3'.3>

Issued January 17, 19H.

HAWAII AGRICULTURAL EXPERIMENT STATION,

E. V. WILCOX, Special Agent in Charge.

Bulletin No. 31.

RICE SOILS. OF HAWAII

THEIR FERTILIZATION AND MANAGEMENT.

BY

W. P. KELLEY,

CHEMIST.

UNDER THE SUPERVISION OF'"*— ^_ OFFICE OF EXPERIMENT STATIONS,

U. 8. DEPARTMENT OF AGRICULTURE.

ORY

s^spr

WASHINGTON:

GOVERNMENT PRINTING OFFICE.

1914.

HAWAII AGRICULTURAL EXPERIMENT STATION, HONOLULU.

[Under the supervision of A. C. True, Director cf the Office of Experiment Sta- tions, United States Department of Agriculture.]

Walter H. Evans, Chief of Division of Insular Stations, Office of Experiment

Stations.

STATION STAFF.

E. V. Wilcox, Special Agent in Charge, J. Edgar Higgins, Horticulturist. W. P. Kelley, Chemist.

C. K. McClelland, Agronomist.

D. T. Fullaway, Entomologist.

W. T. McGeorge, Assistant Chemist. Alice R. Thompson, Assistant Chemist, C. J. Hunn, Assistant Horticulturist. V. S. Holt, Assistant in Horticulture, C. A. Sahr, Assistant in Agronomy,

I8SU .7. 1914.

HAWAII AGRICULTURAL EXPERIMENT STATION,

E. V. WILCOX, Special Agent in Charge.

Bulletin No. 31.

RICE SOILS OF HAWAII

THEIR FERTILIZATION AND MANAGEMENT.

BY

W. P. KELLET

5 CHEMIST.

UNDER THE SUPERVISION' OF

OFFICE OF EXPERIMENT STATIONS,

U. B. DEPARTMENT OF AGRICULTURE.

WASHINGTON: GOVERNMENT PRINTING OFFICE.

1014.

LETTER OF TRANSMITTAL

Honolulu, Hawaii, October 1, 1913. Sir: I have the honor to submit herewith and recommend for publication, as Bulletin No. 31 of the Hawaii Agricultural Experiment Station, a paper on Rice Soils of Hawaii : Their Fertilization and Management, by W. P. Kelley, chemist. The experiments on rice as carried out by this station indicate quite conclusively that for the most successful production of rice all conditions which tend toward nitrification should be avoided. The application of nitrates has been found to be of little or no avail, and sometimes even positively injurious, while the use of ammonium sulphate brings about greatly increased yields. In harmony with this finding is the evidence that conditions which allow nitrification to take place in rice soils result in a diminished yield of rice. It appears, therefore, that ammonium sulphate should be the form of commercial nitrogen to apply to rice and that rice soils should not be aerated between crops. These results are probably applicable to other regions than the rice lands of Hawaii. Respectfully,

E. V. Wilcox,

Special Agent in Charge. Dr. A. C. True,

Director Office of Experiment Stations,

U. S. Department of Agriculture, Washington, D. C.

Publication recommended. A. C. True, Director,

Publication authorized. D. F. Houston,

Secretary of Agriculture,

CONTENTS

Page.

Introduction 5

Origin or rice soils 0

Mechanical composition ' . 6

Chemical composition 8

Fertilizer experiments 10

The form of nitrogen for rice 17

Ammonification and nitrification in rice soils 20

The management of rice soils 22

Summary 24

(2)

RICE SOILS OF HAWAII: THEIR FERTILIZATION AND MANAGEMENT.

INTRODUCTION.

The extensive soil investigations that have been made up to the present time have dealt principally with dry lands, in which the moisture and other conditions differ greatly from those prevailing in rice soils. In America in particular very little study has been devoted to submerged lands, and little, indeed, is really known about them. Consequently recommendations for the treatment and management of rice soils are generally based on knowledge gained from experience with dry lands. It is evident, however, that conclusions applicable to dry soils do not necessarily apply to submerged soils such as are used in rice culture, and, in fact, it is well known in oriental countries that rice lands demand different treatment from those devoted to dry-land cultures.

The one condition that is most obviously different in rice soils and dry lands is that of aeration. The fact that aeration is essential to the successful growth" of most crops, and the belief that fertility is in some way dependent upon its maintenance, has caused agriculturists to recommend for rice soils practices designed to secure aeration in the belief that this is as essential for successful rice culture as for culture of other crops. Experiments are not wanting, however, which show this to be untrue.

One of the most important matters affecting the culture of rice is the form in which nitrogen is taken up by the crop. It is well known that the degree of aeration in soils determines very largely the form assumed by available nitrogen. This phase of the subject has been reported upon previous!}7 by the writer,1 but will be further empha- sized in this bulletin on account of the principle involved and the practical importance attached to it.

In connection with the general soil investigations, which have been under way in the laboratory of the Hawaii station for several years, the rice lands of the Hawaiian Islands have received considerable attention. For a Dumber of years also ii<'l<l experiments with different

i Hawaii Sta. Bui. 24. (3)

fertilizers for rice have been conducted by the station. The subject has been approached from a number of standpoints, both practical and scientific, and it is believed the results are of sufficient interest and value to warrant publication at this time.

ORIGIN OF RICE SOILS.

The rice soils of Hawaii are located at or near sea level along the coast and are not extensive in area, amounting to about 10,000 acres, and during recent years the tendency has been to plant other crops on some of the lands hitherto devoted to rice because of low yields, labor difficulties, etc. The extent of the industry, therefore, is on the decline. The soils have their primary origin in basaltic lavas, just as is the case with all the soils of the islands, but in addition they frequently contain varying amounts of coral lime (CaC03), which has become thoroughly mixed with the lava residues. Whether or not the coral is visible on the surface, in practically all cases the rice lands are underlain at various depths with deep beds of coral lime- stone. Notwithstanding the fact that the lavas are typical basalts, the chemical and physical properties vary enormously; moreover, the rates of disintegration and the composition of the residuum differ greatly from place to place. Therefore the soils coining from lavas of essentially the same type may be very different in composition and properties. The .low lands in and around Honolulu, for instance, having been derived from the disintegration of volcanic cinder, typical black sands, are widely different from the rice lands on the leeward side of Oahu, both in chemical and physical properties. This is especially noticeable in the relative percentages of lime and magnesia.

In most instances the rice soils are strictly alluvial, although on account of the close proximity of the mountains there has been but a limited transportation of the soil materials. The soils in places contain a high percentage of organic matter.

In certain localities, as, for instance, the Hanalei Valley, on Kauai, the soils contain high percentages of clay and are of a close texture. The rice lands around Honolulu, on the other hand, contain quantities of sand and gravel unusual for Hawaiian soils, and as a consequence are open and porous. Samples of soil from all the important rice sec- tions have been examined.

MECHANICAL COMPOSITION.

In view of its bearing on irrigation, etc., the mechanical composi- tion as shown by physical analysis has been determined and is re- corded in the following on page 5.

Physical analyses of rice soils.

District.

Fine gravel,

2 1 nun.

Coarse

saint. 1 0.2 nun.

Fine sand

0.2 0.04

mm.

Silt. 0.04-0.01

nun.

Fine silt .

0.01-0.002

nun.

Clay, 0.002 mm.

Or less.

Organic

matter

and

combined

water

Waikiki:

Soil 298

Ptr c< n(. 20.91 18.61

1.15

1.02 . 82

.35 .33 .13

.06

.05 .22

.15 .46

.41 .22

1'ti cent. 18.75 18.30

1.61 1.28 1.63

.69 .86 .22 .31

.19

.11

3.09 3.59

.83

. 64

Per cent. 22.04

22. 74

18.34 20. 63 15.33

18.78 18.60 18.13 16.75

16.03 15.29

25.94

34.44

21.49 11.29

Pi r a nt. 8.69 8.10

16.28

17. sS 15.77

13.57 15.97 20.42 19.27

30.79 28.94

20.97 19.30

27.45 15.27

12. 11

13. 18

23.88 22.11

21.73

22.92 21.97 22.37

23. 42

14.64 20.67

15.96 10.96

7.61 20.07

Per cait.

7.23 9.52

25.39 24.06 31.61

25.70 23. 97 19.19 22.98

20.16 21.73

19.84 14.29

6.38 6.19

Per'cerU.

s.71

Subsoil 293

10.77

Fort Shatter:

Soil 332.

14.37

Subsoil 333

14.t).'.

Soil 334

15.23

Kailua:

Soil 337

18.72

Subsoil 338. ...

19.54

Soil 339

21.17

Subsoil 340

19.41

Kaneoho:

Soil 343

15.44

Subsoil 344

13.20

Waiaholo:

Soil 345

15.04

Subsoil 34f>

15.31

Kalaunui:

Soil 347

36.14

Subsoil 34S

49.24

The above data show that the rice soils of Oahu. with the ex- ception of those from the Waikiki and Kalaunui districts, are very similar in mechanical composition, and are made up of approxi- mately equal quantities of fine sand, silt, fine silt, and clay. The Waikiki soils, on the other hand, contain relatively small amounts of clay, with correspondingly larger amounts of the coarser grained particles. None of tHe soils except from this district contains any material coarser than fine gravel, while that from Waikiki contains several per cent of stones, etc. This point is of importance because of its bearing on tillage and drainage: The soils from Kalaunui, on the other hand, are very highly organic, and in places this land is peaty to a considerable degree. The organic matter of this soil, how- ever, retards the passage of water through it, with the result tr^at the amounts of water used in its irrigation are practically normal for the islands.

In the main these soils are to be classified as clay loams with a rather high organic content. The irrigation of all these soils requires relatively large amounts of water on account of their porous nature.

In considering the mechanical composition cf Hawaiian soils it should be especially borne in mind that the terms clay, fine silt, etc., have reference only to the size of the particles, and that these art- made up of different chemical substances from those that go to make up clay in most continental soils. Furthermore, the prop- erties of so-called clay in Hawaiian -oils differ from the properties of other flay-. It i- not composed primarily of kaolin, but is made up of ferric and aluminum hydrates, together with double silicates of iron and aluminum and perhaps some aluminum silicate. In

addition the coarser particles are in the main merely lava fragments on their way toward more complete disintegration. These frequently show under the microscope the characteristic structure of lava. As time goes on the relative proportions of these constituents will change, so that eventually a higher percentage of clay and fine silt will predominate. The upland soils at the present time frequently contain practically no material coarser than silt, with abnormally large quantities of clay. The soils are typical laterites,1 and in interpreting the analytical results reported herein it is important to bear this in mind.

CHEMICAL COMPOSITION.

The chemical composition of these soils, as determined by the use of the official methods, is shown in the following table:

Chemical composition of rice soils.

District.

Insoluble

Potash

Soda

Lime

Magnesia (MgO).

matter.

(KsO).

(Na20).

(CaO).

Per cent.

Per cent.

Per cent.

Per cent.

Per cent.

41.69

0.42

1.47

1.99

9.42

38.82

.47

1.36

2.48

9.75

44.57

.25

.46

.97

.94

45.75

.26

.36

.87

.58

44.94

.27

.34

.81

.99

40.53

.26

.45

.76

.82

42. 60

.16

.46

.59

.49

37.20

.14

.44

.43

.26

38.20

.06

.37

.47

.31

50.10

.10

.36

1.22

.87

51.15

.15

.38

1.65

.73

50.52

.09

.24

1.20

1.08

48.30

.08

.28

1.63

1.54

37. 82

.12

.31

2.20

.79

27.70

.09

.32

2.76

.78

42.40

.16

.10

1.16

2.67

40.40

.27

.10

.97

3.35

47.25

.19

.41

1.18

2.28

47.00

.17

.34

.97

6.98

45.18

.15

.42

1.26

1.72

45. 70

.14

.45

1.38

2.65

45.35

.15

. 29

.96

4.16

43.30

.17

.34

1.16

3.07

Manga- nese oxid (Mn304).

Ferric

oxid

(F203).

OAHU.

Waikiki:

Soil 292

Subsoil 293

Fort Shafter:

Soil 332

Subsoil 333

Soil 334

Kailua:

Soil 337

Subsoil 338

Soil 339

Subsoil 340

Kaneohe:

Soil 343

Subsoil 344

Waiahole:

Soil 345

Subsoil 346

Kalaunui:

Soil 347

SubSbil348....

KAUAI

Hanalei Valley:

Soil 460

Soil 461

Soil 462

Soil 463

Soil 464

Soil 465

Soil 466

Soil 407

Per cent.

0.27

.21

.32 .30 .13

.09

.27

.32 .35

.09 1.16 .02 .04 .14 .23 .15 .13

Per cent. 18.01 21.22

18.84 18.48 17.56

19.01 19.67 24.80 26.15

11.20 10.50

17.25 16.18

7.05 6.44

16.22 17.10 14.82

18.20 15. 32 15.23 18.16 15.91

1 The decomposition of basaltic lavas usually gives rise to soils high in iron and aluminum and relatively low in silica, and while the most finely divided particles are usually referred to as clay, the name is improperly applied. Recently Ulpiani (Staz. Sper. Agr. Ital., 45 (1912) pp. 629-653) suggested that this process be called lateritization in contradistinction to kaolinization, which takes place in the decomposition of orthoclase feldspars.

Chemical composition of rice soils Continued.

District.

Alumina

(AlsO,).

Phos-

phorio

acid

(PsO»).

Sulphur trioxid (SO,).

Titanic dioxid (TiO,).

Los-; on ignition.

OAHU.

:ki: Sail 292

Per cent. 14.10 13.09

17.10 17.42

19.35

14.94 14.50

12. :.'

12. 45

20. 35 20.90

14.92 15. 30

14.40 12.42

20. 15 20.10 19.12 13.60 20.30 19.95 16.95 20.35

Percent.

o. as

.71

.32 .26 .45

.76 .68 .29 .22

.20 .23

.21 .23

.19 .13

.44 .52 .53 .35 .51 . 72 .31 .56

Percent.

0.0S

.11

.03 .10 .23

.26 .26 .20 .20

.04 .04

.20 .13

.31 .80

.27 .28 .35 .30 .28 .31 .26 .21

Per cent. 2.17 2.64

2.26 2. 17

1 . 53

2. 43 2. 1 : 2. 92 2.81

2.24

2. 37

1.64 1.60

2.28 1.90

2.78

3.00 2.67 2.06 2.93

2.27 2.57 2.70

Percent 9.10 9. 92

13.96 13.58 13.70

18.63 18.43 21.10 18.41

13.85

12. 30

13. 22 14.70

34.52 46.70

14.15 14.35

12. 25 10.42

12. 95 11.27 11.80

13. 35

Per cent. 100. 78

100.02

100. 13 100.32

98.94 100.24 100.58

99.76

100.94 100.92

100.99 100.42

100.31 100.39

100.59 101.60 101.07

100. 43 101.17 100.30 101.10

101. 35

Ptr cent.

(>. HI

Subsoil 293

.16

Fort Shaffer:

- : m

. It;

-oil 333

. 13

Soil 334

Kailua:

. 23

.44

Subsoil 33S

. 42

Soil 339

.41

Subsoil 340

.30

Kaneohe:

Soil 313

.20

Subsoil 344

. 17

Waiahole:

Soil 345

.21

Sub-oil 346

.20

Kalaunui:

Soil 347

1.24

Subsoil 348

1.44

KAUAI.

Hanalei Vallev:

Soil 460..."

.26

Soil 461

.24

Soil 462

.20

Soil 463

. Is

Soil 464

.20

Soil 465

.15

Soil 466

.17

Soil 467

.17

It will at once be seen that these soils differ from normal soils not only in physical properties but also in chemical composition.

The lavas from which these soils have been derived are made up primarily of pyroxenes or amphiboles and soda-lime feldspars, and therefore are characteristically basic. In the disintegration process solution and oxidation play the most important part-, with the result that the soils formed contain iron and aluminum in great quantities, while the potash, soda, lime, and magnesia are largely leached out as silicates. In a few instances the rice soils, however, contain relatively large amounts of lime and magnesia, due partly to admix- tures with coral limestone and in part to the type of lava from which they were derived. It is also noteworthy that the ratio of lime to magnesia in these soils is abnormal, the latter sometimes being pres- ent in great excess above the former. In view of the interest now taken in the lime-magnesia ratio the relations of these tw< elements are of special interest, particularly since rice has been extensively studied in connection with this ratio.

The potash content is rather low, while phosphoric acid us generally present in large amounts. From a superficial examination of these analyses it would seem that potash fertilization is needed. It will be shown in connection with the fertilizatic n studies, however, that there

8

is no need for potash fertilizer. The decomposition of the lava frag- ments is greatly increased by the products arising from the decay of organic matter under the prevailing anaerobic conditions, with the result that potash is rendered soluble at a rate sufficient to supply the needs of rice, but the limited supply of potash present, together with the fact that large amounts of potash are taken up by rice, will sooner or later necessitate the use of potash-bearing fertilizer.

FERTILIZER EXPERIMENTS.

Some fertilizer experiments with rice have already been published by this station.1 The results were such as to emphasize the need for a more systematic study of this question, and in view of the fact that the yields obtained by the rice growers throughout the islands are frequently unprofitable, a series of fertilizer tests were instituted on the rice trial grounds of the station in the spring of 1909. These ex- periments were continued on the same plats throughout seven con- secutive crops. In Hawaii little or no rotation of crops is practiced, and two crops of rice are grown on the same land each year.

The soil on which these experiments were made had been previ- ously devoted to rice culture and was known to be quite uniform in productivity. After the plats had been laid out. however, an addi- tional crop, without fertilization, was grown for the purpose of determining more definitely their uniformity. The results showed the plats to be extremely uniform throughout, practically the same yield having been obtained from each. The plats were separated by low dikes so constructed as to prevent the lateral movement of fer- tilizers and irrigation was adjusted so as to insure a constant water supply of about 2 inches in depth above the surface of the soil.

After harvesting the first crop the original plats were divided into two equal portions, which here are to be designated as series A and B. The former were fertilized previous to the time of transplanting the spring crop only, while the latter received the same applications in like quantities to both the spring and fall crops. Previous experience had suggested that nitrogen would prove to be the most needed ele- ment, and this was borne out by the results obtained later. The yields obtained, fertilizers applied, etc.. are recorded in the tables, using the following values in calculating the cost of fertilizers, profits, etc. : Ammonium sulphate, $80 per ton; superphosphate, $20 per ton: potassium sulphate, $55 per ton; paddy, $0,025 per pound. In calcu- lating the profit'or loss, the extra expense incurred from the increased labor attached to making the application of fertilizers, harvesting, and marketing the increased yields, etc., was not included.

1 Hawaii Sta. ttpts. 1907 and 1908.

9

Results of applying fertiliser* to spting crop only. 1909— SERIEi A.

Plat.

rertUUer.

10

None

Superphosphate, 225 pounds: Potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate,

225 pounds

: None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

Yield per acre.

Spring crop.

Straw.

Lbs. 1,300

1,641 1,722

2,112 1,267

,950

2,762 2,405

1,950 1,379

Fall crop.

Paddy

Lbs. 1,462

1,625 2,007

2,128 1,543

2,242

2,957

2,730

2,285 1,528

Straw.

Lbs. 1,950

2,242

2,667

2,275 2,275

2,925

2,250

2,307

2,502 2,372

Paddy

Lbs. U.950

3,250 2,632

3,217 3,347

3,347

3,152 3,315

3,867 3,315

ln-

( oat

Total crease 0.f.ft"r

yield per an- num.

I.te. Lbs

in paddy per an- num.

tilizer.

8,758 9,028

9,732 8,432

10,464

11, 121

10,757

10,604 8,594

9

0

479

723

1,243 1,179 1,286

Profit (+)or

loss (-)per an- num.

$5.55 9.30 S.25

I -15.33

- 9.30

j + 3.72

11.55

23.10 12.00 6.00

+ 6.52

+ 7.96

+ 17.47 +26.15

1910— SERIES A.

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium sul- phate, 240 pounds

Ammonium sulphate, 3U0 pounds

Ammonium sulphate, 150 pounds

None

1,657

1,527

1,560

1,690

1,722

1,852

1,950

1,722

1,560

1,982 1,690

2,047

1,820

1,917

2,307

2,470

3,055

2,827

3,347

2,250 1,625

2,502 1,397

1,755

1,852

1,885 1,495

11,202 ' 5,946 2,015 ; 7,279

1,862 '. 7,0S4

2,080 ' 7,929 2,177 7,507

2,307 8,286

2,210 9,555

2,405 10.431

2,535 ! 9,172 1,300

IS.

11.55

1,203

1,690

975

-$5.55

- 9.30

- 6.63

+ 2.25

+ 6.97 +30.35

12.

6.00 I +18.37

i Injured by cold water flowing directly onto plat. Not included in averages. 16845°— 14 2

10

Result 8 of applying fertilizers to spring crop only Continued.

1911— SERIES A.

Plat.

Fertilizer.

Yield per acre.

Spring crop.

Straw.

Paddy

Fall crop.

Straw.

Paddy

Total yield per an- num.

In- crease

in paddy per an- num.

Cost of fer- tilizer.

Profit

(+)0T

loss (-)per

an- num.

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

Lbs. 1,430

1,267 1,852

1,917 1,202

2,147

3,085 2,957

2,535 1,560

Lbs. 1,332

1,527 2,112

2,372 1,365

2,470

3,510

3,380

2,730 1,690

Lbs. 1,300

1,300 1,202

1,202 1,267

1,267

1,300

1,527

1,657 1,397

Lbs. 1,592

1,690 1,527

1,625 1.690

1,755

2,080

2,242 1,755

Lbs. 5,654

5,784 6,693

7,116 5,524

7,574

9,650

9,944

9,164 6,402

Lbs.

76

856

1,019

2,124 2,319 1,831

$5.55 9.30 8.25

11.55

23.10 12.00 6.00

-$3.65 + 3.15 +13.15

+ 13.92

+30.00 +45.97 +39.77

1912— SERIES A.

10

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds ,

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds: potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

1,430 1,490 2,345

2,795 1,430

2,470

3,705 4,420

3,315

1,885

l 1, 495 1,690 2,567

2,66.5 1,852

2,405

3,445

4,095

3,315 2,145

2,925 3,180 4,912

5,460 3,282

4,875

7,150

8,515

6,630 4,030

0 569 667

407

1,447 2,097 1,317

$5.55 9.30 8.25

11.55

23.10 12.00 6.00

-$5.55 4.92

8.42

- 1.38

13.07 40.42 26.92

i Injured by cold water flowing directly onto plat. Not included in averages.

11

Kexults of applying fertilizers to both spring and fall crops,

1909— SERIES B.

Plat.

Fertilizer.

Yield per acre.

Spring crop.

Straw. Paddy. Straw. Paddy

Fall crop.

In-

crease

Total ! paddv yield per aii- per an- num num.

Cost of fer- tilizer.

Profit

( + )or

loss

(-)per

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

Lbs. 1,300

1,041 1,722

2,112 1,267

1,950

2,762

2,405

1,950 1,379

Lbs. 1,402

1,625 2,007

2,128 1,543

2,242

2,957

2,730

2,285 1,528

Lbs. 2,242

2,450 2,450

3,185 2,340

3,770

3,542

3,575

3,250 2.210

Lbs. 2,015

3,2S2

3,867

4,582 3,575

4,582

6,070

5,200

4,940 3,055

Lbs. 7,019

8,998 10,046

12,007 8,725

12,544

14,331 13,910

12,425 8,172

Lbs.

57 1,024

$11.10 18.60

1,850 16.50

1,974

3,177 3,080 2,375

23.10

46.20 24.00 12.00

-$9. 68 + 7.00 +30.00

+26.25

+33.22 +53.00 +47.37

1910-SERIES B.

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium, sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

1,722 1,755 2,632

2,405 1.755

2,307

3,055

3,185

2,470 1,722

U,495 1,430 2,860

2,860 2,080

2,892

3,705 3,900

2,827 U,690

1,560 2,145 2,405

2,470 2,145

2,665

3,250

3,055

2,967 1,495

il,495 2,470 3,055

3,445 2,702

3,835

4,267

4,322

3,867 12,015

6,272 7,800 10,952

11,180 8,742

11,699

14,277

14, 402

12, 131 6,922

0 1,073 1,463

1,885

3,130 3,380 1,852

$11. 10 18.60 16.50

23.10

46.20 24.00 12.00

-$11.10 + 8.22

+ 20.07

+ 24.02

+ 32.05 + 60.50 + 34.30

1 Injured by cold water flowing directly onto plat. Not included in averages.

12

Results of applying fertilizers to both spring and fall crops Continued.

1911— 6ERIES B.

Plat

Fertilizer.

Yield per acre.

Spring crop.

Straw.

Paddy,

Fall crop.

Straw.

Paddy.

Total yield per an- num.

In- crease

in paddy per an- num.

Cost of fer- tilizer.

Profit (+)or loss (-)per an- num.

10

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds _

None

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds; potassium sul- phate, 120 pounds

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds: potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds ,

Ammonium sulphate, 150 pounds

None ,.

Lbs.

1,625

1,307 2,307

2,502 1,332

2,600

3,835

3,900

2,535 1,430

Lbs. 1910

1,397 2,502

2,600 1,627

* 055

4,485

4,420

3,152 1,820

Lbs. 1,755

1,787

2,242

2,405 1,675

2,600

3,347

3,185

2,665 1,365

Lbs.

12,535

2,470 3,022

3,445 2, 437

3,737

4,647

4,615

3,900 1,917

Lbs. 6, 825

7,051 10,073

10.952 6,953

11,992

16,314

16, 120

12,252 6,532

Lbs.

15

1,672 2,193

2,940

5,280 5,183 3,200

511.10 18.60 16.50

-$10.73 + 23.20 + 38.32

23.10

46.20 24.00 12.00

+ 50.40

+ 85.80 +105.57 + 68.00

1912— SERIES B.

1

None

1,430

1,495

2,730

3,055 1,560

3>120

5,330

4,680

4,877 Lo«t.

1,755

1,885

2,665

2,990 2,047

2,925

4,322

4,095

3,120 2,145

3,185

3,380

5,495

6,045 3,607

6,045

9,652 8,775 7,995

2

Superphosphate, 225 pounds; potassium sulphate, 120

0

683

1,008

$5.55 9.30 8.25

-45.55

3

Ammonium sulphate, 150 pounds: potassium sul- phate, 120 pounds

7.77

4

Ammonium sulphate, 150 pounds; superphosphate, 225 pounds

16.95

5

None

6

Ammonium sulphate, 150 pounds- superphosphate, 225 pounds; potassium sul- phate, 120 pounds

........

943

2,340 2,113 1,138

11.55

23.10 12.00 6.00

12.02

7

Ammonium sulphate, 300 pounds; superphosphate, 450 pounds; potassium sul- phate, 240 pounds

Ammonium sulphate, 300 pounds

35.40

8

40.82

9

Ammonium sulphate, 150 pounds ....

22.45

10

None

Injured by cold water flowing directly onto plat. Not included in averages.

13

Summary of the results of applying fertilizer* to seven crops of rice.

Plat.

Fertilizer per crop.

None

Superphosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; potas- sium sulphate, 120 pounds

Ammonium sulphate, 150 pounds; super- phosphate, 225 pounds

None

Ammonium sulphate, 150 pounds; super- phosphate, 225 pounds; potassium sulphate, 120 pounds

Ammonium sulphate, 300 pounds; super- phosphate, 450 pounds; potassium sulphate, 240 pounds

Ammonium sulphate, 300 pounds

Ammonium sulphate, 150 pounds

None

Series A— one application annually.

Paddy.

Total.

Pounds. 110,560

13,519

14,419

16,134 13,857

16, 668

20,084 21,352

19,476 13,130

In-

Pounds

26

2,641

3,175

6,591 7,859 5,983

Total cost of fertili- zer.

§22.20

37.20

33.00

46.20

92.40 48.00 24.00

Total profit or loss.

$21.55

14.05

33.02

33.17

72.37 148.47 125.57

Series B— two applications annually.

Paddy.

Total.

Pounds. Ul,567

14,559

19,978

In- crease.

Pounds

4,908

22,050 6,) 15,971

23,268

29,453 29,282

24,091 14, 170

8,198

14,383 14,212 9,021

Total cost of

fertili- zer.

S38.80

65.10

57.75

80.85

161.70 84.00 42.00

Total profit or loss.

138. so

57.60

116.75

124. 10

197. 87 271.30 183.52

Aver- age

profit

(+)or

loss (— )

per

acre.

-15.14

+ 9.39

+ 16.

4-17.73

+28.27 +38.76 +26.22

3 Injured by cold water flowing directly onto plat. Not included in averages.

The results of these experiments justify the conclusion that for the present at least this soil is in need of nitrogen only. Little or no effects were produced in any case from the use of superphosphate or potassium sulphate, either when applied with or without am- monium sulphate. It is the custom of the rice growers to apply fer- tilizer, when used at all, to the spring crop only, believing that the more unfavorable weather conditions at that time necessitate the use of stimulants, whereas under the more favorable conditions that pre- vail during the late summer and early fall fertilizers are less needed. Moreover, it has been considered that the residual effect resulting from the spring application makes itself felt in the fall crop. The above experiments prove conclusively that neither of these opinions is justified. The growth of the fall crop, when more favorable weather prevailed i. e., higher temperature and longer days was affected to approximately as great extent by ammonium sulphate as was that of the spring crop. On the whole there appeared no evidence of a cumulative effect even from the heaviest application when made twice annually.

14

From the data showing the profit and loss it is noteworthy that the application of 300 pounds of ammonium sulphate proved the most economical, either when applied to the spring crop only or to both spring and fall crops, and that in the latter case the profits were very large. So far as these experiments go, they show in addition that the yields can be maintained at a high point and good profit be made under the system now employed, provided the proper fertilizer be used. This is not to be interpreted, however, as being a recommenda- tion of the system now in use, since it has been shown (p. 19) that with the rotation of crops, involving the plowing under of a legume, still greater yields can be obtained. The rotation system is far more rational and permanent and ought to be employed on all rice lands.

It has been found in other countries that the continued application of ammonium sulphate tends to produce acidity in the soil due to the fact that the sulphate ion tends to accumulate in the soil. The oc- casional application of lime, however, will correct this defect. The highly basic character of Hawaiian soils, on the other hand, partic- ularly the rice soils, justifies the belief that the production of acidity from the use of ammonium sulphate will be far removed in point of time. It is of interest in this connection that the annual application for over 60 years of 300 pounds of ammonium sulphate per acre at Eothamsted to a soil containing considerable amounts of calcium carbonate (probably 100 tons per acre in the first 7 inches) has not produced injurious acidity. The soil on which the above rice ex- periments were conducted contains a relatively high percentage of lime and magnesia, particularly the latter, but neither of these is present as carbonate in more than very limited amounts. The carbon dioxid content of the soil is low, not more than 0.10 per cent. The iron and aluminum, however, occur largely as hydrates which give to the soil its basic character, and which we may reasonably believe will prevent the accumulation of injurious acidity. It is of further interest to note that the application of lime has been shown to cause a decrease in the yields of rice on this soil.

It would not be safe, however, to recommend ammonium sulphate as the only fertilizer to be applied to the rice lands of the islands generally, since the effects of fertilizers frequently vary widely on different soils. In order to throw further light on this question some experiments have been conducted cooperatively on other rice lands, which resulted in showing that ammonium sulphate produced practi- cally as large increases as a complete fertilizer. At Kailua, for instance, approximately 60 per cent increase in yield was produced both by 150 pounds of ammonium sulphate and by a complete fer- tilizer containing an equal amount of ammonium sulphate.

As already pointed out, the rice soils, as a rule, are rich in phos- phoric acid but contain relatively small amounts of potash. While it is true that rice takes up a large amount of potash only a compara-

15

tively small part of it enters the grain. In addition, only a compara- tively small portion of the stnnv is really removed from the land, it being the practice to leave about one-half of it on the ground at the time of harvesting, while the remaining portion is used for bedding, etc., a large part of which sooner or later is returned to the soil. Furthermore, whenever manure is accessible the Chinese rice growers cart large quantities of it onto the lands, thus considerably aug- menting the potash supply. In view of these facts, then, it is hardly to be supposed that potash fertilizer will be required for many years. In the main, therefore, nitrogen fertilizers only are recommended for Hawaiian rice lands.

In this connection the question of the form of nitrogen best suited to rice naturally arises. Experimental data have been obtained on this subject which permit the drawing of definite conclusions.

THE FORM OF NITROGEN FOR RICE.

One of the most generally accepted teachings in all agricultural lit- erature, based, however, mainly upon experiments with dry-land crops, is that of the high availability of nitrates, it being considered that of all the forms of nitrogen nitrate is the most readily taken up from the soil and used as food by plants. As a result of the preva- lence of this view nitrates have been used for rice in America, and indeed sodium nitrate still is recommended at the present time for this crop by some authorities.

It has been known in oriental countries for soma time, however, that nitrate is not the most profitable form of nitrogen to apply to rice. Xagaoka,1 in Japan, demonstrated in 1905 the superiority of ammonium sulphate in a series of pot experiments. He found that while the effects produced by nitrates were variable and discordant the yields were greatly increased in every instance by the use of am- monium sulphate. As a result of his experiments Nagaoka concluded that the value of ammonium sulphate and nitrates stand in the ratio of 100 to 10.

In 1907 Daikuhara and Imaseki 2 also found ammonium sulphate to be much more effective for wet-land rice than either sodium nitrate alone or a combination of the two forms. The value of nitrate was also found to be considerably less when applied in conjunction with organic manures. Likewise it has been shown in several of the Prov- inces of India that other forms are superior to nitrates. Coleman and Ramachandra Rao,3 for example, pointed out that organic fer- tilizers produced a marked stimulation of the growth of rice in Mysore, while niter had but little effect. In 1911 the writer 4 pub-

1 Bui. Col. Agr., Tokyo Imp. T'niv., G (1904), pp. 2S5-334. ■BuL Imp. Cent. Agr. Expt. Sta. Japan, 1 (1907), No. 2, pp. 7-36. •Dept. Agr. Mysore, G^n. Ser. Bui. No. 2, 1912. 4 Hawaii Sta. Bui. 24.

16

lished the results of experiments conducted at the Hawaii station which showed the great superiority of ammonium sulphate over different nitrates.

Notwithstanding these facts some American writers continue to recommend sodium nitrate for rice and to discuss rice soils from the same standpoint as dry lands.

It is not necessary to go into a theoretical discussion of this ques- tion at this time further than to state that abundant experimental evidence has already been brought forth in various parts of the world to prove that nitrate is not the only form of nitrogen available to plants. Results obtained at the Hawaii station show that nitrate can hardly be considered to be the principal source of combined nitrogen for many plants when grown in the state of nature. It is known that nitrates are ill suited to assimilation by rice.

To study the practical effects produced on the growth of rice by ammonium sulphate and nitrate nitrogen, respectively, a series of plats was arranged alongside of those used in the experiments dis- cussed above. To one plat ammonium sulphate and to another nitrate of soda was applied before the time of planting. To other plats ammonium sulphate and sodium nitrate were applied in smaller quantities, the same being repeated at intervals of 10 days until six applications had been made. To each plat the total amount of nitrogen applied per acre was the same, and the experiments were repeated for three successive crops. The results follow:

Comparison of ammonium sulphate and sodium nitrate on rice.

Nitrogen applied.

Fall crop, 1909.

Spring crop, 1910.

Fall crop. 1910.

Straw.

Paddy.

Total.

Straw.

Paddy.

Total.

Straw.

Paddy.

Total.

Ammonium sulphate (ap- plied before planting)

Sodium nitrate (applied be-

Lbs.

3,168

1,881 2,475

2,277

Lbs.

4,603

2,475 3,465 2,623

Lbs. 7,771

4,356

5,940

4,900

Lbs.

3,316

2,029

2,772

1,633 1,930

Lbs.

3,564

2,128

3,078

2.079 2,178

Lbs.

6,880

4, 157

5,850

3,712 4,108

Lbs.

2,920

2,227

2,722

1,831 2, 145

Lbs. 4,010

3,312

3,762

2, 427 ' 2, 762

Lbs. 6,930

5,539

6,484

4,258

Ammonium sulphate (ap- plied in six applications) . . . Sodium nitrate (applied in

Check

4.907

From the above yields it is -apparent that nitrate of soda pro- duced only slight increases either when applied before transplanting or at intervals during the growth of the crop. Ammonium sulphate, on the other hand, brought about notable increases in every instance, the larger harvests having been obtained from the single application before planting. The repeated applications were made for the pur- pose of guarding against the loss of nitrate through leaching, but this appeared to have no advantage over the single application.

17

From pot experiments, where drainage was entirely prevented, the great superiority of ammonium nitrogen over nitrate was again dem- onstrated. In a series of pot experiments with the use of sterile quartz sand, it was found that where nitrate was the only form of combined nitrogen present rice made very poor growth, whereas ammonium forms seemed to be well suited to its needs. The net result of all these experiments forces the conclusion that nitrate is not a suitable form of nitrogen for rice, but that ammonium com- pounds are well adapted to its needs.1

In the rice-producing countries of the Orient organic manures are the chief source of nitrogen applied to rice soils. It has long been the custom of the Chinese and Japanese to grow some legume between crop> for the purpose of enriching the soil. Sometimes the legume is grown on one field, cut, and then distributed over others, so as to gain the benefit of green manuring with as little interruption in the growing of rice as possible. In addition, all sorts of organic nitroge- nous substances are freely applied. In Hawaii, on the other hand, almost no rotation is practiced.

From a single experiment conducted by the agronomist of this station, however, it was found that by plowing under a few months' growth of alfalfa just previous to the planting of rice the yield was 50 per cent greater than has ever been obtained on this soil by the application of any commercial fertilizer. In this experiment the alfalfa was grown on one plat, but was cut and applied to another, so that the effects may be attributed to the organic manure directly rather than to a combination of aeration and other effects, the soil being prepared and submerged very soon after making the applica- tion. Moreover, the application of different organic nitrogenous fertilizers at various times has always resulted in substantial in- creases in the yield of rice on this soil. In a series of pot experi- ments, for example, soy-bean cake was compared with ammonium sulphate. In this experiment nitrogen from each of the two sources was applied at the rate of 70 pounds per acre. The yield> obtained were as follows:

Ammonium

sulphate versus soy-bean cake <

.v fertilizers foi

rice.

ment of plat.

Straw.

Paddy.

Total.

Grams. 215 107

80

Grams. 13fl 122 01

Grams. 353

Check

141

From the above data it will be seen that soy-bean cake brought

about an increase of 100 per cent in the yield, but was considerably inferior in this respect to ammonium sulphate. The reasons for the

1 The full data with reference to the assimilation of different forms of nitrogen by rice and a more complete bibliography of this subject will be found in Hawaii Sta. Bui. 24.

18

superiority of ammonium sulphate over organic forms of nitrogen are discussed in greater detail on page 21. In this connection it is of interest to point out that the plant absorbs the principal part of its nitrogen during the early period of its growth ; 1 readily available nitrogen therefore is' needed when the rice is young, and since the production of available nitrogen from organic forms requires consid- erable time the application should be made some time in advance of planting, a precaution that was not taken in the above experiments. Through a period of years, however, the total effects would probably become more nearly equal.

AMMONIFICATION AND NITRIFICATION IN RICE SOILS.

The analysis of a number of rice soils taken from the field when wet and analyzed immediately has shown that rice soils contain con- siderable quantities of ammonia, varying from a few parts up to as much as 50 or 60 parts per million.2 On the other hand, in the sub- merged condition nitrate is rarely found in more than mere traces, frequently being entirely absent.

Since good effects are known to follow the use of organic manures, and, furthermore, that ammoniacal nitrogen is especially effective with rice, it becomes a matter of interest to ascertain whether or not ammonia is formed in rice soils at rates sufficient to supply the needs of rice.

Accordingly a series of ammonification experiments were carried out with dried blood as the source of nitrogen, using varying amounts of water, starting in with the air-dry condition and increasing the amounts of water applied up to and beyond the saturation point. One hundred gram portions of soil were placed in tumblers with 2 grams of dried blood added to each. After an incubation period of seven days the ammonia was determined by distilling with mag- nesium oxid into standard acid. The results obtained were as fol- lows : Influence of varying amounts of water on the ammonification of dried hlood.

Water added.

Nitrogen found as ammonia.

Water added.

Nitrogen found as ammonia.

Soil 292.

Soil 461.

Soil 292.

Soil 461.

Mg. 2.2 2.2 37.8

Mg.

3.9

5.1

4.3

25.5

41.2

53.2

59.0

35 cc

Mg. 131.1

Mg.

86.8

40 cc. .

90.5

<54.5

:>n. 7

85.4

10 cc...

71.2

15 cc

164.9

85. 3

20 cc

165.5 164.6 140. 1

55 cc 48.2

65 cc

52.4

25 cc

< 15.1

30 cc

70 cc

16.1

1 Hawaii Sta. Bui. 21.

2 Fraps also showed in 1908 that ammonification takes place much more vigorously rice soils of Texas than does nitrification (Texas Sta. Bui. 82).

8 Each soil contained about 5 per cent moisture. 4 Saturated.

19

It is here seen that ammonification proceeded at a slow rate only, if at all. until a certain moisture content was veaefaed (about 10 per cent in the case of soil 292 and 15 per cent with that of 461 >, above which vigorous ammonification took place, which steadily increased up to an approximate two-thirds saturation, then decreased as com- plete saturation was approached. There was. however, active am- monification in the completely saturated soils. This seem- to prove that ammonia is formed in submerged soils and that organic nitroge- nous fertilizers will give rise to nitrogen available to rice under con- ditions that prevail in rice cultures.

As is well known, the formation of ammonia results from the activity of a wide range of soil organisms, bacteria and fungi, some of which are aerobic and some anaerobic. While the above data show that ammonification is more active with moisture supplies below the saturation point, being greatest at approximately two- thirds saturation ; nevertheless, the fact that ammonification can take place in saturated soils is of very great importance in the growth of rice. It makes possible the production of available nitrogen in rice soils without the necessity of employing cultural methods that are primarily designed to bring about aerated conditions.

Free oxygen being essential to nitrification, it seems justifiable to conclude that nitrification does not take place to any considerable extent in a submerged soil. In order to throw positive light on the question, however, search was made for nitrates in various submerged soils about Honolulu, but in no instance was more than a few parts per million found. In some laboratory experiments it was further found that practically no nitrification took place in submerged soils.

The process of denitrification, however, is of considerable impor- tance in this connection. As is well known, free nitrogen gas may be one of the products of the decay of organic manures. Likewise, it is also known that certain denitrifying bacteria break down nitrates into nitrites, ammonia, and finally into free nitrogen gas. The con- ditions under which the denitrifying bacteria function are extremely varied, but the two conditions most favorable for their activity are a source of food supply and a lack of free oxygen. In the rice soils of Hawaii these conditions are abundantly met; tfre high content of organic matter guarantees a source of food, while supersaturation excludes the air.

A- indicated above, the denitrification processes may be conven- iently divided into two classes, (1) those causing a liberation of nitrogen from organic materials, and (2) those bringing about a reduction in the nitrates present. The latter of these has been the subject of considerable study at the Hawaii station.

20

In pot experiments conducted some time ago for the purpose of studying the nutritive value of different forms of nitrogen it was found that in every instance the addition of nitrate to submerged soil resulted in the formation of comparatively large amounts of nitrite within a few days after the time of application. In sand cul- tures similar effects were observed except where complete steriliza- tion was effected. Furthermore, wherever any considerable amount of nitrite was formed, more than 5 to 6 parts per million, toxic effects were produced, while still greater amounts caused the rice to turn yellow and later to die.

Nitrite, however, was not produced to any considerable extent when organic ammoniacal nitrogen was the only form of combined nitrogen present, A further objection to the use of nitrates as fer- tilizer for rice is found in the fact, therefore, that nitrates become reduced to nitrites, which are extremely poisonous to rice. Nitrate, then, is unsuited to the nutrition of rice, and in turn may give rise to a substance that is distinctly poisonous.

THE MANAGEMENT OF RICE SOILS.

During the past few years an increasing amount of study has been given to the question of soil management and cultural methods, the rotation of crops, and various methods of soil treatment are coming to be viewed in their relation to this general question. Investiga- tions on special phases of this subject have thrown new light on the important question of soil fertility in general and on that of sub- merged soils in particular.

In an investigation on the solubility of the island soils1 some data of interest in this connection were recently obtained. Likewise Coleman and Ramachandra Rao2 studied the effects on the yield of rice of aerating the soil.

The solubility of substances in submerged soils has been found to be abnormally high, the amounts of the several mineral constituents going into solution in water having been found to be considerably greater than were obtained from any of the dry-land soils of the islands.1 After the wet soil was allowed to thoroughly dry out, however, the solubility in water was found to be greatly decreased, falling to about the same degree as that of dry lands. Similar data have also been obtained by Coleman and Ramachandra Rao, in Mysore.2 This seems referable in the main to soil colloids and the formation of soil films in the air-dried state. The overcoming of film pressure and diffusion of dissolved materials upon resubmerg- ence require considerable time, so that the amount of soluble plant

1 Hawaii Sta. Bui. 30.

2 Dcpt. Agr. Mysore, Gen. Ser. Bui. No. 2, 1012.

21

food coming into contact with the absorbing root surfaces of rice would be considerably less when planted in a soil thai had been thoroughly dried out. Later the mineral constituents would, of course, regain their former state of solubility, but just how much time would be required for the reestablishment of a permanent con- centration can not be definitely stated. It seem- certain, however, that a lowering of the availability of the mineral constituents would temporarily result from a thorough drying out of the soil.

It is now the practice of the growers, both on the mainland and in Hawaii, to plow their rice lands some weeks before the flooding time, in the latter case immediately following each harvest, so as to permit as much aeration of the soil as possible. As would be expected the aeration prevents nitrification, so that by the time a new crop is planted nitrate has accumulated to a considerable extent. Upon resubmergence the nitrate thus formed becomes partially leached out of the soil and in part converted into poisonous nitrites. The nitri- fication therefore leads to a direct loss of nitrogen on the one hand and to the formation of a substance toxic to rice on the other. If, however, Hawaiian rice soils are not plowed or cultivated after the water is turned off and the previous crop harvested little or no nitrification sets in. The puddled state of the soil and its compacted condition effectively exclude air. It is only after cultivation and consequent aeration that active nitrification sets in.

Unfortunately no experiments showing the practical effects on the growth of rice as produced by aeration against nonaeration have been conducted at this station. Such experiments, however, have been made in Mysore, the results of which are in complete harmony with the inferences drawn from the nitrogen transformations above referred to. As a result of experiments carried on through two years, Coleman and Ramaehandra Rao x found that a considerable gain in the yield of rice was obtained by leaving the land in the unplowed condition during the time between crops, the plowing for the newT crop being deferred until just before the new crop was planted. By growing a legume between rice crops all needed aera- tion can be brought about; while the nitrates formed during this period would be absorbed to a large extent by the legume, and in addition free nitrogen from the air would be added to the -oil through the growth of the Legume. Upon plowing under the Legume ammonification will set in, thus furnishing available nitrogen for the next rice crop. The nitrogen requirements of the rice would there- fore be met and other beneficial effects that arc believed to result from the rotation of crops would be secured. There i^ little ground

1 LOC. 'il.. P. \K

22

to doubt that better conditions would thus be established and greater profits obtained.

In the carrying out of the experiments reported in this bulletin assistance has been rendered by various members of the station staff, to whom thanks are hereby extended.

SUMMARY.

(1) Hawaiian rice soils have originated from basaltic lava, but also contain small amounts of coral limestone.

(2) In texture most of the rice lands are clay loams, and contain approximately equal quantities of fine sand, silt, fine silt, and clay.

(3) In chemical composition these soils are quite similar, with the exception of those from the Waikiki and Kaulaunui districts, the former of which contain abnormal amounts of magnesia, while the latter are highly organic. In general, the nitrogen and phos- phoric acid are high, while the potash is 1owt, due largely to the solubility of potash, which is leached from the soil.

(4) From fertilizer experiments carried on through seven crops it was found that the application of 150 pounds per acre of ammonium sulphate produced notable increases in the yield, but 300 pounds per acre proved the more profitable. Potash and phosphoric acid were without effect. The application of ammonium sulphate to both the spring and fall crops yielded considerably more profit than when made to the spring crop only. The residual effects on the fall crop from the spring application are small. The immediate effects ob- tained from making the application to the fall crop were about the same as those obtained wTith the spring crop.

(5) A complete fertilizer proved no more effective than ammonium sulphate alone, whereas the application of both ammonium sul- phate and potassium sulphate caused a decrease as compared with that obtained from ammonium sulphate alone.

(6) Nitrogenous fertilizers only are recommended for Hawaiian rice soils, and for immediate effects a given amount of nitrogen in the form of ammonium sulphate will produce greater returns than from organic sources. Under no circumstances should nitrates be used as fertilizer for rice.

(7) With nitrate as the only source of combined nitrogen for rice poor growth results. In addition nitrates in submerged soils become reduced to nitrites, wmich are poisonous to rice. Ammoniacal nitro- gen, on the other hand, is well suited to the needs of rice.

(8) Very little nitrification takes place in submerged soil; am- monification, however, goes on, not so vigorously as in aerated soils, but sufficiently to supply the nitrogen needs of rice, provided suffi- cient organic matter is present in the soil.

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(9) A rotation of crops, including the plowing under of a legume, is recommended. It is believed a system can be worked out whereby a legume can be grown between crops and then plowed under, thus gaining the benefits of the rotation and at the same time permitting the growing of two crops of rice annually.

(10) Rice soils should not be plowed and then allowed to lie fallow between crops. Nitrification sets in immediately after aerated con- ditions are produced and the nitrates thus formed become converted into poisonous nitrites upon resubmergence. or are lost through leaching. When no rotation is practiced it is better to leave the land unplowed until just before planting the next crop.

ADDITIONAL COPIES of this publication l may be procured from the Superintend- ent of Documents, Government Printing Office, Washington, D. C, at 5 cents per copy

UNIVERSITY OF FLORIDA

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