/ \ JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOLUME 11, 1921 Robert B. Sosman GEOPHYSICAL LABORATORY BOARD OF EDITORS S. F. Blake; BUREAU OF PLANT INDUSTRY Sidney Paige GEOLOGICAL SURVEY ASSOCIATE EDITORS H. V. Harlan BOTANICAL SOCIETY N. HOLLISTER BIOLOGICAL SOCIETY S. A. ROHWER ENTOMOLOGICAL SOCIETY F. B. SiLSBEE PHILOSOPHICAL SOCIETY G. W. Stose GEOLOGICAL SOCIETy J. R. Swanton ANTHROPOLOGICAL SOCIETW PUBLISHED SEMI-MONTHLY EXCEPT IN JULY, AUGUST, AND SEPTEMBER, WHEN MONTHLY BY THE WASHINGTON ACADEMY OF SCIENCES OFFICE OF PUBLICATION 211 CHURCH STREET E ASTON, PA. DATES OF RECEIPT OE DECAYED JOURNALS On account of the printers' strike in May 1921, all numbers of the Journal from May 4, 1921, to date have been delayed. The dates of receipt in Wash- ington of Numbers 9 to 20, inclusive, are given below : No. 9. Due May 4, 1921. Received May 23, 1921. No. 10. Due May 19. 1921. Received June 27, 1921. No. 11. Due June 4, 1921. Received July 23, 1921. No. 12. Due June 19, 1921. Received Aug. 8, 1921 No. 13. Due July 19, 1921. Received Aug. 18, 1921. No. 14. Due Aug. 19, 1921. Received Sept. 24, 1921. No. 15. Due Sept. 19, 1921, Received Oct. 13, 1921. No. 16. Due Oct. 4, 1921 Received Oct. 17. 1921. No. 17. Due Oct. 19, 1921. Received Nov. 10, 1921. No. 18. Due Nov. 4, 1921. Received Nov. 17, 1921. No. 19. Due Nov. 19, 1921. Received Dec. 9. 1921. No. 20. Due Dec. 4, 1921. Received Dec. 15, 1921. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 January 4, 1921 No. 1 MINERALOGY. — .4 new classification of the sulfo-salt minerals. Edgar T. Wherry and William F. Foshag, National Museum.^ The data for this paper were collected while the senior author was employed in the National Museum; the junior author, his successor there, has aided in bringing them up to date. The plan followed is essentially the same as that recently applied to the sulfide minerals,- although formulas are stated in both ex- panded and condensed forms, to bring out relationships as fully as possible. The chief new features are: the systematic assignment of minerals to divisions based on the ratios of basic and acidic sulfides, and to groups based on crystallization; the classing of minerals containing both univalent and bivalent metals as double compounds rather than as isomorphous mixtures, and the throwing out of evident admixtures before calculating formulas from analyses; and the interpretation of certain instances of high sulfur content as due to a higher state of oxi- dation of the metal rather than the non-metal, resulting in the discarding of a "sulfarsenate-sulfantimonate" division, such as has usually been recognized heretofore. 1 Published with the permission of the Secretary of the Smithsonian Institution. Received November 12, 1920. 2 This JouRNAi, id: 487. 1920. 2 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 09 a o o 09 to < 6 i < I »-« M W O H < C/3 < H H < CO I o (z< w c c eft « "^ bo o o c 3 O T3 C cS C O O ^ B Tj o c o > '•5 a '•5 Q cs eft (ft o z: '-> a C o o G SJ bO O o o t. -^ M -1— t O eft •a -4-t & o •5 ,. o o I-' CJ . J2 ' (2:^. a; C !ft 4;. W B 3 3 bO bo q 'ift '-5 eft o C "O S 2^ .11 -5 o '-5 o < 3 '3 ■9 .ii re t^ CI ^ a CO o B ^ ^ -3 ^ « -a c3 eft 'ci 3 Q .'B en o ^ I; 3 O >. 3. ■H cS QJ ^ 1-1 cs PQ •s. o ■Ph 01 3 O) bo O E o OJ CD tft — ; - ^ ^ B d p- CO e-r w to c3P M U2 CO • •£ eft" s « < § CO ^ « •• .. § ^^, H 3 ~ o I— I I— I > CO < "a o c bO o ►—I o u o p <; N M ►J < }-■ en >< u cu O O W H hi Z o H (A O bO C/J. 5 en CM bo CO 12; :z: 3 O > I ■M 3 C 2 O w Z c O 5: CO « I— ( CO CO s CO, S CO CO CO CO 3 CO < o O CO tt CO « 3 U XTi. H c; (J CO « CO 15 o d) W > 3 O +j CO bO _B '> CO O .2 '> IS o c < « .. c O 0) >1 3 •• d ^^ "" ^ -S ' o ►J < O o I ►4 O c < w K p o CO CO .i' J? P5 bO PL, P9 C-t CO CO e^ ..S' < pq o I— I CO > »— I Q ►4 O Q CO CO w K O H W a 3 JAN. 4, 1921 WHERRY AND FOSHAG: SULFO-SAW MINERALS u ^ M 1 x^ 1 "> 4J g O X -M a; cr. u d ^ d "" _z^ ^ ■^•^ 3 3 cr d o V o a; a d Q ~ Q ■^ •rf >. *0 o s J2 d c d . W 3 Q ^ "a; "■3 a o u 3 C/l C 3 -J 1 "u 3 3! "d 3 -a S 3 o "s -^-t c/; o w ^ d 3 o u a 3 t/i 4J _3 d d o 3 < u 1 is <2 3 N s" d so o o d ^C 3 g Cw _3 o X C ,« O !/5 -*-• a *j o o •a s d u d a a '~' "" '^ -^ — ' -' ^ -' < CO 3 u o o o M W s ^ s o . C/3 m ■ 3 ^^ c< 3 n P C o o ai o w I- H^ n 1^ o *i H -fi (U >J -3 -•-J < ts '*-» s o o 4^ J! s U M CO XI XfX CO < m < .. m x: < c/i CO ■•« 4> O < V ;■ +-> a> '5 +j o 'm M d c u 12 o u IH •4-1 ^ 3 CO CO ^ '■ W /-» t/3 .^-^ s < to' CO c^ a. Ph( (As! s 3 be r- -^ S' u < H Ch p^ CO S CO CO ^. '^ CO CO i -° -^ '^' <; CO PQ <: CO CO CO rn ^ C^ Tl ^-* bo bo be -i < < <; H a. o o w o d ■•3 Q d • -H •a •c (U *d 3 § Xi Q •o o Cm •4-* o d u +-> d u a fu, CO E o u O 4= t« O a c o d N - 4) o Cfi ^ .1-1 y- <: CO « < be be be --! < <<^ CO :i CO s CO CL, pq Ph S^ *2 u, 4> C >• ti r- * S 2 w S A. >-i ►J ►J < cfi g ^, CO y^ be bo .^ O O o 1^ co_ m CO s ^'^co J2 -^ •- ■< CO pa Oi p^ fi!, CO X PL. CO .^ CO' CO X Oh 3 a CO o CO I— ( > I— I Q CO c/l ^. CO CO pq CO Oh -w -M .Q ;3 t' o a l-H Q CO p^ O i-j u o 2; o S CO cr, <: cc CO X Ph ,^ -S S < O ^ J- r^ t, PQ 2 ^ be E d S I-; Oi pq 04 o o w Oi w & a> ■^ T SiH ? = p d < 43 a g 3 d pq 4 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 o •■^ (U Q .2 >> C C ir' 4-. o (/] s c 'a a 3 m O s o Q -2 -t; O rt P4 W u ^. 2 w pq c^ pq i:i( < to Til ro U < (^ o I— c CO (— I > Q CO O ►-^ n o K K O O CO <^' CM 2 •• Ph CO 2 ^ TJ O rt ■t-i o a; -^^ a (M o 02 ^ « •a T-H "^. rt • - ^5' _V) * . 126) bS.Sl 2 o CD S !E oo o bio '•S rt a ..'" C ft o E o <; bO , . o 6 J2 I— I en o \ Includes "w; \ formulas. O CO o o H « O o CO CO C/5 CO fin CO M CO CO Pi CO X! CO CJ CO O CO ■ ■ t— ( CO > CO oo CO r— XJ Ph CO CO 3 CO « P^ w O o a CO Pi Q LO Pi o "S LO G ca CO CO .o >o ^^. ^ Pi < GO, M X X < PL, Ph y CO (xh O W HH Ah « o eg CO CO o z w « G a o I G 1-1 "H-l S :G 3 ^ CO O Ph CO S o < >< CO « co_ CO bo < to s Ph_ bO <: to, Ph ca o O o Z P to o Ph P o CO tin CO PLh to bo < CO s •• ^ to O rO t-H PL, to to > < P O to to PL, to tg CO PLh OJ G QO c o IS •• ca u to P o o w W (A CO JAN. 4, 1921 WHERRY AND FOSHAG: SULFO-SAI.T MINERALS JS CO 6 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 o ^1 ^? (u o C ^ rt o< o 06 3 o SI rt ° >> a) HJ O S o o 00 J^ o E *^ o . u > 'u d ba en £ Q Q. -a > ^ o o . - 3 O s <^ > 00 1— I >> ^- .^ 03 03 dJ OJ 3 rt +i s s d CO CO to eg CO Ph CO •c x> S w rt 00 d o CO • »-< B CM CO tS3 m 0 ►— ( CO c/; P-, > c^ Q C^l (:4 O i-j Q W X < w I- H W o O o w H 2 Q w s w u Ph CO > ro 3 " 3 y -ri ■A ^ O J3 tn 01 o 0) CO 3" a ^ CO bJO ^ a o O C o m 3 CO 3 o CO 'a? 3" a CO CO in < CO Ph CI be < CO ^ £-= ^ (>3 ^ M a c/^ U tXi -r; tn H CO ^ CO ^ co' < CO CO cq CO (M - 01 — 4? 3 3 3 fj O o 'i. LO lO 10 ■4-> • fH u OS 0) bO n v JAN. 4, 1921 WHERRY AND FOSHAG : SULFO-SALT MINERALS S ^ u 0 (U bl c 3; k J3 ■M "TS rt IS S ■5? ■> c Q 0 C •0 IS ■4-' 0 3 ■ >> 0) (J E d V! g 'tr. tr ^ 2 a Cm "^ 3 •"I n ^t-i cS •<-> -i-> tn 0 rj "3 0 ^j-> -^ OS e c3 v; 3 3 Q jr. 2 0 a l^ ^ ii "o V-i "y 0 3 0 OS V4 «3 H 0 0 0 3 Ch Xfl HH 'Ji •5 "c >* < iM o (u (« 0 u • *■ tc - ^^ 0 ,^ ZJ •^ y ^ 3 0. ■4-t cJ ■u 0 3 0 ■^ ^ 0 __^ he 0 1 (J 0 "o . -r • ^4 ■i^J 0 J2 g (3 r- iC CJ ■^ X •a 0 0 _M 0 d .2 d -3 _3 r-H ^ S3 ■'3 3 -l-l d X en ■4-1 d -►J -4-> X 3 "0 D c w X 0 "c X y •a _3 _3 CJ d d a C d d Q i CJ J! 'o X be a 3 d s 'x d d Q X 0 X > Q X ». bo t* 3 X X 3 _o .3 'D 0 X X d :-■ V -M 'bi d 3 0 •0 ^ ^ _aj ^ ^ 01 a cq V) d d fcJ5 'b 'd 3 0 >, 0 3 d r- 3 "cj X 0 a d X OJ X .1 ■*-» 3 OJ 3 V d s 0 -*-» X 3 0 bO _o "d d •3 'x d X 'd 3 d Q X CJ d 3 CJ X d •^3 OJ g d 3 3 3 _s'' 'd -tJ I-. CJ u r-" 3 4-> 0 rt u d f-" "o y 1 d It b« d 0 n CC 0 0 0 "d d N _3 d d > d d 0 d 3 d 1 -4-> 0 CO d 5 fao 0 6 0 CJ 3 s 5 0 3 a H- 1 CJ 0 d 0. d ^ -'- ' — ' '^ *^ --- -"^ -^ a; ^-^ ^— ^ y ^ t* SO < < be be < < o « l-H ^ > s Q 2 ■ ai 3 o 2 O „ P ■• J CO S o 3 |U O 2 2 P ft. O 3 o CO > I— I Q o CO s O' CO w o 0^ p o a; o 2 w o w w n pq CO 8 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 o 3 O O) S3 (U b« O O J3 05 X3 •a c o 6 o £i rt ■" t* &■ o C-l 3 u ci 3 u CO E 3 bo ■* -5 t- (LI a "A O >— I CO h- 1 > 00 -J < s ^ <; 00 p o « o « 1-1 »-( in 1^ (LI C O a !: '^ o S O CO "^ '5. I "3 en 3 o '-' spa o '^ o w >> '2 J-- (U _, 3 E -^ CO rt 3 3 S O Q ^ M .O ca CO M ;-( ° 2E oi oj CO Ah CO rt CO CO CM C-* VI r^ < CO <£! 50 bt> be < < CO Xi CO CO 00 Pi C!3 3 = . Q O K^ ^ E 3 o : 3 en pq c« 3 a Q 3 .a T3. cs o is '^ cS a; pL, CO CO en CO (U Ph 3 u CO (J ILI O CO CO CO CM CO CM bo O o I— I &j CO o I— ( > w « s ■^ _ (3^ w S a> O I— I CO h- 1 > I— I Q (M 2 "^ W ^ o •• w CO ■^ CM a- < P --( O Pi o w o < .ts O £? "o JAN. 4, 1921 WASHINGTON: NOTE ON CRUCIBLES 9 ANALYTICAL CHEMISTRY.— A^o/^' on crucibles used in rock analysis.'^ Henry S. Washington, Geophysical Lab- oratory, Carnegie Institution of Washington. It may be of interest to those who are engaged in the analysis of silicates or silicate rocks to put on record my experience with a palau and an iridium-platinum crucible, which have been used for the fusion of rock powders with sodium carbonate. Palau is an alloy, introduced a few years ago as a substitute for plati- num, and is composed of 80 per cent gold and 20 per cent palla- dium. A small percentage of iridium is often alloyed with platinum to impart greater stiffness, as pure platinum is notice- ably soft.- It is well known to those analyzing rocks that, when platinum or iridium-platinum crucibles are used for the sodium carbonate fusion, the cold cake sometimes adheres obstinately to the crucible walls, after slight soaking with water in the crucible and gentle heating over a low flame, instead of freeing itself as it "should do." This behavior necessitates prolonged digestion of the adherent melt so as to dissolve the cake, which sometimes results in loss of substance, and alwavs in loss of time. This unfortunate behavior is caused, in many cases, by in- dentations or other irregularities in the crucible wall or bottom, brought about by careless handling, such as squeezing the cru- cible to loosen the cake. It is also apparently rendered more liable to happen through the ogee-like curve assumed by the lower parts of the sides of platinum crucibles after long usage; and is easily brought about by attempting to remove the cake before it is quite cold and before it has separated or has started to separate from the walls. The roughness of the inner surface of platinum crucibles is also a determining factor. Even if the ' Received November 15, 1920. - For some studies on the quality and properties of various platinum wares on heating see: R. W. Hall, Journ. Amer. Chem. vSoc. 22: 494. 1900; HulETT and Berger, Journ. Amer. Chem. Soc. 26: 1512. 1904; HillEbrand, Walker, and Allen, Journ. Ind. Eng. Chem. 3: 686. 1911; Burgess and vSale, Journ. Ind. Eng. Chem. 6: 4.52. 1914; 7: 561. 1916; Bull. Bur. Standards 12: 289. 1915 (Sci. Paper 254;; Burgess and Waltenberg, Bull. Bur. Standards 13: 365. 1916 (Sci. Paper 280); Hillebraxd, U. S. Geol. Survey Bull. 700: 102 (Note 3). 1919., 10 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 cake as a whole separates from the walls, there is often left a narrow patch or series of patches around the upper edge of the cake, strongly adherent to the crucible wall, though this is of less consequence. I have frequently had the opportunity to observ^e this annoying occurrence, with both platinum and iridium-plati- num crucibles, and have elsewhere called attention to it.^ In the course of making many rock analyses it was found that crucibles made of pure platinum (Heraeus) were very soft, and apparently not sufficiently polishable internally, so that a ready loosening of the cake from them was seldom accomplished; although for general ignition purposes they are admirable, because of the negligible loss of weight on ignition. Crucibles made of platinum alloyed with a small amount of iridium (such as were used in my laboratory from 1896 to 191 2), were found to be much better for the carbonate fusion. They are stiff er than pure platinum, and are therefore less liable to indentation, and are also susceptible of a higher polish. The cake loosened more often and more readily than from pure platinum, but still adhered occasionally. In the spring of 191 8 I began using a palau crucible, chiefly with the object of testing the material in actual rock analysis, because of the constantly augmenting cost of platinum. To my great gratification it was found that the cold sodium carbonate cake always separated easily, quickly, and almost or quite completely from the crucible, far better and more surely than it had done from either platinum or iridium- platinum crucibles of about the same size and shape. With this crucible, which is now reserved for this purpose, I have made many fusions with sodium carbonate, but have not once found the cake to adhere — in each case it has freed itself rapidly and completely, on gentle heating with enough water to cover it. This satisfactory behavior is the more noteworthy because this crucible is slightly indented, at about the level of the upper edge of the melt, around the zone of contact with the supporting triangle.^ Apparently the palau softens rather more than plati- ' H. S. Washington. Manual of the chemical analysis of rocks (New York, 1919), pp. 132 and 135. * A triangle of fused silica or of pipe stems must be used with palau crucibles. Platinum triangles alloy with palau and ruin both crucible and triangle. JAN. 4, 1921 WASHINGTON: NOTE ON CRUCIBLES 11 num or iridium -platinum on strong ignition. It is to be noted, by the way, that for my fusions the blast was never used. The heating was done for the most part over a half-high Bunsen burner flame, which is quite sufficient to fuse the carbonate mix- ture, and was usually supplemented by a Meker burner during the last fifteen minutes or so. The time of heating varied from forty-five minutes to one hour. About i gram of rock powder and 5 grams of sodium carbonate were used for each fusion. The cause of this freedom from adhesion of the cake to the palau crucible walls is uncertain. I am inclined to attribute it chiefly, if not wholly, to the superior hardness and stiffness of the alloy, and especially to its superior polish. The iridium- platinum alloy is almost, but not quite, equal to palau in these respects, while pure platinum is much softer and susceptible of less polish. Whatever the cause may be, and whether the same behavior is true of palau crucibles in general, the observations mentioned indicate that palau is superior to iridium-platinum, and still more to pure platinum, for the purpose of the sodium carbonate fusion in rock analysis. I have not tested the resistance of the palau crucible to fusion with potassium (or sodium) pyrosulfate, though some of the refer- ences given above indicate that it loses more weight during the operation than platinum or iridium-platinum. It may, however, be of interest to give the data as to loss in weight of the palau crucible, as well as of an iridium-platinum crucible, during some rather long series of fusions of rock powder with sodium carbonate. It must be premised that both crucibles were reserved for this operation, though occasionally they were used for the evaporation of the solution of alkali chlorides in the determination of potash and soda; this, however, w^ould not noticeably affect their weights. Since June 12, 191 8 (when it was used for the first time), the palau crucible has been used 47 times for a sodium carbonate fusion. vSince that date the crucible has not been scrubbed with sand, nor was it used for the pyrosulfate fusion or other ignition that might presumably affect its weight. The evaporations for alkali chlorides for which it w^as used were made at 100°, and 12 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 were followed by a very gentle heating after dryness to drive off the ammonium chloride. It would thus appear that the so- dium carbonate fusion was the only factor that might lead to loss in weight, whether through the temperature of ignition or through the action of the carbonate. The same balance and the same weights were used throughout the series. On June 12, 191 8, the weight of the palau crucible was 32.0712 g., and the weight diminished steadily and with great regularity through the series of 47 carbonate fusions until the last weighing, on November 8, 1920, when it was 32.0613 g. The difference is 0.0099 g., giving an average loss in weight for each fusion of 0.00021 g., that is, about 0.2 mg. For comparison with this there was taken a series of 2 1 weigh- ings of an iridium-platinum crucible (percentage of iridium unknown). The first weighing of the series was made just after the crucible had been scrubbed with sea sand (Dec. 5, 19 14), and the last when another set of weights was put into use (Sept. 9, 191 6). This crucible, likewise, was reserved for the sodium carbonate fusions, and only occasionally for the evaporation of the alkali chlorides. The initial weight of this crucible was 30.1493 g., and the final, after a series of steadily diminishing weights, was 30.0656 g. This gives a total loss in weight of 0.0099 g. (by coincidence identical with the other), and an average loss in weight of 0.00047 g. Thus the iridium-platinum crucible showed an average loss, due to the fusions, rather more than twice that of the palau. It is well known that crucibles made of platinum containing iridium lose weight very noticeably on ignition, which is commonly ascribed to volatization of iridium, and this factor would seem to have had influence here. No estimate was made of the average loss in weight suffered by pure platinum crucibles which had been in use before the iridium-platinum one, as my notes showed that they had been used occasionally for the fusion with potassium pyrosulfate, which would cause a serious and rather irregular loss (which may be as much as 5 mg.). For the same reason a long series of data on my crucibles that had been used in my own laboratory at Locust, New Jersey, from 1896 to 191 2 was rejected. JAN. 4, 1921 kempton: linkage in maize 13 Conclusions. — The cold cake from the sodium carbonate fusion is freed very readily and completely from a palau crucible, much more readily than from one of iridium-platinum, and still more so than from one of pure platinum. The average loss in weight after each sodium carbonate fusion for the palau crucible investigated was about 0.2 mg., and that of an iridium-platinum crucible was about 0.5 mg. The greater average loss of the latter may be ascribed, in part, to volatilization of iridium. GENETICS. — Linkage between hrachytic culms and pericarp and cob color in maize.^ J. H. KempTon, Bureau of Plant Industry, U. S. Department of Agriculture. (Communi- cated by G. N. Collins). Characters which tend to be inherited together are said to be linked, on the assumption that the genes for such characters are arranged in a linear series on the same chromosome. The agree- ment between the number of groups of linked characters and the number of chromosomes and the linear arrangement of the genes has been demonstrated genetically with remarkable detail for the fruit fly (Drosophila melanogaster) by Morgan and his co- workers and for other species of Drosophila by Metz. While it seems almost certain that groups of linked char- acters corresponding to the number of chromosomes will be found also in plants, nevertheless, up to the present time this has not been demonstrated. In several respects plants would seem to offer better oppor- tunities than animals for studies of this kind, and among plants Zea mays has many advantages. In the number and frequency of variations alone Zea probably exceeds Drosophila, while in the physiological importance of the structures involved it far surpasses any animal organism where much less fundamental changes are almost certain to be fatal. The number of chromo- somes, however, is relatively large, necessitating the intensive study of many characters, but with each succeeding linkage or demonstrated independence progress becomes more rapid. ^ Received November 11, 1920. 14 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 Since the first pair of linked characters was found in maize in 191 1, six others have been reported, the present pair making the eighth. The linked characters reported thus far are listed below: Characters Waxy endosperm Aleurone color Factor symbols Xx Cc Per cent crossovers 25 Reported by Bregger, 1918 Collins and Kempton, 1911 Endosperm color .A.lbino seedlings 6 6 25 Kempt on, 1917 Golden leaf color Aleurone co.lor Gg Rr 23 Lindstrom, 1918 Golden leaf color Yellow seedling Gg LI 19 Lindstrom, 1918 Yellow seedling Aleurone color LI Rr 0 Lindstrom, 1918 .Sweet endosperm Podded seeds Ss Tt 18.5 Jones, 1919 Spotted aleurone Aleurone color Ss Rr 12.5 Kempton, 1919" Brachytic culms Pericarp and cob color Br br b 35 + Reported here " Emerson (1918) explains this relationship in another way. * Actual factors involved not identified. Brachytic culms, a variation in which the internodes are verv much shortened, made its appearance in a second generation hybrid and thus far behaves as a unit character in crosses with the normal form. (Kempton 1920.) Unlike Emerson's extreme dwarf anther ear (Emerson 191 2) the brachytic variation is not readily recognized in the seedling stage but is conspicuous before the tassel appears. This variation has been crossed with several others in an effort to determine its relationships. Many of these crosses have been carried through the second generation and most of them indicate little if any association of the brachytic character with the other variations. In some of the crosses the results were conflicting and further analysis is necessary. One relationship, however, seems certain, since it is corroborated in three unrelated crosses. This is the association of brachytic culms with cob and pericarp color. JAN. 4, 1921 kempton: linkage in maize 15 Through the courtesy of Prof. R. A. Emerson we were sup- plied with a sample of his liguleless leaf variation (Emerson 191 2). This variation is one in which the line of demarcation between the sheath and the blade is lost and the leaves possess neither ligules nor auricles. In the strain supplied us the color of the pericarp and cob was red. This liguleless leaf variation was crossed with a strain of brachytic culms which had a white peri- carp and cob. The plants of the first generation were all normal in stature with red cobs, and pericarps and the leaves all had the normal ligules. Nine of these first generation plants were self -pol- linated and separate progenies were grown from each of the resulting ears. With respect to the pericarp and cob colors only two classes of plants were obtained in the second generation, namely, those with a red cob and pericarp and those with a white cob and pericarp. This is in accord with the results of Emerson, 19 11. The other two characters involved (brachytic culms and liguleless leaves) occurred in all possible combinations with each other and with the cob and pericarp colors. Since the color of the cob and that of the pericarp were always alike on any given plant, it has been found convenient to refer to this character simply as the color of the cob. The distribution of the plants of the nine progenies for color of the cob and character of the culm is shown in table i . In each case the red cob color is found to be associated with normal stature which is the parental combination. Although the degree of association varies, the coefficient of association of 0.463 =t 0.038 for the entire group indicates a crossing-over percentage of 35.5. Practically the same percentage of "crossovers" was obtained from a cross between a Maryland red dent variety of normal stature with the white-cobbed strain of the brachvtic variation. The first generation plants of this cross, as in the liguleless- brachytic cross, were all normal in stature with red cobs and pericarps. 16 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 S Z O w o O u w z Vi o ** o O^^^^"— 'O"— ii— I"— !■""_ <^-H■H■tl■H^^-H^^■^^^ Tt* Tf< rf lO X i5 THE INAT c c 0 0 000 0 0 s i lo Tf 05 0 ^00 -+ CO *. o ♦^ y -i (M — (N (M (N CO (N d 41 ^ ■H -H -H -H -H 41 41 u < 9 9 LO 0 X lO LO C5 C s§ ^a :c -+ C CO CO i^ 0 LC 0 !>) !M CI ^ (N --1 (N ■-I 01 S PS < pL, fl, ._- -* -H Tj^ ic 0 iC CO X O zZ- « 22 ti'o ^ ^1 C~l CO CI C^ CO CO IM tt s e^ 41 ^ 41 -H -H -H -H 41 41 CI p u.ti X ro ■* -,0 0 X I^ 0 0 < U VJS K ^ ^ ^ &-> 0 ?o X Oi (M CO 0 -+ t^ < 'O w r* Oa CM (M - p 1— t w 5 l-l tt X < H H-} tH « C/2 ■3 I> -^ lO ^ t^ 0 X Tf 10 m Q m J .0 S "^ — 00 71 -1* (M t- 03 — < 2 O < r^ H < Z J w as o o > o < tt CC '-^ X I- -^ Si 'Oj -M t^ Ci « h4 ^« ^ w .3 O J 0-3 u 1-. H w ^ Vhite c Norm; statur 0 '— 0 CI -f r-H I- — i-t CI CI r-l It CI CI CI 0 w z •^'^0 •0 Kl •0 -t- •+ CO t- X LO WITH BETW -r c^i M r—\ LANTS y^BRID j3 r: iJ lC w X re iC CO t^ -5* a: ^H 3^ C^ L^^ XX-* 0 CO ^ X "C 0 ^ 'M ' ' o CQ M OS o 10 CO X CO o o 41 CO o o 41 35 O IM X o o 41 o X C) CO §Q Q < >< < O H tH CI W £; w (fi w z < a rv 2 fa ^ o K 2^ i- p 2 H PQ O u w Z o < 2 > >« K o < pq A.G a ,^ ,^Tj5 (M (M -H 1 -H -H ■H -H ^1 ■n -H 41 -H •^_ (M CO 00 T— t CO o i> CO q Tf t^MOI>O-*I>C0'-iO^ « uOCjlCl'-iCOCOCOOOO'C^ ■Scoa3cococoi>ioocoooo ^ CO Tl 1-H O -M oiiciccoG205iooocr. o; •513 Ji O g 3 ■"Sis O a! 1- •So2 lO t^cscoco-^ooo^coc^ CO CO --I "-* CO 0005O'-H 2 o fa o z o w z tt O Q 2 O U w CO w w p u B K fa O 2 W w 2 < (1| fa O 2 O >-< 1-" P n M OS ii (A fa n fa' p < lO 00 ^ CO in UO O CO (M O 00 lO C^ tT CO (M CO O lO IC (M ,-( a -H -H -H -H 00 -* CO t^ i> •* t^ CO "* O Tft CO o o o o CD c o ■^i 00 CO OJ3 11 C3 O CO CO 2 O 2 < (J < P5 PQ 2 ^ O— U o ca u V E ^ ■ - o *j J2— 1) O f^ 1- M Tl P H-T 00 I> CO CO (M (M 4i 4J ^ C-l 00 CO -^ C2 IC CO (N r- 1 CO GO CO LO Tjl --I CM CM ^ C5 ■>* CO --I CM t^ 00 1> CD Tji CD t^ C5 i-H 1— I 1— 1 H^ ^ h-t X CO CD o o ■H CO -H CM CD CM CO CO CO I> 00 o CO o 18 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 pa < H K < tn ►4 < s a o W '7. O a z o u w tn w > 2 o < g n o < tn J P U Q W > < w ^ S fa J O P w a < < (J £» 5 ° !^ z fa <; w z <: ■-I pL, fa o z o p 2 2 H >■ lo ^ fo o Lc t- re w •—! 9.0 " Sg c i^ --o o -t c c; o -H So Tji CO -* Li re ca •* Lc Tf OS -t (N -o ro 2 "^^ '-^ ^ ooooooooo a o >-1 CO 03 t^ -H LO --^ ro CO'^'-iC 2 P O ^ H w z n p3 t2 ^ H o z ^ < z w < p_l ^ w s < t/i fa o z o p n fa (/I CO O 0-1 Ol X X •-I CO CO -HCOCOXiCOCOt^OI LO'*-+^foro'*C'3o o 04 mi^ooqi-oxc^^x — lO CO " ^ CO ^ "* CO .-H (N ^ a o o -H o -H o o -H -H coo -f] -H "^ O-j ^ I- Gi CO CO CO O CO "O Ci O X 01 01 ,-1 (M (M CO CI — ' :C Ol CO LO V- bo tij -H O] ic --0 O -t cr. -^ -.C (M 04 01 O] 01 01 ^ 01 r-i O -Tf ^ -* 1-0 iC lO 01 w ■OrtOioicooioicocooi S^-H-H-H-H-H-H-H-H-H u;=i>co-*ocox:^'-'0 PU^ COCOXCiOCOO"*!^ oi oi 01 oi CO oi CO CO C4 O CO O -^ t^ O X •* lO LO Tt< — 1 X -t Ol 1^ O -^ ,0 3 CO »— ' Ol T— I .— 1 .—I t-Pi^ CO -r C o -.5 ■H >. o IQ *^ ^^ tr. X o X^ (-■ -H n c r- o u 01 C-* Ol -^^ o u X 2 .-— :^ o -H CJ -t-> Oi C Ol OJ +.< o XS X r- c^ .is Q .tl 3 oq o 0^1 o o CO ^ lO X 01 V. <4-l 01 T-H 1- c J= M ■*-' ^^ 1/ /2 2 " CO X o X 01 t- c I^ CO 1^ 8 a 3) :5n 1^ Ol rf T— 1 T Ol Ol Ol 01 CO is 5 oii :n t^ Ol IC T— i X T-H lO r— t ^ rt lO 01 -t 1-H CO OvI 1—1 1—1 r-1 c •O 3 01 V M «3 C3 J3 r^ Oil LO g (N 0^ X X CO t^ CO CO .-^ <^ 3 o T— 1 '^f^ CO CO ■vP ■* 1^ -* r' T3 M Ol rH t^ hn rt^ '7. tr, c >. OS £ T— ( 01 CO -t lO CO t^ X G-. o CJ H e to 0 ^ ►-I HH l-I h-! 1-4 h4 h4 h4 H o CJ p. u ^ JAN. 4, 1921 kempton: linkage in maiZE 19 In the first generation the plants showed a segregation with respect to cob color, half the plants having red, the other half white cobs, indicating that the red-cobbed parent was hetero- zygous for cob color. Four self -pollinated ears with red cobs were obtained and progenies of these had approximately three plants with red cobs to one with white. These four progenies are fairly uniform with respect to the Mendelian ratios. The distribution of the plants with respect to cob color and culm characteristics is shown in table 3. The percentage of "cross- overs" varies from 29.6 to 48.8 with an average for the group of 38.1. This percentage, though somewhat larger than in the other two hybrids, does not vary from them by an amount too large to be ascribed to chance. It may be concluded, therefore, that the genes for cob color and stature are located in the same chromosome and rather widely separated, the distance being between 31 and 43 units. The nine second-generation progenies of the liguleless X brachytic cross afford also an opportunity to measure the inter- relations of the leaf and culm characters. These nine progenies vary in the degree of relationship between the brachytic stature and the liguleless leaf. In all but one progeny the correlations were between normal stature and liguleless leaf which is the paren- tal combination. The classes of plants are shown in table 4. In the one exception the probable error does not preclude placing it with the others since the deviation from the mean of the group is but 2.5 times the error. The correlation of 0.204 ± 0.049 ^or the entire group indicates a rather loose linkage, the percentage of crossovers being 43.7. The deviation from independence or 50 per cent crossing over is slightly over 4 times the error. It would seem, therefore, that if the genes for these characters are located on the same chromo- some they are widely separated. If it is held that the genes for the brachytic and liguleless char- acters are located in the same chromosome 44 units apart it then follows from the relation of brachytic culms to cob color that the gene for liguleless leaves must be either 8 or 80 units from that for cob color. The classes of plants are shown in 20 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 table 5. It will be seen from this table that the relation of cob color to liguleless leaf is very erratic with a mean crossover percentage of 45.3, which is practically independence. It is possible, therefore, that the slight relationship of the leaf and culm characters indicated in table 4 is but the result of chance and that the genes for these two characters are borne in reality by separate chromosomes, though this point cannot be deter- mined definitely until some character is found that is independent of cob color and measurably correlated with brachytic culms. Literature cited. Bregger, T. Linkage in maize. The Caleurone factor and waxy endosperm. Amer. Nat. 52: 57-61. 1918. Collins, G. N., and Kempton, J. H. Inheritance of waxy endosperm in hybrids of Chinese maize. IV Conference Internationale de Genetique, Paris, 1911. Emerson, R. A. Genetic correlation and spurious allelomorphism in maize. 24th Ann. Rep. Nebraska Agric. Exp. Station, 1911. The inheritance of certain abnormalities in maize. Amer. Breeders Assoc, 1912. A fifth pair of factors, A a, for aleurone color in maize, and its relation to Cc and Rr pairs. Cornell Univ. Agric. Exp. Sta. Memoir 16. November, 1918. Kempton, J. H. A correlation between endosperm color and albinism in maize. This Journal 7: 146-149. March 19, 1917. Inheritance of spotted aleurone color in hybrids of Chinese maize. Genetics 4: 261-274. May, 1919. Jones, D. F., and Gallastegui, C. A. Some factor relations in maize with reference to linkage. Amer. Nat. 53. May, June, 1919. Lindstrom, E. W. Chlorophyll inheritance in maize. Cornell Univ. Agric. Exp. Sta. Memoir 13. Aug., 1918. JAN. 4, 1921 proceedings: philosophical society 21 PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIEvS PHILOSOPHICAL SOCIETY OF WASHINGTON 833rd meeting The 833rd meeting was held at the Cosmos Club, March 27, 1920. President Sosman presided and about 75 persons were present. The speaker of the evening was Dr. Saul Dushman, of the General Electric Co., who presented a paper on Methods for the production and measure- ment of extremely low pressures. The pressures dealt with under this heading range from one mil- lionth of an atmosphere (1 bar) to pressures lower than 10"^ bar. For the proper operation of a number of hot cathode devices, it is absolutely necessary to obtain pressures which are well below 10"- bar. The methods used for the production of high vacua may be classified for convenience under three headings: (1) Mechanical pumps, of which the rotary mercury or oil pump and Gaede molecular pump are typical illustrations. With the former, pressures as low as 10~^ bar can be attained, while the Gaede molecular pump is capable of producing vacua as high as 10"^ bar. (2) Mercury vapor pumps. The Gaede diffusion pump and Langmuir condensation pumps are both capable of producing extremely high vacua. The latter is, however, much more rapid in its operation. (3) Physico-chemical methods. By means of charcoal immersed in liquid air it is possible to obtain extremely low pressures in devices in which gas is being evolved continually either from metal parts or glass walls. The volatilization of calcium has been suggested by Soddy as another method for producing low pressures in sealed-off tubes. In the actual exhaust operations, it is of importance to consider the resistance to flow of glass tubes, as well as the speed of the pump. The laws of flow of gases at low pressures have been studied by Smolu- chowski and Knudsen and it is possible by means of the formulae de- rived by the latter to calculate the effect of glass tubing of given dimen- sions on the speed of exhaustion. Methods of measuring low pressures. — The McLeod gauge is the sim- plest but is not always applicable and is not very sensitive for pressures below 10~^ bar. Pirani and Hale have developed an electrical re- sistance method which is capable of measuring pressures as low as 10~" bar. The molecular gauge devised by Langmuir is sensitive to 10~^ bar, but is difficult to construct. Knudsen developed a radiometric type of gauge and various modifications of it have been designed by which pressures as low as 10"^ bar can be measured. The simplest method of measuring low pressures is the ionization gauge. This is very convenient for measuring the pressure in sealed-off hot cathode devices and incandescent lamps. 22 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 The paper was illustrated by lantern slides, and was discussed by Messrs. Burka, Foote, Sosman, McKeehan, White, Stimson, Mer- wiN, KIanolt, and WennER. Informal presentations: At the request of Mr. C. A. Briggs, Mr. W. J. Humphreys spoke briefly concerning the aurora of March 22, 1920. Mr. G. F. Hull described an unusual aurora which he had witnessed. 834th meeting The 834th meeting was held at the Cosmos Club April 10, 1920, with 50 persons present, and Vice-President Crittenden in the chair. The program was as follows: H. C. Dickinson: Physical laboratory methods applied to aircraft engines at high altitudes. A special laboratory equipped for making precise determinations of the various factors in the performance of aircraft engines under all con- ditions of operation was developed at the Bureau of Standards during the war. The methods of measuring power, heat and temperature distribution, pressure, densities, etc., are distinctly those of the physical laboratory. In addition to studies of engine performance, parallel investigations have been made of the problems of ignition, carburetion, cooling, lubrication, etc., for which special laboratory equipment has been provided. In connection with these researches, a number of special instruments have been designed. These include a balanced-diaphragm pressure indicator for recording engine cylinder pressures accurately by a point to point method; an instrument for measuring the clearance volume in engine cylinders ; and a device for measuring conveniently the maximum cylinder pressure. The paper was illustrated by lantern slides, and was discussed by Mr. Buckingham. M. D. Hersey: Old and new problems of aeronautic instruments. The speaker called attention to charts and instruments which had accumulated on this subject since the occasion of his last paper before the Society, which was the year before the war. The charts were as follows : 1. Rejection limits for aviation altimeters. 2. Temperature lag of aneroids. 3. The two temperature effects on instruments with elastic action. 4. Theory of groimd speed indicator. 5. Results of Venturi tube experiments in air and water. 6. Results of Venturi tube experiments in vacuum wind tunnel and on an airplane. 7. Dimensional theory of compass damping. 8. List of new problems awaiting solution as follows: (a) Stabilizer for ground speed indicators. (b) Air speed indicator for dirigibles. (c) True altitude meter. (d) Gyroscopic or double pivot compass. (e) Temperature compensated diaphragms with small elastic lag. JAN. 4, 1921 proceedings: archaeological, society 23 The instruments shown were as follows: 1. Vibration stand for instruments, together with Dr. Dickinson's vibrometer. 2. Precision altimeter. 3. Group showing evolution of rate-of-climb indicators. 4. Group of various Pitot and Venturi tubes. 5. Working model of Franklin stabilizer. 6. Air damped compass for dirigibles. 7. Working model of ground speed indicator. 8. Combination inclinometer, banking indicator and gyroscopic turn indicator in operation. Lantern sHdes were also shown as follows: 1. Certificates showing test results on aneroid barometers tested at the govern- ment laboratories of England, France, Germany and the United States. 2. A group of curves showing errors of aneroids. 3. Diaphragm investigation exhibit. 4. Dummy observer utilizing moving picture film for instrument observations in flight (3 views). The paper was discussed by Messrs. Crook and Tuckerman. S. J. Mauchly, Recording Secretary. ARCHAEOLOGICAL SOCIETY The 19 th annual meeting of the Washington Society of the Archaeo- logical Institute of America was held at the home of Mr. Robert Lansing on Saturday, November 13, 1920. Sir William Ramsay gave an illustrated lecture on An archaeological retrospect and prospect in Anatolia. The following officers were elected for the year 1921: President, Robert Lansing; Vice-Presidents, Robert M. Thompson, Miss Mabel Boardman, Henry White and Mrs. H. F. Dimock; Secretary, Mitchell Carroll; Associate Secretary, Miss Helen Wright; Trea- surer, John B. Larner; Councillors, Robert Lansing (ex-officio), Charles Henry Butler, Mitchell Carroll (ex-officio), William ^IiLLER Collier, F. Ward Denys, William P. Eno, William H. Holmes (ex-officio), John B. Larner, H. B. F. MacFarland, James Parmelee, J. Townsend Russell and Robert M. Thompson; Ex- ecutive committee, the above named officers and Albert Douglas, Miss Amaryllis Gillett, Gilbert Grosvenor, Martin A. Knapp, Charles Colfax Long and George Oakley Totten, Jr. Mitchell C.\rroll, Secretary 24 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1 SCIENTIFIC NOTES AND NEWS. A luncheon was given in the Smithsonian Building on November 16, in honor of the seventieth birthday of Dr. J. Walter Fewkes, chief of the Bureau of American Ethnology. Dr. J. Paul Goode, professor of geography at the University of Chi- cago, gave an address before the General Staff at the Army War College on November 12, on The geographic and economic foundations of the world war. Mr. Ralph W. Howell, geologist with the U. S. Geological Survey, was killed by native raiders in Beluchistan in the latter part of Novem- ber, 1920. He was engaged at the time in oil exploratory work for Pearson & Son of London, and was working near the Beluchistan- Punjab border in an area that had been considered safe from bandits. Mr. Howell was born in ISSG, and had been a member of the Survey staff since 1913. He was granted leave of absence from the Survey in October 1919 to engage in private work. He was a member of the Geological Society. A series of lectures on Heaviside's operational methods as applied to physical problems is being given at the Bureau of Standards by Professor A. Press. Rear Admiral Edward R. Stitt, of the Naval Medical Corps, has been appointed surgeon general of the Navy and chief of the bureau of medicine and surgery, Navy Department, succeeding Rear Admiral W. C. Braisted, who has been surgeon general of the Navy since 1914, and who went on the retired list in November. Dr. T. Wayland Vaughan, geologist in charge of the Coastal Plain section of the U. S. Geological Survey, is on leave for several months to engage in private work in Mexico. Prof. Bailey Willis, formerly geologist on the U. S. Geological Survey, and now professor of geology at Leland Stanford Junior Uni- versity, California, is spending several months in Washington. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 January 10, 1921 . No. 2 MINERALOGY. — Bemeniite and neotocite from western Washington, with conclusions as to the identity of bementite and caryopilite} J. T. Pardee, E. S. Larsen, Jr., and George Steiger, U. S. Geological Survey. Occurrence and association. Specimens representative of manganese-bearing deposits in western Washington collected in 191 7 and 191 8 by J. T. Pardee and examined microscopically and chemically by Messrs. Larsen and Steiger, respec- tively, are determined to be chiefly bementite, a hydrated silicate of manganese. The material was collected at the Black and White, Apex, Triple Trip and other mines and prospects along the north and south forks of Skokomish River, Mason County, Washington, and from A. V. Ginnett's prospect on Fidalgo Island south of Anacortes. Similar material was found by Prof. Henry Landes at the Tubal Cain mine west of Quilcene and is reported by others to occur on the mainland about 10 miles northeast of Anacortes and at a locality a few miles south of Lake Queniault. Most of these occurrences are within a narrow belt about 70 miles long that extends from the vicinity of Lake Queniault northeastward into the drainage area of Dungeness River and covers part of the eastern slope of the Olympic Mountains. The remainder, comprising the deposits near Anacortes, are about 60 miles further northeastward. This rather extensive occurrence of bementite in Washington is interesting in view of the fact that so far as known that mineral is rare elsewhere. Dana- mentions only one locality of its occurrence in America, namely, Franklin Furnace, New Jersey. 1 Published by permission of the Director of the U. S. Geological Survey. Received November 26, 1 920. - A system of mineralogy, ed. G, p. 704, 1914; third appendix to same, p. 12, 1915. 25 2'6 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 The belt in which bementite is found is part of a densely forested and extremely rugged area in which the local relief ranges from 2,000 to 6,000 feet or more. It has not been thoroughly prospected or even explored in detail, though most of it is within 15 or 20 miles of Puget Sound. From Hoodsport the deposits along the north and south forks of Skokomish River can be reached over a fairly good road and trails, but most other places in the belt are rather difficult of access. The rocks of the bementite area are chiefly greenstone, arkosic sandstone, argillite, and a deep red or maroon impure limestone that forms discontinuous layers and lenses. These rocks are steeply tilted and compressed and show the effects of regional metamorphism. The strike appears to be generally northeastward parallel with the distribu- tion of the deposits. The limestone contains poorly preserved fos- sils of minute foraminifera determined by Dr. T. W. vStanton as most probably belonging to the genus Glohigerina, which may indicate the rock to be Mesozoic or younger. The field relations show only that the rock group is older than the recognized Tertiary of the region. The deposits that contain the bementite are either inclosed by or closely associated with the limestone. They are tabular or lens- like bodies, commonly from 5 to 20 or 30 feet in thickness and to be measured in their other dimensions by hundreds or thousands of feet. Parts of them are a bright red jaspery-looking rock composed of fine- grained quartz and hematite mixed in various proportions. Locally this material grades into practically unmixed hematite. The remaining and commonly the larger parts of the bodies are chiefly a dense very finely crystalline rock that consists chiefly of bementite. No dense speci- men was found in which the bementite was entirely unmixed with other minerals, and the texture of the rock is so fine that a heavy- solution separation, as described further on, was found necessary to obtain material suitable for analysis. Much of the bementite rock, however, contains but a relatively small amount of other minerals and, therefore, its properties are essentially the same as those of the selected material to be described. The microscope shows the prin- cipal associated minerals to be quartz, rhodonite, and a carbonate near calcite and manganiferous calcite {n = 1.660 to 1.705), these minerals being intergrown with the bementite and also deposited in veinlets that cut it. Locally the bementite rock is cut by veinlets, visible to the unaided eye, that contain one or more of the minerals quartz, calcite, manga- JAN. \\\ lit21 PARDEE, LARSEN, & STEIGER: BEMENTITE 27 nocalcite, rhodonite, rhodochrosite, barite, and manganophyllite. At the Apex mine a dense, hard, fine-textured, dark green to black ma- terial composed chiefly of manganese oxides forms numerous irregu- lar streaks and bunches that are inclosed by the bementite rock. Under the microscope thin sections of this material show an irregular frame-work or skeleton of transparent bementite imbedded in the opaque oxides. The boundaries between the silicate and the oxides are sharp and the two appear to be of contemporaneous origin. The mineral species of the oxides has not been determined. A rather striking local feature of the bementite rock is its associa- tion with native copper. At the Black and White mine this metal is disseminated as fine specks and flakes through a considerable body of the bementite rock to which it imparts a noticeable red color. Similar, though less abundant, occurrences of copper were observed at Ginnett's prospect and a few places elsewhere. Very small amounts of chalcocite were also observed in specimens from the Black and White and other deposits in that vicinity. Some specimens of the bementite rock are cut by thin veinlets of dark brown to black amorphous neotocite, associated with calcite, quartz and barite. The principal weathering product of the ordinary bementite rock is a soft, dull black, amorphous manganese oxide. Weathered spec- imens of the copper-bearing rock commonly show a little green copper stain and specimens from the Black and White mine contain in addi- tion bright red coatings composed of felted aggregates of fine prisms of cuprite or chalcotrichite. The source of the manganese of the bementite rock or the form in which it was first deposited is not known. Its distribution along beds of limestone, however, suggests it to be of sedimentary origin, and the character of the deposits and of the rocks that inclose them indi- cates the bementite to be a product of regional metamorphism. The appearance of some thin sections makes it seem probable that the bementite was derived from a granular mineral, possibly tephroite, that was associated with more or less rhodonite. In some specimens veinlets of fresh rhodonite cut the bementite, in others crystals of rhodonite are embedded in the bementite, but these may represent veinlet cuttings and crystals associated with the mineral from which the bementite was derived and the rhodonite may have resisted de- composition. However, none of the minute veinlets of bementite 2S JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 was observed to cut the embedded rhodonite crystals and it may be that the rhodonite is later than and derived from the bementite. Much of the quartz is clearly later than the bementite and in places the bementite is largely replaced by finely crystalHne quartz. Some cal- cite and manganiferous calcite are also later than the bementite, as is also the copper. Physical properties. The fresh bementite is light gray or grayish brown in color, has a vitreous luster, and is transparent in splinters, but on weathering the color darkens and the material becomes dull and opaque, even in splinters. The mineral has a hardness of about 6 and a specific grav- ity of 3.106. It is tough and has a splintery fracture. It is decom- posed by hot acid, and fuses easily to a black glass. Under the microscope the mineral is seen to be in felted aggregates of fibers or plates. Most of it is very finely crystalline but in some parts the crystalhzation is coarse and tends to be spherulitic; tiny veinlets of more coarsely crystalline mineral, with elongation across the walls, cut the finely crystalline material. The platy crystals show a perfect cleavage with the acute bisectrix normal to the plates and cleavage. The optical character is - and the elongation is therefore +. The axial angle is near o. The indices of refraction are a = 1.624, /^ — 1-647, 7 — 1-647. Composition. A sample of several grams of bementite that was separated by heavy solutions from the manganese-bearing rock of the Black and White mine and, as shown by the microscope, contained not more than I per cent of impurities consisting of calcite and rhodonite, was analyzed by Mr. Steiger with the result shown in column i, table I . For the purpose of comparison, analyses of bementite from Franklin Furnace are given in columns 2 and 3 of table i, caryopilite in column 4, and inesite in columns 5 and 6. In table i are given the chemical analyses, in table 2 the molecular ratios, and in table 3 the molecular ratios reduced to 100. 1. Bementite, Olympic Range, Washington. Analyst, Steiger. 2. Bementite, Franklin Furnace, New Jersey. Analyst, Steiger. 3. Bementite, Franklin Furnace, New Jeisey. Analyst, Konig. 4. Caryopilite, Pajsberg, Wermland, »Sweden. Analyst, Hamberg. 5. Inesite, Dillenberg, Germany. Analyst, Barwald. 6. Inesite, Pajsberg, Wermland, Sweden. Analyst, Flink. JAN. 19, 1921 PARDEE, LARSEN, & STEIGER: BEMENTITE 29 TABLE 1. Analyses of Bementite, Caryopilite, and Inesite. SiO...... MnO... FeO.... MgO.. . CaO.... ZnO.... PbO.... Alkalies . AlsO.i... Fe203... mo--. . H20+.. ci Si02.. MnO. FeO.. MgO. CaO.. ZnO.. PbO.. AI0O3. FeoOs. HoO.. Si02... MnO''. H2O... AI2O3.. 1 2 3 4 5 6 39.92 38.36 39.00 36.16 43.92 43.67 41.58 39.22 42.12 46.46 37.87 37.04 4.15 4.94 3.75 0.69 1.11 4.46 3.35 3.83 4.80 0.33 0.15 0.40 0.62 2.93 Trace 2.86 0.28 0.37 0.20 8.40. 9.38 0.77 1.32 0,96 0.71 0.35 1.33 0.29 0,49 7.90 0.60 1 8.01 J 8.44 \ 9.81 0.09 . 4.54 \ 4.68/ 7.17 100.22 99.70 100.00 99.85 100.72 TABLE 2. Molecular Ratios. 99.29 665 639 650 603 732 728 586 550 593 654 533 522 57 69 52 10 15 112 84 96 120 8 4 7 11 36 35 5 1 150 168 3 13 9 5 3 8 3 439 444 469 545 512 398 Molecular Ratios OF Table 2 Reduced to 100. 35.40 34. 61 34, ,30 31. 10 37.59 39.62 40. 55 40. 62 40. 95 40. 22 35.98 38.74 23. 36 24.07 24.75 28. 12 26.28 21.64 0 69 0. 70 0. 56 0.15 100.00 100.00 100.00 100.00 100.00 100.00 ''Under MnO have been summed up the molecular ratios of MnO, FeO, IMgO, CaO, ZnO, and PbO. The average molecular ratio of the three analyses of bementite is 4O.7Mn0.24.iH20.34.8Si02, and agrees very nearly in composition with the formula SMnO.sHsO.ySiOo. Written in the rational form this formula becomes SMn.io H.ySi. 27O or 5MnH2Si04.MnoSi04.MnSiO3. Leaving out water leads to the rather more simple rational formula 8Mn.7Si.22O.5H2O, or 6MnSiO3.Mn2SiO4.5HoO. Identity of bementite and caryopilite. The distinction between bementite and caryopilite has been based 30 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 a -S o w o "If CD (M en S o .t: ^ "^ PI < w o w I- < w Q < W W S w pq fa o (fi H w cu o y CO 'u ^ O O CI to 05 ■^ S - "^ 2 y 4J o CS 3 O CO o ■^ro CO 00 . o ocD- ^-r. y bo o en CS ctf W o , JO "y oi be o CO "u^i^ p. y i2 y y y o Q y .2 cS u y 3 u y tic s y S.2 2^ +^^2 P. y O CO y 0! 03 O (M "O y o rC oJ "y o 3 Q S-2 y q ..■5 2 y S £f II 9 o oi lO oq CD tn ctf Ui y ■a o cfl y t^ 0 O y o. c« 3 y o tn > 43 . yi2 00-S o ^ bfl ;« ? T ^ y o X y ■(-> d « rt o y -u >< in y ■i-> . 05 y -^ a u O C H o y bo > y O tn y _ h . tn 3 o y « y y d CD Tf lO o CO -t^ CO CD CO CD O CO IM (M 35 O CO CO IM CD CD CD O -t< b- 1^ CO (M ■+ '^ (M CO CO CD O -h O OCO , 1921 PARDEE, LARSEN, & STEIGER! BEMENTITE 31 dices of refraction of the caryopilite are not sufficient to cast any- serious doubt on the identity of the two minerals. The name bemen- tite has the priority, and should be retained for the species. The composition of the inesite and ectropite is much like that of bementite, but their other properties are sufficiently different to dis- tinguish them. NEOTOCITE. Occurrence and properties. The neotocite is present in small veinlets cutting the bementite. It is brown to black, has a clear, resinous luster, and a cpnchoidal frac- ture. It is brittle and has a hardness of about 4. Under the micro- scope it is clear red-brown in transmitted light, isotropic, and has an index of refraction varying from 1.45 to 1.50 and averaging about 1.47. For comparison, neotocite from vSweden was examined. It is black, has a conchoidal fracture, and a vitreous luster and looks like coal. It is brown in powder and in transmitted light under the microscope is clear brown. In part it is isotropic with an index of refraction varying from 1.53 to 1.56, in part it is birefractory with a mean index of refraction varying from 1.54 to 1.58 and a birefringence of about 0.02. The birefractory part is clearly crystallized from the amorphous part and its variable properties are probably due to incomplete crystallization giving submicroscopic admixed amorphous material. The crystalline part is probably bementite. The name neotocite should be confined to the amorphous mineral having the approximate chemical composition MnO.vSiO2.wH2O while bementite should be applied to the crystalline mineral (8 MnO.7 SiO^-S HoO). In common with most amorphous minerals, the composition of neo- tocite is much less uniform than is that of the crvstalline form, be- mentite. Composition . A chemical analysis made of powder separated from admixed quartz and calcite by heavy solution and carrying a small amount of impur- ities is shown in tables 5 and 6. 1. Neotocite, Olympic Range, Washington. Analyst, Steiger. 2 and 3. Neotocite, Gestrickland. Analysts, Cleve and Nordenskiold. 4 and 5. Stratopeite, Pajsberg. Analysts, Cleve and Nordenskiold. 6. Hydrated manganese silicate, near neotocite, from Dillenberg mining region, Germany, described by A. Schneider.'' The mineral dissolves readily in i : i hydrochloric acid with sep- ^ Jahrb. Preuss. Landesanstalt, 472 et seq. 1887. 32 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 aration of sandy silica. The figures shown in table 6 roughly sug- gest a ratio of R"0 to SiOo, of i : i, with a variable quantity of water. However, the chemical composition must be considered very doubtful. TABLE 5. Analyses op Neotocite, Stratopeite, and a Mineral Near Neotocite- 1 2 3 4 5 6 Si02 37.15 35.79 34.38 35.05 35.83 35.64 AI2O3 \ 2.58" / 1.57 2. 59 FesO., / \ 10.90 18.58 1.36 8.20 3.02 MnO 37.00 20.51 22.67 38.49 29.37 39.26 MnOa 2.03" FeO 13.93 2.88 MgO 2.82 2.86 2.44 0.52 2.50 5.27 0.47 8.66 1.31 CaO * 1.75 H2O + 1 f 8.48 9.30 9.81 10.03 1 HoO— 1 14.07 2.10 \ 7.29 8.07 6.91 6.08 J 13.94 CO2 } 0.60 PbO ' 3.31 2.13 100.61 99.86 99.95 100.67 100.30 98.11 ° Part or all of the iron may be present as FeO in which case a correspondingly large part of the manganese will have the form of Mn02. TABLE 6. Molecular Ratios Reduced to 100. SiO: .30.3 28.6 27.4 R2O3 3.5 3.2 6.3 R"0 28.0 26.3 20.2 H2O 38.2 41.9 46.1 26.6 27.3 29.6'' 0.4 2.3 2.2'' 31.7 29.4 29.9* 41.3 41.0 .38.. 3^ 100,0 100.0 100.0 100.0 100.0 100.0 *" Ratios after deducting calcium carbonate equivalent to CO-. PALEONTOLOGY. — Shell regeneration in aPennsyhanian brachiopod.^ W. Armstrong Price, West Virginia Geological Survey. (Com- municated by Sidney Paige.) The accompanying photograph, figure i, shows an area of abnormal sculpture upon the interior surface of a pedicle valve of Derbya crassa (Meek and Hay den). The specimen consists merely of the impres- sion of the interior of the valve in a fine-grained, calcareous sand- stone. It was associated with numerous impressions- of normal shells of this species and with other marine invertebrates. 1 Published with the permission of the Superintendent of the West Virginia Geological Survey. Received December 13, 1920. 2 In gray, sandy .shale collected by Mr. David B. Reger, from the Kanawha Black Flint horizon of the Kanawha Group of the Pottsville Series near Summit Station, Web- ster County, West Virginia. JAN. 19, 1921 PRICE: SHELL REGENERATION IN A BRACHIOPOD 33 I . Description of abnormal sculpture. — The area of abnormal sculp- ture extends from the front margin inward, beyond the center of the shell, for about three-fifths the height and is lobate in outline. It is expanded in the central region where it is sharply defined and has a semicircular border. The lateral borders are somewhat irregular and abnormal sculptural elements (costae) are superimposed upon the normal sculpture in these regions. The megascopic sculpture of the abnormal area con- sists of two elements. Radiating costae of normal size extend inward from the front margin where they are parallel to each other and are rather evenly spaced at the normal in- terval for this portion of the shell. Slight irregu- larities in spacing appear. Fig. 1. Impression of the interior of a pedicle The costae diverge inward, valve of Derbya crassa (X P/s) showing an area of the divergence being ac- abnormal sculpture. From the collection of West cglgj-ated in amOUnt bcVOUd A'irginia Geological vSurvey, locality 203. i r- i i • " ,* the nrst undulation oi growth. They increase irregularly in number toward the central region of the shell by the interpolation of smaller costae in such a manner as to produce a fasciculate distribution. Both the fasciculate design and the irregularity of the interpolation are abnormal in this species. The undulations of growth of the normal portion of the shell which intersect the abnormal lobe are continued with unequal distinctness across it. Faint transverse lines, sharply convex toward the back, cross the costae at three points, each originating just beyond one of the growth undulations of the normal portion of the shell. They appear to be weak undulations of growth. The minute granular projections which covered the interior sur- face of the shell were finer upon the abnormal area than upon the nor- mal shell. The abnormal lobe has the appearance of a patch placed over a hole of somewhat irregular outline and slightly overlapping the edges 34 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 1 1 , NO. 2 of the shell around the hole. Along the overlapped margin the cos- tae are arranged in a cross-hatched design. It is possible that the original break was much smaller than the lobe of reversed sculpture and it may possibly have been subcircular in outline. Along a por- tion of the inner and lateral borders the "patch" appears to have overlapped the edges of the break and to have failed to meet the shell smoothly where a gaping crack in the mold appears to denote an irregular ridge which joined the two. 2. Origin of abnormal lobe by regeneration. — The irregularity of the sculpture of the "patch" and its lack of resemblance to that of any of the associated organisms exclude the possibility of its being merely a portion of another shell pressed against the shell of the derbya or adhering to it. It seems most certainly to be an instance of regen- eration, or replacement of a broken portion of the shell. The mantle must also have been damaged by the breaking away of the shell and this injury probably supplied the stimulus which brought about the regenerative growth. The new growth was thus partly a pathologic phenomenon. 3. Origin of the injury to the shell. — How such a break in the shell may have been caused is not altogether clear. The absence of peb- bles and coarse sand in the sediment which enclosed the shell de- notes comparatively quiet waters and eliminates the likelihood of its having been caused by the pounding of shells, or shells and stones, by wave action. The break appears to have been irregular in outline, and unlike the neat round holes drilled in modern shells by boring snails. It is possible that an enemy among the fish was responsible for the injury. 4. Mode of regenerative shell growth. — From the inward divergence of the costae of the regenerated shell it seems likely that the new shell material grew in the direction of divergence across the break and that the growth did not begin simultaneously all over the damaged area. Increase in extent in the normal shell is in a forward direction, and it is probable that, as in the case of the Pelecypoda, as the thickened margin of the mantle is advanced by mantle growth it deposits the larger bulk of the shell material. In the case of the shell which we are studying, it would appear that the direction of growth was re- versed. Since we have no way of knowing the extent to which the mantle was damaged we cannot determine the method by which it replaced the shell. It is conceivable that the thickened margin may JAN. 19, 1921 PRICE: shell regeneration in a brachiopod 35 have become inverted by reason of the pathologic condition of the mantle and that it reformed the shell by inward growth. By whatever means accomplished, a layer of new shell substance was spread across the break, overlapping the edges of the old shell, and was deposited in part upon its inner surface. While the regenerative growth appears to have been abnormal in direction and in the pattern of the resulting sculpture, yet the costae are normal in size and only slight irregularities in spacing were pro- duced. 5- Rate of regenerative shell growth. — The rate of shell replacement was sufhciently rapid to complete the patching before the death of the animal. 6. Time of the injury. — It may properly be inquired whether the supposed break in the shell occurred before or after the shell had attained its present height. It seems possible that the break may have taken place when the shell had grown only to the last undulation of growth posterior to the present front margin, or to some point between these two lines. The unbroken continuity of the costae of the "patch" up to the present margin without the interpolation of new costae anteriorly suggests that the shell did not grow appreciably in length after the "patch" was completed. A slight anterior diver- gence of the costae of the "patch" at the border of the present margin may indicate a little forward growth. If such growth did occur, it may have taken place while the regeneration was in progress. There appears to be no indication as to whether the injury was sufficient to affect the rate of general shell growth as the shell is within the limits of the common adult size for the species. Summary of conclusions. — The impression of a pedicle valve of Derbya crassa from the Pottsville Series shows a lobate area upon the interior surface in which the normal direction of costal divergence is reversed. 1 . The costae of this lobe are fasciculate, a feature foreign to the species. The inwardly diverging costae overlap the normal costae in places. Other minor details of abnormal ornamentation are noted. 2. The abnormal lobe is not a portion of a foreign shell but was regenerated by the animal following a break in the shell. The mantle also was probably damaged. 3. The origin of the injury to the shell is problematical. The en- closing sediment was deposited in quiet waters. If the injury was caused by an enemy of the brachiopod, the form of the "patch" gives 36 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 no clue to its identity. It is suggested that a fish may have been responsible for the damage. 4. The direction of costal divergence is taken as the direction of progressive shell growth in the regenerated area. The precise mode by w^hich the shell was rebuilt is obscure. 5. Regenerative growth was sufficiently rapid to complete the "patch" before fatal damage was done to the exposed animal. 6. The injury probably occurred when the shell had very nearly reached its present size, or at least had reached the first growth undulation posterior to the margin. JAN. 19, 1921 PROCEKDINGS: PHILOSOPHICAL SOCIETY 37, PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY OF WASHINGTON 835th MEETING The S35th meeting was held at the Cosmos Club, April 24, 1920, with President Sosman in the chair and 40 persons present. The program was as follows: W. H. SouDER and C. G. Peters: Physical properties of dental materials (presented by Mr. Souder). This paper, which was illustrated by lantern slides, has since been published in full in Dental Cosmos for March, 1920. It was discussed by Messrs. A. W. Gray, White and Humphreys. H. A. Marmer : Results of recent tidal current investigations. In the past few years, current obser^-ations have been secured from the Light Vessels stationed on the Atlantic and Pacific coasts of the United States, from five to forty miles offshore. The instruments employed were necessarily of the simplest character. A log line, a fifteen-foot current pole, a sandglass or stop watch, and a pelorus constituted the whole outfit. Observations were made hourly, both night and day. The results of these observations show that on the Atlantic coast, in the inland waters and close inshore along the coast, the tidal currents are of the simple rectilinear or reversing type; that is, the flood runs for a period of about six hours in one direction and the ebb for a like period in the opposite direction. Also, the two floods and the two ebbs of the tidal day are very nearly alike. The curve of velocities, therefore, is approximately a sine curve and the times of slack, and of flood and ebb strengths bear a nearly constant relation to the times of local high and low water. Farther ofl"shore, the currents on the Atlantic coast become more com- plex. Instead of flowing in the same general direction for a period of six hours, and in the opposite direction for a like period, the current constantly changes directions, clockwise, at such a rate that in a little over twelve hours it will have veered completely around the compass. That is, the current is rotary instead of being rectilinear. In a tidal day, therefore, the curves representing the velocity and direction of the current will appear as two ellipses, bearing a close resemblance to each other in every respect. The rotary current is distinguished from the rectilinear current not only by the constant change in direction, but also by a difference of behavior in the change of velocity. In the rectilinear type, the current starts from a slack or period of no motion and gradually increases until it attains a max- imum, after which it decreases to another slack. In the rotarj?" current, there is no period of slack; the current is running at all times. There is, however, a maximum and a minimum velocity, corresponding to half the major and minor axes of the ellipse representing the curve of velocities. This rotary type of current having a circuit of approximately twelve hours and the two circuits of the day being very much alike, is typical of the off- shore current of the Atlantic coast of the United States. 38 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 On the Pacific coast somewhat similar conditions obtain. The currents close inshore are of the rectilinear type, while those offshore are of the clock- wise rotary type. However, the two current curves of a tidal day are gen- erally quite different. This is due to the diurnal inequality present in the tides of the Pacific coast. The diurnal inequality is largely a function of the moon's declination. It therefore varies throughout the month, being at a minimum when the moon is on the equator and a maximum when the moon is furthest north or south. The effect of this on the rotary current is to make the two cir- cuits of a tidal day very nearly alike when the moon is on the equator, but quite unlike when the moon is farthest north or south. The paper was illustrated with lantern slides, and was discussed by Messrs. White, C. A. Briggs, Tuckerman, O. S. Adams, Humphreys, Beall, McKeehan, Bowie and Hawkesworth. In reply to questions by Messrs. White, Humphreys and Adams, it was brought out that the relation of strength of current to time of high and low^ water varies greatly; that the motion of tidal currents is in the same direction from surface to bottom, and that the direction of rotation of the rotary current is conditioned by local causes. S3GTH meeting The S36th meeting was held at the Cosmos Club, May S, 1920, with President Sosman presiding and 30 persons present. The program was as follows : F. B. Silsbee: Physics of the high-tension magneto. Magnetos for igniting internal combustion engines have been gradually evolved in parallel with the development of the engines on which they are used, and the present high-speed, high-compression engines have led to the development of the present so-called "high-tension magneto." This is an extremely complex electrical system and the complete details of its opera- tion are relatively little understood even by the manufacturers of the ap- paratus. The speaker described the results of a study of this type of device carried out at the Bureau of Standards in connection with the developing and test- ing of aircraft engines. The results of this study have been published in Report No. 58 of the National Advisory Committee for Aeronautics. The cycle operations of the magneto can be divided into a number of periods during each of which the electrical phenomena proceed under fairly definite conditions, but each of which is separated from the one preceding and the one following it by a change of conditions, such as the opening of the primary contact or the breaking down of the spark gap. Some of these periods, such as the building up of the primary current can be studied by means of the oscillograph, but others, such as the rise of voltage after "break" are so short that this instrument cannot record the phenomena. The paper was illustrated by a number of oscillograms showing both normal and abnormal performance of ignition apparatus. Discussion: The paper was discussed by Messrs. C. A. Briggs, White, Sligh and Sosman. C. Nusbaum: The magnetic reluctivity relationship as related to certain structures of an eutectoid carbon steel. The magnetic reluctivity p, defined as the ratio of the magnetizing force to the induction, has been shown by Kennelly to be related to the magnetizing force by the relationship JAN. 19, 1921 proceedings: philosophical society 39 p = a + /3// (1) but for high inductions this has to be modified to H B - H = «, + m (2) where p^ is the metalHc reluctivity and B — H is the metalhc induction or flux carried onl}' 1)y the molecules of the metal. For pure and well-annealed materials the reluctivity line is a straight line while in the more or less im- pure commercial materials the reluctivity line while approximately a straight one has generally a point where its slope changes. Since the change in the slope of the line is in general greater with the increase in impurity of the material the cause is evidently a lack of homogeneity; /. e., the presence in the substance as aggregates or inglomerates of materials of different mag- netic characteristics. Although the arrangement of the constituents in a carbon steel is generally a random one, it may be considered as combinations of any of the three simple arrangements; viz., (a) the parallel, (h) the series, and (c) the spheroidal. In the experiments described in the present paper, two specimens of an eutectoid carbon steel (0.S5 per cent carbon) were selected and turned down to a uniform diameter of approximately 7 mm. Each of these specimens was quenched from iSO()° C, one in oil, the other in water, and then care- fully groimd down to (> mm. Each specimen was then cut in halves desig- nated A and B, which were then drawn alternately to increasingly higher temperatures up to 700° C. Normal induction curves, up to values of the magnetizing force as high as 2500 gauss, were determined after each op- eration. Curves for a few of these heat treatments were shown. Other magnetic properties shown graphically were (a) the values of the induction for con- stant values of the magnetizing force as plotted against the drawing tem- peratures; (6) the reciprocals of the susceptibility (47r times the reluctivity) as plotted against the magnetizing forces; (c) the value of the saturation intensity of the magnetization as plotted against the drawing temperatures ; and {d) the values of the "magnetic hardness" as plotted against the draw- ing temperatures. Referring to equation (2) the values of the saturation intensity of magnetization are equal to — -- ; i. e., the reciprocal of the slope 47rp of the reciprocal of susceptibility line. The values of the "magnetic hard- ness" are the values of a; i. c, the intercept on the axis of ordinates. These two characteristics are those with which this paper is most concerned, since they show more than any others the transformations which take place in the steel as a result of the heat treatment. It is found that in a region included by the quenched condition and a drawing temperature of 230° C, in which the specimen is known to be martensitic in structure there is a distinct bend in the reluctivity lines and consequently there are two values of the saturation intensity of magnetization and the "magnetic hardness" as calculated from the upper and lower portions of the reluctivity line. In the range of drawing temperatures bounded by 230° C. and 470° C, in which the steel is troostitic, the reluctivity line has but one slope, hence the satura- tion intensity of magnetization and the "magnetic hardness" each have but one value for a given drawing temperature and the material is magnetically homogeneous. Beyond 470° C. the reluctivity line again has a bend and 40 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 the material is non-homogeneous, this inhomogeneity being due to the in- creasing size of the aggregates and to their approaching stratification. The paper was illustrated by lantern slides. Discussion: This paper was discussed by Messrs. Sosman, C. A. Briggs, SiLSBEE, Tuckerman, and Humphreys. S. J. Mauchly, Recording Secretary. CHEMICAL SOCIETY (Local Section of the American Chemical Society.) 268th to 300th meetings The 268th meeting was held at the Cosmos Club on February 8, 1917. F. A. McDermott presented a paper on Some experiments on the growth of yeast in synthetic media. The pioposed "code of ethics" for the chemical profession was discussed. Messrs. HillEbrand, Buchbinder and others informally discussed current experience with so-called "analyzed chemicals." The 269th meeting was held at the Cosmos Club on March 8, 1917. Co- ordination of action among the local sections of the American Chemical Society was discussed informally. The regular program was as follows: F. B. La Forge: Sedoheptose, a new sugar from Sedum spectabile. E.C. McKelvy: Composition and testing of commercial liqiiid ammonia. D. R. Harper, 3d : Work on the thermodynamic properties of ammonia at the Bureau of Standards. The 270th meeting was held at the Cosmos Club on April 12, 1917. Pro- gram: W. M. Clark: Indicators and the hydrogen electrode in the service of bacteriology. J. N. Currie: Citric acid fermentation of Aspergillus niger. L. E. Wise: Elementary organic analysis by micro-combustion methods. F. R. Bichowsky: The electrometric determination of zinc. The 271st meeting was held at the Cosmos Club on April 20, 1917. Prof. Marston T. Bogert of Columbia University, Chairman of the Chemistry Committee of the National Research Council, spoke upon Chemistry and the war. The aims and purposes of the Research Council in peace and war were discussed with special reference to chemistry. The 272d meeting was held at the Cosmos Club on May 10, 1917. Program : H. D. GiBBs: Catalysis of some oxidation reactions. J. B. TuTTlE and L. YuROW: Direct determination of rubber by combustion of the nitrosite. I. K. Phelps and H. E- Palmer: Separation and identification of lactic acid in biological mixtures. The 273rd meeting was held at the Cosmos Club on October 11, 1917. Program: W. D. Collins: Arsenic in sulphured food products. C. C. McDonnell: Investigations on lead arsenate. F. P. Veitch: Investiga- tions of shoe soling material. The 274th meeting was held at the Cosmos Club on November 8, 1917, and was devoted to the annual election of officers for the ensuing year. The election resulted as follows : President, Frederick B . Power ; Secretary, E. C. McKelvy; Treasurer, F. P. Dewey; Members of Council of American Chemical Society, C. O. Johns, A. Seidell, F, W. Smither, R. B. Sosman; Members of Executive Committee, F. C. Cook, P. B. Dunbar, E. H. Inger- SOLL, M. J. Ingle, E. C. Lathrop, F. A. Wertz. The 275th meeting was held at the Cosmos Club on November 19, 1917. Prof. C. A. Kraus lectured on Laboratory methods and apparatus. JAN. 19, 1921 proceedings: chemical society 41 The 276th meeting was held at the Cosmos Club on December 13, 1917. Program: AtherTon Seidell: Utilization of the adsorptive power of fullers' earth for chemical separation. Oswald Schreiner: The potash situation in relation to food crops. The 277th meeting was held at the Cosmos Club on December IS, 1917. Prof. W. D. Bancroft lectured on Contact catalysis. The 27Sth meeting was held at the Cosmos Club on January 10, 1918. The retiring president, C. S. Hudson, delivered an address on American sources of supply for the various sttgars, illustrated with samples of sugar- bearing products and purified sugars. The 279th meeting was held at the Cosmos Club on February 14, 1918. Program: Grinnell Jones: The work of the Tariff Commission and its relation to the chemical industries. D. B. Jones: The hydrolysis of kafarin. The 2S0th meeting was held at the Cosmos Club on March 14, 1918. Program: J. F. Norris: The activity of certain elements in carbon com- pounds. H. A. LuBS. Determination oi the products formed in the chlorina- tion of toluene. C. J. West: The chemistry of the unsaturated lipoids. The 2Slst meeting was held at the Cosmos Club on April 11, 1918. Pro- gram: C. W. Merrill: The ammonia program for igi8. E. C. Mc- Kelvy and A. Isaacs: N on-condensing gas formation in ammonia absorp- tion machines: its cause and prevention. The 2S2d meeting was held jointly with the Washington Academy of Sciences at the Interior Department. Prof. A. A. NovES lectured on The nitrogen problem in relation to the war. The lecture has been published in the Journal of the Academy.^ The 2S3d meeting was held at the Carnegie Institution on November 14, 1918. Program: Roger Adams: The preparation of organic chemical reagents. C. L. Alsberg: The value of a museum of chemical compounds. Reports on the general meeting of the Society at Cleveland, Ohio, were presented. The 284th meeting was held at the Carnegie Institution on December 12, 1918, and was devoted to the annual election of officers. The following were elected: President, Atherton Seidell; Secretary, E. C. McKelvy; Treasurer, F. P. Dewey; Members of Council, American Chemical Society, C. O. Johns, John Johnston, F. B. Power, F. W. Smither, R. B. Sosman, F. A. Wertz; Members Executive Committee, W. Blum, F. C. Cook, P. B. Dunbar, F. F. Fitzgerald, M. J. Ingle, R. C. Wells. A series of reconstruction proposals, prepared by the local council, were approved for submission to the December meeting of the Council of the general Society. The 2S5th meeting was held jointly with the Washington Academy of Sciences at the Carnegie Institution, on Thursday, January 9, 1919. The retiring president of the Chemical Society, Dr. F. B. Power, gave an illus- trated address on The distribution and character of some of the odorous prin- ciples of plants. This has been published elsewhere.^ The 2S6th meeting was held at the new assembly hall of the Cosmos Club on January 23, 1919. Program: W. H. Smith: Airplane dopes. R. N. Harger: The -preparation of metol. J. D. Davis: The removal of phos- phine from ammonia made from cyanamide. The appointment of the fol- ' This Journal 8: 381-394. 1918. - Journ. Ind. Eng. Chem. ii: 344-352. 1919. 42 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 2 lowing committees was announced: Programs: ]. C. Hostetter, W. M. Clark, F. F. Fitzgerald, L. J. Gillespie, C. O. Johns, G. A. Rankin, E. R. Weaver, R. C. Wells, L. E. Wise; Entertainment: F. F. Fitzgerald, F. R. V. BicHowsKY, P. J. DoNK, A. M. Heinzelman, H. a. Lepper, J. H. Shrader. The 287th meeting was held at the Cosmos Club on February 13, 1919. Lieut. Col. A. H. White lectured on The present status of the nitrate industry in the Inited States. The 2S8th meeting was held at the Cosmos Club on February 27, 1919. Dr. John Johnston lectured on The National Research Council. A general discussion followed on the proposed plans of the Society for compendia of chemical and physical constants and for technologic and scientific mono- grams. The 289th meeting was held at the Cosmos Club on March 13, 1919. Col. A. B. L.'VMB lectured on Chemical protection against poisonous gases. The 290th meeting was held jointly with the Washington Academy of vSciences at the Cosmos Club, on March 27, 1919. Dr. Arthur L. Day lectured on Optical glass. An abstract of the lecture has been published in the Journal of the Academy.'' The 291st meeting was held at the Cosmos Club on April 1.5, 1919, and was devoted to reports on the general meeting of the Society at BufiFalo, New York, April 7-10, 1919. The 292d meeting was held at the Bureau of vStandards on April 24, 1919, and was preceded by a dinner served at the dining-room in the West Build- ing. Dr. W. F. Hillebrand described the plans and construction of the new Chemistry Building of the Bureau. The, remainder of the evening was devoted to an inspection of the building and apparatus. The 293d meeting was held at the Cosmos Club on May 8, 1919. Program : Charles L. Parsons: The oxidation of ammonia. AllErton vS. Cush- man: 7 he chemistry of military primers. The 294th meeting was held at the Cosmos Club on May 22, 1919. Pro- gram: H. D. Gibes: The work of the color laboratory of the Bureau of Chemistry. K. P. Monroe: 7 he commercial preparation and some of the commercial applications of the enzyme invertase. The 295th meeting was held at the Cosmos Club October 9, 1919. Pro- gram: E. K. Nelson: Vanillyl acyl amides. A. J. Finks: Growth ex- periments with the proteins of the navy bean. L. I/. Steele and F. M. Wash- burn: A new hexabromide method for linseed oil. W. M. Clark and F. F. ZollER: Manufacture of commercial casein. The 29Gth meeting^ was held at the Cosmos Club on October 23, 1919. Program: R. E. Rose, of E. I. Du Pont de Nemours and Company: The status and prospects of the dye indtistry in the United States. The 297th meeting was held at the Cosmos Club on November 13, 1919. Program: E- T. Wherry: Crystallography in the service of the chemist. E. T. Allen: A new method for the study of fumaroles. Officers for 1920 were elected, as follows: President, C. O. Johns; Sec- retary, E. C. McKelvy; Treasurer, F. P. Dewey; Members of Council, American Chemical Society, W. D. Collins, F. B. Power, A. vSeidell, F. W. Smither, R. B. Sosman; Members Executive Committee,"!^. H. Adams, F. C. Cook, P. B. Dunbar, M. J. Ingle, W. W. Skinner, R. C. Wells. 3 This JouRNAi, 9: 60.3-604. 1919. JAN. 10, 1921 proceedings: chemical society 43 The 298th meeting was held at the Cosmos Club at 8 p.m. on Tuesday, November 25, 1919. Dr. Charles H. Herty, who had just returned from Europe, where he had been sent with the approval of President Wilson, to secure for the American dye consuming industry a six months' supply of \at dyes from stocks held by the Reparations Commission under the terms of the Peace Treaty, addressed the Society on his interesting experiences. The 299th meeting was held at the Cosmos Club at S p.m. on Thursday, December 11, 1919. Air. R. S. McBride was appointed Secretary pro tern. Program: S. L. Jodidi: The quantitative determination of amino acids, polypeptides, and similar compounds, and their relation to certain plant dis- eases (illustrated). C. S. Cragoe, C. H. Meyers, and C. S. Taylor: The vapor pressure of ammonia (illustrated). The latter part of the meeting was devoted to an appreciation of the hfe and work of the late Secretary of the Society, Mr. E. C. McKelvy, who died on November 29 from burns received in an accident at the Bureau of Standards. The 300th meeting was held at the Cosmos Club at 8 p.m. on Thursday, January S, 1920 Mr. J. B. Reed, of the Bureau of Chemistry, was elected Secretary to succeed the late E. C. McICelvy. The meeting was planned as a commemorative meeting, and the papeis presented were concerned with the organization and early history of the Society. H. W. Wiley, foimerly chief of the Bureau of Chemistry; F. W. Clarke, of the Geological Survey; and F. P. Dewey, of the Bureau of the Mint, gave informal talks, illustrated with early programs, letters, and photographs. R. S. McBride, of the Bureau of Standards, outlined the work of the Society during the past ten j^ears. J. B. Reed, Secretary. SCIENTIFIC NOTES AND NEWS The Pick and Hammer Club met at the Conference Room of the Geological Survey on December 18, 1920, at 8 p.m. The following papers were pre- sented: A. H. Brooks: The Society of Economic Geologists; its origin and its proposed scope of work. David White: Recent meetings and scope of some kindred societies. W. C. Mendenhall : Land classification work under the recent leasing hill. The Washington Branch of the Society of American Bacteriologists met on December 20 at the District Building. Papers were presented by Chari^es Thom, Ruth B. Edmondson, C. L. McArthur, W. D. Bigei^ow, and P. H. Cathcart. The Agricultural History Society met on December 16 at the Public Library. G. K. Holmes spoke on The history of tobacco and O. C. Stine on Agriculture of the Plymouth Colony. Engineering Council held its last meeting in Washington on December 16, having recommended to its parent body, the United Engineering Society, that it be discharged from service and that its current and unfinished busi- ness be referred to the new American Engineering Council, the governing body of the recently organized Federated American Engineering Societies. Dr. W. W. CoBLENTz of the Bureau of Standards has been awarded the Janssen medal of the Academic des Sciences, Institute de France, for his work on the infra-red radiation from terrestrial sources and from stars. Mr. Alfred N. Finn, who resigned from the Bureau of Standards in 1919, was reappointed to the chemical staff of the Bureau in October. Mr. F. F. Fitzgerald resigned from the staff of the National Canners Association Laboratory in November to accept a position with the American Can Company at 120 Broadway, New York City. Mr. M. G. GuLLEY has been appointed assistant geologist in the U. S. Geological Survey, and has been temporarily assigned to assist Mr. F. L. Ransome in field work in the Oatman District, Arizona. Mr. Walter A. Hull, formerly in charge of the work on fire-resistive properties of materials at the Bureau of Standards, has been placed in charge of the work on optical glass in the Division of Ceramics of the Bureau. Mr. W. E. MvER of Nashville, Tennessee, was in Washington in Decem- ber preparing a report for the Bureau of American Ethnology on his archeo- logical field work of last summer in the Cumberland Valley. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 February 4, 1921 No. 3 PHYSICS.— r/z^r .compressibility of diamond.'^ L. H. Adams, Geo- physical Laboratory, Carnegie Institution of Washington. Many of the properties of that remarkable form of carbon, the diamond, are known, but its compressibility has never been measured. The commercial value of a quantity of diamonds sufficient for such a determination is so great that the opportunity for making the deter- mination would seldom present itself. It is not necessary for this purpose, however, that the material be in one piece or even in large fragments although, contrary to what is commonly believed, no ap- prehension need be felt in subjecting diamonds or any other homo- geneous material to the enormous pressures required. - It was the writer's good fortune to have at his disposal about 80 grams of diamond chips obtained through Dr. F. E. Wright, of this Laboratory, from S. L. Van Wezel, Inc., of New York City.^ The material was in the form of clear, colorless fragments of various sizes up to one or two millimeters in their largest dimension. A small amount of metallic impurity was found to be present and was removed by treatment with hot nitric acid. After being washed with water and dried in the oven, a fraction consisting of about 30 grams of the coarser fragments was separated from the remainder and was used for the measurement of the compressibility. The method used has been described in a former publication^ from this Laboratory. Briefly, it is as follows: The material to be investi- gated is surrounded by kerosene and placed in a cylindrical, heavy- walled, steel bomb, one end of which is closed while in the other end is fitted a piston with a suitable packing. Pressure is applied ' Received January 8, 192L - As long, of course, as the pressure is strictly hydrostatic, that is, uniform in all direc- tions. 3 Our thanks are due to this firm and especially to the President, Mr. M. S. Van Wezet, for their courtesy in lending this material. "• L. H. Adams and E- D. Williamson, Journ. Amer. Chem. Soc. 41: 12-42. 1919. 45 4G JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 3 by forcing the piston into the bomb by means of a powerful hydraulic press. In order to determine the compressibility it is necessary to measure the pressure and the decrease in volume. The pressure is measured by means of a small coil of "therlo" wire the resistance of which changes with pressure according to a known relation; and the volume-decrease is determined by the movement of the piston, which is measured with a dial micrometer. Pressures were read to 1 megabar and piston displacements to 0.001 mm. As a means of correcting for the compressibility of the kerosene, an exactly similar series of measurements is carried out with some other sub- stance of known compressibility. The diamonds were placed in a thin- walled steel capsule, and the comparison body was a Bessemer steel cylinder the volume of which was equal to the volume of the diamonds plus the volume of metal in the capsule. In order to remove any air bubbles which might cling to the diamond fragments, the material, having been placed in the capsule, was covered with kerosene and the whole evacuated. With the apparatus used the most accurate measurements are obtained in the range from 4,000 to 10,000 megabars.^ Accordingly, it seemed best to make several series of readings within this range of pressure. Readings were taken at 4,000, 6,000, 8,000 and 10,000 mega- bars. Three separate runs were made with the diamond and two with the steel, but the first series with the diamond was subject to slight irregularities due to trouble with the electrical connections and was therefore neglected in the final calculations. The method for calcu- lating the results and for making the various corrections is described in detail in the paper already referred to. Various ways of combining the data of the two series for steel and the two series for diamond led to substantially the same result. If the mean of the former be compared with the mean of the latter, Av the relative decrease in volume, — , is found to be as shown in table 1. Vo Table 1 Decrease of Volume of Dl^mond under Pressure Pressure megabars p. Volume decrease ^ X 10-= 4000 0 6000 1,01 8000 1.81 10000 2.68 ^ X 103. Calc. from equation (1). Difif. 0.0.5 -0.05 0.93 -1-0.08 1.82 -0.01 2.70 +0.02 ^ 1 megabar = 0.987 atmosphere. FEB. 4, 1921 ADAMS: COMPREvSSIBlUTY OF DIAMOND 47 In table 1 the second column shows the "observed" relative de- crease in volume corresponding to the pressures given in the first column. The arbitrary zero with reference to the volume change was at 4000 megabars. The decrease in volume was assumed to be a linear function of the pressure, that is, — X 103 = a + 6 (^ - p^) X 10-\ (1) and by the method of least squares the values of the constants a and b were calculated from the data in table 1 . The value found for b "was 0.442, which, multiplied by 10 ~^ is the difference between /3, the compressibility of diamond, and /3', that of steel. That is, /3' — ^ = 0.44 X 10 "^ If the compressibility of steeP be taken as 0.60 X 10 ~^ the compressibility of diamond is /3 = o.i6 X io~* per megabar. This value is estimated to be correct within =t 0.02 X 10~^ From this result it is evident that the compressibility of diamond is remarkably low; indeed, of all substances whose elastic behavior is known, diamond is by far the most incompressible. Its nearest com- petitor, tungsten, is nearly twice as compressible (/3 = 0.27 X 10~®), and the majority of solids decrease their volume more than ten times as much for a given increment of pressure. If a diamond were buried 100 miles below the surface of the earth the pressure due to the super- incumbent rock — a higher pressure than has ever been attained in the laboratory — would decrease the volume only about three-fourths of one per cent. It is noteworthy that the other modification of carbon, graphite, is much more compressible, the value of (3, according to Richards,'' being 3.0 X 10"^ Relation of compressibility to other properties.- — ^Einstein^ has derived the following equation, involving the compressibiUty 3 « Compare P. W. Bridgman, Proc. Amer. Acad. 47: 366. 1911. E. GrCneisen, Ann. Phys. (4) 33: 1262. 1910. ' T. W. Richards, Joum. Amer. Chem. Soc. 37: 1646. 1915. 8 A. Einstein, Ann. Phys. (4) 34: 170. 1911. The specific heat per gram-atom, Ct of any monatomic solid, according to Einstein, is a universal function of p/T, thus: R, h and k being universal constants. 48 JOURNAL OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 3 (in absolute units), the atomic weight A, the density p, and the vi- bration frequency v of the atoms : i^ = 3.3 X 10^ A-^>-'^ ^-'^ (2) Lindemann,^ on the other hand, calculates p from the equation: V =3.1 X 10'^ A-^' p^' T^' (3) in which T^ is the melting point on the absolute scale. Eliminating V from these two equations, and multiplying by 10^ in order to change the units of (3 from cmVdyne to cm-/megadyne, we have: /3 = 1.13 X 10-"— (4) This equation closely resembles the empirical equation used by A Richards, ^^ namely, /3 = 2.1 X 10~" ^,^ . rr:, and yields for many elements values of /3 which are in fair accord with the observed A^alues. The melting point of diamond is not known, but assuming that it is 4000°, and taking p as 3.51, the value of /S calculated from equation (4) is 0.10 X 10"". As calculated from Richards' formula, the value is 0.13 X 10 "^ Another equation may be obtained from Griineisen's formula ■} ^ v = 2.^ + wi'-n 'a-^p^ (5) in which c^ is the specific heat per gram, and a is the cubical expansion coefficient. Eliminating v from equations (2) and (5) and multiplying by 10^ as before, we have a ^ = 1.29 X 10-2 — . (6) c„p This equation clearly illustrates the fact that low compressibility tends to be accompanied by low thermal expansibility. In using equation (5) or (6) for numerical calculation, however, for the ratio -- must be taken its limiting value as the temperature is decreased. Cv It may be noted, nevertheless, that if the values of c^ and a for diamond at 25° C. {c, = 0.12 cal. per g.; « = 3.5 X lO"^) be substituted in equation (6), 13 is found to be 0.11 X 10 "^ 9 F. A. LiNDEMANN, Phys. Zeitschr. ii: 609. 1911. 1" Op. cit., p. 1653. See also W. D. Harkins and R. E. Hali,, Journ. Amer. Chem. Soc. 8: 209. 1916. " E. GRiJNEisEN, Ann. Phys. (4) 39: 293. 1912. FEB. 4, 1921 ADAMS: COMPRESSIBILITY OF DIAMOND 49 Another useful relation involving the compressibility is that given by Debye:^- e = ^1^' ^ ^^-74 X 10-" j_ In this equation /3 is in absolute units, and <^ is a function of a, Poisson's ratio, ^^ thus: * = -(3 nryj +(3-03^) Rearranging equation (7), substituting Debye's values for h and k, and expressing /3 in cm.-/megadyne, we have: /3 = 5 . 5 X 10-1 j^;; .4 -^ p-'^ -'^ (8) The value of v,„ for any element can be calculated from equation (7) provided that the specific heat is known at one or more suitable tem- peratures; and 0 can be calculated when a, Poisson's ratio, is known. Equation (8), then, can be used to calculate the compressibility of any element for which C., and a have been measured. For several elements for which these quantities are known the compressibilities have been calculated by equation (8) with the results shown in table 2. TABLE 2 Calculation of Compressibility from Specific Heat and Poisson's Ratio Compress- iljility Max. atomic Poisson's calc. from frequency At. wt. Density ratio equation (8) ^ X 106 Substance. •',„ X 10'^. .1. p. a. /S X 106. observed. Aluminum 8.2 27 . 1 2.7 0 . 34 1 . 42 1 . 32 Copper 6.4 63.6 8.9 0.35 0.83 0.75 SUver 4.4 107.9 10.5 0.38 0.92 0.97 Lead 2.0 207.2 11.3 |0.45] [1.1] 2.2 Diamond 39.2 12.0 3.5 (0.25) 0.16 0.16 The values for v,„ are taken from Debye and those for Year Book, 1919. 92 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 4 grant the same privileges to those who are mainly consumers might, as I have indicated before, swamp the whole process of production. Scientific and technical periodicals. — Concerning much that is published in our voluminous scientific and technical literature we might reasonably ask, as the Mock Turtle did of Alice, "What is the use of repeating all that stuff?" If we had an all-wise censor to judge it, we might well dispense with the greater part of it. But in that "if" is contained the whole argument against any kind of suppression. There is instruction, and perhaps encouragement, in comparing the evolution of scientific periodicals with that of newspapers and popular magazines. The newspapers began with small local cir- culations at a few places. They increased in numbers, and a few papers forged to the front and became leaders, widely read or quoted from. The multiplication of local papers, however, did not cease, but increased, until now every hamlet has one; their diversification, to represent many groups of people with related interests, went on simultaneously. Of recent years, a strongly marked tendency toward financial and operational centralization has appeared. Other types of periodical printed matter have gone through a similar evolution, and scientific periodicals are following along in their turn. We have had (1) the period of early growth, and small circulation, but large influence, and (2) the period of greatly increased circulation of recognized leaders, with precarious existence for the smaller members; and we are just entering (3) the period of rapid multiplication of local scientific periodicals together with minute diversification according to specialties. The period of centralization is still below the horizon. It may be urged that science is universal, and a local scientific publication is an anomaly; then so is a specialized journal, for knowl- edge is no more to be divided into Compartments according to the temporary interests of human beings than according to their geo- graphical residence. Nevertheless local and specialized newspapers, magazines, and scientific journals multiply in spite of logic. Every group of a few hundred or a few thousand persons with aUied interests, whether allied by profession or by geographical location, seems to need its printed organ, and the feelings of librarians are given no consideration whatever. The Washington Academy of Sciences, for example, representing in its own membership and in its affiliated societies nearly 3000 scientific and technical men and women, with FEB. 19, 1921 sosman: distribution of scientific information 93 certain joint interests that are local and not divided according to sciences, finds a demand for a journal which shall represent those joint interests in news, society proceedings, and announcements of the research going on in the city, and strives to fill that need ; it may not always be perfectly filled but it is there. As the number of periodicals relentlessly increases, the need for efficient and thorough abstracting and indexing is being more and more felt and provided for. For example, chemistry and a large part of physics is being admirably served by Mr. Crane in Chemical Ab- stracts. Geology and allied sciences are excellently handled by Mr. Nickles in the annual index issued by the U. S. Geological Survey. Indexing and abstracting is a developing art, which should not be left to amateur bungling, but should be turned over to individuals trained and well paid for the work. The relation of advertising to scientific and technical journals is a matter of especial interest. It is said that any periodical which can attain a circulation of 5000 or more can support itself on adver- tising. Why should scientific periodicals not make better use of this fact? I have already mentioned the Chemical Society's experiment with the Journal of Industrial and Engineering Chemistry , which returns from its advertising a considerable revenue to the Society. Now there is nothing in this situation to abrogate the old rule that "No man can serve two masters." If the time ever comes when the interests of the Society and the interests of the advertisers come into conflict, the Journal either will have to stand by its advertisers or will have to change its character. Naturally, both the advertisers and the Society will seek to avoid occasions which would lead to disagreement ; but that is only another way of saying that the advertisers will exert a considerable influence on the policies of the Society, whether they wish to or not. The situation is further complicated by the existence in the same field of the periodical Chemical and Metallurgical Engineering, which is published for profit and not as the organ of any society. It has the advantages over the Journal of Industrial and Engineering Chem- istry (1) of publication weekly instead of monthly, making its news much fresher and therefore more in demand; (2) of freedom to use its own income for its own purposes, not for carrying another organ- ization on its back. The Journal, on the other hand, (1) has the prestige of representing the largest chemical society in the world and 94 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 4 (2) has the first claim on the material presented before that society. In my opinion, the Journal now publishes a higher grade of material, but the Engineering has been steadily improving. The Journal has the larger circulation by about one fifth. Each claims that it has a circulation more profitable to the advertiser than the circulation of its competitor, but on these claims I am not competent to give any opinion. There is evidently staged here a contest of the social versus the profitable which I, for one, will observe with interest during the coming decade. Meanwhile, without seeking to condemn or approve either side, I believe we shall do well to keep these facts in mind when considering contributing articles to these journals or others similarly situated. The progress of experiments such as I have described may not improbably result in scientific societies finding it to their advantage to have all their publishing done for profit, just as they now have their printing and binding done for profit. Why not turn the whole conduct of their publications over to an organization which makes a business of editing, managing and circulating periodicals, subject of course to some original control by each society as to the general nature of the papers to be published ?^^ One benefit which would result would be the saving of time and energy of investigators now spent on routine editing and publishing. The amount of good research which has been prevented by scientific periodicals would probably be appalling if we could sum it up. An- other benefit would be the suppression of a great deal of data now being published simply because space happens to be available but for which there is not and never will be any demand. On the other hand, the work of a Willard Gibbs might also be suppressed. -'' Another point regarding advertising. We all recognize that the consumer pays for it, yet he has little if any control over what he has paid for. The inanufacturer tells him what the manufacturer would like to have him know, and no more. Why should not the consumer have his advertising page, in which to tell the manufac- ^- An experiment of this kind is about to be tried by the Chemical Society with its two series of Scientific and Technologic Monographs, by contract with the Chemical Catalog Company of New York. ^^ On second thought I find I have selected a bad example. If the Transactions of the Connecticut Academy had not been available, Gibbs' work might have been offered and published where it would have really circulated, and the English-speaking world would not have had to wait for it to be translated into German before it could become known. I FEB. 19, 1921 sosman: distribution of scientific information 95 turer what he wants, and in which to tell his fellow-consumers his experience with what had been offered? The editors of the Journal of the Washington Academy of Sciences have considered the feasi- bility of publishing "consumers' advertising" of this kind, since the Academy, as a private organization with no governmental or commercial affiliations, is in a wholly disinterested position, and furthermore numbers in its membership representatives of almost every ramification of science so that a wide range of experience is available. The task of "advertising manager", to collect, edit, and publish material of this type, however, is one of those public services which are more praised than rewarded. Newspapers and popular magazines . — The appearance of scientific information in newspapers and popular magazines is relatively so recent that it would be rash to try to predict its future. These media themselves may change considerably during the next two decades. The present tendency toward centralized ownership and management of both types probably bodes good rather than ill for the distribution of information, whatever may be thought of the tendency in its political and social bearings. Separates. — The use of separates seems to be on the increase, and I believe is destined for continued growth. In particular, their use in place of special series of "bulletins" published by research institutions is a very desirable development. Bulletins issued in independent series are not likely to be effectively distributed, as each has to be handled by itself and librarians are frequently at a loss as to where to index or file them. Their very existence, also, may remain unknown until long after the stock has become exhausted and copies are no longer available for libraries which find them in demand. Articles published in a regularly circulating journal, on the other hand, are not thus lost to view or rendered inaccessible. The difference is the same as that between the privately printed book and the book issued by a publishing house which is alwa3'^s in touch with the channels of distribution. The distribution of separates by dealers is a service almost lacking in this country. For instance, before the War the surest way to get a separate of an American geological paper was to write to Leipzig for it. Patriotic pride, if nothing else, ought to stir us to remedy this situa- tion. Some authors deliberately send copies of their separates to the second-hand dealers in order better to reach interested persons un- known to them; w^hile others condemn this practise as undignified. 96 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 4 Printed matter in general. — I have reviewed briefly certain phases of the distribution of information by the printed page. There re- mains another point of view from which to consider all of them. To distribute information by printing it is necessary first, to place the printed article in the reader's hands; second, to induce him to read it, rather than file it or put it in the waste-basket; third, to pre- sent the matter so that the reader gets some profit from his reading. The members of the advertising profession are probably the best fitted to instruct us as to the best way of putting reading matter into peoples' hands, but I do not happen to know of any scientific organiza- tion which has actually utilized their experience. The organizations best known to me are experimenting, each with its own system, and the results will after some years be valuable as comparative experi- ments. Present tendencies in the distribution of free or nominal- priced publications seem to be in the direction of the periodical issu- ance of lists or announcements of publications to a large mailing- list, the recipient being expected to make his own choice and go to whatever trouble is necessary to obtain the publication. Details of the process vary widely, and the future will see the elimination of the less effective procedures. The second problem, that of inducing the recipient to begin to read what he has received and perhaps has even personally asked for, calls, in the commercial field, for the highest art of the advertiser. I doubt whether this phase of the question has ever been given much serious consideration by the distributor of scientific information, though it is the very life of modern printed advertising. Certainly the Federal bulletins coming from the Government Printing Office all look alike, and I question whether all of them would be called "attractive" by the commercial printer. I feel that we would do well not to be satisfied with the dictum that "information is infor- mation and the consumer may take it or leave it." The third point, of presenting the matter so that the reader gets something for his pains, is where the investigator himself is put on his mettle. I have presented his complaint against too much ques- tioning, but there is no intention of relieving him from the duty of giving a clear account of his product, in writing. The account need not be non-technical or suited for general reading, but it should be understandable with the minimum of effort by the circle of readers for whom it is written. Here is where the investigator most often fails. Dr. George Otis Smith, director of the U. S. Geological Sur- J FEB. 19, 1021 sosman: distribution of scientific information 97 vey, has made it one of his favorite subjects of discourse to urge that the results of investigation be stated in clear and easily understand- able language, and to point out that muddy writing is usually the product of muddy thinking. He provides, for his organization, an editor who gives his whole attention to improving the readability of the Sur\^ey's publications. Most organizations have editorial committees, sometimes seeming to ramify ad infinitum, but current discussion and comment lead me to believe that the less of this kind of committee work we can get along with, the better. A more prac- tical system to work toward may be indicated in the fable of the suc- cessful publishing house which passed for publication only matter which was found to please the janitor. If the investigator neglects his plain duty of presenting an accurate and clear account of his results (though not necessarily non-technical or adapted to the use of the pubHc), and his organization neglects its duty of seeing that the account is readable and accessible, then there is little ground for complaint on their part if the work is over- looked and even duplicated by somebody else. Although it is per- haps contrary to existing professional tradition, I feel that "a thorough knowledge of the literature" is not incumbent on an investigator if a part of that literature is so obscure as to require a disproportionate time for its discovery and deciphering.-^ The "movie'' film. — The future of the distribution of scientific information by the "movies" is simply beyond prediction. Perhaps its recent vigorous growth is only that of a mushroom, without per- manence. Rapidly increasing investments in the business, on the other hand, indicate considerable confidence in its future. Pro- gressive educators, a'so, are fully aware o: its possibilities, as indi- cated by the recent formation oT a "Society for Visual Education." One thing is certain: tha,t the best results will not be attained by leaving the matter to the ruthless natural selection of commercial com- petition. Neither will anything serious be accomplished by con- sidering the moving picture as merely an adjunct to the lecture or museum. Other methods. — A minor method of distribution, used particularly in crystallography, physiology, paleontology, and geography, is that by models or casts made in any desired number from a mold. Its 2^ "It is the worst of educated men that they cannot speak about any great question till they have read everything that has been written about it, for fear that some one should say, 'But have you read Schwartzenburg?' Then, if they have not read Schwartzenburg, they are done." — Tolstoy. 98 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 4 use could well be extended to other sciences. Phase-rule models in chemistry, for instance, concentrate a great deal of information into a small space and put it into a form very useful for instruction.-' Another minor method is the distribution of type collections of ma- terial, made up in considerable number from a common supply, and distributed usually by sale. This has been used in the fields of min- eralogy and petrology and certain branches of biology. Collections of photographs have been similarly used by some of the Federal bureaus. The number and field of usefulness of such reproducible collected sets of material objects is likely to be enlarged. The general problem of distribution to the public. — I have referred repeatedly to the "bulk" and "heterogeneity" of our present output of scientific information, and hope that by inference as well as by direct statement I have already impressed the idea that haphazard dissemination does not constitute orderly distribution. '-'' We have accomplished little if we have merely reached the auditory or optic nerve of the public without reaching its understanding. Have we any assurance, for example, that the Science Service for the news- papers (after performing its obvious and useful duty of preventing misinformation) will do more than merely replace on the newspaper page an equivalent area of advice, gossip, or fun, producing about the same permanent effect as the displaced material? I hope the plans of the Service will include some method of measurement of its permanent results, for, in , chemical terms, if there is no solubility there will be no absorption, however large we make the area of con- tact; and if the absorption turns out to be small we shall have to do something to increase the solubility.-^ In conclusion, I wish to express ni}' indebtedness to various mem- bers of governmental and private institutions in Washington for assistance and suggestions in the preparation of this address. ^ The Geophysical Laboratory has received a number of requests for copies of its models of silicate systems, but is not equipped to manufacture and sell such a product. Some commercial or philanthropic agency would do a service by taking up this kind of distribu- tion. ^^Dissemination: "Propagation by means of diffusion or dispersion .... Propagation by means of promulgation; a spreading abroad for or with acceptance, as of opinions." (Centur}'^ Dictionary). The disseminator selects what is to be promulgated and the pub- lic is at his mercy. Distribution: "Allotment in shares or according to requirements The division of the aggregate produce of the industry of any society among the individuals who compose it." The public does the selecting and the distributor renders the product ac- cessible. ^^ "One can readily conceive a Dark Ages which was such because of too much instead of too little information." The Villager 4: 94. November 6, 1920. FEB. 19, 1021 sosman: distribution of scientific information 99 GENERAL SUMMARY The production of new information in the United States is much better managed than its distribution. It is distributed through five main channels: (1) by personal communication or through the "informational middleman;" (2) by public lectures; (3) by the museum and public exhibition; (4) by the printed page — books, scientific and technical periodicals, bulletins, general periodicals, newspapers, and separates; (5) by the cinematograph. Ineffective distribution results from (1) disinclination to use new knowledge, a cause not discussed in this paper; (2) the inaccessibility of scientific information, arising from (o) the bulky form in which it comes from the producer, (b) its heterogeneous character, and (t) the arithmetical or psychologi- cal limitations peculiar to each method of distribution. The bearings of these various factors on existing methods of distribution, both to producers of information and to the general public, are touched upon, and desirable or probable future developments in each are briefly discussed. SCIENTIFIC NOTES AND NEWS A reception was held on January 12, 1921, by the President and officers of the Medical Society of the District of Columbia to the members and friends of the Society, including the members of the Academy and its affiliated societies. The reception was held at the new home of the Medical Society at 1718 M Street, following the dedication of the building. The Washington Section of the American Institute of Mining and Metal- lurgical Engineers held a supper and meeting at the Interior Department on Friday, January 14. Dr. H. Foster Bain, the newly appointed director of the Bureau of Mines, lectured on Mines and mining in the Far East. The National Museum has received specimens of various deep-water fishes from Hawaii, which had been killed by the recent lava flow from Mauna Loa. Most of the forms have been found by Dr. D. S. Jordan to be new, and a report on them will be published by the Smithsonian Institu- tion. An exhibit of medicinal substances arranged according to their thera- peutic effects is being prepared for the Division of Medicine of the National Museum. Dr. J. M. Aldrich of the National Museum was elected president of the Entomological Society of America at the Chicago Meeting. Col. J. M. Birch of the British Army, in charge of the agricultural de- velopment of the Mosul district of Mesopotamia, has sailed from New York after spending several months studying American agriculture. While in Washington he used the facilities of the Bureau of Plant Industry. Dr. H. C. Bryant and Dr. L. H. Miller, of the University of California, have been spending some time in Washington, and delivered addresses before the Biological Society on January 22, and the Audubon Society on January 26. Doctors Bryant and Miller were nature guides in the Yosemite National Park during the summer of 1920 and organized field trips for the instruction of visitors. Dr. H. L. Shantz has been appointed plant physiologist in charge of Plant Phj^siological and Fermentation Investigations in the Bureau of Plant Industry. Dr. vShantz returned in September from a year's trip through Africa for the Office of Foreign Seed and Plant Introduction, from which office he is now transferring. Senator Charles S. Thomas, of Colorado, resigned on January 5 as a Regent of the Smithsonian Institution, and the Vice-President appointed Senator A. O. Stanley, of Kentucky, to succeed him. Mr. W. F. Wallis, of the Department of Terrestrial Magnetism, Carnegie Institution of Washington, left Washington on January 9 for Huancayo, Peru, where he will succeed Dr. Harry M. W. Edmonds as magnetician- in-charge of the Huancayo Magnetic Observatory upon the conclusion of the latter's two-year assignment. Dr. Edmonds will return about April via San Francisco for duty at Washington. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 March 4, 1921 No. o RADIOTELEGRAPHY. — The wave front angle in radiotelegraphy^ h. W. Austin, U. S. Naval Radio Research Laboratory. One of the outstanding problems in radiotelegraphic transmission is the determination of the angle between the advancing wave front and the earth. A number of physicists- have treated the subject theoretically and a resume of their conclusions may be found in Zen- neck's Wireless Telegraphy (translation 1915), pp. 246-2.5.3. The subject is of great importance in the theory of transmission and has a very practical interest in the reception of signals on ground antennas. Several experimenters have attempted to measure the wave front angle by means of receiving loops, the method being to rotate the loop around a vertical axis to the point of minimum signal and then to rotate again around a horizontal axis in the plane of the wave front until silence is obtained. A little consideration will show that this method is not applicable to the problem, since after the minimum is obtained by rotation about the vertical axis, none of the magnetic lines of the wave can thread the loop no matter what its angle in ref- erence to the wave front, any residual effect in this position being due to the action of the loop as an antenna. The most obvious method for measuring the angle, and the one which seems most free from objection, makes use of a pivoted straight wire antenna system well elevated above the ground with a receiver inserted in the middle. The general arrangement is shown in figure 1 , and the method of shielding the circuits in figure 2. The antenna consists of two collector wires, each 30 feet long, supported on a piv^oted wooden spreader (Fig. 1) 60 feet long, mounted at the top of a 55 foot wooden pole so as to be capable of rotation about a hori- 1 Received December 20, 1920. /-J. Zenneck, Ann. Phys. 23: 846. 1907. K. UllER, Jahrb. 2: S. 190S. A. SOMMERFELD, Ann. Phys. 28: 665. 1909. P. Eppstein, Jahrb. 4: 176. 1910. 10 1 102 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 5 zontal as well as a vertical axis. The receiving set consists of a pri- mary inductance and parallel capacity connected between the two collectors as shown in figure 2, and a secondary, generally of the mag- netic back-coupled oscillating vacuum tube type, provided with a two-stage audio frequency amplifier, though in some experiments a radio-audio amplifier with heterodyne was used. The whole set in- cluding the batteries was mounted on top of the pole. Itt^OU^TOK. HOUSE W^^///////////W////A IH3U1- 1 TOI^ Fig. 1. Diagram of pivoted straight wire antenna system, mounted on top of 55 foot pole. The method of experiment is as follows. The antenna is first set vertical with the horizontal axis approximately in the plane of the wave front. This gives maximum signal. It is then rotated about the horizontal axis and as the antenna approaches the horizontal position the signal fades as on an ordinary radio compass. At some angle it dies out, and then as the rotation is continued comes in again. At the mean of the two positions of just audible signal, the antenna is perpendicular to the wave front if there are no causes of distortion. The antenna is next rotated through 180 degrees and two more angles of disappearing signal are observed. The mean of the four observa- tions should give the determination with considerable accuracy. In the final experiments the mast with its pivoted antenna and instruments was erected on the Anacostia Flats not far from the Washington Navy Yard. The absence of wire lines and houses within MARCH 4, 1921 AUSTIN: WAVE FRONT ANGLE IN RADIOTELEGRAPHY 103 a distance of more than a quarter of a mile made this an ideal location for the work. The two collector wires of the antenna were stretched in a straight line by the spreader shown in figure 1 . This was con- structed of wood with its joints fastened by wood dowel pins and a few brass screws. The scale for determining the angle was aligned with the wires by means of a transit. All the apparatus, with the exception of the primary inductance and condenser, was contained in a box covered with fine mesh copper screen. This box was sup- ported by ropes in order to reduce the capacity between the receiving set and the mast. It was also found necessary to shield the telephone leads and ground the head band to the copper screen surrounding the apparatus. At first a certain asymmetry was observed in the reading when the antenna was turned through 180 degrees. This was apparently due to an asymmetry in the capacity between the grounded shield and the two collector wares, and was corrected by connecting a small com- pensating condenser between one side of the primary and the shield. This condenser also produced a much sharper minimum. Its action is similar to that of the compensating condenser frequently used with the ordinary radio compass. Figure 2 shows the method of coupling the primary to the secondary, the magnetic field passing with some loss through the shield while . r, fi f, I, f, r; i; r, rj f; f; rj ij r ; ^ r, ^ ( i| r; < r f| SHIELD 1 1 , /iMPLIFIEff TO DETECTOR 'nM'>i) (17) where tan <^ = co/m. From (1) the total displacement x can be found. After sufficient time that the exponential term of (17) has dwindled to an insignificant amount, the cyclic state may be considered es- tablished; the displacement then is given approximately by " sin (coi - <^) (18) X =ii.. hi '4:)]* where tan$ = AE{m/oo). The hysteresis loop will be found by elimi- nating the time {T = t) between the load equation (16) and the dis- placement equation (18). Since (16) and (18) represent two simple harmonic motions at right angles, of the same period but differing in amplitude and phase, the hysteresis loop will be an ellipse. The area of this ellipse will represent the energy dissipated into heat per cycle, after the cyclic state has been reached. Calculation of recovery curve. Suppose a load R suddenly applied, kept on for a time interval to , then suddenly released. What will be the after-effect z (residual displacement) at an interval t' after the instant of release? Since x^ is now zero, the after-effect will equal the yield y at time t = to + t' due to a load increment aX = R 3.t time T = 0 followed by a second increment A A' = —Rat time t = to. Hence by (10) z = R[F{to +t') - Fit')] (19) APRIL 4, 1921 pittier: notes on swartzia 155 Thus the recovery curve can be constructed by making a tracing of the drift curve, inverting it and shifting it along the time axis by an amount ^o- The algebraic sum of the ordinates of these two curves forms the desired curv^e for z sls a. function of /'. This method has been applied with fair success to data furnished by- Dr. C. E. Van Orstrand for the slow stretch in a steel tape over a period of four months, when suspended under tension. The greatest difference be- tween the calculated and observed after-effect at any time during this long period was less than 9 per cent of the initial after-effect. A similar check on equation (19) should be possible by reference to Michelson's data for torsion. His recovery curve formula may be written^ z = KRe-'^^^' (1 - e-"^^o) (20) Substitution from (9) into (19) gives z = KRe-"^^ [1 - e.-«(Vtr+l^- VP)] (21) This, for small values of ^', reduces to Michelson's experimental for- mula (20), but for large values it diverges. It is not possible to make an exact test of equation (19) without reference to the original observa- tions, w^hich were not given in the paper above cited. These examples may suffice to make clear the general purpose of the superposition theory. It is not a molecular theory, neither does it aim to deduce a priori anything about the form of the drift function. It presupposes the availability of just such data as Michelson's drift curve (9) and then proceeds to develop the necessary interconnections between the drift and the remaining irreversible effects. * BOTANY. Notes on the genus Swartzia in Panama and Guatemala.'^ Henry Pittier. The genus Swartzia of the Caesalpiniaceae contains a large number of species, many of which are closely related, and the genus as a whole is badly in need of revision. In the present paper an attempt is made to systematize the representatives of the genus now known from Panama. A little known species of the genus from Guatemala is also described. ^^' 6 Op. cit. See also Journ. Geol. 28: . 1920. /K 1 Received February 11, 1921. / 156 JOURNAL OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 1. REVISION OF THE PANAMA SPECIES Legume broad, long, and flat; racemes many-flowered, elongate; leaves pin- nate, 5-foliolate. (Platypoda.) 1. 5. panamensis. Legume cylindrical, short; racemes 2- to 5-flowered; leaves mostly 1- or 3-foliolate, rarely 5-foliolate. (Strong ylopoda.) Leaves unifoliolate. Petiole narrowly alate or scutellate at the apex; petal about 4 cm. in diameter. 2. 5. simplex. Leaves mostly 3-foliolate, sometimes 1- or 5-foliolate. Stamens 20 or fewer, not conspicuously unequal. Flowers small, the petal hardly longer than the calyx. 3. 5. arborescens. Stamens numerous, conspicuously dimorphous, the longer ones 10 to 20, the smaller ones numerous. Leaflets not over 10 cm. long, lanceolate, the petioles rather broadly winged. 4. 5. trifolia. Leaflets usually larger, ovate, the petioles rather narrowly winged. Petal suborbicular, about 2 cm. in diameter. 5. S. myrtifolia. Petal ovate-cordiform, about 2.5 cm. long and 3 cm. broad. 6. 5. darienensis . 1. Swartzia panamensis Benth. in Mart. Fl. Bras. 15-: 38. 1870. Deciduous (?) tree, 6 to 20 meters high, with short ascending limbs and elongate crown, the trunk seldom over 40 cm. in diameter, often distorted, the bark grayish, smooth. Leaves 5-foliolate, pubescent, glabrate, with lanceolate-acuminate silky- pubescent caducous stipules; petioles 9 to 13 cm. long, almost terete; petio- lules articulate, 4 to 6 mm. long; blades elliptic or ovate-lanceolate, rather long and narrowly acuminate, S to 18 cm. long, 3 to 6 cm. broad, dark green above, pale green beneath, the venation sparse, impressed above, prominent beneath, the 9 to 11 primary veins alternate, arcuate, transversely anasto- mosing. Racemes solitary in the defoliated axils of the preceding season or in the axils of new leaves, very long (20 to 40 cm.), pendent, many-flowered, the bracts awnlike, up to 10 mm. long, caducous; rachis and pedicels minutely pubescent, the former thick and subangular; pedicels reflexed, clavate, about 2 cm. long; calyx opening irregularly by 4 or 5 reflexed lobes about 1 cm. long. Petal creamy yellow, almost square (31 mm. long, 29 mm. broad), unguiculate, hastate and emarginate at the base, subquadrilobate, with irregular margin; claw narrow, about 6.5 mm. long. Stamens very numerous, the larger ones 6 to 10, erect, with thick filaments 12.5 mm. long, the remain- ing small ones with threadlike filaments 15 mm. long and smaller anthers, their cells more or less parted at the base. Ovary short, flattened, entirely smooth, long-stipitate, with a short, blunt, hardly bent style; stipe 6 mm. long, the ovary and style about 5 mm. long; ovules S or fewer. Legume single, 20 to 30 cm. long, 8 to 10 cm. broad, coriaceous, apiculate, dehiscent, 4- to 8-seeded; pedicel thick, 2 cm. long; stipe 1.5 to 2 cm. long; seeds large, irregularly sublenticular-ovate, 7 to ^.o cm. long, 6 cm. wide, and 1.5 cm. thick, exarillate, dark brown. vSpecimens Examined: Panama: Rocky slopes along Chagres River near Alhajuela, flowers and fruit, May 13, 1911, Pittier 3520. Along Trinidad River, Canal Zone, near sea level, flowers, July 20, 1911, Pittier 4019. Around Port Obaldia, San Bias Coast, flowers, September 2, 1911, Pittier 4324. APRIL 4, 1921 pittier: notes on swartzia 157 Also recorded by Seemann from San Juan de Chagres and Hacienda de Juan Lanas. Seemann describes the racemes as being in pairs, a character not shown by the recent specimens, though these agree in the main with Ben- tham's short diagnosis. These collections from the shady forests of the lit- toral plain around Port Obaldia have broader and less coriaceous leaflets than those from the high banks of the Trinidad River or the rocky slopes of the Chagres gorges. In the first locality, too, the tree assumes more frequently an erect, regular shape, with a straight trunk. It seems that only the basal flowers of each spike bear a pistil ; this part was missing altogether on several of the specimens I had occasion to dissect, and, so far as my experience goes, the pods invariably grow out of the 5 flowers nearest to the base of the raceme. Usually there is only one pod to each raceme, but two on the same peduncle are not uncommon. Completely developed seeds are seldom found. The trees on the Chagres River bore only new, incompletely developed leaves, although anthesis was rather advanced and even fully grown pods were pres- ent. These facts would indicate a deciduous species, the only one reported so far in this heterogeneous and not well defined genus. 2. Swartzia simplex Spreng. Syst. Veg. 2: 567. 1825. Small tree, 3 to 10 meters high, the trunk 10 to 15 cm. in diameter, straight or distorted, with smooth grayish bark, the branching sparse and divaricate. Leaves unifoliolate, quite glabrous, more or less coriaceous, nitidulous, the primary veins numerous and subparallel ; stipules setaceous, 5 to 8 mm. long, caducous; petiole 3 to 15 mm. long, terete and auriculate at the apex when ver>^ short, marginate and distinctly articulate at the apex when longest; blades ovate-oblong, rounded or subcuneate at the base, shortly obtuse- acuminate at the apex, 4 to 20 cm. long, 2 to 7 cm. broad, the venation prom- inent on both sides. Inflorescences racemose, 2- to 6-flowered, axillary or terminal, 4 to 10 cm. long, the rachis glabrous; pedicels erect, 5 to 20 mm. long, obclavate; buds globose, 7 to 10 mm. in diameter; calyx opening by 4 irregular lobes; petal orbicular, about 4 cm. in diameter, pale yellow; long stamens 8 to 12, the anthers elongate-oblong; short stamens numerous, the anthers also smaller; ovary long-stipitate, quite glabrous, arcuate, 10- to 12-ovulate, the style arcuate and subulate. Legume oblique-oblong, terete, up to 4 cm. long, 1.5 cm. in diameter, usually 1- or 2-seeded, in the latter case hardly contracted between the seeds. Type Locality: Trinidad. Specimens Examined: Panama: Chagres, Fendler 327. Agua Clara, Canal Zone, along Rio Trinidad, fruit, June 20, 1911, Pittier 3984. Culebra, Canal Zone, flowers, January 6, 1911, Pittier 2256. Penonome and vicinity, fruit, March, 1908, Williams 396. Marraganti, South Darien, fruit, April 5, 1908, Williams 995. 3. Swartzia arborescens (Aubl.) Pittier. Possira arborescens Aubl. PI. Guian. 2: 934. pi. 255- 1775^. Tree, 6 to 10 meters high, the branchlets glabrous or pubescent. Leaves glabrous, 3-foliolate or sometimes 1-foliolate; stipules setaceous; 2 For full synonymy see Fl. Bras. IS^: 22. 1870. 158 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 rachis, including petiolar part, 1 to 4 cm. long, narrowly winged and auricu- late at least under the terminal leaflet ; leaflet blades ovate or ovate-elliptic, rounded or cuneate at the base, obtusely short-acuminate, subcoriaceous, lustrous, the terminal leaflet o to 10 cm. long, the primary veins numerous, parallel, and conspicuous. Racemes axillary or terminal, the short slender glabrous peduncles with 2 to 4 flowers; pedicels filiform, 1 to 1..5 cm. long; bracts small, setaceous; bracteoles very small or none; buds quite glabrous, subglobose, hardly 4 mm. in diameter; petal orbicular, unguiculate, a little longer than the calyx; stamens IS to 20, almost all equal, twice longer than the calyx, the anthers ovate; ovary stipitate, narrow, glabrous, 5- or 6-ovulate, attenuate to a short style, the stipe a little shorter than the calyx. Legume short-stipitate, obliquely ovoid, long-acuminate, 4 to 5 cm. long, thick and carnose; seed oblique-ovoid, the aril lacerate, the raphe very prominent. Type IvOCALITy: Near the source of the Galibi River, French Guiana. This species was collected on Tobago Island by Seemann (no. 1687), but I have seen no specimens of it. 4. Swartzia trifolia Pittier, sp. nov. Small tree, 4 to 5 meters high, the trunk 8 to 12 cm. in diameter, the branchlets, leaves, and inflorescences entirely glabrous, the bark dark red and smooth. Leaves usually 3-foliolate, seldom 5-foliolate, coriaceous; stipules setaceous, stiff, about 4 mm. long; rachis 2 to 5 cm. long, terete, winged-auriculate, the wings broader at the auricles; leaflets subsessile, the blades lanceolate, more or less oblique and rounded at the base, obtusely short-acuminate at the apex, the lateral ones 4. .5 to 7 cm. long, 2 to 2. .3 cm. broad, the terminal one 5.5 to 9 cm. long, 2 to .3.5 cm. broad, the primary veins about 16, anastomosing along the margin, the venation conspicuous on both sides. Flowers not known. Fruiting pedicel about 1 cm. long; stipe 8 mm. long; fruit glabrous, 1-seeded, ovoid, acuminate, 3.5 cm. long, 1.5 cm. broad between the sutures; seed ovoid-subreniform, 2.5 cm. long, brown and lustrous. Type in the U. S. National Herbarium, no. 677726, collected on the savanna of La Tortuga, between El Boquete and Caldera, Panama, at an altitude of about 400 meters, in fruit, March 21, 1911, by H. Pittier (no. 3343). This species is so well characterized by its peculiarly shaped leaves and narrow leaflets that even in the absence of the flowers I do not hesitate to describe it as new. 5. Swartzia myrtifolia J. E. Sm. in Rees' Cycl. 34: Swartzia no. 5. 1819. Small tree, the slender branchlets as well as the leaves and inflorescences glabrous or slightly pubescent. Leaves 3-foliolate or sometimes 1-foliolate; stipules subulate, 3 to 4 mm. long; rachis slender, marginate and more or less distinctly auriculate below the insertion of the leaflets, 2.5 to 5 cm. long; leaflets subsessile, the blades ovate or ovate-oblong, rounded or cuneate at the base, obtusely short-acum- inate at the apex, subcoriaceous, nitidulous, the primary veins numerous and prominent on both sides; lateral leaflets 6.5 to 8 cm. long, 3 to 4 cm. broad; terminal leaflet 6.5 to 14.5 cm. long, 5 to 7 cm. broad. APRIL 4, 1921 pittier: notes on swartzia 159 Racemes axillary or terminal, 2- to 5-flowered, about equaling the petioles; bracts small, setaceous; bractlets minute or none; peduncles short; pedicels slender, 1 to 2 cm. long; buds globose, 6.5 mm. in diameter; segments of the calyx 4, reflexed; petal yellow, orbicular, about 2 cm. in diameter; larger stamens 12 to IS, the anthers oblong; smaller stamens numerous, the anthers half shorter than those of the larger ones; ovary glabrous, narrow, recurved, long-stipitate, S-to 10-ovulate, the style much shorter. Legume nearly 2.5 cm. long, obliquely ovoid-oblong, short-acuminate. Type Locality: West Indies. Specimens Examined: Panama: Obispe Falls, Canal Zone, Hayes. Pinogana, South Dari^n, in forest, flowers, June 21, 1914, Pittier 6676. 6. Swartzia darienensis Pittier, sp. no v. Small spreading tree, entirely glabrous, 6 to 8 meters high, with short trunk and pendent branches, the bark smooth, grayish. Leaves 1- or 3-foliolate, membranous; stipules linear, 4 to 6 mm. long, caducous; petioles of the 1-foliolate leaves 5 to 7 mm. long, articulate and provided at the tip with 2 stiff acute auricles; rachis of the 3-foliolate leaves 3 to 6 cm. long, canaliculate, marginate, with acute auricles at the insertion of the leaflets ; leaflets petiolulate, ovate-elliptic or broadly lanceolate, rounded or obtusely pointed at tip, the lateral ones 7 to 10 cm. long, 3 to 4 cm. broad, the terminal one and the blade of the 1-foliolate leaves 12 to 16 cm. long, 5 to 6 cm. broad; petiolules 4 mm. long; veins very thin, almost parallel, delicately reticulate-anastomosing. Racemes axillary or terminal, often geminate, 3- to 5-flowered; bracts and bractlets linear, minutely pubescent, caducous; rachis 1.5 to 7 cm. long; pedicels 5 to 10 mm. long, clavate, pubescent; segments of the calyx 4, ir- regular, about 1 cm. long; petal pale yellow, irregularly ovate-cordiform, emarginate at the base, about 2.5 cm. long (including the claw, this 5 mm. long) and 3 cm. broad; larger stamens 4 to 9, the smaller ones very numerous, the anthers slightly larger in the former but all alike and broadly ovate or orbicular, with a dark connective; pistil incurved; ovary long-stipitate, 8-ovulate; style a little shorter than the ovary, capitellate. Legume not known. Type in the U. S. National Herbarium, no. 678872, collected on the rocky slope of Mamei Hill, near Gorgona, Canal Zone, Panama, July 6, 1911, by H. Pittier (no. 3800). There is certainly a great deal of confusion as to the segregation of the several very nearly related forms of Swartzia in Panama, and the difficulty of separating them is increased by the vagueness of the descriptions and the lack of material. The species just described belongs without doubt to the polymorphous group of S. myrtijolia, but it seems not to agree with the de- scription of any of the species published. 2. A little known species from GUATEMALA Swartzia guatemalensis (Donn. Sm.) Pittier. Swartzia myrtijolia var. guatemalensis Donn. Sm. Bot. Gaz. 33: 251. 1902. Section Pteropoda. vSmall tree, the branches slender, glabrous or minutely appressed-pubescent. 160 JOURNAIv OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 Leaves 3-foliolate or often reduced to the terminal blade, glabrous or more or less appressed-pubescent ; stipules subulate or linear, minutely pubescent; petioles 1.5 cm. long in the simple leaves, 2.5 to 4 cm. in the compound leaves, glabrous, broadly alate, the wings up to 7 mm. broad, acute or rounded below the insertion of the leaflets; leaflets short-petiolulate, ovate-lanceolate, rounded at the base, obtusely long-acuminate, the main primary veins (of the terminal leaflets) 11 to 14, anastomosing along the margin, prominent on both sides, the intermediate veins numerous and parallel; lateral leaflets 3.5 to 9 cm. long, 1.5 to 4 cm. broad; terminal and single leaflets 8 to 16 cm. long, 3.5 to 6 cm. wide. Inflorescences 2- to 5-flowered, axillary or terminal, the rachis slender, sparsely appressed-pubescent; pedicels subfiliform, 12 to 15 mm. long; buds subglobose or broadly ovoid, glabrous, about 9 mm. long; calyx opening by 3 irregular segments, almost 10 mm. long; petal short-unguiculate, broadly ovate, IG mm. long, 22 mm. broad; longer stamens S, the anthers elongate, recurved; smaller stamens numerous and short; ovary long-stipitate (the stipe 10 to 14 mm. long), 6- to 8-ovulate, glabrous, 6 to 8 mm. long, the style straight, subulate, 5 to G mm. long. Legume not known. Type collected by von Tuerckheim at Cubiquiltz, Alta Verapaz, Guatemala, in flower, May, 1901 (J. D. Smith, no. 7839). This plant, described by Captain John Donnell Smith as a variety of Swartzia myrtifolia, differs from that species in several important particulars, such as the disparity between the lateral and terminal leaflets, the con- spicuousness of the main primary veins, the long acumen of the blades, the broad wing of the petiole, the 3-laciniate calyx, the shape of the petal, the 8 long stamens (instead of 12 to 18), and the long-stipitate ovary. These characters are sufficient to justify specific rank for this interesting member of the Guatemalan flora. OCEANOGRAPHY. — Practical application of the electrical conduc- tivity method of measuring sea water salinity.'^ A. L. Thuras. (Communicated by S. W. Stratton, Bureau of Standards.) Heretofore the only reliable method of measuring the total salt con- tent of sea water has been by chemically titrating for the amount of chlorine present. The relation of chlorine to the total salts being a constant, a measure of the salinity is thereby obtained. Salinity is defined as the number of grams of total salts in 1000 grams of sea water. The titration method, being a laboratory method, requires that the samples after collection be stored in suitable bottles until they can be tested on shore. The disadvantages of such a method are: the loss or breakage of samples, possible errors from evaporation and handling, and the great undesirability of not knowing the physical properties of the waters while they are being investigated. ' Received January 31, 1921. APRIL 4, 1921 THURAS: MEASUREMENT OF SEA WATER SALINITY 161 During the Ice Patrol of 1920 an opportunity was given to use the electrical method of measuring sea water salinity on board ship. An apparatus consisting of instruments and parts secured from the Bureau of Standards was set up on shipboard and several hundred determinations of salinity were made. The operation of the ap- paratus was simple and convenient and at no time did weather condi- tions interfere with the measurements. This apparatus consisted of: a wheatstone bridge, a Leeds and Northrup alternating current galvanometer, a specially constructed electrolytic cell designed for a salinity recorder, ^ a hand regulated temperature bath, and a rebuilt 1/12 horse power direct current motor to give 120 volts, 60 cycles of alternating current when connected to 110 volts direct current. This machine was designed and built by Mr. A. J. Fecht of the Bureau of Standards. All measurements were made at 25° C. and a table was prepared to give salinities directly from the balanced bridge readings. The com- plete apparatus was tested each day by standard sea water taken from a supply which had been carefully measured both by a chemical method and a density method^ before beginning the cruises. This supply of sea water lasted throughout the cruises. The temperature of the electrolytic cell bath could easily be held to within 0.03° C, and the bridge, after balancing the moving coil of the galvanometer so that the center of mass was fairly near the axis of support, could be set to a value corresponding to 0.02 in salinity. No electrical capacity or inductance was necessary for balancing the bridge, and variations in the voltage and frequency of the generator had no appreciable effect on the bridge setting. With the rough apparatus used the determina- tions were accurate to 0.05 in salinity, or better than 0.02 of one per cent. Since the electrical conductivity method may be satisfactorily used at sea to measure the salt content of ocean water, attention is directed to the references given in the foot notes which describe an apparatus which will give a continuous record of sea water salinity from a moving vessel. This instrument in conjunction with an instrument to record temperature, which has been constructed, would give the three most important physical variables of sea water, namely, temperature, salinity and density. Such records taken regularly over the same course would show monthly and yearly variations of these physical properties which might be of much scientific value. 2 See this Journal, 8: 145, 680. 1918. » See this Journal, 7: 605. 1917. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY S37TH MEETING The S37th meeting was held at the Cosmos Club, May 22, 1920, with President Sosman in the chair and 50 persons present. The first two papers of the program were devoted to the general subject Foreign laboratories and societies, the speakers being C. E. Mendenhall and H. L. Curtis. Mr. Mendenhall confined his remarks to his observations and experiences in England referring especially to the Royal Society, the Royal Institution and the Physical vSociety of London. Mr. Curtis spoke of the French societies and laboratories and of the National Physical Lab- oratory of England. Discussion: Messrs. Sosman, Crittenden, Humphreys, Bowie, and Williamson took part in the discussion. The last paper was by W. P. White on Three methods of promoting precision in thermostats. Preliminary publication of this paper appeared in this Journal.^ The paper was discussed by Messrs. Mendenhall, Dickinson, Mueller, and T. S. Sligh. S38TH meeting The 83Sth meeting was held at the Cosmos Club, October 9, 1920. Presi- dent Sosman presided and about 50 members and guests were present. The program was as follows: S. J. Barnett: Further experiments on magnetization by rotation. This paper is a report of progress in the first part of a general investigation of the relations between magnetization and rotation designed to extend the earlier work in this field, to obtain more precise results, and especially to find out whether negative electricity with the known value of m/e is alone re- sponsible for magnetisfn. In earlier papers it has been shown that, if the slowly moving electron, with the value of m/e known from other experiments, is alone involved in the Ampereian vortices, the rotation of a magnetic substance at an angular velocity of one revolution per second is equivalent to placing it in a magnetic field of strength —7.1 X 10"'' gauss directed along the axis of rotation. Two series of experiments made in 1914 and 1915, by a method of electro- magnetic induction, gave 3.6 and 3.1, respectively, instead of 7.1, apparently indicating that negative electricity is chiefly responsible, but that positive electricity also is involved. Another alternative, on the assumption of the correctness of the experimental results, is that negative electricity alone is involved, but that it has, for the motions responsible for magnetism, a smaller value of m/e than that determined in known experiments. Another series of experiments made in 1916 and 1917 by a magnetometer method gave the same sign as before, but gave numbers approximately 5 and 6 in place of 8.1. A few experiments made more than two years ago at the Ohio State University, where the earlier work was done, with copper sub- 1 This Journal, 10: 429-432. 1920. 162 APRIL 4, 1921 proceedings: philosophical society 163 stituted for the magnetic substance, indicated that a part of the effect in the magnetometer experiments was due to eddy currents, the effects of which appear to have been completely eliminated in the work done by the method of electromagnetic induction. This probably accounts for at least a part of the discrepancy between the results obtained by the two methods. In new experiments performed under superior conditions in the non-mag- netic experiment building of the Department of Terrestrial Magnetism, by the magnetometer method, considerable improvements have been made in the completeness with which the earth's field is compensated, in the elimina- tion of mechanical and magnetic disturbances, and in other ways. The polar position of Gauss, which was earlier thought impracticable, has been substituted for the equatorial position, as it makes less difficult the elimina- tion of eddy current effects and has other advantages. Eddy current effects have been more thoroughly studied by rotating copper and otherwise. The work is still in progress and other tests remain to be applied. The most extensive observations have been made on a rod of Norway iron (for which observational curves were shown) . Many observations have been made on a rod of cobalt, and some on rods of cold-rolled steel. All the rods gave values about one-half of 7.1 instead of 7.1, or even less, as in the ex- periments on iron by the method of electromagnetic induction, thus again indicating an effect of positive electricity or else indicating that negative electricity alone is involved, but has, for the motions responsible for mag- netism, a smaller value of m/e than that determined in known experiments. Satisfactory experiments on nickel have not yet been made. It is interesting to observe that, while all the sources of trouble have not yet been removed, the method is so sensitive that, in the later part of the night, when extraneous magnetic disturbances are least, the effect can be measured at even very small speeds. Curves between the scale readings for right and left handed rotations and the time were exhibited showing clearly the effect for cobalt at the speed 3/4 revolution per second. The paper closed with a reference to recent experiments on the converse effect (rotation by magnetization). These experiments, on the theory which has been adopted by the investigators, but which involves an uncertain as- sumption with reference to the seat of the reaction to the resultant electron momentum produced on magnetization, also appear to indicate an effect of positive electricity or else the participation of negative electricity with a value of m/e different from that hitherto known. The paper was illustrated by lantern slides, and was discussed by Mr. Humphreys. S. J. Mauchly: Results of atmospheric electric observations made during solar eclipse of May zg, igig, and summary of similar observations. The only atmospheric-electric observations made within the belt of totality during the total solar eclipse of May 29, 1919, appear to have been those by observers of the Department of Terrestrial Magnetism at Sobral, Brazil. These observations were in charge of Mr. Andrew Thomson, of the Depart- ment of Terrestrial Magnetism, who made measurements of the electrical conductivity of the air due to positive and negative ions, respectively. Mr. Thomson was assisted by Mr. Antonio Lima, a native of Brazil, who had been educated in the United States, and who made potential-gradient observations under Mr. Thomson's direction. 164 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 Owing to considerable cloudiness during the first hour of the eclipse, the conditions at Sobral were not so favorable for the detection of an eclipse- effect as those which favored the observations made for the Department of Terrestrial Magnetism by the author and others, in connection with the eclipse of June 8, 1918. However, in spite of the fact that clouds still remained, they did not obscure the Sun after a time corresponding to about 15 minutes before totality, and it was possible to note, in the results for the remainder of the eclipse, variations of the several elements similar to those observed at Lakin in June, 1918. Briefly enumerated, the Sobral results indicate: (i) A general potential-gradient minimum beginning just before totality and continuing until about 20 minutes after totality. The values during this period were abnormally uniform and about 20 per cent lowei than those which obtained during the equal periods just preceding and following the one under consideration. (2) For both the positive and negative conductivity as de- termined by the ordinary Gerdien apparatus, a maximum of the order of 20 per cent, which set in just after totahty and continued throughout most of the period of potential-gradient minimum. (3) That the air-to-earth current-density, as computed from potential-gradient and total conductivity, remained near the normal station value throughout the period in which obscuration exceeded 50 per cent, and was more constant than during arny equal period of the forenoon. In view of the general agreement between the results obtained at Lakin, in 1918, and at Sobral, in 1919, a detailed study was made of all available data concerning atmospheric-electric observations made during solar ecHpses. It was found that the evidence as a whole is of a very conflicting nature un- less special care is taken to note the apparatus and methods employed by the various observers, and the meteorological (especially cloud) conditions which prevailed during the observations. Following these lines it was found that almost without exception the con- ditions attending previous observations were less favorable for the detection of an eclipse-effect than at Sobral and Lakin, and in nearly all cases where conditions were reasonably favorable the results for potential-gradient and conductivity were in substantial agreement with the foregoing. The paper was illustrated by lantern slides. L. A. Bauer: Results of magnetic and meteorological observations during solar eclipse of May 2Q, igig (illustrated). With the aid of magnetic data from nine stations within the region of visi- bility of the solar eclipse of May 29, 1919, five of these stations being those at which observations were made by the expeditions of the Department of Terrestrial Magnetism of the Carnegie Institution of Washington, and from about eighteen cooperative stations distributed outside the region, the fol- lowing main conclusions weie drawn: (j) Magnetic effects of appreciable and determinable magnitude were ob- served during the solar eclipse of May 29, 1919, at stations inside the region of totality as well as at certain stations in the sunlit region, the magnitude and character of the effects being similar to those observed during previous solar eclipses and showing a distinct connection with the eclipse circumstances. The magnetic data for stations in the night region of the globe did not exhibit similar effects. APRIL 4, 1921 proceedings: philosophical society 165 (2) There were two principal variations (with some subordinate ones), as shown especially at stations near the totahty-belt, having periods approxi- mately that of the entire eclipse (5h. 10 m.) and that of the local eclipse (on the average about 2 hours from first to last contact) . There are evidences that the efifects continued for some time after the end of the eclipse at sunset on the southeast coast of Africa. The amplitude (semi-range) of the short wave was, on the average, about one-half of that for the long wave. In the case of the magnetic declination, for example, the amplitude of the long wave for stations inside or near the totality-belt approximated, on the average, one minute of arc, which was equivalent to a horizontal deflecting force of about 0.01 per cent that of the average west-east component of the Earth's magnetism. (j) A preliminary analysis of the magnetic effects at stations within the region of visibility, or in close proximity, showed that the effects in declination and horizontal intensity were similar to those produced by a north-end at- tracting focus located in the vicinity of the shadow cone. With the aid of the vertical-intensity effects it was found that the eclipse magnetic system was composed of an external and an internal system of forces. At 12h. SOm.G.M.T., May 29, 1919, just before the maximum development of the eclipse system, the north end attracting focus of the external system was located east-southeast of the shadow cone, and that of the internal system was to the northward of the cone and approximately northward of the point where the Sun and the Moon were in the zenith. The momentarily increased magnetization of the Earth for stations near the belt of totality of 0.012 per cent at 12h. 30m. corresponded to the amount associated with about a six per cent decrease in solar radiation. Equally interesting results were dis- closed at other times; invariably the positions of the foci of the disturbing forces could be related to the momentary position of the shadow-cone. The indications are that the complete analysis of the eclipse magnetic system will show that it has characteristics analogous to those exhibited by the systems causing the solar-diurnal and the lunar-diurnal variations of the Earth's magnetism. 839th meeting The S39th meeting was held at the Cosmos Club, October 23, 1920. Presi- dent SoSMAN presided and 25 persons were present. The program was as follows : William Bowie: The Pan-Pacific Scientific Congress. The speaker presented a paper on the recent scientific conference for the exploration of the Pacific which was held under the auspices of the Pan-Pa- cific Union in Honolulu, August 2-20, 1920. In the winter of 1919-20, a committee of the National Research Council, formed to consider the scientific exploration of the Pacific, held several meetings at which the necessary pre- liminary steps were taken and then the activities were transferred to Honolulu where a local committee of scientists perfected arrangements for the conference. At the conference were representatives of the United States, Canada, Japan, New Zealand, Australia, the Philippine Islands and Hawaii. The organization of the conference was described, and the general resolu- tions and those resolutions bearing on the geographic subjects which were adopted by the conference were explained in some detail. The scientific 166 JOURNAL OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 work considered under geography consisted of geodesy, topography, physical oceanography, terrestrial magnetism, and meteorology. It was found that much work remains to be done in the Pacific in the various branches of science, and one of the purposes of the Congress was to present the evidence that would show that some central organization should be created that could assist and be a coordinating agency in scientific explora- tion in the Pacific region. It was the opinion of all those at the conference that the most urgent needs are in topographic mapping, including the shore line of the continents and islands, and oceanography, especially the con- figuration of the bottom of the ocean and the mapping of the direction and strength of the ocean currents. On this work, that is, topographic surveys and ocean charts, must be based much of the work in other lines of science. The sessions of the conference were held at Honolulu, except that two general sessions, one on volcanology and one on seismology, were held at the volcano of Kilauea, which most of the delegates visited. The speaker expressed appreciation of the hospitality and good will shown by the people of Honolulu to the members of the scientific congress. It was stated that a publication will be issued by the Conference giving the resolutions and a brief history of the meeting. This publication will probably be distributed in the very near future. Later in the winter it is expected that one or more volumes will be published which will contain abstracts of minutes of the general sessions and of the meetings of the various sections, papers which were presented at Honolulu, and statements in regard to the various branches of science which are now in process of publication by the members of the conference. These later papers are expected to cover in more comprehensive form the problems of the scientific exploration of the Pacific region. Discussion: Messrs. Silsbee, Sosman, Ferner, Mauchly, and Humph- reys discussed Mr. Bowie's paper. P. V. Wells: The iq20 meeting of the British Association for the Ad- vancement of Science. The meetings were held at Cardiff in the new public buildings which are grouped about a beautiful campus, leaving room at one end for the future Welsh Houses of Parliament. Sectional meetings opened on Tuesday morn- ing (Aug. 24) with the presidential addresses, those of Prof. Karl Pearson on Anthropology and of Prof. EddingTon on the Constitution of the Stars being particular features. The latter spoke of the radiative equilibrium in gaseous giant stars, their change in temperature from red to blue and final contraction to red dwarfs. Although the radiation within the giants is much like that of soft X-rays, their interior being at a temperature of millions of degrees, such stars are nearly heat tight. The radiation pressure prevents rapid shrinking and in fact overcomes gravitation in stars of much more than five times the mass of the sun, causing them to break up. AsTon's experiments leave no room for doubt that all the elements are built up of hydrogen and electrons, and the heat of the stars is accounted for by the mass radiated during their combination. "If indeed the sub-atomic energy in the stars is being freely used to maintain their great furnaces, it seems to bring a little nearer to fulfilment our dream of controlling this latent power for the well- being of the human race, or for its suicide." In the evening President Herdman suggested a new Challenger expedition in his address on Oceanography. The next morning Aston described his APRIL 4, 1921 proceedings: philosophical society 1(37 epoch-making work on mass spectra proving atomic masses of all the elements to be whole numbers excepting hydrogen. Neon, chlorine, argon and many other elements are mixtures of isotopes of different masses but of the same atomic number (the number of positive charges on the nucleus which de- termines its atomic properties). Sir Ernest Rutherford followed with a short description of his work on the disintegration of nitrogen and other gases into hydrogen particles moving ■with, greater velocity than the bombarding a-particles themselves. Thus without doubt the hydrogen nucleus is the positive electron and stable groups of minute hydrogen particles, bound together by the much larger negative electrons, such as the helium nucleus (a-particle) form the nuclei of all the heavier atoms. Especially interesting also were the remarkable discussion on the Origin of Spectra led by Nicholson, the note of Sir Oliver Lodge on Relativity and the reply of Pres. EddingTon, the evening discourse of Sir Richard Glazebrook on Aircraft and the vote of thanks moved by Dr. StraTTon of our Bureau of Standards. The wealth of things of interest in other branches of science, and the pleasant excursions of all sorts filled every moment of a busy and delightful week. Discussion: The paper was discussed by Messrs. Silsbee and SosmaN. 840th meeting The 840th meeting was held at the Cosmos Club, November 6, 1920, with President Sosman in the chair and 32 persons present. The following pro- gram was given : E. F. Mueller and T. S. Sligh, Jr.: The hypsonieter as a precision in- strument (presented by Mr. Mueller). A very simple form of hypsometer, consisting of a nearly closed space into which steam from a boiler can be admitted, will serve to maintain a tempera- ture in the steam space which differs at most by a very few hundredths of a degree from that corresponding to saturated steam at the prevailing atmos- pheric pressure. The well-known Rudberg or Regnault hypsometer is a Y&ry simple apparatus, and is capable of serving the requirements of all but the most precise thermometric measurements. In the more elaborate de- signs which have been developed at the International Bureau and at the Reichsanstalt, the design has been largely influenced by such considerations as the desirability of being able to read mercurial thermometers in either a horizontal or a vertical position, of measuring accurately the difference be- tween the pressure of the steam and atmospheric pressure, or of avoiding superheating of the steam, the last named feature being particularly empha- sized. Apparently the question of purity of material, or the possibility of the steam being mixed with air, has received only incidental consideration. In the design of a new portable hypsometer, advantage was taken of the difference in density of steam and air to insure rapid removal of air from the steam space by introducing the steam into this space at the top. This has the further advantage of rendering the temperature stable with no appreciable excess pressure in the steam space thus dispensing with the water manometer. Electric heating is used and the volume of the boiler is small, so that heating up is rapid. Two sheath heating coils are used which, connected in parallel, provide rapid heating, and connected in series suffice for regular operation. Experiments with heat inputs from 125 to 640 watts indicate that such 168 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 variations produced no measurable eflfect in the temperature of the steam space, thus indicating the absence of both superheating and excess pressure in the steam space. Extended experiments were made to determine the reasons for the fortui- tous errors of about 0.005° usually observed in precise steam point determina- tions. Apparently such errors are due to irregular fluctuations in atmos- pheric pressure and to errors in measurement of barometric pressure, indicat- ing that improvements in this respect will require the use of a closed system and better temperature control of the barometer. The instrument described was exhibited and operated. Discussion: The paper was discussed by Messrs. White, Tuckerman, SosMAN, Heyl, and Beall. T. S. Sligh, Jr.: Thermostatics. In this paper it is shown that the degree of temperature regulation attain- able in a thermostated bath depends upon the thermal and space relations of the various elements of the bath to an equal if not greater extent than upon the characteristics of the thermoregulator alone. The three desirable characteristics of a thermoregulated bath are: steadi- ness of controlled temperature, constancy of controlled temperature, and range of regulation. Steadiness is measured in terms of the periodic variations of the instantane- ous temperatures of the working-space as the regulator operates. It is de- sirable that the amplitude of this variation be small and that the period be short. Constancy is measured in terms of the variations of the time-average tem- perature of the working-space as measured over a complete cycle of operation of the regulator with variations of average rate of energy gain or loss from the bath. Range may be measured in terms of the average energy input controlled by the regulator or its equivalent, the number of degrees of change in sur- roundings temperature for which the regulator is able to compensate. It is shown by reference to the characteristic equations for thermostatic regulators as derived in the author's paper ^ that some gain is to be secured by increasing the sensitivity of the regulator but, in view of present practice, it seems that increased constancy, steadiness, and range can best be secured by reducing the over-all lag of the system. This lag is made up of the lag of the heater, the lag, or lapse, due to the time required for the water to circulate from the heater to the regulator bulb, and the lag of the regulator bulb. The lag of the heater may be made small by the use of a heating coil of small heat capacity and large dissipating surface. The stirring lapse may be made small by securing vigorous circulation and by placing the regulator bulb as close to the heater as is possible without the inclusion of a temperature gradient region between the regulator bulb and the working space. The regulator lag may be made small by the use of bulbs of large surface volume ratio and by securing a vigorous circulation of water past the bulb, thus reducing the thermal resistance of the bulb surface. Great steadiness together with large range may be secured by the use of the oscillating contact regulator which is described in the paper referred to above. ' Some characteristics of the Couy thermoregulator. Journ. Am. Chem. Soc. Jan. 1920. APRIL 4, 1921 proceedings: philosophical society 169 Great range together with constancy may be realized by the use of an auxiliary compensator which consists of a motor geared to the contact of the rheostat which controls the fixed heat supply to the bath. The direction of rotation of this motor is periodically reversed by a relay in such a manner that the fixed heating tends to be slowly increased or decreased during the parts of the cycle of operation of the regulator during which an increased or decreased supply of energy is required by the bath. Thus the fixed heating is increased or decreased as the bath requires an increased or decreased sup- ply of energv^ over one or more complete cycles of operation of the regulator. It is seen that this method of regulation requires only a temporary departure of the bath temperature from its normal value in order that a permanent change in the heating be efTected, whereas without the auxiliary' compensating mechanism the change in the heating persists only during the time that the bath temperature remains above or below normal. The auxiliary compensator may be used in connection with the oscillating contact regulator to secure steadiness, constancy, and range to a high degree. Discussion: This paper was discussed by Messrs. White, Beall, Breit, TucKERMAN, Ferner, Wenner, Adams, Van Dusen, Heyl, Mueller, and SOSMAN. S. J. Mauchly, Recording Secretary SCIENTIFIC NOTES AND NEWS MATTERS OF SCIENTIFIC INTEREST IN CONGRESS.^ The third session of the vSixty-sixth Congress convened on December 6, 1920. Under a special rule adopted on December 14, the joint resolution (SJ. 191) to create a joint commission on reorganization of the administrative branch of the Federal Government was brought up for two hours' debate on that date and passed by the House, having already passed the Senate on May 10. The bill became Public Resolution No. 54 on December 30 without Executive approval. The resolution requires the Committee to make a report in De- cember, 1922. Mr. Smoot announced in February that the Committee would do the work personally and would not turn it over to the Bureau of Efficiency or any other governmental agency. Considerable shifting and rearrangement of the scientific bureaus has been predicted as a probable out- come of the reorganization movement. The House Committee on Patents recommended on December 10 that the Nolan Patent Office bill (H.R. 119S4) be sent to conference, but unanimous consent for such reference was refused in the House. Later, on December 14, the bill was sent to conference, and hearings were reopened by the confer- ence committee in January. Section 9 of the bill, providing for the issuance of patents to Federal employees, continued to meet with opposition from commercial and industrial interests, but was retained in the bill. The House agreed to the conference report on February IG. Opposition developed in the Senate, and the bill did not reach final action before the end of the session on March 4. The bill for Federal supervision of the nitrate plants (S. 3390), including provision for research on the fixation of nitrogen, was made the unfinished business in the Senate on December 15. After several debates and the adoption of a number of amendments, the bill passed the Senate on January 14. The House took no final action. The American Society of Zoologists, at its annual meeting on December 28-30, 1920, passed resolutions protesting against the passage of that part of H.R. 7785 (the scientific apparatus tariff bill) which abolishes the "duty- free privilege" to educational institutions. Occasional protests against this feature of the bill have been discussed in current scientific and technical periodicals. This feature of the bill was brought up in a hearing on the Fordney emergency tariff bill before the House Committee on Ways and Means on February 14, and the sentiment of the Committee seemed to be strongly in favor of eliminating the duty-free privilege on chemical glassware, chemical porcelain and apparatus. The Fordney bill passed both houses, but was vetoed by the President. ' Preceding report: This Journal, 10: 423. 1920. 170 APRIL 4, 1921 SCIENTIFIC NOTES AND NEWS 171 As for the special bill for a tariff on scientific supplies (H.R. TTSo), although it had passed the House as long ago as August 2, 1919, the vSenate took no final action and it lapsed with the adjournment on March 4. A bill "to fix the metric system of weights and measures as the single stand- ard for weights and measures" was introduced in the House by Mr Britten on December 29 (H.R. 15420), and in the Senate by Mr. Freunghuysen (by request) on December 18 (S. 4675). The bills are said to have been "fathered" by the World Trade Club of San Francisco. They were referred to the respective weights and measures committees and no further action was taken. The Smith-Towner bill to create a Department of Education (S. 1017 and H.R. 7) after lying dormant through nearly the entire life of the Con- gress, was reported in the House on January 17 and in Senate on March 1, but progressed no further. A step toward the erection of the proposed building for the National Academy of Sciences was taken in the introduction of S. 4045, "to authorize the Commissioners of the District of Columbia to close upper Water Street between 21st and 22d Streets, NW." The bill passed the Senate on February 24, but advanced no further. With the adjournment of the Sixty-sixth Congress at noon on March 4, various other bills and resolutions which are of interest to scientists and which have been commented upon in this section of the Journal either perished in committees or at the intermediate stage of progress last noted in these columns. NOTES The twenty-third edition of the Directory of the Washington Academy of Sciences and its affiliated societies (the "Red Book")appeared early in March. This edition contains 2779 names and data concerning 35 societies. The following lectures have been presented before the Physics Club of the Bureau of Standards during the present season: November 1, 1920, W. J. Humphreys: TJie roaring mountain and associated phenomena. November 15, J. C. Karcher: X-ray spectroscopy, with special reference to X-ray spectra in vacuo. November 29, R. C. Tolman: The rate of chemical reaction. De- cember 13, F. C. Brown: Propagated light sensitiveness of selenium. January 10, 1921, I. G. Priest: Chicago meeting of the Optical Society of America; E. A. Eckhardt: Chicago meeting of the American Physical Society. January 24, R. S. Woodward : The doctrine of relativity and Einstein's theory of gravi- tation. February 7, P. V. Wells: Statistics, or the theory of sampling, and its relation to the physical sciences. March 7 and 21, P. D. Foote: Modern developments of the Bohr theory of atomic structure. The following-named officers were elected at the annual meeting of the Scientific-Technical Section of Federal Employees Union No. 2 in December: President: J. Franklin Meyer, Bureau of Standards; Vice-President: Geo. A. Hill, U. S. Naval Observatory; and Secretary -Treasurer: C. T. Jarvis, Bureau of Education. At the meeting of the Board of Delegates on February 24, D. R. Glass, Public Health Service, was elected Secretary-Treasurer, to succeed C. T. Jarvis, resigned. The following were named members of the Executive Committee: V. K. Chesnut, Bureau of Chemistry; Miss Eunice Oberly, Library, Department of Agriculture; W. C. Thurber, Patent Office; and W. I. Swanton, Reclamation Service. The section of vertebrate paleontology of the National Museum has just 172 JOURNAL OI' TUB WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 7 received, from the Upper Cretaceous deposits along the Red Deer River of Alberta, Canada, an exhibition specimen of a skull of the crested dinosaur Stephanosaurus, a unique genus heretofore unrepresented in the collections. Stephanosaurus is remarkable on account of the development on the top of the skull of a high thin bony crest resembling that of the living Cassowary. Dr. D. Borodin, Russian economic entomologist, has been visiting Wash- ington and has been looking up Russian entomological literature in the libraries of this city. Before the revolution Dr. Borodin was director of the Agricultural Experiment Station at Poltawa, in southern Russia. The honorary degree of Doctor of Sciences was conferred upon Messrs. Frederick V. Coville, botanist in the Bureau of Plant Industry, U. S. Department of Agriculture, and Frank vSpringer, paleontologist in the U. S. National Museum, at the centenary graduation exercises of George Washing- ton University on February 22. Mr. C. R. DeLong has been appointed chief of the chemical division of the U. S. Tariff Commission, succeeding Dr. Grinnell Jones, who has re- turned to Harvard University but retains a connection with the Commission in an advisory capacity. The other members of the chemical staff of the Commission are Messrs. S. D. Kirkpatrick, W. N. Watson, and A. R. Willis. Dr. Alfred DoolittlE, professor of mathematics and instructor in as- tronomy at the Catholic University since 1S98, died on February 23, 1921. Dr. Pentti Eskola, of the Geological Survey Commission of Finland, is engaged in petrologic research at the Geophysical Laboratory of the Carnegie Institution of Washington. Dr. Maurice C. Hall, of the Bureau of Animal Industry, has been elected secretary of the Washington Alumni Chapter of the Society of the Sigma Xi. The vSociety plans to have a series of informal inspection trips to the scientific institutions of the city. Dr. L. I. Shaw, of the Bureau of Mines, has been elected treasurer of the Chemical Society, succeeding the late Frederic P. Dewey. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 April 19, 1921 No. 8 BOTANY. — Synopsis of the genus Datura.^ William E. Safford, Bureau of Plant Industry. A critical study of the genus Datura has revealed great confusion in botanical literature in connection with the specific identity, as well as the origin, of some of the most common species.- Some authors, for example, call a certain species endemic in Mexico and northern South America Datura metel; but the true Datura metel, described by Linnaeus in the first edition of his Species Plantarum, is a species based upon the Asiatic metel nut, or "jouz-methel," which was used as a narcotic by the Arabs, Persians, and Hindoos long before the discovery of America, and was described by Avicenna in the eleventh centur}^ Forms of this species, differing from the type in color and in the re- duplication of the corolla, have been set apart as a distinct species under the name Datura fastuosa, while the white-flowered type itself was rechristened Datura alba. Much of the confusion is due to the treatment which this genus received at the hands of Dunal in the first part of volume thirteen of De Candolle's Prodromus (1852), in which the name Datura metel was transferred from the Asiatic plant above mentioned to an American plant described in 1768 by Miller under the name Datura innoxia. Conflicting statements regarding the origin of the well known James- town weed [Datura stramonium L.) are frequently encountered.^ Cer- tain authors declare it to be of Asiatic origin, although Linnaeus in describing it states that it is American. Others assign the typical form, with green stem and white flowers, to Asia, and the purple-stemmed lavender-flowered form, commonly called Datura tatula, to America. Still others have separated a variety with smooth capsules from the typical prickly-fruited form under the name Datura inermis. Ob- serN-^ations on growing plants show that both the white-flowered and purple-flowered forms may bear either smooth or prickly capsules, in some cases even on the same plant. Experiments in cross-breeding have demonstrated that of the antagonistic color characters, the ' Received March 14, 192L 2 See Hemsley, Biol. Centr. Am. Bot. 2: 427. 1882. ' See Robinson & Fernald, Gray's Manual ed. 7. 717. 1908. Brixton & Brown, lUustr. Fl. ed. 2. 3: 169. 1913. 173 174 JOURNAL or THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 8 purple is dominant and the white-flowered form recessive, and of the contrasted capsule forms the prickly one is dominant and the unarmed (inermis) recessive ; so that at one end of the series we have the so- called Datura tatula and at the other the white-flowered "Datttra inermis." This is discussed in the author's forth-coming paper, "Datura, an inviting genus J or the study of heredity," to be published in the Journal of Heredity. The tree daturas of South America have been segregated as a dis- tinct genus under the name Brugmansia, chiefly on the score that they have fleshy spineless indehiscent fruits devoid of a persistent expanded calyx base; but the section Ceratocaulis is characterized by similar fruits and may be regarded as connecting the tree daturas with the section Dutra, in which the capsules are irregularly dehiscent and in- clined or nodding, quite unlike the erect valvate capsules of the sec- tion Stramonium. A study of the tree daturas shows that more than one species has been included under certain specific names. Thus Datura arhorea of Ruiz and Pavon and Brugmansia arhorea of Lagerheim are specifically distinct from the true Datiira arhorea L-, based upon P^re Feuillce's Stramonioides arhoreum, and the pubescent orange-flowered huantuc of Ecuador, with sinuate woolly leaves, is also quite distinct from the typical Datura sanguinea of Ruiz and Pavon, with which it has been confused. The following systematic synopsis is part of a paper submitted by the writer as a thesis for the degree of Doctor of Philosophy at George Washington University. The remainder of the paper, illustrated by numerous photographs of living plants, will appear in the forthcoming Year Book of the vSmithsonian Institution. DESCRIPTION OF THE GENUS The genus Datura, established by lyinnaeus (Gen. no. 246) with Datura stramonium as its type, belongs to the family Solanaceae and to the tribe Datureae, which includes also the closely allied genus Solandra of tropical and subtropical America. It may be characterized as follows: Calyx long-tubular, herbaceous, appressed to the corolla tube or inflated, toothed at the apex or spathe-like and split down the side, in certain groups circurascissile at the base, leaving a disk which enlarges like a shield or cup subtending the fruit; in another group either disappearing entirely or per- sisting like a husk which covers the lower part of the fruit. Corolla funnel- shaped or trumpet- shaped, in certain species suggesting the corolla of a Convohndus, the tube usually long and slender, the limb plicate and either 5-lobed with the lobes separated by sinuses, or circular or lo-angled, with the margin between the 5 teeth entire or obtusely angled, the angles sometimes cuspidate giving to the expanded limb the form of a lo-pointed star. Stamens APRIL 19, 1921 safford: synopsis of datura 175 5, perfect, adnate to the inner surface of the tube at the middle or near the base, shghtly or not at all exserted, the filaments slender and thread-like, tlie anthers linear, free or rarely cohering, the anther-cells parallel, longitudinally- dehiscent. Ovary 2-celled (sometimes falsely 4-celled); style thread-like; stigma 2-lobed. Fruit a dehiscent 4-valved capsule or a more or less fleshy berry, the surface spiny or smooth. Seeds numerous, compressed laterally, discoid or imperfectly ear-shaped, sometimes with a cork-like covering; embryo curved, cotyledons semiterete. — Herbs, shrubs, or small trees, glabrous, farinaceous, or pubescent. Leaves broad, thin, entire, angulate, or coarsely sinuate-dentate. Flowers solitary, erect or drooping, sometimes very large. KEY TO THE SECTIONS F'lowers erect; calyx circumscissile near the base, the base persistent and ex- panding like a frill, shield or cup. Fruit an erect dehiscent 4-valved capsule. I. Stranwnhim. Fruit inclined or nodding, not dehiscing regularly. Plants terrestrial; pericarp spiny or tuberculate, with an expanded, frilled or shield-like calyx-base. II. Dutra. Plants aquatic or marsh-loving; pericarp smooth, with small discoid or cup-like calyx-base. III. Ceraiocaidis. Flowers pendulous; calyx not circumscissile, either falling off entirely or per- sisting like a husk appressed to the fruit, the latter unarmed and inde- hiscent, spheroid, lemon-shaped, fusiform, or elongated and terete. IV. Brugmansta. vSection I. Stramonium Gaertner. Flowers erect; calyx tube circumscissile near the base, falling off together with the corolla, the base persisting and expanding into a disc, the margin of which is at length turned downward and frilled. Corolla distinctly 5-lobed, the lobes separated by emarginate sinuses. Fruit (Fig. i. A) an erect regu- larly dehiscent 4-valved capsule, armed with rigid spines or unarmed. Type of the section, Datura stramonium L. KEY TO THE SPECIES Capsule normally armed with subequal spines, these sometimes much abrevi- ated or wanting; flowers white or lavender-coloied. i. D. stramonium . Capsules armed with strongly unequal spines, the upper ones longer and stouter. Leaves ovate or oblong; sinuate- toothed or angled. 2. D.ferox. Leaves pinnately lobed. Branches, petioles, and calyx downy or woolly. 3. D. quercifolia. Branches, petioles, and calyx villous or hair}% 4. D. villosa. 1. Datura stramonium L. Sp. PI. 1: 179. 1753. Datura tatula L. Sp. PI. ed 2. i: 256. 1762. Datura inermis Jacq. Hort. Vindob. 3: 44. pi. 82. 1776. Type Locality: "Habitat in America, nunc vulgaris per Europem." Range: Throughout eastern North America, Central America, and South America; introduced at a very early date into the warmer regions of Eu- rope, Asia, and Africa. A common weed in waste places, used by the Algonquin Indians as a nar- cotic* The purple -flowered variety is commonly known under the name D. tatula, the form with unarmed fruits as D. inermis. * For the origin of its common name, Jamestown, or Jimson, weed, see BEVERLEY, Hist. Virginia, book 2, p. 24. 1706. ]/(■) JOURNAL Ol' THIv WASHINGTON ACADEMY OF SCIRNCRS VOL. 11, NO. 8 >j r$-i ^mim VA V >_ ^'7t^ •^^ V" (^ IS Fig. 1. Fruits of Datura. A, Datura stramonium L. ; B, D.metel L.; C, D. melel fastuosa h-; D, D. meieloides Dunal; E, D. ceratocaiila Jacq.; F, D. sangmnea R. & P.; G, D. arhorea L. All natural size. APRIL 10, 1021 safford: synopsis of datura 177 2. Datura ferox L. Amoen. Acad. 3: 403. 1764. Type Locality: "Habitat in China." Kange: Warmer regions of China; introduced into Sicily and Spain. A weed growing in waste places, very similar to D. stramonmni, with the pericarp bearing 4 very large stout spines at the apex. Called in vSpain Esiramonio de la China. 3. Datura quercifolia H. B. K. Nov. Gen. & Sp. 3: 7. 1818. Type Locality: "Cfescit locis temperatis Regni Mexicani prope Zelaya et Molino de Saravia, alt. 930 hex." Range : Texas to Arizona and Mexico. A common weed along the banks of ditches. Leaves pinnately lobed; pericarps armed with large rigid ascending spines. 4. Datura villosa Fernald, Proc. Amer. Acad. 35: 571. 1900. Type Locality: Bolanos, Jalisco, Mexico. R.\nge: Jalisco and vSan Luis Potosi, Mexico, at altitudes of 1800 to 2500 meters. A weed growing in waste places, related to D. qtiercijolia, with which it has been confused. Section II. Dutra Bernhardi. Flowers erect; corolla trumpet-shaped or funnel-shaped, the expanded limb either 5-lobed or lo-angled; calyx-tube circumscissile, falling off with the corolla, the persistent base at length expanding into a membranous frill or cup, either reflexed or appressed to the fruit. Fruit (Fig. i, B, C, D) borne on an inclined or nodding peduncle, not valvate but at length breaking open irregularly, its surface tuberculate or spiny, the spines sometimes flexible and not pungent, in some species pubescent. Type of the section, Datura metel L. KEY TO THE species Fruiting peduncle usually curved to one side, sometimes cernuous; pericarp tuberculate or armed with short spines; plant glabrous or nearly so; corolla white or colored, normally 5-lobed, in cultivation often double or triple, the outer corolla 5-lobed or 6-lobed, the inner corollas 5-10- lobed, the lobes separated by acute sinuses. — An Asiatic species including several well-marked varieties. 5. D. metel. Fruiting peduncle abruptly nodding; pericarp armed with spines; plants pubescent or pruinose; corolla white or tinged with lavender or purple, the expanded limb lo-angled.^ — Plauts of American origin. Flowers more than 6 cm. long. Corolla funnel-shaped, w^hite or tinged with purple or lavender; pericarp armed with weak spines; seeds light brown. Plant softly pubescent; corolla white, lo-toothed. 6. D. innoxia. Plant glaucescent; corolla usually suffused with pale lavender, 5- toothed. 7. D. metel aides. Corolla trumpet-shaped with broadly flaring lo-toothed limb, white with purple or violet throat; pericarp armed with stout spines; seeds black. 8. D. discolor. Flowers not exceeding 6 cm. in length ; corolla w^hite ; pericarp armed with short slender prickles, which together with the whole surface of the capsule are finely pubescent. 9. D. pruinosa. 178 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 8 5. Datura metel L. Sp. PI. 1: 179. 1753. Fig. 1, B, C. Datura fashiosa L. Syst. ed. lo. 2: 932. 1759. Datura alba Nees, Trans. Linn. Soc. 17: 73. 1834. Type Locality: "Habitat in Asia, Africa." Range: Tropical and subtropical Asia and Africa; now widely cultivated throughout the warmer regions of both hemispheres. In the first edition of the Species Plantarum Linnaeus briefly described this species as "Datura pericarpiis spinosis nutantibus, globosis," and cited his earlier description of it in the Hortus Clifortiamis (1737). In the latter work it is identified with the ''Solanum porno spinoso rotunda longo fiore" of Bauhin (1023); "Stramonia multis dicta she ponium spinosmn' of Bauhin's Historia (1651) ; the "hummatu" of Rheede's Hortus Malaharicus (2: 47. pi. 28. 1678) ; ''Stramonia seu Datura, porno spinoso rotunda, longe flore" of Hermann (1687) ; and ''Stramonium fructo spinoso rotunda, flore albo simplici,'" of Tournefort and Boerhaave. The range is cited as "Crescit in Oriente, in Malabaria, Aegyptio, etc." In the second edition of the Species Plantarum (1762) Linnaeus adds to his citations Rumph's Herbarium Amboinense (5: pi. 8y. 1755), in which the simple -flowered Datura metel is figured, ac- companied by the double-flowered form called Datura fastuosa by Linnaeus in the tenth edition of his Sy sterna (1759). He also adds to his description "foliis cordatis subintegris pubescentibus," but this is not applicable to the true Datura metel. This interpolation, if it can be so called, is re- sponsible for much of the resulting confusion of this and allied species. Dunal, in his description of Datura metel in DeCandolle's Prodromus, does not cite the original de- scription of Linnaeus' s Datura 7netel in the first edition of the Species Plantarum, but that of the second edition, in which the plant is erroneously described as pubescent. In the first edition Linnaeus takes great care to identify his Datura metel with the "metel nut" of Asia. Dunal, on the other hand, amends the original description of the species, and refers to it a plant collected by Berlandier in the vicinity of Victoria, in Illustra- eastern Mexico, undoubtedly distinct from the true Datura metel L., but identical with the pubescent white-flowered Datura innoxia Miller, described from a type also collected in eastern Mexico. The latter species can- Fi g. 2. Datura metel L- tion of J. Bauhinius under the name "Stramonia multis dicta sive Pomum spinosum," Hist. PI. 3: 624. 165L cited by Linnaeus in his Hortus Cliffortianus. APRIL 19, 1921 safford: synopsis of datura 179 not possibly be identified with Datura alba Nees, as suggested by Dunal, as that species is the typical white-flowered form of Datura nietel h. ; and Datura innoxia, described below, has its "stalks, branches, and leaves, covered with soft hairs." It is interesting to note that in the Hortus Clifortianus the first two syn- onyms cited identify Linnaeus's Datura metel with the Stramonia, or Pomum spinosum, described and figured by Johannes Bauhin, and clearly identified by him with the Stramonia of Fuchsius and the Nux methel of Avicenna. Bauhin's figures agree with that of Fuchsius (1542) in the form and surface of the fruit, which bears very short and thick spines, not subulate or needle- like prickles; indeed his second figure, here reproduced, is a reduced copy of Fuchsius's.^ It is surprising that C. B. Clarke,^ in Hooker's Flora of British India, not only ignores Linnaeus's references to the authorities above mentioned in con- nection with Datura metel, but transfers this specific name from the metel- nut or dhatura of India to a plant of American origin, citing as an illustration of the species, not the figures of Fuchsius, Bauhinius, or Rumphius, but an illustration in Curtis s Botanical Magazine (plate 1440) which on investigation proves to be the drawing of a plant grown in London under the name Datura innoxia, from seeds of American origin, identical with the Vera Cruz plant described by Miller in 176S under the latter name. The specific identity of the white and purple forms of the Asiatic Datura metel L. is recognized by the best authorities on East Indian botany; but that the perfectly valid name Datura metel should be discarded for the varietal name D. fastuosa, as by Trimen/ is inexcusable. It was this Asiatic plant, called in India Dhatura, or Dtitra, that gave to the genus its name. True to his principle of not adopting a barbarous word for a generic name, Linnaeus latinized the East Indian Dhatura or Dutra; modifying it, however, to the form Datura, and commending the name by the following pun: "Daturae, licet originis sit peregrinae, vocabulum persistere valet, cum a latina derivari potest; dantur et daturae forte in Indiis posthac semina a lascivis foeminis maritis inertibus."* 6. Datura innoxia Mill. Gard. Diet. ed. 8. Datura no. 5. 1768. Datura metel vSims, Curtis's Bot. Mag. 35: pi. 1440. 1812. Not D. metel L. D. guayaquilensis H. B. K. Nov. Gen. & Sp. 3: 8. 1818. D. metel Dunal in DC. Prodr. 13': 543. 1852. '•' Compare the second figure of J. Bauhinius, Hist. Pi. 3: 624. (1651), with the colored engraving in Fuchsius, Hist. Stirp. 690 (1542), which is clearly the true nux methal, or East Indian dhatura, and is quite distinct from the American plant erroneously called Datura metel in modern text-books. '^ Hooker, Fi. Br. Ind. 4: 243. 1885. ' Handb. Fl. Ceyl. 3: 238. 1895. " Hort. Cliflfort. 56. 1737. ISO JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. S Type Locality: "The fifth sort grows naturally at Vera Cruz, from whence I received the seeds." Range: Mexico to South America and the West Indies. Introduced at an early date into the Canary Islands, North Africa, and India. This "downy thorn-apple," as it was called by Sims, has been frequently confused with the Old World Datura metel of Linnaeus, from which it may be readily distinguished by its 10-angled corolla and the soft pubescence of its foliage and young branches. It was characterized by Miller in 1768 as follows: "Datura {Inoxia) pericarpiis spinosis inoxiis ovatis propendentibus foliis cordatis pubescentibus." A plant grown from seeds from Vera Cruz was described by him as follows: "This rises with a purplish stem three to four feet high, dividing into seveial strong branches, garnished with oblong heart-shaped leaves. The stalks, branches, and leaves of this sort are covered with soft hairs ; the flowers come out at the division of the stalks and branches, standing erect; they are large, white, and are succeeded by oval fruit covered with long soft innocent spines, opening into four cells, which are full of brown seeds." The above description accords with that of the Mexican Nacazctd, or Toloatz'in, the leaves of which were characterized by Hernandez^ as "moUia, pinguia, et hirsuta." It was figured by Sims in 1812, as above cited, from a plant grown in London from seeds of American origin. Sims referred it to Linnaeus's Datura metel, but he was not at all confident that he was correct in doing so. "Our plant was said to be raised from seeds sent from Surinam," he says, "and we think it doubtful whether it be the same species as the East Indian plant, which grows to a much larger size and is not described as being so pubescent. . . . We were favored with the plant from which our drawing was taken, by Mr. Salisbur}^ proprietor of the botanic garden in Sloane Street, under the name of Datura innoxia of Miller; and it is not un- likely but it may be the same as the one described by him, which he raised from seeds received from Vera Cruz." Notwithstanding the uncertainty thus expressed by the author, the name Datura metel was subsequently transferred by several botanists from the Asiatic metel-nut, upon which Linnaeus had bestowed it, to this American "downy thorn-apple," a species which may be readily distinguished from the true Datura metel L. not only by its soft pubescent but by its 10-toothed corollas. It seems strange that even in Hooker's Flora of British India the name Datura metel is applied to this introduced plant of American origin, while the true Datura metel is called by a varietal name D. fastuosa, with D. alba Nees given as the name of its typical form, in which the corolla is white and single. 7. Datura meteloides Dunal. in DC. Prodr. 13^: 544. 1852. Fig. 1, D. Datura wrightii Hort. ex Regel, Gartenfl. pi. 260. 1859. Type Locality: "In calidis Novae Hispaniae regionibus." R.ange : Western Texas to California, Mexico, and northern South America. * Hernandez, Res. Med. Nov. Hisp. Thesaurus, 113. 1651. APRIL 10, 1921 safford: synopsis of datura 181 A handsome plant bearing large heavily scented flowers with a decagonal corolla limb, white, usually suffused with lavender or pale violet. Stems and foliage glaucescent. Fruit nodding, indehiscent (Fig. 1 D). This species is held sacred by several Indian tribes of the southwestern United States. It is without doubt the Ololiuhqui of the Aztecs, who used it ceremonially and medicinally very much after the same manner as it is still used by our own Indians in New Mexico, Arizona, and California. An ac- count of the Zuni myth associated with it and its use by the Luisefio Indians of southern California in initiating their youths to manhood will appear in the paper by the writer to be published in the forthcoming Annual Report of the Smithsonian Institution. 8. Datura discolor Bernh. Trommed. N. Journ. Pharm. 26: 149. 1838. Datura thomasii Torr. Pacif. R. R. Rep. 5: 362. 1856. Type Locality: "Habitat in India occidentali." Range: West Indies, Mexico, and the southwestern United States. A plant somewhat resembling D. meteloides, but with the corolla 10-toothed and trumpet-shaped instead of funnel-shaped, and usually stained with purple at the throat. It is easily distinguished from the former, with which it is not infrequently associated, by its smaller flower, black seeds, and the long stout spines with which its smaller nodding fruit is armed. 9. Datura pruinosa Greenm. Proc. Amer. Acad. 33: 486. 1898. Type Locality: Cuicatlan, Oaxaca, Mexico. Range: State of Oaxaca, altitude 550 to 1550 meters. This plant may readily be distinguished from its allies "by the small flowers and the fine pruinose pubescence of the young leaves and the tips of the young branches." Section III. Ceratocaulis vSpach. Fruit (Fig. i, E) a pendent or abruptly deflexed smooth berry, subtended by the enlarged persistent base of the calyx; flowers erect, trumpet-shaped, the calyx spathe-like and split down one side, the corolla tube long and narrow, the limb lo-toothed; stamens exserted, subequal. This section was segre- gated from the rest of the Daturas by Rafinesque, under the name Apemon. key to the species A single species. — Leaves pinnately lobed, farinose beneath; corollas large, white stained with blue. An aquatic plant of Mexico and Central America. 10. D. ceraiocaiila. 10. Datura ceratocaula Ort. Dec. 11. 1798. Fig. 1, E. Datura macrocaulis Roth, Neue Beitr. 159. 1802. Apemon crassicaide Raf. Fl. Tell. 2: 11. 1836. Datura sinuata Sesse & Moc. PI. Nov. Hisp. ed. 2. 24. 1893. Type Locality: "Prope urbem Mexici et in insula Cuba. R.\nge: States of Mexico, Ouerctaro, and Oaxaca, usually in shallow water. A fleshy plant with thick dichotomous stem and horn-like branches, the narcotic "Torna-loco" ("Maddening-plant") of the Mexican marshes. It 182 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 8 was one of the plants called "Atlinan" by the Aztecs, who called it "Sister of the Ololiuhqui" and invoked its spirit in treating certain diseases.^" Section IV. Brugmansia (Persoon). Flowers pendulous, very large; calyx not circumscissile near the base, either falling off entirely or persisting as a husk-like envelope about the base of the fruit; fruit unarmed, smooth, spheroid, oblong, fusiform, or linear and terete. Type of the section. Datura Candida (Persoon). KEY to the species Calyx spathe-like, terminating in a point. Flower white. Corolla more than 20 cm. long; margin of limb between the teeth entire or rounded. 11. D. Candida. Corolla not exceeding 17 cm. in length; margin of limb between the teeth cordate or emarginate. Calyx tapering into a horn-like point. 12. D. cornigera. Calyx without a horn-like apex. 13. D. arborca. Flower colored. Corolla large, more than 25 cm. long. Peduncle, petioles and young branches glabrous; corolla at length turning red. 14. D. versicolor. Peduncle, calyx, nerves of the corolla, and margins of corolla teeth clothed with soft hairs; corolla pink. 15. D. mollis. Corolla small, not exceeding 15 cm. in length, red. IG. D. rubella. Calyx toothed at the apex. Flower white. Anthers coherent; corolla teeth short, about 1 to 2 cm. long. 17. D. suaveolens. Anthers distinct; corolla teeth 2 to 5 cm. long. Fruit ovoid. IS. D.affinis. Fruit long and slender. Leaves lanceolate to ovate-lanceolate, entire. 19. D. dolichocarpa. Leaves linear-oblong, sinuate-repand. 20. D. longifolia. Flower colored. Calyx deciduous, more than half the length of the corolla. Apex 5-toothed; fruit narrowly ovoid, beaked. 21. D. aurea. Apex 2-toothed ; fruit elongate-ovoid, not beaked. 22. D. pittieri. Calyx persistent, less than half the length of the corolla. Uppermost leaves entire or repand, puberulent. 2."). D. sanguinea. Uppermost leaves angular-toothed, densely tomentose. 24. D. rosei. 11. Datura Candida (Pers.) Saflford. Datura arborea Ruiz & Pavon, Fl. Peruv. 2: 15. pi. 12". 1799. Not D. arbor ea L. 17-53. Brtigmansia Candida Pers. Syn. PI. 1: 210. 1805. Type Locality: "Habitat in Peruviae hortis, versuris et septis, passim ad Cercado, Chancay, et Huanuci Provincias." Range : Known only in cultivation ; now widely spread in tropical and sub- tropical countries. "> Jacinto de la Serna, in Documentos Ined. para la Hist, de Espana 104: 159-160. APRIL H), 1921 safford: synopsis of datura 183 This is the large white-flowered Floripondio of the gardens of Northern Chile, Peru, Honduras, Guatemala, and Mexico. It was figured by Ruiz and Pavon, as above cited, under the name Datura arhorea, but is quite distinct specifically from Pere Feuillee's plant, which was the type of Linnaeus's D. arhorea. It is also distinct from Lagerheim's Brugmansia arborea' (see be- yond, no. 18), the calyx of which is 2- to o-toothed, and the peduncle glabrous. The specimens in the National Herbarium, like that figured by Ruiz and Pavon, are characterized by a relatively short, loose, pointed, spathe-like calyx. In the illustration of the fruit of the latter the calyx is represented as persistent, but this may possibly be an error. 12. Datura cornigera Hook. Curtis's Bot. Mag. pi. 42 j2. 1846. Type Locality: Described from a cultivated plant of unknown origin. Range : According to Hemsley, it occurs in the Valley of Mexico. Hooker points out the characters of this plant, which distinguish it from closely allied species, and adds: "It is not the Datura arborea of Linnaeus and of Feuillee, plate 46; nor the Datura arborea of Ruiz and Pavon's plate 128, which has a much larger flower, with the calyx deeply cleft but appressed to the corolla. In the present species it runs out at the apex into a long, subulate spreading point." 1.3. Datura arborea L. Sp. PI. 1: 179. 1753. Fig. 1, G. Type Locality: "Habitat in Peru." R.\XGE: Peruvian Andes. Now widely cultivated in tropical and subtrop- ical countries. This species was based by Linnaeus on the Stramonioides arboreum described and figured by Pere Feuillee in his Journal des Observations Physiques, Mathe- matiques et Botaniques, 1714, and is quite distinct from D. arborea Ruiz & Pavon. The flowers of the type were about 15 cm. (6 inches) long, with the corolla limb distinctly 5-lobed, the lobes separated by distinct sinuses or notches, the peduncle clothed with whitish velvety pubescence, and the broadly ovoid fruit quite devoid of calyx, about 6.25 cm. long and 5.6 cm. in diameter. 14. Datura versicolor (Lagerh.) Saft'ord. Brtigmansia versicolor Lagerh. Bot. Jahrb. Engl. 20: 666. 1895. Type Locality: "Habitat in Aequatoria, ad 'Balsapamba' in regions tropica provinciae Los Rios." Range : Known only from the type locality. A beautiful species with fragrant flowers, the corolla of which, at first white, gradually turns to a brick red color. It is closely allied to D. dolichocarpa, but differs from it in the form of its spindle-shaped fruit, which terminates in a ver}^ long slender point. The petioles and peduncles are quite glabrous. 15. Datura mollis vSafford, sp. nov. Shrub or small tree, with pubescent, ovate-lanceolate, entire or remotely 1S4 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 8 Fi"'. 3. Fruits of South American Tree Daturas belonging to the '■ection Brug- mansia. A, Datura rubella Saflord; B, D. suaveolens H. & B.; C, D. pittieri Safford; D. D. rosej Safford. All X 'A- APRIL 19, 1*)21 safford: synopsis of datura 185 toothed leaves, 22 cm. long, and 10.5 cm. wide; calyx spathe-like, 19 to 20 cm. long, obtusely pointed at apex, somewhat inflated, densely clothed, like the peduncle, with soft spreading hairs; corolla 25 or 2G cm. long, light pink, resembling that of D. Candida in form, the lower half of the tube very slender, the upper part subcylindrical, about 4 cm. in diameter, the limb, flaring to about 12 cm. in diameter, bearing on its margin 5 caudate teeth 6 or 7 cm. long, at length recurved ; nerves of the corolla and margins of the teeth clothed with soft spreading hairs ; margin of the limb between the teeth not emargin- ate; pistil 25 cm. long, slightly exceeding the stamens; stigma slender, 16 mm. long; stamens 23 cm. long, anthers free, 37 mm. long. Type in the U. S. National Herbarium, no. 1,022,914, collected in the \\- cinity of Portovelo, Ecuador, October, 1918, by J. N. Rose (no. 23,418). 16. Datura rubella SafTord, sp. nov. Fig. 2, A. Shrub 8 to 10 feet high, wdth pubescent, ovate-lanceolate, acuminate, en- tire or repand leaves, the upper ones about 10 cm. long by 4 cm. wide; calyx pubescent like the peduncle, spathe-like, 10 cm. long, split clown one side and terminating in a long caudate-acuminate point; corolla red, 13 or 14 cm. long, not widely flaring, the expanded limb about 5 cm. wide, bearing 5 slender caudate teeth about 15 mm. long; nerves of the corolla and teeth clothed with minute spreading hairs; pistil 11 to 11.5 cm. long, terminating in a thick ob- tuse clavate stigma, slightly exceeding the stamens; stamens 10.5 cm. long, the lower part of the filaments hairy, the anthers free, linear, 2 cm. long, pale straw color; fruit (Fig. 2, A) broadly oval or lemon-shaped, 7 cm. long, 5 cm. in diameter, with a small nipple at tip. Type in the U. S. National Herbarium, no. 1,022,434, collected in the vicinity of Cuenca, Ecuador, September, 1918, by J. N. Rose (no. 22,828). Fruit (in formalin) and seeds in Economic Collection, Bureau of Plant In- dustry. 17. Datura suaveolens Humb. &; Bonpl.; Willd. Enum. Hort. Berol. 227. 1809. Fig. 2, B. Datura gardneri Hook. Curtis's Bot. Mag. sub pi. 4252. 1846. Type: A cultivated plant, erroneously stated to be of Mexican origin. Range: Provinces of Minas Geraes and Sao Paulo, Brazil; now much cultivated in the tropics and in conservatories; common in the Antilles. The native country of this species, distinguished from all others by its co- herent anthers and relatively short, much inflated, 5-toothed calyx, was long doubtful, and its fruit has remained undescribed. Fruiting specimens in the U. S. National Herbarium were collected near Caldas, in the province of Minas Geraes, not far from the boundary of Sao Paulo, May 12, 1873, by Dr. Anders Frederik Regnell of that city, and presented by him to the Bo- tanical Museum of Upsala. The 2-celled fruit (Fig. 2, B) is spindle-shaped, 12 to 12.5 cm. long, 2.5 cm. in diameter at the middle, gradually tapering to- ward each end. It is devoid of all vestige of calyx and is borne on a recurved peduncle 7 cm. long. The dry brown pericarp is thin and fragile, glabrous, and longitudinally veined with delicate raised nerves. The large irregular angular seeds are closely packed in the two cells. 186 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. S 18. Datura affinis Safford, sp. nov. Bnigmansia arborea Lagerh. Bot. Jahrb. Engl. 20: 6U3. pi. ii,fig. i. 1895. Not D. arborea L. 1753, or D. arborea Ruiz & Pavon. 1799. Type Locality: Vicinity of Quito, Ecuador. This species, described by Lagerheim from specimens growing in the vi- cinity of Quito, Ecuador, is very closely allied to D. aurea (no. 21). The flowers differ from those of D. arborea I,, in their glabrous peduncle, their 2- to 5-toothed calyx, and in the margin of the corolla limb, which is not emarg- inate or heart-shaped between the teeth, but entire or rounded, as in D. Candida. The fruit, like that of D. aurea, is narrowly obovate, acuminate, and pubescent. The local name is "floripondio bianco." Lagerheim states that this species accords well with specimens labeled D. arborea, from Pavon's Herbarium, seen by him in the Paris Museum. This would identify it with /). arborea R. & P. rather than with D. arborea L. All specimens of D. arborea R. & P. {D. Candida (Persoon) vSafford) examined by the writer have the apex of the calyx not toothed, but terminating in a point, and the peduncle not glabrous but pubescent. 19. Datura dolichocarpa (Lagerh.) Safford. Brugmansia dolichocarpa Lagerh. Bot. Jahrb. Engl. 20: 605. pi. ii, fig. 6-q. 1S95. Type Locality: "Hal)itat in Aequatoria, prope 'Santo Domingo de los Colorados,' in regionc tropica provinciae Pichincha et prope 'Puente de Chimbos' in rcgione tropica provinciae Chimborazo." Range: Tropical Ecuador. This beautiful species grows in the form of small trees of elegant habit. It is closely allied to D. siiaveolens H. & B. and to D. versicolor (Lagerh.). From the former it is distinguished by its very long terete fruit (29-31 cm. long), its free anthers, its very long corolla teeth, and the form of its seeds. 20. Datura longifolia (Lagerh.) Safford. Brugmansia longifolia Lagerh. Bot. Jahrb. Engl. 20: 066. 1895. Type Locality: "Habitat in Aequatoria, ad 'Santo Domingo de los Color- ados' in regione tropica provinciae Pichincha (Sodiro, in Mus. botan. Univ. Quitensis"). Range: Known only from the type locality. This species, with white flowers 27-30 cm. long and 2- to 5-toothed calyx, is distinguished from all the rest by its very long and narrow leaves. Its fruit is still undcscribed. 21. Datura aurea (Lagerh.) Safford. Brugmansia aurea Lagerh. Gartenfl. 42: 33. 1893. Type Locality: "Habitat in Aequatoria, Quito in hortis passim culta." Range: "In silvis regionis subtropicae probabiliter spontanea." This handsome species bears long golden-yellow flowers, with spathe-like calyces 5-toothed at the apex. It is commonl}^ called "floripondio amarillo" APRIL li), 1021 safford: synopsis of datura ] GEOLOGY. — Scientific by-products of applied geology ^ George Otis Smith, U. S. Geological Survey. "By-product" is a term that suggests large-scale industrial engineer- ing and perhaps even "big business." By-product practice carries the complex idea of waste turned into profit, of painstaking engineering converting the raw material into many products, and of persistent salesmanship that finds a market for commodities as varied as dyna- mite and toilet sets or hams and violin strings. Yet, except in its larger commercial aspect, by-product practice is not limited to modern times or to large corporate enterprise; conserving the incidental or the "left-over" was also a virtue of our forefathers. The giving of value to the additional or secondary products and their successful disposal with profit to all, however, seems the modern expression of old-fashioned thrift. So, while no doubt applied geology has always paid its tithes in the form of incidental contributions to the theoretical side of the science, it is probably true that as our geologic efforts have been spread over larger fields, with greater variety of endeavor, these scientific by- products have come to represent greater values to the world of science. As a large operator in applied geology, the United States Geological Survey would be blind to its opportunity if it failed to utilize these scientific by-products, and indeed it is to be hoped that this Federal service has caught the commercial spirit at least to the extent of seeing large profits in by-products. The other type of by-products — eco- nomic results incidental to research — would make a more impressive showing; but that is another story, well worth telling under other auspices. In the program of geologic work of the United States Geological Survey for the last decade three phases of applied geology stand out prominently — land classification, oil and gas exploration, and the study of mineral reserves both in our own and foreign countries. Each of these phases represents a task laid upon the Survey by a national need, but none of them at first glance is expected to include research into fundamental principles of the science of geology. In fact, they have all been looked upon as a levy upon the science rather than as an aid to its progress. However, it may be opportune to pause and suggest some of the valuable by-products of all this work that has absorbed so much of the activities of geologists of high scien- ^ Presented before the Society of Economic Geologists at Chicago in December, 1920, and the Geological Society of Washington on April 13, 1921. Received April 2, 1921. 204 JOURNAL OF The WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 tific training and attainments. To list all these scientific by-products, however, would result in a bibliography imposing in both length and quality. The principal beneficial influence of land classification surveys upon our science has operated through the requirement of quantitative detail and the necessary training for close observation. The geologist trained in this work has, through great travail of spirit, attained notable accuracy in field methods, which has reacted favorably upon standards of work throughout the field organization. The results of scientific value incidental to the large expenditures of effort and money in the classification of public coal, phosphate, and oil lands have included the increased interest in stratigraphic prob- lems and the increased attention to structural details, overlooked in broad regional studies, and to variation in sedimentation. It is not too much to say that a large part of the present knowledge of the Cretaceous and early Tertiary stratigraphy and paleontology of the West can be traced directly to the public coal-land work, broadly administered by Campbell. The Laramie question became a live issue; Stanton, Lloyd and Hares recognized and discussed new prob- lems in the Lance of the northern area, just as Gilmore contributed to the paleontology of the southern area ; Lee and others made substantial revisions of the stratigraphic column for the eastern flank of the Rocky Mountains; and far to the north, Rollick's monographic study of the Cretaceous flora of Alaska and Martin's work on the Mesozoic stratigraphy of Alaska, of which the Triassic chapter has been pub- lished, are a direct outgrowth of the coal and oil investigations. With these and many other highly scientific contributions in mind, it is not too much to credit the fifteen years devoted so largely to examination of the Nation's coal lands with an addition to our geologic knowledge of the West fully comparable with the pioneer results of the similar period of exploration over the same area forty years earlier. The new geologic map of Wyoming now ready for publication is in largest part the result of the activities directed primarily to classifying oil and coal land. Less obvious, perhaps, have been the scientific results of the in- creased attention given to structure, such as the recognition and de- scription of the Bannock overthrust by Richards and Mansfield in mapping phosphate rocks in Idaho or the interpretation of the Hart Mountain overthrust by Hewett as a by-product of his coal and oil work in Wyoming, although the discovery of this great overthrust is May 4, 1921 smith: geological by-products 205 to be credited to Dake. These are displacements on a large scale, but observations of structural details have formed an essential part of the general geologic descriptions by other geologists. A few petro- graphic contributions have also resulted, such as the discovery of the nepheline basalt on the Fort Hall Indian Reservation by Mansfield and the detailed mapping of the Leucite Hills by Schultz. The close observation necessary in tracing coal outcrops and in valuing public lands according to the thickness and character of the coal beds has naturally led to intensive study of variation in sedi- mentation. Thom's work on the Lance and Fort Union sediments, in which the source of sediment deposited in flood-plain swamps is traced by means of microscopic examination, and Hewett's discovery of the persistent presence of bentonite in the Upper Cretaceous series, proving volcanic activity in four States, are important contributions to paleogeographic science — despite the bar sinister. The observed influence of the oil and gas studies by the Federal geologists has aroused a larger interest in geophysics and in physical chemistry, an influence which shows itself for the most part only in- directly but is none the less of large profit to our science. Here again close attention to structural details is yielding theoretical contribu- tions, but probably the most noteworthy by-product of the oil and gas work of the United States Geological Survey has been the augmented interest in the petrology of sedimentary rocks. For purposes of correlation and of interpretation of the details of "oil sand" stra- tigraphy, petrographic methods must be developed and used. Ques- tions of oil genesis, accumulation, and recovery lead to theoretical problems whose solution will deepen our insight into earth processes. The study of mineral resources stimulated by the war also yielded scientific profits, both subjective and objective. Foremost among these I would place the appreciation of the physiographic relation of manganese oxide deposits to stages of planation and of the fact that degree of rock decay depends more upon physiographic stage than upon climate; and the fact that the tracing of deposits of manganese ore in the Appalachian Valley region disclosed a planation stage that had previously received little attention. The study of the literature of foreign mineral reserves as a part of the American problem of raw material supply has also added to our appreciation of exact statement in geologic reports. The critical reader of scientific literature may even profit by the faults of others, and our geologists who have made largest use of the reports on the 206 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 ore deposits of the world have acquired the keenest understanding of what standards are needed in geologic work, in both field and office. This intensive study of the commercial side of geology should tend to make our science more exact. In the course of a discussion at the Baltimore meeting of the Geo- logical Society of America, Dr. Iddings hesitated to characterize pure geology as unapplied geology, and my suggestion was that pure science is simply not-yet-applied science. I believe this descriptive definition stands the test of our experience, and a long list of economic by- products of pure geology could be cited as proof. One such example of the later application of the results of a purely scientific investiga- tion to everyday use of large value may be mentioned here because it illustrates the final point I wish to make. Alden's glacial studies in Wisconsin, which were continued over a decade and covered about 10,000 square miles, resulted in two professional papers, one bulletin, and one geologic folio, each a contribution of high scientific and edu- cational value. Now, an extensive and intensive program of State highway construction has given to this geologic study a value not anticipated. Measured by the commercial standards of value, Alden's glacial mapping is expected to save the State of Wisconsin in the loca- tion of road material at least two and half times what the geologic work cost the Federal Survey. The economic by-product thus more than repays the production costs, and any economist can see a large profit in the operation. The general trend in useful geology is to call for quantitative re- sults, and indeed exactness is more truly scientific than vagueness. Moreover, the testimony of experience is that whatever the purpose of a geologic project, if its execution is thorough-going, its methods exact, and its standards high, it will yield by-products of value. It is therefore from the best of scientific research that economic by- products are obtained and it is only from applied geology well applied that scientific by-products may be expected. The incidental is not accidental. The personal element in geologic by-product practice is not to be overlooked in this brief resume of the subject. Geologists differ in both their telescopic and their microscopic vision, and even more in their catholicity of interest. The field observer whose eyes are open to every type of geologic phenomena, is pre-eminently a by-product man; and whether his primary object is the examination of a dam site or the correlation of two interglacial formations, he returns with note May 4, 1921 clark: evolution of animals 207 book and mind enriched with all that he saw, so that the by-products may eventually outvalue the answer to his original problem. Mr. Gilbert well illustrated the geologist whose researches yielded so great a wealth of products, and in his work the line between pure geology and useful geology was not marked. In that type of geology, broad in scope and accurate in detail, by-products of high value can always be expected. ZOOLOGY. — The steps in the evolution oj animals} Austin H. Clark, U. S. National Museum. In the following dichotomous table are included all the essential characters of all the major animal groups, showing the successive steps by which the two most specialized phyla, the Vertebrata (in heavy-faced type) and the Arthropoda (in italics), have been evolved, and at the same time the relationship to the main developmental line of all the numerous off-shoots which have proved incapable of further evolution. This table, which is based upon the body structure of adults, assumes the evolutionary course to have run as follows: 1. The formation of a multicellular body overcame the limitation in size inseparable from the unicellular body. 2. The appearance of quadrilateral symmetry (with a right and left side and a dorsal and ventral surface) and the correlated development of a head end overcame the inefficiency of a radially symmetrical body. 3. The development of a vascular and of a respiratory system facilitated the repair of waste and led to a marked increase in bodily activity. 4. The development of a skeleton enabled the muscles to function to better advantage, leading to a more perfect coordination of muscular action and greater perfection of bodily activity. 5. The appearance of gill clefts indicated the final stage in the centralization and perfection of the previously unorganized respiratory system. 6. The development of the dorsal nerve cords led to increased ner- vous efficiency through the unification and concentration of the nervous system. 7. The development, in connection with the last, of a definite head, w^as the final step in the centralization of the nervous control of the body. 1 Received March 9, 1921. 208 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 Unicellular Multicellular Radially or bilaterally symmetrical No definite organs nor body form With definite organs and body form Quadrilaterally symmetrical, with a head end No vascular, respiratory or skeletal system Without a special food collecting mechanism Flattened Cylindrical With a special ciliated food collecting apparatus With a vascular system and a respiratory system No true skeleton Unsegmented Segmented With a skeleton Without gill clefts Skeleton soft Skeleton hard Unsegmented externally With a tentacular food collecting mechanism Without a special food collecting mechanism Segmented externally With gill clefts Nerves ventral With a tentacular food collecting mechanism Without a special food collecting mechanism Nerves Dorsal No definite head, and a special food collecting mechanism Food collecting apparatus internal Food collecting apparatus tentacular and external With a definite head ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. PHYSICS. — TJie efflux of gases through small orifices. Edgar Buckingham and J. D. Edwards. Bur. Standards Sci. Paper 359. Pp. 47, figs. 7. 1920. This paper contains a theoretical discussion of the results of experiments made during an investigation of the effusion method of determining gas den- sity. The effects on effusion of viscosity and thermal conductivity of the gas are studied, and formulas for representing these effects are developed and compared with the observed facts. A physical interpretation is thus obtained for the most striking of the apparent anomalies observed in the behavior of gases flowing through very small orifices such as are used in apparatus for determining density by effusion. The resulting agreement of the theory with the observations is exhibited graphically. It is fairly satisfactory but not perfect, and its imperfections suggest the directions in which further experiments should be made. J. D. E. PHYSICS. — The constants of radiation of a uniformly heated enclosure. W. W. CoBLENTz. Bur. of Standards Sci. Paper 357. Pp. 11. 1920. Experimental data are given on atmospheric absorption. The paper gives also a recalculation of the coefficient of total radiation of a uniformly heated enclosure, or so-called black body, giving a value of 5.72 X 10~^^. The eft'ect of atmospheric absorption is discussed, and the conclusion arrived at is that, if corrections are made for atmospheric absorption, the value recently obtained at Naples is close to the average value, viz., 5.7. In the second part of the paper, the present status of the constant of spectral radiation is dis- cussed. W. W. C. PHYSICS. — An integration method of deriving the alternating current resistance and inductance of conductors. H. L. Curtis. Bur. Standards Sci. Paper 374. Pp. 35, figs. 4. 1920. The solution of the problem was met by a process of integration. The conductor is divided into infinitesimal filaments by surfaces which coincide with the lines of flow. The magnetic field at any point is the sum of the magnetic fields of all these filaments. The counter-electromotive force in a filament is determined by the rate at which the magnetic fields of all the others cut this filament. Formulas for the alternating current resistance and inductance of a straight cylindrical conductor were derived by the use both of real and imaginary power series. These formulas correspond exactly with the asymptotic form- ulas of Russell. The same method is applied to a return circuit making use of imaginary series, and formulas for the alternating current resistance and inductance are derived. Values computed by these formulas are compared with experimental results. H. L. C. 209 210 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 PHYSICS. — The variation of residual induction and coercive force with mag- netizing force. R. L. Sanford and W. L. Cheney. Bur. Standards Sci. Paper 384. Pp. 10, figs. 6. 1920. This paper is a report of an investigation to ascertain whether or not analytical expressions similar to the reluctivity relationship of Kennelly correctly represent the variation of residual induction and coercive force with the maximum magnetizing force. Hysteresis measurements were made on a number of samples covering a wide range of material using magnetizing forces up to 2500 gausses. The relationships Hm/Br = Oi + 6iHm and Hm/Hc = a-j + h{H.,n were found to hold within the limits of the probable experimental error. W. L. C. SPECTROvSCOPY. — Relative spectral transmission of the atmosphere. B. Karrer And E. P. T. Tyndall. Bur. Standards Sci. Paper 389. Pp. 37, figs. 20. 1920. Data on the relative spectral transmission are given, (1) for a clear atmos- phere, (2) for the atmosphere of high humidity, and (3) during rains. The curves for (1) show little selectivity. Between wave-lengths 520 and 6G0 m/x the transmission is uniform. At 6G0 it begins to decrease. Also from 520 to 440 m^t it gradually and continuously decreases. The curves for the atmos- pheric condition of (2) and (3) are almost identical for the region from 430 to 560 m/x, the transmission increasing with the wave-length. In the region from 560 to 670 mju the curve for the rainy atmosphere shows a maximum near 640 m/x, while that for the atmosphere of high humidity indicates two maxima, at 5S0 and at 650 m^t, with a miminum near 620 m/x. The de- crease at 660 mju in both cases is very similar to that noted for the clear atmos- phere, and is probably to be associated with the absorption band of the oxygen of the atmosphere. E. K. SPECTROvSCOPY. — Wave lengths longer than 5500K in the arc spectra of seven elements. C. C. KiESS and W. F. Meggers. Bur. Standards Sci. Paper 372. Pp. 29, fig. 1. 1920. The concave grating spectrograph of the Bureau of Standards was used to photograph the yellow, red and infra-red arc spectra of titanium, vanadium, chromium, manganese, molybdenum, tungsten and uranium. This work is a continuation of a program of standard wave-length determination and spec- troscopic analysis which has as one of its objects the mapping of the spectra of chemical elements as far out into the region of long wave-lengths as modern photographic methods will permit. The spectrograms were made on photographic plates sensitized to the long waves by bathing in solutions of dyes. Recently "made-in- America" dyes were used for many of the plates and were as effective in their photo- sensitizing action as the imported ones. The wave-lengths of more than 2500 spectral lines were derived from the measurement of the plates. These wave-lengths extend from the green at 5500 A into the infra-red beyond 9700 A. So far as known, impurity lines and spurious lines have been eliminated from the wave-length tables. Frequency dififerences which are suspected of being constant have been found in each of the spectra here pre- sented. C. C. K. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOvSOPHICAL SOCIETY 84 1st meeting The S41st meeting was held at the Cosmos Club, November 20, 1920, with President Sosman in the chair and 50 persons present. The program was as follows : C. F. Marvin: The law of the geoidal slope and fallacies in dynamic meteor- ology. This paper presented matters of unusual interest and importance relating to what are beheved to be important fundamental errors in mathematical meteorolog}^ which have almost completely eluded detection throughout the past sixty years. Within that time the faults in question have been subscribed to by many of the highest authorities on the dynamics of atmospheric motions among both popular and mathematical writers. The question deals with a correct representation of the possible motion of the atmosphere or of any bodies on a rotating globe when the motions occur entirely without friction of any kind. This question has occupied the at- tention of scientists for nearly 200 years. A correct statement of the under- lying dynamic principles was first arrived at about 1858 by one of our own countrymen, William FerrEL, a member of the Philosophical Society after 1872. FerrEL was many years the senior and the leader of all 'other writers on the mathematical analysis of atmospheric motions, and it is difficult to adequately commend the originality and completeness of his studies. Not- withstanding this there appear to be certain errors in his application of the principles of his own discovery. These have since been perpetuated in many standard text-books on meteorology which call attention to the super-hurricane wind velocities required by the operation of the law of equal areas and claim that these inconceivable velocities are prevented by atmospheric friction, convection, turbulence, etc. These conclusions are inconsistent with Ferrel's very lucid demonstration that the action of gravity upon bodies moving freely over a rotating globe is expressed in two wholly independent inertia reactions. One of these has long been known and dignified by a specific title, the law of the conservation of angular momentum. The other reaction has also long been known, but strangely enough has never been christened. The important part it pla3^s in controlling the motions of the air has been overlooked, or ascribed to friction and turbulence. Beheving these errors to have arisen and spread, at least partly, because of the lack of an appropriate name, it is proposed that the neglected principle be designated by the name of the law of the geoidal slope. For a globe rotating from the west to the east the law may be stated to be : A geoidal surface is a neutral or horizontal surface only for bodies at rest upon it. That is, gravity is powerless to set up any lateral motions among such bodies. The surface slopes towards the equator for every body having a relative motion eastward and towards the pole for every body with a motion westward. A com- ponent of the force of gravity pulls the moving bodies down the slopes. 211 212 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 Without giving a specific name to the tangential pull of gravity down the slopes, Ferrel nevertheless clearly showed that the resultant of this reaction and that arising from the law of equal areas was continually at right angles to the direction of motion of bodies, therefore this deflective influence of the earth's rotation is powerless to change velocities but tends continually to change direction of motions. It was made clear in the paper that it is the pull of gravity down the geoidal slopes, not friction, which prevents the super- hurricane velocities exploited in the text-books. The paper discussed briefly the equation for the steady motions of the atmosphere under balanced forces, both with and without friction, and for different types of pressure distribution. The application of these equations was shown for the case of an ideal frictionless circumpolar cyclone based on pressure charts for January conditions in the free air at an altitude of 1500 meters. The velocities for this circulation are all shown to be reasonable and moderate and are irreconcilable with the super-hurricane polar winds required by the generally accepted mathematical theories when friction is zero. The paper was illustrated with experiments and lantern slides, and has been published in full in the Monthly Weather Review for October, 1920. Discussion: The paper was discussed by Messrs. Lambert, Breit, Sos- MAN and Kimball. W. R. Blair: Weather information for operating concerns (no abstract received) . Discussion: The second paper was discussed by Messrs. Brooks (C.F.), Marvin, Smith, White, vSosman, Ferner, Kimball, Frankenfield, and C A EVERY. annual meeting The S42nd meeting and 50th annual meeting of the Society was held at the Cosmos Club December 4, 1920. President Sosman presided, and 25 members were present. The report of the Secretaries showed the present active membership to be 21.3, with a net gain of 19 for the year. One active member of the Society, Mr. C. H. Sinclair, died during the year. Thirty-seven new members were elected and qualified; 5 were transferred to the active from the absent list, 17 were transferred to the absent list, 2 resigned, and 2 were dropped. During the year the Society held 16 meetings for the presentation of papers. The average attendance at these meetings was 44, and the total number of papers read was 37. The report of the Treasurer, Mr. J. A. Fleming, showed receipts of $1318.42. Of this amount, $639.25 was from dues, $632.67 from interest, and $46.50 from miscellaneous sources. Total 1920 maintenance expenses were $958.62. $490.90 was invested in United States Liberty Bonds. The securities held by the Society amount to $13,500. The report of the Auditing Committee, consisting of W. R. Gregg, Oscar S. Adams and H. F. Stimsonf, was pre- sented by Mr. Gregg, and the reports of the Treasurer and Committee were accepted. The report of the Tellers, H. S. Roberts, Charles R. Duvall and S. J. Mauchly, was presented by Mr. Roberts. The Society proceeded with the election of officers, which resulted as follows: President, R. L. Faris; Vice- Presidents, E. C. Crittenden and Walter P. White; Recording Secretary, H- H. Kimball; Treasurer, John A. Fleming. May 4, 1921 proceedings: biological society 213 In view of his election as Vice-President, Mr. W. P. White tendered his resignation as Member-at-large of the General Committee. His resignation was accepted, and members-at-large of the General Committee were elected as follows: F. R. Silsbee and O. S. Adams for regular 2-year terms, and W. R. Gregg for one year, to fill the unexpired term of Mr. White. In accordance with action of the Society at its last annual meeting, the General Committee submitted, in the form of a printed memorandum, its recommendations for changes in the by-laws of the Society. Three of these were adopted, and one was referred back to the General Committee for further consideration. The principal change was in the methods of nominating and electing officers. S. J. Mauchly, Recording Secretary BIOLOGICAL SOCIETY 616th meeting The 616th meeting was held in the lecture hall of the Cosmos Club on November 27, 1920. Prof. A. S. Hitchcock called the meeting to order with 46 persons present. The following were elected to membership: R. A. CusHMAN, H. E. Ewing, R. M. Fouts, T. C. Greene, Carl Heinrich, W. M. Mann, H. Morrison, W. Schaus, L. H. Weld, G. E. Thompson, T. B. Wilson, C. R. Aschmeier, A. L. Bennett, N. H. Boss, W. L. Brown, T. Horn, J. B. Reeside, Jr., Miss G. O. Visel, P. C. Villannera, D. H. Adams, Miss L. Allison, G. L. Bowen, T. J. Brineer, C. T. Buckingham, Miss A. M. Charest, Miss E. E. Chickering, W. F. Coakley, G. W. Cres- WELL, F. B. Cunningham, W. G. Cusnard, W. Dean, J. Deuterman, Miss A. E. Drew, Miss M. E. Drew, E. S. Drummond, D. L. DuPre, E. M. Ellerson, p. S. Gault, W. H. Geisler, W. A. Gersdorf, E. J. Gr.\ss, Miss H. F. Hadden, Miss E. M. Hamric, Miss Dora Hansen, S. M. Harding, G. S. Hastings, W. H. Hughes, W. Johnson, J. L. McCarther, F. A. Mayer, Miss A. J. Mills, F. Moore, R. W. Murray, Miss E. Na- thanson, A. D. O'DoNNELL, MissH. R. Ostrom, L. A. Passalaequa, C. W. Parker, H. W. Potter, A. Preece, R. B. Rench, M. Riwchun, G. L. Roberts, A. S. Rubino, Miss M. Russell, G. P. Savage, H. L. Smith, Miss L. W. Steever, H. C. vStraup, Miss Lurana Van Doren, L. R. Wat- son, Jr., S. Weinshellbaum, Miss D. V. Nichols. Informal communications Dr. L. O. Howard referred to Humboldt's statement that mosquitoes occurred in enormous numbers on the Amazon, and Dr. Bradley's statement that they occiu-red only in spots, and asked Dr. Bradley for comments. Dr. J. C. Bradley in reply said that his experiences might have been in an off season; he was, nevertheless, struck by the comparative absence of mos- quitoes. On the Amazon no Anopheles, and no malaria; on certain tributaries some Anopheles, and some malaria; elsewhere only scattering mosquitoes, and no malaria; at other places no mosquitoes, yet malaria is reported. In general the distribution of mosquitoes seems to be quite local. Dr. H. M. Smith exhibited specimens of "unnatural historv^" from Peking, China — artificial lizards, scorpions, millipeds, etc., made from beads, seeds, and common materials. Dr. T. S. Palmer called attention to the special exhibit of bird drawings at the Library of Congress, some very ancient, some recent and the best of their kind. Dr. L. O. Howard also announced the special exhibition of insect drawings at the Corcoran Art Gallery. 214 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 Regular program J. Chester Bradley: Plumarius, an aberrant genus of Hynienoptera. In 1S73 Philippi described a male hymenopterous insect under the name Plumarius, referred tentatively to the family Evaniidae. From that time to the present the identity and relations of this insect have been a puzzle to zoologists. In 1909 Andre described the genus Konowiella, also from the male sex only, remarking that he was unable to assign it to any family. vSpecimens from Argentina in the hands of Professor BruES and the writer, evidently of Konowiella, brought out the probability that it is synonymous with Plumarius, that it is an arid region foim, and nocturnal. Entomologists in Argentina were not able to throw any light upon the time of year, habits, occurrence or identity of these insects, but in the arid foothills of the Eastern Andes near Mendoza the speaker obtained last March about 100 specimens, attracted to light, of five or six species, and later two specimens on the western side of the Andes in Peru. It is thus evident that the insects represent a numerous and not uncommon group in the Andean arid regions, and perhaps may be analogous in their economy to Brachycistis of our Southwestern deserts. Subsequently, at Santiago, the speaker found in the National Museum Philippi 's type of Plumarivis, and has been able to prove the identity of Konowiella with that insect. Ashmead and Szepligeti had placed Plumarius in different subfamilies of Braconidae, and the speaker, eleven years ago, had inclined to the belief that it represented a distinct ichneumonoid family. Andre believed his Konowiella allied with the Mutillidae, Thynnidae and Scoliidae. With the Evaniidae and Braconidae Plumarius has no affinities. It is an aculeate, possessing 1 -segmented trochanters, 13-segmented antennae (not more than 16-segmented, as stated by Philippi), and a distinct preaxillary incision in the hind wings, a character of many aculeates, but of no Ichneu- monoidea. The hind wings are also in venation quite of the aculeate type. Two accessory veins in the forewing appear at first sight without analogy in other wasps. A study of the forewing of Scaptodactyla and Photopsis, howe\cr, demonstrates the manner in which these veins have really arisen from the accessory spurs characteristic of many Mutillidae. In many respects the insects resemble male ants, but lack petioles. The body characters are neither strongly dissimilar, not do they entirely agree with the Mutillidae and their allies. The genitalia are of a type not dissimilar to Myrmosidae. Cerci are present. Andre was undoubtedly correct in suggesting the affinities of these insects with genera which we now place in the Myrmosidae. Yet the relation must not be considered too close. The only justifiable conclusion is to erect for these insects a new family which must take its place as related to Mutillidae and Myrmosidae. It is to be regretted that we do not know the female, but it is undoubtedly apterous. (x\uthor's abstract.) This paper was discussed by L. O. Howard and vS. A. Rohwer. W. E. Safford: Hawaii revisited. The Hawaiian Islands have been visited several times by Dr. Safford. In the paper presented by him he dwelt upon the changes which have taken place in the natural and social conditions between his first visit thirty-three May 4, 1921 proceedings: entomological society 215 years ago, when Kalakaua was King, and his last visit, when he was sent to the islands as delegate from the U. S. Department of Agriculture to the First Pan-Pacific Scientific Conference, held at Honolulu from August 2 to August 20, 1920. During the Conference Dr. Safford presented papers treating of the dis- semination of plants by ocean currents, the introduction of plants in prehis- toric times through human agency, and the role played by the vernacular names of economic plants as indices to the origin not only of the plants but of the people who introduced them. A number of lantern slides were shown illustrating the arts and customs and the physical appearance of the primitive inhabitants and showing the contrast of the Hawaiian Islands as first seen by the lecturer with the Territory of Hawaii of today, with its great sugar and pineapple industries, the rice-fields and water-lily ponds of the Chinese and Japanese, which have almost supplanted the taro-patches of the natives, and the magnificent modern city which has grown out of the early Honolulu, with its homely residences embowered in palms and ferns, and the grass- covered houses of the natives nestling in the valleys surrounded by taro- patches and clumps of 'awa plants from which their narcotic drink was pre- pared. Slides were also shown illustrating the former lava flows on the Island of Hawaii, and the crater of Kilauea, whose activity still continues. Dr. Safford paid a tribute to the generous hospitality received bv the mem- bers of the Conference and called attention to the admirable organization of the Hawaiian Sugar Planters' Association and to the impctant work ac- complished by the U. S. Department of Agriculture Experiment Station at Honolulu, under the management of Mr. J. M. Westgate. The part of this paper relating to the flora of the Islands and the role played by economic plants introduced in prehistoric times in the daily life of the primitive Hawaiians will be published elsewhere. (Author's abstract.) A. A. DooLiTTLE, Recording Secretary. ENTOMOLOGICAL SOCIETY 334th meeting The 334th meeting of the Entomological Society of Washington was held in Room 43 of the new building of the National Museum on November 4, 1920. President Walton presided and there were present 33 members and 9 visitors. Messrs. J. C. Bridwell, of the Bureau of Entomology', and L. L. Buchanan, of the Biological Survey, were elected to membership. Regular program L. O. Howard: A recent visit to certain European entomologists. This was a running account of Dr. Howard's recent visit to Europe, illus- trated by many lantern slides of the entomologists whom he met and of places of entomological interest. The personal characteristics, work, and special interests of the various entomologists were discussed. N. E. McIndoo: The auditory sense of the honey bee. Beekeepers are agreed that bees can hear, yet they cannot prove it, and critics still contend that it has never been experimentally proven that any insect can hear; nevertheless, within the last few years some good experimental results have been obtained. The special sound-producing apparatus of the honeybee consists of the membranes lying between the axillaries at the bases of the front wings. 216 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 Muscles, lying in the thorax and attached to these axillaries, contract and re- lax very quickly, thereby causing the axillaries to vibrate; consequently the above membranes are caused to vibrate rapidly, thus producing the piping, teeting, or squealing noise, commonly heard when a bee is squeezed. Up to date, five so-called auditory organs have been found. Judging from their anatomy, the pore plates, Forel flasks, pit pegs and Johnson's organ, all located in the antennae, do not seem to be well fitted to act as sound receptors; but the chordotonal organs, lying in the tibiae, seem to be better adapted for this purpose. The Johnson's organ consists of the peculiarly modified articular membrane between the second and third antennal seg- ments, and of many sense cells whose fibers unite with peculiar knobs extend- ing inwardly from the articular membrane. The chordotonal organs are quite complicated, resembling those in certain Orthoptera. The sound-producing apparatus and Johnson's organ in the honeybee, and also a minor detail in the histology of the pore plates, are here described for the first time. Notes and exhibition of specimens Mr. August Busck showed specimens of the Oscophorid Carsina quercana Fabricius which had recently been received by him for determination from Mr. E. H. BlackmorE, of Victoria, British Columbia. This is the first American record of this European genus and species and is an interesting addition to our list of Microlepidoptera. The species is a striking form both in structure and in color, with long thick light yellow antennae reaching be- yond the tips of the yellow and purple wing. The species is common and well known in Europe; the larva feeds under a slight web on the under side of oak, beech, apple and pear. The species has hitherto been recorded only from Central and South Europe and from Asia Minor and the occurrence in British Columbia is difficult of explanation. Mr. Busck had assured himself of the identity of this European and American specimen by careful slides of the male genitalia. During the discussion Mr. Busck mentioned two other Oscophorid species, Borkhausenia pseudospretella Stainton and Endrosis lacteella Schififemuller, both common to Europe and to the West Coast of North America — in fact, both nearly cosmopolitan, but not occurring in eastern United States. Both these species are scavengers on stored seeds and refuse and are more or less domestic in their habits. Dr. A. C. Baker stated that certain European plants are found in restricted localities in British Columbia and not elsewhere in North America. Mr. Wm. MiddlETon presented a note on Adult feeding and its effect on the longevity of Dibrachys (Pachyneuron) nigrocyaneum Norton. In the study of the life and seasonal history of Diprion simile, a recently introduced enemy of pine from Europe the advent of which species in America was noted by Mr. S. A. Rohwer in the June 1, 1916 meeting of the Society, a considerable number of a small chalcid parasite {Pachyneuron) Dibrachys nigrocyaneum Norton emerged from a quantity of cocoons in one of the general rearing cages. This parasite, which is an American species, was originally described from Connecticut where the cocoons from which it was this time reared were col- lected, and is recorded in The hymenoptera of Connecticut ^ as bred from cocoons of Diprion abietis and D. simile. The parasites were reared in the latter part of August, 1915, and D. simile was first discovered in this country at New Haven, Connecticut, in August, 1914. ' Connecticut Geol. Natural Hist. Survey, Bull. 22. May 4, 1921 proceedings: entomological society 217 Among the experiments performed with these parasites several were con- ducted to obtain information on the longevity of the adults, with the following results : Sixty-five adults were placed in vials without food, all the males dying within 3 days and the females within S days. Forty adults were place in a vial with a piece of cotton soaked in sugar water; all the males died within 3 days but all the females, except 1, were living on the 13th day and all were not dead until the 17th day. This experiment would seem to indicate that either the female alone took nourishment or at least they were the only ones to benefit by food with in- creased length of life. Mr. RoHWER reported for the Executive Committee that the committee had decided on the National Museum as the meeting place, at least tempo- rarily, and asked for an expression of opinion by the members. Several members expressed themselves as pleased with the arrangement. 335th meeting The 335th meeting of the Society was held December 2, 1920, in Room 43 of the new National Museum building. Vice-President Gahan presided and there were present 36 members and 3 visitors. The Corresponding Secretary reported that he had been advised that the collection of cavern coleoptera secured from Austrian entomologists in ex- change for food parcels had been sent. The collection contains 100 species representing many interesting genera not represented in the National Museum collection. The Secretary stated that these insects are to be accessioned as a gift to the National Museum through the Entomological Society. Dr. H. E. Ewing, of the Bureau of Entomology, and Mr. C. F. W. Muese- BECK, of Cornell University, were elected to membership. Election of Officers for igzi The officers for 1920 were re-elected. They are as follows: President, W. R. Walton; First Vice-President, A. B. "Gahan; Recording Secretary, R. A. Cushman; Editor, A. C. Baker; Corresponding Secretary-Treasurer, S. A. Rohwer; Executive Committee, the Honorary President, E. A. Schwarz, the officers, and A. L. Quaint ance, A. N. Caudell, and E. R. Sasscer; Vice-President to represent the Society in the Washington Academy of Sciences, S. A. Rohwer. Regular program E. R. Sasscer: Quarantine work on the Mexican border. Mr. Sasscer prefaced his paper with some remarks concerning the early history of the Pink Bollworm in the Laguna District of Mexico, and the place- ment of inspectors at the main avenues of entrance along the Mexican border to prevent the entry of this insect in cotton seed concealed in freight cars and other vehicles, and in passengers' baggage. It was pointed out that at the present time the Federal Horticultural Board has twenty-four inspectors located at various ports on the Mexican border, and that fumigation houses of sufficient size to fumigate freight cars are located at Browns\alle, Laredo, Eagle Pass, and El Paso. Two of these houses will accommodate from one to fifteen cars, one from one to six cars, and one from one to eight cars. At Del Rio, where there is at present no railroad connection between the United States and Mexico, a small house has been erected to fumigate wagons, automobiles, etc., requiring such treatment. He stated that steps were now 218 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 9 being taken to erect a fourteen-car fumigation house at Nogales, Arizona. 7,772 cars were fumigated as a condition of entry from October 1, 1919, to June 30, 1920. In addition to the fumigation houses, sterilization plants have been erected by private concerns at three of the principal ports of entry for the purpose of sterilizing, by the use of heat, com arriving from Mexico. The arrival of com fouled with cotton seed made it necessary to adopt this safeguard before permitting the entry of Mexican corn. Reference was made to the inspection work conducted at the foot-bridges of the various ports, and it was indicated that living larvae of the Pink Boll- worm had been intercepted on several occasions in cotton seed found in suit- cases and in pillows. Other injurious insects not known to occur in the United vStates have been repeatedly intercepted. During the first six months of this inspection work there were no less than 1018 interceptions of contraband material. Various phases of the work on the border were illustrated with lantern slides. Notes and exhibition of specimens Mr. R. C. Shannon recorded the collection by himself on Moscow Mt., Idaho, of specimens of the peculiar fly, Ambopogon hyperboreus Greene, originally described and hitherto known only from Alaska near the Arctic Circle. Dr. J. M. Aldrich discussed the use of caterpillars for food by the Pahute Indians of Mono Lake, California. The species used is found to be Color adia pandoria. The eggs are deposited on the bark of pine trees in the spring and hatch in midsummer. The larvae feed on pine needles until cold weather and hibernate in the clusters of needles as small larvae. They finish feeding the following summer, pupate, and emerge the next spring. The life cycle, therefore, requires two yeais. The larvae are collected in very large numbers by means of trenches, placed on hot earth for about an hour, and dried in the sun. They are used in the making of soup. Other insects used as human food were cited by various members: the pupae of the dipterous genus Ephydra, eggs of the hemipterous genus Corixa, etc. Other cases of two- year life-cycles in Lepidoptera were cited by Mr. Busck and Mr. Heinrich, the latter attributing it in many cases to climatic conditions. Mr. Rohwer spoke of the suspended development in a portion of the brood in certain saw- flies. He cited especially Neodiprion lecontei, which has two periods of emer- gence of adults from the same batch of eggs, one period in the spring and one in the fall from eggs the previous fall, and one in fall and one in spring from eggs laid the previous spring. Mr. Caudell stated that certain katydids and walking-sticks have two periods of hatching. Mr. Morrison cited the case of the Coccid genus Margarodes in which life-cycles of 15-17 years are known. 336th meeting The 336th meeting of the Society was held January 6, 1921, in Room 43 of the new building of the National Museum. President Walton was in the chair and there were present 32 members and 3 visitors. The Editor, Dr. A. C. Baker, reported that the contract for the printing of the Proceedings for 1921 had been awarded to the McQueen Co., of Washington. As chairman of the Auditing Committee, Mr. Caudell reported the accounts of the trea- surer correct. The Corresponding Secretary-Treasurer, Mr. S. A. Rohwer, presented his report for 1920, the tenth year of his tenure of office, including his report as May 4, 1921 proceedings: entomological society 219 custodian of literature. After hearing a report by Mr. Rohwer on the re- sults of the conference between the house committee of the Cosmos Club and representatives of the scientific societies, regarding the rental of the hall at the Club, the Society voted to continue to meet at the National Museum. As a delegate representing the Society at the dinner given by the American Association of Economic Entomologists at Chicago on December 20, 1920, President Walton reported a very profitable and enjoyable occasion, listing the representatives of the various entomological societies of the United States and Canada. Regular program W. R. Walton: Entomological drawings and draughtsmen; their relation to the development of economic entomology in the United States. This was a historical account of the artists who have added so much to the value of entomological publications since the beginning of entomology in America. Especial attention was given to those who illustrated the earlier works. This paper is to be published in the Proceedings. R. A. CuSHMAN, Recording Secretary. SCIENTIFIC NOTES AND NEWS The Division of Graphic Arts of the National Museum has installed an exhibit showing the materials and processes involved in the manufacture of hand-made paper. The exhibit was presented by Mr. Dard Hunter, of Chillicothe, Ohio, one of the few makers of hand-made paper in America. The Petrologists' Club met at the Geophysical Laboratory on April 19. Prof. W. J. Miller, of Smith College, Prof. R. A. Daly, of Harvard Uni- versity, and Drs. N. L. Bowen and P. Eskola of the Geophysical Lab- oratory, discussed The origin and structure of the Adirondack anorthosites. A Mathematics Club has been organized at the Bureau of Standards by members of the staff. Dr. F. D. Murnaghan addressed the Club on March 28 on Relativity and vector analysis; modern methods in vector analysis. The collections in the Division of Physical Anthropology of the National Museum have been enriched by an important accession. Dr. Edward A. Spitzka, formerly professor of anatomy at Jefferson Medical College, Phila- delphia, and for many years a student of brain morphology, has donated to the Museum his complete collection of brains of distinguished persons. Dr. E. Q. Adams, of the color laboratory of the Bureau of Chemistry, U. S. Department of Agriculture, has resigned to accept a position at the Nela Research Laboratory of the General Electric Company, Nela Park, Cleve- land, Ohio. Mr. Lincoln Ellsworth, of New York City, has forwarded to the National Museum a 193-kilogram iron meteorite from Owens Valley, California. Dr. Reid Hunt, formerly of the Hygienic Laboratory, now professor of pharmacology at the Harvard Medical School, has been appointed a member of the advisory board of the Hygienic Laboratory of the Public Health Service, to succeed the late W. T. Sedgwick. Mr. Ector B. Latham, hydrographic and geodetic engineer with the U. S. Coast and Geodetic Survey, died on April 7, 1921, at New Orleans, where he was in charge of the Survey's local station. Mr. Latham was bom in Mc- Minn County, Tennessee, June 9, 1864. He was appointed assistant at the Survey in 1895, and had been in the service since that date, engaged in tri- angulation and topographic, photo- topographic, hydrographic, and magnetic work. He took part in the Survey's work in the Philippine Islands, and was with the first expedition to the Mt. St. EHas region in Alaska. He was a member of the Society of Engineers. Mr. B. H. Rawl, assistant chief of the Bureau of Animal Industry, U. S. Department of Agriculture, has resigned, effective April 30, to take charge of the educational work of the California Central Creameries, with head- quarters in San Francisco. 220 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 May 19, 1921 No. 10 CHEMISTRY. — Note on the ice crystals which form on hare soils and on the stems of plants.'^ Victor Birckner, Bureau of Chemistry. (Communicated by Edgar T. Wherry.) The formation in frosty weather of ice crystals on certain soils and on the stems of certain plants early attracted the attention of scien- tists. The literature- on these very fascinating phenomena dates back about a century and contains many speculations as to the cause and the mode of formation of these structures. The explanations usually offered rest almost entirely upon physical grounds, it being assumed that the ice in question consists of pure frozen water. My own find- ings have shown that ice structures both from bare soil and from the stems of dittany {Cunila origan oides) contain organic material. A quantity of ice crystals from bare soil was taken to the laboratory in a small tin pail. The well-known ice structures from Cunila stems were also gathered, practically free from dirt, in a glass vessel and taken to the laboratory. Both kinds of ice, after melting and filter- ing, yielded a colorless opaque solution. After evaporation of 100 cc. of each solution in a platinum dish, the residue was weighed and then ignited. From 100 cc. of filtrate from soil ice, 0.0032 gram of residue was obtained, yielding 0.0016 gram of ash. The same quantity of Cunila ice gave 0.0032 gram of residue, but only 0.0006 gram ash. While, therefore, the two filtrates contained the same amounts of stable solids, the proportion of the ash was much greater, and the amount of organic matter correspondingly smaller, in the case of the soil ice than in the ice from dittany. This may well be due to the fact that the Cunila ice can be collected without difficulty in a state of very high purity. Some of the earlier observ^ers of the ice formation on Cunila have, it is true, suspected the presence of a foreign substance in these struc- tures. In their papers they state that they have tasted the ice, but, 1 Received February 10, 1921. ^ Among the most important references to this subject are the following: W. W. CoBLENTz, Jouru. Franklin Inst. 178: 589. 1914; Monthly Weather Review 42: 490. 1914; Scientific Monthly 2: 334. 1916. J. Sachs, Lehrb. Bot. (4th Ed.), 703. 1872. 221 222 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 finding it devoid of all flavor, they concluded that their suspicion had been unfounded. The low percentage figure of the organic matter present may explain the fact that it is imperceptible to the taste. However, if the ice is allowed to melt, the presence of the organic substance readily manifests itself to the eye through the pronounced turbidity of the solution. The organic substance is, therefore, probably of colloidal character. The question as to whether or not its presence in these ices bears any relation to the peculiar shapes of these structures is, of course, unanswerable at the present time. Our knowledge of the properties of colloidal organic substances is still too incomplete. An attempt was made to obtain an idea as to the chemical nature of the organic substance present in these ices. Upon concentrating the opaque solution on the steam-bath, a yellowish brown fluid was obtained which had a pleasant odor, similar to freshly baked bread. With ferric chloride solution, a yellow coloration was produced. Per- manganate solution, made slightly alkaline, was readily reduced with the formation of an aldehydic odor (not of benzaldehyde, however) . Bromine solution was decolorized. These tests would indicate an aromatic unsaturated compound. The latter was tentatively assumed to belong to the styrolene group, of which cinnamic and cumaric acids are members. This assumption was strengthened by the following biological observation. A solution of melted ice from bare soil, after thorough filtration, was kept in a cold storage compartment at a con- stant temperature of about 1° C. After two weeks, on examining the liquid microscopically, I found it to contain a bacterium in what appeared to be practically a pure culture. The liquid was turned over to Dr. Edwin Le Fevre of the Microbiological Laboratory, who made a careful study of the organism. In this connection. Dr. Wil- liam J. Robbins has isolated from soil a bacterium which is capable of utilizing cumarin as a source of carbon.^ Dr. Robbins was kind enough to send us a culture of the bacterium, and the two organisms were subjected to a comparative study by Dr. Le Fevre, who reported that the classification of both organisms should be the same. From these observations, it would appear that the present physical explanations for the above-mentioned frost phenomena are inadequate and that they cannot be fully explained until the nature and the physical properties of the organic substance present in these ice structures have been elucidated. 3 W. J. Robbins, Science, N. S. 44: 894. 1916. May 19, 1921 hopkins: problems in bioclimatics 223 BIOCLIMATICS. — Intercontinental problems in bioclimatics; with special reference to natural and artificial distribution of plants and animals} Andrew D. Hopkins, Bureau of Entomology. One of the most important subjects for the consideration of ento- mologists, botanists, general biologists and agriculturists in the past, and for the future, relates to the introduction of plants and animals from one part of the world to another. This subject is largely one of the relations between life and climate, with regard to the original home of a species, the environments under which it has developed, the range and limits of its natural distribution on one continent, the place of its artificial introduction to another, its establishment there, and its natural or artificial spread from the point of entry. This address is concerned with some of the principles of the bio- climatic law, methods of application and results as revealed by a study, just completed, of the relations between the advance of spring in eastern North America and western Europe as based on certain phenological events that characterize a particular phase of such ad- vance. This study was made in connection with, and as a prelim- inary to, a more comprehensive investigation of the relation of the law to the bioclimatic zones of the continents, as a key to solving some of the problems in artificial distribution of desirable plants and animals, in the belief that the true guide to success is to be found in zones of similar bioclimatic types. While the subject of the bioclimatic law and its application to re- search and practice has been discussed in papers before this Society, and in recent publications, it is apparent that some of the principles on which the law is founded, and some of the features in the system of application, are not generally understood. Consequently there are skeptics as to the sound basis and the scientific and practical value that we claim for it, which is an excuse for repeating our inter- pretations. The bioclimatic law is a law of life and climate as related to the geographical coordinates latitude, longitude and altitude. It includes, as one of its principles, an average, or constant, rate of variation with variations in geographical positions, as manifested by the advance of the seasons and coincident phenomena, and. by the geographical dis- tribution of living organisms and types of climate. 'Address of the retiring president of the Biological Society of Washington, presented at a joint meeting of the Academy and the Biological Society on April 2, 1921. (Received April 12, 1921.) 224 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 In accordance with this law the country-wide average rates of var- iation in time, temperature, and distance, as related to periodical phenomena, geographical distribution, range and Hmits of zones, etc., are represented by the unit constants of 4 days to each equivalent constant of 1 degree of latitude, 5 degrees of longitude (or 1 degree isophane), 400 feet of altitude and 1 degree F. of the thermal mean. These unit constants are equivalent, one to the other, and, there- fore, the terms of one unit may be converted into those of another as required in the computation and expression of results. The application of the law to the study of any problem relating to life or climate in which the elements and data are subject to expression in terms of quantity, as to time, temperature, and distance, falls within the category of a mathematical concept of variable nature and, therefore, in the solving of bioclimatic problems, involves the determination of certain evidence and facts by mathematical methods. Principles involved in the application of the law. — In this mathe- matical concept of the bioclimatic responses to the solar and other fundamental factors of control there are a number of basic principles, namely : 1. The principle of geographical unit constants which relates to rates of variation or gradients of time, temperature, and distance, with variations in geographical position. 2. The principle of the isophane and altitude in which the isophane is an expression of the combined unit constant of the latitude and longitude coordinates while the altitude unit constant is a measure of variation with elevation of a place above its sea-level isophane in terms of time, and equivalent units of feet, meters, thermal mean, etc. This principle is fundamental in the systems and methods of application of the law, because it serves to locate and designate a geographical position and to fix its unit value relative to another posi- tion designated as the base. 3. The principle of the sea-level constant. This represents a uniform element of the system of computation of tables of altitude, time or thermal constants in accordance with the unit constants of the law. Thus, the isophanes of a map or a table, unless otherwise designated, represent a sea-level base and all computations for altitude positions, unless otherwise mentioned, are to or from this base. 4. The principle of the base station and base data. This principle, in connection with that of the sea-level constant, serves as a central or basic element of a uniform system of computation and comparison May 19, 1921 hopkins: problems in biocumatics 225 of quantities. Thus, the geographical position of a continental or inter- continental base station serv^es as the central unit or key from which, or relative to which, continental and intercontinental tables of sea- level, time, thermal or altitude constant quantities are computed as a basis for making predictions for any given isophane or altitude position on any continent of the northern and southern hemispheres. It also serves as a basis for the establishment of any number of regional and local stations as equivalent bases for the computation of regional or local tables of constants. 5. The principle of the constant and variable. This relates to the study of variability with reference to a "constant" as the measure of the relative intensity of the factors of variation. In other words, the variation of the variable from its "constant" magnitude, is the measure, in terms of time, temperature, and distance, of the intensity of the controlling influence from whatever source. This principle is of fundamental importance because, like the de- clination of the magnetic needle from its normal position, which en- ables the surv^eyor to reach a desired point, the variations of a recorded quantity from its "constant" enable us to determine certain desired facts and evidence in comparative studies of the bioclimatic relations between geographical positions, countries or continents. 6. The principle of equivalents as related to equal unit values of certain elements of the law and of the system of application, such as the geographic unit constants, coincident dates in the events of dif- ferent species, variations from the constant in equivalent terms of time, temperature, and distance; local base stations equivalent to the intercontinental base in conforming to a standard regional or local variation constant. 7. The principle of the average or norm as related to variable quan- tities. 8. The principle or law of averages as related to the compensation of errors in reported dates of events, temperatures, general computa- tion of data, etc. (Examples were given of predictions from records at an intercon- tinental base station at Kanawha Farms, West Virginia, for places in western Europe. These predictions consisted of dates for the advance of a certain stage of spring to a large number of places in the British Isles and in Germany as characterized by the date of the flowering of the English hawthorn, Crataegus oxyacantha; also predic- tions of bioclimatic or life zones of stations and places represented by 226 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 recorded dates of the hawthorn event and recorded normal mean tem- peratures. It is shown that when the predicted dates are compared with the recorded dates at the same places the variation of the re- corded from the predicted gives a reliable guide to the relative dif- ference between eastern North America and western Europe as related to the advance of spring by latitude and by the equivalents of latitude and longitude in accordance with the bioclimatic law.)^ It has been found that, for the same latitudes and a 4-year average, spring advances 13 degrees farther north in western Europe than in eastern North America or on the average is 44 days earlier in western Europe than in the same latitude in eastern North America. In a general comparison of the results of the study as to the rela- tions between the predictions and the actual dates, etc., it is concluded that the significance of the results of this study, based on the pheno- logical facts and evidence represented by the hawthorn event and by the thermal mean, is in showing not only the relations between eastern North America and western Europe, as to the relative ad- vances of spring, but the general range of variations, of the recorded dates and thermal mean equivalents, from the dates, and from the thermal means, predicted from an intercontinental base. These re- sults indicate, as nothing else has heretofore, the amount of regional and local diflference in days to be expected for a spring event between a place in eastern North America and places in western Europe. Indeed, the greatest significance of these results is, that the predicted agree so closely with the actual recorded dates, at such a large num- ber of widely separated stations in western Europe, that we may assume that it is practicable to predict dates for certain seasonal events in any given year or average of years for any place on the eastern continent and to do this from a recorded date of the same or equivalent event at the intercontinental base station at Kanawha Farms, West Virginia, and in many cases as accurately as they are usually observed and recorded. The results relating to the prediction of bioclimatic zones repre- sented by the recorded dates and thermal means are of special sig- nificance in indicating the zonal relations between eastern North America and western Europe and in showing that the law may be applied to the preliminary prediction of zones of equal adaptation to certain species and varieties of plants and animals, farm and garden crops, as a guide to the successful introduction of desirable species "^ The address was illustrated with maps and tables which, together with a part of the paper, are omitted at the suggestion of the author. May 19, 1921 hopkins: biocumatic zones 227 and varieties and the prevention of the introduction of pests from one to another part of the world. These, together with the results relating to variations in equivalent days and to the variations of the recorded from a constant thermal mean, are new and represent new methods and principles. The preliminary prediction of minor bio- climatic zones represented by the meteorological stations of the Brit- ish Isles and Germany is perhaps one of the most important yet attained from the study and application of the bjoclimatic law. The close agreement between the zones and variations in days indicated by this method, as compared with those indicated by the phenological method for western Europe, together with the close agreement found between the predicted zones for North America and the Merriam life zones, are significant, not only in this agreement of results from two quite different methods and as related to two continents, but in opening a new field of research and practice of exceptional promise, in scientific and economic results, as related to a wide range of human interests. The general results of this study of an intercontinental problem in bioclimatics should leave little or no reasonable doubt as to the fact of, and prevailing responses represented by, the bioclimatic law. Neither should there be any doubt as to its practical application to almost any problem in any branch of natural science which involves a consideration of the responses of living organisms and climatic elements to continental, regional and local influences, or to problems that require a measure of the relative intensity of the factors of var- iations as related to periodical manifestations and geographical dis- tributions. BIOCLIMATICS. — Bioclimatic zones of the continents; with proposed designations and classification^ — Andrew D. Hopkins, Bureau of Entomology. The Major Zones are the Frigid, Temperate and Tropical, desig- nated as Majors I, II, and III. These majors are divided into Minor Frigid, Minor Temperate, and Minor Tropical, and are designated by Arabic numerals, as follows: I. Major Frigid Zone. — Arctic and Antarctic, and Alpine, with Minor Frigid 1, 2, 3 and 4 from the poles and from higher to lower altitudes. ' In connection with the author's address at the joint meeting of the Academy and Bi- ological Society (see the preceding article) these designations and classification of biocli- matic zones for the continents of the world were suggested. (Received April 12, 1921.) 228 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 II. Major Temperate Zone.— South and north of and below Major I with Minor Temperate 1, 2, 3, 4, 5, 6, and 7. South and north of and below Minor Frigid 4. III. Major Tropical Zone.— South and north of and below Major II, with Minor Tropical 1, 2, 3, and 4. South and north of and below Minor Temperate 7. This suggested system of designations and classification of the zones is put forward with the idea of replacing names based on geographical features or political divisions of one country, continent, or hemi- sphere with designations that would be applicable to any continental or insular area of both hemispheres. The Minor Temperate 1 to 7, Minor Frigid 4 and Minor Tropical 1, are wholly, or in part, equivalent to the Merriam life zones as related to North America. Thus: Minor Frigid 4 = Merriam's Boreal or Arctic- Alpine. Minor Temperate 1 = Hudsonian; 2 = Canadian; 3 = Transition; 4 = Upper Austral and Upper Sonoran in part ; 5 = Lower section of Upper Austral, Sonoran and Carolinean and upper section of Lower Austral, Lower Sonoran and Austroriparian, and represents a transi- tion between 4 and 6; 6 = Lower Austral and Sonoran in part; and 7 = Gulf strip as a transition between Minor Temperate 6 and Minor Tropical 1 which latter = Merriam's Tropical. The range and limits of the minor zones are characterized pri- marily by certain average ranges of temperature and, as related to world distribution, may be designated as terrestrial thermal zones. Each Minor Zone may embrace in its world-wide range many types of climate and life peculiar to certain regions, local areas and places. Therefore, while their numerical designations and relations are main- tained throughout, each minor is subject to division into many recog- nizable sections and subsections; each characterized by some peculiar regional or local conditions as to life, climate, weather, and physical adaptation of the land to various types and associations of life. In general the position occupied by a given place may represent the upper, middle, or lower section of a zone designated as follows: ( — ) lower, ( — .) lower middle, (.) middle, ( + •) upper middle, ( + ) upper; and ( h) the lower of one and upper section of another or the colimits of two zones, as ( — 3 -f 4) = lower 3, upper 4. The index or characterization elements of the minor zones and their subdivisions into sections are many and varied. Some of the prin- cipal ones are the thermal index; life type and ecological index; the May 19, 1921 pittier: bursera 229 isophane and altitude index; and the phenological index; each modi- fied by topographic, geologic, soil, and other features so as to define local subdivisions, even down to specific places only a few rods or feet in extent which may represent an element or feature of distinction. When we learn to recognize and properly interpret these various guides to the major and minor features of a bioclimatic zone, it will be an easy matter to determine not only what zone is represented by a given region and section of the country, but what section or minor element of a zone is represented by a given place on a given farm. Then we will realize all and far more than Dr. Merriam and others have claimed for the life zones as guides to the development of human welfare in food, health, and prosperity. BOTANY. — Two new species c/ Bursera.^ Henry Pittier. The two new species of Bursera here described have been found by the writer in the course of study of the Central American material of this genus in the United States National Herbarium. Bursera panamensis Pittier, sp. nov. Low tree or shrub; branchlets short, thick, glabrous, grayish; leaves pin- nate, small, the rachis pubescent, 1 to 4 cm. long, narrowly winged be- tween the two lower pairs of leaflets, more broadly so between the upper pair; leaflets 5 to 9, subcoriaceous, sessile or almost so, ovate to ovate-lanceolate, the lateral ones rounded, the terminal one acute at base and apex, serrate and slightly revolute on margin, sparsely hairy above, grayish tomentose beneath; flowers unknown; fruiting racemes pubescent, 2 to 3 cm. long, sparsely branched; drupes pedicelled, glabrous, subglobose, 6 mm. long, the pedicels 5 mm. long, bearing at the apex the persistent calyx. Type in the U. S. National Herbarium, no. 715171, collected near the salt works at Aguadulce, Province of Code, Panama, December 6, 1911, by H. Pittier (no. 4993). This species belongs to the group of Bursera tontentosa (Jacq.) Tr. & PI., with pedicellate flowers and membranous, serrate or crenate leaflets, these more or less hairy on both faces. It is called "almacigo de^cruz" by the natives of Aguadulce. The fluid oleo-resin which distils from the trunk and the decoction of the young leaves are popular medicines, the first being used .as a calmant and the latter as a diuretic. Bursera verapacencis Pittier, sp. nov. Small tree or shrub; branchlets short, at first densely hairy; leaves clus- tered at the ends of the branchlets, alternate, bipinnate at the base, pilosulous above, densely brownish-hairy beneath, up to 5 cm. long and 4 cm. broad, the rachis very slender and narrowly winged; pinnae and leaflets 17 to 23, the former 6 to 10, each with 7 to 11 pairs of leaflets, these sessile, ovate or *oblong, entire, rounded at the base, subacute at the apex, 2 to 8 mm. long, ' Received February 11, 1921. 230 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 1.0 to 4 mm. broad; racemes axillary, few-flowered, up to 3 cm. long; flowers unknown; drupes pedicellate, globose, about 5 mm. long, glabrous, the rachis of the racemes hairy, the pedicels 3 mm. long. Type in the U. S. National Herbarium, no. 858,992 collected between Salama and Rabinal, Baja Verapaz, Guatemala, May 31, 1904, by O. F. Cook and C. B. Doyle (no. 283). This species is closely allied to Bursera gracilis Engler, but differs in the greater number of pinnae and leaflets, in the hairiness of the latter, and in having the racemes much shorter than the leaves. ZOOLOGY. — The selection of family names in zoology.'^ W. L. McAteE, Biological Survey. (Communicated by S. F. Blake.) The principles upon which the names of families and higher groups in zoology shall be selected have not received much attention, chiefly, no doubt, for the reason that the problems of genera and species have been more pressing. Indeed before action can be taken by the Inter- national Zoological Commission (presumably to be reconstituted) it is highly desirable, if not necessary, that there shall be some crys- tallization of opinion on the point among zoologists. The leading Codes of Nomenclature have little to say upon the sub- ject, the most explicit rule being found in the Stricklandian Code of 1842.^ It states that families should be named for "the earliest- known or most typically characterized genus in them." The A. O. U. Code, 1886, says that such names "take the tenable names of some genus, preferably the leading one." The Paris-Moscow Code, 1889-92, states that family names are formed on "the root of the genus serving as the type," a remark paraphrased in the International Rules (1913) as "the stem of the name of its type genus." The A. O. U. provision is intentionally vague; those of the last two codes mean nothing unless they are intended to be understood in the sense of the Stricklandian canon. Since, with the exception of the words "earliest-known" in the latter rule, none of these codes specifies a method of selecting "typical" genera of families, nor states what the preference shall be among competitors for the rank, references in them to the selection of family names are practically meaningless. 1 This paper, prepared in its original form in 1918, was laid aside on the principle of "letting sleeping dogs lie," but recent contributions in Science showing the slumber to be ePfectually broken, a little more disturbance should do no harm. (Received March 2, 1921.) 2 To save time reference is made to iV. ^. Fauna, No. 23, pp. 722-3 (1904), where Dr.. T. S. Palmer has quoted, with references, the code clauses relating to family names. May 19, 1921 mcateE: nomenclature 231 Recently a set of rules has been proposed in Science,^ the most im- portant requirement of which is that "The type genus of a family or subfamily is the included generic group from the name of which the family or subfamily name was originally^ formed, and is to remain the type genus irrespective of changes in its name." In other words,, the name of the family changes with every change in that of the so-called type genus. Thus if a family or subfamily name had been based on the genus to which the rose-breasted grosbeak is assigned, in following all of the mutations of its type genus it would have been changed to conform with the 5 generic names listed hereunder, during the period that family names have been generally used in ornithological nomenclature: Guiraca, Hedymeles, Goniaphaea, Habia, Zamelodia; and in earlier periods the species has been referred to at least 5 addi- tional genera. The writer does not undertake to say whether or not this is an extreme case ; at any rate it illustrates how the system might work. The opposed method of selecting family names is basing each upon that of the oldest included genus. If for any reason the oldest name becomes unavailable the next oldest is used, and so on. It stands to reason that if the bases of family names are exclusively the oldest generic names, there will be fewer nomenclatorial casualties than if any later names are used. For the more recent the name the more likely it is to prove a homonym or synonym. In the absence of definite rules on the subject, how has the selec- tion of family names worked out in actual practice in zoology? Un- questionably the general practice has been to use family names based on the earliest available generic names. Whether they were delib- erately selected from this point of view may be questioned, but the evidence is strongly that way, for as will be pointed out in the sequel the chances of general agreement upon family names having priority in themselves are very remote. To illustrate usage in the selection of family names we may cite the "Index Generum Mammalium,"^ in which 159 of the accepted names are based on the oldest generic name (not preoccupied) or upon one of a group of names of the earliest year date, while 34 (chiefly of fossil groups) are not. Of the total 3 Science, N. S. 52: 142-147. Aug. 13, 1920. * Discussion later in this paper shows that it is by no means easy to decide where and when the family name was "originally formed." Priority in family names is not the com- paratively simple matter that it is in generic names. »T. S. Palmer, N. A. Fauna 23. 1904. 232 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 number of accepted family names 157 also have priority as such among family names cited in the work, which include only those originally published in approved classical form, but it is interesting to note that of 33 "oldest"'' family names not used, 22 are displaced by names based on the oldest genera. In 3 cases the "oldest" family name based on the oldest genus is not accepted. Of the family names of birds used in the A. O. U. check-list^ 63 are based on the oldest generic name, while 7, or possibly 8, are not. Without going into the matter statistically, the writer feels justified in stating that in entomology it has been a very general practice to found family names on those of the earliest available genera.^ The earliest genera certainly deserve consideration as bases for group concepts, if for no other reason than that they represent the first attempts to segregate groups in the families involved. Genera were established before families and the older among them, in many cases, had as broad scope as modern families. After decades upon decades of effort, priority in generic names is now pretty well worked out and family names founded in each case on the oldest available generic name will be little subject to change. Working on this basis, we have a system that comprehends both the original selection of the n'ame and its replacement if necessary. Under the type-genus system replacement of a family name is pro- vided for, as the name once selected follows that of the type genus in all its mutations. But what of the original selection? In brief, the proposal is that the earliest family name shall be selected. What does this mean? In view of the facts of nomenclatorial history and practice, it means that every supergeneric group name (based on that of a genus) proposed since 1758 must be taken into consideration. These names for the most part have never been catalogued, and dis- covering priority among them no doubt would take years of research. Does it not seem we are invited into a new nomenclatorial game in which for years and years when the question is asked, "Who has the oldest name for this family?" there will pop up here and there zealous bookworms each shouting "I have it," each "I have it" portending a change in family nomenclature? « Quoted because names cited in the work do not include vernacular and other names that are available for choice in selection of family names. 7 Check-list of North American birds. American Ornithologists' Union. Third ed. (revised), 430 pp. 1910. « The Entomological Code (Nathan Banks and A. N. Caudell, 1912, p. 22,) rules that the root-genus for a family name should be "preferably the oldest." May 19, 1921 mcateE: nomenclature 233 In the search for earliest family names the following difficulties, among others, will be encountered. Names based on those of genera are understood in each case.^ 1. Family nomenclature as such was not in general use until more than 50 years after the Systema A^a/«ra; therefore what are now con- sidered distinctive endings need not be looked for in the earlier names of supergeneric groups; names of whatever endings will have to be considered. 2. Rank of supergeneric groups was not always indicated and cer- tainly cannot be closely correlated as between diverse authors. Families and genera of various authors equal in scope modern orders and families. Names of every rank will have to be considered. Any name for a group agreeing chiefly in composition with one that now is, or shall in future be, considered of family rank is on the eligible list. Opinion will enter largely into the decision as to whether there is a sufficient degree of coincidence. 3. It is impracticable to choose between names set forth in the formal language of science and vernacular names. Van Duzee, who is quoted as a disciple of priority in family names and of the type- genus method, says: "It was my intention to follow Dr. Horvath's scheme in all its details but as the work advanced it was found neces- sary to abandon his plan to discard all names not strictly in latin form. His method would have thrown out a large number of groups founded by Amyot and Serville in their great work which is really the foundation of all our modern classification of the Hemiptera."^° Here it may be added that in numerous well-conceived systems the family and higher groups were given vernacular names only; indeed, in some cases only numbers were used. As between a family or subfamily name in classical form and prop- erly used, a scientific-appearing name casually used, a vernacular name appearing in an evidently good system, and a vernacular simply in text, who is to be the arbiter.-^ and who will accept his judgment? 4. It would appear that names of whatever form, whatever rank, whatever language, wherever proposed, in fact every supergeneric ' This restriction is necessary of course on account of the ex post facto rules in modern codes relating to the formation of family names. Many names not based on generic names have been used for supergeneric groups, which in other respects are as logical and worthy of consideration as those embodying generic stems. Such names are available for suborders and higher groups but for families, never. Our system of priority is indeed garnished with many an exception. '" Check-list of the Hemiptera . . . of America north of Mexico, pp. vi-vii. 1916. 234 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 name since 1758^^ must be taken into consideration in the selection of family and subfamily names on the basis of intrinsic priority. A great part of these have never been catalogued; who is to do it.^ and how long will it be until we shall be reasonably secure against the resurrection of names which may supersede a family name anywhere in the system? Under this plan would not the way be opened up for an indefinite number of changes in family and subfamily names? Will we not be much better off if we base our family and subfamily nomenclature upon a set of names, the priority in which is already almost completely worked out, than to adopt a rule compelling us to search out priority in another set of names hitherto largely neglected by bibliographers, and in which the problems to be met are more complex and confusing even than they are among genera? In other words, the present view is that due to inevitable difference of opinion as to whether only latinized names of subfamily and higher groups shall be considered, or whether vernaculars shall be included; as to what are classical forms and what vernacular; as to whether all supergeneric names, regardless of the rank given by their proposers, shall be considered; and as to whether the groups defined agree well enough in scope with modern concepts — differences of opinion, we would repeat, as to all these controversial points, would seem to block attainment of real priority in subfamily and family names. If sub- stantial justice cannot be done, and this would further appear certain because of the necessity of ignoring numerical systems and the probability that vernacular-named subfamily and family groups even if considered would not receive consistent treatment, why would it not be better to record attempts at higher classification, formal and informal, only in technical taxonomic discussions and not try to convey this history in connection with the names themselves? We can fix family names by an automatic process, that of basing them on the oldest included genera. Authorities for the names (sel- dom cited under present practice) would of course be unnecessary, but credit or responsibility for family and subfamily groupings could be separately recorded and include not only the more modern pro forma efforts, but also the earlier ones, however crude. With choice between an automatic method having nearly clear sail- ing ahead, and another beset by the complications as to priority here " Unless indeed some other date be selected for the beginning of family nomenclature; substantial agreement upon which probably could not be obtained. May 19, 1921 abstracts: geology 235 alluded to, there would seem to be no reason for hesitation, unless thorough-going application of the former method should involve an entirely disproportionate number of nomenclatorial changes. As evidence on that score it may be said that if 159 out of 193 fam- ily names in a standard work on mammals and 63 out of 71 in another on birds are now based on the oldest genera (and undoubtedly these are fair samples), the percentage of change required to bring all fam- ily names into agreement in this respect is by no means appalling. On the other hand, the search for priority among possible family designations has hardly begun and we know not through what no- menclatorial upheavals pursuit of that policy might lead us. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. GEOLOGY AND HYDROLOGY.— (7^o/og:^' and ground waters of the western pari of San Diego County, California. Arthur J. Ellis and Charles H. Lee. U. S. Geol. Survey Water-Supply Paper 446. Pp. 321, pis. 47, figs. IS. 1919. The report treats of the physiography, geology, and ground-water resources of that part of San Diego County, Calif., which is drained directly into the- Pacific Ocean, and includes a geologic map of this area. This region consists of a mountainous highland area, and a narrow belt along the shore character- ized by broad flat-topped sea terraces. The mountains of the highland area are believed to be due principally to erosion, but differential crustal move- ments have also been largely effective in mountain building. Comparatively flat tracts, or "highland basins," some of them surrounded by steep mountain walls, cover many square miles within the highland area. These tracts lie in three belts parallel to the trend of the main drainage divide, and may be remnants of a peneplain, many other remnants of which are preserved as flat-topped mountains. Several faults, presumably of consid- erable magnitude, have been identified, and numerous others are suggested by topographic evidence. The drainage pattern shows a tendency for the streams to follow parallel courses and to make rectangular changes of direction. The drainage basins are unsymmetrical. There are places in all the principal valleys where the bed-rock floor is deeply buried beneath detritus, and several of the principal streams, after crossing deep valley fill, flow through narrow rock-bottomed gorges. 236 JOURNAL. OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO 10 Repeated submergence and emergence has been the dominant factor in the development of the physiographic features of the coastal belt. These fea- tures comprise several extensive and numerous small sea terraces, ranging in elevation from 2() to 1200 feet above sea level, and dissected by streams to depths as much as 200 feet below the present sea level. The major valleys in the coastal belt have wide, flat, gently sloping floors, bordered by very steep slopes or bluffs several hundred feet high. They contain deposits of valley fill as much as 200 feet in depth. The geologic formations exposed in the highland comprise igneous and metamorphic rocks most of which are considered to be post-Carboniferous and not younger than early Cretaceous. Thick deposits of Quaternary alluvium occupy parts of the principal river valleys. In the coastal belt, sedimentary formations ranging in age from Cretaceous to Recent are ex- posed. Undifferentiated Miocene and Pliocene deposits, parts of which have been referred to in earlier literature as the vSan Diego beds, are designated as the San Diego formation. The portion of this report prepared by Charles H. Lee treats of the ground- water hydrology of the shallow water-bearing formations of the Pacific vSlope of the county, and the utilization of ground water from these formations Complete precipitation records at 106 stations and a detailed map are pre- sented. Conclusions are drawn regarding the amount of rainfall in any season necessary to produce run-off and also the relation of rainfall to run-off. Evaporation observations are given and comparison made between evapo- ration from a pan floating on a large reservoir surface, and the reservoir surface itself, which indicate that there is little difference between the two . Data r egarding soil evaporation and transpiration from mixed natural vegetation are also given. Detailed physical descriptions are given of the largest ten underground reservoirs of the region lying in the principal river valleys, with detailed geological and other data. The conclusion is drawn that ground water in the San Diego County river valleys has very Uttle movement and seldom occurs as underground streams, but occupies underground reservoirs. Sim- ilar data are also presented for other underground reservoirs of the region. Tests of existing pumping plants of various types are presented, which, for working conditions on the farm, show pump and pumping-plant efficiency and cost of pumping for inigation. The selection and installation of pumping machinery are also discussed. A. J. E. and C. H. L. GEOLOGY. — The origin of the faults, anticlines, and buried "Granite Ridge" of the northern part of Mid-Continent oil and gas field. A. E. Fath. U. S. Geol. Survey Prof. Paper 128-C. Pp. 10 (75-84), pis. 3, figs. 3. 1920. The paper is an attempt to find a common cause for the more or less parallel or continuous alinement in a general N.-NE. direction of the buried "granite ridge" of Kansas, certain larger folds, and a line of en echelon faults in Okla- homa and Kansas. Beginning with the discussion of the belts of faults the author assumes that the Pennsylvania strata would be incompetent to trans- mit the stresses which produced the faults but that the deeper-lying rocks from the Mississippian limestones down into the pre-Cambrian would be. He shows that horizontal movement along deep -lying faults coinciding in position and direction with the belts of en echelon surface faults could produce them. He also shows that folds and lines of folds might result from vertical move- May 19, 1921 abstracts: geology 237 ment along such deep faults, but admits that the folds in the region considered have characters which could not be accounted for in this way. The "granite ridge" which is overlain directly by Pennsylvanian rocks must have originated in late Mississippian or early Pennsylvanian time, perhaps by movement along one of these deep-lying faults. Successive movements along these lines at distinct periods have resulted in different effects at different depths. The origin of the assumed deep-lying faults is ascribed to pre-Cambrian moun- tain-building movements, as all subsequent movements in this Mid-Continent region are considered inadequate to have produced them. M. I. Goldman. GEOLOGY. — The Lance Creek oil and gas field, Niobrara County, Wyoming. E. T. Hancock. U. S. Geol. Survey Bull. 716-E. Pp. 32 (91-122), pis. 4. 1920. The Lance Creek field lies in east-central Wyoming, west of the Hartville uplift which connects the Rocky Mountains and the Black Hills. It is probably separated from that uplift by a broad syncline. Cretaceous and Tertiary formations from about 1660 feet below the top of the Cretaceous Pierre shale up to the Tertiary White River formation and Quaternary'' al- luvium are exposed. The sinuous anticline from which oil and gas are being obtained, as represented on a map by 100-foot contours, has a dominant east- west trend but turns north at its east end and south at its west end. The total length of the a:xis is probably about 20 miles, the closure of the anticline about 1,000 feet. The north and west flank is steep with dips up to 27° but on the south flank the dips run from 2^/2° to 5°. Production is being obtained from what the author considers the Newcastle sandsto-ne about 200 feet above the Dakota sandstone, around 3,500 to 4,000 feet below the surface. The yield of the principal wells ranges from 250 to 2,500 barrels of oil and from 8 million to 30 million cubic feet of gas per day. The author suggests testing deeper beds at least to include the Jurassic Sun- dance formation which he estimates could be reached, by a well located on the top of the anticline, at a depth of about 4,200 feet. He also draws attention to the possibility of production from the Wall Creek sandstone which lies about 1,050 feet above the Newcastle sand. M. I. Goldman. ENTOMOLOGY. — The colonizing reproductive adults of termites. T. E. Snyder. Proc. Ent. Soc. Wash. 22: 110-150. 1920. This paper, which was presented to the Faculty of the Graduate School of George Washington University as part of the requirements for the degree of Doctor of Philosophy, summarizes the literature and the author's extensive field notes of the colonizing habits of the reproductive adults of white ants. The three types of reproductive forms are discussed in detail, the nymphs characterized, and methods of colonization described. The results of the breeding experiments and attempts at cross-breeding are set forth. A sum- mary of the paper and conclusions drawn is given and the article concluded by a list of the literature cited. S. A. Rohwer. ENTOMOLOGY. The subfamilies of Formicidae, and other taxonomic notes. WiLLLVM Morton Wheeler. Psyche 27: 47-55. Figs. 3. 1920. This short paper gives a phylogenetic tree of the various subfamilies of ants. It also includes descriptions of new genera and subgenera and some remarks on the digestive system. S. A. Rohwer. 238 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 843d MEETING The 843d meeting of the Philosophical Society of Washington was held in the Cosmos Club, December 18, 1920, with President Faris in the chair, and 52 persons present. The first paper was by R. W. G. WyckoFF, on The determination of the structure of crystals, and was illustrated with lantern slides. An outline of the development of the methods thus far used serves to show the point of view from which the studies of the arrangement of the atoms in crystals have been carried out. The essential steps in this development are the experiments of Laue and of the Braggs, the determination of the ar- rangement of the atoms in some one crystal and the consequent measurement of the absolute wave lengths of X-rays. In nearly all of the structures which have been studied a procedure based upon the point of view of these experiments has been followed. This procedure consists in getting a lim- ited amount of experimental data with the aid of one of the three existing methods of obtaining diffraction effects — ^the Laue method, the spectro- meter method or its modification, and the method of powders. Bearing these experimental facts in mind, the analyst has tried to imagine some arrangement of atoms which will explain them. If he has succeeded in devising such a grouping, it is considered to be the structure of the crystal. This method of procedure is both cumbersome and haphazard and there is no means of knowing whether many other ways of arranging the atoms of the crystal under examination do not exist, all equally capable of explaining the data. This method is to be contrasted with the general method for studying the structure of crystals which can be built around the theory of space groups. The results of this geometrical theory can be given an analytical representation which states in terms of suitable coordinates all of the posi- tions in space that atoms in crystals can occupy. With its aid, and knowing the crystallographic symmetry, it is thus possible to write down in the case of any particular crystal, independently of any X-ray experimentation, all of the ways in which the atoms can be arranged. Suitable calculation will give the kind of dift'raction effects to be anticipated from each of these pos- sible arrangements of atoms. The experimenter may then obtain, by which- ever of the various methods will yield the desired information most readily, those data which the calculations show to be necessary to distinguish be- tween the possible atomic groupings. The second paper, by I. G. Priest and Mabel K. FrEhafer, on The optical basis of Bitiinger's camouflage paintings, was presented by Mr. Priest, and was illustrated with slides and with examples and copies of the paintings. Viewed in daylight, or any illumination approximating to this, these paint- ings appear no different from other paintings of the same kind ; but if viewed through a red glass, or in red light, the aspect of the picture is changed materially. A picture of the sea, with a wave breaking, shows under the red illumination, a mermaid rising from the wave. A summer scene in which May 19, 1921 proceedings : philosophical society 239 are depicted a tree and a house, beside a dam, is transformed by the change in illumination into a winter scene, with ice and snow. In another, the smoke screen from a battleship shows concealed a large American flag, and the inscription, "Victory." The picture of an airplane bearing a cross, the German insignia, shows up the concealed circle, insignia of the Allies. The portrait of a lady is completely transformed by the red light, into a land- scape, with a horse and man in the foreground. The explanation of these effects lies in the two kinds of paints that Mr. Bittinger uses. Any pair of these pigments is very well color-matched in daylight, that is, there are two dark greens, two light greens, two lavenders, etc. But one pigment of each pair reflects a considerable amount of red light, so that in red light one is a highlight and the other a shadow. In any painting the two color-matched pigments are applied, side by side; but that of high reflecting power in the red is so manipulated that a complete picture in this kind of paint is produced which is visible as such only when the ordinary pigments are darkened by the use of the red light. Experimental demonstrations of the above phenomena were made. The spectral reflection curves of the several paints as determined at the Bureau of Standards were shown by lantern slides. These curves have been pub- lished in the Journal of the Optical Society of America, September, 1920, p. 391. The third paper, by I. G. Priest, on A relation between color and spectral distribution of light, was also illustrated with slides. In a study of colors of the same quality evoked by stimuli of different spectral distributions the following rule has been found to hold : If any two lights, however different in spectral distributions, evoke colors of the same quality the wave lengths of the centers of gravity of their spectral distribu- tions are coincident. This paper has been published in the Journal of the Optical Society of America, September, 1920. The last two papers were discussed by Messrs. SilsbeE, Tuckerman, White, Lloyd, Ferner, and Sosman. 844th meeting The 844th meeting was held in the Cosmos Club, January 15, 1921, with President Paris in the chair, and 58 persons present. The address of the evening was by the retiring President, Robert B. Sosman, on The distribution of scientific information. The paper was discussed by Messrs. Pawling, C. A. Briggs, FernER, White, Brooks, Crittenden, Humphreys, Wright, Williamson, Bur- gess, Watson Davis, and others. It has been published in full in the Journal of the Washington Academy of Sciences.'^ 845th meeting The S45th meeting of^the Society was held in the Cosmos Club, January 29, 1921, with President Paris in the chair, and 47 persons present. The following program was given : G. Breit: The distributed capacity of inductance coils. The distributed capacity of inductance coils affects their behavior in elec- trical circuits. It changes the effective resistance and inductance of induc- tance coils. It is important for the radio engineer to be able to predict from the construction of the coil the influence of its distributed capacity. The » This Journal 11: 69-99. February 19, 1921. 240 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 paper dealt with the principles underlying the calculation of the effects of the distributed capacity and with the experimental verification of the cal- culation of these effects. One of the effects due to the distributed capacity is the change in the apparent inductance of the coil. This change may be shown to be due to the fact that the current distribution in the coil is not uniform. On this basis a calculation of the apparent inductance was made and hence the "effective capacity" of a coil was derived. Similarlv the resistance of a coil was discussed. On account of the non- uniform current, distribution based on the definition of resistance used for the case of uniform current-distribution becomes inapplicable. The resis- tance of the coil is redefined in such a way that it can be determined experi- mentally and used to calculate the current in the coil when the coil is placed in a known electric field. The experimental verification of the conclusions derived was discussed. A considerable portion of the distributed capacity of a coil is due to the capacity of the coil to ground. This capacity manifests itself when two condensers are used in series with each other and with the coil. The assump- tions underlying a theory of these phenomena were discussed and the theory was shown to be verified experimentally. J. H. Bellinger and L. R. Whittemore: Radio signal fading phenom- ena (presented by Mr. Bellinger, and illustrated). When radio first began to be used for long distance communication it was noticed that signals were not transmitted as far during the day as during the night-time. It has also been observed that night signals using the shorter radio waves vary greatly in intensity from minute to minute. More recently, since radio direction finders have come into use, it has been learned that great variations may occur in the direction of radio waves as they arrive at the receiving station during the transmission of signals from a given transmitting station. These and related phenomena have been recorded from time to time in the literature, and various hypotheses have been brought forward in expla- nation. The phenomena are dependent upon a large number of variable quantities, such as the weather conditions, the nature of the country over which transmission occurs, the surroundings of the transmitting and receiv- ing stations, and the method of handling the receiving apparatus. Only by a statistical study in which the results obtained simultaneously at a large number of receiving stations are collected and tabulated may reliable averages be obtained. Such a cooperative study is being carried on by the American Radio League and the Bureau of Standards, tests being conducted in June and October, 1920, and January and April, 1921. In these tests from five to ten radio stations transmit signals in succession. These signals are received simul- taneously at about one hundred receiving stations whose operators are pro- vided with forms for recording the variation in the intensity of the signals as received. The paper described the results of the tests so far conducted and proposed an explanation of the phenomena. This explanation associates the long- distance radio transmission accomplished at night wnth the boundary of the highly conducting outer portion of the atmosphere, which is also the origin of auroral disturbances. Fluctuations in intensity are probably caused by irregular absorption of the waves by masses of slightly ionized air through May 19, 1921 proceedings: biological society . 241 which the waves travel in their course. The "fading" phenomena are closelv associated with the strays or atmospheric disturbances which affect all radio communications. This paper will be published in the Journal of the Wasliingtoii Academy of Sciences. F. B. Littell: The variation of latitude and the constant of aberration from four years' work with the photographic zenith tube at Washington. A brief account was given of the principles of the photographic zenith tube devised by Dr. F. E. Ross. The average probable error of a single latitude for the four years 1916-20 was ±0.089 second. A curve was shown giving the path of the North Pole as deduced from a combination of the results of the Washington observations with the results of observations made at Greenwich with the Cookson photographic floating zenith telescope. A value for the constant of aberration of 20.454 =t O.OOS second was deduced from the observations, and curves showing the Kumiro or 2;-term for the years 1916 and 1917 were shown. An analysis of the meteorological conditions showed that the s-term could not be accounted for by the baro- metric gradients. This paper will appear in full in the Astronomical Journal. Dr. R. S. Woodward characterized the subject as most important; and regretted that there was not time for its full discussion. H. H. Kimball, Recording Secretary. BIOLOGICAL SOCIETY 617th meeting The 617th regular (41st annual) meeting of the Biological vSociety of Washington was held in the lecture hall of the Cosmos Club on December 11, 1920, with President A. D. Hopkins in the chair and 2S persons present. It was announced that on May 15, 1920, the resignations of N. Dear- born as Treasurer and A. Wetmore as Corresponding Secretary were re- ceived, and that F. C. Lincoln became the new Treasurer and T. E. Snyder the new Corresponding Secretary. Reports of officers and committees were received, and officers and mem- bers of the council were elected, as follows: President, N. Hollister; Vice-Presidents, A. S. Hitchcock, J. W. Gid- LEY, S. A. RoHW^ER, H. C. Oberholser; Recording Secretary, A. A. Doo- LiTTLE; Corresponding Secretary, T. E. Snyder; Treasurer, F. C. Lincoln; Members of the Council, Wm. Palmer, E. A. Goldman, H. H. T. Jackson, R. E. Coker, R. W. Williams. 61STH meeting The 61Sth meeting of the Society was held in the lecture room of the Cosmos Club at 8.10 p.m. on January 8, 1921. President N. Hollister called the meeting to order with 62 persons present. On recommendation of the Council, Mr. E. G. Runyan was elected to membership. The President announced the following committees: Committee on Pub- lications, C. W. Richmond (Chairman), J. H. Riley, T. E. Snyder, F. C. Lincoln. Committee on Communications, S. A. Rohwer (Chairman), C. E. ChAMBLISS, J. S. GUTSELL. Informal communications J. M. Aldrich exhibited dried specimens of caterpillars of Coloradia pan- dora Blake, which are used as food by Indians in the vicinity of Mono Lake, California. The species has a two-year cycle. Feeding on the Jeffrey pine 242 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 as larvae, they descend at the end of the second summer to pupate. They are then caught, and thrown into a pile of hot earth. After partial cooking they are dried in the shade, and thereafter will keep indefinitely. The specimens shown were eleven years old. There is but one brood, and cater- pillars can be taken only in alternate years. Mr. David Fairchild spoke upon the edibility of certain borers with which he had experimented. Prof. A. S. Hitchcock reported progress toward agreement among the various botanical codes. The desire is to unite the American and Vienna Codes and to agree upon the principle of types. Regular program L. O. Howard: Some views of the fight in southern France last summer against the Moroccan locust. (Illustrated.) This locust lives all around the Mediterranean coast, and at times is threat- ening to vegetation; it was especially so in 1920 in southern France in the sheep pastures. The government detailed soldiers to assist farmers in the campaign against the locusts, the farmer furnishing lodging, food, and all materials. In early morning when the locusts were comparatively sluggish, they were driven to the center of the fields where a flame was played over the mass of insects. A poisoned mash could not be used on account of the scarcity and expense of materials. Views were shown of the farm quarters, the fields and locusts, and the methods of fighting the insects. Dr. Howard also availed himself of the opportunity to visit the home of Henri FabrE, at Avignon. The home is kept by one of his daughters exactly as left by Fabre at his death, five years ago. Fabre was very active to the time of his death, and in his garden there remain many plants which he brought from the Alps. Views of the house, garden, and the medal which was struck in commemoration of the esteem in which Fabre is held by the French were shown. S. F. Blake: Sexual differences in coloration of the spotted turtle. This paper will appear in full in the Proceedings of the U. S. National Museum. It was discussed by Drs. Shufeldt and Howard. A. A. DooLiTTLE. Recording Secretary BOTANICAL SOCIETY 149th meeting The 149th regular meeting of the Botanical Society of Washington was held in the Assembly Hall of the Cosmos Club at 8 p.m., February 1, 1921, with lis members and guests present, and President Chambliss in the chair. Among the guests were: Prof. H. W. Anderson, of the University of Illinois, Prof. F. D. Fromme, of Virginia Polytechnic Institute, Prof. J. F. Collins, of Providence, R. I., Dr. Rudolph Kuraz, Secretary, Czecho- slovak Legation, Dr. Dobroslav Todorovic, Agricultural attache from Serbia, and Mr. Soren Sorenson, Agricultural attache of Denmark. Mr. Joseph W. Wellington was elected to membership. Brief Notes and Reports of Literature Dr. C. L. Shear called attention to an article in Science concerning the formation of a committee of 14 by the British to aid men of science in Russia, the main idea being to provide literature for Russian scientists. The meet- ing instructed the Executive Committee to give attention to the matter of providing scientific literature to Russian scientists, and instructed the So- May 19, 1921 proceedings: botanical society 243 ciety's representative, Dr. Hitchcock, to bring this to the attention of the Washington Academy of Sciences. Mr. Pierce called attention to the series of articles by Dr. John Harsh- BERGER, which began to appear in the October, 1920, number of the Garden Magazine on Old gardens oj Pennsylvania. These articles dealing with the early botanists of Pennsylvania and their collections should be of interest to all students of botanical history. Mr. Lewton called attention to the new edition of Dr. MarcellE Hardy's Geography of plants, a copy of which was passed around for inspection. Regtdar program H. L. Shantz: Natural vegetation of Africa. (Illustrated with lantern slides.) The vegetation of Africa ranges from the absolute desert of the southwest coast and portions of the Sahara, through desert shrub, desert grass, desert grass and acacia, and acacia tall grass to the great tropical savannas and in the Congo basin to the tropical rain forests, as higher elevations, moun- tain grass land and mountain forests appear. The distribution of these more important types was outlined and the agricultural potentiality of the land occupied by each type discussed and compared with somewhat similar types in the United States. Much of Africa is high, cool and dry, and is occupied by desert or semi-desert types, and only a relatively small portion by tropical jungles. The more important agricultural crops are corn, cassava, grain sorghums, bananas, beans and rice. Ivar Tidestrom : Notes on the flora of the Iberian Peninstda. (Illustrated with lantern slides.) The flora of the Iberian Peninsula is richer in species than any other of the European floras. The reason for this great wealth of species is the geo- graphical position of Spain, the high elevation of the land surface above the sea-level, the various mountain ranges, and the proximity to Africa. The littoral from Lisbon to Valencia, including the valley of the Guadal- quivir, is semi-tropical, and appears to be analogous to the Pacific Coast region from San Francisco southward to Arizona, including the valleys between the Coast Range and Sierra Nevada. The Castilian and North African plateaus have a great number of plants in common, which fact tends to prove that there was a land bridge between the two continents at some remote time — a fact already noted by paleontologists. The meteorological conditions of these plateaus show resemblances to those of the southwestern United States where the minimum temperature does not fall below — 17° C. The general aspect of the plateaus and moun- tains is that of our western country, and the types of plants are similar. The upper belts of the mountains in Spain have a northern flora typical of the aspen, spruce, and alpine belts of the Rocky Mountains and Sierra Nevada. The cultivated plants of Spain thrive equally well in our southwestern states. Of the trees in cultivation, the Lombardy poplar is the most inter- esting. Community planting of this tree has been attempted in northern Spain, where plantations now exist for the purpose of supplying timber and pulp. R. G. Pierce, Recording Secretary. 244 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 10 SCIENTIFIC NOTES AND NEWS Messrs. William Bowie and H. G. Avers went to Ottawa, Canada, in March, to consult with the superintendent of the Geodetic Survey of Canada in regard to the coordination of precise-level nets of the two countries. It is proposed that the two nets be adjusted together in order that the eleva- tions on the boundary may agree in the maps and reports published in the two countries. Prof. F. W. Clarke of the U. S. Geological Survey, and Dr. H. S. Wash- ington of the Geophysical Laboratory of the Carnegie Institution of Wash- ington, have been elected Fellows of the Geological Society of London. Messrs. HippolyTE Copaux, of the School of Industrial Physics and Chemistry of Paris; PiERRE Lelaudoux, of the Tunisian Phosphate Com- pany; EuGENio DoNEGANi, of the Sicilian Sulphur Company; and Georges Flusin, of Grenoble, visited the scientific institutions of Washington in April. They are in the United States to make a study of the fertilizer situation. Mr. William Valley Hagar, junior hydrographic and geodetic engineer in the Coast and Geodetic Survey, died at Tarrytown, New York, March 24, 1921. Mr. Hagar was born March 25. 1888, at Weybridge, Vermont. In 1912 he was appointed an assistant engineer in the United States and Canadian Boundary Service and was transferred to the Survey in 1913. The will of the late Miss Caroline Henry, daughter of Professor Joseph Henry, first Secretary of the Smithsonian Institution, gives $1,000 to the Institution and names it as residuary legatee of an estate with provision for several beneficiaries during their lifetime. Dr. A. S. Hitchcock of the Smithsonian Institution left Washington in April for a trip to the Philippine Islands, Japan, China, Indo-China, Singapore, and Java, for the purpose of studying the bamboos. He expects to be absent about eight months. Mr. Douglas Karr, junior hydrographic and geodetic engineer in the Coast and Geodetic Survey, died at his home in Passaic, New Jersey, March 20, 1921. Mr. Karr was born in New York City March 1, 1891, and was appointed an aid in the Survey in 1913. He was retired on account of phys- ical disabiUty only a short time before his death. Mr. A. H. Miller, of the Dominion Astronomical Observatory of Canada, is at the U. S. Coast and Geodetic Survey engaged in a determination of the Washington periods of a set of pendulums for the purpose of determining the difference in the constant of gravity between Ottawa and Washington. This determination is to supplement and strengthen a determination of the difference in gravity between the two stations made just before the War. Mr. William Palmer, taxidermist in the National Museum, died on April 8, 1921. He had been connected with the Museum since its earliest days. The numerous specimens, both casts and mounted animals, in the exhibition series testify to his skill. The exhibit of the vertebrates of the District of Columbia in the National Museum is almost entirely his work. Dr. H. S. Washington of the Geophysical Laboratory, Carnegie Institu- tion of Washington, has been elected a foreign honorary member of Viden- skabs Selskabet i Kristiania (the Norwegian Academy of Sciences) in the section of geology, mineralogy, and physical geography. The other American members are W. M. Davis and J. F. Kemp. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 * JUNE 4, 1921 No. 11 ' RADIOTELEGRAPHY.— i?aJ/o sigfial fading phenomena.' J. H. Bellinger and L. E. Whittemore, Bureau of Standards. INTRODUCTION In actual communication by radio, many difficulties are encoun- tered that would not be expected by one who is familiar only with the rather precise and clear-cut theory of the subject in books. Some of the phenomena in radio-frequency circuits may be represented accurately by ordinar}^ alternating -current theory, the m-athemxatical treatment being even simplified at radio frequencies. However, the phenomena of transmission of radio waves from one place on the earth's surface to another are of quite a different kind, and involve so many variables that they are very difficult of analysis. The difficulties which are peculiar to the transmission and reception of the waves in actual radio communication may be divided into: (1) "fading" or "swinging" of the received wave intensity; (2) strays; and (3) interference from other radio stations whose signals it is not desired to receive. "Fading" is the rapid variation of intensity of the signals received from a given transmitting station, all circuit arrangements at the transmitting and receiving stations remaining constant. It is char- acteristically a night phenomenon. "Strays" are electrical disturbances giving rise to irregular inter- fering noises heard in the telephone receivers of a receiving circuit. They are present in some degree at all times, though they are usually worse at night and in the summer time. Interference from other stations differs from the other phenomena in that it can be eliminated. The means by which this may be done ' Presented before the Philosophical Society of Washington, January 29, 1921. Pub- lished by permission of the Director, Bureau of Standards. Received May 5, 1921. 245 246 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 are: (a) frequency selection, {b) selection of wave direction, and (c) guiding the waves along a channel; for example, along a wire. It is interesting to note that the first and last of these means for elim- inating interference are also used in sound, while the second, the selection of the direction, cannot be used in sound, since sound waves are longitudinal while the electric waves are transverse. The matter of station interference will not be discussed further in this paper. In regard to fading and to strays, a considerable literature now exists, much of it being contradictory. The present authors have attempted to coordinate some of the outstanding and fairly well established facts, and to present recent results. Because of the complexity and uncertainty of many of the phenomena, exceptions can be found to almost all generalizations. Complexity of the problem. — The following four functions are characteristic of radio reception: Intensity of received signals. Fading of signals Direction of signals. Strays In order to determine the facts regarding these functions, from the analysis of which the causes might be determined, research has to be undertaken to determine their behavior with respect to the following variables: Frequency of wave, Kind of wave (as continuous or damped). Distance, Place (e. g., sea, sea-shore, plain land, mountainous land, rivers). Time (e. g., day, night, sunrise, sunset, time of year), Occurrence of eclipse, State of solar activity. Atmospheric electricity, Terrestrial magnetism, Miscellaneous (as discontinuities observed in space and in time) . These variables are by no means independent; for instance, the frequency and kind of wave affect differently the phenomena observed at various places and distances. A complete study of the problem would require about 500 separate researches, each of them on a large scale. The completion of some of these researches would cost millions of dollars. The entire mass of data at present available can be con- sidered as completing only a very few of these researches. The known facts about the variation of the four functions with a few of these variables will now be summarized. Following that, a theory will be given interpreting these facts. June 4, 1921 dellinger and whittemore : radio fading 247 EXPERIMENTAL AND OBSERVATIONAL DATA Intensity of signals in day. (Variation with distance, place, and wave-length.) — The current in a receiving antenna is given by the following expression : T 1 -a d /, ^ ^ e vx . (1) where X is the wave-length, d is the distance from the transmitting station, e = 2. 718. ...and a is a constant known as the absorption coefficient. Quantitative measurements by L. W. Austin and others have shown that signals transmitted in the daytime follow this law within about 50 per cent particularly for the longer waves (over 1000 meters) . Variations in received current are associated with variations of the absorption coefficient a. It is a minimum for transmission over ocean water and varies greatly over land, apparently depend- ing largely upon the nature of the ground over which the waves travel. It has been observed that city buildings obstruct short waves. There is some evidence that waves tend to follow water, thus travel- ing greater distances along the coast than inland, and following rivers very readily. The Alps and other mountains are said by Schwartz- haupt to obstruct signals greatly by day, but little by night. The intensity of signals received from a given transmitting station varies greatly from day to day. Very long w^aves, such as those from the Lafayette station in France, vary as much from day to day as they do between day and night. Greater distances are covered by stations of a given power when transmission is along the Mississippi Valley than in other directions in the United States. For small distances, the factor containing the absorption coefficient in equation (1) is very nearly unity. Within these distances (up to 200 miles in many cases), the intensities of signals during day and during night are about the same, over sea-water at any rate, according to Austin. In transmission entirely in mid-ocean, very little fading has been observ^ed. The absorption factor of equation (1) also approaches unity as the wave-length is increased. Thus for a given distance long waves are absorbed less than short waves and the falling off in intensity with distance is less marked for long than for short waves. Intensity and fading of signals at night. (Variation with distance, place, wave-length and kind of wave.) — The average signal intensity is much greater at night than by day, and the fluctuation or fading 248 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 is violent at night, these tendencies being more pronounced the shorter the wave-length. Thus abnormally great distances are obtained at night by stations using short waves, even though the power employed is as small as one kilowatt. Signals from such stations in the north- eastern part of the United States have been heard across the Atlantic, and off the coast of South America, as well as across the North Ameri- can continent. The phenomenon of fading is much better known among amateurs than among commercial radio men because amateurs do most of their radio transmitting and receiving at night and they are limited by law to short wave-lengths. The great fluctuations in the intensity of signals and the extraordinary distances of transmission at night which have been reported by amateurs have not been taken very seriously by professional radio men because there are so many difficulties with radio apparatus that reliable results are hard to get. What is probably the most comprehensive series ever made of co- operative transmission tests on the phenomenon of fading was con- ducted during the past year through the cooperation of the American Radio Relay League and the Bureau of Standards. Transmission took place from stations at a number of points in the northwest quar- ter of the United States according to a prearranged schedule, and simultaneous records of received signal intensity were made by about one hundred specially appointed receiving operators. Through the hearty and enthusiastic cooperation of the officers and members of the American Radio Relay League it has been possible to obtain many thousands of these records and to gain a great deal of informa- tion which it would be difficult if not impossible to obtain otherwise without an enormous expenditure. The handling of the records made during these tests as well as many details of the management of the tests have been in the hands of Mr. S. Kruse at the Bureau of Standards. These tests have given an opportunity to confirm in a statistical way what had previously been the impressions received by operators and experimenters in the course of receiving signals for other purposes. Fading of signals as well as signals of abnormal intensity are ob- tained only at distances beyond which the absorption has been found to be appreciable. On 200 meter communication, fading is not often found within a distance of 20 miles from the transmitting station, but fading is usually found at a distance of GO miles or more from the trans- mitting station. June 4, 1921 dellinger and whittemore: radio fading 249 Three kinds of fading are observed : (1) Fading or swinging having a period of swing of the order of one second or less. This is associated with a given transmitting station. (2) Fading having a period of the order of one minute. This is associated with a region which may be that of either the transmitting or the receiving station. (3) Fad- ing having a period of the order of one hour. This is associated with a general direction of transmission or with a group of transmitting stations. Signals from a given transmitting station may be received with violent fading by some transmitting stations and simultaneously with very small fading by others. Certain transmitting stations are heard very well by many receiving stations in all directions on some evenings, and heard by very few receiving stations or in only one direction on other evenings. A given receiving station usually "hears" certain transmitting stations with great fading and others with little fading. Transmission wholly over water (both transmitting and receiving stations far from land) shows little if any fading, while a narrow strip of land intervening introduces fading, according to Nichols. Stations near the coast fade worse than inland stations. For three successive nights, no short-wave signals were heard in Virginia, though signals 800 meters or longer in wave-length came in with usual intensity. The same phenomenon occurred one night a week later in Baltimore and the District of Columbia. Later on, the ninth radio district (the Middle West) suffered a similar blank. During the District of Columbia anomaly the atmospheric conductivity was very abnormal, changing from a very high to a very low value without a corresponding change in the atmospheric potential gradient. At 12:17 a.m. normal conditions abruptly returned, transmission becoming very good. Signals on long wave-lengths, up to 23,500 meters, show very little variation in intensity. There is little if any difference in the fading from continuous wave and from spark stations on any wave-length. Strays. (Variation with place and time.) — Strays are more intense in the summer than in the winter, and in the night than during the day. They are more frequent and more severe in the tropics than in temper- ate latitudes. At a given locality most strays come from a given direction. For the northeastern part of the United States this direction is south or south west. Strays are much less common in mid-ocean than near 250 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 land, both by day and night. The change from day to night con- ditions is much more abrupt at sea than on land. Stray storms us- ually accompany convective weather. On October 5, 1920, severe strays were observ^ed by receiving stations in New England, and no New England short-wave transmitting sta- tions were heard outside of that locality. Transmission elsewhere was excellent. Direction of signals. (Variation with time, wave-length, distance and kind of wave.) — Changes in the direction of the wave front of waves reaching a receiving station from a given transmitting station are observed only at long wave-lengths, but are especially marked with continuous waves. They are far more noticeable at night than in the daytime. On 15,000 meters enormous changes in direction are observed at night (as much as 90 degrees within half an hour), while the changes observed during the daytime are very small, seldom exceeding ten degrees. On 1000 meters, direction changes as great as ten degrees are seldom observed. The readings of direction can seldom be made sharply while changes in direction are occurring. Sometimes when it has been changing very rapidly it becomes impossible to determine on any direction, the direction-finder giving no indication of a minimum signal in any position. The minima observable are less distinct at night than during the day. All direction changes are greater at night than in the daytime. Direction changes are very small at very short distances from the transmitting station, are great at medium distances, and small again at very great distances from the transmitting station. These facts have been observ^ed particularly regarding signals from the New Brunswick, New Jersey, radio station. Eckersley states the belief that waves are refracted in passing from sea to land and vice versa. Tests of radio compass stations indicate that those stations which receive signals entirely over water have no error. Effects of sunrise and sunset. (Intensity, fading, strays, and di- rection. Variation with wave-length.) — Great variations in the intensity of radio signals of all wave-lengths, even up to 15,000 meters, are observed at sunrise and sunset. Such variations are especially noticeable when transmission is in an east and west direction. Transmission is not as good between stations when the boundary between dark and daylight intervenes as at other times of the day. JUNB 4, 1921 DELLINGER AND VVHITTEMORE: RADIO FADING 251 It has been reported that at sunrise and sunset the shorter waves have the advantage over the longer ones in transmission across the Atlantic. At sunrise or sunset at the sending or receiving stations the intensity of signals on long wave-lengths becomes abnormally great. On short wave-lengths, at sunrise at the receiving stations, the signals from distant stations merely become steadier for a moment before they suddenly become inaudible. It is possible that the reported differences in the abilities of inland and coastal stations in the United States to receive transatlantic signals may be the result of differences in their relation to the line of sunrise or sunset. Effects of time of year. (Intensity and strays.) — Signals from distant stations are much louder on winter nights than on summer nights. Signals become poorer in the spring and it is a question whether this is caused by vegetation, ionization, change in tempera- ture, or other factors. Strays are much less frequent and normally much less intense, in winter than in summer. Effect of eclipses.— The occurrence of an eclipse has been found to improve signals, even when they pass only through the penumbra. Effects of atmospheric electricity, terrestrial magnetism, solar activity. (Intensity.) — In contrast to its effect on wire telegraphy, an aurora has very little effect on radio, except possibly short-wave signals. On an auroral evening none of the usual western stations could be heard at Hartford, Connecticut, but that city did succeed in com- municating with Boston, a thing which, curiously, is usually impossible. On the day after an aurora a Chicago station copied signals from a station in Los Angeles. An aurora is preceded by violent variations in the earth's magnetic field, and usually occurs during periods of great sunspot activity. An aurora would seem to be an extreme case of disturbance at or below the Heaviside surface, producing ionization and also strays. The conductivity of the atmosphere is somewhat greater at night than during the day. The atmospheric conductivity decreases and the potential gradient increases at the ground level at sunrise and sunset. Culver reports that when the potential gradient and the conduc- tivity of the air fluctuate greatly, strays are intense. He reports also that the intensity of strays varies inversely as the solar constant 252 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 and directly as the intensity of the earth's magnetic field. Over sea the electrical conductivity of the air fluctuates less and is more uniform from day to day than over land. Discontinuities in space and time. (Intensity and strays.)— It is found that some stations have great difficulty in establishing com- munication with other stations quite near them though they have no difficulty in reaching other stations much farther away. Stations in the neighborhood of Boston, Massachusetts, furnish examples of this. It has also been found impossible to transmit over 70 miles east from Hartford, Connecticut. Silent zones, where signals cannot be heard from certain stations, are frequently found at sea, the most noted ones being along the coast or between two bodies of land. Inland stations have been found to get copy when coastal stations cannot. This may possibly be a sunset phenomenon or the result of the location of the stations with respect to sources of strays. Stations less than a mile apart may differ radically in the intensity of strays observed and in the intensity of signals received from a given transmitting station. Meteorological effects. (Intensity, fading, strays.) — A good radio night, that is, one when the signals are loud and the strays are weak, is usually cloudy or is preceded by a cloudy day. Fading, however, is not affected by clouds. Transmission is usually good during and immediately after a rain storm. While correlations between meteorological and radio conditions have been sought repeatedly, little proof of such correlations has been found. Indirectly, meteorological conditions such as temperature, convec- tion, etc., at the earth's surface may somewhat affect the regularity of the boundary surface of the Heaviside or aurora layer, and may thus cause night strays and the disappearance of signals. Thus the difference in temperature between land and sea may cause an effect extending far up into the air. The effect of weather conditions on the insulation of an antenna and the resistance of the ground are principally important in day transmission. The effect of weather conditions on ionization and on the boundaries of the ionized regions in the upper atmosphere are more prominent at night. During the October, 1920, fading tests conducted by the American Radio Relay League and the Bureau of Standards, it was observ^ed June 4, 1921 delunger and whittemore; : r.\dio fading 253 that fading was small, signals were good, and strays were weak when it was raining at the receiving station. (Cases of little fading, 17; medium fading, 18; severe fading, 9. Signals were weak 4, moderately- loud 31, and very loud 7 times. Weak strays 24, medium strays 13, and loud strays 6 times.) Clouds at the receiving station are conducive to good signals. (Weak signals 9, moderately loud 75, and very loud 17 times.) It is possible that clouds blanket the upper air from the distur- bances of temperature and other effects on the earth's surface. DISCUSSION AND EXPLANATION The complexity of the phenomena suggests that the causes are complex, so that no one explanation will fit all the observations. How- ever, many of the more clearly established facts lend themselves very well to the explanation of the transmission of radio waves pro- posed below. Daytime transmission. — The waves that travel along the earth's sur- face (roughly, the sliding waves), and not the waves in the upper at- mosphere, are those which are utilized in the daytime. This is in- dicated by the formula given in equation (1) in which the absorp- tion coefficient, a, varies with the character of the surface over which transmission takes place. It is a minimum for sea water, and is greatly dependent on land characteristics. For short distances, short waves give the loudest signals, the ab- sorption being negligible. For long distances, during the day time when formula (1) holds true, long-wave signaUing is more efficient, for the absorption factor predominates and limits the transmission for short wave lengths. During the day the waves which get up into the atmosphere can be considered as entirely absorbed by the upper ionized regions, known as the stratosphere. Thus the intensity of the transmitted waves depends on the ground conditions. This is borne out by the fact that day transmission over sea varies very little with time. This is to be expected, because the sea exhibits entire uniformity in its effect on waves passing over it, thus tending to confirm the idea that ground conditions determine wave intensity in the daytime. The idea that waves are retarded by ionization is a very old one. Elihu Thomson and Fessenden, however, first locaHzed the ionization on the ground, but it has since been assumed to have its seat at higher and higher levels. The ionization of the air, which is not nearly large 254 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 enough near the ground to produce any effect, becomes larger as the distance from the earth increases. The extreme ultraviolet rays of the sun ionize the air, but these rays are entirely absorbed during their penetration of the upper at- mosphere. In the daytime, ionization in the higher levels is therefore unquestionably much greater than at lower elevations. Fleming states that the conductivity of the air near the earth's surface is 100,000 times too small to explain the observed absorption of radio waves. The ionization of the upper atmosphere, however, is so very great that it is probable that the waves which penetrate into the higher parts of the air in the daytime are totally absorbed, and that the observed absorption of waves received at a receiving station is to be explained by the losses in the poorly conducting earth itself. While the variations from day to day in daytime transmission may not be entirely a ground phenomenon, it seems probable that they are attributable to variations in ground conditions. Intensity and fading of signals at night. — The short radio waves on which signals are heard at great distances during the night must travel detached from the earth's surface, for along the surface these waves are highly absorbed. It is probable that they reach an upper surface of the atmosphere, which is so highly ionized that its electrical conductivity is far greater than that of the surface of the earth, and hence they can travel with relatively little absorption. The idea of an upper conducting surface between which and the earth's surface electrical waves would be propagated, antedates the use of radio for long-distance communication since it was considered by Fitzgerald in 1893 and by Heaviside in 1900. Considerations largely independent of radio phenomena suggest the following structure and boundaries of the atmosphere, as indicated in figure 1. (1) The earth's surface, a relatively poor conductor. (2) The troposphere, about 10 kilometers thick, within which are the causes of our meteorological phenomena, and an atmosphere similar to that which we breathe. (3) A radioactive layer, separating the troposphere from the region above it. (The existence of this layer is not as well established as the others, nor is its existence so important in explanation of the radio phenomena.) (4) The stratosphere, or isothermal layer, having a thickness of approximately 100 kilometers. The stratosphere is ionized in the June 4, 1921 delunger and whittemore: radio fading 255 daytime but quickly loses this property by the recombination of the ions at night. (5) The Heaviside surface, permanently ionized, and an almost perfect conductor. The boundaries of these layers are obviously not absolutely horizon- tal surfaces. The stratosphere is ionized during the day only, the sun's rays being the cause of the ionization. The permanently ionized region above the Heaviside surface is the region of permanent aurora, Heamide surface Stratosphere ^Isothermal layer) Ior)/zed fyay onk/) 100 km. /^Radioactive layer Earth's surface Fig. 1. — Vertical cross-section of the earth's atmosphere. and is so good a conductor that the waves cannot penetrate it. Any waves reaching it can only slide along it, just as waves slide along the even less perfectly conducting surface of the earth. Previous explanations of radio transmission phenomena have con- sidered the waves as being constantly reflected back and forth or progressively refracted between the Heaviside surface and the earth, both by day and by night, their intensity being reduced in the day- time by the ionization in the stratosphere. That view does not ex- plain why the waves have the characteristics of ground absorption 256 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 in the daytime only, nor why they fade only at night. It seems more nearly correct to consider the daylight transmission of waves as being mainly along the earth as a guiding conductor, none of them being able to reach the Heaviside surface because of the intervening ionized stratosphere, while the waves at night reach the Heaviside surface and travel or slide along it without appreciable absorption. If this be true, then the waves should reach enormous distances at night, short waves traveling farther than long ones. Because of the variable absorption which may be introduced by the irregulari- ties of the Heaviside surface and the adjoining regions, the waves may vary rapidly in intensity. Small irregularities would affect short waves more than long waves; hence short waves would fade most. These conclusions are in precise agreement with the facts. Within the distance from a transmitting station in which ground absorption is negligible there is no fading and the night and day in- tensities are equal, since the waves are not affected by conditions in the upper atmosphere. If the theory given here be correct the maximum intensity of signals received at night should be that given by the transmission formula with the absorption factor equal to unity, and this has been observed to be true. This should be taken as a standard transmission distance. Certainly this is the only unique value, the only value in which the nature of the location of the trans- mitting and receiving stations does not enter. Thus the transmission formula cannot predict the varying intensity of signals observed at night, but it does give the limiting value of signal intensity. It also shows why extraordinary ranges are more likely to be obtained at night with short waves than long waves. This theory of night wave transmission is strikingly like the ex- planation of the flight of the projectile from the German long-range gun. In both cases it is now realized that there exists a region of the upper atmosphere of surprisingly low opposition or resistance. G. Sagnac says that "zones of weak signals" observed between moving ships are due to the earth's orbital motion dragging the sur- rounding ether with it. It seems more probable, however, that such phenomena are caused by regions of exceptionally great absorption either of the wave transmitted along the ground or of the wave trans- mitted along the Heaviside surface, depending upon the conditions. The relatively small fading on long wave-lengths is partly attri- butable to the fact that the transmission is along the ground. June 4, 1921 dellinger and whittemore: radio fading 257 If fading were to be explained by reflection and interference be- tween the direct wave and the reflected wave it would seem obvious that fading will be greater in the case of continuous wave stations than spark stations, but apparently this is not the case. It seems probable that the reflection in the upper regions may more truly be considered a quasi-refraction resulting from an increase in the velocity of the waves as they enter the more highly ionized air. Strays. — Of the several kinds of strays, some have their origin near the receiving station while others are waves sent out by electrical disturbances in certain definite regions such as the western part of the Gulf of Mexico or the central part of Africa. vSuch regions are mostly tropical. The fact that strays are more intense at night than in the daytime is explained by the greater ease of propagation of all waves at night so that strays which are only local in their effects in the daytime spread to a distance at night. The strays at night seem to be caused by occurrences at or above the Heaviside surface, because there are times when the strays are intense and yet signals are inaudible or very weak and fading violently. This indicates a turbulent region of ionization over the area involved, which gives rise to strays and which absorbs waves that come into it. The aurora itself represents an extreme case. Direction of signals.— There is no correlation between fading and direction changes except that both are greater at night. Thus fading is greatest for short waves and direction changes are greatest for long waves. This makes it appear that the explanations of the two may not be closely related. The interference caused by waves from the Heaviside surface may explain the direction changes observed at night (rapid direction changes on long waves), as it is too remote to cause interference with short waves. Kinsley has suggested that the direction changes may be the result of reflection at the radioactive boundary between the troposphere and the stratosphere. Effects of sunrise and sunset. — The change from the ionized sun- light condition to the insulating condition of darkness introduces a surface of discontinuity which acts as an obstacle to the waves, partly reflecting them back. It is to be noted that the change takes place in the stratosphere, above the clouds. This deflection of the waves depends on a change in velocity of the waves, produced by the ioniza- tion. Since this change in velocity is proportional to the square of 258 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 the wave-length, the sunrise and sunset effects are greater for the longer wave-lengths. Effects of time of year.— The increase of signal strength at night and the scarcity of strays in winter indicate that the Heaviside surface is more nearly level and encumbered with fewer masses of ionized air which are emitting disturbances. This more quiescent condition is probably a result of the sun's acting on the atmosphere for fewer hours each day. Effects of atmospheric electricity, terrestrial magnetism, solar activ- ity.— There is slight connection between radio phenomena and the usual variations of atmospheric conductivity and similar quantities at the surface of the earth. During intense strays and fading, the conductivity and potential gradient have been known to fluctuate more than usual. This indicates that the masses of ionized air that cause the radio phenomena have a slight effect extending down to the earth's surface. The visible aurora seems to involve a lowering of the Heaviside surface far down into the stratosphere or even lower. It is known to extend down to about 60 kilometers above the earth's surface. This is done with much turmoil so that it usually stops short-wave radio altogether, or, if signals can be heard, the strays are violent. It completely upsets all usual radio conditions, in fact, in special cases it improves short-wave signal intensity over a certain territory, probably because in this case the lowering of the Heaviside surface envelops the usual source of disturbances. Discontinuities. — While often difficult to explain, discontinuities are probably caused by some local ionization which acts like a barrier for that particular region. The fact that transmission is good for points beyond the silent zone substantiates the general theory of trans- mission of waves at night by the upper part of the stratosphere. In such a case they probably go around the barrier. The origin of this local ionization is unknown. Apparently some local condition on the earth's surface may cause it. It may be direct, as by radioactive emission, or indirect, as by extreme temperature dift'erences or vertical convection currents in the air. Such indirect causes seem probable since there are many cases of discontinuities on or near the coast or in mountainous regions. The cause of discontinuities is doubtless related to some sort of ionization change such as that accompanying sunrise and sunset. June 4, 1921 abstracts: geoi^ogy and hydrology 2o9 CONCLUSION It can be concluded that the causes or sources of fading and of strays are in the atmosphere between the earth's surface and the Heavi- side surface. However, the origin of these causes, in turn, is un- doubtedly from below the ground or from outside of the earth's at- mosphere. Daytime transmission is effected entirely by means of the waves carried along the ground, while night transmission, especially at great distances and on short waves, is by means of waves transmitted along the Heaviside surface. The latter, at night, are thus free from the absorption to which ground waves are subject in the daytime. They are, however, subject to great variations, caused by irregularities in the Heaviside surface and absorbing masses of more or less ionized air at or near that surface. These variations account for fading. The theory here given may be only a very rough approximation but it has the advantage of giving a clearer picture than has been available. The inter-relation of radio phenomena and the atmos- phere's electrical condition is very close. Subordinate in importance to the atmospheric conductivity are the other electrical properties, the solar constant, and the terrestrial magnetic and meteorological conditions. The properties of the stratosphere seem to be far more important than those of the troposphere, since the stratosphere seems to be the seat of the immediate causes of the observed radio trans- mission phenomena. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. GEOLOGY AND KYBROLOGY. —Ground water in Pahrmnp, Mesquite, and Ivanpah valleys, Nevada and California. Gerald A. Waring. U. vS. Geol. Survey Water-Supply Paper 450-C. Pp. 30, pis. 5, figs. 2. 1920. The report comprises a geographic and geologic sketch and a discussion of the ground waters of the regions named. The valleys consist of detached basins with interior drainage, mountain-rimmed and deeply filled with al- luvium. Alluvial fans slope, from the mountain areas and grade into the playas which occupy the lowest portions of the basins. Springs occur in all of the valleys, and artesian flows have been obtained in Pahrump Valley. Records of springs and wells are included in the report, and also a brief state- ment of the quality of the water. The extent of irrigation already practiced, the possibilities of further irrigation development, and the limits of agricul- tural projects are discussed. N. E. D. 2G0 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 GEOLOGY. — Geology of Alamosa Creek valley, Socorro County, New Mexico, with special reference to the occurrence of oil and gas. Dean E. Win- chester. U. S. Geol. Survey Bull. 716-A. Pp. 15 (1-15), pis. 5. 1920. This report is based on a field study of the coal resources of the region. Structure is therefore discussed only in a general way and not represented by contours. The geography of the valley lying between the Continental Divide on the west, smaller Tertiary mountain ranges to the south, and the Sierra Ladron on the east, is briefly described. About 8,000 feet of sedimentary rocks from Carboniferous to Recent are exposed. Carboniferous and Triassic represented by red beds are unconformably overlain by Cretaceous consisting of the Dakota sandstone at the base, with a series of shales, sandstones and coal beds overlying it. This upper series is divided into the Miguel formation roughly equivalent to the Mancos shale but more sandy; and the overlying non-marine Chamiso formation containing a Mesaverde flora. Unconform- ably on the Cretaceous lies the Tertiary Datil formation, largely volcanic with associated sandstones and conglomerates. Quaternary terrace gravels overlie all of these, and all formations except the younger terrace gravels are capped by lava flows. Structurally the area is the southeastern part of the San Juan Basin from the rest of which it is largely separated by the northwest trending Zuni Mountain uplift. The prevailing dip at low angles to the west is interrupted by many faults and minor folds and cut by dikes, most of which trend roughly parallel to the Zuni Mountains. As possible source of oil three larger anticlines are described, the largest 13 miles long. The presence of abundant carbonaceous shales, of coal with about 55 per cent fixed carbon, and of several massive persistent sandstones in the Miguel formation, which can be tested by holes less than 2,000 feet deep, afi"ord favorable indications for the presence of accumulations of oil. The formations older than the Cretaceous may also contain oil accumulations. M. I. Goldman BOTANY. — Another conidial Sclerospora of Philippine maize. William H. Weston, Jr. [ourn. Agric. Research 20: 669-684. Pis. 4, figs. 1. 1921. Another conidial Sclerospora is involved in the destructive maize downy mildew of the Philippines in addition to Sclerospora philippinensis, the casual fungus previously described. This second species, found in the Islands of Cebu' Bohol and Leyte, occuring commonly on maize, rarely on the wild grass, Saccha-um spontaneum, and once on sugar cane, differs from 5. philippinensis in that the conidiophores are generally longer and more slender, the basal cells are of much greater length in relation to the main axis, while the conidia especially are longer and less broad; and is described as new under the name of Sclerospora spontanea. These specific morpholog- ical differences remain constant even through several generations on a range of hosts, including maize, teosinte (Euchlaena spp.), Miscanthus japoni- ciis, and Saccharum spontanem. The size and shape of the conidia, the most valuable criteria of interspecific distinction, are given in detail, meas- urements of 700 conidia of each being presented in tables and graphs, and the more significant biometric constants being compared. Although morpho- logically distinct, the two species are alike physiologically in their effect on and in their virulence to the same host species. The probable relation- ship of the two fungi to the other conidial Sclerosporas of the Orient and to the oogonial stages of the Philippines is discussed. The occurrence of June 4, 1921 abstracts: analytical chemistry 261 Sderospora spontanea on the wild Sacchanmi spontaneume is regarded as evidence that the disease has passed and is passing from this native host to introduced maize. W. H. W. ENTOMOLOGY. — The North American ichneitmon- flies of the tribes Lycorini, Polysphinctini, and Theroniini. R. A. Cushman. Proc. U. S. Nat. Mus. 58: 7-48. PI. 2. 1920. This paper adds another to the series of papers revising the American tribes of the subfamily Ichnenmoninae {Pimplinae). In it the genera and species are tabulated and described, and notes on the location of the types, biology of the species, and other valuable taxonoraic information given in detail. As is usual for papers of this series, the host list and an index of the species treated is included. Several text figures illustrating the structural characters and some drawings and photographs showing the habitus of the insects are added. S. A. Rohwer. ENTOMOLOGY. — A^ew Serphidoid, Cynipoid, and Chalcidoid Hymenoptera. A. A. GiRAULT. Proc. U. S. Nat. Mus. 58: 177-216. 1920. This paper contains descriptions of new parasites which have been received for identification by the Bureau of Entomology. Most of the forms char- acterized are from North America and some few of them are known to be of considerable economic importance. S. A. Rohwer. ANALYTICAL CHEMISTRY.— 5«/p/z Mr in petroleum oils. C. E. Waters. Bur. vStandards Tech. Paper 177. Pp. 28, fig. 1. 1920. Short accounts are given of the theories concerning the origin of the sul- phur and sulphur compounds which are found in crude petroleum. The forms of combination in which the element occurs, their identification and significance are briefly discussed. Tests for the detection of sulphur are de- scribed, and the copper test is shown to be one of great delicacy. Although it will show the presence of very minute amounts of free sulphur or of hydrogen sulphide, it may be of no value at all when the sulphur is in stable organic compounds. Various methods that have been used for the determination of sulphur in oils, and finally a new procedure, are described. The new method is based on the preliminary treatment of the oil with nitric acid saturated with bromine, followed by fusion with a mixture of sodium nitrate and carbonate. Data obtained by the analysis of certain oils by this and other methods are given. From these it appears that there is no loss of sulphur by the new method, which is recommended for laboratories which do not have a bomb calorimeter. C. E. W. ANALYTICAL CHEMISTRY.— .4« electrolytic resistance method for de- termining carbon in steel. J. R. Cain and L. C. Maxwell. Bur. Standards Tech. Paper 141. Pp. 24, figs. 6. 1919. Method and apparatus are described for rapidly and accurately determining carbon in steel by absorbing in a solution of barium hydroxide the carbon dioxide resulting from direct combustion of the metal in oxygen, and deducing the carbon content from the change in electrical resistance of the barium hydroxide solution. J. R. C. 262 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 11 PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES BIOLOGICAL SOCIETY 619th meeting The 619th meeting of the Biological Society of Washington was held in the lecture hall of the Cosmos Club at 8.00 p.m., January 22, 1921, with President N. HoLLisTER in the chair, and 112 persons present. Upon rec- ommendation of the Council, Mr. Arthur J. Poole and Mrs. Marion G. Brown were elected to membership. Informal communications Dr. Paul Bartsch stated that the Hiraci collection of Japanese and Pacific molluscs had been given to the U. S. National Museum. This with other large collections makes the collection of molluscs in the National Museum the largest in the world. Dr. Bartsch also stated that a mocking bird was spending a third winter in his yard. It seemed to be the supply of water which is most appreciated. Dr. R. W. vShufeldT exhibited a file fish, part of a collection from Argen- tina, with an apparently abnormal file, it being double. Dr. T. S. Palmer, referring to the height at which birds fly, stated that W. E. D. Scott at Princeton, and Dr. Chapman telescopically observing birds crossing the disk of the sun, estimated their height at 10,000 feet. Photo- graphs of geese crossing the sun's disk yielded an estimate of 29,000 feet or about 5.5 miles. Direct observation from aeroplane has been made up to 10,000 feet. Dr. H. M. Smith made the first public announcement of the taking of the large forked-tailed swift, Microperus pacificus (Latham), upon the North American Continent. The capture was made by Mr. G. D. Hanma of the Bureau of Fisheries in the Pribiloff Islands. Mr. A. H. Howell stated that the crow roost at Laurel, Maryland, oc- cupied for some ten years, has been abandoned for some other place farther north. Dr. L. O. Howard conveyed to the Society the greetings of former President Dr. F. A. Lucas, who was recently in the city. Regular program The speakers were introduced by Dr. J. C. Merriam, President of the Carnegie Institution of Washington. L. H. Miller, of the University of California: A^^^/za/^ beds of Rancho La Brea. ^ The asphalt beds, small and few in number, lie a few miles north of Los Angeles. The asphalt has varied in viscosity from time to time, and has been in a more or less vertical circulation. vSince Pleistocene times the beds have served as a constantly baited trap for all kinds of animals, and have gathered a characteristic fauna from that region in great numbers. Re- ferring principally to the birds. Dr. Miller said that, local as the deposits are, their richness and completeness threw light upon several large biological problems. (1) Questions of phylogeny. fhe deposits at Rancho La Brea show a very plastic condition of the genus Haliaetiis in the Pleistocene. Many forms of bald eagles, some larger and some smaller than those now existing. June 4, 1921 proceedings: biological society 263 occurred, and out of this stock the present species seem to have crystallired. (2) Questions of homoplasy. A walking vulture, Tcratornis, also a walking eaglel occur, both simliar to Serpentarius, the secretary bird of Africa, but the former only superficially. (3) Questions of variability. The great variability already referred to exists in other genera also, as in Bubo and Cathartes'. Some forms of these were of tremendous size. Others such as the Calif ornian condor, had reached more stable form. (4) Questions of distribution. Many forms, now Central and South American in distribution, occur at Rancho La Brea. Thus the caracara and the black vulture, rare along the Californian border, are common. Morphus, the eagle hawk, and certain storks of Brazil and Argentina, occur in lesser numbers. Here is found Parapavo, a peacock-like bird, forming a link, both in distribution and development, between the pheasants of the old world and the ocellated turkey of Yucatan and the turkey of the eastern United States. (5) Indices of climate. Inferences from the present chmatic distribution of birds, iden- tical with or similar to those found at Rancho La Brea, indicate a climate more tropical than that of recent times, and supporting a vastly richer assort- ment of forms. The paper was illustrated with pictures of the asphalt beds and specimens from the beds, and restorations of the life and environment there in Pleistocene days. H. C. Bryant, of the University of California: Birds and mammals of Yosemite Park. The speaker called attention to the changing distribution of birds during the day, or season, or with changes in weather. The white-throated swift, apparently on the wing all the daylight hours, feeds on the floor of the valley in the morning, later it flies at middle heights, and in afternoon only about the highest cliffs. As the season progresses many birds spread from the breeding and feeding grounds of the valley to the higher hill region, such as the jay shrike, and kingbird. On the other hand, storms in the highlands drive birds into the valley, such as the nighthawk. Further notes upon many birds were given. Protection to birds does not 1 ad in all cases to their increase. This is true of grouse and quail, suggesting unsolved problems. Protection cannot be given to all animals alike. The interrela- tion between deer and panther is an example. The speaker emphasized the impossibility of appreciating the fauna and flora of Yosemite or other National Parks or Preserves without familiarity with nature in the field. The interest taken by young and old alike in studies afield of animals and plants justifies a greater development of the naturalist who can interpret the work of the specialist and make it accessible to the nonscientific public. The paper was illustrated by numerous views of Yosem- ite and of individual birds and animals. The papers presented by Drs. Miller and Bryant were discussed by R. W, Shufeldt, a. S. Hitchcock, David White, and J. C. Merriam. A. A. DooLiTTLE, Recording Secretary. 264 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 1 1 , NO. 1 1 SCIENTIFIC NOTES AND NEWS The Pick and Hammer Club met at the Interior Department at 8 p.m. on Saturday, April 30. Prof. E. W. Berry of John Hopkins University gave an illustrated talk on Impressions of Peru and Bolivia. The National Academy of Sciences held its annual meeting in Washington, April 25-27. Sessions for the presentation of scientific papers were held at the National Museum on April 25 and 26. The following-nam.ed 15 per- sons were elected to membership: Frank Michler Chapman, ornithol- ogist, American Museum of Natural History, New York; Willi^vm Leroy Emmet, electrical engineer, General Electric Company; William Draper Harkins, chemist, University of Chicago; AlES Hrdlicka, anthropologist, National Museum; Arthur William Kennelly, engineer, Harvard Uni- versity; William George MacCallum, pathologist, Johns Hopkins Med- ical School, Baltimore; Dayton Clarence Miller, physicist, Case School of x\pplied Science, Cleveland, Ohio; George Abram MillER, mathemati- cian. University of Ilhnois; Benjamin Lincoln Robinson, botanist. Harvard University; Vesto Melvin Slipher, astronomer, Lowell Observatory, Flag- staff, Arizona; Lewis Buckley StillwELL, electrical engineer. New York City; Donald Dexter Van Slyke, biochemist, Rockefeller Institute for Medical Research, New York City; Thomas Wayland Vaughan, geologist, U. S. Geological Survey; Henry Stephens Washington, geochemist. Geo- physical Laboratory, Carnegie Institution of Washington; Robert Sessions WoODWORTH, psychologist, Columbia University. Mr. Arthur E. Fath returned to the U. S. Geological Survey on April 29, after several months' furlough. Dr. Joseph GrinnEll, director of the Museum of Vertebrate Zoology, Berkeley, California, was in Washington in May studying the ornithological collections at the National Museum. Mr. O. B. Hopkins has submitted his resignation as geologist in the U. S. Geological Survey, effective April 1, to continue his work in the prospective oil fields of Canada. Dr. Robert Ricgway, of the U. S . National Museum, receixed the Daniel Giraud Elliot Medal of the National Academy of Sciences on April 26, for his studies of the birds of North America. Dr. H. L. Shantz, agricultural explorer of the Department of Agriculture, lectured before the Cosmos Club on April 25 on Some experiences of a trip from the Cape to Cairo. Mr. E. W. Shaw, geologist, resigned from the U. S. Geological Survey on March 30 to take up consultation work in oil and gas. Dr. C. W. Stiles, of the Hygienic Laboratory, U. S. Public Health Service, received on April 26 a gold medal of the National Academy of Sciences "for eminence in the application of science to the public welfare," in recognition of his work on the hookworm disease. Dr. Charles D. Walcott, Secretary of the Smithsonian Institution, re- ceived the first award of the Mary Clark Thompson Medal of the National Academy of vSciences, for distinguished achievement in geology and paleon- tolog^^ The medal was awarded at the meeting of the Academv on April 26. Mr. Arthur R. Willis, chemist with the U. S. Tariff Commission, met death by accidental drowning in the Potomac River on April 24, 1921. Mr. Willis was a native of Ohio, and was 29 jxars of age. He was a member of the Chemical Society. JOURNAL OF THE WASHINGTON ACx\DEMY OF SCIENCES Vol. 11 June 19, 1921 No. 13 MATHEMATICS AND BACTERIOLOGY.— 0« the dilution method of counting bacteria} P. V. WELLS and W. F. WElls. (Com- municated by S. W. Stratton.) The dilution method of counting the number of bacteria in water is an example of the use of a geometric scale when the variations are so large that an arithmetic scale is cumbersome. We shall investigate briefly the theoretical basis of this method, with a view to the stand- ardization of the experimental procedure, and shall show that its re- sults have a remarkably simple interpretation. FUNDAMENTAL THEOREM Consider a "universe" containing .4 cc. of water, and B bacteria. If a sample of a cc. is examined, the chances of finding n, n — l,....2, 1, 0 bacteria, respectively, in the sample are given by the terms of the hypergeometric series B{B - 1)...{B - n-^ 1) A^(A^- l)...iN -n-\-l) r __W__ 7i(n^-^ W{W-1) 1 [^+''B-n+l~^ 2! {B-n + l)iB-n + 2)^--\ ^^^ where the water is conceived as composed of W "particles," giving the total "population" N = B + W, and the sample contains m parti- cles. Each particle, whether bacterium or water, is assumed to have an equal chance of being sampled. The general term, for the proba- bility of finding C bacteria in the sample is ^^(^-1) .... (B-n-fl) ^ A^(A^ -1)....{N -n+ 1) rnjn - 1) .... {n - C -f 1) W{W - 1) .... {W - n + C + 1)1 . L a {B-n + l){B -n-{-2)....{B-C)l ^ But since the population N is arbitrary, this result is of little use as it stands. Taking the population N as infinite, and n as extremely large, but small compared with A^, and placing X^B/A as the number of bac- ' Received April 29, 1921. 265 26G JOURNAL OF THE WASHINGTON ACADEMY OF SCIEXCES VOL. 11, NO. 12 teriapercc, we have B/N = aX/n. Hence equation (2) reduces to P^ = exp ( — aX) * ^^ C! ^ (3) which is the fundamental expression for the probability Pc of finding C bacteria in an a cc. sample of water containing X bacteria per cc. The sample usually taken is a = 1 cc. From the form of the expres- sion we have 00 ^C{Pc)=l (4) 0 as it should, to represent probability. The probability Pq of a neg- ative result, on plating out, is Po = exp(-aX) (5) and of a positive result is 1— Po- This reduces to McCrady's- result when aX = 1, namely 1 — Po = 1 — l/e = 0.63. As there has been some misunderstanding of McCrady's work, per- haps due partly to the form in which it was expressed, a few remarks on the theory here given may be appropriate. The only assumptions are: (1) that in a large number of samples of a cc. each, the bacterium considered is on the whole as often in one of the samples as in another (random distribution), and (2) that the presence of one bacterium in a sample does not affect the chances of the others being there (inde- pendent probabilities). These assumptions can hardly be doubted in this particular case, because one bacterium occupies about 10~^^ cc, so that one million per cc. would occupy only one millionth of the vol- ume. From studies of Brownian particles it is known that there are considerable fluctuations in density. Now suppose the samples are diluted, /3 cc. in D cc. of water, then the probability of finding C bacteria in a cc. of the diluted sample is, from (3) where zC Pc=~exp.{-z) (6) X a|3 — D 2H. H. McCrady. Journ. Infectious Diseases 17: 183. 1915. June 19, 1921 wells and wells: counting bacterl\ • 267 As a function of z, this equation is a special case of Pearson's Type III frequency curve, and the mode Mz, or most probable value of z is simply Mz = C. "per cent negative" method The quantities a and /3 are usually taken as 1 cc.(q! = /3= 1). The probability of a negative result (no bacteria) in the diluted sample is simply the negative exponential Po = exp. (— -) (7) This is the frequency curve of the negative plates in dilutions D. The mode {Md= ^), or most probable value of the negative dilution D is infinite, as it should be. The fraction of negative plates in dilu- tion D is Pq, and the percentage of negative plates 100 Pq, when the number of samples taken is sufficiently large to overcome the fluctuations of sampling, and when there is no constant error in the experimental procedure. In practice the sample (1 cc.) is diluted in the definite dilutions D=10, 100, 1000, etc., cc. of water, and Fo observed. In order to compute X from these results, place in (7) E = \n Then f-^) = ^ (8) \Pj D x= d +e (9) Where x = log X d = \ogD\ (10) e == log E ] The arithmetic means d and e are therefore related by the simple ex- pression x=d+~e (11) and the number of bacteria per cc. X is given by the product of the geometric means X = GdGe (12) Where e — log Ge J The "per cent negative" method requires for convenient application a table giving e in terms of Po, as in table 1. It is evident from the magnitudes in the second column of table 1 268 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 12 TABLE 1 Per cent Negative Correctioa 100 Po e 5 0.48 10 0.36 15 0.28 20 0.21 25 0.14 30 0.08 35 0.02 36.8 0 40 0.96-1 45 0.90-1 50 0.84-1 55 0.78-1 60 0.71-1 65 0.63-1 70 0.55-1 75 0.46-1 80 0 .35-1 85 0.21-1 90 0.02-1 that the arithmetic mean e in any actual case will be merely a cor- rection to be applied to the "average log dilution negative" d. The number of bacteria per cc, X, is therefore roughly equal to the geo- metric mean Gd of the numbers of cc. (D) into which the sample (Ice.) is diluted. Its precise value is given by (12) which is used in the form (11). The computation of the "log count" (x) is very simple. The dilu- tions are D = 10, 100, 1000, 10,000, etc., and the corresponding "log dilutions" are d = \, 2, 3, 4, etc.; only those dilutions are chosen for which the "per cent negative" (lOOPo) is between 5 and 90 per cent. The values of e are taken from table 1, and the sum {d ■{- e) recorded. The simple average of these figures gives x. The antilogarithm of X is the number of bacteria per cc. (X). The following examples illustrate the method. Example i (20 samples, 3 negative in D = 10 cc, 13 in 100 cc, and all in 1000 cc.) d Per cent Neg. d -\- e 1 20 1.21 2 65 1.63 .T = 1.42 X = 26 bacteria per cc. June 19, 1921 wells and wells : counting bacteria 269 Example 2 (20 samples, 11 negative in 10,000 cc, all negative in 100,000 cc.) d Per cent Neg. d •\- e 4 55 « = 3.78 X = 6 X 10^ = 6,000 bacteria per cc. To determine Po with precision, more samples must be taken at each dilution than is practicable for a single specimen of water, but the method is very useful where many bottles of water are collected, or where the samples represent a seasonal distribution. The use of the geometric mean in such cases is justified only by the type of such frequency distributions. This point will be considered in a subse- quent paper. METHOD OF BACTERIAL COUNTS No information is gained in the "per cent negative" method from the number of colonies found on the positive plates. Returning to the fundamental equation (6) , the probability of finding C bacteria in the diluted sample is Pc=-exp.(-2) (6) Now the bacterial counts are usually fairly large (OlO). In this case Stirling's formula gives C./ = CfV2^exp. (-C) (14) Comparing (6) and (14), Pc = V = f-Yexp.(C-.) (15) This is the frequency curve of bacterial counts of a given sample (at a fixed dilution). The mode {Mc)^ or most probable value, of C is given by the condition ^^ = ln ^ - ^ = 0 (when C^Mc) (16) PdC C 2C Neglecting — compared with In C, involving an error of 2 per cent when C= 10, and less for larger values, we have Mc = z = a0^ (Oio) (17) That is, when q: = /3 = 1, the number of bacteria per cc. (X) is simply the product of the dilution D and the mode Mc of the frequency dis- 270 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 12 tribution of bacterial counts C as would be guessed from "common sense." The frequency distribution (6) is mathematically very complicated. Its graph, represented in figure 1 for the values 2 = 10 and 100 bac- teria per cc, shows it to be nearly symmetrical about the mode, the 1 1^ i. c H««i>*r »\ dacter'to. Fig. 1. — Graph of frequency distribution. maximum becoming very accentuated as z increases. This is obvious from the variability of the curve, computed by Pearson's method of moments, and given in table 2 together with the other constants. Thus the curve possesses the remarkable property that although it is unsymmetrical, the mode and the arithmetic mean coincide within the errors of the computation. The geometric mean is of course slightly smaller, but either mean is quite close enough for practical use. Replacing the mode in (17) by the arithmetic mean (C), we have X = DC (18) so that the number of bacteria per cc. is calculated simply. June 19, 1921 wells and wells: counting bacteria 271 Representing the mode by the geometric mean {Gq), equation (17) becomes X = GdGc (19) where Gd is the geometric mean of the dilution (D) . Changing varia- bles to the logarithm, this gives x=^d + 'c (20) as the relation between the arithmetic means of the logarithms, and x~\ogX } d = \ogGD\ (21) c = log Gc TABLE 2 Constants of Bacterial Frequency Number of Bacteria per cc. (s) 10 100 Arithmetic Mean Bacterial Count (C) 9 .995 100 .001 Geometric Mean " "(G^) 9 . 54 99 .76 Standard Deviation {a) 3 .02 9 .55 Variability (100^) 30 percent 9.6 percent The logarithms can be read conveniently from the two-place table. (Tab. 3). TABLE 3 Two-Place Logarithms 0 1234 5 6789 1 00 04 08 11 15 18 20 23 26 28 2 30 32 34 36 38 40 42 43 45 46 3 48 49 51 52 53 54 56 57 58 59 4 60 61 62 63 64 65 66 67 68 69 5 70 71 72 72 73 74 75 76 76 77 6 78 79 79 80 81 81 82 83 83 84 7 85 85 86 86 87 88 88 89 89 90 8 90 91 91 92 92 93 93 94 94 95 9 95 96 96 97 97 98 98 99 99 00 To illustrate the computation, an example is worked out. (Ex- ample 3.) In any actual experiment the discrepancy between the two means is almost certainly due to experimental errors, and not to theoretical fluctuations of sampling. These errors are largest in the largest dilu- tions. The geometric mean is less affected by large errors in excess than is the arithmetic mean. On the other hand negative plates must be ignored, for a single one would make the geometric mean vanish. The question of what mean to use in this work, however, has little 272 JOXJRNAL OF THE WASHINGTON ACADEMY OE SCIENCES VOL. 11, NO. 12 theoretical importance. It is in space and time distributions that large variations and skewness may arise, and then the means dififer signifi- cantly. In many such cases the geometric mean is more probable than the arithmetic mean, as will be shown in a later paper. Example 3 Explanatory Form Dilution D 1 cc. 10 cc. 100 cc. 1000 cc. 10,000 cc. Bacterial count C Too many to count. (200) 130 190 82 53 None DC Deviation d logZ? 13,000 19,000 82,000 53,000 29.000 23 40 11 c log C 2.11 2.28 1.91 1.72 Sums 167,000 103,000 Arith. means 42,000 ± 13,000 Arith. mean of logs = x = 4.51 Geometric mean = antilog x = 32,000 ± 14,000 f Geom. mean^Gx^Gi) Gc 5 2.5 Number of bacteria per cc. I Arith. mean := X z^ DC = Actual Routine Form DC d d+c 13,000 2 4.11 19 .28 82 3 .91 53 .72 4 1 167 4 1202 d + c Deviation 8.02 2.01 4.11 4.28 4.91 4.72 18.02 4.51^ 0.40 .23 .40 .21 1.24 .16 32,000 ± 14,000 (3.2 ±1.4) X 10^ 42,000 ± 13,000 (4.2 ± 1.3) X 10^ Dev. 40 23 40 21 124 DC = 42,000 Gx = 32,000 a4,000. X = 4.51 ± 0.16 It should be emphasized that the logarithm itself furnishes a most convenient scale for the expression of results in bacteriology. Thus, instead of bothering to find the antilogarithm of x, this value itself can be used; x = S.67 means quite as much as X = 4.7X10^ = 4700, when equally familiar, and it is much more convenient for very large num- bers, as well as for graphical work. Moreover, the significant changes June 19, 1921 mohler and foote: soft x-rays 273 are those in x, not X, for in bacterial phenomena the population must be taken into account. The logarithm of the number of bacteria, and not the number itself, should therefore be used for routine pur- poses. SUMMARY The chance {Pc) of finding C bacteria in a cc. of water containing X bacteria per cc. is Pc = —^ exp. (- aX) This theorem is applied to the "per cent negative" (100 Po) method of counting bacteria and to the method of counting positive plates. It is shown that the variability in samples containing more than ten bacteria is small, so that differences between the arithmetic and geometric means cannot be due to fluctuations of sampling. The extreme variability usually found in bacteriology is due to differences of locality and time. In any case where the data vary very widely, a few very large values, representing perhaps less than one per cent of the results, may double the value of the arithmetic mean ; their effect upon the geometric mean is but slight. This renders the arithmetic mean practically valueless. Bacteriological frequency distributions usually possess not only wide variability, but positive skewness. In such cases the geometric mean is more probable than the arithmetic mean, but the most impor- tant reason for preferring the geometric mean is its stability as an average. PHYSICS. — Soft characteristic X-rays from arcs in gases and vapors.^ F. L. MoHLER and Paul D. Foote, Bureau of Standards. If an electron current is maintained by a potential V between a hot cathode and anode in a vapor at low pressure, then as V is increased successive changes occur in the spectrum excited by electron impact. The highest frequency v of each additional group of lines is related to the least potential required to excite the group by the quantum equa- tion Ve = hv. The authors have studied the stages in the discharge by measuring the photo-electric effect of the radiation on two other electrodes en- tirely shielded from ions produced in the arc. This photo-electric current plotted as a function of the exciting voltage shows nearly a linear relation with changes of slope at critical potentials. In this 1 Received June 15, 1921. 274 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 manner potentials have been found which are determined by the limiting frequency of the softest X-ray series of a number of elements. Table 1 gives the observed potentials, and the corresponding wave lengths for these X-rays. Carbon was studied in the compounds CO, COo, C2H4 and CCI4. The latter compound also gave the chlorine points. The nitrogen point was obtained from air and the other points from the various elements at temperatures giving suitable vapor pressures. TABT.T: 1. Soft X-rays from Low -Voltage Arcs. Element Oteerred potentials in volts X in^ Computed A Reinarks a h a b L^ Sodiun '.lagnesiiun Phosphorus Sulphur Chlorine Carbon Nitrogen Potassium 35. 46. 126. 152. 197. 272. 375. 23. 17. 34. 99. 121. 156. 20. 353. 268. 98.0 81.2 62.7 45.4 32.9 536. 726. 363. 126. 102. 79.1 617. 263. 92.2 77.2 61.9 \K series limits 3/ series limits The limits La of the L series for light elements, computed from X-ray spectral data by the relation La = Ka- K^, are included in table 1. A plot of V Vx against atomic number shows that both the observed (column a) and computed points from magnesium to chlorine fall on the same straight line within the probable observational error. The points h for these elements lie on a nearly parallel line. They indicate a new X-ray series of feeble intensity. The value of L^ for sodium falls above the extrapolated straight line but is consistent with Milli- kan's recent observation of the L„ lines as X = 372 and 376A. The K limits found for carbon and nitrogen fall close to the extrapolated Ka line. The carbon point is in fair agreement with the value X = 42.6 A found by Kurth- who observed the radiation from a solid carbon anode. Theories of atomic structure indicate that the potassium points must be related to the M series. The above preliminary results emphasize the value of this method of stud^dng radiations in the region between the range of the vacuum spectroscope and the X-ray crystal spectrometer. 2 Abstract in Phys. Rev. 17: 528. 1921. June 19, 1921 swann: earth's size; and magnetization 275 TERRESTRIAL MAGNETISM.— 7/^(7 bcarmg of the earth's size upon changes in its magnetization ^ W. F. G. Swann, University of Minnesota. H. Lamb- has shown that if a system of currents is started in a sphere of the size of the earth, endowed with a conductivity equal to that of copper at normal temperature, a period of ten million 3'^ears will elapse before the magnetic field becomes reduced to 1/e of its original value as a result of the decay of the currents. The physical reason for this result lies in the very large effect of self induction in a body of the size of the Earth, as compared with the effect of resistance. The purpose of this note is to examine the bearing of this matter upon one or two questions relating to the Earth's magnetism. For the pur- pose in hand, it is unnecessary to give an exact mathematical analysis, and it wdll sufhce to handle the problem in a way which does not claim more than a determination of the orders of magnitude of the elements involved. Such a simplified procedure serves, moreover, to keep the physical principles more prominently to the fore. In the first place, it may be of interest to verify Lamb's result by this method. Decay of currents in a sphere. — If B is the average magnetic flux through a section of the sphere containing the equator of the axis of magnetic flux, the e. m. f . around the equator is ira-dB/dt, so that, con- sidering an equatorial ring of unit cross section and specific resistance p we have : Tta- h27rapz = 0 (l) dt where i is the current density. Now, at each instant, B is of the order of magnitude of the magnetic field at the equator of a sphere of radius a due to a current density which may be taken for convenience as proportional to the distance from the axis, and such as to have the value i on the equator. For this case, it may readily be shownHhat the field at the equator is 4.Tria/\b, so that, as regards order of magnitude, we may write B = 0.25Tria (2) for a sphere of unit permeability. Substituting in (1) we have, as ^ Presented at the Washington meeting of the American Physical Society, April 29-30» 1921. Received May 25, 1921. ^ Quoted by A. Schuster in A critical examination of the causes of terrestrial magnetism. Proc. Phys. Soc. Lond. 24: 124. 1911-1912. 3 See for example, W. F. G. Swann, The Earth's magnetic field, Phil. Mag. (6) 24: 97. 1912. 276 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 regards order of magnitude: ^+ 5£b=o dt ira^ leading to : Putting p = 1.6X10"^ ohm/cm.^ =1.6X10^ e. m. u, for copper, and (2 = 6.5X10^ cm., as corresponding to the radius of the earth, we read- ily find that 7raV8p = 10^'* seconds; so that, for B/Bo=l/e, we have t = 10^* seconds, that is, 3X10^ years, which, in view of the approxima- tions involved, is in sufficiently good agreement with Lamb's result. Case of the destruction of a state of permanent magnetization. — It is usually maintained that the Earth cannot be a permanent magnet on account of the high temperature of its interior. It is interesting to observe, however, that if it had been a permanent magnet originally, the destruction of this magnetization would set up induced currents which would tend to perpetuate the field; and, as will appear, the net result would be that, for a body of the Earth's size, and with the conductivity of copper, about three million years would elapse before the field had sunk to a value 1/e of that prevailing before the magnetization was destroyed. Suppose that B represents the average induction through a great cir- cle of the order of magnitude of the radius of the sphere. Then equation (1) applies as before. Now if B is the induction due to the permanent magnetization, then for a sphere of unit permeability, which it will suffice to consider, i is of the order of magnitude obtained by replacing Bhy B — B in equation (2), that is, B - B = 0.25Wa so that, using (1), we have, as regards order of magnitude, 7ra2— +8piB-B)=0 (3) at Suppose now that the permanent magnetization B decreases according to the law: 5 = ^oe~"' Then, from (3), dB 8p 8p- , — + —,B = -^Boe-'" 4) dt Ta^ ira^ The solution of this equation, subject to B =Bo when f = 0, is: June 19, 1921 swann: earth's size and magnetization 277 1 2£. 1 To fix our ideas, suppose that the permanent magnetization is practically destroyed in a time short compared with ira^/Sp, which, for copper, and for a equal to the radius of the Earth, amounts to 10^^ seconds. Then 8p/ra-a is a small quantity, and we have approxi- mately : 8pt so that, even though the permanent magnetization is destroyed rapidly, the order of magnitude of B will still be So/e after a lapse of 10^^ seconds, or three million years. APPLICATION TO THE SECULAR VARIATION Such evidence as exists with regard to the secular variation appears to indicate that the magnetic poles describe closed curv'^es about the geographic axis with a period of the order of 500 years. The curv^e is possibly accompanied by smaller loops, which need not concern us here, however. Suppose that, as a first approximation, we divide the Earth's mag- netization into two uniform magnetizations, one parallel to and one perpendicular to the geographic axis, and regard the latter as ro- tating, with regard to the earth itself, once in 500 years. We do not know the mechanism of the process; but, it is interesting to inquire as to what would follow by considering it merely as a rotation of a state of permanent magnetization in the above manner. We shall find that the induced currents play a very important part, both as regards their power to almost cancel the effect of the rotating perma- nent magnetization, and also as regards their influence in producing a lag of the resultant magnetization behind the permanent magnetization. If Do refers to the permanent component of magnetization perpen- dicular to the geographic axis, then, on considering the case of^ me- ridian circle, we shall have an equation similar to (4), but with Boe~°' replaced by Do cos 2x^/7, where 2Trt/T represents the angle between the direction of Do and the perpendicular to the plane of the me- ridian circle in question. As regards order of magnitude we thus have : 1 B = — Do cos — - dt tto^ ira^ T The complementary function may be neglected after a sufi&ciently long time, and we shall be left with the particular solution : 278 JOURNAL, OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 Do B = where tan 6 (2^ \ cos \~ t — Q J 4pT There is thus a lag, and a reduction of amplitude in the ratio unity to (i + Tr^aVier^p-)'/^ If T is of the order of 500 years, and p corresponds to copper, this ratio amounts to 0.27 X10~"^. Thus, if the resulting apparent magnetization perpendicular to the geographic axis is to be at all comparable with the permanent magnetization (or its equivalent^) perpendicular to that axis, the internal conductivity of the Earth must be smaller than that of copper at least in the ratio 0.3 XI 0~Ho unity. Of course, there is nothing remarkable in this since presumably nobody would wish to consider the conductivity of the Earth's interior as comparable with that of copper; but it is nevertheless of interest to observe that the period of the secular variation has something to say as regards an upper limit to the conductivity in question. When one pictures the flow of currents left to themselves in a sphere, he is likely, at first sight, to regard resistance as the main in- fluence controlling them. We see, however, that in the case of a large sphere, such currents are more analogous in their behavior to highly frictionless gyroscopes, and the problems of precession, etc., associated with gyroscopic motions naturally invite attention. The pertinence of the above to problems concerning magnetic fields in sun-spots is obvious. PETROLOGY. — Preliminary note on monticellite alnoite from Isle Cadieux, Quebec.'^ N. L. Bowen, Geophysical Laboratory, Carnegie Institution of Washington. The occurrence of alnoite in the vicinity of Montreal, Canada, has been known for some years. The first discovery was made by Adams, - and a paper by Harvie^ describes a number of separate intrusives of this nature. During the past summer Doctor Harvie called to my '' We are not limited to the case of a rotating permanent magnetization as the active agency. Thus we mighc consider a system of e. m. f.'s of unspecified origin, whose effects were to generate currents which would act as the equivalent of the permanent magneti- zation cited. ' Received June 11, 1921. 2 F. D. Adams. Amer. Journ. Sci. (3) 43: 269-279. 1892. ' Robert Harvie. On the origin and relations of the Palaeozoic breccia of the vicinity of Montreal. Trans. Roy. vSoc. Canada. (3) 3: Sect. 4, 249-299. 1909. June 19, 1921 bowen: monticelute alnoite 279 attention the fact that some new occurrences had been found in the course of a road-materials survey of the area which involved, in a petrographic way, merely the identification of the rock as alnoite.'* An examination of one of these occurrences, that at Isle Cadieux, proved it to be of particular interest, and I am greatly indebted to Dr. Harvie and to the Director of the Geological Survey of Canada for the opportunity of making a more detailed study. The rock is on the whole particularly fresh for a rock of this kind and the paragenesis of its minerals unusually clear. A fuller descrip- tion will be given in a paper now in course of preparation which em- bodies also experimental studies designed to throw some light on the mineral relations. In the meantime it was thought desirable to pub- lish a note on the petrography of the rock mass. The greater part of the rock is a fine-grained dark gray mass in which the individual minerals are not distinguishable in the hand specimen except in the case of large poikilitic biotites that are its principle constituent. Under the microscope the rock is seen to consist of biotite, olivine, augite, melilite, perovskite, apatite, titaniferous magnetite, and al- teration products, largely carbonates. It is therefore a typical alnoite but differs from all alnoites as hitherto described in that it contains two olivines, namely, ordinary chrysolite and also monticellite, the latter usually in amounts considerably in excess of the amount of chrysolite. IVIonticellite, biotite, and melilite constitute groundmass minerals and often poikilitically include augite and chrysolite. Plainly a great deal of resorption of augite and chrysolite has occurred, their places being taken by biotite, monticellite and melilite. There is therefore a marked difference between the chrysolite and monticellite in the manner of their occurrence. Not infrequently monticellite forms a reaction rim about chrysolite with the two olivines in optical contin- uity. In such cases the great difference in birefringence is particu- larly clear on account of their uniform orientation. In addition to the different mode of occurrence and the greatly inferior birefringence of the monticellite it is further contrasted with the chrysolite in being plainly optically negative, whereas the chrysolite is just upon the border between the positive and negative members of the forsterite- fayalite series and its sign is therefore doubtful. * Geol. Survey Canada, Summary Rept. 1916: 198-206. 280 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 Only those distinctive features of the two olivines that are readily seen in thin section are given here. Chemical evidence and more detailed optical measurements are available, but await the final paper in which the characters of the other minerals and variations within the mass will be discussed. An analysis of one of the freshest specimens has kindly been made by Dr. H. S. Washington and is given in table 1. TABLE 1. Chemical Analysis of Monticellite Alnoite. Isle Cadieux, Quebec. H. S. Washington analyst. SiOz 33.26 AI2O3 5.90 FeaOs 5.30 FeO 6.54 MgO 26.41 CaO 14.47 NasO 1.23 K2O 0.82 H2O+ 1.91 H2O- 0.09 CO2 1.10 Ti02 2.15 P2O6 0.76 MnO 0.15 Cr203 0.05 BaO 0.08 SO3 0.22 Sum 100.44 This specimen was chosen primarily for its freshness and, while not an uncommon facies, is not altogether representative of the usual type. It contains more melilite than biotite and somewhat more chrysolite than monticellite, whereas these conditions are reversed in the average rock of the mass. If the amounts of CO2 and H2O be taken as criteria, this is the least altered alnoite that has yet been analyzed. Monticellite as an igneous rock mineral. — Monticellite, the lime magnesia olivine, has hitherto been supposed to occur only in contact metamorphic rocks. That it can crystallize directly from melts of the appropriate composition has been shown by Ferguson and Merwin.^ That it has not been found in igneous rocks before is in part due to the fact that natural magmas have usually not been of appropriate com- position and it was not present, but it may also be due to the fact that it has, at times, escaped detection even though present. I have examined a series of slides made from specimens from the original Alno locality. Only one of these is of alnoite (labeled fine-grained alnoite Aldersnaset, Alno^) and in this I find that many of the chryso- lite grains are surrounded by rims of monticellite, always in optical 6Amer. Journ. Sci. (4) 48: 81-123. 1919. « The specimens are the property of Dr. Washington and were collected by Dr. Hog- BOM. A duplicate of this collection is in the U. S. Geological Survey Petrographic Reference Collection, where this rock is No. 1044. June 19, 1921 abstracts: physics 281 continuity. The resorption relation between the two minerals is plain and the monticellite is here again a groundmass mineral, while the chrysolite occurs as resorbed early crystals. It seems not im- probable that other related rocks may contain monticellite and they should be examined carefully with this in mind. It should be noted that monticellite is readily altered, apparently even more readily than melilite, and its presence is to be expected only in the freshest material. Summary. — In this paper monticellite alnoite from Isle Cadieux, Quebec, is described. The rock shows the two olivines chrysolite and monticellite, the latter usually in greater amount. The chrysolite, together with augite, occurs in early formed crystals, while the monti- cellite, as well as melilite and biotite, occur as groundmass minerals that have attacked and resorbed the chrysolite and augite. Monti- cellite often forms reaction rims around chrysolite that are in optical continuity with it. Monticellite alnoite is a newly recognized but not a new rock type, for some of the alnoite of the original type locality is found to hold monticellite showing the same relationships. ABSTRACTS Authors of scientific papers are requested to see that abstracts preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. PHYSICS. — Polarized light in the study of ores and metals. Fred. E. Wright. Proc. Amer. Phil. Soc. 58: 401-447. 1919. In this paper the attempt has been made to present in connected form the electromagnetic theory of the reflection of light from absorbing media, and especially that part of the theory which treats of the reflection phenomena resulting from vertically incident light-waves under the conditions usually encountered in the use of the reflecting or metallographic microscope. Nor- mally incident white light contains, after reflection by an anisotropic sub- stance, a certain amount of plane-polarized light, and this amount increases with the strength of the birefringence and the biabsorption in the crj^stal plate. The presence of plane-polarized light in natural light can be detected by several different methods, such as are used in determinations of sky polarization. For this purpose Koenigsberger adopted the Savart method with rotating glass compensator. A second and new method is proposed which employs either a single calcite cleavage plate with proper aperture or a small portable Koenig-Martens photometer. This method is more sensitive than the first. Methods of this kind, which are based on differences in in- tensity of the reflected components of vertically incident light, are fifty or more times less sensitive in the detection of anisotropism than methods based on the phenomena produced by plane-polarized transmitted light-waves. In case vertically incident, plane-polarized light is used, the difference in amplitude of the reflected components causes a rotation of a plane of polariza- tion, and this can be detected and measured by any one of a number of devices 282 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 in common use by petrologists, such as the sensitive-tint quartz plate, the Biot- Soleil sensitive-tint biplate, the Bertrand eyepiece, and the biquartz- wedge plate. Of these, the last is the most sensitive, because in it the sensibility is variable and can be adjusted to meet the conditions of illumination. In opaque substances the precision attainable by these methods is, in general, small, and the phenomena which can be observed are relatively few and re- stricted in scope. As a result, one can not expect from the application of polarized light to such substances the harvest of optical data which has been gathered from transparent crystals. F. E. W. PHYSICS. — The measurement of the intensity of transmitted and reflected light by polarization photometers. Fred E. Wright. Joum. Opt. Soc. Amer. 2: 65-75. 1919. (Geophysical Lab. Papers on Optical Glass, No. 22a.) In this article a brief statement is given of the methods used by the writer during the war period for the measurement of the light transmission of optical glasses and of optical instruments. Several new attachments and im- provements on the Koenig-Martens photometer are described ; also the method for their use in the practical measurement of the amount of light transmitted and reflected by optical glasses, and of the light transmission of optical instruments. F. E. W. PHYSICS. — Polarization photometer prisms. Fred E. Wright. Journ. Opt. Soc. Amer. 2: 93-96. 1919. (Geophysical Lab. Papers on Opti- cal Glass, No. 226.) In this paper is considered the quantitative effect of external and internal reflections on the intensity of light-waves transmitted by the calcite rhomb and the Wollaston prism, when these are used in photometric work. This discussion is necessary to an adequate understanding of polarization photom- eters and the factors underlying their use. F. E. W. GEOLOGY. — The future of Alaska mining. Alfred H. Brooks. U. S. Geol. Survey Bull. 7 14-A. Pp. 56, pis. 3, fig. 1 . Although many local factors affect the future of Alaska mining, the most important consists of the mineral reserves. An estimate of Alaska's mineral reserves would be difficult enough, even with complete geologic maps. Only twenty per cent of the Territory has been covered by even reconnaissance geologic surveys, and less than one per cent by detailed surveys. The information at hand does not permit of even approximate quantitative estimates of reserves. It indicates, however, the areal distribution of the mineral deposits and a study of their geologic occurrence gives a basis for forecasting their availability to the miner. The wide distribution of placer gold in Alaska and the known occurrence of many gold-bearing quartz veins shows the large areal extent of the auriferous mineralization. Furthermore, the wide distribution of intrusive granites, with which the occurrence of gold is genetically related, augurs well for future discoveries. The Alaska placers have during 40 years of mining produced $218,000,000 worth of gold. A careful consideration of all the facts avail- able indicates that the placer gold reserves have a value of at least $360,000- 000. The Alaska copper deposits are widespread and are found in a number of different modes of occurrence and geologic relations. It is important to note that the Alaska copper deposits thus far developed are primary. The practical deduction from these facts is that no greater variation in the mineral June 19, 1921 proceedings: phiIvOsophical society 283 composition and copper content of the ores is to be expected at depths to be reached by future mining than has already been noted a few feet below the surface. Alaska has produced a total of 272,500 tons of copper. The Alaska coal reserves include enormous quantities of lignite, con- siderable low-grade bituminous coal, and much smaller quantities of high- grade bituminous coal and anthracite. There are many other potential mineral deposits in Alaska in addition to those listed above. Of these, the petroleum fields give the most promise for immediate development. Be- tween 1880 and 1919 Alaska produced mineral wealth to a total value of $438,160,000. A. H. B. ZOOLOGY.— r/ze Echinoderms of the Canadian Arctic Expedition, iqij-i8. Austin H. Clark. Rep. Canadian Arctic Exped. 1913-18, Vol. 8, Part C, Echinoderms. Pp. 11 (IC-llC). The echinoderms, 2024 specimens representing 20 species, secured by the Canadian Arctic Expedition, are herein described and the relationships of the Canadian Arctic fauna are discussed. A. H. C. ZOOLOGY. — Additional data for the Report on Echinoderms of the Canadian Arctic Expedition, based upon specimens from the ''Neptune'' and other Eastern Arctic Expeditions. A. H. Clark. Rep. Canadian Arctic Exped. 1913-18, Vol. 8, Part C, Echinoderms. Pp. 3 (11C-13C). Herein is recorded additional arctic material in the collections of the Victoria Memorial Museum at Ottawa. A. H. C. ZOOLOGY. — Sea-Lilies and Feather -Stars. Austin H. Clark. Smith- sonian Misc. Coll. 72, No. 7, 1-43, pis. 1-16. 1921. This is a semi-popular summary of the present-day knowledge in regard to living crinoids ; it includes a considerable amount of hitherto unpublished information, especially concerning the color of these animals, the extra- ordinary similarity between crinoids and plants, and the conditions of para- sitism under which crinoids live. A. H. C. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 846th meeting The 846th meeting was held in the assembly hall of the Cosmos Club on February 12, 1921. The meeting was called to order by President Faris with 66 persons present. The following program was given : C. LeRoy Meisinger : The meteorological factor in aeronautics (illustrated) . For various reasons the public confidence, the essential factor in business success, has not been acquired in commercial aeronautics, and it behooves enterprises engaged in promoting civil aviation to take advantage of every agency which will help in this direction. Meteorology is such an agency and its application to aeronautics is two-fold: climatological, dealing with average conditions of the elements; and current, dealing with conditions prevailing at the time of flight. The functions of the Weather Bureau in relation to aeronautics are (1) to collect and disseminate observational data; (2) to forecast for specified regions; and (3) to conduct researches. The limitations of the work of the governmental agency are expected to evolve the aeronautical meteor- ologist, privately retained by commercial concerns. His duties will consist 284 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 in (1) the interpretation and detailing of information for specific craft in fiight; (2) the dispatching of craft; (3) the furnishing of information to other departments of the concern; and (4) the instruction of pilots. Governmental activities must be expanded along lines of the collection of aerological information. With this assistance, the general flying weather forecasts will probably keep pace with the development of the demand. The making of upper air pressure maps is the type of research problem of great assistance in forecasting. The status of this problem was discussed. The work of the commercial meteorologist can be surmised by reference to charts of upper air conditions along flying routes. This paper has appeared in full in the Monthly Weather Review. L. H. Adams and E. D. Williamson: The density of strained glass (illus- trated; presented by Mr. Adams.) The stresses existing in "strained" glass are such that in the interior portion of the glass the density is less than that of unstrained (annealed) glass, while in the outer portion it is greater. It can be demonstrated, however, that in any strained piece of glass these two efi"ects exactly neutralize each other, so that the total volume of the piece is unaffected by strain. In order to reconcile this conclusion with the experimental results which always show a smaller density for strained glass when compared with unstrained glass, it is necessary to assume that the apparent diminution of density is due to the formation of bubbles in the interior, where a hydrostatic negative pressure exists. This agrees with the conclusion reached many years ago by Barus that the low density of Prince Rupert's drops is a consequence of the presence of vacuum bubbles. G. T. Rude : The tidal work of the Coast and Geodetic Survey (illustrated) . Tidal work of the Coast and Geodetic Survey had its origin in the necessity for reducing soundings, in hydrographic surveys, for the fall and rise of the tides. The needs of the engineer and mariner have necessitated the extension of the work until now it covers the following fields: Prediction of tides and preparation of annual tide tables; determination of datum planes; develop- ment of instruments for observing and predicting tides; study of mean sea level and its relation to crustal movements; and the study of tidal phenomena in general. The issue of tide tables for the use of the mariner began in 1853 with a condensed table for eight stations for the United States. These tables have increased in size and scope so that now they appear annually, in advance, as a volume of about five hundred pages covering the entire maritime world, with full predictions for each day of the year at eighty-one principal ports and tidal differences for more than thirty-five hundred subsidiary ports. Prior to 1882 the tides were predicted by means of empirical tables and graphs. Beginning with that year the predictions were made on a machine designed by Mr. William Ferrel of the Survey. This machine was essen- tially a maxima and minima machine and in 1910 it was replaced by a new tide-predicting machine designed and constructed in the office of the Survey. On this new machine the height of the tide at any time between high water and low water is indicated, and the time and height of the tide are indicated on the face of the machine, from which they can be recorded directly on forms for the printer. The setting of the machine and the prediction of tides for a full year at any station require about ten hours. It is, of course, out of the question to predict the tides for all ports. To June 19, 1921 proceedings: philosophical society 285 secure the state of the tide at places where no predictions are made, it is cus- tomary to refer such places to some port for which predictions are made. The referring of a subsidiary port to the proper standard port has led to a study of the different types of tides, the principal ones of which are the semi- daily, the daily and the mixed. In the semi-daily tide we have two high and two low waters every day, with morning and afternoon tides very much 'alike. In the daily tide we have only one high and one low water a day. In the mixed type of tide, caused by a combination of the two preceding types, we have two low and two high waters a day, but with differences in duration and height of morning and afternoon tides. In all types of tides we find a variation with the moon's declination. When the declination is small, the forces giving rise to the daily wave are small, and at such times we may have semi-daily tides even at places where the daily is the predominating type. When the declination of the moon is large the daily forces are at a maximum, and we will have even in the semi-daily tide a difference between the morning and afternoon tides. Formerly surveyors and engineers made use of arbitrary or local datum planes. To eliminate the confusion resulting from this practice, which fre- quently made it impossible to correlate the results of recent with the previous surveys, the Coast and Geodetic Survey has been establishing datum planes, based on tidal definition, for the coasts of the United States. The great advantage of the tidal datum plane lies, not only in its simplicity of definition, but also in the certainty with which it may be reestablished at any future time. For practical purposes a tidal plane determined from a series of observations covering a period of a month may be considered as well determined. How- ever, such planes determined at dift'erent times may differ considerably, and for the accurate determination, it is necessary to have long-continued observations at selected representative points. At these principal stations the Survey maintains self-registering tide gauges, which automatically record the height of the tide. Such observations covering a number of years bring out changes in mean sea level and furnish the data for a quantitative deter- mination of relative changes in elevation of land and water. The space allotted permits the covering of only the practical phases of the tidal work of the Survey as they relate to the needs of the engineer and mariner. The theoretical phases, however, as they relate to the development of the theory of tides, have not been neglected. The tidal papers of William Ferrel and R. A. Harris were results of the vSurvey's tidal studies along these lines. The first paper was discussed by Messrs. Sosman, Lloyd and Humphreys. D. L. Hazard, Corresponding Secretary. 847th meeting The 847th meeting was held in the assembly hall of the Cosmos Club on February 26, 1921. The meeting was called to order by President Faris with 41 persons present. The program was as follows: F. Hastings Smyth and Howard S. Roberts: The system cvipric oxide cuprous oxide, oxygen, (illustrated; presented by Mr. Smyth). This system has been studied by several investigators, notably by FooTE and Smith, and L. Wohler has argued rather convincingly that a continuous series of solid solutions exists between the two copper oxides, and that at 286 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 12 any given temperature the oxygen equilibrium pressure is dependent on the composition of the soHd phase. The authors' results show that solid solutions are absent, and that the following reactions may take place in the system: (1) 4CuO(5)-2Cu20(5) + 02(g) -AH, (2) 4CuO(5)^2Cu20(/ solution in CuO) + 02(g) — AH2 (3) 4CuO(/ solution in Cu20)^2Cu20 {s)-\-02{g) — AH3 where AHi, AH2, and AH3 are the heat quantities absorbed in each reaction. At 1080.2 °C and an oxygen equilibrium pressure of 402.3 mm. Hg, a eutectic containing 72.7 mol per cent CU2O and 27.3 mol per cent CuO fuses. Below this point, therefore, Reaction (1) takes place; above this point either Reaction (2) or (3) takes place, dependent upon the quantity of oxygen originally present in the solid and liquid phases. The pressure-temperature curves for these reactions have been traced experimentally up to temperatures of 1085.0°, a metastable point, for Reaction (1); to 1232.5° for Reaction (2); to 1231.3° for Reaction (3). Theoretically the course of these curves, which intersect at the quadruple (eutectic) point of the system can be followed by means of the general equation dp/dt = An/Av w^hich, under conditions of constant temperature and pressure, becomes dp/dt = 1/T.AH/AV AHi remains substantially constant over the temperature range studied. AH2 can be considered as the algebraic sum of AHi and of additional heat absorbed by fusion of CU2O and of additional CuO to form the liquid solution. AH2 is therefore greater than AHi and the value of dp/dt above the eutectic point is always greater than that of the extrapolation of curve for Reaction (1). Likewise A//^ is always less than A//, and the slope of the curve for Reaction (3) is always less than that of the extrapolation of the curve for Re- action (1). The curve for Reaction (2) is tangent to the curve for the condensed system CuO (5), CuO(/) at the melting point of pure CuO; that for Reaction (3) is tangent to the curve for the system Cu20(5), Cu20(/) at the melting point of CU2O. The melting point of pure CuO has not been reached. The melting-point diagram for mixtures of the two copper oxides, under equilibrium pressures of oxygen, has been established throughout the range 94.4 mol per cent CU2O to 45.9 mol per cent CU2O. Lower equilibrium pressures were determined in a fused silica tube reaction chamber with a mercury manometer attached. Higher pressures were de- termined with a furnace enclosed in a brass bomb, and with a caHbrated Bourdon gage. Temperatures were measured by means of a platinum- platinrhodium thermoelement. Purified electrolytic oxygen was used and copper oxides were prepared from previously analyzed chemically pure me- tallic copper. The paper was discussed by W. P. White. F. Wenner, J. S. Martin, and Nyna L. Forman: The electrical resistance of the human body. (Illustrated; presented by Mr. Wenner). Measurements of the electrical resistance of the human body have given results differing among themselves so radically that one seeking information on the subject is led to question either the reliability of the work or the signifi- cance of the values given. The difficulties encountered have had their origin mainly in those portions June 19, 1921 scientific notes and news 287 of the skin through which the test current entered and left the body. The skin not only has a high and uncertain resistance, but in it there are capacity, polarization, and possibly other effects which not only make the measure- ments difficult but largely destroy their significance. It seemed, therefore, that it might be of interest to measure the resistance of some parts of the body not including those portions of the skin through which the test current enters and leaves. To thus limit the parts whose resistance is to be measured, use is made of four connections to the body. Two of these serve to lead the test current to and from the body and two serve to bring the potential dif- ference developed in a particular part of the body, as a result of the test current, to a place where it can be measured. Ordinarily we understand the resistance of a conductor to be the ratio of the drop in potential in it to the current flowing. However, when a conductor has four terminals to which electrical connections can be made, the resistance is understood to be the ratio of the drop in potential between the potential terminals to the current entering and leaving through the current terminals. In either case the potential considered should be only that caused by the cur- rent and not that which may arise in some other way. In some of the measurements the left hand and the left foot were used as a pair of current terminals, and the right hand and right foot as a pair of potential terminals. Electrical connections to the hands and feet were made by placing them in vessels containing a solution of common salt in water. These vessels are either lined with metal, or contain a piece of metal having a fairly large surface. Insulated wires are attached to the pieces of metal or to the metal lining and serve as leads for connecting the body into the cir- cuits used in making the measurements. The resistance of the four-terminal conductor formed in this way is substantially the resistance of the trunk of the body with all the connecting resistances and practically all disturbing influences eliminated. In most cases the resistance has been found to be between 20 and 30 ohms. The paper was discussed by Messrs. Silsbee, White, C. A. Briggs, and others. H. H. Kimball, Recording Secretary. SCIENTIFIC NOTES AND NEWS The following officers were elected at the annual meeting of the Maryland- Virginia-District of Columbia Section of the Mathematical Association of America, held at the drafting hall of the Capitol on May 7 : President, Oscar S. Adams of the Coast and Geodetic Survey; Secretary-Treasurer, G. R. Clements of the U. S. Naval Academy, Annapolis; Member Executive Committee, F. D. Murnaghan of Johns Hopkins University, Baltimore. The National Geographic Society is sending an expedition this summer to explore and study the Pueblo Bonito and Pueblo del Arroyo ruins in the Chaco Canyon of northwestern New Mexico. The expedition will be led by Mr. Neil M. Judd of the U. S. National Museum. Recent accessions in the Division of Plants of the National Museum include 400 specimens from China and New Caledonia, received as an exchange from Mr. G. Bonati of Lure, France; 250 specimens of Chinese plants, collected by Simeon Ten, purchased from the Arnold Arboretum in Boston; and 713 specimens from Quebec, received as an exchange from the College de Longueuil. 288 JOURNAL, OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 12 The semi-annual meeting of the Advisory Committee on Non-Ferrous Alloys was held at the Bureau of Standards on April 20 and was attended by members of the various technical societies representing the non-ferrous industries and also by representatives from the technical services of the War and Na\T Departnients. The subjects discussed included specifications for hard-drawn brass wire for airplane bomb release, rotating bands for pro- jectiles, various aircraft problems related to aluminum alloys, questions concerning the composition of bearing metals, corrosion and etching of metals, and the part played by gases in metals. The new Low Temperature Laboratory of the Bureau of Mines was dedi- cated by Madame CuRiE at 10 a.m. on Saturday, May 21. The National Screw Thread Commission met at the Bureau of Standards on Monday, April 18, and considered the Progress Report recently issued and outlined a program for continuing the work of the Commission. Messrs. L. H. Adams and E. D. Williamson of the Geophysical Laboratory, Carnegie Institution of Washington, have received the Longstreth Medal from the Franklin Institute of Philadelphia in recognition of their work on the annealing of glass. Dr. C. F. Brooks, meteorologist at the Weather Bureau and editor of the Monthly Weather Review, has resigned, effective June 30, to accept the asso- ciate professorship of meteorology and climatology at Clark University, Worcester, Massachusetts. Mr. F. C. Brown of the Bureau of Standards returned in May from a two months' trip to the scientific institutions of England, France, and Germany. A meeting in honor of Madame CuRiE was held at the National Museum on Friday evening. May 20. Dr. Robert A. Millikan of the University of Chicago lectured on Radium. Dr. Frederick B. Power, of the Bureau of Chemistry, was presented with a gold medal by Mr. Henry S. Wellcome, founder of the Wellcome Chemical Research Laboratories of London, "in commemoration of his eighteen and one-half years of service as Director of the Laboratories and in recognition of his many valuable researches in the field of organic chemistry." The pre- sentation took place at the Cosmos Club on May 9. Dr. Edward Bennett Rosa, chief physicist of the Bureau of Standards, died suddenly in his office at the Bureau on May 17, 1921, in his sixtieth year. Dr. Rosa was born at Rogersville, New York, October 4, 1861. After gradu- ation at Wesleyan and Johns Hopkins Universities, he became instructor at the University of Wisconsin, and then professor of physics at Wesleyan. He was appointed chief physicist of the Bureau in 1901. At Wesleyan he developed the physical side of the respiration calorimeter with W. O. AtwaTER. At the Bureau his attention was directed to the determination of the funda- mental electrical units and constants, including the ampere and the electro- magnetic-electrostatic ratio, and also to numerous engineering problems, particularly during the War. During the past three years he had devoted much thought and labor to the problem of the Federal Government's scien- tific personnel and its reclassification by Congress, and his papers on this subject, first published in this Journal^ and widely reprinted, have focussed much public attention upon this important matter. He was a member of the Academy and the Philosophical Society of Washington, as well as of many national scientific and technical organizations. > This Journal 10: 341-382, 53.3-558. 1920. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. U Jin.Y 19, 1921 No. 13 CHEMISTRY. — The evolution of matter ^ Frank WigglESWORTh Clarke, U. S. Geological Survey. During the greater part of the nineteenth century many philosophi- cal chemists held a vague behef that the so-called chemical elements were not distinct entities, but manifestations of one primal form of mat- ter, the proiyle, as it was sometimes termed. Other chemists, more con- servative, looked askance at all such speculations, and held fast to what they regarded as estabHshed facts. To them an element was something distinct from all other kinds of matter, a substance which could neither be decomposed nor transmuted into anything else. One fact, how- ever, they ignored, namely, that the elements were intimately con- nected by many relations, which are best shown in the periodic law of Mendeleeff, who actually predicted the existence of unknown elements which were afterwards discovered. This is ancient history, with which all chemists are now familiar. It became evident to most chemists that the elements must have had some community of origin, for other- wise their relations to one another are unintelligible. In 1873 I ventured to publish the suggestion, ^ based on spectro- scopic evidence and assuming the nebular hypothesis to be true, that the evolution of planets from nebulae had been accompanied by an evolution of the chemical elements. The nebulae are chemically simple, the hotter stars more complex, the cooler stars and the Sun still more so, and the solid Earth the most complicated of all. This was promptly denounced as heresy ; but nearly a year later Lockyer' put forth an analogous suggestion, based upon the same sort of evi- dence, but starting from the other end. That is, he assumed that in the hotter stars some elements were dissociated, and his suggestion was received with a good deal of favor. The heresy was beginning to be orthodox. In course of time the discovery of radioactivity by aecquerel and of radium by Madame Curie established the fact that > Published with the permission of the Director, U. S. Geological Survey. Received June 16, 1921. *F. W. Clarke, Evolution and the spectroscope. Pop. Sci. Mon. January, 1873. 3N. LocKVER, Proc. Roy. Soc. 21: 513. (Paper dated Nov. 20, 1873). 289 290 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 some, at least, of the elements were really unstable. The evolution of helium from radium, discovered by Ramsay and vSoddy, made the evidence for this instability complete ; a derivation of one element from another had actually been observed. These discoveries opened a new field of research; and it was soon found that the elements at the top of the atomic weight scale, namely, uranium and thorium, are spontaneously but slowly decaying, yield- ing more than thirty new substances which differ widely in point of stability. To each one a half -life period is assigned, measured in some cases by thousands of years, in others by fractions of a second. Among these are two new varieties of lead ; one derived from uranium, the other from thorium, which chemically are not distinguishable from ordinary or normal lead except by differences in their atomic weights and their specific gravities. The lead from thorium has an atomic weight about a unit higher, and that from uranium about a unit lower, than the atomic weight of normal lead. To this class of facts I shall refer later, as evidence in support of my arguments. That chemical elements can decay is the essential fact to be remembered. That the chemical elements were formed by a process of evolution from the simplest forms of matter can hardly be doubted now, but the process is not yet ended. They were developed at high temperatures; but when a certain stage was reached in the cooling mass they began to combine with one another to form the new class of substances which are known as compounds. These, obviously, represent an advanced degree of complexity, with corresponding instability; and with vary- ing conditions both combinations and decompositions, such as are reproducible by human agencies, constantly occur. By this extension of the evolutionary process the solid Earth was built up, but in princi- ple the process is the same throughout. From the formation of the first elements to the chemical changes now taking place upon the Earth there is no real interruption. One line of progress has been followed until a maximum of natural complexity and instability is reached in the organic compounds which form the basis of all physical life, whether vegetable or animal. The same fundamental matter, governed by the same fundamental laws, appears from beginning to end of the evolutionary process. Between the formation of an element and the formation of a com- pound there is, however, an apparent difference. The first stage of the process was one which required a vast period of time, the second stage is marked by rapidity. The series of elements was slowly July 19, 1921 clarke : evolution of matter 291 formed, and their rate of decay, as shown between uranium and lead, is also relatively slow. The formation and decomposition of com- pounds, on the other hand, is rapid; and in some cases their rate is measurable. The distinction is not absolutely definite, for some of the short-lived products of radioactive decay seem to be exceptions to the rule, which in general may be stated as follows: The process of evolution is characterized by progressive acceleration, being slow at first, and becoming gradually more and more rapid. Its rate of acceleration may not be uniform but the general drift is clear. It follows the line from the simplest substances to the most complex. In all vital processes the ease and rapidity with which compounds are formed and developed is evident, and some of these substances are extremely complicated. In any attempt to discuss the evolution of the chemical elements we have for guidance some facts and many analogies. That the most complex elements are unstable we have already seen, and it is sus- pected that all the others follow the same rule. Potassium and rubid- ium are feebly radioactive, which is an evidence of instability, and other confirmatory evidence will be cited later. Stability, however, is a relative term, and a substance which is stable under certain con- ditions becomes unstable under others. The prime factors which determine external stability are temperature, pressure, and chemical environment. For example, some compounds which are stable in anhydrous surroundings are decomposed in presence of water. Calcium carbonate, under ordinary conditions, is divided at high temperatures into carbon dioxide and lime, but heated in a steel bomb it not only re- mains undecomposed, but it may even be melted, to form upon cooling a crystalline marble. Examples like these might be multiplied in- definitely. As a rule stability diminishes with increasing temperature, but ,is favored by increased pressure. We may also assume that the more symmetrical an atom or compound is, the more stable it is likely to be. We are dealing now with compounds; but to the evolution of the elements the same general rules must apply. Now, returning to our main problem, was the evolution of the ele- ments a regular progression, such as might be represented by a smooth curve or a straight line ; or was it irregular and quite independent of their order in the scale of atomic weights? To answer this question we must try to imagine what happened in the development of the larger masses, the nebulae and the stars. On this subject there is a plausible hypothesis which has been favored by many astronomers; 292 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 namely that the nebula at first was relatively cool, that the tempera- ture gradually rose to that of the hottest stars, and then regularly de- clined to the end of the series, the solid planet. A gaseous mass, con- tracting under the influence of gravitation, became warmer; at its center where the pressure was greatest, the increasing condensation generated still higher degrees of temperature, until a luminous nucleus was formed. As condensation went on with increasing intensities of pressure, the temperature continued to rise until the heat generated by compression was less than that lost by radiation into space, when cooling began. Although this hypothesis, in its crude form, is not universally accepted, it nevertheless gives a fair conception of that part of the evidence with which we are now concerned. The process of evolution from cool to hot and then to cool again is fairly outlined. The nucleus of the original nebula has its modern representative in the Sun. In all the foregoing discussion it has been tacitly assumed that the nebula from which the solar system was developed was similar in all essential respects to the planetary nebulae. The latter, as shown by their spectra, consist mainly of hydrogen, helium, andnebulium, with slight traces in some of them of carbon, nitrogen, and perhaps other elements. NebuHum is known only from its lines in the spectrum, and its atomic weight has been estimated by Fabry and Buisson as 2.7, placing it between hydrogen and helium. In any further study of relations between the atomic weights of the elements, nebulium must be taken into account, and perhaps also coronium, so called from its lines in the spectrum of the solar corona. From its position in the corona it is assumed to be lighter than hydrogen, and so would seem to be an even more primitive element. That possibility cannot be con- sidered here; we must limit ourselves to the conditions actually seen in the nebulae. No assumption is made as to the possible ancestry of the nebular elements. They are the visible beginnings. Now it is easy to see that in the process of evolution from nebula to sun an orderly development of the elements could hardly have been possible. With changing temperatures, changing pressures, and changing environments all the conditions required for a regular pro- gression according to the order of the atomic weights were lacking. The order actually followed was that of relative stability. In the hotter stars only the most stable elements were formed, and naturally in the greatest abundance. Calcium (atomic weight 40) and iron (atomic weight 56) were among the earliest to appear, while the others, July 19, 1921 . clarke : evolution of matter 293 between helium (atomic weight 4) and iron, either came later or were developed at first in smaller quantities. As cooling went on more and more elements were generated, and in the Sun all the possible ones are presumably present. It is conceivable that elements of different stability may have been formed simultaneously, one in that part of the cooling mass where temperatures and pressures were highest, another further away from the center under less rigorous conditions. This, however, is something which cannot be proved. If the three nebular elements were the raw material from which the other elements were built, their relative amounts must have been continually chang- ing, and so as each new element appeared a new environment was established for all that followed. How far these changes may have affected the evolution of the elements it is impossible to say, but in the evolution of compounds similar conditions would be significant. That some of the chemical elements are very abundant, and others comparatively scarce, is a familiar fact which bears directly upon the theory of evolution. Their relative abundance in known terrestrial matter has been repeatedly computed, by several workers and by different methods. The results agree remarkably well, at least in the orders of magnitude as expressed in percentages. This order, when we combine the figures for the lithosphere, the ocean, and the atmos- phere, is as follows. First, oxygen, then silicon, aluminum, iron, calcium, sodium, potassium, hydrogen, and titanium, and these ten elements form at least 98 per cent of the whole. Only 2 per cent remains for all the other elements, some 80 or more in number."* For present purposes this estimate is obviously defective, for it covers hardly more than a thin film on the surface of the Earth and says nothing about the Earth's interior. This objection is easily met if we take three facts into consideration. The Earth behaves like a huge magnet, it resembles a huge meteorite, and its mean density is double that of the rocks forming its crust. From these facts, and other quite minor considerations which need not be discussed here, we may fairly assume that the interior of the Earth contains a large propor- tion of metallic iron, and the quantity of it needed to give with the crust the mean density of the globe can be calculated. This has been done by others, and it now appears that in the Earth as a whole, iron predominates, oxygen and hydrogen fall to subordinate positions while the order of the other elements is little changed. Probably *The details of the most recent computation of the relative abundance of the elements will appear in a joint paper by Dr. H. S. Washington and myself, which is in course of preparation. 294 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 nickel would appear among the first ten elements, but such a change will not affect our argument. Ten or eleven elements, all below 59 in atomic weight, exceed in abundance all the others. They are structurally among the simplest elements, and therefore, presumably the most stable. These conclusions may now be applied to the hypothesis of evolu- tion. The total amount of matter in the original nebula was of course finite; a large part of it was absorbed in building the simpler and more stable elements, and only what remained was available for the development of all the others. This conclusion, I admit, is largely speculative, but it is a legitimate interpretation of evidence. It may be modified by future investigations, but it is not likely to be completely overthrown. It is possible that the relative abundance of the elements may be different in different parts of the solar system, but it is not probable that any of the higher elements can find a place among the first ten. The whole scheme of evolution may be figured diagrammatically as a series of waves in which the crests repre- sent the elements, and the depressions the gaps between them. In such a series the waves would reach their greatest height at iron, and then gradually flatten until the end where instability becomes most clearly evident. Between the evolution of the elements and their degradation there is a sharp contrast. The two processes do not follow the same path. Uranium does not decay to thorium, that to radium, then to lead, and so on down the line. The same divergence is shown between the synthesis and decomposition of compounds. It would be easy, for example, to effect a direct synthesis of calcium carbonate from its elements ; but to reverse the process without the intervention of other substances would be extremely difficult. To cite a different example, trinitrotoluene, the T.N.T. of recent warfare, is prepared by the action of nitric acid on toluene, a relatively slow operation. On the other hand, when T.N.T. decomposes it does so instantaneously, and the products are oxides of carbon, methane, water, and free nitrogen. Something like this happens in the decay of a radioactive element, but with a difference; uranium, thorium or radium decom- poses atom by atom; T.N.T. flies to pieces in mass. The one process is slow, the other extremely rapid. I have already specified the external conditions which determine the stability of an element or compound, but when we consider the atom by itself, internal conditions are more important. On the July 19, 1921 clarke: evolution of matter 295 structure of atoms there is not as yet a complete agreement, and much remains to be done before the problem can be definitely solved. I cannot go into this subject in detail, but I may take it for granted that the conception of an atom as consisting of an electropositive nucleus attended by few or many electrons of opposite sign, is well established. In such a structure symmetry would be conducive to stability, and any deficiency in that respect would be unfavorable. For a simple element, with few electrons, symmetry would be most easily attained, for a complex element with many electrons it would be more difficult. Furthermore, an atom to be stable must show an exact balance between the electropositive and electronegative charges. With a single ring or shell of electrons the force of attraction holding nucleus and electrons together should be strongest; with concentric rings of electrons the outer ones would be more loosely held, and the atomic structure should be weaker. This seems to be the case with uranium and its neighbors. Here the structures are the most com- plex, and the number of electrons greatest. In short, the conditions, internal and external, which determine stability are by no means simple, and some of them operate in opposite directions. They all agree, however, in favoring the evolution of the simpler elements and so render the fact of their greater abundance more intelligible. When an atom of uranium decays, an alpha particle, which is an atom of helium, is first discharged, and with a very high velocity. By a succession of such discharges a series of products is generated, each one differing by four units in atomic weight from its predecessor. The atomic weight of helium is 4. Three of these products, omitting intermediate forms, are ionium, radium, and an "isotope" of lead. Ionium is isotopic with thorium, but not identical with it except in its purely chemical relations. The atomic weights are not the same. A similar difference is found for the lead derived from radium, which differs from normal lead in having an atomic weight about a unit lower. The isotope of lead in the thorium series differs from the normal by about the same amount in the opposite direction.-' In short, the degradation path from uranium, and also that from thorium is approximately parallel to the path of evolution, but not identical with it. The short-lived products of radioactive decay might be described as the debris of exploding atoms. They do not appear in the ascending series of the elements. *For a discussion of the nature of isotopic lead see Clarke, Proc. Nat. Acad. Sci. 4 181. 1918. 296 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 For the elements below the radioactive group, that is, those of lower atomic weight, some evidence of instability has recently been obtained. Rutherford, by passing swiftly moving alpha rays through nitrogen, has observ^ed a slight evolution of hydrogen, an indication that hydrogen is a constituent of the heavier and more complex element. Oxygen, treated in the same way, yields a product of different character, something which appears to have an atomic weight near 3. If, however, the value should be slightly lower, it would have a curious significance. Attention has already been called to the existence of nebulium, to which the atomic weight 2.7 has been provisionally assigned. This is very close to 2.666..., or 2 ^/a more precisely. Now 2 Vs X 6 = 16, the atomic weight of oxygen, a relation which may possibly be experimentally verified. If the bombardment of oxygen were carried on for a long time it might yield a gas in which the spectral lines of nebulium could be detected ; and if that were done it would be a step forward in the study of the atoms. I offer this suggestion with some hesitation, but it seems to be worth con- sidering. It affects a number of other elements of which the atomic weights are multiples of 16. By a remarkable series of experiments F. W. Aston^ has obtained evidence which he regards as proof of the complexity of the atomic weights as determined by chemical methods. Powerful positive rays in a magnetic field were applied to a number of elements, which then gave what he terms their "mass spectra." These spectra show lines corresponding to whole number atomic weights, which represent, not the accepted values, but some higher and some lower. Chlorine gives two such lines, corresponding to atomic weights 35 and 37, and mercury gives at least six, ranging from 197 to 204. The last two figures, I may add, are near the atomic weights of gold and thal- lium, that of mercury being 200.6. These new lines, as interpreted by Aston, represent isotopes, and the accepted atomic weights are regarded as mere statistical averages. In other words the atomic weights known to chemistry relate to mixtures, and are not true constants. I must here allow myself to indulge in a very obvious truism. Whenever new phenomena are discovered an attempt is made to interpret them, and to bring them into relations with other phenomena. i 'Science Progress 15:212. 1920. July 19, 1921 clarke : evolution of matter 297 But it does not always follow that the first interpretation is the only- one possible, nor even that it is the best. Now it seems to me con- ceivable, that the lines of Aston's mass spectra may really belong to decomposition products of the elements, produced by the disinte- grating effect of the positive rays. This conclusion, I think, is more in harmony with chemical evidence than the one first proposed. It is, furthermore, sustained by the fact that the elements of high atomic weight seem to show as a rule more lines in their mass spectra than those low in the scale. The most complex elements should undergo the largest amount of disintegration. If the atomic weights as actually determined by the best modern methods are mere statistical averages of widely differing figures, then the elements must be re- garded as variable mixtures, and uniformity could hardly be expected. This lack of uniformity would extend to all chemical compounds, which should vary in composition and also in physical properties; all chemical calculations would become inexact, and even the spectra of the elements would lose much of their significance. Chaos would rule instead of order. In point of fact the evidence in favor of definiteness of atomic weight is much better than anything which has been adduced to the contrary. On that subject I could make a strong argument in support of my position; but I do not care to overload this paper with details. In discussing the evolution of the elements, and also their decay, I must take a pragmatic position and assume their integrity. Their evolution follows an upward path, with which the downward path of decomposition is approximately but not exactly parallel. The two paths, however, coalesce in the region of hydrogen, nebulium, and helium; and so the beginning and the end are the same. That hydrogen and helium are the chief constituents of the elements as we know them is possible, as Harkins in a long series of interesting papers has attempted to show. I cannot accept all his conclusions as final, although he has at least discovered some interesting rela- tions. Nebulium should not be left out of account. On the mechanism of the process by which the elements were built up I have nothing definite to say. I can only ask questions. If a heavy atom, like that of gold or mercury, is formed from simpler atoms, how are the latter changed? What happens to their nuclei and their electrons? Is the structure of the carbon atom the same in graphite and in diamond? Here the tetrahedral atom which plays so important a part in stereochemistry has to be considered. 298 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 With compounds these problems become much more complicated, that is, if we try to explain them in terms of atomic structure. Among organic compounds we find isomers and polymers, and many of them contain a hundred or more atoms to the molecule. How are their electrons rearranged, and what are they doing? All of these com- pounds, as I have already shown, are items in the general scheme of the evolution of matter, in which the question of atomic structure is fundamental. I have in this paper only touched the surface of a vast general problem, but my imagination has never wandered far from evidence and reasonable analogies. Perhaps I have made suggestions which may lead others to the discovery of new truths. MINERALOGY. — On galenobismutite from a gold-quartz vein in Boise County, Idaho. '^ Earl V. Shannon, Department of Geology,. United States. National Museum. (Communicated by E. T. Wherry). The mineral galenobismutite, first described by Sjogren from the Ko Mine, Nordmark, Sweden^ has not heretofore been definitely identified at any second locality. The material from Fahlun, Sweden, described by Atterberg^ contains more selenium than sulfur and is doubtless either a mixture or a variety of weibullite or platynite. It is listed as a distinct species by Hintze'' under the name "selenblei- wismuthglanz."^ Alaskaite, included by Dana under galenobismutite, is regarded by Hintze and also by Wherry and Foshag as a distinct species.^ The lead sulfo-bismuthite from the tungsten veins of Deer Park, Washington, analyzed by R. C. Wells and described by Bancroft^ as intermediate between galenobismutite and cosalite is quite probably distinct from either. It thus appears that galenobismutite, properly so-called, is an exceedingly rare mineral. For this reason it becomes of interest to note that this mineral occurs as a constituent of a gold ore from Idaho preserved in the United States National Museum. 'Published by permission of the Secretary of the Smithsonian Institution. Received May 25, 192L ' H. Sjogren. Geol. Foren. Forh. 4: 109. 1878. 3 Atterberg. Geol. Foren. Forh. 2: 76. 1874. * C. HiNTZE. Handbuch der Mineralogie, 1: 1012. * E. T. Wherry and W. F. Foshag. A new classification of the sulfo-salt minerals. This Journal 11: 1-8. 1921. * HowLAND Bancroft. Notes on tungsten deposits near Deer Park, Washington. U. S.- Geol. Survey Bull. 430: 216. 1910. July 19, 1921 shannon: galenobismutite; 299 The specimen was collected by Edward L. Jones, Jr., of the U. S. Geological Survey and is included in an unstudied collection of ores from southern Idaho. The label gives as the field number SI- 106, and as the locality, Belzazzar Mine dump, Quartzburg district. The specimen was collected September 15, 1915. Regarding the Belzazzar Mine, Lindgren states that it is located on the Fall Creek side and has been opened by sluicing and a tunnel, 200 feet below the summit. Bodies of heavy sulfurets, chiefly pyrite, are exposed along the vein. The western part of the vein lies in hornblende porphyrite, while the eastern end has granite in the footwall and the same porphyrite in the hanging wall.^ Bell gives the location of the mine as near the Jerusalem Valley road, a little west of Quartzburg.^ He states that the ore is merely an altered phase of the enclosing rock traversed by quartz seams. The ore was free-milling on the first and second levels and produced fine specimens of free gold. The third level, however, showed considerable amounts of sulfides and only half of the gold in this sulfide ore was recoverable by amalgamation. The ore is said to average from $8.00 to $12.00 per ton. The specimen which contains the galenobismutite consists in the main of translucent to transparent crystalline white vein quartz. The sequence of deposition of the minerals is not entirely clear but there is a band of more or less pure pyrite adjacent to the wall of the vein and this pyrite appears to be the earliest mineral of the ore. The quartz is slightly sheeted parallel to the vein wall, small grains of pyrite being distributed along the partings. Pyrite occurs also in crystalline grains through the quartz and also as sharply bounded cubic crystals in greatly sericitized fragments of wall rock which occur in the quartz. The quartz is loose textured and contains small angular cavities be- tween the crystals. The galenobismutite occurs interstitially with re- lation to the quartz crystals and projects as fibrous bundles of pris- matic needles into the cavities. It is clearly the youngest mineral of the vein, the common paragenetic position of the majority of the lead sulfo-salts. The galenobismutite is rather light gray in color and tarnishes to a yellowish color. Its luster is rather more brilliant than that of the antimonial sulfo-salts of lead, and the mineral greatly resembles bismuthinite in general appearance. It forms elongated prisms im- 'Waldemar Lindgren. Mining Districts of the Idaho Basin and Boise Ridge, Idaho. U. S. Geol. Survey. Ann. Rept.18, Pt. Ill: 690. 1896-97. * Robert N. Bell. Rept. Idaho State Inspector of Mines for 1905, p. 33. 300 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 bedded in quartz or minute, deeply striated crystals in open cavities. The streak is black on porcelain or brownish black when rubbed very thin with a glass rod. The hardness is about 2.5. Material for analysis was secured free from impurities other than quartz and a little pyrite, both of which remained unattacked when the mineral was dissolved in hydrochloric acid. The ma- terial was found to be free from other impurities by examination of polished surfaces under the miscroscope. Standard methods of analysis were used, the bismuth and lead being separated by the basic nitrate method. It is noteworthy, however, that this method, which is the one recommended by most textbooks, is one which gives satisfactory results only when performed with extreme care. The major separation was accomplished by precipitating the bismuth by means of hydrogen sulfide in strongly acid solution, the precipitate being almost free from lead while very little bismuth remained in solution. The separation by the basic nitrate method was repeated several times on each pro- duct of this separation before these two metals were obtained free from each other. The material available for analysis was too small to permit sulfur to be determined. The results of the analysis, recalcu- lated after deducting gangue, are given in table 1. TABLE 1. Analysis of Galenobismutite from Idaho Per cent Calculation of Ratios Lead Pb 23.93 0.1155 Iron Fe .39 0.0057 1434 1.03 X Copper Cu 1.73 0.0272 Antimony Bismuth Sb 2.56 53.59 0.0213 0.2576, 2789 1.00 X Sulfur (calculated) S 17.80 0.5550 5550 1.00 X Total _ 100.00 The formula thus derived is: Pb Bi2 S4 or PbS.BisSs. The copper, iron, and antimony, while present in minor amount, merit note, f Copper and iron while probably not entirely isomorphous with lead, can perhaps enter into solid solutions in limited amount, the copper in all probability being in the cupric state. It is possibly sig- nificant that copper and iron are molecularly roughly equivalent to the antimony and may be combined with it. Such an amount of cop- per and iron compounds might conceivably be present as submicro- scopic inclusions in the galenobismutite. July 19, 1921 blake: ichthyothere 301 BOTANY. — A remarkable new species c/ Ichthyothere.' S. F. Blake, Bureau of Plant Industry. The genus Ichthyothere of the Asteraceae is of some economic im- portance among the native tribes of South America, since the bruised leaves and stems, placed in water, possess the property of stupefying fish and rendering them easy to capture. This property is shared with the closely allied genus Clibadium and with many other genera of various families, among which the Fabaceae and Sapindaceae are conspicuous. Ichthyothere itself, as at present constituted, contains about a dozen species, all South American. All are low herbs or suffrutes- cent, with the few small whitish discoid heads in close clusters at the tips of the stems. In most species the heads are sessile, but in a few they are distinctly pedicellate. While engaged in the preparation of a key to the species, I found in the National Herbarium a specimen from Colombia, doubtfully referred to this genus, and differing from all the species hitherto described in its loosely racemose-panicled heads and climbing habit. Through the courtesy of Dr. F. W. Pennell, the collector, I have had for study the more complete specimen of the same collection in the New York Botanical Garden. Detailed comparison with specimens of Ichthyothere terminalis (Spreng.) Blake, ^ the type of the genus, shows that its differences in habit and inflorescence are not associated with any important difference in technical characters, and, although so distinct in appearance, the plant is best considered a species of Ichthyothere. It may be recognized by figure 1 and by the following description. / Ichthyothere scandens Blake, sp. nov. Shrubby vine; stems slender, branching, obscurely sordid-pilose with appressed hairs, glabrescent: leaves opposite; petioles slender, sparsely sordid-pubescent, 3 to 10 ram. long: blades ovate or lance ovate, 7 to 11 cm. long, 2 to 4.5 cm. wide, falcate-acuminate, at base acute or acuminate, finely serrulate, membranaceous, green on both sides, sparsely sordid-pubescent on the veins, glabrescent, tripli- or quintuplinerved ; panicles axillary and terminal, very loose, dichotomous, obscurely puberulous, 16 cm. long or less; bracts minute, about 1.5 mm. long; heads loosely racemose along the branches, on pedicels about 4 ram. long, cpmpressed, 4.5 rara. high, 5.5 mm. wide in fruit; outer phyllaries 5, subulate-triangular, coriaceous-herbaceous, 'Received May 31, 1921. ^Rolandra terminalis Spreng. Syst. Pi. 3: 673. 1826, fide BAKER in Mart. FI. Bras. 6': 154. 1884. Ichthyothere cunabi Mart, in Buchn. Rep. Pharm. 35: 195. 1830. For full synonymy see Baker, loc. cit. 302 JOURNAL OP THE WASHINGTON ACADEMY OP SCIENCES VOL. 11, NO. 13 Fig. 1. Ichthy other e scandens Blake, a, branch, X 1/2; b, head, X 5; c, receptacle and pales, X 5; d, phyllary subtending female flower, X 5; e, achene, X 5;/, disk flower, X 5; g, stamens, X 5; A, disk flower with corolla and stamens removed, showing ovary, gland surrounding base of style, and style, X 5. July 10, 1921 eckhardt and karcher : radio recorder 303 ciliate, 1 mm. long; inner phyllaries (subtending the female flowers) 2, ob- ovoid, subherbaceous with thin margin, obtuse, glabrous, many-nerved, 5.5 mm. long; receptacle stipitate, bearing nine hermaphroditf sterile flowers; female flowers 2, their corollas tubular, annulate-pilose at apex, very short; corolla of the hermaphrodite flowers tubular-funnel form, greenish-white, 1.8 mm. long; achenesobovoid-turbinate, thick but somewhat obcompressed, trun- cate, about S-ribbed, glabrous, 4.2 mm. long; pales of the disk suborbicular- cuneate to (inner) cuneate, glabrous, truncate or rounded, many-nerved with thinner apex, 2 to 3 mm. long. Type in the U. S. National Herbarium, no. 1042822, collected in forest at Libano, Department of Tolima, Colombia, altitude 1100 to 1300 meters, December 26-29, 1917, by F. W. Pennell (no. 3430). Duplicate in the herbarium of the New York Botanical Garden. Although in all its technical characters this species is clearly a member of the genus Ichthyothere, it is very distinct from all the previously known species in its scandent habit and its very loose inflorescence. RADIOTELEGRAPHY. — A chronographic recorder of radio time sig- nals ^ E. A. Eckhardt and J. C. Karcher, Bureau of Standards. (Communicated by S. W. Stratton). The problem of recording radio signals is one of amplifying the fee- ble energy in the radio signal to such a degree that in the amplified amount it is sufficient to operate a recording device. Whether the recording be done photographically or by means of some form of stylus, the electrical energy of the radio signal at some stage of the process gives rise to a mechanical motion. The aim of the experi- menter is to make the chain of events between the receiving antenna and the mechanically moving element, as well as the apparatus em- bodying it, as simple and reliable as possible. If it is desired to use the recording apparatus in field service these considerations are es- pecially important. Ruggedness then becomes an additional im- perative requirement. The recording apparatus described in this paper was intended primarily for field use, since with it the U. S. Coast and Geodetic Survey wishes to record Annapolis time signals at any field station which it may desire to occupy within the borders of the United States. So far as we know, success in recording radio signals at long range has heretofore been attained only by the use of amplifiers of many stages. Despite the great progress which has been made in the de- sign and construction of such devices, a field party, which needs to give considerable attention to the weight of its equipment and which in general is not accompanied by a qualified radio engineer, will not ' Presented before the Philosophical Society of Washington, March 26, 1921 . Received May 5, 1921. 304 JOURNAL OF THE WASHINGTON ACADSMY OF SCIENCES VOL. 11, NO. 13 contemplate their use with any degree of confidence. When a multi- plicity of electron tubes is used the storage battery equipment pre- sents a serious problem to the field party. Either the battery must be of large capacity or provision must be made for frequent charging. If, therefore, any radio receiver-recorder is to be available for service in the field, keeping the number of tubes down to a minimum is an important consideration. The nucleus of our receiver-recorder is the regenerative circuit shown in figure 1. It consists of a capacity Ci and inductance Li in the grid circuit of the electron tube, the inductance Li being coupled to the in- ductance Li in the plate circuit of the tube. In order that the circuit may be regenerative the coupling must be of such sign that a rise in plate cur- rent results in a rise in the grid pot- ential. The potentiometer P serves to adjust the mean grid potential over a suitable potential range, both nega- tive and positive. Such a circuit is capable of acting as a generator of electrical oscillations. The frequency is determined in the main by the inductance capacity combination If, by adjusting the potentiometer P, Fig. 1. Regenerative circuit. t^g gj-id potential is gradually made more and more negative, the oscillations are stopped. Upon grad- ually raising the potential it will be found that there is a critical grid potential at which the oscillations set in. This grid potential is characteristic for the circuit used. Figure 2 shows a plate current-grid potential, characteristic of a typical receiver type electron tube. If the grid be at a mean potential corresponding to the point Cr and an alternating e.m.f. be applied to it, the increase of plate current during the positive half of the cycle will be greater than the decrease during the negative half. This is due to the curvature of the characteristic. Thus the mean value of the plate current is increased by the periodic e.m.f. on the grid. If C^ is the critical point on the characteristic at which the circuit becomes self -oscillatory, the amplitude of the periodic component of the grid potential builds up ; Hkewise the amplitude of the periodic plate cur- July 19, 1921 eckhardt and karcher: radio recorder 305 rent, and there results a rise in the mean plate current as shown by figure 2. By proper design, conditions may be so chosen that the rise in plate current occasioned by the initiation of oscillations in the regenerative circuit is many times the plate current flowing just be- Fig. 2. Growth of current in a regenerative circuit. fore the oscillations set in. Regenerative circuits have been operated by us in which the plate current shoots up from 2 or 3 milHamperes to 50 milHamperes when by raising the grid potential a small fraction of a volt the circuit is made to pass from the non-oscillatory to the oscillatory state. In our recorder the rise is from approximately V* 306 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13" milliampere in the non-oscillatory to 2 milliamperes in the oscillatory state. The rise in mean plate current which accompanies the starting of the oscillations is an important feature from the point of view of re- cording radio signals. An ordinary telegraph relay which will operate on one or two milliamperes may be introduced into the plate cir- cuit. The starting of the oscillations will cause the relay to function and the relay contact may be used either to open or close a local circuit. If the local circuit is one operating a chronographic pen the starting of the oscillations may be chronographically recorded. Now the change in grid potential necessary to pass from the nonoscillatory to the oscillatory state is very small, so small indeed that it may be provided by a radio signal re- ceived on an antenna suitably connected to the grid of the electron tube of the regenera- tive circuit. Figure 3 shows a suitable arrangement for this purpose. The antenna leads to the tuned circuit which is connected to the grid of the tube through the potentio- meter. The inductance of Fig. 3. Radio recording receiver. this tuned cirCUit is COUpled regeneratively with an inductance in the plate circuit. The function of the intervening coil we shall consider presently. The os- cillations due to the incoming radio signal cause the grid potential to vary periodically about its mean value. If this mean value is just below the critical one peculiar to the regenerative circuit the incoming signal will cause the critical value to be reached, and local oscillations will be initiated. Unfortunately, however, the local oscillations per- sist even after the mean grid potential has been restored to its orig- inal value below the critical one. To stop these oscillations by chang- ing the grid potential it would have to be lowered considerably below the critical value. We are, therefore, thus far possessed of the means July 19, 1921 eckhardt and karcher: radio recorder 307 for setting up local oscillations by the incoming signal, but the instru- ment does not automatically reset itself. Means must be provided for killing the local oscillations as soon as the periodic potential variation of the grid has ceased,^ e., when no signal is being received. For this purpose the telegraph relay in the plate cir- cuit is provided with a second contact, insulated from the first, which I PE^ 3 Morm a. //y C/osed Vp pr — npor U I I I ffad/o ^ (J aerated Re/au f- Differentia.lly iVounti Pan OB»f<^fina Maonlt ffelcL i A/or-ma/Zy Oaen 3rea.A -Ci rcuit Chronome^r. Fig. 4. is closed when the relay armature is attracted by the relay magnet. The closing of this rear contact short-circuits a low resistance coil of a few turns mounted between the regenerating coils. When short- circuited, this coil provides an effective screen between the grid and plate inductances and regeneration is promptly stopped. The stop- ping of the local oscillations occasions a decrease in the plate current, the relay armature is released and the oscillation-stopping contact is opened. If the potential oscillations of the grid still persist as the ar- mature is leaving the rear contact the local oscillations will immediately build up, the mean plate current will rise, and the relay armature will be 308 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 attracted to the relay magnet before it gets far enough away to make the outer, pen-controlHng, contact. Thus, during a long dash signal the relay armature simply chatters against the rear contact, without at any time moving far enough to make the outer one. It is clear, there- fore, that during the arrival of the signal the relay armature is chat- tering against the rear contact and between signals it rests against the front one. Figure 4 shows the front contact of the telegraph relay normally held closed by the tension spring. The starting of local oscillations causes the relay to operate in the manner previously described, the front contact opens and the rear one closes. The opening of the front contact operates the chronograph pen, and the closing of the rear one short-circuits the oscillation-choking coil. The making of the rear contact, therefore, stops the oscillations, causes the plate cur- rent to fall back to the non-oscillatory value, the relay to release and the front contact to close. If a continuous dash signal is being received the local oscillations build up as soon as the relay armature leaves the rear contact, and it is drawn back before the front contact is remade. Thus the chrono- graph pen continues in the released position until the signal stops long enough for the relay armature to remake the front contact. With no signal coming in, the front contact of the relay is closed and the chronograph magnet is energized. The pen-carrying armature is, therefore, held against the inner stop. When the incoming signal begins, the front contact is opened, the chronograph magnet is de- energized and the pen-carrying armature is released against the outer stop. It remains against the outer stop until the front contact of the plate circuit relay is again made. The pen then returns to its initial position against the inner stop. In the recorder design now in use, a single stage of radio frequency amplification is provided so that the signal oscillations may be ampli- fied before being applied to the grid of the tube in the regenerative circuit. This preliminary stage of amplification increases the over- all sensitivity somewhat, but the regenerative circuit itself and the manner of its use account for all but a few per cent of the total sensi- tivity attained. The preceding account describes a complete mechanism for recording radio signals. A similar recording system has recently been described by Captain L. B. Turner-. His methods of stopping the local oscil- 2 The Electrician 83: 4. July 1919. July 19, 1921 eckhardt and karcher: radio recorder 309- lations involve readjustments in the regenerative circuit when the oscillation-stopping contact is opened. If, for example, the plate inductance is short-circuited for the purpose of stopping the local oscil- lations, the removal of the short involves reestablishment of a dif- ference of potential at the terminals of this coil. This causes a surge which tends to restart the oscillations and results in the recording of a spurious signal. The method employed by us of stopping the oscilla- tions involves no readjustments in the regenerative circuit when the oscillation-destroying contact is opened and the system is restored ta the receptive state. We are, therefore, enabled to work very much nearer the critical grid potential with correspondingly enhanced sensi- tivity. It is proposed to use the radio- time recorder for the determination of the longitude of any station. This may be done by comparing in turn the local time ascertained by star observations and the radio- time signal from a known longitude with a local chronometer. It is,, therefore, necessary to make sim- ultaneous records on a chrono- graphic drum of 1. Local star transits against local chronometer. 2. Radio time signals against local chronometer. From the data thus obtained,, the longitude of the unknown station may be computed with re- ference to that of the radio time signal sending station. RrCO/?D/Ne ELEMENT SAMPLE RECORD Fig. 5. Circuit recording element. It is obviously desirable to have the same lag in the recording appar- atus for both signals. If, therefore, both can be recorded by means of the same mechanical system, i.e., with the same pen, a serious cause of difference in lag has been eHminated. How this has been accom- plished is illustrated in figure 5. The pen-operating magnet is differ- entially wound with two coils of approximately equal resistance and equal number of turns. The break-circuit chronometer operates a relay similar to that in the radio recieving-recording set. The clock- 310 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 controlled relay energizes one of the pen magnet coils during the brief period of the clock break. If the pen is in the released position dur- ing the clock break the pen magnet is momentarily magnetized and the pen is momentarily moved against the inner stop. If the pen is in the attracted position the clock break will serve to demagnetize the pen magnet momentarily and the pen will be released against the outer stop during the break. The pen will record the clock break, there- fore, no matter what its status with reference to the radio signal. When star transits are to be recorded simultaneously with a local chronometer, the pen magnet winding previously utilized for the re- cording of the radio signals may be included in a local signaling cir- cuit. The tapping of the signal key then operates in a manner sim- ilar to the starting of a radio signal. Oscillographic study of the performance of a regenerative circuit with a telegraph relay with double contact in the plate arm and with the screening coil for stopping the regeneration, has shown that the oscillations are started and stopped well within 0.001 second. Figure 5 shows clearly that on the one hand we have a chain consisting of antenna — relay — pen circuit — pen, and on the other, chronometer — relay — pen circuit — pen. The two relays are similar and their re- action times are less than 0.001 second. Their difference will be considerably smaller than this amount. The pen circuits are also sim- ilar, and finally the pen is identical. It is seen clearly that the system has been designed to minimize the lag difference of the two kinds of signals. Since comparisons of two different kinds of signals are to be made, it is only the consistency and magnitude of the lag difference which is of importance. Measure- ments of this quantity are to be made in a number of receiving-record- ing sets prior to their use in the field. The U. S. Coast and Geodetic Survey proposes to obtain an additional check by occupying a sta- tion of precisely known longitude and working the problem back- wards. Thus the lag will be subjected to independent measurement in the laboratory and in the field. It is confidently expected that by the use of this recorder a new order of precision will be attained in measurements of the kind in which this apparatus may be employed. BIBLIOGRAPHY Simon, Hans. Jahrb. drahtl. Telegr. 2: 409-416. 1908-09. TuRPAiN. A. Rev. Electrique. 18: 211-214. Sept. 1912. TuRPAiN, A. Bull. Soc. Int. des Electr. (3) 3: 299-322. 1913. Abraham, H. Bull. Soc. Int. des Electr. (3) 3: 649-662. July 1913. CampbELL-Swinton, a. a. Proc. Wireless Soc. London, 1914. July 19, 1921 abstracts: optics 311 DosNE. Compt. Rend. 158: 473-474. 1914. Raymond-Barker, E. Electrician 72: 743, 744 and 783. 1914 Waggoner, C. W. Phys. Rev. 3: 500. 1914. Rainey, R. M. Electr. World 65: 848. 1915. Lenner, E. Electro, techn. Zeitschr. 36: 598. 1915. Urie, F. D. Pop. Astron. 23. Nov. 1915. PouLSEN, R. M. Electr. World 68: Nov. 1916. Culver, C. A. Joum. Frankl. Inst. 187. May 1919. Abraham, Block. Compt. Rend. 169: 282-285. Aug. 1919. Campbell-Swinton, A. A. Wireless World 8: 641-648. Dec. 1920. Turner, L. B. Electrician 83: 4, 5, 34, 35, 554-557. 1919. HoxiE, J. A. Elektrotechn. Zeitschr. 41: 73.3-734. Sept. 1920. Creed Co. Ltd. and D. McLennan. The Engineer. 130: 366. Oct. 1920. Latour, M. L'Electricien. 51: 452. Oct. 1920. HoxiE, J. A. Radio Rev. 1: 781. Dec. 1920. Campbell-Swinton, A. A. Sci. Amer. Monthly. 3: 155-156. Feb. 1921. CouRSEY, P. P. Wireless World 8: 761-764. Feb. 1921. Wallace, S. T. Wireless World 8: 768-769. Feb. 1921. Brun, J. Radio Electricite 1: 477-487. March 1921. Pratt, H. Proc. Soc. Rad. Eng. 9: 174. Apr. 1921. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and' signed by themselves, are forwarded promptly to the editors. The abstracts should con- form in length and general style to those appearing in this issue. OPTICS. — The contrast sensibility of the eye as a factor in the resolving power of the microscope. Fred. E. Wright. Journ. Opt. Soc. Amer. 2:101- 107. 1919. In this paper three factors of importance in high-power microscope work are emphasized, namely: (1) The use of a polarizing prism to eliminate that part of the field-light which does not contribute to the diflfraction pattern in the image and hence tends to reduce the contrast and to decrease the sharpness and crispness of the image. This phenomenon arises because diffracted beams, which emerge from gratings whose interval is of the order of magnitude of half a wave length of light, are sensibly polarized in a plane normal to the lines of the grating. (2) a Diaphragm of the rectangular type, for use in the image plane of the eyepiece in order to cut out all light except that from the particular object under examination. The field should, however, cover at least 10°. (3) The importance of a field intensity of illumination approaching that of daylight and best adapted for the eye at any particular time. The simplest method for securing this is by means of a substage polarizer in conjunction with the polarizing prism ; the polarizer can be rotated, and with it the intensity of illumination of the field varied. These factors are not important for ordinary observations, because the resolving power there required is not great; but in high-power, critical work they are significant and enable the observer to accomplish with comparative ea,se that which under other conditions is a matter of difficulty. F. E. W. 312 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 GEODESY. — Latitude developments connected with geodesy and cartography, lidth tables, including a table for Lambert equal-area meridional projection. Oscar S. Adams. U. S. Coast and Geodetic Survey Spec. Publ. 67. (Serial 143). Pp. 132. 1921. There are six different kinds of latitude that are found convenient in various cartographic and geodetic applications. In this publication the developments of the differences between each of these latitudes and the geodetic latitude are derived in Fourier series in terms of the geodetic lati- tude and afterwards expressed in terms of the particular latitude in question. In the case of two of the latitudes that are, from their definitions, somewhat complicated in their development, the series have been derived in several different ways. This procedure serves as a check upon the work and the methods in themselves are interesting applications of analysis to practical problems. The coefficients of the series are expressed in terms of the eccentricity of the meridian ellipse; in this form they are applicable to any spheroid of reference. For the computation of tables, these coefficients were afterwards expressed in terms of the Clark spheroid of 1866, this being the spheriod of reference of the North American Geodetic Datum. In this form the coeffi- cients are given in seconds of angle so that the result of a computation may be expressed in seconds of angular measure. The resulting coefficinets are given both as numbers for use in machine computation and as logarithms for work without calculating machine. Tables are included for these latitudes computed for every half degree of latitude. In practical applications, these tables will be found of very great advantage since they give results that would require a great amount of computation if no table were available. In addition to these latitude tables, there are given tables for transforma- tion from latitude and longitude to arc distance and azimuth from a point on the equator. After these is given a table of the radial distance for a Lambert azimuthal equal-area projection upon a meridian plane, and finally there is included a table of the coordinates for this projection. O. S. A. ZOOLOGY. — Report on the Crinoids collected by the Barbados -Antigua Expedi- tion from the University of Iowa in igi8. Austin H. Clark. Univ. Iowa Studies. Studies in Natural History, 9 (First Series No. 45), 5, 1-28. March 15, 1921. The crinoids collected by the Barbados- Antigua Expedition are minutely described; a history of the development of the study of the West Indian crinoids is given, and the faunal characteristics and relationships of the Caribbean region are discussed in detail; a key to the 30 genera of crinoids occurring in the Caribbean Sea is included; the author's 25 previous papers on the Lesser Antillean fauna (dealing with living and extinct birds, mammals, amphibians, fishes, insects and onychophores) are listed. A, H. C. METALLURGY. — The inter crystalline brittleness of lead. Henry S. Raw- don. Bur. Standards Sci. Paper 377. Pp. 19, figs. 11. 1920. Sheet lead sometimes assumes a very brittle granular form during service, dne to corrosion. An explanation which has been offered by previous in- vestigators for this change in properties is that it is due to an allotropic trans- formation, the product resulting from the change being analogous to the well- known "gray tin." The rate at which the intercrystalline brittleness is brought about is proportional to the amount of impurities and to the concen- July 19, 1921 proceedings: philosophical society 313 tration of acid in the solution in which the lead is placed. Practically all the impurities which are found in lead are lodged between the grains. The preferential attack by the corroding agent for these impurities and perhaps also for the "amorphous intercrystalline cement" accounts for the brittleness produced. Investigation showed that specimens of exceptionally pure lead (99.993 per cent), when immersed for 24 days in a neutral solution of lead acetate, became appreciably embrittled by the formation of minute inter- crystalline fissures. No evidence of the existence of an allotropic form of lead similar to gray tin could be obtained. H. S. R. CHEMICAL TECHNOLOGY. — Inks — their composition, manufacture, and methods of testing. Bur. Standards Circular 95. Pp. 24. 1920. The composition and manufacture are discussed only briefly, but the methods of testing which are in use at the Bureau of Standards are given in sufficient detail to enable any chemist to use them. After a brief introduction on the history of ink, there are discussions of writing and copying inks, ink tablets and powders, marking, cancelling, stamping, duplicating, and sym- pathetic inks. The methods used for the laboratory examination of all but the last of these kinds of ink are next taken up. The circular closes with a short bibliography. RADIOTELEGRAPHY. — Principles of radio transmission and reception with antenna and coil aerials. J. H. Bellinger. Bur. Standards Sci. Paper 354. Pp. 63, figs. 17. 1919. Coil aerials are coming to replace the large antennas in radio work. It is found that the coil aerial is particularly desirable for communication on short wave-lengths. A coil aerial is as powerful as an antenna only when its di- mensions approach those of the antenna. For other reasons, however, a small coil aerial is in many cases as effective as a large antenna. An advan- tageous type of radio aerial is a condenser consisting of two large metal plates. This type of aerial has many of the advantages of the coil aerial. The funda- mental principles of design of aerials are given in this paper. On the basis of this work the actual functioning of any type of radio aerial can be deter- mined either from measurements made upon the aerials or from actual trans- mission experiments. J. H. D. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 848th meeting The 848th meeting was held in the Assembly Hall of the Cosmos Club on March 12, 1921. It was called to order by President Faris, with 43 persons present. The program was as follows : T. S. Sligh, Jr: Recent modifications in resistance thermometer construction. (illustrated.) A resume of some of the more important phases of resistance thermometry led up to a brief discussion of present practice at the Bureau of Standards regarding the construction of resistance thermometers. The most important points regarding present practice including recent modifications are: (1) The use of the potential terminal type of thermometer with Wheatstone bridge. (2) Thermometer leads made of 12 strands of No. 28 copper wire instead of the fine flexible strand previously used. (3) 314 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 Thermometer bridge terminals of thin copper. (4) Smaller and neater thermometer heads. (5) Sealing of the strain-free type of thermometer. (6) Elimination of the drying head on calorimeter thermometers. (7) A method of electrical annealing which seems to effectively relieve all winding strains in the thermometer coil. The subject matter of the paper is given in full in Bureau of Standards Scientific Paper No. 407. The paper was discussed by Dr. W. P. White. R. H. Wilhelm and Amelia K. Benson : A comparison of the International Hydrogen Scale with the standard scale of temperature defined by the platinum resistance thermometer . (Illustrated; presented by Miss Benson.) The International Scale of Temperature adopted by the International Committee on Weights and Measures in 1SS7 is the scale of the hydrogen thermometer set up by Chappuis at the International Bureau, the pressure of hydrogen at 0° C. being one meter of mercury. Chappuis calibrated four verre dur thermometers so as to define the mercury-in-glass scale, and com- pared these thermometers with his hydrogen thermometer to get the cor- rection necessary to convert the verre dur scale to the hydrogen scale. Since the platinum resistance thermometer has proved to be a more reliable primary- standard than the verre dur thermometer, it was decided to compare all the verre dur primary standards of the Bureau with platinum thermometers, and then place the verre dur thermometers in the vault. The two scales have been compared by Griffiths in 1893, Waidner and Mallory in 1899, Harker and Chappuis in 1900, and the Bureau of Standards in 1917 and 1920. All the comparisons indicate that the hydrogen scale is lower than the standard platinum scale by perhaps 0.010 degree in the range 10° to 30° C. The paper was discussed by Messrs. Burgess, Fenner, Harper, Sosman, Millar, Sligh, and Dickinson. The President announced that Miss Benson had the distinction of being the first woman who had ever addressed the Society. C. O. Fairchild: New methods of sealing optical glass. (Illustrated.) A new process for joining optical glass has been developed which enables one to join glass parts with finished surfaces without distorting the surfaces except at an edge. It has been applied to the construction of colorimeter tubes, cells, etc., polarimeter tubes, incandescent lamps with optical glass windows, haemacytometers, and Nessler tubes, and the protection of surfaces for internal reflection. The method is carried out by heating the glass parts while in approximate contact, in an electric furnace, to a temperature at or near the annealing range, and applying heat locally (usually at an edge) by means of a small oxy-gas flame. The progress of joining is viewed through a window in the furnace. The process was developed through consideration of the low thermal conductivity of glass, and the rapid change in mobility near annealing temper- atures. These properties make it possible to start fusion by local heating without propagating stress beyond a very restricted portion of the glass. It has been found that two polished surfaces nearly in contact will join readily when junction is once started and it is possible to obtain excellent results without polishing the surfaces. A fine ground surface provides a good joint and the fusion is accomplished with almost complete disappearance of the ground part. July 19, 1921 proceedings: biological society 315 The method has proven to be the simplest and most satisfactory so far developed for the seaUng of glass without distortion. It is, of course, par- ticularly adapted to thin walled articles such as absorption cells and boxes. The paper was discussed by Messrs. White, Fenner, Sosman, Crittenden, and others. H. H. Kimball, Recording Secretary. BIOLOGICAL SOCIETY 620th meeting The 620th meeting was held in the lecture hall of the Cosmos Club on February 5, 1921, with President Hollister in the chair and 50 persons present. On recommendation of the Council, Mr. Glenwood C. Roe and Mr. Maurice K. Brady were elected to membership. The deaths of Mr. W. J. Bennetts on September 13, 1920, and Mr. W. W. Welsh on January 31, 1921 were announced, both having been members of the Society. Informal Communications Dr. H. M. Smith exhibited a string of artificial pearls, and a bottle of finely comminuted fish scales in suspension. The industry of making arti- ficial pearls was transferred to this country during the war, the Bureau of Fisheries assisting by suggesting fish whose scales were of desirable luster. Dr. Smith also exhibited the smallest and consequently the youngest eel ever captured. It was 2 cm. long, taken at 150 meters depth about 150 miles southeast of the Bermudas. This is the locality where fresh water eels of Europe and America resort to breed. The specimen was taken by Dr. ScHMiTT in his recent expedition to study eels. Dr. R. W. ShuFELDT stated that in his studies of birds and mammals fractured bones are sometimes found. An instance in Oxymicterus rufus, a large mouse from Brazil, was described, in which the greatly extended olecranon or elbow process of the forearm was broken, and a false joint had formed. Regular Program Ivar Tidestrom : Notes on the flora of the Iberian Peninsula. Mr. Tidestrom showed that Spain possessed 60 per cent of Europe's 10,000 species of plants, many of which are peculiar to Spain, and explained this fact, as well as the relation of Spain's flora to that of other countries, by her more continuous elevation above sea level in the later geological periods. The resemblance of Spain's topography to that of our own Southwest, and the similarity of climatic and botanical zones, was shown in detail. The paper was illustrated by maps, topographic sections, and landscapes. R. S. Bassler: Paleontological work at the National Museum. The work of the National Museum is divided into three principal fields: the care of the collections, exhibition, and investigation. The space in the museum building is divided approximately into thirds among zoology, paleon- tology, and anthropology. In the exhibits of invertebrate and botanical paleontology', the plan is to have large exhibits, suitable for cursory obser- vation, in the center of the halls; at one side, a series in geological sequence; and on the other side, further large exhibits showing details, restorations, and the like. In the hall of vertebrate paleontology another plan is necessary on account of the size and variety of the exhibits. The display here is de- servedly popular on account of the admirable specimens, some of which are unique. A. A, Doolittle, Recording Secretary. 316 journal of the washington academy op sciences vol. 11, no. 13 621st meeting The 621st meeting of the Biological Society of Washington was held in the lecture hall of the Cosmos Club at 8 p. m., February 19, 1921. Vice-President A. S. Hitchcock presided, and forty seven persons were present. On recom- mendation of the Council, Mr. O. M. Freeman was elected to membership. Informal Communications Professor E. S. Morse, former president of the Boston Society of Natural History, addressed the Society briefly. The Secretary read by title a paper by S. Stillman Berry: Notes on some Japanese Cephalopods; a review of Sasaki's "Albatross" report. Regular Program C. E. McClung : Chromosomes in relation to heredity. Modem biological work is characterized by greater exactness of methods and by the correlation of effort in different fields. These features are particu- larly marked in studies on heredity in which the existence of separate or unit characters has been determined and their exact numerical distribution observed. Correspondingly, careful and minute studies of the germ cells have revealed a mechanism which supplies a full explanation for the behavior of characters in heredity. Of primary importance is the observation that the character of an organism can be fully known only when the composition of its germ cells is understood. Thus, commonly, when two white animals are bred together, it is expected that their young will be white but cases are known where the result is a progeny of strongly colored coat. Such results are now understood and may be predicted in cases where the nature of the germ cells of the parents is known. The basis of all modern work in genetics was laid by an Austrian monk, Gregor Mendel, in the middle of the last century, but his results emained unknown for fifty years. From a study of the mechanism of heredity, as revealed in the germ cells, it is found that the equivalence of the two parents is explained by their equal contribution of a substance, called chromatin, of most highly organized character. As one evidence of this organization the integration into a definite number of bodies, called chromosomes, is observed in every cell in each in- dividual of a given species. Not only is the number exact but the size, form and behavior, so that it is possible to classify some animals by their chromo- somes alone. In the structure and behavior of the chromosomes we find an explanation of the alternative inheritance of contrasting characters, of the chance distribution and recombination of characters, of their transmission in groups, and of breaks in these groups. An exact analysis of the structure of the chromosomes shows them to be made up of definite units whose number, arrangement and movements supply an explanation of the most detailed genetical studies. Finally it has been discovered that a particular chromo- some is concerned with the determination of sex. (Author's abstract.) The paper was illustrated by numerous lantern slides, and was discussed by Mr. T. L. Casey. Sewall Wright: Heredity as a factor in the resistance of guinea-pigs to tuberculosis. The paper described some experiments which have been carried on by cooperation between the Bureau of Animal Industry and Dr. Paul A. Lewis of the Henry Phipps Institute of Philadelphia. The resistance to tuber- culosis has been tested in about 800 guinea-pigs belonging to five closely inbred families, crosses between these families, and in a control stock which has never been inbred. • July 19, 1921 scientific notes and news 317 It was found that sex, age, rate of gain, and weight at inoculation made very little difference in the length of life after inoculation, determining in all less than 10 per cent of the observed variation. On the other hand, marked differences in resistance were found among the inbred families. Inbreeding itself was not a factor of great importance in increasing susceptibility although of the greatest importance in isolating different degrees of resistance. Two of the inbred families, with fifteen to twenty generations of exclusively brothersister matings back of them, were superior to the control stock, while three were inferior. The crosses between the families produced young which were in general at least equal to the better of the two parental families. Resistance is thus apparently dominant over susceptibility. There was equal transmission from sire and dam and to progeny of either sex. In cer- tain crosses, the progeny were markedly superior to either parent strain, indicating that these strains were resistant for different reasons, each thus being able to supply what the other lacks. Among the crossbreds over 30 per cent of the variation in length of life was determined by the amount of blood of the best family, contrasting with less than 10 per cent determination by age, weight and rate of gain combined, and leaving something over 60 per cent determined by conditions at or following inoculation. There was no relation between the rank of the inbred families in resistance to tuberculosis and their rank in other respects, such as average weight, fertility, and success in raising young. As in all of these cases, however, the importance of inbreeding in isolating hereditary differences was brought out by contrasting the marked differences among the inbred families and their crosses, with the lack of appreciable correlation between brothers within the random bred stock. (Author's abstract.) The paper was illustrated by diagrams and curves, showing the tendencies discussed. A. A. DoOLiTTLE, Recording Secretary. SCIENTIFIC NOTES AND NEWS THE PROPOSED CENTRAL ENGINEERING SOCIETY IN WASHINGTON. The initial step toward the organization of a central engineering society in Washington was taken by the Washington Section of the American So- ciety of Mechanical Engineers at its annual dinner on June 9. The plan, as outlined by Professor George A. Weschler, chairman, and A. R. Citey- NEY, secretary- treasurer of the Section, suggested that a larger organization be founded upon one of the existing societies as a nucleus, to be open to all engineering and technical men in the city, and to be governed by a representa- tive body nominated by the local sections of the various national engineering societies. This plan is similar to that of the Academy and its Affiliated Societies. Messrs. A. G. Christie and W. F. Ballinger reported on the experience of the Baltimore and Philadelphia Engineers' Clubs, respectively. Mr. L. W. Wallace, executive secretary of the Federated American Engineering Societies, discussed the work of that organization. Dr. R. B. Sosman, secretary of the Academy, spoke on the experience of the Academy in form- ing such an organization. Informal views of the plan were also presented by the following repre- sentatives of the Washington sections of the engineering societies: John C. 318 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. IS HoYT, American Society of Civil Engineers; E. A. Holbrook, American Institute of Mining and Metallurgical Engineers; Milton M. Flanders, American Institute of Electrical Engineers; Harry D. Appleby, American Association of Engineers; H, C. Dickinson, Society of Automotive Engi- neers; William Blum, American Chemical Society; S. Tour, American Society for Steel Treating; and John S. Conway, Washington Society of Engineers. Mr. Watson Davis offered the aid of the scientific column of the Washington Herald, and there was informal discussion by W. H. Bixby^ A. M. Holcombe, and others. The meeting adopted a resolution endorsing the general idea of a central engineering organization and requesting the various societies interested to appoint delegates to meet at the call of the chairman of the Mechanical Engineers and draw up a detailed plan for submission to the societies. Three societies may be considered available as a nucleus, namely, the Washington Society of Engineers, the local section of the American Associa- tion of Engineers, and the Council of the Federated American Engineering Societies. The last of the three, being a national federation, is less likely to be considered than the other two. The Washington Society of Engineers is the older organization of the remaining two, having been founded in 1905 and having at present about 500 members. The American Association of Engineers is a national organization, but is composed of individuals and not constituted by the combination of other organizations or their representa- tives. Several of the speakers laid special stress upon the desirability of com- bining scientific, technical and engineering societies into a single federation,, but no definite plan toward this end was presented. Among the purposes of the proposed engineering organization would be the provision of a meeting place for the societies, the maintenance of a library for reference books and current periodicals, a central secretarial organization for the routine business of the societies, and the formation of committees to take an active part in civic affairs involving engineering and technical questions. notes The Washington Section of the American Society of Mechanical Engineers elected the following officers at the annual dinner on June 9: Chairman, L. A. Fischer, of the Bureau of Standards; Vice -Chairman, O. P. Hood, of the Bureau of Mines; Secretary-Treasurer, C. E. Oakes, of the Federal Power Commission. The 14th National Conference on Weights and Measures was held at the Bureau of Standards on May 23-26. Among the subjects given special consideration at the meeting were : The sale of bread by weight, the detection of shortages, the weighing of coal, and the testing of pumps for measuring liquids. The purchase of additional land near the Connecticut Avenue entrance to the National Zoological Park, provided for in the Sundry Civil Bill for 1921, has been completed. The addition to the Park is about 6 acres, mak- ing the total area about 175 acres. The Radio Laboratory of the Bureau of Standards is cooperating with the Bureau of Markets of the Department of Agriculture in the establishment of a system of broadcasting market reports by radio. As it is likely that a July 19, 1921 scientific notes and news 319 wide demand for radio equipment will develop, the Bureau has under way- plans for the study of commercial apparatus and the preparation of specifica- tions as to the behavior and usefulness of radio sets designed for general use. The cases containing the exhibit of radium ores and radioactive minerals, prepared incidentally to the visit of Madame Curie to Washington, have been removed from the Art Gallery of the National Museum and now form a permanent exhibit at the east end of the Mineral Hall of the Natural His- tory Building. Scales for the measurement of length are now being constructed directly from the fundamental wave lengths of light without the use of any inter- mediary standard such as the standard meter bars. For example, the Bureau of Standards has recently completed the rulings on a 6-inch standard scale for a manufacturing concern, using light waves from a neon tube as the length standard. Dr. J. M. Aldrich, associate curator of insects at the U. S. National Museum, left Washington in May for a two months' study of the insects, and particularly the Diptera, of central Alaska, along the line of the new Alaska Railroad between Seward and Fairbanks. Vice-President Calvin Coolidge has been elected chancellor of the Board of Regents of the Smithsonian Institution to succeed the late Chief Justice Edward D. White. Dr. F. G. CoTTRELL, chairman of the Division of Chemistry and Chemical Technology, National Research Council, sailed for Europe in June to make a survey of current applications of oxygen and helium in European countries. He also expected to attend the meeting of the International Union of Pure and Applied Chemistry in Brussels on June 27. Mr. S. T. Dana, assistant chief of the research branch of the U. S. Forest Service, has resigned to become land agent and forest commissioner of the State of Maine, with headquarters at Augusta. Mr. Robert C. Duncan, physicist at the Bureau of Standards, has re- signed to accept a position with the Bureau of Ordnance of the Navy Depart- ment. Mr. F. C. Fair, formerly Washington representative of the American Standardizing Bureaus, an organization having supervision of the manufac- turing of pharmaceutical products for several associated companies, has become chief chemist of the Central Railway Signal Company at Hammond, Indiana. Mr. Charles S. Hawes, in charge of the Bureau of Research and Statistics, War Trade Board Section, Department of State, died suddenly on Friday, April 22, 1921, in Chicago, Illinois. Mr. Hawes joined the War Trade Board in 1918 and remained with the new section when the old Board was dissolved. As head of its Bureau of Statistics he had been chiefly concerned of late with the importation of dyes, chemicals, and coal-tar products and had compiled a recently published report on dyes. Mr. Carl L. Hubbs, curator of fishes in the Museum of Zoology, Univer- sity of Michigan, has been studying the lampreys and lancelets of the Nat- ional Museum collections, having been extended laboratory facilities for the purpose. 320 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 13 Dr. W. J. Humphreys of the Weather Bureau has been elected Secretary of the American Geophysical Union, to succeed Dr. H. O. Wood, resigned. Mr. Enoch KarrER has resigned from the Bureau of Standards to accept a position as physicist at the Nela Research Laboratory, Nela Park, Cleve- land, Ohio. Mr. Sidney D. Kirkpatrick, chemist with the U. S. Tariff Commission, has resigned to join the editorial staff of Chemical and Metallurgical En- gineering, in New York City. Mr. Albert G. Loomis has resigned as assistant professor of chemistry at the University of Missouri to become physical chemist at the new cryo- ogenic laboratory of the Bureau of Mines. Dr. William M. Mann, assistant entomologist in the U. S. Department of Agriculture, left Washington in June to accompany an expedition to the region of La Paz, BoUvia, under the direction of Dr. H. H. Rusby, dean of the school of pharmacy at Columbia University. The main object of the expedition, which is financed by the H. K. Mulford Company, is the collec- tion of herbs and plants likely to be of use in medicine, but general studies will also be made of the fauna and flora. Dr. C. L. MarlaTT, assistant chief of the Bureau of Entomology, U. S. Department of Agriculture, received the honorary degree of Doctor of Science from the Kansas State Agricultural College in June. Dr. J. C. Merriam, president of the Carnegie Institution of Washington, received the honorary degree of Doctor of Science from Columbia Univer- sity in June. Dr. Takejiro Murakami, assistant professor in the iron and steel re- search institute of Tohoku Imperial University, Japan, visited Washington in June. Mr. A. DE C. SowERBY visited the scientific institutions of Washington in June, on his way to South China, where he will spend three years in an extensive biological survey, with particular attention to the higher verte- brates. Dr. C. G. Storm has been transferred from the position of professor of chemical engineering at the Ordnance School of Application, Aberdeen Proving Grounds, Maryland, to the office of the Manufacturing Service of the Ordnance Department in Washington. Dr. Alexander Wetmore, of the Biological Survey, U. S. Department of Agriculture, has returned from a year's collecting trip in Argentina. He made a special study of the migratory shore birds. Dr. H. O. Wood, formerly assistant secretary of the National Research Council, has been appointed a research associate of the Carnegie Institution of Washington, and is in California engaged in a reconnaissance of the south- ern California seismological field, under the general supervision of an ad- visory committee in seismology appointed by the Institution. Mr. Harper F. ZollER, formerly chemist with the Dairy Division Re- search Laboratory, U. S. Department of Agriculture, is at present bacteri- ological chemist for the Nizer Laboratories Company, manufacturers of food products at Detroit, Michigan. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 August 19, 1921 No. 14 PHYSIOLOGICAL CHEMISTRY.— C/zem^Va/ structure and phys- iological action.'^ C. L. Alsberg, Bureau of Chemistry. The subject matter which I propose to present to you tonight contains nothing essentially new to the pharmacologist. It deals, however, with a field of research that, while of the greatest impor- tance to the welfare of mankind, is still very much in flux. However, a subject in flux is more interesting than one that is in a static state with all phenomena accurately ticketed and labeled. It still permits the exercise of the imagination. Hence what I have to offer to you tonight must be, in the main, a series of speculations and of observations none too well coordinated. Only a part of it has found its way into the general text-books, and this is my excuse for the selection of my subject. - Paracelsus wrote many centuries ago, "The real object of chemistry- is. not to make gold, but to prepare medicine." Schmiedeberg has defined the aim of the science of pharmacology as the production of physiological reactions with chemical reagents. The pharmacologist hopes, therefore, to contribute toward the solution of some of the problems of biology by using chemical stimuli as the physiologist uses physical ones. Some pharmacologists have believed that the reaction of living things to chemical stimuli is necessaril}^ the result of a chemical reaction between the stimulating chemical and some sub- stance in the cell stimulated. The hope has been expressed that eventually it wiU be possible to write the equations for these reactions as for any other chemical reaction. However, this hope is very very far from realization, and perhaps never will be realized because, as we shaU see, it represents far too simple a conception of the matter. Indeed, almost the only case that occurs to me in which it is possible ^ Address of the retiring President of the Washington Academy of Sciences. Presented at a joint meeting of the Academy and the Chemical Society on January 20, 1921. Received July 20, 1921. 2 L. Spiegel. Chemical constitution and physiological action. Translated, with addi- tions, from the German, by C. Luedeking and A. C. Boylston (D. Van Nostrand Co., New York, 1915). 321 322 JOURNAL OF THE WASHINGTON ACADEMY OP SCIENCES VOL. 11, NO. 14 to write such a reaction is carbon monoxide poisoning. In this intoxication the carbon monoxide gas unites in fixed proportions with the hemoglobin of the blood to form a very stable combination which is incapable of transporting oxygen from the lungs to the tissues. The result is asphyxiation, but even in this case we are not helped much by our ability to write this equation, for it tells us nothing about the processes that take place during asphyxia. Indeed, we know very little about them. Carbon monoxide is the cause of death. The more immediate cause, however, is oxygen starvation, and if we are very exacting, we must demand the equations of asphyxia. These, however, we are quite unable to give. Of recent years very different conceptions have been developed. The older men, dominated by the imagery of organic chemistry, sought the chemical reactions underlying the phenomena of pharma- cological action, thinking that they are ordinary stoichiometric re- actions, very complex ones if you will, but still of the ordinary type and, therefore, dependent upon the chemical properties of the sub- stances taking part in them. In those days the prevailing conception of protoplasm was that it consisted of huge, very complex, very un- stable molecules. The various parts of such a live molecule were believed to have different functions. According to this conception, the live molecule might have been pictured as resembling a chestnut burr bristling with prickles or grappling hooks each capable of grappling a specific and different food substance.^ Some of the poisons were supposed to be anchored by such grappling hooks just like foodstuffs and the specific action of a given substance upon a given cell or tissue was supposed to be due to the fact that that substance had some in- herent property that caused it to be anchored by some specific grappling hook in that cell. Therefore, explanation of the physiological action of a substance was sought primarily in the structure of its molecules rather than in its physical properties. To some particular grouping of the atoms in the molecule solely was attributed the physiological action of the substance.* Such a group was spoken of as the carrier of the action, and much was written about "toxophore" groups, • P. Ehrlich. On immunity with special reference to cell life. Croonian Lecture. Proc. Roy. Soc. London 66: 432-437, 446. *0. LoEW. Einnaturliches System derGiftwirkun gen. (Stuttgart, 1893.) P. Ehrlich. Ueber die Beziehungen von chemischer Constitution und pharmakologischer Wirkung. Vortrag gehalten im Verein fur Innere Medicin am 12 December, 1898. v. Leyden Festschrift p. 647. (August Hirschwald, Berlin, 1902.) AUGUST 19, 1921 ALSBERG : PHYSIOLOGICAL CHEMISTRY 323 "anaesthetic" groups, "narcotic" groups, "tetanic" groups, and the like. Our present-day conception of protoplasm is dififerent. We no longer think of a giant living molecule so unstable that its decomposi- tion and. continuous reconstruction constitute the phenomena of life. We no longer consider protoplasm as homogeneous. We believe it to be heterogeneous, to consist of a series of phases, an emulsion, a series of fine droplets and particles in suspension.^ According to the laws of surfaces, which I shall have to ask you to take for granted tonight, as we have no time to consider them now, some substances will con- centrate at surfaces and this concentration will be greater the greater the curvature of the surface.^ Therefore, in such a system as an emulsion you have membranes formed automatically at all surfaces, and so it seems to be with protoplasm. You must conceive of these as chemical membranes, as mere surface layers, not necessarily visible under the microscope, representing the very great concentration at the surface of a droplet of one or more of the substances dissolved in the droplet or in the surrounding medium. Each droplet is then a sort of test tube shut off to a certain degree from the other droplets and from the liquid in which it is suspended. Phenomena can therefore go on in such a droplet without affecting the other droplets except indirectly. Such a conception of protoplasm very greatly simplifies, as we shall see later, our conception of the physiological action of chemical sub- stances since instead of being a purely chemical concept it is physical as well as chemical. It leaves room for such considerations as the surface effect of the substance, its solubility in the membrane, in the droplet, in the various phases of a gel, etc., etc. With the old conception of protoplasm as a homogeneous chemical entity the physiological action of a substance was referred merely to its chemical character and reactivity. This point of view impeded rather than aided progress. With the acceptance of the idea of proto- plasm as a physical system, rather than as a chemical structure, the conviction has gained ground that the physiological action of a sub- stance depends not rnerely upon its chemical structure but also upon its physical properties, or rather those properties" that lie on the frontier between physics and chemistry, such properties as solubility, diffusi- = C. L. Alsberg. Mechanisms of cell activity. Science N. S. 34: 97-105. July 28, 1911. * W. M. Bayliss. An introduction to general physiology. (Longmans, Green & Co., I^ndon, 1919.) Chap. I. ' G. GiEMSA. Neuere Ergebnisse der Chemotherapie. Archiv Pharm. 257: 194. 1919, 324 JOURNAL OF THB WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 bility, dissociation, colloidal state, electrical charge and the like. Of course, in the last analysis the physical state is but an expression of the chemical constitution and vice versa, but these are problems for the chemist, not the pharmacologist. However, I do not mean to be understood as stating that chemical constitution has nothing to do with physiological action. I mean merely that very frequently changes in constitution produce changes in action chiefly because they influence the physical properties of the substance rather than its power of reacting chemically with other substances. Certainly very slight changes in constitution often produce very great changes in physiological action. You all know that stereo-isomerism influences the taste of simple amino acids, some being sweet, some bitter;^ that one form of asparagin is sweet while the enantiomorphous form is tasteless; that 1-adrenalin causes the smaller arteries to contract greatly while d-adrenalin is far less active.^ The examples might be multiplied almost indefinitely. Indeed, as we shall see later, substances of a very widely different chemical structure may have a very similar action. Of these we may be sure that their action depends rather upon their physical than their chemical properties. What I have to say tonight will deal as much with physical or physico-chemical properties as with chemical constitution. Moreover, I do not propose to deal with many simple inorganic substances like arsenic, iodine or phosphorus. The physiological action of many of the elements seems to be an intrinsic property as much as their atomic weight. Indeed, within the same group of the periodic system the toxicity of kations, with certain exceptions, increases with the increase of the atomic weight.^** Until we know far more than we do now concerning the underlying causes for the physical properties of the elements we are not likely to know why, for example, iron is less poisonous than cobalt. It is much the same question as why bromine is red and chlorine green. We do know, however, that elements like arsenic, phosphorus and nitrogen, which exhibit variable valence, maf be toxic and we suspect that their action is probably in some way connected with their change from one state of valence to another. We also know that in some way the toxic action of kations and anions is * B. Oertly and R. G. Myers. A new theory relating constitution to taste. Journ. Amer. Chem. Soc. 41: 861. 1919. ^ W. H. ScHULTz. Quantitative pharmacological studies: Adrenalin and adrenalin-like bodies. Hygienic Lab. Bull. 55, U. S. Public Health and Marine Hospital Service, 1909. " Blake. Compt. rend. 1839; Proc. Roy. Soc. London 1841. Amer. Journ. Sci. 1874; Ber. deutsch. Chem. Ges. 14: 394. 1881. AUGUST 19, 1921 alsberg: physiological chemistry 325 related to their effects upon colloids, especially proteins ;^^ but here again the power of kations to precipitate proteins and of anions to produce the reverse effect is, so far as our knowledge at present goes, an intrinsic property. Since it is, speculation upon these phenomena is rather fruitless till the physicists have gone a great deal further. I shall deal tonight therefore in the main with substances more complex than the simple elements. There are in the main three general ways in which a substance may affect a cell: The substance may attack the surface of the cell. The substance may affect the cell indirectly without entering it. The substance may affect the cell in the course of entering, or after entrance into the cell. Many substances destroy the surface layer of a cell by precipitating or coagulating it. This is the effect of many astringents, such as the salts of many heavy metals, ferric chloride for example, when in sufficient concentration. Other substances dissolve some of the constituents of the surface layer as, for example, ether when in sufficient concentration.^^ Other substances combine with some component of the surface layer. This may be the action of saponins. ^^ Substances which neither enter cells nor attack the cell surface act chiefly by affecting the concentrations within the cell. They either withdraw water from the cell so that it tends to shrivel and become desiccated, or they cause water to penetrate into the cell so that it swells. These processes are called plasmolysis because they may, if carried to extremes, cause the protoplasm to disintegrate. Those among you who are botanists or physiologists know that this phenom- enon may be studied by observing the behavior of suitable plant cells or red blood corpuscles when placed in solutions of the substances to be tested. In many plant tissues the protoplasm forms a layer lining a rigid cellulose wall. It is really a sac enclosing a relatively large space filled with sap. When such a cell shrinks or is plasmolyzed the protoplasm withdraws from the cellulosic cell wall and this can be seen very easily under the microscope. In the case of red blood corpuscles, these become crenated, that is, they shrink and take on the 11 Bayliss, op. cit., p. 35. 12 L. Hermaxn. Ueber die Wirkungsweise einer Cruppe von Giften. Arch. Anat. Physiol, u. Wiss. Aled. 1866: 27. 1' H. E. Woodward and C. L. Alsberg. A comparison of the effect of certain saponins on the surface tension of water with their hemolytic power. Journ. Pharm. Exp. Therap. 16: 237. 1920. 326 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 appearance of a globe studded with projections like the head of a crusader's mace. That a substance may plasmolyze a cell it is obvious that it must fulfill certain conditions. It must exert osmotic pressure; it must not be able to penetrate into the cell, or if it does, it must do so very slowly, that is, more slowly than water, for if it passes quickly into the cell the osmotic pressure within and without will be very quickly equalized and there will be no plasmolysis. In other words, the cell-membrane must be semi-permeable to the plasmolyzing substance. A semi- permeable membrane is one that permits only certain dissolved sub- stances to pass through it. Now most cell-membranes are semi- permeable to most salts of organic as well as inorganic bases, to the sugars and to many other substances. They do not permit these substances to pass through readily. When brought into solutions of such substances, cells may be plasmolyzed. One group of organisms seems to form an exception. A large number of bacteria do not seem to be surrounded with membranes semi-permeable in this sense; salts pass into them apparently unhindered. They all can be stained according to the method of Gram, and are known as the Gram positive bacteria. They cannot be plasmolyzed. Considerations of this sort help us to understand the action of certain salts and other substances upon the intestines. You all know that Glauber's salt (sodium sulfate) and Epsom salt (magnesium sulfate) are laxatives. Now one of the characteristics that distinguish such salts from others, say sodium chloride, is that they are not readily absorbed through the intestinal wall. Not being absorbed readily they cause the osmotic pressure of the intestinal contents to remain great as the food passes down the alimentary canal. In order to with- draw water from the intestinal contents the intestines would have to do an amount of osmotic work which would be very great indeed. The result is that water remains in the intestinal contents or is secreted into it so that the contents remain bulky and peristalsis is stimulated. This is one of the main factors, though not the only factor, in the purgative action of these salts. It is a physical factor dependent upon the slow absorption of these salts through colloid membranes, rather than upon any strictly chemical reaction dependent upon the structure of the molecule or its chemical reactivity. We have seen that the phenomenon of plasmolysis furnishes a method to tell what substances do not enter cells. Conversely we can tell what substances do pass readily into cells, for such substances will not AUGUST 19, 1921 ALSBERG : PHYSIOLOGICAL CHEMISTRY 327 plasmolyze. A study of the plasmolyzing power of many hundreds of substances has shown that substances of the most diverse chemical character can enter cells readily. They have neither molecules of similar size, nor similar melting points nor similar boiling points, nor similar chemical affinities. They have one property in common; they are more freely soluble in fatty oils and lipoids than in water. If any of these substances be mixed with water and oil, much of the substance will dissolve in the oil and relatively little in the water. As the physicist would put it, the distribution coefficient for these substances between oil and water is greatly in favor of oil.^^ A very good illustration of this phenomenon is furnished by glycerin and its derivatives, mono- and dichlorhydrin.^' Glycerin enters cells very slowly, monochlorhydrin quite rapidly and dichlorhydrin almost instantaneously. Glycerin has no narcotic action, monochlorhydrin has a fairly strong narcotic action and dichlorhydrin quite a powerful narcotic action. In the days of the purely chemical conception of protoplasm, it would have been assumed that chlorine was a "toxo- phore" group, ^^ that perhaps its action depended upon its electro- negative character or that mono- and dichlorhydrin had greater affinity for the cell-substance. The fact is that glycerin is but slightly soluble in oil and very soluble in water while its chlorine derivatives are very much more soluble in oils than in water. ^^ Since so many substances that pass readily through the semi-per- meable cell membranes are oil-soluble, many biologists have concluded that the cell membrane is, in part at any rate, composed of fat-like substances, probably lipoids, like lecithin and cholesterin. This in- ference is based on the fact that it has been shown for a great variety of semi-permeable membranes that they permit only those substances to pass through them that are soluble in them. Thus chloroform, but not alcohol, may be made to pass through rubber membranes. Hence it was inferred that since only fat-soluble substances pass readily through the semi-permeable membranes of cells, these membranes must consist, in part at any rate, of fats or fat-like substances such as " E. Overton. Studien. ueber die Narkose. (Jena, 1901.) H. Meyer. Arch. exp. Path. Pharm. 42: 109. 1899; 46: 338. 1901. P. Ehrlich. Therap. Monatsh., March, 1887. 1' E. Overton. Ueber die allgemeine osmottsche Eigenschaften der Zelle. Vierteljahrb. Naturforscherges. Zurich 44: 889. 1899. i« C. R. Marshall and H. L. Heath. The pharmacology of the chlorhydrins , a contribution to the study of the relations between chemical constitution and pharmacological action. Journ. Physiol. 22: 1, 2. 1897. 1" H. KioNKA. Zur Theorieder Narkose. Arch. Int. Pharmacodynamie et Therapie 7. 328 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 the lipoids and cholesterin. This is the more probable as lecithin and cholesterin have but slight surface tension effect and would therefore tend to accumulate at surfaces. ^^ Indeed it is probable that all substances that lower surface tension must tend to accumu- late at surfaces and take part, to a greater or lesser degree, in the for- mation of such membranes whether such substances come from within the cell or from the liquids that bathe the cell. This hypothesis of the semi-permeability and lipoid character of the cell-membrane has not been accepted universally. Czapek,^^ for example, believes that the ability of substances to pass through the cell-membrane is a function of their ability to affect surface tension rather than a function of their oil solubility. However, substances that lower surface tension seem also to be oil-soluble. Perhaps the two traits are but expressions of the same underlying physical property. Shryver^° believes the semi-permeability to be dependent upon the presence of a gel in the membrane. However, all the theories explain- ing the semi-permeability of cell-membranes that have been advanced of recent years are based upon physical or physico-chemical consider- ations. Not one assumes any dependence upon molecular structure or chemical reaction. That is the important point for us this evening. We see then that the factors that determine the power of substances to enter cells are physical properties rather than molecular structure or chemical reactivity. If we examine the action substances exhibit after they have obtained entrance into cells, we find that an immense number of substances cg-use narcosis. In the lower organisms proto- plasmic streaming and other forms of motion cease. In the higher organisms endowed with a nervous system, this undergoes a more or less complete paralysis. The most diverse substances have this effect: — Pentane, chloroform, ether, alcohol, phenanthrene, salicylamid monacetin. They have no common chemical properties except that they are neither acids nor bases. They are spoken of as the "indiffer- ent narcotics" to distinguish them from the narcotic alkaloids which are bases. We have here again a common physiological action de- ^8 It should, however, be noted that many food substances, for example glucose, cause plasmolysis; yet they must enter cells for otherwise they could not nourish them. There are undoubtedly other factors that enter into the structure of cell-membranes and a number of theories on the subject have been advanced. " F. CzAPEK. Ueber die Oberfldchen-spannung mid den Lipoidgehalt der Plasmahaut in den lebenden Pflanzenzellen. Ber. deutsch. botan. Ges. 28: 480. 1910. 2° S. B. Shryver. Investigations dealing with the phenomena of "clot" formations, Part II. Proc. Roy. Soc. B 87: 366. 1914. AUGUST 19, 1921 AI.SBERG : PHYSIOLOGICAL CHEMISTRY 329 pendent apparently upon a common physical property exhibited by substances of the most diverse chemical structure. ^^ That this relation is not accidental is proven by the fact that the narcotic power of these substances is broadly proportional to their relative solubility in oil as compared with their solubility in water; that is, proportional to their distribution coefficient between these two solvents. The more this ratio is in favor of oil the more narcotic the substance. This was proved for a large number of substances, both by H. Meyer- and by Overton'-^ who experimented with tad- poles. These animals were placed in water containing varying con- centrations of the substance to be tested and the effect noted. In this way the lowest concentration capable of narcotizing the tadpoles was determined. Comparison of the minimum narcotic concentration thus determined for a large number of substances demonstrated that these concentrations show a direct parallelism with the distribution coefficients of the respective narcotics between oil and water. This parallelism of the effective narcotic strength of a substance with its oil-water distribution coefficient is demonstrated strikingly if experiments be made, as was done by Meyer-^ with the same sub- stances at different temperatures. The narcotic power of each sub- stance changes with the temperature in proportion to the shift made by the temperature in the oil-water distribution coefficient. This is especially striking in the case of chloral as will appear from an ex- amination of table 1 which has been adapted from Meyer's publication on this subject. It is obvious that experiments analogous to Overton's tadpole experi- ments can be performed upon animals breathing through lungs instead of gills only with volatile narcotics like ether or chloroform. The non-volatile narcotics cannot be tested in any direct way because when given by the mouth the rate of absorption from the alimentary- tract may vary in different individuals and in the same individual at different times. Moreover the rate varies with the solubility of the narcotic in the contents of the intestinal tract. Thus phenanthrene is not sufficiently soluble in water to be absorbed and exert any action though it has actually narcotic power. Long ago Bert showed that 2' L. Hermann, op. cit. " H. Meyer, op. cit. " E. Overton, op. cit. ** H. Meyer, Zur Theorie der Alkohol Narkose. Ill Mittheilung. Der Etnfluss wech- selnder Tetnperatur auf Wirkungstdrke und Theilungs-Coefficient der Narcotica. Arch, exp. Path. u. PharmakoL 46: 338. 1901. 330 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 narcosis through the inhalation of air containing vapors of narcotics did not take place however long such a mixture was breathed unless the vapor pressure of the narcotic was above a definite threshold value. 2^ The narcosis-producing vapor pressures run parallel in a general way with the oil-water distribution coefficients of the different TABLE 1. — The Rei^ation of the Power of Certain Substances to Narcotize Tadpoles at Different Temperatures, to the Distribution Coefficients of These Substances between Water and Oil at These Temperatures Distribution Threshold narcotic Substance coefficient value in normal solu- tion « 0.026 1/3 Alcohol at 3° C. 0.047 1/7 Alcohol at 36° C. 0.053 1/50 Chloral at 3° C. 0.066 1/70 Monacetin at 36° C. 0.093 1/90 Monacetin at3° C. 0.236 1/250 Chloral at 30° C. 0.437 1/200 Benzamidat36°C. 0.672 1/500 Benzamid at 3° C. 14.000 1/600 Salicylamidat36° C. 22.230 1/1300 Salicylaniidat30°C. volatile narcotics.-^ It is moreover curious to note that the effective vapor tension of the narcotic in the blood of the narcotized animal is of the same general order of magnitude, if calculated for the same body temperature, in the animal series from the frog to the dog." Meyer and Overton assumed that since the narcotics are especially soluble in the lipoids they will, of necessity, accumulate in those parts of the body that are richest in lipoids. The nervous system is peculiarly rich in lipoids. Hence these investigators explained in this manner the accumulation of the lipoids in the nervous system and their selective action upon it.'-^^ However, just as the lipoid theory of semi-per- 2-' P. Bert. Sur la mortpar Vaction des melanges d'air et de vapeurs dechloroform. Compt. rend. Soc. Biol. 35: 241. 1883. Methode d'anaesthesie par les melanges doses d'air et de vapeurs de chloroform. Ibid. 409. Sur I'anaesthesie par l' ether. Ibid. 522. *^ E. Overton, op. cit. p. 85. " jj. Winterstein. Die Narkose (Julius Springer, Berlin, 1919), p. 33. 28 Meyer and also Overton believed that the indifferent narcotics accumulated most in the cortex because, according to the older analyses of the brain, the cortex is richest in lipoids. Bethe, however, pointed out that, according to more recent analyses of Thudichum, Koch and others, the white matter is far richer in lipoids than the gray; and Bethe dwelt upon this as one of the objections to this hypothesis. However, there is no good reason to suppose that interruption of the association tracts is not capable of producing narcosis as readily as direct action on the cortical cells themselves. AUGUST 19, 1921 ALSBERG : PHYSIOLOGICAL CHEMISTRY 331 meability has not been generally accepted, so the Overton-Meyer lipoid theory of narcosis is not accepted universally. Traube believes surface tension effect and not lipoid solubility is the main factor and others believe that adsorption of the narcotic by the nerve cell is the main factor.-^ This is not the place to discuss these hypotheses other than to point out that none of them considers the chemical structure of the narcotic molecule as of moment except in so far as the chemical structure of the molecule determines its physical properties. We may therefore fairly assume that in the case of the indifferent narcotics we have an apparently specific action upon a specific organ, the nervous system, dependent quite as much upon the physical properties of the narcotic as upon its chemical structure. The older pharmacologists would have said that the narcotic acts upon the nervous system specifically because the nerve cell or the nerve cell protoplasm contains a specific chemical group which has a special affinity for the narcotic and combines or reacts with it. Now these theories of narcosis explain why the nervous system attracts the narcotic, in other words, they give a simple physical explanation for the distribution of the narcotic within the body. They do not tell us in the least what the narcotic does after it accumu- lates in the cells. Concerning the nature of the action of the narcotic after it has accumulated within a cell a number of theories have been advanced. We have not yet enough experimental data to reach a decision and there is hardly time tonight for a full discussion of them. However it will be of interest to indicate the general character of some of them: — if protoplasm is essentially an emulsion or gel, one of the phases of which is oil-like, then the solution of the narcotic in the oil phase must greatly affect the character of this phase and its surface phenomena.^" There will inevitably be a tendency to change the permeability of the membranes at the interfaces with a tendency to the redistribution of the protoplasmic components to conform to new conditions. The tendency must be to change the composition of the phases relatively. If the narcotic enters into adsorption combinations with components of the cell this too must alter the relative composition of the phases. If the adsorption be upon enzyme molecules the functioning of the cell would be disturbed correspond- ingly.^^ In either event, whether the narcotic dissolves in the oil 28 H. WiNTERSTEIN, op. cit. 30 H. Meyer. Zur Theorie der Alkohol-narkose. I Mittheilung. Arch. exp. Path. u. Pharmakol. 42: 112. 1899. 31 H. WiNTERSTEIN, op. cit. p. 276, ff. 332 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 phase or forms a blanketing adsorption layer about enzyme molecules, or does both, the effect must be to hasten certain normal processes and retard others. It is a well-established fact that many narcotics retard extra cor pore many enzyme reactions, especially oxidations. It is also well established that in narcotized cells the oxidation metab- olism, that is, respiration, is dampened. That the presence of narcotics also tends to hasten some protoplasmic processes is evident from the effect of such substances on the rate of autolysis, that is, the self-digestion of cells. Even small quantities of such substances as chloroform or toluol very rapidly hasten the onset of the autolysis of cells in vitro. ^^ Apparently they hasten it because through lipoid solubility, surface tension effect, or adsorption, they disturb the balance of the protoplasmic phases with a resulting destruction of the coordi- nating mechanisms of protoplasm. ^^ The intracellular enzymes then run riot and rapid autolysis results. Perhaps physical phenomena, similar in kind if not in degree, are involved in narcosis. Certainly in chloroform narcosis katabolism is increased. It is conceivable that in the manner above suggested a substance may exercise a profound effect upon a cell without necessarily entering into a chemical union with some constituent of the cell. That such a chemical union must of necessity precede the attack of a poison upon a cell was formerly very generally assumed. In discussing phenomena of this character we must beware lest we generalize too widely. No one hypothesis is applicable to all cases. Thus there are cases in which it is perfectly well known that substances accumulate in cells because they combine chemically with some constituent of the cell. The alkaloids furnish an example. Tannic acid precipitates many alkaloids. Some algae contain tannic acid and when they are brought into solutions of the free alkaloids, the base, *2 V. Schroeder long ago showed that the autolysis of yeast went on more rapidly in the presence of a little ether than without. Evidently ether does to yeast cells exactly what it does to red blood corpuscles; it lakes them, i.e., it dissolves the lipoids of the cell-membranes making the latter permeable to intra-cellular substances, among them the enzymes. It seems that a process similar to hemolysis, called cytolysis, may occur in any cell. Probably this phenomenon underlies such pathological conditions as acute yellow atrophy of the liver which is characterized by an ante-mortem autolysis of the liver and perhaps other organs. It is quite conceivable that a toxic substance absorbed from the gut may lake or cytolize the liver cells destroying the coordination between their own ferments and setting these ferments free to work their own cells' destruction. It is significant that yellow phosphorus, chloroform and chloral hydrate, all lipoid-soluble substances, are capable, when taken by the mouth, of producing a pathological condition bearing considerable resemblance to acute yellow atrophy of the liver. 33 C. L. Alsbbrg. Mechanisms of cell activity. Op. cit. AUGUST 19, 1921 alsberg: physiological chemistry 333 which penetrates into the cells, is precipitated by the tannic acid. The formation of these precipitates may be obser\^ed under the microscope. The alkaloid being removed by precipitation, more alkaloid diffuses in until all the available tannic acid has been consumed. The alkaloid enters because the cell-membrane is permeable to it. Whether this permeability is due to lipoid solubility of the alkaloid, surface effect, or adsorption need not concern us now. Were there no tannin within the cell, only so much alkaloid would diffuse into it as is required to es- tablish equilibrium between the interior of the cell and the medium bathing the cell. More, however, passes in because a part is combined firmly with the tannin. By such a chemical mechanism, as well as in the other ways above discussed, substances may accumulate in special organs or cells. ^^ The indifferent narcotics are substances that are not dissociated. The majority of the substances which readily permeate cells are not ionized. This is beautifully illustrated by the difference in the action of the free alkaloid bases and their salts, as shown by Overton. The former are more poisonous than the latter, at least to the individual cell. The free base alone is able to pass through the cell-membrane. In a solution of the base all of it is free to pass through the membrane. The solution of the salt only contains free base to the extent that the salt is dissociated. With a base as weak as the alkaloids united with the common very powerful acids, the amount of dissociation will be very slight. The action of the salt is therefore slower than that of the free base. Analogous conditions seem to prevail in the case of inorganic salts. As a rule ions do not pass through cell-membrane and it is very doubt- ful whether the ordinary salts of the organism, most of which plas- molyze, enter cells as ions.'^' Certain inorganic salts, however, '* For other mechanisms, see W. SchulEmann, Die vitale Fdrhung in ihrer Bedeutung fiir Anatomie, Physiologic, Pathologie und Pharmakologie. Biochem. Zeitschr. 80: 1. 1917. ^ Apparently the fact that the lipoids, as shown by Thudichum, readily form colloidal solutions in water, has been overlooked by those who have speculated on the subject. Koch has shown that such solutions change the solubility of inorganic salts and render them soluble with the lipoid in ether. I myself have observed that if a solution of egg yolk in 10 per cent NaCl be extracted with ether a small amount of material giving the biuret re- action passes into the ether. A thorough study of the manner in which lipoids and proteins modify the solubility of such substances as glucose, amino-acids, and inorganic salts is needed. It may well be that it will furnish the key to the mechanism by which such food-stuffs enter cells. However, it should also be kept in mind that none of the hypotheses concerning the character of cell-membranes is capable of explaining completely the entrance into cells of all substances that undoubtedly get into them. I have been careful to 334 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 probably enter cells because they are more or less lipoid-soluble, for example, mercuric chloride, cadmium chloride and copper chloride. Perhaps for that reason they are so very toxic and antiseptic. Perhaps the best summing up of the relative importance of chemical and physical factors in determining the action of toxic agents has been given by Barger and Dale in one of their papers upon the active principles of the ergot of rye: "but it by no means follows that the peculiar distribution of the action of nicotine or of the sympatho- mimetic amines depends on the existence of specific chemical re- ceptors in the cells primarily sensitive to them, as supposed by Langley. Stimulation may be a chemical process but the fact that certain cells are preferentially stimulated by a certain group of substances such as our amines may mean that in those cells these substances readily reach the site of action; a supposition which is in accord with the view advanced by Straub." "On the whole then the least unsatisfactory view in the present state of knowledge seems to us to be that which regards the existence of stimulant activities as dependent on the possession of some chemical property, the distribution, and, in the main, the intensity of the activity as due to a physical property. "^^ This thought will help us to understand the reasoning that is used in the production of synthetic drugs, that is, the science known as chemo- therapy. Chemo-therapy is the name given to that phase of pharmacology which deals with the production of drugs for special and specific purposes. Sometimes its aim is defined more narrowly as the search for chemical agents that will cure infectious diseases, that is, agents that will act as internal disinfectants for the diseased body. Since such substances are usually more or less poisonous for the body cells as well as for the parasite, much of chemo-therapeutic research aims to so modify the molecular structure of the toxic sub- stance as to render it appreciably more toxic to the parasite than to the body cells of the host." We can then divide the aims of investigators in the field of chemo- therapy into two groups ; those that endeavor to influence the physical properties of drugs and therefore their intensity and place of action in the organisms, and those that endeavor to influence the chemical attribute to the lipoid only a part of the observed phenomena. Schulemann, for example, attributes a large role to phagocytosis, a phenomenon undoubtedly largely dependent upon surface tension effects. 3" Cf. also W. Schulemann, op. cit. 3' G. GiEMSA, op. cit. p. 190-191. AUGUST 19, 1921 ALSBERG : PHYSIOLOGICAL CHEMISTRY 335 properties of drugs and their specific manner of action. ^^ As no sharp line can be drawn between chemistry and physics so these aims of the synthetic chemist in the field of chemo-therapy can not be separated sharply. The attainment of one aim is very apt to bring the other in its train. Thus the rate of action of a drug may be accelerated or retarded by merely changing its solubility. The more soluble it is the more rapidly may it be absorbed and the more intense will be its action, since, obviously, the more rapidly it floods the body the more toxic will it be. At the same time its action is likely to be more evanescent because just as it will be more rapidly absorbed so it is apt to be more rapidly eliminated. The less soluble it is the more slowly will it be absorbed and the milder and more continuous is apt to be its action. Moreover, at the same time, changing its solubility may change the site of action of a drug as when it is rendered insoluble in the stomach but soluble in the intestines. Such an example is the tannate of an alkaloid. These tannates are insoluble in the stomach, but soluble in the intestines. Therefore not merely is their rate of action modified but the action itself may not begin until the drug reaches the intestines. The rate, the intensity, as well as the site of action have been modified by the mere change in solubility. Similar changes in the action of drugs can be brought about by making derivatives that are inactive in themselves but are decomposed somewhere in the body setting the active principle free. By such means it is possible to retard the rate and also to change the site of action. Salol, a condensation product of phenol and salicylic acid, is a good example of this sort. It passes through the acid stomach but is esterified in the alkaline intestines with the gradual liberation of its component drugs. Thus they act slowly and less intensely, exerting local antiseptic action in the intestines and, after gradual absorption, continuous systemic action. A similar result is accom- plished in the administration of inorganic substances if converted into un-ionized organic compounds. Such compounds may reach the tissues before they are decomposed, exerting their action at the site of decomposition. Salvarsan and its congeners are examples of this kind. They are organic compounds of arsenic which are but slowly decomposed within the tissues. By their use it is possible to keep the body continuously under the influence of arsenic without serious toxic symptoms. No doubt a part of the value of salvarsan is due to the '* S. Fraenkel. Die Arzneimittelsynthese auf Grundlage der Beziehungen zwischen chemischen Aufbau und Wirkung. (J. Springer, Beriin, 1912.) 336 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 fact that it is retained in the system a long time and but slowly de- composed. In a very similar manner it is possible to make an element's action milder, more continuous and free from local irritant action. Iodoform is a case in point. Its action is that of iodine; but iodine itself is too powerful for local application to wound surfaces. Iodo- form is slowly decomposed on wound surfaces subjecting them to the mild continuous action of iodine so that there is little local irritation. Except for salvarsan, the cases just given are examples in which the modification of the action of the drug was in the main designed to accomplish a modification of the intensity and site of action of a well-known drug substance rather than to modify its specific action or to create a new drug with a modified specific or even a totally new physiological action. The investigations and the line of reasoning which lead up to the production of the valuable local anesthetic, novocaine, are perhaps typical of the latter form of chemo-therapeutic research. The object of these investigations was to develop a drug with the local anaesthetic action of cocaine but devoid of its objection- able toxic effects. Ecgonine, the mother substance, of cocaine, has the following formula: CH (COOH) CH (OH) Kinhorn^^ discovered that if he esterified the carboxyl (COOH) group of ecgonine with a methyl (CH3) group and the hydroxyl (OH) group with a benzoyl group (CO.CeHr,) he obtained the very anaesthetic natural base cocaine : c coo CHs CH O CO CeH. This led him to make a large number of benzoyl esters, many of which ^'A. EiNHORN. Ueber neue Arzneimittel, Ann. d. Chemie 371: 125. 1909. AUGUST 19, 1921 ALSBERG : PHYSIOLOGICAL CHEMISTRY 337 were anaesthetic. Indeed Filehne^" concluded that the benzoyl group was responsible for the anaesthetic action. The action may be lacking if there are interfering groups such as the carboxyl (COOH) group of ecgonine. Moreover it was found that when, as in cocaine, the benzoyl group was combined with a nitrogen-containing nucleus its action became most apparent. Thereupon a large series of nitrogen-contain- ing nuclei were benzoylated and it was found that so complex a nitrog- enous nucleus as that of cocaine was not necessary. Many of these benzoyl esters derived from quite simple nitrogen-containing nuclei were found to have anaesthetic action. The first very simple sub- stance of this type to find a practical use was orthoform, which is the methyl ester of para-amino-meta-oxybenzoic acid: COOCHs The objection to this compound is that it is too insoluble while its salts are too irritant. It was therefore necessary to make soluble derivatives. This was done by combining it with glycocoU (amino- acetic acid) derivatives. Thus there was produced a substance which has been used practically, nirvanin, the methyl ester of di-ethyl- amine-acetyl-para-amino-ortho-oxy-benzoic acid : NH CO CH2 N(C2H6)2 A .OH COOCH3 Further investigation showed that still greater simplification was possible by the elimination of the hydroxyl group. This led to the development of procaine, known by the trade name of novocaine, the soluble hydrochloride of para-amino benzoic acid di-ethyl-amino- ethyl ester or para-amino-benzoyl-di-ethyl-amino ethanol : NH2 ' COO-CH2-CH2N(C2H5)2HCl This is quite a simple substance as compared with cocaine and easily made synthetically. Another simplification is the removal of the *° W. FiLEHNE. Die local anaesthesirende Wirkung von Benzoylderivaten. Berliner klin. Wochenschr. 24: 107. Feb. 14, 1887. 338 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 amino (NHo) group from the ring as in stovaine and alypine. However, the power to anaesthetize the sensory nerve endings is not limited to basic substances like those above described. Many substances quite unrelated to them possess this power to a greater or less degree, such as antipyrine, certain inorganic salts, quinoline derivatives, phenolic and aromatic side-chain alcohols."*^ Some of the latter, like benzyl alcohol, phenethylol, benzoyl carbinol and saligenin, promise to compete with substances of the procaine type. That so many substances of such varying molecular configuration exhibit similar physiological action arouses the suspicion that, as in the case of the indifferent narcotics, some as yet unrecognized common physical property is concerned in their action. Significant in this connection is the fact that Schleich modified the method of terminal anaesthesia by showing that if hypotonic solutions, that is, solutions of a lesser osmotic concentration than the blood, be injected under pressure until the tissues become rigid, the concentration of the anaesthetic necessary to prove effective is reduced. Now either hypotonic or hypertonic inorganic salt solutions tend to produce local anaesthesia by themselves, perhaps through merely causing swelling or shrinking of the cells, that is partial plasmolysis.^- It is also signif- icant as bearing on the possibility of some common physical property of the local anaesthetics that Gros^^ presents evidence that bases like cocaine and procaine are made more active if set free by sodium bicarbonate from their salts, presumably because they, like other alkaloids, enter cells most readily as the free base.^^ The type of reasoning and experimentation which made a new era in surgery possible through the development of such substances as pro- caine is not limited to the production of new and valuable drugs. It has been applied with success to the production of new perfumes, of new antiseptics^^ and new flavoring materials. As an example of the application of this manner of reasoning in the production of flavoring substances may be cited the work of E. K. Nelson in the Bureau of Chemistry upon capsaicin, the pungent principle of red pepper. Nelson first determined that capsaicin is a ^1 H. G. Barbour. Local anaesthetics. Science N. S. 51: 497-504. May 21, 1920. *2 Barbour, op. cit. ^3 O. Gros. Ueber die Narkotika and Lokalanaesthetika. Arch. exp. Path. u. Phar- makol. 63: 80. 1910. " Cf. supra, p. 333. *^ E. p., Dakin's Di-chloramin T. AUGUST 19, 1&21 ALSBERG : PHYSIOLOGICAIv CHEMISTRY 339 vanillyl-decenoyl amide. ^^ OCH3 HO—/ y—CUt NH COC9H17 He thereupon made a series of homologous vanillyl-acyl amides with acids of different molecular weights.^' He found that with increasing molecular weight there was an increase in pungency up to a maximum beyond which it decreased. Table 2 gives the relative pungency of these substances, capsaicin being rated at one hundred. TABLE 2. — Comparative Pungencibs of Vanillyl-Acyl Amides Vanillyl n-hexoylamide 5 Vanillyl n-heptoylamide 25 Vanillyl n-octoylamide 75 Vanillyl n-nonoylamide 100 Vanillyl n-decoylamide 50 Vanillyl n-undecoylamide 25 Vanillyl n-dodecoylamide 25 Vanillyl undecenoylamide 25 This phenomenon of increasing intensity of physiological action up to a maximum with increase in molecular weight and a diminution beyond the maximum with still further increase in molecular weight is a phenomenon that has been observed frequently. ^^ There is good reason to believe that it is due, in part at any rate, to changes in solubility. For example, for a substance to be odorous it must be sufficiently soluble in both water and lipoids, since the cells of the mucous membrane of the nose are covered by a watery fluid and have in all probability a lipoid semi-permeable cell membrane. ^^ Thus in the homologous series of pungent substances of table 2 the solubility in water decreases with rising molecular weight while the solubility in ether increases. Perhaps this is a plain case in which the manner of action, that is, pungency, is a function of the chemical structure of the molecule, while the intensity of action is dependent upon the physical property of solubility. Perhaps the specificity of the pungent action is not to be sought in the substances so much as in the taste buds of the tongue, according to the well-known physiological law of the specific response of the nerve end-organs. Any stimulus gives the *^ E. K. Nelson. The constitution of capsaicin, the pungent principle of capsicum. Journ. Amer. Chem. Soc. 41: 1115. 1919. *'' E. K. Nelson. Vanillyl-acyl amides. Journ. Amer. Chem. Soc. 41: 2122. 1919. *^ Th. H. Durrans. The relationship between odour and chemical constitution. Per- fumery and Essential Oil Record 10: 107-132. London, May 21, 1919. *' Backmann. Journ. physiol. path. gen. 17: 1. 340 JOURNAIv OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 sensation peculiar to that organ. The capsaicin series is highly irritating to all cells. Perhaps the sensation of pungency is only the effect of the irritation of specific cells on the tongue. The type of reasoning and of investigation above discussed has been used only recently to produce new repellants for insects, to combat human parasites. Moore and Hirschfelder^° have made such a study upon the body louse and have demonstrated that the impregnation of the garments with certain halogenated cresols will repel this parasite for considerable periods. It would seem that here is a wide field for work. Research similar to that of Moore and Hirschfelder should lead to the discovery of repellants for such pests as black-flies and mosquitoes, a boon not merely to those who frequent the swampy lands of our continent but also to those who live in malarial regions. While Moore and Hirschfelder and a few others have made a be- ginning in this sort of research in relation to insects troublesome to man, but little work has been done to improve or devise better insecticides and fungicides useful in agriculture. The economic losses from insect and fungous ravages are enormous. Despite such losses we have been content with relatively few simple insecticides and fungicides. The organic insecticides in present use are largely natural plant substances such as the poisons of the hellebore and larkspur, pyrethrum, and nicotine from the tobacco plant. In addition, cyan- ides, long known to be poisonous, and mineral oil emulsions are also used. Recently the employment of certain war gases has been ad- vocated. Of the inorganic insecticides, arsenates, known for centuries to be poisonous to higher animals, and lime and sulfur sprays represent obvious and readily available substances. The use of fluorides represents a rather distinct and valuable discovery. No really synthetic organic substance has come into use as an insecticide. It is evident that the range of our insecticide and fungicide armamen- tarium at the present time is very narrows There is no reason why this range could not be extended vastly by the development of a sister science to chemo-therapy, a science for which I venture to propose the name chemo-phy to- therapy. The aim of chemo-phyto-therapy would be to protect plants from the attacks of microorganisms and insects just as the aim of chemo-therapy is to protect animals from such attacks. As chemo-therapy demands the working together of pharmacologists and chemists, so chemo-phyto-therapy would demand ^0 W. Moore and A. D. Hirschfelder. An investigation of the louse problem. Re- search Publ. Univ. Minnesota 8: No. 4. July, 1919. AUGUST 19, 1921 WATSON: LAMPROPHYRE DIKE 341 the working together of entomologists, of pathologists and of chemists. The entomologist indeed has a twofold task. Not merely must he test out the substances created by the chemist, but he must also create the science of the pharmacology of insects. Some desultory work of this type has been done in the past. The Bureau of Entomology of the U. S. Department of Agriculture from time to time has tested out numerous substances, often by-products for which no other use was apparent, such substances as naphthols, cresols, crude pyridin bases and many others. These were all found to be comparatively worthless for one cause or another. Few if any systematic studies in which the chemist and the entomologist cooperated seem to have been made. Such studies are now in progress through the cooperation of the Bureau of Entomology and of the Bureau of Chemistry. Notable progress has been made and it is hoped that a solid foundation will be laid for a new science — chemo- phyto-therapy. My hope in addressing you was to give you a conception of the pharmacologist which is perhaps not generally current and to indicate to you how fundamental are some of the problems with which he deals. If I have succeeded in arousing your interest in this science and if in so doing I have demonstrated to you that the action of chemical substances upon living things is quite as much a function of the physi- cal properties of such substances as it is of their molecular structure, then I have achieved the goal that I set for myself this evening. PETROLOGY. — Petrography of a lamprophyre dike cutting a pyrite body in Boyd Smith Mine, Louisa County, Virginia.'^ Thomas L. Watson, University of Virginia. The important large lens-shaped bodies of pyrite in Louisa County, Virginia, so vigorously worked for many years, are inclosed in schists of probable Cambrian age. These pyrite bodies, as well as the more or less closely associated gold deposits, are genetically related to intrusions of plutonic igneous rocks which are exposed in large masses in fairly close proximity to the ore bodies. The ore-bearing schists are also intruded in places by dikes of both acidic and basic igneous rocks, the latest of which is diabase of Triassic age. Although the area is one in which igneous rocks, in part younger than the ore bodies, are fairly common, and in which mining operations have been in progress for a long period of years, not until recently 1 Received June 16, 1921. 342 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 has a single instance been known where the pyrite bodies were intruded by igneous rocks. The object of this paper is (1) to place on record observations of the only known case of a pyrite body in one of the principal pyrite mines of Virginia that is cut by a dike of igneous rock, and (2) to give a petrographic description of the rock, since it is unlike the usual types of basic igneous rocks found in the Virginia Piedmont province, and for the added reason that the mine is closed and is no longer accessible. OCCURRENCE The lamprophyre dike^ described in this paper cuts the pyrite body in the Boyd Smith mine which is located about 2 miles north of Mineral, Louisa County, Virginia. The mine is one of a group of pyrite mines located near Mineral that have yielded large tonnages of ore. Accord- ing to Mr. Neustaedter, the dike was encountered in mining pyrite near the north heading of the so-called "west vein" on the first level about 100 feet below the surface. The ore body at this level is about 8 feet wide, strikes approximately N. 25° E., and dips to the southeast about 60°. The dike does not exceed one foot in thickness, cuts the pyrite body in an east-west direction, and dips about 85° south. The same dike was also observed cutting the "east vein" of pyrite. There is no evidence of the dike on the surface. PETROGRAPHY Megascopic characters. — The general appearance of the rock is that of a typical porphyritic basalt. It is massive and of dark blue- gray color, with small phenocrysts of biotite and nearly black pyroxene in roughly equal amount set in a dense aphanitic groundmass. Polished surfaces of the rock are uniformly darker (nearly black) in color, with groundmass and phenocrysts rather strongly contrasted. The dark minerals, biotite and pyroxene, are the only ones rec- ognized in the hand specimen. Biotite, in small glistening crystals up to 2 mm. in diameter, but usually less than 1 mm., is seemingly more abundant than pyroxene in the hand specimen, but not in the thin section. Pyroxene, nearly black in color, is developed in lath- like prismatic crystals up to 5 mm. long and 1>2 mm. thick, and in 2 Credit for the discovery of the dike belongs to Mr. A. Neustaedter, former mining engineer in charge, to whom the writer is indebted both for a statement of facts relat- ing to its occurrence and for a hand specimen of the rock. The discovery of the dike in 1917 by Mr. Neustaedter was communicated to the writer and a hand specimen sent, but pressing duties prevented the earlier preparation of a statement of the interesting occurrence. AUGUST 19, 1921 WATSON: LAMPROPHYRE DIKE 343 short prismatic nearly equant crystals up to 4 mm. in diameter. The density of the specimen analyzed is 3.065. Microscopic characters. — In thin section the rock shows considerable alteration, especially the goundmass, which is composed chiefly of clay substance admixed with more or less chloritic and serpentinous material, derived probably from either feldspars or feldspathoids or both. Neither feldspar nor glass was observed in the thin section studied, although both may have been present originally. The groundmass of the composition indicated above was roughly estimated at 30 per cent. Phenocrysts of biotite, augite, and altered olivine make up probably 60 per cent or more of the rock. Augite and much of the biotite are usually fresh, but olivine is completely altered. The ore minerals, titaniferous magnetite and apatite, the former predominating, make up chiefly the remaining 10 per cent of the rock. No evidence of the presence of sulfide minerals was indicated in either the hand specimen or the thin section. Biotite is of the type usually characteristic of the lamprophyres. It exhibits intense pleochroism in shades of light and dark brown, and in part dark-colored resorption rims. Much of it is entirely fresh, but some has altered to a faintly pleochroic red substance without trace of cleavage. It usually contains some inclusions. Pyroxene is the variety augite near diopside in composition. Most of it is colorless but some individuals show narrow faintly pleochroic borders indicating some admixture of the aegirite molecule. Faint violet shades indicating the presence of titanium are also noted. The average extinction angle varies from 35 to 40 degrees. The augite occurs in several generations and probably formed during the entire period of crystallization of the rock. It is developed in subhedral short nearly equant and in elongated prismatic (bladed) crystals, the latter being predominant and so closely resembling in outline lath- shaped plagioclase in diabase as to suggest diabasic texture. In extreme cases the augite prisms are more than six times longer than thick. A pronounced zonal structure is usually developed in the nearly equant crystals, and some show hour-glass structure. Some crystals show a green core that is faintly pleochroic and sharply defined from the outer colorless part of the individual; others have a pale green faintly pleochroic outer zone enveloping a colorless core. The microscope indicates augite low in iron and in part titaniferous. Cleavage is usually well developed in the nearly equant crystals and 344 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOIy. 11, NO. 14 to a less degree in the lath-like forms. Twinning is observed in one or two of the crystals. Olivine, originally present in amount roughly estimated at 18 per cent, is completely altered to greenish yellow serpentine, but the outlines of the original mineral are usually well preserved, CHEMICAL, COMPOSITION The composition of the rock is shown in the chemical analysis given in table 1 . It is regretted that fresher material was not available for analysis, for the high water content (5.21 per cent) indicates considerable alteration of the rock, a fact fully confirmed by microscopic study. TABLE 1. — Analysis and Norm of Lamprophyre Dike, Louisa County, Virginia. S. D. GoocH, Analyst Si02 37.40 or 15.01 AI2O3 18.60 ab 4.19 Fe203 6.35 an 40.87 FeO 7.95 di 0.68 MgO 3.80 hy 11.67 CaO 11.57 ol 0.48 Na20 .' 0.50 mt 9.28 K2O 2.53 il 7.45 H2O- 1.89 ap 4.70 H2O + 3.32 Ti02 : 3.89 Symbol: II(III).5.4.2. P2O5 2.04 MnO 0.23 No name for II. 5. 4. 2. in the - — ■ — "Quantitative System." 100.07 Sp. Gr 3.065 Because of the altered condition of the rock the norm and mode do not agree. There is no name yet for the position in the "Quantita- tive System" of classification in which the rock falls, or for the next one in salfemane, but it is so altered (over 5 per cent of water) that it seems not advisable to propose one. The high K2O is undoubtedly contained in the biotite; Ti02 mostly in the titaniferous magnetite or ilmenite, but partly in the augite, and probably to some extent in the biotite ; while the high P2O5 is derived from apatite, which is present in larger amount than is usual for the average rock of this type. AGE The exact age of the dike is unknown. The ore body which it cuts is one of several of similar composition occurring in the same district in Cambrian schists. The pyrite bodies are genetically re- lated to intrusions of granitoid rocks that may be later but not older AUGUST 19, 1921 abstracts: optics 345 than Cambrian, and with which the dike may possibly be correlated as a late differentiate. The youngest known igneous rocks in the dis- trict are dikes of Triassic diabase to which the dike cutting the pyrite body bears no resemblance as it is the first of its kind to be described from the Virginia Piedmont province. It cannot be older than Cam- brian and may be as late as Triassic. The rock is more closely allied in mineral composition and structure with the Triassic dikes of basic igneous rocks than with the igneous bodies of earlier age occurring in the area. For these reasons the writer regards the dike as being probably not older than Triassic. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. OPTICS. — Dispersion in optical glasses: I. Frkd. E. Wright. Journ. Opt. Soc. Amer. 4: 148-159. 1920. (Geophysical Lab. Papers on Optical Glass, No. 27.) If partial dispersions alone are considered and plotted one against the other, the result in each case for a series of optical glasses is a straight line. This fact, that in a series of optical glasses the partial dispersions are re- lated by linear functions and that these functions are the same for all glasses, proves that, if a single partial dispersion is given, the entire dispersion-curve is fixed, irrespective of the type of glass. This means that within the limits to which this statement holds, namely, about one unit in the fourth decimal place, if any partial dispersion is given, all other dispersions follow auto- matically. Thus, a series of standard dispersion-curves can be set up in- dependent of the absolute refractive index. This means that if for any substance two refractive indices be given, the dispersion-curve can be written down directly; that in case two substances of very different refractive indices are found to have the same actual dispersion for one part of the spectrum their dispersion-curves are identical to one or two units in the fourth decimal place throughout the visible spectrum. From these relations it is possible to build up dispersion formulas containing two, three, or more constants which represent the data in the visible spectrum with a high degree of exactness. Certain of these formulas are of such form that they are valid far into the infra-red and ultra-violet, but break down of necessity as an absorption band is approached. Certain of the dispersion formulas thus obtained are well adapted for computation purposes. F. E. W. GEODESY. — Elements of map projection with applications to map and chart construction. Charles H. Deetz and Oscar S. Adams. U. S. Coast and Geodetic Survey Spec. Publ. 68 (Serial 146). Pp. 163, figs. 74, pis. 8. 1921. The aim of the authors is to present in simple form some of the ideas that lie at the foundation of the subject of map projections. Many people have rather hazy notions of what is meant by a map projection, to say nothing of the knowledge of the practical construction of such a projection. 346 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 The subject matter is divided into two parts which are intended to meet the needs of such readers. The first part treats the theoretical side in a way that is as simple as it can be made; the second part takes up the con- sideration of the practical construction of some of the most important pro- jections, the intention of the authors being to give such detailed directions as are necessary to present the matter in a clear and simple manner. The use of mathematical analysis in the first part is studiously avoided since the intention is merely to illustrate the way in which different kinds of projection may arise when we attempt to produce maps with specific properties. Both the first and second part are profusely illustrated with figures that serve to make clear the statements of the text. The projections described in the second part belong mainly either to the conformal class or to the equal-area class. Several tables for projections are included, the most important being that of a Lambert-zenithal equal- area projection for the United States or for North America with center on the parallel of 40°, that of an Albers equal-area projection for the United States, and finally, the most important of all, that of a general Mercator projection. As a closing section of part two and of the whole treatise, some general con- sideration is given to world maps, that is, to maps that are intended to in- clude as great an extent of territory as a hemisphere or in certain cases to represent the whole sphere. C. H. D. and O. S. A. PETROLOGY. — halite: a new leucite rock. Henry vS. Washington. Amer. Journ. Sci. 50: 33^7. 1920. Atti. Accad. Lincei 29: 424-435. 1920. A detailed account of the new leucite rock first described in this Journal 10: 270-272. 1920. ZOOLOGY. — Report on the ophiurans collected by the Barbados-Antigua Expedition from the University of Iowa in iqi8. Austin H. Clark. Univ. Iowa Studies. Studies in Natural History, 9 (First Series No. 45), No. 5, 29-63. March 15, 1921. A history of the study of the ophiurans of the Caribbean region is given, with a list of the more important papers ; the Caribbean echinoderm fauna is discussed, and the peculiarities of the West Indian ophiuran fauna are ana- lyzed and compared with those of the crinoid fauna of the same region; the discontinuous distribution of the echinoderms is discussed and explained as resulting from the extirpation of ancient types from the more favorable areas in the sea so that they now exist only in isolated localities representing the extreme limits of their original habitat; a complete list of the West Indian ophiurans is given; the occurrence of these animals at Barbados and at Antigua is described, and all previous records from these islands are given; the specimens secured by the expedition are described in detail. A. H. C. ENTOMOLOGY.— r/ie ants of the Fiji Islands. W. M. Mann. BuU. Mus. Comp. Zool. Harvard 64: 401-499, figs. 1-38. No. 5, 1921. This is a report of the ants collected by the writer while in Fiji as Sheldon Traveling Fellow of Harvard. The insects of Fiji are not well known ; hither- to but 53 species of the order Hymenoptera had been recorded from the islands. The present paper lists 78 species of ants, including many new species and several new genera and subgenera. Certain genera of ants are well developed in Fiji, among them the genus Camponotus, which is represented by ten forms belonging to a subgenus {Myrmegonia) which is confined to AUGUST 19, 1921 proceedings: philosophical society 347 the islands. About 70 per cent of the species listed are supposedly endemic This number of endemic forms is an unusually high percentage for an island favma and indicates a very long isolation. In a preUminary discussion of the zoogeographical position of the islands it is shown that the ant fauna is not related to that of any one region but consists chiefly of types that formerly were of wide distribution and thus supports the idea that Melanesia has served, as far as the land fauna is con- cerned, as a biological conservatory. Fiji is the eastern limit of this region and has been isolated longer that the islands further west. W. M. M. ENTOMOLOGY. — Diptera of the superfamily Tipuloidea found in the Dis- trict of Columbia. C. P. Alexander and W. L. McAtee. Proc. U. S. Nat. Mus. 58: 385-435, pi. 26. This paper forms another one of the series of insect papers which endeavors to make it possible for local workers to become acquainted with the fauna of the District of Columbia and vicinity. The insects belonging to the superfamily Tipuloidea were commonly called crane-flies, and this paper tabulates all the species known to occur locally, gives notes on the habits of the adults and larvae, and distribution and dates of flight of the various species. The introduction briefly summarizes the history of this science as far as pertains to this region and the paper is followed by a bibliography of titles. One plate illustrates the venation, 40 genera are included. Of the species listed 87 are described from material which was collected in this region, chiefly by the activities of the late C. R. Osten Sacken. S. A. Rohwer. ENTOMOLOGY. — A revision of the North American species of Ichneumon- flies belonging to the genus Apanteles. C. F. W. Muesbeck. Proc. U. S. Nat. Mus. 58: 483-576. 1921. The Ichneumon-flies of the genus Apanteles are small, usually black, insects which in the larval stage are parasitic on the larvae of lepidopterous insects. The above-mentioned paper is a revision of the species of North America, including the West Indies. The revision is based largely upon the extensive collections of the National Museum and 164 species are recog- nized. The types of most of the species have been studied by the author and besides pointing out some synonymy he has described 36 new species. The descriptive part of the paper is preceded by a synoptic key and followed by an aphabetical list of hosts, and a species index. S. A. Rohwer. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 849th meeting The 849th meeting of the Philosophical Society of Washington was held in the Assembly Hall of the Cosmos Club on March 26, 1921. It was called to order by President Faris, with 65 persons present. The program was as follows : O. S. Adams: Authalic latitude, a cartographic expedient. (Illustrated.) It has been found by many scientific investigations of various kinds that the shape of the earth, as a whole, is very nearly that of an ellipsoid of revo- lution with the equatorial diameter about 26 miles longer than the polar diameter, the axis of rotation of the generating ellipse. It is evident that 348 JOURNAL OF THE WASHINGTON ACADEJMY OF SCIENCES VOL. 11, NO. 14 some regular body of this kind must be adopted to form the surface of ref- erence for geodetic investigations as well as for geographical purposes; any irregularities that may be found to exist are viewed as departures from this regular form and can be taken into consideration, as such, whenever necessary. Since this spheroid is taken as the surface of reference, it becomes the problem of cartography to take it into account in all mapping projects. It is comparatively easy to determine projections of various kinds for the sphere; hence mapping can be simplified if we determine an intermediate projection of the spheroid conformally upon a sphere with radius equal to the equatorial radius of the earth. This is done by applying a correction to the geodetic latitude and results in what is called the isometric latitude. In considering equal-area mapping of the spheroid with this fact in mind, the idea arose that the spheroid could be projected equivalently upon a sphere of equal surface by computing a correction to the geodetic latitude, the longitude being left unchanged just as in the case of the conformal mapping. This sphere could then be mapped upon the plane by any desired equal-area projection, and the result would be an equal-area projection of the spheroid. This idea of an intermediate projection was then developed analytically and the resulting latitude has been christened Authalic latitude. The term "authalique" was used by Tissot as a general term for equal-area. Authalic latitude is therefore "equal-area" latitude. The difference between the geodetic latitude has been developed in a Fourier series and tables computed for every half degree of latitude. These results are published in U. S. Coast and Geodetic Survey Special Publication No. 67, entitled Latitude developments connected with geodesy and cartography. The paper was discussed by Messrs. C. A. Briggs, Pawling, Sosman and William Bowie. E. A. EcKHARDT and J. C. Karcher: A chronographic recorder of radio time signals. (Presented by Mr. Eckhardt, and illustrated with slides and a demonstration of the apparatus.) The radio time signal recorder described in this paper was devised at the Bureau of Standards for the field use of the Coast and Geodetic Survey. By its use the Survey will be enabled to record simultaneously on a chrono- graphic drum the time signals sent out by Annapolis on the breaks of the local chronometer without mutual interference. Radio signals originating at Lyons, France, maybe recorded at the Bureau of Standards whenever that station is sending, the air line distance between sending and receiving stations being approximately 3800 miles. It is inferred, therefore, that the sensi- tivity of the apparatus is sufficient to record Annapolis time signals at any field station which the Coast and Geodetic Survey may occupy anywhere within the borders of the United States. The apparatus is sufficiently rugged for field service, and a 50-foot, 6-wire flat-top antenna 40 feet above the ground is sufficient for all ordinary con- ditions. The radio apparatus proper may be used with any kind of chronograph drum or tape recorder. Dot and dash signals are indicated by short and long excursions of the recording pen from the datum line. In an Annapolis time signal these excursions are Vs of a second long, while the pen traces the datum line during 2/3 of every second. The receiver equipment includes a regenerative electron tube circuit in the plate circuit of which there is a telegraph relay. This regenerative circuit starts to oscillate when the grid potential is made to exceed a certain critical AUGUST 19, 1921 PROCEEDINGS : PHILOSOPHICAL SOCIETY 349 value. The passing of the circuit from the non-oscillating to the oscillating state results in a rise in plate current sufficient to operate the telegraph relay. The operation of the relay results successively in a pen excursion and in the killing of the local oscillations. The circuit is thus restored to the receptive state and the pen to the datum line. A very small change in grid potential is sufficient to start oscillations if the grid potential is initially adjusted to a value near to and just below the critical potential. This potential rise may be provided by a radio signal received on an antenna suitably related to the regenerative circuit. The circuits are so located that during the reception of radio signals the breaks of a local break-circuit chronometer may be recorded simultaneously by means of the same pen. This obviates lags which would be encountered if independent pens were used. 850th meeting The 850th meeting of the Philosophical Society was held in the Auditorium of the Cosmos Club on April 9, 1921. It was called to order by President Paris with 31 persons present. The first paper, on Mollier diagrams, by E. F. MuELLER and C. H. Myers, was presented by Mr. Myers and was illustrated. In 1904 Mollier published an article^ in which he described the properties of heat content and its uses in refrigeration problems. This article is illus- trated with (1) a heat content-entropy diagram with rectangular coordinates for steam, (2) a heat content-entropy diagram with oblique coordinates for CO2, and (3) a heat content-pressure diagram for CO2. In the present paper the properties and uses of heat content were discussed, and illustrations of six diagrams shown in which the ordinates were heat content and the abscissas were entropy (rectangular coordinates), entropy (oblique coordinates), volume, log volume, log pressure, and a scale of pressure corresponding to a uniform scale of saturation temperature, respectively. The choice of coordinates is a matter determined by conditions. Where the whole range from saturated liquid to a considerable superheat in the vapor is required the heat content-entropy diagram is poor even with the oblique coordinates since it covers only a small portion of the paper and the lines cross at sharp angles. The use of volume as abscissa is very little if any improvement, although the use of log volume is much better. The diagrams in which a function of the presstu-e serves as abscissa are very read- able, although the pressure corresponding to a uniform temperature scale is probably the best when the diagram does not extend above the critical. Some function of the heat content might be used for the ordinate in order to magnify the scale in parts desired to be especially accurate. The use of uneven coordinates should cause very little trouble if sufficient lines are entered in the diagram so that linear interpolation may be used. The second paper, on The heating of substances by expansion, was presented by Mr. ly. H. Adams, and was illustrated. The pressure to which a fluid is exposed may be released by three princi- pal methods : (1) Isentropic expansion, i.e., at constant entropy. (2) Isenergic or explosive expansion, i. e., at constant energy. * Zeitschr. Ver. Deutscher Ingen'.eure. 350 JOURNAI. OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 (3) Isenkaumic or extrusive expansion, z. e*. at constant cnkaumy,^ or constant heat content. These three methods were discussed and attention was called to the large heating effects when liquids are expanded according to (3). Thus, water by expansion through a porous plug from a little over 4000 atmospheres should heat itself from 20 deg.' to 100 deg. C. Although the ordinary thermodynamic equations are applicable only to fluids, at pressures far in excess of their ultimate strength solids fulfill to a sufficient extent the condition of equality of pressure in all directions, and therefore the equation for isenkaumic expansion may be applied to such phenomena as the extrusion of wires and other solids through small openings. The paper was discussed by Messrs. White, Mueller, C. A. Briggs, and Humphreys. The third paper, on Specific and latent heats of nickel and monel metal, was presented by Dr. W. P. White, and was illustrated. The addition of heat makes all bodies hotter, but the amount of heat re- quired to raise a body 1 degree is different for different bodies. This quantity is the specific heat. It has important relations with the nature of atoms and energy. The principal key to this relation was one of Einstein's earlier discoveries. The specific heat at high temperatures is also of practical im- portance in the treatment of metals, fire brick, and all materials which have to be heated or cooled. An important economy in portland cement manu- facture was effected some years ago by a recovery of heat based on a knowl- edge of the specific heat of the cement at high temperatures. The simplest way to determine specific heat is to give a sample of the material in question a known amount of heat by means of an electric heater, measuring the change in temperature produced. This method works best in a vacuum and at low temperatures where the heat losses are small. It is almost the only method used at the low temperatures of liquid air and liquid hydrogen. Its value at high temperatures is questionable, and it has been little used. The irregularity which is unavoidable in most electric furnaces and the very rapid rate of heat loss at such temperatures are both difficulties. It is possible that by improved technique this method might be used at high temperatures. If so, it would be a very interesting research. A more successful method at high temperatures is to heat a body in a fur- nace and then drop it into a water calorimeter so that the most difficult measurement, the measurement of heat, is carried out at room temperatures with all the refinements of modern technique. The only thing to be done in the furnace is then the heating of a body to constant temperature, for which abundant time can be allowed. The greatest source of error is still in the furnace, but this can be diminished if the distribution of temperature within the furnace is carefully studied. If the material is a metal which will oxidize in air it must be protected. One very ingenious method had been the inclosing of the furnace in a high vacuum. A long tube, also evacuated, led down into the calorimeter so that the body was in a vacuum from begin- ning to end. In work at the Geophysical Laboratory, the metal specimens were sealed up bulbs of sihca glass which held up to 1450° C, the melting point of nickel, although they were somewhat soft at that temperature. Ordi- nary glass would have run like molasses in April at this temperature. The heat that may be lost in dropping the body through the air is not so serious as might be supposed, but it cannot be neglected. This source of error was ^ A proposed new term derived from the Greek Kavixa, heat. AUGUST 19, 1921 SCIENTIFIC NOTES AND NEWS 351 eliminated in the present work, by first dropping empty containers and sub- tracting the heat given out by the empty container. If the heat loss is the same in each drop the subtraction eHminates it. To keep it the same it has been found necessary not to allow the escape of steam, which is likely to be irregular. Hence, second, the calorimeter contained a steam dome into which the steam could rise without getting out. A quick drop has often been accomplished by melting a platinum wire from which the specimen was hanging. After considerable trial a mechanical arrangement for drop- ping has been developed which is more convenient and less expensive. It was necessary to find a suitable material and then a compact design not calling for great strength. The only results for many metals at high temperatures were recently ob- tained by three German investigators, who used the vacuum-closed furnace already mentioned. The results obtained in the Geophysical Laboratory for the latent heat of nickel were about 30 per cent higher than theirs. It is beheved that the Geophysical Laboratory method, though simpler and easier to carry out, was free from several sources of error caused or aggravated by the limitations of working in vacuum, and that the result obtained at the Geophysical Laboratory, 73 calories per gram for the latent heat of nickel, is accurate at least to 5 per cent. The paper was discussed by Messrs. FooTE, Mueller, Sosman, and others. H. H. Kimball, Recording Secretary. SCIENTIFIC NOTES AND NEWS Observations have recently been made by a Coast and Geodetic Survey party on the Explorer to verify the magnetic disturbance reported in the vicinity of Sentinel Point, southeastern Alaska. The maximum disturbance was foimd to be just west of the Point, the ship's compass changing its di- rection 55 degrees within a very short distance. The disturbance extends entirely across Port Snettisham, at one place amounting to more than 20 degrees in midchannel. The securing of sea-water densities and temperatures has been begun by the Coast and Geodetic Survey observers at Portland, Maine, and Boston, Massachusetts. It is the intention of the Survey to secure similar obser- vations at all the principal tidal stations. At the invitation of Mr. Northcott, owner of the Luray Caverns, Virginia, Dr. AlES Hrdlicka of the National Museum visited the caverns on June 27 for the purpose of examining and removing certain bones, enclosed in stalagmite, which were believed to be human. After considerable difficulties, the entire deposit containing the bones was taken out in pieces which showed the remains of most of the parts of a human skeleton ; but no trace remained of the skull with the exception of a portion of the lower jaw. The specimens have been donated to the Museum for further study. The headquarters of the Chemical Warfare Service in Washington have been moved from the temporary buildings at 1800 Virginia Avenue to the seventh wing of the Munitions Building. The Fixed Nitrogen Research Laboratory, together with about a half million dollars from the original appropriation made for the investigation of nitrogen fixation, was transferred on June 30 from the jurisdiction of the War Department to the Department of Agriculture. The Laboratory is now an independent unit of the Department of Agriculture, under the direction of 352 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 14 Dr. Richard C. Tolman, who has the assistance of an advisory com- mittee made up of a representative of the War Department and representa- tives of the agricultural bureaus which are directly interested in the fixation of nitrogen. It is expected that the present allotment will maintain the Laboratory about two years. A farewell dinner to Dr. Carl h. AlsbERG, chief of the Bureau of Chemistry, U. S. Department of Agriculture, was given at the Cosmos Club on June 17 by the chiefs of bureaus of the Department. Dr. Alsberg left Washington in July to become director of the new Food Research Institute established by the Carnegie Corporation at Stanford University, California. Mr. Charles H. Behre, Jr., of Illinois, has been appointed assistant geologist with the U. S. Geological Survey. The following have been appointed geologic aids with the U. S. Geological Survey: Messrs. WilmoT H. Bradley, of Connecticut; PlaTT C. Benedict, of Massachusetts; James Gilluly, of Washington; Harold W. Hoots, of Kansas; Kenneth K. Landes, of Washington; and Lloyd W. Fisher, of Pennsylvania. Mr. Milton N. Bramlette, of Wisconsin, has been appointed assistant geologist with the U. S. Geological Survey. Dr. Hardee Chambliss, formerly research chemist with the General Chemical Company, and lieutenant colonel in charge of U. S. Nitrate Plant No. 1 during the War, has been appointed to take charge of the work of the department of chemistry at the Catholic University on account of the pro- longed illness of Rev. Dr. John J. Griffin, who has been in charge of the department since 1895. Mr. Lloyd C. Fenstermacher, of Pennsylvania, who was recently appointed assistant geologist with the U. S. Geological Survey, was killed on July 9 in an automobile accident while engaged in field work for the Survey near Wilder, Montana. Mr. G. J. Fink, formerly with the Hooker Electrochemical Company of Niagara Falls, is now associated with Dr. M. E. Holmes in the chemical department of the National Lime Association in Washington. Mr. Paul M. Frank, of Allentown, Pennsylvania, has been appointed assistant curator in the Division of Mineral Technology of the National Museum. Dr. Michael E. Gardner has been apointed chief of the bureau of preventable diseases and director of the bacteriological laboratory of the U. S. Public Health Service. Mr. Joseph L. Gillson of Illinois has been appointed assistant geol- ogist with the U. S. Geological Survey. Dr. F. H. Knowlton of the National Museum received the honorary degree of Doctor of Science from Middlebury College in June. Mr. Charles E. Mirguet, who has been associated with the National Museum for several years, has been appointed taxidermist to succeed the late Mr. William Palmer. The sections of Eastern and Western Areal Geology in the U. S. Geological Survey have been merged into one section under the direction of Mr. Sidney Paige. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 September 19, 1921 No. 15 GENERAL SCIENCE.- — .4 list of one hundred poptdar books in sci- ence.'^ Compiled by a committee of the Washington Academy OF Sciences. At the request of Dr. George F. Bowerman, Librarian of the Public Library of the District of Columbia, a committee of the Academy has undertaken the compilation of a list of scientific books which can be recommended for popular use. The Editors believe it to be of sufficient interest to the members of the Academy and other readers of the Journal to warrant the preliminary publication of the report, particularly as it is hoped that criticisms and suggestions from readers may be brought forth and the list thereby improved. It is to be em- phasized that the list is strictly tentative, and that neither the Com- mittee as a whole nor any one member of it can assert that the books named are the very best for the purpose. It will be obvious also that broad areas of the field of science are hardly touched at all, and that the relative number of books treating of different subdivisions of science must not be taken to represent the relative importance of each subdivision or the relative activity of modern research therein. Readability is an essential criterion for selection, and books that are "readable," from the public's point of view, are very unevenly dis- tributed as to subject-matter. The first test for the kind of book that is desired for the list is this : Would the average reader who uses a public library, after beginning to read the book in question, read it through to the end and come back to the Librarian for another on the same subject? Such a book should be included. Or would he lay it down after a little while and turn to some other kind of book as being more interesting, and not return to the subject again? Such a book should not be included, ' Received August 25, 1921. 353 354 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 however accurate, thorough, and complete it might be from the stand- point of a specialist. It is also desirable that the book should not be professedly a text- book, nor should it be written in text-book style ; that is, it must not be a book intended primarily for the seeker after information regard- less of whether the information be interesting reading or not. It is perhaps needless to add that it should have been written by an author who knows his subject thoroughly, and should not be so old as to be obsolete in its facts and speculations.^ The user of such a list may well be reminded at the outset that the field of science is not sharply divisible into little compartments labeled "Chemistry," "Botany," and the like. On the contrary, there is one vast field of human knowledge, and facts concerning any part of that field have a bearing on every other part. The usual subdi- visions, which are those employed here, are not fundamental; they are largely accidental and have arisen merely as a matter of human convenience. If we believe with Pope that "The proper study of mankind is Man" we may well begin with books about Man himself, rather than follow the austere and logical order laid down by philosophers, be- ginning with mathematics and ending with sociology. The natural order of human education is just the reverse, beginning with impres- sions of human nature and reaching formal logic and philosophy last, if ever. In this preliminary list, however, the Committee does not attempt to recommend any books in the fields of psychology, sociology, and related sciences, but begins with Man considered rather as a species or as an organism, suggesting the following books in anthro- pology and physiology : 2 These specifications are not easy to meet. Popular scientific books of a class which might be described as "interesting if true" are not uncommon, but the production of such books seems to demand primarily a sufficient dearth of conscience and professional pride on the part of author and publisher. Others fall on the borderline between the merely "unorthodox" and the "misleading" or "misinforming." It is no great objection to a popular scientific book that its speculations are somewhat wild, provided its statements of fact and principle are based on knowledge and not on ignorance. Librarians and interested readers can be depended upon to compile lists of scientific books that are interesting, but they have no good way of finding out which of these are reliable. It is here that the Academy can do a service, for there are on the shelves and recommended in library lists books of popular science which, under even the most liberal of "pure food laws" for books ought to be labeled "misbranded" or "adulterated" if not "poisonous." They are particularly common in those branches, such as meteo- rology and anthropology, in which every man considers himself something of an expert. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 355 Mason, O. T. The origins of invention. 419 pp. ("Contemporary- Science Series," Walter Scott, London, 1895.) Although old, this book is thoroughly reliable and will remain authoritative for decades to come. It is readable and entertaining, and at the same time based on a wide knowledge of anthropology and ethnology. Mason, O. T. Woman's share in primitive culture. 295 pp. (D. Appleton and Co., New York, 1894.) Like the preceding book by the same author, this work remains a standard. It will be particularly welcome to readers who have been irritated by the irresponsible pseudo-science that is sometimes written about the relative status of the sexes in primitive, as compared with modern, society. OsBORN, Henry Fairfield. Men of the Old Stone Age, their environment, life and art. 545 pp., 268 illustr., 33 pp. of bibliography and index. (Charles Scribner's Sons, New York, 1915.) This book is a popular synthesis of the findings and opinions of many specialists, including the author himself, in the fields of archeology', paleontology, geology, anthropology and primitive art. Haddon, a. C. The study of man. 410 pp. (G. P. Putnam's Sons, New York, 1898.) A reliable and readable work by one of the foremost ethnologists and anthropologists of Great Britain. It deals interestingly with the distribution of Man and his varieties over the Earth's surface. KiDD, Dudley. Savage childhood, a study of Kafir children. 314 pp., 32 illustr. from photographs. (Adam and Charles Black, London, 1906.) This book is less general than the preceding but it is particularly attractive. The games, stories and songs of Kafir children as well as Kafir customs per- taining to children are described in a charming and instructive manner The book is artistic rather than scientific but is a distinct addition to popular knowledge of anthropology and ethnology. Hough, Walter. The Hopi Indians. 265 pp. (Torch Press, Cedar Rapids, Iowa, 1915.) This is one of the best examples available of descriptive anthropology applied to a particular group. It is entertainingly written, and the author's long experience in the field is a guarantee of its accuracy. McCoLLUM, E. V. The newer knovuledge of nutrition. 199 pp. (The Macmillan Co., New York, 1919.) This book contains an authoritative, non-technical statement of the principles underlying proper human nutrition as developed from a great number of experiments and observations, some of the experiments having been carried out by the author and described by him in an interesting way in the book, with illustrations. The literature on the subject of nutrition has been survey^ed and condensed reference is made to this extended field. Sherman, H. C. Food products. 594 pp. (The Macmillan Company, New York, 1918.) The chemistry, physiology, availability and economics of human foodstufi's are authoritatively discussed in essentially nontechnical language. Man shares with every other member of the animal and vegetable kingdoms that remarkable capacity, still a mystery to every investi- gator, whether biologist, chemist, or physicist — the capacity of re- producing his kind and handing down his qualities to his descendants The following books on heredity are standard works in this field 356 JOURNAL OF THE WASHINGTON ACADEMY OE SCIENCES VOL. 11, NO. 15 Darwin, Charles. The origin of species (with additions and corrections from sixth and last English edition). 338 pp. (D. Appleton and Co., New York, 1917.) No collection of works on biology should be without this classic. The observations of Darwin are still the current material in biological dis- cussion. His brilliant imagination, together with the thorough and pains- taking way in which all conclusions are checked and tested without bias, cannot fail to impress the reader that the study of heredity is a noble and engrossing subject. East, E. M., and Jones, D. F. Inbreeding and outbreeding. 285 pp. (Lippincott Co., Philadelphia, 1919.) Although confined to a restricted field, this work presents the most modern interpretation of the phenomena of inheritance in comprehensible form. Castle, W. E., Coulter, J. M., Davenport, C. B., East, E. M., and Tower, W. L. Heredity and eugenics. 315 pp. (Chicago University Press, 1912.) A collection of lectures proposed for an audience not especially trained in biology. Although many important facts have come to light since these lectures were delivered, they give, in readable form, the general conceptions of heredity that are held by leading investigators. Morgan, T. H. A critique of the theory of evolution. 197 pp. (Princeton University Press, 1916.) The author is one of the foremost investigators of heredity. His work in the field of genetics, together with that of his stu- dents, has resulted in discoveries that rank with those of Mendel. This book, written for undergraduates, is semi-popular in style and although special emphasis is laid on the phases of the subject in which the author is especially interested, it introduces the reader to the important discoveries made in genetics. CONKLIN, E. G. Heredity and environment. Third edition. 361 pages. (Princeton University Press, 1919.) Newer and technical aspects of a difficult science are not shunned in this treatise but the direct bearings of the results of recent studies in this field upon the welfare and the future of man are presented in a most readable manner. Galton, Francis. Hereditary genius. 390 pp. (D. Appleton and Co., New York, 1884.) Old, but emphasizes in a delightful way the most impor- tant side of genetics. PoPENOE, Paul, and Johnson, R. H. Applied eugenics. 459 pp. (Mac- millan Co., New York, 1918.) A clear and forceful presentation of the bearing and importance of studies in heredity as applied to the human race. Certain phenomena are common to all kinds of living organisms, whether "animals" or "plants." Reproduction and inheritance have already been spoken of, but there are also growth, and death, and standing behind them waiting to be explained in terms that satisfy the physicist as well as the biologist the fact of evolution : Thomson, John Arthur. The wonder of life. 658 pp. (A. Melrose, Ltd., London, 1915.) "An unconventional introduction to Natural History and Biology, taking broad views of the actual lives of living creatures and working inwards." A bookful of "wonders," not exploited for the curious, but all bringing their evidence to bear on general laws of life and its evolution. HeadlEy, F. W. Problems of evolution. 373 pp. (Crowell and Co., New York, 1900.) The author is a skilled lecturer and introduces his book with an elementary chapter for the general reader, also avoiding technical terms throughout the work. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 357 LoTSY, J. p. Evolution by means of hybridization. 166 pp. (M. Nijhoff, The Hague, 1916.) A brief and stimulating essay on the origin and trans- formations of living beings. On the more purely descriptive side of the biological sciences there exists a wide variety of books. It is convenient to roughly divide the field into "zoology" and "botany," and the following readable books in each of these two subjects can be recommended : In zoology : Buckley, A. B. Life and her children. 312 pp. (Appleton and Co., New York, 1881.) Buckley, A. B. The winners in life's race. 367 pp. (Appleton and Co., New York, 1883.) These two books are elementary but fascinating, forming a delightful introduction to the study of invertebrate and vertebrate zoology, respectively. In botany : Ganong, W. F. The living plant: a description and interpretation of its functions and structure. American Nature Series. 478 pp. (Henry Holt and Co., New York, 1913.) A thoughtful and suggestive book by a leading American plant physiologist. Written in the form of an essay rather than the usual college text-book and designed to appeal to those interested in know- ing how living things "work," rather than to professional botanists. Well illustrated. OsTERHOUT, W. J. V. Experiments with plants. 492 pp. (The Mac- millan Co., New York, 1905.) An introduction to plant physiology with descriptions of many ingenious experiments requiring only simple home-made apparatus. The author is one of the leading plant physiologists of the United States. The reader should take note, however, that much progress has been made in this branch since 1905. SoRAUER, Paul. A popular treatise on the physiology of plants for the use of gardeners or for students of horticulture and agriculture. Translation by F. E. Weiss. (Longmans, Green & Co., London, 1895.) This well- written and comparatively brief but highly authoritative work presents a ver>^ satisfactory treatment of the structure and nutrition of plants. It might be entitled "the plant at work." As the subtitle indicates, the prac- tical application of the principles set forth is constantly in view. Lubbock, John (Lord Avebury). Flowers, fruits and leaves. Nature Series. (Macmillan Co., New York, 1908.) A readable and suggestive little book by the well-known statesman and botanist. A special field of botany is that devoted to the distribution of plants over the earth's surface- — ecology : Hardy, Marcel E. The geography of plants. 339 pp. (Clarendon Press, Oxford, 1920.) A short readable account of the distribution of vege- tation over the surface of the Earth. It is concerned largely with dis- tribution, and only to a slight extent with the relations of plants to their en- vironment. There are many books dealing in an interesting way with restricted groups of living organisms. Some describe the life of a given lo- cality; some tell about the members of a certain family, wherever they may be found. It is much easier to make a list of good manuals 358 JOXIRNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 and information-books in this field^ than to select a list of the type described in our specifications, but the following will serve as good introductions : Darwin, Charles. Insectivorous plants. 462 pp. (Appleton and Co., New York, 1896.) An extremely interesting book, and a classic for nearly fifty years. Darwin did his work so thoroughly and well that no one else has touched the subject since to add anything of importance. Townsend, C. W. Sand dunes and salt marshes. 311 pp. (Dana Estes and Co., Boston, 1913.) Avery readable and interesting book, highly suggestive to anyone spending a vacation at the seashore. Contains much about plant and animal life, and the physiography of the shore region. The zoologists have provided more abundantly the kind of books wanted for this list than have the botanists, though their subject matter is hardly more diverse. A sketchy view of their field, beginning with the mammals and coming down the scale to the protozoa, may be had from the following books : Stone, Witmer, and Cram, W. E. American animals. A popular guide to the mammals of North America north of Mexico. 318 pp. (Doubleday, Page and Co., New York, 1902.) Not simply a manual, but a good book to look through and read. It is abundantly illustrated with plates and half- tones, and tehs just the things about the mammals that the average reader who has met them in the woods or seen them in the "Zoo" is interested to know. Roosevelt, Theodore. African game trails. 583 pp. (Charles Scrib- ner's Sons, New York, 1910.) No American needs to be told that the late ex-president was one of the most versatile of men. Though some of his critics accused him of substituting vigorous assertion for calm argument his zoological writings have often proved to be more reliable than others with a greater appearance of erudition. Beebe, C. Jungle peace. 297 pp. (Henry Holt and Co., New York, 1919.) A combination of zoology and philosophic reflections which makes very interesting reading, written by a keen and scientifically trained observer. Chapman, Frank M. Camps and cruises of an ornithologist. 432 pp. (D. Appleton and Co., New York, 1908.) Bird books for nature lovers are abundant, but are usually written for a particular locality. This one of Chapman's can be read with interest and profit in any part of the United States, and its author is a recognized authority in his subject. Herrick, F. H. The home life of wild birds. 148 pp. (G. P. Putnam's Sons, New York, 1901.) Although the author's subtitle calls the book a descrip- tion of "A new method of the study and photography of birds," it is much more than that. His methods are interestingly described, but are followed up with entertainingly written examples of the additions that anyone who is really interested can make to ornithological science. Fabre, J. H. Social life in the insect world. (Translation by Bernard MiaU.) 327 pp. (Century Co., New York, 1912.) It is difficult to select from Fabre's books. All of them might weU be recommended for such a ' The preliminary circulation of this list has evoked so many requests for a list of re- liable manuals which students in one branch of science can depend upon for information in other branches, that the publication of such a list is recommended to the attention of a future committee. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 359 list as this. They are most interestingly written, and while they are not free from minor inaccuracies, no book dealing with so complex a subject as a living organism can hope completely to avoid that criticism. Peckham, S. W., and Peckham, E. G. Wasps, social and solitary. 310 pp. (Houghton Mifflin Co., Boston, 1905.) A well written record of the habits of our common wasps. Mr. and Mrs. Peckham spent years in careful and patient observation, and have written some of our standard manuals, as well as this very popular work. Maeterlinck, Maurice. Tlie life of the bee. (Translation by Alfred Sutro.) 427 pp. (Dodd, Mead and Co., New York, 1902.) The author is more widely known as a poet and dramatist than as a zoologist, but he is also a careful student and observer and has contributed in this work one of the reliable books in its field. Darwin, Charles. The formation of vegetable mould through the action of worms. 362 pp. (D. Appleton and Co., New York, 1892.) A model of the scientific method of attacking a biological problem. Blatchley, W. S. Gleanings from nature. 348 pp. (Nature Pubhshing Co., Indianapolis, 1899.) One of the few books that give a popular and at the same time accurate account of our common reptiles. The book contains also observations of many other animals and plants. Abbott, Charles C. Upland and meadow. 397 pp. (Harper and Bros., New York, 1886.) A charming book by an author who devoted his life to the study of living organisms as they appeal to the "naturalist" — a type of scientist which has become, temporarily, we may hope, almost extinct.* Mayer, Alfred G. Sea-shore life. 181 pp. New York Aquarium Nature Series. (A. S. Barnes and Co., New York, 1906.) A book intended for read- ers who may be unfamiliar with the technical terms in use among specialists. Ever}- dweller or visitor at the sea-shore will find it of interest, though most of the illustrations are of species along the northern Atlantic coast of the United States. Uncounted multitudes of species of living organisms have risen and then declined in past ages. Their study is far from being the dry subject that the word ' 'bones' ' suggests : Lucas, F. A. Animals of the past. 258 pp. (McClure, Phillips and Co., New York, 1902.) A very entertainingly written book about a few of the better known or more remarkable of the extinct animals of the ancient world, written partly "to ease the strain on these venerable animals, caused by stretching them so often beyond their due proportions." Hutchinson, H. N. Extinct monsters and creatures of other days: a popidar account of some of the larger forms of ancient animal life. 329 pp. (Chapman and Hall, London, 1910.) The field selected by the author is that part of paleontology which is best adapted for arousing and holding the interest of the general reader. Technicalities have been omitted as far as possible. A fairly good idea is given of the progress of animal life through the geologic ages. Copiously illustrated, with many restorations. * Good books of travel, exploration, and adventure written by scientists, or by persons who are keen observers of natural phenomena, are fairly numerous. Such are Thomas Belt's The naturalist in Nicaragua (.306 pp., Button and Co., New York, 1911), and Lyell's Travels in North America, but as librarians usually place such books with "travel and de- scription" or some similar classification, no attempt at a selection will be made here. The Academy could do a service by preparing a list of reliable books of this kind. 360 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 There are not many hard and fast lines of division in science, but there is one that so far has not been wiped out — the line between "living" and "dead" matter. For the rest of our booklist we shall be dealing with sciences not primarily concerned with organic life. The first general group of these is comprehended under the term "geology," including all the sciences which are concerned with the Earth as a whole, with the constitution and structure of its surface and its interior, and with the existing evidences of its past history : DwERRYHOUSE, Arthur R. Geology. 301 pp. ("Romance of Reality" Series. T. C. and E. C. Jack, London and Edinburgh, about 1917.) This up-to-date book is attractively written in clear and simple language for the general reader by a competent geologist. The larger part of it is de- voted to the description of an imaginary geological excursion to a hypothetical country. Thus the book loses something of its force from the fact that its descriptions are not taken from actually known and named localities. In the course of the supposed excursion many interesting geologic facts are brought out and are made to bear directly upon the history of the country and upon the development of its natural resources. Methods of field study are also shown. Seely, H. G. The story of the Earth in past ages. 190 pp. (Appleton and Co., New York, 1910.) An elementary little book, with references mostly to British geology, but containing much matter of general interest. Cole, Grenville A. J. The changeful Earth. 223 pp. (Macmillan and Co., Ltd., London, 1911.) "Inspiration rather than information" is the keynote of the series of which this little book is a member, and it is most effectively carried through, yet without sacrifice of accuracy. Lull, R. S., and others. The evolution of the Earth and its inhabitants. 208 pp. (Yale University Press, New Haven, 1918.) A very readable book, well illustrated, and written by a group of skilful and inspiring lecturers (Barrell, Schuchert, Woodrufi", Lull, and Huntington). Ball, Robert S. Time and tide. Third edition. 192 pp. (Society for Promoting Christian Knowledge, London, 1895.) Justly described as a "Romance of the Moon." Two lectures in popular language devoted to the evolution of the Earth-Moon system. Spurr, J. E., Editor. Political and commercial geology and the world's natural resources. 562 pp. (McGraw-Hill Book Co., New York, 1920.) The political and commercial aspect of Earth-science is usually put under the heading of "geography." This book is in that sense a geographic book, for it tells of the location and accessibility of the world's mineral supplies rather than of their origin and geologic relationships. Mr. Spurr is well fitted to present this readable and accurate account of the subject by his training as an editor, mining geologist, and member of the Government's boards on war minerals. Brigham, Albert P. Geographic influences in American history. 285 pp. Chautauqua Home Reading Series. (Chautauqua Press, Chautauqua, New York, 1903.) A popular account by a well-known American geographer. The treatment is unbiased and scientific ; the presentation is orderly, thorough and mainly accurate, though weak in some details; the style readable, not catchy, but attractive and stimulating. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 361 Water is perhaps the most active of all the agents that are con- tinually modifying the surface of our changeful Earth : BoNNEY, T. G. The work of rains and rivers. 144 pp. Cambridge Manuals of Science and Literature. (Cambridge University Press, Eng- land, 1912.) This is practically the only modern book in its field. It can be called neither abstruse nor popular, but is written in fairly simple language suitable for the reader of average education, and is a logical, thorough, and accurate presentation. Cornish, Vaughan. Waves of the sea and other water waves. 374 pp. (Open Court Publishing Co., Chicago, 1911.) A well written book in non- technical language, beautifully illustrated, dealing in descriptive form with the size, speed, and action of waves in the sea and in rivers. Volcanoes, although they represent only one among dozens of agents that are active in altering the Earth's surface, have always focussed popular attention upon themselves by the amount of noise they can make and the amount of human destruction they can do in a short time: BoNNEY, T. G. Volcanoes, their structure and significance. 321 pp. (G. P. Putnam's Sons, New York, 1899.) By taking up in narrative style the characteristics of some "live" volcanoes the author leads the reader on to do some thinking and speculating for himself as to the cause of vol- canicity — and there is still much room for study though important additions to our knowledge have been made since this book was written. Nevertheless, the new facts have by no means rendered this excellent work obsolete. Russell, Israel C. Volcanoes of North America. 346 pp. (Macmillan Co., New York, 1897.) The author calls his book "a reading lesson for stu- dents of geography and geology" but it is more than that. It is a very read- able account of some of our own volcanic mountains, which are already familiar to most Americans but which gain added interest through comparison with the volcanoes of other countries and through discussion of the agencies which built them. No subject in all the range of man's interests is more commonly used in introducing friendly conversation and in maintaining it than the weather. Well-told information about the atmosphere and the causes of meteorological phenomena, such as is contained in the books listed below, cannot fail to add to its interest : Harrington, Mark W. Abottt the weather. 246 pp. (D. Appleton and Co., New York, 1899.) Attractively written. Antedates many in- teresting discoveries, but otherwise is one of the best of the popular works on meteorology. Dickson, H. N. Climate and weather. 256 pp. (Williams and Norgate, London, 1911.) Brief sketches on special topics, interestingly done. Lempfert, R. G. K. Weather science. 94 pp. (T. C. and E. C. Jack, London, 1912.) Chiefly a very brief popular account of weather forecasting. Ward, R. de C. Climate, considered especially in relation to Man. Second edition. (G. P. Putnam's Sons, New York, 1918.) The best book on cHmate addressed to the general reader. Talman, C. F. Realm of the air. (P. F. Collier and Son, 1921.) Inter- esting, accurate and up-to-date. 362 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 Besides being blanketed with a layer of air, which is the domain of meteorology and "the weather," the Earth is also covered in large part with a thin layer of water, from a few inches to several miles deep — the ocean. The geography of the ocean, the science which treats of the distribution, the physical properties, and the tides and currents of the ocean is known as oceanography : Murray, John. The ocean. 256 pp. (Henry Holt & Co., New York, about 1913.) An interesting, non-technical, yet thoroughly reliable account of the methods, instruments and results relative to the depths, temperatures, physical properties, tides, currents and plant and animal life in the ocean. The structural units of the solid earth — the "bricks" of which it is built — are the rocks, whose composition, properties, and origin form the subject matter of petrology : Cole, Grenville A. J. Rocks and their origins. 175 pp. Cambridge Manuals of Science and I^iterature. (Cambridge University Press, England, 1912.) Neither abstruse nor popular, but adapted to a well-informed reader rather than a beginner. The treatment is unbiased and thoroughly scien- tific, and covers the whole field, though briefly. It is logical, thorough, accu- rate, and stimulating; readable, but not catchy. There is no other book in the field of just the same sort, for comparison. The constituent crystals or particles which make up the rocks .'including the valuable ores) form the subject of "mineralogy" — from ^ne point of view a branch of chemistry : Bennett, Lee F. Rocks and minerals. Third edition. SS pp. (Bo- garte Book Co., Valparaiso, Indiana, 1914.) An excellent little elementary book, describing in an interesting way 40 minerals and 40 rocks. Suited to give the general reader with a minimum of time at his disposal a good idea of the scope of the sciences of mineralogy and petrology. Gratacap, Louis P. A poptilar guide to minerals. 330 pp. (D. Van Nostrand Co., New York, 1912.) A splendidly illustrated work, based on the collections in the American Museum of Natural History in New York City. The text is not up to the standard of the plates, being rather chmisily put together, although reasonably accurate and elementary in most places. Will appeal to the users of books who gain more from illustrations than from text matter. The oldest of the sciences, and still the one with the most permanent popular appeal, notwithstanding the fact that its 5000-year competitor from the field of superstition — astrology — is still active, is astronomy : Abbot, Charles G. The sun. 448 pp. (D. Appleton and Co., 1911). The best book on the subject of the Sun; readable, though technical in places. Ball, Robert S. The story of the heavens. 556 pp. (Cassell and Co., London, 1892.) Delightfully written, and in popular language. Dyson, F. W. Astronomy. '247 pp. (E. P. Dutton and Co., New York, 1918.) Elementary, yet thoroughly reliable. Hale, George E. The study of stellar evolution. 252 pp. (University of Chicago Press, 1908.) An interesting, well illustrated, and authoritative summary of results relating to the constitution of the stars and the Sun. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 363 Lewis, Isabel M. Splendors of the sky. 343 pp. (Duflfield and Co., 1920.) Popular, accurate, and up-to-date. McKready, Kelvin. A beginner's star book. 148 pp. (G. P. Putnam's Sons, 1912.) Many fine illustrations. Turner, H. H. A voyage through space. (Society for Promoting Christian Knowledge, London, 1915.) Pleasingly written and reliable. The Adolf 0 Stahl lectures in astronomy. 257 pp. (Stanford University Press, California, 1919.) Twelve lectures on modern astronomy by members of the Mount Wilson and Lick Observatory staffs. Accurate, interesting, and nontechnical. The properties of matter w^ithout regard to its particular form make the subject matter of physics and chemistry. The carbon in a star has the same interest to the chemist and the physicist as the carbon in a tree-trunk or in a diamond. But it is impossible to write a definition that will divide physics from chemistry and still include under each all that we commonly understand by the two terms. In a general way, the chemist is interested in the composition of things, the physicist in their qualities. The titles of a few chemical books follow.^ Slosson, E. E. Creative chemistry. 311 pp. (Century Co., New York, 1920.) A ver}^ interesting and readable book, showing particularly the im- portant place of chemistry in modern industry and in warfare. It is a book abotit chemistry and what it can do, rather than a book of chemistry, but can be recommended to the general and technical reader alike. Hendrick, Ellwood. Everyman's chemistry. 374 pp. (Harper and Bros., New York, 1917.) This book is specifically "designed for those who declare that they do not know an3i:hing about the subject." Duncan, Robert Kennedy. The chemistry of commerce. 263 pp. (Harper and Brothers, New York, 1907.) An interesting interpretation of various phases of modern industrial chemistry. Martin, Geoffrey. Modern chemistry and its wonders. 358 pp. (D. Van Nostrand Co., New York, 1915.) A description in non-technical lan- guage of some of the striking modern advances in chemistry. Although the chemist has made contributions to almost every other portion of the field of science, it remains unfortunately true that most of his books are written for specialists and not for the general reader. The "physico-chemical" and "physical" portions of the field of physics and chemistry are not quite so lacking in readable books; the titles of some of these follow : SoDDY, Frederick. Matter and energy. 255 pp. (Henry Holt and Co., New York, 1912.) This is one of the best available accounts of fundamental physical and chemical principles. It is very brief and comprehensive, yet authoritative. ^ Acknowledgments are due to the American Chemical Society's committee on chemical reading courses, of which W. A. Hamor is chairman. This committee has published a full and well annotated list of books in all branches of chemistry. See Journ. Ind. Eng. Chem. 12:701,800. 1920. 364 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 Tyndall, John. Fragments of science. Fifth edition. 589 pp. (D. Appleton and Co., New York, 1884.) Though now fifty years old, these spirited essays by the most ardent proponent of the scientific method re- main essentially correct and only the more firmly established by the later prog- ress which has amplified our knowledge in the variety of fields touched upon. EiNSTEi>J, Albert. Relativity. Translation by R. Lawson. 168 pp. (Methuen, London, 1920.) As simple an account as is readily possible of the old and new theories of relativity by the originator and leader of this revolutionary school of thought.^ Whetham, W. C. D. The recent development of physical science. 347 pp. (Blakiston's Son and Co., Philadelphia, 1909.) One of the Cambridge school of physicists tells of the work on the borderland of physics and chemis- try during the important period to which he and his colleagues made valuable contributions. Ames, Joseph S. The constitution of matter. 242 pp. (Houghton, Mifflin and Co., Boston, 1913.) Professor Ames' long and varied experience and his close association with developments of modern physics enabled him to produce this valuable book, which combines comprehensiveness in subject matter with simplicity of expression. Fleming, J. A. Waves and ripples in water, air, and aether. 299 pp. (Society for Promoting Christian Knowledge, London, 1902.) This book is old but much of the field which it covers has not changed in recent years. It represents a course of Christmas lectures delivered to a "juvenile audience" at the Royal Institution, London. It is a most readable, instructive, and delightful book. Perry, John. Spinning tops. 136 pp. (Society for Promoting Christian Knowledge, London, 1901.) This popular lecture stimulates the imagi- nation by illustrating both the wealth of interesting phenomena connected with a commonplace toy and the elegant simplicity with which the science of mechanics unifies these effects. Miller, Dayton C. The science of musical sounds. 286 pp. (Mac- millan Co., New York, 1916.) This book, written by one of the foremost authorities in America, is very readable and particularly strong on the ex- perimental side. Bragg, Wilham. The voorld of sound. 203 pp. (Bell and Co., London, 1920.) A very well done and up-to-date treatment of a branch of physics that appeals to everyone. The material was prepared for a juvenile audience, the most difficult of all audiences to write for.'' MiCHELSON, A. A. Light voaves and their uses. 166 pp. (University of Chicago Press, 1903.) This is a readable popular account of the applications of light waves to the most delicate and refined scientific measurements. The author is a universally recognized leader in this field of science and the examples which he quotes of the conquest by the human mind of the realm of the "infinitely little" are (although he does not say so) in large part the result of his own efforts. ^ This book does not fully fit the specifications in the early paragraphs of this list, but neither does any other of the flood of books and essays on relativity. The reader is not likely to be any better off for having read "Einstein made easy" before reading Einstein himself. ^ Agassiz required of his students in each department of study "first a monograph, second a scientific lecture, third a popular lecture, fourth, a simple child's tale." ShalER, Autobiography {1^91). v-^O^. SEPT. 19, 1921 POPULAR BOOKS IN SCIENCE 365 Abney, W. de W. Colour measurement and mixture. 207 pp. (Society for Promoting Christian Knowledge, London, 1891.) In spite of the age of this book, the subject is one which has not suffered as much change as most of the branches of physics, and the book, which deals with the principles and measurements underlying color sensation, is well worth reading at the present time. Boys, C.V. Soap bubbles: their colours and the forces which mould them. 190 pp. (Society for Promoting Christian Knowledge, London, 1920.) This book, written by a man noted for his skill in devising experiments, contains a very interesting account of the properties of soap bubbles, and describes a large number of interesting experiments which may be made with them. (See also his companion book Splash of the drop.) SoDDY, Frederick. The interpretation of radium. 284 pp. (G. P. Putnam's Sons, New York, 1912.) A readable non-technical account of the subject by one of the pioneers in this field. Mathematics is not ordinarily considered a subject to arouse popular enthusiasm, yet it is full of human interest and is a constantly growing and developing science. The following books will give an insight into its variety and interest : CoNANT, Levi Leonard. The number concept, its origin and development. 218 pp. (Macmillan Co., New York, 1896.) An interesting and readable account of the probable origin and nature of the concept of number, with a description of number systems, past and present, among different races of mankind. Whitehead, A. N. Introduction to mathematics. 256 pp. (Home University Library, Henry Holt and Co., New York, 1911.) A brief survey of the principal topics treated of by mathematics, handled in a popular way. YouN'G, John Wesley. Lectures on the fundamental concepts of algebra and geometry. (Macmillan Co., New York, 1911.) An excellent elementary treatment of the subject. Shaw, James Byrnie. Lectures on the philosophy of mathematics. 206 pp. (Open Court Publishing Co., Chicago, 1918.) An unexcelled elementary survey of the entire field of mathematics, including content, principles, methods, significance, and nature of mathematics, with references to litera- ture. Although the treatment is popular and readable, a considerable knowledge of mathematics is required for a full appreciation of this work. De Morgan, Augustus. On the study and difficulties of mathematics. 288 pp. (Open Court Publishing Co., Chicago, 1902.) A classic. A wealth of material is at hand in the history of science from which the following are selected, though the choice of only a few is difficult : LiBBY, Walter. An introduction to the history of science. 288 pp. (Hough- ton Miffiin and Co., Boston, 1917.) Well-written essays on a few selected topics of the history of science. Perhaps the best elementary introduction to the subject. Sedgwick, W. T., and Tyler, H. W. A short history of science. 474 pp. (Macmillan Co., New York, 1917.) The most comprehensive, if not the most accurate, elementary English book on the subject. White, Andrew D. A history of the warfare of science with theology in Christendom. 2 volumes. 415 and 474 pp. (D. Appleton and Co., New 366 JOURNAL OF' THE WASHINGTON ACADEMY OE SCIENCES VOL. 11, NO. 15 York, 1896.) An excellent book treating a delicate subject with tolerance, kindness and wisdom. Smith, David Eugene. Number stones of long ago. 136 pp. (Ginn and Co., Boston, 1919.) Stories on the history of arithmetic written for children. Accurate and entertaining. Probably the only book on the history of science which was written especially for children. Berry, Arthur. A short history of astronomy. 440 pp. (Charles Scrib- ner's Sons, New York, 1910.) Apparently there is no difference between this edition and a previous one published in London in 1898. Perhaps the best general elementary textbook. A very good introduction to the subject. Thorpe, Edward. History of chemistry. 2 volumes, 185 and 190 pp. (G. P. Putnam's Sons, New York, 1909-10.) Less complete but more ele- mentary and far more easy to read than Ernst von Meyer's standard book. GeikiE, Archibald. The founders of geology. 289 pp. (Macmillan and Co., London, 1897.) The book embodies a series of lectures delivered by this distinguished English geologist before students of Johns Hopkins University. It is a charmingly written account of the beginnings of geological science and of the principal workers in that subject down to the latter half of the nine- teenth century. Only European and British geologists are considered. The book is intended for the mature reader who knows something of geology, but it may be enjoyed as well by those who have no technical knowledge of the subject. Merrill, George P. Contributions to the history of American geology. 546 pp. Part of Report of U. S. National Museum for 1904. (Washington, 1906.) An interestingly written series of sketches of the leaders in American geology since its earliest days, well illustrated, and enlivened with anecdotes and comments. (A new edition is in preparation.) LocY, William A. Biology and its makers. 477 pp. Third edition, revised. (Henry Holt and Co., New York, 1915.) Good introduction; simple, clear and entertaining. PHYSICS. — The wave lengths of X-rays.'^ Ralph W. G. Wyckoff, Geophysical Laboratory, Carnegie Institution of Washington. (Communicated by Arthur L. Day.) It is commonly assumed that the length of X-rays has been uniquely and definitely determined from the study of the structures of crystals. In the following discussion it will be shown, taking the case of sodium chloride as an example, that with the existing knowledge it is impossible to determine definitely the structure of any crystal in advance of a knowledge of the wave length of X-rays. Viewed then from this position only, the problem of the length of X-ray waves and of the structures of crystals becomes indeterminate and recourse must be had to other sources of information. The customary method of determining the wave length of X-rays. — The wave length of X-rays has been determined through the following course of reasoning.- If a crystal is considered as composed of a 1 Received June 16. 1921. " W. H. and W. L. Bragg. X-rays and crystal structure. (London, 1918.) SEPT. 19, 1921 WYCKOFF: WAVE LENGTHS OF X-RAYS 367 regular and orderly repetition of a certain grouping of atoms through- out space (as seems entirely permissible) , and if we assume the correct- ness of the Laue theory^ that the atoms in this crystal act as diffracting centers of a three-dimensional diffraction grating, then it follows that the wave length of the X-rays diffracted by this crystal, the "spacing between like planes" in the direction of the diffraction, and the angle of the diffraction effect are connected by the familiar expression fi\ = 2d sin d (1) Fig. 1. where n is the "order" of the reflection, X is the wave length of the diffracted X-rays, d is the "spacing," that is, the distance between like planes in the chosen direction, and 6 is the angle of the diffraction. In figure 1 ADEFCGBO represents the unit cell which is repeated along the axes of coordinates in a cubic crystal. The length of the side of this unit cube, AO, is (iioo, the "spacing" against the cube face. The volume of this unit is then mM V = (J.oo)^ = — (2) P where M is the weight of one chemical molecule of the substance, »M. Laue. Ann. Phys. 41: 971. 1913. 368 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 m is the number of these molecules in the unit, p is the density of the crystal, and V is the volume of the unit. In this expression the density is known and the value of M is simply the molecular weight of the salt multiplied by the weight of an atom of hydrogen, which has been show^n to be close to 1.64 X 10"-"^ grams. The other term upon the right hand side of this equation, m, can be known, however, only when the crystal structure of the salt is also known. Fig. 2. In first studying the wave lengths of X-rays the alkali halides were investigated, and of these the one which is from all points of view the most satisfactory to treat is sodium chloride. Since no information immediately useful for the present purpose can be obtained from a consideration of any other available crystals, it will be permissible to limit attention to this one salt. The only data for establishing the structure of sodium chloride which are truly independent of assumptions more or less tacitly based upon an imagined structure of some crystal are (1) the observation (from Laue photographs) that only planes all of whose indices are odd are SEPT. 19, 1921 WYCKOFF: WAVE LENGTHS OF X-RAYS 369 found to give effects in what must correspond with the first order region, and (2) the confirmatory observation (from spectrometer measurements) that the first observable reflections from the (100), (110) and (111) faces stand in the ratio of ' V2 ' V3 The familiar "sodium chloride arrangement" (Fig. 2), with four chemical molecules associated with the unit cell, is in agreement with the above data, so that it has been taken as the structure of this crystal. Accepting such an identification as correct, a substitution of m = 4 in expression (2) yields dioo, and since the value of n is also directly determinable from a knowledge of the crystal structure, it is but a step to obtain the wave length of the X-rays (diffracted through the angle 6) . Other possible structures for sodium chloride. — The most serious objection to this determination of the wave length of X-rays obviously rests in the implied statement that because it agrees with these rather meager data, the "sodium chloride arrangement" is the correct one for this salt. It will now be shown that other structures are possible. The effect of this observ^ation will of course be to render this determination of the wave length of X-rays based upon the study of the structure of a crystal indeterminate (and along with it all determinations of the structures of crystals), A factor which gives the effect of phase differences between the waves scattered by the atoms in any arrangement and which is therefore proportional, under certain conditions, to the intensity of the X-rays seemingly "reflected" by a plane of atoms can be written as* I ^ ^[pm cos 2 irn ihxm + kym + Izm) Y -\- m S]p „, sin 2 irn {hx,n + ky^ + IzJ ]-, m where / is the intensity of reflection from planes hkl having the same relative spacings, p is the scattering power of the atom m whose coordinate position is Xj^ymZmt and n is the order of the reflection. « Ralph W, G. Wyckoff. Amer. Journ. Sci. 50: 317. 1920. 370 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 The summation is to be taken over each atom in the unit cell. The spacings between like planes in a simple cubic lattice (Fig. 1) is pro- portional to -==^= (1) where h, k, and / are the indices of the plane. With the aid of these two expressions, and without any precise knowledge of the "laws" of scattering, it is possible to determine the ratio of the spacings between like planes to be observed from any arrangement of atoms. jP$ Every such, structure which possesses complete (holohedral) cubic symmetry must be either a general or a special case of one of the ten space groups O/, ^~^". The ratio of the spacings to be observed from each of these space groupings for the (100), (110) and (111) planes has been calculated.^ Of these ten groups but one, 0;^^ shows the sequence observed for sodium chloride. Any number of conceivable structures for sodium chloride can be developed from this space group by simply assigning different coordinate values to the positions of the sodium and chlorine atoms ; and except for very special values of these coordinates the ratio of the spacing from the three planes under discussion will always be the same as that experimentally observed for sodium chloride.*' For the sake of simplicity of illustration the least compli- cated of the special cases of this space group will be treated. The three special cases containing the fewest number of molecules within the unit cell are:^ Four equivalent positions : (1)000; Il0;l0h0ll (2)^2-2; OO^OiO;,^00. Twenty-four equivalent positions : (3) uOO;u-\- 1, 1,0; u-\- i, 0,1; uH; uOO ; \ - u,io ;\-u, 0,\ ;u\\; OuO;\,u + \,0; 0,u -\-\,\;\u\; OuO;\,i-u,0;0,\-u,\;lu\; 00u;\,0,u-\-\;0,\,u-\r-2;\\u; 00u;2,0,-2-u;0,\,\-u;-2 \u. ^ p. NiGGLi. Geometrische Krystallographie des Discontinuums , p. 492. ^ In the general case there are 192 equivalent positions within the unit cell of this group so that there may be as many as 192 molecules of sodium chloride within it. ' These results are taken from a book now being prepared for publication which con- tains an analytical expression of all of the special cases of each of the space groups. t SEPT. 19, 1921 WYCKOFF: WAVE LENGTHS OF X-RAYS 371 Placing sodium and chlorine (or chlorine and sodium) atoms at the positions of (1) and (2) yields the "sodium chloride arrangement." The next simplest structure that can be developed is obtained from arrangement (3) by placing atoms of sodium at the 24 points corre- sponding to a value of ii = Ui and chlorine atoms at the points where For such a structure the intensity of a reflection from a plane whose indices are h, k and / is proportional to (compare equation (1)) : A = pj,a [2cos2irnhui + 2c.os2irnkui +2cos2xw/wi + cos7rw(2/'2M] -^h-\- k) -\- coswJtih-hui + ^) + costtw {h + 2kni + h) + cosrw(/i + k-2kui) + cosTTiiQi + ^ + 2hti) + costtw {h + k-2lui) + cos7rn(2/zMi + fe + /) + cosTruih - 2hui + /) + cost;z {h + 2kui + /) + cosirn(h - 2kui + /) + cos7r?i(/i + 2/wi + /) + costtw {h + l-2lui) + QOS-Kn{2hUi -\-k -\- I) -f C0S7rw(/j + I ~2hUi) + COS7rw(2feM.i + ^ + /) + COSx«(fe - 2kUi + 0 + COS7rn(fe + 2/Mi + /) + COSttW (k + /-.2/?ii)] + Pci[a similar set of terms involving Wo] . The B term, a similar sine expression, is not in this instance qualita- tively important. When h, k and / are two odd and one even {h = 2m -\- 1, k = 2p -\- 1, I = 2q, w^here m, and p and q are any integers) or when they are two even and one odd (/i = 2m -f l,k = 2p,l = 2g) this expression is invariably equal to zero forn = 1. When, however, the indices are all odd, the intensity becomes A = 8 cos 2Tru (2m + 1) + 8 cos 2xzi {2p -fl) + 8 cos 27rM {2q + 1), for 11 = 1. Except perhaps for very special values of i/i and ii2, this expression will invariably have a value other than zero. In case M =2 all three types of planes will give factors of appreciable value. This arrangement is consequently in entire agreement with the data that we now possess^ upon which to base the first determination of the structure of a crystal.^ * This need be no longer true if we possessed accurate measurements of the relative intensities of the X-rays reflected from different planes of this type, combined with a knowl- edge of the positions of the electrons as the scattering centers within the atom. ^ The agreement with the spectrometer experiments is readily shown. By substituting the appropriate values for h, k and / in expression (1), the ratio of the spacings for the 1 1 (100), (110) and (111) planes in the cubic lattice is seen to be 1 '■~T'' ;-■ Since the calcu- lations given above have shown that the first order reflections from the first two of these planes is blotted out, the first observable reflections would occur at twice the angle of the first reflection and would consequently give apparent spacings of 1 _J_ J_ J_ . _? 2 2V2 "VS^"^^ ■V2 ■ V3' 372 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 It will be sufficient for the present purpose to have pointed out a single structure for rock salt, besides the generally accepted one, which is in agreement with the experimental data. There are undoubtedly numerous others which would serve equally well. It is not, however, feasible to indicate even all of the different types of structures that would fulfill the present requirements. This arises in part from the fact that besides those other structures which can be developed from 0A^ it is conceivable that such special values could be assigned to the coordinates of arrangements developed from other space groups that the intensity of the reflections from certain types of planes would be either obliterated entirely or would be so weak as to pass detection. As a result the sequence of spacings found for such an arrangement might agree with that for rock salt.^"'^^ The wave lengths of the X-rays calculated upon the basis of struc- tures representing sodium chloride but possessing various numbers of molecules in the unit cell must of course differ from one another. For instance the wave lengths of the rays diffracted through the angle 6 when calculated upon the assumption of the correctness of the sodium chloride structure and when calculated upon the assumption of the structure just considered which has twenty-four chemical molecules within the unit cell will stand in the ratio of v^i to -s/'IA. Quantum calculations of the wave lengths of X-rays. — It was early pointed out that the quantum hypothesis furnishes an independent way of obtaining the wave lengths of X-rays. By identifying the energy of the electrons required to excite either the characteristic X-rays^" or those of the short wave length limit of the continuous spectrum ^^ (as the case may be) with the energy of the rays that are produced, it is possible from the quantum relationship E = nhv to get the frequency (i^) and hence the wave length of the correspond- ing X-rays.^"* If it is assumed that such X-rays correspond with the " This sort of agreement with experiment is illustrated in the course of the treatment of the structure of magnesium oxide. Ralph W. G. Wyckoff. Amer. Journ. Sci. 1: 138. 1921. (See the grouping there called (j).) " In the light of present knowledge such a structure as we have just discussed need not be immediately disregarded as impracticably complicated, especially when it is borne in mind that it offers the chance of so placing a sodium and a chlorine atom nearer to one another than to other atoms as to preserve, in the existence of a chemical molecule, the older idea of the nature of solid sodium chloride. 12 W. H. and W. L. Bragg, op. cit., p. 72. 13 W. DuANE and F. S. Hunt. Phys. Rev. (2) 6: 166. 1915, etc. 1* W. DuANE and F. S. Hunt, op. cit. SEPT. 19, 1921 WYCKOFF: WAVE LENGTHS OF X-RAYS 373 expenditure of a single quantum of energy (n = 1), as would seem probable, then the resulting wave length is in agreement with that calculated from the "sodium chloride arrangement." The fact that it is not possible at the present time to obtain the structure of any crystal with surety without at the same time knowing the wave lengths of X-rays would consequently make it seem more logical to think of our determination of the wave lengths of X-rays (and with it all of our studies of the arrangement of the atoms in crystals) as based directly upon this quantum hypothesis, to stand or to fall with it. Of course even this determination of the wave length of X-rays is not entirely satisfactory. For instance if, for some reason, it should seem desirable to suppose that the expenditure of two quanta of energy were required to excite X-rays, then we should have a value of the wave lengths corresponding to a structure for sodium chloride having thirty-two chemical molecules associated wdth the unit. Fur- thermore the extension of the quantum relationship from the range of Hght radiation to that of X-rays was indeed a large extrapolation. In spite of this, the most persuasive evidence that a satisfactory deter- mination has been obtained is to be found in the fact that the appli- cation of the quantum relation to the limit of the continuous radia- tion^^ yields values for wave lengths which are in such close accord with a reasonable determination of crystal structure. This structure happens to be the "sodium chloride arrangement" (in the case of sodium chloride) . Summary Taking the case of sodium chloride as typical, it is shown that there are other structures besides the commonly accepted "sodium chloride arrangement" which are in agreement with the present experimental data. As a result of this lack of definiteness it is emphasized that it is more logical to consider the value of the wave lengths of X-rays as based upon the quantum hypothesis. ^* E, the energy, can be obtained from a knowledge of the voltage required to produce X-rays of the frequency v and of the charge (e) on the electron ; h is the universal constant of Planck; and n is an integer. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. OPTICS. — Dispersion in optical glasses: II. Fred H. Wright. Journ. Opt. Soc. Amer. 4: 195-204. 1920. (Geophysical Lab. Papers on Optical Glass, No. 29.) In this paper proof is given that, because of the relatively short range of the visible spectrum, the substitution in a dispersion formula of the reciprocal of the refractive index, or of the excess refractivity, or by analogy of other func- tions of the refractive index for the direct values, leads to dispersion formulas which are fairly satisfactory. Thus, if in the two-constant Cauchy formula, w = A + B-X"^orw— 1 =A' + B •X"^, the reciprocal of the refractive index or of the excess refractivity be written: m~^ = C' + D-X~- or (w — 1)"^ = C + D-X~^, the new equations represent rectangular hyperbolas in case X"^ is considered to be the independent variable. The last equation was recently suggested as a substitute for the Hartmann dispersion formula. A series of computations demonstrates, however, that for the crown-glasses this equation is less satisfactory than the Cauchy formula, while for the flint-glasses none of the foregoing equations is especially good. The last equation is, moreover, always less satisfactory than the Cauchy formula for computation purposes. The usefulness of the last equation appears, therefore, to be limited and less satisfactory for general application than the two-constant Cauchy formula. F. E. W. GEODESY. — Modern methods for measuring the intensity of gravity. Clar- • Ence; H. Swick. U. S. Coast and Geodetic Survey Special Pub. 69. Pp. 96, figs. 26. 1921. The measurement of gravity on land by the U. S. Coast and Geodetic Survey is made with an accuracy of about 2 or 3 parts in a million. Such accuracy with a field instrument requires more than ordinary care and skill on the part of the observer. At the present time all gravity measurements are made with pendulums only a quarter of a meter in virtual length, which are placed in an air-tight receiver and swung under a pressure of about 1/15 of an atmosphere. The cost and time required for a determination are very much less than they were and the results obtained are far more accurate than with the old types of apparatus. This publication is primarily a working manual for field and office use. Aside from one chapter of historical data the entire book is given over to a detailed description of the instruments and to instructions for making the observations and computations. All the necessary formulas and tables are included. Sample records are shown and a sample computation for one station is carried through all the required steps. INORGANIC CHEMISTRY.— r/j^ binary system dkermanite-gehlenite. J. B, Ferguson and A. F. Buddington. Amer. Journ. Sci. 50: 131-40. 1920. The binary system akermanite (2CaO.Mg0.2SiO)-gehlenite (2CaO.Al203- SiOs) was studied by the quenching method and the solidus and liquidus curves were determined. The system forms a complete series of solid so- lutions with a minimum melting-point about 70° below the melting-point 374 SEPT. 19, 1921 abstracts: geology 373 of akermanite, the component of lower melting-point, at a composition of about 74 per cent Akermanite and 26 per cent gehlenite. The densities of crystals and glasses of akermanite, gehlenite, and several intermediate mixtures were determined and found to confirm the isomor- phous character of the system. Akermanite was found to show the unusual feature of its glass having a greater density than the corresponding crystals at 25° C. This peculiar character is checked by the indices of refraction for glass and crystal, respectively, the index of refraction of the glass being greater than the maximum index of the crystal. The optical characters of the crystals are a continuous function of the composition. In optical characters akermanite is positive and gehlenite is negative. Crystals of certain intermediate compositions are isotropic for light of a definite wave length and constitute a transition phase between positive and negative crystals. J. B. F. GEOLOGY.- — Mining in the Matanuska coal field and the Willow Creek dis- trict, Alaska. Theodore Chapin. U. S. Geol. Survey Bull. 712-E. Pp. 46(131-76). 1920. This report describes developments in the Matanuska coal field up to the end of 1918 and records some recently acquired knowledge of the structure and stratigraphy of the coal-bearing rocks and the character and persistence of the coal beds, details of which are becoming more apparent with the open- ing of the underground workings. The areal distribution, character, chemical analysis, steaming and coking quahty of the coal are discussed, stratigraphy and structure of the region are described, and the mining developments depicted. R. W. Stone. GEOLOGY.— Mmmg in northwestern Alaska. S. H. Cathcart. U. S. Geol. Survey Bull. 712-G. Pp. 14(185-98). 1920. Discusses the adverse conditions which caused greatly decreased mineral production in Seward Peninsula in 1918; describes the use of cold water in thawing perpetually frozen muck and gravel and its application to placer mining. Tungsten and platinum were produced, but wholly incident to the mining of placer gold. A small quantity of coal was mined, and drilling for oil in a locality where the hard rocks are granite and schist was unsuccess- ful. R. W. Stone. GEOLOGY.— r/ie Mogollon district, New Mexico. Henry G. Ferguson. U. S. Geol. Survey Bull. 715-L. Pp. 34(171-204). 1921. The Mogollon or Cooney district is in the southwestern part of Socorro Coimty, New Mexico, about 14 miles from the Arizona line. The rocks of the district are nearly all lavas, or sedimentary rocks composed of materials derived from lavas. Flows of rhyolite and andesite, together with sedimen- tary and pyroclastic rocks, had reached a total thickness of several thousand feet when faulting of considerable magnitude took place and the region was broken up into irregular blocks bounded by normal faults. The faulting was closely followed by the introduction of mineral-bearing solutions, which followed channels determined by the previous faulting, so that practically all the faults are the sites of veins. The ores of the district are valuable mainly for silver. Argentite, pyrite, bomite, chalcopyrite, and tetrahedrite, together with small amounts of horn silver and native silver, are the principal ore minerals. The ores are princi- pally sulfides and give evidence of being in part due to enrichment, although 376 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 15 the relative importance of secondary processes has not yet been fully deter- mined. R. W. Stone. GUOLOGY .—Potash resources of Nebraska. W. B. Hicks. U. S. Geol. Survey Bull. 715-1. Pp. 15(125-39). 1921. Describes the location, area, and probable potash content of the alkali lakes in the sand-hill region of Nebraska, and discusses the composition of the brine and origin of the potash. R. W. Stone. GEOLOGY.- — Mineral resources of the Goodnews Bay region, Alaska. George L. Harrington. U. S. Geol. Survey Bull. 714-E. Pp. 22(207-28). 1921. The Goodnews Bay region as here considered embraces the territory lying south of Arolic River and draining into Kuskokwim Bay, Alaska. In many respects this region is one of the most inaccessible in Alaska for a small expedition. For a number of years it has been necessary to come overland from the Yukon either by the portage or by way of Iditarod, or to travel in a kayak or canoe, or by small schooner or sailing boat from Togiak. The sedimentary rocks comprise limestone, argillite, sandstone, and con- glomerate, and the metamorphosed equivalents of most of these. A con- siderable variety of igneous rocks is also found, including basalt flows, dikes that were taken in the field to be andesites, and intrusive granites, with some massive intrusives that are probably intermediate in composition between the granite and the basalt. A large part of the region is covered by unconsolidated deposits of alluvial, glacio-fluviatile, and marine origin. Gold placer mining is the principal interest. The original deposition of the gold in fissures associated with quartz was probably genetically re- lated to the intrusion of the late Mesozoic granites into the sedimentary and earlier igenous rocks, which range from Paleozoic to probably late Meso- zoic in age. From the original deposits the gold has been eroded by streams and other agencies, not including glaciation, and has been concentrated in placers by some streams, mainly those in the vicinity of the granites. Glacial erosion has removed most of the gold-placer deposits and has scattered the gold widely over a considerable area in amounts not suitable for profitable mining. Postglacial concentration has been effected by some streams in connection with the erosion of the rocks containing auriferous veins. R. W. Stone. GEOLOGY.^ — Potash deposits in Spain. H. S. Gale. U. S. Geol. Survey Bull. 715-A. Pp. 16, pis. 3, figs. 3. 1920. Potash was discovered in Spain in 1912, during an attempt to open a salt mine near Suria, Province of Barcelona. Evidence gained in a shaft and several borings convinced local engineers that the deposits contain 200,000,000 tons of piure potash (K2O), and in 1918 a mine shaft and a refining plant were begun. The shaft is located near the axis of an anticline, in a zone of intense folding, and the potash and associated salt beds are probably much con- torted; such contortions are seen in the beds in the crest of the anticline at Cardona, 8 miles distant, where salt is extensively mined. The evidence of the existence of potash in the Cardona deposits, however, is not very definite, and information as to the occurrence in the surrounding region is meager. Many concessions for prospecting and exploitation in an area of 400 square miles have already been granted, and the Government has re- SEPT. 19, 1921 proceedings: ANTHROPOLOGICAL SOCIETY 377 served about 1800 square miles for future exploration. Restrictive legis- lation, as outlined in this paper, somewhat hampers activities in the district. The prospects indicate an output of potash ample for Spanish needs, but no judgment can yet be ventured as to the influence of the Spanish field on the world market. J. D. Sears. CERAMICS.— -A^o/^ on the motion of the stirrers used in optical-glass manu- facture. E. D. Williamson and L. H. Adams. Journ. Amer. Ceramic Soc. 3: 671-677. 1920. (Geophysical Lab. Papers on Optical Glass, No. 25.) Perhaps the most noticeable difference between the manufacture of optical glass and that of other types of glass (bottle, window, and plate) is that the melt must be stirred vigorously in order to get complete mixing. The reason behind this necessity is the close approach to homogeneity specified in the tests to be passed by the finished article. The stirrers used are necessarily of a very simple nature, generally consisting of a clay rod attached at right angles to an iron water-cooled pole, the other end of which is driven at steady speed in a horizontal circle, while supported near the center by a pulley or other support. Such a device does not cause circular motion of the stirring- rod, but causes it to describe an egg-shaped figure at a variable speed. A slightly more uniform motion is obtained if a pin attached to the pole slides in a fiked slot instead of the pole passing over the pulley, but the general results are not very different. If the support is not close to the center of the pole, the motion of the rod is far from circular and a large part of the glass in the pot is not stirred. E. D. W. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES ANTHROPOLOGICAL SOCIETY 548th meeting The 54Sth meeting of the Society was held at the United States National Museum on October 26, 1920, at 4.45 p.m. Dr. AlES Hrdlicka, curator of physical anthropology, U. S. National Museum, addressed the Society on The anthropological problems of the Far East and the Pacific. The lecture was carefully prepared and dealt with a subject with which Dr. Hrdlicka was most familiar both because of long study and recent field work. The paper was discussed by Mr. Holmes, Mrs. Zelia Nuttall, Dr. Michelson, and Dr. Swanton. 549th meeting At the 549th meeting of the Society, held at the National Museum at 4 . 45 p.m. on November 16, 1920, Mr. Sylvanus G. MorlEy, Associate of the Carnegie Institution of Washington, addressed the Society on The hiero- glyphic writing of the ancient Mayas. Mr. Morley illustrated his excellent presentation with charcoal drawings of the glyphs. At the conclusion of Mr. Morley's lecture, Mr. W. E. Gates, of Baltimore, gave an interesting and enthusiastic talk of ten minutes on the subject of Maya writing, and told especially of recent progress which he has made in the deciphering of color symbols, to which IMr. Morley had referred in his talk. 378 journal of the washington academy of sciences vol. 11, no. 15 550th meeting The 550th meeting was held in the National Museum at 4.45 p.m. on December 14, 1920, and had as program an illustrated lecture by Mr. S. D. Bullock, of the Bureau of Plant Industry, Department of Agriculture, entitled Ten years among the Araucanians of Chile. Mr. Bullock has lived for ten years among the Araucanian Indians of the vicinity of Valdivia, Chile, as industrial teacher of the Indians, and knows them and their customs intimately. At the close of the lecture Mr. Bullock exhibited some Arau- canian costumes and other objects. Questions were asked by Lieut. W. E. Safford and others. 55 1st meeting The 551st meeting was held at the National Museum at 4.45 p.m. on January 18, 1921. Mr. William E. Myer, of Nashville, Tennessee, gave an interesting lecture on Recent explorations in the Cumberland Valley, Tennessee, being an account of archaeological field work done by him in 1920 for the Bureau of American Ethnology. The talk was illustrated by lantern slides. The lecture was discussed by Dr. Fewkes and others. 552d meeting The 552d meeting was held at the National Museum at 4.45 p.m. on February 8, 1921. Lieut. W. E. Safford, of the Department of Agriculture, spoke on Old and new Samoa. The lecture was illustrated by original slides. Lieut. Safford made his first visit to Samoa on the U. S. Ship Mohican in 1888, before Robert Louis Stevenson came to the islands, and made a second visit in 1899, two years after Stevenson's death. The lecturer spoke through- out from first-hand information. At the close of the lecture there was a dis- cussion by Dr. Hough, Mr. Holmes, and others, 553d meeting At the 553d meeting, held at the National Museum at 4.45 p.m., March 21, 1921, Dr. J. Walter Fewkes, Chief of the Bureau of American Ethnology, spoke on The fire temple of the Cliff Dwellers. The ruin of the Fire Temple was excavated by him in the Mesa Verde National Park, Colorado, during the summer of 1920. The lecture was beautifully illustrated by slides. It was discussed by Dr. Hough, Mr. Holmes, and others. 554th meeting The program of the 554th meeting, held at the National Museum at 4.45 p.m., March 22, 1921, was a paper by Mr. G. N. Collins, of the Department of Agriculture, on The origin and early distribution of maize. Mr. Collins agrees on the whole with Harzberger, who advocated the theory that maize has been hybridized with some other close relative, but puts the relationship a little further off — for genetic reasons. The paper was discussed by Dr. Hough, Prof. Hitchcock, Lieut. Safford, Mr. La Flesche, and others. 555th meeting The 555th meeting of the Society was held in conjunction with the Medical Society of the District of Columbia, at the new home of the latter at 1718 M Street, N. W., on April 5, 1921, at 8.00 p.m. Dr. George M. Kober presented as address of the retiring president of the Anthropological Society of Washington, 1920, a paper entitled A plea for the prevention of permanent disabilities in childhood. In pursuance of the established custom of the So- ciety, there was no discussion of this paper, it being a presidential address. SEPT. 19, 1921 SCmNTlFlC NOTES AND NEWS 379 556th meeting The 556th regular meeting (42nd annual meeting) of the Society was held at the National Museum at 4 .45 p.m., April 19, 1921. Dr. C. Hart Merriam, President of the Society, dehvered a lecture on The Indians of the Vosemite Region, California. The lecture was illustrated by a large number of slides showing the distribution of the dialects of the stock, the history of the In- dians, the landmarks of the region, and the present survivors. At the close of the lecture the annual meeting of the Society was held. The Secretary, John P. Harrington, reported that the Society has at present 51 active members, 6 life members, 4 associate members, and 2 honorary members, making a total membership of 63. New members added during the year were: Mr. W. E. Meyer, Mr. M. J. Caples, Mr. R. E- Montgomery, and Miss Ellen Hayes. One active member was lost through death: Dr. Edwin LEE Morgan. The Treasurer's report showed a bal- ance to the credit of the Society of $139.56, and total assets of $667.47. The following officers were reelected for the ensuing year: President, C. Hart Merriam; Vice President, Neil M. Judd; Secretary, John P. Harrington; Treasurer, J. N. B. Hewitt; Board of Managers, Charles L. G. Anderson, Felix Neumann, Francis La Flesche. John P. Harrington, Secretary. SCIENTIFIC NOTES AND NEWS The topographic survey of the Virgin Islands was completed by the U. S. Coast and Geodetic Survey in June. An interdepartmental conference was held on July 25 at the Interior Department to discuss the status of patents arising within the government service. The purpose of the conference was to coordinate and formulate the views held in the various bureaus and departments on this subject. After discussion, a committee of five was appointed to report in detail ways and means for the suggested coordination, and another committee of three was appointed to develop a plan for a general clearing house of information for the departments with respect to licenses, shop rights, and titles in patents which the Government has acquired or may acquire. Mr. Walter G. Campbell was appointed acting chief of the Bureau of Chemistry in August. A geological party of four, consisting of Professors R. A. Daly and Charles Palache of Harvard University, Professor G. A. F. MolEngraaf of the University of Delft, Holland, and Dr. F. E. Wright of the Geophysical Laboratory, Carnegie Institution of Washington, will spend the coming winter in southern Africa, in a geologic and petrologic study of the Bushfeld igneous complex in Transvaal. Dr. H. C. Dickinson, chief of the automotive investigations division of the Bureau of Standards, has been granted a leave of absence to become director of research for the Society of Automotive Engineers. He will con- tinue to assist in the work of the Bureau in a consulting capacity. Dr. Graham Edgar, professor of chemistry at the University of Virginia, has been associated with the Fixed Nitrogen Research Laboratory at the American University during the summer, completing some work which he began there during the War. Major Louis Albert Fischer, chief of the division of weights and measures of the Bureau of Standards, died on July 25, 1921, in his fifty-eighth year 380 JOURNAL OF' THE WASHINGTON ACADEMY OF SCIEJNCES VOL. H, NO. 15 Mr. Fischer was born in Washington, D. C, January 4, 1864. He was educated at George Washington University, and afterwards joined the staff of the U. S. Coast and Geodetic Survey, where he was in charge of the ofifice of weights and measures, the forerunner of the present Bureau of Standards. He took an active part in the organization of the Bureau in 1901, and had been in charge of its special division on standards of length, volume, and mass since that date. He was a leader in the movement to promote uniform standards of weights and measures in the States and municipalities of the country. He was a member of the Academy, past president of the Philo- sophical Society, and chairman of the Washington Section of the American Society of Mechanical Engineers. Dr. F. E. Matthks, of the U. S. Geological Survey, has been spending the summer in exploration of the crest of the Sierra Nevada as far south as Kings River Canyon, in search of data on the earlier glaciation of the region. Mr. J. D. Northrop has been reinstated as geologist in the U. S. Geological Survey, and has been assigned to duty in the mineral division of the Land Classificat'-on Board. Dr. T. Okada, director of the recently established Imperial Marine Ob- servatory at Kobe, Japan, visited the scientific institutions of Washington in August. Prof. J. F. Rock returned in June from an eleven months' exploring trip through remote parts of Siam, Burma, Assam, and Bengal for the U. S. Department of Agriculture. He showed the Botanical Society on June 27 the first photographs ever exhibited of the tree, Taraktogenos k^irzii, in its native habitat. The seeds of this tree are the source of chaulmoogra oil, a remedy for leprosy, and Professor Rock secured enough of the seeds to assure the establishment of a plantation of the tree in Hawaii. Dr. J. H. Shrader, formerly with the Bureau of Chemistry, U. vS. Department of Agriculture, became director of the bureau of chemistry and food of the Health Department of Baltimore on July 1. Dr. George Otis Smith, director of the U. S. Geological vSurvey, attended a meeting on July 20 in London as a member of the organization committee of the International Geologic Congress. Dr. W. W. vSkinnER, chief of the water and beverage laboratory of the Bureau of Chemistry, has been appointed assistant chief of the Bureau. Mr. R. S. Tour, chemical engineer of the Nitrate Division, Ordnance Department of the Army, has been appointed dean of the department of chemical engineering at tlae University of Cincinnati. Dr. TsAi, chancellor of the National University of Peking, China, visited the scientific institutions of Washington in June. Mr. RosENDO Vargas, a member of the Taos tribe of Indians of New Mexico, has been assisting Mr. J. P. Harrington of the Bureau of Ethnology in the study of the ethnology of the tribe. Mr, Vargas is at present an em- ployee of the office of Indian Affairs, Department of the Interior. Mr. C. J. WEvST has resigned as director of the information department of A. D. Little, Inc., of Cambridge, Massachusetts, to become managing editor of the Tables of Physical and Chemical Constants now being compiled under the joint auspices of the National Research Council, the American Chemical Society, and the American Physical Society. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol.11 October 4. 1921 No. 16 PHYSICS. — A radioactive quantity requiring a name.'^ N. Krnest DoRSEY, Bureau of Standards. The problems that are encountered in the quantitative study of radioactive materials and processes may be divided into two classes. In one class will be placed the strictly chemical problems; such as, the amount of the element that is contained in a ton of ore, the ratio of the amounts of different elements that are found associated, the atomic weights and the chemical properties of the several elements. In the other class will be placed the problems that are primarily con- cerned with radioactive phenomena; such as, the rate of transforma- tion, the rate of emission of energy, the rate of production of alpha or of beta particles or of gamma pulses. In problems of the first class one is concerned with the total weight or with the total number of atoms present, and the amount of the element may appropriately be expressed in grams or in terms of the number (N) of atoms present. These problems do not differ in any essential respect from those encountered in dealing with other ele- ments ; the radioactiA^e properties of the element enter into the problem mainly as a means by which different amounts of the material can be compared. In problems of the second class the results may likewise be expressed as functions of the total weight, or of the total number of atoms, of the element present, but when this is done certain fundamental rela- tions are obscured. Only a relatively small fraction (XA^ of the atoms present take part in the phenomenon studied, and the thing that is of fundamental interest is the effect produced per atom actively concerned. It is in this eft'ect per active atom that information re- garding the atomic forces, structure, and instability, and the way these vary from element to element, are to be sought. In such prob- lems one is concerned with the number of atoms that have trans- formed in a certain time ; he is but incidentally interested in the pres- ence of atoms that have remained untraiisformed. He wishes to know ' Contril)ution from the Bureau of Standards. Received August I, 192L 381 382 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. IG the energy emitted per transformed atom, the number of alpha parti- cles emitted per transformed atom, etc. If his observations extend over a time t, he wishes to know the number of atoms transformed during that time; i.e., 'KNt where X is the transformation constant, and N is the total number of atoms present. He is primarily inter- ested in XA^, rather than N. When only a single element is being considered it is a matter of indifference whether the result is expressed in terms of grams, or of N, or of \N. But when similar measurements have been made for two different elements, and it is desired to compare the results obtained these must each be expressed in terms of the quantity, XA^, involved, if fundamental relations are to be obtained. For example, if it is desired to compare the heating effect produced by the transformation of radium with that produced by the transformation of rad'um emanation, then these effects are expressed in gram calories per hour per gram of radium, and per that amount of radium emanation that can exist in equilibrium with one gram of radium ; \N is the same for each of these quantities. This is quite satisfactory when only related elements in an unbranched portion of a family are being considered ; but if a lateral branch arises between the first and the second element, then a more complicated description of the reference amount of the second element is required. For example, uranium-II branches into uranium-Y and ionium, some 4 per cent going into the former ; consequently the heating effect of one gram of uranium-II is not strictly comparable with the heating effect of the amount of ionium that can exist in equilibrium with one gram of uranium-II, but with 1/0.96 of the latter amount. When the effects of elements belonging to unrelated families are to be compared, they will likewise be referred to quantities having the same value for \N; i.e., to quantities so chosen that the same number of atoms take part in the production of the effect. For one element the result may be expressed in terms of the effect per gram, but the corresponding quantity of the other element cannot be very directly expressed with our existing terminology. This difffculty would be removed if there were a name to denote the amount of a radio-element corresponding to a fixed value of XA^^. For example, if XA^ for one gram of radium is equal to k, and that amount of any element for which XA^ = fe is called an r, then an r of any element will be radioactively comparable in amount to an r of any other element, whether related or not. A gram of radium will contain one r of radium, a curie will contain one r of radium emanation, Oct. 4, 1921 dorsey: radioactivte quantity 3S3 the amount of radium-A that can exist in equilibrium with one gram of radium will contain one r of radium-A, the amount of ionium that can exist in equilibrium with one gram of radium will contain one r of ionium, the amount of uranium-II that can exist in equilibrium with one gram of radium will contain (1/0.96) r of uranium-II, etc. As thus defined, an r of any material is that amount of the material that will produce transformed atoms at the same rate as transformed atoms are produced by one gram of radium. The value in grams or in atoms of an r of any element depends upon the ratio of the transformation constant and of the atomic weight of the element to those of radium ; denoting the transformation constant of radium by Xo, the number of atoms in one gram of radium by No and the atomic weight of radium by Ao the number of atoms (A^) in one r of any other element is determined by the equation N= ^- No X and the weight in grams of one r of the element is Xo .1 X -4o since NqAq is by definition equal to one gram. To the precision with which the transformation constants are known, an r of radium emanation weighs 6.55 X 10~^ gram; pf radium-A, 3.54 X 10~^ gram; of uranium-II, 1.51 X 10^ gram; of actinium, 1.29 X 10~^gram; of mesothorium-1, 4.29 X 10~^gram. The quantity that we have denoted by the letter r plays in radio- activity a part that is analogous to that played by the gram-molecule in physical chemistry; the adoption of some name for it will appreci- ably facilitate the recording, discussion, and presentation of radioac- tive observations and phenomena. One illustration of the increased facility that will be secured by the adoption of a name for this quantity is afforded by the frequent use of expressions of the form "radium-C corresponding to one gram of radium" (Rutherford), "von der mit 1 g. Ra in Gleichgewicht stehenden Ra-C Menge" (Hess) ; these would be replaced by the much simpler "one r of radium-C," where the letter r stands for the name adopted. Another illustration may be taken from the surgical application of the active deposit of radium. When it is desired to state the amount of, say, radium-C present, a circumlocution like those in the preceding paragraph is required. This long and awkward expression is fre- 384 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 16 quently abbreviated to the form "% mg. of radium-C," or to ''% milli- curies of radium-C." Such abbreviations may lead to serious mis- understanding and confusion, and can readily be replaced by the exact and unambiguous expression "x mr of radium-C," so soon as a name has been given to the quantity r. The customary expression for the rate of accumulation of a radio- element is = Xl A^2 - >^2 ^2 where A^i and N2 denote, respectively, the total number of atoms of two successive elements. The rate of accumulation of element 2 is made to depend upon both Xi and Xo, although it is evident that the instantaneous growth of element 2 can ultimately depend upon only its own constant and its departure from equilibrium. This is brought out plainly when quantities of the elements are measured in terms of r. Let there be Ri r's of element 1 and R2 r's of element 2 ; as before, let k denote the number of transformed atoms produced in unit time by one gram of radium; i.e., by one r. Then kR2 will be the number of atoms of element 2 that transforms in a unit of time, hence kRo = XiNt, where N2 is the number of atoms of element 2. Whence dA/"2 ^. dRa "d^ ^2 d^ But dt Hence dRo dt — X2 [Ri — R2) If Ri = R2 the two elements are in equilibrium. The differential equation shows at once that the instantaneous growth of element 2 is equal to the product of X., by the departure from equilibrium. The coefficients in the equation applying to the decay of a group of elements initially in equilibrium (Case 2 of Rutherford) are unsym- metrical when the equations are written in the usual notation, the total number of atoms present being the unit. For example, the coefficients for the third element (Rutherford's R) are X2 Xi Xi X2 a = 7^ — TTTi^ — n; 0 = (X2-Xi)(X3-Xi)' " ~ (Xi-X2)(X3-X2)' ' ~ X3(Xi-X3)(X2-X3)" Oct. 4, 1921 dorse y: radioactive quantity 385 When the unit is the r these coefficients become X2 X3 X3 Xi Xi X2 ^ " (X2-Xl)(X3-Xl)' ^" (Xl-X2)(X3-X2)' ^" (Xi-X3)(X2-X3)' In these the symmetry is perfect. A name for the quantity r would be most useful when curves similar to those given by Rutherford as figures 102, 103, 110 {Radioactive substances and their radiations) have to be plotted. The ordinates of these curves are proportional to the number of r's of the several ele- ments, and to the sum of these r's. If the alpha particles from each element are equally effective in producing the effect measured, the total effect is proportional to the sum of the r's and on this assump- tion the ordinates are proportional to the "activities." In lieu of a name for the quantity r the ordinates are labeled "activities," and the assumption is explained in the text. Were there a name for the quan- tity r the ordinates could be so marked and no assumption would be required. It has been shown how the weight of an r of any element can be computed. Consequently there is no serious difficulty in determining the number of r's contained in a given amount specified in grams; or conversely. In the portion of the radium family comprised between ionium and radium-C, both inclusive, the elements are now actually measured in terms of r, which in this region may be regarded as merely an abbreviation of the oft recurrent phrase "amount that is in equili- brium with one gram of radium." Beyond these branch points a factor depending upon the branching ratio must be introduced. Sev- eral methods are available for determining the value in r's of a radio- actively defined amount of an element of another family. If a chemi- cally pure salt of known composition either of this element or of another genetically related to it and not separated from it by a branch point has been prepared, we can determine at once the value of \N for a gram of that element. The ratio of this to k will be the number of r's in a gram of that element, and likewise in such amounts of its derivatives as can exist in equilibrium with a gram of it. Or the num- ber of alpha particles emitted per second by the material considered or by an equilibrium amount of a related element might be determined. This number divided by 3.72 X 10 ^'^ (the value for one gram of radium, i.e., the quantity we have denoted by k) will be the number of r's in the quantity considered, unless more than one alpha particle is emitted during a single transformation of an atom; this can be determined by suitable observ^ations. 386 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 16 For many reasons it is desirable to have a name for the quantity which we have designated by the letter r. Thus arises the question whether the term "curie," which by international agreement is an r of radium emanation, shall be redefined so as to cover the entire field embraced by our definition of the quantity r, or whether a new name shall be added to the nomenclature of the science. In the latter case the name rutherford seems most appropriate. In order to obtain an expression of opinion regarding the advisa- bility of adopting a new name for the quantity we have denoted by the letter r, the Bureau of Standards submitted the preceding portion of this paper, in essentially its present form, to a number of chemists and physicists. While agreeing that it is desirable to have a name for the quantity r, the replies were divided regarding the advisability of adding a new name to the nomenclature. The majority of the re- plies favored the extension of the "curie" to cover the entire field, so as to avoid the existence of two names to denote the same amount of radium emanation. Such an extension involves a redefinition of the curie. The extended term cannot be defined as the amount of an element that is in equiUb- rium with a known amount of any other element, though for the ele- ments of the uranium family from ionium to radium-C it will actually denote the amount of these elements that can exist in equilibrium with one gram of radium. Neither should it be thought of as that amount of an element that under certain conditions will give a fixed, specified ionization current. Its definition must be equivalent to the one we have given for r; namely, as thus extended, a curie of any material will be that amount of the material that will produce transformed atoms at the same rate as transformed atoms are produced by one gram of radium. MINERALOGY. — Lazulite of Graves Mountain, Georgia, with notes on other occurrences in the United States.'^ Thomas L. Watson, University of Virginia. Graves Mountain, Georgia, is located in Lincoln County about 10 miles west from Washington, Wilkes County, the nearest raihoad point. The locality has long been known to mineralogists for the occurrence of rutile and lazulite in association with a group of more common minerals. These are, named without regard to order of abundance, lazulite, rutile, cyanite, pyrophylHte, hydrous antho- 1 Received July 18, 1921. Oct. 4, 1921 watson: lazulite 387 phyllite, hematite, quartz, and muscovite. In addition to these, Shepard" reported barite, minute perfectly formed transparent crystals of sulfur, crystals of pyrite, and traces of gold. The locality is probably best known for the occurrence of rutile, crystals of which have been figured and described by European crystallographers. The ridge locally known as Graves Mountain has a length of 2 miles along an approximate northeast-southwest direction, is less than half a mile wide, and rises several hundred feet above the surface of the surrounding Piedmont Plain. The slopes of the ridge are very unequal, and are greatly roughened from weathering. Graves Mountain is composed of Cambrian quartzite of which there are two facies:^ (1) a foliated quartzite schist which forms the basal portion of the ridge and extends some distance up the slope on the northwest side, and (2) a fine-grained massive quartzite (ita- columite), which forms the crest and upper slopes. Both are com- posed dominantly of quartz with the difference in chemical compo- sition shown in the following partial analyses: Quartzite Massive quartzite schist (itacolumite) SiOa 79.18 69.74 AI2O3 14.14 24.86 FeaOs 3.17 0.53 Igneous rocks are not known to occur in the ridge proper, but are common in the surrounding area. Lazulite, a rare basic phosphate of aluminum, magnesium, and ferrous iron, corresponds to the formula (Fe, Mg) (A10H)2(P04)2 in which the ratio of Fe: Mg(Ca) varies^ from 1:12 to 2:3. It and the associated minerals occur in the itacolumite of the crest and higher slopes of Graves Mountain. The lazulite is irregularly distributed through the itacolumite in rude nests or bunches of single crystals and crystal aggregates. Quartz veins of a few inches thickness cut the quartzite on top of the ridge and sometimes carry rutile, pyro- phyllite, and iron oxide, but lazulite has not been observed in them. The lazulite is imbedded in the itacolumite usually as crystals which range in size up to an inch in length, but as a rule the individual crystals are much smaller. It also occurs massive without distinct crystal boundaries. The crystals are usually acute pyramidal in 2 C. U. Shepard. Amer. Journ. Sci. 27: 36-39. 1859. ^ For a detailed description, including petrography, of the two facies of the quartzite, see Thomas L. Watson and J. Wii,Bxni Watson, A contribution to the geology and mineralogy of Graves Mountain, Georgia. Univ. of Virginia Publications, Bull. Philos. Soc, Sci. Sec, 1: 220-221 (No. 7). 1912. * E. S. Dana. A system of mineralogy, pp. 798-799. 388 JOURNAL OF THE WASHINGTON ACADEMY OV SCIENCES VOL. U, NO. 16 habit and frequently twinned. Shepard^ described and figured five crystals of lazulite from the Georgia locality, and stated that a twin (his fig. 5) "is by far the most abundant form equalling in fre- quency all the others combined." The mineral is opaque, of azure blue color when fresh, has uneven fracture, indistinct cleavage, and vitreous luster. Blow-pipe tests gave the usual reactions characteristic of the mineral. The lazulite is frequently intergrown with greenish to colorless columnar cyanite which is partly altered to muscovite (damourite), and is less often intergrown with coarse white quartz. Small grains of red rutile and of colorless quartz, especially the former, form frequent inclusions in the blue lazulite. The cyanite weathers yellow-brown in color and, like the lazulite, also contains inclusions of red rutile and colorless quartz. Similar red grains of rutile are also frequent in the quartzite. Weathered surfaces of the lazuli te-bearing portions of the itacolumite are generally rough from the more resistant coarse lazulite and cyanite standing in relief. Scales of colorless mica are more or less conspicu- ous in weathered specimens of the rock. When weathered, the lazulite is of lighter or paler blue color, some- times almost entirely white or colorless, but is frequently spotted or mottled white and blue. Microscopically, thin sections show al- teration of some of the lazulite along the periphery and fractures, into minute scales and fibers of a light gray nearly white substance, sometimes stained with iron oxide, having high refraction and double refraction, which probably can be referred to hydrargillite. Under the microscope thin sections of the lazulite show inclusions of rutile and quartz, and occasionally cyanite and muscovite, all of which are common associates in hand specimens of the lazulite. The lazulite is light blue in thin section and distinctly pleochroic, with Z = Y > X. It is optically negative (-), with 2V large. The dispersion is slight, p < V. The values for the indices of refraction and the birefringence determined by Dr. E. S. Larsen on specimens of the lazulite yielding the analysis given below are as follows : a = 1.604, nearly colorless /3 = 1.633, deep blue 7 = 1.642, deep blue T-« = 0.038 A chemical analysis of the lazulite yielding the above optical data is given in table 1. ^ C. U. Shepard. Op. cit. Oct. 4, 1921 watson: lazulite 389 The formula derived from the column of ratios in table 1 is that given in the standard texts for the mineral, except that CaO is usually not expressed : (Fe, Mg (Ca)) O . AI2O3 . P2O5 . H2O withFeO:Mg(Ca)0 = 1 :5, FeO: CaO = 1 : 1, and MgO: CaO = 4: 1. When compared with analyses of lazulite from other localities the Georgia mineral shows a high percentage of CaO (3.30 per cent), the largest reported in any analysis of the mineral of which the writer has found record. The analysis of lazulite from North Carolina quoted by Dana'' shows no CaO. With two exceptions, Georgia and North Carolina, analyses of lazulite thus far published represent TABLE 1. Analysis of Lazulite III I II " . P2O0 38.25 40.61 286 1 AI2O3 33.92 36.02 353 1.2 FeO 3.99 4.24 59] MgO 9.08 9.64 241}- 1.3 CaO 3.12 3.30 59 j H2O 5.83 6.19 343 1.2 Si02 6.05 100.24 100.00 Sp. G 2.958 I. Lazulite collected by Thomas L. Watson from Graves Mountain, Lincoln County, Georgia. J. Wilbur Watson, analyst. II. Analysis I with the Si02, which represents admixed quartz, deducted, calculated to 100 per cent. III. Ratios from II. foreign localities, in which CaO is indicated as being either absent or present in quantity of less than 1 per cent. The only exception found by the writer is an analysis of lazulite quoted by Dana^ from near the mouth of Churchill River, Keewatin, Canada, in which CaO is given as 2.83 per cent. Based on CaO content, published analyses of lazulite, most of which are old, would group the mineral under (o) calcium lazulite, apparently the less frequently occurring variety, to which the mineral from Graves Mountain, Georgia, and Keewatin, Canada, belongs; and (6) essentially calcium-free lazulite which includes the more common variety of the mineral represented by analyses from many European localities. OTHER OCCLTRRENCES OF LAZULITE IN THE UNITED STATES. Lazulite occurs both as crystals and as massive granular to compact material in quartz veins and in metamorphic rocks, especially quartz- • E. S. Dana. Op. cit., p. 799. ' E. S. Dana. Op. cit., p. 799. 390 JOURNAL Olf the; WASHINGTON ACADEMY OF SCONCES VOL. 11, NO. 16 ites of the variety itacolumite. When fresh its azure blue color, vitreous luster, indistinct cleavage, and hardness (5-6) are the more important megascopic properties. It is sub translucent to opaque, and has a specific gravity of 3 =^ . The known occurrences of lazulite in the United States are limited to North Carolina, South Carolina, and Georgia in the southeast Atlantic States, ^ and to California on the Pacific coast. The localities are Graves Mountain, Lincoln County, Georgia; Chesterfield district. South Carolina ; Clubb and Crowder Mountains, Gaston County, and Sauratown, Stokes County, North Carolina. The largest number of occurrences is in California, where the mineral has been reported from the following localities:^ Breyfogle Canyon in Death Valley, Inyo County; San Gabriel Mountain, Los Angeles County; near Mono Lake and in Green Creek Canyon near Bodie, Mono County; and Oceanside, San Diego County. Foreign occur- rences of lazulite have been reported from localities in Austria, . Switzerland, Sweden, Brazil, and Canada.^" Probably the first occurrence of lazulite noted in the United States was by H. S. Hunter in 1822, near Crowder Mountain in the southern part of Lincoln (now Gaston) County, North Carolina. The mineral was found later in greater abundance near the southern end of Clubb Mountain, about 30 miles northeast of Crowder Mountain. Its occurrence in the North Carolina and Georgia localities is in Cambrian quartzite, as crystals and crystal aggregates irregularly distributed through the rock, usually in nests or bunches. With the exception of corundum, which is unknown in the Georgia locality,- the mineral associates of lazulite in the two states are the same. They include rutile, cyanite, pyrophyllite, quartz, and damourite. The mineral association in the Chesterfield district. South Carolina, is, according to Genth,^^ pyrophyllite and cyanite. Unlike the occurrences of lazulite in the Carolinas and Georgi a 8 C. L. Hunter. Amer. Journ. Sci. 15: 376-377. 1853. J. L. Smith and G. J. Brush. Amer. Journ. Sci. 16: 370. 1853. C. U. Shepard. Am. Journ. Sci. 27: 36-39. 1859. F. A. Genth. Amer. PhiL Soc. 13: 367, 382, 383, 404-405. 1873. E. S. Dana. A system of mineralogy (1900), p. 799. G. F. Kunz. N. C. Gaol. Survey BuU. 12: 57. 1907. T. L. Watson and J. W. Watson. Univ. of Virginia. PubL BuU. Phil. Soc, Sci. Ser., 211-214 (No. 7). 1912. 9 A. F. Rogers. Sch. of Mines Quart. 33: 375. 1912. D. B. SterrETT. U. S. Geol. Survey, Min. Res. for 1911. Pt. II, p. 1060. A. S. Eakle. Calif. State Mining Bureau, Bull. 67: 162. 1914. i" For more details of foreign localities see E. S. Dana, loc. cit. 11 F. A. Genth. Amer. Journ. Sci. 18: 410. 1854. Oct. 4, 1921 abstracts: inorganic chemistry 391 the mineral is found in quartz veins in some of the California locali- ties, but its occurrence at Mono Lake in quartzite is similar to that in the southeast Atlantic states. Fewer minerals are associated with lazulite in the California localities, but those noted are also found in the southeast Atlantic states. In Green Lake Canyon, i- near Bodie, lazulite is developed in deep blue anhedra associated with quartz and muscovite in a quartz vein; and in Breyfogle Canyon, ^^ Death Valley, it is distributed as crystals and crystal aggregates of pale to fairly deep azure blue in patches through a white quartz vein cutting schist. At Mono Lake ^^ it is associated with rutile in bands in a white quartzite. ABSTRACTS Authors of scientific papers are requested to see tbat abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should con- form in length and general style to those appearing in this issue. INORGANIC CHEMISTRY. — The crystal structure of some carbonates of the calcite group. Ralph W. G. Wyckoff. Amer. Journ. Sci. 50: 317-360. 1920. By the same general method that has been employed in studying caesium dichloriodide and sodium nitrate, a unique solution has been obtained for the crystal structures of calcite and rhodochrosite. Of the assumptions commonly made in crystal-structure study, the only one required in this determination was that the atoms reflect X-rays in an amount roughly proportional to their atomic numbers. The structure of siderite was shown to be so nearly the same as that of rhodochrosite as to be indistinguishable by the means at hand. Magnesite was also found to give the same sort of pattern and hence to have the same general arrangement of atoms as the other members of the group. The positions of the oxygen atoms, as determined by the present method and by the spectrometer results, are compared. In this particular case, the "nor- mal" decline of intensities is in surprising agreement with the reflections. Evidence is obtained from these crystal structures to show the existence of groups of atoms, as carbonate groups, in the crystal. It is also pointed out that unless every atom in the crystal is electrostatically charged, the outside electrons of the atoms making up these crystals cannot be arranged at the cor- ners of cubes. Some connections are pointed out between the development of faces on cal- cite and its crystal structure, and a way is indicated of deciding the most prob- able indices of a plane when they are in doubt. The bearing of these struc- tures upon the question of what constitutes a series of isomorphous substances is mentioned. A criterion is suggested for determining, in the case of an hexagonal crystal, whether the fundamental unit is a rhombohedron or an hexagonal prism. " A. F. Rogers. Op. cit., p. 375. »» D. B. Sterrett. Op. cit., p. 1060. 1* A. S. EaklE. Op. cit., p. 162. 392 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 1() The use of gnomonic projection in studying Laue photographs is mentioned and a ruler is described, the use of which reduces the time and labor of making such projections. The effect of the voltage impressed on the X-ray tube upon the character of the Laue photograph is considered and the best conditions for operating a tungsten tube for this work are stated. R. W. G. W. PETROLOGY. — The rhyolites of Lipari. Henry S. Washington. Amer. Journ. Sci. 50: 446-462. 1920. Typical obsidians, pumice, lithoidal rhyolite, and a hyalo-dacite of Lipari are described, with six new analyses. As these rhyolites are regarded as typi- cal and have never before been completely analyzed, this work is of use in characterizing the type. The refractive indices of the obsidians and pumice are discussed. There is also given an analysis of an obsidian of the island of Milos, of which the refractive index was also determined. The data corre- spond well. This is compared with analyses of obsidian of Nisyros by Martelli. The observation is made that ferrous oxide dominates ferric oxide in the glassy forms of the same magma, while the converse is true of the crystalline forms in the Lipari rhyolites. The same holds good for the rhyolites of Sar- dinia and the pantellerites and basalts of Pantelleria, described some years ago by the writer. The possible relation of this to the magmatic gases in lavas is briefly discussed. H. S. W. GEOLOGY.— 7/z^ potash deposits of Alsace. H. S. Gale. U. S. Geol. Survey Bull. 715-B. Pp. 39, pis. 2, figs. 2. 1920. The discovery of potash in Alsace in 1904 broke the monopoly of the potash industry which since 1860 had rested with the producers in north-central Germany. The return of Alsace to France now divides the monopoly between two nations. The new field, although of less extent, is in some ways better than the older field ; the beds are very regular, and the salts average remarka- bly high in potash. The deposits, which were discovered accidentally in boring, underlie an area of 65 square miles beneath the valley of the Rhine in southern Alsace. They consist of two regular beds of sylvinite, a simple mixture of potassium and sodium chlorides, included in dolomitic grayish shale of middle Oligocene age. The writer believes that the beds were de- posited by evaporation in an inland salt-lake in the Rhine graben, which probably had no connection with the sea. Forste estimated the reserve of the field as 300,000,000 tons of pure potash, but by no means all of this can be recovered in mining. The crude salt mined in 1913 is reported as 350,341 tons, probably averaging 18 per cent in pure potash. J. D. Sears. GEOLOGY. — A deposit of manganese ore in Wyoming. Edward L. Jones, Jr. U. S. Geol. Survey Bull. 715-C. Pp. 3. 1920. One of the few manganese deposits known in Wyoming is on the western flank of the Laramie Mountains, near the head of Sheep Creek. The core of the Laramie Mountains is a coarse-grained red granite of pre-Cambrian age, but flanking it on the west side is a series of sedimentary rocks ranging in age from Carboniferous to Cretaceous. The manganese deposit is inter- bedded in limestone and sandstone of the Casper formation, of Carboniferous age. The ore consists of the manganese oxides manganite and pyrolusite, in mammillary crusts and nodular aggregates, and is unusual for its number of crystals. It is contained in two beds of chert a few feet apart, from which it is thought to have been derived by weathering and leaching. J. D. Sears. Oct. 4, 1921 abstracts: geology 393 GEOLOGY. — Some deposits of manganese ore in Colorado. Edward L. Jones, Jr. U. S. Geol. Survey Bull. 715-D. Pp. 12. 1920. Many deposits of manganese ore in Colorado have been described by J. B. Umpleby in 1917 and the Colorado Geological Survey in 1918. A number of other localities were examined by the writer in 1917; these are located in Gunnison, Hinsdale, Ouray, Dolores, Custer, and LaPlata Counties. Deposits of manganese ore in Colorado occur in sedimentary and igneous rocks ranging in age from pre-Cambrian to Tertiary. They are found in veins and brecciated zones; as replacement deposits; and as probably original bedded deposits. The veins and brecciated zones constitute by far the most numerous type of manganese deposits in Colorado, but economically they have proved of little importance. Replacement deposits of manganese ores occur principally in the oxidized parts of lead-silver deposits in the Leadville dis- trict, and of deposits containing zinc and iron sulfides in the Red Cliff district. A deposit of manganese ore which probably represents the oxidized and en- riched part of an original sedimentary bed occurs in sandstone and shale in western San Miguel County. The manganese ores are composed domi- nantly of the oxides pyrolusite, manganite, psilomelane, and wad, generally mixed with iron oxides. . J- D. Sears. GEOLOGY. — Deposits of iron ore near Stanford, Montana. L. G. Westgate. U. S. Geol. Survey Bull. 715-F. Pp. 8, figs. 4. 1920. The iron ores known as the Running Wolf hematite deposits lie just within the northern border of the Little Belt Mountains, in Cascade and Fergus Counties, Montana. A great series of sedimentary rocks, ranging in age from Algonkian to Cretaceous, rests unconformably upon Archean granite and gneiss. The deposits occur in tabular bodies in the Madison limestone (Carboniferous), at the contact with intrusive porphyry. The ore is a com- pact gray or reddish-gray hematite, which contains in places enough magne- tite to make it react to the magnet; it is not to any large degree limonitic at the surface. Development work has not gone far enough to make possible any estimate of the quantity of ore that can be mined, although several suggestive calcula- tions are included in the paper.- At the surface the ore body is of varying width, reaching a maximum of 50 feet. As it is a contact deposit in limestone, it will vary in dimensions from place to place according to the character and course of the solutions at work. The depth to which the ore extends below the surface is unknown. J. D. Sears. GEOLOGY. — Phosphate rock near Maxville, Granite County, Montana. J. T. Pardee. U. S. Geol. Survey Bull. 715-J. Pp. 5, pi. 1, fig. 1. 1921. The phosphate bed and its inclosing rocks are bent into several parallel, tightly squeezed folds that trend northward. The westernmost fold, a large syncline, is partly overridden by a huge mass of rock brought by thrust faulting from the west, and the strata that form the western limb of the syn- cline appear as if overturned by a force acting from the west. East of the syncline and beyond the area of the overthrust mass all the anticlines lean to the west as if they had been pushed over by a force acting from the east. Presumably the thrust acting from the west was the later. On the south the folds are lost in areas of faulted and intrusive rocks, and on the north, owing to a persistent pitch in that direction, they disappear beneath a cover of later rocks. As a result of the structure and erosion combined, the out- 394 JOURNAL OF THS WASHINGTON ACADEMY OF SClENCEvS VOL. 11, NO. 16 crop or surface trace of the phosphate bed forms a sinuous line that sweeps north and south, alternately bending sharply around the anticlines and synclines. One hundred million tons of phosphate rock are estimated in reserve, of which a considerable part lies above the natural drainage channels in situa- tions especially favorable for mining. J. T. P. VOIvCANOLOGY. — The Katmai region, Alaska, and the great eruption of IQI2. Clarence N. Fenner. Journ. Geol. 28: 569-606. 1920. A preliminary account is presented of observations made by the writer as geologist of the expedition sent in 1919 by the National Geographic Society, in cooperation with the Geophysical Laboratory of the Carnegie Institution of Washington, to the Katmai region, Alaska. The volcanoes of this region, which form a continuation of the Aleutian loop or festoon, are situated in an area of sedimentary rocks remarkable for the absence of folding or obvious faulting. The more recent lavas are basic andesites, contrasting greatly in composition with the highly siliceous rhyolite of the last eruption. It is believed that in the fumarolic area of the Valley of Ten Thousand Smokes the injection of a sill or closely similar body of magma into the under- lying strata at the beginning of the eruption caused shattering of the rocks above it, and these openings permitted the ascent of magma. The extrusion and inflation of this magma gave rise to a great ash-flow or sand-flow, analo- gous in many respects to the nuees ardentes of Pelee and La Soufriere, and also led to the formation of the parasitic cone of Novarupta. The fumaroles are thought to be due to the continued evolution of volatile constituents from this body of magma. The development of the new vent of Novarupta is ascribed to the enlargement of a channel along one of the fissures. The later extrusion of the stiff lava forming the dome of Novarupta is found to have been similar in many respects to that of the "spine" of Pelee. A study was made to determine the manner in which the top of Mount Katmai disappeared and the great crater-pit was formed. It seems quite certain that the material was not blown out directly, but must be accounted for otherwise. Crater subsidence may have been a factor, but it is believed that collapse of the crater-walls and incorporation of the material in the new magma were chief features. It is recognized that the latter process demands a large quantity of heat for its accomplishment, and the magma evidently was not at very high temperature prior to extrusion; therefore accessions of heat seem to be demanded. A considerable problem is thus presented, but it does not seem at all insuperable, and it is believed that the evidences of solu- tion are so strong that they cannot be disregarded. One of the important features of the eruption brings up for consideration a phenomenon to whose significance little attention seems to have been paid hitherto. It is that of a gas-charged magma gradually developing the explo- sive condition after some interval has elapsed subsequent to its ascent from the depths. The Katmai magma seems to have followed this com-se, and the phenomenon is apparently not uncommon. This is believed to have great significance and to imply changes of physical environment during its ascent, effected with such rapidity that internal readjustments were not able to keep pace with them. C. N. F. Oct. 4, 1921 proceedings : philcsophical society 395 ENTOMOLOGY. — The Dipterous genus Dolichopus Latreille in North America. M. C. Van Duzee, F. R. Cole and J. M. Aldrich. Proc. U. S. Nat. Mus., Bull. 116. Pp. 304, pis. 16. 1921. This paper is a revision of the North American species of the genus Doli- chopus. It is divided into three parts. The introduction by J. M. Aldrich gives a historical account of the genus and notes on the habits of certain species. The second part, entitled "Classification," by M. G. Van Duzee, occupies the largest portion of the work. In it 219 North American species, many of which are new, are described, the location of the types is stated and there is an account of material before the author. This section is in- troduced with a synoptic table of the species. The males are treated first and are divided into nine groups. The females are also tabulated, but do not fall into the same groupings as do the males. This is due to the unusual and peculiar secondary sexual characters of the males. The third part is by F. R. Cole and consists of considerably more than 217 figures illustrat- ing various characters of the species treated. Each species is assigned a number and when two or more figures are given for the same species they are given subletters of the species numbered. This division of the paper in three parts makes it appear that the new species are to be accredited to Mr. M. C. Van Duzee and no statement to the contrary is definitely made, but in the introduction it is implied that new forms should be accredited to the three authors. The present writer understands that such is the intention of the authors of this important and comprehensive work. S. A. Rohwer. ETHNOLOGY. — The Owl sacred pack of the Fox Indians. Truman Mich- ELSON. Bur. Amer. Ethnology, Bull. 72. Pp. 83, pis. 4. The greater part of this bulletin consists of a text in the language of the Fox Indians and a translation of the same setting forth the ritual connected with it, its history, and the benefits supposed to follow upon the performance of the ceremonies. Some linguistic notes on the text are appended and a list of stems fills the 12 concluding pages. It contains contributions to the study of Indian linguistics, sociology, and religion. John R. Swanton PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 851st meeting The 85 1st meeting of the Philosophical Society of Washington was held in the Assembly Hall of the Cosmos Club, May 7, 1921. It was called to order by President Faris with 30 persons present. The first paper, on The self contained base range finder and its errors, was presented by Mr. I. C. Gardner (by invitation) and was illustrated. Tlie self-contained base range finder is probably the most interesting and highly developed optical instrument employed in warfare. The range is determined by triangulation with the base of the triangle actually contained within the instrument. It follows that the angle of parallax which is measured is extremely small and must be measured with great accuracy. For example, with a one-meter instrument at a range of 5000 meters the angle is approxi- mately 40 seconds. The error of measurement for this angle must be less 890 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 16 than one second if an accuracy of 2 per cent in the determination of range is to be secured. To build an instrument which shall successfully attain this accuracy under service conditions and in the hands of men not thoroughly grounded in laboratory practice calls for the greatest refinement of optical and mechanical design. The errors to which a range finder is subject are of two kinds. The adjust- ment error is a systematic error which is constant, when measured in angular units, for all settings of the instrument and may be considered as correspond- ing to a bodily shifting of the entire scale of the instrument with respect to the index. An adjustment is provided for correcting this error in the field. The dispersion error is an accidental error arising from the inability of the observer to correctly determine precise coincidence in the field of the instru- ment. It may be either positive or negative and its distribution for a large number of observations may be expected to be in accordance with the ordi- nary frequency curve for errors. This error can be studied satisfactorily only by a laborious statistical method. A test has recently been completed at Fort Sill by the Ordnance Department with the cooperation of the Field Artillery and the Bureau of Standards which was represented by Mr. W. O. Lytle. Approximately 21,000 separate readings of range were taken by a group of average observers with 17 different instruments on a selected series of targets. The most probable value of the dispersion error was found to be of the order of 0.9 second. Much greater differences were found in the dispersion errors of the different observers than in those of the different instruments. This indicates that at present the selection and training of observers offers a much better prospect for an immediate and spectacular increase in the accuracy of range finding than does the careful selection of an instrument from those types now available. For the poorer observers the dispersion error was approximately twice that of the better. In other words the poorer observer requires a two-meter base range finder in order to obtain an accuracy equal to that of the better observer with the one-meter instrument. The paper was discussed by Messrs. Hawkesworth, Wright, Sosman, Humphreys, and Faris. The second paper, on The spectral distribution of energy required to evoke the gray sensation, was presented by Mr. Irwin G. Priest and was illustrated. The chief significance of this paper lies in the development and testing of an experimental method for determining an objective physical standard of "white light." The standard to be determined is the Planckian ("black body") distribution of energy required to evoke the hueless sensation of brilliance, commonly called "white" or "gray," under certain standard con- ditions stated in detail in the paper. The method of producing and adjusting the spectral distribution of the stimulus is this: Light from a lamp of known spectral distribution is modi- fied by rotary dispersion in a system of quartz plates and nicol prisms in such a way that by rotating one of the nicols the light emerging from it can be made to assume the spectral distribution of a Planckian radiator at any desired temperature between 4000° and 7000° K. Such a system is, in effect, a selec- tive light filter of adjustable spectral transmission. Two methods of observation were described: (1) The method of adjust- ment by trial, in which the observer himself adjusts the stimulus until he calls the sensation "white." (2) The method of answers, in which the opera- tor conducting the experiment adjusts the stimulus to correspond to certain fixed temperatures of the hypothetical Planckian radiator; and records the Oct. 4, 1921 proceedings: philosophical society 397 observer's reactions as "blue," "white," or "yellow," as the case may be. The second method proved to be the more satisfactory. Experimental results were given from four observers. The average results of these observers indicate that "white light" may be represented : (1) theoret- ically, by the light from a Planckian radiator at a temperature of about 5200° absolute; (2) practically, to a fair approximation, by average noon sunlight at Washington. It is, however, emphasized that the final establishment of such a standard should be based on a more extensive statistical investiga- tion. The paper was discussed by Messrs. Gardner, HawkesworTh, Faris, Burgess, Tuckerman, Sosman, and others. The complete paper is being published as a Bureau of Standards Scientific Paper. 852d meeting The 852d meeting of the Philosophical Society of Washington was held in the Assembly Hall of the Cosmos Club, May 21, 1921. It was called to order by President Faris with 36 persons present. The first paper, on Relation of coastal currents and winds on the Pacific Coast was presented by Mr. H. A. Marmer and was illustrated. This paper presented the results of an investigation of the speeds and directions of the current along the Pacific Coast of the United States brought about by local winds. The investigation was undertaken primarily for the purpose of aiding the mariner and was based on observations made under the direction of the Coast and Geodetic Survey by members of the crews of the five light vessels stationed along the coast from San Francisco Bay to the Strait of Juan de Fuca. The apparatus used for measuring the speed and direction of the current was necessarily the simplest, and consisted of a 15 foot current pole, a log line graduated to knots and tenths for a run of one minute, a stop watch, and a pelorus. The wind velocity was estimated in accordance with the Beaufort Scale. Since the current as observed is the resultant of a number of different cur- rents due to various causes, such as tides, winds, river discharge and differences in density, the observations are tabulated with reference to various arguments. Thus by tabulating with reference to time of tide at a nearby port for periods of 29 days, the tidal current is derived. This current on the Pacific Coast, off'shore, is of the rotary type, the direction of rotation being clockwise, and shows considerable diurnal inequality. The wind current is derived by tabu- lating the observations with reference to winds of particular velocity and direction; then by summing for each such wind a large number of observa- tions, the tidal-current may be considered as very nearly eliminated. In the present investigation the observations were tabulated with reference to winds from a given direction divided in groups covering a range of wind velocity of 10 miles. The results derived show that on the Pacific Coast at a distance of from 4 to 10 miles from the land, winds from 10 to 70 miles per hour will give rise to currents from ^ 4 of a knot to over a knot; and this current will set, not in a direction of the wind, but in a direction of about 20° to the right of the wind. This has an important bearing on navigation, since winds blowing parallel to the coast or even away from the coast may give rise to currents tending to set a vessel on shore. In the results presented for each of the light vessels the effect of fresh- water run-off at the light vessels stationed off San Francisco, Columbia River and 398 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 16 Swiftsure Bank was sufficiently large in some cases to change the direction of the current brought about by winds of moderate velocity from the char- acteristic deviation of 20 degrees to the right of the wind direction. But with increasing wind velocity the direction of the current approximated toward the direction of 20 degrees to the right of the wind. This paper, which was illustrated by lantern slides, will form part of a Special Publication of the Coast and Geodetic Survey, dealing with currents on the Pacific Coast, to be published in the near future. It was discussed by Messrs. LittlehalES, Faris, White, William Bowie, and Humphreys. The second paper, on New results concerning the diurnal variation of atmos- pheric electricity, was presented by Mr. S. J. Mauchly, and was illustrated. It has long been known that for any given locality the electrical potential difference between the ground and a point in the air, say 1 meter above ground (potential gradient), varies throughout the course of the day in an approxi- mately cyclical manner; also that the amount and nature of this variation is not the same for all localities ; that some localities have two maxima and two minima during a 24-hour cycle while others have only a single "wave." Although various authorities have assumed that the occurrence of the princi- pal minimum about 4 p.m. was a rather general characteristic for nearly all stations, Mache and Schweidler^ long ago pointed out that the phase angle of the 24-hour wave varied greatly from station to station while the phase angle of the 12-hour wave was approximately the same for nearly all the stations. The results of the observations made aboard the Carnegie since 1915, representing about half the Earth's surface, indicate that the average diurnal variation of the potential gradient at sea is of the single-wave type, i.e., most days show only one maximum and minimum. However, a much more significant fact is the indication that the time of maximum, or of mini- mum, is approximately the same over all the different oceans, occurring on a universal rather than local-time basis. Observations for the diurnal variation of the number of positive ions in the air, and also those for the variation of the electrical conductivity of the air due to its positive ions, indicate that in general both these quantities are, over all oceans, above average value during the day and below average value during the night. But in both cases the average range found was of the order of only 10 per cent of the respective mean values, while for the potential gradient the average range was between 30 and 40 per cent of the mean value. Thus it turns out, on the basis of the Carnegie diurnal-variation data now available, that the computed vertical current density due to positive ions (and probably the total current density) is also subject to a diurnal varia- tion in which a single wave predominates, whose chief maximum (or mini- mum) occurs approximately at the same universal time over all the ocean areas. Attention was directed to the fact that the diurnal-variation curves for the potential-gradient derived from the Carnegie observations are very similar to curves which represent the relative frequencies of the aurora borealis as observed at several stations and also to curves representing the diurnal dis- tribution of magnetic disturbances when all are referred to the same time basis. It was pointed out that owing to the non-coincidence of the Earth's magnetic axis with its axis of rotation, the time of daily potential-gradient maximum, as indicated by the ocean curves, corresponds approximately to ' H. Mach^ and K. v. SchwEidlER. Die Atmosphdrische Electrizitdl, p. 27 (Braunsch- weig, 1909). Oct. 4, 1021 proceedings: phii.osophicai, society 309 the time when the Earth's north magnetic pole, for example, is farthest from the sun. The actual times of maximum and minimum, however, appear to depend upon the positions of both magnetic poles and the fact that their longitude difference is not 180 degrees. These correlations support the assumptions of various investigators that the Earth's electric charge and re- sultant field may be very intimately related to an electric radiation from the Sun. A more complete summary will appear in the current volume of Terrestrial Magnetism and Atmospheric Electricity. The paper was discussed by Messrs. C. A. Briggs, White, and Humphreys. The third paper, on New relations between terrestrial magnetism, terrestrial electricity, and solar activity was presented by L. A. Bauer and was illustrated. Connections between sun-spot activity, disturbances of the Earth's magne- tism, earth-currents, and polar lights have been worked out by various in- vestigators. The recent severe magnetic disturbances and earth-currents which accompanied a week ago the remarkable sunspot activity and brilliant display of polar lights have drawn renewed attention to the relationships between these four classes of natural phenomena. The present paper shows that there is a fifth natural phenomenon — atmos- pheric electricity — with which an interesting and suggestive relationship with solar activity is exhibited. Owing to the many disturbances to which the atmospheric-electric elements are subject, as for example during cloudy and rainy weather, it has been difficult to establish the existence of definite varia- tions of the chief atmospheric-electric elements during the well-known sun- spot cycle of somewhat over 11 years than in the case of magnetic effects, earth currents, and polar lights. The new results found are based upon atmospheric electric data obtained chiefly at four European observatories between 189rS and 1910, the combined data, in the case of the potential grad- ient, thus covering about two sun-spot cycles. Recent observations on board the Carnegie indicate a decrease in the electric potential -gradient since 1017, when sun-spot activity was at a maximum. The following chief facts have resulted : (1) The Earth's average intensity of magnetism, as well as the strength of the normal electric currents circulating in the Earth's crust, suffers a diminu- tion during increased solar activity, i.e., the currents induced in the Earth during periods of increased solar activity are in general reversed in direction to the normal currents, the strength of these superposed currents increasing with increased solar activity. The diurnal range of the strength of the normal earth currents, as in the case of the diurnal range of the Earth's magnetic elements, increases with increased sun-spot activity. (2) The atmospheric potential gradient, or the deduced negative charge on the surface of the Earth, increases with increased solar activity, the range in the variation between minimum and maximum sun-spot activity being about 20 per cent. The electric conductivity of the atmosphere, on the other hand, shows but little, if any, systematic variation during the sun-spot cycle. Ac- cordingly, since the vertical conduction current of atmospheric electricity is derived from the product of the potential-gradient and the electric conductiv- ity, it is found that this vertical current increases in strength with increased solar activity. It would thus appear that atmospheric electricity, like ter- restrial magnetism, is controlled by cosmic factors. The results derived here may have an important bearing upon theories of atmospheric electricity. (3) Instead of using for short periods, as for example a month, the sun- 400 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO, 16 spot numbers direct for comparison with magnetic and electric variations, it is found that a more satisfactory measure of solar radiations and emana- tions affecting the Earth's magnetic and electric condition may be based upon the monthly range of sun-spot frequency, or upon some quantity indica- tive of the rate of change, or variability of sun-spottedness. (4) A discussion of the sun-spot data for the period of 44 years, 1876-1920, confirms the existence of an annual periodicity in sun-spottedness, the mini- mum occurring about the time (January) when the Earth is nearest the Sun, and the maximum occuring on the average in July, when the Earth is farthest away from the vSun ; the average difference between maximum and mimimum is about 6 sun-spot numbers. There would thus be given additional support to the view of planetary influence upon sun-spottedness. (5) The electric potential-gradient, on the average, for both hemispheres shows a minimum value in July and a maximum in January; the annual range is about 50 per cent. On the other hand, the Earth's magnetic energy, as well as the strength of earth-currents, show on the average a higher value during the summer months than during the winter months for the northern hemisphere. The paper was discussed by Dr. Humphreys. A more complete summary will appear in the current volume of Terrestrial Magnetism and Atmospheric Electricity. H. H. Kimball, Recording Secretary SCIENTIFIC NOTES AND NEWS Mr. Louis V. Dieter has resigned as bacteriologist of the Health De- partment of the District of Columbia. He had been with the department since 1909. Dr. Henry Gordon Gale, professor of physics at the University of Chi- cago, has been made chairman of the Division of Physical Sciences of the National Research Council, for the year ending June .30, 1922. Captain Anthony Francis Lucas, retired mining engineer, died at his home at 2.300 Wyoming Avenue on September 2, 1921, in his sixty-sixth year. Captain Lucas was of Montenegrin origin and was born at Trieste on September 9, 185.3. He was for a number of years an officer in the Aus- trian navy. He took an active part in the development of the oil and gas fields of the Gulf Coastal Plain, and was particularly interested in the geo- logical problems of the origin of petroleum and the origin of the salt domes of Louisiana and Texas. He was a member of the Geological vSociety and the Society of Engineers. Mr. J. E. Noble has been appointed bacteriologist of the Health Depart- ment of the District of Columbia. Dr. George B. Roth, pharmacologist with the Hygienic Laboratory of the U. S. Public Health Service, resigned in September to accept a teaching and research professorship at Western Reserve University, Cleveland, Ohio. Mr. Charles K. Wead, for over twenty years an examiner in the U. vS. Patent Office in the Class of Music, has resigned, and will reside at Ann Arbor, Michigan. Professor Charles E. Weaver, non-resident member of the Academy, has returned to the University of Washington at vSeattle to resume his work as professor of paleontology, after a leave of absence of three years in Central and vSouth America as geologist for the Standard Oil Company. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 October 19, 1921 No. 17 PHYSICS.— i4 furnace temperature regulator.''- Howard S. Roberts, Geophysical Laboratory, Carnegie Institution of Washington, (Communicated by Arthur L. Day.) In 1919 White and Adams described a temperature regulator for di- rect current resistance furnaces- in which the heating coil of the furnace was placed in one arm of a Wheatstone bridge and the heating current was varied by a motor-driven switch controlled by the galvanometer of the bridge. The switch opened or closed the circuit through a shunt around a fixed resistance in series wdth the furnace but outside the bridge. This arrangement causes the temperature of the source of heat (the platinum wire) to oscillate within rather nar- row limits at such a rate that the oscillations in the temperature of a body within the furnace are imperceptible. Regulators of the Wheatstone bridge type are particularly adapted to long narrow furnaces where the heating element covers nearly all of the surface of the cavity; their use obviates the need for plac- ing any part of the regulator within the furnace, and there is no ther- mal lag whatever between heater and regulator as there is where the regulator employs a thermocouple placed inside the furnace. The apparatus set up by White and Adams included a specially constructed galvanometer-relay, and it was with the primary idea of replacing the latter with stock apparatus that the present reg- ulator was devised. Incidentally, the choice of a different type of gal- vanometer has overcome one rather serious defect in their apparatus. DESCRIPTION OF THE REGUI^ATOR Figure 1 is a schematic diagram of the present regulator. It is intended for use with furnaces whose resistance when hot lies between 2.5 and 10 ohms, requiring not more than 15 amperes at 110 volts direct current. For heavier currents a different form of main relay is necessary. 1 Received September 2.3, 1921. 2 Phys Rev. 14: 1 !-l8. 1919. 401 402 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 The galvanometer A is essentially a millivoltmeter having a short contact arm or boom in place of the usual pointer, and two contact stops. It differs from the White-Adams instrument in that contact is made as soon as the boom reaches one or the other stop. B is an ordinary polarized telegraph relay, and C a "main line" telegraph re- lay. . The main relay C is operated by current taken directly from the line through the resistance coils Ri and Ro. It opens when its coil /' Fig. 1. — Schematic diagram of furnace temperature regulator. is short-circuited by the contacts of the polarized relay B. The gal- vanometer contacts are so connected that the movements of the galvanometer place the polarized relay B either in parallel with the main relay C or in parallel with 150-ohm resistance Ri. The opera- tion of the polarized relay, however, immediately short-circuits the par- ticular coil with which it has just been connected, thus stopping the flow of current through the contacts of the galvanometer. This arrangeinent was intended to prevent these contacts from be- coming welded together, but was found to be insufiftcient. There- fore, the secondary (low-voltage winding) 5 of a "bell-ringing" transformer was connected in series with the galvanometer, and the OCT. 19, 1921 ROBERTS: FURNACE REGULATOR 403 primary P connected through a "thermal lamp flasher" F to the battery corners of the bridge. The operation of the main relay C increases or decreases the current through P and induces a momen- tary surge of current through the coil of the galvanometer. The current is caused to pass through the primary P in such a direction that this surge causes a rather violent deflection of the boom away from the contact stop. The "lamp flasher" F also causes sudden changes in the current through P and corresponding deflections of the galvanometer, which occur independently of the movement of the relay. The violence of the deflection serves to make contact when the contacts have been brought together but have been prevented from touching by a chance accumulation of dirt. CYCLE OF OPERATION OF THE RELAYS In describing the various operations of the relays by which the regulator controls the temperature of the furnace we shall arbitrarily assume that a rise in the temperature of the furnace causes a movement of the boom of the galvanometer A toward the left; and that clos- ing the galvanometer contacts to the left sends a current through the polarized relay B in such a direction as to cause its boom to move over to the left-hand contact. At a given instant, let us say, the contacts of the polarized relay B are closed on the left; the main relay C is then short-circuited and open ; the current to the furnace is passing through the resistance Rz, being cut down thereby to its lower value, and the furnace is therefore cooling. As it cools, the boom of the galvanometer .4 moves toward the right, and when it touches the right-hand contact, completes a cir- cuit through the coils of the polarized relay B in parallel with the re- sistance Ri. This causes the armature of the polarized relay to start to move over towards its right-hand contact. The main rela}^ C is now no longer short-circuited, and closes, cutting out the resistance Rz. When the armature of the polarized relay reaches the right-hand contact it short-circuits Ri and thus stops the flow of current through its own coils and through the right-hand contacts of the galvanometer A . Since it is a polarized relay, its armature does not swing away from the contact, but remains pressed against it because of the action of the permanent magnetic field of the relay. 404 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 With the resistance R^ cut out, the temperature of the furnace rises and the boom of the galvanometer swings toward the left. ^Vhen it reaches the left-hand contact it completes a circuit through the polarized relay in parallel with the coils of the main relay C, and the armature of the polarized relay moves over to the left hand contact. This short circuits the coils of the main relay C, whose armature drops back and restores the resistance R3 to the furnace circuit. The action of the polarized relay B in short-circuiting the main relay C stops the flow of current through its own coils and through the left-hand contact of the galvanometer The furnace is now cooling, the relays are in their original positions, and the apparatus continues to pass through repetitions of the same cycle which differ only in the time element. DESCRIPTION OF THE REI.AYS, ETC. The galvanometer A, in this particular apparatus, was obtained from the Weston Electrical Instrument Company ; it has an internal resistance of about 50 ohms and a period of about ^/s second, and is provided with two fixed contacts and one movable contact, said to be of "iridium alloy." I have separated these contacts to allow room for the ballistic swing, caused by the bell transformer, so that they close at about plus and minus five millivolts. Experience has indicated that the instrument might better have a resistance as low as 10 ohms and a somewhat shorter period even if the sensibility were halved by the change. The contact buttons need to be cleaned about once a day, and polished with fine emery cloth, or a carborundum stone, about once a month. The polarized relay B of the ordinary telegraph or burglar alarm type is also provided with two fixed contacts. The coils are wound with Number 40 B. & S. gage (O.OS mm.) copper wire to a resistance of 2000 ohms in order to reduce the current through the galvanom- eter contacts. The main relay C is of the ordinary telegraph type, wound to a re- sistance of 150 ohms. It was found well worth while to replace the original silver contacts of this relay, as well as those of the polarized relay, with molybdenum. The bell transformer is of the size designed to operate an elec- tric bell from a 110-volt lighting circuit. The "thermal lamp flasher" is a device which depends for its oper- ation on the thermal expansion and contraction of a strip of metal OCT. 19, 1921 ROBERTS: FURNACE REGULATOR 405 wound with a heating coil connected in series with the lamp. A suitable contact is arranged to short-circuit the heating coil when the strip has expanded to a certain point, whereupon the strip cools and the contact opens. This particular model is mounted in a tube pro- vided with a lamp base at one end and a lamp socket at the other. For the present purpose, a 60-watt, 110-volt lamp flasher, with a lamp in it, is placed in parallel with another lamp. The effect on the gal- vanometer may be adjusted by changing from one size lamp to another. A satisfactory combination of lamps in the present apparatus is one which causes the flasher to complete about four cycles per minute. A satisfactory value for the resistance R3 is about V3 the resistance of the furnace. The rest of the apparatus consists of switches and resistance coils and need not be described. However, it may be per- tinent to point out that the resistance wire used in the bridge should be of constantan, advance, ideal, manganin, therlo or some other al- loy having a very low temperature coefficient of resistance ; that the resistance coils should have ample current-carrying capacity; and that where copper connectors are used in the bridge, these should be short and of large cross section. PRINCIPLES AFFECTING THE CHOICE OF A GALVANOMETER This discussion applies particularly to resistance furnaces having a wire resistor wound on an insulating tube and imbedded in a thin layer of insulating cement, both tube and cement, as well as the wire, being good conductors of heat. The heating element as a whole is surrounded by a thick layer of loose magnesia or other nonconductor of heat. With this type of construction, the difference between the average temperature of the wire and that of the tube amounts at high temperatures to several degrees and adjusts itself much more quickly to changes in the heating current than does the temperature of the tube. Consequently, if the heating current is alternately increased and decreased at short intervals the temperature of the heating wire will oscillate through a considerable interv^al,^ while that of the tube remains nearly constant. The average temperature of a point within the furnace depends, among other things, upon the average rate at which energy is sup- plied to the furnace. Since the regulator must choose between two rates over whose value it has no control, it can only obtain the de- 3 In the only case studied this interval amounted to at least 2° C. with a half period of about one second. 406 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 sired average value by adjusting the ratio of the length of time the one rate is being supplied to the length of time the other is being supplied. In the case of a galvanometer having mechanically operated contacts, the circuit may only be closed at particular instants sepa- rated by arbitrarily fixed time intervals. Consequently, the ratio referred to must be approximated by a fraction whose numerator and Time Fig. 2. Diagram to illustrate the periodic fluctuations in temperature of a furnace con- trolled by a galvanometer having mechanically operated contacts. denominator are integers. This may consume a considerable num- ber of time interv^als and allow considerable fluctuation in the tem- perature of the furnace tube. An attempt has been made to show this graphically in figure 2. The wavy line represents the excursions of an idealized galvanometer OCT. 19, 1921 ROBERTS: FURNACE REGULATOR 407 boom, while the strip between the parallel lines represents the zone in which the boom may lie without causing a movement of the switch. The black dots indicate the positions of the boom at the instants when the mechanically operated contact mechanism is depressed. The ratio of heating time to cooling time in the upper diagram is 13 :12 and there is a slow, cyclic variation in temperature extending over 25 of the equal time interv^als. In the lower diagram, where the ratio is 19:31, this slow variation is much less serious. Decreasing the time interval between the successive instants at which contact can be made \vould undoubtedly improve matters greatly, even if the period of the galvanometer could not be decreased."* The galvanometer with fixed contacts, as used in the present ap- paratus, is free from this restriction and may make contact at any time. Neither type of galvanometer follows the temperature of the heater very closely; the inertia of the moving coil causes a considerable lag which, however, seems to do no harm. The regulator has thus far been used only on direct current furnished by a battery or generator. The pulsating direct current furnished by a mercury arc rectifier causes the galvanometer to vibrate seri- ously because of the alternating current induced in the bell trans- former by the pulsations. Several plans have suggested themselves to make it operate on alternating current: partially rectifying the current with an aluminum cell; putting a 6-volt storage battery in series with the source of suppl}^; or making an alternating-cinrent galvanometer. In any case, it would be necessary to operate the bell transformer from a separate source of direct current, or to adopt some other scheme, such as rotating the galvanometer contacts, in order to prevent their sticking. The alternating-current galvanometer has seemed most hopeful and one is now under construction. Although the foregoing discussion has confined itself to discussing the regulator in combination with a particular type of furnace, there is nothing to prevent the same principles from being applied to other purposes, such as baths of oil or molten metal, or even gas fired fur- naces, since it is not necessary to use any part of the bridge as a heater. PERFORMANCE When it is used with platinum resistance furnaces at tempera- tures below 1250° C, this regulator has been found to maintain the '' A recent experiment indicates that this interval may be decreased to 'A second by a suitable design. 408 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 temperature constant within =t 0.1°C.for hours without any atten- tion. At higher temperatures the furnace cools slowly, 2 or 3° per hour at 1450°. This cooling, which is perfectly regular, is undoubt- edly due to slow changes in the furnace for the resistance of the heat- ing coil is held constant by the regulator. The cooling can be com- pensated for by an occasional manual adjustment of the slide wire contact on the bridge. 1070 1060 1600 jD. 13 s_ 0) a £ 0) 1050 iii» » »>• » Time -^0 Fig. 3. Curves to illustrate the performance of the regulator in the steady heating of the furnace to determine a melting point. In a particular experiment, a platinum wound furnace of the type described was being maintained by the regulator at 1269°. Its re- sistance at this temperature was 9.9 ohms. The galvanometer contacts were set to close at ± 5 millivolts, corresponding to a change of about ± 1° in the temperature of the heating wire. With the rheostat adjusted so that the times of heating and cooling were ap- proximately equal, and the current 10.0 and 7 . 3 amperes respectively, OCT. 19, 19lM parsoNvS and harper: engine r.\diators 409 the relays operated 59 times per minute. When one ohm more re- sistance was put in, causing the current to fall to 9 . 3 and 6 . 9 amperes, the relays operated 38 times per minute, and the temperature within the furnace fell only 0.1°. This change in the heating current cor- responded to a fall of about 6 per cent in the line voltage, about as large a fluctuation as is likely to occur in the voltage of a lighting circuit. ATTACHMENT FOR STEADY HEATING OR COOLING If the furnace is to be used in making heating or cooling curves, the adjustment of the regulator must be changed either continuously or by small, frequent steps. The slide wire of the Wheatstone bridge may be used for this, but it has been found more convenient to shunt the 75 ohm coil of the bridge with a rheostat giving steps of 10 ohms from 1000 to 2000 ohms, placed beside the potentiometer used for meas- uring the furnace temperature. A 10 ohm slide wire rheostat is in- cluded in the circuit and used as an alternate fine adjustment for work at constant temperature. Figure 3 is the heating curve obtained from the melting of a small sample of gold in calibrating a thermocouple. Curve I is the temper- ature of the gold; II, that of a thermocouple placed a little above it; and III, the resistance in parallel with the 70 ohm coil of the bridge. The heating curve, II, of the furnace is not linear, but it is smooth, and the cur\^e, I, furnished by the sample of gold is entirely satisfactory. A linear heating or cooling rate can be obtained by means of a sim- ple potentiometer connected in series with the galvanometer. TECHNOLOGY. — Radiators for aircraft engines.'^ S. R. Parsons AND D. R. Harper, 3d, Bureau of Standards. The technologic paper from which this article is condensed will describe the laboratory investigations relating to aircraft engine ra- diators which were conducted by the Bureau of Standards during the World War and in the two years immediately succeeding it. Indi- vidual reports covering many phases of the subject have been pub- lished previously in the technical series of the National Advisory Com- mittee for Aeronautics and in scientific and engineering journals. These reports, however, lack the systematic coordination, uniform terminology, and unified mathematical treatment which should ' Condensed from a forthcoming official publication of the Bureau of Standards, U. S. Department of Commerce. Comnmnicated by the authors with the permission of the Di- rector of the Bureau of Standards. Received September .24, 1921. 410 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 characterize a handbook on the subject. Moreover the problems which were investigated first because of their greater importance and which were the subjects of the reports published earliest, are for that reason not so well covered as is now possible because the later work threw much additional light upon matters not settled at the time of publication of the early reports. Accordingly, the present paper is much more than a reprint of earlier reports, being a complete revi- sion and recompilation of the material available. The special investigations reported included development of the methods of measuring air flow in radiator tubes ; experiments upon the effect of nature of surface upon air flow and upon heat dissipation from the surface of metal tubes to a high velocity air stream; experi- ments to ascertain the degree of turbulence in the air tubes of a radia- tor core; mapping of temperature distribution, axially and trans- versely, in the air tubes of radiator cores. In addition to recording these special investigations, the paper contains a full description of laboratory methods and instruments for those tests of radiator cores properly made in the laboratory both of physical properties and geo- metrical characteristics such as size and shape of air tubes and of water tubes. The work included laboratory measurements of cooling power, head resistance, and geometrical characteristics of over one hundred types of radiator core. These data are tabulated in an appendix and the performance characteristics of 66 types of core are given in graphical form. The general conclusions from these measurements and from the special laboratory experim.ents mentioned above are incor- porated into an exposition of the fundamental relations between the conditions under which a radiator operates, its characteristics of form and construction, and the properties which describe its performance. This portion of the designer's field is by no means the whole, however, and the paper does not treat the important considerations of stur- diness, ease of construction and repair, cost, form of design imposed by the structure of the aircraft, etc. The heat-dissipating power of a given type of core construction was found to be specified completely when the mass rate of air flow was specified. It makes no difference whether a given mass rate is obtained by high velocity and low density or low velocity and high density, a relation which was studied in some detail because of its significance in respect to behavior of aircraft radiators at high alti- tudes of flight. The empirical relation OCT. 19, 1921 PARSONS AND HARPER: ENGINE RADIATORS 411 (where H is heat dissipated per unit time per unit frontal area of core, M is mass of air per unit area per unit time through the air tubes of the core, and T is difference between the average tempera- ture of the water in the radiator and the temperature of the air at entrance to the core) was found to hold for all ordinary types of core construction, h and n being constants pertaining to any particular core. The numerical value of n was usually in the neighborhood of 0.8, indicating that the relationship between heat dissipation and air flow through the core of a radiator is not far from the relationship of direct proportionality, although too far to assume such a relation over any considerable range of air flows. A second equation for computing the cooling power of a core is H = CpMT (1 - e~""') where H, M, T have the significance quoted in the preceding para- graph, e is the logarithmic base 2.718, Cp is specific heat of air at constant pressure, Xi is the depth of the radiator core (dimension par- allel to air flow) and « is a constant for a given core and given air flow through it. Since a chosen value for a permits no latitude in air flow, or in changing core construction, the equation in this form is intended primarily for study of the effect upon cooling power of changing the depth of core. Giving due consideration to head re- sistance as a function of frontal area and depth, the formula permits computation of the optimum depth of radiator for given conditions. For very high speed flight, it is advantageous to use cores much deeper than was the common practice in early days of airplane development, 8 to 10 or 12 inches depth being desirable for some types of the usual quarter inch to half inch air tube core, in unobstructed positions. The formula just quoted is not entirely empirical in its origin, but has a rational basis. The assumptions underlying it are plausible and it is not surprising to find that in applying it to results of measure- ments with almost all common types of core these results are rep- resented very' well. The parameter a is an abbreviation for pq/MCp, where M and Cp have their former significance; p is total perimeter of the air tubes in unit frontal area, provided the cooling surface is all direct surface (and an equivalent value for the cases where part is indirect cooling surface) ; q is the cooling coefficient between the metal and an air stream of velocity corresponding to M, namely, q is heat transferred per unit time per unit area of metal per degree tempera- 412 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 ture difference between the metal and air flowing past it. The nu- merical values of q were found to agree very well with values com- puted from a formula given by vStanton and Lanchester: CpRf q. = V and by Lees / m V '' Rf = pV- [0.0765 \V^) + 0.0009] the comparison being made for radiator cores with smooth round and square and hexagonal air tubes, nearly all direct cooling surface. The formulas given were originally stated for long circular cylindrical tubes with smooth walls, Cp being specific heat of air at constant pres- sure, V the velocity of the air through the tube, p its density, and M its viscosity. Rj is the surface friction, or force per unit surface be- tween the air stream and walls of the tube, and D is tube diameter. The above formulas m.ay be combined into a single expression (making some reductions not given here in detail), so as to compute heat dissipation of a core from its dimensions, and for simple type regular cellular cores it seems highly probable that results will be reliable within 10 per cent. // = MCpT (1 - e"""') .., = ^ [o.047l(^^J"'V 0.0009] H = heat dissipated, units of power per unit frontal area of core, M — mass of air per unit time per unit frontal area, Cp = specific heat of air at constant pressure, T = temperature difference water and air entering core. Any consistent set of units whatever may be used for the above four quantities, but care must be exercised to avoid any inconsis- tencies; i.e., the heat units for H and Q must match, the mass units for M and Cp, the area unit for H and M, etc. The same is true for the following sets of quantities, although the units for these need not be the same as the first set. Xi = depth of radiator core, in same units as f, r = hydraulic radius of air tube (quotient of area by perimeter) , M = mass of air per unit time per unit frontal area, p. = viscosity of air in a unit consistent with M and r, a = free area of core ; the ratio of the total cross section of the tubes to the frontal area. (Being a ratio it is independent of units.) OCT. 10, 1921 PARSONS AND HARPER: ENGINE RADIATORS 413 The laboratory measurements of heat-dissipating power were made with two sources of heat, steam and hot water. For superheated steam, the effective temperature is computed by weighting properly the heat derived in each stage (loss of superheat, condensation, cool- ing of water) : T (^ + 1) CpS + T,L CS + L where T^ is mean effective temperature, T^ is temperature of con- densation, 5 is superheat (in degrees), L is latent heat of condensa- tion and Cp is specific heat of superheated steam. The condensate was usually not cooled significantly below the temperature of conden- sation and the formula above is in the simplified form resulting from neglecting such cooling. An intercomparison of test data on ten cores, using both superheated steam and hot water as sources of heat for the calorimetric measurements, showed that no appreciable difi'erence existed between the results obtained by the two methods. A series of measurements using water as the source of heat were made with the rate of water flow varying over a wide range. As might be ex- pected, a wide range of variation of heat dissipation occurred with change of rate of water flow when the rates were extremely low, but at the rates of flow common in radiator use, the effect was not significant. It seems safe to assume that heat dissipation for con- ditions all constant except rate of water flow will attain a value within 5 per cent of the maximum which it will reach with any rate of flow, if the rate be as much as 3 gallons per minute per inch depth of core 1 foot wide. This flow is well within the margin of circulation found in most aircraft cooling systems. The effectiveness of indirect cooling surface, namety, cooling sur- face not backed by flov^ring water, is considered in detail and the math- ematical relations are developed which describe its behavior. The eft'ectiveness of indirect surface is defined as the ratio of its heat- dissipating power to that of an equal area of direct cooling surface all at the temperature of the edge of the indirect surface which has contact with the source of heat. For long narrow fins such as the in- direct cooling surface found in a square cell or hexagonal cell con- struction, the effectiveness is _, tanh U 414 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. U, NO. 17 where U takes the form ^ yk b is the width of fin where good thermal contact- occurs along one edge of the fin only, and is half the fin width where good thermal contact is made by both parallel edges. The fin thickness is y and the thermal conductivity k, the quantity q being the surface heat dissipation coefficient in units consistent with k and the dimensions b and y. For the combinations of values usually occurring in radia- tor practice, the effectiveness exceeds 70 per cent and quite commonly averages 85 per cent to 95 per cent. The formula was applied to calculate optimum dimensions for fins under various conditions, the results being tabulated. The equations of thermal conduction are also used to compute a table of temperature drop through water- tube walls of various thickness and materials. A considerable amount of detail not suited to abstracting is to be found in short notes on such topics as effect of yaw on performance, slipstream mountings, wing radiators, shuttering, radiator require- ments at altitude and methods of computing performance at alti- tude from test data obtained at ground level. A brief treatment is included of the subjects of partially streamlined casings to enclose a radiator, and of nose mounting. From the point of view of an airplane designer, it is desirable to specify radiator performance in terms of flying speed of the plane. In general this cannot be done directly because too many factors are involved in the relation between flying speed and the air flow through the radiator core. It becomes necessary, therefore, for describing characteristics of the radiator, to adopt air flow through the core as the prime variable, there being no other quantity or entity available for the purpose. The ease or difficulty of applying such a description of performance to plane design rests then with the difficulty in esti- mating the probable air flow through the core for given flying speed. For a radiator mounted in an unobstructed position the difficulties are inappreciable, the estimation process is replaceable by actual measurement and the results are obtainable with satisfactory accuracy. For a nose mounting, or other obstructed position too many factors enter into the determination of the air flow to make generalizations possible. Consequently, the authors are unable to include in the paper material ^ Soldered or integral rnetal. Mere contact, unsoldered, of two pieces o[ metal is ther- mally a discontinuity. -OCT. 19, 1921 PARSONS AND HARPER: ENGINE RADIATORS 415 of direct application, without any intervening step, for the nose ra- diator, a mounting which is today probably the most common in American practice. The designer who is interested in such a mount- ing must first secure a measurement or estimate of the air flow to be expected in the core of his radiator, taking into account the size and shape fuselage, engine, propeller, and all the objects which will de- termine this air flow, and then with such data in hand he can apply all the results of this paper. The paper is carried one step beyond expressing radiator perform- ance in terms of air flow through the core, and states the results of the measurement in terms of flying speed for a mounting in an un- obstructed position. Comparative performance is stated in terms of figure of merit which is the ratio of the power dissipated as heat to the power required to sustain the weight of the radiator and overcome its head resistance in pushing it through the air. The relative fig- ures of merit of two cores in an unobstructed position do not, of course, furnish an index of value in an obstructed position. The compara- tive behaviors of various classes of core are discussed in some detail for the unobstructed position and it is shown that for this mounting and high speed of flight, the flat plate core construction has a figure of merit sufficiently above other types to deserve attention. Its chief disadvantage is inherent mechanical weakness, a feature of extreme importance in selecting a design for use, and the data presented should afford the designer definite information regarding the sacri- fice in figure of merit which must be balanced against increased stur- diness, when choosing between types of core. For flying speeds of 60 to 200 miles an hour' it seems certain that an unobstructed radiator plus a streamline nose to the fuselage offers a figure of merit so much above that of a nose radiator installation as to justify considerable effort toward overcoming the structural difii- culties attendant upon such a mounting. The measurements made on a very wide range of variety of cores indicate that vaneS, holes in the air-tube walls, and all devices intended to ncrease turbulence in the air tubes are detrimental to radiators in an unobstructed position, lowering the figure of merit for a given flying speed. The effect is to decrease the air flow more than is compensated by the increased heat-dissipating power at a stated rate of air flow. On the other hand, in obstructed positions, where the air flow is determined more by the radiator surroundings than by its own core construction, the cores with turbulence devices 41G JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 may be advantageous. For regularly shaped cellular tubes, with straight walls, parallel to the wind, and with no vanes or holes, an empirical formula was developed which was found to express air flow through the core in terms of flying speed, with a surprising de- gree of accuracy : M — 10 ^ ) ni = a [1 where r is hydraulic radius of an air tube (quotient of cross section by perimeter) and % is depth of the core (length of an air tube) , both these dimensions being measured in the same unit of length; a (the free area of the core) is the ratio of the total cross sectional area of the air tubes in a given frontal area to that frontal area; m is the air flow constant, the fractional part of the air flow approaching the core which passes through it, hence, unity minus the fractional part deflected around the core. In a wind stream of 5 pounds per second per unit area, a core of unit frontal area which transmitted 3 pounds of air per second and deflected the other 2 around it, would have an air flow constant of 0.60. The presence of headers or water boxes would modify the direct application of the formula to a radiator since the formula is for a core alone, but with the exercise of suitable judg- ment in making an allowance for water boxes and connection piping, it should be possible, from the geometrical characteristics of a simple core, to compute with a satisfactory degree of accuracy the air flow which would correspond to any stated flying speed with the core in an unobstructed position. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. The abstracts should con- form in length and general style to those appearing in this issue. GEODESY. — Radio-compass bearings. Oscar S. Adams. U. S. Coast and Geodetic Survey vSpec. Publ. 75. (Serial 167.) Pp. 39. 1921. The radio-compass is coming into very general use for the determination of the positions of vessels at sea. For this reason, it seemed advisable to investigate the methods of plotting bearings thus obtained, both on the Mer- cator projection and on the gnomonic projection. In investigating the subject it is sufficiently exact to consider the earth as a sphere. It is further as- sumed that the path of the wireless wave over the surface of the earth is a great circle, joining the position of the vessel with that of the radio-compass station. A straight line on a Mercator projection represents a rhumb line and not a great circle. A great circle on this projection is represented by a curve OCT. 19, 1921 abstracts: physics 417 which is concave towards the equator. If an observed bearing is laid down upon such a projection without correction, the line so determined is a tangent to the great circle curve at its point of origin, because the Mercator projec- tion is conform al. This publication gives a mathematical derivation of the correction that must first be applied before the bearing is plotted on the projection. A practical method is then devised so that the required cor- rection may be determined by means of three graphic charts with as small an amount of effort as possible. For convenience in application the description of the practical use of the method is given first in the publication and the theoretical discussion is given in the final part of the same for the benefit of those who may be interested in this phase of the matter. A Mercator projection table for the sphere is also included as it is of use in connection with the graphic charts, one of the arguments for the same being obtained from it. On the gnomonic projection a great circle is represented by a straight line, but the angle at the station is not preserved. It is necessary then for any particular gnomonic chart to have a table computed for each radio- compass station that gives the angles that must be laid off on the projec- tion in order that the straight line may represent the great circle with any given observ'ed bearing upon the earth. In this publication, tables are given for ten radio-compass stations along the eastern coast of North America, based upon the U.S.Hydrographic Office Chart No. 1280. O. S. A. PHYSICS. — The annealing of glass. L. H. Adams and K. D. Williamson. Journ. Franklin Inst. 190: 597-631, 835-870. 1920. (Geophysical Lab. Papers on Optical Glass, No. 32.) It is shown that the process of annealing glass can best be carried out if we know for the various glasses and for the various temperatures the rate of release of the internal stresses. The results of such measurements for nine kinds of glass are presented. The release of stress at constant temperature was found to proceed usually according to the equation F Fo in which F is the stress at any time, t, F^is the initial stress, and .4 is a constant for the particular glass at a particular temperature, and is a measure of the rate at which stresses are relieved. The variation of this rate with tem- perature follows the equation log A = Mid — Ma in which Mi and Mo are constants for a particular glass and 6 is the tempera- ture. At any temperature, a glass requires a certain annealing-time. This is arbitrarily defined as the time required to reduce the stress (in optical units) from 50 to 2>^ nn per cm. For convenience of reference, the 150° interval of temperature lying immediately below the temperature at which the anneal- ing time is 2 minutes is called (also quite arbitrarily) the annealing range. At temperatures below the annealing range as thus defined, very little perma- nent stress can be introduced. Concrete directions are given for annealing optical glass. The procedure to be followed for other kinds of glass, such as plate glass, bottles, chemical glassware, etc., is also indicated. Mathematical analysis of the problem shows 418 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 that the best method for annealing requires that the glass be held at constant temperature (below the customary annealing point) for the appropriate time and then cooled at an increasing rate. It is of interest to note that the larger the piece of glass the lower the annealing temperature. Finally, there are presented a number of equations which are convenient for calculating the internal stresses due to heating or cooling solids of various shapes. While the original object of this investigation was to put on a quantitative basis the operations connected with the annealing of glass, it was found that many of the results have an important bearing on certain problems of geo- physics. Thus, for example, the relief of internal stresses in glass probably belongs in the category of elastico-viscous flow and is thus connected with such processes as the tidal deformation of the earth's crust. Moreover, the for- mulas expressing the relation between temperature-differences and stress distribution are directly applicable to the phenomenon of the "jointing" of rocks. L. H. A. and E. D. W. GEOLOGY. — Oil possibilities in and around Baxter Basin, in the Rock Springs uplift, Sweetwater County, Wyoming. Alfred Reginald Schultz. U. S. Geol. Survey Bull. 702. Pp. 107, pis. 17, figs. 9, inserts 3. 1920. The data for this report were collected in 1907 and 1908 while the area involved was being mapped for its coal resources, and are now made available to meet the demand for information about oil and gas resources. As a consequence the report lacks the detailed information, especially the structure contour maps, usual in reports on this subject, but makes up for that de- ficiency by the fullness of the information on larger structural features, stratigraphy, oil shales, oil and gas bearing formations, etc. that is brought together for this and surrounding regions. Drilling for oil and gas was active in the Baxter Basin about 1900 but yielded mainly small amounts of gas. A recent revival of drilling had at the time of the report also struck mainly moderate flows of gas and little oil. Land surveys and geography are briefly discussed, and water supply somewhat more fully. In general water supply is poor except that available from deep artesian sources. Sixteen pages are given to a discussion of stratigraphy with detailed description of the principal exposed units which extend from the Baxter shale near the base of the Mon- tana to the Eocene-Green River formation. Valuable correlation tables bring out the naming and subdivision of the entire section down to the pre-Cambrian at various times in this and adjacent areas. Twelve pages devoted to structure in conjunction with the geological map define the prin- cipal lines of folding, faulting, and overthrusting and their relation to the adjacent Uinta Mountains. Fifty-foot structure contours on the Rock Spring anticline are the only ones on the map, and it is only in relation to this structure that the possible localization of oil or gas accumulations is disscused. A conspicuous feature of the report is the general review of the oil shale situation. In the area under discussion oil shale occurs in two portions of the Green River formation. Very full sections of this formation bring out the position of the oil shales ; and the character of the beds, their oil content and so forth is discussed. A brief review with map shows the known reserves of oil shale in Wyoming, Colorado, and Utah. There follow 13 pages of discussion of the beds from the lower Montana to the Cambrian that might be reservoirs or sources of oil. The discussion is based mainly on evidence from adjacent areas and is accompanied by a valuable table showing the beds that yield oil and gas in various surrounding Rocky Moimtain fields. The OCT. 19, 1921 abstracts: geochemistry 419 remaining 21 pages of the bulletin are given to a rather detailed account of previous drilling in or near Baxter Basin, that is, mainly on the Rock Springs dome, with brief discussion of the beds that would probably yield oil and of analyses of oils from nearby fields. The author believes that the Frontier sandstones and the Aspen formation, both of which are at the base of the Upper Cretaceous and which in most of the area would be reached at depths of from 2U00 to 4U00 feet, will prove to be the principal oil-producing beds. Marcus I. Goldman. GEOLOGY. — Coal in the middle and eastern parts of San Juan County, New Mexico. Clyde M. Bauer and John B. Reeside, Jr., U. S. Geol. Survey Bull. 716-G. Pp. 82, pis. 19. 1921. This report describes briefly the geography and geology of San Juan Coimty, New Mexico, and in detail the coal deposits of the middle and eastern parts. The geologic section includes 9 formations assigned to the Upper Cretaceous and 4 formations assigned to the Eocene. Coal occurs in 2 Upper Cretaceous formations — the Menefee formation of the Mesaverde group and the Fruitland formation. The coal beds of the Menefee formation are in 2 groups, one in the lower part of the formation and one in the upper part, with a barren interval between. Individual beds are lenticular and very variable in thickness and composition. The coal beds of the Fruitland formation are usually grouped in the lower part of the formation and are more persistent and thicker than those of the older jMenefee formation. The number of beds and the quality of the coal decreases from north to south. The coal of both formations is of bitu- minuous rank in the northern part and of sub-bituminous rank in the southern part of the county. The total quantity of coal is large but under present conditions will be developed for local use only, J, B. R. GEOLOGY. — The iron-ore resottrces of Europe. Max RoeslER. U. S. Geol. Survey Bull. 706. Pp. 152. 1921. This bulletin, which is the outgrowth of a report compiled by the U. S. Geological Survey for use at the Peace Conference, is the result of the study of a wealth of literature by many writers in many languages. The author has attempted to reduce the available information to nearly common scale, and to present briefly the distribution, character, and extent of the deposits in the various countries of Europe. The graphic review of the deposits is preceded by a brief sketch of the nature and geology of iron-ore deposits in general and a few notes on the methods of utilizing the ores. The production and consumption of the principal countries is given. The report contains many maps and diagrams and an extensive bibliography. R. W. Stone. GEOCHEMISTRY. — Chemical researches on sediments. H. E. Merwin. Bull. Geol. Soc. Amer. 31: 419-424. 1920. A general discussion of various phases of the chemical problems connected with the study of sedimentary rocks. The problems are difficult because of the complexity of the chemical solutions, the small solubility and lack of definite crystallinity of many of the substances, and the persistence of unstable phases. Diffusion in the solid state, consolidation under difi"erential stress, adsorption, slow reactions, and effects of catalysis are discussed both in general terms and in their relation to the formation of dolomite and phosphate rocks and the oceanic red clay. H. E. M. 420 JOURNAL OF The; Washington academy of sciences vol. 11, no. 17 GEOCHEMIvSTRY.— T/ze chemistry of ike Earth's crust. Henry S. Wash- ington. Journ. Franklin Inst. 190: 757-815. 1920. The number of essential rock-forming minerals is very small. They are mostly silicates of Al, Fe, Mg, Ca, Na, and K. Any two or more of these minerals (with two exceptions) may occur together and in all proportions. The chemical characters of igneous rocks are summarized in the paper and the ranges and maxima of the various constituents are given. The average igneous rock is considered and, after some discussion of the sources of error in- volved in the calculation, a new average (based on 5179 analyses) is given. The average rock is shown to be approximately a granodiorite. The average composition of the Earth's crust in terms of elements is also given. Twelve elements (O, vSi, Al, Fe, Ca, Na, K, Mg, Ti, H, P, and Mn) make up 99. Gl per cent of the crust. The elements are referred to two main groups in the periodic table: (1) the petrogenic elements, characteristic of and most abundant in igneous rocks, of low atomic weight and occurring normally as oxides, silicates, chlorides, and fluorides; (2) the metallogenic elements, rare or absent in ig- neous rocks, but occurring as ores, of high atomic weight, and forming in nature metals, sulfides, arsenides, etc., but not oxides or silicates. The suggestion is made that beneath the silicate crust of petrogenic elements is a zone essentially of nickel-iron, and beneath this a central core of the metallogenic elements. This vertical distribution is in accord with Abbot's views as to the distribution of the elements in the Sun. In igneous rocks and minerals the elements show a correlation, in that certain of them are prone to occur with others, and a similar limited correlation is apparently true of the animal and vegetable kingdom. The idea of "comagmatic regions," that is, the distribution of igneous rocks in regions of chemically related magmas, is discussed, and some of these are briefly described. The calculation of rock densities from their chemical composition is dis- cussed, and the average chemical compositions and densities of the conti- nental masses and oceanic floors are given. It is shown by these that the average densities of the continents, ocean floors, and various smaller regions of the earth stand in inverse relation to their elevations. The bearing of this relation of average density and elevation on the theory of isostasy is pointed out, and it is shown that the data presented are confirmative of the theory. H. S. W. VOLCANOIvOGY.— Two gas collections from Mauna Loa. E. S. Shepherd. Bull. Hawaiian Volcano (3bs. 8: 65-67. 1920. Through the courtesy of Dr. T. A. Jaggar, Jr., of the Hawaiian Volcano Observatory, two tubes of gas were received which he collected in November 1919 from the flow on Mauna Loa. These are the first gases collected at this volcano. Dr. Jaggar had great difficulty in finding a suitable source for collecting, and greater difficulty in approaching it. The analysis of the gases accounts for part of the difficulty, since they show 2 and 8 per cent of vSOs respectively. The combustible gases had practically all disappeared and the samples may be regarded as completely burned. It wi.l be noted, however, that the amount of nitrogen present is not high and could not possi- bly account for the amounts of water present, namely, 67 and 75 per cent respectively. The argon group is present in rather larger amounts than at Kilauea, but amounts to a maximum of only 0.6 per cent. Free sulfur and chlorine were absent. Compared with similarly oxidized gases from OCT. 19, 1921 proceedings: geoi.ogical society 421 Kilaiica, the Loa gas seems entirely similar in composition. The analyses, in A^olume per cent at 1200° and 760 mm., are given in the table below. CO-. 3.84 0.42 CO 0.03 0.19 Ho 0.01 SO. 1.22 1.95 SO3 2.08 8.12 S2 CI2 N2 16.80 15.39 A 0.58 0.42 H2O 75.44 67.43 E. S. S. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES GEOLOGICAL SOCIETY 342d meeting The 342d meeting of the Geological Society of Washington was held at the Cosmos Club at S p.m., on Wednesday, January 28, 1920. Regtilar Program G. R. Mansfield: Types of structure in Southern Idaho. (Illustrated.) F. E. Matthes: Physiographic history of the Yosemite region. (Illustrated.) W. Taylor Thom, Jr. : The structttre of the so-called Poplar Dome in north- eastern Montana. 343d meeting The 343d meeting was held at the Cosmos Club at 8 p.m., February 11, 1920. Informdl Comnmnication Laurence LaForge spoke on the correct use in physiography of the terms mature and maturity. Regular Program H. W. Cornell: Constitutional questions involved in the statutory classifica- tion of mines and minerals for purposes of taxation. ]M. R. Campbell: Abandoned meanders of James and Potomac Rivers and their bearing on Coastal Plain history. special meeting A joint meeting with the Washington Academy of Sciences was held in the auditorium of the Cosmos Club at 8:15 p.m. on Thursday, February 19, 1920. The occasion was a lecture V>y Alfred H. Brooks on The appli- cation of geology to war. An abstract of the lecture has been published with the Proceedings of the Academy in this Journal.^ 344th meeting The 344th meeting was held at the Cosmos Club at 8 p.m., on Wednesday, March 10, 1920. ' This JouR.v.\L, 10: 331-333. 1920. 422 JOURNAL OF THK WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 Informal Communications David T. Day spoke on some substances extracted from oil shale. R. C. Wells spoke on a deposit of aragonite on the inside of a sealed glass tube containing a standard sample of sea water. This commimication has since been published in the Journal.^ Regular Program F. C. Calkins: Thrust fatilting in the Cottonwood District, Wasatch Moun- tains, Utah. The thrust faults discovered in the Cottonwood district during 1912 by Loughlin and Butler and independently by Hintze dip in general eastward and hence were naturally supposed at first to have been caused by westward over- thrusting. Recent field study, however, has brought out the following facts : (1) The main thrust plane dips westward in part. (2) The eastward dip is in places steeper than it could have been at the time the thrust-faulting occurred, so that some eastward tilting must have taken place; this tilting may well have sufficed to reverse an original low dip to the westward. (3) Most of the drag folds associated with the thrust faults indicate an eastward drag. It is therefore believed that the overthrusting was mainly eastward though a little westward thrusting may have taken place later. The Cottonwood district lying at the intersection of the Wasatch and Uinta axes and affected by the stresses that caused the birth of both ranges is a favorable place for determining the position of the overthrusting in the his- tory of the region. The order of the early events in that history is believed to be as follows: At the close of the Mesozoic the site of the Great Basin, instead of beinef depressed relatively to the region at the east, was largely dry land, and the site of the Wasatch and Uinta Mountains formed part of an area of sedimen- tation. Deformation of the ofi"-shore sediments began with "Wasatch" fold- ing on north-south axes. This was followed by thrusting of the land mass over the lower basin at the east. Further movement in the same sense caused the thrust faults to be bent into folds whose axial planes lean eastward. The east-west uplift which gave rise to the Uinta Range, and which was ac- companied or closely followed by the intrusion of granitoid rocks under the crest of the Uinta arch, was antedated by the overthrusting and probably by most of the north-south folding that affects the thrust planes. The thrust- faulting can therefore hardly be more recent than the end of the Cretaceous Sidney Paige : Interpretation of the Moon craters. Kirk Bryan : Mountain pediments. A discussion of the erosion of desert ranges. 345th meeting The 345th meeting was held at the Cosmos Club at 8 p.m., on Wednesday, March 24, 1920. Informal Communication Mr. David White exhibited some highly polished chert pebbles found in residual clay of limestone in Missouri. Regular Program Leon Dominian: Geography of Asia Minor. (Illustrated.) H. S. Washington: The chemistry of the Earth's crust. (Illustrated.) This paper has been published in full.* 2 R. C. Wells. This Journal, 10: 249-254. 1920. »H. S. Washington. Journ. Franklin Institute. 190: 7.57-815. 1920. OCT. 19, 1921 proceedings: geologicaIv society 423 346th meeting The 34Gth meeting was held at the Cosmos Club at 8 p.m., on Wednesday- April 14, 1920. Info rm al Communica tion Dr. G. R. Mansfield showed some enlarged photographs of grains of glauconite from the glauconite-bearing deposits of New Jersey, showing the characteristic forms and microstructure of the grains. Regular Program J. S. Brown: Fault features of the Salton Basin, California. (Illustrated.) Salton Basin is in the southeastern corner of California. Its lowest point, now covered by Salton Sea, is 273.5 feet below sea level. The basin is flanked by mountain ranges on the southwest and northeast, but at the southeast it opens toward the Gulf of California, from which it is separated by the delta of Colorado River which is only 50 feet above sea level. The basin floor is a desert plain covered at some places by large sand dunes. At many places the basin is bordered by badlands. The stratigi'aphy consists essentially of three groups: (1) Pre-Tertiary crystalline rocks, chiefly Paleozoic and Mesozoic, which underlie the basin and compose the surrounding mountains. (2) Soft, saliferous sandstone and clay beds of late Tertiary age, usually folded, exposed in the badlands. (3) Quaternary alluvium, generally undisturbed, forming the basin floor. Salton Basin is generally conceded to be a graben. Numerous faults have been traced to its borders, the most notable being the San Andreas rift, which extends to the northwestern tip of the basin. Topographic and geo- logic evidence adduced by the writer indicates the existence of a fault 50 miles long between the Tertiary of the badlands and thepre-Tertiary crystalline rocks northeast of Salton Basin. The name Indio fault is suggested. The Indio fault probably is a continuation of the San Andreas rift. Southwest of Sal- ton Basin two systems of faults are distinguished whose intersections are re- lated to the mountain spurs that project into the basin. These faults have dis- turbed the pre-existing drainage and created a number of isolated mountain- walled valleys. All the faulting observed is of the normal type. The fault- ing that shaped the basin began before late Tertiary time, but has progressed more or less continuously to the present day, as evidenced by movement along certain faults in recent earthquakes. A. E. Fath: Origin of the faults, anticlines, and buried ''Granite Ridge'' of the northern part of the Mid-Continent oil and gas field. (Illustrated.) J. B. Mertie, Jr.: The Salt Chuck palladium mine near Kasaan, Alaska. 347th meeting The 347th meeting was held at the Cosmos Club at 8 p.m., on Wednesday, April 28, 1920. Regular Program. David G. Thompson: Pleistocene lakes along Mohave River, California. . Mohave River is a typical desert river. It rises in the San Bernardino Mountains in southern California, and flows north to Barstow, thence northeastward along the Los Angeles and Salt Lake Railroad. Except in the mountains its channel is dry for many months at a time. Near the sta- tion of Baxter the river emerges from a canyon and spreads over a large alluvial fan, distributar}^ channels carrying the flood water to playas in two separate closed basins, where it disappears by evaporation and absorption. 424 JOURNAL OV THE WASHINGTON ACAD13MY OF SCIENCES VOL. 11, NO. 17 Lake cliffs and terraces and beach ridges show that a perennial lake once occupied the largest basin which is now occupied by two playas called Silver Lake and Soda Lake. The maximum depth of this ancient lake, which may be called Lake Mohave, was about 40 feet and the area about 75 square miles. A small but distinct channel at the north end shows that it overflowed toward Death Valley. Evidence of another ancient lake, much smaller than Lake Mohave, was found recently in the second basin, which is now occupied by a playa called Cronise Lake. The name Little Mohave Lake is suggested for this lake. Buwalda has described Manix Lake that existed in the Pleistocene along Mohave River about 25 miles upstream from Little Mohave Lake. No evidence has been obtained as to the relative ages of these lakes. At present the flood run-off of Mohave River from the San Bernardino Mountains is the only important factor in flooding the playas in the Lake Mohave Basin. Under similar conditions in Pleistocene time, if the ancient Mohave River followed approximately its present course, after Manix Lake was formed no great supply of water would have reached the Lake Mohave Basin until Manix Lake overflowed. If, however. Lake Mohave was wholly contemporaneous with Manix Lake, the precipitation in the area directly tributary to the Lake Mohave Basin below Manix Lake must have been considerably greater than it is today. Evidence on the relative age of these lakes will aid in inter- preting the climatic conditions under which they existed. In January, 1916, floods from Mohave River covered Silver Lake playa to a depth of 8 or 10 feet. When the water disappeared 18 months later, maay dead fish were found on the playa. These had been carried at least 25 miles from their regular habitat along the river. Fish remains have been reported under similar conditions on the other desert playas. Such occurrences show that fresh-water remains in desert deposits do not necessarily indicate the existence of an ancient perennial fresh- water lake. The fish belong to two species. — One the common catfish, and the other Siphateles mohavensis, which is found only in Mohave River. Other species of the latter genus live in the San Joaquin River, Owens River, Lahontan, and other systems. It is not certain how Siphateles mohavensis reached its present habitat, but it is suggested that members of the genus may have migrated from Owens River to Death Valley, through a chain of lakes described by Gale, and thence up the ancient Mohave River, through Lake Mohave. If such a migration took place the same genus ought to be found in Amargosa River which now enters Death Valley. O. E. Meinzer: Ground-water problems in the Hawaiian Islands. Mr. Meinzer spent February and March, 1920, in the Hawaiian Islands to start a systematic geologic and ground-water survey of the Islands. Work was in progress in 1920 in the Kau district on the Island of Hawaii, by W. O. Clark and L. F. Noble, and in the Honolulu district by H. S. Palmer. The present paper outlined the ground-water problems as seen in this visit of two months. The rocks of the Hawaiian Islands consist chiefly of small irregular bodies of extrusive lava which is very permeable. This great permeability results in (1) heavy absorption of rain by the rocks, (2) flatness of the water tables, (3) scarcity of springs and streams, (4) large yields of aquifers, and (5) large yields and specific capacities of wells. The ground water can be divided into two kinds : high-level water and low- level water. The low-level water does not occur much above sea level; the OCT. 19, 1921 proceedings: geological society 425 high-level water may occur hundreds or even thousands of feet above sea level and is held up by definite rock structures such as dikes and interbedded soils and imper\dous ash. The high-level water may belong to the main body of ground water or may be a perched body of water not associated with the main body. This water is valuable especially because it does not generally have to be lifted as does the low-level water. The problems of its discovery relate to rock structure and require geologic methods of investigation. The geologic studies should indicate effective but inexpensive methods of prospecting. The low-level water is in some places non-artesian, but in other places it occurs in artesian basins produced by nearly impervdous sedimentary beds overlying the water-bearing lavas. The problems with respect to this water relate chiefly to the quantities available and to contamination by sea water. They require studies of the coasts with respect to emergence and sub- mergence, the consequent development and position of sedimentary^ deposits, and the effectiveness of these deposits in producing artesian conditions and in protecting the ground water from sea w^ater. They also require quan- titative studies of absorption, pumpage, head, and correlative salt content, and studies of the underground leakage of wells and methods for conserving the artesian supply. A valuable contribution to the methods of ground-water investigation developed in the Hawaiian work is the use of current meters for detecting leakage of wells. Prof. L. C. Graton spoke on the relation of secondary enrichment to to- pography and ground water, and especially on the problem of the accumula- tion of the iron minerals in gossan. Prof. Wm. M. Davis was invited by the President to address the Society, and spoke on some reef limestones found in the floors of valleys penetrating the lower slopes of the volcanoes on the Island of Oahu, and their bearing on the diastrophic history of the Hawaiian Islands. 348th meeting The 348th meeting was held at the Cosmos Club at 8 p.m., on Wednesday, May 12, 1920. Regular Program Stratigraphy of the Bend Series and contiguous formations in north-central Texas. P. V. Roundy: Micro-paleontology. M. I. Goldman: Lithology. The two papers were discussed by Messrs. Girty, Went worth, Heald, David White, H. Bassler, Stose, Alden, Loughlin, and G. R. Mans- field. Mr. Goldman's paper on Lithology of the ''Bend Series" and cmitiguoiis formations of north-central Texas is the result of the study of a nearly complete series of samples (representing mostly intervals of 10 feet) from 2400 to 4510 feet in the Seaman No. 1 well, Roxana Petroleum Corporation, Palo Pinto County, Texas. In each sample as many types of ingredients as could be recognized were differentiated under the hand lens, and their proportions estimated. Peculiar types and at intervals the common types were made into thin sections, studied under the compound microscope, and the proportion of sand, clay, and lime in each type estimated. Three graphic logs were pre- sented; one showing the estimated proportion of sand, clay, lime, sand flint in each sample, another the usual type of graphic log showing the succession of beds as indicated by the above examinations, the third the usual graphic 42G JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 presentation of the driller's log. From the first-named log (the "percentage log") it appeared that there are in this well distinct lithologic units charac- terized by the proportion of the four ingredients differentiated, and that the boundaries between these are usually well defined. From the second log it appeared that these boundaries are usually marked by some distinct bed, some times by a conglomerate or sandstone, but in most cases by a coarsely glauconitic sandv bed. In this way it was possible to place the boundary between the Marble Falls (Pennsylvanian) and the Lower Bend (Mississippian) with ab- solute precision and in conformity with the paleontologic evidence. Boun- daries between the Marble Falls, Smithwick, and Milsap were also suggested, though in the absence of paleontologic evidence these are uncertain. Other lithologic units not hitherto distinguished by names were indicated. It was shown that the driller's log gives little if any evidence for the most sig- nificant criteria. In further support of a hypothesis previously offered that unconformities are marked by glauconitic beds it was shown that a glauconitic layer occurring at the base of the Lower Bend just above the EUenberger limestone in out- crops in San Saba County had been traced north through all wells (3) exam- ined in which this contact appeared including the Seaman well more than 100 miles north of the outcrop. It was also indicated that pyrite or other sulfides are associated with glauconite and phosphate at unconformities, and it was suggested that the presence of all three minerals is due to the abun- dance of organic matter encountered by a transgressing sea. T. Wayland Vaughan: Results of recent studies of the geology of the North- ern West Indies. (Illustrated.) (Read by W. P. Woodring.) 349th meeting The 349th meeting was held at the Cosmos Club at 8 p.m., on Wednesday, November 10, 1920. Informal Communication C. K. Wentworth: A sizing scale for the constituents of sedimentary rocks. (Presented by M. I. Goldman.) Regtdar Program Courtenay De Kalb: The Rio Tinto and other historic mines of Spain. (Illustrated.) C. W. GiLMORE: Remarks on the reconstruction of extinct reptiles. (Illus- trated.) Laurence LaForge, Secretary. 350th meeting. The 350th meeting was held in the auditorium of the New National Museum at 8 p.m., on Saturday, November 20, 1920. Regular Program Willis T. Lee: An evening "in the air." A popular presentation of the use of aerial photographs in geography. Stereopticon views of natural scenery and of objects of geographic interest as seen from an aeroplane were shown, including views of submarine ob- jects and drowned land forms, shown here for the first time. There was also a series of moving pictures taken from hydroplanes, showing scenes along the Potomac, the Pacific fleet passing through the Panama Canal, and scenes along the coast of California. The films were loaned for the evening by the Navy Department. W. T. Thom, Jr., Secretary. OCT. 19, 1921 proceedings: geological society 427 351st meeting The 351st meeting was held in the auditorium of the Cosmos Club at S p.m., on Monday, December 6, 1920. Regular Program O. E. Meinzer: Recent volcanic events on the Island oj Hawaii. (Illus- trated.) This paper was a concise and graphic presentation of the exceptionally- spectacular events in 1919 and 1920 on Kilauea and Mauna Loa — the two active volcanoes of the Hawaiian Islands. It included lantern slides show- ing one of the lava flows in action, with the two kinds of lava — aa and pahoehoe — being extruded at the same time. The outstanding events of 1919 and 1920, named in chronological order, were (1) long-continued overflow of Hale- maumau, the crater of Kilauea; (2) a vigorous lava flow on the flanks of Mauna Loa, nearly 3,000 feet above the level of Halemaumau, this flow reaching the sea, l4 miles from the vent, within 24 hours of the beginning of the eruption; (3) a drop of 600 feet in the lava column in Halemaumau in one night; (4) gradual and quiet opening of fissures radiating from the cra- ter of Kilauea, some of them to a width of 15 feet; (5) gradual rise of lava in some of the fissures and ultimate overflow which developed into a vigorous lava flow with vents about 6 miles from the crater of Kilauea. The specific facts are recorded in the monthly bulletin of the volcano observatory by Prof. T. A. JAGGAR. The volcanoes of Hawaii have a wide reputation for their gentle habits. When eruptions occur, the inhabitants, instead of fleeing, hastily assemble to see the show. There have, however, been two catastrophes within his- toric times — an explosive eruption of Kilauea in 1790 which is said to have destroyed an Hawaiian army, and a violent earthquake in 1868 which caused a huge landslide that destroyed many lives. The geological survey of this part of the island begun last year by L. F, Noble and the speaker and now being carried out by W. O. Clark, has, however, revealed numerous beds of volcanic ash and deposits of land-slide material interbedded with lavas at many widely separated horizons, showing that, from the standpoint of geo- logic time, violent eruptions and huge landslides have not been unusual occurrences. Baron Gerard De Geer: Geochronology and its application to America and to other parts of the Earth. (Illustrated.) 352d MEETING The 352d meeting was held in the auditorium of the Cosmos Club at 8 p.m., on Wednesday, December 22, 1920. Regular Program Bailey Willis: Evidences of compression on the Pacific Coast. After a brief recess the twenty-eighth annual meeting was called to order. The reports of the Secretaries, Treasurer, and Auditing Committee were read and accepted. The following officers were elected for 1921: President, G. W. StosE; Vice-Presidents, G. F. Loughlin and F. E. Wright; Treasurer, G. R. Mansfield; Secretaries, W. T. Thom, Jr., and Laurence LaForge; Members-at-large of the Council, C. N. Fenner, K. C. Heald, Miss A. I. Jonas, F. J. Katz, E. T. Wherry. Laurence LaForge, Secretary. 428 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 17 SCIENTIFIC NOTES AND NEWS The following educational courses are being offered at the Bureau of Stand- ards this winter: C. A. Skinner, Advanced optics; L. H. Adams (Geophys- ical Laboratory, Carnegie Institution of Washington), Chemical thermo- dynamics; Chester Snow, Interpretation of data, including the theory of errors and methods for numerical, graphical, and mechanical computation; L. B. Tuckerman, Differential equations. The committee in charge consists of L. B. Tuckerman, Chairman; F. B. Silsbee, Secretary; Miss A. K. Benson, L. J. Briggs, L. V. Judson, and C. E. Waters. Prof. Ernst Cohen, of the University of Utrecht, Holland, and Prof. J. W. McBain, of the University of Bristol, England, visited the scientific institutions of Washington in September. Mr. William H. Gamble, topographer and map engraver with the U. S. Geological Survey, and the oldest employee in the Federal service at the time of his retirement in August, died on September 16, 1921, at the age of eighty- five. Mr. Gamble was born in Philadelphia November 4, 1835. He was engaged in map publishing in Philadelphia until 1895, when he joined the U. S. Geological Survey in Washington. A department of botany has been organized at George Washington Uni- versity, in charge of Prof. R. F. Griggs, formerly of Ohio State University and recently director of the Katmai Expeditions of the National Geographic Society. Mr. Ralph C. Holder has resigned as junior chemist in the food research laboratory, Bureau of Chemistry, to take charge of the chemical laboratory of the CoUis Products Company of St. Paul, Minnesota. Dr. Walter Proctor Jenney, mining engineer, died at his home at 1417 Park Road on September 16, 1921, in his seventy-third year. Dr. Jenney was born at Fairhaven, Massachusetts, January 11, 1849. He was mining engineer for several railroad and mining companies during the period of development of the mineral resources of the West, and was with the U. S. Geological Survey in the years 1889-1892. In 1909 he became interested in the investigation of ship forms for the Navy Department and was in that work through the War period. Since 1919 he had been engaged in research work for the Department of Agriculture. Mr. Hugh Miller, recently captain in the U. S. Army and instructor in the engineers' school at Camp Humphreys, and formerly a member of the en- gineering faculties of Clarkson School of Technology at Potsdam, New York, and Rice Institute of Houston, Texas, has been appointed professor of civil engineering at George Washington University. Mr. Samuel Stockton VoorheES, engineer and chemist at the Bureau of Standards, died at Portland, Maine, on September 23, 1921, in his fifty- fifth year. Mr. Voorhees was born at Springfield, Ohio, January 15, 1867. During the first fifteen years of his professional work he was chemist or en- gineer of tests for several of the eastern railroad companies. From 1901 to 1908 he was with the supervising Architect's Office of the U. S. Treasury, and then went into chemical work at the U. S. Geological Survey. Since 1910 he had been in the chemical division of the Bureau of Standards, in charge of the chemical work on structural materials. He was a member of the Acad- emy, a past president of the Chemical Society, and a member of the Bio- logical Society. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 November 4, 1921 No. 18 INORGANIC CHEMIvSTRY.— r/^t- crystal structures of the alkali halides} I. Ralph W. G. Wyckoff, Geophysical Laboratory, Carnegie Institution of Washington. (Communicated by Arthur L. Day.) Introduction. — A knowledge of the cr^^stal structures of a large number of chemical compounds will furnish information concerning the nature of the atoms themselves and of their manner of combination one with another. Though the structures of most complicated com- pounds, especially those having a symmetry that is other than cubic or rhombohedral, cannot yet be obtained with certainty and exactness because of the absence of precise knowledge concerning the laws of scattering, there are many simple substances in which the arrangement of their constituent atoms can be determined with all of the assurance of correctness with which the structure of any crystal can now be obtained. Of these substances the simplest, aside from the elements themselves, are compounds of the type RX, where R is an electro- positive atom and X is a more electronegative (electron-seeking) atom of equal valence. This paper furnishes an account of the study of the crystal structures of one class of the compounds RX, the alkali halides. The possibility, which seems to arise from a consideration of the structures of simple crystals, of assigning definite sizes to the various atoms and building up crystals by the close packing of these atoms has already been given especial attention.- Most of the data upon which this work was based were obtained by assuming a particular arrangement of the atoms in the crystals and by calculating the di- mensions of the unit cells with the aid of the published values of the densities of the crystals. In view of the unreliable character of these density determinations and because of the inabiUty to choose between the different structures that are possible for these simple crystals, ' Received October 10, 192L 2 W. L. Bragg. PhiL Mag. (6) 40: 169. 1920. 429 430 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. IS it is evident that a satisfactory decision concerning the constancy of atomic dimensions can only be made after more direct information is available through studies of the crystal structures of these com- pounds. A detailed discussion of the bearing of these results upon the prob- lem of the shapes and sizes of atoms will be deferred until data upon other simple structures have been given. The method of determination. — The structures of these alkali halides were obtained from a study of their powder photographs.^ A dis- cussion of all of the simple ways of arranging the atoms of the com- pound RX that are geometrically possible, together with the manner of calculating in a qualitative fashion the nature of the diffraction effects to be expected from each of these possible arrangements, has been given elsewhere.^ With the following exception this same method of calculation is pursued in these determinations. A closer accord of the "normal decline" of intensity of "reflection" with the spacing of the reflecting planes as observed by spectrometer measurements upon sodium chloride and other simple crystals^ is obtained by assuming that the intensity is proportional to the 2.35 power of the spacing instead of the simple square. The calculated intensities thus obtained by writing fid/n) = {d/ny-'' give, as the following results will show, a surprisingly close qualitative agreement with the intensities of the corresponding difTraction effects as estimated from the photographs. Since a study of four or five of the most intense lines in the spectrum was in all cases sufiicient to decide between the different possible struc- tures, the accompanying tables will be limited to recording the data from them only. In many cases, however, the number of observed lines was as great as ten or fifteen. Many lines could not be observ^ed in the spectra obtained with rubidium salts and from bromides be- cause of the large amount of secondary radiation emitted by rubidium and bromine." The dimensions of the unit cell were obtained in each 3 A. W. Hull. Phys. Rev. (2) 10: 661. 1917; P. Debye and P. ScherrER. Phys. Zeitschr. 17: 277. 1916. * Ralph W. G. Wyckoff and Eugen Posnjak. The crystal structures of tlie cuprous halides. Journ. Amer. Chem. Soc. (in press). * W. H. Bragg and W. h- Bragg. X-rays and crystal structure. (London, 1918). * Trouble from this secondary radiation could have been eliminated for the most part by the use of a second filtering screen placed next to the photographic plate. Such a film was not, however, available at the time these experiments were carried out. NOV. 4, 1921 WYCKOFF: STRUCTURE ALKALI HALIDES 431 case by averaging the values calculated from these first three or four lines. Unless the true s}'mmetry of these crystals is either tetrahedral or tetratohedral cubic, — and there is no evidence for either of these two kinds of symmetry, — the number of arrangements having four mole- cules within the unit cell is limited to two: the "sodium chloride" arrangement or the "zinc sulfide" arrangement. R • X Fig. 1. The unit cell of the sodium chloride grouping. Sodium chloride The spectrograph used in all of these experiments was standardized using sodium chloride, the length of the unit celP of which was taken to be 5.628X10-^ cm. Sodium bromide The positions of the spectrum lines together with the previously determined value of the density clearly show four molecules to be associated with the unit cell. hkl Hid) 100(2J 110(2) Calculated density' =3.20 Spacing: 'stals is almost identical with that of pyroxenites of Monte Somma, described by Lacroix. The relative merits of the gravitative-adjustment and fraction al-cr}-stallization theories of certain forms of differentiation are discussed. Crystals of augite from Monti Rossi, from the eruption of Etna in 1669 are also described, with a new analysis and optical determinations. No good analyses of the augites of either Vesuvius or Etna are to be found in the literature. Spallanzani (circa 1790) was the first to determine the relative melting points of the feldspars and augite, and to measure their relative mag- netic susceptibility; he is therefore to be regarded as the first experimental geophysicist. The paper also gives a comparison of the chemical compositions of various Italian augites with the lavas that contain them. H. S. W. GEOLOGY.— r/t^ Divide silver district, Nevada. Adolph Knopf. U. S Geol. Survey Bull. 715-K. Pp. 24 (147-170). 1921. The Divide district, one of Nevada's newest silver camps, centers at Gold Mountain, 5 miles south of Tonopah. The discovery of silver ore that started the great activity at this camp was made late in 1917, wholly by chance. A crosscut was being driven to cut a small gold vein that had been worked higher on the slope of Gold Mountain intermittently since 1902, and before it had been driven far enough to cut the gold vein it quite unexpectedly inter- sected a rich silver-bearing lode. Further exploration indicated that a large and valuable ore body had thus accidentally been discovered. The prevailing rock in the Divide district is the Fraction rhyolite breccia. This is intruded by several stocks of the Oddie rhyolite and by a large mass 442 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 18 of andesite. Later than all of these is a series of latite lava flows, which cap the highest peaks of the district. The ore bodies are zones of fracturing and shearing in the Fraction rhyo- lite breccia; strictly speaking they are lodes, not veins. The chief silver- bearing mineral is cerargyrite (horn silver), which is commonly concentrated in rich masses along irregular seams of sericite that traverse the lodes. The primary metalliferous material is leanly mineralized rhyolite breccia carrying a small amount of finely disseminated pyrite and threaded by thin veinlets of exceedingly fine-grained quartz. What the primary silver-bearing mineral is has not been determined. The scarcity of quartz or of silicification is a noteworthy feature of the ores of the Divide district, especially in contrast with the high silica content of the ores in the adjoining district of Tonopah. The silver in the lean primary material of the lodes was concentrated by downward enrichment as soft "sooty" argentite, and subsequently most of this supergene argentite was converted to horn silver. A. K, GEOLOGY and HYDROLOGY.— ii;t;^/orator>' drilling for ivater and use of ground water for irrigation in Steptoe Valley, Nevada. W. O. Clark and C. W. RiddELL, with an introduction by O. B. Meinzer. U. S. Geol. Survey Water-Supply Paper 467. Pp. 70, pis. 6, figs. 6. 1920. Steptoe Valley, in east-central Nevada, is about 95 miles long and 900 square miles in area. It lies in a structural trough between northward- trending mountain ranges and contains thick deposits of alluvium with under- lying lake beds. Ancient shore features show that the valley once contained a lake about 30 miles long which discharged northward into Gosiute Valley. The valley is too arid for agriculture without irrigation, and the supply of surface water is meager. The paper gives the results of test drilling that was done b)^ the Geological Survey, as authorized by Congress, for the purpose of finding water for irri- gation. The test wells demonstrate that beneath the desert surface are stored supplies of water adequate in quality and quantity for irrigation. The paper also comprises a systematic description of the hydrology of the valley with special reference to the interpretation of the results obtained in drilling. It includes numerous measurements of stream flow and absorption, on the basis of which it is estimated that the perennial streams contribute about 20,000 acre-feet a year to the ground-water supply and that the total annual ground-water supply is probably not less than 50,000 acre-feet. Cer- tain plant species were found to feed habitually on the water in the zone of saturation, and different species were found to indicate different depths to the water table. The detailed map shows the zones of the principal water- indicating plants, the areas of active and intermittent ground-water dis- charge, and the estimated depths to the water table. It shows that water is being discharged from the zone of saturation, through soil and plants, in an area of about 115,000 acres. The paper also describes a number of large springs, some of which are thermal. It includes a map of Nevada showing 38 Pleistocene lake beds thus far discovered lying wholly or partly in the State, four of which were mapped in the present investigation. O. E. M. NOV. 4, 1921 proceedings: academy 443 PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES WASHINGTON ACADEMY OF SCIENCES BOARD OF MANAGERS At the 24Sth meeting of the Board, on February 28, 1921, the Editors of the Journal were authorized to classify the Academy's excess stock of sepa- rates from the Proceedings (1898-1911) and to publish lists of these papers on the back cover of the Journal, offering the papers for sale for a limited period at prices from one third to one fifth the regular price. (Publication of the lists was begun on March 4.) Messrs. C. I,. Alsberg, F. V. CoviLLE, H. S. Graves, A. D. Hopkins, and E. W. Nelson were appointed a committee to represent the Academy at the Lubin Memorial Meeting. At the suggestion of the Botanical Society, the President appointed a committee to investigate the facts regarding the sending of scientific literature to Russian scientists, the committee consisting of A. S. Hitchcock, Vernon Kellogg, and Raphael ZON. The 249th meeting, on March 14, and the 250th, on March 28, were de- voted to elections of members and routine business. The committee to consider transmission of literature to Russia reported on the existing situation, but not enough information was available to warrant the Board in adopting any definite proposals for action. At the 251st meeting, on May 2, the Board voted to endorse the Mt. Hamilton project for a National Botanic Garden, and Messrs. H. S. Graves, F. V. Coville, and T. Wayland Vaughan were appointed a committee to cooperate with the Washington Society of the Fine Arts and any other interested organizations in forwarding the project. Mr. A. S. Hitchcock resigned as Vice-President from the Botanical Society on account of absence from the United States, and Mr. Michael Shapo- VALOV was elected to succeed him. At the 252d meeting, on May 23, the committee on distribution of the Proceedings reported that sets in libraries which had been on the mailing-list had been completed in about 90 cases, and that complete sets were being offered to a selected list of libraries which had not formerly received the publication. The following Committee on Meetings for the season 1921-1922 was an- nounced at the 253d meeting, on August 1 : W. J. Humphreys, Chairman; W. D. BiGELOw, O. C. Merrill, A. C. Spencer, and W. T. Swingle. The preliminary^ report of the committee on a list of popular books in science for the Public Library was considered in detail, and approved for publication in the Journal as a tentative list subject to revision.^ Election of members and routine business were taken up at the 254th meeting, on September 26. The following persons have become members of the Academy since the last report in the Journal (March 19, 1921, p. 139): Dr. Sumner Gushing Brooks, Hygienic Laboratory, U. S. Public Health Service, Washington, D. C. ' See This Journal U: .353-.366. September li), 1921. 444 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 18 Dr. Frederick Gardner Cottrell, National Research Council., 1701 Massachusetts Avenue, Washington, D. C. Prof. Robert Fiske Griggs, National Geographic Society and George Washington University, Washington, D. C. Prof. Mayo D. Hersey, Massachusetts Institute of Technology, Cam- bridge, Massachusetts. Dr. Earl S. Johnston, Maryland Agricultural Experiment Station, CoUege Park, Maryland. Dr. E. Lester Jones, U. S. Coast and Geodetic Survey, Washington, D. C. Dr. Robert Hamilton Lombard, Geophysical Laboratory', Carnegie Institution of Washington, Washington, D. C. Dr. Henry C. Macatee, 1478 Harvard Street, Washington, D. C. Dr. Richard Bishop Moore, U. S. Bureau of Mines, Washington, D. C. Dr. Robert W. SaylES, Geological Museum, Harvard University. Cambridge, Massachusetts. Assistant Surgeon General J. W. Schereschewsky, U. S. PubUc Health Service, Washington, D. C. Dr. Michael Shapovalov, Bureau of Plant Industr>% U. S. Department of Agriculture, Washington, D. C. Dr. Edwin Emery Slosson, Science Servdce, 1701 Massachusetts Avenue, Washington, D. C. GEOLOGICAL SOCIETY ,353d meeting The 353d meeting of the Geological Society of Washington was held in the auditorium of the Cosmos Club at 8 p.m. on Wednesday, January 12, 1921. Regular Program H. G. Ferguson: Lode deposits of Manhattan, Nevada. (Illustrated with lantern slides.) C. N. Fenner: Structural and volcanic geology of the Katmai region, Alaska. (Illustrated with lantern slides.) This paper has been published.^ H. D. Miser: Llanoria, the Paleozoic land area in Louisiana and eastern Texas. Evidence for a Paleozoic land area that occupied at least a part of Louisiana and eastern Texas has been published from time to time by different geologists. The most important paper on the subject is one by J. C. Branner, published in the American Journal of Science in 1897. Considerable information on the subject was obtained by the late Dr. A. H. Purdue and the writer during several years' study of the rock formations in the Ouachita Mountains and Arkansas Valley of Arkansas and Oklahoma, beginning in 1907. The follow- ing conclusions are based on this information and on the data published by other geologists. A land area which has been called Llano by Willis, Schu- chert, and Ulrich, and Llanoria by Dumble and Powers, existed in Louisiana and eastern Texas during much, if not most, of the Paleozoic era, and during the Triassic and Jurassic periods of the Mesozoic era. It varied in outline from time to time. It may have occupied a part of the area of the present Gulf of Mexico; at times it was doubtless connected with large land areas 1 Journ. Geol. 28: 569-606. 1920. NOV. 4, 1921 proceedings: geological society 44.") occupying at least much of central and northern Texas, southern Oklalioma, and southern Arkansas, and for short periods it may have extended eastward across the lower Mississippi Valley and joined the southwest end of the Appa- lachian area. It furnished most of the sediments that formed the clastic rocks of Pennsylvanian age in north-central Texas, and for those of Ordovician, Silurian, Mississippian, and Pennsylvanian age in the Ouachita Mountains and Arkansas Valley of Arkansas and Oklahoma. At times, as during the Devonian period, it had very little relief, but at other times, as during the Ordovician and Silurian periods and the Mississippian and Pennsylvanian epochs, it was mountainous. It was depressed and entirely submerged during Lower Cretaceous time and later depressions carried the sea across it during Upper Cretaceous and Tertiary time, so that its rocks are now covered and entirely concealed by deposits of these ages. The discover}'- of pre-Cambrian schists directly beneath Cretaceous strata at Waco, George- town, Maxwell, San Antonio, and Leon Springs, Texas, suggests that the rocks of this old buried land area were similar to the crystalline rocks now exposed in the Piedmont Plateau of the eastern United States. If so, such rocks underlie the Cretaceous strata over much of Louisiana, eastern Texas, and perhaps adjoining areas to the south and east. Prominent structural features of the Gulf Coastal Plain, including the Preston anticline and Sabine uplift, may mark the location of some of the folds that were produced in the rocks on the old land area but that have undergone further movement since they were buried by Cretaceous and later sediments. The results of future deep drilling in the Gulf Coastal Plain and further study of the Paleozoic and older rocks that are exposed around the borders of the Gulf Plain will add greatly to our imperfect knowledge of the old land area considered in this abstract. Laurence LaForge, Secretary. 354th meeting The 354th meeting was held in the lecture room of the Cosmos Club at 8 p.m. on Wednesday, January 20, 1921. Regular Program D. F. Hewett and E. V. Shannon: Orientite, a new silicate of manganese and calcium. A. — Chemical properties (Shannon). B. — Genesis and signifi- cance (Hewett). As Mr. Shannon was out of the city the entire paper was presented by Mr. Hewett. - Charles Butts: General results of recent work on the Mississippian of the Mississippi and Ohio valleys. J. B. Reeside and Harvey Bassler: Phases of the Carboniferous and Triassic of southwestern Utah. The geologic section of southwestern Utah includes rocks assigned to the Redwall limestone of Pennsylvanian age, the Supai and Coconino sandstones and Kaibab limestone of Permian age, the Moenkopi formation of Lower Triassic age, the Shinarump conglomerate and Chinle formation of Upper Triassic age. Comparison with the formations of areas to the southeast in Arizona and to the west and north in Nevada and Utah warrant the follow- ing conclusions: The Supai formation, passing from east to west and north- west, loses its red color and its shale members and merges with the Coconino to form a continuous massive yellow sandstone. The Kaibab limestone becomes thicker but has everywhere two cliff-forming limestone members separated by g^^psiferous beds. The red continental deposits of the Moen^ 446 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. IS kopi pass with considerable interfingering into marine limestone. The Shina- rump conglomerate and the Chinle formation maintain the same general character though quite variable locally. There is a pronounced hiatus at the base of the Moenkopi formation and another at the base of the Shinarump conglomerate. The age assignment of the Redwall, Kaibab, and Moenkopi formations is based on fossils ; the assignment of the other formations is based on lithology and stratigraphic position only. W. T. Thom, Jr., Secretary. 355th meeting The 355th meeting was held in the lecture room of the Cosmos Club at 8 p.m. on Wednesday, February 9, 1921. Regular Program H. S. Washington: The Deccan traps and other plateau basalts. R. C. Wells: Utilization of some western salines and saline lakes. (Illus- trated with lantern slides.) R. S. BasslER: Paleontological work at the National Museum. (Illustrated with lantern slides.) Laurence LaForge, Secretary. 356th meeting The 356th meeting of the Society was held in the lecture room of the Cosmos Club, at 8 p.m. on Wednesday, February 23, 1921. Informal Communications Dr. R. C. Wells called attention to an inadvertent misstatement in his paper given at the previous meeting, and corrected the same. Mr. Laurence LaForge gave a brief review of a paper by J. W. Gregory on The eskers of Ireland and compared Professor Gregory's conclusions with those derived by American glacialists from the study of American eskers. Regular Program F. E. Matthes : Torrent channels and torrent levees in the Yosemite Valley. (Illustrated with lantern slides.) Sidney Paige : Structure of the Homestake ore body (illustrated with black- board drawings and a wooden model). W. T. Thom, Jr., Secretary. 357th meeting The 357th meeting of the Society was held in the lecture room of the Cos- mos Club at 8 p.m. on Wednesday, March 9, 1921. Regular Program G. R. Mansfield: Igneous geology of southeastern Idaho. (Illustrated with lantern slides.) A. I. Jonas and E. Bliss Knopf: Stratigraphy of the metamorphic rocks of southeastern Pennsylvania and Maryland. The oldest metamorphic rocks of the southeastern border of the Piedmont Plateau are of pre-Cambrian age. The oldest formation is the Baltimore gneiss which is a composite gneiss comprising a thoroughly recrystallized biotite gneiss of undeterminate origin, possibly sedimentary, and a granitic intrusion that has interpenetrated the biotite gneiss and produced in many places an injection gneiss. The age of the granite has not yet been definitely determined and it is probable that the Baltimore gneiss has been cut by several granites of widely separated periods of intrusion. The Baltimore gneiss is overlain by a series of sediments that are tentatively considered to be lower Cambrian. The base of this series is the Setters form- NOV. 4, 1921 SCIRNTIFIC NOTES AND NEWS 447 atioii which has hitherto been connected with the lower Cambrian fossiliferotis Chickies quartzite of Pennsylvania. The work of the writers in the last two years has led them to conclude that the Setters formation is older than the Chickies quartzite. The vSetters is overlain by the Cockeysville marble and the Wissahickon formation. An upper member of the Wissahickon formation that is less highly anamorphosed than the Wissahickon itself has been sep- arated and named by the writers the Peters Creek schist. The Peters Creek schist may represent the Harpers schist member of the Mont Alto quartzite of central Pennsylvania, in which case the metamorphic series comprising the Setters formation, Cockeysville marble, Wissahickon formation, and Peters Creek schist would be, as suggested by the writers, basal Cambrian. The Chickies quartzite in Pennsylvania has been shown to be GOO feet above the base of the Cambrian. The Camargo schist is the name given by the writers to a porphyritic albite schist that comformably oAcrlies a dolomite of probable Beekmantown age. It forms the ridge that flanks Chester Valley on the south and comprises a portion of the formation formerly known as the Octoraro schist. It may represent the metamorphosed equivalent of the Normanskill shale found near Harrisburg, Pennsylvania. The contact between the Wissahickon formation, Peters Creek schist, and the Camargo schist on the southwest border of the Camargo schist is a thrust fault called in the report the Drumore fault. It has been traced from Trenton. New Jersey, 150 miles southwest to Carroll County, Maryland. Further work on the northeast continuation of this fault will help to establish a correlation between the geology of New England and of the Pennsylvania Piedmont formations. O. E. Meinzer: a map of Pleistocene lakes in the Basin-and-Range Province, and its interpretation. (Illustrated with lantern slides.) Laurence LaForge, Secretary. 35STH MEETING The 358th meeting was held in the lecture room of the Cosmos Club at 8 p.m. on Wednesday, March 23, 1921. Regular Program h. H. Adams: The elastic properties of rocks. Laurence LaForge : Suggested modification of the doctrine of peneplanation in the light of recent knowledge. - W. T. Thom, Jr., Secretary. SCIENTIFIC NOTES AND NEWS The thirty-eighth annual convention of the Association of Official Agricul- tural Chemists was held at the Washington Hotel on October 24-26. An Executive Board meeting of the American Engineering Council was held at the Cosmos Club at 10 a.m. on Friday, September 30. Reports were presented from the Council's committees on licensing of engineers, classifi- cation and compensation of engineers, Employment Service, and other matters. The following lectures have been given before the Physics Club of the Bureau of Standards since the last report in this Journal (p. 171): April 4, 1921, S. J. Mauchly: The methods and problems of atmospheric electricity; May 27 (joint meeting with Mathematics Club), J. S. Ames: Some appli- JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11 NO. IS cations of hydrodynamics to aeronattttcs; October 17, Arthur L. Day: The study of California earth movements; October 24, H. G. Gale: Earth tides. The National Museum has received the Hubert Ward collection of African ethnologica from Paris, containing 19 sculptures by Mr. Ward and 2(300 specimens of the arms and implements of the Africans of the Congo. Dr. Elmer D. Ball, formerly Assistant Secretary of Agriculture, has entered upon his new duties as director of scientific work for the Department of Agriculture. Mr. E. F. HiCKSON, until recently associate engineer in the department of technical control, American Writing Paper Company, Holyoke, Massachu- setts, has returned to the Bureau of Standards as associate chemist. Mr. C. E- Mangels has resigned as chemist in charge of the commercial dehydration laboratory of the Bureau of Chemistr}^ U. S. Department of Agriculture, to accept the position of cereal chemist at the North Dakota Agricultural Experiment Station at Fargo, North Dakota. Dr. Truman Michelson, of the Bureau of American Ethnology, returned in October from three and a half months' field work among the Fox Indians of Iowa. Prof. Edward E. Richardson discussed the Philosophical aspects of Ein- stein's theory of relativity before the Society for Philosophical Inquiry at the Public Library on October 1. Dr. L. I. vShaw, assistant chief chemist of the Bureau of Mines, has been transferred to the Columbus, Ohio, ceramic experiment station of the Bureau, where he will have charge of some newly organized research on refractory products. Dr. George Otis Smith, director of the U. S. Geological Survey, addressed the annual meeting of the New York State Oil Producers' Association at Olean, New York, on September 31, on The real value of oil. Dr. Merwin Porter Snell, a member of the scientific staffs of the Smith- sonian Institution and the Bureau of Fisheries in the years 1SS1-1S89, died at his home at Stamford, Connecticut, on September 23, 1921, at the age of fifty-eight. Prof. A. Tadakadate, of the Imperial University of Tokyo, visited Wash- ington in August, while on his way to the international conference on weights and measures at Paris. Dr. C. W. Waidner, Chief of the Heat Division of the Bureau of Standards, has been appointed Chief Physicist of the Bureau to succeed the late E- B. Rosa. Secretary Charles D. Walcott of the Smithsonian Institution returned from his field work in October. He reports the coldest and most disagreeable field season he had ever known in the Canadian Rocky Mountains. Paleon- tological and geological work was greatly hindered by mist and snow. Messrs. J. E. Walters, F. W. Schroeder, and Frank Porter, chemists at the helium plant of the Bureau of Mines at Petrolia, Texas, have been transferred to the new cryogenic laboratory of the Bureau in Washington. Dr. R. C. Wells of the U. S. Geological Survey has been appointed treasurer of the Chemical Society of Washington to fill the vacancy caused by the re- moval of Dr. L. I. Shaw from Washington. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 November 19, 1921 No. 19 MATHEMATICS.- — On the correlation between any two functions and its application to the general case of spurious correlation.'^ TowELiv J. Reed, Johns Hopkins University. (Communicated by Ray- mond Pearl.) In problems where correlation methods are employed it is often necessary to determine the coefficient of correlation between one of the measured variables and some function of the others. In certain cases we need to go still further and determine the correlation between two different functions of the measured variables. Such cases arise where two different index numbers are correlated with each other or when an index number is correlated with one of the measured variables. In all problems of this type the coefficient of correlation may be found by computing the value of the function in question at each position for which the values of the variables themselves are known and then finding the correlation coefficient in the usual way. In a great many cases however there would be a considerable saving of labor if this coefficient could be determined directly from the means, standard deviations, and first order correlation coefficients of the variables themselves. The following general equation has been derived to accomplish this and it should prove to be of use in problems of the type outlined above. The proof of the formula is too long to be given in the present paper, but will be published later, together w4th additional illustrations of its application. Let Xi, X2, Xn be a set of n variables, and Xi, 00^, x^ be a second set of k variables. Let Wi, Wo, m„ be the means of the variables of the first set, 0-1, 0-2, (Tn be their standard deviations, and rxix,, fxiXz >'xn-ixn be the coefficients of correlation between these variables taken in pairs. 1 Papers from the Department of Biometry and Vital Statistics, School of Hygiene, Johns Hopkins University, No. 38. Received October 18, 1921. 449 450 JOURNAL OP THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 19 The same notation will be used for the means, standard deviations and coefficients of correlation of the primed variables. Now lety = f {x^, x.^, x„) and z = f{x[,x'„ x'k) represent any two analytic functions of these two sets of variables. Then the correlation between these two functions is measured by X^j ^j fa Fp rxaXp(Ta- = — and 2 = — . X' ^ .... ^ ^h = ^h where h i;«. Thli is cplnlon suted by DtJlla IMH. 472 JOURNAIv OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 19 Domingo and by the downward trend of the arbitrary line dividing the Miocene from the Oligocene. The article is concerned with the value of Orthaulax as a kit fossil, the biological peculiarities of the genus, the his- torical development of the knowledge about it, the distribution of the known species and the systematic treatment of the five forms referred to it. Orthaulax is unique among the gastropods in that the entire spire is en- cased in a shelly envelope, a modification of the outer lip analogous to the finger growths and flanges upon the closely related stromb, the common conch of the West Indies. As in most highly specialized groups, the term of life is short, and, even with the increased knowledge, the limits of dis- tribution remain comparatively narrow. The tabular occurrence of the genus indicates its importance stratigraphically. The systematic treatment is remarkable for the refinement of method emxployed. The determination of the species is based finally upon the sec- tioning of the specimens, though the characteristics are, as a rule, suffi- ciently distinct to justify a confident field determination. Julia Gardner. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES WASHINGTON ACADEMY OF SCIENCES 153d meeting The 153d meeting of the Academy was held jointly with the Chemical Society of Washington in the assembly hall of the Cosmos Club, the evening of Thursday, January 20, 1921. The retiring President of the Academy, Dr. C. L. Alsberg, Chief of the Bureau of Chemistry, U. S. Department of Agriculture, delivered an address entitled The relation of chemical structure to physiological action . This has subsequently been published in the Journal of the Academy.^ 154th meeting The 154th meeting of the Academy was held at the Cosmos Club, the evening of Thursday, February 17, 1921. Dr. L. O. Howard, Chief of the Bureau of Entomology, U. S. Department of Agriculture, delivered an illustrated lecture entitled. How the Government is fighting insects. He discussed briefly the work of the Bureau over which he has presided for the last 27 years and with which he has been connected for more than 40 years, and traced the extraordinary growth of the service, which has been due to the increasing realization of the monetary importance of remedial work against insects affecting crops, the health of man and animals, stored food, and so on. From a beginning with one entomologist and an assistant, the Bureau has grown to a large organization with a budget of nearly two million dollars, with field laboratories scattered all over the country to the number of 75 or more, and with a corps of trained expert assistants numbering several hundreds. Lantern slides were shown of the operations being carried on at a number of these stations against some of the principal crop pests, and the lecture closed with a moving picture film showing the latest discoveries in the fight against the cotton boll weevil. In the course of his talk the speaker emphasized the point that the greater part of the work carried on in the Bureau is of the highest scientific character, requiring men of intensive training. ' This Journal 11: 321-341. August 19. 1921. NOV. 19, 1921 proceedings: botanical society 473 155th meeting The 155th meeting of the Academy was held at the Cosmos Club, the evening of Thursday, March 17, 1921. Dr. A. McL. Nicolson, research engineer of the Western Electric Company, Inc., New York, delivered an address on TJie piezo-electric effect in certain crystals. The address was illustrated with lantern slides, and demonstrations were given of some of the practical applications of the crystals to the transmission and reception of sound. 156th meeting The 156th meeting of the Academy was held jointly with the Biological Society of Washington at the Cosmos Club, the evening of Saturday, April 2, 1921. Dr. A. D. Hopkins of the Bureau of Entomology, U. S. Depart- ment of Agriculture, delivered an address entitled Intercontinental problems in nattiral and artificial distribution of plants and animals. In condensed form this has since been published in two papers in the Journal of the Acad- emy: (1) Intercontinental problems in biocliniatics ; with special reference to natural and artificial distribution of plants and animals."^ (2) Bioclimatic zones of the continents; with proposed designations and classification.^ 157th meeting The 157th meeting of the Academy was held at the Cosmos Club the evening of Thursday, April 21, 1921. Dr. C. G. Abbot, Assistant Secretary of the Smithsonian Institution, delivered an address on The solar constant observing stations of the Smithsonian Institution. In the course of his lecture the speaker described the studies of solar radia- tion carried out at Washington, D. C; Bassour, Algeria; Hump Mountain, North Carolina; Mount Harqua Hala, Arizona; Mount Wilson, California; Calama, Chile; Montezuma, Chile; and Mount Whitney, California, at altitudes ranging from sea level to 14,500 feet. He summarized results accomplished in perfecting processes of investigation, in the invention and construction of highly precise standardized instruments, and in the securing of simultaneous determinations of the solar constant of radiation at Washing- ton, Mount Wilson, and Mount Whitney; and the bearing of these results, notably with respect to meteorological investigations. The data are brought together in a paper of 20 printed pages, entitled Studying the sun's heat on mountain peaks in desert lands, which will appear shortly in the Appendix to the Report of the Smithsonian Institution for 1920. WiLLLf^M R. Maxon, Recording Secretary. BOTANICAL SOCIETY 150th meeting The 150th regular meeting of the Botanical Society of Washington was held in the Assembly Hall of the Cosmos Club at 8 p.m., Tuesday, March 1, 1921. 112 members and guests were present. Among the visitors were Dr. Robert F. Griggs of Ohio, Prof. Leo E. Melchers of Kansas, Dr. A. G. Johnson of Wisconsin, Mr. Paul Siggers, about to leave for his new work with Johnston and Carleton in Panama, and IMr. C. VallEJO, Agricultural Attache of the Argentine Republic. In the absence of President Cham- bliss, the meeting was called to order by Vice-President P. L. RickeR- 2 This Journal II: 223-227. 1921. 3 This Journal 11: 227-229. 1921. 474 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 19 A preliminary report was made by Dr. A. S. Hitchcock on the question of providing Russian men of science with scientific literature. Regular Program Haven Metcalf: The story of a plant introduction. (Address of the retiring President, illustrated with lantern slides.) Because of various diseases and other factors, rice culture in the South Atlantic States was on the decline in the early nineteen hundreds. One rice disease in South Carohna called "blast" or "rotten-neck" was very serious. In order to study the disease further, Dr. and Mrs. Metcalf took a trip to Italy and found that the "Brusone" was the same as blast in South Carolina. Resistant rices were secured and introduced into the United States. They did not retain their resistance, but one of them, now known as Colusa, by still further selection, has become the second in production in California, producing in 1919 1,655,000 bushels of grain, with an estimated farm value of over four million dollars. (A fuller discussion of Dr. Met- calf s address will be published elsewhere.) Roy G. Pierce, Recording Secretary. 151ST meeting The 151st regular meeting of the Society was held in the Assembly Hall of the Cosmos Club at 8:00 p.m. Tuesday, April 5, 1921. 51 members and guests were present. President Charles E. Chambliss presided. Mr. Soren Sorenson and Mr. D. Rudolf Kuraz were elected to member- ship. Mr. P. L. RiCKER reported on the work of the committee on the preservation of the Shaw water lily garden. A contribution from the Botan- ical Society toward the printing of a pamphlet and map in furtherance of the project was requested, and was authorized. Mr. RickER announced a series of "hikes" conducted by the Wild Flower Preservation Society and invited the members to join them. Regular Program W. H. Weston: Following a fungus through the Philippines. This lecture was illustrated with lantern slides exhibiting various phases of the botany of the islands, particularly the terraced rice fields, the tropical jungles, and the conditions surrounding the development and spread of the downy mildew of maize. All but one of the known species of the downy mildews of corn occur in the Orient. No conception of the terrifically destructive effect of this dis- ease can be gained from comparison with any disease known in America. Whole fields are destroyed. The disease is carried through the season by the production of enormous numbers of conidia. Saccharmn spontaneum, wild grass, Miscanthus japonicus, and a primitive type of cultivated sugar cane growing in the remote interior of Northern Luzon were also found to be hosts of this disease. Maize of flinty, poor yielding, tropical types was found to be grown under widely varying conditions, ranging from the swampy soil and coral sand of the hot, humid coast, to the precipitous rocky slopes of high elevations in the cooler mountainous interior. Waxy maize, hitherto known only from China and Burma, was collected from two widely separated localities. On all these types the mildew was, under favorable conditions, almost equally destructive, its ravages, which were aided greatly by the NOV. 19, 1921 proceedings: BOTANICAL SOCIETY 475 primitive agricultural practices of the people, being largely instrumental in bringing about such serious local food shortages as that which recently caused great hardship in Bohol. J. F. ClEVEnger: Zamia integrifolia Chapm., and its starch, Florida arrowroot. (Illustrated with lantern slides). Zamia integrifolia Chapm. is a small plant with a crown of leaves charac- teristic of the Cycadaceae, to which family this plant belongs. It has an enlarged tuberous-like stem which grows below the level of the ground. It is of interest that numerous prominent root tubercles occur on the roots of this plant. It is restricted to a limited region in the vicinity of Miami, Florida. It has not been found very far south of Miami and not much north of Dania, Florida, nor in regions which are liable to overflow. GifTord reports "that in its raw state the leaves, seed and stems are undoubtedly poisonous." He further states "that animals which drink the red water from washing the starch usually die of slow poisoning." There are no available statements relative to the nature of this poison. The starch has been prepared by the Seminole Indians and natives of South Florida by rather crude mills. The starch thus obtained constitutes an important source of food. For some time there existed in southern Florida two mills of comparatively large capacity, one at Dania and one at Little River. At the present time only the mill at Little River is engaged in the manufacturing of this starch. The method for the preparation of this starch consists in grinding the rhizomes in the undried condition, mixing the ground material thus obtained with water, and subsequently running it over a fine screen. The starch is thus separated from the main portion of the fibrous material. This starchy material is then conveyed to settling tanks where the starch becomes further purified by a sedimentation process. This starch is subsequently dried and readv for the market. It is believed to have been used by the natives who preceded the Seminoles, as a source of food. It supplied the early settlers with food, and to some extent, at least, enters into the arrowroot biscuit of commerce. It is in- teresting to point out that the people frequently dig up these rhizomes, soak them in water, and subsequently use them for fertilizer. The plant has been used as a pot plant, by transplanting. Judging from the rapidly diminishing areas over which this plant grows, the apparent improbability of growing the plant profitably on new areas, and the long periods of waiting before the rhizomes from any given region may be subsequently dug up with profit, it is improbable that the starch will ever have anything more than a limited use. The paper of Mr. Arno Viehoever was postponed to the 152d regular meeting. R. Kent Beattie, Acting Secretary. 476 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 19 SCIENTIFIC NOTES AND NEWS The Section of Vertebrate Paleontology of the U. S. National Museum has recently received as a gift from the John A. Savage Company of Crosby, Minnesota, an extensive collection of bones of an extinct buffalo, named Bison occidentalis some years ago by Dr. F. A. T^ucas. These remains were discovered in Pleistocene deposits which overlie a body of iron ore at the Sagamore Mine near Riverton, Minnesota. It has been comparatively easy to select a complete composite skeleton, which it is proposed to mount for the exhibition collection. Secretary of Agriculture Wallace has appointed a committee of six scientists from the Department to consider the problem of land utilization. The committee consists of Messrs. L. C. Gray of the Office of Farm Manage- ment and Farm Economics, C. V. Piper of the Bureau of Plant Industry, G. M. Rommel of the Bureau of Animal Industry, C. F. Marbut of the Bureau of Soils, E. E- Carter of the Forest Service, and S. H. McCory of the Bureau of Public Roads. The Bureau of Standards announces that in testing a number of imported sets of analytical weights it has been found that the weights from 500 to 50 mg. were made of a decidedly magnetic material. This property caused them to behave very irregularly under test. Such weights can readily be detected with a small hand magnet, and it would be well for purchasers of analytical weights to be on their guard against them, as under some cir- cumstances serious errors might be introduced thereby. Dr. C. G. Abbot of the Astrophysical Observatory sailed from New York on October 26 for Antofagasta, Chile, to inspect the solar radiation station at Mt. Montezuma. He expects to return in January. Dr. L. H. Dudley Buxton, anthropologist, visited the scientific institu- tions of Washington in October, on his way around the world on the Kahn traveling fellowship from Oxford University, England. Dr. ImmanuEL Friedlander, Director of the Volcanological Institute of Naples, visited the Geophysical Laboratory and the U. S. Geological Survey in October. Mr. James E. IvES has resigned as research associate and lecturer in physics at Clark University to become physicist in the office of industrial hygiene and sanitation of the Public Health Service in Washington. Dr. William C. Kendall, scientific assistant and ichthyologist of the U. S. Bureau of Fisheries, has resigned after 33 years of service with the Bureau, to accept the position of ichthyologist in the Roosevelt Wild Life Forest Experiment Station of the New York State College of Forestry, Syracuse, New York. Mr. George M. Rommel, chief of the animal husbandry division of the Bureau of Animal Industry, U. S. Department of Agriculture, has resigned to become editor-in-chief of the American International Publishers, New York City. Mr. Rommel had been with the Departmicnt since 1901, and had been chief of his division since its organization in 1910. Dr. Ralph W. G. Wyckoff, of the Geophysical Laboratory, Carnegie Institution of Washington, is on a year's leave of absence, which he will spend at the California Institute of Technology at Pasadena, California. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 December 4, 1921 No. 20 GEOCHEMISTRY.— iVoi^ on the water of Borax Lake.^ Roger C. Wells, U. S. Geological Survey. Borax Lake is of interest, being the first locality in the United States at which borax was produced commercially. It is a broad, shallow lake, seldom over a few feet deep, situated east of the narrow arm of Clear Lake in Lake County, California. It has been described by J. A. Veatch, J. D. Whitney, G. F. Becker, J. A. Philipps, and others. - Borax was first noted in the water by J. A. Veatch in 1856 and shortly afterwards a bed of borax cr3'stals was found in the mud in the bottom of the lake which was worked for borax by means of mov- able coffer-dams. The water of the lake in September, 1863, contained 41.1 grams of solids to the liter, according to an analysis by G. E- Moore, quoted by Whitney, and of this about 4.8 grams is anhydrous borax. Melville's elaborate analysis published in Becker's monograph on the quicksilver deposits of the Pacific slope shows total solids of about 76.6, of which 5 grams per liter is borax. (This sample was probably collected in 1887.) In August, 1921, Hoyt S. Gale collected a sample of water from the lake and very kindly forwarded it to the writer for study with the suggestion that a comparison of the present borax content with previous determinations would be interesting. The material thus presented was welcomed as being also suitable for the study of the alkalinity and hydrogen ion concentration, the latter being a physical property of alkali lake waters that has not yet been widely studied. The total solids obtained on evaporation and drying at 180° C. amounted to 32.0 grams per liter. The water is therefore now more dilute than the early samples mentioned above. This is perhaps not 1 Published by permission of the Director of the United States Geological Survey. Re- ceived October 21, 192L 2 For references see bibliography by H. S. Gale, U. S. Geol. Survey Mineral Resources, 1913: Pt. II, p. .52.3. 477 478 JOURNAL OF THS WASHINGTON ACADEMY OP SCIENCES VOL. 11, NO. 20 surprising as it is said that in 1861 the lake dried up entirely. The proportions of the principal salts appear to have changed somewhat since 1863 as shown by the following percentages: NaCl NasCOj Na2B407 1863 50 25 12. 1887 53 40 6.6 1921 60 33 7.3 The figures for 1863 give the approximate composition stated by Whitney from Moore's analysis.^ The statement is incomplete and the borax determination is open to question, but may be of the right order. The figures for 1887 and 1921 are calculated from CI, total CO2, and B2O3 and are therefore somewhat arbitrary inasmuch as bicarbonates and metaborates are neglected. The latter are evaluated as shown below. Since 1887 there appears to have been a slight gain in borax and sodium chloride and a loss in sodium carbonate. In the 1921 sample the CI found was 11.6; SO4, 0.05; Ca, 0.06; Mg, 0.07; CO2, 4.90; B2O3, 1.62; K, 0.56 grams per liter. The titration al- kalinity to methyl orange was 0.214 normal. The alkaline character of the water may be expressed through the hydrogen ion concentration as ^^ = 9.75. This measurement was made electrometrically, as described elsewhere.* The water is actually somewhat more alkaline than the Searles lake brine (for which p^ = 9.48) although it is far less concentrated in total salts. This peculiarity is caused by the large salt effect in Searles brine. In order to represent the dissolved alkaline matter in the form of the customary buffer salts, as has been done for Searles brine, ^ an artificial water, containing 18.5 g. sodium chloride, 0.5 g. magnesium chloride, 1.0 g. potassium chloride, and 0.03 g. calcium sulfate per liter was made up as a medium to which buffer salts could be added and the resulting ^^ values determined. A set of p^^ determinations was then made with various proportions of sodium carbonate and bicarbonate, keeping the total CO2 equal to that found in the lake water. Another similar set was made with mixtures of borax and sodium metaborate keeping the total B2O3 the same as found in the lake water. The results are given in table 1 and plotted in figure 1 . 3 Calif. GeoLSurv.l: 98. * Journ. Amer. Chem. Soc. 42: 2160. 1920. For general directions, Clark, The determination of hydrogen ions. ^ Joum. Eng. Chem. 13: 691. 1921. DEC. 4, 1921 WELLS : WATER OE BORAX LAKE 479 The cur\^es shown in the figure are drawn to pass through the observational data and also approximately parallel to the curves for the corresponding buffer mixtures in pure water. ^ The effect TABLE 1 Results of p^ Determinations Made after Adding Carbonate and Borate Buffers TO AN Artificial I/AKE Water. Total C02= 4.26 g. per Liter. Total Bo03 = 1.62 g. PER Liter Percentage of total B2O3 present as Na2B204 ^jj 50 9.42 70 9.74 80 9.95 90 10.27 of the salt in Borax Lake water seems to be about 45 and 75 per cent of that in Searles Lake brine in decreasing the p^ values for the car- 10.8 10.6 Percentage total CO2 present as Na2C03 ^H 20 9.07 50 9.63 75 10.10 95 10.78 10.4 101 T 1Q.0 9.8 9.6 9.^ 9.2 9.0 8.8 / / ^ f i /J / / / i n / A i V ( A / } / y / 20 80 100 ^0 60 Per Cent Fig. 1. pH for mixtures of NaHCOa and Na2C03, and of Na2B407 and Na2B204 in an artificial brine resembling Borax Lake water. Curve 1 : per cent of total CO2 present as Na2C03 (balance NaHCOs). Curve 2: per cent total B2O3 present as Na2B204 (balance Na2B407) . 8 Data given in Prideaux, The theory and use oj indicators, pp. 279 and 299. 480 JOURNAL OF THE WASHINGTON ACADKMY OF SCIENCES VOL. 11, NO. 20 bonate and borate buffers, respectively. The addition of salt makes the buffer solutions more acid. Until more measurements on the salt effect are obtained each case must be studied by itself, although it is evident that the salt effect increases only slowly with increasing concentrations of salt. From the curves it is easily seen that in order to yield the value pji = 9.75 the CO2 and B2O3 should be distributed as follows in the respective salts: CO2 57 per cent as NaoCOs 43 per cent as NaHCOs or, as grams per liter: NaaCOs 5.9 NaHCOs 3.5 B2O3 C7] (2c 71 per cent as Na2B204 29 per cent as Na2B407 Na2B204 2.17 Na2B407 .68 It is concluded that the proportions last given approximately represent the concentrations of the salts that determine the alkalinity of the water of Borax Lake. One factor that is not allowed for is the salt effect of the carbonate buffers on the borate buffers, and vice versa, but this effect is probably small compared with the salt effect of the sodium chloride present which has been allowed for. By a strange coincidence the percentage of total B0O3 present as borax is the same as that found for vSearles Lake, but the percentage of CO2 present as carbonate is 57, compared with 78 for Searles Lake. Below (Table 2) is given a statement of the analysis deduced from the present investigation, in the form of gram ions per liter, with a similar one of Searles Lake brine for comparison. The minor constituents noted by Melville were not determined. TABLE 2 Analyses Deduced from the Present Investigation in the Form ok Gram Ions per Liter Borax Lake Searles Lake Ca .06 Mg .07 Na (diff.) 11.42 143.7 K .56 31.9 CI 11.60 159.2 vS04 .05 61.0 HCO3 2.54 7.2 CO3 3.34 25.4 B4O7 .52 4.3 Bj04 1.42 11.8 31.58 444.5 DEC. 4, 1921 WASHINGTON : OBSIDIAN FROM COPAN 481 Borax cr^^stals remain in the mud of Borax Lake although the water is not now saturated with borax. It is not unusual to find certain crystallized salts in the bottom mud of a lake containing water that is not saturated with those salts. Water from the bottom mud and lower is also frequently more concentrated than the lake water. Such relations have been noted in the Wyoming lakes carrying sodium sulfate, in the Nebraska lakes carrying potassium salts, and in the Great Salt Lake, where Glauber's salt has been found below sand and clay. The explanation probably is that in the coldest or driest weather crystals are deposited and fall to the bottom where they be- come covered with silt and clay. The reverse process of solution, being chiefly dependent on diffusion, is too slow to occur in the alter- nate warm or wet seasons or even in several such seasons. Certain salt deposits may therefore owe their origin in some cases to extreme or unusual conditions rather than to average conditions, provided they become silted over. PETROLOGY. — Obsidian from Copan and Chicken Itza} Henry S. Washington, Geophysical Laboratory, Carnegie Institution of Washington. OBSIDIAN FROM COPAN In 1920, during his study of the Maya ruins at Copan, Honduras, Dr. Sylvanus G. Morley obtained a number of obsidian cores, that is, the remnants of rock nodules from which knives and other implements had been flaked off by the ancient Maya. Dr. Morley very kindly gave these cores to me for examination, a courtesy for which I would express mv thanks. It appears that many such cores are found by the natives among the ruins and along the valley floor, and that nodules of ob- sidian are said to occur in the tuffs of the neighborhood. As such cores, valueless in Copan, would scarcely be articles of trade, it may be safely assumed that the obsidian of those studied comes from the vicinity of Copan. Little is known of the volcanic rocks of Central America. Obsidian, dacite, andesite, and basalt are mentioned and described briefly by the few petrologists who have dealt with the subject, but (except for the rocks of Panama and the Canal Zone) there are only five analyses of Central Am.erican rocks, and only one of these is of an obsidian. The cores are from 10 to 13 cm. long, and from 2.5 to 3 cm. at the greatest thickness. They are roughly spindle-shaped (Fig. 1), with the greatest width near the middle in some of them, but near one end in 1 Received November 4, 1921. 482 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCFS VOL. 11, NO. 20 others. The ends are not sharply pointed, but are broken cleanly across. The cores are bounded laterally by 8 to 10 curved, narrow faces, produced by the perfect conchoidal fracture of the material, and nearly all these faces extend the whole length of the core. These narrow faces are slightly concave across their width. The obsidian is of a uniform, jet-black color, perfectly vitreous, and with perfect conchoidal fracture. There are no streaks, and no phenocrysts are visible. In splinters the glass is brownish and very transparent. The thin section shows a clear colorless glass, homo- geneous and with little or no evidence of flow. There are no bubbles but some very minute microlites are scattered sparsely through the glass; the larger (0.01 mm.) being irregular crystal fragments of pyroxene, and the smaller (0.001 mm.) opaque grains of magnetite. Their total percentage cannot amount to more than about 0.01 of the rock. -^ - -^-> -^^~L rjy)>) 0 ) IfJJj pyfpTj^'J '■)'jV Jr I I ; Fig. 1. Obsidian Cores from Copan. Dr. H. B. Merwin very kindly determined the refractive indices, these being measured on a specially ground prism. They are as follows: «c = 1.4896, 71d = 1.4920, tip = 1.4976, and Wg'= 1.5022. It will be seen that the value for yellow light (D) is slightly higher than the indices (determined by Merwin) of the obsidians of I^ipari (Rocche Rosse = 1.488-9, Forgia Vecchia = 1.490), Monte Arci (1.487-9), and Milos (1.490).- The first three have about the same percentage of silica as the Copan obsidian, but are slightly more potassic and with less lime; while that of Monte Arci is higher in silica by about 2 per cent, with a little less soda, but about the same 2 H. S. Washington. Amer. Journ. Sci. 50: 462. 1920. DEC. 4, 1921 WASHINGTON : OBSIDIAN FROM COPAN 483 percentages of potash and lime. These observ^ations are in conformity with the general rule, that silica and alkalies tend to lower, and lime tends to raise, the refractive indices of obsidians. The specific gravity, determined with the balance on a piece weigh- ing about 31 grams, is 2.372 at 23.2 °C., giving a density of 2.366. SiOo... AI2O3. . FeaOs. . FeO... MgO.. CaO... NaoO.. K2O... H2O+. H0O-. Ti02.. P2O3... MnO. . TABLE 1 Analyses of 0 (1) 74 .46 BSIDIAN (2) 76.68 14.49 n.d 1.09 0.84 1.53 3.92 1.20 0.36 n.d. n.d. trace (3) 75.23 12.36 0.96 1.24 0.01 1.00 4.0» 4.62 0.73 n.d. 0.27 n.d. (4) 75.64 13.13 12.68 0.49 1.07 1 .03 n.d 0.29 trace 1.25 0.83 4.52 4.98 4.37 3.51 0.10 1 0.03 J 1.58 0.45 n.d. 0.09 n.d. 0.05 n.d. 100.26 100.11 100.42 100.29 (1) Obsidian, Copan, Honduras. Washington analyst. (2) Obsidian, Corinto, Nicaragua. J. PETERSEN analyst. J. PETERSEN. Neues Jahrb. 1898: II, 157. (3) Obsidian, Cerro de los Navajos, Mexico. F. Baerwald analyst. C. A. TennE. Zeitschr. deutsch. geol. Ges. 37: 616. 1885. (4) Obsidian, Cerro de los Navajos, Mexico. F. Baerwald analyst. C. A. Tenne. Loc. cit. Chemical analysis gave the results shown in No. 1 of table 1, analyses of obsidians from Nicaragua and Mexico being given for comparison. In chemical composition the Copan obsidian closely resembles many others from widely separated localities, as may be seen by reference to U. S. Geological Sur\^ey, Professional Paper 99, pages 113 to 151. Its norm is as follows, represented by the symbol 1.4. 1 (2). 3(4). Quartz 28.86 Orthoclase 26 . 13 Albite 38.25 Anorthite 2.22 Diopside 2.75 Magnetite 0 . 70 Ilmenite 0.91 Apatite 0.30 The Corinto (Nicaragua) obsidian, which is the only other Central American obsidian of which we have an analysis, is higher in silica and with lower alkalies, the soda greatly dominating over potash. One of the analyses of the Mexican obsidian is like that of Copan, but none of the analyses cited can be regarded as quite satisfactory. 484 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 It is probable, however, that the Copan obsidian is much like the general run of Central American and Mexican obsidians, if we may judge from analogy with similar regions in the western United States and along the Andes, a comagmatic zone to which the volcanic rocks of Mexico and Central America belong. OBSIDIAN FROM CHICHEN ITZA Among a large accumulation of sacrificial offerings (mostly of jade) found some years ago in a cenote, or natural well, at the ancient Maya city of Chichen Itza in Yucatan,'^ were a few beads of obsidian. The beads are cylindrical, from 2 to 5 cm. long and about 5 mm, thick, with a shallow groove running spirally around them from end to end. The smooth but unpolished surface is brownish black, with irregular streaks of scarlet, which appear to be painted or burnt into the surface, as the color does not extend into the material below. They are apparently intended to simulate similarly mottled obsidians, which are fairly common, but discussion of this question of technique will be taken up elsewhere. The obsidian is of a somewhat peculiar hair-brown color, quite different from the more usual brown of the Copan obsidian, but is colorless in thin section. It contains some bubbles, which vary in length from 0.02 to 0. 10 mm. These are mostly spindle- or pear-shaped, the former frequently with one end drawn out to a sharp point. The bubbles are arranged in streaks, evidence of flow texture. Apart from these bubbles, the glass is perfectly clear and contains no mi- crolites or phenocrysts. Dr. Merwin determined the refractive index of this obsidian by the immersion method, and I would express my thanks to him for his kindness in making this and the other determinations on the Copan obsidian. He found the value Wd = 1.489 ±0.001. This is notably lower than the refractive index of the Copan obsidian, but is about the same as the indices for the Lipari and Milos obsidians. It is in accord with the rather high silica and alkalies and low lime and alumina. The density was not determined, because the small amount of material available and the presence of the bubbles would have made the determination of little value. ^ This collection, now in the Peabody Museum in Cambridge, Massachusetts, is to be described under the editorship of Prof. A. M. TozzER, to whom I am much indebted for the privilege of studying the stone objects and publishing the present description, which deals only with the petrological aspects of the obsidian. DEC, 4, 1921 WASHINGTON: OBSIDIAN FROM COPAN 485 TABLE 2 Analyses of PantellErite Obsidian and Cognate Rocks (1) (2) (3) (4) SiOa 75.88 72.21 70.14 74.09 AI0O3 9.67 9.72 8.61 10.88 FeoOs 2.23 3.26 6.01 3.35 FeO 0.83 1.07 2.73 0.42 MgO 0.21 0.29 0.20 0.30 CaO 0.72 0.82 0.45 0.16 Na.0 5.13 4.42 5.44 4.56 K2O 4.56 4.98 4.20 4.45 H2O + ] f 1-96 0.35] [ 0.38 ^ \ 1.52 HoO- J ^ 0.24 0.17 J TiOo 0.10 0.62 0.86 n.d. Zr02 n.d. n.d. 0.14 n.d. P2O5 n.d. 0.10 0.12 n.d. SO3 n.d. n.d. 0.06 n.d. MnO trace 0.05 0.38 n.d. 99.71 99.74 99.86 99.73 (1) Obsidian bead, Chichen Itza, Yucatan. Washington analyst. (2) Comendite, Cuddia Nera, Pantelleria. Washington analyst. H. S. Washington. Jour. Geol. 21: 697. 1913. (3)JPantellerite, Monte San Elmo, Pantelleria. Washington analyst. H. S. Wash- ington. Op. cit., p. 703. (4) Comendite, San Pietro, Sardinia. A. Johnsen analyst. A.Johnsen. Abh. preuss. Akad. Wiss. 1912: 22. A chemical analysis, incomplete because of paucity of material, gave the results shown in No. 1 of table 2. In the figures for silica, magnesia, and the alkalies, it is much like the analysis of the Copan and other common obsidians, but is somewhat lower in lime and ti- tanium. In its low alumina and rather high ferric oxide (especially as compared with ferrous oxide), however, it differs widely from most obsidians, and shows close analogies with the more silicic pantellerites and comendites, as may be seen by comparison with the other analyses given in the table. The alumina is, indeed, so low that there is a notable excess of soda and potash over the total amounts of alumina and ferric oxide, so that the norm contains, not only considerable acmite, but some of the sodium metasilicate molecule. The close analog)^ of the Chichen Itza obsidian with the peculiar rocks of the Italian volcanoes will be evident, and the obsidian may properly be called a hyalo-pantellerite, the glass of which is also brown. The occurrence of such a lava within the area from which the votive offerings may be supposed to have come is an unexpected one. Lavas 486 JOURNAL OF THE WASHINGTON ACADEMY OE SCIENCES VOL. 11, NO. 20 TABLE 3 Norms of Pantellerite Obsidian and Cognate Rocks (1) (2) (3) (4) Quartz 35.34 31.14 27.60 31.32 Orthoclase 27.24 29.47 25.02 26.69 Albite 24 .10 22 .01 20 .44 30 .92 Acmite 6.47 9.24 17.56 6.93 Sodium metasilicate... 2.68 1.10 1.34 none Diopside 3.10 2.57 1.21 0.65 Hypersthene 0.23 0.46 4.10 0.50 Magnetite none none none 1 .39 Ilmenite 0.15 1 .22 1 .67 none Apatite none 0.34 0.34 none (1) Obsidian, Chichen Itza. (I) II. 3".1.3. (2) Comendite, Pantelleria. (I) II. (3) 4.1.3. (3) Pantellerite, Pantelleria. II. 3(4). 1.3. (4) Comendite, Sardinia. I (II). (3) 4.1.3. of these types are rather rare and are invariably connected with characteristically sodic comagmatic regions. We know of no such sodic region in or near Central America or in southern Mexico, the nearest being the locality of nephelite syenite, in the State of Tam- aulipas,^ in northeastern Mexico. The lavas here, however, are apparently dacite, andesite, and basalt, Finlay mentioning no highly sodic lavas, such as phonolite or pantellerite. There are occurrences of pantellerite and other sodic lavas in western Texas, and I have pointed out elsewhere the probable existence of a zone of sporadic occurrences of sodic rocks along the eastern border of the North American continent, and that it probably continues down along the east coast of South America. As has been said above, we know very little of the volcanic rocks of Central America, or of Mexico, for that matter, so it is quite possible that another isolated district of sodic rocks occurs in southern Mexico or northern Central America. The finding of these beads made of pantellerite obsidian in the Chichen Itza cenote gives warrant for this belief, which is further strengthened by the abundance of jade objects found in this general region, the material of which may be considered of Mexican or Central American provenance. It would seem to be clear, from the descriptions above, that the Chichen Itza obsidian is derived from a volcanic source quite distinct and, we may reasonably suppose, far distant from that of the Copan cores. The occurrence of two such widely different obsidians, one of which belongs to a chemically very peculiar kind of rock, serves * G. I. Finlay. Ann. N. Y. Acad. Sci. 14: 247. 1904. DEC. 4, 1921 CAUDELi^: the phaneropterae 487 to emphasize the desirability, for archaeological as well as for petro- logical reasons, of a better knowledge of the volcanic rocks of Central Arnerica and Mexico. ENTOMOLOGY. — On the Orthopterous group Phaneropterae ( = Scudderiae) , with descriptions oj a new genus and species.^ A. N. CaudelIv, Bureau of Entomology. The genus Phaneroptera was erected by Serville in 1831,- with two originally included species, Locusta lilifolia Fabr., and Locusta curvi- cauda DeGeer. The only designation of genotype for this genus, so far as now known to the writer, was by Kirby in 1906,^ when the Gryllus falcatus of Poda was so indicated. In his treatment of this matter Kirby followed Brunner in considering the Locusta lilifolia included by Serville as being a misdetermination, the real species being presumably the Gryllus falcatus of Poda. But, when an author names a particular species as originally included in a genus that species is presumed to be correctly determined, the sane and only rational reasoning applying, it seems, as in the case of genera based wholly on a misdetermined species, and covered by opinion No. 65 of the Inter- national Code of Nomenclature and by paragraph No. 96 of the Entomological Code. Thus the Fabrician lilifolia included by Serville in his genus is not to be considered a misidentification, and is eligible for genotype citation. The designation by Kirby of the non-included species falcatus being invalid the genus Phaneroptera is therefore as yet without a designated genotype, and one of the two originally included species, lilifolia and curvicauda, must be selected as the type. The first of these species, Locusta lilifolia Fabr., is the genotype of the monobasic genus Tylopsis of Fieber, 1858. The second species, Locusta curvicauda DeGeer, is the type of the genus Scudderia of Stal 1873, by original definite designation and by virtue of being the sole species of that monobasic genus. Now paragraph 98a and 101 of the Entomological Code and opinion 6 of the International Code re- strict one to the selection of curvicauda as genotype, which I here- by do by definitely designating Locusta curvicauda DeGeer as the genotype of the genus Phaneroptera of Serville. This selection, being in accord with both recent codes governing such matters, can scarcely fail to meet with the approval of most nomenclatorialists. ^ Received October 21, 1921. 2 Ann. Sci. Nat. 22: 158. 3 Syn. Cat. Orth. 2:'434. 488 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 From the above it is clear that Stal's genus Scudderia must fall as a synonym of Phaneroptera Serville, having the same genotype and being more recent by almost two decades. This leaves the species listed under Phaneroptera by Kirby* (except attenuata Walk., marginalis Brunn., and annulata Brunn., as noted below) without valid generic assignment. For these species and grandis, nakoensis and tympanalis M. &. S., I propose the new generic name Anerota, with Gryllus falcatus Poda as the designated genotype. The synonymy is as follows: Anerota Caudell, nom. nov. Phaneroptera Brunner (not Serville), Monogr. Phaneropt. 23, 209. 1878. Phaneroptera Kirby (not Serville), Syn. Cat. Orth. 2: 424. 1906. The writer sincerely regrets these changes, the sinking of an old and well-known American genus and the introduction of a new generic name to replace an older one. However, such acts, being based on sound nomenclatorial grounds, are necessary if we attempt to comply with codified rules. And, as therein lies our only hope for an ulti- mately stable nomenclature, the sooner such changes are wrought the better. The type of Phaneroptera attenuata Walker is in the British Museum, where it was studied by the writer in 1913. It is a female in poor condition, the abdomen being missing and the rest of the insect glued on a card. Most of the parts used in classification were, however, well preserved and prove that the species was wrongly placed by Walker and Kirby. It has conchate foramina and belongs to the genus Tylopsis, where it is a synonym of the older species T. hilin- eolata Serville. Phaneroptera marginalis Brunn. was described from an imperfect female, the anterior and intermediate legs being wanting. Kirby assumed the character of the missing parts to be the same as in Walker's attenuata and so synonymized it under that species. It seems probable that in this Kirby was correct, and the synonymy is as follows : Tylopsis bilineolaris Serville, Orth., p. 419. 1839. Phaneroptera attenuata Walker, Cat. Derm. Salt. Brit. Mus. 2:338. 1869. -Phaneroptera marginalis Brunner, Monogr. Phaneropt. 210, 214. 1878. ♦ Syn. Cat. Orth. 2: 4-34-437 and 3: 574. DEC. 4, 1921 caudell: the phaneropterae 489 Phaneroptera annulata Brunn. has been made the type of the genus Xenodoxus of Carl, described in 1914, thus eliminating it from other generic assignment. Inscudderia, genus nov. This is a member of the group Phaneropterae (= Scudderiae), but tends towards the Insarae, standing between the genera Phaneroptera (= Scudderia) and Insara, hence the generic name Inscudderia. Superficially it resembles Insara, especially I. elegans, but structurally it seems more like Phaneroptera, though in this respect also it tends towards the Insarae, especially in the narrow tegmina with their slightly concave caudal margins, two or more branched radial sectors and variegated color, and the longer and more slender legs. The greatly prolonged and non-style bearing subgenital plate of the male, the fastigium of the vertex failing to meet that of the face, the slightly spinose genicular lobes and the non-sellate pronotum exclude it from the Insarae. In the group Phaneropterae (= Scudderiae) this genus runs out in Brunner's keys, Monogr. Phaneropt., to Scudderia on page 16 except that the fore and middle femora are slightly toothed ventrally, which is also often true of the anterior femora of Scudderia, or Phaneroptera, as we have above shown this American genus must now be called. But there are various characters for the ready sepa- ration of this new genus from that older one, the more prominent ones being the twice or more branched radial sector, the more slender and posteriorly slightly concave tegmina, the comparatively longer and more slender legs, the more rounded lateral carinae of the pronotum with the posteriorly flattened disk of the same, the ventrally subspinose intermediate femora and the more decidely armed ventral margins of the posterior femora. Description. — (o^, the ? unknown). Head with the fastigium of the vertex very narrow, not exceeding a fourth the width of the basal segment of the antenna, subhorizontal and failing to meet the frontal fastigium, the presenting face rounded; eyes almost round, prominent. Pronotum rounding into the lateral lobes without distinct lateral carinae except in the posterior fourth, where the disk, which is other- wise gently convex, is wholly and conspicuously flattened, and there the lateral carinae are sharp and distinct; lateral lobes about equally high as long, the humeral notch deep. 'Organs of flight fully developed ; wings hyaline with the tips, which project beyond the closed tegmina a distance approximately equal 490 JOURNAL OF THE WASHINGTON ACADEMY OE SCIENCES VOL. 11, NO. 20 to the pronotal length, green, especially in the costal area where it is coriaceous like the tegmina; tegmina narrow, slightly over five times as long as broad, at the widest point being very slightly broader than the pronotal length, the posterior margin barely concave; first radial branch two or three forked and joined near the base to the ulnar vein by a diagonal cross vein. Legs slender, the posterior femora just reaching the tips of the closed tegmina; spine of anterior coxa long and sharp; anterior tibiae with open foramen on each face; all the tibiae sulcate dorsally and armed on both ventral margins with several black spines of moderate size; above the intermediate and posterior tibiae also bear sharp black spines on both margins, only one to three on the cephalic margin of the middle ones, and on that margin there is no apical spine, as there is on the opposite margin and on both margins of the hind tibiae; anterior tibiae wholly unarmed on the dorso-cephalic margin, the opposite margin with a basal spine (often very small) near the lower margin of the foramen, a terminal spine and from one to three additional ones at irregular intervals between the above; posterior femora armed beneath on both margins with several black triangular teeth, the fore and middle ones with from none to two very minute teeth on the caudal margin beneath and the anterior ones may have one or two exceedingly minute teeth on the ventro-cephalic margin; posterior genicular lobes very briefly but acutely pointed, the others rounded. Abdomen with the segments evenly truncate except the terminal one, which is slightly prolonged and apically broadly notched, as shown in figure 1, c; subgenital plate greatly prolonged and up- curved, as in Phaneroptera (= Scudderia), without apical styles but the latero-apical angles roundly tubercular, the apex notched; supraanal plate elongate-triangular, deeply concave above; cerci heavy, about twice as long as the last dorsal segment of the abdomen, subcylindrical, tapering moderately to about the middle and then again growing stouter to the noticeably swollen apex, where there is a heavy, sharply pointed and inwardly directed tooth about a third as long as the body of the cercus. (See fig. 1, b and c.) Type Inscudderia taxodii, sp. nov. Inscudderia taxodii, sp. nov. This is undoubtedly one of the most distinct species of Orthoptera, and that such a striking katydid inhabiting the southeastern United States should so long escape notice is indeed remarkable. DEC. 4, 1921 caudell: the phaneropterae 491 (\ \ Fig. 1. a, Left tegmen of type; b, end of abdomen, lateral view; c, end of abdomen, dorsal view. Figures by Dr. A. Bowing. 492 JOURNAL OF the; WASHINGTON ACADEMY OP SCIENCES VOL. 11, NO. 20 Description. — (cf, the 9 unknown). Head slightly broader than the pronotum; labial palpi slender, the terminal segment cylindrical, slightly and gradually thickening apically, the tip truncate, the whole three times as long as the preceding one, which in turn is about one- half as long as the penultimate segment; eyes yellowish brown, the rest of the head yellowish green, the slender antennae being darker green with some very narrow black bands scattered along the length. Pronotum green with a narrow longitudinal mesial stripe on the disk and with the cites of the lateral carinae somewhat lighter; pronotal disk truncate anteriorly, posteriorly broadly and uniformly rounded; lateral lobes with the humeral sinus rounded and margined with black, the callous large but indistinct ; there is a small black splotch anterior of the center of each lateral lobe and there are two small transverse black spots on the posterior margin of the pronotal disk, the mesial longitudinal stripe separating them. Legs as noted in generic descrip- tion, the posterior femora shaped as in Insara; foramina of fore tibiae shining black. Wings slender, over twice as long as broad, the posterior apical margin evenly curved, the membrane transparent with green venation, the apex green and thickened as noted in the generic diagnosis. Tegmina green with the radius, the anal vein, which continues to near the tip of the tegmina, and the heavier of the stridulating veins of the singing area piceous and a series of several conspicuous short, pointed, diagonal, basally directed piceous streaks extending from the posterior margin, following the veins as shown in fig.l, a; these black veins and diagonal markings show very conspicuous- ly against the greent egmina, imparting to them a very characteristic appearance. Abdomen moderately heavy; last dorsal segment about twice as long as the preceding one and apically very broadly notched and laterally concave, the lateral angles thus formed appearing as rounded tubercular-like protuberances, as shown in figure l,c, supraanal plate twice as long as the basal width, the sides straight and tapering to a narrowly rounded apex, the entire dorsal surface deeply concave ; subgenital plate very like that of Phaneroptera (= Sctidderia), being a narrow elongate, upcurved flattened plate with conspicuously thick- ened margins, concave above, convex beneath and the apex triangularly notched, the terminal lateral lobes rounded and about as long as thick, but scarcely at all style-like; cerci characteristic in shape, as shown in the accompanying figure, figure. 1. The immature form shows little essential difference from the adult except that the colors show evidence of the same brilliantly hued DEC. 4, 1921 caudeIvL: the phaneropterae 493 variegation as exhibited by some of our species of Phaneroptera, though the second segment of the antenna does not show such con- spicuous enlargement as is present in the young of some species of the latter genus. The legs are dotted with black and the posterior femora have some larger black markings on the upper surface and on the outer face; the abdomen is ornamented with numerous short narrow red dashes, the lateral lobes of the pronotum are centrally reddish with yellowish lower margin and with some black markings. The pronotal disk of the nymphs, at least the only two examined, does not show the absolute flattening of the posterior fourth as is so conspicuously true of the adult form. Measurements of adult. — Length, pronotum, 4 mm. ; tegmina, 21 mm.; posterior femora, 20 mm. Width, tegmina at widest point, 4 mm. ; pronotum across the posterior flattened portion, 2.3 mm. Type, d', Durant, Miss., July 15, 1921. C. J. Drake, collector; paratypes, one adult cf and two immature d'd', one nearly full grown and one about half grown, Pickens, Miss., July 16, 1921, taken by the same collector. Type and paratypes in collection of the United States National Museum. Catalog No. 24952, U. S. N. M. In addition to the above four specimens Prof. Drake distinctly recalls having seen specimens, adults and nymphs, at the following localities in Mississippi: Fulton, Columbus, Vicksburg, Natchez and Port Gibson. Not realizing their interest and importance he un- fortunately kept but the above described specimens, though many, he says, might easily have been secured. Prof. Drake, who is to be congratulated on the discovery of this unusually interesting addition to our native orthopterous fauna, found this beautiful little katydid to occur quite common on cypress, where he often took them while beating the foliage of that tree for Hemiptera. He also on one occasion swept a few adults from weeds and grass in the immediate vicinity of cypress. The adults aroused his interest by the nicety with which their colors blended with those of the host plant. 494 JOURNAL OF THS WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are fonvarded promptly to the editors. The abstracts should conform in length and general style to those appearing in this issue. GEOI^OGY. — Contact-metam Orphic tungsten deposits of the United States. Frank L. Hess and Esper S. Larsen. U. S. Geol. Surv. Bull. 725-D. Pp. 65(245-309). 1921. Contact-metamorphic tungsten deposits have been formed through the combined action of the heat and solutions emanating from a cooling intrusive granitic magma on limestones and the other intruded rocks and to a less extent on the invading granitic rock itself, by which the rocks are altered to or replaced by an aggregate of garnet, epidote, diopside, quartz, calcite, scheelite, and other minerals. Most deposits of this class are at or very near the contacts, and they clearh^ represent replacement of the limestones and other rocks. The tungsten mineral of such deposits is invariably scheelite. Most of the known contact-metamorphic tungsten deposits in the United vStates are in the Great Basin region in California and Nevada and north- western Utah, but Oregon, Arizona, and New Mexico are known to contain one deposit each, arid it is probable that other such deposits will be found in widely different parts of the country. The geologic features of contact-metamorphic deposits and the causes of metamorphism are discussed. Most of the paper is made up of a brief pre- liminary description of the contact-metamorphic scheelite deposits in the western United States. R. W. StonE- GEOLOGY.- — Chrome ores in Pennsylvania, Maryland and North Carolina. Eleanora Bliss Knopf and J. Volney Lewis. U.S. Geol. vSurv. Bull. 725-B. Pp. 55 (85-139). 1921. Chrome ore was discovered in Maryland as early as 1827. Until 1860 Maryland and Pennsylvania furnished the world's supply of chrome ore, but in 1860 the chief source of the world's supply was transferred to Turkey. Since 1882 practically all of the output of chrome ore in the United States has come from the Pacific coast, and the industry in the Eastern States has lain dormant. The chromite is found in rock ore and in alluvial sand. The rock ore is both massive and granular. It occurs in serpentinized pyroxenites and peridotites that probably represent ultrafemic differentiates of a gabbro in- trusion. The massive ore occurs in pockets of variable size. The ore occurs at intervals in a belt 50 miles long that extends from the southwest corner of Chester County, Pa., to the neighborhood of Baltimore, Md. It has probably originated by the sinking of chromite grains during the crystalli- zation of a highly magnesian magma. The chrome ores of North Carolina occur in granular olivine rocks (peri- dotites), which form numerous small isolated outcrops in a belt 5 to 25 miles wide throughout the mountainous western part of the State, a distance of 200 miles. DEC. 4, 1921 ABSTR.\CTS: ORNITHOLOGY 495 This report describes the character of the rocks and their hydration and decomposition products, also the character and classification of the chrome ores and the nature of the gangue minerals. The chrome ores are believed to have been formed by the local concen- tration of suspended grains and crystals of chromite during the cooling of the molten peridotite magma after its intrusion into the gneisses. Con- vectional circulation was probably the chief agent in the process. The chance of large bodies of deeper-seated ore having been formed at the same time is thought to be very small. R. W. Stone. BIOLOGY. — A new classification of animals. Austin H. Clark. Bulle- tin de rinstitut Oceanographique (Monaco), No. 400, pp. 1-24. 20 September, 1921. This paper is an amplification of the short note on the steps in the evolution of animals published in this Journal,^ and also includes a consideration of the corresponding steps in the evolution of plants. A key is given to all of the animal phyla, in which the larger plant groups are also included, and finally there is a list of the ph3da and higher groups accepted by the author. Several of the higher groups and one of the phyla (Calyssozoa) are here proposed for the first time. ' A. H. C. ENTOMOLOGY.— Z^w^^z-^/oM of flies by flight. F. C. Bishopp and E. W. Laake. Journ. Agric. Res. 221: 729-766. 1921. This paper discusses the dispersion of flies by flight and experiments listed and described show that under rural and urban conditions many species of flies have marked powers of diffusion. The house fly spread a maximum distance of 13.14 miles from the point of release. It is noted that the species tested often pass feeding and breeding grounds and from the experiments there are certain facts which indicate that they have marked migratory habits. The relation of the direction of dispersion and the direction of the winds is discussed and it is stated that no correlation could be determined because when the experiments were conducted. the wind conditions were considered as choppy. The evidence gained by the experiments justifies the conclusion that passing vehicles on highways are not a dominating factor in the dispersion of the flies used. There is no marked difference between the dispersion of males and females. The facility with which flies travel many miles empha- sizes the importance of the general application of sanitary measures looking toward the suppression of fly breeding. S. A. RohwER. ORNITHOLOGY. — A new ptarmigan from Mount Rainier. W. P. Taylor. Condor 22: 146-152. 1920. A new ptarmigan from Mount Rainier is here named Lagopus leucurus rainierensis. Harry C. Oberholser. ORNITHOLOGY.— TFa/^r/owZ in Nebraska. H. C. Oberholser. Bull. U. S. Dept. Agric. 794: 2-35. 1920. The principal waterfowl breeding ground in Nebraska is the sandhill region, which occupies the middle portion of the State. The most important groups of lakes are those of eastern Cherry County, Brown County, Garden and Morrill Counties, and those at the head of the North Loup River. All these 1 This Journal 11: 207-208. IMay 4, 1921. 496 JOURNAL OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 lakes are relatively small and shallow, and many are more or less ephemeral. The water in most is fresh, biit in a few is alkaline. Notes on habits, occurrence, and distribution of 56 species of water birds are here given, 42 of which are breeding species of the State, and 14 are only autumn transients. The most abundant breeding duck is Querquedula discors. H. C. O. ORNITHOLOGY. — Observations on the habits of the white-winged dove. Alexander Wetmore. Condor 22: 140-146. 1920. The habits of Melopelia asiatica mearnsi as observed near Arlington, along the Gila River in Maricopa County, Arizona, present some interesting fea- tures. The species were found breeding in colonies, some of them as large as 2000 pairs. The young are fed by regurgitation for three or four days, after which they are given fresh food. They remain in the nest three or four weeks. A regular morning flight from the breeding colonies begins an hour after sunrise and continues until nearly noon of each day. The species feeds much on wheat and barley, but as most of this is waste grain, the damage to the cultivated crops of the region is comparatively slight. H. C. O. ORNITHOLOGY. — Observations on the habits of birds at Lake Burford, New Mexico. Alexander WetmorE. Auk 37: 221-247. 393-412, pis. 1-7. 1920. Lake Burford lies at an altitude of 7000 feet in the northwestern part of New Mexico. The observations here recorded relate to 105 species, and include sometimes extended notes on habits, particularly of the water birds. H. C. Oberholser. ORNITHOLOGY. — A peculiar feeding habit of grebes. Alexander Wet- more. Condor 22: 18-20. 1920.' The stomachs of grebes usually contain a considerable quantity of feathers. These are eaten by the birds during the process of preening. Although these feathers are eventually ground up and enter the intestines, a plug of them remains in the pyloric lobe of the stomach, apparently serving as a strainer to prevent the passage of the more indigestible parts of food eaten. H. C. Oberholser. ORNITHOLOGY. — A new clifj swallow from Canada. H. C. Oberholser. Canadian Field-Nat. 33: 95. 1920. The form of Petrochelidon albifrons inhabiting most of western Canada is here described as Petrochelidon albifrons hypopolia. It is the largest of the races of Petrochelidon albifrons, and inhabits northwestern North America, from Mackenzie and Alaska, south to Montana and Alberta, migrating through the western United States probably to South America. H. C. O. ORNITHOLOGY. — Description of a new clapper rail from Florida. H. C. Oberholser. Proc. Biol. Soc. Wash. 33: 33-34. 1920. A clapper rail from the Florida Keys is described as Rallus longirostris helius. H. C. O. ORNITHOLOGY. — The migration of North American birds. XIII. Euro- pean Starling and the Bobolink. H. C. Oberholser. Bird Lore 22: 213-216. 1920. The European Starling (Stiirinis vidgaris vidgaris), was introduced into the DEC. 4, 1921 proceedings: philosophical society 497 United States about 1890. Since that time it has spread into Maine, central New York, Pennsylvania, West Virginia, and southeastern Virginia, where it now breeds. It has wandered also to Ohio, Alabama, and Georgia, and probably will continue to spread into suitable areas in the eastern United States. The well-known BoboHnk {Dolichonyx oryzivorus), breeding in North America, migrates to winter in Bolivia and Argentina. Tables of dates of its spring and fall migration are here given. H. C. O. ORNITHOLOGY. — A synopsis of the races of the Guiana flycatcher, Myiarchus ferox (Gmelin). H. C. Oberholser. Proc. Indiana Acad. Sci. 1918: 304-308. 1920. Eight subspecies of this bird are here recognized, one of which has not heretofore been regarded as distinct. H. C. O. ORNITHOLOGY. — -Description of a new Otocoris from California. H. C. Oberholser. Condor 22: 34-35. 1920. The breeding horned lark of the northern Sierra Nevada in California is here named Octocoris alpestris sierrae. H. C. O. ORNITHOLOGY. — Fifth annual list of proposed changes in the A. 0. U. check-list of North American birds. H. C. Oberholser. Auk 37: 274- 285. 1920. This list includes the changes in nomenclature and status of North American birds proposed during the calendar year 1919. It comprises the addition of 7 genera, 8 species, and 16 subspecies; together with 67 changes in generic, subgeneric, specific, and subspecific terms, involving altogether 90 names. Furthermore, there are 14 eliminations from the North American list as now understood, these consisting of 7 genera, 1 species, and 6 subspecies. H. C. O. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PHILOSOPHICAL SOCIETY 853d meeting The 853d meeting of the Philosophical vSociety of Washington was held in the Assembly Hall of the Cosmos Club October 8, 1921. It was called to order by President F.\ris with 44 persons present. The first paper of the evening, on A furnace temperature regulator, was pre- sented by Mr. H. S. Roberts, 3d, and was illustrated. It was discussed by Messrs. Pawling, White, L. H. Adams, and others. This paper was a description of a thermo-regulator for use with electric resistance furnaces and an account of its operation. The apparatus is a modification of the regulator described by White and Adams in 1919, in which the heating coil of the furnace is placed in one arm of a Wheatstone bridge and the supply of energy to the furnace varied in a single step by means of a switch operated by the galvanometer of the bridge. In the White-Adams apparatus the switch was moved by a motor-driven mechanism and could only open or close at particular instants separated by arbitrarily fixed intervals of about one second. In the present regulator 498 JOURNAL OF* THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 the switch is operated by an electro-magnet as soon as a contact button on the boom of the galvanometer reaches one or the other of two fixed contact buttons. As the force with which the galvanometer presses the contact buttons together is very small, it is necessary to employ only a very small cur- rent through its contacts, in order to prevent their sticking. For this purpose a high resistance polarized relay is placed between the galvanometer contacts and the magnet that operates the main switch. As a further precaution, the secondary of a small transformer is connected in series with the coil of the galvanometer, while the primary is connected to the heating circuit in such a way that the operation of the main switch causes a ballistic deflection of the galvanometer towards its central position. All the appliances used are of standard make with a few simple changes. The adjustment of the rate at which energy is supplied to the furnace is effected by varying the ratio of the time it is supplied at a higher rate to the time it is supplied at a lower rate. Thus the present type of galvanometer is able to secure the proper ratio in a single cycle while the type employed by White and Adams could, in general, only approximate it after several cycles by a fraction whose numerator and denominator were integers. Under certain conditions this caused a rather large, slow oscillation of the temperature of the furnace. In order to vary the temperature of the furnace slowly for taking heating or cooling curves, one of the arms of the bridge is shunted by a variable rheo- stat whose resistance is changed in equal steps at intervals of 30 or 60 seconds. This arrangement has been found to give a steady change of temperature, which, however, is not quite linear. The regulator, when used with the ordinary type of platinum resistance furnace, has been found to hold the temperatures up to 1250° constant within 0.2° C. for several hours, in spite of variations of 5° in the room temperattue and of 6 per cent in the line voltage. At higher temperatures the tempera- ture falls slowly, but may be maintained within 0.2 ° by an occasional manual adjustment. The temperature coefficient of nichrome or chromel wire is too low for the regulator; but nickel wire may be used up to perhaps 500° and some other alloy, such as alumel, may be found to work at still higher temper- atures. As is the case with the White-Adams regulator, this apparatus, in its present form, is not suitable for use with alternating current or with the pulsating current furnished by the mercury arc rectifier. The second paper, on Aerial navigation, was presented by Mr. H. N. Eaton, and was illustrated. It was discussed by Messrs. L. J. Briggs, LittlehalES, A. F. Beal and Pawling. Aerial navigation is a recent development as it is only since aircraft have become capable of flying for long distances that the necessity for navigating them as ocean-going vessels are navigated has arisen. Aerial navigation resembles marine navigation in general principles but is more difficult in application owing to the higher speeds of the craft and of the sup- porting medium, to the impossibility of charting the winds as the ocean cur- rents are charted because of the variability of the former, and to the fact that freedom of motion in three dimensions introduces additional problems. Fortunately it is not necessary to determine position as accurately in the case of air-craft as in the case of ships on the ocean, since an error of from 10 to 20 miles involves only a few minutes additional flying time. There are three general scientific methods of aerial navigation; dead reckon- DEC. 4, 1921 SCIENTIFIC NOTES AND NEWS 499 ing, astronomical observation, and directional wireless telegraphy. Dead reckoning involves the measurement of air speed, ground speed, heading, drift, and the amount and direction of the wind. The chief difficulty in this method of navigation arises from the fact that the motion of the craft over the ground is due to the resultant of the air velocity of the craft and the effect of the wind, the latter being often difficult to determine. Instruments have' been developed to measure directly or indirectly all of these quantities. In general principles marine and aerial navigation by astronomical ob- ser\'ations are practically identical. The sextant is the universal instrument used for observation on the celestial bodies in both cases. In the air, how- ever, it often happens that no horizon is available to furnish a reference line and it is then necessary to use an artificial horizon of some type, bubble, pendulum, or gj^oscopic. Consequently, sextants with these horizons at- tached are commonly used in aerial navigation. It is worthy of notice that the aerial navigator often has available natural horizons which are never visible from the surface of the sea. The top surface of the haze lying over the ocean and flat layers of clouds often furnish excellent horizons. The radio direction finder can be used in the air to determine the position of the craft by measuring the directions in which radio waves from the craft reach two or more fixed stations or radio waves from the fixed stations reach the craft. H. H. KiMBAivE, Recording Secretary. SCIENTIFIC NOTES AND NEWS THE PUEBLO BONlTO EXPLORATIONS Mr. Neil M. Judd, curator of American archeology, U. S. National Mu- seum, returned to Washington recently after having been occupied in New Mexico for more than five months as director of the National Geographic Society's Pueblo Bonito Expedition. Pueblo Bonito is one of the largest and best preserved prehistoric ruins north of Mexico. The Society has obtained a permit from the Department of the Interior and it is expected that the ruin can be wholly excavated within five years. No public notice has yet been issued as to the results of this first season's explorations but it is understood that the expedition was entirely successful both from the view- point of excavations actually completed and from the amount of data re- covered. A unique feature of this newest National Geographic Society expedition — • one which has created considerable favorable comment among American men of science — is a proposed series of annual conferences at Pueblo Bonito to which specialists in the various humanistic sciences will be invited. The first of these symposiums, held last August, was attended by archeologists and agriculturists; geologists, botanists, and soil experts will be present at next year's meeting. The willing cooperation of these gentlemen — leaders in their respective fields of research — has made it possible to attack the problem presented by the marvelous ruins of Pueblo Bonito on a scale not thought possible heretofore; their combined efforts should result in a very distinctive contribution to the history of ancient America. NOTES The following lectures have been given recently in the Bureau of Standards Physics Club series on the physics of the Earth: Monday, October 31, WiL- 500 JOURNAL OF the; WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 20 LiAM Bowie : The theory of isostasy; Monday, November 7, Harry Fielding Reid: The causes of earthquakes; Monday, November 14, Lyman J. Briggs: The measurement of the acceleration of gravity at sea. Captain ErnEST h- Bennett, formerly in command of the battleship New York, has been designated by the Navy Department as director of the naval experimental and research laboratory now nearing completion at Belleview, on the Potomac River below Washington. Five buildings, in- cluding office and laboratory^ machine shop, forge and foundry, pattern shop, and power plant, are under construction. Dr. Torbjorn Gaarder, director of the biochemical laboratory of Ber- gens Museum, Bergen, Norway, visited the scientific institutions of Wash- ington early in November. The Directors of the American Chemical vSociety have elected Mr. H. E. Howe, of the National Research Council, editor of the Journal of Industrial and Engineering Chemistry to succeed Dr. Charles H. Herty, who has resigned to become president of the newly organized Association of Synthetic Organic Chemical Manufacturers. Dr. William C. Kendall, scientific assistant and ichthyologist of the U. S. Bureau of Fisheries, has resigned after nearly thirty-three years of service with the Bureau, to accept the position of ichthyologist in the Roose- velt V,''ild Life Forest Experiment Station of the New York State College of Forestry, Syracuse, New York. The collection of birds of the late William Palmer has been transferred from George Washington University to the Division of Birds, U. S. National Museum. This collection is noteworthy for the number of District of Colum- bia records and for the young and molting plumages it contains. Dr. GusTAV TroEdsson, paleontologist at the University of Lund, Sweden, and now traveling on a fellowship in the United States, spent a part of October in studying the Cambrian and Ordovician collections in the National Museum. Mr. S. L. Willis, formerly in charge of the preparation of ceramic data for the U. S. Tariff Commission, has resigned to accept a position with the Corning Glass Works of Corning, New York. /■ JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. 11 Deckmber 19, 1921 No. 21 ZOOLOGY. — A key to the Philippine operculate Imid mollusks of the genus Ceratopoma.i Paul Bartsch, United States National Museum. In 1918 we published in this Journal^ a Classification of the Philip- pine operculate land shells of the family Helicinidae, with a synopsis of the species and sub-species of the genus Geophorus. In that paper we gave keys to the subgenera and species of the largest genus, namely, Geophorus, of the subfamily Helicinidae. Since then enough ma- terial has come to hand to enable us to similarly treat another genus, namely, that of Ceratopoma, a key to the species of which is herewith furnished (see page 502). Ceratopoma has the operculum less specialized than any other Philippine Helicinid. It consists of a simple, horny shell without calcareous deposit. The type of the genus is Helicina caroli Kobelt. The animal, like Geophorus, is usually a ground dweller and may be found among dead leaves as well as in crevices of rocks. At the present time the genus is known from Luzon, Leyte, Siargao and northeastern Mindanao, and it is quite possible that careful collect- ing in the islands between the two extremes will reveal additional species. Ceratopoma caroli Kobelt comes from the island of Siargao. It is a large species, with the parietal callus chestnut brown. In fact, it is the only Ceratopoma so far known with a brown callus. Ceratopoma henningiana Mollendorff was described from Pena Blanca, Luzon, and differs from all the other Ceratopomas in having a broad brown basal band near the periphery. Ceratopoma cagayanica, sp. nov., differs from the other two known large non-color-banded Ceratopomas in having the peripheral keel limited on the base by an incised line, in which character it agrees with Ceratopoma henningiana Mollendorff. The type, Cat. No. *■ Published by permission of the Secretary of the Smithsonian Institution. Received November 8, 1921. 2 This Journal 8: 643-657. 1918. 501 502 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOL. 11, NO. 21 O o 8 O CO W u w Pk CO M w o (U O CO T— I a n ID ■*-> CO a; •T-l -^ •-I c/l +-' ^ as ;=; ir ^ be Si '-' 'u ?e^ Vh o o m TS -t-> u c c3 a; m :0 § <3 S ^ Q C3 ■& tW) 5tl O u ,13 +-) >■ — i
  • .° o «" 2 a> a; O P.^ -^ !n 5^! o +j o 03 3 C O u V B I OJ C o o c en o o u V s c3 V -t-> o I O) a o o x> 03 o 13 CJ 6 00 c 03 iii ii '^ a) OJ U o o Th 1-1 >-i rj J3 V V u u <+-" 'i-' 03 03 Ph ^ pq pq e s I — i f-^ (O to V ^ +-> CO C^ C O o OS Ph a 03 ^ o d o 13 ^ irj t« OJ en O o OJ +-> (U 08 03 O +-> a* d o '^ ^ ^ 1 a ^^ 6 13 13 1/1 tn V o o3 V- o a to lO u ^ )^ ^ "C »s 01 a ft o o to u « ft 8 0) g 3 cS s cS (fl rt o; 1-1 5 C 01 ^ Jr. H. N. Oberholser. 62. *Larus hyperboreiis barrovianus, status of. H. C. Oberholser. 62. *Melanerpes erythrocephalus, new subspe- cies of. H. N. Oberholser. 112. *Migration of North American birds. H. C. Oberholser. XI. Canada jay, Oregon jay, Clarke's nutcracker, pinon jay. 113; XII I. European starling, bobolink. 496. *Mutanda ornithologica VIII. H. C. Oberholser. 112. * Myiarchus ferox, Guiana flycatcher, races of. H. C. Oberholser. 497. *North American birds, notes on. H. C. Oberholser. 63. *North and Middle America, birds of. R. Ridgway. 59, 512. *Otocoris, new from Calif. H. C. Ober- holser. 497. §Palmer collection transferred to U. S. National Museum. 500. *Pipilo fuscus, new subspecies of. H. C. Oberholser. 60. *Protection, federal, of migratory birds. G. A. Lawyer. 61. SUBJECT INDEX 535 *Prunella niodularis, new subspecies from Pyrenees. F. Harper. 63. ^Ptarmigan, new, from Mt. Rainier. W. P. Taylor. 495. *Quiscalus quiscula, races of. H. C. Ober- HOLSER. 62. *Rhynchocyclus, relationships and geo- graphic distribution of species and races of. C. B. Cory. 111. *Rookeries of the Tortugas. P. Bartsch. 60. *£outh American birds, new. W. E. C. Todd. 511. *South America, new birds from Peru, Bolivia, Brazil, and Colombia. F. M. Chapman. 111. Tinamidae, new birds of family. Alex. Wetmore. 434. *Tortugas, bird rookeries of. P. Bartsch. 60. *Washington, all-day bird trip at. H. C. Oberholser. 112. *Washington region, Oct.-Nov., 1919. H. C. Oberholser. 512. *Waterfowl in Neb. H. C. Oberholser. 495. *Whippoorwill, new from Porto Rico. Alex. Wetmore. 60. Paleontology. Brachiopod, shell regenera- tion in. W. A. Price. 32. *Fauna of Cannonball marine member of Lance formation. T. W. Stanton and T. W. Vaughan. 138. tNational Museum, paleontological work at. R. S. BasslER. 315, 446. *Orthatilax, Tertiary guide fossil. C. W. Cooke. 471. *Orthophragmina and Lepidocyclina, American species of. J. A. Cushman. 194. *Orthophragmina, new species, from La. J. A. Cushman. 511. *Operculina and Heterostegina, American species of. J. A. Cushman. 511. fReptiles, reconstruction of extinct. C. W. GiLMORE. 426. fVertebrate, fossil, exhibit in the National Museum. C. W. Gllmore. 66. Petrology. Essex Co., Mass., igneous rocks of. C. H. Clapp. 470. Granites of Washington, D. C. H. S. Washington. 459. *Italite, new leucite rock. H. vS. Washington. 346. Lamprophyre dike cutting a pyrite body in Boyd Smith mine, Va. T. L. Wat- son. 341. Monticellite alnoite from Isle Cadieux, Quebec. N. L. Bowen. 278. Obsidian from Copan and Chichen Itza. H. S. Washington. 481, *Rhyolites of Lipari. H. S. Washington. 392. Physical Chemistry. Acidity, methods of stating. E. T. Wherry and E. Q. Adams. 197, 202. Acidity, Wherry and Adams' methods of stating, reply to. W. M. Clark. 199. Chemical structure and physiological ac- tion. C. L. Alsberg. 321. *Melting point curve, estimating impuri- ties by. W. P. White. 113. Physics. fAerial navigation. H. H. Eaton. 498. fAeronautic instruments, old and new problems of. M. D. Hersey. 22. fAeronautics, meteorological factor in. C. L. Meisinger. 283. fAircraft engines at high altitudes. H. C. Dickinson. 22. *Annealing of glass. L. H. Adams and E. D. Williamson. 417. fDensity of strained glass. L. H. Adams and E. D. Williamson. 284. fDental materials, physical properties of. W. H. SouDER and C. G. Peters. 37. Diamond, compressibility of. L. H. Adams. 45. fElectrical resistance of the human body. F. Wenner, J. S. Martin, and N. L. Forman. 286. fElectricity, diurnal variation of atmos- pheric. S. J. Mauchly. 398. Furnace temperature regulator. H. S. Roberts. 401, t497 *Gases, efflux of, through small orifices. E. Buckingham and J. D. Edwards. 209. fGeoidal slope, law of, and fallacies in dynamic meteorology. C. F. Marvin. 211. 536 SUBJECT INDEX Physics (Continued) fHeat conduction in fins of air-cooled engines. S. R. Parsons and D. R. Harper. 513. fHeating of substances by expansion. L. H. Adams. 349. fHypsometer as precision instrument. E. F. Mueller and T. S. Sligh, Jr. 167. t Illumination measurements, daylight, and sky brightness. H. H. Kimball. 513. flnduction coils, distributed capacity of. G. BreiT. 239. *Integration method of deriving the alter- nating current resistance and induc- tance of conductors. H. L. Curtis. 209. flntemational hydrogen scale, comparison of, with standard scale of temperature defined by platinum resistance ther- mometer. R. H. WiLHELM and A. K. Benson. Irreversible time effects, theory of. M. D. Hersey. 149. fMagnetic reluctivity and eutectoid carbon steel. C. Nusbaum. 38. fMagnetization by rotation, experiments on. S. J. Barnett. 162. *Magnetizing force, variation of residual induction and coercive force with. R. L. Sanford and W. L. Cheney. 210. jMagneto, physics of high-tension. F. B. Silsbee. 38. fMoUier diagrams. E. F. MuELLER and C. H. Myers. 347. *Photometers, measurement of intensity of transmitted and reflected light by polarization. F. E. Wright. 282. fPiezo-electric effect. A. M. NicoLSON. 473. *Polarization photometer prisms. F. E. Wright. 282. *Polarized light in study of ores and metals. F. E. Wright. 281. fPressures, production and measurement of extremely low. S. Dushman. 21. *Radiation, constants of. W. W. Cob- LENTZ. 209. *Radiation, thermal, present status of constants and verification of laws of. W. W. COBLENTZ. 439. Radioactive quantity, name of a (curie or rutherford). N. E. Dorsey. 381. fRange finder, self-contained base, and its errors. I. C. Gardner. 395. fResistance thermometer construction. T. S. Sligh, Jr. 313. fvSky brightness and daylight illumination measurements. H. H. Kimball. 513. fSpecific and latent heats of nickel and monel metal. W. P. White. 350. fSpectral distribution of energy required to evoke gray sensation. I. G. Priest. 396. Supraconductivity, discontinuity of re- sistance preceding. P. W. Bridgman. 455. fThermostatics. T. vS. Sligh, Jr. 168. *Ulbricht sphere in measurement of re- flection and transmission factors. E. Karrer. 439. §Weights, magnetic. 476. X-rays, characteristic soft, from arcs in gases and vapors. F. L. MohlER and P. D. FooTE. 273, 513. X-rays, wave lengths of. R. W. G. Wyckoff. 366. Phytopathology. fCooperation between en- tomologists and plant pathologists. F. K. Ravn. 142. fWhite pine and blister rust. sS. B. DetwilER. 119. Radiotelegraphy. Chronographic recorder of radio time signals. E- A. Eckhardt and J. C. K ARCHER. 303, t348. Radio signal fading phenomena. J. H. Bellinger and L. E. Whittemore. t240, 245. *Transmission and reception with antenna and coil aerials. J. H. DellingER. 313. Wave front angle in radiotelegraphy. L. W. Austin. 101. Science, General. fBritish Association for the Advancement of Science, 1920 meet- ing. 166. §Congress, matters of scientific interest in. 170. Distribution of scientific information in the U. S. R. B. SosMAN. 69. SUBJECT INDEX 537 ^Educational courses at Bureau of Stand- ards. 428. ^Educational courses at Department of Agriculture. 515. §Interchange of publications between Germany and the U. S. resumed. 147. §Lectures at Bureau of Standards. 499. fPan-Pacific Scientific Congress. W. Bowie. 165. W. E. Safford. 118. §Patents arising in government service, conference on. 379. §Personnel Research Federation, organi- zation of. 196. fRock Creek Park, lure of. F. Lamson- SCRIBNER. 121. Scientific Notes and News. 24, 44, 67, 100, 123, 147, 170, 196, 220, 244, 264, 287, 317, 351, 379, 400, 428, 447, 476, 499, 515. Spectroscopy. *Spectral transmission of the atmosphere. E. Karrer and E. P. T. Tyndall. 210. *Wave length measurements in arc spec- tra photographed in yellow, red, and infra-red. F. M. Walters, Jr. 439. *Wave lengths in arc spectra of seven elements. C. C. KiESS and W. F. Meggers. 210. Technology. jOptical glass, new methods of sealing. C. O. Fairchild. 314. Radiators for aircraft engines. S. R. Parsons and D. R. Harper. 409. Terrestrial Magnetism. fAtmospheric elec- tric observations during solar eclipse of May 29, 1919, and summary of similar observations. S. J. Mauchly. 163. Earth's size, bearing of, upon changes in its magnetism. W. F. G. Swann. 275. fMagnetic and meteorological observa- tions during solar eclipse May 29, 1919. L. A. Bauer. 164. fSolar activity, terestrial magnetism, and terrestrial electricity. L. A. Bauer. 399. Volcanology. fHawaii, recent volcanic events in island of. O. E. Meinzer. 427. §Katmai eruption, assimilation during. C. N. Fenner. 514. *Katmai region, Alaska, and eruption of 1912. C. N. Fenner. 394. fKatmai region, Alaska, structural and volcanic geology of. C. N. Fenner. 444. *Mauna Loa, gas collections from. E. S. vShepherd. 420. Zoology. fBirds and mammals of Yosemite Park. H. C. Bryant. 263. fCrinoids. A. H. Clark. 64. *Crinoids collected by Barbados-Antigua expedition. A. H. Clark. 312. *Echinoderms of Canadian Arctic expe- dition. A. H. Clark. 283. Evolution of animals. A.H.Clark. 207. Marionella (Eurystonia), emendation. N. A. Cobb. 504. Mollusks, Philippine land (Ceratopoma). P. Bartsch. 501. Names, family, in zoology. W. L. McAtee. 230. Nomenclature of supergeneric names. S. A. RoHWER. 106. *Ophitirans collected by Barbados-An- tigua expedition. A. H. Clark. 346. *Sea lilies and feather stars. A. H. Clark. 283. fShip worm, damage caused by. P. Bartsch. 65. fTurtle, spotted, sexual differences in coloration. S. F. Blake. 242. Vol. II ' January 4, 192 1 No. i JOURNAL OP THE WASHINGTON ACADEMY OF SCIENCES BOARD OF EDITORS J. Franciix Mbycs RobbkT B. SoaicAM S. F. Bi.An BUBSAu or atABDABoa aiorBTaiCAi, i^abobatomt busbao or plaht mooarBV ASSOCIATE EDITORS H. V. Hasjlan S. a. Robwvr BOTANICAL SOCDIYT BBTOMOMXItCAt, aOOSYV N. HOLUSTBR P- B. SIL8BB8 •tokooicAi, aociam rmxLoaovwncAt. soezBr? Sidney Paigb J. R. Swanton ^ BBOLOOICAi. SOCIBTT ABVBBOrOIAOieAI. BOCBBTT PUBLISHBD SVia-l«ONTHI.T EZCSPT IN JTTtY, AUGDST,' AND SBPTBICBER, WHSN MONTBI.T BY THB WASHINGTON ACADEMY OP SCIENCES OFVICB 0» FUBLICATION an CHURCH STKBBT > 8A8TOM. PA. Entered aa S*coud ClAsa Matter. lanuary 25. 1919. at the poBt^^ffica at ButM. Pa.. BBda* tke Art of ABKoat 24. 1912. Acceptaoce for maUiaK at apcdal rate of paaUfe 9frlAt4 far la Sactie* 1103 Act af October i, 1917. Aatherianl aa Jmlj ». 191t Journal of the Washington Academy of Sciences This Journal, the ofiScial organ of the Washington Academy of Sciences, aims to present a brief record of current scientific work in Washington. To this end it publishes: (1) short original papers, written or communicated by mem- bers of the Academy; (2) short abstracts of current scientific literature published in or emanating from Washington; (3) proceedings and programs of meetings of the Academy and afifiliated Societies; (4) notes of events connected with the scientific life of Washington. The Journal is issued semi-monthly, on the fourth and nineteenth of each month, except during the summer when it appears on the ninet eenth only. Volumes correspond to calendar years. Prompt publication is an essenti al feature; a manuscript reaching the editors on the twelfth or the twenty- eighth of the month will ordinarily appear, on request from the author, in the issue of the Journal for the following fourth or nineteenth, respectively. Manuscripts may be sent to any member of the Board of Editors; they should be clearly t5^ewritten and in suitable form for printing without essential changes. The editors cannot undertake to do . more than correct obvious minor errors References should appear only as footnotes and should include year of publication. Illustrations will be used only when necessary and will be confined to text figures or diagrams of simple character. The editors, at their discretion, may call upon an author to defray the cost of his illustrations, although no charge will be made for printing from a suitable cut supplied with the manuscript. Proof. — :In order to facilitate prompt publication no proof will be sent to authors unless requested. It is urged that manuscript be submitted in final form ; the editors will exercise due care in seeing that copy is followed. Authors' Copies and Reprints. — On request the author of an original article will receive gratis ten copies of the number containing his contribution and as many additional copies as he may desire at ten cents each. Reprints will be furnished at the following schedule of prices: Copies 4 pp. 8 pp. ' 12 pp. 16 pp. Coven 50 $1.40 $2.80 $4.20 $5.60 $1.15 100 1.60 3.20 4.80 6.40 1.40 150 1.80 3.60 5.40 7.20 1.65 200 2.00 4.00 6.00 8.00 1.90 250 2.20 4.40 6.60 8.80 2.15 Covers bearing the name of the author and title of the article, with inclusive pagination and date of issue, will be furnished when ordered. As an author will not ordinarily see proof, his request for extra copies or re- prints should invariably be attached to the first page of his manuscript. The rate of Subscription per volume is $6.00* Semi-monthly numbers 25 Monthly numbers 50 Remittances should be made payable to "Washington Academy of Sciences," and addressed to the Treasurer, R. I<. Paris, Coast and Geodetic Survey, Wash- ington, D. C. European Agent: William Wesley & Son, 28 Essex St., Strand, London. Exchanges. — The Journal does not exchange with other publications. Missing Numbers will be replaced without charge, provided that claim is made within thirty days after date of the following issue. * Volume I, however, from July 19, 1911, to December 19, 1911, will be sent for $i 00. Special rates are giveo to members of scientific societies affiliated with the Academy. OFFICERS OF THE ACADEMY President: Carl L. Alsberg, Bureau of Chemistry. Corresponding Secretary: Robert B. Sosman, Geophysical Laboratory. Recording Secretary: William R. Maxon, National Museum, Treasurer: R. L. Faris, Coast and Geodetic Survey. ANNOUNCEMENT OF MEETINGS OF THE ACADEMY AND AFFILIATED SOCIETIES Tuesday, January 4. The Anthropological Society, at the National Museum, at 4.45 p.m. Tuesday, January 4. The Botanical Society, at the Cosmos Club, at 8.00 p.m. Wednesday, January 5. The Society of Engineers, at the Cosmos Club. Program: Haete Cooke: The Diesel marine engine. Thursday, January 6. The Entomological Society, at the National Museum, at 8.00 p.m. Tuesday, January IL The Academy, at the Carnegie Institution, 16th and P Streets, at 8.15 p.m. Program: J. R. Johnston: Some problems in economic biology in Tropical America. Annual meeting for the reports of officers, announcemerit of elections, and other business. Tuesday, January 11, The Institute of Electrical Engineers, at the Cosmos Club. Wednesday, January 12. The Geological Society, at the Cosmos Club, at 8.00 p.m. Thursday, January 13. The Chemical Society. Saturday, January 15. The Philosophical Society, at the Cosmos Club, at 8.15 p.m. Program: Address of the Retiring President, Robert B. Sosman: The distribution of scien- tific information. Wednesday, January 19. The Society of Engineers. Thursday, January 20. The Academy, at the Cosmos Club, at 8.15 p.m. Program: Address of the Retiring President, C, 1,. Alsberg: The relation of chemical struc- ture to physiological action. CONTENTS Original Papers Page Mineralogy. — ^A new classification of the sulfo-salt minerals. Edgar T. Wherry and William F. Foshag 1 Analytical Chemistry. — Note on crucibles used in rock analysis. Henry S. Washington 9 Genetics. — Linkage between brach5rtic culms and t)ericarp and cob color in maize. J. H. KempTon 13 Proceedings Philosophical Society of Washington 21 Archaeological Society 23 Scientific Notes and News 24 Vol. II January 19, 192 1 No. 2 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES BOARD OF EDITORS Robert B. Sosman S. F. BivAke Sidney Paige GBOPHYSICAI. LABORATORY BUREAU OF PLANT INDUSTRY GBOI^OGICAI. SURVBY ASSOCIATE EDITORS H. V. Harlan F. B. SilsbeE BOTANICAL SOCIBTY PHILOSOPHICAL SOCIBTY N. HOI^LISTER G. W. STOSB BIOLOGICAL SOCIKTV G80L0GICAL SOCIETY S. A. RoHWER J. R- Swanton BNTOMOLOGICAL SOCIBTY ANTHROPOLOGICAL SOCIETY } PUBLISHED SEMI-MONTHLY EXCEPT IN JULY, AUGUST, AND SEPTEMBER, WHEN MONTHLY BY THE WASHINGTON ACADEMY OF SCIENCES * OFiflCE OP PUBLICATION 2 1 1 CHURCH STREET EASTON, PA. Entered as Second Class Matter, January 25, 1919, at the post-office at Eastou, Pa., under the Act of August 24, 1912. Acceptance for mailing at special rate of postage provided for iu Section 1103, Act of October 3, 1917, Authorized on July 3, 1918. Journal of the Washington Academy of Sciences This Journal, the official organ of the Washington Academy of Sciences, aims to present a brief record of current scientific work in Washington. To this end it publishes: (1) short original papers, written or communicated by mem- bers of the Academy; (2) short abstracts of current scientific literature published in or emanating from Washington; (3) proceedings and programs of meetings of the Academy and affiliated Societies; (4) notes of events connected with the scientific life of Washington. The Journal is issued semi-monthly, on the fourth and nineteenth of each month, except during the summer when it appears on the nineteenth only. Volumes correspond to calendar years. Prompt publication is an essential feature; a manuscript reaching the editors on the eighth or the twenty- fourth of the month will ordinarily appear, on request from the author, in the issue of the Journal for the following fourth or nineteenth, respectively. Manuscripts may be sent to any member of the Board of Editors; they should be clearly typewritten and in suitable form for printing without essential changes. The editors cannot undertake to do more than correct obvious minor errors. References should appear only as footnotes and should include year of publication. Illustrations will be used only when necessary and will be confined to text figures or diagrams of simple character. The editors, at their discretion, may call upon an author to defray the cost of his illustrations, although no charge will be made for printing from a suitable cut supplied with the manuscript. Proof. — In order to facilitate prompt publication no proof will be sent to authors unless requested. It is urged that manuscript be submitted in final form; the editors will exercise due care in'seeing that copy is followed. Authors* Copies and Reprints. — On request the author of an original article will receive gratis ten copies of the number containing his contribution and as many additional copies as he may desire at ten cents each. Reprints will be furnished at the following schedule of prices: Copies 4 pp. «pp. 12 pp. 16 pp. Covers 50 $1.40 $2.80 $4.20 $5.60 $1.15 100 1.60 3.20 4.80 6.40 1.40 150 1.80 3.60 5.40 7.20 1.65 200 2.00 4.00 6.00 8.00 1.90 250 2.20 4.40 6.60 8.80 2.15 Covers bearing the name of the author and title of the article, with inclusive pagination and date of issue, will be furnished when ordered. As an author will not ordinarily see proof, his request for extra copies or re- prints should invariably be attached to the first page of his manuscript. The rale of Subscription per volume is $6.00* Semi-monthly numbers 25 Monthly numbers 50 Remittances should be made payable to "Washington Academy of Sciences," and addressed to the Treasurer, R. L- Paris, Coast and Geodetic Survey, Wash- ington, D. C. European Agent: WilHam Wesley & Son, 28 Essex St., Strand, London. Exchanges. — The Journal does not excbtrnge with other publications. Missing Numbers will be replaced without charge, provided that claim is made within thirty days after date of the following issue. * Volume I, however, from July 19, 1911, to December 19. 191 1 . will be tent for S3.00 Special rates are k>v«o to members of scientific societies affiliated with the Academy. ANNOUNCEMENTS OF MEETINGS OF THE ACADEMY AND AFFILIATED SOCIETIES Wednesday, January 19. The Society of Engineers, at the Cosmos Chib. Thursday, January 20. Joint meeting of the Academy and the Chemical Society, at the Cosmos Club, at 8.15 p.m. Program: Address of the Retiring President of the Academy, C. L. AlsbERG : The relation of chemical structure to physiological action. Saturday, January 22. The Biological Society, at the Cosmos Club. Wednesday, January 26. The Geological Society. Saturday, January 29. The Philosophical Society, at the Cosmos Club, at 8.15 p.m. Program; G. BreiT: The distributed capacity of inductance coils. J. H. Dellinger and L. E. Whittemore: Radio signal Jading phetiomena. F. B. Littell: The variaiion of latitude and tlie constant of aberration, from four years' work with the photographic zenith tube at Washington. Tuesday, February 1. The Botanical Society, at the Cosmos Club, at 8.00 p.m. Wednesday, February 2. The Society of Engineers. Thursday, February 3. The Entomological Society. PROGRAMS ANNOUNCED SINCE THE PRECEDING ISSUE OF THE JOUR^AL^ Tuesday, January 4. The Botanical . Society, at the Cosmos Club, a 8.00 p.m. Pro- gram: F. Lamson-Scribner: The lure of Rock Creek Park. J. M. Smn.L: Skunk cabbage, Spathyeraa foetida. Thursday, January 6. The Entomological Society, at the National Museum, at 8.00 p.m. Program: W. R. Walton: Presidential address. R. C. Shannon: Notes on classification of Syrphidae. Saturday, January 8. The Biological Society, at the Cosmos Club, at 8.00 p.m. Pro- gram: L. O. Howard: Some views of the fight in southern France last summer against the Moroccan locust. S. F. Blake: Sexual differences in coloration of the spotted turtle. Tuesday, January 11. The Institute of Electrical Engineers, at the Cosmos Club, at 8.00 p.m. Program: Ralph D. Mershon: Sofn^ things engineers should knmv con- cerning the rudiments of corporate financing. Wednesday, January 12. The Geological Society, at the Cosmos Club, at 8.00 p.m. Program: H. G. Ferguson: Lode deposits of Manhattan, Nevada. C. N. Fenner: Structural and volcanic geology of the Katmai region, Alaska. H. D. Miser: Llanoria, the Paleozoic land area in Louisiana and eastern Texas. Thursday, January 1.3. The Chemical Society, at the Cosmos Club, at 8.00 p.m. Pro- gram: R. C. Tolman: The third law of thermodynamics. Monday, January 17. The Archaeological Society. Program: J. A. Montcomerv: Archaeological work in Palestine and the American School in Jerusalem. ' Notices ieceived too late for publication before the date of the meeting. CONTENTS PaKe Original Papers Mineralogy. — -Bementite and neotocite from western Washington, with conclusions as to the identity of bementite and caryopilite. J. T. Pardee, E. S. LarsEN, Jr., and George Steiger 25 Paleontology. — Shell regeneration in a Pennsylvanian brachiopod. W. Armstrong Price 32 Proceedings Philosophical Society 37 Chemical Society 40 Scientific Notes and News 44 OFFICERS OF THE ACADEMY President: AIvFrbd H. Brooks, Geological Survey. Corresponding Secretary: Robert S. Sosman, Geophysical Laboratory. Recording Secretary: William R. Maxon, National Museum. Treasurer: R. h. Faris, Coast and Geodetic Survey. Voi,, II February 4, 192 1 No, 3 JOURNAL OF THB WASHINGTON ACADEMY OF SCIENCES BOARD OF EDITORS Robert B. Sosman S. P. Bm>e3 Sidney Paige GBOPBYSICAI, ItABORATORV BDRBAD OF PLANT INDDSTRY GSOLOOICAL SDRVBT ASSOCIATE EDITORS H. V. Harlan ' P. B. Silsbee BOTANICAL SOCIBTY PHILOSOPHICAL SOCIBTY N. HOI^LISTER G. W. Stose BIOLOGICAL SOCIBTV OBOLOOICAL SOCIBTY S. A, ROHWER J. R. SWANTON BNTOMOLOOICAL SOCIBTY 'ANTHROPOLOGICAL SOCIBTY PUBLISHED SEMI-MONTHLY EXCEPT IN JULY, AUGUST, AND SEPTEMBER, WHEN MONTHLY BY THB WASHINGTON ACADEMY OP SCIENCES OFPICE 09 PUBLICATION 211 CHURCH STREET EASTON, PA. Entered a3 Second Class Matter, January 25, 1919, at the post-office at Easton, Pa., under the Act of August 24, 1912. Acceptance for mailing at special rate of postage provided for in Section 1103, Act of October 3, 1917. Authorized on July 3, 1918. Journal of the Washington Academy of Sciences This JotTRNAL, the official organ of the Washington Academy of Sdences, aims to present a brief record of current scientific work in Washington. To this end it publishes: (1) short original papers, written or communicated by mem- bers of the Academy; (2) short abstracts of current scientific literature published in or emanating from Washington; (3) proceedings and programs of meetings ven to members of scientific societies affiliated with the Academy. N. CONTENTS y Original Papers Page Mathematics and Bacteriology. — On the dilution method of counting bacteria. P. V. Wells and W. F. Wells 265 Physics. — Soft characteristic X-rays from arcs in gases and vapors. F. L. MohlER and Paul D. Foote 273 Terrestrial Magnetism. — The bearing of the Earth's size upon changes in its magneti- zation. W. F. G. SwANN 275 Petrology. — Preliminary note on monticellite alnoite from Isle Cadieux, Quebec. N. L. BowEN 278 Abstracts .; Physics ' 281 ; Geology 282 Zoology 283 Proceedings Philosophical Society 283 ScxENTiFxc Notes and News 287 ; OFFICERS OF THE ACADEMY President: Alfred H. Brooks, Geological Survey. Corresponding Secretary: Robert B. Sosman, Geophysical Laboratory. Recording Secretary: Wii^uam R. Maxon, National Museum. Treasurer: R. L. Faris, Coast and Geodetic Survey. NOTE The May, June and July numbers of the Journal have been delayed on account of strikes in the printing trades. ANNOUNCEMENTS OF MEETINGS OF THE ACADEMY AND AFFILIATED SOCIETIES PROGRAMS ANNOUNCED SINCE THE PRECEDING ISSUE OF THE JOURNAL^ Monday, June 27. The Botanical Society, at the Cosmos Club, at 8 p.m. Program: J. F. Rock: A trip through North Siam, Burma, and Assam for the Office of Foreign Seed and Plant Introduction. Received too late for publication before the date of the meeting. 1 Vol. II July 19, 1921 No. 13 JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Robert B. Sosman OBOPBVSICAL LABORATOKT BOARD OF EDITORS S. F. Bl^KB BORBAD OP PLANT INDUSTRY SiDNBT PAIGB obolootcai. sdrvbv ASSOCIATE EDITORS H. V. Harlan botanical socibtv N. HOLLISTBR BIOLOGICAL SOCIETY S. A. ROHWBR ENTOMOLOGICAL SOCISTV F. B. SiLSBBB PHILOSOPHICAL SOCIBTV G. W. Stose OBOLOOICAL SOCIETY J. R. SWANTON ANTHROPOLOGICAL SOCIBTV PUBLISHED SEMI-MONTHLY EXCEPT IN JULY, AUGUST, AND SEPTEMBBR, WHEN MONTHLY BY THE WASHINGTON ACADEMY OF SCIENCES OPFICB OP PUBLICATION 211 CHURCH STREET E ASTON, PA. Entered as Second Class Matter, January 25, 1919, at the post-office at Easton, Pa., under the Act of August 24, 1912. Acceptance for mailing at special rate of postaEe provided for in Section 1103, Act of October 3, 1917. Authoriied on July 3, 1918. Journal of the Washington Academy of Sciences This Journal, the ofiScial organ of the Washington Academy of Sciences, aims to present a brief record of current scientific work in Washington. To this end it publishes: (1) short original papers, written or communicated by mem- bers of the Academy; (2) short abstracts of current scientific literature published in or emanating from Washington; (3) proceedings and programs of meetings of the Academy and affiliated Societies; (4) notes of events connected with the scientific life of Washington. The Journal is issued semi-monthly, on the fourth and nineteenth of each month, except during the summer when it appears on the nineteenth only. Volumes correspond to calendar years. Prompt publication is an essential feature; a manuscript reaching the editors on the eighth or the twenty- fourth of the month will ordinarily appear, on request from the author, in the issue of the Journal for the following fourth or nineteenth, respectively. Manuscripts may be sent to any member of the Board of Editors; they should be clearly tjrpewritten and in suitable form for printing without essential changes. The editors cannot undertake to do more than correct obvious minor errors. References should appear only as footnotes and should include year of publication. Illustrations will be used only when necessary and will be confined to text figures or diagrams of simple character. The editors, at their discretion, may call upon an author to defray the cost of his illustrations, although no charge will be made for printing from a suitable cut supplied with the manuscript. Proof. — In order to facilitate prompt publication no proof will be sent to authors unless requested. It is urged that manuscript be submitted in final form ; the editors will exercise due care in seeing that copy is followed. Authors' Copies and Reprints. — On request the author of an original article will receive gratis ten copies of the number containing his contribution and as many additional copies as he may desire at ten cents each. Reprints will be furnished at the following schedule of prices: Copies 4 pp. 8 pp. 12 pp. 16 pp. Covers 50 fl.95 $3.90 $5.85 $7.80 $1.50 100 2.22 4.44 6.66 8.88 1.89 ,150 2.49 4.98 7.47 9.96 2.27 200 2.76 5.52 8.28 11.04 2.66 250 3.03 6.06 9.09 12.12 3.05 Covers bearing the name of the author and title of the article, with inclusive pagination and date of issue, will be furnished when ordered. As an author will not ordinarily see proof, his request for extra copies or re- prints should invariably be attached to the first page of his manuscript. The rale of Subscription per volume is $6.00* Semi-monthly numbers 25 Monthly numbers f . .60 7?emi7/ances should be made payable to "Washington Academy of Sciences," and addressed to the Treasurer, R. L- Paris, Coast and Geodetic Survey, Wash- ington, D. C. European Agent: William Wesley & Son, 28 Essex St., Strand, London. Exchanges. — The Journal does not exchange with other publications. Missing Numbers will be replaced without charge, provided that claim is made within thirty days after date of the following issue. •Volume I, however, from July 19, 191 1. to December 19, 191 1 , will be sent for $3.00. Special rates are Kiven to members of scientific societies affiliated with the Acudemj'. CONTENTS Original Papers Page Chemistry. — The evolution of matter. Frank WigglesworTh Clarke 289 Minerology. — On galenobismutite from a gold-quartz vein in Boise County, Idaho. Earl V. Shannon 298 Botany. — A remarkable new species of Ichthyoihere. S. F. Blake 301 Radiotelegraphy. — A chronographic recorder of radio time signals. E. A. Eckhardt and J. C. KarchER 303 Abstracts Optics 311 Geodesy 312 Zoology 312 Metallurgy 312 Chemical Technology 313 Radiotelegraphy 313 Proceedings Philosophical Society 313 Biological Society 315 Scientific Notes and New^. 317 OFFICERS OF THE ACADEMY President: Alfred H. Brooks, Geological Survey. Corresponding Secretary: Robi^rT B. Sosman, Geophysical lyaboratory. Recording Secretary: William R. Maxon, National Museum. Treasurer: R. L. Faris, Coast and Geodetic Survey. NOTE The July and August numbers of the Journal have been delayed on account of strikes in the printing trades. Vol. II August 19, 1921 No. 14 JOURNAL OF T£tB WASHINGTON ACADEMY OF SCIENCES BOARD OF EDITORS Robert B. Sosman S. F. Blakb Sidney Paigb OSOPBYSICAI. LABORATOBT BDRBA0 OF PLANT INDUSTBT OBOLOOICAI. aUBVSV ASSOCIATE EDITORS H. V. Haioan p. B. SilsbbB BOTANICAI, SOCIBTT PHttOSOPHICAL fiOCIBTV N. HOI.USTER G. W. STOSE BIOLOGICAL 90CIBTY OBOLOOICAL SOCIETY S. A. ROHWBR J- R. SWANTON BNTOMOLOOICAL SOCIBTT AKTHROPOLOOICAL 80CIBTY PUBUSHED SEMI-MONTHLY EXCEPT IN JULY. AUGUST, AND SEPTEMBER, WHEN MONTHLY BT THB ' WASHINGTON ACADEMY OF SCIENCES OFFICE OP PUBLICATION 211 CHURCH STREET EASTON, PA. Entered as Second Class Matter, January 25, 1919, at the post-office at Easton, Pa., under the Act of August 24, 1912. Acceptance for mailing at special rate of postage provided for in Section 1103, Act of October 3, 1917. Authoriied on July 3, 1918. Journal of the Washington Academy of Sciences This Journal, the official organ of the Washington Academy of Sciences, aims to present a brief record of current scientific work in Washington. To this end it publishes: (1) short original papers, written or communicated by mem- bers of the Academy; (2) short abstracts of current scientific literature published in or emanating from Washington ; (3) proceedings and programs of meetings of the Academy and affiliated Societies; (4) notes of events connected with the scientific life of Washington. The Journal is issued semi-monthly, on the fourth and nineteenth of each month, except