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VALUABLE SCIENTIFIC WORKS.
THE FOOT-PRINTS OF THE CREATOR ; or, the Asterolepsis of Stro:
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“ Mr. Miller’s style is remarkably pleasing; his mode of popularizing geological knowledge une
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“The publishers have again covered themselves with honor, by giving to the American public,
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“Tt is withal, one of the most beautiful specimens of English composition to be found, coavey-
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PRINCIPLES OF ZOOLOGY : Touching the Structure, Development, Distribution,
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By Louis AGAssiz and AuGcusTus A.GouLD. Revised edition. 12mo,...cloth,....1,#
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“ A work emanating from so high a source hardly requires commendation to give it currency.
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atyle, full in its illustrations, comprehensive in its range, yet well condensed, and brought into the
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“The work mzy safely be recommended as the best book of the kind in our language.”—Chrese
tian Examiner.
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VALUABLE SCIENTIFIC WORKS.
YHE EARTH AND MAN: Lectures on CoMPARATIVE PHYSICAL GEOGRAPHY, in its
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trations. Second thousand. 120. ee veecccccccerccsccscccscccscesesClOthye. 01,29
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COMPARATIVE PHYSICAL AND HISTORICAL GEOGRAPHY ; or, the
Study of the Earth and its Inhabitants. A series of graduated courses for the use of
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The series hereby announced will consist of three courses, adapted to the capacity of three dif-
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KITTO’S POPULAR CYCLOPADIA OF BIBLICAL LITERATURE, OCon-
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of the present day in all the studies connected with Theological Science.
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The work will first be published in eight numbers, at twenty-five cents eacr
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A ¥Y/REATH AROUND THE CROSS; or, Scripture Truth Illustrated. By
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and consolation to enquiring sinners.”
GUYOT’S MURAL MAP OF THE WORLD, on a large scale, (5 by 7 feet,) for
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5000 learn to reflect on the thoughts which these words represent.”
(From Hon. J.C. Spencer,}
ALBANY, June 18th, 1851.
More than twenty years 4 I procured the Quarto edition, and have used it constantly ever
since. My pursuits in life have rendered it necess to consult it frequently, as well as other
works of 2 kindred or similar character, particularly Dr. Johnson’s Quarto, of the latest and best
edition, Richardson’s Dictionary, Crabbe’s Synonyms, and Horne Took’s Diversions of Purley.
In professional, political, and literary discussions, the turning point of the argument has often been
the exact meaning of words, as ascertained not only from their use, but from their derivation:
while in many cases, perhaps in the majority of them, the works referred too have failed to give
the desired information, that of Dr. Webster has always furnished precisely what has been desired,
and I have long felt individually indebted to the illustrious author, for the labor and time he has
saved me by his unwesred patience, profound learning, and unsurpassed industry.
It is wnquestionably the very best Dictionary of our language extant. It is a model of copious-
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shea Q, :
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Published by G. & C. MERRIAM, Springfield, Mass., and for sale by Booksellers generally.
AOGQUATVE Oty pt
hens
~
| SCIENTIE
or
I hitig Sh
47
ay .
7 be «eae |
A LIST OF RECENT SCIENTIFIC PUBLICATIONS; A CLASSIFIED LIST OF
PATENTS; OBITUARIES OF EMINENT SCIENTIFIC MEN; NOTES ON
THE PROGRESS OF SCIENCE PURING THE YEAR 1ésg, ETO, ETO.
‘er a
; EDITED BY
DAVID A. WELLS, A. M.
| BOSTON;
GOULD AND LIN@®OLN,-
59 WASHINGTON STREET.
ites ll oe 853. ry 4xveil 5 5
Po
~g
2
; 5) F y
j fpr f F
Bee: ah 2 Spine ae Sees
/
Gould & Lincoln, Ihoston,
ANNUAL
or
SCIENTIFIC DISCOVERY:
YEAR-BOOK OF FACTS IN SCIENCE AND ART,
FOR 1802.
EXHIBITING THE
MOST IMPORTANT DISCOVERIES AND IMPROVEMENTS
IN
MECHANICS, USEFUL ARTS, NATURAL PHILOSOPHY, CHEMISTRY,
ASTRONOMY, METEOROLOGY, ZOOLOGY, BOTANY, MINER-
ALOGY, GEOLOGY, GEOGRAPHY, ANTIQUITIES, &e.
TOGETHER WITH
A LIST OF RECENT SCIENTIFIC PUBLICATIONS; A CLASSIFIED LIST OF
PATENTS; OBITUARIES OF EMINENT SCIENTIFIC MEN; NOTES ON
THE PROGRESS OF SCIENCE DURING THE YEAR 1852, ETC. ETC.
EDITED BY
DAVIDA. WELLS; #4. °M,
BOSTON:
GOULD AND LINGOL®M,
59 WASHINGTON STREET.
1853.
Entered according to an Act of Congress, in the year 1858,
Br GOULD & LINCOLN,
In the Clerk’s Office of the District Court of the District of Massachusettr.
\
G. C. Rann, Printer, 8 Cornhill, Boston.
PREFACE.
THE present number completes the fourth yearly vol-
ume of the Annual of Scientific Discovery. In its
preparation, the Editor has followed the general plan
indicated and developed in the former numbers of
the work. :
The mental activity at present displayed in developing
new principles and modifying old ones, to meet the
wants of practical industry, in cheapening and improving
the production and preparation of all raw materials, and
disseminating useful knowledge, is probably greater than
at any former period of the world’s history. Under
these circumstances, the labor of preparing an annual
retrospect has been greatly increased. The Editor has,
however, endeavored to present as faithful an abstract
of the progress of science and the useful arts during
the year eighteen hundred and fifty-two, as the limits
of the present volume would allow. The field for
26 (oF
4 PREFACE.
enlargement is ample, and would willingly be entered
upon, were sufficient promise of encouragement afforded
by the public.
The annual summary of ‘“ Notes by the Editor on the
Progress of Science ” has been considerably enlarged,
and embraces several topics of interest, which could not
conveniently be included in the body of the work.
We present our readers for 1853 with a portrait of
Prof. ALEXANDER Dauuas BacuHeE, President of the
American Association for 1850-51, and Superintendent
of the United States Coast Survey.
Boston, February, 1853.
NOTES BY THE EDITOR
ON THE
PROGRESS OF SCIENCE IN 1852.
In reviewing the progress of Science during the past year, 1852, it is
especially to be remarked, that the annual record of discoveries in all the
branches of science and the useful arts, is more characterized by its utility
than by its brilliancy. The following remarks, appositely observed of the
transactions of the British Association for 1842, apply equally well to the
general scientific progress of the year 1852 :— “ We have this year no great
scientific novelty, theory, or discovery, brought upon the tapis, and claim-
ing the attention of philosophers. There is no voyage to the South Pole
to be promoted, — there is no hypothesis of glaciers to astonish the world,
— there are no observations of the nature of storms to throw a light on those
terrible visitations, —there is no doctrine and measurement of waves, or on
the form of vessels, — there is no new feature in the grand research into the
mysteries of magnetism, —in short, except the idea of following up the
investigation of meteorological phenomena by means of balloons, we have
heard of nothing very particular. Let it, however, be understood, that in
all branches of science, steady progress has been made and recorded. Data
of high consequence are collected, both to check future mistakes, and
advance future information. Induction, the true basis of all truth, will
flourish upon these ; and therefore, though there is nothing extraordinary
in this stage of the onward journey, the distances and milestones are fairly
marked so far, and the prospects in the distance are rendered much more
clear and distinct. The way to the field is beaten, and its ample survey
defined. There is nothing needed but to march on, take time, and labor to
a useful end.”
Europe, as if her energies were overtasked by the demands of the Great
Exhibition year of 1851, has given us in 1852 nothing particularly new,
6 NOTES BY THE EDITOR
striking, or wonderful ; no new application of science to art,and no mechan-
ical or chemical discovery of striking interest have been announced in the
United States during the same period. Notwithstanding, many great plans
are now in the process of development, many new ideas are germinating,
and many old ones, which have long slumbered in the domains of theory
are passing into real, substantial, practical facts. During the year 1852,
more than one thousand patents for discoveries, inventions, and applications,
“new and useful” were granted by the United States. More than three-
fourths of these patents were granted to citizens of the five states of Massa-
chusetts, Connecticut, New York, Pennsylvania, and Ohio. As many as
three applications for patents from the same sources were probably rejected,
where one was granted. The public journals are filled with accounts of the
commercial prosperity induced by the gold discoveries .of Australia and
‘California; but the journalists and the public little know how many secret
springs and incentives to invention and practical application, the same influx
of gold, and the consequent revival of manufactures, has occasioned.
There is an intensity of mental action and thought, devoted to the realiza-
tion of the useful and the new, now pervading some portions of our country,
especially in Massachusetts, the like of which the world has never before
witnessed. The American operatives, mechanics and manufacturers, who
have in vain sought protection from the National Government, are now
creating protection for themselves; educated industry, and skill are rapidly
forming a tariff, which in a few years will undoubtedly put foreign compe-
tition at defiance. Another curious fact in relation to this subject, is the
intensity of competition which the mental activity referred to has engen-
dered. An original thought, or a new idea, admitting the possibility of a
practical application, when once promulgated becomes common property.
A hundred minds at once seize upon it, elaborate it, perfect it. The engines
of Ericsson had barely made a successful revolution before an improvement
by another was announced in the New York Journals. The U.S. Court
were recently occupied at Boston with a closely contested case respeeting
the validity of two patents for cotton-gins; the trial had not concluded
before a new gin was put in operation which will undoubtedly render all
others valueless. The discussions and experiments in England respecting
the manufacture of flax by new processes, have awakened great interest in
the subject in the United States, and more is probably known here at pres-
ent in relation to this matter, than in Europe. We believe the day is not
far distant, when the manufacture of flax will be conducted in the United
States upon a most gigantic scale. We turn, however, from these generali-
zations to some of the more particular events of the past year.
The annual meeting of the American Association, for 1852, appointed to
be held in Cleveland, in August, was postponed on account of the prevail-
ON THE PROGRESS OF SCIENCE. T
ing cholera in that region, and the great heat of the season. The place and
time for the next regular meeting have not yet been determined by the
Executive Committee. :
The twenty-second annual meeting of the British Association, for the
Advancement of Science, was held at Belfast, Ireland, September Ist ; Col
Sabine presiding. The attendance was somewhat less numerous than in
1851, and the papers read, had for the most part, a local rather than a gen-
eral*interest. Among the important measures taken by the Association,
was a strong representation to the British Government, respecting the
importance of sending out an expedition for the purpose of studying the
phenomena of tides, especially those of the Atlantic Ocean. The President
elected for 1853 is William Hopkins, President of the Geological Society,
and of the Cambridge Philosophical Society.
From the annual address of the President we copy the following passa-
ges: —‘‘ Hitherto the researches of Sidereal Astronomy, even in their
widest extension, had manifested the existence of those forces only with
which we are familiar in our own solar system. The refinements of modern
observation and the perfection of theoretical representation had assured us
that the orbits in which the double stars, immeasurably distant from us,
revolve around each other, are governed by the same laws of molecular
attraction which determine the orbits of the planetary bodies of our own
system. But the Nebulz have revealed to us the probable existence in the
yet more distant universe, of forces with which we were previously unac-
quainted. The highest authorities in this most advanced of all the sciences
acknowledge themselves unable even to conjecture the nature of the forces
which have produced and maintain the diverse, yet obviously systematic,
arrangement of the hosts of stars, which constitute those few of the Spiral
Nebulz which have been hitherto examined. Hence the importance of
increasing our knowledge of the variety of forms in which the phenomena
present themselves, by a similar examination of the Southern Heavens to
that which Lord Rosse is accomplishing in the Northern Heavens. In
addition we can scarcely forbear to covet at least an occasional glance at
bodies which from their greater proximity have more intimate relations with
ourselves, and which, when viewed with so vast an increase of optical power,
may afford instruction of the highest value in many branches of physical
science. In our own satellite, for example, we have the opportunity of
studying the physical conformation and superficial phenomena of a body
composed, as we believe mainly at least, of the same materials as those of
our own globe, but possessing neither atmosphere nor sea. When we
reflect how much of the surface of the earth consists of sedimentary
deposites, and consequently ‘how large a portion of the whole field of geo-
logical research is occupied with strata which owe their principal charac-
2
8 NOTES BY THE EDITOR
teristics to the ocean in which they were deposited, we cannot but anticipate
many instructive lessons which may be furnished by the points of contrast,
as well as of resemblance, which the surface of the moon, viewed through
Lord Rosse’s telescope, may present to the best judgment we are able to
form of what the appearance of the earth would be if similarly viewed, or
— with ‘what may be more difficult perhaps to imagine — what we may
suppose the earth would appear if it could be stript of its sedimentary strata,
which conceal from us for the most part the traces of that internal aétion
which has played so large a part in moulding the great outlines of the
present configuration of its surface. It is understood that Lord Rosse him-
self participates in the wish that such an examination of the surface of the
moon should be made, and, should the desire of the Association be
expressed to that effect, is willing to undertake it in conjunction with one
or two other gentlemen possessing the necessary physical and geological
knowledge. It will be for the Association to determine the form in which
a report on the “Physical Features of the Moon, compared wath those of
the Earth,” may most appropriately be requested.
The German Association for the advancement of Science held its 29th
annual meeting at Wiesbaden, commencing September 18th. The attend-
ance was very numerous, nearly 800 members being present. Dr. Fresen-
ius was President of the Association, and Prof. Sandberger, Secretary. A
public address was delivered by Prof. Nees von Esenbeck, of Breslau.
To be a privileged member of this Association, with the right of speak-
ing and voting in the meetings, it is necessary to have written some work
bearing on natural history, physics, or medicine; but to become a temporary
associate, with the right of being present as a listener merely at all the
scientific meetings, as well as of taking part in all the festive social reunions,
is free to every one on the very moderate payment of two Prussian dollars.
The next meeting of the Association was appointed to be held at
Tubingen. P
A “Hygienic Congress,” consisting of gentlemen of different countries,
who take an interest in promoting the health of towns and the welfare of
the working classes, was held in Brussels, in September About 200 gen-
tlemen, Belgians and foreigners, were present, —nearly all the Scientific
Societies of Europe being represented. The work was done in four differ-
ent sections :— one, charged to occupy itself with workmen’s houses, baths,
wash houses, and hospitals; another, with sewers, &c., the distribution of
water, and ventilation; the third, with the organization of public health, the
maintaining of children, interments, and cemeteries; and the fourth, with
the adulteration of food, the labor of children in work shops, and
prostitution.
The Scientific Congress of France, held its annual session at Toulouse,
ON THE PROGRESS OF SCIENCE. 9
commencing on the 13th of September. Count de Peyronnet, of the Acad-
emy of Bordeaux, was elected President of the meeting.
A new Geological Institufe has been formed during the past year at
Vienna, the principal object of which will be, the production of a series of
geological maps of the Austrian dominions :— the whole of which gigantic
undertaking may be completed, it is to be hoped, within thirty years, —
beginning} with Austria proper, and proceeding gradually to the Italian,
Hungarian, and Bohemian dominions. The institution is under the direc-
tion of Prof. Haidinger.
A circular has been issued by several of the prominent geologists of our
country, proposing the organization of an Association of American geolo-
gists, somewhat on the plan of the Geological Societies of England and
France. It is not intended, that the members of the society should sever
their connection with the American Association, but it is thought, that by
means of meetings or sittings of the Society, or of its Committees, to be
held at regular and irregular intervals, to be fixed by the Association, and
at places where interesting and disputed questions arise, or even of ambu-
latory character, in the field, quicker and surer results would be arrived at;
and the conclusions would be more satisfactory at home, as well as more
respected abroad.
A National Agricultural Society composed of delegates from the different
States and Territories, has been formed at Washington, during the past
year. Marshall P. Wilder, of Massachusetts, has been elected President,
with a Vice President from each State.
The French Government have recently instituted a General Horticultural
Society for all France, which is to consist of titular and honorary members,
and of an unlimited number of foreign correspondents. It is to occupy
itself with all matters connected with horticultural science; to publish a
monthly volume of “ annals” thereon ; to give prizes for elementary works ;
and to grant certificates of horticultural merit.
A most noble and princely donation to the cause of science and art has
been made by Mr. Peter Cooper, of New York. The plan proposed is
essentially educational in its features, and has in view the moral and intel-
lectual elevation of the youth of the city of New York.- A large building
is now erecting in New York as the nucleus of the institution, the cost of
which, together with the land will amount to $300,000; the building is to
contain a “sculpture and picture gallery, exhibition hall, library, lecture-
room and observatory. Books, apparatus, instructors, &c., are to be provided,
and it is intended that the institution shall enjoy an annual income of
$25,000.”
Among the other donations made in behalf of Science in the United
States during the past year, we would mention the following : — George
10 NOTES BY THE EDITOR
Peabody, Esq., the eminent London banker, has given to the town of Dan-
vers, Mass., which is his native place, the sum of twenty thousand dollars
for the establishment of a lyceum and library and the erection of the neces-
sary buildings.
The sum of $50,000 has also been given by Joshua Bates Esq., of London,
to the city of Boston, to aid in the establishment of a free public library.
Dr. George C. Shattuck, of Boston, has presented Dartmouth College
with $7,000, to be used in the erection of an observatory, on condition that
the trustees of the college will raise the further sum of $8,000 for the pur-
chase of instruments.
The sum of $1,000 has been given by Hon. Jonathan Phillips, of Boston,
to the American Academy, for the purpose of defraying the expense of its
publications.
The expenses of a new Expedition in search of Sir John Franklin and
for Arctic exploration, are to be defrayed by Henry Grinnell, of New York,
and George Peabody, of London.
Five hundred dollars have been voted by the Board of Underwriters to
the Geographical Society, at its solicitation, to be devoted to a series of
magnetic observations to be made under the direction of Dr. Kane, the
Arctic Explorer on his next expedition.
Within a few years, a number of projects have been set on foot in New
York, for the establishment of an astronomical observatory in that city or
vicinity, but they have all failed, mainly from want of means and encour-
agement. A new enterprise has recently been started, with a fair prospect
of success. The “American Observatory Association,” issue a prospectus
for the establishment of an Observatory on the Palisades, above Fort Lee,
on the basis of a joint-stock association, self-governed. Four hundred
shares are to be offered at twenty-five dollars each, and the names of many
prominent citizens of New York are pledged to the work. The originator
of the plan is Mr. Leon Lewenberg, of New York, who proposes to endow.
the Observatory with a sufficient tract of land, one mile distant from Fort
Lee. He also offers a Telescope of his own manufacture, as an additional.
donation. The building to be erected will be 150 feet in height; giving the
Telescope, with the elevation of the ground — 320 feet above the River —
an altitude of 500 feet. This height will be sufficient to relieve the instru-
ment from the influence of a smoky or impure atmosphere, and will insure
a wide range of vision.
In relation to the progress of astronomy in England, Prof. Piazzi Smyth,
observes, that if it were not for private enthusiasm, Kngland would be left
quite behind in some branches of astronomy; for while the Russians, Ger-
mans, and Americans, are continually ordering for their observatories the
largest telescopes that can be made, the English Government will not supply
ON THE PROGRESS OF SCIENCE. 11
any such to those of Britain. The recommendation of the Britsh Asso-
ciation, and of the Royal Society to the Government, to send a superior
telescope to the clear climate of Australia, has been refused; the East
India Company have also shown themselves unwilling to do anything
towards aiding the establishment of an observatory on the Nilgheny Hills,
India, 6000 feet above the level of the sea. The great purity of the atmos-
phere which prevails in these regions, would undoubtedly lead to many
important and signal discoveries. What the East India Company have
refused to do, Capt. Jacobs is endeavoring to do on his private responsibility.
At the session of the French Academy on the 22d of March, the prize in
Astronomy for 1851, was divided between Mr. Hind, and M. Gasparis, the
former for the discovery of the new planet Irene, and the latter for that of
Eunomia. The Cuvierian prize, (a triennial prize, and never before
awarded,) was given to Prof. Agassiz, for his researches on fossil fishes.
Among the prizes offered by the Academy is one for 1854 in the depart-
ment of Mathematics, as follows: —To determine the equations of the
general movements of the earth’s atmosphere, having in view the rotation
of the earth, the calorific action of the sun, and the attraction of the sun
and moon. The authors are desired to exhibit the concordance of their
theory with the best observations on the atmospheric movements. Even if
the whole question is not resolved, but some important steps are made
towards its solution, the prize will be awarded by the Academy. The prize
is a medal of 3,000 francs. There is also an extraordinary prize for 1853,
on the application of steam tonavigation. It is offered “for the best work
or memoir on the most advantageous employment of steam for steam-
ships, and upon the best system of mechanism, stowage and armament for
such vessels.” The prize is 6,000 francs. /
The French Government, through the Moniteur, have officially offered a
prize of 50,000 francs for the discovery that “shall render the voltaic pile
applicable, with economy, to industry, as a source of heat—to lighting,
chemistry, mechanics, or medical practice. All nations are admitted to
compete during five years.
The Germanic Diet at Frankfort, have voted a sum of £3,500 to M
Schonbein, and others, the inventors of gun-cotton, as a reward for the
discovery.
An Exhibition of the Industry of ali nations will be opened in the city of
New York, in May of the present year. The plan of the Exhibition, as
well as the building erected for the purpose, is essentially that of the Great
Exhibition of 1851. The enterprise has been entered into with great spirit,
and the display of the products of American science and art, together with
the agricultural and mineral productions, of the United States will be proba-
bly unequalled. The productions of foreign countries will be also well
represented. 2%
12 NOTES BY THE EDITOR
The scientific expeditions, surveys and explorations prosecuted, or pro-
jected during the year 1852, have been numerous, and attended with valua-
ble results. _ :
The survey of the coast of the United States, under the superintendence
of Prof. A. D. Bache, has been prosecuted with great energy. With only
one link of twenty-six miles south of the Chesapeake to be filled up, an
unbroken triangulation now extends from the mouth of the Kennebec river,
in Maine, to the harbor of Beanfort, in North Carolina. The topography
and hydrography have made corresponding progress. In afew years an
unbroken series, with points well determined by astronomical aud other
observations, will cover the coast from the Penobscot river in Maine, to the
St. Mary’s in Florida. The progress of the survey on the Florida reef
and the shores of the Peninsula is entirely satisfactory, in view of the
limited appropriations, compared with the vast extent and variety of the
whole work. The entire reef and western shore has been examined ina
preliminary way, and nearly one-half of the survey of the reef has been
made. A reconnoissance has been made of about one-half of the distance
between St. Mark’s and Mobile bay, and the triangulation and topography
now extend from Mobile bay to Lake Ponchartrain, and nearly all the
hydrography has been.completed, and an examination made of the delta of
the Mississippi. Galveston bay has been surveyed excepting a small por-
tion of the hydrography, and the triangulation now extends to the vicinity
of Matagorda bay. On the western Coast, in consequence of the extraor-
dinary difficulties in securing hands and means owing to the discoveries of
gold, the survey did not fairly get under way till about three years since.
A very good preliminary reconnoissance has been made of the whole coast,
from San Diego to the Straits of San Juan del Fuca, and of nearly every
important harbor. In connection with this rapid progress of the survey on
this coast, observations have been made for latitude and longitude, and the
magnetic variation. ‘The geographical position of the coast, from the
Straits of San Juan del Fuca to San Diego, has been established ; the lati-
tude and longitude of the most important headlands having been determ-
ined by sufficiently numerous and reliable preliminary observations. ©
The exploration of the Gulf Stream has been continued. Great progress
has been made in publishing the results of the survey. Forty-two charts,
elaborate and highly finished, and forty-two preliminary charts have already
been published, and twenty-seven sheets are in various stages of engraving.
The geographical positions determined by the survey from its commence-
ment to July, 1851, have been published. The latitude and longitude of
over 3,200 points have thus been given to the public, furnishing infor-
mation of great value for general and local purposes.
Under the direction of the U. S. Government a strong naval expedition
ON THE PROGRESS OF SCIENCE. 13
has sailed for the purpose of endeavoring to establish relations of amity and
commerce with the Empire of Japan. Looking to the magnitude of the
undertaking, and the great expectations which have been raised both in this
country and in Europe, in reference to its results, this expedition is full
of interest, and will undoubtedly be productive of many valuable results,
scientific, as well as commercial and moral. The expedition has on board
a variety of articles as presents to the Emperor of Japan, to conciliate him
and ‘prepare the way for the desired negotiation. A locomotive and a
quantity of railroad iron have been taken with which to show the operations
of a railroad; telegraph apparatus with which to demonstrate how the
lightnings have been converted to the use of civilization. An apparatus for
taking daguerreotypes will also be used and explained for the information
of His Majesty. A beautiful barge is on board to be presented to him.
Also, boxes of domestic goods, comprising a great variety of manufactured
articles, which are to give the Emperor an idea of the industrial pursuits of
this country, and perhaps awaken a desire on his part for an exchange of
commoditics between Japan and the United States.
Somewhat allied in character and importance to these projected operas
tions of the Japan squadron, is the expedition now prepared for the explor-
ation and survey of the China seas, the Northern Pacific, and Bhering’s
Straits. This expedition, in aid of which $125,000 has been appropriated
by Congress, is provided with a corps of scientific men, an astronomers
hydrographer, botanist and naturalist.
Under the direction of the Navy department, Lt. Lynch, well-known from
his connection with the Dead Sea Expedition, has been detailed on a tour of
African exploration, especially of that portion of the Continent lying east of
the settlements of Liberia. Itis supposed that an exploration of this region
would lead to the discovery of a broad tract of fertile and healthy country,
well adapted to the extension of that system of colonization, which for
some years past has greatly interested public attention in the United States.
Lt. Lynch will land at Liberia, Cape Palmas, and other points, and will pur-
sue his inquiries as far as the river Gaboon, with a view to the ascertain-
ment of such localities on the margin of the African continent as may
present the greatest facilities, whether by the river courses or by inland
routes, for penetrating with the least hazard into the interior. He will col-
lect information touching the geographical character of the country; its
means of affording the necessary supplies of men and provisions ; the tem-
per of the inhabitants, whether hostile or friendly; the proper precautions to
be observed to secure the health of a party employed, and all other items
of knowledge upon which it may be proper hereafter, to prepare and com-
bine the forces essential to the success of a complete and thorough explor-
ation of the interior.
14 : NOTES BY THE EDITOR
A fourth expedition under the direction of the United States Government,
commanded by Capt. Page, has sailed to explore the long-sealed and exclu-
ded countries lying on the tributaries of the river La Plata, South Americaa.
By a decree of the Argentine Government, there has recently been opened
to the access of all nations, a vast territory of boundless resource, prover-
bial for its treasures of vegetable and mineral wealth, extending, like the
Mississippi from south to north, and reaching through twenty-four parallels
of latitude, with every climate between the temperate and torrid zones, and
with every variety of product which may be gathered from the alluvial
plains of the ocean border to the height of the Andes.
An expedition under the charge of Lt.’s Herndon and Gibbon, U. S. N.,
charged with the exploration of the Amazon and its tributaries, has in part
returned. These officers were directed to cross the Cordileras in Peru and
Bolivia, and by a selection of the most judicious routes of travel, with a
small company of men, to explore the valley of the Amazon, and to de-
scend that river to the sea. More than a year has has been spent in the
active prosecution of this duty. Lieut. Herndon reached the United States
in July last, bringing with him a large amount of interesting and useful
facts, industriously collected by him in the course of his long and hazard-
ous journey, embracing many valuable statistics of the country, and adding
most important contributions to the hitherto unknown geographical charac-
ter of this region. He is now engaged in preparing a full report of the
incidents and discoveries of his travels.
Another expedition to the Arctic Sea under the charge of Dr. Kane, in
search of Sir John Franklin, and for scientific exploration, is now fitting
out under the auspices of our countrymen, Mr. Henry Grinnell, and Mr.
George Peabody, of London. Their endeavor will be directed to an ex-
ploration of the upper coasts of Greenland, by land as well as sea, and will
furnish occasion for valuable scientific observation tending to the ascertain-
ment of the magnetic poles and the intensity and dip of the needle; and
interesting also, as regards geological questions connected with the sup-
posed existence of an open polar sea, and other subjects of much impor-
tance in the natural history of our globe.
The course adopted by the British Government in relation to the discove-
ries made by the last American Expedition under Lieut. De Haven, is in
the highest degree discreditable and dishonorable. In the Charts published
by the authority and under the direction of the Admiralty, the localities
discovered up Wellington Channel, by the Americans in Sept., 1850, are
for the most part ignored, or altered. The “ Grinnell Land” first seen by
De Haven in 1850, and subsequently by Capt. Penny in 1851, has had its
original name, given in honor of a noble American merchant, changed to
ON THE PROGRESS OF SCIENCE. 15
that of “ Prince Albert’s Land.” Courtesy, if no other motive, should have
prevented a change.
Lieut. Gillis, who, for more than three years past, has been employed, in
pursuance of the directions of Congress, in conducting in Chili the obser- -
vations recommended to be made by the American Philosophical Society
and the Academy of Arts and Sciences, has recently returned to the United
States, bringing with him a rich contribution to science, in a series of ob-
servations, amounting to nearly forty thousand, and embracing a most
extensive catalogue of stars.
Under the auspices of the American Antiquarian Society, Worcester,
Mass., Mr. Lapham has recently made series of complete surveys of numer-
ous ancient mounds now existing in the State of Wisconsin. Mr. Lapham’s
report will be shortly published by the Smithsonian Institution.
An expedition under the charge of M. Deville, is about to be sent out
by the French Government, for the purpose of exploring some parts of
Brazil, Paraguay and the provinces of Para, Pernambuco, and Bahia.
A mission is about to start, under the auspices of the Geographical So-
ciety of St. Petersburgh, for Kamschatka, the Kurile Islands and Rus-
sian America. The objects are—to study the ethnography of these
districts, to collect specimens of their Flora and Fauna, to report on their
physical characteristics, and to make maps and plans of their roads, coasts,
and other topographical features.
An English exploring expedition, consisting of two vessels under the
charge of Capt. Denham, R. N., sailed for the South Pacific in June last.
The cbject of the expedition is to survey and explore all the islands be-
tween Australia and Valparaiso, and particularly the Fejee Islands. Mr.
McGillivray, the well known naturalist, was appointed to take charge of
the department of Natural History, and Mr. 8S. G. Wilson was appointed.
artist, to make drawings of any objects in these islands likely to prove
interesting, and for which purpose he has been supplied with a photo-
graphic apparatus.
_ Some months ago a Scientific Expedition was sent out from Copenhagen
to explore the hills of Greenland and report on their mineral resources.
This expedition has recently returned to Denmark, with a cargo of miner-
als as the fruits of their industry. The explorers have failed to find any of
the more precious metals ; but they have brought back iron, lead, nickel,
tin, and copper mixed with a little silver: —the whole valued at nearly
two thousand pounds. The society appears to be encouraged by these
first-fruits of its enterprise to renewed exertions ; but the rigors of the
climate of Greenland deter even the Norwegian miners from embarking in
the adventure.
The exploration of different portions of Africa have been continued with
16 NOTES BY THE EDITOR.
such success, that even in the brief space of a year the vast blank on all
former maps has been materially reduced. Mr. Oswell, and the mission-
ary Livingston, his companion, to both of whom we are indebted for our
acquaintance with the Ngami Lake, have pushed their researches north-
wards to 17 deg. 25 min. S. latitude, and between 24 deg. 30 min., and
26 deg. 50 min. E. longitude, and have traversed a considerable track,
watered by deep and constantly flowing streams, which they believe to be
feeders of the river Zambesi. We learn from them, that the Zonga, which
was to the east from Lake Ngami, is dissipated and absorbed in sands and
Salt-pans, and the travellers passed over a large salt incrustation of about
100 miles in length and 15 miles in width, and saw many others lying
to the north of the spot where the Zonga loses itself. Considerably to
the north of these great natural salt pans, a population was met with,
more advanced in intelligence than most of the tribes of South Africa.
They also relate as a striking incident, that shortly before their arrival,
the slave-dealers had, for the first time, penetrated from the west coast,
and through the temptation of gaudy European goods had purchased
many children.
Researches made in Africa by Mr. Galton, an English traveller, between
latitude, 17 deg. 58 min. 8., and longitude, 21 deg. E., taken also in con-
nection with the explorations of Messrs. Oswell and Livingston, show,
that the central region of Southern Africa, instead of being mountainous,
is a watershed of no great elevation, and that the most central portion of
it is occupied by a succession of lakes, of which Ngami is the southern-
most.
Under the direction of the Swedish Government, a topographical survey
extending over 8700 geographical miles is now in progress. Levellings
and trigonometrical surveys from Torneo to Alten, in the North Sea, will,
when finished, give not only the relative heights of the Gulf of Bothnia,
and the North Ocean, but will also serve as fixed data from whence to
calculate the greater or less irregularity of the rise, or depression of the
Scandinavian lands.
The most perfect topographical and geographical maps which perhaps
have ever been produced, are those of the cantons of Appenzel and St.
Gallen, in Switzerland, brought out during the past year, by M. Ziegler.
These maps, the part only of a large survey, are on a scale of 2 1-2 inch-
es to amile, or 1-25,000. The lights are all thrown in perpendicularly, and
the altitudes of each terrace, valley, or mountain-top is inserted in num-
bers on a most exquisitely finished lithographic relief.
The great military map of France is also in active progress ; and 149
sheets out of 258 have been already published. As an illustration of the
gigantic nature of this work, it may be stated, that since this survey was
ON THE PROGRESS OF SCIENCE. 17
commenced in 1818, 2250 officers have been employed on it—ji.e., in
the geodesic and topograpical operations alone. _ The annual expense is
about $150,000 per year.
Mr Bartlett, Commissioner for running the boundary between the United
States and Mexico, has devoted much attention to the Indian vocabularies
of the districts visited during the progress of the survey. His researches
have corresponded exactly with those submitted to philological inquiry by
the lamented Albert Gallatin, with the addition of forty words discovered
by Mr. Bartlett during the progress of this Commission. The number of
words now ascertained is two hundred. Mr. B. will return accounts of
the Vocabularies of nineteen languages west of the Rio Grande. These
results will prove highly important and useful.
Considerable interest has been of late excited in Russia among the scien-
tific men in regard to the prosecution of meteorological investigations, and
at their request observations are now being constantly taken in England,
France, Prussia, and other parts of Europe. The Russian Government
has liberally encouraged the desire of its savants to investigate thoroughly
this important branch of science, which has hitherto not received so much
attention as others. It has established for them not fewer than ten magnetic
and meteorological observatories ; viz., one at St. Petersburgh, another at
Catharineburg in the Ural Mountains, two at Barnoual and Nertschinsk
on the Chinese frontier, one at Sitka in North America, one at Tiflis, anoth-
er at Pekin, two others at Bogoslowsk and Zlatouste on the western side of
the Oural mountains, and one at Lougan in the steppes of the Don. In
addition there are also a considerable number of stations in different parts
of the Empire. At all these establishments observations are taken at every
hour of the day and night.
An important step in relation to the system of weights and measures,
was recently taken by the Bank of England. The only weights to be here-
after used in the Bullion Office of that establishment will be ‘‘ the Troy
ounce and its decimal parts,’ — superceding by that change the present
system of pounds, ounces, pennyweights and grains. Practically the
change will be one of great convenience.
Among the scientific publications of 1852, issued by the United States
Government are the following: Report on the Iron Region and the Lake
Superior Mining District, by Messrs. Foster and Whitey, U. 8. Geologists ;
Part second, with volume of maps ; Patent Office Report for 1851, 2 vols.
Mechanical and Agricultural, by Thomas Ewbank ; Expedition to the
Great Salt Lake, by Capt. Howard Stansbury, U. 8. N.; Maury’s Winds,
Currents, and Sailing directions — new and enlarged edition ; Scientific
Report of the Dead Sea Expedition, Lieut, Lynch, U. S. N.; U. 8. Explor-
ing Expedition, Conchology, Dr. A. A. Gould ; Chart of the Arctic Re-
18 NOTES BY THE EDITOR
gions, with the explorations and track of the Grinnell Expedition ; Amer-
ican Nautical Almanac, Lieut. Davis; Annual Report of the Smithsonian In-
stitution; Report on the Geology of Wisconsin, lowa and Minnesota, by
Dr. D. D. Owen, U. 8. Geologist.
The Mechanical volume of the Report of the Patent Office contains a
Report on the Great Exhibition, by Edward Riddle, U. S. Commissioner,
and is by far the best publication, both as regards contents and typo-
graphy that has been issued by the Patent Office. The agricultural volume
is also superior to any that has preceeded it, and contains valuable papers
on wool and sheep-breeding by P. A. Browne, Esq., and on the American
Ruminants, by Prof. §. F. Baird; the remainder of the volume consist of
odds and ends, of little or no value, apparently made up by supplying suffi-
cient paste to agglutinate scraps of paper taken from all sources, to a
substratum of stout grocer’s paper. ‘The letter-press of the Conchology of
the U. 8. Exploring Expedition, by Dr. A. A. Gould, has been published
during the past year; the accompanying volume of plates, is also ina
state of forwardness. Of the published results of this expedition, twelve
volumes quarto and four volumes of plates, have already beenissued, leay-
ing fifteen yet in the course of preparation. The series already published
embraces the Narrative, 5 vols. and atlas ; Zoophites, 1 vol. and atlas;
Philology; Races of Men ; Mammals and Birds ; Geology and Mineralogy,
1 vol. with atlas ; Meteorology ; Charts ; Conchology. Those yet to ap-
pear will embrace the following subjects ; Herpetology, Ichthyology, Crus-
tacea, Medusz, Echinoderms, Annelids, Insects, Ferns, Fungi, Alge,
Botany, (Phanerogams,) Mosses, Geographical Distribution of Species,
Hydrography, Astronomy and Magnetism, Charts. Naturalists, generally,
who have been watching the progress of this great national work, will
learn with deep regret that all the undistributed copies of the first
seven volumes already published were destroyed in the same fire which
consumed the library of Congress in December, 1851. This is the more
melancholy, since but seventy copies were distributed.
The first volume of the American Nautical Almanac, for 1855, publish-
ed by authority, has been issued. It has been prepared under the super-
vision of Lt. C. H. Davis, and is a material improvement on the British
Nautical Almanac ; it having more correct lunar tables, which give more
accurate predictions, as tested in the case of the solar eclipse of July,
1851. At Washington, the British Almanac was in error for the beginning
of the eclipse, 78 seconds, and for the end, 62 seconds. The American
Almanac was in error for the beginning only 18 seconds, and for the end
only one second and a half. Theerrors exposed in this eclipse may give rise to
an error of from 15 to 20 miles in the determination ‘of the longitude at
sea by means of lunar distances, and to an uncertainty of twice that
ON THE PROGRESS OF SCIENCE. 19
amount. The possibility of such an error, arising from this source,
is removed in the American ephemeris. There are other points of su-
periority ; one of the principle being ‘‘ a more complete, full and accurate
table of latitudes and longitudes, particularly of American latitudes and
longitudes, than is now anywhere to be found,’’ and the other relates to
the tide tables and other practical information concerning the tides.
Under resolutions of the two Houses of Congress, the valuable report of
Dr. D. D. Owen on the geography of Wisconsin, Iowa, and Minnesota, (and
incidentally of the ‘‘ Mauvaises Terres ’’ in Nebraska,) has been published.
Its preparation reflects the highest credit upon the author, while the me-
chanical execution of the work is excellent, and forms a striking contrast
with the usual style adopted for Government publications. The report is
voluminous and constitutes a quarto of about 650 pages, with a volume of
maps. A report has also been submitted to Congress by Dr. Owen,
recommending a geological survey of Oregon and a special reconnoissance
of that singular region of Nebraska, known as the ‘‘ Mauviases Terres.’’
The interest awakened throughout the Scientific world by what has been
already made known respecting the latter district is very great. Itisa
tertiary deposite, abounding to a most extraordinary extent with the fossil
remains of extinct animals, some of which combine the distinctive char-
acteristics of several existing and distinct races. The discovery of an
entirely new family of mammalia, embracing eight new genera, is one re-
sult of the examinations already made by Dr. Leidy. In reference to this
region, Dr. Owen states that ‘‘ it is not too much to assert that since the
disclosures by the opening of the gypsum quarries of Montmatre, in
France, that made us first acquainted with those singular extinct fossil
races entombed in the Paris basin, no discovery in geology has divul-
ged such extraordinary and interesting results in palwontology.
The Legislature of Massachusetts have published during the past yeara
new and enlarged edition of Dr. Harris’ valuable work on ‘* Insects Inju-
rious to Vegetation,’’ and the Legislature of New York, ‘‘ A Report on the
Great Exhibition of 1851,’ by B. P. Johnson, Esq.
We would also in this connection call attention to the following scientific
works of great interest, issued during the past year in this country, by pri-
vate individuals. ‘‘ Mastodon Giganteus,”’ a description of the skeleton of
the Mastodon Giganteus of North America, with plates. This elegant and
costly work, the fruit of many years’ investigation, has been brought out
by Dr. J. C. Warren of Boston, and is intended for private distribution.
Several valuable geological and zoological memoirs have been publishd by
Isaac Lea, Esq., of Philadelphia, and a valuable ‘* Catalogue of shells
collected at Panama with notes on their synonomy, station and geographi-
cal distribution,’’ has been issued by the late Prof. C. B. Adams. The num-
3
20 NOTES BY THE EDITOR
ber of specimens of Mollusks collected by Prof. Adams, while at Panama,
amounted to 41,830, embracing 516 species, of which 160 were new and
undescribed. The department of mechanics and civil engineering has been
enriched by the publication of a work entitled ‘* The naval Dry Docks of
the United States,’’ by Charles B. Stuart, Engineer in Chief of the U.S.
Navy.
Two new scientific periodical publications have been started during the
past year ; ‘‘ The Annals of Science, being a record of the inventions and
improvements in applied science,’? conducted by Hamilton L. Smith,
Cleveland, Ohio ; and the ‘‘American Polytechnic Journal,’’ conducted
by Messrs. Page, Greenough & Co., Washington, D. C. Within the same
period, the Journal known as the New York Farmer and Mechanic has
been discontinued. '
A descriptive catalogue of the plants indiginous to is Ohio in the course
of preparation by James W. Ward, Esq., of Cincinnati.
Chemists and others interested in the progress of science will regret to
learn that the reprinting and translating into English of Liebig and Kopp’s
<< Annual Report of the Progress of Chemistry ’’ has failed, after a trial
of three volumes, for want of sufficient encouragement.
Under the auspices of the French Government, a Chinese work on the
production of silk has been translated by M. Julien, an eminent scholar
of Paris ; in consequence of which the Chinese method has been intro-
duced with great benefit into some of the silk-growing districts of France.
M. Julien has also translated a Chinese manual on the fabrication of por-
celain, which, it is anticipated, will be equally beneficial to that branch of
industry.
The Smithsonian Institution, at Washington, has continued silently, but
effectually, to enlarge the sphere of its influence and usefulness, and to
elicit from every part of the civilized world commendations, not only of the
plan of organization it has adopted, but also of the results it has produced,
By a judicious management on the part of the Regents, the funds of the
Institution have been increased by the interest on the original bequest,
until they now amount to a little more than 750,000.
ANNUAL OF SCIENTIFIC DISCOVERY.
MECHANICS AND USEFUL ARTS.
DRAINAGE OF THE GREAT LAKE OF HAARLEM.
Tue drainage of the great lake of Haarlem by the Dutch Govern-
ment, a work which stands unrivalled in the history of hydraulic
engineering, and which has been prosecuted with energy since 1848,
has been nearly completed within the past year. The origin and
history of this great enterprise is as follows :—
In the year 1539, the North Sea, long restrained by artificial dams
and dikes, as well as by some natural ridges of sand, suddenly burst
its barriers, and brought horror and desolation into the fertile flats of
North Holland. Twenty-six thousand acres of rich pasture land, with
meadows, cattle and gardens, were covered by the waves, and the
village of Nieuweinkirk was submerged and all its inhabitants lost in
the tremendous calamity. The inundation resulted at first in the
formation of four lakes, but the barriers of soft alluvial soil which
separated them were gradually destroyed, and the four lakes became
merged into one. The degradation of the shores also continued,
until, at the commencement of the 18th century, the waters covered
an area of 45,000 acres, with an average depth of 13 feet below low
water in the Zuyder Zee. This lake constituted what has since been
known as the Haarlem Meer, or Sea. The people of Holland saw
with much alarm, the rapid extension of its boundaries, and, at an
expense of about £33,000, succeeded in partially arresting its pro-
gress; an expense of about £4,000 per year was moreover entailed,
for the preservation and repair of the works of defence. More than
two centuries elapsed from the time of the first inundation before any
one began to dream of recovering this vast tract of country, and then,
for a long period, all plans proposed were deemed impracticable. At
length, on the 9th of November, 1836, a furious hurricane from the
west drove the waters of the Lake upon the city of Amsterdam, and .
4
ae ANNUAL OF SCIENTIFIC DISCOVERY.
drowned upwards of 10,000 acres of low land in the neighborhood.
On the 25th of December following, another hurricane from the east
drove the waters in an opposite direction upon the city of Leyden,
the lower parts of which were submerged forty-eight hours, and 19,000
acres of land were inundated. The enormous loss occasioned by these
two storms induced the government to determine on the drainage of
the Lake, and a credit of 8,000,000 florins was voted by the States
General. In May, 1840, a commission was appointed to superintend
the work.
The first operation was to cut a canal round the Lake, to isolate it
from the neighboring waters, and to afford the means of navigation to
the enormous traflic which previously passed over the Lake, amount-
ing to 700,000 tons per annum. ‘This canal was 37 miles long, 130
feet wide on the west side, and 115 feet on the east side of the Lake,
with a depth of 9 feet water. On the side next to the Lake, the
mouths of all water-courses entering it, were closed by earthen dams,
having an ageregate length of 3,000 yards, made in 10 feet depth of
water. Other great works were executed by enlarging the sluices at
various points, and in erecting powerful steam engines to assist in
discharging the water from the canal during the time of high water.
The water of the Lake has no natural outfall, being below the lowest
practicable point of sluicage. The area of water enclosed by the
canal was rather more than 70 square miles, and the quantity to be
lifted by mechanical means, including rain water and springs, leak-
age, &c., during the time of drainage, was estimated at 1,000,000,000
tons. In determining the motive power to be employed, two points
were to be kept in view; first, the cost of draining the Lake; second,
the cost of annual drainage; for, when once the work was accom-
plished, the site of the Lake could only be kept dry by mechanical
power. With the exception of a few steam engines, the wind had
hitherto been the motive power employed to work the hydraulie ma-
chines used in the Netherlands to keep the country dry. And the
power of 12,000 wind-mills, having an average aggregate power of
60,000 horses, is required to prevent two-thirds of the kingdom from
returning to the state of morass and lake, from which the indomitable
energy and perseverance of the Dutch people have rescued what is
now the most fertile country in Europe.
The Haarlem Meer Commissioners were convinced that the old
means must be laid aside, and new ones adopted to suit the magnitude
and peculiarities of their work. They accordingly determined to
erect three gigantic steam engines of a peculiar construction, which
was accordingly done, and the whole put in operation in 1848. These
engines consume but two and a half pounds of coal per hour, for each
horse power, and are capable of raising 112 tons of water 10 feet high
at each stroke, or of discharging 1,000,000 tons in 254 hours.
A short description of one of these engines may prove interesting.
It has two steam cylinders, one of 84 inches diameter, placed within
another of 144 inches diameter; both are fitted with pistons; the
outer piston is of course annular, and the two pistons are united to a
MECHANICS AND USEFUL ARTS. 33
great cross-head, or cap, which is furnished with a guide-rod, or spin-
dle; both pistons and cross-head are fitted with iron plates, and
together, with parts of the engine attached, have an effective weight
of nearly 90 tons. The Engine House is a circular tower, on the
walls of which are arranged 11 large cast-iron balance-beams, which
radiate from the centre of the engine. Their inner ends, furnished
with rollers, are brought under the circular body of the great cap,
and their outer ends are connected to the pistons of 11 pumps of 63
inches diameter each; the stroke of both ends is 10 feet; and the
discharge from the pumps 66 cubic metres, or tons, of water per stroke.
The action of the engine is very simple ; it is on the high-pressure-
expansive-condensing principle. The steam is admitted first beneath
the small piston; and the dead weight of 90 tons is lifted, carrying
with it the inner end of the pump balances, and of course allowing
the pistons to descend in the pumps.
The equilibrium valve then opens, and the steam in the cylinders
passes round to the upper surface of the small and annular pistons ;
puts the former in a state of equilibrium, and presses with two-thirds
of its force upon the annular piston, beneath which a vacuum is
always maintained: thus, the down stroke of the engine, and the eleva-
tion of the pump pistons and water, is produced by the joint action of
the descending dead weight in the cap and pistons, and the pressure
of steam on the annular piston. The engine has two air pumps, of 40 |
inches diameter, and 5 feet stroke each. The water is lifted by the
pumps into the canal, from which it passes off towards the sea sluices.
The total weight of iron employed for the engine, pumps, &c., is
640 tons. The cost of the machinery and buildings, £36,000.
The pumping was actively commenced in May, 1848, and has been
continuously carried on up to the present time. The Lake is now
nearly dry; much of the bottom is exposed, only large pools of water
being left. The remains of the unhappy village of Nieuweinkirk have
been found, with a mass of human bones, on the very spot where the
old charts of the province fixed its site. From May, 1848, up to
April, 1851, the Lake was lowered 7 feet 3 inches. The level reached
at the end of October of the same year was 9 feet 7 inches below the
original surface, or at an average rate of 4.79 inches per month. In
November, 1851, a great quantity of snow and rain fell, raising the
level of the Lake about four inches, and in December the weather
was still unfavorable, so that at the end of that month, the level stood
at 9 feet 5.38 inches below the original surface, showing a total gain
since April of 2 feet 5.58 inches, or 3.32 inches per month. This pro-
gress may appear to some inconsiderable ; but when it is recollected
that the lowering of the Lake one inch involved the raising of up-
wards of 4,000,000 of tons of water, and allowing for rain and snow
falling during these eight months, there could not have been less than
186,000,000 tons of water pumped up during that period, the per-
formance will appear great indeed. ‘To give a better idea of this, it is
stated that 186,000,000 tons of water are equal to a mass of solid rock,
one mile square, and 100 feet high, allowing 15 cubic feet to a ton.
34 ANNUAL OF SCIENTIFIC DISCOVERY.
The average progress has been less during the last year than during
the preceding ones, but this is readily accounted for, by the increased
lift of the pumps, and by the difficulty of forming the channels which
lead the water to them.
The annual drainage hereafter, is estimated at 54,000,000 tons of
water, which must be lifted on an average 16 feet; it may eccur,
however, that as much as 35,000,000 of this amount must be dis-
charged in one month, in order to preserve and render the space
formerly occupied by this Lake habitable.
CRYSTAL PALACE IN NEW YORK.
Ir having been determined to open an Exhibition of the Industry
of all Nations in the city of New York, during the summer of 1853,
the following plan of an edifice suitable for the purpose has been
adopted; the plan being furnished by Messrs. Carstensen & Gilde-
miester, of New York. The general idea of the edifice is a Greek
ross, surmounted by a dome at the intersection. Each diameter of
the cross will be 365 feet 5 inches long. There will be three similar en-
trances—one on the Sixth Avenue, one on Fortieth, and one on
Forty-second Street. Each entrance will be 47 feet wide, and that on
the Sixth Avenue will be approached by a flight of eight steps. Each
arm of the cross is on the ground-plan 149 feet broad. This is divided
into a central nave and two aisles, one on each side; the nave 41 feet
wide; each aisle 54 feet wide. On each front is a large semi-circular
fanlight, 41 feet broad and 21 feet high, answering to the arch of the
nave. The central portion, or nave, is carried up to the height of 67
feet, and the semi-circular arch by which it is spanned is 41 feet broad.
There are thus, in effect, two arched naves, crossing each other at
right angles 41 feet broad, 67 feet high, to the crown of the arch, and
365 feet long; and on each side of these naves is an aisle, 54 feet broad
and 45 feet high. The exterior of the ridgeway of the nave is 71 feet
The central dome is 100 feet in diameter—68 feet inside from floor to
spring of arch, and 118 feet to the crown; and on the outside, with the
lantern, 149 feet. The exterior angles of the building are filled up with
a sort of lean-to, 24 feet high, which gives the ground-plan an octagonal
shape, each side or face being 149 feet wide. At each angle isan octa-
gonal tower, 8 feet in diameter, and 75 feet high. Each aisle is covered
by a gallery of its own width, and 24 feet from the floor. The building
contains, on its ground floor, 111,000 square feet of space, and in its
galleries, which are 54 feet wide, 62,000 square feet more, making a
total area of 173,000 square feet for the purposes of exhibition. There
are thus in the ground floor two acres and a half, or exactly two acres
and 52.100; in the galleries, one acre and 44.100; total, within an
inconsiderable fraction of four acres. There are on the ground floor
190 columns, 21 feet above the floor, 8 inches diameter, cast hollow, of
different thicknesses, from half an inch to one inch thick; on the
gallery floor there are 122 columns.
MECHANICS AND USEFUL ARTS. 35
NAVAL DRY DOCK AND RAILWAY AT PHILADELPHIA.
THE Journal of the Franklin Institute gives the following description
of the U. S. Dry Dock and Railway, recently completed at Philadel-
phia; the dock and its appendages being the largest in the world.
The lifting power consists of nine sections, six of which are 105 feet
long inside, and 148 feet over all, by 32 feet wide, and 113 feet
deep; three of them are of the same length and depth as the others,
but two feet less in width; the gross displacement of the nine sections
is 10,037 tons, gross weight 4,145 tons, leaving a lifting power of 5,892
tons, which far exceeds the weight of any vessel yet contemplated.
The machinery for pumping out the sections consists of two engines
of 20, and two of 12 horse power. In connection with the sections
(which form the lifting power of the dock,) is a large stone basin, 350
feet long, 226 feet wide, and 12 feet 9 inches deep, with a depth of
water of 10 feet 9 inches at mean high tide. At the head of this basin
are two sets of ways, each being 350 feet long, and 26 feet wide.
These ways are level, and consist of the bed pieces, which are three
in number, and firmly secured to a stone foundation; the central way
supports the keel, while the side ways receive the weight of the bilge ;
these ways are of oak, and are finished off to a smooth surface. On
the top of the bed pieces or fixed ways, comes the sliding ways or
eradle, which are also 350 feet leng and 26 feet wide, so constructed
as to admit of being adjusted to the length of any vessel. The opera-
tion of the dock is as follows:—The sections are sunk so as to allow
the vessel to be floated in; as soon as she is secured in the proper
position, the pumps are put in operation, when the sections begin to
rise, and as soon as they come to a bearing on the keel, the bilge
blocks are run in until they fit the ship. When all is secure, the sec-
tions are pumped out until the keel is some two or three feet above
the water. If repairs that will only require a short time are contem-
plated, the vessel is kept en the sections, and no other portions of the
dock used. When this is accomplished, the sections are filled with
water, and rest on the bottom of the basin, which is of stone. Bed
ways are now laid on the sections in line with those before mentioned.
When they are secured they are greased, and the cradie is now slid
under the ship, and she is blocked up on the cradle, and the blocks on
the sections are removed. At this point of the operation a new instru-
ment of power is brought forward for the purpose of hauling the ship
from the sections to the bed ways in the Navy Yard. It consists of a
large hydraulic cylinder, having a ram of 15 inches diameter and 8
feet stroke, and a power of 800 tons. On the top of this cylinder,
and attached to it, are two vertical direct acting engines, with cylin-
ders 16 inches in diameter and 16 inches stroke, connected at right
angles to one shaft, on which are four eccentrics for working four
hydraulic pumps of 14 inches bore, and 6 inches stroke; the tank
which carries the water for the press is also on the top of the cylinder,
and forms the bed on which the pumps are secured. The boiler
which supplies these engines with steam, is on a sliding cast iron bed
4*
36 ANNUAL OF SCIENTIFIC DISCOVERY.
way, some 12 or 15 feet ahead of the hydraulic cylinder, and connected
to it by two cast iron rods. This boiler is of the usual locomotive
form, and has 85 tubes of 2 inches diameter, and 9 feet long. To get
ready for operation, the hydraulic cylinder is slid down to the edge
of the basin, its ram is run in, and a connection made by means of two
side rods of wrought iron from the cross head of the ram to the sliding
cradle which carries the ship. The central bed way has key holes
mortised through it horizontally, every 8 feet, and there are projec-
tions from the hy draulic cylinder, which have corresponding key holes
in them. Two cast iron keys, 24 inches wide, and 6 inches thick,
are slid through the key holes on small wheels; these keys secure the
cylinder to the central bed way; the engines and pumps being now
put in operation, a pressure is brought on the 15 inch ram, and as
soon as the pressure overcomes the resistance, the vessel must move.
As soon as the vessel has been moved 8 feet, the keys which hold the
cylinder to the central way are withdrawn, and by means of a screw
which is attached to the head block of the ram, and driven from the
engine, the cylinder and boiler are in their turn rapidly slid ahead,
(the water in the cylinder being allowed to escape into the tank,)
when the cast iron keys are again slid in place, and the vessel moved
another 8 feet. To push the vessel off, the cylinder and appendages
are moved to the head of the ways, put on a turn-table and reversed,
when it is again brought down to the cradle, and the cylinder being
secured as before, the head of the ram is applied directly to the cradle,
and the vessel shoved back on to the sections, which requires the same
time and power as to haul them off. The capacity of this dock ex-
ceeds that of the stone docks at New York, Boston, and Norfolk,
combined, for united they can take but three vessels, while here, two
of our longest war steamers may be hauled out on the ways, and two
frigates lifted on the sections. The advantages that must ‘result from
the facilities of repairing a vessel elevated into light and air over one
sunk in a stone dock, are very great, and have only to be seen to be
appreciated.
BEACON ON ROMER SHOALS.
A NEW beacon, having some peculiarities of structure, has recently
been erected on ‘the Romer Shoals, at the entrance of New York
Harbor, under the direction of Mr. J. W. Lewis, C. E. The Beacon
is built on the southeast crest of the Romer Shoal, about two miles
from Sandy Hook Light, in 13 feet water, and is in plan an octagon
20 feet in diameter and 50 feet in height. The principle of its con-
struction consists in screwing into the sand of the shoal, at each angle
of the octagon, and in the centre, one of Mitchell’s screw piles; the
blade of each screw being 2 feet in diameter, and entering the sand
toa depth of 10 feet; attached to the screw are nine wrought-iron
shafts or piles, each 6 inches in diameter and 324 feet in “length,
extending to a height of 83 feet above high water mark; on “the
top of these piles, heavy Cast iron sockets are keyed, to ahdek are
MECHANICS AND USEFUL ARTS. 37
attached also by keys the cast iron shafts, which rising form the pile
heads, and uniting in a centre frame at the tops, form the supporting
braces for the basket frame, or distinctive mark of the Beacon, which
is secured to a prolongation of the centre pile at a height from the
level of the sand of 63 feet. The whole of the piles and shafts are
securely braced and counter-braced by wrought iron tie-rods, keyed
to the sockets, rings or pile heads, forming altogether one of the most
efficient systems of frame work ever erected for such a purpose. The
whole weight of the structure is but 75 tons, and it cost the Govern-
ment but $10,000, whereas a stone structure would not cost less than
$35,000, that being the cost of a stone beacon on the same shoal, and
but 40 feet in height.
GREAT TUNNEL IN HUNGARY.
OnE of the longest, if not the longest tunnel in the world, is now in
a forward state of completion. It is situated in Hungary, and leads
from the shores cf the river Gran, not far from Zarnowitz, to the
mines in the Schemnitzer hills; it is two geographical, or about ten
English miles, long; it is intended to answer the double purpose of a
channel to drain off the water accumulating in the works, and of a
railway to transport the ore from the mines to the river.
MODERN CYCLOPEAN WALL.
A RECENT number of the Allgemeine Zeitung contains an interesting
account of a visit which the writer had made to inspect the progress
of building a wall in the manner called Cyclopean, near Kiel, in
Schleswig-Holstein. He considers the effect of the work and the
style of execution far superior to any of the numerous remains called
by the same name which he had seen in Italy, and goes so far as to
give it the preference over any other kind of wall, so far as the plain,
vertical surface of the material, apart from ornamental accessories, is
concerned. He thinks that the polygonal stones, exerting their pres-
sure in all directions, must insure stronger work than squared stones,
however closely jointed, which only act in the direction of gravity.
Indeed, the imnumerable many-sided and multangular stones of all
sizes seem run together into one compact mass, of which neither time
nor age will get the better. Neither mortar nor any other means of
binding the stones together is employed ; but the greatest care is taken
im fittme the granite blocks one into the other, the vacant spaces in
the wall as it is carried up being accurately taken off with a lead tape
forced with a hammer into all the angles of the openings, and then
applied to the flat hewn face of the block best suited, and next to be
brought to its proper shape by the workman. From the workmen he
learned that the directions given them by the architect were, “ Five-
sided and six-sided blocks, seldom four-sided; straight lines, obtuse
angles, joint upon angle and angle upon joint; all according to the
lead tape, and only inclined junctions.” In fact, all the junctions be-
38 ANNUAL OF SCIENTIFIC DISCOVERY.
tween the blocks were found to be in every gradation between the
perpendicular and the horizontal, without coinciding with either of
them. In this obliquity of the jomts the author detected the arch
principle of construction as applied to the work, and the workmen
pointed out to him, that each stone either pressed or supported, with
every one of its sides, however numerous. Generally, the writer
holds this polygonal or Cyclopean kind of building to be especially
applicable in, first, hydraulic works, as it offers nowhere a continuous
joint to the water; second, in fortifications; third, for railways in
substruction and steep coverings, and in the cellar story and even in
the next story of large buildings and palaces. In these mortar would
be used, not as a means of connecting the stone, but only as pointing
to the joints, so that the immediate contact of the stone should not be
interrupted. In conclusion, the writer recommends the adoption of
this method of building according to determined and clearly defined
principles and rules, as altogether practical, wherever the material for
polygonal blocks is found,—a method which is at least to us a new
one, and not simply a more careful execution of the long-used rock
walls, or an ornamental imitation of
WHITE’S WOODEN SUSPENSION BRIDGE.
By this invention the Patentees claim to have solved the problem
of spanning broad and rapid rivers with a structure which requires no
piers, yet is suitable for railroad purposes, and can be built at a rea-
sonable and practical cost. The principal feature of the invention is
the substitution of wooden stringers constructed of boards cemented,
dowelled and bolted, for iron chains or wire cables. There is no
question as to the strer ngth which may thus be attained; a reference
to any tables of the streneth of materials will show that the tensile
strength of hard wood is much greater in proportion to its weight than
bar iron. Any number of these stringers considered necessary for a
given structure may be placed one above another and each be ‘firmly
anchored beyond the points of support, by back stays fastened into
the abutment; the only question seems to be, whether the stringers
can be locked to the back stays with a suflicient degree of firmness.
The principal advantage whic +h is claimed for this invention is that it
can be entirely freed from that tendency to vibration, which is fatal to
the use of the iron suspension bridge upon railroads. ‘The means used
to effect this are very simple, and certainly seem to be effectual.
Perpendicular oscillation is partly overcome by springing a direct arch
from one abutment to another which in the centre rises nearly to the
road bed, and which is firmly connected with the stringers above by
the suspension rods which sustain the floor; and lateral oscillation is
overcome partly by making the bridge diminish in width from the
extremities to the centre; “while all possibility of vibrations would
seem to be avoided by the mode of cover ing. This is done as follows:
the entire structure 1s covered with a double di: agonal boarding, and
the planks of the road bed are also laid double, crossing the floor. Joists
also diagonally.
MECHANICS AND USEFUL ARTS. 39
The weight of the structure decreases in a geometrical ratio as the
distance from the towers increases, so that at the centre, though the
full strength of the stringers and the direct arch below them is retained,
the weight of the structure is diminished to an exceedingly low point.
As to economy of construction this bridge can be surpassed by none,
especially where a great span is required. ‘There is no heavy timber,
the entire structure being built of plank and boards. No piers are
necessary, the only stone work being the laying the abutments, etc.
The manner of constructing the stringers speaks well also for their
durability, being put together with oil cement between each_board
which will render decay next to impossible; it is very well known
that wood prepared in this way has been excavated from the ruins of
old cities, after being buried more than three thousand years, ina state
of perfect preservation —airoad Journal.
FLYING RAILROAD BRIDGE.
Tue Scientific American states that C. B. Hurcurnson, of Water-
loo, N. Y., has invented and taken measures to secure a patent for a
valuable improvement on Railroad Bridges for navigable waters.
The object of the invention is to have a bridge perfectly open and
free at all times for vessels to pass, except the few minutes required
for a train to pass over, and to carry over trains expeditiously and
safely. A certain number of piers or abutments are built in the river,
with space between them for the passage of vessels. Instead of having
a stationary platform to the roadway extending across on the piers,
he employs a flying or running platform, which carries the train
spanning and springing over the successive spaces between the piers
from the one side to the other. There are tracks or rails on all the
piers, and on the flying platform there are wheels that run on the
tracks, like a long railroad car. The length of the flying platform is
in proportion to the width of space between the abutments, so that it
will be impossible to overbalance it while springing from one pier to
the other like a sliding drawer. The flying train is stationary at one
side or the other, when the train is not passing. It is to be propelled
across by having stationary power on itself, or to have it so constructed
that the locomotive of a train may propel it across. It may be called
“a flymg railroad bridge.”
THE GENESEE HIGH BRIDGE.
TuE bridge by which the Buffalo and New York Railroad crosses
the Genesee river, near Portageville, is one of the most gigantic
structures in this country, being eight hundred feet in length, and
two hundred and thirty-four feet above the stream. About one hun-
dred feet below the bridge is a perpendicular fall in the river of
sixty-six feet; hence, from the top of the bridge to the bed of the
river below the fall, it is three hundred feet. The Genesee High
Bridge towers above all similar structures in America; even the sus-
40 ANNUAL OF SCIENTIFIC DISCOVERY.
pension bridge at Niagara is only two hundred and thirty feet high,
and no longer than this. Some more definite idea of this immense
structure may be gathered from the following statistics ; — rising from
the bed of the river are eight stone abutments, each thirty feet high.
On these rest the truss work of wood, extending one hundred and
ninety feet above the abutments. On the top of this structure stands
the bridge itself, which is fourteen feet. high. The base of the truss
work is seventy-five feet in width, and the top of the bridge, twenty-
five feet. To furnish the timber for it, over two hundred and fifty
acres of land have been required. More than a million and a half *
feet of timber, board measure, have been used in the construction,
together with sixty tons of iron in bolts. The work was completed in
eighteen months at a cost of about $140,000. The bridge was
designed by Mr. H. C. Seymour, and so perfect is the model, that from
the supporting truss-work any piece of timber can be removed, in
case it becomes defective, and a new one placed in its stead, without
affecting the strength of the work, or displacing any other timber.
The truss-work is composed chiefly of timbers placed on their ends in
an upright position, and so braced, and counter-braced, and the whole
structure made so firm, that it is estimated it will sustain with safety
twenty times the weight of any train that can pass over it.
NOVELTIES IN SHIP BUILDING.
THERE is now building at the Clyde, at Carts’ Dyke, an immense
iron steamship, to be called the Atrato, of much greater capacity and
considerable larger, than that leviathan steamer, the Great Britain ;
indeed so large is the Atrato to be, that the Cunard steamship Arabia,
of 2,400 tons, might be put inside the new steamer, with a good deal
of room to spare.
The origin of the Atrato is somewhat singular. Her builders, hay-
ing constructed the engines (of 850 horse power) for the Demerara,
which got jammed across the Severn, and had to be broken up in
strains she received, got an order from the West India Mail Steam-
ship Company, to whom the Demerara belonged, to build a vessel of
iron instead of wood, to which the new engines might be adapted.
They were permitted to modify the design of the hull so far as the
length was concerned, although the retention of the original paddle-
shafts compelled an adherence to the same breadth of beam at that
line as the original vessel. The result has been that the engineers
submitted plans which were approved of, and are now being carried
out in the building of the largest vessel ever afloat. The entire length
of the keel is laid resting on blocks. The enormous bar is in nine
pieces, joined by scarf-joints, and firmly riveted together. The stern
post is in one piece, and so is the stem, which runs for about ten feet
into the horizontal keel. The stem alone weighs 65 ewt. Only one-
half of the ribs or frames are as yet in place, and even with the long
length of bare keel terminated by the stem standing up some forty
feet or more, the enormous dimensions of the vessel can hardly be
MECHANICS AND USEFUL ARTS. 41
appreciated, but they will be understood from the principal measure-
ments of the Atrato, and those of the largest ship-of-war in the British
service, the Windsor Castle, now on the stocks at Pembroke Dock
Yard, which is stated to be “ the largest vessel in the world.” Their
principal measurements are :
THE ATRATO. Feet. WINDSOR CASTLE. Feet.
Length of keel, 310 | Length extreme, 278
Do. of keel and forerake, 340 | Do. of keel and forerake, 2404
Breadth of beam, 52 | Breadth, 25
Depth of hold, 34 | Depth of hold, 24
It would thus appear that the Atrato will be about 60 feet longer
than the “largest vessel in the world,” and about 10 feet deeper in
the hold ; the only dimension by which she is exceeded by the Wind-
sor Castle being in the breadth of beam, and in that particular the
builders were bound down by the existing machinery, which as above
stated, was made for the Demerara, a much shorter vessel. The floor
of the new steamer will have a rise of four feet at the flattest part, so
that the easy curves afforded by such a sweep of midship section,
combined with the enormous length, can only be appreciated by those
conversant with ship-building. There are to be four decks; the upper
or spar deck being flush from stem to stern, and presenting a prom-
enade of about 330 feet in length, by about 38 in breadth. The hull
is to be divided into seven compartments by six iron water-tight bulk
heads, extending from the keel to the main deck. This will give
rigidity to the hull, and afford security against sinking.
A new and beautiful steamer, called the “ Light of Heaven,’ has
been recently launched at Glascow, for the Pacha of Egypt. Her
engines are of 300 horse power, and of the most beautiful make and
fish. The fittings of the interior are gorgeous beyond comparison,
consisting of papier-mache ornaments and rich brocaded silks, which
will alone cost $125,000. The ceiling of the saloon will be divided
intoa number of panels of rich white silk, having upon the centre the
device of the crescent and the star, encircled with most elaborate and
richly colored wreaths of Eastern flowers of silk. The borders of
the panels are to be richly ornamented Raffaelesque decorations.
Other portions of the ceiling between the beams, are to be covered
with a silk of a white ground and groups of flowers of gold thread.
The panels on the sides are of papier-mache. The ottomans in the
saloon are covered with cloth of gold, formed with a warp of gold and
a weft of glass thread. The awning of the deck is to be formed of
entirely brocaded silk, the fringe being of gold and costing twenty
guineas per yard. ‘The cost of the silk for the awning alone will not
be less than $10,000.
A new steamer has recently been built in England, with the follow-
ing remarkable proportions. Her length exceeds 200 feet; while her
breadth is little more than 13 feet. She is fitted with engines of 80
horse power. Her wheels, which are on the feathering principle, are
42 ANNUAL OF SCIENTIFIC DISCOVERY.
remarkably small, and, to a casual observer, appear totally adequate
to the propulsion of a boat of such great length; this, however, we
are assured is not the case.
STEAMBOAT PROPELLERS.
THERE have been brought to light, recently, two new inventions:
the one adapted to give increased speed to screw, the other to paddle
navigation. Mr. G. Bovill’s screw propeller, described in the Mining
Journal, is an entirely novel affair. Its central portion is fitted up
with a hollow sphere, occupying one-third of the entire diameter of
the propeller, and the blades are made narrower at the outer extrem-
ity than at the base. The blades are also made to revolve, so as to
admit of the pitch being altered to meet the various circumstances of
speed and power. Froma table of the comparative result of trials
on three different boats, it appeared that important advantages have
been obtained from the new propeller.
The paddle invention is that of a Liverpool shipwright named
Hampson. metal and one liquid.
Hitherto it had been laid down as a law, that with the platinum and
acid solution, two gases (oxygen and hy drogen) were necessary to
obtain this result ; only the elements of the battery formed with the
chloride of gold, have a feebler intensity of action than the usual
gas pairs.
5th. The solution of chloride of gold, chemically pure, may there-
fore be considered definitively as superseding the acid solution and
oxygen in the gas battery. The remarkable effects that are manifested
in this circumstance should not be confounded with those that would
be produced by certain gaseous solutions or liquids, such as nitric
acid absorbing hydrogen at the ordinary temperature, without the
apphance of platinum.
ON THE SPHEROIDAL STATE OF BODIES.
AT a lecture before the Royal Institution, England, M. Boutigny
remarked that the simple phenomena of the subject would seem to
have necessarily attracted attention from the most ancient times, and
endeavoring to discover some record of the fact, he had found the
possible expression of it in the Wisdom of Solomon, xix.’ 20:—
“ The fire had power in the water, forgetting his own virtue ; and the
water forgat his own quenching nature.” Eller and Leidenfrost,
however, about the middle of the last century, first truly observed
the simple phenomena; but nothing had since been done, either to
increase our knowledge of the singular facts, or to suggest an explan-
atory theory concerning them. "M. Boutiony then exhibited the
experiments which he had recently made. He placed some nitrate
of ammonia, which is inflammable at a very low temperature, upon a
capsule of platina, greatly heated, but it assumed the spheroidal con-
_ dition without ignition. On removing the lamp, however, and when
the substance was cooled down to the ordinary temperature, it ignited.
The beautiful violet colored vapor of iodine was produced also “in the
same manner, as also distilled water, which passed into steam as soon
as the metal disc was sufficiently cooled. He then proceeded, by
experiment, to show how the fact as relates to water, readily explains
the occasional bursting of steam boilers, when, by the cooling of the
boiler after the introduction of water into it when overheated, the
contents are immediately and violently converted into steam.
202 ANNUAL OF SCIENTIFIC DISCOVERY.
The singular fact of the universal decrease of temperature in the
liquid, when in a spheroidal state, was then adverted to. Numerous
experiments had proved it. This phenomenon has given a result
wholly unforeseen, and most remarkable. The chemist knows that
liquid anhydrous sulphurous acid boils at a very low temperature.
M. Boutigny, in submitting this acid to similar conditions in a slightly
humid atmosphere, the acid first took an opaline appearance, then lost
its transparence, and finally solidified. The solid formed was ice!
As a variation of this experiment, some drops of water were thrown
upon the acid while in the spheroidal state, and the water immediately
congealed. In order to demonstrate that liquids, when im this state,
do not touch the surface of the metal, some concentrated nitric acid
was dealt with, but it did not act upon the copper disc on which the
experiment was made, until the copper was cooled. A cylinder of
silver, at a white heat, was also plunged into water; it was distinctly
observed for many seconds (the room being darkened) not to be
affected by the surrounding medium. The lecturer then insisted that
it was not alone to such physical results that we are to look on the
curious phenomena he has unveiled, but to the new method of chem-
ical analysis and synthesis which they suggest. He has thus found
that some bodies, which are not decomposed at boiling heat, are so
when put in a spheroidal state ; while others, placed in contact under
the influence of this new molecular state, produce new combinations.
When wine and alcohol are in a spheroidal state, their elements are
found to be in a new order; ether is decomposed, and disengages
aldehyde; chloride of ethyle decomposes nitrate of silver; ammonia
dissolves iodine, &e.
PREPARATION OF MAGNESIUM.
BunsEN has observed, that fused chloride of magnesium is readily
decomposed by the voltaic current, so that it is possible, in a short
time, by the employment of a battery of a few pairs only, to obtain a
mass of metal weighing several grammes. For the preparation of the
chloride, Liebig’s method is recommended ; particular care must be
taken, however, in drying the mixture of magnesia and sal-ammoniac,
to avoid the formation of a basic chloride. As a decomposing cell,
Bunsen employs a porcelain crucible divided into two parts by a dia-
phragm reaching to half the depth of the crucible. In this manner
the chlorine set free at one electrode is prevented from again com-
bining with the magnesium deposited upon the other. The electrodes
used are of carbon, in the form in which it is prepared for Bunsen’s
battery ; into the surface of the negative pole kerfs are cut to prevent
the magnesium set free from floating to the surface of the fused liquid
and there taking fire. To determine the quantity of magnesium
formed in a given time, the author introduces a tangents-compass into
the circuit, and deduces by a well known formula the relation between
the chemical and the magnetic effects of the current, so that the latter
being observed, the former may easily be calculated. Magnesium, as
CHEMICAL SCIENCE. 203
obtained by electrolysis, is upon a fresh fracture sometimes faintly
crystalline in large plates, at others fine grained; in the first case, it
is silver-white and very brilliant, in the last more bluish gray and
without lustre. Its hardness is nearly that of cale-spar. It fuses at
a moderate heat; in dry air it is wholly unchangeable, and does not
lose its lustre ; in moist air it soon becomes covered with a coating of
magnesia. Heated to whiteness in the air, it takes fire and burns
with an intense white light; the evolution of light by combustion in
oxygen is of unusual intensity — about 500 times that of a wax can-
dle. The metal decomposes pure cold water very slowly, acidulated
water rapidly. Thrown upon aqueous muriatic acid the metal
instantly ignites. Concentrated sulphuric acid dissolves it slowly; a
mixture of nitric and sulphuric acids has no action in the cold. The
density of magnesium was found to be 1.7430 at 5° Centigrade.
Calculated from this, the atomic volume of magnesium is 86, or
exactly double that of nickel. The metal, as obtained by electrolysis,
may easily be filed, bored, sawed, or somewhat flattened by hammer-
ing, but is hardly more ductile than zinc, at ordinary temperatures.
The magnesium obtained by means of potassium, contains a small
quantity of that metal, and is ductile; that reduced by electrolysis,
almost always contains traces of aluminum and silicon.— Ann. der
Chemie und Pharmacie, \xxxii. 137.
TITANIUM AND ZIRCONIUM IN MINERAL WATERS.
Dr. Mazanpe, of Valence, states that he has detected in the mine-
ral waters of Neyrac, France, both titanium and zirconia. He had
previously announced his having found in the same waters, molybde-
num, tin, tungsten, tantalum, cerium, yttrium, glucinium, nickel, and
cobalt. — L’ Institut, No. 964.
ON THE PASSIVE STATE OF METEORIC IRON.
WoHLER states, that he has observed the curious fact, that the
greater portion of the meteoric iron he has had an opportunity of
examining, is in the so called passive state, that is to say, it does not
reduce the copper from a solution of the neutral sulphate of copper,
but remains bright and uncoppered therein. But if touched in the
solution with a piece of common iron, the reduction of the copper
commences immediately upon the meteoric iron. It also becomes
active instantaneously on the addition of a drop of acid to the solution
of copper; but if the reduced copper be filed away, the new surface
is again passive. I convinced myself by experiments on meteoric
iron, which had never been in contact with nitric acid, and neverthe-
less was passive, that this state could not have been produced by the
corrosion of the surface by the acid, for the production of the Wid-
mannstattean figures. I thought first that this deportment might be
employed as a means of distinguishing true meteoric iron; but it soon
appeared that some undoubtedly genuine meteoric iron was not in this
18*
204 ANNUAL OF SCIENTIFIC DISCOVERY.
state. Seven specimens, from different parts of the world, examined,
were found to be passive ; six reducing, or active ; and four which do
not become coated with copper immediately, but on which the reduction
gradually commences, after a longer or shorter contact with the
cupreous solution, and usually from one point, or from the margins of
the fluid.
These peculiarities appear to have no connection either with the
presence of nickel, or the property of forming regular figures on
corrosion. JI also found that an artificially prepared alloy of 1ron and
nickel, which on corrosion acquired a damasked surface, reduced the
copper from solution in the same manner as common iron. Whether
this state is proper to all meteoric iron on its reaching the earth, and,
as may have happened in the case of the active kinds, have only been
lost in the course of perhaps a very long period of time, and what
probable opinion can be formed of these phenomena must be settled
by experiments and observations of a more extended nature. —
Pogg. Ann.
PRODUCTION OF BRITISH IRON.
Mr. SAMUEL BLACKWELL, an eminent English iron-master, esti-
mates the gross annual production of iron in Great Britain to be
upwards of 2,500,000 tons. Of this quantity, South Wales furnishes
700,000 tons; South Staffordshire, 600,000; and Scotland, 600,000.
The remainder is divided among the various smaller districts. The
number of furnaces in blast in England and Wales during the year
1850, was 336.
ON THE COMPOSITION OF WOOTZ, OR INDIAN STEEL.
Woorz, or Indian Steel, has for a long time been held in high
estimation from the supposition that the celebrated scimitars of
Damascus were made from it. A chemical examination was made of
wootz in 1819, by Faraday, who came to the conclusion that the
peculiar excellence of this steel depended chiefly on a small quantity
of aluminum combined or alloyed with it; two separate analyses
yielding 0,0128, and 0,0693 of aluminum. On the other hand, Kar-
sten could only detect dubious traces of aluminum in wootz, and
Elsner attributed the improvement in the quality of the steel pro-
duced in Faraday’s experiments, not to the small quantity of foreign
metals, aluminum, silver, platinum, &c., alloyed with them, but
entirely to the operation of remelting, and this seems to be the prac-
tical conclusion come to at Sheffield, Eng., at the present day. The
fact that the alloys produced by Faraday possessed a perfectly dam-
asked surface, closely resembling wootz, seems to militate against
the conclusions of Elsner. M. Breaut attributes the damask
of the Eastern blades to the crystallization of two distinct com-
pounds of iron and carbon, and draws a distinction between the
oriental damask, and that produced by alloys of steel. This
CHEMICAL SCIENCE. 205
is confirmed by the experiments of M. Anocoff, a Russian
engineer, published a few years since in the Annuaire des
Mines de Russie. He pretends to have produced blades so nearly ©
emulating those of Damascus, as to allow of their being bent
at a right angle, and capable of dividing a film of gauze floating
in the atmosphere. Mr. Henry, of England, has recently made seve-
ral analyses of wootz, and failed to detect in it the presence of alu-
mina; he, however, found sulphur, silicon, and arsenic, in apprecia-
ble quantities.
SEPARATION OF SILVER FROM OTHER METALS.
The following is an abstract of the specification of a patent granted
to Alexander Parks, of England, for improvements in the separation
of silver from other metals. The invention consists—first, of certain
improvements in the mode of employing zinc for the purpose of
separating silver from lead. Secondly, of improvements in separa-
ting the silver from the alloy of zinc and other metals thus produced.
The patentee states that he has found when lead contains 14 ozs. of
silver to the ton, the most suitable proportion is 1 per cent. of zinc;
thus, for each ton of lead containing 14 ozs. of silver, he uses 23 lbs.
4 ozs. of zinc; for each ton of lead containing 21 ozs., 33 Ibs. 6 ozs. of
zinc; and for each ton of lead containing 28 ozs. of silver, 44 Ibs. 8
ozs. of zinc. The process is conducted as follows :—The lead, in the
state it is received from the smelting-house, is melted in an iron pot,
and heated to the temperature of melted zinc ; the zinc, in a melted
state, is then added, and the whole well mixed; the contents of the
pot are then stirred in the usual way, with a piece of green wood, to
remove any impurities ; it is then cooled; the alloy of silver, zine &c.,
rises to the surface, and is removed by the means of ladles pierced
full of holes. A previous assay of the lead will indicate the right
proportion of zinc to be employed; a larger quantity will be found
necessary in cases where the lead is very impure. The lead which
has thus been desilverised by means of zinc, often retains a small
portion of that metal, which has the effect of rendering it brittle : this
defect is remedied by the following process :—
The melted lead is run into a reverbatory furnace, and raised to a
dull red heat, when the zinc rises to the surface and becomes oxy-
dised ; the furnace is then tapped and the lead run into an iron pot,
when it is stirred with a piece of green wood, to remove any oxide of
lead which may have formed; after which, it is ladled into moulds in
the usual way. By this means, 3 tons of lead may be deprived of the
zine it contains in the course of from 2 to 24 hours; the surface of
metal exposed being from 25 to 30 square feet. The oxide of zine
remains in the furnace, whence in may be afterwards be removed.
In order to separate the silver from the other portions of the alloy
the patentee proceeds as follows :—The silver is first concentrated by .
removing as much of the lead as possible, by placing it in an iron pot,
the bottom of which is preforated with holes, the top being, at the
206 ANNUAL OF SCIENTIFIC DISCOVERY.
same time, covered with a tight-fitting lid; heat is then applied, and
when the metal is nearly red hot a large quantity of the lead in the alloy
will escape, and thus the mass of alloy will become much reduced in
size. If care be taken that the heat be not carried to too great a
degree, the lead which thus escapes will be found to contain but a
very minute quantity of silver. The alloy thus concentrated may
next be treated by either of the following methods: First the alloy is
placed in closed retorts, or muffles, and exposed slowly to a low heat,
and continually stirred, by which means the metal is partly oxydised
and falls down in fine powder ; the heat is then increased, and when
all the metals (except silver) in the alloy become completely oxy-
dised, the whole is transferred to tanks containing dilute sulphuric
or muriatic acid, which dissolves the oxides, leaving the silver in the
metallic state. Secondly, the alloy is placed in suitable retorts, or
distillatory apparatus, formed of Stourbridge clay, or of iron set in
clay retorts and lined with powdered bone and charcoal, and by which
means the zinc is distilled off in the usual way, after which the back
part of the retort is tapped and the residue treated by cupellation, in
the way well known.
By the process of desilvering lead, known as that of Pattinson’s,
many of the English lead mines which are now workable with profit,
must otherwise have been abandoned. The chief ore from which lead
is extracted is that known as galena, or the sulphuret of lead, furnish-
ing from 75 to 80 parts of the metal according to purity. It usually,
though not always contains silver in various proportions. Upon the
quantity of silver often depends the profitable raising of the ore.—
Previous to the invention of Mr. Pattinson, about 20 ounces of silver
in a ton of lead were required to render the extraction of that metal
worth the cost; since then as little as three or four ounces in the ton
of lead will repay extraction. Now, as so many ores contain small
quantities only of silver, the importance of the process is evident.
In a scientific point of view it is one of much interest, as it consists in
so conducting the work that portions of lead can be crystallized, by
which the silver becomes excluded, in the manner in which in many
crystallizing processes, foreign substances are excluded during crystal-
lization, thus by degrees a mixed mass of silver and lead is left,
extremely rich in the first metal. When this richness in silver arrives at
the point desired, that metal is extracted in the usual manner by
cupellation. In one of the lead works in England, in which arrange-
ments exist by which the fumes of the furnaces are prevented from
escaping, the damage to the surrounding country is obviated, and lead
to the amount of 33 per cent. is obtained from the deposits or “ fume.”
ZINC OXIDE AS A PIGMENT.
Tuts branch of industry has already arrived at much importance
in this country through the action of the New Jersey Zinc Company,
whose works are dependant upon the red zine ore and Franklinite so
long known to mineralogists. The products of this manufacture are
CHEMICAL SCIENCE. 207
chiefly two, the white oxide, dry or ground in oil, and of several
grades of quality, and the colored pigments formed mainly by grind-
ing the raw ore. The zine white is made in large oven-shapen retorts
of brick, around which the heat of an anthracite fire is conducted
both above and below. These ovens are very low, but of large superfi-
cial area. A wide pipe of sheet iron connects each with a very large
horizontal tube in which a current of air is kept moving by the
revolution of a fan-wheel. This current flows first through the
retorts, furnishing air to burn the zinc and means of transportation to
the oxyde formed, which is delivered by the current in large cooling
chambers. The charge in the ovens is one thousand pounds of
crushed red zinc and Franklinite mixed with its own bulk of the dust
of anthracite coal. The heat is raised to full redness and so managed
as to be hottest on the upper surface of the charge. Reduction of the
zine is probably effected by the action of the hot carbon, but the
metal is immediately burned by the atmospheric oxygen drawn in by
the mechanical action of the blower before named. All the volatile
products of this chemical action are drawn through the long tubes
and partly delivered into capacious sacks of closely woven muslin
suspended in well ventillated apartments. The heat retained by
the oxide is not sufficient to scorch the muslin. From the proper
openings in the sack the material is collected in casks. In the retorts
the residue consists of undecomposed Franklinite and of metallic iron
mingled with unchanged carbon. When the best results are obtained
the ore yields half its weight of oxide. This oxide is never quite pure,
as a small quantity of dust and foreign materials are drawn in with
the current of air. Dissolved in acetic acid this residue remains on
the filter and perfectly pure carbonate of zinc may be precipitated
from the acetate. Chemists will regard this as an important means of
procuring chemically pure zinc.
It is curious that the carbonate of zine obtained by precipitation
when mingled with oil has no “ body,” or does not cover the surface
on which it is laid, while the anhydrous oxide obtained in the furnace
process covers very well. Water added even in small quantity to the
zine oxide ground in oil, will cause the whole mass to solidify. The
greater cheapness of zinc oxide, its freedom from poisonous quality, and
the fact that sulphuretted hydrogen does not discolor it, are causes
which must -lead to the general use of this material in place of
lead. The New Jersey Zinc Co. are at present manufacturing about
5,000 pounds of zine oxide daily, from 18 furnaces or retorts, only
one-half of which are usually in operation at the same time. The
colored paints formed by grinding the crude ore, are sold at very
cheap rates and found to possess remarkable power to prevent the
oxidation of metallic iron.—Silliman’s Journal.
208 ANNUAL OF SCIENTIFIC DISCOVERY.
ON THE PRODUCTS OF SMELTING FURNACES, AS PROOFS OF GEO-
LOGICAL HYPOTHESES.
A PAPER on the above subject was read before the German Scien-
tific Association at Wiesbaden, by Prof. Leonhard, of Heidelberg, of
which the following is an abstract: “ For a long period of time,”
began the author, “ no particular attention was devoted to scoriz and
slags, the secondary productions of all smelting works. As useless and
unprofitable, they were thrown aside after the metal had been extrac-
ted, as the miner in his shaft gets rid of all waste and unproductive
rock.” He then showed how, until lately, the study of lavas them-
selves was neglected. ‘The same was the case with scoriz and slags ;
they are not, as was formerly supposed, ‘“ accidental combinations of
several materials, nor arbitrary mixtures of earths and metallic oxides,
which, however occurring again and again in this or that smelting
produce, show nevertheless in a quantitative point of view the most
endless varieties. ‘The scientific foundation of a theory of the for-
mation of scoriz and slags is the work of Mbitscherlich. The
production of mineral substances by means of fire, or as the produce
of high furnaces by the gradual diminution of the temperature of
materials melted together in given proportions, or from vapors, attrac-
ted more and more attention. ‘The influence of temperature on the
resulting substances is most important, bringing about new combina
tions and new conditions out of the same material. ‘These phenomena
are most remarkable in the combination of iron and charcoal.
““ Space, quiet, and freedom of motion,” said the author, “are the
most important conditions and necessary requisites for the parti-
cles of matter to be able to arrange themselves in regular order to
produce well-formed crystals; this the chemist had taught us. All
products of this kind are subject to unchangeable laws. The more
gradual the reduction of the igneous fluid to a solid mass, the more
favorable are the conditions of crystallization. If proportions and
conditions are the same, we always see the same forms reproduced.”
After these words the author described the process of late chemists
with regard to the melting and reduction of various rocks, and then rap-
idly noticed the numerous minerals and combinations of minerals found
in the scoriz and slags of smelting furnaces. “ All scorie,” he added,
“have a similarity of substance and degree of flexibility (?) sufficient
to enable the metalic particles thus obtained to sink by means of their
greater specific gravity. Scoriw have a less specific weight than the
products to.be gained by smelting; the latter are pure metals, or a
combination of metal with charcoal, sulphur, &e.—the former consist
entirely or chiefly of earths. We can thus understand how a cover-
ing of slag is formed over the melted treasure as a protection against
the influence of fire and of atmosphere.” After mentioning some of
the principal minerals obtained from furnaces, and which are the
principal ingredients of the most extensively found rocks, he observed
that “in a geological point of view these products are of the greatest
importance. They point out how nature has ever worked in her
CHEMICAL SCIENCE. 209
mysterious abodes, on a still larger scale and with an overwhelming
force. ‘These substances will open up a new field for inquiry and
investigation for observation and experiments. They will play an
important part in all future geological hypotheses, when we have to
argue from the known to the ‘unknown. They will fill many a gap in
imperfect observations, they will explain various phenomena, explode
rash assertions and imaginary assumptions. We may also hope, too,
for further information on the question, whether the fundamental
rocks of our planet, the form of which presumes a fluid state, were
soluble in water; or whether the temperature of the earth was once
so high, that the ingredients of certain rocks were ina melted state ?”
He concluded by mentioning that, “‘ amongst the products of smelting
furnaces there are some which have not yet been found in a natural state
Some of the artificial productions, however, have been subsequently
discovered in the realms of nature, and there is no reason why we
may not expect, with future investigations, te find the others.”
NEW TEST FOR MERCURY.
Mr. ArtHur MorGan in a paper read before the Dublin Medico-
chirurgical Society says, —if a strong solution of iodide of potassium
be added to a minute portion of any “of the salts of mercury, placed
on a clean bright plate of copper, the mercury is immediately depos-
ited in a metallic state, appearing as a silvery stain on the copper,
which cannot be mistaken, as no other metal is deposited by the same
means. By this method corrosive sublimate may be detected in a
drop of solution unaffected either by caustic potash, or iodide of
potassium. In amixture of calomel and sugar inthe proportion of one
grain to two hundred, a distinct metallic stain’ will be obtained with
one grain of the mixture, which of course contains 1-200 of a grain
of calomel; in like manner, 1-400 of a grain of peroxide of mercury
may be detected, although the mixture with sugar is not in the least
colored by it, with preparations of mercury in the undiluted state, this
process acts with remarkable accuracy, the smallest quantity of
calomel in peroxide of mercury, such as would almost require a mag-
nifying lens to perceive, placed on copper and treated with iodide of
potassium, will give a distinct metallic stain.
The advantages of this test may be briefly stated as follows: — It is
a delicate test inferior only to chloride of zinc and the galvanic test of
zinc and gold. It is easy of application. It requires a very small
portion of the substance to be examined—a matter of no small impor-
tance. Acting on the insoluble as well as the soluble salts, it obviates
the intermediate process of solution. When it acts, its indications are
decisive. As to its disadvantages, the only one which seems tenable
is, that although it acts on minute portions, still that must be in a con-
centrated condition.
=
210 ANNUAL OF SCIENTIFIC DISCOVERY.
ON THE PREPARATION OF PURE SILVER FROM CHLORIDE OF
SILVER. BY C. BRANNER.
Ir has long been known that pure silver for chemical purposes is
best prepared by the decomposition of chloride of silver. This decom-
position can be performed in various ways: Poggendorff, several years
ago, described a process in which it was effected by galvanism ; this
appears to me to be preferable to all others hitherto known, and the
one here described can only be regarded as a modification of it.
Well-washed precipitated chloride of silver is to be put into a cup of
silver, platina or copper the outer surface of which is covered with
wax in such a manner that only a round space of one or two inches
in diameter, according to the size of the cup, remains uncovered. On
the bottom of a larger earthen cup a disc of amalgamated zinc is to be
laid, on the middle of which the cup containing the chloride of silver
is placed, in such a manner that the portion not covered with wax
may come in contact with the zinc. Water slightly acidulated with
sulphuric acid is now poured into the apparatus, until it rises above
the margin of the inner cup, so that this will be completely sunk in
the water. The decomposition of the chloride of silver immediately
commences at the edge of the cup containing it and proceeds inwards
to the middle ; this is readily known by the dark gray color assumed
by the silver as it separates ; the decomposition will be completed in
from 24 to 48 hours; its completion may be known by there being no
longer any chloride of silver visible on stirring the precipitate. The
silver thus procured is to be washed with water, and any small residue
of chloride of silver which it sometimes retains may be got rid of by
diluted ammonia. The silver thus prepared is perfectly pure. It is
readily seen that any foreign metals that may be contained in the
zinc, can never mix with it, as the disc of zinc lies during the whole
operation below the cup containing the silver and never comes in
contact with it.
CRYSTALLIZATION OF GLASS. °
SomE interesting experiments on this subject have been made by
M. Leydolt, in the course of his investigations upon the crystallization
of the silicates. He had examined agate by subjecting it to the
dissolving action of fluohydric acid, and obtained a surface with pro-
jecting crystals of quartz, that were left untouched by the acid. On
subjecting glass in the same manner, he was surprised to see that it
was far from homogeneous in its texture. All the kinds of glass
examined contain more or less perfectly distinct crystals, regular and
transparent encased in an amorphous base. ‘The crystals were
brought out by exposing it to the vapors of fluohydric acid and vapor
of water, and arresting it when the crystals appear; the amorphous
part is a little the most soluble in the acid. M. Leydolt observes also
that some natural crystals pure and transparent and apparently
>
CHEMICAL SCIENCE. 211
homogeneous, present similar deficiency in homogeneity with the
glass ; and he has the subject under further examination.
ON THE DISTRIBUTION OF IODINE.
A MEMOIR, it is well known, has been recently published in the
proceedings of the French Academy by M. Chatin, on the existence
of iodine in the atmosphere, in rain-water, soils, &.* Mr. McAdam,
of Edinburgh, ina letter to Prof. Jameson, published in the Philosoph-
ical Journal for July, states that he has endeavored with great care
to verify the results obtained by M. Chatin, but without success. As
the fixed alkalies and their carbonates were re-agents made use of by
M. Chatin, Mr. McAdam is inclined to refer the iodine found, to
these bodies, Mr. McAdam’s success in detecting iodine in pearl
ashes leads to the belief that this substance will be found more gen-
erally distributed in the vegetable kingdom than it has hitherto been
supposed to be; and this opinion is strengthened by the fact that it
has in several instances been detected in charcoal.
RESEARCHES ON THE SULPHURETS WHICH ARE DECOMPOSABLE
BY WATER. BY E. FREMY.
THE object of this paper is to make known the production and
principal properties of a class of sulphurets hitherto little examined,
and the study of which is alike interesting to chemists and geologists,
from the light which it throws on the formation of mineral waters.
When we consider the action of water on the sulphurets, we find that
these compounds may be divided into three classes; the first com-
prises the sulphurets of the alkalies and of the alkaline earths which
dissolve in water; the second is formed of the insoluble sulphurets ;
the third consists of the sulphurets of boron, silicon, magnesium and
aluminum, which are decomposed by water; these latter are scarcely
known, owing to their preparation having hitherto been accompanied
with great difficulties. In order to a thorough investigation of all the
questions which are connected with the decomposition of the sul-
phurets by water I first sought for a method by which they might be
easily prepared, which is as follows. It is well known that sulphur
exerts no action upon silica, boracic acid, magnesia and alumina. I
imagined it might be possible to replace the oxygen in these substances
by sulphur by the intervention of a second affinity, as that of carbon
for oxygen. Such decompositions, produced by two affinities are not
rare in chemistry ; and in some yet unpublished experiments on the
fluorides, I had observed that the sulphuret of carbon completely
decomposed the fluoride of calcium mixed with silica, producing
sulphuret of calcium, I was therefore led to presume that the sulphuret
of carbon, acting by its two elements upon the preceding oxides,
would remove the oxygen by means of the carbon which it contains,
and would at the same time form sulphurets ; this supposition I found
* See Annual of Scientific Discovery for 1851, p. 231.
212 ANNUAL OF SCIENTIFIC DISCOVERY.
confirmed by experiment. In fact, I have obtained the sulphurets of
boron, silicon, magnesium and aluminum, by submitting boracic acid,
silica, magnesia and alumina to the action of sulphuret of carbon at a
high temperature. To facilitate the reaction, and remove the sul-
phuret from the decomposing action of the alkalies contained in the
porcelain tubes, it is sometimes useful to mix the oxides to be reduced
with charcoal, and to form them into little balls similar to those which
are used in the preparation of chloride of silicon. ‘These sulphurets
correspond to the oxides from which they are derived.
The sulphuret of silicon had been obtained in small quantities by
Berzelius in the reaction of sulphur upon silicon, and by M. Pierre
in the decomposition of chloride of silicon by hydrosulphuric acid.
I have obtained this substance with the greatest ease, by passing the
vapor of sulphuret of carbon over pellets of charcoal and gelatinous
silica placed in a porcelain tube heated toa bright red. The sulphuret
of silicon condenses in the tube in beautiful white silky needles, which
are not very volatile, but are readily carried along by the vapor. To
show the interest which attaches to the examination of this substance,
it will suffice to mention here two of its reactions. When sulphuret
of silicon is heated in a current of moist air, it is decomposed and
furnishes silky crystals of anhydrous silica ; it is evident that we may
explain by means of this experiment the natural production of certaim
filamentose crystals of silica. The sulphuret of silicon in the presence
of water is decomposed with a brisk evolution of hydrosulphuric acid
into silica, which remains entirely dissolved in the water, and is not
deposited until the liquid is evaporated. It is impossible not to con-
nect this curious property with those natural conditions under which
certain mineral waters and siliceous incrustations are formed. As the
sulphuret of silicon is probably produced in all those cases where
silica is submitted to the double action of a bmary compound which
cedes sulphur to it, and at the same time appropriates its oxygen, this
sulphuret is probably not so rare as has been hitherto thought; and
by admitting its presence in those rocks in which sulphurous springs
occur, we might explain the simultaneous existence of silica and
sulphuretted hydrogen im the principal sulphurous waters. This
hypothesis is in some measure confirmed by the interesting observa-
tions of M. Descloizeaux, which show that the siliceous springs of the
Geysers of Iceland contain a large quantity of sulphuretted hydrogen.
In explaining the formation of sulphurous and siliceous waters by the
decomposition of the sulphuret of silicon, I am only extending the
ingenious theory proposed by M. Dumas to explain the formation of
boracic acid. ‘The sulphurets of boron and aluminum were prepared
like the sulphuret of silicon, and are likewise decomposed by water.
The sulphuret of magnesium I obtained by passing sulphuret of car-
bon over pure magnesia; in this case the presence of charcoal does
not appear to be of any use. Thissulphuret crystallizes and is soluble
in cold water; when its solution is kept at the ordinary temperature,
there is but a feeble disengagement of sulphuretted hydrogen; but
CHEMICAL SCIENCE. 213
when heated to ebullition, a lively effervescence of sulphuretted hydro-
gen takes place and there is an immediate deposition of magnesia.—
Comptes Rendus, July, 1852.
ON -THE SEPARATION OF MANGANESE.
Dr. Gress in a communication to Silliman’s Journal, September,
1852, gives the following statements in regard to the precipitation ot
manganese : —
Schonbein in a memoir on the relations of peroxide of lead and
ozone, has pointed out the remarkable fact that peroxide of lead
precipitates manganese completely from its solutions in chloro-hydric
and sulphuric acids, a compound of peroxide of lead and peroxide of
manganese being formed. A portion of the lead is at the same time
reduced to protoxide and unites with the acid with which the manga-
nese was combined. Schonbein appears not to have remarked the
importance of this observation in an analytical point of view.
In investigating the subject carefully, I have been led to the con-
clusion that the peroxide of lead constitutes one of the most valuable
re-agents in analytical chemistry, since by means of it the oxide ot
manganese may be easily and completely separated from a number
of other bases, without the employment of ammoniacal salts. The
use of ammonia, as is well known, frequently renders analyses con-
ducted by the ordinary methods laborious and inaccurate, either from
the number of operations involved, from the absorption of carbonic
acid from the air, or from the unavoidable loss in driving off the
ammoniacal salts by heat. The fact which I have determined, and
which serve as the basis of the analytical application of the peroxide
of lead are as follows : —
Peroxide of lead completely precipitates manganese from neutral
solutions in chloro-hydric, sulphuric and nitric acids, slowly in the
cold, but very rapidly by digestion or by boiling. The presence of
an excess of chloro-hydric or sulphuric acid does not prevent the com-
plete precipitation of the manganese; in these cases, however, chlo-
rine or oxygen is set free, and the quantity of lead dissolved is
greater than that which corresponds to the quantity of manganese
precipitated. Such an excess of acid should be avoided as far as
possible. ;
The presence of an excess of nitric acid prevents the precipitation
of the manganese, since hyper-manganic acid is formed and remains
in solution. Tartaric acid, and those organic substances which are
burned at the expense of the peroxide of lead, do not interfere with
the precipitation of the manganese. The organic matter is first
destroyed by the oxygen of the peroxide of lead, and afterwards the
manganese is precipitated by the excess of the peroxide added.
When the quantity of organic matter present is large, it is always
better to separate the manganese by means of sulphydrate of ammo-
nium in the usual manner. When, however, oxalic acid is present,
we may avoid the use either of an inconvenient quantity of peroxide
214 ANNUAL OF SCIENTIFIC DISCOVERY.
of lead, or of sulphydrate of ammonium, by means of chlorine or
bromine. Lither of these agents readily converts oxalates into
carbonates by a well known reaction. ‘The presence of an excess of
free acetic or succinic acid, does not prevent the complete precipita-
tion of manganese by peroxide of lead. The same observation applies
to the presence of sulphate, nitrate, and chloride of ammonium, and
therefore, probably to all ammoniacal salts. Salts of protoxide of iron
are oxidized and partially precipitated by peroxide of lead. The
same remark applies to the salts of cobalt. The precipitation is not
complete even after long digestion upon the sandbath.
The salts of nickel and zinc are not precipitated by peroxide of
lead, and the nickel undergoes no higher oxidation. Peroxide
of lead when perfectly free from protoxide does not precipitate baryta,
hme, magnesia, strontia, alumina from their solutions. The same
remark applies, as might be supposed, a fortiori, to the alkaline bases.
The application of these facts to the quantitative separation of manga-
nese from the above mentioned bases, with the exception of iron and
cobalt, is obvious.
Dr. Gibbs then proceeds at some length to consider the several
cases separately.
ROSIN OIL.
WE derive the following facts relative to the manufacture and use
of rosin oil for mechanical purposes, from a report submitted to the
manufacturing companies of Lowell, Mass., by a committee appointed
to investigate the subject. Dr. Samuel L. Dana, chairman.
The committee have considered this subject in relation to its
manufacture, lubricity, and economical use. Dr. Dana after carefully in-
vestigating the subject states as follows : — “ It was early evident to me
that the amount of practical information on the subject was very limited,
and rested on no fixed principles. I therefore devoted my time to the
investigation of principles relating to the process. I am satisfied, after
producing about 1,000 gallons, that, with due care guided by principles
which have been established, rosin oil of a uniform quality may be con-
tinuously produced at a very low rate per gallon. It was desirable, for
some purposes, that rosin oil should be deprived of its characteristic
odor without detriment. This difficult point has been completely
effected, and many gallons have been thus prepared, which have been
used by the companies. Deodorization will not probably materially
increase the cost of the oil. The first oily product of the distillation of
rosin, by a slight and cheap process, becomes applicable to all heavy
machinery when mixed with its bulk of sperm oil. The Merrimac
Manufacturing Company have used constantly, for several months,
this mixture on all parts of their steam engines, except the cylinder,
&c., on all their blowing fans, revolving at a speed of 600 or 700 turns
per minute, and on all the bearings in the print yard. No evil has
resulted from its use. It spends nearly the same as pure sperm oil.
It was found, moreover, that while first run rosin oil was found per-
CHEMICAL SCIENCE. 215
fectly applicable to all heavy bearings, after undergoing a slight pro-
cess, yet when deodorized, a chemical change or motion among its
particles was induced, by which it oradually thickened and became
unfit for lubrification. This fact led me to believe that rosin oil, under
certain circumstances, is an unstable compound. Hence, ‘it was
desirable, to put it into a stable state by removing the body or bodies
which caused motion to occur. This was effected, and a perfectly
limpid and fixed oil was obtained, quite free from the peculiar odor of
rosin oil.
In reply to certain queries propounded by the committee to an
eminent French chemist, communications have been received, which
fully show that we are not behind the French manufacturers of rosin
oil, either in quality or quantity of product; they have brought to our
knowledge a new preparation from rosin oil, in a semi-solid or lardy
state, now much used in France, with a ‘steady annual increasing
demand. This preparation is a substitute for the various well known
substances used in a fatty or soft-solid state for greasing wheels, gear-
ing and heavy shafting. Following the specific ‘directions for the pre-
paration of this substance, it was found that a hard body like shoe-
maker’s wax was produced; an almost instantaneous solidification
occurring. After many trials, however, with great modifications of
proportions and time, the desired compound was produced, possessing
the properties described, and appearing like the samples received from
France. ‘This rosin fat has been used with success on iron gearing,
and my opinion is favorable to its use as a substitute for tallow, and at
a cost much below the average price of that article. The consumption
of tallow at the Merrimac Cotton Mills, for the year ending Novem-
ber 15th, 1851, was 4,500 lbs., which may be, probably, replaced by
the rosin oil substitute.
In regard to the lubricity of the oil, the committee states, that rosin
oil can be used for lubrification, only when mixed with its bulk of
pure sperm oil. By accurate experiments it appears that spinning
machinery requires more, and weaving machinery less power, when
rosin and sperm oil are used, than when pure sperm oil alone is
employed. This may be explained by reference to the kind of
machinery, looms consisting chiefly of cam movements. Machinery
falls naturally into two classes ; 1st. That with fine or light bearings.
2d. That with cam movements, or with heavy bearings. ‘All machines
of the first class will probably require more, and all of the second
class less power with the mixture of rosin and sperm oil, than with
pure sperm only. Deducting the less pewer required by some
machines, from the oreater demanded by others, the committee would
avoid the question, whether the cheaper mixed oil would not pay for
the balance of greater power, by throwing out all the fine machinery,
as a class to which the rosin mixed oil is inapplicable.
Experiments made with great care, with the same dynamometer,
and under the same circumstances gave the following results :— The
average from the trials on nine spinning frames, shows that 13 8-10
19* .
216 _ ANNUAL OF SCIENTIFIC DISCOVERY.
per cent. more power is required with the mixture of rosin and sperm
oil, than with sperm alone.
The average from the trials on six stretchers, shows that 3 7-10 per
cent. more power is required with the mixture, than with sperm alone.
The average from the trials on five looms, shows that 4 6-10 per cent.
less power is required with the mixture, than with the sperm alone.
In regard to the economy of rosin oil, itis stated that the mixed oil
spends about as economically as pure sperm, and no serious evil has
resulted from mixed oil in the long experience of the use of this
article. It will be recollected that rosin oil can be used only when
mixed with its bulk of sperm oil. Under this division, therefore,
the committee have considered to what extent rosin oil my be substi-
tuted for sperm in the cotton mills of Lowell. As the bases of their
calculation, the oil statistics of the Merrimac Company have been
assumed. ‘The total sperm oil used for lubrification by the Merrrimac
Cotton Mills for the year ending November 15th, 1851, was 6,772
gallons, — of this amount rather more than one-quarter (26,722 0-0)
. . . . . or 1,813 gallons were used for spinning, leaving a balance
of 4,959 gallons. Of this balance, rather less than one-fourth, or 1,192
gallons, were used in weaving, which requires by experiment 4 6-10
less power with mixed oil, than with sperm alone, leavmg 3,767
gallons applicable to machinery, which the committee class among
those with heavy bearings, and which requiries, at least, no more
power with the mixed oil, than with sperm oil only. We have, then,
in the Merrimac Company’s Mills 4,959 gallons, or about three-
fourths of all the sperm oil used there, for which may be substituted a
mixture of equal parts of rosin and sperm oils, thus diminishing the annual
amount of sperm oil by 2,479.5 gallons, or nearly three-eights of the
whole. The Merrimac Mills are using about one-stxth of the power of
the Lowell Corporations. If the other mills use oil in about the propor-
tion above, the total annual diminution of sperm oil, by substituting rosin
oul, will be 14,877 gallons.”
Small as the annual saving in sperm oil thus appears, the committee
are of opinion, that it will have been highly important that this result
has been approximated, since that amount will probably be multiplied
by all heavy bearing machinery in the country now oiled with sperm,
and thus an amount of that article will be thrown into the market,
which may tend to lower its price and improve its quality.”
ON THE TREATMENT OF FAT FOR THE PREPARATION OF
CANDLES.
MM. Masse and Treboullet, in a communication to the Bulletin
de la Societe 1 Encouragement, states :— It is well known that fat may
be made to acquire a soapy character by the influence of sulphuric
acid. In the manufacture of candles the fat is heated with sulphuric
acid, or subjected to mechanical friction therewith ; it is then washed,
and the mass being placed in a still, is heated to between 200° and
250° Centigrade to drive off the aqueous vapor and with it the fatty
acids. With palm oil, the effect of this treatment is as follows :—
CHEMICAL SCIENCE. 217
Palm oil melts at 30° Centigrade ; after the action of sulphuric acid at
38° ; aftér the washing with water at 44.5° Centigrade ; after the distil-
lation at 46°. The first product of distillation liquefies at 53.5°, the
point of liquefacation then sinks, and the product comes gradually
more and more to have a tendency to crystallize. Ifthe entire pro-
duct be pressed together, the mass has a melting point of 54.5°, the
same as that which first passed over. Some fats, however, present
considerable differences in these respects.
IMPROVEMENT IN THE MANUFACTURE OF GAS.
SoME improvements have been recently patented in England, by
Messrs. Barlow and Gore for the manufacture of gas, which are high,
spoken of by the London Mining Journal. ‘The processes are based,
1st, upon an improved method of rendering luminous the gases result-
ing from the perfect decomposition of water or steam ; and, 2d, upon
the conservative influence which hydrogen exercises in protecting
the matter upon which the illuminating power of gas depends from
decomposition by heat. The first has been often attempted, with
dulfous and disputed success. The failures are all traceable to the
same sources — first, to the impossibility of securing the complete
decomposition of water or steam by any of the means employed, and
to the consequent production of a large quantity of vapor, exercising
a fearfully destructive influence over the carbonaceous matter under-
going decomposition for the purpose of rendering the water gases
luminous ; and, secondly, to the presence in the water gases of from
10 to 15 per cent. of carbonic acid, the injurious effects of which upon
the flame need not be alluded to, and the expenses of abstracting which
by any of the ordinary methods are so considerable as materially
to augment the cost of manufacture, besides diminishing the volume of
saleable gas. The present patentees propose to obviate these difficul-
ties by first condensing the water gases, so as to deprive them of all
excess of vapor, and then to pass them through a heated retort con-
taining carbonaceous matter, by which the whole of the carbonic acid
gas will be converted into twice its bulk of carbonic oxide gas, and the
pure hydrogen and the carbonic oxide gases in equal volumes, free from
carbonic acid, are afterwards admitted in regulated quantities into
retorts where carbonaceous matter is undergoing distillation or decom-
- position, and by which they are rendered highly luminous. ‘The con-
servative effect of hydrogen upon olefiant gas has not, we believe,
hitherto been noticed by chemists. It may, however, be demonstrated
by the following very simple experiment : — If olefient gas be passed
through a red hot tube, the carbon will be deposited, and the gas be
thereby converted into light-carburetted hydrogen, a gas of very low
illuminating power. If, however, hydrogen be added to the olefiant
gas, the same process may be repeated without causing any deposition
of carbon, and with only a diminution of illuminating power in the
mixed gases, due to the increased volume of the non-illuminating gas
— hydrogen.
\
218 ANNUAL OF SCIENTIFIC DISCOVERY.
The practical effect of this property, when applied to gas making, is
to reduce the quantity of combustible products, such as tar, &c., and
entirely to prevent the deposition of carbon on the interior surface of
retorts. The importance of these discoveries will be readily under-
stood, when we state that the experience of the patentees leads them
to the conclusion that upwards of fifty per cent. may be added to the
volume of gas yielded by all descriptions of materials ordinarily used
for that purpose, without any diminution of the illuminating power, so
that 15,000 cubic feet will be the probable future product from one
ton of Newcastle coal, and 75,000 cubic feet of London gas from the
same quantity of Boghead Cannel. — London Mining Journal.
FLAX COTTON.
A PARLIAMENTARY document lately published in England, con-
tains a report made by Sir Robert Kane, on Claussen’s invention for
the production of flax cotton. Experiments were made by Sir
Robert, on a smaller scale than had been intended, in consequence of
the want of a sufficient supply of flax. The experiments made were
of two kinds, of the results of which the following account is giver —
The first was as to the direct preparation of flax cotton from flax
straw, in which the separation and cleansing of the fibre from the
refuse part of the stalk was made a part of the process, and this was
not by any means satisfactorily done. The second was as to the
conversion of tow or low priced flax into flax cotton ; and, although in
this material the fibre has been already prepared and cleaned by
the previous dressings, the product obtained did not approach in fine-
ness of texture, uniformity of structure or cleanness of mass to the
quality of the specimens of flax cotton that are usually exhibited by
M. Claussen’s agents. Under these circumstances, Sir Robert Kane
considers the trials “to have been in so far negative as the agents
acting for M. Claussen found it impossible to produce satisfactory
results in those works which they had themselves selected, and where
_ they had been working previously.” At the same time it is admitted
that much weight must be conceded to the defective mechanical
arrangements. In winding up his report, after mentioning incidentally
that when the trials had been concluded and found unsatisfactory, a
letter was received from M. Claussen declining to be responsible for
the results, and stating that he would prefer that the inquiry should be
conducted at some works he had erected near London, Sir Robert
Kane observes : —
“In regard to the more purely scientific portion of the inquiry, I
beg leave to report that several interesting facts have been already
ascertained as to the real nature of the material produced, and as to
the true action of the materials used. Without being understood to
announce a positive conclusion, which in a report of progress would
be premature, I beg to state that I am pretty well satisfied that M.
Claussen’s process does not at all produce a material approaching in
structure or organic quality to cotton. ‘The views of the bursting up
CHEMICAL SCIENCE. 219
of the fibres put forward by some persons who have come forward to
explain the process in public do not appear to be well founded. The
flax fibres are in M. Claussen’s process excessively finely divided and
separated from each other, but each remains still a thorough and com-
plete flax fibre, and quite unlike cotton, and the same amount of
division, and the same fineness and pliability of fibre may be given,
and often is given, to flax by simple dressing, especially if the flax had
been overretted. This point as to structural character is, however,
so fundamental to the value and quality of the flax cotton, that [deem
it indispensable to follow up still further the careful microscopic
examination of the material in all its stages, and shall, therefore,
reserve for a future complete report details and drawings.”
M. Hamel lately delivered an address before the Imperial Academy
of Russia, on the subject of flax cotton, in which he gives a different
account of its invention to what is generally supposed. According to
him, a native of Holstein, named Ahnesorge, by trade a dyer and
bleacher, had applied himself for several years to improvig flax
spinning, as well as to turn to account the tow, which is of little
value. For this purpose he made several journies, and in 1838 went to
St. Petersburgh with a sample of about a dozen pounds of a cottony
material from flax tow. In 1846 the king of Denmark, having been
informed of M. Ahnesorge’s industrious efforts, sent him a sum of
money to help in establishing a manufactory, but just as he had begun,
at Neumeistler, the manufacture of cotton and woolen fabrics, mixed with
his cotton from flax tow, the disastrous war of the Duchies broke out,
and M. Ahnesorge sought refuge in London, where he arrived in
October, 1848.
Having applied to one of the principal patent agents for advice, on
what steps he should take to procure a patent for his invention, he
was introduced to M. Claussen, who, delighted with his project, made
an agreement with him, by which he was to take out the patent in his
name. Ahnesorge commenced his labors in M. Claussen’s house, in
London. His articles were highly spoken of, but he wanted the
necessary funds to develope the manufacture. A native of Hamburgh,
named Auguste Quitzow, resolved to carry on the manufacture in a
large: way in Yorkshire. He bought a place between Bradford and
Leeds, and with the consent of Claussen, engaged Ahnesorge to pre-
a the flax, and make the cotton according to his method. M.
mel says that all the samples, both white and dyed, exhibited at the
Crystal Palace in the name of Claussen, as well as in that of Quitlow,
Schelennger & Co., were made by M. Ahnesorge ; the public were not
informed of this circumstance. The attempts to card and spin
Ahnesorge’s products were made near Rochdale, in a factory that Mr.
Bright, the well-known politician had placed at the disposal of M.
Claussen, who had, in fact, taken out the patent in his own name.
The high price of cotton, at the time of the Great Exhibition, had led
to the hope that a project for substituting flax would easily find
purchasers, and this was the reason why M. Claussen, described, in this
patent, a process for cutting the cotton flax into small pieces, of the
— 220 ANNUAL OF SCIENTIFIC DISCOVERY.
same length as the cotton rovings, so as to be able to card and spin
them on the machines constructed for cotton. Besides, he wishes it to
be supposed that, by placing the flax thus cut up, after it has been
boiled in a solution of bi-carbonate of soda, into sulphuric acid diluted
with water, it will split, from developing carbonic gas, in appearance
resembling cotton. M. Claussen has started a company with a capital
of £250,000 to £500,000, to carry on the manufacture, and he exerts
every possible effort to obtain purchasers for his patent. To exhibit
his patented process of splitting the flax, he has rented a place at
London, where M. Ahnesorge (who is never named) has first to
prepare the flax or tow by boiling it in a solution of soda, and where
afterwards, the experiment of chemical effervescence is made before
visitors. This is called the splitting process.
M. Hamel declares it to be impossible to change the flax into a fibrous
matter resembling cotton, which is the work of nature. He is decidedly
opposed to the project of cutting up the dressed flax into a sort of tow.
The superiority of flax over cotton consists, in a great measure, in
the greater length of its fibres. The result, therefore, would be to
convert a primary valuable material into a very inferior one.
PREPARATION OF CYANIDE OF POTASSIUM.
M. CiemAn, of Paris, gives the following detailed account of the
process for obtaining this salt in a pure state, the accomplishment of
which is a matter of some difficulty : —
Mix intimately eight parts of ferro-cyanide of potassium, perfectly
de-hydrated by calcination, and three parts of perfectly dry carbonate
of potash, and heat the mixture in a covered crucible, or what is
better an iron pot, until the fused mass attains a red heat, when it
will become limpid, and a sample taken out with the rod and cooled,
will appear perfectly white, in this state all the ferro-cyanide is
reduced. If the crucible be now taken out of the fire, the disengage-
ment of the gas ceases when the mass has become a little cool, and the
iron which has been separated in the operation so disposes itself, that
with a little address and slight tapping of the crucible, the principal
part of the cyanide of potassium may be poured off from the iron
which remains in the crucible. To obtain the cyanide perfectly free
from iron, place it across an iron ladle, pierced with fine holes, and
strongly heated beforehand, in a vessel also heated, of greater height
than width, either of silver, iron, or porcelain, or even fire ware, but
with smooth sides, and let it gradually cool. In this state the ferru-
ginous portion may be extracted by means of a sharp instrument
from that which is free from iron. The purity of the cyanide of
potassium entirely depends on the purity of the materials employed ;
the presence of sulphur in the carbonate of potash should therefore
be avoided ;. the ferro-cyanide of potassium of commerce almost inva-
riably contains sulphate of potass, the presence of which is objection-
able. The use of purified tartar might perhaps be advantageously
substituted for that of carbonate of potash. Should any sulphur be
CHEMICAL SCIENCE. OFT
present, a sulphuret of potassium would be formed in the cyanide of
that metal, from which considerable inconvenience would arise in the
employment of the cyanide in chemical analysis, and in its application
to the preparations of the gold, silver, and copper solutions employed
in the electro-plating processes. When the mixture is melted, as
before mentioned, there is at first formed only cyanide of potassium
and carbonate of the protoxide of iron ; but this last quickly changes,
at the temperature to which it is exposed, into carbonic acid, carbonic
oxide, and sesqui-oxide of iron; and this last, when the cyanide of
potassium is melted, becomes converted into metallic iron. It is only
by a long sustained heat that the carbonate of protoxide of iron is
decomposed, so that long after the decomposition of the ferro-cyanide
of potassium, and the formation of cyanide of potassium has taken
place, there is still a disengagement of gas. Consequently, the pro-
portion of cyanide of potassium, which is simultaneously formed,
should entirely depend on the duration of the fusion. The iron which
remains after a prolonged fusion of the cyanide of potassium, out of
contact of air, bemg washed with hot water, disengages, when an acid
is poured on it, not only hydrogen, but always a litle carbonic acid
as.
If we follow the directions given in most chemical works, in which
it is stated that the materials must be melted, so that the mass submit-
ted to a bright red heat becomes tranquil, — only a grey colored pro-
duct will be obtained.
If a closed iron vessel be employed, and the disengaged gases col-
lected, it will be seen that in proportion as the temperature rises, the
relative proportion between the carbonic acid and the carbonic oxide
changes, the latter constantly increasing. It is evident that at a high
temperature, one portion of the carbonic acid, which passes through
the cyanide of potassium, should be reduced into carbonic oxide, and
this reduction, without doubt, extends even in part to the carbonic
oxide itself; that is to say, that its carbon is separated, and that this
renders the product of a grey color. If we dissolve in cold water
some cyanide of potassium completely free from particles of iron, and
which has thus become grey, and filter the solution, there remains in
the filter a black substance, which, being dried, burns away completely
on a slip of platinum, and in fact, possesses all the qualities of char-
coal. This carbon, in a state of extreme division, does not separate,
either by fusion or repose, from the cyanide of potassium, on account
of its feeble specific gravity. Ifa little of this grey cyanide be added
to each new melting, it may be purified from this carbon, and no injury
done to the product of the new materials employed, as the iron in
separating, withdraws the finely-divided carbon, and leaves the cyanide
in a state of purity.
LIQUID GLUE.
M. DuMmo tin publishes the following article on the preparation
and nature of liquid glue,in the Comptes Rendus, Sept., 1852. Chem-
>
222 ANNUAL OF SCIENTIFIC DISCOVERY.
ists well know that heating and cooling repeatedly a solution of glue,
(gelatine,) in contact with the air, it looses its property of becoming a
jelly. M. Gmelin has shown, that a solution of fish glue in a sealed
tube, placed in a water bath heated to the boiling point for several
days, exhibits the same phenomena, 7. e. the glue remains liquid, does
not gelatinize upon cooling.
The change effected, is one of the most difficult problems to resolve,
of organic chemistry. It appears to be a product of the action of the
oxygen of the air and the water upon the glue, as demonstrated from
the action of a small quantity of nitric acid, on a solution of strong
glue. We know that on treating gelatine with an excess of this acid
in the presence of heat, it is conv verted into malic and oxalic acids, fat,
tannin, &c. This does not occur when we treat the glue dissolved in
its weight of water, with a very small quantity of nitric acid; we
obtain only a strone glue which preserves a long time its primitive
qualities, and which no longer has the property of celatinizing. In this
manner the glue sold in France under the name of liquid and
unchangeable glue, is fabricated. This glue is exceedingly conven-
ient for cabinet makers, joiners, pasteboard manufacturers, toy makers,
&c., since it can be used cold. It is prepared as follows : —
Dissolve two pounds of strong glue in one quart of water in a glue
kettle, or in a water bath, when the glue is entirely melted, add
little by little, to the amount of ten ounces of strong nitric acid. ‘This
addition produces an effervescence due to the disencagement of hypo-
nitric acid, when the whole of the acid is added, 1 remove the vessel
from the fire, and leave it to cool. I have preserved glue thus pre-
pared, more than two years in a stoppered flask, without -its under-
going any alteration. This liquid glue is very convenient in chemical
operations. I have employed it with adv antage in my laboratory, for
the preservation of different gases, the same as s lute, covering the little
bands of linen with the glue.”
PERFUMERY AND THE ARTIFICIAL EXTRACTS OF FRUIT.
Dr. PLAYFATR, in his lecture on the Results of the Great Exhi-
bition, thus briefly notices a new class of perfumes and essences,
which of late have attracted no little attention.
Much aid has been given by chemistry to the art of perfumery. It
is true that soap and perfumery are rather rivals, the increasé of the
former diminishing the use of the jatter. Costly perfumes, formerly
employed as a mask to want of cleanliness, are less required now that
soap has bécome a type of civilization. Perfumers, if they do not
occupy whole streets with their shops, as they did in ancient Capua,
show more science in attaining their perfumes than those of former
times. ‘The jury in the exhibition, or rather two distinguished chem-
ists of thaf jury, Dr. Hoffman and M. De la Rue, ascertained that
some of the most delicate perfumes were made by chemical artifice,
and not, as of old, by distillimg them from flowers. The perfume of
flowers often consists of oils and ethers, which the chemist can com-
CHEMICAL SCIENCE. 238
pound artificially in his laboratory. Commercial enterprise has
availed itself of this fact, and sent to the exhibition in the form of
essences, perfumes thus prepared. Singularly enough, they are gen-
erally derived from substances of intensely disgusting odor.
A peculiarly fetid oil, termed ‘“ fusel oil,” is formed in making brandy
and whisky. This fusil oil, distilled with sulphuric acid, and acetate
of potash, gives the oil of pears. The oil of apples is made from the
same fusel oil, by distillation;with sulphuric acid and bichromate of
potash. The oil of pine apples is obtained from a product of the
action of putrid cheese on sugar, or by making a soap with butter, and
distilling it with alcohol and sulphuric acid, and is now largely employed
in England in the preparation of the pine apple ale. Oil of grapes
and oil of cognac, used to impart the flavor of French cognac to Brit-
ish brandy, are little else. than fusel oil. The artificial oil of bitter
almonds now so largely employed in perfuming soap, and for flavor-
ing confectionery, is prepared by the action of nitric acid on the fetid
oils of gas tar. Many a fair forehead is damped with eau de mille-
fleurs, without knowing that its essential ingredient is derived from
the drainage of cow houses. The wintergreen oil, imported from New
Jersey, being produced from a plant indigenous there, is artificially
made from willows, and a body procured in the distillation of wood.
All these are direct modern appliances of science to an industrial pur-
pose, and imply an acquaintance with the highest investigations of
organic chemistry. Let us recollect that the oil of lemons, turpentine,
oil of Juniper, oil of roses, oil of copaiba, oil of rosemary, and many
other oils, are identical in composition ; and it is not difficult to con-
ceive that perfumery may derive still further aid from chemistry.
Prof. Fehling, in the Wurtemberg Journal of Industry, gives the
following abstract of what is at present generally known respecting
the composition and production of some of the artificial extracts of
fruit. He says:
Amongst the chemical preparations exposed at the London Exhibi-
tion, the artificial extracts of fruits were particularly deserving of
attention. Although some of these extracts, as, for instance, butyric
ether, have already found applications, their use has been hitherto
only on a very limited scale. It is now, however, no longer to be
doubted but that the majority of our artificial organic compositions
will, ere long, be extensively applied, and their practical applications
cannot but have a very stimulating effect on the study of organic
chemistry, which will again most probably lead to the discovery of
technical applications for the new organic compositions, which the
investigations of our modern chemists have furnished us with. Among
the extracts of fruit exhibited by a London manufacturer, those which
more particularly attracted attention were pine apple oil, bergamot
pear oil, apple oil, grape oil, cognac oil, &c. Several of these oils
have been analyzed by M. Faiszt, of Stuttgardt. We give here a
succinct description of some of these extracts, and of their manu-
facture.
Pine Apple Oil.— 'This product consists of a solution of 1 part of
20
224 - ANNUAL OF SCIENTIFIC DISCOVERY.
butyric acid ether, in 8 to 10 parts of spirits of wine. For preparing
butyric acid ether, pure butyric acid is required, and this is obtained
most readily, and in the greatest purity, by the fermentation of sugar
or of St. John’s bread, (siliqua dulcis.) For preparing butyric acid
from sugar, M. Bentch takes a solution of 6 pounds of sugar, and half
an ounce of tartaric acid in 26 pounds of water, which is left to stand
for some days; at the same time about a quarter of a pound of old
decayed cheese is diffused in 8 pounds of sour milk, from which the
cream has been removed; and after this has also stood for some days,
it is mixed with the first solution, and the whole is kept from four to
six weeks at a temperature of about 24° to 28° Reaumer, water being
added from time to time to replace that which is lost by evaporation.
After the evolution of gas has entirely ceased, the liquid is dissolved
with its own bulk of water, and finally 8 pounds of crystallized soda,
dissolved in 12 pounds to 16 pounds of water, are added toit. The
liquid is then filtered and evaporated till it weighs only 10 pounds,
when a quantity of 54 pounds of sulphuric acid, (nordhausen, or fum-
ing sulphuric acid,) diluted with 53 pounds of water, is carefully
mixed with it by small portions at atime. The butyric acid, in the
state of an oily substance, will now appear on the surface of the liquid,
from which it may be skimmed off; but as the remaining liquid still
contains some butyric acid, it is submitted to distillation, by which
means another portion of diluted butyric acid is obtained, which may
be concentrated by means of melted chloride of calcium, or by satu-
rating it with carbonate of soda, evaporating and decomposing by
sulphuric acid. By this method 13 pounds of pure butyric acid are
obtained from 6 pounds of sugar.
M. Marsson says that the same product may be obtained from St.
John’s bread, (siliqua dulcis,) by taking 4 pounds of mashed St. John’s
bread, and mixing it with 10 pounds of water and 1 pound of chalk;
the liquid matter must be maintained from three to four weeks ata
temperature of frgm 25° to 35° Reaumer, and be often and well
stirred, and from time to time the water that has evaporated must be
replaced. After all fermentation has ceased, a quantity of water equal
to the bulk of the liquid is added to it, and afterwards a concentrated
solution of 24 pounds to 23 pounds of carbonate of soda, when it is
finally evaporated. To the concentrated liquid is then added 1}
pounds to 2 pounds of sulphuric acid, diluted with 2 pounds of water ;
and the remainder of the process is performed in the same manner as
already described. By this method a little more than half a pound of
colored butyric acid will be obtained. ‘The acid, however, retains a
peculiar smell from the St. John’s bread, which continues even in the
ether prepared from the same, whereas that prepared from sugar gives
an ether of a very pure smell. It will be found advantageous to agi-
tate the oily butyric acid with chloride of calcium, in order to deprive
it entirely of its moisture.
For preparing butyric acid ether, (butyrate of oxide of ethyle,)
from butyric acid, 1 pound of butyric acid is dissolved in 1 pound of
rectified alcohol, (95° Tralles,) and is mixed with one-half to one-
CHEMICAL SCIENCE. 995
fourth of an ounce of concentrated sulphuric acid; the compound is
heated for some minutes, when the butyric acid ether will form a thin
layer on the top. The whole is then mixed with half of its bulk of
water, and the upper layer taken off; the remaining liquid being sub-
mitted to distillation, yields another quantity of butyric acid ether,
which is mixed with that obtained in the first instance, and the whole
well agitated with a very diluted, solution of soda, in order to deprive
it of all the acid; which operation should be repeated several times
if a very pure ether is desired to be obtained. Care should be taken
to use but small quantities of the diluted soda solution at a time, so as
not to lose too much ether, this latter being in some measure soluble
in water. When large quantities are to be acted upon, the washing
water (eau de lavage,) is collected, mixed with an equal volume of
spirits of wine, and distilled, by which means a solution of pure buty-
ric acid ether in spirits of wine is obtained.
Butyric acid ether may be also obtained immediately from butyrate
of soda, by dissolving 1 part of this salt in 1 part of rectified alcohol,
adding 1 part of sulphuric acid, and heating some minutes. The ether
collects on the top of the liquid, and is purified by washing with water
and with diluted soda solution.
For preparing pine apple oil, 1 pound of butyric acid ether is dis-
solved in 8 pounds to 10 pounds of spirits of wine, which should have
been previously deprived of its empyreumatic or fusel oil. Pure
French spirits of wine will be found best suited for this purpose.
According to the purpose for which the pine apple oil is to be applied,
either rectified alcohol of 80° to 90° Tralles, or brandy of 40° to 50°,
should be used for dissolving the ether. 20 drops to 25 drops of such
an extract will suffice for giving a strong pine apple odor to 1 pound
of sugar solution; to which some acid, such as tartaric or citric acid, is
generally added.
Bergamot Pear Oil. — What is called pear oil is an alcoholic solu-
tion of acetate of oxide of amyle, and acetate of oxide of ethyle, pre-
pared from potato fusel oil, (the hydrate of oxide of amyle.) The
potato fusel oil, or oil of potato spirits (in German, /fuseloel,) is the
compound distilled over towards the end of the first distillation of
spirits made from potatoes, and is an oily liquid of a very strong and
nauseous odor. This oil, in the state in which it is obtained from large
potato brandy distilleries, is never pure; but it may be purified by
agitating it with a diluted soda solution, when the pure fusel oil collects
as an oily layer on the top of the liquid; this oily substance is then
submitted to distillation, and that part which distils over at 100° to
112° Reaumer, is collected, and forms the pure fusel oil.
For preparing acetate of oxide of amyle from this fusel oil, 1 pound
of pure ice vinegar is mixed with an equal quantity of fusel oil, to
which is added half a pound of sulphuric acid ; the liquid. is digested
for some hours at about 100°, when the acetate of oxide of amyle
separates, particularly on being mixed with a small quantity of water.
The remaining liquid, when mixed with more water, yields, on being
submitted to distillation, a further quantity of acetate of oxide of
226 ANNUAL OF SCIENTIFIC DISCOVERY.
amyle. The entire mass of acetate of oxide of amyle thus obtained is
now agitated several times with water, and a little soda solution, in
order to deprive it of all free acid.
The acetate of oxide of amyle may also be obtained by taking 1
part of fusel oil to 14 part of dry acetate of soda, or 2 parts of dry
acetate of potash, with 1 to 14 parts of sulphuric acid. The liquid
having been kept for some time at a gentle heat, the acetate of oxide
of amyle is separated by adding water, and proceeding as above
explained. 15 parts of acetate of oxide of amyle are mixed with 13
part of vinegar ether (vinegar naptha, acetate of oxide of ethyle,) and
dissolved in 100 to 120 parts of spirits of wine, as in the case of pine
apple extract ; an acid, for instance, tartaric or citric, should be added
to the sugar solution, on making use of the pear extract, which addi-
tion makes the flavor of the bergamot pear better distinguishable, and
he taste acquires at the same time more of the refreshing qualities of
ruit.
Apple Oil. — What is called apple oil, is a solution of valerianate of
oxide of amyle in spirits of wine, which may be obtained as a secon-
dary product when fusel oil is distilled with chromate of potash and sul-
phuric acid for the preparation of valerianic acid. The light solution
which collects in the tops of the distilled liquid contains valerianate
of oxide of amyle, together with other liquids, such as aldehyde, which
gives to the product a less agreeable taste and smell. It is therefore
to be preferred for preparing pure valerianate of oxide of amyle.
For preparing valerianic acid, 1 part of fusel oil is mixed by small
portions with 3 parts of sulphuric acid, and afterwards 2 parts of water
are added. At the same time, a solution of 23 parts of bichromate of
potash in 43 parts of water, is heated in a tubular retort; the first
liquid is then permitted to flow very slowly into the liquid of the retort
in such manner that the boiling continues but very slowly. The hquid
which is distilled over is saturated with carbonate of soda, and
is evaporated either to dryness for obtaining valeriarate of soda, or to
the consistency of syrup, when sulphuric acid is added, (say two parts
of concentrated acid diluted with the same quantity of water, for every
three parts of crystalline carbonate of soda.) The valerianic acid
forms an oily layer, on the upper part of the liquid ; which latter will
still yield some valerianic acid, on being submitted to distillation. For
preparing valerianate of oxide of amyle,1 part by weight of pure
fusel oil (hydrate of oxide of amyle,) is mixed carefully with an equal
quantity by weight of common English sulphuric acid; the resulting
solution is added to 14 parts of oily valerianic acid, or to 13 parts of
dry valerianate of soda, and is treated by a water bath, and then mixed
with water, by which means the impure valerianate of the oxide of
amyle will be separated; this is washed several times with water,
afterwards with a solution of carbonate of soda, and finally again with
water. In preparing this compound, it is essential, that the mixture
of sulphuric acid and fusel oil, with valerianic acid, should not be
heated to a too high degree, or too long, as the product would thereby
acquire an insufferably pungent smell, when required for use. 1 part
CHEMICAL SCIENCE. O27,
of valerianate of oxide of amyle is dissolved in 6 or 8 parts of spirits ,
of wine, and acid is added in the same manner, as has been before
explained in the preparation of other extracts.
Artificial Oil of Bitter Almonds.— When Mitscherlich, in 1834,
discovered nitro-benzole, he little thought, after twenty years to find
this body in an industrial exhibition. He certainly, at that time
pointed out the remarkable resemblance which the odor of nitro-ben-
zole had to that of oil of bitter almonds; but the only sources for
obtaining benzole at that time, viz., the oil of compressed gas, and the
distillation of benzoic acid, were much too expensive, and put an end
to the idea of substituting the use of nitro-benzole for oil of bitter
almonds. Mansfield, however, in 1849, showed by careful investiga-
tion, that benzole may be procured easily and in large quantities from
oil of coal tar, and this discovery has not been lost sight of in the arts.
Among the articles of French perfumery in the Great Exhibition,
with the title of artificial oil of bitter almonds, and the fanciful name
of essence of Mirbane, there were several specimens of oils, which
consisted of more or less pure nitro-benzole. The apparatus used in
the preparation of this substance is that proposed by Mr. Mansfield.
It consists of a large glass worm, the upper end of which branches
into two tubes, which are provided with funnels. A stream of con-
centrated nitric acid flows slowly through one of these funnels, whilst
the other is for the benzole, (which for this purpose need not be abso-
lutely pure.) At the point at which the tubes of the funnels are
united, the two bodies come in contact, the chemical compound formed
becomes sufficiently cooled in passing through the worm, and only
requires to be washed with water, and finally with some weak solution
of carbonate of soda, to be ready for use. Although the nitro-benzole
closely resembles oil of bitter almonds, in physical properties, it pos-
sesses, however, a somewhat different odor, readily recognized by a
practised person. However it answers well for scenting soap, and
would be extensively applicable for confectionary and for culinary
purposes. For the latter purpose it has the special advantage over oil
of bitter almonds, that it contains no prussic acid.
The application of organic chemistry to perfumery, is still in its
infancy ; and we may expect that a careful survey of those ethers and
etherial compounds with which we are at present acquainted, and
those which are daily being discovered, will lead to further results.
The interesting caprylic ethers which M. Blouis has lately discovered
are remarkable, for their extremely aromatic odor, (thus the acetate of
caprylic oxide possesses an odor as strong as it is agreeable,) and
promises, if they can be obtained in larger quantities, to yield mate-
rials for perfumery. — Hoffman’s letter to Liebigq.
The subject of the composition and artificial production of the
various extracts of fruit and other similar perfumes and essences,
strikingly illustrates the wonderful progress which has been made in
organic chemistry within the last few years. A position has been
taken by some chemists who have carefully investigated this subject,
which cannot at present be controverted, that the extracts or perfumes
20*
228 ANNUAL OF SCIENTIFIC DISCOVERY.
- of the various fruits which can be artificially prepared in our labora-
tories from the basic organic radicals, are identical, and the same with
those which nature carefully elaborates in the apple, the pear, the pine
apple, banana, and the like. The whole subject has been investigated
more carefully, and has been applied to more practical purposes than
the public is generally aware of. ‘Take for instance the well known
perfumes, known as “ Lubin’s Extracts,” extract of geranium, mille-
fleurs, new-mown hay, and many others ; all of these are stated to be
prepared from two or three of the common and cheap essential oils,
and from the organic radicals. In addition to perfumes the most
agreeable, odors of the most disgusting and nauseous character can
also be produced by like means; as for instance, the odor of the bed-
bug, squash-bug, and of many of the common weeds and plants. As
an odor, or perfume of a different character can be produced by the
action of each different acid on the different oxides of the organic
radicals, the number of bodies of this character capable of being pro-
duced is almost innumerable, and may possibly embrace every known
odor, or perfume, which is now recognized in the animal, vegetable,
or mineral kingdom.
The various artificial extracts of fruit have been applied to the
flavoring of an agreeable species of confectionary known as the
“acidulated fruit drops.” These have been denounced as poisonous
by some persons, on the ground that fusel oil is known to produce
deleterious effects; and asa natural consequence the confectionary
referred to has been discarded. ‘There is, however, no foundation for
such statements or belief, and if the confectionary flavored with these
extracts has in any case produced injurious effects, it 1s undoubtedly
to be referred to an injudicious consumption of it, and not to any
inherent deleterious property. — Editor.
POISONOUS CHLOROFORM.
Tue following is a extract from a letter addressed to the Boston
Medical and Surgical Journal, by Dr. C. T. Jackson, respecting the
poisonous qualities of chloroform, when the so-called fusel oil is con-
tained in it.
Dr. Jackson says: — I have had a strong suspicion that the very
sudden deaths resulting from the inhalation of chloroform must have
been produced by the presence of some poisonous compound of amyle,
the hypothetical radical of fusel oil, or the oil of whisky ; and I began
a series of researches upon this subject several years ago, but was
called off from my work by unexpected persecutions. This work I
have resumed, and I will now state what facts and inductions I am
able to lay before the public :
1. When chloroform, and the alcoholic solution of it ealled chloric
ether, was made from pure alcohol diluted with water, no fatal acci-
dents occurred from its judicious administration.
2. When chloroform was made, as it now too frequently is, from
CHEMICAL SCIENCE. 229
common corn, rye and potato whisky, death began to occur, even
when the utmost care was taken in its administration.
From these data, it might justly be inferred that some poisonous
matter exists in the cheap chloroform of commerce, and I suspected
that it arose from the fusel oil which exists in the whisky. Having
succeeded in procuring some very pure fusel oil, (of whisky,) I
undertook the researches which have resulted in the conviction that
it is the amyle compound that produces the poisonous matter of certain
kinds of chloroform. When mixed with hypochlorite of lime
(bleaching powder) and water in the same way as we prepare alcohol
for the production and distillation of chloroform, I found that the
mixture in the retort, after agitation and standing some time, became
warm, indicating that a reaction was taking place between the fusel
oil and the hypochlorite of lime.
After some hours the retort was placed in a water bath, and distil-
lation was effected, the volatized liquid being copdensed by means of
one of Liebig’s condensers. A clear colorless hquid came over, which
was at once recognized as having the peculiar odor of bad chloroform.
It is perhaps a ter-chloride of amyle, but has not yet been submitted
to analysis. It is so powerful that merely smelling of it makes one
dizzy. ‘In order to make sure that the fusel oil was all decomposed, I
again mixed the product of distillation above mentioned, with a new
lot of bleaching powder and water; and after three hours, with
frequent agitation, it was again distilled, and gave what I regard as
the pure unmixed poison.
If my views are correct, it follows :
1. That all chloroform intended for inhalation as anesthetic agent,
should be prepared from pure rectified alcohol, to be diluted with
water when used for distillation from hypochlorite of lime.
2. That no druggist should sell for anesthetic uses, any chloroform
which is not known to have been properly prepared as above
suggested.
3. That the mixture of chloroform and alcohol, commercially
known under the name of strong chloric ether, must be made with
the same precaution as chloroform.
The following experiments were subsequently made by Dr. Jackson,
which conclusively prove the poisonous effects of fusel oil when
mixed with chloroform : — A full grown rat, confined in a quart glass
jar, inhaled the vapor of the fusel oil compound 40 minutes without
any apparent injury.
A kitten seven days old inhaled the vapor of this compound nine-
teen minutes, without apparent effect.
Three kittens, of the same litter, were confined in three separate
vessels, also saturated with this vapor, thirty-three minutes, and when
released appeared as unharmed as a fourth kitten, of the same litter,
confined in a similar vessel supplied with atmospheric air.
A person inhaled this vapor. twelve minutes without any effect.
The rat, of the above mentioned experiment, was then exposed to
the mixed vapors of chloroform and of the fusel oil compound. In
230 ANNUAL OF SCIENTIFIC DISCOVERY.
fifty-five seconds he rolled upon his side, and in three and a quarter
minutes he was taken out dead.
A half-grown cat, in a vessel of equal capacity, bore the vapor of
chloroform alone but thirty seconds before he fell on his side, and was
taken out dead in two minutes.
A kitten, of the litter above mentioned, exposed to the vapor of
chloroform, became insensible in two minutes. It was taken out in
two minutes and twenty-three seconds and partially revived. It was
again returned to the jar, and in two minutes became insensible, but
continued to breathe slowly for nine minutes, when it was taken out,
and finally recovered.
In all the above experiments the air in the jars was repeatedly
removed with the aid of a bellows.
CHLORIC ETHER, CHLOROFORM, AND TINCTURE OF CHLOROFORM.
THE following statement prepared by Dr. A. A. Hayes, of Boston,
at the request of Dr. Warren, and published in the Boston Medical
Journal, clearly sets forth the distinction between the various
anesthetic agents, chloric ether, chloroform and tincture of chloroform.
Chloric Ether. — This substance is the product arising from the
action of hypochlorites of the alkalies, alkaline earths, on a large excess
of alcohol, much diluted with water.. It is obtained by distillation,
and when carefully prepared contains chloroform, chlorinated ether,
and alcehol. In its formation, a large quantity of acetic acid is pro-
duced, and unites with chlorine and the base of the hypochlorite used
in producing it.
It is a permanent compound, possessing the grateful odor and sweet
taste of chloroform ; when evaporated from the hand, or clean linen,
it leaves no odor adhering to the surface. In this state it is efficient
and convenient for use, as an anesthetic agent. It is indefinite in
composition, but when decomposed by mixture with two bulks of
water, it should deposit about one-third of its original bulk of heavy
oily fluid. The extended use of this substance by some of the sur-
geons of the Massachusetts General Hospital, has led to the attempt to
substitute for it, the tincture of chloroform. It will be seen that these
are not like bodies, and as it is more difficult to prepare chloric ether
than chloroform, the manufacture of the former will doubtless remain
in the hands of the skilful pharmaceutists.
Chloroform.— This substance, as a secondary product, is found
after many reactions, in which chlorine and hydrocarbons are present.
When obtained from hypochlorites and alcohol, the proportion of the
latter substance is very small relatively to that of the hypochlorite
used. After careful purification it is a definite compound of well-
known physical characters. There is, however, an important chemical
character recently observed, which should form a part of its history—
it is decomposed by solar light. In the early stages of its changes,
the odor remains fragrant for some time, but is succeeded by a suffo-
cating and corrosive vapor, arising from the action of hydrochloric
CHEMICAL SCIENCE. 231
(muriatic) acid on hydrocarbons present. If the remaining chloro-
form is carefully washed and purified, and again exposed, the same
changes succeed ; conclusively proving that the property is inherent.
The risk attending the use of compounds having the same odor,
but really foreign in composition arising from the use of alcohol,
which contains fusel oil, in the manufacture of chloroform, is obvious.
There is, however, a preparation sold under the name of tincture of
chloroform, which is objectionable, and as it has been substituted for
chloric ether, has been examined.
When chloroform is added to alcohol of 85 per cent., it dissolves
until about double the value of the alcohol has been mixed. After
subsidence, a singular change has taken place; the water, fusel oil,
and some alcohol, unite to form a layer on the surface of the dense
alcoholic solution of chloroform. This may be removed, but the solu-
tion remains too strong for use. Any alcohol of the shops added,
introduces water, hastening the change which chloroform undergoes.
When anhydrous alcohol is used, unless distillation has been a resort,
the tincture is subject to the same change from neutral 'to acid state, as
chloroform exhibits. After such change hydrochloric acid may be
found in it uncombined, unfitting it for any use.
Theoretically and from observation, the compound chloric ether
seems to be the most permanent and convenient form in which the
power of chloroform can be exhibited, and as such, should take the
place of chloroform, in medical and surgical practice.
The following correct method of preparing chloric ether, is furnished
by Mr. Atwood, of Boston, a chemist of much experience in the sub-
ject. He says: —
“Tn my process for the production of chloric ether, the alcohol is
perfectly freed from fusel oil. A larger proportion of alcohol and
water are also employed than in the manufacture of chloroform. The
following are the proportions I use, viz: — Chloride (hypochlorite) of
lime, 10 Ibs.; water, 8 gallons; pure alcohol, 1 gallon; carbonate of
soda, (crystallized,) half pound. Break down the chloride of lime in
the water until the excess of hydrate of lime is in a uniform pulpy
mass, and the chloride is perfectly dissolved. Place the mass ina still
capable of containing twice the quantity, and introduce the alcohol.
Mix perfectly and apply a moderate fire under the still until distil-
lation commences. Continue the distillation as long as a portion of
the distillate will deposit chloroform on being mixed with its bulk of
sr then change the receiver and collect one gallon of alcoholic
quid.
Add water to the first portion of the distillate as long as chloroform
is precipitated. Separate the light liquid from the chloroform, and
wash the latter in twice its bulk of water containing the carbonate
of soda. Separate the chloroform from the carbonate of soda and
weight it.
Mix the chloroform, washings, and alcoholic liquid in a still placed
in a water-bath. After twenty-four hours’ repose, distill three times
232 ANNUAL OF SCIENTIFIC DISCOVERY.
the weight of the chloroform, and mix perfectly. Preserve in well-
stopped bottles.
The ‘chloric ether’ must not redden litmus paper, or give rise to
a precipitate when mixed with a solution of nitrate of silver.”
ON THE VULCANIZATION OF INDIA RUBBER.
Aw elaborate memoir on the sulphuration of caoutchouc has been
communicated to the French Academy by M. Payen, of which the
following is an abstract. The principal conditions of success, says
M. Payen, in the practical operation of sulphuration have been care-
fully determined in England, America and France, but it has not
been known in what the chemical action consisted; there was no ac-
curate idea concerning what has been called the desulphuration ;
finally, certain alterations, especially the rigidity and fragility of
several objects after sometimes a very short duration of the use for
which they were destined, could not be comprehended, nor, conse-
quently, prevented. The researches I have undertaken, will, I think,
clear up this point of applied science ; I will first describe what occurs
in one of the first processes of vulcanization, still employed by several
manufacturers. If a sheet of caoutchouc, two or three millimetres
in thickness, be kept for two or three hours immersed in sulphur,
liquified at the temperature of 201° to 208° Fahr., the liquid will pene-
trate into the pores as water or alcohol would do, and the weight of
the sheet will be increased 10 or 15 per cent. No considerable mod-
ification, however, will have been made in the properties of the
organic matter; it may be fashioned, and its recent sections joined the
same asin the normal state. Solvents will attack it with the same
energy. It is, however, less porous. If, then, we raise in any
medium whatever, inert of itself, the temperature to 275°, 302°, or
320° Fahr., the conversion will be effected in a few minutes. The mark
would be overshot by prolonging the action of the heat; the product
would become gradually less supple and less elastic, and would very
soon be hard and brittle. This last alteration would be more com-
plete if the caoutchouc were maintained at the same temperature,
(275° to 320° Fahr.,) in fused sulphur ; the proportion of the latter body
absorbed would gradually increase, until it became, in 24 hours,
almost equal to the weight of the organic matter, or would constitute
48 per cent. of the compound. From the commencement of the
action of the sulphur at this temperature, a slight but continuous
disengagement of sulphuretted hydrogen occurs. At the same time
an equivalent quantity of organic matter, containing more carbon
than caoutchouc does, is separated, and may be extracted with a hot
solution of caustic potassa or soda, which do not perceptibly attack
the mass of caoutchouc combined with the sulphur. Liquid sulphur,
at the temperature of 302° absorbs, and may retain, a volume of
sulphuretted hydrogen almost equal to its own. A curious phenome-
non results from the foregoing facts. At the moment when the
abatement of temperature allows the sulphur to crystalize, every
CHEMICAL SCIENCE. 233
crystalline particle liberates a bubble of gas; the latter is sometimes
disengaged, and sometimes is interposed among the crystals; so that
the entire mass gradually swells up, increases from 15 to 20 per cent.
in its original bulk, instead of diminishing, as it should have done
during a normal crystallization of sulphur.
Instead of making the liquid sulphur penetrate at a temperature
approaching its fusing point, caoutchouc may be mixed by means of a
mechanical grinding, with 12 or 20 times its weight of sulphur in fine
powder; the properties of the organic substance are not changed, it
may be modelled and joined as in the normal and unmixed state. If
the temperature be then raised to the degree at which, the vulcaniza-
tion is effected, it takes place as in the first case, and the above
mentioned alterations would likewise be manifested. In regard to
the composition and properties of the caoutchouc vulcanized by the
means above indicated, it has been found, that when the suitable term
has not been exceeded, the organic matter contained sulphur in two
different states; from 1 to 2 per cent. are retained in intimate combi-
nation, and the surplus remains simply interposed between its pores.
The sulphur in excess, uncombined, is gradually eliminated from the
caoutchouc by the mechanical action alternately exerted by the
extension which closes the pores, and the contraction which opens
them. This effect lasts for several months. Many chemical agents
more or less quickly or completely effect the elimination of the
interposed sulphur, especially solutions of caustic potassa or soda,
with the aid of heat, (and even without heat if renewed several times
within a month,) sulphuret of carbon, essence of turpentine, benzine
and anhydrous ether. These liquids swell up the organic matter to
such an extent that its volume is very soon increased eight. or
nine times. Ether removes sulphur in a very peculiar manner; a
small portion is first dissolved, and then carried out, when it is separ-
ated into crystalline particles; other particles successively dissolved in
the interior follow the same course, and the crystals soon become very
bulky, affecting the octahedral form. Neither essence of turpentine,
or benzine bring to the outside the crystalline particles of sulphur
carried into the thickness of the swelled-up substance. Ether and sul-
phuret of carbon, kept for a long time in contact with vulcanized
caoutchouc retain in solution 4 or 5 hundredths of caoutchouc, which
may be isolated by evaporating several times and redissolving in ether
which eliminates the free sulphur, and then by alcohol which removes
from 1 to 1-50 per cent. of fatty matter. The caoutchouc thus ex-
tracted may be separated into two parts; one, very ductile dissolved
by benzine, which deposits it in evaporating ; the other more tena-
cious, and less extensible, is not dissolved. These two parts come
from the interior of the plates, at a certain depth where the combi-
nation is less intimate and less abundant in sulphur than near the
surface. After vulcanization, caoutchouc is also formed of two parts
endowed with unequal cohesion and solubility ; this is recognized by
keeping a strip steeped for two months in a mixture of 10 parts of
sulphuret of carbon and one part of anhydrous alcohol; the portion
234 ANNUAL OF SCIENTIFIC DISCOVERY.
dissolved consists of interposed sulphur, which is removed after
dessication by a solution of caustic soda; there then remains the least
ageregated and least resistant organic substance, which is yellowish and
translucent. The undissolved portion then remains under the form of
a tenacious strip, which has become brown and less transparent. The
following are the proportions obtained, besides the fatty matter: tena-
cious insoluble portion, 65 ; soft soluble portion, 25; sulphur in excess, 10.
The process of vulcanization in the cold way, imvented by Mr.
Parker, of England, consists in immersing the sheets, or tubes of
caoutchouc ina mixture of 100 parts of sulphuret of carbon, and 2.5
protochloride of sulphur. The liquid in penetrating into the organic
substance, swells it, and deposits the sulphur, which combines with the
caoutchouc, abandoning the unstable combination which it formed in
the chloride. The- superficial portion would be too strongly vulcan-
ized and become brittle, if these objects were not removed in one or
two minutes, and immediately immersed in water. In this case the
chloride of sulphur, decomposed by its contact with the water, ceases
to act on the surface, while the portions which have entered farther in
continue their sulphurizing action on the interior. ‘This is an ingen-
ious means of regulating this kind of vulcanization by the cold way.
A process, which seemsstill more preferable, as regards the healthi-
ness and regularity of the operation, is due to the same inventor. It
is effected by keeping the objects to be vulcanized immersed for two or
three hours in close vessels, in a solution of 25° Baume, of polysul-
phuret of potassium, at a temperature of 284° Fahr., and submitting to
a washing in an alkaline solution, and then in pure water. We are
thus enabled to combine caoutchouc with a useful proportion of
sulphur, without allowing an excess of it to be interposed in its pores,
thus avoiding the inconveniences of the unequal sulphurization of the
organic substance.
COMPOSITION FOR SILVERING GLASS.
PREPARE a mixture of 30 grains ammonia, 60 grains nitrate of
silver, 90 grains spirit of wine, and 90 grains of water. When the
nitrate of silver is completely dissolved, filter the liquid and add a
small quantity of sugar, for example, 15 grains of the grape sugar
previously dissolved in a mixture of 14 ounces of water, and 13
ounces spirit of wine.
For silvering a glass it is sufficient to leave this solution in contact
with the glass during two or three days. — Civil Engineer and Archi-
tect’s Journal.
PREPARATION OF PURE METHYLIC ALCOHOL.
Wouter has given a very simple and elegant method of preparing
pure wood-spirit from the raw material of commerce, which is of
interest both to the chemist and pharmaceutist. Raw wood-spirit is to
be mixed with an equal weight of sulphuric acid, avoiding an elevation
CHEMICAL SCIENCE. 235
of temperature. The mixture is to be allowed to stand a day, then
distilled from two parts by weight of binoxalate of potash. A volatile
fluid at first passes over, after which the oxalate of methyl condenses
in the neck of the retort. The receiver is now to be changed and the
distillation continued as long as the ether comes over. The neck of
the retort is then to be gently warmed and the oxalate allowed to flow
into the receiver when it is to be strongly pressed between folds of
bibulous paper, and then freed from volatile products by long fusion.
In this way it is obtained directly perfectly colorless. The liquid
which passes over first contains also oxalate of methyl which is readily
obtained by evaporation and crystallization. The pure oxalate of
methyl prepared in this manner is now to be distilled with water ;
pure wood-spirit passes over and oxalic acid remains in the retort.
[ This method obviously presents great advantages over the tedious
processes of Dumas and Kane.]— Ann. der Chemie und Pharmacie,
Ixxxi.
FORMATION OF SULPHURIC ACID FROM SULPHUROUS ACID AND
OXYGEN.
Wouter has published a few observations relating to the formation
of sulphuric acid, which, although involving no new principle, promise
to be of great importance in a manufacturing point of view. The
action of spongy platinum at a high temperature upon a mixture of
sulphurous acid and air or oxygen, has long been known. A patent
was even granted to Peregrine Phillips for the manufacture of sul-
phuric acid by this process, the anhydrous acid formed being condensed
and united to water in an appropriate receiver. The method was
however abandoned as a more extended experience showed that the
platinum speedily lost its power of condensation. Wohler has now
found that various metallic oxides possess in a high degree the property
of causing the union of mixed gases. When the oxides of copper,
iron, or chromium, are heated to a low fedness in a glass tube and a
mixture of sulphurous acid and air or oxygen is caused to pass over
them, thick white vapors of anhydrous sulphuric acid are formed. A
_ mixture of the oxides of chromium and copper prepared by precipi-
tation was found to be particularly efficient; the same quantity of
oxide appeared capable of converting an unlimited quantity of the
mixed gases into sulphuric acid, and the production of sulphuric acid
was so easy and rapid as to lead to the idea of practical application on
a large scale. Metallic copper in a state of powder produces sulphuric
acid in a similar manner, but only when heated and when its surface
has become converted into oxide. No hydrate of sulphuric acid is
formed by passing the vapor of water over the oxide at the same time
with the gaseous mixture. Platinum foil polished and cleaned acts
upon the gaseous mixture like spongy platinum, but not at ordinary
temperature. A mixture of the oxides of copper and iron prepared
by precipitation and ignited, becomes and remains incandescent when
21
236 ANNUAL OF SCIENTIFIC DISCOVERY.
warmed and held in a current of hydrogen gas.— Ann. der Chemie
und Pharmacie, 1x xxi. |
ON THE DECOLORIZING POWER OF CHARCOAL AND OTHER BODIES,
Ir is generally said that charcoal is the only simple body which
possesses the property of absorbing coloring matters dissolved in a
liquid ; it results, moreover, from the labors of Bussy and Payen, that
decoloration by charcoal is a purely physical phenomena, a phenomena
of dyeing. Several compound bodies, (alumina, sulphuret of lead
prepared by the humid way, and hydrate of lead) also possess the
property of decoloring liquids ; but chemists for the most part, regard
the action which the oxides exert on coloring matters in the prepar-
ation of lakes as a chemical action, different from that of charcoal.
However, Berzelius thought he might compare the decoloration by
the oxides and the metallic salts with that produced by charcoal. In
a communication submitted to the French Academy by M. Filhol, the
author proves that charcoal is not the only simple body which possesses
the property of decoloring liquids ; sulphur, arsenic, and iron, resulting
from the reduction of hydrogen, have appreciable decoloring power.
The number of compound bodies endowed with an appreciable decol-
oring power is much greater than has been supposed, as this property
seems to depend much more on the state of division of these bodies
than on their chemical qualities. It was also shown thata certain body
which easily appropriates one coloring matter, may have very little
tendency to remove another; thus bone phosphate of lime (artifically
obtained) with difficulty decolors a solution of sulphindigotate of soda,
whilst it acts on tincture’ of litmus more energetically than animal
black. The decoloration is in the great majority of cases, a purely
physical phenomena; thus, the same coloring matter is absorbed by
metalloids, metals, acids, bases, salts, and organic substances, besides it
is easy, by employing suitable solvents, to procure the color unaltered
from the body by which it had been absorbed. — Comptes Rendus, 1852.
DEODORIZING PROPERTIES OF COFFEE.
THE London Medical Gazette gives the result of numerous experi-
ments with roasted coffee, proving that it is the most powerful means,
not only of rendering animal and vegetable effluvia innocuous, but of
actually destroying them. A room in which meat in an advanced
degree of decomposition had been kept for some time, was instantly
deprived of all smell, on an open coffee roaster, being carried through
it, containing a pound of coffee newly roasted. In another room
exposed to the effluvium occasioned by the clearing out of a cess pit,
so that sulphuretted hydrogen and ammonia in great quantities could
be chemically detected, the stench was completely removed within half
a minute, on the employment of three ounces of fresh roasted coffee,
whilst the other parts of the house were permanently cleared of the
CHEMICAL SCIENCE. 237
same smell by being simply traversed with the coffee roaster, although
the cleansing of the cess pit continued several hours after.
The best mode of using the coffee as a disinfectant is to dry the raw
bean, pound it in a mortar, and then roast the powder on a moderately
heated iron plate until it assumes a dark brown tint, when it is fit for
use. Then sprinkle it in sinks or cess pools, or lay it on a plate in the
rooms which you wish to have purified. Coffee acid or coffee oil acts
more readily in minute quantities.
ADULTERATION OF BEER WITH STRYCHNINE.
GRAHAM and HorrMan, at the instance of a prominent English
brewer, Mr. Alsopp, and in consequence of reports, originating in
Paris, that English ale and beer occasionally derived its bitterness
from strychnine, have carefully tested various specimens of these bey-
erages, but without discovering a trace of the poisonous alkaloid.
Strychnine when present in no greater quantity than 1-1,000 of a
grain may be detected by the following process. The suspected pow-
der is to be moistened with a drop of undiluted sulphuric acid and a
few fragments of bichromate of potash added. An intense beautiful
violet color immediately appears at the points of contact which quickly
spreads through the whole fluid, and after a few minutes again vanishes.
The presence of small quantities of organic matter prevents this
reaction ; in testing beer the authors adopted the following process.
Half a gallon of beer to which half a grain of strychnine had been added
was shaken with two ounces of animal charcoal, and the fluid allowed
to stand over night. The next day the beer was found to be almost
free from bitterness, the strychnine having been precipitated with the
coal. The coal was thrown on a filter, washed, boiled with alcohol
and the alcoholic filtrate distilled. The residue in the retort was
shaken with a few drops of a solution of caustic potash and about an
ounce of ether. The etherial solution evaporated on a watch glass
gave a mass in which the presence of strychnine was easily detected by
the test above given Ann. der Chemie und Pharmacie.
ADTLTERATION OF ANCHOVIES.
THE London Lancet gives the result of the investigation of the
Analytical Sanitary Commission into the composition_of “Anchovies,”
as vended in the metropolis. Having analyzed 28 samples, the follow-
ing conclusion has been arrived at: That seven of the samples consisted
entirely of Dutch fish. That two of the samples consisted of a mix-
ture of Dutch fish and anchovies. That the brine in 23 of the
samples was charged with either bole Armenian or Venetian red, the
quantity varying considerably in amount; but in most cases the brine
was saturated with these earthy powders to such an extent that they
might be obtained and collected from the botton of the bottles almost
by teaspoonfulls. The commissioners add : —‘ It is not to be inferred
that these samples in which no Dutch fish were detected consisted of
238 ANNUAL OF. SCIENTIFIC DISCOVERY.
the true anchovy, since we have ascertained that two other kinds of
fish besides the Dutch are commonly imported and sold as ‘true
anchovies,’ and ‘real Gorgonas’ —namely French and Sicilian fish.”
A further investigation established the fact, that not one-third of the
28 samples consisted of Gorgona anchovies.
ON THE ANALYSIS OF OPIUM, ESPECIALLY WITH REFERENCE TO
THE PROPORTION OF MORPHIA CONTAINED IN IT.
Tue following new process for the examination of opium is given by
Dr. Riegel, of Carlsruhe, in the Jahrbuch de Pharmacie, Nov. :
Half an ounce of opium to be examined is cut in small pieces and
bruised in a mortar with alcohol at 71°; the fluid is then expressed
through linen, and the refuse washed with from ten to twelve drachms
of the same alcohol ; the alcoholic solution is then to be filtered into a
glass containing one drachm of spirits of ammonia. In twelve hours’
time, all the morphia, with some narcotine and meconate of ammonia,
will have become deposited. In order to effectually separate the mor-
phia, the adhering meconate of ammonia must be removed by washing
in water and then shaking the crystals in pure ether, or better still in
chloroform, in which the narcotine is readily dissolved, while the mor- .
phia remains entirely insoluble. After this treatment the morphia
remains behind in large gritty crystals, slightly discolored. This
process may be varied by employing boiling alcohol and powdered
opium, and adding the solution still hot, to the solution of ammonia.
According to good authorities, 15 grammes of opium should yield at
least 1.25 grammes, or 8.33 per cent. Reich estimates 10, and others
12 percent. The author gives the percentage of morphia which is
obtained by the various processes of different experiments, and states
that the largest proportion (13.50 per cent.) is procured by the pro-
cess above described, which he considers also to be the simplest and
most certain for ascertaining the proportion of morphia. ;
The following process is also recommended by Dr. Riegel for the
detection of small quantities of opium. To the suspected substance
some potash is to be added, and then shaken with ether. A strip of
white blotting paper is to moistened with the solution several times
repeated. When dry, the paper is to be moistened with muriatic
acid, and exposed to the steam of hot water; if opium be present, the
paper will be more or less colored red.
METHOD FOR DETECTING THE ORGANIC ALKALOIDS.
THE following paper, by Prof. Stass, of Brussels, is published in
the Bulletin de ? Academie Royal de Medecine de Belgique.
Whatever certain authors may have said on the subject, it is possi-
ble to discover, in a suspected liquid, all the alkaloids, i whatever
state they may be. I am quite convinced that every chemist, who
has kept up his knowledge as to analysis, will not only succeed in
detecting their presence, but even in determining the nature of that
CHEMICAL SCIENCE. 239
which he has discovered, provided that the alkaloid in question is one
of that class of bodies, the properties of which have been suitably
studied. Thus he will be able to discover coniine, nicotine, aniline,
picoline, petinine, morphine, codeine, narcotine, strychnine, brucine,
veratrine, colchicine, delphine, emetine, solanine, aconitine, atrophine,
and hyoscyamine. Ido not pretend to say, that the chemical study
of all these alkaloids has been sufliciently well made to enable the
experimenter who detects one of them to know it immediately,
and affirm that it is such an alkaloid, and no other. Nevertheless, in
those even which he cannot positively determine or specify, he may
be able to say that it belongs to such a family of vegetables, the Sola-
nacez, for example. In case of poisoning by such agents, even this
will be of much importance. The method which I now propose for
detecting the alkaloids in suspected matters, is nearly the same as that
employed for extracting those bodies from the vegetables which con-
tain them. The only difference consists in the manner of setting
them free, and of presenting them to the action of solvents. We
know that the alkaloids form acid salts, which are equally soluble in
water and alcohol; we know, also, that a solution of these acid salts
can be decomposed, so that the base set at liberty remains either
momentarily or permanently in solution in the liquid. J have observed
that all the solid and fixed alkaloids above enumerated, when maintained
in a free state and in solution in a liquid, can be taken up by ether when
this solvent is in sufficient quantity. Thus, to extract an alkaloid from
a suspected substance, the only problem to resolve consists in sepa-
rating, by the aid of simple means, the foreign matters, and then find-
_ing a base which, in rendering the alkaloid free, retains it in solution,
in order that the ether may extract it from the liquid. Successive
treatment by water, and alcohol of different degrees of concentration,
suffices for separating the foreign matters, and obtaining in a small
bulk,-a solution in which the alkaloid can be found. The bicarbo-
nates of potash or soda, or these alkalies in a caustic state, are
convenient bases for setting the alkaloids at liberty, at the same time
keeping them wholly in solution, especially if the alkaloids have been
combined with an excess of tartaric or of oxalic acid.
To separate foreign substances, animal or otherwise, from the sus-
pected matters, recourse is commonly had to the tribasic acetate of
lead, and precipitating the lead afterwards by a current of sulphu-
retted hydrogen. As I have several times witnessed, this procedure
has many and very serious inconveniences. In the first place, the
tribasic acetate of lead, even when used in large excess, comes far
short of precipitating all the foreign matters; secondly, the sulphu-
retted hydrogen, which is used to precipitate the lead, remains in
combination with certain organic matters, which undergo great
changes by the action of the air, and of even a moderate heat; so
that animal liquids, which have been precipitated by the tribasic ace-
tate of lead, and from which the lead has been separated afterwards
by hydrosulphuric acid, color rapidly on exposure to the air, and
exhale at the same time a putrid odor, which adheres firmly to the
21*
240 ANNUAL OF SCIENTIFIC DISCOVERY.
matters which we extract afterwards from these liquids. The use of
a salt of lead presents another inconvenience, viz: the introduction
of foreign metals into the suspected matters, so that that portion of
the suspected substance is rendered unfit for testing for mineral sub-
stances. The successive and combined use of water and alcohol at
different states of concentration, permits us to search for mineral sub-
stances, whatever be their naturc; so that in this way nothing is
compromised, which is of immense advantage when the analyst does
not know what poison he is to look for.
It is hardly necessary to say, that in medico-legal researches for the
alkaloids, we ought never to use animal charcoal for decolorizing the
liquids, because we may lose all the alkaloid in the suspected matters.
It is generally known that animal charcoal absorbs these substances at
the same time that it fixes the coloring and odoriferous matters.
The above observations do not proceed from speculative ideas only,
but are the result of a pretty long series of experiments which I have
several times employed for discovering these organic alkaloids. ‘To
put in practice the principles which I have thus explained, the follow-
ing is the method in which I propose to set about such an analysis : —
I suppose that we wish to look for an alkaloid in the contents of the
stomach or intestines; we commence by adding to these matters
twice their weight of pure and very strong alcohol;* we add after-
wards, according to the quantity and nature of the suspected matter,
from 10 to 30 grs. of tartaric or oxalic acid — in preference, tartaric ;
we introduce the mixture into a flask, and heat it to 160° or 170°
Fahr. After it has completely cooled, it is to be filtered, the insoluble
residue washed with strong alcohol, and the filtered liquid evaporated
in vacuo. If the operator has not an air-pump, the liquid is to be
exposed to a strong current of air at a temperature of not more than
90° Fahr. If, after the volatilization of the alcohol, the residue con-
tains fatty or other insoluble matters, the liquid is to be filtered a
second time, and then the filtrate and washings of the filter evapo-
rated in the air-pump till nearly dry. If we have no air-pump, it
is to be placed under a bell jar over a vessel containing concentrated
sulphuric acid. We are then to treat the residue with cold, anhy-
drous alcohol, taking care to exhaust the substance thoroughly; we
evaporate the alcohol in the open air at the ordinary temperature, or
still better, in vacuo ; we now dissolve the acid residue in the smallest
possible quantity of water, and introduce the solution into a small
test tube, and add, little by little, pure powdered bicarbonate of soda
or potash, till a fresh quantity produces no further effervescence of
carbonic acid. We then agitate the whole with four or five times its
bulk of pure ether, and leave it to settle. When the ether swimming
* When we wish to look for an alkaloid in the tissue of an organ, as the liver,
heart, or lungs, we must first divide the organ into very small fragments, moisten
the mass with pure strong alcohol, then express strongly, and_ by further
treatment with alcohol exhaust the tissue of every thing soluble. The liquid so
obtained is to be treated in the same way as a mixture of suspected matter and
alcohol
CHEMICAL SCIENCE. 241
on the top is perfectly clear, decant some of it into a capsule, and
leave it in a very dry place to spontaneous evaporation.
Now, two orders of things may present themselves — either the
alkaloid contained in the suspected matter is liquid and volatile, or
solid and fixed. I shall now consider these two hypotheses.
Examination for a Liquid and Volatile Alkaloid.— We suppose
there exists a liquid and volatile alkaloid.. In such a case, by the
evaporation of the ether, there remain in the inside of the capsule
some small liquid striz:, which fall to the bottom of the vessel. In this
case, under the influence of the heat of the hand, the contents of the
capsule exhale an odor more or less disagreeable, which becomes,
according to the nature of the alkaloid, more or less pungent, suffo-
cating, irritant ; it presents, in short, a smell like that of a volatile
alkali, masked by an animal odor. If we discover any traces of the
presence of a volatile alkaloid, we add then to the contents of the
vessel, from which we have decanted, a small quantity of ether, 1 or
2 fiuid drachms, of a strong solution of caustic potash or soda, and
agitate the mixture. After a suflicient time, we draw off the ether
into a test-tube, exhaust the mixture by two or three treatments with
ether, and unite all the etherial fluids. We pour afterwards into this
ether, holding the alkaloid in solution, 1 or 2 drachms of water, acidu-
lated with a fifth part of its weight of pure sulphuric acid, agitate it
for some time, leave it to settle, pour off the ether swimming on the
top, and wash the acid liquid at the bottom with a new quantity of
ether. As the sulphates of ammonia, of nicotine, aniline, quinoleine,
picoline, and petinine are entirely insoluble in ether, the water acid-
ulated with sulphuric acid contains the alkaloid in a small bulk, and
in the state of a pure sulphate; but as the sulphate of coniine is
soluble in ether, the ether may contain a small quantity of this alka-
loid, but the greater part remains in the acidulated watery solution.
The ether, on the other hand, retains all the animal matters which it
has taken from the alkaline solutions. If it, on spontaneous evapora-
tion, leaves a small quantity of a feebly colored yellowish residue, of
a repulsive animal odor, mixed with a certain quantity of sulphate of
coniine, this alkaloid exists in the suspected matter under analysis.
To extract the alkaloid from the solution of the acid sulphate, we
add to the latter an aqueous and concentrated solution of potash
or caustic soda; we agitate and exhaust the mixture with pure ether;
the ether dissolves ammonia, and the alkaloid is now free. We
expose the etherial solution at the lowest possible temperature to
spontaneous evaporation ; almost all the ammonia volatilizes with the
ether, whilst the alkaloid remains as residue. To eliminate the last
traces of ammonia, we place, for a few minutes, the vessel containing
the alkaloid in a vacuum over sulphuric acid, and obtain the organic
alkaloid, with the chemical and physical characters which belong to
it, and which it is now the chemist’s duty to determine positively. I
applied the process which I have described to the detection of nico-
tine in the blood from the heart of a dog poisoned by 2 cubic centims.
(0.78 eubic inch) of nicotine introduced into the xsophagus; and
242 ANNUAL OF SCIENTIFIC DISCOVERY.
I was able, in a most positive manner, to determine the presence of
nicotine in the blood. I was able to determine its physical characters,
its odor, taste, and alkalinity. I succeeded in obtaining the chloro-
platinate of the base perfectly crystallized in quadrilateral rhomboidal
prisms of a rather dark yellow color, and to ascertain their insolubility
in alcohol and ether.
I have applied the same process to the detection of coniine in a
very old tincture of hemlock, and I was equally successful in extract-
ing from the liquid colorless coniine, presenting all the physical and
chemical properties of this alkaloid. I was also able to prove that the
ether which holds coniine in solution, carries off a notable portion of
this alkaloid, when the solvent is exposed to spontaneous evaporation.
Examination for a Solid and Fixed Alkaloid. — Let us now suppose
that the alkaloid is solid and fixed; in that case, according to the
nature of the alkaloid, it may happen that the evaporation of the ether
resulting from the treatment of the acid matter, to which we have
added bicarbonate of soda, may leave or not a residue containing an
alkaloid. If it does, we add a solution of caustic potash or soda to
the liquid, and agitate it briskly with ether. This dissolves the vege-
table alkaloid, now free, and remaining in the solution of potash or
soda. In either case, we exhaust the matter with ether. Whatever
be the agent which has set the alkaloid free, whether it be the bicar-
bonate of soda or potash, or caustic soda or potash, it remains, by the
evaporation of the ether, on the side of the capsule as a solid body,
but more commonly as a colorless milky liquid, holding solid matters
in suspension. The odor of the substance is animal, disagreeable, but
not pungent. It turns litmus paper permanently blue.
When we thus discover a solid alkaloid, the first thing to do is to
try and obtain it in a crystalline state, so as to be able to determine
its form. Put some drops of alcohol in the capsule with the alkaloid,
and leave the solution to spontaneous evaporation. It is, however,
very rare that the alkaloid obtained by the above process, is pure
enough to crystallize. Almost always it is contaminated with foreign
matters. To isolate these substances, some drops of water, feebly
acidulated with sulphuric acid, are poured into the capsule, and then
moved over its surface, so as to bring it in contact with the matter in
the capsule. Generally we observe that the acid water does not
moisten the sides of the vessel. The matter which is contained in it
separates into two parts; one formed of greasy matter which remains
adherent to the sides; the other alkaline, which dissolves and forms
an acid sulphate. We cautiously decant the acid liquid, which ought
to be limpid and colorless, if the process has been well executed; the
capsule is well washed, with some drops of acidulated water, added
to the first liquid, and the whole is evaporated to three-fourths in
vacuo, or under a bell jar over sulphuric acid. We put into the
residue a very concentrated solution of pure carbonate of potash, and
treat the whole liquid with absolute alcohol. This dissolves the
alkaloid, while it leaves untouched the sulphate of potash, and excess
of carbonate of potash. The evaporation of the alcoholic solution
CHEMICAL SCIENCE. ee)
gives us the alkaloid in crystals. It is now the chemist’s business to
determine its properties, to be able to prove its individuality. I have
applied the principles which I have just expounded to the detection
of morphine, iodine, strychnine, brucine, veratrine, emetine, colchi-
cine, aconitine, atrophine, hyoscyamine; and I have succeeded in
isolating, without the least difficulty, these different alkaloids, previ-
ously mixed with foreign matters. I have thus been able to extract
by this process, morphine from opium, strychnine and brucine from
nux vomica, veratrine from extract of veratrum, emetine from extract
of ipecacuanha, colchicine from tincture of colchicum, and the like.
Thus it is in all confidence that I submit this process to the considera-
tion of chemists who undertake medico-legal researches.
ON THE DETERMINATION OF PHOSPHORIC ACID BY MOLYBDATE
OF AMMONIA.
SILLIMAN’s Journ: 1 for May contains the followimg article by Mr.
W. J. Craw, of New Haven, on the determination of phosphoric
acid by molybdate of ammonia:
The determination of phosphoric acid has always been one of the
most important and most difficult problems of analytical chemistry.
The bases with which it is most frequently united, are iron, alumina,
the alkalies and alkaline earths. Several of these combinations are
decomposed with very great difficulty, the phosphate of alumina in
particular, resisting nearly every effort to reduce it to its component
parts. Although good methods have been proposed for the analysis
of many of the simple phosphates, that of phosphate of lime for
instance, yet it usually happens that several of these occurs together ;
and until very recently no process has been devised which could effect
the separation of phosphoric acid from all the bases previously men-
tioned, when incompany. A great amount of labor has been spent
by chemists, within the last few years, in the effort to overcome this
difficulty. Numerous ways have been tried with greater or less
success, but most of these contain inherent difficulties, which in many
cases prevent their applications. Even Rose’s process by carbonate of
baryta, though a monument of profound knowledge and admirable
research, is yet too complicated to yield good results, except in the
hands of those who have practised it so often as to be perfectly famil-
iar with all the necessary precautions. The great desideratum of a
simple and accurate method for the determination of phosphoric
acid, with whatever substances it may be combined, has been supplied
by Sonnenschein. He states that the yellow precipitate produced by
molybdate of ammonia in the solution of a phosphate, contains phos-
phoric acid as an essential constituent, and not, as asserted by
Svanberg, and Struve, an accidental admixture. From several
analyses of this compound he finds it to contain about three per cent.
of phosphoric acid. A number of trials were also made to find
whether by this means phosphoric acid could be separated and deter-
mined quantitatively which were completely successfull. For this pur-
244 ANNUAL OF SCIENTIFIC DISCOVERY.
pose a large quantity of the molybdate solution is prepared as follows :
one part of molybdic acid is dissolved in eight parts of ammonia, and
twenty of nitric acid. The phosphate is dissolved in nitric acid, and
there is added to it, a quantity of molybdic acid equal to about thirty
times that of the phosphoric acid. The solution with the precipitate
is digested for some hours with the aid of a very gentle heat, filtered,
and washed with the same solution which was used for the precipita-
tion. The whole is then dissolved in ammonia, and the phosphoric
acid thrown down by a magnesian salt. The presence of molybdic
acid is not injurious, as the double molybdate of ammonia and mag-
nesia is easily soluble. Sonnenschien’s experiments on the separation of
ee acid from alumina and other bases all gave very good
results.
With a view of confirming this discovery, and also of ascertaining
with more precision the cause of the peculiar behavior exhibited by
this substance towards re-agents, numerous trials have been made with
it by Mr. Craw. Solutions of the caustic alkalies, and the alkaline
carbonates and phosphates, dissolve the yellow compound even in
the cold. So do also chloride of ammonium, and oxalate of ammonia.
The mineral acids also act upon it to some extent. Cold water
dissolves it with great difficulty, though it is soluble in hot water. It
appears to be decomposed to a small extent by the combined influence
of air and moisture, as it turns blue when dried in the atmosphere after
washing with water. Its behavior towards solvents is changed by the
presence of molybdate of ammonia, so that it becomes nearly insoluble
in acids even on boiling. The act of solution is probably in all cases
attended with decomposition and removal of molybdie acid which is
prevented by the presence of molybdate of ammonia. Some quanti-
tative experiments were also made on the separation of phosphoric
acid from the bases, and the results obtained confirm those of Sonnen-
schein, and show that the method as regards accuracy, is all that can
be desired, while in point of simplicity, it is superior to any of the old
processes. It will prove of especial advantage in cases where, as in
the analysis of soils, a small quantity of phosphoric acid is associated
with a variety of other substances existing in much larger proportion.
It may be important to remark, that when effecting the precipitation
by means of molybdate of ammonia, this, as well as nitric acid, should
be in decided excess. To ascertain when this is the case, before fil-
tering off the solution, a drop of it may be transferred to a solution of
sulphuretted hydrogen, when a brown precipitate of sulphuret of
molybdenum will appear. After separating the yellow precipitate
from the solution, the latter should be always allowed to stand for
some time in a warm place, to see whether any additional precipitate
is formed.
ON A SPECIAL ACID OF THE LUNGS.
M. Dumas recently presented a paper to the academy, giving an
account of his and M. Verdiel’s researches on a special acid secreted
CHEMICAL SCIENCE. 245
by the pulmonary parenchyna in most animals, and which may be
found free, but is usually combined with a salt of soda. Obtained in
the crystalline form, it is a brilliant body, strongly refracting light. It
does not lose its water of crystallization at a temperatue of 100°
Centigrade ; but when heated still more, it decrepitates, melts and is
decomposed, giving rise to empyreumatic products. Much coal re-
mains, which disappears without leaving any traces of ash. It is
soluble in water and boiling alcohol, but not in cold alcohol or ether.
Its ultimate analysis exhibits definite proportions of carbon, hydro-
gen, oxygen, nitrogen and sulphur. It forms crystallized salts with
bases, and expels carbonate acid from the carbonates. The existence
of this substance is of high physiological interest; for the acid thus
secreted by the parenchyma comes in contact with the carbonate of
soda of the blood, transported by the capillaries, and decomposes it,
uniting with the soda and setting free the carbonic acid which is
-exhaled. The presence of a portion of this acid in the free state, in
the parenchyma, indicates that it is really there that it is formed, and
not in the blood, which is an alkaline fluid. By uniting with the soda
of the blood, the acid does not change the reaction of that fluid, since
it merely takes the place of the carbonic acid which is expelled dur-
ing expiration. — Journ. de Chemie Medicale. ;
ON CHROMIC ACID AS AN ESCHAROTIC.
Curomic acid has been on the recommendation of Dr. Heller tried
in many cases as an escharotic, and the results thus far obtained justify
a further trial of it in cases in which a deeply penetrating, gradual
caustic, and ene constant in its effect would be indicated. When
employed in substance, its action is exceedingly slow and gradual,
eccupying many hours; nevertheless in intensity it exceeds that of
the caustic alkalies. In extremely concentrated solution, its action is
less penetrating and less gradual, but at the same time, it is more con-
tinuous than that of all other known caustics; on the other hand, the
more dilute the solution, the more transient and superficial is the
effect. The facility with which its action can thus be graduated ren-
ders it in all cases a suitable escharotic. The method of application
is as follows: the surrounding parts having been protected by folds of
lint, adhesive plaster, &c., the chromic acid is spread with a spatula on
the part to be cauterized, so as to form a layer scarcely a line in thick-
ness, which is covered with lint, kept in its place by adhesive plaster.
The concentrated solution may be applied by means of a glass rod, or
hair pencil, and the part after a few moments’ exposure covered with
lint. If chromic acid be applied to sound parts, a moderate sensation
of burning commences in ten or fifteen minutes after the application,
increasing for three or four hours, and then diminishing for about an
equal space of time. Its application to ulcerated parts excites similar
sensations instantaneously. Undissolved chromic acid causes severer
and more permanent pains; these are also more violent when the
cutis vera itself, and not morbid growths is cauterised. The pain does
246 ANNUAL OF SCIENTIFIC DISCOVERY.
not disturb the patient’s sleep, and is incomparably less than that
caused by other caustics, such as sulphuric or nitric acids, nitrate of
silver, corrosive sublimate, caustic potassa, &c. According to Dr.
Heller’s experiments, all organic compounds are soluble in the easily
deoxidable chromic acid, their ultimate elements being raised to a
higher degree of oxidation, and partly uniting with the acid. An
elevated temperature accelerates this process. Smaller animals, mice,
birds, &c., were so completely dissolved by chromic acid in fifteen or
twenty minutes, that no trace of their bones, skin, hair, claws or teeth
could be discovered.
WHY BREAD BECOMES STALE.
“Av a late meeting of the French Academy a discussion took place
respecting the grave yet apparently simple question why bread
becomes stale. M. Boussingault laid down that staleness is not, as is
generally supposed, caused by the proportion of water diminishing ;
but arises from a molecular state which manifests itself during the
cooling, becomes afterwards developed, and persists as long as the
temperature does not exceed a certain limit. M. Thenard said, that
it is cause by bread being a hydrate which heat softens, and to which
a lower temperature gives more consistency.
PRESERVATION OF ANIMAL SUBSTANCES.
Tue following is an abstract of a communication to the French
Academy, by M. Blandet : —
The hyposulphite of soda and the chloride of zinc are both employed
for the preservation of dead bodies by injection. I placed blood in a
concentrated solution of each of these salts, and in about a fortnight,
after exposure to the air, the blood appeared bad in the hyposulphite,
though still liquid and black ; while the chloride of zinc gave a precipi-
tate, but without bad odor. I experimented with another’ salt, a
chloride like the salt of zinc, and alkaline the same as the salt of soda
—the chloride of barium. This salt maintains the blood liquid the
same as the salt of soda, and preserves it without odor the same as the
salt of zinc. The author thinks that by employing it for the injection
of the human subject, we may preserve the aspect of the living body,
the blood being rendered imputrescable by the chloride of barium —
Comptes Rendus.
A NEW STYPTIC.
A PHARMACIEN, at Rome, Signor Pagliare, has recently succeeded
in discovering a liquid possessing so extraordinary a power of coagulat-
ing blood, that if to a large basin containing this fluid one drop of the
styptic be added, complete solidification ensues, so that the basin may
be inverted without causing any blood to be lost. The practical
advantages of this styptic are consequently very great, inasmuch as,
CHEMICAL SCIENCE. QAT
by its timely application, the bleeding from large and dangerous
wounds may be immediately staunched. In addition to the other
valuable qualities of this liquid, it is totally devoid of poisonous agency,
and easily prepared as follows:— Take 8 ounces of gum benzoin, 1
pound of alum, and 10 pints of water. Boil all together for the space of
eight hours in an earthenware glazed vessel, frequently stirring the mass,
and adding water sufficient to make up the original quantity of that
lost by ebullition, taking care, however, to add the water so gradually
that boiling may not be suspended. ‘The liquid portion of the com-
pound is now to be strained off, and preserved in well-corked bottles.
It is limpid, like champagne as to color, possessing a slightly styptic
taste, and an agreeable odor.
ALKALIES IN PLANTS.
AT a recent meeting of the Botanical Society, London, Dr.
Daubeny detailed some experiments undertaken by him at the Oxford
Botanic Garden, with the view of determining whether the usual
_ quantity of potash and soda existing in barley might be made to vary
by causing the plant to grow in soil impregnated with more than the
ordinary quantity of one or the other of these alkalies. He found that
when the barley had grown in a soil which had been dressed with a
strong solution, either of carbonate of soda or of chloride of sodium, the
ashes of the plant contained about eight per cent. more soda than was
present when the plant had grown in a soil impregnated with carbon-
ate of potash, or left unimpregnated. ‘This difference may admit of
explanation by supposing one alkali capable of replacing the other
within the organism of the plant; but the author thinks it more
probable that it arose from the sap circulating through the plant at the
time when it was cut, containing in the one case more soda than it did
in the other. The saline contents of the fluid of the sap would of
course be confounded with those which had been actually assimilated
by the plant, and hence, from the variation in its composition, must
tend to modify the amount of the alkalies obtained from the ashes of
the plant in each instance, according to the nature of the material with
which the soil had been impregnated.
ON THE EFFICACY OF BURNT CLAY.
Dr. VOELCKER publishes a communication in the Chemical Gazette,
for April, on the causes of the agricultural efficacy of burnt clay, in
which he shows conclusively, that the change effected, and benefit
resulting, is entirely of a chemical nature.
Prof. Johnson, the well known Agricultural Chemist, had previously
expressed the opinion that the mechanical effects of the burning upon
clay, were insufficient to explain its efficacy, and first pointed out the
true solution of the phenomena in the chemical changes which the soil
undergoes.
Pure clay, silicate of alumina, is rarely found; such a soil could
22
248 _ ANNUAL OF SCIENTIFIC DISCOVERY.
never be improved by burning. The ordinary clay soils, however,
contain besides this chief ingredient, a considerable proportion of
sand, undecomposed fragments of felspar, mica, granite, and other
minerals, with more or less sand, carbonate of lime, magnesia, free or
uncombined alumina, oxide of iron, silicate of potash, traces of phos-
phorus, and sulphuric acid, and chlorine. Now of these substances,
the silicate of alumina, pure clay, does not of itself contribute at all
to the direct nurture of plants, as it is not found in the ashes of culti-
vated plants. We must look, therefore, for the direct fertilizers of
this soil, amongst the accessory or foreign ingredients of agricultural
clays. Of these, the lime, magnesia, sulphuric acid, silica, and chlo-
rine, which are essential to the growth of plants, are found im most
soils, or 1f deficient, can be supplied at a cheap rate. The chief value
of an agricultural clay, depends, therefore, on the proportion ef phos-
phoric acid, potash, and soda it contains. Potash is a most essential
element, and its chief source in ordinary soils is the clay. Clay is in
many cases, derived from felspar, a double silicate of alumina and
potash; and frequently contains some undecomposed fragments of
felspar and other minerals. Plants can only avail themselves of the
soluble potash, and not that which occurs in the form of felspar, which
must first be decomposed by long exposure to air and water; but, as
the soluble potash in the clay soil, sooner or later, will be exhausted
by the removal of the crops grown upon it, the soil becomes gradually
more and more sterile. Although by long exposure felspar may be
decomposed, yet it is now demonstrated that moderate calcination much
accelerates this action. In burning clay properly, a large amount of
potash is liberated by the action of the carbonate of lime present,
upon the double silicate of potash and alumina. This chemical reac-
tion, which occurs at a high temperature, results in the formation of
silicate of lime, and carbonate of potash. Those clays, then, which
are improved by burning, must be the ones that contain the foreign
ingredients named, and undecomposed felspar. ‘The pure pipe and
porcelain clays, would not be improved at all, by the process of soil
burning.
We can now understand, why burnt clays, especially improve the
root crops, such as turnips, carrots, swedes, mangolds, potatoes, &c.,
which require much potash as nutriment, the ashes of these plants,
containing nearly half their weight of this alkali. ;
ON THE ABSORPTION OF THE SOLUBLE HUMATES AND ULMATES
BY PLANTS. °
M. SovusErraNn demonstrated some time since the important fact, so
long denied by Liebig and his supporters, that alkaline ulmates and
humates are absorbed by vegetation. The experiments of Soubeiran
have been recently verified in the fullest extent by M. Malguti.
A plant of Lampsana, whose roots were immersed in a solution of
ammonia, continued to vegetate and prosper. The solution, which
was changed every day, was partially discolored. Oats passed very
CHEMICAL SCIENCE. 249
well through all the stages of vegetation in a soil deprived of organic
matters, and containing a little sulphate and phosphate of lime, and
which was watered from time to time with ulmate of ammonia. Those
who do not believe in the absorption of humus will accept with diffi-
culty results obtamed with a plant (Lampsana) which was found in
an abnormal state. They will add that there is nothing to prove that
oats accomplish their vegetation under the influence of ulmate of
ammonia, since in the soil it must find phosphate and sulphate of that
base. Indeed, if we put sulphate of lime, or powdered calcined bones
(or more properly artificial tribasic phosphate of lime,) in contact with
ulmate of ammonia, ulmate of lime is formed, and at the same time,
sulphate and phosphate of ammonia; and again, when we put sulphate
and phosphate of ammonia in contact with ulmate of lime, a double
decomposition ensues. In all cases there is a division, and four salts
are formed.
An experiment detailed by Maleuti was as follows: I half filled two
large funnels with gravel, and the other half with powdered brick,
- containing one per cent. of calcined bones, and as much chalk. I
sowed in these two artificial soils, moistened with distilled water, the
same quantity of cress seed. During germination I prepared by
means of turf, perfectly neutral ulmate of ammonia, which I divided
inte two equal lots, each about two quarts. One of these was set
aside, and the other was kept for watering the two soils. The seeds
having sprung up four days after they were sown, I began to water
them every day, ene with 100 cubic centimetres of distilled water, and
the other with the like quantity of ulmate of ammonia. After five
waterings, the difference between the two vegetations was very evi-
dent. That which had been watered with the ulmate was of a deep
green; the other which had been treated with water was of a light
green. After eighteen waterings, that is to say after the experiment
had lasted twenty-two days, the most luxuriant plant threatening to
fall, i cut it down. ‘The twocrops dried in the air-and under the same
circumstances weighed, that watered with water, 12,550 grs.; that
watered with the ulmate of ammonia, 15,150 grs. The soil impreg-
nated with the ulmate was then washed until the water passed out
colorless and limpid; dilute hydrochloric acid was then added and the
washing continued until the water became neutral. The treatment
with acid was succeeded by treatment with ammoniacal water, and
the two treatments were alternated, until it was quite certain that the
soil did not centain a trace of ulmic acid. All the waters colored by
ulmate of ammonia were combined with the rest of the lot employed
and the whole brought to a state of neutrality, and to the bulk of two
quarts. Two lots of liquid were thus produced; the first containing
a quart, one-half of the ulmate of ammonia originally produced, and
kept for comparison ; the second, a liquid containing all the ulmic acid
remaining in the soil; over and above what might have been extracted
by the plant. The ulmic acid in both was then precipitated in the
form of ulmate of lime, and separately washed, dried and weighed
under like circumstances. It was found that the ulmate of ammonia
250 ANNUAL OF SCIENTIFIC DISCOVERY.
used for watering the cress had lost 2,367 grammes of ulmic acid, as
it was given by the ulmate of lime dried in vacuo. It might be sup-
posed that the ulmic acid might have remained in the soil, under an
unknown form, which might escape the action of re-agents; but this
transformation could not be the result of the contact of the ulmic
acid either with the earthy matter, or with the external parts of the
roots. Now, this is a question of proving that this acid 1s absorbed,
and not of saying what becomes of it after the absorption.
This experiment and those of M. Soubeiran, seem to me to prove
the absorption of the soluble ulmates during vegetation, and at the
same time their utility. — Comptes Rendus, 1852.
RAIN, A SOURCE OF THE NITROGEN IN VEGETATION.
M. Barrat, from some analyses of rain-water collected at two
distinct spots in the grounds of the Observatory at Paris, during the
last five and six months of the past year, has shown us that the rain-
water is there charged with nitric acid, ammonia, chlorine, lime and
magnesia, to an extent scarcely to be credited, were it not the actual
result of experiment. Taking the average of these analyses, and
reducing the French weights to our own standard of 7,000 grains to
the pound, it will be seen, in these six months, the rain which fell on a
space of ground at the Observatory at Paris, equal in area to an
English acre, contained, as nearly as possible, 7.75 pounds of ammonia ;
36.50 pounds of nitric acid ; 5.56 pounds of chlorine ; 12.60 pounds of
lime ; 4.81 pounds of magnesia.
From July to December is usually the drier half of the year, as well
as that in which the less fuel is consumed, so that we may safely double
these quantities, in estimating the annual supply per acre of nitrogene-
ous compounds, gradually distributed over the country by the rain.
For the sake of illustration, we have calculated the amount of the
solid constituents of the rain falling on an area equal in extent to
Great Britain, and balancing the various causes likely to lessen or
to increase the quantity of these matters, which would so fall on this
island, we may venture to set one against the other, and apply the
above statement to our own country, as the basis of an estimate, which
singularly manifests the “power of littles,’ as well as the grand
scale on which even the minutest of natural phenomena proceed.
Thus, on the Parisian data, the weights of these fertilizing materials
annually supplied to the soil of this island by the rain, amount to
about 400,000 tons of ammonia; 1,850,000 tons of nitric acid ; 279,-
000 tons of chlorine ; 640,000 tons of lime; 244,000 tons of magnesia.
Making every allowance for errors of experiment, which, however,
would rather increase than diminish these quantities, excepting, it may
be, the amounts of the two last on the list, these researches of M.
Barrel prove to us that, the amount of fertilizing matter conveyed to
the soil by the rain, must exercise a constant and most important
influence on the vegetation of a country. These facts also tend to
throw still further doubt upon the peculiar efficiency of the salts of
’
CHEMICAL SCIENCE. 251
ammonia, and of the acid of the nitrates as manures; for we find in
rain-water a constant supply of these nitrogeneous matters, not applied
once, or at most twice, in the year, as is the case with the various
artificial manures, such as the nitrates of potash and of soda, Peruvian,
and those guanos which contain a large proportion of soluble ammo-
niacal salts, and the various ammoniacal composts, made and sold in this
country, the utility of which must chiefly depend on the concurrence
of several favorable conditions of the plants, the soil and the weather ;
for we find that the nitrogen required for the growth of the plant is
supplied in the fittest state for assimilation (viz., that of great dilution,)
and at all stages of its growth, by every shower that falls. The later
opinions entertained by Liebig, of the superior value of the alkaline
and earthy constituents of manures, 7. ¢., the potash, soda, lime,
magnesia, and the phosphates and sulphates of these bases, to that of
their nitrogeneous compounds, derive much weight from these experi-
ments of M. Barral, which show that a vast amount of nitrogeneous
fertilizing matter is distributed by the rain but none of the fixed
alkalies, or of the salts of phosphoric and other acids, equally important
to the due growth of vegetables, and which, unless naturally existing
in sufficient amount in the soil, must be supplied by the application of
manure, or the plant will either dwindle, or yield an imperfect produce,
owing to an insufficient supply to one portion of its requsite constit-
uents, however much it may be stimulated by an abundant applica-
tion of ammoniacal fertilizers. The prevailing use of these manures,
which are so highly charged with the salts of ammonia, readily account
for the increasing “ steeliness” which is observable in English wheat,
arising in great measure, as remarked by Liebig, froma superfluous and
unnecessary supply of the ammoniacal stimulants, and a deficiency in
the more important constituents of the cereals, viz—the earthy phos-
phates and alkaline salts, which are not brought to the growing corn
in the rain, like the nitrogeneous constituents. — London Critic.
ON THE SEPARATION OF BUTTER FROM CREAM BY CATALYSIS.
At the American Association, Albany, President Hitchcock read
the following paper, on the separation of butter from cream by
catalysis : —
It is well known that the separation of butter from cream, during
the winter months, by the ordinary process of churning, is often very
difficult, from some chemical changes in the proximate principles.
From my own small kitchen dairy, the complaint on this subject had
so often reached me, that I was led a few years since to inquire
whether there were not some remedy. My thoughts were turned to
that principle in chemistry, to which Berzelius gave the name of
catalysis. In observing the process of churning with the old-fashioned
cylindrical churn, I had noticed that along the handle, when the
cream had been subject to a more powerful agitation, butter would
show itself much earlier than in the body of the churn. Hence I
inferred that by acting on asmall quantity of the cream, the separation
22*
252 ANNUAL OF SCIENTIFIC DISCOVERY.
might be easily effected in that portion: and it seemed not improbable
that by seizing the exact moment when the separation was taking
place, and adding more cream, the process might be communicated to
that also in a catalytic manner; and if so, perhaps any quantity might
in like manner be made to yield its butter.
I made the experiment, and was successful. I put a small quantity
of cream in the churn at first, and, by a few moments strong agitation,
brought it to that state, familiar to a practised eye, when the butter is
separating. An assistant stood with the principal mass of the cream,
ready to pour it gradually into that where the butter was in a nascent
state, which I continued to agitate with even increased briskness as
more and more cream was added. The effect was magical; for ina
few minutes, I several times had the pleasure of seeing several quarts
of cream give up its butter. I found, however, that if the fresh cream
were poured in too fast, it would stop the process; and that it would
not answer to let the agitation cease for an instant.
I have delayed for two or three years to state these facts publicly,
because I had hoped to make additional experiments on the subject ;
but more important matters have prevented. I cannot, therefore, say
of how much practical value my statements may be. I tried experi-
ments enough to convince me, that although the requisite manipula-
tions would require some skill, it would not be greater than many
other processes common upon farms. The common churn, however,
is not adapted to the experiment. I think one might be invented that
would meet the case; but I must leave the whole matter to any others
who may feel interest enough in it to carry forward what I have only
suggested.
It was suggested by those who took charge of the butter thus
eliminated, that it seemed more difficult to separate and the whey
completely, than when obtained by the ordinary process. ‘To this
point, therefore, the attention of the experimenter should be turned.
FORMATION OF ARTIFICIAL CELLULAR TISSUE.
NorwitHsTANDING chemistry has made us acquainted with the
composition of organic bodies, and the microscope has pointed out
their structure, we have yet much to learn with regard to the particu-
Jar operations by which definite forms are assumed by the elementary
tissues. Many considerations concur to establish the probability of
the proposition, that the fluid state is necessarily the first in which the
elements of a tissue must exist previously to their undergoing a
morphic determination, precipitation, histomorphosis, or whatever
analogous term may be assumed to denominate the simplest change
which may be supposed to occur in the passage of a perfectly amor-
phous fluid into a tissue of definite shape. We owe to Ascherson a
-knowledge of the interesting fact, that the contact of two homogeneous
fluids, oil and albumen, results invariably in the immediate production
of elementary forms. Still more recently, M. Melsens, by a series of
observations and -experiments, has established the possibility of one of
CHEMICAL SCIENCE. 258
these fluids undergoing distinct and very remarkable histomorphosis.
In regard to this interesting phenomena, M. Melsens says : — “ We
know that many feeble acids do not precipitate albumen from its
solution ; my experiments have reference especially to the trihydrated
phosphoric and acetic acids; this ceases to be the case when albumen
is present with those salts which have no apparent chemical action on
it; the reactions change for acetic acid as well as the phosphoric, with
their equivalents of base, and some acid phosphates as well, precipitate
it more or less completely. The following is the process by which I
prepare the salified solution of albumen :— The white of an egg
is mixed with its volume of water and filtered; this constitutes the
normal solution of albumen, with a specific gravity of 1,020. The
filtered liquor is saturated with salts, which are added in excess, after
which the fluid is filtered again, to separate the excess of salts; the
fluid resulting from this second filtration, may be denominated
the normal saturated albumen. The normal albumen saturated with
chloride of sodium has a specific gravity of about 1,200.”
My experiments have been made with almost all the salts which are
without an apparent action on albumen, as well as with those which
begin to precipitate it, but whose precipitations are soluble either in
an excess of albumen or of the salt. I will not pronounce on the
nature of the precipitates obtained ; but it will appear evident that we
must in the generality of cases admit, that the albumen is precipitated
in consequence of a particular physical disposition of the liquid; that
if at times the precipitation does not occur immediately, in dilute
liquor for example, agitation may cause a troubled condition of the
fluid, as occurs in precipitation, crystallization, solidification of water,
of sulphate of soda, &c.. Tribasic phosphoric acid precipitates normal
albumen saturated with salts; certain salts, among which are borax,
phosphate of soda, acetates of soda, and potassa, form an exception to
this rule ; however, if the fluid be agitated with a glass rod, a troubled
condition is slowly produced by the mechanical action. The solutions
of albumen with other salts are all precipitated by phosphoric acid ;
these precipitates are soluble in an excess of the acid. ‘The presence
of the salts, therefore, permits us to make with albumen and the tri-
hydrated phosphoric acid an experiment which requires with normal
albumen, the monohydrated phosphoric acid which precipitates it, and
the trihydrated, which dissolves the precipitate formed.
“Tf,” says M. Melsens, “after the preceding experiments I am
induced to believe that the particular physical constitution of the
liquids plays some part in the precipitation of albumen, those which
' follow cannot leave the least doubt as to the action of agitation. Some
very dilute liquids remain limpid until beaten with a glass rod, when
they become troubled, and immediately parcels of fibres may be
seen to form under the influence of agitation; under the microscope
these appear as very distinctly organized forms, which by juxta-
position and felting together constitute actual membranes. We
have thus a phenomena conformable to the production of mineral
precipitates by the influence of agitation. In another experiment
254 ANNUAL OF SCIENTIFIC DISCOVERY.
a current of air was passed through a solution of normal salified
albumen, sufficiently dilute not to allow of the froth passing out of
the vessel. This froth was seen- to be transformed into a solid
body insoluble in ammonia, potassa, water, or dilute acids. To
obviate two objections which might be started to this experiment,
air saturated with the vapor of water, and hydrogen purified by
caustic potassa and saturated with vapor, were successively employed.
Lastly, to avoid all sources of error, a solution of albumen diluted
with water was agitated in vacuo by converting the vessel into a
sort of water hammer, after expelling the air by heat and an air-
pump, the orifice being subsequently hermetically sealed. The
solution, perfectly limpid at first, became troubled after a few agita-
tions, and a membrane was rapidly formed.”
The solid bodies thus formed from a limpid solution of albumen
by the simple effect of agitation, have been subjected to microsco-
pic examination of M. Gluge, from whose report we make the
following extracts:—‘“The albumen of the white of an egg, soli-
dified by mechanical actions resembles false membranes, and even
serous. It is presented to our view under the form of membranes
covered with granulations from one-half to one millimetre, in diame-
ter, white semi-transparent, about one-fourth or one-half millimetre
thick, and sufficiently elastic. With a magnifying power of three
hundred we can distinguish an amorphous substance, finely punctuated,
in which are found fibres, sometimes isolated, sometimes united in
bundles like the fibres of cellular tissue, more often easily isolated and
elastic. More rarely there may be seen large and transparent fibres,
analogous to those which are met with in fibrine. In the middle of
these fibrous bundles may be observed granulations composed of little
globules of 1-400 to 1-800 of a millimetre in size, and enclosing some
bubbles of air. ‘These globules are sometimes very regularly grouped
and then form rounded masses.”
Dr. Lyons who has carefully examined a specimen of albuminous
membrane prepared by M. Melsens, with a high magnifying power,
says: —‘ The granular base constituted a very considerable portion
of the entire specimen, but did not appear to be uniformly disposed
throughout it, as in some portions it formed nearly the entire, while in
others it was almost altogether replaced by fibres. The solidifying
force would thus appear not to have acted with uniformity. To deter-
mine what modifications of it produced granular matter — what fibres
— what again caused the formation of the little spherical bodies — are
uestions, perhaps, of too delicate a nature to admit of ready solution.
ould we arrive even at an approximate explanation, a great step
would be achieved in the history of the obscure process of histogenesis.
The most interesting of all the structures observable in this prepara-
tion are the spherical bodies. They are nearly uniform in size,
grouped quite close to each other, and present nearly uniform
characters. Under all conditions of light, both as to mtensity and
obliquety, they presented a sort of nucleus, which in all was of a long
elliptical shape, although the bodies themselves appeared as nearly as
CHEMICAL SCIENCE. 255
possible spherical. This nucleus was in length equal to about one-
half the diameter of the sphere, and in breadth about one-eighth.
What was the nature of these bodies? They were certainly not
either spheres of oil, or bubbles of air; there was not the slightest
probability of the former substance being present; air bubbles they
also could not be; the specimen had been at rest in spirit for a very
considerable time, while as more positive evidence of their cell structure
I would adduce the peculiar nucleus, which in all was oblong, and did
not disappear under any conditions of light. May we then regard
them as nucleolated nuclei, or small nucleated cells ? These dis-
coveries have filled me with the highest hopes of seeing before long
some large advances made in this hitherto almost unworked fleld of
investigation.”
ON SPONTANEOUS HUMAN COMBUSTION.
MM. Biscuorr and Lirsic, employed as experts in the recent
celebrated case of the Countess of Gorlitz, not only declared that
her case presented an example of post mortem burning, which proved
to be true, but took the occasion absolutely to deny the trustworthi-
ness of any of the cases of spontaneous human combustion on revord.
This position M. Devergie combats, founding his argument upor the
consideration of a case which occurred to himself, and of the vari-
ous accounts of other examples that have been recor ded by trustworthy
persons. Although the term spontaneous is not strictly a correct one,
masmuch as there has always been an immediate cause of the combus-
tion, he retains it for want of a better; and he considers the leading
characteristic of these cases to be the absence of harmony between the
mass of the parts burned and the feebleness of the agent of combus-
tion. He enumerates the following peculiarities, as exemplified by
most of the facts on record: 1. The extent and depth of the burns,
as compared with the feeble proportion of combustible matter employed
in their production. 2. Indulgence in spirituous liquors by the vic-
tims. 3. The far greater frequency of the occurrence in women, and
especially in old women. 4. The presence of an accidental determin-
ing cause. 5. So complete is the combustion in some cases that
nothing but the ashes remain, and these are always of the same fatty
soot. 6. The combustion while acting on a mass of flesh and fat has
any. ‘spared highly inflammable bodies in the vicinity. 7. The
flame when seen has always been described as of a blueish color and
as inextinguishable. M. Devergie points out how these circumstances
differ from those observed in the Countess’s case and in death from
ordinary combustion. When this extends from the clothes to the
person, very large superficial burns are produced, which from their
very size prove “fatal ; but there is no instance of bodies becoming
completely carbonized or reduced to the condition in which they are-
found in these cases. It is true, that when the amount of combustible
body exists in due proportion to the body to be burned we may see
such effects produced, but the absence of this relation is the prime
256 ANNUAL OF SCIENTIFIC DISCOVERY.
characteristic of these cases. A mere lamp or hot cinder suffices ;
while in the experiments made upon the Countess’s body 125 pounds
of wood had to be used. The other capital point is, the isolation of
the combustion amidst combustible bodies, the most inflammable substan-
ces remaining uninjured. In the Countess’s case the floor and chairs,
even at a distance, were burned. In M. Devergie’s case, complete
combustion of the body had taken place in a little wooden room five
or six feet broad by eight or nine feet long, and yet two muslin
curtains at the window were uninjured. In all the cases, too, abuse of
alcohol is mention; and although Bischoff laughs at this as a mere
invention of the persons of the vicinity, for the purpose of pointing a
moral, it is too particularly specified in all the cases to admit of doubt,
and it is to this abuse of alcohol that M. Devergie is disposed to at-
tribute the production of the phenomenon. ‘The quantity excreted
by the urine and,sweat is probably not in due relation to that imbibed ;
and a vital modification is impressed upon the tissues, by reason of
which they become endowed with a greater combustibility, either
mechanically, or by the transformation of the absorbed alcohol com-
bined with the tissues into a new substance. — Annales d’ Hygiene.
CHEMICAL TESTIMONY IN CASES OF POISONING.
M. OrFiLa, in a recent capital case for poisoning in France, took
occasion to represent to the court the reason why experts could not
reply to the question so often put to them, as to whether a suflicient
quantity of poison to cause death had been administered, and the
danger, in reference to the suppression of crime, the insisting upon
such a question gave rise to. ‘The chemist may only be able to detect
the thousandth, or the twenty-thousandth part that has been adminis-
tered, when the poison has been evacuated or excreted, and the dis-
charges have not been preserved. If all the poison has been thus
expelled he may not be able to detect even a trace, and yet, although
in the one case, what he has detected has been insufficient to cause
death, and in the other he has found none at all, so that the jury may pro-
nounce that no poisoning has occurred, yet has the person died of such
poisoning. To ascertain the whole amount of poison that remains in the
body, the entire frame would have to be submitted to analysis, which
is clearly impracticable; while calculations of the quantity existing
in the whole body from that which has been obtained from a part,
would give rise to the greatest errors, inasmuch as the poison is not
equally distributed over the whole frame, some portions of this absorb-
ing and retaining much more of it than others. Different processes
also employed by the same hand afford very different quantities, as
does the same process performed by chemists of different degrees of
expertness. The French law, too, does not require any decision on
this point, as it punishes the attempt to poison by any substance that
may cause death — this applying not to the proportion employed, but
to the substance used.
CHEMICAL SCIENCE. 25T
ON THE ELIMINATION OF CERTAIN POISONS.
Tue following is an abstract of a paper recently read before the
French Academy by M. Orfila :—
When a poison has been absorbed and carried into the tissues of a
living being, does it remain indefinitely within these tissues? or is it
expelled from them? In the latter case, in how long a time does the
animal economy effect the expulsion? Finally, in what way is the
poison conveyed out ? ‘
These three questions include all that relates to the diminution of
poisonous substances. The experiments relative to the study requires
a very long time. in eighteen months I was able to experiment on
only four poisonous substances— bichloride of mercury, acetate of
lead, sulphate of copper, and nitrate of silver. These experiments
have taught me that when the above poisonous substances are admin-
istered to animals, that mercury disappears in general from the organs
in eight or ten days. In only one case I found it to take eighteen
days. Lead and copper are found in the intestinal parietes and in the
bones eight months after they have ceased to be introduced into the
stomach. Silver, whose presence in the liver may in some cases be
demonstrated after six months, is not found in any organ of other
animals, seven months after the administration of nitrate of silver. In
the course of these researches I have seen that lead, copper, and
mercury pass into the urime; but whilst the two former are carried
away by the renal secretion, only two days after the administration of
the copper or lead compound, the mercury continues to be carried off
by this excretion eight days after the introduction of the mercurial
preparation. I have never been able to detect silver in the urine of
animals which have taken nitrate of silver.
I beg for a moment to call attention to the applications which may
be made by the medical jurist of a knowledge of the elimination of
poisonous substances. When I began this work, I had especially the
view of facilitating the solution of some problems which might impede
or stop the course of justice, if the practitioner did not possess the
most precise knowledge on this portion of toxicological physiology. A
few examples will suflice to show the benefit to be derived from the
study in medical jurisprudence.
A. An individual who had been subjected to a mercurial treatment
by corrosive sublimate, died four months after the cessation of the
treatment, being poisoned by a mercurial preparation. The analysis,
which is performed by the processes hitherto known, detects mercury in
the organs. The detence is able, in consequence of these antecedents,
to raise strong doubts, as to the origin of the metal. According to my
experiments we can ascertain that the mercury does not proceed from
the mercurial medicaments taken four months previous to death ; for
after the administration of corrosive sublimate, the mercury does not
remain in the animal tissues more that eighteen days.
B. Should a man survive a poisoning by corrosive sublimate for
fifteen days, it is very possible that the chemists consulted in the case
258 ANNUAL OF SCIENTIFIC DISCOVERY.
would find no mercury in the organs. They would, however, commit
a great error should they conclude that there had been no attempt to
poison. This error is impossible when we are acquainted with the
above-named facts.
C. A workman in a white lead factory died two months after
having ceased to manipulate saturnine preparations. In his organs the
chemist finds lead. Had this lead been given criminally, or does it
proceed simply from the compounds absorbed by the workman in the
factory? To give a satisfactory reply to this question, the operator
must carefully study the development and the symptoms of the malady
which preceded the death, and combine these facts with those furnish-
ed by the study of elimination.
It is rational to make a comparison of the process hitherto proposed
for the detection of lead, copper, and mercury contained in organic
compounds, before studying their elimination. Three processes are
employed in the search for lead and copper, they really differ from
each other only in the agents employed for the carbonization of the
animal matter. These agents are nitric acid, nitric acid mixed with one-
fifth of chlorate of potassa, and sulphuric acid. From my experiments I
conclude that the carbonisation by nitric acid is superior to the others ;
that the mixture of nitric acid and chlorate of potassa does not give good
results, and, finally, that carbonisation by sulphuric acid is far inferior
to the others. When we seek for mercury, the best-of known pro-
cesses consist in carbonising the organic matter with sulphuric acid.
M. Lanaux proposes the destruction of this matter by a current of chlo-
rine. Comparative experiments have shown me that this last process
is more sensible than the former.— Comptes Rendus.
ON THE ACTION OF OZONE ON MIASMATA. BY M. SCHONBEIN.
M. ScHonBern’s additional researches have still further developed
the analogy of this substance to chlorine, and leave no doubt of the
injurious effects it may exert on the respiratory organs when in excess.
Mice soon perish in an atmosphere containing 1-6,000. The quantity
which prevails in the atmosphere is very variable, being proportionate
to the amount of electricity, and therefore at its maximum in winter,
and its minimum in summer. It is, however, highly probable that,
when existing only in minute quantities, it exerts a purifying effect
on the atmosphere by destroying various deleterious miasmata. There
are a great number of inorganic gaseous bodies, which when diffused
in scarcely appreciable quantities, yet render the airirrespirable. An
incessant source of miasmata exists in the variety of gaseous com-
pounds which are incessantly liberated by the decomposition of the
innumerable masses of organic beings which’ perish on the surface of
our globe. Although the composition of most of these is unknown, it
is supposed that their accumulation would render the air unfit for
respiration. Nature has, however, provided the means of destroying
such deleterious compounds as fast as they are generated, for M.
Schonbein regards ozone, which is so constantly generated under
CHEMICAL SCIENCE. 259
electrical influence, and is so powerful an agent of oxidation even at
ordinary temperature, as specially destined to that end. His experi-
ments prove that air containing 1-6,000 of ozone can disinfect 540
times its volume of air produced from highly putrid meat: or that air
containing 1-3,240,000 of ozone can disinfect an equal volume of air so
corrupted. Such experiments show how little appreciable by weight
miasmata may be, which are yet sensible to the smell, and how small is
the proportion of ozone necessary for the destruction of all the mias-
mata produced by putrifaction of organic matter and diffused in the
atmosphere. We may admit that the electrical discharges which occur
incessantly in different parts of the atmosphere and determine there
the formation of ozone, purify the air by ridding it of oxidizable
miasmata, at the same time that these are destroyed by ozone, the
organic miasmata cause its own disappearance, and prevent dangerous
accumulation of it. The opinion that storms purify the air may not
be without foundation, as a large quantity of ozone is then produced.
In the authors experiments, he has always found a large proportion of
ozone in the vicinity of the stormy clouds of Jura; and the air ozon-
ized by phosphorus by experiment, gives forth a similar smell to that
perceived amidst storms in mountainous regions. It is very propable
that in certain localities the balance between the ozone and the mias-
mata does not prevail and disease may be the consequence. As a
general rule, however, numerous experiments have shown that the
air contains free ozone, so that no free oxidisable miasmata can there
exist. M. Schonbein recommends that the atmosphere should be
tested for ozone, in localities and at periods where fevers and other
forms of disease prevail, so that the results of accumulated observations
may be obtained. — Arch. des Sciences.
Dr. Moffatt, of England, in a paper read before the Meteorological So-
ciety, shows by a series of very elaborate tables, thatan apparent connex-
ion is discoverable between the first appearance, increase, decrease and
disappearance of atmospheric ozone with the decrease and increase of the
readings of the barometer and thermometer and the state of the weather
generally. Also that prevalent diseases form groups corresponding with
certain meteorological conditions. In the formation of these tables Dr.
Moffatt has paid strict attention to all the lesser fluctuations of the barom-
eter and thermometer, being convinced that there exists a great necessity
for so doing, from the slightest variations in the reading of the barometer
being followed by a change in the direction of the wind, and the
appearance and increase, or decrease and disappearance, of ozone.
Ozone Dr. Moffatt considers to be intimately connected with falls of
rain, hail, snow, and sleet, and dynamic electricity, but that it is not
necessary for any of these to occur for ozone to be produced ; for if
the barometer reading increases, and a current of air sets in from the
northern points of the compass after or with any of these, ozone will
disappear, but if the barometer reading decreases and the wind comes
from southward it appears to increase in proportion to the decrease of
the reading of the barometer and the force of the current. The fall
of ie aie ee ozone he thinks is possibly attributable
260 ANNUAL OF SCIENTIFIC DISCOVERY.
to the wind becoming north during the continuation of an ozone
period or at its termination. According to the observations contained
in this paper, the potato and other diseases occur at the same time and
appear to be produced by the same causes. As ozone is invariably
attendant upon these causes, Dr. Moffatt was induced to try its effects
upon vegetable life by means of actual experiments. In August, 1851,
two plants were placed under a glass case, so resting upon slips of
wood as to permit the air freely to pass beneath and an ozone test-
paper was fixed in the crown of each glass. A watch-glass containing
a piece of phosphorus was placed upon the soil in the pot which con-
tained a longiflora. In the course of ten hours the test-paper became
tinged and the interior of the glass was bedewed with moisture. At
noon on the following day, or eighteen hours from the first action of the
etc dew drops were perceived to hang from the points of the
eaves; the test-paper in the other glass did not show the slightest
change. In two days the leaves began to assume a brownish tinge,
and became darker, until nine days after the commencement of the
experiment the branches began to droop, and on the tenth the whole
plant was completely withered ; the ozone paper was not deeply tinged,
less so than was frequently found to be the case in twenty-four hours
in common atmospheric air. The other plant continued healthy.
The experiment was repeated upon two geraniums with the same
result ; that which was exposed to the influence of ozone, although
the stronger of the two plants, perished in seven days, whilst the other
remained possessed of its vitality and continued to blossom. The
principal conclusions arrived at by Dr. Moftatt from the observations
contained in his paper are,—that the greatest number of diseases
occur with decreasing readings of the barometer and thermometer,
and with appearance and increase of ozone, — that certain diseases
would appear peculiar to certain directions of the wind, — that epi-
lepsy and sudden deaths occur most frequently at the commencement
of an ozone period, — that the potato disease accompanies the diseases
in the animal kingdom, — and that atmospheric ozone is injurious not
only to animal but to vegetable life.
ON A PECULIAR PROPERTY OF ETHER, AND OF SOME ESSENTIAL
OILS.
Tu1s property, which has just been made known by Prof. Schon-
bein, so well known by his discovery of ozone, is similar to that
possessed by phosphorus, when put in contact under certain circum-
stances with pure oxygen, or of atmospheric air, of developing that
powerful oxidising agent, which has received the name of ozone. If,
says M. Schonbein, a little ether is poured into a bottle of pure
oxygen, or of atmospheric air, and exposed to the diffused hght,
agitating it from time to time, the ether, after an interval of four
months will have acquired new properties. Although it does not act
on litmus paper, it decolors the solution of indigo, converts pure
phosphorus into phosphoric acid, eliminates the iodine from iodide of
CHEMICAL SCIENCE. 261
potassium, changes sulphate of protoxide of iron, into bibasic sul-
phates and acids, transforms yellow cyanide of potassium into red
cyanide, and converts sulphuret of lead into sulphate, etc. The
essential oil of turpentine, and that of citron produce the same effects,
if treated in the same way. Accordingly to M. Schonbein this new
property is due to the presence of oxygen in an exalted chemical
condition. — Jour. de Chemie.
ANALYSIS OF PERSPIRATION.
THE analysis of perspiration has hitherto given contradictory
results to the several analysts who have examined it; it is still
doubtful. M. Favre has, however, presented to the French Academy
an important memoir upon this subject, in which he establishes some
facts and exhibits results new in the history of secretions. He has
isolated from perspiration two immediate principles, whose existence
in that liquid was never suspected ; one is wrea, a composition found
in several other humors, and an azotic acid discovered by M. Favre,
and which he calls sudrique acid. Among the elements whose exist-
ence remained an object of doubt to physiologists was lactic acid. M.
Favre was so skilful and he had so large a quantity of perspiration to
operate on (no less than 80 pounds!) he succeeded in obtaining six
grammes of lactate of zinc. M. Favre ascertained that the chlorure
of sodium, by its large proportion, must be considered as the essential
mineral element of the liquid secreted by the sudoriparian glands.
The almost absolute absence of other inorganic materials (such as
phosphates and sulphates) in perspiration throws new light upon the
secreting functions, and proves this singular fact: the saline sub-
stances dissolved in the blood are eliminated one to the exclusion of
another, by the different glandular apparatus of the system. For
example, in analysing two equal proportions of urine and of perspira-
tion, 28 pounds of each coming from the same subject, the first gave
21 grammes of alkaline sulphates and the second only one decigramme.
ON A METHOD OF GETTING RID OF SAL-AMMONIAC IN ANALYSIS.
WE copy the following communication by Dr. J. Lawrence Smith,
from Silliman’s Journal, Jan., 1853. There is nothing in mineral
analysis more embarrassing than the accumulation of sal-ammoniac
towards the end of an analysis, especially where potash or soda are to be
estimated. The only method now adopted to get rid of this ammoniacal
salt, is to volatilize it by heat, which if the quantity be considerable, is
attended by no little annoyance, and a certain loss of more or less of
the fixed alkalies which may be present. I have recently discovered a
mode of overcoming that difficulty, and much experience has proved
its value, the method is simply to add nitric acid to the solution
containing the sal-ammoniac and alkalies, and heat it gently overa
lamp or sandbath in a glass flask or porcelain capsule. The nitric
acid may be added either before the liquid is eoncentrated, or after
262 ANNUAL OF SCIENTIFIC DISCOVERY.
concentration ; a most quiet decomposition ensues, and the liquid
readily evaporates to dryness leaving nothing but the fixed alkalies if
they be present. Iam in the habit of using a little more than three
grammes of pure nitric acid of ordinary strength to every gramme of
sal-ammoniac supposed to be present in the liquid. The exact nature
of the decomposition which ensues cannot now be stated, but there is
doubtless formed, besides other things — chlorine, hyponitric acid and
nitrogen.
-GEOLOGY.
THE FUTURE OF GEOLOGY.
REGARDING the geological scale of formations as an artificial scheme,
founded on local considerations, although an instrument and scale of
great value when used judiciously, the questions have to be answered,
whether the terms of its graduation be required, and whether, as
we have them, they are complete. See those broad stripes of demar-
cation printed on every geological diagram between the terms palezo-
zoic and secondary, secondary and tertiary. These lines are popularly
understood to mark boundaries between a complete cessation of one
great system of types of species, and the commencement of an entirely
new series of creatures, animal and vegetable. They really mark pro-
digious gaps in our knowledge of the sequence of formations and the
procession of life. One of these supposed impassible boundaries, that
between “tertiary” and “ cretaceous,” threatens rapidly to give way,
and to vanish in due time, as speedily as artificial social distinctions in
society. In France, Belgium, Germany, and England, there are
symptoms of an intergrowth between the long separated “ chalk” and
“eocene.” Strata are coming to light which rudely insist on finding
elbow-room among our neatly-packed systems and formations, Janus-
like fossils are turning up with two sets of features. Our preconceived
notions of what ought to be are sadly disconcerted. An already exten-
sive terminology is threatened with an inundation of new terms, too
necessary to be evaded. If we are not mistaken, there are little clouds
rising on the geological horizon that indicate revolutions elsewhere in
the series. ‘That narrow black line drawn on geological diagrams
between the words “ Trias” and “ Permian,” has more meaning Mm it
than its dimensions indicate. The line between “ Eocene” and “ Cre-
taceous,” has swollen out, broken up, and is enlarging fast into inter-
mediate sections. But all its changes and increase will be as nothing
compared with those that must take place by and by in its representa-
tive lower down. If we interpret aright, the signs indicated by extinct
organisms preserved to us in paleozoic rocks, and the comparison of
them with others in the lowest mesozoic or secondary strata, there is a
gap in our knowledge of the succession of formations, the extent of
23*
264 ANNUAL OF SCIENTIFIC DISCOVERY.
¢
which it is almost disheartening to think upon. Although the paleo-
zoic fauna and flora, are assuredly portions of the same unique system
of organized nature, with the assemblages of creatures of after-date in
time, they exhibit differences in detail so great that, on superficial
consideration, we might almost be inclined to regard them as belonging
to some other world than our own. ‘These differences are such as at
present set all our calculations respecting the climatal conditions of the
primeval (paleozoic) epochs at defiance. But that these oldest of
creations were linked with ‘those that came after, and those amidst
which we live, is evident in the number of géneric types common to
all, and expressed yet more strongly in the presence of straggling
representatives of types of life, characteristically paleeozoic, among
the very lowermost strata of the secondary period. All analogy
teaches us, however, that there is a graduation of one geological
period into another; and every day’s advance in research goes to
confirm this belief. The facts to which we have alluded indicate
evidences of such a graduation of paleozoic into secondary. But the
stages of that graduation, the intermediate formations, have not yet
been discovered. Calculating from the amount of blank in the series
of organized types, there must have been a vast interval of time inter-
vening between the Permian and Triasic epochs, during which, doubt-
less, sediments were being ‘deposited in seas, sea-beds upheaved,
animals and plants flourishing, generations and generations, nay more,
creations and creations, appearing, succeeding and disappearing; and
yet of all these universal accumulations and organized assemblages,
there has not been as yet a fragment found.
“They are but ill-discoverers,” wrote Lord Bacon, “ that think
there is no land when they can see nothing but sea.” Columbus had
fewer signs to warrant his belief in a new continent than we have to
indicate an unexplored and as yet unseen geological world. Such
signs cannot be dissipated by any appeal to the series of strata already
investigated. If we jot out on the map of the world those portions
which have been sufliciently examined, at once paleontologically and
geologically, the space covered by our ink makes but a poor show. Our
hope lies in ‘the rapidly advancing progress of comparative geology,
especially through the aid and sure operations of organized surveys.
All over Europe such surveys are in progress, or about to commence,
sanctioned as they ought to be by governments of every shade of
opinion.» Some three or four years ago, it was publicly declared that
the geology of England was completed; a plausible announcement,
since almost every corner has been subjected to the tramp and ham-
mers of geologists. Yet, if we are not greatly mistaken, even the
geology of England has much still to be done. Itis ably sketched out ;
portions of it have been developed with skill and ability ; but by far
the greater part will yield a luxuriant harvest of discovery to those
able and willing to enter upon the task. The nearer we come to
geologizing by square miles or leagues, the more interesting will be
the results of our labors, and the economical value of geological
researches depends mainly upon such works. — Westminster Review,
1852.
GEOLOGY. 265
ON THE CAUSES OF THE CHANGE OF CLIMATE AT DIFFERENT
GEOLOGICAL PERIODS.
Tue following is an abstract of the recent address of Mr. Hopkins,
President of the Geological Society of England The author first con-
siders the influence on the earth’s superficial temperature of a central
heat, supposed to be the remains of a former and very much greater
heat which has been gradually diminishing during some indefinite
period of time. The effect on the superficial temperature due to this
cause may have been formerly of any amount, but is now reduced to
within one-twentieth of a degree of Fahrenheit, of that ultimate limit
to which it would be reduced in an indefinite period of time, suppos-
ing the external conditions under which the earth is now placed, such
as the amount of radiation from the sun and stars, and the state of the
atmosphere, to remain as at present. Poisson has calculated that it
would require 100,000 millions of years to reduce the present temper-
ature by about one-fortieth of a degree of Fahrenheit. It is probable,
therefore, that many millions of years must have elapsed since the
central heat can have elevated the earth’s superficial temperature by
a single degree. The author also explained that any very sensible
increase of superficial temperature from this cause must have been
attended with an exceedingly rapid rate of increase of the internal
temperature in descending below the earth’s surface. It is only, how-
ever, to the more remote geological periods that we can refer for any
very sensible change in the climatal conditions of our globe due to this
cause. Such changes, also, must manifestly be continually from a
higher to a lower temperature ; and, therefore, we must appeal to some
other cause to account for such oscillations of temperature as those of
the glacial period. Poisson suggested that the present internal tem-
perature of our globe might not be due to its primitive heat, but to the
fact of the solar system having passed through some region of stellar
space of which the temperature, owing to stellar radiation, is much
greater than that in which it is now placed. Without professing to
say how far this cause may have influenced the climatal conditions of
the earth at former remote periods, the author shows that, reasoning
from all we know respecting the relative positions of the stars and the
probable motion of the solar system, this cause cannot have produced
a change so great as that which must have taken place during the gla-
cial epoch, at a time so recent as we have reason to believe that epoch
to have been. The author next proceeds to examine the effects of
changes in the disposition of land and sea, and of the consequent
changes in the direction of ocean currents. The map of isothermal
lines, recently published by MM. Humboldt and Dove, enables us to
estimate the influence of the existing configuration of land and sea,
and that of currents superinduced thereby, and thus we are enabled
to estimate approximately the effects of like causes in different hypo-
thetical cases. The isothermal lines have thus been constructed by
the author for the following cases: 1. When the progress of the gulf
stream into the North Sea is supposed to be intercepted. by land con-
266 ANNUAL OF SCIENTIFIC DISCOVERY.
necting the northern point of Scotland with Iceland, and that island
with the continent of Greenland. 2. The next case assumes the ele-
vation of the land now constituting western Europe to a sufficient
height to produce such glaciers as those the effects of which we recog-
nize in that region as having been produced during the glacial period.
3. The northern portion of the Atlantic is supposed to be converted
into dry land by the elevation of its bed. 4. In the last case, the
absence of the gulf stream with its ‘nAtSeE upon the western coast
of Europe is assumed, together with the submergence beneath the sea
of a large portion of northern and western Europe. In this part of
his memoir the author restricts himself chiefly to the consideration of
these cases with the view of ascertaining how the cold of the glacial
epoch can be best accounted for, together with its consequent glaciers
of sufficient magnitude to pr oduce the phenomena now so universally
attributed to them. Having constructed the isothermal lines in any
of the above cases for January and July, he deduces the mean annual
temperature at any proposed place. He can then calculate the height
at that place of an imaginary surface in the atmosphere, the tempera-
ture of which, at every point, is equal to 32° Fahr. This imaginary
surface must of course meet the surface of the earth along a line for
every point of which the mean annual temperature is that just men-
tioned; and any line upon this imaginar ry surface (as that in which it
intersects the surface of a mountain, ) is called a line of 32° Fahr.
In estimating the height of this line, the author adopts the results
given by Humboldt and others, as to the decrease of temperature for
an assigned increase of height in ascending from the earth’s surface.
The next step is, to ascertain the position of the snow-line in refer-
ence to the line of 32°. In tropical regions the former line is below
the latter; in higher latitudes it is generally above it. Whenever the
difference between the summer and winter temperature is small, the
snow line has a comparatively low position with respect to the line of
32°. By means of these and other inferences, drawn from existing
cases, we are able to estimate approximately the relative positions of
these two lines in our hypothetical cases, and thus knowing by calcu-
lation the height of the line of 32° at any proposed place, we can
estimate that of the snow line at the same place. Now, it appears by
observation that nearly all the well known glaciers, of sufficient mag-
nitude to be considered of the first order, descend about 4,000 or
5,000 feet below the snow line, and that the smaller glaciers descend
only to smaller distances below that line. We are thus enabled in any
hypothetical case to form an approximative estimate of the distance
which a glacier would probably descend beneath its snow line; or,
knowing the height of that line by the means above stated, we can
thus estimate the height above the sea level to which the lower extrem-
ity of the glacier would probably descend. The author then proceeds
to apply these principles to cases 2, 3, and 4 above mentioned, and to
determine the conditions under which glaciers, sufficiently large to
produce certain observed glacial phenomena, would exist in Western
Europe. In ease 2 it would be necessary that that region should be
GEOLOGY. 267
elevated into a mountainous range of not less than 10,000 feet in
height; a conclusion inadmissible, on account of the entire absence of
all independent geological evidence in support of it. The hypothesis
of case 3, Mr. Hopkins rejects for a similar reason. Case 4 is then
discussed at length. It is shown that glaciers of the required magni-
tude would in that case exist in the region of Western Europe, if in
addition to the absence of the gulfstream we suppose the existence of
a cold current from the north of a moderately refrigerating influence.
This latter current, however, might not be essential. The entire
diversion of the present gulf stream into some other channel, which is
required by this view of the subject, would be the necessary conse-
quence of that submersion of the North American continent, of which
we have such conclusive evidences during the glacial period; for in
such case the current which sets into the Gulf of Mexico would mani-
festly continue in its north-westerly direction along the present valley
of the Mississippi and the range of the Rocky Mountains to discharge
itself into the Atlantic Ocean. This would correspond to the glacial
period on this side the Atlantic; but along the new course of the
gulf stream there would be a much warmer climate than at present,
—and that such a climate has there existed ata recent geological
epoch seems to be abundantly proved by vegetable remains which
have been found between Hudson’s Bay and the Rocky Mountains,
precisely in the line which the warmer current would take.
A subsidence of the American Continent, of less than 2,000 feet
would render the ocean continuous from the Apalachian chain, on the
east, to the Rocky Mountains on the west, and there seems reason to
believe that the subsidence may possibly have attained to a consider-
ably greater amount. Now, it is manifest that the gulf stream is
reflected in a north-easterly direction across the Atlantic, by the con-
tinent of North America, which arrests the north-westerly course by
which the current reaches the Gulf of Mexico. But when that con-
tinent was submerged, as above supposed, the current would necessa-
rily continue its north-westerly course, and probably along the foot of
the Rocky Mountains directly into the Arctic Sea. This is the man-
ner in which it is conceived the gulf stream was diverted from the
shores of Western Europe. This diversion of the current is not to
be regarded as a mere hypothesis adopted to account for any particu-
lar fact, but as a necessary consequence of that submergence of the
North American continent.
Again, if this enormous current discharged itself into the Arctic
Sea, it would seem extremely improbable that it should not give rise
to some great determinate counter-current out of that sea. Now it
appears highly probable that a considerable tract of land must have
existed at the period of which we are speaking in the present region
of north-eastern America, and Greenland. If this were the case, the
only practicable outlet for a great current from the Arctic Sea would
be across the submerged portion of northern Europe, or along the
present North Sea, between Greenland and Norway ; for the passage
through Behring’s Straits, even with a considerable subsidence of the
268 ANNUAL OF SCIENTIFIC DISCOVERY.
land on either side, would be neither sufficiently wide nor deep to
form a considerable outlet. Under such circumstances, it would
scarcely seem more necessary that the gulf stream should hold its
original north-westerly course over the submerged continent of Amer-
ica, than that it should complete its circuit by passing through the
Arctic Sea, and returning to the Atlantic across the submerged land
of Europe, as it now completes a more circumscribed circuit by being
constrained to pass along the northern portion of the Atlantic itself.
The effect of this diversion of the gulf stream from its present
course, would not be less remarkable in elevating the temperature of
the northern shores of America and Asia, than in reducing that of
western Europe. It can be shown that the mean annual temperature
of Iceland is increased 18° or 20° Fahr., and the January tempera-
ture 34°, by the influence of this important current. There can be
no reasonable doubt, therefore, of its raising the temperature of the
north-western coast of America, from the Mackenzie river to Behr-
ing’s Straits, by an amount at least equal to that by which it now ele-
vates the temperature of Iceland. Further, it is highly probable that
the principal course of the current in the Arctic Sea would not be
far from the coasts of northern Asia, the temperature of which would
thus be affected in a manner similar to that of the coast of America
eastward of Behring’s Straits. The temperature of winter immedi-
ately east of the Ural Mountains, would also be considerably moder-
ated, as already stated, by the extension of the European sea towards
their western flanks. The climate of the low lands of northern Asia
would thus differ from the present climate of that region, as much as
the existing climate of the western coast of Norway differs from that
which would desolate that region in the absence of the gulf stream.
According to this view of the subject, the former existence in
northern Asia of the immense numbers of large Mammalia indicated
by the abundance of their fossil remains, no longer presents the
slightest difficulty ; and the theory receives a still further confirmation
from an observation made by Sir John Richardson in his “Arctic
Searching Expedition,” just published. The author observes, “ The
existence of these numerous testimonials of an ancient fauna is sug-
gestive of many curious speculations, and geologists seem hitherto to
have failed in explaining the circumstances under which accumula-
tions so vast could occur in such high latitudes. The difficulty is
increased when we consider that these bones have not been detected
to the east of the Rocky Mountains in high latitudes.” This increased
difficulty, however, is at once removed by the theory now proposed,
for the region in which these remains are not found, must either have
been covered with the waters of the ocean to the foot of the Rocky
Mountains at the period when these Mammalia occupied the region to
the westward, or if land existed on the north-east of the present
American continent, it was probably too cold to be inhabited by them.
Their disappearance from the country bounding the Arctic Sea, from
the Rocky Mountains to the Ural, would be the consequence of the
withdrawal of the gulf stream from the more eastern, and of the Euro-
\
GEOLOGY. 269
pean ocean from the more westerly portion of that region. Fossil
plants also, belonging to a comparatively warm climate, have been
found east of the Rocky Mountains, on the coast of the North Sea;
and extensive beds of lignite exist along the eastern flank of those
mountains. So far as these phenomena may be of Pleistocene origin,
they may be ai once accounted for by this theory. °
Before the depression of the North American continent was sufli-
cient to admit the gulf stream to flow freely to the Arctic Ocean, the
northern part of that continent would be converted into an Arctic sea,
and this would correspond to the first part of the glacial drift period
in that region. On the gradual elevation of the land after its greatest
depression the north-western course of the gulf stream would be again
arrested, and the northern portion of the American continent would
be again converted into an Arctic sea. The temperature of the region
of the eastern portion of North America would probably not be much
affected by the alteration in the course of the gulf stream, nor would
it probably be very different from that which obtains at present along
its eastern coasts. It may also be added, that the continued course of
the gulf stream into the Arctic Ocean would very probably generate
a cold counter-current from the North Sea across the submerged por-
tion of Europe, such as has been above alluded to. The author is
anxious to direct the attention of geologists to this view of the subject,
in the hope that it may be tested by such further observations as may
bear more immediately upon it. Jt appears to him to satisfy better
than any other theory the present known conditions of the great
problem which the glacial epoch presents to us.
DRIFT OF THE NORTHERN AND WESTERN STATES.
M. Dezsor, who has devoted much time to the examination of the
drift, or quarternary deposits of the Northern States, recently pre-
sented an abstract of his observations to the Geological Society of
France. M. Desor classifies the superficial and non-indurated rocks of
the waters of the St. Lawrence, and the Upper Mississippi, as follows ;
1st, Alluvium; 2d, marine drift; 3d, fresh-water drift; 4th, drift
proper, or diluvium. M. Desor proceeds as follows:
Alluvium is here, as everywhere, the least developed member ; com-
prising the deltas of rivers, sand banks, shallows, and dunes. The
marine drift passed at first among the American geologists, under the
name of Tertiary, and comprises deposites of clay, sand and gravel,
containing marine shells.
I propose to call them by the name of Laurentian, because these
deposites are largely developed in the littoral valleys of the Atlantic ;
and principally in the great valley of the River “ St. Laurent,” (Law-
rence,) and its affluents. It is thus I distinguished them from the
similar deposites, that contain any fresh water fossils. Along the
side of the Laurentian beds, and almost in contact with them, but at
a little higher level, is found a series of deposites, externally very
much like them, but without marine shells. This formation has no
270 ANNUAL OF SCIENTIFIC DISCOVERY.
analogue in the continent of Europe ; and it constitutes in America,
the most marked feature in the geology of the quarternary period.
Coming from the sea coast, we meet with it first, on the shores of
Lake Erie, where it forms slopes, and terraces, composed at the lower
parts of blue clay, and hard pan, surmounted by loam and gravel. A
moment’s observation convinces any one, that these ridges, terraces
and slopes, are not the result of violent action; but that they were
deposited in quiet waters. As the fossils are rare, as they differ in
many respects from the Laurentian, doubts naturally arise as to their
origin, and their age. Are they marine, or are they lacustrine ? The
same doubts rest upon the loamy deposites, that form the surface
material over the vast space, occupied by the States of Wisconsin,
Illinois, and Iowa, and the shores of the Mississippi Some geologists
have called them by the name of loess, from their resemblance to the
‘loess ” of the Rhine.
But these doubts have recently been removed, by the discovery by
Mr. Whittlesey, in the blue marly clay of Lake Erie, at Cleveland, of
fresh water and terrestrial shells, (Heleciance and Planorbis,) at 25 to
50 feet above the level of the water. The same gentleman has col-
lected numerous specimens of buried timber and leaves, from the same
deposites, in which they are very abundant. M. Lesquereux has
recognised among them, the leaves of the spruce (Abies nigra,) the
common cranberry (Vaccinium) which now grows in that country,
and many species of Cyperaceec.
Mr. Whittlesey soon atter discovered fresh water shells in the loess-
like deposites, on the shores of the Mississippi, including many species
of Planorbis, one of Cyclas, and a Physa, at 60 to 180 feet above the
level of the river. The same shells have been recently observed near
St. Louis, (250 to 300 feet above the stream,) and at New Harmony
upon the Wabash. Very lately, Dr. Rigsby has found on the banks
of the river Notawassaga, that empties into the Bay of St. George of
Lake Huron, in Canada, a bed of fresh water shells, (Unios) covered
with deposites of much thickness, but he has not given us their eleva-
tion above the lake. Mr. Murray, of the Canadian Geological Society,
has explored the northern shore of Lake Erie, and finds that the
superficial deposites are composed of the same materials as those upon
the southern shore opposite ; and although he has not discovered there
any shells, he does not doubt but the marly clays of Canada, and the
sandy and loamy beds resting upon them, were deposited by the same
waters, as those on the American side. If we examine the map, and
the position of these deposites, and remember the elevation at which
the fossils are found, at different points, we must infer, that there
existed at the quartenary epoch, two immense sheets of fresh water in
North America; one occupied the basin of the Upper Mississippi, the
other, that of the Canadian Lakes, but both formed one vast sea of
fresh water ; from which, however, we must exclude the basin of Lake
Ontario, which was marine, or salt water. The comparison of the
levels, where the shells were found, at Cleveland, and on the Mis-
sissippi, shows that these great basins were not then isolated, but com-
GEOLOGY. 271
municated with each other by many valleys, such as the Wabash and
the Illinois; so that the basin of the lakes, which is now separated
from that of the Mississippi, at that epoch discharged its waters into
the basin of this great river. Mr. Hubbard, of the Michigan Survey,
says, there exists a depression between Lakes Huron and Michigan,
through the valley of Saginaw Bay, where there was a connection of
the waters.
The existence of these fresh water deposites being now demon-
strated, it becomes necessary to give them a specific name, to distin-
guish them from the marine, or Laurentian formation. The geological
corps of the United States, in Michigan, propose to call them Algonquin,
from a powerful nation of Indians, who heretofore inhabited the region
- of the lakes, and the heads of the Mississippi. It has not been defi-
nitely adopted, because there are doubts whether the drift proper that
occupies the central and elevated parts of Ohio, Wisconsin and Mich-
igan, is not of the same age. It was at first admitted, that the lacus-
trine deposites of Lake Erie, (on which Cleveland is situated,) although
at a lower level, was nevertheless more recent than the “ drift,’ and
perhaps, contemporary with the “ Laurentian.” More recent researches
have not confirmed this view; and many geologists, at the head of
whom is Mr. Whittlesey, are now inclined to think, that the lacustrine
or the “ Algonquin ” beds, are members of the “ drift proper,” modi-
fied by local action and circumstances, and that they pass insensibly
into each other. If this is really so, it will follow, not only that the
Laurentian is more recent than the lacustrine formation ; but what is
more important, the whole drift beds of the West must be regarded as
a fresh water deposit. The difficulty in this case arises, in conceiving
of banking, or highlands sufficiently elevated, to hold the waters of
such a basin, for the drift deposites attain the height of 1,600 feet
above tide, between Lake Superior and Lake Michigan, without
including the erratic blocks, or “ boulders ” that are found still higher.
Unfortunately, there have no shells been found in the elevated coarse
drift. The only fossils that these beds have furnished, are parts of
trees, leaves, &c. It is to be hoped that shells may be discovered ;
but until then, the identity of the drift with the Algonquin, or lacus-
trine formation, must remain in suspense. I should remark, that there
is found on the surface of the lacustrine, as well as on the Laurentian,
and on the proper “drift,” boulders of all dimensions. The mere
statement of this fact, proves that they were not transported by the
same agent that has scratched, striated and polished, the rocks in
place. If this agent was a glacier, we can no longer attribute to it the
transportation of boulders, for in that case, their transportation should be
contemporary with the polishing of the rocks; but there is between them
the whole period, during which the lacustrine beds were being depos-
ited. There are also, on the surface of the lacustrine of Lake Erie, (and
other lakes) ridges and elongated hillocks, like the “ osars ” of Sweden,
showing like them, traces of stratification, which proves that they were
all formed under water. Neither the lacustrine or the Laurentian
contain the bones of mammiferous animals, such as the Mastodon, Ele-
24
212 ANNUAL OF SCIENTIFIC DISCOVERY.
phant, &c.; it being now established, that at the Big-bone lick, and in
uumerous other places at the west, heretofore referred to the drift
period, are more recent deposites, such as “ valley drift ” and Alluvium.
M. Verneuil remarked, that he had never met with the fresh water
drift, far from the great lakes and rivers of North America; and that
it appeared to him, to be attributable to an ancient extension of their
waters.
GEOLOGICAL DISCOVERIES IN SOUTH AFRICA.
Amone African discoverers little known to the general public, is
Mr. Bain, surveyor of roads in Cape Colony. This gentleman, in
the course of his duties, has made some remarkable observations and
discoveries in the geological structure of South Africa. He _ has
shown that the oldest rocks form a broken coast fringe around the
southern extremity of Africa, and are surmounted by sand stones,
which from the fossils they contain, are the equivalents of the Silu-
rian rocks. These primeval strata, occupying the highest grounds,
of which Table mountain is an example, and dipping inland from
all sides, are overlaid by carboniferous strata. Above all these
ancient strata, says Mr. Murchison, in his address before the
Geographical Society, and occupying, therefore, a great central
trough or basin, strata occur which are remarkable from being
charged with terrestrial and fresh-water remains only ; and it is ina
portion of this great accumulation that Mr. Bain disinterred fossil
bones of most peculiar quadrupeds. One of the types of these,
which Professor Owen named Dicynodon, from its bidental upper
jaw, is a representative, during a remote secondary period, of the
lacustrine associates of the hippopotami of the present lakes and
waters. The contemplation of these discoveries, has therefore led
me to point out to you how wide.is the field of thought which the
labors of one hard-working geologist have given rise to, and to
express, on my part, how truly we ought to recognize the merits of
the pioneer among the rocks, who enables us, however inadequately,
to speculate upon the entirely new and grand geographical phe-
nomenon, that such as South Africa is now, such have been her
main features during countless past ages, anterior to the creation of
the human race. For the old rocks which form her outer fringe,
unquestionably circled round an interior marshy or lacustrme country
in which the Dicynodon flourished at a time when not a single animal
was similar to any living thing which now inhabits the surface of our
globe. The present central and meridian zone of waters, whether
lakes, rivers, or marshes, extending from Lake Tchad to Lake
Negami, with hippopotami on their banks, are, therefore, but the great
modern, residual, geographical phenomena of those of a mesozoic
age. ‘The differences, however, between the geological past of Africa
and her present state are enormous. Since that primeval time the
lands have been much elevated above the sea-level—eruptive rocks
piercing in parts through them; deep rents and defiles have been
GEOLOGY. 273
suddenly formed in the subtending ridges, through which some rivers
escape outwards, whilst others flowing inwards are lost in the interior
sands and lakes; and with those great ancient changes entirely new
races have been created.
Travellers, continues Mr. Murchison, will eventually .ascertain
whether the basin-shaped structure, which is here announced as
having been the great feature of the most ancient, as it is of the
actual geography of Southern Africa, (7. e., from primeval times to
the present day,) does, or does not extend into Northern Africa.
Looking at that much broader portion of the Continent, we have
some reason to surmise, that the higher mountains also form, in a
general sense, its flanks only. Thus, wherever the sources of the
Nile may be ultimately fixed and defined, we are now pretty well
assured that they lie in lofty mountains at no great distance from its
east coast. In the absence of adequate data, we are not yet entitled
to speculate too confidently on the true sources of the White Nile ;
but judging from the observations of the missionaries, and the position
of the snow-capped mountains called Kilmanjaro and Kenin, (only
distant from the eastern sea about 300 miles,) it may be said that
there is no exploration in Africa, to which greater value would be
attached than an ascent of them from the east coast, possibly from
near Mombas. The adventurous travellers, who shall first lay down
the true position of these equatorial snowy mountains, and shall
satisfy us that they not only throw off the waters of the White Nile
to the north, but some to the east,—and will further answer the query,
whether they may not also shed off other streams to a great lacus-
trine and sandy interior of this continent, will justly be considered
among the greatest benefactors of this age to geographical science.
The great east and west range of the Atlas, which in a similar
general sense forms the northern frontier of Africa, is, indeed,
already known to be composed of primeval strata, and eruptive rocks,
like those which encircle the Cape Colony on the south, and is
equally fissured by transverse rents. As to the hills which fringe the
west coast, and through the apertures of which the Niger and the
Gambia escape, we have yet to learn if they are representatives of
similar ancient rocks, and thus complete the analogy of Northern
with Southern Africa. But I venture to throw out the general sug-
gestion of an original basin-like arrangement of all Africa, through
the existence of a grand encircling girdle of the older rocks, which,
though exhibited at certain distances from her present shores, is still
external as regards her vast interior.
With no region of the old world have we been, till very lately, so
ill-acquainted as Africa. But now the light is dawning quickly
upon us from all sides; and in the generation which follows, I have
no doubt that many of the links in the chain of inductive reasoning,
as to the history of the successively lost races of that part of the
globe, will be made known, from the earliest recognizable zones of
‘animal life, through the secondary and tertiary periods of geologists.
Passing thence to the creation of mankind, and to the subsequent
(274 ANNUAL OF SCIENTIFIC DISCOVERY.
accumulation of the great delta of the Nile, we have recently been
put in the way of learning, what has been the amount of the wear
and tear of upland or granatic rocks, and what the additions to the
great alluvial plain of Lower Egypt, since man inhabited that most
holy region, and erected in it some of his earliest monuments. But
how long will it be before we shall be able to calculate backwards by
our finite measure of time, to those remote periods, in which some of
the greatest physical features of this continent were impressed upon
it,—when the lofty mountains from which the Nile flows, were
elevated, and when the centre of Africa was a great lacustrine jungle, '
inhabited by the Dicynodon, and other lost races of animals ?
WESTERN HIMALAYA AND TIBET.
In the years 1847-8, an expedition was fitted out by the East India
Company, for the exploration of the western Himalaya and Tibet.
A journal of these travels and geological researches, has recently
been published in England, by Dr. Thomson, one of the party, and
a son of the celebrated chemist of that name. From this book,
which contains much new and interesting scientific information, we
derive the following extract. Many of the places examined and
described, have never before been visited by any European traveller.
The old, and still popular notion of Tibet, is that of a great mountain
table land, or a series of table lands, at the back of the Himalaya, by
which mighty chain its southern boundary is made, a barrier broken
through by the Indus at one extremity, and the Brahmaputra at the
other, while its northern limit is similarly walled in by the Kouenlun
chain; the country thus supposed to exist is entirely imaginary.
There is, indeed, no such table land. Nor is there, indeed any such
great continuous chain as the Himalaya itself. The line of snowy
peaks running parallel to the plains of India are not so many sum-
mits of one Alpine chain, but are separated from each other by deep
ravines, through which flow large and rapid rivers. Between the
Indus and the plains of north-west India is a rugged and mountainous
track 150 miles broad. Kashmir is the only plain of any extent
among these mountain ranges. The mountains between the Indus
‘and the. plains may be referred to two great groups, which may be
respectively termed the Cis-Sutle} and Trans-Sutlej Himalayas.
Tibet is the region among and of these mountains between their outer
ramifications and the great chain of Kouenlun beyond the Indus.
This chain separates Tibet from Yarkand and Kohoten. Over this
stupendous barrier there are said to be only four passes, all crossing
regions of eternal snows, and two traversing enormous glaciers. The
Karakoram Pass is one of these, and is 18,200 feet above the level of
the sea. ‘The visit to this extraordinary locality is thus described by
Dr. Thomson :—
“ On the 19th of August, I started to visit the Karakoram pass, the
limit of my journey to the northward. The country round my halt-
ing-place was open, except to the north, where a stream descended
through a narrow valley from a range of hills, the highest part of
GEOLOGY. Zt
which was apparently about 3,000 feet above me. All the rivers had
formed for themselves depressions in the platform of gravel which
was spread over the plain. I ascended this valley for about six miles:
its width varied from 200 yards to about half a mile, gradually
widening as I ascended. The slope was throughout gentle. An
accumulation of alluvium frequently formed broad and gently-sloping
banks, which were cut into cliffs by the river. Now and then large
tracts covered with glacial boulders were passed over; and several
small streams were crossed, descending from the northern mountains
through narrow ravines. About eight miles from my starting-point
the road left the bank of the stream, and began to ascend obliquely
and gradually on the sides of the hills. The course of the valley
beyond where I left it continued unaltered, sloping gently up toa
large snow-bed, which covered the side of a long sloping ‘ridge four
or five miles off. After a mile, I turned suddenly to the right, and,
ascending very steeply over fragments of rock for four or five
hundred yards, I found myself on the top of the Karakoram pass—
a rounded ridge connecting two hills which rose somewhat abruptly
to the height of perhaps 1,000 feet above me. The height of the pass
was 18,200 feet, the boiling point of water being 180.8°, and the
temperature of the air about 50°. ‘Towards the north, much to my
disappointment, there was no distant view. On that side the descent
was steep for about 500 yards, beyond which distance a small streamlet
occupied the middle of a very gently sloping valley, which curved
gradually to the left, and disappeared behind a stony ridge at the
distance of half a mile. The hills opposite to me were very abrupt,
and rose a little higher than the pass; they were quite without snow,
nor was there any on the pass itself, though large patches lay on the
shoulder of the hill to the right. To the south, on the opposite side
of the valley which I had ascended, the mountains, which were
sufficiently high to exclude entirely all view of the lofty snowy moun-
tain seen the day before, were round-topped and covered with snow.
Vegetation was entirely wanting on the top of the pass, but the loose
shingle with which it was covered, was unfavorable to the growth of
plants, otherwise, no doubt, lichens at least would have been seen.
- Large ravens were circling about overhead, apparently quite unaffected
by the rarity of the atmosphere, as they seemed to fly with just as
much ease as at the level of the sea.
“The great extent of the modern alluvial deposit concealed, in a
great measure the ancient rocks. At my encampment a ridge of very
hard limestone, dipping at a high angle, skirted the stream. Further
up the valley a hard slate occurred, and in another place a dark blue
slate, containing much iron pyrites, and crumbling rapidly when
exposed to the atmosphere. Fragments of this rock were scattered
over the plain in all states of decay. On the crest of the pass the
rock in situ was lime-stone, showing obscure traces of fossils, but too
indistinct to be determined; the shingle, which was scattered over the
ridge, was chiefly a brittle black clay slate.”
Conceive a vast tract of country, the lowest valley of which is as
24*
276 ANNUAL OF SCIENTIFIC DISCOVERY.
high as the summit of the Faulhorn in Switzerland, and many of
whose habitable spots are nearly as lofty as the summit of Mont
Blanc, composed of prodigous mountain chains from 17,000 to 19,000
feet above the sea, with occasional peaks exceeding 22,000 feet,
winding and interlacing, intersected by deep and narrow valleys—
ravines on an enormous scale—with too arid a climate to support
forests, or any coniferous tree except alpine junipers—covered by a
sky cloudy in winter, clear and bright in summer, and a powerful sun
heating the bare black rocks, whilst the air is rent by winds of fearful
violence—and we can forma picture of Western Tibet, the region
explored by Dr. Thomson.
Among the discoveries of our traveller is that of the locality
whence the borax imported from Tibet is procured. The plain of
Pugha is the result of the drying up or drainage of an ancient lake.
It is covered to the depth of several feet with white salt, principally
borax. By digging below the superficial layer, the borax is obtained
in a tolerably pure state.
CRYSTALLINE FORM OF THE GLOBE.
M. pe HAvsLas in a recent publication, after discussing the direc-
tion of mountains, and of dykes and of cleavages among rocks, deduces
some general principles with regard to their direction, and then
explains his hypothesis that the surface of the globe presents approx-
imately the faces of the great octahedron. In an octahedron there
are three axial planes intersecting one another at right angles; and
the positions of the circles on the earth’s surface which he lays down
as the limits of these planes (or their intersection with the surface) are
as follows. The jist circle is that of Himalaya and Chimborazo,
passing from Cape Finisterre to the Himalaya, Borneo, eastern chain
of New Holland, (leaving on its sides a parallel line in Mallacca, Java
and Sumatra,) to New Zealand, thence to South America near Chim-
borazo, the chain of Carracas, the Azores to Cape Finisterre. The
second, passes along the South American coast and the north and
south ranges of the Andes, the mountains of Mexico, the Rocky
mountains, Behrings’ Straits, the eastern Siberian chains, going to the
south of Lake Baikel, the Altai, Himalaya, the mountains of Bombay
in Hindostan, a point in the northeast of Madagascar (where the
summits are 12,000 feet high,) the mountains of Nieuwedfeld, 10,000
feet high, Cape Caffres, to Brazil, the rapids of La Plata, Paraguay,
Parana, the elevated basin of Titicaca, the Andes, Illimani and the
defile of Maranova. ‘The third circle cuts the two preceding at
right angles, and passes by the Alps, the Islands of Corsica and Sar-
dina, along the basin of the Mediterranean, the mountains of Fezzen,
Lake Tchad, the Caffre mountains of Nieuwedfeld, the Southern
Ocean near Kerguelen’s Land, the eastern or Blue mountains of
New Holland, straits of Behring, Spitsbergen, Scandinavia, Jutland, ete.
These three great circles point out the limits of the faces of the
great hypothetical octahedron. Each of the faces may be divided
GEOLOGY. QTT
into eight others by means of line of accidents of minor importance,
so as to make in all forty-eight irregular triangles, a form of the dia-
mond. Atthe intersections, M. de Hauslabobserves that there are nodes
of dykes, and along the lines or near them, all the mountains of the
globe occur. The author gives an extended illustration of his subject
and afterwards considers the particular history of the configuration of
the earth’s surface in accordance with his hypothesis.
M. Boue who adopts similar views adds as a note, that we should
remember in this connection that the metals crystallize either in the
tesserel or rhombohedral system, and that native iron, the most com-
mon constituent of meteorities, is octahedral in its crystals.
ON THE STABILITY OF THE EARTH’S AXIS OF ROTATION.
Tue following is a communication read before the Royal Society,
by Henry Hennessy, Feb., 1852.
The author refers to a communication to the Geological Society, by
Sir John Lubbuck, in which he appeals in support of the possibility
of a change in the earth’s axis, to the influence of two disturbing
causes, which appear to have almost entirely escaped the notice of
Laplace and Poisson, in their investigations on the stability of the
earth’s axis of rotation;—1. The neeessary displacement of the
earth’s interior strata, arising from chemical and physical actions
during the process of solidification. 2. The friction of the resisting
medium in which the earth is supposed to move. With reference to
the first of these disturbing causes, the author states, that he has been
led to conclusions which may assist in clearing up the question. From
an inquiry into the process of the earth’s solidification, which appears
to him most in accordance with mechanical and physical laws, he has
deduced results respecting the earth’s structure which throws some
light on the changes which may take place in the relation which is
capable of being expressed by means of a function which depends on
the arrangement of the earth’s interior strata. He then states that he
has found strong confirmation of his peculiar views respecting the
theory of the earth’s figure in the experiments of Bischof of Bonn on
the contraction of granite and other rocks or passing from the fluid
to the solid crystalline state. From the results of these experiments,
he has been led to assign a new form to the function expressing the
relation of the earths’ principal moments of inertia. Referring to his
paper for the mathematical processes by which he has arrived at this
result, he states that from the theory he has ventured to adopt, it
follows, that as solidification advances, the strata of equal pressure in
the fluid spheroidal nucleus of the earth, acquires increased elliptic-
ity, and each stratum of equal density, successively added to the
inner surface of the solid crust, is more oblate than the solid strata
previously formed.
From these considerations alone, he remarks, it is evident that the
difference between the greatest and least moment of inertia of the
earth, would progressively increase during the process of solidification.
278 ANNUAL OF SCIENTIFIC DISCOVERY.
It follows, therefore, that if the earth’s axis of rotation were at any
time stable, it would continue so forever. But, from the laws of fluid
equilibrium, the axis must have been stable from the epoch of the
first formation of the earth’s crust; consequently, it continued undis-
turbed, as the thickness of the crust increased during the several
geological formations. Thus it appears that the displacement of the
earth’s interior strata, instead of having a tendency to change its axis
of rotation, tends to increase the stability of that axis. With reference
to inequalities arising from the friction of a resisting medium at the
earth’s surface, the author observes that this could not exist, if, as in
the manner here shown, the axis of rotation coincided from the origin
with the axis of the figure. In conclusion, he remarks, that if we
could assume for the planets a similarity of physical constitution to
that of the earth, the theorem as to the greatest and least moments of
inertia of the earth would be applicable to all the planets; and thus
we should be as well assured of the stability of our system, with
respect to the motion of rotation of its several members, as we are
already respecting their motion of translation.
In reference to a third cause of disturbance in the place of the
earth’s axis of rotation, namely, the effects of local elevations and
depressions at the earth’s surface, the author says: — If with Hum-
boldt, we regard the numbers expressing the mean heights of the
several continents, as indicators of the plutonic forces by which they
have been upheaved, we shall readily see that these forces are of an
inferior order, to those affecting the general forms and structure of
the earth. If the second class of forces acted, so as not to influence
in any way the stability of the earth’s axis of rotation, the former
class might, under certain conditions, produce a sensible change in the
position of the axis. But when the tendency of the second class ef forces
is to increase the stability of the earth’s axis, it would not be easy to
show the possibility of such conditions, as to render the operation of
the other forces, not only effective in counteracting that tendency,
but also producing a sensible change in the place of the axis of rota-
tion. — Proc. Royal Society.
SHOWERS OF SAND IN CHINA.
Tue following account of sand showers in China is given by Dr.
D. J. Macgowan, of Ningpo :—
The Phenomenon of falling sand is occasionally observed through a
reat extent, if not the entire portion, of the vast Plain ef China. It
1s of such frequent occurrence that the Chinese regard it with no
more surprise than they do the flitting meteor. Probably no year
passes without several of these showers, though frequently so minute
as to escape general observation. Perhaps as often as once in three
years they are very heavy, but it is seldom that sand falls in such a
large quantity as during the last shower. The phenomenon was wit-
nessed three times during the present year, within a period of five
weeks; the last. and greatest commenced on the 26th of March, and
GEOLOGY. 279
continued four days without intermission, varying however, in inten-
sity. The wind blew from the north, northeast, and northwest, fre-
quently shifting between these points, and varying in strength from a ~
perfect calm to a brisk breeze. The altitude of the barometer was
from 29.40 to 30.00 (rather lower than before and after the shower.)
The thermometer ranged from 36° to 81° Fahr. No rain had fallen
for six weeks, and the hygrometric state of the atmosphere was very
high. Neither cloud, fog, nor mist obscured the heavens, yet the sun
and moon were scarcely visible, the orb of day appeared as if viewed
through a smoked glass, the whole sky presenting a uniform rusty
hue. At times this sameness was disturbed, exhibiting between the
spectator and the sun the appearance of a water-spout, owing to the
gyratory motions of the impalpable mineral. The sand penetrated
the most secluded apartments; furniture wiped in the morning would
be so covered with it in the afternoon, that one could write on it
lecibly. In the streets it was annoying, entering the eyes, nostrils and
mouth, and grating under the teeth. My ophthalmic patients gener-
ally suffered a relapse, and an unusual number of new cases soon
after presented. Were such heavy sand storms of frequent occur-
rence, disease of the visual organs would prevail to a destructive
extent. The effect was the same when observed from the Ningpo
Tower, and from the summit of the low mountains in the neighborhood
of the city. :
The specimens I gathered fell on a newspaper placed on the roof
of a house. The whole quantity which fell was about ten grains to
the square foot. It should be remarked, however, that during the
four days the dust seemed suspended in the air for several hours at a
time, scarcely an appreciable quantity falling during these intervals.
The Chinese call it yellow sand; it is an impalpable powder of that
color.
It was observed at sea, at Hangchau, and at Shanghai. Whence
did it originate ? The opinion of the Chinese on this subject may, I
think, be regarded as correct. They assert that it comes from Peking.
We know that the sand of Sahara is sometimes elevated by whirlwinds
into the upper current of the air, and deposited in the Atlantic twelve
hundred miles, sometimes directly opposite to the trade winds. Over
against the vast alluvial Plain of Eastern Asia is the ocean of sand—
the Desert of Gobi or Shamoh, extending from near the sea westerly
2,300 miles, and 3 to 400 broad—including the conterminous sandy
districts. Like its counterpart in Africa, it is subject to whirlwinds
which raise its fine dust like the waves of the sea, and doubtless at
times waft it into the upper currents of air, and transport it to distant
regions. I have been informed by intelligent natives of Kiangsi and
Honan, that the phenomenon occurs in those provinces also. Assum-
ing the Mongolian steppes to be the source whence these showers
descend, the amount of sand which is annually conveyed hither must
be prodigious to cover such an extensive area. Regarded in a mete-
orological and in a geological point of view, these showers possess no
small interest.
280 ANNUAL OF SCIENTIFIC DISCOVERY.
GNEISS AND SURPENTINE FORMATIONS.
Lronarp and Bronn’s Jahrbuch state that they have observed
gneiss associated with conglomerate, and great veins of gneiss travers-
ing gneiss. These facts have been verified by the discovery of similar
phenomena in other countries, and gneiss 1s now divided into the
following formations : — 1, Primary Gneiss, that associated with certain
granites, and forming the fundamental or oldest formation of the
crust of the earth; 2, Transition Gineiss, that which rests upon transi-
tion rocks, as greywacke, clay slate, and old red sandstone, and even
alternates with them; 3, Secondary Gneiss, this formation rests upon
lias, and is well seen in Switzerland. We have no intimation that
gneiss has been met with in the tertiary group.
Many years ago, Jameson noticed the gradual transitions from trap
to serpentine, both in Germany and Scotland. Very lately the cele-
brated Rose, of Berlin, has illustrated this view in a very interesting
manner.
ON THE EVOLUTION OF GAS IN WALLSEND COLLIERY, ENG.
Pror. Puts at the British Association remarked that the
Wallsend Colliery was one of the numerous coal mines in Yorkshire
which have been rendered remarkable for the frequent explosion of
the inflammable and noxious gas with which they are filled, and the
loss of life which has in so many cases been the consequence. In
every coal-pit there are two shafts, one of which serves to admit the
pure air, whilst the foul gases are made to escape by the other. The
ascent of the foul gases is frequently facilitated by creating a draft by
fires placed near the bottom of one of the shafts. The coal is arranged
in perpendicular layers, between which the gases exist in a highly
compressed state. In order to detach these layers with the least pos-
sible danger, it is usual to cut through them endways, by which means
the gases are allowed to make their escape at once froma considerable
portion of the coal. A district of this colliery, covering about fifty
acres, was effectually walled up, in consequence of the immense dis-
charge of gas that was continually taking place. A pipe was led
from this enclosed portion up through the mine and for forty feet
above the surface, and from this pipe there has been a constant dis-
charge of gas for the last eighteen years. This gas has been inflamed,
and in the roughest and most stormy weather it has burned without
intermission ; and were it as rich in naphtha as ordinary carburreted
hydrogen, it would illuminate the country for miles round. Two
water-pressure gauges were fixed to the brick walls, one at the surface
of the earth, and the other at the bottom of the mine, and the results
were that, whilst the pressure in the mine was only 9-10ths of an inch
on an average, that at the top of the pit was upwards of four inches.
From observation in these minés, it 1s seen that discharges of fire-
damp, governed by atmospheric pressure, take place before being indi-
cated by the barometer, and that, as an indicator that instrument can-
GCOLOGY. 281
not be relied on. A fact somewhat similar was first observed by Prof.
Daniels, in his researches at the Royal Society, where the water bar-
ometer indicated the change of pressure an hour earlier than the
usual mercurial standard barometers constantly used for observations.
GEOLOGY AND PALZONTOLOGY OF A PART OF THE ROCKY
MOUNTAIN REGION.
Pror. HAtt, in the Report of Stansbury’s Expedition to the Great
Salt Lake, furnishes some notes on the Geology and Palzontology of
a part of the Rocky Mountain Region, from specimens collected in the
course of the Expedition.
The first specimens furnished are from the west side of the Missouri
River, near and above Fort Leavenworth (39° 21! N., 94° 44! W.)
They are all from limestone of the Carboniferous period, and appar-
ently from the upper of the two great limestones of this period in the
West. The most conspicuous fossils are Productus and Terrebratula.
The route from the Missouri westward, shows a continuation of this
limestone as far as the Big Blue river. Here it disappears, and is soon
succeeded by strata of the Cretaceous age, which extends for a consid-
erable distance on the route. Among the cretaceous fossils are a
species of Pholadomya, and the Incceranaus, which is so abundant in
numerous localities in this region.
It would appear that the character of the country from near Fort
Kearney to near Fort Laramie is uniform, and no deposites of older
date than the Tertiary were observed. Of the specimens collected,
there is but a single individual indicating the character of a marine
formation. From the condition of the bones it may even be ques-
tioned, whether the deposit containing them is not of post tertiary age.
. The specimens from the vicinity of Fort Laramie are all from lime-
stone of the carboniferous period. Some of the fossils are identical
with species collected between the Missouri and the Big Blue, and we
‘an only suppose, from the great similarity of the specimens, that it is
a continuation of the same formation. The specimens collected two
days’ march north-west of Fort Laramie, (105° W..,) are a feldspathic
granite with little quartz or mica. The rocks in this locality are
doubtless of metamorphic origin, probably rocks of the Silurian age.
The specimens collected three days’ march in advance of this place,
(105° 25’ W.,) are shaly sandstones and thinly laminated sandstones
containing fossils. These beds are recorded as dipping at the rate of
15° to the N. E., and are probably Devonian. ‘The specimens col-
lected at 105° 50! W., are precisely like those collected at Fort Lara-
mie and contain the same species of fossils; red and gray sandstones
were also seen here. On the following day, (near 106° W..,) is
recorded a bed of coal, three or four feet thick, with Sigellaria and
Calamites. The specimens collected here are those of bituminous coal,
and soft shale, without any well marked vegetable remains. From the
proximity of limestone of the age of the coals, and the records ot
sigillaria and calamites occurring in the same connection, it may be
282 ANNUAL OF SCIENTIFIC DISCOVERY.
resumed that this coal belongs to the true coal measures ; and this
locality is probably an exposure indicating the existence of a great
basin. This point itself, and the surrounding country are well worthy
of a more extended examination, since the discovery of workable
beds of coal in this region would be a matter of national importance.
From the Wind River Mountain to Fort Bridget, (in 41° 18! N., 110°
32! W.,) the collections are all marine tertiary, including many speci-
mens of nautilus and other marine shells. West of Fort Hall are
chert and limestone of the carboniferous period.
The specimens collected in the islands and shores of the Great Salt
Lake, are sufficient to give a very good idea of the general geological
features. The specimens are of metamorphic rocks, consisting of tal-
cose and mica slates, hornblende rocks, and a few specimens of granitic
and syenitic character. From the facts in my possession, it would
appear that these metamorphic rocks are distinctly stratified and highly
inclined, but do not attain any great elevation. The direction of the
ranges, corresponding to that of the elevating forces, appears nearly
to conform to north by west, and south by east. From the form of
the lake and the different localities at which rocks of this character
occur, we may infer that there were two lines of elevation, corres-
ponding with the divisions of the lake. The more elevated portions
of the lake shore, and the mountain ranges consist of carboniferous
limestone. In some localities this limestone is partially altered, losing
its granular character, and becoming sub-crystalline, or threaded by
numerous veins of calcareous spar. In most localities the limestone
abounds in fossils, particularly corals of the Cyathophillide.
It will be seen from these facts that we have very satisfactory infor-
mation that the limestone of the carboniferous period is widely distrib-
uted in the region around the Great Salt Lake. Its position relative
to the coal bed on the north fork of Platte River has not been
determined ; but since no beds of coal have been observed on the
slopes of the mountains in the region of the Salt Lake, we are left to
infer that the coal is to be sought (as elsewhere) above the limestone.
Since the existence of coal is proved at one point (admitting the evi-
dence in favor of its age being that of the carboniferous period,) we
are warranted that it once existed over a much wider area, and can
be, sought with success in the proper situations. The importance of
coal in that distant region cannot be too highly estimated, and the geo-
graphical position and extent of the beds, should be one of the first
points ascertained in thelocation of any route of communication
between the east and the west.
RESEARCHES IN NEW ZEALAND.
ACCORDING to recent accounts from this interesting country, true
palzeozoic coal has been discovered in the north part of the Middle
Island. The accounts are too vague to be entirely decisive of the
important question, whether in those remotest masses of dry land,
remains of the ancient carboniferous floras are buried. Fossils are
GEOLOGY. 283
stated to have been found in a white, fine sandstone grit, but their
nature is not specified, except that remains of some kinds of Pecop-
teris and Sphenophyllum were mentioned, but the species are not
named.
In the south and south-west regions of the Middle Island, Mr. Wal-
ter Mantell, in an arduous exploration for three months, as government
Surveyor in the almost uninhabited and dreary tracts of that country,
_ kept up an active search for the rare indigenous birds, and for fossils;
but with the exception of a large parrot, believed to be unknown to
naturalists, no additions were made to the fauna of New Zealand. A
diligent hunt for vestiges of the Moas, and for a live specimen of
Notornis, was unattended with success. The last accounts from Mr.
Mantell stated that the servants he had sent out to the localities which
native traditions pointed out as the habitat of the Notornis, had
returned birdless, and reported that the wild dogs occupied the country
to such a degree, that it was hopeless to expect the wingless birds could
escape. The stuffed specimen of Notornis in Dr. Mantell’s possession
(in London,) bids fair, therefore, like the last of the Dodos, to be the
sole representative of its race.
MINNESOTA SALT REGION.
PROBABLY there is not aricher salt region on the face of the earth,
than the one in Minnesota. The territory is generally supposed to be
valuable for its agricultural resources alone ; nothing, however, can be
more erroneous. ‘True, its natural agricultural wealth is probably
second to nene in the Mississippi valley, but its mineral wealth is not
less extensive and valuable. Among the latter, its salt stands pre-
eminent. The region lies between 47° and 49° north latitude, and
97° and 99° west longitude. Its exact locality was ascertained and
defined by an expedition sent out from Fort Snelling, by Major Long,
in 1822-3. A description of that salt region, together with its local-
ity, will be found in the Topographical department at Washington.
Our first information of that salt yegion was from a soldier in the
expedition. He says that they had been travelling for several days
over a vast rolling plain, with no trees or water; the troops and horses
were almost famishing with thirst, when they came suddenly upon the
shore of a beautiful lake, about half a mile in diameter, sunk down
deep in the plain. It resembles more a vast sink hole. From the
height above the waters a vast snow bank appeared to line its shore,
but upon examination it proved to be an incrustation of salt as pure
and as white as snow. The waters of the lake were like the strongest
brine. So strong was it that one bathing in it, upon coming out, in a
few minutes would be covered with the white crystallization of salt.
If this salt region be as rich as it is supposed to be, a railroad pro-
jected into it would prove to be the best stock in the country. There
are mines of undeyeloped wealth more extensive, more durable, and
more important than all the gold regions beyond the Rocky Mountains.
Weare informed also, that a very short distance below the surface the
25
284 ANNUAL OF SCIENTIFIC DISCOVERY.
pure rock salt lies in a strata like coal or lime rock. We hope the
attention of the public and the Government will be turned to the
subject. There is a region lying in our immediate neighborhood,
almost unknown, containing more intrinsic wealth than any State in
the Union, and which would yield an annual income probably equal-
ling the entire revenue of the country. — St. Louis Union.
SALT LAKE OF UTAH.
Lr. STANsBuRY in his report of the “ Expedition to the Valley of
the Salt Lake” says: — No one, without witnessing it, can form any
idea of the buoyant properties of this singular water. A man may
float, stretched at full length upon his back, having his head and neck,
both his legs to the knee, and both arms to the elbow, entirely out of
the water. Ifa sitting position be assumed, with the arms extended to
preserve the equilibrium, the shoulders will remain above the surface..
The water is, nevertheless, extremely difficult to swim in, on account
of the constant tendency of the lower extremities to rise above it.
The brine, too, is so strong, that the least particle of it getting into
the eyes produces the most acute pain, and if accidentally swallowed
rapid strangulation must ensue. I doubt whether the most expert
swimmer could long preserve himself from drowning, if exposed to
the action of a rough sea.
Upon one occasion a man of our party fell overboard into the lake,
and, although a good swimmer, the sudden immersion caused him to
take in a few mouthfuls of water before rising to the surface. The
effect was a violent paroxysm of strangling and vomiting, and the
man was unfit for duty for a day or two afterwards. He would inevit-
ably have been drowned, had he not received immediate assistance. Af-
ter bathing it is necessary to wash the skin with fresh water, to prevent
the deposition of salt arising from evaporation of the brine. Yet a bath
in the water is delightfully refreshing and invigorating. The analy-
sis of this water by Dr. L. D. Gale, has shown that it contains rather
more than 20 per cent. of pure chJoride of sodium, and not more than
2 per cent. of other salts, forming one of the purest and most concen-
trated brines known in the world. Its specific gravity was 1.17, but
this will slightly vary with the seasons, being doubtless affected by the
immense floods of fresh water which come rushing down into it from
the mountains in the spring, caused by the melting of the snows in
the gorges. The ancient extent of the lake must have been far
greater than its present limits indicate. As many as thirteen distinct
marks of ancient levels, successive terraces formed by ancient beaches,
the highest as much as two hundred feet above the plain, were count-
ed in one place. These appearances, comparable with the famous
“ parallel roads” of Glenroy, in Scotland, would lead to the inference
that the Great Salt Lake was formerly vastly more extensive, stretch-
ing for hundreds of miles, studded with huge island, now forming
~the isolated mountains that rise amid the surrounding plains. The
immense miry flats, consisting of soft mud, traversed by rills of salt
GEOLOGY. 285
and sulphurous water, that bound its western shores, would them-
selves, if submerged for a few feet, convert the lake into a far-extend-
ing inland sea. At present they glisten with salt-crystals, whose
brilliant glare is interrupted occassionally by oases of artemisa and
greasewood. The two valleys that lie at the southern end of the lake
are the only parts of its shores adapted for human habitation.
Although not directly stated, several facts are given, in the report ot
the expedition which seem to imply that there are no fish in the lake
itself. A curious feature in its zoology is the immense accumulation
on its shores of the larva-cases and other exuvie of dipterous insects,
prebably preserved in such quantities through the peculiar qualities of
the water. No mention is made of molluscous animals or their shells.
The mammals collected from the neighborhood are stated to belong
to the Rocky Mountain series. The most interesting is the great-
tailed fox, Vulpes Marcrourus, described for the first time. Several
interesting new plants were gathered. The difficulty of finding fresh
water around its shores, the necessity of carrying with them all
their previsions, the barren and savage character of a great part of
the region traversed, rendered the survey unusually arduous and pro-
tracted, and would have proved fatal to its progress had not the
climate been one of exceeding salubrity, so that, with all their trials
and fatigues, the members of the exploring party enjoyed uninter-
rupted good health. .
EARTHQUAKES OF 1852.
Tue following is a record of the various earthquake phenomena
which we find reported through different sources, as having occurred
during the year 1852.—Editor.
January 10. In Massachusetts. In this imstance, which has not been
generally noticed, the shock was sensibly felt throughout the whole
length of the State, from New Bedford to Springfield, on the Connec-
ticut River. Shock, very slight.
Jan. 17. Slight shock at Galveston, Texas.
Jan. 26. Throughout the State of Mississippi, and in the south of
France. At Bordeaux, the shocks were very severe, though momen-
tary. On the same day, also at Messina, Sicily, and at this latter place
throughout the month, shecks were frequent.
March 31. Throughout northern India.
April. 10. At St. Michaels, Azores, at 2 A. M., producing great
devastation.
April 14. At the Sandwich Islands. Severe shocks, followed on the
fifteenth by a volcanic eruption.
April 27. At Valparaiso.
April 28. At the Azores.
April 29. Smart shocks experienced in Maryland, Virginia and
North Carolina.
May 9. In South Wales.
286 ANNUAL OF SCIENTIFIC DISCOVERY.
May 11. At Apalachicola, Florida.
May 26. In the province of Shookingah, China ; 300 persons killed,
and property to a great amount destroyed.
June 19. In Berne and Friburg, and throughout Switzerland gen-
erally.
June 20. At the Bermudas.
June 30. In New Hampshire and Vermont, slight shock.
July 7. At Jamaica, several severe shocks, continuing three min-
utes, and causing much damage.
July 17. At St. Jago de Cuba. This shock was also felt at sea by
the ship Tropic, 70 miles west of Jamaica.
August 1. At Groton, Connecticut.
‘August 2. At Bathurst, Canada. Shock sufficient to break glass,
etc. etc.
August 4. In Northern India.
August 14. At Spezzio, Italy.
August 17 and 18. At Port au Prince; severe shocks.
Aucust 18. Throughout St. Domingo.
August 20. Great “earthquake in St. Jago de Cuba. This earth-
quake was one of great violence and occasioned great loss of property
and life. The same day occurred the great eruption of Mount Etna.
August 21. At Jamaica. Also at Ezeroum, Asia Minor. Loss, 306
houses and 17 lives.
August 25. At Augusta, Georgia, and in various parts of the
United States.
August 27. In Turkey.
Aueust 28. At St. Domingo ; also at St. Jago de Cuba.
August —. In the province of Kalsuch, China; a terrific earth-
uake.
: September 16 to 21. At the Phillipine Islands; severe and repeat-
ed shocks, causing great damage and alarm. These earthquakes
were also felt at sea for a great distance.
October 1. At Malaga, Spain.
October 9. South of England; slight shock.
October 11 and 12. At Manilla and the Phillpine iaexice severe.
October 15. In the North of Hungary; a series of shocks.
October 22. At St. Lucia.
November 8. In Sicily ; particularly at Reggio.
November 19. At Valparaiso, Chili.
November 22. At Lima, Peru.
November 26. At St. Jago de Cuba; severe.
December 4. Throughout Mexico.
December 9. At Acapulco, and the whole west coast of Central
America ; shocks in many places severe, and accompanied with vol-
canic eruptions.
December 17. At St. Jago de Cuba.
GEOLOGY 287
GREAT ERUPTION OF MOUNT ETNA.
Mount Etna, which for some years has remained dormant, experi-
enced a very violent and long continued eruption during the past
year. The eruption commenced on the 20th of August, the same day
on which the terrific earthquake of St. Jago de Cuba occurred, and
continued with greater or less activity until the 17th of November
following.
The indications of its approaching activity were, as usual, the drying
up of wells in the neighborhood, the duration of most dense clouds of
white smoke which rose like a vast pine tree, hollow rumbling sounds,
and three violent shocks, as of an earthquake. Shortly after, towards
the east, two new mouths were opened in the site which is known
under the name of the Valle del Leone. At first only clouds of a very
fine ash were thrown up; which completely covered all the land near
the mountain, and quantities of which being taken up still higher by
an impetuous wind, were carried far off into the sea. These, however,
were but a small instalment of what was to follow. Immediately after-
wards an immense body of lava was vomited forth ; which precipitating
itself down the mountain with the violence of a torrent, divided into
three streams. One of these flowed in the direction of Zaffarana —
another in the direction of the Comune of Giarra, more particularly
on an estate called Milo, near Giarra. To give an idea of the
immense quantity of liquid fire that was thrown out, official state-
ments describe this river of lava as being two miles in breadth at the
greatest, and ten palms in depth, whilst the rapidity with which it
moved was such as to cover in one hour a space of not less than 160
palms in extent. It seems, that in a very short time, in consequence
of the increasing strength of the eruption, the new mouths were
broken up so as to form one only; frem which masses of rock and
cinder were thrown into the air to a great height, and falling on the
wide extent of country round, carried with them the most fearful
ruin. The utmost intensity of the eruption perhaps took place on the
25th, 29th, and 30th of August, and on the 4th of September. The
rumbling subterraneous thunders were then incessant, as was also
the shaking of the ground. To this add the clouds of smoke and
flame which rested like an imperial diadem on the summit—and we
may form some faint idea of the magnificent and awful spectacle which
Etna on those days presented.
The accidents of the land, and the greater or less quantity of materi-
als thrown out of the mountain, produced a great variety in the
course of the streams of lava. Sometimes they appeared to drag their
slow length along, sometimes to precipitate themselves with threaten-
ing violence, expanding widely till they covered vast spaces of land,
or twisting and twining into the most capricious sinuosities, and accord-
ing to the varying rapidity of their movements varying their depth
and extent. On the 22d of August the running lava is stated to have
been 18 palms deep, whilst on the 30th it had mcreased to 240 palms
in some places. On the 31st of August the eruption still continued
25*
288 ANNUAL OF SCIENTIFIC DISCOVERY.
very violent. The lava advancing on the village of Ballo, completely
swallowed up several houses on that day, as also the road which divides
it from Zaffarana. During the next two days it diminished in power,
and hopes were entertained that one or two neighboring villages might
be saved. On the 4th of September, however, it again burst forth
with unusual fury, thundering, shaking, and vomiting forth new
matter in the direction of Milo. Thus the mountain continued its
activity with greater or less violence throughout the whole month. If
the lava flowed in smaller quantity, denser clouds of smoke arose, and
a greater quantity of ashes and sand were thrown out. During
the month of October much activity was manifested, though greater
hopes were entertained that the eruptions might soon cease.
A correspondent of the London Athenzeum says, the damage which
has been inflicted is difficult to estimate, for the course of the lava lay
through a country of extraordinary fertility, and abounding in every
species of vegetation. Had nothing but ashes been thrown out, all the
saints in the callender would have been /esteggiati, for nothing 1s so
ropuctive of fertility as volcanic ashes, but what can make any
impression on large masses of indurated lava but the slow operation of
the elements, or what root for centuries will ever be able to pierce it
except the prickly pear ?
An extraordinary feature of the eruption was the vomiting forth
from the crater of a large quantity of sal ammoniac, rendering the air
so impure as to threaten the lives of seamen on the coast. Vessels in
the vicinity of the mountain were covered with cinders, and ashes
and volcanic dust were wafted by the wind as far as Malta.
GREAT VOLCANIC ERUPTION AT THE SANDWICH ISLANDS.
ONE of the greatest volcanic eruptions on record, —that of the
voleano of Mauna Loa, at the Sandwich Isiands, took place in Feb-
ruary, 1852, commencing on the 17th of the month. The eruption
appears to have been scmewhat unexpected, and was not heralded by
any of the accustomed premonitory signs. ‘Phe current seems to have
broken out through an old fissure, about one-third down the side of
Mauna Loa, on the north-west side, and not from the old crater on the
summit, called Mokuoweoweo. ‘The altitude of the eruption was about
10,000 feet above the level of the sea, and at a distance from the Bay
of Hilo, of about 60 miles. A writer who witnessed the eruption from
Hilo, thus describes some features of it:
“ By an accurate measurement of the enormous jet of glowing lava,
where it first broke forth on the side of Mauna Loa, it was ascertained
to be five hundred feet high! This was upon the supposition that it
was thirty miles distant. We are of the opinion that it was a ereater
distance, say from forty to sixty miles. With a glass, the play of this
jet, at night, was distinctly observed, and a more sublime sight can
scarcely be imagined. A column of molten lava, glowing with the
most intense heat, and projecting into the air to a distance of five hun-
dred feet, was a sight so rare and at the same time so awfully grand,
GEOLOGY. 289
as to excite the most lively feelings of awe and admiration, even when
viewed at a distance of forty or fifty miles. How much more Aawe-in-
spiring would it have been at a distance of one or two miles, where
the sounds accompanying such an eruption could have been heard. The
fall of such a column would doubtless cause the earth to tremble; and
the roar of the rushing mass would have been like the mighty waves
of the ocean beating upon a rock-bound coast. The diameter of this jet
is supposed to be over one hundred feet, and this we can easily believe,
when we reflect that from it proceeded the river of lava that flowed
off from it toward the sea. In some places this river is a mile wide,
and in others more contracted. At some points it has filled up ravmes
one hundred, two hundred, and three hundred feet in depth, and still
it flowed on.”
Mr. Coan, a missionary, residing at Hilo furnishes another graphic
description. He says: “ On the 17th instant, at twenty minutes past
3, A. M., a small beacon light appeared on the summit of Mauna Loa.
This light increased until it looked like a rising moon. In half an
hour, brilliant columns of lava shot up against the heavens, and a gen-
eral burst of blood red fusion poured out of the same orifice appar-
ently, which disgorged such awful floods in 1843. We were awakened
at about 4 o’clock, and saw a glare of light streaming through our
windows. Our first thought was that some building near us was on
fire, but on rising we soon perceived that the whole summit of the moun-
tain was irradiated, and that a vast furnace was there glaring with
vehement heat. The molten flood rolled down the side of the moun-
tain so rapidly that in two hours we judged its progress to have been
fifteen miles, the whole lava glaring with great brilliancy. This flow
continued through the day, but with decreasing energy. It became
sluggish at night, and the next day, or after twenty-four hours, no
traces of it were visible from the station; no smoke by day and no
fire by night. At six o’clock, A. M., on the 20th, yesterday, we per-
ceived fire issuing from the side of the mountain toward Hilo, and
about half way down the mount. This lateral crater soon became
intensively active, pouring out a gory flood which soon reached the
base of the mount. At first the stream shot directly down towards
Hilo ; but meeting some obstacle near the foot of the mount its direc-
tion was changed to the north, and it is still flowing towards Mauna
Loa. A vast area between the mountains is already filled with fire,
and the scene by night is one of terrible sublimity. The red hot lava
still rolls out of the side of the mountain in awful floods. It seems as
if the bowels of Pluto were being disgorged. While I write, our
whole atmosphere is filled with lurid smoke, through which the sun
looks down upon us with a yellow and baleful light. The horizon is
hung in murky drapery; detonations, like distant thunder, are heard
from the mountain, and capilliform filaceous vitrifactions are filling
our streets.”
On the 6th of March the lava was still flowing, and the light emitted
by the stream was so intense, that small objects could be most clearly
seen at midnight in Hilo. e
.
290 ANNUAL OF SCIENTIFIC DISCOVERY.
It must be noticed as one of the incidents of this eruption, that the
most striking display of the Aurora, witnessed in the United
States during the year 1852, took place on the 20th of February, dur-
ing the progress of this great eruption.
A letter from Mr. Fuller published in Silliman’s Journal, Sep-
tember, gives the following picture of the intensity of the eruption.
There played a fountain of liquid fire of such dimensions and such
awful sublimity, shaking the earth with such a constant and deafening
roar, that no picture can give any adequate conception of its grandeur.
A few figures may assist the imagination in its attempts to paint the
scene. I made the following calculations, after careful observations
during nearly twenty-four hours, from different points within a mile
of the crater. The diameter of the crater, which has been entirely
formed by this eruption is about 1,000 feet, its height from 100 to 150.
One part of the crater was raised fifty feet during our presence on
the spot. The height of the column of red hot liquid lava, constantly
sustained above the crater, varied from 200 to 700 feet, seldom falling
below 300. Its diameter was from 100 to 300 feet, rarely perhaps
reaching 400 feet. The motions of this immense jet of fire were beauti-
ful in the extreme, far surpassing all the possible beauties of any water
fountain which can be conceived; constantly varying in form, in
dimensions, in color and intensity ; sometimes shooting up and taper-
ing off like a symmetrical Gothic spire, 700 feet high; then rising in
one grand mass, 300 feet in diameter, and varied on the top and sides
by points and jets, like the ornaments of Gothic architecture. The
New Yorker, as he gazes on the spire of Trinity Church, can imagine
its dimensions increased three-fold, and its substance converted into
red hot lava, in constant agitation, may obtain a tolerable idea of one
aspect of this terrific fire fountain. But he should stand at the foot
of Niagara Falls, or on the rocky shore of the Atlantic when the sea
is lashed by a tempest, in order to get the most terrific element in this
sublime composition of the great artist. For you may easily conjecture
that the dynamical force necessary to raise 200,000 to 500,000 tons
of lava at once into the air, would not be silent in its operations.
A NEW MINERAL AND EARTH.
Dr. D. D. Owen, U S. Geologist, gives the following communi-
cation respecting a supposed new mineral and a new earth, discovered
_ by him, in Silliman’s Journal, May, 1852.
While examining, in the summer of 1848, the north shore of
Lake Superior, situated in Minnesota, particularly in the vicinity of
Baptism River, I observed a peculiar, soft green mineral diffused in
the amygdaloidal traps. ‘Though not in large masses, the mineral was
so abundantly disseminated in some of these rocks, that the least blow
of the hammer indented the rock, and left a whitish-green mark from
the easily crushed particles of the soft green mineral in question.
Chemical analysis of the mineral showed it to be essentially a hydrated
silicate of magnesia, and what appeared to be a new earth, interme-
GEOLOGY. 991
diate in its properties between magnesia and manganese. The color
of the mineral when pure, is of a pale yellowish-green, consistence and
hardness about that of wax. Specific gravity, 2.548. It has not been
found crystallized. Treated with hydrochloric acid, chlorine is evolved,
and the greater part of the constituents, except silica, dissolved.
About 10 per cent. of the mineral is made up of the supposed new
earth, which when separated has the following properties and reac-
tions with re-agents:—It dissolves either in hydrochloric or nitric
acid evolving chlorine from the former acid. The solution in hydro-
ehlorie acid, when concentrated, has a beautiful pea-green color, and
the salt crystallizes either of a slightly paler green, or a light chrome
yellow, depending on the degree of heat at which the evaporation is
completed. The peculiar color of its saits, together with the appear-
ance of the residue left in the analytical process after treating with
caustic potash to separate the alumina, was what first attracted my
attention to this earth. When separated. and still slightly contamin-
ated with magnesia, the earth has a pale, flesh color, not unlike yttria.
When freed from magnesia, it has more the appearance of powdered
dried albumen. The earth differs from alumina and glucina in being
insoluble in caustic potash. From magnesia in producing colored
salts ; in being only slightly soluble in ammoniacal salts ; in the pecu-
liar vesicular character of the precipitate with phosphate of soda; in
being precipitated with oxalate of ammonia. From yttria it differs
in not giving a precipitate with oxalic acid in slightly acid solutions ;
in being precipitated by succinate of ammonia, even before the solu-
tion is quite neutral, which prevents this re-agent being applied to
separate iron from it, as is recommended by Berzelius for separating
oxide of iron from yttria. It differs from zirconium in being soluble
in nitric and muriatic acids after ignition. From cerium, in not turn-
ing a brick-red after ignition, and in the color of its salts which are
not amethystine, but shades of green and yellow, except the nitrate,
which is almost colorless. The nitrate crystallizes in prisms, which
seem to be right-rhombic. Its salts, like the corresponding ones of
magnesia seem to be deliquescent. From the quantity of chlorine
evolved during the solution of the mineral and earth in hydrochloric
acid, it appears that this earth must exist in at least two degrees of
oxidation ; the chlorine being disengaged, just as in the case of the
solution of the higher oxides of manganese when treated with hydro-
chloric acid. From these and other consideration Dr. Owen con-
cludes, that the earth contained in the mineral, which is nearly inso-
luble in sal-ammoniac, insoluble in caustic potassa, and producing the
above reactions with re-agents, and green and yellow salts, must be
either a new earth or else a modification of some known earth not
previously known. The name Thalium is proposed for the base of
this earth, Thalio for the earth itself, aud Thalite for the mineral from
which it is extracted.
The new metal Donarium,* the discovery of which was announced
last year by Bergemann, proves to be nothing but Thorina.
* See Annual of Scientific Discovery, 1852, p 176.
292, ANNUAL OF SCIENTIFIC DISCOVERY.
OBSERVATIONS ON THE DIAMOND.
Sir Davin Brewster at the Belfast meeting of the British Asso-
ciation stated that his opinion had been requested by Prince Albert
respecting different forms into which it was proposed to reduce
the Koh-i-noor diamond, in order to make it an ornamental
gem. In the state in which it then was, it exhibited an inferior dis-
play of colors to its glass model, and it was only by surrounding it
with a number of vivid lights that its colored refractions could be
developed. Having had occasion to observe some remarkable phe-
nomena in small portions of diamond, I was desirous of examining so
large a mass of diamond as the Koh-i-noor before it was reduced in
size, and covered with facets which would not permit it to be exam-
ined. -His Royal Highness readily granted my request, and I had
thus an oppportunity of submitting it to the scrutiny of polarized
light. In place of producing no action upon this species of light, as
might have been expected from its octahedral structure, it exhibited
streaks of polarized tints, generally parallel to one another, but in
some places of an irregular form, and rising to the yellow of the jirst
order of colors. These tints and portions of polarized light were
exactly the same as those which I had Jong ago found in many other
diamonds. In placing the Koh-i-noor under a microscope of consid-_
erable power, I observed in it, and also in each of the two small dia-
monds which accompanied it, several minute and irregular cavities,
surrounded with sectors of polarized light, which could only have been
produced by the expansive action of a compressed gas, or fluid, that
had existed in the cavities when the diamond was in a soft state. In
an external cavity, shown in the model, and which had been used for
fixing the gold setting, I observed, with common light, a portion of
yellow light, indicating a yellow substance. Mr. Garrard and others
considered it as gold rubbed off the gold setting; but as gold is never
yellow by transmitted light, I considered the color as produced by a
yellow solid substance of unknown origin. Sir De la Beche having
suggested to me that it would be desirable to make a general examina-
tion of the principal diamonds in London, I went next day tothe *
British Museum, and found there an interesting specimen, which threw
some light on the yellow solid to whieh I have referred. This speci-
men was a piece of colorless diamond, uncut, and without any crys-
talline faces, about three or four tenths of an inch broad, and about
the twelfth of an inch thick, and on its surface there lay a crystal of
yellow diamond, with the four planes of semi-octahedron. This singu-
lar fact was illustrated by a large model placed beside it. Upon
examining the original, I noticed a pretty large cavity in the thickness
of the specimen, with the extremity of which the yellow octahedron
was connected ; and finding a portion of amorphous yellow diamond
in the other end of the cavity, I had no doubt that the yellow crystal
had emerged, in a fluid state, from the cavity when it was accidentally
opened, and had immediately crystallized on the surface of cleavage.
Iam well aware that such an opinion makes a good demand upon the
GEOLOGY. 293
faith of the mineralogist ; but to those who have seen, as I have done,
the contents of fluid cavities in crystals solidifying and even crystal-
lizing on the face of cleavage, while another portion of the con-
tents of the cavity escaped in gas—to those who have seen in
topaz cavities numbers of regularly formed crystals, some of which,
after being fused by heat, instantly re-crystallized—the conclusion I
have drawn will be stripped of much of its apparent extravagance.
In examining a number of diamonds in the Museum of the East India
Company, and about forty or fifty in the possession of Messrs. Hunt &
Roskill, I found many containing large and irregular cavities of the
most fantastic shapes, and all of them surrounded with irregular
patches of polarized light, of high tint, produced undoubtedly, by a
pressure from within the cavities, and modified by their form. Among
these specimens I found one or two black diamonds, not black
from a dark coloring matter, like that in smoky quartz, but black from
the immense number of cavities which they contam. Tavernier has
described a large and curious diamond which throws some light on the
subject of this notice. It contained, in its very centre, a large black
cavity. The diamond merchants refused to purchase it. At last a
Dutchman bought it, and, by cutting it in two, obtained two very fine
diamonds. The black cavity through which he cut was found to con-
tain eight or nine carats of what Tavernier calls black vegetable mud!
Mr. Tennant, the celebrated geologist, stated that at the last meeting
of the British Association, Dr. Beke read a paper “ On the Diamond
Slab supposed to have been cut from Koh-i-noor.” He stated: — “ At
the capture of Coochan there was found among the jewels of the
harem of Reeza Kooli Khan, the chief of that place, a large diamond
slab, supposed to have been cut from one side of the Koh-i-noor, the
great Indian diamond now in the possession of Her Majesty. It
weighed about 130 carats, showed the marks of cutting on the flat and
largest side, and appeared to correspond in size with the Koh-i-noor.”
Prof. Tennant was induced to record his opinion of the probability of
this being correct. He had made models in fluor spar, and afterwards
broken them, and obtained specimens which would correspond in
cleavage, weight, and size with the Koh-i-noor. By this means he was
enabled to include the piece described by Dr. Beke, and probably the
large Russian diamond, as forming altogether but portions of one large
diamond. The diamond belongs to the tesselar crystalline system ; it
yields readily to cleavage in four directions, parallel to the planes
of the regular octahedron. Two of the largest planes of the Koh-i-
noor, when exhibited in the Crystal Palace, were cleavage planes —
one of them had not been polished. This proved the specimen to be
not a third of the weight of the original crystal, which he believed to
have been a rhombic dodecahedron; and if slightly elongated, which
is a common form of the diamond, would agree with Tavernier’s
description of it, bearing some resemblance to an egg. Referring to
the diamonds procured in the Brazils, he related a fact which, he said,
was told to him by a gentleman from Brazil. A slave in that country
was one day wading in a river in search of the precious gems to be
294 ANNUAL OF SCIENTIFIC DISCOVERY.
found imbedded in the strand, when he struck his crow bar in a spot
which surprised him by its hollow sound. He repeated its blows, and
soon struck the iron through a crust of siliceous particles cemented
together by oxide of iron. On removing the concrete mass, the slave
discovered a bed of diamonds, which were afterwards disposed of for
£300,000. Such an immense number of diamonds being thrown upon
market, so overstocked it that nearly all the dealers became bankrupt,
and upon the diamonds being introduced into England, the glut was
so great that the results to the trade were equally disastrous, only
three English houses being able to stand up against it. One of these
persons was a gentleman in Leadenhall street, who was so largely
engaged in the trade, that he had actually shown him (Mr. Tennant)
a peck full of diamonds.
A London journal furnishes the following account of the re-cutting
of the famous Koh-i-noor diamond : —
This precious stone, which was the synosure of the World’s Exhi-
bition of 1851, attracted, from the multitudes who last year gazed
upon it, expressions of disappointment at the somewhat dim radiance
of its lustre, not fulfilling the expectations entertained from the high
flown descriptions which had been given of the Mountain Light —a
title which many beholders held to be a misnomer. ‘This disappoint-
ment having come to the knowledge of those into whose possession it had
passed, suggested the desirability, if practical, of effecting such altera-
tion in the shape of the diamond as would remove the admitted defects
of the oriental cutting, to which it had been subjected by its original
proprietors. With this view, the opinions of various scientific gentle-
men were taken, and some doubts having been expressed as to the
possibility of cutting the gem without incurring, a great risk of its
destruction, Professor Tennant and Mr. Mitchell were especially
requested to examine and report upon the practicability of the sug-
gestedimprovement. These scientific gentlemen accordingly prepared
a report, wherein they admitted the improvement which the proposed
alteration in shape would effect upon the Koh-i-noor, but expressed
fears that any lateral cutting would endanger its integrity. It was
then determined to submit the matter to the opinions of practical
lapidaries; and with that view the Crown jewellers, Messrs. Garrard,
were instructed to obtain a report from competent persons versed in
diamond cutting. Those gentlemen thereupon consulted Messrs. M.
& E. Coster, of Amsterdam, (the diamond cutting trade having been
entirely lost to this country,) who, while admitting the accuracy of the
fears expressed in the report of Professor Tennant and Mr. Mitchell,
nevertheless were of opinion that the dangers were not so formidable
as to prevent the intended operation from being safely effected, pro-
vided the necessary skill of superior artists was employed. ‘This opin-
ion was sufficiently encouraging to induce an order for the preparation
of the requisite machinery to be erected on the premises of Messrs.
Garrard, and accordingly a smail steam-engine of from two to four-
horse power was erected, and put in operation. As this is the largest
diamond which has been cut in Europe for a long period, the com-
GEOLOGY. | 295
mencement of the work was personally undertaken by the Duke of
Wellington, in the fellowing manner: — The Koh-i-noor having been
embedded in lead, with the exception of one small salient angle
intended to be first submitted to the cutting operation, his Grace
placed the gem upon the soaife—an horizontal wheel revolving with
almost incalculable velocity — whereby the exposed angle was
removed by the friction, and the first facet of the new cutting was
effected. This, the first step in the operation, forms but a small item
of progress, as it is expected that the work, under the hands of the
two Dutch artists to whom it has been entrusted, will occupy a period
of some months, it being, as may be conceived, a work of great deli-
cacy, involving an equal amount of skill and care. The Koh-i-noor
is intended to be converted into an oval brilliant, and the two smaller
diamonds which accompany it, are to be similarly treated as pendants.
The present weight of the principal gem is 186 carats, and the pro-
cess now in course of progress will not, it is anticipated, diminish in
any material degree its weight, while it will largely increase its value,
and develope its beauty. Some conversation has occurred respecting the
doubts imputed to have been cast by Sir D. Brewster upon the iden-
tity of the Koh-i-noor; but the general opinion amongst those best
acquainted with the subject appeared to be, that it was impossible for
Dhuleep Singh to have palmed off a fictitious diamond, when his con-
stantly wearing it on state occasions must have rendered it perfectly
familiar to thousands who would instantly have detected any attempt
at substitution. ‘The more probable assumption was stated to be, that
the weight of the Mountain of Light had been more Orientale some-
what exaggerated.
The business of cutting diamonds is now chiefly confined to
Amsterdam, and is thus described in a late number of the London
News :—
It was on a Sunday, in the early part of 1847, that, being at
Amsterdam, we wandered out from our hotel on a chance excursion
through the town. Before we had gone far the noise of machinery
arrested our attention, and, on making inquiries, we found that it pro-
ceeded from the celebrated diamond-cutting establishment of the
place. Let not the reader picture to himself a clean, neat, well-look-
ing establishment, such as one of our paper or cotton mills, but as an
old lumbering shed, in which, impelled by the labor of four or five
sorry horses, revolved a horizontal wheel. This was the only source
of motion by which the grinding machinery was kept at work; and
its primitive nature ina century when the steam-engine 1s made to spin
cotton, grind corn, and weave cloth, could not but suggest to the
looker-on how remote from ordinary wealth — wealth selt-developing
and expansive — was the conventional wealth represented by the
diamond trade. The operation of cutting is performed in several dilap-
idated rooms up stairs. There are seen in rapid revolution some
scores of horizontal metal wheels, each about a foot and a half in
diameter. Their surfaces being smeared from time to time with a
mixture of diamond dust and olive oil, and set in revolution, the dia-
26
296 ANNUAL OF SCIENTIFIC DISCOVERY.
mond to be ground is brought in contact with the revolving metallic
surface. It need hardly be said, that the task of holding a diamond
to be ground firmly against the revolving wheel for so long a period
of time as is necessary, would be impossible. Continuous pressure is
effected in another and very simple manner: the diamonds are
imbedded, all except the parts to be ground, in a heavy mass of very
fusible solder shaped like a hammer, the handle of which being fixed
as to horizontal motion, but free by means of a hinge to move up and
down, and the face of the hammer being brought flat upon the side
of the horizontal wheel, the operation of grinding, cutting as it is
_ called, proceeds without further trouble.
ARGENTIFEROUS LEAD MINES OF MIDDLETOWN, CONN.
Axsout two miles below the city of Middletown, Connecticut, on
the banks of the Connecticut river, are several excavations, some 18
to 30 feet deep, made during the Revolutionary war by a company,
for the purpose of procuring lead ore, so as to supply the American
troops with lead. It was worked for some time, the ore smelted, and
the lead separated from the rock in which it was found imbedded.
Not being found sufficiently profitable to make it an object, the work-
ing of the mines was discontinued. A recent examination having
been made of these old workings, a considerable quantity of silver
was found associated with the lead, and the persons interested became
satisfied, that it could be worked profitably, and that the quantity of
silver would fully pay the whole expenses of working the mines,
leaving the large quantity of lead obtained to form the profit of the
mining operations. ‘Thus far, although they have worked but a few
months, with a small force, and cannot be supposed to have but
tested the richness of the veins of silver—yet it is paying its way, and
even more than that. Lately, some rich veins of silver ore have been
discovered—and some pure native silver—the former being nearly
free from the lead mixture. The ore is broken up and then fed to a
mill, where it is pounded fine—the pounders, of which there are four,
being operated by an overshot water wheel, which is carried by water
from a dam, with a fall of some 15 or 25 feet. As fast as the ore is
pounded sufliciently fine, a stream of water carries it into troughs,
where it is washed. From these troughs it is taken out, and sent to
New York, where the metals are separated.
MINERALOGICAL NOTICES.
The following mineralogical notices have been communicated to
Silliman’s Journal, July, by Mr. W. 'T. Blake.
Apatite—During the past winter a shaft has been sunk upon the
vein of crystalline phosphate of lime at Hurdstown, Essex Co., N. Y.,
and large blocks of massive apatite have been raised; some of the
largest of these masses weighed not less than 200 pounds, and were
nearly pure apatite,—the specimens have very little color, portions of
GEOLOGY. 297
the masses being translucent and nearly transparent, and resembling
the “asparagus-stone” variety of the mineral. The more compact
and opaque masses frequently cleave into hexagonal prisms, some of
them having lateral planes three inches wide. Rhombohedrons
resulting from cleavage are not uncommon.
Brown Tourmaline—Beautiful transparent crystals of brown tour-
maline occur disseminated in the massive and concretionary phos-
phorite at the “eupyrchroite” locality, Crown-point, Essex Co.,
N. Y.; terminated crystals are rare, but the few found are highly
modified, and are crystallographically similar to the crystals from
Gouverneur, N. Y., described and figured by Rose. (See Dana’s
Mineralogy, p. 136.) The color is a light clove-brown, and the
crystals exhibit dichroism. Specimens cut and polished have much
beauty as gems.
Red Zine Oxide —Fine cabinet specimens of lamellar red zine oxide
can be obtained at the zine mine, Stirling Hill, Sussex Co., N. Y.
The lamellar masses are disseminated in the highly crystalline lime-
stone which has frequently a delicate pink hue and translucent,—
cleaving readily into large rhombohedrons; the contrast between the
red zinc and the gangue adds greatly to the beauty and mineralogical
value of these specimens. These distinct nodules of oxide are found
at the junction of the vein of red zine ore and the limestone, but the
oxide is free from any admixture with Franklinite crystals; good
crystalline specimens of Franklinite are now very rare at the mine.
Fluor-Spar Locality—Shawneetown, Gallatin Co., Ill, has long
enjoyed a reputation among American mineralogists as a locality for
fluor-spar. Having had occasion, a few months since, to visit the
southern portion of Illinois, I explored this locality. It was found,
however, that the fluor-spar did not occur, as reputed, at Shawnee-
town, but ten to fifteen miles farther down the Ohio, and a half a mile
to a mile north of the river.
The fiuor occurs in the carboniferous limestone, it forms numerous
veins, many of which are from ten to twenty feet in thickness. It is
highly crystalline, and often very fetid; beautiful crystallized speci-
mens are found in pockets in the veins, which are sometimes entirely
colorless, frequently of a blue, a violet, or a pink tint, and more
rarely of an emerald-green. The localities have been quite exten-
sively worked for lead, which, under the form of galena, is associated
with the fluor. The amount of galena is quite considerable, although
no regular vein has as yet been found; it is somewhat argentiferous,
yielding, on an average of several specimens examined, about four
ounces of silver to the ton. The mining of these veins has devel-
oped, besides some fine crystallizations of fluor, as a compact variety
in which the associated galena also has the compact structure. An
immense amount of a remarkably fine quality of fluor-spar could be
obtained from these veins should there be a demand for it in the arts.
—Com. to Silliman’s Journal by S. J. Brush.
Platinum in Canada.—This metal was detected last summer, in the
gold washings of the Riviere du Loup, where it is found sparingly
298 ANNUAL OF SCIENTIFIC DISCOVERY.
mixed with the gold, in minute scales and grains. Associated with it
there was another metal which resisted completely the action of the
acid. It forthed small plates of a tin-white, generally hexagonal, and
so hard as to resist steel; these characters show it to be widosmine,
the native alloy of the rare metals iridium and osmium, which is
found with the gold of South America, and is from its extreme hard-
ness, employed “to form the points of gold ‘pens. —heport Canadian
Geologists.
LARGE DEPOSITE OF GRAPHITE.
Ar St. Johns, N. B., near the new suspension bridge over the St.
John’s river, a very extensive deposite of graphite has been opened
and explored to a considerable extent. The vein, or bed as it might
more properly be called, is nearly vertical, and inclosed between beds
of highly metamorphic schists. It is entered near the water on the
face of a precipitate cliff about seventy feet high, the walls of the
lode being in the main parallel to the graphite deposite. This bed has
been explor ed by a gallery or adit level over a hundred feet, and by
cross cuts at right angles to this some twenty or more feet. All these
are in the graphite mass, and of course the floor and roof of the
levels are of the same mineral. The quartzose walls have occa-
sionally approached, and in some cases masses of quartz, or schist,
have been included in the graphite. The course of this deposite is
about northeast and southwest, or nearly in the direction of the strike
of the strata of schist. The graphite i is not of a very superior quality
as a mass, though portions of it are quite pure. As yet no solid and
perfectly homogenous masses have been taken out. It has a foliated
structure more or less highly marked. Iron pyrites is too abundantly
diffused in it to admit of its use for crucibles. The chief economical
use made of it has been in facing the sand moulds for iron castings,
for which purpose it is ground to a fine powder. Some of the finer
parts are also used to manufacture pencils. Many hundred tons of
graphite from this deposite have already been taken out since the
mine was opened two years ago, and the supply may be esteemed
- inexhaustible. The vein or bed re- appears on the opposite side of the
St. John’s river, and on the side now opened it has been traced over
amile. The position of the deposite in conformable metamorphic
schists, suggests the conjecture that this deposite of graphite may
represent a ‘former coal bed.
LAKE SUPERIOR COPPER MINES.
Tue National Intelligencer publishes a few facts to show the advan-
tage of a judicious prosecution of the copper mining business. The
Intelligencer says :—
The mine which has thus far been the most productive is called the
Boston and Pittsburg Mining Company. Work was commenced in
1848. A capital of $110, 000 was paid in, or about $18 50 per share on
GEOLOGY. i 999
6,000 shares. In 1849, $60,000 was divided among the shareholders ; in
1850, $84,000; in 1851, $60,000, and in 1852, $60,000 more will be
divided. In another view, shares which cost $184 have received
back in dividends $34 and are worth $100 in the market.
The Northwest Mining Company ranks next in value. Mining was
here commenced in earnest in 1849. About $80,000 have been paid in.
In 1849 the net proceeds from the sale of copper amounted to some
$5,000 ; in 1850 to about $32,000; and in 1851 to something over
$50,000. This company owns a large tract of mineral territory, upon
which two valuable veins have been opened and a number of others
discovered. The property owned by this company is of immense
value, and magnificent fortunes will in a few years doubtless be
realized from it.
The Minnesota Mining Company is located near the Ontonogon
River, some forty miles westward of the two preceding. Immense
blocks of pure copper are taken from this mine. It commenced in the
autumn of 1848, and has a capital paid in of some $90,000, or $300na
share —there being but three thousand shares. They command $150
ih the’ market. A large dividend will, we think, be paid from the
earnings this year.
The gain reaped from the workings of a successful mine is free-
quently 500 per cent. Shares in the Boston and Pittsburg Company,
which cost $18 50, sell for $100. In the Minnesota for $30 the owner
can now receive $150. The Northwest shares will probably increase
100 per cent. in value in a year.
NEW METEORITES.
PROFESSOR SHEPARD, of Amherst College, has recently added to
his collection of meteorites a very valuable specimen, which is des-
cribed as a mass of compact malleable iron weighing 178 pounds, of an
elongated ovoidal form, covered with the usual indentations, and
exhibiting the characteristic crystalline figures. It was discovered on
the Great Lion River, in the Nemaqua Land, in South Africa, and,
having beeen transported several hundred miles in wagons to the
Cape of Good Hope, was shipped to London. Prof. Shepard, being
fortunately in that city at the time of its arrival, immediately entered
into negotiations to obtain it, and with considerable difficulty, succeed-
ed. He also has another specimen from Newberry, South Carolina,
weighing fifty-eight pounds. His collection of extra terrestrial sub-
stances weighs more than 350 pounds, and includes two hundred
specimens from more than a hundred different localities.
Prof. Root in a communication to Silliman’s Journal, November,
1852, states, that a mass of malleable iron weighing nine pounds, was
found last fall in digging a ditch on a farm near the free bridge on the
Cayuga side of the Seneca River. It was drop shaped, about four
inches in diameter and seven inches in length. When found it was
coated with oxide of iron. The surface was uneven, and some of the
prominent ait ta terminated by planes of octahedral crystals. It
300 ANNUAL OF SCIENTIFIC DISCOVERY.
may be an interesting fact, that the locality where this iron was found is
only a few miles from Waterloo, in Seneca county, where a meteorite
fell in 1827, as has been stated by Prof. Shepard.
GOLD DISTRICTS OF CANADA.
From the recent reports of the Provincial Geologists, we derive
the following facts relative to the existence and production of gold in
Canada: — The auriferous district has been found by examination to
spread over an area probably comprising between 3,000 and 4,000
square miles. It appears to occupy nearly the whole of that part of
the Province which lies on the southeast side of the prolongation of
the Green Mountains into Canada, and extends to the boundary
between the Colony and the United States. Two general lines of
exploration were followed, one of them up the Chaudiere and Riviere
du Loup and the other from Lake Etchemin to Sherbrooke on the St.
Francis. The former, running transverse to the rock ranges measur-
ed about forty-five miles, and the latter with them about ninety miles.
The transverse line was more closely examined than the other, and
traces of the precious metal were met with at moderate intervals
throughout the whole distance. ‘They were not confined to the chan-
nels of the main streams merely, but those of various tributaries
furnished indications sometimes for a considerable distance up. It is
not supposed that the limits of the auriferous district have been ascer-
tained, but that it very probably extends much farther to the north-
east, and attains the valley of the river St. John, while to the south-
west it is known to reach Vermont, and to be traceable at intervals
through the United States, even, it is said, as far as Mexico. In its
breadth, however, it does not appear to cross the range of mountains
with which it runs parallel, and no traces of it have been met with on
their northwestern flank. The deposite in which the gold occurs is
part of an ancient drift, probably marine, and supposed to be of higher
antiquity than that which occupies the valley of the St. Lawrence
and some of its tributaries. In this, alluded to in various reports as
tertiary and post-tertiary, the remains of whales, seals, and two species
of fish,and many marine shells of those species still inhabiting the
Gulf of St. Lawrence, are found. ‘These shells on the Mountain of
Montreal attain a height of about 470 feet above tide level in Lake St.
Peter, which is the greatest altitude known; none of the remains
have yet been found in the Canadian gold drift, and as this appears in
its lowest undisturbed parts to be at a height of about 500 feet above
the sea, it is probable what is now exposed of it, had emerged from the
ocean before the Laurentian drift was placed, while in lower levels it
would be covered up by it.
During the five months of the summer of 1851, the whole amount of
gold collected by fifteen men at the washings on the River de Loup at
its junction with the Chaudiere, was about 1,900 penny-weights.
From among a few ounces of fine gold obtained, there were collected
small grains both of platinum and iridosmine, the value of the
GEOLOGY. | 301
former being below, and of the latter double that of gold ; almost all of
this fine gold was at first of so white a color that it was considered
probable the circumstance might be owing to the presence of a very
large proportion of silver; some of the larger pieces also obtained
were spotted white from the same supposed cause; but, Mr. Hunt, on
heating this white gold, found that it quickly turned to a good golden
yellow, and that the discoloration was occasioned by a thin coating of
mercurial amalgam. As the spots were perceived on some of the
larger pieces immediately on their being first obtained on the shovel,
it is supposed they must have been spotted with the mercury while
still undisturbed in the drift; and as no mercury had been used on
the ground, it leads to the supposition that some ore of mercury may
possibly be one of the mineral products of the country, though not a
grain of cinnabar, the commonest form of the ores of mercury, has been
observed in the gravel. Among the substances obtained in separating
the gold, lead shot of various sizes, from partridge to swan shot, has
been nearly as abundant as the gold. Not a vanning was made of the
concentrated material without obtaining some of it ; its presence is no
doubt due to the operations of those who have followed the chase, and
to judge from the quantity of the shot the place must have been one of
favorite resort. Whether the hunters may at any time have brought
quicksilver with them and spilt it, is a question that cannot be deter-
mined.
The Geologist concludes, from the evidence collected, that the de-
posites are not generally sufficiently rich to render their working re-
munerative to unskilled labor; and that the agriculturist and others
engaged in ordinary occupations of the country, would only lose their
time and labor by turning gold hunters.
GOLD AND ITS PRODUCTION.
FIveE years have hardly elapsed since the gold yield in California
became a fixed fact, and within that short period of time between a
hundred and ninety and two hundred millions worth of gold dust has
been added to the wealth of the world, and a trade has sprung up
between the Atlantic States and San Francisco of the greatness of
which some idea may be indirectly formed, from the fact that the im-
ports from all other parts of the world to that port have increased
from three and a half millions in 1851, to ten and a half millions in
1852. The California movement has made its influence felt all over
the world; but now even California itself seemes to be eclipsed and
outstripped in its productiveness by the more recent and more magni-
ficent discoveries of gold fields in Australia. They completely throw
into the shade all the mines of Peru, Mexico, or California. So
extensive are the gold deposites distributed in Australia, that the very:
streets of Melbourne are found, in a manner, to be paved with them.
The broken quartz rocks which have been used to MacAdamize the
streets are found to contain gold. :
302 ANNUAL OF SCIENTIFIC DISCOVERY.
While Melbourne is thus favored, mines of immense value have
been opened at Mount Ballaret and Mount Alexander, about eighty
to one hundred miles north of the city. The treasure taken from
these two deposites alone, from the 1st of December, 1851, to the 1st of
April, 1852, amounted to about $9,000,000.
The first discovery of gold was made near Bathurst, in New South
Wales, on the 22d May, 1851, from 150 to 164 miles west of Sidney.
The localities first worked were at Summerville Creek, Abercrombie
river, from whence further discoveries have been made over a vast
mountain region of country. From May to the 6th September the
shipments reached $750,000, and on the 8th November about $1,000,-
000. Lumps were occasionally found weighing from twenty to
twenty-seven pounds. In December, 1851, the parties at the diggings
in Victoria were estimated at from eight to ten thousand, and near
Bathurst, at four thousand. The whole amount sent to England since
the discover y in May, 1851, is estimated at twenty millions. The gold
region already discovered in Australia promises to yield double ‘and
triple the quantity of gold, by the same number of laborers, over that
obtained in California. Good observers suppose it to extend over an
area of not less than 15 to 20,000 square miles, the whole area of the
island being estimated at about three million square miles.
Accounts from Australia to November, 1852, state that the produc-
tion of gold is on the increase, and many of the stories which are
received would seem almost incredible, were they not fully corrobo-
rated by actual receipts. Not only do the old diggings yield abun-
dantly, but new ones are found daily of wide extent. To show that the
recent accounts must be founded in truth, it is said that the receipts
from Mount Alexander and Ballarat diggings alone, are given in the
Australia papers at one million seven hundred thousand nine hundred
and seventy-four ounces, or between seventy-three and seventy-four
tons, in ten months. From the entire Victoria gold fields, in the same
period, the receipts had been one hundred and five tons. The
amount of gold actually exported from the country from October,
1851, to September, 1852, amounted to over forty millions of dollars.
The assays made of the Australian gold show that it is somewhat
purer than that obtained in California. The assays of the United
States Mint, at Philidelphia, give a fineness of 966 thousandths. Making
an allowance for melting, “this gives a value to the native grains of
about $19 60 per ounce. ‘Assays. that have been made in England
are reported to have given the result of 938 thousandths fine. Upon
these facts, it is pre esumed that Australian gold is better than Califor-
nia or, in other words, that it contains less silver by six or seven per
cent. on the average.
Gold in Australia.— A report has been presented to the Imperial
Geological Society of Vienna relative to the production of gold in
Austria. Austria produces the most gold of any European State. It
amounts yearly to 7,500 marks, which promises asum of 603,000
ducats. Much of this j is obtained by the Gipseys by sand-washing i in
Hungary and Siebenburgen. There are two ways in which the gold
GEOLOGY. 303
is found —one is in the deposites of sand and soil; the other in the
strata of ore. The latter is the most common method of finding it in
Hungary and Siebenburgen.
Gold in Vermont. — Specimens of gold have been found during the
past season in Bridgewater, Vermont, by Mr. Mathew Kennedy, of
Plymouth, Vt. They were taken from a quartz vein in mica and talcose
slate, and the gold is associated and intermingled with the white quartz,
ferruginous quartz, galena, and iron and copper pyrites. In occurs in
scales and grains of various sizes, and is of a beautiful clear yellow.
The vein has been traced some 50 or 100 rods, and farther explora-
tions will soon be made to prove it at other points. The gold forma-
tion is known to extend nearly the whole length of the State, and this
discovery may lead to a fair examination of the formation.
Gold in Demerara.— Advices from Demerara state, that gold has
been discovered in that colony up the Cuyuni river, and that about
£200 had already been brought in. It is alleged to be remarkably
pure and to consist of small lumps, and also of scales and dust. The
locality is said to be not more than two or three days’ journey into the
interior.
In addition to the gold discoveries made within a recent period in
Australia and California, it is stated that valuable deposites have been
found on the St. John’s river, near Liberia, in Africa; howéver this
may be, it is undoubtedly true, that the exportation of gold from the
west coast of Africa has greatly increased within the last two years.
The amount received in Liverpool alone from this source, was estimat-
ed for the year 1851, to exceed £300,000.
Consumption of Gold. —'The following curious statistics relative to
the consumption of gold were stated in a lecture lately delivered at the
Geological Society at London. The entire amount in circulation is
said to be £48,000,000; of which the wear and waste is stated to be
33 per cent., annually £1,680,000. The consumption of gold in arts
and manufactures is as follows : —
inthe Umited Kingdom, .... 6. 25.9) jays, » «py.s)4a24000,000
France, . RE Ra et age AT Ne . 1,000,000
ERIN ari sf otek ne, wate ih oak alas coll alls Seu Oe
iMher parts of Hnrope,.. (joey <) sicsji eons 4y2e 1,600,000
ALCS a aes s \iisitle Ae Siackh, aifle om finger’s end of the author —and the most unwilling, cautious, and antago
nistic reader ig compelled to yield his thorough assent to the argument.'’—Boston Post.
GOULD AND LINCOLN, PUBLISHERS, BOSTON.
THE OLD RED SANDSTONE;
— orn —-
NEW WALKS IN AN OLD FIELD.
BY HUGH MILLER.
FTROM THE FOURTH LONDON EDITION—ILLUSTRATED.
A @riter, in noticing Mr. Miller’s ‘‘ First Impressions of England and the People,”’ iz
the New Hnglander, of May, 1850, commences by saying, ‘‘ We presume it is not neces
gery formally to introduce Hugh Miller to our readers; the author of ‘The Old Red Sand-
stone’ placed himseif, by that production, which was first, among the most successfii
geologists, and the best writers of the age. We well remember with what mingled emotion
and delight we first read that work. Rarely has a more remarkable book come from the
press... . For, besides the important contributions which it makes to the science of Geol-
ogy, it is written in a style which places the author at once among the most accomplished
writers of the age. . . . He proves himself to be in prose what Burns has been in poetry.
We are not extravagant in saying that there is no geologist living who, in the descriptions
of the phenomena of the science, has united such accuracy of statement with so much
poetic beauty of expression. What Dr. Buckland said was not a mere compliment, that
*he had never been so much astonished in his life, by the powers of any man, as he had
been by the geological descriptions of Mr. Miller. That wonderful man described these
cbjects with a felicity which made him ashamed of the comparative meagreness and pov-
arty of his own descriptions, in the Bridgewater Treatise, which had cost him hours and
days of labor.’ For our own part we do not hesitate to place Mr. Miller in the front rank
of English prose writers. Without mannerism, without those extravagances which give a
factiticus reputation to so many writers of the day, his style has a classic purity and ele-
gance, which remind one of Goldsmith and Irving, while there is an ease and a naturalness
in the illustrations of the imagination, which belong only to men of true genius.”’
“The excellent and lively work of our meritorious, self-taught count: yman, Mr. Miller,
is as admirable for the clearness of its descriptions, and the sweetness of its composition,
as for the purity and gracefulness wnhich pervade it.”—Hdinburgh Review.
‘A geological work, small in size, unpretending in spirit and manner; its contents, the
sonscientious narration of fact; its style, the beautiful simplicity of truth; and altogether
possessing, for a rational reader, an interest superior to that of anove.* —Dr. J. Pye Smith.
‘This admirable work evinces talent of the highest order, a deep and healthfal mora.
feeling, a perfect command of the finest language, and a beautiful union of philosophy and
poetry. No geologist can peruse this volume without instruction and delight.'’—Silis-
man’s American Journal of Science.
“Wr. Miller’s exceedingly interesting book on this formation is just the sort of work te
render any subject popular. Itis written in a remarkably pleasing style, and ccnia'ss a
wonderful amount of information.’’— Westminster Review.
“Ty. Mr. Miller's charming little work will be found a very graphic description of the O14
Redfishes. I know not of a more fascinating volume on any branch of British geology,""—=
Mantell’s Medals of Creation.
Sir RODERICK MURCHISON, giving an account of the investigations of Mr. Miller, spoke
In the highest terms of his perseverance and ingenuity as a geologist. With no other advan
tages than acommon education, by a careful use of his means, he had been able to give
himself an excellent education, and to elevate himself to a position which any man, in any
sphere ef life, might wellenvy. He had seen some of his papers on geology, written @
style so beautiful and poetical as to throw plain geologists, like himself, in the shade.
GOULD AND LINCOLN, PUBLISHERS, BOSTON.
———
THE EARTH AND MAN:
Lectures on Comparative Physical Geography, in its Relation to the History
of Mankind.
By Arnoxp Guyot, Prof. Phys. Geo. & Hist. Neuchatel.
Translated from the French, by Pror. C.C. Feiton. — With Illustrations.
Revised Edition. 12mo. Price $1.25.
“Those who have been accustomed to regard Geography as a merely descriptive
branch of learning, drier than the remainder biscuit after a voyage, will be dolighted
to find this hitherto unattractive pursuit converted into a science, the principles of
which ars definite and the results conclusive ; a science that embraces the investigae
tion of natural laws and interprets their mode of operation ; which professes to dis-
cover in the rudest forms and apparently confused arrangement of the materials com-
posing the planets’ crust, a new manifestation of the wisdom which has filled the
earth with its riches. * * * To the reader we shall owe no apology, if we have
said enough to excite his curiosity and to persuade him to look to the book itself for
further instruction.’’—JVorth American Review.
‘‘ The grand idea of the work is happily expressed by the author, where he calls it
the geographical march of history. * * * 'The man of science will hail it as a beauti-
ful generalization from the facts of observation. The Christian, who trusts in a mer
ciful Providence, will draw courage from it, and hope yet more earnestly for the
redemption of the most degraded portions of mankind. Faith, science, learning,
poetry, taste, in a word, genius, have liberally contributed to the production of the
work under review. Sometimes we feel as if we were studying a treatise on the
exact sciences ; at others, it strikes the ear like an epic poem. Now it reads like
history, and now it sounds like prophecy. It will find readers in whatever language
it may be published ; and in the elegant English dress which it has received from the
accomplished pen of the translator, it will not fail to interest, instruct and inspire.
We congratulate the lovers of history and of physical geography, as well as all
those who are interested in the growth and expansion of ourcommon education, that
Prof. Guyot contemplates the publication of a series of elementary works on Physical
Geography, in which these two great branches of study which God has so closely
joined together, will not, we trust, be put asunder.’’— Christian Exeminer.
** A copy of this volume reached us at too late an hour for an extended notice. The
work is one of high merit, exhibiting a wide range of knowledge, great research, and
a philosophical spirit of investigation. Its perusal will well repay the most learned
in such subjects, and give new views to all, of man’s relation to the globe he inhabits.” ~
Silliman’s Journal, July, 1849.
‘© These lectures form one of the most valuable contributions to geographical science
that has ever been published in this country. They invest the study of geography
with an interest which will, we doubt not, surprise and delight many. ‘They will
open an entire new world to most readers, and will be found an invaluable aid to the
teacher and student of geography.”’—Evening Traveller.
‘© We venture to pronounce this one of the most interesting and instructive” books
which have come from the American press for many a month. The science of which
it treats is comparatively‘of recent origin, but it is of great importance, not only on
account of its connections with other branches of knowledge, but for its bearing upon
many of the interests of society. In these lectures it is relieved of statistical details,
and presented only in its grandest features. It thus not only places before us most
instructive facts relating to the condition of the earth, but also awakens within us a
stronger sympathy with the beings that inhabit it, and a profounder reverence for the
beneficent Creator who formed it, and of whose character it is a manifestation and
expression. They abound with the richest interest and instruction to every intelli-
gem: reader, and especially fitted to awaken enthusiasm and delight in all who are
devoted .c the study either of natural science or the history of mankind.’’—Providence
fournal.
** Geography is here presented under a new and attractive phase ; it is no longer s
dry description of the features of the earth’s surface. The influence of soil scenery
and climate upon character, has not yet received the consideration due to it from his-
torians and philosophers. In the volume before us the profound investigations of Hum-
boldt, Ritter and others, in Physical Geography, are presented in a popular form, and
with the clearness and vivacity so characteristic of French treatises on science The
work should be introduced into our higher schools.””— The Independent, New York.
** Geography is here made to assume a dignity, not heretofore attached to 1t. The
knowledge communicated in these Lectures is c irious, unexpected, absorbing.”’?~—
Christian Mirror, Portland.
COMPARATIVE
PHYSICAL AND HISTORICAL GEOGRAPHY,
OR THE STUDY OF
THE EARTH AND ITS INHABITANTS.
A SERIES OF GRADUATED COURSES FOR THE USE OF SCHOOLS.
BY AEN OLD Gurwen
Late Professor of Physical Geography and History, at Neuchatei, Switzerland,
Auther of “ Larth and Man,” ete.
G., K. § L. are happy to announce that the above work, which has been undertaken
in compliance with the earnest solicitations of numerous teachers and friends of educaticn,
isin a forward state of preparation. The plan of the author, and the principal charac-
teristics of this series may be gathered from the following exposition of the subject :
A knowledge of the globe we inhabit, whether considered in itself alone, or in ita
relations to man, the distribution of the races of men, and the civil divisions of its sur-
face, are subjects of interest too varied, too direct, and too vital, not to command the
attention, and excite the sympathy of the mind atevery period of life.
If Geography has been considered a dry and often fruitless study,—if indeed, te
teach it with success has been considered as one of the most difficult problems in edw-
cation, there is reason to believe that the difficulty lies not in the subject but in ths
method of teaching it.
In most manuals the accumulation of facts, and especially the want of an arrange-
ment of them, really corresponding to their connection in nature, renders the study
difficult, and overburdens the memory at the expense of a true and thorough under-
standing of the subject. Ilence there is confusion and a want of clear and comprehen-
sive views, and consequently a lack of interest for the student. For, if the mind seeks
to comprehend, it is only interested in what appears clear and well connected. ‘To attain
to this end it is necessary—
First. To attempt a rigid selection of materials, and to reject from school instruc-
tion all details which have but a transient value, and, on the other hand, to render
facts of permanent value prominent; preferring, for instance, the details of Physical
Geography and of Ethnography, to those of Statistics, which may find a larger place
slsewhere,
Seconp. To distribute geographical instruction throughout the whole course of edu-
cation, so as to divide the labor of learning, and to give at the same time to each period
of life the nutriment most appropriate for its intellectual taste and capacity. To this
end, the globe should be studied from the different points of view successively ; gradu-
ating each view to the capacity of different classes of students. At first, the funda-
mental outlines, alone, should be presented, and next, not only additional facts, but a
deeper understanding of the connection, and so on; and thus, by a regular and natural
path, a full and intelligent knowledge of the globe in all its relations, will be finally
attained.
Tuirp. The comparative method, recently adopted with so much success in Europe,
should always be employed; for it is by the recognition of resemblances and differences
that the mind seizes upon the true characters, and perceives the natural relations, and
the admirable connection, of the different parts which form the grand whole; ina
word, gains real knowledge.
The series hereby announced is designed to meet these wants. It will consist of three
courses adapted to the capacity of three different ages and periods of study. ‘The first
is intended for primary schools, and for children of from seven to ten years. ‘he
second is adapted for higher schools, and for young persons of from ten to fifteen years.
The third is to be used as a scientific manual in Academies and Colleges.
Each course will be divided into two parts, one of purely Phy sical Geography, tha
ether for Ethnography, Statistics, Political and Historical Geography. Each part will
be illustrated by a colored Physical and Political Atlas, prepared expressly for this
purpose, delineating, with the greatest care, the configuration of the surface, and
the other physical phenomena alluded to in the corresponding work, the distributica
of the races of men, and the political divisions into States. Hach part with the corres-
ponding maps will be sold separately.
The two parts of the first, or preparatory course, are now ina forward state of pre.
paration, and will be issued at an early day.
Also, in prenaration, by the same Author,
A SERIES OF ELEGANTLY COLORED MURAL MAPS,
EXHIBITING
THE PHYSICAL PHENOMENA OF THE GLOBE,
PROJECTED ON A LARGE SCALE, FOR THE RECITATION ROCK.
CLASSICAL STUDIES
ESSAYS ON
ANCIENT LITERATURE AND ART.
With the Biography and Correspondence of Eminent Philologists.
By Barnas Sears, President of Newton Theol. Institution, B. B
EDWARDS, Prof. Andover Theol. Seminary, and C. C. FEtron,
Prof. Harvard University. 12mo. Price $1.25.
SECOND THOUSAND.
*‘ The collection is a most attractive one, and would be acceptable in any circum:
stances. The discourses, particularly those of Jacobs, are written in words that burn,
A general could not exhort his troops with more energy and spirit, than are used
by the German Professor in stimulating the youth before him to labor in the acqui-
sition of classical learning. ‘The biographical portions of the book, naturally fess
exciting, no less tend to the same end.’’—London Lit. Examiner, by John Forster, Esq
*¢ This elegant book is worthy of a more extended notice than our limits at present
will permit us to give it. Great labor and care have been bestowed upon its typo-
graphical execution, which does honor to the American press. It is one of the rare
beauties of the page, that not a word is divided at the end of a line. The mechanical
part of the work, however, is its least praise. It is unique in its character—standing
alone among the innumerable books of this book-making age. ‘The authors weii
deserve the thanks of the cultivated and disciplined portion of the community, for the
service which, by this publication, they have done to the cause of letters. The book
is of a high order, and worthy of the attentive perusal of every scholar. It isa nobla
monument to the taste, and judgment, and sound learning of the projectors, and will
yield, we doubt not, a rich harvest of fame to themselves, and of benefit to our
literature.”— Christian Review.
“Jt is refreshing, truly, to sit down with such a book as this. When the press ig
teeming with the hasty works of authors and publishers, it is a treat to take up a book
that is an honor, at ance, to the arts and the literature of our country.”—Wew York
Observer.
‘¢ This is truly an elegant volume, both in respect to its literary and its mechanical
execution. Its typographical appearance is an honor to the American press ; and with
equal truth it may be said, that the intrinsic character of the work is highly credit-
able to the age. It is a novel work, and may be called a plea for classical learning.
To scholars it must be a treat; and to students we heartily commend it.??—Bostor
Recorder.
‘¢ This volume is no common-place production. It is truly refreshing, wnen we are
ovliged, from week to week, to look through the mass of books which increases upon
eur table, many of which are extremely attenuated in thought and jejune in style, to
find something which carries us back to the pure and invigorating influence of the
master minds of antiquity. The gentlemen who have produced this volume deserve
the cordial thanks of the literary world.’”’—New England Puritan.
‘© We heartily welcome this book as admirably adapted to effect a most noble and
much desired result. We commend the work to general attention, for we feel sure it
must do much to awaken a zeal for classical studies, as the surest means of attaining
the refinement and graceful dignity which should mark the strength of every nation.”—
New York Tribune.
‘© We make no classical pretensions, or we might say more about the principal
articles in this volume ; but it needs no such pretensions to commend, as we heartily
do, a book so full of interest and instruction as the present, for every reader who is at
al] imbued with a love of literature.”,-—Salem Gazette.
“ This book will do good in our colleges. Every student will want a copy, and
many will be stimulated by its perusal to a more vigorous and enthusiastic pursuit of
that higher and more solid learning which alone deserves to be called ‘ classical.°
The recent tendencies have been to the neglect of this, and we rejoice in this timely
effort of minds so well qualified for such a work.??—Christian Reflector.
“The volume is, in every way, a beautiful affair of its kind, and we hazard nothing
is recommending it to the literary world? —Christian Secretary, Hartford.
** The-desi#ii is a noble and generous one, and has been executed with a taste and
¢4od sense, that do honor both to the writers and the publishers.””—Prov. Journas
CONTRIBUTIONS TO THEOLOGICAL SCIENCE.
BY JOHN HARRIS, D.D.
I. THE PRE-ADAMITE EARTH.
NOTICES OF THE PRESS.
*“ As we have examined every page of this work, and put forth our best efforts to un-
derstand the full import of its varied and rich details, the resistless impression has come
over our spirits, that the respected author has been assisted from on high in his labo-
rious, but successful undertaking. May it please God yet to aid and uphold him, to
complete his whole design ; for we can now see, if we mistake not, that there is great
unity as well as originality and beauty in the object which he is aiming to aecomplish.
If we do not greatly mistake, this long looked for volume, will create and sustain a
deep impression in the more intellectual circles of the religious world.”,— London Evan-
gelica! Magazine.
“The man who finds his element among great thoughts, and is not afraid to push
{nto the remoter regions of abstract truth, be he philosopher or theologian, or both,
will read it over and over, and will find his intellect quickened, as if from being in con-
tact with a new and glorious creation.’’—Albany Argus.
“Dr. Harris states in a lucid, succinct, ané often highly eloquent manner, all the
leading facts of geology, and their beautiful harmony with the teachings of Serip-
ture. As a work of paleontology in its relation to Seripture, it will be one of the most
complete and popular extant, It evinces great research, clear and rigid reasoning, and
a style more condensed and beautiful than is usually found in a work so profound.
It will be an invaluable contribution to Biblical Science.”’— New York Evangelist.
“He is a sound logician and lucid reasoner, getting nearer to the groundwork of a
subject generally supposed to have very uncertain data, than any other writer within
our knowledge.”— New York Com. Advertiser.
“The elements of things, the laws of organic nature, and those especially that lie at
tke foundation of the divine relations to man, are here dwelt upon in a masterly man-
uer.”’— Christian Reflector, Boston.
sagen le ail 98 Bl Shh (GR
OR THE CONSTITUTION AND PRIMITIVE CONDITION OF THE HUMAN BEING.
WITH A FINE PORTRAIT OF THE AUTHOR.
NOTICES OF THE PRESS.
“Jt surpasses in interest its predecessor. It is an able attempt to carry out the
author’s grand conception. His purpose is to unfold, as far as posstble, the saecessivs
steps by which God is accomplishing his purpose to manifest His All-sufficieney. * * *
The reader is led along a pathway, abounding with rich and valuable thought, going
on from the author's opening propositions to their complete demonstration. To stu-
dents of mental and moral science, it will be a valuable contribution, and will assuredly
secure their attention.””— Christian Chronicle, Philadelphia.
“It is eminently philosophical, and at the same time glowing and eloquent. It can-
not fail to have a wide circle of readers, or to repay richly the hours which are given
to its pages.”,— New York Recorder.
“The reputation of the author of this yolume is co-extensive with the English lan-
guage. The work before us manifests much learning and metaphysical acumen. Its
great recommendation is, its power to cause the reader to think and reflect.”,— Boston
Recorder.
“Reverently recognizing the Bible as the fountain and exponent of truth, he is as in-
dependent and fearless as he is original and forcible; and he adds to these qualities
consummate skill in argument and elegance of diction.”— WV. Y. Com Advertiser.
“His copious and beautiful illustrations of the successive laws of the Divine Mani-
festation, have yielded us inexpressible delight.”"-— London Eclectic Review.
“The distribution and arrangement of thought in this volume, are such as to afford
ample scope for the author’s remarkable powers of analysis and illustration. 11 look-
ing with a keen and searching eye at the principles which regulate the conduct of Gog
towards man, as the intelligent inhabitant of this lower world, Dr. Harris has laid down
for himself three distinct, but connected views of the Divine procedure: First, The End
aimed at by God; Second, the Reasons for the employment of it. In a very masterly
way does our author grapple with almost every difficulty, and perplexing subject which
eomes within the range of his proposed inquiry into the constitution and condition
a Man Primeval.”?—London Evangelical History.
ill, THE PASILY:
ITS CONS™ITUTION, PROBATION AND HISTORY
{IN PREPARATION.}
-
CHAMBERS’S
CYCLOPADIA OF ENGLISH LITERATURE,
4 8ZLECTION OF THE CHOICEST PRODUCTIONS OF ENGLISH AUTHORS, FROM THE
EARLIEST TO THE PRESENT TIME: CONNECTED BY A CRITICAL
AND BIOGRAPHICAL HISTORY.
EDITED BY ROBERT CHAMBERS.
ASSISTED BY ROBERT CARRUTHERS AND OTHER EMINENT GENTLEMEN,
Complete in two imperial octavo volumes, of more than fourteen
hundred pages of double column letterpress, and upwards of
three hundred elegant illustrations.
This valuable work has now become so generally known and appreciated, that there need
pearcely be any thing said in commendation, except to those who have not yet seen it.
The work embraces about One Thousand Authors, chronologically arranged and classed
«8 Poets, Historians, Dramatists, Philosophers, Metaphysicians, Divines, etc., with chowes
eesections from their writings, connected by a Biographical, Historical, and Critical Narra-
tive ; thus presenting a complete view of English Literature, from the earliest to the present
time, Let the reader open where he will, he cannot fail to find matter for profit and delight,
which, for the most part, too, repeated perusals will only serve to make him enjoy the more,
We have indeed infinite riches in a little room. No one, who has a taste for literature,
should allow himself, for a trifling consideration, to be without a work which throws se
much light upon the progress of the English language. The selections are gems— @ mase
of valuable information in a condensed and elegant form.
EXTRACTS FROM COMMENDATORY NOTICES.
From W. H. Prescott, Author of “‘ Ferdinand and [sabella.?? ‘*The plan of the work
is very judicious. * * It will put the reader in the proper point of view, for survey-
ing the whole ground over which he is travelling. * * Such readers cannot fail to
orunt largely by the labors of the critic who has the talent and taste to separate what
tz really beautiful and worthy of their study from what is superfluous.”?
*‘] concur in the foregoing opinion of Mr, Prescott.”” — Edward Everett.
‘¢ Tt will be a useful and popular work, indispensable to the library of a student of
English literature.’? — Francis Wayland.
‘* We hail with peculiar pleasure the appearance of this work, and more especially
Its republication in this country at a price which places it within the reach of a great
number of readers.’? — North American Review.
“ This is the most valuable and magnificent contribution to a sound popular Jitera-
ture that this century has bronght forth. It fills a place which was before a vlank.
Without it, English literature, to almest a/l of onr countrymen, educated or unedu-
rated, is an imperfect, broken, disjointed mass. Much that is beautiful—the most
perfect and graceful portions, undoubtedly — was already possessed ; but it was not
a whole. Every intelligent man, every inquiring mind, every scholar, felt that the
foundation was missing. Chambers’s Cyclopedia supplies this radical defect. It be-
gins with the beginning ; and, step by step, gives to every one who has the intellect or
taste to enjoy it a view of English literature in all its complete, beautiful, and perfect
proportions.” — Onondaga Democrat, N. Y.
‘We hope that teachers wil! avail themselves of an early opportunity to obtain @
work so well calculated to impart useful knowledge, with the pleasures and ornaments
of the English classics. The work will undoubtedly find a place in our district and
other public libraries; yet it should be the ‘vade mecum?’ of every scholar.’?—
Teachers’ Advocate, Syracuse, N. Y.
‘© The work is finely conceived to meet a popular want, is full of literary instruction,
vad is variously embellished with engravings illustrative of English antiquities, his
a and biography. Tke typography throughout is beautiful.’? — Christian Reflecter,
oston.
*¢ The design has been well executed by the selection and concentration of some of
the best productions of English intellect, from the earliest Anglo-Saxon writers down
to those of the present day. No one can give a glance at the work withcut being
truck with its beauty and cheapness.’? — Boston Courier. :
“© We should be glad if any thing we can say would favor this design. The elegance
of the execution feasts the eye with beauty, and the whole is suited to refine and ele
vate the taste. And we might ask, who can fail to go back to its beginning, and trace
his mothier-tongue from its rude infancy to its present maturity, elegance, and richness /”
Christian Mirror, Portland.
*.* The Publishers of the AMERICAN Edition of this valuable work desire to state that, besides the
wumerous pictorial illustrations ia the English Edition, they have greatly enriched the work by the addition
ef fine steel and mezzotint engravings of the heads of Shakspeare, Addison, Byron; a full iength portrelt
of Dr. Johnson, and a beautiful scenic representation of Oliver Goldsmith and Dr. Johnson. These impor
tant and elegant additious, together with superior paper and binding, must give this a decided nreferense
ever all other editions.
£FOR SCHOOL AND FAMILY LIBRARIES.
CHAMBERS’S MISCELLANY
OF USEFUL AND ENTERTAINING KNOWLEDGE,
TEN VOLUMES, ELEGANTLY ILLUSTRATED.
The design of the MisceLttany is to supply the increasing demand for useful,
instructive, and entertaining reading, and to bring all the aids of literature to bear
on the cultivation of the feelings and understanding of the people — to impress Correct
views on Important moral and social questions — to furnish an unobtrusive friend
end guide, a lively fireside companion, as far as that object can be attained through
the instrumentality of books.
This work is confidently commended to Teachers, School Committees, and
ell others interested in the formation of ‘‘ School Libraries,’’ as the very best work
for this purpose. Its wide range of subjects, presented in the most popular style,
makes it exceedingly interesting and instructive to all classes. The most flat-
tering testimonials from distinguished school teachers and others, expressing an
earnest desire to have it introduced into all school libraries, have been received by
the publishers.
From George B. Emerson, Esq., Chatrman of the Book Committee of the Boston Schools.
— ‘I have examined with a good deal of care ‘ Chambers’s Miscellany of Useful
and Entertaining Knowledge,’ particularly with reference to its suitableness to
form parts of a library for young persons. It is, indeed, a library in itself, and one
of great value, containing very choice selections in history, biography, natural
history, poetry, art, physiology, elegant fiction, and various departments of science,
made with great taste and judgment, and with the highest moral and philanthropie
purpose. It would be difficult to find any miscellany superior or even equal to it
it richly deserves the epithets ‘ useful and entertaining,’ and [ would recommend
it very strongly, as extremely well adapted to form parts of a library for the young,
or of a social or circulating library, in town or country.”’
From the Rev. John O. Choules, D. D.—‘‘I cannot resist the desire which I feel
to thank you for the valuable service which you have rendered to the public by
aa this admirable work within the reach of all who have a desire to obtain
nowledge. I am not acquainted with any similar collection in the English lan-
guage that can compare with it for purposes of instruction or amusement. J should
rejoice to see that set of books in every house in our country. I cannot think of
any method by which a father can more materially benefit his children than by
surrounding them with good books ; and if these charming and attractive volumes
can be placed in the hands of the young, they will have their tastes formed for good
reading. I shall labor to see the Miscellany circulated among my friends, and shall
lose no opportunity to commend it every where.”
‘¢ They contain an excellent selection of historical, scientific, and miscellaneous
articles in popular style, from the best writers of tho language. ‘The work is ele
gantly printed and neatly illustrated, and is sold very cheap.”? — Independent Dem-
ecrat, Concord, N. I.
“‘ It is just the book to take up at the @lose of a busy day; and especially will it
shod a new charm over autumn and winter in-door scenes.’’—Christ. World, Bostim,
‘* The information contained in this work is surprisingly great; and for the fire-
side, and the young particularly, it cannot fail to prove a most valuable and enter-
taining companion.” — Vew York Evangelist.
‘¢ We are glad to see an American issue of this publication, and especially in so
neat and convenienta form. It is an admirable compilation, distinguished by the
ood taste which has been shown in all the publications of the Messrs. Chambers.
t unites the useful and the entertaining.” —.Vew York Commercial Advertiser
“It is an admirable compilation, containing interesting memoirs and historicel
eketches, which are useful, instructive, and entertaining. Every head of a family
should supply himself with a copy for the benefit of his children.’? — Corning Journal.
‘ The enterprising publishers deserve the thanks of every lover of the beautiful
and true, for the cheap and tasteful style in which they have spread this truly val-
aable work before the American people.”? — People’s Advocate, Pa.
“‘ It is filled with subjects of interest, intended for the instruction of the youthful
mind, such as biography, history, anecdotes, natural philasopiy, && %— New
Orleans Bee mes
THE POPULAR
CYCLOPADIA OF BIBLICAL LITERATURE.
CONDENSED FROM THE LARGER WORK.
By JOHN BED TO. D. De
4UTHOR OF “HISTORY OF PALESTINE,” ‘* DAILY BIBLE ILLUSTRATIONS,” ETC.
ASSISTED BY NUMEROUS DISTINGUISHED SCHOLARS IN EUROPE AND AMERICA.
Octavo. 812pp. With more than Three Hundred Illustrations. Price, cloth, $3,00.
Tux Poruvar Brevicat Cyciopxp14 oF Literature is designed to furnish a Dictrion-
ARY OF THE Breve, embodying the products of the best and most recent researches in bib-
lical literature, in which the scholars of Europe and America have been engaged. The
work, the result of immense labor and research, and enriched by the contributions of writers
of distinguished eminence in the various departments of sacred literature, has been, by
universal consent, pronounced the best work of its Glass extant, and the one best suited to
the advanced knowledge of the present day in all the studies connected with theological
science.
This work, condensed by the author from his larger work in two volumes, is not only in-
tended for ministers and theological students, but is also particularly adapted to parents,
Sabbath-school teachers, and the great body of the religious public. It has been the author’s
aim to avoid imparting to the work any color of sectarian or denominational bias. On such
points of difference among Christians, the /istorical mode of treatment has been adopted,
and care has been taken to provide a fair account of the arguments which have seemed
most conclusive to the ablest advocates of the various opinions. The pictorial illustra-
tions — amount ng to more than three hundred — are of the very highest order of the art.
EXTRACTS FROM LETTERS.
From Rev. J. J. Carruthers, D. D., Pastor of Second Parish Cong. Church, Portland, Me.
By far the most valuable boon presented to the Christian public for many years. The
condensation of the work, at little more than a third of the price, is, what it professes to
be, a condensation, a reduction, not of ideas, but of words, without in the slightest degree
o scuring the meaning of the gifted authors.
.
From Rev. Daniel Sharp, D. D., Pastor of Third Baptist Church, Boston.
A most valuable, as it was a much needed, publication. Every minister ought to have a
copy of it on his study table. As a book of reference, shedding its collected light on almost
all scriptural subjects, and furnishing a brief, but clear and compendious history of the most
remarkable events and personages mentioned in the Bible, it cannot fail of being a great
help. Every lover of God’s word, not to say every Sabbath-school teacher, and every theo-
logical student, will find treasures of information in the above-named work.
From Rev. Joel Hawes, D. D., Pastor of First Congregational Church, Hartford, Ct.
_ Acapital work, containing a vast amount of information on a great variety of subjects,
in a very condensed, yet clear and interesting form. Every family and every Sabbath-schoo}
teacher, wishing to understand the Bibie, should possess this work.
From Rev W. B. Sprague, D. D., Pastor of Second Presbyterian Church, Albany, N. ¥.
I regard it as the most important auxiliary to the study of the Scriptures, among the great
mass of people, of which I have any knowledge. Every Sabbath-school teacher, and indeed
every Christian, who is able to do so, ought to possess himself of the work ; and the fact
that such a work is in existence, may well be regarded as one of the favorable signs of the
times in regard to the progress of evangelical knowledge.
From Rev. J. B. Waterbury, D. D., Pastor of Bowdoin St. ( Congregational) Church, Beston.
It is a most valuable book, suited to the wants of clergymen, and well adapted to aid
Sabbath-school teachers in their responsible work. Every family that can afford it, would
do well to possess themselves of so important and interesting a volume; to which they
might refer in elucidating the Scriptures, and rendering their study ne’ anly profitable but
delightful e
KITTO’S CYCLOPAZDIA OF BIBLICAL LITERATURE.
From Rev. E. N. Kirk, Pastor of Mount Vernon Congregational Church, Boston.
The work is invaluable to the student of the Bible. We have no other in this depast
ment to be compared with it, for condensing the results of modern researches or Oriental
antiquities and topography, which are so valuable in explaining the language of the Bible.
From Hon. Thomas §. Williams, Hartford, Ct.
A mass of information, in a condensed form, highly important to those who regard the
sacred vclume ; and to Sabbath-school teachers it will prove a most valuable assistant.
From Hon. Edward Everett, LL. D., Boston.
i have kept it on my table, and have frequently referred to it; and it has been a gocd deal
read by different members of my family. I unite with them in the opinion that it is a val-
uable work, well adapted for the above-named purpose. It appears to embody, in a popu-
lar form, the results of much research, and will promote, I doubt not, the intelligent read-
ing of the Scriptures.
From Hon. George N. Briggs, LL. D., Pittsfield, Mass.
To all who read and study the Bible it will be found to be a work of surpassing interest
and utility. In families and in the hands of Sabbath-school teachers, its value and impor-
tance can hardly be over-estimated. Its explanations of the habits, customs, and religious
rites of the Hebrews and the surrounding nations, are clear and important; and the light
which it throws upon the biography, geography, and history of the Old and New Testa-
ment develops in those inspired volumes new beauties, and inspires a higher admiration
for that Book of books, and a profounder reverence for its Divine Author. I wish there
Was a copy of it in every family in the land.
From Jared Sparks, LL. D., President of Harvard College.
I am glad to possess the work; and I enclose three dollars, which I understand to be the
price of it.
From Hon. Theodore Frelinghuysen, LL. D., New Brunswick, N. J.
I regard it as a very valuable help to the student of the Bible. It brings to the aid of the
reading community, in an instructive and condensed form, a rich treasure of historical and
biblical literature, prepared and arranged by some of the best minds, and which could
otherwise be gained only by a laborious and patient research, that very few have the lei-
sure to give to the subject. No family would, I think, ever regret the purchase of a book so
deserving of a household place.
From Hon. John McLean, LL. D., of Ohio.
It is only necessary to look through this volume to appreciate its value. There is no work
I have seen which contains so much biblical knowledge, alphabetically arranged under ap-
propriate heads, in so condensed a form, and which is sold so cheap. Under a leading
word is to be found in this book, whether it relate to natural science or scriptural illus-
tration, enough to satisfy every inquirer. Next to the Bible, this dictionary of it contains
more interesting knowledge than any work of the same size, and it should be found in every
family, in our public schools as well as in all our academies and colleges.
From Hon. Simon Greenleaf, LL. D.
A book that will prove highly useful to all persons engaged in the study of the Bible,
or in eens its sacred truths to the young. I hope, therefore, that it will be widely
circulated.
From Hon. Robert C. Winthrop, EL. D., Boston.
1 have examined with great pleasure your edition of Kitto’s Popular Cyclopedia of Bibli-
cal Literature. It seems to me a most convenient and valuable aid to the study of the
Scriptures, and I am glad that you have been able to publish it at so reasonable a price.
ft can hardly fail to commend itself to those who would teach, and to those who would
learn, something more than the mere letter of the inspired volume.
From Henry J. Ripley, D. D., Author of ‘* Notes on the Scriptures,” and Professor in Newton
Theological Institution.
It would be invaluable to Sabbath-school teachers, and of great utility to preachers. It
every where shows evidence of research, and is particular and accurate in its details. It
employs appropriate authorities, both less and more modern, as to questions of sacred
criticism, of history and geography, and gives the reader the results of recent learned in-
vestigations. If the purpose of this book is gained, scriptural knowledge will be increased.
Valuable School Books.
THE ELEMENTS OF MORAL SCIENCE. By Francia
Waysind, D.D. President of Brown University, and Professor of
Moral Philosephy. Fortieth Thousand. 12mo. cloth... Price $1.25.
*,* This work has been extensively and favorably reviewed and adopted as a class-book
in most of the collegiate, theological, and academical institutions of the country.
From Rev. Wilbur Fisk, President of the W-sleyan University,
“TI have examined it with great satisfaction and interest. The work was greatly neede
end is well executed. Dr. Wayland deserves the grateful acknowledgments and bed
patronage of the public. I need say nothing further to express my high estimate of the
work, than that we shall immediately adopt it as a text-book in our university.”
From Hon. James Kent, late Chancellor of New York.
“ The work has been read by me attentively and thoroughly, and I think very highly ef
it The author himself is one of the most estimable of men, and I do not know cf any
ethical treatise, in which our duties to God and to our fellow-men are laid down with mare
precision, simplicity, clearness, energy, and truth.”
“The work of Dr. Wayland has arisen gradually from the necessity of correcting the
false principles and fallacious reasonings of Paley. It is a radical mistake, in the edura-
tion of youth, to permit any book to be used by students as a text-book, which contains
erroneous doctrines, especially when these are fundamental, and tend to vitiate the whole
system of morals. We have been greatly pleased with the method which President Way-
land has adopted ; he goes back to the simplest and most fundamental principles; and, in
the statement of his views, he unites perspicuity with conciseness and precision. In alJ
the author’s leading fundamental principles we entirely concur.” — Biblical Repository.
“ This is a new work on morals, for academic use, and we welcome it with much satis-
faction. It is the result of several years’ reflection and experience in teaching, on the part
of its justly distinguished author ; and ifit is not perfectly what we could wish, yet, in the
most important respects, it supplies a want which has been extensively felt. It is, we
think, substantially sound in its fundamental principles; and being comprehensive and
elementary in its plan, and adapted to the purposes of instruction, it will be gladly adopted
by those who have for a long time been dissatisfied with the existing works of Paley.”
The Literary anit Theological Review.
MORAL SCIENCE, ABRIDGED, bythe Author, and adapted
to the use of Schools and Academies. Twenty-fifth Thousand. 18mo.
half cloth. Price 25 cents.
The more effectually to meet the desire expressed for a cheap edition, the present edition is issued
at the reduced price of 25 cents per copy, and it is hoped thereby to extend the benefit of moral in-
struction to all the youth of our land. Teachers and ali others engaged in the training of youth, are
invited to examine this work.
“Dr. Wayland has published an abridgment of his work, for the use of schools. Of
this step we can hardly speak too highly. It is more than time that the study of moral
philosophy should be introduced into all our institutions of education. We are happy to
gee the way so auspiciously opened for such an introduction. It has been not merel
abridged, but also xe-written. We cannot but regard the labor as well bestowed.” — North
American Review.
“We speak that we do know, when we express our high estimate of Dr. Wayland’s
ability in teaching Moral Philosophy, whether orally or by the book. Having listened te
his instructions, in this interesting department, we can attest how lofty are the prineiples,
how exact and severe the argumentation, how appropriate and strong the illustrations
which characterize his system and enforce it on the mind.” — The Christian Witness.
“ The work of which this volume is an abridgment, is well known as one of the best and
most complete works on Moral Philosophy extant. The author is well known as one of
the most profound scholars of the age. That the study of Moral Science, a science which
teaches goodness, should be a branch of education, not only in our colleges, but in oar
echools and academies, we believe will not be denied. e abridgment of this work
seems to us admirably calculated for the purpose,and we hope it will be extensively
applied to the purposes for “which it is intended.” — The Mercantile Journal.
“We hail the abridgment as admirably adapted to supply the deficiency which has lon,
been felt in common school education, —the study of moral obligation. Let the chil
eerty be taught the relations it sustains toman and to its Maker, the first acquainting it
weer the duties owed to society, the second with the duties owed to God,and who cas
yoreteil how many asad and disastrous overthrow of character will be prevented, and how
elevated and pure will be the sense of integrity and virtue?” — Evening Gasette,
Daluable School Books.
ELEMENTS OF POLITICAL ECONOMY. By Franers
WAYLAND, D.D., President of Brown University. Fifteenth ‘Thousand.
12mo. cloth. Price $1.25
“ His obiect has been to write a book, which any one who chooses may understand. He
has, therefore, labored to express the general principles in the plainest manner possible,
and to illustrate them by cases with which every person is familiar. It has been to the
author a source of regret, that the course of discussion in the following pages, has, unar
voidably, led him over ground which has frequently been the arena of political contro-
versy. In all such cases, he has endeavored to state what seemed to him to be truth,
without fear, favor, or affection. He is conscious to himself of no bias towards any party
whatever, and he thinks that he who will read the whole work, will be convinced thet he
hag been influenced by none.” — Extract from the Preface.
POLITICAL ECONOMY, ABRIDGED, by the Authcr, and
adanted to the use of Schools and Academies. Seventh Thousand.
18mo. half morocco. Price 50 cents.
*,* The success which has attended the abridgment of “The Elements of Mora}
&cience” has induced the author to prepare an abridgment of this work. In this case,
as in the other, the work has been wholly re-written, and an attempt has been made to
adapt it to the attainments of youth.
“The original work of the author, on Political Economy, has already been noticed on
our pages; and the present abridgment stands in no need of a recommendation from us.
We may be permitted, however, to say, that both the rising and risen generations are
deeply indebted to Dr. Wayland, for the skill and power he has rut forth to bring a highly
important subject distinctly before them, within such narrow limits. Though ‘abri¢ged
for the use of academies,’ it deserves to be introduced into every private family, and to be
studied by every man who has an interest in the wealth and prosperity of his country. It
is a subject little understood, even practically, by thousands, and still less understood
theoretically. It is to be hoped, this will form a class-book, and be faithfully studied in
our academies; and that it will find its way into every family library; not there to be
shut up unread, but to afford rich material for thought and discussion in the family
circle. It is fitted to enlarge the mind, to purify the judgment, to correct erroneous
popular impressions, and assist every man in forming opinions of public measures,
which will abide the test of time and experience.” — Boston Recorder.
“ An abridgment of this clear, common sense work, designed for the use of academies
is just published. We rejoice to see such treatises spreading among the people; and we
urge all who would be intelligent freemen, to read them.” — New York Transcript.
“We can say, with safety, that the topics are well selected and arranged; that the
author’s name is a guarantee for more than usual excelleuce. We wish it an extensive
circulation.” — New York Observer.
“Ttis well adapted to high schools, and embraces the soundest system of republican
political economy of any treatise extant.” — Daily Advocate.
THOUGHTS on the present Collegiate System in the United States.
By Franeois WAYLAND, D.D. Price 50 cents.
“ These Thoughts come from a source entitled to a very respectful attention ; and as the
author goes over the whole ground of collegiate education, criticising freely all the arrange«
ments in every department and in all their bearings, the book is very full of matter. 6
hope it will prove the beginning of a thorough discussion.”
PALEY’S NATURAL THEOLOGY. [Illustrated bv forty plates,
and Selections from the notes of Dr. Paxton, with additional Notes,
original and selected, for this edition; with a vocabulary of Scientifio
Terms. Edited by Joun Warez, M.D. 12mo. sheep. Price $1.25. |
“The work before us is one which deserves rather to be studied than merely read.
kndeed, without diligent attention and study, neither the excellences of it can be fully dis-
@overed nor its advantages realized. It is, therefore, gratifying to find it introduced, se a !
text-book, into the colleges and literary institutions of our country. The edition before ug |
fs superior to any we have seen, and, we believe, superior to any that has yet been pub-
lished.” — Spirit of the Pilgrims.
“Perhaps no one of our author’s works gives greater satisfaction to all classes of readers,
the young and the old, the ignorant and the enlightened. Indeed, we recollect no book in
which the arguments for the existence and attributes of the Supreme Being, to be drawn
from his works are exhibited in a manner more attractive and more convincing.”
Christian Haaminer
;
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