-active agents: U.S. production and sales. 1974--Continued 



Quantity^ 



Unit 
value' 



Anionic Surfaoe- Active Agents — Continued 

Sulfuric acid esters (and salts thereof) --Continued 

Natural fats and oils, sulfated, total 

Castor oil, sulfated, sodium salt 

Cod oil, sulfated, sodium salt 

Neat's-foot oil, sulfated, sodium salt 

Sperm oil, sulfated, sodium salt 

Tallow, sulfated, sodium salt 

All other 



Other anionic surface-active agents^- 



Cationia Surface-Active Agents 
Total 



Amine oxides and oxygen-containing amines (except those 

having amide linkages), total 

Acyclic, total 

(Coconut oil alkyl)amine, ethoxylated 

(Tallow alkyl)amine, ethoxylated 

All other 

Cyclic (including imidazoline and oxazoline deriva- 
tives), total 

l-(2-Hydroxyethyl)-2-(8-heptadecenyl)-2- 

imidazoline 

1- (2-Hydroxyethyl)-2-heptadecyl-2- 

imidazoline 

l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2- 

imidazoline 

All other 

Amines and amine oxides having amide linkages, total 

Carboxylic acid - diamine and polyamine condensates, 

total 

Tall oil acids - diethylenetriamine and poly- 
alky lenepolyamine condensate 

All other 

Other amines and amine oxides having amide linkages — 



Amines, not containing oxygen (and salts thereof), 
total 

Diamines and polyamincs, total 

Imidazoline derivatives 

N- (Mixed alkyl)polyethylenepolyamine 

N-(9-0ctadecenyl)trimethylenediamine 

N- (Tallow alkyl) trimethylenedi amine 

All other 

Primary monoamines, total 

9-Octadecenylamine 

(Tallow alkyl) amine 

All other 

Secondary and tertiary monoamines, total 

N,N-Dimethyl (hydrogenated tallow alkyl)amine — 

N,N-Di methyl (mixed alkyl) amine 

N,N-Dimethyltetradecylamine 

N-Methylbis (hydrogenated tallow alkyDamine — 
All other 



1,000 
pounds 

31,584 
5,926 
2,225 
1,858 
1,327 
4,948 

15,300 

132,912 



283,834 



1,000 
■pounds 

29,559 

5,278 

1,451 

1,319 

4,653 

16,858 



1,000 
do I lars 

9,398 
2,637 

472 

459 

1,127 

4,703 



Pep 
pound 



40,886 


15,923 


15,551 


.98 


3,704 


3,086 


2,052 ! 


.66 


1,579 


1,550 


996 


.64 


35,603 


11,287 


12,503 


1.11 


6,348 


5,446 


3,433 ; 


.63 


767 


76 7 


588 


.77 


369 


348 


261 i 


.75 


1,197 


544 


505 '■■ 


.93 


4,015 


3,787 


2,079 1 


.55 


24,799 


21,885 ; 


11,624 1 


.53 



24,680 


21,812 


11,565 


53 


14,438 


13,594 


4,754 


35 


10,242 


8,218 


6,811 1 


83 


119 


73 


59 i 


81 


113.079 


66,877 


43,113 : 


64 


22,088 


18,164 


9,433 


52 


2,530 


1,487 


616 


41 


4,494 


4,308 


1,341 1 


31 


3,243 


2,733 


1,603 


59 


7,444 








4,377 


9,636 


5,873 


61 


51,287 


34,659 


21,795 


63 


6,894 


5,932 


3,343 


56 


7,534 


4,354 


2,495 


57 


36,859 


24,373 


15,957 


66 


39,704 


14,054 


11,885 


85 


4,848 








1,749 


1,749 


1,569 


90 


1,012 










653 


370 


57 


32,095 


11,652 


9,946 


86 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEfilCALS, 197^: 
TABLE 1. --Surface-active agents: U,S, production and, sales, 1974--Continued 



Cationic Surface- Active Agents — Continued 

Oxygen-containing quaternary ammonium salts 

Quaternary ammonium salts, not containing oxygen, 
total 

Acyclic, total 

Bis(hydrogenated tallow alkyl)dimethylammonium 

chloride 

All other 

Benzenoid, total 

Benzyl (coconut oil alkyl)dimethylammoniiim 

chloride 

Benzyldimethyl (mixed alkyl)ammonium chloride 

Ben zyldimethyloctadecyl ammonium chloride 

All other 

Nortionic Surface-Active Agents 

Total - 

Carboxylic acid amides, total 

Diethanol amine condensates (amine/acid ratio=2/l), 
total 

Coconut oil acids 

Coconut oil and tallow acids 

Laurie acid 

Linoleic acid 

Oleic acid 

Stearic acid 

Tall oil acids 

All other 

Diethanolamine condensates (other amine/acid 

ratios) , total 

Coconut oil acids (amine/acid ratio=l/l) 

Laurie acid (amine/acid ratio=l/l) 

Laurie and myristic acids (amine/acid ratio= 

1/1) -- - 

Oleic acid (amine/acid ratio=l/l) 

All other 

All other carboxylic acid amides 

Carboxylic acid esters, total 

Anhydrosorbitol esters 

Diethylene glycol esters, total 

Diethylene glycol distearate 

Diethylene glycol monostearate 

All other 

Ethoxylated anhydrosorbitol esters, total 

Ethoxylated anhydrosorbitol mono-oleate^ 

Ethoxylated anhydrosorbitol monostearate 

All other 

Ethylene glycol esters 

Glycerol esters, total 

Complex glycerol esters 

Glycerol esters of chemically defined acids, 

total 

Glycerol mono-oleate 

Glycerol monostearate 

All other 



1,000 
pounds 



13,199 



85,523 



68,533 

36,992 
31,541 
16,990 

121 
9,344 
1,665 
5,860 



1,217,719 



25,883 
10,628 
3,869 

50 

696 

608 

1,169 

8,863 

41,490 

21,443 

8,274 



558 
11,215 
21,751 



33,102 
1,639 

357 

1,282 

30,168 

6,743 

7,075 

16,350 

4,196 

107,660 

6,994 

32,119 
4,925 
25,676 



Quantity' 



1,000 
pounds 



75,296 



1,000 
dollars 



6,657 



60,509 

31,960 
28,549 
14,787 

113 
9,300 

528 
4,846 



55,537 



19,398 

9,171 

2,244 

707 

50 

638 

397 

432 

5,759 

30,463 

20,589 

5,041 



1,634 
5,676 



209,523 



19,681 

1,634 

555 

341 

738 

26,365 

4,626 
21,739 

3,975 
92,913 

6,073 

24,489 
3,705 
19,330 

1,454 



27,255 

11,816 
15,439 
16,702 

136 

11,557 

165 

4,844 



36,164 



12,208 

5,932 

948 

616 

31 

336 

231 

197 

3,917 

20,718 
13,034 
4,471 



1,090 
3,238 



108,323 



11,911 
862 
294 
164 
404 

14,933 

2,981 
11,952 

2,082 
47,603 

4,013 

13,260 



1,302 



Unit 
value^ 



Per 
pound 



.54 
1.13 

1.20 
1.24 
1.45 



See footnotes at end of table. 



SURFACE-ACTIVE AGENTS 
TABLE 1. --Surface-active agents: U.S. production and sales. 1974--Continued 



Production 



Quantity 



Nonionic Suyfaae-Aotive Agents — Continued 

Carboxylic acid esters — Continued 
Glycerol esters--Continued 

Glycerol esters of mixed acids, total 

Glycerol monoester of hydrogenated cottonseed 

oil acids 

Glycerol monoester of hydrogenated soybean oil 

acids 

Glycerol monoester of lard acids 

All other 

Natural fats and oils, alkoxylated, total 

Castor oil, ethoxylated 

Hydrogenated castor oil, ethoxylated 

Lanol in, ethoxylated 

All other 

Polyethylene glycol esters, total 

Polyethylene glycol esters of chemically defined 

acids, total 

Polyethylene glycol dilaurate 

Polyethylene glycol dioleate 

Polyethylene glycol monolaurate 

Polyethylene glycol mono-oleate 

Polyethylene glycol monostearate 

All other 

Polyethylene glycol esters of mixed acids, total- 
Polyethylene glycol sesquiester of coconut oil 

acids 

Polyethylene glycol sesquiester of tall oil 

acids 

All other 

Propanediol esters, total 

1 , 2-Propanediol monolaurate 

1,2- Propanediol monostearate 

All other 

Other carboxylic acid esters^ 

Ethers, total 

Benzenoid ethers, total 

Dodecyl phenol, ethoxylated 

Nonylphenol, ethoxylated 

Phenol, ethoxylated 

All other 

Nonbenzenoid ethers, total 

Linear alcohols, alkoxylated, total 

Decyl alcohol, ethoxylated 

Dodecyl alcohol, ethoxylated 

Mixed linear alcohols, ethoxylated 

Mixed linear alcohols, ethoxylated and pro- 

poxylated 

9-Octadecenyl alcohol, ethoxylated 

Octadecyl alcohol, ethoxylated 

All other 

Other ethers and thioethers, total 

Tridecyl alcohol, ethoxylated 

All other* 



1,000 
pounds 



10,8b8 

54,165 
14,773 
6,807 
5,045 
935 
1,986 
34,898 

27,988 
1,375 
6,267 
4,460 
3,073 
7,083 
5,730 
6,910 

556 

2,602 
3,952 
7,661 
158 
5,534 
1,969 
28,056 

866,44 2 



260,838 

11,382 

143,978 

4,678 

100,800 

605,604 

535,874 

2,060 

5,718 

492,205 

15,489 
2,401 
1,164 

16,837 

69,730 
9,221 

60,509 



1,000 



62,351 



11,492 
5,897 

44,962 

13,637 
6,219 
4,929 
899 
1,590 

26,093 

21,026 
1,210 
3,117 
3,767 
2,840 
5,894 
4,198 
5,067 



2,476 
2,331 
4,461 

3,634 

827 

20,764 



1,000 
dollars 



6,322 

4,313 

19,695 

5,840 

3,101 

1,898 

381 

460 

14,725 

12,387 
999 
1,552 
2,576 
1,580 
3,282 
2,398 
2,338 

209 

1,046 
1,083 
2,601 

2,094 

507 

7,766 



216,939 

10,702 

126,462 

79,775 
350,677 
291,228 

4,702 
263,694 

16,209 

2,261 

546 

3,816 

59,449 
8,272 

51,177 



75,952 

2,714 

40,324 

32,914 
94,705 
71,865 

2,364 
60,208 

4,990 

1,675 
283 

2,345 
22,840 

3,273 
19,567 



.38 



' All quantities are given in terms of 100 percent organic surface-active ingredient. 

^ Sales include products sold as bulk surface-active agents only. 

' Calculated from rounded figures. 

* The term "benzenoid," used in this report, describes any surface-active agent, except lignin derivatives, whose 
molecular structure includes 1 or more 6-membered carbocyclic or heterocyclic rings with conjugated double bonds 
(e.g., the benzene ring or the pyridine ring). 

fContinued) 



SYNTHETIC ORGANIC CHtMICALS, 1974 

Footnotes for table 1 — Continued 



Includes ligninsulfonates. 



^ nc ude production of "ail other" sulfated alcohols and other acids amides and esters. 
' Includes ethoxylated sorbitol esters, polyglycerol esters, and miscellaneous esters. 
° Includes "other" nonionic surface-active agents. 



SURFACE-ACTIVE AGENTS i63 

TABLE 2. --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER^ .197'^ 

[Surface-active agents for which separate statistics are given in table 1 are marked with an asterisk (*); products 

not so marked do not appear in table 1 because the reported data are accepted in confidence and may not be 

published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



f'anufacturers ' identification codes 
(according to list in table 3) 



Amphoteric Surfaae-Aative Agents 

Acyclic: 

Alkylbetaine 

(l-Carboxvheptadecyl)trinethyl ammonium hydroxide, 

inner salt. 
N- [ 2- (Carboxymethylamino) ethyl ] -N- C2-hydroxyethyl ) - 

coconut oil amide, sodium salt. 
(Carboxymethyl) [3- (coconut oil amido]proDyl]dimethyl- 

ammonium chloride, ammonium salt. 
(Carboxymethyl) [3- (coconut oil amido)propyl]di- 

methylammonium chloride, sodium salt. 
(Carboxymethyl) [3- (coconut oil amido)propyl]diiiiethyl- 

ammonium hydroxide, inner salt. 
(l-Carboxvtridecyl)trimethylammonium hydroxide, inner 

salt. 
(l-Carboxyundecyl)trimethylammoniuni hydroxide, inner 

salt. 
N-(Coconut oil alkyl)-B-alanine, partial sodium salt-- 

N-(Coconut oil alkyl)-R-alanine, sodium salt 

3- [(Coconut oil alkyl)amino]butyric acid, sodium 

salt. 

N-(Podecvl and tetradecyl)-6-alanine 

N-(Dodecyl and tetradecvl)-B-alanine, triethanolamine 

salt. 

N-Dodecvl-3-iminodipropionic acid 

N-riodecvl-3-iminodipropionic acid, disodium salt 

*1ixed acvclic nrimarv amines, ethoxvlated and 

sulfated, sodium salt. 

Mixed fatty betaines 

Oleic acid - ethylenediamine condensate, propoxylated 

and sulfated, sodium salt. 
N- (Tallow alkyl) -3-iminodipropionic acid, disodium 

salt. 

All other acyclic 

Cyclic: 

1 ,1- Bis (carboxymethyl) -2- (coconut oil alkyl)-2- 

imidazolinium chloride, disodium salt. 
1 , 1-Bis (carboxymethyl) -2-oleyl-2-imidazoliniuin 

chloride, disodium salt. 
1 , 1-Bis (carboxymethyl) -2-undecyl-2-imidazolinium 

chloride, disodium salt. 
1 , 1-Bis (carboxymethyl) -2-undecvl-2-imidazolinium 

hydroxide, disodium salt. 
1 -Carboxymethyl -2-heptadecy 1-1- (2-hydroxyethyl) -2- 

imidazolinium hydroxide, sodium derivative, sodium 

salt. 
l-Carhoxvnethyl-l-(2-hydroxvethyl)-2-dodecvl-2- 

imidazolinium hydroxide, sodium salt. 
1-Carboxymethyl-l- (2-hydroxyethyl) -2-nonyl -2- imid- 

azolinium hydroxide, sodium derivative, sodium 

salt. 
1 -Carboxymethyl -1- (2-hydroxvethvl)-2-undecyl-2- 

imidazolinium hydroxide, sodium derivative, 

sodium salt. 
Hentadecylmethylbenzimidazolinesulfonic acid, 

sodium salt. 
l-Hydroxyethyl-2-heptyl- 3- carboxvethyl imidazoline, 

sodium salt. 
l-Hydroxyethyl-2-undecyl-3-carboxyethylimidazoline , 

sodium salt. 



DUP. 
DUP. 



TCH. 

SNW. 

DUP. 

GW. 
CN". 
ARC. 



CN!'. 



TXT. 

s. 

GW1. 
SNW, X. 
SCP. 
SCP. 
SCP. 

BRD, MIR. 
Ml P. 

TCH. 
MIR. 



cnY. 

MOA. 
MOA. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2, --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'-|--CONTINUED 



Manufacturers' identi<'ication codes 
(according to list in table 3) 



Anionic Surfaae- Active Agents 

*Carboxylic acids (and salts thereof): 

Amine salts of fatty, rosin, and tall oil acids: 

Coconut oil acids, mono-ethanolainine salt 

Laurie, nyristic, and stearic acids, mono- 

ethanolamine salt. 

Oleic acid, n-butylamine salt 

Oleic acid, diethylamine salt 

Oleic acid, triethanolamine salt 

Rosin acid, triethanolamine salt 

Stearic acid, dimethylpropylamine salt 

Stearic acid, N,N,N'N'-tetrakis (2-hydroxyethyl) - 

ethylenediamine salt. 

Stearic acid, triethanolamine salt 

Tall oil acids, diethanolamine salt 

Tallow acids, mono-ethanolamine salt 

Tallow acids, triethanolamine salt 

•Carboxylic acids having amide, ester, or ether 

linkages : 

N-(Coconut oil acyl)polypeptide, potassium salt 

N-(Coconut oil acyl)Dolypetide, sodium salt 

N- (Coconut oil acyl)polypentide, triethanolamine 

salt. 

N- (Coconut oil acyl)sarcosine, sodium salt 

Diisobutylene - maleic anhydride copolymer, 

ammonium and sodium salts (Diisobutylene maleate) . 

Epoxidized oleic acid, ammonium salt 

N-Lauroylsarcosine, sodium salt 

Lauryl (ethyleneoxv)r)ropionic acid, sodium salt 

^-(Hixed alkylsulfonyl)glycine, sodium salt 

N-OleoylpolvTieptide, sodium salt 

N-Oleoylsarcosine , sodium salt 

N- (Undecylenic oil acyl)nolypeotide, potassium salt- 
Tridecyloxypoly(ethyleneoxy)acetic acid, sodium 

salt. 

Unspecified sarcosine derivatives 

All other 

'Potassium and sodium salts of fatty, rosin, and 

tall oil acids: 

Animal grease, sodium salt 

*Castor oil acids, potassium salt 

•Castor oil acid, sodium salt 

*Coconut oil acids, potassium salt 

*Coconut oil acids, sodium salt 

Coconut oil and tallow acids, sodium salt 

*Com oil acids, potassium salt 

Corn oil acids, sodium salt 

Laurie acid, potassium salt 

*Mixed vegetable oil acids, potassium salt 

♦Oleic acid, potassium salt 

*01eic acid, sodium salt 

Olive oil acids, sodium salt 

Palm oil acids, sodium salt 

Peanut oil acids, potassium salt 

Rosin acids, potassium salt 

Rosin acids, sodium salt 



SBP. 
SEP. 

DYS. 

IVTC. 

DA, SNW. 

ONX. 

WM. 

ICI. 

GLY. 
SOP. 
SBP. 
SBP. 



fflP. 
RH. 

SCP. 

CP, mp, 

SEY. 
CAP. 
LMI, X. 
GAP. 

X. 

MIL, STC. 

H"IP. 
CHP, BRD. 



MCP, NTL, PEK, SEA. 

HEW, NTL. 

AES, CON, DA, DYS, ESS, GRC, GRL, HEW, HNT, 

JRG, NMC, PCH, PEK, PC, PNX, SOP, VAL. 

AGP, CON, CP, GRC, HEW, JRG, LEV, NMC, NPR, PG. 
BSW. 

GRC, HNT, NMC. 

GRC, NMC. 

GAP, USR. 

AES, DYS, GRC, GRL, GYR, LUP., PCH, PEK. 

AES, ARL. DA, DAN, GYR, HNT, SCP, SNW, USR, WBG. 

BSW, DA, LUR, ™v, NMC, USR, WBG, WTC. 

HEW, HNT, LUR. 

HEW, LUR, NMC, PRX. 

KAL, SLC. 

ASY, GYR, SNW, x. 

.ASY, CRT, GYR, HRT, PRX, SLM, USR, x. 



SURFACE-AC i I VE AGENTS 



FABLE 2.- 



-Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'|--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionia Surface -Active /l3ents--Continued 

•Carboxylic acids (and salts thereof ) --Continued 
♦Potassium and sodium salts of fatty, rosin, and 
tall oil acids- -Continued 

Soybean oil acids, Dotassium salt 

Soybean oil acids, sodium salt 

♦Stearic acid, potassium salt 

Stearic acid, sodium salt 

*Tall oil acids, potassium and sodium salts: 

Tall oil acids, potassium salt 

Tall oil acids, sodium salt 

Tallow acids, potassium salt 

•Tallow acids, sodium salt 

All other 

♦Phosphoric and polyphosnhoric acid esters (and salts 
thereof) : 
♦Alcohols and phenols, ethoxylated and phosphated: 

Butyl alcohol, ethoxylated and phosphated 

Decyl alcohol, ethoxylated and phosphated 

Dinonylphenol, ethoxylated and phosphated 

Dodecyl alcohol, ethoxylated and phosphated 

Dodecylphenol , ethoxylated and phosphated 

2-Ethylhexanol , ethoxylated and phosphated 

Hexylphenol, ethoxylated and phosphated 

Isopentyl alcohol, ethoxylated and phosphated 

♦Mixed linear alcohols, ethoxylated and phosphated- - 

♦Nonylphenol , ethoxylated and phosphated 

9-Octadecenyl alcohol, ethoxylated and phosphated-- 

Octylphenol, ethoxylated and phosphated 

Octylphenol, ethoxylated and phosphated, magnesium 
salt. 

Phenol, ethoxylated and phosphated 

Polyalkylene glycol, phosphated 

Polyhydric alcohol, ethoxylated and phosphated 

Polypropylene glycol, phosphated 

♦Tridecyl alcohol, ethox>'lated and phosphated 

All other 

♦Alcohols, phosphated or polyphosphated: 

Butyl phosphate, potassium salt 

Decyl, dodecyl, and octyl phosphate, morpholine 
salt. 

♦2-Ethylhexyl phosphate, sodium salt 

2-Ethylhexyl phosphate, triethanolam.ine salt 

2-Ethylhexyl polyphosphate 

2-Ethylhexyl polyphosphate, sodium salt 

Hexyl phosphate 

Hexyl phosphate, potassium salt 

Hexyl polyphosphate, potassium salt 

Isooctyl phosphate 

Mixed alkyl phosphate 

Mixed alkyl phosphate, diethanolamine salt 

9-Octadecenyl phosphate 

Octadecyl phosphate 



DYS, PCH, PEK. 

HEW, NMC. 

CON, DA, DYS, HEW, SCO, USP, IVTC. 

DA, HEW, JRn, IVTC. 

AES, ASY, CON, DAN, DYS, ESS, GAP, GRC, GYR, HNT, 

NMC, PEK, PNX, SOP, VAL, x. 
CON, GRC, GYK, mV , PRX, SOP, UNP, x. 
AES, AGP, ASY, GYR, PG, USR. 
ASY, BSW, CON, CP, GRC, GYR, HE™, JRG, LEV, LUR, 

NMC, NPR, PG, PRX, USR. 
USR. 



GAP. 

TCH. 

ARL, GAP, MOA, TCH. 

GAP. 

GAP. 

SCP, WAY. 

CRT. 

GAP. 

BAS, CEL, CHP, CRT, CST, GAP, SEY , SNW, TCH, TXT, 

WTC. 
ARL, CHP, DEX, GAP, HDG, MOA, NLC, SCP, SEY, SOP, TCC, 

TXN, TXT, WAY, WTC. 
GAP. 
ARL, MOA, RH, WAY. 



GAP, 


MOA, 


WTC, 


X. 


BAS. 








NLC. 








LUR. 








ARL, 


GAP, 


SNW, 


TCC, mc. 


TXT, 


WTC. 






DUP. 








DUP. 








CHP, 


HP.A , 


SEY, 


ucc. 


MIL. 








X. 








X. 








ICl. 








ICI. 








DEX. 








GAP. 








DUP, 


SPS, 


TCC, 


WTC. 


DUP. 









SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2. 



-Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974— CONTI NUED 



Anionic Suffaoe-Aativs Agents — Continued 

'Phosphoric and polyphosphoric acid esters (and salts 
thereof) --Continued 
*Alcohols, phosphated or polyphosphated--Continued 

Octyl phosphate 

Octyl phosphate, alkylamine salt 

Octyl phosphate, potassium salt 

Octyl polyphosphate 

Octyl polyphosphate, potassium salt 

Oleyl phosphate 

All other 

♦Sulfonic acids (and salts thereof): 
*Alkylbenzenesulfonates : 
*Podecylben2enesulfonates : 

*nodecylbenzenesulfonic acid 

Dodecylbenzenesulfonic acid, ammonium salt 

Dodecylbenzenesulfonic acid, butylamine salt 

♦Dodecylbenzenesulfonic acid, calcium salt 

Dodecylbenzenesulfonic acid, dimethylamine salt-- 

Dodecylbenzenesulfonic acid, isopropanol amine 
salt. 

♦Dodecylbenzenesulfonic acid, isopropylamine salt- 

Dodecylbenzenesulfonic acid, (mixed alVyl)amine 

salt. 

Dodecylbenzenesulfonic acid, potassium salt 

♦Dodecylbenzenesulfonic acid, sodium salt 



♦Dodecylbenzenesulfonic acid, triethanolamine 
salt. 
♦Other alkylbenzenesulfonates : 

Didodecylbenzenesulfonic acid 

Didodecylbenzenesulfonic acid, sodium salt 

Pentadecylbenzenesulfonic acid, potassium salt 

Tridecylbenzenesulfonic acid 

Tridecylbenzenesulfonic acid, ammonium salt 

Tridecylbenzenesulfonic acid, calcium salt 

Tridecylbenzenesulfonic acid, sodium salt 

Undecylhenzene sulfonic acid 

Undecylbenzenesulfonic acid, ammonium salt 

Undecylbenzenesulfonic acid, isopropylamine salt- 

Undecylbenzenesulfonic acid, sodium salt 

Undecylbenzenesulfonic acid, triethanolamine 
salt. 

All other 

♦Benzene-, cumene- , toluene-, and xylenesulfonates : 

Allylsulfonic acid, sodium salt 

Cumenesulfonic acid, ammonium salt 

Cumenesulfonic acid, sodium salt 

♦Toluenesulfonic acid, potassium and sodium salts: 

Potassium salt 

Sodium salt 



Manufacturers' identification codes 
(according to list in table 3) 



TXT, li/TC. 

DUP, NLC, TXN, TXT. 

DUP. 

DEX. 

X. 

DUP. 

BRD, qCP, l«TC, X. 



ATR, BLA, Cn, CRT, CTL, EMK, LAK, LEV, MON, PIL, PLX, 

PRX, RCD, STP, TCI, TEN, tVTC. 

ARL, HLT, STC. 
WTC. 

ICI, NLC, RCD, RH, STP, TMH, WTC. 
PIL. 

CTL, SNW. 

CHP, CIN, CTL, ICI, RCD, STP, TCH, WTC. 
ECC, NLC. 

STP, VAL. 

.AAC, ARD, ARL, ATR, BLA, CEL, CO, CP, CRT, 

CTL, DA, DEP, ECC, HLI , LEV, NMC, PG, PIL, PLX, 

PRX, QCP, RCD, SEY, SOP, STP, TEN, UCC, 

WTC. 
AAC, ARD, ARL, ATR, CTL, ECC, ESS, HLI, PEK, 

PIL, RCD, SOP, SOS, STP, IVTC. 

CO, \nc. 

ATR. 

STP. 

CO, RCD, TXT, OTC. 

TXT. 

IVTC. 

BLA, CP, NPR, PC, RCD, WTC. 

T.XT. 

TXN, TXT. 

TXT. 

TXN, TXT. 

TXN, TXT. 

TXT, USR. 



NES, PRX, STP, WTC. 
NES. 



NES, STP, TXN, WTC. 
CO, NES, WTC. 



SURFACE-ACTIVE AGENTS 



TABLE 2. --Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 197i(--CONTI NUED 



Anionic Surface-Active Agents- -Continued 

•Sulfonic acids (and salts thereof^) --Continued 

*Benzene-, cumene-, toluene-, and xylenesulfonates-- 
Continued 

*Xylenesulfonic acid, ammonium salt 

*Xylenesulfonic acid, sodium salt 

*Ligninsulfonates : 

Ligninsulfonic acid, ammonium salt 

*Ligninsulfonic acid, calcium salt 

Ligninsulfonic acid, chromium salt 

Ligninsulfonic acid, iron salt 

Ligninsulfonic acid, magnesium salt 

Ligninsulfonic acid, mixed salts 

Ligninsulfonic acid, potassium salt 

Ligninsulfonic acid, sodium salt 

Ligninsulfonic acid, zinc salt 

*Naphthalenesulfonates : 

Butyl naphthalene sulfonic acid 

Butylnaphthalenesulfonic acid, sodium salt 

Dibutylnaphthalenesulfonic acid 

Didodecylnaphthalenesulfonic acid, sodium salt 

Diisopropylnaphthalenesulfonic acid, sodium salt 

Dipentylnaphthalenesulfonic acid, (mixed alkyl)- 
amine salt. 

Dipentylnaphthalenesulfonic acid, sodium salt 

Isopropylnaphthalenesulfonic acid 

Methylenebis (2-naphthalene5ulfonic acid) 

Methylnaphthalenesulfonic acid, sodium salt 

Tetrahydronaphthalenesulfonic acid, sodium salt 

•Sulfonic acids having amide linkages: 
*Sulfosuccinic acid derivatives: 

N-(l ,2-Dicarboxyethyl)-N-octadecylsulfosuccinamic 

acid, tetrasodium salt. 
N- (2-Hydroxyethyl)-N-(undecyl)sulfosuccinamic 
acid, disodium salt. 

N-Octadecylsulfosuccinamic acid, disodium salt 

N-(nieoyloxyisopropyl)sulfosuccinamic acid, 

disodium salt. 
Sulfosuccinic acid, alkanolamide ester, sodium 

salt. 
Sulfosuccinic acid, alkanolamide ester, tri- 

ethanolamine salt. 
Sulfosuccinic acid, 2- (coconut oil amidolethyl 
ester, disodium salt. 
•Taurine derivatives : 

N- (Coconut oil acyl)-N-methyl taurine, sodium salt- 

N-Cyclohexyl-\-palmitoyltaurine, sodium salt 

N-Methyl-N-oleoyltaurine, sodium salt 

N-Methyl-N-palmitoyltaurine, sodium salt 

N-Methyl-N-(tall oil acyl)taurine, sodium salt 

•Sulfonic acids having ester or ether linkages: 
•Sulfosuccinic acid esters: 

•Sulfosuccinic acid, bis(2,6-dimethyl-4-heptyl) 

ester, sodium salt. 
•Sulfosuccinic acid, bis(2-ethylhexyl) ester, 
sodium salt. 



Manufacturers' identification codes 
(according to list in table 3) 



CO, NES, STP, TXN, WTC. 

Cn, ICI, NES, PIL, PRX, SDC, STP, TXN, IVTC. 



CPP, CRZ 


SPA. 






CRZ, CWP 


LKY, 


MAR, 


PSP. 


MAR, PSP 


RAY. 






CRZ, PSP 








MAR, SPA 








MAR, SPA 








SPA. 








CRZ, MAR 


PSP, 


RAY, 


SPA, W\'A 


PSP. 








DA, ECC. 








DA. 








GAP, S. 








PFZ. 








DA, PFZ. 








NLC. 








CGY. 








DA, DUP, 


GRD. 






DUP. 








DA, UDI. 








DUP. 








ACY, MOA. 








ARD. 








ACY. 








WTC. 








HDG, SCP. 








SCP. 








I.\K. 








GAF, LIL, 


TNI. 






GAF. 








DA, GAF, 


HRT. 






GAF. 








CRT, GAF, 


MRA, 


X. 





DAN, ECC, GAF, MOA. 



ACY, CGY, CHP, CRT, CST, DA, DAN, EMK, HDG, 
HRT, MCP, MOA, MRA, PC, SCO, WTC. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2. 



-Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--CONTINUED 



Anionic Surface-Active 4f7e)its--Continued 

•Sulfonic acids (and salts thereof)--Continued 
♦Sulfonic acids having ester or ether linkages- - 
Continued 
*Sulfosuccinic acid esters--Continued 

Sulfosuccinic acid, bis (tallow monoglyceride) 
ester, sodium salt. 

Sulfosuccinic acid, dihexyl ester, sodium salt 

Sulfosuccinic acid, diisodecyl ester, sodium 

salt . 
Sulfosuccinic acid, diisooctyl ester, sodium 
salt. 

Sulfosuccinic acid, dipentyl ester, sodium salt 

Sulfosuccinic acid, ditridecyl ester, sodium 

salt. 
Sulfosuccinic acid, monolauryl ester, sodium salt-- 
*nther sulfonic acids having ester or ether 
linkages : 
Coconut oil acids, 2-sulfoethyl ester, sodium 

salt. 
Dodecyldiphenyloxidedisulfonic acid, disodium 
salt. 

Dodecyl sulfoacetate, sodium salt 

Glycerol monostearate sulfoacetate, sodium salt 

Herring oil, sulfonated, sodium salt 

Iso-octylphenol, ethoxylated and sulfonated, 
sodium salt. 
n-Octylphehol , ethoxylated and sulfonated, sodium 
salt. 

All other 

*A11 other sulfonic acids: 

But ylhydroxybiphenyl sulfonic acid 

Mixed alkanesulfonic acid, sodium salt 

Mixed alpha olefin, sulfonic acid, sodium salt 

Petroleumsulfonic acid, water soluble (acid layer), 
sodium salt. 
♦Sulfuric acid esters (and salts thereof) : 
♦Acids, amides, and esters, sulfated: 

Coconut oil acids - ethanolamine condensate, 
sulfated, potassium salt. 
♦F.sters of sulfated oleic acid: 

2-Rutoxyethyl oleate, sulfated, sodium salt 

♦Butyl oleate, sulfated, sodium salt 

2-Hthylhexyl oleate, sulfated, sodium salt 

Glyceryl trioleate, sulfated, sodium salt 

Isohutyl oleate, sulfated, sodium salt 

♦Isoprooyl oleate, sulfated, sodium salt 

Methyl oleate, sulfated, sodium salt 

♦Propyl oleate, sulfated, sodium salt 

Oleic acid, sulfated, disodium salt 

nieic acid, sulfated, sodium salt 

Other acids, amides, and esters, sulfated: 

Glycerol monoester of coconut oil acids, sulfated 
sodium salt. 



Manufacturers' identification codes 
(according to list in table 3) 



ACY, MOA. 
MCP. 



ACY. 
ACY, MOA. 



GAF, LFV, X. 



STP. 
i«TC. 
SLM. 



CRT. 
SLM. 



RBC. 

DUP. 

CP, LAK, NLC, STP, TXT. 

IVTC. 



DFX, EMK. 



AKS, CIN, CRT, EFH, ICI, MCP, PC. 

CHP. 

MRV. 

DA. 

CRT, DFX, HRT, LFA, SCP . 

ICI. 

ACY, AKS, CHP, MCP, MRV. 

ACT, ACY, DA, GAF, LFA, SCO, TEN. 

WHI. 

CP. 



SURFACE-ACTIVE AGENTS 



TABLE 2. 



--Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 197^I--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



Anionic Surface- Active Agents — Continued 

•Sulfuric acid esters (and salts thereof) --Continued 
*Acids, amides, and esters, sulfated- -Continued 

Other acids, amides, and esters sulfated- -Continued 
*Tall oil, sulfated, sodium salt 

All other 

*Alcohols, sulfated: 

Coconut and sperm oil alkyl sulfate, sodium salt 

Decyl and octyl sulfate, sodium salt 

*Decyl sulfate, sodium salt 

3,9-Diethyl-6-tridecyl sulfate, sodium salt 

*Dodecyl sulfate salts: 

2-Amino-2-methylpropanol salt 

* Ammonium salt 

Diethanolamine salt 

N,N-Diethylcyclohexyl amine salt 

Isopropanolamine salt 

Magnesium salt 

Potassium salt 

♦Sodium salt 

*Triethanolamine salt 

2-Ethylhexyl sulfate, sodium salt 

7-Ethyl-2-methyl-4-undecyl sulfate, sodium salt 

Hexadecyl and 9-octadecenyl sulfate, sodium salt 

Hexadecyl sulfate, sodium salt 

Hexyl sulfate, potassium salt 

Lauryl alcohol sulfate, diethylamine, sodium salt — 

Lauryl alcohol sulfate, sodium salt 

Lauryl alcohol sulfate, triethanolamine salt 

♦Mixed linear alcohols, sulfated, ammonium salt 

Mixed linear alcohols, sulfated, diethanolamine 

♦Mixed linear alcohols, sulfated, sodium salt 

Mixed linear alcohols, sulfated, triethanolamine 
salt. 

Nonyl sulfate, sodium salt 

Octadecyl sulfate, sodium salt 

♦Octyl sulfate, sodium salt 

Oleyl sulfate, sodium salt 

Tridecyl sulfate, sodium salt 

All other 

♦Ethers, sulfated: 

♦Alkylphenols, ethoxylated and sulfated: 

Iso-octylphenol, ethoxylated and sulfated, sodium 

salt. 
1-Nanhthol, ethoxylated and sulfated, sodium salt- 
Nonylphenol , ethoxylated and sulfated, ammonium 

salt. 
Nonylphenol, ethoxylated and sulfated, sodium 

salt. 
Nonylphenol, ethoxylated and sulfated, tri- 
ethanolamine salt. 
♦Dodecyl alcohol, ethoxylated and sulfated, 

ammonium salt. 
♦Dodecyl alcohol, ethoxylated and sulfated, 
sodium salt. 
Dodecyl and tetradecyl alcohols, ethoxylated 
and sulfated, ammonium salt. 

2-Hexyloxyrropyl sulfate, sodium salt 

♦Mixed linear alcohols, ethoxylated and sulfated, 

ammonium salt. 
♦Mixed linear alcohols, ethoxylated and sulfated, 
sodium salt. 



ACT, APX, BAO, CHP, CRT, DA, ICI, SEA, WHI , WW, 

KTC. 
DA, DUP, EMR, SCO. 



TCH. 

APX, CTL, HLI, SCP. 

UCC. 



A^C, 
DUP, 
DUP. 
JRG, 
AAC, 
GYR, 
AAC, 
AAC, 
AAC, 
UCC. 
SCP. 
AAC, 
DEX. 
AAC. 
SEY. 
SEY. 
LAK, 
TXT. 
LAK, 
LAK, 



CTL, HLI, JRG, ONX, PG, SCP, STP, TCH. 

HLI, JRG, SCP, STP. 

TCH. 

HLI, ONX, STP. 

PG. 

CTL, DUP, HLI, JRG, ONX, SCP, STP, TCH. 

CTL, DUP, HLI, ONX, SCP, -STP, TCH. 

TCH, UCC. 



NTL, RCD, S, SCP, TXT, UCC, WTC. 



PG, RCD, SCP, TXT. 
PG, SCP, TXT. 



TEN. 

DUP, EMK, ONX, PG. 

AAC, DUP, WTC. 

DUP. 

AAC, SCP. 

DA, HLI, LEV, SW. 



TCH. 
CGY, STP. 



CRT, DEX, GAP. 

ARL. 

AAC, AKS, CTL, HLI, STP. 

AAC, CTL, HLI, ONX, SCP, STP, TCH. 

LEV . 

S. 

CO, LAK, PG, PIL, RCD, SCP, SHC, STP, TXN, TXT, WTC. 

AAC, CO, DA, GAP, PG, PIL, RCD, SCP, 
SHC, STP, TCI, TXT, WTC. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 2. 



--Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--CONTINUED 



.'.nionio Surface-Active Agents-- Continuec' 

•Sulfuric acid esters Cancl salts thereof--Continue'1 
•Ethers, sulfated--Continued 

Tridecyl alcohol, ethoxvlated and sulfated, 

amFionium salt . 
Tridecyl alcohol, ethoxvlated and sulfated, sodium 
salt. 
•Natural fats and oils, sulfated: 

•Castor oil, sulfated, sodium salt 

Coconut oil, sulfated, sodium salt 

•Cod oil, sulfated, sodium salt 

Grease, other than wool, sulfated, sodium salt 

Herring oil, sulfated, ammonium salt 

Herring oil, sulfated, sodium salt 

Lard, sulfated, sodium salt 

Mixed alpha olefins and vegetable oils, sulfated, 

sodium salt . 
Mixed animal and vegetable oils, sulfated, sodium 
salt. 

Mixed fish oils, sulfated, sodium salt 

Mixed vegetable oils, sulfated, sodium salt 

Mustard seed oil, sulfated, sodium salt 

*Neat's-foot oil, sul<^ated, sodium salt 

Peanut oil, sulfated, sodium salt 

Pecan oil, sulfated, sodium salt 

Ricebran oil, sulfated, sodium salt 

Soybean oil, sulfated, sodium salt 

•Sperm oil, sulfated, sodium salt 

♦Tallow, sulfated, sodium salt 

Other anionic surface-active agents: 

Lignin, sodium salt 

Mixed linear alcohols, ethoxylated and carbonated, 

sodium salt. 
Polyethylene-vinyl alcohol copolymer, potassium salt — 
Tridecyl alcohol, ethoxylated and carbonated, 

sodium salt . 
All other 

Cationic Surfaae-Aotive Agents 

•Amine oxides and oxygen- containing amines (except 
those having amide linkages): 
•Acyclic: 

N,N-BisC2-hydroxvethyl) (coconut oil alkyl)amine 
oxide. 

N,N-Bis(2-hydroxve thy l)octadecyl amine 

N,N-BisC2-hvdroxyethyli (tallow alkyl) amine 

N,N-Bis(2-hydroxvethyl) (tallow alkyl^amine oxide 

•(Coconut oil alkyl)amine, ethoxylated 

(Coconut oil alkvl)amine, ethoxylated, acetate 

(Coconut oil alkyl)amine, ethoxvlated, maleate 

N,N-Dimethyl (coconut oil alkvl)amine oxide 

M,N-nimethyldie thy 1 amine oxide 

N.N-Dimethyldodecvlamine oxide (Lauryl dimethylamine 
oxide) . 

N,N-Dimethylhexadecyl amine oxide 

N,N-Dimetbyl(hydrogenated tallow alkyl)amine oxide — 

N,N-Dimethylmyristyl amine oxide 

Ethylenediamine, ethoxylated and propoxylated 



Manufacturers' identification codes 
(according to list in table 3} 



PRX. 
AAC, ARL. 



ACT, ACY, AKS, AFX, ARL, BAO, CRT, DA, DEX , 
GAP, HRT, ICl, KAL, KNG , LEA, LUR, MRD, MRV, 
S, SCO, SCP, SLM, IVHW. 

ACY, BAG, DA, LUR, MRD. 

ACT, BAO, SEA, IVHI, WHW. 

SEA, WHI. 

SCP. 

DA, SLM, raiW. 

CRT, WAW, vm. 

SLM. 



SLM 



ACT, DA, MRD, SLM. 
LUR, SEY. 
DA. 

ACT, BAO, DA, KAL, LUR, MRD, PC, SEA, SLM 
ACY, LUR, SLC. 
CRT. 

DA, KN1, SEA. 
ACT, HRT, ONX. 
ACT, BAO, DA, KAL, LEA 
ACT, ACY, DA, ECC , LU" 
SOS, Mil. 



MRD, ONX, SCO, SEA, WHI, IVHW. 
MCP, MRD, PC, SID, SLM, 



W\'A. 



NLC. 
S. 



ARC. 

ARC, FIN, TCH. 

ARC, SBC. 

ARC. 

ARC, ASH, B^D, ICI , NLC, TCH. 

RPC. 

SDH. 

ARC. 

BRD. 

BRD, X. 

ONX. 
ARC. 
BPD. 
ICI. 



SURFACE-ACTIVE AGENTS 



TABLE 2, 



-Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 197^--C0NTINUED 



^^anufacturers ' identification codes 
(according to list in table 3) 



Cationia Surface-Active /43ents--Continued 

*Amine oxides and oxygen- containing amines Cexcent those 
having amide linkages) — Continued 
*Acyclic- -Continued 

N-(2-Hydroxyethyl)-N,N' ,N' -tris (2-hvdroxyp^onyl)- 
ethylenediamine. 
N- (2-Hydroxyethyl)-N,N' ,N' -tris (2-hydroxyDrooyl) - 
ethylenediamine distearate, methyl sulfate. 

(Mixed alkyl)amine, ethoxylated 

("ixed alkyl)r)oly(oxye thy lene) amine 

Mixed substituted oximes 

(9-0ctadecenyl)amine, ethoxylated 

Octadecyl amine , ethoxylated 

N ,N-01eyl amine oxide 

Polyethylenepolyamine, alkoxylated 

(Soybean oil alkyl)amine, ethoxylated 

*(Tallow alkyl)amine, ethoxvlated 

Tallow alkyl amine ethoxylated, sulfate 

N- (Tallow alkyl)trimethylenediajnine, ethoxvlated 

N,N,N' ,N'-Tetrakis (2-hydroxyethyl) ethylenediamine 

N,N,N' ,N'-Tetrakis (2-hydroxypropyl) ethylenediamine 

dioleate, methyl sulfate. 
N,N,N ' ,N'-Tetrakis (2-hydroxypropyl) ethylenediamine , 
propoxvlated and ethoxylated. 

Trie thanol amine, ethoxylated 

All other 

*Cyclic (including imidazoline and oxazoline 
derivatives) : 

Aniline, ethoxylated 

Lignin amines 

Rosin amine, ethoxylated 

m-Toluidine, ethoxvlated 

All other 

Imidazoline and oxazoline derivatives; 

1- (2-Aminoethyl)-l,2-distearvHiTiidazoline 

2- (8-Hentadecenyl)-4,4-bis (hydroxymethvl) -2- 

oxazoline. 
2- (8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2- 

oxazoline. 
*l-(2-Hydroxyethyl)-2- (8-heptadecenyl)-2-imidazoline- 
1- (2-Hydroxyethyl)-2-hentadecyl-4-carboxyethyl- 
imidazoline. 

*1- (2-Hydroxyethyl) -2-heptadecyl-2-imidazoline 

1- (2-Hydroxyethyl) -2-hexyl-4-carboxyethyl- 

imidazoline. 
1- (2-Hydroxyethyl) -2-nor (coconut oil alkyl)-2- 
imidazoline. 
*l-(2-Hydroxyethyl)-2-nor(tall oil alkyl)-2- 
imidazoline . 
1- (2-Hydroxyethyl) -2-tridecyl-2- imidazoline 

hydrochloride. 
1- (2-Hydroxyethyl)-2-undecyl-4,4-bis(carboxyethyl)- 

imidazoline . 
1- (2-Hydroxyethvl) -2-undecvl-4-carboxyethvl- 
imidazoline. 

1- (2-HydroxyproDyl) -2- imidazoline 

•Amines and amine oxides having amide linkages: 

*Carboxylic acids - diamine and polyamine condensates: 
Adipic and stearic acids - diethylenetriamine 

condensate. 
Caprylic acid - tetraethylenepentamine condensate — 
Coconut oil acids - diethylenetriamine condensate — 
Coconut oil acids - N,N-dimethyltrinethylene- 
diamine condensate. 



NLC. 

DUP. 

nA, GAF, ICl, RH, TCH. 
GAF. 

r;wi. 

ARC, TCH. 

ARC, TCH. 

SCP. 

NLC. 

ARC. 

ARC, DUP, TCH. 

DUP. 

ARC. 

NLC. 

DUP. 

ARC, BAS. 

MTL. 
ARC, TCH. 



TCH. 
WVA. 
HPC, 
TCH. 
TCH. 

TCH. 
COM. 



BRD, 
MOA 

BRD, 
MOA. 

BRD, 

BRD, 

CGY. 

MOA . 

MOA. 

TCH. 

STC. 



ICI. 
APX. 
JRC, TXT. 



COM. 

DA, ONX, TXT. 

CGY, CHP, MOA, SNW. 



CGY, GAF, MOA, TCH, TXT. 
HDG, MOA, NLC, TCH, TXT, WTC. 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2. 



-Surface-active agents for which U.S. 

IDENTIFIED BY MANUFACTURER, 



PRODUCTION OR SALES WERE REPORTED, 
1974--CONTINUED 



Chemical 






Manufactur 


ers ' 


identification codes 






(ac 


cording to 


list in table 3) 


Caticnio Surface- Active Agents — Continued 














•Amines and amine oxides having amide linkages--Continued 














*Carboxylir acids - diamine and polyamine condensates-- 














Continued 














Mixed dicarboxylic acids - polyalkylenenolyaraine 


TXT. 












condensate. 














Mixed fatty acids - polyalkylenepolyamine 


GP.D, 


NLC, 


QCP, 


TCH. 






condensate. 
















ICI. 












uieic aciu - aie Lny lenetriajnine conuensate 




Oleic acid - N,N-dimethyltrimethylenediamine 


CCW. 












condensate. 














Pelargonic acid - tetraethylenepentaitiine 


ICI 












condensate. 














.Stearic acid, diethanolamine condensate. 


DUP. 












methyl sulfate. 














Stearic acid - diethylenetriamine condensate 


CHP, 


S. 










Stearic acid - N,N-diethylethylenediamine 


cnY, 


S. 










condensate. 














Stearic acid - N,N-dimethyltTimethvlenediamine 


SNIV. 












condensate. 
















VND. 












oteanc acia - poiyaiTiine conuensate 




Stearic acid - tetraethylenenentamine condensate 


ONX. 












*Tall oil acids - diethylenetriamine and 














polyalkylene polyamine condensates: 














Tall oil acids - diethylenetriamine condensate 


AZS, 


NCW, 


NLC, 


TXT, 


OTC. 




*Tall oil acids - polyalkylenepolyamine condensate-- 


AZS, 


QCP, 


TXN, 


TXT, 


WTC. 




Tallow acid - N,N-dimethyltrimethylenediamine 


TXT. 












condensate. 
















NLC. 












iallow acid - poiygiycoiamine conaensate 




♦Other amines and amine oxides having amide linkages: 














Coconut oil acids - dimethylamine oxide 


HLI. 












3-Lauramido-N,N-dimethylpropylamine oxide 


SNW . 












Oleic acid - ethylenediamine condensate, mono- 


CLD, 


DA, 


DEX, 


SOC, 


TNA. 




ethoxylated. 














Palm oil acids - ethylenediamine condensate, mono- 


APX. 












ethoxylated. 














Stearic acid - diethylenetriamine condensate, poly- 


ARC. 












ethoxylated. 














Stearic acid - ethylenediamine condensate, mono- 


CLD, 


CST 


DEX 


ICI, 


MRV, 


S, SCP. 


ethoxylated. 














Stearic acid - ethylenediamine condensate, poly- 


ICI. 












ethoxylated. 














3-Tallow-N,N-dimethylpropylamine oxide 


TXT. 












♦Amines, not containing oxygen (and salts thereof): 














Amine salts: 
















ARC. 












l^LOConut oii aiKyijamine acetate 






ARC. 












t^nycirogenatea taiiow aiKyijamine acetate 






GNU. 












(_y-uctaaecenyi J amine acetate 






ARC . 












uct auecyi amine acetate 


ARC. 












N- (Oleyl alkyl ) trimethylenediamine tallate 






SM. 












i\-l_iaiiOw aiKyijamine succinate 






ARC, 


ASH 










iN-(_iaiiow aiKyi J trimetnyieneaiamine acetate 






ARC, 


ASH 










N-(^lallow alKyi J trimetny leneui amine oieate 






ARC. 












iN-i^iaiiow aiKyi J trimetnyieneaiamine taiiate 




♦Diamines and polyamines: 
















ARC, 


ENO 


GNM 








iN-i^LOConut oil aiKyi J trimetnyieneaidiiiiiie 






ENO. 












^-[_uocosyi ana eicosyij trimetnyieneaiamine 






ARC. 












r^-i)oaecyiaietnyienetri amine 

♦Imidazoline derivatives: 












l-[3-(2-Aminoethyl)naphth-l-yl]-2-(8-hepta- 


NLC. 












decenyl) -2 -imidazoline. 














l-(2-Aminoethyl)-2-norCtall oil alkyl)-2- 


ARC, 


AZS 


NLC 


TXT 






imidazoline. 
















SCO. 












z-neptaaecyi-z-imiaazoime 






APC, 


BAS 


CCW 


SNIV 


STC. 




N- (^^'ixea alKyijno lyetny lenepo ly amine 






ARC, 


ASH 


GN»< 








N- (^M-i 'ctadeceny 1 J trimetny i eneoi amine 






RNO. 












IN- i^ooynean oil aiKyi j trimetnyieneaiamine 






ARC, 


GNM 










N- (^ 1 ai low aiKyi j aipropyienetri amine 






ARC, 


ASH 


ENO 


GW 






In- t lai low aiKyi j trimetnyieneaiamine 





SURFACE-ACTIVE AGENTS 
TABLE 2, --Surface-active agents for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197^--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Cationio Surface- Active Agents — Continued 

•Amines, not containing oxygen (and salts thereof) -- 
Continued 
•Primary monoamines: 

(Coconut oil alkyllamine 

Dodecyl amine 

Hexadecy lamine 

(Hydrogenated tallow alkyljamine 

(Mixed alkyl) amine 

(Mixed tert-alkyl) amine 

Myri sty lamine 

*9-0ctadeceny lamine 

Oct adecy 1 ami ne 

Octy lamine 

tert-Dctyl amine 

(Soybean oil alkyl)amine 

(Tall oil alkyl)amine 

*(Tallow alkyl) amine 

•Secondary and tertiary monoamines: 

Bis(coconut oil alkyl)amine 

Bis (hydrogenated tallow alkyl)amine 

N,N-Dimethyl (coconut oil alkyl)amine 

N,N- Dime thy Idecy lamine 

N,N-Dime thy Idodecy lamine 

N, N- Dime thy Ihexadecy lamine 

*N,N-Dimethyl (hydrogenated tallow alkyl)amine 

♦N,N-Dimethyl (mixed alkyl)amine 

N,N-Dime thy loct adecy lamine 

N,N-Dimethyl octy lamine 

N,N-Dimethyl (soybean oil alkyl)amine 

*N,N-ninethyltetradecy lamine 

N,N-Dime thy Itridecy lamine 

N-Methylbis (coconut oil alkyljamine 

*N-Methylbis (hydrogenated tallow alkyl)amine 

N-Methyldi Oct adecy lamine 

Triisodecy lamine 

Trilaury lamine 

Triocty lamine 

•Oxygen- containing quaternary ammonium salts: 

Quaternary ammonium salts having amide linkages: 
(2-Hydroxyethyl) dimethyl (S-stearamidoorooyl) - 

ammonium dihydrogen phosphate. 
(2-Hydroxyethyl) dimethyl (3-stearamidonroDyl) - 

ammonium nitrate. 
( 3- Lauramidopropyl)trimethyl ammonium methyl 

sulfate. 
2- (2-Lauroyloxyethyl) carbamoyl -1-methylpyridinium 

chloride . 
l-Hethyl-2- (2-5tearoyloxyethyl)carhamoylpyridinium 
chloride. 

All other 

Other oxygen-containing quaternary ammonium salts: 
(2-Aminoethyl) ethyl (hydrogenated tallow alkyl)(2- 

hydroxyethyl) ammonium ethyl sulfate. 
(2-Aminoethyl)ethyl(oleyl)-2-imidazolinium 

chloride. 
Benzyl (coconut oil alkvl)bis (2-hydroxyethyl) - 

ammonium chloride. 
Benzyl (coconut oil alkyl, ethoxylated)dimethvl- 

ammonium chloride. 
l-Benzyl-l-(2-hydroxyethyl)-2-nor (coconut oil 

alkyl)-2-imidazoliniun chloride. 
l-Benzyl-l-(2-hvdroxyethyl)-2-nor(tall oil alkvl)- 
2-imidazolinium chloride. 



ARC, 


ASH, 


ENO, 


GNM 


ARC, 


ASH. 


GNM. 




ARC, 


ENO. 






ARC, 


ASH, 


ENO, 


GW 


ARC. 








PH. 








GNM. 








ARC, 


ASH, 


ENO, 


GNM 


ARC, 


ASH, 


ENO. 




ARC. 








RH. 








ARC, 


ENO. 






ASH, 


cm. 






ARC, 


ASH, 


ENO, 


GNM 


ARC. 








ARC, 


ASH, 


ENO. 




ARC, 


BRD. 






BRD. 








ARC, 


BRD, 


ONX. 




ARC, 


BRD. 






ARC, 


ASH, 


ENO. 




ARC, 


BRD, 


ENO, 


ONX 


ARC, 


BRD, 


ENO, 


ONX 


BRD. 








ARC, 


END. 






ARC, 


BPD, 


ENO. 




BRD. 








ASH, 


ENO. 






ARC, 


ASH, 


ENO, 


GNM 


ASH . 








cm. 








CNM. 








GNM. 








ACY. 








ACY. 








ACY. 








OTC. 








WTC. 








MRV , 


X. 






LUR 








HLI 








NLC 


TXT 






DUP 


GAP 






TXT 








MOA 


NLC 







SYNTHETIC ORGANIC CHEMICALS. 197^1 



TABLE 2. --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197^1 



"anufactuTers ' identification codes 
(accordinp to list in table 3) 



Cationic Surfaoe-Actiue /1f7e>its--Continued 

*rixygen- containing quaternary airanon i um salts--Continued 
Other oxygen-containing quaternary anmonium 
salts- -Continued 
Bis(2-hydroxyethyl , ethoxylated) ethyl (hydrogenated 

tallow alkyl)aminonium ethvl sulfate. 
BisC2-hydroxyethyl , ethoxylated)methyl (9-octa- 

decenyl) ammonium chloride. 
Bis(2-hydroxyethyl, ethoxylated)methyloctadecyl- 

ammonium chloride. 
(Coconut oil alkyl)bis(2-hydroxyethyl, ethoxy- 

lated)methylammonium chloride. 
(Coconut oil alkyl)bis (2-hydroxyethyl)methylamrioniura 

nitrate. 
(Ethoxybenzyl) dimethyl (octylohenoxv) ammonium 

chloride. 
(Ethoxybenzyl) dimethyl (octyltolyloxy) ammonium 

chloride . 
l-Ethyl-2- (8-heptadecenyl)-l- (2-hydroxyethyl) -2- 
imidazolinium ethyl sulfate. 

N-Ethyl-N-hexadecvlmorpholinium ethyl sulfate 

N-Ethyl-N- (soybean oil alkyl)morDholinium ethyl 
sulfate. 

Hexadecyl trimethyl ammonium p-toluenesulfonate 

2-Hydroxvtrimethylenebis r (coconut oil alkvl^di- 

methyl ammonium chloride]. 
(Methyloctyl)bis (2^hydroxvethyl) ammonium n-toluene 
sulfonate. 
'Quaternary ammonium salts, not containing oxygen: 
*Acvclic: 

Bis (coconut oil alkyl)dimethvlammonium chloride 

Bis (coconut oil alkyl)dimethylammonium nitrate 

*Bis (hydrogenated tallow alkyl)dimethylammonium 
chloride . 
Bis (hydrogenated tallow alkvl)dimethylammonium 
methyl sulfate. 

(Coconut oil alkyl)trimethylammonium chloride 

Didecyldime thy 1 ammonium chloride 

Didodecyldimethvl ammonium bromide 

Dimethy Ibis (soybean oil alkyl ) ammonium chloride 

Dimethvldi Oct adecvl ammonium chloride 

Dimethy Idioctyl ammonium chloride 

Dodecyl trimethyl ammonium chloride 

Ethyldimethyl (mixed alkyl) ammonium ethyl sulfate 

Ethyldimethyl(9-octadecenyl) ammonium bromide 

Ethy Ihexadecv Id imethyl ammonium bromide 

Hexadecvl trimethyl ammonium bromide 

Hexadecyl trimethyl ammonium chloride 

(Hydrogenated tallow alkvl) trimethvlammonium 
chloride . 

Hethyltrioctylammonium chloride 

Mixed dialkyldimethvlammonium chloride 

N,N,N' ,N' ,N'-Pentamethyl-N-(tallow alkyl)tri- 
methylenebis [ammonium chloridel . 

Trimethyl (mixed alkyl) ammonium chloride 

Trine thy loctadecyl ammonium chloride 

Trimethyl (soybean oil alkyl) ammonium chloride 

Trimethyl (tallow alkyl)ammonium chloride 

Trimethyl tetradecyl ammonium bromide 

All other 

•Benzenoid: 

*Benzyl (coconut oil alkyl)dimethylammonium 

chloride. 
*Benzyldimethyl (mixed alkyl)aramonium chloride 



ICl. 

APC. 

ARC. 

ARC. 

ARC. 

RH. 

RH. 



BRD, ICI. 

in. 



FIN. 
CCY. 



ARC, ASH, ENn, RN". 

ARC. 

.WC, ASH, CIN, END, CNM. 



ARC, 


CN". 




BRP. 






ONX. 






ARC. 






ASH, 


ONX, 


PC. 


BRn. 






ARC, 


CN". 




DEX, 


JOR, 


TCC 


ONX. 






FIN. 






FIN. 






ARC, 


BPD. 




ARC. 






r,N»'. 






BRD. 






ARC. 






NLC. 






ARC. 






ARC, 


ENO. 




ARC , 


.^SH, 


GNM 


FIN. 







ARC, CRT, DEP, ENO, LUR. 
AAC, BRD, FIN, ONX, RH, SDH 



SURFACE-ACTIVE AGENTS 



TABLE 2. --Surface-active agents for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 197^--C0NT1 NUED 



Manufacturers' identification codes 
(according to list in table 3) 



Cationic Surface-Aative Agents — Continued 

'Quaternary ammonium salts, not containing oxvgen-- 
Continued 
♦Benzenoid-- Continued 

* Benz vl dime thy loctadecyl ammonium chloride 

Benzvldimethvl ftallow alkvllammonium chloride 

Benzyldinethyltetradecyl ammonium chloride 

Benzvldodecvldimethvl ammonium chloride 

Benzvlhexadecyldimethyl ammonium chloride 

Benzvl (hvdrogenated tallow alkvl)dimethylaramonium 

chloride. 

Benzvloctyldecyldinethvl ammonium chloride 

l-Benzvl-2-picolinium bromide 

l-Benzylnvridinium chloride 

Benzyltrime thy 1 ammonium chloride 

( 3, 4-nichlorobenzyl)dodecyldimethyl ammonium 

chloride. 

(Dodecylbenzyl)triethyl ammonium chloride 

2-Dodecylisoquinolinium bromide 

(Dodecylme thy lbenzyl)trimethyl ammonium chloride — 

l-Dodecyloyridinium chloride 

(Ethylbenzyl) dimethyl (mixed alkyl) ammonium 

chloride. 

1- (Mixed alkyl)quinolinium ethyl sulfate 

l-Phenethyl-2-picolinium bromide 

All other 

Nonionic Surface-Active Agents 

*Carboxylic acid amides: 

*Diethanolamine condensates (amine/acid ratio=2/l): 

Capric acid 

Castor oil acids 

*Coconut oil acids 

•Coconut oil and tallow acids 

*Lauric acid 

Laurie and mvristic acids 

*Linoleic acid 

Mixed vegetable oil acids 

•Oleic acid 

Pel argoni c acid 

•Stearic acid 

•Tail oil acids 

Tallow acids 

•Diethanolamine condensates (other amine/acid 
ratios) : 
•Coconut oil acids (amine/acid ratio=l/l) 

Coconut oil acids (amine acid ratio=l/1.2) 

Lard oil (amine/acid Tatio=2/l) 

•Laurie acid (amine/acid ratio=l/l) 

•Laurie and myristic acids (amine/acid ratio=l/l)-- 

Linoleic acid (amine/acid ratio=l/l) 

Mixed fattv acids (amine/aeid ratio=l/l) 

•Oleic acid (amine/acid ratio=l/l) 

Palmitic and stearic acid (amine/acid ratio=l/l)-- 

lapeseed oil acids (amine/acid ratio=l/l) 

Stearic acid (amine/acid ratio=l/l) 

Stearic acid (amine/acid ratio=2.7/l) 



BPn, FIN, ONX, 

F.NO. 

FIN, SDH. 

FIN, ONX. 

ONX. 

FNO. 

TXT. 
FIN. 

nFP. 

CIN, CRT, SNV,', TCC. 
ONX. 

PC. 



FIN. 
DUP, ICl. 



RH, SNV, TNI, TXT. 



CCY, SCP, TCH. 

CLI, NTL. 

ACT, AKS, AP.D, APL, BPn, BS'", CHP, CIN, CLI, CTL, DA, 
DPP, ECC, EFH, HLT, HPT, KNP, LUR, ^CP, MOA, MRV, 
ONX, PC, Vr,, PNX, PVO, RCn, SBC, SCP, STP, TCH, 
TXC, TXN, TXT, VAL, WTC. x. 

ACT, CLI, CRT, ESS, "OA, PC, PVO, SEY, SOS, TXT, UNN. 

BRD, CLI, DA, PC, TCH. 

MOA, RCD, SBC, STP. 

VND, KNP, WTC. 

HLI. 

CCW, CLI, SBC, STP, TXT. 

TCH. 

CLI, DA, ECC, ONX, SCO, SOS, TCH, TXC, VAL. 

ECC, EFH, MCP, MOA, MRV, WTC. 

SOS, TCH. 



ARD, AZS, CCL, CCY, CLI, CTL, DA, HLI, JRG, MOA, MRV, 
ONX, PIL, SBC, SCP, SEY, STP, TCC, TXN, TXT, 
l"TC. 

CON, .JPr;, SCP. 

EFH. 

ARD, CLI, CTL, EMK, HLI, LEV, MOA, ONX, SBC, TCH, TXN. 
TXT, WTC. 

CLI, PC, SBC, TXN, TXT. 

MOA, SBC. 

STP. 

CCY, HLI, SCP, TXT. 

•CP. 

EFH. 

CGY, E"", MRV, RPC, SEY. 

EFH. 



SYNTHETIC ORGANIC CHEMICALS, 197^ 



TABLE 2.- 



-SURFACE-ACTIVE AGENTS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED, 
IDENTIFIED BY MANUFACTURER, 197^--CONTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



Non-ionic Surface-Active Agents — Continued 

*Carboxylic acid amides--Continued 

'Diethanolamine condensates (other amine/acid 
ratios) --Continued 

Tall oil acids (amine/acid ratio=l/l) 

Tallow acids (amine/acid ratio=l/l) 

Ml other 

Ml other carhoxylic acid amides: 

Coconut oil acids - diethanolamine condensate, 

propoxylated. 
Coconut oil acids - ethanolamine condensate 

(amine/acid ratio=2/l) . 
Coconut oil acids - ethanolamine condensate 

(amine/acid ratio=l/l). 
Coconut oil acids - ethanolamine condensate, 

ethoxylated. 

Coconut oil acids - isopropanolamine condensate 

Hydrogenated castor oil acids - ethanolamine 

condensate (amine/acid ratio=2/l). 
Laurie acid - ethanolamine condensate (amine/acid 

ratio=2/i;) . 

Laurie acid - isopropanolamine condensate 

Laurie and myristic acids - ethanolamine 

condensate (amine/acid ratio=l/l) . 
Laurie and myristic acids - isopropanolamine 

condensate. 
Oleic acid - ethanolamine condensate (amine/acid 

ratio=l/l). 
Oleic acid - ethanolamine condensate, ethoxylated — 

Oleic acid - iscpropanolamine condensates 

Succinic acid - ethanolamine condensate (amine/acid 

ratio=2/l) . 
Stearic acid - ethanolamine condensate (amine/acid 

ratio=2/l') . 
Stearic acid - ethanolamine condensate (amine/acid 

ratio=l/l). 
Tallow acids - ethanolamine condensate (amine/acid 

ratio=l/l) . 

All other 

*Carboxylic acid esters: 
*Anhydrosorhitol esters: 

Anhydrosorbitol dioleate 

Anhydrosorbitol distearate 

Anhydrosorbitol monoester of tall oil acids 

Anhydrosorbitol monolaurate 

Anhydrosorbitol mono- ol eat e 

Anhydrosorbitol monopa Imitate 

Anhydrosorbitol monostearate 

Anhydrosorbitol sesquiester of tall oil acids 

Anhydrosorbitol sesquioleate 

Anhydrosorbitol triester of tall oil acids 

Anhydrosorbitol triisostearate 

Anhydrosorbitol trioleate 

Anhydrosorbitol tristearate 

*Diethylene glycol esters : 

Diethylene glycol dioleate 

*Diethylene glycol distearate 

Diethylene glycol monoester of coconut oil acids 

Diethylene glycol monoester of tallow acids 

Diethylene glycol monolaurate 

Diethylene glycol mono-oleate 

Diethylene glycol monoricinoleate 

♦Diethylene glycol monostearate 

Diethylene glycol sesciuilaurate 

Diethylene glycol sesquistearate 



ECC, 
RPC. 
ORO. 

F.FH . 

CTL, 

ARn, 



PFK, PPX, STP, TCH, VND, IfTC . 
HLT, HII", MOA, Pn, STP, WTC. 
STP. 



STP. 










GLY, 


NTL. 








ARC, 


CTL, 


PRX. 






CLI 


MOA, 


SNW. 






MOA, 


TXN, 


TXT. 






LEV, 


TXT. 








VPC . 










DA, 


GAP. 








SRC. 










ECC 










CLI, 


FCC. 








HAL, 


MOA, 


SBC, 


SNW, 


VND 


SCP 










ROR 


MCP, 


TCH. 






ICl 










CHP 










HDG 


TCI, 


TCH. 






GLY 


HDG, 


ICl, 


PVO 


TCH 


GLY 


HDG, 


ICl, 


PVO, 


TCH 


GLY 


HDG, 


ICl, 


TCH. 




GLY 


HDG, 


ICl, 


PVO, 


TCH 


WTC 










GLY 


HDG, 


TCH. 






GLY 










TCH 










GLY 


TCI, 


TCH. 






GLY 


ICl. 








GLY 










ARC 


FCC, 


GLY, 


VAL 




AAC 


DA. 








OCR 










ECC 


GLY, 


HAL, 


HDG 




ARC 


HAL. 








DA, 


GLY. 








ARC 


CHP, 


CLI, 


DA, 


HAL, 


ARC 


GLY. 








Wt, 


mc. 









J 



SURFACE-ACTIVE AGENTS 



TABLE 2. 



-Surface-active agents for which U.S, production or sales were reported^ 
identified by manufacturer^ isz^^ — continued 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionia Surfaae-Aotive Agents — Continued 

*Carboxylic acid esters--Continued 
*Ethoxylated anhydrosorbitol esters: 

F.thoxylated anhydrosorbitol isostearate 

Ethoxylated anhydrosorbitol monolaurate 

*F.thoxylated anhydrosorbitol mono-oleate 

Ethoxylated anhydrosorbitol monopalmitate 

*Ethoxylated anhydrosorbitol monostearate 

Ethoxylated anhydrosorbitol triester of tall oil 
acids. 

Ethoxylated anhydrosorbitol trioleate 

Ethoxylated anhydrosorbitol tristearate 

Ethoxylated sorbitol esters: 

Ethoxylated sorbitol beeswax ester 

Ethoxylated sorbitol distearate 

Ethoxylated sorbitol heptaoleate 

Ethoxylated sorbitol hexaester of tall oil acids-- 

Ethoxylated sorbitol hexaoleate 

Ethoxylated sorbitol lanolin ester 

Ethoxylated sorbitol mono-oleate 

Ethoxylated sorbitol oleate, acetylated 

Ethoxylated sorbitol pentalaurate 

Ethoxylated sorbitol pentaoleate 

Ethoxylated sorbitol tetraester of lauric and 
oleic acids. 

Ethoxylated sorbitol tetraoleate 

'Ethylene glycol esters: 

Ethylene glycol distearate 

Ethylene glycol mono-oleate 

Ethylene glycol monostearate 

♦Glycerol esters: 

♦Complex glycerol esters: 

Glycerol diacetyltartrate monostearate 

Glycerol esters ethoxylated 

Glycerol lactate esters of fatty acids 

Glycerol lactate stearate 

Glycerol raonoester of mixed fatty acids, 
acetylated. 

Glycerol mono-oleate, acetylated 

Glycerol mono-oleate, ethoxylated 

Glycerol monostearate, succinylated 

Glycerol pelargonate 

♦Glycerol esters of chemically defined acids: 

Glycerol dioleate 

Glycerol dilaurate 

Glycerol distearate 

Glycerol monocaprylate 

Glycerol monoisostearate 

Glycerol monolaurate 

♦Glycerol mono-oleate 

Glycerol monopalmitate 

Glycerol monoricinoleate 

♦Glycerol monostearate 

Glycerol trioleate 

♦Glycerol esters of mixed acids: 

Glycerol mono and diesters of mixed fatty acids- 

Glycerol monoester of coconut oil acids 

Glycerol monoester of cottonseed oil acids 



TCH. 

AAC, GLY, HDG, ICI, MIL, PVO, TCH. 

AAC, GLY, HDG, ICI, MIL, PVn, TCH. 

AAC, GLY, ICI, TCH. 

AAC, GLY, HPG, ICI, PVn, TCH. 

ICI, TCH. 

AAC, GLY, ICI, TCH. 

AAC, GLY, HDG, ICI, PVn, TCH. 

ICI. 

ICI. 

ICI. 

ICI, TCH. 

GLY, ICI, TCH. 

in. 

AAC, GLY, ICI. 

ICI. 

ICI. 

ICI. 

ICI. 

ICI. 

ARC, EW, HUM, WM. 

EFH. 

.ARC, CLI, GLY, HAL, HDG, KNP , TCH, VND, Wl. 



WTC. 
GLY. 
GLD. 
GLY. 
EKT. 

GLY. 
SCP. 
EKT. 

WM. 

ARC, HAL. 

VND. 

APC, ICI. 

ARC, PVn. 

TCH. 

ARC, GLY, HAL. 

ARC, CCW, DA, EFH, FJ'R, GLY, GR", HAL, HDG, PVO, 

TCH, WM, WTC. 
ARC. 

DA, HAL, HDG. 
ARC, ASH, BLS, CHL. CIN, DA, EFH, EMR, GLY, GRO, HAL, 

HDG, HRT, PG, PVO, SCP, TCH, VND,, WM, WTC. 
HAL, TCH. 

BFP, GLD, ICI, LEV. 

PVO. 

EKT. 



SYNTHETIC ORGANIC CHEfUCALS. 197^1 



TABLE 2,- 



-Surface-active agents for which U.S, production or sales were reported, 
identified by manufacturer, 1974--c0ntinued 



Nonionic Surf ace- Active Agents — Continued 

*CarboxyIic acid ester5--Continued 
♦Glycerol esters--Continued 

♦Glycerol esters of mixed acids--Continued 

♦Glycerol monoester of hydrogenated cottonseed 

oil acids. 
♦Glycerol monoester of hydrogenated soybean oil 
acids . 
Glycerol monoester of hydrogenated tall oil acids - 

♦Glycerol monoester of lard acids 

Glycerol monoester of mixed vegetable oil acids — 

Glycerol monoester of peanut oil acids 

Glycerol monoester of safflower oil acids 

Glycerol monester of tall oil acids 

Glycerol monoester of tallow acids 

Glycerol sesquiester of hydrogenated tallow acids- 

Glycerol sesquiester of tall oil acids 

♦Natural fats and oils, alkoxylated: 

♦Castor oil, ethoxylated 

Corn oil, ethoxylated 

♦Hydrogenated castor oil, ethoxylated 

♦Lanolin, ethoxylated 

Tall oil, ethoxylated 

All other 

♦Polyethylene glycol esters: 

♦Polyethylene glycol esters of chemically defined 
acids: 

♦Polyethylene glycol dilaurate 

♦Polyethylene glycol dioleate 

Polyethylene glycol distearate 

Polyethylene glycol ditallate 

Polyethylene glycol methylcarbitol maleate 

Polyethylene glycol monocaprylate 

Polyethylene glycol monoisostearate 

♦Polyethylene glycol raonolaurate 

♦Polyethylene glycol mono-oleate 

Polyethylene glycol mono-oleate, ethoxylated 

Polyethylene glycol monopalmitate 

Polyethylene glycol monopelargonate 

Polyethylene glycol monricinoleate 

♦Polyethylene glycol monostearate 

Polyethylene glycol monotallate 

Polyethylene glycol sesquioleate 

♦Polyethylene glycol esters of mixed acids: 
Polyethylene glycol monoester of coconut oil 

acids, ethoxylated. 
Polyethylene glycol monoesters of lauric and 

stearic acids. 
Polyethylene glycol monoester of soybean oil 

acids. 
Polyethylene glycol monoester of tall oil acids — 
Polyethylene glycol monoester of tall oil acids, 

ethoxylated. 
Polyethylene glycol sesquiester of castor oil 

acids . 
♦Polyethylene glycol sesquiester of coconut oil 

acids. 



Manufacturers' identification codes 
(according to list in table 3) 



EKT, GLD, LEV, WM. 

ASH, EKT, GLD, NW, PVn, TCH, WTC. 

TCH. 

EKT, GLD, GLY. 

EKT. 

Pvn. 

EKT. 
EFH. 

BFP, EKT. 
JRG. 
SLM. 

AAC, DA, GAF, ICI , MIL, NLC, NTL, PVO, TCH, T>(H, 

WTC. 
TCH. 

DA, ICI, NTL, TCH. 
AAC, CRD, CRN, ICI, PRX, TCH. 
DA, JCC, TCH. 
ARC, TCH. 



ARC, DA, EFH, GLY, HAL, HDG, PVn, TCH, Wl. 

ARC, BRD, CGY, CLD, EFH, GLY, HAL, HDG, NLC, TCH, 

VND, WM. 
ARC, GLY, HAL, HDG, PVO, TCH. 
EFH. 
CCA. 
ECC. 
TCH. 
AAC, ARC, BRD, CCA, CGY, DA, GLY, HAL, HDG, ICI, KNP, 

TCH. 
ARC, BRD, CCA, CHP , GIN, CLD, CRT, DA, DEP, DEX, EFH, 

GAF, GLY, HAL, HDG, MRV , ONX, SCP, STC, TCH, WM, 

WTC. 
ICI. 

ICI, WTC. 
EMR, TCH. 
DA, HAL. 
AAC, AKS, ARC, CGY, CHP, CIN, CRT, DA, DEP, DEX, EFH, 

EMR, GAF, GLY, HAL, HDG, HRT, TCI, KNP. MCP, ONX, 

PC, PVO, STC, TCH, VND, WM, WTC. 
TCH. 
ICI, S»1, TCH, WTC. 



ICI. 
MCP. 








GLY, 


TCH. 






ACT, 


TCH. 






NLC. 








CGY. 








ARL, 


MRT, 


PG, 


VND 



SURFACE-ACTIVE AGENTS 



TABLE 2. --Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197'4--C0NTINUED 



Nonionic Surface-Active Agents — Continued 

*Carboxylic acid esters--Continued 

•Polyethylene glycol esters--Continued 

♦Polyethylene glycol esters of mixed acids-- 
Continued 

Polyethylene glycol sesquiester of rosin acids 

♦Polyethylene glycol sesquiester of tall oil acids- 
Polyethylene glycol sesquiester of tallow acids — 

All other 

Polyglycerol esters; 

Polyglycerol decaoleate 

Polyglycerol mono ester of tall oil acids 

Polyglycerol mono-oleate 

Polyglycerol monos tear ate 

♦Propanediol esters; 

1,2- Propanediol dioleate 

1 ,3-Propanediol monoester of coconut oil acids 

♦1 ,2- Propanediol monolaurate 

1,2- Propanediol mono-oleate 

*1 ,2- Propanediol monostearate 

1,2-Propanediol sesquiester of hydrogenated tallow 
acids. 

All other 

Miscellaneous carboxylic acid esters; 

Anhydrosorbitol glycerol monolaurate 

Ethoxylated glycerol sesquiester of mixed fatty 
acids . 

Ethoxylated 1 ,2-propanediol mono-oleate 

Ethoxylated 1,2-propanediol monostearate 

2-Hydroxymethyl-:-butene-l,4-diol monopelargonate--- 
Laurie acid esters of glycerol and ethoxylated 
nonylphenol . 

Mannitol dioleate, propoxylated 

Methylglucoside laurate 

Mixed polyhydric alcohols-triester of tall oil 
acids . 

Oleic acid esters of ethoxylated nonylohenol 

Pentaerythritol distearate -- 

Pentaerythritol stearate 

Polyalkylene glycol adipate 

Polyalkylene glycol naphthenate 

Polyethylene glycol monoester of coconut oil acids, 
ethoxylated. 

Polv-propylene glycol mono-oleate 

Polypropylene glycol monostearate 

All other 

♦Ethers : 

♦Benzenoid ethers; 

(Mixed alkyl)phenol - formaldehyde, alkoxylated 

Nonylphenol - formaldehyde, alkoxylated 

tert-nctylphenol - formaldehyde, ethoxylated 

Pentylphenol- formaldehyde, alkoxylated 

Diisobutylphenol, ethoxylated 

Dinonylphenol , ethoxylated 

♦Dodecylphenol , ethoxylated 

Iso-octylphenol , ethoxylated 



Manufacturers' identification codes 
(according to list in table 3) 



HPC, STC. 

ICI, HON, SW, SM, WTC. 

SOS. 

EMK. 

TCH. 

AZS. 

HDG, TCH, VND, WTC. 

GLY, PVO, TCH, IVTC. 



WM. 

ARC, 

EFH, 

ARC, 

JRG. 



HAL, PVO, SBC. 

HAL. 

EKT, GLD, GLY, HAL, ICI, PVO, TCH, WM, WTC. 



IMTC. 




ICI, 


WTC. 


ICI. 




TCC. 




WTC. 




HDG. 




ICI. 




EFH. 




GLY, 


OCP. 


VAL. 




NLC. 




TCH. 




AAC. 




HDG. 




HDG. 




CCK, 


EMR, SOS, TCH. 


NLC, 


NTL, IVTC. 


NLC 


WTC. 


ARC, 


DA, SDW. 


AAC 




GAF 




GAF 


JCC, STP, TCH. 


DA, 


GAF, MON, TCH, TMII, UCC, WTC 


AAC 


APX, DA, OMC, RH. 



SYNTHETIC ORGANIC CHEMICALS. 197^1 



TABLE 2.- 



-SURFACE-ACTIVE AGENTS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED. 
IDENTIFIED BY MANUFACTURER. 1974~CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



Nonionia Surf ace- Active Agents — Continued 

♦Ethers --Continued 

*Benzenoid ethers--Continued 

(Mixed alkyl)phenol, ethoxylated 

(Mixed alkyl)phenol, ethoxylated, butyl ether 

(Mixed alky l)phenoxypoly(ethyleneoxy) ethyl 
chloride. 
*Nonylphenol , ethoxylated 

Nonylphenol, ethoxylated and propoxylated 

Nonylphenoxypoly(ethyleneoxy) ethyl iodide 

n-Octylphenol, ethoxylated 

•Phenol , ethoxylated 

Phenol , propoxylated 

Styrenated phenol, ethoxylated 

Tetradecylphenol, ethoxylated 

Tridecylphenol, ethoxylated 

Xylenol , ethoxylated 

*Nonbenzenoid ethers: 

'Linear alcohols, alkoxylated: 

Coconut oil alcohol, ethoxylated 

*Decyl alcohol, ethoxylated 

Decyl and octyl alcohols, ethoxylated 

Decyl and octyl alcohols, ethoxylated and 
propoxylated. 

Decyloxypoly(ethyleneoxy) ethyl chloride 

*Dodecyl alcohol, ethoxylated 

Hexadecyl alcohol, ethoxylated 

Hexyl alcohol, ethoxylated 

Lauryl alcohol, ethoxylated 

'Mixed linear alcohols, ethoxylated 

•Mixed linear alcohols, ethoxylated and 
propoxylated. 
Mixed linear alcohols, propoxylated 

*9-nctadecenyl alcohol, ethoxylated 

*nctadecyl alcohol, ethoxylated 

nieyl alcohol, ethoxylated 

Sperm oil alcohol, ethoxylated 

Stearyl alcohol, ethoxylated 

Stearyl alcohol, propoxylated 

Tallow alcohol, ethoxylated 

Tetradecyl alcohol, ethoxylated 

Wool wax alcohols, ethoxylated 

*Other ethers and thioethers : 

tert-Dodecyl mercaptan, ethoxylated 

4-Ethyl-l-octyn-3-ol , ethoxylated 

2-EthyIhexanol , ethoxylated 

Glycerol , alkoxylated 

Isodecyl alcohol, ethoxylated and propoxylated- 

Iso-octyl alcohol, ethoxylated 

Mixed alcohols, ethoxylated 

Poly(mixed ethylene, propylene) glycol 

Polyoxy-4-ethyl-l-octyn-3-ol 

Polypropylene glycol, ethoxylated 

Primary alcohols, ethoxylated 

Rosin alcohol, ethoxylated 

Sorbitol , ethoxylated 

2,4,7,9-Tetramethyl-5-decyne-4 ,7-diol , 
ethoxylated. 

*Tridecyl alcohol, ethoxylated 

Tridecyl alcohol, propoxylated and ethoxylated- 

Trimethylheptanol, ethoxylated 

Trimethylnonyl alcohol, ethoxylated 

Trimethylolpropane, alkoxylated 

All other 



PRX, RK, TCH. 








NTL. 








GAF. 








DA, GAF, HDG, ICI , JCC, MON, 


NLC, 


OMC, 


RH 


STP, TCH, TMH, UCC, WTC. 








WTC. 








GAF. 








TCH. 








DA, GAF, ICI, MIL, TCH, UCC. 








ICI. 








DA. 








ORG. 








TCH. 








NLC. 








GLY, JCC, TCH, WTC. 








GAF, ICI, VPC, WTC. 








GAF, GLY. 








GAF. 









( 



GAF. 

AAC, DUP, GAF, HDG, ICI, MIL, UCC, WTC. 

AAC, GLY, ICI. 

TCH. 

GLY. 

AAC, GIN, CO, DUP, GAF, HDG, JCC, NLC, RH, SHC, 

TCH, UCC, WTC. 
BAS, DUP, JCC, STP, TCH, UCC, WTC. 

DUP. 



AAC, 


CRN, DA, GAF, ICI, 


TCH, 


VPC. 


DA, 


DUP, GAF, ICI, HDG, 


VPC. 




CRD. 








DUP. 








TCH. 








ICI. 








AAC, 


JCC, TCH. 






ICI. 








CRD. 








AAC. 








TCH. 








TCH. 








NLC. 








TCH. 








G.\F. 








CRN, 


MIL, pvn. 






BAS, 


NLC, UCC, WTC. 






TCH. 








NLC, 


TCH, WTC. 






RH. 








NLC. 








TCH 


WTC. 






GLY. 








AAC, 


DA, DUP, GAF, ICI 


JCC 


MIL, MON, NLC, OMC 


PVO, TCH, WTC. 






JCC 








TCH 








HDG 


UCC. 






BAS 


HDG. 






VAL 









SURFACE-ACTIVE AGENTS 



TABLE 2. 



-Surface-active agents for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1974— CONTINUED 



Chemical 


Manufacturers' identification codes 
(according to list in table 3) 


Nonionic Sicf face- Active /3^ents--Continued 

Other nonionic surface-active agents: 

Dodecylbenzenesulfonic acid - diethanolamine 
condensate, fatty acid monoester. 


ACT. 
nUP, GLY. 









SYNTHETIC ORGANIC CHEMICALS, 1974 
TABLE 3, --Surface-active agents: Directory of manufacturers, 1974 



ALPHABETICAL DIP.ECTnRY BY CODE 

[Names of manufacturers that reported production or sales of surface-active agents to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


AAC 


Alcolac Chemical Corp. 


FIN 


Fine Organics, Inc. 


ACT 


Arthur C. Trask Co. 






ACY 


American Cyanamid Co. 


GAF 


GAF Corp., Chemical Div. 


AES 


Amerace Corp., Penetone Div. 


GLD 


SCH Corp., Glidden-Durkee Div. 


AGP 


Armour- Dial, Inc. 


GLY 


Glyco Chemicals, Inc. 


AIP 


Air Products 5 Chemicals, Inc. 


GNU 


General Mills Chemicals, Inc. 


AKS 


Arkansas Co. , Inc. 


GRC 


Chemed Corp., Dubois Chemicals Div. 


APX 


Apex Chemical Co., Inc. 


GRD 


W.R. Grace § Co., Polymer 5 Chemicals Div. 


ARC 


Armak Co. 


GRL 


Chemed Corp., Vestal Laboratories, Inc. 


ARD 


Ardmore Chemical Co. 


GRO 


Millmaster Onyx Corp., A. Gross 5 Co. Div. 


ARL 


Arol Chemical Products Co. 


GYR 


Goodyear Tire 5 Rubber Co. 


ASH 


Ashland Oil, Inc., Ashland Chemical Co. 








Div. 


HAL 


CP. Hall Co. of Illinois 


ASY 


American Synthetic Rubber Corp. 


HDG 


Hodag Chemical Corp. 


ATR 


Atlantic Richfield Co., ARCn Chemical 


HEW 


Hewitt Soap Co., Inc. 




Co. 


HK 


Hooker Chemicals 5 Plastics Corp. 


AZS 


AZS Corp. : 


HLI 


Haag Laboratories, Inc. 




AZ Products Co. Div. 


HMP 


W.R. Grace 5 Co., Dewey f, Almy Chemical 




Lancaster Chemical Co. Div. 




Div., Organic Chemicals 






HNT 


Huntington Laboratories, Inc. 


BAO 


Bayoil Co. , Inc . 


HPC 


Hercules, Inc. 


BAS 


BASF Wyandotte Corp. 


HRT 


Hart Products Corp. 


BFP 


Breddo Food Products Corp. 


HlPt 


Kraftco Corp., Humko Products Div. 


BLA 


Astor Products, Inc., Blue Arrow Div. 






BLS 


Life Savers, Inc. 


ICI 


ICI United States, Inc., Specialty 


BRD 


Lonza, Inc. 




Chemicals Group 


BSW 


Original Bradford Soap Works, Inc. 






CCA 


Interstab Chemical, Inc. 


JCC 


Jefferson Chemical Co., Inc. 


CCW 


Cincinnati Milacron Chemicals, Inc. 


JOR 


Jordan Chemical Co. 


CCL 


A.E. Staley Manufacturing Co., Textile Div. 


JP.G 


Andrew Jergens Co. 


CEL 


Celanese Corp. , Celanese Coatings 5 Specialties 








Co. , Wica Plant 


KAL 


Pathan Chemical Co. 


CGY 


Ciba-Geigy Corp. and Ciba Pharmaceutical Co. 


KNG 


Far-Best Corp., O.L. King Div. 


CHL 


Chemol, Inc. 


KNP 


Knapp Products, Inc. 


CHP 


C.H. Patrick 5 Co., Inc. 






CIN 


Cindet Chemicals, Inc. 


LAK 


Lakeway Chemicals, Inc. 


CLD 


Colloids, Inc. 


LFA 


Leatex Chemical Co. 


CLl 


Clintwood Chemical Co. 


LEV 


Lever Brothers Co. 


cn 


Continental Oil Co. 


LIL 


Eli Lilly 6 Co. 


COM 


Commercial Solvents Corp. 


LKY 


Lake States Div. of St. Regis Paper Co. 


CON 


Concord Chemical Co. , Inc. 


LMI 


North American Chemical Co. 


CP 


Colgate-Palmolive Co. 


LUR 


Laurel Products Corp. 


CPP 


Charmin Paper Products Co. 






CRD 


Croda, Inc. 


MAR 


American Can Co. 


CRN 


CPC International, Inc. 


HCP 


Moretex Chemical Products, Inc. 


CRT 


Crest Chemical Corp. 


MIR 


Miranol Chemical Co., Inc. 


CRZ 


Crown Zellerbach Coro. , Chemical Products Div. 


MOA 


Mona Industries, Inc. 


CST 


Charles S. Tanner Co. 


MON 


Monsanto Co. 


CTL 


Continental Chemical Co. 


MRA 


Crown -Metro, Inc. 


CW 


Consolidated Papers, Inc. 


MRD 


Marden-Wild Corp. 






MRT 


Morton Chemical Co. Div. of Morton-Norwich 


DA 


Diamond Shamrock Corp. 




Products, Inc. 


DAN 


Dan River, Inc. 


MRV 


Marlowe-Van Loan Corp. 


DEP 


DePaul Chemical Co., Inc. 






DEX 


Dexter Chemical Corp. 


NCW 


Nostrip Chemical Works, Inc. 


DOW 


Dow Chemical Co. 


NES 


Nease Chemical Co., Inc. 


DUP 


E.I. duPont de Nemours 5 Co., Inc. 


NLC 


Nalco Chemical Co. 


DYS 


Davies -Young Co. 


NMC 


National Milling S Chemical Co., Inc. 






NPR 


Safeway Stores, Inc. 


ECC 


Eastern Color f, Chemical Co. 


NTL 


NL Industries, Inc. 


EPH 


E.F. Houghton 6 Co. 


NW 


Northwestern Chemical Co. 


EKT 


Eastman Kodak Co., Tennessee Eastman Co. Div. 






EMK 


Emkay Chemical Co. 


OMC 


01 in Corp. 


EMR 


Emery Industries, Inc. 


ONX 


Millmaster Onyx Corp., Onyx Chemical 


ENO 


Enenco, Inc. 




Co. 


ESS 


Essential Chemicals Corp. 


ORO 


Chevron Chemical Co. 



SURFACE-ACTIVE AGENTS 



TABLE 3. —Surface-active agents: Directory of manufacturers, 1974— Continued 



Code 


Name of company 


Code 


Name of company 


PC 


Proctor Chemical Co., Inc. 


SOP 


Southern Chemical Products Co., Inc. 


PCH 


Peerless Chemical Co. 


SOS 


Southern Sizing Co. 


PEK 


Peck's Products Co. 


SPA 


Scott Paper Co. 


PFZ 


Pfizer, Inc. 


stc 


Sou-Tex Chemical Co., Inc. 


PG 


Procter 6 Gamble Co. 


STP 


Stepan Chemical Co. 


PIL 


Pilot Chemical Co. 


SW 


Sherwin-Williams Co. 


PLX 


Plex Chemical Corp. 


SYL 


Deering Milliken, Inc., Milliken Chemical 


PNX 


Murphy-Phoenix Co. 




Div. 


PRX 


Purex Corp. 






PSP 


Georgia-Pacific Corp. , Bellingham Div. 


TCC 


Tanatex Chemical Corp. 


PVO 


PVO International, Inc. 


TCH 


Emery Industries, Inc., Trylon Chemical 

Div. 
Texize Chemical Co. 


OCP 


Ouaker Chemical Corp. 


TCI 






TEN 


Cities Service Co., Copperhill Operations 


RAY 


ITT Rayonier, Inc. 


TMH 


Thompson-Hayward Chemical Co. 


RBC 


Fike Chemicals, Inc. 


TNA 


Ethyl Corp. 


RCD 


Richardson Co. 


TNI 


The Gillette Co., Chemical Div. 


RH 


Rohm S Haas Co. 


TXC 


Tex Chera. Co. 


ROB 


Robeco Chemicals, Inc. 


TXN 


Textilana-Nease, Inc. 


RPC 


Millmaster Onyx Corp., Refined-Onyx Div. 


TXT 


Text 11 ana Corp. 


S 


Sandoz, Inc., Sandoz Colors 5 Chemical Div. 


UCC 


Union Carbide Corp. 


SBC 


Scher Bros. Inc. 


UDI 


Petrochemicals Co., Inc. 


SBP 


Sugar Beet Products Co. 


UNN 


United Chemical Corp. of Norwood 


sen 


Scholler Bros. , Inc. 


UNP 


United Chemical Products Corp. 


SCP 


Henkel, Inc. 


USR 


Uniroyal, Inc., Chemical Div. 


SDC 


Martin-Marietta Corp. , Sodyeco Div. 








Sterling Drug, Inc. : 


VAL 


Valchem 


SDH 


Hilton-Davis Chemical Co. Div. 


VND 


Van Dyk S Co . , Inc . 


SDW 


Winthrop Laboratories Div. 


VPC 


Mobay Chemical Corp. , Verona Div. 


SEA 


Seaboard Chemicals, Inc. 






SEY 


Seydel-Woolley 5 Co. 


WAW 


W.A. Wood Co. 


sfs 


Stauffer Chemical Co., Specialty Div. 


WAY 


Philip A. Hunt Chemical Corp., Wayland 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 




Chemical Div. 


SID 


George F. Siddall Co., Inc. 


WBG 


White 6 Bagley Co. 


SLC 


Soluol Chemical Co., Inc. 


WKI 


White 5 Hodges, Inc. 


SLM 


Salem Oil § Grease Co. 


WHW 


Whittemore-Wright Co., Inc. 


SM 


Mobil Oil Corp., Mobil Chemical Co., 


OTI 


Inolex Corp. 




Chemical Coatings Div. 


WTC 


Witco Chemical Co., Inc. 


SNW 


Sun Chemical Corp., Chemicals Div. 


WVA 


Westvaco Corp., Chemicals Div., Poly- 


snc 


Standard Oil Co. of California, Chevron 
Chemical Co. 




chemicals Dept . 



Note. --Complete names and addresses of the above reporting companies are listed in table 1 of the appendix 



184 SYNTHETIC ORGANIC CHEMICALS^ 197^ 



PESTICIDES AND RELATED PRODUCTS 



Pesticides and related products include fungicides, herbicides, insecticides, 
rodenticides, and related products such as plant hormones, seed disinfectants, 
soil conditioners, soil fumigants, and synergists. The data are given in terms 
of 100 percent active material; they thus exclude such materials as diluents, 
emulsifiers, and wetting agents. 

U.S. production of pesticides and related products in 1974 amounted to 1,417 
million pounds--9.9 percent greater than the 1,289 million pounds reported for 
1973 (table 1).^ Sales in 1974 were 1,365 million pounds, an increase of 13.8 
percent, as compared with 1,199 million pounds reported in 1973; the value of 
sales was $1,815 million in 1974, compared with $1,344 million in 1973--an 
increase of 35.0 percent. 

The output of cyclic pesticides and related products amounted to 1,026 million 
pounds in 1974--12.7 percent greater than the 910 million pounds produced in 
1973. Sales in 1974 were 971 million pounds, valued at $1,468 million, compared 
with 852 million pounds, valued at $1,091 million in 1973. Production of acyclic 
pesticides and related products in 1974 amounted to 392 million pounds, compared 
with 379 million pounds reported for 1973, an increase of 3.4 percent. Sales 
in 1974 were 394 million pounds, an increase of about 13.5 percent, as compared 
to the 347 million pounds reported in 1973; the value of sales was $347 million 
in 1974, compared with $252 million in 1973--an increase of 37.7 percent. 



1 See also table 2 which lists these products and identifies the manufacturers 
by codes. These codes are given in table 3. 



PESTICIDES AND RELATED PRODUCTS 



TABLt 1. --Pesticides and related products; U.S. production and sales. 1974 



[Listed below. are all pesticides and related products for which any reported data on production or sales may be pub 
lished. (Leaders are used where the reported data are accepted in confidence and may not 

data were reported.) Table 2 lists all pesticides and — i-*-".i 1..^*^ r — ,,ui^u j-,*--, — 

were reported and identifies the manufacturers of each 



1.LMICU. i_i.cciuci:> cti c LI3CU tvnci c i.iic n^pwx Lcu uttLa ai IT ai_i_cpLcu ill «„uii i- iucnt„c diiu may not be published or where no 
data were reported.) Table 2 lists all pesticides and related products for which data on production and/or sales 



Quantity 



Unit 
value' 



Grand total 

Benzenoid 

Nonbenzenoid 

PESTICIDES AND RELATED PRODUCTS, CYCLIC 

Total 

Fungicides, total 

Naphthenic acid, copper salt 

Pentachlorophenol (PCP) 

Phenylmercuric acetate (PMA) 

All other cyclic fungicides^ 

Herbicides and plant hormones, total 

l,2-Dihydropyridazine-3,6-dione (Maleic hydrazide) 
CMH) - 

2,4-Dichlorophenoxyacetic acid, dimethylamine salt- 
All other cyclic herbicides and plant hormones' 

Insecticides and rodenticides, total 

Aldrin-toxaphene group"* 

Organophosphorus insecticides, total 

0,0-Dimethyl 0-p-nitrophenyl phosphorothioate 

(Methyl parathion) 

All other organophosphorus insecticides^ 

1 , 1 , l-Trichloro-2 , 2-bis (p-methoxypheny 1 ) ethane 

(Methoxychlor) 

All other cyclic insecticides and rodenticides^ 

PESTICIDES AND RELATED PRODUCTS, ACYCLIC 

Total 

Fungicides, total 

Dithiocarbamic acid salts' 

All other acyclic fungicides' 

Herbicides and plant hormones^ 

Insecticides, rodenticides, soil conditioners and 

fumigants, total 

Methyl bromide (Bromomethane) 

Organophosphorus insecticides'^ 

Trichloronitrome thane (Chloropicrin) 

All other acyclic insecticides, rodenticides, soil 
conditioners and fumigants" 



1,000 

pounds 

1,417,158 



844,959 
372,199 



136 
70,072 



5,834 

14,459 

467,404 



141,719 
107,825 



51,448 
56,377 



5,248 
160,496 



35,419 
2,816 



36,921 



30,452 
78,762 

4,757 

122,950 



1,000 

pounds 

1,365,214 



1,000 
do I lavs 
1,815,433 



765,586 
599,628 



1,176,408 
639,025 



1,468,494 



108,658 



94,233 



1,794 

53,869 

131 

52,864 

417,044 



802 
16,193 

756 
76,482 

930,410 



13,207 
398,939 



445,376 



12,449 

6,961 

911,000 



176,551 
114,761 



53,376 
61,385 



4,051 
150,013 



99,425 
176,224 



41,883 
134,341 



3,773 
164,429 



36,222 



28,670 



33.398 
2,824 



22,803 
5,867 



30,354 
74,274 
4,610 



15,244 

115,588 

2,307 



Per 

pound 
$1,330 



1.537 
1.066 



.447 

.301 

5.771 

1.447 

2.231 



2.542 

.527 

2.284 



.563 
1.536 



.785 
2.188 



.931 
1.096 



.683 
2.078 



.502 

1.556 

.500 



See footnotes on following page. 



186 SYNTHETIC ORGANIC CHEHICALS, 1974 

Footnotes for table 1 

' Calculated from rounded figures. 

^ Includes benomyl , captafol , captan, chlorothalonil , dinocap, DMT, folpet, pentachloronitrobenzene, sodium 
pentachlorophenate, tri- and tetra-chlorophenols (including 2,4,5-trichlorophenol and its salts), all other 
phenylmercury compounds, and others. 

' Includes alachlor, atrazine, barban, benefin, bensulide, CDMA, 2,4-D, acid, esters, and salts, 2,4-DB, dicamba, 
dimethylurea compounds, dinitrophenol compounds, isopropyl phenylcarbamates (IPC and CIPC) , MCPA, molinate, NPA, 
picloram, propanil, silvex and its esters, 2,4,5-T acid esters and salts, triazines, trifluralin, uracils, and 
others. 

'* Includes aldrin, chlordan, dieldrin, endrin, heptachlor, and toxaphene. 

^ Includes carbophenothion, coumaphos, diazinon, dioxathion, fensulfotliion, parathion, ronnel, and other 
phosphorothioates and phosphorodithioates, and others. 

^ Includes carbaryl, carbofuran, chlorinated insecticides (BHC + lindane, chlorobenzilate, DDT, dicofol, endo- 
sulfan, and others), insect attractants, DEET and other insect repellents, small amounts of rodent icides, piperonyl 
butoxide and other synergists, and others. 

' Includes ferbam, maneb, nabam, PETD and zineb, plus the remaining dithiocarbamates which are used chiefly as 
fungicides. 

' Includes dodine, and others. 

' Includes cacodylic acid, CDAA, dalapon, methanearsonic acid salts, sodium TCA, thiocarbonate, thiolcarbonate, 
and organophosphorus herbicides, and others. 

'° Includes dichlorvos, dimethoate, disulfoton, ethion, malathion, monocrotophos, naled, phorate, and other organo- 
phosphorus insecticides. 
" Includes DBCP, soil conditioners and fumigants, methomyl, aldicarb, small quantities of rodenticides, and others. 

Note. --Does not include data for the insect fumigant, p-dichlorobenzene nor the fungicide, o-phenylphenol. These 
data are included in the report on cyclic intermediates. 



PESTICIDES AND RELATED PRODUCTS i87 

TABLE 2, --Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974 

[Pesticides and related products for which separate statistics are f;iven in table 1 are marked below with an 
asterisk (*); chemicals not so marked do not appear in table 1 because the reported data are accepted in confidence 
and may not be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies 
that the manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICinF.S AND RELATED PROnUCTS, CYCLIC 

'Fungicides : 

2,6-Bis(dimethylaminomethyl)cyclohexanone 

4-Bromoacetoxymethyl-ni-dioxolane 

2 ' -Bromo-4 ' -hydroxyacetophenone 

Cyanomethylthiobenzothiazole 

2,4-Dichloro-6-Co-chloroanilino) -s-triazine 

l,4-Dichloro-2,5-dimethoxybenzene (Chloroneb) 

l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline 

(Ethoxyquin) . 
3,5-Dimethyl-l ,3,5-2H-tetrahydrothiadiazine-2-thione 

CDMTT) . 

5-Ethoxy-3-(trichloromethyl)-l,2,4-thiadiazole 

Hexahydro- 1, 3, 5 -trie thy 1- s-triazine 

Mercury fungicides: 
*Phenylmercuric acetate (PMA) 

Phenylmercuric ammonium acetate 

Phenylmercuric hydroxide 

Phenylmercuric lactate 

Phenylmercuric oleate 

Phenylmercuric propionate 

Methyl l-(butylcarbanoyl)-2-benzimidazole carbamate 

(Benomyl) . 
2- [l-Methyl-n-heptyl)-4,6-dinitrophenyl crotonate 

(Dinocap) . 
3-(2-Methylpiperidino)propyl-3,4-dichlorobenzoate 

(Piperalin) . 

*Naphthenic acid, copper salt 

lO.lO'-Oxybisphenoxarsine 

Pentachloronitrobenzene (PCNR) 

*Pentachlorophenol (PCP) 

Pentachlorophenol , sodium salt 

8-Quinolinol (8-Hydroxyquinoline5 , copper salt 

cis-N-[(l,l,2,2-Tetrachloroethyl)thiol-4-cvclohexene- 

1 ,2-dicarboximide (Captafol) . 

2,4,5,6-Tetrachloroisophthalonitrile 

2,3,4,6-Tetrachlorophenol 

N-Trichloromethylthio-4-cyclohexene-l,2-dicarboximide 

(Captan) . 

N-Trichloromethylthiophthalimide (Folpet) 

2,4,5-Trichlorophenol acid and salts: 

2,4,5-Trichlorophenol 

2,4,5-Trichlorophenol, ethanolamine salt 

2,4,5-Trichlorophenol, sodium salt 

2,4 ,6-Trichlorophenol 

1 ,3,5-Tris ( 2- isopropanol) -s-triazine 

*Herbicides and plant hormones: 

3-Amino-2 ,5-dichlorobenzoic acid, ammonium salt 

4- Amino-6- ( 1 , 1 -dimethy lethy 1) -3- (methylthio) -1,2,4- 

triazin-5(4H)-one (Metribuzin) . 

4-Amino-3,S,6-trichloropicolinic acid (Picloram) 

2,4-Bis(isopropyl amino) -6-methoxy-s-triazine 

tPrometon) . 
2, 4- Bis(isopropyl amino) -6-methylthio)- s-triazine 

(Prometryn) . 

5-Bromo-3-sec-butyl-6-methyluracil (Bromacil) 

2- tert -Butylamino-4-chloro-6-e thy 1 amino- s-triazine 

2-tert-Butylamino-4-ethylamino-6-nethoxy-s-triazine--- 
2-tert-Butylamino-4-ethylamino-6-methylthio-5- 

triazine. 
3-tert-Butyl-5-chloro-6-methyluracil (Terbacil) 



CHG. 
DUP. 
MOM. 



DMC. 
TOC. 

CLY, MRK, TRO. 

TRn. 

TRO. 

TRO. 

TRO. 

MRK . 

DUP. 

RH. 



CCA, 


FER, 


MCI, TRO 


SAL. 






nuc. 






DOW, 


FRO, 


MON, RCI 


DOW, 


RCI. 




ASH. 






ORO. 






DA. 






DOW. 






SFA, 


SrC. 




SFA, 


SFC. 




DOW. 






CAP. 






DOW. 






DOW. 






EFll. 
AMC, 


GAF. 




CHC. 






DOW. 






cr,Y. 







ACN, 
CGY. 
CGY. 
CGY. 



58 SYNTHETIC ORGANIC CHEniCALS. 1S74 

TABLE 2. --Pesticides and related products for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 197^--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CYCLlC--Continued 

'Herbicides and plant hormones — Continued 

N-Butyl-N-ethyl-a,a,a-trifluoro-2,6-dinitro-p- 

toluidine (Benefin). 

2-Butynyl-4-chloro-m-chlorocarbanilate (Barban) 

2-Chloro-4 ,6-bis (ethylamino) -s-triazine (Simazine) 

2-Chloro-4,6-bis (isopropylamino) -s-triazine 

(Propazine) . 
2-Chloro-4-cyclopropylamino-6-isopropylariino-s- 

triazine. 
2-Chloro-2' ,6 '-diethyl-N- (n-butoxymethyl)acetani lide 

CButachlor) . 
2-Chloro-2 ' ,6 '-diethyl-N- (metho.xyne thy 1) ace tani lide 

(Alachlor) . 
2-Chloro-4-e thy lamino-6-isopropyl amino- s-triazine 

(Atrazine) . 
2- (4-Chloro-6-ethylamino-s-triazin-2-ylamino) -2- 

methylpropionitrile CCyanazine) . 

2-Chloro-N-isopropylacetanilide (Propachlor) 

4-Chloro-5- (methylamino] -2-Ca,a,a-trif luoro-m-tolyl) - 

3(2H)-pyridazinone (Norflurazon) . 

4- (4-Chloro-2-iTiethylphenoxy)butyric acid 

3- (p-Chlorophenyl)-l, 1- dime thy lurea (Monuron) 

3- (p-Chlorophenyl) -1,1-dimethylurea trichloroacetate- 
3,5-Dibromo-4-hydroxybenzoylnitrile, octanoic acid 

ester (Bromoxynil octanoate) . 

3,6-Dichloro-2-anisic acid (Dicamba) 

2,4-Dichlorobenzyltributylphosphonium chloride 

2,5-Dichloro-6-nitrobenzoic acid, sodium salt 

4- (2,4-Dichlorophenoxy)butyric acid (2,4-nB) 

3- (3, 4- Dichlorophenyl)- 1,1-dimethylurea (Diuron) 

3- (3, 4- Dichlorophenyl) -1-methoxy-l-methylurea 

(Linuron) . 

2,4-Dichlorophenyl p-nitrophenyl ether 

3' ,4 ' -Dichloropropionanilide (Propanil) 

N ^n' -Die thy 1-2, 4-dinitro-6-tri fluoromethy 1-1,3- 

phenylenediamine (Dinitroamine) . 
*1 ,2-Dihvdronvridazine-3,6-dione (Haleic hvdrazide) 

(^^H) . 
N-(e-u,0,-Diisopropyl-dithiophosphorylethyl) benzene 

sulfonamide CBensulide) . 

N,N-Dimethyl-2 ,2-diphenylacetamide (Diphenamid) 

N- (l,l-Dimethyl-2-propynyl)3,5-dichlorobenzamide 

(Pronamide) . 

Dimethyl-2,3,5,6-tetrachloroterephthalate (DCPA) 

Dinitrobutylphenol (DNBP) 

Dinitrobutylphenol , ammonium salt 

Dinitrobutylphenol, triethanolamine salt 

Dinitrocresol, sodium salt 

2 ,6-Dinitro-N,N-dipropylcumidine (Isopropalin) 

2-Ethylamino-4-isopropylamino-6-methylmercapto-s- 

triazine (Ametr\T\) . 

S- Ethyl Ccyclohexyl)ethylthiocarbamate 

S-Ethyldiethylthiocarbamate 

S- Ethyl hexahydro-lH-azepine-1-carhothioate 

(Molinate) . 
2-Ethylthio-4,6-bis(isopropylamino) -s-triazine 

(Dipropetryn) . 

Gibberellic acid 

3-lndolebutyric acid 

Isopropyl N- (3-chlorophenyl) carbamate (CIPC) 

Isopropyl N-phenylcarbamate (IPC) 



GOC. 
CCY. 
CGY. 

nnc. 

MOM. 

HON. 

CGY, VTC. 

CGY. 

MON. 
S. 

RDA. 

niip. 

ACN. 
RDA. 

VEL. 

SM. 

GAP. 

RDA. 

DUP. 

DUP. 

RII. 
EGR, RH. 

X. 

ACY, ASL, FMT, USR. 

SFA. 

CIVN. 
Rli. 

DA. 

Dnw. FfIN, VTC. 

nnw, FUN. 
Dnn, FUN. 

FMN. 
LIL. 
CGY. 

SFA. 
GOC. 
SFA. 



ARA. 
PPG. 

PPG. 



PESTICIDES AND RELATED PRODUCTS isg 

TABLE 2.— Pesticides and related products for which U,S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'4--C0NTINUED 



Chemi cal 




Manufacturers ' 


identification codes 






( 


according to 


list in table 3) 


pesticides and RELATED PRODUCTS, CYCLIC--Continued 










♦Herbicides and plant hormones — Continued 










l-(2-Methylcyclohexyl) -.'^-phenylurea CSiduron) 


DUP. 








Methyl 5- (2 ' ,4 ' -dichlorophenoxy) -2-nitrobenzoate 


SH. 








4-Methyl-l-pivaloyl-3-thiosemicarbazide 


LIL. 








4-(Methylsulfonyl) -2,6-dinitro-N,N-dipropvlaniline 


sue. 








(Nitralin). 










1-Naphthaleneacetic acid and derivatives: 










1-Naphthaleneacetic acid 


AMC. 








1-Naphthaleneacetic acid, sodium salt 


BKL. 








1 ,8-Naphthalic anhydride 


Gnc. 








N-l-Naphthylphthalamic acid (NPA) 


USR. 








7-Oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid, di- 


PAS. 








sodium salt (Endothall). 










Phenoxyacetic acid derivatives: 










4-Chloro-2-methylphenoxyacetic acid (MCPA) 


CLY, 


RDA, 


THH. 




2 ,4-Dichlorophenoxyacetic acid (2,4-D) 


Dnw, 


HON, 


RDA. 




2,4-Dichlorophenoxyacetic acid esters and salts: 










2,4-Dichlorophenoxyacetic acid, 2-butoxyethanol 


DOW. 








ester. 










2,4-Dichlorophenoxyacetic acid, butoxypolypropy- 


DOW . 








leneglycol ester. 










2,4-Dichlorophenoxyacetic acid, n-butyl ester 


RDA, 


RIV. 






2,4-Dichlorophenoxyacetic acid, sec-butyl ester 


DOW. 








*2,4-Dichlorophenoxyacetic acid, dimethylaraine 


DON, 


RDA, 


RIV, THH. 




salt. 










2,4-Dichlorophenoxyacetic acid, ethanolamine and 


DOW . 








isopropanolanine salt. 










2,4-Dichlorophenoxvacetic acid, iso-octyl ester 


DOW, 


RDA, 


RIV. 




2,4-Dichlorophenoxyacetic acid, isopropyl ester 


DOW, 


RIV. 






2,4-Dichlorophenoxyacetic acid, lithium salt 


GTH. 








2,4-Dichlorophenoxyacetic acid, sodium salt 


DOW, 


GTH, 


RIV. 




2,4,5-Trichlorophenoxyacetic acid esters and salts: 










2,4,S-Trichlorophenoxyacetic acid, 2-butoxyethanol 


DOW. 








ester. 










2,4,5-Trichloropheno.xyacetic acid, butoxypoly- 


DOW. 








propyleneglycol ester. 










2,4,5-Trichlorophenoxyacetic acid, sec-butyl 


DOW. 








ester. 










2,4,S-Trichlorophenoxyacetic acid, iso-octyl 


DOW, 


RIV, 


TIBI. 




ester. 










Polychloro-tetrahydro-methanoindene (Polychlorodicyclo- 


VEL. 








pentadiene) isomers. 










2-(2,4,5-Trichlorophenoxy)propionic acid (Silvexl 


TfOl. 








2-(2,4,5-Trichlorophenoxy5propionic acid esters and 










salts: 










2-(2,4,5-Trichlorophenoxy)propionic acid, butoxypoly- 


DOW. 








propylene glycol ester. 










2-C2,4,5-Trichlorophenoxy)propionic acid, dimethyl- 


RIV. 








amine salt. 










2-(2,4,S-Trichlorophenoxy)propionic acid, iso-octyl 


DOW, 


RIV. 






ester. 










a,a,a-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine 


LIL. 








(Trifluralin) . 










All other cyclic herbicides 


CWN, 


X. 






Insect attractants and repellents: 










tert-Butyl 4(and 5) -chloro-2-methylcyclohexanecarboxy- 


UOP. 








late (Trimedlure) . 










N M-Pli *st-hv 1 t-nl iiami r1^ fflFFTI — — 


HPC, 


PFZ. 






IN , iN-uietny itoiuami oe i^utn i j 






MCK. 








ui -n-propy iisocincnomeronate 





SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 2, --Pesticides and related products for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--CoNTINUED 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued 

Insecticides ; 

3 -sec- Amy Iphenyl-N-methyl carbamate 

5-Benzyl-3-furylmethyl-2,2-dimethyl-3-(2-niethyl- 
propenyl) cyclopropane carboxylate (Resmethrin) . 

Bacillus thuringiensis 

2-sec-Butyl-4,6-dinitrophenyl-3,3-dimethylacrylate 

(Binapacryl) . 
2- Cp-tert-Butylphenoxy) cyclohexyl-2 ' -pronynyl sulf ite-- 

o-sec-Butylphenyl-N-methylcarbamate 

Chlorinated insecticides: 
*Aldrin-toxaphene group: 

Heptachloro-tetrahydro-endo-methanoindene 

(Heptachlor) . 
Hexachloro-epoxy-octahydro-endo, endo-dinethano- 

naphthalene (Endrin) . 
Hexachloro-epoxy-octahydro-endo, exo-dimethano- 

naphthalene (Dieldrin) . 
Hexachloro-hexahydro-endo, exo-dimethanonaphthalene 
(Aldrin) . 

Octachloro-hexahydro-methanoindene CChlordan) 

Toxaphene (Chlorinated camphene) 

a-Bis(p-chlorophenyl)B,B,B-trichloroethane (DDT) 

o-Chlorophenyl-N-methylcarbamate 

p-Chlorophenyl 2,4,5-trichlorophenyl sulfone 
(Tetradifon) . 

1, 1 -Dichloro- 2, 2-bis(p-ethylphenyl) ethane 

4,4'-Dichloro-a-trichloromethylbenzhydTOl (Dicofol) -- 
Dodecachlorooctahydro-l,3,4-metheno-2H-cyclobuta-[cd] 
pentalene (Hirex) . 

Ethyl 4,4' -dichlorobenzilate (Chlorobenzilate) 

Hexachlorocyclohexane (Benzene hexachloride) (BHC) 

Hexachlorocyclohexane, 100% y-isomer (Lindane) 

Hexachloro-hexahydro-methano-benzodioxathiepin- 

3-oxide (Endosulfan) . 
* 1 , 1 , l-Trichloro-2 , 2-bi5 (p-raethoxyphenyl) ethane 
(Methoxychlor) . 
2,3-Dihydro-2,2-dimethyl-7-benzofuranyl methyl- 

carbamate (Carbofuran) . 
ra-[ [(Diinethylamino)methylene]amino]phenyl methyl- 
carbamate. 

m-(l-Ethylpropyl) phenyl methylcarbamate 

m- Cl-Methylbutyl)phenyl methylcarbamate 

1-Naphthyl N-methylcarbamate (Carbaryl) 

*Organophosphorus insecticides: 

0-(4-Bromo-2,5-dichlorophenyl) 0-methylphenyl- 

phosphonothioate (Leptophos) . 
4-tert-ButyI-2-chlorophenyl methyl methylphos- 

phoramidite (Crufomate) . 
S-[[(p-Chlorophenyl)thio]methyl]0,0-diethyl phos- 

phorodithioate (Carbophenothion) . 
2-Chloro-l- (2,4,5-trichlorophenyl) vinyl dinethyl- 

phosphate. 
2- (Diethoxyphosphinylimino)-4-methyl-l,3- 

dithiolane. 
0,0 -Diethyl 0-3-chloro-4-methyl-l-oxo-2H-l-benzo- 

pyran-7-yl-phosphorothioate (Coumaphos) . 
0,0-Diethyl S-(2-Chloro-l-phthalimidoethyl) - 
phosphorodithioate . 



Manufacturers' identification codes 
(according to list in table 3) 



ABB, S. 

FMN. 



USR . 

nTC. 



VEL. 

VEL. 

SHC. 

SHC . 

VEL. 

HN, HPC, VTC. 

urn. 

OTC. 

FMM. 

RH. 
RH. 
ACN. 

CCY. 
HK. 

ACN, HK. 
HK. 

ACN, CHF, DUP, EGR. 

FflN. 



ORG. 
ORO. 
UCC. 

VEL. 

Dnw . 

SFA. 
SHC. 
ACY, X. 
CHC . 
HPC. 



PESTICIDES AND RELATED PRODUCTS ^^■ 

TABLE 2,— Pesticides and related products for which II. S, production or sales were reported^ 

IDENTIhlED BY ^"^ ANUFACTURER, 1974--C0NTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, CYCLIC--Continued 

Insecticides --Continued 

*Organophosphorus insecticides --Continued 

0,0 -Diethyl 0- (2-isopropyl-4-methyl-6-pyriniidinyl) - 

phosphorothioate (Diazinon) . 
0,0-Diethyl 0- [p- (niethylsulfinyl)phenyl] phosphoro- 
thioate (Fensulfothion) . 
0,0-Diethyl 0-p-nitrophenyl phosphorothioate 

(Parathion) . 
0,0-Diethyl 0-3,5,6-trichloro-2 pyridyl phosphoro- 
thioate. 
OjO-Dimethyl 0-[4- (methylthio) -m-tolyl]phosphoro- 
thioate (Fenthion) . 
*0,0-Dimethyl O-p-nitrophenyl phosphorothioate (Methyl 
parathion) . 
0,0-Diraethyl S- [4-oxo-l,2,3-benzotriazin-3(4H)- 
ylmethyl] phosphorodithioate (Azinphos -methyl) . 
Dimethyl 2,4,S-trichlorophenyl phosphorothionate 

(Ronnel) . 
2,3-p-Dioxane S,S-bis(0,0-diethylphosphorodithioate) 

(Dioxathion) . 
0-Ethyl 0-p-nitrophenylphenylphosphonothioate 
(EPN) . 

0-Ethyl S-phenylethylphosphonodithioate (Fonofos) 

2-Imino-l,3-dithiolane, dihydrogen sulfate 

a-Methylbenzyl 3- (dimethoxyphosphinyloxy) -cis- 

crotonate. 
0,0,0' ,0'-Tetramethyl 0,0' -thiodi-p -phenyl ene 
phosphorothioate . 

All other organophosphorus insecticides 

N-Cl-Phenyl-2-nitropropyl)piperazine 

All other cyclic insecticides 

Nematocides : 

0,0-Diethyl 0- (2,4-dichlorophenyl) phosphorothioate 
(Dichlofenthion) . 
Rodenticides : 

3- (a-Acetonylbenzyl)-4-hydroxycoumarin (Warfarin) 

2-Diphenylacetyl-l ,3-indandione and sodium salt 
(Diphacinone) . 

2-Pivaloyl-l,3-indandione and salts (Pindone) 

Synergists and adjuvants: 

a- [2-(2-n-Butoxyethoxy)-ethoxy] -4,S-methylenedioxy-2- 

propyltoluene (Piperonyl butoxide) . 
N-(2-Ethylhexyl)bicyclo(2.2.1)-5-heptene-2,3-di- 

carboximide. 
Piperonal his [2- (2' -n-butoxyethoxy) ethyl ]acetal 
(Heliotropin acetal) . 
All other cyclic pesticides and related products 

PESTICIDES AND RELATED PRODUCTS, ACYCLIC 

*Fungicides : 

Bis-I,4-bromoacetoxy-2-butene 

Cadmium sebacate 

Cadmium succinate 



CCY. 

CMC. 

MON. SFA. 

DOW. 

CHG. 

AflP, HON, SFA, VTC. 

CHC. 

DOW. 

HPC. 

SFA. 

SFA. 
ACY, X. 
SHC. 



SFA. 
HRK. 
PLC. 



MOT. 
NES. 

MOT, PIC, RSA. 

ALP, BKL, FMN, FMP. 

MCK. 

MGK. 



VIN. 
MAL. 
MAL. 



SYNTHETIC ORGA^lIC CHEHICALS, 197^1 
TABLE 2. --Pesticides and related products for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1974--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



PESTICIDES AND RELATED PRODUCTS, ACYCLIC--Continued 

•Fungicides --Continued 

Chloromethoxypropylmercuric acetate 

l-Chloro-2-nitropropane 

Copper tallate 

Di sodium cyanodithioimidocarbonate 

*Dithiocarbamic acid fungicides: 

Dimethyldithiocarbamic acid, ferric salt (Ferbam) 

Dimethyldithiocarbamic acid, manganese salt 

Dimethyldithiocarbamic acid, potassium salt 

Ethylene bis (dithiocarbamic acid), disodium salt 
(Nab am) . 

Ethylene bis (dithiocarbamic acid), manganese salt 
(Maneb) . 

Ethylene bis (dithiocarbamic acid), manganese salt 
with zinc ions. 

Ethylene bis (dithiocarbamic acid), zinc salt 
(Zineb) . 

Polyethylenethiuram disulfide (PETD) 

All other dithiocarbamic acid fungicides 

n-Dodecylguanidine acetate (Dodine) 

2-Hydroxypropylmethanethiol sulfonate (HPflTS) * 

Metliylene bis(thiocyanate) 

•Herbicides and plant hormones: 

N,N-Bis(phosphonome thy 1) glycine 

N,N-Bis (phosphonomethyl) glycine, isopropylamine salt 

2-Chloroallyl diethyldithiocarbamate (CDEC) 

2-Chloro-N,N-diallylacetamide (CDAA) 

(2-Chloroethyl)phosphonic acid 

(2-Chloroethyl) trimethyl ammonium chloride 

S-2 ,3-Dichloroallyl diisopropylthiolcarbamate 

(Diallate). 

2 , 2-Dichloropropionic acid, sodium salt (Dalapon) 

N-Dimethylaminosuccinamic acid (DMSA) 

Dimethylarsinic acid (Cacodylic acid) 

S-Ethyl diisobutylthiocarbamate (Butylate) 

S-Ethyl dipropylthiocarbamate (EPTC) 

Ethyl xanthogen disulfide (EXD) 

Methanearsonic acid, disodium salt (DSHA) 

Methanearsonic acid, dodecyl- and octylammonium salts-- 

Methanearsonic acid, monosodium salt (MSftA) 

Poly [oxye thy lene(dimethylimino) ethylene -(dimethylimino) 

ethylene dichloride] . 

S-Propyl butylethylthiocarbaraate (Pebulate) 

S-Propyl dipropylthiocarbamate (Vemolate) 

S,S,S-Tributyl phosphorotrithioate 

Tributyl phosphorotrithioate (Merphos) 

Trichloroacetic acid, sodium salt (TCA) 

S-2 ,3,3-Trichloroallyl diisopropylthiolcarbamate 

(Triallate) . 

All other acyclic herbicides 

•Insecticides : 

2- (2-Butoxyethoxy)ethyl thiocyanate 

S -Methyl N- [ (methylcarbamoyl)oxy] thioacetimidate 

(Me thorny I) . 
*Organophosphorus insecticides: 

S- [l,2-Bis(ethoxycarbonyl)ethyl] 0,0 -dimethyl 
phosphorodithioate (Halathion) . 

2-Carbomethoxy-l-propen-2yl dimethyl phosphate 
(Mevinphos) . 

l,2-Dibromo-2,2-dichloroethyl dimethyl pliosphate 
(Naled) . 



TRO. 

FMN. 
AMP. 



FflN. 
FMN. 
BKH. 
ALC, 



Rll, USR, VCC. 



DUP, RH. 



FMN. 
VNC. 
ACY. 



Mon. 

MON. 
GAF. 
ACY. 

MON. 

DOW . 

USR. 

ASL. 

SFA. 

SFA. 

RBC. 

ASL, CLY, VIN. 

CLY. 

ASL, DA. 

BKH. 

SFA. 

SFA. 

PLC. 

SM. 

DOW. 

MON. 

LIL, SFA. 

Rll. 
DUP. 



ACN, ACY. 
SHC. 

sue. 



PESTICIDES AND RELATED PRODUCTS is 

TABLE 2, --Pesticides and related products for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, I974--CONTI NUED 







Manufacturers' identification codes 


Chemical 




(according to list in table 3) 


PESTICIDES AND RELATED PRODUCTS, ACYCLIC--Continued 






*Insecticides--Continued 






♦Organophosphorus insecticides — Continued 






0,0-Diethyl S-2-(ethylthio)ethyl phosphorodithioate 


CHG. 




(Disulfoton) . 






0,0-Diethyl 0-2- (ethylthioO ethyl phosphorothioate 


CHG. 




(Demeton 0) . 






0,0-Diethyl S-(ethylthio)methyl phosphorodithioate 


ACY. 




(Phorate) . 






3-(Dimethoxyphosphinyloxy)-N,N-diniethyl-cis- 


SHC. 




crotonamide (Dicrotophos) . 






0,S-Dimethylacetylphosphorainidothioate (Acephate) 


ORO. 




0,0-Dimethyl 2,2-dichlorovinyl phosphate CDi- 


SHC. 




chlorvos) . 






0,0-DimethyI S- [2- (ethylsulfiny I) ethyl] phosphoro- 


CHG. 




thioate (Oxydemetonmethyl) . 






0,0-Dimethyl S- (N-methylcarbainoylmethyl)phosphoro- 


ACY. 




dithioate (Diraethoate) . 






Dimethyl phosphate of 3-hydroxy-N-methyl-cis 


SHC. 




crotonaraide (Monocrotophos) . 








CHG. 




u ,o-uimetny 1 pnospnorainiaotnioate 




0,0,0' ,0'-Tetraethyl S,S' -methylene bis-phosphoro- 


FUN, 


FHP. 


dithioate (Ethion) . 








SFA. 




u,u,u ,u - letra-n-propyi aitniopyropnospnate 




All other acyclic insecticides 


ARJ^, 


PLC. 


Nematocides : 








SM. 




U-bthyl o,b-aipropyi pnospnoroditnioate-— 




2-Methyl-2- (piethylthio)propionaldehyde 0-(methylcarba- 


IICC. 




moyl)oxinie (Aldicarb) . 






Soil conditioners: Polyacrylonitrile, hydrolyzed. 


ACY, 


NLC. 


sodium salt. 






Soil fumigants; 








DOW , 


SHC. 


1 , i-uiDromo- j-cn ioropTopdne \^uD*^r j — 






DOW. 




i , J- uicnioropropene 






DOW, 


SHC. 


i , .3-uicnioropropene ana i,z-aicnioropropane 






AflP, 


nnv/ GTL MCH . 


Metny i oroniiae i^Kromometnanej 




N-Methyldithiocarbamic acid, sodium salt (flethara) 


SFA. 






MRT. 




Metnj i isotniocyanate — — " 






DOW, 


NLO, SBN. 


In en ioroni trometnane (.Lni oropicrm j 




All other acyclic pesticides and related products 


PCW, 


PLC, RBC, TRO. 



SYNTHETIC ORGANIC CHEMICALS. 1974 
TABLE 3. --Pesticides and related products; Directory of manufacturers, 1974 



ALPHABETICAL DIRECTORY BY CODE 

[Names of manufacturers of pesticides and related products that reported production or sales to the U.S. International 
Trade Commission for 1974 are listed below in the order of their identification codes as used in table 2] 



Code 


Name of company 


Code 


Name of company 


ABB 


Abbott Laboratories 


MAL 


Mallinckrodt Chemical Works 


ACN 


Allied Chemical Corp., Union Texas 


MCH 


Michigan Chemical Corp. 




Petroleum Div., Agricultural Dept. 


MCI 


Mooney Chemical Corp. 


ACY 


American Cyanamid Co. 


MGK 


McLaughlin, Gormley 5 King Co. 


ALC 


Alco Chemical Corp. 


MON 


Monsanto Co. 


ALP 


Alpha Laboratories, Inc. 


MOT 


Motomoco, Inc. 


AMC 


Amchem Products, Inc., 


MRK 


Merck 5 Co., Inc. 




Div. of Rorer-Amchem, Inc. 


MRT 


Morton Chemical Co. Div. of Morton-Norwich 


AMP 


Kerr-McGee Chemical Corp. 




Products, Inc. 


ARA 


Arapahoe Chemical, Inc. Sub. of 
Syntex Corp. (U.S. A. 5 


MTO 


Montrose Chemical Corp. of California 


ASH 


.Ashland Oil, Inc., Ashland 


NES 


Nease Chemical Co., Inc. 




Chemical Co. Div. 


NLC 


Nalco Chemical Co. 


ASL 


Ansul Chemical Co. 


NLO 


Niklor Chemical Co. 


BKL 


Millmaster Onyx Corp., Millmaster Chemical 


OMC 


Olin Corp. 




Co. Div., Berkeley Chemical Dept. 


ORO 


Chevron Chemical Co. 


BKM 


Buckman Labs., Inc. 


OTC 


Story Chemical Corp. 


CCA 


Interstah Chemical, Inc. 


PAS 


Pennwalt Corp. 


CGY 


Ciba-Geigy Corp. , 


PCW 


Pfister Chemical , Inc. 




Ciba Agricultural Co. 


PEN 


CPC International, Inc., Penick Div. 


CHF 


Chemical Formulators, Inc. 


PFZ 


Pfizer, Inc. 


CHG 


Mobay Chemical Corp., Chemagro Agricultural 


PIC 


Pierce Organics, Inc. 




Div. 


PLC 


Phillips Petroleum Co. 


CLY 


W. A. Cleary Corp. 


PPG 


PPG Industries, Inc. 


cm 


Upjohn Co., Fine Chemical Div. 










RBC 


Fike Chemicals, Inc. 


DA 


Diamond Shamrock Corp. 


RCI 


Reichhold Chemicals, Inc. 


DOW 


Dow Chemical Co. 


RDA 


Rhodia, Inc. 


DUP 


E. I. duPont de Nemours 5 Co., Inc. 


RH 


Rohm 6 Haas Co. 






RIV 


Riverdale Chemical Co. 


EFH 


E. F. Houghton § Co. 


RSA 


R.S.A. Corp. 


EGR 


Eagle River Chemical Corp. 










S 


Sandoz Corp., Crop Protection Dept. 


FER 


Ferro Corp., Ferro Chemical Div. 


SBN 


Sobin Chemical Co. 




FMC Corp . : 




Stauffer Chemical Co. : 


FMN 


Agricultural Chemical Div. 


SFA 


Agricultural Div. 


FMP 


Industrial Chemical Div. , 


SFC 


Calhio Chemicals, Inc. Div. 




Organic Busiiess Group 


SHC 


Shell Oil Co., Shell Chemical Co. Div. 


FMT 


Fairmount Chemical Co. 


SM 


Mobil Oil Corp., Mobil Chemical Co. Div. 


FRO 


Vulcan Materials, Co., Chemical Div. 










TMH 


Thompson-Hayu'ard Chemical Co. 


GAF 


GAF Corp., Chemical Div. 


TRO 


Troy Chemical Corp. 


GOC 


Gulf Oil Corp., Gulf Oil 








Chemical Co. - U.S. 


UCC 


Union Carbide Corp. 


gth 


Guth Chemical Co. 


UOP 


Universal Oil Products Co., UOP Chemical 


gtl 


Great Lakes Chemical Corp. 




Div. 






USR 


Uniroyal, Inc., Chemical Div. 


HK 


Hooker Chemicals § Plastics Corp. 






HN 


Tenneco Chemicals, Inc. 


VCC 


Vinings Chemical Co. 


HPC 


Hercules, Inc. 


VEL 


Velsicol Chemical Corp. 






VIN 


Vineland Chemical Co. 


LAK 


Lakeway Chemicals, Inc. 


VNC 


Vanderbilt Chemical Corp. 


LIL 


Eli Lilly 5 Co. 


VTC 


Vicksburg Chemical Co. Sub. of Vertac 
Consolidated. 






WTC 


H'itco Chemical Co., Inc. 



Note. --Complete names and addresses of the above reporting comrianies are listed in table 1 of the appendi 



MISCELLANEOUS CHEMICALS 195 

MISCELLANEOUS CHEMICALS 

The term miscellaneous chemicals comprises those synthetic organic 
products that are not included in the use groups covered by the other 
preliminary reports in the 1974 series. They include products that are 
employed in a great variety of uses. The number of chemicals used ex- 
clusively for only one purpose is not large. Among the products covered 
are those used for gasoline and lubricating oil additives, paint driers, 
photographic chemicals, tanning materials, flotation reagents, refriger- 
ants, textile polymers, sequestering agents, organic fertilizers, anti- 
freeze chemicals, solvents, and acyclic intermediates. This report presents 
statistics on U.S. production and sales of miscellaneous chemicals in as 
great detail as is possible without revealing the operations of individual 
producers. 

Production of miscellaneous cyclic and acyclic chemicals in 1974 
totaled over 100.6 billion pounds, or 1.9 percent more than the output of 
98.7 billion pounds reported for 1973. Sales of miscellaneous chemicals 
in 1974 amounted to 47.4 billion pounds, valued at $7.8 billion, compared 
with 49.6 billion pounds, valued at $5.3 billion in 1973. 

The total output of miscellaneous cyclic chemicals in 1974 was 3.6 
billion pounds, or 20.0 percent more than the output of 3 billion pounds 
reported for 1973. Sales in 1974 totaled over 1.3 billion pounds, valued 
at $674 million, compared with 1.4 billion pounds, valued at $511 million 
in 1973. In 1974, the most important cyclic compound was polyethylene 
terephthalate, the output of which was 1.9 billion pounds. The lubricating 
oil and grease additives group output decreased from 535 million pounds 
in 1973 to 490 million pounds in 1974. 

Total production of miscellaneous acyclic chemicals in 1974 was 97.0 
billion pounds, or 1.4 percent more than the output of 95.7 billion pounds 
reported for 1973. Sales in 1974 totaled 46.1 billion pounds, valued at 
$7.1 billion, compared with 48.2 billion pounds, valued at $4.8 billion, 
in 1973. The statistics for acyclic chemicals are grouped primarily by 
chemical function. The order of precedence of these functional groups is 
generally that used in naming and indexing chemical compounds by Chemical 
Abstracts , but other important considerations are comparability with other 
statistics and the need for groupings that will not reveal the operations 
of individual producers. 

In 1974, the most important groups of acyclic chemicals were the 
halogenated hydrocarbons, the nitrogenous compounds, monohydric alcohols, 
and aldehydes and ketones. Production of halogenated hydrocarbons, which 
are used as solvents, intermediates, refrigerants, and aerosol propellants, 
totaled 23.1 billion pounds. The most important chemicals in this group 
were dichloroethane (production of 9.2 billion pounds in 1974, compared 
with 9.3 billion pounds in 1973) and vinyl chloride (5.6 billion pounds 



196 SYNTHETIC ORGANIC CHEMICALS, 197^ 



in 1974, compared with 5.4 billion pounds in 1973). Output of nitrogenous 
compounds totaled 17.6 billion pounds. The most important chemical in this 
group was urea (used principally in fertilizers and as a feed additive), 
production of which was 7.6 billion pounds in 1974 and 7.1 billion pounds 
in 1973. 

Monohydric alcohols, which are used largely as solvents and inter- 
mediates, were the third largest group in 1974, with production of 14.6 
billion pounds. The most important items in the group in terms of pro- 
duction were synthetic methanol [6.9 billion pounds in 1974, compared with 
7.1 billion pounds in 1973), synthetic ethyl alcohol (1.6 billion pounds 
in 1974, compared with 2.0 billion pounds in 1973), and isopropyl alcohol 
(1.9 billion pounds in 1974, compared with 1.8 billion pounds in 1973). 
Aldehydes and ketones, which are also used largely as solvents and inter- 
mediates, were the next largest group with production of 12.6 billion 
pounds. The most important items in this group in 1974 were formaldehyde 
(5.8 billion pounds) and acetone (2.0 billion pounds). 



MISCELLAIIEOUS CHEMICALS 



TABLE l.--f1lSCELLAME0LJS CHEMICALS; U.S. PRODUCTION AND SALES, 1974 

[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. 
(Leaders (...) are used where the reported data are accepted in confidence and may not he published or where 
no data were reported.) Table 2 lists all miscellaneous chemicals for which data on production and/or sales 
were reported and identifies the manufacturers of each] 



Grand total 

MISCELLANEOUS CHEMICALS, CYCLIC 

Total 

Benzoic acid, sodium salt 

Benzoyl peroxide 

Benzyl alcohol 

tert- Butyl peroxybenzoate 

2,6-Di-tert-butyl-p-cresol : 

Food grade 

Tech 

p-Diraethoxybenzene (Dimethyl ether of hydroquinone)-- 

Dioxane (1,4-Diethylene oxide) 

Enzymes 

Flotation reagents 

Gasoline additives^: 

N,N*-Di-sec-butyl-p-phenylenedi amine 

N.N'-Diisopropyl phenyl enediamine 

N' ,N' -Disalicylideie-l,2-propanediamine 

Hexamethylenetetramine, tech 

Lubricating oil and grease additives, total 

Oil-soluble petroleum sulfonates, total 

Oil-soluble petroleum sulfonate, calcium salt 

Oil-soluble petroleum sulfonate, sodium salt 

All other 

Phenol salts 

All other lubricating oil and grease additives 

Methyl p-hydroxybenzoate (Methylparaben) 

Morpho line 

Naphthenic acid salts, total** 

Calcium naphthenate 

Cobalt naphthenate 

Lead naphthenate 

Manganese naphthenate 

Zinc naphthenate 

All other 

Photographic chemicals: 

2,5-Diethoxy-4-morpholinobenzenediazonium chloride- 

p-Diethylaminobenzenediazonium chloride 

p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium 

chloride 



1,000 
pounds 

100.604.57S 



13,513 
9,092 

13,923 
2,733 

10,286 

15,800 

836 

17,646 

(2) 

5,304 

914 



145,892 
490.141 



308,678 
168,778 
102,898 
37,002 
89,062 
92,401 

1,049 



19.398 



1,626 
4,015 
9,039 



203 
148 



1,000 
pounds 



11,233 
8,329 

12,344 
2,767 

7,986 
15,464 

8,365 

(O 

3,620 

1,082 

974 

63,285 
319.268 



75,890 
140,820 

976 
20,210 

18.056 



1,552 
5,846 
8,257 
1,899 
1,355 
1,127 



1,000 
dollars 



673,915 



4,904 
10,581 
6,090 
5,639 

6,246 



4,129 
36,918 

2,714 

1,291 
1,377 

14,136 
109.523 



26,199 
60,326 

2,141 
14,627 

8,935 



618 
3,329 
2,753 
788 
515 
932 



1,435 
410 



Unit 
Value' 



Per 

pound 



1.27 

.49 

1.52 



.49 
.75 



1.19 
1.41 



.35 
.43 

2.19 
.72 



.33 
.41 
.38 
.83 



8.64 
2.77 



See footnotes at end of table. 



SYUTHETIC ORGANIC CHEHICALS, 197^1 
TABLE 1. --Miscellaneous chemicals: U.S, production and sales, 197^1— Continued 



Production 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

Pinene (a- and B-) 

Polyethylene terephthalate 

Tall oil salts'*: 

Calcium tall ate 

Cobalt tall ate 

Lead tall ate 

Manganese tall ate 

Tanning materials, synthetic 

All other miscellaneous cyclic chemicals 

MISCELLANEOUS CHEMICALS, ACYCLIC 

Total 

Cellulose Esters and Ethers 
Total 

Cellulose esters: Cellulose acetate 

Cellulose ethers: Sodium carboxymethylcellulose, lOO-i 
All other cellulose esters and ethers^ 

Lubricating Oil Additives 

Total 

Phosphorodithioates (Thiophosphates) 

Sulfur compounds: Sulfurized lard oil 

All other 

Nitrogenous i^ompounds 

Total' 

Acrylonitrile 

Amines, total 

Butyl amines 

Diethylenetriamine 

Ethylamines : 

Diethyl amine 

All other 

Ethyl enediamine 

Methylamines : 

Dimethylamine 

Methylamine, mono 

Trimethy lamina 



1,000 



76,857 
1,934,367 



758 
1,004 
1,132 

456 

60,570 

744,284 



97,037,182 



1,057,690 



819,597 
75,604 
162,489 



596,304 



124,443 

3,458 

468,403 



17,599-341 



1,411,749 
1,590,962 



28,358 



12,067 
46,232 



116,811 

54,677 
28,711 



1,000 
pounds 



28,494 
309,849 



737 

904 

1,252 

426 

54,544 
468,318 



46,072,171 



1,000 
dollars 



5,340 
111,375 



184 
618 
431 
204 

16,031 
299,805 



7,141,574 



71,490 
250,160 



157,583 



44,290 
138,269 



55,471 



2,127 
155,456 



566 
54,905 



1.383,274 



511,701 
389, 956 



95,171 
151,253 



14,879 
32,341 



42,559 
51,309 



37,351 
16,706 



13,064 

21,240 



7,790 
3,202 



See footnotes at end of table. 



MISCELLANEOUS CHEMICALS 
TA:BLE 1.--"1iscellai]Eous chemicals: U.S. production and sale, 1974--Continued 



Production 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

Amines- -Continued 
Propylamines: 

Dipropyl amine 

Propylamine, mono- 

Tetraethylenepent amine 

Triethylenetetramine 

All other 

2- (2-Aminoethylamino)ethanol 

Capro lactam 

Erucamide 

Ethanolamines, total 

2-Aminoethanol (Monoethanolamine) 

2,2'-Aminodiethanol (Diethanolamine) 

2, 2', 2' ' -Nitrilotriethanol (Triethanolamine) 

N,N' -Ethylene bis(stearamide) 

Hexamethylenediammonium adipate (Nylon salt) 

Nitriloacids and salts, total 

(Diethylenetrinitrilo)pentaacetic acid, pentasodium 

salt 

(Ethylertedinitrilo)tetraacetic acid, tetrasodium salt 
(N -Hydro xyethylethylenedinitrilo^triacetic acid, 

trisodium salt 

All other 

Nylon 6 and 6/6 (polymers for fiber, only) 

Pentaerythritol tetranitrate 

Polyacrylamide 

Polyacrylonitrile 

Urea in compounds or mixtures (100% basis), total 

In feed compounds 

In liquid fertilizer 

In solid fertilizer 

In plastics 

All other 

All other nitrogenous compounds 

Aaids, Aeyl Halides and Anhydrides 

Total 

Acetic acid, synthetic, 100% 

Acetic anhydride, 100% 

Acrylic acid 

Adipic acid 

Dodecenyl succinic anhydride 

Formic acid, 90% 



24,496 
3,607 



13,506 

668,164 

3,316 



86,494 
98,263 
122,194 

6,765 
743,347 



4,177 
64,484 

6,002 
97,932 

1,757,182 

6,009 

29,217 

621,108 

7.578.160 



753,334 

2,691,407 

2,870,219 

982,362 

280,838 

2,890,310 



7,329,024 



2,583,554 

1,633,102 

232.987 

1,478,423 

62,631 



1,000 
pounds 



12,576 

17,281 

148,481 

10,641 

3,253 

263,967 



1,000 
dollars 



8,291 
9,546 
59,195 

5,905 

5,394 

59,987 



76.439 
79,327 
108,201 



17,040 
17,569 
25,378 



3,985 
87,336 



4,397 
30,844 



5.792.952 



699,917 

2,012,113 

2,523,867 

399,139 

157,916 

1,085,918 



666,485 
409,855 

123,575 

1,266 

51,383 



1,384 
13,938 



2,211 
23,800 



4,633 
25,849 



348.233 



43,239 
97,278 
175,366 
23,202 
9,148 

641,818 



61,667 
48,377 

37,770 

692 

5,264 



See footnotes at end of table. 



SYNTHETIC ORGANIC CHEMICALS, 1974 
TABLE 1.— .'Miscellaneous chemicals: U.S. production and sales, 1974--Continued 



MISCELLANEOUS CHEMICALS, ACYCLIC--Cont inued 

Acids, Acyl Halides and Anhydrides — Continued 

Fumaric acid 

Lauroyl chloride 

Maleic anhydride 

Poly aery lie acid 

Propionic acid 

All other acids, acyl halides and anhydrides 

Salts of Organic Acids 

Total 

Acetic acid salts, total 

Barium acetate 

Potassium acetate 

Zinc acetate 

All other 

2-Ethylhexanoic acid (a-Ethylcaproic acid) salts, total-- 

Calcium 2-ethylhexanoate 

Cobalt 2-ethylhexanoate 

Lead 2-ethylhexanoate 

Manganese 2-ethylhexanoate 

Nickel 2-ethylhexanoate 

Zinc 2-ethylhexanoate 

Zirconium 2-ethylhexanoate 

All other 

Formic acid, sodium salt, tech 

Gluconic acid, sodium salt 

Qctanoic acid salts 

Oleic acid salts 

Stearic acid salts, total'" 

Aluminum stearates, total 

Aluminum distearate 

Aluminum monostearate 

Aluminum tristearate 

Barium stearate 

Calcium stearate 

Magnesium stearate 

Zinc stearate 

All other 

All other salts of organic acids 



Production 



1,000 
pounds 

52,925 

2,282 

289,819 

864 

73,975 

918,462 



38,899 



2 


,567 




660 


35 


,672 


15 


693 


> 


748 


3 


746 


2 


443 


1 


226 




234 


1 


065 


2 


356 


1 


875 


41 


833 


8 


169 



4,258 

3,282 

425 

551 

700 

45,619 

5,993 

22,316 

3,955 

169,405 



Quantit)' 



1,000 
pounds 

37,251 

214,418 

758 

64,235 

409,396 



1,998 
663 



2,157 
3,354 
2,473 
1,200 
239 
982 
2,449 
1,727 

43,173 
12,751 



83,518 



4,086 

3,159 

421 

506 

751 

47,505 

6,047 

21,504 

3,625 

118,077 



1,000 
dollars 



13,801 
62,579 



9,184 
168,078 



9,514 



1,067 

366 

8,033 

12,071 



1,056 

3,383 

956 

551 

348 

572 

2,336 

2,869 

2,141 

5,078 

1,766 

642 

46,688 



2,640 

2,043 

284 



3,831 
13,601 
2,530 



Unit 
value 



Per 
pound 



.49 
1.01 

.39 

.46 
1.46 

.58 



.05 
.40 



See footnotes at end of table 



MISCELLANEOUS CHEMICALS 
TABLE 1.— Miscellaneous chemicals: U.S. production and sales, 1974— Continued 



Production 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Aldehydes and Ketones 

Total 

Acetone, total 

From cumene 

All other 

2-Butanone (Methyl ethyl ketone) 

Butyraldehyde 

Formaldehyde (37°i by weight) 

4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) — 
Isobutyraldehyde 

4-Methyl-2-pentanone (Methyl isobutyl ketone) 

4-Methyl-3-penten-2-one (Mesityl oxide) 

All other aldehydes and ketones 

Alcohols, Monohydria, Unsubstituted 

Total 

Alcohols, Ci 1 or lower, unmixed, total 

Butyl alcohols: 

n-Butyl alcohol (n-Propylcarbinol) 

Isobutyl alcohol (Isopropylcarbinol) 

Ethyl alcohol, synthetic 

2-Ethyl-l-hexanol 

Hexyl alcohol 

Isopropyl alcohol 

Methanol , synthetic 

Propyl alcohol (Propanol) 

All other 

Alcohols, Ci2 and higher, unmixed, total 

Mixtures of alcohols, total 

Cj 1 and lower, only 

Ci2 ^"d higher, only 

All other 

Polyhydric Alcohols and Their Esters and Ethers 

1 2 

Total 

Polyhydric alcohols, total 

Ethylene glycol 

Glycerol, synthetic only 

Pentaerythritol 

Propylene glycol (1 ,2-Propanediol) 

Sorbitol 

All other 

Polyhydric alcohol esters 



1,000 
noimds 



1,980,306 



1,277,532 
702,774 

506,187 

564,903 

5,764,458 

381,885 
207,167 



14,587,742 



13,768,730 



557,650 

160,980 

1,617,565 

394,919 

36,684 

1,938,561 

6,878,310 

96,290 

2,087,771 

156,047 



116,697 

525,293 

20,975 



6,373,622 



4,749,654 



3,340,695 
202,793 
125,133 
510,206 
171,819 
399,008 

235,879 



1,000 
pounds 



6,784,640 



1,000 
pounds 



1,041,259 
593,581 



2,660,373 

57,127 

165,16? 

26,824 

1,771,699 



112,670 
55,445 



72,744 
10,089 

30,456 
4,615 
137,461 



687,084 



7,646,496 



550,218 



345,910 

113,657 

1,230,133 

368,152 

868,467 

3,555,993 

79,809 

1,084,375 



,171 



49,370 

14,334 

115,214 

60,086 

72,922 

129,318 

13,728 

95,246 

32,100 

104,766 



93,934 

354,551 

18,661 



5 .065.865 



16,936 

79,174 
8,656 



,699,075 

110,672 
476,450 
145,728 
354,266 

196,558 



388,098 

39,491 
99,017 
40,165 
128,083 

63,794 



See footnotes at end of table. 



SYIITHETIC ORGANIC CHEfllCALS, 1974 

TABLE l,--!'llSCELLANEOUS CHEMICALS: U.S. PRODUCTION' AND SALES, 1974--CoNTINUED 



Quantity 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Polyhydric Alcohols and Their Esters and Ethers- -Continued 



Polyhydric alcohol ethers, total 

2-Butoxyethanol CEthylene glycol monobutyl ether) 

2- (2-Butoxyethoxy)ethanol (Diethylene glycol 

mono isobutyl ether) 

Diethylene glycol 

Dipropylene glycol 

2-Ethoxyethanol (Ethylene glycol monoethyl ether) 

2- (2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl 

ether) 

2- [2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol 

monoethyl ether) 

2-Methoxyethanol (Ethylene glycol raonomethyl ether) 

2- [2-(2-Methoxyethoxy)ethoxy]ethaiiol (Triethylene glycol 

monomethyl ether) 

2- (2-Methoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether) 

Polyethylene glycol 

Po lypropy 1 ene g 1 yco 1 

Tetr ae t hy lene glycol 

Triethylene glycol 

All other ethers of polyhydric alcohols 

Esters of Monohydrio Alcohols 

Total 

n-Butyl acetate, unmixed 

Butyl aery late 

tert- Butyl peroxy-2-ethylhexanoate 

tert- Butyl peroxypivalate 

Dibutyl maleate 

Di(2-ethyl-l-hexyl) maleate 

Dilauryl 3, 3' -thiodipropionate 

Dioctyl maleate 

Distearyl 3,3' -thiodipropionate 

Ethyl acetate (85%) 

Ethyl aery late 

2-Ethyl-l-hexyl aery late 

Isopropyl acetate 

Methyl acetate 

Methyl methacrylate, monomer 

Phosphorus acid esters, not elsewhere specified 

Propyl acetate 

Vinyl acetate 

All other 



1,000 
pounds 



1,388,089 



131,266 

26,288 
309,302 

52,947 
159,952 

31,856 

21,496 
115,591 



14,683 
96,890 
48,872 

110,495 
235,200 



5.680.857 



77,218 

169,874 

1,637 

1,011 

13,592 

501 

2,313 

2,045 

197,590 

307,237 

52,483 

7,915 

718,810 

78,832 

34,686 

1,402,675 

612,438 



1,000 
pounds 



1.085,116 



1,000 
do I lars 



241,835 



122,711 

19,872 
213,527 
50,831 
92,803 

36,134 



26.642 

4,409 
34,635 
10,190 
19,487 



12 


071 


79 


755 


37 


995 


10 


525 


97 


216 


194 


068 



7,694 I 



2,131 

2,621 
24,597 
10,543 

2,308 
19,232 
54,432 



443.263 



68,994 

101,713 

1,626 

986 

9,836 

1,930 
3,741 
2,106 
153.041 
149,301 
47.367 
43,038 



65,665 

34.150 

830,674 

540,011 



12 


399 


23 


997 


2 


828 


2 


064 




407 




668 




302 




871 


23 


Oil 


30 


542 


12 


650 


6 


339 


34 


561 


5 


888 



See footnotes at end of table. 



ISCELLANEOUS CHEMICALS 



TABLE 1.— lIlSCELLANEOUS chemicals: U.S. PRODUCTION AND SALES, 1974 — CONT I NUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Halogenated Hydrocarbons 

Total 

Carbon tetrachloride 

Chlorinated paraffins, total 

35-64% chlorine 

Other 

Chloroethane (Ethyl chloride) 

Chloroform 

Chloromethane (Methyl chloride) 

l,2-L)ibromoethane (Ethylene dibromide) 

1,2-Dichloroethane (Ethylene dichloride) 

Dichloromethane (Methylene cliloride) 

1,2-Dichloropropane (Propylene dichloride) 

Fluorinated hydrocarbons, total 

Chlorodifluoromethane 

Dichlorodif luoromethane 

Tetrafluoroethylene, monomer 

Trichlorof luoromethane 

All other fluorinated hydrocarbons 

Tetrachloroethylene (Perchloroethylene) 

1,1,1-Trichloroethane (Methyl chloroform) 

Trichloroethylene 

Vinyl chloride, monomer (Chloroethylene) 

All other halogenated hydrocarbons 

Alt Other Miscellaneous Acyclic Chemicals 

Total 

2 - Butanone peroxide 

tert-Butyl peroxide (Di-tert-butyl peroxide) 

Carbon disulfide 

Epoxides, ethers, and acetals, total 

Ethylene oxide 

Ethyl ether, tech 

Isopropyl ether 

Propylene oxide 

All other epoxides, ethers, and acetals 

Organo-silicon compounds, total 

Silicone fluids 

Other organo-silicon compounds 

Phosgene (Carbonyl chloride) 

Sodium methoxide (Sodium methylate) 

Tetraethyllead 

Other organo-lead compounds 

All other 



1,000 
pounds 

23,110,413 



1,162,655 



78,012 



61,251 
16,761 

662,493 
301,787 
15 493,097 
332,125 
9,165,077 
608,821 
145,061 

1,172.602 



487,394 

24,620 

340,963 

319,625 

734,437 

591,633 

388,129 

5,621,191 

1,653,293 



6.258,294 



13 3,892,543 
62,627 



1,756,305 
546,819 



256,190 



86,314 
169,876 

867,410 
18,016 
464,228 
455,368 
655,055 



Quantity 



1,000 



59,074 
15,896 

279,325 
252,300 
214,718 
170,829 
1.313,614 
527,413 
48,197 



111,905 
449,007 



708,897 
575,715 
402,595 
,121,997 
206,738 



6,595 

2,705 

498,797 

1,361.468 



457.102 

12.103 

892.263 

125.621 



72.685 
52.936 

10.078 

18,137 

391,705 

581,295 

398,018 



1,000 
dollars 



12.379 
4.645 



20 


184 


38 


006 


68 


620 


67 


175 


1 


756 


62 


397 


138 


234 



74,160 
75,087 
46,152 
259,588 
98,014 



6,361 

2,293 

23,276 



83,111 
99,152 

1,282 

4,883 

264,412 

348.433 

120,807 



See footnotes on following page. 



SYNTHETIC ORGANIC CHEMICALS, 197^* 



Footnotes for tdb'Le 1 

Calculated from rounded figures. 
Sot available. 

Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given 
with "Plasticizers." 

* Quantities are given on the basis of solid naphthenate, tallate or linoleate content. 

^ Statistics excl'ide production and sales of copper naphthenate. Statistics on copper naphthenate are given 

vith "Pesticides and Related Products." 

^ Ethylcellulose which was formerly included with cellulose ethers is now included with cellulosic plastics 

aaterials. 

' Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given with "Surface- 

.Active Agents." 

* Production of urea in primary solution totaled 7,582,715 thousand pounds. 
' Includes estimated values for sales of urea in nitrogen compounds. 

'° Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are 

included with "Surface-Active Agents." 
" Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Department of 

Treasury, Bureau of Alcohol, Tobacco, and Firearms. 
'* Some polyols which are used as intermediates for urethanes have been included with "Plastics and Resin 

Materials." 
^^ Production totals may be understated because some methyl chloride, ethylene dichloride and ethylene oxide is 

produced but not separated or accurately measured ( and therefore not reported) by some producers. 



niSCELLANEOUS CHEMICALS 205 

TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 1974 

[Miscellaneous chemicals for which separate statistics are given in table 1 are marked with an asterisk (*) ; 
chemicals not so marked do not acoear in table 1 because the reported data are accepted in confidence and may not 
be published. Manufacturers' identification codes shown below are taken from table 3. An x signifies that the 
manufacturer did not consent to his identification with the designated product] 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLVNEOUS CHE?1ICALS, CYCLIC 



6-Acetoxy-2 , 4-dimethyl- 1 , 3-dioxane 

Acetylcyclohexanesulfonyl peroxide 

Adenosine and derivatives 

2-.\minobenzothiazole 

1- (2- Aminoethyl) piperazine 

Anyl-p-diraethylaminobenzoate 

•Benzoic acid, sodium salt 

p-Benzoquinone (p-Quinone) 

Benzothiazole 

•Benzoyl peroxide 

♦Benzyl alcohol 

BisC2-cyclopentenyl) ether 

BisC2,4-dichlorobenzoyl5 peroxide 

Bis [a, a-dine thy Ibenzyl) peroxide 

2,4-Bis(4-Hydroxy-3,5-di-tert-butylnhenoxy)-6-(n-octyl- 
thio)-l,3,5-triazine. 

Bis(6-methyl-3-cvclohexenylmethyl) adipate 

1 , 3-Bi s (N-m-methox>T>henylurethane) benzene 

2,-"-Bis(n-octylthio)-6-(4'-hvdroxv-3' ,5'-di-tert-butyl- 
anilino)-l ,3,5-triazine. 

Boron fluoride-phenol complex 

Butvl benzoate 

2(and 3)-tert-Butyl-4-nethoxyDhenol (BHA) 

*tert- Butyl peroxybenzoate 

4-tert-Butylnyrocatechol 

Camphene 

Cellulose acetate hexahydrophthalate 

Cellulose acetate phthalate 

N,N'-Diethyl-N,N'-diphenylurea 

Chemical indicators and reagents 

l-(3-Chloroallyl)-3,5,7-triaza-l-azoniaadamantane 
chloride. 

p-Chlorophenyldiiodomethyl sulfone 

Cumene hydroperoxide 

Cyanuric acid 

1,3-Cyclohe.xadiene 

Cyclohexanone peroxide 

3-Cyclohexenyl-3-cyclohexene carbox>'late 

1,4-Cyclohexylenedimethanol 

Cyclopropane 

Cytidine and derivatives 

Decahromobiphenyl or ether 

Decahydronaphthalene (Pecalin) 

Dehydroacetic acid or sodium salt 

Diaminodiohenylmethane 

l,4-Piazobicvclo(2.2.2)octane 

Piazodinitrophenol 

2,5-Pi(benzoylpero.xv)-2,5-dimethvlhexane 

Pibromodimethyl hydantoin 

Pi- and tribromosalicylanilide 

:,6-Pi-tert-butyl-p-cresol (BHT) : 

*Food grade 

•Tech 

Di-tert-butyl diperoxyphthalate 



GIV. 

WTL. 

PLB. 

PIT. 

JCC. 

VND. 

HN, MON. PFZ. 

EKT. 

ACY. 

A2T, 

BPC, 

ucc. 

CAD. 
WTL. 

cny. 

UCC. 
OTC. 
CHY. 



CAD, NOC, RCI. HTC, WTL. 
HN, MNP, UOP, VEL. 



ACS. 
PFZ, 
EKT. 
A2T, 
DOW. 
r,LP, 



OTC. 
ARA, 

POW. 



TCC, VEL. 

CAP, NOC, WTC, WTL. 

HPC. 

EK, FIN, GFS. LAM, NEP. 



ABB. 

ACS, RCI. 

FMB. 

ALP. 

NOC. 

UCC. 

EKT. 

OH, TAE. 

PLB. 

FIN. 

PUP. 

flAN. 

JCC. 

AIP. 

HPC. 

WTL. 

ARA . 

FIN. 

ASH, KPT, SHC, USR. 
ASH. KPT, PPP, SHC, USR. 
WTL. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2. 



-Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--C0NTI NUED 



MISCELLANEOUS CHEMICALS, CYCLIC--Continued 

2.5-Di-tert-butylhydroquinone 

l,3-Dichloro-5,5-diFiethylhydantoin 

Dichloroisocyanuric acid and salts 

4,4'-Dichloro-3- (trifluoromethyljcarbanilide 

Dicyclohexyl ammonium nitrate 

2,5-Dihydrothiophene-l,l-dioxide (Sulfolene) 

2,2'-Dihydroxy-4 ,4'-dimethoxybenzophenone 

3,5-Dihydroxy-3,5-dimethyl-l ,2-peroxycyclopentane 

2,6-Dihydroxypyridine-4-carboxylic acid 

Diiodomethyl-p-tolyl sulphone 

Diisopropylbenzene hydroperoxide 

Diisopropyl cresols 

Diketene 

*p-Dimethoxybenzene CHydroauinone dimethyl ether) 

2,6-DimethyImorpholine 

Dimorpholino diethyl ether 

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyrimidinol 

Di-n-octadecyl-3,5-di-tert-butyl-4-hydroxyphenyl phos- 
phonate. 

♦Dioxane (1,4-Diethylene oxide) 

1,3-Dioxolane 

4- (Dodecy 1 oxy ) - 2-hydroxyben zophenone 

♦Enzymes ; 

Hydrolytic: 

Amylases 

Proteases 

Other 

Nonhydrolytic 

l,2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether) 

2-Ethylhexyl-p-dimethylaminobenzoate 

Ethyl idene norbornene 

4-Ethylmorpholine 

•Flotation reagents: 

Dicresylphosphorodithioic acid (Dicresvldithiophos- 
phoric acid). 

Dicresylphosphorodithioic acid, ammonium salt 

Dicresylphosphorodithioic acid, sodium salt 

2,2'-Dimethylthiocarbanilide (Di-o-tolyl thiourea) 

Rosin amines 

Thiocarbanilide (Diphenyl thiourea) 

Furan derivatives: 

2-Furaldehyde (Furfural) 

Tetrahydrofurfuryl alcohol 

Gallic acid 

♦Gasoline additives: 

N,N'-Bis(l,4-dimethylpentyl)-p-Dhenylenediamine 

Buty Iphenols, mixed 

4,4'-Di-sec-butylaminodiphenylmethane 

2,6-Di-tert-butyl-a-dimethylamino-p-cresol 

2,6-Di-tert-butylphenol 

N, N'-Di- sec- buty 1-o-phenylenedi amine 

*N,N'-Di-sec-butyl-p-phenylenediamine 

2,6-Diethylaniline 

*N,N' - Di i sop ropy 1-p-phenylenedi amine 

*N,N'-Disalicylidene-1 ,2-propanediamine 

Methylcyclopentadienylmanganese tricarbonyl 

4,4'-Methylenebis (2 ,6-di-tert-butylnhenol) 

N-Phenyl-N-sec -buty Iphenylenedi amine 



Manufacturers' identification codes 
(according to list in table 3) 



EKT. 

GLY. 

FMB. 

CGY. 

OMC. 

PLC. 

ACY, GAF. 

WTL. 

EK. 

ABB. 

HPC. 

GIV. 

ALD, FMP. 

ASL, EKT, GAF. 

DOW. 

JCC. 

MRK. 

CGY. 

DOW, FER, UCC. 

FER. 

EKT. 



DLI, MLS, PFZ, PMP, RH, x. 

CHH, DOL, MLS, PEN, PFZ, PMP, 

JFR, MLS, OMS, RH, WBC, x. 

OMS, PFZ, PLB, WBC. 



BAX, 

BAX, 

BAX, 

MLS, 

x. 

VND. 

UCC. 

JCC. 

ACY. 

ACY. 
KCU. 
RBC. 
HPC. 
ACY. 



QKO. 
QKO. 
HSH, MAL. 

EKT. 
TNA. 

TNA. 
GLY, TNA. 

X. 

DUP, EKT, USR, X. 

TNA. 

DUP, EKT, USR. 

DUP, SM, TX. 

TNA. 

TNA. 



ISCELLANEOUS CHEHICALS 



TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974— CONTINUED 



Planufacturers ' identification codes 
(according to list in table 3) 



MlSCELLANEnuS CHEMICALS, CYrLIC--Continued 

*r,asoline additives --Continued 

2,2'-Thiobis(6-tert-hutvl-p-cresol) 

4,4'-Thiohis (6-tert-hutyl-o-cresol) 

Trihentyl nhenol 

l,3,5-Tris(3,5-di-tert-butvl-4-hvdroxybenzvl)- 
mesitvlene. 

Other 

nivcervl o-aminobenzoate 

fluanosine and derivatives 

♦Hexamethylenetetramine, tech 

Hy drab ami ne hvdrob romi de 

Hydrindantin 

p-Hydroxybenzoic acid esters: 

Butvl p-hydroxvbenzoate CButyloaraben) 

Ethyl p-hydroxybenzoate (Ethylparaben) 

♦Methyl o-hvdroxybenzoate (^1ethvlnaraben) 

Propyl p-hydroxvben:oate (Propylparaben) 

2-Hydroxy-4-methoxvhenzophenone 

2-Hydroxy-4-methoxy-5-5ulfobenzophenone trihydrate 

2- (2-Hydroxv-5-tert-octvlphenvl)benzotriazole 

Inosine and derivatives 

Isonropyl-o-cresols 

Ketene diner 

'Lubricating oil and grease additives: 
♦nil-soluble Petroleum sulfonates: 

nil-soluble petroleum sulfonate, ammonium salt 

Oil-soluble petroleum sulfonate, barium salt 

♦Oil-soluble petroleum sulfonate, calcium salt 

♦Oil-soluble petroleum sulfonate, sodium salt 

nther 

♦Phenol salts: 

Barium alkylphenolates 

Calcium alkylphenolates 

Other 

All other 

P-Men thane 

8-p-Menthyl hydroperoxide 

p-Methoxybenzylidenemalonic acid, diethyl and 
dimethyl esters. 

p-Methoxybenzylidenemalonic acid, dimethyl ester 

4 -'lethoxypheno 1 

2,2'-Methylenebis(4-chlorophenol) (Dichlorophene) 

Hethylene-bis(5,5-dimethyl hydantoin) and derivatives- 
Methyl enebi s (phenoxvpropanol ) 

2,2'-Methylenebis (3,4 ,6-trichloroohenol) (Hexachloro- 
phene) . 

Methyl gal late 

4-Methylmorpholine 

l-Methyl-2-pyrrolidone, monomer 

♦Morpholine 

♦Naphthenic acid salts: 

A luminum naphthenat e 

Barium naphthenat e 

Cadmium naphthenate 

♦Calcium naphthenate 

Chromium naphthenate 

♦Cobalt naphthenate 

Iron naphthenate 

Lead manganese naphthenate 

♦Lead naphthenate 

Lithium naphthenate 

♦Manganese naphthenate 

Magnes i urn naphthenate 

Rare earths naphthenates 

Sodium naphthenate 



ASH. 

TNA. 



TNA. 



EKT, CLY, TNA, x. 

VNP. 

PLB. 

BOR, DlIP, HKD, HN, HMP, PLS, IICC . 

ABB. 

HEX. 

HN. 

HN. 

APS, HN, LE»<. 

APS, HN, LE". 

ACY, GAP. 

ACY. 

ACY. 

PLB. 

CP. 

EKT. 



NTL. 

urn, PAR, OTC. 

ENJ, LUB, OW, PAR, PLC, TX, WTC . 

ENJ, MOR, PAR, SHC, Snc, WTC. 

LUB, TX. 

CCA, ENJ, TX. 

OPO, TX. 

ACY, .AT", ENJ, GOC, ORO, S", TX . 

ENJ, P'P, Cnc, LUB, npn, PLC, SHC, SM, TX. 

HPC. 

HPC. 

ACY. 

ACY. 

.IVRS, ASL, EKT. 

CIV. 

CLY. 

JCC. 

GIV. 

HSH. 

JCC, UCC. 

GAF. 

DOW, JCC, UCC. 

SHP. 

CCA. 

CCA. 

CCA, PEP, HN, MCI, SHP, SW, Ton, WTC. 

MCI. 

CCA, FER, HN, MCI, SHP, TPO, WTC. 

CCA, HN, MCI, WTC. 

CCA. 

CCA, FER, MCI, SHP, SW , TX, OTC. 

CCA, MCI. 

CCA, FFP, HN, MCI, SHP, SM, SW, IVTC. 

CCA. 

CCA, SHP. 

CCA. 



SYNTHETIC ORGANIC CHEMICALS, 197^1 



TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197A--C0NTINUED 



MISCELLANOEOUS CHEMICALS, CYCLIC--Continued 

•Naphthenic acid salts- -Continued 

Strontium naphthenate 

*Zinc naphthenate 

All other 

5-Nitroimidazole 

l-Octadecenyl-2-naphthenyl tetrahydro pyrimidine 

l-Octadecenyl-2-oleyl tetrahydro pyriraidine 

Octadecyl 3- C3,5-di-tert-butyl-4-hydroxyphenyl) - 
propionate. 

l-Oleylpyrimidine-2-oleyldiainine 

Phenothiazine 

2-Phenoxyethanol (Ethylene glycol monophenyl ether) 

2-(2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl 
ether) . 

2,2'- (p-Phenylene)diethanol 

m- Phenyl ene i sonaphtha 1 ami de 

Phenyl hydrogen phosphate 

Photographic chemicals: 

N-(2-Acetamidoohenethyl)-l-hydroxy-2-nanhthamide 

3-(3'-Aminobenzamido)-l-(2' ,4' ,6' -trichlorophenyl)- 
5-pyrazolone. 

5-Amino-2 ,3-dihydro-l ,4-phthalazenedione 

N- [2- (4-Amino-N-ethyl-m-toluidino)ethyl]methane- 
sulfonamide. 

2-(4-Amino-N-ethyl-m-toluidino)ethyl sulfate 

3- Amino- 1 ,2 ,4-triazole 

Benzotriazole 

a-Benzoyl-o-methoxyacetanilide 

p-Benzylaminophenol hydrochloride 

Catechol 

5-Chlorobenzotriazole 

3-Chloro-4-diethylaminobenzenediazonium chloride (p- 
Diazo-2-chloro-N,N-diethylaniline) - zinc chloride. 

Chi orohydroquinone 

N,N'- (2,4-Di-tert-amylphenoxyacetyl) -ami do- 4,6- 

dichloro-5-methyl phenol. 
4-Diazo-2,4-diethoxy-l-thio-p-cresylbenzene zinc salt- 

4-Diazo-l-morpholine benzene zinc chloride 

a-Diazo-1-naphthol- 5- sulfonate 

*2,5-Diethoxy-4-morpholinobenzenediazonium chloride 

*D-Diethylaminobenzenediazonium chloride 

N,N-Diethyl-p-phenylenediamine hydrochloride 

N,N-Die thy 1 toluene- 2, 5-diamine, monohydrochloride 

2,5-Dihydroxy-p-benzenedisulfonic acid dipotassium 
salt. 

p-Dimethylaminobenzenediazonium chloride 

2,5-Dimethylbenzothiazole 

p-Diphenylaminediazonium sulfate 

p- (N-Ethylbenzimido)benzenediazonium chloride 

*p- [Ethyl (2-hydroxyethyl)amino]benzenediazonium- 
chloride (p-Diazo-N-ethyl-N-hydroxyethylani line- 
zinc chloride) . 

N-Ethyl-N-hydroxyethyl-p-phenylenediaraine sulfate 

Hydroquinone (Hydroquinol) 

p[ t2-Hydroxyethyl)methylamino]benzenediazonium 

chloride. 
N-(2-Hydroxyethyl)-6-resorcylamide 



Manufacturers' identification codes 
(according to list in table 3) 



CCA. 

CCA, PER, HN, MCI, SHP, SW, WTC . 

MCI. 

PCW. 

SM. 

SM. 

cr.Y. 

SM. 

WAC. 

DOW, JCC, TCH. 

pni" . 

EKT. 
DUP. 
HDG. 

EKT. 
WAY. 

EK. 
EKT. 

EKT. 

FMT. 

EK, FMT, SW. 

EKT. 

EK. 

CRZ. 

FMT. 

ESA, FMT. 

EK. 
WAY. 



FMT. 






FMT. 






ALL, 


ESA, 


HST 


ESA, 


FMT, 


WAY 


EKT. 






EKT, 


FW, 


WAY 


EK. 






ESA, 


FMT, 


WAY 


FMT. 






FMT. 






ESA. 


FMT. 




ESA, 


FMT, 


WAY 


WAY. 






EKT. 






ESA, 


FMT. 





1ISCELLANE0US CHEMICALS 



TABLE 2, 



-Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. 1974--CoNTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, CYCLIC- -Continued 

Photogranhic chemicals- -Continued 

2-Hydrox)Tiaphthoic ethylamide 

1 - ( S-Hydroxynheny l)urea 

4-Methoxy-l-naphthol 

p-Methylaminophenol sulfate 

5-Methylbenzotriazole 

5-Methyl-l ,7-dihydroxy-l,3,4-triazaindolizine 

4-Methyl-l-phenyl-3-pyrazolidinone 

2-Methylthiazoline 

6-Nitrobenziinidazole 

l-Phenyl-3-pyrazolidine 

1- Phenyl -3-pyrazolidone 

4- Pheny Ipyro catechol 

1- Phenyl -2-tetrazole-S- thiol 

6-Resorcylic acid monoethanolamide 

2,2' ,4,4 '-Tetrahydroxydiphenyl sulfide 

1- (2,4,6-Trichlorophenyl) -3-p-anilino-2- 
pyrazolin-5-one . 

All other 

Phthalic acid, lead salt, dibasic 

Picraraic acid, sodium salt 

*Pinene (a- and B-) 

a-Pinene, P2S5 treated 

Pinene, sulfate 

Piperazine, ethoxylated 

Poly- 4- (2-acryloxyethoxy)-2-hydroxybenzophenone 

'Polyethylene terephthalate 

Propyl gallate 

Pyrogallol (Pyrogallic acid) 

2-Pyrrolidinone 

Resorcinol monobenzoate 

Rosin acid salts: 

Calcium resinate 

Calcium zinc resinate 

All other 

Salicylanilide 

Salicylic acid, lead salt 

Sodium cresoxide (Cresylic acid, sodium salt) 

Sodium ferric ethylenediaminedihydroxyphenylacetate 

Stannous octanoate dioctylphthalate 

Sulfo salicylic acid 

Tall oil salts (Linoleic-rosin acid salts): 

Calcium manganese tallate 

*Calcium tallate 

Calcium zinc cobalt tallate 

*Cobalt tallate 

Copper tallate 

Iron tallate 

Lead manganese tallate 

*Lead tallate 

'Manganese tallate 

Zinc tallate 

All other 

Tannic acid 

'Tanning materials, synthetic: 

Cresol phenol formaldehyde condensate 

Hydroxytoluenesulfonic acid, formaldehyde condensate 
(Cresol -formaldehyde sulfonate), sodium salt. 

Naphthalene sulfonic acid 

1-Naphthalenesulfonic acid, formaldehyde condensate 
and salt. 



FMT. 
FW. 

X. 

EK. 

EK. 
FMT. 
WAY. 
FMT. 
EK, FMT. 

cr,Y. 

WAY. 

X. 

FMT. 
¥m. 
FMT. 
EKT. 



BKC, 
NTL. 
SDC. 
ARZ, 
ENJ. 
HPC. 
GAF. 
ACY. 
CEL, 
EKT, 
HSH, 
GAF. 
EKT. 



CBY. 

CBY. 

SHP. 

FIN, PCW. 

NTL. 

DEX, GOC. 

CGY. 

X. 

MON. 



EK, FMT, WAY, x. 

CBY, GLD, HN, HPC, NCI. 



DUP, EK, EKT, FRF, GYR. 

HSH. 

MAL. 



MCI. 










CCA, 


HN, 


MCI, SHP, 


ZGL. 




MCI. 










CCA, 


FER, 


FOC, HN, 


MCI, 


SHP 


CCA, 


MCI. 








CCA, 


SHP. 








MCI. 










CCA, 


FER, 


HN, MCI, 


SHP. 




CCA, 


FER, 


HN, MCI, 


SHP. 




MCI. 










KCH, 


MCI. 








HSH, 


MAL. 









CGY. 
DA. 



SYNTHETIC ORGANIC CHEMICALS, 197 ^ 



TABLE 2.- 



-Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197'^|--CONTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, CYCLIC- -Continued 

*Tanning materials, synthetic--Continued 

2-Naphthalenesulfonic acid, formaldehyde condensate 

and salt. 
l-Phenol-2-sulfonic acid, formaldehyde condensate 
(Phenol-formaldehyde, sulfonated) . 

Tetrabromob i sphenol A 

2,3,5,6-Tetrachloro-4- (methyl sulfonyl) pyridine 

1 ,2,3,6-Tetrahydrobenzaldehyde 

TetrahydrothioDhene 

Tetrahydrothionhene-1 ,1 -dioxide (Sulfolanel 

let rabis [methylene- 3- (3' ,5'-di-tert-butyl-4'-hydroxy- 
nheno 1 ) prop i onate ] methane . 

1 ,3,6,8-Tetranitrocarbazole 

Tetraphenyltin chloride 

Tetraphenyltin succinic acid 

Textile chemicals, other than surface-active agents: 

tlimethyloldihydroxy ethylene urea 

1- ((Octadecyloxy)methyl)pyridinium chloride 

Tetrahydro-3,5-bis(methoxymethyn-4H-l,3,5-oxadiazin- 
4-one (1 ,3-Bis (methoxymethyl)uron) . 

2,2',4,4'-Tet rahy dro xyben zophen one 

Tri(phenyloxymethyl)trimethyloxymethylmelamine 

Thioanisole 

Thiophene 

Thymidine and derivatives 

o-Toluidine formaldehyde hydrochloride 

p-Toluquinone 

Trial lyl cyanurate 

3,4' ,5-Tribromosalicylanilide 

1 ,2,3-Triketohydrindene hydrate 

Trimethylaminopronyl piperazine 

3,5,5-Trimethyl-2-cyclohexen-l-one (Isophorone) 

Triphenyl phosphite 

2,4,6-Trinitroresorcinol and lead derivative 

Triphenyl sulfonium chloride 

Uridine derivatives 

Vinyl norhornene 

l-Vinyl-2-pyrrolidinone, monomer and polymer 

l-Vinyl-2-pyrrolidinone - ethylacrylate, copolymer 

l-Vinyl-2-pyrrolidinone - vinyl acetate, copolymer 

l-Vinyl-2-pyrrolidinone - other copolymers 

All other 



MISCELLANEOUS CHEMICALS, ACYCLIC 

Cellulose Esters and Ethers 

Cellulose esters: 

♦Cellulose acetate 

Cellulose acetate butyrate 

Cellulose acetate propionate 

Cellulose ethers: 

Hydroxye thy 1 cellulose 

Hydroxyp ropy Ice llulose 

Methylcellulose 

*Sodium carboxymethylcellulose, 100% 



AKS, CRD, RH. 

RH. 

GTL. 

DOW. 

UCC. 

PAS. 

PLC, SHC. 

CCY. 

SDC. 



DUP. 
DEX. 

CAF. 

DUP. 

EVN. 

PAS. 

PLB. 

RBC. 

EK. 

ACY. 

FIN. 

PIC 

JCC. 

ENJ, UCC. 

MON. 

REM . 

ASH . 

PLB. 

UCC. 

DAN, GAP. 

CAF. 

GAF. 

GAF. 

ABB, ALB, ALD, AMB, ARA, ARS, CCA, CDY. CGY, CTN, DUP, 
EK, EKT, EVN, FIN, FMT, GAF, GIV, GOC, HEX, HMY, HPC, 
MON, MRK, PD, PFN, PIC, PLB, RCI, REM, RSA, SM, SYP, 
TRO, XC, VND, RAY, WBC, x. 



AV, CEL, DUP, EKT. 

EKT. 

EKT. 



DOW. 

BAS, BUK, DUP, KON, WP, 



ISCELLANEOUS CHEMICALS 



TABLE 2. 



llSCELLANEOUS CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED. 
IDENTIFIED BY MANUFACTURER. 1974--CONTINUED 



Manufacturers' identification codes 
(accordinE to list in table 3) 



HISCELLANEnuS CHEMICALS, ACYCLIC--Continued 

Lubrioating Oil Additives 

*PhosDhorodithioates ( Dithionhosphates) : 

ni-2-ethylhexylphosphorodithioic acid 

Di-N-nropylnhosohorodithioic acid 

Zinc dialkyl dithiophosphate 

Zinc di (butylhexyl) phosphorodithioate 

Zinc hydrocarbon dithiophosphate 

Zinc isopropyl hexyl phosphorodithioate 

Sulfur compounds: 

Aliphatic hydrocarbon sulfides 

Chlorosulfurized sperm oil 

Diisobutylene polysulfide 

Phosphosulfuri zed polybutene 

*Sulfurized lard oil 

Sulfurized sperm oil and substitutes 

Triisobutylene polysulfide 

Other sulfur compounds 

All other 

Nitrogenous Compounds 

Acet amide 

Acetamidoethanol (N-Acetyl-ethanolamine) 

Acetone semicarbazone 

Acetonitrile 

Acetyl glycine 

Aery 1 amide monomer 

*Acrylonitrile 

Adiponitrile 

B- Alanine 

l-Allyl-3-(2-hydroxyethyl)-2-thiourea 

Allyl isothiocyanate, non-perfume grade 

* Amines : 

Allylamines 

Bis-hexame thy lane tri amine amine 

*Butylamines : 

n-Butylamine, mono- 

Di-n-butyl amine 

sec- Butyl amine, mono- 

tert- Butyl amine, mono- 

Tri -n-butyl amine 

n- Butyl ethyl amine 

*Diethylenetrianine 

N,N-Diethylethylenediamine 

n' ,n' -Diethyl- 1 ,4-pentanedi amine (Novoldi amine) 

Dimethylaminopropylamine 

*Ethylamines : 

'Diethyl amine 

Diethyl amine hydrochloride 

Ethylamine, mono- 

Tr ie thy 1 amine 

*Ethvlenedi amine 

Ethyleneimine 

(2-Ethylhexyl)aJiiine, mono- ; 

1,6-Hexanediamine (Hexamethylenediamine) 

3,3'-Iminobispropylamine 

Isobutylamines : Diisobutylamine 



SFA. 
SFA. 
ATR. 
ORO. 
LUB. 
TX. 

LUB. 

CCW. 

TX. 

ENJ. 

ATR 

CCW 

TX. 

ATR, 

ALD 



CCW, GOC, OCP, WBG. 



CCW, HK, TX. 

ALX, ATR, ENJ, GOC, LUB, NLC, ORO, UCC, 
WTH, X, x, X. 



ACS. 








ALB, 


RBC. 






NOR. 








EKX, 


MON, 


SOH. 




CHT. 








ACY. 








ACY. 


DUP, 


MON, 


SOH 


DUP, 


MON. 






HFT. 








FMT. 








OPC. 








SHC. 








DUP. 








AlP, 


PAS, 


UCC, 


VGC 


AIP. 


PAS, 


UCC, 


VGC 


PAS, 


VGC. 






MON, 


RH. 






PAS, 


VGC. 






PAS. 








DOW, 


JCC, 


UCC. 




ALB, 


GCY. 






SDH. 








JCC. 








AIP, 


PAS, 


UCC. 




RSA. 








AIP, 


PAS, 


UCC. 




AIP, 


PAS. 


UCC. 




DOW, 


JCC, 


UCC. 




DOW. 








VGC. 








CEL, 


DUP, 


ELP, 


MON 


JCC. 








AIP, 


VGC. 







SYNTHETIC ORGANIC CHEMICALS. 1971 



TABLE 2. --Miscellaneous chemicals for which U,S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURERy 1974--C0NTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

♦Amines- -Continued 
Isopropylamines : 

Diisopropyl amine 

Isopropvlamine , mono- 

Methylamines : 

'Dimethyl amine 

Dimethyl amine hydrochloride 

Dimethyl amine sulfate 

*Methylamine, mono- 

*Triraethylamine 

Octyl amine, mono 

Oleylamine 

Pent aethy 1 enehexam ine 

Pentylamines (Amylamines) : 

Dipentyl amine 

Pentylamine, mono- 

Tripentylamine 

Polyalkylene poly amines 

1,2- Prop anedi amine (Propylenedi amine) 

1 , 3- Propanedi amine ( 1 , 3- Diaminopropane ) 

Propylamines : 

*Dipropyl amine 

♦Propylamine , mono- 

Trinropylamine 

*Tetraethy lenepentamine 

N,N,N' ,N'-Tetramethyl-l,3-butanediamine 

Tetramethylethylenediamine 

*Triethylenetetramine 

Other amines 

2-Amino-l-hutanol 

Aminoethoxyethanol 

*2- (2-Aminoethylamino)ethanol (Aminoethylethanolamine)- 
2-Aminoethyl mercaptoacetate O'onoethanolamine thio- 

glycolate) . 

2-Amino-2-ethyl-l,3-propanediol 

Aminoguanidine bicarbonate 

2-Amino-2-(hydroxymethyl)-l,3-propanediol (Tris- 

(hydroxymethyl)aminomethane) . 

2-Amino-2-methyl-l,3-propanediol 

2-Amino-2-methyl-l-propanol 

2-Araino-2-methyl-l-propanol hydrochloride 

y-Aminopropyl trie thoxysi lane 

l,l'-Azobisformamide 

2,2-Azobi5 [2-me thy Ipropionami dine) dihydrochloride 

2,2'-Azobis[2-methylpropionitrile] (Azobisisobutyro- 

nitrile) . 

N,N-Bis(2,2'-acetamido)glycine 

N-Bis(hydroxyethyl)amino alkanol 

l,3-BisChydroxymethyl)urea (nimethylolurea) 

N,0-Bis(trimethylsilyl)acetamide 

N,N-Bis-(trimethylsilyl)acetamide 

N,0- Bis- Ctrimethylsilyl)trifluoroacet amide 

Biuret 

N-Bromoacet amide 

N-Bromosuccinimide (Succinibromimide) 

2,3-Butanedione monoxime 

2-Butanone oxime 



Manufacturers' identification codes 
(according to list in table 3) 



AIP, UCC. 

AIP, UCC, VGC. 

AIP, COM, DUP, GAP. 

EK, RSA. 

RH. 

AIP, COM, DUP, GAP. 

AIP, COM, DUP, GAP. 

VGC. 



JCC, 


UCC. 






PAS, 


VGC. 






PAS. 








PAS. 








NLC. 








UCC. 








JCC, 


X. 






AIP, 


PAS, 


UCC, 


VGC. 


AIP, 


PAS, 


UCC, 


VGC. 


PAS, 


VGC. 






DOW, 


JCC, 


UCC. 




UCC. 








RH. 








DOW, 


JCC, 


UCC. 




ALB, 


ALD, 


BPC, 


DUP, EK, LIL, NIL, ONX, PAS, PIC 


UCC, VGC, X. 




COM. 








JCC. 








DOW, 


HDG, 


JCC, 


UCC. 


EVN. 








COM. 








COM. 








COM. 








COM 


JCC. 






COM. 








VAL. 








UCC. 








NPI, 


USR 






x. 








DUP 


FMT 







HMP. 

TX. 

GLY, X. 

PIC. 

ALD. 

PIC. 

DOW. 

ARA. 

ARA. 

CDY, EK. 

ALB. 



ISCELLANEOUS CHEHICALS 



TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197^--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLlC--Continued 

Nitrogenous Compounds — Continued 

l-Butyl-3-ethyl- 2- thiourea 

Butyl isocyanate 

n-Butyronitrile 

*Caprolactam (2-Oxohexamethylenimine) 

Chlorocholine chloride 

2-Chloro-N,N-diethylethylaiiiine hydrochloride 

2-Chloro-N,N-dimethylethylaiiiine (Dimethylamino ethyl 
chloride) hydrochloride. 

3- Ch loro-N,N- dime thy Ipropyl amine 

2-Chloro-N,N-dime thy Ipropyl amine hydrochloride 

3-Chloro-N,N-dimethy Ipropyl amine hydrochloride 

2-Chloroethylamine, hydrochloride 

3-Chloro-2-hydrox>'propyltrimethyl , ammonium chloride- 

Chloro-N- (2-hydroxye thy l)acet amide 

N-Chlorosuccinimide (Succinichlorimide) 

2-Chlorotriethylamine hydrochloride 

Choline base 

Choline bicarbonate 

Choline bisulfite 

Coco nitrile 

Coconut oil acids - ammonium condensate 

Coconut oil amide 

Cyanoacetic acid 

Cyanogen bromide 

2,2'-Di- (3-aminopropoxy)ethyl ether 

2-Dibutylaminoethanol 

l,3-Dibutyl-2-thiourea 

1,4-Dicyanobutene 

2-Diethylaminoethanol 

2- (2-Diethylaminoethoxy)ethanol 

2-Diethylaminoethyl aery late 

2-Diethylaminoethyl methacrylate 

Diethylcarba-Tioyl chloride 

Diethyldithiocarbamic acid, sodium salt 

N,N-Diethyldodecanamide 

Die thy Ihydroxyl amine 

1,3-Diethyl -2- thiourea 

Diisopropylaminoethanol 

2-niisopropylamino ethyl chloride hydrochloride 

N,N-Dimethylacetamide 

2-Dimethylaminoethanethiol hydrochloride 

2-Dimethylaminoethanol 

Dime thy laminoethyl aery late 

Dimethyl aminoethyl methacrylate 

Dimethylaminoethyl methacrylate, methyl chloride 
quaternary salt. 

2-Dimethylamino-2-methyl-l-propanol 

Dimethyl amino- 2 -prop and 

3-Dimethylaminopropionitrile 

Dimethylenetriaminepentamethylene phosphonic acid 

N,N-Dimethylformamide 

1,1-Dimethylhydrazine 

Dimethylol methoxyethyl carbamate 

Dime thy Ithiocarbamoyl chloride 

2,S-Dithiobiurea 

*Erucamide 

Erucamide - Lauramide 



PAS. 






CWN, 


OTC, 


UPJ. 


EKX. 






ACP, 


CNP, 


DEC. 


ACY. 






HEX, 


MCH. 




HEX, 


MCH. 




SK. 






MCH. 






MCH. 






NES. 






OTC. 






KF. 






ARA. 






CCY. 






RH. 






TCH. 






WAY. 






ARC, 


ASH. 





EK. 






UCC. 






AAC, 


PAS. 




PAS. 


RBC. 




DUP. 






AAC, 


PAS, 


UCC. 


PAS. 






ABC, 


UCC. 




DUP. 






ASH. 






EK. 






EK. 






PAS. 






PAS, 


RBC. 




PAS, 


UCC. 




MCH. 






DUP. 






EVN. 






AAC, 


PAS, 


RH, UCC. 


ABC. 






AAC, 


CPS. 




AAC. 






COM. 






PAS. 






ABB, 


ACY, 


UCC. 


WAY. 






AlP, 


DUP. 




FMP. 






DAN. 






ald. 






ACY. 






ARC, 


ASH, 


FIN, HUM 


FIN. 







SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2.- 



-fllSCELLANEOUS CHEMICALS FOR WHICH U.S. PRODUCTION OR SALES WERE REPORTED. 
IDENTIFIED BY MANUFACTURER. 1974--CoNTINUED 



MISCELLANEnUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

*Ethanolamines : 

*2-Aniinoethanol (Monoethanol amine) 

*2,2'-Aminodiethanol (Diethanolamine) 

*2,2'2' '-Nitrilotriethanol (Triethanolamine) 

Ethoxymethyl enema lononitrile 

3-Ethoxypropionitrile 

2-Ethylaminoethanol (Ethylmonoethanolamine) 

Ethyl cyanoacetate 

Ethyl diazoacetate 

*N,N' -Ethylene bis Cstearamide) 

2-Ethylhexyl ammonium tridecylphosphate 

5- (N-Ethyl-N-hydroxyethylamino) -2-pentanone 

Ethylmonoethanolamide, mixed 

Fish oil fatty acid amide 

Formamide 

Glycine (Aminoacetic acid) 

Glycine ethyl ester hydrochloride 

Glycolonitrile 

4-Guanyl-l-nitrosoguanyl-l-tetra2ine 

♦Hexamethylenediammonium adipate (Nylon salt) 

Hexamethylene phosphoric triamide 

Hydracrylonitrile (Ethylene cyanohydrin) 

Hydrazine hydrate (100%) 

2-(Hydroxymethyl)-2-nitro-l,3-propanediol (Tris- 
(hydroxymethyl)nitromethane) . 

Iminodiacetic acid 

Iminodiacetic acid, disodium salt 

1 sob utyronit rile 

Isopropanolamines : 

l-Amino-2-propanol (Monoisopropanolamine) 

l,l'-Iminodi-2-propanol (Diisopropanolamine) 

1,1' ,1' '-Nitrilotri-2-nropanol (Tri isopropanol amine ) - 

2-Isopropylaminoethanol 

Isopropylethylthionocarbamate 

Ketimine, tetrafunctional 

Lactonitrile 

Lauronitrile (Dodecyl nitrile) 

Methacryl amide 

Methacrylonitrile 

Methoxyethyl carbamate 

3-riethoxypropyl amine 

N-Methylacetamide 

N-'lethylacetamide, sodium salt 

2-Methylaminoethanol (N-Methylethanolamine) 

5-Methyl-2- ami nohexane 

Methylcarbamate 

Methyl cyanoacetate 

Methyl a-cyanoacrylate 

N, N'->1ethylenehi 5 (aery 1 amide) 

2,2'-(Methylimino)diethanol (^1ethyldiethanolamine) 

Methyl isocyanate 

2-Methyl lactonitrile (Acetone cyanohydrin) 

2-Methyl-2-(methylthio)propionaldoxime 

2-Methyl-2-nitro-l-propanol 

Methylpolyethanolamine 

N- »1e thy 1 1 aurine 

N-Methylurea 

*Nitriloacids and salts: 

(niethylenetrinitrilo)pentaacetic acid 

(niethylenetrinitrilo)pentaacetic acid, monosodium 
hydrogen ferric salt. 



Manufacturers' identification codes 
(according to list in table 3) 



DUP, MON. 



DOW, 

DOW, 

DOW, 

ALD. 

DIX. 

PAS. 

KF. 

ALD. 

CCW, 

DUP. 

SDW. 

PAS. 

HUM. 

DUP. 

CHT. 

BPC. 

KF. 

REM. 

CEL, 

DUP. 

AAE. 

USR. 

COM. 



HMP. 
HMP. 
AlP, EKX. 

DOW, UCC. 
DOW, UCC. 
DOW, UCC. 
PAS. 
DOW. 
GNM. 
MON. 
ARC, ASH. 

X. 

SOH. 

DAN. 

JCC. 

ARS, EK. 

ARS. 

PAS, UCC. 

PAS. 

FHP. 

KF. 

EKT. 

ACY, SOH. 

PAS, UCC. 

OTC, UCC. 

RH, X. 

UCC. 

COM. 

GAF. 

GAF. 

LIL. 

HMP. 
CGY. 



GLY, JCC, CMC, UCC. 
JCC, OMC, UCC. 
JCC, OMC, UCC. 



DA, HUM, NLC. 



?1ISCELLANE0US CHENICALS 



TABLE 2.- 



-Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER, 1974--C0NTINUED 



^^anufacture^s ' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

'Nitriloacids and salts--Continued 
* (Diethylenetrinitrilo)pentaacetic acid, nentasodium 
salt. 

(niethylenetrinitrilo)rientaacetic, sodium salt 

N,N-Dihydroxvethylglvcine, sodium salt 

Ethanoldiglycine, disodium salt 

(Ethvlenedinitrilo)tetraacetic acid CEthylenediamine- 

tetraacetic acid). 
(Ethvlenedinitrilo)tetraacetic acid, calcium disodium 

salt. 
(Ethylenedinitrilo)tetraacetic acid, diammonium salt — 
(Ethylenedinitrilo)tetraacetic acid, diammonium zinc 
salt, dihydrate. 

(Ethylenedinitrilo)tetraacetic acid, disodium salt 

(Ethylenedinitrilo)tetraacetic acid, disodium copper 

salt, dihydrate. 
(Ethylenedinitrilo)tetraacetic acid, disodium zinc 
salt, dihydrate. 

(Ethylenedinitrilo)tetraacetic acid, manganese salt 

(Ethylenedinitrilo)tetraacetic acid, monoammonium 

iron salt. 
(Ethylenedinitrilo) tetraacetic acid, monosodium iron 

salt. 
(Ethylenedinitrilo)tetraacetic acid, tetraammonium 

salt, 
(Ethvlenedinitrilo)tetraacetic acid, tetrapotassium 
salt. 
*(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt-- 

(Ethylenedinitrilo)tetraacetic acid, trisodium salt 

(N-Hydroxye thy lethvlenedinitrilo)tri acetic acid 

(N-Hydroxyethylethylenedinitrilo)triacetic acid, copper 

salt. 
(N-Hydroxyethylethylenedinitrilo)triacetic acid, iron 

salt. 
(N-Hydroxye thy lethylenedinitri Id) tri acetic acid, 

magnesium salt. 
(N-Hydroxyethylethylenedini tri lo) tri acetic acid, 
manganese salt. 
* (N-Hydroxye thy 1 ethyl enedinitrilo) tri acetic acid, 
trisodium salt. 

Ni tri lotri acetic acid 

Nitrilotriacetic acid, trisoditm salt 

Nitrilo-tris-methylene triphosnhonic acid 

Nitrilo-tris-methylene triphosphonic acid, sodium 
salt. 

Other 

Nitrilotriacetonitrile 

2-Nitro-l-butanol 

Nitroethane 

Nitrome thane 

1-Nitropropane 

2-Nitropropane 

*Nylon, 6 and 6/6 polymer for fiber 

Octadecyl isocyanate 

N-nctylethanol amine 

Oleamide (Octadecene amide) 

Oleic acid - ethylenediamine condensate (amine/acid 
ratio=l/2) . 

Oleonitrile (Octadecene nitrile) 

Oleoylnalmitamide 

Oleyl nitrate 

*Pentaerythritol tetranitrate 



COY, DAN, DOW, H"P. 



COY, 

now, 

HMP. 
COY, 



DOW, 
DOW. 



COY, 
DOW 



DOW, 



COY, 
COY, 
H>'P. 
HMP. 

H»'P. 

Hf'P. 



RPC. 
H"P. 

DOW, HMP. 

HMP. 

HMP. 



DOW, EK, HMP, RPC. 
HMP. 



CPT, DAN, Dnw, WiP, JOR, RPC. 
HMP. 



COY, 


CRT, 


DAN, 


DOW, 


e!P, RPC 


m'P. 










DOW, 


HMP, 


MON. 






WAY. 










WAY. 










EK, 


HMP, 


WAY. 






HMP. 










COM. 










COM. 










COM. 










COM. 










C0^^. 










ALF, 


CEL 


DBC, 


DUP, 


MON. 


MOB, 


UPJ 








X. 










ARC 


FIN 


OLY, 


HUM. 




CCK 










ARC 










FIN 










SM. 










COM 


DUP 


HPC. 







SYNTHETIC ORGANIC CHEMICALS, 1974 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were REPORiEDy 

IDENTIFIED BY MANUFACTURER^ 197'<--C0NTINUED 



^Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Nitrogenous Compounds — Continued 

Pentyl nitrate fAmyl nitrate) S hexyl nitrate 

*Poly aery 1 amide 

Polyacrylamide polyners other than polvacrylamide 

* Poly aery 1 on itrile 

Polyalkylene amine 

Polyamide resin (flake) 

Polyaminonolymethylene phosphonic acids 

Polyethoxy (Hydrogenated tallow) amide 

Polyethyleneimine 

Polyoxypropylenedi amine 

Propyl eneimine 

Propyl isocyanate 

Ricinol amide 

Sarcosine (N-Methylaminoacetic acid) 

Senicarbazide hydrochloride 

Stearamide (Octadecane amide) 

Stearonitrile (Octadecanenitri le) 

Stearylerucamide 

Tallow anide, hydrogenated 

Tallow nitrile 

Tallow nitrile, hydrogenated 

N ,N ,N ' ,N ' -Tetraki s C2-hydroxypropvl ) ethyl enedi amine 

Tetramethyl ammonium bromide 

Tetramethyl ammonium hydroxide 

Tetramethylguanidine 

Thioacet amide 

3,3'-Thiodipropionitrile 

Thiosemicarbazide-- 

N-Trimethylsilylacetamide 

*Urea in compounds or mixtures, 100% basis: 

*In feed compounds 

*In liquid fertilizer 

*In solid fertilizer 

*ln plastics 

All other 

Urea ammonium nitrate solution 

Urea - urethane copolymer 

All other nitrogenous comnounds 



TNA. 

ACY, 

ACY. 

ACY. 

NLC. 

MON. 

TXT. 

ARC. 

AAC, 

JCC. 

ARS. 

OTC. 

TKL. 

CCY, 

FMT. 

ARC, 

ARC, 

FIN. 

ARC. 

ARC, 

ASH. 

BAS. 

RSA. 

RSA. 

ACY. 

EK, 

ACY, 

ACY. 

LIL. 



DOW, HPC, NLC. 
DBC, DUP, EKX, MON. 



FIN, GLY, HUH. 
ASH. 



RBC. 
EVN. 



ACN, AIP, AKL, APD, ACY, FTX, GCC, HKY, JDC, MSC, 

PPC, SNI, SOH, TER, TRI , VLN, WYC . 
ACN, ACS, A(^Y, AIP, AKL, APD, AR", CFA, CHN, CNC, 

FCA, FTX, GCC, HKY, HPC, JDC, MSC, PLC, PPC, SNI, 

SOH, TER, TRI, TVA, VLN, WLC, WYC 
ACN, ACS, ACY, AKL, APD, CFA, COL, FMS, GCC, HPC, 

JDC, MSC, OMC, PPC, SOH, TER, TRI, T\'A, VLN, WLC, 

WYC. 
BOR, F^^S, MSC, OMC, SOH, TRI. 
DAN, DUP, PPC, SOH, SNW, TER, WAY, mC. 

mc. 

DUP. 

ABB, ALB, ALD, ARC, AZT, CDY, CHP, COM, DUP, EFH, 
EK, B'N, GAF, GNU, IP'P, HUM, ICI, JCC, KF, LIL, 
MAL, HOB, OTC, PAS, PD, PEN, PFZ, PIC, RSA, S, 
SBC, SDW, SM, SNW, STC, TWA, TXT, UCC, USR, VND, 
WAY, WLC, ZGL, x. x, x. 



Acids, Aoid Anhydrides, and Aoyl Ealides 

*Acetic acid, synthetic, 100% 

♦Acetic anhydride, 100%; 

From acetic acid 

From ethylene 

*Acrylic acid 

*Adipic acid 

Azelaic acid 

Behenic acid 

Bromoacetic acid 



ATR, BOR, CEL, EKT, FMP, MON, PUB. UCC. 

CHL, EKT, FMP. 

UCC. 

BFG, CEL, DBC, UCC. 

CEL, DUP, ELP, MON, RH. 

EMR. 

ASH. 

^1CH. 



MISCELLANEOUS CHEMICALS 



TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197'l— CONTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Aaids, Acid Anhydrides, and Aoyl flalides— Continued 

tert-Butylneroxvmaleic acid 

Butyric acid 

But y r i c anhydri de 

Castor oil fatty acids, dehydrated 

Chloroacetic acid, mono- 

Chloroacetyl chloride 

2-Chloropropionic acid 

Citric acid 

Crotonic acid (2-Butenoic acid] 

Decanoyl chloride 

Dimethyl Drop ionic acid 

Di-n-propylacetic acid and chloride 

Dipropylmalonic acid 

Dodecanedioic acid 

*Dodecenyl succinic anhydride 

Dodecyl succinic anhydride 

Erucic acid 

2-Ethylbutyric acid CDiethylacetic acid) 

2-Ethylhexanoic acid (a-Ethylcaproic acid) 

2-Ethylhexanoyl chloride 

'Formic acid, 90% 

*Fumaric acid 

Gluconic acid, tech 

G lut ar i c anhydri de 

Glycolic acid [Hydroxyacetic acid) 

n-Hexadecenyl succinic anhydride 

n-Hexanoic acid 

1-Hydroxyethylidene-l ,l-diDhost)honic acid 

Isethionic acid (2-Hydroxyethanesulfonic acid) 

Isoascorhic acid 

Isobutyric acid 

Isobutyric anhydride 

Isobutyryl chloride 

Iso-octadecenylsuccinic anhydride 

Itaconic acid (Methylenesuccinic acid) 

2-Keto-D-gluconic acid 

Lactic acid 

* Lauroy 1 chloride 

Maleic acid 

*Maleic anhydride 

Malic acid 

Malonic acid 

Mercaptoacetic acid (Thioglycolic acid) 

3-Mercaptopropionic acid 

Mercaptosuccinic acid (Thiomalic acid) 

Methacrylic acid 

Methanesulfonic acid 

Methanesulfonyl chloride 

Neodecanoic acid 

Neodecanoyl chloride 

NeoDentanoic acid 

Nonanoic acid (Pelargonic acid) 



Manufacturers' identification codes 
(according to list in table 3) 



WTL. 






CEL, EKT. 






EKT. 






NTL. 






BUK, DOW, X. 






DOW. 






DO!V. 






MLS, PFZ. 






EKT. 






WTL. 






COM. 






ARA. 






ARA. 






DUP. 






ACS, DIX, HMY. 






HN. 






ASH. 






UCC. 






EKT, UCC. 






AZT, IVTL. 






CEL, DUP, UCC. 






ACS, HN, MON, PFZ 


USS. 




PFZ. 






UCC. 






DUP. 






H><Y. 






UCC. 






WAY. 






GAF, WTC. 






»1RK, PFZ. 






EKT, EKX. 






EKT. 






WTL. 






HMY-. 






PFZ. 






MRK. 






CLN, MON. 






HK, ONX, TEK, UOP, 


WTTL. 




ACS, PFZ. 






HN, KPT, MON, PTT, 


RCI, SOC, USS. 


ACS, EK. 






KF. 






e™. 






EVN. 






EVN. 






DUP, RH. 






EK, PAS. 






PAS. 






ENJ. 






OTL. 






ENJ. 






EUR, GIV. 







SYNTHETIC ORGANIC CHE^llCALS. 197'^ 



TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1974--C0NTI NUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Aaids, Aaid Anhydrides , and Aoyl Halides — Continued 

Nonenylsuccinic anhydride 

Oleic acid 

Octanoyl chloride 

Oc t any 1 succinic anhydride 

Oleoyl chloride 

Oxalic acid 

Palmitoyl chloride 

Peroxyacetic acid 

Pivaloyl chloride 

*Polyacrylic acid 

♦Propionic acid 

Propionic anhydride 

Pronionyl chloride 

Sebacic acid 

Sebacoyl chloride 

Stearoyl chloride 

Succinic acid 

Succinic anhydride 

Tetrahydroxysuccinic acid (Dioxytartaric acid) 

Thioacetic acid 

Thio lactic acid 

3,3' -Thiodipropionic acid 

Tri ch loroacet i c acid 

Valeric acid 

All other 



Salts of Organic Acids 

* Acetic acid salts: 

Aluminum acetate 

Ammonium acetate 

* Barium acetate 

Calcium acetate 

Chromi um acetate 

Cobalt acetate 

Coppe r acetate 

Lead acetate 

Lead subacetate 

Lead tetraacetate 

Magnesium acetate 

Manganese acetate 

Mercuric acetate 

Nickel acetate 

♦Potassium acetate 

Silver acetate 

Sodium acetate 

Sodium diacetate 

*Zinc acetate 

Zirconium acetate 

Other acetic acid salts 

Acrylic acid, sodium salt 

Adinic acid, ammonium salt 

Allylsulfonic acid, sodium salt 

Chloroacetic acid, sodium salt 

Citric acid salts: 

Ammonium citrate 

Calcium citrate 

Ferric ammoniiun citrate 

Ferric citrate 



Manufacturers' identification codes 
(according to list in table 3) 



HMY. 
ASH. 
HK. 

GAP, HRT. 
ACS, PFZ. 
GAF, OPC. 
FHE, UCC. 
AZT, WTL. 
AAE, DA, RH. 
CEL, COM, EKT, UCC. 
EKT. 
EK. 

RH, IVTH. 
IVTL. 

GAF, UOP. 
ACS. 

ACS, ORO. 
ACY. 
EVN. 
EVN. 

CCW, B'N. 
DOW. 
UCC. 

ABB, ALD, AJi'B, EK, EKX, ENJ , ETO, GAF, HMY, LIL, PAS, 
PFN, PLC, OKO, RH, RSA, SHA, WAY. 



ACY, 


UCC. 






ACS, 


BKC, 


MAL. 




ACS, 


BKC, 


MAL. 




ACS, 


MAL. 






SHP. 








HSH, 


SHP. 






ACS, 


BKC. 






BKC, 


MAL. 






BKC, 


MAL. 






ARA. 








BKC, 


SHP. 






HSH, 


SHP. 






MAL. 








BKC, 


HSH, 


SHP. 




ACS, 


BKC, 


MAL, 


UCC. 


MAL, 


RSA. 






ACS, 


BKC, 


D.^N, 


EKT, MAL, UCC 


UCC. 








ACS, 


BKC, 


HSH, 


MAL, SHP, UCC 


HSH, 


SNF, 


TZC. 




MAL. 








AAE. 








ASH. 








IOC, 


NES, 


UOP. 




DOl'i. 








MAL 


PFZ 






PFZ. 








MAL 


PFZ 






MAL 









MISCELLANEOUS CHEniCALS ; 

TABLE 2. --Miscellaneous chemicals for which U.S, production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 1974--CONTI NUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Coiitinued 

Salts of Organic Acids — Continued 

Citric acid salts--Continued 

Potassium citrate 

Sodium citrate ' 

Other citric acid salts 

Diethyl chlorophosphate 

Di-n-propylacetic acid, sodium salt 

*2-Ethylhexanoic acid (a-Ethylcaproic acid) salts: 

Aluminum 2-ethylhexanoate 

Barium 2-ethylhexanoate 

Cadmium 2-ethylhexanoate 

♦Calcium 2-ethylhexanoate 

*Cobalt 2-ethylhexanoate 

Copoer 2-ethylhexanoate 

Iron 2-ethylhexanoate 

*Lead 2-ethylhexanoate 

Lithium 2-ethylhexanoate 

♦Manganese 2-ethylhexanoate 

♦Nickel 2-ethylhexanoate 

Potassium 2-ethylhexanoate 

Rare earths 2-ethylhexanoate 

Stannous 2-ethylhexanoate 

♦Zinc 2-ethylhexanoate 

♦Zirconium 2-ethylhexanoate 

All other 

Formic acid salts; 

Aluminum formate 

Ammonium formate 

Calcium formate 

Chromic formate 

Coppe r formate 

Lead forma te 

Sodium formate, refined 

♦Sodium formate, tech 

Fumaric acid, lead salt 

Glucoheptonic acid salts: Sodium glucoheptanoate 

♦Gluconic acid, sodium salt 

9H-Hexadecaf luorononanoic acid, ammonium salt 

Humic acids, sodium salts 

Isoascorbic acid, sodium salt 

Lactic acid salts: 

Calcium lactate 

Sodium lactate 

Laurie acid, zinc salt 

Linoleic acid salts: 

Calcium linoleate 

Manganese linoleate 

Maleic acid salts: Lead Ctribasic) maleate 

Mercaptoacetic acid (Thioglycolic acid) salts: 

Ammonium mercaptoacetate 

Antimony mercaptoacetate 

Calcium mercaptoacetate 

Dibutyltin mercaptoacetate 

Potassium mercaptoacetate 

Sodium mercaptoacetate 

Mercaptopropionic acid, dibutyltin salt 

Methacrylic acid, sodium salt 



Manufacturers' identification codes 
(according to list in table 3) 



MLS, PFZ. 
MLS, PFZ. 
EK. 
SFA. 
ARA. 

PFZ, IVTC. 

CCA, TRO. 

CCA. 

CCA, FER, HN, MCI, PFZ, SW, TRO, WTC . 

CCA, FER, HN, MCI, SHP , SW, TRO, WTC. 



CCA. 






CCA, HN, SHP. 






CCA, FER, HN, 


NTL, SH", 


WTC. 


OTC. 






CCA, FER, HN, 


MCI, SHP. 




MCI, SHP, IVTC 






CCA, MCI. 






CCA. 






WTC. 






CCA, FER, HN, 


MCI, SHP, 


SW, WTC 


CCA, FER, HN, 


MCI, TRO, 


WTC. 


MCI, SHP. 






WSN. 






ACS, RSA. 






COM. 






GAF. 






CTN. 






NTL. 






ACS, BKC. 






CEL, COM, HPC 


, PNA. 




NTL. 






HMP. 






PFZ, SFI, X. 






IVTC. 






NLC. 






MRK, PFZ. 






SHE. 






MAL. 






SNIV. 






CCA, SHP. 






SHP. 






NTL. 






EVN, TNI. 






CCA. 






EVN. 






CCA. 






EVN. 






EVN. 






CCA. 






AAE. 







SYNTHETIC ORGANIC CHEMICALS, 197'l 



TABLE 2. --Miscellaneous chemicals for which U.S, production or sales were reported. 

IDENTIFIED BY MANUFACTURER, 1974--C0NTI NUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Cont inued 

Salts of Organic Acids — Continued 

Neodecanoic acid salts: 

Cadmium neodecanoate 

Calcium neodecanoate 

Cobalt manganese neodecanoate 

Cobalt neodecanoate 

Lead cobalt neodecanoate 

Lead neodecanoate 

Lithium neodecanoate 

Manganese neodecanoate 

Zinc neodecanoate 

Zirconium neodecanoate 

•Octanoic acid (Caprylic acid) salts: 

Aluminum octanoate 

Barium cadmium octanoate 

S tannous octanoate 

Other 

*01eic acid salts: 

Aluminum oleate 

Chromium oleate 

Copper oleate 

Lead oleate 

Stannous oleate 

Other oleic acid salts 

Oxalic acid salts: 

Ammonium oxalate 

Ferric ammonium oxalate 

Potassium oxalate 

Sodium oxalate 

Palmitic acid salts: 

Aluminum palmitate 

Zinc palmitate 

Phosphorodithioic acid salts (Dithiophosphates) : 

Potassium dihexyl phosphorodithioate 

Sodium di-sec-butyl diethyl phosphorodithioate 

Sodium di-sec-butyl phosphorodithioate 

Sodium diethyl phosphorodithioate 

Sodium dihexyl phosphorodithioate 

Sodium diisopropyl phosphorodithioate 

Polyacrylic acid salts: 

Ammoniiom polyacrylate 

Sodium ammonium polyacrylate and copolymers 

Sod ium polyacrylate 

Polymethacrylic acid, sodium salt 

Propionic acid salts: 

Calcium propionate 

Sodium propionate 

Ricinoleic acid salts: 

Calcium ricinoleate 

Lithium ricinoleate 

Sodium ethyl oxalacetate 

Sodium polypectate 

Sodium sorbitol borate 

•Stearic acid salts: 
•Aluminum stearates: 

•Aluminum distearate 

♦Aluminum monostearate 

•Aluminum tristearate 

Ammonium stearate 

•Barium stearate 

Cadmium stearate 

•Calcium stearate 



Manufacturers ' identification codes 
(according to list in table 3) 



CCA. 

CCA, MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

MCI. 

CCA , MC I . 

MCI. 



CCA 




CCW, 


X. 


BKC, 


DA. 


SHP, 


WTC. 


SHP. 




WTC. 




NOC. 




CCW, 


X. 


ARS, 


SHP. 


ACS, 


PFZ. 


PFZ. 




BKC, 


PFZ. 


BKC. 




DA. 




DA, 


WTC. 


ACY. 




ACY. 




ACY. 




ACY. 




ACY. 




ACY. 




BFG. 




BFG. 




ALC, 


BFG, DA, RH, STC 


GRD. 




HFT 


PFZ. 


HFT, 


PFZ. 


NIL 




NTL 




FMP 




SKG 




ICI 





DA, MAL, NOC, PEN, SYP , WTC. 

DA, MAL, NOC, SYP, WTC. 

DA, MAL, NOC, PEN, SYP, IVTC. 

DA. 

DA, NOC, PEN, SYP, IVTC . 

SYP, WTC. 

ACY, DA, FER, HN, JTC, MAL, NOC, PEN, SYP, WTC. 



MISCELLANEOUS CHEHICALS 



TABLE 2,— Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197i|--C0NTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
Salts of Organic /leids- -Continued 

•Stearic acid salts--Continued 

Cobalt stearate 

Copper stearate 

Ferric stearate 

Ferrous stearate 

Lead stearate 

Lead stearate, dibasic 

Lithium stearate 

*Magnesium stearate 

Nickel stearate 

Silver stearate 

*Zinc stearate 

All other 

Succinic acid, sodium salt 

Sulfosuccinic acid, trisodiura salt 

Tartaric acid salts: 

Antimony potassium tartrate 

Potassium sodium tartrate 

Valeric acid, ammonium salt 

Xanthic acid salts: 

Potassium amylxanthate 

Potassium ethylxanthate 

Potassium hexylxanthate 

Potassium pen tylxan that e 

Sodium n-butylxanthate 

Sodium sec-butyl xanthate 

Sodium ethylxanthate 

Sodium isobutylxanthate 

Sodium isopropylxanthate 

All other salts of organic acids 

Aldehydes and Ketones 

Acetaldehyde 

*Acetone : 

*From cumene 

From isopropyl alcohol 

Other 

Acrolein (Acrylaldehyde^ 

*2-Butanone (Methyl ethyl ketone) 

*Butyraldehyde 

Chloral (Trichloroacetaldehyde) 

5-Chloro-2-pentanone 

l-Chloro-l-penten-3-one (S-Chlorovinyl ethyl ketone V 

Chloro-2-propanone (Chloroacetone) 

Crotonaldehyde 

l,3-Dihydroxy-2-propanone (Dihydroxy acetone) 

2,4-Dimethyl-3-pentanone 

Ethyl amyl ketone 

Ethyl butyl ketone 

2-Ethylbutyraldehyde 



Manufacturers ' identification codes 
(according to list in table 3) 



WTC. 
NOC, 
SHP 

MCr 



WTC. 
NOC. 
NOC, WTC. 

PEN, SYP, WTC. 
DA, MAL, NOC, PEN, SYP, WTC. 



DA, HN, MAL, NOC, PEN, SNW, SYP, WTC. 
NOC. 



mL. 
STP. 

PFZ. 
PFZ. 
RSA. 

DOW. 
DOW. 
DOW. 
ACY. 

KCC, USR. 
DOW. 
DOW. 
DOW. 
DOW. 

ALD, BAX, BKC, CRN, DA, EK, MCI, MLS, SDH, SHF, SHP, 
UCC, x. 



CEL, EKT, EKX, PUB, SHC, UCC. 

ACS, CLK, DOW, GP, GYR, MON, SHC, SKO, SOC, UCC, USS. 

EKT, ENJ, SHC. UCC. 

CEL, DIX, OCC. 

SHC, UCC, X. 

ATR, CEL, DIX, ENJ, SHC, UCC. 

CEL, EKX, UCC. 

DA, ^m). 



EK, MRK. 




CEL, EKT, 


UCC. 


BAX. 




EKX. 




SHC. 




UCC. 




UCC. 





SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--C0NTINUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Aldehydes and Xetones--Continued 

2-Ethylhexanal (a-Ethylcaproaldehyde) 

♦Formaldehyde (37% by weight) 

Glutaraldehyde 

Glyoxal 

2-Heptanone (Methyl amyl ketone) 

Hexaf luoroace tone 

2,5-Hexanedione (Acetonylacetone) 

*4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol) — 

*Isobutyraldehyde 

Isopentaldehyde, mixed isomers 

Isovalerone (Diisobutyl ketone) 

Lac tide (3,6-Dimethyl-2,5,p-dioxanedione) 

Me th acrolein 

4-Methoxy-4-methyl-2-pentanone 

2-Methylbutyraldehyde 

S-Methyl-2-hexanone (Methyl isoamyl ketone) 

Methylnonyl ketone 

*4-Methyl-2-pentanone (Methyl isobutyl ketone) 

Methylpentenal 

*4-Methyl-3-penten-2-one (Mesityl oxide) 

2-Methylvaleraldehyde (2-Methylpentaldehyde) 

n-Nonyl ketone 

2-Octanone (Hexyl methyl ketone) 

Paraformaldehyde 

2,4-Pentanedione (Acetyl acetone) 

3-Pentanone (Diethyl ketone) 

Propionaldehyde 

Pseudoionone 

2,6,8-Trimethyl-4-nonanone (Isobutvl heptyl ketone)- 

Valeraldehyde 

All other 

Alaohols, Monohydria, Unsubstituted 

•Alcohols Cii or lower, unmixed: 

Allyl alcohol 

Amyl alcohols: 

2-Methyl-l-butanol 

2-Methyl-2-butanol 

1-Pentanol 

Butyl alcohols : 
Primary : 

*Iso (Isopropylcarbinol) 

*Normal (n- Propylcarbinol) 

Secondary (Methylethylcarbinol) 

Tertiary (Trimethylcarbinol) 

1-Decanol 

2,6-Dimethyl-4-heptanol (Diisobutylcarbinol) 

•Ethyl alcohol, synthetic 

2-Ethyl-l-butanol 

*2-Ethyl-l-hexanol 

2-Ethyl-4-methyl-l-pentanol 

Heptyl alcohol 

3-Hexyne-2-ol 

*Hexyl alcohol 

Isodecyl alcohol 

Iso-octyl alcohol 

*Isopropyl alcohol 

•Methanol, synthetic 



Manufacturers' identification codes 
(according to list in table 3) 



EKX UCC. 

Acs', bor, cbd, cel, com, nup, g/vf, goc, gp, hkd, hn, 

HPC, MON, RCI, RH, UCC, WCL. 
UCC. 
UCC. 
UCC . 
DUP. 
ARS. 

CEL, SHC, UCC. 
DEC, EKX, OXC, UCC. 
UCC. 
UCC. 
CLN. 

ALD, RDA. 
SHC. 
UCC. 
EKT. 
CRT. 

CEL, EKT, ENJ, SHC, UCC. 
UCC. 

ENJ, SHC, UCC. 
EKX, UCC. 
ARC. 
WTH. 

CEL, HN. 
UCC. 

HEX, CRT. 
EKX, UCC. 
RDA. 
UCC. 
UCC. 
ALD, AZT, EK. 



FMP, 


SHC. 
















CPS, 


UCC 
















ENJ. 


















UCC. 


















DBC, 


EKX 


OXC 


SHC 


UCC 










CEL, 


CO, 


DBC, 


EKX, 


GAF, 


OXC, 


SHC, 


TNA, 


UCC. 


ENJ, 


SHC 


UCC 














SHC 


X. 
















CO, 


PG. 
















UCC 


















EKX 


ENJ 


PUB 


SHC 


UCC 


USI 


X. 






UCC 


















CEL 


DBC 


EKX 


OXC 


SHC 


UCC 








EKX 


















EKX 


















LIL 



















CO, ENJ, PG, TNA, UCC. 
ENJ, TID, UCC, USS. 
ENJ, TID, USS. 
ATR, CEL, ENJ, SHC, UCC. 
AIP, ALD, ATR, BOR, CEL, 
RH. 



COM, DUP, GP, HN, HPC, MON, 



MISCELLANEOUS CHEMICALS 



TABLE 2,- 



-Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 197'^--CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Alaohols, Monohydria, Unsi4bstituted--Continued 

•Alcohols Cji or lower, unmixed--Continued 

Methyl amyl alcohol 

3-Methyl-l-butanol 

2-Methyl-l-pentanol 

4-Methyl-2-pentanol (l-Methylisobutylcarhinol) 

Nonyl alcohol 

1-Octanol 

2-Octanol Csec-Capryl alcohol) 

3-Pentanol 

♦Propyl alcohol (Propanol) 

2-Propyn-l-ol 

♦Alcohols, Ci2 or higher, unmixed: 

1-Pecanol 

Dodecyl alcohol (Lauryl alcohol) (95%) 

7-Ethyl-2-methyl-4-hendecanol 

1-Hexadecanol (Cetyl alcohol) (95%) 

Hexadecyl alcohols, other 

1-Octadecanol (Stearyl alcohol) (95%) 

cis-9-Octadecen-l-ol (Oleyl alcohol) 

1-Tetradecanol (Myristyl alcohol) 

1-Tridecanol 

2,6,8-Trimethyl-4-nonanol 

♦Mixtures of alcohols: 

*Cii and lower only 

*Ci2 and higher only 

All other monohydric alcohols, unsubstituted (including 
mixtures) . 

Polyhydria Alaohols and Their Esters and Ethers 

*Polyhydric alcohols: 

2,2-Bis(hromomethyl)-l,3-propanediol 

1,2 (and 1 ,3)-Butanediol 

1,4-Butanediol 

2-Butene-l ,4-diol 

2-Butyne-l,4-diol 

3-Chloro-l,2-propanediol (Glycerol-a-chlorohydrin) 

1 ,10-Decanediol 

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol) 

♦Ethylene glycol 

2-Ethyl-l ,3-hexanediol- 

2-Ethyl-2-(hydroxymethyl)-l,3-Dronanediol (Tri- 
methylolpropane) . 

♦Glycerol , synthetic 

1,6-Hexanediol 

2-(Hydroxymethyl)-2-methyl-l ,3-propanediol (Tri- 
methylolethane) . 

•lanni t ol 

3-Mercapto- 1,2 -propanediol (Thioglycerol) 

2-Methyl-2,4-pentanediol (Hexylene glycol) 

♦Pentaerythritol 

1,5-Pentanediol 

♦Propylene glycol (1,2-Propanediol) 

♦Sorbitol 

2,2,4-Trimethyl-l,3-pentanediol 

All other 

♦Polyhydric alcohol esters: 

1,3-Butanediol dimethacrylate 

2-(2-Butoxyethoxy)ethyl acetate 

2-Butoxyethyl acetate 

1,3-Butyleneglycol diacetate 

1,3-Diacryloxy-l ,3-dimethylproDane 

Diethylene glycol bisCallyl carbonate), monomer—--.- 



UCC. 

EKX, UCC. 

EKX, UCC. 

SHC. 

ENJ. 

CO, PG, UCC. 

RH, WTH. 

EK, UCC. 

CEL, EKX, UCC. 

GAF. 

CO, PG. 

CO. 

UCC. 

CO, ENJ, GIV, PG. 

ENJ, SCP. 

CO, PG. 

ASH, DUP. 

CO, PG. 

ENJ, UCC. 

UCC. 

CEL, CO, EKX, ENJ, PUB, TNA. 
ASH, CO, ENJ, PG, SHC, TNA, WTH. 
ALD, CO, PG, TNA. 



DOW. 

CEL. 

GAF, DUP. 

GAF. 

GAF. 

EVN. 

ASH. 

BAs! CAU, CEL, DIX, DOW, EKX, JCC, NWP, OMC, PPG, SHC, 

UCC. 
UCC. 
CEL. 

DOW, FMP, SHC. 

CEL. 

COM. 

ICI. 

EVN. 

CEL, SHC, UCC. 

CEL, COM, HN, HPC, PNA, RCI . 

UCC. 

DOW, JCC, OCC, OMC, UCC. 

BRD, ICI, MRK, PFZ. 

EKX. 

GLY, ICI, PNA. RSA, x. 

SAR. 

EKT, UCC. 

UCC. 

SAR. 

UCC. 

PD. 



SYNTHETIC ORGANIC CHEMICALS, 197" 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER. 1974— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLlC--Continued 

Polyhydcio Alcohols and their Esters 
and Ethers — Continued 

*Polyhydric alcohol esters--Continued 

Methylene glycol chloroformate 

2-Diisonropylaininoethyl methacrylate 

2,2-Diiiiethyl-3-hydroxylpronyl-2' ,2-dimethyl-3' - 
hydroxy propionate. 

2-(2-Ethoxyethoxy)ethyl acetate 

2-Ethoxyethyl acetate 

Ethylene glycol diacetate 

Ethylene glycol dimercaptoacetate 

Ethylene glycol dimethacrylate 

Ethylene glycol hydroxyacetate 

2-Ethyl-2-(hydroxymethyl)-l ,3-propanediol tri- 
methacrylate. 

Glyceryl diacetate (Diacetin) 

Glyceryl monoacetate (Monoacetin) 

Glyceryl monothioglycolate 

Glyceryl triacetate (Triacetin) 

Glycol adipate 

1,6-Hexanediol di aery late 

Hexylene glycol diacetate 

Hydr oxye thyl acrylate 

HydroxyproDy 1 aery late 

Lanolin alcohol acetate 

2-^!ethoxyethyl acetate 

2-Methoxyethyl carbamate 

Neopentyl glycol diacrylate 

Pentaerythritol stearate 

Pentaerythritol tetraacrylate 

Pentaerythritol tetrakis (3-mercaptopropionate) 

Polyethylene glycol dimethacrylate 

Polymercaptopolyesters 

Sucrose oct a- acetate 

2-Sulfoethyl methacrylate 

Tetraethylene glycol diacrylate 

Tetraethylene glycol dimethacrylate 

Triethylene glycol diacetate 

Triethylene glycol diacrylate 

Triethylene glycol dimethacrylate 

2,2,4-Trimethyl-l ,3-pentanediol monoisobutyrate 

Trimethylolpropane tri aery late 

Trimethylolpropane tri- (3-mercaptopropionate) 

Trimethylpropane trimethacrylate 

All other 

*Polyhydric alcohol ethers: 

Allyloxy polyethylene glycol 

Bis(2-butoxyethyl) ether (Diethylene glycol di-n- 

butyl ether) . 
Bis(2-ethoxyethyl) ether (niethylene glycol diethyl 

ether) . 

Bis (hydro xye thyl) ether butynediol 

Bis[2-(2-methoxyethoxy)ethyl] ether (Tetraethylene 

glycol dimethyl ether) . 
Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl 

ether) . 

*2-Butoxyethanol (Ethylene glycol monobutyl ether) 

*2- (2-Butoxyethoxy)ethanol (Diethylene glycol monoiso- 

butyl ether) . 
2- [2- (2-Butoxyethoxy)ethoxy]ethanol (Triethylene 

glycol monobutyl ether) . 

1 - Butoxye thoxy- 2 -propano 1 

Butoxypropanol 

N-Eutoxypropanol polyalkylene glycol 

Diethoxytetraglycol 



PD, PPG. 

DUP. 

UCC. 

EKT, UCC. 

UCC. 

EKT, UCC. 

EVN. 

SAR. 

CCA. 

SAR. 

ARC, HAL. 

ARC, HAL. 
EVN. 

EKT, UCC. 

X. 

SAR. 
UCC. 
DOW. 
DOW. 
TCH. 
UCC. 
VAL. 
SAR. 
GLY. 
SAR. 
EVN. 
SAR. 
CCW. 

HPT, PD. 
DOW. 

AAE, SAR. 
SAR. 
UCC. 
AAE. 
SAR. 
EKX. 

AAE, SAR. 
EVN. 
SAR. 

ALD, EK, EVN, PG, PLB, PVO, RH, SAR, SBC, SHC, TXT, UCC, 
USB. 



UCC. 
UCC. 



GAP. 
ASL. 



CEL, DOW, EKX, JCC, OUC, SHC, UCC. 
DOW, EKX, JCC, CMC, SHC, UCC. 

DOW, OMC, UCC. 

UCC. 
UCC. 
UCC. 
UCC. 



ISCELLANEOUS CHEfllCALS 



TABLE 2. --Miscellaneous chemicals for which U.S, production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--CoNTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Polyhydrio Alcohols and Their Esters 
and Ethers — Continued 

*Polyhydric alcohol ethers --Continued 
*Di ethylene glycol 

Diethylene glycol, borated 

Diethylene glycol raonobutyl ether 

Dimethoxyethane (Ethylene glycol dimethyl ether) 

*nipropylene glycol 

Di -tributy let here thy lene glycol 

*2-Ethoxyethanol (Ethylene glycol raonoethyl ether) — 

*2- (2-Ethoxyethoxy)ethanol (Diethylene glycol mono- 
ethyl ether) 

*2-[2- (2-Ethoxyethoxy)ethoxy]ethanol (Triethylene 
glycol monoethyl ether) . 

Ethylene glycol monoisobutyl ether 

Glycerol tri (polyoxypropylene) ether 

2- (Hexyloxy)ethanol 

2- [2- (Hexyloxy)ethoxy] ethane 1 

2- 1 sobut oxye th ano 1 

l-Isobutoxy-2-propanol (Propylene glycol isobutyl 
ether) . 

*2-Methoxyethanol (Ethylene glycol monoraethyl ether) - 

*2- (2-Methoxyethoxy)ethanol (Diethylene glycol mono- 
methyl ether) . 

*2-[2- (2-^1ethoxyethoxy)ethoxy]ethanol (Triethylene 

glycol monomethyl ether) . 
2- (2-Methoxyethoxy)ethyl-2-methoxyethyl ether (Tri 
ethylene glycol dimethyl ether) . 

Methoxypolyethylene glycol 

l-Methoxy-2-propanol 

3- (3-Methoxypropoxy)propanol 

3- [3- (3-Methoxypropoxy)prDDOxy]propanol 

Polye thoxye thy 1 sorbitol 

Polyethoxypolypropoxy but ano 1 

Po 1 yp ropoxybuty 1 ether 

•Polyethylene glycol 

Polyoxypropylene polyoxyethylene glycol, mixed 

* Polypropylene glycol 

Polypropylene glycol raonobutyl ether 

Polytetramethylene ether glycol 

Propoxypropano 1 

*Tetrae thy lene glycol 

1,1,3,3-Tetramethoxypropane 

2,2'-Thiodiethanol (Thiodiglycol) 

*Triethylene glycol-- 

Tripropylene glycol 

All other 

Esters of Monohydric Alcohols 

Allyl methacrylate 

Amyl acetates, 90%: 

Isopentyl acetate (Isoamyl acetate) 

n-Pentyl acetate 

Butyl acetates ; 

I so 

*Norma 1 

Secondary 

*Butyl aery late 

Butyl chloroacetate 



BAS, CEL, DIX, DOW, EKX, JCC , NWP, CMC, PPG, SHC, 

UCC. 
GLY. 
CMC. 
ASL. 

DOK, JCC, OCC, CMC, UCC. 
EKX. 

CHL, DOW, EKX, JCC, CMC. SHC, UCC. 
DOW, EKX, JCC, OMC, SHC, UCC. 

DOW, OMC, UCC. 

EKX. 

BAS, UCC. 

UCC. 

UCC. 

UCC. 

DOW. 

DOW, EKX, JCC, OMC, PPG, SHC, UCC. 
DOW, EKX, JCC, OMC, PPG, SHC, UCC. 

DOW. OMC, UCC. 

ASL. 

UCC. 

DOW, UCC. 

DOW, UCC. 

DOW. 

UCC. 

JCC. 

DA, JCC. 

BAS, DA, DOW, DUP, GAP, HDG, JCC, OMC, TCH, UCC. 

JCC. 

BAS, DOW, JCC, HDG, NLC, OMC, UCC. 

UCC. 

DUP, QKO. 

UCC. 

DOW, EKX, OMC, UCC. 

KF. 

UCC. 

CEL, DIX, DOW, EKX, JCC, OMC, PPG, SHC, UCC. 

DOW. HDG, UCC. 

ALD, CAU. DOW. EKX, GAF . GLY. ICl. JCC, NLC, SAR, x. 



UCC. 






PFW, 


PUB. 




EKX, 


EN J, 


UCC. 


CEL. 


CPS 


EKT. 


EK, 


EKT, 


ENJ. 


CEL 


DBC 


RH. 


"ON. 







PUB. SHC. UCC. 



SYNTHETIC ORGANIC CHEMICALS. W^ 



TABLE 2.— Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197'-|--CONTI NUED 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Esters of Monohydria Alcohols— Continued 

Butyl formate 

Butyl lactate 

Butyl maleate, mono- 

Butyl methacrylate 

tert- Butyl peroxyacetate 

*tert- Butyl peroxy-2-ethyIhexanoate 

tert- Butyl peroxyisobutyrate 

tert - Buty I neroxy i sopropy 1 c arbonate 

tert -Butyl peroxyneodecanoate 

*tert- Butyl peroxypivalate 

tert-Butyl peroxy-3, 3,5-trimethyl cyclohexane 

Cetyl lactate 

Diallyl maleate 

Di (sec-butyl) chloro formate 

Dibuty I f umar ate 

*nihutyl maleate 

Di (sec-butyl) peroxydi carbonate 

Dicyclohexyl peroxydi carbonate 

Diethyl sec-butylethylmalonate 

Diethyl see-but ylmalonate 

Diethyl carbonate (Ethyl carbonate) 

Diethyl diethylmalonate (Diethyl malonic ester) 

Diethyl (ethoxymethylene)malonate 

Diethyl ethyl (l-methylbutyl)malonate 

Di(2-ethylhexyl) chloroformate 

*Di(2-ethyl-l-hexyl) maleate 

Di (2-ethyl-l-hexyl) peroxydicarbonate 

Diethyl maleate 

Diethyl malonate (Malonic ester) 

Diethyl (l-methylbutyl)malonate 

Diethyl oxalate (Ethyl oxalate) 

Diisobutyl maleate 

Diisodecyl maleate 

Diisononyl maleate 

Diisopropyl peroxydicarbonate (Isopropyl percarbonate)- 
Dilauryl maleate 

*Dilauryl 3,3' -thiodipropionate 

Dimethyl carbonate 

2 ,5-Dimethylhexane-2 ,S-diperoctoate 

Dimethyl maleate 

Dimethyl malonate 

Di -(4-me thy 1 -2 -pentyl) maleate 

Dimyristyl 3, 3 '-thiodipropionate 

*Dioctyl maleate 

Di-n-propyl peroxydicarbonate 

*Distearyl 3,3' -thiodipropionate 

Dithiobis(stearyl propionate) 

Ditridecyl maleate 

Di(tridecyl) 3, 3 '-thiodipropionate 

*Ethyl acetate (85%) 

Ethyl acetoacetate 

*Ethyl aery late 

Ethyl-2-bromopropionate 

Ethyl chloroacetate 

Ethyl chloroformate 

Ethyl chlorothiol formate 

Ethylene carbonate 

2-Ethyl-l-hexyl acetate 



Manufacturers' identification codes 
(according to list in table 3) 



CPS. 






COM. 






TCH. 






X. 






AZT, 


IVTL. 




AZT, 


WTC, WTL. 




AZT, 


WTL. 




AZT, 


PPG, WTL. 




WTL. 






AZT, 


IVTC, WTL. 




WTL. 






VND. 






FMP. 






WTL. 






MON, 


RCl, USS. 




HN, 


ION, RCl, USS. 




WTL. 






WTL. 






ABB. 






ABB. 






CTN, 


FMP. 




LIL. 






KF. 






ABB. 






i\rrL. 






CHP, 


DAN, HRT, RUB. 




WTL. 






ACY. 






ABB, 


KF. 




ABB, 


LIL. 




CDY, 


FMP. 




RUB. 






RUB. 






RUB. 






PPG. 






EFH. 






ACY, 


CCW, EVN. 




CTN. 






WTC. 






AAC. 






KF. 






RUB. 






EVN. 






MON, 


RCl, USS. 




IVTL. 






ACY, 


CCW, EVN. 




EVN. 






RUB 






ACY, 


EVN. 




CEL 


EKT, EKX, ENJ, MON, 


PUB, UCC 


EKT 






CEL 


DBC, RH, UCC. 




BAX 






POW 






CTN 


FMP, OTC. 




SFA 






JCC 






EKT 


UCC. 





MISCELLANEOUS CHEMICALS 2 

TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 197^--C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Esters of Monohydrio /5Zeof2ols --Continued 

*2-Ethyl-l-hexyl aery late 

2-Ethyl-l-hexvl methacrylate 

Ethvl sulfate (niethvl sul^'ate") 

Ethyl thioElvcolate 

Fatty acid esters, not included with nlasticizers or 
surface- active agents: 

Butyl na Imitate 

tert-Butvlperoxy neodecanoate 

Butvl stearate 

nimethvl brassy late 

2-Ethvlhexvl oleate 

Ethylhexvl stearate 

Isonronyl ester of lanolin 

Tsopropyl linoleate 

Lanolin acetate 

Methyl esters of coconut oil 

Methyl esters of cottonseed oil 

Methyl esters of tallow 

Methyl 12-hydroxystearate 

Methyl myristate 

Myristyl myristate 

Myristyl stearate 

Propyloleate 

All other 

Clycidyl acrvlate 

niycidyl methacrylate 

Hexyl acetate 

Isoamyl ethylmalonate 

Isohutyl acrvlate 

Isobutvl chloro formate 

Isobutyl isobutyrate 

Isodecvl thioglycolate 

Iso-octyl mercantoacetate 

Tso-octvl-'^-mercantonronionate 

*Isopronvl acetate 

I sonronv 1 ch lorof ormate 

Isostearyl neonentanoate 

Laurvl lactate 

Laurvl methacrylate 

Maleic esters and conolvmers 

Methallylidene diacetate 

*Methyl acetate 

Methyl acetoacetate 

Methyl acrylate, monomer 

Methyl borate 

Methyl chloroacetate 

Methyl chloro formate 

Methyl formate 

•Methyl methacrylate, monomer 

4-Methyl-2-pentyl acetate 

Methyl sulfate (Dimethyl sulfate) 

Methyl vinyl acetate 

Myristyl lactate 

'Phosphorus acid esters: 

Bis(2-chloroethyl)-2-chloroethylpho5phonate 

Bis(2-ethylhexyl) hydrogen phosphate 

Bis(2-ethvlhexyl) hvdrogen phosphite 

Butvl hydrogen phosphates 

Dibutvl butylnhosnhonate 

Dibutyl hydrogen phosphite 

Didodecvl hvdrogen phosphate 

Diethyl ethylnhosphonate 

riiethvl hydrogen phosphite 

niethyl phosphorochloridothionate 

Dimethvl hvdrogen phosphite 



CEL, DBC, UCC. 



UCC. 

EVN. 



AAF, 

vnc. 

CHP. 
E^"R. 
CHP. 
TCH. 

CRN. 
I'ND . 
CRN. 



BFR. 
CHL, 
HUM, 
HUM, 
VND. 
VNn. 
CHP. 
CPS, 
.AAE. 
.^AE. 
CPS. 
LIL. 
CEL, 
OTC. 
EKX. 
EVN. 
CCW, 
E\'N. 
CEL, 
CTN, 
VNn. 
VNP. 

X. 

GAP. 

RPA. 

EK, 

EKT. 

CEL, 

SFS. 

now . 

CTN, 
CEL, 
ACY, 

sue, 

DUP. 
UCC. 

VND . 



Hlffl, PC. 

NTL. 

PC. 



DA, EVN, HUM, LIL, MRV, ROB, TCH. 



EKT, EN.I, UCC. 
PPC. 



CRD, MON, UCC. 
RH. 



FMP. 
DUP. 

DUP, RH. 
UCC. 



SYNTHETIC ORGANIC CHEMICALS, 197^ 



TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported, 

IDENTIFIED BY MANUFACTURER, 197^I~C0NTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



mSCELLANEnilS CHEHICALS, ACYCLIC--Cont inued 

Esters of Monohydrvo i4Zc?(:>/io^s--Continued 

*Phosphorus acid esters-~Continued 

Dimethyl methylphosphonate 

Dimethyl phosphorochlori doth ion ate 

Dioleyl hydrogen phosphite 

2-Ethylhexyl hydrogen phosphate 

Methyl dihydrogen phosphate 

Iso-octyl hydrogen phosphate 

Oleyl hydrogen phosphate 

Trialkyl phosphites 

Tri Cbut oxye thy 1 ) phosphate 

Tributyl phosphate 

Tributyl phosphite 

Triethyl phosphite 

Tri iso-octyl phosphite 

Triisopronyl phosphite 

Trimethyl phosnh ite 

Tri s ( 2- ch loroe thy 1 ) phosphite 

Tris(2,3-dibromopropyl) phosphate 

All other 

Polvnethacrvlic acid esters 

* Propy 1 acetate 

Propylene carbonate 

Stearyl methacrylate 

Tetraethyl silicate 

1 , 1,3,3-Tetramethyl butylhydroperoxide 

Tetraoctyl orthosilicate 

Titanic acid esters: 

Tetrabutvl titanate 

Tetraisopropyl titanate 

TetrakisC2-ethylhexyl) titanate 

Other 

Triethyl orthoacetate 

Triethyl orthoformate 

Triethyl orthopropionate 

Triisodecyl ortho format e 

Tri me thy 1 or thof orma te 

*Vinyl acetate, monomer 

All other 

Halogenated Hydfoaapbons 

1-Bromobutane (n-Butyl bromide) 

2-Bromobutane (sec-Butyl bromide) 

Bromoch 1 orome th ane 

l-Bromo-3-chloronropane (Trimethvlenechlorobromide) -- 

2-Bromo-2-chloro-l ,1 ,1-trifluoroethane 

Bromoethane (Ethyl bromide) 

l-Bromo-3-methyl-2-butene 

2-Bromopentane (1-Methylbutyl bromide) 

1-Bromoprnpane (n-Propvl bromide) 

Bromotrichloromethane 

Bromotrifluoromethane 

*Carbon tetrachloride 

Carbon tetrachloride crude 

*Chlorinated paraffins: 

Less than 35% chlorine 

*35%-64% chlorine 

65% or more chlorine 

2-Chloro-l,3-butadiene 

1-Chlorobutane (n-Butyl chloride) 



SFA. 
SM. 



SM. 

SM. 

MCB. 

HN. 

FMP. 

SM. 

SFA, SFS, SM. 

SM. 

SM. 

SFA, SFS, SM. 

S^'. 

now, MCH. 

MCH, SM. 

DUP. 

GEL, EKT, UCC. 

JCC. 

X. 

ncc. 

WTL. 
►ION. 

raip. 

DUP. 
DUP. 
DUP. 
EK, KF. 
KF. 
KF. 
KF. 
KF. 
BOR, 
ALD, 
KF 



CEL, DUP, NSC, UCC, USI . 

CPS, CRN, CTN. DAN, DUP, EFH, EK, EKX, EMR, EVN, 
RH, SAR, SBC, TCH, TNI, UCC, USS, VND, WTL. 



DOW. 






MCH. 






ICI. 






DOW, GTL 


MCH. 




SDW. 






ABB. 






EK, SDW. 






MCH. 






DUP. 






ACS, DA, 


DOW, DUP, 


FMB, FRO 


TNA. 






DA, HK. 






CCH, DA, 


DVC, HPC, 


ICI, NEV 


DA, DVC, 


NEV. 




DUP. 






PUB, UCC 







MISCELLANEOUS CHEMICALS 



TABLE 2, 



--Miscellaneous chemicals for which U.S, production or sales were reported, 
identified by manufacturer. 1974--c0ntinued 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Halogenated Hydroaavhons — Continued 

Chloroethane (Ethyl chloride) 

Ch 1 oro form 

2-Chloro-3-hexyne 

Chloromethane (Methyl chloride) 

l-Chloro-3-methyl-3-butene 

2-Chloro-2-iiiethylpropane (tert-Butyl chloride) 

3-Chloro-2-methylpropene (Methallyl chloride) 

3-Chloropropene (Allyl chloride) 

■1 ,2-Dibromoethane (Ethylene dibromide) 

Dibromomethane (Methylene bromide) 

1,4-Dibromopentane 

Dichlorobutadiene 

1 ,4-Dichlorobutene 

'1,2-Dichloroethane (Ethylene dichloride) 

'Dichloromethane (Methylene chloride) 

>l,2-Dichloropropane (Propylene dichloride) 

2,3-Dichloropropene 

Diiodomethane (Methylene iodide) 

'Fluorinated hydrocarbons: 

1-Chloro-l ,1-difluoroe thane 

*Ch lorodi fluorome thane 

Chlorodifluoromethane and chloropentaf luoroethane , 
mixture . 

Chloropentaf luoroethane 

Chlorotrifluoroethylene (Trifluorovinyl chloride) -- 

Chlorotrifluoromethane 

1 ,2-nibromo-l ,1,2 ,2-tetraf luroethane 

*Di chlorodifluoromethane 

nichlorodifluoromethane and 1,1-dif luoroethane, 
mixture. 

Dichlorotetraf luoroethane 

1 , 1-Dif luoroethane 

Difluorotetrachloroethane 

Fluoronated ethylene propylene 

Hexafluoro- 2 -propane 

Hexaf luoropropy 1 ene , monomer 

1-Iodoperf luorohexane 

Octaf luorocyclobutane 

Terfluoroakyl iodides 

*Tetrafluoroethylene , monomer 

Tetra fluorome thane 

*Trichl oro fluorome thane 

Trichlorotrif luoroethane 

Vinyl fluoride 

Vinyl idene fluoride 

lodoethane (Ethyl iodide), tech 

lodomethane (Methyl iodide) 

n-Octyl bromide 

1,1,2,2-Tetrabromoethane (Acetylene tetrabromide) --- 

*Tetrachloroethylene (Perchloroethylene) 

*1,1,1-Tri chloroethane (Methyl chloroform) 

1,1,2-Trichloroethane (Vinyl trichloride) 

*Trichloroethylene 

1,2,3-Trichloropropane 

1 , 2 , 3-Tri ch 1 oropronene 

Vinyl bromide (Bromoethylene) 

*Vinyl chloride, monomer (Chloroethylene) 

Vinylidene chloride, monomer (1,1-Dichloroethylene)- 
All other 



DOW, DUP, HPC, PPG, SHC, TNA. 
ALD, DA, DOW, DUP, FRO, SFI. 



DCC, DOW, DUP, FRO, TNA, UCC. 



MCH, PPC, TNA. 



AMH, 

ACS, 

LIL. 

ACS, CO, 

RDA. 

EK. 

FMP. 

DOW, SHC 

DOW, GTL 

DOW. 

PD. 

DUP. 

DUP, PTT. 

kCS, AflE, B.AS, BEG 

TNA, UCC. 
ACS, DA, DOW, DUP, FRO, SFI. 
BAS, DOW, JCC, OMC, UCC. 
DOW. 
ALD, NTB, SDW. 



DA, DOW, FRO, PPG, SHC, 



nup, 


PAS. 












ACS, 


DUP, 


KAI, 


PAS, 


RCN 


UCC 




UCC. 














DUP. 














ACS, 


MMM. 












DUP. 














DUP. 














ACS, 


DUP, 


KAI, 


PAS, 


RCN 


UCC 




UCC. 














ACS, 


DUP, 


PAS, 


UCC 








ACS, 


DUP. 












DUP. 














DUP. 














DUP. 














DUP, 


PAS. 












DUP. 














DUP. 














TKL. 














ACS, 


DUP, 


ICI 


TKL 








DUP. 














ACS, 


DUP, 


KAI 


PAS 


RCN 


, UCC 




ACS, 


UCC, 


X. 










DUP. 














DUP, 


PAS. 












FMT, 


RSA 












FMT, 


RSA 












MCH. 














DOW 














DA, 


DOW, 


FRO, 


HK, 


3PG, 


SFI, 


TNA. 


DOW, 


FRO 


ppn 


TNA 








DOW 














DA, 


DOW, 


HK, 


3PG, TNA. 






DOW 


SHC 












DOW 














DOW 


TNA 












ACS 


AME 


BFG 


CO, 


DOW, 


GP, 


HN, MNO, PPG, SHC, TNA, USR 


DOW 


FRO 












ALD 


EK, 


GAF, 


H»ri', 


NTB, 


RSA. 





SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 2. --Miscellaneous chemicals for which U.S. production or sales were reported^ 

IDENTIFIED BY MANUFACTURER. I97i)--C0NTI NUED 



Manufacturers ' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 
All Other Miscellaneous Acyclia Chemicals 

Acetyl peroxide 

Aluminum isopropoxide (Aluminum isopropylate) 

* 2- But anone peroxi de 

tert- Butyl hydroperoxide 

*tert-ButyI peroxide (Di-tert-butyl peroxide) 

But yrolac tone 

2-Butyrolactone 

Cap ro lac tone 

*C arbon disulfide 

2-Chloroethanol (Ethylene chlorohydrin) 

Decanoyl peroxide 

Dextran 

Di aldehyde starch 

2 , 3- nib romop ropano 1 

2,5-nimethyl-2 ,5-bis(2-ethyl-l-hexanoylperoxy)hexane — 

2,5-Dimethyl-2 ,5-Ms (tert-butylperoxy)hexane 

2,5-Dimethyl-2,S-di (tert-butylperoxy)hexyne-3 

Ditertiary nonyl polysulfide 

♦Epoxides, ethers, and acetals: 

Acetone dimethylacetal (2,2-Dimethoxypropane) 

1- (Allyloxy)-2,3-epoxypTopane (Allyl glycidyl ether)- 

Allyloxymethoxytri glycol 

Bis(2-chloroethoxy)methane (Dichloroethylformal) 

Bis(2-chloro-l-methylethyl) ether (Dichloroisopropyl 
ether) . 

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether) 

Butylene oxide 

Butyl ether (Di-n-butyl ether) 

Butyl vinyl ether 

2-ChloroethyI vinyl ether 

Chloromethyl methyl ether 

2,2-Dichloro-I ,1-difluoroethyl methyl ether 

1,2,7 ,8-Diepoxyoctane 

Dimercaptodiethyl ether 

Dimethyl chloroacetal 

Ep i ch 1 orohy dr i n 

1,2- Epoxyhexadecane 

1,2-Epoxytetradecane / 1,2-Epoxyhexadecane, mixture-- 
*Ethylene oxide 

Ethyl ether: 

Absolute 

*Tech 

II.S.P 

Ethyl vinyl ether 

Glycidol (2,3-Epoxy-l-propanol) 

Isobutyl vinyl ether 

* I sopr opy 1 ether 

Methyl al 

Methyl ether (Dimethyl ether) 

Methyl vinyl ether 

Octadecyl vinyl ether 

Polyacrylated linseed oil epoxide 

♦Propylene oxide 

Triglycol dichloride 

Other 

Epoxy curing agents 

Ethane thiol 

2- (Ethylmercapto)ethanol 

Ethylphosphorous thiodi chloride 



CAD, NOC, RCr, WTC, WTL. 
CAD, OCC, WTC, WTL. 
CAD, SHC, WTC, WTL. 



FMB, PAS, PPG, SFI. 
WTL. 



WTL. 
CHT, 
AZT, 
AZT, 
AZT, 
GAP. 
GAP. 
UCC. 
ACS, 
UCC. 
WTC, 
PHR. 
MLS . 
GTL, 
WTL. 
WTL. 
WTL. 
PAS. 



DOW. 
ACC. 
ARA. 
TKL. 
DOW, JCC. 

DOW. 
DOW. 
PUB. 
GAP. 
ACC. 
RH. 
DOW. 
ALD. 

EVN, USR. 
LIL, UCC. 
DOW, SHC, X. 
UCC. 
UCC. 

BAS, CAO, CEL, DOW, EKX, JCC, NWP, OMC, PPG, SHC, SNO, 
UCC 



MAL, 

EKX, 

MAL, 

GAP. 

DIX. 

GAF. 

ENJ, 

CEL. 

DUP. 

GAF. 

GAF. 

UCC. 

BAS, 

RH. 

ALD, 

SHC. 

EK. 

PLC. 

TNA. 



USI. 

ENJ, HPC, USI. 

OMS, USI. 



SHC, UCC. 



DOW, JCC, OCC, OMC. 
EK, GAF, X. 



MISCELLANEOUS CHEMICALS 2 

TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974— CONTINUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

Alt Othev Miscettanesous Acyclic ChemicaZs--Continued 

Fats and oils, chemically modified 

FattV acids, hydrogenated 

Fatty acids, non-hydrogenated 

niucono- delta- lac tone 

Glutaraldehyde hisCsodium bisulfite) 

n- Hexadecy 1 disulfide 

Hydrocarbons: 

n-Decane 

n-r>odecane 

l-Podecene 

n-Eicosane 

Hexadecane 

n-Hexane 

Myrc ene 

n-Nonane 

n- Oc tadecane 

n- Octane 

l(and 2) -Oct ene 

Terpine hydrocarbons 

Other 

Hydrogenated tallow glycerides 

Hydroxypropy 1 methacrylate 

2-Mercaptoethanol 

Methyl sulfide (Dimethyl sulfide) 

Methyl sulfoxide 

Organo- aluminum compounds: 

Diethyl aluminum chloride 

Diethyl aluminum ethoxide 

Diethyl aluminum iodide 

Diisobutyl aluminum chloride 

Ethyl aluminum chlorides 

Ethyl aluminum sesqui chloride 

I sopropenyl aluminum 

Methyl aluminum sesqui chloride 

Sodium aluminum chlorohydroxvlactate complex 

Sodium aluminum hydroxylactate comnlex 

Trie thvl aluminum 

Triisobutvl a lumi num 

Organo-boron comnounds : 

Boron fluoride - ethyl ether comnlex 

1,3-Butylene glvcol diborate / hexvlene glycol boric 
anhydride. 

Hexvlene glycol boric anhydride 

Trie thy Iborane 

Trimethyl borate 

Other 

Organo- lead comnounds: 

Mixed lead alkyds 

*Tetraethyllead 

Tetrame thy Head 

Tetra (methyl -ethyl) lead 

Organo- lithium compounds: 

n-Butyllithium 

sec- Butyl lithium 

Organo- magnesium halides 

•Organo- silicon compounds: 

Aminopronyltriethoxysilane 

Chloroprooyltrimethoxysilane 

a- Ch 1 orop rony Itrichlorsilane 

Chlorot rime thy Is i lane 

Dichlorodimethylsilane 

Dichloronethylsilane 



DOM, 


SDW. 


CLY. 




GLY. 




PFZ. 




EK, 


FMT. 


PAS. 




HMY, 


PLC. 


HMY, 


PLC. 


WH. 




H"Y. 




HMY. 




HMY. 




IFF, 


GLD, NCI. 


HMY, 


PLC. 


HMY. 




H»»Y, 


PLC. 


HMY, 


PLC. 


CBY. 




HMY, 


PLC. 


CHL, 


GLY. 


CPV. 




TCH. 




CRZ. 




ALD, 


CRZ. 


TNA, 


TSA. 


TSA. 




TSA. 




TNA, 


TSA. 


TNA, 


TSA. 


TNA, 


TSA. 


TSA. 




TNA. 




REH. 




REH. 




TNA, 


TSA. 


TNA, 


TSA. 


ACS. 




USB. 




USB. 




TSA. 




^1H1. 




HSH. 




TNA 




DlIP, 


PPG, TNA. 


DUP, 


NLC, PPG, TNA 


DUP 


PPG. 


FTE 




FTE 




ARA 




UCC 




UCC 




UCC 




DCC 


UCC. 


DCC 


UCC. 


DCC 


UCC. 



SYNTHETIC ORGANIC CHEfllCALS. 197'( 



TABLE 2, --Miscellaneous chemicals for which U.S. production or sales were reported. 

IDENTIFIED BY MANUFACTURER. 1974--CoNTI NUED 



Manufacturers' identification codes 
(according to list in table 3) 



MISCELLANEOUS CHEMICALS, ACYCLIC--Continued 

All Other Miscellaneous Aayalia Chemicals — Continued 

Organo- silicon compounds --Continued 

Silicone greases 

Ethyl silicate 

^lercantooronyltrinethoxysilane 

a-Methacrvloxvnropyltrimethoxy silane 

Methyltriethoxvsilane 

Polyoxyalkylenes silicone 

•Silicone fluids 

Trichloromethylsilane 

Trichlorovinylsilane 

Vinyl (tris-2-methoxyethoxy)silane 

Other organo-silicon compounds 

Organo-tin compounds: 

Bis-mercaptolauric acid, dibutyltin salt 

Bis(tributyltin) oxide 

Dibutyltin bis (isooctyl maleate) 

Dibutyltin bis (isooctylthioglycolate) 

Dibutyltin bis (isopropylmaleate) 

Dibutyltin bis (laurylmaleate) 

Dibutyltin bis (mercaptopropionate polyrner) 

Dibutyltin bis (stearylmaleate) 

Dibutyltin di acetate 

Dibutyltin di chloride 

Dibutyltin dilaurate 

Dibutyltin maleate 

Dibutyltin methoxide 

Pihutvltin oxide 

Dibutyltin sulfide-- 

Organo-tin mercantide 

Tributyltin chloride 

Tributyltin fluoride 

Other 

Organo- zinc compounds 

Oxidized hydrocarbon mixtures 

Perchlorothiomethane (Perchloromethyl mercaptan] 

*Phosgene (Carbonyl chloride) 

Pine oil, synthetic 

Propanone peroxide 

$-Propiolactone 

Rare sugars 

Sodium ethoxide 

Sodium formaldehyde bisulfite 

Sodium formaldehyde sulfoxylate 

Sodium glutaraldehyde bis bisulfite 

*Sodium methoxide (Sodium methylate) 

Sodium succinaldehyde bisulfite 

Succinyl peroxide 

Tetraki s (hydroxymethy 1 ) phosnhonium ch 1 ori de 

Other 



DCC. SPD, SWS. 

SFS. 

UCC. 

UCC. 

UCC. 

UCC. 

DCC, ORO, SPD, SWS, UCC. 

DCC. 
UCC. 
UCC. 
ALD, PLC, UCC. 



ccw, 


X. 






ccw. 


X. 






CCA 


X. 






CCA 


X. 






CCA 








X. 








CCA 








CCW 








PCW, 


X. 






X. 








CCA 


X. 






ISA 








ALX 








SFC 








ACS, 


CTN 


DUP 


MOB 


CBY, 


GLD 


NCI 




UCC 


X. 






CEL 








PFN 


RSA 






FMP 








EK, 


WAY. 






DA, 


RH. 






WAY 








DA, 


HSH, 


OMC, 


RBC. 



one, OTC, PPG, RUC, UPJ. UCC. 



ALD, ALX, BAX, CCW, CDY, CEL, DUP, EK, EKX, FER, FRS, 
GWU my, HSH, ICI, KCH, LIL, MON, PD, PIC, PLC, RSA, 
SAR, SFS, SM, TNA, ISA, USO, WAY, x. 



MISCELLANEOUS CHEMICALS 
TABLE 3, --Miscellaneous chemicals; Directory of hanufacturers, 1974 



ALPHABETICAL DIRECTORY BY CODE 



[Names of miscellaneous chemical manufacturers that reported production or sales to the U.S. International Trade 
Commission for 1974 are listed below in the order of their identification codes as used in table 21 



Code 


Name of company 


Code 


Name of company 


AAC 


Alcolac Chemical Corp. 


CHN 


Cherokee Nitrogen Co. 


AAE 


American Aniline & Extract Co., Inc. 


CHP 


C. H. Patrick 5 Co., Inc. 


ABB 


Abbott Laboratories 


CHT 


Chattem Drug 6 Chemical Co., Chattem 


ABC 


Balchem Corp. 




Chemicals Div. 




Allied Chemical Corp. : 


CLK 


Clark Chemical Corp. 


ACM 


Union Texas Petroleum Div. , 


CLN 


Standard Brands, Inc., Clinton Corp. 




Agricultural Dept. 




Processing Co. Div. 


ACS 


Specialty Chemicals Div. 


CNC 


Columbia Nitrogen Corp. 


ACY 


American Cyanamid Co. 


CNP 


Nipro Inc. 


AGY 


Agway, Inc., Olean Nitrogen Complex 


cn 


Continental Oil Co. 


AIP 


Air Products 5 Chemicals, Inc. 


COL 


Collier Carbon 6 Chemical Corp. 


akl 


Gardinier Big River, Inc. 


COM 


Commercial Solvents Corp. 


AKS 


Arkansas Co., Inc. 


CP 


Colgate-Palmolive Co. 


ALB 


•Ames Laboratories, Inc. 


CPS 


Chemical 5 Pollution Sciences, Inc. 


ALC 


Alco Chemical Corp. 


CPV 


Cook Paint 5 Varnish Co., Inc. 


ALD 


Aldrich Chemical Co., Inc. 


CRN 


CPC International, Inc. 


ALF 


Allied Chemical Corp., Fibers Div. 


CRT 


Crest Chemical Corp. 


ALL 


Alliance Chemical, Inc. 


CPZ 


Crown Zellerbach Corp., Chemical Products 


ALX 


AIox Corp. 




Div. 


AMB 


American Rio-Synthetic Corp. 


CTN 


Chemetron Corp., Chemical Products Div. 


AME 


Stauffer Chemical Co., Polymers West 


cm 


Upjohn Co., Fine Chemical Div. 


APn 


Atlas Powder Co., Subsidiary of Tyler 








Corp. 


DA 


Diamond Shamrock Corp. 


A1A 


Arapahoe Chemicals, Inc. Sub/Syntex 


DAN 


Dan River, Inc. 




Corp. (U.S. A) 


DBC 


Dow Badische Co. 


ARC 


Armak Co. 


DCC 


Dow Corning Corp. 


ARM 


USS Agri-Chemicals Div. of U. S. Steel Corp. 


DEX 


Dexter Chemical Com. 


ARS 


Arsynco, Inc. 


DIX 


Dixie Chemical Co. 


ARZ 


Arizona Chemical Co. 


DLI 


Dawe's Laboratories, Inc. 


ASH 


Ashland oil. Inc., Ashland Chemical Co. Div. 


DDL 


Castle 5 Cooke, Inc., Castle S Cooke 


ASL 


Ansul Chemical Co. 




Foods, Hawaii Region 


ATR 


Atlantic Richfield Co., ARCO Div. 


DOM 


Dominion Products, Inc. 


AV 


FMC Corp. , Fiber Div. 


DOW 


Dow Chemical Co. 


AZT 


Dart Industries, Inc., Catalyst Div. 


DUP 


E. I. DuPont de Nemours 6 Co., Inc. 






DVC 


Dover Chemical Corp. 


BAS 


BASF Wyandotte Corp. 






BAX 


Baxter Laboratories, Inc. 


EFH 


E. F. Houghton 5 Co. 


BFG 


B. F. Goodrich Co., B. F. Goodrich Chemical 


EK 


Eastman Kodak Co. : 




Co. Div. 


EKT 


Tennessee Eastman Co. Div. 


BFR 


Pace National Corp. 


EKX 


Texas Eastman Co. Div. 


BKC 


J. T. Baker Chemical Co. 


ELP 


El Paso Products Co. 


BKL 


Millmaster Onyx Corp., Millmaster Chemical 


EMR 


Emery Industries, Inc. 




Co. Div., Berkeley Chemical Dept. 


ENJ 


Exxon Chemical Co. U.S.A. 


BOR 


Borden Co., Borden Chemical Co. Div. 


ESA 


East Shore Chemical Co., Inc. 


BPC 


.'^tauffer Chemical Co., .'Specialty Chemical 
Div., Benzol Products 


FVN 


Evans Chemetics, Inc. 


BRn 


Lonza, Inc. 


FCA 


C. F. Industries, Inc. 


BUK 


Buckeye Cellulose Corp. 


FOC 


Handschy Chemical Co., Farac Oil 5 
Chemical Div. 


CAD 


Noury Chemical Corp. 


FER 


Ferro Corp. : 


CAU 


Calcasieu Chemical Corp. 




Ferro Chemical Div. 


CBD 


Chembond Corp. 




Grant Chemical Div. 


CBY 


Crosby Chemicals, Inc. 


FIN 


Fine Organics , Inc. 


CCA 


Interstab Chemical, Inc. 




FMC Corp. : 


CCH 


Pearsall Chemical Corp. 


FMB 


Industrial Chemical Div. 


CCW 


Cincinnati Milacron Chemicals, Inc. 


FMP 


Industrial Chemical Div. 


CDY 


Chemical Dynamics Corp. 


FMS 


First Mississippi Com. 


CEL 


Cel anese Corp. : 


FMT 


Fairmount Chemical Co., Inc. 




Celanese Chemical Co. 


FRF 


Firestone Tire 5 Rubber Co., Firestone 




Celanese Fibers Co. 




Synthetic Fibers Co. 


CFA 


Cooperative Farm Chemicals Association 


FRO 


Vulcan ^laterials Co., Chemicals Div. 


CGY 


Ciba-Geigy Corp. 


FTE 


Foote Mineral Co. 


CHH 


Charles Hansen's Laboratory, Inc. 


FTX 


CF Industries, Inc., Fremont Nitrogen 


CHL 


Chemol, Inc. 




Complex 



SYNTHETIC ORGANIC CHEMICALS, 197^1 
TABLE 3, --Miscellaneous chemicals; Directory of manufacturers, 197^^— Continued 



Code 


\ame of coFicany 


Code 


Name of company 


GAF 


GAF Co]-p., Chemical Div. 


MNR 


Monroe Chemical Co. 


CAN 


Gane's Chemical Works, Inc. 


MOB 


Mobay Chemical Co. 


GCC 


W. R. Grace 5 Co., Agricultural Chem. Group 


MON 


Monsanto Co. 


GFS 


G. Frederick Smith Chemical Co. 


MOR 


Marathon Morco, Co. 


GIV 


Givaudan Corp. 


MRK 


>'erck f, Co., Inc. 


GLD 


SCM Corp. Glidden-Durkee Div. 


flPT 


Morton Chemical Co., Div. of Morton- 


GLY 


Glyco Chemicals, Inc. 




Nonvich Products, Inc. 


GLX 


Gl as flex Corn. 


MRV 


"arlowe-Van Loan Corp. 


GW. 


General Mills Chemicals, Inc. 


MSC 


Mississippi Chemical Corn. 


Gnc 


Gulf nil Corp., Gulf Oil Chemicals Co. -U.S. 


mto 


Montrose Chemical Corp. of California 


GP 


Georgia-Pacific Corp. and Rebecca Plant 






GRD 


1". R. Grace 5 Co., Polymers 5 Chemicals niv. 


NCI 


Union Camn Corp., Chemical Div. 


GRH 


"'. R. Grace f, Co., Hatco Chemical Div. 


NFP 


Nepera Chemical Co. 


GTL 


Great Lakes Chemical Corp. 


NFS 


Nease Chemical Co., Inc. 


GYP. 


Goodyear Tire 6 Rubber Co. 


NEV 


Neville Chemical Co. 






NLC 


Nalco Chemical Co. 


HAL 


C.P. Hall Co. of Illinois 


NOC 


Norac Co., Inc. and Mathe Chemical Co. Div 


HDG 


Hodag Chemical Com. 


NOR 


Norwich Pharmacal Co. 


HEX 


Hexagon Laboratories, Inc. 


NPI 


Stephan Chemical Co., Polychem Dept. 


HFT 


S.NTitex Agribusiness, Inc., Nutrition S 


NSC 


National Starch 5 Chemical Corp. 




Chemical Div. 


NTB 


National Biochemical Co. 


HK 


Hooker Chemicals S Plastic Corp. : 


ntl 


NL Industries, Inc. 


HKP 


Durei Div. 


NWP 


Northern Petrochemicals Co. 


HKY 


Hawkeye Chemical Co. 






mp 


K. R. Grace 5 Co., Dewey § Almy Chemical 


OCC 


Oxirane Chemical Co. 




Div. , Organic Chemical 


OH 


Airco, Inc., Ohio Medical Products Div. 


HMY 


Humphrey Chemical Co. 


OMC 


Olin Corp. 


HN 


Tenneco Chemicals, Inc. 


0»'S 


E. R. Squibb 6 Sons, Inc. 


HPC 


Hercules, Inc. 


ONX 


Millmaster Onyx Corp., Onyx Chemical Co. 


HRT 


Hart Products Corp. 


OPC 


Orbis Products Corp. 


HSH 


Harshaw Chemical Co. Div. of Kewanee Oil 


opn 


Chevron Chemical Co. 




Co. 


OPT 


Roehr Chemicals, Inc. 


HST 


American Hoechst Coi-p. 


OTC 


Story Chemical Corn. 


HUM 


Kraftco Corp., Humko Products Chemical Div. 


nxc 


Oxochem Enterprises 


ICI 


ICI Hnited States, Inc., Snecialty Chemical 


PAR 


Pennzoil Co., Penneco Div. 




Group 


PAS 


Pennwalt Corp. 


IFF 


International Flavors f, Fragrances, Inc. 


PCW 


Pfister Chemical Works 


IOC 


lonac Chemical Co. Div. of Sybron Corp. 


PD 


Parke, Davis f, Co. 






PEN 


CPC International, Inc., S. B. Penick Div. 


JfC 


Jefferson Chemical Co., Inc. 


PEN 


Pfanstiehl Laboratories, Inc. 


jnc 


N'ioak, Inc. 


PFi" 


Polak's Frutal Works, Inc. 


.TFR 


George A. Jeffrey's S Co., Inc. 


PFZ 


Pfizer, Inc. 


JOR 


Jordan Chemical Co. 


PC 


Procter 5 Gamble Co. 






PHR 


Pharmachem Com. 


KAI 


Kaiser Aluminum f, Chemical Corp. , Kaiser 


PIC 


Pierce Chemical, Inc. 




Chemicals Div. 


PLB 


P-L Biochemicals, Inc. 


KCC 


Kennecott Copper Corp., Chino "ines Div. 


PLC 


Phillips Petroleum Co. 


KCH 


Joseph Ayers, Inc. 


PLS 


Plastics Engineering Co. 


KCU 


Kennecott Copper Corp. , Utah Copper Div. 


PMP 


Premier Malt Products, Inc. 


KF 


Kay-Fries Chemicals, Inc. 


PNA 


Pan .American Chemical Corp. 


KON 


H. Kohnstamm fi Co., Inc. 


PPC 


Premier Petrochemical Co. 


KPT 


Koppers Co., Inc., Organic Materials Div. 


PPG 


Pittsburgh Plate Glass Co. 






PRD 


Productol Chemical Co., Inc. 


LAK 


Lakeway Chemical, Inc. 


ptt 


Petro-Tex Chemical 


LAIl 


LaMotte Chemical Products Co. 


PUB 


Publicker Industries, Inc. 


LEU 


Mapp Chemicals, Inc. 


PVO 


PVO International, Inc. 


lil 


Eli Lilly 5 Co., Inc. 






LUB 


Lubrizol Corp. 


QCP 


Quaker Chemical Corp. 






QKO 


Quaker Oats Co. 


?ial 


Mallinckrodt Chemical Works 






MCB 


Borg-Warner Corp., Borg-Wamer Chemicals Div. 


RBC 


Fike Chemicals, Inc. 


MCH 


"ichigan Chemical Corp. 


RCI 


"eichhold Chemicals, Inc. 


MCI 


Mooney Chemicals, Inc. 


RCN 


Racon, Inc. 


HHI 


Ventron Corp. 


RDA 


Rhodia, Inc. 


ML<; 


'liles Laboratories, Inc., "larschall Div. 


REH 


Reheis Chemical Co. Div. of Armour 




fi Sumner Div. 




Pharmaceutical Co. 


HMM 


Minnesota "ining 5 Manufacturing Co. 


REM 


Remington Arms Co., Inc. 


Hvn 


"onochem. Inc. 


RH 


Rohm 5 Haas Co. 






ROB 


Robeco Chemicals, Inc. 



MISCELLANEOUS CHEniCALS 
TABLE 3.— Miscellaneous chemicals: Directory of manufacturers. 1974— Continued 



Name of company 



Name of company 



RPC 
RSA 
Rim 
RUC 

S 

SAR 

SBC 

SCP 

SDC 

SPH 
SDW 

SPA 

SFC 

SFI 

SFS 

SHA 

SHC 

SHF 

SHP 

SK 

SKG 

SKO 



SNn 
SNW 
SOC 

SOH 
SPD 

STC 
STP 



Millmaster Onyx Corp. , Refined-Onyx Div. 
R.S.A. Corp. 

Hooker Chemical Corp., Ruco Div. 
Rubicon Chemicals, Inc. 

Sandoz, Inc. 

Partomer Industries, Inc. 

Scher Bros . 

Henkel, Inc. 

Martin-Marietta Corp., Sodeyco Div. 

Sterling Drug, Inc. : 

Hilton-Davis Chemical Co. Div. 

Winthrop Laboratories Div. 
Stauffer Chemical Co.: 

.Agricultural Div. 

Calhio Chemicals, Inc. Div. 

Industrial Div. 

Specialty Chemical Div. 
Shanco Plastics 6 Chemicals, Inc. 
Shell Oil Co., Shell Chemical Co. Div. 
Kraftco Corp., Humko Sheffield Div. 
Shepherd Chemical Co. 
Smith, Kline 5 French Laboratories 
Sunkist Growers, Inc. 
Skelly Oil Co. 
Mobil Oil Corp., Mobil Chemical Co., 

Chemical Coatings Div. 
Kaiser Aluminum f, Chemical Corp. , Kaiser 

Agricultural Chemicals Div. 
SunOlin Chemical Co. 
Sun Chemical Corp. , Chemical Div. 
Standard Oil Co. of California, Chevron 

Chemical Co. 
Vistron Corp. 
General Electric Co., Silicone Products 

Dept. 
Sou-Tex Chemical Co., Inc. 
Stepan Chemical Co. 
Sherwin-Williams Co. 
Stauffer Chemical Co., SWS Silicones 

Div. 
Dart Industries, 

Co. Div. 

Chemetron Corp. , 
Div. 



Inc. , Synthetic Products 



Medical Products 



TCC 
TCH 

TER 
TID 
TKL 
TNA 
TNI 
TRI 
TRO 
TSA 



UCC 
UOP 
UPJ 
UPM 
USB 
US I 

U?o 
USR 
USS 

VAL 
VEL 
VGC 
VLN 
WD 

WAG 
WAY 

WBC 

WBG 

WLC 

WM 

WtP 

WTC 

IVTH 

WTL 

WYC 



Tanatex Chemical Corp. 

Emery Industries Inc., Trylon Chemicals 

Div. 
Terra Chemicals International, Inc. 
Getty Oil Co. (Eastern Operations, Inc.) 
Thiokol Chemical Corp. 
Ethyl Corp. 

The Gillette Co., Chemical Div. 
Triad Chemicals 
Troy Chemical Corp. 
Texas Alkyls, Inc. 
Texaco , Inc . 
Textilana Corp. 
Magnesium Elektron, Inc. 

Union Carbide Corp. 

Universal Oil Products Co., UOP Chemical Div. 

Upjohn Co. 

Universal Oil Products Co. 

U.S. Borax Research Corp. 

National Distillers 5 Chemical Corp., U.S. 

Industrial Chemicals Co. Div. 
U.S. Oil Company 
Uniroyal, Inc., Chemical Div. 
USS Chemicals Div. of U.S. Steel Corp. 

Valchem 

Velsicol Chemical Corp., Inc. 
Virginia Chemicals, Inc. 
Valley Nitrogen Producers, Inc. 
Van Dyk 5 Co . , Inc . 

West Agro Chemical, Inc. 

Phillip A. Hunt Chemical Corp. , Wayland 

Chemical Div. 
Worthington Biochemical Corp. 
White § Bagley Co. 
Agrico Chemical Co. 
Index Corp. 

Essex International, Inc. 
Witco Chemical Co., Inc. 
Union Camp Corp., Harchem Div. 
Pennwalt Corp., Lucidal Div. 
Wycon Chemical Co. 

Carolina Processing Corp. 



Note. --Complete names and addresses of the above reporting companies are listed in table I of the appendix. 



APPENDIX 



appe:jdix 

DIRECTORY OF MAriUFACTURERS 



TABLE 1, 



--Synthetic organic chemicals; Alphabetical directory of manufacturers, 
BY company, 197'I 



[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. International Trade 
Commission for 1974 are listed below alphabetically, together with their identification codes as used in table 2 
of the 14 individual sections of this report] 




Office address 



A 5 E Plastic Pak Co., Inc 

AZS Corp . : 

AZ Products Co. Div 

Lancaster Chemcial Co. Div 

Abbott Laboratories 

Abex Corp., Friction Products Group 

Agrico Chemical Co 

Agway, Inc., Olean Nitrogen Div 

Airco, Inc., Ohio Medical Products Div 

Air Products 6 Chemicals, Inc., Chemicals 
Group. 

Alco Chemical Corp. 

Alcolac, Inc 

Aldrich Chemical Co., Inc 

Alliance Chemical Co., Inc 

Allied Chemical Corp. 

Fibers Div 

Specialty Chemicals Div 

Union Texas Petroletmi Div 

Agricultural Dept 

Alox Corp 

Alpha Laboratories, Inc 

Amchem Products, Inc. Div. of Rorer- 
Amchem, Inc. 

Amerace Corp., Penetone Div 

American Aniline S Extract Co., Inc 

American Bio-Synthetics Corp 

American Can Co 

American Color S Chemical Corp 

American Cyanamid Co 

American Hoechst Corp 

American Oil Co. (Texas) 

American Petrofina Co. of Texas 

American Synthetic Rubber Corp 

Ames Laboratories, Inc 

Amoco Chemical Corp 

Amoco Oil Co. (Maryland) 

Amoco Production Co 

Ansul Chemical Co 

Apex Chemical Co., Inc 

Apollo Colors, Inc 

Arapahoe Chemicals, Inc. Sub. Syntex 
Corp. (U.S.A.). 

ARCO/Polymers, Inc 

Ardmore Chemical Co., Inc 

Arenol Chemical Corp 

Arizona Chemical Co 

Arkansas Co., Inc 

Armak Co 

Armour- Dial , Inc 

Armour Pharmaceutical Co 

Armstrong Cork Co 

Arol Chemical Products Co 

Arsynco, Inc 



14505 E. Proctor Ave., Industry, CA 91749. 

2525 So. Combee Rd. , Eaton Park, FL 33840. 

762 Marietta Blvd., Atlanta, GA 30313 

14th St. and Sheridan Rd. , N. Chicago, IL 60064. 

2401 S. Loudoun St., Winchester, VA 22601. 

P. C. Box 3166, Tulsa, OK 74101. 

1446 Buffalo St., Olean, NY 14760. 

3030 Airco Dr., Madison, WI 53701. 

636 E. Swedesford Rd, #5 Executive Mall, 

Wayne, PA 19087. 
Trenton Ave. and William St., Philadelphia, PA 19134. 
3440 Fairfield Rd. , Baltimore, MD 21226. 
940 W. St. Paul Ave., Milwaukee, WI 53233. 
33 Avenue P, Newark, NJ 07105. 
Columbian Rd. , Morristown, NJ 07960. 
1 Times Square, New York, ^JY 10036. 
P. 0. Box 1087-R and P. 0. Box 1219-R, 

Morristown, NJ 07960. 
P. 0. Box 2120, Houston, TX 77001. 
P. 0. Box 2120, Houston, TX 77001. 
3943 Buffalo Ave., Niagara Falls, NY 14303. 
1685 S. Fairfax St., Denver, CO 80222. 
Brookside Ave., and Spring Garden St., Ambler, PA 19002. 

750 Hudson Ave., Tenafly, NJ 07670. 

Venango and F Sts., Philadelphia, PA 19134. 

710 W. National Ave., Milwaukee, WI 53204. 

American Lane, Greenwich, CT 06830. 

P. 0. Box 51, 1729 N. 11th St., Reading, PA 19604. 

Wayne, NJ 07470. 

129 Quidnick St., Coventry, RI 02816. 

200 Randolph Dr., Chicago, IL 60680. 

P. 0. Box 849, Port Arthur, TX 77604. 

P. 0. Box 360, 4500 Camp Ground Rd., 

Louisville, KY 40201. 
200 Rock Lane, Mil ford, CT 06460. 
200 E. Randolph Dr., Chicago, IL 60601. 
200 E. Randolph Dr., Chicago, IL 60680. 
P. 0. Box 591, Tulsa, OK 74102. 
1 Stanton St., Marinette, WI 54143. 
200 S. 1st St., Elizabethport, NJ 07206. 
899 Skokie Blvd., Northbrook, IL 60062. 
2855 Walnut St., Boulder, CO 80302. 

1500 Market St., Philadelphia, PA 19101. 

840 Valley Brook Ave., Lyndhurst, NJ 07071. 

40-33 23d St., Long Island City, NY 11101. 

Wayne, NJ 07470. 

185 Foundry St., Newark, NJ 07101. 

300 S. Wacker Dr., Chicago, IL 60606. 

2000 Oucutt Rd. , Montgomery, IL 60538. 

Ill W Clarendon Ave., Greyhound Tower, Phoenix, AZ 8507' 

Liberty and Charlotte Sts., Lancaster, PA 17604. 

649 Ferry St., Newark, NJ 07105. 

P. 0. Box 8, Carlstadt, NJ 07072. 



SYNIHETIC ORGANIC CHEMICALS, 197^1 



TABLE 1, 



-Synthetic organic chemicals: Alphabetical directory of manufacturers, 
by company. 197^--conti nued 



Name of company 



Office address 



Ashland Oil, Inc 

Ashland Chemical Co. Div 

Astor Products, Inc., Blue Arrow Div 

Astra Pharmaceutical Products, Inc 

Atlantic Chemical Corp 

Atlantic Richfield Co 

Atlas Powder Co. Sub. of Tyler Corp 

Atlas Processing Co 

Joseph Ayers, Inc 

BASF Wyandotte Corp 

BP Oil, Inc 

J. T. Baker Chemical Co 

Bal ch em Corp 

Baltimore Paint 5 Chemical Corp 

Baxter Laboratories, Inc 

Bayoil Co., Inc 

Beecham, Inc 

Belding Chemical Industries 

Belport Co., Inc 

Bendix Corp., Friction Materials Div 

Bennett's 

Benzenoid Organics, Inc 

Bemcolors-Poughkeepsie, Inc 

Biocraft Laboratories, Inc 

Borden, Inc. 

Borden Chemical Div 

Printing Ink Div 

Borg-Wamer Corp., Borg-Wamer Chemicals-- 

Breddo Food Products Corp 

Bristol -Meyers Co., Bristol Laboratories 
Div. 

M. A. Bruder § Sons, Inc 

Buckeye Cellulose Corp 

Buckman Laboratories, Inc 

Burdick ^ Jackson Laboratories, Inc 

Burroughs Wellcome Co 

CF Industries, Inc 

Fremont Nitrogen Complex 

CPC International, Inc 

Acme Resin Co. Div 

S. B. Penick Co 

Samuel Cabot, Inc 

Calcasieu Chemical Corp 

Carborundum Co 

Cargi 11, Inc 

Carolina Processing Corp 

Carus Corp., Carus Chemical Co. Div 

Castle 5 Cooke, Inc., Castle § Cooke 

Foods, Hawaii Region. 
Celanese Corp. : 

Celanese Chemical Co 

Celanese Coatings 5 Specialties Co. and 
Wica Plant 

Celanese Fibers Co 

Celanese Plastics Co 

Certified Processing Corp 

Champlin Petroleum Co 



1401 Winchester Ave., Ashland, KY 41101 and 

P. 0. Box 2458, Columbus, OH 43316. 
5200 Blazer Pkway. , Dublin, OH 43017. 
5244 Edgewood CT. , Jacksonville, FL 32205. 
Neoponset St., Worcester, MA 01606. 
10 Kingsland Rd. , Nutley, NJ 07110. 
515 S. Flower St., Los Angeles, CA 90071. 
P. 0. Box 87, Joplin, MO 64801. 

P. 0. Box 9389, 3546 Midway St., Shreveport , LA 71109. 
Route #2, Bethlehem, PA 18017. 

100 Cherry Hill Rd. , Parsippany, NJ 07054. 

270 Midland Bldg. , Cleveland, OH 44115. 

222 Red School Lane, Phillipsburg NJ 08865. 

Intersections 6 and 284, Slate Hill, NY 10973. 

2325 Hollins Ferry Rd., Baltimore, MD 21230. 

6301 Lincoln Ave., Morton Grove, IL 60053. 

2 Union St., Peabody, MA 01960. 

65 Industrial S., Clifton, NJ 07012. 

1430 Broadway, New York, NY 10018. 

553 Dawson Dr., Camarillo, CA 93010. 

P. 0. Box 238, Troy, NY 12180. 

2131 S. 30th St., Salt Lake City, UT 84115. 

P. 0. Box 157, Bellingham, MA 02019. 

75 N. Water St., Poughkeepsie, NY 12602. 

12 Industrial Way, Waldwick NJ 07463. 

180 E. Broad St., Columbus, OH 43215. 

630 Glendale-Milford Rd. , Cincinnati, OH 45215. 

P. 0. Box 1868, Parkersburg, WV 26101, and 

103 Spring Valley Rd. , Montvale, NJ 07645. 
18th and Kansas Avenue, Kansas City, KS 66105. 
P. 0. Box 657, E. Syracuse, NY 13057. 

52d St. and Grays Ave., Philadelphia, PA 19143. 

2899 Jackson Ave., Memphis, TN 38108. 

1256 N. McLean Blvd., Memphis, TN 38108. 

1953 S. Harvey St., Muskegon, MI 49442. 

3030 Comwallis Rd. , Research Triangle Park, NC 27709. 

P. 0. Box 87, Harrison, TN 37341. 

P. 0. Box 68, RFD #3, Fremont, NB 68025. 

International Plaza, Englewood Cliffs, NJ 07632. 

1401 Circle Avenue, Forest Park, IL 60130. 

1050 Wall St., W., Lyndhurst, NJ 07071. 

One Union St., Boston, MA 02108. 

P. 0. Box 1522, Lake Charles, LA 70601. 

P. 0. Box 477, Niagara Falls, NY 14302. 

Cargill Bldg., Minneapolis, MN 55402. 

P.O. Box 161, Severn, NC 27877. 

1500 8th St., LaSalle, IL 61301. 

650 Iwilei Rd. , Honolulu, HI 96817. 



1211 Avenue of Americas, New York, NY 100 
P. 0. Box 1863, Louisville, KY 40201. 

P. 0. Box 1414, Charlotte, NC 28232. 
550 Broad St., Newark, NJ 07102. 
Route 22 6 Harding Terrace, Hillside, NJ 
P. 0. Box 9176, Corpus Christi, TX 78408. 



APPENDIX 
TABLE 1, --Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY, 1974--CONTINUED 



Name of company 



Office address 



CPP Charmin Paper Products Co 

SOG Charter International Oil Co 

CHT Chattem Drug 5 Chemical Co. , Chattem 

Chemicals Div. 
CBD Chembond Corp 

Chemed Corp. : 

GRC Dubois Chemicals Div 

GRL Vestal Laboratories Div 

Chemetron Corp. : 

CTN Chemical Products Div 

TAE Medical Products Div 

HSC Pigments Div 

CI Chem-Fleur, Inc 

CDY Chemical Dynamics Corp 

CHF Chemical Formulators, Inc 

GPS Chemical 5 Pollution Sciences, Inc 

CKL Chemlek Laboratories, Inc 

CHL Chemol, Inc 

CPX Chemplex Co 

CHN Cherokee Nitrogen Co 

ORO Chevron Chemical Co 

CPC Childs Pulp Colors, Inc 

CHC Choate Chemical Co., Div. of E.R. 
Carpenter. 

CHH CHR. Hansen's Laboratory, Inc 

CGY Ciba-Geigy Corp 

Agricultural Div 

CCW Cincinnati Milacron Chemicals, Inc 

CIN Cindet Chemicals, Inc 

Cities Service Co. : 

CBN Columbian Div. and Plastics Div 

TEN Copperhill Operations 

CSO Cities Service Oil Co 

CBN Petrochem Operations 

CLK Clark Chemical Corp 

CLY W. A. Cleary Corp 

CLI I Clintwood Chemical Co 

CSP I Coastal States Petrochemical Co 

CP I Colgate-Palmolive Co 

COL ' Collier Carbon 5 Chemical Corp 

CLD Colloids, Inc 

CNC Columbia Nitrogen Corp 

CMP ! Commercial Products Co., Inc 

COM j Commercial Solvents Corp 

COR i Commonwealth Oil Refining Co., Inc 

CPI j Commonwealth Petrochemicals, Inc 

CNI I Conap, Inc 

I Conchemco, Inc: 

SED ' Colony Paint Div 

CNE Conchemco Coatings 

CON ' Concord Chemical Co., Inc 

CWP Consolidated Papers, Inc 

CTL Continental Chemical Co 

CO Continental Oil Co 

CPV Cook Paint 5 Varnish Co 

CFA Cooperative Farm Chemicals Association- 

COO Cooper Polymers, Inc 

COP Coopers Creek Chemical Corp 



6000 Center Hill Rd., Cincinnati, OH 4S224. 

P. 0. Box 5008, Houston, TX 77012. 

1715 W. 38th St., Chattanooga, TN 37409. 

P. 0. Box 270, Springfield, OR 97477. 

Dubois Tower, Cincinnati, OH 45202. 

4963 Manchester Ave., St. Louis, MO 63110. 

P. 0. Box 63 White Pine, TN 37890. 

1801 Lilly St., St. Louis, MO 63110. 

491 Columbia Ave., Holland, MI 49423. 

200 Pulaski St., Newark, NJ 07105. 

P. 0. Box 395, 3001 Hadley Rd. , S. Plainfield, NJ 07080. 

P. 0. Box 26, Nitro, WV 25143. 

P. 0. Box 162, Old Bridge, NJ 08857. 

4040 W. 123d St., Alsip, IL 60658. 

P. 0. Box 20687, Greensboro, NC 27420. 

3100 Golf Rd., Rolling Meadows, IL 60008. 

P. 0. Box 429, Pryor, OK 74361. 

200 Bush St., San Francisco, CA 94120. 

5 Albany St., Springfield, MA 01101. 

P. 0. Box 27205, Richmond, VA 23261. 

9015 W. Maple St., West Allis, WI 53214. 

556 Morris Ave., Summit, NJ 07901 and 444 Saw Mill 

River Rd., Ardsley, NY 10S02. 
P. 0. Box 11422, Greensboro, NC 27409. 
West St., Reading, OH 45215. 
2408 Doyle St., Greensboro, NC 27406. 

G. P. 0. Box 300, Tulsa, OK 74102. 

Copperhill, TN 37317. 

P. 0. Box 300, Tulsa, OK 74102. 

P. 0. Box 1522, Lake Charles, LA 70601. 

131st St. 5 Kedzie Ave., Blue Island, IL 60406. 

P. 0. Box 10, Somerset, NJ 08873. 

4342 S. Wolcott Ave. , Chicago, IL 60609. 

P. 0. Drawer S21, Corpus Christi, TX 78403. 

300 Park Ave., New York, NY 10022. 

P. 0. Box 60455, Los Angeles, CA 90017. 

394 Frelinghuysen Ave., Newark, NJ 07114. 

P. 0. Box 1483, Augusta, GA 30903. 

117 Ethel Ave., Hawthorne, NJ 07506. 

245 Park \ve. , New York, NY 10017. 

Petrochemical Complex, Ponce, PR 00731. 

Petrochemical Complex, Ponce, PR 00731. 

1405 Buffalo St., Olean, NY 14760. 

18th f, Garfield Sts., Kansas City, MO 64127. 

P. 0. Box 778, Baltimore, MD 21230. 

17th 5 Federal Sts., Camden, NJ 08105. 

231 1st Ave N., Wisconsin Rapids, WI 54494. 

270 Clifton Blvd., Clifton, NJ 07015. 

Park Eighty Plaza East, Saddle Brook, NJ 07662. 

P. 0. Box 389, Kansas City, MO 64141. 

P. 0. Box 308, Lawrence, KS 66044. 

820 Wobum St., Wilmington, MA 01887. 

River Rd. , W. Conshohocken, PA 19428. 



SYNTHETIC ORGANIC CHEMICALS, 1974 
TABLE 1. --Synthetic organic chemicals; Alphabetical directory of manufacturers, 

BY COMPANY, 1974--CONTI NUED 



Name of company 



Copolymer Rubber S Chemical Corp 

Corco Cyclohexane, Inc 

Cosden Oil 5 Chemical Co 

Crest Chemical Corp 

Croda, Inc 

Crompton 5 Knowles Corp., Dyes 5 Chemical 

Div. 

Crosby Chemicals, Inc 

Crown Central Petroleum Corp 

Crown Metro, Inc 

Crown Zellerbach Corp., Chemical Products 

Div. 
Customs Resins, Inc 



Dan River, Inc 

Dart Industries, Inc.: 

Catalyst Div 

Rexene Polymers Co. Div 

Synthetic Products Co. Div 

Davies- Young Co 

Dawe's Laboratories, Inc 

Day-Glo Color Corp 

Deering Milliken, Inc., Milliken Chemical 
Div. 

Degen Oil § Chemical Co 

Dennis Chemical Co 

DePaul Chemical Co., Inc 

DeSoto, Inc 

Dexter Chemical Corp 

Hysol Div 

Midland Div 

Diamond Shamrock Corp 

Disogrin Industries Corp 

Dixie Chemical Co 

Dixie Pine Products Co., Inc 

Dominion Products, Inc 

Dover Chemical Co 

Dow Badische Chemical Co 

Dow Chemical Co 

Dow Coming Corp 

E. I. duPont de Nemours 5 Co., Inc 

Dye Specialties, Inc 



Eagle Pitcher Industries, Inc., Ohio 

Rubber Co. Div. 

Eagle River Chemical Corp 

Eastern Color 5 Chemical Co 

Eastman Kodak Co 

Tennessee Eastman Co. Div 

Texas Eastman Co. Div 

East Shore Chemical Co., Inc 

Eastside Chemical Laboratory 

Elan Chemical Co 

El Paso Products Co 

Emery Industries, Inc 

Trylon Chemicals Div 

Emkay Chemical Co 

Endo Laboratories, Inc 

Enenco, Inc 

Epoxylite Corp 

Essential Chemicals Group 

Essex International, Inc 

Ethyl Corp 

Evans Chemetics, Inc 



Office address 



P. 0. Box 2S91, Baton Rouge, LA 70821. 
Petrochemicals Complex, Ponce, PR 00731. 
P. 0. Box 1311, Big Spring, TX 79720. 
225 Emmet St., Newark, NJ 07114. 
51 Madison Ave., New York, NY 10010. 
500 Pear St., Reading, PA 19603. 

P. 0. Box 460, Picayune, MS 39466. 
1 N. Charles St., Baltimore, MD 21201. 
P. 0. Box 5695, Greenville, SC 29606. 
Camas, WA 98607. 

P. 0. Box 933, Henderson KY 42420. 

P. 0. Box 261, Danville, VA 24541. 

555 Garden St., Elyria, OH 44035. 

W. 115 Century Rd. , Paramus, NJ 07652. 

1636 Wayside Rd., Cleveland, OH 44112. 

2700 Wagner Place, Maryland Heights, MO 63043. 
450 State St., Chicago Heights, IL 60411. 
4732 St. Clair Ave., Cleveland, OH 44103. 

P. 0. Box 817, Inman, SC 29349. 

200 Kellogg St., Jersey City, NJ 07305. 

2701 Papin St., St. Louis, MO 63103. 

44-27 Purvis St., Long Island City, NY 11101. 

1700 S. Mt. Prospect Ave., Des Plaines, IL 60018. 

845 Edgewater Rd., Bronx, NY 10474. 

211 Franklin St., Olean, NY 14760. 

P. 0. Box 1020, Waukegan, IL 60085. 

1100 Superior Ave., Cleveland, OH 44114. 

Perimeter Rd.-Grenier Field, Manchester, NH 03130. 

3635 W. Dallas Ave., Houston, TX 77019. 

P. 0. Box 470, Hattiesburg, MS 39401. 

882 3d Ave., Brooklyn, NY 11232. 

W. 15th and Davis Sts., Dover, OH 44622. 

602 Copper Rd., Freeport, TX 77541. 

2020 Dow Center, Midland, MI 48640. 

P. 0. Box 1592, Midland, MI 48640. 

DuPont Bldg., Wilmington, DE 19898. 

26 Journal Sq., Jersey City, NJ 07306. 

P. 0. 1398 Denton, TX 76201. 

P. 0. Box 2648, W. Helena, AR 72390. 

35 Livingston St., Providence, RI 02904. 

343 State St., Rochester, NY 14650. 

P. 0. Box 511, Kingsport, TN 37662. 

P. 0. Box 7444, Longview, TX 75601. 

1221 E. Barney Ave., Muskegon, MI 49443. 

12880 NE Be llevue- Redmond Rd. , Bellevue, WA 98005 

268 Doremus Ave., Newark, NJ 07105. 

P. 0. Box 3986, Odessa, TX 79760. 

1300 Carew Tower, Cincinnati, OH 45202. 

P. 0. Box 628, Mauldin, SC 29662. 

319 2d St., Elizabeth, NJ 07206. 

1000 Stewart Ave., Garden City, NY 11530. 

P. 0. Box 398, Memphis, TN 38101. 

1901 Via Burton, Anaheim, CA 92806. 

28391 Essential Rd. , Merton, WI 53056. 

1601 Wall St., Fort Wayne, IN 46804. 

330 S. 4th St., Richmond, VA 23231. 

90 Tokeneke Rd., Darien, CT 06820. 



APPENDIX 
TABLE 1. -Synthetic organic chemicals: Alphabetical directory of manufacturers. 

BY company, IQ/^-'CONTINUED 



Name of company 



Office address 



Exxon Chemical Co. U.S.A. 

FMC Corp . : 

Agricultural Chemical Div 

Fiber Div 

Industrial Chemical Div 

Industrial Chemical Div 

FRP Co 

Fabricolor Manufacturing Corp 

Fairraount Chemical Co., Inc 

Far-Best Corp., 0, L. King Div 

Felton International, Inc 

Ferro Chemical Corp.: 

Ferro Chemical Div 

Grant Chemical Div 

Ottawa Chemical Div 

Fike Chemicals, Inc 

Fine Organics, Inc 

Firestone Tire 5 Rubber Co. : 

Firestone Plastics Co. Div 

Firestone Synthetic Fibers Co 

Firestone Synthetic Rubber 5 Latex Co. 
Div. 

First Chemical Corp 

First Mississippi (?Drp 

Fleming Laboratories, Inc 

Florasynth Inc 

Foote Mineral Co 

Formica Corp 

Foster Grant Co., Inc 

Freeman Chemical Corp 

Fritzsche Dodge 5 Olcott, Inc 

H. B. Fuller Co 

Fuller-O'Brien Corp 

GAF Corp 

Chemical Div 

Gane's Chemical Works, Inc 

Gardinier Big River, Inc 

General Electric Co 

Insulating Materials Dept 

Silicone Products Dept 

General Foods Corp., Maxwell House Div — 

General Latex 6 Chemical Corp 

General Mills Chemicals, Inc 

General Plastics Manufacturing Co 

General Tire 5 Rubber Co. , Chemical/ 
Plastics Div. 

P. D. George Co 

Georgia-Pacific Corp 

Bellingham Div 

Rebecca Chemical Div 

Getty Oil Co. (Eastern Operations, Inc.) 

The Gillette Co. , Chemical Div 

Oilman Paint § Varnish Co 



P. 0. Box 3272, Houston, TX 77001. 



100 Niagara St., Middleport, NY 14105. 

1617 John F. Kennedy Blvd., Philadelphia, PA 19103. 

2000 Market St., Philadelphia, PA 19103 and Sawyer Ave. 

5 River Rd. , Town of Tonawanda, NY 14150. 
2000 Market St., Philadelphia, PA 19103. 
P. 0. Box 349, Baxley, GA 31513. 
24-1/2 Van Houten St., P. 0. Box 2398, Paterson. 

NJ 07509. 
117 Blanchard St., Newark, NJ 07105. 
640 Gilman St., Berkeley, CA 94710. 
599 Johnson Ave., Brooklyn, NY 11237. 

P. 0. Box 46349, 7050 Krick Rd. , Bedford, OH 44146. 
P. 0. Box 263, Baton Rouge, LA 70821. 
700 N. Wheeling St., Toledo, OH 43605. 
P. 0. Box 546, Nitro, WV 25143. 
205 Main St., Lodi, NJ 07644. 

P. 0. Box 699, Pottstown, PA 19464. 

Hopewell, VA 23869. 

381 W. Wilbeth Rd. , Akron, OH 44301. 

P. 0. Box 1427, Pascagoula, MS 39567. 

656 N. State St., P. 0. Box 1249, Jackson, MS 39205. 

P. 0. Box 10372, Charlotte, NC 28201. 

900 Van Nest Ave., Bronx, NY 10462. 

Route 100, Exton, PA 19341. 

120 E. 4th St., Cincinnati, OH 45202. 

289 N. Main St., Leominster, MA 01453. 

222 E. Main St., Port Washington, WI 53074. 

76 9th Ave., New York, NY 10011. 

2400 Kasota Ave., St. Paul, MN 55108. 

450 E. Grand Ave., S. San Francisco, CA 94080. 

P. 0. Box 6037, Chattanooga, TN 37401. 

P. 0. Box 12, Linden, NJ 07036. 

535 5th Ave., New York, NY 10017. 

P. 0. Box 825, Helena, AK 72342. 

1 Plastics Ave., Pittsfield, MA 01201 and So. 

Second St., Coshocton, OH 43812. 
1 Campbell Rd. , Schenectady, NY 12306. 
Mechanicville Rd. , Waterford, NY 12188. 
1125 Hudson St., Hoboken, NJ 07030. 
666 Main St., Cambridge, MA 02139. 
4620 W. 77th St., Minneapolis, MN 55435. 
3481 S. 35th'St., Tacoma, WA 98409. 
1 General St., Akron, OH 44329. 

5200 N. 2d St., St. Louis, MO 63147. 
900 S.W. 5th Ave., Portland, OR 97204 
P. 0. Box 1236, Bellingham, WA 98225. 
P. 0. Box 629, Plaquemine, LA 70764. 
Delaware, DE 19706. 

3500 W. 16th St., N. Chicago, IL 60064. 
216 W. 8th St., Chattanooga, TN 37402. 



SYNTHEIIC ORGANIC CHEMICALS, 1974 



TABLE 1. 



-Synthetic organic chemicals: Alphabetical directory of manufacturers, 
by company, 1974--conti nued 



Name of company 



Office address 



GIV 
GLX 
GLY 
BFG 

GYR 
GOR 



GCC 

HMP 

GRH 
MRO 
GRD 
GPR 
GRA 
GTL 
GRW 
GRV 



HNC 
HLI 
HAL 
FOG 

HAN 
HDM 
HSH 

HRT 

HVG 

HKY 

SCP 

HCR 

HPC 

HER 

HES 

HEX 

HEW 

HEX 

REZ 

HDG 

HOP 

HK 

HKD 

RUB 

EFH 

HMY 

WAY 

HNT 
HUS 
HYN 



RAY 
INP 
INL 



Givaudan Corp 

G las flex Corp 

Glyco Chemicals, Inc 

B. F. Goodrich Co., B. F. Goodrich Chemical 
Co. Div. 

Goodyear Tire 5 Rubber Co 

Carl Gordon Industries, Inc., Gordon 

Chemical Co. Div 
W. R. Grace S Co. ; 

Agricultural Chemicals Group 

Dewey 5 Almy Chemical Div., Organic 
Chemicals- 

Hatco Chemical Div 

Marco Chemical Div 

Polymers 5 Chemicals Div 

Grain Processing Corp 

Great American Chemical Corp 

Great Lakes Chemical Corp 

Great Western Sugar Co 

Guardsman Chemical Coatings, Inc 



Gulf Oil Corp. 

U. S. 
Guth Corp 



Gulf Oil Chemicals Co. 



H § N Chemical Co 

Haag Laboratories, Inc 

C. P. Hall Co. of Illinois 

Handschy Chemical Co. , Farac Oil and 
Chemical Div. 

Hanna Chemical Coatings Corp 

Hardman , Inc 

Harshaw Chemical Co. Div. of Kewanee Oil 
Co. 



Hart Products Corp 

Haveg Industries, Inc 

Hawkeye Chemical Co 

Henkel , Inc 

Hercor Chemical Corp 

Hercules , Inc 

Heresite 5 Chemical Co 

Hess Oil Virgin Islands Corp 

Het eroch emi cal Corp 

Hewitt Soap Co., Inc 

Hexagon Laboratories, Inc 

Hexcel Corp., Rezolin Div 

Hodag Chemical Corp 

Hoffmann-LaRoche, Inc 

Hooker Chemicals 5 Plastics Corp 

Durex Div 

Ruco Div 

E. F. Houghton 6 Co 

Humphrey Chemical Co 

Philip A. Hunt Chemical Corp., Organic 
Chemical Div. 

Huntington Laboratories, Inc 

Husky Industries, Inc 

Hynson, Westcott 6 Dunning, Inc 



ICI United States, Inc., Specialty 
Chemical Group. 

ITT Rayonier, Inc 

Indpol , Inc 

Inland Steel Co., Inland Steel Container 
Co. 



100 Delawanna Ave., Clifton, NJ 07014. 
P. 0. Box 66, Stirling, NJ 07980. 
51 Weaver St., Greenwich, CT 06830. 
6100 Oak Tree Blvd., Cleveland, OH 44131. 

1144 E. Market St., Akron, OH 44316. 

lOni Southbridge St., Worcester, MA 01610. 



P. 0. Box 277, Memphis, TN 38101. 
Poisson Ave., Nashua, NH 03060. 

King George Post Rd., Fords, NJ 08863. 

1711 W. Elizabeth Ave., Linden, NJ 07036. 

55 Hayden Ave., Lexington, MA 02173. 

1600 Oregon St., Muscatine, LA 52761. 

650 Water St., Fitchburg, MA 01420. 

P. 0. Box 2200, West Lafayette, IN 47906. 

P. 0. Box 5308, Terminal Annex, Denver, CO 80217. 

1350 Steele Ave., S.W., Grand Rapids, MI 49502, and 

1350 S. 15th St., Louisville, KY 40210. 
P. 0. Box 2100, Houston, TX 77001. 

P. 0. Box 302, Naperville, IL 60540. 

90 Maltese Dr., Totowa, NJ 07512. 
14010 S. Seeley Ave., Blue Island, IL 60406. 
7300 S. Central Ave., Chicago, IL 60638. 
13601 S. Ashland Ave., Riverdale, IL 60627. 

P. 0. Box 147, Columbus, OH 43216. 

600 Cortlandt St., Belleville, NJ 07109. 

1945 E. 97th St., Cleveland, OH 44106. 

173 Sussex St., Jersey City, NJ 07302. 

900 Greenback Rd. , Wilmington, DE 19808. 

P. 0. Box 899, Clinton, lA 52733. 

480 Alfred Ave., Teaneck, NJ 07666. 

Petrochemical Complex, Ponce, PR 00731. 

910 Market St., Wilmington, DE 19899. 

822 S. 14th St., Manitowoc, WI 54220. 

Kingshill P. 0. Box 127, St. Croix, VI 00850. 

Ill E. Hawthorne Ave., Valley Stream, NY 11580. 

333 Linden Ave., Dayton, OH 45403. 

3536 Peartree Ave., Bronx, NY 10475. 

20701 Nordhoff St., Chatsworth, CA 91311. 

7247 N. Central Park Ave., Skokie, IL 60076. 

324-424 Kingsland St., Nutley, NJ 07110. 

MPO Box 8, Niagara Falls, NY 14302. 

Walck Rd., N. Tonawanda, NY 14121. 

P. 0. Box 456, Burlington, NJ 08016. 

303 W. Lehigh Ave., Philadelphia, PA 19133. 

Devine St., North Haven, CT 06473. 

P. 0. Box 4249 E. Providence, RI 02914. 

P. 0. Box 710, Huntington, IN 46750. 

62 Perimeter Center E. , Atlanta, GA 30346. 

Charles and Chase Sts., Baltimore, MD 21201. 

Wilmington, DE 19899. 

605 3d Ave., New York, NY 10016. 

8434 Rochester Ave., Cucamonga, CA 91730. 

4300 W. 130th St., Chicago, IL 60658. 



APPENDIX 



TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY. 1974 — CONTI NUED 



Name of company 



Office address 



BRD 
LUB 

TZC 
MGR 

MAL 



Inmont Corp 

Color Systems Group 

Inolex Corp 

Inolex Pharmaceutical Div 

Insilco Corp., Frisch 5 Co. Div 

International Flavors 5 Fragrances, Inc- 

Interplastic Corp 

Interstab Chemical, Inc 

lonac Chemical Co. Div. of Sybron Corp-- 
Ironsides Resins, Inc 



Jefferson Chemical Co. , Inc — 
George A. Jeffreys 6 Co., Inc- 

Jennison-Wright Corp 

Andrew Jergens Co 

Jersey State Chemical Co 

S. C. Johnson 5 Son, Inc 

Jones-Blair Co 

Jordan Chemical Co 

Julian Associates, Inc 



Kaiser Aluminum S Chemical Corp.: 
Kaiser Agricultural Chemicals Div- 

Kai s er Chemi cal s 

Kalama Chemical Co 

Kay-Fries Chemicals, Inc 

Kelly-Moore Paint Co 

Kennecott Copper Corp.: 

Chino Mines Div 

Utah Copper Div 

Kerr-McGee Chemical Corp 

Keysor Century Corp 

Keystone Color Works, Inc 

Knapp Products, Inc 

Knoedler Chemical Co 

Kohler-McLister Paint Co 

H. Kohnstamm 5 Co., Inc 

Koppers Co., Inc 

Organic Materials Div 

Roads Materials Div 

Krafto Corp. : 

Humko Products Div 

Humko Sheffield Chemicals 

Kyanize Paints, Inc 



Lakeside Laboratories Div. of Richardson- 
Merrill, Inc. 

Lake States Div. of St. Regis Paper Co 

Lakeway Chemicals Inc 

LaMotte Chemical Products Co 

Laurel Products Corp 

Leatex Chemical Co 

Lever Brothers Co 

C. Lever Co., Inc 

Life Savers, Inc 

Eli Lilly 5 Co 



Lonza, Inc 

Lubrizol Corp- 



Magnesium Elektron, Inc 

Magruder Color Co., Inc 

Mallinckrodt Chemical Works- 



5935 Milford Ave., Detroit, MI 48210. 

150 Wagaraw Rd. , Hawthorne, NJ 07506. 

Jackson 5 Swanson Sts., Philadelphia, PA 19148. 

2600 Bond St., Park Forest South, IL 60466. 

88 E. 11th St., Paterson, NJ 07524. 

521 W. 57th St., New York, NY 10019. 

2015 NE. Broadway St., Minneapolis, MN 55413. 

500 Jersey .Ave., New Brunswick, NJ 08903. 

Birmingham, NJ 08011. 

270 W. Mound St., Columbus, OH 43216. 

P. 0. Box 53300, Houston, TX 77052. 

P. 0. Box 709, Salem, VA 24153. 

P. 0. Box 691, Toledo, OH 43694. 

2535 Spring Grove Ave. , Cincinnati, OH 45214. 

59 Lee Ave., Haledon, NJ 07508. 

1525 Howe St., Racine, WI 53403. 

2728 Empire Central, Dallas, TX 75235. 

1830 Columbia Ave., Folcraft, PA 19032. 

9352-58 W. Grand Ave., Franklin Park, IL 60136. 



P. 0. Box 246, Savannah, GA 31402. 

P. 0. Box 337, Gramercy, LA 70052. 

P. 0. Box 427, Kalama, WA 98625. 

360 Lexington Ave., New York, NY 10017. 

1015 Commercial St., San Carlos, CA 94070. 

Hurley, MN 88043. 

P. 0. Box 11299, Salt Lake City, UT 84111. 

Kerr-McGee Bldg., Oklahoma, OK 73102. 

P. 0. Box 308, Saugus, CA 91350. 

151 W. Gay Ave., York, PA 17403. 

187 Garibaldi Ave., Lodi, NJ 07644. 

650 Lafayette St., Lancaster, PA 17604. 

P. 0. Box 546, Denver, CO 80201. 

161 Avenue of the Americas, New York, NY 10013. 

Koppers Bldg., Pittsburgh, PA 15219. 

Koppers Bldg., Pittsburgh, PA 15219. 

Koppers Bldg., Pittsburgh, PA 15219. 

P. 0. Box 398, Memphis, TN 38101. 
1099 Wall St., Lyndhurst, NJ 07071. 
2d and Boston Sts., Everett, MA 02149. 

1707 E. North Ave., Milwaukee, WI 53201. 

603 W. Davenport St., Rhinelander, WI 54501. 

5025 Evanston Ave., Muskegon, MI 4944 3. 

Chestertown, MD 21620. 

2600 E. Tioga St., Philadelphia, PA 19134. 

2722 N. Hancock St., Philadelphia, PA 19133. 

390 Park Ave., New York, NY 10022. 

736 Dunks Ferry Rd., Comwells Hgts, PA 19020. 

Church St., Canajoharie, NY 13317. 

307 E. McCarty St., Indianapolis, IN 46206 and G.P.O. 

Box 4388, San Juan, PR 00936. 
22-10 Route 208, Fair Lawn, NJ 07410. 
29400 Lakeland Blvd., Wickliffe, OH 44092. 

P. 0. Box 202-1, Flemington, NJ 08822. 
1 Virginia St., Newark, NJ 07114. 
3600 N. 2d St., St. Louis, MO 63147. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE 1.— Synthetic organic chemicals; Alphabetical directory of manufacturers. 

BY COMPANY. igZ^*— CONTINUED 



Name of company 



Manufacturing Enterprises, Inc., Squibb 
Manufacturing, Inc., Trade Enterprises, 
Inc. 

Marathon Morco Co 

Marathon Oil Co., Texas Refining Div 

Marblette Co 

Marden-Wild Corp 

Marlowe-Van Loan Corp 

Martin-Marietta Corp., Sodyeco Div 

Max Marx Color 5 Chemical Co 

Masonite Corp., Alpine Chemical Div 

Otto B. May, Inc 

McCloskey Varnish Co 

McLaughlin Gormley King Co 

Mead Johnson 5 Co 

Melamine Chemicals, Inc 

Merck 5 Co., Inc 

Merichem Co 

Michigan Chemical Corp 

Midwest Manufacturing Corp 

Miles Laboratories, Inc., Marschall Div. 

and Sumner Div. 
Millmaster Onyx Corp. : 

A. Gross 5 Co. Div 

Millmaster Chemical Div. , Berkely 
Chemical Dept. 

Onyx Chemical Co. Div 

Refined-Onyx Div 

Minnesota Mining § Manufacturing Co 

Miranol Chemical Co., Inc 

Mississippi Chemical Corp 

Mobay Chemical Co 

Mobay Chemical Corp.: 

Chemagro Agricultural Div 

Verona Div 

Mobil Oil Corp 

Mobil Chemical Co 

Chemical Coatings Div 

Mona Industries, Inc 

Monochem , Inc 

Monroe Chemical Co 

Monsanto Co 

Bircham Bend Plant 

Chocolate Bayou Plant 

Plastics Div 

Springf ie 1 d PI ant 

Textiles Div 

Montrose Chemical Corp. of California 

Mooney Chemicals, Inc 

Moretex Chemical Products, Inc 

Morton Chemical Co. Div. of Morton -Norwich 
Products, Inc. 

Motomco , Inc 

Murphy- Phoeni X Co 

NL Industries, Inc 

Nalco Chemical Co 

Napp Chemicals, Inc 

National Biochemical Co 

National Casein Co 

National Distillers S Chemical Corp., U.S. 
Industrial Chemicals Co. Div. 



Office address 



P. 0. Box 609, Humacao, PR 00661. 



P. 0. Drawer C, Dickinson, TX 77539. 
P. 0. Box 1191, Texas City, TX 77590. 
37-31 30th St., Long Island City, NY 11101. 
500 Columbia St., Somerville, MA 02143. 
1511 Joshua Circle, High Point, NC 27261. 
P. 0. Box 10098, Charlotte, NC 28237. 
192 Coit St., Irvington, NJ 07111. 
P. 0. Box 2392, Gulfport, MS 39503. 
52 Amsterdam St., Newark, NJ 07105. 
7600 State Rd., Philadelphia, PA 19136. 
8810 10th Ave., N., Minneapolis, MN 55427. 
2404 Penna. St., Evansville, IN 47721. 
P. 0. Box 748, Donaldsonville, LA 70346. 
126 E. Lincoln Ave., Rahway, NJ 07065. 
1914 Haden Rd. , Houston, TX 77015. 
2 N. Riverside Plaza, Chicago, IL 60606. 
Oak St. and Bluff Rd., Burlington, lA 52601. 
1127 Myrtle St., Elkhart, IN 46514. 



652 Doremus Ave., Newark, NJ 07105. 
99 Park Ave., New York, NY 10016. 

190 Warren St., Jersey City, NJ 07302. 

624 Schuyler Ave., Lyndhurst, NJ 07071. 

3M Center, St. Paul, MN 55101. 

660 Stuyvesant Ave., Irvington, NJ 07111. 

P. 0. Box 388, Yazoo City, MS 39194. 

Penn Lincoln Parkway, W. Pittsburgh, PA 15205. 

P. 0. Box 4913, Station "F", Kansas City, MO 64120. 

lorio Ct., Union, NJ 07083. 

P. 0. Box 900, Dallas, TX 75221. 

P. 0. Box 3868, Beaumont, TX 77704, and P. 0. Box 

26683, Richmond, VA 23261. 
1024 South Ave., Plainfield, NJ 07062. 
65 E. 23d St., Paterson, NJ 07524. 
P. 0. Box 488, Geismar, LA 70734. 
Eddystone, PA 19013. 
2710 Lafayette St., Santa Clara, CA 95050 and 800 N. 

Lindbergh Blvd., St. Louis, MO 63166. 
190 Grochmal Ave., Indian Orchard, MA 01151. 
P. 0. Box 711, Alvin, TX 77511. 
5100 W. Jefferson Ave., Trenton, MI 48183; 

River Rd. , Addyston, OH 45001 and P. 0. Box 1311, 

Texas City, TX 77590. 
730 Worcester St., Indian Orchard, MA 01151. 
800 N. Lindbergh Blvd., St. Louis, MO 63166. 
3250 Wilshire Blvd, Suite 1800, Los Angeles, CA 90010. 
2301 Scranton Rd. , Cleveland, OH 44113. 
314 W. Henry St., P. 0. 1799, Spartanbury, SC 29301. 

110 N. Wacker Dr., Chicago, IL 60606. 

89 Terminal Ave., Clark, NJ 07066. 
9505 Cassius Ave., Cleveland, OH 44105. 

111 Broadway, New York, NY 10006. 

2901 Butterfield Rd, Oak Brook, IL 60521. 

199 Main St., Lodi, NJ 07644. 

3127 W. Lake St., Chicago, IL 60612. 

601 W. 80th St., Chicago, IL 60620. 

99 Park Ave., New York, NY 10016. 



APPENDIX 



TABLE 1. --Synthetic organic chemicals; Alphabetical directory of manufacturers, 
BY company, 197^1— Continued 




National Milling 5 Chemical Co-- 

National Petro Chemical Corp 

National Starch 5 Chemical Corp- 

Nease Chemical Co. , Inc 

Nepera Chemical Co., Inc 

Neville Chemical Co 

Niklor Chemical Co 

Nilok Chemicals, Inc 

Nipak, Inc 

Nipro, Inc 

Norac Co. , Inc 

Mathe Chemical Co. Div 

Norda, Inc 

Norris Paint S Varnish Co 

North American Chemical Co 

Northern Fine Chemicals, Inc 

Northern Petrochemical Co 

Northwestern Chemical Co 

Northwest Petrochemical Corp 

Norwich Pharmacal Co 

Nostrip Chemical Works, Inc 

Noury Chemical Corp 

Novamont Corp., Neal Works 

Nyanza, Inc 



O'Brien Corp- 
Olin Corp 



Orbis Products Corp 

Organics, Inc 

Original Bradford Soap Works, 
Owens -Coming Fiberglas Corp- 
Oxirane Chemical Co 

Oxochem Enterprise 



P L Biochemicals, Inc 

PPG Industries, Inc 

PVO International, Inc., Chemical 

Specialties Div. 

Pace National Corp 

Pacific Resins 5 Chemicals, Inc — 

Pan American Chemical Corp 

Pantasote Co. of New York, Inc 

Parke, Davis § Co 

Passaic Color S Chemical Co 

Pathan Chemical Co 

C. H. Patrick 6 Co., Inc 

Pearsall Chemical Corp 

Peck's Products Co 

Peerless Chemical Co 

Pelron Corp 

Pennwal t Corp 

Lucidol Div 

Pennzoil Co., Penreco Div 

Perry 6 Derrick Co., Inc 

Petrochemicals Co., Inc 

Petro-Tex Chemical Corp 

Pfanstiehl Laboratories, Inc 

Pfister Chemical, Inc 

Pfizer, Inc 

Pfizer Pharmacuticals, Inc 



4601 Flat Rock Rd. , Philadelphia, PA 19127. 

99 Park Ave., New York, NY 10016. 

10 Findeme Ave. , Bridgwater, NJ 08876. 

P. 0. Box 221, State College, PA 16801. 

Route 32, Harriman, NY 10926. 

Neville Island P. 0., Pittsburgh, PA 1S225. 

2060 E. 220th St., Long Beach, CA 90810. 

2235 Langdon Farm Rd., Cincinnati, OH 45230. 

301 S. Harwood St., Dallas, TX 75221. 

P. 0. Box 1483, Augusta, GA 30903. 

405 S. Motor Ave., Azusa, CA 91703. 

169 Kennedy Dr., Lodi, NJ 07644. 

475 10th Ave., New York, NY 10001. 

P. 0. Box 2023, Salem, OR 97308. 

19 Chestnut St., Cambridge, MA 02139. 

93 Main St., Franklin, NJ 07416. 

2350 Devon Ave., Des Plaines, IL 60018. 

120 N. Aurora St., W. Chicago, IL 60185. 

P. 0. Box 99, Anacortes, WA 98221. 

17 Eaton Ave., Norwich, NY 13815. 

P. 0. Box 160, Pedrichtown, NJ 08067. 

2153 Lockport-Olcott Rd. , Burt, NY 14028. 

P. 0. Box 189, Kenova, WV 25530. 

Maguno Rd. , Ashland, MA 01721. 

2001 W. Washington Ave., South Bend, IN 46627. 
120 Long Ridge Rd. , Stamford, CT 06904, and 

Box 991, Little Rock, AR 72203. 
475 10th Ave., New York, NY 10008. 
7125 N. Clark St., Chicago, IL 60628. 
200 Providence St., W. Warwick, RI 02893. 
Fiberglas Tower, Toledo, OH 43659. 
10801 Choate Rd., Houston, TX 77062. 
P. 0. Box 27, King George Post Rd. , Fords, NJ 08863. 

1037 W. McKinley Ave., Milwaukee, WI 53205. 
1 Gateway Center, Pittsburgh, PA 15222. 
416 Division St., Boonton, NJ 0700S. 

500 7th Ave., S. , Kirland, WA 98033. 

1754 Thorne Rd., Tacoma, WA 93421. 

21 Stable .Ave., Wilmington, DE 19803. 

26 Jefferson St., Passaic, NJ 07056. 

Jos. Campau at the River, Detroit, MI 48232. 

28-36 Paterson St., Paterson, NJ 07501. 

427 Meyer St., Philadelphia, PA 19125. 

P. 0. Box 2526, Greensville, SC 29602. 

P. 0. Box 437, Houston, TX 77001. 

610 E. Clarence Ave., St. Louis, MO 63147. 

12416 Cloverdale Ave., Detroit, MI 48204. 

7847 W. 47th St., Lyons, IL 60534. 

3 Parkway, Philadelphia, PA 19102. 

1740 Military Rd. , Buffalo, NY 14240. 

Union Bank Bldg., Butler, PA 16001. 

2S10 Highland Ave., Norwood, OH 45212. 

P. 0. Box 2199, Fort Worth, TX 76101. 

8600 Park Place Blvd., Houston, TX 77017. 

1219 Glen Rock Ave., Waukegan, IL 60085. 

Linden Ave., Ridgefield, NJ 07657. 

235 E. 42d St., New York, NY 10017. 

P. 0. Box 628, Barcelonita, PR 00617. 



SYNTHETIC ORGANIC CHEMICALS, 1974 



TABLE L— Synthetic organic chemicals; Alphabetical Directory of manufacturers, 

BY company. 1974--CONTINUED 



RIV 
ROB 
RBT 
MFC 

ORT 

RGC 



Name of company 



Pharmachem Corp 

Phillips Petroleum Co 

Phillips Puerto Rico Core, Inc 

Pierce Chemical Co 

Pilot Chemical Co 

Pioneer Plastics Corp 

Pitt-Consol Chemical Co 

Plastics Engineering Co 

Plastics Manufacturing Co 

Plex Chemical Corp 

Polak's Frutal Works, Inc 

Polymer Corp 

Polyrez Co., Inc 

Polyvinyl Chemical Ind. Div. of 

Beatrice Foods Co. 

Pope Chemical Corp 

Pratt 5 Lambert, Inc 

Premier Malt Products, Inc 

Premier Petrochemical Co 

Princeton Chemical Research, Inc 

Procter 5 Gamble Co. , Procter 5 Gamble 

Mfg. Co. 

Proctor Chemical Co., Inc 

Productol Chemical Co., Inc 

Products Research 5 Chemical Corp 

Publicker Industries, Inc 

Puerto Rico Chemical Co., Inc 

Puerto Rico Olefins 

Pur ex Corp 

Quaker Chemical Corp — 

Quaker Oats Co 

K. J. Quinn 5 Co., Inc 

R.S.A. Corp 

Rachelle Laboratories, Inc 

Racon, Inc 

Raybest OS -Manhattan, Inc 

Red Spot Paint 5 Varnish Co., Inc 

Reheis Chemical Co. Div. of ,^rmour 

Pharmaceutical Co, 

Reichhold Chemicals, Inc 

Reilly Tar 5 Chemical Corp 

Reliance Universal, Inc. of Texas 

Resin Div 

Remington Arms Co., Inc 

Resyn Corp 

Rhodia, Inc 

Richardson Co. 

Polymeric Systems Div 

Riker Laboratories, Inc., Sub. of 3M Co-- 

Rilsan Corp 

F. Ritter S Co 

Riverdale Chemical Co 

Robeco Chemicals, Inc 

Robintech, Inc 

Rockwell International Corp., Automotive 

Products Group, Resin Plant. 
Roehr Chemicals Div of Aceto Industrial 

Chemical Co. 

Rogers Corp 

Rohm 5 Haas Co 



Office address 



719 Stefko Blvd., Bethlehem, PA 18018. 

16D2 Phillips Bldg. , BartlesviUe, OK 74003. 

GPO Box 4129, San Juan, PR 00936. 

3747 N. Meridan Rd., Rockford, IL 61103. 

11756 Burke St., Santa Fe Springs, CA 90670. 

Pionite Rd. , Auburn, ME 04210. 

Park Eighty Plaza East, Saddle Brook, NJ 07662. 

P. 0. Box 758, Sheboygan, WI 53081. 

2700 S. Westmoreland Ave., Dallas, TX 75224. 

1205 Atlantic St., Union City, CA 94487. 

33 Sprague Ave. , Middletown, NY 10940. 

2120 Fairmont Ave., Reading, PA 19603. 

S. Columbia St. § Railroad, Woodbury, NJ 08096. 

730 Main St., Wilmington, MA 01887. 

33 6th Ave., Paterson, NJ 07524. 

P. 0. Box 22, Buffalo, NY 14240. 

917 W. Juneau Ave., Milwaukee, WI 53201. 

530 N. Witter, Pasadena, TX 77501. 

P. 0. Box 651, Princeton, NJ 08540. 

301 E. 6th St., Cincinnati, OH 45202. 

P. 0. Box 399, Salisbury, NC 28144. 
13215 E. Penn St., Whittier, CA 90602. 
2919 Empire Ave., Burbank , CA 91505. 
1429 Walnut St., Philadelphia, PA 19102. 
P. 0. Box 496, Arecibo, PR 00613. 
Firm Delivery, Ponce, PR 00731. 
5101 Clark Ave., Lakewood, CA 90712 and 
2258 Elston Ave., Chicago, IL 60614. 

Lime 5 Elm Sts., Conshohocken, PA 19428. 

345 Merchandise Mart Plaza, Chicago, IL 60654. 

195 Canal St., Maiden, MA 02148. 

690 Sawmill River Rd. , Ardsley, NY 10502. 
700 Henry Ford Ave., Long Beach, CA 90801. 
P. 0. Box 198, Witchita, KS 67201. 
74 E. Main St., Stratford, CT 06497. 

110 Main St., Evansville, IN 47703. 

111 W. Clarendon Greyhound Tower, Phoenix, AZ I 

525 N. Broadway, White Plains, NY 10602. 
1615 Merchants Bank, Indianapolis, IN 46204. 
6901 Cavalcade St., Houston, TX 77001. 
P. 0. Box 21423, Louisville, KY 40221. 
939 Barnum Ave., Bridgeport, CT 06602. 
1401 W. Blancke St., Linden, NJ 07036. 
120 Jersey Ave., New Brunswick, NJ 08903. 
2400 E. Devon Ave., Des Plaines, IL 60018. 
15 Miegs Ave., Madison, CT 06443. 
19901 Nordhoff St., Northridge, CA 91324. 
139 Harristown Rd., Glen Roc, NJ 07452. 
4001 Goodwin Ave., Los Angeles, CA 90039. 
220 E. 17th St., Chicago Heights, IL 60411. 
51 Madison Ave., New York, NY 10010. 
1407 Texas St., Fort Worth, TX 76102. 
4501 Benefit Ave., Ashtabula, OH 44004. 

52-20 37th St., Long Island City, NY 11101. 



Rogers, CT 06263. 
Independence Mall West, 



Philadelphia, PA 19105. 



APPENDIX 



TABLE 1, 



-Synthetic organic chemicals; Alphabetical directory of manufacturers, 
by company. 197'l--conti nued 



Identi- 
fication 
code 



Name of company 



NPR 
SLM 
SAL 



SAR 

SCN ' 

SBC ; 

SCR : 

SCH ' 

SCO I 

SPR ! 

SPA ! 

SEA i 

SRL 

SEY 

SKP 

SHA 

SHO 

SHC 

SHP 

SW 

SID 

SIM 

SKC 

SPC 

AMS 

SKO 

GFS 

SK 

SBN 

MTR 

SOL 

SLT 

SLC 

STC 

SAC 

SOP 
SOS 
SPL 
OMS 
STA 
UBS 
CCL 
CLN 

SBI 
SOC 



Office address 



SIO 
STG 



Rubicon Chemicals, Inc 

SCM Corp., Glidden-Durkee Div 

Safeway Stores, Inc 

Salem Oil S Grease Co 

Salsbury Laboratories 

Sandoz, Inc. : 

Crop Protection Dept 

Sandoz Color 5 Chemicals Div 

Sartomer Industries, Inc 

Schenectady Chemicals, Inc 

Scher Bros., Inc 

R. P. Scherer Corp 

Schering Corp 

Scholler Bros., Inc 

Scientific Protein Labs., Inc 

Scott Paper Co 

Seaboard Chemicals, Inc 

G. D. Searle 5 Co 

Seydel -Wool ley 6 Co. div of AZS Corp 

Shakespeare Co., Monofilament Div 

Shanco Plastics § Chemicals, Inc 

Shell Oil Co 

Shell Chemical Co. Div 

Shepherd Chemical Co 

Shenvin-Williams Co 

George F. Siddall Co., Inc 

Simpson Timber Co., Chemicals Div 

Sinclair-Koppers Chemical Co 

Sinclair Paint Co. , Div. of Insilco Corp-- 
Sinclair 8 Valentine Co., Inc 

Ridgway Color 5 Chemical 

Skelly Oil Co 

G. Frederick Smith Chemical Co 

Smith, Kline 5 French Laboratories 

Sobin Chemical Co 

Sobin Chemicals, Inc., Montrose Div 

Solar Chemical Corp 

Solte.x Polymer Corp 

Soluol Chemical Co., Inc 

Sou-Tex Chemical Co., Inc 

Southeastern Adhesives Co 

Southern Chemical Products Co., Inc 

Southern Siting Co 

Spaulding Fibre Co., Inc 

E. R. Squibb 5 Sons, Inc 

A. E. Staley Manufacturing Co 

Staley Chemicals Div 

Textile Div 

Standard Brands, Inc. , Clinton Com 

Processing Co. Div. 
Standard Brands Chemical Industries, Inc-- 
Standard Oil Co. of California, Chevron 

Chemical Co. 

Standard Oil Co. of Ohio 

Stange Co 



07936. 
Essington, PA. 



P. 0. Box 517, Geismar, LA 70734. 

900 Union Commerce Bldg. , Cleveland, OH 44115, and 

2333 Logan Blvd., Chicago, IL 60647. 
8390 Capwell Dr., Oakland, CA 94604. 
60 Grove St., Salem, MA 01970. 
2000 Rockford Rd. , Charles City, lA 50616. 
P. 0. Box 357, Fair Lawn, NJ 07410. 
P. 0. Box 207, Wasco, CA 93280. 
Route #10, P. 0. Box 11, E. Hanover, 
Gov. Print z Blvd. 8 Wanamaker Ave. 

19029. 
P. 0. Box 1046, Schenectady, NY 12301. 
P. 0. Box 538, Allwood Station, Clifton, NJ 07012. 
9425 Grinnell Ave., Detroit, MI 48213. 
Galloping Hill Rd., Kenilworth, NJ 07033. 
Collins and Westmoreland Sts., Philadelphia, PA 19134. 
P. 0. Box 1409, Madison, WI 53701. 
106 Central Ave., Oconto Falls, WI 54154. 
30 Foster St., Salem, MA 01970. 
P. 0. Box 5110, Chicago, IL 60680. 
762 Marietta Blvd., NW. , Atlanta, GA 30318. 
6111 Shakespare Rd. , Columbia, SC 29240. 
HI Wales St., Tonawanda, NY 14150. 
P. 0. Box 2463, Houston, TX 77001. 

One Shell Plaza, P. 0. Box 2463, Houston, TX 77001. 
4900 Beech St., Cincinnati, OH 45212. 
101 Prospect Ave., NW Cleveland, OH 44115. 
P. 0. Box 925, Spartanburg, SC 29301. 
2301 N. Columbia Blvd., Portland, OR 97217. 
P. 0. Box 12188, Houston, TX 77012. 
3960 E. Washington Blvd., Los Angeles, CA 90023. 
75 Front St., Ridgway, PA 15853. 

P. 0. Box 1650, Tulsa, OK 74102. 

867 McKinley Ave., Columbus, OH 43223. 

1500 Spring Garden St., Philadelphia, PA 19101. 

P. 0. Box 149, Orrington, ME 04474. 

100 Listen Ave., Newark, NJ 07105. 

29 Fuller St., Leominster, MA 01453. 

550 Broad St., Newark, NJ 07102. 

Green Hill and Market Sts., W. Warwick, RI 02893. 

E. Catawba Ave., P. 0. Box 866, Mount Holly, NC 

28120. 
P. 0. Box 791, Lenoir, NC 28645. 
430 Lower Boundary St., Macon, GA 31202. 
1550 E. Taylor Ave., East Point, GA 30344. 
310 Wheeler St., Tonawanda, NY 14150. 
Georges Rd. , Brunswick, NJ 08903. 
2200 Elorado St., Decatur, IL 62525. 
320 Schuyler Ave., Kearny, NJ 07032. 
P. 0. Box 948, Charlotte, NC 28231. 
1251 Beaver Channel Parkway, Clinton, lA 52733. 



P . . Drawer 
200 Bush St. , 



C, Dover, DE 19901. 
San Francisco, CA 94i; 



Midland Bldg., Cleveland, OH 44115. 
342 N. Western Ave., Chicago, IL 60612. 



SYNTHETIC ORGA^JIC CHEf^ICALS, 1974 
TABLE 1.— Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY COMPANY, 1974--CONTI NUED 



Identi- 
fication 
code 



Name of company 



SFA 

SFC 

SFF 

SFI 

SFP 

AME 

SFS 

BPC 

SWS 

SH 

STP 

MYW 

NPI 

SDG 
SDH 
TMS 
SDW 
SLV 
OTC 
STY 
SBP 

SNW 

SNA 
SKG 
SUN 
SNO 
SNT 
SWT 



FAR 
FCD 
HFT 



TCC 

GST 

TEK 

HN 

CIK 

TOG 

TVA 

TER 

TX 

TSA 

TUS 

TXC 

TCI 

TXT 

TXN 

SKT 

TKL 

SOR 



TRC 

ACT 



Stauffer Chemical Co. : 

Agricultural Div 

Calhio Chemicals, Inc 

Food Ingredients Div 

Industrial Div 

Plastics Div 

Polymers West 

Specialty Div 

Benzol Products 

SWS Silicones Div 

Stein Hall 5 Co., Inc 

Stepan Chemical Co 

Maywood Div 

Polychem Dept 

Sterling Drug, Inc. : 

Glenbrook Laboratories Div 

Hilton-Davis Chemical Co. Div 

Thomasset Colors Div 

Winthrop Laboratories Div 

Sterwin Chemicals, Inc 

Story Chemical Corp 

Styrochem Corp 

Sugar Beet Products Co 

Sun Chemical Corp. : 

Chemical Div 

Pigments Div 

Sunkist Growers, Inc 

Sun Oil Co 

SunOlin Chemical Co 

Suntide Refining Co 

Swift Specialty Chemicals Products of 

Unitich Chemical, Inc. 
Synalloy Corp., Blackman-Uhler Chemical 
Div. 

Syncon Resins, Inc 

Synres Chemical Corp 

Syntex Agribusiness, Inc., Nutrition 5 
Chemical Div. 

Tanatex Chemical Corp 

Charles S. Tanner Co 

Teknor Apex Co 

Tenneco Chemicals, Inc 

Cal/Ink Div 

Tenneco Oil Co 

Tennessee Valley Authority 

Terra Chemicals International, Inc 

Texaco, Inc 

Texas Alkyls, Inc 

Texas-U.S. Chemical Co 

Tex Chem Co., Inc 

Texize Chemicals, Co 

Text il ana Corp 

Textilana Nease, Inc 

Textron, Inc., Spencer Kellogg Div 

Thiokol Corp 

Thomason Industries, Inc., Southern Resin 

Div. 
Thompson-Hayward Chemical Co 

Toms River Chemical Corp 

Arthur C. Trask Co 



Office address 



636 California St 
636 California St 
636 California St 
636 California St 
636 California St 
2112 E. 223d St. , 
636 California St. 
Meadow Rd., Edison 
636 California St. 



, San Francisco, CA 94119. 

, San Francisco, CA 94119. 

, San Francisco, CA 94119. 

, San Francisco, CA 94119. 

, San Francisco, CA 94119. 

P. 0. Box 1110 Long Beach, ( 

, San Francisoc, CA 94119. 

NJ 08817. 

San Francisco, CA 94119. 



P. 0. Box 1154, Louisville, KY 40201. 
RR #1, Elwood, IL 60421. 
100 West Hunter Ave., Maywood, NJ 07607. 
51 Fames St., Wilmington, MA 01887. 

90 Park Ave., New York, NY 10016. 
2235 Langdon Farm Rd. , Cincinnati, OH 45237. 
120 Lister Ave., Newark, NJ 07105. 
90 Park Ave., New York, NY 10016. 
Military Rd. , Rothschild, WI 54474. 
500 Agard Rd. , Muskegon, MI 49945. 
Petrochemical Complex, Ponce, PR 00731. 
P. 0. Box 1387, Saginaw, MI 48605. 

P. 0. Box 70, Chester, SC 29706. 

441 Tompkins Ave., Staten Island, NY 10305. 

P. 0. Box 7888, Valley Annex, Van Nuys , CA 9140 

240 Radnor-Chester Rd., St. Davids, PA 19087. 

P. 0. Box F, Claymount, DE 19703. 

P. 0. Box 2608, Corpus Christi, TX 78403. 

115 W. Jackson Blvd., Chicago, IL 60604. 

P. 0. Box 5627, Spartanburg, SC 29301. 

77 Jacobus Ave., S. Kearny, NJ 07032. 

209 N. Michigan Ave., Kenilworth, NJ 07033. 

P. 0. Box 1246 SSS, Springfield, MO 65805. 



P. 0. Box 388, Lyndhurst, NJ 07071. 

1310 Barcelona Dr., Greensville, SC 29606. 

505 Central Ave., Pawtucket, RI 02662. 

Park Eighty Plaza West-One, Saddle Brook, NJ 07662. 

600 California St., San Francisco, CA 94104. 



77001. 

51121. 

10017. 

77536. 
rx 77651. 
, NJ 07410. 



P. 0. Box 2511, Houston, TX 

Muscle Shoals, AL 35660. 

507 6th St., Sioux City, lA 

135 E. 42 St. , New York, NY 

P. 0. Box 600, Deer Park, TX 

P. 0. Box 667, Port Neches, ' 

20-21 Wagaraw Rd., Fair Lawn 

P. 0. Box 368, Greenville, SC 29602. 

12607 Cerise Ave., Hawthorne, CA 90250. 

12607 Cerise Ave., Hawthorne, CA 90250. 

120 Delaware Ave., Buffalo, NY 14240. 

P. 0. Box 27, Bristol, PA 19007. 

P. 0. Drawer 1600, Fayetteville, NC 29302. 

5200 Speaker Rd. , Kansas City, MO 66110 and 

2 E. Madison St., Waukegan, IL 60085. 
P. 0. Box 71, Toms River, NJ 08753. 
7666 W. 63d St., Summit, IL 60501. 



APPENDIX 
TABLE 1. --Synthetic organic chemicals: Alphabetical directory of manufacturers, 

BY company, 1974--CONTINUED 



Name of company 



Office address 



Triad Chemical 

Troy Chemical Co 

USS Agri-Chemicals Div of U.S. Steel Corp-- 

USS Chemicals Div. of U.S. Steel Corp 

Paul Hulich 5 Co., Inc 

Ungerer 5 Co 

Union -Camp Corp 

Harchem Div 

Union Carbide Corp 

Union Oil Co. of California 

Uniroyal, Inc., Chemical Div 

United Chemical Corp. of Norwood 

United Chemical Products Corp 

United-Erie, Inc 

United Merchants 5 Manufacturers, Inc., 

Roma Chemical Div. 

U.S. Borax Research Corp 

U.S. Industries, Inc., E. Helman Co. Div 

U.S. Oil Co 

U.S. Pipe 5 Foundry Co 

U.S. Plywood 

Universal Oil Products Co 

UOP Chemical Div 

Upjohn Co 

Fine Chemical Div 

Valchem Chemical Div. of United Merchants 

5 Manufacturers, Inc. 

Valentine Sugars, Inc 

Valley Nitrogen Producers, Inc 

The Valspar Corp 

Vanderbilt Chemical Corp 

Van Dyk 6 Co., Inc 

Velsicol Chemical Corp 

Ventron Corp 

Vertac Consolidated, Vicksburg Chemical Co. 

Viking Chemical Co 

Vineland Chemical Co 

Vinings Chemical Co 

Virginia Chemicals, Inc 

Vistron Corp 

Silmar Div 

Vitamins , Inc 

Vulcan Materials Co., Chemicals Div 

Wamer-Jenkinson Manufacturing Co 

West Agro-Chemicals, Inc 

West Coast Adhesives Co 

Westinghouse Electric Corp. , Industrial 
Plastics Div., Chemical Products Plant. 

Westvaco Corp. , Polychemicals Dept 

Weyerhaeuser Co 

White 5 Bagley Co 



P. 0. Box 310, Donaldsonville, LA 70346. 
One Avenue L, Newark, NJ 07105. 

P. 0. Box 1685 Atlanta, GA 30301. 

600 Grant St., Rm. 2880, Pittsburgh, PA 15219. 

90 West St., New York, NY 10006. 

161 Avenue of the Americas, New York, NY 10013. 

P. 0. Box 6170, Jacksonville, Fl 32205. 

P. 0. Box 220, Dover, OH 44622. 

270 Park Ave., New York, NY 10017. 

200 E. Gulf Rd., Palatine, IL 60067. 

Emic Bldg. , Naugatuck , CT 06770. 

Endicott St., Norwood, MA 02062. 

472 York St., Jersey City, NJ 07302. 

438 Huron SE., Erie, PA 16512. 

749 Quequechan St., Fall River, MA 02721. 

3075 Wilshire Blvd., Los Angeles, CA 90005. 

P. 0. Box 5129, Akron, OH 44313. 

P. 0. Box 4228, E. Providence, RI 02914. 

3300 1st Ave., N. , Birmingham, AL 35202. 

Anderson, CA 96007. 

10 UOP Plaza, Algonquin 6 Mt. Prospect Rds., 

Des Plains, IL 60016. 
State Highway 17, E. Rutherford, NJ 07073. 
7000 Portage Rd., Kalamazoo, MI 49002. 
410 Sackett Point Rd., North Haven, CT 06473. 

1407 Broadway. New York, NY 10018. 

726 Whitney Bldg., New Orleans, LA 70130. 

1221 Van Ness Ave., Fresno, CA 93717. 

1101 S. 3d St., Minneapolis, MN 55415. 

31 Taylor Ave., Bethel, CT 06801. 

Main 6 Williams Sts., Belleville, NJ 07109. 

341 E. Ohio St., Chicago, IL 60611. 

12-16 Congress St. Beverly, MA 01915. 

P. 0. Box 3, Vicksburg, MS 39180 

915 Midland Bank Bldg., Minneapolis, MN 55401. 

W. Wheat Rd., Vineland, NJ 08360. 

2555 Cumberland Pkwy. , Suite 200, Atlanta, GA 30339. 

3340 W. Norfolk Rd. , Portsmouth, VA 23703. 

Midland Bldg., Cleveland, OH 44115. 

12333 S. Van Ness Ave., Hawthorne, CA 90250. 

401 N. Michigan Ave., Chicago, IL 60611. 

P. 0. Box 545, Wichita, KS 67201. 

2526 Baldwin St., St. Louis, MO 63106. 
1900 W 47th PI., Suite 324, Westwood, KS 66204. 
11104 NW. Front Ave., Portland, OR 97231. 
Manor, PA 15665. 

P. 0. Box 5208, N. Charleston, SC 29406. 
118 5. Palmetto Ave., Marshfield, WI 54449. 
P. 0. Box 706, Worcester, MA 01613. 



SYNTHETIC ORGANIC CHEnlCALS, 197^) 

TABLE 1.— Synthetic organic chemicals; Alphabetical directory of manufacturers. 
BY company, 1974--Continued 



Identi- 
fication 
code 


Name of company 


Office address 


WHI 
WHL 

WHC 
APT 

WHW 
WLN 

wtc 

WAW 
WBC 
WYC 

wyt 








19 N. Railroad St., Myerstown, PA 17067. 

3540 Aero Ct., San Diego, CA 92123. 

3134 California St., NE., Minneapolis, MN 55418. 

62 Alford St., Boston, MA 02129. 

P. 0. Box 66, Wilmington, DE 19899. 

P. 0. Box 305, Paramus, NJ 07652. 

108 Spring St., Everett, MA. 02149. 

Halls Mills Rd., Freehold, NJ 07728. 

5 Greenwav Plaza East, Houston, TX 77046. 

P. 0. Box 831, Paoli, PA 19301. 


Whittaker Corp. : 


Whittaker Coatings 5 Chemicals 
Mol Rez Resins 






W. A. Wood Co 


Wycon Chemical Co 

Wyeth Laboratories, Inc., Wyeth Laboratories 
Div. of American Home Products Corp. 



253 

APPENDIX 

U.S. IMPORTS OF BENZENOID CHEMICALS AND PRODUCTS 

U.S. general imports of benzenoid chemicals and products entered under 
the Tariff Schedules of the United States (TSUS) , schedule 4, part 1, subparts 
B and C are analyzed by the U.S. International Trade Commission annually and 
published in detail in a separate report.^ General imports of benzenoid items 
entered in parts IB and IC totaled 589.5 million pounds with a foreign invoice 
value of $555.5 million in 1974 compared with 390.6 million pounds with a 
foreign invoice value of $300.0 million in 1973. 

Benzenoid products that are "competitive" with similar domestic products, 
because they accomplish results substantially equal to those accomplished by 
the similar domestic product when used in substantially the same manner, are 
subject to a special basis of valuation for customs purposes known as the 
"American selling price." If "noncompetitive," the benzenoid products are 
valued for customs purposes on the basis of the "United States value." The 
essential difference between these two values is that "American selling price" 
is based on the wholesale price in the United States of the "competitive" 
domestic product, whereas "United States value" is based on the wholesale price 
in the United States of the imported product less most of the expenses incurred 
in bringing the product to the United States and selling it. When neither of 
these two valuation bases applies, then the "export value," "foreign value," or 
"constructed value" is used as the valuation basis under section 402 or 402a 
Tariff Act of 1930, as amended. The competitive status of benzenoid imports in 
1973 is shown in table 2. 

Industrial organic chemicals that are entered under part IB consist chiefly 
of benzenoid intermediates and small quantities of acyclic compounds which are 
derived in whole or in part from benzenoid compounds. Also included are mixtures 
and small quantities of finished products not specially provided for in part IC 
(e.g., rubber-processing chemicals). In terms of value, 28.7 percent of all the 
benzenoid imports under part IB in 1974 came from West Germany; 26.3 percent, 
from Japan; 8.4 percent, from the United Kingdom; and 7.1 percent from Italy. 

Finished organic chemical products entered under part IC include dyes, 
pigments, medicinals, flavor and perfume materials, pesticides, plastics materials, 
and certain other specified products. In terms of value 23.3 percent of all 
finished benzenoid imports under part IC in 1974 came from West Germany; 20.0 
percent, from Japan; 16.2 percent, from the United Kingdom; and 12.4 percent from 
Switzerland. 



^ Imports of Benzenoid Chemicals and ProductSy 1974, TC Publication 762, 1976 
[processed] . 



SYrlTIIETIC ORGAiJIC CHErllCALS. 197'^ 

TABLE 2.--BENZEN0ID chemicals and products: Summary of U.S,' general imports entered under 
Schedule 'I, Parts IB and IC of the TSUS^ and analysis by competitive status^ 1974 



Part and competitive status 



Number 
of 
items 



Quantity 



Percent 
of total 
quantity 



Foreign 
invoice 
value 



Percent of 
foreign 
value 



Unit 
foreign 
value 



Competitive : 

Duty based on ASP^ 



Noncompetitive : 

Duty based on U.S. value — 
Duty based on export value- 



Competitive status not available- 



Schedule 4, Part IC 



Competitive: 

Duty based on ASP^ 



Noncompetitive: 

Duty based on U.S. value — 
Duty based on export value - 



Competitive status not available 

Summary (Schedule 4, Parts IB and IC) 
Total' 



Competitive: 

Duty based on ASP^ 



Noncompetitive : 

Duty based on U.S. value — 
Duty based on export value- 



Competitive status not available- 



260 
16a 



i.npo 

278 



1,350 

447 



1,000 
pounds 



17,57? 
23,148 



194.151 



32,486 
34,973 



50,065 
58,121 



45,656 



1,000 
dollars 



4.5 
5.P 



172,642 



25,185 
29,361 



4,024 



16.7 
18. n 



76,616 
65,637 



8.5 
9.9 



101,801 
94,998 



40,452 



12.7 
1.7 



23.6 
20.2 



18.3 
17.1 



Per 
pound 



' Detail may not add to total due to rounding. 
^ American selling price. 

Source; Compiled by the U.S. International Trade Commission from records of the U.S. Bureau of Customs. 

Note: --The totals shown in this table differ from those given in the official statistics of the U.S. Department 
of Commerce chiefly because of differences in coverage and in the methods used in compiling the data. In general, 
the statistical coverage in 1974 varies from a low of 82 percent for pigments to almost complete coverage of inter- 
mediates, flavors arid perfumes, and medicinals. 



APPENDIX 



TABLE 3.— Cyclic intermediates: Glossary of synonymous names 



Standard (Chemical Abstracts] na 



1,2, 4- Acid 

Acid yellow 9 

p-Aminobenzenesulfonic acid-- 

Amino G acid 

Amino_I acid 

Amino R salt 

Aniline oil 

Anthraflavic acid 

An thraruf in 

Benzal chloride 

Ben z an throne 

Benzotrichoride 

Bisphenol A 

B.O.N 

Bromobenzan throne 

Broenner's acid 

C acid 

Chlorobenzan throne 

Chromotropic acid 

Chrysazin 

2-Cyanopyridine 

3-Cyanopyridine 

Cyanuric chloride 

DADI 

DBB 

Decacyclene 

Developer Z 

o-Dianisidine 

l,l'-Dianthrimide 

Dibenzan throne 

4 ,4 ' -Dihydroxydiphenylsulfone 

Dimethyl POPOP 

4,5-Dinitrochr\'sazin 

Durene 

Fast Red G base 

Fast Scarlet R base 

G salt 

Gamma acid 

Gold salt 

H acid 

Hellimellitene 

J acid 

J acid urea 

Koch's acid 

MEP 

Mesitylene 

Methane base 

Michler's hydrol 

Michler's ketone 



4- Amino- 3-hydroxy-l-naph thai enesulfonic acid. 

6-Aniino-3,4 '-azodibenzenesulfonic acid. 

Sulfanilic acid and salt. 

7- Ami no- 1 ,5-naphthalenedi sulfonic acid. 

6- Amino- 1,3-naph thai enedisulfonic acid. 

3-Anino-2,7-naphthalenedisulfonic acid. 

Aniline. 

2,6-Dihydroxyanthraquinone . 

l,S-Dihydroxyanthraquinone. 

a,a-Dichlorotoluene. 
7H-Benz [de] anthracen-7-one . 
a,a,a,-Trichlorotoluene . 
4,4'-lsopropylidenediphenol . 
3-Hydroxy-2-naphthoic acid. 
3-Bromo-7H-benz[de]anthracene-7-one. 
6-Anino-2-naphthalenesulfonic acid. 

3- Anino- 1 ,5-naphthalenedisulfonic acid. 

Chloro-7H-benz[de]anthracen-7-one . 

4, 5 -Dihydroxy-2,7-naphthalenedi sulfonic acid. 

1 , 8-Dihydroxyanthraquinone . 

Picolinonitrile. 

Nicotinonitrile. 

2,4,6-Trichloro-s-triazine. 

Dianisidine diisocyanate. 

p-Dibutoxybenzene. 

Diacenaphtho[l,2-j ; 1 ,2'-J.]fluoranthene. 

3-Methyl- l-phenyl-2-pyrazolin-S-one . 

3,3' -Dimethoxybenzidine . 

1,1 '-Iminodianthraquinone. 

Violan throne. 

4 ,4'-Sulfonyldiphenol . 

1 ,4-Bis[2-C4-methyl-S-phenyloxazolyl)]benzene. 

l,8-Dihydroxy-4,5-dinitroanthraquinone. 

1 ,2 ,4 ,5-Tetramethylbenzene . 

2-Nitro-p-toluidine [NHj^l] . 
5-Nitro-o-anisidine [NH2=1]. 

7-Hydroxy-l,3-naphthalenedisulfonic acid. 
6-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodium 

salt. 
9,in-Dihydro-9,10-dioxo-l-anthracenesulfonic acid 

and salt. 
4 -Amino- 5 -hydroxy- 2, 7 -naphthal enedisulfonic acid. 
1 ,2 ,3-Trimethylbenzene. 

7-Amino-4-hydroxy-2-naphthalenesulfonic acid, sodium 

salt. 
7,7'-Ureylenebis [4-hydroxy-2-naphthalenesulfonic 

acid] . 

8-Amino-l ,3,6-napthalenetrisulfonic acid. 

S-Ethyl-2-picoline 

1,3,5-Trinethylbenzene. 

4,4 '-Hethylenebis[N,N-diraethylaniline] . 

4,4 '-Bis [dimethyl amino]benzhydrol . 

4 ,4 '-Bis [ di me thy 1 amino] ben zophen one . 



SYNTHETIC ORGANIC CHEMICALS. 1974 



TABLE 3,— Cyclic intermediates: Glossary of synonymous names--Continued 



Common name 



Naphthionic acid 

o-Naphthionic acid 

6-Naphthol 

Naphthol AS 

a-Naphthylamine 

Nevilles Winther's acid 

Pentaanthrimide 

Phenylbiphenyl 

N-Phenyldiethanol amine 

Phenyl J acid 

Phenyl peri acid 

POPOP 

Pseudocumene 

Pyrazoleanthrone 

Pyrazoleanthrone yellow — 
Pyrazolone T 

Quini zarin 

2-Quinizarinsulfonic acid- 

Quinoline yellow base 

R salt 

Schaffer's acid 

Silver salt 

Solvent Yellow 1 

Solvent Yellow 3 

o-Sulfobenzaldehyde 

Thiosalicylic acid 

Tobias acid 

TODI 

o-Tolidine 

a-Toluic acid 

a-Tolunitrile 

4-m-Tolylenedi amine 

Trimellitic anhydride 

Trimethyl base 

Trinitrophenol 

Vinyl toluene 



Standard (Chemical Abstracts) name 



4-Amino- 1-naphthalenesulfonic acid. 
1- Ami no -2 -naphthalene sulfonic acid. 
2-Naphthol, tech. 
3-Hydroxy-2-naphthani lide . 
1 -Naphthyl amine . 
4-Hydroxy-l-naphthalenesulfonic acid. 

l,4,S,8-Tetral;is(l-anthraquinonylamino)anthraquinone. 
Terphenyl. 

2,2'-[(Phenyl)imino]diethanol . 
7-Anilino-4-hydroxy-2-naphthalenesulfonic acid. 
8- Aniline- 1-naphthalenesulfonic acid. 
1 ,4-Bis [2- C5-phenyloxazolyl)] benzene. 
1 ,2 ,4-Trimethylbenzene . 
Anthra[l ,9 cd]pyrazol-6(2H)-Dne. 

[3,3'-Bianthra[l ,9-cd]pyrazole] -6 ,6 ' - (2H,2 'H)dione. 
5-0x0-1- (p-sulfophenyl) -2 -pyrazoline-3-carboxy lie 
acid. 

1 ,4-Dihydroxyanthraquinone . 
9,10-Dihydro-l,4-dihydrox>'-9,l'l-dioxo-2-anthracene- 

sulfonic acid. 
Quinophth alone. 

3-Hydroxy-2 ,7-naphthalenedisulfonic acid, disodium 
salt. 

6-Hydroxy-2-naphthalenesulfonic acid. 
9,10-Dihydro-9,10-dioxo-2-anthracenesulfonic acid 

and salt. 
p-Phenylazoaniline and hydrochloride. 
4- (o-Toly lazo) -o-toluidine . 
o-Formylbenzenesulfonic acid. 

o-Mercaptobenzoic acid. 

2- Amino- 1-naphthalenesulfonic acid. 

Bitolylene diisocyanate. 

3,3'-Dimethylbenzidine. 

Phenylacetic acid. 

Phenyl ace tonit rile. 

Toluene-2 ,4-di amine. 

1 ,2 ,4-Benzenetricarboxylic acid, 1 ,2-anhydride. 

l,3,3-Trimethyl-2-methyleneindoline. 

Picric acid. 

ar-Methylstyrene . 



■ U.S. GOVERNMENT PRINTINC OFFICE : 1976 O - 208-038 



Library Cataloging Data 

U.S„ International Trade Commission ^ 
Synthetic organic chemicals o 
United States production and sales, 
1974o [Washington, 1976] 

256 p„ 27 cm. annual. 
(USITC Pubo 776) 

I. Dyes and dyeing--U„S. 2, Coal-tar products, 
3o Tar. 4o Petroleum industry and trade--UoS,- 
Statistics. 5. Gas, Natural--U„S, --Statistics , 
6„ Color. 7„ Drugs. 8o Perfumes, Synthetic » 
9, Flavoring essences. 10 „ Elastomers. 

II. Plastics industry and trade--UoS. 
lo Title.