ACIDIC PRECIPITATION
IN ONTARIO STUDY

ANNUAL STATISTICS OF
CONCENTRATION AND DEPOSITION
DAILY PRECIPITATION AND

AIR MONITORING NETWORK
1987

MAY 1990

Environment
Environnement

Ontario = Jim Bradley, Minister/ministre

ACIDIC PRECIPITATION IN ONTARIO STUDY

ISSN 0824-88
ISSN 0830-1¢é

ANNUAL STATISTICS OF CONCENTRATION AND DEPOSITION

DAILY PRECIPITATION AND AIR MONITORING NETWORK

O87

Report prepared for:
Air Resources Branch
Ontario Ministry of the Environment

Report prepared by:
A.P.I.0.S. Coordination Office
Ontario Ministry of the Environment

MAY 1990

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RECYCLABLE

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Copyright: Queen's Printer for Ontario, 1990
This publication may be reproduced for non-commercial purposes

with appropriate attribution.

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ACKNOWLEDGEMENT

This report was prepared by Diane Green and Joe Lam of the APIOS
Atmospheric Deposition and Chemistry Program. However, the data
themselves are a product of the combined efforts of many
individuals. Collection of air filter samples was coordinated by
Bill Trayling (in Northeastern Region), Steve Elliott (in
Southeastern Region), Scott Kennedy (in Southwestern Region), Wim
Smits (in Northwestern Region) and J.P. Varto (in Central Region).

Sample handling was carried out by Sue Lampinen and Celine Audette.

Chemical analyses were performed at the Laboratory Services and
Applied Research Branch under the coordination of Frank Tomassini.

Data entry was performed by Diana Rhodes and co-ordination of data
entry and records management by Peter Maheras. Joe Lam provided
invaluable assistance with systems development. Data validation
and overall systems management was performed by Diane Green. All
enquiries regarding the reported data should be directed to Neville
Reid, Co-Ordinator, Atmospheric Deposition and Chemistry Program
(416) 326-1691.

PART I

PART II

PART III

PART IV

PART V

TABLE OF CONTENTS

INTRODUCTION
STATION DESCRIPTION AND LOCATION MAP

SUMMARY STATISTICS OF PRECIPITATION
CONCENTRATION BY STATION

Station Map Ref. No
Balsam Lake 06
Charleston Lake wal
Dawson 7,
Dorset 08
Fernberg 16
Longwoods 02
Melbourne 01
Nithgrove 07
North Easthope 03
Quetico Centre 14
Railton 10
Raven Lake 05
Sutton n/a
Wellesley 04
Wilmer 9A

SUMMARY STATISTICS OF PRECIPITATION
CONCENTRATION BY REGION

Central Region

Northwestern Region
Southeastern Region
Southwestern Region

Page
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SUMMARY STATISTICS OF WET DEPOSITION BY STATION

Station Map Ref. No.
Balsam Lake 06
Charleston Lake ikat
Dorset 08
Dawson Fy
Fernberg 16
Longwoods 02
Melbourne ol
Nithgrove 07
North Easthope 03
Quetico Centre 14
Railton 10
Raven Lake 05
Sutton n/a
Wellesley 04

Wilmer 9A

PART VI

PART VII
REGION

SUMMARY OF STATISTICS OF WET DEPOSITION BY REGION

PAGE
Central Region 36
Northwestern Region 37
Southeastern Region 38
Southwestern Region 39

SUMMARY STATISTICS OF AIR CONCENTRATION BY STATION,

Station Map Ref. No. PAGE
Charleston Lake, SE Reg. 1 41
Dorset, Central Reg. 08 42
Fernberg, NW Region 16 43
High Falls, NE Region 19 44

Longwoods, SW Region 02 45

PART I

INTRODUCTION

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INTRODUCTION

This report was prepared by Diane Green. The statistical summaries presented in this report pertains to
the 1987 analytical results obtained from Acidic Precipitation in Ontario Study (APIOS) daily precipitation
and air monitoring network. The relevant data can be obtained on request from the Air Resources Branch
of the Ministry. All available data are utilized in the calculations except results reported as being unreliable
(i.e. results are identified as unreasonable values by using the validation procedures; detailed description of
the validation procedures is available from the Ministry upon request) or approximate (i.e., inexact results
are reported due to laboratory difficulties, such as may be encountered in calibration, or when the sample
cannot be re-analyzed to confirm the reported values). In a very few cases, concentration levels exceeded
the upper limit of the range of the chemical analysis. Rather than using the upper limit, a decision was
made to exclude these values from the statistics generated in this report. If a reported vale is labelled as
<W, it is replaced by a "zero". W is the level which the analytical technique cannot distinguish from zero.
Prior to 1986, if a level was recorded less than the detection limit T, a value corresponding to one half the
detection limit is utilized for statistical calculations as reported in the statistical summaries. These values
are no longer halved. Note that T is normally about ten times W, and values above the T criterion are
considered to be precise and accurate. W corresponds to approximately one standard deviation of low level
duplicates of real samples.

The reported precipitation gauge depth (standard rain gauge or nipher shielded snow gauge) is utilized in
the calculation of deposition. If a rain gauge value is not available then the collection sample volume is
converted to its equivalent precipitation depth and is used in the deposition calculation.

In the air concentration statistical summaries, "Nitric" represents "Nitric Acid” and "Total NO," represents
lotal nitrates calculated by the summation of particulate "Nitrate" and "Nitric Acid". The air filter
measurement for sulphur dioxide includes a contribution from filter measurement for sulphur dioxide
includes a contribution from nylon-filter impregnated SO, In these reports the sulphur on nylon filter is
interpreted as sulphur dioxide. However, it is possible that organic sulphur compounds also contribute to
this loading. Methods do not currently exist to quantify this contribution in routine network operation.

The statistical summaries presented in Parts III to VII include the number of samples, mean
(arithmetic/geometric), standard deviation (arithmetic/geometnic), maximum, minimum and quartiles and
volume weighted means using precipitation gauge depths where appropriate.

PART II

STATION DESCRIPTION AND LOCATION MAP

LEGEND

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Graham Lake _.
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PART VI

SUMMARY STATISTICS OF WET DEPOSITION BY REGION

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SUMMARY STATISTICS OF AIR CONCENTRATION BY STATION, REGION

— >

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