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Models  of  the  Atom 


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The 
Project 
Physics 
Course 


Transparencies 


5 


UNIT 

Models  of  the  Atom 


Published  by  HOLT,  RINEHART  and  WINSTON,  Inc.    New  York,  Toronto 


Project  Physics 

Overhead  Projection  Transparencies 

Unit  5 

T35  Periodic  Table 

T36  Photoelectric  Experiment 

T37  Photoelectric  Equation 

T38  Alpha  Scattering 

T39  Energy  Levels — Bohr  Theory 


m 

f- 


Periodic  Table 


T35 


Periodic  Table 


This  transparency  will  be  useful  in  discussions  centered  around  the  classification  of  the  elements. 
Various  overlays  highlight  chemical  families  and  other  pertinent  groupings. 

Overlay  A  The  modern  long  form  of  the  Periodic  Table.  The  number  below  each  chemical  symbol 
represents  the  element's  atomic  number.  The  Roman  numerals  identify  the  Groups  or 
Families.  The  numbers  to  the  left  of  Group  I  identify  the  Periods. 

Overlay  B  This  includes  the  62  elements  which  Mendeleef  included  in  his  1872  classification.  His 
grouping  was,  of  course,  unlike  the  present  long  form.  Rather  it  resembled  the  modern 
"short"  form  of  the  Table.  Remove  this  overlay. 

Overlay  C  The  Alkali  Metal  Family  (Group  I). 

Overlay  D  The  Halogen  Family  (Group  VII). 

Overlay  E  The  Noble  Gas  Family  (Group  O). 

Overlay  F  The  elements  known  as  the  Transition  Elements.  Remove  Overlays  C,  D.  E.  and  F. 

Overlay  G  The  Natural  Radioactive  Elements.  Those  which  undergo  J-decay  only  are  tinted 
lighter.  Technetium  (Tc,  Atomic  Number  43)  is  a  synthetic  element. 

Overlay  H       The  Transuranium   Elements.   These   have   all   been   synthesized   in   the  laboratory. 


T-35 


Periodic  Table  of  the  Elements 


1 


T5 
O 

'^  4 


0 


H 

1 

II 

III 

IV 

V 

VI 

VII 

He 

2 

Li 

3 

Be 

4 

B 

5 

c 

6 

N 

7 

0 

8 

F 

9 

Ne 

10 

Na 
II 

Mg 

Al 

13 

Si 

14 

P 

15 

s 

16 

CI 

17 

Ar 

18 

K 

19 

Ca 

20 

Sc 

21 

Ti 

22 

V 

23 

Cr 

24 

Mn 

25 

Fe 

26 

Co 

27 

Ni 

28 

Cu 

29 

Zn 

30 

Ga 

31 

Ge 

32 

As 

33 

Se 

34 

Br 

35 

Kr 

36 

Rb 

37 

Sr 

38 

Y 

39 

Zr 

40 

Nb 

41 

Mo 

42 

Tc 

43 

Ru 

44 

Rh 

45 

Pd 

46 

Ag 

47 

Cd 

48 

In 

49 

Sn 

50 

Sb 

51 

Te 

52 

1 

53 

Xe 

54 

Cs 

55 

Ba 

56 

1 

Hf 

72 

Ta 

73 

w 

74 

Re 

75 

Os 

76 

Ir 

77 

Pt 

78 

Au 

79 

Hg 

so 

TI 

8! 

Pb 

82 

Bi 

83 

Po 

84 

At 

85 

Rn 

86 

Fr 

87 

Ra 

S8 

• 
• 
• 
• 

La 

57 

Ce 

58 

Pr 

59 

Nd 

60 

Pm 

61 

Sm 

62 

Eu 

65 

Gd 

64 

Tb 

65 

Dy 

66 

Ho 

67 

Er 

68 

Tm 

69 

Yb 

70 

Lu 

71 

Ac 

89 

Th 

90 

Pa 

91 

U 

92 

Np 

93 

Pu 

94 

Am 

95 

Cm 

96 

Bk 

97 

a 

98 

Es 

99 

Fm 

100 

Md 

101 

No 

102 

Lw 

103 

TRK 


Periodic  Table  of  the  Elements 


B 


1 

1 

H 

1 

Elements  Inck 

ided  in 

1872 

0 

He 

1 

II 

Mendeleef  Classification 

ill     IV      V     VI    VII 

2 

2 

Li 

Be 

B 

c 

N 

o 

F 

Ne 

3 

4 

5 

6 

7 

8 

9 

10 

'^ 

Na 

Mg 

Al 

Si 

P 

s 

CI 

Ar 

3 

II 

12 

13 

14 

15 

16 

17 

18 

o 

^      A 

K 

Ca 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Zn 

Ga 

Ge 

As 

Se 

Br 

Kr 

<D   4 
Q- 

19 

20 

2 

22 

23 

24 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

c 

Rb 

Sr 

Y 

Zr 

Nb 

Mo 

Tc 

Ru 

Rh 

Pd 

Ag 

Cd 

In 

Sn 

Sb 

Te 

1 

Xe 

5 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

6 

Cs 

Ba 

' 

Hf 

Ta 

w 

Re 

Os 

Ir 

Pt 

Au 

Hg 

TI 

Pb 

Bi 

Po 

At 

Rn 

55 

56 

"• 

72 

73 

74 

75 

76 

77 

78 

79 

80 

81 

82 

83 

84 

85 

86 

7 

Fr 

Ra 

' 

/ 

87 

^s 

• 
• 

La 

■■  57 

Ce 

58 

Pr 

59 

Nd 

60 

Pm 

61 

Sm 

62 

Eu 

6i 

Gd 

64 

Tb 

65 

Dy 

66 

Ho 

67 

Er 

6% 

Tm 

69 

Yb 

70 

Lu 

71 

Ac 

■•.  89 

Th 

90 

Pa 

9 

U 

92 

Np 

93 

Pu 

94 

Am 

95 

Cm 

^6 

Bk 

97 

a 

98 

Es 

99 

Fm 

100 

Md 

101 

No 

102 

Lw 

103 

m 


1 

1 

H 

1 

11 

Periodic  Table  of  the  Elements 
Alkali 

Metals 

III     IV 

Noble. 
Gases 

V    VI 

• 
• 

• 

VII 

0 

He 

2 

2 

Li 

Be 

\ 

B 

c 

N 

0 

F 

Ne 

^ 

3 

4 

5 

6 

7 

8 

9 

10 

3 

Na 

Mg 

Al 

Si 

P 

S 

CI 

Ar 

II 

Q 

13 

14 

15 

16 

17 

18 

O 

'^  4 

0- 

K 

Ca 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Zn 

Ga 

Ge 

As 

Se 

Br 

Kr 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

5 

Rb 

Sr 

Y 

Zr 

Nb 

Mo 

Tc 

Ru 

Rh 

Pd 

Ag 

Cd 

In 

Sn 

Sb 

Te 

1 

Xe 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

6 

Cs 

Ba 

*• 

Hf 

Ta 

w 

Re 

Os 

Ir 

Pt 

Au 

Hg 

TI 

Pb 

Bi 

Po 

At 

Rn 

\j 

55 

56 

• 

72 

73 

74 

75 

76 

77 

78 

79 

so 

81 

82 

83 

84 

85 

86 

7 

Fr 

87 

Ra 

S8 

• 
• 

• 

Halogens 

La 

57 

Ce 

58 

Pr 

59 

Nd 

60 

Pm 

61 

Sm 

62 

Eu 

6i 

Gd 

64 

Tb 

65 

Dy 

66 

Ho 

61 

Er 

6S 

Tm 

69 

Yb 

70 

Lu 

71 

Ac 

89 

Th 

90 

Pa 

91 

U 

92 

Np 

93 

Pu 

94 

Am 

95 

Cm 

96 

Bk 

97 

a 

9S 

Es 

99 

Fm 

100 

Md 

101 

No 

102 

Lw 

103 

c 

D 
E 


TT3a5 


Periodic  Table  of  the  Elements 


1 

1 
H 

0 

He 

1 

II 

III     IV      V     VI    VII 

2 

2 

Li 

Be 

B 

C 

N 

0 

F 

Ne 

3 

4 

5 

6 

7 

8 

9 

10 

3 

Na 

Mg 

Al 

Si 

P 

S 

CI 

Ar 

II 

0 

13 

14 

15 

16 

17 

18 

o 

Q. 

K 

Ca 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Zn 

Ga 

Ge 

As 

Se 

Br 

Kr 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

31 

32 

33 

34 

35 

36 

5 

Rb 

Sr 

Y 

Zr 

Nb 

Mo 

Tc 

Ru 

Rh 

Pd 

Ag 

Cd 

In 

Sn 

Sb 

Te 

1 

Xe 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

6 

Cs 

Ba 

■■, 

Hf 

Ta 

w 

Re 

Os 

Ir 

Pt 

Au 

Hg 

TI 

Pb 

Bi 

Po 

At 

Rn 

55 

56 

"• 

72 

73 

74 

75 

76 

77 

78 

79 

so 

SI 

82 

83 

84 

85 

se, 

7 

Fr 

87 

Ra 

88 

• 

Rad 

ioa 

ctiv 

eE 

em 

ent! 

La 

57 

Ac 

89 


58 

Th 

90 


Pr 

59 

Pa 

91 


iNdl 

60_ 

U 

92 


Pm 

61 

Np 

93 


Sm 

62 

Pu 

94 


Eu 


Al 

95 


64 


Tb 

65 

Bk 

97 


a 

98 


Ho 

67 

Es 

99 


Er 

es 

Fm 

100 


Tm 

69 

Md 

101 


Yb 

70 

No 

102 


Lu 

71 

Lw 

103 


im 


Periodic  Table  of  the  Elements 


1 

1 

H 

0 

He 

1 

II 

III     IV      V     VI    VII 

2 

2 

Li 

Be 

B 

c 

N 

0 

F 

Ne 

3 

4 

5 

6 

7 

8 

9 

10 

3 

Na 

Mg 

Al 

Si 

P 

S 

CI 

Ar 

II 

0 

13 

14 

15 

16 

17 

18 

O 

«  4 

0. 

K 

Ca 

Sc 

Ti 

V 

Cr 

Mn 

Fe 

Co 

Ni 

Cu 

Zn 

Ga 

Ge 

As 

Se 

Br 

Kr 

19 

20 

21 

22 

23 

24 

25 

26 

27 

28 

29 

30 

3! 

32 

33 

34 

35 

36 

5 

Rb 

Sr 

Y 

Zr 

Nb 

Mo 

Tc 

Ru 

Rh 

Pd 

Ag 

Cd 

In 

Sn 

Sb 

Te 

1 

Xe 

37 

38 

39 

40 

41 

42 

43 

44 

45 

46 

47 

48 

49 

50 

51 

52 

53 

54 

6 

Cs 

Ba 

' 

Hf 

Ta 

w 

Re 

Os 

Ir 

Pt 

Au 

Hg 

TI 

Pb 

Bi 

Po 

At 

Rn 

55 

56 

. 

72 

73 

74 

75 

76 

77 

78 

79 

so 

81 

82 

83 

84 

85 

S6 

7 

Fr 

87 

Ra 

S8 

• 
• 

Rac 

lioa 

ctiv 

eE 

lem 

ent 

s  .••' 

Transuranium 
Elements 

La 

57 


Ac 

89 


Ce 

58 


Th 

90 


Pr 

59 


iNd 

eo 


Pa 

91 


u 

92 


Pm 

61 


Np 

93 


Sm 

62'' 


Pu 

94 


Eu 


Al 

95 


Gd 

64 


l 


c 


Tb 


Dy 

66 


Ho 

67 


rl 


Bk 


C»fi 


:S 


Er 

68 


Fm 

inn 


Tm 

59 


Yb 

^0 


Md 

101 


Lu 

7! 


No  Lw 


Photoelectric  Experiment 


T36 


Photoelectric  Experiment 


This  transparency  can  be  used  to  help  students  visualize  the  mechanism  of  the  photoelectric  effect 

and  the  method  of  measuring  the  stopping  voltage. 

Overlay  A  A  schematic  diagram  is  presented  of  the  photoelectric  tube  connected  to  a  micro- 
ammeter,  voltmeter,  and  a  power  supply  (the  empty  rectangle  above  the  voltmeter) 
The  curved  emitter  is  on  the  right  and  the  collecting  rod  is  on  the  left.  Note  that  the 
circuit  is  open  between  the  emitter  and  collector. 

Overlay  B  When  the  DC  power  supply  provides  a  positive  bias  on  the  collecting  rod,  the  voltmeter 
mdicates  this  positive  potential.  Photons  of  a  particular  frequency  are  depicted  commg 
in  to  the  emitter.  These  photons  eject  photoelectrons  whose  paths  are  illustrated  by 
arrows.  The  negative  photoelectrons  complete  the  circuit  as  they  accelerate  toward  the 
positive  collector  and  register  a  current  on  the  micro-ammeter.  Remove  this  overlay 
and  introduce  overlay  C. 

Overlay  C  The  bias  on  the  collecting  rod  is  now  made  negative  by  reversing  the  terminals  on  the 
power  supply.  The  voltmeter  indicates  this  reversal.  Now  as  photons  eject  photoelec- 
trons thev  are  slightlv  repelled  by  the  negative  field  surrounding  the  collecting  rod.  As  a 
result  only  the  more  energetic  photoelectrons  get  to  the  collector.  The  resulting  reduc- 
tion in  current  is  shown  as  a  lower  reading  on  the  ammeter.  Remove  this  overlay  and 
introduce  overlay  D. 
Overlay  D  An  increased  voltage  is  applied  to  the  collector.  When  it  is  sufficiently  high  it  will  stop 
all  photoelectrons  (note  zero  reading  on  ammeter).  This  "stopping  ^oltage  can  be 
used  as  a  measure  of  the  maximum  kinetic  energy  of  the  photoelectrons. 


T-36 


m 


i 


W 


--^■i 


Current 


Collector  Voltage 


T-36 


+ 


A 
B 


Current 


Collector  Voltage 


T'36 


A 
C 


■ ' 

■'■4 

;, 

■m 

i 

'W" 

.    i 
■Y 

"i^K^'J 

-4 

W; 

''^P'  ' 

'^^K' 

'  iSP^' ' 

'W- 

"®- 

+ 


■  A^ 


Current 


Collector  Voltage 


T^BS 


Current 


'. 

1 

i 

i 

"^ 

w 

^ 

^^^»^^ 

4 

■M^'. 

itt 


+ 


Collector  Voltage 


j^  Photoelectric  Equation 

CO 


"^ 


T37 


Photoelectric  Equation 


This  transparency  will  be  useful  in  analyzing  data  obtained  from  experiments  dealing  with  stopping 
voltage  (see  T36).  With  it  you  can  arrive  at  the  Einstein  photoelectric  equation. 

Overlay  A  A  plot  of  typical  experimental  data  on  the  voltage  required  between  the  terminals  of  a 
vacuum  phototube  to  reduce  the  tube  current  to  zero.  Remove  this  overlay  and  in- 
troduce overlay  B. 

Overlay  B  Such  data  imply  that  the  maximum  kinetic  energy  of  the  emitted  photoelectrons  is 
proportional  to  the  frequency  of  the  incident  photons.  Remove  this  overlay  and 
introduce  overlay  C. 

Overlay  C  This  shows  Einstein's  interpretation  of  the  data  in  terms  of  a  "work  function"  W,  an 
amount  of  energy  that  must  be  supplied  to  the  electrons  before  they  can  escape  the 
surface.  The  energy  supplied  to  the  electron  by  the  photon  is  hf,  so  the  emission  energy 
KE  ^ax  =  hf-  W. 


> 


T-37 


Experimental  Data  on  "Stopping  Voltages" 


3 

O 
O 


© 


© 


on 


© 


> 


0 


no  emission 


© 


light  frequency  (f ) 


137 


o 
it 


o 

E 


O 

o 


E 


0 


Inference  about  Kinetic  Energy  of  Photoelectrons 


B 


no  emission 


light  frequency  (f) 


T-37 


o 
o 


0 


Einstein's  Interpretation  of  Data 


no  emission — .*— ► 


maximum  KE  of 
photoelectron 


energy  required 
to  escape  surface 


light  frequency  (f) 


Alpha  Scattering 


oo 


T38 


Alpha  Scattering 


This  transparency  is  useful  in  discussing  Rutherford's  alpha  particle  scattering  experiment  and  in 
contrasting  the  Thomson  and  Rutherford  models. 

Overlay  A  A  diagrammatic  sketch  of  the  Rutherford  scattering  experiment.  A  magnifying  glass 
(not  shown)  could  be  moved  around  the  ZnS  screen  to  detect  flashes  produced  by  the 
alpha  particles  as  they  strike  the  screen. 

Overlay  B  Shows  the  expected  results  of  the  scattering  experiment  under  the  assumption  that 
matter  is  composed  of  Thomson  atoms.  Note  that  there  is  very  little  deflection.  Remove 
this  overlay  and  add  overlay  C. 

Overlay  C  These  are  the  results  which  Rutherford  and  his  co-workers  actually  observed.  The 
large  deflections  required  a  completely  new  explanation  of  the  structure  of  the  atom. 
Remove  overlays  A  and  C  and  introduce  overlay  D. 

Overlay  D  Two  representations  of  the  Thomson  model  are  shown.  The  left  side  depicts  large 
(lA  diameter)  spheres  of  positive  electrification  with  negative  electrons  imbedded  in 
them  "Uke  raisins  in  a  muffin".  The  right  side  shows  a  "potential  hill"  which  positive 
alpha  particles  encounter  like  marbles  rolhng  up  a  slope.  Relatisely  small  deflections 
will  be  caused  by  this  hill. 

Overlay  E  The  paths  of  alpha  particles  would  be  only  slightly  deviated  as  they  pass  through 
Thomson  atoms. 

Overlay  F  The  Rutherford  modification  on  the  Thomson  model  will  account  for  the  large  de- 
flections actually  observed  in  experiments.  The  new  model  contains  a  very  small  positive 
nucleus  with  negative  electrons  surrounding  it.  This  allows  a  close  approach  by  alpha 
particles  and  a  consequent  large  deflection.  The  "potential  hill"  model  is  also  adapted 
to  a  very  steep  slope  (greatly  broadened  in  the  diagram)  causing  sharp  deflections  the 
closer  the  particles  approach  the  center.  Remove  overlays  D  and  E  and  introduce 
overlay  G. 

Overlay  G       Alpha  particle  deflections  now  match  observations. 


T-38 


-  ■•^>-i," 


Gold 
Foil 


Alpha  Particle 
Source 


^Sm.^:'--: 


Zinc  Sulfide 
Screen 


ir» 


A 

B 


Results  expected 
with  Thomson  Model 


.^yti-:'-  -p;--!^ 


; '  Y-!*-!--! 


■•*^^ 


5^?:. 


Zinc  Sulfide 
Screen 


**--<-.i»V,:j..'«v. ;; 


Alpha  Particle 
Source 


T'38 


Results  obtained 
by  Rutherford 


A 

c 


!•■■-■ 


<^o\d^ 


Zinc  Sulfide 
Screen 


^ 


Alpha  Particle 
Source 


T-38 


\ 


+ 


Thomson  Model 


TraasB 


^-scattering 


D 
E 


I 


Thomson  Model 


T-38 


+ 


Rutherford  Model 


tT^W 


F 

( 


^-scattering 


+ 


Rutherford  Model 


Energy  Levels  —  Bohr  Theory 


as 


T39 


Energy  Levels  —  Bohr  Theory 


This  transparency  will  be  useful  in  relating  the  Bohr  theory  of  energy  levels  to  the  spectrum  of  hydro- 
gen. It  includes  a  general  treatment  of  the  L\man.  Balmer  and  Paschen  Series  with  a  more  detailed 
coverage  of  the  Balmer  Series. 

Overlay  A  On  the  left  the  Bohr  orbits  for  hydrogen  are  drawn  to  scale  (since  the  radii  should 
increase  according  to  the  expression  Rn  =  0.5 A  li-).  An  energy  level  diagram  is  mcluded 
on  the  right,  and  a  space  for  spectral  Imes  across  the  bottom.  Introduce  overlays  B, 
C  and  D  in  order. 

Overlay  B  Representations  of  electron  quantum  "falls"  from  higher  energy  levels  to  the  ground 
slate.  The  resulting  emission  of  the  Lyman  Series  is  shown  in  the  spectrum  window. 

Overlay  C  The  Balmer  Series  is  produced  by  excited  electrons  falling  back  to  the  second  energy 
level. 

Overlay  D  The  Paschen  Series  is  produced  by  excited  electrons  falling  back  to  the  third  energy 
level.  Remove  overlays  B,  C  and  D.  Add  the  remaining  overlays  in  order. 

Overlay  E  The  Ha  line  in  the  Balmer  Series  is  produced  by  an  excited  electron  falling  from  the 
third  energy  level  to  the  second.  Note  that  the  scale  of  the  spectral  line  representation 
has  been  changed. 

Overlay  F  The  H.j  line  in  the  Balmer  Series  is  produced  by  an  excited  electron  falling  from  the 
fourth  energy  level  to  the  second. 

Overlay  G  The  H-,  line  in  the  Balmer  Series  is  produced  by  an  excited  electron  falling  from  the  fifth 
energy  level  to  the  second. 

Overlay  H  The  H-,  line  in  the  Balmer  Series  is  produced  by  an  excited  electron  falling  from  the 
sixth  energy  level  to  the  second. 

Overlay  I  The  limit  of  the  Balmer  Series  is  approached  as  excited  electrons  from  energy  levels 
higher  than  /i  =  6  fall  back  to  energy  level  2. 


T-39 


T=ai 


f49 


r        1    r      I    F 


♦ 


Lyman  Series 


Balmer  Series 


ultraviolet 


infrared 


limits  of  visible  range 


ft 


B 


c 
I- 


r«: 


i'y^ 


;>'«'; 


m 

■-V. 


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