Skip to main content

Full text of "Synthetic organic chemicals"

See other formats


I.IH'. 

SYNTHETIC  ORGANIC  CHEMICALS 


BOSTON  PUBLIC  LIBRARY 


3  9999  06317  170  4 
United  States  Production 
and  Sales,  1990 


(Investigation  No.  332-135) 


"'^^">. 

^ 


m. 


*if 


JFEB  ^1992 


BOSTbN  Put-IC  LIBRARY 


USITC  PUBLICATION  2470 
DECEMBER  1991 


United  States  International  Trade  Commission 
Washington,  DC  20436 


UNITED  STATES  INTERNATIONAL  TRADE  COMMISSION 


COMMISSIONERS 

Anne  E.  Brunsdale,  Acting  Chairman 

Seeley  G.  Lodwick 

David  B.  Rohr 

Don  E.  Newquist 

Carol  T.  Crawford 

Janet  A.  Nuzum 


Office  of  Operations 
Charles  W.  Ervin,  Director 


Office  of  Industries 
Robert  A.  Rogowsky.  Director 


This  report  was  prepared  principally  by  Cynthia  B.  Foreso, 
Jesse  Lawrence  Johnson,  Dr.  Aimison  Jonnard,  Eric  Land, 
Edward  Matusik,  David  Michels,  Elizabeth  R.  Nesbilt,  James  Raftcry, 
Edward  J.  Taylor,  Cynthia  Trainor,  and  Steve  Wanser. 

Assistance  in  ihc  preparation  of  the  report  was  provided  by 

Kenneth  R.  Kozel,  Owen  L.  Bennett,  Brenda  Cairoli,  Elaine  T.  Freeman, 

Lemuel  Shields,  and  Darlene  Smith.  Data  Processing  was  provided  by 

Barbara  Bobbin,  James  Gill,  and  Marie  Jagannathan. 

Electronic  publishing  and  design  was  provided  by  Pamela  Chase, 

Keven  Blake,  Joyce  Bookman,  and  Pauleiic  Henderson. 


Address  all  coiiimunicatiuns  tu 

Kt  nneth  R.  Mason,  Secretary  to  the  Cominission 

United  States  International  Trade  Commission 

Washington,  DC  20436 


UNITED  STATES  INTERNATIONAL  TRADE  COMMISSION 


SYNTHETIC  ORGANIC  CHEMICALS 

United  States  Production  and  Sales,  1990 


USITC  Publication  2470 


Synthetic  Organic  Chemicals.  1990 

CONTENTS 

Page 

Introduction 1 

Summary  3 

General 5 

Sections 

1.  Coal  tar,  tar  crudes  and  pilches 1-1 

2.  Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion 2-1 

3      Cyclic  intermediates  3-1 

4.  Dyes 4-1 

5.  Organic  pigments   5-1 

6.  Medicinal  chemicals  6-1 

7.  Flavor  and  perfume  materials  7-1 

8.  Plastics  and  resin  materials 8-1 

9.  Rubber-processing  chemicals  9-1 

10.  Elastomers 10-1 

11.  Plasticizers 11-1 

12.  Surface-active  agents 12-1 

13.  Pesticides  and  related  products 13-1 

14.  Miscellaneous  end-use  chemicals  and  chemical  products 14-1 

15.  Miscellaneous  cyclic  and  acyclic  chemicals 15-1 

Appendixes 

A.  Directory  of  manufacturers A-1 

B.  Cyclic  intermediates:  Glossary  of  synonymous  names  B-1 

C.  Synthetic  Organic  Chemicals,  U.S.  production  and  sales, 

1990,  harmonized  system  basis C-1 

D.  Alphabetical  chemical  index D-1 


jymncuL  wrguniL  i^nerrucaii,  lyyu 


Introduction 

This  is  the  74th  annual  repon  of  the  U.S. 
International  Trade  Commission  on  domestic 
production  and  sales  of  synthetic  organic  chemicals 
and  the  raw  materials  from  which  they  are  made.  The 
report,  along  with  the  quarterly  report  titled 
Preliminary  Report  on  U.S.  Production  of  Selected 
Synthetic  Organic  Chemicals  (Including  Synthetic 
Plastics  and  Resin  Materials),  is  prepared  under 
investigation  No.  332-135,  Synthetic  Organic 
Chemicals  Reports.  This  investigation  is  conducted 
under  the  authority  of  section  332(g)  of  the  Tariff  Act 
of  1930  (19  U.S.C.  1322(g)).  for  the  purpose  of 
collecting  data  and  preparing  public  reports  on 
synthetic  organic  chemicals,  plastics  materials, 
medicinal  chemicals,  pesticides,  and  other  organic 
chemical  products.  The  annual  report  consists  of  15 
sections,  each  covering  a  specified  group  (based 
principally  on  use)  of  organic  chemicals  as  follows: 
Coal  tar,  tar  crudes  and  pitches;  primary  products  from 
petroleum  and  natural  gas  for  chemical  conversion; 
cyclic  iniermediates;  dyes;  organic  pigments;  medicinal 
chemicals;  flavor  and  perfume  materials;  plastics  and 
resin  materials;  rubber-processing  chemicals; 
elastomers;  plasticizers;  surface -active  agents; 
pesticides  aiKl  related  products;  miscellaneous  end-use 
chemicals  and  chemical  products;  and  miscellaneous 
cyclic  and  acyclic  chemicals.  Data  have  been  supplied 
by  approximately  670  producers. 

Each  of  the  15  sections  is  headed  by  a  summary  of 
the  statistical  data.  The  first  table  in  each  section  gives 
statistics  on  products  and  groups  of  products  in  as  great 
detail  as  is  possible  without  revealing  the  operations  of 
individual  producers.  Statistics  for  an  individual 
chemical  or  group  of  chemicals  are  given  only  when 
there  are  three  or  more  producers,  no  one  or  two  of 
which  may  be  predominant  Moreover,  even  when 
there  are  three  or  more  producers,  statistics  are  not 
given  if  there  is  any  possibility  that  their  publication 
would  violate  the  statutory  provisions  relating  to 
unlawful  disclosure  of  information  accepted  in 
confidence  by  the  Commission.' 

Data  are  reported  by  producers  for  only  those  items 
where  the  volume  of  production  or  sales  or  value  of 
sales  exceeds  certain  minimums.  Those  minimums  are 
450  kilograms  of  production  or  sales  or  $  1 ,0(X)  of  value 
of  sales  for  organic  pigments,  medicinal  chemicals, 
flavor  and  perfume  materials,  rubber-processing 
chemicals,  elastomers,  and  those  chemicals  whose 
end-use  is  not  readily  determinable;  2,250  kilograms  or 
$5,000  for  coal  tar,  tar  crudes  and  pitches,  primary 
products  from  petroleum  and  natural  gas  for  chemical 
conversion,  dyes,  plasticizers,  surface-actjve  agents, 
and  pesticides;  4,500  kilograms  or  510,000  for  cyclic 
intermediates  and  miscellaneous  cyclic  and  acyclic 
chemicals;  9,000  kilograms  or  520,000  for 
miscellaneous  end-use  chemicals  and  products;  and 
22,500  kilograms  for  550,000  for  plastics  materials. 
Data  are  usually  supplied  in  terms  of  undiluted 
materials;  however,  for  reporting  purposes,  products  of 
95  percent  or  greater  purity  are  considered  to  be 


'  18  use  w  1905  atxj  44  US  C  w  3508 


100  percent  pure.  Commercial  concentrations  are 
applicable  for  dyes,  certain  plastics  and  resins,  and  a  few 
solvents;  such  concentrations  are  specifically  noted. 

The  statistics  given  in  this  report  include  data  from 
all  known  domestic  producers  of  the  items  covered  and 
include  the  total  output  of  each  company's  plants,  i.e., 
the  quantities  produced  for  consumption  within  the 
producing  plant,  as  well  as  the  quantities  produced  for 
domestic  and  foreign  sale.  The  quantities  reported  as 
produced,  therefore,  generally  exceed  the  quantities 
reported  as  sold.  Some  of  these  differences,  however, 
are  attributable  to  changes  in  inventory. 

The  second  table  in  each  section  lists  all  items  for 
which  data  on  production  or  sales  have  been  reported, 
by  primary  manufacturers,  identified  by  manufacturers' 
codes.  Each  code  consists  of  not  more  than  three 
capital  leuers  and  is  assigned  on  a  permanent  basis. 

The  third  table  in  each  section  is  a  directory, 
alphabetized  by  the  codes  of  the  manufacturers 
reporting  in  that  section. 

Appendix  A  is  a  directory,  alphabetized  by  the 
names  of  the  manufacturers  reporting  in  all  sections 
and  which  includes  their  general  corporate  phone 
numbers  and  office  addresses. 

Appendix  B  lists  synonymous  names  for  cyclic 
iniermediates.  Information  on  synonymous  names  of 
the  organic  chemicals  included  in  this  repon  may  be 
found  in  the  SOCMA  Handbook:  Commercial  Organic 
Chemical  Names,  published  by  the  Chemical  Abstracts 
Service  of  the  American  Chemical  Society,  or  the 
Colour  Index  (Revised  Third  Edition),  published 
jointly  by  the  Society  of  Dyes  and  Colourists  and  the 
American  Association  of  Textile  Chemists  and 
Colorists. 

Appendix  C  presents  the  data  in  this  report 
aggregated  in  the  format  of  the  Harmonized  System 
(HS)  nomenclature  on  a  6-digit  HS  basis. 

Appendix  D  is  an  alphabetical  index  of  all  the 
products  in  this  edition  of  the  report. 

Data  contained  in  this  report  are  compiled 
primarily  from  Commissions  questionnaires  sent  to 
domestic  producers  and  represent  the  best  data 
available  to  the  Commission.  While  the  data  supplied 
in  the  questionnaires  are  checked  against  data 
previously  supplied  by  the  submitting  firm  and  with 
data  supplied  by  other  domestic  producers,  data  are  not 
independently  verified  by  direct  Commission 
examination  of  the  books  of  companies  furnishing 
information.  Data  contained  in  this  report  should  not 
be  used  for  investment  and  other  purposes  without 
independent  verification. 

As  specified  in  the  reporting  instructions  sent  to 
manufacturers,  production  and  sales  (unless  otherwise 
specified)  arc  defined  as  follows: 

Production  is  the  total  quantity  of  a  commodity  made 
available  by  Original  Manufacturers  Only  within 
the  customs  territory  of  the  United  States  (includes 
the  50  states,  the  District  of  Columbia,  and  Puerto 
Rico).  It  covers  synthetic  organic  chemicals, 
specified  crudes  from  petroleum  and  coal  tar,  and 
certain  chemically  described  natural  products,  such 
as,  alkaloids,  enzymes,  and  perfume  isolates.  It  is  the 
sum — expressed  in  terms  of  100  percent  active 
ingredient  unless  otherwise  specified  in  the  reporting 
instructions — of  the  quantities: 


Introduction 


Produced,  separated,  and  consumed  in  the  same 
plant  or  establishment.  A  Commodity  is 
considered  separated  either  when  it  is 
isolated  from  the  reactive  sytem  or  when  it 
is  not  isolated,  but  weighed,  analyzed,  or 
otherwise     measured.  This     includes 

by-products  and  co-products  that  are  not 
classifiable  as  waste  materials; 

Produced  and  not  isolated,  but  directly 
converted  to  a  fmished  or  semifinished  item 
not  included  in  this  report  (e.g.,  polyester 
film,  polyurethane  tires,  nylon  fiber,  bar 
soap,  etc.).  (See  specific  instructions  in 
individual  sections); 

Produced  and  transferred  to  other  plants  or 
establishments  of  the  same  firm  or 
1(X)  percent  owned  subsidiaries  or  affiliates; 

Produced  and  sold  to,  or  bartered  with,  other 
firms  (including  less  than  100  percent 
owned  subsidiaries); 

Produced  for  others  under  toll  agreements  (see 
general  instructions); 

Produced  and  held  in  stock. 

PRODUCTION  EXCLUDES: 

Purification  of  a  commodity,  which  is  purchased 
by,  or  transferred  from  within,  the  company, 
unless  inclusion  of  such  processing  is 
specifically  requested  in  the  reporting 
instructions  for  individual  sections; 

Intermediate  products  which  are  formed  in  the 
manufacturing  process,  but  are  not  isolated 
from  the  reaction  system — that  is,  not 
weighed,  analyzed,  or  otherwise  measured; 
except  such  products  as  described  above  as 


being  produced  and  not  isolated,  but  directly 
converted  lo  a  finished  or  semifinsihed  item. 


Materials  that  are  used  in  the  process  but 
which  are  recovered  for  re-use  or  sale; 

Waste  products  having  no  economic 
significance. 

SALES  are  actual  quantities  of  commodities  sold  by 
Original  Manufacturers  Only.  Sales  include  the 
quantity  and  value  of: 

Shipments  of  a  commodity  for  domestic  use  or 
for  export,  or  segregation  in  a  warehouse 
when  title  has  passed  to  the  purchaser  in  a 
bona  fide  sale; 

Shipments  of  a  commodity  produced  for  you  by 
others  under  toll  agreement; 

Shipments  to  subsidiary  or  affiliated  companies, 
provided  the  ownership  is  less  than  100 
percent. 

SALES  EXCLUDE: 

All  intra-company  transfers  within  a  corporate 
entity; 

All  shipments  to  100  percent  owned  subsidiary 
or  affiliated  companies; 

All  resales  of  imported  or  purchased  material, 
including  materials  obtained  by  barter. 

All  shipments  of  commodity  produced  for 
others  under  toll  agreements. 

VALUE  OF  SALES  is  the  net  dollar  receipts  of  sales 
f.o.b.  plant  or  warehouse,  or  delivered.  F.o.b.  values 
are  preferred,  but  if  they  are  not  readily  available  form 
your  records,  delivered  values  are  acceptable. 


Synthetic  Organic  Chemicals.  1990 


Summary 

Combined  production  of  all  synihetic  organic 
chemicals  and  primary  products  from  petroleum  and 
natural  gas  in  1990  was  179,546  million  kilog 
rams — an  increase  of  3.7  percent  from  the  output  in 
1989  (which  also  included  data  on  tars)  (table  1).  Sales 
of  these  materials  in  1990,  which  totaled  101,624 
million  kilograms,  valued  at  S93,092  million,  were  3.2 
percent  larger  than  in  1989  in  terms  of  quantity  and  3.2 
percent  less  in  terms  of  value.  These  figures  include 
data  on  production  and  sales  of  chemicals  measured  at 
several  successive  steps  in  the  manufacturing  process, 
and,  therefore,  they  necessarily  reflect  some 
duplication.  During  1986-90,  the  total  output  of  these 
products  rose  each  year  since  1986  (figure  1).  During 
that  period  the  output  of  these  products  generally 
followed  the  trend  of  the  Federal  Reserve  Board  Index 
of  U.S.  Production,  except  for  1989. 

In  1990,  production  of  all  synthetic  organic 
chemicals,  including  cyclic  intermediates  and  finished 
products  totaled   126,981   million  kilograms,  or  4.6 


percent  more  than  the  output  in  1989.  Eight  sections 
showed  an  increase  in  production  in  1990  over  1989. 
Surface-active  agents  (3,795  million  kilograms) 
increased  by  23.0  percent;  plastics  and  resin  materials 
(30,053  million  kilograms)  increased  by  11.3  percent; 
miscellaneous  end-use  chemicals  and  chemical 
products  (14,992  million  kilograms)  increased  by  11.0 
percent;  medicinal  chemicals  (144  million  kilograms) 
increased  by  10.8  percent;  elastomers  (synthetic 
rubber)  (2,233  million  kilograms)  increased  by  6.8 
percent;  organic  pigments  (53  million  kilograms) 
increased  by  4.4  percent;  miscellaneous  cyclic  and 
acyclic  chemicals  (49,912  milhon  kilograms)  increased 
by  2.1  percent;  rubber-processing  chemicals  (179 
million  kilograms)  increased  by  1.6  percent;  of  the 
remaining  sections,  dyes  (117  million  kilograms) 
showed  a  decreased  of  32.8  percent;  plasticizers  (891 
million  kilograms)  decreased  8.8  percent;  flavor  and 
perfumes  materials  (60  million  kilograms)  decreased 
6.8  percent;  cyclic  intermediates  (23,996  million 
kilograms)  decreased  3.1  percent;  pesticides  and 
related  products  (557  million  kilograms)  decreased  2.7 
percent  in  1990  from  that  in  1989. 


Table  1 

Synthetic  organic  chemical*  and  their  raw  material*:  U.S.productlon  and  *ale«,  1989  and  1990 

Sales 

Production  Quantity  Value 

Increase  Increase 

or  or 

Decrease  decrease 

(-).  1990  (■).  1990 

over  over 

Chemical  1989 1990 1989'  1989  1990  1969'  1989 

Million  Million  Million  Million  Million 

kilograms      kilograms      Percent      kilograms     kilograms     Percent      dollars 

Grand  total 172.977        179.546 3.7  98.382        101,624 32         96.071 

Tar  857  843  Ti  (2)  F)  (^)  W 

Pnmary  products  from 

petroleum 

and  natural  gas 50.742         51.722  19  27,834         26.914  -3  3  11.369 

Synthebc  organic  chemicals. 

totalV  121.378        126.981  4  6  70,548         74.710  58         84.702 

Cyclic  intermediates  24,756         23.996  -3  1  12,371  11.866  -4  1  10.284 

Dyes  174  117  -32  8  146  104  -28  7  858 

Organic  pigments  .  .  50  53  4  4  43  45  3  6  702 

Medianal  chemicals  130  144  108  204  107  -47  3  1,988 

Flavor  and  pertvjme 

matenals 64  60  -6  8  38  37  -5  0  1,005 

Plastics  and  resin 

matenals 26.995         30,053  113  23.819         25.729  80         32,180 

Rubber-processing 

chemicals     176  179  16  129  136  59  473 

Elastomer  (synthetic 

njbber)      2,091  2,233  68  1.395  1,555  115  2,872 

Plasnazers  976  891  -8  8  837  827  -12  1,046 

Surlace-active  agents  3.085  3,795  23  0  1,724  1.930  12  0  2.086 

Pesticides  and  related 

products  572  557  -2  7  461  442  -4  3  5.203 

Miscellaneous  end-use 

chemicals  and  chemical 

products  13.503  14.992  110  9.278  10.737  15  7  9.759 

Miscellaneous  cyclic 

and  acydic  chemicals  48.871  49.912  2  1  20.167         21.197  5  1  16.270 

'  Percentage  calculated  from  figures  rounded  to  thousands 

^  Not  available 

■•  Because  of  rounding,  figures  may  not  add  to  the  totals  shown 
Note  —Data  tor  1988  ■  1990  do  not  include  ethane,  propane,  and  butane  production 
Source    Compiled  from  data  received  in  response  to  questionnaires  of  the  US  Intemaoonal  Trade  Commission. 


Increase 


1990 


(-).  1990 

over 

1989' 


Million 

dollars     Percent 


93,092      -32 


(^)        (^) 


11,206      -14 


81,886 

10,981 

775 

717 

2,169 

-3.4 
68 
-96 
22 
9  1 

992 

-14 

30,529 

-5  1 

458 

-32 

3,128 

967 

2,193 

89 
-7.6 
5  1 

4,774 

-82 

9.711 

-0.5 

14,492 

-11.0 

Summary 

Figure  1-1 

Synthetic  organic  chemicals  and  their  raw  materials,  total  production,  vs  FRB  industrial 

production  Index 


r  120 


•100 


80 


60 


40 


•    20 


1986 


1987 


1988 


1989 


1990 


Source:  Production,  US.  International  Trade  Commission,  Synthetic  Organic  Chemicals:  United  States 
Production  and  Sales:  FRB  Industrial  Production  index.  The  Board  of  Governors  of  the  Federal  Reserve  System 


Syniheiic  Organic  Chemicals.  1990 


General 

In  this  report,  syniheiic  organic  chemicals  are 
classified  on  the  basis  of  iheir  principal  use  as  follows: 
Cyclic  intemiediaies,  dyes,  organic  pigments, 
medicinal  chemicals,  flavor  and  perfume  materials, 
plastics  and  resin  materials,  rubber-processing 
chemicals,  elastomers  (synthetic  rubber),  plasticizers, 
surface-active  agents,  pesticides  and  related  products, 
miscellaneous  end-use  chemicals  and  chemical 
products,  and  miscellaneous  cyclic  and  acyclic 
chemicals.  Most  of  ihese  groups  are  further  subdivided 
either  by  use  or  by  chemical  composition.  As 
intermediates,  chemicals  are  used  in  the  manufacture  of 
finished  products,  aggregate  figures  thai  cover  both 
intermediates  and  finished  products  necessarily  include 
considerable  duplication. 

Total  production  of  synthetic  organic  chemicals 
(intermediates  and  finished  products  combined)  in 
1990  was  126,981  million  kilograms,  or  4.6  percent 
more  than  the  output  of  121,378  million  kilograms 
reported  for  1989,  and  60.4  percent  more  than  the 
output  of  79,144  million  kilograms  reported  in  1977 
(see  table  2).    Sales  of  synthetic  organic  chemicals  in 


1990  amounted  to  74,710  million  kilograms,  valued  at 
S81,886  million,  compared  with  70,548  million 
kilograms,  valued  at  $84,702  million,  in  1989,  and 
44,378  million  kilograms,  valued  at  532,434  million,  in 
1977.  Production  of  all  cyclic  (ring  chemical  structure) 
products  (miermediaies  and  finished  products 
combined)  in  1990  totaled  38,823  million  kilograms,  or 
0.2  percent  less  than  the  38,895  million  kilograms 
reported  for  1989,  and  122.4  percent  more  than  the 
17,451  million  kilograms  reported  for  1977;  however, 
the  transfer  of  eight  items,  in  1979,  from  the  primary 
products  from  petroleum  and  natural  gas  section  to  the 
section  on  cyclic  intermediates  has  caused  the  output  of 
cyclic  products  to  appear  much  higher  in  relation  to 
1977  than  would  otherwise  have  resulted.  Production 
of  all  acyclic  (linear  or  branch  chemical  structure) 
products  in  1990  totaled  85,925  million  kilograms,  or 
6.8  percent  more  than  the  80,392  million  kilograms 
reported  for  1989,  and  45.4  percent  more  than  the 
59,057  million  kilograms  reported  for  1977. 
Differences  in  trends  between  cyclic  and  acylic 
products  reflect  the  aggregation  of  changes  in  usage  of 
individual  chemicals  rather  than  preferences  for  cyclic 
versus  acyclic  chemicals. 


Table  2 

Synthetic  organic  chemicals:  Summary  U.S.  production  and  sales  of  intermediates  and  finished  products, 

1977, 1989,  and  1990 

(Production  and  sales  in  thousands  ol  kilograms:  sales  value  in  thousands  ol  dollars) 


Increase  or  decrease  (-) 


Chemicals  1977^ 

Organic  chemicals,  cydlc  and 
acydlc,  total: 

Producton   79.144.460 

Sales    44.378.105 

Sales  value 32.434,301 

Cyclic,  total:' 

Production   17.451.083 

Sales   10.833.542 

Sales  value 13,410.029 

Acyclic,  total:' 

Production   59,056.510 

Sales   31,649,694 

Sales  value 17.084,012 

1.  Cyclic  Inlermadlatea 

Production    8,493,888 

Sales    3,622,331 

Sales  value 2,596,627 

2.  Dyes 

Production   119.917 

Sales    115.448 

Sates  value 689.992 

3.  Organic  Pigment* 

Production   31 .165 

Sates    26.052 

Sates  value    267.747 

4.  Medicinal  Chemicals 

Cydlc: 

Production   69.819 

Sates    37.914 

Sates  value 718.392 

Acvdic: 

Production   39.377 

Sates   35,743 

Sates  value 75,626 

See  lotenotes  at  end  ol  tabte. 


1990 


1990  over 
1977 


1990  over 
1989 


121,378.075 
70.548,189 
84,702,188 

126,980.989 
74,710.337 
81.885,632 

604 
68.3 
1524 

46 
58 
-34 

38,895.104 
23,577.601 
38.189.601 

38,823.382 
23.567.459 
37.221.177 

122  4 
1175 
177.5 

-02 
-01 
-26 

80.391,891 
45,575,686 
43,640,346 

85.924,531 
49,587,756 
41,536.592 

454 
566 
143  1 

6.8 
8.8 
-49 

24,755,837 
12,370,861 
10,283,993 

23.995.795 
11.865,617 
10.980,553 

1825 
2276 
3229 

-3.1 
-4  1 
68 

174,358 
145,757 
857.554 

117,135 
103.897 
775.352 

-23 
•100 
12  4 

-328 

-287 

-96 

50.360 
43.236 
701,552 

52.551 
44.773 
717.194 

686 
71  9 
1679 

44 
36 
22 

95,672 

153,166 

1,782,033 

119.726 

65,847 

1.867,993 

71  4 
73  6 
160  0 

25  1 

-57.1 

48 

34.654 

50,447 
205,486 

24,615 

41,400 

301,351 

-375 

158 

2985 

-290 

-17.9 
46.7 

General 


Table  2— Continued 

Synthetic  organic  chemicals:  Summary  U.S.  production  and  sales  of  intermediates  and  finished  products, 

1977, 1989, and  1990 

(Production  and  sales  in  thousands  of  kilograms;  sales  value  in  thousands  of  dollars) 


Chemicals 

1977' 

1989 

Increase  or  decrease  (■) 

1990  over 
1990                     1977 

1990  over 
1989 

5.  Flavors  and  Perfume  Materials 

Cydic; 

Production   

Sales    

26,514 
21.232 
134,628 

41,715 
27,559 
72.473 

4.899.932 
4,284,062 
4,275,111 

10.804.977 
9.232,677 
6,606.712 

38,097 

27.502 

908.457 

26,227 
10,918 
96,786 

8,017,658 
6,955,265 
13,065,234 

18.977,823 
16.864,135 
19.115.146 

155.035 
108.721 
429.565 

20.830 
20.125 
43.327 

2,091,080 
1,394,902 
2,872,241 

734,653 
634,202 
703,942 

241,738 
202,387 
341,585 

1,347168 
911,195 
743,088 

1,738.206 

812.840 

1.342,759 

365.900 

286.745 

3,639,436 

206,486 

174.427 
1,563,346 

39.514 

27867 

909,620 

20,417 

8,647 

81,992 

8,925.713 
7512.789 
12.394.918 

21.127193 
18.215.939 
18.134.437 

138.426 
104.280 
413.253 

40.181 
32.131 
44.399 

2.233.076 
1.555.122 
3.127863 

640,099 
644,104 
665,385 

250,619 
182,423 
301,132 

1,263.291 

1.018.716 

813.759 

2.531.363 

911.544 

1.379.089 

361.202 

280.112 

3,366.910 

195,673 

161,453 

1,407435 

49.0 

31.3 

575.7 

-51.1 
-68.6 
13.1 

82.1 
75.3 
189.9 

95.5 
97.2 
174.4 

-9.1 
13.7 
66.1 

90.6 
97.7 
53.1 

-15.4 
-17.9 
61.2 

0.3 

2.1 

40.1 

435 
450 
91  1 

<^ 
(*) 

0 

0 

^.0 
-10.7 
102.3 

-22  7 
-37.8 
230 

3.7 
1.3 
0.1 

Acydic: 

Production   

Sales    

-22.2 
-20.8 
-15.3 

6.  Plastics  and  Resin  Materials 

Cydic: 

Production   

Sales    

11.3 
8.0 
-5.2 

Acydic: 

Production   

Sales    

11.3 
8.0 
-5.2 

7.  Rubber-Processing  Chemicals 

Cydic: 
Sales    

152.204 
91.740 
248.756 

-10.8 
-4.1 
-3.8 

Acydic: 

Production    

Sales    

8.  Elastomers  (Synthetic  Rubber) 

Production   

Sales    

21.076 
16,254 
29.009 

2,636,867 
1,894.869 
1 ,940.260 

92.9 

59.7 

2.5 

6.7 
11.5 
8.9 

9.  Plastlcizers 

Cydic: 

Production   

Sales    

638.249 
630.645 
474.781 

-12.9 
1.6 
-5.5 

Acydic: 

Production   

Sales    

Sales  value 

10.  Surface-Active  Agents 

Cydic:' 
Production    

174,615 
125.784 
157549 

448.863 
212.933 

3.7 
-99 

-11.8 

-6.2 
11.8 

200.244 

9.5 

Production   

Sales    

1,691,285 
927,674 
674  778 

45.6 
12.1 
27 

11.  Pesticides  and  Related  Products 

Cydic 

Production   

Sales    

376,276 

313,520 

1 ,664,008 

-1.3 
-2.3 
-7.5 

Acydic 

253,099 

-5.2 

Sales                    

259,376 

-7.4 

1.144,265 

-100 

See  toter>otes  ai  end  ot  table 


Synthetic  Organic  Chemicals.  1990 


Tablo  2— Continued 

Synthetic  organic  chemicais:  Summary  U.S.  production  and  sales  of  intermediates  and  finished  products, 

1977, 1989,  and  1990 

(Production  and  sales  in  thousands  of  kilograms:  sales  value  in  thousands  of  dollars) 


Chemicals 


1977' 


1989 


Increase  or  decrease  (■) 


1990 


1990  over 
1977 


1990  over 
1989 


12.  MIscellaneou*  End-Use  Chemicalu 
nd  Chemical  Product 

Cydic: 

Production    1,252,527  1,592,471  1,469,599  17.3  -7.7 

Sales    1,004,105  1,205,851  1,126.028  12.1  -6.6 

Sales  value 1,479,800  3,606,757  2,831,664  91.4  -21.5 

Production    7,523,638  11.910,252  13,522,424  79.7  13.5 

Sales    3.919.801  8,072.193  9.610,721  145.2  19.1 

Sales  value 1,067.681  6,152.720  6.879.700  544.4  11.8 

13.  MIscellaneou*  Cyclic  and 
Acyclic  Chemical* 

Cydic: 

Production   941,729  1.567.895  1.700.331  80.5  8.4 

Sales    473,560  735,100  773,429  63.3  5.2 

Sales  value 659,943  1,467,990  1,484.576  124.9  1.1 

Acydic: 

Production 38.506.728  47.235.675  48,212,046  25.2  2.0 

Sales 17.104,826  19,368,214  20,423,498  19.4  5.4 

Sales  value 7,255,919  14,779,191  13,007,057  79.2  -12.0 

'  Standard  reference  t)ase  period  for  Federal  Government  general-purpose  index  numbers. 
^  Does  not  include  data  tor  elastomers 
''  Indudes  ligninsulfonates. 

*  The  data  for  1977  are  not  comparable  with  current  data  as  a  result  of  a  change  in  accounting  procedures. 
Source:  Compiled  from  data  received  In  response  to  questionnaires  of  the  U.S.  International  Trade  Commission 

The  following  labuiaiion  shows,  by  chemical  groups,  the  number  of  companies  that  reported  production  in  1990  of 
one  or  more  of  the  chemicals  included  in  each  group. 


Number  of 

Chemical  group  companies 

Cyclic  inlemiediales  163 

Dyes 33 

Organic  pigmeras    34 

Medicinal  diemicals 79 

Ravor  and  perfume  materials 29 

Plastics  and  resins  materials 237 

Rut>ber-processing  chemicals 21 


NunU>erof 

Chemical  group  companies 

Elasloniers  (synthetic  rubber) 28 

Plasiicizers 45 

Surface -active  agents    1 45 

Pesticides  and  related  produas 61 

Miscellaneous  end-use  chemicals  and 

chemicals  products   1 54 

Miscellaneous  cyclic  and  acyclic 

chemicals 234 


Synthetic  Organic  Chemicals.  1990 


Section  1 
Coal  Tar,  Tar  Crudes  and  Pitches 

Coal  tar  is  produced  chiefly  by  the  steel  industry  as 
a  by-product  of  the  manufacture  of  coke;  water-gas  tar 
and  oil-gas  tar  are  produced  by  the  fuel-gas  industry. 
Production  of  coal  tar,  therefore,  depends  on  the 
demand  for  steel;  production  of  water-gas  tar  and 
oil-gas  tar  reflects  the  consumption  of  manufactured 
gas  for  industrial  and  household  use.  Water-gas  and 
oil-gas  tars  have  properties  intermediate  between  those 
of  petroleum  asphalts  and  coal  tar.  Petroleum  asphalts 
are  not  usually  considered  to  be  raw  materials  for 
chemicals. 

The  U.S.  International  Trade  Commission  began 
collecting  data  on  crude  coal  tar  for  the  1986  reponing 
year.  In  1990,  U.S.  production  of  crude  coal  tar  was 
597  million  liters.  Production  of  crude  light  oil  was 
255  million  liters  in  1990. 

Tar  crudes  are  obtained  from  coke-oven  gas  and  by 
distilling  coal  tar,  water-gas  tar,  and  oil-gas  tar.  The 
most  important  tar  crudes  are  benzene,  toluene,  xylene, 
creosote  oil,  and  pitch  of  tar.   Some  of  these  products 


are  identical  with  those  obtained  from  petroleum.  Data 
for  materials  obtained  from  petroleum  are  included,  for 
the  most  part,  with  the  statistics  for  like  materials 
obtained  from  coke-oven  gas  and  tars,  and  are  shown  in 
table  1-1. 

The  domestic  production  by  coke-oven  operators  of 
industrial  and  specification  grades  of  benzene,  toluene 
and  xylene  cannot  be  published  since  to  do  so  would 
disclose  the  operations  of  individual  companies.  Some 
of  the  products  obtained  from  tar  and  included  in  the 
statistics  in  table  1  - 1  are  obtained  from  other  products 
for  which  data  are  also  included  in  the  table.  The 
statistics,  therefore,  involve  considerable  duplication, 
and  for  this  reason  no  group  totals  or  grand  totals  are 
given. 

Table  1-2  hsis  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 
1-3. 

Data  for  1990  tar  crudes  were  supplied  by  25 
companies  and  company  divisions. 

Cynthia  B.  Foreso 
202-205-3348 


Figure  1-1 

Crude  Coal  tar:  U.S.  production,  1986-90 

Millions 
of  liters 

800 


700 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


M 


Section  1 


Table  1-1 

Coal  tar,  tar  crudes,  and  pitches:  U.S.  production  and  sales,  1990 


Unit  of 


Coal  tar,  tar  crudes  ar)d  pitches 


Crude  coal  tar 

(coke-oven  operators)   1 .000  liters 

Crude  light  oil: 

(coke-oven  operators)  1 ,000  liters 

Light-oil  distillates: 

Benzene,  all  grades,  totaP 1 .000  liters 

Coke-oven  operators  1 .000  liters 

Petroleum  refiners   1,000  liters 

Toluene,  all  grades,  total* 1 .000  liters 

Coke-oven  operator 1 .000  liters 

Petroleum  refiners   1 ,000  liters 

Xylene,  all  grades,  total'    1 .000  liters 

Coke-oven  operators  1 .000  liters 

Petroleum  refiners   1 .000  liters 

Other  tar  distillates 1 .000  liters 

Crude  naphthalene    1 .000  liters 

(solidifying  at  76°C  to  less 
than  yg'C) 

Crude  tar  acid  oils    1 .000  liters 

(having  a  tar  acid  content 
of  5%  to  less  than  24%) 
Creosote  oil  (Dead  oil)  (100  percent 
aeosote  basis): 
Distillate  as  such  (100  percent 

creosote  basis) 1 .000  liters 

Creosote  in  coal  tar  solution 

(100  percent  solution  basis) 1 .000  liters 

Tar  and  tar  pitches: 

Pitch  of  tar  -  Hard 1 .000  metric 

tons 


Sales 

Average 
Unit 

Production 

Quantity 

Value 

value' 

1.000 

Dollars 

596.762 

481.843 

49,252 

$0.10 

254.902 

255.494 

45.440 

.18 

C) 

(') 

f) 

e) 

e) 

(') 

e) 

0 

6.421.078 

4.072,402 

1.596,254 

.39 

e) 

e) 

(') 

e) 

C) 

f) 

e) 

0 

3,248,838 

1.830,999 

557.575 

.30 

0 

e) 

C) 

{') 

e) 

e) 

C) 

e) 

3.083,285 

1 .440.573 

429,503 

.30 

415.598 

271.768 

44,356 

.16 

110,314 

(') 

{') 

C) 

8.726 


8,047 


2,145 


.27 


237,310 

145,952 

25,331 

.17 

59,248 

117,769 

16,880 

.14 

615 

652 

120.932 

185.50 

'  Unit  value  per  liter  or  metric  ton  as  specified. 

*  Includes  data  tor  material  produced  for  use  in  blending  motor  fuels.  The  annual  production  statistics  for 
petroleum  refiners  on  benzene,  toluene,  and  xylene  are  not  comparable  with  the  combined  monthly  production  figures 
because  of  fiscal  year  revisions. 

^  Statistics  cannot  be  published;  to  do  so  wouM  disclose  the  operations  of  individual  companies. 
Note. — Statistics  for  materials  produced  in  tar  and  petroleum  refineries  are  compiled  by  the  U.S.  International  Trade 
Commission.  Data  for  all  other  tars  and  tar  crudes  are  not  included  in  the  1990  report  tMcause  publication  would 
disck>se  the  operations  of  individual  companies. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


1-2 


Synthetic  Organic  Chemicals.  1990 

Table  1-2 

Coal  tar,  tar  crudes  and  pitches  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 
manufacturer,  1990 


Coal  tar,  tar  crudes  and  pitches 


Separate 
statistics ' 


Manufacturers' ider)tificatior)  codes 
(according  to  list  in  table  1-3) 


Light  oil,  light  oil  distillates,  and  tar  bases: 

Crude  coal  tar Yes 


Crude  light  oil Yes 


Light  oil  distillates: 
Benzene  (benzol): 

Tar  bases:  crude  bases  (Dry  basis)  No 

Toluene  (toluol): 

Toluene  (Toluol)  other  grades No 

All  other: 

All  other  light-oil  distillates   No 

Other  tar  distillates: 
Naphthalene,  crude: 

Methylnaphthaiene No 

Naphthalene,  crude,  solidifying  at  less  than  74°  C  . .     No 
Naphthalene,  crude,  solidifying  at  76°  C  to  less 

than  79°  C Yes 

Crude  tar  acid  oils: 
Crude  tar  acid  oils  having  a  tar  acid  content  of:  5 

percent  to  less  than  24  percent Yes 

Creosote  oil  (dead  oil): 
Creosote  oil  (Dead  oil):  creosote  content  in 

solution  (100  Percent  basis) No 

Creosote  oil  (Dead  oil):  creosote  in  coal  tar 

solution  <100  Percent  solution  basis)  Yes 

Creosote  oil  (Dead  oil):  distillate  as  such  (100 

Percent  creosote  basis)   Yes 

All  other  distillate  products: 

Crude  coal  tar  solvent No 

Priming  and  refractory  oil No 

All  other  tar  distillates No 

Tar  and  tar  pitches: 
Tar,  road: 

Tar,  road No 

Tar  for  other  uses: 

Tar  lor  other  uses:  crude    No 

Tar  tor  other  uses:  refined    No 

Pitch  of  tar: 

Pitch  of  tar:  hard  (MP  1 61°  F  and  Over) Yes 

Pitch  of  tar:  medium  (t^.P  110°  To  160°  F) fio 

Pitch  of  tar:  soft  (MP  80°  To  109°  F) No 

All  other: 
All  other  pitch  of  tar   No 


ABP,  ALS,  CGU,  DTR,  EKO,  GSS,  IL».  INL. 

KPT,  LTV,  NBC,  NTS,  SGO,  TWO,  USX. 

WPS. 
ABP,  ALS,  BTS,  CGU,  EKO,  GSS,  ILf,  INL, 

KPT,  LTV,  NBC,  NTS,  SGO.  TWD,  USX, 

WPS. 


KPT  USX. 
EEP 
LYP,  NTS. 


KPT 

BTS.  COP,  GSS. 

ACS,  ART  KPT 


ACS.  INL,  KPT  NTS. 

ey 

ACS,  ART  COP.  KPT  {% 

ACS,  ART  KPT  (^. 

KPT 

BTS,  KPT 
ACS,  GIV 

ACS,  {'). 

ALS, BTS. 

ACS,  COP  KPT  {')■ 

ACS,  COP,  KPT  (2). 
ART  C). 
ART  COP. 

WPS. 


'  Chemicals  for  which  separate  statistic^  are  reported  in  this  section  are  indicated  by  yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

'  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  d^ta  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


1-3 


Section  I 

Table  1-3 

Coal  tar,  tar  crudes  and  pitches:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  o1  company 

ILI   Acme  Steel  Corp. 

INL    Inland  Steel  Co. 

KPT Kopper  Industries 

LTV LTV  Steel  Co. 

LYP Lyondell  Petrochemical  Co. 

NBC    New  Boston  Coke  Corp. 

NTS National  Steel  Corp.,  Great  Lakes  Div. 

SGO Shenango,  Inc. 

TWD  Tonawanda  Coke  Corp. 

USX U.S.  Steel.  Div.  of  USX 

Chemical  Div. 

Gary  Works 

WPS Wheeling-Pittsburg  Steel  Corp. 


ABP Drummond  Co.  Inc. 

ACS Allied  Signal.  Inc..  Engineered  Materials 

Sector 

ALS  Armco,  Inc. 

ART Aristech  Chemical  Corp. 

BTS Bethlehem  Steel  Corp. 

CGU Citizen  Gas  And  Coke  Utility 

COP Coopers  Creek  Chemical  Corp. 

DTR Detroit  Coke  Corp. 

EEP Furon 

EKO Empire  Coke  Co. 

GIV   Givaudan  Corp. 

GSS Gulf  States  Steel 


Note.— Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S  International  Trade  Commission. 


1-4 


Section  2 

Primary  Products  from 

Petroleum  and  Natural  Gas  for 

Chemical  Conversion 

Primary  products  that  are  derived  from  petroleum 
and  natural  gas  are  related  to  the  intermediates  and 
finished  products  made  from  such  primary  materials  in 
much  the  same  way  that  crude  products  derived  from 
the  distillation  of  coal  tar'  are  related  to  their 
intermediates  and  finished  products.  Many  of  the 
primary  products  derived  from  petroleum  are  identical 
with  those  derived  from  coal  tar  (e.g.,  benzene,  toluene, 
and  mixed  xylenes).  Considerable  duplication  exists  in 
the  statistics  on  the  production  and  sales  of  primary 
petroleum  products  because  some  of  these  primary 
chemicals  are  converted  to  other  primary  products 
derived  from  petroleum  and  because  data  on  some 
production  and  sales  are  reported  at  successive  stages 
in  the  conversion  process.  The  statistics  are 
sufficiently  accurate,  however,  to  indicate  trends  in  the 
industry.  Many  of  the  primary  products  for  which  data 
are  included  in  the  statistics  may  be  used  either  as  fuel 
or  as  basic  materials  from  which  other  chemicals  are 
derived.  In  this  report  every  effort  has  been  made  to 
exclude  data  on  materials  that  are  used  as  fuel; 
however,  data  are  included  on  toluene  and  mixed 
xylenes,  which  are  used  in  blending  aviation  and  motor 
fuel. 


'  Staiisiics  on  chemicals  from  coal  tar  are  given  in  Section  1 
(Tar  and  Tar  Crudes)  of  this  report. 


Synthetic  Organic  Chemicals.  1990 

The  total  production  of  primary  products  derived 
from  petroleum  and  natural  gas  during  1986-90  is 
shown  in  figure  2-1.  Beginning  in  1988,  production 
and  sales  data  no  longer  are  collected  for  ethane, 
propane,  and  butane.  Total  production  for  primary 
products  during  1990  amounted  to  51,722  million 
kilograms. 

The  output  of  aromatic  and  naphihenic  products 
from  petroleum  amounted  to  12,974  million  kilograms 
in  1990,  compared  with  12,628  million  kilograms  in 
1989.  Sales  amounted  to  S2,889  miUion  in  1990  and 
S2,635  million  in  1989.  In  1990,  producuon  of 
benzene  was  5,644  million  kilograms;  production  of 
toluene  was  2,816  million  kilograms;  and  production  of 
mixed  xylenes  was  2,816  million  kilograms  (table  2-1). 

Production  of  all  aliphatic  hydrocarbons  and 
derivatives  from  petroleum  and  natural  gas  was  38,749 
million  kilograms  in  1990.  Sales  of  these  products 
were  valued  at  $8317  million.  Production  of  ethylene 
was  16,541  million  kilograms  in  1990.  The  output  of 
1 ,3-butadiene  was  1,401  million  kilograms  and 
propylene  production  was  9,909  million  kilograms 
during  1990  (table  2-1). 

Table  2-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code.  The 
codes  are  identified  by  company  name  in  table  2-3. 

Data  for  1990  primary  products  from  petroleum 
and  natural  gas  for  chemical  conversion  were  supphed 
by  64  companies  or  company  divisions. 

James  Rafiery 
202-205-3365 


Figure  2-1 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion  U.S.  production, 

1986-90 


Billions 
ol  kilograms 
60  


1986 


1987 


1988 


1989 


1990 


Note. — Data  for  1988-90  do  not  include  ethane,  propane,  and  butane  production. 

Source;  Compiled  from  data  received  in  response  to  questionnaires  ol  the  US  International  Trade  Commision. 


2-1 


Section  2 


Table  2-1 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion:  U.S.  production  and  sales,  1990 


Primary  products  from  petroleum  arid  natural 
gas  for  cfiemical  conversion 


Grand  total 

Aromatics  and  naphthenes^ 

Total  

Benzene,  all  grades    

Toluene,  all  grades-** 

Xylenes,  mixed    

All  other  aromatics  and  naphthenes* 

Aliphatic  hydrocarbons 

Total   

Cz  Hydrocarbons,  total^ 

Acetylene^  (For  chemical  use  only) 

Ethylene 

C3  Hydrocarbons,  total* 

Propylene' 

Ci  Hydrocarbons,  total'"  

Butadiene  and  butylene  fractions 

1,3-Butadiene,  grade  for  rubber  (elastomers) 

1-Butene    

Isobutane 

Isobutylene 

All  other  C4  hydrocarbons" 

C5  Hydrocartwns,  total 

Isoprene  {2-Methyl-1 ,3-butadiene) 

Pentenes,  mixed    

Piperylene  (1 ,3-Pentadiene)    

All  other  C5  hydrocarbons'^  "   

All  other  aliphatic  hydrocart)ons,  derivatives, 
and  mixtures,  total    

Alpha  olefins,  Ce-Cio    

Alpha  olefins,  d,  and  higher 

Dodecene  (Tetrapropylene) 

Hexane  

n-Heptane    

Nonene  (Tripropylene) 

n-Paraffins" 

Another'^ 

See  footnotes  at  end  of  table. 


Sales 


Production 


Quantity 


Value 


1.000 
kilograms 

51,722,325 


12,973.769 


1.000 
kilograms 


1,000 
dollars 


7,750,486        2,889.296 


Average 

Unit 

value' 


Per 

kilogram 


26,914.110       11.206,171       $0.42 


.37 


5.644,128 

3.579.641 

1,596.254 

.45 

2.816,418 

1.587.293 

557,575 

.35 

2,815,656 

1.315.531 

429,503 

.33 

1,697,567 

1,268.021 

305,964 

.24 

38,748,556 

19.163.624 

8,316,875 

.43 

16.668.909 

7.636,120 

3,740,745 

.49 

127,568 

59,473 

49.633 

.83 

16.541,341 

7.576.647 

3.691.112 

.49 

9,909.380 

5.576.191 

2.037,468 

.37 

9.909.380 

5.576.191 

2,037,468 

.37 

6.003.903 

3.454.932 

1 ,327,042 

.38 

942.991 

615,034 

153,719 

.25 

1.400.905 

1 ,347,094 

768,558 

.57 

297.896 

162,428 

69,274 

.43 

551.077 

407,545 

93,689 

.23 

549.733 

137,801 

62,177 

.45 

2.261.301 

785,030 

179,625 

.23 

1.185.396 

397,870 

134,655 

.34 

191.856 

135,815 

47,914 

.35 

104,265 

0 

n 

n 

42,566 

0 

C) 

n 

846.709 

262,055 

86,741 

.33 

4.980,968 

2.098.511 

1.076,965 

.51 

470,862 

217,763 

185.073 

.85 

354,794 

197,251 

163.249 

.83 

173.343 

132,120 

59,742 

.45 

258.855 

268,516 

74,415 

.28 

71.977 

74,671 

27,893 

.37 

241,308 

127,466 

50,384 

.40 

801,628 

575,321 

190,277 

.33 

2,608,201 

505,403 

325,932 

.64 

2-2 


Synthetic  Organic  Chemicals.  1990 

Table  2-1 — Continued 

Primary  products  from  petroleum  and  natural  gas  for  cliemlcal  conversion:  U.S.  production  and  sales,  1990 

'  Calculated  from  rounded  figures. 

^  The  chemical  raw  materials  designated  as  aromatics  are  in  some  cases  identical  with  those  obtained  from  the 
distillation  of  coal  tar;  however,  the  statistics  given  in  the  table  above  relate  only  to  such  materials  as  are  derived  from 
petroleum  and  natural  gas.  Statistics  on  production  and/or  sales  of  benzene,  toluene,  and  xylene  from  all  sources  are 
given  in  table  1-1  of  the  report  on  "Coal  tar,  tar  crudes  and  pitches." 

^  Includes  toluene,  solvent  grade,  90  percent. 

*  Includes  toluene  and  xylene  used  as  solvents;  may  include  that  which  is  blended  in  aviation  and  motor  gasolines. 

*  Includes  data  for  alkyl  aromatics,  crude  cresylic  add,  cydopentane.  naphthalene,  naphthenic  acid,  carbon  black 
feedstock,  distillates,  solvents  and  miscellaneous  cyclic  hydrocarbons. 

*  Ethane  production  and  sales  data  are  no  bnger  collected. 

'  Production  figures  on  acetylene  from  cateium  carbide  for  chemical  synthesis  are  collected  by  the  U.S.  Bureau  of 
the  Census. 

^  Propane  production  and  sales  data  are  no  longer  collected. 

*  Includes  data  for  refinery  propylene. 

'°  Butane  production  and  sales  data  are  no  longer  collected. 

"  Includes  produdion  and/or  sales  data  for  2-butene,  mixtures  of  1  -butene  and  2-butene,  and  mixed  C4  streams. 

^^  Reported  data  are  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

'^  Includes  data  for  mixtures  of  C5  hydrocarbons,  isopentane,  n-pentane,  1  -pentene,  and  2-pentene. 

^*  Includes  sales  data  for  mixed  pentenes  and  piperylene. 

'*  Includes  data  for  the  following  chain  lengths:  Cg-Cg,  C9-C15,  Cio-Cu.  C,o-Ci6.  C,2-Ci8  and  others. 

^^  Includes  production  and/or  sales  data  for.  methane,  isoheptanes,  isohexane,  iso-octane,  neohexane, 
methyk:yck}pentadiene,  mixed  hexenes,  mixed  heptenes,  mixed  octenes,  n-octane.  di-isobutylene,  eicosane.  mixtures 
of  Cj  and  C3.  Cs-Cg.  C5-C7.  Cg-C?  hydrocarbons,  hydrocartwn  derivatives,  and  other  hydrocartwns. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


2-3 


Section  2 

Table  2-2 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production  and/or 
sales  were  reported,  identified  by  manufacturer,  1990 


Primary  products  from  petroleum  and  natural 
gas  for  chemical  conversion 


Separata 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  2-3) 


Production  and  sales  of  aromatics  and  naphthenes: 

All<yl  aromatics: 

Cyclosols   No 

All  other  all<yl  aromatics No 

Benzene  total: 
Benzene  High  purity  (98-100%)    No 

Benzene  Other    No 

Cresylic  acid  (Less  than  75  percent  distilling  over 

215°  C) No 

Cyclopentane No 

Naphthalene   No 

Naphthenic  acid: 

fslaphthenic  acid,  acid  number  150-199 No 

Naphthenic  acid,  acid  number  200-224 No 

Naphthenic  acid,  acid  number  less  than  150 No 

Toluene  total: 

Toluene  High  purity  (98-100%) No 

Toluene  Other No 

Xylenes,  mixed,  total: 
Xylene  High  purity  (98-100%) No 

Xylene  Other No 

All  other  aromatics  and  naphthenes: 

Benzene,  toluene,  xylene,  mixtures No 

Carbon  black  feedstock No 

All  other  products  from  petroleum  and  natural  gas, 

cyclic No 


Production  and  sales  of  aliphatic  hydrocartwns: 

Ci  hydrocarbons: 
Methane No 

Ca  hydrocarbons: 

Acetylene  (For  chemical  use  only) Yes 

Ethylene Yes 


Cs  hydrocarbons: 
Hydrocartxjns,  Cz-Cs  mixtures 
Propylene 


No 
Yes 


C4  hydrocarbons: 

Butadiene  and  butylene  fractions Yes 

1 ,3-Butadlene,  grade  for  rubber  (Elastomers)  Yes 

1  -Butane Yes 

2-Butene No 

1  -Bulene  and  2-butene,  mixed No 

Hydrocartx5ns,  C4  fraction    No 

Hydrocartxjns,  C4  mixtures No 

Isobutane  (2-fw1ethylpropane) Yes 

Isobutylene  (2-Methylpropene) Yes 

All  other  hydrocartxans,  C4 No 


CXI. 
SHC. 

AMO,  ASH,  CGO,  CNE,  CSD,  CSP,  DOW, 
ENJ,  GRS,  HES,  KHI,  LYP,  MOC,  PLC, 
PPR,  SHC.  810,  SM,  SOC,  SOG,  SUN, 
SWR,  TX,  UOC,  USI. 

ATR,  DUP,  KLM,  VST 

KHI.  PSG. 

PLC. 

CXI.TX. 

CPS,  HEC,  MER. 

MER. 

HEC,  SHC. 

ASH,  CNE,  CSD.  ENJ,  GRS,  HES,  KHI, 
LYP.  MOC.  PLC,  PPR,  PPX,  SC,  SHC, 
SIO,  SM,  SOC,  SOG,  SUN.  SWR.  TX, 
UOC. 

GE.  LYP 

AMO,  ASH,  CSD,  CSR  ENJ,  HES.  PLC, 

PPR,  SHC,  SOG,  SUN,  SWR,  UOC. 
AMO,  MOC. 

ATR,  ELP 
ENJ. 

AMO,  ASH,  BAS,  BFG,  CSD,  EKX,  ELP, 
ENJ,  LYP,  OMC,  SHC,  SOG,  TX,  UCC, 
UPM,  UTP  VST 


SHO. 

BCP  RH  UCC 

AMO,  BAS,  BFG,  CNE,  DOW,  EKX,  ELP. 
ENJ.  GE,  KHI,  LYP  OMC,  PLC,  SHC, 
SM,  SOC,  SUN,  TX,  UCC,  USI.  UTP. 
VST 

CGO. 

AMO,  ASH,  BAS.  BFG.  CCP  CGO.  CLK. 

CNE.  CSD.  DA,  DOW,  DUP,  EKX,  ELP. 

ENJ.  EPC,  KHI,  LYP  MOC,  PLC,  SHC. 

SIO.  SM.  SOC,  SOG,  SUN,  TX,  UCC, 

USI,  UTP  VLR,  VST 

BAS,  CNE,  DA,  DOW,  EKX,  ELP  PLC. 

SOC.  TX,  UCC,  USI,  UTP,  VST 
AMO,  CNE,  ENJ.  LYP.  SHC,  SM,  TPC,  TX. 

ENJ,  SHC,  SM,  SOC,  TNA,  TPC. 

TPC. 

LYP  SHC. 

TX. 

LYP  PPR,  SOG. 

AMO,  CSP  DA.  ENJ,  MOC,  PLC.  SHO, 

SUN,  TX. 
AMO,  ATR,  ENJ,  SHC,  TPC,  TX. 
GE,  TNA,  TX. 


See  footnotes  at  end  of  table. 


2-4 


Synthetic  Organic  Chemicals.  1990 

Table  2-2 — Continued 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production  and/or 

sales  were  reported,  identified  by  manufacturer,  1990 


Primary  products  from  petroleum  and  natural 
gas  for  chemical  conversion 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  2-3) 


Production  and  sales  of  aliphatic  hydrocarbons- 
Continued 

Cj  hydrocarbons: 

Amylenes  No 

Hydrocartx)ns,  Cj  mixtures No 

isopentane  (2-Methyibutane) No 

Isoprene  (2-Methyl-1 .3-butadiene) Yes 

n-Pentane No 

1  -Pentene No 

2-Pentene No 

Pentenes,  mixed Yes 

Piperylene  (1 ,3-Pentadiene) Yes 

All  otiner  Cj  hydrocarbons No 

All  other  aliphatic  hydrocarbons,  derivatives,  and 
mixtures,  total: 

Cg  hydrocarbons: 

Hexane Yes 

1  -Hexene  No 

Hexenes,  mixed  No 

Hydrocartxjns,  Cs-Cs  mixtures No 

isohexane No 

Methylcyciopentadiene No 

Neohexane  (2,2-Dimethylbutane) No 

Ail  other  hydrocarbons,  Cs No 

C7  hydrocarbons: 

n-Heptane Yes 

Heptenes,  mixed    No 

Isoheptanes  No 

All  other  hydrocartxjns,  C7 No 

Cg  hydrocarljons: 

Di-isobutyiene  (Di-isobutene) No 

n-Octane No 

Octenes,  mixed    No 

2,2,4-Trimethylpentane  (Iso-octane)    No 

All  other  hydrocarbons,  0$ No 

C9  and  above  hydrocarbons  (except  alpha  olefins): 

Dodecene Ye« 

Nonene  (Tripropylene) Yes 

Alpha  olefins: 

Alpha  olefins.  Ce-Cio    Yes 

Alpha  olefins,  C,,  and  higher  Yes 

N-paraffins  -  carbon  chain  length: 

n-Paraffins,  C,o-C,4    No 

n-Paraffins,  Cio-C,6    No 

n-Paraffins,  Ci2-C,8    No 

n-Paraffins,  Cs-Cis No 

n-Paraffins,  Cs-Cg No 

n-Paraffins,  C9-C15 No 

n-Paraffins,  other  No 

Polybutene No 

Hyarocartxjn  derivatives: 

n-Butyl  mGrcaptan(l-Butanethiol) No 

sec-Butyl  mercaptan  (2-Butanethioi)   No 

ten-Butyl  mercaptan  (2-Methyl-2-propanethiol) No 

Decyl  mercaptans No 

Di-ten-butyl  disulfide No 

Diethyl  sunide  (Ethyl  sulfide)    No 

Dimethyl  sulfide    No 

Ethyl  mercaptan  (Ethanethlol)    No 

Isopropyl  mercaptan  (2-Propanethiol)    No 


ENJ. 

ONE,  LYR 

PLC  SHO 

DOW,  ENJ,  GYR,  LYP,  SHC,  SOC. 

PLC,  SHO. 

DOW. 

BFG. 

CSP,  CXI,  PLC,  SHO.  TX. 

CXI,  ENJ,  LYP. 

DOW,  ENJ.  SHC. 


ATR.  ENJ.  PLC.  SOG,  TX.  UOC. 

PLC.  (2). 

ENJ. 

PLC. 

PLC. 

ENJ. 

PLC. 

DA.  PLC.  SHC,  SM,  TNA. 

ENJ,  PLC,  SOG.  TX.  UOC. 
ENJ,  TX. 
PLC. 
EKX.  SHC. 

EKT.  TPC.  (2). 
SOG. 
ENJ. 

LYP,  PLC. 
SHC.  TX. 

ATR.  CSP.  ENJ.  SOC,  SUN. 
ATR,  CSP.  ENJ.  SOC.  TX. 

SHC.  SOC,  TNA. 
SHC.  SOC,  TNA. 

SHC,  UOC. 

VST 

VST 

ENJ. 

SOG.  UOC. 

ENJ,  SOG,  TX,  UOC. 

ENJ.  SOG,  UOC. 

AMO,  BUC. 

PAS,  PLC. 
HAP,  PLC. 
HAP  PAS.  PLC. 
PAS. 
PLC. 

HAP  PAS. 
GAY.  PAS. 
HAP,  PAS.  PLC. 
HAP.  PAS,  PLC. 


See  footnotes  at  end  of  table. 


2-5 


Section  2 

Table  2-2— Continued 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion  for  which  U.S.  production  and/or 
sales  were  reported,  Identified  by  manufacturer,  1990 

Primary  products  from  petroleum  and  riatural  Separate         Manufacturers '  identification  codes 

gas  for  chemical  conversion  statistics '         (according  to  list  in  table  2-3) 

All  other  aliphatic  hydrocarbons,  derivatives,  and 
mixtures,  total-Continued 

Hydrocarbon  derivatives-Continued 

Methyl  ethyl  sulfide No  CED,  HAP.  PAS. 

Methyl  mercaptan  (Methanethiol) No  PAS. 

n-Propyl  mercaptan  (1  -Propanethiol) No  PAS.  PLC. 

Thiopnane  (Tetrahydrothiophene) No  HAP. 

All  other  hydrocartion  derivatives:  hydrocartx>n 

derivatives No  EKX.  PAS.  PLC.  SHC.  TNA. 

All  other  hydrocarbons,  Co  and  above,  including 

mixtures  No  ENJ.  PLC.  SOC.  TNA. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


2-6 


Synthetic  Organic  Chemicals.  1990 

Table  2-3 

Primary  products  from  petroleum  and  natural  gas  for  chemical  conversion:  Directory  of  manufacturers, 

alphabetical  by  code,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


AMO 

Amoco  Corp 

ASH 

Ashland  Oil.  Inc.,  Ashland  Petroleum 

Co. 

ATR 

Atlantic  Richfield  Co.,  Arco  Chemical 

Co. 

BAS 

BASF  Corp. 

BCP 

Borden  Chemical  &  Plastics  Delaware 

Limited 

BFG 

B.  F  Goodrich  Co.,  B.  F  Goodrich 

Chemical  Group 

BUC 

Synalloy  Corp.,  Blackman  Uhler 

Chemical  Div. 

CCP 

Crown  Central  Petroleum  Corp. 

CED 

Cedar  Chemical  Co. 

CGO 

Citgo  Petroleum  Corp. 

CLK 

Clark  Oil  &  Refining  Corp. 

CNE 

Oxy  Petrochemicals,  Inc. 

CPS 

CPS  Chemical  Co.,  Inc. 

CSD 

Fina  Oil  &  Chemical  Co., 

Cosden  Chemical  Div. 

CSP 

Coastal  Refining  &  Marketing,  Inc. 

CXI 

Chemical  Exchange  Industries,  Inc. 

DA 

Diamond  Shamrock  Refining  & 

Marketing 

DOW 

Dow  Chemical  Co. 

DUP 

E.  1.  duPont  de  Nemours  &  Co.,  Inc. 

Eastman  Kodak  Co.: 

EKT 

Tennessee  Eastman  Co.  Div. 

EKX 

Texas  Eastman  Co.  Div. 

ELP 

Rexene  Products  Company 

ENJ 

Exxon  Chemical  Americas 

EPC 

EPC  Partners,  Ltd. 

GAY 

Gaylord  Chemical  Corp. 

GE 

General  Electric,  Specialty  Chemical 

Group 

GRS 

Champlin  Refining  Co. 

GYP 

Goodyear  Tire  &  Rubber  Co. 

HAP 

Helmerich  &  Payne  Inc.,  Natural  Gas 

Odorizing.  Inc 

HEC 

Hewchem 

HES 

Amerada  Hess  Corp.  (Hess  Oil  Virgin 

Islands  Corp.) 

KHI 

Koch  Refining  Co. 

KLM 

Kalama  Chemical,  Inc. 

LYP 

Lyondell  Petrochemical  Co. 

MER 

Merichem  Co. 

MOC 

Marathon  Petroleum  Co.,  Texas 

Refining  Div. 

CMC 

Olin  Corp. 

PAS 

Atochem  North  America,  Inc. 

PLC 

Phillips  66  Co. 

RPR 

Phillips  Puerto  Rico  Core,  Inc, 

PPX 

Phillips  Paraxylene,  Inc. 

PSG 

PMC,  Inc.,  Specialities  Group,  Inc. 

RH 

Rohm  &  Haas  Co. 

SC 

Sterling  Chemicals,  Inc. 

SHC 

Shell  Chemical  Co. 

SHO 

Shell  Oil  Co. 

SIO 

BP  Oil  Company 

SM 

Mobil  Oil  Corp.: 

Gas  Liquids  Dept. 

Petrochemicals  Div. 

SOC 

Chevron  Corp.,  Chevron  Chemical  Co. 

SOG 

Hill  Petroleum  Co. 

SUN 

Sun  Company,  Inc. 

SWR 

Southwestern  Refining  Co.,  Inc. 

TNA 

Ethyl  Corp. 

IPC 

Texas  Petrochemicals  Corp. 

TX 

Texaco  Chemical  Co. 

UCC 

Union  Carbide  Corp.,  Industrial 

Chemical  Div. 

UOC 

Union  Oil  Co.  of  California 

UPM 

UOP  Inc. 

USI 

Quatum  Chemical  Corp.,  USI  Div. 

UTP 

Union  Texas  Product  Corp. 

VLR 

Valero  Refining  Co.  &  MarKetimg  Co. 

VST 

Vista  Chemical  Co. 

Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission 


2-7 


Synthetic  Organic  Chemicals.  1990 


Section  3 
Cyclic  Intermediates 

Cyclic  intermediates  are  synthetic  organic 
chemicals  derived  principally  from  petroleum  and 
natural  gas  and  from  coal-tar  crudes  produced  by 
destructive  distillation  (pyrolysis)  of  coal.  Most  cyclic 
intermediates  are  used  in  the  manufacture  of  more 
advanced  synthetic  organic  chemicals  and  finished 
products,  such  as  dyes,  medicinal  chemicals, 
elastomers  (synthetic  rubber),  pesticides,  and  plastics 
and  resin  materials.  Some  intermediates,  however,  are 
sold  as  end  products  without  further  processing.  For 
example,  ethylbenzene  may  be  used  as  a  raw  material 
in  the  manufacture  of  sfyrene.  In  1990,  about  46 
percent  of  the  total  output  of  cyclic  iniennediates  was 
sold:  the  rest  was  const^med  chiefly  in  the  producing 
plants  in  the  manufacture  of  more  advanced 
intermediates  and  finished  products. 

The  total  annual  production  of  cyclic  intermediates 
during  1986-90  is  shown  in  figure  3-1.  Total 
production  of  cyclic  intermediates  in  1990  amounted  to 
23.996  million  kilograms,  a  decrease  of  3  percent 
compared  with  production  reported  to  the  Commission 
in    1989.      Reported    sales   of  cyclic    intermediate 


chemicals  in  1990  were  11,866  million  kilograms, 
valued  at  S10,981  million,  compared  with  12,371 
million  kilograms,  valued  at  510,284  million,  in  1989. 

Intermediates  that  were  produced  in  excess  of  500 
million  kilograms  in  1990  were  ethylbenzene  (3.796 
million  kilograms),  styrene  (3,636  million 
kilogTams).terephthalic  acid  and  terephthalic  acid 
dimethyl  ester  (3.526  million  kilograms),  p-xylene 
(2,359  million  kilograms),  cumene  (1,955  million 
kilograms),  phenol  (1.604  million  kilograrns), 
cyclohexane  (1,116  million  kilograms),  and  bisphenol 
A  (521  million  kilograms),  polymethylene 
polyphenylisocyanate  (5(X).46I  million  kilograms). 
Intermediate  chemicals  produced  in  excess  of  1  billion 
kilograms  accounted  for  about  70  percent  of  the  total 
output  of  cyclic  intermediate  chemicals  produced  in 
1990. 

Table  3-2  lists  the  products  reported  in  this  section 
ai)d  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  i^me  in  tabic 

3-3. 

Ed  Matusik 
202-205-3356 


Figure  3-1 

Cylic  Intermediates:  U.S.  production,  1986-90 


Billions 
of  kilograms 


30. 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


^1 


Section  3 

Table  3-1 

Cyclic  intermediates:  U.S.  production  and  sales,  1990 


Cyclic  Intermediates 


Production 


Sales 


Quantity 


Value 


Average 
Unit 
value ' 


1.000  1,000  1.000  Per 

kilograms  kilograms  dollars  kitogram 

Grand  total    23.995,795  11,865,617  10,980,553  $0.92 

Aniline  (Aniline  oil)    448,620  254,260  180,807  .71 

Benzoic  acid,  tech  45,579  (2)  (*)  (^) 

Biphenyl    24,310  10,628  7,491  .70 

Chlorobenzene,  mono-    107,526  {')  (*)  (') 

Cresols  and  cresyhc  acid^ 38,255  32,973  53,550  1.62 

Cumene     1,955,372  1,257,751  636,823  .51 

Cyclohexane   1,116,205  988,338  496,770  .50 

Cyclohexanone   473.736  51.302  53.722  1.05 

o-Dichlorobenzene 22.100  22,477  20,597  .92 

p-Dichlorobenzene 41.004  35.530  32.818  .92 

Dicyclopentadiene  (including  cyclopentadiene) 60.352  52,581  21,602  .41 

p-Dodecylphenol  7,705  7,808  9,418  1.21 

Ethylbenzene 3,796,296  467,093  284,927  .61 

Isocyanic  acid  derivatives,  total 1,050,267  722,869  1,225,293  1.70 

Diphenylmethane-4,4'-diisocyanate  (MDI)   81,320  38,038  83,595  2.20 

Polymethylenepolyphenylisocyanate    500,461  307,417  485,567  1.58 

Toluene-2,4-  and  2,6-diisocyanate 

(80/20  mixture) 445.781  367.797  628.081  1 .71 

All  other  isocyanic  acid  derivatives    22,705  9,617  28,050  2.92 

4,4'-lsopropylidenediphenol  (Bisphenol  A)   521.258  194,589  226,036  1.16 

Nonylphenol 79,176  43,241  46,775  1.08 

Octylphenol 16,746  4,134  6,719  1.63 

Phenol,  total 1,604,623  682,234  521,514  .76 

From  cumene 1.592,813  671,351  512,816  .76 

All  other  phenol   11,810  10,883  8,698  .80 

Phthalic  anhydride 426,483  189,704  115,269  .61 

Salicylic  acid,  tech 14,084  6,011  11,098  1.85 

Styrene    3,636,269  1,602,738  1,221.317  .76 

Terephthalic  acid,  dimethyl  ester*   3,525,662  (')  (2)  (Z) 

Tetrahydrofuran 84,980  35,603  71,638  2.01 

o-Xylene    427,738  281.504  117,402  .42 

P-Xylene    2,358,829  1 ,280,275  663,036  .52 

All  other  cyclic  intermediates 2.112.620  3.641.974  4.955.931  1.36 

'  Calculated  from  unrounded  figures. 

^  Reported  data  were  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

^  Does  not  include  data  for  coke  oven  and  gas-retort  ovens. 

*  The  figure  for  terephthalic  acid,  dimethyl  ester  (DMT)  includes  both  the  acid  itself  and  the  dimethyl  ester  without 
double  counting.  The  acid  production  figure  was  multiplied  by  the  factor  1.16  to  convert  it  to  equivalent  DMT. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


3-2 


Synthetic  Organic  Chemicals,  1990 

Table  3-2 

Cyclic  intermediates  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  3-3) 


Cyclic: 

Acetoacetanilide    

o-Acetoacetanisidide No 

o-AcetoacGtotoluidide  No 

2',4'-Acetoacetoxylidide No 

Acetoguanamine  No 

1  '-Acetonaphthone No 

Acetophenone,  tech No 

p-Acetotoluidide No 

2-Acetylpyridine No 

Adamanlane   No 

Aldadiene No 

Ali^ylbenzenes: 
Alkylbenzene  straight-chain  (Except  dodecyl  and 

tridecyl) No 

Oodecylbenzene  (including  tridecyibenzene): 

Oodecylbenzene,  straight-chain No 

Other  dodecylbenzone     No 

Ail^ylbenzene  all  other  (Except  dodecyl.  tridecyl  and 

stright-chain) No 

All^ylphenols,  mixed No 

Alkylpyrldines,  mixed No 

4'-Aminoacetanilide  (Acetyl-p-phenylenediamine) No 

3'-Amino-p-acetanisidide No 

3-Amino-p-anisanilide  No 

1  -Aminoanthraquinone  and  salt No 

p-Aminot)enzamide No 

o-Aminot)enzenethiol t*to 

p-Aminobenzoic  acid,  tech No 

2-Aminobenzothiazole No 

2-Amino-6-benzothiazolesulfonicacid No 

2-Amino-1-bromo-3-chloroanthraquinone No 

7-AminocGphalosporanic  acid No 

1  -Amino-2-chlorobenzene No 

5-Amino-2<hlorobenzenesuHonicacld No 

3-Amino-5<hloro-2-hydroxybenzenesulfonicacid No 

6-Amino-5-chloro-m-toluenesulfonic  acid  [SOsH-l]  (2B 

Acid) No 

4-Amino-N,N-di(|3-hydroxyethyl)aniline  sulfate  No 

4-Amino-5-mGthoxy-2-mothyll)enzenesuHonic  acid  (5- 

methyl-o-anisidlnesulfonic  acid) No 

m-[(4-Amino-3-methoxyphenyl)azo]benzanesuHonicacid  .  No 

2-Amino-2-methylpropyl8-bromotheophyllinate   No 

2-Amino-3-methylpyridine No 

2-Amino-4-methylpyridine No 

2-Amino-5-methylpyridine No 

2-Amino-6-methylpyridine No 

3-Amino-2,7-naphthalenGdisulfonicacid  No 

2-Amino-4-nitroacetanilide No 

2-Amino-5-nitrothiazole No 

5-Amino-2-((2-oxo-5-bGnzimidazolinyl)aminol- 

benzenesulfonic  acid No 

p-Aminophenol    No 

p-[(p-Aminophenyl)azo]benzenesulfonlcacid  No 

3-AmlnophenylphosphonJcacid No 

2-AminopyridinG No 

5-Aminosalicylic  acid No 

4-Amino-m-toluenesulfonicacid  [S0jH»1]   No 

6-Amino-m-toluenesulfonic  acid  [SOsH-lj   No 

Aniline  (Aniline  oil)   Yes 

2-Anilinoethanol No 


BRD.  EKT. 

BRD.  EKT. 

BRD.  Eia. 

BRD.  EKT. 

DIX. 

GIV. 

S. 

EK. 

(^ 

DIX. 

SRL. 


GIV.  I^N. 

MON.  VST 
K40N. 

{") 

PSG.  SCN. 

{") 

HCL. 

BUC.  SDC. 

PLC. 

SDC. 

NSC. 

FMT. 

NSC.  WYK. 

VPC. 

VPC. 

PLC. 

BRS. 

LI^C. 

LIWIC. 

CWN. 

DUP.  PHC. 
WAY. 

PSG. 
VPC. 
CHT 

Q 

<5 
(*) 

NES. 
SDC. 
PCW.  SAL. 

BRS.  PFZ. 

MAL. 

ATL.  VPC. 

ICI. 

(^ 

SAL. 

DUP 

DUP  PHC. 

ART.  DUP  FSI  ICI.  MAL.  MOB.  RUC. 

USR. 
SCP2 


See  footnotes  at  end  of  table. 


3-3 


Section  3 

Table  3-2 — Continued 

Cyclic  intermediates  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates  Separate  Manufacturers '  ideritification  codes 

statistics '         (accordir^g  to  list  in  table  3-3) 


Cyclic-Continued 

Anilinomethanesutfonic  acid  and  salt No  ATL,  VPC. 

o-Anisidinomethanesulfonicacid No  VPC. 

AnisolG,  tech   No  CHF. 

AnisoyI  chloride No  SD. 

Anthranilic  acid  (o-Aminobenzoic  acid) No  PSG. 

Anthra[1 .9]pyrazol-6(2H)-one  (Pyrazoieanthrone) No  SDC. 

N,N'-(1,5-Anthraquinonylene)dianthranilicacid No  SDC. 

Benzaldehyde,  tech No  KLM. 

Benzanilide   No  EK. 

Benzene  phosphorous  chloride No  ICI. 

Benzenesulfonic  acid No  UPF. 

Benzenesulfonyl  chloride No  UPF. 

1 ,2,4,5-Benzenetetracartx)xylicacid  No  AMO. 

1 ,2,4-BGnzenetricartx3xylic  acid.  1 ,2-dianhydride 

(Trimellitic  anhydride) No  AMO. 

BGnzhydrol(Diphenyimethanol) No  PD. 

Benzimidazole No  EK. 

1 ,3-Benzodioxole No  AMB. 

Benzoic  acid,  methyl  ester No  HCF. 

Benzoic  acid,  tech  Yes  KLM,  PFZ.  VEL. 

Benzoinoxime   No  RSA. 

Benzonitrile  No  PSG. 

Benzophenone No  CWN. 

2-Benzothiazolethiol,  sodium  salt    No  BFG.  USR. 

1  H-Benzotriazole No  PSG. 

2-Benzoxazolethiol    No  EK. 

Benzoyl  chloride    No  HK,  VEL. 

Benzylamine   No  HXL.  KLM. 

2-(Benzylamino)ethanol No  HXL. 

2-Benzyl-2'-hydroxy-5.9-dimethyl-6,7- 

tjenzomorphanhydrobromide No  SD. 

1  -Benzyl-4-phenylisonipecotonitrile No  SOW. 

Benzyltrimethylammonium  hydroxide  No  RSA. 

Biphenyl Yes  CXI,  KHI.  MON.  SOC. 

2,6-Bis(p-azidobenzylidene)-4-methylcyclohexanone  ....   No  (^) 
3'-[Bis(2-hydroxyethyl)amino]benzanilide.  diacetate 

ester No  SCP. 

N,N-Bis(2-hydroxyGthyl)-p-toluidine No  RSA. 

N,N-Bis((4-mGthylphonyl)sulfonyl)amine.  potassium  salt   .   No  EK. 

1 ,2-Bis(tribromophGnoxy)ethane No  GTL. 

3-BromoacetophenonG   No  (^ 

Bromobenzene,mono   No  DAZ,  GTL. 

p-Bromobenzenesulfonyl  chloride No  EK. 

o-Bromobenzoic  acid No  PD. 

2-Bromo-4,6-dinitroaniline No  HCL. 

Bromoethylbenzene No  GTL. 

p-Bromolluorobenzene    No  I*) 

2-Bfomopyridine    No  DAZ. 

p-Butylaniline No  TNA. 

p-tert-Butylbenzaldehyde No  GIV. 

n-Butylbenzene  No  PLC. 

2-tert-Butyl-p-cresol No  PSG.  RDA. 

6-tert-Butyl-m-cresol    No  RDA. 

o-sec-Bulylphenol   No  SCN,  TNA. 

o-tert-Butylphenol    No  TNA. 

p-sec-Butylphenol   No  SCN. 

p-ien-Butylphenol    No  PSG,  SCN. 

Butylphenols,  mixed No  FMC,  PSG.  O  r) 

p-tert-Butyltoluene No  GIV. 

6-tert-Butyl-2,4-xylenol    No  GAF. 


See  lootnotes  at  end  ol  table. 
3-4 


Synthetic  Organic  Chemicals,  1990 


Table  3-2 — Continued 

Cyclic  Intermediates  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

4,4'-CartK3nylbis[phthalic  anhydride]  No 

N-Carboxy-N-methylanthranilic  anhydride No 

2-Chloroacetophenone   No 

1  -(3-Chloro-allyl)-D-3,5,7-tria2a-1  -azaoniaadamante 

chloride    No 

2-Chloro-4-aminotoluene No 

o-Chloroaniline    No 

p-Chloroaniline    No 

Chlorobenzene,  mono Yes 

p-Chlorobenzenesulfonic  acid No 

4'-Chloro-2',5'-dimethoxyacetoacetanillde No 

2-Chloro-1 ,4-dimethoxybenzene No 

1  -Chloro-2,4-dinitrobenzene  (Dinitrochtorobenzene) No 

4-Chloro-3,5-dinitrobenzenesulfonic  acid,  potassium  salt  No 

p-[(2-Chloroethyl)methyiamino]benzaldehyde No 

1-Chloro-4-hydroxyanthraquinone 'No 

1  -Chloro-2-nitrobenzene  (Chloro-o-nitrobenzene) No 

1-Chloro-4-nitrob©nzene(Chloro-p-nitrobenzene) No 

4-Chloro-3-nitrobenzotrifluoride No 

2-Chloro-4-nitrotoluene No 

2-Chlorophenothiazine No 

N-(4-Chlorophenyl)-N'-(3,4-dichloropheny)urea  No 

(m-Chlorophenyl)diethanolamine No 

4-Chloro-o-phenylenediamine No 

4-Chlorophthalic  acid No 

1-(3-Chloropropyl)-4-methylpiporazine  No 

3-Chloropropyl-2,5-xylyl  ether  No 

2-Chloropyridine    No 

2-(4-Chlorosulfonylphenyl)ethyttrichlorosilane No 

o-Chlorotoluene No 

a-Chlorotoluene  (Benzyl  chloride) No 

3-Chloro-p-toluidine  [NHz-IJ No 

4-Chloro-3.5-xylenol    No 

Cresols: 

m-Cresol    No 

o-cresol: 

o-Cresol,  from  petroleum  No 

p-Cresol No 

Cresols,  mixed: 

(m,p)-cresol: 

(m,p)-Cresol,  from  petroleum No 

Cresylic  acid,  refined; 

Cresylic  acid,  refined,  from  petroleum No 

Cumene  (Isopropyl  benzene)    Yes 

Cumene  hydrogen  peroxide    No 

4-(Cyanoacetyl)morpholine No 

N-Cyanoethyl-hj-acetoxyethylaniline No 

N-Cyano-s-methyl-N-2(4-methyl-5-imidazolyl)- 

methylthioethylisothiourea No 

3-Cyanopyridine No 

Cyclohexane  Yes 

1 ,2-Cyclohexanedicartx}xyllc  acid  anhydride No 

Cyclohexanol No 

Cyclohexanone  Yes 

Cyclohexanone  oxime No 

Cyclohexene  No 

4-Cyclohexene-1.2-dicart)Oxylic  anhydride   No 

Cyclohexene  oxide    No 

P-(1-Cyclohexenyl)ethylamine No 

Cyclohexylamine No 


ACH. 

EK. 

DOW. 

LMC. 

DUP. 

DUP. 

MON,  PPG,  sec 

UPF. 

BRD. 

CHF. 

SDC. 

LMC. 

VPC. 

SK 

DUP.  MON. 

DUP,  MON. 

DAZ. 

CED. 

SK. 

VPC. 

SCP. 

FMT. 

PSG. 

SK. 

PD. 

OMC. 

NOD. 

S. 

MON. 

DUP. 

PER. 

MER. 

GE,  MER,  PSG. 
MER,  PSG. 


MER,  PSG. 

MER. 

ASH,  BTL,  GGC.  GRS,  KHI.  SHC.  SOC. 

TX,  (') 
ART 

DUP,  PCW. 
SCR 

SK. 

e) 

GRS,  PLC.  PPR,  SOC.  SUN,  TX,  UOC. 

BCC,  HK. 

ACS,  BAS,  DUP  MON. 

ACS,  BAS,  CNP,  DUP  MON. 

CNR 

USR. 

DKA. 

USR. 

HXL. 

AlP,  HCL. 


See  footnotes  at  end  of  table. 


3-5 


Section  3 


Table  3-2 — Continued 

Cyclic  Intermediates  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

Cyclohexylmethyldimethoxysilane No 

Cyclooctadiene   No 

2-Cyclopropylmethylamino-5-chlorobenzophenone   No 

2-{N-Cyclopropylmethyl-N-phthalimidoacetyl)-amlno-5- 

chlorobenzophenone No 

p-Cymene   No 

Decyldiphenyl  oxide No 

Dialkylbenzene    No 

1 ,3  Diaminocyclohexane  No 

2,6-Diaminopyridine No 

2,5-Dianilinoterephthalic  acid No 

m-Dibromobenzene No 

p-Dibromobenzene   No 

(1 .2-Dibromoethyl)benzene No 

2,6-Dibromo-4-ni1roaniline No 

Dibromostyrene No 

p-Dibutoxybenzene  (DBB) No 

2,5-Dibutoxy-4-morpholinobenzenediazonJum  sulfate  salt 

(DBB  Sulfate) No 

2,5-Dibutoxy-4-morpholinonitrobenzene No 

2.6-Di-ter1-butyl-alpha-dimethylamino-p-CTesol No 

Dibutyl-p<resol  No 

2.6-Di-t-butyl-p<resol   No 

2.4-Di-tert-butyiphGnol No 

2,6-Di-ten-butylphenol No 

2,6-Di-terl-4-sec-butylphenol No 

3,4-Dichloroaniline No 

Dichlorobenzanthrone No 

o(and  p)-Dichlorobenzene Yes 

o-Dichlorobenzene No 

m-Dichiorobenzene Yes 

p-Dichlorobenzene No 

3.3'-Dichlorobenzidine  base  and  salts No 

3,4-Dichlorobenzotrifluoride No 

3.3'-Dichloro-4,4'-biphenyl No 

Dichlorodiphenylsilane No 

2.6-Dichloro-3-methylaniline  No 

Dichloromethylphenylsilane No 

2,6-Dichloro-4-nitroaniline No 

1 ,2-Dichloro-4-nitrobenzene   No 

2,4-Dichloro-4-(2-nitro-4-trifluoromethylphenyl)- 

cinnamic  acid No 

2,6-Dichlorophenylamidinourea  hydrochloride    No 

2,6-Dichloropyridine No 

Dicyctohexylamine No 

Dicyclopentadiene  (includes  Cyclopentadiene) Yes 

a.a-DiethoxyacGtophenone No 

p-(Diethylamino)benzaldehyde  No 

4-(Diethylamino)benzaldehyde,  1,1-diphenylhydrazone  ..  No 

N-(3-Diethylamino-1,4-methoxyphenyl)acetamide   No 

N.N-Diethylaniiine   No 

Diethylbenzene  No 

N,N-Diethylcyclohexylamine  No 

3,5-Diethyl-1 ,2-dihydro-1-phenyl-2-propylpyridine No 

N,N-Diethyl-m-toluidine No 

N,N-Diethyl-p-toluidine No 

6,11-Dihydrodibenz(b,e)oxepin-11-one No 

2,3-Dihydro-2,2-dimethyl-7-benzofuranol  No 

2-2-(2.3-Dihydro-1 ,3-dioxo-l  H-inden-2yl)-(quinolinyl)]- 

6-methylbenzothiazole-7-sulfonicacid No 

2,4-Dihydroxybenzaldehyde   No 


NOD. 
DUP. 
PD. 

PD. 
HPC. 
TOG. 
VST. 
DUP  (2) 

VPC. 
DAZ. 
DAZ. 
DAZ. 
HCL. 
GTL. 
ALL. 

ALL. 

ALL. 

TNA. 

PSG. 

PLC. 

PSG,  SON. 

SCN. 

SCN. 

DUP 

SDC. 

see 

MON.  PPG,  sec,  SOI. 

MON. 

MON.  PPG.  sec  SOI. 

LMC. 

HK.{2) 

LMC. 

DCC. 

SDC. 

DCC. 

CWN. 

DUP 

SK. 

PCW. 

OMC. 

AiP.  HK. 

CXI,  DOW.  ENJ.  LYP  SHC.  VEL.  {') 

CWN. 

VPC. 

EKT. 

SCP 

BCC.  DUP 

UPM. 

AiP. 

DUP  FST 
RSA. 
PFZ. 
FMN. 

VPC. 
EK. 


See  footnotes  at  end  of  table. 


3-6 


Synthetic  Organic  Chemicals,  1990 

Table  3-2 — Continued 

Cyclic  Intermediates  (or  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers'  iderjtification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

6,7-Dihydroxy-2-naphthalenesulfonicacid No 

16,17-Dihyclroxyviolanthrone(Dihydroxydibenzanthrone)  .  No 

m-Diiodobenzene No 

m-Diisopropenylbenzene No 

2,5-DimGthoxybenzaldehydG No 

m-Dimethoxybenzene No 

m-(Dimethylamino)benzoic  acid    No 

2-[4-(DimethylamJno)benzoyl]benzoicacid  No 

m-DimethylaminophGnol  No 

N,N-Dimethylaniline No 

N.N-Dimethylbenzylamine No 

N.N-Dimethylcyclohexylamine No 

5,5-Dimethylhydantoin No 

2.6-DimethylnaphthalGne No 

Dimethyl-2,6-naphthalenedicarboxylate   No 

N,N"-Dimethyl-3,4,9,10-perylenetetracarboxylic  acid  3, 

4:9,1 0-diimide    No 

3,5-Dimethylpiperidine No 

N,N-Dimethyl-o-toluidinG No 

N,N-Dimethyl-p-toluidine No 

3,5-Dinitro-N*.N^-dipropylsulfanilamide No 

2,4-Dinitroacetanilide No 

m-Dinitrobenzene    No 

2,4-Din(trobenzenesulfonic  acid,  sodium  salt    No 

3,5-Dinitrobenzoic  acid   No 

2,4-Dinitrophenol,  tech No 

3.5-Dinitrosalicylic  acid,  methyl  ester No 

p-Dinilrosobenzene No 

2,4-Dinitrotoluene    No 

2,4(and  2,6)-DinitrotoluGne   No 

Dinitrotrimethyjeneglycoi-di-p-aminobenzoate No 

DinonylphGnol  No 

2,4-Dioxo-3-azaspiro[5,5]undecane-1.S-dicarbonitrile 

monoonium  sait  No 

Di-para-benzoquinone  dioxime  No 

2,4-Di-tGr1-pGntylphGnol No 

Diphenylamine No 

DiphenykJimethoxysilane No 

Diphenyldisulfido No 

DiphGnyl  phosphorous  chloride No 

Dipheny!  phthalatG No 

Di-2-picolylamine No 

1 .3-Di-4-pip>GridylpropanG   No 

2,5-Di-p-toluidinotGrGphthalic  acid No 

1 ,5-diurGidonaphthalene  No 

DivinylbenzGriG    No 

1 .1  -Di-3,4-xylylGthanG No 

Dodecyldlphenyl  oxide No 

p-DodGcylphGnol  Yes 

4-EthanolpipGridinG No 

2-EthanolpyridinG No 

5-Ethanoxy-3-trichloromGthyl-1,2,4-thiadiazole No 

Ethisterone    No 

N-EthylaniliriG,  rGfined  No 

2-{N-Ethylanilino)Gthanol No 

3-(N-Ethylanilino)propioni1rilG    No 

a-(N-Ethyianilino)-m-toluGnGsulfonicacid No 

Ethylbenzene Yes 

2-{N-Ethyl-N.|3-cyanoGthyl)-4-acetaminoanisole No 

N-EthylcycJohexylamine No 


COG. 

EK. 

GGC. 

DLT. 

OWN. 

ACY 

EK. 
ACY 

BGC,  DUP. 
HXL. 

AlP.  BAS. 
BRD. 
UPM. 
UPF. 

VPG. 

RSA. 

FST.  RSA. 

LMG. 

SDG. 

DUP.  FST. 

EK. 

SAL. 

SDG. 

SAL. 

LG. 

DUR 

RUG,  (2) 

SAL. 

TX. 

PD. 

LG. 

PAS,  PSG.  SCN. 

ART  RUG.  USR. 

NOD. 

PAH. 

IGI. 

EK. 

VPG. 

SOI. 

DLT  DOW,  TGG. 

AGH. 

TGG. 

MON.  SGN,  SOG,  TX. 

<^ 

OMC. 
SRL,  UPJ. 
BGC,  FST 
MIL,  SGP. 
SCR 

AMO,  GSD,  DOW.  ELP.  GE.  KHI.  PLC.  SC. 

SOG,  SOG. 
SGR 
BAS. 


See  footnotes  at  end  of  table. 


3-7 


Section  3 


Table  3-2 — Continued 

Cyclic  intermediates  for  which  U.S.  production  and/or  sales  were  reported.  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

N-Ethyl-N-(2-hydroxyethyl)-m-toluidine No 

N-Ethylmaleimide    No 

2-[Ethyl(3-methylphenyl)aminolethanol No 

Ethyl  2{2-nitro-4-trifluoromethylphenyl)-3-oxobutanoate  . .   No 

N-Ethyl-N-phenylbenzylamine No 

N-Ethyl-m-toluidine   No 

3-(N-Ethyl-m-toluidino)propionitriie  No 

o-FluorobenzoyI  chloride No 

p-Fluoronitrobenzene No 

1  -Formylpiperidine No 

Furan No 

Furturyl  alcohol   No 

Guanine No 

Hexachlorocyclopentadiene No 

1,4,5,6,7,7-Hexachloro-5-norbomene-2,3-dicartx)xylic 

anhydride  {Chlorendic  anhydride)   No 

Hexahydro-1-[(2-aminophenyl)sulfonyll-1h-azepine No 

Hexahydro-1-[{2-nitrophenyl)sulfonyl]-1h-a2epine No 

Hexamethyleneimine No 

Hydroquinone,  tech No 

p-Hydroxybenzenesulfonicacid No 

p-Hydroxybenzoic  acid    No 

4-Hydroxy-2H-1 ,2-benzothiazine-3-carboxylic  acid, 

methyl  ester,  1 ,1  -dioxide  No 

2'-Hydroxy-5,9-dimethyl-6,7-benzomorphan No 

3-(N-(2-Hydroxyethyl)anillno]propionitrile   No 

N-P-Hydroxyethyl-2,4-dihydroxybenzamide   No 

5-Hydroxyisophthalic  acid  No 

4-Hydroxy-2-fnethyl-2H-1,2-benzothiazine-3-carfc)oxylic 

acid,  methyl  ester,  1,1 -dioxide  No 

2-Hydroxymethylene-1 7a-ethinylandrost-1 73-oi-4-en-3-oneNo 
3-Hydroxy-N-(3-N-morpholino-Y-propyl)-2-naphthimide   . .   No 

6-l-lydroxy-2-naphthalenesulfonic  acid,  sodium  salt    No 

1  -Hydroxy-2-naphthoic  acid No 

3-Hydroxy-2-naphthoic  acid(B.O.N.) No 

3-Hydroxy-2-naphthoic  acid,  methyl  ester No 

2-lmidazolidinone  modification    No 

5-indanol  No 

p-lodotoluene No 

Isobutylbenzene No 

isobutylbiphenyl No 

Isobutyrophenone  No 

Isocyanic  acid  derivatives: 

Bitolylene  diisocyanate  (TODI)  No 

Diphenylmethane-4,4'-diisocyanate  (MDI) No 

Polymethylenepolyphenylisocyanate   No 

Toluene  2,4-diisocyanate No 

Toluene  2,4-and  2,6-diisocyanate  (80/20  Mixture) No 

Toluene  2,4-and  2,6-diisocyanate  (65/35  Mixture) No 

p-Toluenesulfonyl  isocyanate No 

All  other  isocyanic  acid  derivatives    No 

isonicotinic  acid No 

Isonicotinonitrile No 

Isophthalic  acid,  diallyl  ester    No 

Isophthalic  acid,  dimethyl  ester No 

Isophthalonilrile No 

IsophthaloyI  chloride   No 

Isopropylbiphenyl No 

4,4'-lsopropylidenediphenol  (Bisphenol  A)    Yes 

4,4'-lsopropylidenediphenol,ethoxylated No 

4,4'-lsopropylidenediphenol,propoxylated    No 


SOP. 
REG. 
FST 
SK. 

DUP,  FST 

SOP. 

OMC. 

QKO. 
QKO. 
LLi. 
VEL. 

OMC,  VEL. 

SAL. 

SAL. 

CXI,  DUP. 

EKT,  GYR. 

UPF. 

LEM. 

PFZ. 
SD. 
SCP. 
PCW. 

e) 

PFZ. 

SD. 

PCW. 

(^ 

PCW. 
PCW. 
PCW. 

RSA. 

PLC.  TNA. 
TCC. 
ARS. 

CWN. 

BAS.  DOW,  ICI.  MOB.  RUC. 

BAS.  DOW,  ICI.  MOB.  RUC. 

MOB. 

BAS.  DOW.  ICI.  MOB.  OMC.  RUC. 

MOB. 

VCM. 

CWN,  MOB,  UCC. 

<^ 

AMO. 

UTC. 

DUP,  PSG. 

DUP,  TLC. 

TCC 

ART,  DOW,  GE.  SHC. 

ICI.  SCP. 

ICI,  SCP. 


See  lootnotes  at  end  ol  table. 


3-8 


Synthetic  Organic  Ctumicals,  1990 

Table  3-2 — Continued 

Cyclic  Intermediates  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manulacturer,  1990 


Cyclic  intermediates  Separate         Martuiacturers '  identification  codes 

statistics '         (according  to  list  in  table  3-3) 


?UC. 


Cyclic- Continued 

Isopropylphenol.  mixed  No 

2,6-Lutidine   No  r) 

f^elamine No  ACY,  MLC. 

p-Mentha-1 ,4{8)-diene No  NCI. 

dl-p-f>^entha-1 ,8-diene  (Limonene)   No  ARZ.  NCI. 

4-f5lethoxyacetophenone No  BUG. 

4-Methoxybenzyl  alcohol No  BUG. 

2-lwtethoxyethylpiperidine No  (^ 

N-{4-Methoxy-3-nilrophenyl)acetamide No  SDG. 

2-(N-Methylanilino)ethanol No  SGP. 

3-(N-Methylanilino)propionitrile No  SGP. 

2-Methylanthraquinone  No  ACY. 

Methyl-2-bGnzimidazole  carbamate No  GEO. 

2-Methylbenzothiazole No  FMT. 

4-Methylbenzotriazole No  VPG. 

o-MethylbenzoyI  chloride No  TLG. 

4-MethylbGnzoyl  chloride No  GR2,  TLG. 

N-Methylbenzylamine   No  HXL. 

2-»y4ethyl-l,1-biphenyl(n-3-yl) methanol No  NES. 

Methylcyclohexane   No  PLC. 

h/tethyl3-(2,2-dichlorovinyl)-2,2-dimethylcyctopropane 

carboate No  Ffi^N. 

2,2'-K4ethylenebis(4-methyl-6-nonyl-p<resol) No  PSG. 

4,4'-MethylenGdiapiline  No  RUG,  USR. 

Methylenedicyclohexylmethane1,4-diisocyanate No  MOB. 

1 ,2-Methylenedioxybenzene No  GRZ. 

5,5'-(^ethylenedisalicylic  acid    No  KLM. 

Methyl  p-formylbenzoate No  EKT. 

(2,4-Methyl-5-imidazolyl)methylthioethylamine 

dihydrochloride- No  SK. 

N-Methyl-p-nitroanilino    No  ACY.  USR. 

4-Methyl-2-nitroanisole    No  PSG. 

1-{2-Methyl-4-nitrophonyl)pyrrolidine No  ALL. 

2-Methyl-5-norbornene-2,3-dicarboxylic  anhydride No  BCG. 

N-(3-Methylphenyl)ac8tamide No  SDG. 

4-(1-Methyl-1-phenyl)ethylphenol  No  SGN. 

4-MGlhylphthalic  acid No  EK. 

1  -Methylpiperidine No  (^ 

2-Methylpiperidine No  ir) 

a-Mothylstyrene No  ART.  BTL,  GGC. 

ar-Molhylstyrene  (Vinyltotuene) No  DLT. 

2,6-Naphthalenedicartx3xyltc  acid  No  AMO. 

2-NaphthalGnesulfonic  acid No  ACY. 

Naphlhalimide No  VPG. 

1-Naphthylamine  (a-Naphthylamine)    No  DUP. 

p-(2-Naphthylamino)phenol  (N-(p-Hydroxyphenyl)-2- 

naphthylamine)    No  SDG. 

Nicotinonitrile  (3-Cyanopyridine) No  NEP. 

o-Nitroaniline No  BUG.  MON. 

p-Nitroaniline No  MON. 

S-Nitroanthranilic  acid   No  SAL. 

I-Nitroanthraquinono No  SDG. 

-Nitrobenzamide    No  PD. 

Nitrobenzene No  FST.  ICl,  RUG. 

m-NitrotjenzenesuHonic  acid,  sodium  salt No  USM. 

o-Nitrobenzoic  acid  No  SAL. 

m-Nitrobonzoic  acid No  SAL.  (^) 

p-Nitrobenzoic  acid  No  DUP. 

m-Nitrobenzoic  acid,  sodium  salt No  SAL. 

2-Nitro-M-ben2oylaniline   No  SAL. 

2-Nitro-p-cresol   No  PSG. 

See  footnotes  at  end  of  table. 


M 


Section  3  ^ 

Table  3-2 — Continued 

Cyclic  intermediates  for  which  U.S.  production  and/or  salas  war*  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 

statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

5-Nitrodimethylisophthalate No 

Nitrodiphenylamine  No 

5-Nitroisophthalic  acid No 

p-Nitrophenethyl  alcohol   No 

p-Nitrophenol No 

p-Nitrophenoi,  sodium  salt No 

p-Nitrophenoxyethanol No 

5-Nitrosalicylic  acid   No 

p-Nitrosophenol No 

4-Nitrosophenol,  sodium  salt No 

o-Nitrotoluene   No 

m-Nitrotoluene No 

p-Nitrotoluene   No 

Nitrotoluene  mixtures No 

(2-Nitro-4-tri1luoromethylphenyl)acetic  acid No 

Nonylphenol Yes 

Octylphenol  Yes 

Octylphenoxydiethoxy  chloride    No 

1-[(7-Oxo-7H-benz[de]anthracene-3-yl)amino]- 

anthraquinone   No 

3-0x0-1 ,2-benzisothia20line-2-acetic  acid,  methyl  ester, 

1.1-dioxide No 

Oxyaluminum  tienzoate No 

4,4'-Oxydianiline   No 

o-Pentylphenol  (o-Amylphenol) No 

p-tert-Pentylphenol   No 

3,4.9, 10-Perylenetetracart>oxylic-3,4:9,10-dianhydrid«  ...   No 

3,4,9, 10-Perylenetetracartx)xyiic-3.4:9,10-diimide   No 

1,10-Phenanthroline    No 

2-Phenethylamine  No 

p-Phenetidine No 

Phenol: 
Natural: 
From  petroleum: 

Phenol,  natural,  from  petroleum,  U.S.P   No 

All  other  phenol,  natural,  from  petroleum No 

Synthetic: 
By  caustic  fusion: 

All  other  phenol,  synthetic,  by  caustic  fusion   No 

Phenol,  benzylated No 

Phenol,  styrenated  No 

Phenol,  synthetic,  from  cumene  by  oxidation,  U.S.P.  .   No 

All  other  phenol,  synthetic   No 

Phenolsulfonaphthalein No 

Phenolsulfonic  acid  No 

Phenolsulfonic  acid,  sodium  salt No 

Phenoxyacetic  acid,  sodium  salt  No 

m-Phenoxytoluene No 

4-(Phenylazo)diphenylamine No 

2-Phenylbenzimide    No 

m-Phenylenebismaleimide No 

o-Phenylenediamine   No 

m-Phenylenediamine No 

p-Phenylenediamine  No 

Phenyl  ether  (Diphenyl  oxide) No 

d(-)a-Phenylethylamine No 

N-Phenyiglycine No 

Phenylglycine,  potassium  salt No 

Phenylglycine,  sodium  salt    No 

2,2'-[(Phenyl)imino]diethanol(N-Phenyldiethanolamine) . .   No 
2.2'-[(Phenyl)imino]diethanol,  diacetale  ester No 


SAL. 

ACY,  MON. 

SAL. 

PCW. 

K40N. 

DUP 

SCR 

SAL. 

LC,  SDC. 

SDC. 

FST. 

DUP.  FST. 

DUP,  FST 

FST 

SK 

GAP.  GE.  KLM,  MON.  RH.  SON,  TX. 

PSG,  RH,  SON. 

RH. 

SDC. 

PFZ. 

CHT 

DUP. 

PAS,  SON. 

PAS. 

VPC. 

VPC. 

VNC. 

HXL. 

HCL,  MNA. 


IVIER. 
ISP,  PSG. 


DOW. 

MIL. 

MIL.  PSG. 

ACS,  ART  BTL.  GE.  GGC. 

KLM.  SHC.  TX. 

EK. 

SAL. 

SAL. 

NCC. 

MER. 

EK. 

SAL. 

NES. 

DUP.  PSG. 

DUP.  FST 

DUR 

DOW,  MON. 

HXL. 

EK. 

KAN. 

BCC,  LIL. 

MIL,  SCR 

SCR 


See  footnotes  at  end  of  table. 


3-10 


Synthetic  Organic  Chemicals.  1990 

Table  3-2 — Continued 

Cyclic  intermediates  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

o-Phenylphenol   No 

p-Phenylphenol  No 

o-Phenylphenol,  sodium  salt No 

N-Phenyl-p-phenylenediamine   No 

1-Phenyl-1,2-propanedione,  2-oxime    No 

Phenyl-2-propanonG   No 

4-PhGnylpropylpyridinG   No 

Phenyltrimethyl  ammonium  chloride  No 

N-Phenyluroa No 

Phthalic  acid   Yes 

Phthalic  anhydride No 

Phthalimide  No 

(Phthalocyaninato(2-)]copper No 

PhthalocyaninetetrasuHonyl  chloride,  copper  derivative  ..  No 

PhthaioyI  chloridG  (Phthaiyl  chlorido) No 

Picolines: 

Picoline  (3,4-mlxture) No 

2-Picoline  (a-Picoline) No 

3-Picoline  (P-Picoline) No 

4-Picoline  (Y-Picoiine) No 

Picolinonitrile  (2-Cyanopyridine)   No 

3-Picolylamine No 

Picric  acid  (Trinitrophenol)   No 

Piperidine No 

Polyethylbenzene  (60  percent  diethylbenzene)   No 

Propiophenone    No 

Pyridine  hydrochtaride No 

3-Pyridinemethanol No 

Pyridine,  refined; 

2°  Pyridine,  refined No 

All  other  grades  pyridine,  refined No 

2  Pyridinethiol-1  -oxide,  sodium  salt No 

2  Pyridinelhiol-1  -oxide,  zinc  salt   No 

Pyromeilitic  dianhydride No 

2-Pyrrolidinone  (2-Pyrrolidone) No 

Pyrvinium  pamoate   No 

Quinaldino No 

Quinone  dioxime  No 

Resorcinoi,  tech No 

B-Resorcylic  acid No 

Salicylaldehyde No 

Salicylaldehyde  oxime No 

Salicylanilide  No 

Salicylic  acid,  tech Yes 

Sodium  p-sulfophenylmethallyl  ether No 

Sodium  trichlorobenzenesulfate    No 

Styrene  (Vinylbenzene) No 

Sultanilic  acid  (p-Aminobenzenesulfonic  acid)  and  salt  . .  No 

5-Sulfoisophthalic  acid,  1 ,3-dimethyl  ester,  sodium  salt   . .  No 

5-Sulfoisophthalic  acid,  sodium  salt No 

4-Sulfophthalic  acid No 

Terephthalic  acid  No 

Terephthalic  acid,  dimethyl  ester No 

Terephthaloyl  chloride  No 

Torphenyl  (Phenylblphenyl)  (m-,o-,and  p-isomers)   No 

Terpinene-4-ol  No 

Totrabromophthalic  anhydride No 

Tetrabromophthalic  anhydride,  diester No 


DOW. 

DOW. 

DOW. 

USR. 

ORT. 

SK. 

(^ 

LLI. 

RSA. 

EK. 

ART.  BAS,  ENJ,  STP.  USR. 

PSG. 

PHC. 

VPC. 

TLC. 

(') 
(') 
NEP,  (^) 

{") 

NEP 

(^ 

SDC. 

AlP,  (*) 

ELP 

ORT 

RSA. 

i") 

NEP. 

OMC. 
OMC. 
ACH. 
GAR 

ACY  GIG. 

LG. 

ISP. 

ISP. 

RDA. 

EK. 

PGW. 

DOW,  KLU/I,  RDA,  (^ 

SAL. 

UPF. 

AMO,  ATR.  GSD,  DLT  DOW,  ELP.  GE, 

PLC.  SC,  SOC 
{') 

DUP 
PCW. 
CWN. 

AMO.  DUP.  HGF. 
DUP.  EKT.  HCF. 
DUP,  TLC. 
MON. 

(^ 

GTL. 

GTL. 


See  footnotes  at  end  of  table. 


3-11 


Section  3 


Table  3-2 — Continued 

Cyclic  intermediates  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer,  1990 


Cyclic  intermediates 


Separate 
statistics ' 


Manufacturers '  identification  codes 
(according  to  list  in  table  3-3) 


Cyclic-Continued 

Tetrachlorophthalic  anhydride  No 

Tetrahydrofuran Yes 

1 ,2,3,4-Tetrahydronaphthalene No 

1 ,2,4,5-Tetramethylbenzene  (Durene)   No 

p-(1,1,3,3-Tetramethylbutyl)phenol  No 

Tetranilrodibenzo-1.3a,4.6a-tetraazapentalene No 

3,3'-Thiobis[7h-benz[de]anthracen-7-one] No 

6,6'-Thiodimetanilic  acid    No 

Toluene-2,3-(and  3,4)-diamine  (35/65  Mixture) No 

Toluene-2,4-diamine  (4-m-Tolylenediamine)    No 

Toluene-2,4-(and  2,6)-diamine  (80/20  Mixture) No 

Toluene-3,4-diamine   No 

p-Toluenesutfonamide No 

p-Toluenesultonic  acid No 

p-Toluenesuttonic  acid,  aniline  salt    No 

m-Toluic  acid  No 

p-Toluic  acid,  methyl  ester No 

o-Toluidine No 

m-Toluidine    No 

p-Toluidine No 

2.2'-(o-Tolylimino)diethanol  No 

2,2'-(m-Tolylimino)diethanol No 

Tolyltriazole  No 

2,4,6-Tribromophenol    No 

1 ,2,3(and  1 ,2,4)-Trichlorobenzene No 

1 .2,4-Trichlorobenzene  No 

3-Trichloromethyl-1 ,2,4-thiadiazole No 

Trichlorophonylsilane No 

a,a,a-Trichlorotoluene  (BenzotrichJoride) No 

2,4,6-Trichloro-s-triazine  (Cyanuric  chloride) No 

Tri(dimethylaminomothyl)phenol No 

Trimellitic  anhydride,  acid  chloride No 

Trimellitic  trichloride No 

1 ,2.4-Trimethylbenzene  (Pseudocumene)  No 

1 .3,5-Trimethylbenzene  (Mesitylene) No 

1,3.3-Trimethyl-5^,  a-indolineacetaldehyde No 

2,3,6-Trimethylphonol   No 

Triphenylmethane   No 

a,a',a"-Tris(dimethylamino)mesitol No 

1,1,1-Tris(p-hydroxyphenyl)ethane  No 

Tris(2-methyl-1-a2iridinyl)phosphine  oxide   No 

7,7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonicacidl 

(J-Acid  urea)    No 

Veratraldehyde  {3,4-Dimothoxybenzaldehyde)  No 

2-\/inylpyridine No 

4-Vinylpyridine No 

o-Xylene  (90-100%  of  o-xylene  isomer)    Yes 

m-Xylene  (90-100%  of  m-xylene  isomer)    No 

p-Xylene  (90-100%  Of  p-xylene  isomer) Yes 

2,4-Xyienesulfonic  acid   No 

Xylenesulfonic  acid,  mixed  isomers No 

2,6-Xylenol No 

Xylenol  crystals  No 

Xylenols; 

Xylenol,  low  twiling  point   No 

Xylenols,  not  classified  as  to  boiling  point  No 


MON. 

ATR.  BAS.  DUP,  GAF,  QKO. 

RDA. 

KHI. 

GAF. 

TLI. 

CRZ. 

CRZ. 

OMC. 

RUG.  (2) 

OMC. 

UTC. 

TEN.  UPF. 
NES. 
WTC. 
HCF. 

DUP.  FST 
DUP.  FST 
DUP.  FST 
SCR 

MIL.  SCP. 
PSG. 
GTL. 
PPG.  sec. 

sec. 

OMC. 
DCC. 
HK.  VEL 
DGC. 
PEL. 

TLC. 

KHI.  SOG. 

ABB.  KHi. 

VPC. 

GE. 

EK. 

RH. 

SAL. 

ARS. 

S. 
GIV. 

<^ 

ENJ.  KHI.  LYP,  PLC,  PPR. 

AMO.  PLC. 

AMO,  ENJ.  KHi,  LYP.  PLC.  PPX,  SOC. 

STX. 
UPF. 
NES. 
GE. 
HCL.  HXL 

MER. 
GE. 


See  footnotes  at  end  of  table. 


3-12 


Synthetic  Organic  Chemicals.  1990 

Table  3-2 — Continued 

Cyclic  Intermediates  tor  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Cyclic  intermediates  Separate         Manufacturers' identificatbn  codes 

statistics '         (according  to  list  in  table  3-3) 

Cyclic-Continued 

Xylidines: 
Xylidine,  original  mixture   No  DUP,  (^) 

All  other  cyclic  intermediates    Yes  ACY,  AMB,  ATL.  BRD,  BRS.  BUG,  CHD, 

CRZ.  DUP,  EK,  EKT,  HOP,  HCL,  HK, 
HXL,  KAN,  LC,  NOD,  OMC,  PCI,  PCW, 
PD,  PFZ,  PIL,  PRC,  PSG,  RAY  SAL, 
SCH.  SCP,  SD,  SDC,  SDW,  SK,  TOG, 
TNA,  UGG.  UPF,  UPJ,  UPJ,  UPJ,  UPJ, 
UPJ,UPJ,  UPJ,  VPG. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


3-13 


Section  3 

Table  3-3 

Cyclic  Intermediates:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Ck>de  Name  of  company 

ABB Abbott  Laboratories 

ACH Alico  Chemical  Corp. 

ACS Allied  Signal  Inc.,  Engineered  Material 

Sector 

ACY American  Cyanamid  Co. 

AlP Air  Products  &  Chemicals.  Inc. 

ALL   Alliance  Chemical,  Inc. 

AMB American  Bio-Synthetics  Corp. 

AMO    Amoco  Corp. 

ARS Arsynco,  Inc.,  Sub.  Div.  of  Aceto  Corp. 

ART Aristech  Chemical  Corp.,  Chemical  Div. 

ARZ Arizona  Chemical  Co. 

ASH Ashland  Oil,  Inc.,  Ashland  Petroleum 

Co. 

ATL   Atlantic  Industries,  Inc. 

ATR Atlantic  Richfield  Co.,  Arco  Chemical 

Co. 

BAS BASF  Corp. 

BCC Buffalo  Color  Corp. 

BFG B.  F.  Goodrich  Co..  B.  F.  Goodrich 

Chemical  Group 

BRD Lonza,  Inc. 

BRS Bristol-lwfyers  Co. 

BTL   BTL  Specialty  Resin  Corp. 

BUC Synalloy  Corp.,  Blacl<man  Uhler 

Chemical  Div. 

CCC C.N.C.  International,  Inc. 

CED Cedar  Chemical  Co. 

CHD Chemdesign  Corp. 

CHF Kincaid  Enterprises.  Inc. 

CHT Chattem,  Inc. 

CIC    Color  Chem  International  Corp. 

CNP DSM  Chemicals  North  America 

CRZ James  River  II  Corp, 

CSD Fina  Oil  &  Chemicals  Co.,  Cosden 

Chemical  Div. 

CWN   Upjohn  Co.,  Fine  Chemicals 

CXI Chemical  Exchange  Industries.  Inc. 

DAZ Diaz  Chemical  Corp. 

DCC    Dow  Corning  Corp. 

DGC Degussa  Corp. 

DIX Dixie  Chemical  Co..  Inc. 

DKA Mobay  Synthetics  Corp. 

DLT   Deltech  Corporation 

DOW   Dow  Chemical  Co. 

DUP E.I.  duPont  de  Nemours  &  Co..  Inc. 

Chemicals  and  Pigments  Dept. 

Petrochemicals  Dept. 

EK  Eastman  Kodak  Co.; 

EKT Tennessee  Eastman  Co.  Div. 


Code 


Name  of  company 


ELP  . .  . 

Rexene  Products  Company 

ENJ  . .  . 

Exxon  Chemical  Americas 

FER  . .  . 

FerroCorp.: 

Bedford  Chemical  Div. 

Grant  Div. 

FMC   .. 

FMC  Corp..  Nitro  Div. 

FMN    .. 

Agricultural  Chemical  Group 

FMT . . . 

Fairmount  Chemical  Co.,  Inc. 

FST  . . . 

First  Chemical  Corp. 

GAF  . . . 

GAF  Chemical  Corp. 

GE  . . . . 

General  ELectric  Co.,  Speciality 

Chemical  Group 

GGC  .. 

Georgia-Gulf  Corp.: 

Houston  Div. 

Plaquemine  Div. 

GIV  ... 

Givaudan  Corp 

GRS    .. 

Champlin  Refining  Co. 

GTL... 

Great  Lakes  Chemical  Corp. 

GYR    .. 

Goodyear  Tire  &  Rubber  Co. 

HCF . .  . 

Cape  Industries 

HCL . .  . 

Hoechst  Celanese  Corp. : 

Bayport  Works 

Fine  Chemicals  Div. 

Sou-Tex  Works 

Specialty  Chem  Group 

HIL    ... 

Hilton  Davis  Co. 

HK  . . . . 

Occidental  Chemical  Corp..  ED  &  S  Div. 

HFC    .. 

Hercules.  Inc. 

HXL  . . . 

Hexcei  Corp.,  Hexcel  Chemical 

Products 

ICI  .... 

ICI  Americas,  Inc., 

Agricultural  Chemicals  Div. 

Polyurethanes  Group 

Specialty  Chem  Div. 

ISP    ... 

Indspec  Chemical  Corp. 

KAN... 

Kanasco.  Ltd 

KHI   ... 

Koch  Refining  Co. 

KLM  . . . 

Kalama  Chemical,  Inc. 

LC     ... 

Lord  Corp.,  Chemk:al  Products  Group 

LEM  . . . 

Napp  Chemicals.  Inc. 

LIL  . . . . 

Eli  Lilly  &  Co. 

LLI  . . . . 

Lee  Laboratories.  Inc. 

LIWlC    .. 

Lomac,  Inc. 

LYP  ... 

Lyondell  Petrochemical  Co. 

MAL . . . 

Maliinckrodt.  Inc. 

MER   .. 

Merichem  Co. 

h4IL   ... 

Milliken  &  Co..  Milliken  Chemical  Div. 

MLC    .. 

Melamine  Chemicals.  Inc. 

MNA   .. 

Monsanto  AgricuKure  Co. 

See  note  at  end  of  table. 


3-14 


Synthetic  Organic  Chemicals,  1990 


Table  3-3 — Continued 

Cyclic  intermediates:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 

Name  of  company 

MOB    ... 

Mobay  Chemical  Corp.,  Pittsburgh  Div. 

MOU    . . . 

Monsanto  Co. 

NOG.  .  . . 

Niacet,  Corp. 

NCI    . .  . . 

Union  Canrip  Corp.,  B  B  A  Div. 

NEP  .  .  . . 

Nepera,  Inc. 

NES  . .  . . 

Ruetgers-Nease  Chemical  Co. 

NOD . . . . 

Huls  America,  Inc. 

NSC  ... . 

National  Starch  &  Chemical  Corp. 

OMC    ... 

Olin  Corp. 

ORT  .  . .  . 

Roehr  Chemicals,  Inc.,  Div.  of  Aceto 

Corp. 

PAH  .  .  . . 

Parish  Chemical  Co. 

PAS   .  .  . . 

Atochem  North  America,  Inc. 

PCI 

Piedmont  Chemical  Industries.  Inc. 

PCW    .  . . 

Plister  Chemical,  Inc. 

PD 

Parke-Davis  Div.  of  Warner-Lambert 

Co. 

PEL  .... 

Pelron  Corp. 

PFZ  .... 

Pfizer,  Inc.,  &  Rizer  Pharmaceuticals. 

Inc. 

PHC  . . . . 

Phthalchem,  Inc. 

PLC  . . . . 

. .     Phillips  66  Co. 

PPG  . . . . 

PPG  Industries,  Inc. 

PPR  .  . . . 

Phillips  Puerto  Rico  Core,  Inc. 

PPX  .  .  . 

Phillips  Paraxylene,  Inc. 

PRC  . . . . 

Products  Research  &  Chemical  Corp. 

PSG  . . . . 

PMC,  Inc.,  PMC  Specialty  Group,  Inc. 

QKO  . . . . 

OO  Chemicals,  Inc. 

RAY  ... . 

Rayonier  Chemical  Products.  Inc. 

RDA  . . . . 

Rhone-Poulenc,  Inc. 

REG  ... . 

Regis  Chemical  Co. 

RH 

Rohm  &  Haas  Co. 

RSA  . . . . 

R.S.A.  Corp. 

RUC  . . . . 

Rubicon,  Inc. 

S    

Sandoz  Chemicals  Corp. 

SAL   ..    . 

Solvay  Animal  Health  Inc. 

SC 

Sterling  Chemicals,  Inc. 

sec ... . 

Standard  Chlorine  of  Delaware,  Inc. 

SCH  .  . . . 

The  Schering  Corp. 

SCN  .  . . . 

Schenectady  Chemical,  Inc. 

Code 


Name  of  company 


SCP Henkel  Corp. 

SD Sterling  Drug,  Inc.,  Sterling 

Pharmaceuticals,  Inc. 

SDC    Sandoz  Chemicals  Corp. 

SDW Sterling  Drug,  Inc., 

Organic  Div. 

SHC    Shell  Chemical  Co. 

SK Smithkline  Beecham  Chemicals 

SOC    Chevron  Corp.,  Chevron  Chemical  Co. 

SOG   Hill  Petroleum  Company 

SOI   Specialty  Organics.  Inc. 

SRL G.  D.  Searle  &  Co. 

STP Stepan  Co. 

STX St.  Croix  Petrochemical  Corp. 

SUN    Sun  Company,  Inc. 

TCC Sybron  Chemicals,  Inc. 

TEN Tennessee  Chemical  Co. 

TLC Twin  Lake  Chemcal,  Inc. 

TLI Teledyne  Industries  Inc..  Teledyne 

McCormick  Selph 

TNA Ethyl  Corp. 

TX Texaco  Chemical  Co. 

UCC    Union  Carbide  Corp.,  Industrial 

Chemicals  Div. 

UOC    Union  Oil  Co.,  of  California 

UPF Stoss  Industries 

UPJ Upjohn  Co 

UPM   UOP,  Inc 

USM   Crown  Metro,  Inc. 

USR    Uniroyal  Chemical  Co.,  Inc. 

UTC Unitex  Chemical  Corp. 

VCM   Vanchem,  Inc. 

VEL Velsicol  Chemical  Corp, 

VNC    Vanderbilt  Chemcal  Corp. 

VPC Mobay  Chemical  Corp.,  Dyes  & 

Pigments  Div. 

VST Vista  Chemical  Co. 

WAY    Olin  Hunt  Specialty  Products.  Inc. 

WTC Witco  Corp. 

WYK Wyckoff  Chemical  Co.,  Inc. 


Note. — Complete  names,  telephone  numt>ers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission 


3-15 


Syntheiic  Organic  Chemicals,  1990 


Section  4 
Dyes 

Synthetic  dyes  are  derived  in  whole  or  in  part  from 
cychc  intermediates.  Approximately  two-thirds  of  the 
dyes  consumed  in  the  United  States  are  used  by  the 
textile  industry  to  dye  natural  and  synthetic  fibers  or 
fabrics;  about  one-sixth  is  used  for  coloring  paper,  and 
the  rest  is  used  chiefly  in  the  production  of  organic 
pigments  and  in  dyeing  leather  and  plastics.  Of  the 
several  thousand  different  synthetic  dyes  that  are 
known,  more  than  one  thousand  are  manufactured  by 
domestic  producers,  collectively.  The  large  number  of 
dyes  results  from  the  many  different  types  of  materials 
to  which  dyes  are  applied,  the  different  conditions  of 
service  for  which  dyes  are  required,  and  the  cost  that  a 
particular  use  can  bear.  Commercial  dyes  are 
formulated  products  which  are  sold  in  a  variety  of 
physical  forms  (e.g.  granular,  powders,  liquids,  and 
pastes)  containing  concentrations  of  colorant  ranging 
from  6  percent  (approximately)  to  100  percent.  In  the 
statistical  tables,  production  and  sales  quantities  are 
expressed  in  terms  of  a  standard  strength  of  product 
(based  on  dyeing  performance)  and  not  in  terms  of  the 
amount  of  actual  colorant. 


Total  domestic  production  of  dyes  in  1990 
amounted  to  117  million  kilograms,  or  33  percent  less 
than  the  174  million  kilograms  produced  in  1989  (table 
4-1).  Sales  of  dyes  in  1990  amounted  to  103  million 
kilograms,  valued  at  $775  million,  compared  with  146 
million  kilograms,  valued  at  S858  million,  m  1989.  In 
terms  of  quantity,  sales  of  dyes  in  1990  was  29  percent 
lower,  and  in  terms  of  value  II  percent  lower.  The 
average  unit  value  of  sales  of  all  dyes  in  1990  was 
$7.46  per  kilogram,  compared  with  $5.83  per  kilogram 
in  1989. 

Production  of  five  classes  of  dyes  decreased  in 
1990,  while  the  remaining  six  major  classes  increased 
their  production.  Fiber-reactive  dyes  and  flourescent 
brightening  agents  registered  significant  increases  in 
1990  while  direct  dyes  and  flourescent  brighming  agent 
registerd  a  noticeable  declines.  Changes  in  U.S. 
production  of  synthetic  dyes  followed  overall  changes 
in  U.S.  economic  activity  during  1986-90  (see  figure 
4-1). 

Table  4-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 

4-3. 

Stephen  Wanfer 
202-205-3363 


Figure  4-1 

Oyee:  U.$.  production.  1986-90 


Millions 
of  kilograms 


140 


1986  1987  1988  1989  1990 

Sourca:  Compiled  from  data  rac«iv»d  in  rsspons*  to  qusstionnair^s  of  the  U.S.  International  Trade  Commission. 


4-1 


Section  4 

Table  4-1 

Dyes:  U.S.  production  and  sales,  1990 


Dyes 


Production 


Sales 


Quantity 


Value 


Average 

Unit 

value' 


1.000 
kilograms 

Grand  total 117,135 

Acid  dyes 

Total 7.309 

Acid  yellow  dyes   1 ,91 4 

Acid  orange  dyes    657 

Acid  red  dyes,  total   990 

Acid  violet  dyes  26 

Acid  blue  dyes 1 .91 0 

Acid  Blue  324 564 

All  other  acid  blue  dyes  1 .346 

Acid  green  dyes 115 

Acid  brown  dyes    627 

Acid  black  dyes  1 .070 

Basic  dyes  (classical  and  modified) 

Total  5.991 

Basic  yellow  dyes 2.027 

Basic  orange  dyes 299 

Basic  red  dyes 650 

Basic  violet  dyes,  total 1.410 

Basic  Violet  3 574 

Basic  violet  16   96 

All  other  basic  violet  dyes 740 

Basic  blue  dyes 968 

All  other  basic  dyes 637 

Direct  dyes 

Total  20.235 

Direct  yellow  dyes  7,685 

Direct  orange  dyes 614 

Direct  red  dyes,  total  3,347 

Direct  Red  254 1 ,01 6 

All  other  direct  red  dyes 2,331 

Direct  violet  dyes 1 09 

See  tootnotes  at  end  ot  table. 


1.000 
kilograms 

103,897 


6,295 


4,936 


18,660 


7.358 
523 

3.084 


929 
2.155 


1.000 
dollars 

775,352 


82,533 


72,912 


120.127 


38,512 
3.677 

23.619 


5.709 
17.910 

1.383 


Per 
kilogram 

$7.46 


13.11 


1.532 

17,624 

11.51 

575 

5,245 

9.12 

841 

12.452 

14.81 

26 

596 

22.51 

1,787 

28,807 

16.12 

545 

9.041 

16.60 

1,242 

19,766 

15.91 

115 

1,547 

13.42 

526 

6,786 

12.91 

893 

9.476 

10.62 

14.77 


1.087 
268 

15.500 
3.215 

14.26 
11.99 

645 

9.036 

14.01 

1,409 

15,250 

10.82 

587 
115 
707 

5,287 
1,895 
8,068 

9.01 
16.41 
11.41 

1,004 

18.099 

18.03 

523 

11,812 

16.48 

6.43 


5.24 
7.03 


7.66 


6.15 
8.31 


12.24 


4-2 


Table  4-1 — Continued 

Dyes:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals,  1990 


Dyes 


Sales 

Average 
Unit 

Productiort 

Quantity 

Value 

value' 

1,000 
kilograms 

1,000 
kilograms 

1.000 
dollars 

Per 
kilogram 

Direct  dyes — Continued 

Direct  blue  dyes,  total    3,946 

Direct  Blue  80    1 90 

Direct  Blue  86    384 

Direct  Blue  98    121 

All  other  direct  blue  dyes  3,251 

Direct  green  dyes 27 

Direct  brown  dyes   136 

Direct  black  dyes,  total 4.371 

Direct  black  22 1 .891 

Direct  black  80 837 

All  other,  direct  black  1.643 

Disperse  dyes 

Total  17.776 

Disperse  yellow  dyes 1,113 

Disperse  orange  dyes   6.044 

Disperse  red  dyes,  total 3,867 

1  ■ 

Disperse  Red  167  and  167:1  485 

Disperse  Red  1 77    99 

All  other  disperse  red  dyes 3.283 

Disperse  violet  dyes 160 

Disperse  blue  dyes    5.043 

Disperse  black,  brown  and  green  dyes,  total 1 .549 

Disperse  Brown  1 335 

All  other  disperse  black,  brown,  and  green  dyes  ....  1 ,214 

FIber-reactlvc  dyes 

Total  13,010 

Fluorescent  brightening  agents 

Total  17.677 

See  footnotes  at  end  of  table. 


3,144 


25.479 


$8.10 


156 

338 

107 

2.543 

1,842 

2,411 

1,099 

20,127 

11.83 
7.13 

10.19 
7.92 

11 

191 

17.36 

130 

854 

6.26 

4.306 

26.412 

6.13 

2,073 

819 

1,414 

8,928 
5,937 
11,547 

4.31 
7.25 
8.16 

15,151 


791 
5,502 
3.160 


492 

125 

2.543 

133 
4.361 

1,204 


324 
880 


9,635 


17.879 


110.805 


9.294 
10,436 
27,804 


1,891 

1.672 

24.241 

3.*51 
49,945 

9,875 


2,978 
6.897 


112,427 


75.298 


7.31 

11.75 

1.90 

8.80 

3.84 

13.42 

9.53 

25.95 

11.45 

8.20 

9.20 
7.84 

11.67 

4.21 


4-3 


Section  4 

Table  4-1 — Continued 

Dyes:  U.S.  production  and  sales,  1990 


Dyes 


Production 


Sales 


Quantity 


Value 


Average 
Unit 
value ' 


1.000 
kilograms 


1.000 
kilograms 


1,000 
dollars 


Per 
kitogram 


Food,  drug,  and  cosmetic  colors 

Total   3,747 

Food,  drug  and  cosmetic  dyes 3,086 

Drug  and  cosmetic  dyes 661 

Mordant  dyes 

Total   9 

Solvent  dyes 

Total  6.032 

Solvent  yellow  dyes 986 

Solvent  orange  dyes   98 

Solvent  red  dyes   1 ,488 

Solvent  violet  dyes 162 

Solvent  blue  dyes    2,181 

All  other  solvent  dyes 1,117 

Vat  dyes 

Total 13,353 

Vat  orange  dyes 88 

Vat  red  dyes 153 

Vat  violet  dyes  111 

Vat  blue  dyes 12.689 

Vat  green  dyes 69 

Vat  brown  dyes   101 

Vat  black  dyes 142 

All  other  dyes 

Total*    11,996 


3,596 


3.000 
596 


3,812 


12,716 


51 ,084 


39,137 
11,947 


234 


46,152 


52,899 


$14.21 


13.04 
20.03 


19.76 


12.11 


562 

10,572 

18.80 

127 

2.633 

20.72 

1,417 

15.808 

11.15 

72 

2,022 

28.22 

516 

8,299 

16.08 

1,118 

6,818 

6.10 

4.12 


85 

1.666 

19.55 

168 

3.499 

20.85 

127 

1,868 

14.68 

12.088 

42,783 

3.54 

44 

494 

11.24 

81 

1,174 

14.46 

123 

1,415 

11.48 

11,206 


50,881 


4.54 


'  Calculated  from  unrounded  figures. 

^  Reported  data  were  accepted  In  confiderx:e  and  may  not  be  published,  or  no  data  were  reported. 

^  The  data  include  external  drug  and  cosmetic  dyes. 

*  The  data  include  azoic  compositions,  azoic  coupling  components,  azoic  diazo  components  (bases  and  salts). 
sulfur  dyes,  and  miscellaneous  dyes.  Statistics  for  those  groups  of  dyes  may  not  be  published  separately  because 
publication  would  disclose  information  received  in  confidence. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


4-4 


Synthetic  Organic  Chemicals.  1990 


Table  4-2 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Dyes 


Separate         Manufacturers '  identHicatiort  codes 
statistics '         (according  to  list  in  table  4-3) 


Acid  dyes: Yes 

Acid  yellow  dyes:  Yes 

Acid  Yeltow  3   No 

Acid  Yellow  17  No 

Acid  Yellow  19   No 

Acid  Yeltow  23   No 

Acid  Yeltow  34   No 

Acid  Yellow  36    No 

Acid  Yellow  49   No 

Acid  Yellow  59   No 

Acid  Yeltow  65   No 

Acid  Yeltow  73   No 

Acid  Yeltow  114    No 

Acid  Yeltow  135    No 

Acid  Yellow  137   No 

Acid  Yeltow  151    No 

Acid  Yeltow  159    No 

Acid  Yeltow  1 74    No 

Acid  Yeltow  198    No 

Acid  Yeltow  200   No 

Acid  Yeltow  219    No 

Acid  Yeltow  226    No 

All  other  acid  yellow  dyes No 

Acid  orange  dyes:    Yes 

Acid  Orange  7    No 

Acid  Orange  8    No 

Acid  Orange  10    No 

Acid  Orange  24    , No 

Acid  Orange  60    No 

Acid  Orange  64    No 

Acid  Orange  89   No 

Acid  Orange  116 No 

Acid  Orange  1 28    No 

Acid  Orange  152    No 

Acid  Orange  156    , No 

Acid  Orange  161    No 

All  other  acid  orange  dyes  No 

Aad  red  dyes:   Yes 

Acid  Red  1   No 

Acid  Red  4  No 

Acid  Red  14  No 

Acid  Red  57  , No 

Acid  Red  73  No 

Acid  Red  87   No 

Acid  Red  88 No 

Acid  Red  119   No 

Acid  Red  137  No 

Acid  Red  151    No 

Acid  Red  166   No 

Acid  Red  182  No 

Acid  Red  226   No 

Acid  Red  266  No 

Acid  Red  278   No 

Acid  Red  296   No 

Acid  Red  299   No 

Acid  Red  337  No 

Acid  Red  364   No 

Acid  Red  384   No 

Acid  Red  388   No 

Acid  Red  400   No 

Acid  Red  410  No 

Acid  Rod  418  No 

Acid  Red  419  No 


BAS. 

ATL,  CK,  (2). 

CK 

BAS.  CK.  DGO.  LVR.  WJ.  (2). 

ATL. 

ATL. 

ATL.  CK.  FAB. 

BAS.  CK. 

ATL.  CK. 

DGO. 

ICI. 

CK. 

CK. 

CK. 

FAB. 

CK. 

CK. 

CK. 

BAS. 

CK. 

BAS.  CK. 

ATL.  BAS,  CK. 

ATL,  CK. 

CK,  FAB. 

CK. 

ATL. 

BAS. 

CK. 

CK. 

CK. 

CK.  S. 

ATL. 

CK. 

ATL.  CK.  FAB. 

ATL.  FAB. 

ATL. 

CK. 

PSC,  S 

(2). 

FAB. 

CK 

ATL.  BAS. 

CK. 

FAB. 

CK.  VPC. 

BAS. 

CK. 

CK. 

BAS. 

CK 

ATL.  CK,  FAB. 

CK. 

CK. 

CK. 

ATL. 

ATL. 

CK. 

CK. 


See  footnotes  at  end  of  table. 


4-S 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Dyes  statistics'  (according  to  list  in  table  4-3) 

Acid  dyes-Continued 
Acid  red  dyes-Continued 

All  other  acid  red  dyes  No  BAS,  OK. 

Acid  violet  dyes: Yes 

Acid  Violet  3 No  FAB. 

Acid  Violet  7 No  FAB. 

Acid  Violet  12 No  FAB. 

Acid  Violet  17 No  (2). 

Acid  Violet  49 No  (^. 

Acid  blue  dyes: Yes 

Acid  Blue  9 No  BAS,  WJ.  ('). 

Acid  Blue  15 No  BAS. 

Acid  Blue  25 No  VPC. 

Acid  Blue  29 No  FAB. 

Acid  Blue  40 No  CK. 

Acid  Blue  41  No  CK. 

Acid  Blue  62 No  CK. 

Acid  Blue  67 No  BAS. 

Acid  Blue  92 No  FAB. 

Acid  Blue  113 No  CK. 

Acid  Blue  118 No  ATI. 

Acid  Blue  231  No  CK. 

Acid  Blue  281  No  CK. 

Acid  Blue  283 No  S. 

Acid  Blue  298 No  CK. 

Acid  Blue  321  No  ATL. 

Acid  Blue  324 Yes  CK.  S.  VPC. 

Acid  Blue  330 No  ATL. 

All  other  acid  blue  dyes  No  CK. 

Acid  green  dyes: Yes 

Acid  Green  1    No  LVR. 

AcidGreenie    No  LVR. 

Acid  Green  20    No  ATL.  FAB. 

Acid  Green  25    No  CK. 

All  other  acid  green  dyes  No  CK. 

Acid  brown  dyes:  Yes 

Acid  Brown  14   No  CK. 

Acid  Brown  19   No  CK. 

Acid  Brown  50   No  BAS. 

Acid  Brown  96   No  FAB. 

Acid  Brown  97   No  BAS.  FAB. 

Acid  Brown  98   No  FAB. 

Acid  Brown  147   No  CK. 

Acid  Brown  159   No  BAS. 

Acid  Brown  160   No  BAS. 

Acid  Brown  161    No  BAS. 

Acid  Brown  165   No  BAS. 

AcidBrown188   No  CK. 

Acid  Brown  189   No  CK. 

Acid  Brown  227   No  BAS. 

Acid  Brown  239    No  CK. 

Acid  Brown  264    No  BAS. 

Acid  Brown  439    No  CK. 

All  other  acid  brown  dyes No  CK. 

Acid  black  dyes: Yes 

Acid  Black  1   No  CK. 

Acid  Black  2  No  ATL.  LVR. 

Acid  Black  52 No  CK.  S. 

Acid  Black  60 No  CK. 

AckJ  Black  63 No  BAS. 

Acid  Black  92 No  FAB. 


See  footnotes  at  end  of  table. 


4-6 


Synthetic  Organic  Chemicals,  1990 

Table  4-2 — Continued 

Dyes  (or  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer,  1990 

Separate         Manufacturers'  iderytification  codes 

Dyes  statistics '         (according  to  list  in  table  4-3) 

Acid  dyes-Continued 
Acid  black  dyes-Continued 

Acid  Black  107 No  OK. 

Acid  Black  172  No  OK. 

Acid  Black  194 No  BAS. 

Acid  Black  210  No  BAS. 

All  other  acid  black  dyes No  BAS. 

Azoic  dyes  and  components: No 

Azoic  compositions: No 

Azoic  yellow  compositions: No 

Azoic  Yellow  1 No  BUG. 

Azoic  red  compositions: No 

Azoic  Red  1    No  BUG. 

Azoic  Red  2    No  BUG. 

Azoic  Red  6    No  BUG. 

All  other  azoic  red  compositions No  BUG. 

Azoic  violet  compositions:    No 

Azoic  Violet  1    No  BUG. 

All  other  azoic  violet  compositions  No  BUG. 

Azoic  blue  compositions:   No 

Azoic  Blue  3  No  BUG. 

Azoic  brown  compositions: No 

Azoic  Brown  9 No  BUG. 

Azoic  black  compositions:   No 

Azoic  Black  4   No  BUG. 

All  other  azoic  black  compositbns   No  BUG. 

Azoic  diazo  components,  bases:  No 

Azoic  Oiazo  Component  5,  base   No  All. 

Azoic  Diazo  Component  13.  base   No  All. 

Azoc  Diazo  Component  32.  base   No  All. 

All  other  azoic  diazo  components,  base No  All. 

Azoc  diazo  components,  salts:  No 

Azoc  Diazo  Component  1 ,  salt    No  All,  BUG. 

Azoc  Diazo  Component  3,  salt    No  BUG. 

Azok:  Diazo  Component  5,  salt    No  All,  BUG. 

Azoic  Diazo  Component  8,  salt   No  All,  BUG. 

Azoic  Diazo  Component  9,  salt    No  All,  BUG. 

Azoic  Diazo  Component  10,  salt    No  BUG. 

Azoc  Diazo  Component  12,  salt   No  All,  BUG. 

Azoc  Diazo  Component  13,  salt   No  All.  BUG. 

Azoic  Diazo  Component  32,  salt    No  ATL. 

Azoic  Diazo  Component  48,  salt    No  ATL. 

All  other  azok:  diazo  components,  salt No  All. 

Azok;  coupling  components:    No 

Azok:  Coupling  Component  2 No  All. 

Azoic  Coupling  Component  12 No  All. 

Azok:  Coupling  Component  14 No  All. 

Azok:  Coupling  Component  18 No  All. 

Azok:  Coupling  Component  20 No  PGW. 

Azoic  Coupling  Component  29 No  PGW. 

Basic  dyes  (classical  and  modified): Yes 

Bask:  yellow  dyes:    Yes 

Basic  Yellow  11 No  ATL,  GK. 

Basic  Yeltow  15 No  GK. 

Basic  Yeltow  28 No  BAS.  VPG. 

Basic  Yeltow  29 No  BAS. 

Basic  Yeltow  53 No  GK. 

Basic  Yeltow  58 No  VPG. 

Basic  Yeltow  65 No  BAS. 

Basic  Yeltow  78 No  BAS. 

Basic  Yeltow  79 No  GK. 


See  footnotes  at  end  of  table 


4-7 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  ideritification  codes 

Dyes  statistics '  (accordirtg  to  list  in  table  4-3) 

Basic  dyes  (classical  and  modlfled)-Contlnued 
Basic  yellow  dyes-Continued 

Basic  Yellow  83   No  OK. 

Basic  Yellow  94   No  S. 

Basic  Yellow  96   No  BAS. 

Basic  Yellow  98   No  BAS. 

Basic  Yellow  102    No  BAS. 

All  other,  basic  yellow  dyes No  BAS. 

All  other  basic  yellow  dyes,  modified  No  (^. 

Basic  orange  dyes: Yes 

Basic  Orange  1 No  ATL.  BAS,  OK. 

Basic  Orange  2 No  ATL.  BAS,  PSC. 

Basic  Orange  21 No  ATL.  VPC. 

Basic  Orange  26 Ho  OK. 

All  other  basic  orange  dyes   No  BAS,  (^). 

Basic  red  dyes:    Yes 

Basic  Red  12   No  ATL.  VPC. 

Basic  Red  14   No  ATL.  BAS.  CK. 

Basic  Red  15   No  ATL.  BAS.  CK. 

Basic  Red  17   No  CK. 

Basic  Red  29   No  BAS. 

Basic  Red  46   No  CK. 

Basic  Red  49   No  BAS. 

Basic  Red  54   No  BAS. 

Basic  Red  73   No  CK. 

Basic  Red  104  No  CK. 

Basic  Red  111 No  S. 

All  other,  basic  red  dyes No  BAS,  (*). 

Basic  violet  dyes: Yes 

Basic  Violet  1    No  BAS.  DSC. 

Basic  Violet  3  No  BAS.  CK.  DSC. 

Basic  Violet  4  No  BAS.  DSC. 

Basic  Violet  10  No  BAS. 

Basic  Violet  16  Yes  ATL.  CK,  VPC. 

Basic  Violet  35  No  BAS. 

All  other  basic  violet  dyes No  BAS,  (^). 

Basic  blue  dyes: Yes 

Basic  Blue  1  No  BAS. 

Basic  Blue  3 No  BAS,  CK. 

Basic  Blue  7 No  DSC. 

Basic  Blue  10 No  BAS. 

Basic  Blue  21   No  CK. 

Basic  Blue  41   No  BAS. 

Basic  Blue  60 No  BAS. 

Basic  Blue  77 No  CK. 

Basic  Blue  94  and  94:1 No  CK. 

Basic  Blue  140 No  S,  VPC. 

Basic  Blue  152 No  BAS. 

All  other  basic  blue  dyes No  BAS.  (*). 

All  other  basic  blue  dyes,  modified No  BAS. 

Basic  green  dyes: Yes 

Basic  Green  1 No  BAS. 

Basic  Green  4 No  fi. 

All  other  basic  green  dyes   No  BAS. 

Basic  brown  dyes:  Yes 

Basic  Brown  1    No  PSC. 

Basic  Brown  4    No  BAS.  PSC. 

All  other  basic  brown  dyes No  BAS. 

Basic  black  dyes: Yes 

Basic  Black  1    No  (f). 

All  other  basic  black  dyes No  BAS.  (2). 


See  footnotes  at  end  of  table. 
4-8 


Synthetic  Organic  Chemicals,  1990 

Table  4-2 — Continuad 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers' identification  codes 

Dyes  statistics '  (according  to  list  in  table  4-3) 

Basic  dyes  (classical  and  modlfied)-Continued 
Basic  black  dyes-Continued 

All  other  modified  basic  black  dyes  No  BAS. 

Direct  dyes:  Yes 

Direct  yellow  dyes: Yes 

Direct  Yeltow  4  No  BAS.  CK,  LVR,  VPC. 

Direct  Yellow  5  No  BAS. 

Direct  Yeltow  6  No  VPC. 

Direct  Yellow  11    No  BAS,  VPC. 

Direct  Yellow  28  No  CK. 

Direct  Yeltow  34  No  CK. 

Direct  Yeltow  44  No  CK. 

Direct  Yeltow  51    No  S. 

Direct  Yeltow  105  No  CK. 

Direct  Yeltow  106   No  CK. 

Direct  Yeltow  107 No  CK. 

Direct  Yeltow  118   No  CK. 

Direct  Yellow  119   No  VPC. 

Direct  Yeltow  127  No  BAS,  CK.  S.  VPC. 

Direct  Yeltow  131    No  VPC. 

Direct  Yeltow  132  No  S. 

Direct  Yeltow  133  No  S. 

Direct  Yeltow  137  No  VPC. 

Direct  Yeltow  147 No  BAS.  VPC. 

Direct  Yeltow  148  No  S. 

Direct  Yeltow  154  No  VPC. 

All  other  direct  yeltow  dyes No  ATL.  BAS.  CK. 

Direct  orange  dyes:  Yes 

Direct  Orange  15   No  VPC. 

Direct  Orange  26   No  CK. 

Direct  Orange  34  No  FAB. 

Direct  Orange  39  No  CK. 

Direct  Orange  72   No  CK. 

Direct  Orange  80   No  ATL. 

Direct  Orange  102   No  BAS.  VPC. 

Direct  Orange  118    No  S. 

All  other  direct  orange  dyes No  ATL.  BAS. 

Direct  red  dyes:  Yes 

Direct  Red  9 No  CK. 

Direct  Red  16 No  ATL.  FAB. 

Direct  Red  24 No  ATL.  FAB. 

Direct  Red  26 No  ATL. 

Direct  Red  72 No  CK. 

Direct  Red  73 No  ATL. 

Direct  Red  80 No  ATL.  CK. 

Direct  Red  81   No  ATL,  CK.  FAB,  VPC. 

Direct  Red  83 No  ATL,  CK,  FAB. 

Direct  Red  224 No  CK. 

Direct  Red  227 No  ATL. 

Direct  Red  236 No  BAS.  VPC. 

Direct  Red  238 No  VPC. 

Direct  Red  239 No  BAS,  CK,  S. 

Direct  Red  254 Yes  BAS,  CK,  VPC. 

All  other  direct  red  dyes  No  ATL.  BAS.  CK.  VPC. 

Direct  vtolet  dyes: Yes 

Direct  Vtolet  9 No  ATL. 

Direct  Violet  66 No  ATL. 

Direct  Violet  99 No  VPC. 

Direct  Violet  1 95 No  CK. 

All  other  direct  violet  dyes No  BAS. 


See  footnotes  at  end  of  table. 


4-9 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Dyes  statistics '         (according  to  list  in  table  4-3) 

Direct  dyes-Continued 

Direct  blue  dyes:    Yes 

Direct  Blue  15 No  VPC. 

Direct  Blue  25 No  ATL.  FAB. 

Direct  Blue  75 No  OK.  S. 

Direct  Blue  76 No  OK. 

Direct  Blue  80 No  ATL.  OK,  FAB. 

Direct  Blue  86 No  OK.  S.  VPC. 

Direct  Blue  98 No  ATL.  OK.  FAB. 

Direct  Blue  100 No  FAB. 

Direct  Blue  108 No  ATL. 

Direct  Blue  1 20. 1 20:1 . 1 20:2.  and  1 20:3 No  FAB. 

Direct  Blue  160 No  CK. 

Direct  Blue  189 No  CK. 

Direct  Blue  191 No  CK. 

Direct  Blue  199 No  BAS,  S.  VPC. 

Direct  Blue  218 No  CK.  FAB,  VPC. 

Direct  Blue  269 No  VPC. 

Direct  Blue  279 No  VPC. 

Direct  Blue  281 No  VPC. 

Direct  Blue  283 No  ATL. 

Direct  Blue  285 No  ATL. 

Direct  Blue  286 No  ATL. 

All  other  direct  blue  dyes   No  ATL.  BAS.  S.  VPC. 

Direct  green  dyes:  Yes 

Direct  Green  92   No  ATL. 

All  other  direct  green  dyes  No  FAB. 

Direct  brown  dyes: Yes 

Direct  Brown  44  No  FAB. 

Direct  Brown  231    No  ATL. 

Direct  Brown  232  No  ATL. 

All  other  direct  brown  dyes No  BAS.  FAB,  VPC. 

Direct  blacit  dyes: Yes 

Direct  Black  22 Yes  ATL.  CK.  FAB. 

Direct  Black  80 Yes  ATL,  CK.  FAB. 

Direct  Black  163 No  S. 

Direct  Black  165 No  ATL. 

Direct  Black  170 No  ATL. 

Direct  Black  179 No  CK. 

All  other  direct  black  dyes No  ATL.  BAS,  CK,  FAB.  VPC. 

Disperse  dyes: 

Disperse  yeltow  dyes:    Yes 

Disperse  Yellow  3 No  CK.  FAB. 

Disperse  Yellow  23 No  ATL.  CK. 

Disperse  Yeltow  34 No  EKT. 

Disperse  Yeltow  42 No  CK.  S. 

Disperse  Yellow  54 No  BAS. 

Disperse  Yelkjw  64 No  BAS.  HCL. 

Disperse  Yellow  77 No  VPC. 

Disperse  Yellow  86 No  CK.  EKT 

Disperse  Yellow  88 No  EKT. 

Disperse  Yellow  108 No  EKT. 

Disperse  Yellow  114 No  HCL. 

Disperse  Yellow  1 26 No  ICI. 

Disperse  Yellow  198 No  BAS. 

Disperse  Yellow  219 No  S. 

Disperse  Yeltow  238 No  CK. 

Disperse  Yellow  239 No  CK. 

All  other  disperse  yellow  dyes   No  BAS.  ICI.  VPC. 

See  footnotes  at  end  of  table. 


4-10 


Synthetic  Organic  Chemicals.  1990 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers'  identification  codes 
Dyes                                                                                    statistics '         (according  to  list  in  table  4-3) 

Disperse  dyes-Continued 

Disperse  orange  dyes: 

Disperse  Orange  3 No  ATL.  OK. 

Disperse  Orange  25  and  25:1    No  ATL,  OK.  ICI. 

Disperse  Orange  29 No  OK. 

Disperse  Orange  30 No  ATL.  BUG,  OK,  S,  SDC. 

Disperse  Orange  37 No  ATL.  CK,  EKT. 

Disperse  Orange  41  No  CK,  EKT.  S. 

Disperse  Orange  44  and  44:1    No  ATL.  CK.  EKT. 

Disperse  Orange  73 No  ATL,  BAS. 

Disperse  Orange  89 No  CK. 

Disperse  Orange  94 No  S. 

Disperse  Orange  138 No  EKT. 

Disperse  Orange  153 No  CK. 

Disperse  red  dyes: Yes 

Disperse  Red  1 No  ATL.  CK. 

Disperse  Red  5 No  ATL.  CK. 

Disperse  Red  13 No  ATL. 

Disperse  Red  17 No  ATL,  CK. 

Disperse  Red  22 No  MRT 

Disperse  Red  30 No  EKT. 

Disperse  Red  50 No  CK. 

Disperse  Red  55 No  BAS. 

Disperse  Red  60 No  BAS. 

Disperse  Red  65 No  CK. 

Disperse  Red  73 No  ATL,  CK,  S. 

Disperse  Red  74 No  S. 

Disperse  Red  86 No  S.  SDC. 

Disperse  Red  88 No  EKT. 

Disperse  Red  91 No  BAS,  EKT 

Disperse  Red  117 No  EKT. 

Disperse  Red  135 No  CK. 

Disperse  Red  136 No  EKT. 

Disperse  Red  137 No  EKT. 

Disperse  Red  145 No  CK. 

Disperse  Red  153 No  CK,  FAB,  S. 

Disperse  Red  159 No  VPC. 

Disperse  Red  167  and  167:1   Yes  ATL.  CK.  EKT.  S. 

Disperse  Red  177 Yes  CK.  ICI,  S. 

Disperse  Red  179 No  BAS,  CK,  S. 

Disperse  Red  263 No  BAS. 

Disperse  Red  273 No  S. 

Disperse  Red  274 No  S. 

Disperse  Red  278 No  ICI. 

Disperse  Red  307 No  EKT. 

Disperse  Red  311 No  ICI. 

Disperse  Red  313 No  S. 

Disperse  Red  316 No  S. 

Disperse  Red  325 No  CK. 

Disperse  Red  333 No  S. 

Disperse  Red  338 No  EKT. 

Disperse  Red  339 No  EKT. 

Disperse  Red  340 No  EKT. 

Disperse  Red  345 No  CK. 

Disperse  Red  358 No  HCL. 

All  other  disperse  red  dyes No  BAS,  SDC. 

Disperse  violet  dyes:   Yes 

Disperse  Violet  1    I^o  CK. 

Disperse  Violet  17    No  CK. 

Disperse  Violet  28   No  CK. 

Disperse  Violet  33   No  ICI.  S. 


See  footnotes  at  end  of  table. 


4-11 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Dyes 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  4-3} 


Disperse  dyes-Continued 
Disperse  violet  dyes-Continued 

Disperse  Violet  36   No 

Disperse  Violet  48    No 

Disperse  Violet  60    No 

All  other  disperse  violet  dyes  No 

Disperse  blue  dyes: Yes 

Disperse  Blue  1    No 

Disperse  Blue  3   No 

Disperse  Blue  14   No 

Disperse  Blue  27   No 

Disperse  Blue  60   No 

Disperse  Blue  62   No 

Disperse  Blue  64   No 

Disperse  Blue  73   No 

Disperse  Blue  79   No 

Disperse  Blue  95   No 

Disperse  Blue  102   No 

Disperse  Blue  106   No 

Disperse  Blue  118    No 

Disperse  Blue  148   No 

Disperse  Blue  175   No 

Disperse  Blue  183   No 

Disperse  Blue  200   No 

Disperse  Blue  281    No 

Disperse  Blue  284   No 

Disperse  Blue  291    No 

Disperse  Blue  333   No 

Disperse  Blue  337   No 

Disperse  Blue  359   No 

All  other  disperse  blue  dyes No 

Disperse  green  dyes: No 

Disperse  Green  9 No 

Disperse  brown  dyes: No 

Disperse  Brown  1 No 

Disperse  Brown  18 No 

Disperse  Brown  22 No 

Disperse  Brown  26 No 

Disperse  Brown  27 No 

Disperse  black  dyes:   No 

Disperse  Black  9    No 

All  other  disperse  black  dyes  No 

Fiber-reactive  dyes:   Yes 

Reactive  yellow  dyes: No 

Reactive  Yellow  17 No 

Reactive  Yellow  18 No 

Reactive  Yellow  37 No 

Reactive  Yellow  86 No 

Reactive  Yellow  125 No 

Reactive  Yellow  135 No 

Reactive  Yellow  1 60 No 

All  other  reactive  yeltow  dyes No 

Reactive  orange  dyes: No 

Reactive  Orange  1   No 

Reactive  Orange  4 No 

Reactive  Orange  12 No 

Reactive  Orange  13 No 

Reactive  Orange  16 No 

Reactive  Orange  20 No 

Reactive  Orange  72 No 

Reactive  Orange  78 No 


S. 

HCL. 
S. 
CK. 

OK. 

CK.  EKT. 

CK. 

EKT. 

BAS. 

EKT. 

EKT. 

S. 

BAS,  BUC,  ICI,  S. 

HCL. 

CK.  EKT 

CK. 

EKT. 

BAS. 

CK. 

S. 

ICI. 

S. 

ICI. 

CK.  S. 

HCL. 

EKT. 

CK. 

ATL.  BAS,  BUC.  HCL.  ICI.  SDC. 

iCI. 

ATL.  BUC.  CK.  S.  SDC. 

S. 

EKT. 

CK. 

CK. 

ATL,  CK.  EKT.  FAB. 
BAS.  SDC. 


HCL. 

ICI. 

HCL. 

ICI. 

S. 

ICI. 

HCL. 

HCL. 

ICI. 

ICI. 

ICI. 

ICI. 

ATL.  CK.  HCL. 

CK. 

CK. 

HCL. 


See  footnotes  at  end  of  table. 


4-12 


Synthetic  Organic  Chemicals.  1990 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  ider\tification  codes 

Dyes  statistics '         (according  to  list  in  table  4-3) 

Fiber-reactive  dyes-Continued 
Reactive  orange  dyes-Continued 

Reactive  Orange  84 No  101. 

Reactive  Orange  86  No  101. 

All  other  reactive  orange  dyes  No  HOL. 

Reactive  red  dyes: No 

Reactive  Red  2 No  OK,  101. 

Reactive  Red  11  No  101. 

Reactive  Red  21 No  HOL. 

Reactive  Red  31 No  iOI. 

Reactive  Red  43 No  OK.  ICI. 

Reactive  Red  49 No  HOL. 

Reactive  Red  94 No  HOL. 

Reactive  Red  120 No  ATL.  OK.  iOI.  S. 

Reactive  Red  141 No  IOI. 

Reactive  Red  1 47 No  S. 

Reactive  Red  1 80 No  HOL. 

Reactive  Red  1 98 No  ATL. 

Realtive  Red  35  No  HOL. 

All  other  reactive  red  dyes  No  ATL.  OK,  HOL. 

Reactive  violet  dyes:   No 

Reactive  Violet  1 No  ICI. 

Reactive  Violet  5 No  HOL. 

Reactive  Violet  33 No  S. 

All  other  reactive  violet  dyes No  HOL.  IOI. 

Reactive  blue  dyes:  No 

Reactive  Blue  3    No  IOI. 

Reactive  Blue  4    No  OK.  iOI. 

Reactive  Blue  7    No  OK. 

Reactive  Blue  19    No  HOL. 

Reactive  Blue  21    No  HOL. 

Reactive  Blue  28    No  OK. 

Reactive  Blue  38    No  HOL. 

Reactive  Blue  41    No  S. 

Reactive  Blue  71    No  IOI. 

Reactive  Blue  89    No  IOI. 

Reactive  Blue  1 99    No  IOI. 

All  other  reactive  blue  dyes   No  HOL.  IOI. 

Reactive  green  dyes: No 

Reactive  Green  19 No  ICI. 

Reactive  brown  dyes: No 

Reactive  Brown  1  No  IOI. 

Reactive  Brown  17 No  IOI. 

Reactive  Brown  18 No  HOL. 

All  other  reactive  brown  dyes No  HOL. 

Reactive  black  dyes:    No 

Reactive  Black  5 No  ATL.  OK.  HOL.  S. 

Reactive  Black  9 No  ICI. 

All  other  reactive  black  dyes No  HOL. 

Fluorescent  brighteners:    Yes 

Fluorescent  Brightener  28   No  VPO. 

Fluorescent  Brightener  49    No  S. 

Fluorescent  Brightener  52   No  S. 

Fluorescent  Brightener  61    No  BAS. 

Fluorescent  Brightener  71    No  VPC. 

Fluorescent  Brightener  130    No  BAS. 

Fluorescent  Brightener  205    No  VPC. 

Fluorescent  Brightener  231    No  S. 

Fluorescent  Brightener  232   No  S. 

Fluorescent  Brightener  290   No  S. 

All  other  fluorescent  brighteners No  S.  VPC,  (*). 


See  footnotes  at  end  of  table 


4-13 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separata         Manufacturors' identification  codes 

Dyes  statistics '         (according  to  list  in  table  4-3) 

Food,  drug,  and  cosmetic  colors: Yes 

Food,  drug,  and  cosmetic  dyes; Yes 

Food,  Drug,  and  Ck)smetic  Blue  1    No  WJ. 

Food,  Drug,  and  Cosmetic  Blue  2   No  WJ,  0. 

Food,  Drug,  and  Cosmetic  Green  3 No  WJ. 

Food,  Drug,  and  Cosmetic  Red  3 No  WJ. 

Food,  Drug,  and  Cosmetic  Red  4 No  CK. 

Food.  Drug,  and  Cosmetic  Red  40 No  WJ.  ('). 

Food,  Drug,  and  Cosmetic  Yellow  5 No  WJ. 

Food,  Drug,  and  Cosmetic  Yellow  6 No  CK.  WJ,  (2). 

Drug  and  cosmetic  dyes: Yes 

Drug  And  Cosmetic  Red  57:1 No  SNA. 

Drug  And  Cosmetic  Red  63 No  SNA. 

Drug  And  Cosmetic  Red  11    No  SNA. 

Drug  and  Cosmetic  Green  5 No  CK. 

Drug  and  Cosmetic  Green  8 No  (^. 

Drug  and  Cosmetic  Orange  4 No  CK. 

Drug  and  Cosmetic  Orange  5 No  CCG,  SNA. 

Drug  and  Cosmetic  Red  3   No  CCG. 

Drug  and  Cosmetic  Red  6   No  CCG.  SNA.  {^). 

Drug  and  Cosmetic  Red  7   No  CCG.  SNA.  {% 

Drug  and  Cosmetic  Red  17   No  WJ. 

Drug  and  Cosmetic  Red  21    No  CCG.  SNA. 

Drug  and  Cosmetic  Red  27   No  CCG.  SNA.  {'). 

Drug  and  Cosmetic  Red  30   No  CCG.  SNA. 

Drug  and  Cosmetic  Red  33   No  CCG.  CK,  SNA. 

Drug  and  Cosmetic  Red  34   No  CCG,  SNA. 

Drug  and  Cosmetic  Red  36   No  SNA. 

Drug  and  Cosmetic  Yellow  5    No  CCG. 

Drug  and  Cosmetic  Yellow  10    No  CK.  (^. 

Drug  and  cosmetic  dyes,  external: No 

External  Drug  and  Cosmetic  Orange  3 No  CK. 

Ingrain  dyes:   No 

inorain  blue  dyes: No 

Ingrain  Blue  2 No  WJ. 

Mordant  dyes:  Yes 

Mordant  yellow  dyes: No 

Mordant  Yellow  16  No  ATL. 

Mordant  Yellow  20   No  FAB. 

Mordant  orange  dyes:   No 

Mordant  Orange  3    No  FAB. 

Mordant  Orange  6    No  ATL.  FAB. 

Mordant  brown  dyes: No 

Mordant  Brown  1    No  FAB. 

Mordant  Brown  70   No  FAB. 

Solvent  dyes: Yes 

Solvent  yellow  dyes: No 

Solvent  Yellow  3 No  PSC. 

Solvent  Yellow  13 No  BAS.  FAB. 

Solvent  Yellow  14 No  PSC. 

Solvent  Yellow  16 No  PSC. 

Solvent  Yellow  33 No  BAS,  CIC,  MRT 

Solvent  Yellow  40 No  CK. 

Solvent  Yellow  42 No  CK. 

Solvent  Yellow  43 No  HCL.  MRT 

Solvent  Yellow  56 No  PSC. 

Solvent  Yellow  72 No  CIC.  FAB,  PSC.  UCM. 

Solvent  Yellow  94 No  (^. 

Solvent  Yellow  107 No  MRT 

Solvent  Yellow  131  No  DGO. 

Solvent  Yellow  135 No  (^. 


See  footnotes  at  end  of  table. 


4-14 


Synthetic  Organic  Chemicals,  1990 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate         Manufacturers '  identification  codes 

Dyes  statistics '         (according  to  list  in  table  4-3) 

Solvent  dyes-Continued 
Solvent  yellow  dyes-Continued 

Solvent  Yellow  143 No  MRT. 

Solvent  Yellow  160 No  (^. 

Solvent  Yellow  161  No  MRT. 

Solvent  Yellow  167 No  GIG. 

All  other  solvent  yellow  dyes   No  ATL,  MIL.  MRT.  {'). 

Solvent  orange  dyes: Yes 

Solvent  Orange  2 No  PSG. 

Solvent  Orange  3 No  BAS,  PSG. 

Solvent  Orange  7 No  ATL.  PSG. 

Solvent  Orange  20 No  BAS.  GK.  FAB. 

Solvent  Orange  23 No  GK. 

Solvent  Orange  31  No  PSG. 

Solvent  Orange  60 No  GIG. 

Solvent  Orange  77 No  MRT 

Solvent  Orange  97 No  MRT. 

All  other  solvent  orange  dyes No  {'). 

Solvent  red  dyes: Yes 

Solvent  Red  1 No  PSG. 

Solvent  Red  23 No  PSG. 

Solvent  Red  24 No  PSG. 

Solvent  Red  26 No  PSG. 

Solvent  Red  27 No  PSG. 

Solvent  Red  49 No  BAS. 

Solvent  Red  68 No  ATL.  GK,  MRT 

Solvent  Red  111  No  MRT 

Solvent  Red  164 No  AG.  MRT  (^). 

Solvent  Red  166 No  MRT 

Solvent  Red  168 No  MRT 

Solvent  Red  169 No  MRT 

Solvent  Red  172 No  MRT 

Solvent  Red  1 75 No  MRT 

Solvent  Red  179 No  GIG. 

Solvent  Red  207 No  MRT 

Solvent  Red  208 No  MRT 

All  other  solvent  red  dyes No  ATL.  MIL.  PSG. 

Solvent  violet  dyes:   Yes 

Solvent  Violet  8 No  DSG. 

Solvent  Violet  9 No  DSG. 

Solvent  Violet  11 No  GK. 

Solvent  Violet  13 No  GK. 

Solvent  Violet  14 No  MRT 

Solvent  Violet  38 No  MRT 

All  other  solvent  violet  dyes  No  MIL. 

Solvent  blue  dyes:  Yes 

Solvent  Blue  3   No  PSG. 

Solvent  Blue  4   No  BAS. 

Solvent  Blue  5    No  DSG. 

Solvent  Blue  23   No  BAS. 

Solvent  Blue  35   No  AG.  MRT  UGM. 

Solvent  Blue  36   No  MRT 

Solvent  Blue  38   No  ATL.  TNI. 

Solvent  Blue  58    No  VPG. 

Solvent  Blue  59   No  MRT  VPG. 

Solvent  Blue  98   No  MRT 

Solvent  Blue  99   No  MRT 

Solvent  Blue  1 00   No  MRT 

Solvent  Blue  101    No  MRT 

Solvent  Blue  102    No  MRT 

Solvent  Blue  128    No  MRT 


See  footnotes  at  end  of  table. 


4-lS 


Section  4 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate         Manufacturers '  identification  codes 

Qyes  statistics '         (according  to  list  in  table  4-3) 

Solvent  dyes-Continued 
Solvent  blue  dyes-Continued 

Solvent  Blue  129   No  MRT. 

All  other  solvent  blue  dyes No  MIL. 

Solvent  green  dyes:  ,.^  ^.n-r 

Solvent  Green  3 No  CK,  MRT. 

Solvent  brown  dyes: No 

Solvent  Brown  12 No  PSC. 

Solvent  Brown  20 No  ATL. 

Solvent  Brown  22 No  PSC. 

Solvent  Brown  38 No  FAB. 

Solvent  Brown  52 No  MRT. 

Solvent  black  dyes:    No 

Solvent  Black  7 No  BAS.  OCC.  PSC. 

Solvent  Black  13 No  CK. 

Solvent  Black  26 No  FAB. 

Solvent  Black  46 No  MRT 

Solvent  Black  47 No  MRT 

Solvent  Black  49 No  MRT 

Sulfur  dyes:   No 

Sulfur  yellow  dyes: No 

Leuco  Sulfur  Yellow  22 No  SDC. 

All  other  sulfur  yellow  dyes No  SDC. 

Sulfur  orange  dyes:   No 

All  other  sulfur  orange  dyes No  SDC. 

Sulfur  red  dyes:   No 

Leuco  Sulfur  Red  14 No  SDC. 

Sulfur  Red  10 No  SDC. 

Sulfur  blue  dyes:   No 

Leuco  Sulfur  Blue  7   No  S,  SDC. 

Leuco  Sulfur  Blue  11    No  SDC. 

Leuco  Sulfur  Blue  20   No  S. 

Sulfur  green  dyes:    No 

Leuco  Sulfur  Green  2 No  SDC. 

Leuco  SuHur  Green  16 No  SDC. 

Leuco  Sulfur  Green  34 No  SDC. 

Leuco  SuHur  Green  35 No  SDC. 

Leuco  Sulfur  Green  36 No  SDC. 

Sulfur  brown  dyes: No 

Leuco  Sulfur  Brown  1.1:1    No  SDC. 

Leuco  Sulfur  Brown  3 No  SDC. 

Leuco  Sulfur  Brown  37 No  S,  SDC. 

Leuco  Sulfur  Brown  52 No  SDC. 

Sulfur  Brown  96  No  S. 

All  other  sulfur  brown  dyes No  SDC. 

Sulfur  black  dyes: No 

Leuco  SuHur  Black  1    No  SDC. 

Leuco  Sulfur  Black  2    No  S,  SDC. 

Leuco  Sulfur  Black  11.  11:1    No  SDC. 

Leuco  Sulfur  Black  18 No  SDC. 

Solubilized  Sulfur  Black  2 No  SDC. 

Sulfur  Black  2 No  SDC. 

Sulfur  Black  11, 11:1 No  SDC. 

Vat  dyes:    Yes 

Vat  orange  dyes: Yes 

Vat  Orange  1.  20% No  SDC. 

Vat  Orange  2,  12% No  BAS. 

Vat  Orange  7. 11% No  HCL. 

Vat  Orange  9.  12% No  BAS. 

Vat  red  dyes:   Yes 

Vat  Red  1.  13% No  BAS. 


See  footnotes  at  end  of  table. 


4-16 


Synthetic  Organic  Chemicals.  1990 

Table  4-2 — Continued 

Dyes  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate         Manufacturers '  ider}tification  codes 
Dyes  statistics '         (according  to  list  in  table  4-3) 

Vat  dyes-Continued 
Vat  red  dyes-Continued 

Vat  Red  10,  18% No  BAS. 

Val  Red  15,  10% No  HCL 

All  other  vat  red  dyes No  HCL. 

Vat  violet  dyes: Yes 

Vat  Violet  13,  6-1/4%   No  BAS.  SDC. 

Vat  blue  dyes: Yes 

Vat  Blue  1,  20%  No  BOO. 

Vat  Blue  6,  8-1/3%  No  BAS,  SDC. 

Vat  Blue  16.  16%  No  BAS. 

Vat  Blue  19 No  BAS. 

Vat  Blue  29 No  BAS. 

Vat  Blue  43 No  S.  SDC. 

Vat  Blue  66 No  BAS. 

All  other  vat  blue  dyes   No  SDC. 

Vat  green  dyes:    Yes 

Vat  Green  1.6% No  SDC. 

Vat  Green  3. 10% No  SDC. 

Vat  Green  7    No  SDC. 

Vat  brown  dyes:  Yes 

Vat  Brown  57. 12.8%  No  HCL 

All  other  vat  brown  dyes No  HCL. 

Vat  black  dyes: Yes 

Vat  Black  22.  19%    No  SDC. 

Vat  Black  25,  12-1/2%   No  BAS.  SDC. 

Vat  Black  63 No  S. 

Miscellaneous  dyes: No 

All  other  dyes  No  DAN,  MRT,  SDC. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  "yes.'  Chemk^als  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  t>y  'no.' 

^  The  manufacturer  did  not  consent  to  his  kjentification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commissbn. 


4-17 


Section  4 

Table  4-3 

Dyes:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  of  company 

tCI ICI  Americas,  Inc.,  Specialty  Chem  Div. 

LVR C.  Lever  Co.,  Inc. 

MIL  Milliken  &  Co.,  Milllken  Chemical  Div. 

MRT   Morton  International,  Inc.,  Specialty 

Chemicals 

OCC  Orient  Chemical  Corp. 

PCW Pfister  Chemical,  Inc. 

PSC Passaic  Color  &  Chemical  Co. 

PSG   PMC.  Inc.,  PMC  Specialities  Group,  Inc. 

S Sandoz  Chemical  Corp., 

SDC   Colors  &  Chemicals  Div. 

SNA Sun  Chemical  Corp.,  Pigments  Div. 

TNI   Gillette  Co.,  Chemical  Div. 

UCM United  Color  Manufacturing  Co. 

VPC Mobay  Chemical  Corp.,  Dyes  & 

Pigments  Div. 

WJ Warner-Jenkinson  Co. 


ALL   Alliance  Chemical,  Inc. 

ATL    Atlantic  Industries,  Inc. 

BAS BASF  Corp. 

BCC Buffalo  Color  Corp. 

BUC Synalloy  Corp.,  Blackman  Uhler 

Chemical  Div. 

CCG Clark  Color/HK  Color  Group 

CIC    Color  Chem  International  Corp. 

CK Crompton  &  Knowles  Corp. 

DAN Dan  River,  Inc.,  Chemical  Products  Div. 

DGO   Day-Glo  Color  Corp. 

DSC Dye  Specialties,  Inc. 

EKT Eastman  Kodak  Co.,  Tennessee 

Eastman  Co.  Div. 

FAB Fabriootor  Manufacturing  Corp. 

HCL Hoechst  Celanese  Corp.: 

Sou-Tex  Works 

Specialty  Chem  Group 


Note.— Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaire  of  the  U.S.  International  Trade  Commisskin. 


4-18 


Synthetic  Organic  Chemicals,  1990 


Section  5 
Organic  Pigments 

Organic  pigmenis  are  toners  and  lakes'  derived  in 
whole  or  in  part  from  benzenoid  chemicals  and  colors. 

Statistics  on  production  and  sales  of  all  organic 
pigments  in  1989  are  given  in  table  5-1.  Individual 
toners  and  lakes  are  identified  in  this  report  by  the 
names  used  in  the  third  edition  of  the  Colour  Index. 

Total  production  of  organic  pigments  in  1990  was 
52  million  kilograms,  4  percent  more  than  the  50 
milUon  kilograms  produc»J  in  1989.  Total  sales  of 
organic  pigments  in  1990  amounted  to  45  million 
kilogams,  valued  at  S717  million,  compared  with  43 
million  kilograms,  valued  at  $697  million,  in  1989.  In 
terms  of  quantity,  sales  of  organic  pigments  in  1990 
were  5  percent  higher  than  in  1989;  in  terms  of  value, 
sales  in  1990  were  3  percent  higher  than  in  1989. 
Changes  in  U.S.  production  of  pigments  have  followed 
overall  changes  in  U.S.  economic  activity  during 
1986-90  (see  figure  5-1). 


'  Toners  and  lakes  are  essentially  (he  same  in  their  fmal  form; 
they  differ  in  the  method  of  preparation.  A  lake  is  an  organic 
pigment  produced  by  the  interaction  of  a  soluble  dye,  a 
pecipitant,  and  an  absorptive  inorganic  substrate.  A  toner  is  an 
insoluble  dye  produced  as  a  powder,  some  toners  are  extended 
by  the  inclusion  of  a  solid  diluent. 


Production  of  toners  in  1990  accounted  for  99.4 
percent  of  total  pigment  production.  Changes  in  loner 
production  and  sales  mirrored  changes  in  production 
and  sales  of  total  pigments.  The  individual  loners  listed 
in  the  report  which  were  produced  in  the  largest 
quantities  in  1990  were  Pigment  Yellow  12,  Pigment 
Yellow  14,  Pigment  Red  48:1  barium  loner.  Pigment 
Red  49;  1  barium  toner.  Pigment  Red  53:1  barium  toner. 
Pigment  Red  57:1,  calcium  loner.  Pigment  Violet  19, 
Pigment  Blue  15:3,  beta  form,  and  Pigment  Green  7. 

Production  of  lakes  totaled  288,000  kilograms  in 
1990,  6  percent  lower  than  the  307,000  pounds 
reported  for  1989.  Sales  of  lakes  in  1990  amounted  to 
204,000  kilograms,  valued  at  $3.8  million.  In  terms  of 
quantity,  sales  of  lakes  in  1990  were  7  percent  lower 
than  in  1989;  in  terms  of  value,  sales  in  1990  were 
Mercent  higher  lower  than  in  1989. 

Table  5-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 

5-3. 

Stephen  Wanser 
202-205-3363 


Figure  5-1 

Organic  pigments:  U.S.  production,  1986-90 


Millions 
of  kilograms 


60- 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


5-1 


Section  5 

Table  5-1 

Organic  pigments:  U.S.  production  and  sales,  1990 


Organic  pigments 


Production 


Sales 


Quantity 


Value' 


Average 

Unit 

value' 


Grand  Total 

Toners 

Total  

Yellow  toners,  total 

Acetoacetarylide  yellows,  total 

Pigment  Yellow  3,  C.I.  11  710 

Pigment  Yellow  65,  C.I.  11  740 

Pigment  Yellow  74.  C.I.  11  741 

All  other  acetoacetarylide  yellows   

Diarylide  yellows,  total  

Pigment  Yellow  12.  C.I.  21  090    

Pigment  Yellow  13,  C.I.  21  100    

Pigment  Yellow  14.  C.I.  21  095    

Pigment  Yellow  17,  C.I.  21  105    

Pigment  Yellow  83,  C.I.  21  108    

All  other  yellow  toners   

Orange  toners,  total 

Pigment  Orange  5,  C.I.  21  075    

Pigment  Orange  13  

Pigment  Orange  16.  C.I.  21  160    

Pigment  Orange  34  

Pigment  Orange  46.  C.I.  15  602    

All  other  orange  toners 

Red  toners,  total    

Naphthol  reds,  total   

Pigment  Red  2,  C.I.  12  310   

Pigment  Red  17,  C.I.  12  390    

Pigment  Red  22,  C.I.  12  315    

Pigment  Red  23,  C.I.  12  355    

Pigment  Red  31   

All  other  naphthol  reds 

Other  red  toner,  total   

Pigment  Red  3.  C.I.  12  120   

Pigment  Red  4,  C.I.  1 2  085   

Pigment  Red  38,  C.I.  12  120   

Pigment  Red  48:1.  barium  toner.  C.I.  15  865  . 

Pigment  Red  48:2,  calcium  toner.  C.I.  15  865 

Pigment  Red  49:1,  barium  toner,  C.I.  15  630  . 


1,000 
Kilograms 
dry  basis^ 


1.000 
Kilogtams 
dry  basis^ 


1,000 
dollars 


52.551 

44,773 

717,194 

52.263 

44,569 

713,357 

14.176 

11.126 

137.826 

Per 
kilogram 

$16.01 


16.08 


12.39 


1.311 

809 

14.448 

17.86 

53 

44 

507 

11.40 

105 

104 

2.007 

19.32 

378 

376 

7.329 

19.48 

775 

285 

4,605 

16.17 

12.788 

10.255 

120.900 

11.79 

8,850 

6.663 

75.371 

11.31 

278 

236 

3,404 

14.41 

2.863 

2,612 

26.463 

10.13 

276 

261 

4.065 

15.57 

521 

483 

11.597 

24.03 

77 

62 

2,478 

39.97 

1,288 

1.099 

15,848 

14.42 

484 

327 

3,930 

12.03 

65 

60 

1,325 

22.07 

258 

247 

4,201 

16.99 

57 

45 

992 

22.23 

385 

382 

4,741 

12.42 

39 

38 

659 

17.38 

18,448 

16,754 

275,982 

16.47 

924 

885 

24.662 

27.87 

20 

22 

714 

32.58 

19 

8 

191 

22.56 

140 

141 

2,897 

20.52 

70 

89 

2,397 

27.02 

7 

6 

147 

26.11 

668 

619 

18.316 

29.57 

17.524 

15.869 

251 ,320 

15.83 

352 

330 

4,837 

14.64 

35 

39 

602 

15.51 

91 

78 

1.697 

24.18 

901 

985 

14.009 

14.22 

964 

1,014 

13,368 

13.19 

2,304 

2,060 

20,460 

9.93 

See  footnotes  at  end  of  table. 


5-2 


Table  5-1 — Continued 

Organic  pigments:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals.  1990 


Organic  pigments 


Sales 

Average 

Unit 
value^ 

Production 

Quantity 

Value' 

1,000 

1.000 

1.000 

Per 

Kilograms 

Kilogtams 

dollars 

kilogram 

dry  basis^ 

dry  basis^ 

461 

414 

5,438 

$13.12 

671 

650 

8,291 

12.75 

1.962 

1,902 

19,524 

10.26 

8.247 

6.251 

72,072 

11.53 

218 

221 

8,617 

39.08 

8 

7 

358 

50.80 

1,310 

1.918 

82.047 

42.56 

808 

1,362 

66.939 

49.15 

13 

13 

506 

38.27 

795 

1.349 

66,433 

49.25 

16,101 

12,829 

186,657 

14.55 

18 

15 

624 

40.84 

229 

269 

5,078 

18.87 

520 

506 

11,188 

22.13 

8,749 

7.129 

96,924 

13.60 

630 

502 

7.601 

15.13 

5.955 

4.408 

65.242 

14.80 

1.421 

1,378 

29,940 

21.73 

1,363 

1,314 

27,716 

21.09 

38 

43 

1,179 

27.45 

20 

21 

1,045 

48.93 

Red  toners — Continued 

Pigment  Red  49;2,  calcium  toner,  0.1.  15  630 
Pigment  Red  52:1,  calcium  toner,  C.I.  15  860 
Pigment  Red  53:1,  barium  toner,  C.I.  15  585  . 
Pigment  Red  57:1 ,  calcium  toner.  C.I.  15  850 

Pigment  Red  81 ,  PMA,  C.I.  45  160    

Pigment  Red  81  PTA  

All  other  red  toners 

Violet  toners,  total    

Pigment  Violet  1.  C.I.  45  170 

All  other  violet  toners 

Blue  toners,  total  

Pigment  Blue  1 ,  (PMA),  C.I.  42  595 

Pigment  Blue  15,  alpha  form,  C.I.  74  160   

Pigment  Blue  15:1,  alpha  form,  C.I.  74  160  . . . . 

Pigment  Blue  15:3,  beta  form,  C.I.  74  160 

Pigment  Blue  15:4.  beta  form.  C.I.  74  160 

All  other  blue  toners 

Green  toners,  total 

Pigment  Green  7,  C.I.  74  260    

Pigment  Green  36  

All  other  green  toners 

Brown  and  black  toners 

Lakes 

Total  

Pigment  Red  83,  C.I  58  000 

Pigment  Violet  5:1 ,  C.I.  58  055    

All  other  lakes   


21 


288 


21 


204 


165 


7.86 


3,837       18.81 


13 

17 

537 

34.20 

25 

25 

619 

24.76 

250 

162 

2,681 

16.33 

'  The  value  of  sales  for  toners  is  reported  on  a  dry-full  strength  basis  and  the  value  of  sales  for  lakes  is  reported 
on  a  dry  form  basis.  All  sales  value  data  exclude  the  additional  cost  of  processing  or  packaging  in  commercial  forms 
other  than  the  dry  full-strength  or  dry  form. 

^  Calculated  from  unrounded  figures. 

^  Quantities  for  toners  are  reported  as  dry  full-strength  toner  content,  excluding  the  weight  of  any  dispersing  agent, 
vehicle,  or  extender  Quantities  for  lakes  are  reported  as  dry  lake  content,  excluding  the  weight  of  any  dispersing 
agent  or  vehicle. 

Note. — The  C.I.  (Colour  Index)  number  shown  in  this  report  are  the  identifying  numt)er  given  in  the  third  edition  of  the 
Cotour  Index.  The  abtweviations  PMA  and  PTA  stand  for  phosphomolybdic  and  phosphotungstc  (including 
phosphotung-stomolybdic)  ackJs,  respectively. 

Source:  Compiled  from  data  received  in  response  to  questnnnaires  of  the  U.S.  International  Trade  Commission. 


5-3 


Section  5 

Table  5-2 

Organic  pigments  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Organic  pigments 


Separate 
statistics ' 


Manufacturers' identification  ccxies 
(according  to  list  in  table  5-3) 


Toners: 

Yellow  toners: Yes 

Acetoacetarylide  yellows: Yes 

Pigment  Yellow  1    No 

Pigment  Yellow  3    Yes 

Pigment  Yellow  60    No 

Pigment  Yellow  65    Yes 

Pigment  Yellow  73    No 

Pigment  Yeltow  74    Yes 

Pigment  Yellow  75    No 

Pigment  Yellow  97    No 

All  other  acetoacetarylide  yellows    No 

Diarylide  yellows:  Yes 

Pigment  Yellow  12    Yes 

Pigment  Yellow  13    Yes 

Pigment  Yellow  14   Yes 

Pigment  Yellow  17   Yes 

Pigment  Yellow  83    Yes 

Pigment  Yellow  124   No 

Yeltow  pigments,  other: 

(Basic  Yeltow  2),  fugitive No 

Pigment  Yellow  139    No 

All  other  pigment  yellow  toners    No 

Orange  toners: Yes 

Pigment  Orange  1    No 

Pigment  Orange  2   No 

Pigment  Orange  5   Yes 

Pigment  Orange  13    Yes 

Pigment  Orange  15    No 

Pigment  Orange  16   Yes 

Pigment  Orange  34    Yes 

Pigment  Orange  36    No 

Pigment  Orange  38    No 

Pigment  Orange  46    Yes 

Pigment  Orange  49    No 

All  other  pigment  orange  toners No 

Red  toners:    Yes 

Naphthol  reds:   Yes 

Pigment  Red  2   Yes 

Pigment  Red  5   No 

Pigment  Red  13   No 

Pigment  Red  14   No 

Pigment  Red  17   Yes 

Pigment  Red  21    No 

Pigment  Red  22   Yes 

Pigment  Red  23   Yes 

Pigment  Red  31    Yes 

Pigment  Red  112    No 


BAS.  DUP.  GLX.  HSH,  MAX.  SNA. 

HEU.  HSH,  KCW,  MAX,  SNA. 

HSH. 

HEU.  HSH.  MAX,  SNA,  VPC. 

HCL.  HSH.  SNA. 

BAS.  HCL.  HEU.  HSH,  ROM,  SNA,  VPC, 

(')(E). 
SNA. 
HCL. 
KCW. 

AMS,  APO,  BAS.  HCL.  HSH.  IDC.  IND. 

POP.  ROM.  SNA.  (2)(E). 
AMS,  APO,  BAS,  GLX,  HCL.  IDC.  IND, 

ROM,  SNA. 
AMS,  BAS.  BNS.  FAB.  GLX,  HCL,  HSH, 

IDC.  IND.  ROM,  SNA. 
APO.  BAS,  FAB,  GLX,  HCL,  HSH,  iDC, 

IND.  ROM.  SNA. 
BAS,  FAB,  GLX.  HCL.  IDC.  IND,  ROM, 

SNA. 
GLX. 

MAX. 
VPC. 
HSH. 

MAX. 

UHL. 

BAS,  HCL.  HSH.  PCW,  SNA,  (^){E). 

BAS,  HSH,  IND,  SNA. 

BNS. 

BNS,  GLX,  HSH,  IND,  ROM,  SNA. 

BAS,  HCL,  IND,  ROM.  SNA. 

SNA. 

HCL,  UHL. 

AMS,  BAS.  CDR.  CIK,  K4GR.  SNA. 

CGY 

GLX. 


GLX.  HCL,  HSH. 

GLX.  HSH. 

KCW. 

HCL 

BNS.  ROM.  SNA,  UHL. 

BNS. 

FAB.  GLX.  HEU.  MAX.  ROM,  SNA.  UHL. 

DUP,  FAB.  GLX.  HEU,  HSH.  IND,  KCW, 

ROM,  SNA,  UHL. 
GLX,  ROM,  (2)(E). 
HCL. 


See  footnotes  at  end  of  table. 


5-4 


Synthetic  Organic  Chemicals,  1990 

Table  5-2 — Continued 

Organic  pigments  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Organic  pigments 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  S-3) 


Toners — Continued 
Red  toners — Continued 
Naphthoi  reds — Continued 

Pigment  Red  146    No 

Pigment  Red  147    No 

Pigment  Red  1 70    No 

Pigment  Red  210   No 

All  other  naphthoi  reds   No 

Red  pigments,  other:   Yes 

Pigment  Red  1 ,  (light) No 

Pigment  Red  3   Yes 

Pigment  Red  4   Yes 

Pigment  Red  38    Yes 

Pigment  Red  41    No 

Pigment  Red  48;1 ,  (barium)  Yes 

Pigment  Red  48:2.  (calcium)    Yes 

Pigment  Red  48:3,  (strontium)   No 

Pigment  Red  48:4,  (manganese)   No 

Pigment  Red  49:1 ,  (barium)  Yes 

Pigment  Red  49:2,  (calcium)    Yes 

Pigment  Red  52:1 ,  (calcium)    Yes 

Pigment  Red  52:2,  (manganese)   No 

Pigment  Red  53:1 ,  (barium)   Yes 

Pigment  Red  57    No 

Pigment  Red  57:1 ,  (calcium)    Yes 

Pigment  Red  63   No 

Pigment  Red  63:1 ,  calcium No 

Pigment  Red  81 ,  (PMA)  Yes 

Pigment  Red  81 ,  (PTA) Yes 

Pigment  Red  122   No 

Pigment  Red  123    No 

Pigment  Red  168    No 

Pigment  Red  169   No 

Pigment  Red  1 79   No 

Pigment  Red  188   No 

Pigment  Red  190    No 

Pigment  Red  200   No 

Pigment  Red  202    No 

Pigment  Red  206    No 

Pigment  Red  207    No 

Pigment  Red  209    No 

Pigment  Red  224    No 

Pigment  Red  245   No 

All  other  pigment  red  toners  No 

Violet  toners:    Yes 

Pigment  Violet  1 ,  (fugitive) No 

Pigment  Violet  1 ,  (PMA) No 


HCL. 

HSH. 

GLX.  HCL,  HEU. 

SNA. 

BUG,  FAB,  GLX,  IND,  ROM,  {'){£).  C) 

HSH. 

BAS,  HSH.  KCW,  MAX,  SNA.  UHL.  X(E). 

HSH.  MAX.  UHL,  (=)(E). 

HCL.  HSH.  SNA. 

APO. 

AMS.  APO.  BAS.  CDR,  CIK.  HEU.  HSH. 

MAX.  MGR,  SNA,  UHL,  (2)(E). 
AMS,  APO,  BAS,  CDR.  CIK.  HEU.  HSH. 

MAX,  MGR,  SNA.  UHL,  VPC,  ('){E). 
HSH. 

HEU,  HSH.  SNA.  UHL. 
AMS.  BAS.  BNS,  CDR,  CIK,  IDC,  MAX. 

MGR.  SNA.  UHL,  {^){E). 
AMS,  BNS,  CDR.  CIK.  iDC.  MGR,  SNA. 

UHL. 
BAS,  CDR,  CIK,  HSH.  MGR,  SNA.  UHL. 
BAS,  HSH.  UHL. 
AMS.  BAS.  CDR.  CIK.  FAB,  HCL.  HSH, 

IDC.  MAX,  MGR.  SNA,  UHL.  {^){E). 
BNS. 
AMS.  APO,  BAS.  BNS.  CDR.  CIK.  FAB, 

HEU,  HSH,  IDC,  MGR,  POP.  PS.  SNA, 

UHL. 
HSH.  UHL. 
SNA. 

BAS.  MGR,  SNA.  UHL. 
BAS,  MAX,  UHL. 
SNA.  VPC. 
VPC. 
VPC. 
MAX. 

SNA.  VPC. 
HCL. 
VPC. 
BAS. 

CGY  SNA,  VPC 
CGY 
CGY 
SNA. 
VPC. 
IND. 
HCL,  UHL. 

KCW,  UHL. 
MAX,  MGR.  UHL. 


See  footnotes  at  end  of  table. 


5-5 


Section  5 

Table  5-2 — Continued 

Organic  pigments  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated.  Identified  by 

manufacturer,  1990 


Organic  pigments 


Separate 
statistics' 


Manufacturers'  identification  codes 
(according  to  list  in  table  S-3) 


Toners — Continued 
Violet  toners — Continued 

Pigment  Violet  1 ,  (PTA)    No 

Pigment  Violet  3,  (fugitive) No 

Pigment  Violet  3,  (PMA) No 

Pigment  Violet  3,  (PTA)    No 

Pigment  Violet  4,  (fugitive) No 

Pigment  Violet  19 No 

Pigment  Violet  23 No 

Pigment  Violet  27 No 

Pigment  Violet  29 No 

Pigment  Violet  39.  (PMA) No 

All  other  pigment  violet  toners   No 

Blue  toners:   Yes 

Pigment  Blue  1 ,  (Pf^^A) Yes 

Pigment  Blue  1 ,  (PTA)  No 

Pigment  Blue  2,  (PMA) No 

Pigment  Blue  14,  (PMA) No 

Pigment  Blue  1 5,  (a  form)  Yes 

Pigment  Blue  15:1,  (a  form) Yes 

Pigment  Blue  15:2,  (a  form) No 

Pigment  Blue  15:3,  (P  form) Yes 

Pigment  Blue  15:4.  (P  form) Yes 

Pigment  Blue  19 No 

Pigment  Blue  25 No 

Pigment  Blue  61 No 

Pigment  Blue  62 No 

All  other  pigment  blue  toners  No 

Green  toners: Yes 

Pigment  Green  1 ,  (PMA)   No 

Pigment  Green  2,  (PMA)   No 

Pigment  Green  2,  (PTA) No 

Pigment  Green  4,  (fugitive)    No 

Pigment  Green  4,  (PMA)   No 

Pigment  Green  7    Yes 

Pigment  Green  8    No 

Pigment  Green  10    No 

Pigment  Green  36    No 

All  other  pigment  green  toners No 

Brov^n  toners: No 

Pigment  Brown  5    No 

Black  toners:    No 

Pigment  Black  7 No 

All  other  pigment  black  toners    No 

Lakes:    No 

Yellow  lakes: No 

(Acid  Yellow  23)    No 

Orange  lakes: No 

Pigment  Orange  17 No 

Red  lakes:    No 

(Acid  Red  26)  No 

(Basic  Red  1 )   No 


MGR.  SNA.  UHL. 

KCW.  MGR,  UHL. 

MAX.  MGR,  UHL.  (2)(E). 

MAX.  MGR.  UHL. 

KCW. 

BAS.  CGY  SNA. 

HCL.  IPP,  SNA. 

MAX. 

SNA.  VPC. 

BAS. 

BUG,  UHL. 

BNS.  MAX,  MGR.  UHL.  (^){E). 

MGR. 

UHL. 

BAS.  UHL. 

BAS.  BFC.  CGY  HEU.  HSH,  SNA. 

CGY.  HEU.  SNA.  VPC,  ('XE). 

CGY.  HEU.  SNA.  VPC. 

ALG.  AMS.  APO.  BAS.  BFC.  CDR.  CGY. 

CIK.  HEU.  IDC,  MGR,  POP,  PS.  ROM. 

SNA. 
BAS.  CGY  HEU.  POP.  SNA. 
PSG. 
GLX. 
BAS. 
MAX. 
FAB. 

MAX.  UHL. 

MAX. 

MAX. 

UHL. 

UHL. 

ALG.  BAS.  BFC,  HCL.  MGR.  POP.  SNA. 

VPC.  (2)(E) 
KCW. 
HEU. 

ALG.  BAS.  SNA.  VPC. 
UHL. 

GLX. 

BAS. 
HCL.  UHL. 


MAX. 
KCW. 


KCW. 
BNS. 


See  footnotes  at  end  of  table. 


5-6 


Synthetic  Organic  Chemicals,  1990 

Tabl«  5-2 — Continued 

Organic  pigments  for  which  U.S.  production  and/or  sales  were  either  reported  or  estlnuted,  Identified  by 

manufacturer,  1990 

Organic  pigments  Separate         Manufacturers' identification  codes 

statistics '         (according  to  list  in  table  5-3) 

Toners — Continued 
Lakes — Continued 

(Basic  Red  81 ,  PMA)   No  LVR. 

Pigment  Red  60:1  No  HSH.  MAX.  SNA. 

Pigment  Red  83   Yes  HSH.  MAX.  UHL 

Violet  lakes:    No 

(Basic  Violet  1)  No  BNS. 

(Basic  Violet  4)  No  BNS. 

Violet  5:1 Yes  HSH,  MAX.  UHL.  VPC. 

Blue  lakes:   No 

(Basic  Blue  14,  PMA)  No  LVR. 

Green  lakes: No 

(Basic  Green  1.  PMA) No  LVR. 

(Basic  Green  1,  PMA) No  LVR. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yss.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


5-7 


Section  5 

Table  5-3 

Organic  pigments:  Directory  of  manufaeturvrs,  alphabetical  by  coda,  1990 


Code 


Name  of  company 


Code  Name  of  company 

HEU    Cool<son  Pigment,  Inc. 

HSH    Engelhard  Corporation 

IDC Industrial  Color.  Inc. 

IND Indol  Color  Co.,  Inc. 

IPP    Spectrachem  Corp. 

KCW Keystone  Color  Works,  Inc. 

LVR C.  Lever  Co..  Inc. 

MAX   Max  Marx  Color  Corp. 

MGR Magruder  Color  Co..  Inc. 

PCW Pfister  Chemical.  Inc. 

POP    Daicolor-Pope,  Inc. 

PS     CPS  Corp. 

PSG    PMC.  Inc.  Specialities  Group.  Inc. 

ROM Roma  Color.  Inc. 

SNA Sun  Chemical  Corp.,  Pigment  Div. 

UHL Paul  Uhlich  &  Co.,  Inc. 

VPC Mobay  Chemical  Corp.,  Dyes  & 

Pigments  Div. 


ALG Allegheny  Chemical  Corp. 

AMS Ridgway  Color  Co. 

APO Apollo  Colors,  Inc. 

BAS BASF  Corp. 

BFC Baker  Fine  Color,  Inc. 

BNS Binney  and  Smith.  Inc. 

BUC Synalloy  Corp..  Blackman  Uhler 

Chemical  Div. 

CDR CDR  Pigments  &  Dispersions 

CGY Ciba-Geigy  Corp. 

CIK Flint  Ink  Corp..  Cal/Ink  Div. 

DUP E.I.  duPont  de  Nemours  &  Co..  Inc., 

Chemicals  and  Pigments  Dapt. 

FAB Fabricolor  Manufacturing  Corp. 

GLX Galaxie  Chemical  Corp. 

HCL Hoechst  Celanese  Corp.: 

Sou-Tex  Works 

Specialty  Chem  Group 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


Synthetic  Organic  Chemicals.  1990 


Section  6 
Medicinal  Chemicals 

Medicinal  chemicals  include  the  medicinal  and 
feed  grades  of  all  organic  chemicals  having  iherapeudc 
value,  whether  obtained  by  chemical  synthesis,  by 
fermentation,  by  extraction  from  naturally  occurring 
plant  or  animal  substances,  or  by  refining  a  technical 
grade  product.  They  include  antibiotics  and  other 
anti-infecuve  agents,  antihistamines,  autonomic  drugs, 
cardiovascular  agents,  central  nervous  system 
depressants  and  stimulants,  hormones  and  synthetic 
substitutes,  vitamins,  and  other  therapeutic  agents  for 
human  or  veterinary  use,  and  for  animal  feed 
supplements.  Data  for  the  production  of  these  products 
during  1986-90  are  shown  in  figure  6-1. 

Table  6- 1  shows  statistics  for  production  and  sales 
of  medicinal  chemicals  grouped  by  pharmacological 
class.  The  statistics  shown  are  for  bulk  chemicals  only. 
Finished  pharmaceutical  preparations  and  products  in 
dosage  form  (i.e.,  pills,  capsules,  tablets,  or  other 
measured    doses)    are    excluded.'       Differences    in 


'  Complemeniaiy  statistics  on  ihe  dollar  value  of 
manufaciurers'  shipments  of  finished  phannaceutical 
preparations,  except  biologicals,  are  published  annually  by  the 
U.S.  Department  of  Commerce,  Bureau  of  the  Census,  in 
Current  Industrial  Reports,  Series  MA-28G.  Many 
pharmaceutical  manufacturers  that  report  to  the  Bureau  of  the 
Census  are  excluded  from  the  U.S.  International  Trade 
Commission  report  because  they  are  not  primary  producers  of 
medicinal  chemicals:  that  is,  they  do  not  themselves  produce 
the  bulk  drugs  which  go  into  their  pharmaceutical  piroducts.  but 
purchase  their  drug  requirements  from  domestic  or  foreign 
producers. 


reported  levels  of  production  and  sales  refiecl 
inventory  changes,  processing  losses,  and  captive 
consumption  of  medicinal  chemicals  processed  into 
ethical  and  proprietary  pharmaceutical  products  by  the 
primary  manufacturer.  In  some  instances,  the 
differences  may  also  include  quantities  for  medicinal 
grade  products  used  as  intermediates:  for  example, 
penicillin  V  used  as  an  intermediate  in  the  manufacture 
of  other  antibiotics.  All  quantities  are  given  in  terms  of 
100  percent  content  of  the  pure  bulk  drug.  Table  6-2 
lists  the  products  reported  in  this  section  and  indicates 
the  manufacturer(s)  of  each  by  code.  These  codes  are 
identified  by  company  name  in  table  6-3. 

Total  U.S.  production  of  bulk  medicinal  chemicals 
in  1990  amounted  lo  144.0  million  kilograms.  Total 
sales  of  bulk  medicinal  chemicals  in  1990  amounted  to 
107.2  million  kilograms,  valued  at  S2, 169.3  million. 
Since  1980,  methionine  and  most  other  amino  acids 
and  their  sails  have  been  reported  in  the  section  on 
Miscellaneous  End-Use  Chemicals  and  Chemical 
Products.  Section  totals  are  not,  therefore,  comparable 
with  years  prior  to  1980. 

Production  of  the  larger  groups  of  medicinal 
chemicals  in  1990  was  as  follows  (see  table  6-1): 
Antibiotics,  24.1  million  kilograms,  2  percent  higher 
than  in  1989;  anti-infective  agents  other  than 
antibiotics,  8.2  million  kilograms,  8  percent  lower  than 
in  1989;  central  nervous  system  depressants  and 
stimulants,  40.3  million  kilograms,  17  percent  higher 
than  in  1989;  gastrointestinal  agents  and  therapeutic 
nutrients,  24.9  million  kilograms,  28  percent  lower 
than  in  1989;  and  vitamins,  37.6  kilograms,  34  percent 
higher  than  in  1989. 

Elizabeth  R.  Nesbitt 
202-205-3355 


Figure  6-1 

Medicinal  Chemicals:  U.S.  production,  1986-90 


Millions 
of  kilograms 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


6-1 


Section  6 

Table  6-1 

Medicinal  chemicals:  U.S.  production  and  sales,  1990 

Sales  Average 

Unit 

Medicinal  chemicals  Production'         Quantity  Value  value^ 

1,000  1,000  1,000  Per 

kilograms  kilograms        dollars  kiktgram 

Grand  total  144,341 107.247  2.169,344        $20.23 

Acyclic  24,615  41,400  301.351  7.28 

Benzenoid^    90.371  47,234  963.447  20.40 

Cyclic  nonbenzenoid*    29,355  18,613  904.546  48.60 

Antibiotics   24.696  10.718  574,188  53.57 

Antihistamines 279  148  7.412  50.08 

Anti-infective  agents  (except  antibiotics),  total 8,173  4,618  46,379  10.04 

Anthelmintics  3.847  2,176  6.054  2.78 

All  other  anti-Infective  agents  (except 
antibiotics)* 4.326  2,442  40.325  16.51 

Central  depressants  and  stimulants,  total  40.314  30.656  423,356  13.81 

Analgesics,  antipyretics,  and  nonhormonal  anti- 
inflammatory agents,  total 37,102  28,823  172.665  5.99 

Aspirin    10,230  («)  («)  («) 

All  other  analgesics,  antipyretics,  and 

nonhormonal  anti-inflammatory  agents^ 26,872  28,823  172.665  5.99 

Antidepressants 33  12  2.928  244.00 

Antitussives   214  165  51.019  309.21 

All  other  central  depressants  and  stimulants*   2,965  1 ,656  1 96,744  11 8.81 

Expectorants  and  mucolytic  agents 602  530  1 1 ,441  21 .59 

Gastrointestinal  agents  and  therapeutic  nutrients'   24,948  41.324  122,737  2.97 

Vitamins'"   37.566  17.017  173.458  10.19 

Miscellaneous  medicinal  chemicals"    7.763  2.236  810,373  362.42 

'  The  data  on  production  and  sales  are  for  bulk  medicinal  chemicals  only.  Methionine  and  most  other  amino  acids 
and  their  salts  are  now/  reported  in  the  section  on  Miscellaneous  End-Use  Chemicals  and  Chemical  Products.  Section 
totals  are  not.  therefore,  comparable  with  years  prior  to  1980. 

^  Calculated  from  rounded  figures. 

'  Benzenoid,  as  used  in  this  report,  describes  any  cyclic  medicinal  chemical  whose  molecule  contains  either  a 
6-membered  carbocyclic  ring  with  conjugated  double  bonds  or  a  6-membered  heterocyclic  ring  with  1  or  2  hetero 
atoms  and  conjugated  double  bonds,  except  the  pyrimidine  hng. 

*  Includes  antibiotics  of  unknown  structure. 

'  Includes  production  and  sales  of  antiprotozoan  agents,  sulfonamides,  and  urinary  antiseptics;  does  not  include 
production  of  sutfaguanidine  used  as  an  intermediate  in  the  production  of  anti-infective  sulfonamides. 

*  Reported  data  were  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 
^  Includes  sales  quantity  and  value  of  aspirin. 

*  Includes  production  and  sales  of  amphetamines,  general  anesthetics;  respiratory  and  cerebral  stimulants; 
skeletal  muscle  relaxants;  tranquilizers;  and  antk»nvulsants,  hypnotics,  and  sedatives. 

'  Methionine  and  its  salts  are  reported  in  the  section  in  Miscellaneous  End-Use  Chemicals  and  Chemical  Products 
under  amino  acids. 

'°  Includes  production  and  sales  of  vitamin  A.  vitamin  B.  vitamin  0,  vitamin  D.  vitamin  E.  and  vitamin  K. 

"  Includes  production  and  sales  of  antineoplastk:  agents,  cardiovascular  agents,  diagnostic  agents,  hematotogical 
agents,  renal-adlng  and  edema-reducino  agents,  autonomic  drugs,  dermatological  agents  and  unclassified  medrcinal 
chemicals.  Also  includes  production  and  sales  of  tocal  anesthetics,  smooth  muscle  relaxants  (including  theophylline 
derivatives),  and  hormones  and  synthetic  substitutes. 

Source:  Compiled  from  data  received  in  response  to  questrannaires  of  the  U.S.  International  Trade  Commission. 


6-2 


Synthetic  Organic  Chemicals,  1990 

Table  6-2 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  nianufacturer,  1990 

Separate  Manufacturers '  identification  codes 

fiAedicinal  chemicals  statistics '  (according  to  list  in  table  6-3) 

Antibiotics    Yes 

Cephalosporins: No 

Cefaclor   No  LIL 

Cefamandole  No  LIL. 

Cefazoiin,  sodium No  LIL. 

Cefoxitin No  MRK. 

Cephalexin No  BRS,  LIL 

Cephalothin,  sodium No  LIL. 

Cephapinn,  sodium    No  BRS. 

Cephradine No  BRS. 

Penicillins,  semisynthetic:    No 

Amoxicillin: No 

Amoxicillin  (trihydrate) No  BEE.  BOC.  KAN. 

Amoxicillin  (anhydrous) No  BEE.  BRS. 

Ampicillin: •. No 

Ampicillin  (trihydrate) No  BOC.  BRS.  KAN. 

Other  semisynthetic  penicillins:   No 

Ampicillin,  sodium No  BEE.  WYT. 

Cloxacillin,  sodium   No  BEE.  BOC. 

Dicloxacillin.  sodium No  BEE,  BOC,  KAN. 

Hetacillin No  BRS. 

Nafcillin,  sodium  No  BEE.  WYT. 

Oxacillin,  sodium No  BEE.  BOC. 

Piperacillin    No  BRS. 

Ticarcillin,  disodium No  BEE. 

All  other  semisynthetic  penicillins No  BEE. 

Penicillins  (except  semisynthetic): No 

For  medicinal  use:    No 

Penicillin  V   No  BRS. 

Penicillin  G,  benzathine   No  WYT. 

Penicillin  G,  potassium  No  PFZ. 

Penicillin  V.  potassium    No  BRS.  LIL. 

Penicillin  G,  procaine  (medicinal  grade) No  PFZ.  WYT. 

For  nonmedicinal  uses:    No 

Penicillin  G.  procaine  (animal  feed  grade)   No  PFZ. 

Tetracyclines: No 

For  medicinal  use:    No 

Chlortetracycline  (medicinal  grade)    No  ACY. 

Demedocycline No  ACY. 

Methacycline No  GAN. 

Minocycline No  ACY. 

Tetracycline No  ACY. 

For  nonmedicinal  uses:    No 

Chlortetracycline  (animal  feed  grade) No  ACY.  PFZ. 

Oxytetracycline  (animal  feed  grade) No  PFZ. 

Other  antibiotics:    No 

For  medicinal  use:   No 

Antifungal  antibiotics:   No 

Amphotericin  B  No  BRS.  PEN. 

Nystatin  (medicinal  grade)    No  ACY,  BRS. 

Tobramycin  No  LIL. 

Antitubercular  antibiotics:   No 

Dihydrostreptomycin No  PFZ. 

Other  antibiotics  for  medicinal  use: No 

Aztreonam No  BRS. 

Cefonicid No  SK. 

Ceftiofur No  UPJ. 

Cefuroxime   No  LIL. 

Clindamycin No  ABB. 

Erythromycin No  ABB,  ANG,  UPJ. 

Erythromycin  estolate No  LIL,  UPJ. 

Erythromycin  stearate No  UPJ. 


See  footnotes  at  end  of  table. 


6-3 


Section  6 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate         Manufacturers '  identificatior)  codes 
Medicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 


Antibiotics-Continued 
Other  antibiotics-Continued 
For  medicinal  use-Continued 
Other  antibiotics  for  medicinal  use-Continued 

Gentamycin No  SCH. 

Kanamycin    No  BRS. 

Moxalactam No  LIL. 

Neomycin  (medicinal  grade) No  UPJ. 

Netilmicin No  SCH. 

Novobiocin,  sodium No  UPJ. 

Polymyxin  B    No  PFZ. 

Sisomycin  No  SCH. 

Spectinomycin  (medicinal  grade)   No  ABB,  BRS,  UPJ. 

Vancomycin No  ABB.  ACY,  LIL. 

All  other  antibiotics,  for  medicinal  use No  ABB,  MRK. 

For  nonmedicinal  uses;    No 

Bacitracin  (animal  feed  grade)  No  IMC. 

Cydoheximide   No  UPJ. 

Hygromycin  B No  LIL. 

Lasalocid.  sodium No  HOF. 

Lincomycin  (animal  feed  grade)  No  UPJ. 

Monesin   No  LIL. 

Neomycin  (animal  feed  grade) No  PFZ,  UPJ. 

Spectinomycin  (animal  feed  grade)    No  UPJ. 

Streptomycin No  PFZ. 

Tylosin No  LIL. 

Antihistamines: Yes 

Antinauseants: No 

Dimenhydrinate No  GAN. 

Diphenidol No  SK. 

Diphenidol  hydrochloride    No  SK. 

Metoclopramide  hydrochloride  No  LLI. 

Other  antihistamines; No 

Brompheniramine  maleate No  LLI. 

Chlorpheniramine No  SK,  UPJ. 

Chlorpheniramine  maleate  No  SK. 

Cyproheptadine  hydrochloride  No  MRK. 

Dimethindene  maleate  No  CGY. 

Diphenhydramine  citrate No  VTM. 

Diphenhydramine  hydrochtoride No  PD,  WYK. 

Diphenylpyraline No  SK. 

Diphenylpyraline  hydrochloride No  SK. 

Doxylamine  succinate No  BKC,  MAL. 

Phenindamine  tartrate    No  HOF. 

Phenyttoioxamine  crtrate No  GAN. 

Terfenadine No  GAN. 

Trimeprazine No  SK. 

Tripelennamine No  CGY. 

Tripelennamine  citrate    No  CGY. 

Tripelennamine  hydrochloride No  CGY. 

Triprolidine  hydrochloride No  AMD.  BUR. 

Triprolidine  oxalate  No  AMD. 

Anti-infective  agents  (except  antibiotics): Yes 

Anthelmintics  agents; Yes 

Diethylcarbamazine  citrate No  SK. 

Piperazine No  TX,  UCC. 

Piperazine  dihydrochloride No  FLM. 

Piperazine  hexahydrate   No  BRS. 

Piperazine  hydrochloride    No  FLM. 

Piperazine  sulfate No  FLM. 


See  footnotes  at  end  of  table. 


6-4 


Synthetic  Organic  Chemicals.  1990 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  nianufacturer,  1990 

Separate  Manufacturers'  idenlification  codes 

Medicmal  chemicals  statistics '         (according  to  list  in  table  6-3) 

Anti-infective  agents  (except  antibiotics)-Continued 
Anthelmintics  agents-Continued 

Thiabendazole  No  MRK. 

All  other  anthelmintic  agents    No  MRK. 

Antiprotozoan  agents:    No 

Arsenic  and  bismuth  compounds:    No 

Arsanilic  acid No  FLM. 

Bismuth  subsalicylate No  MAL. 

Nitarsone    No  SAL. 

Roxarsone    No  SAL. 

Roxarsone,  sodium No  SAL. 

Other  antiprotozoan  agents: No 

Amprolium No  MRK. 

Dinitolmide   No  SAL. 

Ethopabate No  MRK. 

Florfenicol No  SCH. 

Hydroxychloroquine  sulfate No  SD. 

lodochlorhydroxyquin  No  CGY. 

Metronidazole No  SRL. 

Sulfonamides:   No 

Mafenide No  SDW. 

Mafenide  acetate  No  SDW. 

Sulfadiazine,  silver No  BOX  LEM. 

Sulfadimethoxine  No  HOF. 

Sulfamethizole  No  ACY. 

Sulfamethoxazole No  HOF. 

Sutfapyridine No  ACY. 

Sulfasalazine   No  SAL. 

Sutfathiazole,  sodium No  SAL. 

Sulfisoxazole    No  HOF. 

Sulfisoxazole,  acetyl No  HOF. 

Urinary  antiseptics;    No 

Methenamine  No  ARN. 

Methenamine  mandelate   No  ARN,  PD. 

Other  anti-infective  agents:    Yes 

Antifungal  agents: No 

Benzoic  acid No  KLM. 

Calcium  undecylenate    No  WTL. 

Fluconazole   No  PFZ. 

Flucytosine  No  HOF. 

Sodium  caprylate   No  LEM. 

Zinc  undecylenate No  WTL. 

All  other  antifungal  agents    No  ARN. 

Antileprotic  and  antitubercular  agents: No 

Aminosalicylic  acid  No  HXL. 

Sulfoxone,  sodium    No  ABB. 

Antiviral  agents:   No 

Acyclovir No  (^. 

Azidothymidine No  (*). 

Rimantidine  hydrochloride    No  HOF. 

General  antiseptics  and  antibacterial  agents: No 

Capreomycin No  LIL. 

Ceftazidime No  BRS.  LIL.  SK. 

Ceftazidine  dihydrochloride No  SK. 

Cetylpyridinium  chloride  No  HXL. 

Iodoform  No  MAL. 

Magnesium  salicylate No  ARN. 

Ormetoprim No  HOF. 

Oxyquinoline  citrate    No  LEM. 

Oxyquinoline  sulfate No  LEM. 


See  footnotes  at  end  of  table. 


6-5 


Section  6 

Table  6-2— Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  wars  rsportsd,  Idsntlflsd  by  manufactursr,  1990 


Separate         Manufacturers '  identification  codes 
Medicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 


Anti-infective  agents  (except  antlblotlcs)-Contlnued      Yes 

Other  anti-infective  agents-Continued    Yes 

General  antiseptics  and  antibacterial  agents-Cont  No 

Pentamidine  isethionate No  J^??',  c.j 

Povidone  -  iodine   No  GAF.  LEM. 

Resorcinol No  «P- 

Trimethoprim No  BUR. 

Autonomic  drugs: No 

Sympathomimetic  agents:  No 

Albuterol  sulfate  No  SCH. 

Dobutamine   No  LIL 

Methoxyphenamine  hydrochloride No  HXL 

Naphazoline  hydrochloride No  CGY. 

Phenylephrine  hydrochloride   No  GAN.  SOW. 

Phenylpropanolamine  bitartrate No  ARS. 

Phenylpropanolamine  hydrochloride   No  ARS,  ORT. 

Propylhexedrine No  SK. 

Pseudoephedrine  hydrochloride No  GAN. 

Pseudoephedrine  sulfate  No  GAN. 

Terbutaline  sulfate    No  CGY. 

Other  autonomic  drugs: No 

Parasympatholytic  quaternary  ammonium  compounds 

(except  tropane  derivatives): No 

Glycopyrrolale No  LLI. 

Methantheline  bromide No  SRL. 

1  1-Trimethylene-bis-(4-formylpyridinium  Isromide) 

oxime No  ARN. 

Parasympatholytic  tertiary  amines  (except  tropane 

derivatives): No 

Oxybutynin  chloride    No  ABB. 

Parasympathomimetic  agents: 

Bethanechol  chloride    No  GAN. 

Neostigmine  methylsulfate  No  HOP. 

Pyridostigmine  bromide   No  HOP. 

Sympatholytic  agents:   No 

Timolol  maleate No  MRK. 

Central  depressants  and  stimulants:  Yes 

Analgesics,  antipyretics,  and  nonhormonal  anti- 
inflammatory agents: Yes 

Acetaminophen No  t?iJ'-,':BrA^P.y\-  ^,^ 

Aspirin  ...    Yes  CX)W.  NOR.  RDA,  SD. 

Auranofin    No  SK. 

Aurothioglucose   No  SCH. 

Butorphanol  tartrate    No  BRS. 

Choline  magnesium  salicylate    No  ARN.  LEM. 

Choline  salicylate   No  ARN. 

Diflunisal No  MRK 

Fenoprolen No  LIL,  (^). 

Fentanyl  citrate No  MRX. 

Hydromorphone  hydrochloride No  PEN. 

Ibuprofen No  TNA. 

Indomethacin    No  MRK. 

Ketoprofen    No  ^'^;,vw 

Meclofenamate,  sodium  No  PD,  WYK. 

Meclofenamic  acid   No  PD. 

Mefenamic  acid No  PD. 

Meperidine  hydrochloride No  PEN,  SDW. 

Mesalamine    No  SRL. 

Methadone  hydrochloride No  MAL. 

Morphine  sulfate No  MAL,  PEN. 


See  footnotes  at  end  of  table. 
6-6 


Synthetic  Organic  Chemicals,  1990 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separata  Manufacturers '  identification  codes 

Medicinal  chemicals  statistics '  (according  to  list  in  table  6-3) 

Central  depressants  and  stimulants-Continued Yes 

Analgesics,  antipyretics,  and  nonhormonal  anti- 
inflammatory agents-Continued Yes 

Oxycodone  hydrochloride No  DUP,  MAL.  PEN. 

Oxycodone  terephthalate No  PEN. 

Pentazocine  No  SD. 

Pentazocine  hydrochloride No  SD. 

Piroxicam  No  PFZ. 

Potassium  salicylate No  KLM. 

Propoxyphene  hydrochloride  No  GAN,  LIL. 

Propoxyphene  napsylate  No  ABB,  GAN,  LiL 

Salsalate No  (^. 

Sodium  salicylate No  KLM. 

Sulindac No  MRK. 

Anticonvulsants,  hypnotics,  and  sedatives:   No 

Anticonvulsants  (except  barbiturates): No 

Elhosuximide    No  PD. 

Ethotoin No  ABB. 

Methsuximide No  PD. 

Phensuximide No  PD. 

Phenytoin  No  PD. 

Phenytoin,  sodium    No  PD. 

Valproic  acid No  ABB. 

Barbiturates: No 

Amobarbilal,  sodium No  GAN. 

Butabarbitai No  GAN. 

Butalbital No  GAN. 

Pentobarbital No  GAN. 

Phenobarbital No  GAN. 

Phenobarbital,  sodium    No  GAN. 

Poiy(oxy-1 ,2-ethanediyl)-a<artx)xymethyl,  omega- 

(tridecyloxy),  potassium  salt  No  GAN. 

Secobarbital  No  GAN. 

Secobarbital,  sodium    No  GAN. 

Thiamylal,  sodium No  PD. 

Thiopental,  sodium No  ABB. 

Hypnotics  and  sedatives  (except  barbiturates): No 

Alprazolam  No  UPJ. 

Dichtoralphenazone   No  ARN. 

Ethchlorvynol    No  ABB. 

Glutethimide No  GAN. 

Antidepressants:    Yes 

Amitriptyline  hydrochbride No  GAN,  MRK. 

Benaclyzine  hydrochloride No  ARN. 

Bupropion No  BUR. 

Doxepin  hydrochloride  No  SK. 

Imipramine  hydrochloride No  CGY. 

Maprotiline  hydrochloride No  ABB. 

Nortriptyline  hydrochloride  No  LIL,  WYK. 

Antitussives: Yes 

Benzonatate No  CGY.  WYK. 

Caramiphen  No  SK. 

Caramiphen  edisylate No  SK. 

Codeine   No  MAL,  PEN. 

Dextromethorphan  hydrobromide No  AMD,  HOP. 

Doxepin   No  SK. 

Hydrocodone  bitartrate No  MAL.  PEN. 

Noscapine    No  MAL.  PEN. 

Thebaine    No  MAL,  PEN. 


See  footnotes  at  end  of  table. 


6-7 


Section  6 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  salaswwr*  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

hAedicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 

Central  depressants  and  stimulants-Continued Yes 

Tranquilizers: No 

Phenothiazine  derivatives: No 

Clilorpromazine   No  SK. 

Chlorpromazine  hydrochloride No  SK. 

Fluphenazine  hydrochloride No  BRS. 

Perphenazine No  SCH. 

Prochlorperazine   No  SK. 

Prochlorperazine  edisylate No  SK. 

Prochlorperazine  maleate   No  SK. 

Other  tranquilizers: No 

Chlorprothixene   No  HOP. 

Clorazepate  dipotassium   No  ABB. 

Hydroxyzine  pamoate No  LEM. 

Molindone  hydrochloride    No  PD. 

Thiothixene  hydrochloride    No  PFZ. 

Other  central  depressants  and  stimulants:   Yes 

Amphetamines:   No 

Amphetamine No  ARN,  SK. 

Amphetamine  sulfate  No  ARN. 

Dextroamphetamine No  ARN.  SK. 

Dextroamphetamine  sulfate No  ARN,  SK. 

Methamphetamine No  ARN. 

Methamphetamine  hydrochloride No  ARN. 

Tranylcypromine No  SK. 

General  anesthetics:   No 

Enflurane  No  OH. 

Isoflurane No  OH. 

Ketamine  hydrochloride  No  PD. 

Respiratory  and  cerebral  stimulants: No 

Caffeine  (natural  and  synthetic): No 

Caffeine,  natural  No  CPR. 

Caffeine,  synthetic    No  PFZ. 

Other  respiratory  and  cerebral  stimulants: No 

Benzphetamine  hydrochloride    No  UPJ. 

Diethylpropion  hydrochloride    No  GAN. 

Doxapram  hydrochloride No  LLI. 

Methylphenidate  hydrochloride No  CGY. 

Pemoline No  ABB. 

Phentermine No  GAN.  SDW. 

Skeletal  muscle  relaxants: No 

Cyclobenzaprine  hydrochloride   No  MRK. 

fi^etaxalone No  LLI. 

Methocarbamol No  LLI. 

Orphenadrine  citrate No  ABB,  WYK. 

Succinylcholine  chloride No  ABB,  BUR. 

Tubocurarine    No  ABB. 

Dermatological  agents:   No 

Ammonium  phenolsutfonate No  SAL. 

Bismuth  subgallate No  MAL. 

Salicylic  acid    No  DOW.  KLM. 

Sodium  phenolsulfonate No  MAL. 

Expectorants  and  mucolytic  agents:   Yes 

Ethylenediaminedihydriodide   No  AJY,  DPW. 

Guaifenesin  No  LLI. 

lodinated  glycerol No  (^. 

Gastrointestinal  agents  and  therapeutic  nutrients: Yes 

Gastrointestinal  agents: No 

Choline  chloride  (all  grades):  No 

Choline  chloride  (animal  feed  grade) No  CHO.  Nl,)T,  TMH. 


See  footnotes  at  end  of  table. 


6-8 


Synthetic  Organic  Chemicals.  1990 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  identificalion  codes 

Medicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 

Gastrointestinal  agents  and  therapeutic  nutrients 

-Continued    Yes 

Gastrointestinal  agents-Continued  No 

Choline  chloride  (all  grades)-Contlnued  No 

Choline  chloride  (medicinal  grade)    No  CHO. 

Other  gastrointestinal  agents: No 

Betaine  hydrochloride No  CHO. 

Calcium  polycartxjphil No  DAhJ,  LLI. 

All  other  choleretics  and  hydrocholeretics   No  UPJ. 

Choline  bicarbonate   No  CHO. 

Choline  bitartrate    No  CHO. 

Choline  citrate No  CHO. 

Choline  dihydrogen  citrate   No  CHO. 

Cimetidine No  SK. 

Cimetidine  hydrochloride    No  SK. 

Colestipol  hydrochloride No  UPJ. 

Dihydroxyaluminum  aminoacetate  No  CHT. 

Diphenoxylate No  MAL. 

Docusate,  calcium    No  MAL. 

Docusate,  potassium    No  ACY. 

Docusate,  sodium No  ACY.  MAL. 

Gemfibrozil No  PD. 

All  other  lipotropic  agents  and  cholesterol 

reducers,  other  than  choline  salts No  MRK. 

Methscopoiamine  bromide  No  UPJ. 

Nizatidine   No  LIL. 

Sitosterols No  UPJ. 

Sucralfate No  SK. 

All  other  gastrointestinal  agents  No  MRK. 

Therapeutic  nutrients:    No 

Calcium  gluceptate No  PFN. 

Copper  gluconate No  PFZ. 

Manganese  gluconate   No  PFZ. 

z-l-Tnreoninamide  mesylate No  BRS. 

Zinc  gluceptate No  PFN. 

Zinc  gluconate   No  PFZ. 

Hormones  and  synthetic  substitutes: No 

Anabolic  agents  and  androgens:  No 

Fluoxymesterone  No  UPJ. 

Methyltestosterone No  UPJ. 

Stanozolol No  SD. 

Testosterone No  UPJ. 

Testosterone  cypionate No  UPJ. 

Testosterone  propionate No  UPJ. 

Zeranol No  IMC. 

All  other  anabolic  agents  and  androgens No  UPJ,  (^). 

Corticosteroids: 

Aclomethasone No  SCH. 

Betamethasone    No  SCH. 

Betamethasone  dipropionate No  SCH,  {'). 

Betamethasone  sodium  phosphate   No  SCH,  ('). 

Betamethasone  valerate No  SCH,  (*). 

Cortisone  acetate No  MRK,  UPJ. 

Dexamethasone No  MRK,  (*). 

Dexamethasone  sodium  phosphate No  MRK,  (*). 

Diflorasone  diacetate  No  UPJ. 

Fludrocortisone  acetate   No  UPJ. 

Fluoromethotone    No  UPJ. 

Halcinonide No  BRS. 

Hydrocortisone No  UPJ. 


See  footnotes  at  end  of  table. 


6-9 


Section  6 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported.  Identified  by  manufacturer,  1990 

Separate         Manufacturers'  identification  codes 
fyledicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 


Hormones  and  synthetic  substitutes-Continued No 

Corticosterolds-Continued No 

Hydrocortisone  acetate No  UPJ. 

Isoflupredone,  acetate  No  UPJ. 

Medrysone No  UPJ. 

Methylprednisolone   No  ABB,  SCH,  UPJ. 

Prednisolone    No  MRK,  UPJ. 

Prednisolone  acetate  No  UPJ. 

Prednisone No  UPJ. 

Triamcinolone No  BRS,  (*)■ 

Triamcinolone  acetonide    No  BRS,  n- 

Triamcinolone  diacetate No  BRS,  (^. 

Estrogens  and  progestogens:   No 

Estrogens:   No 

Estradiol  cypionate No  UPJ. 

Estrogens,  conjugated   No  ORG. 

Estrogens,  esterified No  ORG. 

All  other  estrogens  No  ORG. 

Progestogens:   No 

Alprostadil No  (^. 

Dinoprostone    No  UPJ. 

Hydroxyprogesterone No  CWN. 

Medroxyprogesterone  acetate   No  UPJ. 

Megestrol  acetate No  UPJ. 

Melengestrol  acetate    No  n. 

Norgestrel No  UPJ. 

Synthetic  hypoglycemic  agents: No 

Chlorpropamide  No  SAL. 

Glipizide No  PFZ. 

Tolazamide No  UPJ. 

Tolbutamide  No  UPJ. 

Thyroid  hormone  and  antithyroid  agents: No 

Levothyroxine,  sodium  No  BOT. 

Methimazole No  LIL. 

Thyroglobulin  No  NEP 

ThyroK) No  ARP 

Other  hormones  and  synthetic  substitutes: No 

Calcitonin  No  ARP. 

Corticotropin No  ARP.  ORG. 

Danazol   No  SD. 

Flutamide No  SCH. 

Gonadorelin,  acetate  No  ABB. 

Humatrope No  LIL. 

Insulin No  LIL. 

Local  anesthetics:   No 

Benzocaine   No  MAL,  WYK. 

Butamben No  ABB.  WYK. 

Cocaine  No  MAL. 

Dibucaine No  CGY. 

Dibucaine  hydrochloride No  CGY. 

Lidocaine  .    No  LEM.  WYK. 

Lidocaine  hydrochloride No  LEM,  WYK. 

Pramoxine  hydrochloride No  ABB. 

Prilocaine  hydrochloride No  WYK. 

Tetracaine  hydrochloride   No  WYK. 

Renal-acting  and  edema-reducing  agents:  No 

Benzothiadiazine  derivatives: No 

Chlorothiazide    No  MRK. 

Hydrochlorothiazide No  CGY  MRK,  SK. 


See  footnotes  at  end  of  table. 


6-10 


Synthetic  Organic  Chemicals.  1990 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Medicinal  chemicals  statistics '  (according  to  list  in  table  6-3) 

Renal-acting  and  edema-reducing  agents-Continued  ....  No 

Other  renal-acting  and  edema-reducing  agents: No 

Acetazolamide  No  ACY. 

Amiioride  hydrochloride   No  MRK. 

Canrenoate,  potassium    No  SRL. 

Dichlorphenamide    No  MRK. 

Ethacrynic  acid No  MRK. 

Probenecid No  MRK,  SAL. 

Spironolactone No  SRL. 

Triamterene   No  GAN,  SK. 

Smooth  muscle  relaxants: No 

Atracurium  besylate No  (^. 

Flavoxate  hydrochloride No  SK. 

Oxtriphylline No  PD. 

Papaverine  hydrochloride    No  CHT. 

Theophylline No  AMB. 

Vitamins:   Yes 

Vitamin  A: No 

Beta  carotene  (provitamin  A)  No  HOP 

Tretinoin  (vitamin  A  acid)  No  EK. 

Vitamin  A  acetate  (animal  feed  grade) No  RDA. 

Vitamin  A  acetate  (medicinal  grade) No  HOP. 

Vitamin  A  alcohol  No  EK,  HOP 

Vitamm  A  palmitate  (medicinal  grade) No  HOP 

All  other  vitamin  A    No  EK. 

Vitamin  B-complex:   No 

Niacin  and  derivatives: No 

Niacinamide  (medicinal  grade) No  HOP,  NEP. 

Niacinamide  (animal  fecKJ  grade) No  RDA. 

Pantothenic  acid  derivatives:  No 

Dexpanthenol No  HOP. 

Panthenol  No  HOP 

Other  B-complex  vitamins: No 

Biotin No  AMD,  HOP  RDA. 

Cyanocobalamin  (animal  feed  grade) No  RDA. 

Cyanocobalamin  (medicinal  grade)    No  MRK. 

Pyridoxine No  HOP 

Riboflavin  (animal  feed  grade)  No  MRK. 

Thiamine  hydrochloride    No  HOP 

Thiamine  mononrtrate No  TKD. 

All  other  vitamin  B-complex    No  HOP. 

Vitamin  C: No 

Ascorbic  acid   No  HOP,  TKD. 

Calcium  ascorbate   No  HOP. 

Sodium  ascorbate    No  HOP. 

All  other  vitamin  C    No  HOP. 

Vitamin  D: No 

Calcifedral  (vitamin  D3) No  UPJ. 

Cholecalcrterol  (vitamin  D3)    No  RDA,  VTM. 

Ergocalciferol  (vitamin  Dj)   No  VTM. 

All  other  vitamin  D    No  DUP. 

Vitamin  E: No 

Dl-alpha  tocopheryl  acetate  (all  grades):  No 

dl-a-Tocopheryl  acetate  (animal  feed  grade)  No  BAS,  HOP,  RDA. 

dl-a-Tocopheryl  acetate  (medicinal  grade) No  BAS,  HOP. 

Other  vitamin  E:   No 

d-a-Tocopherol No  EKT,  SCP. 

d-a-Tocopheryl  acetate No  EKT,  SCP. 

d-a-Tocopheryl  acid  succinate  No  EKT,  SCP. 


See  footnotes  at  end  of  table 


6-11 


Section  6 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 
h/ledicinal  chemicals                                                              statistics '         (according  to  list  in  table  6-3) 

Miscellaneous  medicinal  chemicals:  Yes 

Antineoplastic  agents:   No 

Azathioprine No  BUR. 

Carboplatin No  MRX. 

Cisplatin No  MRX. 

Cytarabine  No  PFN.  UPJ. 

Gallium  nitrate   No  MRX. 

Leuproiide  acetate   No  ABB. 

Procarbazine  hydrochloride  No  HOF. 

Streptozocin No  PFN. 

Vinblastine  sulfate    No  LIL. 

Vincristine  sulfate No  LIL. 

All  other  antineoplastic  agents No  {^. 

Cardiovascular  agents:    No 

Antihypertensive  agents:    No 

Captopnl No  BRS. 

Diazoxide   No  SCH. 

Dilevatol  hydrochloride  No  SCH. 

Hydralazine  hydrochloride   No  CGY. 

Methyldopa No  MRK. 

Metoprolol  tartrate No  CGY. 

Minoxidil  No  UPJ. 

Nadolol No  BRS. 

Phenoxybenzamine    tio  SK. 

Prazosin  No  ABB. 

Prazosin  hydrochloride No  PFZ. 

Sodium  nitroprusside   Nd  ABB. 

Terazosin    No  ABB. 

All  other  antihypertensive  agents,  other  than 

rauwolfia  and  veratrum  alkabids No  MRK. 

Vasodilators: 

Nifedipine  No  PFZ. 

Other  cardiovascular  agents: 

Disopyramide  phosphate   No  GAN,  SRL. 

Procainamide  hydrochloride No  PD,  WYK. 

Propranolol  hydrochloride No  WYK. 

Tocainide No  SDW. 

All  other  cardiovascular  agents No  MRK. 

Diagnostic  agents: No 

Roentgenographic  contrast  media: No 

Diatrizoate,  sodium No  SDW. 

lohexol   No  SD. 

lothalamate,  meglumine No  MAL. 

Other  diagnostic  agents: No 

Albumin No  SPR. 

Edrophonium  chloride    No  MRX. 

Glutamyl-p-nitroaniline  (liver  function  test) No  REG. 

Metyrapone No  CGY. 

Xylose  (intestinal  malabsorption  test) No  PFN. 

All  other  diagnostic  agents,  other  than 

roentgenographic  contrast  media  No  PFZ. 

Hematological  agents:  No 

Anticoagulants: No 

Ammonium  heparin No  SPR. 

Benzalkonium  heparin    No  RIK. 

Lithium  heparin No  SPR. 

Sodium  heparin No  SPR. 

Other  hematological  agents: 

Cellulose,  oxidized   No  EKT. 

Dextran No  PHR. 


See  footnotes  at  end  of  table. 
6-12 


Synthetic  Organic  Chemicals.  1990 

Table  6-2 — Continued 

Medicinal  chemicals  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 

Separata         Manufacturers '  identification  codes 
Medicinal  chemicals  statistics '         (according  to  list  in  table  6-3) 

Miscellaneous  medicinal  chemicals — Continued Yes 

Unclassified  medicinal  chemicals:  No 

Allopurinol No  BUR. 

Aminobenzoic  acid,  potassium  salt   No  WYK. 

Carbidopa No  MRK. 

Etidronate,  disodium No  NOR. 

Levodopa No  SRL. 

Melatonin  No  REG. 

Nicotine  polacrilex    No  WYK. 

Oxiracetam No  SK. 

Tacrine  No  PD. 

All  other  medicinal  chemicals No  ABB.  BIB. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yss.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


6-13 


Section  6 

Table  6-3 

Medicinal  chemicals:  Directory  of  manufacturers,  alphabetical  by  coda,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


ABB Abbott  Laboratories 

ACY American  Cyanamid  Co. 

AJY  Ajay  Chemicals,  Inc. 

AMB American  Bio-Synthetics  Corp. 

AMD Cycio  Products.  Inc. 

ANG Angus  Chemical  Co. 

ARN Arenol  Chemical  Corp. 

ARP Armour  Pharmaceutical  Co. 

ARS Arsynco,  Inc.,  Sub.  Div.  of  Aceto  Corp. 

BAS BASF  Corp. 

Beecham,  Inc.: 

BEE Beecham  Laboratries  Div. 

BIB Beckman  Instruments,  Inc.,  Spinco  Div. 

BKC J,  T.  Baker  Chemical  Co. 

BOC Biocratt  Laboratories,  Inc. 

BOT The  Boots  Company 

BRS Bristol-Myers  Co. 

BUR Burroughs  Wellcome  Co. 

CGY Ciba-Geigy  Corp. 

CHO Ducon 

CHT Chattem.  Inc. 

CPR Certified  Processing  Corp. 

CWN   Upjohn  Co.,  Fine  Chemicals 

DAN Dan  River,  Inc.,  Chemical  Products  Div. 

DOW Dow  Chemical  Co. 

DPW   Deepwater,  Inc. 

DUP E.  I.  duPont  de  Nemours  &  Co.,  Inc. 

Medical  Products  Dept. 

EK Eastman  Kodak  Co.: 

EKT Tennessee  Eastman  Co.  Div. 

FLM Fleming  Laboratories,  Inc. 

GAF GAF  Corp.,  Chemical  Group 

GAN Ganes  Chemicals,  Inc. 

HOF Hoffmann-LaRoche,  Inc. 

HXL Hexcel  Corp.,  Hexcel  Chemical 

Products 

IMC   IMC  Pitman-Moore,  Inc. 

ISP Inspec  Chemical  Corp. 

KAN Kanasco,  LTD 

KLM Kalama  Chemical,  Inc. 

LEM Napp  Chemicals,  Inc. 

LIL Eli  Lilly  &  Co.,  Eli  Lilly  Industries.  Inc. 

LLI Lee  Laboratories,  Inc. 


MAL Mallinckrodt,  Inc. 

MRK   Merck  &  Co.,  Inc. 

MRX   Johnson  Matthey,  Inc. 

NEP Nepera  Inc. 

NOR   Norwich  Eaton  Pharmaceutical.  Inc. 

NUT Bioproducts,  Inc. 

OH Anaquest 

ORG Organics/LaGrange.  Inc. 

ORT   Roehr  Chemicals.  Inc..  Div.  of  Aceto 

Corp. 
PD Parke-Davis  Div.  of  Warner-Lambert 

Co. 

PEN Penick  Corp. 

PFN Ranstiehl  Laboratories,  Inc. 

PFZ Rizer.  Inc.  &  Pfizer  Pharmaceutcals. 

Inc. 

PHR    Pharmachem  Corp. 

RDA   Rhone-Poulenc.  Inc. 

REG   Regis  Chemical  Co. 

SAL Solvay  Animal  Health.  Inc. 

SCH    The  Schering  Corp. 

SCP Henkel  Corp. 

SD Sterling  Drug.  Inc.: 

Sterling  Pharmaceuticals,  Inc. 

SDW Sterling  Organics  Div. 

SK Smithkline  Beecham  Chemk:als 

SPR Scientlfk:  Protein  Laboratories 

SRL G.D.  Searle  &  Co. 

TKD Takeda  Chemical  Product  USA,  Inc. 

TMH   Harcros  Chemicals,  Inc. 

TNA Ethyl  Corp. 

TX Texaco  Chemk:al  Co. 

UCC   Unnn  CarfokJe  Corp.,  Industrial 

Chemcal  Div. 

UPJ Upjohn  Co. 

VTM    Vitamins,  Inc. 

WTL    Atochem  North  America.  Inc.,  Organic 

PeroxkJes  Div. 

WYK  Wyckoff  Chemical  Co..  Inc. 

WYT Wyeth  Laboratories,  Inc..  Wyeth 

Latx>ratories 

Div.  of  American  Home  Products 

Corp. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questkinnaires  of  the  U.S.  International  Trade  Commission. 


6-14 


Section  7 
Flavor  and  Perfume  Materials 

Flavor  and  perfume  materials  are  organic 
chemicals  used  to  impan  flavors  and  aromas  to  foods, 
beverages,  cosmetics,  and  soaps.  These  aroma 
chemicals  are  also  utilized  to  neutralize  or  mask 
unpleasant  odors  in  industrial  processes  and  products, 
as  well  as  in  consumer  products. 

Total  domestic  production  of  fbvor  and  perfume 
materials  in  1990  amounted  to  59.9  million  kilograms 
(see  figure  8-1).  Sales  of  these  materials  in  1990 
amounted  to  36.5  million  kilograms,  valued  at  $991.6 
million,  compared  with  38.4  million  kilograms,  valued 
at  $1,005.2  million,  in  1989.  U.S.  production  of  flavor 
and  perfume  materials  in  1990  decreased  by  6.8 
percent  from  the  level  in  1989  while  the  value  of  sales 
decreased  by  1 .4  percent. 

Production  of  cyclic  flavor  and  perfume  materials 
in  1990  amounted  to  39.5  million  kilograms;  sales 


Synthetic  Organic  Chemicals,  1990 

amounted  to  27.9  million  kilograms,  valued  at  $909.6 
million.  Individual  publishable  chemicals  in  the  cyclic 
group  produced  in  the  greatest  volume  in  1990  were 
anethoie  (1.2  million  kilograms),  and  a-terpineol  (984 
thousand  kilograms). 

U.S.  output  of  acyclic  flavor  and  perfume  materials 
in  1990  amounted  to  20.4  million  kilograms;  sales  of 
these  materials  amounted  to  8.6  million  kilograms, 
valued  at  $70.3  million.  Individual  publishable  acyclic 
flavor  and  perfume  chemicals  produced  in  the  greatest 
volume  in  1990  were,  tetrahydrogeraniol  (266  thousand 
kilograms)  and  geranyl  acetate  (93  thousand 
kilograms). 

Table  8-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 
8-3. 

Eric  Land 
202-205-3349 


Figure  7-1 

Flavor  and  perfume  materials:  U.S.  production,  1986-90 


Millions 
of  kilograms 


100- 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


7-1 


Section  7 

Table  7-1 

Flavor  and  perfume  materials:  U.S.  production  and  sales,  1990 

Sales  Average 

Unit 

Flavor  and  perfume  materials                                                 Production  Quantity  Value           value' 

1.000  1,000  1.000           Per 

kilograms  kilograms  dollars         kitogram 

Grand  total 59.931  36.514  991.612       $27.16 

Cyclic 

Total  39,514  27,867  909.620         32.64 

Benzenoid  and  Naphthalenoid 

Total   30.077  22.304  839.268         37.63 

4-Allyl-2-methoxyphenol  (Eugenol) 11  15  146           9.54 

Benzyl  benzoate 245  255  721           2.82 

Phenethyl  isobutyrate 10  {*)  (')              (*) 

2-Phenethyl  phenylacetate 24  {')  {')              (') 

p-Propenylanisole  (AnetholG)  1.178  1.049  10,027           9.56 

All  other  benzenoid  and  naphthalenoid  materials    ....         28.609  20.985  828.374         39.47 

Terpenoid,  Heterocyclic,  and  Alicyclic 

Total  9.437 5.563  70,352  12.65 

P-Caryophyllene 13  11  82          7.47 

Cedryl  acetate   96  30  424         13.96 

Y-Methylionone 602  288  6,024         20.89 

a-Terpineol 984  692  1,419           2.05 

All  other  terpenoid,  heterocyclic,  and  alicyclic 

materials 7,742  4,542  62,403         13.74 

Acyclic 

Total   20.417 8.647  81 .992  9.48 

Citronellyl  acetate   41  22  261         12.12 

Citronellyl  formate  11  5  109         21.60 

3.7-Dimethyl-cis-2.6-octadienol.  acetate 

(Neryl  acetate) 13  12  129         10.33 

3.7-Dimethyloctanol-1 

(Tetrahydrogeraniol)    266  52  436           8.37 

3.7-Dimethyl-6-octen-1 -ol  (CitroneJIol) 1.198 

Geranyl  acetate 93  77  796         10.34 

All  other  acyclic  materials   18.795  8.479  80.261            9.47 

'  Calculated  from  unrounded  figures. 

'  Reported  data  are  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S,  International  Trade  Commission. 


7-2 


Synthetic  Organic  Chemicals.  1990 


Table  7-2 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,1 990 


Flavor  and  perfume  materials 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  7-3) 


Cyclic: 

Benzenoid  and  naphthalenoid: 

Acetaldehyde  ethyl  phenethyl  acetal   No 

Acetaldehyde  phenethyl  propyl  acetal  No 

2'-Acetonaphthone  (|3-Methyl  naphthyl  ketone) No 

1-Acetoxy-2-sec-butyl-1-ethenylcyclohexane No 

p-Allylanisole    No 

4-Allyl-1,2-diniethoxybenzene  (4-Allylveratrole) No 

4-Allyl-2-mGthoxyphenol  (Eugenoi)    Yes 

l-Amyl  cinnamic  aldehyde    No 

Amyl  cinnamyl  alcohol  No 

p-Anisaldehyde No 

Anisyl  acetate No 

Aurantiol No 

Benzaldehyde  glyceryl  acetal No 

Benzophenone No 

Benzyl  acetate  No 

Benzyl  benzoate Yes 

Benzyl  butyrate No 

Benzyl  isobutyrate   No 

Benzyl  isopentyl  ether   No 

Benzyl  isovalerate    No 

1-(Benzyloxy)-2-methoxy-4-propenylbenzene 

(Benzyl  isoeugenyl  ether) No 

Benzyl  phenylacetate No 

Benzyl  propionate No 

Benzyl  salicylate No 

p-tert-Butyl-a-methylhydroctnnamalehyde No 

Carvacrol  No 

Cineole  [eucalyptol]   No 

Cinnamyl  acetate  No 

Cinnamyl  nitrile No 

Cinnamyl  propionate    No 

Coumarin  No 

Cuminyl  acetate  No 

trans-Decahydro-P-naphthol    No 

Dihydrocoumarin    No 

1 ,2-Dimethoxy-4-propenylbenzene  (4- 

Propenylveratrole)    No 

2.4-Dimethyl-5-acetylthiazole No 

p,4,Dimethyl-3<yclohexene-1-propanal No 

Y,4-Dimethyl-3-cyctohexene-1-propanol No 

3.7-Dimethyl-1 ,  6-octadien-3-yl  formate No 

3, 7-Dimethyl-2,6-octadieny I  phenylacetate 

(Geranyl  phenylacetate) No 

a,a-Dimethylphenethyl  acetate  No 

N-(p-EthoxycarbonylphGnyl)-N'-ethyl-N"- 

phenyHormamidine No 

2-Ethoxynaphthalene No 

Ethyl  benzoate  No 

Ethyl  cinnamate  No 

Ethyl-a,p-epoxy-P-methylhydrodnnamate No 

2-Ethylhexyl-p-methoxy  cinnamate    No 

Ethyl  phenylacetate    No 

Heliotropyl  acetate  No 


IFF. 

IFF 

GIV. 

GIV. 

NCI.  SCM. 

CI. 

BDS.  CI.  ELN.  GIV. 

KLM. 

IFF 

GIV. 

ELN.  GIV. 

BOS. 

GIV. 

CWN.  PD. 

HAR. 

HAR.  KLM.  (*). 

ELN. 

ELN. 

GIV. 

ELN. 

GIV 

ELN.  GIV. 

ELN. 

HAR. 

GIV 

GIV. 

SCM. 

ELN. 

IFF 

ELN. 

RDA. 

IFF 

IFF 

ARS. 

CI. 

STG. 

CI. 

CI. 

GIV 

GIV 
IFF 

GIV 
GIV 
ELN. 
ELN. 
ELN. 
GIV 
ELN. 
IFF 


See  footnotes  at  end  of  table. 


7-3 


Section  7 

Table  7-2 — Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported.  Identified  by 

manufacturer,1990 

Flavor  and  periume  materials  Separate  Manufacturers '  identification  codes 

statistics '  (according  to  list  in  table  7-3) 

Cyclic-Continued 
Benzenoid  and  naphthalenold-Contlnued 

Heliotropyl  acetone No  AMB. 

cis-3-Hexenyl  salicylate  No  BDS.  IFF. 

a-Hexylcinnamaldehyde No  01,  KLM. 

Hydratropaldehyde.dimethyiacetal    No  IFF. 

Hydrocinnamic  acid    No  ELN. 

Hydrocoumarin No  ELN,  GIV. 

Hydroxycitronelial  methyl  anthranilate  No  GIV,  IFF. 

4-Hydroxy-3-ethoxybenzaldehyde  (Ethylvaniiiin)  ....  No  ROA. 

4-Hydroxy-3-methoxyben2aldehyde  [Vaniiiin]    No  RAY,  RDA. 

4(4-Hydroxy-3-methoxyphenyi)-2-butanone 

(Vanillyacetone)    No  GIV. 

p-Hydroxy  phenylbutanone No  GIV. 

Isoamyl  phenylacetate  No  ELN. 

Isobutyl  phenylacetate  No  ELN. 

Isobutylquinoline No  IFF. 

Isohexenyl  tetrahydrobenzaidehyde  (Myrac  aldehyde)  No  IFF. 

Isopentyl  benzoate No  GIV. 

I-Limonene No  SCM. 

Linalyl  anthranilate No  BDS,  FMT. 

p-Mentha-1 ,8-diene  (Limonene) No  IFF,  SCM. 

4.7-Methano-1  H-indene-2-methanol  octahydro 

acetate   No  Ci. 

o-Methoxy  benzaldehyde No  CI. 

p-Methoxybenzyl  alcohol  (Anisyl  alcohol) No  ELN,  GIV. 

2-Methoxynaphthalene No  GIV. 

3-(4-Methoxyphenyl)-2-methyl  propanai   No  CI. 

1 -p-Methoxyphenyl  penten-1-one-3  (a-Methyl- 

anisaiacetone)    No  GIV. 

3-(2-Methoxyphenyl)-2-propenai  No  CI. 

2-Methoxy-4-propenylphenoi  (Isoeugenol) No  CI. 

2-Methoxy-4-propenylphenoi,acetate No  ELN. 

2-Methoxy-4-propylphenol No  CI. 

4'-Methylacetophenone   No  CWN. 

p-Methylanisole   No  GiV. 

Methyl  anthranilate No  PSG. 

P-Methylbenzene  propanai    No  Ci. 

Methyl  benzoate No  KLM,  MRF 

a-Methylbenzyl  acetate  (Styralyl  acetate)   No  IFF. 

a-Methylcinnamaldehyde No  IFF. 

1 ,2-Methylenedioxy-4-propylene  benzene 

(isoSafrole) No  AMB. 

p-Methylhydratropaldehyde No  GIV. 

3-Methylindole  (Skatole) No  GIV. 

Methyl  N-methylanthranilate No  AMB. 

a-Methyl-3,4-methylenedioxyhydrocinnamaldehyde  .  No  GiV. 

Methyl  phenylacetate No  GiV. 

3-Methyl-5-phenyl-1-pentanol    No  IFF. 

Methyl  salicylate No  KLM,  RDA. 

Octahydro-5-methoxy-4.7-methano-1  H-indene,  2- 

carboxaldehyde    No  CI. 

1,1,3,3.5-Pentamethyl-4,6-dinitroindan(Moskene)    ..  No  GiV. 

a-Pentylcinnamaldehyde No  Ci. 

Phenethyl  acetate No  BOS,  IFF 

See  footnotes  at  end  of  table. 

7-4 


Synthetic  Organic  Chemicals.  1990 

Table  7-2— Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  identified  by 

manufacturer,1990 

Flavor  and  perfume  materials  Separate  Manufacturers '  identification  codes 

statistics '  (according  to  list  in  table  7-3) 

Cyclic-Continued 
Benzenoid  and  naphthalenold-Contlnued 

Phenethyl  alcohol No  IFF. 

Phenethyl  formate    No  ELN,  IFF. 

Phenethyl  isobutyrate Yes  ELN.  GIV,  IFF 

Phenethyl  isovalerate No  ELN. 

2-Phenethyl  phenylacetate Yes  BDS.  ELN,  GIV,  IFF. 

Phenethyl  propionate No  ELN. 

2-Pheno)(yethyl  isobutyrate   No  IFF. 

Phenylacetaldehyde No  CI,  GIV. 

Phenylacetaldehyde.dimethyl  acetal   No  (^ 

Phenylacetic  acid No  GIV. 

Phenylethyl  benzoate No  IFF. 

Phenylethyl  2-methyl  butyrate   No  SCM. 

3-Phenylpropyl  acetate No  ELN,  GIV. 

Piperonal  (Heliotropin)  No  AMB. 

p-Propenylanisole  (Anethole) No  ARZ,  HPC,  NCI,  SCM. 

p-Propylanisol  (Dihydroanethole) No  GIV. 

p-Tolyl  acetate   No  ELN. 

p-Tolyl  isobutyrate    No  IFF. 

p-Tolyl  octanoate   No  IFF. 

p-Tolylphenylacetate No  GIV. 

a-(Trichloromethyl)benzyl  acetate  (Rosetone) No  ARS. 

Trimethylcyclohexyl  salicylate    No  ARS. 

Sweeteners,  synthetic: 

Cyclohexanesulfamic  acid  (Cydamlc  add) No  ABB. 

Cydohexanesulfamic  acid,  sodium  salt  (Sodium 

cydamato) No  ABB. 

Saccharin  (1 ,2-Benzisothiazolin-3-one,-1 , 1  • 

dioxide)  No  PSG. 

Saccharin.sodium  salt No  PSG. 

Tetramethyl,  octahydro  acetophenone  No  IFF. 

Tetramethyl  octahydro  acetyl  naphthalene No  IFF. 

Synthetic  sweetner  material, all  other  No  NSW. 

All  other  benzenoid  or  naphthalenoid  chemicals    ....  No  IFF.  PFZ. 
Terpenoid,  heterocyclic,  and  alicyclic: 

Acetyl  cedrene  (Verloflex)   No  BDS. 

N-Acetyl  methyl  anthranilate No  AMB. 

Allo-ocimene No  SCM.  (*). 

Allyl  cydohexyl  propionate No  GIV. 

Amyl  cydohexyl  acetate No  IFF. 

Amyris  acetate No  GIV. 

2-ten-Butyl  cyclohexanol   No  IFF. 

2-sec-Butylcyclohexanone No  GIV. 

o-tert-Butylcyclohexyl  acetate No  CI.  IFF. 

p-ten-Butylcyclohexyl  acetate  (Vert>eniax)   No  IFF. 

CanrenoatG,  potassium    No  IFF. 

I-Carvone   Yes  SCM. 

P-Caryophyliene Yes  BDS.  CI.  GIV 

a-Cedrene  epoxide  (Andrane) No  BDS.  IFF. 

Cedrenol No  BDS.  ELN.  IFF 

Cedrol Yes  ELN.  IFF. 

Cedryl  acetate   Yes  BDS.  ELN.  IFF 

Cydohexyl  ethyl  acetate No  IFF. 

Cyctohexyl  methanol  dimethyl  acetate No  IFF. 

See  footnotes  at  end  of  table. 

7-5 


Section  7 

Table  7-2 — Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,1990 

Flavor  and  perfume  materials  Separate  Mar)ufacturers '  identHicatior)  codes 

statistics '  (according  to  list  in  table  7-3) 

Cyclic-Contlnued 
Terpenoid,  heterocyclic,  and  allcyclic-Contlnued 

Dihydronordicyclopentadienyl  acetate  (Cyclacet) ....  No  CI. 
Dihydronordicyclopentadienyl  propionate 

(Cyciaprop)  (Verdyl  propionate  extra) No  CI. 

Dihydro  terpineol    No  NCI,  SCM. 

Dimethyl  cyclohexane  methanol No  IFF. 

2. 6-Dimethylheptan-2-ol   No  GIV. 

Dimethyl-3-oxo-2-pentylcyclopentane  propanedioate  No  (^. 

Ethyl  furoate No  IFF.  SCM. 

Galaxolide  (1 ,3.4,6,7,8-Hoxahydro-4,6.6.7.8,8- 

hexamethyl-cyclopenta-Y-2-benzopyran) No  IFF. 

Guaiacwood  acetate No  ELN. 

2-Heptylcyclopentanone No  IFF. 

Hexadecanolide No  IFF. 

3-Hydroxy-2-ethyl-4.pyrone  (Ethylmahol)  No  PFZ. 

4-(4-Hydroxy-4-methyl  pentyl)-3-cyclohexene-1 0- 

carbioxaldehyde  (Lyra!) No  IFF. 

3-Hydroxy-2-methyl-4-pyrone  (Maltol) No  PFZ. 

4-Hydroxynonanic  acid,  y-lactone  (Y-Nonalactone)   . .  No  ELN. 

2-(1-Hydroxypentyl)-cyclopentanone No  (^. 

4-Hydroxyundecanoic  acid, y- lactone  (y- 

Undecalactone) Ho  ELN. 

lonone(a-  and  3-) No  NCI.  SCM. 

o-lonone Ho  GIV.  IFF 

B-lonone No  GIV. 

Isobornyl  acetate   No  SCM. 

Isobornyl  methyl  ether  No  SCM. 

Isobornyl  propionate No  ELN. 

Isolongifolene  epoxide  No  GIV. 

Isomenthone No  GIV. 

2-lsopropylcyclohexanol No  GIV. 

6-lsopropyldecalone No  GIV. 

Isopulegyl  acetate No  GIV. 

p-Mentha-1.3-diene  (a-Terpinene) No  SCM. 

p-Mentha-1 ,4-diene  (y-Terpinene)   No  SCM. 

p-Menth-8-en-3-ol  (Isopulegol) No  GIV. 

p-Month-1-en-3-one(Piperitone)  No  GIV. 

p-Menth-4-(8)-en-3-one  (Pulegone) No  GIV. 

1-1-p-Menthen-6-yl-1-propanone No  GIV. 

dl-Menthol,  synthetic    No  HAR,  NCI.  SCM. 

I-Menthol.  synthetic   No  HAR. 

I-Menthyl  acetate   No  SCM. 

Methylionone(a-  and  |3-)    No  GIV.  IFF.  NCI. 

y-Methylionone Yes  BDS.  GIV  IFF,  NCI. 

6-Methyl-a-ionone   No  BDS,  GIV. 

Methyl-3-oxo-2-pentane  acetate No  CI. 

Methyl-2-thiofuroate No  STG. 

Nopyl  acetate No  NCI. 

3-Oxo-2-pentylcyclopropane  acetic  acid    No  (*). 

para-Cymene  No  SCM. 

2-Pentyl-cyclopenten-1-one No  (^. 

1  -Phenysal-1 .2-propanidione No  STG. 

Plinyl  acetate   No  SCM. 

Terpinene-ol  No  SCM. 


See  footnotes  at  end  of  table. 


7-6 


Synthetic  Organic  Chemicals,  1990 

Table  7-2 — Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,1990 

Flavor  and  perfume  materials  Separate  Manufacturers '  identification  codes 

statistics '  (according  to  list  in  table  7-3) 

Cyclic-Continued 
Terpenoid,  heterocyclic,  and  allcycllc-Contlnued 

a-Terpineol Yes  HPC.  NCI,  SCM. 

a-Terpinyi  acetate   No  NCI,  SCM. 

a-Terpinyl  propionate No  ELN. 

3,3,5-TrimGthyl  cyclohexanoi  (m-Homomenthoi)  ....  No  ARS. 

Trimethyl  cyclohexenyl  butenone No  IFF. 

1  -(2,6,6-Trimethyi-2<yclohGxen-1  -yi)-1 ,6-heptadien- 

3-one  (Allyl-a-ionone) No  IFF. 

Trimethyi  norbornane  methanol  No  IFF. 

a,a.5-Trimethyi-5-vinyi-furf uryl  alcohol  and 

tetrahydro-2,2,6-trimGthyl-6-vinyl-3-oi No  GIV. 

5-{2.2.3-Trimethyl(yclopent-3-en-1-yl)-3- 

methylpentan-2-ol No  GIV. 

Vetivenol No  GIV. 

Vetivenyl  acetate    No  BDS.  ELN,  IFF. 

Aii  other  terpenoid, hetercyclic,  or  alicyciic 

flavor  and  perfume  chemicals No  IFF,  SCM,  STG. 

Acyclic: 

Allyl  disulfide    No  IFF. 

Ally!  heptanoate No  ELN. 

Allyl  hexanoate No  ELN. 

Ammonium  isovalerate    No  RSA. 

Butanoicacid,  1-cyctohexylethyl  ester No  (^. 

Butyl  butyri  lactate   No  ELN. 

Citral  dimethyl  acetal  No  IFF. 

Citronellyl  acetate Yes  BDS,  ELN,  GIV,  IFF,  SCM. 

Citronellyl  formate   Yes  BDS,  ELN,  GIV,  IFF. 

Citronellyl  isobutyrate No  ELN,  IFF. 

Citronellyl  nitrile  No  SCM. 

Citronellyl  propionate No  IFF. 

Crude  acetate  mixture  (Linalyl,neryl,geranyy  acetates, 

main  components)  No  NCI. 

Decanal  (Capraldehyde)   No  CI. 

Decyl  acetate No  GIV. 

Diethyl  sebacate No  ELN. 

Diethyl  succinate   No  MRF. 

Dihydrocarvone   No  SCM. 

Dihydrolinalool No  SCM. 

Dihydro  myrcenol No  SCM. 

Dihydro  pentamethyl  indanone    No  IFF. 

Dihydroterpinyl  acetate    No  IFF,  NCI. 

1 , 1  -Dimethoxy  octane    No  IFF. 

3,7-DimGthyl-cis-2,6-octadienal  (Citral  B)  (Neral)    No  NCI. 

3,7-Dimethyl-trans-2,6-octadienal  (Citral  A, 

geranial) No  BDS.  NCI. 

3,7-Dimethyl-2,6-octadienal  (Citral  A  &  B)   No  SCM. 

3,7-Dlmethyl-2,6-octadienenitrile No  CI. 

3.7-Dimothyl-cis-2,6-octadien-1-ol  (Nerol) Yes  ELN,  GIV.  NCI.  SCM. 

3,7-Dimethyl-trans-2,6-octadien-1-ol(Geraniol)    Yes  ELN,  FEL.  GIV.  NCI.  SCM. 

3,7-Dimethyl-1 ,6-octadien-3-ol  (Linalool) 

(Linalyl  alcohol)    No  IFR  SCM. 

3.7-Dimethyl-cis-2,6-octadienol,  acetate  (Neryl 

acetate)    Yes  ELN,  GIV,  IFF,  SCM. 

See  footnotes  at  end  of  table. 

7-7 


Section  7 

Table  7-2 — Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  identified  by 

manufacturer,!  990 


Flavor  and  perfume  materials 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  7-3) 


Acyclic — Continued 
3,7-Dimethyl-1 .6-ocladien-3-ol,acetate  (Linalyl 

acetate)   No 

3,7-Diniethyl-1 .6-octadien-3-yl  isobutyrate    (Linalyl 

isobutyrate) No 

3,7-Dimethyl-1.6-octadien-3-yl  propionate  (Linalyl 

propionate) No 

Dimethyloctanal No 

3.7-Dimethyloctanol-1  (Tetrahydrogeraniol)  Yes 

3.7-Dimethyl-3-octanol No 

Dimethyloctanyl  acetate No 

3,7-Dimethyl-6-octen-1-al  (Citronellal) No 

3.7-Dimethyl-6-octen-1-ol  (Citronellol) Yes 

3,7-Dimethyl-7-octenol  70%,  6sDCtenol  isomer  30%   ...  No 

Ethyl  butyrate No 

Ethyl  heptanoate    No 

Ethyl  hexanoate No 

Ethyl  isovalerate No 

Ethyl  laurate No 

Ethyl-2-methyl  butyrate   No 

Ethyl-2  methyl  pentanoate No 

Ethyl  myristate No 

Ethyl  propionate No 

Ethyl  trimethyl  cyclopentenyl  buterol  No 

Ethyl  valerate No 

Geranyl  acetate  Yes 

Geranyl  butyrate    No 

Geranyl  formate No 

Geranyl  isobutyrate  No 

Geranyl  nitrile  (Citralva) No 

Geranyl  propionate    No 

N-hexanal No 

2-Hexenal No 

cis-3-Hexen-1  -yl  acetate   No 

cis-3-Hexenyl  butyrate No 

cis-3-Hexenyl  methyl  carbonate No 

cis-3-Hexenyl  tiglate No 

Hexyl  2-methylbutyrate    No 

Hydroxycitronellol No 

7-Hydroxy-3.7-dimethyl-1-octanal 

(Hydroxycilronellal) No 

7-Hydroxy-3,7-dimGthyl  octanal,  dimethyl  acetal 

(Hydroxycttronellal,  dimethyl  acetal) No 

lsobutyl-2-butenoate    No 

Isopentyl  acetate  (Isoamyi  acetate) No 

Isopentyl  butyrate No 

Isopentyl  formate No 

Isopentyl  isovalerate    No 

3-Mothyl-2-butonyl  acetate No 

2-Methylbutyl  isovalerate No 

2-MethylenG  undecanal  No 

Methyl  hexyl  ether  No 

Methyl  isobutyrate   No 

Methyl-2-mothyl  butyrate No 


GIV.  SCM. 

GIV. 

GIV. 

SCM. 

GIV,  IFF,  NCi.  SCM. 

NCi.  SCM. 

GiV. 

GiV.  SCM. 

ELN,  GIV,  IFF,  NCI.  SCM. 

GIV 

HPC.  NW. 

ELN. 

ELN.  NW. 

ELN. 

ELN. 

SCM. 

HPC. 

ELN. 

NW. 

IFF. 

ELN. 

BDS.  CI.  ELN.  FEL.  GIV.  IFF.  NCi.  NW. 

SCM. 
ELN.  GIV. 
BDS.  ELN. 
IFF. 

IFF.  SCM. 
ELN. 
Ci. 
GiV 

BDS.  GiV 
SCM. 
IFF. 
BDS. 
SCM. 
SCM. 

GIV  IFF.  SCM. 

GIV 
AMB. 
ELN.  NW. 
GiV  NW. 
ELN. 

ELN,  HPC. 
IFF. 
SCM. 

0. 
SCM. 
HPC. 
SCM. 


See  footnotes  at  end  of  table. 


7-8 


Synthetic  Organic  Chemicals,  1990 

Tabis  7-2 — Continued 

Flavor  and  perfume  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,1990 

Flavor  and  perfume  materials  Separate         Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  7-3) 

Acyclic — Continued 

3-K48thyl-2-[and3]nonene  nitriie No  GiV. 

Methyl-2-nonenoate No  HPC. 

2-Methylundecanal No  CI,  GIV. 

Myrcenyl  acetate   No  IFF. 

Myristaldehyde No  GIV. 

Nonanal  No  CI. 

1,3-Nonanediol  acetate   No  ELN.  GIV  SBC. 

Ocimene No  IFF. 

Ocimenyl  acetate No  IFF. 

Octanal No  CI. 

2-Octene-4-one  No  STG. 

N-Octyl  acetate   No  SCM. 

Octyl  isovalerate   No  GIV. 

Pseudo  IJnalyl  acetate  (Neobergamate) No  IFF. 

Rhodinol No  GIV  IFF 

Tepyl  acetate   No  ELN. 

Tetrahydrolinalyl  acetate   No  SCM. 

Tetrahydromyrcenol No  SCM. 

2.4.6. 8-Tetramethylnonan-1-yl  acetate No  CI. 

Trimethyl-cyclododeca-trienyl  ethanone No  IFF. 

3.5,5-Trimethyl  hexanal  No  IFF. 

Undecanal  No  CI,  GIV 

All  other  acyclic  flavor  and  perfume  materials No  AiP.  IFF.  PFZ. 

^  Chemicals  for  which  seperate  statistics  are  reported  in  this  section  are  indicated  by  'yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  disignated  products. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


7-9 


Section  7 

Table  7-3 

Flavor  and  perfume  materials:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  of  company 

KLM Kalama  Chemical,  Inc. 

MRF   Morilex  Inc. 

NCI Union  Camp  Corp.,  BBA  Div. 

NSW Nutrasweet  Co. 

NW  Norttiwestem  Chemical  Co. 

PD Parke-Davis,  Div.  of  Warner-Lambert 

Co. 

PFZ Pfizer,  Inc. 

PSG   PMC  Inc.,  Specialities  Group,  Inc. 

RAY Rayonier  Chemical  Products  Inc. 

RDA   Rhone-Poulenc,  Inc. 

SBC Scher  Chemicals,  Inc. 

SCM   SCM  Corp.,  Glidco  Organics 

STG McCormick  &  Co.,  Inc 

McCormick-Stange  Flavor  Div. 


ABB Abbott  Laboratories 

AlP Air  Products  &  Chemicals,  Inc. 

AMB American  Bio-Synthetics  Corp. 

ARS Arsynco,  Inc.,  Sub.  Div.,  of  Aceto  Corp. 

ARZ Arizona  Chemical  Co. 

BDS Fragrance  Resources,  Inc. 

CI    Firmenich,  Inc. 

CWN   Upjohn  Co.,  Fine  Chemicals 

ELN Elan  Chemical  Co. 

FEL  Felton  WorkJwide.  Inc. 

FMT Fairmount  Chemical  Co..  Inc. 

GIV    Givaudan  Corp. 

HAR Haarmann  &  Reimer  Corp. 

HPC Hercules,  Inc. 

IFF International  Flavors  &  Fragrances,  Inc. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


7-10 


Section  8 
Plastics  and  Resin  Materials 

Plastics  and  resin  materials  are  high  molecular 
weight  polymers  which,  at  some  stage  in  their 
manufacture,  exist  in  such  physical  condition  that  they 
can  be  shaped  or  otherwise  processed  by  the 
application  of  heat  and  pressure.  The  terms  "plastics," 
"resin,"  and  "polymers,"  can  be  (and  often  are)  us«l 
interchangeably  by  the  trade.  Depending  on  the 
chemical  composition,  manufacturing  [xxxess,  or 
intended  use,  the  commercial  products  may  contain 
piasiicizers,  fillers,  extenders,  stabilizers,  coloring 
agents,  or  other  additives.  There  are  about  40  to  50 
basic  plastics  and  resins  which  are  available 
commercially.  These  basic  materials  are  available  in 
literally  thousands  of  individual  compounds  each  with 
its  distinct  properties  depending  on  the  molecular 
weight  of  the  resin  and  the  types  and  amounts  of  the 
additives  present  Plastics  materials  may  be  molded, 
cast,  or  extruded  into  semirmished  or  finished  solid 
forms.  Resin  materials  may  be  in  the  fonn  of 
solutions,  pastes,  or  emulsions  for  applications  such  as 
protective  coatings,  adhesives,  or  paper  and  textile 
treatment 

Statistics  on  U.S.  production  and  sales  of  synthetic 
plastics  and  resin  materials  for  1990  are  given  in  table 
8-1.  U.S.  production  of  plastics  and  resin  materials  in 
1990  totaled  30,053  million  kilograms,  or  11.3  percent 
more  than  the  26,995  million  kilograms  produced  in 
1989.  From  1986-90,  the  production  of  plastics  and 
resin  materials  increased  irregularly  from  23,790 
million  kilograms  in  1986  to  30,053  million  kilograms 
in  1990,  or  at  an  average,  annual  rate  of  growth  of  6.0 
percent  (see  figure  8-1).  Sales  in  1990  totaled  25,729 
million  kilograms,  valued  at  S30^29  million, 
compared  with  23,819  million  kilograms,  valued  at 
$32,180  million,  in  1989. 

Figure  8-1 

Plastics  and  resin  materials:  U.S.  production,  1986-90 


Synthetic  Organic  Chemicals,  1990 

Thermosetting  maienals  are  those  which  harden 
with  a  change  in  composition  in  the  final  treatment  so 
that  in  their  final  state  as  fmished  articles  they  are 
substantially  infusible  and  insoluble;  that  is,  they 
cannot  again  be  softened  by  heat  or  solvents.  U.S. 
production  of  thermosetting  materials  totaled  4,309 
million  kilograms  in  1990,  compared  with  4,033 
million  kilograms  in  1989.  Production  of  the  most 
important  products  in  1990  included  phenolic  (944 
million  kilograms),  amino  (urea  and  melamine)  resins 
(1,213  million  kilograms),  polyester  resins,  unsaturated 
(537  million  kilograms),  and  alkyd  resins  (349  million 
kilograms). 

Thermoplastic  materials  are  those  which  in  their 
fmal  state  as  finished  articles  can  be  repeatedly 
softened  by  heat  and  hardened  by  a  decrease  in 
temperature.  U.S.  production  of  thermoplastic 
materials  totaled  25,743  million  kilograms  in  1990  (or 
85.7  percent  of  the  total  plastics  and  resin  materials 
output  for  1990),  compared  with  22,962  million 
kilograms  in  1989.  Production  of  the  most  important 
products  in  1990  included  polyethylene  (9,071  million 
kilograms),  polypropylene  (3,465  million  kilograms), 
vinyl  resins  (4,944  million  kilograms),  and  styrene  type 
materials  (4,624  million  kilograms).  In  1990. 
production  of  saturated  polyester  resins  reached  1 ,598 
million  kilograms  (polyethylene  terephthalate  alone 
reached  1348  million  kilograms).  Production  of 
engineering  plastics,  in  the  aggregate,  amounted  to  526 
million  kilograms  in  1990. 

Table  8-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 
8-3. 


Edward  J.  Taylor 
202-205-3362 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


8-1 


Section  8 

Table  8-1 

Plastics  and  resin  materials:  U.S.  Production  and  sales,  1990 


Sales 


Plastics  and  resin  materials 


Production      Quantity 


Value 


Average 

Unit 

value' 


1.000  1.000 

kilograms  kilograms 

dry  basis'  dry  basis' 

Grand  total 30,052.906  25.728.728 

Thermosetting  resins 

Total  4.309.457  3.177.057 

Alkyd  resins,  total 349.019  264.323 

Alkyd-acrylate  cxjpolymer  resins    4.912  2.195 

Phthalic  anhydride  type  290,456  227.789 

Polybasic  acid  type    9.429  6.093 

Styrenated-alkyds  or  copolymer  alkyds 7.057  1.746 

Vinyl  toluene  alkyds 12.962  12,460 

All  other  alkyd  resins   24.203  14.040 

Dk:yandiamide  resins  (an  amino  resin) 1 ,285  1 .461 

Epoxy  resins:^* 

Unmodified 315.895  230.026 

Advanced (158,283)  (100.997) 

Furfuryl  type  resins    6,368  6,375 

Glyoxal-formaldehyde  resins 6,962  (*) 

Melamine-formaldehyde  resins  (an  amino  resin) 109,181  89,639 

Phenolic  and  other  tar  acid  resins 943,851  621 ,871 

Polyester  resins,  unsaturated* 537,224  512.696 

Polyether  and  polyester  polyols  for  urethanes^ 760,612  561 .408 

Polyurethane  elastomers  and  plastics  products. 

total 114.239  98.237 

Elastomers* 62.575  48.605 

Plastics 51,664  49.632 

Urea-formaldehyde  resins  (an  amino  resin)* 1 ,103.881  742.723 

All  other  thermosetting  resins'° 60,940  48,298 

Thermoplastic  resins 

Total  25,743.449  22,551,671 

Acrylic  resins,  total"    683,771  610,847 

Homopolymer  resins,  except  PMMA,  of  acrylic 

or  methacrylic  acid  esters 26,902  21,319 

Polymethyl  methacrylate  (PMMA)  resins 304,726  189,221 

Thermosetting  acrylic  resins    41.395  22.833 

All  other  acrylic  resins    310.748  377,474 


1.000 
dollars 


200.932 
136,992 


235,889 

129,371 


Per 
kilogram 


30,529,355      $1.19 


4,141,133        1.30 


358,212 

1.36 

6,426 

2.93 

276,724 

1.21 

9,119 

1.50 

4,126 

2.36 

21,355 

1.71 

40,462 

2.88 

3,174 

2.17 

535,670 

2.33 

(179.310) 

(1.78) 

9.889 

1.55 

(*) 

C) 

218.729 

2.44 

843.403 

1.36 

735.388 

1.43 

733.484 

1.31 

337.924        3.44 


4.13 
2.76 


.32 
2.68 


26,388,222       1.17 


1,543,286        2.53 


56,290  2.64 

449,571  2.38 

67,142  2.94 

970,283  2.57 


See  footnotes  at  end  of  table. 


8-2 


Synthetic  Organic  Chemicals.  1990 


Table  8-1 — Continued 

Plastics  and  resin  materials:  U.S.  Production  and  sales,  1990 


Plastics  and  resin  materials 


Sales 

Average 
Unit 

Production 

Quantity 

Value 

value' 

1.000 
kilograms 
dry  basis^ 

1.000 
kilograms 
dry  basis' 

1.000 
dollars 

Per 
kilogram 

526.105 
171.762 

470,522 
156,225 

1,551.075 
166,516 

$3.30 
1.07 

288.561 

279.926 

823.034 

2.94 

261,912 
26.649 

253,893 
26,033 

783,991 
39.043 

3.09 
1.50 

1 .598.385 

1.381.640 

2.524,161 

1.83 

1.347.638 

1.147,676 

1.615.026 

1.41 

250,747 

233,964 

909.135 

3.89 

9.070,936 

8,125.164 

7.708,072 

.95 

279,944 

267.621 

371,511 

1.39 

4,675.025 
3,281 .300 

4.310,109 
3,059,978 

4,005.593 
2.912.078 

.93 
.95 

1,393,725 
4.115,967 

1,250,131 
3,547,434 

1.093.515 
3.330,968 

.87 
.94 

3,465,465 

3,146,662 

2,523.573 

.80 

176.016 

157.378 

198.026 

1.26 

77.846 
67.247 
30.923 

64.342 
62,392 
30,644 

60,259 
98,826 
38,941 

.94 
1.58 
1.27 

4.624.113 

3,648,932 

4,481,201 

1.23 

521.932 

519,157 

1.011.673 

1.95 

3,427.928 

679,661 

1,067,546 

1,680,721 

369,320 

348,048 

21,272 

304,933 

2,536,623 
364,259 
954,005 

1.218.359 

327,804 

307,909 

19,895 

265.348 

2,437,499 
419.692 
964,295 

1,053,512 

457.619 

428.315 

29.304 

574,410 

.96 
1.15 
1.01 

.86 
1.40 
1.39 
1.47 
2.16 

Thermoplastics  resins — Continued 

Engineering  plastics'^  

Petroleum  hydrocarbons  resins 

Polyamide  resins,  total 

Nylon  type"  '^   

Non-nylon  type 

Polyester  resins,  saturated,  total"  '^ 

Polyethylene  terephthalate  (PET)    

All  other  saturated  polyesters,  including  Poly- 
butylene  terephthalate,  (PBT)  resins   

Polyethylene  resins,  total 

Ethylene-vinyl  acetate  and  other  copolymer 
resins  

Specific  gravity  0.940  and  below,  totaP^    

Low  density  polyethylene  (LDPE)  resins  

Linear  low  density  polyethylene  (LLDPE) 

resins    

Specific  gravity  over  0.940 

Polypropylene  resins 

Rosin  modifications,  total 

Modified  rosin  (unesterified) 

Modified  rosin  esters   

Rosin  esters,  unmodified  (Ester  gums)   

Styrene  plastics  materials,  total 

Acrylonttrile-butadiene-styrene  terpolymer  (ABS) 
resins  

Polystyrene  homopolymers,  total 

Expandable  polystyrene  beads    

Rubber  modified  polystyrene  

Straight  polystyrene   

Styrene  latexes,  total 

Styrene-butadiene  latexes  

All  other  styrene  latexes 

All  other  styrene  plastics  materials'*  

See  footnotes  at  end  of  table. 


8-3 


Section  8 


Table  8-1 — Continued 

Plastics  and  resin  materials:  U.S.  Production  and  sales,  1990 


Sales 


Plastics  and  resin  materials 


Production     Quantity 


Value 


Average 

Unit 

value' 


1.000 
kilograms 
dry  basis' 
Thermoplastics  resins — Continued 

Vinyl  resins,  total'' 4,943.944 

Polyvinyl  acetate'* 305,943 

Polyvinyl  chloride  and  copolymers 4,247,008 

Vinyl  acetate-acrylate  copolymers 220,976 

All  other  vinyl  and  vinylidene  resins"    1 70,01 7 

All  other  thermoplastic  resins^  194,391 


1.000 
kilograms 
dry  basis' 

4,430,301 


204.811 
3.848.569 
218.696 
158.225 
144.074 


1.000 
dollars 


310,587 
3.203.036 
217.312 
371.383 
766,960 


Per 
kilogram 


4,102,318        $.93 

1.52 

.83 

.99 

2.35 

5.32 


'  Calculated  from  unrounded  figures. 

^  Dry  weight  basis  unless  otherwise  specified.  Dry  weight  basis  is  the  total  weight  of  the  materials  including  resin 
and  coloring  agents,  extenders,  fillers,  plasticizers,  and  other  additives,  but  excluding  water  and  other  liquid  diluents 
unless  they  are  an  integral  part  of  the  materials. 

^  Includes  reactive  diluents  which  are  an  integral  part  of  the  resin.  Excludes  the  weight  of  hardeners  sold  in 
association  with  the  resin  as  part  of  a  two-component  system. 

*  Data  shown  for  advanced  epoxy  resins  are  that  part  of  the  unmodified  epoxy  resins  which  is  further  processed; 
therefore,  the  total  in  parentheses  are  not  included  in  the  grand  total. 

^  Reported  data  were  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

^  Polyester  resins  are  unsaturated  alkyd  resins,  later  to  be  copolymerized  with  a  monomer  (Such  as  styrene  or 
methyl  methacrylate),  and  polyallyl  resins  (such  as  diallyl  phthalate  and  diglycol  carbonate).  Data  are  on  an  "as  sold" 
basis,  including  monomer  if  pari  of  the  resin  system. 

'  In  addition  to  the  polyols,  the  other  principal  starting  materials  used  in  the  production  of  urethane  products  are 
the  isocyanic  acid  derivatives,  mainly  the  80/20  mixture  of  toluene-2.4-  and  2.6-diisocyanate. 

Statistics  for  the  isocyanic  acid  derivatives  are  reported  in  the  "Cyclic  Intermediates"  section  of  the  Synthetic 
Organic  Chemicals  report. 

*  The  data  on  urethane  elastomers  are  believed  to  be  not  fully  representative  of  the  total  urethane  market  in  view 
of  the  very  large  number  of  urethane  elastomer  producers.  The  commission  has  begun  reporting  statistics  for 
urethane  elastomers  in  two  sections,  section  VIII,  plastics  and  resin  materials,  and  section  X,  elastomers  (synthetic 
rubber).  Henceforth  those  polyurethane  products  classified  as  "thermoplastic"  urethane  elastomers  will  be  reported  in 
SOC  section  X:  all  other  urethane  elastomers  will  remain  in  SOC  section  VIII. 

'  Includes  thiourea  resins. 

'°  Includes  acetone-formaldehyde  resins,  giyoxal-formaldehyde  resins  (sales  only),  polybutadiene  resins,  silicone 
resins,  and  certain  other  thermosetting  resins. 

"  Does  not  include  production  or  sales  for  fiber  use. 

'^  Engineering  plastics:  Includes  acetal.  polycarbonate,  polyetheretherketone  (PEEK)  resins,  polyimide  and 
amide-imide  polymers,  polyphenylene  oxide,  polyphenylene  surfide.  and  polysuKone.  Engineering  plastics  are  defined 
in  Whittington's  Dictionary  of  Plastics,  as  "All  plastk:s,  with  or  without  fillers  or  reinforcements,  whk;h  have  mechanical, 
chemical  and  thermal  properties  suitable  for  use  in  constructon,  machine  components  and  chemical  processing 
equipment."  The  above  list  of  plastics  (all  of  which  are  thermoplastic)  was  selected  from  a  larger  group  in  this  source. 
Certain  other  plastics  named  In  Whittington's  Dictionary  as  engineering  plastics,  such  as  ABS  resins,  acrylic  resins, 
and  nylon  resins,  are  not  included  in  the  above  list  as  they  are  published  separately. 

'^  Statistics  for  nylon  6  and  nylon  6/6  which  are  used  in  plastics  applications  (e.g.,  molding,  etc.)  are  included  here. 

'*  Statistics  are  included  here  for  polyethylene  terephthalate  used  in  plastics  appllcatbns  (e.g.,  molding,  etc.) 
Statistics  also  are  included  here  for  production  only  when  the  starting  materials  are  converted  directly  to  a  finished 
product(i.e.,  "in  situ"  production);  polyester  film  and  tape  are  examples  of  such  a  conversion. 

'5  Data  shown  for  LLDPE  resins  are  incomplete  because  several  of  the  leading  producers  of  LLDPE  (e.g..  Union 
Carbide  Corp.)  still  continue  to  aggregate  these  data  with  that  of  LDPE. 

'*  Includes  data  for  a-methyl  styrene  polymers,  methyl  methacylate-butadiene-styrene  (MBS),  styrene  acrytonitrile 
(SAN)  copolymer  resins,  styrene-allyl  alcohol  copolymer  resins,  styrene-divinylbenzene  copolymer  resins, 
styrene-maleic  anhydride  copolymers  resins,  styrene-methyl  methacrylate  copolymers  resins,  and  other  styrene 
resins. 

''  Data  are  on  the  basis  of  dry  resin  content,  excluding  the  weight  of  plasticizers.  extenders,  fillers  coloring  agents, 
stabilizers,  or  impact  modifiers,  unless  othenwise  noted. 

'*  Data  for  polyvinyl  acetate  produced  and  sokJ  in  latex  form  includes  the  weight  of  any  protective  colbids  which 
are  used  as  emulsion  stabilizers  and  form  an  integral  part  of  the  resin  system.  Production  and  sales  do  not  include 
polyvinyl  acetate  used  as  a  reactive  intermediate  for  cx3lyvinyl  alcohol  or  other  vinyl  resins. 

'"  Includes  polyvinyl  alcohol,  polyvinyl  butyral,  polyvinyl  formal,  polyvinylidene  chbride.  and  other  vinyl  resins. 

^  Includes  cellulose  plastics,  coumarone-indene  resins,  fluorocartwn  resins,  phenoxy  resins,  polybutylene  type 
resins,  polyphenyl  aromatic  ester  resins,  and  certain  other  thermoplastic  materials. 

Note. — Data  reported  to  the  U.S.  International  Trade  Commissbn  do  not  necessarily  coincbe  with  that  reported  to  the 
Society  of  the  Plastics  Industry  (SPI)  because  of  differences  in  both  the  reporting  instrucions  and  in  the  coverage  of 
certain  resins. 

Source:  Compiled  from  data  received  in  response  to  questbnnaires  of  the  U.S  Internatbnal  Trade  Commission. 


8-4 


Synthetic  Organic  Chemicals.  1990 

Table  8-2 

Plastics  and  resin  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer, 

1990 


Plastics  and  resin  materials 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  8-3) 


Thermosetting  resins:    Yes 

Acetone-formaldehyde  resins    Yes 

Alkyd  resins: 

Acrylate-alkyd  copolymer  resins No 

Alkoyl  phenol   Yes 

Phthalic  anhydride  type  alkyd  resins   No 


Polybasic  acid  type  alkyd  resins Yes 

Styrenated-alkyds,  or  copolymer  alkyds Yes 

Vinyl  toluene  alkyds  Yes 

All  other  alkyd  copolymers Yes 

Amino  resins: 

Melamine-formakJehyde  resins   Yes 

Thiourea  resins No 

Urea-formakJehyde  resins   Yes 

Dicyandiamide  resins Yes 

Epoxy  resins: 

Epoxy  resins,  advanced Yes 

Epoxy  resins,  unmodified Yes 

Furturyl  type  resins    Yes 

Glyoxal-formaklehyde  resins Yes 

Phenolic  and  other  tar  acid  resins  Yes 


Polybutadiene  resins  Yes 

Polyester  resins,  unsaturated,  and  allyl  resins: 

Allyl  resins    No 

Diallyl  isophthalate No 

Polyester  resins,  unsaturated No 


ACY,  CMP,  FLH,  GP. 

ACY,  CKC,  CPV.  DRC.  FRE,  MNP.  PPG. 
QCP,  REL.  VSP.  (2). 

(\ 

AGO,  ACY,  AKZ.  BLC.  BRU.  CGL.  CJO, 

CPV.  DRC,  DUP.  EW,  FOC.  FRE.  GLD, 

GRG,  GRV 

ICF.  IMI.  JOB.  Lie.  MMM.  MNR  NCR 

OBC.  PPG,  PRT  RCI,  RDA.  REL,  SRY 

TCC.  UNO, 

VSP.  (')  (\  ('),  ev 

CJO,  CKC,  CPV  EW.  FOC.  GLD.  ICR  IMI. 

lOV  PPG.  REL.  SCN.  VSP.  (\ 
CJO,  CKC,  CPV  DRC.  EW.  FRE,  IMI, 

JOB.  MNP.  MRT  SCN,  VSP,  (^. 
BLC,  CGL,  CKC.  CPV  FRE.  GLD.  IMI. 

JOB.  MNR  REL.  (\ 
AGO,  BLC,  CGL.  CJO.  DUR  ICR  MNR 

ACY  AUX.  BOR,  CBD,  CKC,  CPV  DRC. 

GR  GRG,  MNR  MON,  PLS,  PMC,  PPL. 

PST  RCI,  RDA,  REL,  TCC,  WRD. 
CMR 
ACY  AUX,  BOR.  CBD.  CGL,  CKC.  CMR 

CPV  GR  GRV  MMM,  PMC,  PPL.  PST 

RDA.  REL.  SAC,  SOR.  SQA,  VSR 

WPG. 
CMR  ECC.  HCL.  S.  TCC. 

AKZ.  CGL,  CGY,  CKC.  CNI.  CPV  DOW. 
EW.  GE.  GLD.  GRG.  GRV  HXL.  ICR 
Lie.  MID,  MIL.  MMM,  MRT  OCR  PPG, 

RCI.  RDA.  SMO,  VSR  (^). 

ASH.  CGY  CJO,  CKC.  CLU.  CPV  DAN. 
DOW,  HYA,  MNR  NES,  PRT  RCI.  RDA. 

SHC.  UCC,  (*). 

CLU.  DRR.  HVG.  UNO.  WRD. 

AUX.  CMR  HCL.  SQA.  TCC.  WPG. 

ADC.  AR2,  ASH.  BME,  BOR.  BSC.  BTL, 
CBD.  CGL.  CKC.  DRR,  EW,  GE.  GR 
HCL.  HER.  HKD.  HPC,  HVG.  ICR  IMI, 
IRI.  ISR  Lll,  MCA.  MID,  MMM,  NCI. 
OBC.  OCR  PLS,  PSG,  RH.  SCN.  SIM. 
SPL.  UCC.  UNO.  USR,  VSR  VSV  WPG. 
WRD.  (»),  (*),  I?). 

CCS,  CNI.  HCL.  LC,  PSL. 

CMS. 

CMS.  IMI. 

ACY.  ADC.  APH.  ART.  ASH,  CGL.  CKC. 
CMS,  CPV  EW,  GLD,  GRG.  ICR  ICI, 
IMI,  IPC.  JOB,  Lll.  MRT  NCR  OCR 
PPG.  PPL,  RCI.  SCN.  SHX,  SIC,  VSR 


See  footnotes  at  end  of  table. 


8-S 


Section  8 

Table  8-2 — Continued 

Plastics  and  resin  materials  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer, 

1990 


Plastics  and  resin  materials 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  8-3} 


Thermosetting  resin— Continued 

Polyether  and  polyester  polyols  for  urethanes Yes 


Polyurethane  elastomer  and  plastic  products: 
Polyurethane  elastomers  Yes 

Polyurethane  resins  Yes 

Silicone  resins    No 

All  other  thermosetting  resins,  benzenoid    Yes 

Thermoplastic  resins: 

Acrylic  resins:    Yes 

Copolymer  resins  of  acrylic  and/or  methacryllc  acid 

resins: 
Butyl  acrylate  ethyl  acrylate  copolymer  resins   ....    No 
Butyl  methacrylate-ethyl  methylacrylate  copolymer 

resins No 

2-Ethylhexyl  acrylate-methy  acrylate  copolymer 

resins No 

Lauryl  methacrylate-stearyl  methacrylate 

copolymer  resins No 

Other  copolymer  resins  of  acrylic  and/or 

methacrylic  acid  esters No 


Homopoiymer  resins  of  acrylic  and/or  methacrylic 
acid  resins: 
Other  homopoiymer  resins  of  acrylic  and/or 

methacrylic  acldesters Yes 

Polymethyl  methacrylate  (PMMA)    Yes 

Thermosetting  acrylate  resins    Yes 

Cellulose  plastics  and  resins: 

Cellulose  acetate   No 

Cellulose  acetate  butyrate   No 

Cellulose  acetate  propionate   No 

Ethyl  cellulose    No 

Coumarone-indene  resins   No 

Engineering  plastics:    Yes 

Acetal  resins No 

Polycartxjnate  resins   No 


BAS,  BMC.  BPT.  CHC,  CKC,  CPV.  CXI. 
DOW,  PRE,  GRG.  HCF,  ICF,  ICI,  MRT, 
OMC.  PPG.  PPL.  RCI,  RUO,  SLC.  SYT. 
UCC.  WM.  (2). 

ACY  ADC.  ARO.  BPT  CAS,  CGY  CNi, 

DNS.  EPI,  GLC.  HXL,  ICF.  INP.  MRT. 

PPG.  PRC,  QUN.  RUO.  SCN.  SLC. 

SMO.  SYT  USM.  USR.  VSP 
ACO.  BAS.  CGL.  DUP.  EW,  GLD.  GRD. 

HYC,  IMI,  INP  JOB.  LC.  MID,  MO^. 

OMC.  PEL.  SHX.  SIF.  (=*). 
CJO.  DCC.  PEL.  RH,  SPD. 
ACY  AKZ.  BAS,  FRE,  GLD.  ICF,  MID. 

OBC,  REL.  RTC.  S.  TCC.  (\  (\  l^). 


AiP  BFG.  ICI,  RDA.  RH.  TCC.  UOC. 

CGL.  RDA.  UOC. 

RDA.  UOC. 

ICI. 

ACO,  AIR  BPT,  CHP.  CKC.  CPV.  ORB. 
DRC,  FLH,  GGI,  GLD.  iCF.  ICI.  JNS. 
KMP  MON,  NES.  NSC.  PPG.  PRA.  PYi. 
RAS.  RCD.  RCI,  RDA.  RH.  SCN.  SYT. 
TCC.  UCC,  VSP  (2). 


CKC,  CPV.  DRC.  DUP.  ESS.  GRV.  PYI. 

RH,  SAR,  SCP  UOC.  (% 
ART  CTP  CYR.  DUP  JOB.  MRT  PKL. 

RH,  SAR,  SQA,  TCC. 
AIP  AKZ,  CKC,  CPV.  DRC,  DUP  FRE, 

GRV,  ICF,  MID,  MNP,  PPG,  PRA.  RDA. 

REL.  SCP  SM. 

EKT. 
EKT. 
EKT. 
AQU. 
CKC. 

DRR,  DUP  HCL,  PRT 
DOW,  GE.  MOB.  SQA. 


See  footnotes  at  end  of  table. 


8-6 


Synthetic  Organic  Chemicals,  1990 

Table  8-2 — Continued 

Plastics  and  resin  materials  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer, 

1990 


Plastics  and  resin  materials 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  8-3) 


Thermoplastic  resins — Continued 
Engineering  plastics — Continued 

Polyetheretherketone  (PEEK)  resins  No 

Polyimides  and  amide-imide  polymers No 

Polyphenylene  oxide  type  resins   No 

Polyphenylene  sulfide  resins   No 

Fluorocarbon  resins: 

Ethylene/chlorotrifluoro  ethylene  copolymer  (Halar)  .  No 

Polytetrafluoroethylene  (PTFE)   No 

Poly vinylldene  f buride  No 

Polyvinylidene  fluoride  resin No 

All  other  fluorocarton  resins No 

Nylon  6,6-acrylonitrile-butadiene-styrene No 

Petroleum  hydrocarbon  resins Yes 

Phenoxy  (R)  resin  (other  than  for  coating  and 

adhesives)  No 

Plastics  alloys  or  blends No 

Polyamide  resins: Yes 

Non-nylon  type,  polyamide  resins    Yes 

Nylon  type,  polyamide  resins Yes 

Polybutylene  type  resins   No 

Polyester  resins,  saturated:   Yes 

Polybutylene  terephthalate(PBT) No 

Polyethylene  terephthalate  (PET) Yes 

Ail  other  polyester  resins,  saturated Yes 

Polyethylene  and  copolymers  resins: 

Ethylene-vinyl  acetate  (EVA)  copolymer  resins Yes 

Other  ethylene  copolymer  resins  Yes 

Specific  gravity  0.940  and  below  Yes 

Specific  gravity  0.940  and  below   Yes 

Specific  gravity  over  0.940 Yes 

Polypropylene  polymer  and  copolymer  resins Yes 

Polyterpene  resins No 

Rosin  modifications: Yes 

Modified  rosin  (unesterified) Yes 

Modified  rosin  esters    Yes 

Rosin  esters,  unmodified  (Ester  gums) Yes 

Styrene  type  plastics  materials: Yes 

Acrylonitrile-butadiene-styrene  (ABS)  terpolymer 

resins   Yes 

a-Methyl  styrene  polymers Yes 


GE. 

DUP.  EW,  GRG.  PDI.  SON. 

ELP.  GE. 

HCL,  PLC. 

AUS. 

AUS,  DUP.  ICI. 
AUS. 
PAS. 
DUR 
MON. 

ARZ,  CFX,  CXi,  EKX.  ENJ.  GYR.  HPC.  Lll, 
NEV,  (=>). 

IGF.  NEV.  UCC. 
MOB. 

ARZ,  COO,  EFH.  GP.  Lll,  NCI,  OBC.  S. 

SHX.  SQA.  USM. 
ACS.  AGI.  BAS.  BCM.  CTR,  DUP.  GRG. 

HCL.  MON,  RSN.  SKP  USM. 
ENJ.  SHC. 

BAS.  CKC.  DUP.  GE.  HCL,  MOB. 

ACS.  DUP  EKT.  FBI.  GYR,  HCL,  ICI.  IMI. 

MOB,  RDA,  (*). 
ACS.  BPT  CPV,  DUP.  EKT.  GLD.  GRG, 

GYR,  HCL,  iCF.  ICI,  MNP  PPG.  REL. 

SCN.  USM. 

COO.  ENJ.  NSC.  RCI.  USI. 

DOW.  EKT.  EKX.  ENJ.  EVL.  SQA,  C^). 

ACS,  DOW.  DUP.  EKX.  ELP.  ENJ,  LYP. 

SM.  SOC,  SQA,  UCC.  USI. 
CMP.  DOW,  ENJ,  SM.  USI. 
ACS,  CNE,  DOW,  HCL,  HIM,  SLT  SOC, 

UCC.  USI. 
AMO.  ART.  BAS.  CSD.  EKX,  ENJ,  HIM. 

LYP.  MIL.  PLC,  SHC,  SLT  USI. 
ARZ.  GRV.  HPC. 

ARZ,  CJO.  HPC.  NCI.  SYL.  WVA,  C). 
CKC,  CPV  EW,  FRP  GP,  GRV  HCL.  HPC. 

ICF,  Lll.  NCI,  SYL,  WVA. 
ARZ,  CKC,  CPV,  FRP  HPC,  NCI.  SYL 


DOW,  GE,  GRD.  MON. 

AlP  AMO.  ATR.  CKC,  CPV  JNS. 


See  footnotes  at  end  of  table. 


8-7 


Section  8 


Table  8-2 — Continued 

Plastics  and  resin  materials  for  which  U.S.  production  and/or  sales  were  reported,  identified  by  manufacturer, 

1990 


Plastics  and  resin  materials 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  8-3) 


Thermoplastic  resins— Continued 
Styrene  type  plastics  materials — Continued 

Styrene-acrylonitrile  copolymer  resins  (SAN) No 

Polystyrene:  Yes 

Expandable  polystyrene  beads Yes 

Rubber  modilied  polystyrene   Yes 

Straight  polystyrene   Yes 

Styrene  latexes;  Yes 

Styrene-butadiene  latexes   Yes 

All  other  styrene  latexes No 

Other  styrene  copolymers: 

Acrylic-styrene-acrylonitrile No 

Methyl  methacrylate-butadiene  styrene  (MBS) 

resins No 

Styrene-acrylonitnle-a-methyl  styrene No 

Styrene-allyl  alcohol  copolymer  resins No 

Styrene-dlvinylbenzene  copolymer  resins    No 

Styrene-limonone  copolymer   No 

Styrene-maloic  anhydride  copolymer  resins No 

Styrene-maleic  anhydride,  glass  filled    No 

Styrene-maleic  anhydride-isobutanol  terpolymer  . .  No 

Styrene-methyl  methacrylate  copolymer  resins  ...  No 

All  other  styrene  copolymers    No 

Ail  other  styrene  type  plastics  materials No 

Vinyl  resins: 
Polyvinyl  acetate  resins   Yes 

Polyvinyl  alcohol  resins    No 

Polyvinyl  butyral  resins No 

Polyvinyl  formal  resin No 

Vinyl  acetate-acrylate  copolymers  Yes 

Polyvinyl  chloride  and  copolymer  resins:  Yes 

Polyvinyl  chloride  homopolymer  resins No 

All  other  polyvinyl  chloride  copolymer  resins    No 

Polyvinylidine  chloride  resins: Yes 

Latex  type  polyvinylidene  chloride  resins  No 

All  other  vinyl  resins  No 

All  other  thermoplastic  resins,  benzenoid No 


DOW,  GE,  ICI,  MON.  USR. 

ATR.  BAS,  DPI,  HMN.  TXS. 

AMO.  API.  CSD,  DOW,  DPI,  HMN,  PLR. 

SM. 
AEP.  AMO.  API.  ATR.  CSD.  DOW.  DPI. 

GAP.  HMN.  HPC.  KTP,  PLR.  RCD.  SM. 

SOC.  TXS. 

DOW.  GRD.  GYR,  PYI,  RCI,  RDA,  UOC. 
ADC,  CCS.  FRS.  GRD,  SPO,  UCC,  UOC. 

MON, 

CYR,  RH. 
MON. 

HPC.  MON. 
EK.  RH,  TCC. 
AR2.  MON. 
ATR.  JNS.  RSN. 
MON. 
MON. 

ADC.  RCD. 

AlP.  ATR,  CKC,  CPV,  EW,  FLH.  GE.  GGI. 
HPC.  JNS,  MON,  OBC,  PLC,  TCC.  VSP, 

PER,  GYR.  HMN,  ICI. 

AlP.  CGL.  DAN.  FLH.  FLN.  GLD.  GRD. 

JOB.  MNP.  MON.  NSC.  PRA.  PYI.  RCI. 

SQA.  TCC.  UCC.  UOC.  (2). 
AlP.  DUP. 
MON. 

GRG.  MON. 
ACO.  AlP.  CMP.  DAN.  FLH.  GLD.  KMP. 

NCJ.  NTC,  OBC.  PRA.  RCI.  RDA.  RH. 

SPC.  UCC,  UOC,  VSP 

AlP,  BCP,  BFG,  CNT  FOR,  GGC,  GYR. 

HKP,  KYS,  SHT  UCC,  VST  VYN. 
BCP,  BFG,  HKP,  KYS,  VYN. 

BFG,  GRD.  UOC. 

DOW.  DUP.  EW.  FLH.  GLD.  NCJ.  RH. 

UCC. 
DUP.  ENJ,  HCL,  Lll,  NES.  PRC,  RSN. 

TNA.  UOC,  VSR 


'  Chemicals  for  v*(hich  separate  statistics  are  reported  in  this  section  are  indicated  by  yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  t>e  published  are  indicated  by  'no.' 

*  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


8-8 


Synthetic  Organic  Chemicals.  1990 


Table  S-3 

Plastics  and  resin  materials:  Directory  of  nianufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


AGO Adco  Chemical  Co. 

ACS Allied  Signal,  Inc. 

Engineered  Materials  Sector. 

Engineered  Plastic  Div. 

High  Density  Polyethylene  Business 

ACY American  Cyanamid  Co. 

ADC Anderson  Development  Co. 

AEP A  &  E  Plastics  Corp. 

AGI   EMS-American  Grilon,  Inc. 

AlP Air  Products  &  Chemicals,  Inc. 

AKZ Ak20  Coating,  Inc. 

AMO    Amoco  Corp. 

APH Alpha  Corporation  of  Tennessee 

API American  Polymers,  Inc. 

AQU Aqualon  Co. 

ARO Arnco 

ART Aristech  Chemical  Corp. 

ARZ Arizona  Chemical  Co. 

ASH Ashland  Oil,  Inc. 

ATR Atlantic  Richfield  Co.,  Aroo  Chemical 

Co. 

AUS Ausimont  N.V. 

AUX Auralux  Corp. 

BAS BASF  Corp. 

BCM Belding  Chemical  Industries 

BCP Borden  Chemical  &  Plastics  Delaware 

Limited  Partnership 

BFG B.  F,  Goodrich  Co. 

BLC Ranbar  Technology,  Inc. 

BMC Brin-Mont  Chemicals,  inc. 

BME Allied  Signal  Bendix  Corp.,  Friction 

Materials  Div. 
BOR Borden,  Inc..  Packaging  &  Industria 

Products  Div. 

BPT Permuthane  Coatings,  Inc. 

BRU M.  A.  Bruder  &  Sons,  Inc. 

BSC Cascade  Resins.  Inc. 

BTL   BTL  Specialty  Resin  Corp. 

CAS CasChem,  Inc. 

CBD Chembond  Corp. 

CCS Colorado  Chemical  Specialties,  Inc. 

CFX Chemfax,  Inc. 

CGL Cargill,  Inc. 

CGY Ciba-Geigy  Corp. 

CHC Carpenter  Chemical  Co. 

CHP C.  H.  Patrick  &  Co.,  Inc. 

CJO C.  J.  Osborn  Chemicals,  Inc. 

CKC Cook  Composites  and  Polymers 

Company 
CLU CL  Industries,  Inc. 


CMP   Commercial  Products  Co.,  inc. 

CMS   Cosmic  Plastics,  Inc. 

CNE    Oxy  Petrochemicals,  Inc. 

CNI  Conap,  Inc. 

CNT Certainteed  Corp. 

COO H.B.  Fuller  Co. 

CPV Cook  Paint  &  Varnish  Co. 

CSD   Fina  Oil  &  Chemical  Co.,  Cosden 

Chemical  Div. 

CTP Continential  Polymers,  Inc. 

CTR Custom  Resins  Div.  of  Bemis  Co.,  Inc. 

CXI   Chemical  Exchange  Industries,  Inc. 

CYR    CYRO  Industries 

DAN    Dan  River.  Inc.,  Chemical  Products  Div. 

DCC   Dow  Corning  Corp. 

DNS    Dennis  Chemical  Co. 

DOW Dow  Chemical  Co. 

DPI   Dart  Polymers,  Inc.,  Sub  of  Dart 

Container  Corp. 

DRB    Rohm  Tech,  Inc. 

DRC   Dock  Resins  Corp. 

DRR   Delta  Resins  4  Refractories 

DUP    E.  I.  duPont  de  Nemours  &  Co.,  Inc. 

Automotive  Product  Dept. 

Chemicals  and  Pigments  Dept. 

ED/IMG  Dept. 

Petrochemicals  Dept. 

Polymer  Products  Dept. 

ECC   Eastern  Color  &  Chemical  Co. 

EFH E.  F  Houghton  &  Co. 

EK    Eastman  Kodak  Co.: 

EKT Tennessee  Eastman  Co.  Div. 

EKX Texas  Eastman  Co.  Div. 

ELP Rexene  Products  Company 

ENJ Exxon  Chemical  Americas 

EPI   Eagle  Picher  Industries,  Orthane  Div. 

ESS Essential  Industries,  Inc. 

EVL Eval  Company  of  America 

EW   Westinghouse  Electric  Corp.,  Insulating 

Materials  Div. 

FBI    Fibers  Industries,  Inc. 

FER Ferro  Corp.,  Keil  Chemical  Div. 

FLH H.  B.  Fuller  Co. 

FLN Franklin  International 

FOC    Handschy  IrxJustries,  Inc.,  Ink  & 

Chemcals  Div. 

FOR   Fonnosa  Plastics  Corp.  -  U.S.A. 

FRE Freeman  Chemcal  Corp. 

FRP Akzo  Coatings,  Inc. 


See  note  at  end  of  table. 


8-9 


Section  8 

Table  8-3 — Continued 

Plastics  and  resin  materials:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Coda  Name  of  company 

FRS Firestone  Tire  &  Rubber  Co.,  Firestone 

Synthetic  Rubber  &  Latex  Co.  Div. 

GAF GAF  Chemical  Corp. 

GE General  Electric  Co.: 

Electromaterials  Div. 

Specialty  Chemical  Group 
GGC    Georgia-Gulf  Corp.,: 

PVC  Compound  Div. 

Piaquemine  Div. 

GGI   Grow  Group,  Inc. 

GLC General  Latex  &  Chemical  Corp. 

GLD Glidden  Co. 

GP Georgia-Pacrtic  Corp.: 

Resins  Operations 

GRD W.  R.  Grace  &  Co.,  Organic  Chemicals 

Div., 

GRG    P  D.  George  Co. 

GRV Guardsman  Chemicals,  Inc. 

GYR Goodyear  Tire  &  Rubber  Co. 

HCF Cape  Industries 

HCL Hoechst  Celanese  Corp: 

Bayport  Works 

Engineering  Plastics  Div. 

Fibers  Industrial  Div. 

Sou-Tex  Works 

HER Heresite  Protective  Coatings.  Inc. 

HIM   Himont  U.S.A.,  Inc. 

Occidental  Chemk:al  Corp.: 

HKD Durez  Div. 

HKP Polymers  and  Plastics  Div. 

HMN    Huntsman  Chemical  Corp. 

HPC Hercules,  Inc. 

HVG Ametek,  Inc.,  Haveg  Div. 

HXL Hexcel  Corp.,  Hexcel  Chemical 

Products 

Dexter  Corp: 
HYA Dexter  Adhesives  and  Structual  Material 

Div. 

HYC Dexter  Electronic  Materials  Div. 

ICF BASF  Corp.,  Coating  and  Colorants 

ICI   ICI  Americas: 

Film  Group  Div. 

Resin  Div. 

Specialty  Chemical  Div. 

IMI Insulating  Materials,  Inc. 

INP Synair  Corp. 

lOV    Ak20/lovite,  Inc. 

IPC Interplastic  Corp. 

IRI   Stuart-Ironsides,  Inc. 

ISP Indspec  Chemical  Corp. 


Code 


Name  of  company 


JNS S.C.  Johnson  &  Son,  Inc. 

JOB Jones-Blair 

KMP   Kelly-Moore  Paint  Co.,  Inc. 

KTP Kama  Corp. 

KYS Keysor  Century  Corp. 

LC     Lord  Corp.,  Chemical  Products  Group 

Lie   Lilly  Industrial  Coatings,  Inc. 

Lll   Lawter  International,  Inc. 

LYP Lyondell  Petrochemical  Co. 

MCA  Masonite  Corp.,  Alpine  Resin  Div. 

MID Dexter  Corp.,  Dexter  Specialty  Coatings 

MIL  Milliken  &  Co.,  Milliken  Chemical  Co. 

MMM Minnesota  Mining  &  Manufacturing  Co. 

MNP   Mcw^horther,  Inc. 

MOB Mobay  Chemical  Corp.,  Pittsburgh  Div. 

MON Monsanto  Co. 

MRT   Morton  International  Inc.,  Morton 

Chemical  Div. 

NCI  Union  Camp  Corp. 

NCJ National  Casein  of  New  Jersey 

NCP    Niles  Chemical  Paint  Co. 

NES Ruetgers-Nease  Chemical  Co. 

NEV Neville  Chemical  Co. 

NSC   National  Starch  &  Chemical  Corp. 

NTC National  Casein  Co. 

OBC   O'Brien  Corp. 

OCF   Owens-Corning  Fiberglas  Corp. 

OMC Olin  Corp. 

PAS Atochem  North  America,  Inc. 

PDI   Phelps  Dodge  Industries,  Inc.,  Phelps 

Dodge 

Magnet  Wire  Co.  Div. 

PEL Pelron  Corp. 

PKL Plaskolite,  Inc. 

PLC Phillips  66  Co. 

PLR Polysar,  Inc.,  Plastics  Div. 

PLS Plastics  Engineering  Co. 

PMC  Plastics  Manufacturing  Co. 

PPG   PPG  Industries.  Inc. 

PPL Pioneer  Plastk»  Corp. 

PRA Para-Chem  Southern,  Inc. 

PRC   Products  Research  &  Chemical  Corp. 

PRT Pratt  &  Lambert,  Inc. 

PSG    PMC  Specialites  Group 

PSL Plastok  Corp. 

PST Perstorp  Compounds,  Inc. 

PYI    Morion  International,  Inc.,  Morton 

Chemical  Div. 

QCP    Quaker  Chemcal  Corp. 

GUN   K.  J.  Quinn  &  Co.,  Inc. 


See  footnotes  at  end  of  table. 


-10 


Sxniheiic  Organic  Chemicals.  1990 


Tabic  8-3 — Continued 

Plastics  and  resin  materials:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  of  company 

SOR    MW  Manufacturers,  Inc..  Southern 

Resin  Div. 

SPC Insiico  Corp  ,  Sinclair  Paint  Co.  Div. 

SPD General  Electric  Co  .  Silicone  Products 

Dept. 
SPL  Spaulding  Composites  Co.,  Inc. 

SPO    Amenpol  Synpol  Co.  Div  of  Uniroyal 

Goodrich  Tire  Co. 

SQA   Sequa  Chemcals.  Inc. 

SRY Synray  Corp. 

SYL Arizona  Chemical  Co. 

SYT Synthron.  Inc. 

TCC Sybron  Chemicals,  Inc. 

TNA Ethyl  Corp. 

TXS Scon  Polymers.  Inc. 

UCC    Union  Carbide  Corp.,  Industrial 

Chemical  Div. 
UNO  United-Erie.  Inc. 

UOC   Union  Oil  Co.  of  California 

USI   Quantum  Chemical  Corp.,  US!  Division 

USM   Emhart  Corp.,  Bostik  Div. 

USR    Uniroyal,  Chemical  Co  ,  Inc. 

VSP Valspar  Corporaton 

VST Vista  Chemical  Co. 

VSV Valentine  Sugars.  Inc 

VYN Vygen,  Inc. 

WM Inolex  Chemical  Co 

WPG West  Point-Pepperell,  Inc..  Grifftex 

Chemical  Co  Sub. 

WRD Weyerhaeuser  Co. 

WVA   Westvaco  Corp. 


RAS Surface  Coatings.  Inc. 

RCD Polysar,  Inc 

RCI    Reichhold  Chemicals.  Inc. 

RDA Rhone-Poulenc,  Inc. 

REL Akzo  Coatings.  Inc. 

RH  .     Rohm  &  Haas  Co 

RSN Atochem,  Inc.,  Polymers  Div. 

RTC Mount  Vernon  Mills,  Inc. 

RUO Ruco  Polymer  Corp. 

S   Sandoz  Chemicals  Corp..  Color  and 

Chemicals  Div. 

SAC Southeastern  Adhesives  Co. 

SAR Esschem.  Inc 

SCN Schenectady  Chemicals.  Inc. 

SCP Henkel  Corp. 

SHC Shell  Chemical  Co. 

SHT Shintech.  Inc. 

SHX Sherex  Chemical  Co. 

SIC BP  Chemicals.  Inc.,  Silmar  Div. 

SIF BP  Chemicals,  Inc.,  Filon  Div. 

SKP Shakespeare  Co  Monofilament  Div. 

SLC Soluol  Chem  Co..  Inc. 

SLT    Soltex  Polymer  Corp. 

SM Mobil  Oil  Corp.: 

Mobil  Chemical  Co.: 

Chemical  Products  Div. 

Petrochemicals  Div. 

Polystyrene  Business  Group 

SMO    Smooth-On,  Inc. 

SCO Chevron  Corp.,  Chevron  Chemical  Co. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questonnaires  of  the  U.S.  International  Trade  Commission. 


8-11 


Synthetic  Organic  Chemicals,  1990 


Section  9 
Rubber-Processing  Chemicals 

Rubber-processing  chemicals  are  organic 
compounds  that  are  added  to  natural  and  synthetic 
rubber  to  give  them  qualities  necessary  for  their 
conversion  into  fmished  rubber  goods.  In  this  report, 
statistics  are  given  for  cyclic  and  acyclic  compounds  by 
use--such  as  accelerators,  antioxidants,  and  vulcanizing 
agents.  Data  on  production  and  sales  of  rubber- 
processing  chemicals  in  1989  are  given  in  table  9-1. 
Data  on  production  of  rubber-processing  chemicals 
during  1985-89  are  given  in  figure  9-1. 

Production  of  rubber-processing  chemicals  as  a 
group  in  1990  amounted  to  179  million  kilograms,  or  2 
percent  more  than  the  176  million  kilograms  produced 
in  1989.  Sales  of  rubber-processing  chemicals  in  1990 
amounted  to  136  million  kilograms,  valued  at  S458 
milUon,  compared  with  129  million  kilograms,  valued 
at  $474  million,  in  1989. 

The  production  of  cyclic  rubber-processing 
chemicals  in  1990  amounted  to  138  million  kilograms, 
or  11  percent  less  than  the  ISS  million  kilograms 
produced  in  1989.  Sales  of  cyclic  rubber-processing 
chemicals  in  1990  totaled  104  million  kilograms, 
valued  at  S413  million,  compared  with  109  million 


kilograms,  valued  at  $430  million,  in  1989.  Of  the 
total  production  of  cyclic  rubber-processing  chemicals 
in  1990,  antioxidants,  antiozonants,  and  stabilizers 
accounted  for  69  percent,  and  accelerators,  activators, 
and  vulcanizing  agents  for  29  percent.  Production  of 
antioxidants,  antiozonants,  and  stabilizers,  which 
amounted  to  %  million  kilograms  in  1990,  included  59 
milUon  kilograms  of  amino  compounds  and  37  million 
kilograms  of  phenolic  and  phosphite  compounds.  Sales 
of  amino  antioxidants,  antiozonants,  and  stabilizers  in 
1990  amounted  to  73  million  kilograms,  valued  at  $274 
million;  sales  of  phenolic  and  phosphite  compounds 
totalled  26  million  kilograms,  valued  at  $91  million. 

Production  of  acyclic  rubber-processing  chemicals 
in  1990  amounted  to  40  million  kilograms,  or  93 
percent  more  than  the  21  million  kilograms  produced 
in  1989.  Sales  in  1990  totaled  32  million  kilograms, 
valued  at  $44  million,  compared  with  20  million 
kilograms,  valued  at  $43  million,  in  1989. 

Table  9-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  indentified  by  company  name  in  table 
9-3. 

Cynthia  Trcdnor 
202-205-3354 


Figure  9-1 

Rubber-processing  chemicals:  U.S.  production,  1986-90 

MilBons 

of  kilograms 

200 — 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


9-1 


Section  9 

Table  9-1 

Rubber-processing  chemicals:  U.S.  production  and  sales,  1990 


Rubber-processing  chemicals 


Sales 

Average 
Unit 

Production 

Quantity 

Value 

value^ 

1,000 
l<ilograms 

1.000 
kilograms 

1.000 
dollars 

Per 
kilogram 

Grand  Total 

Cyclic 

Total  

Accelerators,  activators,  and  vulcanizing 
agents  total 

Thiazole  derivatives,  total 37.690 

N-tert-Butyl-2-ben20thia2olesulfenamide  ....  10,257 

2,2'-Dithiobis[benzothia2ole] 5.585 

All  other  thiazole  derivatives 21 ,848 

All  other  accelerators,  activators,  and 

vulcanizing  agents^  ^    1 .786 

Antioxidants,  antiozonants.  and  stabilizers, 

total 96.043 

Amino  compounds,  total 59,375 

Substituted  p-phenylenediamines    36,741 

All  other  amino  compounds* 22,634 

Phenolic  and  phosphite  compounds,  total*   ....  36,668 

Polyphenolics 3,281 

All  other  phenolic  and  phosphite 

compounds 33,387 

All  other  cyclic  rubber-processing  chemicals*  ....  2,907 

Acyclic 

Total  40.181 


178,607 

136,411 

457,652 

138,426 

104,280 

413,253 

39,476 

27,381 

108,120 

1,936 


32,131 


17,100 


44,399 


$3.35 


3.96 


3.95 


25,445 

91,020 

3.58 

9,415 

38,628 

4.10 

5,500 

14,252 

2.59 

10,530 

38.140 

3.62 

13.72 


72,851 

274,695 

3.77 

46,557 

183,673 

3.95 

26,600 

123,073 

4.63 

19,957 

60,600 

3.34 

26,294 

91,022 

3.46 

2.529 

18.756 

7.42 

23.765 

72,266 

3.04 

4.048 

30.438 

7.52 

1.38 


^  Calculated  from  unrounded  figures. 

'  Includes  aldehyde-amine  reaction  products,  dithiocarbamates,  and  other  accelerators,  activators,  and  vulcanizing 
agents. 

'  Data  on  dithiocarbamates  included  in  this  table  are  for  materials  used  chiefly  in  the  processing  of  natural  and 
synthetic  rubber.  Data  on  dithiocarbamates,  which  are  used  chiefly  as  fungicides,  are  included  in  the  section  on 
"Pesticides  and  Related  Products." 

*  Includes  aldehyde-  and  acetone-amine  reaction  products  and  other  amines. 

*  Also  includes  other  antioxidants,  antiozonants,  and  stabilizers. 

*  Includes  blowing  agents  and  other  cyclic  rubber-processing  chemicals. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


9-2 


Synthetic  Organic  Chemicals.  1990 

Table  9-2 

Rubber-processing  chemicals  for  which  U.S:  production  and/or  sales  were  reported,  Identified  by 

manufacturer,  1990 

Rubber-processing  chemicals  Separate         Manufacturers'  identification  codes 

statistics '        (according  to  list  in  table  9-3) 

Cyclic: 

Accelerators,  activators,  and  vulcanizing  agents: 
Aldehyde-amine  reaction  products: 

Heptaldehyde-aniline  condensate No  USR. 

Triethyttrimethylenetriamine No  USR. 

All  other  aldehyde-amine  reaction  products,  cyclic  .  No  OUP. 

Oithiocarbamic  acid  derivatives: 

Dibenzyldithiocarbamic  acid,  sodium  salt No  USR. 

Dibenzyidithiocarbamic  acid,  zinc  salt    No  USR. 

Guanidines: 

Dicatechol  borate,  di-o-tolylguanidine  saK   No  VNC. 

All  other  guanidines,  cyclic No  VNC. 

Thiazole  derivatives: 

N-ten-Butyl-2-benzothiazolesulfenamide Yes  BFG,  MON,  USR. 

N-Cyclohexyl-2-benzothiazolesulfenamide No  MON,  USR. 

2,2'-Dithiobis(t>enzothiazolel Yes  BFG,  MON,  USR. 

2-Mercaptobenzothiazole No  MON,  USR. 

2-Mercaptobenzothiazole,  copper  salt   No  ACY. 

2-Mercaptobenzothiazole,  zinc  salt No  USR,  VNC. 

N-Morpholinyl-2-benzothiazolyl  disulfide    No  GYR. 

N-Oxydiethylene-2-benzothiazolesulfenamlde  ....  No  BFG,  USR. 

N-Oxydiethylenethiocarbamyl-N'- 

oxydiethylenesullenamide No  BFG. 

All  other  thiazole  derivatives,  cyclic    No  (^. 

All  other  cyclic  accelerators,  activators,  and 

vulcanizing  agents:  No 

Bis(morpholinothiocarbamoyl)  disulfide   No  ACY. 

Dibenzylamine   No  HXL 

1 .3-Dihydro-4(or  5)-methyl-2H-benzimida2ole- 

2-thlone No  VNC. 

DImethylammonium  hydrogen  Isophthalate No  VNC. 

DI-N,N'-pentamethylenethiuramtetrasulfide No  VNC. 

4,4'-Dlthiodlmorpholine No  MON. 

2-Mercaptotololuimldazole,  zinc  salt No  VNC. 

m-Phenylenebismalelmide No  DUP. 

All  other  accelerators,  activators,  and  vulcanizing 

agents,  cyclic No  DUP,  USR. 

Antioxidants,  antiozonants,  and  stabilizers  : 
Amino  antioxidants,  antiozonants,  and  stabilizers: 
Aldehyde-  and  acetone-amine  reaction  products: 

Olphenylamine-acetone  aldehyde No  USR. 

Oiphenylamine-acetone  condensate No  BFG,  USR. 

All  other  aldehyde  and  acetone-amine  reaction 

products,  cyclic   No  USR. 

Substituted  p-phenylenediamines: 

Alkylaryl-p-phenylenedlamines No  MON. 

N,N'-Bls(1 ,4-dimethylpentyl)-p- 

phenylenediamine No  MON,  UPM. 

N,N'-Bis(1-ethyl-3-methylpentyl)-p- 

phenylenediamine No  UPM. 

N,N'-Bis(1-methylheptyl)-p-phenylenedlamine  .  .  No  UPM. 

N-Cyclohexyl-N'-phenyl-p-phenylenediamine  ...  No  USR. 

Diarylenediamines,  mixed No  GYR. 

N-(1,3-Dimethylbu1yl)-N'-phenyl-p- 

phenylenediamine No  UPM,  USR. 

See  footnotes  at  end  of  table. 

9-3 


Section  9 

Table  9-2 — Continued 

Rubber-processing  chemicals  for  which  U.S.  production  and/or  salas  war*  raportod.  Mantlfiad  by 

manufacturer,  1990 

Rubber-processing  chemicals  Separate        h4anufactur«fs' idenWieation  codas 

statistics '        (according  to  list  in  table  9-3) 

Cyclic-Continued 

Antioxidants,  antiozonants,  and  stabiiizara-Continuad 
Amino  antioxidants,  antiozonants,  and  stabillzars-Contlnuad 
Substituted  p-phenylenediamines: 

N,N'-Di-2-naphthyl-p-phenylenediamina No  BFG. 

N,N'-Diphenyl-p-phenyienediamine   No  BFG. 

N-lsopropyl-N'-phenyl-p-phenylenediamine  ....  No  USR. 

N-(1  -MGthylheptyl)-N'-phenyl-p- 

phenylenediamine No  UPM. 

N-(1  -MethylpentyO-N'-phenyl-p- 

phenylenediamine No  USR. 

All  other  p-Phenylenediamines,  substituted   No  KPI,  USR. 

Other  amines: 

p-Anilinophenol No  BFG. 

1,2-Dihydro-6-ethoxy-2.2,4-trimethykjuinoiine 

(Ethoxyquin)    No  USR. 

1,2-Dihydro-2.2,4-trimethylquinoline No  BFG.  MON. 

Nonyldiphenylamine  mixture  (Mono-,  di-, 

and  tri-)   No  USR. 

Octyldiphenylamine No  BFG,  USR. 

Octyldiphenylamine.  aWtylated No  BFG. 

p-(p-Toluenesultonamido)dlphenylamine   No  USR. 

All  other  amino  antioxidants,  antiozonants,  and 

stabilizers No  FER. 

Phenolic  and  phosphite  antioxidants  and  stabilizers: 
Phosphites: 

All^ylaryl  phosphites  mixed  No  GE. 

Nonylphenyl  phosphites,  mixed No  GE,  USR. 

Polymeric  phosphites  No  GE. 

Polyphenolic  phosphites,  polyalkylated No  BFG,  GE. 

Triaryl  phosphites  No  GE- 

Polyphenolics  (including  bisphenols): 

Bisphenol,  hindered    No  USR. 

4,4'-Butylidenebis(6-ten-butyl-m-cresol) No  MON. 

2,5-Di-sec-butyldecylhydroquinone No  USR. 

2,5-Di-(1,1-dimethylpropyl)hydroquinone No  MON. 

2,2'-Methylenebis(6-tert-butyl-p-aesol)   No  ACY,  FER. 

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol)  ...  No  ACY. 

1 ,1 ,3-Tri(2-methyl-4-hydroxy-5-tert-butylphenyl) 

butane No  ICI. 

All  other  phenolic  antioxidants  and  stabilizers: 

Phenol,  alkylated No  ACY  BFG.  GYR,  NEV. 

Phenol,  hindered No  FER,  GYR.  USR. 

Phenol,  styrenaled,  mixtures No  NEV,  USR. 

N-Stearoyl-p-aminophenol   No  HXL. 

All  other  phenolic  antioxidants No  USR. 

Blowing  agents: 

p,p'-Oxybis(benzenesuHonhydrazide)  No  USR. 

S-Phenyltetrazole No  OMC. 

p-Toluenesulfonylsemicarbazide   No  USR. 

All  other  cyclic  rut>ber-processing  chemicals: 

p-terl-Amylphenol  suHido  (Tackifier)   No  PAS. 

N-(Cyclohexylthio)phthalimide No  MON. 

Diphenyl-4.4'-diphenylmethylenedicarbamate No  USR. 

All  other  rubber-processing  chemicals,  cyclic No  FER. 

See  footnotes  at  end  of  table. 
9-4 


Synthetic  Organic  Chemicals,  1990 

Tabic  9-2-Contlnued 

Rubber-processing  chemicals  for  which  U.S.  production  and/or  sates  ware  reported.  Identified  by 

manufacturer,  1990 

Rubber-processing  chemicals  Separate  Manufacturers' identification  codes 

statistics '  (according  to  list  in  table  9-3) 

Acyclic 

Accelerators,  activators,  and  vulcanizing  agents: 
Dithiocarbamic  acid  derivatives: 

Dialkyldithiocarbamic  acid  derivative   No  VNC,  (*). 

Dibutyldithiocarbamic  acid,  nickel  salt   No  USR,  VNC. 

Dibutyldithiocarbamic  acid,  sodium  salt  No  DUP,  USR,  VNC. 

Dibutyldithiocarbamic  acid,  zinc  salt No  VNC. 

Diethyldithiocarbamic  acid,  cadmium  salt  and 

bis{diethylthiocarbamoyl)disutfide,  mixture No  VNC. 

Diethykjithiocarbamic  acid,  tellurium  salt   No  VNC. 

DiethyWithracarbamic  acid,  zinc  salt No  VNC. 

Oimethyldithiocarbamic  ackJ,  bismuth  salt   No  VNC. 

Dimethyldithiocarbamic  ackJ,  copper  salt No  VNC. 

Dimethyldithiocarbamic  acid,  lead  salt  No  VNC. 

Dimethyldithiocarbamic  acid,  selenium  salt   No  VNC. 

Dimethyldithiocarbamic  acid,  zinc  salt   No  VNC. 

All  other  dithkjcarbamic  acid  derivatives,  acyclk;  . .  No  (^. 
Thiurams: 

Bis(dibutylthiocarbamoyl)  disulfide No  VNC,  {% 

Xanthates  and  sulfides: 

Di-n-butylxantho  disulfide No  USR. 

Zinc  isopropyl  xanthate No  VNC. 

All  other  xanthates  and  sulfkjes,  acyclk: No  USR. 

All  other  acyclic  accelerators,  activators,  and 
vulcanizing  agents: 

All  other  accelerators,  activators,  and  vukranizing 

agents,  acyclic No  DUP,  (^). 

Polymerization  regulators: 

n-Oodecyl  mercaptans No  PAS,  PLC. 

tert-Nonyl  mercaptan   No  PAS.  PLC. 

n-Octyl  mercaptan   No  PAS,  PLC. 

All  other  polymerization  regulators,  acyclic   No  PLC. 

Shonstops: 

Dimethykjithiocarbamcackj,  potassium  salt  No  USR. 

DimethyWithiocarbamc  ackJ,  sodium  salt No  ALC,  USR,  VCC,  VNC. 

All  other  acyclk;  rubber-processing  chemcals: 

Cobalt  borate  neodecanoate  complexes   No  KCH. 

Waxes  and  paraffinic  products No  DUP. 

Zinc  laurate  (Activator,  physical  property 

improver,  and  processing  auxiliary)    No  USR. 

All  other  rubber-processing  chemicals,  acydc No  VNC. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yes.'  Chemcals  for  whch 

data  are  accepted  in  confidence  and  may  not  be  published  are  indk:ated  by  'no.' 

^  The  manufacturer  dkj  not  consent  to  his  identificatkin  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questnnnaires  of  the  U.S.  Internatnnal  Trade  Commlssk>n. 


9-5 


Section  9 

Table  9-3 

Rubber-processing  chemicals:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code  Name  of  company 

ACY American  Cyanamid  Co. 

ALC AIco  Chemical  Corp. 

BFG B.F.  Goodrich  Co.,  B.F.  Goodrich 

Chemical  Group 
DUP E.  I.  duPont  de  Nemours  &  Co.,  Inc. 

Chemicals  and  Pigments  Dept. 

Polymer  Products  Dept. 

FER Ferro  Corp.,  Bedford  Chemical  Div. 

GE General  Electric  Co.,  Speciality 

Chemical  Group 

GYR Goodyear  Tire  &  Rubber  Co. 

HXL Hexcel  Corp.,  Hexcel  Chemical 

Products 


Code 


Name  of  company 


ICI ICI  Americas,  Inc.,  Specialty  Chemicals 

Div. 

KCH    Manchem,  Inc. 

KPI   Kenrich  Petrochemicals,  Inc. 

MON Monsanto  Co. 

NEV Neville  Chemical  Co. 

OMC Olin  Corp. 

PAS Atochem  North  America,  Inc. 

PLC Phillips  66  Co. 

UPM  UOP,  Inc. 

USR   Uniroyal  Chemical  Co.,  Inc. 

VCC   Vinings  Chemical  Co. 

VNC   Vanderbitt  Chemical  Corp. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  atx>ve  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


9-6 


Synlhelic  Organic  Chemicals.  1990 


Section  10 
Elastomers 

Elastomers  (syniheiic  rubber)  are  high  polymeric 
materials  with  properties  similar  to  those  of  natural 
rubber.  The  term  "elastomers"  as  used  in  this  report 
means  substances,  whether  in  bale,  crumb,  powder, 
latex,  or  other  crude  form,  which  can  be  vulcanized  or 
similarly  processed  into  a  material  that  can  be  stretched 
to  at  least  twice  their  original  length:  and,  after  having 
been  so  stretched  and  the  stress  removed,  will  return 
with  force  to  approximately  their  original  length.  U.S. 
production  and  sales  of  elastomers  in  1990  are  shown 
in  table  10-1. 

Total  U.S.  production'  of  synthetic  rubber  in  1990 
amounted  to  2,233  million  kilograms,  an  increase  of 
6.8  percent  from  that  produced  in  1989.  The 
production  of  synthetic  rubber  increased  irregularly 
from  1,851  million  kilograms  in  1986  to  2,233  million 
kilograms  in  1990,  or  by  20.6  percent  (see  figure 
10-1).  Total  sales  of  elastomers  in  1990  amounted 
1^55  million  kilograms,  an  increase  of  ll.S  percent 
from  that  sold  in  1989. 


'  Until  now  urethane  type  elastomers  have  been  included  in  the 
section  VIII  "Plastics  and  Resin  Materials."  The  Commission 
has  now  begun  reporting  statistics  for  urethane  elastomers  in 
two  sections,  section  VIII,  plastics  and  resin  materials,  and 
section  X,  elastomers  (synthetic  rubber).  Henceforth  those 
polyureihane  products  classified  as  "thermoplastic"  urethane 
elastomers  will  be  reported  in  SOC  section  X;  all  other  urethane 
elastomers  will  remain  in  SOC  section  Vm. 


Styrene-buiadiene  rubber  (SBR-type  rubber)  in 
1990  continued  to  be  the  elastomer  produced  in  the 
greatest  quantity  as  it  has  been  for  more  than  35  years. 
U.S.  production  of  SBR-iype  rubber,  including 
vinylpyridine  sub-type,  amounted  to  900  million 
kilograms  in  1990.  Polybutadiene  rubber,  mainly 
solution-polymerized  type,  was  produced  domestically 
in  1990  in  the  next  largest  amouni-349  million 
kilograms.  Other  principal  types  of  synthetic 
elastomers  for  which  U.S.  production  data  are  reported 
separately  are  ethylene-propylene  rubber,  production  of 
which  was  232  million  kilograms  in  1990; 
buiadiene-acrylonitrile  (nitrile  or  NBR-type)  rubber, 
production  of  which  was  58  million  kilograms  in  1990; 
and  thermoplastic  elastomers  (a  family  of  products), 
production  of  which  was  237  million  kilograms  in 
1990. 

Sales  of  SBR-type  rubber,  including  its 
vinylpyridine  sub-type,  by  U.S.  producers  in  1990 
amounted  to  604  million  kilograms.  In  1990,  sales  of 
polybutadiene  rubber  amounted  to  176  million 
kilograms,  and  those  of  ethylene-propylene  rubber  to 
204  million  kilograms.  Sales  of  nitrile  or  NBR-type 
rubber  amounted  to  57  million  kilograms,  silicone  type 
elastomer  sales  amounted  to  68  million  kilograms,  and 
sales  of  thermoplastic  elastomers  amounted  to  167 
million  kilograms  in  1990. 

Table  10-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacture(s)  of  each  by  code. 
These  codes  are  identified  by  company  names  in  table 
10-3. 

Edward  J.  Taylor 
202-205-3362 


Figure  10-1 
Elastomers: 


U.S.  production,  1986-90 


Billions 
of  kilograms 

5 


1986  1987  1988  1989  1990 

Source:    Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


10-1 


Section  10 

Table  10-1 

Elastomers  (synthetic  rubber):'  U.S.  production  and  sales,  1990 


Elastomers 


ProductiorP^ 


Sales 


Quantity^       Value 


Average 

Unit 

value-' 


1,000 
kilograms 

Grand  total 2.233,076 

Butadiene-acrylonitrile  type  (nitrile)  (NBR-type)   57,889 

Ethylene-propylene  type  (EP-type)  232,336 

Polybutadiene  type  (BR-type)  349.199 

Silicone  (Q)  type  elastomers 94.698 

Sty rene-butadiene  type  (SBR-type)* 900,175 

Thermoplastic  elastomers  (such  as  styrene-block 

copolymers, thermoplastic  olefin  elastomers, 

thermoplastic  polyurethane  elastomers, 

and  co-polyesters) 256,787 

All  other  elastomers* 341,992 


1.000 
kilograms 


1,000 
dollars 


56,894 
204,101 
175,575 

68.412 
604,301 


166,995 
278,844 


117,044 
415,460 
196,262 
508,308 
741 ,988 


464,322 
684,479 


Per 
kitogram 


1,555,122      3,127,863      $2.01 


2.06 
2.04 
1.12 
7.43 
1.23 


2.78 
2.45 


'  The  term  "elastomers"  is  defined  as  substances  in  bale,  crumb,  powder,  latex,  and  other  crude  forms  which  can 
be  vulcanized  or  similarly  processed  into  materials  that  can  be  stretched  at  68°  F.  to  at  least  twice  their  original  length 
and  after  having  been  stretched  and  the  stress  removed,  will  return  with  force  to  approximately  their  original  length. 

*  Includes  oil  content  of  oil-extended  elastomers. 
^  Calculated  from  unrounded  figures. 

*  About  three-fourths  of  SBR  elastomer  production  is  the  dry  type  of  product.  The  data  includes  the 
styrene-butadiene  vinylpyridine  type. 

*  Includes  butyl,  chlorinated  natural  rubber,  chlorosulfonated  polyethylene,  epichlorohydrin,  fluoroelastomers, 
polyacrylic  ester  type,  polychloroprene  (neoprene)  type,  polyisoprenes  (including  cyclorubber),  polysulfide,  and 
miscellaneous  elastomers. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


10-2 


Synthetic  Organic  Chemicals,  1990 

Table  10-2 
Elastomers  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by  manufacturer,  1990 


Elastomers 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  10-3) 


Cyclic  elastomers: 

Styrene-butadiene  (S  or  SBR)  type: Yes 

Styrene-butadiene,  dry  type No 

Styrene-butadiene,  latex  type No 

Styrene-butadiene-vinyipyridine No 

Styrene-butadiene  type  elastomers,  other No 

Thermoplastic  elastomers  (such  as  styrene-block  , 
copolymers,  thermoplastic  olefin  elastomers, 
thermoplastic  polyurethanes  elastomers,  and  oo- 

polyester)  Yes 

Acyclic  elastomers: 

Butadiene-acrylanitrile  type  (nitrile)  (NBR-type) Yes 

Butyl  (isobutylene-isoprene)  type No 

Chlorinated  rubber,  natural  and  synthetic    No 

ChlorosuHonated  polyethylene  (CSM)  type  No 

Ethylene-propylene  (EP)  type   Yes 

Fluorelastomers  (CFM,  FKM,  FFKM)  type No 

Polyacrylic  (ACM)  type  elastomers   No 

Polybutadiene  acrylic  acid  acrylonitrile  terpolymer 

(PBAN) No 

Polybutadiene  (br)  type: Yes 

Polybutadiene,  emulsion-polymerized  No 

Polybutadiene,  solution-polymerized  No 

Polychloroprene  (Neoprene)  (CR)  type No 

Polyisoprene  (IR)  type  No 

Polysulfide  (T)  type  elastomers  No 

Silicone  (Q)  type  elastomers  Yes 

All  other  acyclic  elastomers No 


BFG,  CPY  FRS,  GYR,  SPO. 
BAS.  BFG.  GNT,  GRD,  GYR,  MMM. 
FRS,  GNT  GYR. 
ASY.  LC. 


BAS,  BFG,  DOW.  ENJ.  FRS,  GEP,  HCL. 
MON,  SHC,  TNA. 

BFG,  CPY  GYR.  RCI.  USR. 

ENJ. 

DOW. 

DUP. 

CPY  DUP,  ENJ,  USR. 

DUP,  MMM. 

ACY 

ASY 

GNT,  GYR.  RCI,  SPO. 

ASY  FRS,  GYR,  PLC. 

DUP  LC. 

GYR. 

MRT 

DCC.  DUP,  MRT.  SPD,  SWS. 


'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


10-3 


Section  10 

Table  10-3 

Elastomers  (synthetic  rubber):  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  ot  company 


Ck)de  Name  of  company 

HCL Hoechst  Celanese  Corp.,  Engineering 

Plastics  Div. 

LC    Lord  Corp.,  Chemical  Products  Group 

MMM Minnesota  Mining  and  Manufacturing 

Co. 

MON Monsanto  Co. 

MRT  Morton  International,  Inc.,  Morton 

Chemical  Div. 

PLC Phillips  66  Co. 

RCI Reichold  Chemicals,  Inc. 

SHC   Shell  Chemical  Co. 

SPD General  Electric  Co.,  Silicone  Products 

Dept. 
SPO   Ameripol  Synpol  Co.,  Div.  of  Uniroyal 

Goodrich  Tire  Co. 

SWS Wacker  Silicones  Corp. 

TNA Ethyl  Corp 

USR   Uniroyal  Chemical  Co.,  Inc. 


ACY American  Cyanamid  Co. 

ASY American  Synthetic  Rubber  Corp. 

BAS BASF  Corp. 

BFG B.  F  Goodrich  Co. 

CPY Copolymer  Rubber  &  Chemical  Corp. 

DCC Dow  Corning  Corp. 

DOW Dow  Chemical  Co. 

DUP E.  I.  duPont  de  Nemours  &  Co.,  Inc., 

Polymer  Products  Dept. 

ENJ  Exxon  Chemical  Americas 

FRS Firestone  Tire  &  Rubber  Co.,  Firestone 

Synthetic  Rubber  &  Latex  Co.  Div 

GEP General  Electric  Co.,  Plastic  Div. 

GNT Gencorp  Polymers  Products 

GRD W.  R.  Grace  &  Co.,  Organic  Chemicals 

Div 

Polymers  &  Chemical  Div. 
GYR Goodyear  Tire  &  Rubber  Co. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app  A. 
Source:  Compiled  from  data  recieved  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


10-4 


Synthetic  Organic  Chemicals.  1990 


Section  11 
Plasticizers 

Plaslicizers  are  organic  chemicals  that  are  added  to 
syniheiic  plastics  and  resin  materials  to  (1)  improve 
workability  during  fabrication,  (2)  extend  or  modify 
the  natural  properties  of  these  materials,  or  (3)  develop 
new  improved  properties  not  present  in  the  original 
material.  Table  11-1  presents  statistics  on  U.S. 
production  and  sales  of  plaslicizers  in  as  great  detail  as 
is  possible  without  revealing  the  operations  of 
individual  producers. 

U.S.  production  of  plasticizers  totaled  891  million 
kilograms  in  1990,  a  decrease  of  8.7  percent  from  the 
976  million  kilograms  reported  for  1989.  The  trend  of 
production  of  these  products  is  shown  in  the  graph  in 
Tigure  11-1.  Sales  of  plasticizers  totaled  827  million 
kilograms,  valued  at  S967  million,  in  1990  compared 
with  837  million  kilograms,  valued  at  $1,046  million, 
in  1989. 

Production  of  cyclic  plaslicizers  in  1990,  which 
consisted  chiefly  of  the  esters  of  phthalic  anhydride, 
phosphoric  acid,  and  trimellitic  acid,  amounted  to  640 


miUion  kilograms,  an  decrease  of  12.9  percent  from 
the  735  million  kilograms  reported  for  1989.  Sales  of 
cychc  plasticizers  in  1990  totaled  644  million 
kilograms,  valued  at  S665  million,  compared  with  634 
million  kilograms,  valued  at  S704  million,  in  1989. 
The  most  important  cyclic  plaslicizers  were  the  dioctyl 
phthalates,  with  production  of  141  million  pounds,  in 
1990. 

Production  of  acyclic  plasticizers  in  1990  totaled 
251  million  kilograms,  an  increase  of  3.7  percent  from 
the  242  million  kilograms  reported  for  1989.  Sales  of 
acyclic  plasticizers  totaled  182  million  kilograms, 
valued  at  S301  million,  in  1990,  compared  with  202 
million  kilograms,  valued  at  S342  million,  in  1989. 
Adipic  acid  esters  were  the  most  important  acyclic 
plasticizers  in  1990  with  production  of  87  million 
kilograms. 

Table  11-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 
11-3. 

Jesse  Lawrence  Johnson 
202-205-3351 


Figure  11-1 

Plasticizers:  U.S.  production,  1986-90 


Millions 
of  kilograms 


1200 


1000 


800 


600 


400 


200 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


ll-I 


Section  U 

Table  11-1 

Plasticlzers:  U.S.  production  and  sales,  1990 


Plastidzers 


Sales 

Average 

Unit 

value' 

Production ' 

Quantity 

Value 

1.000 
kilograms 

1.000 
kilograms 

1.000 
dollars 

Per 
kitogram 

890.718 

826.527 

966.517 

$1.17 

754,231 
136,487 

716.678 
109.849 

795,127 
171,390 

1.11 
1.56 

640,099 

644.104 

665,385 

1.03 

573.892 

572.137 

544.485 

.95 

7,917 
93,575 

7.714 
93.911 

7,936 
78,011 

1.03 
.83 

5.679 
140.649 
326.072 

5.194 
149.805 
315.513 

5,830 
119.159 
333.549 

1.12 

.80 

1.06 

22.942 
43.265 

28,631 
43,336 

44,524 
76,376 

1.56 
1.76 

250.619 

182,423 

301,132 

1.65 

87.020 

46,683 

79,371 

1.70 

24.228 

1.494 

61.298 

24,587 

732 

21,364 

30,498 

1.211 

47.662 

1.24 
1.65 
2.23 

52.904 

28,820 

59,484 

2.06 

47.456 

46.518 

54.132 

1.16 

805 

775 

1,149 

1.48 

3.139 

2.902 

14,995 

5.17 

259 
2.880 

268 
2.634 

1.008 
13.987 

3.76 
5.31 

5.093 

4.850 

8.632 

1.78 

3.444 
1.649 

3,406 
1,444 

4,338 
4,294 

1.27 
2.97 

Grand  total  

Benzenoid'    

Nonbenzenoid 

Cyclic 

Total  

Phthalic  anhydride  esters,  total  

Dibutyl  phthalates  (including 

diisobutyl  phthalates)  

Diisononyl  phthalate 

Dimethyl  phthalate  (including 

dimethyl  isophthalate) 

Dioctyl  phthalates* 

All  other  phthalic  anhydride  esters 

Trimellitic  acid  esters 

All  other  cyclic  plasticizers* 

Acyclic 

Total  

Adipic  acid  esters,  total  

Di(2-ethylhexyl)  adipate 

Diisodecyl  adipate   

All  other  adipic  acid  esters 

Complex  linear  polyesters  and 

polymeric  plasticizers 

Epoxidized  esters    

Butyl  oleate  

Sebacic  acid  esters,  total 

Dibutyl  sebacate 

Sebacic  acid  esters,  all  other 

Stearic  acid  esters,  total    

Isobutyl  stearate 

All  other  stearic  acid  esters   

All  other  acyclic  plasticizers* 54.202 

See  footnotes  at  end  of  table. 


51,875 


83,369 


1.61 


11-2 


Synthetic  Organic  Chemicals,  1990 


Table  11-1 — Continued 

Plasticlzers:  U.S.  production  and  sales,  1990 


'  Includes  data  tor  compounds  used  principally  (but  not  exclusively)  as  primary  plasticizers.  Does  not  include 
clearly  defined  extenders  or  secondary  plasticizers. 

^  Calculated  from  unrounded  figures. 

^  Includes  benzenoid  products  as  defined  in  part  1 ,  schedule  4,  of  the  Tariff  Schedules  of  the  United  States 
Annotated. 

*  The  difference  between  the  production  reported  here  and  that  shown  on  the  Proliminary  Report  on  U.S. 
Production  of  Selected  Organic  Chemicals  (including  Synthetic  Plastics  and  Resin  Materials),  1989,  results  from  a 
combination  of  incorrect  reporting  by  some  companies,  end-of-year  inventory  adjustments,  and  rounding. 

*  Includes  data  for  cresyl  diphenyi  phosphate,  dibutyl  phenyl  phosphate,  diphenyl  octyl  phosphate,  tricresyl 
phosphate,  triphenyl  phosphate,  and  other  cyclic  phosphoric  acid  esters,  glycol  dibenzoates,  toluenesulfonamides, 
tetrahydrofurfuryl  oleate,  and  other  cyclic  plasticizers. 

^  Includes  data  for  azelaic  acid  esters,  citric  and  acetylcitric  acid  esters,  myristic  acid  esters,  pelargonic  acid 
esters,  ricinoleic  and  acetylricinoleic  acid  esters,  glyceryl  and  glycol  esters,  and  other  acyclic  plasticizers. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


11-3 


Section  11 

Table  11-2 

Plastlcizers  for  which  U.S.  production  and/or  sales  werereported,  Identified  by  manufacturer,  1990 


Plasticizers 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  11-3) 


Cyclic  plastlcizers: 

N-n-butyl  benzenesutfonamide    No 

Diethylene  glycol  dibenzoate No 

Dipropanediol  dibenzoate  (Dipropylene  glycol 

dibenzoate) No 

N-Ethyl-p-toluenesutfonamide No 

Phosphoric  acid  esters: 

Isodecyl  diphenyl  phosphate   No 

Tricresyl  phosphate   No 

Triphenyl  phosphate No 

All  other  phosphoric  acid  esters No 

Phthalic  anhydride  esters:   Yes 

Bis(2-ethylhexyl)terephthlate  No 

Butyl  benzyl  phthalate    No 

Butyl  octyl  phthalates No 

Di(2-butoxyethyl)  phthalate No 

Dibutyl  phthalate  (including  diisobutyl  phthalate)  ....  Yes 

Dicyclohexyl  phthalate  No 

Diethyl  isophthalate   No 

Diethyl  phthalate No 

Di-(n-heptyl-n-nonyl)  phthalate No 

Di-(n-heptyl-n-nonyl)  undecyl  phthalate No 

Diisodecyl  phthalate No 

Diisononyl  phthalate Yes 

Dimethyl  isophthalate No 

Dimethyl  phthalate  No 

Dinonyl  phthalate  No 

Dinonyl  undecyl  phthalate   No 

Di-tridecyl  phthalate  No 

Diundecyl  phthalate   No 

Hexyl  n-decyl  phthalate   No 

n-Octyl  n-decyl  phthalate  No 

Dioctyl  phthalates:   Yes 

Di(2-ethylhexyl)  phthalate No 

Diiso-octyl  phthalate No 

Di-n-octyl  phthalate No 

All  other  dioctyl  phthalates  No 

Glycol  phthalate  esters: 

Butyl  phthalyl  butyl  glycolate No 

All  other  glycol  phthalate  esters  No 

All  other  phthalic  anhydride  esters     Yes 

Polyethylene  glycol  dibenzoate  No 

Tetrahydrofurfuryl  oleate    No 

Toluenesulfonamide  o-,  p-mixtures   No 

Trimellitic  acid  esters: Yes 

Tri(2-ethylhexyl)  trimellitate    No 

Tri-n-hexyltrimellitate   No 

Triisodecyl  trimellitate No 

Triisononyl  trimellitate No 

Triiso-octyl  trimellitate No 

Trimethyl  trimellitate No 

Tri-n-octyl  n-decyl  trimellitate No 

Trioctyl  trimellitate No 

All  other  trimellitic  acid  esters No 

Cyclic  plasticizers,  all  other  Yes 


UTC. 
KLM,  VEL 

KLM.  VEL. 
UTC. 

MON. 

FMC. 

FMC,  MON. 

FMC.  MON,  SCP,  SM. 

EKT. 

DKA,  MON. 

ART 

HAL. 

ART  BAS,  EKT.  NOD.  UTC,  WTH. 

UTC.  (2). 

(^. 

CMB.  EKT,  MRF 

BAS.  SC. 

BAS.  ENJ.  SC. 

ART  BAS.  ENJ.  HCC,  MON,  NOD,  TEK. 

ART  BAS,  ENJ,  TEK. 

UTC.  ('). 

EKT,  MRR  UTC. 

ENJ.  MRF,  SC.  TEK. 

TEK. 

ART.  ENJ.  HCC.  NOD.  SM.  TEK. 

ART  BAS.  SC.  TEK. 

VST 

ART  VST 

ART  BAS.  EKT.  ENJ.  TEK. 

ENJ,  HAL,  HCC,  NOD,  TEK. 

EK. 

BAS.  HCC.  WTH. 

(^. 

HAL. 

BAS.  MON.  NOD,  SC.  TEK.  TNA.  WTC. 

VEL. 

WTC. 

UTC. 

BAS.  ENJ.  TEK. 

ENJ.  WM. 

ART  TEK. 

ENJ,  HAL,  NOD,  TEK. 

FER. 

HAL. 

ART  EKT,  HAL. 

AQU,  ART  BAS.  TEK,  {'),  (*). 

BOE,  NEV  NOD,  TNA,  UTC. 


See  footnotes  at  end  of  table. 


IM 


Synthetic  Organic  Chemicals,  1990 

Table  11-2— Continued 

Plasticizers  for  which  U.S.  production  and/or  sales  werareported,  Identified  by  manufacturer,  1990 


Plasticizers 


Separata 
statistics ' 


Manufacturers'  identHication  codes 
(accordir)g  to  list  in  table  1 1-3) 


Acyclic  plasticizers: 

Adipic  acid  esters:   Yes 

Butylene  glycol  adipate No 

Di(2-(2-butoxyethoxy)ethyl)  adipate No 

Dibutoxyethyl  adipate No 

Di(2-ethylhexyl)  adipate  Yes 

Di-n-hexyl  adipate    No 

Diisobutyl  adipate No 

Diisodecyl  adipate    Yes 

Diisononyl  adipate   No 

Diiso-octyl  adipate   No 

Diisopropyl  adipate No 

Dimethyl  adipate No 

Di-n-octyl  adipate No 

Di-tridecyl  adipate No 

Ethylene  glycol  adipate No 

Neopentyl  glycol  adipate    No 

All  others  adipic  acid  esters Yes 

Azelaic  acid  esters: 

Di(2-ethylhexyl)  azelate  No 

All  other  azelaic  acid  esters No 

Citric  and  acetylcitric  acid  esters: 

Tributyl  acetylcitrate No 

Tributyl  citrate No 

Triethyl  acetylcitrate  No 

Triethyl  citrate No 

All  other  citric  and  acetylcitric  acid  esters    No 

Complex  linear  polyesters  and  polymeric  plasticizers: .  .  Yes 
Adipic  acid  type  complex  linear  polyesters  and 

polymeric  plasticizers  No 

All  other  complex  linear  polyesters  and  polymeric 

plasticizers   No 

Epoxidized  esters:  Yes 

Epoxidized  linseed  oils No 

Epoxidized  pentaerythritol  tetraphthalate No 

Epoxidized  soya  oils No 

2-Ethylhexyl  epoxytallates   No 

All  other  epoxidized  esters     No 

Glyceryl  tripropionate No 

Glutaric  acid  esters: 

Neopentyl  glycol  glutarate   No 

All  other  glutaric  acid  esters     No 

Laurie  acid  esters: 

All  other  lauric  acid  esters    No 

Myristic  acid  esters: 

Isopropyl  myristate No 

All  other  myristic  acid  esters    No 

Octandic  aciud  esters: 

2-Butoxyethyl  oleate No 

Oleic  acid  esters: 

Butyl  oleate Yes 

Decyl  oleate  No 

2-Ethylhexyl  oleate No 

Glyceryl  trioleate  (Triolein) No 

Isobutyl  oleate    No 


HAL. 

HAL,  MON. 

EKT.  HAL. 

ART.  BAS,  CAS.  EKT,  ENJ.  HAL.  MON. 

NOD,  TEK.  WTH. 

EKT.  H^N. 

HAL.  WM.  WTC.  (2). 

HAL,  HCC,  NOD,  QCP. 

ART,  TEK. 

HAL.  HCC.  SM. 

VND.  WTH. 

MRF.  C). 

WTH. 

NOD.  WM. 

HAL. 

HAL. 

CMB,  HAL.  PCI.  SCP,  SM.  WTC. 

HAL.  SCP.  TEK. 
SCP 

UTC. 

MRF. 

0. 

0- 

CCL.  MRF,  (*).  (*). 


CMB.  HAL.  SCP  TEK.  WTC.  WTH. 

EKX.  HPC.  SBC.  SCP,  SM.  TEK,  VND, 
WTC. 

UCC.  WTC. 

UCC. 

FER.  FMB.  TEK.  UCC.  WTC. 

UCC.  WTC. 

UCC. 

EKT. 

HAL. 
HAL. 

HAL. 

WM.WTH. 
WTH. 

HAL. 

CHL.  HAL.  SCP  WTC.  WTH. 

SBC.  VND. 

HAL. 

SCP  WTC. 

SBC. 


See  footnotes  at  end  of  table. 


11-5 


Section  11 

Table  11-2 — Continued 

Plasticizers  for  which  U.S.  production  and/or  sales  worereportad,  Identified  by  manufacturer,  1990 

Plasticizers  Separate  Manufacturers' identification  codas 

statistics '  (according  to  list  in  table  1 1  -3) 

Acyclic  plasticizers: 
Oleic  acid  esters: 

Iso-oclyl  oleate No  HAL. 

Methyl  oleate   No  SCP.  WTC. 

Oleyl  oleate    No  CAS.  SBC. 

Propyl  oleates: 

n-Propyl  oleate  No  SCP. 

All  other  oleic  acid  esters No  HAL.  SCP. 

Palmitic  acid  esters: 

n-Butyl  palmitate No  EKT. 

2-Ethylhexyl  palmitate    No  VND.  WM.  WTH. 

Isobutyl  palmitate No  WTH. 

Isopropyl  palmitate No  CAS.  WM.  WTH. 

Pelargonic  acid  esters: 

Glycol  pelargonate  No  SCP. 

Isodecyl  pelargonate    No  SCP. 

All  other  pelargonic  acid  esters    No  CAS.  SBC.  SM.  WM. 

Phosphoric  acid  esters: 

Tri(2-butoxyethyl)  phosphate  No  FMC.  MON.  RDA. 

Triethyl  phosphate   No  EKT. 

Trioctyl  phosphate   No  FMC.  RDA. 

All  other  phosphoric  acid  esters    No  FMC. 

Ricinoleic  and  acetylricinoleic  acid  esters: 

n-Butyl  acetylricinoleate No  CAS. 

Butyl  ricinoleate   No  CAS. 

Glyceryl  monoricinoleate   No  CAS.  SM. 

Glyceryl  tri(acetylricinoleate)    No  CAS. 

Methyl  ricinoleate No  CAS,  SCP. 

Propylene  glycol  monoricinoleate No  CAS. 

All  other  ricinoleic  and  acetylricinoleic  acid  esters  ...  No  CAS. 

Sebacic  acid  esters: Yes 

Dibutyl  sebacate Yes  HAL.  WM.  (*).  (^). 

Di(2-ethylhexyl)  sebacate No  HAL.  TEK.  {^). 

Diisopropyl  sebacate  No  SBC,  (^. 

Dimethyl  sebacate  No  (^.  (^• 

Propylene  glycol  sebacate No  HAL. 

All  other  sebacic  acid  esters Yes 

Stearic  acid  esters:    Yes 

n-Butyl  stearate   No  CHL.  SCP.  WM.  WTC.  WTH. 

Diethylene  glycol  succinate   No  CMB. 

2-Ethylhexyl  stearate  No  CAS.  HCL.  WM. 

Glyceryl  triacetyl  stearate No  CAS. 

Isobutyl  stearate Yes  SCP.  WM.  WTC.  WTH. 

Isopropyl  stearate No  CAS. 

Myristyl  stearate No  VND. 

Tridecyl  stearate No  WM. 

All  other  stearic  acid  esters    Yes  SBC.  VND.  WM.  WTC. 

Sucrose  acetate  isobutyrate No  EKT. 

Tetraethylene  glycol  di(2-ethylhexanoate)  No  HAL.  UCC.  WM. 

Triethylene  glycol  di(caprylate-caprate) No  HAL.  WM. 

Triethylene  glycol  di{2-ethylbutyrate) No  HAL. 

Triethylene  glycol  di(2-ethylhexanoate) No  EKT,  HAL. 

2,2,4-Trimethyl-1,3-pentanedioldiisobutyrate   No  EKX. 

All  other  acyclic  plasticizers     No  AR2.  HCL.  VND.  WM. 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'y*s.'  Chemicals  for  which 

data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 

11-6 


Synthetic  Organic  Chemicals.  1990 


TabI*  11-3 

Plasticizcrs:  DIrsctory  of  manufacturers,  alphatMtlcal  by  coda,  1990 


Code 


Name  of  company 


Code 


Name  ot  company 


AQU Aqualon  Co. 

ART Aristech  Chemical  Corp.,  Chemical  Div. 

ARZ Arizona  Chemical  Co. 

BAS BASF  Corp. 

BOE Boehme  Filatex.  Inc. 

CAS CasChem.  Inc. 

CCL Catawba-Charlab.  Inc. 

CHL Chemol  Co. 

CMB Cambridge  Industries  Co. 

DKA Mobay  Synthetics  Corporation 

EK Eastman  Kodak  Co.: 

EKT Tennessee  Eastman  Co.  Oiv. 

EKX Texas  Eastman  Co.  Div. 

ENJ  Exxon  Chemical  Americas 

PER Ferro  Corp.: 

Bedford  Chemical  Div. 

Grant  Chemical  Div. 

FMB FMC  Corp..  Chemical  Products  Group 

FMC FMC  Corp..  Nitro  Div. 

HAL C.  P.  Hall  Co. 

HCC Hatco  Chemical  Corp. 

HCL Hoechst  Celanese  Corp.,  Sou-Tex 

Works 


HPC    Hercules.  Inc. 

KLM Kalama  Chemcal,  Inc. 

MON Monsanto  Co. 

MRF   Mortlex  Chemical  Co..  Inc. 

NEV Neville  Chemcal  Co. 

NOD   Huls  America.  Inc. 

PCI   Piedmont  Chemcal  Industries.  Inc. 

RDA   Rhone-Poulenc.  Inc 

SBC Scher  Chemicals.  Inc. 

SC Sterling  Chemical,  Inc. 

SCP Henkel  Corp. 

SM Mobil  Oil  Corp.  Chemcal  Products  Div. 

TEK Teknor  Apex  Co. 

TNA Ethyl  Corp. 

UCC   Union  Caibide  Corp.,  Industrial 

Chemcals  Div. 

UTC Unitex  Chemical  Corp. 

VEL Velsiool  Chemical  Corp. 

VND    Van  Dyk,  Div.  of  Mallinckrodt,  Inc. 

VST Vista  Chemical  Co. 

WM Inolex  Chemcal  Co. 

WTC Witco  Chemical  Corp. 

WTH  Union  Camp  Corp.,  Chemcal  Division 


Note.— Complete  names,  telephone  number,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


11-7 


Synthetic  Organic  Chemicals,  1990 


Section  12 
Surface-Active  Agents 

The  surface-active  agents  included  in  this  report 
are  organic  chemicals  that  reduce  the  surface  tension  of 
water  or  other  solvents  and  are  used  chiefly  as 
detergents,  dispersing  agents,  emulsifiers,  foaming 
agents,  or  wetting  agents  in  either  aqueous  or 
nonaqueous  systems.  Waxes  and  products  used  chiefly 
as  plasticizers  are  excluded.  Surface-active  agents  are 
produced  from  natural  fats  and  oils,  from 
silvichemicals  such  as  lignin,  rosin,  and  tall  oil,  and 
from  chemical  intermediates  derived  from  coal  tar  and 
petroleum.  A  major  part  of  the  output  of  the  bulk 
chemicals  shown  in  this  report  is  consumed  in  the  form 
of  packaged  soaps  and  detergents  for  household  and 
industrial  use.  The  remainder  is  used  in  the  processing 
of  textiles  and  leather,  in  ore  flotation  and  oil-drilling 
operations,  and  in  die  manufacture  of  agricultural 
sprays,  cosmetics,  elastomers,  foods,  lubricants,  paint, 
pharmaceuticals,  and  many  other  products. 

The  statistics  for  production  and  sales  of 
surface-active  agents  (table  12-1)  are  grouped  by  ionic 
class  and  by  chemical  class  and  subclass.  All 
quantities  are  reported  in  terms  of  100-percent  organic 
surface-active  ingredients  and  thus  exclude  all 
inorganic  salts,  water,  and  other  diluents.  Sales 
statistics  reflect  sales  of  bulk  surface-active  agents 
only:  sales  of  fomulated  products  are  excluded.  Data 
for  the  production  of  surface-active  agents  during 
1986-90  are  shown  in  figure  12-1. 

Total  U.S.  production  of  surface-active  agents  in 
1990  amounted  to  3,795  milUon  kilograms,  or  23 
percent  more  than  the  3,085  million  kilograms  reponed 
for  1989.  Sales  of  bulk  surface-active  agents  in  1990 
amounted  to  1.930  million  kilograms,  valued  at  $2,193 
million,  compared  with  sales  in  1989  of  1,724  million 
kilograms,  valued  at  $2,086  million.     In  terms  of 


quantity,  sales  in  1990  were  12  percent  more  than  in 
1989. 

Production  of  anionic  surface-active  agents  in  1990 
amounted  to  2,586  million  kilograms,  or  68  percent  of 
the  total  surfactant  output  reponed  for  1990.  Sales  of 
anionics  in  1990  amounted  to  982  million  kilograms, 
valued  at  S704  million. 

Production  of  cationic  surface-active  agents  in 
1990  amounted  to  343  million  kilograms,  17  percent 
more  than  the  293  million  kilograms  reported  in  1989. 
Production  of  nonionic  surface-active  agents  amounted 
to  845  million  kilograms  in  1990, 14  percent  more  than 
the  743  million  kilograms  reported  in  1989.  Sales  of 
cationic  surface-active  agents  in  1990  increased  by  13 
percent  in  terms  of  quantity,  and  by  6  percent  in  terms 
of  value  when  compared  with  sales  as  reported  in  1989. 
Sales  of  nonionics  in  1990  increased  by  12  percent  in 
terms  of  quantity,  but  decreased  by  less  than  1  percent 
in  terms  of  value  when  compared  with  sales  as  reported 
in  1989. 

The  difference  between  production  and  sales 
reflects  inventory  changes  and  captive  consumption  of 
surface-active  agents  by  synthetic  rubber  producers, 
and  by  manufacturers  of  cosmetics,  packaged 
detergents,  bar  soaps,  and  other  formulated  consumer 
products.  In  some  instances  the  difference  may  also 
reflect  quantities  of  surface-active  agents  used  as 
chemical  intermediates,  e.g.,  nonionic  alcohol  and 
alkylphenol  ethoxylates.  which  may  be  converted  to 
anionic  surface-active  agents  by  phosphation  or 
sulfation. 

Table  12-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 
12-3. 

Eric  Land 
202-205-3349 


12-1 


Section  12 

Figure  12-1 

Surface-active  agents:  U.S.  production,  1986-90 

Billions 

of  kilograms 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


12-2 


Table  12-1 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals,  1990 


Surface-active  agents 


Production' 


Sales' 


Quantity 


Value 


Average 

Unit 

value^ 


481,169 
1 .449.091 


12,262 


1,885 
10.377 


982.220 


Per 
kilogram 

2.192,848      $1.14 


1.000 
dollars 


586,917        1.22 
1,605,931         1.11 


30,104 


5.053 
25,051 


703.913 


2.46 


2.68 

{*) 
2.41 


.72 
1.02 

1.13 


1.000  1.000 

kilograms  kitograms 

Grand  total 3,794,654             1,930,260 

Benzenoid*    710,700 

Nonbenzenoid 3,083,954 

Amphoteric 

Total  20.621 

(Carboxymethyl)[3-(coconut  oil 

amido)propyl]  dimethylammonium 

hydroxide,  inner  salt 1.981 

(Mixed  alky!)  sulfobetaine   249 

All  other  amphoteric  surface  active  agents  18,391 

Anionic 

Total  2.585.985 

Carboxylic  acids  (and  salts  thereof),  total  1 .143,058                103.730               105.495 

Amine  salts  of  fatty,  rosin,  and  tall  oil  adds 5.737                    4.887                  5,544 

Cartwxylic  acids  having  amide,  ester,  or 

ether  linltages 6,513 

Coconut  oil  acids,  potassium  salt 

Coconut  oil  acids,  sodium  salt 274,773 

Oleic  acid,  sodium  salt 46 

Rosin  acids,  potassium  salt 36,568 

Stearic  add.  sodium  salt   

Tall  oil  acids,  potassium  salt 6,101 

Tallow  acids,  sodium  salt 459,827 

All  other  carboxylic  acids  (and  salts  thereof) 353,493 

Phosphoric  and  polyphosphoric  add  esters 

(and  salts  thereof),  total  32.688                  27.325                50.106        1 .83 

Alcohols  and  phenols,  alkoxylated  and 

phosphated,  total    25.644 

Decyl  akx}hol,  ethoxylated  and  phosphated 134 

Dinonylphenol,  ethoxylated  and  phosphated 630 

2-Ethylhexanol,  ethoxylated  and  phosphated 928 

Mixed  linear  alcohols,  ethoxylated  and 

phosphated 1 ,372 

Nonylphenol,  ethoxylated  and  phosphated 3,968 

9-Octadecenyl  alcohaol,  ethoxylated  and 

phosphated 1,323 

Phenol,  ethoxylated  and  phosphated 1,312 

All  other  alcohols  and  phenols,  alkoxylated  and 

phosphated 15,957                  14,255                 17,594        1.23 


6,247 

14.375 

2.30 

225 

3.637 

16.13 

4,475 

4,552 

1.02 

45 

81 

1.82 

38,172 

19.450 

.51 

25 

46 

1.84 

885 

1065 

1.20 

13,033 

7.560 

.58 

35,736 

49.185 

1.38 

22.493 
236 
417 
7S7 

36.635 
595 
839 
795 

1.63 
2.52 

2.01 
1.01 

1,711 
3.300 

4.128 
7,667 

2.41 
2.32 

617 
1.170 

2,238 
2,779 

3.62 
2.38 

See  footnotes  at  end  of  table. 


12-3 


Section  12 

Table  12-1 — Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Surface-active  agents 


Production' 


Sales^ 


Quantity 


Value 


Average 

Unit 

value^ 


1.000 
kilograms 
Anionic — Continued 

Phosphoric  and  polyphosphoric  acid  esters 
(and  salts  thereof) — Continued 

Decyl  and  octyl  phosphate 754 

2-Ethylhexyl  phosphate   386 

Mixed  alky!  phosphate  1 ,181 

All  other  phosphoric  and  polyphosphoric 

acid  esters  (and  salts  thereof)   4.723 

Sulfonic  acids  (and  salts  thereof),  total  931 .522 

Alkylbenzenesulfonates.  total 300.161 

Dodecylbenzenesutfonicacid 150.901 

Dodecylbenzenesulfonic  acid,  ammonium  salt 67 

Dodecylbenzenesulfonic  acid,  calcium  salt    3.202 

Dodecylbenzenesulfonic  acid,  isopropylamine 

salt   2.230 

Dodecyltienzenesulfonic  acid,  potassium  salt   21 

Docecyibenzenesuitonic  acid,  sodium  salt 101 ,881 

Dodecylbenzenesulfonic  acid,  triethanolamine 

salt 3,721 

All  other  alkylbenzenesulfonates 38,138 

Benzene-,  cumene-,  toluene-,  and 

xylenesutfonates.  total    71.634 

Xylenesulfonic  acid,  sodium  salt 33.406 

All  other  benzene-,  cumene-.  toluene-,  and 

xylenes  sulfonates    38,228 

Ligninsulfonates  and  naphthalenesulfonates, 

total 468,425 

Ligninsulfonic  acid,  ammonium  salt  2.276 

Ligninsulfonic  acid,  calcium  salt 255.694 

Ligninsulfonic  acid,  sodium  salt   125,153 

Diisopropylnaphthalenesulfonic,  sodium  salt 1,119 

All  other  ligninsulfonates  and  naphthalene- 
sulfonates    84.183 

Mixed  linear  olefin  sulfonate 13.855 

Sulfosuccinamic  acid  derivatives 1 .579 

Sulfonic  acids  having  ester  or  ether  linkages. 

total ' 69,489 

Sulfosuccinic  acid  esters,  total 11,566 

Sulfosucpinic  acid.  bis(2-ethylhexyl)ester, 

sodium  salt   7.720 

All  other  sulfosuccinic  acid  esters 3.846 

All  other  sulfonic  acids  having  ester  or  ether 

linkages 57.923 

All  other  sulfonic  acids  (and  salts  thereof) 6,379 


1.000 
kilograms 


1.000 
dollars 


Per 
kikygram 


754 
298 
929 

1,378 

564 

3.163 

$1.83 
1.89 
3.40 

2.851 

8,366 

2.93 

696.400 

348.810 

.50 

141.335 
102.305 

143.345 
80,284 

1.01 
.78 

1.837 

4.485 

2.44 

1.733 

3.802 

2.19 

28,769 

44.118 

1.53 

2,721 
3,970 

4.890 
5,766 

1.80 
1.45 

58.809 
29.203 

44,014 
21.834 

.75 
.75 

29,606 

22.180 

.75 

465,728 

2,257 

255,871 

122.668 

1,479 

93.393 

599 

28.319 

16.100 

2.835 

.20 
.27 
.11 
.13 
1.92 

83.453 

13.494 

2.112 

45.540 

22.025 

2.626 

.55 
1.63 
1.24 

10.953 
8,583 

33,900 
23,962 

3.09 
2.79 

5,839 

2,744 

17.514 
6,448 

3.00 
2.35 

2,370 
3.969 

9,938 
9,507 

4.19 
2.40 

See  footnotes  at  end  of  table. 


12-4 


Table  12-1 — Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals.  1990 


Surface-active  agents 


Production ' 


Sales^ 


Quantity 


Value 


Average 

Unit 

value^ 


1.000 
kilograms 
Anionic — Continued 

SuKuric  acid  esters  (and  salts  thereof),  total*    478,717 

Adds,  amides,  and  esters,  sulfated,  total 4,609 

Butyl  oleate,  sulfated,  sodium  salt  344 

All  other  acids,  amides,  and  esters,  sulfated   4,265 

Alcohols,  sulfated,  total    169,166 

Dodecyl  sulfate,  ammonium  salt 17,132 

Dodecyl  sulfate,  sodium  salt 13,665 

Dodecyl  sulfate,  triethanolamine  salt  4,081 

2-Ethylhexyl  sulfate  sodium  salt 812 

All  other  alcohols,  sulfated  133,476 

Ethers,  sulfated,  (included  all  other  anionic 

surface-active  agents)   291,736 

Natural  fats  and  oils,  sulfated,  total  13,206 

Castor  oil,  sulfated,  sodium  salt 2,429 

Tall  oil,  sulfated,  sodium  salt 465 

Tallow,  sulfated,  sodium  salt 299 

All  other  natural  fats  and  oils,  sulfated 10.013 

Cation  Ic 

Total   343,469 

Amine  oxides  and  oxygen-containing  amines  (except 

those  having  amide  linkages),  total  85,723 

Acyclic,  total 80.405 

N.N-Bis(2-hydroxyethyl)octadecylamine. 

ethoxylated 683 

N.N-Bis(2-hydroxyethyl)(tallow  alkyl)amine, 

ethoxylated 

(Coconut  oil  alkyl)amine,  ethoxylated 1 .595 

(l-lydrogenated  tallow  alkyl)amine,  ethoxylated    ....  546 

(Mxed  alkyl)amine.  ethoxylated    687 

(9-Octadecenyl)amine,  ethoxylated  •     1,364 

Octadecylamine,  ethoxylated 707 

(Soybean  oil  alkyl)amine,  ethoxylated   501 

(Tallow  alkyljamine,  ethoxylated 3,784 

N-(Tallow  alkyl)  trimethylene  diamine, 

ethoxylated 1 .274 

All  other  acyclic  amine  oxides  and  oxygen 

containing  amines  (except  those  having 

amide  linkages) 69,264 

Cyclic  (including  imidazoline  and  oxazoline 

derivatives),  total 5,318 

1-(2-Hydroxyethyl)-2-nonyl-2-imida20line    479 

1  -(2-Hydroxyethyl)-2-nor(tall  oil  alkyl)-2- 

imidazoline  728 

All  other  cyclic  amine  oxkJes  and  oxygen 

containing  amines  (except  those  having 

amide  linkages) 4,111 


1.000 
l<ilograms 

154.765 


1.000 
dollars 


Per 
kilogram 


4.039 

343 

3.696 

44.653 

7.506 

12,432 

2,104 

815 

21,796 

94,575 

11,498 

2,095 

425 

210 

8,768 


191,503 


772 


13,899 


2,849 
471 


303 


2,075 


199,502      $1.29 


7,388 
483 

6,905 
75,873 
15,969 
33.977 

5.334 

2.331 
18.262 

104.503 

11.738 

3,546 

501 

191 

7,500 


8,312 
1,529 


1,555 


1.83 
1.41 
1.87 
1.70 
2.13 
2.73 
2.54 
2.84 
.84 

1.10 
1.02 
1.69 
1.18 
.91 
.86 


396,663        2.07 


>7,214 

57.365 

2.11 

>4,365 

49.053 

2.01 

1,546 

3.016 

1.95 

1,329 

2,033 

1.53 

511 

615 

1.20 

480 

1,672 

3.48 

1,541 

2,440 

1.58 

558 

1,509 

2.70 

237 

554 

2.33 

3.492 

4,643 

1.33 

1,054         1.37 


31.517        2.27 


2.92 
3.25 


5.13 


5.228        2.52 


See  footnotes  at  end  of  table. 


12-5 


Section  12 

Table  12-1— Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Surface-active  agents 


Production ' 


Sales' 


Quantity 


Value 


Average 

Unit 

value' 


1,000 
kilograms 
Cationic — Continued 

Amines  and  amine  oxides  having  amide  linkages 24,914 

Amines,  not  containing  oxygen  (and  salts 

thereof),  total    112.672 

Amines  salts 4,471 

Amine  salts,  diamines  and  polyamines   13,954 

Monoamines,  total  94,247 

(Coconut  oil  alkyl)amine (*) 

N.N-Dimethylhexadecylamine   2.792 

N.N-Dimethyloctadecylamine 3.245 

(Hydrogenated  tallow  alkyl)amine   3,907 

9-Octadecenylamine    3.288 

Octadecylamine 1 ,256 

(Tallow  alkyl)amine (') 

All  other  monoamines 79,759 

Quaternary  ammonium  salts,  containing 

oxygen,  total 24,999 

Quaternary  ammonium  salts,  not  containing 

oxygen,  total 88,658 

Acyclk:.  total 67.161 

Bis(coconut  oil  alkyt)dimethylammoniuffl  chloride  1,541 
Bis(hydrogenated  tallow  alkyl)dimethylaminonium 

chksride 38.317 

N-(coconut  oil  alkyl)  aminobutyric  acid,  sodium  salt  294 

Hexadecyltrimethylammonium  chtoride   638 

Trimethyl(tallow  alkyl)ammonium  chloride  1 .368 

All  other  acyclic  quaternary  ammonium  salts,  not 

containing  oxygen 25.003 

Benzenoid,  total*    21 ,497 

Benzyl(coconut  oil  alkyl)dimethylammonium 

chloride  838 

Benzyldimethyl(mixed  alkyl)ammonium  chloride  9.033 

Benzyldimethyl  octadecyl  ammonium  chloride  .  566 
Benzyl(hydrogenated  talksw  alkyl) 

dimethylammonium  chloride  1.665 

Benzyltrimethyl  ammonium  chlorida 1,553 

All  other  benzenoid  quaternary  ammonium 

salts,  not  containing  oxygen    7.842 

All  other  cationic  surface-active  agents   6,503 


1.000 
kilograms 

19.346 
51.837 


1.000 
dollars 


Per 
kilogram 


16.905 


74.166 


29.832      $1.54 


82.353         1.59 


4.299 

4.548 

1.06 

10.000 

16.331 

1.63 

37.538 

61,474 

1.64 

497 

1,306 

2.63 

935 

1,655 

1.77 

2.382 

6,390 

2.68 

1.599 

2,287 

1.43 

2.093 

4,030 

1.93 

733 

1,846 

2.52 

5,809 

8,735 

1.50 

23,490 

35,225 

1.50 

39,662        2.35 


165,791         2.24 


61,782 
1,487 

129,803 
3,798 

2.10 
2.55 

35.552 

265 

593 

1.308 

64,580 
1.024 
2.820 
3.757 

1.82 
3.86 
4.76 
2.87 

22.577 
12.384 

53,824 
35,988 

2.38 
2.91 

812 

4.489 

398 

1,753 

15.083 

1.508 

2.16 
3.36 
3.79 

879 
1.250 

1.898 
2.558 

2.16 
2.05 

4.556 
2,035 

13.188 
21,660 

2.89 
10.64 

See  footnotes  at  end  of  table. 


12-6 


Table  12-1— Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals,  1990 


Surface-active  agents 


Sales^ 

Average 
Unit 

Production ' 

Ouar)tity 

Value 

value^ 

1.000 

1,000 

1.000 

Per 

kilograms 

kilograms 

dollars 

kik>gram 

844.579 

744.275 

1.062,168 

$1.43 

42.304 

49,103 

78.495 

1.60 

7.729 

7.075 

13,735 

1.94 

1.304 

1.181 

2.080 

1.76 

14 

(*) 

(*) 

(*) 

103 

100 

427 

4.26 

497 

(*) 

(') 

(*) 

5.811 

5.794 

11.228 

1.94 

34.575 

42.028 

64.760 

1.54 

7.943 

6.700 

11.969 

1.79 

647 

630 

1.580 

2.51 

799 

792 

1,865 

2.36 

39 

43 

126 

2.91 

96 

85 

124 

1.45 

Nonlonic 

Total  

Cartxjxyiic  acid  amides,  total 

Diethanoiamine  condensates,  amine/acid 

ratio  -  2/1 ,  total 

Coconut  oil  acids   

Laurie  and  myristic  acids    

Oleic  acid  

Tall  oil  acids   

All  other  diethanoiamine  condensates,  amine/acid 

ratio  -  2/1    

Diethanoiamine  condensates  (other  amine/acid 
ratios),  and  other  carboxylic  acid  amides,  total  . 
Coconut  oil  acids,  amine/acid  ratio  •  1/1    ..... 

Laurie  acid,  amine/acid  ratio  «  1/1   

Laurie  and  myristic  acids,  amine/acid  ratio  ■  1/1 

Oleic  acid,  amine/acid  ratio  «  1/1  

Stearic  acid,  amine/acid  ratio  -  1/1    

All  other  diethanoiamine  condensates 
(other  amine/acid  ratios),  and  other 
cartxjxylic  acid  amides  25.051 

Cartxjxylic  acid  esters,  total 166.424 

Anhydrosorbitol  esters,  total 18.986 

Anhydrosorbitol  monolaurate 3.744 

Anhydrosorbitol  mono-oleate 4.442 

Anhydrosorbitol  monostearale 8,782 

All  other  anhydrosorbitol  esters   2.018 

Diethylene  glycol  esters,  total    2,857 

Diethylene  glycol  monolaurate 1 05 

All  other  diethylene  glycol  esters   2.752 

Ethoxylated  anhydrosorbitol  esters,  total 14,292 

Ethoxylated  anhydrosorbitol  monolaurate    3.315 

Ethoxylated  anhydrosorbitol  mono-oleate    3.852 

Ethoxylated  anhydrosorbitol  monostearale   5.117 

Ethoxylated  anhydrosorbitol  tristearate   273 

All  other  ethoxylated  anhydrosorbitol  esters 1 .735 

Ethylene  glycol  distearate   1 .483 

Ethylene  glycol  monostearate  2,021 

Glycerol  esters,  total    47,883 

Glycerol  dilaurale 233 

Glycerol  mono-oleate , 4.602 

Glycerol  monostearate 3.828 

All  other  glycerol  esters    39.020 

Natural  fats  and  oils,  ethoxylated.  total    26.300 

Castor  oil,  ethoxylated   10,552 

Hydrogenated  castor  oil,  ethoxylated 1 ,895 

Lanolin,  ethoxylated   215 

All  other  natural  (ats  and  oils,  ethoxylated   13,638 


33.778 
129.375 


14.303 
2,399 
2.493 
7.919 
1.492 
1.653 
105 
1,548 

13,117 
2.991 
3,554 
4,772 
291 
1,509 
1.434 
1.907 

37,518 

176 

4,926 

3.869 

28.547 

18.239 

9,025 

1,671 

201 

7.342 


49,096         1.45 


238.044 


1.84 


24.106 

1.69 

4.594 

1.92 

4.676 

1.88 

12.170 

1.54 

2.666 

1.79 

3.701 

2.24 

172 

1.64 

3,529 

2.28 

29.875 

2.28 

7.332 

2.45 

7,486 

2.18 

10,803 

2.26 

659 

2.26 

3.595 

2.38 

2,475 

1.73 

3.554 

1.86 

71.108 

1.90 

489 

2.79 

8.466 

1.72 

7,252 

1.87 

54.901 

1.92 

28.530 

1.56 

12,366 

1.37 

2,233 

1.34 

529 

2.64 

13,402 

1.83 

See  footnotes  at  end  of  table. 


12-7 


Section  12 

Table  12-1— Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Surface-active  agents 


Production ' 


Sales^ 


Quantity 


Value 


Average 

Unit 

value^ 


1,000 
kilograms 
Nonlonlc — Continued 

Cartjoxyiic  acid  esters — Continued 

Poiyethyiene  glycoi  esters,  totai 27,483 

Poiyethyiene  giycoi  diester  of  tall  oii  acids 3,003 

Polyethylene  glycol  dilaurate  724 

Polyethylene  glycol  dioleate 1 ,729 

Polyethylene  glycol  distearate   920 

Polyethylene  glycol  monolaurate  3.456 

Polyethylene  glycol  mono-oleate  1 ,865 

Polyethylene  glycol  monopalmitate   792 

Polyethylene  glycol  monostearate  3,158 

Polyethylene  glycol  sesquiester  of  tall  oil  acids  ....  865 

All  other  polyethylene  glycol  esters   10,971 

Polyglycerol  mono-oleate 315 

Polyglycerol  monostearate 

1 ,2-Propanediol  monostearate 775 

All  other  cart)oxylic  acid  esters 24,029 

Ethers,  total 627,651 

Benzenoid  ethers,  total* 242,848 

Dinonylphenol,  ethoxylated    2,104 

Dodecylphenol,  ethoxylated 2,602 

Iso-octylphenol,  ethoxylated 25,047 

(Mixed  alkyl)phenol-formaldehyde,  alkoxylated  ....  8,562 

Nonylphenol,  ethoxylated 181,204 

Nonylphenol,  ethoxylated  and  propoxylated 1,667 

Nonylphenol-formaldehyde,  alkoxylated 3,561 

Phenol,  ethoxylated   1 .494 

All  other  benzenoid  ethers  16.607 

Nonbenzenoid  ethers,  total    339.396 

Chemk:aliy-defined  linear  alcohols,  ethoxylated. 

total 12.462 

Decyl  alcohol,  ethoxylated   4.333 

Dodecyl  alcohol,  ethoxylated    1 ,767 

Hexadecyl  alcohol,  ethoxylated    761 

9-Octadecenyl  alcohol,  ethoxylated   1.952 

Oleyl  alcohol,  ethoxylated 1.963 

All  other  chemically-defined  linear  alcohols, 

ethoxylated  1 .686 

Mixed  linear  alcohols,  alkoxylated,  total 326,934 

Mixed  linear  alcohols,  ethoxylated   301,987 

Mixed  linear  alcohols,  ethoxylated  and 

propoxylated  10,690 

All  other  mixed  linear  alcohols,  alkoxylated    14,257 


1.000 
kilograms 


21.503 

832 

643 

610 

821 

3,504 

1,752 

(') 

2,928 

873 

9,540 

265 

26 

199 

19,211 

562.299 


203,483 

1,508 

2,307 

17,215 

7,706 

163,671 
1,142 

{') 

619 

9,315 

319,891 

10,196 

{') 

1.245 

715 

1.212 

1.905 

5.119 
309,695 
289,765 

10,570 
9.360 


1.000 
dollars 


34.975 

844 

946 

1.153 

2.726 

5.309 

2.312 

(') 

5,353 

1,652 

14,680 

829 

102 

812 

37,977 


288,389 

3,251 

4,664 

41,599 

13,455 

191.929 

2.906 

{') 

1.610 

28.975 

368.302 

24.242 

{') 
2,986 
1,945 
2,311 
5,308 

11,692 
344,060 
312,728 

17,329 
14,003 


Per 
kilogram 


$1.63 
1.01 
1.47 
1.89 
3.32 
1.51 
1.32 
(*) 
1.83 
1.89 
1.54 
3.12 
3.82 
4.09 
1.98 


733.542         1 .30 


1.42 
2.16 
2.02 
2.42 
1.75 
1.17 
2.54 

(') 
2.60 
3.11 
1.15 

2.38 

(') 
2.40 
2.72 
1.91 
2.74 

2.28 

1.11 
1.08 

1.64 
1.50 


See  footnotes  at  end  of  table. 


12-8 


Table  12-1 — Continued 

Surface-active  agents:  U.S.  production  and  sales,  1990 


Synthetic  Organic  Chemicals,  1990 


Surface-active  agents 


Sales' 


Average 


Production' 

Quantity 

Value 

value^ 

1.000 

1.000 

1.000 

Per 

kilograms 

kilograms 

dollars 

kitogram 

45.407 

38.925 

76.851 

1.97 

927 

(*) 

(*) 

(*) 

5.255 

(*) 

(') 

(') 

5.478 

3.364 

5.849 

1.74 

938 

938 

2.263 

2.41 

32.809 

34.623 

68.739 

1.99 

Nonionic — Continued 

Ethers — Continued 

Other  ethers  and  thioethers.  total 

Mixed  alcohols,  ethoxylated 

Poly(mixed  ethylene,  propylene)  glycol 

Tridecyl  alcohol,  ethoxylated    

Trimethylol  propane,  alkoxylated 

All  other  ether  ethers  and  thioethers    . . 

All  other  nonionic  surlace-active  agents   .  .  . 


6,200 


3,498 


12,087 


3.46 


'  All  quantities  are  given  In  terms  of  100  percent  organic  surface-active  ingredient. 

^  Sales  include  products  sold  as  bulk  surface-active  agents  only. 

^  Calculated  from  unrounded  figures. 

*  The  term  "benzenoid"  used  in  this  report,  describes  any  surface-active  agent,  except  lignin  derivatives,  whose 
molecular  structure  includes  1  or  more  6-membered  cartx>cyclic  or  heterocylic  rings  with  conjugated  double  bonds 
(e.g.,  the  benzene  ring  or  the  pyridine  ring). 

^  Reported  data  were  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

^  Includes  all  other  anionic  surface-active  agents. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


12-9 


Section  12 

Table  12-2 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 

Separate       Manufacturers'  identification  codes 
Surface-active  agents  statistics '      (according  to  list  in  table  12-3) 

Amphoteric 

1 , 1  -Bis(carboxy  methy  l)-2-undecy  l-2-innidazolinium 

hydroxide,  disodium  sail No  PCI. 

Caprylamphopropionate No  MOA. 

1  -Cart)oxyethyl-1  -(2-hydroxyGthyl)-2-heptyl-2- 

imidazolinlum  hydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

1  -Cartx)xy8thyl-1  -(2-hydroxyethyl)-2-nonyl-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

N-[2-(Carboxymethylamino)ethyl)-N-(2-hydroxyethyl)- 

coconut  oil  amide,  sodium  salt No  WM. 

Carboxymethyl-3-cocoamidopropyl  dimethyl  ammonium 

chloride,  sodium  salt No  ENJ. 

(Cartx)xymethyl)[3-(coconut  oil  amido)propyl)- 

dimethylammonium  hydroxide,  inner  salt No  BRD,  PPG.  RDA.  SBC,  SCP.  SHX.  WTC, 

(Cartx>xymethyl)dodecyldimethylammonium  hydroxide, 

inner  salt No  RDA. 

1-Caftx)xymethyl-2-heptadecyl-1-{2-hydroxyethyl)-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

1  -Cart)oxymethyl-1  •(2-hydroxyethyl)-2-heptyl-2- 

Imidazoliniumhydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

1  -Cartx>xymethyl-1  -{2-hydroxyethyl)-2-nony  1-2- 

imidazolinium  hydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

1-Cartx)xymGthyl-1-(2-hydroxyethyl)-2-undecyl-2- 

imideizolinium  hydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

1-Cart)oxymethyl-1-(2-hydroxyethyl)-2-undecyl-2- 

imidazoliniumhydroxide,  sodium  derivative,  sodium 

salt  No  RDA. 

(I-Carboxytridecyl)trimethylammonium  hydroxide,  inner 

salt  No  SQA. 

Cocoamidoamphoglycinate No  MOA. 

Cocoamidopropyl  betaine    No  MOA. 

N-Cocoamido-propyl-N,N-dimethylamine  oxide No  MOA. 

3-^-(Cocoamidopropyl)dimethylammonio]-2- 

nydroxypropane  suflonate   No  RDA. 

3-Cocoamidopropyl-2-hydroxy-3-sulfopropyldimethyl 

ammonium  hydroxide,  inner  salt No  SHX. 

Cocoamphocarboxyglycinate No  MOA. 

Cocoamphocarboxypropionate   No  MOA. 

Cocoamphopropionate No  MOA. 

3-[(Coconut  oil  aikyl)amidoethylene-(2-hydroxyethyl)- 

amino]propionlc  acid    No  RDA. 

N,N-di(hydroxyethyl)-n-cartx)xymethyl  tallow  ammonium 

quat,inner  salt No  SHX. 

N,N-Dihydroxyethyl  tallow  glycinate No  MOA. 

N-Dodecyl-3-iminodipropionic  acid    No  MOA. 

N-Dodecyl-3-iminodipropionic  acid,  disodium  salt No  MOA,  RDA.  SCP. 

N-Dodecyl-3-imino-dipropionic  acid,  monosodium  salt   . .    No  RDA. 

1  -Hydroxyethyl-1  -(2-hydroxy-3-sodiumsutfonatopropyl)- 

2-nor-coconut  oil  tatty  acids-2-imida2olinium 

hydroxide  No  RDA. 

1  -Hydroxyethyl-1  -(2-hydroxy-3-sodiumsuHonatopropyl-2- 

oleyl-2-imlda2olinium  hydroxide No  RDA. 

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine, 

sodium  salt No  MOA. 

Isodecyloxypropyliminopropionic  acid,  monosodium  salt .     No  ENJ. 

See  footnotes  at  end  ol  table. 
12-10 


Synthetic  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate       Manufacturers '  identification  codes 
statistics '      (according  to  list  in  table  12-3) 


Amphoteric — Continued 

Isonanylamidocaproic  acid,  triethanolamine  salt No 

Laurylamidopropyl  betaine No 

Laurylamphoglycinate   No 

(Mixed  alkyl)sunobetaine Yes 

Oleamidopropyl  betaine No 

Oleic  acid-ethylenediamine  condensate,  propoxylated 

and  sulfated,  sodium  salt  No 

Oleyl  betaine   No 

1 -(Sodium  cartx)xyethyleno)-1 -(sodium 
cart)oxymethyleneoxyethylene)-2-nor-(tall  oil  fatty 

acids)-2-imida2olinium  hydroxide No 

1-(Sodium  cartxjxy methyl)- 1 -(sodium 
cart)Oxymethyleneoxyethylene)-2-nor-(coconutoil 

fatty  acids)-2-imida20linium  lauryl  sulfate No 

N-(Tailow  alkyl)-3-iminodipropionic  acid,  disodium 

salt  No 

Tridecyloxypoly(ethyleneoxy)propionic  acid,  potassium 

salt  No 

All  other  acyclic  amphoteric  surface-active  agents    No 

All  other  cyclic  amphoteric  surface-active  agents    No 

Anionic 
Carboxyllc  acids  (and  salts  thereof): 
Amine  salts  of  fatty,  rosin,  and  tall  oil  acids: 

Coconut  oil  acids,  diethanolamine  salt  No 

Coconut  oil  acids,  ethanolamine  salt    No 

Coconut  oil  acids,  triethanolamine  salt No 

Isostearic  acid,  mixed  isopropanolamines  salt No 

Isostearic  acid,  triethanolamine  salt  No 

Oleic  acid,  diethanolamine  salt No 

Oleic  acid,  mixed  isopropanolamine  salt No 

Oleic  acid,  morpholine  salt  No 

Oleic  acid,  triethanolamine  salt No 

Rosin  acids,  triethanolamine  salt   No 

Stearic  acid,  triethanolamine  salt  No 

Tall  oil  acids,  diethanolamine  salt  (Condensate)  ....    No 

Tall  oil  acids,  triethanolamine  salt No 

(Tall  oil.fatty  adds),  triethanolamine  salt No 

Tallow  acids,  triethanolamine  salt No 

All  other  amine  salts  of  fatty,  rosin,  and 

tall  oil  acids  No 

Carboxylic  acids  having  amide,  ester,  or  ether 
linkages: 

Butoxyethylene  oxyacetic  acid,  sodium  salt No 

5(or  6)-Cartx3xy-4-nexyl-2-cyck)hexene-1  -octanoic 

acid,  reaction  products  with  castor  oil No 

N-(Coconut  oil  acyl)sarcosine.  sodium  salt No 

N.N-Dimethyl  capramide No 

Dodecyk]xypoly(ethyleneoxy)acetic  acid,  sodium 

salt No 

N-Lauroylsarcosine,  sodium  salt No 

Maleic  acid,  monoalkyi  ester No 

Mixed(secondary  linear  alcohol)polyethylene 

propionic  acid,  sodium  salt   No 

Naphthenic  acid,  ethoxylated  No 

Nonylphenol  poly(ethyleneoxy)acetic  acid,  sodium 

salt No 

Poly(oxy-1 ,2-ethanediyl),  w-(2<artx>xyethoxy)-w- 
hydroxy-a,  a'-(iminodi-2,  1-ethanediyl)  bis-.N- 

tallow  alkyl  derivs.,  potassium  salt    No 

Poly(oxy-1 ,2  ethanediyl)acart)oxy-methyl, 
(O-(tri-decyk)xy),  potassium  salt No 


TNI. 

MOA. 

MOA. 

BRD.  MOA,  SBC,  (^). 

PDA. 

MOA. 
PDA. 


PDA. 

PDA. 

MOA.  PDA,  SCP. 

MRV. 


BPD,  CGY  DUP.  ENJ.  MOA.  PDA.  S.  SCP. 
BRD.  SBC.  UTC. 


PDA,  SHX. 

SBR 

SCP. 

PCI. 
PDA. 
UTC.  a 

CPC 

PCI.  SBP.  (*). 

PDA. 

PNX. 

WPG. 

CPC.  ENJ.  SBP. 


BRD,  S,  WVA.  (*). 


PDA. 

ENJ,  HMP. 
PEL. 

RDA. 
HMP,  RDA. 

{')■ 

CHR 
BPI. 


PDA. 
PCI. 


See  footnotes  at  end  of  table. 


12-11 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  12-3) 


Anionic  -Continued 
Carboxylic  adds  (and  salts  thereof)-Continued 
Carboxyllc  acids  having  amide,  ester,  or  ether 
llnkages-Contlnuedf 

Tridecyloxypoly(ethyleneoxy)ac8ticacld, 

sodium  salt  No 

All  other  cartx3xylic  acids  with  amide,  ester  or 

ether  linkage  No 

Potassium  and  sodium  salts  of  fatty,  rosin,  and 

tall  oil  acids: 

Alkoxy  triacryl  titanate No 

5(or  6)cart)oxy-4-hexyl-2-cyclohexene-1  -octanoic 

acid,  potassium/sodium  salts    No 

Castor  oil  acids,  potassium  salt   No 

Castor  oil  acids,  sodium  salt No 

Coconut  oil  acids  and  oleic  acid,  potassium  salt  No 

Coconut  oil  acids,  potassium  salt Yes 

Coconut  oil  acids,  sodium  salt    Yes 

Corn  oil  acids,  potassium  salt No 

Corn  oil  acids,  sodium  salt  No 

Gluconic  acid,  potassium  and  sodium  salts  W/20% 

mix  of  sodium  bisulfite-formaldehyde  No 

Heptanoic  acid,  potassium  salt No 

Isostearic  acid,  isoproxy  titanium  salt No 

Laurie  acid,  potassium  salt No 

Mixed  vegetable  fatty  acids,  potassium  salt No 

Mixed  wool  grease  and  tall  oil  fatty  acids No 

Neoalkoxy,  trineodecanoyi  titanate No 

Neoalkoxy.  trineodecanoyi  zirconate    No 

Oleic  acid,  ammonium  salt No 

Oleic  acid,  potassium  salt No 

Oleic  acid,  sodium  salt  Yes 

Olive  oil  acids,  potassium  salt No 

Palmitic  and  stearic  acids,  sodium  salt No 

Palm  kernel  oil  acids,  potassium  salt  No 

Palm  kernel  oil  acids,  sodium  salt No 

Palm  oil  acids,  sodium  salt No 

Rosin  acids,  potassium  salt    Yes 

Rosin  acids,  sodium  salt No 

Soybean  oil  acids,  potassium  salt No 

Stearic  acid,  ammonium  salt No 

Stearic  acid,  potassium  salt   No 

Stearic  acid,  sodium  salt Yes 

Tall  oil  acids,  potassium  salt Yes 

Tall  oil  acids,  sodium  salt    No 

Tallow  acids,  potassium  salt No 

Tallow  acids,  sodium  salt    Yes 

All  other  potassium  and  sodium  salts  of  fatty. 

rosin  and  tall  oil  acids  No 

Other  cartjoxylic  acids: 

All  other  carboxylic  acids    No 

Phosphoric  and  polyphosphoric  acid  esters  (and  salts 
thereof): 
Alcohols  and  phenols,  alkoxy lated  and  phosphated: 
C,2-C,5  Alcohol,  ethoxylated,  propoxylated  and 

phosphated No 

Butyl  alcohol,  ethoxylated  and  phosphated    No 

Decyl  alcohol,  ethoxylated  and  phosphated Yes 


FTX,  HMP,  S. 
WM. 

KPI. 

(\ 

CAS.  GRL 

DEX.  HEW. 

HCL 

AGP  CON,  ESS.  GRL.  HEW.  HNX  NMC, 

PG.  PNX. 
BSW,  CON.  CP.  ENJ,  HEW.  LEV.  NMC, 

PG.  PNX.  (2). 
EKT.  HNT 
NMC. 

HCL. 

(^ 

KPI. 

PG. 

CRT  GRL. 

SLM. 

KPI. 

KPI. 

ccc 

BSW.  EKT  HNT  PG.  VKR.  WBG,  (\ 

BSW,  NMC.  SCP  WBG. 

HNT 

BRI. 

PG. 

PG. 

BSW.  CON.  PG. 

ARZ,  WVA.  (2). 

SLM,  (2). 

ARZ. 

BSW. 

CON,  SCP 

CON.  CRT  HEW,  LEV.  PNX. 

CCC.  CON.  DAN,  ESS.  PER,  HNT  LEA. 

PNX.  SEP.  SCP  VKR.  WVA.  (\ 
NMC.  WVA.  (2).  (2). 
AGP  BSW,  PG.  PNX. 
CON.  CP  HEW.  LEV  NMC.  PG.  (\ 

MOA.  USR,  WVA. 

MOA.  TX,  WVA. 


GAP. 
RDA. 
MCP  OC,  RDA. 


See  footnotes  at  end  of  table. 


12-12 


Synthetic  Organic  Chemicals.  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Suriac9-activ0  agents 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Anionic-Contlnued 

Phosphoric  and  poiyphosphoric  acid  esters  (and  salts 
thereof)- Continued 
Alcohols  and  phenols,  alkoxylated  and  phosphated 
•Continued 

Dinonylphenol,  ethoxylated  and  phosphated   Yes 

Dodecyl  alcohol,  ethoxylated  and  phosphated No 

Dodecylphenol,  ethoxylated  and  phosphated No 

2-Ethylhexanoi  and  ethoxylated  nonylphenol, 

polyphosphated No 

2-Ethylhexanol  and  ethoxylated  nonylphenol, 

foly phosphated,  sodium  salt No 
thylhexanol,  ethoxylated  and  phosphated Yes 

2-Ethylhexanol,  ethoxylated,  phosphated, potassium 

salt No 

l-lexylalcohol,  ethoxylated  and  phosphated    No 

Lauryl  alcohol,  ethoxylated  and  phosphated No 

Meta,  para-cresol,  ethoxylated  and  polyphosphated, 

neutralized No 

Mixed  linear  alcohols,  alkoxylated  and  phosphated, 

potassium  salt No 

Mixed  linear  alcohols,  ethoxylated  and  phosphated  .    Yes 


Mixed  linear  alcohols,  ethoxylated  and  phosphated, 
sodium  salt   No 

Mixed  tridecyl  alcohol  and  2-ethylhexanol, 
phosphated,  potassium  salt No 

Nonylphenol,  ethoxylated  and  phosphated Yes 


Nonylphenol,  ethoxylated  and  phosphated, 

dietnanolamine  salt No 

Nonylphenol,  ethoxylated  and  phosphated,  sodium 

salt No 

9-Octadecenyl  alcohol,  ethoxylated  and  phosphated  Yes 

Octylphenol,  ethoxylated  and  phosphated   No 

Octylphenol,  ethoxylated  and  phosphated. 

magnesium  salt No 

Phenol,  ethoxylated  and  phosphated  Yes 

Polyhydric  alcohol,  ethoxylated  and  phosphated  No 

Polypropylene  glycol,  phosphated    No 

Tridecyl  alchol,  ethoxylatea  and  phosphated, 

polyalkylene  polyamine  salt No 

Tridecyl  alcohol,  ethoxylated  and  pirasphated   Yes 

Tridecyl  alcohol  ethoxylated  and  phosphated, 

potassium  salt No 

Tridecylphenol,  ethoxylated  and  phosphated No 

All  other  alcohols  and  phenols,  alkoxylated  and 

phosphated  or  polyphosphated No 

Alcohols,  phosphated  or  polyphosphated: 

Butyl  phosphate   No 

Butyl  phosphate,  potassium  salt No 

Decyl  and  octyl  phosphate  Yes 

Decyl  polyphosphate,  sodium  salt    Uo 

Ethyl  alcohol,  pnosphatod,  amine  salt    No 

2-Ethylhexyl  phosphate No 

2-Ethylhexyl  phosphate,  sodium  salt    No 

2-Ethylhexyl  polyphosphate,  sodium  salt   No 

IHexadecylmonophosphate No 


CPC.  ETC,  GAP,  RDA,  WTC. 
CPC,  ENJ,  GAP.  HCL.  RDA. 
DEX,  GAP,  RDA. 

COG. 

CCC. 

CPC,  ETC.  PPG,  SCP,  SDC,  UTC,  WTC. 

BRI. 
RDA. 
RDA. 

RDA. 

PCI. 

BAS,  CRD,  CTL,  ENJ.  ESS,  ETC.  PER. 

HCL,  HRT  LUR,  MOA,  MRV.  NES.  RDA. 

SOS.  WTC. 

CHP 

CHR 

ARL,  CPC,  CTL,  DEX.  ESS,  ETC,  GAP. 

GDC.  HDG.  HRT  LEA.  MCP  MOA. 

NES,  OC,  OMC,  PPG,  RDA.  UTC.  VKR, 

WTC. 

OMC,  WTC 

WTC. 

ETC,  GAP,  HCL.  RDA,  WTC. 

LUR,  PPG,  RDA,  RH,  WTC. 

HIP 

ETC,  GAP  HDG,  LUR,  MOA,  PEL,  PPG, 

RDA,  WTC. 
ETC,  RDA. 
BAS. 

CPC,  DAN.  DEX.  ETC.  GAP.  MIL.  RDA. 
WTC. 

DEX. 
TCC. 

ETC.  RDA,  SCR  TCC,  ('){E). 

HRT  TCC, 

DUR 

ENJ,  ETC,  HCL,  SCR 

CRD. 

UTC. 

CHR  ETC.  PER,  OC,  OMC.  RDA,  SOS, 

VKR,  (^. 

CHR  DAN,  ENJ,  S. 

DEX. 

{')■ 


See  footnotes  at  end  of  table. 


12-13 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Suri ace-active  agents 


Separate      Manufacturers '  identification  codes 
statistics '      (according  to  list  in  table  12-3) 


Anionic-Continued 
Phosphoric  and  polyphosphoric  acid  esters  (and  salts 
thereof)-Continued 
Alcohols,  phosphated  or  polyphosphated-Contlnued 

Hexyl  phosphate No 

Hexyl  phosphate,  potassium  salt   No 

Isooctyl  phosphate   No 

Isooctyl  phosphate,  potassium  salt No 

Isopropyl  phosphate No 

Methylbutyl  pyrophosphate,  ethylenedioxy  titanium 

salt No 

Mixed  alky!  phoshate,  sodium  salt   No 

Mixed  alky!  phosphate    Yes 

Mixed  alky!  phosphate,  alkylamine  salt No 

Mixed  alky!  phosphate,  diethanolamine  salt No 

Mixed  alkyl  phosphate,  potassium  salt No 

Mixed  alkyl  phosphate,  triethanolanine  salt    No 

Neoalkoxy  tris(dioctyl)  pyrophosphato  zirconate    ...  No 

9-Octadecenyl  phosphate No 

Octyl  phosphate,  alkylamine  salt    No 

Octyl  phosphate,  isoproxy  titanium  salt   No 

Octyl  phosphate  neoalkoxy  titanium  sah No 

Octyl  polyphosphate No 

Octyl  polyphosphate,  potassium  salt    No 

Octyl  pyrophosphate,  ethylenedioxy  titanium  salt  ...  No 

Octyl  pyrophosphate,  isoproxy  titanium  salt No 

Octyl  pyrophosphate  neoalkoxy  titanium  salt No 

Octyl  pyrophosphate,  oxoethylenedioxy  titanium 

salt No 

Octyl  pyrophosphate  titanium  salt No 

N-2(C2  to  Ci7)alkylamido-N-carboxyethyl.N-2- 

hydroxyethyl,  3-amino-2-mydroxypropyl  phosphate. 

disodium  salt No 

Tridecyl  phosphate No 

All  other  phosphated  and  polyphosphated 

alcohols No 

Other  phosphoric  and  polyphosphoric  acid  esters; 

Blend  o(  fatty  and  phosphate  esters No 

Glycerol,  ethoxylated  and  phosphated No 

Glycerol  monoester  of  mixed  fatty  acids, 

phosphated No 

Octadeclyamine,  ethoxylated  and  phosphated, 

sodium  salt   No 

All  other  phosphoric  and  polyphosphoric  acid 

esters    No 

Sulfonic  acids  (and  salts  thereof): 
Alkylbenzenesulfonates: 
Dodecylbenzenesutfonates: 

Dodecylbenzenesulfonic  acid Yes 

Dodecylbenzenesulfonic  acid,  (Mixed  alkyl)amine 

salt No 

Dodecylbenzenesulfonic  acid,  ammonium  salt Yes 

Dodecylbenzenesulfonic  acid,  calcium  salt Yes 

Dodecylbenzenesulfonic  acid,  diethanolamine 

salt No 

Dodecylbenzenesulfonic  acid,  isopropanolamine 

salt No 

Dodecylbenzenesulfonic  acid,  isopropylamine 

salt Yes 


ETC,  HCL,  ICI. 

iCI. 

BOE,  BRI.  OCR 

OCR,  RDA, 

TCC. 

KPI. 

CTL.  DUR  HCL,  HIR  WTC,  {% 

(^. 

DUR  SCR 

OCR 

{'). 

KPI. 

GAR 

{"). 

KPI. 

KPI. 

DEX. 

DEX. 

KPI. 

KPI. 

KPI. 

KPI. 
KPI. 


MOA. 
HCL. 

ETC. 

MIL. 
(')■ 

WTC. 

GDC. 

ENJ.  MOA,  SCR  WTC. 


EMK.  ENJ,  JLR  LEV,  NRR,  PIL,  STR  TEN. 
VST  WTC,  (^). 

JLR  ('). 

CCC,  NES,  WTC.  (2). 

HCL.  ICI.  RH,  STR  TMH,  WTC,  (^). 

RDA. 

PIL. 

HIR  ICI.  KPI.  NES,  PPG,  RDA.  STR 
WTC.(2). 


See  footnotes  at  end  of  table. 


12-14 


Synthetic  Organic  Chemicals.  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Surface-activB  agents 


Separata 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Anionlc-Continued 
Sulfonic  acids  (and  salts  thereof)-Continued 
Aikyibenzenesuifonates-Contlnued 
Dodecylbenzenesulfonates-Contlnued 

Oodecylbenzenesulfonic  acid,  monoethanolamine 

salt No 

Dodecylbenzenesulfonlcacid,  potassium  salt  ....    Yes 
Dodecylbenzenesultonicacid,  sodium  salt Yes 


Dodecylbenzenesulfonic  acid,  triethanoiamine 

salt Yes 

All  other  dodecylbenzene  sulfonates No 

Other  alkylbenzenesulfonates: 

Benzene  sulfonic  acid No 

Didodecylbenzenesulfonic  acid,  sodium  salt No 

Neoalkoxy,  dodecylbenzene-sulfonyl  titanate  ....  No 

Tridecylbenzenesulfonic  acid    No 

Tridecylbenzenesulfonic  acid,  sodium  salt   No 

Benzene-,  cumene-,  toluene-,  and  xylenesulfonates: 

CumenesuHonic  acid,  ammonium  salt   No 

CumenesuKonic  acid,  sodium  salt    No 

Toluenesulfonic  acid,  potassium  salt No 

Toluenosulfonic  acid,  sodium  salt No 

Toluene  xylene  sulfonic  acid No 

Xylenesulfonic  acid,  ammonium  salt No 

Xylenesulfonic  acid,  sodium  salt Yes 

All  other  benzene-,  cumene-,  toluene-,  and 

xylenesulfonates No 

Ligninsulfonates: 

Ligninsulfonic  acid,  ammonium  saK   Yes 

Ligninsulfonic  acid,  calcium  salt  Yes 

Ligninsulfonic  acid,  chromium  salt   No 

Ligninsulfonk:  acid,  iron  salt   No 

Ligninsulfonic  acid,  magnesium  salt No 

Ligninsulfonic  acid,  mixed  chromium  and  iron 

salts No 

Ligninsulfonic  acid,  potassium  salt No 

Ligninsulfonic  acid,  sodium  salt    Yes 

Ligninsulfonic  acid,  zinc  salt No 

All  other  ligninsulfates No 

Naphthalenesulfonates: 

Butylnaphthalenesulfonic  acid,  sodium  salt   No 

Di(C5-Cs  alkyl)naphthalenesulfonic  ackJ No 

Dibutylnaphthalenesulfonicacid No 

Diisopropylnaphthalenesulfonic  acid,  sodium  salt    ..  No 

Isopropylnaphthalenesulfonicacid   No 

Methylnaphthalenesulfonic  acid,  sodium  salt No 

Methylnonylnaphthalenesulfonic  acid,  sodium  salt  ..  No 
Naphthalenesulfonic  acid,  sodium  salt, 

formaldehyde  condensate No 

All  other  naphthalenesulfonates No 

Sulfonic  acids  having  amide  linkages: 
Sulfosuccinamk:  acid  derivatives: 
N-[Coconut  oil  alkyl]sulfosuccinamk:  and 

disodlum  salt  No 

N-(1 .2-Dicart)oxyethyl)-N- 
octadecylsulfosuccinamk:  acid,  tetrasodium 

salt No 


ESS,  RDA. 

BRI,  ESS,  GDC.  LEA. 

BLA,  BOE,  BRI.  CP,  CPC.  CTL,  DOW, 

DUP.  ECC,  LEA.  LEV,  NES,  NPR,  PCI. 

PIL.  PNX,  RDA.  STP  TEN,  VST  WTC, 

BRD,  BRI.  CCC,  CPC,  CTL,  ESS.  NES. 
PCI.  PIL,  PPG.  RDA,  SCP  STP  WTC. 
ENJ,  PG.  (2)(E). 

WTC. 

ENJ. 

KPI. 

CP  STP. 

BLA,  CMT  CPC,  STP. 

NES,  STP. 

NES,  STP  WTC. 

NES. 

NES,  PG,  VST 

WTC. 

NES.  STP,  WTC. 

ICI,  NES,  PIL.  STP.  WTC. 

SCR 

MAR.  PSP  RAY,  SPA. 
FPC.  MAR.  PSP 
PSP  RAY 
MAR.  PSP 
MAR.  WVA. 

PSP 

PSP 

ENJ.  MAR.  PSP  RAY 

MAR,  PSP 

ETC.  LKY  MAR. 

SCP.  UDI. 

(% 

UDI. 

DUP.  SCP  UDI. 

UDI. 

CPC.  SCP  UDI. 

UDI. 

ICI. 

HAL.  SCP  UDI. 


WPG. 
ACY  MOA. 


See  footnotes  at  end  of  table 


12-15 


Sec  lion  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separata 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  12-3) 


Anionlc-Contlnued 
Sulfonic  adds  (and  salts  thereof)-Contlnued 
Sulfonic  acids  having  amide  linitages-Continued 
Sulfosucclnamic  acid  derivatives-Continued 

N-Octadecylsulfosuccinamic  acid,  disodium  salt .  .    No 
Oleamidosulfosuccinamicacid,  disodium  salt  ....    No 

ISl-(Oleoyloxyisopropyl)sulfosuccinamic  acid No 

All  other  sulfosucclnamic  acid  derivatives No 

Taurine  derivatives: 
N-(Coconut  oil  acyl)-N-methyltaurine,  sodium 

salt No 

N-Methyl-N-oleoyltaurine,  sodium  salt    No 

N-Methyl-N-palmitoyltaurine,  sodium  salt No 

N-Methyi-N-(tall  oil  acyl)taurine,  sodium  salt No 

All  other  sulfonic  acids  having  amide  linkages: 
All  other  sulfonic  acids  having  amide  linkages   ...    No 
Sulfonic  acids  having  ester  or  ether  linkages: 
Sulfosuccinic  acid  esters: 
SuHosuccinic  acid,  bis(diisobutyl)ester, 

amidodisodium  salt  No 

Sulfosuccinic  acid,  bis(2,6-dimethyl-4-heptyl)- 

ester,  sodium  salt No 

Sulfosuccinic  acid,  bis(2-ethylhexyl)ester, 

sodium  salt    Yes 


Sulfosuccinic  acid,  dihexyl  ester,  sodium  salt  ....    No 
Sulfosuccinic  acid,  dlisobutyl  ester,  sodium 

salt No 

Sulfosuccinic  acid,  diisodecyl  ester,  sodium 

salt No 

Sulfosuccinic  acid,  diisooctyl  ester,  sodium 

salt No 

Sulfosuccinic  acid,  dioctyl  ester,  sodium  salt No 

Sulfosuccinic  acid,  dipentyl  ester,  sodium  salt    ...    No 
Sulfosuccinic  acid,  ditridecyl  ester,  sodium 

salt No 

Sulfosuccinic  acid,  (lauryl  polyethylene  glycol 

ether)  ester,  disodium  salt No 

Sulfosuccinic  acid,  (coconut  oil  alkyl)- 

iminoisopropanol  half-ester,  sodium  salt No 

Sulfosuccinic  acid,  lauramidomonoethanolamine, 

disodium  salt  No 

Sulfosuccinic  acid,  monolaureth  ester,  disodium 

salt No 

Sulfosuccinic  acid  myristyl  ester  disodium 

monoethanolamine  sail No 

Sulfosuccinic  acid,  nonoxynyl-10  ester, 

disodium  salt  No 

Sulfosuccinic  acid,  oleamidopolyethyleneglycol, 

disodium  salt  No 

Sulfosuccinic  acid,  ricinoleamide 

monoethanolamine,  disodium  salt No 

All  other  sulfosuccinic  acid  esters No 

All  other  sulfonic  acids  having  ester  or  ether 

linkages: 
Coconut  oil  acids,  2-sulfoethyl  ester,  sodium 

salt No 

Dodecyldlphenyloxidedisulfonicacid No 

Dodecyldlphenyloxidedisulfonic  acid,  disodium 

salt No 


ACY,  HIP. 
SBC. 
WTC. 
SCP. 


FTX,  RDA. 

CPC.  FTX.  HCI^  RDA,  WPG. 

GAP.  RDA. 

CCC,  RDA,  WVA. 

HCL. 


MOA. 
MOA.  NSC. 

ACY.  AMU.  APX.  BRI,  CCC.  CHP.  ECC, 
EMK.  ENJ.  FTX,  HCL,  MCP,  MOA.  RDA. 
RH,  WTC. 

FTX,  MOA. 

FTX. 

ACY 

ACY  ARi.  SCP.  SHX.  SOS. 

MOA. 

ACY 

ACY  MOA. 

SHX. 

MOA. 

RDA. 

MOA.  RDA. 

WTC. 

MOA. 

MOA. 

RDA. 

FTX.  MOA.  WTC. 


FTX,  GAF  LEV,  RDA. 
CTL,  PIL,  RDA,  {'). 


See  footnotes  at  end  of  table 
12-16 


Synthetic  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Suriace-activo  agents 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


An  Ionic-Continued 
Sulfonic  acids  (and  salts  thereof)-Continued 
Sulfonic  acids  having  ester  or  ether  llnkages-Contin 
All  other  sulfonic  acids  having  ester  or  ether 
linkages-Continued 
iso-octyphenol,  ethoxylated  and  sulfonated, 

sodium  salt    No 

n-Octylphenol,  ethoxylated  and  sulfonated. 

sodium  salt    No 

All  other  sulfonic  acid  with  ester  linkages No 

All  other  sulfonic  acids  with  ether  linkages No 

Other  sulfonic  acids: 

Allyl  sulfonate,  sodium  salt No 

Diphenylsulfone  sulfonic  acid,  potassium  salt No 

Mixed  alkanesulfonic  acid No 

Mixed  alkane  sulfonic  acid,  sodium  salt  No 

Mixed  linear  olefin  sulfonate Yes 

n-Octanesutfonic  acid,  sodium  salt No 

Oleyloxyethyldiamide  oxypropanol  sulfonk:  acid  ....    No 
Petroleumsutfonic  acid,  water  soluble  (Acid 

layer),  sodium  salt No 

Tall  oil.  sulfonated,  potassium  salt    No 

All  other  sulfonic  acids   No 

Sulfuric  acid  esters  (and  salts  thereof): 
Acids,  amides,  and  esters,  sulfated: 
Coconut  oil  acids-ethanolamine  salt,  sulfated, 

potassium  salt No 

Mixed  alkyl  phenol  sulfate,  ethoxylated. 

tnethanolamine  salt No 

Carboxylic  acid  esters  (except  natural  fats  and 
oils),  sulfated: 
Esters  of  sulfated  oleic  acid: 

Butyl  oleate,  sulfated,  sodium  salt Yes 

Isopropyl  oleate.  sulfated,  sodium  salt No 

Methyl  oleate.  sulfated,  sodium  salt No 

Oleic  acid,  sulfated   No 

Oleic  acid,  sulfated,  disodium  salt No 

OIek:  acid,  sulfated,  sodium  salt   No 

Propyl  oleate.  suHated.  sodium  salt No 

All  other  esters  of  sulfated  oleic  acid No 

Other  sulfated  esters: 
Glycerol  monoester  of  coconut  oil  acids, 

sulfated,  sodium  salt    No 

Tall  oil  acids,  sulfated,  sodium  salt    No 

All  other  sulfated  esters No 

Alcohols,  sulfated: 

Decyl  and  octyl  sulfate,  sodium  salt  No 

Decyl  sulfate,  sodium  salt No 

Dodecylsulfate  salts: 
Dodecyl  sulfate,  2-amino-2-methylpropanol  salt  .  .    No 

Dodecyl  sulfate,  ammonium  salt Yes 

Dodecyl  sulfate,  diethanolamine  salt No 

Dodecyl  sulfate,  N,N-diethylcyclohexylamine 

salt No 

Dodecyl  sulfate,  isopropanolamine  salt No 

Dodecyl  sulfate,  magnesium  salt No 

Dodecyl  sulfate,  sodium  salt  Yes 

Dodecyl  sulfate,  tnethanolamine  salt Yes 

3,9-Dielhyl-6-tridecyl  sulfate,  sodium  salt No 

2-Ethylhexyl  sulfate,  sodium  salt Yes 


RH. 

APX. 
GAF. 
PG,  PPG,  SCP. 

ARD. 
UPF. 


a 


M.  STP  WTC. 
RDA,  STP,  WVA. 


PIL. 

CGY  CLU,  HAL. 


EMK,  ENJ. 
MIL. 


HIP,  ICi,  MCP.  MRV.  NSC. 

DEX. 

ICI. 

ACT 

MCP 

ACY  CIN. 

MRV. 

LUR,  SCP 


CP 
ICI. 
RDA. 

STP 

ARI,  SCP  VVTC. 

SCP 

BRD,  LEV,  RDA,  STP  TNI,  WTC,  {^). 

DUP  JRG,  STP 

DUP 

JRG. 

RDA  STP 

BRd!  DUP  RDA,  STP 

BRD,  RDA,  STP  TNI. 

NCC. 

NCC,  PCI,  RDA,  WTC. 


See  footnotes  at  end  of  table. 


12-17 


Section  12 

Table  12-2— Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Suriace-active  agents 


Separata 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Anionic — Continued 
Sulfuric  acid  esters  (and  salts  thereof)-Continued 
Alcohols,  suifated-Continued 

7-Ethyl-2-methyl-4-undecyl  sulfate,  sodium  salt No 

Hexadecyl  sulfate,  sodium  salt No 

Hexyl  sulfate,  potassium  salt    No 

Ail  other  linear  alcohols,  sulfated   No 

Mixed  linear  alcohols,  sulfated,  ammonium  salt  ....  No 

Mixed  linear  alcohols,  sulfated,  sodium  salt  No 

Mixed  linear  alcohols,  sulfated,  triethanoiamine 

salt No 

Octyl  sulfate,  sodium  salt   No 

Oieyl  sulfate,  sodium  salt  No 

Oxoaicohoi  bottoms,  sulfated,  sodium  salt No 

Tridecyl  sulfate,  sodium  salt  No 

All  other  alcohols  and  phenols,  sulfated No 

Ethers,  sulfated: 
Ail^ylphenols,  ethoxyiated  and  sulfated: 

1  -t^aphthol,  ethoxyiated  and  sulfated,  free  acid   . .  No 

Nonyiphenoi,  ethoxyiated  and  sulfated,  ammonium 

salt No 

Nonyiphenoi,  ethoxyiated  and  sulfated,  sodium 

salt No 

Octylphenoi,  ethoxyiated  and  sulfated,  sodium 

salt No 

Octylphenoxy  polyethoxy  ethyl  sulfate   No 

All  other  sulfated  cyclic  ethers No 

Dodecyl  alcohol,  ethoxyiated  and  sulfated. 

ammonium  salt  No 

Dodecyl  alcohol,  ethoxyiated  and  sulfated,  sodium 

salt No 

Dodecyl  and  tetradecyi  alcohols,  ethoxyiated  and 

sulfated,  ammonium  salt   No 

Isobutanol,  ethoxyiated  and  sulfated,  ammonium 

salt No 

Mixed  linear  alcohols,  ethoxyiated  and  sulfated, 

ammonium  salt   No 

Mixed  linear  alcohols,  ethoxyiated  and  suKated. 

sodium  salt   No 

Tridecyl  alcohol,  ethoxyiated  and  sulfated, 

sodium  salt   No 

Natural  fats  and  oils,  sulfated: 

Castor  oil,  sulfated,  sodium  salt  Yes 

Coconut  oil,  sulfated,  sodium  salt No 

Cod  oil,  sulfated,  sodium  salt   No 

Cod  oil,  sulfated,  sodium  salt   No 

Grease,  other  than  wool,  sulfated,  sodium  salt  No 

Herring  oil,  suHated No 

Herring  oil,  sulfated,  sodium  salt No 

Lard,  sulfated,  sodium  salt  No 

Mixed  animal  and  vegetable  oil,  sulfated,  sodium 

salt No 

Mixed  fish  oils,  sulfated,  ammonium  salt    No 

Mixed  fish  oils,  sulfated,  sodium  salt No 

Mixed  vegetable  oils,  sulfated,  sodium  salt No 

Mixed  vegetable  oils,  sulfated,  sodium  salt No 

Mustard  seed  oil,  sulfated,  sodium  salt No 

Neatsfoot  oil,  sulfated,  sodium  salt No 


NCC. 

RDA. 

DEX. 

PG.  RDA. 

CP,  S,  SCP,  WTC,  (2). 

BRD.  CP,  DUP.  PG.  SCP,  WTC. 

SCP,  WTC. 

ARC.  DUP,  RDA. 

DUP.  RDA. 

WVA. 

RDA. 

RDA. 


SCP. 

GAP.  RDA.  STP. 

GAP.  RDA.  WTC. 

RDA,  STP 

RH. 

RDA. 

MOA,  RDA. 

BRD.  RDA. 

PG,  RDA,  SCP,  SHC.  STP,  TNA,  VST. 
WTC.  (2). 

DUP  PG.  PIL,  RDA,  SCP  SHC.  STP.  VST. 
WTC,  WVA. 

RDA. 

ACT  ACY,  ARI.  ARL.  CRT  DEX.  HIP.  ICI. 

LEA,  LUR,  MRV,  S,  SCR  SLM,  WHW. 
ACY 
ARI. 
WHW. 
WHW. 
SLM. 

ARI,  SLM,  WHW. 
CIN,  CRT  WHW. 

SLM. 

CIN. 

CRT  SLM,  WHW. 

CRT  LUR. 

CPC. 

CRT 

ARI,  WHW. 


See  footnotes  at  end  of  table. 


12-18 


Synthetic  Organic  Chemicals.  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  saies  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistics ' 


Marjufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Anionic-Continued 
Sulfuric  acid  esters  (and  salts  thereof>-Continued 
Natural  fats  and  oils,  suifated-Continued 

Peanut  oil,  sulfated,  sodium  salt No 

Soybean  oil,  sulfated,  sodium  salt    No 

All  other  sulfated  animal  fats  and  oils No 

All  other  sulfated  fish  and  manne  fat  oils    No 

Synthetic  fatty  alcohol  ester,  sulfated,  sodium 

salt No 

Tall  oil, sulfated,  ammonia  salt No 

Tall  oil,  sulfated,  sodium  salt Yes 

Tallow,  sulfated,  sodium  salt Yes 

All  other  vegetable  oils,  sulfated No 

All  other  sulfuric  acid  esters  No 

Other  anionic  surface-active  aqents: 
Allcylalcohol  ethoxylated  and  cartxinated,  sodium 

salt    No 

Ethoxylated  acetic  acid,  sodium  salt No 

IHalf-phthalic  acid  ester  of  tallow 

alkanolamide/monoglyceride   No 

Lignin,  sodium  salt   No 

Mixed  alpha-olefins  and  vegetable No 

Mixed  linear  alcohols,  ethoxylated  and  cartxjnated, 

sodium  salt  No 

Nonylphenol,  ethoxylated  and  cartwnated,  sodium 

salt   No 

StearoyI  iso-lactylate,  sodium  salt   No 

StearoyI  lactylate,  mixed  sodium  and  calcium  salt  ....  No 

StearoyI  lactylate,  sodium  salt   No 

StearoyI  lactylate,  sodium  salt   No 

Tridecyl  alcohol,  ethoxylated  and  cartranated, 

sodium  salt  No 

All  other  anionic  surface-active  agents    No 

Cationic  surface-active  agents: 
Amine  oxides  and  oxygen-containing  amines  (except 
those  having  amide  linkages): 
Acyclic: 

3-(C,2-C,5  alkyloxy)-1-propanamine No 

N,N-Bis(2-hydroxyethyl)(coconut  oil  alkyl)amine    ...  No 
N,N-Bis(2-hydroxyethyl)(coconut  oil  alkyl)amine 

oxide No 

N,N-Bis(2-hydroxyethyl)dodecylamine No 

Bis-(2-hydroxyethyl)isodecyloxypropylamineoxkJe   .  No 

N,N-Bis(2-hydroxyethyl)octadecylamine Yes 

N.N-Bis(2-hydroxyethyl)(talk)w  alkyljamine    Yes 

Cocoamidopropyl  dimetfiyl  amine No 

(Coconut  oil  alkyl)amine,  ethoxylated No 

Coconut  oil(alkyl)amine,  ethoxylated  and 

phosphated No 

Coconut  oil  alkyl  amine,  propoxylated    No 

Diethylenetriamine,  alkoxylated   No 

N,N-DimGthyl(coconut  oil  alkyl)amine  oxide No 

N,N-DimethyldGcylaminG  oxide No 

N,N-Dimethyldodecylamine  oxide No 

N,N-Dimethylhexadecylamine  oxide No 

N,N-DimGthyl(mixGd  alkyl)amine  oxide No 

Di(pyrrolidonylGthyl)imine No 

Ethylene  diamine  ethoxlated No 

Hexyloxypropyl  amine No 

(Hydrogenated  tallow  alkyl)amlne.  ethoxylated    ....  Yes 


ACY 

ACT  SCP,  WHW. 

WHW. 

WHW. 

SLM. 

CIN. 

ACT  AMU,  ARi,  CIN,  CRT  WHW.  WTC. 

CCC.  CRT  NSC.  SCP,  WHW. 

CRT  LUR.  SCP.  TEN. 

SCP. 


MIL. 
S. 

EFH. 
WVA. 
SLM. 


WTC. 

BFP. 

BFP. 

BFP. 

BFP 


CGY  DUP.  MOA. 


ENJ. 
ARC. 

SHX. 
ARC. 
ENJ. 

ARC.  GAF.  SHX. 
ARC,  ENJ.  HCL.  JTO,  SHX,  (2). 
0. 

ARC,  BAS.  ENJ.  ETC.  SHX.  SVC.  WTC. 
{').{')■ 

{')■ 
SHX. 
{% 
ARC. 


ik 


^D,  CTL,  PG.  SHX. 
ARC. 
S. 

PCI. 
KPI. 

DUP,  ENJ. 
ENJ.  ETC,  RDA.  SHX.  WTC. 


See  footnotes  at  end  of  table. 


12-19 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistics' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Cationic-Continued 
Amine  oxides  and  oxygen-containing  amines  (except 
those  having  amide  linkages)-Continued 
Acyclic-Continued 
N-(2-Hydroxyethyl)-N.N',N'-tris(2-hydroxypropyl)- 

ethylenediamine   No 

Isodecyloxypropylamine No 

Isodecyloxypropylamine,  ethoxylated No 

3-(3-lsodecyloxy)propylaminopropyl  amine  No 

N-lsodecyloxypropyl  trimethylene  diamine No 

lsopropoxy-tris(2-ethylenediamino)ethyltitanate   ...  No 

isotridecyloxypropylamine    No 

N-lsotridecyloxypropyl  trimethylene  diamine    No 

3-(Mixed  alkoxyjpropyiamine,  ethoxylated  oxides   .  .  No 

3-(3-Mixed  alkoxy)propylaminopropyi  amine   No 

(Mixed  alkyl)amine,  ethoxylated Yes 

Neoalkoxy,  tri(m-amino)-phenyl  titanate No 

Neoalkoxy,  tris(m-amino)  phenyl  zirconate No 

(9-Octadecenyl)amine,  ethoxylated   Yes 

Octadecylamine,  ethoxylated  Yes 

Octyldimethyiamine  oxide No 

Polyalkylene  polyamine,  ethoxylated   No 

Polyether  amine,  ethoxylated  No 

(Soybean  oil  alkyljamine.  ethoxylated    Yes 

(Tallow  alkyl)amine,  ethoxylated Yes 

(Tallow  alkyl)amine,  propoxylated No 

N-(Tallowalkyl)tnmethylenediamine,  ethoxylated  . .  .  Yes 

[Tallow  ethyl  alkyljamine,  ethoxylated,  sulfate    No 

N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine  .  No 
N.N,N'.N'-Tetrakis(2-Hydroxyethyl)ethylenediamine. 

propoxylated  No 

N,N,N',N'-Tetrakis(2-hydroxypropyl)- 

ethylenediamine,  propoxylated  and  ethoxylated  . .  No 

3-(3-Tridecyloxy)propyiaminopropyl  amine No 

Tridecyl-3-(trimethyleneamine),  ethoxylated No 

Triethanolamine,  ethoxylated   No 

Triethanolamine  phosphate  ester No 

All  other  amine  oxides  and  oxygen-containing  amines 

(Except  those  with  amide  linkages),  acyclic  No 

Cyclic: 

Aniline,  ethoxylated No 

2-Butenedioic  acid-(")-diamine  -  1-(2-aminoethyl)- 

2-(tall  oil  alkyl)-2-imida2oline  condensate No 

2,5-Dimethoxyaniline,  ethoxylated   No 

2-(8-Heptadecenyl)-4,4-bis(hydroxymethyl)-2- 

oxazoline No 

N-Hexadecylmorpholine No 

N-(2-Hydroxyethyl)-1,2-diphenylethylenediamine  .  .  .  No 

1-(2-Hydroxyethyl)-2-nonyl-2-imidazoline Yes 

1-(2-Hydroxyethyl)-2-nor(coconLrt  oil  alkyl)-2- 

imidazoline    No 

1-(2-Hydroxyethyl)-2-nor(tall  oil  alkyl)-2- 

imidazoline    Yes 

1  -(2-Hydroxyethyl)-2-(tall  oil  alkyl)imida2oline, 

fatty  acid  salt No 

Lignin  amine No 

Rosin  amine,  ethoxylated No 

m-Toluidine,  ethoxylated No 


ENJ. 

ENJ. 

SHX. 

ENJ. 

KPI. 

ENJ. 

ENJ. 

SHX. 

SHX. 

BRD.  ICI.  RH. 

KPI. 

KPI. 

ETC,  RDA,  SHX.  WTC.  (=>). 

ARC.  ETC.  WTC. 

HNT 

BAS. 

RH 

ARC,  ENJ.  ETC.  JTO.  SHX.  SVC,  C). 

BAS.  DUP.  ENJ.  ETC.  HCL.  PPG.  RDA,  S, 

SCP.  SHX.  WTC.  (2).  (2). 

SHX 

ARC.  ENJ,  ETC,  JTO.  {'). 

RDA. 

BAS,  (2). 

HCL. 

BAS.  ETC. 

SHX. 

JTO. 

[wllL.  RSA.  SCP. 

(^ 

ARC.  ENJ.  ETC.  MOA.  PG.  RDA.  SCP. 
SHX.  WTC.  (2).  (2). 

MIL. 

MIL. 

ENJ. 

BRD.  RDA. 

MOA.  RDA. 

BRD.  MOA.  RDA.  SHX.  WTC. 

BRD.  FTX.  MOA. 

HDG.  MOA.  RDA.  SCP.  (*). 

(^. 
WVA. 
HPC.  (2). 
MIL. 


See  footnotes  at  end  of  table 


12-20 


Synthetic  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 

Separate       Manufacturers '  identification  codes 
Surface- active  agents  statistics '      (according  to  list  in  table  12-3) 

Cationic-Continued 
Amines,  not  containing  oxygen  (and  salts  thereof) 
•Continued 
Secondary  and  tertiary  monoamines-Contlnued 

N-Methylbis(hydrogGnated  tallow  alkyl)amine    No  ARC.  SHX. 

N-f^ethyldioctadecylamine No  ARC. 

Tri(hydrogenated  tallow)  amine    No  SHX. 

Tnisodecylamine No  SCP. 

Trilaurylamine No  SCP. 

Tri(mixed  alkyljamine  No  SHX. 

Trioctylamine No  SCP.  SHX. 

Ail  otiner  secondary  and  tertiary  monoamines No  ARC.  BRD.  ENO.  JTO,  TNA.  WTO. 

OxygGn<ontalning  quaternary  ammonium  salts: 
P-Alanine-N-(2-hydroxyethyl)-N-  2  1- 

oxococoyi  amino  ethyl,  sodium  salt    No  SHX. 

2-(C,3-C,7  Ail<yl)-1-(C1-,8  amidoGthyl)(4,5-dlmydro- 

3-methyl)imidazolinium,  methyl  sulfate No  DOW.  SVC. 

(2-Aminoethyl)ethyl(hydrogenated  tallow  aii(yi)(2- 

hydroxyethyl)ammonium  ethyl  sulfate No  OC. 

Benzyl(cooonut  oil  alkyl)bis(2-hydroxyethyl)- 

ammonium  chloride    No  {'). 

1  -Benzyl-2-heptadecyl-1  -(2-hydroxyethyi)-2- 

imidazolinium  chloride    No  HDG. 

1  -Benzyl-1  -(2-hydroxyethyl)-2-nor(tali  oil  aikyi)-2- 

imidazoline   No  (^). 

Benzyl(tallowalkyi)bis(2-hydroxyethyl)ammonium 

chloride No  DUP. 

Bis(N-amidopropyl)-N.N-dimethyl-N-ethyiammonium 

ethyl  sulfate,  dimer  acid    No  SBC. 

Bis(N.N1-ethyl(stearic/arachidic/behenic)amide)- 

cyanoethyl  ethylammonium  ethosuifate  No  PCI. 

Bis(2-hydroxyethyl,  ethoxylated)- 

methyioctadecyiammonium  chloride No  SHX. 

Bis-2-hydroxyethyl-hydrogenated  tallow-ethyl 

sulfate No  ICI. 

Bis[2-hydroxyethyi]methyl[tallowalkyi)ammonium 

chloride No  ARC,  JTO. 

Bis-2-hydroxyethyl-octyl-methyl-p-toluene  sulfonate  .  .    No  HXL. 

(Coconut  oil  alkyl)bis(2-hydroxyethyl,  ethoxyiated)- 

methyiammonium  chloride   No  ENJ.  GAP,  RDA,  SHX. 

Dimethyl  dodecyl  ethyl  ammonium  ether  sulfate    No  PCI. 

Distearyldimethyl  ammonium  methosulfate   No  HXL. 

Ethoxylated(hydrogenatGd  tallow  amine),  methyl 

ammonium  chloride    No  ENJ. 

Ethoxylated,  quaternized(C,2-C,s  alkyl)  oxypropyi 

trimethyiene  diamine No  ENJ. 

Ethoxylated.  quaternized  reaction  product  of 

formaldehyde  and  tallow  diamine No  ENJ. 

N-Ethyl-N,N-bis(polyoxyethylene)tallow  ammonium 

ethyl  sulfate No  SHX. 

1-Ethyl-2-(8-heptadecenyl)-1-(2-hydroxyethyl)-2- 

imidazolinium  ethyl  sulfate   No  iCi,  SHX. 

N-Ethyi-N-hexadecylmorpholinium  ethyl  sulfate No  BRD,  ICI. 

Ethyl(polyoxyethylene.  cocoamine)  ethylsulfate No  S. 

N-Ethyl-r\l-(soybean  oil  alkyl)morpholinium  ethyl 

sulfate No  ICi. 

a-Gluconamidopropyl  dimethy-2-hydroxyethyl  ammonium 

chloride No  VND. 

(2-Hydroxyethyl)dimethyl(3-stGaramidopropyl)- 

ammonium  nitrate No  ACY. 


See  footnotes  at  end  of  table. 


12-23 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sates  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 

Separate      Manufacturers' idontUication  codes 
Suriace-active  agents  statistics '      (according  to  list  in  table  12-3) 

Cationic-Continued 
Oxygen-containing  quaternary  ammonium  salts-Continued 

Hydroxyethyl-2-undecyl-2.3-imidai:oline No  MOA. 

N-2-hydroxy  propyl-n-methyl-N,n-bis[tallow  amide 

ethyl]  ammonium  ethyl  sulfate    No  SHX. 

Imidazolinium,  1  -carboxymethyl)-4,5-dihydro-1  - 

(hydroxyethyl)-2-nor(cocoalkyl),  hydroxides, 

monosodium  salts No  SHX. 

Isostearamidopropyldimethylaminoglycolate No  SBC. 

(3-Lauramidopropyl)trimethylammonium  methyl  sulfate    N  ACY. 

2-(2-Lauroyloxyethyl)carbamoyl-1-methylpyridinium 

chloride No  ENJ. 

Methyl,  bis-(2-hydroxyethyl)  hydrogenated  tallow 

alkylammonium  chloride No  ENJ. 

Methyl,  bis-(2-hydroxyethyl) 

isodecyloxypropylammonium  chloride   No  ENJ. 

Methyl,  bis-(2-hydroxyethyl) 

isotridecyloxypropylammonium  chloride No  ENJ. 

Methyl,  bis-(2-hydroxyethyl)  soyaalkylammonium 

chloride No  ENJ. 

Methyl-ditallowimidazolinium  methosulfate    No  SVC. 

Methyl(hydrogenated  tallow  alkyl)diethyiamine 

condensate, polyethoxylated,  methyl  sulfate No  SVC. 

1-Methyl-2-nor-tallow-1-(2-tallowamidoethyl)- 

imidazoliniummethyl  sulfate   No  SHX. 

N-Methyl-N-polyoxyethylene-N,N-bis(hydrogenated 

tallow  amidoethyl)ammonium No  SHX. 

N-Methyl-N-polyoxyGthylene-N,N-bis(tallow 

amidoethyl) No  SHX. 

Methyltallowdiethylenetriamine  condensate, 

polyethoxylated, methyl  sulfate  No  SVC. 

Methyltallowdiethylenetriamine  condensate, 

polypropoxylated,  methyl  sulfate No  SVC. 

Mixed  alkyl  imidazoline  derivative,  ethoxyiated   No  MOA. 

Mlxed(coco  and  soya  fatty  acids),  reaction  products 

with  chloromethane  and  diethyienetriamine, 

ethoxyiated,  quaternized No  ENJ. 

Mixed  tatty  acid  amide  with  diethylene 

triamine/ethyl  sulfate No  EFH. 

N-Octadecyl-N,N-di(2-hydroxyethyl)-N-methylammonium 

chloride No  SHX. 

All  other  oxygen-containing  quaternary  ammonium 

salts  (Except  those  having  amide  linkages)  No  ARC,  ETC,  SBC.  SCP,  SDC,  SHX  SVC 

Polyethoxy  methylstearyl  ammonium  chloride No  WTC. 

Poly(oxyethanyl,  2-diyl)-di-[2-[2-bis(2-aminoethyl)- 

methylamiumethyl]- No  SVC. 

Polypropoxy  diethylmethyl  ammonium  chloride No  WTC. 

1  -Propanaminium,  N-ethyl-N,N-dimethyl-3-[(1  - 

oxooctadecyljamino]-,  ethyl  sulfate No  SBC. 

Soya  fatty  acids,  reaction  products  with 

chloromethame  and  diethyienetriamine,  ethoxyiated, 

quaternized No  ENJ. 

Soya  fatty  acids,  reaction  products  with 

chloromethane  and  diethyienetriamine, 

propoxylated,  quaternized No  ENJ. 

Stearamidopropyldimethylceterylammonium  tosylate 

and  propylene  glycol No  VND. 

Stearylamidopropyl  dimethyl  myristyl  acetate 

ammonium  chloride    No  VND. 

Tallow  amine,  ethoxyiated,  quarternary  ammonium 

salt   No  DUP.  VND. 

See  footnotes  at  end  of  table. 
12-24 


Syniheiic  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistics ' 


Manufacturers' ider)tificatior)  codes 
(according  to  list  in  table  12-3) 


Cationic-Continued 
Amines,  not  containing  oxygen  (and  salts  thereof) 
-Continued 
Secondary  and  tertiary  monoamines-Continued 

N-l^ethylbis(hydrogenated  tallow  alkyl)aminG    No 

N-Methyldioctadecylamine No 

Tri(hydrogenated  tallow)  amine    No 

Tnisodecylamine No 

Trilaurylamine No 

Tri(mixed  alkyl)amine   No 

Trioctylamine No 

All  other  secondary  and  tertiary  monoamines No 

Oxygen-containing  quaternary  ammonium  salts: 
p-Alanine-N-(2-hydroxyGthyl)-N-  2  1- 

oxococoyl  amino  ethyl,  sodium  salt    No 

2-{C,3-C,7  Alkyl)-1-(C1-,8amidoGthyl)(4,5-dimydro- 
3-methyl)lmidazolinlum,  methyl  sulfate No 

(2-Aminoethyl)ethyl(hydrogenated  tallow  alkyl)(2- 

hydroxyethyl)ammonium  ethyl  sulfate No 

Benzyl(coconut  oil  alkyl)bis(2-hydroxyethyl)- 

ammonium  chloride    No 

1  -Ben2yl-2-heptadecyl-1  -(2-hydroxyethyl)-2- 

imidazolinium  chloride    No 

1  -Benzyl-I  -(2-hydroxyethyl)-2-nor(tall  oil  alkyl)-2- 

imidazoline   No 

Benzyl(tallow  alkyl)bis(2-hydroxyethyl)ammonium 

chloride No 

Bis(N-amidopropyl)-N,N-dimethyl-N-ethylammonium 

ethyl  sulfate,  dimer  acid    No 

Bis(N,N1-ethyl(stearic/arachidic/behenic)amide)- 

cyanoethylethylammonium  ethosulfate  No 

Bis(2-hydroxyethyl,  ethoxylated)- 

methyloctadecylammonium  chloride No 

Bis-2-hydroxyethyl-hydrogenated  tallow-ethyl 

sulfate No 

Bis[2-hydroxyethyl]methyl[tallowalkyl]ammonium 

chloride No 

Bis-2-hydroxyethyl-octyl-methyl-p-toluene  sulfonate  .  .    No 
(Coconut  oil  alkyl)bis(2-hydroxyethyl,  ethoxylated)- 

methylammonium  chloride   No 

Dimethyl  dodecyl  ethyl  ammonium  ether  sulfate   No 

Distearyldimethyl  ammonium  methosulfate   No 

Ethoxylated(hydrogenated  tallow  amine),  methyl 

ammonium  chloride    No 

Ethoxylated,  quaternized(C,2-C,e  alkyl)  oxypropyl 

trimethylene  diamine No 

Ethoxylated,  quaternized  reaction  product  of 

formaldehyde  and  tallow  diamine No 

N-Ethyl-N,N-bis(polyoxyethylene)tallow  ammonium 

ethyl  sulfate No 

1  -Ethyl-2-(8-heptadGcenyl)-1  -(2-hydroxyethyl)-2- 

imidazolinium  ethyl  sulfate   No 

N-Ethyl-N-hexadecylmorpholinium  ethyl  sulfate No 

EthyKpolyoxyethylene,  cocoamine)  ethylsulfate No 

N-Ethyl-N-(soybean  oil  alkyl)morpholinium  ethyl 

sulfate No 

a-Gluconamidopropyl  dimethy-2-hydroxyethyl  ammonium 

chloride No 

(2-Hydroxyethyl)dimethyl(3-stearamidopropyl)- 

ammonium  nitrate No 


ARC.  SHX. 

ARC. 

SHX. 

SCP. 

SCP. 

SHX. 

SCP  SHX 

ARC,  BRD,  ENO.  JTO.  TNA.  WTC. 


SHX. 

DOW,  SVC. 

OC. 

{'). 

HDG. 

{')■ 

DUR 

SBC. 

PCI. 

SHX. 

ICI. 

ARC,  JTO. 
HXL. 

ENJ.  GAR  RDA.  SHX. 

PCI. 

HXL. 

ENJ. 

ENJ. 

ENJ. 

SHX. 

ICI,  SHX. 
BRD,  ICI. 
S. 

ICI. 
VND. 

ACY 


See  footnotes  at  end  of  table. 


12-23 


Sec  lion  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 

Separate      Manufacturers'  identification  codes 
Surface-active  agents  statistics '      (according  to  list  in  table  12-3) 

Cationic-Continued 
Oxygen-containing  quaternary  ammonium  salts-Continued 

Hydroxyethyl-2-undecyl-2,3-lmidazoline No  MOA. 

N-2-hydroxy  propyl-n-methyl-N,n-bis[tallow  amide 

ethyl]  ammonium  ethyl  sulfate    No  SHX. 

Imidazolinium,  1-carboxymethyl)-4.5-dlhydro-1- 

(hydroxyethyl)-2-nor(c»coalkyl),  hydroxides, 

monosodium  salts No  SHX. 

Isostearamidopropyldimethylaminoglycolate No  SBC. 

(3-Lauramidopropyl)trimethylammonium  methyl  sulfate    N  ACY. 

2-(2-Lauroyloxyethyl)carbamoyl-1-methylpyridinium 

chloride No  ENJ. 

Methyl,  bis-(2-hydroxyethyl)  hydrogenated  tallow 

alkylammonium  chloride No  ENJ. 

t/lethyl,  bis-(2-hydroxyethyl) 

isodecyloxypropylammonium  chloride   No  ENJ. 

Methyl,  bis-(2-hydroxyethyl) 

isotridecyloxypropylammonium  chloride No  ENJ. 

Methyl,  bis-(2-hydroxyethyl)  soyaalkylammonium 

chloride No  EKi. 

Methyl-ditallowimidazolinium  methosulfate    No  SVC. 

Methyl(hydrogenated  tallow  alkyl)diethyiamine 

condensate.polyethoxylated,  methyl  sulfate No  SVC. 

1  -Methyl-2-nor-tallow-1  -[2-tallow  amidoethyl]- 

imidazoliniummethyl  sulfate   No  SHX. 

N-Methyl-N-polyoxyethylene-N,N-bis(hydrogenated 

tallow  amidoethyl)ammonium No  SHX. 

N-Methyl-N-polyoxyethylene-N,N-bis(tallow 

amidoethyl) No  SHX. 

Methyltallowdiethylenetriamine  condensate, 

polyethoxylated. methyl  sulfate  No  SVC. 

Methyltallowdiethylenetriamine  condensate, 

polypropoxylated,  methyl  sulfate No  SVC. 

Mixed  alkyl  imidazoline  derivative,  ethoxylated   No  MOA. 

Mixed(coco  and  soya  fatty  acids),  reaction  products 

with  chloromethane  and  diethylenetriamine, 

ethoxylated,  quaternized No  ENJ. 

Mixed  fatty  acid  amide  with  diethylene 

triamine/ethyl  sulfate No  EFH. 

N-Octadecyl-N,N-di(2-hydroxyethyl)-N-methylammonium 

chloride No  SHX. 

All  other  oxygen-containing  quaternary  ammonium 

salts  (Except  those  having  amide  linkages)  No  ARC,  ETC,  SBC,  SCP,  SDC,  SHX.  SVC, 


WTC. 


Polyethoxy  methylstearyl  ammonium  chloride No 

Poly(oxyethanyl,  2-diyl)-di-[2-[2-bis(2-aminoethyl)- 

methylamiumethyl]- No  SVC. 

Polypropoxy  diethylmethyl  ammonium  chloride No  WTC. 

1  -Propanaminium,  N-ethyl-N,N-dimethyl-3-[(1  - 

oxooctadecyl)amino]-,  ethyl  sulfate No  SBC. 

Soya  fatty  acids,  reaction  products  with 

chloromethame  and  diethylenetriamine,  ethoxylated, 

quaternized No  ENJ. 

Soya  fatty  acids,  reaction  products  with 

chloromethane  and  diethylenetriamine, 

propoxylated,  quaternized No  ENJ. 

Stearamidopropyldimelhylceterylammonium  tosylate 

and  propylene  glycol No  VND. 

Stearylamidopropyl  dimethyl  myristyl  acetate 

ammonium  chloride    No  VND. 

Tallow  amine,  ethoxylated,  quarlernary  ammonium 

salt   No  DUP,  VND. 


See  footnotes  at  end  of  table. 


12-24 


Synthetic  Organic  Chemicals.  1990 


Table  12-2 — Continued 

Surtace-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate       Manufacturers '  identification  codes 
statistics '      (according  to  list  in  table  12-3) 


Cationlc-Continued 
Oxygen-containing  quaternary  ammonium  salts 
•Continued 

All  other  quaternary  ammonium  salts  having 

amide  linkages  No 

Quaternary  ammonium  salts,  not  containing  oxygen: 
Acyclic: 

Bis(coconut  oil  alkyl)dimethylammonium  chloride  Yes 
Bisjhydrogenated  tallow  alkyl)dimethylammonium 

chloride  Yes 

Bis(hydrogenated  tallow  alkyl)- 

dimethylammoniummethyl  sulfate No 

Bis(tallow  alkyl)dimethylammonium  chloride    No 

N-(Cocoamidopropyl,N,N-acetic  acid)  ammonium  salt  No 

Cocodimethyl  ethyl  ammonium  ethyl  sulfate No 

N-[(Goconut  oil  alkyl)amino]butyric  acid,  sodium 

salt Yes 

Didecyldimethylammonium  chloride No 

Dimethyldi(Ci2-C,8)ammonium  chloride  (mixed 

straight  and  branched  chains) No 

Dimethyldiocladecylammoniumchoride No 

N,N-Dioctyl-N,N-dimethyl  ammonium  chloride No 

Dodecyltrimethylammonium  bromide No 

Dodecyltrimethylammonium  chloride   No 

Ethyldimethyl(mixed  alkyl)ammonium  ethyl  sulfate    .  No 

Hexadecyltnmethylammonlum  bromide  No 

Hexadecyltrimethylammonium  chloride    Yes 

Hexane-1 ,6-bis(tribulylammonium  bromide) No 

(Hydrogenated  tallow  alkyl)trimethylammonium 

chloride  No 

Lauryl  pyridinium  chloride No 

Methyl  (tri-hydrogenated  tallow  alkyl)  ammonium 

chloride No 

Methyl  tri(C9-C,o)ammonium  chloride No 

Methyltrioctylammonium  chloride No 

(Mixed  alkyl)ammonium  chloride    No 

Octyl  decyl  dimethyl  ammonium  chbride No 

N,N.N'.N',N'-Pentamethyl-N-(tallowalkyl)- 

trimethylene-bis(ammonium  chloride] No 

Stearyl  pyridium  chloride    No 

Trihydrogenated  tallow  ammonium  chloride Yes 

Trimethyloctadecylammonium  chloride No 

Trimethyl(soybean  oil  alkyljammonium  chloride  ...  No 

Trimelhyl(tallow  alkyljammonium  chloride    No 

All  other  quaternary  ammonium  salts,  not 

containing  oxygen  acyclic No 

Benzenoid: 

Benzyl(alkylpyridinium)chloride    No 

Ben2yl(cocoamidopropyl)dimethyl  ammonium  chloride  No 
Benzyl(coconut  oil  alkyl)dimethylammonium 

chloride  Yes 

Benzyldimethyl(mixed  alkyljammonium  chloride   .    .  Yes 

Benzyldimethyloctadecylammonium  chloride Yes 

Benzyldimethyloleylammonium  chloride No 

BenzyldimeIhyl(tallow  alkyljammonium  chloride    ...  No 

Benzyldimethyltetradecylammonium  chloride No 

Benzyldodecyldimethylammonium  chloride   No 

Benzylhexadecyldimethylammonium  chloride    No 

Benzyl(hydrogenated  tallow  alkyljdimethylammonium 

chloride  Yes 


BRD,  ENJ. 

ARC,  ENJ,  JTO,  PPG,  SHX. 

ARC,  END,  SHX,  WTC. 

ARC,  SHX. 
ARC,  SHX. 

SHX. 

ARC,  JTO.  PPG.  SHX. 
HNT  SHX. 

SHX. 

ARC,  SHX. 

HNT 

RSA. 

ARC,  BRD,  SHX. 

DEX. 

ARC. 

ARC,  BRD.  SHX. 

HXL 

ARC,  SHX. 
WTC. 

WTC. 

SHX. 

SCP 

MIL. 

HNT 

ARC,  SHX. 

WTC. 

END. 

SHX. 

ARC,  JTO,  SHX. 

ARC,  ENO,  JTO,  SHX.  WTC. 

ARC,  BRD,  CRD.  MOA,  SHX.  TNA. 

ARC.  ENJ.  ENO.  GDC.  HRT  LUR,  WTC. 

■{')■ 

BRD,  CRD,  HNT  PCI,  SHX,  STR  TCC. 

(').{')■ 
BRD,  PPG,  RDA,  SHX,  TNI. 
RDA. 

BOE,  ENO.  WTC. 
BRD. 
HIP 
BKM. 

ARC,  ENO,  SHX,  WTC. 


See  footnotes  at  end  of  table. 


12-25 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistts ' 


Manufacturers'  identification  codes 
(according  to  list  In  table  12-3) 


Cationic-Continued 
Quaternary  ammonium  salts,  not  containing  oxygen 
-Continued 
Benzenoid-Continued 

Benzyl-methyl-bis(hydrogenated  tailow)ammonium 

chloride No 

Ben2yl(mixed  alkyl)pyridinium  chloride No 

Benzyl  picolinium  chloride    No 

1  -Benzylpyridinium  chloride  No 

Benzyltrimethylammonium  chloride   Yes 

Butyl  picolinium  bromide No 

1-Dodecylpyridinium  chloride No 

(Ethylbenzyl)dimethyl(mixed  alkyl)ammonium 

chloride  No 

Octadecyl-dibenzyltrimethyl-1,3-propane 

diammonium  chloride   No 

All  other  quaternary  ammonium  salts  not 

containing  oxygen  cyclic No 

Other  cationic  surface-active  agents: 

All  other  cationic  surface-active  agents  No 

Nonionic: 

Cartraxylic  acid  amides: 
(amine/acid  ratio  =  2/1): 

Capric  acid  (Ratio  =  2/1 )   No 

Castor  oil  acids  (Ratio  =  2/1 )    No 

Coconut  oil  acids  (Ratio  =  2/1 ) Yes 

Coconut  oil  and  tallow  acids  (Ratio  -  2/1) No 

Lard  oil  acids ,  No 

Laurie  acid  (Ratio  -  2/1 ) No 

Laurie  and  myristic  acids  (Ratio  -  2/1 ) Yes 

Linoleic  acid  (Ratio  =  2/1 )    No 

Mixed  cartwxylic  acids   No 

Mixed  fatty  acids,  neutralized No 

Oleic  acid  (Ratio  -  2/1 )   Yes 

Pelargonic  acid  (Ratio  =  2/1) No 

Stearic  acid  (Ratio  =  2/1 ) No 

Tall  oil  acids  (Ratio  =  2/1 ) Yes 

Tallow  acids  (Ratio  =  2/1 )    No 

All  other  diethanolamine  condensates 

(Ratio  =  2/1 )  No 

Other  amine/acid  ratios: 

Capric  acid  (Ratio  -  1/1)   No 

Coconut  oil  acids  (Ratio  =  1/1) Yes 

Laurie  acid  (Ratio  •=  1  /I ) Yes 

Laurie  and  myristic  acid  (Ratio  -  1/1)    Yes 

Linoleic  acid  (Ratio  •=  1  /I )    No 

Mixed  carboxylic  acids No 

Mixed  fatty  acids  (  Ratio  «  1/1)    No 

Myristic  acid  (Ratio  =  1/1)    No 

Oleic  acid  (Ratio  =1/1)    Yes 

Palm  kernel  oil  acids  (Ratio  -  1/1)   No 

Rapeseed  acids  (Ratio  =1/1) No 

Soybean  oil  acids  (Ratio  =1/1)  No 

Stearic  acid   (Ratio  =1/1) Yes 


ENO. 

er 

GDC.  LUR. 

PCI. 

HIP  RSA,  SHX,  TCC,  UTC. 

HXL 

CCL.  DAN. 

BRD,  HNT  STP 

GDC. 

ARC.  BRD.  CRT  RDA,  WTC,  (^). 

BRD.  BRI,  CGY  CRT  DUP  JTO.  LUR, 
MOA.  PPG.  RDA.  S.  SCP  WM,  WTC. 


SCP 

NSC.  RDA. 

ARD,  ARL.  BRI.  CCC.  CON,  CRT  CTL, 
EFH.  ETC.  HNT  HRT  LEA.  LUR.  MCP 
MOA.  MRV.  PNX.  PPG.  RDA,  SBC, 
SCP  SHX,  VKR.  WPG,  WTC. 

ENJ,  MOA,  SBC,  UNN. 

PER. 

CRD.  MOA. 

CRD.  FTX.  MOA.  SBC. 

MOA. 

FER.  SOS. 

FTX. 

CRT  CTL.  EFH.  MOA.  RDA. 

MIL. 

AiP  OC.  RDA. 

BRI.  ECC.  MOA.  PNX.  PPG,  SBC,  WVA. 

EFH,  ICI,  MOA. 

LUR,  MOA,  RDA,  SHX. 

MOA. 

ARD,  BRD,  CCL,  CPC,  CTL,  EMK,  ESS. 

ETC.  FTX.  HNT  HTN.  JRG.  MIL.  MOA. 

PIL.  RDA.  SBC.  SCP  SHX.  VND.  WTC. 

{')■ 
FTX.  MOA,  RDA,  SBC.  SHX.  TNI.  WTC. 
BRD.  HTN.  MOA.  RDA.  SBC. 
MOA.  SBC.  VND. 
SOS.  WTC 
RDA.  WTC 
MOA. 

BRD,  RDA,  SBC. 
SVC.  TMH. 
EFH. 

MOA.  RDA.  SBC. 
ECC.  ENJ.  ETC,  Hip  LEA.  MRV  RDA. 


See  footnotes  at  end  of  table. 


12-26 


Synthetic  Organic  Chemicals.  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 

Separate       Manufacturers '  identification  codes 

Surface-active  agents  statistics '      (according  to  list  in  table  12-3) 

Nonionlc-Continued 
Carboxylic  acid  amides-Continued 
Other  amine/acid  ratios-Continued 

Tall  oil  acids   No  ESS,  WTO.  (\ 

Tallow  acids    No  MOA. 

All  other  diethanolamine  condensates, 

(Ratio  =  1/1)    No  BRD,  MOA. 

All  other  carboxylic  acid  amides; 

All  other  alkanolamine  condensates No  SOP,  ('). 

All  other  carboxylic  acid  -  alkanolanfiine 

condensates  No  SOP. 

All  other  carboxylic  acid-diamine  and  polyamine 

condensate  No  JTO. 

Coconut  oil  acids    No  NES. 

Coconut  oil  acids  (Ratio  =1/1) No  FIX,  MOA,  RDA.  STP 

Coconut  oil  acids  (Ratio  =  2/1 ) No  ENJ,  HTN.  MOA,  SCR 

Coconut  oil  acids    No  MOA,  PAT,  PPG. 

Coconut  oil  acids-dimethylaminopropylamine 

condensate  (Ratio  =  1/1) No  (^). 

Coconut  oil  acids-ethanolamine  condensate, 

ethoxylated  No  SVC. 

All  other  diethanolamine  condensate  No  EFH,  RDA,  SCP,  SHX. 

Dioleic  acid  (Ratio  -  1/2) No  (^). 

All  other  ethanolamine  condensates No  LUR. 

All  other  ethanolamine  condensates, 

(Ratio -1/1)    No  BRD. 

Ethanolamine  condensates  (Ratio  -2/1)   No  SHX. 

Hydrogenated  tallow  amides,  ethoxylated    No  PCI. 

Hydrogenated  tallow  glycerides  diethylenediamine 

condensate  No  LEA. 

Hydrogenated  tallow  glycerides  diethylenetriamine 

condensate No  HRT. 

Isonanoic  acid,  mono-  and  triethanolamine  salt  ....  No  HCL. 

All  other  isopropanolamine  condensates   No  SBC,  VND. 

Isostearic  acid,  aminoethylethanolamide,  acetate 

salt No  PCI. 

Laurie  acid    No  HTN,  MOA. 

Laurie  acid  (Ratio  -  1/1) No  RDA. 

Laurie  and  myristic  acids    No  RDA. 

Laurie  and  myristic  acids  (Ratio  -  1/1) No  MOA,  STP. 

Mixed  fatty  acids,  diethanolamine  condensate No  WTC. 

Oleic  acid-ethanolamine  condensate,  ethoxylated  . .  No  ETC. 

Ricinoleic  acid No  RDA. 

Stearic  acid  (Ratio  -  1/1 ) No  MOA,  RDA. 

Stearic  acid  (Ratio  -  2/1 ) No  ECC. 

Stearic  acid  aminoethanolamine  (Ratio  -  1.0/1.65  . .  No  CHP. 
Stearic  acid  aminoethylethanolamine 

(Ratio  -  1/2)    No  VKR. 

Stearic  acid-N-aminoethyl  ethanolamine  condensate  No  BOE. 
Stearic  acid-ethylenediamine  condensate 

(Ratio -1/2)    No  SLC. 

Stearic  acid  monoethanolamme  condensate   No  VND,  WTC. 

Tall  oil  acids-dimethylamine  condensate 

(Ratio -1/1)    No  BKM. 

Tall  oil  fatly  acids  (Ratio  -  1/2)  No  EFH. 

Tall  oil  fatty  acids  (Ratio -2.7/1) No  EFH. 

Talloilfany  acids  (Ratio- 1.5/1) No  EFH. 

Tall  oil  fatty  acids-tnethanolamme  condensate  No  (^). 

See  footnotes  at  end  of  table. 


12-27 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 

statistics ' 


Mariufacturers' identification  codes 
(according  to  list  in  table  12-3) 


Nonionic-Continued 
Carboxylic  acid  amides-Continued 
All  other  carboxylic  acid  amides-Continued 

Tallow  acids  (amime/acid  ratio- 1.00/1. 65) No 

Tallow,  n-  3-(dimethylamino)propyi  (Ratio  =  1/3)    .  .  .  No 

All  other  artioxylic  acid  amides No 

Carboxylic  acid  esters: 

Anhydrosorbitol  esters: 

Anhydrosorbitol  dioleate No 

Anhydrosorbitol  monoester  of  tall  oil  acids No 

Anhydrosorbitol  monolaurate   Yes 

Anhydrosorbitol  mono-oleate   Yes 

Anhydrosorbitol  monopalmitate    No 

Anhydrosorbitol  monostearate  Yes 

Anhydrosorbitol  sesquioleate   No 

Anhydrosorbitol  tnester  of  tall  oil  acids No 

Anhydrosorbitol  trioleate No 

Anhydrosorbitol  tristearate  No 

All  other  anhydrosorbitol  esters    No 

Oiethylene  glycol  esters: 

Diethylene  glycol  monoester  of  tall  oil  acids No 

Diethylene  glycol  monoester  of  tallow  acids No 

Diethylene  glycol  monolaurate  Yes 

Diethylene  glycol  mono-oleate  No 

Diethylene  glycol  monostearate  No 

Diethylene  glycol  sesquiester  of  tall  oil  acids  No 

Diethylene  glycol  terephthalate No 

All  other  diethylene  glycol  esters    No 

Ethoxylated  anhydrosorbitol  esters: 

Ethoxylated  anhydrosorbitol  monolaurate Yes 

Ethoxylated  anhydrosorbitol  mono-oleate Yes 

Ethoxylated  anhydrosorbitol  monopalmitate No 

Ethoxylated  anhydrosorbitol  monostearate Yes 

Ethoxylated  anhydrosorbitol  triester  of  tall  oil 

acids   No 

Ethoxylated  anhydrosorbitol  trioleate  No 

Ethoxylated  anhydrosorbitol  tristearate Yes 

All  other  ethoxylated  anhydrosorbitol  esters No 

Ethoxylated  sorbitol  esters: 

Ethoxylated  sorbitol  beeswax  ester    No 

Ethoxylated  sorbitol  hexaester  of  tall  oil  acids    No 

Ethoxylated  sorbitol  hexaoleate   No 

Ethoxylated  sorbitol  lanolin  ester   No 

Ethoxylated  sorbitol  mono-oleate  No 

Ethoxylated  sorbitol  monostearate No 

Ethoxylated  sorbitol  oleate,  acetylated No 

Ethoxylated  sorbitol  tetraester  of  lauric  and 

oleic  acids No 

Ethoxylated  sorbitol  tetraester  of  tall  oil  acids No 

Ethoxylated  sorbitol  tetraoleate No 

Ethoxylated  sorbitol  tetrastearate No 

Ethylene  glycol  esters: 

Ethylene  glycol  distearate Yes 

Ethylene  glycol  mono-oleate No 

Ethylene  glycol  monostearate Yes 

Ethylene  glycol  sesquistearate No 


PAT 
PAT 
CGY 


ICI. 

HDG. 

BRD.  HDG.  ICI.  PPG. 

BRD.  HDG.  ICi,  PPG.  SCP 

BRD.  ICI.  PPG. 

BRD.  HDG.  ICI.  PPG. 

BRD,  HDG. 

BRD.  (2). 

BRD.  HDG.  ICI.  PPG. 

BRD.  PPG. 

BRD.  PG. 

BKM. 

ENJ. 

BRD.  CTL.  ECC.  HDG.  PPG. 

BRD.  SCP  SHX. 

BRD.  ECC.  HDG.  RDA. 

ECC.  WVA. 

UPF. 

{')■ 

BRD.  ETC.  HDG.  ICI.  PPG.  SVC. 
BRD,  ETC.  HDG.  ICI,  PPG.  SVC. 
HDG.  ICI.  PPG. 
BRD.  ETC.  HDG.  ICI.  PPG. 

WTC. 

ETC,  HDG,  ICI,  PPG. 

BRD.  HDG.  ICI.  PPG. 

BRD. 

ICI. 

PPG. 

ICI. 

ICI. 

CPC.  ICI. 

CPC. 

ICI. 

ICI. 

(^)- 
ICI. 
ICI. 

BRD.  ENJ.  HDG.  ICI.  PPG.  RDA.  STP, 

WM,  WTC. 
EFH. 
BRD.  HDG.  PPG,  RDA,  SCP  STP.  VND. 

WtWi.  WTC. 
JTO. 


See  footnotes  at  end  of  table. 


12-28 


Synthetic  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate       Manufacturers'  identification  codes 
statistics '      (according  to  list  in  table  12-3) 


Nonlonic-Continued 
Carboxylic  acid  esters-Continued 

Glycerol  esters: 
Complex  glycerol  esters: 

Glycerol  diacetyltarlrate  monostearate No 

Glycerol  mono-  and  diesters  of  mixed  fatty 

acids    No 

Glycerol  monoester  of  mixed  fatty  acids, 

acetylated    No 

Glycerol  monoester  of  mixed  fatty  acids, 

succinylated No 

All  other  complex  glycerol  esters    No 

Glycerol  esters  of  chemically  defined  acids: 

Glycerol  dilaurate    Yes 

Glycerol  monolaurate   No 

Glycerol  mono-oleate   Yes 

Glycerol  monoricinoleate No 

Glycerol  monostearate   Yes 

Glycerol  trioctanoate/decanoate No 

All  other  glycerol  esters  of  chemically  defined 

acids   No 

Glycerol  esters  of  mixed  acids: 

Glycerol  diester  of  lard  acids No 

Glycerol  monoester  of  Ce-Cio  acids    No 

Glycerol  monoester  of  cottonseed  oil  acids No 

Glycerol  monoester  of  hydrogenated  cottonseed 

oil  acids  No 

Glycerol  monoester  of  hydrogenated  lard  acids  .  .  No 
Glycerol  monoester  of  hydrogenated  soybean  oil 

acids    No 

Glycerol  monoester  of  lard  acids No 

Glycerol  monoester  of  palm  oil  acids    No 

Glycerol  monoester  of  safflower  oil  acids No 

Glycerol  monoester  of  tall  oil  acids No 

Glycerol  monoester  of  tallow  acids No 

Glycerol  sesquiester  of  hydrogenated  tallow 

acids   No 

Glycerol  triester  of  mixed  fatty  acids No 

All  other  glycerol  esters  of  mixed  acids No 

Natural  fats  and  oils,  ethoxylated: 

Castor  oil,  ethoxylated    Yes 

Coconut  oil,  ethoxylated   No 

Hydrogenated  castor  oil.  ethoxylated   Yes 

Lanolin,  ethoxylated    Yes 

Mixed  fatty  acids,  alkyl  ether,  ethoxylated No 

Mixed  tall  oil  and  rosin  acids,  ethoxylated No 

Oleic  acid,  ethoxylated  No 

Oleic  acid,  ethoxylated  and  propoxylated No 

Tall  oil  acids,  ethoxylated    No 

Tall  oil  acids,  ethoxylated  and  propoxylated No 

Tall  oil.  refined,  ethoxylated No 

All  other  natural  fats  and  oils,  ethoxylated    No 

Polyethylene  glycol  esters: 
Polyethylene  glycol  esters  of  chemically  defined 
acids: 

Polyethylene  glycol  dilaurate Yes 

Polyethylene  glycol  dioleate   Yes 


EKT 

ICI. 

EKT. 

EKT. 

BRD,  LEV,  RDA,  SCP 

CAS,  HIP  STP.  VND. 

BRD,  HDG. 

BRD,  EFH,  ETC,  HAL,  HDG,  PPG.  SCP 

STP,  SVC,  WTC. 

BRD.  HDG. 

BRD,  CCC.  CHL,  CPC,  HAL.  HDG,  HRT 

PPG.  SCP  SQA,  STP  VND.  WM,  WTC. 

WM. 

SCP  SVC,  VND,  WTC.  (2)(E). 

BRD.  SVC.  WPG. 

SVC. 

EKT 

EKT  WM. 
EKT 

BFP  EKT 

EKT. 

EKT 

EKT 

EFH.  FER. 

EKT 

PCI. 
SVC. 
BFP  EKT,  ETC. 

CAS,  CPC,  CRD,  ETC,  GAP,  HCL.  ICI. 

MIL,  PPG,  RDA.  S,  SCP  SVC,  TMH. 

WTC,  (2). 
SVC. 

ETC.  ICI.  MIL.  PPG.  RDA.  SCP 
CRD.  HCL.  SVC,  {'). 

{')■ 
HCL. 
TMH. 
MIL. 

HCL,  RDA. 
RDA,  (2). 

{')■ 

BAS,  CRD.  ETC.  HDG,  MIL.  RDA,  SCR 


BRD.  EFH.  ETC.  HDG.  PPG.  STP  WM. 
BRD.  EFH.  HAL.  HDG.  MIL.  OC.  PPG. 
QCP  SCP  SOS.  STP  (2).  (2). 


See  footnotes  at  end  of  table 


12-29 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Sufiace-active  agents 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Nonionic-Continued 
Carbcxylic  acid  esters-Continued 
Polyethylene  glycol  esters-Continued 
Polyethylene  glycol  esters  of  chemically  defined 
aclds-Continued 
Polyethylene  glycol  distearate    Yes 

Polyethylene  glycol  monocaprylate , No 

Polyethylene  glycol  monolaurate   Yes 

Polyethylene  glycol  mono-oleate   Yes 

Polyethylene  glycol  monopalmitate Yes 

Polyethylene  glycol  monopelangonate, 

methoxylated , No 

Polyethylene  glycol  monopelargonate    No 

Polyethylene  glycol  monoricinoleate No 

Polyethylene  glycol  monostearate   Yes 

Polyethylene  glycol  monotallate , No 

Polyethylene  glycol  sesquinoleate   No 

Polyethylene  glycol  terephthalate No 

All  other  polyethylene  glycol  esters  of 

chemically  defined  acids No 

Polyethylene  glycol  esters  of  mixed  acids: 
Polyethylene  glycol  diester  of  coconut  oil 

acids  No 

Polyethylene  glycol  diester  of  coconut  oil  and 

oleic  acids No 

Polyethylene  glycol  diester  of  mixed  liner 

acid/oleic  acid  No 

Polyethylene  glycol  diester  of  tall  oil  acids  Yes 

Polyethylene  glycol  ester  of  mixed  fatty  acids    No 

Polyethylene  glycol  monoester  of  coconut  oil 

acids  No 

Polyethylene  glycol  monoester  of  tall  oil  acids No 

Polyethylene  glycol  (mixed  ester)  of  tall  oil 

acids  No 

Polyethylene  glycol  sesquiester  of  coconut  oil 

acids  No 

Polyethylene  glycol  sesquiester  of  tall  oil 

acids  No 

Polyethylene  glycol  sesquiester  of  tallow  acids   ....  No 
All  otherp  olyethylene  glycol  esters  of 

mixed  acids No 

Polyglycerol  esters: 

Hexaglycerol No 

Mixed  oleic,  lauric,  stearic,  and  palmitic 

hexaglycerol  esters No 

Polyglycerol  distearate No 

Polyglycerol  mono-oleate Yes 

Polyglycerol  monostearate Yes 

Triglycerol  distearate    No 

All  other  polyglycerol  esters No 

Propanediol  esters: 

1 ,2-Propanedioldioctanoate/decanoate No 


BRD,  ETC,  HDG,  HIP,  PPG,  RDA.  SBC. 

STP,  WTC. 
ECC 
BRd!  CCA.  ECC,  EFH.  ENJ.  ETC,  HAL, 

HDG.    ICI,  PPG.  RDA,  STP. 
BOE.  BRD.  CCA.  CRT  ECC,  EFH,  ETC. 

GDC,  HAL.  HCL.  HDG,  MRT  MRV,  OC, 

PPG,  SHX.  STP  SVC.  WTC.  {^). 
BRD.  ETC,  HCL.  ICI.  RDA. 

RDA. 

ETC.  SOS. 

ECC.  S. 

APC.  BRD.  CCC,  CPC,  CRT  EFH,  ETC. 

GDC,  HDG,  HRT  ICI,  LUR,  OC.  PPG. 

RDA.  SCP  STP.  SVC.  VKR.  VND.  {^){E). 

CCC,  PPG. 
SOS. 
BOE,  PCI, 

BRD,  ETC,  HCL. 


PPG. 

EFH. 

PCI. 

ARI,  BRD,  EFH,  ETC,  HIP  LUR,  PAT 

PPG,  OCR  (2). 
SHX,  SOS. 

CRT  ICI,  LUR. 
BKM.  EFH,  FER. 

CRT 

ENJ,  SCP  WPG. 

ICI,  SLI^.  WTC,  C). 
PAT  RDA. 

BRD.  ETC,  LEA,  WPG,  WTC,  (^){E). 

SVC. 

SVC. 

BRD. 

HDG,  PPG.  WTC. 

BRD,  HDG,  PPG,  SVC. 

PPG. 

BRD. 

SVC. 


See  footnotes  at  end  of  table 


12-30 


Synthetic  Organic  Chemicals.  1990 

Table  12-2— Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Sufiace-active  agents 


Separate 
statistics ' 


Manufacturers '  identification  codes 
(according  to  list  in  table  12-3) 


Nonionic-Continued 
Carboxylic  acid  esters-Continued 
Propanediol  esters-Continued 

1 ,2-Propanediol  monolaurate  No 

1 ,2-Propanediol  mono-oleate  No 

1 ,2-Propanediol  monostearate Yes 

Other  carboxylic  acid  esters: 

Di-isobutylene  maleate No 

ethoxylated  1 ,3-butyiene  glycol  condensed  with 
oil  fatly  aciEthoxylated  1,3-butylene  glycol 

stearate No 

Ethoxylated  castor  oil.  ditridecylmaleate No 

Ethoxylated  glycerol  and  propylene  glycol  esters 

of  coco  fatly  acids  No 

Ethoxylated  glycerol  sesquiester  of  mixed  fatty 

acids  No 

Ethoxylated  1 ,2-propanediol  monostearate    No 

Ethoxylated  and  propoxylated  glycerol  mono-  and 

diesters  of  tallow  acids   No 

Linoleic  acid  dimers,  alkoxylated    No 

Maleic  anhydride,  polypropylene  glycol  copolymer .  .  No 

dMethylglucoside  laurate   No 

Mixed  alkyl  benzoate    No 

Mixed  alkyl  stearate    No 

Nonyl  phenol  ethoxylate,  oleate  No 

Pentaerythritol  stearate No 

Polyalkylene  glycol  oleate No 

Polycarboxylic  acid,  alkylate No 

Polycarboxylic  acid,  alkylphenoxyalkoxylate No 

Polypropylene  glycol  dioleate No 

Propylene  glycol  esters  of  hydrogenated  palm  oil    .  .  No 

All  other  carboxylic  acid  esters No 


Ethers: 
Benzenoid  ethers: 
Alky  Iphenol-formaldehyde  condensates, 

alkoxylated   No 

t-Amylphenol,  ethoxylated    No 

Amylphenol-formaldehyde,  alkoxylated   No 

Bisphenol  A.  ethoxlated  and  propoxylated No 

Bisphenol  A,  ethoxylated   No 

P-ten-Butylphenol-formaldehyde,  alkoxylated   No 

Dinonylphenol,  ethoxylated    Yes 

Dodecylphenol,  ethoxylated Yes 

Epichlorohydrin  bisphenol  A,  ethoxylated No 

Iso-octylphenol,  ethoxylated Yes 

(Mixed  alkyl)phenol  epichlorohydrin-formaldehyde, 

alkoxylated   No 

(Mixed  alkyl)phenol,  ethoxylated    No 

(Mixed  alkyl)phenol,  ethoxylated,  butyl  ether No 

(Mixed  alkyl)phenol-formaldehydG,  alkoxylated  Yes 

Naphthalene  sulfonic  acid,  polymer  with 

formaldehyde,  sodium  salt    No 

B-Naphthol,  ethoxylated No 

Naphthalene  sulfonic  acid,  polymer  with 

formaldehyde  and  4,4-dihydroxydiphenyl  sulfone, 

ammonium  salt No 


SBC,  STP 

EFH. 

BRD.  EKT,  HAL,  PPG,  SBC,  STP,  WM. 

RH. 


HCL. 
UPF. 

SVC. 

SHX. 
ICI. 

SVC. 

{')■ 

PCI. 

HDG,  PPG. 

APC. 

SOS. 

EFH. 

BRD,  PPG. 

SOS. 

0- 

PG,  VND. 

ARI,  BRD,  ETC,  HDG,  MOA.  PPG.  OOP. 
SVC.  SYL.  WM.  (2),  (2)(E). 


ETC,  {% 

('). 
PPG. 
PPG,  RDA. 

ei 

CPC.  ETC.  GAF.  HTN.  PPG.  RDA.  RH.  S. 
GAF.  MON,  RDA.  SCP,  TMH, 

e). 

BAS.  GAF.  PPG.  RDA.  RH,  TMH. 

{% 

MIL 

RH 

ENJ,  HCL,  WTC,  (2),  (^). 

PCi. 
BAS. 


PCI. 


See  footnotes  at  end  of  table 


12-31 


Section  12 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate       Manufacturers '  identification  codes 
statistics '      (according  to  list  in  table  12-3) 


Nonionic-Continued 
Ethers-Continued 
Benzenoid  ethers-Continued 

Nonylphenol,  ethoxylated   Yes 

Nonylphenol,  ethoxylated,  phosphate  esters    No 

Nonylphenol,  ethoxylated  and  propoxylated Yes 

Nonyl  phenol,  ethoxylated  with  mixed  fatty  acids  ...  No 

Nonylphenol-formaldehyde,  alkoxylated Yes 

Nonyl  phenol  oleate,  ethoxylated   No 

nonylphenoxy  ethoxycocoate   No 

Nonylphenoxypoly(ethyleneoxy)ethyl  iodide No 

n-Octylphenol,  ethoxylated No 

tert-Octylphenol-lormaldehyde,  ethoxylated No 

Phenol,  ethoxylated    Yes 

Phenol-formaldehyde  resin  (with  lignite) No 

Phenol,  propoxylated    No 

p-Phenylphenol,  all^oxylated No 

p-Phenylphenol,  ethoxylated  and  propoxylated    ....  No 

Phenylstyrene,  ethoxylated No 

Xylenol,  ethoxylated    No 

All  other  phenols,  ethoxylated No 

Nonbenzenoid  ethers: 
Linear  alcohols,  alkoxylated: 

Butyl  alcohol,  propoxylated No 

Decyl  alcohol,  ethoxylated Yes 

Decyloxypoly(ethyleneoxy)ethyl  chloride    No 

Dodecyl  alcohol,  ethoxylated Yes 

Glycerol,  ethoxylated No 

Hexadecyl  alcohol,  ethoxylated Yes 

Hexadecyl  alcohol,  propoxylated No 

N-Hexyl  alcohol,  ethoxylated No 

Isostearyl  alcohol,  ethoxylated    No 

Methyl  alcohol,  alkoxylated No 

9-Octadecenyl  alcohol,  ethoxylated    Yes 

Octadecyl  alcohol,  ethoxylated   No 

Oleyl  alcohol,  ethoxylated Yes 

Stearyl  alcohol,  propoxylated    No 

All  other  chemically  defined  linear  alcohol, 

alkoxylated No 

Coconut  oil  alcohol,  ethoxylated No 

Decyl  and  octyl  alcohols,  ethoxylated No 

Decyl  and  octyl  alcohols,  ethoxylated  and 

propoxylated   No 

Mixed  linear  alcohols,  alkoxylated    No 

Mixed  linear  alcohols,  ethoxylated    Yes 


Mixed  linear  alcohols,  ethoxylated.  t>enzyl  ether    .  .  No 
Mixed  linear  alcohols,  ethoxylated  and 

propoxylated   Yes 

Myristyl  alcohol,  propoxylated No 

Stearyl  alcohol,  propoxylated   No 

Tallow  alcohol,  ethoxylated No 

Wool  wax  alcohols,  ethoxylated    No 

All  other  mixed  linear  alcohols,  alkoxylated    No 

Other  ethers  and  thioethers 


BAS,  BRD,  CPC,  DUP  ENJ,  ETC,  GAP, 
HCL,  HDG,  HTN,  ICI,  MIL,  MOA,  MON, 
CMC,  PPG,  RDA,  RH,  S,  SCR  STP 
TMH,  TX,  UCC,  WPG,  WTC,  {^),  (^). 

CMC. 

RDA,  RH,  SCP  STP  TMH,  WTC.  (^). 

SOS. 

RDA,  WTC,  (2),  (2). 

SOS. 

AMU. 

RDA. 

SCP  WTC. 

SDW. 

ETC,  GAP,  ICI.  MIL,  PPG,  RDA,  SCR 

PSP 

RH. 

BAS. 

RDA. 

HCL. 

RDA. 

ETC,  GAP,  RDA,  SCR  (^){E). 


WTC. 

BAS,  CPC,  ENJ,  GAR  HCL,  ICI,  S. 

GAR  RDA. 

BRD,  ENJ,  HCL,  HDG,  ICI,  MIL,  PPG,  {% 

RDA. 

BRD,  ICI,  RDA,  SVC. 

PPG. 

RDA. 

SHX. 

ei 

ETC,  GAR  ICI,  RDA,  S. 

GAR  HTN,  ICI,  PPG,  SCP 

CPC,  CRD,  HCL,  PPG,  RDA,  SHX. 

SVC. 

CRD,  GAR  HDG,  RDA,  SCP 
ETC,  GAR  HCL,  RDA,  TX. 
GAR  MIL,  SHX,  STP 

PPG. 

WTC,  (2). 

BAS,  DUR  ENJ,  GAR  HCL,  HDG,  ICI,  MIL, 
MOA,  RDA.  RH,  S,  SCR  SHC,  SHX, 
STR  TMH,  TNA,  TX,  UCC,  VST  WTC, 


{')■ 


a 


BAS,  DUR  ENJ,  ETC,  GAR  MIL,  OMC, 
PPG,  RDA,  S,  SCR  SHX.  STR  SVC, 
UCC,  (2). 

WTC. 

WTC. 

ENJ,  ETC,  HCL,  PPG,  RDA,  TX. 

CRD. 

ETC,  RDA,  RH,  SHC. 


See  footnotes  at  end  o(  table. 


12-32 


Synthenc  Organic  Chemicals,  1990 

Table  12-2 — Continued 

Surface-active  agents  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified  by 

manufacturer,  1990 


Surface-active  agents 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  12-3) 


Nonlonic-Continued 
Ethers-Continued 
Other  ethers  and  thioethers-Contlnued 

Bis-cumylphenyl-oxoethylenetitanate    No 

1,3-Butylene  glycol,  ethoxylated No 

terl-Dodecyl  mercaptan,  ethoxylated No 

Glucose,  ethoxylated    No 

Glycerine,  alkoxylated No 

Glycerol,  alkoxylated,  toluene  diisocyanate 

copolymer No 

Isodecyl  alcohol,  ethoxylated   No 

Iso-octyl  alcohol,  ethoxylated  No 

Lignin,  ethoxylated   No 

Mixed  alcohols,  ethoxylated  Yes 

Poly(epichlorhydrin No 

Polyether  diols    No 

Polyether  triols   No 

Polyethoxylate/polypropoxylate  dibenzyi  ether No 

Polyethylene  glycol  mono(nonylphenol)ether 

ammonium  sulfate No 

Polyethylene  glycol,  propoxylated No 

Poly(mixed  ethylene,  propylene)glycol Yes 

Poly(mixed  ethylene/propylene  glycol)  capped  with 

alkyl  oxirone    No 

Poly(oxy- 1 ,2-ethanediy  l),a-phenylmethyl-70- 

hydroxy,Ci2  C15  alkyl  ethers   No 

Poly(oxy-1,2-ethanediyl),a-phenylmethyl-70- 

hydroxy,  ethoxylated  nonylphenol  alkyl  ether  No 
Polypropylene  glycol,  alkoxylated,  polymer  with 

maleic  anhydride,  acrylic  acid,  and  alkylphenol- 

formaldehyde  resin,  alkoxylated  No 

Polypropylene  glycol,  ethoxylated No 

Polypropylene  glycol  glycerol  triether,  copolymer 

with  epichlorhydin  bisphenol  epoxy  resin   No 

2,4,7,9-Tetramethyl-5-decyne-4,7-diol, 

ethoxylated   No 

Thiodiglycol  ethoxylated No 

Tridecyl  alcohol,  ethoxylated No 

Tridecyl  alcohol,  propoxylated  and  ethoxylated  No 

Trimethylnonyl  alcohol,  ethoxylated    No 

Trimethylolpropane,  alkoxylated Yes 

All  other  ethers  and  thioethers  No 

Other  nonionic  surface-active  agents: 

Cumyl  phenolate  isopropoxy  titanium  salt   No 

Formaldehyde,  dicyandiamide,  ethylene  sulfate 

polymers No 

(Mixed  alkyOphenol  alkylenediaminealkanolamine 

formaldehyde   No 

Tetra-(2,2-diallyloxymethylene)-1  -butoxy  titanium 

bis-(ditridecyl)  phosphite No 

Tetra-isopropoxy  titanium  (bis  dioctyl)  phosphite  No 

Tetra  octyloxy  titanium  (bis-tndecyl  phosphite)  No 

All  other  nonionic  surlace-active  agents No 


KPI. 
HCL. 

ETC,  RDA. 
RDA. 


(')■ 

ETC,  PPG. 

ETC. 

WVA. 

ENJ,  MIL,  S,  (2). 

(=). 

WTC, 

WTC. 

{')■ 

{')■ 

RDA. 

ETC,  UCC,  WTC,  (\  ('). 

(2). 

PCI. 

PCI. 


BAS.  ETC,  HCL,  HDG,  PPG,  RDA,  SCP, 
WTC,(2). 

{')■ 

SCP 

RDA. 

BAS.  CPC,  DUP  ETC,  GAP,  HCL.  ICI.  MIL. 

OMC.  PPG.  RDA.  S.  WTC,  {^). 

ETC,  HTN,  PPG,  TX. 

UCC. 

BAS,  ETC,  RDA,  WTC. 

BAS,  ETC,  HCL,  OMC,  RDA,  RH,  SCP,  {'). 


KPI. 
PCI. 

{')■ 

KPI. 
KPI. 
KPI. 
BAS,  BRD,  BRI,  CGY  CLU,  CRT  DUR  ICI, 

KPI,  LUR,  MIL.  MOA,  PG,  RDA,  SCP 

SVC. 


'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'y^s.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  no.' 

'  The  manufacturer  did  not  consent  to  his  identrficatksn  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  US  International  Trade  Commission. 


12-33 


Section  12 

Table  12-3 

Surface-active  agents:  Directory  of  manufacturers,  aiphabetical  by  code,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


ACT Climax  Perlormance  Materials  Corp. 

ACY American  Cyanamid  Co. 

AGP Dial  Corp. 

AIR Air  Products  &  Chemicals,  Inc. 

AMU RPM  American  Emulsion  Co..  Inc. 

APC Apollo  Chemicals  Corp. 

APX Apex  Chemical  Co.,  Inc. 

ARC Akzo  Chemicals,  Inc. 

ARD Ardmore  Chemical  Co..  Inc. 

ARI Atlas  Refinery,  Inc. 

ARL Aroi  Chemical  Products  Co. 

ARP Armour  Pharmaceutical  Co. 

ARZ Arizona  Chemical  Co. 

BAS BASF  Corp. 

BFP American  Ingredients  Company 

BKM Buckman  Laboratories,  Inc. 

BLA Astor  Products,  Inc.,  Blue  Arrow  Div. 

BOE Boehme  Filatex,  Inc. 

BRD Lonza,  Inc. 

BRI Sedgefied  Specialities 

BSW    Original  Bradford  Soap  Works,  Inc. 

CAS CasChem,  Inc. 

CCA Akzo  Chemicals,  Inc. 

CCC C.N.C.  International,  Inc. 

CCL Catawba-Charlab,  Inc. 

CCW   Morton  International,  Inc. 

(Specialty  Chemicals  Group). 

CGY Ciba-Geigy  Corp. 

CHL Chemol  Co. 

CHP C.  H.  Patrick  &  Co.,  Inc. 

CIN    Stockhausen,  Inc. 

CLU CL  Industries,  Inc. 

CMT Chemithon  Corp. 

CON Concord  Chemical  Co.,  Inc. 

CP Colgate-Palmolive  Co. 

CPC Grant  Industries,  Inc. 

CRD Croda,  Inc. 

CRT Reilly-Whiteman,  Inc. 

CTL Continental  Chemical  Co. 

DAN Dan  River,  Inc.,  Chemical  Products  Div. 

DEX Dexter  Chemical  Corp. 

DOW   Dow  Chemical  Co. 

DUP E.  I.  duPont  de  Nemours  &  Co..  Inc. 

Chemicals  &  Pigments  Dept. 

ECC Eastern  Color  &  Chemical  Co. 

EFH E.  R  Houghton  &  Co. 

EKT Tennessee  Eastman  Co.  Div. 

EMK Emkay  Chemical,  Inc. 

ENJ   Exxon  Chemical  Americas 

ENO Enenco,  Inc 


ESS Essential  Industries,  Inc. 

ETC Ethox  Chemicals,  Inc. 

FER Ferro  Corp.,  Keil  Chemical  Div. 

FPC Flambeau  Paper  Corp. 

FTX Finetex.  Inc. 

OAF GAF  Chemical  Corp. 

GDC   Gresco  Mfg.,  inc. 

HAL C.  P.  Hall  Co. 

HCL Hoechst  Celanese  Corp.,  Sou-Tex 

Works 

HDG   Hodag  Chemical  Corp. 

HEW Hewitt  Soap  Co.,  Inc. 

HIP   High  Point  Chemical  Corp. 

HMP   W.  R.  Grace  &  Co.,  Hampshire 

Chemicals  Div. 

and  Organic  Chemical  Div. 

HNT Huntington  Laboratories,  Inc. 

HPC    Hercules,  Inc. 

HRT Hart  Products  Corp. 

HTN Heterene  Chemical  Co. 

HXL Hexcel  Corp.,  Hexcel  Chemical 

Products 

ICI ICI  Americas,  Inc.,  Specialty  Chemicals 

Div. 

JLP J.  L.  Prescott  Co. 

JRG Andrew  Jergens  Co. 

JTO Jetco  Chemicals,  Inc. 

KPI    Kenrich  Petrochemicals.  Inc. 

LEA Leatex  Chemical  Co. 

LEV Lever  Brothers  Co. 

LKY Lake  States  Div.  of  Rhinelander  Paper 

Co. 

LUR Reilly  Whiteman,  Inc. 

MAR  Daishowa  Chemicals.  Inc. 

MCP   Moretex  Chemical  Products,  Inc. 

MIL   Milliken  &  Co.,  Milliken  Chemical  Div. 

MOA Mona  Industries,  Inc. 

MON Monsanto  Co. 

MRT   Morton  International,  Inc., 

Morton  Chemical  Div. 

MRV   Marlowe-Van  Loan  Corp. 

NCC   Niacet  Corp. 

NES Ruetgers-Nease  Chemical  Co. 

NMC Namico.  Inc. 

NPR    Safeway  Stores,  Inc. 

NSC    National  Starch  &  Chemical  Corp. 

OC Omega  Chemicals,  Inc. 

OMC Olin  Corp. 

PAT Pat-Chem,  Inc. 

PCI    Piedmont  Chemical  Industries,  Inc. 


See  note  at  end  of  table 


12-34 


Syntheiic  Organic  Chemicals.  1990 


Table  12-3 — Continued 

Surface-active  agents:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  of  company 

STP Stepan  Chemical  Co. 

SVC Capital  City  Products  Co. 

SYL Arizona  Chemical  Co. 

TCC Sybron  Chemicals,  Inc. 

TEN Tennessee  Chemical  Co. 

TMH    Harcros  Chemicals,  Inc. 

TNA Ethyl  Corp. 

TNI    Gillette  Chemical  Co. 

TX     Texaco  Chemical  Co. 

UCC    Union  Carbide  Corp.,  Industrial 

Chemical  Div. 

UDI  Desoto,  Inc. 

UNN    United  Aniline  Co. 

UPF Sloss  Industries 

USR    Uniroyal  Chemical  Co.,  Inc. 

UTC Unitex  Chemical  Corp. 

VKR Virkler  Co. 

VND    Van  Dyk.  Div.  of  Mallinckrodt.  Inc. 

VST Vista  Chemical  Inc. 

WBG Dryden  Oil  Co..  White  and  Bagley  Div. 

WHW Whittemore-Wright  Co.,  Inc. 

WM Inolex  Chemical  Co. 

WPG West  Point-Pepperell,  Inc.,  Grifftex 

Chemical  Co.  Sub. 

WTC  Witco  Chemical  Corp. 

WVA   Westvaco  Corp. 


PEL Pelron  Corp. 

PG Procter  &  Gamble  Co.,  Procter  & 

Gamble  Mfg.  Co. 

PIL Pilot  Chemical  Co. 

PNX Murphy-Phoenix  Co. 

PPG PPG  Industries,  Inc. 

PSP Georgia-Pacific  Corp.,  Bellingham  Div. 

QCP Quaker  Chemical  Corp. 

RAY Rayonier  Chemical  Products,  Inc. 

RDA Rhone-Poulenc,  Inc. 

RH Rohm  &  Haas  Co. 

RPC Colloids,  Inc.,  Lyndal  Div 

RSA R.S.A.  Corp. 

S    Sandoz,  Chemical  Corp.,  Colors  & 

Chemicals  Div 

SBC Scher  Chemicals,  Inc. 

SBP SBS  Products  Inc. 

SCP Henkel  Corp. 

SDC Sandoz  Chemical  Corp. 

SDW    Sterling  Drug,  Inc., 

Sterling  Organics  Div. 

SHC Shell  Oil  Co.,  Shell  Chemical  Co. 

SHX Sherex  Chemical  Co.,  Inc. 

SLC Soluol  Chemical  Co..  Inc. 

SOS SSC  Industries,  Inc. 

SPA Scott  Paper  Co. 

SOA Sequa  Chemicals,  Inc. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


12-35 


Section  13 
Pesticides  and  Related  Products 

Pesticides  and  related  products  include  fungicides, 
herbicides,  insecticides,  rodenucides,  and  related 
prcxlucts  such  as  plant  growth  regulators,  seed 
disinfectants,  soil  conditioners,  soil  fumiganis,  and 
synergists.  The  data  are  given  in  terms  of  100  percent 
active  materials;  they  exclude  such  materials  as 
diluents,  emulsifiers,  and  welling  agents. 

U.S.  production  of  pesticides  and  related  products 
in  1990  amounted  to  557  million  kilograms,  3  percent 
less  than  the  572  million  kilograms  reported  for  1989 
(table  13-1).  Sales  in  1990  were  442  million 
kilograms,  a  decrease  of  4  percent,  as  compared  with 
461  million  kilograms  reported  in  1989;  the  value  of 
sales  was  S4,774  million  in  1990,  compared  with 
S5,203  million  in  1989,  a  decrease  of  8  percent  Data 
for  production  of  pesticides  and  related  products  during 
1986-90  are  shown  in  figure  13-1. 


Synthetic  Organic  Chemicals.  1990 

Production  of  cyclic  pesticides  and  related  products 
amounted  to  361  million  kilograms  in  1990,  1  percent 
less  than  the  366  million  kilograms  produced  in  1989. 
Sales  in  1990  were  280  million  kilograms,  valued  at 
S3367  million,  compared  with  287  million  kilograms, 
valued  at  $3,639  mUUon,  in  1989. 

Production  of  acyclic  pesticides  and  related 
products  in  1990  amounted  to  196  million  kilograms, 
compared  with  206  million  kilograms  reported  for 
1989.  Sales  in  1990  were  161  million  kilograms, 
compared  with  174  million  kilograms  reported  for 
1989;  the  value  of  sales  was  51,407  million  in  1990, 
compared  with  $1,563  million  in  1989. 

Table  1 3-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code. 
These  codes  are  identified  by  company  name  in  table 

13-3. 

Stephen  Wanser 
202-205-3363 


Figure  13-1 

Pesticides  and  related  products:  U.S.  production,  1986-90 


Millions 
of  kilograms 


700- 


600- 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  o)  the  U.S.  International  Trade  Commission. 


13-1 


Section  13 

Table  13-1 

Pesticides  and  related  products:  U.S.  production  and  sales,  1990 


Pesticides  and  related  products 


Sales 


Production         Quantity 


Value 


Average 
Unit 
value ' 


1.000 
kilograms 

Grand  total 556,875 

Cyclic 

Total  361 .202 

Fungicides^   38,564 

Herbicides  and  plant  growth  regulators,  total    260,092 

Phenoxyacetic  acid  derivatives   20,441 

All  other  cyclic  herbicides" 239,651 

insecticides  and  rodenticides,  total  51 ,968 

Chlorinated  Insecticides 1 ,491 

Organophosphorus  Insecticides* 25,462 

All  other  cyclic  insecticides  and  rodenticides® 25,015 

All  other  cyclic  pesticides 10,578 

Acyclic 

Total  195,673 

Fungicides^  5,149 

Herbicides  and  plant  growth  regulators'  56,578 

Insecticides,  rodenticides,  soil  conditioners,  and 

fumigants,  total 122,938 

Organophosphorus  insecticides' 28,622 

N-Methyldithiocarbamic  acid  (Metham) 17,308 

All  other  acyclic  insecticides,  rodenticides.  soil 

conditioners,  and  fumigants'° 77,008 

All  other  acyclic  pesticides 11,008 


1,000 
kilograms 

441.565 


280,112 


32,878 
201.112 


17.642 
183.470 

42.779 


1.404 
19.655 
21.720 

3.343 


161,453 


5,783 
61.223 

83.968 


15,802 
14.563 


53.603 
10.479 


1.000 
dollars 

4.774.345 


3.366.910 


249,780 
2,306.188 


51.343 
2.254.845 


792.426 


12.028 
332.019 
448.379 

18.516 


1 .407.435 


33.611 
886.194 

425.797 


215.286 
19.643 

190.868 
61.833 


Per 
kitogram 

$10.81 


12.02 

7.60 

11.47 

2.91 
12.29 

18.52 

8.57 
16.89 
20.64 

5.54 


8.72 

5.82 

14.47 

5.07 

13.62 
1.35 

3.56 
5.90 


'  Calculated  from  unrounded  figures. 

^  Includes  benomyl,  captan,  chlorothalonil,  DMTT,  foipet,  pipron,  and  others. 

^  Reported  data  were  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 

*  Includes  alachlor.  atrazine,  benefin,  bensulide,  2,4-D  and  other2,4-D  esters  and  salts,  dicamba.  dinitrophenot 
compounds,  diuron,  DNBP,  isopropyl  phenylcarbamates  (IPC  and  CIPC),  maleic  hydrazide,  molinate,  NPA.  picloram, 
prometon,  triazines,  trifluralin,  plant  growth  regulators,  and  others. 

'  Includes  diazinon,  methyl  parathion,  and  other  phosphorothloates  and  phosphorodithioates. 

^  Includes  carbaryl,  chlorinated  Insecticides  (chlordan,  heptachlor,  and  others),  insect  attractants,  DEET  and  other 
insect  repellents,  small  amounts  of  rodenticides,  and  others. 

'  Includes  dithiocarbamates. 

^  Includes  butylate,  EPTC,  methanearsonic  acid  salts,  thiocarbamates,  and  organophosphorus  herbicides,  and 
others. 

^  Includes  acephate,  disuHoton.  ethion.  malathion,  phorate,  and  other  organophosphorus  insecticides. 

'°  Includes,  methyl  bromide,  soil  conditioners  and  fumigants,  small  quantities  of  rodenticides,  and  others. 

Note. — Does  not  include  data  for  the  insect  fumigant,  p-dichlorobenzene,  nor  the  fungicide,  o-phenylphenol.  These 
data  are  included  in  the  section  on  "Cyclic  Intermediates.'  It  also  does  not  include  data  for  the  fungicides, 
dimethyldithiocarbamic  acid,  sodium  salt  and  dimethyldithiocarbamic  acid,  zinc  salt  (i.e.,  ziram).  These  data  are 
included  in  the  section  on  "Rubber-Processing  Chemicals."  The  data  for  ethylene  dibromide,  a  fumigant,  are  Included 
in  the  "Miscellaneous  End-Use  Chemicals  and  Chemical  Products"  section. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


13-2 


Synthetic  Organic  Chemicals,  1990 

Table  13-2 

Pesticides  and  related  products  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate  Mar)ufacturers '  identHicatior)  codes 

statistics '         (accordirig  to  list  in  table  13-3) 

Cyclic: Yes 

Fungicides: Yes 

2.6-Bis(dimethylaminomethyl)cyclohexanone  No  FER. 

2-Bromo-4'-hyclroxyacetophenone No  BKM. 

a-(2-Chlorophenyl)-a-{4-chlorophenyl)-5- 

pyrimidinemethanol No  LIL. 

a-(2-Chlorophenyl)-a-(4-fluorophenyl)-5- 

pyrimidinemethanol No  LIL. 

2.4-Dichloro-6-(o-chloroanilino)-s-tria2ine No  CHG. 

1,4-Dichloro-2,5-dimethoxybenzene  (Chloroneb)  ...  No  CHF. 

Hexahydro-1,3,5-triethyl-s-triazine No  VNC. 

Hexahydro-1,3,5-tri{2-hydroxyethyl)-s-triazine No  (^. 

2-MercaptobGnzothiazole,  sodium  salt No  (^. 

Methyl-1-(butylcarbamoyl)-2-benzimidazolecarbamate 

(Benomyl) No  DUP. 

3-(2-Methylpiperidino)propyl-3,4-dichlorobenzoate 

(Pipron) No  LIL.  USR. 

Naphthenic  acid.copper  salt No  CCA,  MCI,  NOD,  TRO. 

2-n-Octyl-4-isothiazolin-3-one   No  RH. 

Pentachloronitrobenzene  (PCNB)   No  AMV. 

Pentachlorophenol, sodium  salt    No  FRO. 

8-Quinolinol,  copper  salt No  NOD. 

2,4,5,6-Tetrachloroisophthalonitrile No  SDS. 

Tetrahydro-3,5-dimethyl-2H-1,3,5-thiadiazine-2- 

thione  (DMTT)  No  BKM,  MRK,  VCC. 

2-{Thiocyanomethylthio)benzothiazole No  BKM. 

N-Trichloromethylthio-4-cyclohGxene-1,2- 

dicarboximide  (Captan) No  ICI,  VNC. 

All  other  cyclic  fungicides No  CHD,  NOD. 

Herbicides  and  plant  growth  regulators: Yes 

3-Amino-2,5-dichtorobenzoic  acid,  ammonium  salt 

(2,5-Dichloro-3-aminobGnzoic  acid,  ammonium  salt)  .  No  RDA. 

4-Amino-6-(1,1-dimethylethyl)-3-(methylthb)-1,2,4- 

triazin-5-(4H)-one No  CHG,  DUP. 

4-Amino-3,5,6-trichloropicolinic  acid  (Picloram) No  DOW. 

S-benzyl  thiocarbamate  No  ICI. 

4,6-Bis(isopropylamino)-2-methoxy-s-triazine 

(Prometon)  No  CGY. 

2,4-Bis(isopropylamino)-6-(methylthio)-s-triazine 

(Prometryn) No  CGY. 

5-Bromo-3-sec-butyl-6-methyluracil  (Bromacil)   No  DUP. 

2-(sec-Butylamino)-4-ethylamino-6-mGthoxy-s- 

triazine    No  CGY. 

2-(tGn-Butylamino)-4-ethylamino-6-(mGthylthio)-s- 

triazinG    No  CGY. 

3-tGn-Butyl-5<hloro-6-mGthyluracil  No  DUP. 

N-Butyl-N-Gthyl-a,a,a-trilluoro-2,6-dinitro-p- 

toluidine  (Benefin) No  LIL. 

Butyl  2-[4-[[5-(trltluoromGthyl)-2-pyridinyl]oxy]- 

phGnoxyJpropanoatG No  (^). 

1  -(cart>OGthoxy)Gthyl  5-[2-chloro-4-(tri1luoromGthyl) 

phGnoxy)-2-nitrobGnzoatG No  SOC. 

2-Chloro-4,6-bis(Gthylamino)-s-triazinG  (Simazine)   .  .  No  CGY. 

2-Chloro-4.6-bis(isopropylamino)-s-triazinG 

(Propazine) No  CGY. 

2-Chloro-2',6-diGthyl-N-(n-butoxymGthyl)- 

acGtanilidG  (Butachlor)    No  MNA. 


See  footnotGs  at  Gnd  of  table. 


13-3 


Sec  lion  13 

Table  13-2— Continued 

Pesticides  and  related  products  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate         Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  13-3) 

Cyclic-Continued 
Herbicides  and  plant  growth  regulators-Contlnue<l 

2-Chloro-2',6'-diethyl-N-(mGthoxymethyl)acetanilide 

(Alachlor)    No  I^NA. 

2-Chloro-N-ethoxymetliyl-N-(2-ethyl-6-methyiphenyl)- 

acetamide  (Acctochlor) No  MNA. 

2-Chloro-1-(3-ethoxy-4-nitrophenoxy)-4- 

(trifluoromethyl)benzene  (Oxyfluorfen) No  RH. 

2-Chloro-4-(ethylammo)-6-(isopropylamlno)-$- 

triazine  (Atrazine)  No  CGY,  DUP. 

2-[4-Chloro-6-(ethylamino)-s-tria2in-2-ylafnino]-2- 

methylpropionitrile  (Cyanazine)    No  DUP. 

2-Chloro-N-isopropylacetaniiide  (Propachlor) No  MNA. 

2-Chloro-N-[(4-methoxy-6-methyl-1,3,5-triazln-2-yl)- 

aminocartx)nyl]benzenesulfonamide    No  DUP. 

2-{4-Chloro-2-methylphenoxy)propionicacid, 

dimethylamine  sail   No  RIV. 

2-{2-Chlorophenyl)methyl-4,4-dimethyl-3- 

isoxazolinono   No  FMN. 

5-[2-Chloro-4-(trifluoromethyi)phenoxy)-2- 

introk)enzoic  acid,  sodium  salt No  BAS. 

3-Cyclohexyl-6-(dlmethylamino)-1-methyl-1.3,5- 

triazine-2,4-(1  H,3H)-dione   No  DUP. 

3.5-Dibromo-4-hydroxybGnzonitriie  (Bromoxynil)  ....   No  RDA. 

3,6-Dichloro-2-anisic  acid  (Dicamba) No  ZOO. 

2,6-DichlorobGnzonitrile No  USR. 

2-(2,4-Dichlorophenoxy)propionicacid, 

dimethylamine  salt   No  RIV. 

2-(2,4-Dichlorophenoxy)propionicacid,  isooctyl 

ester  No  RIV. 

3-(3,4-Dichlorophenyl)-1,1-dimethylurea(Diuron)  ...   No  DUP. 

3-(3,4-Dichlorophenyl)-1  -methoxy-1  -methylurea 

(Linuron) No  DUP. 

2-(3,4-Dichlorophenyl)-4-methyl-1,2.4- 

oxadiazolidine-3,5-dione  (Methazoie)  No  ZOO. 

1-[-(2,4-Dichlorophenyl)4-propyl-1,3-dioxolan-2- 

ylmethyi]-1H-1,2,4-triazole  No  101. 

3'.4'-Dichloropropionanilide  (Propanil) No  CED,  CYT,  RH. 

3,7-Dichioro-8-quinolinic  Acid No  NES. 

S-(0,0-Diisopropyl  phosphorodithioate)  ester  of  N- 

(a-mercaptoethyl)benzenesulfonamide  (Bensulide)    No  ICI. 

1,1'-Dimethyl-4,4'-bipyridiniumdichloride No  {'). 

Dimethyl-2,3,5,6-tetrachloroterephthalate  (DCPA)   .  .    No  SDS. 

2,6-Dinrtro-N,N-dipropyl  cumidino    No  LIL. 

2-(Ethylamino)-4-(isopropyiamino)-6-(methyithio)-s- 

triazine  (Ametryne) No  CGY. 

Ethyl  2-(4-chloro-6-methoxypyrimidin-2-yi)- 

amino  cartKinyl  amino  sulfonyi  benzoate 

(Chlorimuron  ethyl) No  DUP. 

S-Ethylcyclohexylmethylthiocarbamate  No  ICI. 

S-Ethyl-hexahydro-1  H-azepine-l  -carbothbate 

(Molinate)  No  ICI. 

(-)-5-Ethyl-2-(-4-isopropyl-4-methyl-5-oxo-2- 

imidazolin-2-yicotinlc  acid No  ACY. 

N-[3-(1  -Ethyl-I  •methylpropyl)-5-isoxazolyll-2,6- 

dimethoxybenzamide  (Flexidor)  No  LIL. 

N-(1-Ethylpropyl)-3,4-dimethyl-2,6- 

dinrtrobenzenamine    No  ACY. 

See  footnotes  at  end  of  table. 
13-4 


Synthetic  Organic  Chemicals,  1990 

Table  13-2— Continued 

Pesticides  and  related  products  for  which  U.S.  production  and/or  sales  were  reported,  identified  by 

manufacturer,  1990 

Pesticides  and  relat9d  products  Separate         Manufacturers '  identificatbn  codes 

statistics '         (accordir)g  to  list  ir)  table  13-3) 

Cyclic-Continued 
Herbicides  and  plant  growth  regulators-Continued 

Imazaquin  2-4,5-dihydro-4-methyl-4-(1  -methylethyl)- 

5-0X0-1  hidazol-2-ylquinoline-carboxylic  acid    No  ACY. 

Imazebethbenz  methyl  ester  (cl222,293) No  ACY. 

Isopropyl  N-{3-chlorophenyl)carbamate  (CIPC) No  SOC. 

Methyl  3- No  DUP. 

2-(2-Methyl-4-chlorophenoxy)propionic  acid,  iso- 

odyl  ester No  RIV. 

1-(2-Methylcyclohexyl)-3-phenylurea(Siduron)    No  ADC,  DUP. 

Methyl  2-(4,6-dimethoxypyrimidin-2-yl)- 
amino  carbonyl  amino  sultonyl  methyl  benzoate 

(Bensulfuron)  (Londax) No  DUP 

Methyl  2-[[[[(4,6-dimethyl-2-pyrlmidinyl)amino]- 

carbonyl]amino]sulfonyl]benzoate No  DUP. 

methyl  2(4-methoxy-6-methyl-1 ,3,5-triazin2-yl)- 
amlno  carbonyl  amino  sulfonyl  benzorle 

(Metsulfuron  methyl) No  DUP. 

Methyl  2-[[[[N-(4-methoxy-6-methyl-1 ,3,5-tna2in-2- 

yl)thylamino]carbonyl]amino]sulfonyl]benzoate    ...    No  DUP. 

1-Methyl-3-phenyl-5-[3-(trifluoromethyl)phenyl]- 

4(1H)-pyridone(Fluridone)    No  LIL. 

N-1  -Naphthylphthalamic  acid  (NPA) No  USR. 

Nicotinic  acid.  2-(4-isopropyl-4-methyl-5-oxo-2- 

imidazolin-l) No  ACY. 

7-Oxabicyclo-(2.2.1]-heplane-2,3-dicarboxylicacid, 

disodium  salt  (Endothall) No  PAS. 

Phenoxyacetic  acid  derivatives: Yes 

4-Chloro-2-methylphenoxyaceticacid. 

dimethylamine  salt    No  RIV. 

4-Chloro-2-methylphenoxyacetic  acid,  iso-octyl 

ester   No  RIV. 

2,4-dichlorophenoxyacetic  acid,  esters  and  salts: 

2,4-Dichlorophenoxyacetic  acid  (2.4-D)    No  DOW. 

2,4-Dichlorophenoxyacetic  acid,2-butoxyethyl 

ester No  DOW. 

2,4-Dichlorophenoxyacetic  acid, sec-butyl  ester   .   No  DOW. 

2, 4-Dichlorophenoxyacetic  acid, dimethylamine 

salt No  DOW,  PBI,  RIV 

2.4-Dichlorophenoxyacetic  acid,ethanolamine  and 

isopropanolamine  salts   No  DOW. 

2,4-Dichlorophenoxyacetic  acid, iso-octyl  ester  .  .    No  DOW,  RIV. 

2,4-Dichlorophenoxyacetic  acid, isopropyl  ester   .    No  AMV. 

2,4-Dichlorophenoxyacetic  acid, lithium  salt    ....    No  GTH. 

All  other  2,4-dichlorophenoxyacetic  acid,  esters 

and  salts    No  ICI. 

Plant  growth  regulators:  No 

N-[(Acetylamino)methyl]-2-chloro-N-(2,6- 

dlethylphenyl)acetamide No  MNA. 

2-Chloro-N-(2,6-dinitro-4-(trilluoromethyl)phenyl) 

-N-ethyl-6-fluorobenzenemethanamine No  CGY. 

(i-(4-Chlorophenyl)methyl-a-(1 , 1  -dimethylethyl)-1 , 

2,4-triazole-1  -ethanol    No  (^). 

a-Cyclopropyl-a-(p-methoxyphenyl)-5-pyrimidine 

methanol  (Ancymidol) No  LIL. 

2,3-Dihydro-5,6-dimethyl-1 .4-dithiin-1 ,1 ,4,4- 
tetraoxide    No  NES. 

See  footnotes  at  end  of  table. 

13-5 


Section  13 

Table  13-2 — Continued 

Pesticides  and  related  products  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate  Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  13-3) 

Cyclic-Continued 
Herbicides  and  plant  growth  regulators-Continued 

1 ,2-Dihydro-3,6-pyrida2inedione  (Maleic 
hydrazide)  (MH) No  DRX,  USR. 

1 ,1  -Dimethylpiperidinium  chloride No  BAS. 

N-[2,4-dimethyl-5-[[trifluoromethyl]sulfonyl]- 
amlno]phenyl]acetamlde,  diethanolamine  salt    .  .    No  MMM. 

Gibberellic  acid No  ABB. 

a-(1-methylethyl-x-  4-trifluore-methoxy  phenyl)-5- 

pyrimidinemethanol  (Flurprimidol) No  LIL. 

a,  a,  a-Trifluoro-2,6-dinitro-N,N-dipropyl-p- 

toluidine  (Trifluralin) No  LIL. 

a.a,a-Trifluoro-2,6-dinitro-N-ethyl-N-(2-methyl-2- 

propenyl)-p-toluidine  (Ethylfluralin) No  LIL. 

All  other  cyclic  herbicides     No  DOW,  FRI,  101,  RH,  SOC. 

Insect  attractants  and  repellents: No 

N,N-Diethyltoluamide  (DEET)    No  TNA,  (^). 

All  other  Insect  attractants   No  ('). 

Insecticides: Yes 

Bacillus  thuringiensis   No  ABB,  DUP,  ZOO. 

Bis{pentachloro-2,4-dicyclopentadien-1-yl)   No  ZOO. 

2,3,4,5-5^-Butenylene-tetrahydrofurfural   No  PLC. 

2-{p-tert-Butylphenoxy)cyclonexyl-2-propynyl 

sulfite    No  USR. 

Cyano-3-phenoxyben2yl-cis,  t^ans-3-(2,2- 
dichlorovinyl)-2,2-dlmethylcyclopropane 

carboxylate No  (^). 

Cyano(3-phenoxyphenyl)methyl-4-chloro-a-(1- 

methylethyl)benzeneacetate No  DUP. 

Cyclic  insecticides, all  other No  FMN,  ZOC,  (^). 

N-cyclopropyl-1,3,5-triazine-2,4,6-lriamine    No  CGY. 

Cypermethrin   No  CED,  FMN. 

0,0-DiethylO-{2-diethylamlno-6-methyl-4- 

pyrimidlnyljphosphorothioate   No  ('). 

2,3-Dihydro-2,2-dimethyl-7- 

benzofuranyl[(dibutylamino)thio]methyl  carbamate      No  FMN,  NES. 

2,3-Dihydro-2.2-dimethyl-7-benzofuranyl 

methylcarbamate    No  FMN. 

2,3-dihydroxy-2,2-dimethyl-7-ben2ofuranyl  No  (^). 

5, 6-Dimethyl-2-dimethylamino-4-pyrimidinyl  dimethyl 

carbamate No  FSN. 

Di-n-propylisocinchomeronate No  MGK. 

Distinnaxane,  hexakis(2-methyl-2-phenylpropyl)  ....    No  DUP. 

0-ethyl  S,s-di-sec-butyl  phosphorodithioate  No  FMN. 

Methyl  3-(2,2-dichloroethenyl)-2,2-dimethyl-3<yano- 

3-phenoxyphenylcyclopropanecartx)xylate No  FMN. 

1-Naphthyl  N-methylcarbamate  (Carbaryl) No  RDA. 

3-(Phenoxyphenyl)  methyl-cis,  trans-3-(2,2 

dichloroethenyl)-2,2-dimethyl 

cyclopropanecarboxylate   No  FMN,  (^). 

Tetrahydro-3,5-dimethyl-2(1H)-pyrimidinone[3-[4- 

(tritluoromethyl)phenyl]- 1  -[2-[4-(lrif  luoromethyl) 

phenyl]ethenyll-2-propenylldine]hydrozone   No  ACY. 

Chlorinated  insecticides: Yes 

Heptachloro-tetrahydro-endo-methanoindene 
(Heptachlor)    No  VEL. 

Octachlorohexahydro-4,7-methanoindene 
(Chlordan) No  VEL. 

See  footnotes  at  end  of  table 


13-6 


Synthetic  Organic  Chemicals,  1990 

Table  13-2 — Continued 

Pesticides  and  related  products  (or  which  U.S.  production  and/or  sales  were  reported,  identified  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate         Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  13-3) 

Cyclic-Continued 
Insecticides-Continued 

1 ,1 ,1  -Trichloro-2,2-bis(p-methoxyphenyl)ethane 

(Methoxychlor)    No  CHF. 

All  other  chlorinated  insecticides,  cyclic No  DUP. 

Organophosphorus  insecticides:   Yes 

0-(2-(Diethylamino)-6-methyl  (4-pyrimidinyl)  O.O- 

dimethyl  phosphrothioate No  (*). 

0,0-DiethylO-(2-isopropyl-4-methyl-6-pyrimidinyl) 

phosphorothioate  (Diazinon) No  CGY. 

0,0-Diethyl  0-3,5, 6-trichloro-2-pyridyi 

phosphorothioate    No  DOW. 

0,0-Dimethyl  S-((4-oxo-1 ,2,3-benzotriazin-3(3H)- 

yl)methyl]phosphorodithioate  (Azinphos-methyl)     No  CHG,  DUP. 

N-(Mercaptomethyl)phthalimideS-(0,0- 

dimethylphosphorodithioate) No  ICI. 

0,0'-(Thiodi-4, 1  -pheny  lene)bis(0,0-<Jimethyl 

phosphorothioate  (Temphos) No  ICI. 

All  other  organophosphorus  insecticides,  cyclic,    . .   No  (^. 

Rodenticides: No 

3-{a-Acetonylben2yl)-4-hydroxycoumarin  (Warlarin)  .   No  MOT. 

3-[3-(4'-Bromo[1 , 1  •-biphenyl]-4-yl)-1 .2,3,4- 
tetrahydro-1  -naphthalenyl]-4-hydroxy-2H-1  - 

benzopyran-2-one No  (*). 

2-Diphenylacetyl-1,3-indandione  and  sodium  salt  ...   No  MOT. 

2-lsovaleryl-1,3-indandione   No  MOT. 

2-Pivaloyl-1 ,3-indandione{Pindone) No  MOT. 

All  other  cyclic  pesticides;    Yes 

a-[2-(2-n-Butoxyethoxy)ethoxy]-4.5-methylenedioxy-2- 

propyltoluene(Piperonyl  butoxide)    No  ALP,  TNA. 

N,N-<Jiallyl-2,2-dichloroacetamide    No  ICI. 

N-(2-Ethylhexy  l)bicyclo(2.2. 1  )-5-heptene-2,3- 

dicarljoximide  No  MGK. 

1  -Methyl-3.5,7-tria2a-1  -azonia  tricyclodecane 

chloride No  BKM. 

2.2.5-Trimethyl-3-(dichloroacetyl)-1,3-oxazolidine  . .  .    No  ICI. 

All  other  pesticides  and  related  products,cyciic  No  GTL,  (^. 

Acyclic: Yes 

Fungicides: Yes 

Bis-1,4-bromoacetoxy-2-butene No  VIN. 

Disodiumcyanodithioimidocartxjnate No  BKM. 

n-Dodecylguanidine  acetate  (Dodine) No  ACY,  MRK. 

Methylenebis(thiocyanate)   No  VIN. 

Poly[oxyethylene(dimelhylimino)- 

ethylene(dimethylimino)ethylenedichloride]  ....  No  BKM. 

Dithiocarbamic  acid  fungicides: 

Dimethyldithiocarbamic  acid, manganese  salt No  ALC. 

Dimethyldithiocarbamic  acid, potassium  salt No  BKM. 

Ethylene  bis(dithiocarbamic  acid),disodium  salt 

(Nabam)    No  ALC,  VCC. 

Ethylene  bis(dithiocarbamic  acid),  manganese  salt 

with  zinc  ions No  DUP. 

Hydroxymethyl(methyl)dithiocarbamicacid, 

potassium  salt No  BKM. 

N-Methyldithiocarbamic  acid,  potassium  salt No  BKM. 

All  other  fungicides No  MRK. 


See  footnotes  at  end  of  table 


13-7 


Section  13 

Table  13-2 — Continued 

Pesticides  and  related  products  for  which  U.S.  production  and/or  sales  were  reported,  Identified  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate         Manufacturers '  identification  codas 

statistics '         (according  to  list  in  table  13-3) 

Acyclic: Yes 

Herbicides  and  plant  growth  regulators: Yes 

S-Ethyl  diisobutytthiocarbamate  (Butylate) No  ICI. 

S-Ethyl  dipropylthlocarbamate  (EPIC) No  ICI. 

Methanearsonic  acid.disodium  salt  (DSMA) No  VIN. 

Fungicides: Yes 

Methanearsonic  acid.dodecyl-  and  octyl-  ammonium 

salts    No  VIN. 

Methanearsonic  acid, monosodium  salt  (MSMA)   ....  No  SDS,  VIN. 

N-(Phosphonomethyl)glycine,  isopropylamine  salt ...  No  MNA. 

S-Propyl  butylethylthiocarbamate  (Pebulate) No  ICI. 

S-Propyl  dipropylthlocarbamate  (Vernolate) No  ICI. 

Thiocyanic  acid,  methylene  ester No  BKM. 

Plant  growth  regulators:  No 

6-Benzyledenine  (bap)  No  ABB. 

2-(Chloroethyl)phosphonic  acid    No  RDA. 

N-(Phosphonomethyl)glycine,  sodium  sesqui  salt   .  No  MNA. 

All  other  plant  growth  regulators,  acyclic    No  DOW,  USR. 

Acyclic  herbicides No  DUP.  VIN. 

Insecticides: Yes 

Ethyl  3,7,11-trimethyldodeca-2,4-dienoate No  ZOC.  (^). 

Isopropyl- 1 1  -methoxy-3,7,1 1  -trimethyldodeca-2,4- 

dienoate   No  ZOC.  ('). 

Methyl  N',N'-dimethyl-N-[(methylcarbamoyl)oxy)-1- 

thiooxamidate No  DUP. 

S-Methyl-N-[{methylcarbamoyl)oxy]thioacetimidate 

(Methomyl)  No  DUP  RDA. 

2-Methyl-2-(methylthio)propionaldehydeO- 

(methylcarbamoyl)oxime  (Aldicarb) No  RDA. 

2-propynyl3,7,11-trimethyl-(2e,4e)-dodecadienoate  .  No  ('). 

N,N'-thiobis-(methylimino)carbonyloxy  bis 

ethanimidothiate No  RDA. 

Organophosphorus  insecticides:   Yes 

S-[1,2-Bis(ethoxycart)onyl)ethyl]0,0-dimethyl 

phosphorodithioate  (Malathion) No  ACY. 

2-Carbomethoxy-1  -propen-2-yl  dimethyl 

phosphate No  AMV. 

1 ,2-Dibromo-2,2-dichloroethyl  dimethyl  phosphate 

(Naled)    No  AMV. 

0,0-DiethylS-[(ethylthio)methyl] 

phosphorodithioate  (Phorate) No  ACY. 

3-(Dimethoxyphosphinyloxy)-N,N-dimethyl-cis- 

crotonamide    No  DUP. 

0,S-Dimethylacetylphosphoramidothioate 

(Acephate  No  SOC. 

0,0-Dimethyl-0-2,2-dichlorovinyl  phosphate 

(DDVP)   No  AMV. 

S-[[(  1 , 1  -Dimethylethy  l)thio]methyl]  0,0-diethyl 

phosphorodithioate  (Turbutos)    No  ACY. 

Dimethyl  phosphate  of  3-hydroxy-N-methyl-cis- 

crotonamide    No  DUP. 

0,0,0',0'-Tetraethyl  S,S'-methylene 

bisphosphorodithioate  (Ethion) No  FMN. 

Rodenticides: No 

2-Hydroxyethyl  n-octyl  sulfide No  PLC. 

Sodium  (luoroacetate No  TUL. 

Soil  conditioners:   No 

Polyacryionitrile.hydrolyzed, sodium  salt No  ACY. 

See  footnotes  at  end  ot  table. 
13-8 


Synthetic  Organic  Chemicals,  1990 

Table  13-2 — Continued 

Pesticides  and  related  products  for  which  U.S.  production  and/or  saiss  war*  raportad,  Wantlfiad  by 

manufacturer,  1990 

Pesticides  and  related  products  Separate         Manufacturers '  identification  codes 

statistics '         (according  to  Ust  in  table  13-3) 

Acyclic: 

Soil  fumigants:  No 

1 ,3-Dichloropropene No  DOW. 

0-Ethyl  S,S-dipropyl  phosphorodithioate No  RDA. 

Methyl  bromide  (Bromomethane) No  GTL. 

N-Methyldithiocarbamic  acid.sodium  salt  (Metham) .  .  Yes  BKM,  CED,  ICI. 

Trichloronitromethane  (Chloropicrin)   No  LCP.  NLO,  WCL. 

All  other  soil  fumigants.  etc No  AMV.  MRT. 

All  other  acyclic  pesticides:    Yes 

3-Alkoxy-2-hydroxypropyl  trimethyl  ammonium 

chloride No  (^. 

Ammonium  oxydiethylenebis  (alkly  dimethyl  chloride) 

Alkyl-40%  C,2.  50%  Cu.  10%  Ce No  BKM. 

Bromoacetic  acid   No  VIN. 

N-Cocoalky I- 1.3-propylenediamine  acetate  No  (*). 

2-[(Hydroxymethyl)amino]-2-methylpropanol No  TRO. 

2-(Hydroxymethyl)ethanol    No  TRO. 

3-lodo-2-propynyl  butylcarbamate No  TRO. 

All  other  pesticides  and  related  products,  acyclic No  DOW.  USR.  ZOC. 

1  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  t>y  Vas.'  Chamicais  lor  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  'no.' 

2  The  manufacturer  did  not  consent  to  his  identifcation  with  the  designated  products. 

Source:  Compiled  from  data  received  In  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


13-9 


Section  13 

Table  13-3 

Pesticides  and  related  products:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code  Name  of  company 

ABB Abbott  Laboratories 

ACY American  Cyanamid  Co. 

ADC Anderson  Development  Co. 

ALC AIco  Chemical  Corp. 

ALP  Alpha  Laboratories.  Inc. 

AMV Amvac  Chemical  Corp. 

BAS BASF  Corp. 

BKM Buckman  Laboratories,  Inc. 

CCA Al^zo  Chemicals,  Inc. 

CED Cedar  Chemical  Co. 

CGY Ciba-Geigy  Corp. 

CHD Chemdesign  Corp. 

CHF Kincaid  Enterprises,  Inc. 

CHG Mobay  Chemical  Crop.,  Agricultural 

Chemicals  Div. 

CYT Cumberland  International  Corp. 

DOW  Dow  Chemical  Co. 

DRX Drexel  Chemical  Corp. 

DUP E.I.  duPont  de  Nemours  &  Co.,  Inc. 

Agricultural  Products 

FER Ferro  Corp.,  Bedford  Chemical  Div. 

FMN FMC  Corp.,  Agricultural  Chemical 

Group 

FRI Farmland  Industries,  Inc. 

FRO Vulcan  Materials  Co.,  Chemicals  Div. 

FSN Nor-am  Chemical  Co. 

GTH Guth  Corp. 

GTL Great  Lakes  Chemical  Corp. 

ICI   ICI  Americas,  Inc.,  Agricultural 

Chemicals  Div. 

LCP LCP  Chemicals-Maine 


Code  Name  of  company 

LIL Eli  Lilly  &  Co. 

MCI Mooney  Chemicals,  Inc. 

MGK McLaughlin  Gormley  King  Co. 

MMM Minnesota  Mining  &  Manufacturing  Co. 

MNA  Monsanto  Agricultural  Co. 

MOT Motomco,  Ltd. 

MRK  Merck  &  Co.,  Inc. 

MRT  Morton  International,  Inc.,  Morton 

Chemical  Div. 

NES Ruetgers-Nease  Chemical  Co. 

NLO Niklor  Chemical  Co.,  Inc. 

NOD  Huls  America.  Inc. 

PAS Atochem  North  America,  Inc. 

PBI   PBI-Gordon  Corp. 

PLC Phillips  66  Co. 

RDA   Rhone-Poulenc,  Inc. 

RH Rohm  &  Haas  Co. 

RIV  Riverdale  Chemk:al  Co. 

SDS Fermenta,  ASC  Corp. 

SOC   Chevron  Corp.,  Chevron  Chemical  Co. 

TNA Ethyl  Corp. 

TRO   Troy  Chemical  Corp. 

TUL Tull  Chemical  Co.,  Inc. 

USR   Uniroyal  Chemical  Co.,  Inc. 

VCC   Vinings  Chemical  Co. 

VEL Velsicol  Chemical  Corp. 

VIN   Vineland  Chemical  Co.,  Inc. 

VNC    Vanderbilt  Chemical  Corp. 

WCL  Wright  Corp. 

ZOC   Sandoz  Crop  Protection 


Note — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


13-10 


Synthetic  Organic  Chemicals.  1990 


Section  14 

Miscellaneous  End-Use  Chemicals 

and  Chemical  Products 

This  section  incorporates  those  end-use  groups 
which  are  not  readily  classifiable  within  the  prior  sections 
of  this  report.  Both  cyclic  and  acyclic  chemicals  fall 
within  this  section.  Production  and  sales  of  the  end-use 
chemicals  contained  within  this  section  continue  to 
follow  a  general  increase  since  1986. 

In  1990,  the  production  of  miscellaneous  end-use 
chemicals  amounted  to  14,992  million  kilograms,  an 
increase  of  1 1  percent  from  the  caculaied  1 3,S03  million 
kilograms  of  production  for  1989  (table  14-1). 
Production  of  these  chemicals  steadily  increased 
throughout  1986-90  (figure  14-1).  Sales  in  1990  totaled 
10,737  million  kilograms,  valued  atS9,71 1  million  (table 
14-1).  The  sales  quantity  increased  16  percent  from  that 
of  1989  with  the  value  of  sales  decreasing  by  0.5  percent 
Polymers  for  fibers  and  end  uses  of  luea  collectively 


accounted  for  52  percent  of  the  1 990  production  of  these 
miscellaneous  end-use  chemicals.  The  total  published 
end-uses  for  urea  accounted  for  49  percent  of  the  1990 
sales  quantity  of  these  chemicals. 

Production  of  end-use  chemicals  used  in  the  auto  and 
motor  fuels  market  indicated  continued  upward  trends. 
Production  of  fuel  additives  for  1990  totaled  4,224 
million  kilograms,  an  increase  of  5.9  percent  from  the 
previous  year.  Approximately  95.4  percentof  production 
in  this  category  was  methyl  t-butyl  ether.  The  increase  of 
147  percent  in  reported  production  from  1 987  isdue  to  the 
increasing  demand  for  this  chemical  as  an  octane 
enhancer  as  well  as  adjustments  to  production  data  for 
companies  that  had  failed  legal  reporting  requirements. 

Table  14-2  lists  the  products  reported  in  this  section 
and  indicates  the  manufacturer(s)  of  each  by  code.  These 
codes  are  identified  by  company  name  in  table  14-3. 

David  G.  Michels 
202-205-3352 


Figur*  14-1 

Miscellaneous  End-Use  Chemicals  and  Chemical  Products:  U.S.  production,  1986-90 

Billions 
o1  kilograms 


20. 


is- 


le- 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  US  International  Trade  Commission. 


14-1 


Section  14 


Table  14-1 

Miscellaneous  end-use  chemicals  and  chemical  products:  U.S.  production  and  sales, 


1990 


Miscellaneous  end-use  chemicals  and  chemical  products 


Sales 

Average 
Unit 

Production 

Quantity 

Value 

value ' 

1.000 
kilograms 

1.000 
kilograms 

1.000 
dollars 

Per 
kilogram 

14.992,023 

10,736,749 

9.711.364 

$1.05 

137.248 

101,448 

151,392 

1.49 

2.824 

1.889 

3,473 

1.84 

879 

781 

3,123 

3.95 

45.984 

24,542 

41,837 

1.71 

4.005 

1.230 

2,890 

1.35 

83.556 

73.006 

100,069 

1.37 

5 

3 

435 

145.00 

609 

558 

34,564 

61.94 

19.930 

3.326 

21 ,408 

0 

4.224.660 

1 ,935,600 

1,200,813 

.62 

4.029.748 
194.912 

1 .800,089 
135,511 

826,640 
374,173 

.46 
2.76 

387,172 

343,627 

548,318 

1.60 

4,175 

96,647 

286.350 

3,658 

95,044 

244,925 

7,592 
141,129 
399,597 

2.08 
1.48 
1.63 

3.650 

3,401 

13.192 

3.88 

1,105 
2.545 

1,001 
2,400 

5,476 
7,716 

5.47 
3.88 

8.399 

4,601 

71,312 

15.50 

2.358,523 

1,379,071 

4,817,834 

3.44 

1.090,301 

220,703 

1,047.519 

1.379.071 

4,817,834 

3.49 

Grand  total  

Chelating  agents,  nitnloacids  and  salts,  total  . . . . 

(Ethylenedinitrilo)letraacetic  acid  (EDTA)  .  . . . 
(Ethylenedinitrilo)tetraacetic  acid,  disodium 

salt  

(Ethylenedinitrilo)tetraacetio  acid,  tetrasodium 

salt  

(N-Hydroxyethylethylenedinitrilo)triaceticacid, 

trisodium  salt    

All  other  chelating  agents,  nitriloacids  attd 

salts   

Chemical  indicators 

Chemical  reagents  and  fine  chemicals   

Enzymes: 

Bacterial  amylase 

Other  hydrolytic  enzymes    

Rennin  

Fuel  additives.  totaP   

Methyl  t-butyl  ether**    

All  other  fuel  additives    

Lubricating  oil  and  grease  additives,  total 

Oil  soluble  petroleum  sulfonate,  barium  salt  . . 
Oil  soluble  petroleum  sulfonate,  calcium  salt  . . 
All  other  lubricating  oil  and  grease  additives  . . 

Paint  driers,  naphthenic  acid  salts,  total*' 

Cobalt  naphthenate  

All  other  paint  driers 

Photographic  chemicals 

Polymers  for  fibers,  total* 

Nylon  6  and  6/6"    

Polyacrylonitrile  and  acrylonitrile  copolymers*  . 
All  other  polymers  for  fibers 

See  footnotes  at  end  of  table. 


14-2 


Synthetic  Organic  Chemicals.  1990 


Table  14-1 — Continued 

Miscellaneous  end-use  chemicals  and  chemical  products:  U.S.  production  and  sales,  1990 


Miscellaneous  end-use  chemicals  and  chemical  products      Production 


Sales 


Quantity 


Value 


Average 
Unit 
value ' 


1.000 
kilograms 

Polymers  lor  fibers — Continued 

Polymers,  water  soluble,  total  309,661 

Hydroxethylcellulose   15,456 

Polyacrylic  acid  salts,  total 136,928 

Sodium  ammonium  polyacrylate  and 

copolymers 61 .027 

All  other  polyacrylic  acid  salts 75,901 

All  other  water  soluble  polymers   1 57,277 

Poly-a-olefins   69,427 

Tanning  materials  synthetic 23,215 

Textile  chemicals,  other  than  surface -active 

agents    22,442 

Urea  in  compounds  or  mixtures: 

In  feed  compounds 573,631 

In  liquid  fertilizer 1,1 40,976 

In  solid  fertilizer    3,740,966 

All  other  miscellaneous  end-use  chemicals  and 

chemical  products' 1,991,439 


1.000 
kilograms 


264,719 


115,966 
55,840 


1.000 
dollars 


768,531 


271,433 
121.231 


Per 
kilogram 


$2.90 

{') 

2,34 

2.17 


60,126 

150,202 

2.50 

148,753 

497,098 

2.43 

50,228 

88,246 

1.76 

10,796 

20,239 

1.87 

19,798 

30,314 

1.53 

551.155 

62,441 

.11 

1,037,209 

178,832 

.17 

3,682,092 

499,162 

.14 

1,352,443 

1,181,075 

.87 

'  Calculated  from  unrounded  figures. 

^  Reported  data  were  acceptoo  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 
'  Statistics  exclude  production  and  sales  of  tricresyl  phosphate.  Statistics  on  tricresyl  phosphate  are  given  with  the 
section  on  "Plasticlzers." 

*  The  difference  between  the  production  reported  here  and  that  shown  on  the  Preliminary  Report  on  U.S. 
Production  oi  Selected  Organic  Chemicals  (including  Synthetic  Plastics  and  Resins  Materials.  1989.  results  from  a 
combination  of  incorrect  reporting  by  some  companies,  end-of-year  inventory  adjustment,  and  rounding. 

*  Production  totals  shown  for  this  chemical  include  quarterly  production  data  in  instances  where  companies 
reported  inaccurate  annual  data  or  failed  to  report  annual  data.  Totals  also  include  reporting  by  companies  which 
failed  to  report  on  a  quarterly  basis. 

*  Quantities  are  given  on  the  basis  of  solid  naphthenate. 

'  Statistics  exclude  production  and  sales  of  copper  naphthenate    Statistics  for  copper  naphthenate  are  given  in  the 
section  on  "Pesticides  and  Related  Products." 

*  Quarterly  production  data  for  polyethylene  terephthalate  are  incorrect  reporting    Annual  production  figures 
cannot  be  published  because  disclosure  would  result. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


14-3 


Section  14 

Tablfl14-2 

Miscellaneous  end-use  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  were 

reported,  identified  by  manufacturer,  1990 


Miscellaneous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers '  identification  codes 
(according  to  list  in  table  14-3) 


Amino  acids  and  their  salts: 

N.N-Bis(2,2-acGtamido)glycine   No  PIC. 

Glutamic  acid  hydrochloride No  LEM. 

Glycine  (Aminoacetic  acid),  non-medical No  CHT,  HMP. 

Phenyl  alanine No  NSW. 

Potassium  glutamate No  LEM. 

Methionine  and  its  salts: 

Methionine  (animal  feed  grade) No  DGC. 

Methionine,  hydroxy  analogue,  calcium  salt No  MNA. 

Protein  hydrosylates No  BRS. 

Sarcosine No  HMR 

Serine No  VNC. 

All  other  amino  acids  and  salts,  acyclic No  BRS. 

All  other  amino  acids  and  salts,  cyclic No  AJI. 

Biological  stains: 

Biological  stains No  ALD.  EK. 

Chelating  agents,  nitriloacids  and  salts: 

N-alkyTamine  bismethylenephosphonic  acid    No  DUP,  (^). 

N-alkylaminobismethylene  phosphonic  acid  salts   No  ('). 

(Diethylenetriamine)pentamethylenephosphonicacid  ...  No  MYO,  {^). 
(Diethylenetriamine)pentamethylenephosphonicacid. 

sodium  salt No  MYO. 

(Diethylenetrinitrilo)pentaaceticacid    No  CGY,  DOW,  HMP. 

(Diethylenetrinitrilo)pentaacetic  acid,  pentasodium 

salt  No  CGY.  DOW,  HMP. 

N.N-Dihydroxyethylglycine,  sodium  salt No  HMP. 

Ethanoldiglycine.  disodium  salt   No  HMP. 

(Ethylenedinitrilo)tetraacetic  acid 

(Ethylenediaminetetraacetic  acid)    (EDTA) Yes  CGY,  DOW,  HMP 

(Ethylenedinitrilo)tetraacetic  acid,  calcium  disodium 

salt  No  DAN,  DOW. 

(Ethylenedinitrilo)tetraacetic  acid,  diammonium  salt   ....  No  CGY.  DOW.  HMP. 
(Ethylenedinltrilo)tetraacetic  acid,  disodium  copper 

salt,  dihydrate No  DAN,  DOW.  HMR 

(Ethylenedinitrilo)tetraacetic  acid,  disodium  salt    Yes  CGY,  DOW,  HMP. 

(Ethylenedinitrilo)tetraacetic  acid,  disodium  zinc 

salt,  dihydrate No  CGY,  DOW,  HMP 

(Ethylenedinitrilo)tetraacetic  acid,  magnesium  salt   No  SHC. 

(Ethylenedinitrito)tetraacetic  acid,  manganese  salt  No  CGY,  HMP. 

(Ethylenedinitrilo)tetraacetic  acid,  monoammonium 

ferric  salt No  DOW. 

(Ethylenedinitriio)tetraacetic  acid,  monosodium  iron 

salt  No  CGY.  PER,  HMR 

(Ethylenedinitrib)tetraacetic  acid,  tetraammonium 

salt  No  DOW. 

(Ethylenedinitrilo)tetraacetic  acid,  tetrapotassium 

salt  No  HMR  {'). 

(Ethylenedinitrilo)tetraacetic  acid,  tetrasodium  salt  Yes  CGY,  DOW,  HMP. 

(Ethylenedinitrilo)tetraacetic  acid,  trisodium  salt    No  HMP. 

Glucoheptonic  acid,p-isomer,  sodium  salt No  Bi_Z. 

Glucoheptonic  acid,  sodium  salt    No  BLZ,  PFN. 

Hexamethylenediaminetetra{methylenephosphonicacid). 

potassium  salt    No  MYO. 

Hydroxyethane-1 -diphosphonic  acid  No  MYO. 

(N-Hydroxyethylethylenedinitrilo)  triacetic  acid    No  HMR 

(N-Hydroxyethylethylenedinitrilo)triacetic  acid,  iron 

salt  No  DOW,  HMR 

(N-Hydroxyethylethylenedinltrilo)triaceticacid, 

magnesium  salt    No  DOW. 

(N-Hydroxyethylethylenedinitrilo)triaceticacid, 

trisodium  salt    Yes  CGY  DOW,  HMR 

Hydroxyethylidene  diphosphonic  acid,  potassium  salt  ..  .  No  (^). 


See  footnotes  at  end  of  table. 


14-4 


Synthetic  Organic  Chemicals,  1990 

Table  14-2 — Continued 

Miscellaneous  end-use  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  were 

reported,  Identified  by  manufacturer,  1990 


Miscellaneous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  14-3) 


Chelating  agents,  nitriloacids  and  salts-Continued 

Hydroxyethylidene  diphosphonic  acid,  sodium  salt No 

Nitriloacetic  acid,  zinc  salt   No 

Nitrilotriacetic  acid  No 

Nitrilotriacetic  acid,  trisodium  salt No 

Nitrilo-tris-methylene  triphosphonic  acid    No 

Nitrilo-tris-methylene  triphosphonic  acid,  potas No 

Nitrilo-tris-methylene  triphosphonic  acid,  sodium 

salt  No 

2-Phosphonobutane-1,2,4-tricartx]xylic  acid,  sodium 

sail  No 

Polyamine  polymethane  phosphonic  acid  No 

All  other  chelating  agents,  nitriloacids  and  salts    No 

Chemical  indicators: 

Chemical  indicators  Yes 

Chemical  reagents  and  fine  chemicals: 

Chemical  reagents  and  fine  chemicals    Yes 

Enzymes: 
Hydrolytic  enzymes: 
Amylases: 

Bacterial  amylase Yes 

Glucoamylaso No 

All  other  amylases    No 

Proteases: 

Papain No 

Pepsin No 

Protease  (bacterial)    No 

Rennin Yes 

All  other  proteases   No 

Other  hydrolytic  enzymes: 

Cholesterol  esterase No 

Hydrolytic  enzyme  mixtures   No 

Lipase No 

Pectinase   No 

Other  hydrolytic  enzymes No 

Non-hydrolytic  enzymes: 

Cholesterol  oxidase No 

Glucose  oxidase No 

Glucose-6-phosphate  dehydrogenase No 

Glycerol  kinase    No 

Urease No 

Uricase No 

Flotation  reagents: 
Phosphorodlthioates.  used  as  flotation  reagents: 

Dicresylphosphorodithioic  acid No 

Dicresylphosphorodithioic  acid,  ammonium  salt No 

Dicresylphosphorodithioic  acid,  sodium  salt No 

Rosin  amines No 

Xanthates  and  sulfides,  used  as  flotation  reagent: 

Sodium  n-butylxanthate   No 

All  other  flotation  reagents No 

Fuel  additives: 
Diesel  fuel  additives: 

Hexyl  nitrate No 

All  other  diesel  fuel  additives,  acyclic No 

All  other  diesel  fuel  additives,  cyclic No 

Fuel  oil  additives: 
Adipic  acld-diethylenetnamine-epichlorohydrin 

polymer No 

Di-terl-amyl-phenyl  acid  phosphate  No 


MYO.  (2). 
HMR 

HMP  MON. 
BKM,  HMP 

MYO.  e).  ei 

MYO.  (2). 

BKM.  CGY.  HMP  OMC.  RDA.  ('). 
ALD,  COC,  EK,  GFS.  VNC. 


\  (% 


ALD.  COC.  EK.  ENJ.  GFS.  PAH.  PFN, 
PIC,  PLB.  REG,  RSA,  UPM.  («). 


GBF.  MLS.  NBI.  PMR  RDA. 
GBF.  MLS.  NBI.  RDA. 
GBF.  RDA, 

GBF.  PFZ.  RDA. 

CHH.  PFZ.  RDA. 

NBI. 

CHH.  MLS.  PFZ.  RDA. 

GBF  MLS.  RDA.  SPR. 

BCK. 
JFR. 
RDA. 
GBF 
GBF  PMP  RDA.  (^). 

BCK. 
BCK. 
BCK. 
BCK. 
BCK. 
BCK. 


ACY 
ACY 

{')■ 

ACY  HPC,  SHX. 

USR. 
DAN. 


DUR 
TNA. 
SM. 


ALW. 


See  footnotes  at  end  of  table. 


14-5 


Section  14 


Table  14-2— Continued 

Miscellaneous  end-use  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  were 

reported,  identified  by  manufacturer,  1990 


Miscellaneous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  14-3) 


Fuel  additives-Continued 
Fuel  oil  additives-Continued 

4,4'-Di-sec-butylaminodiphenylmethane   No 

N,N-Dimethyl-1.3-propanediamine  polymer  with 

epichlorohydrin,  sulfate No 

N,N-Disalicylidene-1,2-propanediamine  No 

Imidazoline  from  tall  oil  fatty  acids  and 

diethylenetriamine No 

Polybutylether  carbamate No 

Poly(dimethylimino(2-hydroxytrimethylene)chtoride)  . .  No 
Polyethylenepoiyamine  polymer  vi^ith  1 ,4-dihyroxy-2- 

butyne No 

Rust  preventing  additives No 

Tetrahydropyrimidine  from  tall  oil  fatty  acids  and 

propylenediamine No 

All  other  fuel  additives,  acyclic No 

Gasoline  additivies: 

N,N'-Di-sec-butyl-p-phenylenediamine No 

N,N'-Diisopropyl-p-phenylenediamine  No 

Ethylene  dibromide No 

Methyl-t-butyl  ether Yes 

Methylcyclopentadienylmanganesetricarbonyl   No 

N-{1-Methylheptyl)ethanolamine    No 

Tetraethyl  lead   No 

All  other  gasoline  additives,  acyclic  No 

All  other  gasoline  additives,  cyclic  No 

Lubricating  oil  and  grease  additives: 

Alkyl  imidazoline    No 

Alkyl  succinic  anhydride No 

Alkyl  terephthalamate No 

Bornyl  phenylamine No 

Chlorosulfurizer  and  sulturized  compounds: 

Sutfurized  lard  oil   No 

Sulfurized  sperm  oil  substitutes  No 

Di-2-ethylhexylphosphorodithioicacid  No 

Diisopropyl  hydrogen  phosphite No 

Di-N-propylphosphorodithioic  acid No 

Dodecylphenyl-a-naphthylamine No 

Ethylene-propylene  copolymer No 

Fatty  acid  polyamine  condensate No 

Hydrocarbon  carboxylic  acid  derivatives  (specify) No 

Hydrocartwn  phosphorous  acid,  barium  salt No 

Hydrocarbon  phosphoryl  derivatives  No 

Methylene-bridged  polyalkyi  phenols No 

Oxidized  hydrocarbon  mixture No 

Oil-soluble  petroleum  sulfonates: 

Oil-soluble  petroleum  sulfonate,  barium  salt    Yes 

Oil-soluble  petroleum  sulfonate,  calcium  salt Yes 

Oil-soluble  petroleum  sulfonate,  magnesium  salt No 

Oil-soluble  petroleum  sulfonate,  mixed  salts    No 

Oil-soluble  petroleum  sulfonate,  sodium  salt   No 

All  other  oil-soluble  petroleum  sulfonate No 

Phenol  salts: 

Alkylphenol,  calcium  salt    No 

Alkyl  phenols    No 

Dodecylphenol,  sulfurized,  calcium  salt No 

Nonylphenol,  barium  salt    No 

All  other  phenol  salts    No 


UPM. 

DUP  FER,  SM,  TNA. 

soc. 

(^ 

ALX. 

{')■ 

DUP,  PAH,  Sl^.  UPM. 

TNA.  UPM. 

DUP,  TNA. 

GTL. 

AMO.  ATR.  CGO.  CO,  CSD.  CSP.  DA. 

ENJ.  GRS.  LYP.  MOC.  PLC.  SM.  SOG. 

SUN.  TPC,  TX.  VLR. 
AMO.  TNA. 
UPM. 
DUR 

ATR.  TNA.  TX.  UPM.  (h 
VNC. 

OCR. 

{'). 
SOC. 

soc. 

CCW.  OCR 

CCW,  ELC. 

ELC. 

ALW. 

ELC. 

SM. 

TX. 

SOC. 

FER.  OCR  SCR  {%  (2). 

ei 
{')■ 

TX. 

ALX.  FER,  (*). 

PAR,  TNA.  TX,  WTC,  (h 
PAR,  SOC,  TX,  WTC,  f). 
WTC. 

ei 

PAR,  WTC. 

DUR  MON,  SOC.  TX. 

SOC.  TX. 

SOC,  TX. 

CCA,  FER,  WTC. 

TNA. 


See  footnotes  at  end  of  table. 


14-6 


Synthetic  Organic  Chemicals.  1990 

Table  14-2 — Continued 

Miscellaneous  end-use  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  were 

reported,  identified  by  manufacturer,  1990 


Miscellaneous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  14-3) 


Lubricating  oil  and  grease  additives-Continued 
Phosphorodithloates(dithiophosphates): 

Polyisobutenyl  succinic  anhydride  No 

Succinimides: 

Alkenyl  succinimide    No 

Dodecenyl-aceticsuccinimlde No 

Modified  succinimides No 

All  other  succinimides No 

Sulfur  compounds: 

Aliphatic  hydrocarbon  sulfides   No 

Di-tertiary  nonylpolysutfide No 

All  other  sulfur  compounds No 

1 ,3,4-Thiadiazole,  2,5-bis(dialkyldithio)  derivatives   ...  No 

Trlbutyl  phosphite No 

Trimethylol  prop>ane  ester No 

Very  high  molecular  weight  (>1 000)  hydrocarbons    ...  No 

Zincdialkyldtthiophosphate    No 

Zinc  dialkylphenol  dithiophosphate No 

Zinc  dibutyl  phosphorodithioate  No 

Zinc  hydrocarbon  dithiophosphate No 

All  other  phosphorodithioates  used  as  lubricating 

oil  and  grease  additives   No 

All  other  lubricating  oil  and  grease  additives,  acyclic  . .  No 

All  other  lubricating  oil  and  grease  additives, 

cyclic    No 

Paint  driers,  naphthenic  acid  salts: 

Barium  naphthenate No 

Cadmium  naphthenate No 

Calcium  naphthenate No 

Chromium  naphthenate   No 

Cobalt  naphthenate   Yes 

Iron  naphthenate    No 

Lead  naphthenate No 

Manganese  naphthenate  No 

Naphthenate  driers,  mixed  salts No 

Rare  earths  naphthenate  No 

Zinc  naphthenate  No 

Photographic  chemicals: 
N-2-{4-Amino-N-ethyl-m-toluidino)ethyl  methane- 

sulfonamide    No 

Aryl  alkyl  polyether  ak»hol No 

5-Chlorobenzotria2ole    No 

4-Dia20-2,5-diethoxymorpholinobenzene No 

2,5-Diethoxy-4-morpholinoben2enediazonium  chloride  No 
p-Diethylaminobenzenedia2onium  chtaride  (p-Diazo-N, 

N-diethylaniline  zinc  chtoride) No 

p-DimethylaminobenzenedicLZoniumchbride 

(p-Diazo-N,  N-dimethylaniline  zinc  chloride)    No 

p-[Ethyl(2-hydroxyethyl)aminojbenzenedia2onium 
chloride  KJiazo-n-hydroxyetnylaniline  zinc 

chlorkfe)   No 

(N-Ethyl-N-(2-hydroxyethyl)-3-methyldehydrogen 

sulfate)p-phenylenediamine No 

Hydroquinone     (Hydroquinol)   No 

5-Methyl-1,7-dihydroxy-1,3,4-triazaindoli2ino No 

3-Melhyl-N-[2(methylsutfonamidoethyl)-N-ethyl-p- 

phenylenediamine]  sequisulfate  monohydrate No 

4-Methyl-1-phenyl-3-pyrazolidione No 

p-Morpnolinyl-2,5-dibutoxybenzene  diazonium  chtoride  No 

Phenyl-5-mercaptotetrazole No 


TX. 

SOC,  TNA,  TX.  C). 

SM. 

CXI 

PER,  SM,  (2). 

ELC,  PER,  (2). 

PAS. 

CHD,  PER.  QCP.  TNA.  (\  (% 

ELC. 

ALW. 

QCP.  SCP.  SM. 

{')■ 

ELC.  SOC.  TNA. 

SOC 

ELC. 

(')■ 

ELC,  PER,  (2). 

TX.  ('). 

ALW.  CGY.  DCC.  DUP.  QCP.  SCP.  SM. 

TNA.  TX,  (2). 

ENJ.  PER.  HMY.  SM.  TNA.  C).  (').  {^). 

OCP. 

CCA 

CCa!  MCI,  NOD.  TRO. 

MCI. 

MCI.  NOD.  SHP.  TRO. 

MCI.  NOD. 

CCA,  MCI. 

MCI,  NOD. 

MCI. 

NOD. 

MCI,  NOD,  TRO. 


WAY 
DIX. 
FMT 

All. 
All. 

All. 

All. 


All. 

EKT. 
FMT 

CWN. 

All. 
FMT 


See  footnotes  at  and  of  table. 


14-7 


Section  14 

Tabl«  14-2 — Continued 

Miscallaneous  end-usa  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  wore 

reported,  Identified  by  manufacturer,  1990 


Miscellaneous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers' identification  codes 
(according  to  list  in  table  14-3) 


Photographic  chemicals-Continued 

1-Phenyi-3-pyrazolidone  No 

Poly(vinyl-O-sulfobenzal) No 

4-N-(1-Pyrrolidyl)-m-toluenedia2onium  chloride    No 

All  other  photographic  chemicals No 

Polymers  for  fibers: 

Cellulose  acetate No 

Nylon  6  and  6/6: 

Nybn  6  (Polymer  for  fiber,  only) No 

Nylon  6/6    No 

Polyacrylonitrile  and  acrylonitrile  copolymers    Yes 

Polyethylene  terephthalate No 

Poly-m-phenylene  isophthalamido No 

Poly-p-phenyleneterephthalamide    No 

All  other  polymers  for  fibers No 

Polymers,  water  soluble: 
Acrylamide  polymers  and  co-polymers: 
Acrylamide-2-acrylamido-2-methylpropanesulfonic 

acid,  sodium  salt  polymer No 

Acrylamide-acrylic  acid  copolymer No 

Acrylamide-acrylic  acid  copolymer,  sodium  salt No 

Acrylamide-trimethylaminoethyl  acrylate  chloride 

polymer No 

Acrylamide-trimethylaminoethyl  methacry  late 

chloride No 

Adipic  acid-crosslinked  polycrylamide   No 

Polyacrylamide No 

All  other  polyacrylamide  copolymers   No 

Cellubse  esters  and  ethers: 

Hydroxyethylcellulose No 

Hydroxyethyl  hydroxypropyl  cellulose    No 

2-Hydroxypropyl  cellulose    No 

Methylcellulose No 

Sodium  cartxjxymethylcellulose  (100%) No 

All  other  cellulose  ethers  and  esters No 

Dimethylamine  epichbrohydrin  ethylenediamine 

copolymer No 

Ethyl  acrylate  methacrylic  acid  copolymer No 

Hydroxypropyl  guar  gum   No 

Poly(acrylic  acid,  ethyl  ester) No 

Poly(acrylic  acid,  methyl  ester/ethylene/1,1- 

dichlorosuccinic  acid,  methylene-) No 

Poly(acrylic  acid,  methyl  ester/ethylene/1,1- 
dichlorosuccinic  acid,  methylene-)  with  ethyl 

acrylate No 

Polyacrylic  acid  salts: 

Ammonium  polyacrylate No 

Polyacrylate  methacrylate  copolymers No 

Polyacrylate  poly(hydroxypropylacrylate)  copolymer  . .  No 

Polyacrylic  acid No 

Sodium  ammonium  polyacrylate  and  copolymers   ....  No 

Sodium  carboxymethyl  amylose No 

Sodium  cartxjxymethyl  starch    No 

Sodium  polyacrylate No 

Sodium  polyacrylate,  grafted   No 

All  other  polyacrylic  acid  salts No 

Polyacrylonitrile,  hydrolyzed No 

Polyacrylonitrile,  starch  hydrolized  polymer No 

Polyamines    No 

Polydextrose    No 

Poly(diallyldimethylammoniumchtaride No 


CWN. 

DUP. 

All. 

CHD.  DAN.  DUP.  EK.  FMT.  WAY.  (»).  (*). 

EKT. 

ACS.  BLY.  CNP. 

DUP.  MON. 

ACY.  BKM.  DUP.  MON. 

DUP  EKT.  FRF.  GYR. 

DUP 

DUP 

DUP.  HCL. 


ENJ.  (2). 
CHP 
BKM.  (2). 

(^. 

ACY  BKM.  ENJ,  SCR  (*).  ('). 
ACY  ENJ,  MRK.  {'). 
HCL.  (2). 

AQU.  DOW.  UCC. 

AQU. 

DOW.  UPJ. 
AQU.  CBC.  MAK.  (*). 
AQU.  DIX.  S. 

(^ 

ALC. 
AQU. 
DUP 

DUP 


DUP 

CCL.  RH.  (*),  (2). 
RH.  ('). 

MY0.(^).(2). 

ALC,  BAS.  BFG.  DIX.  RH.  SCP.  {\  (*). 

CCL. 

BKM.  EFH,  MYO.  SYT. 

<'>  ,  , 

BAS.  BFG,  DOW.  ENJ,  (*).  (*). 

BKM,  GPC. 

GPC. 

ENJ,  OCR 

PFZ. 

CPS.  MRK.  (*). 


See  footnotes  at  end  of  table. 


14-8 


Synthetic  Organic  Chemicals,  1990 

Table  14-2 — Continued 

Miscellaneous  end-use  chemicals  and  chemical  products  for  which  U.S.  production  and/or  sales  were 

reported,  Identified  by  manufacturer,  1990 


Miscellanoous  end-use  chemicals 


Separate 
statistics ' 


Manufacturers '  identification  codes 
(according  to  list  in  table  14-3) 


Polymers,  water  soluble — Continued 

Polyethyleneimine  No 

All  other  polymers,  water  soluble No 

Polymethacrylic  acid,  sodium  salt   No 

Poly(1 ,1  '-(methylimino)bis(3-chloro-2-propanol)- 

teetramethylethylenediamine No 

1-Vinyl-2-pyrrolidinone,  copolymers  with  vinyl  acetate    ..  No 

1 -Vinyl-2-pyrrolidinone,  polymers No 

Xanthan  gum  No 

Poly-a-olefins: 

Poly-a-olefins No 

Poly-a-olofins,  suKurized No 

Rare  sugars: 

l-Arabinose No 

D-Galactose No 

D-Maltose No 

Silicone  greases: 

Silicone  greases No 

Tanning  materials,  synthetic: 
1-Naphthalenesulfonic  acid.formaldehyde  condensate 

and  salt No 

2-Naphthalenesul1onic  acid,  formaldehyde  condensate 

and  salt No 

1-Phenol-2-suKonic  acid.formaldehyde  condensate 

(Phenol-formaldehyde, sulfonated) No 

Polyoxyalkylated  cyclic  amines   No 

All  other  tanning  materials,  synthetic No 

Textile  chemicals,  other  than  sudace  active  agents: 

Alkylphenol/formaldehyde  polymer   No 

N,N-bis-(2-Hydroxyethyl)octadecanamide No 

N,N-Dibenzylhydroxylamine No 

Oicyanodiamide  formaldehyde  ammonium  chloride 

polymer No 

Dimethyloldihydroxyethylene  urea No 

Formaldehyde  polymer  with  carbamate  esters    No 

Hydrogenated  tallow  fatty  acid  aminoethylethanolamine 

condensation  products No 

Lauryl  alkyl  dimethylamine  acetate   No 

Lauryl  alkyl  dimethylamine  phosphate No 

Melamine  lormaWehyde  methanol  polymer No 

Melamine  formatoehyde  copolymer No 

Melamine  stearyl  akxshol  polymer   No 

Propoxylated  starches No 

2.2',4,4'-Tetrahydroxybenzophenone No 

Tri(behenoyloxymethyl)trimethoxymethylmelamine No 

Urea  polymers  with  formaldehyde  and  methanol No 

Textile  chemicals,  other  than  surface  active  agents No 

Urea,  by  end-use  markets: 
Urea,  primary  solutkin  (Report  on  100%  urea-content 

basis)  Yes 

Urea  in  compounds  or  mixtures  (100%  basis): 

Urea  in  feed  compounds  (100%  basis) Yes 

Urea  in  liquid  fertilizer  (100%  basis)   Yes 

Urea  in  plastics  (100%  basis)   No 

Urea  in  solid  fertilizer  (100%  basis) Yes 


DAN. 

BKM,  DAN,  EFH,  PRA,  RDA,  RH.  SOP. 

SYT,  (2).  e).  e).  n  ('). 

ALC. 

BKM. 
DAN. 

DAN.  GAP. 
PFZ. 

SM,  SOC, 
QCP  SM. 

PFN. 
PFN. 
PFN. 

SPD,  SWS. 


RH,  S. 
GRD. 


BAS,  RH. 

MIL. 

BAS,  SOP 

ei 

ccc. 

COG. 

CCC,  DAN, 

PCI.  S.  SYT. 

ACY  CCC, 

CHP  DAN, 

,SYT. 

SYT. 

CCC. 

Q- 

ei 

ACY  CCC. 

ENJ. 

SYT. 

SYT. 

BAS 

SYT 

ACY  CCC. 

BAS,  CCC, 

DUP  ENJ. 

PAT 

ARM,  BCP  CAC.  CFI,  CHN.  FRI.  GCC, 
HKY  MSC,  SOC.  SOH,  TER.  TRI,  TVA. 
UOC.  WLC,  WYC,  (=»). 

CAC.  HKY  SOH,  TER,  TRI,  WYC. 
CFI,  CHN.  FRI.  HKY  MSC.  SMP  SOC. 

SOH.  TER,  TVA.  UOC. 
BCP  SOH,  TRI. 
BCP  CAC,  CFI.  FRI.  GCC.  HKY  MSC, 

SOH.  TER.  TRI.  TVA.  UOC.  WLC.  WYC. 


'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  'yes.'  Chemicals  for  which 
data  are  accepted  in  confidence  and  may  not  be  published  are  indicated  by  no  ' 

^  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  US   International  Trade  Commission. 


14-9 


Section  14 


Table  14-3 


Miscellaneous  end-use  chemicals  and  chemical  products:  Directory  of  manufacturers,  alphabetical  by  code, 
1990 


Code 


Name  of  company 


Code 


Name  of  company 


ACS Allied  Signal,  Inc.  Engineered 

Materials  Sector 

ACY American  Cyanamid  Co. 

AJI Ajinomoto  USA,  Inc. 

ALC AIco  Chemical  Corp. 

ALD Aldrich  Chemical  Co..  Inc. 

ALL   Alliance  Chemical,  Inc. 

ALW Albright  &  Wilson  Americas,  Inc. 

ALX   Alox  Corp. 

AMO    Amoco  Corp. 

AQU Aqualon 

ARM LaRoche  Industries.  Inc. 

ATR Atlantic  Richfield  Co.,  Arco  Chemical 

Co. 

BAS BASF  Corp. 

BCK Beckman  Instruments.  Inc., 

Diagnostics  System  Group 

BCP Borden  Chemical  &  Plastics  Oolaware 

Limited 

BFG B.  F  Goodrich  Co. 

BKM Buckman  Laboratories,  Inc. 

BLY   Berkley  &  Co.,  Inc. 

BL2   Belzak  Corp. 

BRS Bristol-Myers  Co. 

CAC Cominco  Fertilizers,  Inc. 

CBC Carbose  Corp. 

CCA Akzo  Chemicals.  Inc. 

CCC C.N.C.  International,  Inc. 

CCL Catawba-Charlab,  Inc. 

CCW   Morton  International,  Inc., 

Specialty  Chemicals  Group 

CFI CF  Industries,  Inc. 

CGO    Citgo  Petroleum.  Corp. 

CGY Ciba-Geigy  Corp. 

CHD Chemdesign,  Corp. 

CHH Chris  Hansen's  Laboratory.  Inc. 

CHN Wil-Gro  Fertilizer,  Inc. 

CHP C.  H.  Patrick  &  Co.,  Inc. 

CHT Chattem.  Inc. 

CNP DSM  Chemicals,  North  America 

CO Conoco  Specialty  Products,  Inc. 

COC Columbia  Organic  Chemical  Co.,  Inc. 

CPS CPS  Chemical,  Co.,  Inc. 

CSD Fina  Oil  &  Chemical  Co.,  Cosdan 

Chemical  Div. 

GSR Coastal  Refining  &  Marketing.  Inc. 

CWN    Upjohn  Co.,  Fine  Chemicals 

CXI Chemical  Exchange  Industries.  Inc. 

DA Diamond  Shamrock  Refining  & 

Marketing 


DAN    Dan  River,  Inc.,  Chemical  Products  Div. 

DCC    Dow  Corning  Corp. 

DGC   Degussa  Corp. 

DIX   Dixie  Chemical  Co.,  Inc. 

DOW Dow  Chemical  Co 

DUP    E.  I.  duPont  de  Nemours  &  Co..  Inc. 

Chemicals  and  Pigments  Dept. 

ED/IMG  Dept. 

Fibers  Dept. 

EFH E.F  Houghton  Co. 

EK     Eastman  Kodak  Co.: 

EKT Tennessee  Eastman  Co.  Div. 

ELC EIco  Corp.  Sub.  of  Detrex  Chemical 

Industries,  Inc. 

ENJ Exxon  Chemical  Americas 

FER FerroCorp.: 

Bedford  Chemical  Div. 

Keil  Chemical  Div. 

FMT Fairmount  Chemical  Co.,  Inc. 

FRF Firestone  Tire  &  Rubber  Co.,  Firestone 

Fibers  &  Textiles  Co. 

FRI   Farmland  Industries,  Inc. 

GAF GAF  Chemical  Corp. 

GBF International  Bio-Synthetics,  Inc. 

GCC Arcadian  Corp. 

GFS GFS  Chemicals,  Inc. 

GPC    Grain  Processing  Corp. 

GRD   W.  R.  Grace  &  Co.,  Organic  Chemicals 

Div. 

Polymers  &  Chemical  Div. 

GRS   Champlin  Refining  Co. 

GTL Great  Lakes  Chemical  Corp. 

GYR   Goodyear  Tire  &  Rubber  Co. 

HCL Hoechst  Celanese  Corp: 

Fibers  Industrial  Div. 

Sou-Tex  Works. 

HKY Arcadian  Corp. 

HMP    W.  R.  Grace  &  Co.,  Organic  Chemicals 

Div. 

Hampshire  Chemical  Div. 

HMY  Humphrey  Chemical  Co. 

HPC    Hercules,  Inc. 

JFR George  A.  Jeffreys  &  Co.,  Inc. 

LEM Napp  Chemicals,  Inc. 

LYP Lyondell  Petrochemical  Co. 

MAK   MAK  Chemical  Corp. 

MCI Mooney  Chemicals,  Inc. 

MIL    Milliken  &  Co.,  Milliken  Chemical  Div. 


See  note  at  end  of  table 


14-10 


Synthetic  Organic  Chemicals,  1990 

TabI*  14-3 — Continued 

Miscellaneous  end-use  chemicals  and  chemical  products:  Directory  of  manufacturers,  alphabetical  by  code, 

1990 


Code 


Name  of  company 


Code  Name  of  company 

SHX Sherex  Chemical  Co.,  Inc. 

SM Mobil  Oil  Corp.,  Chemical  Product  Div. 

Beaumont  Refinery  Div. 

SMP   J.  R.  Simplot  Co. 

SOC   Chevron  Corp.,  Chevron  Chemical  Co. 

SCX3   Hill  Petroleum  Company 

SOH    BP  Chemicals  Amenca,  Inc. 

SPD General  Electric  Co.,  Silicone  Products 

Div. 

SPR Scientific  Protein  Laboratories 

SUN    Sun  Co..  Inc. 

SWS Wacker  Silicones,  Corp. 

SYT Synthron,  Inc. 

TER Terra  International,  Inc. 

TNA Ethyl  Corp. 

TPC Texas  Petrochemicals  Corp. 

TRI    Triad  Chemical 

TRO    Troy  Chemical  Corp. 

TVA Tennessee  Valley  Authority.  NFDC.  TVA. 

OACD. 

Div.  of  Devebpmental  Production 

TX Texaco,  Inc.,  Texaco  Chemical  Co. 

UCC   Union  Carbide  Corp.,  Industrial 

Chemical  Div. 

UOC  Union  Oil  Co.  of  California 

UPJ Upjohn  Co. 

UPM   UOP  Inc. 

USR    Unlroyal  Chemical  Co.,  Inc. 

VLR Valero  Refining  &  Marketing  Co. 

VNC    Vanderbilt  Chemcal  Corp. 

WAY   Olln  Hunt  Specialty  Products,  Inc. 

WLC   Freeport-McMoran  Resource  Partners 

WTC Witco  Chemical  Corp. 

WYC Coastal  Chem.  Inc. 


MLS Miles  Laboratories.  Inc..  Biotechnology 

Group. 

MNA Monsanto  Agricultural  Co. 

MOC    Marathon  Petroleum  Co.,  Texas 

Refining  Div. 

MON    Monsanto  Co. 

MRK Merck  &  Co..  Inc. 

MSC Mississippi  Chemical  Corp. 

MYO    Mayo  Chemical  Co. 

NBi Novo  Biochemical  industries,  Inc. 

NOD Huls.  America.  Inc. 

NSW   NutraSweet  Co. 

OMC    Olln  Corp. 

PAH Parish  Chemical  Co. 

PAR Pennzoll  Co..  Penreco  Div. 

PAS Atochem  North  America,  Inc. 

PAT   Pat-Chem.  Inc. 

PCI Piedmont  Chemical  industries.  Inc. 

PFN Pfanstlehl  Laboratories,  inc. 

PFZ Pfizer,  inc. 

PIC Pierce  Chemical  Co. 

PLB Pharmacia  P-L  Blochemlcals.  Inc. 

PLC Phillips  66  Co. 

PMP PMP  Fermentatwn  Products.  Inc. 

PRA Para-Chem  Southern,  inc. 

OCP Quaker  Chemkral  Corp. 

ROA Rhone-Poulenc.  Inc. 

REG Regis  Chemical  Co. 

RH Rohm  &  Haas  Co. 

RSA R.S.A.  Corp. 

S   Sandoz  Chemical  Corp.,  Cotors  & 

Chemicals  Div. 

SOP Henkel  Corp. 

SHC Shell  Chemical  Co. 

SHP Shepherd  Chemical  Co. 


Note. — Complete  names,  telephone  numbers,  and  addresses  of  the  above  reporting  companies  are  listed  in  table  1  of 
the  appendix. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


14-I1 


Synthetic  Organic  Chemicals.  1990 


Section  15 

Miscellaneous  Cyclic  and  Acyclic 

Chemicals 

The  lerm  "miscellaneous  chemicals"  as  ii  is  used 
here  comprises  those  synthetic  organic  products  that 
are  not  included  in  the  use  groups  covered  by  sections 
I-XIV  of  this  repon.  They  include  products  that  are 
employed  in  a  great  variety  of  applications.  The 
number  of  chemicals  used  extensively  for  only  one 
purpose  is  not  large.  Among  the  products  covered  in 
this  section  are  those  used  for  refrigerants,  aerosols, 
solvents,  catalysts,  additives  in  plastics  and  food 
products,  and,  especially,  a  wide  range  of  acyclic 
chemical  intermediates. 

Figure  15-1  shows  the  trend  of  production  of 
miscellaneous  chemicals  during  1986-90,  and  shows 
that  the  substantial  rate  of  increase  after  1985, 
contmued  through  1990  albeit  at  a  slower  pace. 

U.S.  production  of  miscellaneous  cyclic  and 
acyclic  chemicals  in  1990  amounted  to  49.9  billion 
kilograms,  an  increase  of  2.1  percent  compared  with 
production  in  1989  (Table  15-1).  Production  of 
miscellaneous  acyclic  chemicals  comprised  96.6 
percent  of  this  section's  total  production. 

Because  most  of  the  production  of  miscellaneous 
chemicals  is  used  iniemally  by  their  producers  to  make 
more  advanced  intermediates  and  other  chemical 
products,  their  sales  are  much  smaller  than  their 
production.  In  1990,  sales  of  miscellaneous  chemicals 
were  21.2  billion  kilograms,  valued  at  S14.5  billion, 
compared  with  20.2  billion  kilograms,  valued  at  S16.3 
billion,  in  1989.  The  increase  in  sales  quantity  in  1990 
was  13  percent.  However,  the  surge  in  prices  through 
1989  was  sharply  reversed.  The  average  unit  value  of 
sales  in  1990,  68.4  cents  per  kilogram,  was  15  percent 
less  than  the  previous  year's  80.6  cents  per  kilogram. 
This  reflected  the  effects  of  the  recession  as  well  as  a 
changing  production  mix,  overcapacity  for  a  number  of 
chemicals,  and  a  lower  cost  of  raw  materials. 
Oxygenated  hydrocarbons  accounted  for  about  60 
percent  of  the  production  of  all  acyclic  miscellaneous 


chemicals.  Production  of  oxygenated  hydrocarbons, 
which  include  organic  acids,  alcohols  (the  largest 
group),  ketones,  esters,  ethers,  aldehydes,  epoxides, 
and  other  chemicals,  was  28.7  billion  kilograms  in 
1990,  a  marginal  decrease  from  the  28.8  billion 
kilograms  produced  in  1989. 

SlighUy  larger  in  volume  than  the  alcohols  in 
miscellaneous  acyclic  chemicals  is  the  chlorinated 
hydrocarbons  group.  Production  of  chlorinated 
hydrocarbons  was  about  13.2  billion  kilograms  in 
1990,  about  0.5  billion  kilograms  more  than  in  1989. 
While  many  of  these  chemicals  suffer  the  opprobrium 
of  the  environmental  cause,  only  chloroform  and 
perchlorethylene  (among  the  publishable  items)  lost 
ground  in  production  in  1990  (down  more  than  20 
percent  from  1989).  The  remainder  (carbon 
tetrachloride,  methylene  chloride,  ethyl  chloride, 
ethylene  dichloride,  1,1,1,-irichloroethane,  and  vinyl 
chloride)  held  their  own.  Production  of  methyl 
chloride  was  67  percent  greater  than  in  1989. 

The  second  largest  category  in  the  miscellaneous 
chemicals  groups  is  alcohols-boih  monohydric  and 
polyhydric.  Though  production  of  ethylene  glycol  and 
other  polyhydric  alcohols  decreased  about  8  percent  in 
1990,  that  of  the  monohydric  alcohols  increased  very 
slightly,  to  almost  7  billion  kilograms. 

Virtually  in  a  tie  for  third  place  among 
miscellaneous  acyclic  chemicals,  each  with  production 
between  4.5  and  4.9  billion  kilograms  in  1990,  are 
nitrogenous  compounds,  acids/anhydrides,  and 
aldehydes.  Production  of  all  three  groups  increased  in 
1990,  by  14,  17,  and  12  percent,  respectively. 
Noteworthy  for  increased  production  in  1990  were 
ethanolamines,  acrylonitrile,  acetic  acid,  butyraldchyde 
and  formaldehyde. 

Table  15-2  lists  the  products  in  this  section 
individually  identified  by  manufacturer(s)  codes.  Table 
15-3  lists  those  codes  alphabetically  and  identifies  the 
manufacturer  by  name. 

Aimison  Jonnard 
202-205-3350 


15-1 


Section  15 

Figure  15-1 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production,  1986-90 


Billons 

of  kilograms 


1986  1987  1988  1989  1990 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


15-2 


Synthetic  Organic  Chemicals.  1990 


Table  15-1 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Production 


Sales 


Quantity 


Value 


Average 

unit 
value' 


Grand  total 

Cyclic 

Total  

Benzoic  acid  esters 

Benzoyl  peroxide 

Butyrolactone 

Tert-butyl  peroxybenzoate 

Caproiactam    

2,6-Di-tert-butyl-p-cresol  (BHT) 

Hexamethylenetetramine,  tech   

Maleic  anhydride 

Morpholine 

Pinene  and  derivatives,  total 

a-Pinene  

B-Pinene    

Pine  oil.  natural,  sulfate  

Pine  oil.  synthetic 

All  other  pinene  and  derivatives 

Succinic  anhydride  derivatives    

Tall  oil,  chemically  modified 

All  other  miscellaneous  cyclic  chemicals 

Acyclic 

Total  

Nitrogenous  compounds 

Total  

Amides,  total   

Erucamide   

N.N'-Ethylenebis-oleamide    

N.N'-Elhylenebis-slearamide 

Oleamide  (Ocladecene  amide) 

All  other  amides 

Amines,  totaP 

Butylamines 

Diethylamine    


1.000 
kilograms 

49.912.377 


1.000 
kilograms 


1.000 
dollars 


Per 
kihgram 


21.196.927        14.491.633      $0.68 


1.700.331 

773.429 

1.484,576 

1.92 

1.683 

e) 

(') 

(') 

4.701 

3.583 

21.903 

57.103 

9.981 

26.246 

2.63 

1.664 

1.623 

7.312 

4.51 

625.729 

1?) 

(') 

(') 

7.067 

e) 

e) 

e) 

41.947 

{') 

(^) 

(') 

192.529 

160.228 

154.647 

.97 

(') 

17.288 

28.749 

1.66 

(?) 

31.218 

36.625 

1.17 

55.194 

(') 

e) 

C) 

20.729 

1?) 

(') 

(') 

2.037 

1.730 

1.303 

.75 

21.073 

19.685 

26.078 

1.32 

e) 

9.803 

9.244 

.94 

18.191 

8,334 

16.999 

2.04 

8.122 

e) 

(') 

{^) 

642.562 

541,174 

1.192.095 

2.16 

48,212.046 

20.423.498 

13.007.057 

4.726.058 

1.814.312 

1.642.158 

138.947 

75.847 

128.571 

.64 


.91 


1.70 


4.616 

3.718 

17.923 

4.82 

218 

(=) 

e) 

<?) 

14.577 

14.505 

20.692 

1.43 

2.768 

2.459 

5.679 

2.31 

116.768 

55.165 

84.277 

1.52 

897.254 

294,665 

438.918 

1.49 

12.949 

12.508 

25.623 

2.05 

9,970 

3.475 

4,406 

1.27 

See  footnotes  at  end  of  table. 


15-3 


Section  15 

Table  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Sales 

Average 
unit 

Production 

Quantity 

Value 

value' 

1.000 
kilograms 

1,000 
kilograms 

1,000 
dollars 

Per 
kihgram 

Acyclic — Continued 

Nitrogenous  compounds — Continued 

Amines — Continued 

Ethylenediamine 

Isopropylamine,  mono-    

Triethylamine 

Trimetliylamine 

All  other  amines 

Ethanolamines,  total   

2,2'-Aminodiethanol  (Oiethanolamine)  . . . 
2-Aminoethanol  (Monoethanolamine)  .... 
2,2',2"-Nitritotriethanol  (Triethanolamine)  . 

3-Methoxypropylamine    

Methyldiethanolamine 

Nitriles.  total 

Acetonitrile 

AcrylonitrJIe    

2-Methyllactonitrile  (Acetone  cyanohydrin) 

All  other  nitriles    

All  other  nitrogenous  compounds   

Acids,  acyl  halides  and  anhydrides 

Total  

Acetic  acid,  synthetic,  100%  

Acrylic  acid* 

Dimer  acid  (Gag  dibasic  acid) 

2-Ethylhexanoyl  chloride 

Fatty  acids 

Fatty  acids,  hydrogenated*   

Fumaric  acid   

NeodecanoyI  chloride   

PivaloyI  chloride 

Propionic  acid   

All  other  acids,  acyl  halides  and  anhydrides  . 
Salts  of  organic  acids 

Total  

Acetic  acid  salts,  total   

Potassium  acetate 

Sodium  acetate   

All  other  acetic  acid  salts 


36.881 

26,070 

46.657 

$1.79 

(') 

26,872 

23.826 

.89 

15.619 

11,894 

14.934 

1.26 

26,367 

19,675 

14.552 

.74 

795,468 

194.171 

308.920 

1.59 

329.936 

230.830 

217.645 

.94 

88,378 

80,976 

70.290 

.87 

150,105 

72,910 

70.487 

.97 

91.453 

76,944 

76.868 

1.00 

2.270 

2,932 

6.226 

2.12 

<?) 

6.401 

20.907 

3.27 

(') 

805,777 

527.994 

.66 

17.863 

(') 

(^) 

(') 

1.213.875 

767,440 

451.173 

.59 

610,453 

1?) 

(') 

(') 

- 

38.337 

76.821 

2.01 

1.515,460 

397.860 

301.897 

.76 

4.912.173 


1.200.816         1.126.617 


.94 


1.701.303 

405.260 

150,138 

.37 

477.759 

125,072 

138,286 

1.11 

16.776 

14.015 

15,557 

1.11 

1.305 

(') 

1?) 

(') 

14.298 

13.946 

8,671 

.62 

155.576 

125.824 

85,656 

.68 

12.268 

16,368 

1.33 

821 

e) 

1?) 

(') 

2.878 

(^) 

(') 

(') 

46.340 

(^) 

{') 

(') 

2.495,117 

504.431 

711,941 

1.41 

238.037 

156.262 

259,843 

1.66 

23.962 

9,930 

19,241 

1.94 

2.535 

2,229 

3.334 

1.50 

19.521 

(') 

(') 

(^) 

1.906 

7,701 

15.907 

2.07 

See  footnotes  at  end  of  table. 


15^ 


Synthetic  Organic  Chemicals,  1990 


Table  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Production 


Sales 


Quantity 


Value 


Average 
unit 
value ' 


Acyclic — Continued 

Aluminum  Octanoate 

2-Ethylhexanoic  acid  (a-Ethylcaproic  acid)  salts, 
total 

Cobalt  2-ethylhexanoate   

Zinc  2-ethylhexanoate  

All  other  2-ethylhexanolc  acid  salts 

Formic  acid  salts  

Laurie  acid  salts 

Oleic  acid  salts    

Oxalic  acid  salts,  total   

Potassium  oxalate  

All  other  oxalic  acid  salts  

Propionic  acid  salts,  total 

Calcium  propionate   

Sodium  propionate 

All  other  propionic  acid  salts   

Stearic  acid  salts,  total* 

Aluminum  stearates,  total 

Aluminum  tristearate    

All  other  aluminum  stearate  salts 

Calcium  stearate   

Magnesium  stearate 

Zinc  stearate    

All  other  stearic  acid  salts    

All  other  salts  of  organic  acids 

Aldehydes 

Total  

n-Butyraldehyde 

Formaldehyde  (37%  by  weight) 

All  other  aldehydes    

Ketones 

Total  

Acetone 

Diacetone  alcohol  (Hydroxymethyl  pentanone)  . . 

Methyl  ethyl  ketone  (2-Butanone) 

4-Methyl-2-p«ntanone  (Methyl  isobutyl  ketone)  . 
All  other  ketones   


1.000 
kilograms 


72 


11,451 


65.395 


4,552,709 


859,744 

3,048.110 

644,855 


1.381,796 


1.000 
kilograms 


1.000 
dollars 


72 


6,936 


57,299 


1 ,395,346 


33,681 

1,216,734 

144,931 


1,095,806 


270,759 


16,005 
163,810 
90,944 


591,601 


Per 
kik>gram 


275      $3.83 


22,475        3.24 


1,878 

1,391 

6,409 

4.61 

i?) 

161 

572 

3.55 

9,573 

5,384 

15,494 

2.87 

7,956 

0 

(') 

(') 

683 

0 

(^) 

(') 

99 

(') 

(^) 

(') 

54 

51 

344 

6.76 

13 

12 

84 

7.19 

41 

39 

260 

6.67 

e) 

23,008 

16,955 

.74 

12,540 

(') 

(?) 

{*) 

4,086 

4,272 

3,351 

.78 

(') 

18,736 

13,604 

.73 

111,739 

58,966 

89,910 

1.52 

2,083 

1,990 

5,589 

2.81 

791 

776 

2,480 

3.20 

1.292 

1,214 

3,109 

2.56 

39,315 

38,433 

46,933 

1.22 

3,468 

3,394 

7,117 

2.10 

64,351 

13,266 

25.425 

1.92 

2.522 

1,883 

4,846 

2.57 

110,643         1.93 


.19 

.48 
.13 
.63 


.54 


1,056,654 

761,192 

354,189 

.47 

(') 

9,261 

10,087 

1.09 

211,048 

240,258 

124,696 

.52 

(') 

48,750 

42,070 

.86 

114,094 

36,345 

60,559 

1.67 

See  footnotes  at  end  of  table. 


15-5 


Section  15 

Table  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Sales 


Production  Quantity 


Value 


Average 

unit 

value' 


Acyclic — Continued 

Alcohols,  monohydric,  unsubstituted 

Total  

Alcohols,  C,,  or  lower,  unmixed,  total   

n-Butyl  alcohol  (n-Propylcarbinol) 

Isobutyl  alcohol  (Isopropylcarbinol)' 

Ethyl  alcohol,  synthetic' 

2-Ethyl-1  -hexanol 

Isopropyl  alcohol    

Methanol,  synthetic   

Propyl  alcohol  (Propanol)  

All  other  alcohols,  C,i  or  lower,  unmixed 

Alcohols,  Ci2  and  higher,  unmixed,  total  

Hexadecanol  (cetyl  alcohol) 

All  other  alcohols,  0,2  and  higher,  unmixed  . . . . 

Mixtures  of  alcohols,  total    

Containing  Cn  and  lower 

Containing  C,2  and  higher* 

All  other  mixtures  of  alcohols 

All  other 

Esters  of  monohydric  alcohols 

Total  

n-Butyl  acetate 

Butyl  acrylate 

Dilauryl-3,3'-thiodipropionate 

Distearyl-3,3'-thiodipropionate 

Ethyl  acetate  (1 00%  basis)    

Ethyl  acrylate 

2-Ethylhexyl  acrylate 

Fatty  acid  esters,  not  included  with  plasticizers  or 
surlace-active  agents,  total   

Methyl  esters  of  tallow   

Myristyl  myristate   

All  other  fatty  acid  esters  not  included  with 

plasticizers  or  surface-active  agents    

Isopropyl  acetate 

Methyl  methacrylate , 

Phosphorus  acid  esters,  not  elsewhere 

specified 

Propyl  acetate  , 

Vinyl  acetate   

All  other  esters  of  monohydric  alcohols 


1.000 
kilograms 


6.939.676 


114.530 

280.129 

694 

2,519 

123.522 

136,485 

53,348 


5.614 


1.000 
kilograms 


4.388,982 


1.000 
dollars 


Per 
kibgram 


2.955 


1.525,491         $.35 


6.275.073 

4.087,317 

1,219,169 

.30 

575.647 

281.575 

148.401 

.53 

69.865 

52.432 

31,269 

.60 

247.644 

297,615 

186.353 

.63 

294.671 

156.900 

106.097 

.68 

660.466 

562.836 

256.977 

.46 

3.784.957 

2.372.038 

291.635 

.12 

85.535 

52.519 

40.196 

.77 

556.288 

311.402 

158.241 

.51 

85.639 

{') 

{') 

(^) 

18.677 

(') 

(^) 

0 

66.962 

e) 

{') 

(') 

578.964 

C) 

{') 

e) 

e) 

53.977 

44.924 

.83 

365.210 

221,766 

218.827 

.99 

213.754 

(') 

{') 

(') 

(') 

25.922 

42.571 

1.64 

3.113.090 

1.481.937 

1.354.300 

$0.91 

93.242 

70.511 

.76 

108.684 

129.733 

1.19 

704 

2.684 

3.81 

2,456 

8,168 

3.33 

113.668 

76.296 

.67 

66.442 

71.791 

1.08 

46.300 

55.475 

1.20 

4.904         1.66 


2.526 

88 

607 

6.86 

3,088 
•  20,376 
536.283 

2.867 
19.299 

4.297 
16,970 

.61 
.88 

129,395 

32.868 

1.206.021 

471,306 

30.027 

30.612 

674.970 

292,578 

64.661 

29.968 

465.772 

357.367 

2.15 
.97 
.69 

1.22 

See  footnotes  at  end  of  table. 


15-6 


Synthetic  Organic  Chemicals.  J 990 


Table  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales. 


1990 


Miscellaneous  cyclic  artd  acyclic  chemicals 


Sales 

Average 
unit 

Productior) 

Quarttity 

Value 

value' 

1,000 
kilograms 

1,000 
kilograms 

1,000 
dollars 

Per 
kitogram 

3.388.542 

2.866.459 

1,754,639 

.61 

194.623 
2.299.942 

55.516 
342.204 
121,886 

42.382 
331.989 

2.252.303 
52.936 

258.323 
79.056 
34,329 

189,512 

1,064,352 
67,284 

243.171 
59.515 
37,994 

282,323 

.47 

1.27 

.94 

.75 

1.11 

1.49 

1.179.398 

969.029 

1,060,738 

1.09 

145.708 

128.357 

184.527 

1.44 

4.701 
8.357 

2.957 
6.492 

4,476 
9,709 

1.51 
1.50 

13.863 
118.787 

13.387 
105.521 

16.993 
153.349 

1.27 
1.45 

1.033.690 

840.672 

876.211 

1.04 

Acyclic — Continued 
Polyhydric  alcohols* 

Total  

1 .4-Butanediol 

Ethylene  glycol 

Pentaerythritol 

Propylene  glycol    

Sorbitol  (70%)   

Sorbitol,  crystalline 

All  other  polyhydric  alcohols   

Esters  and  ethers  of  polyhydric  alcohols 

Total  

Polyhydric  alcohol  esters,  total 

2-{2-Butoxyethoxy)ethylacetate 

2-Butoxyethyl  acetate 

Glycendes.  mixed  (Cu-Cia  and  Cis-Cib) 

mono  &  di  

All  other  polyhydric  alcohol  esters   

Polyhydric  alcohol  ethers,  total    

2-Butoxyethanol  (Ethylene  glycol 

monobutyl  ether) 

2-(2-Butoxyethoxy)ethanol  (Diethylene  glycol 

monobutyl  ether) 

2-[2-(2-Butoxyethoxy)ethoxy]ethanol  (Triethylene 

glycol  monobutyl  ether) 

Diethylene  glycol    

2-Ethoxyethanol  (Ethylene  glycol  ethyl  ether)  . . 
2-(2-Ethoxyethoxy)ethanol  (Diethylene  glycol 

monoethyl  ether) 

2-Methoxyethanol  (Ethylene  glycol 

methyl  ether) 

2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol 

monomethyl  ether)  

2-(2-(2-Methoxyethoxy)ethoxy]ethanol  (Triethylene 

glycol  monomethyl  ether)  

Polyethylene  glycol 

Polytetramethylene  glycol  ether 

Tetraethylene  glycol  

Triethylene  glycol 

Glycol  ethers  derived  Irom  propylene  oxide,  total 

Dipropylene  glycol    

Polypropylene  glycol 

Sorbitol,  ethoxylated 

2.2'-Thiodiethanol  (Tiodiglycol) 

Tnpropylene  glycol   

All  other  polyhydric  alcohols  ethers    

See  footnotes  at  end  of  table. 


187,491 


41,168 


168,765 


30,907 


123,881 


36.862 


.73 


1.19 


12.081 

(') 

{') 

e) 

218,777 

159.402 

81,143 

.51 

53,471 

29.588 

32,158 

1.09 

17.289 

16,647 

18,632 

1.12 

{') 

16,320 

13,615 

.83 

21.271 

30,638 

30,256 

.99 

22.360 

(') 

e) 

{') 

55.993 

52,245 

79,369 

1.52 

{') 

23,588 

80.039 

3.39 

11.574 

8,141 

10,909 

1.34 

50,949 

46.310 

50.823 

1.10 

(') 

(') 

(') 

{') 

35,588 

29.415 

26,487 

.90 

14,859 

8,962 

13,856 

1.55 

111 

{') 

{') 

{') 

773 

{') 

{') 

{') 

10.385 

{') 

{') 

{') 

279.550 

219,744 

278,181 

1.27 

15-7 


Section  15 

Table  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Production 


Sales 


Quantity 


Value 


Average 

unit 

value' 


Chlorinated  and  fluorinated 
hydrocarbons 

Total  

Chlorinated  hydrocartxans,  total 

Carbon  tetrachloride 

Chlorinated  paraffins  more  than  35%  chlorine 
(Cio-Cao),  total    

35%-64%  chlorine 

65%  or  more  chlorine  

Chloroform  

Chloromethane  (Methyl  chloride)* 

Dichloromethane  (Methylene  chloride)  . . . 

Ethyl  chloride  (Chloroethane)* 

Ethylene  dichloride  (1 ,2-Oichloroethane)*  . 
Tetrachloroethylene  (Perchloroethylene) . . 
1.1,1-Trichloroethane  (Methyl  chloroform) 
Vinyl  chloride,  monomer  (Chloroethylene)* 
All  other  chlorinated  hydrocartxjn 

Fluorinated  (including  other  fluorohalogenated) 
hydrocarbons,  total 

Chlorodifluoromethane  (F-22) 

Dichlorodifluoromethane  (F-12)    

Trichlorofluoromethane  (F-11) 

All  other  fluorinated  (including  other 
fluorohalogenated)  hydrocarbons 

All  other  miscellaneous  acyclic  chemicals 

Total  

Acyclic  peroxides,  total   

2-Butanone  peroxide  (MEK  peroxide) 

ten-Butyl  peroxy-2-ethylhexanoate   

All  other  acyclic  peroxides 

Expoxides,  ethers  and  acetals,  total   

Ethylene  oxide*   

All  other  expoxides.  ethers  and  acetals 

Fats  and  oils,  chemically  modified'"   

Hydrocartxjns    

Hydrogenated  tallow  glycerides 

All  other  fats  oils,  chemically  modified 

Organo-txjron  compounds 

Chloropropyltrimethoxysilane    

Hexamethyldisilazane 

Silicone  fluids 

Phosgene  (Cartxjnyl  chloride)    

All  other  miscellaneous  acyclic  chemicals 


1.000 
kilograms 


13.592.020 


13.175.011 


187,470 


34,818 


122.601 


1.000 
kilograms 


1.000 
dollars 


4,068.431  2.080.054 


3.760.172 


229.020 


31.938 


56,972 


1.312,219 


62.960 


Per 
kilogram 


$.51 
.35 
.27 


34.162        1.07 


28.405 

26,349 

24.275 

.92 

6.413 

5,589 

9.887 

1.77 

219.687 

196,164 

92.707 

.47 

350.114 

79.476 

36.308 

.46 

209.116 

128.921 

58,938 

.46 

67.710 

(') 

(') 

{') 

6.282.199 

1.021.869 

126.247 

.12 

168.844 

166.234 

55,177 

.33 

364,073 

308.228 

182,232 

.59 

4,818,754 

1,430,931 

573,526 

.40 

472,226 

167,391 

89.962 

.54 

417,009 

308,259 

767.835 

2.49 

138.823 

107.707 

273.360 

2.54 

94,626 

81.697 

178.943 

2.19 

60,959 

61.883 

109.415 

1.77 

206.117        3.62 


4.115.985 

917.253 

1,318.426 

1.44 

26.642 

23.814 

119,026 

5.00 

4.424 

4.425 

21,406 

4.84 

1.563 

1.373 

8.924 

6.50 

20.655 

18.016 

88,696 

4.92 

3.188.980 

(') 

e) 

(') 

2.428.914 

241,851 

255.000 

1.05 

760,066 

(') 

e) 

(') 

19,869 

16.604 

20.953 

1.26 

18,937 

e) 

{') 

{') 

8.942 

e) 

(') 

{') 

10.927 

e) 

e) 

(') 

{') 

502 

3,521 

7.01 

530 

{') 

{') 

(') 

362 

67.922 

40,541 

220.223 

5.43 

307.584 

465.290 

593,941 

699.703 

1.18 

See  footnotes  at  end  of  table. 


15-8 


Synthetic  Organic  Chemicals,  1990 


TabiA  15-1 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  U.S.  production  and  sales,  1990 


Production 

Sales 

Average 
unit 

Miscellaneous  cyclic  and  acyclic  chemicals 

Quantity 

Value 

value' 

Mixtures  not  specifically  Itemized 

Total  

1,000 
kilograms 

72.562 

1.000 
kilograms 

68.865 

1,000 
dollars 

22,431 

Per 
kitogram 

.33 

Fatty  acid  residues 

15,562 
57,000 

14,877 
53,988 

1.961 
20,470 

13 

All  other  mixtures  not  specifically  itemized'* 

.38 

'  Calculated  from  unrounded  figures. 

^  Reported  data  are  accepted  in  confidence  and  may  not  be  published,  or  no  data  were  reported. 
^  Statistics  limited  to  compounds  of  carbon,  hydrogen,  and  nitrogen;  and  exclude  production  and  sales  of  fatty 
amines.  Statistics  on  fatty  amines  are  Included  In  the  section  on  "Surface-Active  Agents.' 

*  The  difference  between  the  production  reported  here  and  that  shown  on  the  Preliminary  Report  on  U.S. 
Production  of  Selected  Organic  Chemicals  (including  Synthetic  Plastics  and  Resin  Materials).  1990,  results  from  a 
combination  of  Incorrect  reporting  by  some  companies,  end-of-year  Inventory  adjustments,  and  rounding. 

^  Excludes  minor  amounts  reported  as  "fatty  acids'  and  "partially  hydrogenate'. 

'  Statistics  exclude  production  and  sales  of  potassium  and  sodium  stearates.  Statistics  on  these  stearates  are 
included  in  the  section  on  "Surface-Active  Agents.' 

'  Synthetic  ethyl  alcohol  Is  conventionally  defined  as  that  portion  made  from  ethylene.  Bureau  of  Alcohol, 
Tobacco,  and  Firearms  statistics  give  the  production  from  "natural'  sources,  mainly  grain. 

'  Includes  small  amount  of  mixtures  of  alcohols  on  both  sides  of  the  C1 1  -CI  2  dividing  line. 

*  Some  polyols  which  are  used  as  intermediates  for  urethanes  have  been  Included  In  the  section  on  "Plastics  and 
Resin  Materials.' 

'°  Other  than  esters,  salts,  alcohols,  acids,  or  acyl  halides,  which  are  tabulated  in  preceding  groups. 
"  Products  included  here  are  predominately  acyclic;  however,  unspecified  amounts  of  mixtures  containing  some 
cyclic  chemicals  may  also  be  included. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


15-9 


Section  15 

Table  15-2 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  cyclic: Yes 

6-Acetoxy-2,4-dimethyl-1,3-dioxane   No  GiV. 

Acetylcyclohexane  sulfonyl  peroxide No  ART,  CKC. 

Alkylated  arylamine  No  SM. 

Alkylated  naphthylamine/dioctylphenylamine  copolymer  No  SM. 

Alkylphenol  formaldehyde  condensate,  alltoxylated  ....  No  (^. 

Alkylphenol  formaldehyde  copolymer   No  r). 

1-(2-Aminoethyl)pipera2ine  No  DOW. 

1-(3-Aminopropyl)morpholine    No  TX. 

Amyl  ortho-  and  para-dimethylaminobenzoates No  VND. 

t-Amyl  peroxybenzoate    No  WTL. 

p-Amylphenol No  {^. 

Anisaldehyde  bisulfite    No  EKT. 

a-Aspartyl-phenylalanane  methyl  ester  (a-Amino 

succinic  etc.) No  HXL. 

Benzenephosphinicacid    No  FER. 

Benzothiazole No  CGY. 

Benzotriazole,  polychlorinated No  EVN. 

Benzotriazole,  potassium  &  sodium  saKs No  (^). 

Benzoyl  peroxide Yes  AZT,  CAD,  NOC.  RCI,  WTL. 

Benzyl  alcohol   No  KLM. 

Benzyl  chloroformate No  HCC,  VCM. 

Benzyl  4-hydroxy  benzoate  No  CHD. 

Benzoic  acid  esters: Yes 

Benzoic  acid,  2-butoxyethanol  ester No  PCI. 

Benzoic  acid,  butyl  ester  (Butyl  benzoate) No  UTC. 

Benzoic  acid,  Cij-Cis  ester   No  FTX. 

Benzoic  acid,  isodecyl  ester No  VEL. 

2-Ethylhexyl  benzoate   No  BRI. 

Resorcinol  monobenzoate  No  EKT. 

Sucrose  benzoate No  VEL. 

Benzoic  acid  salts: 

Ammonium  benzoate No  WTK. 

Barium  benzoate   No  CCA,  FER. 

Potassium  benzoate No  KLM,  PFZ. 

Sodium  benzoate No  HCP,  JRC,  KLM,  PFZ. 

a,a-Bis(t-butylperoxy)diisopropylbenzene No  WTL. 

Bis(p-chlorobenzoyl]peroxide No  CAD. 

Bis(2,4-dichlorobenzoyl)  peroxide  No  CAD. 

Bis(a,a-dimethylbenzyl)peroxide No  WTL. 

1.3-Bis(hydroxymethyI)-5,5-dimethylhydantoin No  BRD. 

2,2-Bis(4-hydroxyphenyl)4-methylpentane   No  ASL. 

Bis(perfluoroalkyl)bis(alpha-monochbrohydryl)- 

pyromellitate No  HCL. 

Bis(triphenyisilyl)chromate No  (^. 

Bromochloro-5.5'-dimethyl  hydantoin No  BRD. 

B-Bromo-P-nitrostyrene No  GIV. 

2-Butoxyethyl  benzoate  (Butyl  cellosolve  benzoate)  ...  No  (^). 

tert-Butylhydroquinone No  EKT. 

2  (and  3)-ten-Butyl-4-methoxyphenol  (Butylated 

hydroxyanisole,  or,  BHA)   No  EKT  UPM. 

Butylmorpholine No  TX. 

tert-Butyl  peroxybenzoate   Yes  AZT,  FRE,  NOC,  WTL. 

Camphene No  SCM. 

Campholenic  aldehyde No  SCM. 

Caprolactam  (2-Oxohexamethylenimine) Yes  ACS,  BAS,  CNP. 

Caprolactam  magnesium  bromide No  FER. 

Cellulose  acetate  hexahydrophthalate No  (^). 

Cellulose  acetate  phthalate  No  EVN. 

Chlorothiaxanthone  No  PSG. 

Cumene  hydroperoxide  No  BTL,  FRE.  WTL. 

a-Cumyl  peroxyneodecanoate No  WTC,  WTL. 

See  footnotes  at  end  of  table. 
15-10 


Synthetic  Organic  Chemicals.  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  cyclic-Continued 

a-Cumyl  peroxyneoheptanoate No  WTL. 

Cyanuric  acid No  MON. 

Cyclic  silizane    No  (f). 

Cyclohexane  carbonitrile  No  DUP. 

1,4-Cyclohexanedimethanoldibenzoate No  VEL. 

CyclohGxanethiol No  PAS. 

All  other  cyclohexene-1 ,2-dicart)oxylic  acid  (Tetra- 

hydrophthalicacid),disubstituted,  polyester  salts  ...  .  No  ART. 
2-CyclohexenG-1-octanoic  acid,  5  (and  6)-cartx3xy-4- 

hexyl,C2,H3604 No  WVA. 

1,4-Cyclohexylenedimethanol  No  EKT. 

Cyctohexyl  methacrylate    No  CPS. 

Decabromodiphenyl  ether  (DBDP) No  GTL. 

4.4-Diaminodiphenyl  ether No  MAL. 

1,1-Di(t-amylperoxy)cyciohexane    No  WTL. 

1 ,8-Dia2abicyclo  (5.4.0)undecane   No  AlP. 

1,4-Dia2obicyclo(2.2.2)octane No  (^). 

Dibenzylglycerol No  DIX. 

2,6-Di-ten-butyl-p-cresol  (BHT  or,  Butyiated 

hydroxytoluene Yes  RDA,  UCC,  USR. 

Di-t-butyl  diperoxyphthalate No  WTL. 

2,5-Di-tert-butylhydroquinone No  EKT. 

2,6-Di-t-butyl-4-nonylphenol No  RDA. 

1,1-Di(t-butyl  peroxy)  cyclohexane No  AZT,  WTL. 

1,1 -Di(t-butylperoxy)-3,3,5-trimGthy I  cyclohexane No  WTL. 

1,3-Dichloro-5,5-dimethylhydantoin No  BRD. 

Dicumyl  peroxide No  PRE,  WTC. 

Dicyclopentadienyl  acrylate No  RDA. 

Dicyclopentadienylchromium  (Chromocene) No  ('). 

Dicyclopentadienyl  methacrylate No  RDA. 

3-DiGthylamino-6-methyl-7-(2,4-dimethylanilino) 

fluoran    No  ESA. 

N,N'-Diethyl-N,N'-diphenylurea   No  VCM. 

Di{2-ethylhexyl)chlorendate No  VEL. 

CO-Diethyl-o-phenyl  phosphorothioate    No  ICI. 

2,5-Dihydrothiophene-1,1-dioxidG(SuHolene) No  PLC. 

2.4-Dihydroxybenzophenone No  BAS. 

2,2'-Dihydroxy-4.4'-climethoxybenzophenone No  BAS. 

4,4-Dihydroxymelhyl-2-oxazoline No  ANG. 

Diiodomethyl-p-toiylsullone  No  ANG. 

Diisopropylbenzene  hydroperoxide   No  HPC. 

Diisopropyl/naphthalene  suit,  acid  amine  salts    No  {'). 

p-Dimethoxybenzene  (Dimethyl  ether  of  hydroquinone)  ASL. 

Dimethyl-1,4-cyclohGxanedicartx3xylate  No  EKT. 

4,4-DimGthyl  oxazolidene No  ANG,  EFH. 

N,N-Dimethylphenyl  urea No  AC. 

Dimethyl  piperazine  No  TX. 

Dimorpholine  diethyl  ether No  TX. 

Di-tert-octyl  hydroquinone   No  EKT. 

Dioxane     (1,4-Diethylene  oxide) No  PER. 

1 ,3-Dioxolane No  PER. 

Dioxolanone No  (^). 

1 ,2-Diphenoxyethane No  CHD. 

Diphenyl-t-butylhexyl  phosphite No  WTC. 

Diphenylisodecyl  phosphite   No  WTC. 

Diphenylisooctyl  phosphite No  WTC. 

Dipropylene  glycol  salicylate   No  SBC. 

Dodecyl  pyridinium  chloride No  TLC. 

6-Elhoxy-12-dihydro-2.2,4-trimethylquinoline No  MON. 

Ethyl  cyclohexylamine   No  AlP. 


See  footnotes  at  end  of  table. 


15-11 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Separate         Manufacturers '  identification  codes 
Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 


See  footnotes  at  end  of  table. 
15-12 


VND. 
VND. 


Miscellaneous  chemicals,  cyclic-Continued 

2-Ethylhexyl-1-p-dimethylaminobenzoate  No 

2-Ethylhexyl-p-methoxycinnamate  No 

2-Ethylhexyl  salicylate  No  VND. 

4-(N-Ethyl-N-2-hydroxyethyl)-2-methylphenyiene- 

diamine  sulfate No  WAY. 

4-Etliyi-4-hydroxymethyloxa2oiine No  ANG. 

2,2'-hthylidGne-bis(4,6-di-tert-butyiphenoi)  (Isonox 

1 29)    No  SON. 

Ethyiidine  norbornene   No  UCC. 

4-Ethylmorpholine   No  TX. 

N-Ethyl  pyrrolidone    No  GAR 

Hexabromocyclodecane No  GTL. 

Hexahydro-1.3,5-tris(2-hydroxyethyl)-s-triazine No  ^^S" ,...,,  r,,  ^  ,.,^, 

Hexamethylenetetramine.  tech    Yes  BOR,  HMP.  PLS.  WCL 

Homomenthoi  salicylate No  WTO. 

Hydrindantin No  PIC 

Hydroquinone,  di(a-hydroxyethyl)  ether    No  EKT. 

p-Hydroxybenzoic  acid,  butyl  ester   No  KLM,  UPJ. 

p-Hydroxybenzoic  acid,  ethyl  ester  (Ethyl  paraben)  ...  No  KLM. 

p-Hydroxybenzoic  acid,  methyl  ester No  KLM.  LEM. 

p-Hydroxybenzoic  acid,  propyl  ester  No  KLM,  LEM. 

N-(Hydroxyethyl)piperazine No  SCP. 

2-Hydroxy-4-melhoxybenzophenone No  VND. 

Hydroxymethyl-bis-oxazoline No  ANG. 

Hydroxymethyl-5,5-hydantoin   No  BRD. 

a-D-p-Hydroxyphenylglycine  methyl  ester  K No  BOG. 

1,2,3-lnaantrione  monohydrate  (Ninhydrin) No  PIC. 

isobornyl  acrylate No  RDA. 

Isobornyl  methacrylate No  RDA. 

lsooctyl-3,5-di-t-butyl-4-hydroxyhydrocinnamate No  ASL. 

Isophorone No  ENJ. 

Lead/iron  resorcylate  salicylate  No  SHP. 

Maleic  anhydride  Yes  AMO.  ART.  ASH,  DKA,  MON. 

Methoxyethyl  morpholine No  TX. 

4-Methoxyphenol No  ASL,  EKT. 

Methylbenzene  sulfonate No  EVN. 

Methyl-p-benzoquinone No  EVN. 

2-MethylcyclohGxylaminG No  AlP. 

3-(N-Methyl-N-cyclohexylamino)-6-methyl-7-aniiino 

fluoran    No  GTL. 

4-Methylmorpholine No  TX. 

1-Methyl-2-pyrrolidone,  monomer   No  ATR.  BAS.  GAP.  (2). 

Methyltetrahydrophthalic  anhydride No  DIX. 

Methyl  thiopinacolone  oxime  No  CED. 

Methylvinyl  cyclic  siloxane No  (  ).  „„  .,  ,.^    „ 

Morpholine  .    Yes  AlP.  BAS.  DOW,  TX,  (2). 

Morpholine  salt  of  gluconic  acid No  (^). 

Morpholine  salt  of  p-toluene  sulfonic  acid   No  AMB. 

Naphthenic  acid/polyamine  condensates No  (  ). 

4-(2-Nitrobutyl)  morpholine    No  ANG. 

N-Nitrosophenylhydroxylamine,  ethanolamine  salt   ....   No  MAL. 
Furan  derivatives; 

2-FuraldGhyde  (Furfural)    No  QKO. 

Furt uryl  amine    No  QKO. 

Furoic  acid   No  QKO. 

Tetrahydrofurfuryl  alcohol No  QKO. 

All  other  furan  derivatives No  QKO. 

Lactones: 

Butyrolactone Yes  BAS,  GAF,  UCC. 

Diketene No  EKT. 


Synthetic  Organic  Chemicals,  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers'  identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  cyclic-Continued 
Lactones-Contlnued 

Glucono-5-lactone   No 

Octabromodiphenyl  oxide    No 

Oxoaluminumbenzoate/2-ethylhexanoate No 

Pentaerythritol  tribenzoate No 

Phenol-sulfonated  formaldehyde  rosin No 

2-Phenoxyethanol  (Ethylene  glycol  monophenyl  ether)  .  No 

Phenoxyethyl  acrylate   No 

Phenyl  acid  phosphate No 

Phenyldiisodecyl  phosphite  No 

a-D-Phenylglycine  methyl  ester  K No 

Phenylpropanolamine    No 

Phosphonate  ester,  cyclic    No 

Phthalic  acid,  lead  salt,  (Dibasic) No 

Picramic  acid,  sodium  salt No 

Pinene  and  derivatives:  Yes 

Pinane    No 

Pinane  hydroperoxide No 

2-Pinanol  (cis  and  trans)    No 

Pinanols/plinol  mixtures  No 

a-Pinene    Yes 

p-Pinene Yes 

a-Pinene  oxide No 

Pinene,  suHate  No 

Pinene,  wood  No 

Pine  oil,  natural,  sulfate   Yes 

Pine  oil,  synthetic Yes 

Polyethylene  glycol  ditallate No 

Polyglycols-toluene  diisocyanate  reaction  product    ....  No 

Polypropylene  glycol  ditallate/distearate   No 

Propylene  glycol  dibenzoate    No 

Propyl  gallate No 

2.4(1H.3H)-Pyrimidinedione  (Uracil) No 

p-Quinone   No 

Rosin  acid  salts: 

All  other  rosin  acid  salts No 

Salicylic  acid,  ammonium  salt   No 

Salicylic  acid  magnesium  salt    No 

Styrene  oxide No 

Succinic  anhydride No 

Succinic  anhydride  derivatives:  Yes 

Dodecenylsuccinic  anhydride No 

Dodecylsuccinic  anhydride No 

iso-hexadecenyl  succinic  anhydride No 

Iso-octadecenylsuccinic  anhydride No 

Nonenylsuccinic  anhydride No 

Octadecenyl  succinic  anhydride No 

Octenylsuccinic  anhydride  No 

Polyisobutenyl  succinic  anhydride  No 

All  other  succinic  anhydride  derivatives No 

Tall  oil  acyl  chloride    No 

Tall  oil,  chemically  modified  Yes 

Tall  oil,  diethanolamine  salt    No 

Tall  oil  fatty  acids,  polymerized No 

Tall  oil  monomer No 

Tall  oil:  Neopentyl  glycol  tallate   No 

Tall  oil:  Pentaerythritol  tallate No 

Tall  oil,  triethanolamine  salt    No 


BRD. 

GTL. 

KCH. 

VEL. 

HCL. 

SCP  UCC. 

CPS. 

ALW. 

WTC. 

BOG. 

ORT 

ALW. 

ALL 

SDC. 

SCM. 

SCM. 

SCM. 

SCM. 

AR2,  NCI,  SCM. 

ARZ,  NCI,  SCM. 

SCM. 

ARZ,  HPC. 

HPC 

ARZ,  NCI,  SCM. 

ARZ,  NCI,  SCM. 

RDA. 


a 


DA. 
VEL. 
EKT. 
PCR. 
EKT 

GP 
WTK. 

KLM,  WTK. 
UCC. 
see,  MIL. 

DIX,  HMY 
MIL. 
DIX. 

DIX,  HMY 
HMY 
HMY 

HMY  MIL 
SM. 
HMY  i?). 

ccc 

FOC,  RDA,  SHX,  WVA,  (^),  (^). 

OCP. 

SHX,  WVA. 

WTC. 

QCP. 

EFH. 

QCP, 


See  footnotes  at  end  of  table. 


15-13 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  cyclic-Continued 

Tall  oil  salts  (linoleic-rosin  acid  salts): 

Cadmium  tallate No 

Calcium  manganese  tallate   No 

Calcium  tallate  No 

Cobalt  manganese  tallate No 

Cobalt  tallate    No 

Copper  tallate No 

Lead  tallate No 

Manganese  tallate    No 

Potassium  tallate    No 

Zinc  tallate   No 

All  other  tall  oil  salts  (Linoleic-rosin  acid 

salts) No 

Tannic  acid,  N.F No 

Terpene  hydrocarbons,  monocyclic  (Solvenol)    No 

Tetrabromobisphenol  A   No 

1,2,3,4-Tetrahydronaphthalene  (Tetralin) No 

Tetrahydrothiophene    No 

Tetrahydrothiophene- 1,1 -dioxide  (Sulfolane) No 

Thiophene  No 

TMPD  dibenzoate    No 

Tolyltriazole/butyl  vinyl  ether,  combined No 

Tolyltriazole,  potassium  salt No 

Triallyl  trimellitate No 

Triazine    No 

3,4,4'-Trichlorocarbanilide  No 

Trichloromelamine No 

1,3.5-Trichloro-s-tnazine-2,4,6-(1H,3H,5H)trione 

(Trichloroisocyanuric  acid) No 

Tri(2.4-ditertiarybutylphenyl)  phosphite  No 

Tri(methoxymethyl)  tri(stearoxymethyl)  melamine No 

3,3,5-Trimethylcyclohexanol  (m-homomenthol) No 

3,5.5-Trimethyl-2-cyclohexene-1-one(lsophorone)  ....  No 

Triphenyl  phosphite  No 

Twitchell  chemicals  (Naphthalene/oleic  acid, 

sulfonated)  No 

Urea  toluenesulfonate   No 

1-\/inyl-2-pyrrolidinone-other  copolymers No 

1  -Vinyl-2-pyrrolidinone-methylacrylic  acid, 

dimethylamine  ethyl  ester,  copolymer    No 

1-Vinyl-2-pyrrolidinone,  monomer   No 

1-Vinyl-2-pyrrolidinone-vinyl  acetate  copolymer No 

All  other  cyclic  chemicals No 


Miscellaneous  chemicals,  acyclic; Yes 

Nitrogenous  comp>ounds: Yes 

Acetamidoethanol  (N-Acetyl-ethanolamine) No 

Ally!  ureido  monomer No 

Amides:    Yes 

Acetamide No 

Acrylamide  monomer   No 

1,1'-Azobisformamide No 

Behenamide No 

Chloromethylene  dimethyliminium  (Amide  chloride)  No 

Coconut  oil  amide No 

N,N-Diethyldodecanamide  No 


CCA. 
MCI.  SHP. 

ei 

MCI,  SHP 

MCI,  SHP 

MCI. 

MCI. 

MCI,  SHP 

QCP. 

CCA,  MCI,  (2). 

CCA,  SHP.  (2). 

MAL. 

HPC,  NCI,  SCM. 

GTL,  TNA. 

DUP. 

PAS. 

PLC. 

PAS. 

VEL. 

SM. 

0- 

RDA. 
QCP. 
MON. 
GFS. 

MON,  OMC. 

WTC. 

WPG. 

ARS. 

ENJ.  UCC. 

WTC. 

SCP 
NES. 
GAR 

GAF. 
GAF 
GAF. 
ALW,  ARS,  BAS,  BRD,  CWN.  EKT.  EVN, 

EVN,  EVN,  EVN,  EVN,  EVN.  GAF,  HXL. 

ICI.  LYP  MCK,  MIL,  MNA.  PIC,  QCP. 

RDA,  REG,  REG,  RH,  RQT  RSA.  S. 

SCM,  SCP,  SDC.  SHP,  TNA,  TX,  UCC. 

upj,  e).  n  n  n  {').  n  h  n  n 
e).  ei  {').  {')■ 


SBC. 
RDA. 

WTK. 
ACY,  (2). 
USR. 

ASL,  WTC. 
CWN. 
ARC,  FER. 
EVN. 


See  footnotes  at  end  of  table. 


15-14 


Synthetic  Organic  Chemicals.  1990 

Table  15-2— Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  15-3} 


Miscellaneous  chemicals,  acyclic-Continued 
Nitrogenous  compounds-Continued 
Amides-Continued 

N,N-DimGthylacetamide  No 

N.N-Dimethylacetoacetamide No 

Dimethylaminopropyl  methacrylamide  No 

N,N-Dimethylformamide No 

Erucamide Yes 

Erucyl  stearamide No 

N-N-Ethylenebiscocoamide   No 

N.N'-Ethylenebis-oleamide  (Oleic  acid- 
ethylenedlamine  condensate  (Amine/acid  ratio  > 

1/2)) Yes 

N,N'-Ethylenebis(stearamide) Yes 

Ethylene(12)hydroxystearamide No 

Fatty  acid  amide  mixtures No 

Methacrylamide    No 

N-MethylacGtamide No 

OleamidG  (Octadecene  amide)   Yes 

Oleoylpalmitamide   No 

Oxamide No 

Stearamide  (Octadecane  amide)  No 

Stearylerucamide   No 

Stearyl  stearamide  No 

Tallow  amide No 

Tallow  amide,  hydrogenated No 

All  other  amides   No 

Amines:    Yes 

t-Alkylamines,  primary,  mixed No 

Allylamines: Yes 

Diallylamine No 

Triallylamine   No 

N.N'-Bis(2-amino-2-mGthyl)propyl-1,2-ethane 

diamine  No 

Bis-hexamethylenetriamine  amine No 

Butylamines: Yes 

n-Butylamine,  mono    No 

sec-Butylamine,  mono No 

tert-Butylamine,  mono No 

Dl-n-butylamine No 

Diisobutylamine No 

Tri-n-butylamine   No 

n-Butylethylamine No 

Di-tert-butylethyldiamine No 

Diethylaminopropylamine No 

Diethylenetriamine   No 

Diisopropylamine    No 

2,2-Dimethyl-N-(2-aminoGthyl)-1 ,2-ethane  diamine  No 

Dimethylaminopropylamino    No 

DimethylGthyl  amine  (DMEA) No 

Dodecamethylenediamine    No 

Ethylamines: 

Diethylamine Yes 

Ethylamine,  mono-    No 

Triethylamine Yes 

Ethylenediamine Yes 

(2-Ethylhexyl)amine,  mono-  No 

N-Ethyl-2-methylallylamine No 

Fatty  amines No 

1,6-Hexanediamine(Hexamethylenediamine)   ....  No 


DUP,  EKT,  MON. 

BRD. 

TX. 

AlP,  DUP. 

ARC,  SYP,  WTC. 

WTO. 

WTC. 


BRD,  CCW,  WTC. 
BRD,  CCW,  WTC. 
CAS. 
ARC. 
DUP. 

ARS.  EKT. 
ARC,  SYP,  WTC. 
HXL.  WTC. 
HML.  (2). 
ARC.  SYP.  WTC. 
HXL,  WTC. 
WTC. 
QCP. 
ARC. 

AC,  ARS,  CAS,  DOW,  MIL.  QCP.  SDC. 
VCM,  (\ 

BRD.  RH. 

HCL,  ICI. 
HCL. 

HXL. 
DUP,  MON. 

AlP,  PAS. 

FER,  PAS. 

MON,  SC. 

AlP,  PAS. 

AlP,  HCL. 

AlP.  PAS. 

AlP. 

HCL. 

UCC. 

ARC,  DOW.  TX. 

AlP,  PAS,  UCC. 

HXL. 

AlP,  BAS.  TX,  (2). 

BAS 

(% 

AlP.  HCL.  PAS,  QTR,  UCC 

AlP,  HCL,  PAS.  QTR,  UCC. 

AlP,  PAS,  QTR,  UCC. 

DOW,  TX,  UCC. 

PAS. 

HCL. 

NCI. 

DUP.  MON. 


See  footnotes  at  end  of  table. 


15-15 


Sec  lion  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identification  ccxies 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Nitrogenous  compounds-Continued 
Amines-Continued 

n-Hexylamine  No  CXI,  PAS. 

Isopropylamlnes: 

Isopropylamine.  mono No  AlP,  HCL,  PAS.  UCC. 

Methylamines: 

Dimethylamine    Yes  AiP  DUP,  IMC,  RDA,  UCC. 

Methylamine,  mono-  No  Aip  DUP  IMC,  RDA. 

Trimethyl  amine Yes  AIP,  DUP  IMC,  RDA. 

tert-Octyiamine No  RH,  (^). 

n-Octylamine,  mono No  ELC. 

Pentaethylenehexamine No  DOW,  UCC. 

Pentylamines  (amylamines): 

Dipentylamine No  PAS. 

Pentylamine,  mono-    No  PAS. 

Tripentylamine No  PAS. 

Propylamines: 

Dipropylamine No  AIP,  HCL,  PAS. 

Propylamine,  mono-   No  AIP,  PAS. 

Tripropylamine No  AIP,  PAS. 

N,N,N',N"-Tetrabutylhe)(anediamine No  MON. 

Tetraethylenepenlamine No  DOW,  UCC. 

N,N,N',N'-Tetramethyl-1,3-butanediamine   No  UCC. 

Tetramethylethylenediamine No  BKM. 

Triethylenediamine No  TX. 

Triethylenetetramine No  DOW,  TX,  UCC. 

All  other  amines   No  ANG,  MON,  SCR  UCC. 

5-Amino-1,3-bis(2-ethylhexyl-5-methyl)- 

hexahydropyrimidine No  ANG. 

2-Amino-1  -butanol   No  CED. 

2-Aminoethanol  hydrochloride  No  OMC,  (^). 

2-Aminoethanol  (Monoethanol  amine)  sulfite No  EVN. 

Aminoethoxyethanol No  TX. 

2-(2-Aminoethylamino)ethanol 

(Aminoethylethanolamine)   No  DOW,  {^). 

(2-Aminoethyl)amino  ethanol.  reaction  product  with 

octadecanoic  acid No  BRI. 

2-Aminoethyl  mercaptoacetate  (Monoethanolamine 

thioglycolate) No  EVN. 

2-Amino-2-ethyl-1,3-propanediol   No  ANG. 

2-Amino-2-(hydroxymethyl)-1,3-propanediol 

[Tris(hydroxymethyl)aminomethane] No  ANG,  CED,  GON,  WTK. 

2-Amino-2-methyl-1 ,3-propanediol No  ANG. 

2-Amino-2-methyl-1-propanol No  ANG,  CED,  GON. 

Bis(dimethylaminoethyl)  ether    No  TX. 

tert-Butylaminoelhyl  methacrylate   No  CPS,  RDA. 

ten-Butyldiethanolamine No  PAS. 

ten-Butyl  urea No  PAS. 

Choline No  RH. 

Diallyldimethyl  ammonium  chloride   No  CPS,  (^). 

Di-amine  derivatives  of  dimer  acids  No  WTC. 

2-Dibutylaminoethanol  No  PAS. 

Dibutylaminomethanol,  condensed  with  formaldehyde  No  (^). 

2-Diethylaminoethanol(N,N-Diethylethanolamine)    ..  No  PAS. 

2-{2-Diethylaminoethoxy)ethanol No  PAS. 

Diethylaminoethylacrylate,  dimethyl  sulfate, 

quaternary  salt    No  CPS. 

2-Diethylaminoethyl  methacrylate    No  CPS,  DUP. 

Diethylcarbamoyl  chloride    No  GAR 


See  footnotes  at  end  ol  table 


15-16 


Synthetic  Organic  Chemicals,  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Nitrogenous  compounds-Continued 

Diethylhydroxylamine No  PAS. 

1 ,3-Diethyl-2-thiourea No  PAS. 

2-Diisopropylaminoethanol  (N,N- 

Diisopropylethanolamine) No  PAS. 

Dimethylamine  epichlorohydrin  copolymer No  GPS. 

2-Dimethylaminoethanol{N,N-DimethylGthanolamine)  No  AlP,  PAS. 

Dimethylaminoethyl  acrylate No  GPS. 

Dimethylaminoethyl  acrylate,  dimethyl  sulfate, 

quaternary  salt    No  GPS. 

Dimethylaminoethylacrylate,  methyl  chloride. 

quaternary  salt   No  GPS.  RDA. 

Dimethylaminoethyl  chloride No  SK. 

Dimethylaminoethyl  methacrylate No  GPS,  RDA. 

Dimethylaminoethylmethacrylate.  dimethyl  sulfate, 

quaternary  salt    No  GPS,  RDA. 

Dimethylaminoethylmethacrylate.  methyl  chloride, 

quaternary  salt   No  GPS.  RDA,  UGG. 

Dimethylaminoethylmethacrylate  sulfate   No  RDA. 

Dimethylaminomethanol No  (^). 

1  •{Dimethylamino)-2-propanol No  PAS. 

Dimethylaminopropyi  chloride    No  SK. 

Dimethyl  soy  amine    No  (^). 

Ethanolamines Yes 

Diethanolamine Yes  GNE.  DOW.  OMC.  TX.  UGG. 

Monoethanolamine Yes  GNE.  DOW.  OMG.  TX.  UGG. 

Triethanolamine   Yes  GNE.  DOW.  OMG.  TX.  UGG. 

2-Ethylamlnoethanol  (Ethylmonoethanolamine)  ....  No  PAS. 

2-Ethylhexyl  nitrate  ethyl  ester No  BUG. 

N-Ethyl-N-hydroxyethyl-1.4-pentanediamine No  SDW. 

2-Ethyl-2-nitro-1 .3-propanediol No  SDW. 

Fatty  acid,  alkanolamine  ester  No  (^. 

Fatty  acid/polyamine  condensates No  (^. 

Hexamethylenediamine  adipate  (Nylon  salt) No  DUP  MON.  ('). 

Hexamethylene-1.6-diisocyanate(HDI) No  MOB. 

Hexylamine  ethoxylate No  GXI. 

N-(2-Hydroxyethyl)-12-hydroxystearamide    No  GAS. 

2-(Hydroxymethyl)-2-nltro-1.3-propanediol(Tris- 

(hydroxymethyl)nitromethane)   No  ANG.  GED. 

Iminodiacetic  acid No  HMP. 

Isopropanolamines: 

Diisopropanoiamine   No  DOW. 

Dimethyl  isopropanolamine    No  PEL. 

Monoisopropanolamine    No  DOW. 

Triisopropanolamine No  DOW. 

2-lsopropylaminoethanol    No  PAS.  UGG. 

Ketimine,  tetrafunctional No  SM. 

3-Methoxypropylamine Yes  BAS.  PAS,  TX. 

Methylaminoacetaldehyde  dimethyl  acetal  (MAADMA)  No  ASL. 

2-Methylaminoethanol  (N-Methylethanolamine)  ....  No  UGG. 

Methyl  ammonium  chloride    No  NOD. 

2.2'-(Methylimino)diethanol  (Methyldielhanolamine)  .  Yes  DOW,  PAS.  TX.  UGG. 

Methyl  isocyanate No  RDA. 

2-Methyl-2-nitro-1  -propanol   No  ANG.  GED. 

Mixed  higher  glycol  amine  (MHGA) No  AlP. 

Nitrated  lard  oil No  SM. 

Nitriles: Yes 

Acetonitrile   Yes  BKC.  DUP  SOH.  (=*). 

Acrylonitrile,  monomer   Yes  AGY.  DUP.  MON.  SG.  SOH. 


See  footnotes  at  end  of  table. 


15-17 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Nitrogenous  compounds-Continued 
Nitriles-Continued 

Adiponitrile   No 

Aminodimethyl  butyronitrile No 

2,2-Azobis(dimethyl  pentane  nitrile) No 

2.2-Azobis(2-methyl  butane  nitrile) No 

2.2'-Azobis[2-methylpropionitrile] 

(Azobisisobutyronitrile)  No 

Cyanoacetic  acid  (Malonic  nitrile)   No 

1  -(2-Cyanoethyl)elhyl  urea No 

Ethyl  cyanoacGtate No 

Isobutyronitrile    No 

Methyl  cyanoacetate No 

4-Methyl-5-hydroxymethyl  imidazole    No 

2-Methyllactonitrile  (Acetone  cyanohydrin) Yes 

Octadecenenitrile  (Oleonitrile) No 

Propionitrile No 

Tallow  nitrile   No 

3,3'-ThiodipropionitrilG    No 

Tnchloroacetonitrile No 

All  other  nitriles No 

2-Nitro-1  -butanol    No 

Nitroethane No 

Nitromethane   No 

1  -Nitropropane No 

2-Nilropropane No 

Polyoxypropylene  triamine No 

n-Propylaminoethanol    No 

Semicarbazide  hydrochloride No 

Tetraethyl  ammonium  bromide No 

Tetramethylammonium  chloride No 

Thiosemicarbazide No 

Tnethanolamine  hydrochloride No 

Triethanolamine,  sulfuric  &  phosphoric  acid  salts  ....  No 

Triethylamine,  nitric  acid  sah   No 

Triethylenetetramine,  propoxylated    No 

All  other  nitrogenous  compounds,  acyclic   No 

Acids,  acid  anhydrides,  and  acyl  halldes:    Yes 

Acetic  acid,  synthetic  (100%)    Yes 

Acetic  anhydride,  other  than  recovered  acetic 

anhydride   No 

D-(-)-3(Acetylthio)-2-methylpropanoyl  chloride    No 

Acrylic  acid Yes 

Adipic  acid   No 

Anhydride-acid  mixture No 

Azelaic  acid    No 

2,2-Bis(hydroxymethyl)propionic  acid    No 

2-Bromohexanoic  acid  No 

Butyric  acid No 

Butyric  anhydride   No 

Butyryl  chloride No 

Castor  oil  fatty  acids,  dehydrated No 

Chtoroacetic  acid,  mono No 

Citric  acid  No 

Crotonic  acid  (2-Butenoic  acid)    No 

Decanoic  acid  (Capric  acid) No 

DecanoyI  chloride No 

2,2-Dichloroacetyl  chloride No 


DUP,  MON.  (2). 

NOD. 

DUP. 

DUP. 

DUP,  EKX. 

NOD. 

GAP. 

NOD. 

EKX. 

NOD. 

SK. 

CYR.  DUP,  RH.  SOH. 

ARC. 

MON. 

SHX. 

EVN. 

OMC. 

AC.  EKT,  HMP.  HXL.  RSA.  TNA.  WTC. 

CED. 

ANG,  GON. 

ANG.  GON. 

ANG.  GON. 

ANG.  GON. 

TX. 

PAS. 

OMC. 

RSA. 

RSA. 

FMT 

WPG. 

(^. 

HXL 

AlP.  ANG.  CCC.  EVN.  HXL.  OMC.  PAH. 

RDA.  REG.  RSA,  SCM.  SK.  TX.  UCC. 

WTL.  (2).(2). 

AiP.  ARC.  EKT,  HCL.  SC.  UCC.  USI,  (2). 

EKT.  HCL. 

BRS. 

BAS.  HCL.  RH.  UCC. 

DUP,  MON. 

HCL. 

SCP 

IMC. 

EKT. 

EKT.  HCL.  PEN. 

EKT. 

TLC. 

CAS. 

NCC.  PFZ. 

HAR.  PFZ. 

EKT. 

ARC. 

WTL. 

RDA. 


See  footnotes  at  end  of  table. 


15-18 


Synthetic  Organic  Chemicals.  1990 

Tabl«  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Acids,  acid  anhydrides,  and  acyl  halides-Continued 

Dimer  acid  {Cx  aliphatic  dibasic  acid) Yes 

DImethylpropionIc  acid  (Neopentanoic  acid)    No 

DIthiodiglycoiic  acid    No 

DIthiodipropionic  acid No 

Dodecanedioic  acid   No 

Dodecanolc  acid  (Laurie  acid) No 

2-Ethylhexanoic  acid  (a-Ethylcaproic  acid) No 

2-Ethylhexanoyl  chloride    Yes 

Etidronic  acid  ((l-Hydroxyethylidene)biphosphonic 

acid)   No 

Fatty  acids   Yes 

Fatty  acids,  hydrogenated    Yes 

Fatty  acids,  partially  hydrogenated No 

Formic  acid,  90% No 

Fumaric  acid Yes 

Gluconic  acid,  technical No 

Glutaric  acid No 

Glycolic  acid  (Hydroxyacetic  acid) No 

Heptanoic  acid  No 

Hexadecanoic  acid  (Palmitic  acid) No 

Isoascorbic  acid  (Erythorbic  acid)    No 

Isobutyric  acid    No 

Isobutyric  anhydride No 

Itaconic  acid  (Methylenesuccinic  acid)   No 

Lactic  acid,  1 00% No 

LauroyI  chloride   No 

Malic  acid No 

Mercaptoacetic  acid  (Thioglycolic  acid) No 

3-Mercaptopropionic  acid No 

Mercaptosuccinic  acid  (Thiomalic  acid) No 

Methacrylic  acid  No 

Methanesulfonic  acid  No 

Methanesulfonyl  chloride  No 

Neo-Cj-Ciz  acids  No 

Neodecanoic  acid No 

NeodecanoyI  chloride Yes 

NeoheptanoyI  chloride  No 

Neopentanoic/neoheptanoic  acids No 

Nonanoic  acid  (Pelargonic  acid)  No 

Octanoic  acid  (Caprylic  acid) No 

Oleic  acid   No 

Oxidized  Fischer-Tropsch  wax No 

PivaloyI  chloride Yes 

Polyacrylic  acid No 

Propionic  acid Yes 

Propionic  anhydride   No 

Sebacic  acid No 

Sorbic  acid  (2.4-Hexadienoic  acid)  No 

Stearic  acid  (Octadecanoic  acid) No 

Tetradecanoic  acid  (Myristic  acid) No 

3.3'-Thiodipropionic  acid    No 

Thiodisuccinic  acid No 

Trilluoroacetic  acid No 

Trifluoroacetic  anhydride   No 

Trif luoroacetyl  chloride No 

Trimer  dibasic  acids  No 

Undecylenic  acid    No 

Valeric  acid No 


SOP.  SYL,  WTO. 

QTR. 

EVN. 

EVN. 

DUR 

ARC. 

EKT,  UCC. 

DUP,  PPG,  WTO.  WTL. 

BRD. 

ARC,  CAS,  DRL,  PG.  SHX,  WTC. 

BRD,  CAS,  DRL,  SHX,  SYR  WTC,  (2). 

SYP.  WTC. 

HCL 

HAR,  MON.  PFZ. 

PFZ.  PMR 

DUP 

DUP 

HCL. 

ARC. 

PFZ,  RDA. 

EKX. 

EKT. 

PFZ. 

SC. 

WTL. 

HAR. 

EVN. 

EVN,  WTC. 

EVN. 

DUP.  RH. 

PAS. 

PAS. 

ENJ. 

ENJ. 

PPG,  WTC,  WTL. 

WTC,  WTL. 

ENJ. 

HCL,  SCP 

ARC. 

ARC.  DRL,  WTC. 

SOA. 

PPG,  WTC,  WTL. 

BFG,  BKM,  RH. 

EKT,  HCL,  UCC. 

EKT. 

WTH. 

EKT  MNA. 

ARC. 

ARC. 

EVN. 

EVN. 

HOC. 

HOC. 

HOC. 

WTC. 

WTL. 

UCC. 


See  footnotes  at  end  of  table. 


15-19 


Section  15 

Table  15-2— Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  ^les  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate 
statistics ' 


Manufacturers '  identification  codes 
(according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Acids,  acid  anhydrides,  and  acyl  halides-Continued 

All  other  acids,  acid  anhydrides,  and  acyl  halides   ...  No 

Salts  of  organic  acids: 

Acetic  acid  salts: Yes 

Aluminum  acetate No 

Ammonium  acetate    No 

Barium  acetate No 

Calcium  acetate  No 

Cobalt  acetate    No 

Cobalt  manganese  acetate No 

Copper  acetate No 

Hydrazine  acetate No 

Lead  acetate No 

Lead  subacetate No 

Magnesium  acetate    No 

Nickel  acetate No 

Potassium  acetate   Yes 

Sodium  acetate    Yes 

Sodium  diacetate  No 

Zinc  acetate   No 

Zirconium  acetate No 

Adipic  acid,  ammonium  salt No 

Adipic  dihydrazide   No 

3-Allyloxy-2-hydroxypropane  sulfonic  acid,  sodium 

salt  No 

Citric  acid  salts: 

Ammonium  citrate    No 

Calcium  citrate No 

Potassium  citrate  No 

Sodium  citrate    No 

Diammonium  dithiodiglycolate No 

2-Ethylhexanoic  acid  (alpha-ethylcaprolc  acid)  salts  . .  .  Yes 

Barium  2-ethylhexanoate No 

Bismuth  2-ethylhexanoate   No 

Cadmium  2-ethylhexanoate No 

Calcium  2-ethylhexanoate   No 

Cerium  2-ethylhexanoate No 

Chromium  2-ethylhexanoate    No 

Cobalt  2-ethylhexanoale Yes 

Copper  2-ethylhexanoate No 

Ferrous  2-ethylhexanoate No 

Iron  2-ethylhexanoate No 

Lead  2-ethylhexanoate No 

Manganese  2-ethylhexanoate    No 

Nickel  2-ethylhexanoate No 

Potassium  2-ethylhexanoate   No 

Rare  earths  2-ethylhexanoate    No 

Stannous  2-ethylhexanoate  No 

Zinc  2-ethylhexanoate   Yes 

Zirconium  2-ethylhexanoate No 

All  other  2-ethylhexanoic  acid  salts   No 

Fish  oil,  C,4-C22  menhaden,  lead  salts No 

Formic  acid  salts: Yes 

Aluminum  formate    ts|o 

Calcium  formate No 

Sodium  formate,  technical   No 

Gluconic  acid  salts: 

Sodium  gluconate No 

Glycolic  acid,  potassium  salt  No 

Glycolic  acid,  sodium  salt No 


ARC,  DUP.  ENJ.  HOC,  MAL,  SK,  UCC. 
WTL. 


NCC. 

ARC,  BKC,  WTK. 

BKC. 

HFT,  NCC. 

SHR 

SHR 

BKC. 

FMT. 

BKC. 

BKC. 

BKC.  EKT,  SHP. 

SHR 

BKC.  HCR  JRC.  NCC.  PEL. 

ATL.  BKC,  HCR  JRC,  MAL,  NCC,  UCC. 

HCR  JRC.  NCC. 

BKC.  SHR  WTK. 

TZC. 

ACS. 

FMT 

RDA. 

WTK. 

PFZ. 

HAR.  HXL,  PFZ. 

BRI,  HAR,  HXL,  PFZ. 

EVN. 

WTC. 

SHR 

WTC. 

CCA.  FER.  MCI.  NOD,  TRO.  WTC. 

CCA.  SHR 

MCI.  SHR 

CCA,  MCI.  NOD.  SHR  TRO. 

CCA,  MCI,  NOD. 

CCA. 

NOD. 

CCA.  NOD.  SHR 

CCA.  MCI.  NOD.  SHR  TRO. 

MCI.  SHR 

CCA,  MCI,  PEL,  WTC. 

MCI. 

FER. 

CCA,  FER,  MCI,  NOD,  SHR  TRO,  VNC 

WTC. 

CCA,  MCI,  TRO. 

FER.  NOD. 

ELC. 

WTK. 

IMC,  QTR.  RDA. 

BKC.  PST 

PFN,  PFZ,  PMR 
HCR  JRC. 
HCR  JRC, 


See  footnotes  at  end  of  table. 


15-20 


Synthetic  Organic  Chemicals.  1990 

Table  15-2— Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturefs '  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '  (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Salts  of  organic  acids-Continued 

2-HydroxyethanGsulfonic  acid,  sodium  salt    No  RDA. 

isoascorbic  acid,  sodium  salt  (Sodium  erythorbate)  .  .  No  PFZ. 
Tertiary-alpha-alkyicarboxylic  acid  salts 
(isocarboxylic  acid  salts): 

Calcium  t-a-alkylcarboxylate    No  MCI. 

Cobalt  t-a-alkylcarboxylate No  MCI. 

Cobalt/zirconium  t-a-alkylcarboxylate No  MCI. 

Copper  t-a-aikyicarboxylate No  MCI. 

Iron  1-a-alkylcarboxylate No  MCI. 

Lead  t-a-alkylcartX3xylate No  MCI. 

Manganese  t-a-aikylcarboxylate No  MCI. 

Mixed  t-a-alkylcartx)xylic  acid  salts    No  MCI. 

Zinc  t-a-alkylcarboxylate    No  MCI. 

Zirconium  t-a-alkylcart)oxylate No  MCI. 

Lactic  acid  salts: 

Potassium  lactate  No  PFN. 

Sodium  lactate  (Nalac)    No  BFP,  PFN. 

Laurie  acid  salts: Yes 

Barium  cadmium  laurate No  FER,  WTC. 

Barium  laurate    No  SYP. 

Cadmium  laurate    No  SYP. 

Laurie  acid,  zinc  salt No  SYP. 

Tin  laurate No  FER. 

Maleic  acid  salts:    No 

Dibutyltin  maleate No  WTC. 

All  other  maleic  acid  salts No  ALL 

Mercaptoacetic  acid  (thioglycolic  acid)  salts: 

Ammonium  mercaptoacetate  No  EVN,  WTC. 

Sodium  mercaptoacetate   No  EVN. 

All  other  mercaptoacetic  acid  (Thioglycolic 

acids)  salt   No  (^). 

N-Methyl  taurine,  sodium  salt  (2-Methyl-2- 

aminoethanesultonic  acid,  sodium  salt)   No  RDA. 

Neodecanoic  acid,  diethanolamine  salt   No  OCP. 

Neodecanoic  acid  salts: 

Bismuth  neodecanoate No  SHP. 

Calcium  neodecanoate No  FER,  MCI. 

Cobalt  neodecanoate   No  MCI.  SHP. 

Lead-cobalt  neodecanoate No  MCI. 

Lead  neodecanoate    No  MCL 

Lithium  neodecanoate No  MCI. 

Manganese  neodecanoate No  MCI,  SHP. 

Neodecanoic  acid,  potassium  salt    No  QCP. 

Neodecanoic  acid,  sodium  salt No  QCP. 

Rare  earths  neodecanoate No  MCI. 

Zinc  neodecanoate No  SHP. 

Zirconium  neodecanoate    No  MCI,  SHP. 

Octanoic-acid  (caprylic  acid)  salts: 

Aluminum  octanoate Yes  NOC,  SYP.  WTC. 

All  other  octanoic  acid  (Caprylic  acid)  salts    No  WTC. 

Oleic  acid  salts:    Yes 

Calcium  oleate   No  (^. 

Copper  oleate No  MCI. 

Sodium  oleate No  QCP,  WTC. 

Oxalic  acid  salts:    Yes 

Ammonium  oxalate No  BKC,  HML,  WTK. 

Potassium  oxalate    Yes  BKC,  HML,  WTK. 

Sodium  oxalate No  BKC,  HML. 

See  footnotes  at  end  of  table. 

15-21 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Salts  of  organic  acids-Continued 
Oxalic  acid  salts-Continued 

All  other  oxalic  acid  salts    No 

Pelargonic  acid,  calcium  salt  (Calcium  nonoate)  ....  No 
Phosphorodithioic  acid  salts  (dithiophosphates): 

Potassium  dihexyl  phosphorodilhioate No 

Sodium  di-sec-bulyl/diethylphosphorodithioate  ...  No 

Sodium  di-sec-butyl  phosphorodithioate No 

Sodium  diethyl  phosphorodithioate No 

Sodium  dihexyl  phosphorodithioate   No 

Sodium  diisobutyl  phosphorodithioate    No 

Sodium  diisopropyl  phosphorodithioate   No 

Propionic  acid  salts:  Yes 

Ammonium  propionate  No 

Calcium  propionate Yes 

Sodium  propionate  Yes 

All  other  propionic  acid  salts No 

Ricinoleic  acid  salts: 

Calcium  ricinoleate No 

Lithium  ricinoleate No 

Ricinoleic  acid,  magnesium  salt  No 

Sorbic  acid,  potassium  salt No 

Stearic  acid  salts: Yes 

Aluminum  stearates: Yes 

Aluminum  distearate No 

Aluminum  monostearate No 

Aluminum  tristearate Yes 

Barium  stearate    No 

Cadmium  stearate    No 

Calcium  stearate Yes 

Cobalt  stearate No 

Lead  stearate,  dibasic No 

Lithium  stearate    No 

Magnesium  stearate Yes 

Manganese  stearate No 

Potassium  stearate No 

Silver  stearate No 

Sodium  stearate  No 

Zinc  stearate Yes 

Tartaric  acid  salts: 

Potassium  sodium  tartrate   No 

Thioacetic  acid,  potassium  salt No 

All  other  salts  of  organic  acids  No 

Aldehydes: Yes 

Acetaldehyde  No 

Acrolein  (Acrylaldehyde) No 

Butyraldehyde    Yes 

Crotonaldehyde    No 

2-EthylhGxanal  (2-Ethylcaproaldehyde) No 

Formaldehyde  (37%  HCHO  by  weight) Yes 

Glyoxal No 

Isobutyraldehyde   No 

Propionaldehyde    No 

Valeraldehyde  (Pentanal) No 

All  other  aldehydes,  acyclic    No 

Ketones: Yes 

Acetone    Yes 


WTK. 
SYR 

ACY 

ACY 

ACY  ELC. 

ACY  ELC. 

ACY 

ELC. 

ACY 

KMi. 

DVR.  HFT.  NCC. 

HFT,  KMi,  NCC. 

MCK. 

CAS. 
CAS. 
CAS. 
EKT. 


MAL.  NOC,  NOD.  SYP. 

MAL,  NOD,  SYR 

MAL.  NOD.  SYR  WTC.  (*). 

NOD,  SYR  WTC. 

SYR  WTC. 

PER,  MAL,  NOD,  SCR  SQA.  SYR  WTC. 

SHR 

ALL 

WTC. 

MAL,  NOD,  SYR  WTC. 

SHR 

WTC. 

WTC. 

WTC. 

MAL,  NOC,  NOD.  PLS.  SYR  WTC. 

PFZ. 
RSA 
EVn!  SDC.  SK.  (2). 

EKX.  HCL. 

UCC. 

BAS,  EKX,  HCL.  UCC. 

EKT. 

EKX  UCC 

AQU.  BCR  BOR.  CBD.  DGC,  DUR  GAR 

GR     HCL.  IMC.  MON.  QTR,  UCC. 

WCL. 
ACY  BAS. 
BAS.  EKX.  UCC. 
EKX.  HCL.  UCC. 
UCC. 
ASL.  UCC. 

ACS.  ART  ATR.  BTL.  DOW,  ENJ.  GE, 
GGC,  SHC,  UCC,  {"). 


See  footnotes  at  end  of  table. 


15-22 


Synthetic  Organic  Chemicals,  1990 

Tabis  15-2 — Continued 

MiscAllaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers '  identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Ketones-Continued 

5-Chloro-2-pentanone   No 

1  -Chloro-1  -penten-3-one  (|J-Chlorovinyl  ethyl  Icetone)  No 

Diisopropyi  ketone  (2,4-Dimethyl-3-pentanone)   ....  No 

2-Heptanone  (Methyl  amyl  ketone) No 

3-Heptanone    (Ethyl  butyl  ketone)    No 

4-Hydroxy-4-methyl-2-pGntanone  (Diacetone  alcohol)  Yes 

isovalerone  (Diisobutyl  ketone) No 

Methyl  ethyl  ketone Yes 

5-Methyl-2-hexanone  (Methyl  isoamyl  ketone) No 

Methyl  isobutyl  ketone   Yes 

Methylisopropyl  ketone No 

4-Methyl-3-pGnten-2-one  (Mesltyl  oxide) No 

Methylpropyl  ketone No 

Methylpseudoionone   No 

2-Octanone  (Hexyl  methyl  ketone)   No 

2,4-Pentanedione  (Acetylacetone)    No 

3-Pentanone  (Diethyl  ketone)  No 

Pseudoionone No 

2,6,8-Trimethyl-4-nonanone  (isobutyl  heptyl  ketone)  No 

All  other  ketones No 

Alcohols,  monohydric,  unsubstituted: Yes 

Alcohols.  On  or  lower,  unmixed  (95%  or  more  pure):  Yes 

Allyl  alcohol No 

Amyl  alcohols: 

2-Methyl-1  -butanol   No 

3-Methyl-1  -butanol   No 

1  -Pentanol No 

Butyl  alcohols: 

n-Butyl  alcohol  (n-Propylcarbinol)   Yes 

sec-Butyl  alcohol  (Methylethykiarbinol)   No 

tert-Butyl  alcohol  (Trimethylcarbinol)  No 

isobutyl  alcohol  (isopropylcarbinol)  Yes 

1  -Decanol No 

Ethyl  alcohol,  synthetic Yes 

2-Ethyl-1-hexanol Yes 

n-Hexyl  alcohol I^o 

Isodecyl  alcohol    No 

Isoheptyl  alcohol No 

Isononyl  alcohol   No 

Iso-octyl  alcohol   No 

Isopropyl  alcohol Yes 

Methanol,  synthetic Yes 

2-Methyl-3-butyn-2-ol  No 

2-MGthyl-1  -pentanol   No 

4-Methyl-2-pentanol  (1-Methylisobutylcarbinol)  ...  No 

1-Octanol    No 

2-C)ctanol  (sec-Capryl  alcohol)    No 

Propyl  alcohol  (Propanol)    Yes 

2-Propyn-1-ol  (Propargyl  alcohol) No 

Undecanol  (Linear  C,,  alcohol) No 

All  other  alcohols,  unmixed  C,,  or  tower No 

Alcohols  C,2  or  higher,  unmixed  (95%  or  more  pure):  Yes 

Dodecyl  alcohol  (Lauryl  alcohol)   No 

1-Hexadecanol  (Cetyl  alcohol) Yes 

Isooctadecanol No 

1  -Octadecanol  (Stearyl  alcohol)    No 

cis-9-OctadGcen-1-ol  (Oleyl  alcohol) No 


SOW. 
ASL. 
EKX. 

EKT,  ei 

UCC. 

HCL,  SHC,  UCC. 

EKT,  UCC. 

ATR,  ENJ,  HCL,  LYP,  SHC,  UCC. 

EKT.  (2). 

EKT.  ENJ,  SHC,  {^). 

EKX. 

UCC. 

EKT. 

NCI. 

UPM,  WTH. 

SCP,  UCC. 

UCC. 

NCI.  SCM. 

UCC. 

ASL,  EKT. 


ATR.  FMB. 

UCC. 
CPS. 
UCC. 

BAS,  CXI,  EKX.  GAP,  HCL.  SHC,  UCC. 

VST  (^). 
ENJ.  SHC. 
ATR.  (2). 

BAS,  CPS,  EKX,  HCL,  SHC,  UCC. 
TNA,  VST 

DOW,  EKX,  HCL,  SHC,  UCC,  USI,  VST 
ART  BAS,  EKX,  SHC.  UCC. 
TNA,  VST 
ENJ. 
ENJ. 
ENJ. 
ENJ. 

ATR.  ENJ,  LYR  SHC,  UCC. 
AlP,  ATR,  BCP  DUP  EKT,  GGC,  HCL,  LYP. 

PLC.  TOC,  USI,  (=>). 

{'). 

UCC. 

ENJ,  UCC. 

TNA,  VST 

WTH. 

ATR,  EKX,  HCL,  UCC. 

GAP. 

BAS. 

TX,  UCC,  WTK. 

PG,  TNA,  VST  (*). 

PG.  TNA.  VST  (^). 

SHX 

PG,  TNA,  VST  {")■ 

SHX. 


See  footnotes  at  end  of  table. 


15-23 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers'  identification  codes 
statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Alcohols,  monohydric,  unsubstituted-Continued 
Alcohols  C,2  or  higher,  unmixed  (95%  or  more  pure) 
-Continued 

l-Tetradecanol  (Myristyl  alcohol) No 

Mixtures  of  alcohols: Yes 

Alcohol  mixtures,  C,,  or  lower  only Yes 

Mixtures  of  alcohols,  C-,2  and  higher Yes 

All  other  alcohol  mixtures  No 

Esters  of  monohydric  alcohols:    Yes 

0,2-0,5  alcohol-lactates  No 

Allyl  methacrylate No 

Amyl  acetates: 

Amyl  acetate  (n-Pentyl  acetate)    No 

Butyl  acetates: 

n-Butyl  acetate   Yes 

Isobutyl  acetate No 

Butyl  acrylate   Yes 

sec-Butyl  chloroformate  No 

Butyl  formate    No 

Butyl  lactate   No 

Butyl  maleate  No 

Butyl  mercaptopropionate No 

Butyl  methacrylate   No 

Butyl  oleate No 

n-Butyl  perchlorocrotonate No 

Oarboxyethyl  acrylate No 

Cetyleicosyf  methacrylate No 

Oetyl  lactate  No 

Diallyl  maleate   No 

Dibutyl  maleate No 

Didecyl  adipate No 

Diethyl  carbonate  (Ethyl  cart)onate)   No 

Di(2-ethyl-1  -hexyl)  maleate    No 

Diethyl  maleate No 

Diethyl  oxalate  (Ethyl  oxalate)   No 

Dilauryl-3,3'-thiodipropionate  Yes 

Dimethyl  carbonate    No 

Dioctyl  maleate No 

Distearyl-3,3'-thiodipropionate Yes 

Dithiobis(stearyl  propionate) No 

Ditridecyi  maleate No 

Di(tridecyl)-3,3'-thiodipropionate    No 

Dodecenyl  succinic  acid No 

Dodecenylsuccinic  lactate   No 

Dodecylpientadecyl  methacrylate No 

2-Ethoxyethyl  acetate No 

Ethyl  acetate  (100%  basis) Yes 

Ethyl  acetoacetate   No 

Ethyl  acrylate    Yes 

Ethyl  chloroformate    No 

Ethyl  chlorothioformate No 

Ethyl  3-ethoxy  propionate No 

2-Ethyl-1  -hexyl  acetate No 

2-Ethyl-1 -hexyl  acrylate   Yes 

2-Ethythexyl  chloroformate No 

2-Ethyl-1  -hexyl  methacrylate   No 

Ethyl  maleate,  mono No 

Ethyl  methacrylate   No 


PG,  VST,  (2). 

BAS,  PG,  SHC,  TNA,  UOC,  VST 
PG,  SHC.  TNA,  VST  (^). 
VST 

VND. 
OPS. 

UCO. 

BAS,  EKT  HOL,  UOC. 

BAS,  EKT  HOL,  UOC. 

BAS,  HOL,  RH,  UCC. 

PPG,  VOM,  WTL. 

AMB. 

OPS. 

SOP 

EVN. 

DUP,  RH. 

ELC. 

MAL. 

RDA. 

RH. 

VND. 

RDA. 

ART  NOD. 

OOP. 

PPG. 

OHP,  SHX. 

ACY 

(2). 

COW,  EVN,  WTO. 

PPG. 

ART  NOD. 

AOY  COW,  EVN.  WTO. 

EVN. 

DUP.  EFH. 

EVN,  WTO. 

HMY 

SM. 

RH 

ONE,  UOC. 

EKT  EKX,  HCL.  MON.  UCC. 

BRD,  EKT. 

HCL.  RH,  UCO. 

PPG. 

Id. 

EKT,  TX. 

EKT. 

BAS.  HCL.  PPG.  UCC.  VOM. 

HCL.  WTL. 

DUP 

RDA. 

DUP. 


See  footnotes  at  end  of  table. 


15-24 


Synthetic  Organic  Chemicals,  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identificatior)  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '  (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Esters  of  monohydric  alcohols-Continued 

Ethyl  suKate  (Diethyl  sulfate) No  ICI,  UCC. 

Fatty  acid  esters,  not  included  with  plasticizers  or 

surface  active  agents: Yes 

Diisopropyl  dimerate No  SBC. 

Diisostearyl  dimerate    No  SBC. 

Dioctyl  dimerate   No  WTC. 

Docosanyl  docosenoate No  SBC. 

2-Ethylhexyl  stearate    No  BRI. 

Isocetyl  stearate  No  VND.  WTC. 

isopropyl  linoleate No  VND. 

isostearyl  isostearate   No  SBC. 

Methyl  behenate No  WTC. 

Methyl  esters  of  coconut  oil    No  PG. 

Methyl  esters  of  lard  oil No  FER. 

Methyl  esters  of  tallow    Yes  CHL.  FER,  WTC,  {^). 

Methyl  12-hydroxystearatG No  CAS. 

Methyl  iso-octadecenoate No  SYL. 

Methyl  linoleate No  HRT 

Methyl  oleate    No  CHL. 

Methyl  pentachlorostearate No  VCM. 

Methyl  stearate No  CHL,  WTC. 

Myristyl  mynstate   Yes  RDA,  SBC,  VND. 

Myristyl  stearate  No  WTC. 

Stearyl  stearate No  RDA. 

Tridecyl  stearate No  HCL,  RDA,  WTC. 

Fatty  acid  esters,  not  Included  with 

plasticizers  surface-active  agents No  BRD,  SCP,  SHX,  WTC. 

Hexyl  acetate  No  ENJ. 

Hexyl  acrylate No  CPS. 

Hexyl  neopentanoate No  SBC. 

Isobutyl  acrylate No  BAS. 

Isobutyl  chloroformate    No  PPG,  VCM. 

Isobutyl  isobutyrate No  EKX. 

Isobutyl  methacrylato No  RH. 

Isodecyl  acrylate No  CPS,  RDA. 

Isodecyl  methacrylate No  RH. 

isooctyl  acrylate   No  RDA. 

Iso-octyl  mercaptoacetate    No  CCW,  EVN. 

lso-octyl-3-mercaptopropionate No  EVN. 

Isopropyl  acetate    Yes  EKT,  HCL,  UCC. 

Isopropyl  chloroformate   No  PPG,  VCM. 

Isostearyl  neopentanoate No  SBC,  VND. 

Lauryl  acrylate    No  CPS. 

Lauryl  lactate    No  VND. 

Lauryl  methacrylate   No  CPS,  RH. 

1  -Methoxy-2-ethyl  acetate   No  EKX. 

2-Methoxyethyl  acrylate No  CPS. 

Methyl  acetoacetato No  BRD.  EKT. 

Methyl  acrylate.  monomer  No  HCL. 

Methyl  butyrate No  PD. 

Methyl  chloroformate   No  PPG. 

Methyl  3,3-dimethyl-4-pentenoate  No  FMN. 

Methyl  formate No  HCL. 

Methyl  methacrylate,  monomer    Yes  CYR,  DUP  RH. 

Methyl  pivaloylacelate   No  EKT. 

Methyl  sulfate  (Dimethyl  sulfate) No  DUP  NOD. 

Myristyl  lactate  No  CAS,  SBC,  VND. 

Octadecyl-3-mercaplopropionato No  EVN 


See  footnotes  at  end  of  table. 


15-25 


Section  IS 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 

Separate  Manufacturers '  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Esters  of  monohydric  alcohols-Continued 

Phosphorus  acid  esters: Yes 

Alkoxylated  acid  phosphate  No  ALW. 

Amy!  hydrogen  phosphate  No  HK. 

Bis-(2-chloroethyl)-2-chloroethylphosphonate No  ALW. 

Bis(2-ethylhexyl)hydrogen  phosphite No  ALW. 

Butyl  acid  phosphate   No  ALW,  HK. 

ChloroalkyI  diphosphate  ester,  neutral No  ALW. 

ChloroaikyI  phosphate  ester No  ALW. 

Dibutyl  butylphosphonate No  ALW. 

Dibutyl  hydrogen  phosphite   No  ALW. 

Dibutyl  pyrophosphate  No  ALW. 

Diethylhexyl  phosphoric  acid   No  ALW. 

Diethyl  hydrogen  phosphite   No  ALW. 

Diethyl  phosphorochloridothionate No  TNA. 

Dimethyl  hydrogen  phosphite No  ALW. 

Dimethyl  methylphosphonate No  ALW. 

2-Ethylhexyl  hydrogen  phosphate    No  ALW. 

Iso-octyl  hydrogen  phosphate    No  ALW. 

Methyl  dihydrogen  phosphate    No  HK. 

Mixed  dialkyi  hydrogen  phosphates,  amine  salts  ....  No  ELC. 

mono(2-Ethylhexyl)-2-ethyihexyl-phosphonicacid  . . .  No  ALW. 

Stearyl  acid  phosphate No  HK. 

Tetraisopropylmethylenediphosphonate  No  ALW. 

Tetrakis(2-chloroethyl)ethylene  diphosphate   No  OMC. 

Tetrakis(2-chloroisopropyl)ethylene  diphosphate 

(T-RDT) No  OMC. 

TrialkyI  thiophosphite  No  GE. 

Triethyl  phosphite No  ALW,  ICI. 

Triethyl  phosphonacetate No  AMV. 

Triisodecylphosphite No  WTC. 

Triisooctyl  phosphite No  ALW,  GE. 

Triisopropyl  phosphite    No  ALW. 

Trimethyl  phosphite    No  ALW,  ICI. 

Tns(2-chloroethyl)phosphate  No  PEL. 

Tris(2<hloroethyl)  phosphite   No  ALW. 

Tris-2<hloropropyl  phosphate  No  ALW,  PEL. 

Tris(1,3-dichloro-2-propy I)  phosphate    No  ALW. 

Tris(2-ethylhexyl)phosphite    No  ALW. 

All  other  phosphorus  acid  esters   No  ALW,  ('). 

Propyl  acetate   Yes  BAS,  EKT,  HCL,  UCC. 

n-Propyl  chloroformate No  WTL. 

Propyl  chlorothioformate   No  TX. 

Stearyl  methacrylate    No  CPS,  RH,  TX. 

Tetraethyl  orthosilicate  (Tetraethyl  silicate)    No  UCC. 

Tetrapropyl  silicate No  UCC. 

Titanic  acid  esters: 

Bis[2-(bis[2-hydroxyethyl]amino)ethyl) 

diisopropyl  titanate   No  DUP. 

Bis(ethyl-3-oxobutanato)bis(2-propanolato) 

titanium No  DUP. 

Di{hydroxy)bis(ammoniumlactato)titanium No  DUP. 

Tetrabutyl  titanate No  DUP. 

Tetraisopropyl  titanate    No  DUP. 

Tetrakis(2-ethylhexyl)titanate No  DUP  NOD. 

Triethanolamine  titanate No  NOD. 

All  other  titanic  acid  esters No  DUP. 

Triethyl  onhoacetate    No  NOD. 

Triethyl  orthoformate    No  NOD. 


See  footnotes  at  end  ot  table. 


15-26 


Synthetic  Organic  Chemicals.  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers'  identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 

Esters  of  monohydric  alcohols-Continued 

Triethyl  orthopropionate  No 

Trimethyl  orthoacetate   No 

Trimethyl  orlhoformate No 

Vinyl  acetate,  monomer  Yes 

All  other  monohydric  alcohol  esters No 

Polyhydric  alcohols: Yes 

2-Bromo-2-nitropropanediol No 

1 .2(and  1 ,3)-Butanediol   No 

1 ,4-Butanediol   Yes 

2-Butene-1 ,4-diol  No, 

2-Butyne-1 ,4-diol   No 

3-Chloro-1,2-propanediol  (Glycerol  a-chlorohydrin)  . 

2, 2-Dimethyl-1, 3-propanediol  (Neopentyl  glycol)    ...  No 

Ethylene  glycol Yes 

2-Ethyl-1 ,3-hexanediol No 

2-Ethyl-2-(hydroxymethyl)-1, 3-propanediol 

(Trimethylolpropane) No 

Glycerol,  synthetic  only    No 

1 ,6-Hexanediol No 

2-(Hydroxymethyl)-2-methyl-1, 3-propanediol 

(Trimethylolethane) No 

Mannrtol  No 

3-Mercapto-1,2-propanediol  (Thioglycerol) No 

2-Methyl-2,4-pentanediol  (Hexylene  glycol)    No 

Pentaerythritol    Yes 

Propylene  glycol  (1 ,2-Propanediol) Yes 

Sorbitol  (70%  by  weight)    Yes 

Sorbitol,  crystalline Yes 

Starch,  hydrolyzed  and  hydrogenated  No 

2.2,4-Trimethyl-1,3-pentanediol No 

Xylitol  (1,2,3,4,5-Pentane(OH)5)  No 

All  other  polyhydric  alcohols No 

Esters  and  ethers  of  polyhydric  alcohols: Yes 

Polyhydric  alcohol  esters: Yes 

2-(2-Butoxyethoxy)ethyl  acetate Yes 

2-Butoxyethyl  acetate Yes 

1 ,3-Butylene  glycol  ditiorate/hexylene  glycol 

twric  anhydride No 

1 .3-Butylene  glycol  dimethacryiate No 

Diethylene  glycol  adipate No 

Diethylene  glycol,  borated    No 

Diethylene  glycol  dimethacryiate   No 

Dipropylene  glycol  monomethyl  ether  acetate No 

2-(2-Ethoxyethoxy)othyl  acetate No 

Ethylene  glycol  diacetate  No 

Ethylene  glycol  dimercaptoacetate No 

Ethylene  glycol  dimethacryiate No 

Glycerides,  mixed  C,4-,s  and  C,s-ia,  mono-  and  di-  . .  Yes 

Glyceryl  diacetate  (Diacetin)    No 

Glyceryl  monoacetate  (Monoacetin)  No 

Glyceryl  monothioglycolate    No 

Glyceryl  triacetate  (Triacetin) No 

Hydroxyethyl  acrylale No 

Hydroxyethyl  methacrylate No 

Hydroxypropyl  acrylate No 

Hydroxypropyl  methacrylate No 


NOD. 
NOD. 
NOD. 

DUP,  HCL,  UCC,  USI. 
BAS,  COC,  DUP  ENJ,  f^ON,  RDA,  SBC. 
SCP  SDC,  VND,  (2),  (2). 

ANG. 

HCL 

ATR,'  BAS,  DUP  GAR 

GAR 

BAS,  GAR 

DIX,  EVN. 

BAS  EKX 

BAS!  CNE,  CXI,  DOW,  EKT,  EKX,  HCL. 

OMC,  PDG,  PLC,  SCP  SHC,  TX,  UCC. 

USi.  (2). 
SCP  UCC. 

HCL 

BRD,  DOW,  SYP  C). 

BAS,  CXI. 

IMC,  QTR. 

ICI. 

EVN. 

ATR,  SHC,  UCC. 

AOU,  HCL,  PST  RDA. 

ATR,  DOW,  OMC,  TX,  UCC. 

BRD,  HOR  ICI,  PRZ,  ROT 

BRD,  EHC.  PRZ,  ROT 

BRD. 

EKX. 

BRD. 

ICI,  QKO. 


CNE,  EKT,  UCC. 
CNE,  EKT  UCC. 

USB. 

CPS. 

HAL. 

OMC. 

CPS. 

(2). 

EKT 

EKT. 

EVN. 

CPS 

BRD,  SHX,  WTC. 

HAL. 

HAL. 

EVN,  WTC. 

EKT. 

DOW,  RH. 

RDA,  RH. 

DOW,  RH. 

RH 


See  footnotes  at  end  of  table 


15-27 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  identHication  codes 
statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Esters  and  ethers  of  polyhydric  alcohols-Continued 
Polyhydric  alcohol  esters-Continued 

2-Methoxyethyl  acetate    No 

2-Methoxyethyl  carbonate   No 

1-Methoxy-2-propyl  acetate  No 

Neopentyi  glycol  oleate    No 

Neopentyl  glycol  vegetable  oil  ester No 

Pentaerythritol  tetrakis  (3-Mercaptopropionate) No 

Pentaerythritol  tetrastearate No 

Polyethylene  glycol  oleate   No 

Polypropylene  glycol  ester No 

Propylene  glycol  dicaprylatecaprate No 

Sucrose  octa-acetate No 

Trimethylolpropane  decanoic  acid  ester No 

Trimethylolpropane  tallowate  (TMP  tallowate No 

Trimethylolpropane  triacrylate    No 

Trinfiethylolpropane  trimethacrylate    No 

Trimethylolpropane  trioleate  (TMP  trioleate) No 

Trimethylolpropane  tris-3-mercaptopropionate No 

2,2,3-Trimethyl-1,3-pentanediolmonoisobutyrate   ...  No 

Tripropylene  glycol  diacrylate No 

All  other  polyhydric  alcohol  esters   No 

Polyhydric  alcohol  ethers: Yes 

Bis(2-butoxyethyl)ether  (Diethylene  glycol  di-n- 

butyl  ether)   No 

Bis(2-ethoxyethyl)ether  (Diethylene  glycol 

diethyl  ether) No 

Bis(2-(2-methoxyethoxy)ethyl]  ether 

(Tetraethylene  glycol  dimethyl  ether)   No 

Bis(2-methoxyethyl)ether  (Diethylene  glycol 

dimethyl  ether)   No 

2-Butoxyethanol  (Ethylene  glycol  monobutyl  ether)    .  Yes 

2-(2-Butoxyethoxy)ethanol  (Diethylene  glycol 

monobutyl  ether) Yes 

2-[2-(2-Butoxyethoxy)ethoxy)ethanol  (Triethyiene 

glycol  monobutyl  ether) Yes 

1  -Butoxyethoxy-2-propanol   No 

i-Butyraldehyde  trimer   No 

Diethylene  glycol   Yes 

Diethylene  glycol  mono-n-propyl  ether No 

Dimethoxyethane  (Ethylene  glycol  dimethyl  ether)  . . 

2-Ethoxyethanol  (Ethylene  glycol  monoethyl  ether)   .  Yes 
2-(2-Ethoxyethoxy)ethanol  (Diethylene  glycol 

monoethyl  ether) Yes 

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol  (Triethyiene 

glycol  monoethyl  ether) Yes 

Ethylene  glycol  di-tributyl  ether No 

Ethylene  glycol  di-triethyl  ether No 

Ethyl  ethers  of  tetra  and  higher  ethylene  glycols 

(high  boiling) No 

Glycerol  monoallyl  ether No 

Glycol  ethers  derived  from  propylene  oxide: 

Dipropylene  glycol   Yes 

Dipropylene  glycol  monomethyl  ether  (3-(3- 

methoxypropoxy)propanol) No 

Ethylene  glycol  di-tri-propyl  ether No 

Propylene  glycol  monomethyl  ether  (1-Methoxy-2- 

propanol) No 

Tripropylene  glycol Yes 


UCC. 

EKT 

(2). 

OOP. 

QCP. 

EVN. 

HPG. 

SM. 

SM. 

ATR. 

HFT. 

SM. 

QCP. 

GPS. 

GPS. 

EFH. 

EVN. 

EKX. 

GPS 

DUP.'  EVN,  GPI.  SQA.  TX.  UCC. 


PER. 

PER. 

PER. 

PER. 

GNE.  DOW.  EKX,  SHC.  UCC. 

GNE.  EKX.  SHC.  UCC. 

GNE.  DOW,  UCC. 

UCC. 

(^. 

BAS.  GNE.  DOW.  EKX.  HCL.  OMC.  PDG. 

SHC,  TX.  UCC. 
EKX.  SQA. 
PER. 
GNE.  EKX,  OMC.  UCC. 

GNE.  EKX.  OMC.  UCC. 

GNE.  OMC.  UCC. 
EKX.  PER. 
EKX. 

OMC. 
RDA. 

ATR.  DOW.  OMC.  UCC.  {'). 

OMG.  (^). 
EKX. 

OMG.  C). 

ATR.  DOW,  UCC.  {'). 


See  footnotes  at  end  of  table. 
15-28 


Syntheuc  Organic  Chemicals.  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  identification  codes 
statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Esters  and  ethers  of  polyhydric  alcohols-Continued 
Polyhydric  alcohol  ethers-Continued 
Glycol  ethers  derived  from  propylene  oxide-Continued 

Tripropylene  glycol  monomethyl  ether  {3-(3-[3- 

methoxypropoxy]propoxy)propanol)   No 

All  other  propylene  glycol  ethers No 

2-[2-(Hexyloxy)ethoxyjethanol   No 

2-Methoxyethanol  (Ethylene  glycol  monomethyl 

ether) Yes 

2-(2-Methoxyethoxy)ethanol  (Diethylene  glycol 

monomethyl  ether)    Yes 

2-[2-(2-Methoxyethoxy)ethoxy]ethanol 

(Triethylene  glycol  monomethyl  ether)    Yes 

2-(2-Methoxyethoxy)ethyl-2-methoxyethyl  ether 

(Triethylene  glycol  dimethyl  ether)    No 

Methoxypolyethylene  glycol    Yes 

Paraformaldehyde    No 

Poiyelher  polyols  based  on  propylene  oxide: 

Polypropylene  glycol Yes 

Polypropylene  glycol  butyl  ether  (Poiypropoxy 

butyl  ether) No 

Polypropylene  glycol  butyl  ether,  ethoxyiated 

(Poiypropoxy  butyl  ether,  ethoxyiated)    No 

Polypropylene  glycol  glycerol  triether 

(Polypropoxyglyceryl  triether)    No 

All  other  polyether  polyols  based  on 

propylene  oxide No 

Polyethoxy  propoxy  diethylene  glycol  ether No 

Polyethylene  glycol No 

Polyethylene  glycol  butyl  ether,  propoxylated No 

Polyethylene  glycol  dimethyl  ether No 

Polyglycols,  ethylene  glycol  and  glycol  ether, 

mixed No 

Polyoxyalkylene  glycol No 

Polyoxypropylene  polyoxyethylene  glycol,  mixed  ....  No 

Polytetramethyiene  glycol  ether Yes 

Propoxyethanol  (Ethylene  glycol  monopropyl  ether)    . 

Propylene  glycol,  alkoxylated No 

Sorbitol,  alkoxylated No 

Sorbitol,  ethoxyiated Yes 

Sorbitol  monooleate No 

Sorbitol  monostearate    No 

Tetraethylene  glycol  Yes 

Tetra/penta  glycols,  mixed   No 

2.2'-Thiodielhanol  (Thiodiglycol) Yes 

Triethylene  glycol  No 

All  other  polyhydric  alcohol  ethers   No 

Bromlnated,  chlorinated  and  fiuorinated  hydrocarbons: 
Brominated  (including  bromochlonnated) 

hydrocartxsns; No 

1-Bromobutane  (n-Butyi  bromide) No 

Bromochloromethane No 

Bromodocosane  No 

1  -Bromododecane    No 

Bromoethane  (Ethyl  bromide) No 

1-Bromohexadecane    No 

1-Bromohexane  (n-Hexyl  bromide) No 


OMC,  (2). 

ATR. 

UCC. 

ONE,  OMC.  UCC. 

CNE,  DOW,  OMC.  UCC. 

CNE,  DOW,  OMC,  TX,  UCC. 

PER,  OMC. 
PPG,  RDA.  UCC. 
HCL. 

BAS.  DOW.  OMC,  PPG,  RDA.  TX,  (\  (\ 

PPG. 

BAS,  PPG. 

PPG,  RDA. 

ATR. 
RDA. 
ABB,  BAS.  DOW.  OMC,  PPG,  RDA,  SHX. 

UCC, 
ICI. 
DAN,  SHX 

HCL  UCC,  (\ 

0.  h 

OMC. 

UCC. 

BAS,  DUP,  QKO, 

EKX 

(^ 

ICI.  PPG,  (2). 

WTC. 

WTC. 

DOW,  EKX,  UCC,  (\ 

CNE,  CXI. 

MRT  OMC,  PLC,  RDA. 

CNE,  CXI,  DOW,  EKX,  HCL.  OMC.  PDG. 

SHC.  TX,  UCC,  (^. 

DOW,  DUP  MIL,  SCP  UCC. 


DAZ,  GTL. 

TNA. 

HMY 

HMY 

GTL. 

HMY 

HMY 


See  footnotes  at  end  of  table. 


15-29 


Section  IS 

Table  15-2— Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate 
statistics ' 


Manufacturers'  identification  codes 
(according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Brominated,  chlorinated  and  fluorinated  hydrocarbons 

-Continued 
Brominated  (including  bromochlorinated) 

hydrocarbons-Continued 

1-Bromo-3-methyl-2-butene No 

1  -Bromo-octadecane  No 

1  -Bromopropane  (n-Propyi  bromide) No 

1 ,4-Dibromobutane No 

Dibromomethane  (Methylene  bromide)  No 

Vinyl  bromide  (Bromoethylene) No 

All  other  brominated  (Including  bromochlorinated) 

hydrocarbons   No 

Chlorinated  (not  otherwise  halogenated) 

hydrocarbons: Yes 

CartxDn  tetrachloride Yes 

Chlorinated  paraffins  (Cio-Cso):    No 

Chlorinated  paraffins,  35-64%  chlorine    Yes 

Chlorinated  paraffins,  less  than  35%  chlorine    No 

Chlorinated  paraffins,  65%  or  more  chlorine   Yes 

1 -Chlorobutane  (n-Butyl  chloride) No 

Chloroform  Yes 

Chloromethane  (Methyl  chloride)    Yes 

3-Chloropropene  (Allyl  chloride)   No 

1 ,2-Dichloroethane  (Ethylene  dichloride)    Yes 

2,3-Dichloropropene No 

Ethyl  chloride  (Chloroethane) Yes 

Lauryl  chlorides    No 

Methylene  chloride  (Dichloromethane) Yes 

Octyl  chloride  No 

Perchloroethylene  (Tetrachloroethane) Yes 

Tetrahydroalloocimenyl  hydrochbride  (Tetrahydro- 

dimethylatriene  hydrochloride No 

1 ,1 ,1  -Trichloroethane  (Methyl  chloroform)    Yes 

1,1,2-Trichloroethane  (Vinyl  trichloride) No 

Trichloroethylene   No 

1 ,2,3-Trichloropropane No 

Vinyl  chloride,  monomer  (Chloroethylene)    Yes 

Vmylidene  chloride,  monomer  (1,1- 

Dichloroethylene)  No 

All  other  chlorinated  (Not  otherwise  halogenated) 

hydrocarbons   No 

Fluorinated  (including  other  f luorohalogenated) 

hydrocarbons: Yes 

Bromochlorodifluoromethane No 

2-Bromo-1-chloro-1,2,2-trifluoroethane   No 

2-Bromo-2-chloro-1,1.1-trifluoroethane  (Halothane)    .  No 

Bromotrifluoromethane No 

1-Chloro-1,1-difluoroethane(F-142b) No 

Chloroditluoromethane  (F-22)    Yes 

2-Chloro-1,1,1,2-tetrafluoroethane(F-124)    No 

Chlorotrlfluoroethylene  (Trifluorovinyl  chloride) No 

2-Chloro-1 , 1 ,2-trifluoroethy I  methyl  ether No 

Chlorotrifluoromethane  (F-13)    No 

Dibromodifluoromethane   No 

1,2-Dibromo-1,1,2,2-tetrafluoroethane No 

Dichlorodifluoromethane  (F-12)  Yes 

Dichlorotetralluoroethane  (F-114) No 

Dichloro-trifluoroethane  (F-123) No 


SD. 

HMY 

DAZ.  GTL. 

HMY 

TNA. 

TNA. 

FER.  HMY  TNA. 


AKZ.  DOW.  FRO.  HK.  LOP. 

DVC.  FER.  HK. 

DVC.  SHC. 

DVC.  FER.  HK. 

ALW. 

DOW.  FRO.  HK. 

DCC.  DOW.  FRO.  HK.  LCP.  SPD.  VST 

DOW.  SHC. 

ALW,  BFG.  DOW.  FOR,  FRO.  GGC.  HK. 

OMC,  PLC.  PPG.  SHC.  VST 
DOW.  SHC. 

DOW.  DUP,  LCP.  PPG.  TNA. 
BRD. 

DOW.  FRO,  HK.  LCP. 
BRD. 
DOW,  FRO,  HK,  MIL.  PPG. 

NCI. 

DOW.  FRO,  PPG. 
DOW. 

DOW.  PPG. 
DOW. 

BCP  BFG.  DOW.  FOR.  GGC.  HK.  PPG. 
VST 

DOW.  PPG. 

BRD,  TNA. 


GTL. 

HOC. 

HOC. 

DUP,  GTL. 

PAS. 

ACS,  DUP.  LRO.  PAS.  RCN. 

{')■ 

ACS. 

OH. 

DUP.  GTL. 

GTL. 

{'). 

ACS.  DUP,  LRO,  PAS,  RCN. 

ACS,  DUP. 

DIX,  HOC. 


See  footnotes  al  end  of  table. 


15-30 


Synthetic  Organic  Chemicals.  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 

Separate  Manufacturers'  identification  codes 

Miscellaneous  cyclic  and  acyclic  chemicals  statistics '         (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic-Continued 
Brominated,  chlorinated  and  fiuorinated  hydrocartxjns 
-Continued 
Fiuorinated  (including  other  fluorohalogenated) 
hydrocarbons-Continued 

1,1-Difluoroethane No  DUP.  {^). 

Hexafluoropropylene,  monomer No  DUP. 

1-lodopertluorohexane  No  DUP. 

1 ,2,2.2-Tetrafluoroethane  (F-134a) No  HOC. 

Tetrafluoroethylene  (F-1114) No  DUP. 

Tetrafluoromethane(F-14)    No  DUP. 

Trichlorofluoromethane  (F-11) Yes  ACS,  DUP  LRO,  PAS,  RCN. 

Trichlorotritluoroethane  (F-11 3) No  ACS,  DIX.  DUP. 

Trifluoropropjene  No  HOC. 

Vinyl  fluoride,  monomer    No  DUP. 

Vinylidene  fluoride,  monomer  No  PAS. 

All  other  fiuorinated  (Including  other  fluoro- 
halogenated) hydrocarbons No  DUP,  HOC,  REG.  C). 

Other  miscellaneous  acyclic  chemicals: Yes 

lodinated  (not  otherwise  halogenated)  hydrocarbons: 

Diiodomethane  (l\^ethylene  iodide) No  DPW. 

lodoethane  (Ethyl  iodide),  non-medical No  DPW,  RSA. 

lodomethane  (Methyl  iodide)  No  RSA. 

All  other  iodinated  (Not  otherwise  halogenated) 

hydrocarbons    No  DPW,  RSA, 

Acetylacetonates: 

Aluminum  acetylacetonate   No  MCK. 

Titanium  acetylacetonate    No  NOD. 

All  other  acetylacetonates No  MCK. 

Acyclic  peroxides: Yes 

Acetylacetone  peroxide No  CAD. 

tert-Amyl  hydroperoxide    No  WTC,  WTL. 

t-Amylperoxy  acetate    No  WTL. 

t-Amylperoxy  neodecanoate No  WTL. 

t-Amylperoxy  pivalate  No  WTL. 

2-Butanone  peroxide  (MEK  peroxide) Yes  CAD.  FRE,  NOC.  WTC.  WTL. 

n-Bulyl-4.4-bis(t-butylperoxy]valerate No  WTL. 

t-Butyl-2-ethylhexyl  monoperoxycartxjnate No  WTL. 

ten-Butyl  hydroperoxide    No  ATR,  FRE,  WTC,  WTL. 

tert-Butyl  peroxide  (Di-tert-butyl  peroxide)    No  WTC,  WTL. 

tert-Butyl  peroxyacetate    No  AZT,  WTL. 

tert-Butyl  peroxy-2-ethylhexanoate Yes  AZT,  WTC,  WTL. 

tert-Butyl  peroxyisobutyrate    No  WTL. 

tert-Butyl  peroxyisopropylcartxinate  No  WTL. 

tert-Butylperoxy  maleic  acid   No  WTC,  WTL. 

tert-Butyl  peroxyneodecanoate No  WTC.  WTL. 

tert-Butyl  peroxyneoheptanoate    No  WTC. 

tert-Butyl  peroxypivalate  No  AZT,  WTC. 

DecanoyI  peroxide    No  WTL. 

Di(sec-butyl)peroxydicartx)nate    No  WTL. 

Di-(2-ethylhexyl)  peroxydicarbonate No  WTC,  WTL. 

2,5-Dihydroperoxy-2,5-dimethylhexane    No  WTL. 

DiisononanoyI  peroxide No  WTL. 

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane  ....  No  AZT,  WTL. 

2.5-Dimethyl-2,5-di(lert-butylperoxy)hexyne-3  .  .  No  AZT,  WTL. 

2,5-Dimethyl-2.5-di(2-ethylhexanoyl  peroxy)hexane  WTC,  WTL. 

1 . 1  -Dimethyl-3-hydroxybuty  l-peroxy  neohexanoate  No  WTL. 

Di-n-propyl  peroxydicarbonate   No  WTL. 

Ethyl  3,3-di(t-butyl  peroxy)  butyrate    No  WTL. 

LauroyI  peroxide  No  WTL. 

2,4-Pentanedione  peroxide No  WTL. 


See  footnotes  at  end  of  table. 


15-31 


Section  15 

Table  15-2— Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate  Manufacturers' identification  codes 

statistics '         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Other  miscellaneous  acyclic  chemicals-Continued 
Acyclic  peroxides-Continued 

Peroxyacetic  acid  (Peracetic  acid)  No 

Succinyl  peroxide   No 

Tertiary  amy!  per-2-ethylhexanoate    No 

n-Butanol,  ethoxylated  No 

Carbon  disulfide No 

Carboxylic  acid  all^oxyjates   No 

Epoxides,  ethers,  and  acetals: Yes 

Ethyl-3.3-di(t-amylperoxy)butyrate No 

Bis(2-chloroethyl)ether  (Dichlorodiethyl  ether)    ...  No 

Butylene  oxide    No 

Butyl  vinyl  ether    No 

Chloromethyl  methyl  ether  No 

2.2-Dichloro-1,1-difluoroethyl  methyl  ether No 

Diethoxyethane No 

Dimethyl  sulfone No 

Epichlorohydrin No 

Ethylene  oxide    Yes 

Ethyl  ether No 

Ethyl  vinyl  ether    No 

Glycidol  (2,3-Epoxy-1-propanol)   No 

Glycidyl  ethers: 

Alky!  glycidyl  ether.  Ci2-Ci4  and  Ciz-Cig No 

Alkyl  glycidyl  ethers,  Ce-Cio    No 

1  -(Allyloxy)-2,3-epoxypropane  (Allyl  glycidyl 

ether) No 

1 .4-Butanediol  diglycidyl  ether    No 

1-Buloxy-2,3-epoxypropane  (Butyl  glycidyl 

ether) No 

tert-Butyl  glycidyl  ether  No 

Glycerol  polyglycidyl  ether    No 

Polyol  glycidyl  ether    No 

Isopropyl  ether   No 

Methylal  (Dimethoxymethane) No 

Methyl  vinyl  ether  No 

Propylene  oxide   No 

1,1 ,3,3-Tetramethoxypropane No 

All  other  epoxides,  ethers,  acetals  No 

Ethyl  succinyl  chloride   No 

Ethytthioacetate  No 

Fats  and  oils,  chemically  modified: Yes 

Brominated  vegetable  oil    No 

Castor  oil,  hydrogenated No 

Castor  oil,  polymerized No 

Chlorinated  fatty  materials   No 

Hydrogenated  menhaden  fish  oil    No 

Hydrogenated  tallow  glycerldes   Yes 

Tallow,  partially  hydrogenated No 

Vegetable  glycerides,  hydrogenated No 

All  other  tats  and  oils,  chemically  modified No 

Glutaraldehyde  bis(sodium  bisulfite)    No 

Hydrocarbons:   Yes 

n-Decane    ,  .  fsjo 

Diisobutylene  isomers No 

3,3-Dimethylbutene No 

n-Dodecane    No 

Hexadecana No 

Hexadecene  No 


FMB. 
WTL. 

WTC.  WTL. 
WTL. 
PAS. 


WTL. 

BKM. 

DOW 

GAR 

RH. 

OH. 

WPG. 

CRZ. 

DOW, 

BAS. 

SUN, 

EKX. 

GAF. 

DIX. 


SHC 

CNE.boW.  EKX.  HCL,  OMC.  SHC. 
TX.  UCC,  USI.  VST 
USI. 


RDA. 
PDA. 

CPS.  RDA. 
RDA. 

CPS.  RDA. 

CPS, 

RDA. 

RDA. 

SHC. 

HCL. 

GAF,  UCC. 

ATR. 

NOD. 

GAF,  UCC. 

CWN. 

CAS. 

DOM. 

CAS. 

CAS. 

FER. 

CHL,  WTC. 

BRD.  CHL.  WTC. 

CHL. 

WTC. 

ARC.  BRD,  CJO,  EVN.  SCP  SM. 

FMT 

HMY,  PLC. 

NCI. 

PLC. 

HMY.  PLC. 

HMY 

{')■ 


See  footnotes  at  end  of  table. 


15-32 


Synthetic  Organic  Chemicals,  1990 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  identified 

by  manufacturer,  1990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  identification  codes 
statistics^         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Other  miscellaneous  acyclic  chemicals-Continued 
Hydrocarbons-Continued 

Myrcene   No 

n-Octadecane No 

n-Octane No 

n-Tetradecane No 

Tetradecene   No 

Tetrahydroalloocimene No 

Ail  other  hydrocartxjns  No 

2-M8rcaptoethanol No 

Methyl  sulfide  (Dimethyl  sulfide)  No 

Methyl  sulfoxide  (Dimethyl  suHoxide) No 

Octadecanoic  acid,  2-(1<art)Oxyethoxy)-1-methyl-2- 

oxoethyl  ester,  sodium  salt No 

Organo-aiuminum  compounds: 
Aluminum  di-sec-butoxide  acetoacetic  ester 

chelate No 

Aluminum  diisopropoxide  acetoacetic  ester  chelate 
Aluminum  ethyi-3-oxobutanoato-0\0^-dihydroxy  T-4 
Aluminum  [1 ,3-butanedialato(2)-0,0'](ethyl-3- 

oxobutanoato-O'.O-'-hydroxy  T-4   No 

Aluminum  isooctoxide,  diisopropoxide  No 

Aluminum  isopropoxide  (Aluminum  isopropyiate)  .  No 

Aluminum  tri-sec-butoxide   No 

Diethylaluminum  chloride No 

Diethyl  aluminum  ethoxide No 

Diethylaluminum  iodide No 

Diisobutylaluminum  chloride No 

Diisobutylaluminum  hydride   No 

Di-n-propylalumlnum  chloride No 

Ethylaluminum  dichloride  No 

Ethylaluminum  sesquichloride   No 

Isobutylaluminum  chloride    No 

isopropenylaluminum  No 

Oxoalumlnum  isopropoxide    No 

Oxoaluminum  stearate  No 

Oxyaluminum  octanoate No 

Polyol  aluminum  chelate No 

Tri-n-butylaluminum   No 

Triethylaluminum No 

Tri-n-hexyl  aluminum    No 

Triisobutylaluminum   No 

Trimethylaluminum No 

Tri-n-octylaluminum    No 

Tri-oxyaluminum  tri-isopropoxide  No 

All  other  organo-aiuminum  compounds    No 

Organo-boron  compounds:    Yes 

Boric  acid-amine  adducts No 

N-Methyl-methanamine  with  borane  (1:1)    No 

2-Methyl-2-propanamine  with  borane(1 :1 ) No 

Mixed  alcohol  borates No 

TriethyltMDrane No 

Trimethoxyboroxine    No 

Trimethyl  tx>rate   No 

N.N.N-Trimethyl  methanaminium  octahydrotriborate  No 

All  other  organo-boron  compounds No 

Organo-lithium  compounds: 

n-Butyllithium    No 

sec-Butyllithium No 

Lithium  hydroxystearate  No 

Organo-magnesium  compounds: 

Butyl  ethyl  magnesium   No 


SCM.  (2). 
HMY. 

HMY,  PLC. 
HMY 

(=^- 

NCi. 

DUP,  HMY.  WTK. 

MRT  PLC.  RDA. 

PLC. 

GAY 

WTC. 


CHT 

CHX  KCH. 
KCH. 

CHT 

KCH. 

CHT  KCH. 

CHT 

TNA.  TSA. 

TSA. 

TNA,  TSA. 

TNA,  TSA. 

TNA.  TSA. 

TSA. 

TNA(E).  TSA. 

TNA(E).  TSA. 

TNA.  TSA. 

TSA. 

KCH. 

CHT.  KCH. 

CHT.  KCH. 

SQA. 

TNA.  TSA. 

TNA(E).  TSA. 

TNA(E).  TSA. 

TNA(E).  TSA. 

TNA(E),  TSA. 

TNA,  TSA. 

CHT 

CHT  KCH,  TNA(E).  TSA. 

FER. 

0- 

MHI. 

(")• 

ADC.  HCL.  HXL.  RDA.  TSA,  (*). 

FTE. 
FTE. 
WTC. 

TSA. 


See  footnotes  at  end  of  table. 


15-33 


Section  15 

Table  15-2 — Continued 

Miscellaneous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1 990 


Miscellaneous  cyclic  and  acyclic  chemicals 


Separate         Manufacturers '  ider)tification  codes 
statistics^         (according  to  list  in  table  15-3) 


Miscellaneous  chemicals,  acyclic-Continued 
Other  miscellaneous  acyclic  chemicals-Continued 

Di-n-hexyl  magnesium   No 

Magnesium  methylate No 

Organo-silicon  compounds: 

N-Aminoethylaminopropyltrimethoxysilane No 

a-Chloropropyltrichlorosilane No 

Di-n-butylmagnesium No 

Chloropropyllrimethoxysilane Yes 

Chlorolrimethylsilane   No 

Dichlorodimethylsilane  No 

Dichloromethylsilane No 

Dichloromethylvinylsilane No 

Diisobutyl  dimethoxychloro  sliane No 

Divinyl  tetramethyldisiloxane    No 

a-Glycidoxypropyltrimethoxysilane No 

Hexamethyldisilazane Yes 

Hexyltrichlorosiiane No 

Isobutyltrimethoxysilane No 

Mercaptopropyltrimethoxysilane No 

a-Methacryloxypropyltrimethoxysilane No 

Methyltrimethoxysilane  and  poiymethyltrisiloxane   .  No 

N-Octyltriethoxy  silane  No 

Polyoxyalkene  silicones  No 

Silicone  fluids  Yes 

Tetramethyldisiloxane No 

Trichloromethylsilane  No 

Trichloropropylsilane No 

Trichlorovinylsiiane No 

Tris(2-methoxyethoxy)vinyl  silane No 

Tris(pentametnyldisiloxanyl)-3- 

methacrylatopropylsilane    No 

Vinyldimethylchlorosilane No 

Vinyttriethoxysilane No 

Vinyl  trimethoxy  silane   No 

All  other  organo-silicone  compounds  No 

Organo-tin  compounds: 

Dibutyltin  bis(Dutylmaleate  No 

Dibutyitin  bis(isooctylmercaptoacetate)   No 

Dibutyltin  dichloride No 

Dimethyltin  dichloride No 

Dimethyltin-IOTG   No 

Ester  tin  dilaurate  No 

Monomethyl  tin No 

Organotin  mercaptides No 

All  other  organo-tin  compounds  No 

Orqano-zinc  compounds: 

Diethylzinc    No 

All  other  organo-zinc  compounds No 

Perfluoroalkyl  polyether    No 

Phosgene  (Carbonyl  chloride)    Yes 

Polyalphaoiefins  No 

Polyhexafluoropropylene  oxide No 

Polymethacrylic  acid  esters   No 

Potassium  2-methyl-2-butanol   No 

Potassium  2-methyl-2-propanol  No 

Sodium  methoxide  (Sodium  methylate) No 

Trilluoroethanol No 

ZIrcoaluminate  compounds No 

All  other  miscellaneous  acylic  chemicals  No 


TSA. 
SOi. 

DOG.  NOD. 

DCC. 

TSA. 

DCC.  NOD.  UCC. 

DCC. 

DCC. 

DCC. 

DCC.  (2). 

NOD. 

NOD.  (2). 

NOD,  UCC. 

DCC.  NOD.  PCR. 


So 


CC.  NOD. 
NOD.  UCC. 
UCC. 
DCC.  UCC. 

{^. 

UCC. 

DCC.  SPD.  SWS.  UCC. 


g 


CC. 
DCC. 

DCC.  UCC. 
NOD. 

ARA. 

{\ 

NOD.  UCC. 

NOD. 

NOD.  SCP,  UCC.  (2).  (2).  (2). 

CCA. 

WTC. 

CCA.  WTC. 

WTC. 

WTC. 

CCA. 

CCW. 

')• 

Tw„. 

TSA. 

DUR 

DUP,  ICI.  OMC.  PPG.  VDM. 

USi. 

DUP. 

DUP.  WTL. 

HK.  OMC. 

HOC. 

KCH 

ASL.  BRS,  COC.  CWN,  EKT.  ENO.  EVN. 

HXL.  MCK,  MIL.  PAH.  PFZ.  PiC.  QCP. 

RSA.  SCP.  SHX.  TCC.  TNA.  TSA.  USR. 

WTL.  C). 


See  footnotes  at  end  of  table. 


15-34 


Synthetic  Organic  Chemicals.  1990 

Tabic  15-2— Continued 

MIsotllanaous  chemicals  for  which  U.S.  production  and/or  sales  were  either  reported  or  estimated,  Identified 

by  manufacturer,  1990 

Separate         Manufacturers '  identification  codes 
Miscellaneous  cyclic  and  acyclic  chemicals  statistics '        (according  to  list  in  table  15-3) 

Miscellaneous  chemicals,  acyclic — Continued 
Other  miscellaneous  acyclic  chemicals — Continued 

Mixtures  not  specificall/  itemized:   Yes 

Alcohols,  monohydnc,  and  their  esters,  Cg  and 

higher   No  EKX. 

Butyl  formcel No  HCL. 

Celtone No  HCL. 

Fatty  acid  residues Yes  BRD.  DRL.  SHX.  SYP.  WTO. 

Gluconic  acid  and  salts,  mixed No  PMP. 

Glycol  residues No  OMC. 

Methyl  formcel  No  HCL.  NOD. 

Oxidate  light  ends No  HCF. 

Oxo  process  bottoms No  CXI. 

Propionic  blends No  HCL. 

All  other  mixtures  not  specifically  itemized No  AlP.  DUP,  HCL.  LYP.  MON,  NES,  UCC. 

WAY 

'  Chemicals  for  which  separate  statistics  are  reported  in  this  section  are  indicated  by  Yes  '  Chemicals  for  which  data  are 
accepted  in  confidence  and  may  not  t>e  published  are  indicated  by  'No.' 

'  The  manufacturer  did  not  consent  to  his  identification  with  the  designated  products. 

Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  international  Trade  Commission. 


15-35 


Section  15 

Table  15-3 

Miscellaneous  cyclic  and  acyclic  chemicals:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


ABB Abbott  Laboratories 

AC  AC  &  S.  Inc. 

ACS Allied  Signal  Inc.,  Engineered  Material 

Sector 

ACY American  Cyanamid  Co. 

ADC Anderson  Development  Co. 

AlP Air  Products  &  Chemicals,  Inc. 

AKZ Akzo  Chemical,  Inc. 

ALI Anzon,  Inc. 

ALW Albright  &  Wilson.  Inc. 

AMB American  Bio-Synthetics  Corp. 

AMO    Amoco  Corp. 

AMV Amvac  Chemical  Corp. 

ANG Angus  Chemical  Co. 

AQU Aqualon  Co. 

ARA Syntex  Chemicals,  Inc. 

ARC Akzo  Chemicals,  Inc. 

ARS Arsynco,  Inc.,  Sub.  Div  of  Aceto  Corp. 

ART Aristech  Chemical  Corp. 

ARZ Arizona  Chemical  Co. 

ASH Ashland  Oil,  Inc. 

ASL Speciattychem  Products  Corp. 

ATL   Atlantic  Industries,  Inc. 

ATR Atlantic  Richfield  Co.,  Arco  Chemical 

Co. 

AZT Catalyst  Resources,  Inc. 

BAS BASF  Corp. 

BCC Buffalo  Color  Corp. 

BCP Borden  Chemical  &  Plastics  Delaware 

Limited 

BFG B.F.  Goodrich  Co. 

BFP American  Ingredients  Company 

BKC J.  T  Baker  Chemical  Co. 

BKM Buckman  Laboratories,  Inc. 

BOC Biocraft  Laboratories,  Inc. 

BOR Borden,  Inc.,  Packaging  &  Indus.  Prod. 

Div. 

BRD Lonza,  Inc. 

BRI Sedgefied  Specialities 

BTL  BTL  Specialty  Resin  Corp. 

BUG Synalloy  Corp.,  Blackman  Uhler 

Chemical  Div. 

CAD Akzo  Chemicals,  Inc. 

CAS Caschem,  Inc. 

CBD Chembond  Corp. 

CCA Akzo  Chemicals,  Inc. 

CCC C.N.C.  International,  Inc. 

CCW  Morion  International,  Inc., 

Speciality  Chemicals  Group 

CED Cedar  Chemical  Co. 

CGY Ciba-Geigy  Corp. 


CHD   Chemdesign  Corp. 

CHL Chemol,  Inc. 

CHP    C.  H.  Patrick  &  Co.,  Inc. 

CHT Chattem.  Inc. 

CJO C.  J.  Osborn  Chemical,  Inc. 

CKC   Cook  Composites  and  Polymers 

Company 

CNE   Oxy  Petrochemicals,  Inc. 

CNP   DSM  Chemicals,  North  America 

COC  Columbia  Organic  Chemicals  Co.,  Inc. 

CPS CPS  Chemical  Co.,  Inc. 

CRZ James  River  II  Corp. 

CWN Upjohn  Co.,  Fine  Chemicals 

CXI   Chemical  Exchange  Industries,  Inc. 

CYR   CYRO  Industries 

DAN    Dan  River  Inc.,  Chemical  Products  Div. 

DAZ Diaz  Chemical  Corp. 

DCC   Dow  Coming  Corp. 

DIX   Dixie  Chemical  Co.,  Inc. 

DKA Mobay  Synthetics  Corporation 

DOM Dominion  Products,  Inc. 

DOW Dow  Chemical  Co. 

DPW Deepwater,  Inc. 

DRL Unichema  North  America 

DUP   E.I.  duPont  de  Nemours  &  Co.,  Inc. 

Automotives  Products  Dept. 

Chemicals  &  Pigments  Dept. 

Petrochemicals  Dept. 

Polymer  Products  Dept. 
DVC   Dover  Chemical  Corp.  Sub.  of  ICC 

Industries,  Inc. 

DVR   Diversified  Technology,  Inc. 

EFH E.  F.  Houghton  &  Co. 

EHC    Ethichem  Corp. 

Eastman  Kodak  Co.: 

EKT Tennessee  Eastman  Co.  Div. 

EKX Texas  Eastman  Co.  Div. 

ELC EIco  Corp.  Sub.  of  Detrex  Chemical 

Industries,  Inc. 

ENJ Exxon  Chemical  Americas 

ENO   Enenco,  Inc. 

ESA East  Shore  Chemical  Co. 

EVN W.  R.  Grace  &  Co.,  Organic  Chemicals 

Div. 
Evans  Chemetk:s 
FER Ferro  Corp.: 

Bedford  Chemical  Div. 

Grant  Chemical  Div. 

Keil  Chemical  Div. 
FMB    FMC  Corp.,  Chemical  Products  Group 


See  note  at  end  of  table. 


15-36 


Synthetic  Organic  Chemicals.  1990 


Table  15-3 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code 


Name  of  company 


FMN FMC  Corp.,  Agricultural  Chemical 

Group 

FMT Fairmount  Chemical  Co.,  Inc. 

FOC Handschy  Industries,  Inc.,  Ink  and 

Chemical  Div. 

FOR Formosa  Plastics  Corporation  Louisiana 

FRE Freeman  Chemical  Corp. 

FRO Vulcan  f^aterials  Co.,  Chemicals  Div. 

FTE   Cyprus  Foote  Mineral  Company 

FTX   Finetex,  Inc. 

GAF GAF  Corp.,  Chemical  Group 

GAY Gaylord  Chemical  Corp. 

GE General  Electric  Co.,  Specialty 

Chemical  Group 

GFS GFS  Chemical,  Inc. 

GGC    Georgia-Gulf  Corp.: 

Plaquemine  Div. 

GIV    Givaudan  Corp. 

GON    W.R.  Grace  &  Co.,  Organic  Chemicals 

Div.,  Nitroparaffins 

GP Georgia-Pacific  Corp.,  Resins 

Operations 

GPI    Grindsted  Products,  Inc. 

GTL Great  Lakes  Chemical  Corp. 

HAL C.  P.  Hall  Co. 

HAR Haarman  Reimer  Corp.,  Food 

Ingredients  Div. 

HOC Hatco  Chemical  Corp. 

HCF Cape  Industries 

HCL Hoechst  Celanese  Corp: 

Chemical  Group  Inc. 
Fibers  Industrial  Division 
Fine  Chemicals  Division 
Sou-Tex  Works 

HCP Honig  Chemical  &  Processing  Corp. 

HFT Syntex  Agribusiness,  Inc. 

HK Occidential  Chemical  Corp.,  ED  &  S  Div. 

HML Hummel  Crotton,  Inc. 

HMP W.  R.  Grace  &  Co.,  Hampshire 

Chemicals  Div. 

&  Organic  Chemicals  Div. 

HMY Humphrey  Chemical  Co. 

HOC Halocarbon  Products  Corp. 

HOF Hotfman-LaRoche,  Inc. 

HPC Hercules,  Inc 

HRT Hart  Products  Corp. 

HXL Hexcel  Corp.,  Hexcel  Chemical 

Products 

ICI    ICI  Americas,  Inc.: 

Agricultural  Chemical  Div. 


Rubicon,  Inc. 

Specialty  Chem  Div. 
IMC IMC  Pitman-Moore  Industrial  Chemicals 

Div. 

JRC Jarchem  Industries,  Inc. 

KCH    Rhone  Poulenc,  Manchem,  Inc. 

KLM Kalama  Chemical,  Inc. 

KM! Kemin  Industnes,  Inc. 

LOP LCP  Chemicals  -  West  Virginia,  Inc. 

LEM Napp  Chemicals,  Inc. 

LRO Laroche  Chemicals,  Inc. 

LYP Lyondell  Petrochemical  Co. 

MAL Mallinckrodt,  Inc. 

MCI Mooney  Chemicals,  Inc. 

MCK  MacKenzie  Chemical  Works,  Inc. 

MHI Morton  International,  Inc., 

Ventron  Division 

MIL   Milliken  &  Co.,  Milliken  Chemical  Div. 

MNA   Monsanto  Agricultural  Co. 

MOB   Mobay  Chemical  Corp.,  Pittsburgh  Div. 

MON Monsanto  Co. 

MRT   Morion  International,  Inc.,  Speciattys 

Chemical 

NOG    Niacet  Corp. 

NCI Union  Camp  Corp.,  BBA  Div. 

NCI   Union  Camp  Corp. 

NES Ruetgers-Nease  Chemk:al  Co. 

NOC   Norac  Co..  Inc.  Mathe  Div. 

NOD   Huls  America,  Inc. 

OH Anaquest 

OMC Olin  Corp. 

ORT    Roehr  Chemicals,  Inc.,  Div  of  Aceto 

Corp. 

PAH Parish  Chemical  Co. 

PAS Atochem  North  America,  Inc. 

PCI   Piedmont  Chemical  Industries,  Inc. 

PCR    PCR,  Inc. 

PD Parke-Davis,  Div.  of  Warner-Lambert 

Co. 

PDG   PD.  Glycol 

PEL Pelron  Corp. 

PEN Penick  Corp. 

PFN Pfanstiehl  Laboratories,  Inc. 

PFZ FMizer  Pharmaceuticals,  Inc. 

PG Procter  &  Gamble  Co.,  Procter  & 

Gamble  Mfg.  Co. 

PIC  Pierce  Chemical  Co. 

PLC Phillips  66  Co. 

PLS Plastics  Engineering  Co. 


See  note  at  end  of  table 


15-37 


Section  15 

Table  15-3 — Continued 

Miscellaneous  cyclic  and  acyclic  chemicals:  Directory  of  manufacturers,  alphabetical  by  code,  1990 


Code 


Name  of  company 


Code  Name  of  company 

SUN    Sun  Co.,  Inc. 

SWS Wacker  Silicones 

SYL Arizona  Chemical  Co. 

SYP Synthetic  Products  Co. 

TCC Sybron  Chemicals,  Inc. 

TLC Twin  Lake  Chemical,  Inc. 

TNA Ethyl  Corp. 

TCX;    Tenneco  Oil  Co. 

TRO   Troy  Chemical  Corp. 

TSA Texas  Alkyls,  Inc. 

TX     Texaco  Chemical  Co. 

TZC Magnesium  Elektron,  Inc. 

UCC   Union  Carbide  Corp. 

UPJ Upjohn  Co. 

UPM   UOP,  Inc. 

USB U.  S.  Borax  &  Chemical  Corp. 

USI   Quantum  Chemical  Corp.,  USI  Div. 

USR   Uniroyal,  Inc.,  Uniroyal  Chemical  Div. 

UTC Unitex  Chemical  Corp. 

VCM  Vanchem,  Inc. 

VDM  Van  De  Mark  Chemical  Co.,  Inc. 

VEL Velsicol  Chemical  Corp. 

VNC   Vanderbilt  Chemical  Corp. 

VND    Van  Dyk.  Div.  of  Mallinckrodt,  Inc. 

VST Vista  Chemical  Co. 

WAY   Olin  Hunt  Specialty  Products.  Inc. 

WCL   Wright  Chemical  Corp. 

WPG West  Point-Pepperell.  Inc.,  Grifftex 

Chemical  Co.  Sub. 

WTC Witco  Chemical  Corp. 

WTH  Union  Camp  Corp.,  Chemical  Division 

WTK   Heico  Chemicals.  Inc. 

WTL   Atochem  North  America,  Inc.,  Organic 

Peroxides  Div. 

WVA  Westvaco  Corp. 


PMP PMP  Fermentation  Products,  Inc. 

PPG PPG  Industries.  Inc. 

PSG PMC,  Inc.,  PMC  Specialities  Group,  Inc. 

PST Perstorp  Polyols,  Inc. 

QKO QO  Chemicals,  Inc. 

OTR Questra  Chemical,  Corp. 

RCI    Reichhold  Chemicals,  Corp. 

RCN Racon,  Inc. 

RDA Rhone-Poulenc,  Inc. 

REG Regis  Chemical  Co. 

RH     Rohm  &  Haas  Co. 

ROT Roquette  Corporation 

RSA R.S.A.  Corp. 

S   Sandoz  Chemical  Corp. 

SBC Scher  Chemicals,  Inc. 

SC Sterling  Chemicals,  Inc. 

SCM SCM  Corp.,  PCR,  Inc.,  & 

Glidco  Organics 

SCN Schenectady  Chemicals,  Inc. 

SCP Henkel  Corp. 

SD Sterling  Drug,  Inc.; 

Sterling  Pharmaceuticals,  Inc. 

SDC Sandoz  Chemicals  Corp. 

SDW    Sterling  Drug,  Inc.,  Sterling  Organics 

Div. 

SHC Shell  Chemical  Co.  Div. 

SHP Shepherd  Chemical  Co. 

SHX Sherex  Chemical  Co.,  Inc. 

SK  Smithkline  Beecham  Chemicals 

SM Mobil  Oil  Corp.: 

Chemical  Products  Div. 

SOH BP  Chemicals,  Inc. 

SOI    Speciality  Organics,  Inc. 

SPD General  Electric  Co.,  Silicone 

Products  Div. 

SQA Sequa  Chemicals  Inc. 


Note. — Complete  names,  telephone  number,  and  addresses  of  the  above  reporting  companies  are  listed  in  app.  A. 
Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


15-38 


APPENDIX  A 
DIRECTORY  OF  MANUFACTURERS 


Appendix  A 

Table  A-1 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                            number  Office  address 


AEP  A  &  E  Plastic  Inc 818-968-3801 

AC  AC  &  S.  Inc 304-755-9275 

ABB  Abbott  Laboratories   708-937-8343 

ILI  Acme  Steel  Company 708-849-2500 

ACO  Adco  Chemical  Co  201  -589-0880 

CCS  Advanced  Resins.  Inc 303-245-8148 

AIR  Air  Products  &  Chemicals,  Inc 215-481-4911 

AJY  Ajay  Chemicals.  Inc  404-943-6202 

AJI  Ajinomoto  USA.  Inc   201-488-1212 

ARC  Akzo  Chemicals,  Inc 312-906-7500 

ARC  Akzo  Chemicals.  Inc 312-906-7500 

CCA  Akzo  Chemicals.  Inc 312-906-7500 

CAD  Akzo  Chemicals.  Inc 312-906-7500 

FRP  Akzo  Coatings.  Inc 912-367-3616 

REL  Akzo  Coatings.  Inc 502-459-9110 

AK2  Akzo  Coatings.  Inc 502-459-9110 

lOV  Akzo/Resins  &  Vehicles 708-481-8900 

ALW  Albright  &  Wilson.  Americas,  Inc   804-550-4476 

ALC  AIco  Chemical  Corp 615-629-1405 

ALD  Aldrich  Chemical  Co.,  Inc 414-273-3850 

ACH  Alico  Chemical  Corp 214-733-6841 

ALG  Allegheny  Chemical  Corp 814-772-3965 

ALL  Alliance  Chemical.  Inc   201-945-5400 

BME  Allied  Signal-Bendix.  Corp 518-270-0200 

Friction  t^aterials  Div. 

ACS  Allied  Signal  Inc: 

Engineered  Materials  Sector    201-455-4911 

Engineered  Plastic  Div 201-455-2000 

High  Density  Polyethylene  Business   ...  201-455-2000 

ALX  Alox  Corp 716-282-1295 

APH  Alpha  Corporation  of  Tennessee  901  -853-2450 

ALP  Alpha  Laboratories.  Inc    303-756-1338 

HES  Amerada  Hess  Corp.  (Hess  Oil   201-750-6000 

Virgin  Island  Corp.) 

AMB  American  Bio-Synthetics  Corp 414-384-7017 

ACY  American  Cyanamid  Co 201  -831  -2768 

BFP  American  Ingredients.  Co 81 6-561  -9050 

API  American  Polymers.  Inc 508-987-0144 

ASY  American  Synthetic  Rubber  Corp 502-449-8300 

SPO  Ameripol  Synpol  Co..  Div.  of 21 6-762-4442 

Uniroyal  Goodrich  Tire  Co. 

HVG  Ametek,  Inc.,  Haveg  Div 302-995-0400 

AMO  Amoco  Corporation    312-856-6111 


14505  Proctor  Ave.  Industry.  CA  91749. 
West  19th  St.,  Nitro,  WV  25143. 
1401  Sheridan  Rd..  N.  Chicago,  IL  60064. 
13500  S.  Perry  Ave.,  Riverdale, 

IL  60627. 
49  Rutherford  St.,  Newark,  NJ  07105. 
569  24  1/4  Rd..  Grand  Junction. 

CO.  81505. 
7201  Hamilton  Blvd,  Allentown, 

PA  18195-1501 
1400  Industry  Rd.,  Powder  Springs, 

GA  30073. 
4020  Ajinomoto  Dr.,  Raleigh,  NC  27610. 
RO.  Box  100,  Axis,  AL  36505. 
300  S.  Riverside  Plaza,  Chicago,  IL 

60606. 
500  Jersey  Ave,  New  Brunswick,  NJ 

08903 
2153  Lockport-Olcott  Rd.,  Burt,  NY 

14028. 
PO.  Box  349,  Baxley.  GA  31513. 
4730  Crittenden  Dr.,  Louisville,  KY  40233. 
1313  Windsor  Ave.,  Columbus,  OH 

43211. 
21625  Oak  St.,  Matteson,  IL  60443. 
100  Lakeridge  Pkwy.,  Ashland,  VA  23005. 
909  Mueller  Dr.,  Chattanooga,  TN  37406. 
1001  W.  St.  Paul  Ave.,  Milwaukee, 

Wl  53233. 
17304  N.  Preston  Dr.,  Dallas,  TX  75252. 
Gillis  Ave.,  Ridgway.  PA  15853. 
Linden  Ave..  Ridgefield.  NJ  07657. 
PO.  Box  238,  Troy,  NY  12180. 


PO.  Box  1087  R,  Morristown,  NJ  07962. 
100  Columbia  Rd.,  Morristown, 

NY  07962. 
12875  Scenic  Hwy,  Baton  Rouge, 

LA  70892. 
3943  Buffalo  Ave..  Niagara  Falls.  NY 

14303. 
423  Highway  57  East,  Collierville,  TN 

38017. 
1685  S.  Fairfax  St.,  Denver,  CO  80222. 
1  Hess  Plaza,  Woodbridge, 

NJ  07095-0961. 
710  W.  National  Ave.,  Milwaukee,  Wl 

53204. 
One  Cyanamid  Plaza,  Wayne,  NJ  07470. 
3947  Broadway,  Kansas  City,  MO  64111. 
Old  Webster  Rd..  Oxford.  MA  01801. 
4500  Campground  Rd..  Louisville, 

KY  40232. 
146  South  High  St.  Akron,  OH 

44308-1493. 

900  Greenbank  Rd.,  Wilmington,  DE 

19808. 
200  E.  Randolph  Dr.,  Chicago,  IL 

60680-0703. 


A-2 


Synthetic  Organic  Chemicals.  1990 


Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  betow  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 


Identi- 
fication 
code  Name  of  company 


Telephone 
number 


Office  address 


AMV  Amvac  Chemical  Corp 213-264-3910 

OH  Anaquest    608-273-0019 

ADC  Anderson  Development  Co    517-263-2121 

ANG  Angus  Chemical  Co  708-498-6700 

ALI  Anzon,  Inc    215-531-6010 

APX  Apex  Chemical  Co  908-354-5420 

APC  Apollo  Chemical  Corp 919-226-1161 

APO  Apollo  Colors.  Inc 708-564-9190 

AQU  Aqualon  Co 302-996-2000 

HKY  Arcadian  Corp    901-351-6500 

GCC  Arcadian  Corp    901-351-3314 

ARD  Ardmore,  Inc 201-481-2406 

ARN  Arenol  Chemical  Corp    201-526-5900 

ART  Aristech  Chemical  Corp 412-433-2747 

ARZ  Anzona  Chemical  Co 904-785-6700 

SYL  Arizona  Chemical  Co 904-785-6700 

ALS  Armco,  Steel  Co 513-425-5000 

ARP  Armour  Pharmaceutical  Co    815-932-6771 

ARO  ARNCO    213-567-0587 

ARL  Arol  Chemical  Products  Co    201  -344-1 51 0 

ARS  Arsynco,  Inc..  Sub  Div.  of  Aceto 516-627-6000 

Corp, 

ASH  Ashland  Oil,  Inc    614-889-3333 

Ashland  Petroleum  Co   606-329-3333 

BLA  Astor  Products.  Inc.,  Blue  Arrow  Div   904-783-5352 

AIL  Atlantic  Industries,  Div 201-235-1800 

Crompton  Knowles  Corp. 

ATR  Atlantic  Richfield  Co. 215-359-2000 

Arco  Chemical  Co 

ARI  Atlas  Refinery,  Inc    201  -589-2002 

RSN  Atochem  North  America,  Inc    215-587-7000 

PAS  Atochem  North  America,  Inc    215-587-7452 

WTL  Atochem  North  America,  Inc 716-877-1740 

Organic  Peroxides  Div. 

AUX  Auralux  Corp    203-886-261 6 

AUS  Ausimont  N  V 201  -292-6250 

AZT  Aztec  Catalyst  Co 713-957-6818 

BAS  BASF  Corp 

Chemicals  Div 201  -31 6-2937 

ICF  Coating  &  Colorants 201-365-3400 

SOH  BP  Chemicals,  Inc   216-586-4141 

SIF  Com  merical  Composites 213-757-5141 

SIC  Commerical    213-757-1801 

SIO  BP  Oil  Co  419-226-2300 

BTL  BTL  Speciality  Resin  Corp 419-244-5856 


4100  E.  Washington  Blvd.,  Los  Angeles, 

CA  90023. 
2005  W.  Bellline  Hwy.,  I^adison,  Wl 

53713. 
1415  E.  Michigan  St.,  Adrian,  Ml  49221. 
2211  Sanders  Rd.,  Nonhbrook,  IL  60085. 
2545  Aramingo  Ave.,  Philadelphia, 

PA  19125. 
200  S.  First  St.,  Elizabeth,  NJ  07206. 
1105  Southerland  St.,  Graham,  NC 

27253. 
3000  W.  Dundee  Rd.,  Suite  415, 

Northbrook,  IL  60062. 
2711  Centerville  Rd.,  Wilmington,  DE 

19850. 
6750  Poplar  Ave.,  Suite  600,  Memphis, 

TN  38138-7419. 
PO.  Box  27147,  Memphis,  TN  38127. 
29  Riverside  Ave.,  Newar1<,  NJ  07104. 
189  Meister  Ave.,  Somerville,  NJ  08876. 
600  Grant  St..  Pittsburgh.  PA 

15230-0250. 
1001  E.  Business  Hwy.  98.  Panama  City. 

FL  32401. 
PO.  Box  947,  Port  St.  Joe,  FL  32456. 
703  Curtis  St.,  Middletown,  OH  45043. 
RO.  Box  511,  Kankakee,  IL  60901. 
5141  Firestone  Place.  Southgate, 

CA  90280. 
649  Ferry  St..  Newark.  NJ  07105. 
One  Hollow  Lane.  Lake  Success. 

NY  11042-1215. 
RO.  Box  2219.  Columbus,  OH  43216. 
RO.  Box  391,  Ashland,  KY  41114. 
5244  Edgewood  Ct.,  Jacksonville, 

FL  32205. 
10  Kingsland  Rd.,  Nutley,  NJ  07110. 

3801  West  Chester  Pike,  Newtown 

Square,  PA  19073. 
142  Lockwood  St.,  Newark,  NJ  07105. 
1112  Lincoln  Rd.,  Birdsboro,  PA  19508. 
Three  Parkway,  Philadelphia,  PA  19102. 
1740  Military  Rd.,  Buffalo,  NY  14240. 

29  Scott  Ave.,  Norwich,  CT  06360. 
44  Whippany  Rd.,  Morristown,  NJ  07962. 
2190  N.  Loop  West,  Suite  400  Houston, 
TX  77018 

100  Cherry  Hill  Rd.,  Parsippany, 
1255  Broad  St.,  Clifton,  NJ  07015. 

NJ  07054 
200  Pubic  Square  31  -N-41 05.  Cleveland. 

OH  44114-2375. 
12333  South  Van  Ness  Ave..  Hawthorne, 

CA  90250. 
12333  South  Van  Ness  Ave.,  Hawthorne, 

CA  90250. 
1150  South  Metcalf  St..  Lima,  OH  45804. 
2112  Sylvon  Ave  ,  Toledo,  OH  43606. 


A-3 


Appendix  A 


Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 


Identi- 
fication 
code  Name  of  company 


Telephone 
number 


Office  address 


BKC  J.  T  Baker  Chemical  Co 908-859-2151 

BFC  Barker  Fine  Color,  Inc 606-261  -0200 

BIB  Beckman  Instruments,  Inc   415-859-1510 

BCK  Diagnostic  Systems  Group 619-438-6433 

BCM  Belding  Heminway  Co    212-944-6040 

BLZ  Belzak  Corp   201-773-0602 

BLY  Berkley  &  Co.,  Inc 712-336-1520 

BTS  Bethlehem  Steel  Corp    215-694-4522 

BNS  Binney  &  Smith,  Inc   215-253-6271 

BOC  Biocraft  Laboratories,  Inc 201-703-0400 

NUT  Bioproducts,  Inc 502-968-3321 

BOE  Boehme  Filatex,  Inc 919-342-6631 

BOT  Boots  Pharmaceuticals,  Inc 708-405-7400 

BOR  Borden,  Inc.: 

Packaging  &  Industrial  Products 614-225-4000 

Div. 

BCP  Borden  Chemical  &  Plastics 504-673-6121 

Delaware  Limited  Partnership 

BMC  Brin-Mont  Chemicals,  Inc 919-292-0566 

BRS  Bristol-Myers  Squibb  Co 212-546-4000 

BRU  M.  A.  Bruder  &  Sons,  Inc  215-353-5100 

BKM  Buckman  Laboratories.  Inc 901-278-0330 

BCC  Buffalo  Color  Corp   716-827-4500 

BRI  Burlington  Industries,  Inc 919-379-2000 

BUR  Burroughs  Wellcome  Co    91 9-248-3000 

COR  CDR  Pigments  &  Dispersions    502-737-1700 

CFI  CF  Industries,  Inc 708-438-9500 

CLU  CL  Industries,  Inc 217-662-2136 

CCC  C.N. C.  International,  Inc 401-769-6100 

PS  CPS  Corp 71 6-366-601 0 

CPS  CPS  Chemical  Co.,  Inc 908-727-3100 

CYR  CYRO  Industries    201  -770-3000 

GRL  Calgon  Corp.,  Calgon  Vestal   314-862-2000 

Laboratories  Div. 

CMB  Cambridge  Industries  Co  201-465-4565 

HCF  Cape  Industries    919-341-5500 

CBC  Carbose  Corp 814-443-1611 

CGL  Cargill,  Inc    612-475-7634 

CHC  Carpenter  Chemical  Co   804-359-0800 

BSC  Cascade  Resins,  Inc    503-343-2111 

CAS  Caschem,  Inc 201-858-7900 

CCL  Catawba-Charlab,  Inc 704-523-4242 

CED  Cedar  Chemical  Corp 501-572-3701 

CNT  Certainteed  Corp   215-341  -7000 

CPR  Certified  Processing  Corp    201-923-5200 


222  Red  School  Lane,  Phillipsburg, 

NJ  08865. 
38  Elm  St.,  Lodlov,  KY  41016. 
1050  Page  Mill  Rd.,  Palo  Alto,  CA  94304. 
2470  Faraday  Ave.,  Carlsbad,  CA  92008. 

NJ  07424. 
RO.  Box  130,  Hendersonville,  NC  28793. 
850  Bloomfield  Ave.,  Clifton.  NJ  07012. 
One  Berkley  Dr.,  Spirit  Lake.  lA  51360. 
866  Martin  Tower  -  8th  Fl.,  Bethlehem. 

PA  18016. 
1100  Church  Lane,  Easton, 

PA  18044-0431. 
12  Industnal  Park,  Waldwick,  NJ  07463. 
4820  Jennings  Lane,  Louisville,  KY 

40218. 
Rt.  11  Box  5,  Reidsville.  NC  27320. 
300  Tristate  Int'l  Ctr,  Suite  200, 

Lincolnshire,  IL  60015 

180  E.  Broad  St.,  Columbus.  OH  43209. 
Box  427,  Geismar,  LA  70734. 

3921  Spring  Garden  St.,  Greensboro. 

NC  27407. 
345  Park  Ave.,  New  York,  NY  10154. 
52nd  &  Grays  Ave.,  Philadelphia.  PA 

19143. 
1256  N.  McLean  Blvd.,  Memphis.  TN 

381 08 
RO.  Box  7027.,  Buffalo.  NY  14240. 
3330  W.  Friendly  Ave.,  Greensboro. 

NC  27406. 
3030  Cornwallis  Rd..  Research  Triangle 

Park.  NC  27709. 
305  Ring  Rd.,  Elizabethtown,  KY  42701. 
Salem  Lake  Dr.,  Long  Grove,  IL  60047. 
RO.  Box  218,  Georgetown,  IL  61846. 
20  Priviledge  St..  Woonsocket.  Rl  02895. 
3257  Middle  Rd..  Dunkirk,  NY  14048. 
Old  Water  works.  Rd.,  Old  Bridge, 

NJ  08857. 
100  Valley  Rd.,  MT  Arlington.  NJ  07856. 
5035  Manchester  Ave..  St.  Louis. 

MO  63110. 
7-33  Amsterdam  St..  Newark.  NJ  07103. 
RO,  Box  327.  Wilmington.  NC  28402. 
100  Maple  St.,  Somerset.  PA  15501. 
RO.  Box  5630,  Minneapolis,  MN  55428. 
5016  Monument  Ave.,  Richmond. 

VA  23230. 
W.  1st  &  Bertleson  Rd.,  Eugene, 

OR  97440. 
40  Avenue  A,  Bayonne,  NJ  07002. 
5046  Old  Pineville  Rd.,  Charlotte, 

NC  28217. 
Highway  242  South,  West  Helena. 

AR  72390. 
RO.  Box  860,  Valley  Forge,  PA  19482. 
U.S.  Highway  #22,  Hillside,  NJ  07205. 


A-4 


Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi-  ~ 

fication  Telephone 

code  Name  of  company  number  Office  address 


GRS  Champlin  Refining.  Co 512-882-8871 

CHT  Chattem.inc 615-821-4571 

CHD  Chemdesign  Corp    508-345-9999 

CFX  Chemfax,  Inc    601-863-6511 

CXI  Chemical  Exchange  Industries,  Inc   713-526-8291 

CMT  Chemithon  Corp 206-937-9954 

CHL  ChemoICo 919-333-3050 

SOC  Chevron  Corp.,  Chevron  Chemical    415-842-5500 

CHH  Chris  Hansen's  Laboratory,  Inc    414-476-3630 

CGY  Clba-Geigy  Corp 914-478-3131 

CGO  Citgo  Petroleum  Corp 918-495-4000 

CGU  Citizens  Gas  &  Coke  Utility    317-264-8802 

CCG  Clark  Colors  908-757-4500 

H.K.  Color  Group 

ACT  Climax  Performance  Materials  Corp    708-458-8450 

WYC  Coastal  Chem,  Inc  307-637-2700 

CSP  Coastal  Refining  &  Marketing  Inc 713-877-1400 

CP  Colgate-Palmolive  Co 212-310-2536 

CLD  Colloids,  Inc  404-422-1250 

CIC  Color  Chem  International  Corp 404-396-1230 

COC  Columbia  Organic  Chemical  Co.,  Inc 803-425-1 786 

CAC  Cominco  Fertilizers  Inc 509-747-6111 

CMP  Commercial  Products  Co.,  Inc 201-427-6887 

CNI  Conap,  Inc   716-372-9650 

CON  Concord  Chemical  Co.,  Inc    609-966-1526 

CO  Conoco  Specialty  Products,  inc 713-293-1000 

CTL  Continental  Chemical  Co  201-472-5000 

CTP  Continental  Polymers,  Inc    901-942-0787 

CPV  Cook  Paint  &  Varnish  Co   816-391-6000 

CKC  Cook  Composites  and  Polymers  Co 816-391-6000 

HEU  Cookson  Pigments,  Inc    201-242-1800 

COP  Coopers  Creek  Chemical  Corp    215-828-0375 

CPY  Copolymer  Rubber  &  Chemical  504-355-5655 

Corp. 

CMS  Cosmic  Plastics,  Inc 818-365-3249 

CRD  Croda,  Inc 212-683-3089 

CK  Crompton  &  Knowles  Corp 215-775-8000 

CCP  Crown  Central  Petroleum  Corp   301-539-7400 

USM  Crown  Metro,  Inc   803-299-1331 

CYT  Cumberland  International  Corp    713-682-1221 

CTR  Customs  Resins  Div.  of  Bemis 502-826-7641 

Co.,  Inc. 


1801  Nueces  Bay  Blvd.,  Corpus  Chrlsti, 

TX  78469. 
1715  W.  38th  St.,  Chattanooga,  TN 

37409. 
99  Development  Rd.,  Fitchburg,  MA 

01420. 
10045  Three  River  Rd.,  Gulfport,  MS 

39502. 
3813  Buffalo  Speedway,  Houston, 

TX  77098. 
5430  W.  Marginal  Way,  SW.,  Seattle, 

WA  98106. 
2410  Randolph  Ave.,  Greensboro, 

NC  27406. 
6001  Bollinger  Canyon  Rd.,  San 

Co.  Ramon,  94583. 
9015  W.  Maple  St.,  West  Allis,  Wl  53214. 
444  Saw  Mill  River  Rd.,  Ardsley,  NY 

10502. 
RO.  Box  1562,  Lake  Charles,  LA  70602. 
3133  Southeastern  Ave.,  Indianapolis, 

IN  46203. 
155  Helen  St.,  South  Plainfield. 

NJ  07080. 
7666  W.  63rd  St.,  Summit.  IL  60501. 
PO.  Box  1287,  Cheyenne,  WY  82003. 
Nine  Greenway  Plaza,  Houston,  TX 

77046. 
300  Park  Ave.,  New  York,  NY  10022. 
P.O.  Box  769,  Marietta,  GA  30061 . 
5145  Meadow  Creek  Dr.,  Atlanta, 

GA  30338. 
1424  Mt.  Zion  Road,  Cassatt  SC  29032. 
W.  601  Riverside  Ave.,  Spokane, 

WA  99201. 
117  Ethel  Ave.,  Hawthorne.  NJ  07506. 
1405  Buffalo  St.,  Clean,  NY  14760. 
17th  &  Federal  Sts.,  Camden,  NJ  08105. 
PO  Box  2197,  Houston,  TX  77079. 
270  Clifton  Blvd.,  Clifton,  NJ  07011-3686. 
2225  E.  Del  Amo  Blvd.,  Compton, 
P.O.  Box  419389,  Kansas  City,  MO 

64141. 
919  East  14th  Ave.,  N.  Kansas  City. 

MO.  64141-6389. 
256  Vanderpool  St..  Newark,  NJ  07114. 
River  Rd.,  West  Conshohocken,  PA 

19428. 
PO.  Box  2591 ,  Baton  Rouge,  LA  70821 . 

12314  Gladstone  Ave.,  San  Fernando. 

CA  91311 
183MadisonAve.,  NewYork,  NY  10016. 
PO.  Box  341,  Reading,  PA  19603. 
1  N.  Charles  St.,  Baltimore,  MD  21203. 
Echelon  Road,  Donaldson  Centre, 

Greenville,  SC  29606. 
1523  N.  Post  Oak  Rd.,  Houston.  TX 

77055. 
PO.  Box  933.  Henderson,  KY  42420. 


A-5 


Appendix  A 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                            number  Office  address 


AIVID          Cyclo  Products,  Inc   213-582-6411 

FTE           Cyprus  Foote  Mineral  Co 215-889-9605 

CNP          DSM  Chemicals  Norlh  America,  Inc 404-823-4240 

POP          Daicolor  Pope,  Inc   201-279-2702 

MAR          Daishowa  Chemical,  Inc 203-625-0701 

DPI            Dart  Polymers,  Inc.,  Sub.  of  Dart 717-656-2236 

Container  Corp. 

DGO          Day-Glo  Color  Corp  216-391-7070 

DPW          Deepwater,  Inc 714-751-3522 

DGC           Degussa  Corp    201-641-6100 

DRR          Delta  Resins  &  Refractories,  Inc    414-462-1200 

DNS          Dennis  Chemical  Co 314-771-1800 

UDI            DeSoto,  Inc 708-391-9000 

PLX               Union  City 312-391-9000 

DTP          Detroit  Coke  Corp 313-842-6222 

Dexter  Corp; 

HYA              Dexter  Adhesive  &  Structual 415-687-4201 

Material  Div. 

HYG              Dexter  Electronic  Material  Div    818-968-6511 

DEX              Dexter  Chemical  Corp    212-542-7700 

MID               Dexter  Speciality  Coatings  708-623-4200 

AGP          Dial  Corp    602-248-2800 

DA             Diamond  Shamrock  Refining  &    512-641  -6800 

Marketing. 

DAZ           Diaz  Chemical  Corp 716-638-6321 

DVR          Diversified  Technology,  Inc 904-673-4136 

DIX            Dixie  Chemical  Co..  Inc   713-863-1947 

DRC           Dock  Resins  Corp    908-862-2351 

DOM          Dominion  Products,  Inc    718-499-3050 

DVC           Dover  Chemical  Corp.  Sub.  of  ICC    216-343-7711 

Industries,  Inc. 

DOW          Dow  Chemical  Co 517-636-6125 

Dec          Dow  Corning  Corp  51 7-496-4000 

DRX          Drexel  Chemical  Corp   901-774-4370 

ABP           Drummond  Co.,  Inc   205-945-6301 

WBG         Dryden  Oil  Co 508-791-3201 

CHO          Ducon 618-654-2070 

DUP          E.  I.  duPont  de  Nemours  &  Co.,  Inc 302-774-1 000 

DSC          Dye  Specialties,  Inc  201-866-9504 

AGI            EMS-American  Grilon,  Inc 803-418-9172 

EPC           EPC  Partners,  Ltd    713-880-6500 

EPI             Eagle  Pitcher  Industries  Inc.,  Orthane 817-387-0585 

Div. 

ECC           Eastern  Color  &  Chemical  Co    401-331-9000 

EK              Eastman  Kodak  Co    716-724-4000 

EKT               Tennessee  Eastman  Co.  Div    615-229-2000 

EKX               Texas  Eastman  Co.  Div    903-237-5122 

ESA           East  Shore  Chemical  Co 616-726-3106 

ELN           Elan  Chemical  Co 201-344-8014 


1922  E.  64th  St.,  Los  Angeles,  CA  90001 . 
301  Lindenwood  Dr.,  Suite  301 ,  Malvern, 

PA  19355. 
P.O.  Box  2451 ,  Augusta,  GA  30903. 
33  Sixth  Ave.,  Paterson,  NJ  07524. 
81  Holly  Hill  Lane  Greenwich,  CT  06830. 
60  E.  Main  St..  Leola,  PA  17540. 

4515  St.  Clair  Ave..  Cleveland.  OH 

44103. 
P.O.  Box  17599.  Irvine.  CA  92713. 
65  Challenger  Rd.,  Ridgefield  Park, 

NJ  07660. 
6263  N.  Teutonia  Ave.,  Milwaukee. 

Wl  53209. 
2700  Papin  St.,  St.  Louis.  MO  63103. 
3950  Fossil  Creek  Blvd..  Fort  Worth, 

TX  76137. 
1700  So.  Mt.  Prospect  Rd.,  Des  Plaines. 

IL  60018 
7819  West  Jefferson  Ave.,  Detroit, 

Ml  48209. 

2850  Willow  Pass  Road,  Pittsburgh, 

CA  94565. 
211  Franklin  St.,  Olean,  NY  14760. 
845  Edgewater  Rd.,  Bronx,  NY  10474. 
E.  Water  St.,  Waukegan,  IL  60085. 
2000  Aucutt  Rd..  Montgomery.  AL  60538. 
PO.  Box  696000,  San  Antonio, 

TX  78269-6000. 
40  Jackson  St..  Holley,  NY  14470. 

NH  03103. 
1625  State  Ave.,  Holly  Hill,  FL  32117. 
300  Jackson  Hill.  Houston,  TX  77007. 
1512  W.  Elizabeth  Ave.,  Linden.  NJ 

07036. 
882  -  3rd  Ave..  Brooklyn,  NY  11232. 
W.  15th  &  Davis  Sts.,  Dover,  OH  44622. 

2020  Willard  H.  Dow  Center,  Midland, 

Ml  48674. 
RO.  Box  994,  Midland.  Ml  48686-0994. 
2487  Pennsylvania  St..  Memphis,  TN 

38109. 
P.O.  Box  10246,  Birmingham.  AL  35202. 
694  Millbury  St..  Worchester,  MA  01607. 
115  Executive  Dr.,  Highland,  IL  62249. 
1007  Market  St..  Wilmington.  DE  19898. 
100  Plaza  Center,  Secaucus,  NJ  07096. 
RO.  Box  1717,  Sumter,  SC  29151. 
RO.  Box  4324.  Houston,  TX  77210. 
RO.  Box  1389.  Denton,  TX  76202. 

35  Livingston  St.,  Providence,  Rl  02904. 
343  State  St.,  Rochester,  NY  14650. 
RO.  Box  511,  Kingsport,  TN  37662. 
PO.  Box  7444,  Longview.  TX  75607. 
1221  E.  Barney  Ave..  Muskegon,  Ml 

49443. 
268  Doremus  Ave.,  Newark.  NJ  07105. 


A-6 


'  Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                            number  Office  address 


ELC  EIco  Corp.  Sub.  of  Delrex  Chemical 216-749-2605 

Industries,  Inc. 

USM  Emhan  Corp.,  Bostik  Div   508-777-0100 

EMK  Emkay  Chemical  Co 201-352-7053 

EKO  Empire  Coke  Co 205-323-2400 

ENO  Enenco,  Inc    901-328-5800 

HSH  Engelhard  Corp   201-632-6000 

SAR  Esschem,  Inc   215-521-3800 

ESS  Essential  Industries,  Inc 414-538-1122 

EHC  Ethichem  Corp 201  -933-7880 

ETC  Ethox  Chemicals,  Inc 803-277-1 620 

TNA  Ethyl  Corp 804-788-5537 

EVL  Eval  Company  of  America  708-719-4610 

ENJ  Exxon  Chemical  Americas 713-870-6000 

FMC  Corp: 

FMN  Agricultural  Chemical  Group 215-299-6000 

FMB  Chemical  Products  Group 215-299-6000 

FMC  Nitro  Div   215-299-6000 

FAB  Fabricolor  Manufacturing  Corp 201-742-3900 

FMT  Fairmount  Chemical  Co.,  Inc  201-344-5790 

FRI  Farmland  Industries,  Inc 816-459-6000 

816-238-8111 

FEL  Felton  Worldwide,  Inc 718-497-4664 

SDS  Fermenta  ASC  Corp 216-357-4100 

FER  Ferro  Corp.: 

Bedford  Chemical  Div 216-641-8580 

Grant  Chemical  Div 504-654-6801 

Keil  Chemical  Div 21 9-931  -2630 

FBI  Fiber  Industries,  Inc  704-357-2000 

CSD  Fina  Oil  &  Chemical  Co 214-750-2400 

Cosden  Chemical  Div. 

FTX  Finetex,  Inc 201-797-4686 

Firestone  Tire  &  Rubber  Co.; 

FRF  Firestone  Fibers  &  Textile  Co   216-379-7000 

FRS  Firestone  Synthetic  Rubber  & 216-379-7495 

Latex  Co.  Div. 

CI  Firmenich,  Inc 609-452-1 000 

FST  First  Chemical  Corp 601  -762-0870 

FPC  Flambeau  Paper  Corp   715-762-5235 

FLM  Fleming  Latx)ratories,  Inc 704-372-5613 

FOR  Formosa  Plastics  Corp-Louisiana    504-356-3341 

Formosa  Plastics  Corp-USA 201-992-2090 

BDS  Fragrance  Resources,  Inc  908-264-6767 

FLN  Franklin  International,  Inc 614-443-0241 

FRE  Freeman  Chemical  Corp   414-284-5541 

WLC  Freepon  McMoran  Resource 504-582-4000 

Partners. 

COO  H.B.  Fuller  Co 612-481-1588 


1000  Beltline  Rd.,  Cleveland  OH  44109. 

Boston  St.,  Middleton,  MA  01949. 
319-325  Second  St.,  Elizabeth,  NJ 

07206. 
1927  Ist  Ave.,  N.,  Suite  900,  Birmingham, 

AL  35203. 
755  Crossover  Lane,  Suite  216,  Memphis, 

TN  38117. 
3400  Band  Street,  Louisville,  KY  40212. 
Governor  Printz  Blvd.,  Essington,  PA 

19029. 
28391  Essential  Rd.,  Merton,  Wl  53056. 
150  Grand  St.,  Carlstadt.NJ  07072. 
RO.  Box  5094,  Station  B,  Greenville. 

SC  29606. 
330  S.  4th  St.,  Richmond.  VA  23217. 

1001  Warrenville  Rd..  Suite  201,  Lisle, 
IL  60532. 

P.O.  Box  3272.  Houston.  TX  77253-3272. 

2000  Market  St..  Philadelphia,  PA  19103. 
2000  Market  St..  Philadelphia,  PA  19103. 
2000  Market  St..  Philadelphia.  PA  19103. 
24-1/2  Van  Houten  St..  Paterson,  NJ 

07509. 
117  Blanchard  St.,  Newark.  hJJ  07105. 
RO.  Box  308,  Lawrence.  KS  66044. 
1 41 7  Lower  Lake  Rd..  St.  Joseph. 

MO  64502. 
599  Johnson  Ave..  Brooklyn.  NY  11237. 
5966  Heisley  Rd..  Mentor,  OH  44060. 

7050  Krick  Rd.,  Bedford,  OH  44146. 
RO.  Box  263,  Baton  Rouge,  LA  70821. 
3000  Sheffield  Ave.,  Hammond.  IN 

46320. 
5146  Parkway  Plaza  Blvd..  Charlotte. 

NC  28217. 
8350  N.  Central  Expressway.  Dallas. 

TX  75206. 
RO.  Box  216,  Elmwood  Park, 

NJ  07407. 

RO.  Box  450,  Hopewell,  VA  23860. 
RO.  Box  26611,  Akron,  OH  44319-0006. 

RO.  Box  5880.  Princeton,  NJ  08543. 
RO.  Box  1427.  Pascagoula,  MS  39567. 
200  N.  First  Ave..  Park  Falls,  Wl  54552. 
2215  Thrift  Rd.,  Charlotte,  NC  28234. 
RO.  Box  271 ,  Baton  Rouge,  LA  70821 . 
9  Peach  Tree  Hill  Rd.,  Livington. 

NJ  07932. 
275  Clark  St.,  Keyport,  NJ  07735. 
2020  Bruck  St.,  Columbus,  OH  43207. 
217  Freeman  Dr.,  Port  Washington, 

Wl  53074. 
1615  Poydras  St.,  New  Orleans,  LA 

70112. 
820  Woburn  St.,  Wilmington.  MA  01887. 


A-7 


Appendix  A 


Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication 
code  Name  of  company 


Telephone 
number 


Office  address 


FLH 
EEP 
GAF 
GFS 
GLX 
GAN 
GAY 
GNT 

GNR 


GE 

GEP 
SPD 

GE 
GLC 
GRG 
GGC 


PSP 
GP 

TNI 
GIV 
GLD 
BFG 

GYR 

EVN 

GRD 

HMP 

GON 

GPC 

CPC 
GTL 
GDC 

GPI 

GGI 

GRV 

GSS 

GTH 


H.B.  Fuller  Co 612-645-3401 

Furon  Co    714-831-5350 

GAF  Chemical  Corp 201  -628-3000 

GFS  Chemicals,  Inc 614-881-5501 

Galaxie  Chemical  Corp    201-279-0558 

Ganes  Chemicals,  Inc    201-507-4300 

Gaylord  Chemical  Corp   504-649-5464 

Gencorp  Polymers  Products    216-869-4200 

Genencor,  International  Inc   415-742-7500 

General  Electric  Co.: 

Electromatenals  Div   614-622-5310 

Plastics  Div 413-448-6681 

Silicone  Products  Div   518-233-3377 

Speciality  Chemicals  Group 413-448-6681 

General  Latex  and  Chemical  Corp 617-576-8000 

PD.  George  Co    314-621-5700 

Georgia  Gulf  Corp: 

Houston  Div   404-395-4500 

Plaquemine  Div 404-395-4500 

PVC  Compound  Div 404-395-4500 

Georgia-Pacific  Corp.: 

Bellingham  Div   206-733-4410 

Resins,  Inc   404-521  -4000 

Gillette  Chemical  Co 61 7-421-7000 

Givaudan  Corp 201-365-8000 

Glidden  Company 216-344-8000 

B.  F  Goodrich  Co 21 6-447-7802 

Goodyear  Tire  &  Rubber  Co 216-796-2121 

W.  R.  Grace  &  Co.: 

Organic  Chemicals  Div.,  Evans    617-861-6600 

Chemetics. 

Organic  Chemicals  Div.,  Chemicals  &    ..  617-861-6600 

Polymers  Div. 

Organic  Chemicals  Div 617-861-6600 

l-lampshire  Chemicals  Div. 

Organic  Chemicals  Div 617-861-6600 

Nitroparafins. 

Gram  Processing  Corp 319-264-4211 

Grant  Industries,  Inc 201-791-6700 

Great  Lakes  Chemical  Corp 317-497-6100 

Gresco,  Mfg.  Inc 919-475-8101 

Grinstead  Products,  Inc   913-764-8100 

Grow  Group,  Inc 301  -939-1 234 

Cello  Corp  Div 

Guardsman  Products,  Inc 616-452-5181 

Gull  States  Steel,  Inc 205-543-6201 

Guth  Corp 414-644-6461 


4450  Malsbary  Rd.,  Blue  Ash,  OH  45242. 
I^ain  &  Orchard  Sts.,  Mantua,  OH  44255. 
1361  Alps  Rd.,  Linden,  NJ  07036. 
PO.  Box  245,  Columbus,  OH  43065. 
26  Piercy  St.,  Paterson,  NJ  07524. 
630  Broad  St.,  Carlstadt,  NJ  07072 
PO.  Box  1209,  Slidell,  LA  70459-1209 
165  S.  Cleveland  Ave.,  Mogadore, 

OH  44260. 
180  Kimball  Way,  S.  San  Francisco, 

CA  94080. 

1350  S.  Second  St.,  Coshocton,  OH 

43812. 
1  Plastics  Ave.,  Pittsfield,  MA  01201. 
260  Hudson  River  Rd.,  Waterford. 

NY  12188. 
One  Plastic  Ave.,  Pittsfield,  MA  01201. 
PO.  Box  498,  Ashland,  OH  44805. 
5200  N.  Second  St.,  St.  Louis,  MO  63147. 

3503  Pasadena  Freeway,  Pasadena, 

TX  77503. 
400  Perimeter  Center  Terrace,  Suite  595, 

Atlanta,  GA  30348. 
PO.  Box  629,  Plaquemine,  LA 

70765-0629. 

PO.  Box  1236,  Bellingham,  WA  98227. 
133  Peachtree  St.  NE.,  Atlanta,  GA 

30303. 
3500  W.  16th  St.,  N.  Chicago,  IL  60064. 
100  Delawanna  Ave.,  Clifton,  NJ  07014. 
925  Euclid  Ave.,  Cleveland  OH  44115. 
6100  Oak  Tree  Blvd.,  Cleveland,  OH 

44131. 
1144  E.  Market  St.,  Akron.  OH  44316. 

55  Hayden  Ave.,  Lexington,  MA  02173. 

55  Hayden  Ave.,  Lexington,  MA  02173. 

55  Hayden  Ave.,  Lexington.  MA  02173. 

55  Hayden  Ave,,  Lexington,  MA  02173. 

1600  Oregon  Street,  Muscatine. 

lA  52761-0349. 
PO.  Box  360,  Elmwood  Park,  NJ  07407. 
U.S.  Hwy.  52  NW.,  Lafayette,  IN  47906. 
216  E.  Holly  Hill  Rd.,  Thomasville, 

NC  27360. 
200  Industrial  Parkway  Industrial  Airport, 

KS  66031. 
1354  Old  Post  Rd.,  Havre  De  Grace, 

MD  21078. 
1350  Steele  Ave.  SW.,  Grand  Rapids. 

Ml  49507. 
1 74  South  26th  St.,  Gadsden 

AL  35904-1935. 
PO.  Box  347,  Slinger,  Wl  53086. 


A-8 


Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1 990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 

ficalion  Telephone 

code  Name  of  company  number  Office  address 


HAR 

HAL 
HOC 
FOC 

TMH 

HRT 
HCC 
WTK 

HAP 

SCP 
HPC 
HER 

HTN 
HEC 
HEW 
HXL 


DAN 
HIP 
SOG 
HIL 

HIM 
HDG 

HCL 


HOP 
HCP 
EFH 
NOD 

HML 
HMY 
HNT 
HMN 

ICI 


Haarmann  &  Reimer  Corp  201  -467-5600 

Food  Ingredients  Div 219-262-6916 

C.  R  Hall  Co 312-767-4600 

Halocarbon  Products  Corp 201-262-8899 

Handschy  Industries,  Inc    708-597-7990 

ink  and  Chemical  Div. 

Harcros  Chemicals,  Inc   913-321-3131 

Hart  Products  Corp 201-433-6665 

Hatco  Chemical  Co    908-738-3000 

Heico  Chemicals,  Inc 717-476-0353 

Helmerich  &  Payne,  Inc.,  Natural 713-424-5568 

Gas  Odorizing  Div. 

Henkel  Corp 215-270-8100 

Hercules,  inc    302-594-5000 

Heresite  Protective  Coating,  Inc 414-684-6646 

Heterene  Chemical  Corp  201-278-2000 

Hewchem 601-863-6600 

Hewitt  Soap  Co.,  Inc 513-253-1151 

Hexcel  Corp: 

Chemical  Products  Div 805-498-1399 

Chemical  Products  Div 616-772-2193 

Hickson  Danchem  Corp 804-797-8105 

High  Point  Chemical  Corp  919-884-2214 

Hill  Petroleum  Company 203-661-4770 

Hilton  Davis  Chemical  Co 513-841-4000 

Himont,  USA,  Inc  302-996-6000 

Hodag  Chemical  Corp  312-675-3950 

Hoechst  Celanese  Corp: 

Bayport  Works,  SP  &  W  Div 713-474-6737 

Chemical  Group  Div 214-689-4000 

Engineering  Plastics  Div 201-635-2600 

Fibers  Industrial  Div  201-231-2000 

Fine  Chemical  Div 804-393-3100 

SpecialityChem  Group  Coventry    201  -231  -2000 

Plant. 

Sou-Tex    201-231-2000 

Hotfmann-LaRoche,  Inc 201-235-5000 

Honig  Chemical  &  Processing  Corp 201-344-0881 

E.  F.  Houghton  &  Co 215-666-4100 

Huls  America,  Inc 201  -981-5000 

Hummel  Croton,  Inc 201-754-1800 

Humphrey  Chemical  Co 203-281-0012 

Huntington  Laboratories,  Inc   219-356-8100 

Huntsman  Chemical  Corp   801-532-5200 

ICI  Americas,  Inc: 

Agricultural  Products  Div    302-886-8000 

Films  Group  Div    302-886-3793 


70  Diamond  Rd.,  Sphngfield,  NJ  07081. 
1127  Myrtle  St..  Elkhart,  IN  46515. 
7300  S.  Central  Ave.,  Chicago,  IL  60638. 
82  Burlews  Ct.,  Hackensack,  NJ  07601. 
13601  S.  Ashland  Ave.,  Riverdale, 

IL  60627-1099. 
5200  Speaker  Rd.,  Kansas  City,  KS 

66110. 
1 73  Sussex  St.,  Jersey  City,  NJ  07302. 
King  George  Post  Rd.,  Fords,  NJ  08863. 
Route  611 ,  Delaware  Water  Gap.  PA 

18327. 
3601  Decker  Dr..  Baytown.  TX  77520. 

2200  Renaissance  Blvd.,  Gulpn  Mills, 

Hercules  Plaza.  Wilmington,  DE  19894. 

822  S.  14th  St..  Manitowoc, 

Wl  54221-0250. 

790  -  21st  Ave.,  Paterson,  NJ  07513. 

RO.  Box  188,  Gulfport,  MS  39502. 

333  Linden  Ave.,  Dayton,  OH  45403. 

4505  Las  Virgenes  Rd..  Calabasas, 

CA  91302. 
215  N.  Centennial  St.,  Zeeland,  Ml 

49464. 
RO.  Box  400,  Danville,  VA  24543. 
243  Woodbine  St.,  High  Point,  NC  27261. 
RO.  Box  5038,  Houston,  TX  77262-5038. 
2335  Langdon  Farm  Rd.,  Cincinnati, 

OH  45237. 
RO.  Box  15439,  Wilmington,  DE  19894. 
7247  N.  Central  Park  Ave..  Skokie, 

IL  60076. 

RO.  Box  58160,  Houston.  TX  77258. 
1250  W.  Mockingbird  Lane.  Dallas, 

TX  75247. 
26  Main  St.,  Chatham.  NJ  07928. 
RO.  Box  5887.  Spartanburg. 

SC  29304-5887. 
1250  W.  Mockingbird  Lane.  Dallas, 

TX  75247. 
500  Washington  St.,  Coventry,  Rl  02816. 

RO.  Box  866,  Mt.  Holly,  NC  28120. 
340  Kingsland  St.,  Nutley,  NJ  07110. 
414Wilson  Ave.,  Newark,  NJ  07105. 
RO.  Box  930,  Valley  Forge,  PA  19482. 
80  Contennial  Ave.,  Piscataway, 

NJ  08855-0456. 
10  Harmich  Rd.,  S.  PlainfieW.  NJ  07080. 
45  Divine  St..  N.  Haven.  CT  06473-0325. 
970  E.  Tipton  St..  Huntington.  IN  46750. 
2000  Eagle  Gate  Tower,  Salt  City. 

UT  84111. 

Delaware  Corp.  Center.  Wilmington, 

DE  19897. 
Concord  Pike  &  Murphy  Rd..  Wilmington, 

DE  19897. 


A-9 


Appendix  A 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 

fication  Telephone 

code  Name  of  company  number  Office  address 


ICI 


IMC 

ISP 
IND 
IDC 
INL 

WM 

SPC 

IMI 
GBF 

IFF 

IPC 

CR2 
JRC 
JFR 
JRG 

JTO 
MRX 
JNS 
JOB 
KLM 

KTP 
KAN 

SVC 
KMP 

KMI 
KPI 

KYS 

KCW 

CHF 

KHI 

KPT 

LCP 


LTV 
LKY 


LRO 
ARf^ 


Lll 


ICI  Americas,  Inc — Continued 

Polyurethanes  Group  609-423-8300 

Resin  Div    508-658-6600 

Speciality  Chemicals  Div    302-886-3000 

IMC  Pittman-Moore,  Inc: 

Industrial  Chemical  Div 708-615-3700 

INDSPEC  Chemical  Corp 412-765-1200 

Indol  Color  Co..  Inc 201-242-1300 

Industrial  Color,  Inc 815-722-7402 

Inland  Steel  Co 312-346-0300 

Inolex  Chemical  Co   215-271-0800 

Insilco  Corp.,  Sinclair  Paint  Co.  Div 213-888-8888 

Insulating  Materials,  Inc 518-395-3300 

International  Bio-Synthetics  Inc  704-527-9000 

International  Flavor  &  Fragrances  Inc   ....  908-264-4500 

Interplastic  Corp 612-331-6850 

James  River  II,  Inc 804-644-5411 

Jarchem  Industries,  Inc   201-344-0600 

George  A.  Jeffreys  &  Co..  Inc 703-389-8220 

Andrew  Jergens  Co  513-421-1400 

Jetco  Chemicals,  inc   214-872-3011 

Johnson  Matthey.  Inc 609-853-8000 

S.  C.  Johnson  &  Son,  Inc 414-631-3388 

Jones-Blair  Co  214-353-1600 

Kalama  Chemical,  Inc    206-682-7890 

Kama  Corp 717-455-2022 

Kanasco,  Ltd    301-789-7800 

Kartshamns  LDP  Specialities,  USA 608-752-9007 

Kelly-Moore  Paint  Co.,  Inc 415-592-8337 

Kemin  Industries,  Inc 515-266-2111 

Kenrich  Petrochemicals.  Inc 201-823-9000 

Keysor  Century  Corp 805-259-2360 

Keystone  Color  Works,  Inc 717-854-9541 

Kincaid  Enterprises,  Inc 304-755-3377 

Koch  Refining  Co 316-832-5813 

Koppers  Industries,  Inc 412-227-2001 

LCP  Chemicals: 

Maine  Div.  of  Hanlin  Group,  Inc   201-225-4840 

West  Virginia,  Inc   304-843-1310 

LTV  Steel  Co.,  Inc    216-622-5000 

Lake  States  Div.  of  Rhinelander 715-369-4217 

Paper  Co. 

LaRoche  Chemical,  Inc    504-356-8406 

LaRoche  Industries  Inc 404-851-0475 

Lawter  International,  Inc 708-498-4700 


286  Mantua  Grove  Rd.,  W.  Deptford, 

NJ  08066-1732. 
730  Main  St..  Wilmington.  MA  01887. 
Concord  Pike  &  Murphy  Rd..  Wilmington, 

DE  19897. 

421  E.  Hawley  St..  Mundelein,  IL  60060. 
411  Seventh  Ave..  Pittsburgh.  PA  15219 
1029  Newark  Ave..  Elizabeth,  NJ  07201. 
50  Industry  Ave..  Joliet.  IL  60435. 
3210  Watling,  St.,  E.  Chicago.  IL  46312. 
Jackson  &  Swanson  Sts.,  Philadelphia. 

PA  19148. 
6100  South  Garfield  Ave..  Los  Angeles. 

CA  90040. 
1  Campbell  Rd..  Schenectady.  NY  12306. 
8720  Red  Oak  Blvd..  Charlotte. 

NC  28224-1068. 
1515  Highway  #36,  Union  Beach. 

NJ  07735. 
2015  NE  Broadway.  Minneapolis, 

MN  55413. 
4th  &  Adams  Sts..  Camas.  WA  98607. 
40  Ball  St.,  Newark.  NJ  07105. 
RO.  Box  909,  Salem.  VA  24153. 
2535  Spring  Grove  Ave..  Cincinnati, 

OH  45214. 
PO.  Box  1898.  Corsicana,  TX  75110. 
2001  Nolte  Dr..  W.  Deptford.  NJ  08066. 
1525  Howe  St..  Racine.  Wl  53403. 
2728  Empire  Central,  Dallas,  TX  75235 
Bank  of  California  Center,  Suite  1110, 

Seattle.  WA  98164. 
666  Dietrich  Ave.,  Hazelton,  PA  18201. 
6118  Robinwood  Road,  Baltimore. 

MD  21225. 
525  W.  First  St.,  Janesville,  Wl  53547. 
987  Commercial  St.,  San  Cark>s.  CA 

94070. 
2100  Maury  St..  Des  Moines.  lA  50301. 
140  E.  22nd  St..  Bayonne.  NJ 

07002-0032. 
PO.  Box  308,  Saugus.  CA  91350. 
151  W.  Gay  Ave..  York.  PA  17403. 
PO.  Box  549,  Nitro,  WV  25143. 
PO.  Box  2256.  Wichita.  KS  67201. 
436  Seventh  Ave..  Pittsburgh, 

PA  15219-1800. 

PO.  Box  149.  Orrington.  ME  04474. 
PO.  Box  Box  J.  Moundsville.  WV  26041. 
LTV  Steel  BIdg.,  25  W.  Prospect  Ave.. 

Cleveland,  OH  44115. 
515  W.  Davenport  St.,  Rhinelander. 

Wl  54501. 
P.O.  Box  1031.  Baton  Rouge,  LA  70821. 
1100  Johnson  Ferry  Rd.,  Alanta  GA 

30342. 
990  Skokie  Blvd..  Northbrook,  IL  60062. 


A-10 


Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  ciiemicais  alphaljetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 

fication  Telephone 

code         Name  of  company  number  Office  address 

LEA  Leatex  Chemical  Co 215-739-6324       2722  N.  Hancock  St.,  Philadelphia. 

PA  19133. 
LLI  Lee  Laboratories,  Inc 804-862-2534       2820  N.  Normandy  Dr.,  Petersburg. 

VA  23805. 
LVR  C.  Lever  Co.,  Inc    215-639-8640       736  Dunks  Ferry  Rd.,  Bensalem,  PA 

19020. 

LEV  Lever  Brothers  Co   212-688-6000       390  Park  Ave..  New  York.  NY  10022. 

LIL  Eli  Lilly  &  Co 317-276-6448       Lilly  Corporate  Center.  Indianapolis. 

IN  46285. 
Eli  Lilly  Industries,  Inc 809-257-5555       Call  Box  11 98  -  Puebb  Station,  Carolina, 

PR  00630-1198. 

MAR  Lignotech  (U.S.),  Inc 203-625-0701       81  Holly  Hill  Lane,  Greenwich,  CT  06830. 

Lie  Lilly  Industrial  Coatings.  Inc 317-634-8512       PO.  Box  946.  Indianapolis.  IN  46206. 

Lt\4C  Lomac,  Inc  616-788-2341       5025  Evanston  Ave.,  Muskegon,  Ml 

49443. 

BRD  Lonza.  Inc 201-794-2400       17-17  Route  208.  Fair  Lawn,  NJ  07410. 

LC  Lord  Corp..  Chemical  Products    814-868-3611        2000  W.  Grandview  Blvd..  Erie. 

Group.  PA  16514-0038. 

LCS  Louisiana  Chemical  Polymers.  Inc 504-775-1801        12537  Scenic  Hwy..  Baton  Rouge, 

LA  70807. 
LYP  Lyondell  Petrochemical  Co 713-652-7200       1221  McKinney.  Suite  1 600,  Houston. 

TX  77253-3646. 
STG  McCormick  &  Co..  Inc 301-771-7401       230  Schilling  Circle  S..  Hunt  Valley, 

MD  21031. 
MGK  McLaughlin  Gormley  King  Co 612-544-0341       8810- 10th  Ave.  N..  Minneapolis, 

MN  55427-4372. 
MNP  McWhorter.  Inc 312-428-2657       400  E.  Cottage  Place.  Carpentersville, 

IL  60110. 
RIK  3M  Pharmaceuticals 818-341-1300       19901  Nordhoff  St..  Northridge. 

CA.  91324. 
MAK  MAK  Chemical  Corp 317-288-4464       1200  Rochester  Ave..  Muncie. 

IN  47302. 

SOR  MW  Manufacturers,  Inc..  Southern 919-475-1348       P.O.  Box  68.  Thomasville,  NC  27360. 

Resin  Div. 

MCK  MacKenzie  Chemical  Works  Of  LA   504-886-2173       78015  Chemical  Rd..  Bush.  LA  70431. 

TZC  Magnesium  Elektron.  Inc  908-782-5800       500  Point  Breeze  Road,  Flemington, 

NJ  08822. 

MGR         Magruder  Color  Co..  Inc 201-242-1300       1029  Newark  Ave..  Elizabeth.  NJ  07208. 

MAL  Mallinckrodt.  Inc 314-895-2000       675  McDonnell  Blvd..  St.  Louis  MO 

63042. 

MOC         Marathon  Oil  Co 419-422-2121       539  S.  Main  St..  Findlay,  OH  45840. 

MRV  Marlowe-Van  Loan  Corp 919-886-7126       1511  Joshua  Circle,  High  Point,  NC 

27260. 

MCA  Masonite  Corp.,  Alpine  Resin  Div 601-649-6000       PO.  Box  1048,  Laurel.  MS  39440. 

MAX  Max  Marx  Color  Corp 201-373-7801        1200Grove  St..  Irvington.  NJ  07111. 

MYO  Mayo  Chemical  Co 404-696-6711        5544  Oakdale  Rd.,  Smyrna.  GA  30082. 

MLC  Melamine  Chemicals.  Inc 504-473-3121       PO.  Box  748.  Donaldsonville,  LA  70346. 

MRK  Merck  &  Co..  Inc 201-574-4000       PO.  Box  2000,  Rahway,  NJ  07065. 

MER  Merichem  Co   713-455-1311        1914  Haden  Rd..  Houston.  TX  77015. 

MLS  Miles  Inc..  Biotechnology  Products    219-262-6916       1127  Myrtle  St.,  Elkhart.  IN  46515. 

Div. 

MIL  Milliken  &  Co.,  Milliken  Chemical  Div 803-472-9041        PO.  Box  81 7,  Inman,  SC  29349. 

MMM         Minnesota  Mining  &  Manufacturing    612-733-3647       3M  Center  224-6S.  St.  Paul,  MN  55144. 

Co. 

MSC  Mississippi  Chemical  Corp 601-746-4131       PO.  Box  388,  Yazoo  City,  MS  39194. 

DKA  Mobay  Corp  713-477-8821       8701  Park  Place  Blvd.,  Houston  TX 

77017. 


A-11 


Appendix  A 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  Internatbnal 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                          number  Office  address 


Mobay  Chemical  Corp.: 

CHG  Agricultural  Chemicals  Div  816-242-2345 

VPC  Dyes  &  Pigments  Div  412-777-2000 

MOB  Pittsburgh  Div 412-777-2000 

SM  Mobil  Oil  Corp.: 

Beaumont  Refinery  Div 703-846-3000 

Chemical  Products  Div 201-321-6000 

Gas  Liquids  Dept    703-849-3000 

Petrochemicals  Div 713-590-7700 

Polystyrene  Business  Group    201-321  -6000 

MOA  Mona  Industries,  Inc 201-345-8220 

MON  Monsanto  Co    314-694-1000 

MNA  Monsanto  Agricultural  Co 314-694-1000 

MCI  Mooney  Chemicals,  Inc  216-781-8383 

MCP         Moretex  Chemical  Products,  Inc   803-583-8441 

MRF  Morflex,  Inc 919-292-1781 

MHI  Morton  International,  Inc 508-774-3100 

PYI  Morton  Chemical  Div    312-807-2000 

MRT  Morton  Chemical  Div.  312-807-2000 

CCW  Industrial  Chemical  &  Additives   513-733-2100 

MOT  Motomco,  Ltd  608-244-2904 

RTC  Mount  Vernon  Mills,  Inc   803-233-4151 

PNX  The  Murphy-Phoenix  Co    216-349-7179 

NMC  NAMICO,  Inc    215-482-6600 

LEM  Napp  Chemicals,  Inc   201  -773-3900 

NTC  National  Casein  Co    312-846-7300 

NCJ  National  Casein  of  New  Jersey    312-846-7300 

NSC  National  Starch  &  Chemical  Corp 201  -685-5000 

NTS  National  Steel  Corp.,  Great  Lakes  313-297-2100 

Div. 

NEP  Nepera,  Inc 914-782-1200 

CBD  Neste  Resins  Corp 503-687-8840 

NEV  Neville  Chemical  Co 412-331-4200 

NBC  New  Boston  Coke  Corp  614-456-4154 

NCC  Niacet  Corp    716-285-1474 

NLO  Niklor  Chemical  Co.,  Inc 213-830-2253 

NCP  Niles  Chemical  Paint  Co 616-683-3377 

NOC  TheNoracCo.Inc 818-334-2908 

Mathe  Div  818-334-2908 

FSN  NOR-AM  Chemical  Co 302-575-2000 

NW  Northwestern  Flavors,  Inc 312-231-6111 

NOR  Norwich  Eaton  Pharmaceutical,  Inc 607-335-2049 

NBI  Novo  Nordisk  Biochem,  Inc 919-494-2014 

NSW  The  Nutrasweet  Co    708-940-9800 

OBC  The  O'Brien  Corp 415-871-2300 


Hawthorne  Rd.,  Kansas  City,  MO  64120. 
Mobay  Road,  Pittsburgh,  PA 

15205-9741. 
Mobay  Road,  Pittsburgh,  PA 

15205-9741. 

3225  Gallows  Rd.,  Fairfax.  VA  22037. 
P.O.  Box  250,  Edison,  NJ  08818. 
RO.  Box  900,  Dallas,  TX  75221. 
World  Towers  One,  15600  Kennedy  Blvd., 

Houston,  TX  77032. 
PO.  Box  3029,  Edison,  NJ  08818. 
76  E.  24th  St..  Paterson,  NJ  07544. 
800  N.  Lindbergh  Blvd..  St.  Louis, 

MO  63167. 
800  N.  Lindbergh  Blvd.,  St.  Louis, 

MO  63167. 
2301  Scranton  Rd..  Cleveland.  OH 

44113. 
314  W.  Henry  St.,  Spartanburg,  SC 

29301 . 
2110  High  Point  Road,  Greensboro, 

NC  27403. 
150  Andover  St..  Dan  vers.  MA  01923. 
130  Montain  Creek  Church  Rd.. 

Greenville,  SC  29602. 
1 00  N.  Riverside  Plaza 
2000  West  St..  Reading.  OH  45215. 
3699  Kinsman  Blvd..  Madison.  Wl  53704. 
PO.  Box  2478.  Greenville.  SC  29602. 
6550  Davis  International  Pkwy. 

Solon.  OH  44139. 
4601  Flat  Rock  Rd..  Philadelphia.  PA 

19127. 
199MainSt.,  Lodi,  NJ  07644. 
601  W.  80th  St.,  Chicago.  IL  60620. 
601  W.  80th  St..  Chicago.  IL  60620. 
10  Finderne  Ave.,  Bridgewater,  NJ  08807. 
1  Quality  Dr.,  Ecorse,  Ml  48229. 

Route  #17,  Harriman,  NY  10926. 
1600  Valley  River,  Eugene,  OR  97401. 
2800  Neville  Rd.,  Pittsburgh,  PA  15225. 
600  River  Ave.,  New  Boston.  OH  45662. 
400  -  47th  St..  Niagara  Falls,  NY  14304. 
2060  E.  220th  St.,  Long  Beach,  CA 

90810. 
RO.  Box  307,  Niles,  Ml  49120. 
405  S.  Motor  Ave.,  Azusa,  CA  91702. 
169  Kennedy  Dr.,  Lodi,  NJ  07644-0230. 
3509  Silverside  Road,  Wilmington, 

DE  19810. 
120  N.  Aurora  St.,  W.  Chicago, 

IL  60185. 
1 7  Eaton  Ave.,  Nonwich,  NY  13815. 
State  Road  1003,  Franklinton,  NC  27525. 
1751  Lake  Cook  Rd.,  DeerfiekJ,  IL  60015. 
450  E.  Grand  Ave.,  S.  San  Francisco, 

CA  94080. 


A-12 


Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                            number  Office  address 


Occidential  Chemical  Corp.: 

HKD              Durez  Div  716-696-6000 

HK                 ED  &  S  Div   214-404-3300 

HKP              Vinyls  Div 215-251-1000 

OMC          Olin  Corp    203-356-2000 

WAY          Olin  Hunt  Speciality  Products,  Inc   201-972-6000 

OC            Omega  Chemicals,  Inc 803-582-5346 

ORG          Organics/LaGrange,  Inc 312-764-6700 

OCC          Orient  Chemical  Corp 908-355-4010 

BSW         Original  Bradford  Soap  Works,  Inc 401  -821  -2141 

CJO           C.  J.  Osborn  Chemicals,  Inc 609-662-0128 

OCF          Owens-Corning  Fiberglas  Corp  419-248-8000 

CNE          Oxy  Petrochemicals,  Inc 713-623-2246 

PBI            PBI-Gordon  Corp 816-421-4070 

PCR          PCR,  Inc 904-376-8246 

PDG           PD  Glycol 409-838-4521 

PSG          PMC  Inc.,  PMC  Specialities  Group 216-356-0700 

Inc. 

PMP          PMP  Fermentation  Products,  Inc 414-352-3001 

PPG          PPG  Industries,  Inc   412-434-3131 

PRA           Para-Chem. Southern  Inc 803-967-7691 

PAH           Parish  Chemical  Co 801-226-2018 

PD             Parke-Davis  Div.,  of  Warner  Lambert 616-392-2375 

Inc. 

PSC          Passaic  Color  &  Chemical  Co   201  -279-0400 

CHP          C.  H.  Patrick  &  Co.,  Inc    803-244^831 

PEL           Pelron  Corp   708-442-9100 

PEN           Penick  Corp 201-621-2804 

PAR           Pennzoil  Products  Co.,  Penreco  Div   713-337-1534 

BPT           Permuthane  Coatings,  Inc  508-531-1880 

PST           Perstorp  Compounds,  Inc 413-584-2472 

PST           Perstorp  Polyols,  Inc    419-729-5448 

PFN           Pfanstiehl  Laboratories.  Inc  708-623-0370 

PCW          Pfister  Chemical,  Inc    201-945-5400 

PFZ            Pfizer,  Inc 212-573-2323 

Pfizer  Pharmaceuticals,  Inc    809-846-4300 

PHR           Pharmachem  Corp 215-867-4654 

PLB           Pharmacia  P-L  Biochemicals,  Inc 414-227-3600 

PDI            Phelps  Dodge  Industries,  Inc 219-456-4444 

Phelps  Dodge  Magnet  Wire  Co. 

PLC           Phillips  66  Co 918-661-6600 

PPX           Phillips  Paraxylene,  Inc    809-864-1515 

PPR           Phillips  Puerto  Rico  Core,  Inc 809-864-1515 

PHC           Phthalchem,  Inc 513-681-0099 

PCI            Piedmont  Chemical  Industries.  Inc 919-885-5131 

PIC            Pierce  Chemical  Co 815-968-0747 

PIL             Pilot  Chemical  Co 213-723-0036 

PPL           Pioneer  Plastics  Corp 207-784-91 1 1 

IMC            PIttman-Moore,  Inc 812-232-0121 

PKL           Plaskolite,  Inc 614-294-3281 

PSL            PlaslokCorp 716-681-7755 


Waick  Rd.,  N.  Tonawanda,  NY  14120. 
5005  LBJ  Freeway,  Dallas,  TX  75244. 
PO.  Box  1772,  Berwyn,  PA  19312. 

120  Long  Ridge  Rd.,  Stamford,  CT 
06904. 

One  Wellington  Rd.,  Lincoln,  Rl  02865, 
PO.  Box  1723,  Spartanburg,  SC  29304 
7125  N.  Clark  St.,  Chicago,  IL  60626. 

121  Tyler  St..  Port  Newark.  NJ  07114. 
200  Providence  St.,  W.  Warwick,  Rl 

02893, 
820  Sherman  Ave.,  Pennsauken,  NJ 

08110. 
Fiberglas  Tower,  Toledo,  OH  43659. 
5  Greenway  Plaza.  Suite  2500,  Houston, 

TX  77046. 
1217W.  12th  St.,  Kansas  City, 

MO  64101-1407. 
RO.  Box  1466.  Gainsville.  FL  32609. 
PO.  Box  3785.  Beaumont,  TX  77704. 
20525  Center  Ridge  Rd,  Rocky  River, 

OH  44116. 
7670  N.  Port  Washington  Rd.,  Milwaukee. 

Wl  53217. 
One  PPG  Place,  Pittsburgh,  PA  15272. 
P.O.  Box  127,  Simpsonville,  SC  29681. 
145  N.  Geneva  Rd.,  Orem,  UT  84057. 
188  Howard  Ave.,  Holland,  Ml  49424. 

28-36  Paterson  St.,  Paterson,  NJ  07501. 
PO.  Box  2526,  Greenville,  SC  29602. 
7847  W.  47th  St.,  Lyons,  IL  60534. 
158MountOlive  Ave..  Newark  NJ  07714 
4401  Park  Ave..  Dickinson,  TX  77539. 
13  Corwin  St.,  Peabody,  MA  01960. 
238  Nonotuck  St..  Florence,  MA  01060. 
600  Matzinger  Rd,  Toledo.  OH  43612. 
1219  Glen  Rock  Ave..  Waukegan,  IL 

60085. 
Linden  Ave.,  Ridgefield,  NJ  07657. 
235  E.  42nd  St.,  New  York,  NY  10017. 
PO.  Box  628,  Barcetoneta,  PR  00617, 
719  Stefko  Blvd.,  Bethlehem,  PA  18016. 
2202  N.  Bartlett  Ave.,  Milwaukee,  Wl 

53202. 
4300  New  Haven  Ave.,  Fort  Wayne, 

IN  46803. 
Phillips  BIdg.,  Bartlesville,  OK  74004. 
PO.  Box  1162,  Guayama,  PR  00655. 
PO.  Box  1166.  Guayama,  PR  00655. 
266  W.  Mitchell  Ave.,  Cincinnati,  OH 

45232. 
331  Burton  Ave.,  High  Point,  NC  27261. 
3747  N.  Meridan  Rd.,  Rockford,  IL  61103. 
11756  Burke  St.,  Santa  Fe  Springs, 

CA  90670. 
1  Pionite  Rd.,  Auburn,  ME  04210. 
1401  S.  3rd  St.,  Terre  Haute,  IN  47808. 
PO.  Box  1497,  Columbus,  OH  43216. 
3155Broadway,  Buffalo,  NY  14227. 


A-13 


Appendix  A 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 

ficathn  Telephone 

code  Name  of  company  number  Office  address 


PLS 

PMC 

RCD 
PLR 
PRT 
JLP 
PG 

PRC 

QKO 
QCP 

USI 

QTR 

QUN 
AMU 
RSA 

RCN 
BLC 

RAY 
REG 

RCI 

RIL 

CRT 

LUR 

ELP 

RDA 
KCH 
AMS 

RIK 

RIV 

ROB 
CRT 

RH 

DRB 
ROM 

ROT 

RUC 
RUO 


Plastics  Engineering  Co 414-458-2121 

Plastics  Manufacturing  Co  214-330-8671 

Polysar.  Inc 203-934-6315 

Polysar,  Inc  Plastic  Div 508-537-1111 

Pratt  &  Lambert,  Inc 716-873-6000 

J.  L.  Prescott  Co 708-331  -8800 

Procter  &  Gamble  Co.,  Procter  & 513-627-6386 

Gamble  Mfg.  Co. 

Products  Research  &  Chemical 818-702-8900 

Corp. 

QO  Chemicals.  Inc 317-497-6110 

Quaker  Chemical  Corp 215-828-4250 

Quantum  Chemical  Corp.,  USI  Div 513-530-6500 

Questra  Chemicals  Corp  404-434-1333 

K.  J.  Quinn  &  Co.,  Inc 603-474-7177 

RPM  American  Emulsions  Co.,  Inc   404-226-7028 

RSA  Corp 914-693-1818 

Racon,  Inc   316-524-3245 

Ranbar  Technology,  Inc  412-486-1111 

Rayonier  Chemical  Products,  Inc 203-348-7000 

Regis  Chemical  Co 708-967-6000 

Reichhold  Chemicals,  Inc 914-682-5700 

Reilly  Industries,  Inc 317-247-8141 

Reilly-Whiteman,  Inc   215-423-5300 

Reilly-Whiteman,  Inc   215-423-5300 

Rexene  Products  Co   214-450-9000 

Rhone-Poulenc,  Inc  201-821-1000 

Manchem,  Inc 609-297-0100 

Ridgway  Color  Co    513-771-1900 

Riker  Laboratories,  Inc.,  Sub.  of  3M 818-341-1300 

Co. 

Riverdale  Chemical  Co 708-754-3330 

Robeco  Chemicals,  Inc    212-986-6410 

Roehr  Chemicals,  Inc,  Div.  of  Aceto 

Corp   718-784-8473 

Rohm  &  Haas  Co 215-592-3000 

Rohm  Tech,  Inc    508-342-5831 

Roma  Color,  Inc 61 7-676-3481 

Roquette  Corp   708-249-5950 

Rubicon,  Inc 504-673-6141 

Ruco  Polymer  Corp  516-931-8100 


3518  Lakeshore  Rd.,  Sheboygan,  Wl 

53081 . 
2700  S.  Westmoreland,  Dallas,  TX 

75233. 
345  Morgan  LA,  West  Haven,  CT  06516. 
690  Mechanic  St.,  Leominster,  MA  01453. 
PO.  Box  22,  Buffalo,  NY  14240. 
27  -  8th  St.,  Passaic,  NJ  07055. 
Spring  Grove  &  June  St.,  St.  Bernard, 

OH  45217. 
5430  San  Fernando  Rd.,  Glendale, 

CA  91209. 
2801  Kent  Ave.,  W.  Lafayette,  IN  47906. 
Elm  &  Lee  Sts.,  Conshohocken, 

PA  19428-0809. 
11500  Northlake  Dr.,  Cincinnati,  OH 

45249. 
2859  Paces  Ferry  Rd..  Atlanta,  GA 

30339. 
135  Folly  Mill  Rd.,  Seabrook.  NH  03874. 
1202  Dozier  St.,  Dalton,  GA  30721. 
690  Saw  Mill  River  Rd.,  Ardsley, 

NY  10502. 
6040  S.  Ridge  Rd.,  Wichita,  KS  67201. 
1114  William  Flinn  Highway,  Glenshaw, 

PA  15116. 
RO.  Box  68967.  Seattle.  WA  98188. 
8210  Austin  Ave..  Morton  Grove.  IL 

60053. 

800  Calitola  Dr.,  Research  Triangle  Park, 
Durham.  NC  27713. 

1510  Market  Square  Center,  Indianapolis, 
IN  46204. 

801  Washington  St.,  Conshohocken, 
PA  19428. 

2600  E.  Tioga  St.,  Philadelphia,  PA 

19134. 
5005  LBJ  Freeway,  Occidental  Tower, 

Dallas,  TX  75244. 
CN  5266,  Princeton,  NJ  08543-5266. 
275  Keystone  Dr.,  Bethlehem,  PA  18017. 
410  Glendale-Milford  Rd.,  Cincinnati, 

OH  45215. 
19901  Nordhoff  St.,  Northridge,  CA 

91324. 
220  E.  17th  St.,  Chicago  Heights, 

IL  60411-3699. 
99  Park  Ave.,  New  York,  NY  10016. 

52-20  37th  St.,  Long  Island  City,  NY 

11101. 
Independence  Mall  West.,  Philadelphia. 

PA  19105. 
119  Authority  Dr.,  Fitchburg,  MA  01420. 
749  Quequechan  St.,  Fall  River,  MA 

02723. 
1 550  Northwestern  Ave.,  Gurnee, 

IL  60031-2392. 
PO.  Box  517,  Geismar,  LA  70734. 
New  South  Rd.,  Hicksville,  NY  11802. 


A-14 


Synthetic  Organic  Chemicals,  1990 

Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 

Identi- 
fication Telephone 
code          Name  of  company                                            number  Office  address 


NES           Ruetgers-Nease  Chemical  Co 814-238-2424 

SBP           SBS  Products  Inc 517-799-4941 

SCM  SCN^  Corp.: 

Glidco  Organics    904-768-5800 

SOS          SSC  Industries,  Inc 404-762-9651 

NPR          Safeway,  Inc 415-632-7373 

STX           St.  Croix  Petrochemical  Corp 809-778-6450 

SLM          Salem  Oil  &  Grease  Co   508-745-0585 

Sandoz  Chemical  Corp.: 

S                    Sandoz  Chemical  Corp 704-331-7016 

SDC              Sandoz  Chemical  Corp 704-331-7016 

ZOC              Sandoz  Corp.  Protection 312-699-1616 

SCN          Schenectady  Chemicals,  Inc   518-370-4200 

SBC          Scher  Chemicals,  Inc 201-471-1300 

SCH          ScheringCorp   201-298-4000 

SPR          Scientific  Protein  Laboratories 608-849-5944 

SPA           Scott  Paper  Co 206-259-7409 

TXS           Scott  Polymers,  Inc    81 7-831  -3541 

SRL           G.  D.  Searle  &  Co 708-982-7000 

SQA          Sequa  Chemicals,  Inc    803-385-5181 

SKP           Shakespeare  Monofilament  Div 803-754-7011 

SHO          Shell  Oil  Co    713-241-9548 

SHC              Shell  Chemical  Co   713-241-9548 

SGO          Shenango.  Inc    412-771-4400 

SHP          Shepherd  Chemical  Co   513-731-1110 

SHX          Sherex  Chemical  Co.,  Inc 614-764-6500 

SHT           Shintech.  Inc 713-965-0713 

SMP          J.  R.  Simplot  Co 208-336-2110 

UPF           Stoss  Industries  Inc   205-254-7801 

SK              SmithKline  Beechman  Chemicals    215-751-4000 

SMO          Smooth-On,  Inc    908-647-5800 

SLC           Soluol  Chemical  Co.,  Inc   401-821-8100 

SAL           Solvay  Animal  Health,  Inc    515-257-2422 

SLT           Solvay  Polymers  Inc 713-522-1781 

SAC          Southeastern  Adhesives    704-754-3493 

SWR         Southwestern  Refining  Co.,  Inc  512-884-8863 

SPL            Spaulding  Composites  Co   716-692-2000 

ASL           Specialty Chem  Products  Corp 715-735-9033 

SOI            Specialty  Organics,  Inc 818-962-2008 

IPP             Spectrachem  Corp 201-595-8181 

sec           Standard  Chlorine  of  Delaware.  Inc 201-997-1700 

STP           StepanCo    815-727-4944 

SC             Sterling  Chemicals,  Inc 409-942-3360 

SD             Sterling  Drug,  Inc 212-907-2000 

212-907-2000 

SDW             Sterling  Organics  Div   212-907-2000 

CIN            Stockhausen,  Inc   919-333-3500 


201  Struble  Rd.,  State  College,  PA 

16801. 
302  Waller  St.,  Saginaw,  Ml  48602. 

P.O.  Box  389,  Jacksonville,  FL  32201. 
1550  E.  Taylor  Ave.,  East  Point,  GA 

30344. 
1 1 00  77th  Ave.,  Oakland,  CA  94621 . 
P.O.  Box  6801 ,  Sunny  Isle.  St.  Croix, 

U.S.  VI  00823-6801. 
60  Grove  St.,  Salem,  MA  01970. 

4000  Monroe  Rd.,  Charlotte,  NC  28205. 
4000  Monroe  Rd.,  Charlotte.  NC  28205. 
1300  E.  Touity  Ave.,  Des  Plaines,  II 

60018. 
Congress  &  10th  Ave.,  Schenectady, 

NY  12306. 
Industrial  West,  Clifton,  NJ  07012. 
1011  Morris  Ave..  Union.  NJ  07081. 
700  E.  Main  St.,  Waunakee,  Wl  53597. 
P.O.  Box  925,  Everett.  WA  98206. 
3607  N.  Sylvania  Ave..  Fort  Worth. 

TX  76111. 
5200  Old  Orchard  Rd.,  Skokie,  IL  60077. 
PO.  Box  70,  Chester,  SC  29706. 
6111  Shakespeare  Rd.,  Columbia, 

SC  29223 
PO.  Box  3105,  Houston.  TX  77253. 
PO.  Box  3105.  Houston.  TX  77253. 
200  Neville  Rd..  Pittsburgh,  PA 

15225-1690. 
4900  Beech  St.,  Cincinnati,  OH  45212. 
5777  Frantz  Rd.,  Dublin,  OH  43017. 
24Greenway  Plaza,  Suite  811,  Houston. 

TX  77046. 
P.O.  Box  912  Pocatelk).  ID  83204. 
3500  -  35th  Ave..  Birmingham.  AL  35207. 
One  Franklin  Plaza.  Phildelphia,  PA 

19101. 
1000  Valley  Rd..  Gillette,  NJ  07933. 
Green  Hill  &  Market  Sts.,  W.  Warwick. 
2000  Rockford  Rd.,  Charles  City,  lA 

50616. 
RO.  Box  1000,  Deer  Park,  TX  77536. 
815-D  Virginia  St.,  SW.,  Lenoir,  NC 

28645. 
RO.  Box  9217,  Corpus  Christi,  TX  78469. 
310  Wheeler  St.,  Tonawanda,  NY  14150. 
2  Stanton  St.,  Marinette,  Wl  54143. 
5623  N.  4th  St.,  Irwindale,  CA  91706. 
200  Sheridan  Ave.,  Paterson,  NJ  07512. 
1035  Belleville  Turnpike,  Kearny,  NJ 

07032. 
22  West  Frontage  Rd..  Northflekl.  IL 

60093. 
1200  Smith,  Texas  City.  TX  77592-1311. 
2144  E.  State  St.,  Trenton,  NJ  08619. 
RO.  Box  11247,  Barcelonita,  PR  00617. 
90  Park  Ave.,  New  York,  NY  1 001 6. 
2408  Doyle  St.,  Greensboro,  NC  27406. 


A-15 


Appendix  A 


Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chennicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report)  


Identi- 
fication 
code  Name  of  company 


Telephone 
number 


Office  address 


IRI             Stuart-Ironsides.  Inc 708-655-4595 

SUN          Sun  Company,  Inc   215-977-6358 

SNA          Sun  Chemical  Corp..  Pigments  Div   212-986-5500 

RAS           Surface  Coatings,  Inc 61 7-933-4200 

TCC           Sybron  Chemicai.Inc 609-893-1100 

INP            Synair  Corp    615-698-8801 

BUC          Synalloy  Corp.,  Blackman  Uhler 803-585-3661 

Chemical  Div. 

SRY            Synray  Corp 201-245-2600 

HFT           Syntex  Agribusiness.  Inc   417-866-7291 

SYP           Synthetic  Products  Co  216-531-6010 

SYT           Synthron.  Inc   704-437-8611 

TKD           Takeda  Chemical  Products  USA.  Inc 919-762-8666 

TEK           Teknor  Apex  Co  401-725-8000 

TLI             Teledyne  Industries.  Inc..  Teledyne    408-637-3731 

McCormick  Selph. 

TOC          Tenneco  Methanol  Co    713-757-2131 

TEN           Tennessee  Chemical  Co    615-496-3331 

TVA           Tennessee  Valley  Authority.  NFDC 205-386-3521 

TVA,  OACD,  Div.  of  Developmental 

Production. 

TER           Terra  International,  Inc 712-277-1340 

TER              Terra  International,  Inc   712-277-1340 

TX             Texaco  Chemical  Co    71 3-432-3734 

TSA           Texas  Alkyls,  Inc 713-479-8411 

TPC           Texas  Petrochemicals  Corp 713-477-9211 

TWO         Tonawanda  Coke  Corp 71 6-876-6222 

TRI            Triad  Chemical 504-473-9231 

TRO          Troy  Chemical  Corp 201  -589-2500 

TUL           Tull  Chemical  Co..  Inc   205-831-1154 

TLC           Twin  Lake  Chemical,  Inc    716-433-3824 

UPM          UOPInc 312-391-2000 

UHL           Paul  Uhlich  &  Co.,  Inc    914-478-2000 

DRL           Unichema  North  America 312-376-9000 

NCI            Union  Camp  Corp 201-628-2000 

NCI                BBA  Div    201-628-2000 

WTH             Chemical  Div 201-628-9000 

UCC           Union  Carbide  Corp 304-747-3825 

UOC          Union  Oil  Co.  of  California   213-977-5131 

UTP           Union  Texas  Products  Corp 713-623-6544 

USR           Uniroyal  Chemical  Co.,  Inc 203-573-3886 

UNN           United  Aniline  Co  617-762-4057 

UCM          United  Color  Manufacturing,  Inc 215-860-2165 

UNO          United  Erie,  Inc 814-456-7561 

USB           U.S.  Borax  &  Chemical  Corp  213-251-5400 


7575  Plaza  Court,  Willowbrook.  IL  60521 
1801  Market  St..  Philadelphia,  PA  19103. 
411  Sun  Ave..  Cincinnati,  OH  45232. 
100  Eames  St.,  Wilmingon.  MA  01887. 
P.O.  Box  66,  Birmingham  Rd., 

Birmingham,  NJ  08011. 
2003  Amnicola  Hwy.,  Chattanooga, 

TN  37406. 
Croft  Industrial  Park,  Spartanburg, 

SC  29304. 
209  N.  Michigan  Ave.,  Kenilworth, 

NJ  07033. 
PO.  Box  1246,  Springfield,  MO  65810. 
1000  Wayside  Rd..  Cleveland.  OH  44110. 
PO.  Box  1111,  Morganton.  NC  28655. 
PO.  Box  2577,  Wilmington.  NC  28402. 
505  Central  Ave.,  Pawtucket,  Rl  02861. 
3601  Union  Rd.,  Hollister,  CA 

95024-0006. 
1010  Milan  St.,  Houston,  TX  77252. 
1  Ocoee  St.,  Copperhill,  TN  37317. 
Muscle  Shoals,  AL  35660. 


Terra  Centre,  600  -  4th  St.,  Sioux  City, 

lA  51101. 
1000  Terra  Dr..  Woodward.  OK  73801. 
3040  Post  Oak  Rd..  Houston.  TX  77056. 
PO.  Box  600,  Deer  Park,  TX  77536. 
8600  Park  Place  Blvd.,  Houston.  TX 

77017. 
P.O.  Box  5007,  Tonawanda. 

NY  14151-5007. 
P.O.  Box  310,  Donaldsonville.  LA  70346. 
One  Avenue  L,  Newark.  NJ  07105. 
PO.  Box  3246.  Oxford,  AL  36203. 
520  Mill  St..  Lockport.  NY  14095. 
25  E.  Algonguin  Road,  Des  Plaines, 
1  Railroad  Ave.,  Hastings-on-Hudson, 

NY  10706. 
4650  S.  Racine  Ave.,  Chicago,  IL  60609. 
1600  Valley  Rd.,  Wayne,  NJ  07470. 
2051  N.  Lane  Ave.,  Jacksonville,  FL 

32236. 
875  Harger  St.,  Dover,  OH  44622. 

IL  60017-5017. 
PO.  Box  8361,  Charleston,  WV  25303. 
1201  W.  Fifth  St..  Los  Angeles.  CA 

90017. 
1330  Post  Oak  Blvd.  Houston 

TX  77252-2120. 
World  Headquarters.  Middlebury,  CT 

06749 
Endicott  St.,  Norwood.  MA  02062. 
638  Newtown-Yardley  Rd.,  Newton, 

PA  18940. 
438  Huron  St.,  Erie,  PA  16502. 
3075  Wilshire  Blvd.,  Los  Angeles, 

CA  90010. 


A-16 


Synthetic  Organic  Chemicals,  1990 


Table  A-1 — Continued 

Synthetic  organic  chemicals  alphabetical  directory  of  manufacturers,  by  company,  1990 

(Names  of  synthetic  organic  chemicals  manufacturers  that  reported  production  and/or  sales  to  the  U.S.  International 
Trade  Commission  for  1 990  are  listed  below  alphabetically,  together  with  their  identification  codes  as  used  in  the  15 
individual  sections  of  this  report) 


Identi- 
fication 
code  Name  of  company 


Telephone 
number 


Office  address 


USX 


UTC 
UPJ 
CWN 

VSV 
VLR 
VCM 
VDM 
VNC 

VND 
VEL 
VIN 
VCC 

VKR 
VST 

VTM 

FRO 

VYN 

SWS 

WJ 

EW 

WPG 


WVA 
WRD 

WPS 

WHW 

CHN 

WTC 

WCL 

WYK 

WYT 


PAT 


U.S.  Steel,  Div.  Of  USX: 

Clainon  Plant    412-433-4980 

Gary  Works 219-888-4657 

Unitex  Chemical  Corp    919-378-0965 

The  Upjohn  Co 61 6-323-4000 

Fine  Chemicals 203-281  -2700 

Valentine  Sugars,  Inc 504-532-2541 

Valero  Refining  &  Marketing  Co 512-246-2000 

Vanchem,  Inc  716-434-2624 

Van  De  l^ark  Chemical  Co.,  Inc 716-433-6764 

Vanderbilt  Chemical  Corp 203-744-3900 

203-853-1400 

Van  Dyk,  Div.  of  Mallinckrodt,  Inc 201-450-3206 

Velsicol  Chemical  Corp    708-698-9700 

Vineland  Chemical  Co..  Inc    609-691-3535 

Vinings  Industnes.  Inc    404-436-1542 

Virkler  Co 704-527-2350 

Vista  Chemical  Co   713-588-3000 

Vitamins,  Inc 312-861-0700 

Vulcan  Ivlaterials  Co.,  Chemicals  Div 205-877-3000 

Vygen  Corporation  216-998-1120 

Wacker  Silicones  Corp 517-264-8500 

Warner-Jenkmson  Co 314-658-7342 

Westinghouse  Electric  Corp 412-864-8200 

Electrical  Materials  Div. 

WestPoint  Pepperell.  Inc    404-645-4753 

Grifftex  Chemical  Co.  Sub. 

Westvaco  Corp 212-688-5000 

Weyerhauser  Co    715-384-2141 

Wheeling-Pittsburgh  Steel  Corp 304-234-2400 

Whittemore-Wright  Co.,  Inc   617-242-1180 

Wil-Gro  Fertilizer,  Inc  918-825-3383 

Witco  Corp 201-573-2800 

Wright  Corp    919-251-0234 

Wyckoff  Chemical  Co.,  Inc 616-637-8474 

Wyeth  Laboratories,  Inc.,  Wyeth    215-341-3867 

Laboratories  Div.  of  American 

Home  Products  Corp. 

Yorkshire  Pat-Chem,  Inc 803-233-3941 


600  Grant  St.,  Pittsburgh,  PA  15219. 
1  N  Broadway,  Gary,  IN  46402. 
520  Broome  Rd.,  Greensboro,  NC  27406. 
7000  Portage  Rd.,  Kalamazoo,  Ml  49001. 
410  Sackett  Point  Rd.,  North  Haven, 

CT  06473. 
Rt  2,  Box  625,  Lockport,  LA  70374. 
530  McCullough,  San  Antonio,  TX  78292. 
1  N.  Transit  Rd.,  Lockport,  NY  14094. 
1  N.  Transit  Rd.,  Lockjxjrt,  NY  14094. 
31  Taylor  Ave.,  Bethel,  CT  06801. 

and  Rt.  #2,  Box  54,  Murray,  KY  42071. 
Main  &  William  Sts.,  Belleville,  NJ  07109. 
5600  N.  River  Rd.,  Rosemont,  IL  60018. 
1611  Wheat  Rd..  Vineland,  NJ  08360. 
3950  Cumberland  Pkwy.,  Atlanta, 

GA  30101. 
1022  Pressley  Rd..  Charlotte,  NC  28273. 
15990  N.  Barker's  Landing  Rd., 

Houston,  TX  77224. 
200  E.  Randolph  Dr.,  Chicago,  IL  60601. 
RO.  Box  7689,  Birmingham,  AL  35233. 
Middle  Road,  Ashtabula,  OH  44004. 
3301  Sutton  Rd.,  Adrian,  Ml  49221. 
2526  Baldwin  St.,  St.  Louis,  MO  63106. 
Route  993,  Manor,  PA  15665. 

1900  Cunningham  Dr.,  Opelika,  AL 
36801. 

299  Park  Ave.,  NY  NY  10171. 

118  S.  Palmetto  Ave.,  Marshfield,  Wl 

54449. 
1134  Market  St.,  Wheeling,  WV  26003. 
62  Alford  St.,  Boston,  MA  02129. 
PO.  Box  429,  Pryor,  OK  74362. 
155  Tice  Blvd.,  Woodcliff  Lake,  NJ  07675. 
1 02  Orange  St.,  Wilmington,  NC  28403. 
1421  Kalamazoo  St.,  S.  Haven,  Ml 

49090. 
PO.  Box  13745,  Philadelphia, 


11  Worley  Road,  Greenville,  SC  29602. 


Source:  Compiled  from  data  received  in  response  to  questionnaires  of  the  U.S.  International  Trade  Commission. 


A-17 


Synthetic  Organic  Chemicals.  1990 


Table  B-1 — Continued 

Cyclic  Intermediates:  Glossary  of  synonymous  names 


Common  name Standani  (chemical  abstracts)  name 

F  acid 7-Hydroxy-2-naphthalenGsulfonicacid. 

Fast  Red  G  base 2-Nilrc>-p--toluidine  [N2=1I. 

Fast  Scarlet  R  base 5-Nitro-o-anisidine[NH2=1]. 

Fischer's  aldehyde 1 ,3,3-Trimethyl-w@,a-indolineacetaldehyde. 

Fischer's  base 1 ,3,3-Trimethyl-2-methylenGindoline. 

Freund's  acid 4-Amino-2,7-naphthalGnGdisulfonicacid. 

G  satt 7-Hydroxy-1 ,3-naphthalenesulfonic  acid,  sodium  salt. 

Gamma  acid   6-Amino-4-hydroxy-2-naphthalenesulfonicacid, 

sodium  salt. 
Gold  salt    9,10-Dihydro-9,10-dioxo-1-anthracenBsulfonic 

acid  and  salt. 

H  acid    4-Amino-5-hydroxy-2,7-naphthalenedisutfonic 

acid,  (8-Amino-1  -naphthol-3,6-disulfonic  acid). 

Hellimellitene 1 ,2,3-Trimethylbenzene. 

Indoxyl 3(2H)-lndolone. 

Isodurene 1 ,2,3,5-Tetramethylbenzene. 

J  acid 7-Amino-4-hydroxy-2-naphthalenesulfonic  acid, 

sodium  salt. 
J  acid  urea 7,7'-Ureylenebis[4-+iydroxy-2- 

naphthalenesulfonic  acid] 

K  acid 4-Amino-5-hydroxy-1 ,7-naphthalenedisulfonic  acid. 

Koch's  acid    8-Amino-1,3,6-naphthalenetrisul(onicacid. 

L  acid 5-Hydroxy-1-naphthalenesulfonicacid. 

Lake  Red  C  amine 2-Amino-5-chloro-p-toluenesulfonicacid. 

Laurent's  acid    S-Amino-l-naphthalenesuHonicacid. 

M  acid   8-Amino— 4-hydroxy-2-oaphthalenesulfonicacid. 

MEP 5-Ethyl-2-picoline  (2-Methyl-5-ethylpyridine). 

Mesitylene 1 ,3,5-Trimethylbenzene. 

Methane  base   4,4'-Methylenebis[N,N-dimGthylaniline). 

Michler's  hydrol 4,4'-Bis[dimothylamino]benzhydrol. 

Michler's  ketone 4,4'-Bis(dimethylamino]benzophenone. 

MOCA  3,3'-Dichloro— 4,4'-diaminodiphGnylmethane. 

MVP 5-Vinyl-2-picoline. 

Naphthionk:  acid   4-Amino-1-naphthalGnesulfonicacid. 

o-Naphthonk:  ackJ   1-Amino-2-naphthalenesulfonicacid. 

b-Naphthol    2-Naphthol.  tech 

Naphthol  AS 3-Hydroxy-2-naphthanilidG. 

a-Napthylamine 1-Naphthylamine. 

Neville  &  Winther's  acid 4-Hydroxy-1-naphthalGnGsulfonicacid. 

m-NitrobenzoyI  J  ackl 4-Hydroxy-7-(m-nitrobenzamido>-2- 

naphthalenesuHonic  acki. 

Oxy  Koch's  ackJ 1-Naphthol-3,6,8-trisulfonk:  acid. 

PentaanthrimkJe 1,4,5,8-Tetrakis(1-anthraquinonylamino) 

anthraquinone. 

Peri  acid 8-Amino-1-naphthalenesul1onk:acid. 

Phenylbiphenyl    Terphenyl. 

N-Phenyldiethanolamine 2,2'-[(PhGnyl)imino)diethanol. 

Phenyl  gamma  acid 6-Anilino-4-hydroxy-2-naphthalGnesutfonk;acid. 

Phenyl  J  acid 7-Anilino-4-hydroxy-2-naphthalenesul1onicacid. 

Phenyl  peri  ackl 8-Anillno-1-naphthalenesulfonicacid. 

Picrk:  acid    2,4,6-Trinrtrophenol. 

POPOP   1 ,4-Bis[2-(5-phenyloxazolyl)bGnzene. 

Pseudocumene 1 ,2,4-Trimethylbenzene. 

Pyrazoleanthrone Anthra(1 .9-cd]pyrazol-6(2H>-one. 

B-3 


Appendix  B 

Table  B-1 — Continued 

Cyclic  Intermediates:  Glossary  of  synonymous  names 


Common  name  Standard  (chemical  abstracts)  name 

Pyrazoleanthrone  yellow (3,3'-Blanthral[1 ,9-cd}-pyrazole}-6,6'- 

(2H,2'H)dionG 
Pyrazolone  T  5-Oxo-1-(p-sulfophenyl)-2-pyrazollne-3- 

carboxylic  acid. 

Quinlzarin    1 ,4-Dihydroxyanthraqulnone. 

2-Ouinizarinsutfonic  acid 9,10-Dinydro-1,4-dihydroxy-9,10-dioxo-2- 

anthracenesulfonic  acid. 

Quinoline  yellow  base  Quinophthalone. 

R  salt 3-Hydroxy-2,7-naphthalenedisulfonic  acid, 

disodium  salt. 

RG  acid  (Violet  acid) 4-Hydroxy-2,7-naphthalenedisulfonicacid. 

Rhoduline  acid  (J  Acid  imide) 7,7'-lminobis[4-hydroxy-2-naphthalenesulfonic  acid]. 

RR  acid  3-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid. 

S  acid 4-Amino-5-hydroxy-1-naphthalenesulfonicacid. 

Schaffer's  acid 6-Hydroxy-2-naphthalenesulfonicacid. 

Silver  salt 9,10-Dihydro-9,10-dioxo-2-anthrazenesulfonic 

acid  and  salt. 

Solvent  Yellow  1    p-Phenylazoaniline  and  hydrochloride. 

Solvent  Yellow  3    4-(o-Tolylazo)-o-toluidinG. 

SS  acid  (Chicago  acid) 4-Amino-5-hydroxy-1,3-naphthalenedisulfonicacid. 

Sulf  anilic  acid p-Aminobenzenesulfonic  acid. 

o-Sulfobenzaldehyde  o-Formylbenzenesulfonic  acid. 

Tetralin 1 .2,3,4-Tetrahydronaphthalene. 

Thiolindoxyl 3(2H)-Thianaphthenone. 

Thiosalicylic  acid  o-Mercaptobenzoic  acid. 

Tobias  acid 2-Amino-1-naphthalenesulfonicacid. 

TOD!   Bitolylene  diisocyanate. 

o-Tolidine    3.3'-Dimethylbenzidine. 

a-Toluic  acid   Phenylacetic  acid. 

a-Tolunitrile Phenylacetonitrile. 

4-n>-Tolylenediamine  Toiuene-2,4-diamine. 

Trimellitic  anhydride 1 ,2,4-Benzenetricarboxylic  acid,  1 ,2-anhydride. 

Trimethyl  base 1 ,3,3-Trimethyl-2-methyleneindoline. 

Trinitrophenol Picric  acid. 

Urea  J  acid  (J  acid  urea) 7,7'Ureylenebis[4-hydroxy 

-2-naphthalenesulfonic  acid]. 

VeratrakJehyde   3,4-Dimethoxybenzaldehyde. 

Veratrole   o-DimethoxybenzGne. 

Vinyltoluene ar-Methylstyrene. 

VioiGt  acid  (RG  acid) 4-Hydroxy-2,7-naphthalenedisulfonicacid. 


B-4 


APPENDIX  C 

SYNTHETIC  ORGANIC  CHEMICALS, 

U.S.  PRODUCTION  AND  SALES,  1990, 

HARMONIZED  SYSTEM  BASIS 


Appendix  C 

Synthetic  Organic  Chemicals,  U.S.  Production  and  Sales,  1990,  Harmonized 

System  Basis 

The  following  table  contains  1990  U.S.  production  and  sales  data  for  synthetic  organic 
chemicals  in  the  6-digit  Harmonized  System  (HS)  format.  The  Commission  decided  to  compile 
such  data  in  this  format  in  response  to  the  decision  by  the  U.S.  Bureau  of  the  Census  to  publish 
Standard  Industrial  Classification  (SIC)  data  which  will  be  convertible  to  the  HS  beginning  with 
the  1987  Census  of  Manufactures.  The  U.S.  Bureau  of  the  Census  has  historically  referred  to  the 
Synthetic  Organic  Chemicals,  United  States  Production  and  Sales  (SOC)  report  in  the  chemicals 
section  of  the  Census  of  Manufactures,  which  permits  them  to  omit  collecting  synthetic  organic 
chemicals  production  and  shipments  data  from  its  respondents.  Because  of  this  situation,  the  SOC 
data  will  now  also  be  compiled  on  an  HS  basis  to  provide  comparablility  with  the  new  SIC  format. 

The  table  provides  production  and  sales  data  on  a  6-digit  HS  basis  only  where 
publication  would  not  violate  the  statutory  provisions  relating  to  unlawful  disclosure  of 
information  accepted  in  confidence  by  the  Commission.  It  includes  only  the  6-digit  item  numbers 
with  publishable  data  from  a  number  of  HS  chapters  in  which  these  chemicals  are  classified,  but 
does  not  provide  totals  by  chapter  or  overall  total  figures. 


C-2 


Synthetic  Organic  Chemicals,  1990 


Table  B-1 — Continued 

Cyclic  Intermediates:  Glossary  of  synonynfious  names 


Common  name Standard  (chemical  abstracts)  name 

F  acid 7-Hydroxy-2-naphlhalenesulfonicacid. 

Fast  Red  G  base 2-Nitro-p-toluidine  [N2-1]. 

Fast  Scarlet  R  base 5-Nttro-o-anisidine  [NH2=1  ]. 

Fischer's  aldehyde 1 ,3,3-Trimethyl-w@,a-indolineacetatdGhyde. 

Fischer's  base 1,3,3-Trimethyl-2-methyleneindoline. 

Freund's  acid 4-Aniino-2,7-naphthalenedisulfonicacid. 

G  salt 7-Hydroxy-1 ,3-naphthalenesutfonic  acid,  sodium  satt. 

Gamma  acid    6-Amino--4-hydroxy-2-fiaphthalenesulfonicacid, 

sodium  salt. 
Gold  salt    9,10-Dihydro-9,10-dioxo-1-anthracenesulfonic 

acid  and  salt. 

H  add    4-Amino-5-hydroxy-2,7-naphthalenedisulfonic 

acid,  (8-Amino-1-naphthol-3,6-disulfonic  acid). 

Hellimellitene 1 .2.3-Trimethylbenzene. 

Indoxyl 3(2H)-lndolonG. 

Isodurene 1 .2,3,5-Tetramethylbenzene. 

J  acid 7-Amino-4-hydroxy-2-naphthalenesulfonicacid, 

sodium  salt. 
J  acid  urea 7,7'-UreylGnGbis{4-hydroxy-2- 

naphthalenesulfonic  acid] 

K  acid 4-Amino-5-hydroxy-1 ,7-naphthalenedisutfonic  acid. 

Koch's  acid    8-Amino-1 ,3.&-naphthalGnetrisulfonicacid. 

L  acid 5-Hydroxy-1-naphthalenesulfonicacid. 

Lake  Red  C  amine 2-Amino-5-chloro-p-toluenesulfonicacid. 

Laurent's  acid    S-Amino-l-naphthalenesulfonicacid. 

M  acid   8-Amino-4-hydroxy-2-naphthalenesulfonicacid. 

MEP 5-Ethyl-2-picoline  (2-Methyl-5-ethylpyridine). 

Mesitylene 1 ,3,5-TrimGthylbenzene. 

Methane  base  4,4'-MGthylenGbis[N,N-dimGthylaniline]. 

Michler's  hydro! 4,4'-Bis[dimethylamino]ben2hydrol. 

Michler's  ketone 4,4'-Bis(dimethylamino]bGnzophenone. 

MCX)A  3,3'-Dichloro-4,4'-diaminodiphenylmethane. 

MVP 5-Vinyl-2-picoline. 

Naphthionc  acid   4-Amino-1-naphthalenesulfonicacid. 

o-Naphthionic  acid    1-Amino-2-naphthalenosulfonicacid. 

b-Naphthol    2-Naphthol.  tech 

Naphthol  AS 3-Hydroxy-2-naphthanilide. 

a-Napthylamine 1-Naphthylamine. 

Neville  &  Winther's  acid 4-Hydroxy-1-naphthalenesulfonicacid. 

m-NitrobenzoyI  J  acid 4-Hydroxy-7-(m-nitroben2amido)-2- 

naphthalenesulfonic  acid. 

Oxy  Koch's  acid 1-Naphthol-3,6,8-trisulfonic  add. 

Pentaanthrimide 1,4,5,8-Tetrakis(1-anthraquinonylamino) 

anthraquinone. 

Peri  acid S-Amino-l-naphthalenesulfonicacid. 

Phenylbiphenyl    Terphenyl. 

N-Phonyldiethanolamine 2,2'^(Phenyl)imino]diethanol. 

Phenyl  gamma  acid 6-Anilino-4-hydroxy-2-naphlhalenesulfonicacid. 

Phenyl  J  acid 7-Anilino-4-hydroxy-2-naphthalenesuHonicacid. 

Phenyl  peri  acid 8-Anilino-1-naphthalenesulfonicacid. 

Picric  acid    2,4,6-Trinitrophenol. 

POPOP   1 ,4-Bis[2-(&-phenyloxazolyl)benzene. 

Pseudocumone 1 ,2,4-Trimethylbenzene. 

Pyrazoleanthrone Anthra|1  ,&-cd]pyrazol-6(2H)-one. 

B-3 


ApperuUxB 

Table  B-1— Continued 

Cyclic  Intermediates:  Glossary  of  synonymous  names 


Common  name Standard  (chemical  abstracts)  name 

Pyrazoleanthrone  yellow [3,3'-Blanthral[1,9-cd]-pyrazole)-€,6'- 

(2H,2'H)dione 
Pyrazolone  T  5-Oxo-1-(p-suHophenyl)-2-pyra2olin6-3- 

carboxylic  acid. 

Quinizarin    1 ,4-Dihydroxyanthraquinone. 

2-Quinizarinsulfonic  add 9,10-Dinydro-1,4-dlhydroxy-9,10-dioxo-2- 

anthracenesulfonlc  acid. 

Quinoline  yellow  base  Quinophthalone. 

R  salt 3-Hydroxy-2,7-naphthalenedisulfonic  acid, 

disodium  salt. 

RG  acid  (Violet  acid) 4-Hydroxy-2,7-naphthalenedisulfonicacid. 

Rhoduline  acid  (J  Acid  Imide) 7,7'-lminobis(4-hydroxy-2-naphthalenesulfonic  acid). 

RR  acid  3-Amino-5-hydroxy-2,7-naphthalenedisulfonic  acid. 

S  acid 4-Amino-5-hydroxy-1-naphthalenesulfonicacid. 

Schaffer's  acid 6-Hydroxy-2-naphthalenesulfonicacid. 

Silver  salt 9,10-Dihydro-9,10-dioxo-2-anthrazenesulfonic 

acid  and  salt. 

Solvent  Yellow  1    p-Phenylazoaniline  and  hydrochloride. 

Solvent  Yellow  3    4-(o-Tolylazo)-o-toluidine. 

SS  acid  (Chicago  acid) 4-Amino-5-hydroxy-1,3-naphthalenedisulfonicacid. 

Sulfanilic  acid p-Aminobenzenesulfonic  acid. 

o-SuHobenzaldehyde  o-Formylbenzenesulfonic  acid. 

Tetralin 1 ,2,3.4-Tetrahydronaphthalene. 

Thiolindoxyl 3(2H)-Thianaphthenone. 

Thiosalicylic  acid  o-Mercaptobenzoic  acid. 

Tobias  acid 2-Amino-1-naphthalenesulfonicacid. 

TODI    Bitolylene  diisocyanate. 

o-Tolidine    3,3'-DimGthylbenzidine. 

a-Toluic  acid   Phenylacetic  acid. 

a-Tolunitrile  Phenylacetonitrile. 

4-n»-Tolylenediamine  Toluene-2,4-diamine. 

Trimellitic  anhydride 1,2,4-Benzenetricarboxylicacid,  1 ,2-anhydride. 

Trimethyl  base 1 ,3,3-Trimethyl-2-methyleneindoline. 

Trinitrophenol Picric  acid. 

Urea  J  acid  (J  acid  urea) 7,7'Ureylenebis(4-hydroxy 

-2-naphthalenesultonic  acid). 

VeratrakJehyde   3,4-Dimethoxybenzaldehyde. 

Veratrole   o-Dimethoxybenzene. 

Vinyltoluene ar-Methylstyrene. 

Violet  acid  (RG  acid) 4-Hydroxy-2.7-naphthalenedisulfonicacid. 


B-4 


APPENDIX  D 
ALPHABETICAL  CHEMICAL  INDEX 


Appendix  D 

Alphabetical  Chemical  Index 

The  alphabeiical  index  of  chemicals  contained  in  this  appendix  table  is  an  outgrowth  of  the 
processing  of  data  by  the  U.S .  International  Trade  Commission  for  its  annual  report.  Synthetic  Organic 
Chemicals.  United  States  Production  and  Sales.  This  index  will  aid  those  who  have  an  interest  in  the 
report,  either  as  users  of  the  published  data  or  as  suppliers  of  individual  company  data  to  the 
Commission,  principally  by  showing  the  section  number  and  line  item  number  of  specific  chemicals. 
This  information  can  be  used  to  assist  in  locating  a  chemical  in  the  report  and  to  provide  respondents  to 
the  Commission's  questionnaire  with  information  on  where  to  list  their  production  and  sales  data.  The 
index  shows  only  those  chemicals  for  which  production  or  sales  were  reported  to  the  Commission  for 
this  edition  of  the  report 

The  index,  initially  designed  for  Commission  use  in  computer  processing  of  data  for  the  annual 
report,  has  certain  characteristics  that  should  be  noted  to  increase  its  usefulness.  For  example,  superior 
headings  for  indi v  idual  entries  are  not  shown  in  the  index.  Thus,  understanding  the  contents  of  the  Hrst 
item  in  the  index,  "accelerators,  activators,  and  vulcanizing  agents,  acyclic,  other"  necessitates  that 
the  index  user  turn  to  the  individual  section  (in  the  report)  and  item  number  (in  the  questionnaire)  to 
fmd  those  acyclic  accelerators,  activators,  and  vulcanizing  agents  already  specified.  Similarly,  the 
index  entry  "specific  gravity  0.940  and  below"  does  not  by  itself  identify  the  chemical  product.  The 
index  user  will  need  to  turn  to  the  indicated  section  number  and  item  number  to  determine  the  chemical 
referred  to — in  this  case,  polyethylene. 

The  chemical  names  used  in  this  report  and  in  the  questionnaires  sent  to  U.S.  producers  to 
obtain  the  data  aggregated  in  the  report  are  listed  alphabetically  in  the  fu-st  column  of  each  listing  in  the 
index .  The  second  column  refers  to  the  section  in  the  report  and  questionnaire  containing  the  chemical, 
and  the  third  column  shows  the  appropriate  item  number  in  that  section  in  the  questionnaire. 


D-2 


Synthetic  Organic  Chemicals,  1990 


6    . 


^;£ 


d>* 


C>OOOCJ'^OOOOOOOOOI~^0000»-000»-'>»OOOOOOOOt--.0)0'-mcOCT>t^O>'*0)0000 
<0OOh.0>»-OOOOOOOO<i3OOOO0000O)C>JC\JC0OOOir)OOOtmU><0l00000C>JO«DC0OOOO 

opO'-^_c\jpppc>qppppppppc\jc>jcs)cococoqqpopop'-;''-^'^'^^»^T-c\)cypjTroppp 

■*'ir>tDo6ododoicJcn<D'odc>^'ininc^r>^oDobodcba3od<i)odo)0)0'tin 

»--t-»-^»-t-»-corjcocO'^^'«i''^uimioto«>u3<r3io<£)<DtDooo)o>a)a)0>o>o>oioio)o»o)ooooot-^i^t-^ 


CVJ  CVJ  CM  C\J  Csl  CM  CM  ' 


■CJCMCMCMCM'-'-'- 


«D  0>  ^  »-  r-  CM  -Og,  i2  CM  §1  § 

SSSSSSS^SS  —  —  —  —  — 
OD  CD  ffl  ffi  ffl  ffl  ^  CD  CD  CD  CD  ffl 

:sss.'5s:5:sss:s:s:s 


C000'-»-C000'-^O 

»-CM^»c^J^^c?Joo<»9>t^'CMc^ 

^(0(00><-'<-CM^CMCjrOCOCO 
CD  GO  CD  CD  CD  ffi  OD  3S  CD  ffl  ffl  CD  S 

:y.-2.'2:5:2ssss."5:5ss 


h»  o>  o  »- u)  00  o>  r^  O)  ^ 

2'<»o>o<or-oorfunDCDci5oooocMco«o 

«  ,-  ^IOO)0)Cn«-»-»-»-'-'-»-CMCMCM 

■g'cccccccccccccccc 
3S222992229222S59 

5  ffl  CD  CD  CD  CD  CD  CO  CD  CD  CO  OO  CO  CD  CO  CO  CD 

o  o  o  o  q  o  o  o  o  o  o  o  o  o  o  o  o 
<<<<<<<<<<<<<<<<< 


^  "O  »-  •-  CM 
C  c  c  c  c 

:5:5:2:ss 

u  u  u  u  y 
<<<<< 


lOOOOOOOO 


O>U)t>>f^00IAIAIO<OCMin 


oooooooo  oooo 

oSoOoScMO    SoOO 


O  OO  o  o  o  o 


oooi/)or-o>      o>  irt  < 


IPIOPPPPQO 

lOirtTrr^oooo 


(}>ir>pomir>oo( 


00  0>  O  t^  »- •- U>  CM  »- «0  •- CM    0>  ^  m  CO  •- »- »-   00  to  CM  00  CO  o>  OO  5  •- ^ 

00      »-      »-•-•- •t-       o      CO       <o »- T- o)      00  00      toot      CO o» "- * o  o  r- "- 

9  •-  00        ^         •-  CMCM        »-  ■^CMCMCMCM 


o *- O O O »- »- O O »- »-       •- OO O O O O O  O r- o  »-        ^ooo«-»-»-       »- o »- o o o «- O  O  I 


»jX 

CBC 

o    .o 

«.U  re 

o  o  o 

S      -S   O^  ^  ^  (fl 

'*                  .    Q     Q  O  O 

u  re  re  re  fl] 

fr  •  »  «  a 


2  •  •  i  >.?  -S  5 

€  ^S  3  « -5  9-  c 

»  o  oi"o-o^o  2 

g  c  E  o  «  re  re  5  0 
t  t  t^  y  #1  <>  ».  *  " 
re  <"  ™  ™  -^  J^  ji  •  2 


■5  >>:2 
■«  •  = 

re  f.o 

re  «  re 
o  reB 

9   O   O 

o<  o 


8  E£  : 

re  re  a. 
o  c  re 

g  D  o    o 

<8'8  « 

fM<^ 


E 
o  ^ 

0   9  0)-^ 
-      C    C    C 

_  o  o  o 

^   Q)   O   <S 
_.     O   (J   O 

eM<<< 


<  re 

b5 


^15  It 
.  •  y  -D  •  (5.  o 

®S  X  X  S  S2-E 
0.2521915  'S 
o  »  *  o  >.  >.ir  ^5 

S<<<  8  8^" 

<  Q.»-  «><<Z 


CM 


2  c 
o  o 

xl-ll 

^  :&  o  (0 

^5e£ 
a  o  »  c 
>  c  ^  re       „ 
—  re  "-^o-^ 

c  o  o  £  ^  ^ 

°  o  »  i-5-^-!5 

»  o  0)  <  rf  ,:.^ 
o  o  o_i  ^  •  o 
<<<ZcmQ< 


CMO 
CM  I/)  <0 
J£  JC  JC 

u  u  u 
CD  03  CO 

u  u  y 
<<< 


D-3 


Appendix  D 


^2 


co^ 


0)2 


coooooooooooooi^ooooocntoooo 
cvjooooooooooooeoooooo'^oiooo 
ppqppoppqpppp^ppppcvicvjpq^-;© 
•^co<di^odT-^e\ii>>^0)T-^cO«dc\ic\jpi'tirif^t^t^'«tooooro 

O  »- »- »- ••- CNJ  C\J  «M  CO  «  rt  rt  CO  CO  CO  CO  CM  CO  ■^  00 

cvj  toi^ 


oo  o  o 
in(£>t<  00 

0>  O)  oi  CVJ 

cocococvj     cot 


oooooooooooooooooo 
ooooinooooooooooooo 
Lopo)popppppooooi/)oooo 
cjiO'.-^^'^cjcooiuStNiocbcvi^-'cJcoioco 
•^■^co'-oi'-cooocvjinoii-om 

•^        ■<-CM't-»-        lO^JOt^ 


;g 


o  « 
E  E 


am 


s  s  » 


u  o  u  u  u 

<<<<< 


:s:s.'s 

u  u  u 

<<< 


S  S  S  S  » 


•*ooo 

T-..-C\J 

S  S  S 

T2:s:s 


0>  (D  (B  O 
'-CM  >,c 
CMPJTJ  O 

*  *  i  ™ 

ffi  ffl  ^  O 
>•>  >.§ 


8.8. 
88 

■6-"2  ._-D-o  - 
i-E  eo'o  !siS 
■§«£«««?>> 
2  £•>•.«  .9  |£ 
«  o  2  -S.-^.  g  • 

■E>?|-ooo| 
Scvj^  9  <P  E^ 
<  «  CO  «  s  a  a 
— ^"5  e'2'2'2"o 
.EE  IeEEE 
—  J5  ^  JS  J5  J5  J5  ■ 
9£>8  £>£<£•£> 
o  o      o  o  o  o 

<<    <<<< 


_    =  >> 

•^  ®    !  ~  «      

£  a.    ■  o  =6  O  y  «  en  K 

?8  -Slo®*^!? 
■  ij£x>  2  *  ®  °-?^a  :^c 

5-D<?^i>=5^Eg««^S« 
I  ■=  i  «  «  .« .^  «  ^  .c  Q.._  .2  c 

Q  '>>'>«'>»'>>'>>'>>  <J  <J  <J  <->  o  —  E 
o  o  o  o  o  o  o  oo  oo  0"D 

<<<<<<<<<<<<< 


E 


2 
«.fi 

■■0£ 

m  O. 

J5  o 
■£•4 

Wo  E 
*"  Q..<S 

■ill 

§=€ 

ECO  ?• 

E  o  a 

*  V"9 
:5"o"-o-g 

So  o'o 
(0  CO  <0 

.9  y  .9  .u 

0.0.0.0. 

<<<< 


»     '     '  lO  00  c>j  <o  1-  S     ■ 

5,t^  00'>-C\J<D«Oe0»-»-^»-»-  -o  ■ 

C   0>0>0>0>a>0>0)OQ>0)0)0)  Q)       t-  ^  ^ 

S§nra§nrai§n||  §  g'S^g  ■§■§■§■§"§■§  "g-g-g-g  "J -g-g-g-g-g -g-g  ■g-g-S"g-^-^-^  S-S-S-S-ii 

oOOOOOOOOOOOOo'^trircrircctrcEirDccrirtrirccocarccccccccccirirSSS  „-i-55!>i> 

s. "5:5:2:522 -5:2:253:5:5^3. "2  ."S 
oooooooouoooo  0^  000 

<<<<<<<<<<<<<<s<<< 


:::::::::!:::!!:::::::!  «^  :  :  :  :  : 

o)r«.»-<otM«oioflo«DO>i^^^oooo"'2£_:^'«^»f*-2 

ft^cor-oo»-coirt<Dooc\jtor^o)a>cotoooooO''-™°'  •  n>co»>»»-'-^ 
■mr^oooo-'-'-'-'--'>-cjCMrjc\jojcocococo'«i-'*^^  ^-o  ■5  «  m  m  « 


'2.2  222^222222222222222'022222S2 
ioooo'ooo'o'cj  o'oo'o'o'o'o'o'o'o'o  uoooooooo 


D-4 


Synthetic  Organic  Chemicals,  1990 


ll 


CNi 

o  o 

CVJ  o 

m  n 

S2  CO  CO 


o  Ln  o  o 

o  tT  o  lO 
o  o  o  ■«! 
r^  ^  ^'  CO 

<o  C\J  CM 
CM  CO  C\J 


oooooooooooooo 

O'-OOOIOOOOOOOOO 

ouioo'-copooooocpo 
<bcocoo)cocoodo)cvjc\icoiri(bcji 

CM         r^^CMCM«3^lOr-0)'-CMCM 
h-         TT  CM  CM  CM  CM  •-         CM  ■•- 00 


o  o 

O  U1 

o  o> 


oooooooooo 
oootDoocnooo 
ootoinoc)cj>ooo 
ibcJCMContDibr-iriirj 

CM  ■^         0>        CM  CM  CM  CO 
1-00  ^  •-  •-  CO 


o  o  o  o  o  o  o 
o  o  o  o  o  o  o 

O  l/l  •-  ^  »-  l/>  '- 

■«r  cji  CO  d  CM  lb  ai 

O  CM  (D  CO  «J  f^ 
CM  CM  TT  <0 


mm'^CM"*ir>      cMif)'<»'Vcoeo'^'V'«ti~-r--Ttt--to      CMiT)      f^inr-r-*N.r^r^r^mr^S^oocMmcMCM«o<o 


2  « 
«>. 

X  o 
O  J£ 

^  m 
n  - 
.  <o 


Q.  «  >•>. 

>  _:5 :2  a  J?  o  o  o 

:  —  j£  j£  jc  ^d£  ^  d£ 
<<<co<<< 


o  o 


•D   «  ^ 


a  o 
11 


-  ^  «  w  i  u 

o  o  2  o  .9  £ 

jc  £  ■£  ^  >. 
^  Q.  Q.3  Q- Q-_ 
■^  >.>.>.>.>.>> 

j£  jc  j£  j£  je  je 

<<<<<< 


^      o  o 

fc  '— —   n 


$  y 
SI- 5-5 


£  $  y  g 


c  a 


•  w  _  w  _  E 

ffl   0)    Q    O    ®  'o 

.  >.o  o  o  o  i 
<<<<<< 


c_  9 


«  o 

>i^ 
<5  « 
■go 

-S.y 

o  u 

tsS 

n.-5  • 
U  o  o 
c  c  a 
o  S  e 

^  i^  ® 
u  o  «  Q- 


c  <» 
I- 

Q.  X 
O   O 

Q.£ 
_    9 

_    X    C 

-=  -S  * 


oE 

CD  "O 
_    O 

Is 


D  S;  ® 

_    O   Q. 

g  Q.2 


o  o 


o  o  5  ■?  S 

R  £  o  '-  3  Q-  X 


-"l|o 

^£CM-^ 
a    |~CM 


.s> 


sod 


is  J 

^  eo 
8  _ 

S  E  w  <« 
£   r    ?>•£   0:5   0)   <B  w-D 
p  -i   >--iL   ?    3    3    m    m    N    M 


°  £  ^  5  J  ^  £  ^2  2  ™  5-<  ^<  ^^l'^<  S<  ^1-^  a  a  Q.  5. 
<<      <<      <  d<  ^<<<  <•*  ^co  <<<<<<< 


ll 


000 
000 

»-  CO  o 
»^  CO  5 
CO  »-  CO 

■•-  <o  ^ 


000  000000 

000  mooooo 

CSOOO  ■^  CO  ■V  ■•- CM  O 

r^  •^  CO  <b  ^  CO  CO  CO  i/i 

•*  r-~  CM  r~  rr  00  00  < 

^  m  CO 


o  o  o  o  o  o  »- o  o  m  o  o      ooooooooo 


00  CM 

C)  00  00  00  ^ 


o  o  o  >» 
^  t^  d  ^ 

(J)  T  f^  CM 


o  10  r^  1 1  >-  m 

a>  CM  l/>  CM  CM  o 


mr^<\joo^i/i'»coco 

"-         Ul  CM  0>  CM         Ift  00 


toe 


•-  -r-   lf)lti 


00 

■5  "S 


■=  w 

c  a. 
n  <o 

B  o 
O   tOTJ 

i-2  2  i 

-fie^S  55-2 

S-P    P*  ■£    3   •- 

oOO-og  -g" 
««,-«^»  I  •  * 
2  2  2  g"Q.™"Q.i 

=  =  =  0-D-g.T3  I 
SxSfc«)C§ 
E  1 1  -  "  2  "  . 
oooooSoo 

^  ^  ^  ^  .C  -^^  J3  ■ 

<<<<<     << 


"8^ 


E 


22  ° 
<< 


>■  >~  m  O 
J=  JI    ™    C 

«  ffl  -t  ra 
22  J-J£ 
<<<< 


2     X     Q.  P 

E  2  -S^i 


It 


2  3.  0)  y 

•g    O    U)    OL 

?  E  c5  Q.<B 

^■o   rc-5  ^ 

"■S.OccB" 
t  o^  y  w  S 


E  "O 

"   X 

E 


E  2 


i§ 


y-   ■  e^--Sjo 

*  t-o  =.  •  ?^2  IB 
o  c 


EC  •.£ 


ScM-§^§8^°<.X|.|||i.^Sc 


1-^1     _ 

;;nJc^p-p= 


<CO<<<<<CM 


2  2-^£.^?  g£ 
^—  iS  i5  ™  iS  ^  g* 

•    nj  ^  ^  _^  ^  j^  j^    to 

:z<<<<<< 


D-5 


Appendix  D 


1^ 


W2 


ll 


W2 


o 
o 

CO  o 

o  o 

ID  ■^ 

o  o  o  o  o 
o  o  o  o  o 

<£)  0>  O  O  O 

o  o 
o  in 
lO  ■<*■ 

o 

0>  CO 

00)0  j^CNI 
CO?)  CO  n 

C*J0O 

mm 

CO 

m  lo 

CO  in  I/)  m  m 

in  IT) 

o      o  o  o  o  o      o 

oomoooo 

o      O'^ooo      o      o      ooooO'-;ir)iniDooaoo 

00      n-<f  <o  ■^  ■^      00      <b      <boorv!o)ocococorriria>oo 

^        »-  O  O         T-        ■.-         »-        '-'-•-»- CO  CO  CO  CO  CO  ^  CD  f^ 


OOOCOOOOO 


OTJ-  -"l- 


CO        CO 


CO 


•  C0( 


IBS' 

Ie 

c  3 

H 

o-g 

CO  o 
o  <0 

o.y 


-I 

IT)  C7 

cm"  g 
o  o 


CO 


X    w    * 


o  i 
nj  t3 


.£  o 

<  « 

2 

"o_- 

w  c 


®  n  «  re 
<o  *  'S  « 

W:i    3   O 


2  c 


®£ 
o"  • 
oSgrs 

c  E 


o 

c  c  =  o 

re  re  t  re 

■£  >.  jS.  (J 

I    -"    -.te   t  ^   ® -C  "^  o 

o  ^  5  (J 

«  E.c-D 
o<  EiS 
l£i<8 


c  re 

P 

re  "T 
:5  CM 


Q       ■ 

c«oin 
6=  o  c 
£  ^  .£  N 
E.EE.2 
<  E<  i: 


E  E 
<< 


?   «   *   <B 

E  =  E  •s 
c  •  T  ™ 

^2 1  8 
o-^  re  re 

>-_£■  >.  >.  re  -5  3  -5  -5  g  .'S 

l§s|8g8  8cv.Ei 

o  g-D  oi-EEE  0<  c 


«   °   n,   t  - 

■i-^asE 

.   V  Q.COJ: 


■  -  y  a  N  o 


-  E  ^  -  >;  *  _  n 
'7o>.£c5oS 

?■  E  ®  3  n  O  2  00  9   (S  «   9  <B  -S 

E  >.c\j  J  o  «  9-  o^  ■=  =  ■=  re  re 
S  e  S'S  ^  HI  a  Q- Q- Q- Q-f  * . 
■D|.£re9£££££££S-o' 
£.SE°6EEEEEEEt^c 

C  O  ff^  c 


■OTJ 

I  o  c 
i-9:i 
!  m  3 


(A 

c  :9 

a>  o 
N  re 


's 


EE^  !.§'<<<  |S| 
E£i-^  6<<0i<-£2!.£l.£i<cM  m 

<C\jCi        ZCi.         CM  r^T^rlcgZ 


gCVICMCVlCp'^irxpCM^I 
0£.b'S^QOOOOOOOO 


<  c  c  c 


E  E  E  ^  S  E  E 1  E  E  E  E  E 1  E 

eg    ^    E  dj  CM  CM  CVI  CM  CM  CM  CO  CM  CM 


E  E 
<  re 


N  re  c 
re  Q-O 

<B   o   (S   9-  Z   >.:= 

-c  c -c  2  >-y  re 

.  a-^  CL.E  Q.=  CO 

o  E  o  E  o  iS  o 

E  clE^  E.c  E 

Q.  CLCO  ■^  e^<ir> 


O^  lOlO  O  CD 

t^  ^  ift  uS  «b  ui 
oocotniA'^  tn 
incMcocoh»  CO 


lAocccooor^oou) 
lft^^uSlf)t^colf)ob^^^b 
ifl'^irtin^'-in^inco 
co«ocoeor>»t^cor^CMr^ 


o  o  o 
oo  o 
t~«.'i><;co 


oo»-ooooO'-oinooo 
irir^t^cMcoirii^'TiricocjicbKoo 

COCMCMCMCMCOCOOO^l/ICMlOlftlft 


o  o  oo  oo  o 
<n  o  o  o  o  o  o 

<}>  <3  p  IT)  in  I/)  o 

r^  o)  oo  ^  o  *—  O) 
o  m  o  CO  t^  t><.  r>. 


m  in  m  m  m  in      m  m  in  m  m  in  m  m  m  co 


2  * 
re  TJ 

C    X 

2  o 
c»  B 

2^-S 

O   9   crt 

re  (ij^ 
E  E  E 

3    3    3 
C    C    C 

E  E  E 

3    3    3 


&2 
p  re 

Q.  re 
o  9 
.i2m 

^•6 
E  E 

3  3 
C    C 


bbt^ 

reSio 

rei5  >■ 
3 .2-^ 

O  90 
K    C       - 

o  re  T- 
coB92 

?-core  E 
E  E2  E 

3   3    3    3 
C    C  -Q   C 


8-^ 


9"S  2 

;5  X  re  9 
S  R2  re 

8&|^ 
.2 .2  E  6 
E  E  E  E 

3  3  3  3 
C    C    C    C 


£  To 


CM    CMinCM   CM  CO  CO  •^  n  CO  CO  O)  CO  CO  CD  CO  CO  CO 

--      ■^ -r- ■^     ■.- o  o  >- >- o  o  oo  oo  o  o  o 


LU  % 


iiiw!S.9 

«n  2  <o£ 
9£   9   O 

.£  o  c  = 

E=  E  " 
re  »«  o 

?if  ?^ 
•i  ^1  S> 

re  y  re  ^^ 

C3) 


en 


re 


^   w   »w   9    E 

9  o>je  0)= 
^  >.c  >»- 
^  ><  ;=  X 

E 


>.re 

X  *"^ 


E  E 

3    3 
C   C 


•  E 

k-  X  ;=  X  . 

5  o  a,  o  I 

*  g  re  E  re  o,Z 

S  -D  cfl  •«  <n  c  -5 

o  >.9  x:  9  >  ° 

=5  -c  :o  « :5  (0  = 


9  x  i  — 

„-;o  o  o  o  9 


re  = 

.  re 

o    . 

^% 
re  o 


2;  c 

re  re 

en  c 

■D  o 

re.S 
9  c 


S!9  i2;g"  •  c  ra 


re  9 
y  E 
o'f? 

3  ^ 
in  S 


*   m   O 
.  9   N 


^^:2  o 


<<< 


E  E 

_3  _3 
<< 


EExE 

^_3   O3 
<<         < 


E  E  E  E 

^  ^  ^  .3 
<<<< 


E  E 
<< 


5   C    O    c    O   C 

E  EE^  E- E 
<<<     <      < 


re  re 
en  en  fc_ 
999 
c  c  j: 

EEO 
<< 


■O  c  en  in^.E  S 

E  «  c  c  en  i^JS 
re  0  re  reg  "~ 
9  re  en  en  re£  2 

y  6.-0  -g  Ac  S 

f  *fE'E«f  <1 
V  co<  <co  »-< 


11 


E  E 
<< 


S   9 
9  *".  9 

"■■Oo 
■o  2  S 
g  re. 5 

re.o£ 
o  o  o 


goo 
■§=.£ 
.E  E  E 
E<< 
<  (icvi 


c.U 


:  c~ 
I  9  3 
:  ^  en 


-2£       O 
~  >>9^ 
£.E  o 
£  ®:5co_ 
oEii  6  o 
g  «  t  E  re 
§-9  123 

.0  CO   2-0-0 

o  oj:  o  o 
c  c  re  c  c 

E  E  See 

CM  in        CMCM 


CM   E 

o^  =  2S 


S22 
Hi 

SCMCM 


E  E  E 
<<< 


EE?5 


h~  »-  mcocD 


D-6 


Syntheiic  Organic  Chemicals,  1990 


*:2 


C02 


ooooooooooooooooooooooooooo 

00000000000000000000)0000000 

oooooooooocMooooooooooppoopo 
o^c\icr)Tr<DO>ocJc\Jc>Ji/So)<bc><rio)oboor--cric\JfOt^c\j'- 
a>o>o)0)050>o)00'-'T'-»-iocg  cvicoco      cocococoidt 

lo  m  m  1/5  If)  m  m  CD  CD  c\j  CO  c\i  CM      co  cm  c\j  c\i      »- cm  c\j  cm      •- 


C\JCMC\JCJCMCMCMCMCMnCMOC001CMt-»ir>C0C0C0t-»<DC0C0C2<0tD 
^T-^.^T-^T-.-t-O'-OOOT-O'-OOOOOOOOOO 


O  O  OCT)  O  O  O 

C3  CO  uS  r>^  ^'  ^  ^~' 
ID  CD  lO  »-  in  CM  o 
CO  CM  ^  n  •-  CO  00 


_    _  _iOOOOOO 

OOCMO'iPpppCOCO 

cj)LriuSr^r-».odN^cocriob^' 
CO  •<»  O)      o)  r-- o)  r- CO  CO 

COI-^CO        COCM'J-         •-'» 


lOCDlD(Df^<D«Din^«Dm 

•-oooooo--»-o»- 


n 


i  2  2  E  S  S^ 
>  o  o  o  o  £  «  o 

ieeeeSss 


«  ^1 


ooooooooo« 

.tr  .«  -tr  .tr  .tr  .tr  .n  .^r  .tr  c 
^^^^^^^^^^ 

(ntAcnbO(nv)(n(A(A^ 

222222999 
>%>>>%>.>>>>>.>.  >..9 
cccccccccc 

<<<<<<<<<< 


■2  0  0) 
><  c  c 
5  <o  (0 

*  OE 
a  ~  o 


o  o 

—  c 

"E 


f-t    ®    0)  ^  ^ 
§»   >vg   E 

^^■g  >.o 

•~  ft  in  -£  en 


<  eM< 


QL<  Q.<  6> 


C  O 

a  — 
.  .^  «  «  3 
■g  5  ™  -  " 

•  £  '5  c  .y 

—  o  o  •=  = 

•  >.«!  i 

O  O  Sk®  t: 
in  in  in  .c  ^ 


OS 


—-2  c  ^ 
T3  o  5  5 

5  c  <n 
9  «  3 

I  ^« 

CM   o   S 

Jo.E.y 
"o  g-  $ 


;a 


cJi 


C7)    r  en 


9°o'. 

O  c   " 

^  Si."  ■ 

0)c  « 
.  «  »  c 

g)*i 

5  >.  ™ 
s.-E  o 

c  c> 
<< 


a.  o  >.  u  >,  u 


<    W 

a 


c  5  o  is  -^  .2  o  o 
Q.ra222w®« 

(n.^333NNN 
<<<<<<<< 


i.i 
ss 

5< 


ooooooooooo 
ooooooooooo 
ooooo«-oocooo 
CMC0»^ifla>O)'-^cor--^»-'cM 

O  O  n  CM  CO        CMCMCViOCM 

CM  eg      1/1  in      w<D«-«or-- 


CMOOOOOOOOOOOOOOOOOOOOCgOOOOOOOOOOOOO 
CMOOOOOOOOOOQOOOmiOOCOOOQCOU>Ol/><SLn001DOOOO 

ooouio<oirtooo»-oooom<off>oui^O'-;Ococoppino<ppir>pp 
ir)co<£>«b^O)0)C>ico»-o^<ou)c6  i/)(/)coc6<dcoobcoo6cocoobcM»-^co5CMO>co 

^1/>CMC0^  *-»-        *-»-CDCOC)  O)l/5»-00        CO        COCO        ^CMCMC)^0)C0O 

CMUi^r^^  irtio  »-oo  ocM      CM      CMCM      r>.r».»-      uj^mio 


E  E  E 

■  oooS 
E  E  E  o 
E  E  E  E 
<<<< 


re  n  .^ 
^  -o  -n 


^i 


5  ra  <»  re  o  2 
o  9  re5S-g-2 

Q-  Q._    O   «    8    > 

c  o  g  re  £  c  o 


o  o 
E  E 
<< 


o  re 

q.'q.'q.  S.  S.  Q.  ■>.'>. 
EEEEEEEE 
<<<<<<<< 


^  o  o  9  o 

O    =    O   o  -D  ■J.f    «   S   « 

^if  ^1  :E  J  °  ■§:>.■§: 

"EEEE^E<<< 
0<<<<  2<  ^-L  ^ 


>..2 
X  :^ 
O  Jt 

^  .re 


■£  E 
Q-_  ".  o  «  «  ■£ 'P  i 

9®  «g  >-s«<bas 

S.i--§_2|":yl9  9 

E  J  E  >-^  ^-^^^^ 
<<<E-rEcccc 
.i  cs.  j:.  <  Q.<  <  <  <  < 


re  £  re  « 

re  g  -o  • 
:"o  o  O 


D-7 


Appendix  D 


§  o 

«:2 


V>^ 


0)oooooooooTroc\joo-<3-oooooO'-ooooo--oooooiDorrc2;2;^oO'-^oooo 
Soooooooooo^i--oooooooo-^ooooooooooqqqqq^'-pqoqqqqq 

c^'f«^c^cn^^^•«r•<r■*c^«•*c\Jcoc^c^onc^c^Jcocococ^coc^Jcocooc^c^cocoor)c^"cop^ 
oooooooooooooooooooooooooooooooooooooooooooooooo 


n  (0 


is  T3  ®  ®  ® 

M  .a  M  .a  .a 

vi  tn  ui  tn  w 

(0   (0   <0   (Q   (0 
CD  CO  CD  OD  ^D 


n 

Of"*'* 

CD  CO  CD 
U.U.U 

0)    V>    (/>    (A    </>    V) 


m  ®  ® 

5  =  = 
^coco 


o  O^' 

"5  «2 

.    .0. 

_  ^,   CO  «)      . 

oc>a  «  o^^^ 
•*  m  >.  >..r-  _  Z. 
'-'-■D-o  _  £  £ 
*  «  a  «  1  s  s 
3  =  53^  2  2 

coco  £  £       CD  £D 

u.a.u.u  s.y.u 

V)   <n   <A   M   Jg   (ft   in 

(0  <0  (P  W  m  <0  to 
coco  CDCDi±l(OC0 


(ft 
« 

c  c 

i  « 
o  2 

n  m 
asm 


=  < 
in'O. 


^«J« 


5.^"  •-  C\i  CM  C\J 

"D  c  ®  ®  ®  ®  m  ^CNJ  ^ 


u.u  s  y  y  y  y  y  «  y  y 

iniAjgMMinOTtnJginift 


CCCCCC 
o.o.o 
(ft  "(ft 'S 

CO  CD  CD 


to  O)  ^  rj 
•*  ■«»  mr^ 

■o  -D-D-D 
®   ®  O   9 

cccroccr 

o  .o.oo 
'(ft  '(ft  '(ft  (ft 
(0  CO  (TJ  (0 
CO  CO  CD  CD 


*  «'2 
tree  £ 

o  y  o 

(ft  (ft  (ft 

CD  CD  CD 


)< 

'■D-S-S  •  «  *  * 

"■>-*>>i>> 

y.y.y  o  ooo 

(8  (0  (8  «  «  s  S 

CD  CD  CD  iS  i!  iS  iS 
tt.'a.^itCD  CD  CD  CD 


oo 
o  o 

CNJPJ 
CM'«* 


ooooooooooooooooooooooooooooooooor-oooocjoooooq 
ir)'-^oa><bi<uih-^^cri«bf^c\juS'-^cr)uif--^<boi'-'cMirirod«btv:ob(7>Trir)iDdob<oco 
comi/>cO'ro)00'-»-'-i/5tocor-^t^r^i^r^r>.ooa5ooo>r^o>c\jc\icgnnoojP5«otoo)oo      i^nt^omm 

'T  C\i  (\J  CM  CJ  CM  CO  CO  CO  CO  CO  CVJ  CJ  CJ  CM  C\j  C\(  C\J  CM  pg  eg  C\J  CM  CM  CJ  CM  C\J  CNJ  CJ  CM  C\J  CJ  c\j        •-  m       «o  «o  «)  CM  r-.  CO 


^-•t-        ••-OOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO'-O'-'-^^'-^-'-'-O 


■£.■£ 

?.i 

E-c£  2 
(0  "S  «  >>   ' 

OcM£i,0^ 

.12  "STe  i2  -g 

•.-  cMCM  —  y 

'-"cm"  cm'      < 


«    w 

£  « 
=  o 

^  ^  (0  = 

CMVCDOC7)   ?   2   5*=*=*=*=*=^^^^^   «"*" 

fMi-:ZS:ruS<o^^iO(0(0(0(0(«(ft(«(n(ftift  — 

^  •?  •^  ■T  ■?  P      -eOCM OCMCOCMOOoS 

a  a  o  o  «  ^irt'-co^coirtooo)  —  ^^c^il--".  "• 
oooooo^^ccccccccccci2« 


c  c  c  c  c  c 


8. 8. 8. 8. 8. 8.*  »  »•  »o  * 

Q  Q  o  Q  Q  Q  8.8.S.S.S.8.S.S.8.S.S.S.S.9  q 

OOOOOOEEEEEEEEEEEEE|-g- 


-    Q.Q.C1.Q.Q.Q.000000000000000 


"-  CM<D   P  ^  „   J 


«2 


JI'SQ.Q.Q.Q.Q.CI.OOOOOOOOOOOOOOO'^'^OOB'SOC 

<o  ^  2  <?  o  Q  CD  Q  o  .2 .2 .5 .™ .?  .5 .5 .™ .™ .™  .2 .5 .5  S  <3  ^  ^  "8  "o  "o  "o  ^  <o 
ScDCDO05oOOOQQQQQQQQQQQClQ^-6Cra:QC2>>>-g 

y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  y  S 
0000000000000000000000000000000^ 


(0  — 

.1 1  1ft  2  E 

C3>._  JO   o  <fl  D 

^  (0  p  S  N  b 

^   C   ™   O  «  (0 

=  2  i  E  E  E 

=  ■&  5  3  3  3 


10 


10 


^       «  « 

■>.2£  «^ 

■■^  "-"^  (0 

^  ^  »2'§ 
cmJS  c  (ft  J2 

EEEE<° 
3  3  3  3.y 

c  '=:  'C  '^  (ft 

/   (0   (0   (0   (0   (O 
1  CD  CD  CD  00  CD 


D-8 


Synthetic  Organic  Chemicals,  1990 


^S 


toS 


<oe 


noooooooooooooooi 

OOOOOOOOOOOOOOOOi 

0)Of^ppo»-;pc\ipcO'J;c\JC)ppi_.  _.,____    .— 
'»u)t^ir)odobobuSob»-inuSco<dtf>ir)o>i^obo>o»— cvjr^oo 

■^  »«.  |v.  CNJ  f^        t^  •- r^  00  »- r- 00  00  »- CO        •- OeO  0» '-'-»- o 
SJC\J^C\J        CM        CVJCNJ  CVJCM        U)  I/)  CM  CM  ID 


O  O  O  ( 

o  o  o  < 


o  o 


o  in 
o  ri 
o  o 


(  O  O  O  O  I-  _    _ 

I  O  O  O  O  U)  o  o 

O  O  O  O  O  00  O  p  CM  pO 

oioidr-^cMCMcO't'-'  ••-'iri      <bo> 

•«•  O  •-'-■•-'-■•-'- CO  ie>y-        T- 

•*l 


•  in  lo  irt  irt  lo  ifl  irt  CM     ^  m 


o  o  o  o 

coin  in  ui 
in  ••-'-•■- 


CO  CO  CO  <o  CO  h- CO  m  CO  CO  m  m  CO  CO  in  <o  (*»  m  CM  CO  CO  1^  1^  m  CM     cm  cm  cm  cm  cm  cm  cm  cm  co      cmcm 

O  O  O  O  O  O  O  »- O  O  »- »- O  O  »- O  O  »- ^  O  O  O  O  T- »-        »-»-»-»-»-»-»-»- T-        »- •- 


,1 

<5«8 
iE 
a. 2 

£   CO 

«  S- 
-     ^iS  o 


Ei 

"c  >. 
o£ 
E« 

n  o 

£  >> 
c5-= 
ECi. 
=6.<2 

fc-g  o 


-2!s5t:o>.cfcH>»oR 


|^;S    -0:5  ^ 
I  u^-g"o|"5 

iipi|l 
iillilE 

•>.E  c  E  E  =  = 
«  18  =  c  «  I  o 

IS||fl|  ;^. 


c  c  c  c  c 
00  OD  CD  CD  ^D 


oinooooocoooinooo)cO'«<ooocMOOOOOOOOO 


g.i.i|EE-gl:Ho 

c  c  c  c  c  c  c  $^  E 
CD  CD  CD  CD  CD  OD  CD  (D  ^ 


E 
-I 

E.i 

is 


E| 

8"® 
T)  2 


CD'S  CM 

«■?§£ 


in  w  >* 

>.>.o 


P  >.-c   . 
£j  0)  9  «'E 

g  CD  iS  m  E 

CDCM        T^ 


CD 'S  e 
2  >«5 

(A    (A    V) 


C   C   C 
ODODtO 


<ooocMocMh-floooooooooooin»-ino>ini>»i>~'«»'0) 
o>  o>  ^  <D  «o  «o  «o  f^  t^  r~»  r>»  h- r«»  t^  h«.  h<.  r*.  CM  f>- •- CM  CM     ncMin 

CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO  CO   CM«n   CM<OCM   »- 


0000000000 
ooomoo'-ooo 
pmincMinptv-ppp 

^in<bo>''-''th»«bN^co 


oooooomooo 
oooooo»-CMcoin 
»-pT-pinpppc5p 

000*CO^CO^O>00>0 

<o  «D  r^  oh«  CO 

CMCMCMf^CM  •- 


S'^^^^  n'^'^'^^  ^  ^^  ■^'»  "?  ^^  ^  m  in<or-co«oco     cm  cm  cm  m  co  co  cm  co  co  cm     co  co  co  <o  p>  <d  m  in  m  in 
O  00  O  O  000000  O  00  O  0000  •- 00000       ^00»-00»-000        O  O  000  Ot-'<- «- »- 


CM  •   •  ,< 

cooomoooco^toooo  >.>><\j 


:s 


inin«or^r~-flbeno>o>»-"o"o 


i^co  *•'" 

u  u  u  u 

(A   (0   <A   V) 

(0  n)  cQ  (0 
CDCDIQCQ 


en  10  en 
CD  CDS] 


.u.u.u.u 

(0  (A  (A  </) 
(0  (0  (0  CO 
(Q  CO  CD  CD 


CA    CA    CA 

CDCQffl 


lllllll 

.U.U.U.U.U^  o 
(A  en  in  CA  CA  ffl  £ 
CO  CD  (Q  CO  CO  £Q  o 
CD  CD  ffi  CD  CD  -    -fP 


£9  •  p 
■n  Ti  P 


?««-E-5 


.£  .C.C  c-o  - 

N  «  e  o  —  a 

>-5  2:¥  E  c 

t!  <o  (0  CO  <o  « 

(0    N    N    N    N  IM  . 

c  c  c  c  c  c 

OD  CD  CD  CD  CD  ffl 


.^ 


«  3-D 
CO* 


10 


P5= 


CD  CD 


Q."-cn 
c  c  c 

N    N    N 

c  c  c 
CD  CD  CD 


■9 
"ScAfH 

X  E  •« 
-11^1' 

5«i.-.s 

•Je  >.  «  c  t 

£   C    S    «   CD 
=   3    C    O   ® 

O  CD  CD  o  o 


■p  >• 


<0Q    ® 

lis? 

oiTj^  re 

.il-.i8 

J  *— '  (S    (D   (D 

CD  CD  CD 


2l  ^ 

if  b-g 

CM  £  O   « 

.2  ;o;5T3:2;o 

6  re  re  re  ro  « 
c  o  y  o  o  0 
®  o'o'o'o'o 

CD    N    N    N    N    Nl 

'  c  c  c  c  c 
co^  <p  o  o  .  (D 
«— *  CD  CD  ffl  CD  OD 


D-9 


Appendix  D 


^2 


C02 


o  o  o  o 
o  o  •-  o 
CO »- »-  m 


oo 


ooooooooo      o  o  o  oo 

•"toooooooin      »-  o  o  oo 

inoocoovp'Tinin      o  in  p  pp 

ui  o>  c\i  in  1- eri  o  ■<*  o      od  •-  in  <d  o 

m  00  cvj  in  cj  m  c\j  o>  cvj      »-  ■^  t  ^  to 

'S- ■*  CD  ■t  coo      ■««•■•-  »-  ■•- 


como)      CO      ^  o  ■^ ''^  o      CM  m  og      cj      c\j      cocmcvjcm      cmcvjcm      cm  ^  cj  cj  cm  co  m  in  in      co      <o      in      m  g 


h 
1.1 


So 

id 
«0« 


§o 

S  A  >..Q  >• 

J,  M  CO  Q-^ 
"Si  •  w  • 
-'^'^.gcM 


II 


ii 
IP 

*■©  « 

«  o  c. 
JI  c  «- 

9-a 


«0     (O^ 


Q-S  2  Wo 
*■£  >>';^!5 

D)£  J=  o .« 

9  a^S  «  9 
1^2  CO  5  2 

>.>.-Aco  • 
•  ?  ?  m  £    - 

ffiffiZbOCD 


.,     •£ 

O  /«  «=  • 

*'E  iS.2. 

E  «  >;>; 

c  c  (g  n 
iE  $  * 
i-^  = 
«^iS  « 
>.  C-p  "O 

^  o  a  a 

'  •  >•  CO  IS 

■^£  c  c 

^  9   9   O         w 

o  .2  .2  m  o  2 
oaCDCD      (Q 


flj  (0  Q  ^ 

olll 


Ml? 

X    X    X   ?^ 

■5-D-o  * 
>.>.>>x 


2-5- 


2epcQep^  o 

aZZ_Z  M^  2  £2*2 
zzzffi  mom 


IIe 

W  X  3 
>•«)  o 

«■£  E 

i  <5  « 
«  8"i 

«g^ 
S>.2 

s-Sl" 

■o  o  ■!: 
>.<o  ® 
-=3E 

til 
«  ^« 

X   **   X 

o  S  o 

^,  CM  .^.  -2 


nil 


(fl-iS  ijr:  c£  co-r.x 
|?.|^^2  2tgc 

.2;2£^;2  «r  ■««'■«  i 

Z_Z_  2  Z  Z_(«)  rvi  CM  CO  ^^ 
Z  Z  CD  Z  Z  ^'cm'cm*  V 


9-^  o  £  * 
2  c^jc  «  X 
§.£>•  e| 
2 2  ?^ •    '^ 

CD  i  CM  ^W  £  J- 

m'      is      <D      Z 


ooooooo  o ^ o o o o o o o o o o o o o 

ooooooo  ot^  o  o  oo  o  o  o  o  o  o  o  O  Q 

ooc\jT-opo  inopppppinppinpppp 

(brNleoi^odedo)  coooo>oo>^o>o>o»-^^^"n^co 

••-»- o> »-»-•<- »-  in»- ^  o«o»-'»  ^  ioin»-CMO>o 

CMin      lo  ^ »- lo CO r* to <o «o «) «D P)     r«-eo 


ino^ 


o  o 

o  CM 
O   00 

cdcb 
inK 


o  o 
oo 
<o  o 


oooooooooo 
oooooooinoo 
kno>ooooooa)oa> 


CM  t^      >- r^  r^o  ^  o  in^ooi 

^  -•      »-ocooor^'^»-( 

O  CO  •<*  ■*  t>»  •^      ( 


^  »-      eM»-  »-  oi 


inco      mm      cm  m  mmcMCMCvjotm  m 


9S 

•c  p 
iJ-o 

0£< 

E  E  c 

2  3'E 
•S  'c  'c  a 
n  o  o  iS  s 

S  E  E  95 

££  •  2  Q 
£  o  o  a-D  £ 
r EEB^5 

^  C   C   K    _  ♦; 


?•§. 

■S  c2 

Q.^  (IS 

•D  *  >  o 
9  9  9  _c 
C   C   CO. 

OT  OT  (0*0 
(0   <0   (Of 

£  £  £  ^  ■« 

O  <D  <B  S  O 


c  • 
0  E 


i* 
E  9- 

«  a  ^ 
c-c  5- 
n  o  g 
■Co  .2 

•  g-TS 

9- .  o 


c  ft-fra.£  E  E  E  e|  Q>c 

"d  •  .a  .2 
SOD  com 


■a^-o>>cA 

:h2  }k  E>.c5 
gtE<i'  =  x 

«  Q.2  Esl" 
«M-85  7asM 

"'^Z^t^CDCM  « 
.Q-^..2  *  ^.<o  .2  ■*- 
cQzm     zcM'm 


8 

i> 

o> 
o 

c 

«£ 

;|^ 

cmT" 
>.• 

X  £ 
O  9 
•  =• 
O  >• 
«o£ 

9  « 

2S 

•9  =-c- 

v"2J.£ 

.2  .2  * 


o  (d 

N    C 


eCM 
8| 

Q.E 


■S.1" 
in  t 


-2 


o  13 
«_|2i.l|l|| 

.?CM   «   O   Oa.C    0)   >.~^j^ 

|:tE$.v|tl|t|f 


2SB 


■££.c  >. 


mm 


■9  to:p  505  =  c-^>.ii£ 


—  mcoTovv  ^j3-»  E 
O^^  (/)  w  "«',"«',"«'. 2  .2  .2  .2 

Q  v-T     cQ  CD  m  m  m  m  m  m  m 


D-10 


Synthetic  Organic  Chemicals,  1990 


^§ 


ViZ. 


■»J-00000U50000000'<J;tir)C)00  0 


o  o  ■<»•  o  o  o 
c\j  o  »-  o  <D  o 
c\i  q  p  U5  •^  q 


cjCNj  eoc\J      irt  •* 


•  r^  o  o  CO  •- CM  c\j 


oooooooooooooo 
oooocnuiooooouioo 
qqqqcjioioiqqqqoiqq 
CMobooirJuSoiotbocooitficr) 

t-^(T>U5C7)C\JCOOOO)OC\JCn''-'«l"^ 


nir)mir)i/)c\i»-io»-mmeomm 


«  «  §.=5  S 

o  o  o  o-c 
EE  E  E  o 

O  O  O  O  g 
CDOQCD  CD  O 


«     _ 
c  c.« 

•a-e 

ill 


«  O 

a  e 

ts 

I? 

«>  2    .CO 

c  S  «  5 
m  <-  cocD  t- 


u-^  «  « 

3  3  O  (0  n> 

.t?  t?   «   3   3 


C\J  c 

^« 

^"O 

,   c 

«  8 

9—9 
C    o   C 

2  =  2 

3  W   3 

CD  ^HD 


(0 

C    C    C 

9   ®   0) 

3  3  3 
fflCDCD 
T^CVlT^    CNI         C\J 


^O 

C*   O 

£  ®  — 
e-^  o 
_  ^o 

^  =  -^ 
r2-o  o) 

0)0  a 

**■?; 
«  S  c 
o  >.  S 

IB       >;  -C  t 

c  r  Q-o  o 
2  «  ®  c£ 
=  ^co  iS  • 

r;    C<V  *  g     •  3  t 

'"ca.oomSfMO 
■*■  o  3  3  ^  ■£  ;j' >> 
eo"3<iicD2i«£i.o> 
cvJoDr^cgcvj      eg 


E_ 


t  5 


§2 

o  I 


>.T5 
3  a 


x_ 
o  >. 

£3 

Si 

3   E 


0)  4> 

o  f5 


•5;  o  * 

X    3   <5 

lilies  2.. 

m  =  >.£  £  £  -!.£ 

',    >^3    X    X    X    5    X 

2i-9^  000  >-o 

CO   2-\333   03 
if.  Q-£iCD  CDCD^CD^ 

O         CNJ'AcNICVlCDrslCCCDmCDCM 


O    «   °   ®         -Q. 
m  n  n>  n  ^0  J, 


8.gS 
85>. 

t-a£ 
u  o  a 


a  — ^ 


9  9  Q- ™  JS  8  « 
>s  >»  03  nj  (0  >N^ 

3   3  ■>.5'5'5   A 
mm    3   3    3CD   5J 


0000000 
0000000 
U)  U)  lA  O)  O  O  O 


if  d 


(6r«>iA »-  »- 


CO  o>  in  u)  <o  (O  CO 


omoooooooooo 

000)0)00'-OOQOO 

ooO'-iocM^  q«r-.q 
_      »-'cNic\io6c\Jd»-^t>^»-'r-^'-^ 

(CM       CM^^OOOOQC>J»- '-«or^ 


o  or^  000  o 


t>.t^        ^  CO 


ooooooooooooooooor^»-o 

OOOOOOOOOOOOOOOIOO'-OO 
mOOCDO)0»-000)OOOU10>OU100l/) 
O>l>>^C\i(M'-'O>C0CO^d'-'cMuSl/JCMC0<riC)lO'^ 

«DO>^i/)CMO>mm'^ooo5500o>^or^ 

■w- T-        CM   »- CM  CM  CO  CM  CM  CM  CO  CO  CM  CM 'T   CM  O 


& 


I- 

iS.3 


^  o  * 


:  (0 


1§ 


l^5§ 
^■££8 

9  2  ?■* 

Ei^^ 


"PeII 


o  10 

H 

2"?  "ST 

<n  «>  iij  S 


:5 

JC 

u 

E 

I  2 
S  n 


E£  02 
E  •  ofc.  « 
<?  >:ts^-5  «2 


^SE« 


8-^ 


2S2«|? 


:S<   <0- 


■5.9 

_g"<M 
(0   C 

.£:  ra 
2  >. 
^.& 

CO    N 

CM  a 


5  o 

O   C 

£  o 


=  "0 

3   0 

9  O 
N  M 
C    C 


5  5 

E  ESS 
*~-.2 .2 .2 .52  .52  .2  .2 
ZODISCDCOCDCDffi 


E  C  £  C  o  — -^  £  o  0 

.2  .2 .2 .2  tM  .2  .c  5  g 
CD  CD  CD  CD  «— ~CD  CD  CD  QJ  ( 


*  5 

II 
(0  g 


?,  ™  s 

E  2  E 

gope 

mroCD 


o  o 
E  E 
o  o 
mm 

CLO 


^^  3 
■5.S-9-S  c£ 

o  «  c  ^^"?  E- 
E"s  ™  «  o  o  o" 

2-£  5co  5  55' 
op ^o  6 -c JC i= 
V  ro  E  E  o  o  o 
X"?  2  2  E  E  E 
£2."- CD  CD  9  o  o( 

~       T^  inCDCDCD  ( 


T-      O 


25 

o  njLU 


^?:2 

o  a-D 

^  «   3   2 

2^  "-o  re 

■—.<i  o  >.  5. 

c  c"°f  2 
re  re  ^  c  •■= 

X    X     .     p    p 

9  9 : 


EV-ll 


Appendix  D 


^S. 


«^ 


o  ooooooooooooooooooooooooot-~ooooooo  ooo 

O    O  O  O  O  O  O  O  O  O  O  O  O  in  00  O  CMCO  O  O  O  O  O  O  O  O  »- O  O  O  O  O  O  O  IT)  o  o 

po>o>qoqp      O)      oo>ir)pppqpc>ju^pc\jpc\jc\j(«)cocoi/)oppoq«>op'»in'*inpop  pinp 

00)0)0)00        -<-        CM   C\J  CM  <0  CM  0>  O  lA  O)  O  CO  CO  C\J  00  CO  CO  CO  00  00  00  00  00  00  00  CM  00  (C  0>  O)  Tf  ^  O '^  00  ^CMO 

O)                    «J>  O)                                        T-               0)CM        0)CMCM        CM  CM  CM  CM  CM  CM  CM  CO  CO  CO  CO  t^  P5  ■•-                     10 '- »- CO  COCO 


u)  CM  CM  CM  tn  m 


»-  oo  o  »-  • 


^O  Q. 


w 


^  c  >. 

«  =  •  « 
met  CM  c 

5  8-S-Q.JS  « 
-  S-s  ys  £•£• 

10   ^  c   c   (0  n)   (Q 

5  •_    y  £  £ 

E>.ff  EEE 
CD  c  wSmmm 


£< 
•  I 

ECQ 


.  £ 


-    I    ^  § 

^  -c      <B  2  « -y 'o  £  « 
2  5a)«f.t.S:2SB.£ 

SqSSIIP-S^I  :  :  :  :§  •? 

J5«S-§«'-o.i2.2Ecccs.ooOoos« 

^52  2-s  >.>.>.>.>.>,>»>.>>c  c  c  c  c 

^^^  -  ^xxxxx^xxxam;a};:a 


e2 


-^5 


fl 

g  o 


o»-0)pooo      o  •*  o  pp  in  o  ocM  lo  p  o  p  p  r- r^  00  oior^ 
cdr~»c6c)»-^ouir>^^'N^flbcdr>^<dcoco"co^>>-'o6 

T-CM<OKr<.        CM  •- CO  CM  O)  »- r*  t^  0>  0>  O)  0>  CM  IT) 
'"COCOOCO  CM»— 00'~COCO  CO 


t^  «0^  '-  ^  Ift  oo 

Sr^  CO  (o  (o  <o  'T- 
ts.  CMCMCM'- 


IZ)  O  O  O  O  O  O 

m  o  "It  o  o  o  o 

■.-  CVj  <J>  O  O  ^  00 

d  d  CO  CO  r^  •v'  ■^ 


OOOOOOOOOO 

oooh>-omoooo 

OOO^pOOCMppp 

cooidr^iri'^oddcMC) 


lA  CM  CM  lA  lA  in  CO   CO  lA  CO  CO  CO  «- 0>  ^  lA  h^  lA  CO  CO  CO  (^  f^  f^  t^  lA  ^    lA  lA  CM  lA  lA  lA  lA    CO  lA  lA  lA  lA  lA  0>  lA  lA  M 
»- ^  1- .r- »- .^  I-    .^^  000'-0'-»- O-- --OOO  OOO'- •>-    •.-'-•.-•.- I- •.- ,-    ,- f- ••-•.-,-•.- O  •--»- »- 


n 

O    <A 
C    O 


5 


«  S  'a 

—  JS  >« 


M.S 


JO   (0 


.^       _    .  o  o  ?  ? 
P_-_-m  i.E  n  ^ 


O   3 

3   O  ■^ 

<2   N 


E 
f5«o 


-s^«  i  eogS  g  gg»:g-5 


E:g 


>-^ 


I 


?E 


<B  X  O 

o>ro «  E €  g* 


Smm  c  <n  BcMCM 


«  m  -S^t:  -5  -9  H  -^5  ■i'?  ccccyccm  -^m  -§ 
£  c  m  5  m  <=  V  =1?  BgSSSSSSSr:  f"  co  « 

£  Q.a.cZZCD  CCD  (OCOCMcbcMCM  6  Q.2  CD  •-' 


mm;?.  =  t>., 

CO  CO.  3  op  jD  3   ' 
«-"»-"  CD  c  ^  CD 


£  S  go 

5  9  O  •     .        3 
s*r *f  -p*  ra  o  PT|^  ^^  IS  •—  .*2 

££333  3j5-5:,3 
—  —  eOOQCDOQ— ^—CD 


.^■§cccV§opo 

CD  CD  2  2  2  TtCD  c  <n 


D-12 


Synthetic  Organic  Chemicals,  1990 


k 


0)2 


ooooooooo 

(OOIAOOOOO 

q  p  p  <£>  p  '-••-;  in 
CO  (b  (b  <b  h-  o  CO  T-^ 


o  o  o  o 
o  o »-  o 
m  o<o  o 
CO  c\i  (d  ob 

CO  CO  C>  00 
U)  CM  U) 


o  o  o  o  o  o 

o  o  o  o  o  o 

O  O  O  O  O  Tf 

n  ■■-■  in  •^  CO  ■^ 


CM    CM    CM  CM  10  CM    CM    CM    CM  CM  <NJ    CM    CJ  CO    CM    CM 


*:2 

id 


^  a^y 
CM  o  $ 

u)  c  2  U 

• -•=  >.  4  ai  O 

£  >.£  ra  V)  ^ 
^  c^  c  c  c 

S  I.  (5  ■?  ■§  -§ 

^      cmOOO 


15 


E 

3 
t 

(A 

CM   « 

l| 
•  ■£ 
■c  « 

CM-O 

=-E 
>>.3 

«  5 

o  a 
■5S 
>'S 


^■1  :5 

>»(0      .   O 


E 

3 

^ 

CM 

> 

>< 

b 

a 

(\J 

•o 

J^ 

e 

>>  3 

£ 

■o 

5? 

bi 

o 

e 

•o 

S 

>.x 

f 

o 

CM"0 

>. 

^. 

E 

3 

«i 

C 

o 

^ 

8 


E 
18. 


Otj 


<3§-s-el 

^||o.iS<3.iS 


|°8 

o  o  • 

o     ?"|3e<»=w 

T<OCMO(D««I8 

5<  c  •  *5  S"?  P 
^  -B  t  5^  .  fo  «  "9 
5-1  1111'^ 


■S.2  (5  c.U.U.w.U    . 

g  <g o .2  >.■>.>.■>. ^ 

fttlllll|i|i|iii|gi 

«      uT     OOOO  ~ 


w  «5  E 
.£  %  2  ^  « 
E£  5  =  ;i 
.2  o  ^  «  J 

■?  ^  •  »  «n 
S    .3. "2  3 

(0    W    A    w    ra 

S  5  5  5 


^E 
E? 

I"! 
eE 

X  := 

P 


u    o    ooo 


1« 

«  8  « 
>.p  « 

£9e 

fl>  CO    3 

E-i^ 


+5  X  k 

9  «  « 
zo 


?E 

C    3 

.  c 
-^  •  o 
OS  E 
•"2  S  E 
E2| 
w^  >. 

—  ^s 

°  c  ® 
t;  E  c 


8 

•r2 

86- 

H 

«  6 

•>.ii 

>. 

•=>, 

.c 

(B-C 

o 

F  • 

fc 

■n  b 

>. 

X 

>.  X 

8 

0.0 
O  -O 

« 

hi3 

o 

O 

F 

.  CM 

3 

•  --^ 

■o 

•  >.o 

•  £ 

Ut 

>. 

? 

.  p 

«       . 

•  V 

>      • 

t- 

V- 

3 

^ 

^ 

8  : 

T> 

T3      • 

a 

o 

o    ■ 

>.    • 

SI      . 

^ 

F    • 

a 

3      . 

F 

c     • 

o    • 

^  : 

CM  in 


^  -e  ^ 
<oO  - 


^  -5 

« .2 
E.9 
X  O 

Jl 


OQ  O  OQ  o  o  < 

o  o  o  o  o  o  o  < 

O  O  O  t^  O  O  lO  < 


ior5000i/)iooooooooooovnu30ooooo  —  r-~ir)— ooLOi/ioo^ooom 


•^ift'*»-o>0'^»-»-r>'-t^coo»-»-oooocMCMooo)ococooo»-r^ocM'-mo>0)<D'-oioiDO)CT>o)ir>ui<oo 

o>t^  CO  loO)  o  o  o  to  1^  ID  (oto  •- o>  o>  «o  o  ojco  ^  u)  t^  o>  o  •- o>co  ^  vor^  CO  r- -•  — .-.-. 

coot^»-^in»-u>«o<or»iftifloo<oirtcoco<o<o«Dr«.»-cMr^i^ir>r^h<-t^»-'- 


iCMCMCO'-COCOtCMCM 


comu)tf)intnminmmiA(0(0(0(oiAir)(OiAiAi/)(Oir)^min<oi/)mu)m(ominu>r->(ocMCMinu)CM(0(o<o<o 

0»-»-'-»-'-»-»-»-»-»-0000»-«-0»-»-»-0«-'-»-«-0»-»-»-»-0»-'-000'-»-'-«-'-0000 


CM  ^  ■©  >. 


_     •  ■  .y  ~ 

>.£  n  -=  a  E 
£  <5  J5  5-2  « 


(orgmljrmoQODCOOOUOOOUO 


•  E  E 


a  • 
■>.2 
£  E 

«  o 

1-^ 

><  2  2 

a  .2  O  o)  a 

<o  re  eg  2  2 

:  — —  c  e  o 

5.:a:s  «  m  o.     - 

g  <J  <JBTj  £  =  ■§. 
:  2  2  S---2  Q-l" 

'    CL  a.  Q.  Q.  C^  CLQ.  !2 

)00000000 


u 

n  ^ 
OO 


D-13 


Appendix  D 


^§ 


co^ 


ooooooooo 
ooooooooo 
pcotocvir-oooo 

«)  0>  OICM 


o  o  o 
o  o  o 
o  o  r-- 


OOOOOOOOOtVJ 
OOOOOIOOOOO 

ooooooO'-rv.N. 


oooooooo 

OOOOOOOiO        ^j  ^^        %^ 
CO  IT)  O  O  O  O  O  O        »- O        »- 

picvJTrinr^oo)' 

T-  1-  •.-  ^  CM  CO  CM  ■ 


»-  O  O  O  CM  O        CM 


CMt-CMCMCM        IT)  t  O  O        Tf  ^  >*  "» 'I- •^  CO 


't  in  «o  00  ^  CO 
Tt  in  m  ■«}■  lo  ift 

CM  CM  •^  ■^  ^ 


CMM-m      in  CO  in  ir>  in  o  ir>  CO  in  m 


0=5 


•s  « 


■See- 

.r  O 


Q)  O  O  O 
0000 


u  <0^ 

^  ^"9.  o)-= 


>-6    -lo^SS 


Is 


"8 


cr  w  ® 
■=  •=   10 

£  e  o 

C   i,„ 

R  To  To 
.si  c  _c 

•  00 


000660  000  000000 


c  a 

c  c 

o"S  o 

(s  _j:5s 
*-  Q  f\  f-  q> 

™  JC  CO  O  </) 

o$£  o  « 
•   .  .  .«  S 

!S  in  (A  10  c  S 
U  c  c  c  ^.  E 

^   w   w   O   w   O   O 

£  73  <o  To  fl5  ffS  (ij 
B  .§  .£  %  .£  .£  0 


9   ^_^ 


a-£  o  >» 


18 


2  5"^  5 
e  « "s  2  c 

O  O  O  Q  o 

6||d-5 

cmOO-- 


E  c 
«)■= 

is 

ee 

2.2. 

.C  JC 

00 

CM   6 


«   (B 

C   C 
:=  a 


E  .£  £  N  N 


2S, 
2  o 

^  o 

Q.O 


.io. 

OT.E 

~^  N 

a  m 

II 
■v  o 

O     .OS 

E  9- 
>^  »,  ™  o 
—  ">.  a 

c  i:  2  <2 
®  o  ;o  '.O 

rsi  N  i   i 
c  c  (O  (O 

o  g  2  2 
0000 

.CCJZ.C 

0000 

CLinCMCM 


IS 

O   3 


<D   (0  ID  "C 
C  ~  .  ■  O 

S  9  9  a 
%22% 

t6o£ 


ffi  I/) 
5  8. 


8y 

11.  ^o  go  D 

"-"CM  «  S  "^  2 

•  CM  8  g  *  • 

c . ;    ni  <D  s:  ^ 

£  «  o  5"=  <= 
§££S 


^.2 


^*  (B  O  r  —  — 
•  c  .C  n  *  • 

•e  c-D.i  c.c 
■9  O  -J,  ?  ■?  ? 
.'-  o-  ■*  ■*"' 
T  — *^T*y*?" 
9=5  2  2  9  9 
o  0.2.0  00  J 

O  2  9  O  O  O  « 
•Ao  Vcvi'A  •* 


o  0000  0000000000  00000000000000000000000 

o  0000  ooooQo^cMoo  coooo>ooooooooinooo>ooo<-ooino 

CO  ooinro  iaooooo<o<ooo  i^i>»r^a)«oioO'»-CMm<otot^oo>oo>oooocMO 

■r^  ooeoco^  ^>-^eMcoo>c\ih^i>^ioo>  ^'^WoioiodododdVO'-'oio^eouio^ 

CM  eOCMO)   0>C01AIA<OOCMCMOCM   0>0>0>0>C0t0^'«-'»*'»^'*^00CM<MCUC0CMT-OC0'« 

CO  m  «oiocococom  co  ^O'^ 

(M  CM<or>-r>>  r^cMCMCMCMinmincMcsi  r^(^t^t>>(0(o<o<o<o(0(0(o<o^oosominao^(Dm(D 

^  <-SoO  0»-i-^»-^--i-'t-'.-   OOOOOOOOOOOOO'.-OO'-'-O'-O'-O 


CM      . 
-L  • 


w  g 


^E 
•  .2 
E.E 


CM  O 
-L  <n 

fl 

CM  O 

^E 


£t9 


E.e 


(3 .i  59.1 


«v1 


•S.2 

.S-E 

•.= 

2  in 


Wo 

T  >• 

•.= 

E:i 

9.i 


^ 


Si' 

•35  E 


II 


E  • 


111151131 

>.'o 


^■5  « 

5  9c 

*^    S  a  s 

■   "•  «  wo 

c    ooi. 


I)  10  «  3  ™  t:  in  g 


•&s| 


o  o  o  "5  "o  'o  'o  o 
iooooooo  § 


g-o 

eQ.O( 


VI     Wl     VI     VI     VI     VI     VI    ^^ 

,fCO(Ofon3(0(0(0(o 

>oooooooo 


9  _  c  u  ,.  ^ 

J?iJgo.9:i^^ 

>.uEMCxa!9 


I'O.^U^:.!^:.^.^^^ 


>66(S66ooo 


.0         9>     • 

2  -£  n  .2  15 

3  ai£  9*0 
.O.C  a.ac.Q 

OOOOOOw 

'S'S'S'a'S'SS-s 
a,  u  o  o  u  o  0'=  S 
_~(0(0(0(un)n3iD 

3'x<o«o<o<o<o«n«o«n<nJ» 
•R  000000.0.00  c  « 

.2^33:}333330.C 

«:.^  =  =  =  =  =  =  =  =  f:  O. 

006666660660 


D-14 


Synthetic  Organic  Chemicals,  1990 


u 


0)2 


oooooooooo  ooooo 

oor--ooooooo  ooooo 

opoO'>-c\jio<Doo  oqocvjo 

oiodcvJoioii^-^oicj  irjt^oooioi 

r-»ooww      CO  m  CO  »- ^  't  •^  irt  IT)  IT) 


••-ooooooooooooooooooooooooooooo 

1/100000000000000000000000000000 

ooomooooooooooooooooooococomo'*«ot^o 


1^  lA  lA  in  cvj  CNi  cvj      '-cow 


OOtO*— »-C0tD<D<DCD<0<0C5O<OCSJ(0«D 


fit 

(/)  u  « 
o|  c 


to 


■»)  <0  — 
O  >»i< 

■gf  w       


S-  O  Q.  Q.^  5  V  .2 
•SO^OOyjOO 

do  (OCNiOrg  (mO 


5     ?     !§ 


ao 

£9 
o  o 

I9 

o  6 


o  * 

c  * 

>  i> 

O  <B 


2    'r-tSU.   • 
Ny   «   O   • 

Seles 

£0000 

^■c  o-c  o 
oosof 

OnOcyO 


E 

e 

o 

3f 


«  — 


I 


-0  2 
n  o> 

c  =  i 

E  «  « 


8 
■5  *  • 


•  — c 
E*? 
.£  2 
00 

:£9 
o4 


^1 

2L« 


^  «  o 
2:5:5  o 


E 

99     .  .*.  '  a  a  >  ^ 

EE.£.£Sc  =  =o 
S  S  E  E  CL-B  CO  «  ij 

■Q.Q.  0.0.0.0.*^   ^ 

666666666000000000 


»-   (0 
)    C    M    X 

(0  a  o 
.1222 

!Z.    U)   </> 


on 
"2  5) 


^E 


P 


s. 

2: 

«  « 


00 


c  c  c  c 
o  ooo 


2S«|1 

T3    E   M    t   g   C 
^  ^  ^  ^  ^  .E 

000000 


2  Q-l 
«  2  * 
I  82 

E  c  c 


0000000 
o  o  ir>  o  o  o  o 
»-  o  c\j  o  OCVJ  o 


qo 

00  ^  r^  O^  O)  «U  U/  ^JW  V*/  k^  *—     V>l  W 

»-eoo      00  »- o)  o)  o  »- ^  »- »- 

»-cgco      ■»-■•-  •- ^  ^  u)  irt  CO  eo  10 


n  o  o  »-  o 
lA  o  o  ^  1- 
ON.  o 


odiAododcvji-^  CNJoi 


0000 
<\j  o  o  o 
o»-«>o 
dcocjco 
■^  cvjcgcvj 

lA  U)  lA 


^  r^  o  000 

<n  10  o  000 

a>  o  o  o  o  q 

00  CO 06  <6aid 


D-15 


Appendix  D 


^S 


«S 


ll 


co« 


o  o  o 

OOCM 

dcboi 


ooooooooo 
ooooooooo 
or-^opopppq 
obiri^'i/iadoirJouS 
<M  ^     .,-     r^ 


OOOOOOOOOOOO        OOOOOOO' 


omooooooioooo 
poippcNipppcvjpinp 


oo  inoooooo 
oo  oooocoo 

■^  lo  CO  JO  t-^  r^  '- 


<M        CM        CMCMCM        CMfMCMCJCVJCJCMCNJCM        OJCNiCMCMCMCMCM        CMCNJCVJlOCMCMOJtOCMCNKOCvJ        •.-lOlOincDlDlfiOJCXJ 


3  ni 


:2  e 
u    . 


« s2      - 


"e 


n 


6=6 

(0  « 
c  c 

OmS  2  OT52  =-c: 


—  —  j:.£^—  O P 


S£ 
E«, 

.2'o 

T3    O    (0 

2  *'  » 

5 -DO 

•  «o§ 
o  o  o 


II 


E  E  a  (o  o 
.3.3:5  a  M 

■§■§081 

«»  fn  r"   "''•5c 


■DT3 
22-D 


82^ 


^  =^  -C  -sic  CD 

,   3   3 01c=   >.   O 

«  «  Q  X  X  ®  « 

2_-_-.9-«  jdS  «- 

SOO  w  Q-Q-O  g. 

-?  6  E^  Q. 


(0 

^«)  :  :  :  =  « 
x5  :  :  :i:2 

O  2    .    .    .wE 

■P  £      .     .      .  «  3 

«S„  ■  -2=5 
i  32  •  so 
>._r  n    '    -  Q.<a 

«^o22  «»" « 
7£  8  «  «.-ss 
a  ?  =  *=  o  u 

^CM  c3>o  iS_J5  ™ 

0)  (D  ®  01  0)  o  o 


lAOcvit-^oooooroinoooo  oroooooooo  oinpcvjcvicocMmcNjtA 
iv:o6o6r>-'i-^iAa>d^°T^^i-'u>adnco  0)C>eoeoc\i»-"ioco«Ni  oiT-^uSoiinoioiedino) 
CM  e\j  t<»  CM  r>.  o  cj  CO  CO  n  CO  Tf  O) »- o>  to  00  CO  oi  !>>■  o  o  lo  r^  «o  o  ^      coco     cgoo 
CNj'.-     «»'-»-»-■•-■•-     ^     in  «o »- CO  in »- CO t>» rs. »- «o r^ CM     co^     coco 


<S<S(S   5<Sa<S<35<S<S 


OOIAOOOOOOOO 

o<o<oaomoooooo 
r«.cMCMCMr«-.oooooo 
o>o>o>o>CMO>^c\j<dcb^ 


CM   CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM 


9. -a 

1  9   ■  ^» 

C  CJ.       ^ 

C   C  Q.«-^   y 

.£  .£  .<2  .e  .c  .c 

OOOOOOOOOOOOOOt 


2  fS    '2 

^?||j  :  : 

§g«2  ^^ 

so  2  *  ? «  g 


•i-S^  o     -DOS: 
«o.?cQ,C2'"i5 

ieliillll 

-?-?3  55(3(3  <S<S<S55 


■icx:  c  c  «  J?  «        3 
n5.c5'g>£-5?2   S 


as?««8-82=s 

.J.i5cMEEccM2 


.^  p.-T  o  o  o  o  •  —  a. a-^  m  n  S ^  g 

•^s  E  ls.-i:2  I  8  >•  ££■§.■§.-§.«  o 

»2Eg8EEEg,QogOEEE.i5 
»9Po<'SrPo5  'T^  o  E  R  P  o  P  o 

59  8<S^8  8  8s>£?^o  »  8  8  ^  §  J^ 

JzocozocjCjzco    CO    O00(3(3 


CO    Crt    CA   CA    CO 

"9  .'5  "5  ."S  S 
'o'o'o'oo 
n)  (0  n]  n)  (0 

o'o'ooo 


D-16 


Synthetic  Organic  Chemicals,  1990 


^■Z. 


<o^ 


oooooooooooooooo 
loooooooooinoocoooo 
irtoqopoqpqc^jinqcNjqojq 

oococM»-^«-tDmiocor^oop5oocooo 
If)  c\4'-'-io  ■"tirtin 


o  o  oo  oo 
o  o  o  o  o  o 
o  00  oo  o  o 


oo  o  o  ID  o  o  o  o>  o  o  o  o  o  o  o  o  o       oo 

oo  oooooo  f-ot^ooiooinoo       ■^  a 

oo  lOT-CMoqq  oq^c\i'^fooc\joqq       "-r-. 

oin  oi'^'^uSi/ico  o6'-in'-uStv;ob'>*r^T-' 

«0>  CO  o>  O)  to  o>  c\j  »- ■v  oi  ^  o>  o>  U)  c\j  o>  »- 


in  tn 


lO 


lO      ■•-  ui 


00  1- 

o  o 

--US 


2  5  e  «5  o^ 

g-m  g-S  o>^  *  «  S  N  N  (0 

O*"<0  uuuuuuuuuu 
.       >>>.>.  >N  >s  >.  >^  >.>.>>  > 


coOOOOOOOOOOO 


*  c  E  E 
■?  «  p  «  0 

lllll 

5  £  5  =  = 

w  <0  CO  (o  c/) 
9  X  X  o  O 
c  *  *  c  c 

(0-g.C  (0  (0 
X  55  X  X 
®  o  o  ®  ® 

50U55 
■  00 


^ 


■D   • 

>>■£  _  V 

o  •  >.^ 
■o  *c>j  9      • 


,>,CNJ'*_  >»>. 
0-r--r-00 


-^ooooas-OaaXV 
ren]nR)R)»«v>S£,Ca> 

eXXXXXXT3^^^X 

000000     -«rc\j     O 


CO 

"2  >• 

Ie 


o  P 


«?5 
■Si 


N    ®    -. 

-  S^"5 


"Oocvf 
OZcS 


«  «2 

a  c  >> 

™  «  c 

—  r=  O  ffl 

^         I  Sal 
■5  2  2  -5  £  ^  « 

^  c5  t-o  .i  ®  -§. 
g  TO  re  <5  -  9. 2 
®  >»£  ■£  ^  z  -t^ 
«  E  E  E  >.x  o  c 

—  >,>,>,>,(l»^-D^ 
^XXXXJI-XBJC 

>.-c  j::  £  j:  73  "  X  O. 
05  o  o  o  S.^o  o 
•000  ooiiTj  o 
--000022  0^0 


^  •  2 
o 


oi-o  E 
Ee^ 

?<  I 

>>     ■>. 

o  o  ir 

>'2  >% 
O  Eo 
a      rg 


in  10      •-  •- 


0000      oooooooooooooooo      CO      O) 


^-^--  —  —  t^  m  ao  at  ai  CO  ■v 

f^  T^  m  t-»  r-  m  CO 


in     -r-      ■^ 


o      ■•-      •- 


?|:? 


•t:       ■=  O  t 


eg.U*5™^nie2o':   E 


8"  §>  S..U  .y  • 
Q.2  255™ 

■ '-  -'^    Irt    *0    TO 

c  c  c  c  c  >• 
E  E  E  E  E  E 

3   3   3   3   3    3 
000000 


•    *  —  „   c TO    »  3h—    >.  O 

5"5rTOOf:E  E^^of  g€ 

2  2oSf  toJ  >.|e8|^ 

E    E-5,OTOOO™OTO^OT 

3  3   ?^  C  ,>•  C   C   >,V   >s  «   C  CM 

O  O  I  TOO  TO  TOO  cjo  E  TO rg 

6  aoo-^ooi-^i    o 


giS 


9-2 
CO  a 

is 

o 


D-17 


Appendix  D 


O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  O  ••- O  O  O  O  O  O  O  O  O  O  O  O  CO  o  o  o  m 

o  o  o  o  ■«*■  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  n  o  o  o  o  o  o  o  o  o  o  o  o  ■^  o  o  o  o 

pcop'-oqp'«i;c\jc>oqo«)pc>inpoo'*popin  ppcoop»-i/)ppp»-;pc\jp  r-cjcoooom 

cooitviodiri^t^tbr^ooi'^sdi^tduSooJooiioodoicNi  r^'oo>oocooc\i»-^{\jrii/>o>o>'<»  to  to  to  ei  to  d  o 

w<;     ■•- T  ••- »- ^  CO  «Nj  •»)■  ift  t  m  to  ^  ^  CO  m  ^      ^■wt^mu)'-  »- <o  m  ■•- >- <o  w  co  o  o  us  m  m  c\j  to  (o  u>  <o  m  i/>  u) 

*:<     0)C5^u5      cD«o      '-co      m          coco                   ^coiocij  cm  cm  «o  »- cm  «>  to  cm  r^  c^  co  to  co  <o  cm  »- co  co 

(5:5     ift  IT)  CM  CO  in  CO  m  m  •<»■  CO  cj)  «D  in  m  ■<*■  to  o>  en  o)  m  •*  CO  CO  in  co  lo  co  co  m  co  co  m  to  to  co  t- ^  »-  co  co  co  m  tt  m  m 

"J*       »--.-i- Ot- Ot- T- 1- OO  O  ^ --•.- OOO  0»- i-O  Oi-  .-■.- O  ••-••- O  O  T- O  OO '-'- ■•-  o  o  O  T- •r- •r- ^r^ 


ll 

<0^ 


oo 


>  °-  ^  9-  S.'S 

111  II 

to  •=  'E  'E  c 
•  E  t  i  o 
c  2 .5 .2  E 
EQQQ  E 
.2  CO  ^  to  ,2 
©•-"■^"cm'Q 


e  n 

n  a. 
X  lo-n 

0  0.(0-0 

■■c:o:yS 
'|S|e 

X  >>■£  to"  E 
O  c  Q.«  3 
5*  2.£=6 

E  S^-E'B  •' 

9  •  9  £>•£ 
^'o  cM'i5  i5 


PCM  E 

-^cvi  >• 
Sftcsi  o 

o  0.2 

5  S  •«- 

to  OCM  ® 

asp 

99.2  2 

ob'^O  (0 


^.g 


"9'S 
o  o 

(0  (0 

E  E 

n  !o--°  * 


c  c 


™  ™  o  5.N  S  S 

s:s:ss>a  e  c  g 

>.  >K  >.  >,  j5  o  E  £ 
c  c  c  cO^O^Q 

|5||z9q5 
bobbz  E  (i^' 


CM 

6 
E^: 

jQ  .2 

i5« 


o 

E 

£| 

e  E 
•=  o 

■lis 

o  e 

«  c  g 
c  g  •  « 

C   N-S£  = 

«  £  X  to  c 
£  5  o^  (0 

E  >.  ><  o  .t: 

o  «  ■<«•  <5 1 


._  E 
■o  o 


*  CD  •« 


®  O 
to  O 


E^E 


?|S§9 

o9q  go 
■Ja^.in^to 
bCco'bcM' 


sic 

E:^   <0 

29  " 

:Q  CM:€ 


b  Q.b  b  b  cm' 


?9- 
a  o 
N  c 

S   10 

2  >< 

•«:£ 

£■«» 


._8  8 

E  10  to 


^•(0    .5££ 
f  ^.£  S  g  E 

S-iE-o-ig 

•>fi  tD.5  irbfi 
cm'ojQ  VcmQ 


000000)OOOVOOOOOOOOOOOOOOOOOOOOOOOOOOOOO 
Oti-OCMOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO 

oqpppppcoioot^opifiiooomocMoinO'-oocoooooooooooo 
»-^tbn'cMtD'-"(»CMcooicMr^'tbc)r-''-^CMr^tbtocMtbtdcMN!c>t»ir)t»cj^'ir)iTit>^ 
oio      otoo>r^o)^  CMcocoomoo)coc\ji^oo>cocoo>i-<j)CMO>'f-coir)ir)ooco»-'-co 
tO'-     to »-     CMto  •- CO  ift  eo  m  CM  •- r^     to     r^  r^     cm     r*     cm     to  to  r^  to  lo  lo  ^ 


ooooocooo 
oomoO'-oeo 

OCMO)in»-OCMC5 

CMo6r^c\iodu50)^' 
ooocM  to  inr^  ^ 
m  to  T-  »-  cy  •- CO 


CJ 


2    .._ 
^  c-c 

-l^co 

B    N   >, 

ac  Q. 
^22 


CM     2  O  aO  O  O  Q 


O 
m 


£    Q.« 


C  CQ.O 

2  6S 
1  SO. 

o   »-=  c 

592s 

(Q     M   (0   S 

^  g^9 

O  :=0  c 


X  X  o 

six 
SCO 


T3T> 
X    X 

II 

tn  to"  ™ 


D 
<o_ 

og 

ig 

i^9 


5  2  9-zi-^->. 
g  g  (IS  (0  (0  ^ 
000000( 


9  9Q.2 

C   to  (0   Q.fO 

Iff* 


J5 


ti 


g  to  to 
£  «  E 
-2  15  = 


^  to  to  2  c 

"  O  Q-ts  >,(0 

a  Tj  ^  Tj  T3  g  2:-^=  y  £ 

.2cCCC®?J-Q3.e<D 

c(0(a(0(0OQa.v)op 
OOOOQQOOOO 


82 


c  c  £ 
E  (0  (0 
(0  a.i: 

XXX 

QQO 


E  c 

o  2  « 

^2i 
00^0 

C    C    c      - 

EE^I* 
iS  i2p.o-£ 

<»   0)  o   CJ)0 

Jzx;  2  (0  = 

CJ.Ci.-§   o   (8 

F  g  m  ~    . 
«  «  E  jq  .5 

O   O  O  °T3 

i:  i:  i:  £,<!> 

X  X  X  S'c 

®  ©  ®  (w  ^ 

QQQQ 


«  O 

1  = 
O   (0 

•o  a 

:5i 
S« 

E  a. 

(0   (0 


«'0 

(0-5 

o  c 
«  1 

2  c 

-21 


S  £  <o  c  -1  a>  q1 
S  .=  to  E  >•  E  O 

b  o  b  b  2'b  b 


D-18 


Synthetic  Organic  Chemicals.  1990 


id 


to* 


oooooooooooooo 

00000000U100000 

oooooooooooooo 
oooc\i'^'^c\iocr)Tr<bco'^r^od 

OCD        l/)00O>C0O)O>G0G0O)O> 
COCM  CO  <0  CM  (O  <D  O  CO  «D  to 


O  O  O  O  o 
O  O  O  O  o 

o  o  o  o  o 
^'  to  r^  o  ^ 

O  GO  GO  O)  O) 


O  O  O  O 
O  O  o  o 
q  q  q  q 
cvi  uS  <b  t--^ 
O)  o>  o>  O) 


c\j  o  o  o 
in  «3  o  o 
q  q  in  q 

GO  GO  O  CO 
»-  ■•-  O  Ift 


(O  moooooooooo 

CO  CD  o  o  o  or^  o  o  o  o  o 

q  q  q  q  q  irt  q  q  CO  q  q  q 

GO  GO  GO  <D  CD  CO  00  CO  CO  00  tT  C3 

r-  <-  CO  CO  in  O  >-  to  CO  CO  •r-  CO 

•-  '-CMCM     r^'-cMcjr^      »- 


CO  m  in  CO  lo  m  CO  m  CO  CO  m  lo  CO  CO     cococococo     co     cococoeo     cocoeoco     co      co 

••-•.- T-'T-,- ^  0»- OO  »- •r- O  O         O'-'-'-'-         »-         y-y-'^-^         y- ■.- O  y-        t-         y- 


«  o 


;  CD^X  — 
>  o  a  a  « 

r'".  o  ""^ 

5  T^"  Q  CVj"  up 

5  6^  9  6 
r  fvj  .U  4  CO 


9  O  m 
c  c^ 
J5J5 


c5  »  * 
E  Q.2 

22-5 

.y.UCVi 


*  *1  gi 
E  a^ut  '>  c 

2  CD  «  »  9 
5  E  E  E^ 
■5222-5 
9li^9 

<o  U  .i>  .U  CD 

cm'O  O  O  c\i' 


i=2? 


iipj  en  T3  O) 
■S-DTJT3T3 

00  00  O 
CO  n}  n)  fo  CO 
o  ,0 .0 .0 .0 


6  6 
99 

•-"cm 


00000 

c  c  c  c  c 

m  cic^aa.a 
y  e  9  2  2  2 

™  o  o  y  o  y 
c  9  O  b  b  b 
u  •«»■  Tj-  4  'i-  •^ 

CMCMCvfcvfci 


re 


o.y 


SV,      <» 

^>>coT 
o  o  £"0 

*?  Q--'a 

O  OjC  ™ 
<2  (0£  o 

:5 :5:5  § 

re  (5  re  Q- 
o  u  u  " 

:  (/)'»«  v-  '^  Q. 
9  2r  ®  O  ®  "C 
)  re  o  o  o  >> 
3  (A  re  re  re  s 
c  *  X  X  X  £ 
>.S  O  O  O  • 

B  E  a  a  «  9- 

3.0  aQ.Q.o 
)  c  o  o  o-= 

O  Q  Q  Q  ■* 
cm"  CM  CM  CM 


i-creogoo^ 
-ccM  £  £-2  c.£  o 

oi2  2  5.>.^^ 
^S.22i29l 

Q  ><5  ^  2  —  —  2 


5  :e« 

c5  <».2  2 
o!Pt3  o 

oES-i. 


CM  cm"  CO  CO 


CM  Ebb"bb  J 

^  >'C0  CO  '^.co  r^  .y 
•^      ^"cm"cocm"co"Q 


°^^%. 
fc-  h-  re  >* 

O  O  X  « 

y  .y  y  y 
oooo 


0(010     o '^  CMOi- 0000  ocMO  oco  mm  m  ocMcnooiAO  cMtno  o 


CM  CO  in 

CM  CO  CO 
OCOGD 


•-OOCOCMOOOOOt^COCO'VCOCOCOO»-ON.r<.CDOmCOCM»-CUr^CM 

mG0l/)a>CMCMC0C0CMir>hx-C0IAIA0)tf)C0CD9  00CMCM<-OO00lA 

y-y-y-OiO        C0O)»-  CM        COCOOO*-        O'-^^CD'- 


000000000000000 
oomoooooooooomo 
ooc\iiooo»-ooooo--'-in 
f«^f^i^t^oc3inGOh^cb<j>cM^co^' 


T-OO'-O'-OOOOOO' 


CO 


u 


re  ">  ^ 
"  E  « 

-5   3  CO 

y^.g 

c  en  iM 

U  O   U  9-7;; 

re  re  re  c  g- 


5Q.-g  E  E  E  re-c-o.3 
~rerere—  "■■»"- 


re  9  c 
X  •S.E 
o  re  k- 


^■| 
re^ 

IS 


•  1 


cg-S-eco"  :  :» 


:2i 


0     ^ 

re  9  IS4 
y  c  ? 


I   «   O  g 


I>-19 


Appendix  D 


^5 


WS 


o  o  o  o  o  o 
o  o  o  o  o  o 
p  q  o  p  q  q 
t^  o>  00  oi  c\i  o 
CM  c\j  T-  ir>  c\j  o 
t^  r-  »-  «  o)  t^ 


oooooooooooooooooooooo 

OOOOOOOOOOOOOOOOOOOOCOO 
a  a  a  d  c^  m  a  p^  tn  Ci  m  c^  t~\  r^  f\  t~\  r^  tr\  ^vi  rr\  m  r^ 


•>*  O  O 

n  o  o 
q  tp  ■^ 

CO  O  N-        CM  CD  h*  in  CO  O  ■'^    ■»—  \-^  1*/  My  %w  i-»  WW  -N   ^_/  T—  uj  -w^  u*  1^  ^— 
CDCOIO        COCOCOCOIOOO        O'^OOOOiO'-'^CM^— CDCVICO 


iqqqqcoqcoqqoqqqqqqoincMoocoo 
icor-^inrooi-T-^nuSiricbr^-^oci^cai-'uS'^oir-^-^' 

PJCOCOCOIOOO        0-^OOOOlOT-»-C\l'-CDC\ir- 
i-»-»-CMt-'-»-         T-CO«DtD<D(O»-(O'D»-CDCMC0 


o  o  o 

C\i  CO  to 
CO  CO  CO 


ooooooooo 
ooooooooo 
qqqioqqcNjqq 

■^  d  r^  r-'  00  CM  ri-'  ro'  ■*" 

CMCOCDirjCMOlCMCOCO 


55  2>  o>  lo  in  irt  lo  »- If)  CM  CM  CM  CM  CM  in  CM  CM  »- CM  in  CM  •*      Tt  rt  Tt      CO  ■■- ■•- in  in  m  in  •>»•  T- 


§  «  E 

^•W-D  =  =  O 

«  «  CO  .2  "5  .£ 

»-    Co   O'o   O^ 

6  •  (0  E  «  w  E 

■5Q.y  5  y  y  « 


CO   CO 
•D"0 

u  u 

CO  CO 


CJ.£(»®«CCCCCcg^Wg- 

Tj-o  o  E  E  E  E  E  E 


CO    CO 

u  o 
'c'c 
o  o 

^  SI 

a.Q. 
in  CO 
O  O 

a.c3. 

O   (D 

c  c 
_2^ 


co;: 
c  "> 


CO   o 

2  o 


11 


2  Q. 

a.  CO 

u  o  Q- 
CO  co=> 
,o  o  >■ 

881 


zbbbbzd    n'zb    bbz'bbboobbabbbbbbbbb&S- 


c  c^  i: 

—  —  "CD   t^ 

9.9.0 


xxx-CS"-xx 
£  £  £  H  ^  X  £  £ 

>.  >^  >>  >»  ?■  2    >s  >. 


a>  ®  0)  CD 


CM  CM^CM  CM  Ct-JI  CM  CM^ 

aaoaaaaa 


o  o  o  o 
o  o  o  m 
o  o  m  o 


o o o o o o oo o o oo o o o o  o  oooooooooo 

o  o  o  o  o>  o  CO  o  o  m  o  o  o  o  o  o  o  oooooooooo 

p  pp  pr>>  oc>a>  q  ino>  op  p  p  p  p  p  o  CMin  o  ocm  oo  o  m 

t^CMfNi^r^rsIr^t^tocMoiNi^-^CMdin  in  cocoociodcbcor^Ni'-'- 

r~»  »- CM  »- m  m  m  ••- CO  CO  00  CO  m  m  00  m  Tt  m  «- o  co  m  m  in  (^  cm  cm 

Trr>»     r>«.  a*-^'^     ^-♦-■.-eoin  m  in  t^ co co co co co cm t^ t^ 


o  o  o 
o  o  o 
o  o  o 
d  inco 


»-  O  CO  CM 

i<odcM  n: 

mmcM  m 
cocoi^ 


o  o 
o  o 

(OO 


CM  CO  m  ^  m  m  in  in  CO  CO     Tt-mm     ininco 


11 
11 

CO    (0 

u  u 

CO  CO 

.u.y 

Q.S 

JC  ^ 

11 


8 

E 
o 

ii 

-■  m  E  ^^ 

CD   •   3   O 
."SfE^ 

«  o  S*2  « 
:S  £  n  ;5  E 

•  «»>.>.>. 
c^  c  c  c  c 

e£.?.5.?.2  •  ><»  S 

m    Q.T)  T3  -D  T3  IS  -C    <-    t 


.i|5 

?co  o£ 
9  ._  o 
tjS  co  = 

EC    Q.  3      .      . 
CO  -^  in  CO  CO 

<o  -c  -s  c  .>  .> 

CO   CO   E 


®  C 

II 

CO 
.  CO 

S  £ 


88 


in  oS  E 

^95EcO^XXCCCC:=P    »7   ■   XI m 

Q     Q     C.     (0     CO 

y  .«.«.£■.$■ 

OOOOQ 


•  -^-^5  SSZa-o  -^^-o  «  ™  CO  E 

-^■p  o  o  o  o  "o  ^  ^b  Q  "g  »  "S  ^ 


"-  y  5^  S^  5^  £"  ^'S  "5  ^  in  :2  2  2  2 


E  E 

JO_CO 

o  o 

c  c        _ 
(0  CO   (D   CO   ® 

■££"^  ££ 

aa    a 


u  « 
CO  c 


tfb 


£  O"© 
o2  X  o 

o-g  •.2 

EeIe 

i,£  ■?£(»£=- 

E    E    E   t:    m   m    E 

E  3  S  =  <o  10  b 


C^ 

2  CO 
■5Q 


Q-5 
7-5 


11- E 

O   O  'c 


O   O   0) 

>>>«N  «^£-o 

C   C    N   O    £  £    O 

®  •  c  c  2  *  « 

y  y  o  ®  o  c  « 
-  -  c  c  c  ^  2 
p  c  -^  —  •=  <o  o 

3 .2  3  E  "S.'i.-i5  J5  i5  ■=  E 
■£  jO  J^  JO  TO  ^£  ^  S-^.*  JS 

Q.c.c^^-=-=«  2  2'-<=TO 
in  .2  .2  .2  .2  S-S-b  "o  Q  Ci.'S  cO 

cM'bbbbcL^Q.    cvicMb 


<o-= 


=  1 

•.i 
So.-? 
JO  >.^ 

&«ocm" 

?  •'> 

E^.f 
>.T  E 

Li* 

o  E  o 

£  n£ 
E  >-E 
JS£  J2 
>-.2  >-S 

^  o  ■=  *- 

•S  »  § 

cmZco 


E|i 

to   r»   V 


0.  Q. 


~r  E.C 

Si's  « 
6    b 


D-20 


Synthetic  Organic  Chemicals,  1990 


^S 


<oS 


8  d 


ooo  OOON.OOOOOOOCVJ  oomooooooooooooooooooooooooo 

h«.oco  ooaxoooooooou)  CNiOcvimooooooooooooooor^oooooooo 

■"tcvjirt  coO'<a;cnpooc\jmirtpo  copcoooppqinpooocvjocjoootoiOf-ooovncMO 

lo'Vco  adcdin(dodo>oado6a>o><d  oaiiof^'^<6t'^t~^e^-r^(Daiic6\r>'^t^t~^eicimciominait^&>i6 

atmo)  (O      o)  (o  m  (o  c\j  u3  in  lA  lA  <o  ••- co  »- «o  t^  r^  t^  r^  i^  «o  m  m  to  oo  r^  co  o  <o  ct  oi  <d  co  to  C5  o  r-- to  oo 

»- c\j  --          --          to  1^      o      y-  r^  t^  t^  CM          to  CO  CM  CO      cor--          cm                  tt  h-      cm 


CM'^cMiocococoiniO'-ininioiocMincM^'-in'.-'^'t-T-mcoT-i/) 


ۥ 

c£.2 

c o  «  -o 

.2  «■  c  E  • 

"O  i:  TO  =   C 
«    K  -O  ?    N 

•£  o  .^  u)  ni 
®  «'>,cm"S 

S  c  a  X  Q. 
e.2  E  2  to 

|iie9 
■2.:?  "2.992 

r£  '—r^  in  CM  ~- 

O      Q  cm"  ^' 


CO  o 
-g  o  (0 

X  -s 


•=  c  — 


_       * 
3  «  iiS 


o  =  o  _  •  u  5"!^  5 


3   «  -^ 

c  E  «  c 


>•—  y-S'i-HccE^.cMf 
E  9  "  '^«rE  «  •  «  •^  -r  » 

2§-e-ee-se2>;|o^ 

9e8-c^e££^£  £■— 
>.  >.  >s9  9  >.9  9  *-9  ^  ■? 

:Gr£:^inCM£'^^  ;=-CM  CO  ^. 

O  Q  O  cm'^'O  cm'cm'O  cm'cm'Z 


"1 

e2         " 
5  I  «  ^  :g 

>>  >sf  to  .S 

££  S  "r  >  ® 
«  ••E'^xS 
n  J^  X  >•  >-  ®  '>' 


•o 

JZ   3 


«   Q. 


^■2 
JZ  >. 

u  ^ 

E  E 

(S    3    3 

5.S  - 


^5 


"  o  2  s  ■    ^2  : 

J-B  o  £    .  «  X    .  « 
9-E  E.S  ?  2«  2:S-i  >,:g-^:g-^-S  £^  E 


■D  -D  ^ 


(oOO 

i-zz 

ZZ-<iv>^  E 


.2  .2  .52  .i2  .i2  .i2  .i2    i  .52  t  .!2  .i2  .i2  .2  .2  .2  .!2  .i2  '^  .12  .2 

ooooooooooi5i5oooooo  Eoo 


o  o  o  o 

OOOO) 

CO  to  cit^ 


o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  in  o  o  o  o  o  o  o  o  to 

O  O  O  O  O  O  O  O  O  •- O  O  O  O  O  O  O  O  O  O  OCM  O  O  lO  00  o  o  o  oo> 

o  o  o<o  o  o  o  o  o  oo  o  o  o  in  »- o  o^  inoootomot^m  »-  co  ■*  en 

inO'^t-^r^cb^eo^'cM»-^oooi<»>  tbcMeoiriirin'cbooo^^cjio^  ob  obob 

m  CO  CO  m  CM  CM  ^  CO  CO  o><o  ■*  CO  CO  in  •«•  o  m  oo  to  cm  cvj  to  r<.  co  cm  ^  ^  ■«•  ^  to 

^o>o>      o      in »- »-      co»-r>.t^  f-CM^tococM  eo »-      t^r^  •-  »-'- 


o  o  o  o  o  o 

o  o  o  in  o  CO 

to  O  in  ^  •-;  CO 

CM  00  to  ^  ■^  iri 

m  to  CO  t  CO  O) 


•.-mm'-      commm  m.-tor^i^  CM  mcococo      co  cm  m  to  to  m  .-.-■.- mr^  r^  coco      co     coco 
.-.-.-.-      1- »-,-^..-»- oooo.-'i-oo      •.-»-»-oo.-'- •-'-.- ooo  o      "-      ••-••- 


0)0. 

P 
■Bts 

^  c 
a3 


.  c 

:e 


g  eg  (0 
^  o  o 

c-  C  C 


xN-h- 

o  -^  -^        -^ 

£.  a  a  E  <9 


o.E 

i5o 
«.£ 

*r  3 

'ill 


-J^x  _2CM 

^  .2  o  cm" 
i..iE«.E«.i".Jf 

££«§,«    C^CMCM<5CMC<oONa) 

9  <=  -D  i5  o  c  "S  cm"cm"- CM  S  in -o  (B  <o 

i.t.™   E    £   §  I   O   O^O^   0:e£0 
*-   Q.  ><  >.  «   R    >,-D  TJ   01  T3  i  T5  Q  ^T3 

«xxxXj:  >.>.c  >->.  >.  '  i=  >< 
^^e»89o-£-S  — -£  -c  ^  CO  a>  ^ 
^  ^  -9  ■<?  -o -o  iJ  bb.2Q«b2i.Eb 
•v-r'F^I'I'^cocofcoE-   ■-'^-- 


b  O  O  O  O  O  to'  cm'  cm' 


to  CM 

cm"  CM        ^ 


.    .  m—  o 

o  o^ g  g 

£  -Ob  ■o'o 
III  >- ,   >.  >. 

~-£CO:C£ 

Q--'QO 


D-21 


Appendix  D 


^5 


^;S 


5j  d 


o  oi  in  o 

t--^!^  Cvi  00 
(O  (O  t~-  (O 


ir>  m  ID  u) 


ooooooooinooooooooooo  ■<-  ooo 

O-r-OOOOOOOCMOO'^O-'-UIOOCDfOOO    O    OOO 

ooir>or^ooi~~-r^ooo'Trocooocor-^ir)  in  toooq 
(D<o«ootDr~r~c»)'^oO'-coi/)'«l"^ncNj<oo>  co  co»-c\j 

CO  CO  PJ  OJ  CO  C\J  CO  CM   00  00  »- CO      0>  "U- CO  00  CO 


E  w  e 


b    b 


^  ?s~ 

o  E  E  E 
>.?  >.>. 
£cvi,££ 

oz  o  o 
cIl  c  c 

E  ^E  E 

">.  S  ">.'>. 

-=  ab  «  » 

".icM.i  E 
bcvjbb 


(0 

|.i 

-S  "  « 

-oo  2e2  2-0 
E  w  2 ^, -^i. >,-E 


'■   (S 

.  c 

:e 

.  n 

•^ 

•  o 

•  c 

•   <B 

a 

;  >. 

X 

.  c 

.  ® 

1 

.  Q. 
■i. 

^ 

:t. 

E 

•  c 

•   0) 

•  IZ 

•  e!i 

■  a. 

•  c-c 

■  -'   <x> 

:  E  > 

s  :z.| 

J5.C 

^-=5:g_ 

.£.£  5- 
EE9    • 

o  o  «  E 


o  .0  o  og  E  o  o  o  0  «:9  2il"i?  S:^i-V  o  9 
E  fe^E  E-i.-5.E  E  E  E£££l>|£  gSfZ-S-^ 

>.!K>»>.'S;/S>^>^>.>^FFCSQP>.PP>^>^?: 


3-E 
b 


0-EE9G.E  EEEZZi.c;,92E22EE 


I  s  i  i  " 

^   ffi  0)  T3  nj 

E.i.if-S 
599«-g 
^zz  E  « 
?izzb 


00000 

00  o  o  o  o 


CM  ir>  loco  m 


>  c£ 
Q  (0  « 

C    C   W    C^c 

X  X  Q.  c  ;5 

Q>    O    V)    ®    C 

£.£-^^= 

>•  >>CJ.  >•  >> 
X  xi^o  Q. 

2  2  >'C^ 

0>   0) .—   *^ 


ft"il.| 

33  o  >,E 
^  J3  s:  j:  n 
cr::^  S  >• 
22?CM~ 

T)  -D  cm"  "9   E 

in  uSq  inT? 
cm'cJV  cm" cm 

—  —   >*—  —   m 

>N    >.^      >.   >.  iJ 

^  ^  -g^.^   (0 

■5  0)  c  «  «  E 

9959915 

in  ift  y.  in  «3  w 
cm"cm"0  CM"in" 


o> 


(A 

■<o±s  '.a 
o  v)  <Q  ''^ 
"O  —  «)  ~  ® 
•c-£  •_  «  c 
o  3  s  tn  n 

1^  o  ®  E 
'E"o  p'o's 
o  0  'o  o  o 
E  ^  (0  (0  (0 
p  y  y  u  y 
ioE  E'e'E 

>K  <T)  ns  (0  <Q 

Issss 

iS  o  o  o  o 

.y  .-e  .ts  .ti  .12 
II  III 

bbbbb 


ooinooooooooooooooo 
oooocMomoooo^omooooo) 

O'-O)«DO<DOOC0t^r^OCMOOOptf> 

ooTfob'^'ouiocTioir^t^^tMco'^Niincji 


mmm^  miocM'^   co  ^  m  in  in  to  to  m  cm  cm  cm  to  cm  co  co  m  m  r^ 


ooooomooo 
ooooincvjooin 
ooinmocMCMOt^ 
ocbujcvjdcocoob'"!)- 

COCOCOCMCOtflOlOOtf) 


cspin  p  p 
(b  cbcc><dr~ 
Tf-cnoxou) 
CO  r^  f^  CO  CO 


^    .2 

8.9  2 
2  E'o 


?«,2 

£  *  o 
CO  «si 

■p  w  .  c  4 
Q-E^^  S 
Sb«=t 


S  c 
(0  o 


:ME 


25 

O   3 


lllllllll 

22  S:S:S:S:S:S:i' 

ag-OOOOOO:^ 
S  .«  Q-  Q-  Q-  Q.  Q.  Q.Q 
Q  Q  _«   «   «   «  ,tf)   wl  Z 

oi    bbbbboz' 


o  »  <o  " 

nS  2 2  c 

S-eIII 


0.0 
2? 


n 


-Q—      wE 

.2  o  •  S  " 
£  2  reO  >- 

CO   >«Ct,   <0 
3   >   <S   ®   O 

■5-i  i  i  i 
bbbbb 


■5  « 

O    Q) 

.c£ 
•s  ® 


11 


n  c 
<->  P 

zb 


^  a>      Q  >> 

•  -2  oT-  «  5 
«  «  «  c  *llJ  c-c 

•  X  X  >.-9.-£  X  >.-p 

III! s ^5  Si 


, ^  S"^  :£  <5  ;S  Q-  ®  ®  ® 

:h  i  i  ?  *-c  i  2  o 
■Sbb^  Eab— o 
.einin9bE^^o 
O  cm"cm"  E  ib »-  CO 


o  2  E  Ho-ir  •  >■ 
f  »  8  0  S  72- 
5i£££l"-S£EEE 


I* 
—  iS 

8  9 
c  c 

■o-o 


Q.Q. 


3 


n 
■9-£ 

U  <B 
«>. 

.a-B 

O  (S 


t « 


<I}  CO   fO   (0 


c  °  E  E  E  c  >~E  >>>->> 

(5'V999(5  fl59c5  o5S 
c^j  Sz  ZW^EZEEE 

^    2"z'OcM"bz"bbb 


s.-S{^=5:z, 

c85f|^ 

o  *  c  E  o  IS 

^  E  c  ra  >.E  = 
a>  (0  nj  >,'i;  CO  c 
E  >■">.£  *  >> « 
.>■£  £  0)  E  £  ^ 
Q  0)  0)  F  Q  <B  j: 
|.i.Eii|-.E| 
o  Q  T3  -rf  n  E 

lb.        EcMCNib 


D-22 


Synthetic  Organic  Chemicals.  1990 


U 


WS 


8  d 


i-Trio«DOO'-oo) 


o  o       o  o  C\J 


O  lO 


in  o  csi 
»-^  cvjeb 


m  O)      (\j  CO  <o 


o  o  CM  into 
in  CM  CO  ir>  00 

C\J  CO  (O  CM(0 


CO  t-  i/>  coco 


pqpojpqoo'-oocjCNjooo 
ddd'^irJcncMoicvidTfTrr^oo 


Tt  •>»•«»  00  00 


CJCMOOUl'-O'- 

00  op  »^  7-'  r-'  oo'  ■»!•  iri 


--0* 


?  9^  >•_ 

^  OT5T7  Qs  ® 


.  o  «  8  ®  •  •  J-o 

S5co?«D<orv.>.S 
nj  — —  «  —  —  —  -£  — 

oS'S-fi'So'S-i'S 

£.i.i£.i.i.i£  i 

oOQoOOOvO 
E  rij«l.  E  fL  i-L  N.  E  •«»• 
Q  CO  CO  Q  co"  CO  co"0  •^' 


7        •    ™    (J 
CO    >>0:^ 

co£  t:  >> 

'     •   «   S 

N  V  g-S 

«   <0   0.(0 

o-Sc  2 
•  y  £  • 


^4  2&<n 

E  >.>.Eo 

.  «  ®  ■  O) 
O  E  E  Z  ■* 
d     QZ 


^5o 
■s  >>• 
£  S  « 

>,>.o:p 

£5-§.E 
«  »  _  « 

99CD   O 

CJZ  E  & 

6'z.'Ci 


c  " 

o  c 
a>  (Q 
2? 


:  «  •: 


•^E 

-c-o 
u  « 

<D.i  a5  2^ 

9  9  9  =  qo  -, 

2 .9  i:  •=  ^  c  9-  o  •  9  >. 

Tr   tij   A   ffl  CO  .^  ^  -^  IS   ?    ST 


*   « 

o.g 
o  E 
S  « 

~  iS-o 


"CO       =^ « 


«  "D  c      —  —      .">.  « 


1  sti:::tT"s  «  »:^^  g^^-^og  9  9->.|| 


n  >--o  if  >.  >.-t  g  ,„ 
c£:g*oo 

m  «  *  O  «  -Si-^  .:."  —  —  — 2-*=-*=22.£nC 

>»>>c  c  E"?  c  >'>'>'E  >.>»>.£  ><>>E  E^D  =?  " 
■££.E.E~-gE££^-£i:.c£-£^£~-^V^.c 

•  aQQ'TQQ'S'ScS'-P'SoflD'-p'S'S'r'T  -^  « 
EEiA^LZg-c^jEEEZEEEZEEZZ  £L,'=-^ 
b  b  co'-'z' 


®   0) 
O  Q. 

■3.9- 
£  >. 


.Jk^ 


^■?  e  c 

-"  «    M    C 

2  o  c  « 
.  re  o  J3 
oS-gS 

c  c  .t:  c 


N  b  b  b  z"b  b  b  z'b  b  z'z'z 


EZ.lin'.fP^ 
Q  Z  Q  co'  CNj'  E  CM 


000000000 
oooooo»-oo 
'-0  0  00  ooiirxo 

oor~^h-^coc\iiooo 


0000000000000000000000000 
oO'-ooooooooooomooinooinoinoo 
inq<oppppp'>-;W)'-;pp»-;r--ioin^poqoqej>ropp 
cor^i/)ioob«)«bob<b»-^ob<J>h^flOO)0)rN^cooo'^^^dioa) 

CMCOO>COCM»-COCMO>COOCMCOC\i'-'-COCOCOCOCOeO^COCO 
C\JC\J        •^tOflO^OCM        •*  O^COCOflO^^  ^  »-»-»- T- »- »- 


p      ^      po)      p     p 
<b      in     r~-'  d      o>     >-' 

CO        CO        CO  CO        CO        CO 


coo»o>o>o>c\jcMC\iin      coinr~c\j<>jcocMioirt»-mu>CMCMCoeocMC\jCMr>»r^t^r~r~.r^ 


»-  o  000  ' 


■000000 


.2  s  3  c  n 
3  o  «  5.9 
•ssa.-ss  «  a  eS^ 

o  o  u  o  u  c  c  ci^ 


>>. . 

j:  in 
^•50 


«  2 
2  "? 

?  2S" 
So  « 


■5  •=■ 


e  c 

«E 
>.« 

—  *'=~<5  as  0);=<5' 


jc  j=  ^  ^  j:: 

tr  t:  -c  e  t:  „  .„  _  .>-  .- 


>•  >>'g  >•  S  6  >~  >.  >•  >--r.  >«"0  -^  y-  y-S  >~  >--^t6  >»  >■  >--^-;i-:r.-:;.-=.-c.-^ 
-d-d  O.C  P  »--cr  I— _C-C  ^*-cr  ^»  ^*  0  0*",^.^  ^*    -.cr  _c  ^  ^*  **  >*  ^  ^*  ^  » 

^^^jdii  •  •_*Q^  ®  01  «  «-5  •_'5:z:z±  »  So-^  »  ?  JcoQDo'S'S'SflB 

>.>.>,>.>.££>.>.'    Q.6FEEcE>»c>->->-EEc>«EEEccccccc 

S»»SS99S»  £09999159  »QSo»99q»  99  90QQ0QDQ 
E  E  E  E  E  Z  Z  E  E  ^aZ.«>  Z  Z.,^  Z  E  .AEE.EZZ^EZZZ^:.^L^L^L^L^L^:. 


f5  ^ 
£8 


2  <« 

98 


b  b  b  b  b  z'z'b  b  co 


—..=  ^  .=  .=  .= —.—.w  .E  zzZf^  (.;,  (.1.  i-i,  t-i  (.1,  fC. 

Z  CM  Z  Z  m'Z  O  T-*0  OQZ  Z  cm'OZ  Z  Z  co' co' co' co' co' co' co' 


■5*2 
jc  E  ™ 


>>    ■>.■>.—  ■>.«■>, 2 

®  2   <5  CD    ^^  o  —  m  ? 


2ii2icE§. 
Socobf  Q  o 

ID  r:.  ^.  .i2  ^:.  QLrL  Q. 
CO  CO        CO        CO 


D-23 


Appendix  D 


U 


o5x 


1^ 

*:2 


«J* 


oooooooro 

OOOOOOO'- 

(NJodi^iriinoodoo 

CO  00  Oi  00  00 


f-  IT)  mm  in 


>o  oo  o  0( 


E 
o  o 


Is 


8. 


8i 


"•-1-2 


^t|lls|ti^l 


O  CO 


-c'-c'^.  ■  2  2  o 
■ffi  «  o  •  5  «  o 

iillllii 


i If ill! 


—  m    —    —    r w^  ^^-i*  Q.^  O    ii    O  ^  CM  O  (O 


Z  o.  a  Q.  a  Q.  V  rS  q.x) 

zbooboi5^'(5 


9-ooooeor-  r- •  >,b  t3  ^ 
bbbbb    bbbbobbb 


tor* rs.  ?L 

^  T-  V^  -n  ><)  lA  m  (O 
u  u'Ou  O  <B  o  o 

JSJS   (D  flJ^^^5 
OOCDja^CQCQCDCD 


0(0  00 

o  •  Q> 
CD  CD  CD 
O  tj  t) 


I  CD  CD  CD  CD 
t>  t>  t)  B 


1-  I-  ^  (M  £M  CM 
CD  CD  CD  CD  CD  CD 


ooobobbbooaoQDODOODoo 


—  com 

00  00  00 
CMCMtXJ 

CD  CD  00 

o  o  o 


ocoooooooooooooooooooooo 
ortooooooooooooocMinoooooo 
oooc\ioooocor^onoiocMcoo»-c\jooo»-o 


OOOOOOOCMOOOOOOOOOOOOOOOO 

oolftoooooooooO'-ooocvjominoTO 
moo»-oooooi-i/)c<jcoooh-ocMirtcocijcocoq 
(dcocor^'cviuirv^ifiiridococS'r^eocvicocoiri'^iflcococ) 
^i^rs.^^ai^^o>oooor^cMr>.iAinint^ir>cNjiAr^r^c\j 

CO  00       CMOO'-  tO'-OO  oo»-oo  o 


-o  « 


o5« 


"  1  •  c  g  E 
2  c  2  «  « 


U 


5.=  « 


l8«  s 
n)  u  o  0)  ® 
a  o-c  c  E 
c  c  Q.<o  "5, 

°°>-"  £ 
0)  a>  X  >,  <D 


u  u  o  X.C  _^u.« 


Q.-S-9 


8  99  8  E 


:  c  c  c  ^  c 
SOOOCO 
xo'^  inb  4 
jojcjcrf  Q-cg 


~ '-;'  ^•E  o  o  o  o  o  o  c 

jobbbbbboo: 


/-N  O  fli      -  C  i 


w  2  t'.  i  c  c  c  c  . 
P)  Q  r-  I    Ql^  Q-  Q-  9-  Q-CM  £iCJ  Q.Q.Q.Q.Q.Q.Q.Q.Q.Q. 

^'b  bbbcM'bbbb^'bcgbbbbbbbbbb 


b  2  5 


'"H  jc  j:  j:  x:  v  ^  —  c  ^^^jr^^^Jix: 


D-24 


Synthetic  Organic  Chemicals,  1990 


^§ 


WS 


cox 


oooooc\jror~-h«oo'»'OOOooooo^oooooooo«oooovocoO'-''j''-wr^o>ooooc\jcof^o>o 

OOOOOC0C0C0^^V/)OOOOOOOO'-OOOOOOOOOO^r^00OC0C00>C*)C0l0OO*— OJCMCVJOO 

qqqpp'-i-i-^T-'-oqqirtqqqqqqqqqoqqqr-p.'-^'.-ojcvjcvJCvjnnco 


i  Q  o  i5  i5  Q  o  o  o  i5 


b  z'b  b  b  o  o  o  (5  i5  i5  b  b  b  o  o  o  Q  Q  o  Q  o  o  o  o  o  o  o  o  o  o  o  o  o  o  a  o 


CMOOC\ic\ioooooooooo'700ooqqqqqqcvjc\ic\jc\ic*jc\jqqqq^q  qqqqqqqqqq 

f^t^O>OOO0000tDJ0JD<Or^f^r>-f^000000O>O>0)OOOOCJ(\iCSJC\4CMC\4CMC\IC0OC0C0C\JCVIC\iC\JC0OC5C055 


-     '  •-  C\J 

OTtT  coco 

[  ••'t  C\JC\J 

I -DC  c  c 

)   CD   »   *   * 

I  jscomffi 


>-2i 

c  c 
»  a 
o2 


*w «J 

gin<o-*o>cgoo2  5 
5,»-  c>jcocor^oo.-»--5 

c   0J0)0)0)0)0)0»05  njO*  *-  CNJ  CM  r^ 

500000  000  occtrccoici: 

t3  C  ^  C  C  C  TJ  T3  C  C  C  C  C  C  C 


coo 
r-co 

"CO 

<B  <S 

crcc 


.  r^  <oooo)  n  !J  , 


»!?:c\jcococnm  50> 


SS2?- 


crcc 
t5C 


Scvi  CMCgrgpg^x  v  v  ^  —  *  *  ? 
5  5  5  5 
O'a'a'a 


T3   « 
jTJ   O 

ictttcctrtr  25 


O   Oo 

55  5 


^00 

'-eg 
=  =. 


in  CO 
n  n  •-  o  o 

CO'*  U)  »-  "- 

$  $  $  $  i 

05  05.2 


bbbbbbbbbobbbboobbbobbbbbbbbbbbbbobbbbbbbbbbbbbb 


D-2S 


Appendix  D 


«:< 


COS 


0>S 


OinoOOOr^OCOCDOOOOOOOOOTCOOOOO'l-CDCOOlOOOOOOT-OOOOOOOOOOOOOOOO 

■^Trir)ooi-omc^'^;Doooooo<DooooT-CMO>'>-cocoovno^ooooooooooooooooo 
coeoploooopppppppppppooO'r-^'-i'f-T-cvjcvjCNipuipOinooooooT-'-^pppcooqp 
rirj  ■^'irtr^ooocnco^aj^uS«dooo>CNi'^<ooc)T-'»-^^»-^i-^cvjuJo>«ouSr>^o>0'^r5ortir)w 
30ooo-i-»-»-'-'-'-c\jcococococo'^'fnininininioioiomm'r<oooir)c\jm'^r-^»-to«>iftcoinco«>«o 
^  r~  t-«  r^  r^  t^  h.  h.  r^  h«  r>.  (O  <o  (o  <o  (o  <o  (o  (o  (O  (O  W  (D  (O  (O  (O  <o '<r  o> '^  CO  CM     O) »- m      moo     o>     oi      ooco 


n 

oinoo  M 

cococo  >>^ 

«  4  •  "g  o  ■ 
crcccc  S^: 

CO   jO   M   V)   JO 

Q.ciS.a.S. 

CO    CO    (O    CO    CO 

bi5bbb 


n 


h^  00  CO  CO  00  O  >.m 
•-  CM  CO  CO  •«»■  to  "D   J 

Q  Q  .2  .Q  Q  S  o  o 

CO    jO    CO 


CO   CO 


in  in  yi 
o  <D 

,cj.a_ 

CO   CO   CO 


CO   CO  CO 

bob 


00  ^  (O  00  O)  00  o> 
COnCNJ'^tr^tOCOO^CMCJl'-COCO 

c\jcO'*iocot^ooeo»-'-'-'-CN(C\icj 
^^^^^^^^^^^^^^^ 

JOMMMJACOCOjOCO^COCOCOCOCO 

,aS.Q.S.S.S.S.S.S.ciQ.o.aaa. 

COCOCOCOCOCACOCOCOCOCOCOCOCOCO 

bbbbbbbbbbbbbbb 


£  i  <5  o  a      « 
«  O  Q.cvj,liS  (3 

lic^of  o:^ 


P5 


.2 .2 .2 .2  ^..i  c\i 


~   CO   O  -O   S-=   «•   P    O.  J^  Q.  O   N 

.2l.a>:c.Q-6.5-5-5'5"&2  5 


.  ~Q||||S-o.c 

^  ^  i_  .^    -  -  .tr  .ts .«  ^  .«£  m  .^  .^  ,^  .^.2  irt  .> 

oooQzoc\rooO'«ocM'ooaaO'r-'o 


ooooooooo»-»-ooopoooooppppppp»-;pp»-;'-_p'-;ppcgcvic\jc\jcqtO{ococoeoeocq 
o)o>cl'-^c\i«r^ooobeoc6oc\i«bodo)Oco^cor^fldodo»-"c\iViri«ot^o»<j>oO'-^cjcocococo 


ooooooooooooc 

^  M  Mi  N  M  N  N  N  N  N  N  N  N  M  N  i  Ni  M  N  N  M  i  N ;  N 

CO  :  :  :  :ra  :  :  :„«  :::::::::::::::::::::  :-o  :;:::::::::::  : 

ift  o>  o  t-~  •.- 3  CO  cj>  •*  CO  ;S <e 

««»««««»»»•    •    • '^!Q<o'^ac2o>'^C~?>'2£?;?S?!:i'-«^««!{>S2SRSJ 

9  a  «  e  «  a  a  9  a  «  n  cof>-CijoomomtO'*<oa>'.-»-rt{OcoTfirtmcDKr~cDh-t>.r~0'-»-''-r>jcocOco 

0>0>0>0>C7>C7>C3>CnO>C7>  tj,,-  irt^,-CMCOlOmcOCDt^h>.00000)»-T-»-»-»-»-»-»-»-'-CNJCVICMCMCOCOCOCOCOCOCOCO 

S  §  §  §  §  II  §  «  §  ^-g-g-j-j-j-g-j-g-g-j-g-g-gig-g-g-g-g-j-g-g^-g-g-j-g-g-g^-g-g-g-S-g-g-g-j 
0000000000  oOcaioccocccccaitrccccircctEtrirocccDCfrccirccoctrccirccccDCcctroccrircca: 

2222222222222222222*''2^22*''^*'*2^2^2*'^*'^222*''2222.2.2.2.2.2.2 

bbbbbbbbbbbQbbabbbb(5bi5bb(5(5oQob(5bi5obbbi5bi5bbbbbbQO 


D-26 


Synthetic  Organic  Chemicals.  1990 


^5 


oooo  oooooooooooo 

OOOO  OtOOCVJOOOOOOOO 

oooo  0-«rOU300000000 

iitoiod  r~-'Tr<ouSd'^c\ico^'uitv;o6 

00  r^      eg  c\j      m  •- cm  cj  c\i  cm  cm  c\j  cvi  c\j 


ooo»-ooor>-eo»-oooooooooooooooooooo 
oooooooir)<oooooooooooooooooooooo 

OOOOOOOOOO'-OOOO'^OOOOOOOOOOOI^inOlO 


WX 


COCMCM'*   '^lACMIACMCMCMCMCMCMCMCM 


E       _ 

CO   «-D 


E    . 
—  ~ 


:s.i« 


E  «»i  e-w  c~  1-2 
^:S|«cMi«>'|.i«^^i 

£5|?gc2.2S.SEi-' 
-=  w  V  v>  ^i—wcMnJ-oZ.etcfliiwc 

—     *     "     *  -^_C  -Q-=4)94}0<DOOO'^| 
■2^Q.>>5;</)</)c»o)</)c»i/)(nco^ 

-  5- &  1 5>  &  e>  5- 6- e- 5- 6- 5- e-i 

oo'-r'oooooooooo' 

oO'Aooooooaooo 


-S  • 

I? 

I- 

^  u 
E  E 

c'c  • 
o  0:5 
EES 
EES 

(D   R)   U 

•ill 

c"  cT  5.  a  5. 

Q)   w   (0  O   0) 
"O  "O  X  X  X 

00000 
OOOOQ 


r:    '■.-    '    ' ^ "> 


m  <o  r-  c  c  o>  O)co  «or^^cMCMr)rocon  s  s 

^^;8  2  2  2  s-g-g'S^'S'g'S'S'S^II  „ 
•  a:£rocooooa:Qcoc£r(xcr(r£ra:(r>=>^5 
2  .u  .u  .y  .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9 .9  '^^ 

^EEEEEEEEEEEEEEEEEEEo 

^c[)(/)(q(/)(/)(/)c/)(0(/)c0V)</)(n(/>tf>c/)cA</}(Ap 

.^ooS888S88Soo88ooo88.2 

•=-D-D-Dt3-D"D-D-0^-D-OT3-0-OT3T3-0"OT3   5   • 

fccccccccccccccccccccgg 
.<5<<<njw«<oreren>BJ«>(Tjnj<o<oni(ocD-^<5 

i*0)0)0)D)0>0>0)00>00)0)0)CTOIOlO>0>0>0^ 

o22E22EEEE222EE2EEEE-o'c 
ooaoooooQoooooooaoooiuLiJ 


c  c 

■5-0 

o  o 
so 

jC  ^ 

9  9 
QlQ. 

UJliJ 


1^ 


iocMCMor^r~~N-ir)00oooir)<oooooo 


CO  in  CO  o>  in  I/)  in  CM  CO  I/)  lo     CMO>»-o>oor^ 


o»-ooo)oo'VCMint-~ooO'-cgcomf^om<DooO'.-.-o>»-ocM 


«0* 


"IS 

s  " 


3r«5 

Q.in 

"?? 
eg  a 


ill  II 


«  -  w  S  S  J5 
>  o  o 

•|.«.y=i»«  • 

I'illiiii 

K>.>>>.(a  (0  re  re 


^' 


».-    2e2|^ 

^  I  SJS  c JS  re  E  ™i5 
«>  i  r-  o  S  i-£  3  "  o 

X  t  ot  CO.^   ""ti  — 

c=    •e.reo^.«.ieEa.°i: 

-  "2:52 :2:5s. "2 12:25:2 
"Qyuouuuuuu 


.■2:2 


e1 


^  E 


"g 


O  0:5-0-2:2  • 
.9.9(2  «"'  y  >• 

c  c  ti  o  o  •«  5 
33  re  2.2  g_^ 

«   in  r-   0.0."^"^ 

■5^  ?.P  q 


.'S 


5.5 


o  2  U  0  W  U  o  o  o  o  o  "  <J 
j^wjQrererererererererere 

fnyyuuyyuuuuo  ..^.^gjg-g-vj  -  c-^ 
m  •2'  5  c  c  c  c  c  c  c  c  c  c  c  m  "S  "2  9  fe  Sc  Q.  m  m  »  • 
?reOooooooooooo-5®®ra  Q.9.;=-iS  c-Sc 

O»)533333333D33Xxxca06<?'P;—  >. 

.  ."cocoio««cn«cncn«o<nOQQ^"gg(3Q.a)y 
o   cccccccccccccc>->-  >-c  E  E  E  ?  2  -i^ 

0.|NggNgNNNNN2gN    -|||3COCOC7-    I    ^1 


i::-<Sc 


>"0'0'DT3"DT3T3T3T3' 


56  66  6  6  o't'"V'V'c9oo 
3QQQOQQcZZZ2cQQ 


I>-27 


Appendix  D 


u 


(0« 


S^ 


«o* 


o  ooo  q 

(O  <0  CO  (O  CO 


oo 

CJO 
COO) 

oo 


o  o  o  o 

00  o  o  o 

rv.  o  ^  q 

CO  O)  00  »- 

oo  mr- 


oooooooo 

lAOOOOOOO 

CNiqqqqqou) 
cdi/>N^odo>0'<-'-^ 
mcMCvjCNJCvjcocon 


00000»-000000000 

ooooooooooooooo 
qq'^inqqqqqrv.qqqqq 
iri<btf>uji0'«tinu)0)«bc»ic>»-^obirj 

CO  CO  CO  C^  C*  "^  "^  "^  ■"  '^  "^  "^  "^  **"  ''^ 
(0(0<0(0 


Ul  U^  U^  UJ  U7  "^T  U}  UJ  U)  kU  CJ   (^  T—  GU  ITJ 

cococococoifiuimT-cJ)ir)iD<pi^eo 

te\  tn  tr\  »e\         ^^  fr\  *^»  m*         qq  ^  (Jrj  ^  j«^ 


0)00^ 


o  o  o  o 
o  o  o  o 
o  o  o  o 

oico  -^  <D 

U)  CO  CO  CO 

00  CO  00 


CM  (\i  CV  CNi  CM        CMCJ        CM  CM        CM  CM        CM        CM        CM  CM  CM  Ca  CM  CM  CM  Csl 


IS  5  — 


.«  to 
S  • 
■o  « 

!28 


eQ5.22p||| 


-e-fi-e-e-e  •"^■o  .„_ 
8888S«-o=«  :«>£ 

29Se  e2r|o  o      o  §> 


•2e 
■o    . 


25 
5E 

o  9 

o  « 

o  o> 

^"S 

%S.    - 

2  S  % 

fe    rt    ? 


■o.U 
a  ^ 
IS  a 


.SE 

■8:5 


*S8=o82!S 


|S8|g 

i^5 «  EE o2 


:oooooooo 

) .«:  la  .t:  ■«:  ■«:  .t:  la.  la 

.-e-e€-e€-s-s-e 

}OOOOQQQO 

kWOTWMIAOTOTM 


2  •'3 

«5  2  * 
a  O  <o 

9  o  o  ^  ^ 

111 J^o 

•fi-s-s  *°S 


as 

8? 

SE 


it 

—  • 


c.E 


>>><>.>.>>>i.>,>.>.Q  >>>>n  ><  >''S 

|||||il||8||-5||l 

UJUJUJUJUJ^       UJUJ       UJUJ       UJUJ 


m    LU 


|-§.|||  :o8f 

QSQ^^a      ^°-"EEc«-?rc 

■g^^-g-g-g^-S  :'S"g?gSoi-2||||?|Ef 

UJ  UJ  UJ  UJ  UJ  UJ  Gj  UJ       UJ  UJ  UJ  CM  UJ  UJ  LU  UJ  UJ  UJ  UJ  111  LLI  CM  CM 


=  1 
(«  Q. 

~  a  a 
•If 


ZCMCO 


OOOOOOOOOOOOOQOOOOOOO 

ooooooQoooinoooooooooo 
qo'«a>oooqqiACMOiAr»qtnqqqqq 
ir)oi/iir)(b(6ujp)<boa>(b(d«bco^o>u)(oc»ed 
CMcor^h-r^         »-c»)CMco^^  ^lor^r^r^f^coio 

m  OOCM^CM  CM  <D  lO  ID  <0  r>  lA 


OOOOOOOOOOOOOO 


coeocoeoeofloiococMOJO^coo 
«>^r^r<.r^(oF>t^r^^CMcoi>-u) 

lA       0000fl0^K09»-^'»  »- 


ooooooo 
ooooooo 
PPPtPPP 
»-^  tfi  CO  00  ■*'  CO  r«^ 
«o  o  m »- CM  T- 1- 

•- T- C»  CO  CD  to  CO 


lAi-^^  •-0000<OIACMin(O(O(OCM(O<OCO(O(OCM   CM   CM  ^  CO  CO  CO  <0  CM  CO  (O  (O  (O  r^  U)  lA   in   lA  lA  in  CM  CM  CM  CM 
■.-••-••-i-»-000i-i-»-000t-00000»-   t-   •-»-0000'«-00000  — »-   ■>-       »-»-•.- ^ »- ^  ^ 


fill 
ttit 


•      o 


ffl  ■=  -"^  TJ    W  Q 

S o^^    ■  •£  c 
o"5  o^«  s'gE 

S2il2.-S§t 
sSJS.8  w«-5 

m  *  *  4  *  «  S ._  „ 
UJUJUJ  TI'MIMIMIMII 


E  «  « 


i^i.g  c 


tf 

LU  ^ 


«  2o 
tS2^ 

9  9  9»= 
ooo  2 

E  E  E-5 
29  9m 


=  E 


CoE-«;5  « 
Q.CB  0  *  S  c 

O  co"  «  co".U  E 
7;  c  C  C  C  (0 

2  8'8'i'si 


o  o  o 


ii)««<»i»ssSii 


B^B 


..S>5-^x  I.-? 
a  o  5  m  n-^  m 

(Q  *-  *«  *«  O  w 


?>?«?«l «     -.,.-- 

LU  UJ  liJ  LU  LU  111  LU  LU  UJ  LU  111      LU       IU^C>JU)UJUJ 


0  S« X 

■2:9  O  ° 

w^.  2  ® 
ST  o  X    .£ 

^000  i£.£K.«  ■ 


,      8 

:  o  — 


^  «  « 

as  .  m  9 
S  Co  o 
"  •  c  c 

Et;oo 

3  «  E  E 


Z  >•    "o  o  Q  g 

■*».«  «  2  2  2 


UJUJUJUJZCDCMCM 


g£  ~  o  c  c  c 
2  '3  >.  (o  n  (0  (s 
o  >.-£-p'o-o-5 
E  X  flj  0  *  o  4 
^  _^  w*JS  J5  J5  ^ 

8(2  o  5" 5" 5*5* 
^pj,~  0000 


_^   X   X   X   X 

oiCtiD  C  "  r  r 

CM  CM  UJ  LU  LU  LU 


D-28 


Synthetic  Organic  Chemicals.  1990 


U 


«o:a 


to* 


o  o  o 
o  o  o 
o  o  o 

mtn  in 


2 S2 2 S 9 °2 o o o o oo oo o o o o o o o o  ooo 

ooo  oooinooooococMooo  ooooo  o  o  ooo 

qoqqqq-*qqqqN.r-«r)oooiooooN.oo  ^"" 

q^-c^JP5■^»-co<bNioboo»-^^-^t--^o>o••-^^-^c^io>c>■r^  t^pS  ■r-^^iri 

(o«)<D<o(Doo<ooooc«)cotf>ooco-*-*^VrS^j;5  f:;$2  55S{ 

O  ■•-■r-'r-«)r-^^<O«>«OC\JC0C\J  CO  -l-S 


oooo  ooo  ooo 
oooo  ooo  ooo 
qqqq  qoo  ooo 
o  iri  <—  o  o>  rvj  (b  ai  <si-^ 
(DTj-<Dt-»  ooooTt  ^rrm 
^'-^      f^o»-m«Doo 


J     ???     ^     ^  ^  ^  3  2  u)  j;  in  lo  in  c\j  IT)  w  m  c\j  cNj  c\j  ifl  lo  ■*  o  00  i>»  to     minK     cm  r- c\i  n  m  in  t^  in  in  in 


(0 

en 

«.? 
in  N 

E  E 
<a  10 
o  o 


_i^E 
«  CO  2 

(0  V)  ^ 
C  <9  O 
^   CO   c 

10  c  E 
Q)  (0  <o 

c  o>o 
race 

(D  CO  o 

E  EE 


.9 .9 .9 


5  5"^ 
«  «  ■-  ■-  ^ 
c  c       c  c  c 

w  w  CO  O  O  w 
c  c^  c  c  c 

">.'>>JI  >.">.■>. 
££^£££, 

LLIUJ       LULLIUJ 


C  •   (0  « 

0  •  c  "^ 
-  "   3   E   " 

1  lip 

in  ■  E  Q  0.2 

O  CO    Q.  CO  "Q 

c  CO  CO  CO  o 

O  .  ^  ^  ^    10 

E  ■  5  5  5  'S 

o  ■  o'D'o'o 

CO  *  CO  CO  CO  CO 

9  :.9.9.9.9 


.  <X>  <D  0  O 

■  s^'ss 


(0  JS 


O  9^ 


•  !5 


«    8  S 

E  Q-rf  >• 

fill  S«8S8888888  S^."^  ||^  o 

C      -CCCC®®®®®®®®®®®®®®®®®  CO-  r-  x:   OJ  o 

9*    •a)««»^'^cccccccccccccccrt's;-s;c' 

rl      t±i.^V=.^LU  LULUUJLUUJUJLIJLUUJlULUUJUJIiJUJUJUJUJUJ       lij 


S.  b  5  -= -r  9-  •  S  <» 
6 .2  E  E  .2  .T  .i  .i  o  o  g  S 

CO'D-DTJ-D'O-D-O   E   E   (0-S 


» 

« 

CO 

« 

E 

E 
m 

>> 

c 

v  * 

T3£ 


(0     Q 

*  t 

-c  2 

*m   E 
3-i  CO 


O 

£   <B 

JSTo 
3.9 
<o  j: 

1-1 : 


.2  V  -D 

C    •    CO 

It  I 
E±  ^  o 

S  X  .c  CO  o 

2   CD   (0  C£ 

S-C  X  CO    • 

is    '    «  X  CO 

">s.^-  ■£■£ 


If 

>.= 

£  CO 

aJ  co" 

5.  CO 
CO 

u  u 

CO  CO -5 

•  .9.9  c 

to  o'o  2 

o  c  c  5 

C    CO  CO  • 

X  w  a> 
_  *  £  £_L 


uJtI      uJZiO  cvjcvjlli  cvicgrg 


oooo 
qoo>  o 

i~>^cjini< 


ooo  oo 

lOOC^  o  o 

00  qq  q  q 

00  ^T-  COO) 

^ »-     cuo> 


csirv-oo  mm 


mooo  oooomomoooooo 
cvjooo  oooo»-c\jmoo'-ooo 
q<oqT-  »-^^T--i-cocqqmqoooo> 
oioicbo  in 00 (o o> (b <b (o cNJ c> CO cvi o o) 
comco^  O)t^o>«oo>o><oow^otcn 

0>        ^   CO        00        CM  C\J  ^  CNi  ^  CNJ  C\i        CM 


o  ooooomo 

o  o  ocoo  omo 

in  qocjooTTO 

IT  C)  ^'  CO  d  CO  00  CM 

CO  ^'^COOOCSCNJCO 

»-  CMCM        CVimCO'- 


mmcomcocM^ 


oo 
ai  d 
^  m 


QUJ 


I 
11 


£5? 
•  8. 

_£  >.co 
—  >»•£*= 
.c£uj  (0 


E 

O 
—  • 


S5 


9 


Slo«?>. 

Op  B  c 
•S90^8 
2-2?  oy  « 


iiJ 5 JO fi  >. ™ X)  o "O  cj cy .E  >.o  o  & 


;UJ. 


. ^E«  >«>>>. 

£££-c^  C09j=££ 

UJUJUJUJUJ  UJUJUJ 


E 

.8 

2  g 
E45  2  o 

(Q   <p   (Q  ^ 

^   C   ©   § 


g_co 

^    X 

^  o 


SI 

?s 

D  ,,  o 
CO  .9  CO 
.9  ®.9 

III 
5^o    !  (0  a  CO 

^   9   9  9   S  A 


"O      -999 


9  I  ;«,=    •  €  •  -g  2_?  2 

«  <   CO  .t   9   9   ®   c   O   p   O" 
9   9   9  o   P   P   E   9  ••=  :S  .•= 

^  E  ^^   9   9   9   9  i   «   i 
^_9^^^  —  -C-S 


CO  9 

il 

E? 


CO  CO 


.£££££t:— i:  •> 

z'uj  uj  uj  uj  uj  4i     4i 


D-29 


Appendix  D 


^:s 


wz. 


0)% 


(\JOOOOOOOOOOOOOOOOOOOtOOO»- 

«ooooinooonoc»500ooooooi/>'>-ooo 

OOOOfMODOOOOOPJOCTOMO^OOOCVJOPJOO 


o  oo  o  o  o 

o^oooo  _           _ 

moooioi-  opt^copp 

c\j  Tt  cvj «  o>  t  00  eo  o>  n  c\j  CM 

ui     oocococM  oicjco^mio 


lA  ^  ininmin 


^  a>  c  fl)  ©)  _2  <o 
•  E^«  2  "  ») 

£f5.9  b  X  o  « 

>>S  j:  com* 

5^=S  "  «  •  <0 

g  S  §  «  (0  (0  « 
fli  Je  ,.  >t  >«  >«  ^ 

X  X  «  «  (0  (0 
LLI  LLI  U.  LL  UL  U. 


^9SSi 


«  • 

CO  fS 
«>   V) 

c  c 

«  9 
■?■§ 

88 
»  • 

.£.B  <» 
EE§ 


o  ooooooooo 
o  «-ooopoa>po 
o     ddddcimaiy-^ai 


cono)h»cM^f«.0)»-o<o<et^o»o>o>o>c5 
t^<ot^t^to«ocor^o>o>o>o>o>o>i^«)»-^ 

i-O  00»  CO  0>»-CM 


oicvifberi 


oo  coo 
mo  r^o 
mo     om 


CMCMCNjmmmoomm      comm«-mmr^  mm<- i-CMC\jcMm  m^CM 


la 

(0   CO 

^8 


Q  .3    W  ^  _g 


f  2 
2  o 


•S  5  5<  S<  J-  To  CO  ■   '^  «  o 


cog-cog-cococo®*  >,  J'>.^.£ 
xJSxnXxx-^^xmX^x 

£   Q.:E   Q^  :E  £  _L  -1  £  =5,£  £  -e 
>.>,>.>,>.>»>.>.>.  >.  ?^  >»UJ   CO 

UJ  QjjJ  Q4JJ  UJ  UJ  UJ  UJ  UJ  H^  UJ  ^^ 

rvj     CNi     (\i  cNi  c\j  CNj  c\i  c\i  SUxi  Z     rg  c\i  c\i  rtj  c\i  CNi  c\i  cvi  e\i  CNj  rvi  c\i  CNt  est  c\i  cvj 


XXXX-I^XXXXXXXXXxXXi     CZ>v^ 
O   CD  C2>  <S  __  0®0CDQ>Q>9C9C]>aCS9  cm    I      ,    r*    ^ 

££££lL£dE£££££££-c£:^^^0'>.c»£ 

>,>,>.>,>,>,>.>.>,>»><>,><  >.■>,  >•  >~  ?"  M  ^  -£  UJ 

.^^^^^^^^^^^^^^  ^^  ^  t  .2  -J  tt  . 

jujujujuJUJLUtSiSiiJUJUJUJLijuj  cSujuj \iL^  •  d^s. 

CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  a   S- 


«  5  c  E  coo. 
>'E  t  >>Q.!2 

(O  tii  liJ  Hi  UJ  C{vj  ••- 
Z  Z  '^  CM        CM* 


D-30 


Synthetic  Organic  Chemicals.  1990 


U 


cos 


o  o  o  o  o  o  o 
o  o  o  o  o  o  o 

O  O  O  CNi  O  'J-  o 


CO  m  to  m  00  lo  •* 

O  t-  O  •-  O'.- t- 


pvooovooooopiotfl'^pppp  in 

<bob  O)  dcj  d  00  ^ricri  riocood  od«d  uS  to  -r-^ 

tn  (-- 00  tn  (\j  t\j '<r  lO  IT)  mi/>  in  tr>  to  00  (7)  to  to  r- 

cj'T-^toto      »- »- ^  ^  T- 1- ■r- to  n 


ooo  ooooooooooooooo 

COOO   lOOOOOOOOUIOOOOOO 

uioqp  tpooooinotntjiO'^t^cooo 

f-^'^tb  •^dcoTrodtbcStbuS'-^d'-^'-^'^cJ 

m  to  oj  o  to  CM  t\j      r-- CO  c>j  00  h- >- to  to  ■<»  to 

•^  irt  T- t^  »- •>-      inciifi      -^^  >- 1^  h- to  to 


cviiAin  locj'^j-'^^toiftin^toiftCNjcgcMCsj 


•o  * 


ss- 


«  o  i 


(0  in  S 

t         ®   ®   C   w 

5 .2  o  o  ^  -p 

2  =  (/)  to  «  t 
flj    nj   <TJ   <TJ    (5 

ooooo 


a  10  i^'( 


a  o>  n>  4^-  u  «^  T} 
3  3  3  ■=  (0  ^ 


—  —  —  —  —  —    tCg 

QO 


3   3   3   3   3   3 


to  a> 
5'c5 

11 


^  E  o 
^        O  0)  "> 


in 


nj  E  a>  «  _-_  _ 
y  S  ?  i  2  2  9 

!;;  Tn  O  9  O  <B  O 
iS  —  O  O  O  O  O 
3  3   >'^^^^ 

BOOOOOO 


OOOOOOOOOOOOOOOOOOlft'>-CVIOO        OOOOOOOOOOOOOOIOOOOOOCOOOO 

— ~ ooootooooooooo^oooooomooo 


ioooon'«rr^^nr)m<-iotoior<-t^r^cooooocooo 
»e\j^  ^toh»  •-•-'-»- to     r>.  r^  f..  h«  f»  r^  r>.  K  r>.  In.  tN. 


lOlrttDtDU»tOtO^<0<Dt00^^^^^5^^'5'55 
»-»-00»-00»-000»-00000000000 


or>-c\joir)oot^oooooooooinoo»-ooo 

h**— C)m»-^00O)000000<O00CD0DO)CJC000C\l*— r^CMOO 

ciiOJ     to  o>  to  ^  to r>^ r^ r^  r^ f- 1^  r- 1^  p^  r^  Tt  irt  o) »- u> 


irtwooto{otototo^5'»'*nn'«mu>cg^ioc5^inm 


<-OOOOOOOOI 


(OOOOOO'-'-'-'-O'-'-'- 


■g 
15 

c 
« 

f 


?f:floo>cj^^oor:ejg«'5J     £ 
'i-<\j'*trttor-.»-cMrpp)5>    -■S  a  e  o 

-._._._._w,_^CMC\JCVJ20jc'"  — 
U.CCCCCCC«*«Cc° 

«2.S>.B>.2'.5>.5'.g'.o^-^-£^g)o  m 


is- 

o  •— 

_    U)    « 

>■  o  c 


o  o 


S  bi  ii  !;!  «  l!?  !^  !;!  I  8  8  b!  I  ^ 

llllllllilill^ 


c  5^  ^  S.c 
5"i  OC  IP  S 


2  S  E 
52  2 

U._3_3 
OU-LL 


C    <B   SO 

o  E  c^S 

ll._3_3_3 
(■Ui.li.LL 


^—  • 

£  c  • 
g>J5  « 
ir)to«i"E 
-CNjc„^§  s  i^sS 

.u  .u  .u . u . u  .u  u  ■«  1 1 1 

E  e  E  E  E  E  E  E^  c  <d 

■D-0-D-D-DT3"DT>  — "^   cl< 

«n)(0(0(0(o<ora.5.g.g* 
ci  w  CT  ci  ci  ci  ti  CT  ?■?•?■  r2 
E22S2EEE***'-' 

QQQQQQQQ222 " 

rerora.y 

i-o-DTJ-o-o  E  E  E  E 


.g 


Ll.li.li.Ll.Li.Ll.U.li.U.li.1 


•c 

3 

9-.>  5  >• 

>-2   OTJ 
•-li-LLPJ 


E)-31 


Appendix  D 


^^ 


w5« 


ll 
id 


O  O  O  O  O  O  O  O  O  O  O  O  O  O  OOC\J 

o  o »~»  o  in  o  irt  o>  p '-^  p  o  irt  i/i  cr»  u>  in 

•^'ij-'-^uSaior^cvicJcD'tcNJ'-'oi  cdod 

(O  00  ^  n  00  o>      o)  o>  o>  00  CM  CM  in  <-oooo 

^c\jr>.     <o  CM     m     a><D  eo 


ooooocMOinoooo 
looinoooooioooo  ooooooO'>-ocmoo 
p  o  o  o  m  in  p  o  o  m  TT  o  o  00  o  '- o  o  o  to  o  o  o  o  in  o  o 
«D  CO  «b  •r^  00  n!  oi  o  cvi  (D  00  oi  iri  t^  •^  \rt  d  en  c6  to  d  d  d  ■'^  en  t^  d 
CT)  ^  h*  CM  m  •»- cj  h»  en  oi  o>  »- 00  CM  cm  •*  cm  r-- o>  ■<»■  co  co  cm  en  •^  co 
»-co  in      0000  CMCM  cji      oicoineo      cot^r^t      cocm 


o  >> 


2  2 

Si  c 

ri 


•  o  «  f^ 

si «  o  2   .  s  s 
S  «  JS  >.  >.  o  u  iS  -c  • 

XX      XXX       CmX  C 


o  o 


**  *^      c  5  £ 


i: 


1 


(gaiQ.Q.«cxcc 

X  X  CNJ  CO  X  CSI  X  X 


l- 


go- 

<=     M     0  = 

O  c£ 

«  a>j: 
jB  o  «. 
o  o  m 


£5 


so 


O  Q>  4>  ^ 

XXX  ^" 


«  c  c 
"S  «  « 

■588 

-g  (0  R) 


X   X 

a  « 

XX 


_  • 
°1 
M  o  a 
Sec 
S  (0  « 

I*   X   X 

T^XX 


2  m 
X  O    •  «  _  § 
«  Q. 
II  •til 

J!  J?  J  E  S- J2 

w  w  o  w  (0  w 
■OTJTJ-O  X-O 

(0  n)  (0  (0  d>  (0 

X   X   X   XX   X 

XXXXZX 


ooooooooo 

OOOOQOOOO 

inpph^anppoqo) 
•-o>a>o>*— incoooo 
inin<ocM'-CM«5'^«D 


OO  OOOOOQOOOOOOOOOOOOOOOQOQQOOOOO  oooo 

oo  oooooooooooooooooooooooooooooo  oooin 

po  oinpppo^, oqcMco'<4;pppp(D^oo><^pppppppoop  pppr-^ 

t^CM  cocri'»ino>CMOiincb<d«bin<bt^a>i>«.'i^^t««!od»-^CModco^o>c)»-^eor^'  r>»'oobc»j 

(0(0  <o<o(0<o^^^(D(0(0<oinininm^(Doo(Oin'^<-OT-<-ocMO>oo^  oo<-cmco 


CO  CO     inio 


CMCMCN!CM<M^inCMCM        CMCM       CMCMeMCMCMCMCMCMCMCMCMCMCMCMCMinCMinCMCMinin»-U»in»-»-»-»-inin^U>UJ 


«^^££Soooo 
•■6«S**iEEEE 


«  « 

a  e 
o  o 

c  c 


2 


c  «.2  o)  '. 

i'>,2 -2  2- 
o5-e~«  Q.UJ 

a  SiS  Sco 


gggggllllg: 

uouuuuuuou 
000000(50(3(3 


3  g  9  w  g  9  e 
o  o  a  S  a  9  9 

Q  U  O  U  U  U  U 

oo  OOO 


99999999992.  £.£.£.£.£.£.£.  e-o 
ooououuoouuuuuuuuuu'o 
OOOOOOOOOOOOOOOOOOOOOOOOOO 


9  &  e 

u  u  o 


992 

(D  0)  4> 
"  O  O 


2  So 

>>  ..a  « 


>"a  >.2 

9:e.-5  3 

X  <  o  o 
OOOO 


D-32 


Synthetic  Organic  Chemicals.  1990 


^S 


o>  o  o  o  o  o  o 


u)  (o  (o  h>  ir>  ir> '« 
'-  o  o  o  »-  1-  »- 


ooooooooo 
ooooooooo 
qoqqqqqqq 

CViCMCO 


ooooooooooooooooooo 
ooooorooooooooioooooo 
o<\jo<cmoomoooooooooo<\j 
o)«-^crlo)o6Nicjconc>^'«rc>(T>c\i'^oicbuS 


o  o 
o  o 
o  o 


U)  o 

•«r  o 
o>  o 


II 


o  ra 
E  E 

O   3 

XX 


n 

£^.   . 

>'a  »      — 

■^•o  O  c  c  c  « 
"O -O  "O -O -O  TJ -S 

xxxxxx 


II 

—  n 
0)  u 

»  2 


9  e 
.■S£ 


U-O      .    0)   (B   «   o   o   O 
Q.Q.B  «  «  «  «  10  g 

£  2  «  o  o  o  00  O 


^  ^  to  «  <o"  O)"  «o"  «)  <fl" 
ccccccccc    . 

•o-o-o-o-o-otj-d-d'e 
XXXXXXXXX 


3  V>   tf>   3 

c  tj  «  e  ■; 

2.5  »-   ^  .5 

?  3  3  ;= 


2o  E  EO  *-o 

,    ^    ,    .«    Inl^'O 

O  00  O  O  a « 

<«  «o"  </»  CO*  lo"  !c  -J; 
c  c  c  c  c  jr  E 

nj  B>  nj  ra  nj  .c  .E 

T3  T3 -O  TJ  T3  -O  T3 

xxxxxxx 


u 

E 

«   3 

«!_«*«>"  ■£2'5 
■>.«  c  c  c  « ■£  o 

g^EEll*:! 

*  "P  ">.">>  ">.'>.T3  ^ 
■o-onjwninis  — 


ni 


«  « 


!a  a  »  c 


S  5  J  J  5  ™  „  C 

Sc  o  o  oj  l^o  o 

O   E^~  —  —  is   TO-D 

■5  -o  T3  -5  -5  -o  >L'>.'>,^"5  c\j  <5 

1  ^  ^  >«  >*  >*  ^^  ^  T"  T"  ^^r' 

XXXXXX  i-i-i-i-x  .r- 


t;  ts  >•>' 
3  ^  o>  o> 

■0.0  T3  "O  a 
©  ts  ®  ®  ts 

fu   </)  R)   (v   tf) 

C    C  C    C    C 

d)   ©  O    ®   9 

0)*D  O)  CT'D 

O   C  O   O   C 

X       XX 


m 
S 

3 

E 
• 
^    •  E 
•0  e  fi" 

CO    cfl   „ 

c  c.U 

®  «  tr 

o  c  p 

tsf 

X      X 


OOOI^OOCMCMOOO 
OOOTtOO'-CJOOO 

oooomooooino 


OOOOOOOOOOl/)OOP5^0<OOOOOOOOOOmOOOOOOOO 

oos-O'-oooooi-CNjinminomooooooooo'-ooooO'-oco 
0'-eooooi/)oocooocDtD(Dir)(Doooo)i/ioooor^c\joo«oo)0)oin 


T-T-T-  *—   0>000h» 


f-O*'-  •-  CO 


.00»-«-»-00000000»-»-»-»-»-'-'-0'-0»-'>-'-T-^»-»-^ 


5  • 
E  EE 


13 


as 


iS.  3  M  a  >. 


■g. 

^  <fl 


•5^ 

2  S- 


(oS 
.9-10 

■D  5 

<o  e 

ill til I I 

CO  c  v  V  v  N  .2 .2 
r^cg«n'n>n:2'8'g^ 

^  *^^CO  CO  CO  .jQ   c   C 

e«e9  29e£"^^ 

O   y  T>  -O  T3  T3  -O   flS   o   o 

"o  T}  :=  o>.c  .c  x:  .c  .c  b  c  b 

CQCQCQCOCQCOCQCQCOCOCOCQ 
XXXXXXXXXKXX 

XXXXXIXXXXXX 


^r 


<0  _ 

'e 

T  E  • 
c  c  c 

£■£■£« 


-£■£■£« 

u,   O   O   9   C 

«  E  E  E  5 


fi    X    X    X   • 


• 

IS  E 
E.!S 

g"8 


O   9 
CO   9   0 

T  n  re  " 

C  C  9  9  2 
CS  CQ  XX  S 
9  StfXO? 
XX^"-'<M 


To 

c 

5  *      re 


J5  T3 

5  re 

£    X 
9   Q 

o'O   9      •£ 


;  V  >.>.>.-5> 2  2 .c -c    -  9  a> 

'   9   9  9   9   9  •=    >  O  •=  •£   p   C 

:  X  X  X  X  X  9  L.  (Q  re  p  ^  — 

wl99999Ua_-:-i5J5E 

2cXXXXX«J5>-J-re>.re 
9  *cocorir)ro  i'J'9*  >'9  >• 

IX X    X  ^  "T"    X  ^    X 
,    9«««(»i!>mc299+.9^9 

^  X  u  o  u  u  o  X  X  c  Z  X  c  X 


"O   *   9 

_^J5  ■5  9 
2-£  ?Q 


E^ 

3   (A 

in  b 


5  c     .'Sot 

■5  JO  e  9'  g  io 
>.  >.'re  re  "■'«» 


glEo2t^S85i 

ii  ¥  V  9  ■=  5  S'.c  j:  3  u 
>■  c  £^  c  c  X  S  33J!1  ^ 

9  >.>>>.><';;'>.  >N  >.>«  >. 

XXXXXC>JXXXXX 

B I  X  X  X  clTx  X  I X  X 


D-33 


Appendix  D 


U 


*!^ 


WS 


o  o  o  o  o  o 

o  o  -^  o  o  o 

q  p  q  o  p  p 

o)  o  CO  to  1^  rj 

•^  in  CO  o>  o>  ■r- 

CO  CO  CNJ 


CM  CM  en  lo  i~~ 


o  o  o  o  o 
o  o  o  o  o 

o  O  lO  CO  o 
C>  TT  cvi  •*  1^: 

CO  «0  <D  •^  0> 

CO  •^  o> 


O  O  O  CM  O 

in  o  •-  >-  o 

p  CO  p  p  in 

o  o>  o>  m  o) 


o  oo  oooooooooooo 

o  oo  oooooooooinoo 

o  oo  cviomoppppineqcMtp 

CO  OCM  0)0>N-COff><nO>0>05^0K 


0)  o 
Ltl  2 

—  ^     '—* 
"Si  «  «5 

C=  c  c  <0 
^  3  -r;   O     ' 

o«a2cM 


>»  e  ®  ^j:  a  9^ 

g  J  go  S.'V  g 
S  o  2  >>  X  >• " 

I  :s  I  -o  >.-D  ^ 
Ci-i  «ij.i  5-1  £i 

■A      'A  rviZcoZ 


> 

■2  c^ 
P  o   • 

<0   O   m 

■—  o  *  *  >; 


o 


«  C  ><; 
p   «  -D 

«v  CM  .e  c 

E  csi  "^  X 


2c  S 


,        JS:55X£     .ni_:.i_-i-> 

«i^-|EEco^|E^>. 


Sis 


SJxxxc^PxPfc 


■>-      Z     im'VCM'*      cvj'^r      I 


E  E.'S  « 
X  S  E  e 

>:  -o  X  X 

T5   >.0   O 

-T  ^  >•  >■ 

cmcmX  X 


% 


9  a 

c  c 
o  o 


a« 


9-^*  V 

0.0)  g  « 
CM   *  CM  ~  _L  £  -i_L 

EiEi^S":Scv 


E>: 

^    (0 

ti 

%^ 

«  9-0 


za- 


*  Zs 


m  E 

c  ^         "^^     - 

—  5  "O  "O  ^ 
o  $  o  o  o 
^  c  nj  (D  flj 
g-  flj  o  o  o 


•>->«Lp-s 


xSxx5>2«>> 
2*22  o"§,g  S 


CM         CM        ■^  'J- 


2  -c  £  j:  £ 

CO  fll  (0  TO  (w 
V  1=  c  <=  c 

Z  CM  CM  CM  CM 
>>>>>>>>>. 
X    X    X    X    X 

O  O  O  O  O 

■5  -o  •5  -o  -D 
>.  >^  >.  >.  >. 

IXXII 
CO  to  T^  CO  CO 


-li 
^.%% 

o  V  iS 
o  >•£ 
™  2  £ 

X  'n   X 

S  >.2 
tjX-o 

>.  '  >. 
3CC.I 

^  CM   O. 


•  p 


X  >• 

1     X 

a.p 

ax 


O  O    O  O 

o  o  m  o 

•«»■  O   CM  o 

o  m  o>co 
•*co      o> 


o  o 
o  o 
o  o 


o  o  o  o 
o  o  o  o 
o  o  o  o 


o  o  o  o  o  o 


^  Oi  0\  Oi  o> 


o  o  o  o  o  o 
o  o  o 
oo  o 


o  o  o  o 

o  o  o  o      o  o  o 
p  op»-      pp  p 
r-^  oi<d  ^      (doi  00 
^■^-^H/w/wj      incoco^      mom      i^uji^      i^ 
0)»*      »-o>»—      »—      <o      oo>^o>      ^co 

8 

a> 
>  m  m  m  m     co  <d  t^  r«- co  r^     h- ^  m  t^  j:  co  t  co     cmcm^      ^ 
>»-»-•»-■•-      oooooo      Oi-'i- o^  ©■^  o      ^^1-      1- 


lo  oo  oo 
>  o  o  o  o  o 

ICM  oo  CM  O 


cm     CO      ■^  at 


r^  o      CM      eM< 


^  •^      CM      CMm  ^^ 


■2=- 
po 


UJ 


& 


t.  I-  *  *  m 
»  »  JS  m  i 

>.>.£q:!3 

S£  • 2£ • • « 
^  «  E  Q.3S  w-^ 


P  (0 
c  "  S 


3.21»       .      _ 
5t5e&.u!S 

?->.  >.-o  g  o  £ 


pp555^55'Vb-2  2  2'2^t?co-0 


EQ. 
^  O 


cm'E 

£■?. 


■  c    c  c  >.>.>.  >K : 


E 
2 

■OT) 

><  >. 

XX 


r? 


3^^ «-  j-j-j'-lttoi's^^sixj-^^* 

i-2222222J'5-5'5'2  9B->-ee=r^>- 
2  "S-'S.'S.'S.'S.'S.'S. »  2  2  2  ^"e"S.  >•  2  "S."?.  2x2 


XX  Q.CLO.Q.^C 


E-o-D-ox:?-:?'3E.-o: 


Q.n      XXXcMh-r^      XcM^XcoX 


eg 

CQ.3:  ■; 

zCt 


I  g  o 


E  ■2  TJ 
«>  ^  o 

o  .U  y 

c  ^r  — 


-o  «  « 

CM    '^    ^ 


■5  £  S  •» 
>..2  >>p 
X  10  X  ^ 
2  «  P.3 

1 1  <S  I  g  X  -^ 


9  p  2 

P-D   QL 

p  g.p 


^  c  ^ 
O    t  £ 

3  •£"= 

<A  :=  <n 

E  P  E 

=  w  E  w  S  m  .SJ  .U 
•«:,•.«  gg-cc 


p  (0 

=  «» 

in  E 
!3J 


fas 


s  2^>."  " - 

"0'r-  =  »-Pi"CC'S>. 

>-_L  P_;.a£®«?£ 
x:  >.^  >,  <5  (D  -o  -o  fc  (5 

^osoEo-c-c-cg 
>-P  R  o^  >.>•>•  >-5. 


.zt: 


(A 


2^^      ^       ^ 


E-¥.E 
z    z 


V    ^   V    m — 1 
>»  P    >.5  CM  • 


^£g£p2t-o^-o2i 

X^       ^      ZXXX-- 


D-34 


Synthetic  Organic  Chemicals,  1990 


ii 


ooooooooooooooc*>ooooooooooooooooooooooocnmooo*-*-ooo 
oo^inooooooooiooooooooooooioooooooooooooooooinooooocM 
ootor^cMcoocsJoooi/>r^oooooi/)OOO^cr)<£)OOOOoocoooioo^i/>f^'-;^^o>c*50oooh*r^ 


^6 


^•S   TO   «   >^0   *   O   «   •  — 

o  5  -z^-B  £  0.2  -c 

ir  >.>>>.>.>.c  C 

gCCCCCjOTO 

ciStotAcocniocov) 


—  ^^_^«^»_^^JzJ2^.^^^^^^  —  —  —  i^^  —  —  —  —  —  ^C*)  —  Z  —  —  ^ 


Q.  Ql  o 


OOOO  OOOOO  l/)'90 

oooo  o»  o  o  o  o  r^t^o 

poop  -r-pppip  PP'-. 

por-r-  ^  ■^  c^io  r-  eoeoui 


oooooooooo      o  o  o  oo  o  CO  m  o  o  o  oo  o  o  o  o  o 


oooooooooo 
■vooiooooooo 
^rJobcvirjcNJcvJO'tuJ 


*S 


oooooo>-o>o  o  o  oo  ooooo 


oor--.r~.u3a3iD^»-iD  o  o  or-  r-oonrj 
CM  •- CM  c\j  c\j  CM  c\j  o  (/>'-•-•- in  <o  (o  p)      ir> 


lo  ^  ^  lo      CM  r- «o  CD  (o      c^cncn      ^ 

»-^»-»-        »-    O  O  O  O        ••-'-O        •- 


CMM(OC0in<O^C0CO(O 

»-»-oo»-oo»-oo 


o 


s 


i! 


■5 
cr-r- 


E 
a 

■e 

Rl 

_  «  ^ 

IK   X 


1 


o  ^ 
5^£ 


3  .=  .=  -r   u   u   u 

c2J    21S 


"One 
E  f  *  CM  o  _ 

■S-gSSo" 
^Ji^A  CL-2 


C3)  S 


»  a; ' 


(0  _  m  T3 
a  5  ™  >-o 

<S     >-i    S   0)   ,> 


8)    o   6"   0?ra?" 
£    '^    c  ra 


c  m  -<<'  c  E  jg 
c  c  c  2  2 


D-35 


Appendix  D 


li 


05^ 


5S 


oooootoooooooooooooooooooooooooooooooooooooooooo 

OOOOW»-OOOOOOOOC\JO^OOOOOOOC\JOOOOOOOOOOir)00'-000000000 

ooooc)pooppr-oui'VC\jinc<5«0'^uiCNjcoc)encopo>oooopnopiDo<ooooooc»)oooo 
odo)Oc\i<b»-obc)ood»-er)c>»-<b^uS^^o>o)oc^iuSoo^o>o)ot^^o>CJC^i'— cococboN^irio 
co{0^r«.o>CToot^coo>^<oocsioi^r^mc>jc\jcor^o>cococ\j«ocoi/)cO'-coo'<rr»coo><Difiooh.r^'^<Dr5oomt^ 

O  O  O  0>        CM        '-CM        O        »-»-»- "W  lO  1^  0>  0>  CO  CO  00  I- Irt        ■^ '^  00  ■*  lO  CO  U1  CM  CO  ■^  lO  IT)  IT)  Ul  <D 

COC0eOlOCMC0»-CMCMT-C0O>eM»-h»eMCMCSJCMCMCMlrtlOCM«MlOCOU>«O<Oinirt«DlrtCMCMCM<D00CMCMCMC\JCMCMi-CNJir) 


a 


•  >. 

■5  X 

0.0  — 
.<2^  O 

mo  a 

III 

9-Q-9- 

O  9  w 

c  c  c 

'>s">.">. 

Ca.Q.CL 

2  S  2 

Q.Q.Q. 

o  o  o 

^  JO  JO 


osz 

'■tz  a 
o  E 

«  T 
O'- 

CM  CO 


c  5 

n  o 

2l.£ 

(0  CO  o 

-2  y  E 

ill 

Q.Q.Q. 

22  2 
aca.a 

to   (A   « 


O   (0 


>.Q.a 
E  "  o 


Q.Q.C1 

2  2  2 

0.0.0. 
OT  (A  9> 


2  >• 

S  C  « 

•E  •  n 

>.>.o  >. 
o.o.>:  a 

228-2 

O.  0.10  O. 

88" 


n 


^■D      _ 

o  «  <5  mis 
£  o  "o  « 
EcEc" 
m  n  u  m  o 
■2  £  I  a.E 

£  «  Bj  2  E 
•  >>E  9-« 

;z=  O  X  —  C 
^   O   O-O   <" 

_  •  ac  0-5  « 
fi^«-i2E- 

A   «^  U  O  U   U 

■JSJ^  c  n>  "O  ™  <o 

>  ^  0>  k-  k.  k„  h.   k_ 

O.  O   to  It)  10  (Q   (0 

O   —   O  O  Q  o   o 

O.O.OT  M  V)  M  Xi) 

(A   9)  <A  W  si  10  9) 


n 
u 

tl 

ifi.i|lli 

_  o  E  "i.i"?  » 

iS-2  g"2'8"''~ 
I  w  £  o  Q-.sa  T  5 


T3  C 

"O  w  o     *  ^ 


■^^£«S'-g2.2S'5i«2    " 

L   H<   At   m  T-   Mt   m   u   ^^._ 


X  c 
(0  O  c 
E   ®   3 

(0  C.2 

£e§ 

a)j5  g 
■9  >-P 
=  0-5 
o  o  JS 

^tt 

•£* 

ffi  (dS 

■J.E5. 

i  ><?   >< 

E   ^5-   <^ 

8&0:§. 


^^^°E 
I   •   a  n.3'^ 
.2  .Q  .S  «■  m  « 
m  75  «  5  2  y 

£££s  a-s 


p  ■S;  o  10  _-  ®  ■ 


00000000000000000000000000000 
OOOOI/)OOOOOmOOOC0OOOOOOCMOOU)OOOO 

o  CM  CO  o 'T- o  01  o  o  ir>  (^  a>  o  o  o>  o  o  o 

<bKir)(b^Kt^o>ob<binoai 

<o^oo(OCMCMcviir>r^(oa>u) 

•-»-l«        000000^0)00 


S2J3-J  3 

_i_jeol2._i 


y.y.u 

3    3   3 


y  .y  .y 

3   3   3 


ra  (0  (0  n)  CO  (Q 


ooooooooooooocoooooo 

ift<^r-»r^r^i-»*-»ON-0000*—  000»-0 

OCMOOOO'lOOCMCMO 

CMCJCOON.'^lft^'J-tbcbO) 

v'#  1-^  \-j  ^-j  uj  i^  <D  CO  0>  CD  00  ^  ^  C>  f^  O  O  »— 

0000      irt  cocomoocM^  o  o>      i-^co 


•Ox 

f^ 

CD   9 

c  c  O.C 
SS  X  0>c 

.c  j=  .S  E 
0000 

CO    CO    (O    </) 


-o-o 
E  u 

io 

y  3  (0 
is   g   O 

o  mc 

o  >«■•= 

c  c 

m  nj. 

c  c 


15 


5- 
■922 

O-L  j- 
.C   >.^ 

.   «5   C 

.--9  « 

00         ~ 


<0 

2  I 

(0  g 

1° 


CO   <0 
<0T5 

c  c     •  « 
Cm  —  o 

<o  g  c_ 
<o  *  ™  >« 

o-5"^o 


CO 


'.  c 

ffl   T-     O 


To  E 


™   CD-g   <0   ™    ™CO'^  J2   °§ 

ooOOOOOOOOOOOOo6wwww«wwwww-v.  —  ----- 
<2J2i2J2i2*'**A(0<o<0(0<0(0(OfO(0*o<oto*ococo<0(0<o<o<o«0(o*oinwtot/) 


fxcccccc 

X   O   ®   <D   O   <D   9 

^^TQ.aaaacx 
ooooddooooooo 

<0(OfO(0<0<0<0(OCOfO(0(0(0 


o  (0  n]  (0  CO  ®  (0 
Q  jc  ji  .c  jc  c  a 
.c£  2  Jc  E  2  9 
a  Q.  a.  Q.  Q.  Q.  Q. 

0000000 


ECi2o 
3  !2  2-5 

>.>.co  CO 


O  (0 


<»  o 

0000 


r-    O      •    w    O   O   C 

E  o  >.o:i.c5 

_-  c  c  o  <J  .2  <o 

iE^oo^^l 
£  JO  g.j:    •  ^2  •£ 

™a:=sif5g:S:.? 

—  ->.>.>.o--^ 


^  ^  2  2  d 
oaoooQ-ao 
•    -  ■    005^ 

o-^'  o  o  6""  "  o 
Irvico^ 


I    CO    to  ^1    CO    CO    CO  , 


D-36 


Synthetic  Organic  Chemicals,  1990 


h 


ioiop'-oc)o>'»ooooppc\ir>-pioc\jtnppoqpcjo 
•  cooioo      in<0'i-i«ioirtinioirtioiftir)in>n'««o?.  ■*«2^:: 


ooooooooooo 
ooooooooooo 

00l/)0000000>0 


o  o  o  o  o  o 
o  o  o  o  o  o 
o  o  m  o  u)  o 


CO  CM  CJ  O)  ■n  O 

cJiifliof^'-      toio'nr^S-KtMCMOCMCMi/iCTCjr-*      to 


iSS! 


00»-'-»-»-'-»-000 


W2 


=ls 


cc>  • 


II 


E« 


M  E 


s  E 
n  3f 

ii" 


IS 


Si 


•  (0  =  ' 


:oIe5  2-2815 

^EyOcO>2w=0 


•  E 


•o  o 

2=         >. 

•  «  •  •  * 

■a'?  2.2  2 


88 

3   3 
«   « 


III 


^8 


♦r2g.2  5ccccccccc_ 

—   S«iA3333333333S 

Tcccccccccccccg 
£  E  c  c  ■£  'c  c  c  c  c  c  c  c  c  E 
.2*.2*.S'.2*.S*.C.2*.0*.2*.B*.B*.S*.S*.5Pij 


9  n  3 
«  E    " 


<0   « 


B  t  "  w  w  c 

Sao 

.^  «=  o 

10  >•« 

^O  n 
«  O  a 
c  c  c 


SS5 

oo'o 
c  c  c 


o  • 

«l  (0 


(0  • 

5  8« 


£  « 

o£ 
=  o 


^1- 


t    -c  >>S  S  • 
•  J2  c  S  « -2  « 

•  o| E  E  E  E 

<n  ^   O   3   3   3   3 
«   8_-g  :£  £  £  S 


3   3   3   3    3   S 


■D-O 

c  c 
(D  n 

5  5 

I  OIO>c 

-     -   3 


u.u 


<o_ 


28»-i52i^ 
a  n  c  M  v>  c  jj; 

S  E  E  E  E-d:S 
«  •  3  3  3.3  0  u 

c  i  ?  ?  ?  ?  y  y 

*^  .X  o>  O)  O)  o>~  — 

(Q(QtQffifO(Qff(0 

22222222 


OOOOO  OOOOOOOOQOPP  O  P  O   O  P  0(00  O  p  O  Pp  O  Q  eOO  O  O  p  po  CM  o  o  ^  in  to 

ooooo  poSrooiniooopoS  eo  op  ppON.opppPoS5i-porM  o  oom  o  oronro 

Ciipp^o  5^,  ocMoocNjCM^inooo  o>MoiApoKopppppoooppppppppoppp 

r^r^iti^  m  jbjbVui^oioirtrioijoi^  oio6l^)0^p^^V«^-^»^p«bt^dl/i^rtuSo^-0)•-'-'-'»r>>■'r»ir>>."^^ 

^ h> CO (O ^  r<>0> ^  Oi 00 epop ^  ^ moi Q>  ^o>0i  n.  ocoP  p  Oiactf^O  ^  ^ '-r^  oo  oooo  o>o  o  ooeoeooo  oo 

iniAiniAiA  '»c\i     S>     95         eMO>o>  ^ift«or<-«o»-«r«.i>»in^«-j;j;^ooooo»-»-ooooo 

CM  c\j  c\j  eg  u)  CM  m  CM  in  CM  ^  ^  CM  CM  irt  tn  in  oocmio  inminin^  in  win  inj  ^  jt  n  5  n  5  n  ^5  5  ^  ^  5  ^  ^ 


Si::: 
•   • 

.2.2 

oca: 


(0  (0 


.U  .S^  .U  .U 

T»  m  1/i  Xi!  _  — 

■c  t  cc  •  >> 

eeee|-2 


?8 


1 


T5«   *  = 


10  <o  a  a  —  2  -£ 

3   3   3   3   3  2i.t3 


|-|tltl||llllsl|1p|l1l 

eSttt>t>t>tt^£-tg£-2-a-2-ol-o-o-o-OT)8 

3_J3333333333S3A  AA«)mR)nl<0<0(S3 


»-CM»-  "-^    •- 


III 


S3  2 
cdSco 


IOQs333333 


388 

^ _._  3    33 

(0   (Q  (0  <0  Q  ^r*        (Q'(0(On)(QfO(OIO(On)<B         (09     <p<^Q}999i9<p<p<D<p<p9<i><B 


•OTJ 


•-COO 
O  C  C  C 
CM   >   »   J 

•  922 

300  0)0) 

.u    k.    h.    ». 

>.    3   3   3 
3s  x:  3=  : 

I  S    3    3    3 


in  CM  >-  COCO  PI 
c  c  c  c  c  c 

$09900 
Q   9   9   9   9   9 

(£00066 

3   3   3   3  3   3 


888888 

3    3   3    3   3    3 


D-37 


Appendix  D 


u 


to^ 


•^oooouio  oooo  ooooooooooooooooooooooooo 

c\joooor~*o  oooo  ooooooooooooooooooooomooo 

ooooo'^in  0)000  ppqoqppoooiooi^pcnpppoppoej>ocoo 

ioo6oob«-'-''r  »-^o6N^c\i  o>'«j-ino>ot--i'*iouScri'*'o»-'»-^o)'-^iricouSo>iO'-^c>ii^cb 


oooo 
oooo 

O  00  o  o 


^  f\J  Irt    CO        •*  IT)  to        CMCMCNJIAin 


o »-        ^        r- 


5  «  o 
n  E.E 

=    O   N 


:S2^ 

A  2  S.  a  «  o  s 
>.  o  2  c  E  «  E 

E  o    •  2  ^  o  -S 
o-£TQ.o02my 

m  *  2  2  mffl'2  — 

^EooSooJ^n 


01  "O 

:s  o 

E 


8    9   (D 
C   C 

■5  E  E 

Q  9^SS 

t-M  •?  ? 

j:  o  tj  E  E 


10 

m 

(0 

a 

E 

w 

3      • 

8 

Is 

(0 

o 

•5 

?2 

<0 

8 

o 

■o  E 

c 

C   3 

10 

W;= 

^ 

,  ^ 

—  o 

V 

li 

E 

lie  acid,do(j 
lie  acid.mo 
nie  acid   . . 
nyl  chloride 
iH-indene- 

thetic 

1  bromide 

-  a 

:« 

■   9 

■  « 

•  E 

i  «  o  o  _ 

~X(0(0      m^^^^^^ 


c  c 

o  o 

CO  (0 

(3  ra 

«  o 

c  c 


,   c  •  « 
o  >>.£  c 


o  o 

11s"-1e 

o  «^  o-s  n 
•^  c^  -  c  c  c 


(0   A 


c  * 
E  ° 
iE 


O  CO  .cc 

^    0    O   O 

S2S 


"O   9 


«  c 

O   10 

E2 

ill 

».   m   <" 

SS-e 

cc  2 
-9.9  Q 


E- 


®   IS  h^   <D   O   <D 


X  X  S  X  S  £  E 

O   O  O   O   O   m   o 

■B-B-B-B-B^  c 
9  s  a  9  c  <  o 
222ZS£^E 


X  "C 

o  a 

£  JC 

«  o 
.-  E-;, 
0-C-tM£ 

|£5^8«8S' 

«  •  o  >•  >>  ra  So 

>•  E  £  wS 

■o  o  t?  •-=£ 


Q)  Q>  9 

Z  S  S  ^  6  6.^  eg  c\j 


--  _  -,  X  U 
.  „ »£  o  o  o 

^  >>  .  >  •  •  • 
c\j      eg      »^cgcti 


oooo  ooooooooooooooooooooooo 

ooooooooooooooooooooooooooo  _    _ 

oot^oo  ooooooooomtoooooifioooiooifto  o  r««oop«^t^«)»-CM'-pppocooop 

S"»-^p>;o)  y-^aiieiaiaidf^t^aic^c^t^dc^eidomcoaidui'^  tv!  Nl^dcJobodoboddd'-^'^oiobdddcsJri 

»-^iO  t^cOJOOOtoKoocMOOtocDtooeomco      oooicooo  o  oinmiooooO'-'-'-o^mcootcom 

»- ^»  ifl  Tt  «D  cc  r^  CO  !>>•  r*  •- o  m 't  tt  00  CO  «D  t  to  o  ^      t  •*  oo  <o  »-  •- o      o '-•-'-'-•-•-'"  ^  id  <o  co 

mcviin^  irtir>co'»miO(OiocococDCDcD<DcDcDn^oo^^cD«D  t^  r»«t>»cor»r^i^h»r^r^i^«omi/50>o>cno>in 

^•.-»-^    ^^.©'-•-'-'-••-OOOOOOOOO'-O'-'-OO    O    000000000000'-»-00»-0«- 


9  9 
•OTJ 

(0   (0   O   o 
O  O  "*: 

•   «;^-5 
(0  (0   (0"T 

Z220 


S  E 

0:i 


^2 


•1.  CNJ   0>  C   C    <A  ^ 
</)    CO    CO    CO    (A    CO    </) 

c  c  c  c  c  c  c  ' 

0>0>0>0)0>0>0)C 
cccccccc 

22222Z22 


■5  •  «  eS 

f-   <0   (0  —   rt 


S  2 


9   P 


2  55:u 

w    QD   CD   O 

2222 


222 


^  E  • 
CO  <o^E 
-^  -  S-^ 
•  <"  B-O 
E  28°- 
«  a  o  o 

V  •  •  <g 

2S  o_ 

(0  <o  CO  £* 

E  E  E  g 

_      5£5x5 

e*~~   o  O   O   O   9   C 
C    C    C    C   C  'g 

I  E  E  E  E  E  S 

Qj  JQ   (0   W   fO   (0   CO 

2222222 


11 


_1   (D   OU-    C     . 


Mm 

p 


O)   CO^ 

1.1  S 

S--6  g 
8  ot'n 


■9  ^j5  o  o  o  o 
o  —"CO  (0  CO  3 
-c  12 :5  S  j:  £  £ -J 


2  6. 


o2««=,»T..sty  

S;.S=9of  i^5^o8!^Soooo8 
^oo--5«>om  <P  iH£  To-D  9  9  c  c  c  c  2 

CO  CO  cb  f «?  T  ?  §  o    -^  g  §  B.a.B.B.tt. 

«  a  a   ,   a  a  9  Q.^  ££Sou9«aoai 
2  2  2  9-2 22»^^-^^  "^-^  •^^^<«>«:-e 


^22  *  *  ® 


22222 


(b.  Q.  Q.'D  h.  ii.  cb.^  -o-L-!.222rgrgrgKi(\i 


D-38 


Syntheiic  Organic  Chemicals,  1990 


u 


to« 


W)S 


o  o  o  o  o 
o  o  o  o  o 
p  q  CO  q  o 
00  oi  d  ^'  CM 
o  o  •*  •^ 


lO  o  o  o  O  >-f\J 

CO  t  CO  o  o  o  ■.- 

■^  •.-  ^  o  o  o  o 

in  in  iri  d  ^  t-'  c\i 

tf>  <o  «>  •wr  ^  <o 

•V  ■*  ^  C\J  00  CO  »- 


oomooooo 

OO"-©©©©© 
0>00<MOCOOO 


rv  o  o  o  o 
m  o  m  o  o 
O  O  ID  o  ■•- 


o  o  o  o 

o  o  o  o 
c\j  o  m  o 


'»-'^tMOC\ito»-oo      000)000'-      »-«3inin 
CM  eo  <o  o«)  o  »- o      •-  in  tt  CO  »-      •- r-~  «3  oo 

r-  ■r-  .- CO  O  f  O        >-         TJ-  o  *-        >-  ^ 


oo  o 

in  o  o 
•-  o  o 

Tt  Tt  iO 
00  CO  <o 
O  O  CO 


cvjcommh-      co^f^cNjinm^m      c^r^incom      mcocvj^t      co      com^ 


Si 


E  nj5  >. 

I'^'^^S^ctj   gcM 

ZiT-O-O-2   £.52  <B 
—  —  _  —  —   r.    tjO-rj 


.1 

-i  >• 

I" 
I  8 

--.  O  J-. 

>.  E  >> 

£  E£ 

O  (0  ® 


>.><■>.  ><">.-°   m-°S 

x:  £  £^^  ^  _-  ^_-  ^ 
• • o ® *^^^2 

OZc^ZZZ      2 


CM^^  CM 
•i2  S".!!!  ffl 


O  >,^  >.o  >,-fcfc 


Z^'^E^st^Bll^  : 

i  >.  >.'7  o  -r  >>i5  >"0  0  "^  •  w 
£  £  >K  =  >.£  >.■£  >.>.  >.2  2 
*  *'£(n£  *£  *'£'££(<i« 

'  "^      ScmZcmSZZcm 


'  *?  -r     f    - 

ZcM  cocoZE 


1 

n 

c  X 

--.    -E* 
«  «       nj  o 

E8S|2r 

c  o*  oZ 
>>  G"  g- >.  *  ^ 

|£|-|il 

OZEZE  r>j  CO 


c  t? 


■§£  «-^ 

C  CM    ^     I 


™    «    O    >> 

^.'        E  £  5^  C 

;--  »    >.  *    o    > 

>-S  £  2u  2 

"  «  «■?  »■? 

a  a.(M  -c  CM 

<5  g-e-^  oco  s 
2  >>>•>•  ®  >--S 
c<,£££-c:£  (5 

^^  <j)   <p   (D   Q.  <p   O 


o      >. 
£  ^• 

«  CM   p 

.5£  >. 

■  i::5  c 

54.EO 

°-2£i§ 

c:>£  =  c  -p- 
9?^  S  o 


TJ  r»  "*'.  ^  S 
>•_■•*  (0  ^ 
52  — "3 

•O    >,CM   O   M 

®  i  «  ™  • — • 
2i^2 


o^ino»-qqco 
iriooNicoduSoico 
CMOinintoeoom 
T-  •«-  o      oco  »- 


mS 


U 


■^r^oO'-eoO'-h^ooooooor^oooO'- 

co<DCMn^uS^^^d^'odcorJin*'dddcoo)0) 

inf^i>»inincMr-incMCM»-^oinocMcno>»-'-»- 

•-  »- ^      40V-CMO      ocor^cgn^'^ 


t^f^ini^N-ininK<D<ocoininr«.mincMinininin 

00»-00'-'-000'-'-'-0'-»-»-»-»-'i-»- 


OOOOOOO   OOOOQOOOO 

goooooo  r^inooooooo 
qqooqco  0'-co»-;C\jqpN.oq 
obd'-Jor^incM  r-id'Ti^dooodoood 
cjJt^r^mmr^h-  in'-u3in»-t^r--.f~-r- 
•»r  o  o  o  O)       •- t      >- o  o  o  o 


_  2 
c   O 


E   • 


2  E  £  a>  -c 
?  eg. 

£  S££2  S£2  •§. 
CM2cM<MZ2Trco  •- 


^\ 


m      . r 

Q._    O    O 


C* 


t;  • 


CM  c»  Q- Q-  S  •  ?  E 

^«     >.>.RjC-^0 

><  £  «  » ">.  E  ■5..0 
.£■^"■51.0.™  a  IS 
1^2  92  >-9.E 
Si»  9-9-9-P9-E  _ 

><  ^■^  f  CM  £  •»»  J5  "O 


i<;i322222  o  o 

C02cMCM»^C0CVl22 


£  • 


•  E  ?  « 
S  o  t  >■ 
«  2  c  o  5  o 

1222e5^ 

»   O   «  iS  ^^  ^ 
CO   >»  TO  ^  W  *J^   (TJ 

£-2  ■^■^  ■£  -£  £ 

flP  flP     ,     CP    9    CD 

2z2Vr222 


if 

«  J5 


ES 

till 

gislES, 

<=  c  E  E.C 
E  c  n>  E  z  » 

£  £      £  £  ? 
22c<i22 


n  CL 


« 


« 


fl5  .^ 


00     .  —  :; 
;iJ    <B-    0-* 
C   C   o   S   2    " 

>.>.■£  •£  c  ^ 
£  £  J?  c  J5  ® 

22£  >.£^ 

■      ■     <»  ^    (T  £ 

S.5.2  o  2  ffl 
CM  CO  ci2  cm2 


c  o 


C  J»    B    C    C 

o  0-555 
E  y  N  j:  J= 

^         3.5  (0  <J  o 

w  _  E  2  ?£  i:  >■  >- 

•?i5«Soooo 

£t^>-^££££ 

©^^^JH    (D    (S    9    © 


D-39 


Appendix  D 


^•s. 


C02 


ll 


toa 


OOOOOOOOO'-OO 

oooooooootoo 

OOinU1lf)C\JO<DOOOCD 

c\iodoJ'^'r~-^ooo)r-.' •»)••<»■»-' 00 


c\j  o  o      o  o 


o  o  U) 
(OOJCvj 


oo 
cocvj 


oooooooooooo 
ooooooooinooo 
looinooocopi^copp 
cors.'c\icr)c\i'^'<b<bcjc\i'^eo 
^•.-»-h>.ooo>c\j«>«)f-»o 

OJ'-        ^  ^  ^  O  •*'-•-'- •- 


oooooooooo 
ooiooooinoooo 
oqipoqqcNjqr^qp 

t--.r--o>«ja)'^a>r~a>«) 
■V  o>      c\j  •-'-•- o>  O  00 


CO      CO  r^  ^^     CO  ^ 
1-      .-oo      •i-O 


o    ■    •  * 
o      *  10^ 


CNjC 


■o^o 


~  >.>.>.>, 


•  -2  5  -^  i:  "^ 

|1      I 

*  ^  t  c  «o  •- 
ff  C  ~  Q.O  o^  2  O 

Et55  o^£  2  .  fe 
J>.||  E  EE  >.wo 


N  2 


S^E^E  2^ 
9JS.W  <5  <5 


■£—  • 
n  o-o 

>."0  (0  «2 
>>E  =  S^ 

X  (Q  lA  n 


«   3 


o  5     i2 

Om  $£ 
c  u  o  a 

!2c\j2L3 
c  e^.S 
2  c 

fiiiiil|i|litl|l!l 


_^o  c 


nj"0 


r5s%rc?i|ES-r. 


n  c 

c  3  2  o 

1=6  «  <» 

"-"S"il.9 


3  o  Q.P  O  c  « 
Ql9. 


(oiliJ 


■£  *££'££^£  E 

Q  2  O  O  (D  ^  ^  ^  (0 

Zc<j2ZZZzE 


lAOCOCNJOOOOOOOOOOOOOOOOOOO 


r^ooooooooo 
o>oooooooooo 
o>oomou)oo^oo 


floc5i/>r^^floo^o>iooo5»-»-»-o«Mco«o^in«oco  cooor^coio^r<.cgo 
«-^<ocs^i/)o>o><oo>ocoo>a>a>ioa>(or^h>h~-CMa>  (D^-mo><-oo(ocM<o<o 
'-■^^'-cuco         o^rxcMOOO     O'r-oxnoioo         »-o^flor^»-     flo»- 


^^  r-   ^    ^ 
OClJCO   »-    •- 


coinirtcocM'^aimt^N- 


E  • 
Z  P 


3=  • 

Ie^ 

3  3  CO 
-   S      '  S  <"  P 

"oj  :  ?  2  3 

8>>o  :Eo.8 
•  f^     Erss 

$  >.'o'~  c  *  " 
?-£.iE=5«« 

■*  •  ei5  a  E  E 
iiSll-E^^ 


5  »>.s 
»  •  o 


=  3  >..^S'5 

22ESfS|>.|^g.|§5| 


o— ■ 

EE 
•■§. 


E_ 
.S  * 
*§  o 

s  • 

«  E 
-S  « 

'E^>> 
«  c£ 

T5  2S9-^ 

=■=■0 


=  2 

JO   3 

.$£  « 
2.2  o 

18  5  p 
^*^  X^  i?^ 


■»2  SL>.«  3   :=oiSl 


s^S.'O-fiJo  • 


d  o 


m  r-  ^  -C  -— '  m 


8.1 


2  a2     421^!. 


cm2 
eg  CO 


o  2 
2  ;t- 


D-40 


Synthetic  Organic  Chemicals.  1990 


(OS 


«:S 


299200000000000001000000  oo 
oooooooooooocMOOommooooir)  oo 
qppuiococopop'<j-pi^pooo)0)oor^i«'^  >-;« 
oo»cooc\i»-o6t~^obir)odrjodc\JT-^c\icioco»-^ff>^  ^-^uS 


nrt  ■>-  ^  m 


v^  WW   u/  1^   I'*  VJ   UJ  V>J  UJ  U^   '^    ^  S'J  I'J  ^^J  fj  ui  w»  ■ 

o      CO  »- to      rj  n  CO  r^  PJ  CM  CO  CO  ■*  CO  CT«  I 


oooo  o  o  o  o  o  o  o  o  o  o  in  oo  o 
oooo  o  o  o  o  o  in  c\j  o  CM  o  5  o  ui  vn 
^ppp      co'-oinoo^pinp'^.  ooTfoc) 

csjv-*-^— T-^-'-^r^      cocNjmu) 


00        C\J  rr  T  CM 


in  CM  r^  in  l/>  (O  (C  (O  (O  (O  (O  lA  m  CM  CM  (M  CM  CM  CM  CM  CM  CM  CM   in  CM        CM        CMCMCMCM        CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM  CM 
t- ^O  •-»- O  oo  O  O  O '-»-'-»- '-•^  »-»-»-»-'- r-*- »-        »-         »- »- ^  ••-         ^  T- ^  »-»- ^  »-»-»-»-•-»-•- »- 


&I 


K  E  <5==  ?  •  2 

E  Q^  c.c  Si  « 
g  ;g  >.  >  >  g-  o  :2 

0    0  ^E    ^    Q    9    (])    Q 

22cmZZ222 


u  a  o  W 

m  —  £  in 
3  O  Q  • 


in 
« 

X    a. 
-I 

•  E 

e|& 

w  S  E 
c  o  a 


«  «  £ 

>wcx: 
X  ao 

5Se 

•■§.12 
«  a  o  <S 

E  e  E  S 

EEEc 
n  R)  CO  9 


"2^ 
•  « 
n  o 

X  ™ 


ǤE 

■D  «=o 
*  5  S 


a.  ojs  ™  (0  «  « 


=s'8.x«  

■g.x2'g"g'8^-g  -g-g 


=  '^  ? 
«  (0  £    ■ 
o-o  •  « 


9   R) 

•  S 


•^  m  * 


1-1  til 

^  n  "  w  " 
S  S  X  o  X 


.9>. 
-o  ■n'D  X 
9  9  >'0 

■>.">.2  * 

X  X  m  J," 
o  o  c  ■s 

£  £  E  ™ 
9  9  _o  ^ 

_-_-~  v> 

Q  O  O-^ 

e  c  c  o 

9   9   9    £ 

j:  .c  j:  9 
5:5:5:0. 
—  >.  >.  >.— 
JO  jc  je  jc  >■ 
>.  (0  <o  <o  -= 


<0r= 
S  O 


=   ?=   9   » 
si  9.E  c 

«E  "  S  E 

I  o  2  o  >. 

|||«& 

>.£    «  V   9 
JC   9   Q   9   c 

«  ^  S-i:  9 

*^      .99999^ 

"  (ojij:.c.c.c>«S_5  "  >  s 
« .c  a  a  a  a  a©  2  o  -  "o  /. 

™  c^  a.  a  a  a  a^  •"  =■  Jo  "  S 
,  o  ■5.>.>.">.>.>«  <o  >..5'-£  .i  -g  ■ 

£j£J£JJJ£J£JS-DJ£^.a.c  io 
2(o<ora(0(0(09io"'(0(0o 

■p'p-p-D-0-?~"0'§T5'DT)- 


tUi 


9   9   9S 
X    X    X  ^  ,- 


•s  a  9 


^onin^co'^coo 

<DCM(OTr^(0^(0(0 

oooo     in'-     •-     CO 


o  in  in  00      o  00 

flb  OCO  '-^        OCM 
»-  CMCMCM        ^  »- 


o>o>or^inooooo  o<-  opppp 
(dcdcooDoiodd'^od  inin  ihco^incb 


*  ^<ocooo< 


O)   ^"  ^-  O  CO  CO  »- 


o  o  o  o  o  o  o 
o  o  o  o  o  o  o 
CO  eg  CO  n  n  o>co 
•-'•-'  d  ^  d  o>  in 
O  n  CM  •-  CMwr^ 
r^  <o  ^  T-  ^  ^  ^ 


cocococo      CO  in      cm  cm  «d  in  in  in  in  »- r<- m  co  co  oo  m  m  m  cm 


E.CJCO   >>o£9 
IS  ■s  c  o  ~  ~  ~ 


-    C    9    c 
(0   o    E    9 


o^tltii-ilF"^^ 


^ ^ S'c  Q.  Q.  a-£ 

£:£2-g2>j£££?£:§:i3  a.  >.^  ^  t  "§;-  >^"i;-  s^^  > 
'IT  .^  zZz2 'f  CO  < '^      ^>^CMco     2z     z2cm22t^222 


c  ~— *=  «  ■=  » 

A  —  _  ^  <o .—  n  ■— 

i-^:5  0-;  J  X  * 


22 

O  (0 


9£££9^-g£ 

6222ZZ      2 


»!  <0 
95  « 
CO  CM  E 
=  — ^  D 

c  -2  <J 

"5  " 

'  9    .3 

O  —    9 

§;£.£ 


as 


II 

9   c   C 

E  I  o 

Si  2 

§oS|f| 

9  -0   3   ™  T  tC 

o  (0£  gOco" 

«   CD  CM  £  £  ■>, 

>.  >-■>.">.■>.—. 
.C  .C  .C  .C  .C   9 


I>-41 


Appendix  D 


U 


cos 


«2 


ViZ. 


ooooooooor-^oorooooooooooooooooooooouiooooo  oooo 

ooooooi/)OOf~~oooooooooooooooooooooooc\]ooooo  oooo 

ooir)oooo>ooooooooooir)ooqooomoooooo>oooO'-mir)oooo  oooo 

^'cioiuiodoi'-^citvi'TrT^cviood'^'cvJiO'-^^cvicriO'.-'oicoo'^rN.'oioduSo  ^  duo  -^ 

■<»^'<»-ocor>.coi^oof^oo'^iO'^Tj-oc\jtMc\jcor~-ioo'«#ujtO'»-a3cO'<-f^t^c\jir>'-c^'-r-  ^^t^.,j- 

cvjm      CO  o  o  ■^  ^  00  00  00  00  00  00  •<»■•-■>- •-      m     cotO'-»-m     t^ooo^-n      co  oo^-»- 


c  C  o 

</)</)  9. 

0  0  = 


>M0 

CVJ  •• 


» ?^"«  ^ 


£  c  c  c 


n  (0(o  o 

«  "^"^ 
c»o>S  S 

E  £  o  o 


:e:e:e  c  S 


o  >.2o  2  21=1 
a£  m  CD  O  O  >  > 
o  ®  ^^  *- 
,2  E  ^  5 


c  c  c  c 


ccccciitrt: 


S  ®  M 

m  "O    " 
"£^ 

.9  3  i 
c  <2  c 

Ot3  « 
"  «  N  -Q 

8l|i 

0>Q.  9  T> 

(0  flJ-^-i 
tn  a  o  « 1=  ~  c 

Q.  Q.  Q.  Q.  O   o   S 


li  i^  Ji^^lilliiiliiiii^i^i^^^^^^^^^ 


2  2 


.2  «  9 

S  i-o  T)  o  2  ::  nj  (0 
w-Soo  o  o  ?••  ® 

£  £  iS  i^  i^  S>  >•i>i•i^  o : 

8  S  .i2 .52  .12  .S2  .52  .52 .52  .12  O  ' 


0£ 


w  o 


n  re 

0)0) 


CT3     .  =  2 

.=  £    •"-". 

"O  ffi  ®  ®  Q) 
O  c  c  c  c 

to  ;=  _®  ^  ^ 

-  "  T  re  re,. 

(  a   Q.  Q.Q.Q.S; 

I  re  re  re  re  re  "^ 
IZZZZZ 


5 

■o  -;  ■  "> 

U   (8 

rex: 

.y  o 

X  re  'o  o 
O    -  n  re 

re  m  c  c 
o  "  o  o 

■r  J  m  ffl 
«  «n  S  S 
re  *^  « 
£  ffl  re  re 
j:-=  x:  j: 

^-£  re  re 
<o  reZZ 

C\j"Z  CM»- 


OC\J 
CM  O 


ooinooooooo 
ooir>or--o>oooift 
OT-ooooino>oi/>oo> 
r^»-^t^co<bo)0  0'-^«> 


r-  o  o  o  o  o  o 

oo  o  oo  »-  o 

o  o »-  mo  oo 

r-i  r^  r-.'  ob  r^  r»^  oo 

00  CO  CO  ^-00  00  CO 


i><-i^ 


CO 


o  o  oo  «-  »- 

(b  odcNJcococNJ 

h^  r^  CO  CO  CO  *— 

CM  CMCMCMCtJCM 


o  o 

oo 

f^co     ooooopco 

iri't-^     r^ o> r^ 00 '»  o CO 

'^t>>      oomoor^ooo 


(O 


CMin    CM    CM  CM  CM  CM  CM  CM  CM  Irt  CM  CM   CM  CM  CM   CM  CM   CM  CM    CM   CM  CM  CM  CM  CM    CM 


COCO        lAOO 


CM  CM  CM  CM  CM  in  lA 


tl 


re;;  c 

gs8 

0*0) 

•tree 
-^  |-o  E 


*; re 

re^"   - 

•^  'p  nj  nj  nj 

(0    CO    (O" 


2re'!5™-S^-S 


®  re 


woo 

">.■>>■>. 
000 


tf)  9  to  <o  (/>  <n  u) 
re  ^  re  re  re  re  'g 

:<AXQ.KX><><X 


Es 


to  _^ 

£.  ^re  relo 

o  «  S  S  S  ^  .. 

j=  n  V  A  o  '-  o 

®  O  w  w  O  O  O 

K    ><    X  X    K    Q.  K 

iS22i22     2 


re  re 
^£ 
ao. 
to  to 
o  o 

^£ 

aa. 
■D-D 

c  c 
n  re 

a^ 
'm'n 
>.■>• 

X   X 

«   CD 


_re 

P 
fire 

a.  CO 

■D-D 

c  c 
re  re 

"8  "8 

X    X 

O  O 
O  CD 


00 

|;588^188  :||  ill 

o»-s  <"<'<o«<renfrerefrere 

reretoreretorere 

c  c  c  c  c  c  c 


«  8 
to^ 


^^■D^^-D^^ 

a>oo®®owo 

XXAXXIAXX 

22     22     22 


:*:E 

i  re  « 
!  «o  o 

I  ^  re 

I  tn  .^ 

('•d'-d' 
)  at  9 
I  ■S  ■S  o 


JO  J2  JO  3  rj 

8^^  «  5 

re  re  re  o  JS 
re  re  re  re  u' 


■5  ^ -D -D -D -D -D 

X    X    X    X    X 


;  « 


2     2 


2222 


a,™ 
C"<rt 
re  p 

o^ 

2^:2 

to  o  u 
o  X  re 

2 


S€ 

*  « 

^CM 

o-o 

«  o 
0-5 


c  re 
^1" 

=  -D- 

rec 

-O-D 
«  0 
X    X 

22 


I EEoOO 
re  o  o  5  "D  oi 
^^"glE-g 

to  •=    m=    9    £ 

-d22  re  «  * 

S'S  =^  >•  ~ 
re  to  to  w  =  o 
>^   -    -  c  re 
c  J2  J2  "  .U  OT 
■2  5  ©•'So 

^   ®    ®   O   W   ?   rt 

5355  2  S-8 
re  re  re  o>.„  re 
C  9  (B  o  —  o  .^ 
2  CJic3)Cji2  c  o 
to  o  o  9  s  CO  to 
10  >  >  >  5  S  5 

2-D  "D-D-O  5  5 

aa>  (B  9  a  ^  ^ 
X    X    X    X    X    X 

222222 


D-^2 


Synthetic  Organic  Chemicals.  1990 


u 


(/>2 


W)« 


OOO-^OOOOO 

ooooooooo 
<Dh-oomoooo 

CVJC^J'-lOCOOOOI-CO 

-  m      t-^  r^  <o  CO  00 


CTOOOOOOOOOOOOOOOCnOOCOOOOCOOlOOOOOOOOOOOCM 

r^oooooooooooooooooooooooooouiooooooooo 

OOC\I0000000000000ir)00U1000<£>0'^0'-00000000C\J 

»-»or^ir)fOirtoot^oooooooor^r^ooooooo>o>ooooouiCvj'-'---inoo'-iDCjf\)(\jfo 

"- •- CO  >- ^  •*  ^  »- »- T- ^  ^  T- CM  C\J  CM  CM  CM  ^  »- CM  CM  eg  ■«»  Tj-  C\J  ■*  CM  OJ  CM  C\J 


■S2 

O    >£ 


88 


>.  >«'c  c 

®  S  S  o 
zzzz 


T3.E 
O)  c 

III 

(0    (0   ™ 

.c.c-5 

O    O  JC 

ro  m  o 

zzz 


re 


in 


re  K  n 
X  •V 
2  =  CM 

*  5.™  o 


E 

as 

"2  "O  s" 
u  u  u 

u  u  o 


-i 

•n  -^ 


aaa 
in  in  in 
O  O 


'Is 


■n  -o  a  a 
oO-- 


c  c  c 


U.U 


o  i 
c  a. 

II 
ZZ 


If  .«"•• 


I  0£ 


:t  .tr  .tr  .e  .tr  .tr  .t:  .- 

zzzzzz: 


.•e  .t;  .n;  Z 


u  c 
re  o 
o.g 

=  3-6 

«  re  re  E 

.-=  -^  ^  N 
c  c  c  c 
re  re  re  <D 
000^ 
•=■=■=  2 
ZZZ^ 

Q.lf>    T^ 


O 

^  re 
•  •  o 


"S  «^  i: 

2z| 

z  E  6 


o  2 


Si 


.0  K  c^o->. 
o  c  re  "^  -  - 


2o  2 


E  Q.E 


ZZ 

CM  CM 


?;sfl 

■3  2c5  ^a.  <5-c 
4  CM  inZ  ZZ  i^ 


1° 
.2  re 
■D-c 

*  «  o  o  o 

m  c  c  c  c 
^  9  0  9  <B 
t  ^  jC  ^  ^ 
<t)  □.  Q.  O.  CX 
g   O   O   O   O 

J  z  z  z  z 

Z   0.0.0.  Q. 


0000000000 
ooooooooirjirt 

IftOOOOOOOOCM^ 

■^aodaidaotoixici^ 

f^^»-»-CM»-CMVCMU> 

f-  T-m  ♦-co 


00000  000  00000000000000000000000 

0  00)0  0  000  moooi^ouiocMOiinooof-^ooooooom 

CM  moo  o  oo<j>  ^oooo>ma5<otooqir)qir)<Dh-;P^oooqi/)«> 

r^aiiDtoco  ddr^  CMCocvi^iuSr^^oioi'-CMtb'— 0)0>^^^^^^CMO)cb^l/i 

IT)  <oint>.  CM  r«- »- o>  10  CO  CO  irt  irt  o  o  irt  o  o  o  m  in  <o  i/>  <o  ui  (o  00 

♦-  •- •-  t^  «o     CM  u)  •- CO  CO  »- «r)  h*  h»  r«»  ui  m  ui 


CS<0(0  00 

CO  r^  CM 


CM        CM  CO  Tf  CM  CM  CM  CO  CM  10  CM        C><   CM  CM  Ifl   CO        CO  CO  CO 
^         r- O  •- 00  O  •-»-'- »-        «-»-♦- O    O 


6        <",=    «    <B 

re      ®  re  o  m 

re  ^  re  » 
•-.     .C.2.C-0 

i  ilts 
5  5^ 


0)CM  ? 
r-CM-S 

<5  .-CM.2 


</)  ?  re 

«  E  9 
<n  re  Q. 


EEE«5|^5. 


11 

-2z 


|l 

Z  0. 

6 


E  o 
o  E  _ 

ill 


9      .     .      .".      .^MM 
«  T3   o   0   00   O   U   0   U   O 

^(prererererererere^ 
ETo.U.y  U.U.9.U  U.U  c 

;=CCCCCCCCCp 
reA0Q}<9®9090M 

aaaao.aaaQ.o.g^ 

rererererererererere 

ZZZZZZZZZZ 


re  re-E 

CCL^Z 


E  o  J7  c  S- 
M  ^    •  •£  re  Js  >.  ,,- 

=  >>E2  >.•;§  re    .  „ 
^■£«-^^V  in  »f 

^z-§.-§.5|^2£-? 
re^re  re.-gc  dStS 

.-a    - z z    z e-z 


T  c  re  2  g.g 
JS    ■  ">.E  *5  re  o 

-•!^  III  1 1  IS 


E  "  = 
re  c  re 
o  i  <" 

I'll 
^  □. « 

^  ■°"° 
o  o  o 

w  o  o  o 

■>*>*>.>.>»>*c  c  c  c 
-  QQQQQQrererere.. 

(?d£^d£^d£:£  (1^  !l^  ^  (1^  ^ 
VnjrerererereT3"OT3T3'D 


C3> 


00000 

zzzzzzzz: 


T3T3 

o  o 

9   9 

ZZ 


.:2 

_o 

>*  rti  o»  ^  ®  m 

o:iPu™  8  ™- 
■5if^--g|§8  8 

g-g  a>i-2.g  0.0. 
£reS9.9re>.>. 
™  Q-2  "  "  c  c  c 

-O.C.C  E  E  CXQ.O. 
00000000 

ZZZZZZZZ 


D-^3 


Appendix  D 


^S 


ooooooooo 

0U10000000 

o^oor^oqinqq 
oicvJujcriuSiricNJotb 
CO  m  <M  tf>  CD  c\j  ^  ■»!■ 
CO  ^  T-  f-  »-  CO 


ooooooooooo 
inoooooooooo 
'-ooooooooooo 
irJNiooO'-'^^cvJcoi/ico 


o  o  o  o  o 
CO  o  o  o  o 
u>  q  q  q  q 

OJ  C\i  IT)  «b  CO 


oooooooooooooo 
ooooooooooinocvjo 

CDOOO*— OOOOOCvjr^OOCO 

^tocduSc\Joib«Dt~^'-<biriiri<b 

tf)U>tr^'-«D'-U3C0C0«0f^lD<0 

>- CO      CM  in  r-- 00  00  00  »-      •- •- 


id 


in  IT)  m  m  CM  c\j  cj  c\j  CM  in  c\j      c\i  c\j  cm  c\i  cm      cm      cmq^ 


m  S  k. 

=  S  o> 

C  «  C 
(0 


o  o 


2"o-p 


Q--^-:irr 


V  .-  ™  ^  ^  TS  TK 

^  E—  oO  •  • 


(o  CO  i'.E  c  c  o 
c  c  c  «  ?  ?^  o 

zzzz 


CD  .0-  2   •  O   U)   O 

»-8      ^^ 


o  'B) 
Si 


n  c 

SO. 


_  o  o 
9^^  - 

t58| 

c  «3  n 


E^ 

0)  "O  c 
T3   *  18 


c  Q-U. 


_  e:  S  ^  J^  iS  ^3  3 


S  c  c  c 

^  <1>  (B  O 

r;  «  $  o 


E  o 

■cc 

=^  Q.  y  c  » 
•  £■>.*§ 

C -D  « 
<p  (0  ^ 


r% 


«SE 


•See  E*    -r. 
S"  2r  8"  B"  5^ -g  s 


Eai 
T5 
3   C 

(0  ^ 
T5  6 

«  "■£ 
c  ™  « 
O  O  c 

Sh  >. 

<B  5  o 
o  2-c  « 

Nl> 


•sEEco«iP«xB*'o»55Sn5''<»>"<9"'''"™™-C(*\-c 


G^-g  -o  g  ■=  c  c 
•S  r  ^-2  c  "  " 


o  «  « 

"^  o 

"  ™  m 

0  o 


="2 

o  a 

<o£ 

(0  >. 

1«9 


(/)  TO  (0  ^  ^  c    • 

g.yagggi 

re  o  o  (0  (0  n  a 
T3  «  ™T3t5t3T3 

9^^9999 


lis 
<»" « ™ 

a  >>>. 
=  =  u 

5<Si 


oooooooooooooooooooooooooo 
ooooomoooooooooor<-ooomooo'<fo 
oocMO'>-'«ooooiAooorgoor»oqi^CMOOO(oo 
«-^CMO>oc)cg'«tni4<o>AOi/>irio>oiQi^r>^<b'^Ciioio>e6cM 

COCDCO^^CM^>»'t^lOCMCO«OlO00W00CMr^.h>.CO{Mn»-00 
^  ^  cm  CM  CM  ••- CM  CM  CM  <M  CM  CO  •- »- m        »- r-  »-CMCMt>.CO 


^CMOoooqcoqino>otoooqqqinoo 

cocr)dcfr^o6d^coaluSc)''^iriir)C\J»^»-^'^'cocb 

cooomiAooooiA'>-CM'<9"<tir>moO'-eocorocou)oo 

r^  r»  CM  CM  f".  r>«  r<.  h<.     f^h»     »-cocom<     co 


|S 
in  >• 


?«.u88c<i. 


«  E. 


c  '*'  t-  .= 


(I)  «)  o 

^  •  « 
«  "-  2 

Paris  §e 


Q.  Ql  O -C  -^  ^is   ** 

o&ooo2ocooc-oc 

zzzzzZz 

T^  CM  «rt  <!».•*  z  6 


E  (iZ< 


i::-^ 


<o  e  a.S  T  >«Z 
c  c  c  c  c  c  • 
"  o  o  o  o  o  ^ 


58-S- 

•S  o  o 
o  Q.a 
c  c  c 

(Q  S  o  o  o 

P  >.>.>.>. 

^    X    X    X    K 


jb  o  o  o  <D 

"o'o'o'o'o'o 
c  c  c  c  c  c 

.C  ^  ^  JZ  ^  ^ 
Q.Q.Q.Q.Q.Q. 
>>>.>.>.>.  >.^ 

c  c  c  c  c  c 
o  o  o  o  o  o 
ZZZZZZ 


2  "  « 

ill 

5  •   >--p  TJ  ~ 

•g^«  X  s  0)^ 
Slpls 

^8-°33E 


"2  •  * 
2  M  '(5 


^^  —  ^^  '^ 


s^^siil-g.-^ggiE 

■D-p-DTJ-OS      .^O  C   H  «      . 
O  a  9  9   9SL  9  ^£  ^   X  ">.  <" 

55555  —  5  **  ?■"£* 

xxxxx5!<nj2<l)o";^Q. 

^^^^^££  t  (»-**=  8  Q 
»o5cdcd'5*o5oo2?  5-5 


"S5 


E£ 


ctc^ccczc^cccc-cicca.  ci'-i  C  m  >  , 
OOOOOOOOOOoOOOO^OOO 

zzzzzzzzzzczzzzcmZZz: 


D-44 


Synthetic  Organic  Chemicals,  1990 


*:2 


ViZ. 


*:2 


O  O  O  O  IT)  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o 

OOOOO  OOOOOOOOOOOOOOOOinOOOOO'-OOO 

oooinin  o'Tmoo«>f^oooop'-^i/)c\jc\ja)00ooooiOLr)in 

-  7)  r^  r^  r^  »- co  co  <£>  co  »D  (D  <D  o  oj  m  o  "- O) »- co  lo  U3  r^  (O  o  o  o  o  <D  r-~ 

l/)(0(C  CJCsJPJ        -r-CVir^             CvJCJ       O  CO  »- CT^  •^  •^  CM  ■^ 


c\j^c\jcsjw      c\j  cj  CM  cvi  CM  c\j  c\j  e\j  CM  CM  m  c\j  cvj »- c\j  CM  cMin  m  CO  m  m  in  lO  <D  JO 


o  CO 
d  ^ 


o  o 
in  o 
o  o 


oooc\|00oir)in 
cjodt^'-'-idcbjbob 
oO"-ogi/>ir);D'- oco 

r^  CM  •<I  lO  CM  00  CM 


>-~^ 


c  c 
E 


®=  E  5  •s'o  « 
c  CO  re  is  J2  *  ^ 

"O  «  c  X  *<  5  -' 

z  S  «  •  •  •  * 

o'oo'o'oo  2 
re  re  re  re  re  re  re 

.y  .y  .y  .y  .y  .y  ? 
^  ^  ^  ^  ^  ^  (/) 
oooooo 


S.re^ 
o  »  « 

s":5.'2:2 

o  u  u  o 
re  re  re  re 
o  o.o  o 

<P  <X>  <1)  o 

OOOO 


y 

E 
re 

c 


.2  E 


re  re 

s  :t : 
3  3 
in  en 

s:2 

u  o 

re  re 

y  y 
!*  * 
oo 


!  C   3 


!t8E» 


°5g^ 
■re£    -o^ 

.  O  tn  ^  0} 

>•=  P  O  TJ  t3  5  re 
O".2c3«0<o«)? 

^!iiip|ll| 

.ii&i8|2|s| 


O  in 

re£ 


.9  re 
i/>  ■» 

3)  O 
^  "> 
«.£ 
p  in 

8.  o 


E?o 


)6zoo6oooooo66do6o66 


>-  •-'2 

66 


*CM  ^- 
<JCM;e 
TT'T-re 

^  O    CO 

-  ™  s 

»  X  <n 
6r^ 


^1 


I 


IJ^E^ 

"'  s        CWJ.  jc  £  O 
re  re  re:2:5S.±  o 

XXXXKKXK 

oooooooo 


oooooooooooooo 


CMCMCMU)       m 


OOOOCOOOOOOOQQQOQOOOOOOOOOOOOOOOOO 
OOOO»-OOOOOOOlS(0f^OOOOOOOOOOOOOOOOO0> 

oooo»-»-o^r^oo»-«-»-'-CMOi/)ooooinoocj>c7)Ooooooo> 


CM  CM  rs.  Cti  CM  < 


•  CM  en  CM  CM  CM  CM  CM  CM  CM        •- lO  U5  tf>  CO 


CMCMCMCMCOCMCMCMCMCMCMCMCMCMCMCMCMlrt^'^^'^^'^tnCMCMCMCMlrtCMCMCM 


re  3 

il 
111 

III 

^  in  ^  _ 

■?«■§,?£  sii 

'«'S-S-2*->.5f 
■pS-g-c  e-e  X  o 

$155  o  X  S  pje 
s>.2  >■ 


re  in 
-•      1.2 


o«e=s 


^c  re  re 

III  I 

«  X  i  ™  ^ 
E|r  >.|5 


8.».i2 


re 

in 

^  "  l:c  re 

-Ei"- 
3  c^ 
_  -5     _ 
rejD  o  E  E 

9  IS  o  19  9  O  '^ 

re  re  re  re  re  re  "u 

c  c  c  c  c  c  5 

£££  o 0£  t 

3   3  3   333   « 


cO-E  «»'"'"'""' 


|>|S|J.«.§§||rere|rere|||||||j| 
j^  o  ^  .0  Q  o'  o*  0  -^-g^  Q.  Q.  a  Q.  a5>.opooppnj 
•rt?>»>Kl5<?2oooo  ooo.o«©®<i)<i><c>; 


0600    bob   *".  OCDCP®®CD<D/^ 


^■>.t3^^Q.Q.  Q.  a.S.  aO.  Q.  Q.Q.jn   =r^^- 


y 
•E-; 
.£  re  <;  - 
re  c »-  c 

■o  §  o  I 
'>.'''•=■ 

o|£C 

Q-  <"  _  , 
00:5:^ 


Se^ 
E  i  o 

•?  Pj: 

CiE  • 
^  re5 


■g  -g  o 
E  E  ™ 
ra  ra  y 

6660606000 


3  _3  _3  _3  ^  ^  ^ 

o  o  o  o  o  o  E 
in  in  en  I/)  I/)  ■* 


OOOOO 


D-45 


Appendix  D 


^2 


co2 


ooooooooooooooo 
ooooooooooooooo 
opoppooopT-^pcor^ocn 

C\(CMCMC\ih-CJC\JC\IO)'-C5COC\JO>«3 
O  h-  »-  1-  1-  C\J 


OOOOOOO'-OOOOOO  oooooooooc^oooo 
OOOOCMOOOOOOOOO    OlOOOOOOCOOOOOOO 

pr^pp^poppppppp  pop'-pO'^-toinoooo 

oN-mcoo'^fO'-'-mirjioLno)  cD«-tv.f^o'^'-o>ooooooth~c\j 
m  CM      00  c\j  00  eo  Tt  Tj-  ■«»  c\j       >- c\(  cm  ^  oj  ri- cm  •^  c\i  oj  cm  »- 


o  o> 


c  c 


2¥ 

«  _  CD 

lis 

c  ®  « 

„      rate 

^  fc   (B  o  N 

«  i  £  £  % 
§2882 

d  >"o"d  § 

:  c  c  c  c  c 
9  o  ®  ®  ®  o 
.Q.Q.Q.CLQ. 


2  2 

«2 


c£ 

(D   m 

-^  C 
<n   C 

o'£ 
2=- 

■ —  >. 
c^ 
ra  (0 

?5 
2  = 
c  — 
7Z 
«>■=■»• 


flip's  o  c^-£~ 
■g^ooooog'Eti.g 

O  '^  '^  '^  '^  '^  9   *  ^  O 

o  -^  -^  -^  -^  -^  ■>.°-    -  E 
B^?-^^^£inZ  E 


ra  (0  ra  ra  ra  ra  ra  ^  Z  "gj*  ra 
c  c  c  c  c  c  c    -2"o  c 

CLQ.Q.Q.CLCLQ.  T-'Z       Q. 


ra  a 


ra  t  c  ra 
•p  «  «^ 

e'W  « 
Q.  '^  Tt-  Q. 
c  CvJ  cm"  T^ 


E2 


E  5  • 


59| 

l^e  - 

2  *<  — 

?^°i 

5  Vq.c 


ra       o 
^  S;  ™ 

2-T3 


e£ 


5i  o  2 

oo  "  ° 
'■-  *".  o"  « 

<?>«»^  d 

cncri  Jg  g. 
=  .=  <»  « 

X  X  y  y  !2 


o.o 

■tf-tf  O  o  » 
ra  ra  s  fe  "- 

ra  ra  -p  "o  o  - 
^  ^  ©  a  ^ 
ZZmnm 
2  «■©■©  o- 


c  c  ff 
"^^  w  «,  2  2  "o  ■©  "o 

m^ra^oo-o-o? 


»  ©  e 

§.£.£« 

=  X  J^  c 
ra  o  o  Q) 

c  S  S  c 
•  ^  •=  © 

COQ.Q.T-CMQ.Q.Q.   OcM  o  0.0.0- Q-Q.  Q.  coco' Q.Q-Q. 


■    ,,*r  ©  ©  ©  ©  ©^_^.  ©  ©  © 


=  «  5 
<n  (o  ra 

Q.       -- 


r^  o  o  o 

o)  ir>  o  o 

•^  Or-  p 

i/icoco  o> 

C\J<0(C  (C 


'.-  ^   T-  o 


0000000000000 
ouiooooooooooo 
pocooqr--.CMOir)p^oo»- 
CMuS»-^iniflco<j>«-^tb<Dir)'«»'«t 
i^»-mTrt^<ooooor~coco 
cM'-'Vr--cMco»-co'»^eM 


r^  o)  o  CM  CO 

^CMCM 


o  p  w  ^ 
S  Q-raV 

EE  Ei: 

EEEg; 

---9-i 

o  o  oC^ 

X   X   x»— 

000- 


o 

00 


25  = 
"  0  2    •  " 


o  ra 

sills'^ 


:525 
2s  2  • 

©"■6  c£ 

S9e« 

OZ  «'i 

£ESS' 
S|2^ 


i^g  « 


M   E 

*-  "P  ra 


O   O-T) 


es- 


CM. 


.s.a.s;  13 


■ — :rar> 


5  -g  .c*  1  2  2  2  c  JJ  2  c  To 

«c©©rajc.CQjS.9  y  "S 

■'^■-^'^TJ'SoO.cooora 

J^  -e  c  ©  E  .£  2  y 

^  2  ^.9--s-io^  8  89  s?|-S,S  g-g-ll 

~>'>»»»«'V*-r'x»-xxxra 

OOOo. 


■5c^  5^E  E">.;i^ 
t  -=  ^  r*^  ^ 


_  *'*  O  O  O  « 

©  ©  'o I 

E  E  "  o 

©  ©  :=   C 


coOOOO  ciOOO-^ZZO 


jc  je  O  © 
EEEf 

(0  (Q  nf  fl) 
0.0.  0.0. 


-O      ■  jc.     ° 

.c  •  oO( 
2  ©  <o  <»■ 
i  E.C.9. 

c  5o  ra  ra 


!,9cJd-5 

-  to  <D  01^  :^ 
)OOCJ  <»  3 

r  to"  to  w"  "m  _r 

;.g.g.g  is 

1  ra  ra  ra  o  3 
i  to  ra  ra°re  E 
.Cl.a.CL  S  e 
:  c  c  CO.Q. 


CM  «=:  w 
■   g«>. 

2 .2  2  « 
ra  .y  ©  ra 


ra  ra  ra  I 

y.y.y.y  „ 

„  c  c  c  c  • 
c  o)  o>  5)  o>Q 
Tj  j5  J5  J5  ^  E 
O.Q.Q.O.aQ. 


D-^6 


Synthetic  Organic  Chemicals.  1990 


W2 


8om88SS°88o8S8So°cjooS"ooifiOoqqooqq;Dir>qqqa!qocsq^.ifi-ptf3 
'^'^i^'^co  Ji^i^rJrj^coCTn      nco  CO  n  »-co  coco  coconcor^  r-non '"^  "  J2      co  co  i^ '- »- co  co  >- t  ■* 


*:^ 


<0S 


^    ^    ^    ^X"-C    C  -C  -^    r-  ■*-    f    r- 

«  a  «  OQ-Q-  «Q.Q.n-Q.£n    w  w 

q.q.q.q.'vcmq.  E  E  o  E  a. 0.0. o. 


-OQ.Q.Z 


OQ.O.cti'rgO.  6  Q.Q.Q.oZ'-Q-O-Q-Q-co'T'-Q.mQ-Q.Z'-Q.OL 


ooooooooooooocooooooooooootoooqo 
oooooooooooooooooooooorvjoopootgo 
ooooooooooooO'-qo^  qqqqqqqqN.q^<T>c\j 
ujfv:c\iaJo>0'-^c\Jtfic\iebo>^ob'n<xJir)C\iu)oicJ<-"»'-obootoo>ing) 
<DcDoo<ocoh»f^r^a>oinifioo>ir)oocMOO      (jxjimcomcDoocvjO) 

C>j  cvi »- 1 1- »- CM  l~--       h-T-»-       CM  cvj  r»  CM  r-- CVJ  •- CM  •- cj 


OCMOOOOOOOO 

oooooooooo 

OOOOOOUJCOOIOO 


•*CMCMCMCMCMfO»-«- 


ncococococo«omiftr. 

••-OOOOOO'-'-O 


in  o  o  o  o  o 
CM  o  in  o  o  o 
o  o  t»-.  q  q  q 
<b  in  o>  CO  O)  ih 

»0  CM  C7)  CM  •^^  1^ 
»-   CM  T  in 


«  »  u  «  ■  S 

JO  (TJ  -^  fO 

2o?2S»«  eg 
re5|<S3w«g    .- 
^  p  E  E^  >-S  o«  • 

»">-r~-.z>3|E 


E 
2 

■§ 

v> 

2  2 

-8-8 

c  c 

O   9 


■o  a 

c  •- 

(0   « 


re  re 
<n  (0 


red 

E  E' 

2  .$ 
99 


m  J2  jr  ^         re   © 

"2  2  relS  »-5S£ 

rS»-£— >;  =  rere 
re5<»<»o.Cyy 

o'o'o'o'o'o'o'o 
cccccccc 


E  E 

29  _^ 

■«'"«'  ^^  i"  re  re  Q. 

To  re 


||5 


o  n 

«   <B- 

.2  c 


>■«  ° 


2  o 

>•  re  re 
Q  ™  o  £  S 

>v  >»  9  ^  a  ^i- 
c  c  Q.™     .Xo  <rt 


O  O 

c  c 
a  e 


|i 

2  °-B.«2'o 
4;  •  re  o  re  re 

o  o  o  S  ?  9 


O) 


C    C 

CM  re  re 


2^e£ 

re  >-.ir 

-   •    3    C  ' 
UJS  n  E, 


•t  o 


JCM-S 


O   O   O 

c  c  c  c  c  c 


^j:^.c£.c.c.cx:.c£jCjCjCjC 


Q.a.cMa.Q.a.cMQ-  cIlq- a. a. o. o. o. a. cl o. a. o. o. a. Q. a. Q. a. o. 


JZ  JC  £  'V  ~£ 

0.0.0. '—      o. 


5  !5  =  2 

re  ^i  :5"  ?  -  >,  o  =^^  _  Q, 
.y.ii.areEco~c>'<n» 

■£•££•£  ^£  >--"q.-c  — 2-S 
cccga»£®>.cDa:  >.  E 
>*>»^nio  wO)  w?  O  ""^  *5  .— 

<«  «  "  "-S-S  "o  g  5  >•?  >< 

— ■— "— "xxcXcS—  S£^ 
0. 0.  0.  O.  O.  CM  O.  CM  CO      O.  EQ. 


1^ 

2  >s 

c  c 

O   9 

0.0. 


EM7 


Appendix  D 


^■Z 


cos 


1^ 
*:S 


502 


oooooooooooooooooooooiocnooooooooO'-oooooooooooooo 

OOOOOOOOOC£)OOOOOOOOCDOLO^*^OOOOOOOOOCNJOOOOOOOOOOOOOO 
OOOOOOOOOCMOOOOOOOO'-'-CVJOOOpOOOOOOOOOOOOO'-CVJCO^OOOOO 

c>irir-^ooo)OC\ico^^ir)oio»-ci'»io<buSuSir)<btbo>odc)o>c>'-tDr~~0)Ocj'ti^ 


ooooooooooooooooooooooooooooooooooooooooooooooo 


0.(1.0. 


._< 

^0. 


W  »-  CMCVJ 
C   C   C   C 

S  «  «  o 

P     9     Q    Q) 

0DOOOC3OO 


^  ^  t^  CO  T-  CO  o 


CO  m  »£)  r~  ■*  <o  00  «o  o>  c -s, 

OtO  C..-Cgirt«-»-»-'-rOCOCT^'TO:= 


p  fc.3  (0  F 
3.2  c  0)i 

cOoSc „_ 

•onsiSniramSw 
J3UotE.OOOE.O 


E  e  ip- 

2  2  o>3 
o  o  c  z 

S3e5 


■^CMCO^'-CJ'-CM'- 


n^t>»»-eMroT-oo»-oo 


^^_ 22225222222iS«'S"S?"S"S'S"S'S'S'S'S'S«'S« 

c3c56  o>6ddddddo6doo  ocrcrazccQccccrcECEcrcrcrcEcra: 


GO  00  00  0> 

•0-DT3-0 
9   O   O   O 


Ol  CMCVJ  CO 

't  in  ift  in 
■o-o-o-o 
a>  o  o  o 
CCCEQCCr 


ccccccccccccccccccccccccccccccccccccccccccccccc 
EEEEEEEElEEEEEEEEEEEEilEEEEEEEEEEiEEEEEEEEEEEEE 

Q.bLa.Q.Q.O.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.Q.irirQ.Q.Q.Q.Q.Q.Q.Q.Q^ 


OOOOOCMOOO 

oQoomoooo 
ooa>oo>tnopo 
»-^»-^5'«)in''-^«jinco 

^'— C0fl0OC0*-O»- 


OOOOOOOOOOOOO  O   O  OOOOOr-OOOOO   O   O   O   O  000'-C\JO 
OOOOOOOQOOOOO   O    O   OOOOOOOOOOO    ^   C\J   CO    •-   C\JOO(0<00 

ppqppoooppcoqo  o  o  o^opppooooo  o  o  o  o  oooooo 
2'o?co<pinop»7CNi'rfyr?'0^  to  r^'  flpen»r«PtVtP^o>c>cvi.r-'  cri  co  co  i-  ^cboipp^' 


I 


E 
IP 

:2|i- 

>^|-E 


S  tt 


^8 


IP 

_  -go  •  £  ^  Q  <o 

■D'S    ••rccOO£io 

.2  Qi^,M-^i.«  «  S  * 


Q  "■•  n  o  o  »  «  S.«£ 
^•Oio3PP-a-o— ,00 


?  o  P.o  yo"^ 


000^  fei.  O  O  O  O  X 
.c  .c  jc  ^r   '     •  .c  .c  x:  .c 
Q.Q.a.rgZZQ.Q.Q.QL 


I& 


o.  a.  ,s  a.  u 

CO  '<«'Q.COQ. 


«— .     ~< 

t-'SiS  «  o  a  <B 
™  «  .2 .2 .2 .2 
T}  CO  ^  CD  (Q  CD  CO 
C  ._»..»..__  „ 
n  c  c  c  c  c  c 

^  E  E  E  E  E  E 

U  Ql  5^  0>  Q)  Q>  ^ 
0.0.0.0.0.0.0. 


-.^  E  E 

E  "     " 


E  E 


<■  E  £  £  £  5 


■s  a 

in  liri  ijri 


(0 

m 
CO'  •^' 
liri  in  o>  m  •-  c\j  £ 

»-  »-  »-CMCO  <o  o 
O    <D   O   Q>  <&   O   ffl 

^  .2  2.2.2.2^ 
CD  CD  CD  CD  CD  CD  JO 


E  E  E 
o>  o>  o> 
0.  0.  0. 


c  c  c  c  c  c  c 
E  I  I  ^  I  I  I 
O)  ^  ^  ^  ^  ^  2> 
0.  0.0.0.0.0.0. 


D-48 


Synthetic  Organic  Chemicals.  1990 


«:S 


we 


we 


C\JCO'.__ ___„„„„ 

cotf)(0(o<£)r--.oooc\ji/)oqc>  o  o  looo^cvjcviooooooocomooooooincsjrvjoinooooo 

;b«o<b»-<b'-^oo«o«o«b<b  r^l  ob  o>o^»-^o>tTiiotot^O)i/50obc\Jc>c6r>^<bc>o^i/JuicnuS^~^oboocri 

»-   »-»-»-{ncneoeo  co  co  cT^^'»^»-Cijcgc>ie\jc\noooirt'>-r)£\ic\jcM«>t^roe\j'-oocvjc\jr~-r)c\j 


oooooooo 


•  O  O  O  O  O  O  O  O  O  O  O  O  O  O '-'-•-  o  o  •-•- ^  •- ^  ^  •-  ■^ 


•"TO)  * 


cccccccc^ 
EEEEEEEEn 
OL  Q.  Q.  Q.  d.  Q.  a.  Q.  i£ 


o 

"o  Sl- 
oe o>  o 


_  S25 
5  «  >. 
£  E  o 
o  ^i5 

"ra  Q.  o. 
-  o  9 

e™s 

9  7^  ■ 


^  c 

»  « 

~*£ 
9  </>  o 
«  ®  E 

O    E    y 

:2  "o.s 


■5->,s™«  —  —  —  —  =  -^  >.■>.  9 

jc  >  ^^  '^  ^^  (Q  re  re  re  <Q  (0  <-^-_.-  #) 
re  -^  c  (fl  F"^^^^^^^^^ 
,2Q.rere^oooooooo^ 
a.rMQ.Q.Q.a.Q.CLQ.a.Q.Q.a 


t^ooooooooo<ot>-oi/>ooooooc\j<Dt^<j>o^m»-ooooooo'}'00o>o>oooooooom 

-         -     —     -     -     -         -  ~)0000»-CM'*000000000(DOC\J«OOOQOOO(0<0 

IC\iCMfViC\ja>C\IC\iOOOOOOOOO'-C\JC\J'^0000000^^ 


iobobobcb^o6cbh^GOcooodoo>o)ctcto)o>o>o>o) 


0.0. 


o  .1  :?-^*  s--L* 


8  ".  ?; 


g>S» 


3Q.Q.3Q.Q.3 


id.  <» 


CM  r5^  r^  o  m 


•  OPO'^'-f5^c\jfM^^«o«>r-.f^oD<Dooooo»-eM5tc5e'-'-'-nt^t^'«»-f^Jp>Jt^S  ^  ^  ^  ^  ^  ^  ^  _. 

ItDtOODOOOO^.-'.-'.-.-.-.-'.-.-^.-rviC'JCJCiJCNJCNICVJCJUSO'S'S'S-I'S'S'S'SITK'S;^—   *    *   *    *   *    *    *    * 


CCQC 


____________________________________  .^  _-  ^  v«  T*  v«  w.  •-^^o^^^^^^^^^  COOOOOOOO 

a:a:oca:a:cca:a:QCQ:a:a:cra:QC(rtrtrcccc(rcra:cEtr$>>i>>>i>>>>>>  >>-)->->>>->•>- 


cccccccccccccccccccccccccccccccccccccccccccccccc 

S?*B*C^2^&^CPC^S^S^C*S^9^C^C^S'S'S^2^ff^2^C^S^2^S*2^2^C*Q^2'C*2^2^S^2^2^2*2*2^2*C^2*?^^?^2*^2^2^ 
Q.Q.Q.Q.Q.d.Q.Q.Q.d.Q.Q.d.Q.Q.Q.Q.d.Q.d.Q.d.Q.Q.i:Ld.ixa(:LQ.Q.Q.d.Q.iXai:Li^ 


D-49 


Appendix  D 


*:< 


<OS 


*:2 


W^ 


•^inOCNlOO'iJT^ 

^  ■^'  ^'  •^  ui  tfi  ^'  ■«' 
GO  CO  ^  CD  ^  r^  ^  00 


O  O  O  O  O  O 

o  o  o  »-  o  o 
q  q  lo  inr^.  o 
■^  "-^  h-'  in  uS  00 
00  O)  r^  GO  00  r^ 

CO  (O  (O  CO  (O  CO 


ooooooooooooooooo 
r^ooiDooomococDoooooo 
o>qqc\jc\jqqc\io)--a)OOooc>jo 
cvioiodd'-^CNJcJuScvifvir-icTicocorocJ 

(Or^00C0G0G000C000COCDG0G0C7)CDC0^ 

r^cocccocococococov-r^cococococo^ 


qooir>oooococ\j 
'-^codojcdcbt^'t^'^ 

f^0>OC7>0)0>0>00^*~ 
^  CO        CO  CD  CD  CO  ■•-•>- ■t 


CO     CM     c\j  rvj  cvj  in  CM  c\j  u)  c\j      cm  c\j  c\j  cm  cm  cm      cm  cm  c\j  cm  cm  cm  cm  cm  cm  in  cm  cm  cm  cm  cm  cm  •^j-      ■^ 'j- oo  cm  cm  cm  cm  in  in  m 


<n  o 
:5t5 
o  c 
ra  ra 


3   3 

c  c 
o  o 


TJTJ 


«  « 

c  c 


r      «    ■  a,    ■  p  o 

o  *  >.<»  re  o-rO 

«  2£  re  (5  (5  2  !2 

to  =  ?5  ®==  «  « 


OQQOOpOO 

oooooooo 
cccccccc 


__  « 

•5:5 


X  js'o'5 


"o  re  to  CO 
u)  o  ®  e 
52  o  o  o 
»  c  c  c 

TnOOO 

«  E  E  E 


™  c 

=  ? 

re  c_ 

o  o 

c  c 

o  o 

E  E 


Sl^^^^C^C 


oooooooo 

0.0.0.0.0.0.0.0. 


o  Q  g  o  o  o 

U   O   O   CJ   U   (J 

>.^_>s^_>.^ 

O)  o>  O)  o>  O)  o> 

c  c  c  c  c  c 

^  ">>">.">.■>.">»  "3^ 
^££££^^ 

000000 

o.  0.0.  0.0.0. 


2  a> 
"  re  • 

™  o  £  re  ©    •  ^ 

C6  "  o>2^  -s  ^ 
■s •  -  c  2*0  22s 
S^rerecreret) 

■5re(»<»o*-s*    

§SooooS|S9«§^g«£ 
EEEEEEESoO.S«*S2 


o 

i?  CO  en 

•5:3:2 

j:  o  o 

S  re  re 

o  o  S 
o  — S 
R  <o  re 


5  •.>->.  re  ■= 
q  0)  9  o  ^  iS 
"5s  to  to  «)  o  2 
X  .5 .5 ,5  ^  "^ 


^.  o 

4>  Q, 


81^ 


(b55    "oS  2-^S  ? 

lUlre^.-SSl-o*. 

oooooooooooopoo<i)nJ3aca.recn6o«co 

^^^  >-^  >>^^^^^^^^^-=  -S 'V   ^mtn^OO^SO- 
C7>CnC7IO)0)CJ)C3)0>C3)C3)O)0)C71O)  C3).E  g^  >.2  "'-SoEESo^ 

ccccccccccccccccc2cc'o'o'o'Oio"<o^ 

O)  >,>s>K>.>.>.>.>.>K>.>s>.>s>.>.>s  >c?   >>>-cjoocjooS 

re££-££££££-££-£-££-£-£-£'£'9££  ^^^^^^  « 

—   94>0®(D(l>0®CI)<]>®Q>®CI>CD<D(D^®®Q)0>Q)0)0  0>^ 

ooooooooooooooooo'~ooooooooo 

O.  Q.  O.  0.  O.  O.  O.  O.  O.  0.  0.  0.  0.  0.  CL  D.  O.       0.0.0.0.0.0.0.0.0. 


000000000000000 
ooooooooinoinoooQ 
ooooooomor^^oo'^o 
iri'VcO'^uS^cbr-ioicO'-^rv.'rNlcricr) 

CMC0*-O>COCOC0*"»-C*)^00C)»— 

v^      CO  ^  CM^  ■*  r^  CO'*      ^* 


0000000000000000000000000000000 
ooooocMOOoO'-oooooinoocoomcDinoooooooo 
cooooooooocMCMOoqq'*oq'*N;OOinh~;oqcqioqqqq 
co^duScDdoooioio>oit^o6o>dcMdcM'*'cOcoc\it--:cMc\iinc3cj)«-''r^c\i 

.-^-•.-^-GOCOCMCOCM'-'-'-COfOt^COfOT-COCOCO'-OOCDCDCOOOCOeOCOin 

■,-      r^t^      ^  ^  »- r^  CO  h«  »- r.  r-.  •»»••- CO  »- •- 


^^O^^CO^CMCMCVJUi'^^CMOO        OOOOOCMOOflO^flOCMCMOM-'^nCMOOOOCMCMflOOOinCMCMCMinCOininT- 
.-^^^T-^^^i-T-^v-r-i-O        •r-^0»-000«-0»-'-'-'-'-'-'-00»-»-00'-'-''-«-'-0»-»-'- 


»  J^  «  >.-D  -0-5  re  re  f  E 
=  CJ  «  '^  £  ^  ^-tn  -^  P  "> 

:2  E  -,  -2  a  o  o>  <»  a.^  o  2  5. 

"as  S-=  cc  e  c  q,  <B  <B  2 

5^  o  £•  &-  ^  £-  £~  e-  ir^.5-a  I  I 
^-.  orererererererererererere 

000000000000 
O.0.O.Q.0.O.a.Q.0.O.Q.O.C 


"■§. 

a  v)  u 
c  9  re 

°il 

2  re.y 

o  •S're 
=  -0  o 
2  O  £ 


re  A  aCD 


—   CO-. 

3  c 

oT  9 
c  c 
a  « 
■6t3 
re  re 
3  B 


re.c  " 

£   CO   t 


TJ  c 
re  « 
S3 

J3.0 


_re 

>> 

X    « 

9  Q- 

So 

C  "— 

«>  Q-S 
■>.>.2 

J£  J£    Q. 

-.  -  „  re  re  0 
•  *  «  P  p  3  9  2 

^2^£-e -e -e  5  s; 

333rerere.ccii 

.O^JOUUCJUT) 


"I 

Es:. 

3    X 


O-D 
1^ 

reCi, 
">.o.g 

E  ><c  c 


rejo 


3  « 

5  CO 

re  c 

CO  3 

10"  co" 


£    >,  Jr    CO    10 

re  E  H22 
2.2. 5.0  % 


8L| 

i=  "S  o .«  re 
TS  re  Q-i:  >. 


a,  (B 


•45    •  - 
^s  ^  • 

•  5  •  g 

rg  O  •£ 

1181- 

*  E  •? 
X  CO  >.t: 

9  <"  =  o      

5_»T>oO      'J3-D 
-^—  x^'opO 

-^:£  2.  =  -^-^-^ 
cAooogoicno) 
StaEQ.caaia 
i:'5.^>,*  c  c  c 

t!  X  X  X  S  •  *  * 

a)000>.>>>.>. 


8. 


35 


C  JO 

E.Q^ 

^    ^    WW    w    w    KX    W  -^    W    W    W 


D-50 


Synthetic  Organic  Chemicals,  1990 


*:2 


co2 


ll 


«)S 


q  o  LO  o  <D  t 
c\j  uS  ui  CO  in  r~^ 

O)  CO  CO  O)  <^  GO 


CO  o  o  o  o 
O  O  O)  CO  o 
IT)  'T  ■<»  CNJ  O 

r^  oi  in  f\i  ^' 
00  •-  ^  co<o 


i/>  CM  lo  m  cvj 


ooooooooooooooooooooooooooo 


CO  <o      <o  r^  (o 


*^ 

.e  t 

So 
1° 

ai 


■g:S 

2  ™ 


^ 


£.£      El 
flj  S  c  n>  j^ 

•    K    3    (»-C    >.>.^2    >. 

>.•  *  — ^  «  o  ni  >><» 

E'-ci.222>.,c05 
.  a  Q.  .  a  Q.  a-c  «  a^ 
>«  >-i-^i>  >•  >>  S  9>-= 
oooooooo 

0.0.0.0.0.0.0.  o. 


W^W     W     W      >.     w 

0)^0)0)0)0)0 
O   K   O   O   ®   9   O 

c  Q  c  c  c  c  c 
">.  2  ">.">.■>.■>.'>. 

0.0.0.0.0.0.0. 

2^22222 

O.  O  O.  O.  O.  O.  Q. 

o      o  o  o  o  o 

0.       0.0.0.0.0. 


>'2-S22Di;'K^22cccccccc.|5) 

.  o  a-y  Q.o.<rt2*®33>>>>>>>>ic2 

Jl^     >.0■>s>.>.>.>.>.>.>«>^>^>.>.>.>^>•>>>•ra 


ooooooooooooooooooo 

O.       0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.0.1 


6  »>■">.  E  *  £  £ 

§i:.c«3ott 
Ji   O  ^  CM   0>i5  CM  CM 

EEEEEEEE 


iAwi/ivttnviViin 


ooooooooooooooo 

00000(0000000000 


»-  »-         O        •-CM 


O  O  O 

to  dm 

•*  CM«0 


oom  o  or^oooq 
co«bco  CO  •*'r>^«-^oO'r^ 

(0U)<0    I/)    l/)'>-0><000 

r~      coT^POCO'^'- 


'^oocM      CM  «o  ifl  •*  >w  vo  m  mo 


<0        (O        0>  (S  <0  CO 


o       ^       —      ■•-      ^.-^o 


^  ^T3 
0)  o  c 


.  a  « 


ram  «  |-Si:i: 


Q.-0  -O 


(/)"  Jrt   X   o  E   m  ID 

5b2=too„      


«■•£  " 
o  °  • 


ooo-5i§§|:ts'5° 

BjnjBjnaaic  as  o  S 

u.u.u.u  «  =3  s.u.nI;;  „■ 

"S.'S.'S.'S.-E  o  o  o  5  »  «  « 
.c  .c  .c  ^.i  a  «  .i2  E  E  E  E 

.2->-.a-.a-.i->->-.i-.i-i-.2-.s 

oooooooooooo 
o.Q.ao.o.o.a.a.o.o.o.0. 


2«V   •   -88 
«  o  :     >'i. 

mS    •<So) 

JK.C   O  ^  «   m 

«  i  «  G.  E  Q.  -i,-2 

5  ^  >^!2  .2  •-■  S- a 
S  g  CD-P  •  2  p 

-D  :s  Q..|  •£"•"« 

UO.S"E>>iiicc 
o  o  "•?■»£  >.>. 
^t-S  •£  E  •  c5 

IllJltll 

9   O    9      -  tZ    9   c    c 

E  E  E:i.fl5  E  E.E. 

oooo—ooo 
Q.o.o.a     0.0.0. 


>■? 


;  Eo 
'  o  o 

0.0. 


$«o^ 

<" « «"  s  •£ 

«>    «■>.?  r5  •  ? 

J  J  :^  •  >.  >.«H 

•    «  0  J£  *  *  T 

O      Q  ^*  flJ     (fl    (0    ^, 

T  r  o)  ><>•>•  jT 
r  r  o  o  o  o-H. 

o  o  o  o  o  o  o 
0.  Q.o.o.o.o.a 


i  E 


.t  in 
E  " 

a   - 


O.  ID  CM 


liE^ 

c    c  ^   c 
ra   R)  5   R>  m 

pg  cy  ? 


"  ^  t;  -^ 


™    O      -CD    O    O 
CM   •   fM   *    ™   c  ^"O 

>»i    >•>■>•>,>.  <B 
o   ^  o  o  o^  o  >• 

0.       0.      0.      0. 


x"  C  „- 

S.E5 


e  «  w 
c  c  5 

*    «Q. 

>.  >.• 

.  X     X  .C 

00a 

000 
a.ao. 


D-51 


Appendix  D 


h 


«:^ 


«oi 


OCOTOOOOICDCOIT) 

c\i  o  o  c\i      o '-'-'- r^ 


coioioc^cjinminuicg 


in  oooooooooocnooooooooooococnooooooo 

r-  oooooooooo»-ooooooooooooiDOoaioooo 

Tj-  T}-mi/)oooooooooooooot^ooooooooa>opoc\j 

CO  CO^— •— C\J^^0^0>C0CDC*^OO'— ^^COCDOOCOf^r^OOCO'-O^OOCOOl 

■r-  •-'-•- CO  »- CO    c\j  00  CM  »- •-   t»)  c^  OS »- CO  CO  o  n  CO  cn  CO  00  »- n  CO  CO  r^ 


£  2  i  2 


^  o 


_  ™ 

to     A 

ag  2 

ll  2  Pt 
on  5  ™'5  2, 

t^  S  ®  ^*  • 


^  j^  o -^^       O)  o>  o  o  o>  o> 
■^— ^-c-^c  c  c  c  c  c  c 

(o  c  £  CO  a!  1^  (^  (^  (^  IT  (^     ir 


Eo 
V) 


5. 
0  re  E 


>-i-s  is : 


«  9-     »Q-^  « 

■^•«="  xjs-fttreoo_-re 
iiM3)O)0reS»j275J«^ 

«»0«0.£>.>>0>.g^„ 

2  aaa&frE  2  a2  2 « 

Q.  2   g   g  g   go.  OL   go.   Q.  0 

0.0.0.0.0.  c  cQ.c\jc\ia. 


re  3  •" 
5-1  c 


.  a 


z 

m   ®  '  '£    ®~  ®~  "O 

■Stj     •  •  OTJ-O  c 

«  o  £  ®  re  o  o  9 


re  S  «  « 

v>  >.a.Q.' 
o  jc  o  a .! 

J2  c  o  o  < 
2=  -o  ■o•u 
*  «  D  3  3 

00*** 
^  ^  V)  in  V) 
0.0.0.0.0. 


>.2'S«co2c 

"rnTS   C      -r:  '^  JT  '? 


5^re  *  :5  g  E 
.2'-S  <»«i~.a.!i;.t    .Q."Oo7:rere 


o     1  S 

^  0)  o^ 
VT]   b   O 

cc  >.T       - 
5^re  *  :5  g  E 


-  •  *  .5>  c  i  S  T>  >.  E  re 
■D.esc.c:oT2oolEt'-  CO* 

O.O.corMO.CMCvjQ.O.CM'O.rg'VO.O 


F 

s: 

E 

0 

re 

^ 

re 

re 

c 

U 

re 

-1 

>• 

0 

00  00000000000^000000000 

00  00  o  00  o  100  o  o  o  o  o 'J  o  00  o  o  o  o 

op  00  i/)(\jo  o<ot^  o  o  o  o  o  000  ^  00  o  o  in 

itjn;  '«'ob'>-^rN:^'oo>o>'«uStf>(bd'-^ooo>(br^abro 

cvjflo  r^ <o  «o r^  t^  •- m  10  (o  «o  <D  »- en  e\j  •<»  CO r^  00  00  00  »- 

r^co  r*  t^  •- cj  t>»  CO  CO  lo  CO  to  1^  ^      r^cocsj^^^^ 


00000000000000000000000 
cooooooooooooooinooooooooo 
CNioooooooooomor^ooomooomcM 
r>;o>^c\ic^^'cNi<\io>coc>d'V>^<dci^^'<3ot><r-^oo^ 
t^o>oooooor^coi^<oio^-ooa>»-»-floi/)«DOtOflo 
^coi^t^r*     00  m  r^  ift 'J- ■^  CO  •- •«•  f^  CO  o  00  CO  ■<» 


CMCMCMCMCUf^l/imtftlrtmirtCOI/l' 


a  %  e  S 
"  E  "•  c 
>*J=^  re 
57  =  o 

«'zl-^225i' 

3;- e  -*oreooSc 

^  E  ''r.  E  2  o  o  o  ~ 

a,  a,  «,t^  E  rejo  E  E  E5  „ 

•S.e.S  •i'^o  o  o  g  °"D 


—     .2  *■© 


&, 


■g-5-g  2  2  ga.Q.Q.Q.  2  5.a5.1i.ii.8.8.a&Q. 
99&Q-'^°(^<cv<c^'Ck<'^925929959299 

0.0.0.»^t1       ^"^"^■^"  (io.  0.0.  0.0.  0.0.  0.0.  0.0.0. 


w  ?  re  j: 
c  *  ■ — ■ 

2o  -go 
re£  ••=  « 
•5  fl  E  E  E 
oi  E  —  JS 

0.0.0.2  S 
9  9  90.0. 
(£(^(£  c  o. 


D-52 


Synthetic  Organic  Chemicals.  1990 


U 


»-*-♦-»—  ^-OJOOOOOOOOO'-'-'-OOOOOO    00000>l/^<0000000000000  0000 

r-'^'^^'^^c\icr)<o<br-^<bN^oc>oc>o^ob<bc\io>o>c\ir~^^^'i'»-<x50uStbcvJi/i<rJo> 


p-  V—  V-  V^  ^ 

CCGCQCCC  ? 


«  a 


l.i.i 
ococa: 


.2  .2  .2 

(rcoc 


■S-2 

«  « 
>  > 

CO  « 
«   9 

(rcc 


5  _2  ^  _o  _o  _o 
.S  o  o  "o "« "3 
>■>■>>>■>■ 

.2.2.2.2.2.1 
T3t3tjt3T3T5 
nj  (Q  n}  to  (0  (1} 

ccccoc  (recce 


(S 

O  9 
«©  >. 

=  = 

>  >sr 

II.I.C 
ra  (0  n  c 

O  9  O  9 
OC  CCCCOC 


.2.2.1 
T3t3t3 

CCCCOC 


E- 


n 


So 
o>c 

nj  (J 
E  « 

'—    i;  O  >  9  9 


O   O   O 
to   V)   10 


8|||| 

*T?  o  c  e 
oxQCccif  ix 


■ill 

9   0  = 
«  O  ™ 

■5  « 
?-^« 

■55 


in  ^ 

E 


in  Q  n 


^■Ri^ 


:Q.iS 

occro: 


S  0  = 

u.  to  ^ 
w"  to 

:5:2: 

c  c  c  c  c  c 


Oi: 

=  o 


«  6" 


c  c 
EE 


I/)    V) 

o  o 
OCOCt 


)  </>  in 
)  O  O 
IQCCC 


in  X 
O  O 
OCQC 


i.s.s  ._ 

Ie  ES£ 

i^g  g  ra  ®  E 

9099  S'X  "- 9 
c  E  Q.a>  g.g-D 
g  -  S  S  2  S  15  « 

iL'    9    9    9    Q.J3  ^  ^ 

n  £1  £i  £i  in  O  U'.= 
O3DDDrei0«J 
CC  CC  OC  QC  OC  O)  (O  (O 


000»-0000000000000000'-'-0>0)OOr^OOOO)OOOOOOCNJOO^«OOOOOOP50)^ 

OQOOOooomoooooooo<Mo^r>-ooo>oo»-^o»-oooooc\jr^h»ooooooooo^^o> 
oSooiflcvjooi^oooooooopoooq'^pqpppppppqpqqpqpqqqqpqpp 
ooe»)C)»-t^oiciic\Jo>CNico^'oio(\Jco'»'*'«b«)«b«><or<;o>o>o>ooocJ(r)''riht^ 


o  o  o  2 
mm^O 

9   O    9   O 
2  2  2.2 

TJtJtJC 
(Q  n  nj  (0 

<S   9   9   9 


_  S.  CD  00 
O<B<l)(I>(90>(f)<X>9(DA 

ccccccg'ccc  ^_: 

006060  oOOOoOC 

.2  .2  .2  .2  .2  .2  .2  .2  .2  ,2  .2  .2 
'Ct3t3T3tJoi3t3t5ot3'D 

(riricirtrirtLiriririrci: 


•^  c\j  n  ^  ■ 


•^  c\j  n 

T3  T3  T3 

CCOCOC 

.2  .2  2 

13  t)  o 

(T  crir 


(Tcrcr 

.2  .2  .2 
t3t3T3 

oicco: 


D-53 


Appendix  D 


u 


«x 


l£ 


Vi^ 


OOOOOOOOOOOOOOOOOOOOOCDh^OOOOriinOOOOOOO'^CVJOOOlOOOOOCMOO 

ooooooooooooooooooooo'<*'«t'^oooc\inoooooo)00opvjc\ioooooir)oo 

oooooa>inooo^oo^^ir)oooooooooooooooooooO'-'-'^-^oooooooo 

c^io•v'^^odoioi<bo>coc^<boc\ioc>c^»-^ouir-^^-iK^-io■r^cjobobcn^'o 

~        *      ^     ■  m  IT)  IT)  ifi  in  in  c\i  cj  CM  CNj  CM  CM  n  CO  CO  CO  CO  CO  CO  CO  o  CO  CO  •*  •^  ■^  ■v  t 'it  r^ 

OOOOOOOOOOOOOOOOOOOOOOOOOOOOOO) 


:  :  :  :e 
:  :  :  :e 

...         3 


?»• 


•S  w- 
'  «  e ' 

•  >.N 

•  C   C 

■  a  « 

0.0 
&2 
<n  u 

E  E 

333333D33 


:=  «  «  • 


J2  5^??"  «2 


X.C  Q  Q  2  n  * 
o  Q.  Q.  a.  a.<n  <n 

E  E  E  E  E  E  E 


T3  TJ  TJ -D -O  T3  T3 
O  O  O  O  O  O   O 

wtowtowwcn 


"CD 
»  3 
<0   3 

cW 

5>a> 

as 

__3 

o  o 

WW 


o  o  o  o 


O'.-CMascn  2'^°'^® '^      «^ 

•COmtOOOOOCDOOOIOOOCMtM   >,'"  P>J  «^  «">  CO   9 

j^^^^^^cotvr>CMcococoir)ino)0>'-'-'-'-'--oc  £  =  =  £  c  o) 
iSJSJSiSJSJ52^^^.2^^.2^.2^^^^^^.2  o  o  g  g  g  2  ™ 

CO  OD  CO  CD  CD  CD  CD  CD  CD  CD  CD  CD  CD  CD  CD  CD  ffl  CD  CD  CD  CD  CD  .O  CD  CD  CD  CD  CD  O  O 
cccccccccccccccccccc'ccc'c'c'cc'c'c'c 

OOOOOOOOOOOOOOOOOOOOOOOOOOOOOO 

wwwwwwwwwwwwwwwwwwwwwwwwwwwwww 


CMOOOOOOOOOOOOOOOOOOOOOOOOOOOO 

ooooooooooooooooooooooooooooo 
u)ootncMOOoooooooooooooor--ooooooo 
>*ir)r-i^cj«Jej>^aJ'^C)'-^f^cooo>CMCM'^'-'cM«bobco>-^o>^c\Jr^ 

OOt/)«0(000000»-r^<D«0^t^CM'^0>(0'-CM«DIO>-OCOO'-'^CO 


o  o  o 
ooo 
^  oo 

r^csicj 


oooooooooooo 
oooooooooooo 
CMCgooqoqoinpqq 
i^CMsbT}''^'cMco'»»-'«tir>CMiri 


CM^mmmmiAtnmmcoiA 


—  °*-— 2  o  P  " 

WWWWWWWW 


lis 

E  "> 

1^ 

E  ,. 

E  E 

3   3 


15 


t 


'  £  P 


til 

>nX   3 


«^   _    C   "' 
1.1  Jl 


^   fli   c;  .C  .C 


«   CO   «   S^   N 

-i5-e-£:s 

£"  n>  »  c 
Q-O  E  T 
™  E  >'fV 

"     T     X  ^ 


e  10 
■Jo  25 
P  >• 

E  E 

3   3 
1 


"8  "8  "8  "8  "§52. 8  » ■§■§<£ 

WWWWW'^  WW'T- 


££  I  S J£ 

E  E  5- »  g  E 
>•  >•  S  >•  JS  >< 

X  x-6  -'^  ^  X  ai 

o  o  §  X  ^  o  <J 
E  E^5"EE 
.5.2  o^?.2.2 

WW 


9  « 

^g-g2i-§. 

>.>.o  P  a--5, 
•  ?  2  -S  ■o.>>  Q- 
™-9-9  3-£5  2 

«  O  O  >.  J- JO  p. 

g  a>  cBx:  Sop 

JJ  m  irt  ♦?   ?  ^^  is 


CO  S 
O  CO 

o  E 


EEEEEEEEE 

3333333   3    3 

WWWWWWWWW 


I>-54 


Synthetic  Organic  Chemicals,  1990 


U 


«oi 


ll 


<o* 


lO'-r^ooooO'-ooo 


mirtioirxDcoui'^ajTroioo 
o>0)0)Oio>mN-0'-0'-»-»- 


o o o o o o o o o o o o o o o o o o o o  oooooo 

(o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  I/)  o  a>  o  o  o  o  o 

CO  CO  o  o  o  o  o  •- ^  o  o  o  irt  o  lo  c\j  o  o>  c)  lO  CO  in  o  o  o  o 

r^  oi  rv  r~^  ui  ■*  c\i '-  ^  pj  iri  r~»  o  CO  •-  ■*  cri  CO  00  •«j-  -■—■-•—■-■.—• 


r^o>rs.r..(/5^c\l»-»-c\jmr»oco«-^cooDOD^ 
r-~^(orgco»-'-cococof^irt''»''*'*a)ir)oooO'- 


1-  uo  irt  If)  in  trt      i/> 


in  o 
o  o 
m  c\j 
in  ^ 
r-eo 
in  in 


<\l  m  CJ  CNJ  CM  Csl        C\J        <MC\J 


c  c  c 

J  >  J 

OOP 

coco  to 


li 

o  s 

=  T3 

ni  (0 

.  X 

.  <n  e 
"  r^  ®  X 
5  CO  5,-V 

S  J  Jcm" 

>  SkO 
^  ^  (0 
C    C    <j  

OOOOOQOO 
C/)  </5  CO  W  W  (O  </5  CO 


it 

'V)>  S  o  « 
^■^   X    "   « 

—  oJ£  ?>£ 
f^  (0  o  ® 


A    W    A  .S 

o5  o  « 

■=    (0-=   3 


CO  (Q  en  >, 

p£  o  2^  E 


n» 


>>c  ™  i  * 


«  n 
To  « 
«  » 
o  Tn 


o  o 

(0(« 


.9  .£  .2  .S  •=  «  c  c  E  in  (8  (0 '':  —  .£ 
SE^EtSsEE^-D-oo^pl 

.■2  «:5  •  a  §  «  «  o  «.^.^.-£'£  5  c€ 
a^a>J!«  =  =°^->>>oo|- 

o  O  —  J 

>.cB  >«B  g-g-S^o^g.®  §^§^§^§^-5^«2 
CO     (o     en  to  i2.^z  CO  CO  CO  en  w  CO  w  w  CO 


^  10 


E 
a. 3 

c  c 

2^E 
(0  ni  g 

«  •"  * 
2  c 


2      9-^2 
?  ffl  £  >*tr 


CO  'i 

?t3 


oai. 
^.E 

£1  n> 


nn 

:^  U  CM  Jc 

>.>•  >.Q. 
££  J=  P 


O^ 


0 

■0 

i8 

(0 

:|j 

•S 

•9 

. « 

c 

^ 

8 

• 

• 

c 

*  ^i^ 

E 
m 

.  0 

.  c 

1 

» 

:  fc 

8 

•-cQ'-  (0    .  >. 


-rO£££ 


pS.2.e.2.2  o 
o  t5  75  «  ™  fo  .£ 


O  9   O  Q. 
0000 

2  2. "2  2 
E  E  E  E 

(0   (0   (0   CQ 
CO   (0   (0   C3   (0 


0>^'^-'~'^-^—  (0 


2  flj  (0 

0.2.2 


re  o 
WW 


®  ®  ®  9 


2.2.2 
i  is  re  re 
)  a  o  o 

iwww 


re  <o  re  •r  fl 
2  C. 2  0.2 
<S  re  g 
55 


*  •-  « 


oooooor^r^oocoooooooooooo)CMmo>f^ooooo»-oooooooo<oooooooio«-in 

00000<Or^0100CMOOOOOOOO«D<Cr^l^t^OOOOO^OOCOOOOO»-000000<J>OCOCO 

ooooooooooooooooooo»-»-»-»-»-CMC\jooopoooopopooooooooO'-;»- 
obo■'-c^juSt^t^f^oboi^ojco^ai^ob»-c\jc^jc^jcjc^ic^ic^jc^jc^i^^nl'i«bt^orio)^>^c»m 
r^flOoooocooooooocDooo>o*OiOio»oo*~»-»-*-*-*"*"«— '-'-▼-'-•■'-^"•■'■ininmincocDcDcDf^r^r^r^f^h^ 

0>0>0)0)0)00>0>dO>000>0>0>0000000000000000000010>0)00>0>C)0>0>0>0>010>0> 

ooooooooSooooooooooooooooooooSoooooooooooooooooo 


n  r- c\4  CM  CO  CO  rv.  cj> -5'    .  ^  n  <o  00  cj>  cm  m 

ooooQOOOffl      co^cor^o>oo«-(0(0i0(or^r^ 

0)0)0)CJ>C7>C3»C3)0)  p)^  CM  CM  CM  CM  t  «> 

§  ^  re  re  re  re  re  re  l-g-g-g-g-g-g-g-S-g-g-S-S-g-g 

00000000  otrcctrcEcrccircEccDCCcccoccc 

ccccccccccccccccccccccc 

Aa}a)<|)a)AAAaA9900009Q>90000 


f^cgcNii?*—  —  ^  —  *-  —  ^  > 
"5  *  *  "^  i5  o  o  ^Q  ,Q .  2  o  "5 

©oca:  £t>b>  >b>b>i>>> 

■Hccccccccccc 
8(/5cococowc/5c8coc/5c/5co 


CO^CDCOOCMCOCDCMVO 

^•-«-co^^^inr^o»'- 

ccccccccccc 
c$5c55c/5(oc/)c^cncoc55c^eo 


>-> 

c  c 
o  • 

o  o 
coco 


D-55 


Appendix  D 


<o2 


«:< 


toS 


OIDIOCOOOP^^OOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO 
OOLDTIDUI'^OOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO 

oooooootniooininooocvjooooooooooooO'-uioooooo 


o  o  o  c\j  c\]  <\j  n 

>-  cJ  rr  Tj-  tt  •>*  ■^ 
O^  O^  O^  ^  0>  Oi  ^ 


^■or  E 

0)   9   O    >. 
C  -'  I     to 

c  a  a,  g,— 

*-»  -j^  -^  ~   o 
-OTJT3   iS 

>.>.  >.^ 

^-  JT    r-  ■^ 


<J  --2 


(ft  "O  o  ® 

—  p 

a.c 


I& 


(0  a  c  c  c  g 

-  C  (0  (0  (0  c 

S  o  o  a  o  >, 

«=  E  E  e  E  Si-"  o5* 
cccccccc.ccc  = 


l  =  .£»2^ 


<B   C   "!   « 


«  <s 

e  s 

u  u 
cow 


E  «  « 

1 « I 


s  "  -• 

c  5.  (ft 


:  >.  V)  (ft 
1  o  «;= 

JTJ  "D  "D 
<D    9   Q>    <D 


£   (0 
O   (ft 

EE 

T5.2 

-:^.. 

—  oo-^ 


0  «  ^ 

=  ^01 

"o^ 

(fl=  o 
(»  (0  = 
o>    .  (0 

m  (ft  . 
.n:  a  (ft 

C    C7>  0) 

—  m  o> 

01  jc  to 

111 


0)  ^ 

T3  ;5 


>£^  o  to-o 

«  *  *  :y  E  " 

"o  "o  "o  n  to  .y 
Goo  £.9 .9 
to  to  to  j=  o  u 

y.y.y  g-y  ^ 

C    C    C  .f    (ft   (ft 


(0   10   (0   '" 

O    O   O    Q.  Q.(j 
N  a  a  O  O  (0 

.2  2  2  2  S  o 

■C  O  O  O  O   F 
■5.S2.i23  3   - 

3    3    3WW .__  _  __ 

cocn</)inuiWW<oW'«tOT«     w     cow 


.y  y  .y  S"  3  3 

C    C    C  .f    (ft   (ft  . 

000300- 


5^"  »  2  e  « 

Si  S  o  o  o  ■Q 

pTj"g'x»-D  ■g" 
■"o'o'oo 
to  to  to  (0 
u  o  y  u 
c  c  c  'c 
o  o  o  "o 
0000 


to  to 
Sec 

E88 


33333333 


in  o  CM 
r^  IT)  00 

<0  CM  (O 


O  O  O  O  O  O  O  O  O  O  in  O  O  O  O        O  O  O  O  O  O  O  O  O  O  O  O    •<»  CO  o  o 
OOOOOOO0D(3)O00O'-OO         --- - 

inir)OOOOOh-rv.oqtv.cocot^c\j 
oiT— aooJo^^aooooooincooooo 

«D00«0«0I^C0O»-»-i-«-C0C0C000 

com  CO      ▼- CO  CO  CO  CO  o  ^^  h^  CO 


OOOmOOCOOOOOO    l/)'»OtD_    _ 


r^  in  ID  o  (/)  r^  •<»■  r^  r^      »- t  ■^  • 

^CMOinCMO)  CM        ^ 


o  o  ocn  n 
o  o  p  'J  '» 
'      000 


|CMCMCMCMCMCMO>CMCMCMCMincMCMCM      CMinincMininoxotcicocooo  coooocoooooooo 


E  o  o' 

«"  (0  to 
^  (ft  (ft 
(0  c  c 
(ft  •  a 
c-n-D 
o  c  c 

188 
8?? 

to  c  c  e 
•"'E  .5  .2 
fiS'S'S 

2  O  c  c 
c  £  a  a 

o  »>,>. 

E.2  «  5 

lOTJ^pTp 

:2:5':2:2 

0000 
to  to  to  (0 

y.y.y.y 


0^.5 


a  to 
•a  «« 

c  c 


18. 

2  £ 


C_'.3 


(0   C 
<"    3 

E^- 


a  (ft 
c  c 

E  £ 


TO  IS 
t»  "  " 

«.y.y 


wwww     www 


9  E 
:5  cm  15:2: 

o  ;;  o  o 
J^  .9  y  ^ 

to    m   to    to 

W  wi 


;    C  to 

'   3  <« 

;'«  E 

I  o  5 


9  ^ 


075  b  (ft  (ft^g  9>.">. 


s  05  = 

Q.  (ft   0)  ^   j- 


i]S -2 .2^1-50"  a  5. 


>'2 :2 

)  o  o 
)  to  to 

i.u.y 

)  So  to 
>  e  a 
)WW 


s:2 

o  o 
to  to 

y.u 

to  (0 
»  « 

WW 


>  ~zr  "^  "^  ^;  o  o  »-*-  **■ 

^2-i-Q-^^  o  o 

■     0000-DOO"0'S 


(J)  jO 

c  to  .2  to  to 
o  tr  "^  to  to 
3      >»2  is 

g    E     Q.  U5   ■(ft 

(0   (0   (0   (0   (0 

wwwww 


«  t»  Q 


< 
W    ^ 

»r  £ « 

o  o 


E  >.• 


?..£  £«?•■> 

„    t    M  *i     _      ' 


».  o  .£  ,_  -=^ 
6lS:S^^^l8 

•    _  -D   to  is   >.  >      -  • 

S  o    -~    -•-  t  i2  iM 

'^^tDQ)t])tD(l)mC 
.t;QCCCCCc$ 

c^oooaoec^ 

S   tOT3TJT3'-6^-5'>> 

>,—  to  <o  to  to  to  2  9 
^:  >-t;  ^  ■=:■=;  t;  Q. :» 


J£  £0   .a   to  T3  TJ  T)  ■■ 


•-  E  rg  T=  _  ^ 
■=  2  2  c  c  c 

.?  a.  o. «  tB  0) 
wwww WW 


D-56 


Synthetic  Organic  Chemicals.  1990 


^^ 


ooooooolooooooooooooooooooooooooooooooooo 
ocDOO'-O'-ooor^inoooooooonoouiooooooo'j-ooooooooo 
r~nTroor)c5c<HDiofooO'-i/)oir)t^coooo''rooinoooooooooooa>or^ 


c\j      '-'-•- m  in  i/i '- in      »-»-»- «5 «- co  p5  cj »- m  m  m 


r^TTCOCOCO'^        ■«»■<»  CO -"T  C\J  CM  TT 


ID  o  in  o  c\|  o  o 
r^  id  rri  rri  d  in  o 
00  CO  r^  in  CO  O)  00 
in  CO  CO  'T  CO  c\j  •- 


c\jc\jininu)(\ic\jc\jinc\ic\iiAinincNiiAC\j(\ic\jin(vieviryjc\ic\irvjc\j(\jcac\ic\ic\jc\jc\jcNjc\jc\jininc\j      cvjcjrginincMin 


1^ 


W2 


■81 


^^   11 


:t^  m 

"Cij'.-^ 


R)  o 


? 


-    -^ 


«  ^  ™ 

o  "   "  E«£ 
~  Q  o  5.^  • 

crt  tn  V)  «  w  — 
"O  *0  T)  "2  "D 
oCDoG 

(Q    R)    ni   (0   (0  Q 

_<5  jj  JO  «  <o  ^  g 


o  o  o 


o'o'o  o'o  ° 
|«  ^  [n  is  is  t^  i2 


■5  5T3-5 
W   TO*   C 

>.o  o  « 

—  -Coo 

^?--^-= 

™  c 

V    «    ?    <0 

o'Soo 


I' 
E  o 


2  •  ^ 


w  CO 


c  E 
(0  <2 

E£ 


•o  ® 
«>• 

5S8. 


I 


*-£ 


Eo 


«  0£  . 


>   (A   (A 


io-I 


5S| 
8^5 


E  o  E  E  E  E 

flj  -x^  nj  (TJ  5  5 

C   oT3  TJ  ^  T3 

m  ^  a>  <»  *  a> 
2  Q.  c  c  c  c 

,  0  "O  _o  ^  _®  _® 
■^  o  >.>.>.>. 

a  E  ■£  £  £  £ 

O   P   O   9    CD   <P 

Q.T  E  E  E  E 


EEES-^S-S-S-S 

(0  (Q  ni   >«>.>«>.>«>., 
;=^;^>^>  j£  J£  j^  j^  -3^  _s^    < 


o  o 


'    ^  ^^  ^  ^  ^  ^  ^ 

^Je  J£  J£  ^  ^  J£  * 

'•mnjfljmcTjniiS 

S  S  S  3  S  S  E 

.(0  ffl  n  .nj  ,<o  ,10  5 
'-'-'-'-'- "-.2 


E   TO 

E  ® 

fO  c 


22E 
a>  J5  TO 

o  «  S 
S. 9  CO  CO 
EE  A- 

(0  flj  »-    I 

$  S  S"  9 

^  55  TO 


"5.E 
".  E 


J5^ 

x£ 
O  * 
£>. 

«£ 
»■  ® 

i^ 

TO  n 

(0  (J 
—   TO   , 


«  (5 
=  o  o 

^    TOTO 


I   nj   ^ 


■^   -u; 

TO  tr 
■^  TO  __• 
t  =  3 

TO   3   o 

O.M  n 

s"  $.a 


o  o  o  o 

o  o  mo 

qo  ■^9 

uS  (b  (oi^      CO     (ci  (b 

^  ^  O)  O)        ^        C>  O) 


oin 

5? 


>Q< - __ 

o  o  o  o  o>  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o  o 
mm  (o  ooooo  oooo  oo  oo  omm  o  o  o  oo>co  o 
jojo  ^  <r>o>Qi^«'m^r>io(viN;om^cJa>t^ro<-^ci^''-' 
o>a\  o>  oi^  o>- o  o<o»- o  o«or^  CD'- oooco  ^  m  1^  coi^ 
»- »-      .-      •-•.-•-»-»-»- CNj  CO  c\j  c\i  o  o  o  ■*  CO      00  m  m  CO      co 


o  ocvj  o  »-  o  o 

m  'T  ^  o  P  P  P 

1^  eg  cvi  pii  c\i  p  r- 


cvjCM      rgc\j 


CMCU        CJCM 


(\j  (O  ^  ^  ^  «"^  C\i  ^  5t"«  ^  ^  (0  C\J  r^  CO  CM  CM  CVJ  CM  CVJ        CMCMCMCM 
•-00000»-»-'-«-0000«- oo»- •- ••- •-••-       ^^^T- 


<a  S.Z. 


&! 


af  o 

"  S  o  = 

SEE" 
tl"E 

■o  -o  ®  *  l^ 
®  *  £  £  o 

TO   TO-^-^S 

>.  >.^  ^  rg 
r"  irt  irt  40  y)  *  -_ 

;:  "o  TJ  T5  Ts  Tj  :5 

,    OOOO   5   o 

"  nj  (0  ro  rtj  "o  TO 

O  —  —  :=  —  j;   > 
•=   O   O   O   O  r:  C 

nj  __  ^  ^  ^  >  oj 

;m    iw  ^    lu   »u    lu   lu  ffl    (0    ro    (0 


E    TO 


're'ra 


D-57 


Appendix  D 


«:S 


id 


CO  p  p  (£> 
C)  O  ^  00 


ppppp'r^pcj 
cJodcricooioitboo 
i-cooomtodjoon 


ooooifi'^oir) 

Tj->^  00  r-'  ■^'  iri  '-^  in 

r^ooooooocococo 

•,-■■-•,-•«)•      .- 1- ■--■»»■  r-^  o  o  o 


ooo  o  o o o o o o o o o o o o o 

moo  o  oooooooooi/>0'>-o 

moo  ••-  oooT-ooot^pcjoqoqrv. 

uScvicd  00  o)'>9-'h^CNJT)-rocb'ririo>a)odco 

mom  CO  nc\j  t~~  ^  o  ■^  CO  O)  o  <o  00  00  5 

ooco  CO  coco^^co^r^coco^-  ^ 


CO  CO  m  ••- 1^  1^  m  CO      t  m  in  tt  c\i  in  in  in      in  in  c\j      c\j      cvj  in  in  co  in  co  c\i  m  in  t^  t-^  r^  co 
— —      r- ,- ■^  ■,- ■^  ■,-■•- ■^      T- ■^  ■^      »-      ^  ^  ^  o  »- o  •^  »- •- o  o  o  o 


I'J  I.  I  K'l  Ul   ^—   1^   1^   U#   ^  J 

■^      •.- o  »- >- o  o  >- o 


'=-■*_ 


c  c 


2-> 

cof 


o 


CVl 
^O   9   « 

9  c  c  c 

§i2N 

c  «  o  .is 


So  2:6 
.-2^-0^ 


(0 

«  >.2>-c  o  >, 
i  i  o  i  :==21  i 

-=  -r:  ts  CO   c  -C  CO 

2  2'>'2  03.2- — ■ 

•O  -D  ■£  -D   O  ■>."D  t 


9  a>  <B 


« 


(B  c  Q  a 

n>ouocc,c«cco.-e^ 
—  — .B)cOOT3~a)a>^  —  — 


^       . — ^  ™ 


a  Q. 

o-o 

.Q-c 


j:  >. 


.t;  O  O 
*"  5  O 


nj .™ 

*i 

5.:=- 

■>.>■ 


2-^       mis. 

>,;^-     .    to   ry   O 


2  O  2 

wd'2. 


« 

£  .^  .X 

>^  (0  nJ 
j^  ^  i: 


-mi 


2  X  O.^  <»  CO  i"  o 
T302"n^-=« 


2  •« 


„  «  n>  S 


^H=i=Fi=    (=        t=:    jS  (S  jS  (S;  ^  ^  ^  (2: 


re  (Q  (0  CO  fQ  CO  CO  re  i;  re  re  ^.  re  re 

7S  7K  ^   m  TS  ^^  rtl         o5  ^  ^  ^   CD 


Q  «  2  O  w  ^.fr. 

re  iS  iS  ti  iS  ^.^. 


^S^eeeSSe.^£e8^  S 

-ijf  k»  -llr   ^    -^^  •-  ►—  T~~    ^-    *w  ^^  ^-    *w  «*_  •  — 


X  7  X  Li  ^  l:  ^  "  P^  ^  t:  u:  7:  ^ 
a.:,'  5.C 


".  E'^-z"*  e  E".  E  E 


2    -  2  co"  re  I-"    -  ""-r-"  re  re  to'  re  re 


OOOOOOOOOOOOOOOOOCM 
OOOOOOOOOOOOOOOOOO 

pcyoqpcoppcvjcqp^cvjinoinppin 

'-clcg^ihcoo>o>t^c\j'^^o»c\j«btb«b  t^  o  »-'co^c\ic\i'^o>o>c\idin'>-'inrv;c6c>CT>o6 

r^'>-c>jCMCMC\i<ointCMC\jc\ioooc\j»-c\j  »-  cm  cjflo^'^^oocjcviotDr-cococo'«rr^r~~'«t 

---  .-__-        ^      coinooco 


ooooooooooooooooo 
ooooooooooooooooo 
ooooooocMnoomooomm 


'-COCO^'^^'-'-^'-^    "-    y-    ^-CgtOJOtO^-lf^COOt^ 


oooooo  oo 
oooooo  oo 
ininO'--oo      oo 


■V  »- »- ^  ^  »- r-.  <o  to  CO  CO  CO  <o  m  CO  r*  CO  t-~  t--.  t-»  m  <o  «D  <D  m  CO  CO  m  m  «D  CO  CO  <D  m  m  m  m      cjinm'>-in^      com 

•- O  oo  O  O  O  oo  O  O  O  O  ■r- O  O  O  O   O  O  >- O  O  O  •- O  O  •-•-  O  •-  O  O '-•-'-  •-        ^  ^  ,- •- ^  ^        ,- ,- 


w  re 

19,  ■     ^ 

T:        w  *  • 

■5«reSS 

™  o  B  «  » 
E  «  re-c  £ 

C  m  «  ^   ^ 


■Ow 


reSP£ 
E  u  u  u 
3  re  re 


=sE 


.«?- 
o  q 
>.  < 
8E 

if 

-  a 
It 


a  a 


X   (B 


CJ 


_» 


re  o  • 
IS. 


c  c  *o  re  re  .=  jz  " 


^tt  S  «  c 


3   Q.C3.  C^^   <S^. 

<p  (0  JO  ^  re  JO  ^  ^  ^  ^  ^  ^  ^  ^  ^ 


a  .a 


•o  E 

■JS  re  ^  c  c  • 
™  c  "5  re  re  £ 

2  2  E  E  E-'^ 
o  a>  o  o  o  z.  ■t^ 

o  o  re  re  re       ^ 


o    o  — 
re  Q.  >-c 

.   Q.   Q.  t"  « 
m    S  .2   O  ......  .. 

h-  f— C'in«wJ=iri=Z.i= 


o  9 

re  .-5 

«  £  >. 
."5  Q.-C 
^  8  10 

■S2:« 

sore 


>>^ 


^2 


Ore 


o  «-o 

ElE 

a.2 


Ig,:^! 


o  O  § 

=    Q.  t 

.2:=.E 
■a  >.re 

tM.'o  £ 


.  ~^re 

CO  ™  » 
^.Q  re 


A'O'in 


^.  !52«2fl522^2 


88f 

>>>>E       '   w    —   in 

■5>-5.§.^2  2o 

0)  a  o  re  m  9^ 
c  c  c  op -c  ^ 

>,>,>,  >o  o  >» 

.£.£.£  ^7-1  _g  £ 
OD   OD    «    OO    ^  • 

re  re  re  jX-.S  2 
^,2,2,20      (2 


D-58 


Synthetic  Organic  Chemicals.  1990 


I  o 


</)S 


"RPP  P  P  P  P  PPP<»qconqioooiDuioooocooorv.a)ir)oc\jooqcyoooi-^!Dt^ 
'-00  o  o  o  o  oooooooooooooo'-ooo'-^oo  —  oooooi-^ooooooo 


3   3   «  S  T3 

•  *  X  ™  (0  c  .£ 

«  «  *  5  y  :5  5 

^^  ffl  —  ^  ^  — 
£i2  =t2££t2 


^9  2  „S 


2 1  E  >. 
8£t2- 


p  rat^T.e  o 


u  *  P 


2  >.  6  E  > 


>=  a  6.1^  E  Q.  6  E  Q.  E 


o  o  ^ 
Q.ca.t= 


o  o  o  o  o  o 
o  o  o  o  c^  o 
p  pen  q  o  o 
t^  ui  <b  oj  o  00 

O  CJTT  lOCJ■•- 
lO  •*  t^ 


ooooooooo 

800000000 
poooooioo 
iftc\ioirir>co<boo 


00  O  (S  o  o  o 

•-  o  •>-  o  o  o 
o  in  o  otr>  o 
^r^  oHflo  cvj 
CO  o  •*  o>tD  in 

PU<\J  T-  t^  ^ 


qpp«-^popoqooqoqqminfloo<o 
uScviuSc\i^(£>o6dCT>r~^(dir>«boi— 'r-~'cri»- 
(Ocoir>oo<oo>o>ooo^(oo<o><-rgr^(Doo 
»- ift  ■«  m  n      •- ■<»  m      1^  «o  <o      C5«ooe\j 


8- 
« 

— '  X 

IE 

c   «   •   " 

I  8  3^' 

E>-c  a^c  « 
5  o  o  -c 

i;  i:  i:  'C'S 
,0)  ,9  ,9  ,9 


^  «  1  £>' 

■some 
O  !r  TO  t 

=  i""s;  o 

ni  <n 


C    W    C    (J 


III 


—  -  i5 

o  <» 
c  S  S  o  * 
S  c  -IS- w  ™ 
2  *  «  «£ 
*-°  ®  9-2 

:5«"Eii. 

<o  S  ™^  o 

=  «=  U  i-  !2 
«  »  (8  E  a- 

i  E  E  8.5 


in.P 

(\j"  o 


:«E 


.-=  >-  r-  • 


^a 


o  o  c  y 

•  p  w  o  ro 

c  ^—  o 

E  c  O  <-> 

fc  b  y  ra 

CO  CO  n)  Q 


o  >. 

V- 

8  ^ 

£  n 
cii 
CD  o 
«".£ 
2.E 

C   >.( 

^£| 

(/)  in  !5 

.2.2  I 
££  ra 
,  -  -"^ 
foZ  o5 

cd'Z 


•£=5 
c/)  o  o 

•  •.!? 

E£75  X  = 
.«  2  O  c 
.■5  E  «  £  2 
y  o-c:  •  • 
"  r=  ■s;-=  E 


c  2 
.c  .2>^ 

■^  t-pu  ;£  Jo 
Hcjcvi' 


113 


»  a. 

ill!. 

litti 

T  o  t- 1-  XI 

q-S-c^c^i 

O     cocoF 


11 

— ■  -»  i*  '^  ®  ® 
nj  ?  2  2  =  "- 

c SSeSS 

Q.  a  a  cn£  3 
.2.S.2.S.S.O 
jc  £  j:  ^  ^  ^ 


is  :|l 
is  » 
of     gE 


£  « 

o  c5 

=  c 

li  o 

XI  u 

if 

™  cfl  E 
J5  c  c 
.E  .t:  .t: 


D-59 


Appendix  D 


^S 


(02 


o  o  o  o 
>-  o  o  o 
o  o      o  o 


q  q  p  ■■-;  c\j  q 
o  c\i  o  o>  oi  d 
o>  00  r>.  CO  CO  vn 


oooooooocoooooooooooooooooooooooo 
ooooooooooooininoooooooooooooooiooo 
i/jtococoqooq-^ojuiqO'i-qcjuicoqqcoooTrujqqqqqint^qq 

»-oo)'-ooc\j'}-cooiocoteo^oou5r-~ior^oo<ot^ooc\jc\ic\JOootoiOtf> 


'-Ol'-CMn'^CNJCOCOtOTO 


CO  >->---  T-  CO  •^ 


--         CM  C\J    CM  CM    CM  CM  CM  CM  CM  CM    CM  CM  CM  CM  in  ••- CM  CM  CO  l/>  IT)  CM  IT)  CM  lO  1/1  »-  lO  lO  lO  LO  ^  LO  IT)  t-  >-  t-  lO  U1  >-  U1  in 


E 

■—  2 

TO  ■</) 

9.-0 


"   TO-D  T3 
73  c/)  Q)  ® 

2   *   TO   TO 
>.  E    X    X 

X  S  O  O 

•?>••£■£ 
II  8.**- 

TO  jc   TO   TO 


o  o 

TO   TO 

"to  •  * 


E    TO   c 

2  o  O 

to    -Q  -iS.S 

T3  0)  ."S  !2  >.  >. 

0)  m  O  O  X  X 
^JS   TO   TO   O   O 

X   Q   C    C    o   IS 

o  o.  o  o  -5,-5. 
£  233  J3£ 
0)  Q.  v)  v)  0)  e 

o  o  c  c  ^^ 
-=  -=    O   9    X    X 

w  !2  ."2  ."S  !5  ."5  ."2  *rt 


E-^ 
TO  <n 

I" 
O  TO 

S-a 
E  • 

_TO   to 
Q.  X 


^o| 


2  J:; 

TO-S 


.  <».9 


^■Sa^SS.iE^ 
■5lcgTOre"i:J5t 

*Q  Q.<n  <n  inCO-^.tr 

;o  ^ 1-  ffl  Tp 

Ko'oQ'oOoE'V 

C.^  !S  !2  15  !5  !2  .■^.■=- 


5.y  a. 

Q}  Q>   9 
C    C    C 


E  E  E 

000 
c  c  c 


E  E  E 

o  o"o 
c  c  c 


i:  E 
u  2 


•:^  c 
E 


-S-S-S-S  o  3 


£S    TO 

E  6  fi 

TO   TO  i5 


it 

»  TO  ^ 
TOT)  <^ 
i:  O  « 
T;  c  c 


a>  3  o 
-2>.>. 
9-  *  ® 

TO     I 
^CMCM 

^  ^  ^  E 
o  o  o  E 

U   O   U   TO 


8.2 

O   TO 

5.= 


:  TO  ■" 
LoD  E 


-="^-^^  •=    X 


■£  £  £ 


®  o  ®  o 
c  c  c  c 

(S    Q>   0}    ® 


IS    X 

2  « 


—  ■B 


o  o 


00000000000000C31000000000 

oooooomoooooirtooooouioooooo 
TrinioqcMCMqqqooiO'-ocMO'-wocMonqo 
oicricodcboodrvIaJoi'-^jodoboticM'r-fotDT-^oiiod'--' 
o>o)ror^coir>0(0<0(0^oooo>ooor^(0<Dt^ooina>o> 


0000000  000 
0000000  000 
oqqqqqin  oqin 
ibroin<bh»'cMco  ^■v'cm 
■^©^•^^t^o  0)cno> 


•- ••- m  t^  o  CM  CM  «D  CD  «o  r^   CM  n  •*  •-   cocm   cm'^^'^t   •- cm  cm  cm  cm  cm  cm   con 


0000000  ooq 

t'  CM  n'  00  in  iri  cji  •*'  CO  CD 

cono>no)do>  of^o> 

CM  ■n  CM  CO    t  t  CMCMCn 


m  m  <D  CD  m  m  m  CO  CD  CD  CD  o>  m  ■*  CO  •- »- m  m  »- M- m  CO  CO     co  m  m  in  mm  m  t^  m  c^      coeocommcoco      mmm 


•.-^OO'-'-'-OOOOO'-'-O'-'-'-^'-'-'-OO 


is; 

fa 
o  o 
13 13 


u 
re  0) 

e  E  o 

E  ""-S 


■62 
c2 
o  a> 


TO-O 

?  «  5  5  £ 


fc  o  o  o 


^^  >-2 


■  re  <B 


(Q   (0   (0    (Q   fl) 


2-R 
111 


E 
o 
«  :  a 

E      -TO 

■^  :•§. 


«£q.2  E 

c   *  — TO   3 
>.-Q.>..e.C  « 

tilfliill 

XcD(<|3Ac33.c 


■.-•.- ^  ^  »- ^  ^    O  •-  O         »-  •- O  »- ^    O  O         ^  ^  »- 


E_ 

o  •" 

•5:5 

T32> 


9  a 
,^      -e  TO  re 

j'V  o  «  o  « 
>  o^  2  o  o . 

J  .2  ^-2 .2 .2 . 

-  -^  X -R  -c  .c  • 
J  .2  Q  a  U  U 

-  .>-  JC  L_  .>-  .>- 


~-     ■.        •      »  - 


™  .™  .™  .!»  .™  .™  .•='n  .■srAi  .J.  .i  Ai  Ai  .y  CM  <M 
'"■'"■'"■''■'"■'=  (^  cm' t^  (^  t^  t^  t^  t^  (^  ^'  ^' 


'"-2  "♦. '-.CM_ 
^'       CO"^''^' 


3.Q.S. 


re  u 
$  «cm'  o 

2  o  o5  2 

6>^co2 


o 


5  or) 

£    OTf 


<»  «  n'S 

loll 
o^IT  o 
.c  j:  CO  jr 

,y  .y  CM  y 


0)  c  c 

C   N   S 


I^J?5^ 


".CO  m 
Ot'co' 
Ocm't-' 


T3  »- 

^^ 

TO  ^— 
U   « 

z  c 

3   TO 

c  jr  e 

"  ®  S 

o  « 

2—  *- 

O  i:  > 

222 
y  05 

ill  .c  j: 
Coo 


D-60 


Synthetic  Organic  Chemicals.  1990 


oo-^rooo   OOOOOOOOOOOOOh^OOOOOOOOOOO 
OCO-^OIOO    OOOOCNJOOOOOO'-OOOOOOOOLnOOOO 

ooooino  oioooooooocooonocNjoooQDi/ioooo'^ 


oooooooooooo 

•-00000000000 

ot-^'<3-oioooinoooo 


*:S 


c\]'-uii/)a)i/)  inooococNJco'^OT-oioooojDootoinaioton-TLnir) 
CNjoir^CTicDoi  »-i^nr^cjor-~cnoinT^T'jiDcDr^o^c\j'T'-iootr) 
■r-      >- oj  •^       IT)  CO  CO  r-- ■^  in  r~  >- CNj »- >- T- ■•- •- o  o      o  •- >- in  o  i/)  in 


CMM-cDmin->t<ciD--c\jcor-- 
csj-sj-iDTtinoiniO'-'-'-O) 


•^        .-  ■"3-  CO  ■^        •- 


n  "-  »-  —  (M 


r^cMincvj.—  '-•-iniDiDiDin 


!p  E 
o  2 

N  J3 

9  3 
n'c 


JO  ra  c 


'  c  ^ 


*  <«  U  A  £ 
c  —  ^  .<2  ™ 

C   X    •     '    fl)  -^ 

<  o  e  n  0)  ^  >■ 
-  ^  -L  c  —  £ 

">.  >««5  jz  o5   . 
:  ?  *.ni-uSo 


llii^lirisitlll 


(0 


■(5  3 
>-^ 

3    V> 


>-.E 


2  <»  E  "  ■§  *  2  ^  S  S  5 


tvE'Oc??ccSccccc 

-i  ?^—  5-S  aaS-O-Q-Q-Q-Q- 
>•£  _>•  >.^  ^ooSgoooo 

c5  ?  o5  o  o  Tj  Q- Q-3  Q- Q- S.  Q.  a 
p  =  p£_ooooooooo 

"-zSi.i.i.i.i.i.i.i.i.i.i 


TJ  o  o  o 

9  T3X)  -O 
o  O  0)  o 
_K  c:  c  c 

_   0)  c  c  c 
O   w    ^    m   A    0)  ^ 

T5c5nj9-9-9-2  „, 
mEcconrooi^c^ 
o  o  2  ^"^"^"£  .c  «  "> 
re,^  Q.  I     .     '    Q.  n  9  > 

rt    n"r'"r'"^"^"^    in    n    > 


P 

it 

iS.o 

(0   flj 


2  :t 

o 

^    ■  5 

3  9  — 

-  >  y 


^■^szsi^^^  o  ^-M 
—  —  E  E  E  E  E  — ir=r 
£  :£  K  t^  K  K  H  £  £  £ 

c  c"».-«.'>:t^.«o  p  p  c 

C      C    rvi    ^Nl    f*il    />VI    /IM       ^       ^      C 


2  >«:?: 
aj  >•■£  ■ 


5  5  cvi"c\j"c\j  cvj'co  £  •=  g 
H-t-  cJcvTcvrpgcvTl—  f-t- 


0)  ?•—  * 

F  £  *  E 

i  o5  E  c 

'r  E  •=  H- 

E  <^J"t^'2i.o 
i:  «'      in 


l§ 


oV  ^ 

rare  1^0 

<»  t)  i5  tj  — 
><  O  i-o  >• 


>.E 
^-2  c 

m  t:  re  ^  »-^«- 


.45  ^  » 


«  — 
re  E 

ee| 

_  ^  c 

rr  re  c 
^  >-^ 
o  o  <" 


E 

e 

E 

r 

r 

c 

0 

c 

a> 

0) 

0 

Q.  Q.Q. 

^2 

«)2 


_    _    _'  O  Q  (_ 
OOO'-OOOO 

«o  cri  d  d  r^  •^  • 


m^-mmo)Ujmin 


000000000000000000000000000000000000 
ooinooininoooooinooooooooooooooooooomooin 
»-coinm<noooooocoino>o>oooou>0'-no»-ooinooo«-or^o>cDOOD 


(D  <D  O  CO  f*^  ^ 

>-       >-  cvj  r--  o)  CD 

>-  '-tT  CViCO  CO 


"*  CD  ^  m " 

10  T  O  <D  > 

•^  m  co■' 


■o•v■v■•-lnc3>c^J•«^-o>o»o^lno>lncD(Mcocooo>co■•-^^'- 


'»  m  m  TT  m  o  •^  • 


•moO'-cnr--<DO<Dcji«-»-h-cooc\jopa 
inin'-incMcocNjcoc\jmmcO'-c\j'-c\j'- 


if 

T3   >• 


0.2 


^^p 


o  3  E  • 
c  S  o  5 

•Elig 


c  o  2  ®  0) 

®  c  £  ><  •^ 

£  2  2  ^  i 
re  ffl^  0-5. 
<J-^   n   <J  c 

I?"   >.V  I 

c  >,  >,  f5  —  >«  >•  >>5 

re  Iff  ?"1  I  f  S" 

£  h=  t^  £  £  t^  h:  I- £ 
«  4  in  ®  "  in  in  in  ^ 
^  (\i'  co"  ^  ^  co'  co'  in  •£ 
K  »-"'-"  ►^  K  co"  co"  co"l— 


D-61 


Appendix  D 


*:S 


C/5^ 


oooqpppqoqoooopooopoop^popooopoooocnooooooir) 

^^-^c^jcrllr)l^)^^0'-a>dc)a>'-;b^»c\j■ 

<D(Dr^r-^r^r^r»t^oor-~ooooc\jcncoroi-' 


0000000 


OOOOOOOOOOOOOOO'-'-O'-OOOOO'-'-'-t-'-'-T-OO'-''-         y-  ^  y-  -r- 


£5« 

O  CO 

=  c\j 


imm 


atcnto  ^'" 

CNJ  ^  lO-o  c 
®  ®  O  ffi  > 
_3  _3  ^^   O 

CD  CD  00  ^  (Q 


ra 

>.  - 
■o  '- 
c  c 
S  <» 
o  2 


"^   "V?   nP   -"^ 

•-  C\J  f^  o>  fo  '- 
to  1^  e  «  «  «  ^  Q- 

C   C    0>0)  CDCDi-  ^ 

«a)cccc__ 
OOOOOOCCOC 


•I 

H 


a  o 

J3  O 


•5    ™    O    rj 


1-    >•>- 


■D  5 

DC  2> 


.5  w  50 

c  o 

*£    ~    A 
_  O) 

jcxf.E  5 
-  »Q  J 

■o^    -i5 

[1       .  V    ffi 

-i":^    >,  O 

10   «   ™   -   '^ 


16 


®  ^ 
c  « 


«  >  " 

E    .y 


^  "  ;: 

S™E 


8. 
„_  .  .8 

».  •"  —  ^  •     — 

y- 1  ra  o  F  0)  dj 

8.  T  «      .     .  > 
o  o  -^  ®  o  ® 

C  C   C   >'C   c  c 

o  o  o-£  o  o  o 

c  c  c  «  c  c  c 
J6  i6  J6  «  jo  Jo  j6 


CD  CD 


c  u) 
>5 
>>>> 


el 

e  g  I  n  5  o  o 
o  o  c  0  o    • 

E        .u^Oooaooo-iooo 
oTi?  «>.a)"-c  a.S.StttEttt 

•S  ^  T3  ^-5    <J=-DT3    >>>->»n)    >.>.>. 

we^S'c*®^^^-^-  °->.  Q-  Q-  Q- 
0  2 1  E  §  S  S  a  a^V  fH  ^H  £  fy  ^H  fy 

>.>.■>.>.    >.^^;£    ^C^C.E^^^ 

C    C    C    C    C    C    C>>>>>TJ>>> 


CNJOOOOOOO         000000    0000000  00000000000 

O  O  O  O  O  O  in  O       (00)0000000000  10  o  o  o  o  o  o  o  o  o  o 

----       -       -      Tro>0'«»-mopi/)moi/>o  loooi^mooooop 

tvicriTruSjb  ir)obiri<b<bt-^'r-'  •^t^ooi'^r-sioibcvi^co 

•*  ■^    CM  M- CM  0>  C\J  O  00  X"  1^  f^ 'O  00  r- O  '-•-'-  o 


(oooomoM-to 
CO  uS  d  ^'  ^'  cvi  r-^  o 

OJ'.-'-'-'-OOO'V 


000  O  O  O  O  O  O  O  O  CO 

000  OOOOOOOOtfJ 

po(o  ppppo>pppp 

oor^v-  oooo^i/>c*5^coo>co 

OCMr-  C\J  CM  o  00  CsJ  <£>  o  o  •- 


CM  •- •- n  T- »-      •- o  o  o  o  I/)  o  m  CO  in  CTV      cm      •-cou)      m  tr>  in  m  m      10  »- cm      io»-ooir>'* 
fo  ^  vrt  <o  <D  irt  m  m      m  m  irt  ifl  irt  CO  m  CO  irt  o  m  to      m  <o  i~»  irt  m  00  ■^  •*  •v  ■^  ■^      't  <<r  in      co  t  in  m  co  co  •* 'T  •* 


O'-'-OO'-'-'-         ^T-^i-^O'i-O'i-O'-O        i-OO'-T-O  —  '-•-■•-'- 


^  ^  r-        O  •-'-'- o  o  o  o  o 


2  eS 


O  ro 


»55-=  o 
E  Q.  ex  a>  9 


i__  c  c 

C    C   C  5  5 
O    O 


9. 9.9. 9. 9. 1 


»  a. 

80  O  J"=-ir  >-CM 
u  o  n  >.  >.Q.  A 
>•>->■  S.-C  -c  O  2 
0>  O)  D)  O   CD    a   Q.5 

O    9    O    K  —  —  —  T3 

a  S:  a-c  V  V  V  ". 

2   2   2  '3  CM  CM  CM  >- 
.  Q.  Q.  Q.2    */>  .*rt    in    t/) 


a  ra 


?  So-? 

-c  -5  X  O  t  « 

,  .2^_Q.££  E.£ 
>  K  j:  m  «  «  2  S 
5  .'    ©^  E  E  c  5 


u 
E. 


EsS 


'-LCD 


^s 


cS3 

:    </)    (D    a 
»^3  3 


(/)  "O        ^  — 

2-   D   *  O   != 

•D  >.E  t:^^ 

fro  c  c  c  c  X  Q..2  » 

_  (Qra(orarefl)(QcQfl3 
0  o  0  ®  ®  o  o  J3  0 

)53    5 


•  8. 

nJCC 
E=- 


flJJC 

|i 

®  ?  2 
o  2  " 


<B  ii 
0)2  " 
irt  ra  .y 


5  o-5i5i5 
^  U  CD  CD  CD 
■&  c  ^  ^  ^ 
(0  (0  (0  (^  cp 


3>>>>>>> 


D-62 


Synthetic  Organic  Chemicals,  1990 


W2 


*:S 


ooooooo  ooooooooo 

OOOOOOO    U100000000 
OOOIOUIOO    0)000000000 

l/i^~^Ol^i•-ou^  •— uS(£ic>^^-.^-c\iTT 

'T'»mCT>oD'»}-or~roncO'^to<DTrm  _.      . . 

\r>  \n  \n  o  in  lo  to  iDC\jcjc\jtf>f^r-~c\i»-      •-CTr^r-^»-»-^«)  <o^r». 


OOOOOOOO  l/)00 

oooooooo  r~~oo 

OOOOOO'^IO  o>oo 

oiuiocoobocirvi  ^uS,-' 

t^T-^JOI^'^OO  f^'^'- 


(/) 


^  (Q   o   C 

0>tf)  ^Q. 
-  <"      .« - 

_-  «  o"-- 
O  O  c  — 
C    C  =    O 

O  0) .?  e 


«  .  s 

c       Z 
■=-_  » 

»  9  iii 

«   C   (0 

^  m  o 
XtsiN 


nj 
■S  * 

o  o 

ffi  01  Q..-e: 

•s-E  o"o 

m  °  °  O  " 
_  ?J=  S 
>.S  Q  Q-j:  i;  ni  to  fi" 

V-  i?  i? ^  Q.  c  <J  -  * 

a>  o  o 


o  9  ._- 
£  ™  2 

(0   (J 


—  ^  T3  T)  CM  C3)  O)^  .52  J5 

ouuuouuouu 
cccccccccc 
MNNNNJSINJtSlisiisj 


Wan 
«  is  nJ 


£  S  n  o 


^  i5  w 

-  -  2=s 
■o  c  c  wi2 
o  o  u  u 


So* 
2  "  f5 


»  E  E 

3   (0   C 


ss* 

5^  o 


0*8 
E  e  E 


u  u   u  o  u 


"•cccc 

N  N  N  N  Kl  MNJ  NNKj 


OOOO0h~OO00OO000OOO00OOO0OC\JO0O0 
OOOOOCVJOOOOOOOOOOOOOOOOOOOOOOOO 

oeoocoocvjoooooooooqioooooouimoDOuioirtoo 

^c^«nodoc6<bo^'-c\jc^i<bu^ooo»-uSoo)^o^c^ioorjoVV^» 

ir>      o>  O)  CM  o>  r^  »- *- r^  r^  r^  o  r^  r^  ^  m  IT)  ^  CO  ^  CO  CO  ^  ^  ^  i/>  ^  ^  i/> 

CO  CO  CNj      r^  00  00  r^  r^  r^  CO  r^  »- r^  ^  *- m  lo  u)  m  »- u> »- u^  u^  r^ 


oocoir)i/)i/)i/)(C(C<C(0(c<0(C(r>ai<\jTi'(7icocococ\jcMcoc\jcoc\jcoco(M 

0O'-'-0OO0000O0O0t-t-000OO0O»-0»-0O»- 


_  =  —  >~ 


<rt  c  5  _ 


c  c  c  c  g 
>>>>> 


n 


25 

O)  10 

"g  5) 

01  n 


"to    '  "^ 

slit 

o  2  2  o 
=  E.^-£ 

^  T^  ^  ro  ra^  Q.-  TO  j; 


ra.E 
2  2  2  a>  «^ 


o  o o|  ™  o 
TO ro ra " 8^ 

TO    TO   03 

<dd<<< 

CM  c  c  c  c  c  c 
o  E  E  E  E  E  E 

Q   (D   tTJ   <TJ    fO   (U   (TJ 

>>>>>>> 


E  c  re  o 
ore  Q-y 

O   Q.-0   TO 

£  £  «  J 

E  E  So 
2  2  TO  S 
>>55 


-  o  c  2 

—  O  2  S 

«  ®  c  •  ^ 


r>-o 


"■   ■    p  A  J- 
.  o  ^  °- • 

3  o  g  b  H 
w  o  °  o  3 

^So,  »<i)XO 

c  c  ^->C  ^^  ^ 

TO   TO     .     J.     .     >«  > 

XX  o  E  ci>:x 


(5  <2 
u  n  c  (/> 

y^^ - 

g  <t  re  !^ 
^e.u.y.y 

2  c  c  c     •  r;  o 
X  O  O  o  ■;;  K!  j: 

9  ifi  (/)  (/)  _0 r 

^  a  9  9  >,  O  O 
X  C   C  Cx  P  C 


•-  O 


-=  ^^    •    *  * 

cmxxxcmxx 


»:■>.">.">.<' 


D-63 


f  ^  " 


iiBBre5g!iigj]u.uiJj-jjj,iJniniMgi!BiaraiiJ^^ 


FOR  IMMEDIATE  RELEASE 
January  29,  1992 


Contact: 


Ed  Carroll 
202-205-1819 

OPA  92-005 


ITC  PUBLISHES  74TH  ANNUAL  REPORT  ON  SYNTHETIC  ORGANIC  CHEMICALS 


The  combined  production  of  all  synthetic  organic  chemicals  and  primary 
products  from  petroleum  and  natural  gas  in  1990  was  179.5  billion  kilograms, 
according  to  the  ITC.  That  amo\int  is  3.7  percent  more  than  the  output  in 
1989. 

Sales  of  these  materials  in  1990,  which  totaled  101.6  billion  kilograms, 
valued  at  $93.1  billion,  were  3.2  percent  more  than  in  1989  in  terms  of 
quantity  and  3.2  percent  less  in  terras  of  value.  These  figures  include  data 
measured  at  several  successive  steps  in  the  manufacturing  process  and, 
therefore,  they  necessarily  reflect  some  duplication. 

The  report,  which  is  the  74th  in  an  annual  series,  covers  about  6,000 
individual  chemicals  and  chemical  products  and  presents  statistics  in  as  great 
detail  as  possible  without  revealing  the  operations  of  individual  producers. 
The  report  was  prepared  from  data  supplied  by  670  primary  manufacturers  and 
includes  a  list  of  manufacturers  of  each  item  for  which  production  and/or 
sales  were  reported. 

Copies  of  the  report  Synthetic  Organic  Chemicals.  United  States  Production  and 
Sales.  1990  (USITC  Publication  2470,  December  1991)  may  be  obtained  by  calling 
202-205-1809  or  from  the  Office  of  the  Secretary,  U.S.  International  Trade 
Commission,  500  E  Street  SW. ,  Washington,  DC  20436.  Requests  may  also  be 
faxed  to  202-205-2186. 


-30-