PTF LS PALS GC BEGELPSLELALL ESAS BAe 1 3 LARD bP epee > tee > 47>) Abe bo! Bae Ob Leh Re AAR ES PLA | Pt AR Ee ea poas as Bahia taeitt ia: th te | Wyin' iy i i pat ie a i) i di ei i pa ti ae a ant Saal ait ij if Hit | CA ' aad ek Al } I hid ih (cy) Wut ut He tt iy 1) F i nit L Wh TERE Robe, Birt tre ih PHT Ly Nha es i Mtisneltt retiee baie Hi iA ai hii i} i) jt + it AM lie bi eb a f\" i ey vy! iii as n Hy | {ii HHA att iy" i) one) : Ih ed iit an l iD) yaa + ba i Hythe es \) pa Hh, iil UY, j ake Ait if 1 ee) | | i ' mp i) mS tag Isle iy, Wa it isthe: } | i, | i} 4 ¥ ( Ue: a Mt We ci se a ! By, iu eh j a aate r ; | } jaitley | ate A Peed a PhD i Esra | ea i ee i 1c) al ! a prey } aie \ i | | \ Oi qa | ¥ ten — vet Nathan = pers 2 are ~ + os —~ 1 — iP ages Sim ios im Ht p> ey bs! Af, EEE PEL AN z A A tn ; Sy } To) \ooeeraieur 7 enh ue at ! T i i f ' ib), = wad WA ey ty i | ie iN vl ih ay ih NN ALE ee a “ant i i en ‘ aN t\ Cat on i ji au ih i i i it i A ave 3 Ha A | net, a i i: ian (4, Hints tainted 4 Milust ci maine Aisi ticettd Peete LG PEE RRLL Th OX and —_—— = eens —_— — a a ae ne =) a i tame met = = Spotter Se a = a, Spe _~ Z a = a —_- 7 ete ee — ae aa Se ee se Na 2 —— eer a a me ne ced | SW a i } airs 7 | baet ys) Rs! VT sah ea (es A te a - ré 1 sili a, He Y cae se She, 2 ws tra ote 4 ory he VALUABLE WORKS GOULD AND LINCOLN. 59 WASHINGTON STREET, BOSTON. ANNUAL OF SCIENTIFIC DISCOVERY FOR 1850; or, Year-Book of Facts im Science and Art, exhibiting the most important discoveries and improvements in Mechan- fics, Useful Arts, Natural Philosophy, Chemistry, Astronomy, Meteorology, Zoology Botany, Mineralogy, Geology, Geography, Antiquities, &c. ; together with a list of recent Scientific Publications ; a classified list of Patents; obituaries of eminent Scientific Men ; an index of important papers in Scientific Journals, reports, &c. Edited by Dayip A. WELisS, and GEORGE PLiss, Jk. With Portrait of Prof. Agassiz. 12mo,..cloth,....1,25 paper covers,....1,00 ‘This work will be issued annually, and the reading public may easily and promptly possess themselves of the most important facts discovered or announced in these departments. As it is not intended for scientific men exclusively, but to meet the wants of the general reader, it has been the aim of the Editors that the articles should be brief and intelligible toall. The Editors have received the approbation, counsel and personal contributions of Professors Agassiz, Horsford, and Wyman, of Harvard University, and many other scientific gentlemen. FHE ANNUAL OF SCIENTIFIC DISCOVERY, FOR 1851; Edited by Davin A. WELLS, and GEORGE BLiss, JR. With Portrait of Prof. Silliman. 12mo,..cloth,....1,25 Paper covers,...-1,00 ear Each volume of the above work is distinct in itself, and contains entirely new matter. THE POETRY OF SCIEN CE ; or, The Physical Phenomena of Nature. By RoBERT Hunt, author of *‘ Panthea,’”’ “ Researches of Light,” ete. First American, from the second London edition. 12m0,.....cccccccccccccccccccccccsccccce ----Cloth,....1,25 “ The author, while adhering to true science, has set forth its truths in an exceedingly captivating style.”—Commercial Advertiser. “We are heartily glad to see this interesting work re-published in America. It isa book that is a book.”—Scientific American. “Tt is one of the most readable, interesting, and instructive works of the kind, that we have ever peer.” —Phil. Christian Observer. CYCLOPADIA OF ANECDOTES OF LITERATURE AND THE FINE ARTS. Containing a copious and choice selection of Anecdotes of the various forms of Literature, of the Arts, of Architecture, Engravings, Music, Poetry Painting and Sculpture, and of the most celebrated Literary Characters and Artists of different countries and Ages, etc. By Kazuitr Arvine, A. M., author of “‘ Cyclopzedia of Moral and Religious Anecdotes,” OCLAVO,cccccccccccccccccccccedeccccccccccccccsceccsesecreccsccccore ClOth, im Ure28 CYCLOPADIA OF SCIENTIFIC ANECDOTES, containing a selectica rospecting the various Sciences and Mechanical Arts, and of their most distinguished Votaries. By KazuitT ARVINE, A. M., author of “ Cyclopedia of Moral and Religious Anecdotes.” One VOlUME,....ccrcecccocccccccccvcccressccccccesscccscccssesesssecllOu, 1 press. The two works together, will embrace the best Anecdotes in Ancient and Modern collections, as well as in various Histories, Biographies and Files of Periodical Literature, §c. The whole classified under appropriate subjects, alphabetically arranged, and each supplied with a very fall and perticular Index of topicsand names. Both the above volumes will first be published in numbers —sixteen in all, at 25 cents each—making together two large octavo volumes, of about 700 pages each, illustrated with numerous fine engravings. The first number will be issued about the firsé ef April, to be continued semi-montk!y until completed. VALUABLE SCIENTIFIC WORKS. .AKE*SU PERIOR : its Physical Character, Vegetation and Animais, compared with those ¢* other and-similar regions, by L. AGAssiz, and contributions from other eminent Scientific Gentlemen. With a Narrative of the Expedition, and illustrations by J. E. Cabot. One volume octavo, elegantly illustrated,.....+ssessceceee coe eClOth,. «+ 03,50 The illustrations, seventeen in number, are in the finest style of the art, by Sonrel; embracing take and Landscape Scenery, Fishes, and other objects of Natural History, with an outline map of Take Superior. This work is one of the most valuable scientific works that has appeared in this country. Nmbodying the researches of our best scientific men, relating to a hitherto comparatively unknown region, it will be found to cortain a great amount of scientific information. CHAMBERS’ CYCLOPADIA OF ENGLISH LITERATURE. A Selection of the choicest productions of English Authors, from the earliest to the present time. Connected by a Critical and Biographical History. Forming two large imperial octavo volumes of 700 pages each, double column letter press; with upwards of 300 elegant Illustrations. Edited by RoBERT CHAMBERS,......se.e0. «----embossed cloth,....5,00 cloth, full gilt, extra,....7,5C sheep, extra, raised bands,....6,00 The work embraces about one thousand Authors, chronologically arranged and classed as Poets, Historians, Dramatists, Philosophers, Metaphysicians, Divines, etc., with choice selections from their writings, connected by a Biographical, Historical, and Critical Narrative; thus presenting a eomplete view of English Literature, from the earliest to the present time. Let the reader open where he will, he cannot fail to find matter for profit and delight. The Selections are gems,— imfinite riches in a little room,—in the language of another “A WHOLE ENGLISH LIBRARY FUSED DOWN INTO ONE CHEAP BOOK!” ea- The AMERICAN edition of this valuable work is enriched by the addition of fine steel and mezzotint Engravings of the heads of SHAKSPEARE, ADDISON, BYRON; a full length portrait of Dr. JOHNSON; and a beautiful scenic representation of OLIVER GOLDSMITH and Dk. JOHNSON. These important and elegant additions, together with superior paper and binding; render the AMERICAN, superior to all other editions. CHAMBERS’ MISCELLANY OF USEFUL AND ENTERTAINING KNOWL=e EDGE. Edited by WiL1AM CHAMBERS. With elegant Llustrative Engravings. 10 vols. cloth,.... 7,50 cloth, gilt,....10,06 library, sheep,....10,00 ea~ This work has been highly recommended by distinguished individuals, as admirably adapted to Eamily, Sabbath and District School Libzaries. “Tt would be difficult to find any miscellany superior or even equal to it; it richly deserves the epithets ‘useful and entertaining,’ and I would recommend it very strongly, as extremely well adapted to form parts of a library for the young, or of a social or circulating library, in town or eeuntry.”—George B. Emerson, Esq., Chairman Boston School Book Committee. CHAMBERS’ PAPERS FOR THE PEOPLE. 12mo, in beautiful ornamented COVETB.c cece e rere reer e seers eee se see e ee Sess sere erases esses eeeet sessseseses® “sees This series is mainly addressed to that numerous class whose minds have been educated by the tmproved schooling, and the numerous popular lectures and publications of the present day, and who consequently crave a higher kind of Literature than can be obtained through the existing cheap periodicals. The Papers embrace History, Archeology, Biography, Science, the Industrial and Fine Arts, the leading topics in Social Economy, together with Criticism, Fiction, Personal Narrative, and other branches of Elegant Literature, each number containing a distinct subject. The series will consist of sixteen numbers, of 192 pages each, and when completed, will make eight handsome volumes of about 400 pages each. VALUABLE SCIENTIFIC WORKS. THE FOOT-PRINTS OF THE CREATOR ; or, the Asterolepsis of Stro: with numerous illustrations. By Hue MILLER, author of “The Old Red Sandstone,” &c. From the third London Edition. With a Memoir of the author, by Louis Agassiz. T2M0 ye ie ccc ccecccccvccccccccsecccccccccccccccccccccccccccesccccsesceClOth,. «+ 21,00 Dr. BrcKLAnND, at a meeting of the British Association, said he had never been so much aston- ished in his life, by the powers of any man, as he had been by the geological descriptions of Mr, Miller. Tkat wond2rful man described these objects with a facility which made him ashame? of the comparative meagreness and poverty of his own descriptions in the “ Bridgewater Treatises,” ~ which had eost him hours and days of labor. He would give his left hand to possess such powera of description as this man; and if it pleased Providence to spare his useful life, he, if any one, would certainly render science attractive and popular, and do equal service to theology and geology. “ Mr. Miller’s style is remarkably pleasing; his mode of popularizing geological knowledge une surpassed, perhaps unequalled; and the deep reverence for Divine Revelation pervading all, adds interest and value to the volume.”—New York Com. Advertiser. “The publishers have again covered themselves with honor, by giving to the American public, with the Author’s permission, an elegant reprint of a foreign work of science. We earnestly bespeak for this work a wide and free circulation, among all who love science much and religion more.”—Puritan Recorder. THE OLD RED SANDSTONE ; or, New Walks in an Old Field. By Hueco Maer Illustrated with Plates and Geological Sections. 12mo,.........++....+-.cloth,....1,00 “Mr. Miller’s exceedingly interesting book on this formation is just the sort of work to render any subject popular. It is written in a remarkably pleasing style, and contains a wonderful amount of information.’ — Westminster Review. “Tt is withal, one of the most beautiful specimens of English composition to be found, coavey- ing information on a most difficult and profound science, in a style at once novel, pleasing and elegant. It contains the results of twenty years close observation and experiment, resulting in an accumulation of facts, which not only dissipate some dark and knotty old theories with regard to ancient formations, but establish the great truths of geology in more perfect and harmonious con- sistency with the great truths of revelation.”’— Albany Spectator. PRINCIPLES OF ZOOLOGY : Touching the Structure, Development, Distribution, and Natural Arrangement of the Races oF ANIMALS living and extinct, with numerous illustrations. For the use of Schools and Colleges. Part I., ComPARATIVE PHYSIOLOGY. By Louis AGAssiz and AuGcusTus A.GouLD. Revised edition. 12mo,...cloth,....1,# “This work places us in possession of information half a century in advance of all our elemens tary works on this subject. * * No work of the same dimensions has ever appeared in the English language, containing so much new and valuable information on the subject of which ! treats.”—Prof. James Hall, in the Albany Journal. “ A work emanating from so high a source hardly requires commendation to give it currency. The volume is prepared for the student in zoological science; it is simple and elementary in its atyle, full in its illustrations, comprehensive in its range, yet well condensed, and brought into the Barrow compass requisite for the purpose intended.”—Silliman’s Journal. “The work mzy safely be recommended as the best book of the kind in our language.”—Chrese tian Examiner. “Tt is not a mere book, but a work—a real work in the form of a book. Zoology is an interesting science, and here is treated with a masterly hand. The history, anatomical structure, the nature and habits of numberless animals, are described in clear and plain language and illustraged with innumerable engravings. It is a work adapted to colleges and schools, and no young man should be without it.”— Scientific American. PRINCIPLES OF ZOOLOGY, PART II. Systematic Zoology, in which the Prin- ciples of Classification are applied, and the principal groups of animals are briefly ’ characterized. With numerous illustrations. 12mo,...........+..++-[im preparation, VALUABLE SCIENTIFIC WORKS. YHE EARTH AND MAN: Lectures on CoMPARATIVE PHYSICAL GEOGRAPHY, in its relation to the flistory of Mankind. By ARNOLD Guyot, Professor of Physical Geography and Ifistory, Neuchatel. Translated from the French, by Prof. C. C. FELTON, with illuse trations. Second thousand. 120. ee veecccccccerccsccscccscccscesesClOthye. 01,29 “ 'Thsse who have been accustomed to regard Geography as a merely descriptive branch of learns ing, drier than the remainder biscuit after a voyage, will be delighted to find this hitherto un- attractive pursuit converted into a science, the principles of which are definite and the results conclusive.”—North American Review. “ The grand idea of the work is happily expressed by the author, where he calls i the geographe tcal march of kistory. Faith, science, learning, poetry, taste, in a word, genius, have liberally contributed to the production of the work under review. Sometimes we feel as if we were studying « treatise on the exact sciences; at others, it strikes the ear like anepic poem. Now it reads like history, and now it sounds like prophecy. It will find readers in whatever language it may be published.’—Christian Examiner. “The work is one of high merit, exhibiting a wide range of knowledge, great research, and @ philosophical spirit of investigation. Its perusal will well repay the most learned in such subjects, and give nsw views to al, of man’s relation to the globe he inhabits.”—Silliman’s Journal. COMPARATIVE PHYSICAL AND HISTORICAL GEOGRAPHY ; or, the Study of the Earth and its Inhabitants. A series of graduated courses for the use of Schools. By ARNOLD GuyoT, author of ‘“ Earth and Man,” etc. The series hereby announced will consist of three courses, adapted to the capacity of three dif- ferent ages and periods of study. The first is intended for primary schools, and for children of from seven to ten years. The second is adapted for higher schools, and for young persons of from ten to fifteen years. The third is to be used as a scientific manual in Academies and Colleges. Each course will be divided into two parts, one of purely Physical Geography, the other for Eth- nography, Statistics, Political and Historical Geography. Each part will be illustrated by a colored Physical and Political Atlas, prepared expressly for this purpose, delineating, with the greatest care, the configuration of the surface, and the other physical phenomena alluded to in the corres- ponding work, the distribution of the races of men, and the political divisions into States, §c., §c. The two parts of the first or preparatory course are now in a forward state of preparation, and will be issued at an early day. MURAL MAPS: aseries of elegant colored Maps, exhibiting the Physical Phenomena of the Globe. Projected on a large scale, and intended to be suspended in the Recitation Room. By ARNOLD GUYOT..-cceceecccccccccccccceccccccccsceccosce afin preparation] KITTO’S POPULAR CYCLOPADIA OF BIBLICAL LITERATURE, OCon- densed from the larger work. By Joun Kirrto, D. D., F. S. A., author of “ The Pictoral Bible,” “‘ History and Physical Geography of Palestine,’ Editor of “‘The Journal .of Sacred Literature,” etc. Assisted by numerous distinguished Scholars and Divines,, British, Continental and American. With numerous illustrations. One yolum octavo, Rey ics .otvac.-.escetnward. coneahoctts Met: aie cee THE PoPpuLAR BIBLICAL CYCLOPZDIA OF LITERATURE is designed to furnish a DICTIONARY OF THE BIBLE, embodying the products of the best and most recent researches in Biblical Liter ature, in which the Scholars of Europe and America have been engaged. The work, the result of immense labor and research, and enriched by the contributions of writers of distinguished eminence in the various departments of Sacred Literature,—has been, by universal corsent, pronounced the best work of its class extant; and the one best suited to the advanced knowledge of the present day in all the studies connected with Theological Science. -The Cyclopxdia of Biblical Literature from which this work is condensed by the author, it published in two volumes, rendering it about twice the size of the present work, and is intended, gays the author, more particularly for Ministers and Theological Students; while the Povular Cyclopedia is intended for Parents, Sabbath School Teachers, and the great body of the religious public. It has been the author’s aim to avoid imparting to the work any color of sectarian or denominational bias. On such points of difference among Christians, the Historical mode of treatment has been adopted, and care has been taken to provide a fair account of the arguments which have seemed most conclusive to the ablest advocates of the various opinions. The Pictorai Mlustrations — amounting to more than three hundred —are of the very highest order of the ax . - WORES RECENTLT PUBLISHED: ARVINE’S CYCLOPADIA OF ANECDOTES OF LITERATURE AND THE FINE ARTS. Containing a copious and choice selection of Anecdotes of the various forms of Literature, of the Aris, of Architecture, Engravings, Musio, Poetry, Painting and Sculpture, and of the most celebrated Literary Characters and Artists of different countries and ages, etc. Elegantly Illustrated. This is a most amusing, instructive and entertaining work. The anecdotes are of a high order, and of such wonderful variety as to furnish something of interest for every class of readers, upon almost every possible topic. The Christian Times says, ‘‘ The work will be one of rare interest to the scholar and tu the general reader. It is illustrated with engravings, and finely printed, the pages resem- bling in size and form the noble edition of ‘Chamber’s Cyclopsdia,’ by the same pub Hshers.”’ Tie Carpet Bag says, ‘*‘ This is one or the best books of the season, and it presents, ina compact form, a thousand wise, witty and remarkable things, that might otherwise never have reached that inordinate public, which, like the daughter of the ‘horse leech’ we read of, is continually craving.” The work will first be published in eight numbers, at twenty-five cents eacr which together will make an elegant royal octavo volume of about 780 pages. The first number has just been issued, and the others will follow once in two weeks till com- pleted. A ¥Y/REATH AROUND THE CROSS; or, Scripture Truth Illustrated. By Rey. A. Morton Brown. With an Intropuction, by Rev. JoHN ANGELL JAMES. With an elegant Frontispiece. 16mo. cloth, 60 cents. The Zion’s Herald says, “In a richly evangelical style the author illustrates the essential truths of religion by their relation to the Cross. The plan of the work is happy, and its execution able.” The Albany Spectator says, *‘We have not seen a book for many a day with a more beautiful iitle than this. And the frontispiece is equally beautiful, presenting Christ as cheering the prospect. Leaving the field of mere controversy to others, the author at once approaches and leads all with him to the cross; exhibits it as the means of our justifica- tion, sanctification and eternal blessedness; aims to cultivate the heart rather than the intellect ; takes the enquirer from the sign to the thing sanctified ; and gives both edificat‘on and consolation to enquiring sinners.” GUYOT’S MURAL MAP OF THE WORLD, on a large scale, (5 by 7 feet,) for the Recitation Room. Printed in three colors. Price, mounted, $10,00 THE NATURAL HISTORY OF THE SPECIES; its typical forms and primeval distribution. With elegant illustrations. By Caantzs Hamrron Smirz. With an Inrropuction, containing an abstract of the views of Bluimenbach, Prichard, Bachman, Agassiz, and other writers of repute, by SAMUEL KNEELAND, Jr, M.D. 12mo. cloth, $1,25 THE EXCELLENT WOMAN, as described in the Book of Proverbs. With splendid Illustrations, and an Introduction, by Rev. Wiauam B. Spraeuz, D. D. 12mo. cloth, extra, in presa iG Anelegant Gift Book. NOVELTIES OF THE NEW WORLD, an Account of the Adventures and Discoveries of the First Explorers of North America. 12mo. cloth, ™ press. Being second volume of BANVARD’s SERIES OF AMERICAN HIsToRIES “OUNG AMERICANS ABROAD: or Vacation in Europe; embodying the results ef atour through Great Britain, France, Holland, Belgium, Germany and Switzerland, with elegant Hlustrations. iémo. cloth, t press DICTIONARY FOR THE PEOPLE. WEBSTER’S Q@UARTO DICTIONARY, WWAWMRmwD SDea Containing three times the mutter found tn ann other oe Dictionary comptley tw this counirp, or any Abridgment of this Work. Geographical Cable of 12,000 Names, Ellustratiobe Quotations, and other peculiarities and abbuntages found in no other WMork, net is sold at a trifling abbance abobe the price of other and limited Dictionaries. Tre Jegislatureof New York have just passed an Acfto furnish this work in the common schoois of the State. war The following is an extract from the Report on the subject, by the “ Committee on Literature.” “Your committee regard it as superfluous labor to enlarge upon the superiority of this Diction- ary; this is attested by the general circulation which this work has gained in this country,which is believed to be unprecedented for a work so expensive, “That this work is peculiarly valuable for common schools, is, in the opinion of your commiitee, very evident. There is no branch of knowledge, in which it is so important, that the 750,000 children of this State who are taught in them should be perfected, as in the knowledge of their own lan- guage. There is no end so important to the education of the common mind as to use this our com-~ mon language with correctness, ease and elegance, and to attain which we should make every possible facility readily accessible toall. And,in the opinion of your committee, there is no one pook which furnishes so many facilities for this purpose as Webster’s Unabridged Dictionary. The habit of referring to it will lead every scholar to a knowledge of this rich mine of wealth in- tellectual ; and as he uncovers its treasures, his mind will be enlerged by the variety of knowledge which is condensed in the definitions of the familiar words he uses. The habit of reflection too, will be matured, by being employed on objects so entirely within his reach as the words which he spells, and reads and usesin speech. If he be once taught the habit of reflecting on words, he will 5000 learn to reflect on the thoughts which these words represent.” (From Hon. J.C. Spencer,} ALBANY, June 18th, 1851. More than twenty years 4 I procured the Quarto edition, and have used it constantly ever since. My pursuits in life have rendered it necess to consult it frequently, as well as other works of 2 kindred or similar character, particularly Dr. Johnson’s Quarto, of the latest and best edition, Richardson’s Dictionary, Crabbe’s Synonyms, and Horne Took’s Diversions of Purley. In professional, political, and literary discussions, the turning point of the argument has often been the exact meaning of words, as ascertained not only from their use, but from their derivation: while in many cases, perhaps in the majority of them, the works referred too have failed to give the desired information, that of Dr. Webster has always furnished precisely what has been desired, and I have long felt individually indebted to the illustrious author, for the labor and time he has saved me by his unwesred patience, profound learning, and unsurpassed industry. It is wnquestionably the very best Dictionary of our language extant. It is a model of copious- ness and precision,and its great accuracy in the definition and derivation of words, gives it an authority that no other work on the suject possesses. It is constantly cited and relied on in our Courts of Justice, in our Legislative bodies, and in public discussions, as entirely conclusive. shea Q, : “Yn revising and publishing an enlarged edition of this invaluable work at so cheap a rate as to bring it within the reach of aknost every family, you have rendered AN ESSENTIAL SERVICE TO MANKIND.” i fi A Dictionary is the last book which a scholar ever wants to have abridged, the process being ure to cut off THE VERY MATTER WHICH HE MOST VALUES,’—Chronotype. Published by G. & C. MERRIAM, Springfield, Mass., and for sale by Booksellers generally. AOGQUATVE Oty pt hens ~ | SCIENTIE or I hitig Sh 47 ay . 7 be «eae | A LIST OF RECENT SCIENTIFIC PUBLICATIONS; A CLASSIFIED LIST OF PATENTS; OBITUARIES OF EMINENT SCIENTIFIC MEN; NOTES ON THE PROGRESS OF SCIENCE PURING THE YEAR 1ésg, ETO, ETO. ‘er a ; EDITED BY DAVID A. WELLS, A. M. | BOSTON; GOULD AND LIN@®OLN,- 59 WASHINGTON STREET. ites ll oe 853. ry 4xveil 5 5 Po ~g 2 ; 5) F y j fpr f F Bee: ah 2 Spine ae Sees / Gould & Lincoln, Ihoston, ANNUAL or SCIENTIFIC DISCOVERY: YEAR-BOOK OF FACTS IN SCIENCE AND ART, FOR 1802. EXHIBITING THE MOST IMPORTANT DISCOVERIES AND IMPROVEMENTS IN MECHANICS, USEFUL ARTS, NATURAL PHILOSOPHY, CHEMISTRY, ASTRONOMY, METEOROLOGY, ZOOLOGY, BOTANY, MINER- ALOGY, GEOLOGY, GEOGRAPHY, ANTIQUITIES, &e. TOGETHER WITH A LIST OF RECENT SCIENTIFIC PUBLICATIONS; A CLASSIFIED LIST OF PATENTS; OBITUARIES OF EMINENT SCIENTIFIC MEN; NOTES ON THE PROGRESS OF SCIENCE DURING THE YEAR 1852, ETC. ETC. EDITED BY DAVIDA. WELLS; #4. °M, BOSTON: GOULD AND LINGOL®M, 59 WASHINGTON STREET. 1853. Entered according to an Act of Congress, in the year 1858, Br GOULD & LINCOLN, In the Clerk’s Office of the District Court of the District of Massachusettr. \ G. C. Rann, Printer, 8 Cornhill, Boston. PREFACE. THE present number completes the fourth yearly vol- ume of the Annual of Scientific Discovery. In its preparation, the Editor has followed the general plan indicated and developed in the former numbers of the work. : The mental activity at present displayed in developing new principles and modifying old ones, to meet the wants of practical industry, in cheapening and improving the production and preparation of all raw materials, and disseminating useful knowledge, is probably greater than at any former period of the world’s history. Under these circumstances, the labor of preparing an annual retrospect has been greatly increased. The Editor has, however, endeavored to present as faithful an abstract of the progress of science and the useful arts during the year eighteen hundred and fifty-two, as the limits of the present volume would allow. The field for 26 (oF 4 PREFACE. enlargement is ample, and would willingly be entered upon, were sufficient promise of encouragement afforded by the public. The annual summary of ‘“ Notes by the Editor on the Progress of Science ” has been considerably enlarged, and embraces several topics of interest, which could not conveniently be included in the body of the work. We present our readers for 1853 with a portrait of Prof. ALEXANDER Dauuas BacuHeE, President of the American Association for 1850-51, and Superintendent of the United States Coast Survey. Boston, February, 1853. NOTES BY THE EDITOR ON THE PROGRESS OF SCIENCE IN 1852. In reviewing the progress of Science during the past year, 1852, it is especially to be remarked, that the annual record of discoveries in all the branches of science and the useful arts, is more characterized by its utility than by its brilliancy. The following remarks, appositely observed of the transactions of the British Association for 1842, apply equally well to the general scientific progress of the year 1852 :— “ We have this year no great scientific novelty, theory, or discovery, brought upon the tapis, and claim- ing the attention of philosophers. There is no voyage to the South Pole to be promoted, — there is no hypothesis of glaciers to astonish the world, — there are no observations of the nature of storms to throw a light on those terrible visitations, —there is no doctrine and measurement of waves, or on the form of vessels, — there is no new feature in the grand research into the mysteries of magnetism, —in short, except the idea of following up the investigation of meteorological phenomena by means of balloons, we have heard of nothing very particular. Let it, however, be understood, that in all branches of science, steady progress has been made and recorded. Data of high consequence are collected, both to check future mistakes, and advance future information. Induction, the true basis of all truth, will flourish upon these ; and therefore, though there is nothing extraordinary in this stage of the onward journey, the distances and milestones are fairly marked so far, and the prospects in the distance are rendered much more clear and distinct. The way to the field is beaten, and its ample survey defined. There is nothing needed but to march on, take time, and labor to a useful end.” Europe, as if her energies were overtasked by the demands of the Great Exhibition year of 1851, has given us in 1852 nothing particularly new, 6 NOTES BY THE EDITOR striking, or wonderful ; no new application of science to art,and no mechan- ical or chemical discovery of striking interest have been announced in the United States during the same period. Notwithstanding, many great plans are now in the process of development, many new ideas are germinating, and many old ones, which have long slumbered in the domains of theory are passing into real, substantial, practical facts. During the year 1852, more than one thousand patents for discoveries, inventions, and applications, “new and useful” were granted by the United States. More than three- fourths of these patents were granted to citizens of the five states of Massa- chusetts, Connecticut, New York, Pennsylvania, and Ohio. As many as three applications for patents from the same sources were probably rejected, where one was granted. The public journals are filled with accounts of the commercial prosperity induced by the gold discoveries .of Australia and ‘California; but the journalists and the public little know how many secret springs and incentives to invention and practical application, the same influx of gold, and the consequent revival of manufactures, has occasioned. There is an intensity of mental action and thought, devoted to the realiza- tion of the useful and the new, now pervading some portions of our country, especially in Massachusetts, the like of which the world has never before witnessed. The American operatives, mechanics and manufacturers, who have in vain sought protection from the National Government, are now creating protection for themselves; educated industry, and skill are rapidly forming a tariff, which in a few years will undoubtedly put foreign compe- tition at defiance. Another curious fact in relation to this subject, is the intensity of competition which the mental activity referred to has engen- dered. An original thought, or a new idea, admitting the possibility of a practical application, when once promulgated becomes common property. A hundred minds at once seize upon it, elaborate it, perfect it. The engines of Ericsson had barely made a successful revolution before an improvement by another was announced in the New York Journals. The U.S. Court were recently occupied at Boston with a closely contested case respeeting the validity of two patents for cotton-gins; the trial had not concluded before a new gin was put in operation which will undoubtedly render all others valueless. The discussions and experiments in England respecting the manufacture of flax by new processes, have awakened great interest in the subject in the United States, and more is probably known here at pres- ent in relation to this matter, than in Europe. We believe the day is not far distant, when the manufacture of flax will be conducted in the United States upon a most gigantic scale. We turn, however, from these generali- zations to some of the more particular events of the past year. The annual meeting of the American Association, for 1852, appointed to be held in Cleveland, in August, was postponed on account of the prevail- ON THE PROGRESS OF SCIENCE. T ing cholera in that region, and the great heat of the season. The place and time for the next regular meeting have not yet been determined by the Executive Committee. : The twenty-second annual meeting of the British Association, for the Advancement of Science, was held at Belfast, Ireland, September Ist ; Col Sabine presiding. The attendance was somewhat less numerous than in 1851, and the papers read, had for the most part, a local rather than a gen- eral*interest. Among the important measures taken by the Association, was a strong representation to the British Government, respecting the importance of sending out an expedition for the purpose of studying the phenomena of tides, especially those of the Atlantic Ocean. The President elected for 1853 is William Hopkins, President of the Geological Society, and of the Cambridge Philosophical Society. From the annual address of the President we copy the following passa- ges: —‘‘ Hitherto the researches of Sidereal Astronomy, even in their widest extension, had manifested the existence of those forces only with which we are familiar in our own solar system. The refinements of modern observation and the perfection of theoretical representation had assured us that the orbits in which the double stars, immeasurably distant from us, revolve around each other, are governed by the same laws of molecular attraction which determine the orbits of the planetary bodies of our own system. But the Nebulz have revealed to us the probable existence in the yet more distant universe, of forces with which we were previously unac- quainted. The highest authorities in this most advanced of all the sciences acknowledge themselves unable even to conjecture the nature of the forces which have produced and maintain the diverse, yet obviously systematic, arrangement of the hosts of stars, which constitute those few of the Spiral Nebulz which have been hitherto examined. Hence the importance of increasing our knowledge of the variety of forms in which the phenomena present themselves, by a similar examination of the Southern Heavens to that which Lord Rosse is accomplishing in the Northern Heavens. In addition we can scarcely forbear to covet at least an occasional glance at bodies which from their greater proximity have more intimate relations with ourselves, and which, when viewed with so vast an increase of optical power, may afford instruction of the highest value in many branches of physical science. In our own satellite, for example, we have the opportunity of studying the physical conformation and superficial phenomena of a body composed, as we believe mainly at least, of the same materials as those of our own globe, but possessing neither atmosphere nor sea. When we reflect how much of the surface of the earth consists of sedimentary deposites, and consequently ‘how large a portion of the whole field of geo- logical research is occupied with strata which owe their principal charac- 2 8 NOTES BY THE EDITOR teristics to the ocean in which they were deposited, we cannot but anticipate many instructive lessons which may be furnished by the points of contrast, as well as of resemblance, which the surface of the moon, viewed through Lord Rosse’s telescope, may present to the best judgment we are able to form of what the appearance of the earth would be if similarly viewed, or — with ‘what may be more difficult perhaps to imagine — what we may suppose the earth would appear if it could be stript of its sedimentary strata, which conceal from us for the most part the traces of that internal aétion which has played so large a part in moulding the great outlines of the present configuration of its surface. It is understood that Lord Rosse him- self participates in the wish that such an examination of the surface of the moon should be made, and, should the desire of the Association be expressed to that effect, is willing to undertake it in conjunction with one or two other gentlemen possessing the necessary physical and geological knowledge. It will be for the Association to determine the form in which a report on the “Physical Features of the Moon, compared wath those of the Earth,” may most appropriately be requested. The German Association for the advancement of Science held its 29th annual meeting at Wiesbaden, commencing September 18th. The attend- ance was very numerous, nearly 800 members being present. Dr. Fresen- ius was President of the Association, and Prof. Sandberger, Secretary. A public address was delivered by Prof. Nees von Esenbeck, of Breslau. To be a privileged member of this Association, with the right of speak- ing and voting in the meetings, it is necessary to have written some work bearing on natural history, physics, or medicine; but to become a temporary associate, with the right of being present as a listener merely at all the scientific meetings, as well as of taking part in all the festive social reunions, is free to every one on the very moderate payment of two Prussian dollars. The next meeting of the Association was appointed to be held at Tubingen. P A “Hygienic Congress,” consisting of gentlemen of different countries, who take an interest in promoting the health of towns and the welfare of the working classes, was held in Brussels, in September About 200 gen- tlemen, Belgians and foreigners, were present, —nearly all the Scientific Societies of Europe being represented. The work was done in four differ- ent sections :— one, charged to occupy itself with workmen’s houses, baths, wash houses, and hospitals; another, with sewers, &c., the distribution of water, and ventilation; the third, with the organization of public health, the maintaining of children, interments, and cemeteries; and the fourth, with the adulteration of food, the labor of children in work shops, and prostitution. The Scientific Congress of France, held its annual session at Toulouse, ON THE PROGRESS OF SCIENCE. 9 commencing on the 13th of September. Count de Peyronnet, of the Acad- emy of Bordeaux, was elected President of the meeting. A new Geological Institufe has been formed during the past year at Vienna, the principal object of which will be, the production of a series of geological maps of the Austrian dominions :— the whole of which gigantic undertaking may be completed, it is to be hoped, within thirty years, — beginning} with Austria proper, and proceeding gradually to the Italian, Hungarian, and Bohemian dominions. The institution is under the direc- tion of Prof. Haidinger. A circular has been issued by several of the prominent geologists of our country, proposing the organization of an Association of American geolo- gists, somewhat on the plan of the Geological Societies of England and France. It is not intended, that the members of the society should sever their connection with the American Association, but it is thought, that by means of meetings or sittings of the Society, or of its Committees, to be held at regular and irregular intervals, to be fixed by the Association, and at places where interesting and disputed questions arise, or even of ambu- latory character, in the field, quicker and surer results would be arrived at; and the conclusions would be more satisfactory at home, as well as more respected abroad. A National Agricultural Society composed of delegates from the different States and Territories, has been formed at Washington, during the past year. Marshall P. Wilder, of Massachusetts, has been elected President, with a Vice President from each State. The French Government have recently instituted a General Horticultural Society for all France, which is to consist of titular and honorary members, and of an unlimited number of foreign correspondents. It is to occupy itself with all matters connected with horticultural science; to publish a monthly volume of “ annals” thereon ; to give prizes for elementary works ; and to grant certificates of horticultural merit. A most noble and princely donation to the cause of science and art has been made by Mr. Peter Cooper, of New York. The plan proposed is essentially educational in its features, and has in view the moral and intel- lectual elevation of the youth of the city of New York.- A large building is now erecting in New York as the nucleus of the institution, the cost of which, together with the land will amount to $300,000; the building is to contain a “sculpture and picture gallery, exhibition hall, library, lecture- room and observatory. Books, apparatus, instructors, &c., are to be provided, and it is intended that the institution shall enjoy an annual income of $25,000.” Among the other donations made in behalf of Science in the United States during the past year, we would mention the following : — George 10 NOTES BY THE EDITOR Peabody, Esq., the eminent London banker, has given to the town of Dan- vers, Mass., which is his native place, the sum of twenty thousand dollars for the establishment of a lyceum and library and the erection of the neces- sary buildings. The sum of $50,000 has also been given by Joshua Bates Esq., of London, to the city of Boston, to aid in the establishment of a free public library. Dr. George C. Shattuck, of Boston, has presented Dartmouth College with $7,000, to be used in the erection of an observatory, on condition that the trustees of the college will raise the further sum of $8,000 for the pur- chase of instruments. The sum of $1,000 has been given by Hon. Jonathan Phillips, of Boston, to the American Academy, for the purpose of defraying the expense of its publications. The expenses of a new Expedition in search of Sir John Franklin and for Arctic exploration, are to be defrayed by Henry Grinnell, of New York, and George Peabody, of London. Five hundred dollars have been voted by the Board of Underwriters to the Geographical Society, at its solicitation, to be devoted to a series of magnetic observations to be made under the direction of Dr. Kane, the Arctic Explorer on his next expedition. Within a few years, a number of projects have been set on foot in New York, for the establishment of an astronomical observatory in that city or vicinity, but they have all failed, mainly from want of means and encour- agement. A new enterprise has recently been started, with a fair prospect of success. The “American Observatory Association,” issue a prospectus for the establishment of an Observatory on the Palisades, above Fort Lee, on the basis of a joint-stock association, self-governed. Four hundred shares are to be offered at twenty-five dollars each, and the names of many prominent citizens of New York are pledged to the work. The originator of the plan is Mr. Leon Lewenberg, of New York, who proposes to endow. the Observatory with a sufficient tract of land, one mile distant from Fort Lee. He also offers a Telescope of his own manufacture, as an additional. donation. The building to be erected will be 150 feet in height; giving the Telescope, with the elevation of the ground — 320 feet above the River — an altitude of 500 feet. This height will be sufficient to relieve the instru- ment from the influence of a smoky or impure atmosphere, and will insure a wide range of vision. In relation to the progress of astronomy in England, Prof. Piazzi Smyth, observes, that if it were not for private enthusiasm, Kngland would be left quite behind in some branches of astronomy; for while the Russians, Ger- mans, and Americans, are continually ordering for their observatories the largest telescopes that can be made, the English Government will not supply ON THE PROGRESS OF SCIENCE. 11 any such to those of Britain. The recommendation of the Britsh Asso- ciation, and of the Royal Society to the Government, to send a superior telescope to the clear climate of Australia, has been refused; the East India Company have also shown themselves unwilling to do anything towards aiding the establishment of an observatory on the Nilgheny Hills, India, 6000 feet above the level of the sea. The great purity of the atmos- phere which prevails in these regions, would undoubtedly lead to many important and signal discoveries. What the East India Company have refused to do, Capt. Jacobs is endeavoring to do on his private responsibility. At the session of the French Academy on the 22d of March, the prize in Astronomy for 1851, was divided between Mr. Hind, and M. Gasparis, the former for the discovery of the new planet Irene, and the latter for that of Eunomia. The Cuvierian prize, (a triennial prize, and never before awarded,) was given to Prof. Agassiz, for his researches on fossil fishes. Among the prizes offered by the Academy is one for 1854 in the depart- ment of Mathematics, as follows: —To determine the equations of the general movements of the earth’s atmosphere, having in view the rotation of the earth, the calorific action of the sun, and the attraction of the sun and moon. The authors are desired to exhibit the concordance of their theory with the best observations on the atmospheric movements. Even if the whole question is not resolved, but some important steps are made towards its solution, the prize will be awarded by the Academy. The prize is a medal of 3,000 francs. There is also an extraordinary prize for 1853, on the application of steam tonavigation. It is offered “for the best work or memoir on the most advantageous employment of steam for steam- ships, and upon the best system of mechanism, stowage and armament for such vessels.” The prize is 6,000 francs. / The French Government, through the Moniteur, have officially offered a prize of 50,000 francs for the discovery that “shall render the voltaic pile applicable, with economy, to industry, as a source of heat—to lighting, chemistry, mechanics, or medical practice. All nations are admitted to compete during five years. The Germanic Diet at Frankfort, have voted a sum of £3,500 to M Schonbein, and others, the inventors of gun-cotton, as a reward for the discovery. An Exhibition of the Industry of ali nations will be opened in the city of New York, in May of the present year. The plan of the Exhibition, as well as the building erected for the purpose, is essentially that of the Great Exhibition of 1851. The enterprise has been entered into with great spirit, and the display of the products of American science and art, together with the agricultural and mineral productions, of the United States will be proba- bly unequalled. The productions of foreign countries will be also well represented. 2% 12 NOTES BY THE EDITOR The scientific expeditions, surveys and explorations prosecuted, or pro- jected during the year 1852, have been numerous, and attended with valua- ble results. _ : The survey of the coast of the United States, under the superintendence of Prof. A. D. Bache, has been prosecuted with great energy. With only one link of twenty-six miles south of the Chesapeake to be filled up, an unbroken triangulation now extends from the mouth of the Kennebec river, in Maine, to the harbor of Beanfort, in North Carolina. The topography and hydrography have made corresponding progress. In afew years an unbroken series, with points well determined by astronomical aud other observations, will cover the coast from the Penobscot river in Maine, to the St. Mary’s in Florida. The progress of the survey on the Florida reef and the shores of the Peninsula is entirely satisfactory, in view of the limited appropriations, compared with the vast extent and variety of the whole work. The entire reef and western shore has been examined ina preliminary way, and nearly one-half of the survey of the reef has been made. A reconnoissance has been made of about one-half of the distance between St. Mark’s and Mobile bay, and the triangulation and topography now extend from Mobile bay to Lake Ponchartrain, and nearly all the hydrography has been.completed, and an examination made of the delta of the Mississippi. Galveston bay has been surveyed excepting a small por- tion of the hydrography, and the triangulation now extends to the vicinity of Matagorda bay. On the western Coast, in consequence of the extraor- dinary difficulties in securing hands and means owing to the discoveries of gold, the survey did not fairly get under way till about three years since. A very good preliminary reconnoissance has been made of the whole coast, from San Diego to the Straits of San Juan del Fuca, and of nearly every important harbor. In connection with this rapid progress of the survey on this coast, observations have been made for latitude and longitude, and the magnetic variation. ‘The geographical position of the coast, from the Straits of San Juan del Fuca to San Diego, has been established ; the lati- tude and longitude of the most important headlands having been determ- ined by sufficiently numerous and reliable preliminary observations. © The exploration of the Gulf Stream has been continued. Great progress has been made in publishing the results of the survey. Forty-two charts, elaborate and highly finished, and forty-two preliminary charts have already been published, and twenty-seven sheets are in various stages of engraving. The geographical positions determined by the survey from its commence- ment to July, 1851, have been published. The latitude and longitude of over 3,200 points have thus been given to the public, furnishing infor- mation of great value for general and local purposes. Under the direction of the U. S. Government a strong naval expedition ON THE PROGRESS OF SCIENCE. 13 has sailed for the purpose of endeavoring to establish relations of amity and commerce with the Empire of Japan. Looking to the magnitude of the undertaking, and the great expectations which have been raised both in this country and in Europe, in reference to its results, this expedition is full of interest, and will undoubtedly be productive of many valuable results, scientific, as well as commercial and moral. The expedition has on board a variety of articles as presents to the Emperor of Japan, to conciliate him and ‘prepare the way for the desired negotiation. A locomotive and a quantity of railroad iron have been taken with which to show the operations of a railroad; telegraph apparatus with which to demonstrate how the lightnings have been converted to the use of civilization. An apparatus for taking daguerreotypes will also be used and explained for the information of His Majesty. A beautiful barge is on board to be presented to him. Also, boxes of domestic goods, comprising a great variety of manufactured articles, which are to give the Emperor an idea of the industrial pursuits of this country, and perhaps awaken a desire on his part for an exchange of commoditics between Japan and the United States. Somewhat allied in character and importance to these projected operas tions of the Japan squadron, is the expedition now prepared for the explor- ation and survey of the China seas, the Northern Pacific, and Bhering’s Straits. This expedition, in aid of which $125,000 has been appropriated by Congress, is provided with a corps of scientific men, an astronomers hydrographer, botanist and naturalist. Under the direction of the Navy department, Lt. Lynch, well-known from his connection with the Dead Sea Expedition, has been detailed on a tour of African exploration, especially of that portion of the Continent lying east of the settlements of Liberia. Itis supposed that an exploration of this region would lead to the discovery of a broad tract of fertile and healthy country, well adapted to the extension of that system of colonization, which for some years past has greatly interested public attention in the United States. Lt. Lynch will land at Liberia, Cape Palmas, and other points, and will pur- sue his inquiries as far as the river Gaboon, with a view to the ascertain- ment of such localities on the margin of the African continent as may present the greatest facilities, whether by the river courses or by inland routes, for penetrating with the least hazard into the interior. He will col- lect information touching the geographical character of the country; its means of affording the necessary supplies of men and provisions ; the tem- per of the inhabitants, whether hostile or friendly; the proper precautions to be observed to secure the health of a party employed, and all other items of knowledge upon which it may be proper hereafter, to prepare and com- bine the forces essential to the success of a complete and thorough explor- ation of the interior. 14 : NOTES BY THE EDITOR A fourth expedition under the direction of the United States Government, commanded by Capt. Page, has sailed to explore the long-sealed and exclu- ded countries lying on the tributaries of the river La Plata, South Americaa. By a decree of the Argentine Government, there has recently been opened to the access of all nations, a vast territory of boundless resource, prover- bial for its treasures of vegetable and mineral wealth, extending, like the Mississippi from south to north, and reaching through twenty-four parallels of latitude, with every climate between the temperate and torrid zones, and with every variety of product which may be gathered from the alluvial plains of the ocean border to the height of the Andes. An expedition under the charge of Lt.’s Herndon and Gibbon, U. S. N., charged with the exploration of the Amazon and its tributaries, has in part returned. These officers were directed to cross the Cordileras in Peru and Bolivia, and by a selection of the most judicious routes of travel, with a small company of men, to explore the valley of the Amazon, and to de- scend that river to the sea. More than a year has has been spent in the active prosecution of this duty. Lieut. Herndon reached the United States in July last, bringing with him a large amount of interesting and useful facts, industriously collected by him in the course of his long and hazard- ous journey, embracing many valuable statistics of the country, and adding most important contributions to the hitherto unknown geographical charac- ter of this region. He is now engaged in preparing a full report of the incidents and discoveries of his travels. Another expedition to the Arctic Sea under the charge of Dr. Kane, in search of Sir John Franklin, and for scientific exploration, is now fitting out under the auspices of our countrymen, Mr. Henry Grinnell, and Mr. George Peabody, of London. Their endeavor will be directed to an ex- ploration of the upper coasts of Greenland, by land as well as sea, and will furnish occasion for valuable scientific observation tending to the ascertain- ment of the magnetic poles and the intensity and dip of the needle; and interesting also, as regards geological questions connected with the sup- posed existence of an open polar sea, and other subjects of much impor- tance in the natural history of our globe. The course adopted by the British Government in relation to the discove- ries made by the last American Expedition under Lieut. De Haven, is in the highest degree discreditable and dishonorable. In the Charts published by the authority and under the direction of the Admiralty, the localities discovered up Wellington Channel, by the Americans in Sept., 1850, are for the most part ignored, or altered. The “ Grinnell Land” first seen by De Haven in 1850, and subsequently by Capt. Penny in 1851, has had its original name, given in honor of a noble American merchant, changed to ON THE PROGRESS OF SCIENCE. 15 that of “ Prince Albert’s Land.” Courtesy, if no other motive, should have prevented a change. Lieut. Gillis, who, for more than three years past, has been employed, in pursuance of the directions of Congress, in conducting in Chili the obser- - vations recommended to be made by the American Philosophical Society and the Academy of Arts and Sciences, has recently returned to the United States, bringing with him a rich contribution to science, in a series of ob- servations, amounting to nearly forty thousand, and embracing a most extensive catalogue of stars. Under the auspices of the American Antiquarian Society, Worcester, Mass., Mr. Lapham has recently made series of complete surveys of numer- ous ancient mounds now existing in the State of Wisconsin. Mr. Lapham’s report will be shortly published by the Smithsonian Institution. An expedition under the charge of M. Deville, is about to be sent out by the French Government, for the purpose of exploring some parts of Brazil, Paraguay and the provinces of Para, Pernambuco, and Bahia. A mission is about to start, under the auspices of the Geographical So- ciety of St. Petersburgh, for Kamschatka, the Kurile Islands and Rus- sian America. The objects are—to study the ethnography of these districts, to collect specimens of their Flora and Fauna, to report on their physical characteristics, and to make maps and plans of their roads, coasts, and other topographical features. An English exploring expedition, consisting of two vessels under the charge of Capt. Denham, R. N., sailed for the South Pacific in June last. The cbject of the expedition is to survey and explore all the islands be- tween Australia and Valparaiso, and particularly the Fejee Islands. Mr. McGillivray, the well known naturalist, was appointed to take charge of the department of Natural History, and Mr. 8S. G. Wilson was appointed. artist, to make drawings of any objects in these islands likely to prove interesting, and for which purpose he has been supplied with a photo- graphic apparatus. _ Some months ago a Scientific Expedition was sent out from Copenhagen to explore the hills of Greenland and report on their mineral resources. This expedition has recently returned to Denmark, with a cargo of miner- als as the fruits of their industry. The explorers have failed to find any of the more precious metals ; but they have brought back iron, lead, nickel, tin, and copper mixed with a little silver: —the whole valued at nearly two thousand pounds. The society appears to be encouraged by these first-fruits of its enterprise to renewed exertions ; but the rigors of the climate of Greenland deter even the Norwegian miners from embarking in the adventure. The exploration of different portions of Africa have been continued with 16 NOTES BY THE EDITOR. such success, that even in the brief space of a year the vast blank on all former maps has been materially reduced. Mr. Oswell, and the mission- ary Livingston, his companion, to both of whom we are indebted for our acquaintance with the Ngami Lake, have pushed their researches north- wards to 17 deg. 25 min. S. latitude, and between 24 deg. 30 min., and 26 deg. 50 min. E. longitude, and have traversed a considerable track, watered by deep and constantly flowing streams, which they believe to be feeders of the river Zambesi. We learn from them, that the Zonga, which was to the east from Lake Ngami, is dissipated and absorbed in sands and Salt-pans, and the travellers passed over a large salt incrustation of about 100 miles in length and 15 miles in width, and saw many others lying to the north of the spot where the Zonga loses itself. Considerably to the north of these great natural salt pans, a population was met with, more advanced in intelligence than most of the tribes of South Africa. They also relate as a striking incident, that shortly before their arrival, the slave-dealers had, for the first time, penetrated from the west coast, and through the temptation of gaudy European goods had purchased many children. Researches made in Africa by Mr. Galton, an English traveller, between latitude, 17 deg. 58 min. 8., and longitude, 21 deg. E., taken also in con- nection with the explorations of Messrs. Oswell and Livingston, show, that the central region of Southern Africa, instead of being mountainous, is a watershed of no great elevation, and that the most central portion of it is occupied by a succession of lakes, of which Ngami is the southern- most. Under the direction of the Swedish Government, a topographical survey extending over 8700 geographical miles is now in progress. Levellings and trigonometrical surveys from Torneo to Alten, in the North Sea, will, when finished, give not only the relative heights of the Gulf of Bothnia, and the North Ocean, but will also serve as fixed data from whence to calculate the greater or less irregularity of the rise, or depression of the Scandinavian lands. The most perfect topographical and geographical maps which perhaps have ever been produced, are those of the cantons of Appenzel and St. Gallen, in Switzerland, brought out during the past year, by M. Ziegler. These maps, the part only of a large survey, are on a scale of 2 1-2 inch- es to amile, or 1-25,000. The lights are all thrown in perpendicularly, and the altitudes of each terrace, valley, or mountain-top is inserted in num- bers on a most exquisitely finished lithographic relief. The great military map of France is also in active progress ; and 149 sheets out of 258 have been already published. As an illustration of the gigantic nature of this work, it may be stated, that since this survey was ON THE PROGRESS OF SCIENCE. 17 commenced in 1818, 2250 officers have been employed on it—ji.e., in the geodesic and topograpical operations alone. _ The annual expense is about $150,000 per year. Mr Bartlett, Commissioner for running the boundary between the United States and Mexico, has devoted much attention to the Indian vocabularies of the districts visited during the progress of the survey. His researches have corresponded exactly with those submitted to philological inquiry by the lamented Albert Gallatin, with the addition of forty words discovered by Mr. Bartlett during the progress of this Commission. The number of words now ascertained is two hundred. Mr. B. will return accounts of the Vocabularies of nineteen languages west of the Rio Grande. These results will prove highly important and useful. Considerable interest has been of late excited in Russia among the scien- tific men in regard to the prosecution of meteorological investigations, and at their request observations are now being constantly taken in England, France, Prussia, and other parts of Europe. The Russian Government has liberally encouraged the desire of its savants to investigate thoroughly this important branch of science, which has hitherto not received so much attention as others. It has established for them not fewer than ten magnetic and meteorological observatories ; viz., one at St. Petersburgh, another at Catharineburg in the Ural Mountains, two at Barnoual and Nertschinsk on the Chinese frontier, one at Sitka in North America, one at Tiflis, anoth- er at Pekin, two others at Bogoslowsk and Zlatouste on the western side of the Oural mountains, and one at Lougan in the steppes of the Don. In addition there are also a considerable number of stations in different parts of the Empire. At all these establishments observations are taken at every hour of the day and night. An important step in relation to the system of weights and measures, was recently taken by the Bank of England. The only weights to be here- after used in the Bullion Office of that establishment will be ‘‘ the Troy ounce and its decimal parts,’ — superceding by that change the present system of pounds, ounces, pennyweights and grains. Practically the change will be one of great convenience. Among the scientific publications of 1852, issued by the United States Government are the following: Report on the Iron Region and the Lake Superior Mining District, by Messrs. Foster and Whitey, U. 8. Geologists ; Part second, with volume of maps ; Patent Office Report for 1851, 2 vols. Mechanical and Agricultural, by Thomas Ewbank ; Expedition to the Great Salt Lake, by Capt. Howard Stansbury, U. 8. N.; Maury’s Winds, Currents, and Sailing directions — new and enlarged edition ; Scientific Report of the Dead Sea Expedition, Lieut, Lynch, U. S. N.; U. 8. Explor- ing Expedition, Conchology, Dr. A. A. Gould ; Chart of the Arctic Re- 18 NOTES BY THE EDITOR gions, with the explorations and track of the Grinnell Expedition ; Amer- ican Nautical Almanac, Lieut. Davis; Annual Report of the Smithsonian In- stitution; Report on the Geology of Wisconsin, lowa and Minnesota, by Dr. D. D. Owen, U. 8. Geologist. The Mechanical volume of the Report of the Patent Office contains a Report on the Great Exhibition, by Edward Riddle, U. S. Commissioner, and is by far the best publication, both as regards contents and typo- graphy that has been issued by the Patent Office. The agricultural volume is also superior to any that has preceeded it, and contains valuable papers on wool and sheep-breeding by P. A. Browne, Esq., and on the American Ruminants, by Prof. §. F. Baird; the remainder of the volume consist of odds and ends, of little or no value, apparently made up by supplying suffi- cient paste to agglutinate scraps of paper taken from all sources, to a substratum of stout grocer’s paper. ‘The letter-press of the Conchology of the U. 8. Exploring Expedition, by Dr. A. A. Gould, has been published during the past year; the accompanying volume of plates, is also ina state of forwardness. Of the published results of this expedition, twelve volumes quarto and four volumes of plates, have already beenissued, leay- ing fifteen yet in the course of preparation. The series already published embraces the Narrative, 5 vols. and atlas ; Zoophites, 1 vol. and atlas; Philology; Races of Men ; Mammals and Birds ; Geology and Mineralogy, 1 vol. with atlas ; Meteorology ; Charts ; Conchology. Those yet to ap- pear will embrace the following subjects ; Herpetology, Ichthyology, Crus- tacea, Medusz, Echinoderms, Annelids, Insects, Ferns, Fungi, Alge, Botany, (Phanerogams,) Mosses, Geographical Distribution of Species, Hydrography, Astronomy and Magnetism, Charts. Naturalists, generally, who have been watching the progress of this great national work, will learn with deep regret that all the undistributed copies of the first seven volumes already published were destroyed in the same fire which consumed the library of Congress in December, 1851. This is the more melancholy, since but seventy copies were distributed. The first volume of the American Nautical Almanac, for 1855, publish- ed by authority, has been issued. It has been prepared under the super- vision of Lt. C. H. Davis, and is a material improvement on the British Nautical Almanac ; it having more correct lunar tables, which give more accurate predictions, as tested in the case of the solar eclipse of July, 1851. At Washington, the British Almanac was in error for the beginning of the eclipse, 78 seconds, and for the end, 62 seconds. The American Almanac was in error for the beginning only 18 seconds, and for the end only one second and a half. Theerrors exposed in this eclipse may give rise to an error of from 15 to 20 miles in the determination ‘of the longitude at sea by means of lunar distances, and to an uncertainty of twice that ON THE PROGRESS OF SCIENCE. 19 amount. The possibility of such an error, arising from this source, is removed in the American ephemeris. There are other points of su- periority ; one of the principle being ‘‘ a more complete, full and accurate table of latitudes and longitudes, particularly of American latitudes and longitudes, than is now anywhere to be found,’’ and the other relates to the tide tables and other practical information concerning the tides. Under resolutions of the two Houses of Congress, the valuable report of Dr. D. D. Owen on the geography of Wisconsin, Iowa, and Minnesota, (and incidentally of the ‘‘ Mauvaises Terres ’’ in Nebraska,) has been published. Its preparation reflects the highest credit upon the author, while the me- chanical execution of the work is excellent, and forms a striking contrast with the usual style adopted for Government publications. The report is voluminous and constitutes a quarto of about 650 pages, with a volume of maps. A report has also been submitted to Congress by Dr. Owen, recommending a geological survey of Oregon and a special reconnoissance of that singular region of Nebraska, known as the ‘‘ Mauviases Terres.’’ The interest awakened throughout the Scientific world by what has been already made known respecting the latter district is very great. Itisa tertiary deposite, abounding to a most extraordinary extent with the fossil remains of extinct animals, some of which combine the distinctive char- acteristics of several existing and distinct races. The discovery of an entirely new family of mammalia, embracing eight new genera, is one re- sult of the examinations already made by Dr. Leidy. In reference to this region, Dr. Owen states that ‘‘ it is not too much to assert that since the disclosures by the opening of the gypsum quarries of Montmatre, in France, that made us first acquainted with those singular extinct fossil races entombed in the Paris basin, no discovery in geology has divul- ged such extraordinary and interesting results in palwontology. The Legislature of Massachusetts have published during the past yeara new and enlarged edition of Dr. Harris’ valuable work on ‘* Insects Inju- rious to Vegetation,’’ and the Legislature of New York, ‘‘ A Report on the Great Exhibition of 1851,’ by B. P. Johnson, Esq. We would also in this connection call attention to the following scientific works of great interest, issued during the past year in this country, by pri- vate individuals. ‘‘ Mastodon Giganteus,”’ a description of the skeleton of the Mastodon Giganteus of North America, with plates. This elegant and costly work, the fruit of many years’ investigation, has been brought out by Dr. J. C. Warren of Boston, and is intended for private distribution. Several valuable geological and zoological memoirs have been publishd by Isaac Lea, Esq., of Philadelphia, and a valuable ‘* Catalogue of shells collected at Panama with notes on their synonomy, station and geographi- cal distribution,’’ has been issued by the late Prof. C. B. Adams. The num- 3 20 NOTES BY THE EDITOR ber of specimens of Mollusks collected by Prof. Adams, while at Panama, amounted to 41,830, embracing 516 species, of which 160 were new and undescribed. The department of mechanics and civil engineering has been enriched by the publication of a work entitled ‘* The naval Dry Docks of the United States,’’ by Charles B. Stuart, Engineer in Chief of the U.S. Navy. Two new scientific periodical publications have been started during the past year ; ‘‘ The Annals of Science, being a record of the inventions and improvements in applied science,’? conducted by Hamilton L. Smith, Cleveland, Ohio ; and the ‘‘American Polytechnic Journal,’’ conducted by Messrs. Page, Greenough & Co., Washington, D. C. Within the same period, the Journal known as the New York Farmer and Mechanic has been discontinued. ' A descriptive catalogue of the plants indiginous to is Ohio in the course of preparation by James W. Ward, Esq., of Cincinnati. Chemists and others interested in the progress of science will regret to learn that the reprinting and translating into English of Liebig and Kopp’s << Annual Report of the Progress of Chemistry ’’ has failed, after a trial of three volumes, for want of sufficient encouragement. Under the auspices of the French Government, a Chinese work on the production of silk has been translated by M. Julien, an eminent scholar of Paris ; in consequence of which the Chinese method has been intro- duced with great benefit into some of the silk-growing districts of France. M. Julien has also translated a Chinese manual on the fabrication of por- celain, which, it is anticipated, will be equally beneficial to that branch of industry. The Smithsonian Institution, at Washington, has continued silently, but effectually, to enlarge the sphere of its influence and usefulness, and to elicit from every part of the civilized world commendations, not only of the plan of organization it has adopted, but also of the results it has produced, By a judicious management on the part of the Regents, the funds of the Institution have been increased by the interest on the original bequest, until they now amount to a little more than 750,000. ANNUAL OF SCIENTIFIC DISCOVERY. MECHANICS AND USEFUL ARTS. DRAINAGE OF THE GREAT LAKE OF HAARLEM. Tue drainage of the great lake of Haarlem by the Dutch Govern- ment, a work which stands unrivalled in the history of hydraulic engineering, and which has been prosecuted with energy since 1848, has been nearly completed within the past year. The origin and history of this great enterprise is as follows :— In the year 1539, the North Sea, long restrained by artificial dams and dikes, as well as by some natural ridges of sand, suddenly burst its barriers, and brought horror and desolation into the fertile flats of North Holland. Twenty-six thousand acres of rich pasture land, with meadows, cattle and gardens, were covered by the waves, and the village of Nieuweinkirk was submerged and all its inhabitants lost in the tremendous calamity. The inundation resulted at first in the formation of four lakes, but the barriers of soft alluvial soil which separated them were gradually destroyed, and the four lakes became merged into one. The degradation of the shores also continued, until, at the commencement of the 18th century, the waters covered an area of 45,000 acres, with an average depth of 13 feet below low water in the Zuyder Zee. This lake constituted what has since been known as the Haarlem Meer, or Sea. The people of Holland saw with much alarm, the rapid extension of its boundaries, and, at an expense of about £33,000, succeeded in partially arresting its pro- gress; an expense of about £4,000 per year was moreover entailed, for the preservation and repair of the works of defence. More than two centuries elapsed from the time of the first inundation before any one began to dream of recovering this vast tract of country, and then, for a long period, all plans proposed were deemed impracticable. At length, on the 9th of November, 1836, a furious hurricane from the west drove the waters of the Lake upon the city of Amsterdam, and . 4 ae ANNUAL OF SCIENTIFIC DISCOVERY. drowned upwards of 10,000 acres of low land in the neighborhood. On the 25th of December following, another hurricane from the east drove the waters in an opposite direction upon the city of Leyden, the lower parts of which were submerged forty-eight hours, and 19,000 acres of land were inundated. The enormous loss occasioned by these two storms induced the government to determine on the drainage of the Lake, and a credit of 8,000,000 florins was voted by the States General. In May, 1840, a commission was appointed to superintend the work. The first operation was to cut a canal round the Lake, to isolate it from the neighboring waters, and to afford the means of navigation to the enormous traflic which previously passed over the Lake, amount- ing to 700,000 tons per annum. ‘This canal was 37 miles long, 130 feet wide on the west side, and 115 feet on the east side of the Lake, with a depth of 9 feet water. On the side next to the Lake, the mouths of all water-courses entering it, were closed by earthen dams, having an ageregate length of 3,000 yards, made in 10 feet depth of water. Other great works were executed by enlarging the sluices at various points, and in erecting powerful steam engines to assist in discharging the water from the canal during the time of high water. The water of the Lake has no natural outfall, being below the lowest practicable point of sluicage. The area of water enclosed by the canal was rather more than 70 square miles, and the quantity to be lifted by mechanical means, including rain water and springs, leak- age, &c., during the time of drainage, was estimated at 1,000,000,000 tons. In determining the motive power to be employed, two points were to be kept in view; first, the cost of draining the Lake; second, the cost of annual drainage; for, when once the work was accom- plished, the site of the Lake could only be kept dry by mechanical power. With the exception of a few steam engines, the wind had hitherto been the motive power employed to work the hydraulie ma- chines used in the Netherlands to keep the country dry. And the power of 12,000 wind-mills, having an average aggregate power of 60,000 horses, is required to prevent two-thirds of the kingdom from returning to the state of morass and lake, from which the indomitable energy and perseverance of the Dutch people have rescued what is now the most fertile country in Europe. The Haarlem Meer Commissioners were convinced that the old means must be laid aside, and new ones adopted to suit the magnitude and peculiarities of their work. They accordingly determined to erect three gigantic steam engines of a peculiar construction, which was accordingly done, and the whole put in operation in 1848. These engines consume but two and a half pounds of coal per hour, for each horse power, and are capable of raising 112 tons of water 10 feet high at each stroke, or of discharging 1,000,000 tons in 254 hours. A short description of one of these engines may prove interesting. It has two steam cylinders, one of 84 inches diameter, placed within another of 144 inches diameter; both are fitted with pistons; the outer piston is of course annular, and the two pistons are united to a MECHANICS AND USEFUL ARTS. 33 great cross-head, or cap, which is furnished with a guide-rod, or spin- dle; both pistons and cross-head are fitted with iron plates, and together, with parts of the engine attached, have an effective weight of nearly 90 tons. The Engine House is a circular tower, on the walls of which are arranged 11 large cast-iron balance-beams, which radiate from the centre of the engine. Their inner ends, furnished with rollers, are brought under the circular body of the great cap, and their outer ends are connected to the pistons of 11 pumps of 63 inches diameter each; the stroke of both ends is 10 feet; and the discharge from the pumps 66 cubic metres, or tons, of water per stroke. The action of the engine is very simple ; it is on the high-pressure- expansive-condensing principle. The steam is admitted first beneath the small piston; and the dead weight of 90 tons is lifted, carrying with it the inner end of the pump balances, and of course allowing the pistons to descend in the pumps. The equilibrium valve then opens, and the steam in the cylinders passes round to the upper surface of the small and annular pistons ; puts the former in a state of equilibrium, and presses with two-thirds of its force upon the annular piston, beneath which a vacuum is always maintained: thus, the down stroke of the engine, and the eleva- tion of the pump pistons and water, is produced by the joint action of the descending dead weight in the cap and pistons, and the pressure of steam on the annular piston. The engine has two air pumps, of 40 | inches diameter, and 5 feet stroke each. The water is lifted by the pumps into the canal, from which it passes off towards the sea sluices. The total weight of iron employed for the engine, pumps, &c., is 640 tons. The cost of the machinery and buildings, £36,000. The pumping was actively commenced in May, 1848, and has been continuously carried on up to the present time. The Lake is now nearly dry; much of the bottom is exposed, only large pools of water being left. The remains of the unhappy village of Nieuweinkirk have been found, with a mass of human bones, on the very spot where the old charts of the province fixed its site. From May, 1848, up to April, 1851, the Lake was lowered 7 feet 3 inches. The level reached at the end of October of the same year was 9 feet 7 inches below the original surface, or at an average rate of 4.79 inches per month. In November, 1851, a great quantity of snow and rain fell, raising the level of the Lake about four inches, and in December the weather was still unfavorable, so that at the end of that month, the level stood at 9 feet 5.38 inches below the original surface, showing a total gain since April of 2 feet 5.58 inches, or 3.32 inches per month. This pro- gress may appear to some inconsiderable ; but when it is recollected that the lowering of the Lake one inch involved the raising of up- wards of 4,000,000 of tons of water, and allowing for rain and snow falling during these eight months, there could not have been less than 186,000,000 tons of water pumped up during that period, the per- formance will appear great indeed. ‘To give a better idea of this, it is stated that 186,000,000 tons of water are equal to a mass of solid rock, one mile square, and 100 feet high, allowing 15 cubic feet to a ton. 34 ANNUAL OF SCIENTIFIC DISCOVERY. The average progress has been less during the last year than during the preceding ones, but this is readily accounted for, by the increased lift of the pumps, and by the difficulty of forming the channels which lead the water to them. The annual drainage hereafter, is estimated at 54,000,000 tons of water, which must be lifted on an average 16 feet; it may eccur, however, that as much as 35,000,000 of this amount must be dis- charged in one month, in order to preserve and render the space formerly occupied by this Lake habitable. CRYSTAL PALACE IN NEW YORK. Ir having been determined to open an Exhibition of the Industry of all Nations in the city of New York, during the summer of 1853, the following plan of an edifice suitable for the purpose has been adopted; the plan being furnished by Messrs. Carstensen & Gilde- miester, of New York. The general idea of the edifice is a Greek ross, surmounted by a dome at the intersection. Each diameter of the cross will be 365 feet 5 inches long. There will be three similar en- trances—one on the Sixth Avenue, one on Fortieth, and one on Forty-second Street. Each entrance will be 47 feet wide, and that on the Sixth Avenue will be approached by a flight of eight steps. Each arm of the cross is on the ground-plan 149 feet broad. This is divided into a central nave and two aisles, one on each side; the nave 41 feet wide; each aisle 54 feet wide. On each front is a large semi-circular fanlight, 41 feet broad and 21 feet high, answering to the arch of the nave. The central portion, or nave, is carried up to the height of 67 feet, and the semi-circular arch by which it is spanned is 41 feet broad. There are thus, in effect, two arched naves, crossing each other at right angles 41 feet broad, 67 feet high, to the crown of the arch, and 365 feet long; and on each side of these naves is an aisle, 54 feet broad and 45 feet high. The exterior of the ridgeway of the nave is 71 feet The central dome is 100 feet in diameter—68 feet inside from floor to spring of arch, and 118 feet to the crown; and on the outside, with the lantern, 149 feet. The exterior angles of the building are filled up with a sort of lean-to, 24 feet high, which gives the ground-plan an octagonal shape, each side or face being 149 feet wide. At each angle isan octa- gonal tower, 8 feet in diameter, and 75 feet high. Each aisle is covered by a gallery of its own width, and 24 feet from the floor. The building contains, on its ground floor, 111,000 square feet of space, and in its galleries, which are 54 feet wide, 62,000 square feet more, making a total area of 173,000 square feet for the purposes of exhibition. There are thus in the ground floor two acres and a half, or exactly two acres and 52.100; in the galleries, one acre and 44.100; total, within an inconsiderable fraction of four acres. There are on the ground floor 190 columns, 21 feet above the floor, 8 inches diameter, cast hollow, of different thicknesses, from half an inch to one inch thick; on the gallery floor there are 122 columns. MECHANICS AND USEFUL ARTS. 35 NAVAL DRY DOCK AND RAILWAY AT PHILADELPHIA. THE Journal of the Franklin Institute gives the following description of the U. S. Dry Dock and Railway, recently completed at Philadel- phia; the dock and its appendages being the largest in the world. The lifting power consists of nine sections, six of which are 105 feet long inside, and 148 feet over all, by 32 feet wide, and 113 feet deep; three of them are of the same length and depth as the others, but two feet less in width; the gross displacement of the nine sections is 10,037 tons, gross weight 4,145 tons, leaving a lifting power of 5,892 tons, which far exceeds the weight of any vessel yet contemplated. The machinery for pumping out the sections consists of two engines of 20, and two of 12 horse power. In connection with the sections (which form the lifting power of the dock,) is a large stone basin, 350 feet long, 226 feet wide, and 12 feet 9 inches deep, with a depth of water of 10 feet 9 inches at mean high tide. At the head of this basin are two sets of ways, each being 350 feet long, and 26 feet wide. These ways are level, and consist of the bed pieces, which are three in number, and firmly secured to a stone foundation; the central way supports the keel, while the side ways receive the weight of the bilge ; these ways are of oak, and are finished off to a smooth surface. On the top of the bed pieces or fixed ways, comes the sliding ways or eradle, which are also 350 feet leng and 26 feet wide, so constructed as to admit of being adjusted to the length of any vessel. The opera- tion of the dock is as follows:—The sections are sunk so as to allow the vessel to be floated in; as soon as she is secured in the proper position, the pumps are put in operation, when the sections begin to rise, and as soon as they come to a bearing on the keel, the bilge blocks are run in until they fit the ship. When all is secure, the sec- tions are pumped out until the keel is some two or three feet above the water. If repairs that will only require a short time are contem- plated, the vessel is kept en the sections, and no other portions of the dock used. When this is accomplished, the sections are filled with water, and rest on the bottom of the basin, which is of stone. Bed ways are now laid on the sections in line with those before mentioned. When they are secured they are greased, and the cradie is now slid under the ship, and she is blocked up on the cradle, and the blocks on the sections are removed. At this point of the operation a new instru- ment of power is brought forward for the purpose of hauling the ship from the sections to the bed ways in the Navy Yard. It consists of a large hydraulic cylinder, having a ram of 15 inches diameter and 8 feet stroke, and a power of 800 tons. On the top of this cylinder, and attached to it, are two vertical direct acting engines, with cylin- ders 16 inches in diameter and 16 inches stroke, connected at right angles to one shaft, on which are four eccentrics for working four hydraulic pumps of 14 inches bore, and 6 inches stroke; the tank which carries the water for the press is also on the top of the cylinder, and forms the bed on which the pumps are secured. The boiler which supplies these engines with steam, is on a sliding cast iron bed 4* 36 ANNUAL OF SCIENTIFIC DISCOVERY. way, some 12 or 15 feet ahead of the hydraulic cylinder, and connected to it by two cast iron rods. This boiler is of the usual locomotive form, and has 85 tubes of 2 inches diameter, and 9 feet long. To get ready for operation, the hydraulic cylinder is slid down to the edge of the basin, its ram is run in, and a connection made by means of two side rods of wrought iron from the cross head of the ram to the sliding cradle which carries the ship. The central bed way has key holes mortised through it horizontally, every 8 feet, and there are projec- tions from the hy draulic cylinder, which have corresponding key holes in them. Two cast iron keys, 24 inches wide, and 6 inches thick, are slid through the key holes on small wheels; these keys secure the cylinder to the central bed way; the engines and pumps being now put in operation, a pressure is brought on the 15 inch ram, and as soon as the pressure overcomes the resistance, the vessel must move. As soon as the vessel has been moved 8 feet, the keys which hold the cylinder to the central way are withdrawn, and by means of a screw which is attached to the head block of the ram, and driven from the engine, the cylinder and boiler are in their turn rapidly slid ahead, (the water in the cylinder being allowed to escape into the tank,) when the cast iron keys are again slid in place, and the vessel moved another 8 feet. To push the vessel off, the cylinder and appendages are moved to the head of the ways, put on a turn-table and reversed, when it is again brought down to the cradle, and the cylinder being secured as before, the head of the ram is applied directly to the cradle, and the vessel shoved back on to the sections, which requires the same time and power as to haul them off. The capacity of this dock ex- ceeds that of the stone docks at New York, Boston, and Norfolk, combined, for united they can take but three vessels, while here, two of our longest war steamers may be hauled out on the ways, and two frigates lifted on the sections. The advantages that must ‘result from the facilities of repairing a vessel elevated into light and air over one sunk in a stone dock, are very great, and have only to be seen to be appreciated. BEACON ON ROMER SHOALS. A NEW beacon, having some peculiarities of structure, has recently been erected on ‘the Romer Shoals, at the entrance of New York Harbor, under the direction of Mr. J. W. Lewis, C. E. The Beacon is built on the southeast crest of the Romer Shoal, about two miles from Sandy Hook Light, in 13 feet water, and is in plan an octagon 20 feet in diameter and 50 feet in height. The principle of its con- struction consists in screwing into the sand of the shoal, at each angle of the octagon, and in the centre, one of Mitchell’s screw piles; the blade of each screw being 2 feet in diameter, and entering the sand toa depth of 10 feet; attached to the screw are nine wrought-iron shafts or piles, each 6 inches in diameter and 324 feet in “length, extending to a height of 83 feet above high water mark; on “the top of these piles, heavy Cast iron sockets are keyed, to ahdek are MECHANICS AND USEFUL ARTS. 37 attached also by keys the cast iron shafts, which rising form the pile heads, and uniting in a centre frame at the tops, form the supporting braces for the basket frame, or distinctive mark of the Beacon, which is secured to a prolongation of the centre pile at a height from the level of the sand of 63 feet. The whole of the piles and shafts are securely braced and counter-braced by wrought iron tie-rods, keyed to the sockets, rings or pile heads, forming altogether one of the most efficient systems of frame work ever erected for such a purpose. The whole weight of the structure is but 75 tons, and it cost the Govern- ment but $10,000, whereas a stone structure would not cost less than $35,000, that being the cost of a stone beacon on the same shoal, and but 40 feet in height. GREAT TUNNEL IN HUNGARY. OnE of the longest, if not the longest tunnel in the world, is now in a forward state of completion. It is situated in Hungary, and leads from the shores cf the river Gran, not far from Zarnowitz, to the mines in the Schemnitzer hills; it is two geographical, or about ten English miles, long; it is intended to answer the double purpose of a channel to drain off the water accumulating in the works, and of a railway to transport the ore from the mines to the river. MODERN CYCLOPEAN WALL. A RECENT number of the Allgemeine Zeitung contains an interesting account of a visit which the writer had made to inspect the progress of building a wall in the manner called Cyclopean, near Kiel, in Schleswig-Holstein. He considers the effect of the work and the style of execution far superior to any of the numerous remains called by the same name which he had seen in Italy, and goes so far as to give it the preference over any other kind of wall, so far as the plain, vertical surface of the material, apart from ornamental accessories, is concerned. He thinks that the polygonal stones, exerting their pres- sure in all directions, must insure stronger work than squared stones, however closely jointed, which only act in the direction of gravity. Indeed, the imnumerable many-sided and multangular stones of all sizes seem run together into one compact mass, of which neither time nor age will get the better. Neither mortar nor any other means of binding the stones together is employed ; but the greatest care is taken im fittme the granite blocks one into the other, the vacant spaces in the wall as it is carried up being accurately taken off with a lead tape forced with a hammer into all the angles of the openings, and then applied to the flat hewn face of the block best suited, and next to be brought to its proper shape by the workman. From the workmen he learned that the directions given them by the architect were, “ Five- sided and six-sided blocks, seldom four-sided; straight lines, obtuse angles, joint upon angle and angle upon joint; all according to the lead tape, and only inclined junctions.” In fact, all the junctions be- 38 ANNUAL OF SCIENTIFIC DISCOVERY. tween the blocks were found to be in every gradation between the perpendicular and the horizontal, without coinciding with either of them. In this obliquity of the jomts the author detected the arch principle of construction as applied to the work, and the workmen pointed out to him, that each stone either pressed or supported, with every one of its sides, however numerous. Generally, the writer holds this polygonal or Cyclopean kind of building to be especially applicable in, first, hydraulic works, as it offers nowhere a continuous joint to the water; second, in fortifications; third, for railways in substruction and steep coverings, and in the cellar story and even in the next story of large buildings and palaces. In these mortar would be used, not as a means of connecting the stone, but only as pointing to the joints, so that the immediate contact of the stone should not be interrupted. In conclusion, the writer recommends the adoption of this method of building according to determined and clearly defined principles and rules, as altogether practical, wherever the material for polygonal blocks is found,—a method which is at least to us a new one, and not simply a more careful execution of the long-used rock walls, or an ornamental imitation of WHITE’S WOODEN SUSPENSION BRIDGE. By this invention the Patentees claim to have solved the problem of spanning broad and rapid rivers with a structure which requires no piers, yet is suitable for railroad purposes, and can be built at a rea- sonable and practical cost. The principal feature of the invention is the substitution of wooden stringers constructed of boards cemented, dowelled and bolted, for iron chains or wire cables. There is no question as to the strer ngth which may thus be attained; a reference to any tables of the streneth of materials will show that the tensile strength of hard wood is much greater in proportion to its weight than bar iron. Any number of these stringers considered necessary for a given structure may be placed one above another and each be ‘firmly anchored beyond the points of support, by back stays fastened into the abutment; the only question seems to be, whether the stringers can be locked to the back stays with a suflicient degree of firmness. The principal advantage whic +h is claimed for this invention is that it can be entirely freed from that tendency to vibration, which is fatal to the use of the iron suspension bridge upon railroads. ‘The means used to effect this are very simple, and certainly seem to be effectual. Perpendicular oscillation is partly overcome by springing a direct arch from one abutment to another which in the centre rises nearly to the road bed, and which is firmly connected with the stringers above by the suspension rods which sustain the floor; and lateral oscillation is overcome partly by making the bridge diminish in width from the extremities to the centre; “while all possibility of vibrations would seem to be avoided by the mode of cover ing. This is done as follows: the entire structure 1s covered with a double di: agonal boarding, and the planks of the road bed are also laid double, crossing the floor. Joists also diagonally. MECHANICS AND USEFUL ARTS. 39 The weight of the structure decreases in a geometrical ratio as the distance from the towers increases, so that at the centre, though the full strength of the stringers and the direct arch below them is retained, the weight of the structure is diminished to an exceedingly low point. As to economy of construction this bridge can be surpassed by none, especially where a great span is required. ‘There is no heavy timber, the entire structure being built of plank and boards. No piers are necessary, the only stone work being the laying the abutments, etc. The manner of constructing the stringers speaks well also for their durability, being put together with oil cement between each_board which will render decay next to impossible; it is very well known that wood prepared in this way has been excavated from the ruins of old cities, after being buried more than three thousand years, ina state of perfect preservation —airoad Journal. FLYING RAILROAD BRIDGE. Tue Scientific American states that C. B. Hurcurnson, of Water- loo, N. Y., has invented and taken measures to secure a patent for a valuable improvement on Railroad Bridges for navigable waters. The object of the invention is to have a bridge perfectly open and free at all times for vessels to pass, except the few minutes required for a train to pass over, and to carry over trains expeditiously and safely. A certain number of piers or abutments are built in the river, with space between them for the passage of vessels. Instead of having a stationary platform to the roadway extending across on the piers, he employs a flying or running platform, which carries the train spanning and springing over the successive spaces between the piers from the one side to the other. There are tracks or rails on all the piers, and on the flying platform there are wheels that run on the tracks, like a long railroad car. The length of the flying platform is in proportion to the width of space between the abutments, so that it will be impossible to overbalance it while springing from one pier to the other like a sliding drawer. The flying train is stationary at one side or the other, when the train is not passing. It is to be propelled across by having stationary power on itself, or to have it so constructed that the locomotive of a train may propel it across. It may be called “a flymg railroad bridge.” THE GENESEE HIGH BRIDGE. TuE bridge by which the Buffalo and New York Railroad crosses the Genesee river, near Portageville, is one of the most gigantic structures in this country, being eight hundred feet in length, and two hundred and thirty-four feet above the stream. About one hun- dred feet below the bridge is a perpendicular fall in the river of sixty-six feet; hence, from the top of the bridge to the bed of the river below the fall, it is three hundred feet. The Genesee High Bridge towers above all similar structures in America; even the sus- 40 ANNUAL OF SCIENTIFIC DISCOVERY. pension bridge at Niagara is only two hundred and thirty feet high, and no longer than this. Some more definite idea of this immense structure may be gathered from the following statistics ; — rising from the bed of the river are eight stone abutments, each thirty feet high. On these rest the truss work of wood, extending one hundred and ninety feet above the abutments. On the top of this structure stands the bridge itself, which is fourteen feet. high. The base of the truss work is seventy-five feet in width, and the top of the bridge, twenty- five feet. To furnish the timber for it, over two hundred and fifty acres of land have been required. More than a million and a half * feet of timber, board measure, have been used in the construction, together with sixty tons of iron in bolts. The work was completed in eighteen months at a cost of about $140,000. The bridge was designed by Mr. H. C. Seymour, and so perfect is the model, that from the supporting truss-work any piece of timber can be removed, in case it becomes defective, and a new one placed in its stead, without affecting the strength of the work, or displacing any other timber. The truss-work is composed chiefly of timbers placed on their ends in an upright position, and so braced, and counter-braced, and the whole structure made so firm, that it is estimated it will sustain with safety twenty times the weight of any train that can pass over it. NOVELTIES IN SHIP BUILDING. THERE is now building at the Clyde, at Carts’ Dyke, an immense iron steamship, to be called the Atrato, of much greater capacity and considerable larger, than that leviathan steamer, the Great Britain ; indeed so large is the Atrato to be, that the Cunard steamship Arabia, of 2,400 tons, might be put inside the new steamer, with a good deal of room to spare. The origin of the Atrato is somewhat singular. Her builders, hay- ing constructed the engines (of 850 horse power) for the Demerara, which got jammed across the Severn, and had to be broken up in strains she received, got an order from the West India Mail Steam- ship Company, to whom the Demerara belonged, to build a vessel of iron instead of wood, to which the new engines might be adapted. They were permitted to modify the design of the hull so far as the length was concerned, although the retention of the original paddle- shafts compelled an adherence to the same breadth of beam at that line as the original vessel. The result has been that the engineers submitted plans which were approved of, and are now being carried out in the building of the largest vessel ever afloat. The entire length of the keel is laid resting on blocks. The enormous bar is in nine pieces, joined by scarf-joints, and firmly riveted together. The stern post is in one piece, and so is the stem, which runs for about ten feet into the horizontal keel. The stem alone weighs 65 ewt. Only one- half of the ribs or frames are as yet in place, and even with the long length of bare keel terminated by the stem standing up some forty feet or more, the enormous dimensions of the vessel can hardly be MECHANICS AND USEFUL ARTS. 41 appreciated, but they will be understood from the principal measure- ments of the Atrato, and those of the largest ship-of-war in the British service, the Windsor Castle, now on the stocks at Pembroke Dock Yard, which is stated to be “ the largest vessel in the world.” Their principal measurements are : THE ATRATO. Feet. WINDSOR CASTLE. Feet. Length of keel, 310 | Length extreme, 278 Do. of keel and forerake, 340 | Do. of keel and forerake, 2404 Breadth of beam, 52 | Breadth, 25 Depth of hold, 34 | Depth of hold, 24 It would thus appear that the Atrato will be about 60 feet longer than the “largest vessel in the world,” and about 10 feet deeper in the hold ; the only dimension by which she is exceeded by the Wind- sor Castle being in the breadth of beam, and in that particular the builders were bound down by the existing machinery, which as above stated, was made for the Demerara, a much shorter vessel. The floor of the new steamer will have a rise of four feet at the flattest part, so that the easy curves afforded by such a sweep of midship section, combined with the enormous length, can only be appreciated by those conversant with ship-building. There are to be four decks; the upper or spar deck being flush from stem to stern, and presenting a prom- enade of about 330 feet in length, by about 38 in breadth. The hull is to be divided into seven compartments by six iron water-tight bulk heads, extending from the keel to the main deck. This will give rigidity to the hull, and afford security against sinking. A new and beautiful steamer, called the “ Light of Heaven,’ has been recently launched at Glascow, for the Pacha of Egypt. Her engines are of 300 horse power, and of the most beautiful make and fish. The fittings of the interior are gorgeous beyond comparison, consisting of papier-mache ornaments and rich brocaded silks, which will alone cost $125,000. The ceiling of the saloon will be divided intoa number of panels of rich white silk, having upon the centre the device of the crescent and the star, encircled with most elaborate and richly colored wreaths of Eastern flowers of silk. The borders of the panels are to be richly ornamented Raffaelesque decorations. Other portions of the ceiling between the beams, are to be covered with a silk of a white ground and groups of flowers of gold thread. The panels on the sides are of papier-mache. The ottomans in the saloon are covered with cloth of gold, formed with a warp of gold and a weft of glass thread. The awning of the deck is to be formed of entirely brocaded silk, the fringe being of gold and costing twenty guineas per yard. ‘The cost of the silk for the awning alone will not be less than $10,000. A new steamer has recently been built in England, with the follow- ing remarkable proportions. Her length exceeds 200 feet; while her breadth is little more than 13 feet. She is fitted with engines of 80 horse power. Her wheels, which are on the feathering principle, are 42 ANNUAL OF SCIENTIFIC DISCOVERY. remarkably small, and, to a casual observer, appear totally adequate to the propulsion of a boat of such great length; this, however, we are assured is not the case. STEAMBOAT PROPELLERS. THERE have been brought to light, recently, two new inventions: the one adapted to give increased speed to screw, the other to paddle navigation. Mr. G. Bovill’s screw propeller, described in the Mining Journal, is an entirely novel affair. Its central portion is fitted up with a hollow sphere, occupying one-third of the entire diameter of the propeller, and the blades are made narrower at the outer extrem- ity than at the base. The blades are also made to revolve, so as to admit of the pitch being altered to meet the various circumstances of speed and power. Froma table of the comparative result of trials on three different boats, it appeared that important advantages have been obtained from the new propeller. The paddle invention is that of a Liverpool shipwright named Hampson. metal and one liquid. Hitherto it had been laid down as a law, that with the platinum and acid solution, two gases (oxygen and hy drogen) were necessary to obtain this result ; only the elements of the battery formed with the chloride of gold, have a feebler intensity of action than the usual gas pairs. 5th. The solution of chloride of gold, chemically pure, may there- fore be considered definitively as superseding the acid solution and oxygen in the gas battery. The remarkable effects that are manifested in this circumstance should not be confounded with those that would be produced by certain gaseous solutions or liquids, such as nitric acid absorbing hydrogen at the ordinary temperature, without the apphance of platinum. ON THE SPHEROIDAL STATE OF BODIES. AT a lecture before the Royal Institution, England, M. Boutigny remarked that the simple phenomena of the subject would seem to have necessarily attracted attention from the most ancient times, and endeavoring to discover some record of the fact, he had found the possible expression of it in the Wisdom of Solomon, xix.’ 20:— “ The fire had power in the water, forgetting his own virtue ; and the water forgat his own quenching nature.” Eller and Leidenfrost, however, about the middle of the last century, first truly observed the simple phenomena; but nothing had since been done, either to increase our knowledge of the singular facts, or to suggest an explan- atory theory concerning them. "M. Boutiony then exhibited the experiments which he had recently made. He placed some nitrate of ammonia, which is inflammable at a very low temperature, upon a capsule of platina, greatly heated, but it assumed the spheroidal con- _ dition without ignition. On removing the lamp, however, and when the substance was cooled down to the ordinary temperature, it ignited. The beautiful violet colored vapor of iodine was produced also “in the same manner, as also distilled water, which passed into steam as soon as the metal disc was sufficiently cooled. He then proceeded, by experiment, to show how the fact as relates to water, readily explains the occasional bursting of steam boilers, when, by the cooling of the boiler after the introduction of water into it when overheated, the contents are immediately and violently converted into steam. 202 ANNUAL OF SCIENTIFIC DISCOVERY. The singular fact of the universal decrease of temperature in the liquid, when in a spheroidal state, was then adverted to. Numerous experiments had proved it. This phenomenon has given a result wholly unforeseen, and most remarkable. The chemist knows that liquid anhydrous sulphurous acid boils at a very low temperature. M. Boutigny, in submitting this acid to similar conditions in a slightly humid atmosphere, the acid first took an opaline appearance, then lost its transparence, and finally solidified. The solid formed was ice! As a variation of this experiment, some drops of water were thrown upon the acid while in the spheroidal state, and the water immediately congealed. In order to demonstrate that liquids, when im this state, do not touch the surface of the metal, some concentrated nitric acid was dealt with, but it did not act upon the copper disc on which the experiment was made, until the copper was cooled. A cylinder of silver, at a white heat, was also plunged into water; it was distinctly observed for many seconds (the room being darkened) not to be affected by the surrounding medium. The lecturer then insisted that it was not alone to such physical results that we are to look on the curious phenomena he has unveiled, but to the new method of chem- ical analysis and synthesis which they suggest. He has thus found that some bodies, which are not decomposed at boiling heat, are so when put in a spheroidal state ; while others, placed in contact under the influence of this new molecular state, produce new combinations. When wine and alcohol are in a spheroidal state, their elements are found to be in a new order; ether is decomposed, and disengages aldehyde; chloride of ethyle decomposes nitrate of silver; ammonia dissolves iodine, &e. PREPARATION OF MAGNESIUM. BunsEN has observed, that fused chloride of magnesium is readily decomposed by the voltaic current, so that it is possible, in a short time, by the employment of a battery of a few pairs only, to obtain a mass of metal weighing several grammes. For the preparation of the chloride, Liebig’s method is recommended ; particular care must be taken, however, in drying the mixture of magnesia and sal-ammoniac, to avoid the formation of a basic chloride. As a decomposing cell, Bunsen employs a porcelain crucible divided into two parts by a dia- phragm reaching to half the depth of the crucible. In this manner the chlorine set free at one electrode is prevented from again com- bining with the magnesium deposited upon the other. The electrodes used are of carbon, in the form in which it is prepared for Bunsen’s battery ; into the surface of the negative pole kerfs are cut to prevent the magnesium set free from floating to the surface of the fused liquid and there taking fire. To determine the quantity of magnesium formed in a given time, the author introduces a tangents-compass into the circuit, and deduces by a well known formula the relation between the chemical and the magnetic effects of the current, so that the latter being observed, the former may easily be calculated. Magnesium, as CHEMICAL SCIENCE. 203 obtained by electrolysis, is upon a fresh fracture sometimes faintly crystalline in large plates, at others fine grained; in the first case, it is silver-white and very brilliant, in the last more bluish gray and without lustre. Its hardness is nearly that of cale-spar. It fuses at a moderate heat; in dry air it is wholly unchangeable, and does not lose its lustre ; in moist air it soon becomes covered with a coating of magnesia. Heated to whiteness in the air, it takes fire and burns with an intense white light; the evolution of light by combustion in oxygen is of unusual intensity — about 500 times that of a wax can- dle. The metal decomposes pure cold water very slowly, acidulated water rapidly. Thrown upon aqueous muriatic acid the metal instantly ignites. Concentrated sulphuric acid dissolves it slowly; a mixture of nitric and sulphuric acids has no action in the cold. The density of magnesium was found to be 1.7430 at 5° Centigrade. Calculated from this, the atomic volume of magnesium is 86, or exactly double that of nickel. The metal, as obtained by electrolysis, may easily be filed, bored, sawed, or somewhat flattened by hammer- ing, but is hardly more ductile than zinc, at ordinary temperatures. The magnesium obtained by means of potassium, contains a small quantity of that metal, and is ductile; that reduced by electrolysis, almost always contains traces of aluminum and silicon.— Ann. der Chemie und Pharmacie, \xxxii. 137. TITANIUM AND ZIRCONIUM IN MINERAL WATERS. Dr. Mazanpe, of Valence, states that he has detected in the mine- ral waters of Neyrac, France, both titanium and zirconia. He had previously announced his having found in the same waters, molybde- num, tin, tungsten, tantalum, cerium, yttrium, glucinium, nickel, and cobalt. — L’ Institut, No. 964. ON THE PASSIVE STATE OF METEORIC IRON. WoHLER states, that he has observed the curious fact, that the greater portion of the meteoric iron he has had an opportunity of examining, is in the so called passive state, that is to say, it does not reduce the copper from a solution of the neutral sulphate of copper, but remains bright and uncoppered therein. But if touched in the solution with a piece of common iron, the reduction of the copper commences immediately upon the meteoric iron. It also becomes active instantaneously on the addition of a drop of acid to the solution of copper; but if the reduced copper be filed away, the new surface is again passive. I convinced myself by experiments on meteoric iron, which had never been in contact with nitric acid, and neverthe- less was passive, that this state could not have been produced by the corrosion of the surface by the acid, for the production of the Wid- mannstattean figures. I thought first that this deportment might be employed as a means of distinguishing true meteoric iron; but it soon appeared that some undoubtedly genuine meteoric iron was not in this 18* 204 ANNUAL OF SCIENTIFIC DISCOVERY. state. Seven specimens, from different parts of the world, examined, were found to be passive ; six reducing, or active ; and four which do not become coated with copper immediately, but on which the reduction gradually commences, after a longer or shorter contact with the cupreous solution, and usually from one point, or from the margins of the fluid. These peculiarities appear to have no connection either with the presence of nickel, or the property of forming regular figures on corrosion. JI also found that an artificially prepared alloy of 1ron and nickel, which on corrosion acquired a damasked surface, reduced the copper from solution in the same manner as common iron. Whether this state is proper to all meteoric iron on its reaching the earth, and, as may have happened in the case of the active kinds, have only been lost in the course of perhaps a very long period of time, and what probable opinion can be formed of these phenomena must be settled by experiments and observations of a more extended nature. — Pogg. Ann. PRODUCTION OF BRITISH IRON. Mr. SAMUEL BLACKWELL, an eminent English iron-master, esti- mates the gross annual production of iron in Great Britain to be upwards of 2,500,000 tons. Of this quantity, South Wales furnishes 700,000 tons; South Staffordshire, 600,000; and Scotland, 600,000. The remainder is divided among the various smaller districts. The number of furnaces in blast in England and Wales during the year 1850, was 336. ON THE COMPOSITION OF WOOTZ, OR INDIAN STEEL. Woorz, or Indian Steel, has for a long time been held in high estimation from the supposition that the celebrated scimitars of Damascus were made from it. A chemical examination was made of wootz in 1819, by Faraday, who came to the conclusion that the peculiar excellence of this steel depended chiefly on a small quantity of aluminum combined or alloyed with it; two separate analyses yielding 0,0128, and 0,0693 of aluminum. On the other hand, Kar- sten could only detect dubious traces of aluminum in wootz, and Elsner attributed the improvement in the quality of the steel pro- duced in Faraday’s experiments, not to the small quantity of foreign metals, aluminum, silver, platinum, &c., alloyed with them, but entirely to the operation of remelting, and this seems to be the prac- tical conclusion come to at Sheffield, Eng., at the present day. The fact that the alloys produced by Faraday possessed a perfectly dam- asked surface, closely resembling wootz, seems to militate against the conclusions of Elsner. M. Breaut attributes the damask of the Eastern blades to the crystallization of two distinct com- pounds of iron and carbon, and draws a distinction between the oriental damask, and that produced by alloys of steel. This CHEMICAL SCIENCE. 205 is confirmed by the experiments of M. Anocoff, a Russian engineer, published a few years since in the Annuaire des Mines de Russie. He pretends to have produced blades so nearly © emulating those of Damascus, as to allow of their being bent at a right angle, and capable of dividing a film of gauze floating in the atmosphere. Mr. Henry, of England, has recently made seve- ral analyses of wootz, and failed to detect in it the presence of alu- mina; he, however, found sulphur, silicon, and arsenic, in apprecia- ble quantities. SEPARATION OF SILVER FROM OTHER METALS. The following is an abstract of the specification of a patent granted to Alexander Parks, of England, for improvements in the separation of silver from other metals. The invention consists—first, of certain improvements in the mode of employing zinc for the purpose of separating silver from lead. Secondly, of improvements in separa- ting the silver from the alloy of zinc and other metals thus produced. The patentee states that he has found when lead contains 14 ozs. of silver to the ton, the most suitable proportion is 1 per cent. of zinc; thus, for each ton of lead containing 14 ozs. of silver, he uses 23 lbs. 4 ozs. of zinc; for each ton of lead containing 21 ozs., 33 Ibs. 6 ozs. of zinc; and for each ton of lead containing 28 ozs. of silver, 44 Ibs. 8 ozs. of zinc. The process is conducted as follows :—The lead, in the state it is received from the smelting-house, is melted in an iron pot, and heated to the temperature of melted zinc ; the zinc, in a melted state, is then added, and the whole well mixed; the contents of the pot are then stirred in the usual way, with a piece of green wood, to remove any impurities ; it is then cooled; the alloy of silver, zine &c., rises to the surface, and is removed by the means of ladles pierced full of holes. A previous assay of the lead will indicate the right proportion of zinc to be employed; a larger quantity will be found necessary in cases where the lead is very impure. The lead which has thus been desilverised by means of zinc, often retains a small portion of that metal, which has the effect of rendering it brittle : this defect is remedied by the following process :— The melted lead is run into a reverbatory furnace, and raised to a dull red heat, when the zinc rises to the surface and becomes oxy- dised ; the furnace is then tapped and the lead run into an iron pot, when it is stirred with a piece of green wood, to remove any oxide of lead which may have formed; after which, it is ladled into moulds in the usual way. By this means, 3 tons of lead may be deprived of the zine it contains in the course of from 2 to 24 hours; the surface of metal exposed being from 25 to 30 square feet. The oxide of zine remains in the furnace, whence in may be afterwards be removed. In order to separate the silver from the other portions of the alloy the patentee proceeds as follows :—The silver is first concentrated by . removing as much of the lead as possible, by placing it in an iron pot, the bottom of which is preforated with holes, the top being, at the 206 ANNUAL OF SCIENTIFIC DISCOVERY. same time, covered with a tight-fitting lid; heat is then applied, and when the metal is nearly red hot a large quantity of the lead in the alloy will escape, and thus the mass of alloy will become much reduced in size. If care be taken that the heat be not carried to too great a degree, the lead which thus escapes will be found to contain but a very minute quantity of silver. The alloy thus concentrated may next be treated by either of the following methods: First the alloy is placed in closed retorts, or muffles, and exposed slowly to a low heat, and continually stirred, by which means the metal is partly oxydised and falls down in fine powder ; the heat is then increased, and when all the metals (except silver) in the alloy become completely oxy- dised, the whole is transferred to tanks containing dilute sulphuric or muriatic acid, which dissolves the oxides, leaving the silver in the metallic state. Secondly, the alloy is placed in suitable retorts, or distillatory apparatus, formed of Stourbridge clay, or of iron set in clay retorts and lined with powdered bone and charcoal, and by which means the zinc is distilled off in the usual way, after which the back part of the retort is tapped and the residue treated by cupellation, in the way well known. By the process of desilvering lead, known as that of Pattinson’s, many of the English lead mines which are now workable with profit, must otherwise have been abandoned. The chief ore from which lead is extracted is that known as galena, or the sulphuret of lead, furnish- ing from 75 to 80 parts of the metal according to purity. It usually, though not always contains silver in various proportions. Upon the quantity of silver often depends the profitable raising of the ore.— Previous to the invention of Mr. Pattinson, about 20 ounces of silver in a ton of lead were required to render the extraction of that metal worth the cost; since then as little as three or four ounces in the ton of lead will repay extraction. Now, as so many ores contain small quantities only of silver, the importance of the process is evident. In a scientific point of view it is one of much interest, as it consists in so conducting the work that portions of lead can be crystallized, by which the silver becomes excluded, in the manner in which in many crystallizing processes, foreign substances are excluded during crystal- lization, thus by degrees a mixed mass of silver and lead is left, extremely rich in the first metal. When this richness in silver arrives at the point desired, that metal is extracted in the usual manner by cupellation. In one of the lead works in England, in which arrange- ments exist by which the fumes of the furnaces are prevented from escaping, the damage to the surrounding country is obviated, and lead to the amount of 33 per cent. is obtained from the deposits or “ fume.” ZINC OXIDE AS A PIGMENT. Tuts branch of industry has already arrived at much importance in this country through the action of the New Jersey Zinc Company, whose works are dependant upon the red zine ore and Franklinite so long known to mineralogists. The products of this manufacture are CHEMICAL SCIENCE. 207 chiefly two, the white oxide, dry or ground in oil, and of several grades of quality, and the colored pigments formed mainly by grind- ing the raw ore. The zine white is made in large oven-shapen retorts of brick, around which the heat of an anthracite fire is conducted both above and below. These ovens are very low, but of large superfi- cial area. A wide pipe of sheet iron connects each with a very large horizontal tube in which a current of air is kept moving by the revolution of a fan-wheel. This current flows first through the retorts, furnishing air to burn the zinc and means of transportation to the oxyde formed, which is delivered by the current in large cooling chambers. The charge in the ovens is one thousand pounds of crushed red zinc and Franklinite mixed with its own bulk of the dust of anthracite coal. The heat is raised to full redness and so managed as to be hottest on the upper surface of the charge. Reduction of the zine is probably effected by the action of the hot carbon, but the metal is immediately burned by the atmospheric oxygen drawn in by the mechanical action of the blower before named. All the volatile products of this chemical action are drawn through the long tubes and partly delivered into capacious sacks of closely woven muslin suspended in well ventillated apartments. The heat retained by the oxide is not sufficient to scorch the muslin. From the proper openings in the sack the material is collected in casks. In the retorts the residue consists of undecomposed Franklinite and of metallic iron mingled with unchanged carbon. When the best results are obtained the ore yields half its weight of oxide. This oxide is never quite pure, as a small quantity of dust and foreign materials are drawn in with the current of air. Dissolved in acetic acid this residue remains on the filter and perfectly pure carbonate of zinc may be precipitated from the acetate. Chemists will regard this as an important means of procuring chemically pure zinc. It is curious that the carbonate of zine obtained by precipitation when mingled with oil has no “ body,” or does not cover the surface on which it is laid, while the anhydrous oxide obtained in the furnace process covers very well. Water added even in small quantity to the zine oxide ground in oil, will cause the whole mass to solidify. The greater cheapness of zinc oxide, its freedom from poisonous quality, and the fact that sulphuretted hydrogen does not discolor it, are causes which must -lead to the general use of this material in place of lead. The New Jersey Zinc Co. are at present manufacturing about 5,000 pounds of zine oxide daily, from 18 furnaces or retorts, only one-half of which are usually in operation at the same time. The colored paints formed by grinding the crude ore, are sold at very cheap rates and found to possess remarkable power to prevent the oxidation of metallic iron.—Silliman’s Journal. 208 ANNUAL OF SCIENTIFIC DISCOVERY. ON THE PRODUCTS OF SMELTING FURNACES, AS PROOFS OF GEO- LOGICAL HYPOTHESES. A PAPER on the above subject was read before the German Scien- tific Association at Wiesbaden, by Prof. Leonhard, of Heidelberg, of which the following is an abstract: “ For a long period of time,” began the author, “ no particular attention was devoted to scoriz and slags, the secondary productions of all smelting works. As useless and unprofitable, they were thrown aside after the metal had been extrac- ted, as the miner in his shaft gets rid of all waste and unproductive rock.” He then showed how, until lately, the study of lavas them- selves was neglected. ‘The same was the case with scoriz and slags ; they are not, as was formerly supposed, ‘“ accidental combinations of several materials, nor arbitrary mixtures of earths and metallic oxides, which, however occurring again and again in this or that smelting produce, show nevertheless in a quantitative point of view the most endless varieties. ‘The scientific foundation of a theory of the for- mation of scoriz and slags is the work of Mbitscherlich. The production of mineral substances by means of fire, or as the produce of high furnaces by the gradual diminution of the temperature of materials melted together in given proportions, or from vapors, attrac- ted more and more attention. ‘The influence of temperature on the resulting substances is most important, bringing about new combina tions and new conditions out of the same material. ‘These phenomena are most remarkable in the combination of iron and charcoal. ““ Space, quiet, and freedom of motion,” said the author, “are the most important conditions and necessary requisites for the parti- cles of matter to be able to arrange themselves in regular order to produce well-formed crystals; this the chemist had taught us. All products of this kind are subject to unchangeable laws. The more gradual the reduction of the igneous fluid to a solid mass, the more favorable are the conditions of crystallization. If proportions and conditions are the same, we always see the same forms reproduced.” After these words the author described the process of late chemists with regard to the melting and reduction of various rocks, and then rap- idly noticed the numerous minerals and combinations of minerals found in the scoriz and slags of smelting furnaces. “ All scorie,” he added, “have a similarity of substance and degree of flexibility (?) sufficient to enable the metalic particles thus obtained to sink by means of their greater specific gravity. Scoriw have a less specific weight than the products to.be gained by smelting; the latter are pure metals, or a combination of metal with charcoal, sulphur, &e.—the former consist entirely or chiefly of earths. We can thus understand how a cover- ing of slag is formed over the melted treasure as a protection against the influence of fire and of atmosphere.” After mentioning some of the principal minerals obtained from furnaces, and which are the principal ingredients of the most extensively found rocks, he observed that “in a geological point of view these products are of the greatest importance. They point out how nature has ever worked in her CHEMICAL SCIENCE. 209 mysterious abodes, on a still larger scale and with an overwhelming force. ‘These substances will open up a new field for inquiry and investigation for observation and experiments. They will play an important part in all future geological hypotheses, when we have to argue from the known to the ‘unknown. They will fill many a gap in imperfect observations, they will explain various phenomena, explode rash assertions and imaginary assumptions. We may also hope, too, for further information on the question, whether the fundamental rocks of our planet, the form of which presumes a fluid state, were soluble in water; or whether the temperature of the earth was once so high, that the ingredients of certain rocks were ina melted state ?” He concluded by mentioning that, “‘ amongst the products of smelting furnaces there are some which have not yet been found in a natural state Some of the artificial productions, however, have been subsequently discovered in the realms of nature, and there is no reason why we may not expect, with future investigations, te find the others.” NEW TEST FOR MERCURY. Mr. ArtHur MorGan in a paper read before the Dublin Medico- chirurgical Society says, —if a strong solution of iodide of potassium be added to a minute portion of any “of the salts of mercury, placed on a clean bright plate of copper, the mercury is immediately depos- ited in a metallic state, appearing as a silvery stain on the copper, which cannot be mistaken, as no other metal is deposited by the same means. By this method corrosive sublimate may be detected in a drop of solution unaffected either by caustic potash, or iodide of potassium. In amixture of calomel and sugar inthe proportion of one grain to two hundred, a distinct metallic stain’ will be obtained with one grain of the mixture, which of course contains 1-200 of a grain of calomel; in like manner, 1-400 of a grain of peroxide of mercury may be detected, although the mixture with sugar is not in the least colored by it, with preparations of mercury in the undiluted state, this process acts with remarkable accuracy, the smallest quantity of calomel in peroxide of mercury, such as would almost require a mag- nifying lens to perceive, placed on copper and treated with iodide of potassium, will give a distinct metallic stain. The advantages of this test may be briefly stated as follows: — It is a delicate test inferior only to chloride of zinc and the galvanic test of zinc and gold. It is easy of application. It requires a very small portion of the substance to be examined—a matter of no small impor- tance. Acting on the insoluble as well as the soluble salts, it obviates the intermediate process of solution. When it acts, its indications are decisive. As to its disadvantages, the only one which seems tenable is, that although it acts on minute portions, still that must be in a con- centrated condition. = 210 ANNUAL OF SCIENTIFIC DISCOVERY. ON THE PREPARATION OF PURE SILVER FROM CHLORIDE OF SILVER. BY C. BRANNER. Ir has long been known that pure silver for chemical purposes is best prepared by the decomposition of chloride of silver. This decom- position can be performed in various ways: Poggendorff, several years ago, described a process in which it was effected by galvanism ; this appears to me to be preferable to all others hitherto known, and the one here described can only be regarded as a modification of it. Well-washed precipitated chloride of silver is to be put into a cup of silver, platina or copper the outer surface of which is covered with wax in such a manner that only a round space of one or two inches in diameter, according to the size of the cup, remains uncovered. On the bottom of a larger earthen cup a disc of amalgamated zinc is to be laid, on the middle of which the cup containing the chloride of silver is placed, in such a manner that the portion not covered with wax may come in contact with the zinc. Water slightly acidulated with sulphuric acid is now poured into the apparatus, until it rises above the margin of the inner cup, so that this will be completely sunk in the water. The decomposition of the chloride of silver immediately commences at the edge of the cup containing it and proceeds inwards to the middle ; this is readily known by the dark gray color assumed by the silver as it separates ; the decomposition will be completed in from 24 to 48 hours; its completion may be known by there being no longer any chloride of silver visible on stirring the precipitate. The silver thus procured is to be washed with water, and any small residue of chloride of silver which it sometimes retains may be got rid of by diluted ammonia. The silver thus prepared is perfectly pure. It is readily seen that any foreign metals that may be contained in the zinc, can never mix with it, as the disc of zinc lies during the whole operation below the cup containing the silver and never comes in contact with it. CRYSTALLIZATION OF GLASS. ° SomE interesting experiments on this subject have been made by M. Leydolt, in the course of his investigations upon the crystallization of the silicates. He had examined agate by subjecting it to the dissolving action of fluohydric acid, and obtained a surface with pro- jecting crystals of quartz, that were left untouched by the acid. On subjecting glass in the same manner, he was surprised to see that it was far from homogeneous in its texture. All the kinds of glass examined contain more or less perfectly distinct crystals, regular and transparent encased in an amorphous base. ‘The crystals were brought out by exposing it to the vapors of fluohydric acid and vapor of water, and arresting it when the crystals appear; the amorphous part is a little the most soluble in the acid. M. Leydolt observes also that some natural crystals pure and transparent and apparently > CHEMICAL SCIENCE. 211 homogeneous, present similar deficiency in homogeneity with the glass ; and he has the subject under further examination. ON THE DISTRIBUTION OF IODINE. A MEMOIR, it is well known, has been recently published in the proceedings of the French Academy by M. Chatin, on the existence of iodine in the atmosphere, in rain-water, soils, &.* Mr. McAdam, of Edinburgh, ina letter to Prof. Jameson, published in the Philosoph- ical Journal for July, states that he has endeavored with great care to verify the results obtained by M. Chatin, but without success. As the fixed alkalies and their carbonates were re-agents made use of by M. Chatin, Mr. McAdam is inclined to refer the iodine found, to these bodies, Mr. McAdam’s success in detecting iodine in pearl ashes leads to the belief that this substance will be found more gen- erally distributed in the vegetable kingdom than it has hitherto been supposed to be; and this opinion is strengthened by the fact that it has in several instances been detected in charcoal. RESEARCHES ON THE SULPHURETS WHICH ARE DECOMPOSABLE BY WATER. BY E. FREMY. THE object of this paper is to make known the production and principal properties of a class of sulphurets hitherto little examined, and the study of which is alike interesting to chemists and geologists, from the light which it throws on the formation of mineral waters. When we consider the action of water on the sulphurets, we find that these compounds may be divided into three classes; the first com- prises the sulphurets of the alkalies and of the alkaline earths which dissolve in water; the second is formed of the insoluble sulphurets ; the third consists of the sulphurets of boron, silicon, magnesium and aluminum, which are decomposed by water; these latter are scarcely known, owing to their preparation having hitherto been accompanied with great difficulties. In order to a thorough investigation of all the questions which are connected with the decomposition of the sul- phurets by water I first sought for a method by which they might be easily prepared, which is as follows. It is well known that sulphur exerts no action upon silica, boracic acid, magnesia and alumina. I imagined it might be possible to replace the oxygen in these substances by sulphur by the intervention of a second affinity, as that of carbon for oxygen. Such decompositions, produced by two affinities are not rare in chemistry ; and in some yet unpublished experiments on the fluorides, I had observed that the sulphuret of carbon completely decomposed the fluoride of calcium mixed with silica, producing sulphuret of calcium, I was therefore led to presume that the sulphuret of carbon, acting by its two elements upon the preceding oxides, would remove the oxygen by means of the carbon which it contains, and would at the same time form sulphurets ; this supposition I found * See Annual of Scientific Discovery for 1851, p. 231. 212 ANNUAL OF SCIENTIFIC DISCOVERY. confirmed by experiment. In fact, I have obtained the sulphurets of boron, silicon, magnesium and aluminum, by submitting boracic acid, silica, magnesia and alumina to the action of sulphuret of carbon at a high temperature. To facilitate the reaction, and remove the sul- phuret from the decomposing action of the alkalies contained in the porcelain tubes, it is sometimes useful to mix the oxides to be reduced with charcoal, and to form them into little balls similar to those which are used in the preparation of chloride of silicon. ‘These sulphurets correspond to the oxides from which they are derived. The sulphuret of silicon had been obtained in small quantities by Berzelius in the reaction of sulphur upon silicon, and by M. Pierre in the decomposition of chloride of silicon by hydrosulphuric acid. I have obtained this substance with the greatest ease, by passing the vapor of sulphuret of carbon over pellets of charcoal and gelatinous silica placed in a porcelain tube heated toa bright red. The sulphuret of silicon condenses in the tube in beautiful white silky needles, which are not very volatile, but are readily carried along by the vapor. To show the interest which attaches to the examination of this substance, it will suffice to mention here two of its reactions. When sulphuret of silicon is heated in a current of moist air, it is decomposed and furnishes silky crystals of anhydrous silica ; it is evident that we may explain by means of this experiment the natural production of certaim filamentose crystals of silica. The sulphuret of silicon in the presence of water is decomposed with a brisk evolution of hydrosulphuric acid into silica, which remains entirely dissolved in the water, and is not deposited until the liquid is evaporated. It is impossible not to con- nect this curious property with those natural conditions under which certain mineral waters and siliceous incrustations are formed. As the sulphuret of silicon is probably produced in all those cases where silica is submitted to the double action of a bmary compound which cedes sulphur to it, and at the same time appropriates its oxygen, this sulphuret is probably not so rare as has been hitherto thought; and by admitting its presence in those rocks in which sulphurous springs occur, we might explain the simultaneous existence of silica and sulphuretted hydrogen im the principal sulphurous waters. This hypothesis is in some measure confirmed by the interesting observa- tions of M. Descloizeaux, which show that the siliceous springs of the Geysers of Iceland contain a large quantity of sulphuretted hydrogen. In explaining the formation of sulphurous and siliceous waters by the decomposition of the sulphuret of silicon, I am only extending the ingenious theory proposed by M. Dumas to explain the formation of boracic acid. ‘The sulphurets of boron and aluminum were prepared like the sulphuret of silicon, and are likewise decomposed by water. The sulphuret of magnesium I obtained by passing sulphuret of car- bon over pure magnesia; in this case the presence of charcoal does not appear to be of any use. Thissulphuret crystallizes and is soluble in cold water; when its solution is kept at the ordinary temperature, there is but a feeble disengagement of sulphuretted hydrogen; but CHEMICAL SCIENCE. 213 when heated to ebullition, a lively effervescence of sulphuretted hydro- gen takes place and there is an immediate deposition of magnesia.— Comptes Rendus, July, 1852. ON -THE SEPARATION OF MANGANESE. Dr. Gress in a communication to Silliman’s Journal, September, 1852, gives the following statements in regard to the precipitation ot manganese : — Schonbein in a memoir on the relations of peroxide of lead and ozone, has pointed out the remarkable fact that peroxide of lead precipitates manganese completely from its solutions in chloro-hydric and sulphuric acids, a compound of peroxide of lead and peroxide of manganese being formed. A portion of the lead is at the same time reduced to protoxide and unites with the acid with which the manga- nese was combined. Schonbein appears not to have remarked the importance of this observation in an analytical point of view. In investigating the subject carefully, I have been led to the con- clusion that the peroxide of lead constitutes one of the most valuable re-agents in analytical chemistry, since by means of it the oxide ot manganese may be easily and completely separated from a number of other bases, without the employment of ammoniacal salts. The use of ammonia, as is well known, frequently renders analyses con- ducted by the ordinary methods laborious and inaccurate, either from the number of operations involved, from the absorption of carbonic acid from the air, or from the unavoidable loss in driving off the ammoniacal salts by heat. The fact which I have determined, and which serve as the basis of the analytical application of the peroxide of lead are as follows : — Peroxide of lead completely precipitates manganese from neutral solutions in chloro-hydric, sulphuric and nitric acids, slowly in the cold, but very rapidly by digestion or by boiling. The presence of an excess of chloro-hydric or sulphuric acid does not prevent the com- plete precipitation of the manganese; in these cases, however, chlo- rine or oxygen is set free, and the quantity of lead dissolved is greater than that which corresponds to the quantity of manganese precipitated. Such an excess of acid should be avoided as far as possible. ; The presence of an excess of nitric acid prevents the precipitation of the manganese, since hyper-manganic acid is formed and remains in solution. Tartaric acid, and those organic substances which are burned at the expense of the peroxide of lead, do not interfere with the precipitation of the manganese. The organic matter is first destroyed by the oxygen of the peroxide of lead, and afterwards the manganese is precipitated by the excess of the peroxide added. When the quantity of organic matter present is large, it is always better to separate the manganese by means of sulphydrate of ammo- nium in the usual manner. When, however, oxalic acid is present, we may avoid the use either of an inconvenient quantity of peroxide 214 ANNUAL OF SCIENTIFIC DISCOVERY. of lead, or of sulphydrate of ammonium, by means of chlorine or bromine. Lither of these agents readily converts oxalates into carbonates by a well known reaction. ‘The presence of an excess of free acetic or succinic acid, does not prevent the complete precipita- tion of manganese by peroxide of lead. The same observation applies to the presence of sulphate, nitrate, and chloride of ammonium, and therefore, probably to all ammoniacal salts. Salts of protoxide of iron are oxidized and partially precipitated by peroxide of lead. The same remark applies to the salts of cobalt. The precipitation is not complete even after long digestion upon the sandbath. The salts of nickel and zinc are not precipitated by peroxide of lead, and the nickel undergoes no higher oxidation. Peroxide of lead when perfectly free from protoxide does not precipitate baryta, hme, magnesia, strontia, alumina from their solutions. The same remark applies, as might be supposed, a fortiori, to the alkaline bases. The application of these facts to the quantitative separation of manga- nese from the above mentioned bases, with the exception of iron and cobalt, is obvious. Dr. Gibbs then proceeds at some length to consider the several cases separately. ROSIN OIL. WE derive the following facts relative to the manufacture and use of rosin oil for mechanical purposes, from a report submitted to the manufacturing companies of Lowell, Mass., by a committee appointed to investigate the subject. Dr. Samuel L. Dana, chairman. The committee have considered this subject in relation to its manufacture, lubricity, and economical use. Dr. Dana after carefully in- vestigating the subject states as follows : — “ It was early evident to me that the amount of practical information on the subject was very limited, and rested on no fixed principles. I therefore devoted my time to the investigation of principles relating to the process. I am satisfied, after producing about 1,000 gallons, that, with due care guided by principles which have been established, rosin oil of a uniform quality may be con- tinuously produced at a very low rate per gallon. It was desirable, for some purposes, that rosin oil should be deprived of its characteristic odor without detriment. This difficult point has been completely effected, and many gallons have been thus prepared, which have been used by the companies. Deodorization will not probably materially increase the cost of the oil. The first oily product of the distillation of rosin, by a slight and cheap process, becomes applicable to all heavy machinery when mixed with its bulk of sperm oil. The Merrimac Manufacturing Company have used constantly, for several months, this mixture on all parts of their steam engines, except the cylinder, &c., on all their blowing fans, revolving at a speed of 600 or 700 turns per minute, and on all the bearings in the print yard. No evil has resulted from its use. It spends nearly the same as pure sperm oil. It was found, moreover, that while first run rosin oil was found per- CHEMICAL SCIENCE. 215 fectly applicable to all heavy bearings, after undergoing a slight pro- cess, yet when deodorized, a chemical change or motion among its particles was induced, by which it oradually thickened and became unfit for lubrification. This fact led me to believe that rosin oil, under certain circumstances, is an unstable compound. Hence, ‘it was desirable, to put it into a stable state by removing the body or bodies which caused motion to occur. This was effected, and a perfectly limpid and fixed oil was obtained, quite free from the peculiar odor of rosin oil. In reply to certain queries propounded by the committee to an eminent French chemist, communications have been received, which fully show that we are not behind the French manufacturers of rosin oil, either in quality or quantity of product; they have brought to our knowledge a new preparation from rosin oil, in a semi-solid or lardy state, now much used in France, with a ‘steady annual increasing demand. This preparation is a substitute for the various well known substances used in a fatty or soft-solid state for greasing wheels, gear- ing and heavy shafting. Following the specific ‘directions for the pre- paration of this substance, it was found that a hard body like shoe- maker’s wax was produced; an almost instantaneous solidification occurring. After many trials, however, with great modifications of proportions and time, the desired compound was produced, possessing the properties described, and appearing like the samples received from France. ‘This rosin fat has been used with success on iron gearing, and my opinion is favorable to its use as a substitute for tallow, and at a cost much below the average price of that article. The consumption of tallow at the Merrimac Cotton Mills, for the year ending Novem- ber 15th, 1851, was 4,500 lbs., which may be, probably, replaced by the rosin oil substitute. In regard to the lubricity of the oil, the committee states, that rosin oil can be used for lubrification, only when mixed with its bulk of pure sperm oil. By accurate experiments it appears that spinning machinery requires more, and weaving machinery less power, when rosin and sperm oil are used, than when pure sperm oil alone is employed. This may be explained by reference to the kind of machinery, looms consisting chiefly of cam movements. Machinery falls naturally into two classes ; 1st. That with fine or light bearings. 2d. That with cam movements, or with heavy bearings. ‘All machines of the first class will probably require more, and all of the second class less power with the mixture of rosin and sperm oil, than with pure sperm only. Deducting the less pewer required by some machines, from the oreater demanded by others, the committee would avoid the question, whether the cheaper mixed oil would not pay for the balance of greater power, by throwing out all the fine machinery, as a class to which the rosin mixed oil is inapplicable. Experiments made with great care, with the same dynamometer, and under the same circumstances gave the following results :— The average from the trials on nine spinning frames, shows that 13 8-10 19* . 216 _ ANNUAL OF SCIENTIFIC DISCOVERY. per cent. more power is required with the mixture of rosin and sperm oil, than with sperm alone. The average from the trials on six stretchers, shows that 3 7-10 per cent. more power is required with the mixture, than with sperm alone. The average from the trials on five looms, shows that 4 6-10 per cent. less power is required with the mixture, than with the sperm alone. In regard to the economy of rosin oil, itis stated that the mixed oil spends about as economically as pure sperm, and no serious evil has resulted from mixed oil in the long experience of the use of this article. It will be recollected that rosin oil can be used only when mixed with its bulk of sperm oil. Under this division, therefore, the committee have considered to what extent rosin oil my be substi- tuted for sperm in the cotton mills of Lowell. As the bases of their calculation, the oil statistics of the Merrimac Company have been assumed. ‘The total sperm oil used for lubrification by the Merrrimac Cotton Mills for the year ending November 15th, 1851, was 6,772 gallons, — of this amount rather more than one-quarter (26,722 0-0) . . . . . or 1,813 gallons were used for spinning, leaving a balance of 4,959 gallons. Of this balance, rather less than one-fourth, or 1,192 gallons, were used in weaving, which requires by experiment 4 6-10 less power with mixed oil, than with sperm alone, leavmg 3,767 gallons applicable to machinery, which the committee class among those with heavy bearings, and which requiries, at least, no more power with the mixed oil, than with sperm oil only. We have, then, in the Merrimac Company’s Mills 4,959 gallons, or about three- fourths of all the sperm oil used there, for which may be substituted a mixture of equal parts of rosin and sperm oils, thus diminishing the annual amount of sperm oil by 2,479.5 gallons, or nearly three-eights of the whole. The Merrimac Mills are using about one-stxth of the power of the Lowell Corporations. If the other mills use oil in about the propor- tion above, the total annual diminution of sperm oil, by substituting rosin oul, will be 14,877 gallons.” Small as the annual saving in sperm oil thus appears, the committee are of opinion, that it will have been highly important that this result has been approximated, since that amount will probably be multiplied by all heavy bearing machinery in the country now oiled with sperm, and thus an amount of that article will be thrown into the market, which may tend to lower its price and improve its quality.” ON THE TREATMENT OF FAT FOR THE PREPARATION OF CANDLES. MM. Masse and Treboullet, in a communication to the Bulletin de la Societe 1 Encouragement, states :— It is well known that fat may be made to acquire a soapy character by the influence of sulphuric acid. In the manufacture of candles the fat is heated with sulphuric acid, or subjected to mechanical friction therewith ; it is then washed, and the mass being placed in a still, is heated to between 200° and 250° Centigrade to drive off the aqueous vapor and with it the fatty acids. With palm oil, the effect of this treatment is as follows :— CHEMICAL SCIENCE. 217 Palm oil melts at 30° Centigrade ; after the action of sulphuric acid at 38° ; aftér the washing with water at 44.5° Centigrade ; after the distil- lation at 46°. The first product of distillation liquefies at 53.5°, the point of liquefacation then sinks, and the product comes gradually more and more to have a tendency to crystallize. Ifthe entire pro- duct be pressed together, the mass has a melting point of 54.5°, the same as that which first passed over. Some fats, however, present considerable differences in these respects. IMPROVEMENT IN THE MANUFACTURE OF GAS. SoME improvements have been recently patented in England, by Messrs. Barlow and Gore for the manufacture of gas, which are high, spoken of by the London Mining Journal. ‘The processes are based, 1st, upon an improved method of rendering luminous the gases result- ing from the perfect decomposition of water or steam ; and, 2d, upon the conservative influence which hydrogen exercises in protecting the matter upon which the illuminating power of gas depends from decomposition by heat. The first has been often attempted, with dulfous and disputed success. The failures are all traceable to the same sources — first, to the impossibility of securing the complete decomposition of water or steam by any of the means employed, and to the consequent production of a large quantity of vapor, exercising a fearfully destructive influence over the carbonaceous matter under- going decomposition for the purpose of rendering the water gases luminous ; and, secondly, to the presence in the water gases of from 10 to 15 per cent. of carbonic acid, the injurious effects of which upon the flame need not be alluded to, and the expenses of abstracting which by any of the ordinary methods are so considerable as materially to augment the cost of manufacture, besides diminishing the volume of saleable gas. The present patentees propose to obviate these difficul- ties by first condensing the water gases, so as to deprive them of all excess of vapor, and then to pass them through a heated retort con- taining carbonaceous matter, by which the whole of the carbonic acid gas will be converted into twice its bulk of carbonic oxide gas, and the pure hydrogen and the carbonic oxide gases in equal volumes, free from carbonic acid, are afterwards admitted in regulated quantities into retorts where carbonaceous matter is undergoing distillation or decom- - position, and by which they are rendered highly luminous. ‘The con- servative effect of hydrogen upon olefiant gas has not, we believe, hitherto been noticed by chemists. It may, however, be demonstrated by the following very simple experiment : — If olefient gas be passed through a red hot tube, the carbon will be deposited, and the gas be thereby converted into light-carburetted hydrogen, a gas of very low illuminating power. If, however, hydrogen be added to the olefiant gas, the same process may be repeated without causing any deposition of carbon, and with only a diminution of illuminating power in the mixed gases, due to the increased volume of the non-illuminating gas — hydrogen. \ 218 ANNUAL OF SCIENTIFIC DISCOVERY. The practical effect of this property, when applied to gas making, is to reduce the quantity of combustible products, such as tar, &c., and entirely to prevent the deposition of carbon on the interior surface of retorts. The importance of these discoveries will be readily under- stood, when we state that the experience of the patentees leads them to the conclusion that upwards of fifty per cent. may be added to the volume of gas yielded by all descriptions of materials ordinarily used for that purpose, without any diminution of the illuminating power, so that 15,000 cubic feet will be the probable future product from one ton of Newcastle coal, and 75,000 cubic feet of London gas from the same quantity of Boghead Cannel. — London Mining Journal. FLAX COTTON. A PARLIAMENTARY document lately published in England, con- tains a report made by Sir Robert Kane, on Claussen’s invention for the production of flax cotton. Experiments were made by Sir Robert, on a smaller scale than had been intended, in consequence of the want of a sufficient supply of flax. The experiments made were of two kinds, of the results of which the following account is giver — The first was as to the direct preparation of flax cotton from flax straw, in which the separation and cleansing of the fibre from the refuse part of the stalk was made a part of the process, and this was not by any means satisfactorily done. The second was as to the conversion of tow or low priced flax into flax cotton ; and, although in this material the fibre has been already prepared and cleaned by the previous dressings, the product obtained did not approach in fine- ness of texture, uniformity of structure or cleanness of mass to the quality of the specimens of flax cotton that are usually exhibited by M. Claussen’s agents. Under these circumstances, Sir Robert Kane considers the trials “to have been in so far negative as the agents acting for M. Claussen found it impossible to produce satisfactory results in those works which they had themselves selected, and where _ they had been working previously.” At the same time it is admitted that much weight must be conceded to the defective mechanical arrangements. In winding up his report, after mentioning incidentally that when the trials had been concluded and found unsatisfactory, a letter was received from M. Claussen declining to be responsible for the results, and stating that he would prefer that the inquiry should be conducted at some works he had erected near London, Sir Robert Kane observes : — “In regard to the more purely scientific portion of the inquiry, I beg leave to report that several interesting facts have been already ascertained as to the real nature of the material produced, and as to the true action of the materials used. Without being understood to announce a positive conclusion, which in a report of progress would be premature, I beg to state that I am pretty well satisfied that M. Claussen’s process does not at all produce a material approaching in structure or organic quality to cotton. ‘The views of the bursting up CHEMICAL SCIENCE. 219 of the fibres put forward by some persons who have come forward to explain the process in public do not appear to be well founded. The flax fibres are in M. Claussen’s process excessively finely divided and separated from each other, but each remains still a thorough and com- plete flax fibre, and quite unlike cotton, and the same amount of division, and the same fineness and pliability of fibre may be given, and often is given, to flax by simple dressing, especially if the flax had been overretted. This point as to structural character is, however, so fundamental to the value and quality of the flax cotton, that [deem it indispensable to follow up still further the careful microscopic examination of the material in all its stages, and shall, therefore, reserve for a future complete report details and drawings.” M. Hamel lately delivered an address before the Imperial Academy of Russia, on the subject of flax cotton, in which he gives a different account of its invention to what is generally supposed. According to him, a native of Holstein, named Ahnesorge, by trade a dyer and bleacher, had applied himself for several years to improvig flax spinning, as well as to turn to account the tow, which is of little value. For this purpose he made several journies, and in 1838 went to St. Petersburgh with a sample of about a dozen pounds of a cottony material from flax tow. In 1846 the king of Denmark, having been informed of M. Ahnesorge’s industrious efforts, sent him a sum of money to help in establishing a manufactory, but just as he had begun, at Neumeistler, the manufacture of cotton and woolen fabrics, mixed with his cotton from flax tow, the disastrous war of the Duchies broke out, and M. Ahnesorge sought refuge in London, where he arrived in October, 1848. Having applied to one of the principal patent agents for advice, on what steps he should take to procure a patent for his invention, he was introduced to M. Claussen, who, delighted with his project, made an agreement with him, by which he was to take out the patent in his name. Ahnesorge commenced his labors in M. Claussen’s house, in London. His articles were highly spoken of, but he wanted the necessary funds to develope the manufacture. A native of Hamburgh, named Auguste Quitzow, resolved to carry on the manufacture in a large: way in Yorkshire. He bought a place between Bradford and Leeds, and with the consent of Claussen, engaged Ahnesorge to pre- a the flax, and make the cotton according to his method. M. mel says that all the samples, both white and dyed, exhibited at the Crystal Palace in the name of Claussen, as well as in that of Quitlow, Schelennger & Co., were made by M. Ahnesorge ; the public were not informed of this circumstance. The attempts to card and spin Ahnesorge’s products were made near Rochdale, in a factory that Mr. Bright, the well-known politician had placed at the disposal of M. Claussen, who had, in fact, taken out the patent in his own name. The high price of cotton, at the time of the Great Exhibition, had led to the hope that a project for substituting flax would easily find purchasers, and this was the reason why M. Claussen, described, in this patent, a process for cutting the cotton flax into small pieces, of the — 220 ANNUAL OF SCIENTIFIC DISCOVERY. same length as the cotton rovings, so as to be able to card and spin them on the machines constructed for cotton. Besides, he wishes it to be supposed that, by placing the flax thus cut up, after it has been boiled in a solution of bi-carbonate of soda, into sulphuric acid diluted with water, it will split, from developing carbonic gas, in appearance resembling cotton. M. Claussen has started a company with a capital of £250,000 to £500,000, to carry on the manufacture, and he exerts every possible effort to obtain purchasers for his patent. To exhibit his patented process of splitting the flax, he has rented a place at London, where M. Ahnesorge (who is never named) has first to prepare the flax or tow by boiling it in a solution of soda, and where afterwards, the experiment of chemical effervescence is made before visitors. This is called the splitting process. M. Hamel declares it to be impossible to change the flax into a fibrous matter resembling cotton, which is the work of nature. He is decidedly opposed to the project of cutting up the dressed flax into a sort of tow. The superiority of flax over cotton consists, in a great measure, in the greater length of its fibres. The result, therefore, would be to convert a primary valuable material into a very inferior one. PREPARATION OF CYANIDE OF POTASSIUM. M. CiemAn, of Paris, gives the following detailed account of the process for obtaining this salt in a pure state, the accomplishment of which is a matter of some difficulty : — Mix intimately eight parts of ferro-cyanide of potassium, perfectly de-hydrated by calcination, and three parts of perfectly dry carbonate of potash, and heat the mixture in a covered crucible, or what is better an iron pot, until the fused mass attains a red heat, when it will become limpid, and a sample taken out with the rod and cooled, will appear perfectly white, in this state all the ferro-cyanide is reduced. If the crucible be now taken out of the fire, the disengage- ment of the gas ceases when the mass has become a little cool, and the iron which has been separated in the operation so disposes itself, that with a little address and slight tapping of the crucible, the principal part of the cyanide of potassium may be poured off from the iron which remains in the crucible. To obtain the cyanide perfectly free from iron, place it across an iron ladle, pierced with fine holes, and strongly heated beforehand, in a vessel also heated, of greater height than width, either of silver, iron, or porcelain, or even fire ware, but with smooth sides, and let it gradually cool. In this state the ferru- ginous portion may be extracted by means of a sharp instrument from that which is free from iron. The purity of the cyanide of potassium entirely depends on the purity of the materials employed ; the presence of sulphur in the carbonate of potash should therefore be avoided ;. the ferro-cyanide of potassium of commerce almost inva- riably contains sulphate of potass, the presence of which is objection- able. The use of purified tartar might perhaps be advantageously substituted for that of carbonate of potash. Should any sulphur be CHEMICAL SCIENCE. OFT present, a sulphuret of potassium would be formed in the cyanide of that metal, from which considerable inconvenience would arise in the employment of the cyanide in chemical analysis, and in its application to the preparations of the gold, silver, and copper solutions employed in the electro-plating processes. When the mixture is melted, as before mentioned, there is at first formed only cyanide of potassium and carbonate of the protoxide of iron ; but this last quickly changes, at the temperature to which it is exposed, into carbonic acid, carbonic oxide, and sesqui-oxide of iron; and this last, when the cyanide of potassium is melted, becomes converted into metallic iron. It is only by a long sustained heat that the carbonate of protoxide of iron is decomposed, so that long after the decomposition of the ferro-cyanide of potassium, and the formation of cyanide of potassium has taken place, there is still a disengagement of gas. Consequently, the pro- portion of cyanide of potassium, which is simultaneously formed, should entirely depend on the duration of the fusion. The iron which remains after a prolonged fusion of the cyanide of potassium, out of contact of air, bemg washed with hot water, disengages, when an acid is poured on it, not only hydrogen, but always a litle carbonic acid as. If we follow the directions given in most chemical works, in which it is stated that the materials must be melted, so that the mass submit- ted to a bright red heat becomes tranquil, — only a grey colored pro- duct will be obtained. If a closed iron vessel be employed, and the disengaged gases col- lected, it will be seen that in proportion as the temperature rises, the relative proportion between the carbonic acid and the carbonic oxide changes, the latter constantly increasing. It is evident that at a high temperature, one portion of the carbonic acid, which passes through the cyanide of potassium, should be reduced into carbonic oxide, and this reduction, without doubt, extends even in part to the carbonic oxide itself; that is to say, that its carbon is separated, and that this renders the product of a grey color. If we dissolve in cold water some cyanide of potassium completely free from particles of iron, and which has thus become grey, and filter the solution, there remains in the filter a black substance, which, being dried, burns away completely on a slip of platinum, and in fact, possesses all the qualities of char- coal. This carbon, in a state of extreme division, does not separate, either by fusion or repose, from the cyanide of potassium, on account of its feeble specific gravity. Ifa little of this grey cyanide be added to each new melting, it may be purified from this carbon, and no injury done to the product of the new materials employed, as the iron in separating, withdraws the finely-divided carbon, and leaves the cyanide in a state of purity. LIQUID GLUE. M. DuMmo tin publishes the following article on the preparation and nature of liquid glue,in the Comptes Rendus, Sept., 1852. Chem- > 222 ANNUAL OF SCIENTIFIC DISCOVERY. ists well know that heating and cooling repeatedly a solution of glue, (gelatine,) in contact with the air, it looses its property of becoming a jelly. M. Gmelin has shown, that a solution of fish glue in a sealed tube, placed in a water bath heated to the boiling point for several days, exhibits the same phenomena, 7. e. the glue remains liquid, does not gelatinize upon cooling. The change effected, is one of the most difficult problems to resolve, of organic chemistry. It appears to be a product of the action of the oxygen of the air and the water upon the glue, as demonstrated from the action of a small quantity of nitric acid, on a solution of strong glue. We know that on treating gelatine with an excess of this acid in the presence of heat, it is conv verted into malic and oxalic acids, fat, tannin, &c. This does not occur when we treat the glue dissolved in its weight of water, with a very small quantity of nitric acid; we obtain only a strone glue which preserves a long time its primitive qualities, and which no longer has the property of celatinizing. In this manner the glue sold in France under the name of liquid and unchangeable glue, is fabricated. This glue is exceedingly conven- ient for cabinet makers, joiners, pasteboard manufacturers, toy makers, &c., since it can be used cold. It is prepared as follows : — Dissolve two pounds of strong glue in one quart of water in a glue kettle, or in a water bath, when the glue is entirely melted, add little by little, to the amount of ten ounces of strong nitric acid. ‘This addition produces an effervescence due to the disencagement of hypo- nitric acid, when the whole of the acid is added, 1 remove the vessel from the fire, and leave it to cool. I have preserved glue thus pre- pared, more than two years in a stoppered flask, without -its under- going any alteration. This liquid glue is very convenient in chemical operations. I have employed it with adv antage in my laboratory, for the preservation of different gases, the same as s lute, covering the little bands of linen with the glue.” PERFUMERY AND THE ARTIFICIAL EXTRACTS OF FRUIT. Dr. PLAYFATR, in his lecture on the Results of the Great Exhi- bition, thus briefly notices a new class of perfumes and essences, which of late have attracted no little attention. Much aid has been given by chemistry to the art of perfumery. It is true that soap and perfumery are rather rivals, the increasé of the former diminishing the use of the jatter. Costly perfumes, formerly employed as a mask to want of cleanliness, are less required now that soap has bécome a type of civilization. Perfumers, if they do not occupy whole streets with their shops, as they did in ancient Capua, show more science in attaining their perfumes than those of former times. ‘The jury in the exhibition, or rather two distinguished chem- ists of thaf jury, Dr. Hoffman and M. De la Rue, ascertained that some of the most delicate perfumes were made by chemical artifice, and not, as of old, by distillimg them from flowers. The perfume of flowers often consists of oils and ethers, which the chemist can com- CHEMICAL SCIENCE. 238 pound artificially in his laboratory. Commercial enterprise has availed itself of this fact, and sent to the exhibition in the form of essences, perfumes thus prepared. Singularly enough, they are gen- erally derived from substances of intensely disgusting odor. A peculiarly fetid oil, termed ‘“ fusel oil,” is formed in making brandy and whisky. This fusil oil, distilled with sulphuric acid, and acetate of potash, gives the oil of pears. The oil of apples is made from the same fusel oil, by distillation;with sulphuric acid and bichromate of potash. The oil of pine apples is obtained from a product of the action of putrid cheese on sugar, or by making a soap with butter, and distilling it with alcohol and sulphuric acid, and is now largely employed in England in the preparation of the pine apple ale. Oil of grapes and oil of cognac, used to impart the flavor of French cognac to Brit- ish brandy, are little else. than fusel oil. The artificial oil of bitter almonds now so largely employed in perfuming soap, and for flavor- ing confectionery, is prepared by the action of nitric acid on the fetid oils of gas tar. Many a fair forehead is damped with eau de mille- fleurs, without knowing that its essential ingredient is derived from the drainage of cow houses. The wintergreen oil, imported from New Jersey, being produced from a plant indigenous there, is artificially made from willows, and a body procured in the distillation of wood. All these are direct modern appliances of science to an industrial pur- pose, and imply an acquaintance with the highest investigations of organic chemistry. Let us recollect that the oil of lemons, turpentine, oil of Juniper, oil of roses, oil of copaiba, oil of rosemary, and many other oils, are identical in composition ; and it is not difficult to con- ceive that perfumery may derive still further aid from chemistry. Prof. Fehling, in the Wurtemberg Journal of Industry, gives the following abstract of what is at present generally known respecting the composition and production of some of the artificial extracts of fruit. He says: Amongst the chemical preparations exposed at the London Exhibi- tion, the artificial extracts of fruits were particularly deserving of attention. Although some of these extracts, as, for instance, butyric ether, have already found applications, their use has been hitherto only on a very limited scale. It is now, however, no longer to be doubted but that the majority of our artificial organic compositions will, ere long, be extensively applied, and their practical applications cannot but have a very stimulating effect on the study of organic chemistry, which will again most probably lead to the discovery of technical applications for the new organic compositions, which the investigations of our modern chemists have furnished us with. Among the extracts of fruit exhibited by a London manufacturer, those which more particularly attracted attention were pine apple oil, bergamot pear oil, apple oil, grape oil, cognac oil, &c. Several of these oils have been analyzed by M. Faiszt, of Stuttgardt. We give here a succinct description of some of these extracts, and of their manu- facture. Pine Apple Oil.— 'This product consists of a solution of 1 part of 20 224 - ANNUAL OF SCIENTIFIC DISCOVERY. butyric acid ether, in 8 to 10 parts of spirits of wine. For preparing butyric acid ether, pure butyric acid is required, and this is obtained most readily, and in the greatest purity, by the fermentation of sugar or of St. John’s bread, (siliqua dulcis.) For preparing butyric acid from sugar, M. Bentch takes a solution of 6 pounds of sugar, and half an ounce of tartaric acid in 26 pounds of water, which is left to stand for some days; at the same time about a quarter of a pound of old decayed cheese is diffused in 8 pounds of sour milk, from which the cream has been removed; and after this has also stood for some days, it is mixed with the first solution, and the whole is kept from four to six weeks at a temperature of about 24° to 28° Reaumer, water being added from time to time to replace that which is lost by evaporation. After the evolution of gas has entirely ceased, the liquid is dissolved with its own bulk of water, and finally 8 pounds of crystallized soda, dissolved in 12 pounds to 16 pounds of water, are added toit. The liquid is then filtered and evaporated till it weighs only 10 pounds, when a quantity of 54 pounds of sulphuric acid, (nordhausen, or fum- ing sulphuric acid,) diluted with 53 pounds of water, is carefully mixed with it by small portions at atime. The butyric acid, in the state of an oily substance, will now appear on the surface of the liquid, from which it may be skimmed off; but as the remaining liquid still contains some butyric acid, it is submitted to distillation, by which means another portion of diluted butyric acid is obtained, which may be concentrated by means of melted chloride of calcium, or by satu- rating it with carbonate of soda, evaporating and decomposing by sulphuric acid. By this method 13 pounds of pure butyric acid are obtained from 6 pounds of sugar. M. Marsson says that the same product may be obtained from St. John’s bread, (siliqua dulcis,) by taking 4 pounds of mashed St. John’s bread, and mixing it with 10 pounds of water and 1 pound of chalk; the liquid matter must be maintained from three to four weeks ata temperature of frgm 25° to 35° Reaumer, and be often and well stirred, and from time to time the water that has evaporated must be replaced. After all fermentation has ceased, a quantity of water equal to the bulk of the liquid is added to it, and afterwards a concentrated solution of 24 pounds to 23 pounds of carbonate of soda, when it is finally evaporated. To the concentrated liquid is then added 1} pounds to 2 pounds of sulphuric acid, diluted with 2 pounds of water ; and the remainder of the process is performed in the same manner as already described. By this method a little more than half a pound of colored butyric acid will be obtained. ‘The acid, however, retains a peculiar smell from the St. John’s bread, which continues even in the ether prepared from the same, whereas that prepared from sugar gives an ether of a very pure smell. It will be found advantageous to agi- tate the oily butyric acid with chloride of calcium, in order to deprive it entirely of its moisture. For preparing butyric acid ether, (butyrate of oxide of ethyle,) from butyric acid, 1 pound of butyric acid is dissolved in 1 pound of rectified alcohol, (95° Tralles,) and is mixed with one-half to one- CHEMICAL SCIENCE. 995 fourth of an ounce of concentrated sulphuric acid; the compound is heated for some minutes, when the butyric acid ether will form a thin layer on the top. The whole is then mixed with half of its bulk of water, and the upper layer taken off; the remaining liquid being sub- mitted to distillation, yields another quantity of butyric acid ether, which is mixed with that obtained in the first instance, and the whole well agitated with a very diluted, solution of soda, in order to deprive it of all the acid; which operation should be repeated several times if a very pure ether is desired to be obtained. Care should be taken to use but small quantities of the diluted soda solution at a time, so as not to lose too much ether, this latter being in some measure soluble in water. When large quantities are to be acted upon, the washing water (eau de lavage,) is collected, mixed with an equal volume of spirits of wine, and distilled, by which means a solution of pure buty- ric acid ether in spirits of wine is obtained. Butyric acid ether may be also obtained immediately from butyrate of soda, by dissolving 1 part of this salt in 1 part of rectified alcohol, adding 1 part of sulphuric acid, and heating some minutes. The ether collects on the top of the liquid, and is purified by washing with water and with diluted soda solution. For preparing pine apple oil, 1 pound of butyric acid ether is dis- solved in 8 pounds to 10 pounds of spirits of wine, which should have been previously deprived of its empyreumatic or fusel oil. Pure French spirits of wine will be found best suited for this purpose. According to the purpose for which the pine apple oil is to be applied, either rectified alcohol of 80° to 90° Tralles, or brandy of 40° to 50°, should be used for dissolving the ether. 20 drops to 25 drops of such an extract will suffice for giving a strong pine apple odor to 1 pound of sugar solution; to which some acid, such as tartaric or citric acid, is generally added. Bergamot Pear Oil. — What is called pear oil is an alcoholic solu- tion of acetate of oxide of amyle, and acetate of oxide of ethyle, pre- pared from potato fusel oil, (the hydrate of oxide of amyle.) The potato fusel oil, or oil of potato spirits (in German, /fuseloel,) is the compound distilled over towards the end of the first distillation of spirits made from potatoes, and is an oily liquid of a very strong and nauseous odor. This oil, in the state in which it is obtained from large potato brandy distilleries, is never pure; but it may be purified by agitating it with a diluted soda solution, when the pure fusel oil collects as an oily layer on the top of the liquid; this oily substance is then submitted to distillation, and that part which distils over at 100° to 112° Reaumer, is collected, and forms the pure fusel oil. For preparing acetate of oxide of amyle from this fusel oil, 1 pound of pure ice vinegar is mixed with an equal quantity of fusel oil, to which is added half a pound of sulphuric acid ; the liquid. is digested for some hours at about 100°, when the acetate of oxide of amyle separates, particularly on being mixed with a small quantity of water. The remaining liquid, when mixed with more water, yields, on being submitted to distillation, a further quantity of acetate of oxide of 226 ANNUAL OF SCIENTIFIC DISCOVERY. amyle. The entire mass of acetate of oxide of amyle thus obtained is now agitated several times with water, and a little soda solution, in order to deprive it of all free acid. The acetate of oxide of amyle may also be obtained by taking 1 part of fusel oil to 14 part of dry acetate of soda, or 2 parts of dry acetate of potash, with 1 to 14 parts of sulphuric acid. The liquid having been kept for some time at a gentle heat, the acetate of oxide of amyle is separated by adding water, and proceeding as above explained. 15 parts of acetate of oxide of amyle are mixed with 13 part of vinegar ether (vinegar naptha, acetate of oxide of ethyle,) and dissolved in 100 to 120 parts of spirits of wine, as in the case of pine apple extract ; an acid, for instance, tartaric or citric, should be added to the sugar solution, on making use of the pear extract, which addi- tion makes the flavor of the bergamot pear better distinguishable, and he taste acquires at the same time more of the refreshing qualities of ruit. Apple Oil. — What is called apple oil, is a solution of valerianate of oxide of amyle in spirits of wine, which may be obtained as a secon- dary product when fusel oil is distilled with chromate of potash and sul- phuric acid for the preparation of valerianic acid. The light solution which collects in the tops of the distilled liquid contains valerianate of oxide of amyle, together with other liquids, such as aldehyde, which gives to the product a less agreeable taste and smell. It is therefore to be preferred for preparing pure valerianate of oxide of amyle. For preparing valerianic acid, 1 part of fusel oil is mixed by small portions with 3 parts of sulphuric acid, and afterwards 2 parts of water are added. At the same time, a solution of 23 parts of bichromate of potash in 43 parts of water, is heated in a tubular retort; the first liquid is then permitted to flow very slowly into the liquid of the retort in such manner that the boiling continues but very slowly. The hquid which is distilled over is saturated with carbonate of soda, and is evaporated either to dryness for obtaining valeriarate of soda, or to the consistency of syrup, when sulphuric acid is added, (say two parts of concentrated acid diluted with the same quantity of water, for every three parts of crystalline carbonate of soda.) The valerianic acid forms an oily layer, on the upper part of the liquid ; which latter will still yield some valerianic acid, on being submitted to distillation. For preparing valerianate of oxide of amyle,1 part by weight of pure fusel oil (hydrate of oxide of amyle,) is mixed carefully with an equal quantity by weight of common English sulphuric acid; the resulting solution is added to 14 parts of oily valerianic acid, or to 13 parts of dry valerianate of soda, and is treated by a water bath, and then mixed with water, by which means the impure valerianate of the oxide of amyle will be separated; this is washed several times with water, afterwards with a solution of carbonate of soda, and finally again with water. In preparing this compound, it is essential, that the mixture of sulphuric acid and fusel oil, with valerianic acid, should not be heated to a too high degree, or too long, as the product would thereby acquire an insufferably pungent smell, when required for use. 1 part CHEMICAL SCIENCE. O27, of valerianate of oxide of amyle is dissolved in 6 or 8 parts of spirits , of wine, and acid is added in the same manner, as has been before explained in the preparation of other extracts. Artificial Oil of Bitter Almonds.— When Mitscherlich, in 1834, discovered nitro-benzole, he little thought, after twenty years to find this body in an industrial exhibition. He certainly, at that time pointed out the remarkable resemblance which the odor of nitro-ben- zole had to that of oil of bitter almonds; but the only sources for obtaining benzole at that time, viz., the oil of compressed gas, and the distillation of benzoic acid, were much too expensive, and put an end to the idea of substituting the use of nitro-benzole for oil of bitter almonds. Mansfield, however, in 1849, showed by careful investiga- tion, that benzole may be procured easily and in large quantities from oil of coal tar, and this discovery has not been lost sight of in the arts. Among the articles of French perfumery in the Great Exhibition, with the title of artificial oil of bitter almonds, and the fanciful name of essence of Mirbane, there were several specimens of oils, which consisted of more or less pure nitro-benzole. The apparatus used in the preparation of this substance is that proposed by Mr. Mansfield. It consists of a large glass worm, the upper end of which branches into two tubes, which are provided with funnels. A stream of con- centrated nitric acid flows slowly through one of these funnels, whilst the other is for the benzole, (which for this purpose need not be abso- lutely pure.) At the point at which the tubes of the funnels are united, the two bodies come in contact, the chemical compound formed becomes sufficiently cooled in passing through the worm, and only requires to be washed with water, and finally with some weak solution of carbonate of soda, to be ready for use. Although the nitro-benzole closely resembles oil of bitter almonds, in physical properties, it pos- sesses, however, a somewhat different odor, readily recognized by a practised person. However it answers well for scenting soap, and would be extensively applicable for confectionary and for culinary purposes. For the latter purpose it has the special advantage over oil of bitter almonds, that it contains no prussic acid. The application of organic chemistry to perfumery, is still in its infancy ; and we may expect that a careful survey of those ethers and etherial compounds with which we are at present acquainted, and those which are daily being discovered, will lead to further results. The interesting caprylic ethers which M. Blouis has lately discovered are remarkable, for their extremely aromatic odor, (thus the acetate of caprylic oxide possesses an odor as strong as it is agreeable,) and promises, if they can be obtained in larger quantities, to yield mate- rials for perfumery. — Hoffman’s letter to Liebigq. The subject of the composition and artificial production of the various extracts of fruit and other similar perfumes and essences, strikingly illustrates the wonderful progress which has been made in organic chemistry within the last few years. A position has been taken by some chemists who have carefully investigated this subject, which cannot at present be controverted, that the extracts or perfumes 20* 228 ANNUAL OF SCIENTIFIC DISCOVERY. - of the various fruits which can be artificially prepared in our labora- tories from the basic organic radicals, are identical, and the same with those which nature carefully elaborates in the apple, the pear, the pine apple, banana, and the like. The whole subject has been investigated more carefully, and has been applied to more practical purposes than the public is generally aware of. ‘Take for instance the well known perfumes, known as “ Lubin’s Extracts,” extract of geranium, mille- fleurs, new-mown hay, and many others ; all of these are stated to be prepared from two or three of the common and cheap essential oils, and from the organic radicals. In addition to perfumes the most agreeable, odors of the most disgusting and nauseous character can also be produced by like means; as for instance, the odor of the bed- bug, squash-bug, and of many of the common weeds and plants. As an odor, or perfume of a different character can be produced by the action of each different acid on the different oxides of the organic radicals, the number of bodies of this character capable of being pro- duced is almost innumerable, and may possibly embrace every known odor, or perfume, which is now recognized in the animal, vegetable, or mineral kingdom. The various artificial extracts of fruit have been applied to the flavoring of an agreeable species of confectionary known as the “acidulated fruit drops.” These have been denounced as poisonous by some persons, on the ground that fusel oil is known to produce deleterious effects; and asa natural consequence the confectionary referred to has been discarded. ‘There is, however, no foundation for such statements or belief, and if the confectionary flavored with these extracts has in any case produced injurious effects, it 1s undoubtedly to be referred to an injudicious consumption of it, and not to any inherent deleterious property. — Editor. POISONOUS CHLOROFORM. Tue following is a extract from a letter addressed to the Boston Medical and Surgical Journal, by Dr. C. T. Jackson, respecting the poisonous qualities of chloroform, when the so-called fusel oil is con- tained in it. Dr. Jackson says: — I have had a strong suspicion that the very sudden deaths resulting from the inhalation of chloroform must have been produced by the presence of some poisonous compound of amyle, the hypothetical radical of fusel oil, or the oil of whisky ; and I began a series of researches upon this subject several years ago, but was called off from my work by unexpected persecutions. This work I have resumed, and I will now state what facts and inductions I am able to lay before the public : 1. When chloroform, and the alcoholic solution of it ealled chloric ether, was made from pure alcohol diluted with water, no fatal acci- dents occurred from its judicious administration. 2. When chloroform was made, as it now too frequently is, from CHEMICAL SCIENCE. 229 common corn, rye and potato whisky, death began to occur, even when the utmost care was taken in its administration. From these data, it might justly be inferred that some poisonous matter exists in the cheap chloroform of commerce, and I suspected that it arose from the fusel oil which exists in the whisky. Having succeeded in procuring some very pure fusel oil, (of whisky,) I undertook the researches which have resulted in the conviction that it is the amyle compound that produces the poisonous matter of certain kinds of chloroform. When mixed with hypochlorite of lime (bleaching powder) and water in the same way as we prepare alcohol for the production and distillation of chloroform, I found that the mixture in the retort, after agitation and standing some time, became warm, indicating that a reaction was taking place between the fusel oil and the hypochlorite of lime. After some hours the retort was placed in a water bath, and distil- lation was effected, the volatized liquid being copdensed by means of one of Liebig’s condensers. A clear colorless hquid came over, which was at once recognized as having the peculiar odor of bad chloroform. It is perhaps a ter-chloride of amyle, but has not yet been submitted to analysis. It is so powerful that merely smelling of it makes one dizzy. ‘In order to make sure that the fusel oil was all decomposed, I again mixed the product of distillation above mentioned, with a new lot of bleaching powder and water; and after three hours, with frequent agitation, it was again distilled, and gave what I regard as the pure unmixed poison. If my views are correct, it follows : 1. That all chloroform intended for inhalation as anesthetic agent, should be prepared from pure rectified alcohol, to be diluted with water when used for distillation from hypochlorite of lime. 2. That no druggist should sell for anesthetic uses, any chloroform which is not known to have been properly prepared as above suggested. 3. That the mixture of chloroform and alcohol, commercially known under the name of strong chloric ether, must be made with the same precaution as chloroform. The following experiments were subsequently made by Dr. Jackson, which conclusively prove the poisonous effects of fusel oil when mixed with chloroform : — A full grown rat, confined in a quart glass jar, inhaled the vapor of the fusel oil compound 40 minutes without any apparent injury. A kitten seven days old inhaled the vapor of this compound nine- teen minutes, without apparent effect. Three kittens, of the same litter, were confined in three separate vessels, also saturated with this vapor, thirty-three minutes, and when released appeared as unharmed as a fourth kitten, of the same litter, confined in a similar vessel supplied with atmospheric air. A person inhaled this vapor. twelve minutes without any effect. The rat, of the above mentioned experiment, was then exposed to the mixed vapors of chloroform and of the fusel oil compound. In 230 ANNUAL OF SCIENTIFIC DISCOVERY. fifty-five seconds he rolled upon his side, and in three and a quarter minutes he was taken out dead. A half-grown cat, in a vessel of equal capacity, bore the vapor of chloroform alone but thirty seconds before he fell on his side, and was taken out dead in two minutes. A kitten, of the litter above mentioned, exposed to the vapor of chloroform, became insensible in two minutes. It was taken out in two minutes and twenty-three seconds and partially revived. It was again returned to the jar, and in two minutes became insensible, but continued to breathe slowly for nine minutes, when it was taken out, and finally recovered. In all the above experiments the air in the jars was repeatedly removed with the aid of a bellows. CHLORIC ETHER, CHLOROFORM, AND TINCTURE OF CHLOROFORM. THE following statement prepared by Dr. A. A. Hayes, of Boston, at the request of Dr. Warren, and published in the Boston Medical Journal, clearly sets forth the distinction between the various anesthetic agents, chloric ether, chloroform and tincture of chloroform. Chloric Ether. — This substance is the product arising from the action of hypochlorites of the alkalies, alkaline earths, on a large excess of alcohol, much diluted with water.. It is obtained by distillation, and when carefully prepared contains chloroform, chlorinated ether, and alcehol. In its formation, a large quantity of acetic acid is pro- duced, and unites with chlorine and the base of the hypochlorite used in producing it. It is a permanent compound, possessing the grateful odor and sweet taste of chloroform ; when evaporated from the hand, or clean linen, it leaves no odor adhering to the surface. In this state it is efficient and convenient for use, as an anesthetic agent. It is indefinite in composition, but when decomposed by mixture with two bulks of water, it should deposit about one-third of its original bulk of heavy oily fluid. The extended use of this substance by some of the sur- geons of the Massachusetts General Hospital, has led to the attempt to substitute for it, the tincture of chloroform. It will be seen that these are not like bodies, and as it is more difficult to prepare chloric ether than chloroform, the manufacture of the former will doubtless remain in the hands of the skilful pharmaceutists. Chloroform.— This substance, as a secondary product, is found after many reactions, in which chlorine and hydrocarbons are present. When obtained from hypochlorites and alcohol, the proportion of the latter substance is very small relatively to that of the hypochlorite used. After careful purification it is a definite compound of well- known physical characters. There is, however, an important chemical character recently observed, which should form a part of its history— it is decomposed by solar light. In the early stages of its changes, the odor remains fragrant for some time, but is succeeded by a suffo- cating and corrosive vapor, arising from the action of hydrochloric CHEMICAL SCIENCE. 231 (muriatic) acid on hydrocarbons present. If the remaining chloro- form is carefully washed and purified, and again exposed, the same changes succeed ; conclusively proving that the property is inherent. The risk attending the use of compounds having the same odor, but really foreign in composition arising from the use of alcohol, which contains fusel oil, in the manufacture of chloroform, is obvious. There is, however, a preparation sold under the name of tincture of chloroform, which is objectionable, and as it has been substituted for chloric ether, has been examined. When chloroform is added to alcohol of 85 per cent., it dissolves until about double the value of the alcohol has been mixed. After subsidence, a singular change has taken place; the water, fusel oil, and some alcohol, unite to form a layer on the surface of the dense alcoholic solution of chloroform. This may be removed, but the solu- tion remains too strong for use. Any alcohol of the shops added, introduces water, hastening the change which chloroform undergoes. When anhydrous alcohol is used, unless distillation has been a resort, the tincture is subject to the same change from neutral 'to acid state, as chloroform exhibits. After such change hydrochloric acid may be found in it uncombined, unfitting it for any use. Theoretically and from observation, the compound chloric ether seems to be the most permanent and convenient form in which the power of chloroform can be exhibited, and as such, should take the place of chloroform, in medical and surgical practice. The following correct method of preparing chloric ether, is furnished by Mr. Atwood, of Boston, a chemist of much experience in the sub- ject. He says: — “Tn my process for the production of chloric ether, the alcohol is perfectly freed from fusel oil. A larger proportion of alcohol and water are also employed than in the manufacture of chloroform. The following are the proportions I use, viz: — Chloride (hypochlorite) of lime, 10 Ibs.; water, 8 gallons; pure alcohol, 1 gallon; carbonate of soda, (crystallized,) half pound. Break down the chloride of lime in the water until the excess of hydrate of lime is in a uniform pulpy mass, and the chloride is perfectly dissolved. Place the mass ina still capable of containing twice the quantity, and introduce the alcohol. Mix perfectly and apply a moderate fire under the still until distil- lation commences. Continue the distillation as long as a portion of the distillate will deposit chloroform on being mixed with its bulk of sr then change the receiver and collect one gallon of alcoholic quid. Add water to the first portion of the distillate as long as chloroform is precipitated. Separate the light liquid from the chloroform, and wash the latter in twice its bulk of water containing the carbonate of soda. Separate the chloroform from the carbonate of soda and weight it. Mix the chloroform, washings, and alcoholic liquid in a still placed in a water-bath. After twenty-four hours’ repose, distill three times 232 ANNUAL OF SCIENTIFIC DISCOVERY. the weight of the chloroform, and mix perfectly. Preserve in well- stopped bottles. The ‘chloric ether’ must not redden litmus paper, or give rise to a precipitate when mixed with a solution of nitrate of silver.” ON THE VULCANIZATION OF INDIA RUBBER. Aw elaborate memoir on the sulphuration of caoutchouc has been communicated to the French Academy by M. Payen, of which the following is an abstract. The principal conditions of success, says M. Payen, in the practical operation of sulphuration have been care- fully determined in England, America and France, but it has not been known in what the chemical action consisted; there was no ac- curate idea concerning what has been called the desulphuration ; finally, certain alterations, especially the rigidity and fragility of several objects after sometimes a very short duration of the use for which they were destined, could not be comprehended, nor, conse- quently, prevented. The researches I have undertaken, will, I think, clear up this point of applied science ; I will first describe what occurs in one of the first processes of vulcanization, still employed by several manufacturers. If a sheet of caoutchouc, two or three millimetres in thickness, be kept for two or three hours immersed in sulphur, liquified at the temperature of 201° to 208° Fahr., the liquid will pene- trate into the pores as water or alcohol would do, and the weight of the sheet will be increased 10 or 15 per cent. No considerable mod- ification, however, will have been made in the properties of the organic matter; it may be fashioned, and its recent sections joined the same asin the normal state. Solvents will attack it with the same energy. It is, however, less porous. If, then, we raise in any medium whatever, inert of itself, the temperature to 275°, 302°, or 320° Fahr., the conversion will be effected in a few minutes. The mark would be overshot by prolonging the action of the heat; the product would become gradually less supple and less elastic, and would very soon be hard and brittle. This last alteration would be more com- plete if the caoutchouc were maintained at the same temperature, (275° to 320° Fahr.,) in fused sulphur ; the proportion of the latter body absorbed would gradually increase, until it became, in 24 hours, almost equal to the weight of the organic matter, or would constitute 48 per cent. of the compound. From the commencement of the action of the sulphur at this temperature, a slight but continuous disengagement of sulphuretted hydrogen occurs. At the same time an equivalent quantity of organic matter, containing more carbon than caoutchouc does, is separated, and may be extracted with a hot solution of caustic potassa or soda, which do not perceptibly attack the mass of caoutchouc combined with the sulphur. Liquid sulphur, at the temperature of 302° absorbs, and may retain, a volume of sulphuretted hydrogen almost equal to its own. A curious phenome- non results from the foregoing facts. At the moment when the abatement of temperature allows the sulphur to crystalize, every CHEMICAL SCIENCE. 233 crystalline particle liberates a bubble of gas; the latter is sometimes disengaged, and sometimes is interposed among the crystals; so that the entire mass gradually swells up, increases from 15 to 20 per cent. in its original bulk, instead of diminishing, as it should have done during a normal crystallization of sulphur. Instead of making the liquid sulphur penetrate at a temperature approaching its fusing point, caoutchouc may be mixed by means of a mechanical grinding, with 12 or 20 times its weight of sulphur in fine powder; the properties of the organic substance are not changed, it may be modelled and joined as in the normal and unmixed state. If the temperature be then raised to the degree at which, the vulcaniza- tion is effected, it takes place as in the first case, and the above mentioned alterations would likewise be manifested. In regard to the composition and properties of the caoutchouc vulcanized by the means above indicated, it has been found, that when the suitable term has not been exceeded, the organic matter contained sulphur in two different states; from 1 to 2 per cent. are retained in intimate combi- nation, and the surplus remains simply interposed between its pores. The sulphur in excess, uncombined, is gradually eliminated from the caoutchouc by the mechanical action alternately exerted by the extension which closes the pores, and the contraction which opens them. This effect lasts for several months. Many chemical agents more or less quickly or completely effect the elimination of the interposed sulphur, especially solutions of caustic potassa or soda, with the aid of heat, (and even without heat if renewed several times within a month,) sulphuret of carbon, essence of turpentine, benzine and anhydrous ether. These liquids swell up the organic matter to such an extent that its volume is very soon increased eight. or nine times. Ether removes sulphur in a very peculiar manner; a small portion is first dissolved, and then carried out, when it is separ- ated into crystalline particles; other particles successively dissolved in the interior follow the same course, and the crystals soon become very bulky, affecting the octahedral form. Neither essence of turpentine, or benzine bring to the outside the crystalline particles of sulphur carried into the thickness of the swelled-up substance. Ether and sul- phuret of carbon, kept for a long time in contact with vulcanized caoutchouc retain in solution 4 or 5 hundredths of caoutchouc, which may be isolated by evaporating several times and redissolving in ether which eliminates the free sulphur, and then by alcohol which removes from 1 to 1-50 per cent. of fatty matter. The caoutchouc thus ex- tracted may be separated into two parts; one, very ductile dissolved by benzine, which deposits it in evaporating ; the other more tena- cious, and less extensible, is not dissolved. These two parts come from the interior of the plates, at a certain depth where the combi- nation is less intimate and less abundant in sulphur than near the surface. After vulcanization, caoutchouc is also formed of two parts endowed with unequal cohesion and solubility ; this is recognized by keeping a strip steeped for two months in a mixture of 10 parts of sulphuret of carbon and one part of anhydrous alcohol; the portion 234 ANNUAL OF SCIENTIFIC DISCOVERY. dissolved consists of interposed sulphur, which is removed after dessication by a solution of caustic soda; there then remains the least ageregated and least resistant organic substance, which is yellowish and translucent. The undissolved portion then remains under the form of a tenacious strip, which has become brown and less transparent. The following are the proportions obtained, besides the fatty matter: tena- cious insoluble portion, 65 ; soft soluble portion, 25; sulphur in excess, 10. The process of vulcanization in the cold way, imvented by Mr. Parker, of England, consists in immersing the sheets, or tubes of caoutchouc ina mixture of 100 parts of sulphuret of carbon, and 2.5 protochloride of sulphur. The liquid in penetrating into the organic substance, swells it, and deposits the sulphur, which combines with the caoutchouc, abandoning the unstable combination which it formed in the chloride. The- superficial portion would be too strongly vulcan- ized and become brittle, if these objects were not removed in one or two minutes, and immediately immersed in water. In this case the chloride of sulphur, decomposed by its contact with the water, ceases to act on the surface, while the portions which have entered farther in continue their sulphurizing action on the interior. ‘This is an ingen- ious means of regulating this kind of vulcanization by the cold way. A process, which seemsstill more preferable, as regards the healthi- ness and regularity of the operation, is due to the same inventor. It is effected by keeping the objects to be vulcanized immersed for two or three hours in close vessels, in a solution of 25° Baume, of polysul- phuret of potassium, at a temperature of 284° Fahr., and submitting to a washing in an alkaline solution, and then in pure water. We are thus enabled to combine caoutchouc with a useful proportion of sulphur, without allowing an excess of it to be interposed in its pores, thus avoiding the inconveniences of the unequal sulphurization of the organic substance. COMPOSITION FOR SILVERING GLASS. PREPARE a mixture of 30 grains ammonia, 60 grains nitrate of silver, 90 grains spirit of wine, and 90 grains of water. When the nitrate of silver is completely dissolved, filter the liquid and add a small quantity of sugar, for example, 15 grains of the grape sugar previously dissolved in a mixture of 14 ounces of water, and 13 ounces spirit of wine. For silvering a glass it is sufficient to leave this solution in contact with the glass during two or three days. — Civil Engineer and Archi- tect’s Journal. PREPARATION OF PURE METHYLIC ALCOHOL. Wouter has given a very simple and elegant method of preparing pure wood-spirit from the raw material of commerce, which is of interest both to the chemist and pharmaceutist. Raw wood-spirit is to be mixed with an equal weight of sulphuric acid, avoiding an elevation CHEMICAL SCIENCE. 235 of temperature. The mixture is to be allowed to stand a day, then distilled from two parts by weight of binoxalate of potash. A volatile fluid at first passes over, after which the oxalate of methyl condenses in the neck of the retort. The receiver is now to be changed and the distillation continued as long as the ether comes over. The neck of the retort is then to be gently warmed and the oxalate allowed to flow into the receiver when it is to be strongly pressed between folds of bibulous paper, and then freed from volatile products by long fusion. In this way it is obtained directly perfectly colorless. The liquid which passes over first contains also oxalate of methyl which is readily obtained by evaporation and crystallization. The pure oxalate of methyl prepared in this manner is now to be distilled with water ; pure wood-spirit passes over and oxalic acid remains in the retort. [ This method obviously presents great advantages over the tedious processes of Dumas and Kane.]— Ann. der Chemie und Pharmacie, Ixxxi. FORMATION OF SULPHURIC ACID FROM SULPHUROUS ACID AND OXYGEN. Wouter has published a few observations relating to the formation of sulphuric acid, which, although involving no new principle, promise to be of great importance in a manufacturing point of view. The action of spongy platinum at a high temperature upon a mixture of sulphurous acid and air or oxygen, has long been known. A patent was even granted to Peregrine Phillips for the manufacture of sul- phuric acid by this process, the anhydrous acid formed being condensed and united to water in an appropriate receiver. The method was however abandoned as a more extended experience showed that the platinum speedily lost its power of condensation. Wohler has now found that various metallic oxides possess in a high degree the property of causing the union of mixed gases. When the oxides of copper, iron, or chromium, are heated to a low fedness in a glass tube and a mixture of sulphurous acid and air or oxygen is caused to pass over them, thick white vapors of anhydrous sulphuric acid are formed. A _ mixture of the oxides of chromium and copper prepared by precipi- tation was found to be particularly efficient; the same quantity of oxide appeared capable of converting an unlimited quantity of the mixed gases into sulphuric acid, and the production of sulphuric acid was so easy and rapid as to lead to the idea of practical application on a large scale. Metallic copper in a state of powder produces sulphuric acid in a similar manner, but only when heated and when its surface has become converted into oxide. No hydrate of sulphuric acid is formed by passing the vapor of water over the oxide at the same time with the gaseous mixture. Platinum foil polished and cleaned acts upon the gaseous mixture like spongy platinum, but not at ordinary temperature. A mixture of the oxides of copper and iron prepared by precipitation and ignited, becomes and remains incandescent when 21 236 ANNUAL OF SCIENTIFIC DISCOVERY. warmed and held in a current of hydrogen gas.— Ann. der Chemie und Pharmacie, 1x xxi. | ON THE DECOLORIZING POWER OF CHARCOAL AND OTHER BODIES, Ir is generally said that charcoal is the only simple body which possesses the property of absorbing coloring matters dissolved in a liquid ; it results, moreover, from the labors of Bussy and Payen, that decoloration by charcoal is a purely physical phenomena, a phenomena of dyeing. Several compound bodies, (alumina, sulphuret of lead prepared by the humid way, and hydrate of lead) also possess the property of decoloring liquids ; but chemists for the most part, regard the action which the oxides exert on coloring matters in the prepar- ation of lakes as a chemical action, different from that of charcoal. However, Berzelius thought he might compare the decoloration by the oxides and the metallic salts with that produced by charcoal. In a communication submitted to the French Academy by M. Filhol, the author proves that charcoal is not the only simple body which possesses the property of decoloring liquids ; sulphur, arsenic, and iron, resulting from the reduction of hydrogen, have appreciable decoloring power. The number of compound bodies endowed with an appreciable decol- oring power is much greater than has been supposed, as this property seems to depend much more on the state of division of these bodies than on their chemical qualities. It was also shown thata certain body which easily appropriates one coloring matter, may have very little tendency to remove another; thus bone phosphate of lime (artifically obtained) with difficulty decolors a solution of sulphindigotate of soda, whilst it acts on tincture’ of litmus more energetically than animal black. The decoloration is in the great majority of cases, a purely physical phenomena; thus, the same coloring matter is absorbed by metalloids, metals, acids, bases, salts, and organic substances, besides it is easy, by employing suitable solvents, to procure the color unaltered from the body by which it had been absorbed. — Comptes Rendus, 1852. DEODORIZING PROPERTIES OF COFFEE. THE London Medical Gazette gives the result of numerous experi- ments with roasted coffee, proving that it is the most powerful means, not only of rendering animal and vegetable effluvia innocuous, but of actually destroying them. A room in which meat in an advanced degree of decomposition had been kept for some time, was instantly deprived of all smell, on an open coffee roaster, being carried through it, containing a pound of coffee newly roasted. In another room exposed to the effluvium occasioned by the clearing out of a cess pit, so that sulphuretted hydrogen and ammonia in great quantities could be chemically detected, the stench was completely removed within half a minute, on the employment of three ounces of fresh roasted coffee, whilst the other parts of the house were permanently cleared of the CHEMICAL SCIENCE. 237 same smell by being simply traversed with the coffee roaster, although the cleansing of the cess pit continued several hours after. The best mode of using the coffee as a disinfectant is to dry the raw bean, pound it in a mortar, and then roast the powder on a moderately heated iron plate until it assumes a dark brown tint, when it is fit for use. Then sprinkle it in sinks or cess pools, or lay it on a plate in the rooms which you wish to have purified. Coffee acid or coffee oil acts more readily in minute quantities. ADULTERATION OF BEER WITH STRYCHNINE. GRAHAM and HorrMan, at the instance of a prominent English brewer, Mr. Alsopp, and in consequence of reports, originating in Paris, that English ale and beer occasionally derived its bitterness from strychnine, have carefully tested various specimens of these bey- erages, but without discovering a trace of the poisonous alkaloid. Strychnine when present in no greater quantity than 1-1,000 of a grain may be detected by the following process. The suspected pow- der is to be moistened with a drop of undiluted sulphuric acid and a few fragments of bichromate of potash added. An intense beautiful violet color immediately appears at the points of contact which quickly spreads through the whole fluid, and after a few minutes again vanishes. The presence of small quantities of organic matter prevents this reaction ; in testing beer the authors adopted the following process. Half a gallon of beer to which half a grain of strychnine had been added was shaken with two ounces of animal charcoal, and the fluid allowed to stand over night. The next day the beer was found to be almost free from bitterness, the strychnine having been precipitated with the coal. The coal was thrown on a filter, washed, boiled with alcohol and the alcoholic filtrate distilled. The residue in the retort was shaken with a few drops of a solution of caustic potash and about an ounce of ether. The etherial solution evaporated on a watch glass gave a mass in which the presence of strychnine was easily detected by the test above given Ann. der Chemie und Pharmacie. ADTLTERATION OF ANCHOVIES. THE London Lancet gives the result of the investigation of the Analytical Sanitary Commission into the composition_of “Anchovies,” as vended in the metropolis. Having analyzed 28 samples, the follow- ing conclusion has been arrived at: That seven of the samples consisted entirely of Dutch fish. That two of the samples consisted of a mix- ture of Dutch fish and anchovies. That the brine in 23 of the samples was charged with either bole Armenian or Venetian red, the quantity varying considerably in amount; but in most cases the brine was saturated with these earthy powders to such an extent that they might be obtained and collected from the botton of the bottles almost by teaspoonfulls. The commissioners add : —‘ It is not to be inferred that these samples in which no Dutch fish were detected consisted of 238 ANNUAL OF. SCIENTIFIC DISCOVERY. the true anchovy, since we have ascertained that two other kinds of fish besides the Dutch are commonly imported and sold as ‘true anchovies,’ and ‘real Gorgonas’ —namely French and Sicilian fish.” A further investigation established the fact, that not one-third of the 28 samples consisted of Gorgona anchovies. ON THE ANALYSIS OF OPIUM, ESPECIALLY WITH REFERENCE TO THE PROPORTION OF MORPHIA CONTAINED IN IT. Tue following new process for the examination of opium is given by Dr. Riegel, of Carlsruhe, in the Jahrbuch de Pharmacie, Nov. : Half an ounce of opium to be examined is cut in small pieces and bruised in a mortar with alcohol at 71°; the fluid is then expressed through linen, and the refuse washed with from ten to twelve drachms of the same alcohol ; the alcoholic solution is then to be filtered into a glass containing one drachm of spirits of ammonia. In twelve hours’ time, all the morphia, with some narcotine and meconate of ammonia, will have become deposited. In order to effectually separate the mor- phia, the adhering meconate of ammonia must be removed by washing in water and then shaking the crystals in pure ether, or better still in chloroform, in which the narcotine is readily dissolved, while the mor- . phia remains entirely insoluble. After this treatment the morphia remains behind in large gritty crystals, slightly discolored. This process may be varied by employing boiling alcohol and powdered opium, and adding the solution still hot, to the solution of ammonia. According to good authorities, 15 grammes of opium should yield at least 1.25 grammes, or 8.33 per cent. Reich estimates 10, and others 12 percent. The author gives the percentage of morphia which is obtained by the various processes of different experiments, and states that the largest proportion (13.50 per cent.) is procured by the pro- cess above described, which he considers also to be the simplest and most certain for ascertaining the proportion of morphia. ; The following process is also recommended by Dr. Riegel for the detection of small quantities of opium. To the suspected substance some potash is to be added, and then shaken with ether. A strip of white blotting paper is to moistened with the solution several times repeated. When dry, the paper is to be moistened with muriatic acid, and exposed to the steam of hot water; if opium be present, the paper will be more or less colored red. METHOD FOR DETECTING THE ORGANIC ALKALOIDS. THE following paper, by Prof. Stass, of Brussels, is published in the Bulletin de ? Academie Royal de Medecine de Belgique. Whatever certain authors may have said on the subject, it is possi- ble to discover, in a suspected liquid, all the alkaloids, i whatever state they may be. I am quite convinced that every chemist, who has kept up his knowledge as to analysis, will not only succeed in detecting their presence, but even in determining the nature of that CHEMICAL SCIENCE. 239 which he has discovered, provided that the alkaloid in question is one of that class of bodies, the properties of which have been suitably studied. Thus he will be able to discover coniine, nicotine, aniline, picoline, petinine, morphine, codeine, narcotine, strychnine, brucine, veratrine, colchicine, delphine, emetine, solanine, aconitine, atrophine, and hyoscyamine. Ido not pretend to say, that the chemical study of all these alkaloids has been sufliciently well made to enable the experimenter who detects one of them to know it immediately, and affirm that it is such an alkaloid, and no other. Nevertheless, in those even which he cannot positively determine or specify, he may be able to say that it belongs to such a family of vegetables, the Sola- nacez, for example. In case of poisoning by such agents, even this will be of much importance. The method which I now propose for detecting the alkaloids in suspected matters, is nearly the same as that employed for extracting those bodies from the vegetables which con- tain them. The only difference consists in the manner of setting them free, and of presenting them to the action of solvents. We know that the alkaloids form acid salts, which are equally soluble in water and alcohol; we know, also, that a solution of these acid salts can be decomposed, so that the base set at liberty remains either momentarily or permanently in solution in the liquid. J have observed that all the solid and fixed alkaloids above enumerated, when maintained in a free state and in solution in a liquid, can be taken up by ether when this solvent is in sufficient quantity. Thus, to extract an alkaloid from a suspected substance, the only problem to resolve consists in sepa- rating, by the aid of simple means, the foreign matters, and then find- _ing a base which, in rendering the alkaloid free, retains it in solution, in order that the ether may extract it from the liquid. Successive treatment by water, and alcohol of different degrees of concentration, suffices for separating the foreign matters, and obtaining in a small bulk,-a solution in which the alkaloid can be found. The bicarbo- nates of potash or soda, or these alkalies in a caustic state, are convenient bases for setting the alkaloids at liberty, at the same time keeping them wholly in solution, especially if the alkaloids have been combined with an excess of tartaric or of oxalic acid. To separate foreign substances, animal or otherwise, from the sus- pected matters, recourse is commonly had to the tribasic acetate of lead, and precipitating the lead afterwards by a current of sulphu- retted hydrogen. As I have several times witnessed, this procedure has many and very serious inconveniences. In the first place, the tribasic acetate of lead, even when used in large excess, comes far short of precipitating all the foreign matters; secondly, the sulphu- retted hydrogen, which is used to precipitate the lead, remains in combination with certain organic matters, which undergo great changes by the action of the air, and of even a moderate heat; so that animal liquids, which have been precipitated by the tribasic ace- tate of lead, and from which the lead has been separated afterwards by hydrosulphuric acid, color rapidly on exposure to the air, and exhale at the same time a putrid odor, which adheres firmly to the 21* 240 ANNUAL OF SCIENTIFIC DISCOVERY. matters which we extract afterwards from these liquids. The use of a salt of lead presents another inconvenience, viz: the introduction of foreign metals into the suspected matters, so that that portion of the suspected substance is rendered unfit for testing for mineral sub- stances. The successive and combined use of water and alcohol at different states of concentration, permits us to search for mineral sub- stances, whatever be their naturc; so that in this way nothing is compromised, which is of immense advantage when the analyst does not know what poison he is to look for. It is hardly necessary to say, that in medico-legal researches for the alkaloids, we ought never to use animal charcoal for decolorizing the liquids, because we may lose all the alkaloid in the suspected matters. It is generally known that animal charcoal absorbs these substances at the same time that it fixes the coloring and odoriferous matters. The above observations do not proceed from speculative ideas only, but are the result of a pretty long series of experiments which I have several times employed for discovering these organic alkaloids. ‘To put in practice the principles which I have thus explained, the follow- ing is the method in which I propose to set about such an analysis : — I suppose that we wish to look for an alkaloid in the contents of the stomach or intestines; we commence by adding to these matters twice their weight of pure and very strong alcohol;* we add after- wards, according to the quantity and nature of the suspected matter, from 10 to 30 grs. of tartaric or oxalic acid — in preference, tartaric ; we introduce the mixture into a flask, and heat it to 160° or 170° Fahr. After it has completely cooled, it is to be filtered, the insoluble residue washed with strong alcohol, and the filtered liquid evaporated in vacuo. If the operator has not an air-pump, the liquid is to be exposed to a strong current of air at a temperature of not more than 90° Fahr. If, after the volatilization of the alcohol, the residue con- tains fatty or other insoluble matters, the liquid is to be filtered a second time, and then the filtrate and washings of the filter evapo- rated in the air-pump till nearly dry. If we have no air-pump, it is to be placed under a bell jar over a vessel containing concentrated sulphuric acid. We are then to treat the residue with cold, anhy- drous alcohol, taking care to exhaust the substance thoroughly; we evaporate the alcohol in the open air at the ordinary temperature, or still better, in vacuo ; we now dissolve the acid residue in the smallest possible quantity of water, and introduce the solution into a small test tube, and add, little by little, pure powdered bicarbonate of soda or potash, till a fresh quantity produces no further effervescence of carbonic acid. We then agitate the whole with four or five times its bulk of pure ether, and leave it to settle. When the ether swimming * When we wish to look for an alkaloid in the tissue of an organ, as the liver, heart, or lungs, we must first divide the organ into very small fragments, moisten the mass with pure strong alcohol, then express strongly, and_ by further treatment with alcohol exhaust the tissue of every thing soluble. The liquid so obtained is to be treated in the same way as a mixture of suspected matter and alcohol CHEMICAL SCIENCE. 241 on the top is perfectly clear, decant some of it into a capsule, and leave it in a very dry place to spontaneous evaporation. Now, two orders of things may present themselves — either the alkaloid contained in the suspected matter is liquid and volatile, or solid and fixed. I shall now consider these two hypotheses. Examination for a Liquid and Volatile Alkaloid.— We suppose there exists a liquid and volatile alkaloid.. In such a case, by the evaporation of the ether, there remain in the inside of the capsule some small liquid striz:, which fall to the bottom of the vessel. In this case, under the influence of the heat of the hand, the contents of the capsule exhale an odor more or less disagreeable, which becomes, according to the nature of the alkaloid, more or less pungent, suffo- cating, irritant ; it presents, in short, a smell like that of a volatile alkali, masked by an animal odor. If we discover any traces of the presence of a volatile alkaloid, we add then to the contents of the vessel, from which we have decanted, a small quantity of ether, 1 or 2 fiuid drachms, of a strong solution of caustic potash or soda, and agitate the mixture. After a suflicient time, we draw off the ether into a test-tube, exhaust the mixture by two or three treatments with ether, and unite all the etherial fluids. We pour afterwards into this ether, holding the alkaloid in solution, 1 or 2 drachms of water, acidu- lated with a fifth part of its weight of pure sulphuric acid, agitate it for some time, leave it to settle, pour off the ether swimming on the top, and wash the acid liquid at the bottom with a new quantity of ether. As the sulphates of ammonia, of nicotine, aniline, quinoleine, picoline, and petinine are entirely insoluble in ether, the water acid- ulated with sulphuric acid contains the alkaloid in a small bulk, and in the state of a pure sulphate; but as the sulphate of coniine is soluble in ether, the ether may contain a small quantity of this alka- loid, but the greater part remains in the acidulated watery solution. The ether, on the other hand, retains all the animal matters which it has taken from the alkaline solutions. If it, on spontaneous evapora- tion, leaves a small quantity of a feebly colored yellowish residue, of a repulsive animal odor, mixed with a certain quantity of sulphate of coniine, this alkaloid exists in the suspected matter under analysis. To extract the alkaloid from the solution of the acid sulphate, we add to the latter an aqueous and concentrated solution of potash or caustic soda; we agitate and exhaust the mixture with pure ether; the ether dissolves ammonia, and the alkaloid is now free. We expose the etherial solution at the lowest possible temperature to spontaneous evaporation ; almost all the ammonia volatilizes with the ether, whilst the alkaloid remains as residue. To eliminate the last traces of ammonia, we place, for a few minutes, the vessel containing the alkaloid in a vacuum over sulphuric acid, and obtain the organic alkaloid, with the chemical and physical characters which belong to it, and which it is now the chemist’s duty to determine positively. I applied the process which I have described to the detection of nico- tine in the blood from the heart of a dog poisoned by 2 cubic centims. (0.78 eubic inch) of nicotine introduced into the xsophagus; and 242 ANNUAL OF SCIENTIFIC DISCOVERY. I was able, in a most positive manner, to determine the presence of nicotine in the blood. I was able to determine its physical characters, its odor, taste, and alkalinity. I succeeded in obtaining the chloro- platinate of the base perfectly crystallized in quadrilateral rhomboidal prisms of a rather dark yellow color, and to ascertain their insolubility in alcohol and ether. I have applied the same process to the detection of coniine in a very old tincture of hemlock, and I was equally successful in extract- ing from the liquid colorless coniine, presenting all the physical and chemical properties of this alkaloid. I was also able to prove that the ether which holds coniine in solution, carries off a notable portion of this alkaloid, when the solvent is exposed to spontaneous evaporation. Examination for a Solid and Fixed Alkaloid. — Let us now suppose that the alkaloid is solid and fixed; in that case, according to the nature of the alkaloid, it may happen that the evaporation of the ether resulting from the treatment of the acid matter, to which we have added bicarbonate of soda, may leave or not a residue containing an alkaloid. If it does, we add a solution of caustic potash or soda to the liquid, and agitate it briskly with ether. This dissolves the vege- table alkaloid, now free, and remaining in the solution of potash or soda. In either case, we exhaust the matter with ether. Whatever be the agent which has set the alkaloid free, whether it be the bicar- bonate of soda or potash, or caustic soda or potash, it remains, by the evaporation of the ether, on the side of the capsule as a solid body, but more commonly as a colorless milky liquid, holding solid matters in suspension. The odor of the substance is animal, disagreeable, but not pungent. It turns litmus paper permanently blue. When we thus discover a solid alkaloid, the first thing to do is to try and obtain it in a crystalline state, so as to be able to determine its form. Put some drops of alcohol in the capsule with the alkaloid, and leave the solution to spontaneous evaporation. It is, however, very rare that the alkaloid obtained by the above process, is pure enough to crystallize. Almost always it is contaminated with foreign matters. To isolate these substances, some drops of water, feebly acidulated with sulphuric acid, are poured into the capsule, and then moved over its surface, so as to bring it in contact with the matter in the capsule. Generally we observe that the acid water does not moisten the sides of the vessel. The matter which is contained in it separates into two parts; one formed of greasy matter which remains adherent to the sides; the other alkaline, which dissolves and forms an acid sulphate. We cautiously decant the acid liquid, which ought to be limpid and colorless, if the process has been well executed; the capsule is well washed, with some drops of acidulated water, added to the first liquid, and the whole is evaporated to three-fourths in vacuo, or under a bell jar over sulphuric acid. We put into the residue a very concentrated solution of pure carbonate of potash, and treat the whole liquid with absolute alcohol. This dissolves the alkaloid, while it leaves untouched the sulphate of potash, and excess of carbonate of potash. The evaporation of the alcoholic solution CHEMICAL SCIENCE. ee) gives us the alkaloid in crystals. It is now the chemist’s business to determine its properties, to be able to prove its individuality. I have applied the principles which I have just expounded to the detection of morphine, iodine, strychnine, brucine, veratrine, emetine, colchi- cine, aconitine, atrophine, hyoscyamine; and I have succeeded in isolating, without the least difficulty, these different alkaloids, previ- ously mixed with foreign matters. I have thus been able to extract by this process, morphine from opium, strychnine and brucine from nux vomica, veratrine from extract of veratrum, emetine from extract of ipecacuanha, colchicine from tincture of colchicum, and the like. Thus it is in all confidence that I submit this process to the considera- tion of chemists who undertake medico-legal researches. ON THE DETERMINATION OF PHOSPHORIC ACID BY MOLYBDATE OF AMMONIA. SILLIMAN’s Journ: 1 for May contains the followimg article by Mr. W. J. Craw, of New Haven, on the determination of phosphoric acid by molybdate of ammonia: The determination of phosphoric acid has always been one of the most important and most difficult problems of analytical chemistry. The bases with which it is most frequently united, are iron, alumina, the alkalies and alkaline earths. Several of these combinations are decomposed with very great difficulty, the phosphate of alumina in particular, resisting nearly every effort to reduce it to its component parts. Although good methods have been proposed for the analysis of many of the simple phosphates, that of phosphate of lime for instance, yet it usually happens that several of these occurs together ; and until very recently no process has been devised which could effect the separation of phosphoric acid from all the bases previously men- tioned, when incompany. A great amount of labor has been spent by chemists, within the last few years, in the effort to overcome this difficulty. Numerous ways have been tried with greater or less success, but most of these contain inherent difficulties, which in many cases prevent their applications. Even Rose’s process by carbonate of baryta, though a monument of profound knowledge and admirable research, is yet too complicated to yield good results, except in the hands of those who have practised it so often as to be perfectly famil- iar with all the necessary precautions. The great desideratum of a simple and accurate method for the determination of phosphoric acid, with whatever substances it may be combined, has been supplied by Sonnenschein. He states that the yellow precipitate produced by molybdate of ammonia in the solution of a phosphate, contains phos- phoric acid as an essential constituent, and not, as asserted by Svanberg, and Struve, an accidental admixture. From several analyses of this compound he finds it to contain about three per cent. of phosphoric acid. A number of trials were also made to find whether by this means phosphoric acid could be separated and deter- mined quantitatively which were completely successfull. For this pur- 244 ANNUAL OF SCIENTIFIC DISCOVERY. pose a large quantity of the molybdate solution is prepared as follows : one part of molybdic acid is dissolved in eight parts of ammonia, and twenty of nitric acid. The phosphate is dissolved in nitric acid, and there is added to it, a quantity of molybdic acid equal to about thirty times that of the phosphoric acid. The solution with the precipitate is digested for some hours with the aid of a very gentle heat, filtered, and washed with the same solution which was used for the precipita- tion. The whole is then dissolved in ammonia, and the phosphoric acid thrown down by a magnesian salt. The presence of molybdic acid is not injurious, as the double molybdate of ammonia and mag- nesia is easily soluble. Sonnenschien’s experiments on the separation of ee acid from alumina and other bases all gave very good results. With a view of confirming this discovery, and also of ascertaining with more precision the cause of the peculiar behavior exhibited by this substance towards re-agents, numerous trials have been made with it by Mr. Craw. Solutions of the caustic alkalies, and the alkaline carbonates and phosphates, dissolve the yellow compound even in the cold. So do also chloride of ammonium, and oxalate of ammonia. The mineral acids also act upon it to some extent. Cold water dissolves it with great difficulty, though it is soluble in hot water. It appears to be decomposed to a small extent by the combined influence of air and moisture, as it turns blue when dried in the atmosphere after washing with water. Its behavior towards solvents is changed by the presence of molybdate of ammonia, so that it becomes nearly insoluble in acids even on boiling. The act of solution is probably in all cases attended with decomposition and removal of molybdie acid which is prevented by the presence of molybdate of ammonia. Some quanti- tative experiments were also made on the separation of phosphoric acid from the bases, and the results obtained confirm those of Sonnen- schein, and show that the method as regards accuracy, is all that can be desired, while in point of simplicity, it is superior to any of the old processes. It will prove of especial advantage in cases where, as in the analysis of soils, a small quantity of phosphoric acid is associated with a variety of other substances existing in much larger proportion. It may be important to remark, that when effecting the precipitation by means of molybdate of ammonia, this, as well as nitric acid, should be in decided excess. To ascertain when this is the case, before fil- tering off the solution, a drop of it may be transferred to a solution of sulphuretted hydrogen, when a brown precipitate of sulphuret of molybdenum will appear. After separating the yellow precipitate from the solution, the latter should be always allowed to stand for some time in a warm place, to see whether any additional precipitate is formed. ON A SPECIAL ACID OF THE LUNGS. M. Dumas recently presented a paper to the academy, giving an account of his and M. Verdiel’s researches on a special acid secreted CHEMICAL SCIENCE. 245 by the pulmonary parenchyna in most animals, and which may be found free, but is usually combined with a salt of soda. Obtained in the crystalline form, it is a brilliant body, strongly refracting light. It does not lose its water of crystallization at a temperatue of 100° Centigrade ; but when heated still more, it decrepitates, melts and is decomposed, giving rise to empyreumatic products. Much coal re- mains, which disappears without leaving any traces of ash. It is soluble in water and boiling alcohol, but not in cold alcohol or ether. Its ultimate analysis exhibits definite proportions of carbon, hydro- gen, oxygen, nitrogen and sulphur. It forms crystallized salts with bases, and expels carbonate acid from the carbonates. The existence of this substance is of high physiological interest; for the acid thus secreted by the parenchyma comes in contact with the carbonate of soda of the blood, transported by the capillaries, and decomposes it, uniting with the soda and setting free the carbonic acid which is -exhaled. The presence of a portion of this acid in the free state, in the parenchyma, indicates that it is really there that it is formed, and not in the blood, which is an alkaline fluid. By uniting with the soda of the blood, the acid does not change the reaction of that fluid, since it merely takes the place of the carbonic acid which is expelled dur- ing expiration. — Journ. de Chemie Medicale. ; ON CHROMIC ACID AS AN ESCHAROTIC. Curomic acid has been on the recommendation of Dr. Heller tried in many cases as an escharotic, and the results thus far obtained justify a further trial of it in cases in which a deeply penetrating, gradual caustic, and ene constant in its effect would be indicated. When employed in substance, its action is exceedingly slow and gradual, eccupying many hours; nevertheless in intensity it exceeds that of the caustic alkalies. In extremely concentrated solution, its action is less penetrating and less gradual, but at the same time, it is more con- tinuous than that of all other known caustics; on the other hand, the more dilute the solution, the more transient and superficial is the effect. The facility with which its action can thus be graduated ren- ders it in all cases a suitable escharotic. The method of application is as follows: the surrounding parts having been protected by folds of lint, adhesive plaster, &c., the chromic acid is spread with a spatula on the part to be cauterized, so as to form a layer scarcely a line in thick- ness, which is covered with lint, kept in its place by adhesive plaster. The concentrated solution may be applied by means of a glass rod, or hair pencil, and the part after a few moments’ exposure covered with lint. If chromic acid be applied to sound parts, a moderate sensation of burning commences in ten or fifteen minutes after the application, increasing for three or four hours, and then diminishing for about an equal space of time. Its application to ulcerated parts excites similar sensations instantaneously. Undissolved chromic acid causes severer and more permanent pains; these are also more violent when the cutis vera itself, and not morbid growths is cauterised. The pain does 246 ANNUAL OF SCIENTIFIC DISCOVERY. not disturb the patient’s sleep, and is incomparably less than that caused by other caustics, such as sulphuric or nitric acids, nitrate of silver, corrosive sublimate, caustic potassa, &c. According to Dr. Heller’s experiments, all organic compounds are soluble in the easily deoxidable chromic acid, their ultimate elements being raised to a higher degree of oxidation, and partly uniting with the acid. An elevated temperature accelerates this process. Smaller animals, mice, birds, &c., were so completely dissolved by chromic acid in fifteen or twenty minutes, that no trace of their bones, skin, hair, claws or teeth could be discovered. WHY BREAD BECOMES STALE. “Av a late meeting of the French Academy a discussion took place respecting the grave yet apparently simple question why bread becomes stale. M. Boussingault laid down that staleness is not, as is generally supposed, caused by the proportion of water diminishing ; but arises from a molecular state which manifests itself during the cooling, becomes afterwards developed, and persists as long as the temperature does not exceed a certain limit. M. Thenard said, that it is cause by bread being a hydrate which heat softens, and to which a lower temperature gives more consistency. PRESERVATION OF ANIMAL SUBSTANCES. Tue following is an abstract of a communication to the French Academy, by M. Blandet : — The hyposulphite of soda and the chloride of zinc are both employed for the preservation of dead bodies by injection. I placed blood in a concentrated solution of each of these salts, and in about a fortnight, after exposure to the air, the blood appeared bad in the hyposulphite, though still liquid and black ; while the chloride of zinc gave a precipi- tate, but without bad odor. I experimented with another’ salt, a chloride like the salt of zinc, and alkaline the same as the salt of soda —the chloride of barium. This salt maintains the blood liquid the same as the salt of soda, and preserves it without odor the same as the salt of zinc. The author thinks that by employing it for the injection of the human subject, we may preserve the aspect of the living body, the blood being rendered imputrescable by the chloride of barium — Comptes Rendus. A NEW STYPTIC. A PHARMACIEN, at Rome, Signor Pagliare, has recently succeeded in discovering a liquid possessing so extraordinary a power of coagulat- ing blood, that if to a large basin containing this fluid one drop of the styptic be added, complete solidification ensues, so that the basin may be inverted without causing any blood to be lost. The practical advantages of this styptic are consequently very great, inasmuch as, CHEMICAL SCIENCE. QAT by its timely application, the bleeding from large and dangerous wounds may be immediately staunched. In addition to the other valuable qualities of this liquid, it is totally devoid of poisonous agency, and easily prepared as follows:— Take 8 ounces of gum benzoin, 1 pound of alum, and 10 pints of water. Boil all together for the space of eight hours in an earthenware glazed vessel, frequently stirring the mass, and adding water sufficient to make up the original quantity of that lost by ebullition, taking care, however, to add the water so gradually that boiling may not be suspended. ‘The liquid portion of the com- pound is now to be strained off, and preserved in well-corked bottles. It is limpid, like champagne as to color, possessing a slightly styptic taste, and an agreeable odor. ALKALIES IN PLANTS. AT a recent meeting of the Botanical Society, London, Dr. Daubeny detailed some experiments undertaken by him at the Oxford Botanic Garden, with the view of determining whether the usual _ quantity of potash and soda existing in barley might be made to vary by causing the plant to grow in soil impregnated with more than the ordinary quantity of one or the other of these alkalies. He found that when the barley had grown in a soil which had been dressed with a strong solution, either of carbonate of soda or of chloride of sodium, the ashes of the plant contained about eight per cent. more soda than was present when the plant had grown in a soil impregnated with carbon- ate of potash, or left unimpregnated. ‘This difference may admit of explanation by supposing one alkali capable of replacing the other within the organism of the plant; but the author thinks it more probable that it arose from the sap circulating through the plant at the time when it was cut, containing in the one case more soda than it did in the other. The saline contents of the fluid of the sap would of course be confounded with those which had been actually assimilated by the plant, and hence, from the variation in its composition, must tend to modify the amount of the alkalies obtained from the ashes of the plant in each instance, according to the nature of the material with which the soil had been impregnated. ON THE EFFICACY OF BURNT CLAY. Dr. VOELCKER publishes a communication in the Chemical Gazette, for April, on the causes of the agricultural efficacy of burnt clay, in which he shows conclusively, that the change effected, and benefit resulting, is entirely of a chemical nature. Prof. Johnson, the well known Agricultural Chemist, had previously expressed the opinion that the mechanical effects of the burning upon clay, were insufficient to explain its efficacy, and first pointed out the true solution of the phenomena in the chemical changes which the soil undergoes. Pure clay, silicate of alumina, is rarely found; such a soil could 22 248 _ ANNUAL OF SCIENTIFIC DISCOVERY. never be improved by burning. The ordinary clay soils, however, contain besides this chief ingredient, a considerable proportion of sand, undecomposed fragments of felspar, mica, granite, and other minerals, with more or less sand, carbonate of lime, magnesia, free or uncombined alumina, oxide of iron, silicate of potash, traces of phos- phorus, and sulphuric acid, and chlorine. Now of these substances, the silicate of alumina, pure clay, does not of itself contribute at all to the direct nurture of plants, as it is not found in the ashes of culti- vated plants. We must look, therefore, for the direct fertilizers of this soil, amongst the accessory or foreign ingredients of agricultural clays. Of these, the lime, magnesia, sulphuric acid, silica, and chlo- rine, which are essential to the growth of plants, are found im most soils, or 1f deficient, can be supplied at a cheap rate. The chief value of an agricultural clay, depends, therefore, on the proportion ef phos- phoric acid, potash, and soda it contains. Potash is a most essential element, and its chief source in ordinary soils is the clay. Clay is in many cases, derived from felspar, a double silicate of alumina and potash; and frequently contains some undecomposed fragments of felspar and other minerals. Plants can only avail themselves of the soluble potash, and not that which occurs in the form of felspar, which must first be decomposed by long exposure to air and water; but, as the soluble potash in the clay soil, sooner or later, will be exhausted by the removal of the crops grown upon it, the soil becomes gradually more and more sterile. Although by long exposure felspar may be decomposed, yet it is now demonstrated that moderate calcination much accelerates this action. In burning clay properly, a large amount of potash is liberated by the action of the carbonate of lime present, upon the double silicate of potash and alumina. This chemical reac- tion, which occurs at a high temperature, results in the formation of silicate of lime, and carbonate of potash. Those clays, then, which are improved by burning, must be the ones that contain the foreign ingredients named, and undecomposed felspar. ‘The pure pipe and porcelain clays, would not be improved at all, by the process of soil burning. We can now understand, why burnt clays, especially improve the root crops, such as turnips, carrots, swedes, mangolds, potatoes, &c., which require much potash as nutriment, the ashes of these plants, containing nearly half their weight of this alkali. ; ON THE ABSORPTION OF THE SOLUBLE HUMATES AND ULMATES BY PLANTS. ° M. SovusErraNn demonstrated some time since the important fact, so long denied by Liebig and his supporters, that alkaline ulmates and humates are absorbed by vegetation. The experiments of Soubeiran have been recently verified in the fullest extent by M. Malguti. A plant of Lampsana, whose roots were immersed in a solution of ammonia, continued to vegetate and prosper. The solution, which was changed every day, was partially discolored. Oats passed very CHEMICAL SCIENCE. 249 well through all the stages of vegetation in a soil deprived of organic matters, and containing a little sulphate and phosphate of lime, and which was watered from time to time with ulmate of ammonia. Those who do not believe in the absorption of humus will accept with diffi- culty results obtamed with a plant (Lampsana) which was found in an abnormal state. They will add that there is nothing to prove that oats accomplish their vegetation under the influence of ulmate of ammonia, since in the soil it must find phosphate and sulphate of that base. Indeed, if we put sulphate of lime, or powdered calcined bones (or more properly artificial tribasic phosphate of lime,) in contact with ulmate of ammonia, ulmate of lime is formed, and at the same time, sulphate and phosphate of ammonia; and again, when we put sulphate and phosphate of ammonia in contact with ulmate of lime, a double decomposition ensues. In all cases there is a division, and four salts are formed. An experiment detailed by Maleuti was as follows: I half filled two large funnels with gravel, and the other half with powdered brick, - containing one per cent. of calcined bones, and as much chalk. I sowed in these two artificial soils, moistened with distilled water, the same quantity of cress seed. During germination I prepared by means of turf, perfectly neutral ulmate of ammonia, which I divided inte two equal lots, each about two quarts. One of these was set aside, and the other was kept for watering the two soils. The seeds having sprung up four days after they were sown, I began to water them every day, ene with 100 cubic centimetres of distilled water, and the other with the like quantity of ulmate of ammonia. After five waterings, the difference between the two vegetations was very evi- dent. That which had been watered with the ulmate was of a deep green; the other which had been treated with water was of a light green. After eighteen waterings, that is to say after the experiment had lasted twenty-two days, the most luxuriant plant threatening to fall, i cut it down. ‘The twocrops dried in the air-and under the same circumstances weighed, that watered with water, 12,550 grs.; that watered with the ulmate of ammonia, 15,150 grs. The soil impreg- nated with the ulmate was then washed until the water passed out colorless and limpid; dilute hydrochloric acid was then added and the washing continued until the water became neutral. The treatment with acid was succeeded by treatment with ammoniacal water, and the two treatments were alternated, until it was quite certain that the soil did not centain a trace of ulmic acid. All the waters colored by ulmate of ammonia were combined with the rest of the lot employed and the whole brought to a state of neutrality, and to the bulk of two quarts. Two lots of liquid were thus produced; the first containing a quart, one-half of the ulmate of ammonia originally produced, and kept for comparison ; the second, a liquid containing all the ulmic acid remaining in the soil; over and above what might have been extracted by the plant. The ulmic acid in both was then precipitated in the form of ulmate of lime, and separately washed, dried and weighed under like circumstances. It was found that the ulmate of ammonia 250 ANNUAL OF SCIENTIFIC DISCOVERY. used for watering the cress had lost 2,367 grammes of ulmic acid, as it was given by the ulmate of lime dried in vacuo. It might be sup- posed that the ulmic acid might have remained in the soil, under an unknown form, which might escape the action of re-agents; but this transformation could not be the result of the contact of the ulmic acid either with the earthy matter, or with the external parts of the roots. Now, this is a question of proving that this acid 1s absorbed, and not of saying what becomes of it after the absorption. This experiment and those of M. Soubeiran, seem to me to prove the absorption of the soluble ulmates during vegetation, and at the same time their utility. — Comptes Rendus, 1852. RAIN, A SOURCE OF THE NITROGEN IN VEGETATION. M. Barrat, from some analyses of rain-water collected at two distinct spots in the grounds of the Observatory at Paris, during the last five and six months of the past year, has shown us that the rain- water is there charged with nitric acid, ammonia, chlorine, lime and magnesia, to an extent scarcely to be credited, were it not the actual result of experiment. Taking the average of these analyses, and reducing the French weights to our own standard of 7,000 grains to the pound, it will be seen, in these six months, the rain which fell on a space of ground at the Observatory at Paris, equal in area to an English acre, contained, as nearly as possible, 7.75 pounds of ammonia ; 36.50 pounds of nitric acid ; 5.56 pounds of chlorine ; 12.60 pounds of lime ; 4.81 pounds of magnesia. From July to December is usually the drier half of the year, as well as that in which the less fuel is consumed, so that we may safely double these quantities, in estimating the annual supply per acre of nitrogene- ous compounds, gradually distributed over the country by the rain. For the sake of illustration, we have calculated the amount of the solid constituents of the rain falling on an area equal in extent to Great Britain, and balancing the various causes likely to lessen or to increase the quantity of these matters, which would so fall on this island, we may venture to set one against the other, and apply the above statement to our own country, as the basis of an estimate, which singularly manifests the “power of littles,’ as well as the grand scale on which even the minutest of natural phenomena proceed. Thus, on the Parisian data, the weights of these fertilizing materials annually supplied to the soil of this island by the rain, amount to about 400,000 tons of ammonia; 1,850,000 tons of nitric acid ; 279,- 000 tons of chlorine ; 640,000 tons of lime; 244,000 tons of magnesia. Making every allowance for errors of experiment, which, however, would rather increase than diminish these quantities, excepting, it may be, the amounts of the two last on the list, these researches of M. Barrel prove to us that, the amount of fertilizing matter conveyed to the soil by the rain, must exercise a constant and most important influence on the vegetation of a country. These facts also tend to throw still further doubt upon the peculiar efficiency of the salts of ’ CHEMICAL SCIENCE. 251 ammonia, and of the acid of the nitrates as manures; for we find in rain-water a constant supply of these nitrogeneous matters, not applied once, or at most twice, in the year, as is the case with the various artificial manures, such as the nitrates of potash and of soda, Peruvian, and those guanos which contain a large proportion of soluble ammo- niacal salts, and the various ammoniacal composts, made and sold in this country, the utility of which must chiefly depend on the concurrence of several favorable conditions of the plants, the soil and the weather ; for we find that the nitrogen required for the growth of the plant is supplied in the fittest state for assimilation (viz., that of great dilution,) and at all stages of its growth, by every shower that falls. The later opinions entertained by Liebig, of the superior value of the alkaline and earthy constituents of manures, 7. ¢., the potash, soda, lime, magnesia, and the phosphates and sulphates of these bases, to that of their nitrogeneous compounds, derive much weight from these experi- ments of M. Barral, which show that a vast amount of nitrogeneous fertilizing matter is distributed by the rain but none of the fixed alkalies, or of the salts of phosphoric and other acids, equally important to the due growth of vegetables, and which, unless naturally existing in sufficient amount in the soil, must be supplied by the application of manure, or the plant will either dwindle, or yield an imperfect produce, owing to an insufficient supply to one portion of its requsite constit- uents, however much it may be stimulated by an abundant applica- tion of ammoniacal fertilizers. The prevailing use of these manures, which are so highly charged with the salts of ammonia, readily account for the increasing “ steeliness” which is observable in English wheat, arising in great measure, as remarked by Liebig, froma superfluous and unnecessary supply of the ammoniacal stimulants, and a deficiency in the more important constituents of the cereals, viz—the earthy phos- phates and alkaline salts, which are not brought to the growing corn in the rain, like the nitrogeneous constituents. — London Critic. ON THE SEPARATION OF BUTTER FROM CREAM BY CATALYSIS. At the American Association, Albany, President Hitchcock read the following paper, on the separation of butter from cream by catalysis : — It is well known that the separation of butter from cream, during the winter months, by the ordinary process of churning, is often very difficult, from some chemical changes in the proximate principles. From my own small kitchen dairy, the complaint on this subject had so often reached me, that I was led a few years since to inquire whether there were not some remedy. My thoughts were turned to that principle in chemistry, to which Berzelius gave the name of catalysis. In observing the process of churning with the old-fashioned cylindrical churn, I had noticed that along the handle, when the cream had been subject to a more powerful agitation, butter would show itself much earlier than in the body of the churn. Hence I inferred that by acting on asmall quantity of the cream, the separation 22* 252 ANNUAL OF SCIENTIFIC DISCOVERY. might be easily effected in that portion: and it seemed not improbable that by seizing the exact moment when the separation was taking place, and adding more cream, the process might be communicated to that also in a catalytic manner; and if so, perhaps any quantity might in like manner be made to yield its butter. I made the experiment, and was successful. I put a small quantity of cream in the churn at first, and, by a few moments strong agitation, brought it to that state, familiar to a practised eye, when the butter is separating. An assistant stood with the principal mass of the cream, ready to pour it gradually into that where the butter was in a nascent state, which I continued to agitate with even increased briskness as more and more cream was added. The effect was magical; for ina few minutes, I several times had the pleasure of seeing several quarts of cream give up its butter. I found, however, that if the fresh cream were poured in too fast, it would stop the process; and that it would not answer to let the agitation cease for an instant. I have delayed for two or three years to state these facts publicly, because I had hoped to make additional experiments on the subject ; but more important matters have prevented. I cannot, therefore, say of how much practical value my statements may be. I tried experi- ments enough to convince me, that although the requisite manipula- tions would require some skill, it would not be greater than many other processes common upon farms. The common churn, however, is not adapted to the experiment. I think one might be invented that would meet the case; but I must leave the whole matter to any others who may feel interest enough in it to carry forward what I have only suggested. It was suggested by those who took charge of the butter thus eliminated, that it seemed more difficult to separate and the whey completely, than when obtained by the ordinary process. ‘To this point, therefore, the attention of the experimenter should be turned. FORMATION OF ARTIFICIAL CELLULAR TISSUE. NorwitHsTANDING chemistry has made us acquainted with the composition of organic bodies, and the microscope has pointed out their structure, we have yet much to learn with regard to the particu- Jar operations by which definite forms are assumed by the elementary tissues. Many considerations concur to establish the probability of the proposition, that the fluid state is necessarily the first in which the elements of a tissue must exist previously to their undergoing a morphic determination, precipitation, histomorphosis, or whatever analogous term may be assumed to denominate the simplest change which may be supposed to occur in the passage of a perfectly amor- phous fluid into a tissue of definite shape. We owe to Ascherson a -knowledge of the interesting fact, that the contact of two homogeneous fluids, oil and albumen, results invariably in the immediate production of elementary forms. Still more recently, M. Melsens, by a series of observations and -experiments, has established the possibility of one of CHEMICAL SCIENCE. 258 these fluids undergoing distinct and very remarkable histomorphosis. In regard to this interesting phenomena, M. Melsens says : — “ We know that many feeble acids do not precipitate albumen from its solution ; my experiments have reference especially to the trihydrated phosphoric and acetic acids; this ceases to be the case when albumen is present with those salts which have no apparent chemical action on it; the reactions change for acetic acid as well as the phosphoric, with their equivalents of base, and some acid phosphates as well, precipitate it more or less completely. The following is the process by which I prepare the salified solution of albumen :— The white of an egg is mixed with its volume of water and filtered; this constitutes the normal solution of albumen, with a specific gravity of 1,020. The filtered liquor is saturated with salts, which are added in excess, after which the fluid is filtered again, to separate the excess of salts; the fluid resulting from this second filtration, may be denominated the normal saturated albumen. The normal albumen saturated with chloride of sodium has a specific gravity of about 1,200.” My experiments have been made with almost all the salts which are without an apparent action on albumen, as well as with those which begin to precipitate it, but whose precipitations are soluble either in an excess of albumen or of the salt. I will not pronounce on the nature of the precipitates obtained ; but it will appear evident that we must in the generality of cases admit, that the albumen is precipitated in consequence of a particular physical disposition of the liquid; that if at times the precipitation does not occur immediately, in dilute liquor for example, agitation may cause a troubled condition of the fluid, as occurs in precipitation, crystallization, solidification of water, of sulphate of soda, &c.. Tribasic phosphoric acid precipitates normal albumen saturated with salts; certain salts, among which are borax, phosphate of soda, acetates of soda, and potassa, form an exception to this rule ; however, if the fluid be agitated with a glass rod, a troubled condition is slowly produced by the mechanical action. The solutions of albumen with other salts are all precipitated by phosphoric acid ; these precipitates are soluble in an excess of the acid. ‘The presence of the salts, therefore, permits us to make with albumen and the tri- hydrated phosphoric acid an experiment which requires with normal albumen, the monohydrated phosphoric acid which precipitates it, and the trihydrated, which dissolves the precipitate formed. “Tf,” says M. Melsens, “after the preceding experiments I am induced to believe that the particular physical constitution of the liquids plays some part in the precipitation of albumen, those which ' follow cannot leave the least doubt as to the action of agitation. Some very dilute liquids remain limpid until beaten with a glass rod, when they become troubled, and immediately parcels of fibres may be seen to form under the influence of agitation; under the microscope these appear as very distinctly organized forms, which by juxta- position and felting together constitute actual membranes. We have thus a phenomena conformable to the production of mineral precipitates by the influence of agitation. In another experiment 254 ANNUAL OF SCIENTIFIC DISCOVERY. a current of air was passed through a solution of normal salified albumen, sufficiently dilute not to allow of the froth passing out of the vessel. This froth was seen- to be transformed into a solid body insoluble in ammonia, potassa, water, or dilute acids. To obviate two objections which might be started to this experiment, air saturated with the vapor of water, and hydrogen purified by caustic potassa and saturated with vapor, were successively employed. Lastly, to avoid all sources of error, a solution of albumen diluted with water was agitated in vacuo by converting the vessel into a sort of water hammer, after expelling the air by heat and an air- pump, the orifice being subsequently hermetically sealed. The solution, perfectly limpid at first, became troubled after a few agita- tions, and a membrane was rapidly formed.” The solid bodies thus formed from a limpid solution of albumen by the simple effect of agitation, have been subjected to microsco- pic examination of M. Gluge, from whose report we make the following extracts:—‘“The albumen of the white of an egg, soli- dified by mechanical actions resembles false membranes, and even serous. It is presented to our view under the form of membranes covered with granulations from one-half to one millimetre, in diame- ter, white semi-transparent, about one-fourth or one-half millimetre thick, and sufficiently elastic. With a magnifying power of three hundred we can distinguish an amorphous substance, finely punctuated, in which are found fibres, sometimes isolated, sometimes united in bundles like the fibres of cellular tissue, more often easily isolated and elastic. More rarely there may be seen large and transparent fibres, analogous to those which are met with in fibrine. In the middle of these fibrous bundles may be observed granulations composed of little globules of 1-400 to 1-800 of a millimetre in size, and enclosing some bubbles of air. ‘These globules are sometimes very regularly grouped and then form rounded masses.” Dr. Lyons who has carefully examined a specimen of albuminous membrane prepared by M. Melsens, with a high magnifying power, says: —‘ The granular base constituted a very considerable portion of the entire specimen, but did not appear to be uniformly disposed throughout it, as in some portions it formed nearly the entire, while in others it was almost altogether replaced by fibres. The solidifying force would thus appear not to have acted with uniformity. To deter- mine what modifications of it produced granular matter — what fibres — what again caused the formation of the little spherical bodies — are uestions, perhaps, of too delicate a nature to admit of ready solution. ould we arrive even at an approximate explanation, a great step would be achieved in the history of the obscure process of histogenesis. The most interesting of all the structures observable in this prepara- tion are the spherical bodies. They are nearly uniform in size, grouped quite close to each other, and present nearly uniform characters. Under all conditions of light, both as to mtensity and obliquety, they presented a sort of nucleus, which in all was of a long elliptical shape, although the bodies themselves appeared as nearly as CHEMICAL SCIENCE. 255 possible spherical. This nucleus was in length equal to about one- half the diameter of the sphere, and in breadth about one-eighth. What was the nature of these bodies? They were certainly not either spheres of oil, or bubbles of air; there was not the slightest probability of the former substance being present; air bubbles they also could not be; the specimen had been at rest in spirit for a very considerable time, while as more positive evidence of their cell structure I would adduce the peculiar nucleus, which in all was oblong, and did not disappear under any conditions of light. May we then regard them as nucleolated nuclei, or small nucleated cells ? These dis- coveries have filled me with the highest hopes of seeing before long some large advances made in this hitherto almost unworked fleld of investigation.” ON SPONTANEOUS HUMAN COMBUSTION. MM. Biscuorr and Lirsic, employed as experts in the recent celebrated case of the Countess of Gorlitz, not only declared that her case presented an example of post mortem burning, which proved to be true, but took the occasion absolutely to deny the trustworthi- ness of any of the cases of spontaneous human combustion on revord. This position M. Devergie combats, founding his argument upor the consideration of a case which occurred to himself, and of the vari- ous accounts of other examples that have been recor ded by trustworthy persons. Although the term spontaneous is not strictly a correct one, masmuch as there has always been an immediate cause of the combus- tion, he retains it for want of a better; and he considers the leading characteristic of these cases to be the absence of harmony between the mass of the parts burned and the feebleness of the agent of combus- tion. He enumerates the following peculiarities, as exemplified by most of the facts on record: 1. The extent and depth of the burns, as compared with the feeble proportion of combustible matter employed in their production. 2. Indulgence in spirituous liquors by the vic- tims. 3. The far greater frequency of the occurrence in women, and especially in old women. 4. The presence of an accidental determin- ing cause. 5. So complete is the combustion in some cases that nothing but the ashes remain, and these are always of the same fatty soot. 6. The combustion while acting on a mass of flesh and fat has any. ‘spared highly inflammable bodies in the vicinity. 7. The flame when seen has always been described as of a blueish color and as inextinguishable. M. Devergie points out how these circumstances differ from those observed in the Countess’s case and in death from ordinary combustion. When this extends from the clothes to the person, very large superficial burns are produced, which from their very size prove “fatal ; but there is no instance of bodies becoming completely carbonized or reduced to the condition in which they are- found in these cases. It is true, that when the amount of combustible body exists in due proportion to the body to be burned we may see such effects produced, but the absence of this relation is the prime 256 ANNUAL OF SCIENTIFIC DISCOVERY. characteristic of these cases. A mere lamp or hot cinder suffices ; while in the experiments made upon the Countess’s body 125 pounds of wood had to be used. The other capital point is, the isolation of the combustion amidst combustible bodies, the most inflammable substan- ces remaining uninjured. In the Countess’s case the floor and chairs, even at a distance, were burned. In M. Devergie’s case, complete combustion of the body had taken place in a little wooden room five or six feet broad by eight or nine feet long, and yet two muslin curtains at the window were uninjured. In all the cases, too, abuse of alcohol is mention; and although Bischoff laughs at this as a mere invention of the persons of the vicinity, for the purpose of pointing a moral, it is too particularly specified in all the cases to admit of doubt, and it is to this abuse of alcohol that M. Devergie is disposed to at- tribute the production of the phenomenon. ‘The quantity excreted by the urine and,sweat is probably not in due relation to that imbibed ; and a vital modification is impressed upon the tissues, by reason of which they become endowed with a greater combustibility, either mechanically, or by the transformation of the absorbed alcohol com- bined with the tissues into a new substance. — Annales d’ Hygiene. CHEMICAL TESTIMONY IN CASES OF POISONING. M. OrFiLa, in a recent capital case for poisoning in France, took occasion to represent to the court the reason why experts could not reply to the question so often put to them, as to whether a suflicient quantity of poison to cause death had been administered, and the danger, in reference to the suppression of crime, the insisting upon such a question gave rise to. ‘The chemist may only be able to detect the thousandth, or the twenty-thousandth part that has been adminis- tered, when the poison has been evacuated or excreted, and the dis- charges have not been preserved. If all the poison has been thus expelled he may not be able to detect even a trace, and yet, although in the one case, what he has detected has been insufficient to cause death, and in the other he has found none at all, so that the jury may pro- nounce that no poisoning has occurred, yet has the person died of such poisoning. To ascertain the whole amount of poison that remains in the body, the entire frame would have to be submitted to analysis, which is clearly impracticable; while calculations of the quantity existing in the whole body from that which has been obtained from a part, would give rise to the greatest errors, inasmuch as the poison is not equally distributed over the whole frame, some portions of this absorb- ing and retaining much more of it than others. Different processes also employed by the same hand afford very different quantities, as does the same process performed by chemists of different degrees of expertness. The French law, too, does not require any decision on this point, as it punishes the attempt to poison by any substance that may cause death — this applying not to the proportion employed, but to the substance used. CHEMICAL SCIENCE. 25T ON THE ELIMINATION OF CERTAIN POISONS. Tue following is an abstract of a paper recently read before the French Academy by M. Orfila :— When a poison has been absorbed and carried into the tissues of a living being, does it remain indefinitely within these tissues? or is it expelled from them? In the latter case, in how long a time does the animal economy effect the expulsion? Finally, in what way is the poison conveyed out ? ‘ These three questions include all that relates to the diminution of poisonous substances. The experiments relative to the study requires a very long time. in eighteen months I was able to experiment on only four poisonous substances— bichloride of mercury, acetate of lead, sulphate of copper, and nitrate of silver. These experiments have taught me that when the above poisonous substances are admin- istered to animals, that mercury disappears in general from the organs in eight or ten days. In only one case I found it to take eighteen days. Lead and copper are found in the intestinal parietes and in the bones eight months after they have ceased to be introduced into the stomach. Silver, whose presence in the liver may in some cases be demonstrated after six months, is not found in any organ of other animals, seven months after the administration of nitrate of silver. In the course of these researches I have seen that lead, copper, and mercury pass into the urime; but whilst the two former are carried away by the renal secretion, only two days after the administration of the copper or lead compound, the mercury continues to be carried off by this excretion eight days after the introduction of the mercurial preparation. I have never been able to detect silver in the urine of animals which have taken nitrate of silver. I beg for a moment to call attention to the applications which may be made by the medical jurist of a knowledge of the elimination of poisonous substances. When I began this work, I had especially the view of facilitating the solution of some problems which might impede or stop the course of justice, if the practitioner did not possess the most precise knowledge on this portion of toxicological physiology. A few examples will suflice to show the benefit to be derived from the study in medical jurisprudence. A. An individual who had been subjected to a mercurial treatment by corrosive sublimate, died four months after the cessation of the treatment, being poisoned by a mercurial preparation. The analysis, which is performed by the processes hitherto known, detects mercury in the organs. The detence is able, in consequence of these antecedents, to raise strong doubts, as to the origin of the metal. According to my experiments we can ascertain that the mercury does not proceed from the mercurial medicaments taken four months previous to death ; for after the administration of corrosive sublimate, the mercury does not remain in the animal tissues more that eighteen days. B. Should a man survive a poisoning by corrosive sublimate for fifteen days, it is very possible that the chemists consulted in the case 258 ANNUAL OF SCIENTIFIC DISCOVERY. would find no mercury in the organs. They would, however, commit a great error should they conclude that there had been no attempt to poison. This error is impossible when we are acquainted with the above-named facts. C. A workman in a white lead factory died two months after having ceased to manipulate saturnine preparations. In his organs the chemist finds lead. Had this lead been given criminally, or does it proceed simply from the compounds absorbed by the workman in the factory? To give a satisfactory reply to this question, the operator must carefully study the development and the symptoms of the malady which preceded the death, and combine these facts with those furnish- ed by the study of elimination. It is rational to make a comparison of the process hitherto proposed for the detection of lead, copper, and mercury contained in organic compounds, before studying their elimination. Three processes are employed in the search for lead and copper, they really differ from each other only in the agents employed for the carbonization of the animal matter. These agents are nitric acid, nitric acid mixed with one- fifth of chlorate of potassa, and sulphuric acid. From my experiments I conclude that the carbonisation by nitric acid is superior to the others ; that the mixture of nitric acid and chlorate of potassa does not give good results, and, finally, that carbonisation by sulphuric acid is far inferior to the others. When we seek for mercury, the best-of known pro- cesses consist in carbonising the organic matter with sulphuric acid. M. Lanaux proposes the destruction of this matter by a current of chlo- rine. Comparative experiments have shown me that this last process is more sensible than the former.— Comptes Rendus. ON THE ACTION OF OZONE ON MIASMATA. BY M. SCHONBEIN. M. ScHonBern’s additional researches have still further developed the analogy of this substance to chlorine, and leave no doubt of the injurious effects it may exert on the respiratory organs when in excess. Mice soon perish in an atmosphere containing 1-6,000. The quantity which prevails in the atmosphere is very variable, being proportionate to the amount of electricity, and therefore at its maximum in winter, and its minimum in summer. It is, however, highly probable that, when existing only in minute quantities, it exerts a purifying effect on the atmosphere by destroying various deleterious miasmata. There are a great number of inorganic gaseous bodies, which when diffused in scarcely appreciable quantities, yet render the airirrespirable. An incessant source of miasmata exists in the variety of gaseous com- pounds which are incessantly liberated by the decomposition of the innumerable masses of organic beings which’ perish on the surface of our globe. Although the composition of most of these is unknown, it is supposed that their accumulation would render the air unfit for respiration. Nature has, however, provided the means of destroying such deleterious compounds as fast as they are generated, for M. Schonbein regards ozone, which is so constantly generated under CHEMICAL SCIENCE. 259 electrical influence, and is so powerful an agent of oxidation even at ordinary temperature, as specially destined to that end. His experi- ments prove that air containing 1-6,000 of ozone can disinfect 540 times its volume of air produced from highly putrid meat: or that air containing 1-3,240,000 of ozone can disinfect an equal volume of air so corrupted. Such experiments show how little appreciable by weight miasmata may be, which are yet sensible to the smell, and how small is the proportion of ozone necessary for the destruction of all the mias- mata produced by putrifaction of organic matter and diffused in the atmosphere. We may admit that the electrical discharges which occur incessantly in different parts of the atmosphere and determine there the formation of ozone, purify the air by ridding it of oxidizable miasmata, at the same time that these are destroyed by ozone, the organic miasmata cause its own disappearance, and prevent dangerous accumulation of it. The opinion that storms purify the air may not be without foundation, as a large quantity of ozone is then produced. In the authors experiments, he has always found a large proportion of ozone in the vicinity of the stormy clouds of Jura; and the air ozon- ized by phosphorus by experiment, gives forth a similar smell to that perceived amidst storms in mountainous regions. It is very propable that in certain localities the balance between the ozone and the mias- mata does not prevail and disease may be the consequence. As a general rule, however, numerous experiments have shown that the air contains free ozone, so that no free oxidisable miasmata can there exist. M. Schonbein recommends that the atmosphere should be tested for ozone, in localities and at periods where fevers and other forms of disease prevail, so that the results of accumulated observations may be obtained. — Arch. des Sciences. Dr. Moffatt, of England, in a paper read before the Meteorological So- ciety, shows by a series of very elaborate tables, thatan apparent connex- ion is discoverable between the first appearance, increase, decrease and disappearance of atmospheric ozone with the decrease and increase of the readings of the barometer and thermometer and the state of the weather generally. Also that prevalent diseases form groups corresponding with certain meteorological conditions. In the formation of these tables Dr. Moffatt has paid strict attention to all the lesser fluctuations of the barom- eter and thermometer, being convinced that there exists a great necessity for so doing, from the slightest variations in the reading of the barometer being followed by a change in the direction of the wind, and the appearance and increase, or decrease and disappearance, of ozone. Ozone Dr. Moffatt considers to be intimately connected with falls of rain, hail, snow, and sleet, and dynamic electricity, but that it is not necessary for any of these to occur for ozone to be produced ; for if the barometer reading increases, and a current of air sets in from the northern points of the compass after or with any of these, ozone will disappear, but if the barometer reading decreases and the wind comes from southward it appears to increase in proportion to the decrease of the reading of the barometer and the force of the current. The fall of ie aie ee ozone he thinks is possibly attributable 260 ANNUAL OF SCIENTIFIC DISCOVERY. to the wind becoming north during the continuation of an ozone period or at its termination. According to the observations contained in this paper, the potato and other diseases occur at the same time and appear to be produced by the same causes. As ozone is invariably attendant upon these causes, Dr. Moffatt was induced to try its effects upon vegetable life by means of actual experiments. In August, 1851, two plants were placed under a glass case, so resting upon slips of wood as to permit the air freely to pass beneath and an ozone test- paper was fixed in the crown of each glass. A watch-glass containing a piece of phosphorus was placed upon the soil in the pot which con- tained a longiflora. In the course of ten hours the test-paper became tinged and the interior of the glass was bedewed with moisture. At noon on the following day, or eighteen hours from the first action of the etc dew drops were perceived to hang from the points of the eaves; the test-paper in the other glass did not show the slightest change. In two days the leaves began to assume a brownish tinge, and became darker, until nine days after the commencement of the experiment the branches began to droop, and on the tenth the whole plant was completely withered ; the ozone paper was not deeply tinged, less so than was frequently found to be the case in twenty-four hours in common atmospheric air. The other plant continued healthy. The experiment was repeated upon two geraniums with the same result ; that which was exposed to the influence of ozone, although the stronger of the two plants, perished in seven days, whilst the other remained possessed of its vitality and continued to blossom. The principal conclusions arrived at by Dr. Moftatt from the observations contained in his paper are,—that the greatest number of diseases occur with decreasing readings of the barometer and thermometer, and with appearance and increase of ozone, — that certain diseases would appear peculiar to certain directions of the wind, — that epi- lepsy and sudden deaths occur most frequently at the commencement of an ozone period, — that the potato disease accompanies the diseases in the animal kingdom, — and that atmospheric ozone is injurious not only to animal but to vegetable life. ON A PECULIAR PROPERTY OF ETHER, AND OF SOME ESSENTIAL OILS. Tu1s property, which has just been made known by Prof. Schon- bein, so well known by his discovery of ozone, is similar to that possessed by phosphorus, when put in contact under certain circum- stances with pure oxygen, or of atmospheric air, of developing that powerful oxidising agent, which has received the name of ozone. If, says M. Schonbein, a little ether is poured into a bottle of pure oxygen, or of atmospheric air, and exposed to the diffused hght, agitating it from time to time, the ether, after an interval of four months will have acquired new properties. Although it does not act on litmus paper, it decolors the solution of indigo, converts pure phosphorus into phosphoric acid, eliminates the iodine from iodide of CHEMICAL SCIENCE. 261 potassium, changes sulphate of protoxide of iron, into bibasic sul- phates and acids, transforms yellow cyanide of potassium into red cyanide, and converts sulphuret of lead into sulphate, etc. The essential oil of turpentine, and that of citron produce the same effects, if treated in the same way. Accordingly to M. Schonbein this new property is due to the presence of oxygen in an exalted chemical condition. — Jour. de Chemie. ANALYSIS OF PERSPIRATION. THE analysis of perspiration has hitherto given contradictory results to the several analysts who have examined it; it is still doubtful. M. Favre has, however, presented to the French Academy an important memoir upon this subject, in which he establishes some facts and exhibits results new in the history of secretions. He has isolated from perspiration two immediate principles, whose existence in that liquid was never suspected ; one is wrea, a composition found in several other humors, and an azotic acid discovered by M. Favre, and which he calls sudrique acid. Among the elements whose exist- ence remained an object of doubt to physiologists was lactic acid. M. Favre was so skilful and he had so large a quantity of perspiration to operate on (no less than 80 pounds!) he succeeded in obtaining six grammes of lactate of zinc. M. Favre ascertained that the chlorure of sodium, by its large proportion, must be considered as the essential mineral element of the liquid secreted by the sudoriparian glands. The almost absolute absence of other inorganic materials (such as phosphates and sulphates) in perspiration throws new light upon the secreting functions, and proves this singular fact: the saline sub- stances dissolved in the blood are eliminated one to the exclusion of another, by the different glandular apparatus of the system. For example, in analysing two equal proportions of urine and of perspira- tion, 28 pounds of each coming from the same subject, the first gave 21 grammes of alkaline sulphates and the second only one decigramme. ON A METHOD OF GETTING RID OF SAL-AMMONIAC IN ANALYSIS. WE copy the following communication by Dr. J. Lawrence Smith, from Silliman’s Journal, Jan., 1853. There is nothing in mineral analysis more embarrassing than the accumulation of sal-ammoniac towards the end of an analysis, especially where potash or soda are to be estimated. The only method now adopted to get rid of this ammoniacal salt, is to volatilize it by heat, which if the quantity be considerable, is attended by no little annoyance, and a certain loss of more or less of the fixed alkalies which may be present. I have recently discovered a mode of overcoming that difficulty, and much experience has proved its value, the method is simply to add nitric acid to the solution containing the sal-ammoniac and alkalies, and heat it gently overa lamp or sandbath in a glass flask or porcelain capsule. The nitric acid may be added either before the liquid is eoncentrated, or after 262 ANNUAL OF SCIENTIFIC DISCOVERY. concentration ; a most quiet decomposition ensues, and the liquid readily evaporates to dryness leaving nothing but the fixed alkalies if they be present. Iam in the habit of using a little more than three grammes of pure nitric acid of ordinary strength to every gramme of sal-ammoniac supposed to be present in the liquid. The exact nature of the decomposition which ensues cannot now be stated, but there is doubtless formed, besides other things — chlorine, hyponitric acid and nitrogen. -GEOLOGY. THE FUTURE OF GEOLOGY. REGARDING the geological scale of formations as an artificial scheme, founded on local considerations, although an instrument and scale of great value when used judiciously, the questions have to be answered, whether the terms of its graduation be required, and whether, as we have them, they are complete. See those broad stripes of demar- cation printed on every geological diagram between the terms palezo- zoic and secondary, secondary and tertiary. These lines are popularly understood to mark boundaries between a complete cessation of one great system of types of species, and the commencement of an entirely new series of creatures, animal and vegetable. They really mark pro- digious gaps in our knowledge of the sequence of formations and the procession of life. One of these supposed impassible boundaries, that between “tertiary” and “ cretaceous,” threatens rapidly to give way, and to vanish in due time, as speedily as artificial social distinctions in society. In France, Belgium, Germany, and England, there are symptoms of an intergrowth between the long separated “ chalk” and “eocene.” Strata are coming to light which rudely insist on finding elbow-room among our neatly-packed systems and formations, Janus- like fossils are turning up with two sets of features. Our preconceived notions of what ought to be are sadly disconcerted. An already exten- sive terminology is threatened with an inundation of new terms, too necessary to be evaded. If we are not mistaken, there are little clouds rising on the geological horizon that indicate revolutions elsewhere in the series. ‘That narrow black line drawn on geological diagrams between the words “ Trias” and “ Permian,” has more meaning Mm it than its dimensions indicate. The line between “ Eocene” and “ Cre- taceous,” has swollen out, broken up, and is enlarging fast into inter- mediate sections. But all its changes and increase will be as nothing compared with those that must take place by and by in its representa- tive lower down. If we interpret aright, the signs indicated by extinct organisms preserved to us in paleozoic rocks, and the comparison of them with others in the lowest mesozoic or secondary strata, there is a gap in our knowledge of the succession of formations, the extent of 23* 264 ANNUAL OF SCIENTIFIC DISCOVERY. ¢ which it is almost disheartening to think upon. Although the paleo- zoic fauna and flora, are assuredly portions of the same unique system of organized nature, with the assemblages of creatures of after-date in time, they exhibit differences in detail so great that, on superficial consideration, we might almost be inclined to regard them as belonging to some other world than our own. ‘These differences are such as at present set all our calculations respecting the climatal conditions of the primeval (paleozoic) epochs at defiance. But that these oldest of creations were linked with ‘those that came after, and those amidst which we live, is evident in the number of géneric types common to all, and expressed yet more strongly in the presence of straggling representatives of types of life, characteristically paleeozoic, among the very lowermost strata of the secondary period. All analogy teaches us, however, that there is a graduation of one geological period into another; and every day’s advance in research goes to confirm this belief. The facts to which we have alluded indicate evidences of such a graduation of paleozoic into secondary. But the stages of that graduation, the intermediate formations, have not yet been discovered. Calculating from the amount of blank in the series of organized types, there must have been a vast interval of time inter- vening between the Permian and Triasic epochs, during which, doubt- less, sediments were being ‘deposited in seas, sea-beds upheaved, animals and plants flourishing, generations and generations, nay more, creations and creations, appearing, succeeding and disappearing; and yet of all these universal accumulations and organized assemblages, there has not been as yet a fragment found. “They are but ill-discoverers,” wrote Lord Bacon, “ that think there is no land when they can see nothing but sea.” Columbus had fewer signs to warrant his belief in a new continent than we have to indicate an unexplored and as yet unseen geological world. Such signs cannot be dissipated by any appeal to the series of strata already investigated. If we jot out on the map of the world those portions which have been sufliciently examined, at once paleontologically and geologically, the space covered by our ink makes but a poor show. Our hope lies in ‘the rapidly advancing progress of comparative geology, especially through the aid and sure operations of organized surveys. All over Europe such surveys are in progress, or about to commence, sanctioned as they ought to be by governments of every shade of opinion.» Some three or four years ago, it was publicly declared that the geology of England was completed; a plausible announcement, since almost every corner has been subjected to the tramp and ham- mers of geologists. Yet, if we are not greatly mistaken, even the geology of England has much still to be done. Itis ably sketched out ; portions of it have been developed with skill and ability ; but by far the greater part will yield a luxuriant harvest of discovery to those able and willing to enter upon the task. The nearer we come to geologizing by square miles or leagues, the more interesting will be the results of our labors, and the economical value of geological researches depends mainly upon such works. — Westminster Review, 1852. GEOLOGY. 265 ON THE CAUSES OF THE CHANGE OF CLIMATE AT DIFFERENT GEOLOGICAL PERIODS. Tue following is an abstract of the recent address of Mr. Hopkins, President of the Geological Society of England The author first con- siders the influence on the earth’s superficial temperature of a central heat, supposed to be the remains of a former and very much greater heat which has been gradually diminishing during some indefinite period of time. The effect on the superficial temperature due to this cause may have been formerly of any amount, but is now reduced to within one-twentieth of a degree of Fahrenheit, of that ultimate limit to which it would be reduced in an indefinite period of time, suppos- ing the external conditions under which the earth is now placed, such as the amount of radiation from the sun and stars, and the state of the atmosphere, to remain as at present. Poisson has calculated that it would require 100,000 millions of years to reduce the present temper- ature by about one-fortieth of a degree of Fahrenheit. It is probable, therefore, that many millions of years must have elapsed since the central heat can have elevated the earth’s superficial temperature by a single degree. The author also explained that any very sensible increase of superficial temperature from this cause must have been attended with an exceedingly rapid rate of increase of the internal temperature in descending below the earth’s surface. It is only, how- ever, to the more remote geological periods that we can refer for any very sensible change in the climatal conditions of our globe due to this cause. Such changes, also, must manifestly be continually from a higher to a lower temperature ; and, therefore, we must appeal to some other cause to account for such oscillations of temperature as those of the glacial period. Poisson suggested that the present internal tem- perature of our globe might not be due to its primitive heat, but to the fact of the solar system having passed through some region of stellar space of which the temperature, owing to stellar radiation, is much greater than that in which it is now placed. Without professing to say how far this cause may have influenced the climatal conditions of the earth at former remote periods, the author shows that, reasoning from all we know respecting the relative positions of the stars and the probable motion of the solar system, this cause cannot have produced a change so great as that which must have taken place during the gla- cial epoch, at a time so recent as we have reason to believe that epoch to have been. The author next proceeds to examine the effects of changes in the disposition of land and sea, and of the consequent changes in the direction of ocean currents. The map of isothermal lines, recently published by MM. Humboldt and Dove, enables us to estimate the influence of the existing configuration of land and sea, and that of currents superinduced thereby, and thus we are enabled to estimate approximately the effects of like causes in different hypo- thetical cases. The isothermal lines have thus been constructed by the author for the following cases: 1. When the progress of the gulf stream into the North Sea is supposed to be intercepted. by land con- 266 ANNUAL OF SCIENTIFIC DISCOVERY. necting the northern point of Scotland with Iceland, and that island with the continent of Greenland. 2. The next case assumes the ele- vation of the land now constituting western Europe to a sufficient height to produce such glaciers as those the effects of which we recog- nize in that region as having been produced during the glacial period. 3. The northern portion of the Atlantic is supposed to be converted into dry land by the elevation of its bed. 4. In the last case, the absence of the gulf stream with its ‘nAtSeE upon the western coast of Europe is assumed, together with the submergence beneath the sea of a large portion of northern and western Europe. In this part of his memoir the author restricts himself chiefly to the consideration of these cases with the view of ascertaining how the cold of the glacial epoch can be best accounted for, together with its consequent glaciers of sufficient magnitude to pr oduce the phenomena now so universally attributed to them. Having constructed the isothermal lines in any of the above cases for January and July, he deduces the mean annual temperature at any proposed place. He can then calculate the height at that place of an imaginary surface in the atmosphere, the tempera- ture of which, at every point, is equal to 32° Fahr. This imaginary surface must of course meet the surface of the earth along a line for every point of which the mean annual temperature is that just men- tioned; and any line upon this imaginar ry surface (as that in which it intersects the surface of a mountain, ) is called a line of 32° Fahr. In estimating the height of this line, the author adopts the results given by Humboldt and others, as to the decrease of temperature for an assigned increase of height in ascending from the earth’s surface. The next step is, to ascertain the position of the snow-line in refer- ence to the line of 32°. In tropical regions the former line is below the latter; in higher latitudes it is generally above it. Whenever the difference between the summer and winter temperature is small, the snow line has a comparatively low position with respect to the line of 32°. By means of these and other inferences, drawn from existing cases, we are able to estimate approximately the relative positions of these two lines in our hypothetical cases, and thus knowing by calcu- lation the height of the line of 32° at any proposed place, we can estimate that of the snow line at the same place. Now, it appears by observation that nearly all the well known glaciers, of sufficient mag- nitude to be considered of the first order, descend about 4,000 or 5,000 feet below the snow line, and that the smaller glaciers descend only to smaller distances below that line. We are thus enabled in any hypothetical case to form an approximative estimate of the distance which a glacier would probably descend beneath its snow line; or, knowing the height of that line by the means above stated, we can thus estimate the height above the sea level to which the lower extrem- ity of the glacier would probably descend. The author then proceeds to apply these principles to cases 2, 3, and 4 above mentioned, and to determine the conditions under which glaciers, sufficiently large to produce certain observed glacial phenomena, would exist in Western Europe. In ease 2 it would be necessary that that region should be GEOLOGY. 267 elevated into a mountainous range of not less than 10,000 feet in height; a conclusion inadmissible, on account of the entire absence of all independent geological evidence in support of it. The hypothesis of case 3, Mr. Hopkins rejects for a similar reason. Case 4 is then discussed at length. It is shown that glaciers of the required magni- tude would in that case exist in the region of Western Europe, if in addition to the absence of the gulfstream we suppose the existence of a cold current from the north of a moderately refrigerating influence. This latter current, however, might not be essential. The entire diversion of the present gulf stream into some other channel, which is required by this view of the subject, would be the necessary conse- quence of that submersion of the North American continent, of which we have such conclusive evidences during the glacial period; for in such case the current which sets into the Gulf of Mexico would mani- festly continue in its north-westerly direction along the present valley of the Mississippi and the range of the Rocky Mountains to discharge itself into the Atlantic Ocean. This would correspond to the glacial period on this side the Atlantic; but along the new course of the gulf stream there would be a much warmer climate than at present, —and that such a climate has there existed ata recent geological epoch seems to be abundantly proved by vegetable remains which have been found between Hudson’s Bay and the Rocky Mountains, precisely in the line which the warmer current would take. A subsidence of the American Continent, of less than 2,000 feet would render the ocean continuous from the Apalachian chain, on the east, to the Rocky Mountains on the west, and there seems reason to believe that the subsidence may possibly have attained to a consider- ably greater amount. Now, it is manifest that the gulf stream is reflected in a north-easterly direction across the Atlantic, by the con- tinent of North America, which arrests the north-westerly course by which the current reaches the Gulf of Mexico. But when that con- tinent was submerged, as above supposed, the current would necessa- rily continue its north-westerly course, and probably along the foot of the Rocky Mountains directly into the Arctic Sea. This is the man- ner in which it is conceived the gulf stream was diverted from the shores of Western Europe. This diversion of the current is not to be regarded as a mere hypothesis adopted to account for any particu- lar fact, but as a necessary consequence of that submergence of the North American continent. Again, if this enormous current discharged itself into the Arctic Sea, it would seem extremely improbable that it should not give rise to some great determinate counter-current out of that sea. Now it appears highly probable that a considerable tract of land must have existed at the period of which we are speaking in the present region of north-eastern America, and Greenland. If this were the case, the only practicable outlet for a great current from the Arctic Sea would be across the submerged portion of northern Europe, or along the present North Sea, between Greenland and Norway ; for the passage through Behring’s Straits, even with a considerable subsidence of the 268 ANNUAL OF SCIENTIFIC DISCOVERY. land on either side, would be neither sufficiently wide nor deep to form a considerable outlet. Under such circumstances, it would scarcely seem more necessary that the gulf stream should hold its original north-westerly course over the submerged continent of Amer- ica, than that it should complete its circuit by passing through the Arctic Sea, and returning to the Atlantic across the submerged land of Europe, as it now completes a more circumscribed circuit by being constrained to pass along the northern portion of the Atlantic itself. The effect of this diversion of the gulf stream from its present course, would not be less remarkable in elevating the temperature of the northern shores of America and Asia, than in reducing that of western Europe. It can be shown that the mean annual temperature of Iceland is increased 18° or 20° Fahr., and the January tempera- ture 34°, by the influence of this important current. There can be no reasonable doubt, therefore, of its raising the temperature of the north-western coast of America, from the Mackenzie river to Behr- ing’s Straits, by an amount at least equal to that by which it now ele- vates the temperature of Iceland. Further, it is highly probable that the principal course of the current in the Arctic Sea would not be far from the coasts of northern Asia, the temperature of which would thus be affected in a manner similar to that of the coast of America eastward of Behring’s Straits. The temperature of winter immedi- ately east of the Ural Mountains, would also be considerably moder- ated, as already stated, by the extension of the European sea towards their western flanks. The climate of the low lands of northern Asia would thus differ from the present climate of that region, as much as the existing climate of the western coast of Norway differs from that which would desolate that region in the absence of the gulf stream. According to this view of the subject, the former existence in northern Asia of the immense numbers of large Mammalia indicated by the abundance of their fossil remains, no longer presents the slightest difficulty ; and the theory receives a still further confirmation from an observation made by Sir John Richardson in his “Arctic Searching Expedition,” just published. The author observes, “ The existence of these numerous testimonials of an ancient fauna is sug- gestive of many curious speculations, and geologists seem hitherto to have failed in explaining the circumstances under which accumula- tions so vast could occur in such high latitudes. The difficulty is increased when we consider that these bones have not been detected to the east of the Rocky Mountains in high latitudes.” This increased difficulty, however, is at once removed by the theory now proposed, for the region in which these remains are not found, must either have been covered with the waters of the ocean to the foot of the Rocky Mountains at the period when these Mammalia occupied the region to the westward, or if land existed on the north-east of the present American continent, it was probably too cold to be inhabited by them. Their disappearance from the country bounding the Arctic Sea, from the Rocky Mountains to the Ural, would be the consequence of the withdrawal of the gulf stream from the more eastern, and of the Euro- \ GEOLOGY. 269 pean ocean from the more westerly portion of that region. Fossil plants also, belonging to a comparatively warm climate, have been found east of the Rocky Mountains, on the coast of the North Sea; and extensive beds of lignite exist along the eastern flank of those mountains. So far as these phenomena may be of Pleistocene origin, they may be ai once accounted for by this theory. ° Before the depression of the North American continent was sufli- cient to admit the gulf stream to flow freely to the Arctic Ocean, the northern part of that continent would be converted into an Arctic sea, and this would correspond to the first part of the glacial drift period in that region. On the gradual elevation of the land after its greatest depression the north-western course of the gulf stream would be again arrested, and the northern portion of the American continent would be again converted into an Arctic sea. The temperature of the region of the eastern portion of North America would probably not be much affected by the alteration in the course of the gulf stream, nor would it probably be very different from that which obtains at present along its eastern coasts. It may also be added, that the continued course of the gulf stream into the Arctic Ocean would very probably generate a cold counter-current from the North Sea across the submerged por- tion of Europe, such as has been above alluded to. The author is anxious to direct the attention of geologists to this view of the subject, in the hope that it may be tested by such further observations as may bear more immediately upon it. Jt appears to him to satisfy better than any other theory the present known conditions of the great problem which the glacial epoch presents to us. DRIFT OF THE NORTHERN AND WESTERN STATES. M. Dezsor, who has devoted much time to the examination of the drift, or quarternary deposits of the Northern States, recently pre- sented an abstract of his observations to the Geological Society of France. M. Desor classifies the superficial and non-indurated rocks of the waters of the St. Lawrence, and the Upper Mississippi, as follows ; 1st, Alluvium; 2d, marine drift; 3d, fresh-water drift; 4th, drift proper, or diluvium. M. Desor proceeds as follows: Alluvium is here, as everywhere, the least developed member ; com- prising the deltas of rivers, sand banks, shallows, and dunes. The marine drift passed at first among the American geologists, under the name of Tertiary, and comprises deposites of clay, sand and gravel, containing marine shells. I propose to call them by the name of Laurentian, because these deposites are largely developed in the littoral valleys of the Atlantic ; and principally in the great valley of the River “ St. Laurent,” (Law- rence,) and its affluents. It is thus I distinguished them from the similar deposites, that contain any fresh water fossils. Along the side of the Laurentian beds, and almost in contact with them, but at a little higher level, is found a series of deposites, externally very much like them, but without marine shells. This formation has no 270 ANNUAL OF SCIENTIFIC DISCOVERY. analogue in the continent of Europe ; and it constitutes in America, the most marked feature in the geology of the quarternary period. Coming from the sea coast, we meet with it first, on the shores of Lake Erie, where it forms slopes, and terraces, composed at the lower parts of blue clay, and hard pan, surmounted by loam and gravel. A moment’s observation convinces any one, that these ridges, terraces and slopes, are not the result of violent action; but that they were deposited in quiet waters. As the fossils are rare, as they differ in many respects from the Laurentian, doubts naturally arise as to their origin, and their age. Are they marine, or are they lacustrine ? The same doubts rest upon the loamy deposites, that form the surface material over the vast space, occupied by the States of Wisconsin, Illinois, and Iowa, and the shores of the Mississippi Some geologists have called them by the name of loess, from their resemblance to the ‘loess ” of the Rhine. But these doubts have recently been removed, by the discovery by Mr. Whittlesey, in the blue marly clay of Lake Erie, at Cleveland, of fresh water and terrestrial shells, (Heleciance and Planorbis,) at 25 to 50 feet above the level of the water. The same gentleman has col- lected numerous specimens of buried timber and leaves, from the same deposites, in which they are very abundant. M. Lesquereux has recognised among them, the leaves of the spruce (Abies nigra,) the common cranberry (Vaccinium) which now grows in that country, and many species of Cyperaceec. Mr. Whittlesey soon atter discovered fresh water shells in the loess- like deposites, on the shores of the Mississippi, including many species of Planorbis, one of Cyclas, and a Physa, at 60 to 180 feet above the level of the river. The same shells have been recently observed near St. Louis, (250 to 300 feet above the stream,) and at New Harmony upon the Wabash. Very lately, Dr. Rigsby has found on the banks of the river Notawassaga, that empties into the Bay of St. George of Lake Huron, in Canada, a bed of fresh water shells, (Unios) covered with deposites of much thickness, but he has not given us their eleva- tion above the lake. Mr. Murray, of the Canadian Geological Society, has explored the northern shore of Lake Erie, and finds that the superficial deposites are composed of the same materials as those upon the southern shore opposite ; and although he has not discovered there any shells, he does not doubt but the marly clays of Canada, and the sandy and loamy beds resting upon them, were deposited by the same waters, as those on the American side. If we examine the map, and the position of these deposites, and remember the elevation at which the fossils are found, at different points, we must infer, that there existed at the quartenary epoch, two immense sheets of fresh water in North America; one occupied the basin of the Upper Mississippi, the other, that of the Canadian Lakes, but both formed one vast sea of fresh water ; from which, however, we must exclude the basin of Lake Ontario, which was marine, or salt water. The comparison of the levels, where the shells were found, at Cleveland, and on the Mis- sissippi, shows that these great basins were not then isolated, but com- GEOLOGY. 271 municated with each other by many valleys, such as the Wabash and the Illinois; so that the basin of the lakes, which is now separated from that of the Mississippi, at that epoch discharged its waters into the basin of this great river. Mr. Hubbard, of the Michigan Survey, says, there exists a depression between Lakes Huron and Michigan, through the valley of Saginaw Bay, where there was a connection of the waters. The existence of these fresh water deposites being now demon- strated, it becomes necessary to give them a specific name, to distin- guish them from the marine, or Laurentian formation. The geological corps of the United States, in Michigan, propose to call them Algonquin, from a powerful nation of Indians, who heretofore inhabited the region - of the lakes, and the heads of the Mississippi. It has not been defi- nitely adopted, because there are doubts whether the drift proper that occupies the central and elevated parts of Ohio, Wisconsin and Mich- igan, is not of the same age. It was at first admitted, that the lacus- trine deposites of Lake Erie, (on which Cleveland is situated,) although at a lower level, was nevertheless more recent than the “ drift,’ and perhaps, contemporary with the “ Laurentian.” More recent researches have not confirmed this view; and many geologists, at the head of whom is Mr. Whittlesey, are now inclined to think, that the lacustrine or the “ Algonquin ” beds, are members of the “ drift proper,” modi- fied by local action and circumstances, and that they pass insensibly into each other. If this is really so, it will follow, not only that the Laurentian is more recent than the lacustrine formation ; but what is more important, the whole drift beds of the West must be regarded as a fresh water deposit. The difficulty in this case arises, in conceiving of banking, or highlands sufficiently elevated, to hold the waters of such a basin, for the drift deposites attain the height of 1,600 feet above tide, between Lake Superior and Lake Michigan, without including the erratic blocks, or “ boulders ” that are found still higher. Unfortunately, there have no shells been found in the elevated coarse drift. The only fossils that these beds have furnished, are parts of trees, leaves, &c. It is to be hoped that shells may be discovered ; but until then, the identity of the drift with the Algonquin, or lacus- trine formation, must remain in suspense. I should remark, that there is found on the surface of the lacustrine, as well as on the Laurentian, and on the proper “drift,” boulders of all dimensions. The mere statement of this fact, proves that they were not transported by the same agent that has scratched, striated and polished, the rocks in place. If this agent was a glacier, we can no longer attribute to it the transportation of boulders, for in that case, their transportation should be contemporary with the polishing of the rocks; but there is between them the whole period, during which the lacustrine beds were being depos- ited. There are also, on the surface of the lacustrine of Lake Erie, (and other lakes) ridges and elongated hillocks, like the “ osars ” of Sweden, showing like them, traces of stratification, which proves that they were all formed under water. Neither the lacustrine or the Laurentian contain the bones of mammiferous animals, such as the Mastodon, Ele- 24 212 ANNUAL OF SCIENTIFIC DISCOVERY. phant, &c.; it being now established, that at the Big-bone lick, and in uumerous other places at the west, heretofore referred to the drift period, are more recent deposites, such as “ valley drift ” and Alluvium. M. Verneuil remarked, that he had never met with the fresh water drift, far from the great lakes and rivers of North America; and that it appeared to him, to be attributable to an ancient extension of their waters. GEOLOGICAL DISCOVERIES IN SOUTH AFRICA. Amone African discoverers little known to the general public, is Mr. Bain, surveyor of roads in Cape Colony. This gentleman, in the course of his duties, has made some remarkable observations and discoveries in the geological structure of South Africa. He _ has shown that the oldest rocks form a broken coast fringe around the southern extremity of Africa, and are surmounted by sand stones, which from the fossils they contain, are the equivalents of the Silu- rian rocks. These primeval strata, occupying the highest grounds, of which Table mountain is an example, and dipping inland from all sides, are overlaid by carboniferous strata. Above all these ancient strata, says Mr. Murchison, in his address before the Geographical Society, and occupying, therefore, a great central trough or basin, strata occur which are remarkable from being charged with terrestrial and fresh-water remains only ; and it is ina portion of this great accumulation that Mr. Bain disinterred fossil bones of most peculiar quadrupeds. One of the types of these, which Professor Owen named Dicynodon, from its bidental upper jaw, is a representative, during a remote secondary period, of the lacustrine associates of the hippopotami of the present lakes and waters. The contemplation of these discoveries, has therefore led me to point out to you how wide.is the field of thought which the labors of one hard-working geologist have given rise to, and to express, on my part, how truly we ought to recognize the merits of the pioneer among the rocks, who enables us, however inadequately, to speculate upon the entirely new and grand geographical phe- nomenon, that such as South Africa is now, such have been her main features during countless past ages, anterior to the creation of the human race. For the old rocks which form her outer fringe, unquestionably circled round an interior marshy or lacustrme country in which the Dicynodon flourished at a time when not a single animal was similar to any living thing which now inhabits the surface of our globe. The present central and meridian zone of waters, whether lakes, rivers, or marshes, extending from Lake Tchad to Lake Negami, with hippopotami on their banks, are, therefore, but the great modern, residual, geographical phenomena of those of a mesozoic age. ‘The differences, however, between the geological past of Africa and her present state are enormous. Since that primeval time the lands have been much elevated above the sea-level—eruptive rocks piercing in parts through them; deep rents and defiles have been GEOLOGY. 273 suddenly formed in the subtending ridges, through which some rivers escape outwards, whilst others flowing inwards are lost in the interior sands and lakes; and with those great ancient changes entirely new races have been created. Travellers, continues Mr. Murchison, will eventually .ascertain whether the basin-shaped structure, which is here announced as having been the great feature of the most ancient, as it is of the actual geography of Southern Africa, (7. e., from primeval times to the present day,) does, or does not extend into Northern Africa. Looking at that much broader portion of the Continent, we have some reason to surmise, that the higher mountains also form, in a general sense, its flanks only. Thus, wherever the sources of the Nile may be ultimately fixed and defined, we are now pretty well assured that they lie in lofty mountains at no great distance from its east coast. In the absence of adequate data, we are not yet entitled to speculate too confidently on the true sources of the White Nile ; but judging from the observations of the missionaries, and the position of the snow-capped mountains called Kilmanjaro and Kenin, (only distant from the eastern sea about 300 miles,) it may be said that there is no exploration in Africa, to which greater value would be attached than an ascent of them from the east coast, possibly from near Mombas. The adventurous travellers, who shall first lay down the true position of these equatorial snowy mountains, and shall satisfy us that they not only throw off the waters of the White Nile to the north, but some to the east,—and will further answer the query, whether they may not also shed off other streams to a great lacus- trine and sandy interior of this continent, will justly be considered among the greatest benefactors of this age to geographical science. The great east and west range of the Atlas, which in a similar general sense forms the northern frontier of Africa, is, indeed, already known to be composed of primeval strata, and eruptive rocks, like those which encircle the Cape Colony on the south, and is equally fissured by transverse rents. As to the hills which fringe the west coast, and through the apertures of which the Niger and the Gambia escape, we have yet to learn if they are representatives of similar ancient rocks, and thus complete the analogy of Northern with Southern Africa. But I venture to throw out the general sug- gestion of an original basin-like arrangement of all Africa, through the existence of a grand encircling girdle of the older rocks, which, though exhibited at certain distances from her present shores, is still external as regards her vast interior. With no region of the old world have we been, till very lately, so ill-acquainted as Africa. But now the light is dawning quickly upon us from all sides; and in the generation which follows, I have no doubt that many of the links in the chain of inductive reasoning, as to the history of the successively lost races of that part of the globe, will be made known, from the earliest recognizable zones of ‘animal life, through the secondary and tertiary periods of geologists. Passing thence to the creation of mankind, and to the subsequent (274 ANNUAL OF SCIENTIFIC DISCOVERY. accumulation of the great delta of the Nile, we have recently been put in the way of learning, what has been the amount of the wear and tear of upland or granatic rocks, and what the additions to the great alluvial plain of Lower Egypt, since man inhabited that most holy region, and erected in it some of his earliest monuments. But how long will it be before we shall be able to calculate backwards by our finite measure of time, to those remote periods, in which some of the greatest physical features of this continent were impressed upon it,—when the lofty mountains from which the Nile flows, were elevated, and when the centre of Africa was a great lacustrine jungle, ' inhabited by the Dicynodon, and other lost races of animals ? WESTERN HIMALAYA AND TIBET. In the years 1847-8, an expedition was fitted out by the East India Company, for the exploration of the western Himalaya and Tibet. A journal of these travels and geological researches, has recently been published in England, by Dr. Thomson, one of the party, and a son of the celebrated chemist of that name. From this book, which contains much new and interesting scientific information, we derive the following extract. Many of the places examined and described, have never before been visited by any European traveller. The old, and still popular notion of Tibet, is that of a great mountain table land, or a series of table lands, at the back of the Himalaya, by which mighty chain its southern boundary is made, a barrier broken through by the Indus at one extremity, and the Brahmaputra at the other, while its northern limit is similarly walled in by the Kouenlun chain; the country thus supposed to exist is entirely imaginary. There is, indeed, no such table land. Nor is there, indeed any such great continuous chain as the Himalaya itself. The line of snowy peaks running parallel to the plains of India are not so many sum- mits of one Alpine chain, but are separated from each other by deep ravines, through which flow large and rapid rivers. Between the Indus and the plains of north-west India is a rugged and mountainous track 150 miles broad. Kashmir is the only plain of any extent among these mountain ranges. The mountains between the Indus ‘and the. plains may be referred to two great groups, which may be respectively termed the Cis-Sutle} and Trans-Sutlej Himalayas. Tibet is the region among and of these mountains between their outer ramifications and the great chain of Kouenlun beyond the Indus. This chain separates Tibet from Yarkand and Kohoten. Over this stupendous barrier there are said to be only four passes, all crossing regions of eternal snows, and two traversing enormous glaciers. The Karakoram Pass is one of these, and is 18,200 feet above the level of the sea. ‘The visit to this extraordinary locality is thus described by Dr. Thomson :— “ On the 19th of August, I started to visit the Karakoram pass, the limit of my journey to the northward. The country round my halt- ing-place was open, except to the north, where a stream descended through a narrow valley from a range of hills, the highest part of GEOLOGY. Zt which was apparently about 3,000 feet above me. All the rivers had formed for themselves depressions in the platform of gravel which was spread over the plain. I ascended this valley for about six miles: its width varied from 200 yards to about half a mile, gradually widening as I ascended. The slope was throughout gentle. An accumulation of alluvium frequently formed broad and gently-sloping banks, which were cut into cliffs by the river. Now and then large tracts covered with glacial boulders were passed over; and several small streams were crossed, descending from the northern mountains through narrow ravines. About eight miles from my starting-point the road left the bank of the stream, and began to ascend obliquely and gradually on the sides of the hills. The course of the valley beyond where I left it continued unaltered, sloping gently up toa large snow-bed, which covered the side of a long sloping ‘ridge four or five miles off. After a mile, I turned suddenly to the right, and, ascending very steeply over fragments of rock for four or five hundred yards, I found myself on the top of the Karakoram pass— a rounded ridge connecting two hills which rose somewhat abruptly to the height of perhaps 1,000 feet above me. The height of the pass was 18,200 feet, the boiling point of water being 180.8°, and the temperature of the air about 50°. ‘Towards the north, much to my disappointment, there was no distant view. On that side the descent was steep for about 500 yards, beyond which distance a small streamlet occupied the middle of a very gently sloping valley, which curved gradually to the left, and disappeared behind a stony ridge at the distance of half a mile. The hills opposite to me were very abrupt, and rose a little higher than the pass; they were quite without snow, nor was there any on the pass itself, though large patches lay on the shoulder of the hill to the right. To the south, on the opposite side of the valley which I had ascended, the mountains, which were sufficiently high to exclude entirely all view of the lofty snowy moun- tain seen the day before, were round-topped and covered with snow. Vegetation was entirely wanting on the top of the pass, but the loose shingle with which it was covered, was unfavorable to the growth of plants, otherwise, no doubt, lichens at least would have been seen. - Large ravens were circling about overhead, apparently quite unaffected by the rarity of the atmosphere, as they seemed to fly with just as much ease as at the level of the sea. “The great extent of the modern alluvial deposit concealed, in a great measure the ancient rocks. At my encampment a ridge of very hard limestone, dipping at a high angle, skirted the stream. Further up the valley a hard slate occurred, and in another place a dark blue slate, containing much iron pyrites, and crumbling rapidly when exposed to the atmosphere. Fragments of this rock were scattered over the plain in all states of decay. On the crest of the pass the rock in situ was lime-stone, showing obscure traces of fossils, but too indistinct to be determined; the shingle, which was scattered over the ridge, was chiefly a brittle black clay slate.” Conceive a vast tract of country, the lowest valley of which is as 24* 276 ANNUAL OF SCIENTIFIC DISCOVERY. high as the summit of the Faulhorn in Switzerland, and many of whose habitable spots are nearly as lofty as the summit of Mont Blanc, composed of prodigous mountain chains from 17,000 to 19,000 feet above the sea, with occasional peaks exceeding 22,000 feet, winding and interlacing, intersected by deep and narrow valleys— ravines on an enormous scale—with too arid a climate to support forests, or any coniferous tree except alpine junipers—covered by a sky cloudy in winter, clear and bright in summer, and a powerful sun heating the bare black rocks, whilst the air is rent by winds of fearful violence—and we can forma picture of Western Tibet, the region explored by Dr. Thomson. Among the discoveries of our traveller is that of the locality whence the borax imported from Tibet is procured. The plain of Pugha is the result of the drying up or drainage of an ancient lake. It is covered to the depth of several feet with white salt, principally borax. By digging below the superficial layer, the borax is obtained in a tolerably pure state. CRYSTALLINE FORM OF THE GLOBE. M. pe HAvsLas in a recent publication, after discussing the direc- tion of mountains, and of dykes and of cleavages among rocks, deduces some general principles with regard to their direction, and then explains his hypothesis that the surface of the globe presents approx- imately the faces of the great octahedron. In an octahedron there are three axial planes intersecting one another at right angles; and the positions of the circles on the earth’s surface which he lays down as the limits of these planes (or their intersection with the surface) are as follows. The jist circle is that of Himalaya and Chimborazo, passing from Cape Finisterre to the Himalaya, Borneo, eastern chain of New Holland, (leaving on its sides a parallel line in Mallacca, Java and Sumatra,) to New Zealand, thence to South America near Chim- borazo, the chain of Carracas, the Azores to Cape Finisterre. The second, passes along the South American coast and the north and south ranges of the Andes, the mountains of Mexico, the Rocky mountains, Behrings’ Straits, the eastern Siberian chains, going to the south of Lake Baikel, the Altai, Himalaya, the mountains of Bombay in Hindostan, a point in the northeast of Madagascar (where the summits are 12,000 feet high,) the mountains of Nieuwedfeld, 10,000 feet high, Cape Caffres, to Brazil, the rapids of La Plata, Paraguay, Parana, the elevated basin of Titicaca, the Andes, Illimani and the defile of Maranova. ‘The third circle cuts the two preceding at right angles, and passes by the Alps, the Islands of Corsica and Sar- dina, along the basin of the Mediterranean, the mountains of Fezzen, Lake Tchad, the Caffre mountains of Nieuwedfeld, the Southern Ocean near Kerguelen’s Land, the eastern or Blue mountains of New Holland, straits of Behring, Spitsbergen, Scandinavia, Jutland, ete. These three great circles point out the limits of the faces of the great hypothetical octahedron. Each of the faces may be divided GEOLOGY. QTT into eight others by means of line of accidents of minor importance, so as to make in all forty-eight irregular triangles, a form of the dia- mond. Atthe intersections, M. de Hauslabobserves that there are nodes of dykes, and along the lines or near them, all the mountains of the globe occur. The author gives an extended illustration of his subject and afterwards considers the particular history of the configuration of the earth’s surface in accordance with his hypothesis. M. Boue who adopts similar views adds as a note, that we should remember in this connection that the metals crystallize either in the tesserel or rhombohedral system, and that native iron, the most com- mon constituent of meteorities, is octahedral in its crystals. ON THE STABILITY OF THE EARTH’S AXIS OF ROTATION. Tue following is a communication read before the Royal Society, by Henry Hennessy, Feb., 1852. The author refers to a communication to the Geological Society, by Sir John Lubbuck, in which he appeals in support of the possibility of a change in the earth’s axis, to the influence of two disturbing causes, which appear to have almost entirely escaped the notice of Laplace and Poisson, in their investigations on the stability of the earth’s axis of rotation;—1. The neeessary displacement of the earth’s interior strata, arising from chemical and physical actions during the process of solidification. 2. The friction of the resisting medium in which the earth is supposed to move. With reference to the first of these disturbing causes, the author states, that he has been led to conclusions which may assist in clearing up the question. From an inquiry into the process of the earth’s solidification, which appears to him most in accordance with mechanical and physical laws, he has deduced results respecting the earth’s structure which throws some light on the changes which may take place in the relation which is capable of being expressed by means of a function which depends on the arrangement of the earth’s interior strata. He then states that he has found strong confirmation of his peculiar views respecting the theory of the earth’s figure in the experiments of Bischof of Bonn on the contraction of granite and other rocks or passing from the fluid to the solid crystalline state. From the results of these experiments, he has been led to assign a new form to the function expressing the relation of the earths’ principal moments of inertia. Referring to his paper for the mathematical processes by which he has arrived at this result, he states that from the theory he has ventured to adopt, it follows, that as solidification advances, the strata of equal pressure in the fluid spheroidal nucleus of the earth, acquires increased elliptic- ity, and each stratum of equal density, successively added to the inner surface of the solid crust, is more oblate than the solid strata previously formed. From these considerations alone, he remarks, it is evident that the difference between the greatest and least moment of inertia of the earth, would progressively increase during the process of solidification. 278 ANNUAL OF SCIENTIFIC DISCOVERY. It follows, therefore, that if the earth’s axis of rotation were at any time stable, it would continue so forever. But, from the laws of fluid equilibrium, the axis must have been stable from the epoch of the first formation of the earth’s crust; consequently, it continued undis- turbed, as the thickness of the crust increased during the several geological formations. Thus it appears that the displacement of the earth’s interior strata, instead of having a tendency to change its axis of rotation, tends to increase the stability of that axis. With reference to inequalities arising from the friction of a resisting medium at the earth’s surface, the author observes that this could not exist, if, as in the manner here shown, the axis of rotation coincided from the origin with the axis of the figure. In conclusion, he remarks, that if we could assume for the planets a similarity of physical constitution to that of the earth, the theorem as to the greatest and least moments of inertia of the earth would be applicable to all the planets; and thus we should be as well assured of the stability of our system, with respect to the motion of rotation of its several members, as we are already respecting their motion of translation. In reference to a third cause of disturbance in the place of the earth’s axis of rotation, namely, the effects of local elevations and depressions at the earth’s surface, the author says: — If with Hum- boldt, we regard the numbers expressing the mean heights of the several continents, as indicators of the plutonic forces by which they have been upheaved, we shall readily see that these forces are of an inferior order, to those affecting the general forms and structure of the earth. If the second class of forces acted, so as not to influence in any way the stability of the earth’s axis of rotation, the former class might, under certain conditions, produce a sensible change in the position of the axis. But when the tendency of the second class ef forces is to increase the stability of the earth’s axis, it would not be easy to show the possibility of such conditions, as to render the operation of the other forces, not only effective in counteracting that tendency, but also producing a sensible change in the place of the axis of rota- tion. — Proc. Royal Society. SHOWERS OF SAND IN CHINA. Tue following account of sand showers in China is given by Dr. D. J. Macgowan, of Ningpo :— The Phenomenon of falling sand is occasionally observed through a reat extent, if not the entire portion, of the vast Plain ef China. It 1s of such frequent occurrence that the Chinese regard it with no more surprise than they do the flitting meteor. Probably no year passes without several of these showers, though frequently so minute as to escape general observation. Perhaps as often as once in three years they are very heavy, but it is seldom that sand falls in such a large quantity as during the last shower. The phenomenon was wit- nessed three times during the present year, within a period of five weeks; the last. and greatest commenced on the 26th of March, and GEOLOGY. 279 continued four days without intermission, varying however, in inten- sity. The wind blew from the north, northeast, and northwest, fre- quently shifting between these points, and varying in strength from a ~ perfect calm to a brisk breeze. The altitude of the barometer was from 29.40 to 30.00 (rather lower than before and after the shower.) The thermometer ranged from 36° to 81° Fahr. No rain had fallen for six weeks, and the hygrometric state of the atmosphere was very high. Neither cloud, fog, nor mist obscured the heavens, yet the sun and moon were scarcely visible, the orb of day appeared as if viewed through a smoked glass, the whole sky presenting a uniform rusty hue. At times this sameness was disturbed, exhibiting between the spectator and the sun the appearance of a water-spout, owing to the gyratory motions of the impalpable mineral. The sand penetrated the most secluded apartments; furniture wiped in the morning would be so covered with it in the afternoon, that one could write on it lecibly. In the streets it was annoying, entering the eyes, nostrils and mouth, and grating under the teeth. My ophthalmic patients gener- ally suffered a relapse, and an unusual number of new cases soon after presented. Were such heavy sand storms of frequent occur- rence, disease of the visual organs would prevail to a destructive extent. The effect was the same when observed from the Ningpo Tower, and from the summit of the low mountains in the neighborhood of the city. : The specimens I gathered fell on a newspaper placed on the roof of a house. The whole quantity which fell was about ten grains to the square foot. It should be remarked, however, that during the four days the dust seemed suspended in the air for several hours at a time, scarcely an appreciable quantity falling during these intervals. The Chinese call it yellow sand; it is an impalpable powder of that color. It was observed at sea, at Hangchau, and at Shanghai. Whence did it originate ? The opinion of the Chinese on this subject may, I think, be regarded as correct. They assert that it comes from Peking. We know that the sand of Sahara is sometimes elevated by whirlwinds into the upper current of the air, and deposited in the Atlantic twelve hundred miles, sometimes directly opposite to the trade winds. Over against the vast alluvial Plain of Eastern Asia is the ocean of sand— the Desert of Gobi or Shamoh, extending from near the sea westerly 2,300 miles, and 3 to 400 broad—including the conterminous sandy districts. Like its counterpart in Africa, it is subject to whirlwinds which raise its fine dust like the waves of the sea, and doubtless at times waft it into the upper currents of air, and transport it to distant regions. I have been informed by intelligent natives of Kiangsi and Honan, that the phenomenon occurs in those provinces also. Assum- ing the Mongolian steppes to be the source whence these showers descend, the amount of sand which is annually conveyed hither must be prodigious to cover such an extensive area. Regarded in a mete- orological and in a geological point of view, these showers possess no small interest. 280 ANNUAL OF SCIENTIFIC DISCOVERY. GNEISS AND SURPENTINE FORMATIONS. Lronarp and Bronn’s Jahrbuch state that they have observed gneiss associated with conglomerate, and great veins of gneiss travers- ing gneiss. These facts have been verified by the discovery of similar phenomena in other countries, and gneiss 1s now divided into the following formations : — 1, Primary Gneiss, that associated with certain granites, and forming the fundamental or oldest formation of the crust of the earth; 2, Transition Gineiss, that which rests upon transi- tion rocks, as greywacke, clay slate, and old red sandstone, and even alternates with them; 3, Secondary Gneiss, this formation rests upon lias, and is well seen in Switzerland. We have no intimation that gneiss has been met with in the tertiary group. Many years ago, Jameson noticed the gradual transitions from trap to serpentine, both in Germany and Scotland. Very lately the cele- brated Rose, of Berlin, has illustrated this view in a very interesting manner. ON THE EVOLUTION OF GAS IN WALLSEND COLLIERY, ENG. Pror. Puts at the British Association remarked that the Wallsend Colliery was one of the numerous coal mines in Yorkshire which have been rendered remarkable for the frequent explosion of the inflammable and noxious gas with which they are filled, and the loss of life which has in so many cases been the consequence. In every coal-pit there are two shafts, one of which serves to admit the pure air, whilst the foul gases are made to escape by the other. The ascent of the foul gases is frequently facilitated by creating a draft by fires placed near the bottom of one of the shafts. The coal is arranged in perpendicular layers, between which the gases exist in a highly compressed state. In order to detach these layers with the least pos- sible danger, it is usual to cut through them endways, by which means the gases are allowed to make their escape at once froma considerable portion of the coal. A district of this colliery, covering about fifty acres, was effectually walled up, in consequence of the immense dis- charge of gas that was continually taking place. A pipe was led from this enclosed portion up through the mine and for forty feet above the surface, and from this pipe there has been a constant dis- charge of gas for the last eighteen years. This gas has been inflamed, and in the roughest and most stormy weather it has burned without intermission ; and were it as rich in naphtha as ordinary carburreted hydrogen, it would illuminate the country for miles round. Two water-pressure gauges were fixed to the brick walls, one at the surface of the earth, and the other at the bottom of the mine, and the results were that, whilst the pressure in the mine was only 9-10ths of an inch on an average, that at the top of the pit was upwards of four inches. From observation in these minés, it 1s seen that discharges of fire- damp, governed by atmospheric pressure, take place before being indi- cated by the barometer, and that, as an indicator that instrument can- GCOLOGY. 281 not be relied on. A fact somewhat similar was first observed by Prof. Daniels, in his researches at the Royal Society, where the water bar- ometer indicated the change of pressure an hour earlier than the usual mercurial standard barometers constantly used for observations. GEOLOGY AND PALZONTOLOGY OF A PART OF THE ROCKY MOUNTAIN REGION. Pror. HAtt, in the Report of Stansbury’s Expedition to the Great Salt Lake, furnishes some notes on the Geology and Palzontology of a part of the Rocky Mountain Region, from specimens collected in the course of the Expedition. The first specimens furnished are from the west side of the Missouri River, near and above Fort Leavenworth (39° 21! N., 94° 44! W.) They are all from limestone of the Carboniferous period, and appar- ently from the upper of the two great limestones of this period in the West. The most conspicuous fossils are Productus and Terrebratula. The route from the Missouri westward, shows a continuation of this limestone as far as the Big Blue river. Here it disappears, and is soon succeeded by strata of the Cretaceous age, which extends for a consid- erable distance on the route. Among the cretaceous fossils are a species of Pholadomya, and the Incceranaus, which is so abundant in numerous localities in this region. It would appear that the character of the country from near Fort Kearney to near Fort Laramie is uniform, and no deposites of older date than the Tertiary were observed. Of the specimens collected, there is but a single individual indicating the character of a marine formation. From the condition of the bones it may even be ques- tioned, whether the deposit containing them is not of post tertiary age. . The specimens from the vicinity of Fort Laramie are all from lime- stone of the carboniferous period. Some of the fossils are identical with species collected between the Missouri and the Big Blue, and we ‘an only suppose, from the great similarity of the specimens, that it is a continuation of the same formation. The specimens collected two days’ march north-west of Fort Laramie, (105° W..,) are a feldspathic granite with little quartz or mica. The rocks in this locality are doubtless of metamorphic origin, probably rocks of the Silurian age. The specimens collected three days’ march in advance of this place, (105° 25’ W.,) are shaly sandstones and thinly laminated sandstones containing fossils. These beds are recorded as dipping at the rate of 15° to the N. E., and are probably Devonian. ‘The specimens col- lected at 105° 50! W., are precisely like those collected at Fort Lara- mie and contain the same species of fossils; red and gray sandstones were also seen here. On the following day, (near 106° W..,) is recorded a bed of coal, three or four feet thick, with Sigellaria and Calamites. The specimens collected here are those of bituminous coal, and soft shale, without any well marked vegetable remains. From the proximity of limestone of the age of the coals, and the records ot sigillaria and calamites occurring in the same connection, it may be 282 ANNUAL OF SCIENTIFIC DISCOVERY. resumed that this coal belongs to the true coal measures ; and this locality is probably an exposure indicating the existence of a great basin. This point itself, and the surrounding country are well worthy of a more extended examination, since the discovery of workable beds of coal in this region would be a matter of national importance. From the Wind River Mountain to Fort Bridget, (in 41° 18! N., 110° 32! W.,) the collections are all marine tertiary, including many speci- mens of nautilus and other marine shells. West of Fort Hall are chert and limestone of the carboniferous period. The specimens collected in the islands and shores of the Great Salt Lake, are sufficient to give a very good idea of the general geological features. The specimens are of metamorphic rocks, consisting of tal- cose and mica slates, hornblende rocks, and a few specimens of granitic and syenitic character. From the facts in my possession, it would appear that these metamorphic rocks are distinctly stratified and highly inclined, but do not attain any great elevation. The direction of the ranges, corresponding to that of the elevating forces, appears nearly to conform to north by west, and south by east. From the form of the lake and the different localities at which rocks of this character occur, we may infer that there were two lines of elevation, corres- ponding with the divisions of the lake. The more elevated portions of the lake shore, and the mountain ranges consist of carboniferous limestone. In some localities this limestone is partially altered, losing its granular character, and becoming sub-crystalline, or threaded by numerous veins of calcareous spar. In most localities the limestone abounds in fossils, particularly corals of the Cyathophillide. It will be seen from these facts that we have very satisfactory infor- mation that the limestone of the carboniferous period is widely distrib- uted in the region around the Great Salt Lake. Its position relative to the coal bed on the north fork of Platte River has not been determined ; but since no beds of coal have been observed on the slopes of the mountains in the region of the Salt Lake, we are left to infer that the coal is to be sought (as elsewhere) above the limestone. Since the existence of coal is proved at one point (admitting the evi- dence in favor of its age being that of the carboniferous period,) we are warranted that it once existed over a much wider area, and can be, sought with success in the proper situations. The importance of coal in that distant region cannot be too highly estimated, and the geo- graphical position and extent of the beds, should be one of the first points ascertained in thelocation of any route of communication between the east and the west. RESEARCHES IN NEW ZEALAND. ACCORDING to recent accounts from this interesting country, true palzeozoic coal has been discovered in the north part of the Middle Island. The accounts are too vague to be entirely decisive of the important question, whether in those remotest masses of dry land, remains of the ancient carboniferous floras are buried. Fossils are GEOLOGY. 283 stated to have been found in a white, fine sandstone grit, but their nature is not specified, except that remains of some kinds of Pecop- teris and Sphenophyllum were mentioned, but the species are not named. In the south and south-west regions of the Middle Island, Mr. Wal- ter Mantell, in an arduous exploration for three months, as government Surveyor in the almost uninhabited and dreary tracts of that country, _ kept up an active search for the rare indigenous birds, and for fossils; but with the exception of a large parrot, believed to be unknown to naturalists, no additions were made to the fauna of New Zealand. A diligent hunt for vestiges of the Moas, and for a live specimen of Notornis, was unattended with success. The last accounts from Mr. Mantell stated that the servants he had sent out to the localities which native traditions pointed out as the habitat of the Notornis, had returned birdless, and reported that the wild dogs occupied the country to such a degree, that it was hopeless to expect the wingless birds could escape. The stuffed specimen of Notornis in Dr. Mantell’s possession (in London,) bids fair, therefore, like the last of the Dodos, to be the sole representative of its race. MINNESOTA SALT REGION. PROBABLY there is not aricher salt region on the face of the earth, than the one in Minnesota. The territory is generally supposed to be valuable for its agricultural resources alone ; nothing, however, can be more erroneous. ‘True, its natural agricultural wealth is probably second to nene in the Mississippi valley, but its mineral wealth is not less extensive and valuable. Among the latter, its salt stands pre- eminent. The region lies between 47° and 49° north latitude, and 97° and 99° west longitude. Its exact locality was ascertained and defined by an expedition sent out from Fort Snelling, by Major Long, in 1822-3. A description of that salt region, together with its local- ity, will be found in the Topographical department at Washington. Our first information of that salt yegion was from a soldier in the expedition. He says that they had been travelling for several days over a vast rolling plain, with no trees or water; the troops and horses were almost famishing with thirst, when they came suddenly upon the shore of a beautiful lake, about half a mile in diameter, sunk down deep in the plain. It resembles more a vast sink hole. From the height above the waters a vast snow bank appeared to line its shore, but upon examination it proved to be an incrustation of salt as pure and as white as snow. The waters of the lake were like the strongest brine. So strong was it that one bathing in it, upon coming out, in a few minutes would be covered with the white crystallization of salt. If this salt region be as rich as it is supposed to be, a railroad pro- jected into it would prove to be the best stock in the country. There are mines of undeyeloped wealth more extensive, more durable, and more important than all the gold regions beyond the Rocky Mountains. Weare informed also, that a very short distance below the surface the 25 284 ANNUAL OF SCIENTIFIC DISCOVERY. pure rock salt lies in a strata like coal or lime rock. We hope the attention of the public and the Government will be turned to the subject. There is a region lying in our immediate neighborhood, almost unknown, containing more intrinsic wealth than any State in the Union, and which would yield an annual income probably equal- ling the entire revenue of the country. — St. Louis Union. SALT LAKE OF UTAH. Lr. STANsBuRY in his report of the “ Expedition to the Valley of the Salt Lake” says: — No one, without witnessing it, can form any idea of the buoyant properties of this singular water. A man may float, stretched at full length upon his back, having his head and neck, both his legs to the knee, and both arms to the elbow, entirely out of the water. Ifa sitting position be assumed, with the arms extended to preserve the equilibrium, the shoulders will remain above the surface.. The water is, nevertheless, extremely difficult to swim in, on account of the constant tendency of the lower extremities to rise above it. The brine, too, is so strong, that the least particle of it getting into the eyes produces the most acute pain, and if accidentally swallowed rapid strangulation must ensue. I doubt whether the most expert swimmer could long preserve himself from drowning, if exposed to the action of a rough sea. Upon one occasion a man of our party fell overboard into the lake, and, although a good swimmer, the sudden immersion caused him to take in a few mouthfuls of water before rising to the surface. The effect was a violent paroxysm of strangling and vomiting, and the man was unfit for duty for a day or two afterwards. He would inevit- ably have been drowned, had he not received immediate assistance. Af- ter bathing it is necessary to wash the skin with fresh water, to prevent the deposition of salt arising from evaporation of the brine. Yet a bath in the water is delightfully refreshing and invigorating. The analy- sis of this water by Dr. L. D. Gale, has shown that it contains rather more than 20 per cent. of pure chJoride of sodium, and not more than 2 per cent. of other salts, forming one of the purest and most concen- trated brines known in the world. Its specific gravity was 1.17, but this will slightly vary with the seasons, being doubtless affected by the immense floods of fresh water which come rushing down into it from the mountains in the spring, caused by the melting of the snows in the gorges. The ancient extent of the lake must have been far greater than its present limits indicate. As many as thirteen distinct marks of ancient levels, successive terraces formed by ancient beaches, the highest as much as two hundred feet above the plain, were count- ed in one place. These appearances, comparable with the famous “ parallel roads” of Glenroy, in Scotland, would lead to the inference that the Great Salt Lake was formerly vastly more extensive, stretch- ing for hundreds of miles, studded with huge island, now forming ~the isolated mountains that rise amid the surrounding plains. The immense miry flats, consisting of soft mud, traversed by rills of salt GEOLOGY. 285 and sulphurous water, that bound its western shores, would them- selves, if submerged for a few feet, convert the lake into a far-extend- ing inland sea. At present they glisten with salt-crystals, whose brilliant glare is interrupted occassionally by oases of artemisa and greasewood. The two valleys that lie at the southern end of the lake are the only parts of its shores adapted for human habitation. Although not directly stated, several facts are given, in the report ot the expedition which seem to imply that there are no fish in the lake itself. A curious feature in its zoology is the immense accumulation on its shores of the larva-cases and other exuvie of dipterous insects, prebably preserved in such quantities through the peculiar qualities of the water. No mention is made of molluscous animals or their shells. The mammals collected from the neighborhood are stated to belong to the Rocky Mountain series. The most interesting is the great- tailed fox, Vulpes Marcrourus, described for the first time. Several interesting new plants were gathered. The difficulty of finding fresh water around its shores, the necessity of carrying with them all their previsions, the barren and savage character of a great part of the region traversed, rendered the survey unusually arduous and pro- tracted, and would have proved fatal to its progress had not the climate been one of exceeding salubrity, so that, with all their trials and fatigues, the members of the exploring party enjoyed uninter- rupted good health. . EARTHQUAKES OF 1852. Tue following is a record of the various earthquake phenomena which we find reported through different sources, as having occurred during the year 1852.—Editor. January 10. In Massachusetts. In this imstance, which has not been generally noticed, the shock was sensibly felt throughout the whole length of the State, from New Bedford to Springfield, on the Connec- ticut River. Shock, very slight. Jan. 17. Slight shock at Galveston, Texas. Jan. 26. Throughout the State of Mississippi, and in the south of France. At Bordeaux, the shocks were very severe, though momen- tary. On the same day, also at Messina, Sicily, and at this latter place throughout the month, shecks were frequent. March 31. Throughout northern India. April. 10. At St. Michaels, Azores, at 2 A. M., producing great devastation. April 14. At the Sandwich Islands. Severe shocks, followed on the fifteenth by a volcanic eruption. April 27. At Valparaiso. April 28. At the Azores. April 29. Smart shocks experienced in Maryland, Virginia and North Carolina. May 9. In South Wales. 286 ANNUAL OF SCIENTIFIC DISCOVERY. May 11. At Apalachicola, Florida. May 26. In the province of Shookingah, China ; 300 persons killed, and property to a great amount destroyed. June 19. In Berne and Friburg, and throughout Switzerland gen- erally. June 20. At the Bermudas. June 30. In New Hampshire and Vermont, slight shock. July 7. At Jamaica, several severe shocks, continuing three min- utes, and causing much damage. July 17. At St. Jago de Cuba. This shock was also felt at sea by the ship Tropic, 70 miles west of Jamaica. August 1. At Groton, Connecticut. ‘August 2. At Bathurst, Canada. Shock sufficient to break glass, etc. etc. August 4. In Northern India. August 14. At Spezzio, Italy. August 17 and 18. At Port au Prince; severe shocks. Aucust 18. Throughout St. Domingo. August 20. Great “earthquake in St. Jago de Cuba. This earth- quake was one of great violence and occasioned great loss of property and life. The same day occurred the great eruption of Mount Etna. August 21. At Jamaica. Also at Ezeroum, Asia Minor. Loss, 306 houses and 17 lives. August 25. At Augusta, Georgia, and in various parts of the United States. August 27. In Turkey. Aueust 28. At St. Domingo ; also at St. Jago de Cuba. August —. In the province of Kalsuch, China; a terrific earth- uake. : September 16 to 21. At the Phillipine Islands; severe and repeat- ed shocks, causing great damage and alarm. These earthquakes were also felt at sea for a great distance. October 1. At Malaga, Spain. October 9. South of England; slight shock. October 11 and 12. At Manilla and the Phillpine iaexice severe. October 15. In the North of Hungary; a series of shocks. October 22. At St. Lucia. November 8. In Sicily ; particularly at Reggio. November 19. At Valparaiso, Chili. November 22. At Lima, Peru. November 26. At St. Jago de Cuba; severe. December 4. Throughout Mexico. December 9. At Acapulco, and the whole west coast of Central America ; shocks in many places severe, and accompanied with vol- canic eruptions. December 17. At St. Jago de Cuba. GEOLOGY 287 GREAT ERUPTION OF MOUNT ETNA. Mount Etna, which for some years has remained dormant, experi- enced a very violent and long continued eruption during the past year. The eruption commenced on the 20th of August, the same day on which the terrific earthquake of St. Jago de Cuba occurred, and continued with greater or less activity until the 17th of November following. The indications of its approaching activity were, as usual, the drying up of wells in the neighborhood, the duration of most dense clouds of white smoke which rose like a vast pine tree, hollow rumbling sounds, and three violent shocks, as of an earthquake. Shortly after, towards the east, two new mouths were opened in the site which is known under the name of the Valle del Leone. At first only clouds of a very fine ash were thrown up; which completely covered all the land near the mountain, and quantities of which being taken up still higher by an impetuous wind, were carried far off into the sea. These, however, were but a small instalment of what was to follow. Immediately after- wards an immense body of lava was vomited forth ; which precipitating itself down the mountain with the violence of a torrent, divided into three streams. One of these flowed in the direction of Zaffarana — another in the direction of the Comune of Giarra, more particularly on an estate called Milo, near Giarra. To give an idea of the immense quantity of liquid fire that was thrown out, official state- ments describe this river of lava as being two miles in breadth at the greatest, and ten palms in depth, whilst the rapidity with which it moved was such as to cover in one hour a space of not less than 160 palms in extent. It seems, that in a very short time, in consequence of the increasing strength of the eruption, the new mouths were broken up so as to form one only; frem which masses of rock and cinder were thrown into the air to a great height, and falling on the wide extent of country round, carried with them the most fearful ruin. The utmost intensity of the eruption perhaps took place on the 25th, 29th, and 30th of August, and on the 4th of September. The rumbling subterraneous thunders were then incessant, as was also the shaking of the ground. To this add the clouds of smoke and flame which rested like an imperial diadem on the summit—and we may form some faint idea of the magnificent and awful spectacle which Etna on those days presented. The accidents of the land, and the greater or less quantity of materi- als thrown out of the mountain, produced a great variety in the course of the streams of lava. Sometimes they appeared to drag their slow length along, sometimes to precipitate themselves with threaten- ing violence, expanding widely till they covered vast spaces of land, or twisting and twining into the most capricious sinuosities, and accord- ing to the varying rapidity of their movements varying their depth and extent. On the 22d of August the running lava is stated to have been 18 palms deep, whilst on the 30th it had mcreased to 240 palms in some places. On the 31st of August the eruption still continued 25* 288 ANNUAL OF SCIENTIFIC DISCOVERY. very violent. The lava advancing on the village of Ballo, completely swallowed up several houses on that day, as also the road which divides it from Zaffarana. During the next two days it diminished in power, and hopes were entertained that one or two neighboring villages might be saved. On the 4th of September, however, it again burst forth with unusual fury, thundering, shaking, and vomiting forth new matter in the direction of Milo. Thus the mountain continued its activity with greater or less violence throughout the whole month. If the lava flowed in smaller quantity, denser clouds of smoke arose, and a greater quantity of ashes and sand were thrown out. During the month of October much activity was manifested, though greater hopes were entertained that the eruptions might soon cease. A correspondent of the London Athenzeum says, the damage which has been inflicted is difficult to estimate, for the course of the lava lay through a country of extraordinary fertility, and abounding in every species of vegetation. Had nothing but ashes been thrown out, all the saints in the callender would have been /esteggiati, for nothing 1s so ropuctive of fertility as volcanic ashes, but what can make any impression on large masses of indurated lava but the slow operation of the elements, or what root for centuries will ever be able to pierce it except the prickly pear ? An extraordinary feature of the eruption was the vomiting forth from the crater of a large quantity of sal ammoniac, rendering the air so impure as to threaten the lives of seamen on the coast. Vessels in the vicinity of the mountain were covered with cinders, and ashes and volcanic dust were wafted by the wind as far as Malta. GREAT VOLCANIC ERUPTION AT THE SANDWICH ISLANDS. ONE of the greatest volcanic eruptions on record, —that of the voleano of Mauna Loa, at the Sandwich Isiands, took place in Feb- ruary, 1852, commencing on the 17th of the month. The eruption appears to have been scmewhat unexpected, and was not heralded by any of the accustomed premonitory signs. ‘Phe current seems to have broken out through an old fissure, about one-third down the side of Mauna Loa, on the north-west side, and not from the old crater on the summit, called Mokuoweoweo. ‘The altitude of the eruption was about 10,000 feet above the level of the sea, and at a distance from the Bay of Hilo, of about 60 miles. A writer who witnessed the eruption from Hilo, thus describes some features of it: “ By an accurate measurement of the enormous jet of glowing lava, where it first broke forth on the side of Mauna Loa, it was ascertained to be five hundred feet high! This was upon the supposition that it was thirty miles distant. We are of the opinion that it was a ereater distance, say from forty to sixty miles. With a glass, the play of this jet, at night, was distinctly observed, and a more sublime sight can scarcely be imagined. A column of molten lava, glowing with the most intense heat, and projecting into the air to a distance of five hun- dred feet, was a sight so rare and at the same time so awfully grand, GEOLOGY. 289 as to excite the most lively feelings of awe and admiration, even when viewed at a distance of forty or fifty miles. How much more Aawe-in- spiring would it have been at a distance of one or two miles, where the sounds accompanying such an eruption could have been heard. The fall of such a column would doubtless cause the earth to tremble; and the roar of the rushing mass would have been like the mighty waves of the ocean beating upon a rock-bound coast. The diameter of this jet is supposed to be over one hundred feet, and this we can easily believe, when we reflect that from it proceeded the river of lava that flowed off from it toward the sea. In some places this river is a mile wide, and in others more contracted. At some points it has filled up ravmes one hundred, two hundred, and three hundred feet in depth, and still it flowed on.” Mr. Coan, a missionary, residing at Hilo furnishes another graphic description. He says: “ On the 17th instant, at twenty minutes past 3, A. M., a small beacon light appeared on the summit of Mauna Loa. This light increased until it looked like a rising moon. In half an hour, brilliant columns of lava shot up against the heavens, and a gen- eral burst of blood red fusion poured out of the same orifice appar- ently, which disgorged such awful floods in 1843. We were awakened at about 4 o’clock, and saw a glare of light streaming through our windows. Our first thought was that some building near us was on fire, but on rising we soon perceived that the whole summit of the moun- tain was irradiated, and that a vast furnace was there glaring with vehement heat. The molten flood rolled down the side of the moun- tain so rapidly that in two hours we judged its progress to have been fifteen miles, the whole lava glaring with great brilliancy. This flow continued through the day, but with decreasing energy. It became sluggish at night, and the next day, or after twenty-four hours, no traces of it were visible from the station; no smoke by day and no fire by night. At six o’clock, A. M., on the 20th, yesterday, we per- ceived fire issuing from the side of the mountain toward Hilo, and about half way down the mount. This lateral crater soon became intensively active, pouring out a gory flood which soon reached the base of the mount. At first the stream shot directly down towards Hilo ; but meeting some obstacle near the foot of the mount its direc- tion was changed to the north, and it is still flowing towards Mauna Loa. A vast area between the mountains is already filled with fire, and the scene by night is one of terrible sublimity. The red hot lava still rolls out of the side of the mountain in awful floods. It seems as if the bowels of Pluto were being disgorged. While I write, our whole atmosphere is filled with lurid smoke, through which the sun looks down upon us with a yellow and baleful light. The horizon is hung in murky drapery; detonations, like distant thunder, are heard from the mountain, and capilliform filaceous vitrifactions are filling our streets.” On the 6th of March the lava was still flowing, and the light emitted by the stream was so intense, that small objects could be most clearly seen at midnight in Hilo. e . 290 ANNUAL OF SCIENTIFIC DISCOVERY. It must be noticed as one of the incidents of this eruption, that the most striking display of the Aurora, witnessed in the United States during the year 1852, took place on the 20th of February, dur- ing the progress of this great eruption. A letter from Mr. Fuller published in Silliman’s Journal, Sep- tember, gives the following picture of the intensity of the eruption. There played a fountain of liquid fire of such dimensions and such awful sublimity, shaking the earth with such a constant and deafening roar, that no picture can give any adequate conception of its grandeur. A few figures may assist the imagination in its attempts to paint the scene. I made the following calculations, after careful observations during nearly twenty-four hours, from different points within a mile of the crater. The diameter of the crater, which has been entirely formed by this eruption is about 1,000 feet, its height from 100 to 150. One part of the crater was raised fifty feet during our presence on the spot. The height of the column of red hot liquid lava, constantly sustained above the crater, varied from 200 to 700 feet, seldom falling below 300. Its diameter was from 100 to 300 feet, rarely perhaps reaching 400 feet. The motions of this immense jet of fire were beauti- ful in the extreme, far surpassing all the possible beauties of any water fountain which can be conceived; constantly varying in form, in dimensions, in color and intensity ; sometimes shooting up and taper- ing off like a symmetrical Gothic spire, 700 feet high; then rising in one grand mass, 300 feet in diameter, and varied on the top and sides by points and jets, like the ornaments of Gothic architecture. The New Yorker, as he gazes on the spire of Trinity Church, can imagine its dimensions increased three-fold, and its substance converted into red hot lava, in constant agitation, may obtain a tolerable idea of one aspect of this terrific fire fountain. But he should stand at the foot of Niagara Falls, or on the rocky shore of the Atlantic when the sea is lashed by a tempest, in order to get the most terrific element in this sublime composition of the great artist. For you may easily conjecture that the dynamical force necessary to raise 200,000 to 500,000 tons of lava at once into the air, would not be silent in its operations. A NEW MINERAL AND EARTH. Dr. D. D. Owen, U S. Geologist, gives the following communi- cation respecting a supposed new mineral and a new earth, discovered _ by him, in Silliman’s Journal, May, 1852. While examining, in the summer of 1848, the north shore of Lake Superior, situated in Minnesota, particularly in the vicinity of Baptism River, I observed a peculiar, soft green mineral diffused in the amygdaloidal traps. ‘Though not in large masses, the mineral was so abundantly disseminated in some of these rocks, that the least blow of the hammer indented the rock, and left a whitish-green mark from the easily crushed particles of the soft green mineral in question. Chemical analysis of the mineral showed it to be essentially a hydrated silicate of magnesia, and what appeared to be a new earth, interme- GEOLOGY. 991 diate in its properties between magnesia and manganese. The color of the mineral when pure, is of a pale yellowish-green, consistence and hardness about that of wax. Specific gravity, 2.548. It has not been found crystallized. Treated with hydrochloric acid, chlorine is evolved, and the greater part of the constituents, except silica, dissolved. About 10 per cent. of the mineral is made up of the supposed new earth, which when separated has the following properties and reac- tions with re-agents:—It dissolves either in hydrochloric or nitric acid evolving chlorine from the former acid. The solution in hydro- ehlorie acid, when concentrated, has a beautiful pea-green color, and the salt crystallizes either of a slightly paler green, or a light chrome yellow, depending on the degree of heat at which the evaporation is completed. The peculiar color of its saits, together with the appear- ance of the residue left in the analytical process after treating with caustic potash to separate the alumina, was what first attracted my attention to this earth. When separated. and still slightly contamin- ated with magnesia, the earth has a pale, flesh color, not unlike yttria. When freed from magnesia, it has more the appearance of powdered dried albumen. The earth differs from alumina and glucina in being insoluble in caustic potash. From magnesia in producing colored salts ; in being only slightly soluble in ammoniacal salts ; in the pecu- liar vesicular character of the precipitate with phosphate of soda; in being precipitated with oxalate of ammonia. From yttria it differs in not giving a precipitate with oxalic acid in slightly acid solutions ; in being precipitated by succinate of ammonia, even before the solu- tion is quite neutral, which prevents this re-agent being applied to separate iron from it, as is recommended by Berzelius for separating oxide of iron from yttria. It differs from zirconium in being soluble in nitric and muriatic acids after ignition. From cerium, in not turn- ing a brick-red after ignition, and in the color of its salts which are not amethystine, but shades of green and yellow, except the nitrate, which is almost colorless. The nitrate crystallizes in prisms, which seem to be right-rhombic. Its salts, like the corresponding ones of magnesia seem to be deliquescent. From the quantity of chlorine evolved during the solution of the mineral and earth in hydrochloric acid, it appears that this earth must exist in at least two degrees of oxidation ; the chlorine being disengaged, just as in the case of the solution of the higher oxides of manganese when treated with hydro- chloric acid. From these and other consideration Dr. Owen con- cludes, that the earth contained in the mineral, which is nearly inso- luble in sal-ammoniac, insoluble in caustic potassa, and producing the above reactions with re-agents, and green and yellow salts, must be either a new earth or else a modification of some known earth not previously known. The name Thalium is proposed for the base of this earth, Thalio for the earth itself, aud Thalite for the mineral from which it is extracted. The new metal Donarium,* the discovery of which was announced last year by Bergemann, proves to be nothing but Thorina. * See Annual of Scientific Discovery, 1852, p 176. 292, ANNUAL OF SCIENTIFIC DISCOVERY. OBSERVATIONS ON THE DIAMOND. Sir Davin Brewster at the Belfast meeting of the British Asso- ciation stated that his opinion had been requested by Prince Albert respecting different forms into which it was proposed to reduce the Koh-i-noor diamond, in order to make it an ornamental gem. In the state in which it then was, it exhibited an inferior dis- play of colors to its glass model, and it was only by surrounding it with a number of vivid lights that its colored refractions could be developed. Having had occasion to observe some remarkable phe- nomena in small portions of diamond, I was desirous of examining so large a mass of diamond as the Koh-i-noor before it was reduced in size, and covered with facets which would not permit it to be exam- ined. -His Royal Highness readily granted my request, and I had thus an oppportunity of submitting it to the scrutiny of polarized light. In place of producing no action upon this species of light, as might have been expected from its octahedral structure, it exhibited streaks of polarized tints, generally parallel to one another, but in some places of an irregular form, and rising to the yellow of the jirst order of colors. These tints and portions of polarized light were exactly the same as those which I had Jong ago found in many other diamonds. In placing the Koh-i-noor under a microscope of consid-_ erable power, I observed in it, and also in each of the two small dia- monds which accompanied it, several minute and irregular cavities, surrounded with sectors of polarized light, which could only have been produced by the expansive action of a compressed gas, or fluid, that had existed in the cavities when the diamond was in a soft state. In an external cavity, shown in the model, and which had been used for fixing the gold setting, I observed, with common light, a portion of yellow light, indicating a yellow substance. Mr. Garrard and others considered it as gold rubbed off the gold setting; but as gold is never yellow by transmitted light, I considered the color as produced by a yellow solid substance of unknown origin. Sir De la Beche having suggested to me that it would be desirable to make a general examina- tion of the principal diamonds in London, I went next day tothe * British Museum, and found there an interesting specimen, which threw some light on the yellow solid to whieh I have referred. This speci- men was a piece of colorless diamond, uncut, and without any crys- talline faces, about three or four tenths of an inch broad, and about the twelfth of an inch thick, and on its surface there lay a crystal of yellow diamond, with the four planes of semi-octahedron. This singu- lar fact was illustrated by a large model placed beside it. Upon examining the original, I noticed a pretty large cavity in the thickness of the specimen, with the extremity of which the yellow octahedron was connected ; and finding a portion of amorphous yellow diamond in the other end of the cavity, I had no doubt that the yellow crystal had emerged, in a fluid state, from the cavity when it was accidentally opened, and had immediately crystallized on the surface of cleavage. Iam well aware that such an opinion makes a good demand upon the GEOLOGY. 293 faith of the mineralogist ; but to those who have seen, as I have done, the contents of fluid cavities in crystals solidifying and even crystal- lizing on the face of cleavage, while another portion of the con- tents of the cavity escaped in gas—to those who have seen in topaz cavities numbers of regularly formed crystals, some of which, after being fused by heat, instantly re-crystallized—the conclusion I have drawn will be stripped of much of its apparent extravagance. In examining a number of diamonds in the Museum of the East India Company, and about forty or fifty in the possession of Messrs. Hunt & Roskill, I found many containing large and irregular cavities of the most fantastic shapes, and all of them surrounded with irregular patches of polarized light, of high tint, produced undoubtedly, by a pressure from within the cavities, and modified by their form. Among these specimens I found one or two black diamonds, not black from a dark coloring matter, like that in smoky quartz, but black from the immense number of cavities which they contam. Tavernier has described a large and curious diamond which throws some light on the subject of this notice. It contained, in its very centre, a large black cavity. The diamond merchants refused to purchase it. At last a Dutchman bought it, and, by cutting it in two, obtained two very fine diamonds. The black cavity through which he cut was found to con- tain eight or nine carats of what Tavernier calls black vegetable mud! Mr. Tennant, the celebrated geologist, stated that at the last meeting of the British Association, Dr. Beke read a paper “ On the Diamond Slab supposed to have been cut from Koh-i-noor.” He stated: — “ At the capture of Coochan there was found among the jewels of the harem of Reeza Kooli Khan, the chief of that place, a large diamond slab, supposed to have been cut from one side of the Koh-i-noor, the great Indian diamond now in the possession of Her Majesty. It weighed about 130 carats, showed the marks of cutting on the flat and largest side, and appeared to correspond in size with the Koh-i-noor.” Prof. Tennant was induced to record his opinion of the probability of this being correct. He had made models in fluor spar, and afterwards broken them, and obtained specimens which would correspond in cleavage, weight, and size with the Koh-i-noor. By this means he was enabled to include the piece described by Dr. Beke, and probably the large Russian diamond, as forming altogether but portions of one large diamond. The diamond belongs to the tesselar crystalline system ; it yields readily to cleavage in four directions, parallel to the planes of the regular octahedron. Two of the largest planes of the Koh-i- noor, when exhibited in the Crystal Palace, were cleavage planes — one of them had not been polished. This proved the specimen to be not a third of the weight of the original crystal, which he believed to have been a rhombic dodecahedron; and if slightly elongated, which is a common form of the diamond, would agree with Tavernier’s description of it, bearing some resemblance to an egg. Referring to the diamonds procured in the Brazils, he related a fact which, he said, was told to him by a gentleman from Brazil. A slave in that country was one day wading in a river in search of the precious gems to be 294 ANNUAL OF SCIENTIFIC DISCOVERY. found imbedded in the strand, when he struck his crow bar in a spot which surprised him by its hollow sound. He repeated its blows, and soon struck the iron through a crust of siliceous particles cemented together by oxide of iron. On removing the concrete mass, the slave discovered a bed of diamonds, which were afterwards disposed of for £300,000. Such an immense number of diamonds being thrown upon market, so overstocked it that nearly all the dealers became bankrupt, and upon the diamonds being introduced into England, the glut was so great that the results to the trade were equally disastrous, only three English houses being able to stand up against it. One of these persons was a gentleman in Leadenhall street, who was so largely engaged in the trade, that he had actually shown him (Mr. Tennant) a peck full of diamonds. A London journal furnishes the following account of the re-cutting of the famous Koh-i-noor diamond : — This precious stone, which was the synosure of the World’s Exhi- bition of 1851, attracted, from the multitudes who last year gazed upon it, expressions of disappointment at the somewhat dim radiance of its lustre, not fulfilling the expectations entertained from the high flown descriptions which had been given of the Mountain Light —a title which many beholders held to be a misnomer. ‘This disappoint- ment having come to the knowledge of those into whose possession it had passed, suggested the desirability, if practical, of effecting such altera- tion in the shape of the diamond as would remove the admitted defects of the oriental cutting, to which it had been subjected by its original proprietors. With this view, the opinions of various scientific gentle- men were taken, and some doubts having been expressed as to the possibility of cutting the gem without incurring, a great risk of its destruction, Professor Tennant and Mr. Mitchell were especially requested to examine and report upon the practicability of the sug- gestedimprovement. These scientific gentlemen accordingly prepared a report, wherein they admitted the improvement which the proposed alteration in shape would effect upon the Koh-i-noor, but expressed fears that any lateral cutting would endanger its integrity. It was then determined to submit the matter to the opinions of practical lapidaries; and with that view the Crown jewellers, Messrs. Garrard, were instructed to obtain a report from competent persons versed in diamond cutting. Those gentlemen thereupon consulted Messrs. M. & E. Coster, of Amsterdam, (the diamond cutting trade having been entirely lost to this country,) who, while admitting the accuracy of the fears expressed in the report of Professor Tennant and Mr. Mitchell, nevertheless were of opinion that the dangers were not so formidable as to prevent the intended operation from being safely effected, pro- vided the necessary skill of superior artists was employed. ‘This opin- ion was sufficiently encouraging to induce an order for the preparation of the requisite machinery to be erected on the premises of Messrs. Garrard, and accordingly a smail steam-engine of from two to four- horse power was erected, and put in operation. As this is the largest diamond which has been cut in Europe for a long period, the com- GEOLOGY. | 295 mencement of the work was personally undertaken by the Duke of Wellington, in the fellowing manner: — The Koh-i-noor having been embedded in lead, with the exception of one small salient angle intended to be first submitted to the cutting operation, his Grace placed the gem upon the soaife—an horizontal wheel revolving with almost incalculable velocity — whereby the exposed angle was removed by the friction, and the first facet of the new cutting was effected. This, the first step in the operation, forms but a small item of progress, as it is expected that the work, under the hands of the two Dutch artists to whom it has been entrusted, will occupy a period of some months, it being, as may be conceived, a work of great deli- cacy, involving an equal amount of skill and care. The Koh-i-noor is intended to be converted into an oval brilliant, and the two smaller diamonds which accompany it, are to be similarly treated as pendants. The present weight of the principal gem is 186 carats, and the pro- cess now in course of progress will not, it is anticipated, diminish in any material degree its weight, while it will largely increase its value, and develope its beauty. Some conversation has occurred respecting the doubts imputed to have been cast by Sir D. Brewster upon the iden- tity of the Koh-i-noor; but the general opinion amongst those best acquainted with the subject appeared to be, that it was impossible for Dhuleep Singh to have palmed off a fictitious diamond, when his con- stantly wearing it on state occasions must have rendered it perfectly familiar to thousands who would instantly have detected any attempt at substitution. ‘The more probable assumption was stated to be, that the weight of the Mountain of Light had been more Orientale some- what exaggerated. The business of cutting diamonds is now chiefly confined to Amsterdam, and is thus described in a late number of the London News :— It was on a Sunday, in the early part of 1847, that, being at Amsterdam, we wandered out from our hotel on a chance excursion through the town. Before we had gone far the noise of machinery arrested our attention, and, on making inquiries, we found that it pro- ceeded from the celebrated diamond-cutting establishment of the place. Let not the reader picture to himself a clean, neat, well-look- ing establishment, such as one of our paper or cotton mills, but as an old lumbering shed, in which, impelled by the labor of four or five sorry horses, revolved a horizontal wheel. This was the only source of motion by which the grinding machinery was kept at work; and its primitive nature ina century when the steam-engine 1s made to spin cotton, grind corn, and weave cloth, could not but suggest to the looker-on how remote from ordinary wealth — wealth selt-developing and expansive — was the conventional wealth represented by the diamond trade. The operation of cutting is performed in several dilap- idated rooms up stairs. There are seen in rapid revolution some scores of horizontal metal wheels, each about a foot and a half in diameter. Their surfaces being smeared from time to time with a mixture of diamond dust and olive oil, and set in revolution, the dia- 26 296 ANNUAL OF SCIENTIFIC DISCOVERY. mond to be ground is brought in contact with the revolving metallic surface. It need hardly be said, that the task of holding a diamond to be ground firmly against the revolving wheel for so long a period of time as is necessary, would be impossible. Continuous pressure is effected in another and very simple manner: the diamonds are imbedded, all except the parts to be ground, in a heavy mass of very fusible solder shaped like a hammer, the handle of which being fixed as to horizontal motion, but free by means of a hinge to move up and down, and the face of the hammer being brought flat upon the side of the horizontal wheel, the operation of grinding, cutting as it is _ called, proceeds without further trouble. ARGENTIFEROUS LEAD MINES OF MIDDLETOWN, CONN. Axsout two miles below the city of Middletown, Connecticut, on the banks of the Connecticut river, are several excavations, some 18 to 30 feet deep, made during the Revolutionary war by a company, for the purpose of procuring lead ore, so as to supply the American troops with lead. It was worked for some time, the ore smelted, and the lead separated from the rock in which it was found imbedded. Not being found sufficiently profitable to make it an object, the work- ing of the mines was discontinued. A recent examination having been made of these old workings, a considerable quantity of silver was found associated with the lead, and the persons interested became satisfied, that it could be worked profitably, and that the quantity of silver would fully pay the whole expenses of working the mines, leaving the large quantity of lead obtained to form the profit of the mining operations. ‘Thus far, although they have worked but a few months, with a small force, and cannot be supposed to have but tested the richness of the veins of silver—yet it is paying its way, and even more than that. Lately, some rich veins of silver ore have been discovered—and some pure native silver—the former being nearly free from the lead mixture. The ore is broken up and then fed to a mill, where it is pounded fine—the pounders, of which there are four, being operated by an overshot water wheel, which is carried by water from a dam, with a fall of some 15 or 25 feet. As fast as the ore is pounded sufliciently fine, a stream of water carries it into troughs, where it is washed. From these troughs it is taken out, and sent to New York, where the metals are separated. MINERALOGICAL NOTICES. The following mineralogical notices have been communicated to Silliman’s Journal, July, by Mr. W. 'T. Blake. Apatite—During the past winter a shaft has been sunk upon the vein of crystalline phosphate of lime at Hurdstown, Essex Co., N. Y., and large blocks of massive apatite have been raised; some of the largest of these masses weighed not less than 200 pounds, and were nearly pure apatite,—the specimens have very little color, portions of GEOLOGY. 297 the masses being translucent and nearly transparent, and resembling the “asparagus-stone” variety of the mineral. The more compact and opaque masses frequently cleave into hexagonal prisms, some of them having lateral planes three inches wide. Rhombohedrons resulting from cleavage are not uncommon. Brown Tourmaline—Beautiful transparent crystals of brown tour- maline occur disseminated in the massive and concretionary phos- phorite at the “eupyrchroite” locality, Crown-point, Essex Co., N. Y.; terminated crystals are rare, but the few found are highly modified, and are crystallographically similar to the crystals from Gouverneur, N. Y., described and figured by Rose. (See Dana’s Mineralogy, p. 136.) The color is a light clove-brown, and the crystals exhibit dichroism. Specimens cut and polished have much beauty as gems. Red Zine Oxide —Fine cabinet specimens of lamellar red zine oxide can be obtained at the zine mine, Stirling Hill, Sussex Co., N. Y. The lamellar masses are disseminated in the highly crystalline lime- stone which has frequently a delicate pink hue and translucent,— cleaving readily into large rhombohedrons; the contrast between the red zinc and the gangue adds greatly to the beauty and mineralogical value of these specimens. These distinct nodules of oxide are found at the junction of the vein of red zine ore and the limestone, but the oxide is free from any admixture with Franklinite crystals; good crystalline specimens of Franklinite are now very rare at the mine. Fluor-Spar Locality—Shawneetown, Gallatin Co., Ill, has long enjoyed a reputation among American mineralogists as a locality for fluor-spar. Having had occasion, a few months since, to visit the southern portion of Illinois, I explored this locality. It was found, however, that the fluor-spar did not occur, as reputed, at Shawnee- town, but ten to fifteen miles farther down the Ohio, and a half a mile to a mile north of the river. The fiuor occurs in the carboniferous limestone, it forms numerous veins, many of which are from ten to twenty feet in thickness. It is highly crystalline, and often very fetid; beautiful crystallized speci- mens are found in pockets in the veins, which are sometimes entirely colorless, frequently of a blue, a violet, or a pink tint, and more rarely of an emerald-green. The localities have been quite exten- sively worked for lead, which, under the form of galena, is associated with the fluor. The amount of galena is quite considerable, although no regular vein has as yet been found; it is somewhat argentiferous, yielding, on an average of several specimens examined, about four ounces of silver to the ton. The mining of these veins has devel- oped, besides some fine crystallizations of fluor, as a compact variety in which the associated galena also has the compact structure. An immense amount of a remarkably fine quality of fluor-spar could be obtained from these veins should there be a demand for it in the arts. —Com. to Silliman’s Journal by S. J. Brush. Platinum in Canada.—This metal was detected last summer, in the gold washings of the Riviere du Loup, where it is found sparingly 298 ANNUAL OF SCIENTIFIC DISCOVERY. mixed with the gold, in minute scales and grains. Associated with it there was another metal which resisted completely the action of the acid. It forthed small plates of a tin-white, generally hexagonal, and so hard as to resist steel; these characters show it to be widosmine, the native alloy of the rare metals iridium and osmium, which is found with the gold of South America, and is from its extreme hard- ness, employed “to form the points of gold ‘pens. —heport Canadian Geologists. LARGE DEPOSITE OF GRAPHITE. Ar St. Johns, N. B., near the new suspension bridge over the St. John’s river, a very extensive deposite of graphite has been opened and explored to a considerable extent. The vein, or bed as it might more properly be called, is nearly vertical, and inclosed between beds of highly metamorphic schists. It is entered near the water on the face of a precipitate cliff about seventy feet high, the walls of the lode being in the main parallel to the graphite deposite. This bed has been explor ed by a gallery or adit level over a hundred feet, and by cross cuts at right angles to this some twenty or more feet. All these are in the graphite mass, and of course the floor and roof of the levels are of the same mineral. The quartzose walls have occa- sionally approached, and in some cases masses of quartz, or schist, have been included in the graphite. The course of this deposite is about northeast and southwest, or nearly in the direction of the strike of the strata of schist. The graphite i is not of a very superior quality as a mass, though portions of it are quite pure. As yet no solid and perfectly homogenous masses have been taken out. It has a foliated structure more or less highly marked. Iron pyrites is too abundantly diffused in it to admit of its use for crucibles. The chief economical use made of it has been in facing the sand moulds for iron castings, for which purpose it is ground to a fine powder. Some of the finer parts are also used to manufacture pencils. Many hundred tons of graphite from this deposite have already been taken out since the mine was opened two years ago, and the supply may be esteemed - inexhaustible. The vein or bed re- appears on the opposite side of the St. John’s river, and on the side now opened it has been traced over amile. The position of the deposite in conformable metamorphic schists, suggests the conjecture that this deposite of graphite may represent a ‘former coal bed. LAKE SUPERIOR COPPER MINES. Tue National Intelligencer publishes a few facts to show the advan- tage of a judicious prosecution of the copper mining business. The Intelligencer says :— The mine which has thus far been the most productive is called the Boston and Pittsburg Mining Company. Work was commenced in 1848. A capital of $110, 000 was paid in, or about $18 50 per share on GEOLOGY. i 999 6,000 shares. In 1849, $60,000 was divided among the shareholders ; in 1850, $84,000; in 1851, $60,000, and in 1852, $60,000 more will be divided. In another view, shares which cost $184 have received back in dividends $34 and are worth $100 in the market. The Northwest Mining Company ranks next in value. Mining was here commenced in earnest in 1849. About $80,000 have been paid in. In 1849 the net proceeds from the sale of copper amounted to some $5,000 ; in 1850 to about $32,000; and in 1851 to something over $50,000. This company owns a large tract of mineral territory, upon which two valuable veins have been opened and a number of others discovered. The property owned by this company is of immense value, and magnificent fortunes will in a few years doubtless be realized from it. The Minnesota Mining Company is located near the Ontonogon River, some forty miles westward of the two preceding. Immense blocks of pure copper are taken from this mine. It commenced in the autumn of 1848, and has a capital paid in of some $90,000, or $300na share —there being but three thousand shares. They command $150 ih the’ market. A large dividend will, we think, be paid from the earnings this year. The gain reaped from the workings of a successful mine is free- quently 500 per cent. Shares in the Boston and Pittsburg Company, which cost $18 50, sell for $100. In the Minnesota for $30 the owner can now receive $150. The Northwest shares will probably increase 100 per cent. in value in a year. NEW METEORITES. PROFESSOR SHEPARD, of Amherst College, has recently added to his collection of meteorites a very valuable specimen, which is des- cribed as a mass of compact malleable iron weighing 178 pounds, of an elongated ovoidal form, covered with the usual indentations, and exhibiting the characteristic crystalline figures. It was discovered on the Great Lion River, in the Nemaqua Land, in South Africa, and, having beeen transported several hundred miles in wagons to the Cape of Good Hope, was shipped to London. Prof. Shepard, being fortunately in that city at the time of its arrival, immediately entered into negotiations to obtain it, and with considerable difficulty, succeed- ed. He also has another specimen from Newberry, South Carolina, weighing fifty-eight pounds. His collection of extra terrestrial sub- stances weighs more than 350 pounds, and includes two hundred specimens from more than a hundred different localities. Prof. Root in a communication to Silliman’s Journal, November, 1852, states, that a mass of malleable iron weighing nine pounds, was found last fall in digging a ditch on a farm near the free bridge on the Cayuga side of the Seneca River. It was drop shaped, about four inches in diameter and seven inches in length. When found it was coated with oxide of iron. The surface was uneven, and some of the prominent ait ta terminated by planes of octahedral crystals. It 300 ANNUAL OF SCIENTIFIC DISCOVERY. may be an interesting fact, that the locality where this iron was found is only a few miles from Waterloo, in Seneca county, where a meteorite fell in 1827, as has been stated by Prof. Shepard. GOLD DISTRICTS OF CANADA. From the recent reports of the Provincial Geologists, we derive the following facts relative to the existence and production of gold in Canada: — The auriferous district has been found by examination to spread over an area probably comprising between 3,000 and 4,000 square miles. It appears to occupy nearly the whole of that part of the Province which lies on the southeast side of the prolongation of the Green Mountains into Canada, and extends to the boundary between the Colony and the United States. Two general lines of exploration were followed, one of them up the Chaudiere and Riviere du Loup and the other from Lake Etchemin to Sherbrooke on the St. Francis. The former, running transverse to the rock ranges measur- ed about forty-five miles, and the latter with them about ninety miles. The transverse line was more closely examined than the other, and traces of the precious metal were met with at moderate intervals throughout the whole distance. ‘They were not confined to the chan- nels of the main streams merely, but those of various tributaries furnished indications sometimes for a considerable distance up. It is not supposed that the limits of the auriferous district have been ascer- tained, but that it very probably extends much farther to the north- east, and attains the valley of the river St. John, while to the south- west it is known to reach Vermont, and to be traceable at intervals through the United States, even, it is said, as far as Mexico. In its breadth, however, it does not appear to cross the range of mountains with which it runs parallel, and no traces of it have been met with on their northwestern flank. The deposite in which the gold occurs is part of an ancient drift, probably marine, and supposed to be of higher antiquity than that which occupies the valley of the St. Lawrence and some of its tributaries. In this, alluded to in various reports as tertiary and post-tertiary, the remains of whales, seals, and two species of fish,and many marine shells of those species still inhabiting the Gulf of St. Lawrence, are found. ‘These shells on the Mountain of Montreal attain a height of about 470 feet above tide level in Lake St. Peter, which is the greatest altitude known; none of the remains have yet been found in the Canadian gold drift, and as this appears in its lowest undisturbed parts to be at a height of about 500 feet above the sea, it is probable what is now exposed of it, had emerged from the ocean before the Laurentian drift was placed, while in lower levels it would be covered up by it. During the five months of the summer of 1851, the whole amount of gold collected by fifteen men at the washings on the River de Loup at its junction with the Chaudiere, was about 1,900 penny-weights. From among a few ounces of fine gold obtained, there were collected small grains both of platinum and iridosmine, the value of the GEOLOGY. | 301 former being below, and of the latter double that of gold ; almost all of this fine gold was at first of so white a color that it was considered probable the circumstance might be owing to the presence of a very large proportion of silver; some of the larger pieces also obtained were spotted white from the same supposed cause; but, Mr. Hunt, on heating this white gold, found that it quickly turned to a good golden yellow, and that the discoloration was occasioned by a thin coating of mercurial amalgam. As the spots were perceived on some of the larger pieces immediately on their being first obtained on the shovel, it is supposed they must have been spotted with the mercury while still undisturbed in the drift; and as no mercury had been used on the ground, it leads to the supposition that some ore of mercury may possibly be one of the mineral products of the country, though not a grain of cinnabar, the commonest form of the ores of mercury, has been observed in the gravel. Among the substances obtained in separating the gold, lead shot of various sizes, from partridge to swan shot, has been nearly as abundant as the gold. Not a vanning was made of the concentrated material without obtaining some of it ; its presence is no doubt due to the operations of those who have followed the chase, and to judge from the quantity of the shot the place must have been one of favorite resort. Whether the hunters may at any time have brought quicksilver with them and spilt it, is a question that cannot be deter- mined. The Geologist concludes, from the evidence collected, that the de- posites are not generally sufficiently rich to render their working re- munerative to unskilled labor; and that the agriculturist and others engaged in ordinary occupations of the country, would only lose their time and labor by turning gold hunters. GOLD AND ITS PRODUCTION. FIveE years have hardly elapsed since the gold yield in California became a fixed fact, and within that short period of time between a hundred and ninety and two hundred millions worth of gold dust has been added to the wealth of the world, and a trade has sprung up between the Atlantic States and San Francisco of the greatness of which some idea may be indirectly formed, from the fact that the im- ports from all other parts of the world to that port have increased from three and a half millions in 1851, to ten and a half millions in 1852. The California movement has made its influence felt all over the world; but now even California itself seemes to be eclipsed and outstripped in its productiveness by the more recent and more magni- ficent discoveries of gold fields in Australia. They completely throw into the shade all the mines of Peru, Mexico, or California. So extensive are the gold deposites distributed in Australia, that the very: streets of Melbourne are found, in a manner, to be paved with them. The broken quartz rocks which have been used to MacAdamize the streets are found to contain gold. : 302 ANNUAL OF SCIENTIFIC DISCOVERY. While Melbourne is thus favored, mines of immense value have been opened at Mount Ballaret and Mount Alexander, about eighty to one hundred miles north of the city. The treasure taken from these two deposites alone, from the 1st of December, 1851, to the 1st of April, 1852, amounted to about $9,000,000. The first discovery of gold was made near Bathurst, in New South Wales, on the 22d May, 1851, from 150 to 164 miles west of Sidney. The localities first worked were at Summerville Creek, Abercrombie river, from whence further discoveries have been made over a vast mountain region of country. From May to the 6th September the shipments reached $750,000, and on the 8th November about $1,000,- 000. Lumps were occasionally found weighing from twenty to twenty-seven pounds. In December, 1851, the parties at the diggings in Victoria were estimated at from eight to ten thousand, and near Bathurst, at four thousand. The whole amount sent to England since the discover y in May, 1851, is estimated at twenty millions. The gold region already discovered in Australia promises to yield double ‘and triple the quantity of gold, by the same number of laborers, over that obtained in California. Good observers suppose it to extend over an area of not less than 15 to 20,000 square miles, the whole area of the island being estimated at about three million square miles. Accounts from Australia to November, 1852, state that the produc- tion of gold is on the increase, and many of the stories which are received would seem almost incredible, were they not fully corrobo- rated by actual receipts. Not only do the old diggings yield abun- dantly, but new ones are found daily of wide extent. To show that the recent accounts must be founded in truth, it is said that the receipts from Mount Alexander and Ballarat diggings alone, are given in the Australia papers at one million seven hundred thousand nine hundred and seventy-four ounces, or between seventy-three and seventy-four tons, in ten months. From the entire Victoria gold fields, in the same period, the receipts had been one hundred and five tons. The amount of gold actually exported from the country from October, 1851, to September, 1852, amounted to over forty millions of dollars. The assays made of the Australian gold show that it is somewhat purer than that obtained in California. The assays of the United States Mint, at Philidelphia, give a fineness of 966 thousandths. Making an allowance for melting, “this gives a value to the native grains of about $19 60 per ounce. ‘Assays. that have been made in England are reported to have given the result of 938 thousandths fine. Upon these facts, it is pre esumed that Australian gold is better than Califor- nia or, in other words, that it contains less silver by six or seven per cent. on the average. Gold in Australia.— A report has been presented to the Imperial Geological Society of Vienna relative to the production of gold in Austria. Austria produces the most gold of any European State. It amounts yearly to 7,500 marks, which promises asum of 603,000 ducats. Much of this j is obtained by the Gipseys by sand-washing i in Hungary and Siebenburgen. There are two ways in which the gold GEOLOGY. 303 is found —one is in the deposites of sand and soil; the other in the strata of ore. The latter is the most common method of finding it in Hungary and Siebenburgen. Gold in Vermont. — Specimens of gold have been found during the past season in Bridgewater, Vermont, by Mr. Mathew Kennedy, of Plymouth, Vt. They were taken from a quartz vein in mica and talcose slate, and the gold is associated and intermingled with the white quartz, ferruginous quartz, galena, and iron and copper pyrites. In occurs in scales and grains of various sizes, and is of a beautiful clear yellow. The vein has been traced some 50 or 100 rods, and farther explora- tions will soon be made to prove it at other points. The gold forma- tion is known to extend nearly the whole length of the State, and this discovery may lead to a fair examination of the formation. Gold in Demerara.— Advices from Demerara state, that gold has been discovered in that colony up the Cuyuni river, and that about £200 had already been brought in. It is alleged to be remarkably pure and to consist of small lumps, and also of scales and dust. The locality is said to be not more than two or three days’ journey into the interior. In addition to the gold discoveries made within a recent period in Australia and California, it is stated that valuable deposites have been found on the St. John’s river, near Liberia, in Africa; howéver this may be, it is undoubtedly true, that the exportation of gold from the west coast of Africa has greatly increased within the last two years. The amount received in Liverpool alone from this source, was estimat- ed for the year 1851, to exceed £300,000. Consumption of Gold. —'The following curious statistics relative to the consumption of gold were stated in a lecture lately delivered at the Geological Society at London. The entire amount in circulation is said to be £48,000,000; of which the wear and waste is stated to be 33 per cent., annually £1,680,000. The consumption of gold in arts and manufactures is as follows : — inthe Umited Kingdom, .... 6. 25.9) jays, » «py.s)4a24000,000 France, . RE Ra et age AT Ne . 1,000,000 ERIN ari sf otek ne, wate ih oak alas coll alls Seu Oe iMher parts of Hnrope,.. (joey <) sicsji eons 4y2e 1,600,000 ALCS a aes s \iisitle Ae Siackh, aifle om