a ‘at TRANSACTIONS OF THE ROYAL SOCIETY OF EDINBURGH: Vou. VIII. NUN (i Wil EDINBURGH, PRINTED FOR ARCHIBALD CONSTABLE & CO. AND FRANCIS PILLANS ; AND FOR CADELL AND DAVIES, STRAND, AND JOHN MURRAY, ALBEMARLE STREET, LONDON. 1818. CONTENTS OF VOLUME EIGHTH. (Parr First.) On the Action of Transparent Bodies upon the differently coloured Rays of Light. By David Brewster, LL.D. F. B.S. Lond. & Edin. and F. A. 8. Ed. Page 1 . Description of a New Darkening Glass for Solar Ob- servations, which has also the property of polari- sing the whole of the transmitted Light... By- David Brewster, LL. D. F. B.S. Lond: & Ed. and F. A. S. Ed. - - 25 . Observations on the Fire-Damp of Coal Mines ; with a Plan-for Lighting Mines, so as to guard against its Explosion. By John Murray, M. D. F.R.S. Edin. Fellow of the Royal College of Physicians of Edinburgh, - - 31 . On the Lines that divide each heinsttnredad Are into Six equal- Parts. By W. A. Cadell, ie F. B.S. Lond. & Edin. - 61. . On the Origin of Cremations or the Riioniites of the: Dead. By the Rev. John. Jamieson, D. D. F. RB. S. Edin. & F. A. S. E. = 83 . Additional Communications respecting the Blind and Deaf Boy, James Mitchell. By John Gordon, M. D. F. B.S. Edin. - - 129 \VIL. vi CONTENTS. VII. On the Education of James Mitchell, the young Man born Blind and Deaf. By Henry Dewar, M. D. F. R. 8S. Edin. - Page VIII. On the Optical Properties of Mur iate of Soda, Fluate of Lime, and the Diamond, as exhibited in their action upon Polarised Light. By David Brewster, LL. D: & F-R.S. Tan & Edin. and F. A. S. Edin. - - 1X. On a New Optical and Mineralogical Piety of Calcareous Spar. By David ic watzr, LL. D. F. R. S. Lond. & Edin. and F. A. 8. Edin. X. On the Ancient Geography of Central and Eastern Asia, with Illustrations derived from Recent Dis- coveries in the North of India. By Hugh Mur- ray, Esq. F. R. 8. Edin. - = XI. An Analysis of Sea-Water ; with Observations on the Analysis of Salt-Brines. By John Murray, M. D. F. R. 8. Edin. = 4 XII. Elementary Demonstration of the Composition of Pres- sures. By Thomas Jackson, LL. D. F. B.S. Edin. and Professor of Natural Philosophy in the University of St. Andrew’s, - o XIII. Account of the remarkable Case of Margaret Lyall, who continued in a State of Sleep nearly Six Weeks. By the Rev. James Brewster, Minister of Craig. Communicated by Dr Brewster, XIV. A General Formula for the Analysis of Mineral Wa- ters. By John Murray, M.D. F. B.S. Edin. 137 157 165 171 205 245 249 259 {Part CONTENTS. vil (Part SEconp.) XV. On the Effects of Compression and Dilatation in al- tering the Polarising Structure of Doubly Re- fracting Crystals. By David Brewster, LL. D. F. RB. S. Lond. & Edin. - - Page 281 XVI. Experiments on Muriatic Acid Gas, with Observations on its Chemical Constitution, and on some other Subjects of Chemical Theory. By John Murray, M. D. F. R. S. Edin. - - 287 XVIL Experiments on the Relation between Muriatic Acid and Chlorine; to which is subjoined the Descrip- tion of a New Instrument, for the Analysis of Gases by Explosion. By Andrew Ure, M. D. Professor of the Andersonian Institution, and Member of the Geological Society, . 329 XVUL On the Laws which regulate the Distribution of the Polarising Force in Plates, Tubes, and Cylinders of Glass, that have received the Polarising Siruc- ture. By David Brewster, LL. D. F. R. S. Lond. and Edin. - - 353 XIX. Remarks, illustrative of the. Scope and Influence of the Philosophical Writings of Lord Bacon. By Macvey Napier, Esq. F.R.S. Lond.;& Edin. vnd F.A.S. Edin. - 3 373 XX. Sketch of the Geology of the Environs of Nice. By Thomas Allan, Esq. F. R. S. Edin. S = Aly XXI. On certain Impressions of Cold transmitted from the Higher Atmosphere, with the Description of an Instrument adapted to measure them. By John Leslie, F. R. S. Edin. and Professor of Mathema- tics in the University of Edinburgh. - - 465 XX. vili CONTENTS. XXII. A Method of determining the Time with Accuracy, from a Series of Altitudes of the Sun, taken on the same side of the Meridian. By Major-Gene- ral Sir Thomas Brisbane, Knt. F. R.S. Ed. Page 497 XXIII. Observations on the Junction of the Fresh Water of Rivers with the Salt Water of the Sea. By the Reverend John Fleming, D. D. F.R.S. Edin. 507 XXIV. Memoir of the Life and Writings of the Honour- able Alexander Fraser Tytler, Lord Woodhouselee. By the Rev. Archibald Alison, LL. B. F. BR. 8. Lond. & Edin. - - - 515 Appenpix, containing Lists of the Members elected since 1815, z 2 565 DIRECTIONS ro rue Binver. Plate I. To face page 58. aan \ To follow p. $1. —— IV. To follow p. 164. ra i Maps of India, to follow p. 203. — VII. To face p. 356. —— VIII. Map, to face p. 452. is To foll Xx. \ o follow p. 464. —— XI. To face p.476. I. On the Action of Transparent Bodies upon the differently coloured Rays of Light. By Daviv Brewster, LL. D. F. B.S. Lonv. & Epy. & F. A. S. Ep. (Read 5th June 1815.) ‘ROM the intimate connexion of the present subject with the improvement of the Achromatic Telescope, it must be admitted to be one of the most important in Optics ; while, from the minuteness of the effects which are to be observed and compared, it is unquestionably one of the most difficult. From this cause very little progress has been made in the in- vestigation. The irrationality of the coloured spaces, in pris- matic spectra, formed by different substances, has not even been mentioned in any of our elementary treatises on Natural Philosophy, and there are some philosophers who have scru- pled to receive it as a truth established in Physics. In order to render this subject sufficiently intelligible, let us suppose that a ray of light is transmitted successively through two prisms, one of rock-crystal, and the other of flint-glass, ha- ving the same refracting angles. The rock-crystal will be found to bend the ray of light more from its primitive direc- tion than the prism of flint-glass. The former is therefore said _ Vox. VIII. P. I. A to 2 ON THE ACTION. OF TRANSPARENT BODIES: to have a greater refractive power than the latter. If we again take other two prisms of the same substances, having such re-. fracting angles, that a ray of light is equally refracted by both, and if we examine the spectrum which each of’ them affords, by admitting the sun’s light into a dark chamber, it will be found that the spectrum formed by the flint-glass is much longer than the spectrum formed by the rock-crystal. The flint-glass is therefore said to. have a greater dispersive power than the rock-crystal, or a greater power of separating the ex- treme rays from the mean ray of the spectrum. If we then take other two prisms with their refracting angles of such a magnitude that they produce spectra of said lengths, it will be found by a particular mode of examination, that the colour- ed spaces have not the same size in the two spectra. The red and green rays will occupy more space, and the blue and vio- let ones less space, in the spectrum formed by the rock-crystal, than in the spectrum formed by the flint-glass. This want of proportionality, or irrationality in the coloured spaces of differ- ent spectra, is not of such a magnitude as to be visible upon a mere examination of the spectra themselves. In order to ob- serve it, we must make the prism of flint-glass refract in op- position to the prism of rock-crystal; and if we look at the bars of a window through the combined prisms, we shall per- ceive on the side of the bar to which the vertex of the flint- glass prism is directed, a fringe of green light, and on the other side of the bar, a purple or wine-coloured fringe. The flint-glass, therefore, acts less powerfully upon the green rays than the rock-crystal, or they are less separated from the red extremity of the spectrum. These uncorrected colours, have been called the secondary spectrum, and form the principal ob- stacle to the perfection of the achromatic telescope. In, UPON: THE DIFFERENTLY COLOURED RAYS OF LIGHT. 3 . In order to observe the secondary spectrum with distinctness, a prism of sulphuric or phosphoric acid should be made to act in opposition to a prism of flint-glass, or what is still better, to a prism of oil of cassia; the uncorrected fringes will in this case be remarkably broad and distinct, and I have seen them, when a prism of flint-glass acted in opposition to a prism of phosphoric acid, with a refracting angle of only 11°. When we look at the bars of a window through a prism of phospho- ric acid, they are fringed with the prismatic colours, and so dif- ferent are these colours, in their general appearance, from the colours formed by a flint-glass prism, that any person unac- quainted with the subject, would immediately perceive that there was an excess in the space occupied by the orange-co- loured light in the spectrum formed by the phosphoric acid. This simple experiment, may be considered as affording ocular evidence of the irrationality of the coloured spaces. In my Treatise on New Philosophical Instruments, I have already published the first experiments which I made upon this subject, and I have there pointed out a method of ob- taining a numerical value of the magnitude of the second- ary spectrum*. Since these experiments were published, I have pursued the subject to a much greater length, and have examined almost every transparent body of importance. The results of both these sets of experiments are contained in the following pages, and are arranged in an alphabetical order, to facilitate the reference from the General Table given at the end of the Paper. * The reader is referred to this work, p.353—401. for farther details illus: trative of this subject. A@2 1. Acetate 4 ON THE ACTION OF TRANSPARENT BODIES: 1. Acetate of Lead, melied. A prism of acetate of lead acting in opposition to a prism of crown-glass, produces a onademile secondary spectrum, in which the green fringe is on the same side of the window bar as the vertex of the ere of acetate of lead. This last has therefore a less powerful action on the green ee than crown- glass. _ A prism of acetate of lead acting in opposition to flint-glass, produces a less secondary spectrum, but the green fringe is still on the same side of the bar. Owing to the imperfection of the image, I was not able to compare this substance with bodies of a higher dispersive power, as the secondary spectrum became too small. 2. Acid, Acetic. The acetic acid acts more powerfully upon the green rays than flint-glass. It acts a little more powerfully upon the green rays than crown-glass. It acts less powerfully upon the green rays than rock-cry-+ stal. It acts a little less powerfully upon the green rays than mu- riatic acid ; but it is very difficult, in this case, to perceive the secondary spectrum. 3. Acid, Citric. Citric Acid acts more powerfully upon green light than flini- glass. 4. Acid, Malic. Malic Acid acts more powerfully upon the green rays than flint-glass. It UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. 5 It acts less powerfully upon the green rays than crown- glass. 5. Acid, Muriatic. Muriatic Acid acts much more ee upon green light that flint-glass. It acts more powerfully upon. green light than crown-glass. It acts less powerfully upon green light than rock-crystal. It acts less powerfully upon green light than water. It acts very much less powerfully upon green light than sul- phuric acid. 6. Acid, Nitric. Nitric acid acts much more powerfully upon the green rays than flint-glass. It acts a little more powerfully upon the green rays than crown-glass. It acts much less powerfully upon. the green rays than sul- - phuric acid. 7. Acid, Nitrous. Nitrous acid acts much.more powerfully upon green light than flint-glass. It acts less powerfully upon green light than topaz. (Nota. good observation.) It acts less powerfully upon green ight than rock-crystal. It acts less powerfully upon green light than nitric acid. It has nearly the same action upon green light as crown- glass; an uncorrected green fringe appearing towards the vertex of the nitrous acid prism, when it is inclined to the in- ‘cident ray, and, towards the vertex of the crown-glass prism, when it is placed first, and-inclined to the incident ray. The fringe is, however, greater in the latter case, and therefore the acid 6 ON THE ACTION OF TRANSPARENT BODIES acid may be regarded as exercising a greater action upon the green rays than the glass. When the nitrous acid acts in opposition to the muriatic acid, no uncorrected colour is perceived. 8. Acid, Phosphoric. Phosphoric Acid acts very much more powerfully upon green light than flint-glass. The secondary spectrum is very vivid and beautiful. It acts much more powerfully upon green light than crown- glass. The secondary spectrum is very distinct. It acts much more powerfully upon green light than the mu- riatic acid. Its action upon green light is nearly as small as that of su/- phuric acid. By inclining the phosphoric acid prism, the uncor- rected green light appears towards its vertex ; but by inclining the sulphuric acid prism, it does not appear. Hence the phos- phoric acid acts a little more powerfully upon green light than the sulphuric acid. 9. Acid, Phosphorous. Phosphorous Acid acts more powerfully upon green light than flint-glass, crown-glass, rock-crystal, or water. 10. Acid, Prussic. Prussic Acid acts much more powerfully upon the green rays than flint-glass. It acts more powerfully upon the green rays than crown- glass. When it acts in opposition to blue topaz, no uncorrected co- Jour is visible. The refracting angle, however of the topaz prism, UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. Ti prism, was too small for ascertaining accurately the relative ac- tion of the two bodies. It acts less powerfully upon the green rays than water. When it. acts in opposition to muriatic acid, no-secondary spectrum is perceived. 11. Acid, Sulphuric. Sulphuric Acid acts more powerfully upon the green. rays- than flint-glass, and affords a secondary spectrum greater than: any other substance. It acts. more powerfully upon the green light than crown-- glass, muriatic acid, rock-crysta!, fluor-spar, water, and phospho- ric acid. 12. Acid, Sulphurous,—water saturated with the gas. Sulphurous Acid acts more powerfully upon green light than: Alint-glass, crown-glass, rock-crystal, and water. | 13. Alcohol. Alcohol acts less powerfully upon the green rays than muria- tic acid and water. It acts rather more powerfully upon the green rays than flint and crown glass. . When it acts in opposition to ether, no uncorrected colour is seen. 14. Almonds, Oil of. Oil of Almonds acts more powerfully upon green light than Jlini-glass.. It acts a little less powerfully upon green light than crown-. glass. S 15... Almonds, 8 ON THE ACTION OF TRANSPARENT BODIES 15. Almonds, Bitter, Essential Oil of *. This oil acts more powerfully upon green light than oi/ of cassia, sulphur, and balsam of Tolu. It acts less powerfully upon green light than oil of anise- seeds, flint-glass, and crown-glass. 16. Amber. Amber acts less powerfully upon green light than crown-glass and rock-crystal. It acts a little less powerfully upon green light than flint- glass. It acts less powerfully upon green light than rock-salt. 17. Amber, Oil of: This oil acts less powerfully upon green light than orange- coloured glass, oil of lavender, flint and crown glass, topaz, and gum-arabic. It acts very much more powerfully upon green light than oil of cassia. It acts more powerfully upon green light than oil of anise- seeds. 18. Ambergris, Oil of: This oil acts less powerfully upon green light than topaz, rock-crystal, alcohol, and water. It acts more powerfully upon green light than oil of cum- min. 19. Anise Seeds, Oil of. This oil acts less powerfully upon green light than oil of sas- safras, oil of amber, and orange-coloured glass. It * IT am indebted for this oil to my friend Dr Gornoy. It is a part of that which Mr Bnonis used in his interesting experiments on the action of Vegetable Poisons, ‘UPON: THE DIFFERENTLY COLOURED RAYS OF LIGHT. ‘9 It acts more powerfully upon green light than oil of cas- sid. 20. Arabic, Gum. Gum Arabic acts more powerfully upon green light than oi of cassia, balsam of Tolu, and flint-glass. When it opposes crown-glass, the uncorrected colour is scarcely perceptible ; the excess of action on green light being on the side of the gum. It acts less powerfully upon green light than ¢opaz and rock- crystal. : 21. Beech Nut, Oil of. This oil acts less powerfully on green light than crown- glass. _ It acts a very little less powerfully upon green light than Slnt-glass. 22. Bergamot, Oil of. This oil acts less powerfully upon green light than flint and crown glass. No uncorrected colour is visible when it acts in opposition to oil of marjoram. 23. Beryl. Beryl acts more powerfully upon green light than Jlint and crown glass. 24. Borax. Borax acts more powerfully upon green light than flint and trown glass. Vou. VIL PL B ‘25. ies 10 ON THE ACTION OF TRANSPARENT BODIES. 25. Glass of Borax. Glass of Borax acts more powerfully upon green light than flint and crown-glass. 26. Calcareous Spar. Calcareous Spar acts. less powerfully upon green light than. topaz and rock-crystal. It acts more powerfully upon green light than flint-glass. When opposed to crown-glass, 1 have not been able to per- ceive distinctly any uncorrected colours. 27. Canada Balsam. Canada Balsam acts less powerfully upon green light than flint and crown glass. It acts more powerfully upon green light than oil of cloves. 28. Capivi, Balsam of. This balsam acts less powerfully upon green. light than crown-glass. It acts more powerfully upon green light than oil of marjo- ram. When it disperses in opposition to flint-glass, no secondary spectrum is visible. 29. Caraway-Seeds, Oil of. This oil acts less: powerfully upon green light than crown and flint glass. 30. Carbonate of Lead. This metallic salt acts more powerfully upon the green rays. than oil of cassia. It UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. li It acts very little more powerfully than the balsam of Tolu. 31. Cassia, Oil of: Oil of Cassia acts less powerfully upon green light than sul- phur, balsam of Tolu, and every other substance with which I have compared it. With sulphur the uncorrected colour is just visible. When acting in opposition to sulphuric acid, it forms a se- condary spectrum of a very large size; these substances being at the opposite extremities of the scale. 32. Castor Oil. Castor Oil acts less powerfully upon green light than crown- glass. : It acts a very little less powerfully upon green light than Juni-glass. 33. Chamomile, Oil of. This oil acts less powerfully upon green light than crown- glass. It acts a little less powerfully upon green light than flint- glass. 34. Cloves, Oil of. Oil of Cloves acts less powerfully upon the green rays than oil of lavender, Canada balsam, and flint-glass. _It acts more powerfully upon the green rays than oid of sas- safras, and oil of cummin. B2 35. Copal, 12 ON THE ACTION OF TRANSPARENT BODIES 35. Copal, Gum. Gum Copal acts less powerfully upon green light than crown- glass. It acts a very little less powerfully on green light than flint- glass, 36. Cummin, Oil of. This oil acts less powerfully upon green light than o7/ of la- vender, flint-glass, and crown-glass. It acts more powerfully upon green light than balsam of: Tolu. 37. Diamond.. When diamond acts in opposition to oil of cassia, the uncor- rected colours are nearly of the same magnitude, and in the same situation, as when the oil of cassia is combined with flint, glass. Hence diamond has nearly the same action upon green light as flint-glass, 38. Dill Seed, Oil of. This oil acts less powerfully upon green light than crown~ glass. It acts a very little less powerfully upon green light than- flint-glass. 39. Ege, White of an. The white of an.egg acts more powerfully upon green. light: than crown-glass, topaz, muriatic. acid, nitric acid, and fluor spar. It acts less powerfully upon green light than water, and much less than sulphuric acid. 40. Ethers. UPON -THE DIFFERENTLY COLOURED RAYS OF. LIGHT. 13 40. Ether. Ether seems to have the same action upon green light as ai- cohol. 41. Fennel-seeds, Sweet, Oil of. This oil acts much less powerfully upon green light than junt and crown. glass, and.less powerfully than oi! of dill seed. 42, Fenugreek, Oil of. This oil acts less powerfully upon green light than flin¢ and - crawn glass. 43. Fluor-Spar. Fluor-Spar acts less powerfully upon green light than sulphu- ric acid, and the white of an egg. 44. Glass, Crown. Crown-glass acts more-powerfully upon green light than fint-glass, oil of spermaceti, oil of olives, oil of ambergris, copal, or oil of juniper. It acts less powerfully upon green light than gum Arabic, al- cohol, topaz, fluor-spar, the acids, rock-crystal, and water. . 45. Glass, Flint. Flint-glass acts less powerfully upow green light than oil of spermaceti, oil of olives, oil of ambergris, essential a of juniper, oil of rape-seeds crown-glass, &c. It acts more powerfully upon green light than Canada bal- sam, and almost all the essential oils, excepting those ey mentioned, When. . 14 ON THE ACTION OF TRANSPARENT BODIES When flint-glass acts in opposition to balsam of Capivi, nut oil, oil of rhodium, and oil of rosemary, no secondary spectrum is ~visible. 46. Glass, Opal-coloured. This glass acts more powerfully upon green light than oil of cassia, and balsam of Tolu. It acts less powerfully upon green light than flint-glass. 47. Giass, Orange-coloured. This glass acts less powerfully upon green light than crown- glass, and very little less than flint-glass. It acts more powerfully upon green light than oil of amber, and oil of anise-seeds. 48. Glass, Red-coloured. This glass acts less powerfully upon green light than flint nd crown glass. 49. Hyssop, Oil of. This oil acts less powerfully upon green light than crown- glass, and a little less powerfully than flint-glass, and oil of pep- permint. 50. Ice. When ice is opposed to flint-glass, it forms a secondary spec- trum, having the same position, and nearly the same magni- tude, as when water is combined with flint-glass. 51. Juniper, Gum. This gum acts less powerfully upon green light than crown- glass. 52. Juniper, UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT.. is 52. Juniper, Oil of: This oil acts less powerfully upon green light than crown- glass. It acts a very little more powerfully upon green light than . Jfint-glass. 53. Lavender, Oil of: This oil acts less powerfully upon green light than flint and crown glass. It acts more powerfully upon green light than oil of cassia, balsam of Tolu, and oil of amber.. 54. Lemon, Oil of. This oil acts less powerfully upon green light than crown- glass, and a very little less powerfully than flint-glass: 55. Leucite. - This mineral acts more powerfully upon green light than fiint and crown glass. It acts less powerfully upon green light than topaz. 56. Marjoram, Oil of: This-oil acts less powerfully upon green light than flint and - crown glass, and. nut oil. 57. Muriate of Antimony. This fluid, (the dispersive power of that which I used was. 0.059,) acts far less powerfully upon green light than flint and — crown glass. It acts more powerfully upon green light than oil of sassa-. - fras. 6 ON THE ACTION OF TRANSPARENT BODIES It exercises almost the same (perhaps a litile greater) action “upon green light, as oil of cloves. 58. Nitrate of Potash. The refractive force which produces the greatest refraction in this salt, acts much less powerfully upon green light than - crown-glass, and a little less powerfully than flint-glass. 59. Nut Oil. Nut oil acts less powerfully upon green light than crown- glass. When it acts in opposition to flint-glass, no secondary spec- trum is visible. It acts more powerfully upon green light than oil of marjo- ram. 60. Nutmegs, Oil of. This oil acts less powerfully upon green light than crown- glass, and a very little less than ane Saat. 61. Olives, Oil of. Oil of olives acts less powerfully upon the green rays than crown-glass, and a very little less than flint-glass. 62. Pennyroyal, Oil of: This oil acts much less powerfully upon green light than crown-glass, and considerably less than flint-glass. 63. Peppermint, Oil of. Oil of peppermint acts less powerfully upon the green rays than crown-glass, and a little less powerfully than flint-glass. 64. Poppy, UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. [7 ; 64. Poppy, Oil of. This oil acts less powerfully upon green light than either flint or crown glass. 65. Rape-seed, Oil of. This oil acts less powerfully upon the green rays than crown- glass, and a very little more powerfully than flint-glass. 66. Rhodium, Oil of. This oil acts less powerfully upon green light than crown- -glass, and more powerfully than oil of cloves. When a prism of oil of rhodium witha great refracting angle, ‘was opposed to a prism of flint-glass with a small angle, the green fringe appeared towards the vertex of the flint-glass prism. When a prism of oil of rhodium with a small refracting angle, was made to correct a prism of flint-glass with a large angle, the uncorrected green appeared towards the vertex of the oil of rhodium. Hence we may infer that these two bo- dies exercise the same action upon the green rays. 67. Rock-Salt. This substance exercises a much greater action upon green light than rosin. It exercises a less action upon the green rays than crown- glass. Its action exceeds a little that of Jlint-glass, and is a little less than that of calcareous spar. — rarity wy 68. Rock-Crystal. This intents acts more powerfully upon green Awe than _Jlint-glass, crown-glass, and muriatic acid. Vor. VIII. P. I. Cc It 18 ON THE ACTION OF TRANSPARENT BODIES It acts less powerfully upon green light than sulphuric acid, phosphoric acid and water. 69. Rosemary, Oil of. This oil acts less powerfully upon green light than crown-. glass, and a very little more powerfully than flint-glass. 70. Rosin. This substance acts less powerfully upon green light than: crown-glass and flint-glass. The secondary spectrum with. flint-glass, is fully as great as that produced by flint-glass.oppo- sed to crown-glass. Rosin acts a little less powerfully upon the green rays than oil of cloves. . 71. Rue, Oil of This oil acts more powerfully upon the green rays than crown-glass, and a very little more powerfully than flint-glass.. 72. Sage, Oil of: This oil acts less powerfully upon green light than either crown or flint glass. 73. Sassafras, Oil of: This oil acts more powerfully upon green light than o#/ of: cassia, balsam of Tolu, and oil of anise-seeds, but less powerful- ly than crown and flint glass, and oil of cloves. 74. Savine, Oil of. This oil acts less powerfully upon the green rays than crown-. glass, and perhaps a little less powerfully than flint-glass ; but more powerfully than oi/ of spearmint, ie 75. Selenite. WPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. 19 15. Selenite. This mineral acts more powerfully upon green light than crown and flint glass, but less powerfully than ¢opaz. 76. Spearmint, Oil of. This oil acts less powerfully upon green light than flint and crown glass, and oil of savine. - 77. Spermaceti, Oil of: This oil acts more powerfully upon the green rays than flint- glass and oil of marjoram, and less powerfully than crown-glass. 78. Sulphur. Sulphur produces a secondary spectrum when opposed to Jflint-glass and crown-glass, nearly as great as when oil of cassia is opposed to them. When it refracts in opposition to oil of . Cassia, no uncorrected colour is visible, but the oil appears to have a less action upon the green rays. 79. Sulphuret of Carbon. This fluid acts much less powerfully upon the green rays than flint and crown glass, and all the essential oils except oil of cassia. Its action does not greatly exceed that of the oid of cassia. 80. Super-sulphuretted Hydrogen. . This fluid has a more powerful action upon the green rays than flint and crown glass. When it refracts in Opposition to water, no uncorrected colour is visible, C2 81. Tartrate 20° ON THE ACTION OF TRANSPARENT BODIES 81. Tartrate of Potash and Soda. This salt acts more powerfully upon green light than flint- glass, and does not appear to act very differently from crown- glass. 82. Thyme, Oil of. This oil acts. less powerfully upon green light. than flint’ and crown glass, and oil of juniper, but more powerfully than: oil of cloves. 83. Tolu, Balsam of. This balsam acts less powerfully upon the green rays than: oil of anise-seeds, oil of sassafras, and oil of lavender, and fint- glass, but more powerfully than oil of cassia and sulphuret of carbon. 84. Topaz, Blue. This mineral acts more powerfully upon green light than: crown and flint glass, selenite, and Jeucite, but less powerfully than water and rock-erystal. 85. Tourmaline. This mineral acts more powerfully upon green light than: crown and flint glass. 86. Turpentine, Oil of: This oil acts more powerfully upon the green rays than oil of sassafras, oil of cloves, and Canada balsam, but less power- fully than crown and flint glass. ; 87. Water: UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. QF 87. Water. Water acts more powerfully upon the green rays thar flint and crown glass, rock-crystal, the white of an egg, and the great-. er number of the acids. It acts less powerfully, however, than the phosphorous, sulphurous, phosphoric and sulphuric acids. 88. Wormwood, Oil of. This oil exceeds flint and crown glass in its action upon gree light, but is inferior to oil of sassafras and oil of cloves. 89. Zircon: This mineral acts less powerfully upon green light than crown-glass, but no secondary spectrum was visible when it re- fracted in opposition to flint-glass. In order to present under a general view the results of the: preceding experiments, I have arranged the various substances in a Table, inversely according to their action upon green: light ; that is, the bodies at the top of the Table form spectra: in which the red and green spaces are most contracted, and the: blue and violet ones most expanded. The relative position of several of the substances, particularly the essential oils, is quite empirical ; but it can readily be found by a reference to the preceding experiments, whether or not the relative action of any two bodies has been actually determined.. To have attempted to fix the exact place of every substance, would have required a great degree’ of labour, and more time than I could easily command; and it is almost certain, that the Table would still have been incomplete, as there are many of the essential oils, and some minerals, which do not exhibit any difference in their action upon green light. Several of the oils, too, which I used, had been exhausted by re- peated. 22 ON THE ACTION OF TRANSPARENT BODIES peated trials, and as it would have been impossible to replace them from the same source, the prosecution of the experi- ments with fresh oils, sold under the same name, might have introduced a new degree of uncertainty among the results. For all the purposes of the Practical Optician, the relative position of the substances, where it has been determined by experiment, is sufficiently accurate. Numerous combinations for correcting the secondary spectrum, may be formed, ei- ther by taking two media that have nearly the same ac- tion upon green light, while they differ in their powers of refraction and dispersion, or by adopting the ingenious method discovered by Dr Brarr, and fully described in the Transactions of this Society. In the production of perfect achromatic instruments, the optician cannot expect much more aid from the principles of optics. The great, and almost the only desideratum, is to obtain two kinds of glass, which shall have the same action upon green light, while they differ suffi- ciently in refractive and dispersive power; and it is chiefly from the labours of the Chemist, guided by the preceding in- quiries, that such a discovery can be expected. There is still, however, another source of error, of which neither the Theoretical nor the Practical Optician has hitherto been aware. It arises from a crystallisation in the glass, which is always accompanied with double refraction, and with a va- riation of density. This crystallisation, which most frequent- ly affects the flint-glass, and which can easily be detected by its action upon polarised light, should be carefully removed from every piece of glass used in the construction of optical instru- ments, by annealing it in an oven of a high temperature, where the heat is regularly and very slowly reduced. The ex- periments upon which this opinion is founded, will form the subject of another paper. TABLE UPON THE DIFFERENTLY COLOURED RAYS OF LIGHT. 23 TABLE of Transparent Bodies, arranged inversely according to their Action upon Green Light. 1 Om or Cassa. Sulphur. Sulphuret of carbon. Balsam of Tolu. ° & Carbonate of lead. Essential oil of bitter almonds. Oil of anise-seeds. Oil of cummin. Oil of sassafras, 10 Oil of amber. Acetate of lead melted. Opal-coloured glass. Orange. coloured glass. Red-coloured glass. 15 Oil of sweet fennel seeds: Oil of cloves. Muriate of antimony. Oil of lavender. Canada balsam. 20 Oil of turpentine. Oil of sage. Oil of pennyroyal. Oil of poppy. Oil of hyssop. 25 Oil of spearmint. Amber. Oil of lemon. Oil of caraway-seeds. Oil of nutmegs.. 30 Oil of thyme. Oil of peppermint: . Oil of bergamot. _ Oil of marjoram. Oil of wormwood. 35 Oil of dill-seeds. Oil of chamomile. . Castor-oil. Gum copal. - Rosin. 40 Diamond. Nitrate of potash« Oil of beech-nut. Oil of rue. Oil of savine. 45 Nut oil. Balsam of capivi. Oil of fenugreek. Oil of rosemary. Oil of rhodium. 50 Fuint Guass. Zircon. Oil of olives. Oil of rape-seed. Oil of spermaceti, 55 Oil of juniper. Oil of ambergris. Calcareous spar. Rock-salt. Gum juniper. 60 Tartrate of potash and soda. Oil of almonds, Crown-Guass. Gum-Arabic. Alcohol. 65 Ether. Borax, glass of. Borax. Tourmaline. Leucite. 70 Selenite... Beryl, . Topaz, blue. Fluor-spar. Citric acid. . 75 Malic acid. Acetic acid. Nitrous acid. Muriatic acid: Prussic acid. 80 Nitric acid. Rock. crystal. White of an eggs Ice. Water. 85 Super-sulphuretted hydrogen. Phosphorous acid. Sulphurous acid. Phosphoric acid. 89 Sunruuric Acip, IL. a: ay A NeFt reer vee aad us Tiere ‘nett a iets vee aim 5 REN Bh see re 4): — IL Description of a New Darkening Glass for Solar Observa- tions, which has also the property of polarising the whole of the transmitted Light. By Davin Brewster, LL. D- F. R. S. Lonp. & Enix. & F. A.S. Ev. [Read 1st May 1815.] T will be readily admitted by every person who has been accustomed to solar observations, that an apparatus for di- minishing the intensity of the sun’s light, without distorting or colouring the resulting image, is still a desideratum in Prac- tical Astronomy. Dr Herscuet is the only person who has given any degree of attention to this subject. When he applied his powerful telescopes to examine the surface of the sun, he found that the ordinary method of attenuating the light by smoked or colour- ed glasses, was of no avail; and it was in the prosecution of his experiments for determining the relative advantages of differ- ently coloured glasses, or of combinations of differently colour- ed glasses, that he was conducted to those splendid discoveries respecting the invisible rays, which have formed an epoch both in Chemistry and Optics. : Vou VAL. Tt D The 26 DESCRIPTION OF A NEW DARKENING GLASS The combination of coloured and smoked glasses which he found most effectual for diminishing the heat of the sun’s rays,. and at the same time preserving distinct vision, was extreme- ly complicated ; and after every attempt to improve it, he seems to have preferred another apparatus in which the light was transmitted through a mass of diluted ink contained in a trough bounded by plates of parallel glass. By this means he obtained an image of the sun as white as snow, and so very distinct, that, with a mirror nine inches in diameter, and the eye-piece open, he could observe the sun in the meridian for any length of time, without injuring either his eye, or the glasses of his eye-piece. Notwithstanding these advantages, this apparatus can never: be brought into general use, and can only be employed in in-. struments that are stationary. The necessity of frequently re- newing the ink, and the difficulty of retaining it in the trough,. are evils which are not easily remedied. The darkening glass which we propose to substitute in place of these contrivances, depends upon the diminution of light by two or more reflexions within a thick plate of parallel glass. The pencil, attenuated by reflexion, reaches the eye in the state of white light, while the direct rays transmitted through the plate are stopped by two pieces of metal properly disposed upon the opposite surfaces of the parallel glass. The nature of this contrivance will be understood from the following figure, where AB is a section of a piece of parallel glass, and C, D sections of two opaque plates placed on the upper and under surfaces of this glass. A ray of light RS, incident ob- liquely at S, will be transmitted in the direction aT, but is pre- vented from reaching the eye by the opaque plate D. A portion of this ray is reflected at a, and a second time at }, and emer- ges in the direction c V in a very attenuated state. The inten- sity TOR SOLAR OBSERVATIONS. Q7 sity of the pencil eV may be varied either by varying the thickness of the plate, or by R changing the angle of inci- dence ; and if it cannot be ren- dered sufficiently feeble by any of these means, it may be ex- posed to other two reflections at c and d, when it will emerge in the direction e W, having its intensity very greatly reduced. In order that the light may be freely reflected at the points a, 6, c and d, the opaque plates C, D must be kept at a little distance from the surface of the glass, and all extraneous re- flexion must be removed, by covering their interior surfaces with a black pigment. This may be done most conveniently by making the plates C, D rest upon the glass only by their margins. The aperture at S, where the light is introduced, should be of an elliptical form, so as to admit a cylindrical pencil at an oblique incidence. Hitherto we have supposed, the reflecting surfaces to be sn contact with air, so that the reflecting force is allowed to exercise its maximum action upon the incident rays. But it is very easy to diminish the reflective power, in any ratio that we choose, by introducing between the opaque plates and the glass a cement either of a greater or a less refractive power than the glass. By this means we obtain a degree of reflexion corresponding to a refractive power equal to the quotient of the greater refractive power divided by the lesser; and the re- flexion will be made either from the surface of the cement, or from the glass, according as the one or the other exercises the most powerful action upon light. As it may sometimes be difficult to procure a thick plate of parallel glass, we may substitute in its place two common D2 plates, 28 DESCRIPTION OF A NEW DARKENING GLASS plates, cemented together by a thin layer of indurated Canada balsam, or any other transparent substance, having the same refractive power. The rays of light will then pass from the, one plate into the other, without suffering either reflexion or refraction. This compound plate may even be formed of glasses of different colours, if we wish to produce a great de- gree of attenuation. The simple apparatus which has now been described, pos- sesses a still more valuable property than that of attenuating the incident light. The pencil ¢ V, which has undergone two reflexions, emerges completely polarised, unless when the angle of incidence is very small; and the polarisation continues complete, although this angle suffers a very considerable varia- tion. The other pencil e W is also polarised, and preserves this character, even when the angle of. incidence has a much wider range. If a plate of fine flint-glass is used in the construction of the eye-piece, we may employ it to great advantage in experiments on polarisation, even when the light has a moderate degree of intensity. But if the light of the sun is under examination, the eye-piece will possess the peculiar advantage, of at the same time attenuating and polarising the incident pencil. The polarisation of the emergent pencils c V, e W, enables us to explain a very perplexing anomaly in the law of the po- larisation of light by oblique refraction *. From numerous experiments made with piles of glass plates, I found that the tangents of the angles at which they polarised the transmit- ted light, were inversely as the number of plates of which the pile was composed. ‘The coincidence of this law, with the ex- perimental results, was extremely accurate when the number of plates was between eight and forty-seven, corresponding to a series * See the Philosophical Transactions, for 18}4, p. 223. } ‘ FOR SOLAR OBSERVATIONS. 2g series of angles between 41° 41’ and 79° 11’.. When the light was transmitted through one plate, it ought to have been pola- rised, according to the preceding law, at an angle of 88° 38’; but upon examining the image with a prism of calcareous spar, it did not vanish in any position of the spar, even when the incidence was greater than 88° 38’. A similar aberration from the law takes place when the pencil is transmitted through one, two, three, or four plates. In order to discover the cause of this anomaly, I made a great variety of experiments, without obtaining any satisfac- tory result ; and it was only by examining the phenomena of the polarising eye-piece that my attention was again called to the subject. We have already seen, that the pencils eV and and eW, are polarised in the plane of reflexion Sabcde. If we now remove the lower plate D, so as to per- - mit the direct pencil a@ T to reach the eye, the pencils c V, and. e W will be mingled with the pencil aT. When RS is inci- dent at an angle of 88° 38, the pencil aT ought to be com- pletely polarised, and ought to vanish in every quadrant, when examined with a polarising crystal. It is prevented, however, from vanishing, by the admixture of the pencils c V and e W, which are polarised in an opposite manner, and which will therefore remain visible when the whole of the direct pencil has vanished. As the angle of incidence diminishes, the in-- tensity of the pencils c V, e W suffers a very rapid diminution, while that of the direct pencil aT receives a corresponding augmentation. On this account, the oppositely polarised rays eV, eW form but a very small proportion of the compound pencil, and they are scarcely perceptible when the number of plates exceeds eight. The union of the reflected light with the obliquely refracted pencil, constitutes, therefore, the true cause of the anomaly which we have been considering. Il. : : cae gs 5 re Raped ma eenoal ws : “yn aaiisiied Se unghie aonb 38h ee me, : yop signe gppdlits oh "age r- te Naame * ; ‘ inten oe Hately dy . - 4 7 - , “ os - é. = : e — = St tine a VV. On the Lines that divide each semidiurnal Are into Six equal Parts. By W. A. gpa Esa. F. R. S. Lonp. & En. i [Read 3d June 1816.] ‘HE divisions of the day which different nations have em- i ployed, are denoted by hour-lines of various kinds on the ‘sphere. Of these hour-lines, drawn on.a supposition that ne- glects the inequalities of the Earth’s motiGe, there are three Jinds. _ The first kind, denotes hours counted from nis sot equal to each other at all, declinations of the sun. ‘These lines are great circles on the sphere, passing through the poles of the equator, and every pair intercepting a similar arc on each of the parallels. Of this kind: are the hour-lines of sidereal time, counted from the meridian, and the hour-lines of solar time, counted from the meridian. The second kind of hour-line denotes hours counted from the horizon, equal to each other in duration at all declinations of the sun. These lines are great circles which touch the greatest vi- sible parallel on the one hand, and the greatest invisible paral- lel on the other; each pair of these great circles cuts off a si- milar are from si diurnal arc. They are the horizons of different 62 ON THE ANTIQUE HOUR-LINES. different points of the parallel which passes through the ze- nith. The Italian hours counted from sunset, and the Ba- bylonian hours counted from sunrise, are denoted. by lines of this kind. The third kind of hour-line, and of which it is proposed to speak more particularly here, denotes hours varying in length as the declination of the sun varies, each hour being one-sixth part of the semidiurnal arc, whether that arc be a smaller por- tion of the circumference, as in winter, or a greater, as it is in summer. On the oblique sphere these lines are not great cir cles, and each adjacent pair intercepts @ dissimilar arc on each: semidiurnal arc. This kind comprehends the hour-lines of the- ancient Greeks and. Romans, which denote hours called hecte-. moria *, that is, sixth parts of the semidiurnal: arc. The curvature of these lines is visible when they are drawn on a globe; it is likewise seen in their gnomonic projection, in the following manner. Figure Ist is a perspective: view of the lines which intercept one-sixth part of each semidiurnal arc ; the point of sight is the centre of the sphere ; the plane of projection touches the sphere at the pole of the equator, and is therefore parallel to the equa- tor ; the latitude is 66° 30’; at this latitude the whole of each hectemorial hour-line is gone over by the sun in a year. This. perspective view is the same as the central or gnomonic pro- jection of the sphere on the inside of a plane which touches the sphere at the pole of the equator; it forms an inferior equi- noxial dial for the latitude 66° 30, when placed parallel to the equator, with its inscribed surface downwards, and the point xxiy. elevated. In * ‘Exlnudgio, sexta pars, sextarius, is used by Protomy. The lines that separate. the hectemoria from each other are in this paper called hectemorial lines, ta ON THE ANTIQUE HOUR-LINES. 63 In this view the projections of the parallels are circles, and equal arcs of the parallels are represented by equal arcs of their projections: the construction of the lines which intercept one- sixth part of each semidiurnal arc, is therefore performed by dividing the projection of each semidiurnal arc into six equal parts, and connecting each point of division with its corre- sponding points on the projections of the other semidiurnal arcs. . ‘In figure Ist, these hectemorial hour-lines are seen to con- verge at that point of the meridian which is marked 66° 30’. This is the point of contact of the horizon, and greatest unseen parallel ; it is s also the point where the.mid-day part of the me- ridian cuts the horizon. At this point the semidiurnal arc is indefinitely small, and therefore the lines which divide it into _ six parts must be indefinitely near to each other, or, in other words, must converge. At this point of convergence each hectemorial line is incli- ned at a considerable angle to the meridian. As the line pro- ceeds, the inclination becomes less, till it is nearly as small as the inclination of the astrenomical hour-line, which this hecte- morial line cuts at the equator; and the hectemorial line on this projection is asymptotic with that astronomical hour-line. For the distance of their intersection from P, measured on the plane of projection, is infinite, being equal to the distance of the intersection of the equator and plane of projection, two planes parallel to each other ; and however far the projection is extended, the two lines approach indefinitely, but do not meet. Take, for example, the third hectemorial line HS (in the figure on the margin) which cuts the ninth astronomical hour- line at the equator; the projection of a great circle which in- tersects the ninth astronomical hour-line at the equator, is a straight 64 ON THE ANTIQUE HOUR-LINES. straight line parallel to the ninth astronomical hour-line on this projection; but the third hectemorial line is continually approaching to the ninth astronomical hour-line ; the distance- between them at the horizon being HD = are. 45° x tan. polar distance, and afterwards it is (arc 45° —'} semidiurn. arc) X tan. polar distance of the star ;\ + semid. are increases, but never at- tains to be 45°, so that the distance never becomes equal to. nothing, and tan. polar distance increases indefinitely. All great circles are seen under the form of straight lines in this projection of the sphere ; and therefore the projection of one great circle cannot be an asymptot to the projection of another ; it follows, that the projections of the hectemorial lines are not projections of great circles.» Ifa straight line be drawn through the point H, (in the figure on the margin,) cut- ting off a given aliquot, one-half, for example, from a semi- diurnal are on the projection, it will cut off a smaller aliquot. from the meridional extremity of the other semidiurnal arcs, in proportion as they are nearer to the point H; and in order that a straight line drawn from H may cut off the same aliquot part from several concentric arcs which are included. between the versed sine HN and sine HO of the outer arc, it is necessary that the chords of these arcs be parallel to each other; which happens ‘only in the case where all the arcs are of 90°, then H coincides with P, and then the straight line which cuts off the same aliquot from every arc, is a line passing through P the centre ; and this sole case is a central projection of a sphere so placed, that each semidiurnal arc is 90°, the poles of the equator being in the horizon. In ‘this position alone are the ey hectemorial ON THE ANTIQUE HOUR-LINES. 65 hectemorial lines great circles, and in this case they coincide with the astronomical hour-lines, and pass through the poles of the equator. When the poles are thus in the horizon, all the three kinds of hour-lines coincide. When the pole is in the zenith, the second kind or horizontal, and the third or hectemorial hour-lines cease to be, because then the horizon does not cut any of the parallels into diurnal and nocturnal arcs. To express algebraically some of the above-mentioned pro- perties. Let the abscisse 2 be taken on the meridian HM, and the ordinates y at right angles to the meridian, the cen- tral projection g gives n : ay SIN. 63 tan. polar dist. star, se si Or OFT... 8 n ee . “= | COs. & S—COS. 8 i tan. pol. dist. star. es i hee P oy) PH is cos. ; the cosine of the semidiurnal arc. PM is cos. rae iv } + ‘ the cosine of the fractional part of the semidiurnal arc. MS Bee: : ; is sin. & 8; the sine of the fractional part of the semidiurnal arc, PS is tan. pol. dist. star ; the tangent of the polar distance ~ of the star. m is one of the numbers 1, 2, 3, 4, 5; it is 5 for the curve that contains the first and eloton tie hectemorial line ; 4 for the second and tenth, and so forth. it n sin. = vie hes is not tl tion of a straight li - s not the equation of a straight line, except “COS. 6 7. 5—COS. Sik in the case where cos. s = 0, that is, whet the semidiurnal arcs are all 90°, the poles being in the horizon. Vou. VIL P. I. I go 66 ON THE ANTIQUE HOUR-LINES. Liat 0 sp : : y = sin. G5 tan. pol. dist. in this equation, when the describing diameter arrives at H, sin. g°= 0, that is, the curve cuts the axis of the absciss2 at H, and when the describing diameter ‘ ee : passes onward, the sign of e538 changed, expressing that there: are two similar and equal branches, one on each side of the axis of the abscissz. n ee Cos. 6° has only one value, because g ° 18 never so great as 90°, and its cosine, therefore, does not Recore =9@ which: it must do before its sign changes. If a central projection of any one forenoon hectemorial hour- line, and of the afternoon hectemorial line equi-distant from: the meridian, be drawn for different heights of the pole,, it will be seen that these two hectemorial lines form for each height of the pole an equicrural curvilinear branch, including within it the cor- responding hectemorial lines for a higher latitude, and all of them included mci two astro~ ifaraieal hour-lines as asymptotes. With these asymptotes the pair of hectemorial lines coincides, when the poles are in the horizon. The figure in the margin represents the equicrural curves formed by the: third hectemorial hour-line and by the ninth, which is the afternoon branch equi-distant from the me- ridian. The curved branches are drawn for every ten degrees of la- titude from 30 to 70 inclusive ; the rectilinear asymptotes with- in. ON THE ANTIQUE HOUR-LINES. 67 in which the curves are contained, are the ninth and fifteenth astronomical hour-line counted from midnight. From figure Ist it may be collected, that the asymptotes of each hectemorial line are as follows : (! The equicrural curvilinear branch, | has for asymptoles the astro- | which compre- | composed of the hectemorial lines nomical howr-/ines, counted | hend an angle From midnight, of First A,and Eleventh IA,) VII. and XVII. 150° Second B,andtenth I,} VILL. and XVI. 120° Third Tr, and ninth ©,) IX.and XV. 90° | Fourth A, and eighth 4, X. and XIV. 60° Fifth, E, and seventh Z, XI. and XIII. 30° “aoe Figure 1st represents the portions of the day hectemorial lines which touch the greatest invisible parallel for the latitude 66° 30’; these are the winter portions. In-order to delineate the portions which touch the greatest wholly visible parallel, or the summer portions, the projection is made on the plane which touches the sphere ‘at the depressed pole ; this projec- tion is exhibited in figure 2d, which contains portions of curves, each of which is similar and equal to the curve of the sane hour in figure Ist, but differently placed. It forms a su- perior equinoxial dial for 66° 30’, when placed parallel to the equator, with the inscribed surface upwards, and the a XXxiv. elevated. Th tia - However extended the plane of projection touching the sphere at the pole be, still it will not contain the portions of the hectemorial lines that are near the equator. To have these, the plane of projection is taken at right angles to the equator, in touching thie Saaunig at the depressed intersection of the ms Tern 12 equator 68 ON THE ANTIQUE HOUR-LINES. equator and meridian. This projection, which is drawn at figure 3d, contains some of the hectemorial lines from the point of their contact with the greatest wholly unseen to the points of their contact with the greatest wholly seen parallel. It forms a polar dial for the latitude 66° 30, when placed parallel to the plane of the sixth astronomical hour-line. The lines thus drawn in the above projections are curved ; consequently they are not the projections of great circles ; nei- ther are they the projections of small circles, for if they were, they must necessarily touch the horizon at its intersection with the mid-day portion of the meridian, because in that point the hectemorial lines converge, and do not go on the other side of the horizon. Now, if small circles so placed, be drawn on the sphere or projected on a plane, it will be found that their course deviates entirely from the course of the lines bounding the hectemoria. The hectemorial lines, therefore, do not coin- cide with small circles on the sphere, nor with conic sections; on the central projection. ‘The projections above exhibited shew that each pair of hee- temorial lines for a given meridian and latitude, is an equicru- ral curved line ; but this is only one branch of an entire curve, because the diameter whose extremity has traced a pair of these lines on the surface of the sphere, has still to complete its revolution, which is.done when it has arrived by progressive and continuous motion at the point from which it set out. In order to accomplish this with the same kind of motion with which they described the first branch, the extremities of the diameter leave the two parallels that touch the horizon, and proceed to cut off the same aliquot part from the semidiurnal arcs belonging to this second point of departure, as they had done from the semidiurnal arcs of the first point of departure ; the second point of departure is to be considered as the mid- day point of a horizon on the opposite side of the equator to the ON THE ANTIQUE HOUR-LINES. 69 the first. The extremities of the diameter, after having in this way passed several times to and fro between the greatest whol- ly unseen and the greatest wholly seen parallel, aud after ha- ving completed one or more circumferences, attain precisely the two opposite points from which they set out, having form- ed two opposite re-entering curves on the surface of the sphere, and afterwards, in every subsequent revolution, the extremities of the diameter only retrace the lines they had described in their first revolution. The nature of the motion is such, that the describing points cannot go beyond the two parallels which touch the horizon, because there are no semidiurnal arcs be- yond these parallels, and the constitution of the hectemorial lines, consists in cutting the semidiurnal arcs. Whilst the extremities of the diameter describe two re-en- tering curves on the surface of the sphere, the diameter itself describes two opposite re-entering curved surfaces, whose com- mon vertex is the centre of the sphere. These two opposite sur- faces coincide with a straight line directed to the vertex, but do not coincide with a straight line in any other direction. In this respect they resemble a conical surface, and they may be considered as a kind of opposite cones with an undulated sur- face, included between the outer surfaces of the two opposite circular based cones that touch the horizon; the apex of each undulation being applied alternately to the one and to the other of these right circular based cones, so that as the com- mon vertex of all these cones is the centre of the sphere, each _of the two opposite undulated cones has two similar and equal _ bases or right sections, the one above the centre of the sphere, _the other below it. Each of these bases is an uninclosed curve, - composed. of many equiecrural branches, each equicrural branch haying for asymptotes two straight lines that intersect in the »axis ; these two right sections are indefinitely extended ; and the 70 ON THE ANTIQUE HOUR-LINES. the bicrural branches of one right section are alternately placed in respect to the branches of the other right section. The undulated cone belonging to each of the five hectemo- rial lines is different from that of the others. The five upper bases are represented in figures 4th, 5th, 6th, 7th, and 8th, drawn according to the rules of the central projection, on a - plane parallel to the equator, for the latitude 66° 30... The full lines are the upper base of one of the two opposite undu- lated cones; the dotted lines are the upper base of the other opposite undulated cone. These bases or right sections are each made up of a pair of hectemorial lines for a given lati- tude, forming one equicrural branch, and of similar and equal pairs for other points of the same panei of latitude and of the opposite parallel. In order to present to the eye the image of one of the un- dulated cones, figure 9th is drawn. It is a shaded view of one of the two opposite conical surfaces to which the 3d and 9th hectemorial lines belong, for the latitude 66° 30’. The point of sight is in the plane of the equator; the distance is two dia- meters from the centre of the sphere. The sections of the undulated cones, by a cylindrical seeds circumscribed round the equator, are made up of the same branches ; they are complete and re-entering, whereas the sec- tions by a plane are always incomplete. These cylindrical sections are laid down in figures 10th, 11th, 12th, 13th, and 14th. The cylindrical surface is here unrolled ; when restored to its cylindrical form, the inscribed curve is re-entering, and without a break. Where the number of degrees between the upper apices of each undulation is a divisor of 360, the undulated cone is com- pleted in one circumference, because at the beginning of the second circumference, the generating diameter enters into the path ON THE ANTIQUE HOUR-LINES. 71 path it had described in the first; this is the case with the three undulated cones which contain the third, fourth and fifth hectemorial lines, figures 6th and 12th, 7th and 13th, 8th and 14th. ‘The number of degrees between the meridians of two adja- cent upper apices, is equal to twice the distance between the two adjacent sides of each undulation measured on the equa- tor, or to four times the distance of the equatorial point of the hectemorial line from the meridian measured on the equa-. tor. : Where this number of degrees between the meridians of tlre upper apices is not a divisor of 360, but of a multiple of 360, the revolution is completed in as many circumferences as there are units in that multiple; because the generating diameter does. not enter into its former path till it has described that number of circumferences. The undulated cone which con- tains the second and tenth hectemorial lines, having an inter- val of 16 equinoxial hours, or 240° between the adjacent up- per apices; the describing diameter completes. its: revolution, and comes to the point from which it set out at the end of two circumferences or 720° ; the number of the upper apices being 3, which, multiplied by 240, is equal to 360 x 2; this is seen in figures 5th and 11th. The undulated cone which contains the first and eleventh hectemorial lines, figures 4th and 10th, having an interval of 20 equinoxial hours, or 300° between the upper apices of the. undulations, the describing diameter must go over five circum- ferences before it comes to. the point from which it set out, be- cause 300 multiplied by 6, which is the number of upper api-. ces, is equal to 360 x. 5.. gi, The eh ON THE ANTIQUE HOUR-LINES. The circumstances of each of the undulated cones with re- spect to the number of undulations and of circumferences, are as follows : | The undulated cone containing hectemortal lines —$ ———S- ————- In degrees. First A, and eleventh IA,| 300 Second B, and tenth 1,| 240 Third T, and ninth @,| 180 Fourth A, and eighth H,| 120 Fifth E, and seventh = Z, 60 o the | intercepts between two adjacent upper apices, a In equinoc- tial hours. 20° 16 12 8 4 of upper apices 1s Awnw a” —— —— | The number | The number of circumferences in which a revolu. | tion is completed, ts, Hee bo & Four of the five undulated cones have opposite and similar undulated cones, formed by the remote half of the generating diameter; but in that undulated cone which contains the fourth hectemorial line A, and eighth H, the two opposite un- dulated cones coincide in one, as is seen in figures 7th and. 13th. The algebraic formula expres- ses the different branches of the right section of the undulated cone, by the change of sign of tan. pol. dist. in the values of @ and y; n : TS cosgs—cos8)) tan. pol. dist, y = sin. stan. pol. dist. For example, in the right sec- tion of the undulated cone which contains the third and ninth hec- temorial —+- ~ ON THE ANTIQUE HOUR-LINES. | 13 temorial lines, the radii from the centre P’ are = tan. poi. dist. and the co-ordinates are affected by that quantity. Ifthe gene- rating diameter GKR move in the direction of the dart, and set out from I; it describes the curvilinear branch A, and tan. pol. dist. is positive till the generating diameter come to the situation II, where it is infinite. If its revolution be continued, it re-appears at ITI, on the other side ofthe centre with the nega- tive sign, and gives the curvilinear branch B; at IV. it is again infinite, and re-appears positive at V, going on to form the curvi- linear branch C; at VI. it is infinite; and at VII. it becomes negative, and forms the branch D; it then comes out positive at I, and goes over its former path. ‘The way that the change of sign takes place is apparent, by considering that whilst the diameter is moving in the direction of the dart, it has another motion at right angles to the plane of projection. Let GPK be a section of the generating sphere, at right angles to the plane of projection; NPR being the section of that plane ; GKR. is the generating diameter; and when in the position GKR, then tan. pol. dist. = PR, ne is positive ; when GK is: parallel to PR, then tan. pol. dist. is infinite. If the motion in this plane be continued, tan. pol. dist. passes to the other side of P, as at PN, and is affected with the contrary sign. Most of the writers who have spoken of the hectemorial lines, have treated them as great circles, because their intertro- pical parts, at a moderate height of the pole, coincide sensibly with great circles; and it is. this case with which. authors had to do in ep a the gnomonic projection of the hectemo- rial lines for the climates of Greece or of Italy. The writings of a considerable number of authors on this subject have been consulted, and they all take the hectemorial lines. for great circles, except Cravius and Mowrucia. Cxavius demonstrates that the antique hour-lines do not coincide with great circles; Vor, VIII. P. 1, kK and: 74 ON THE ANTIQUE HOUR-LINES. and Monrucra merely states, but without discussion, that they are curves of a peculiar nature *. It has been shewn above, chiefly by means of a paced on a plane touching the sphere at the pole, that the hectemorial hour-lines on the oblique sphere are not great circles; and be- cause the describing diameter, in order to form a continuous and uniform surface, must go on moving during its whole re- volution with that motion which it had in the beginning of its course, and must be always included between the two parallels that touch the horizon, it is concluded that the curved surface whase * The passages from Cravius and Montucta are as follows: Crarix Astrolabium lib. i. lemma 39. “ Circuli maximi transeuntes per horas inequales A¢quatoris, et duorum paratlelorum oppositorum, non necessario per horas inzequales parallelorum intermediorum transeunt in sphera obliqua.” He gives a demonstration of this, and concludes, in the scholium, that in order to de- lineate the antique hours with strict accuracy, a considerable number of the se- midiurnal arcs are to be divided into six parts, and the corresponding points of division joined. Monrvcra, Hist. des Math. tom i, edition de 1758S: ‘ Les lignes de ces sortes Wheures {les heures antiques] ne sont point droites comme les precedentes, mais courbes, et meme d’une forme tres bizarre ; de sorte qu’on ne peut les decrire qu’en determinant plusieurs points de chaewne; la maniére de les trouver se pre- sentera facilement a tout geometre ; c’est pourquoi nous ne nous y arretons pas.” The circumstance mentioned in the beginning of the paragraph to which this note refers, has led the celebrated and profound astronomer Deramere to con- trovert the opinion of Monructa in the following words: “ Monrtucta dit, en parlant des heures temporaires antiques, qu’elles sont courbes, et méme d’une forme tres bizarre, &c. Hist. des Mathem. tom i. On ne congoit pas com- ment une pareille inadvertance a pu echapper 4 un homme aussi instruit ; car si la surface est spherique, ces lignes seront des grands cercles; et si la surface est plane, elles seront des lignes droites, puisqu’elles seront les intersections des plans de ces grands cercles avec le plan du cadran.” Detampre sur un cadran“anti- que trouvé dans Visle de Delos, et par occasion de la gnomonique des anciens ; noz tice lue & la classe des Sctences Physiques et Mathematiques de [Institut Royal de France, le 10 Octobre 1814. ON THE ANTIQUE HOUR-LINES. 15 whose section contains the hectemorial line, isa kind of undu- lated conical surface; and the right sections of the surface are two infinite unenclosed bases, one’on each side of the vertex of the undulated cone. This section, at right angles to the axis, consists of several bicrural branches, varying in number as the cone belongs to each different hectemorial line. Of the Gnomonic Instruments of the Ancients. The object of the preceding pages has been, to treat of the eurves to which the hectemorial lines belong. As an appen- dix, it may not be improper to enumetate some of the remains of art which contain the antique hour-lines ; for these hour-- lines are the intertropical parts of the hectemorial lines. Se- i i Saag of these gnomonic instruments exist. The first to be ‘mentioned, and the most perfect, are the: eight sun-dials on the Tower of Andronicus Cyrrhestes, at A- thens. They appear to have been coeval with the building, and to have formed part of the original design, as may be in- ferred from the care with which they are'delineated, and from the greatest part of the surface of the wall being left plane to receive the lines. This tower’is mentioned under the denomi- nation of horologium by Varro, who flourished in the 85th year before the Christian era; it is also spoken of by Virru- vius. The carefully wrought channels, and cylindrical cavities in the pavement, and the cylindrical chamber at the south side, have led to the conjecture, that, béfides serving to shew the: hour when the sun was shining on it, the tower was formed to. contain some machine of the nature of the clepsydra, whereby the hour might be known at all times for the use of the city.. Another of the destinations of this tower was to indicate the K 2 direction: 76 ON THE ANTIQUE HOUR-LINES: direction of the wind. Tach of the eight dials is exposed to one of the eight principal equidistant points of the horizon ; two of the dials being parallel to the plane of the meridian, The radii of the spheres from which the dials are projected, vary ; the smallest being about eight inches, and the greatest about twenty-five inches. In Sruart’s Antiquities of Athens, the building and the dials are represented in detail. The second example of the gnomonic lines of the ancients, js in the valuable collection of antiquities brought from Athens by the Earl.of Ereiy. It consists of four vertical dials, two of which are nearly south-east, and two nearly south-west in azi- muth. They are inscribed on a block of white marble, which bears the maker’s name. The radius of the generating sphere is about four inches and a half. The third example, is a projection of the antique hour-lines on the inner surface of a cone whose axis is parallel to the axis of the earth. It exists at Athens, and is figured by Sruarr. The fourth is a small east dial, on a vertical plane, described by DrvaMsre. It was found at Delos. The radius is half an inch. The fifth is a piece of Roman workmanship, figured by Bors- sarp *. It is composed of five dials on the upper part of a squared block of marble ; three of the vertical sides of which are covered with an ancient Roman agricultural calendar. In like manner, the treatise of Paruaprus de Re rustica, which is a set of agricultural directions for every month, contains a gno- monic table, shewing the length of a man’s shadow for each month, and for a climate in Italy. Some * Borssarv1 Antiquitates Romane. ON THE ANTIQUE HOUR-LINES. q7 Some. fragments of ancient dials, are also published by Grx- wius *. Except the table of Pariapis, the instruments above men- _ tioned are each made for an unvarying azimuth. In the de- scription of the antiquities of Herculaneum +, there is repre- sented and explained a dial whose azimuth is changeable, to suit the hour and the different declinations of the sun. It jis drawn on an irregularly curved surface of bronze, and the de- clinations are marked with the Roman names of the months. The ancient names of different kinds of fixed and moveable sun-dials, with the names of their inventors, are given by Vi- TRUVIUS. Something respecting the time of the first introduction of gnomonic instruments, is to be collected from Greek and Ro- man authors. The ancient inhabitants of Egypt appear to have cultivated astronomy at a time prior to the earliest histo- rical accounts ; and they have left a monument of their practi- cal skill in that science, in the accurate meridional position of these most ancient of human works the Pyramids. Portions of their knowledge were diffused amongst the Hebrews and Babylonians. , The astronomical science of the Greeks was derived partly from the Egyptians, and partly from the Babylonians {. Tua- Es || acquired his knowledge of astronomy and geometry from the Egyptian priests, and introduced these sciences into Greece. The gnomonic projection of the sphere is a branch of the doctrine of spherical astronomy, and when applied to the * Graevu Thesaurus Antiquitatum Romanarum. + Le Pitture antiche d’Erculano, tom. iii, Napoli 1762. + Heroporvus. > }| Diogenes Larrtivs. 78: ON THE ANTIQUE HOUR-LINES, the purpose of shewing the parts of the day, constitutes the Sun-dial, an instrument which may be supposed to have come: into use soon after the introduction of astronomy. According to Driocenes Larrtius and Pury, the first gnomonic instru- ment that appeared in Greece was constructed by a disciple of Tuaxes, about the 545th year before the Christian era, and 115 years before the death of Prricres. SaumaisE * contends, that this instrument was for the use of astronomers only, and that sun-dials did not come into general use in Greece till 200 years after, that is, a short time before the age of ALEXANpER. The Romans got their first sun-dial from one of the Greek cities of Sicily +, 260 years before the Christian era ; and for nearly a hundred years after, they possessed no artist acquaint- ed with the principles of the instrument, so as to construct one: adjusted to the climate of Rome.. 3 * Sapmasi Pliniane Exercitationes; + Puinn Hist. Naturalis. Explanation ‘ON THE ANTIQUE HOUR-LINES. 79 » Explanation of the Figures. Central Projection of the Twelve Hour-lines, Figure ist do Figure 3d. Figure. 1st, Is a central or gnomonic projection of the hecte- morial lines or antique hour-lines, on the inside of a plane touching the sphere at the elevated pole of the equator. This and all the other figures are drawn for the latitude 66° 30. Each antique hour-line is marked with the Greek numeral that belongs to it, Figure 2d, Is a central projection of the summer Ne se of these lines on the inside of a plane touching the apbere at the depressed pole of the equator. The circle placed between figure Ist and figure 2d is a great circle of that sphere from which all the projections jap these. figures (except figure 9th) are formed. Figure 3d, Is a central projection of the hectemorial lines on a .. plane touching the sphere at the depressed intersection of the meridian and the equator. yo Be of 1 the five undulated Cones which contain the antique hour. lines, by a plane at right angles to the avis, figure 4th ‘to figure 8th. Figure 4th, Is a section at right sie to the axis of the un- dulated conical surface, which contains the first antique »hour-line A, and eleventh 1A. In this and the other fi- gures, the full lines are the section of one of the two op- posite cones, and the dotted lines are the section of the other. 50. ON THE ANTIQUE HOUR-LINES. other. The section of the same undulated cone by a cy- lindrical surface, is seen in figure 10th. Figure 5th, Is the right section of the undulated cone whicli contains the second antique hour-line B, and tenth I. The section, by a cylindrical surface, is seer at figure 11th. Figure 6th, Is the right section of the undulated cone which: ao * contains the third antique hour-line T, and ninth ©. Its section, by a cylindrical surface, is figure 12th. A per- spective and shaded view of this undulated conical sur- face is figure 9. } Figure 7th, Is the right section of the undulated cone which: contains the fourth antique hour-line A, and the eighth H ;, figure 13th is its section by a cylindrical surface. Figure 8th, Is the right section of the undulated cone which contains the fifth antique hour-line E, and the seventh Z.. Figure 14th, is its section by a cylindrical surface. Perspective and shaded wiew of one of the Surfaces, figure 9th. Figure 9th, Is a perspective and shaded view of the undulated’ conical surface which contains the third antique hour-line Tr, and ninth ©; the point of sight is in the plane of the: equator, and the distance of the eye is two. diameters from. the centre of the sphere ; in this view only one of the two. opposite surfaces is drawn. The right section of these opposite cones is figure 6th, and their section by a cylin- drical surface is figure 12th. Sections: a NO THE ANTIQUE HOUR-LINES. 81 Sections of the five undulated Conical Surfaces by a Cylindri- cal Surface, figures 10th to 14th. Figure 10th, Is the section of the undulated cone which con- tains the first antique hour-line A, and eleventh IA, by a cylindrical surface touching the sphere at the equator. To avoid intricacy in this figure, the section of only one: of the two opposite cones is drawn.. Figure 4th is the: right section of the two opposite surfaces.. Figure 11th, Is the section of the undulated cone which con- tains the second antique hour-line B, and tenth I, by a cy- lindrical surface. The full line is the section of one of the two opposite cones; the dotted line is the section of the other. Fig. 5. is the right section of this surface. Figure 12th, Is the section of the two opposite surfaces which. contain the third antique hour-line I, and ninth 0, by a cylindrical surface. Their right section is figure 6th ; and one of these two opposite surfaces is represented in per- spective, and shaded at figure 9th. ee: Figure 13th, Is the section of the undulated cone which con- tains the fourth antique hour-line A, and eighth H, by a cylindrical surface. In this itdutieea cone, the two op- posite conical surfaces coincide in one: there are therefore no dotted lines, neither on this figure, nor on figure 7th, which is the right section of this undulated cone. Figure 14th, Is the section of the undulated cone which con- tains the fifth antique hour-line E, and seventh Z, by a cy- lindrical surface, “Figure 8th, is the right section of the same. Vot. VIII. P. I. iy V. “Wotooe oh 0 ae ds. "to, Gating, ih PLATE I. Engraved for the Royal Society Trans" Vol 8.page 82. Ze Oe - wn Engraved by WaD tears Edin? PLATE Il. Engraved. tor the Rapal Society Trans’ Tol b page 82. Fig. 7 fe Se 7 ee eee r,@ —*< Se -—— shes 5 ed wK Co ( Le K Ar <"| Engraved by WA DLguare dial ' — ~ ~ — Y. On the Origin of Cremation, or the Burning of the Dead. By Joun Jamurson, D. D. F. B.S. & F. AS. E, (Read April 3. 1815.) S far as we can judge from historical records, the primevat mode of disposing of dead bodies, was by inhumation. It has been observed in another essay, that according to Puuyy, the ancient Romans did not burn their dead, but consigned them to the earth *, It must be admitted, however, that by some the mode of cremation had been preferred in a very ear- ly period of their history ; as we cannot otherwise account for the prohibition, which Piurarcn ascribes to Numa, as to the burning of his body. If we may eredit the testimony of Crcz- Ro, the Greeks, during the reign of Crcrors, inhumated their dead +. The same mode of interment is attributed, by xian, to the Athenians |; and by Priurarcu to the Greeks in genes. ral ||, It is well known that Cecrors and Danaus, who brought iL 2 colonies * Pury. Hist. Nat. lib. viii. ¢. 54, _t De. Leg, lib. ii. + Var. Hist, lib. v. 14.3 vii. 19, || In Vit. Soroy, 84 ON THE ORIGIN OF CREMATION, colonies into Athens and Argos, were Egyptians ; and general- ly admitted that Capmus, who founded Thebes in Beeotia, was a Phenician. It may therefore be conjectured, that as neither the Egyptians nor the Phenicians burnt their dead, while the me- mory of these illustrious men retained any considerable influence, the colonies planted by them would strictly adhere to the rites of sepulture which they had introduced ; especially as these had been sanctioned by the authority and example of their an- cestors, in the countries from which they had migrated. From the institutes of Lycurcus it is evident, that, in his time, the ancient mode of inhumation prevailed among the Spartans. For he enacted, that the dead should be deposited in the earth, wrapt in a covering of scarlet cloth, and surrounded with olive leaves *. It seems to be generally believed, that, in later ages, the Greeks universally burned their dead. Lwucran, indeed, as Porter has remarked in his Archeologia, expressly assigns cre- mation to Greece, and inhumation to the Persians}. But this must be understood with great latitude. From the language ascribed by Prato to Socrates, it appears, that both these modes had been promiscuously used in his time, according to the predilection of individuals. For he speaks of it as a mat- ter of indifference to him, whether, after his death, his body should be burned or buried. The language of /Zt1an would - imply, that inhumation had continued to be the general prac- tice at Athens. For he says, “ It is an Athenian law, that if “ any one accidentally meet with the corpse of a man not bu- “* ried, he shall cover it entirely with earth; and that the dead “ shall ® Prurarcn. in Vit. Lycure. t Aucrcpesvor ncerce 20yn res Ta Peec, o wiv EAAny, aveey. ade Megons, ebatev, &c. Lucian. de Luctu, Oper. ii. 306. edit. Amstel. 1687. OR THE BURNING OF THE DEAD. 85 * shall be buried so that they may look towards the west *.” Both these institutes obviously preclude the idea of crema- tion. But although, in some of the Grecian states, the ancient cus- tom seems to have long retained its influence, it cannot be de- nied, that, according to Homer, the mode of burning had been yery common among the Greeks before the time of the Trojan war. From the particularity with which he describes the fune- ral rites of Parroctus, in the twenty-third book of the Jliad, there is no reason to suppose that he viewed them as even at that time a recent institution. It would appear, indeed, that the Phrygians were acquainted with this custom before it was received by the Greeks +. But it can scarcely be supposed, that the Greeks borrowed it from them, either during the Trojan war, or in any preceding era. It is far more probable, that it had made its way from Thrace, where it unquestionably prevailed in an early age { ; especial- ly as it cannot reasonably be doubted, that a considerable, if not the greatest part of Greece, was peopled from that coun- try. The Thracians, most probably, received this custom from their progenitors the Scythians, who inhabited those vast re- _gions now known by the name of Tartary. As the people of ' that country, apparently in the most remote ages,.erected very large tumuli in honour of the dead, it is undeniable, from the remains found in those which have been explored by the Rus- sians or Tartars, that, in many instances at least, they burned their bodies. Mr Tooxe, indeed, informs us, that no sepul- chral urns have been discovered in any of these tombs. “ Of * Aun. Var. Hist, lib. v. c. 14. + Azex. ab Anexanpro, Gen. Dies, lib. iii. c. 2, t Heropor. Hist. Terpsicn. c. 8. 86 ON THE ORIGIN OF CREMATION, “ Of these Russian and Siberian sepulchres, some (he says) are encompassed with a square wall of large quarry stones, placed in an erect position; others are covered only with a small heap of stones, or they are tumuli adorned at top. In many of these sepulchres the bones of men, and frequently of horses, are found, and in a condition that renders it pro- bable the bodies were not burnt before they were inhumed. Other bones shew clearly that they have been previously burnt ; because a part of them is unconsumed, and because they lie in a disordered manner, and some of them are want- ing. Urns, in which other nations of antiquity have deposi- ted the ashes of their dead, are never met with here. But sometimes what remained of the bodies after the combu- stion, and even whole carcases, are found wrapped up in thin plates of gold—There is a very remarkable circumstance observable in some of the tombs on the upper part of the Yenisei, which forms an exception to the general rule of other sepulchres. Instead of ornaments and utensils of gold and silver found in other tombs, you meet here only with copper utensils, Even such instruments as would have been better wrought of iron are here found all of copper, as knives, darts and daggers. The nation, therefore, whose dead are here inhumed, seems to have been unacquainted with the use of iron; and these tombs must accordingly be more ancient than the others *.” This learned writer seems himself to admit, that some of these monuments are far more ancient than others; and gives an indubitable proof of the high antiquity of some of them, when he remarks, that all the instruments found in them were made * Account of the Burial-places of the ancient 'l'artars, by the Reverend Wix- siam Tooxe, F.R.S. Chaplain to the English Factory at St Petersburgh, Ar- chaologia, vol, vii. p. 223, 224. OR THE BURNING OF THE DEAD. 87 made of copper; whence he reasonably concludes, that the use of iron had been unknown in those regions when these monu- ments were erected. This might seem to carry us as far back as to the times of the Massagetz ; who, as we learn from Hr- Ropotus, used no iron, having all their weapons made of brass *. From the same venerable historian, we learn the great respect which the Scythians had for the tombs of their ances- tors. That intelligent traveller SrranLenzerc informs us, that these monuments contain earthen urns of different sizes f. He does not say, however, that bones have been found in any of them. It affords a strong presumption that many tribes of the Scythians anciently burned their dead, that the Chinese Tartars, who are said to be the descendants of those Scythians whose tombs are to be seen on the river Jenisei, still retain this mode ft. Perhaps the first notices which we have of this custom, in ancient history, occur in the slender accounts that have been handed down to us concerning the manners of some of the na- tions of Hindostan. How early they burned their dead we are not informed. But we certainly know, that, before the time of Axexanver of Macedon, they erected funeral piles for the li- ving. Quintus Curtius, from Troeus, asserts, that those who were called Wise Men, when they saw the infirmities of age _ approaching, ordered their pyres to be raised, and cheerfully devoted themselves to the flames §. The same thing is assert- ed by Ciemens of Alexandria concerning the Gymnosophists. Speaking "Ove piv yap & ctingecs nae) dedeis nde cooydeuis, ywrnol rec medvree xeewvras. Clio, c. 215. 4p Description of the North and East parts of Europe and Asia, p. 364, 365, t Ibid. p. 365. 367. § Hist. lib. viii. 88 ON THE ORIGIN OF CREMATION, Speaking of those who unnecessarily exposed themselves to de- struction, under the false idea of being martyrs, he adds, ‘ In « vain do they give themselves up to death, as the Gymnoso- phists of India rashly cast themselves into the flames *. As it is acknowledged even by heathen writers, that the most ancient mode was that of inhumation, a question natural- ly occurs, which, although from deficiency of evidence it may be impossible to solve in a satisfactory manner, affords ample ground for curious and interesting disquisition. It is this ; Whence might the practice of cremation originate ? or, in other words, What could induce men, in opposition to the feelings of nature, to devote the mortal part of this frame, which they had cherished so tenderly during life, as far as possible to appa- rent destruction, after the departure of the spirit ? By the primitive Christians it was objected to cremation, that the practice involved in it the idea of inhumanity to the body. Hence Terruriian having remarked, that some of the gentiles disapproved of the mode of burning, because they wached to spare the soul, which hovered over the body after death, subjoins, “ But we have another reason,—that of piety, “ not as flattering the reliques of the soul, but as detesting * cruelty even to the body; because, being itself man, it does * not deserve. to be subjected to a penal death f.” In another . place, * Cuvara dt taurde drod:doace neva, noibdmreg xxi or Tay LddY yrpevorePiscel porrecies mugl. emt) 02 Si Yevdaryeos ore TH capex Oiabwcrrect, &c. Crem. ALEXANDR. Strom. lib. iv. p. 351. edit. Lugd. 1616. + Et hoc enim in opinione quorundam est ; propterea nec ignibus funerandum aiunt, parcentes superfluo anim. Alia est autem ratio pietatis istius, non reli- quiis anime adulatrix, sed crudelitatis etiam corporis nomine aversatrix, quod et ipsum homo non utique mereatur poenali exitu impendi. Trrtuxnuian. de Anim. c. 5k. OR THE BURNING OF THE DEAD. 89 place, he ridicules the heathen for their inconsistency, in first burning the dead in the most unfeeling manner, and then cele- brating the feasts which they denominated Parentalia, by the same fires both honouring and insulting them, treating them as if they had been gluttons after they had consumed them. “ O “ piety !” he exclaims, “ sporting itself in acts of cruelty *.” The adversaries of the Christians, indeed, objected to them, that they had a weightier reason for opposing cremation. M1- nucius Fenix, accordingly, introduces the heathen as saying, “ For this reason they execrate the funeral pile, and condemn “ sepulture by burning,” as if it precluded the possibility of re- surrection. But Mrvuctus replies, “ We do not, as you be- “ lieve, fear any injury by this kind of sepulture; but we ad- “here to inhumation as the more ancient and the preferable “mode +.” From the ridiculous reason assigned by Terrutiian, for the reluctance which some of the heathen felt to cremation, it ap- pears fMat they were actuated by the self-same feeling with Christians ; although, according to this ancient writer, they transferred their compassion from the body to the soul. But some of them, it is evident, viewed the practice as inhuman on Vox. VIII. P. I. M a * Ego magis ridebo vulgus, tunc quoque quum ipsos defunctos atrocissime exurit, quos postmodum gulosissime nutrit, iisdem ignibus et promerens et of- fendens. O pietatem de crudelitate ludentem! Id. de Resurrect. c. i. + Inde videlicet et execrantur rogos, et damnant ignium sepulturas, quasi non omne corpus, etsi flammis subtrahatur, annis tamen et etatibus in terram resol- vatur.—Hoc errore decepti beatam sibi, ut bonis, et perpetem vitam mortuis pol- licentur ; czteris, ut injustis, peenam sempiternam. Mun. Feu. Octavius, p. 97, 98. edit. Lugd. 1672. Nec, ut creditis, ullum damnum sepulture timemus, sed veterem, et meliorem consuetudinem humandi frequentamus. Ibid. p. 327, 328. 90 ON THE ORIGIN OF CREMATION, a more general ground. Hence a poet, cited by Eusrarutvus, introduces a person as exclaiming against it, and as invoking Prometuevs to hasten to his assistance, and snatch, if possible, from mortals, the fire with which he had supplied them *. As Jews and Christians, in every age, preferred inhumation, because it bore a more direct analogy to the origin of man, it is remarkable, that even Lucretius virtually assigns the same reason for the practice : Cedit enim retro, de terra quod fuit ante In terram. A variety of reasons may be supposed, either separately or in connection with each other, according to the prejudices and habits of particular tribes or families, to have induced the in- troduction of this mode. The influence of such reasons may also be supposed to have been greater or less, in proportion to their relative probability, as they appeared to the minds of those who contemplated them ; or according to peculiar cir- cumstances, as existing in different ages, or among different nations. There are other reasons, which have a superior claim to our attention, as being expressly mentioned by ancient wri- ters. 1. The mode of cremation may have been preferred, in some instances, as a means of guarding the living against the fatal effects of putridity from the dead. The Romans, we know, originally used their dwelling-houses as tombs for their decea- sed relations. The same practice prevailed among the more early Greeks +. The Thebans, in one period of their history, had * Evsraru. in Iliad. A. p. 32. - Pare ts ' EY , 5 e t OF DE ced beeivwy medrspos duct xcceh Woemroy ty ay dixie vods emobavovras ; Hyutis 3: cobray gdiy xoicvusy. Pua, Minoe, Oper. ii. p. 315. edit. Paris. 1578. OR THE BURNING OF THE DEAD. 91 had a law, that no one should build a house without providing a repository for his dead*. The disastrous consequences of this unnatural approximation, as they were strangers to the art of embalming, might be felt for a considerable time, before in- dividuals could find it possible to release themselves from the fetters of custom, strengthened by superstition. But as men advanced in civilization, this strange practice would become matter of cognisance to those whose office obliged them to watch over the public weal; and we may naturally enough suppose, that the prohibition of domestic sepulture would be an intermediate step between the observation of this custom, and the enactment of that law which forbade the Romans ei- ther to bury, or to burn, the bodies of the dead within the city. It may be observed by the way, indeed, that they, with many other ancient nations, as well as the Chinese, have manifested much more common sense and delicacy in -this respect than the nations of modern Europe, notwithstanding their boasted refinement. 2. Those who wished to preserve the remains of the dead as long as possible, in token of regard for their memory, might prefer this mode to inhumation. Knowing that, in conse- quence of interment in the common way, the bones themselves gradually moulder into dust, till every vestige of the person be lost, they might in some instances adopt the plan of calcina- tion, as a means of partially preserving them. There can be no doubt that this was the most eligible mode, where embalming was not used, when it was meant to transport the remains of the dead from one place to another. As the Greeks ascribe the - introduction of cremation 'to Hercurss, they in effect assign, as the reason of his burning the body of Arerus, that he was un- M2 der * * V. Porrer’s Archeol. ii. p, 218. Lond. edit. 1751. 92 ON. THE ORIGIN OF CREMATION, der the necessity of transmitting it to his father Licymntus, as the only way in which he could fulfil the promise he had made to restore his son. 3. Before cremation was generally adopted by any nation, it might be found necessary during the prevalence of any pesti- lential disease. In the passage in which Homer first mentions this mode as observed by the Greeks, although he does not di- rectly assign the pestilence as the reason of its being used, he ascribes the frequency of the kindling of the funeral pile to the prevalence of that contagion which was viewed as the effect of the wrath of AroLto : \ ~ / Vv 7 A Avra exer’ auroios Peros eyerevnes eQueis, , 7 / v4. Baan csci de rvent vexvar xasovro Oawesces. Iliad. A. 51. From a comparison of this passage, indeed, with what the poet has said in his introduction, it may be inferred, that cre- mation was supposed to be more peculiarly necessary in this ease ; as he there speaks of the multitude of heroes that fell in battle, who were left a prey to dogs and to all the fowls of heaven : c ~ / "Auras De choose revye nuverow, > ~ vA ~ Otwvoici re THC. It appears that the Hebrews, though they adhered to the more ancient mode, had no objection to burn the dead in a time of contagion. In this sense are we to understand the language of the prophet Amos, when foretelling the conse- quences of a continued famine: “ A man’s uncle,” or near re- lation, “ shall take him up, and he that burneth him, to bring “ out OR THE BURNING OF THE DEAD. 93 “ out the bones out of the house, and shall say unto him that “ is by the sides of the house, Is there yet any with thee * ?” Though they carried the bones to the sepulchres, they did not venture to bring out the dead body before cremation, lest others should be infected. From several passages in the Sacred Writings, it has been in- ferred, that the Jews in a later age actually burnt their dead. But it is to be observed, that as the language refers exclusive- ly to their kings, it is not said that they burnt their bodies, but only that they “ made burnings for them +.” Even from the account which is given of the honours paid to the memory of Asa, though it has been urged as a proof that the Jews had adopted cremation, it is evident that the burning was a cere- mony superadded to his interment; for it would appear that his body was wrapped in spices: “ They buried him in his * own sepulchre, which he had made for himself in the city of ~“ David, and laid him in the bed,” the coffin or sarcophagus, as would seem, “ which was filled with sweet odours and di- . © vers kinds of spices prepared by the apothecaries art; and “ they made a very great burning for him {.” The writers of the Ancient Universal History suppose, that these spices were burnt around the body §. But this does not seem likely; for we cannot well conceive, how, in this case, the body itself should not have been affected by the force of the fire. It may, therefore, more naturally be supposed, that this burning did not take place in the sepulchre. Perhaps, though the Jews did not consume the body, yet on such occasions they so far com- ‘ ; plied * Amos, vi. 10. + 2 Chron. xxi. 19.; Jer, xxxiv, 5. + 2 Chron, xvi. 14. § Vol. iii. p. 173. 94 ON THE ORIGIN OF CREMATION, plied with the customs of other nations, as to erect a funeral pile at the entrance of the tomb, which they might burn in ho- nour of the dead, containing nothing save spices and odorife- rous woods, or having an image of the deceased prince substi- tuted for the body. It cannot reasonably be thought,’ that they would have accounted that an honour to their kings, which was deemed a disgrace to every other person. Not on- ly in the more early period of their history *, but even towards the dissolution of the monarchy, the burning of the dead body was viewed as a sort of posthumous punishment, expressive of the greatest contempt and detestation. For Josran, we are in- formed, “ burned the bones of the priests of Baat upon their “ altars f.” 4. It tended greatly to facilitate the reception of this custom, that it seemed the most certain plan for protecting the dead body from those indignities to which it might otherwise have been subjected. It is highly probable, indeed, that the danger to which the bodies of departed relations was exposed, of be- ing disfigured or devoured by beasts of prey, first suggest- ed the idea of covering their graves with heaps of stones; and that this course had been followed in a very early stage of so- ciety. But when war had begun to extend its cruel ravages, when man had become as unfeeling to his fellows as the tyger or the hyzena, when his ferocity reached even beyond the hal- lowed precincts of the tomb; it would be found necessary to devise some more effectual plan for securing rest to the dead. It has been observed, accordingly, in another dissertation, that, as Priny informs us, the Romans adopted cremation in consequence of being engaged in distant wars; and also, that SYLLA, * Josu, vii, 25. + 2 Chron. xxxiv. 5. OR THE BURNING OF THE DEAD. 95 Syxxa, contrary to the custom which had hitherto been religi- ously observed in the Cornelian family, ordered his body to be committed to the flames, lest the dishonour done by him to Mantvus might be retaliated. For a similar reason, undoubted- ly, the valiant inhabitants of Jabesh-gilead “ arose, and went “ all night, and took the body of Savr, and the bodies of his * sons, from the wall of Beth-shan, and came to Jabesh and “ burnt them there *.” They deeply felt the dishonour that had been already done to their deceased sovereign and his gal- lant sons, whose bodies had been “ fastened to the wall of “ Beth-shan,” one of the cities of the Philistines, that they might be exposed to every species of outrage from their re- morseless adversaries. ‘They, therefore, carried them off and burned them ; not with the intention of giving them the fune- ral honours of cremation, but merely to prevent the possibility of their being hung up as before. This, they had every reason to suspect, would have been the case, had they interred them in the usual way, because the land of Palestine was at this time completely under the power of their enemies, and circumstan- ces did not permit them to carry the bodies across Jordan. They gave them, as far as possible, the common rites of se- pulture, by interring their remains; but not till they had done what seemed previously necessary for guarding against a repe- tition of similar indignities. _5. Some of the ancients preferred this mode, because, accord- ing to their ideas (whether well or ill founded, it is not our bu- siness here to inquire), it most speedily reduced the body to its first principles. Tuatzs, and his followers, viewed water as the origin of all things ; and therefore reckoned it most fit that the body should, by putrefaction, be reduced to its original ele- ment. _ Hirron, as we learn from Trertuuian, taught the same doctrine. * 1 Sam. xxxi. 10,—13. 96 ON THE ORIGIN OF CREMATION, doctrine *. Heracuirus, who is said to have flourished in the time of Darius Hysraspes, held fire to be the first principle. Hence he, with those of his sect, preferred cremation ¢. Ma- cRoRIUS mentions two of this name, whose doctrine was mate- rially the same. Heracurrus of Pontus, he says, affirmed that the soul was light ; and Heracrirus the natural philosopher, that it was the scintillation of a stellar essence {. “ The old “ heroes in Homer,” says Sir Tuomas Brown, “ dreaded no- “ thing more than water or drowning; probably upon the old “ opinion of the fiery substance of the soul, onely extinguish- “ able by that element ; and therefore the poet emphatically “ implieth the total destruction in this kinde of death, which “ happened to Asax Ortzus |.” Hence Servius, in reference to the horror expressed by AZNEas in prospect of being ship- wrecked, remarks, that this was not from the fear of death, but from the apprehension that his soul might perish, if his body should have no other than a watery grave §. Several ancient writers held fire in such estimation, that they considered it as animated, and therefore as not to be ex- tinguished * Terruxuian. de Anima, c. 4. 4+ Vide Avex. ab Aurxanpro Genial. Dies, lib. iii. c. 2. Porrer’s Archeol. ii. p. 207. + Heracuitus Ponticus lucem; Heracritus physicus, scintillam stellaris es- sentiz. In Somn. Scipion. lib. i. || Hydvotaphia, p. 4. § Commenting on these words in the first book of the Bneid, Extemplo Atnex solvuntur frigore membra, Ingemit, &c.——he says, Non propter mortem, sequitur enim, O terque quaterque beat, sed propter mortis genus. Grave est enim secundum Homerum, perire naufragio, quia anima ig- nea est: et extingui videtur in mari, id est, elemento contrario. OR THE BURNING OF THE DEAD. 97 tinguished *. Barruoiie has observed, that the ancient Scandinavians were influenced by a similar idea, how much so- ever it is enveloped in the darkness of their mythology. As they believed the principal heaven to be fiery, they adored that sacred fire which it was impious to extinguish. Fire being also considered as eternal, they assured themselves that the soul, which was loosed from the body: by means of this ho- noured element, would most certainly, and in the most expe- ditious mode, be conveyed to the seats of the blessed. As Oonrn had enjoined cremation on his followers, they were per- suaded that the honour, with which the person whose body was burned would be received into heaven, would be exactly in the ratio of the height to which the flame of his funeral pile as- cended. As they denominated the rainbow “ the bridge of “ the gods,” by which it was necessary that men should as- cend. into the celestial regions, they affirmed that the red divi- sion consisted of fire f. . This learned writer gives it as his opinion, that Op1x, whom the northern nations worshipped, was the Sun; that the souls of heroes were said to be received by him, because they belie- ved that the soul, being of an igneous essence, was a particle derived from their deity ; and that the warrior, who led the Ase, or Asiatic chiefs into Scandinavia, assumed this name, by which the sun was known in eastern regions, that he might en- sure divine honours to himself. He thinks that it was with this design that he ordered his body to be burned, that his sub- jects, following his example, might be supposed, after death, to be translated by fire to a state of eternal fellowship with the object of their adoration. Vou. VIII. P. I. N 6. The * V. Scaccuir Myrothecium, lib. i. c. 9. p. 46. s+ V. Bartuonw. de Causis Contempt.Mort. p. 272,—274. 98 ON THE ORIGIN OF CREMATION, 6. The reception of this mode has been also ascribed to the influence of the ancient tradition, that the world should be de- stroyed by means of fire. The very ingenious and learned physician quoted above, observes, in that light and rather af- fected sort of style which characterizes his writings ; ‘ Such as “ by tradition or rational conjecture held any hint of the final “ pyre of all things, or that this element must at least be too “ hard for all the rest, might conceive most naturally of the “ fiery dissolution *.” y That this tradition was not only known to some of the Greek philosophers, but even received by some of them, is unques- tionable. Pxaro, when giving an account of the conference which Soron had with the Egyptian priests at Sais, acknow- ledges that they spoke in the most contemptuous terms of the learning of the Greeks, asserting that they were always chil- dren, that there was no old man among them, as they still pos- sessed juvenile minds. ‘“ For, (said one of the senior priests,) “* you have no ancient doctrine from old tradition, nor any dis- cipline that has become hoary with age :” adding, “ The greatest dissolutions of the world have originated, and will “ originate, from fire and water }.” Soton having proposed some queries in regard to Dreucation, Pyrrua, Puarron, &c. the priest proceeded to describe the dissolution by fire, in re- ference to the mythological account of Puarron having set the world on fire. “ This (he said) has indeed the air of a fable; “ but the truth is, there shall be a great parallax,” or “ change, “ in heaven and in earth; and in a short time the dissolution “ of terrestrial things shall be effected by much fire }.” ce ‘49 This * Brown’s Hydriotaphia, p. 3. t Thorac! 32 xcerce morre& Qbogce) yeysvariy avdewmoy, xoul erovrecs, wuel pty OF Oder mlyicote gus fy’ e 2 ee peey’ Trmzus, Oper. iii. p. 22. $ Taro ptdov ptr oryinun exov Aeyerces, ToD dArndis ist, civ oregi yity xeel Kove’ ovgeevoy fovray me 2chrwksc, noel Dice moaned Hedvay ryivopeeyn Fav Ems vis wuel moras Pdopd Ibid. pus OR THE BURNING OF THE DEAD. 99 This, it has been observed, was the general doctrine of the Platonists. It was also held by other philosophers, especially by the Stoics. It has been asserted by the learned Grortus, that Zeno of Cittium, the founder of the sect of the Stoics, re- ceived this opinion from the Phenicians ; as Cittium was a Phe- nician colony in Cyprus. Whether this remark be well found- ed or not, the doctrine was generally adopted by his followers. Seneca expressly asserts, that, as “ the world had its origin by “ water, it shall be destroyed by fire*.” He says in another place ; “ All things shall fall by their own power ; the stars shall “ rush on the stars, and universal matter shall blaze in one “ fire. Whatever now shines in the world shall then be in “ flames +.” Diocenes Larrtius thus expresses the doctrine of Heracui- tus; “ There is one world, which was produced by fire, and “ shall be again reduced into fire t.” Need I add the well- known language of Ovip ? Esse quoque in fatis reminiscitur, affore tempus Quo mare, quo tellus, correptaque regia cceli _* Ardeat; et mundi moles operosa laboret. yr , ; Metam. lib. i. ver. 256. - It ought to be observed, however, that neither this, nor the preceding reason, assigned for the introduction of cremation, _ can be viewed as satisfactory. For it appears that this custom oF cca . N 2 "was Lamy gts ‘ t bs Ita ignis exitus mundi est, humor primordium, Natural. Quest. lib. iii. ec. 13. + Epist. de Consolat. ad Porys. T “Evee civees xdopeoy, yeneiobas re dutoy & mens, xal mart exmuezctar. WV. Gain’s Court of the Gentiles, b. iii, c. 7. 100 ON THE ORIGIN OF CREMATION, was pretty general in Greece before the existence either of Tuazes or of Heractirus, and, indeed, before either of their peculiar systems had been broached. It seems highly probable, indeed, from what Homer has said in regard to. the fate of Agax, that tl ose philosophers who honoured fire as the prima- ry element, had built their hypothesis on ancient tradition, Besides, it is attested by universal experience, that the theo- ries of philosophers have had very little influence on the man- ners and customs of mankind. In many instances they have endeavoured, in their own way, to account for certain customs which prevailed among their countrymen, or in other nations ; and have occasionally accommodated their systems to those modes which had the sanction of antiquity. But it may well be questioned, if, in any one instance, the dogma of the most cele- brated school has given rise to a rite or custom which has been generally received by the multitude. The influence of their authority was almost entirely confined to their own disciples ; and, while a theory directly opposite was keenly supported by others, who claimed equal authority, and who had an equal right to exhibit this claim, the surrounding multitude could only stare at the supposed wisdom of contending sects, without attempting to decide the controversy, or even supposing that they were qualified for so arduous a task. We must inquire, therefore, if there was no idea pretty g ge- nerally received among men, that entwined itself with their re-. ligious creed, and derived peculiar influence from their hopes _ and fears, as to a state of future existence ; which, if it did not absolutely originate this custom, must have greatly facilitated its progress. We accordingly observe, 7. That the body was believed to be unclean after the depar- ture of the soul; and that it was therefore deemed necessary that it should be purified by fire. This is given by Eustarutvs as OR THE BURNING OF THE DEAD. 101 as one reason for the general reception of this custom in Greece. ‘ There was,” he says, “ a certain purification by the “* consumption of fire, because fire is a purificator; wherefore “ purifications were made by fire.” And Evuripines gives a si- milar statement, when he says, “ that the body of CrvremMnes- “« pra was purified,” literally, ‘« sanctified by fire*.” The idea of pollution by the dead seems to have been early diffused : and this idea presupposes that of the body, as separated from the soul, being itself unclean. _ “ Not the Jews only,” says the accurate and learned Por- TER, “ but the greatest part of the heathen world, thought “« themselves polluted by the contact of a dead body ; death “‘ being contrary to nature, and therefore abhorr’d by every “ thing endued with life .” Among the Greeks, as long as there was a corpse in any house, a vessel of water was placed before the door, that those who had had any communication with the dead body, might, before their departure, purify them- selves by washing. Hence Evuririprs makes the chorus call in question the death of AucrsteEs, because this customary signal was not exhibited. TlvAwv ragoiber 0 ovy’ oga TInydésov, we vomiCerat Te, yzenS ai xecbvea avrous: Alcestid, vers. 69. aa _' They supposed that even the house in which the corpse lay ‘was not free from pollution. The same poet therefore intro-’ pit uae} ¥. xy : 4a duces * Aynops 08 rig Hv H Dict wvgos Damedyn TOU vengabevros. art xul To wie cyvisixoy dio xcel ot xee- decgpess Dice mugs eywovro. soe Eveimidns 92 tosovroy 7 exPavor, are ov Qnow ove To 745 Kavranmmrens Dinas, wes xeelnynsat Kustatu. in Iliad, A. ver. 52. + Archeolog. ii. p. 188. 102 ON THE ORIGIN OF CREMATION, duces Hexen as saying, “ Our houses are pure, not being defi- “ Jed by the death of Menetaus*.” To this idea, of defile- ment being contracted by approximation to the dead, we ought undoubtedly to trace the custom which prevailed among the Romans, of thrice sprinkling with consecrated water all the re- lations of the deceased, and all who had attended the funeral ; who were then said to have received expiation or lustration. This ceremony was performed by a priest, after the burnt bones had been put into an urn, and immediately before he gave the company leave to depart, by pronouncing the words of vale- diction. Ossaque lecta cado texit Chorinzus aheno : Idem ter socios pura circumtulit unda, Spargens rore levi, et ramo felicis olive, Lustravitque viros, dixitque novissima verba. Vira. En. lib. vi. As a further purification, those who had attended the obse- quies of the dead, after being sprinkled with water, as we learn from Festus, stepped over a fire. This act was called Suffitus. The house was also purified, and swept with a particular kind of besom. The Ferie Denicales were certain ceremonies insti- tuted with this design. The Flamen of Juprrer was laid under the same restrictions as the Jewish High-priest. He was not permitted to touch the dead, or even to approach a grave f. The ancient Scythians themselves, though strangers to any species of refinement, supposed that they necessarily contract- ed defilement from the dead. Herovorus relates according- ly, Evriewm. Helen. vers. 1446. + Aut. Gewn. Noct. Attic. lib. x. c. 15. OR THE BURNING OF THE DEAD. 103 ly, that they purified themselves, first by washing their heads, and then by burning hemp-seed on red-hot stones, with which they produced a powerful fumigation *. It is well known that the Romans viewed fire and water as the two great principles of purification, and that with this de- sign they applied them to things of every description. Hence Ovip, when describing the Palilia ; ew, Certe ego transilui positas ter in ordine flammas ; Virgaque roratas laurea dedit aquas. Fast. lib. iv. v. 727. They extended the purifying virtue of fire not only to their flocks, but to the owners of them. —Per flammas saluisse pecus, saluisse colonos. Ibid. v. 805. He proceeds to enumerate the different theories which had been formed, in order to account for the use of fire and water with this view. The variety of these, he says, caused hesita- tion as to the real origin. By some it was supposed, that as. fire purified every thing, particularly metallic substances, it would have the same effect on the shepherd and his flock. Omnia purgat edax ignis, vitiumque metallis Excoquit. Idcirco cum duce purgat oves. Ibid. v. 785. ting | ~~ Others imagined, that as all things had their origin from fire and water, their ancestors had conjoined these elements in their rites of purification; while there were some who traced this practice to a conviction that in these existed the principle of life. * Melpom. c, 73. 75. 104 ON THE ORIGIN OF CREMATION, life. Others again, he says, understood the one rite as refer- ring to Puarrton, and the other to the flood of Deucatron. Sunt quia Phaéthonta referri Credant, et nimias Deucalionis aquas. Ibid. v. 793. Pieris, in his Heroglyphica, quotes the language of PLav- tus, as affording a “a that the ancient apie ascribed a purifying virtue to fire. Quid impurate, quanquam Volcano studes, Coenz ne causa, aut mercedis gratia, Nos nostras edes postulas comburere ? Aulular. ap Pier, fol. 343. E. Priertus, however, remarks, that they made a distinction be- tween the use of fire and water, viewing the one as the means of purification, the other of expiation. Ignis autem, ut nostri veteres tradidere, purgat ; aqua expiat, lustratque. As both these modes of purification were practised long be- fore the Romans had a national existence, it is not surprising that the ritual poet found himself quite at a loss to account for their origin. Though I do not pretend to determine from whom the Romans received these rites; yet the analogy, not only in the use, but in the conjunction of these, with that ordi- nance given to the Hebrews, with respect to the spoils taken in war, is too striking to be passed over in silence: “ The gold “ and the silver, the brass, the iron, the tin and the lead, eve- “ ry thing that may abide the fire, ye shall make it go through “ the fire, and it shall be clean ; nevertheless, it shall be puri- “* fied with the water of separation: and all that abideth not “the OR THE BURNING OF THE DEAD. 105 * the fire, ye shall make go through the water*.” In the re- moval of defilement by the dead, the use both of fire and of water was necessary. A red heifer was to be killed, and com- pletely burnt without the camp ; the ashes of which were to be carefully collected, and laid up for future use in regard to all who had “ touched a dead body, or a bone of a man, ora “ grave.” The law, enjoining the necessary purification, is thus expressed): “ For an unclean person,” that is, one pollu- ted by the dead, “ they shall take of the ashes of the burnt hei- “ fer of purification,” or of atonement for sin, “jand running wa- “ ter shall be put thereto in a vessel: and a clean person,” a priest, according to the Targum of Jonaruan, “ shall take hys- “sop, and dip it in the water, and sprinkle it upon the tent, < ‘and upon all the vessels, and upon the persons that were “ there, and upon him that touched a bone, or one slain, or “one dead, or a grave: and the clean person shall sprinkle “ upon the unclean on the third day, and on the seventh day : Ss and on the seventh day he shall purify himself, and wash his “ clothes, and bathe himself in water, and shall be clean at even +.” Prerrus, as we have seen, while he marks the de- signed distinction between the use of fire and that of water, says that the fire was viewed as purifying, the water as possess- ing the power of expiation. This, however, was reversed among the Hebrews. The ashes of the burnt heifer seem to have respected the expiation of guilt, and the running water the removal of pollution. Not only in the Hebrew, but in the a ritual, sprinkling was expressly enjoined. According to both, it was administered by similar means. In the one case, a branch of olive, the emblem of peace and reconciliation, was used instead of a bunch of hyssop in the other. Von. VIII. P. I. O It * Num, xxxi. 22, 23, + Num, xix. 1,—19, 106 ON THE ORIGIN OF CREMATION, ~ It is well known, that, among some of the ancient nations of the East, parents were wont to consecrate their children to Mo- loch, whom some suppose to be the Sun, and others Saturn, by actually giving them up to the devouring flame. The infa- tuated parents persuaded themselves, that by this inhuman act they would secure their own prosperity, and that of the rest of their offspring. But this was not the only mode of consecra- tion. We learn from Marmonies, that, a great fire being kindled, the parent delivered his son to the priest, who had the charge of this fire ; and that he gave him back to the father, in token of his being permitted to make him pass through the fire. After this ceremony, the father himself led his child through the flames, from one side of the fire to the other *. Correspondent with this account, the language containing the prohibition of this crime, in Deut. xviii. 10. is rendered in the Septuagint, “‘ There shall not be found among you any one “ that purifieth his son or his daughter in fire f.” The Druids, we are told, on May-eve kindled two great fires, between which the men and beasts, which were to be sacrificed, were made to pass in order to their purification t. In Ireland to this day, at the Feast of Beltein, which is held at the sum- mer solstice, as they kindle fires on the tops of hills, every member of a family is made to pass through the fire; this ce- remony being deemed necessary to ensure good fortune through the *® Marmon. de Idololat. c. 6. s. 3. T Megicabarigay cov inoy ewes val thy Ovyarion dure uel. { ‘© Two fires were kindled by (near) one another, on May-eve, in every vil- lage of the nation, (as well thro’out all Gaule, as in Britain, Ireland, and the ad- joining lesser islands,) between which fires the men and the beasts to be sacri- fic'd were to pass.” Totanp’s Hist. of the Druids, Lett. ii. § 4. OR THE BURNING OF THE DEAD. 107 the succeeding year *. As the designation of this feast retains the name of Baal or Bel, I need scarcely remark the striking resemblance of this rite to the ancient worship of the false god who was thus denominated by the nations of the Kast. There is great reason, indeed, to believe, that Baal and Moloch were merely different names for the same idol; the one word signi- _ fying Lord, and the other King. For those, who in one place are said to have “ built the high places of Baal,—to cause their * sons and their daughters to pass through the fire unto Mo- -“ loch f,” are said, in another, to have “ built the high “ places of Baal, to burn their sons with fire for burnt offer- s ings unto Baal}.” There can be no doubt that the wor- 9 of Baal was that of the sun, who was designed “ the lord,” and « the king, of heaven.” The ancient Goths ascribed a similar virtue to this element. When, in their religious feasts, they drunk in honour of their ods or departed heroes, they stood around a great fire in the st of the temple, and caused the cups, filled with wine or ~ mead, to ) be passed through gpe: flames ||. v6 PENNANT ane notice of a singular superstition, which still remains in the Highlands of Scotland, and which must certain- ly be viewed as a remnant of druidical worship. “ It has hap- Sf ‘ pened,” he, ys, “ iehigts after baptism, the father has placed si om O 2 “ao Me a Thus I Tae seen the people running and leaping through the St John’s fires in Ireland; and not only proud of passing unsing’d, but, as if it were some be lustration, thinking themselves in a special manner blest by this ceremo- ‘ny, of whose original, nevertheless, they were wholly ignorant, in their imperfect imitation of it.” Toxanp, ibid. § 7. V. also Borxass’s Antiquities of Corn- wall, p. 130. if Jer. xxxii. 35. { Jer. xix. 5, || Sturteson, Vit. Haquin. Adalstan. V. Keysuen. Antiq. Septentr. p. 355, 356. 108 ON THE ORIGIN OF CREMATION, al ‘ a basket, filled with bread and cheese, on the pot-hook that “ impended over the fire in the middle of the room, which the “ company sit around, and the child is thrice handed across. “ the fire, with the design to frustrate all attempts of evil spi- “ rits, or evil eyes. This,” he adds, “ originally seems to have “ been designed as a purification, and of idolatrous origin, as. “ the Jeradlites made their children to pass through the fire to. “ Moloch *.” The mode of performing this unhallowed rite is didfexenggd in some parts of the Highlands. One holds the new-born child by the shoulders, and another by the feet, while they shove it backwards and forwards across the fire. This is sometimes used as a test, whether the child be of the right blood, or mere- ly a fairy urchin substituted in lieu of the genuine offspring. If, after this operation, the child, on being put to bed, fall into. a copious perspiration, it is viewed as an infallible proof that there has been no elvish imposition. It must be admitted, in- deed, that scarcely any method could be adopted more likely to ensure the wished for favourable omen. It may be obser- ved, that, in the investigation of ancient superstitions, we have many examples of a change of the reason assigned for a pecu- liar rite, especially if there has been a change of the religious. ereed of'a people; when there is no ground to doubt that the rite itself has remained unaltered. m I have met with one superstition in the low country, (for it still exists in the county of Angus), which seems to claim the same origin. A burning coal is put into the water in which. a new-born child is to be erates Were this important ceremo- ny neglected, it is believed by many that the infant could not thrive. The * Tour in Scotland, 1772, p. 46: OR THE BURNING OF THE DEAD. 109 The language of Vireit proves, that the Romans were not strangers to the same kind of idolatry. As the mountain So- racte was consecrated to AroLto, his votaries manifested their ardour in his service, by rushing through the burning coals of the fire lighted up in honour of their god. © Summe deum, sancti custos Soractis Apolla, Quem primi colimus, cui pineus ardor acervo Pascitur, et medium freti pietate per ignem Cultores multa premimus vestigia pruna ; Da pater hoc nostris aboleri dedecus armis _ Omnipotens. — J ZEn. lib. xi. ' Servius explains the term acervo, “ Pyra coacervatione lig- * norum.” Perhaps he did not use the word as denoting a fu- neral-pile, as it also signifies a bonefire. There is indeed no reason for supposing, that Virert referred to the burning of the dead. We learn the meaning of this language from the testimony of Privy: “ Haud procul urbe Roma in Faliscorum “ agro familiz sunt paucee, quae vocantur Hirrre : que sacrifi- Taig eanEO, quod fit ad montem Soractem Apotiini, super “ ambustam ligni struem ambulantes non aduruntur.” Nat. Hist. lib. vii. c. 2. The same species of worship is described by Srxrus Irauicvs, lib. v. ver. 175. bal I need scarcely observe, that, as AroLto was the same Pcih the Sun, the passage affords a proof of the striking analogy be- tween his worship among the Romans, and that which has been already illustrated. Did we know the particular day annually coaggroted in this manner, the coincidence might be still more remarkable. The early Greeks ascribed the same efficacy to fire. Homer, accordingly, makes ULysszs, after the slaughter of those who al sought. 110 ON THE ORIGIN OF CREMATION, sought to rival him in the affections of Prnexore, to purity his house from blood by the use of fire and sulphur: Oirs Sesion vend xeoxay cxos, dios Oe pros mde "Oden baisbow Heyagor. Odyss. lib. xxii. v. 481. As we certainly know, that the ordeal by fire was used in the times of heathenism, there is no reason to doubt that it originated from the same persuasion as to the purifying virtue of fire. The person who passed without injury, bare-footed and blind-fold, over nine glowing ploughshares, was said to be purged from the crime of which he had been accused. The names given, in various instances, to this species of trial, ex- pressed the same idea. In the language of Iceland it was de- nominated skirsla, from skir-a purgare. The learned Lunp traces the Gothic term ordel, urdel, perhaps rather fanci- fully, to Heb. ur ignis, as denoting judgment by fire*. In the Latin of the dark ages, the act was designed purgatio vul- garis; and the person was said, per calidum ferrum se purgare, or ferro candenti se purificare. It may be added, that, as the other mode of ordeal was by water, whether cold or hot, it ap- pears that the principal tests of imputed criminality bore a strict analogy to the two great means of purification acknow- ledged by the ancients,—fire and water. ' As a proof that the ordeal by fire was a remnant of pagan worship, the justly celebrated Du Cancxr refers to the testimo- . nony of SopHocLes. "Hyey F eroiwor nat pvdeus cegew egos, Kai wie diéerew, xock bees oguapmoréire Antigon. ver. 270. ") “ We * Ture Glossar. voc. Ordela. OR THE BURNING OF THE DEAD. 111 “ We were prepared to grasp the burning irons in our hands, “« and to pass through the fire, and to adjure the gods.” Pa- cuymergs has remarked, that uvdgos, or the burning share, was said to be ays, or holy, because it had been blessed by the priest *. ; 8. It was believed by some, that by the action of fire, the soul was completely loosed from all its corporeal bonds. Trr- TULLIAN charges some philosophers with holding, that even af- ter death, certain souls continued in a state of connection with the bodies which they had formerly animated : “ Ita argumenta- “ tiones emendicant, ut velint credi etiam post mortem quasdam “ animas adherere corporibus }.” He asserts, that PLaro was of this opinion. But the passage to which he refers, can only be viewed as a proof that Prato believed the immortality of the soul. It is the apologue introduced by him in his Republic, conceming Hervs the Armenian, who is said to have revived, when he was laid on the funeral-pile, twelve days after he fell in battle t. ~Macrosius, however, gives the same account of the doctrine of this philosopher. For, according to him, Pate asserts tha the souls of those who die by violence wander long + ie - around, ede ; ° Ap. Du Ca 3, voc. Ferrum Candens. As the Greek word ve has been deduced from the Hebrew sik, ur, pro- peny de count of the natural subserviency of fire to purification, as well as the ri- tual use of it with this view, it is possible that the verb purgo may have been formed quasi mig ayo, as originally signifying to lead, or make to pass through the fire. Perhaps the language of the ancient Latin poet Navius, in the use of the phrase puriter facere, may be considered as favourable to this etymon of pu- _ rus; Sequere me, puriter volo factas, igne atque aqua volo hunc accipere.. _ Ap. Non. Marcexy. Gothofred. 775. + De Anima, p. 501. edit. Paris. 1616.. t Puar. Republic. lib. x. vol. ii. p. 614. 112 ON THE ORIGIN OF CREMATION, around the body or the place of its sepulture; the soul being more and more fettered to the mortal part: “ Exitu autem coac- “ to, animam circa corpus magis magisque vinciri. Et revera “ ideo sic extort anime diu circa corpus ejusve sepulturam, vel “ locum in quo injecta manus est, pervagantur*.” “ On the “ contrary,” he says, “ those souls, which, during life, are loosed “ from corporeal bonds by a philosophical death, are translated “ to heaven even while the body exists.” _ It is not perfectly clear, however, whether Macrozrvs assigns this doctrine to Piato himself, or to his disciple PLotinus, who, he says, carried the principles of his master still farther. In the passage to which Macrosrus seems immediately to refer, Prato does not speak of those who die by violence, but in ge- neral of men leaving this world under moral contamination +. Elsewhere, indeed, he says, that, besides the immortal soul, the gods have placed in the body of man éidos Puyis bara, “ a kind “ of mortal soul.” This, according to his idea, includes the will and affections f. TerTuLuiaN has ascribed the same opinion to Democritus ; observing that he reasons from the growth of the nails and But it would seem that here he has rather’ mistaken the meaning of the language of Democritus ; as all that we can certainly infer from it is, that he held the ee of a future resurrection. JamBuicuus says, that “ fire destroyed whatever it ae ma- terial in the sacrifice, purified, and released it from the bonds “ of * Macros. Somn. Scipion. lib. i. p. 87. edit. Lugd. 1560. + He expresses his sentiments in the following terms: "EyBgi:s 0: ys, @ Dire, rex0 1 soba men Cover xaei Ceegu, noel yeadec, nol oguror' 2 3: nal Byoure 4 rorcurn Puyn, Baguveros ve xl Anita mar es gay ogeToy 7, yas Acaroy 8 recusouy gdasay becy- Lycopuron, Cassandr. ver. 44. V. Porren, ii. 208. It is pretended that the fire, by which the body of Hercurzs was consumed, was kindled by the thunderbolt of Jove; and that, in this manner, the son was called into the presence of his divine parent : Eir éravqyarye die oe Keouwvis mueog re0g eauroy *. As the Greeks and Romans forbade the cremation of any who had been killed by lightning +, it is not improbable that this prohibition might originate from the idea, that such persons had been already purified, or consecrated, by the stroke of fire from heaven. It may be observed in addition, that the rites of apotheosis; or consecration, an honour given to the Emperors of Rome, evidently include the idea that the soul was not completely re- leased from its mortal entanglements, save by the influence of fire. The body, indeed, was previously burned: But an image of the person in wax was substituted; and consumed on a lofty and costly pile, with all possible pomp and solemnity. This pile consisted of four different frames of wood, gradually de- creasing in their dimensions, and placed one: above another. When the fire had nearly reached the fourth or highest frame, an eagle was let loose from it, “ which, ascending with the “« flames towards the skies, was supposed to carry the prince’s “ soul to heaven t.” On some of the coins, struck in memo-. ry. * Juuian. Imp. Orat. vii. p. 408.; ap. Spannem. ut sup. p. 241. + V. Gorner. de Jure Manium, lib. i. c. 3. + V. Heropian. Hist, lib, iy. 118 ON THE ORIGIN OF CREMATION, ry of consecrations, the emperor appears carried aloft by an eagle *. Or, perhaps, the figure here exhibited is rather to be viewed as the emblem of his soul. Y. The soul itself was thus supposed to be purified from the contamination which it had contracted in its embodied state. The ancient Gymnosophists of India, of whom the Brachmans, now called Bramins, formed one sect, and the Germanes, Her- muines, or Sermanes, another, were wont to burn themselves alive +; although, in our day, they require this sacrifice of their wives only. ‘That they ascribed some peculiar virtue to fire as thus applied, might be inferred from the language of that Indian, who, when he cast himself into the flaming pile at Athens, said to the astonished spectators, “ Thus I make my- “ self immortal {.” But perhaps the inference is confirmed by the account which Porrnyry gives of the reason of this act of suicide. Having observed, that they who are about to de- vote themselves in this manner, first coolly receive from those around them the commissions which they wish them to carry to their friends in the other world; he subjoins, “ They cast “ their body into the fire, that they may separate the soul from “ it in a state of the greatest possible purity.” This at least seems to be the natural meaning of the words of Porpuyry ; wuel 70 capes mugadorres, Oxws Oy nabugurarny cmonelacr ToD caput ros yy spoyny ||. Lucran, when speaking of the self-devotement of Hercuxss, which he attributes to mere ostentation of fortitude in suffer- ing, * V. Havercamp. Nummophylac. Reg. Christin. p. 100, 101. + Oavarw BE taxvtss arodidiarr xe0, xalimte xel cs Tov Iiday yuouvoroPigai parciw Mer, Ciem. Avexanpn. Stromat. Lib. iv. p. 351. } Nic. Damascen. V. Hydriotaph. p. 3. || De Abstinentia, lib. iv. sect. 18. OR THE BURNING OF THE DEAD. 119 ing, introduces the Brachmans, and refers:to the history of Ca- LANUS, who, leaving his own society, followed ALEXANDER the Great from India. “ The Brachmans,” he says, “ do not leap “ into the fire like Onrsicrrrus, the Governor of ALEXANDER, who, it is related, when he saw Catanus burning, flung him- “ self into the flames ; but after they have erected the funeral- “ pile, standing immoveable beside it, patiently allow them- “* selyes to be accosted, then ascending it with dignity, are * consumed, not shrinking in the slightest degree from the ap- “* proach of the fire *.” But, as it was the design of Lucran to ridicule the philosophers, he assigns no other reason for this con- duct than the love of vainglory. To the same motive does he -ascribe the act of PrrEcrinus, a Stoic, or, as he says, a Cynic philosopher, who devoted himself to the flames. Cexsus the Epicurean, however, as quoted by OricEn, view- ‘ed this suicidal act in a more favourable light. His testimony ‘corresponds with that of Porruyry. His language intimates, that, what virtue soever might be ascribed to the flame of the funeral-pile, in ordinary circumstances, the effect was. supposed to be far greater, if any one consigned himself to it alive. Ont- cen thus expresses his sentiments : “ Cexsus says, that it is im- « pious to violate the laws of our country in regard to the bles- “ sed* termination of life (as it is accounted) by the funeral- “ pile, into which those who voluntarily cast themselves are “ perfectly purified in their aberration from life f.” QuinTILIAN ascribes the same purifying efficacy to the fune- ral-pile. Speaking of the soul, he says ; “ Quoties humani pecto- (74 7 66 ris * Lucian. de Morte Peregrin. Oper. ii, p. 576. * “Huiy 6 Kéaoos, was By dot moegarvesy voperss merelsc—mtel Ts peacrecdgtoy Euvees Yevocamn roy t » cad vv Y eee) ’ ‘ © LU / ~ ‘ \ ~ \ x > : ~ Biov eeabay. motvras xacbcciger bas TBs tauTEs mreepcO1oavr ces TH Wugi, nak Th uct Wugos amanrrcryy 7% amo 72 Bis. ORIGEN. cont. Cexs. Lib. v. p.249. “ Kedaiger$at,” says the learned Stuc- Klus, “idem quod Avyaiv ; expiare, resecrare, purgare, expurgare, purificare.” Sacr. Sa- erific. Descript. p. 123... ae 120 ON THE ORIGIN OF CREMATION, “ ris carcerem effugerit, et exonerata membris mortalibus levi “ se igne lustraverit, petere sedes inter astra *.” Servius, when explaining the language of Virert, Aliw panduntur inanes Suspense ad ventos: aliis sub gurgite vasto Infectum eluitwr scelus: aut exuritur igni remarks, that he “ speaks poetically concerning the purgation “of souls ; for he alludes to what the philosophers said.” He then proceeds to shew, that there was a threefold purification of man, by earth, by water, and by air ; that the earthy purifica- tion denoted that which was made by fire, which has its origin from earth; and that this was necessary for those whe had in~ dulged in sensual enjoyments }. As it was accounted unlawful for Christians to burn their dead, TerruLuian assigns as one reason for their rejection of this practice, that they had already received the benefit of a pu- rification far superior. “ Et cremabitur,” he inquires, “ ex dis- “ ciplina castrensi Christianus, cui cremare non licuit, cui — Christus merita ignis indulsit ? {” it is well known that the Platonists denominated the end of the present state of this world ayarvegacis, as believing that it should be purified and refined by fire; and that to this change the Stoics gave the name of ézzvgasig. As it is equally certain that many of the dogmas of the Oriental, of the Platonic, and * QerntiniaN. Declam.*x. + Loquitur quidem poétice de purgatione animarum: tangit tamen quod phi- tosophi dicunt. Nam triplex ‘est hominis purgatio. Aut in terra purgantur : que nimis oppress sordide fuerunt, dedite scilicet corporalibus blandimentis, enim transeunt in corpora terrena; et hec igni dicuntur purgari. Ignis enim ex terra est, quo exuruntur omnia, nam ccelestis nihil perurit. Serv. in 4- neid. Vi. ver. 742. +t Tertunitan. de Corona Militis, p. 292. OR THE BURNING OF THE DEAD. 121 and of the Stoic, philosophy were early incorporated into the Christian system; it has been asserted by several learned wri- ters, that the Popish doctrine of a middle state, or of the puri- fication of souls by fire, was borrowed from that of the ézqveu- o. The doctrine of purgatory, indeed, is nearly allied to the ideas which the gentiles entertained concerning the efficacy of fire in preparing the soul for the abodes of Elysium. It has also been observed, that the sacrifices which the Greeks denominated revere}, were offered with the same design. Some have supposed that these sacrifices for the dead received this name, because, being the most sumptuous of all sacrifices, the greatest part of them was consumed *. But there is another interpretation of the term, which is more probable. They seem to have been thus denominated, as perfecting whatever had been deficient in the merit of the dead, and as securing their liberation from suffering in the eternal state f. 10. I shall only further remark, that this igneous purifica-. tion was intimately’ connected with sacrifice. Though, as has already been observed, we cannot view this practice as origina- ting from the tenets of any particular school ; sufficient proof’ has been brought to shew, that it was viewed as a solemn act of religion : and it may naturally enough be supposed, that the philosophers who considered fire as the principle of all things, would take advantage of a custom which was pretty general in their times, as affording an argument that seemed to lend its. aid to their peculiar system. As this custom: was observed, not. merely as a religious rite, but as. am important means of puri- fication ; as it has been so generally diffused, although doubtless. abhorrent from the feelings of humanity; I have at times been: Vou. VIIL. P. I, Q inclined: * Sur. in voc. + V. Gane’s Court of the Gentiles, Part IIT. B. ii, c. 2. § 11. 122 ON THE ORIGIN OF CREMATION, inclined to think, that, at an early age, the cremation of the body might have been immediately meant as an act of expiatory sacrifice. Of this, however, it must be acknowledged, we have no direct evidence. But the want of this evidence is not a de- cisive proof that the conjecture is totally unfounded. The ori- gin of the practice itself being buried in the obscurity of ve- ry remote ages, almost beyond the period of fabulous history ; it is by no means surprising, that we should be as much at a loss in regard to the primary design. On a subject of this kind, even the feeble voice of conjecture ought not to be with- held, as no other can be heard; nor should it be totally disre- garded, because at times mere conjecture has eventually led to the discovery of truth. It is highly probable, that this custom had its rise in the dis- tant regions of Scythia, if not in Hindostan. As we learn from the earliest accounts of the inhabitants of this interesting peninsula, which have reached our times, that even when these were written, they not only burnt the dead, but that the living often devoted themselves to the flames; it may afford ground for conjecture that the latter practice preceded the former. Those who viewed it as a signal act of piety for a man to cast himself into the funeral-pile, and as a complete atonement for all the transgressions of his past life, though they could not ri- val him in intrepidity, might, like those who affect liberality in their latter wills, wish to imitate him as far as possible, by de- voting the mortal part to the fire after the extinction of life. It may perhaps be supposed, that this act of self-dedication to the flames was originally meant as a consecration to the sun. Yor, though the Persian fire-worshippers objected to cremation as a profanation of their deity, we are not warranted to con- clude, that all who concurred with them in worship entertain- ed the same idea. While we know that some of the ancient , Brachmans OR THE BURNING OF THE DEAD. 123 Brachmans devoted themselves to a fiery death, we are assured by Srernanus Byzanrinus, from Hrerocres, that they were chiefly consecrated to the sun*. ‘tian expressly declares, that. Catanus, the Gymnosophist, after he had ascended the funeral-pile on which he devoted himself, adored the sun which shone on him; and that this was indeed the signal which he had agreed’ to. give’ to. the Macedonians, that they should set fire to the pile +. Lucraw. gives a similar account of the death of Perecrinus, who, although a Parian by birth, seems to have imitated the customs of the Gymnosophists. The pile being kindled, “ he called for incense; which when he had received “ from some one, he cast into the fire. Then looking stedfast- “ ly towards the meridian, (for the meridian was concerned in “ this tragedy), he said, O! ye maternal and paternal demons, “ receive me graciously ! Having said this, he threw himself “ into the flames.” He subjoins, “ It has been lately report- “ ed, that, as he ascended the pyre, he saluted the rising sun, “ as it is said the Brachmans are wont to do t.” It. merits ob- servation, that the Bramins of our own time daily pay their de- voirs to the sun ; not considering him, they pretend, as the pro- per object of worship, but as the visible representative of the Supreme Being. Incense, I am assured on good authority, is uniformly used by them, in the manner above described, in the: Q2 inhuman: eee ; : : ™ Beceyeecivay ide QUAcv avdeav, Pirorapay xal bois Pirwy grlw oe et risce nabercromcvav. SrePu. BYZANT. voc. Beaypmires. . HY; ] : 3 Kal o pty Hass cevrov HeordounAsy : @ O& auroy meorewves > nal vero gy TO cUbne es +O mare? mueay ois Mexedoct, ABELIAN. Var. Hist. Lib. v.c. 6. £* ‘Eve ares AiGavorey as tmiocros em) ro mie. week aveedovros Thv0s, emtoans Te, noe eearny & Thy peconubeiey amobAtway, nol yee 3 7T8t0 eos Thy “eerste & ay Py pont Dect eoves penrea- ot xak TOT EMO. Shard: fe. évpeeverg.—Kas yee 02 rade ™ meoregice Beledore, ws 7 @05 avorovre. Tay rw aorerapesves, womep autre Se TB; Beoryzcvas Derr mosci, emioyrerdas whe meds, Lis - cian. De Morte Perecrin. Oper. ii. p. 584,—586, . 124 ON THE ORIGIN OF CREMATION, inhuman act of burning the living with the dead. This act is in- variably performed in the vicinity of a river. For all the ashes of the dead are collected, and completely dispersed on the wa- ter; as if they accounted both these elements, which other nations used for purification, necessary for perfecting this hor- rid consecration. There can be no doubt that the Greeks and Romans also worshipped fire, under the names of Esi« and Vesta. It may be remarked by the way, that as the Latin name of this deity is evidently from the Greek, some learned writers have with great probability traced the Greek word to that country in which, it has been supposed, fire-worship had its origin. The Chaldaic term Zsth signifies fire, synonymous with Hebrew Tw, ashch *. Whether cremation was originally meant as a sacrifice or not, it cannot be denied that a variety of circumstances were conjoined with it, which had the closest connexion with this act of religion. The funeral-pile was erected in the form of an altar. Hence the language of Vircit, when describing the obsequigs of Mr- SENUS 3 Aramque sepulchri Congerere arboribus, czloque educere certant. fin. lib. vi. —— Cremation was accompanied with the oblation of victims. Originally the blood of captives was shed. Acutuzs sacrificed twelve gallant Trojans in honour of his friend Parrocuus fF. Gladiators were afterwards substituted for captives. These were * V. Srucku Sacr. p. 151.; Pier. Hieroglyph. fol. 135, b.; Bocuart, de fEn, p. 13. + Iliad. ¥ ver. 175. OR THE BURNING OF THE DEAD. 125 \ were by the Romans called Bustuarii, because their blood was shed before the bustum, which was the designation given to the funeral-pile, after the body was combustum, or burnt; or, as others say, quasi bene ustwm, thoroughly burnt or consumed. For it bore the name of rogus, while the fire continued to burn; because, as Servius explains it, during this operation the attendants continued rogare, to call upon or invoke the manes of their departed friend. They sometimes sacrificed beasts, as oxen, swine, &c. which they threw into the blazing pile. Multa boum circa mactantur corpora morti, Setigerasque sues, raptasque ex omnibus agris Tn flammam jugulant pecudes. “En, lib. xi, It must be acknowledged, however, that while the ancients, in some passages, unquestionably speak of these offerings as made to the manes, or ghost, of the person whose funeral was celebrated, in others their language can apply only to the Di Manes, or infernal gods. This inconsistency causes consider- able difficulty in attempting to form a judgment with respect to their proper design in these oblations. When the body was consumed, they extinguished the fire by pouring wine upon it. This is said to have been done, that they might more easily collect the bones and ashes. But even this has much the appearance of a sacrifical act, and may ori- ginally ‘have ‘been ‘meant as a libation. Water, because of its purity, might otherwise have been preferred for extinguishing the flames. From the manner in which Homer describes the employment of AcuitiEs, while watching the flaming pile of Parrocius by night, it would seem: that he continued to pour wine on the ground, as a libation to the manes of his friend : ‘Osvov 126 ON THE ORIGIN OF CREMATION, Ne , , ~ ay ~ Ojvoy aPvocopnevos ycepce 65 y 4rd deve 05 Y Usa, Won HIEANTLOY TlareoxAnos OesAoro. Tliad. ¥. ver. 220. Prato informs us, that the ancient Greeks hired female mourners, whose office it was to. bewail the dead, and to make libations *. It may be also observed, that they evidently wished that the wine, used on this occasion, should as nearly as possible re- semble blood. Thus, in the account given of the funeral of Hecror, we find it expressly mentioned that the wine with. which the remains. of the fire were extinguished, was dark-co-- loured, ~ \ \ +X , Ld ww Tlgaroy (ee? LATO VCH oPeouy asbors Ola Ildowy oxorooy emerye mugos puevoc: Thid. a. ver. 791. Now, this is the very language which the same illustrious: pet had employed to denote the libation by Curysrs, the priest of ApoLto, on the joints of the hecatomb, which he of-- fered as an.expiatory sacrifice for the Greeks. Kate 3 emi oyilns 6 yéewr, ext 0 ciBorce osvor. Ibid. a. ver. 462. I have already adverted’ to the Indian practice of casting frankincense on the funeral fire. As the use of incense has from time immemorial been an established rite in. sacrifical worship, it appears that it was not unknown to the Greeks and Romans, in celebrating the obsequies of the dead. Kircuman has * "lepeie re meorPelrovres med TBs exPoghs +H vengov, xa eyyurersins weremeumousvol PLAT. Minoe, Oper. ii. 315.. KincHMan supplies some observations on this singular rite. De Funer, p. 370. OR THE BURNING OF THE DEAD. 127 has remarked, that he finds incense mentioned among other spices, which were thrown into the funeral-pile. The great expence in multiplying these might latterly proceed from mere ostentation. In some instances, they might be merely meant to overpower the fetid odour arising from the act of cremation. But it may be supposed, that the use of incense had originally a sacrifical signification. Lucan, when describing the funeral of Pompey, mentions this as the only odoriferous substance that. was burnt with the body *. Non pretiosa petit cumulato thure sepulchra Pomrstus, Fortuna, tuus. Pharsal. lib, viii, Without particularising the games celebrated at funerals, or the feasts connected with them, which were on other occasions accompaniments of sacrifice, I shall only add, that besides the pyre, which had the form of an altar, another altar was erected, after cremation, immediately before the sepulchre. This recei- ved the name of acerra; and is by Servius expressly distin- guished from the funeral pile +. * Kircuman. De Funeribus Romanorunm, p. 226. + In dn, lib. vi. VI oe i “~ Fiaene ‘aig hi Boetetaey ‘vet | eae 30s em mt @ cone ott ve faces ra cope ‘cadets ani: toe ES saliey tiictalk qh tondi wieteately vender inch Fetadsdpeettowad tebe cve, cach eh Ta aay ue sph Aikertrs me Iestaare re’ , a ? oie as aaa ‘ay a We / | tid be scorn A - wheres a + nk = . tf ate a i tea Wrepre ett! ican i phen 2 bt etre «A teaehvanra ; "et A pth 7 a aletoeiul ja bean ‘ofS: De we ¥ih30 no eto) j : ‘att pebpimedl imi bho iho hapa te vane HN pays. addon 7 a sa | fenbatpeaths gee fi cath ee ee ete Pee hcg’ ‘im ee est Oiaciw sad .* ee wc taal goa | soba se Ga bean y we eh bah te ied sad Ga Bharat we : ca RA, ta ce f ee ee wig Swe pt ae a ori ae) gui iia 8 Na Staphamia. eat shania ’ , vu & at ARPS tory cae ‘” I sk Cede Oe RY OO 7 " bese \ ae wit o® on ont ww a ~~ pe 4e*>” a a oftt.] VI... Additional Communications respecting the Blind and Deaf Boy, Jamzs Mircuexrt. By Joun Gorvon, M. D. F. B.S. Epin. { (Read Nov. 20. 1815. ) 55 HE following circumstances respecting the Blind and Deaf & Boy, James Mircuetr, have come to my knowledge since the publication of Professor Srrwart’s Memoir; and I doubt not but the Society will think them worthy of being recorded. They are derived from the most accurate and authentic of al] sources, the boy’s sister, Miss Mircuett. _In the month of April 1814, Mr Parker, an English gen- ‘tleman, (distinguished, as I have since learned, for his active benevolence,) did me the honour to wait upon me, to commu- nicate a plan for the instruction of young Mircuetx, which had some time before occurred to him, and which he was very de- sirous should be put to the test of experiment. This method seemed in no respect inconsistent with those principles which in all circumstances appear to regulate the acquisition of lan- guage; and IJ therefore expressed my willingness, to promote, by every means in my power, the object which Mr Parker had in view. Vou. VIII. P. I. R Mr 130 ADDITIONAL COMMUNICATIONS Mr Parker, accordingly, took the trouble of getting an alpha- bet cut in wood ; the letters of which were in relief, and in sepa- rate pieces, each about an inch long. He provided, also, two other alphabets, one of pasteboard, and the other of metal, with the letters of the same size, and detached, as in the former. These alphabets I transmitted to Miss Mrrcnett on the 2d of June; informing her, at same time, of the purpose for which they were intended; and expressing my anxiety, that she would lose no time in giving the plan proposed a fait trial. Particular di- rections for the use of the alphabets were drawn up by Mr Parker; and I took the liberty of adding only a few general hints ; being well aware how unnecessary it was to go into the minutie, when addressing so judicious a preceptor. The outline of the plan was simply this: The name of any familiar object being chosen, such as egg, bread, sugar, arm, &c., the letters forming the word were to be put together by Miss Mrrcnett, exactly as they are arranged in print. Mrrcuetr was then to be made to touch, first the object, and then this word, in immediate succession, as often as possible; so as to form a close association in his mind, between the thing and its tangible name. It was left entirely to Miss Mrrcnetx’s judg- ment, to employ such means as she deemed best, for securing her brother’s perseverance in the task for such a length of time, as might enable him to perceive its object: And in the event of this primary and fundamental step being gained, the experi- ment was to be prosecuted, according to similar principles. The following is a copy of a letter which I received from Miss Mircuext, dated Nairn, the 30th June. - “ Ihave been from home during these last ten days, which has prevented my sooner acknowledging the receipt of your favour RESPECTING THE BLIND AND DEAF BOY. 131 favour of the 2d instant, accompanying a parcel from Mr Par- KER, to whom we consider ourselves very much indebted for the interest he takes in my brother. Have the goodness to make offer of our warmest acknowledgements to him, and say that I shall, with much pleasure, avail myself of the liberty he allows me, of informing him of the progress made, in the plan he has so ably sketched for my brother’s instruction, which I mean to attempt immediately, and: shall not be easily discou- raged by not succeeding at first. If I can once interest my bro- ther, by affording him any gratification, in my communications by the means of letters, I shall have very great hopes of suc- cess. I shall first try the pasteboard letters, as I think them less likely to distract the attention than the wooden ones. “« My brother was twice at Ardclach of late. The first time, he probably found his way there by chance, as) he had not been. at Ardclach before, since he came to reside. at Nairn ; 3 but the md. time, he must have gone intentionally, as there:was on- e one day between the two visits. I have seen Mrs Macsran since these visits, and inquired particularly respecting his con- duct. The first day, after having taken some refreshment, he went through the different apartments of the manse, examin- ing, by touch, the furniture, &c. and seemed to miss a closet- door, which had. been shut up after we left the place. He did not betray any particular emotion, upon thus visiting, for the first time, a house which had been for so many years his home; but when he had satisfied his curlosity, seemed anxious to get away, and returned directly to Nairn. On the second visit, he found workmen employed i in taking down the kitchen, (a part of the 1 repair which the manse was then undergoing,) and after standing some time, evidently very much displeased at the _work of destruction which was going forward, he came away in very bad humour, and could not be prevailed on to return and R 2 go 132 ADDITIONAL COMMUNICATIONS go into the house. He did not discover the least wish to visit the church-yard either time. “ T had an opportunity of observing his conduct with regard to a dead body very lately ;—the body of an old gentleman, a near neighbour of ours, and one who had been very kind to him, frequently indulging him with a pipe and tobacco, his fa- * vourite gratification. I brought him to the room where the body was laid, and allowed him to feel it, which he did very willingly, not shrinking as upon a former occasion, but seem- ingly rather anxious to examine it. When he had done so, he stood for a few seconds, rather thoughtful ; and this was follow- ed by a smile, with, I thought, something of wildness in the expression of the countenance. He then came away very wil- lingly with me, but not before he shewed that he recognised the person, and was sensible of the situation. This he did, by making his usual sign for smoking, and by putting his hand to the ground, his sign for interment. He discovered a wish to learn when the ceremony was to take place, (by a slight incli- nation of his head to one side,) which I endeavoured to inform him of; and he kept constantly in the way until it was over; frequently going to the apartment where the body was kept ; but without discovering sorrow, further than now and then ap- pearing rather thoughtful. “ These particulars are perhaps of little consequence; but from the great interest you have always taken in my brother, I think it right to mention them. And, with best respects, -I m,” &c. The following letter, dated Nairn, 31st October 1814, is from Miss Mircuett to Mr Parker, and communicates the complete failure of her attempts to educate her brother by ‘means of the tangible alphabet. “ Srr, RESPECTING THE BLIND. AND DEAF BOY. 133. “ Sir, ya coe! “ T have from time to time deferred writing you, from a de- sire rather than from a hope, of being able to give you favour- able accounts of the result of my endeavours to instruct. my brother, by the means of letters; and regret excessively being obliged to state, that I have completely failed in putting into. effect the plan you so ably sketched out for me, principally, and, indeed, I may say wholly, from my brother’s wanting the necessary habits of application. With my first attempts he seemed rather amused, but afterwards appeared teazed, and got into bad humour, and, without risking the loss of the little power I have over him, I could not persist in irritating him,, being sensible that I only retain it from having recourse to it. seldom, and using it sparingly. How much I am grieved, at thus being obliged to relinquish a plan from which so much benefit might have been derived, I cannot say ; my only con- solation is, that it is not from any want of exertion on my part. Had any such plan been commenced with him in infancy; or at an early period, and steadily persevered in, I doubt not but it might have had the wished for success; but now, when ‘his habits are formed, and his passions strong, I much fear there is little chance of any thing being done; at least if there is any: thing done, it must be by some person who has more the power of controlling him than I now have. In short, I am unable to. make it sufficiently interesting to be a source of amusement to him, and, as a task, he will not apply to it. Nor is it (how- ever much to be regretted) astonishing that he will not, accus- tomed, as he has always been, to follow his own immediate gratification only, and dispose of his time as inclination leads him.—Allow me now to’ make offer of our warmest acknow- ledgments for the benevolent interest you have taken in this affair, and to assure you, that it will afford us much happiness to be 134 ADDITIONAL COMMUNICATIONS be at any time able to show, how sensible we are ea your good- ness. And I have the honour to sai &e. In the month of December 1815, I had the pleasure of re- ceiving a letter from Miss Mrrcuett, from which the follow- ing is an extract. “ I cannot say that my brother is making any very visible progress in knowledge ; but he had a severe illness, about ten or twelve months ago, which rather placed him in a new point of view, and I shall endeavour to mention what we considered as most striking in his conduct. In the first place, he seemed very apprehensive of dying, at least we could not otherwise ac- count for many of his actions, than by supposing they proceed- ed from a fear of death. Although reduced to that state of de- bility that he could not move without two people supporting him, we never could prevail with him to lie a single day in bed; he literally watched the first appearance of dawn, and insisted on being dressed immediately, thinking, probably, that he would not die out of bed. Any thing white, too, he could not. bear to see near his bed, or even in the room with him. Several times, by accident, something white was thrown across the foot of his bed, and he appeared most unhappy un- til it was removed, attempting most eagerly to grasp it himself, before we discovered the source of his uneasiness. In the same way, too, when any linens were put to the fire to air by him, he was in the greatest possible distress until they were ta- ken out of his sight ; and this, when there was not any glare of light that could affect him ; it, therefore, must have been some idea connected with them that distressed him; and from his having always seen dead bodies laid out in white, we could on- ly attribute his evident dislike, to his associating the idea of death and this appearance together. He took a particular fan- ei, RESPECTING THE BLIND AND DEAF BOY. 135 cy to a sister of my father’s, who was here at that time, insist- ing on her sitting constantly by him, (probably from finding her kind and attentive to him). But I chanced to be taken ill before he was quite recovered ; and after my being attacked, he would not allow her to sit down near him, but always signed to her to go up stairs where I was, and was not satisfied until he made good his point. This is, perhaps, the most decided in- stance of affection and consideration for. others, he has ever shewn. He, once or twice, discovered a: wish to get. up stairs. himself, and, upon being brought up, seemed quite satisfied: when I patted him, and shook hands with him.” 9h ei VIL. Sse wel vole So iets rite wi og oF + puns Aird ue A wii ae i i “ent ip ine te ri mom ‘hath en ti : Beaashondinlinccs th Sane Y viet 8 ‘Vas Dray Auth diate 0 "a ye hy ap eee’ Sonceahntectbetls Cis el IP te Aeneitiens HEE ER EY On eee fay i ea me Age: iets anit nin nit aL brie: iv Raval ney bacwt Ye! oui ey lhvnetentites, eoAkieteray 8 INFO RTI aid rey rn i eh oe tae er our CURA SAP tei elses odtterteat om ee MR “wel cos thor a pis dt AO Letiipeent egy 6 Be eI CD wiley Bicone . Bee eee, eet ey ae Unset eg etter esr ARTA EB gl BO na mans WU | ype: ‘Bde deeb, Sp ; ‘ Minden Athi heli al + is Naito ath a se xa ; : , i i ee saebegoah : a a pan tia ceivtamsitnes qt ay aed ‘na ig EF daivay! oA Tesi y (Se Panties aechetoaa gihect vonage eaten ” Re en aes Pr Roe vid rte Monee: 8 rbitided anni corey es Co pena pws eet ors i wie panto , swnett ana og ee BBiiredsolonocjagn (hava 16x “ pi fiielin a dat iwi raronte arate ses nb eT es gerne . bawolln (ioemvinws at a gos ait! ‘tot, (oR a age ue : “aQiirodhipg soul or i Sy oT i X = = —s = = | \~aes ee eS pH O ee eon Sa Ee x iat? e A Fredy j we S se | } pee ; se VHD : g Sk AES oder ay / i S ; Be a see fe Se ae a : es | i ENV $VAGD 0a0 WO VY ~~ a ; ay \ Shae / | : fix ese a\ 7 : ! ) o-- t Ye = Vy Cats | 29S s qa . is | % ic 1 Z & a Ne yw VIS: 7 2 Ss | ; Tae Sayuoy \\ Ns Neti ons hes | | < = N a \ yst8 wopessl> \ pate wop9stl / { i Ne Sriooen are . : Ite Se t a = / | a) y * J prise. _\ ? ) a ee nt \ / AY & of \ if ‘ Le fod \ din V 3 5 red di * She are pee ofr . ae ai Dy | | “inty au ; S : 5 ve lee ; a — TAA le Site 5 5 ue Pen, | vd s = . = iy 7 bps a, Sa) = 2 ia ya ete = = #¥ So —— Beek We mo Se at XI. An Analysis of Sea-Water ; with Observations on the Ana- lysis of Salt-Brines. By Joun Murray, M. D. F.R.S. E. (Read 15th April, and 20th May, 1816. ) HE composition of Sea-Water has been variously sta- ted by different chemists, not only with regard to the peahradtisih of the salts which it holds in ews but with re- gard even to the ingredients themselves. According to Lavorsrer, it contains muriate of soda, muriate _of magnesia, and muriate of lime, sulphate of soda, sulphate of magnesia, sulphate and carbonate of lime. The pro- portions he assigns are, in'a pound of water, (French weights) 126 grains of muriate of soda, 14% grains muriate of magnesia, 23 grains muriate of lime mixed with muriate of magnesia, 7 grains of sulphate of soda and sulphate of magnesia, and 8 grains of sulphate and carbonate of lime *. BereMan gives a very different statement. He found only muriate of soda, muriate of magnesia, and sulphate of lime; the proportions in a Swedish kanne, which is equal to about 64 English pints, are 2 ounces 433 grains of muriate of soda, 380 ) grains “* Memoires de Academie des Sciences, 1772. 206 AN ANALYSIS grains of muriate of magnesia, and 45 grains of sulphate of lime *. Reducing them to English weights, they are equal, in a pint of water, to, muriate of soda 241 grains, muriate of mag- nesia 65.5, sulphate of lime 8. This, however, is with regard to water from the Canaries, containing 1 part of saline matter in about 231 of water. Reducing it to the proportion of the water of our shores, that of about 1 to 30, the proportions will be, muriate of soda 186.5, muriate of magnesia 51, sulphate of lime 6 = 243.5 grains. Bereman’s analysis is evidently incorrect in the omission of sulphate of magnesia, which every other chemist has obtained, and which is known to be extracted even on a large scale. And, what is singular, this did not arise from his not being aware that it might be present. On the contrary, he made an experiment to discover it ; and even now, in reviewing his me- thod, it is not apparent how he had been deceived. He eva- porated to dryness, and treated the dry residuum with alcohol, by which he found muriate of magnesia to be dissolved; he then washed the residual matter, consisting chiefly of muriate of soda, with a small quantity of warm water, by which, as he remarked, if any sulphate of magnesia were present, it ought to have been dissolved. But this water shewed no signs of the presence of this salt, either in taste or by precipitation, and contained nothing but a small portion of common salt. Now unquestionably, in this way, sulphate of magnesia ought to have been discovered ; or if it should be supposed that it does not originally exist, but that sulphate of soda is the primary ingredient, still the method employed was equally proper to discover this latter salt. The only supposition that can be made is, that, in the first step of the analysis, a very weak alco- : hol * Beroman’s Essays, vol. i. p. 230. ae OF SEA-WATER. 9207 hol had been used in large quantity, by which a portion of these sulphates would be dissolved, though still it is difficult to imagine that in this way they would be entirely abstrac- ted. Lavoister’s analysis has been considered as incorrect in two circumstances,—in the finding muriate of lime and sulphate of soda. Neither of these have been discovered by other che- mists ; and in a late analysis of sea-water by Vocrt and La- GRANGE, one of the objects of experiment was to detect their presence, and the conclusions drawn were, “ that sea-water “‘ contains no sulphate of soda,” and “no muriate of lime.” In this analysis the saline ingredients found in sea-water were the same as those assigned by Berean, with the addition of sulphate of magnesia. In 1000 grammes there were found 25.10 grammes of muriate of soda, 3.5 of muriate of magnesia, 5.78 of ~ sulphate of magnesia, 0.20 of carbonate of lime and magnesia, and 0.15 of sulphate of lime *. Some other recent analyses have been given; that by Licn- TENBERG is noticed by VocreL and Lacrance, from a German Journal, as approaching to’ their own; and that of Prarr, in which, as in Lavoisrer’s analysis, there is found a portion of muriate of lime. It is obvious, that there remains a degree bf uncertainty with regard to the ingredients of sea-water, sufficient to give interest to a new analysis. The principle, too, which I have illustrated in a preceding paper, on the analysis of Mineral Waters,— that the substances obtained are not always to be regarded as the original ingredients, but frequently as products of new combinations established by the analytic operations, may con- tribute to throw light on the conclusions to be drawn, and seemed * ‘Tuomson’s Annals, vol, iv. p. 200. 208 AN ANALYSIS seemed to me to admit of being applied to the explanation of some of the preceding results. This led to the experiments of which I now propose to give an account. The peculiarity in the results of Lavorsrer’s analysis, and with regard to which the others differ from him, is the obtain- ing, as ingredients of sea-water, portions of sulphate of soda and muriate of lime. Applying the principle now referred to, it is obvious, that in an analysis by evaporation, the composi- tion of these salts would be subverted by their reciprocal ac- tion ; neither of them would be obtained ; but by mutual decom- position they would be converted into muriate of soda, and sulphate of lime. Sulphate of lime is accordingly obtained in all these analyses, and probably has this origin. But, admitting this, how had muriate of lime, and sulphate of soda, been procured by Lavorsrer. This, supposing the re- sult accurate, can only be ascribed to some peculiarity in his process, by which their mutual action had been prevented, and their distinct existence preserved. The method he employed was to evaporate sea-water to dryness ; during the evaporation, sulphate and carbonate of lime were precipitated and were withdrawn ; the dry saline mass was lixiviated with alcohol ; and the ley being poured off clear, was found to hold in solu- tion muriate of magnesia, and muriate of lime; the undissol- ved matter was then heated, with a mixture of two parts of al- cohol and one of water, by which it was almost entirely dissol- ved ; it deposited, however, on cooling, a white powder, which was found to be sulphate of soda, and sulphate of magnesia, and it retained dissolved the muriate of soda of the sea-water with a portion likewise of muriate of magnesia. Now a portion of sulphate of lime was obtained in this pro- cess, which, according to the view I have stated, was probably produced OF SEA-WATER. 209 produced by the mutual decomposition of sulphate of soda and muriate of lime. But it is also possible, that this decomposi- tion might not be complete. I had formerly found, indeed, that when a liquor containing these two salts is evaporated, their decomposition is not entirely effected *; it seemed pos- sible, therefore, that portions of both might remain undecom- posed in Lavoisier’s process; the alcohol applied to the solid matter would remove the muriate of lime, and thus the sul- phate of soda would remain. To elucidate the whole subject, therefore, it seemed. best to repeat LavoisiEr’s analysis as he had performed it, and ascertain the actual results, A. Four pints of sea-water of the Frith of Forth, taken up near Leith, at a distance from any fresh water, were evapora- ted by the heat of a sand-bath ; the evaporation being continu- ed until a pellicle of salt formed on the boiling liquor. A pre- cipitate subsided during the boiling, which being washed, weighed when dry 25 grains. B. The liquor was evaporated to dryness, and the saline mass was dried thoroughly by a continued heat of about 150° ; it weighed 1025 grains. To separate the salts composing it, it was submitted to the action of alcohol. About 4 ounces of alco- hol of the specific gravity of 840 were poured upon it.in a bottle, and allowed to remain over it for 12 hours, being occa- sionally agitated; and when poured off an ounce of the same alcohol was added, and after frequent agitation, and being kept _ oyer it for some hours, was poured off, and added to “ithe for- THER hysy anys t: gris cil an C. The. residuum, aM risibgs asieiaia 890 tininisyaid 96 grains had mreraline been abstracted, consisting maa of earthy, mutiates. faliiues it’ Indoeauspiloh Vou. VILL P. L puri: d ; D. The * Transactions, Vol. vii p. 475. 210 AN ANALYSIS D. The saline matter was digested with 9 ounces of a weak- er spirit, composed of 2 of alcohol and | of water, heat being applied to it by a sand-bath nearly to ebullition, with frequent agitation; and the liquor having been poured off while hot, 4 ounces more of the same diluted alcohol were added, heated as before, and after it had become clear by subsidence, this li- quor was added to the other. The greater part of the saline mass, consisting chiefly of muriate of soda, was thus dissolved. E. The residue was submitted to the action of successive quantities of a still weaker spirit, composed of 3 of alkohol, and 4 of water, aided by heat, with the view of dissolving the sul- phate of magnesia and of soda. A solution was obtained of a strong saline taste. F. To abstract these salts more completely, the residue was lixiviated with small successive portions of warm water ; a so- lution having a similar taste was obtained. G. There was left at length a powder, soft, light, tasteless, and insoluble. It now remained to examine these products more minutely, to determine their nature, and estimate precisely their quanti- ties. The powder obtained in the first evaporation A, consists, according to Lavorster, of sulphate and carbonate of lime. It weighed when dry 25 grains ; it was submitted to the action of a very dilute alcohol, acidulated with muriatic acid, which ex- cited effervescence ; this being poured off, and the residue be- ing lixiviated, and dried, weighed 22 grains. It was sulphate of lime, and absorbed water with avidity, becoming solid and dry. The liquor poured off, afforded by evaporation a saline deliquescent matter, which, heated with sulphuric acid, gave products Nae OF SEA-WATER, 211 products equivalent to 1.7 grains of carbonate of magnesia, and 1.2 grain of carbonate of lime. The solution (B) obtained by the action of the stronger al- cohol, ought to have contained, according to the results of La- vorsiEr’s analysis, muriate of magnesia and muriate of lime. A small portion of it was diluted with distilled water, and a few drops of a solution of oxalate of ammonia were added, but caused, no precipitation, nor eyen any opacity. The liquor, therefore, contained no muriate of lime. It was distilled to dryness. The dry matter deliquesced on exposure to the air ; being lixiviated with alcohol, a small portion of muriate of so- da remained undissolved, which was added to the solution D. The liquor being evaporated so far as to be of an oily consist- ence, afforded, on cooling, muriate of magnesia in prisms. This, dried until it had no appearance of moisture, weighed 145 grains. Decomposed. by sulphuric acid, it afforded 105.9 grains of dry sulphate of magnesia, equivalent to 88.5 of real mu- riate. The solution D had a strong saline taste, and, in cooling, had deposited muriate of soda in cubes on the sides of the bottle. A little of it being diluted with distilled water, oxalate of ammonia did not impair the transparency. Carbonate of potash, and muriate of barytes, produced a turbid appearance. The entire liquor was submitted to distillation, until the alcohol _ was abstracted, and was then evaporated in an open bason, un- til crystals formed in it while hot. These were cubes of mu- viate of soda, and this salt continued to be afforded by succes- sive ‘evaporations. The last product deliquesced a little on exposure to the air, indicating the presence of muriate of mag- _nesia ; and the remaining liquor afforded by evaporation a deli- quescent saline mass: both these were washed with repeated - portions of alcohol ; muriate of magnesia was thus obtained, Dd2 which 212 AN ANALYSIS which dried, weighed 17:3 grains, and which, converted into sulphate, gave 12.4 grains, equivalent to 9.7 of real muriate. The matter not dissolved by the alcohol, being dissolved in wa- ter, afforded by slow: evaporation sulphate of magnesia in prisms, which dried, weighed 6.3 grains. The crystallised) mu- riate of soda, dried at a heat of 200°, weighed 580 grains. « The solution E deposited, on standing after twelve hours, ery- stals in flat striated prisms, having every appearance of sulphate of soda, and which, on more minute examination, were found to be so: freed from sensible moisture, they weighed 18 grains. The liquor diluted with distilled water, was not sensibly affect- ed by oxalate of ammonia; it became slightly turbid with sub- carbonate of potash, and with muriate of barytes. The alcohol was drawn off by distillation ; being then submitted to evapo- ration, a crust of muriate of soda formed on the surface, and crystals in cubes were deposited ; additional portions of them were obtained by successive evaporations, and the liquor conti- nued to afford a crust of muriate of soda on its surface, while hot, until it was almost entirely evaporated. A small por- tion of liquor remained, which, on cooling, afforded prisma- tic crystals of sulphate of magnesia, which, freed from moisture, weighed 8.9 grains. The muriate of soda dried weighed 170.8 grains. The first portions of the aqueous solution F had deposited crystals of sulphate of soda on cooling ; and the whole quanti-~ ty being partially evaporated, yielded an additional portion. The crystals of both, freed from adhering moisture, weighed 44.2 grains. The liquor being farther evaporated, cubes of muriate of soda were formed on the sides of the capsule, while it was warm, and by continuing the evaporation, a quantity of this salt was obtained, which weighed when dry 12.3 grains. oa bs h r = ta a a cS ke et oe OY SEA-WATER. 243 to the end of it, and the muriate of soda would be depo- sited in the same manner ; so that the proportion between the two would continue nearly the same, But if the sulphate of lime did not exist in solution, but derives its origin from the action of sulphate of soda on muriate of lime, which these brines contain, this action would take place, when a certain degree of concentration of the liquor had been attained; the sulphate of lime would then be copiously deposited ; but as the evaporation continued to proceed, its quantity would be di- minished, as the quantity either of sulphate of soda, or of mu- riate of lime, became less; and its deposition would cease when either of these salts was exhausted. This is placed in a still clearer light, by an analysis of these brines, after evaporation, to a certain extent, compared with their original composition. A brine from Northwich was found by Dr Henry to afford, by evaporation, saline matter, which, he inferred, contained in 1000 parts, muriate of lime and muriate of magnesia in nearly equal proportions 5 parts, sulphate of lime 19 parts, muriate of soda 974 parts. But the brine remaining after the separation of all the common salt, which it is thought worth while to extract, afforded saline mat- ter by evaporation, which he found to contain, in 1000 parts, muriate of magnesia 35, muriate of lime 32, sulphate of lime 6, muriate of soda 927. Here, in the progress of the evapora- tion, the quantity of sulphate of soda, which may be consider- ed as an original ingredient of the brine, had been diminished by the decomposition arising from its action on the muriate of lime. The liquor, therefore, after this, afforded by farther evaporation, along with a large quantity of muriate of lime, a small quantity only of sulphate of lime ; while, if this sulphate had been an original ingredient, it would have continued to be afforded at least in equal proportion. Hh 2 Something 244 AN ANALYsI8, &c. Something similar to this occurs in the evaporation of sea- water. It is, after a certain extent of evaporation, but while a large portion of liquor still remains, that the precipitation of sulphate of lime takes place ; that is, after the concentration is sufficient to favour the mutual action of the sulphate of soda, or sulphate of magnesia, and muriate of lime. After this, the quantity diminishes as the evaporation proceeds, till at last not a trace of it, or of sulphate of lime, remains in the bittern, which consists of muriate of soda, muriate of magnesia, and sulphate of magnesia alone. This curious fact has not been particularly noticed, though it is in consequence of it that mag- nesia is prepared from bittern on the large scale, perfectly pure. All these facts seem scarcely to admit of any explanation, but on the view that has been stated, and they afford a strong confirmation of it. XI. “ a ET el XII. Elementary Demonstration of the Composition of Pres- sures. By Tuomas Jackson, LL.D. F.R.S. Eni. and Professor of Natural Philosophy in the Universi-- ty of St. Andrew’s. (Read June 3, 1816.) T is well-known as a fundamental principle in statics, that’ “« Two pressures, represented in direction and quantity by “ two adjoining sides of a parallelogram, are equivalent to one “ represented in direction and quantity by the diagonal “ which passes through the point at which these sides meet.” A demonstration of this proposition, that shall be at once suf- ficiently concise, and sufficiently elementary, to admit of its be- ing with propriety introduced into a course of academical in-. struction, has been hitherto, so far as I know, a desideratum.. The following may perhaps be — to possess that advan-. tage.. : Lema. “ If the equivalent of two pressures, represented by the ad- “ joining sides of a rectangle, given in species, be always re- “« presented in direction by the eee gee diagonal, it's shall “ be represented by the same in quantity.” Let 246 FLEMENTARY DEMONSTRATION OF THE Let ABCD be a rec- FIG.1 tangle, and AC the dia- gonal passing through eo A; draw EAF perpen- ” A dicular to AC, and let fall the perpendiculars — fort BF, BH, DG, DE: then x shall ABCD, AFBHand =» c AEDG be similar rectangles ; and if, in each of these, the equivalent of the pressures represented in direction and quan- tity by the sides, be represented in direction by the diagonal, it shall be represented by the same in quantity also. For if the forces AH and AF be equivalent to m AB; AE and AG shall be equivalent to m AD; and AB and AD to m AC; or m AB and mAD to m AC: that is, the forces AH, AF, AE, and AG, will be equivalent to m AC: But AE and AF are equal and opposite : hence the forces AH and AG are equi- valent to m= AC. But AH and AG are equivalent to AC; therefore m = 1. 1. Now let ABDC be any square ; and let the sides AB and CD be produced indefinitely towards B and D; draw the dia- gonal AD; in CD produced, take DF equal to AD ; join AF; take FH equal to AF; join AH, and so on. the rectangles ACFE, ACHG, &c. It is obvious, that AD, AF, AH, &c. bisect the angles BAC, BAD, BAF, &c. respectively. Hence the resultant of AB And complete aio i ee _AC makes with AB an angle: COMPOSITION OF PRESSURES- Q4AT AB and AC, which are equal, must be represented in direc- tion by AD; and therefore by the same in quantity also. The equivalent Bo AE and AC being the same with that of BE and AD, which are equal, will be represented in direction, and therefore in quantity by AF, (vid. Lemma). Thus may the- proposition be proved of any rectangle whose diagonal makes, with one of the sides any angle found by the continued bisec-. tion of a right angle. 2. Let (@) be any angle in the series above mentioned ; a proposition shall be true in relation to any rectangle whose diagonal forms with one of the sides an angle that is any mul-- tiple of (a). . Let AB and BC be two sides FIG.3 of a rectangle whose diagonal: in relation to which the propo-- sition has been already pro- ved ; and let CAG be equal to. (a); the proposition shall be. true in relation to the angle- BAG;; for let GED be parallel ™ to AC, and draw the perpendiculars AD, EF, GH:. Ie is al- ready proved, that two forces represented by AD and AF are equivalent to the single force represented by AE; for < DAE= < BAC. AE may therefore be resolved into AD and AF; that is, the forces AK and AC are equivalent to the forces AD and AH, or to the single force AG. Since, then, | AB and BC are equivalent to AC ; and.AC and CG equiva- lent to AG ; AB and BG must be equivalent to AG. 3. Let. 248 ELEMENTARY. DEMONSTRATION, &c. 3. Let BAD be an angle in- commensurable with a right +. angle. The proposition is true in relation to BAC, the multiple of (a) next less than BAD, and of BAE, the multiple of (a) next ™ higher, the difference between which (= a) may be less than any «= assigned angle. But the equivalent of AB and BD must, in respect of direction, be always intermediate between the equi- valent of AB, BC, and that of AB, BE. It must, therefore, pass through D; and this is evidently true in the case of any similar rectangle ; that is, so long as the angle BAD remains the same. Hence it must be represented by AD, also in quan- tity (vid. Lemma). From what is said above in § 2. it is manifest that celia has now been proved universally of the rectangle, may be extend- ed to the oblique-angled parallelogram. XIII. XIII. Account of the remarkable Case of Marcarer Lyart, who continued in a State of Sleep nearly Six Weeks. By the Reverend James Brewster, Minister of Craig. Com- municated by Dr Brewster. (Read February 19. 1816. ) My Dear Broruer, Manse of Craig, Feb. 16. 1816. HE inclosed account was drawn up at the request of Roser Grane, Esq. when all the circumstances were fresh in my own recollection, and that of all with whom I had occasion to confer on the subject. Since you requested me to send you a correct copy of the whole case,I have renewed my inquiries a- mong the friends of the young woman, and submitted my ac- count to several persons, who were most capable of supplying any omissions, or correcting any mistakes. [ can confidently vouch for the general accuracy of the statement ; but would not wish its credibility to rest entirely on my single testimony. I have, therefore, procured the signature of the young woman’s fa- ther, and of several gentlemen, with whom you are more or less - acquainted, and who frequently saw hér during her illness. The account of her recovery, on the 8th of August, indeed, rests wholly on the testimony of the father, which there is not the smallest reason to doubt. I am sensible, that many of the cir- cumstances which I have mentioned, may appear to be unne- Vou. VII. P. 1. Ti cessarily 250 ACCOUNT OF MARGARET LYALL, WHO CONTINUED eessarily minute, or even altogether unimportant ; but, in de- tailing so remarkable a case, I did not think myself qualified or entitled to select according to my own judgment ; and consi- dered it to be my business, as a reporter, merely to relate, as clearly and correctly as possible, whatever was observable in the situation of the patient. I have noted, also, her previous em- ployment, the places where she resided, and some of the indi- viduals who attended to her case, partly to render the account more intelligible, and partly to enable others to make farther inquiries for themselves. I may mention farther, in case you may not be aware of the circumstance, that there is a similar case recorded in the T'ransactions of the Royal Society of Lon- don for 1705, vol. xxiv. p. 2177. Yours, &c. To Dr Brewster. Jas. Brewster. Margaret Lyatt, a young woman, about twenty-one years of age, daughter of Joun Lyat1, shoemaker in the parish of Marytown, served during the winter half-year preceding Whitsunday 1815, in the family of Perrr Arxiry, Esq. of Dunninald, in the parish of Craig. At the last mentioned term, she went as servant to the Reverend Mr Foorr of Lo- gie; but, in a few days after entering her place, was seized with a slow fever, which confined her to bed rather more than a fortnight. During the latter part of her illness, she was convey- ed to her father’s house; and, on the 23d of June, about eight days after she had been able to leave her bed, she resumed her situation with Mrs Foorr, who had, in the mean time, removed to Budden, in the parish of Craig, for the benefit of sea-bath- ing. She was observed, after her return, to do her work rather in a hurried manner; and, when sent upon any errand, to run or an IN A STATE OF SLEEP NEARLY SIX WEEKS. 251 or walk very quickly, as if impatient to finish whatever she had in hand. Her health, however, appeared to be perfectly restored, except that her menses were obstructed. On Tuesday morning, June 27th, about four days after her return to service, she was found in bed in a deep sleep, with the appearance of blood having flowed from her nose ; and about half a Scotch pint of blood was perceived on the floor, at her bed-side. All attempts to awaken her were utterly ineffectual ; and she was conveyed in a cart to her father’s house, about half a mile distant from Bud- den. Dr Grzson, physician in Montrose, having been called, a pound of blood was taken from her arm; but she still remain- ed in the same lethargic state, without making the slightest motion, or taking any nourishment, or having any kind of eva- cuation, till the afternoon of Friday the 30th day of June, when she awoke of her own accord, and asked for food. At this period she possessed all her mental and bodily faculties ; mentioned distinctly, that she recollected her having been awa- kened on Tuesday morning at two o'clock, by a bleeding at her nose, which flowed very rapidly ; said, that she held her head over the bed-side till the bleeding stopped ; but declared, that, from that moment, she had no feeling or remembrance of any thing, and felt only as if she had taken a very long sleep. An injection was administered with good effect, and she went to sleep as usual; but, next morning, (Saturday, July 1.), she was found in the same state of profound sleep as before. Her breathing was so gentle as to be scarcely perceptible ; her coun- tenance remarkably placid, and free from any expression of distress ; but her jaws were so firmly locked, that no kind of food or liquid could be introduced into her mouth. In this si- tuation she continued for the space of seven days, without any motion, food, or evacuation either of urine or feces. At the end of seven days she began to move her left hand; and, by 1i2 pointing 252 ACCOUNT OF MARGARET LYALL, WHO CONTINUED pointing it to her mouth, signified a wish for food. She took readily whatever was given to her, and shewed an inclination to eat more than was thought advisable by the medical atten- dants. Still, however, she discovered no symptoms of hearing, and made no other kind of bodily movement, than that of her left hand. Her right hand and arm, particularly, appeared completely dead and devoid of feeling, and, even when pricked with a pin, so as to draw blood, never shrunk in the smallest degree, or indicated the slightest sense of pain. At the same time, she instantly drew back the left arm, whenever it was touched by the point of the pin. She continued to take food, whenever it was offered to her; and when the bread was put into her left hand, and the hand raised by another person to her mouth, she immediately began to eat slowly, but unremit- tingly, munching like a rabbit, till it was finished. It was re- marked, that, if it happened to be a slice of loaf which she was eating, she turned the crust, when she came to it, so as to intro- duce it more easily into her mouth, as if she had been fully sen- sible of what she was doing. But when she had ceasedto eat, her hand dropped upon her chin or under lip, and rested there, till it was replaced by her side, or upon her breast. She took medicine, when it was administered, as readily as food, without any indication of disgust ; and, in this way, by means of castor oil and aloetic pills, her bowels were kept open ; but no evacua- tion ever took place without the use of a laxative. It was ob- served, that she always gave a signal, by pushing down the bed-clothes, when she had occasion to make any evacuation. The eye-lids were uniformly shut, and, when forced open, the ball of the eye appeared turned upwards, so as to shew only the white part of it. Her friends shewed considerable reluc- tance to allow any medical means to be used) tor her recovery; but, about the middle of July, her head was shaved, and a:large blister ne _IN A’STATE OF SLEEP NEARLY SIX WEEKS. 253 blister applied, which remained nineteen hours, and produced an abundant issue, yet without exciting the smallest symptom of uneasiness in the patient. Sinapisms were also applied ta her feet, and her legs were moved from hot water into cold, and vice versd, without any appearance of sensation. In this state she remained, without any apparent alteration, till Tues- day the 8th day of: August, precisely six weeks from the time when she was. first seized with her lethargy, and without ever appearing to be awake, except, as mentioned, on the afternoon of Friday the 30th of June. During the whole of this period, her colour was generally that of health ; but her complexion rather more delicate than. usual, and occasionally changing, sometimes to paleness, and at other times to a feverish flush.. The heat of her body was natural ; but, when lifted out of bed, she ge- nerally became remarkably cold. The state of her pulse was not regularly marked ; but, during the first two weeks, it was generally at 50; during the third and fourth week, about 60; and, on the day before her recovery, at 70 or 72; whether its increase was gradual was not ascertained. She continued, du- ring the whole period, to breathe in the same soft and almost imperceptible manner as at first; but was observed occasional- ly, during the night time, to draw her breath more strongly, like a person who had fallen asleep. She discovered no symp- toms of hearing, till about four days before her recovery, when, upon being requested, (as she had often been before, without effect), to give a sign if she heard what was said to her, she made a slight motion with her left. hand, but soon ceased again. to shew any sense of hearing. On Tuesday forenoon, the day of her recovery, she shewed evident signs of hearing ; and by moving her lett hand, intimated her assent or dissent in a to- lerably intelligent manner ; yet, in the afternoon of the same day, she seemed to have again entirely lost all sense of hear- ing. 254 ACCOUNT OF MARGARET LYALL, WHO CONTINUED ing. About eight o’clock on Tuesday evening, her father, a shrewd intelligent man, and of a most respectable character, anxious to avail himself of her recovered sense of hearing, and hoping to rouse her faculties by alarming her fears *, sat down at her bed-side, and told her that he had now given consent, (as was in fact the case,) that she should be removed to the Mon- trose Infirmary; that, as her case was remarkable, the Doctors would naturally try every kind of experiment for her recove- ty; that he was very much distressed, by being obliged to put her entirely into their hands ; and would “ fain hope,” that this measure might still be rendered unnecessary, by her getting better before the time fixed for her removal. She gave evident signs of hearing him, and assented to his proposal of having the usual family-worship in her bed-room. After this was over, she was lifted into a chair till her bed should be made; and her father, taking hold of her right hand, urged her to make an exertion to move it. She began to move first the thumb, then the rest of the fingers in succession, and next her toes in like manner. He then opened her eye-lids ; and, pre senting a candle, desired her to look at it, and asked, whether she saw it. She answered, “ Yes,” in a low and feeble voice. She now proceeded gradually, and in a very few minutes, to regain all her faculties; but was so weak as scarcely to be able to move. Upon being interrogated respecting her extraordi- nary * Lest it might be supposed, that this procedure of the father implied a sus- picion on his part of some deception being practised by the young woman, it may be proper to state, that it was suggested by his own experience in the case of another daughter, who had been affected many years before in a very extraordi- nary degree, with St Virus’s dance, or, as it is termed in this country, “* The <: Jouping ague ;” and who was almost instantaneously cured by the application of terror. IN A STATE OF SLEEP NEARLY SIX WEEKS. 255 nary state, she mentioned, that she had no knowledge of any thing that had happened ; that she remembered, indeed, ha- ving conversed with her friends at her former-awakening, (Fri- day afternoon 30th of June), but felt it a great exertion then to speak to them; that she recollected also having heard. the voice of Mr Cowrr, Minister in Montrose, (the person who. spoke to her on the forenoon of Tuesday the 8th of August,) but did not hear the persons who spoke to her on the after- noon of the same day; that she had never been conscious of having either needed or received food, of having been lifted to make evacuations, or of any other circumstance in her case. She had no idea of her having been blistered ; and expressed great surprise, upon discovering that her head was shaved. She continued in a very feeble state for a few days, but took her food nearly as usual, and improved in strength so rapidly, that on the last day of August she began to work as a reaper in the service of Mr Arxuiey of Dunninald; and continued to per- form the regular labour of the harvest for three weeks, without any inconvenience; Extept being extremely — the — day. After the conclusion of the harvest, she went into Mr Anx- LEY’S family, as a servant; and on. the 27th day of September, was found in the morning, by her fellow-servants, in’ her for- mer state of profound sleep, from which they were ‘inable' to rouse her. She was conveyed immediately to her father’s ‘house, (little more than a quarter of a mile distant,) and re- mained exactly fifty hours in a gentle, but deep sleep, without making any kind of evacuation, or taking any kind of nourish- ment. Upon awakening, she arose apparently in perfect. health, took her breakfast, and resumed her work as usual at Dunninald. On the 11th of October, she’was again found in the 256 ACCOUNT OF MARGARET LYALL, WHO CONTINUED the morning in the same lethargic state ; was removed to the house of her father, where she awoke, as before, after the same period of fifty hours sleep ; and returned to her service, with- out seeming to have experienced any inconvenience. At both of these times her menses were obstructed. Dr HENpErson, physician in Dundee, who happened to be on a visit to his friends at Dunninald, prescribed some medicines suited to that complaint ; and she has ever since been in good health, and able to continue in service *. (Signed) Jas. Brewster, Minister of Craig. * On the morning of September 21. 1816, Marcarer Lyatz, whose case is described above, was found in an out-house at Dunninald, hanged by her own hands. No cause could be assigned for this unhappy act. Her health had been good since the month of October 1815; and she had been comfortable in her situation. It was thought by the family, that, a day or two preceding her death, her eyes had the appearance of rolling rather wildly ; but she had assist- ed the day before in serving the table, and Fossa in good spirits that evening. On the following morning, she was seen to bring in the milk as usual, and was heard to say in passing rather hurriedly through a room, where the other maids were at work, that something had gone wrong about her dairy; but was not seen again till she was found dead about half an hour after. She is known to have had a strong abhorrence of the idea of her former distress re- curring ; and to have occasionally manifested, especially before her first long sleep, the greatest depression of spirits, and even disgust of life. a IN A STATE OF SLEEP NEARLY SIX WEEKS. 257 I hereby certify the preceding account of my daughter Mar-- GArEt’s illness and recovery to be correct in every circum-. stance, according to the best of my recollection. (Signed) Joun Lyat. > We hereby attest, That the above-mentioned particulars in the extraordinary case of Marcarer Lyatt, are either consist- ent with our personal knowledge, or agreeable to all that we - have heard from the most credible testimony. (Signed) Perer Arxiey of Dunninald. Anow. Frrcusson, Minister of Maryton. . Wii. Gisson, Physician in Montrose. Vor. VITL PI. Kk AE Ve. A ; pias lige ie A gis an ARS aon ; | lin VIOT a. Iii om £8) | : “he oe 4 . Yews APR pia ppibiehs. phh’, Rivas: a oy ; abit : ‘ + vt 7 4 Es? A orm ii. & aa Me: Piet wenn : wh Suk VERO te P 7 : gi eralnoivendg | tag'l’ Jtokhs gore -jeianc railis . jo suspen beomheol i danecis¢ we iw Ie A agno minions aldibass jog: ait inedh bigysley yl ¢ Hoouehte yawA agen! « (SFC) » ce “ HOD? THY 3G equal id) en ¥ arate & Livy VE - ‘ . . > - 3 Sls Aly 4 aye I. coz bis jawnl esate) 26 iis SROWMOS, Ih MEAL BAe edae PELE ? ewes seaeeals ‘ > 3 ; i . hy ste ¥ A h - ‘s a . cay ol ‘TF ¢ TTS yao “a : sy ts Pine ee pa tity GHA ebay: . 4 bari ' a _ ” . y ‘ *- PES i ae . ¢ ‘i . ‘ & A - % st iT f septa XIV. A General Formula for the Analysis of Mineral Waters. : By Joun Murray, M.D. F.B.S. E. (Read June 7. 1816. ) HE analysis of Mineral Waters has always been consider- - edas a difficult operation. Numerous methods are em-. ployed to discover their ingredients, and estimate their quan- tities, many of which are liable to errors. This diversity of method itself is a source of discordant results. And to those not familiar with such researches, it presents the difficulty of- ten of determining what process is best adapted to discover a particular composition. Hence the advantage of a general for- mula, if this could be given, applicable to the analysis of all waters. The views which have been stated in the papers, connected with this subject, which I have had the honour of submitting to the Society, have suggested a method which ap- pears to me to admit of very general application, and to be- simple, not difficult of execution, nor liable to any sources of error but what may be easily obviated. The principles on which this method is founded, and the details of the process itself, form the subject of the following observations. Two methods of analysis have been employed for discover- ing the composition of mineral waters,—what may be called Kk 2 the 260 A GENERAL FORMULA FOR THE the direct method, in which, by evaporation, aided by the subse- quent application of solvents, or sometimes by precipitants, certain compound salts are obtained ; and what may be called the indirect method, in which, by the use of re-agents, the prin- ciples of these salts, that is, the acids and bases of which they are formed are discovered, and their quantities estimated, whence the particular salts, and their proportions, may be in- ferred. Chemists have always considered the former of these me- thods as affording the most certain and essential information : they have not neglected the latter; but they have usually em- ployed it as subordinate to the other. ‘The salts procured by evaporation, have been uniformly considered as the real ingre- dients, and nothing more was required, therefore, it was ima- gined for the accuracy of the analysis, than the obtaining them pure, and estimating their quantities with precision. On the contrary, in obtaining the elements merely, no information, it was believed, was gained with regard to the real composition, for it still remained to be determined, in what mode they were combined, and this, it was supposed, could be inferred only from the compounds actually obtained. This method, there- fore, when employed with a view to estimate quantities, has been had recourse to only to obviate particular difficulties at- - tending the execution of the other, or to give greater accuracy to the proportions, or, at farthest, when the composition is very simple, consisting chiefly of one genus of salts. Another circumstance contributed to lead to a preference of the direct mode of analysis ;—the uncertainty attending the de- termination of the proportions of the elements of compound salts. This uncertainty was such, that even from the most ex- act determination of the absolute quantities of the acids and bases existing in a mineral water, it would have been difficult, or ANALYSIS OF MINERAL WATERS. 261 dr nearly impracticable, to assign the precise composition, and the real proportions of the compound salts; and hence the necessity of employing the direct method of obtaining them. The present state of the science leads to other views. If the conclusion were just, that the salts obtained by eva- poration, or any analogous process from a mineral water, are its real ingredients, no doubt could remain of the superiority of the direct method of analysis ; and even of the absolute ne- cessity of employing it. But no illustrations, I believe, are re- quired to prove, that this conclusion is not necessarily true. The concentration by the evaporation, must, in many cases, change the state of combination, and the salts obtained are hence frequently products of the operation, not original ingre- dients. Whether they are so or not, and what the real com- pesition is, are to be determined on other grounds than on their being actually obtained; and no more information is gained, therefore, with regard to that composition, by their be- ing procured, than by their elements being discovered ; for when these are known, and their quantities are determined, we can, according to the principle from which the actual modes of combination are inferred, whatever this may be, as- sign with equal facility the quantities of the binary compounds they form. The accuracy with which the proportions of the constituent principles of the greater number of the compound salts are now determined, enables us also to do this with as much precision, as by obtaining the compounds themselves. And if any error should exist in the estimation of these proportions, the prose- cution of these researches could not fail soon to discover it. The mode of determining the composition of a mineral wa- ter, by discovering the acids and bases which it contains, ad- mits, in general, of greater facility of execution, and more ac- curacy, 262 A GENERAL FORMULA FOR THE curacy, than the mode of determining it by obtaining insulated the compound salts. Nothing is more difficult than to effect the entire separation of salts by crystallization, aided even by the usual methods of the action of alcohol, either as a solvent or a precipitant, or by the action of water as a solvent at dif- ferent temperatures ; in many cases it cannot be completely attained, and the analysis must be deficient in accuracy. No such difficulty is attached to the other method. The princi- ples being discovered, and their quantities estimated in gene- ral from their precipitation in insoluble compounds, their en- tire separation is easily effected. Nothing is easier, for ex- ample, than to estimate the total quantity of sulphuric acid by precipitation by barytes, or of lime by precipitation by oxalic acid. And this method has one peculiar advantage with re- gard to accuracy, that if any error is committed in the estima- tion of any of the principles, it is discovered in the subsequent step of inferring the binary combinations, since, if all the ele- ments do not bear that due proportion to each other which is necessary to produce the state of neutralization, the excess or deficiency becomes apparent, and of course the error is detec- ted. The indirect method, then, has every advantage over the other, both in accuracy and facility of execution. Another advantage is derived from these views, if they are just, that of precluding the discussion of questions which other- wise fall to be considered, and which must often be of difficult determination, if they are even capable of being determined. From the state of combination being liable to be influenced by evaporation, or any other analytic operation by which the salts existing in a mineral water are attempted to be procured, dis- cordant results will often be obtained, according to the me- thods employed ; the proportions at least will be different, and sometimes even products will be found by one method which are ANALYSIS OF MINERAL WATERS. 263 are not by another. In a water which is of complicated com- position, this will more peculiarly be the case. The Chelten- ham waters, for example, have, in different analyses, afforded results considerably different ; and, on the supposition of the salts procured being the real ingredients, this diversity must be ascribed to inaccuracy, and ample room for discussion, with regard to this is introduced. In like manner, it has often been a subject of controversy, whether sea-water contains sul- phate of soda with sulphate of magnesia. All such discus- sions, however, are superfluous. The salts procured are not necessarily the real ingredients, but in part, at least, are pro- ducts of the operation, liable, therefore, to be obtained or not, or to be obtained in different proportions, according to the me- thod employed. And all that can be done with precision, is to estimate the elements, and then to exhibit their binary combinations according to whatever may be the most probable view of the real composition. The process I have to state, conformable to these views, is essentially the same as that which I employed in the analysis of sea-water in a preceding memoir ; and it was the consideration of the advantages belonging to it, that has led me to propose it, with the necessary modifications, as one of general applica- tion. Mineral waters have been arranged under the four classes of Carbonated, Sulphureous, Chalybeate, and Saline. But all of them are either saline, or may be reduced under this division, From waters of the first class, the carbonic acid which is in ex- cess, is expelled by heat, and its quantity is estimated. Sul- phuretted hydrogen is in like manner expelled or decomposed. And iron may be detected by its particular tests, and removed by appropriate methods. In all these cases the water remains, with any saline impregnation which it has, and of course is es- sentially / 264 A GENERAL FORMULA FOR THE sentially the same in the subsequent steps of its analysis as a water purely saline; the precaution only being observed of these principles being removed, and of no new ingredient be- ing introduced by the methods employed. The salts usually contained in mineral waters are Carbo- nates, Sulphates, and Muriates, of Lime, of Magnesia and of Soda. In proceeding to the analysis, a general knowledge is of course first to be gained of the probable composition by the application of the usual tests ; the presence of sulphuric and carbonic acids being detected by nitrate of barytes, of muriatic acid by nitrate of silver, of lime by oxalic acid, of magnesia by lime-water or ammonia, and of any alkaline neutral salt by evaporation. It will also be of advantage to obtain the pro- ducts of evaporation, and ascertain their quantities, without any minute attention to precision, the object being merely, by these previous steps, to facilitate.the more accurate analy- sis. Supposing this to be done, and supposing the composition of the water to be of the most complicated kind, that is, that by the indications from tests, or by evaporation, it has afford- ed carbonates, sulphates, and muriates of lime, magnesia and soda, the following is the general process to be followed to as- certain the ingredients, at their proportions. Reduce the water by evaporation, as far as can be Mae without occasioning any sensible precipitation or crystalliza- tion ; this, by the concentration, rendering the operation of the re-agents to be employed more certain and complete. Tt also removes any free carbonic acid. Add to the water thus concentrated a saturated solution: of muriate of barytes, as long as any precipitation is produced, taking care to avoid adding an excess. By a previous experiment, let it be ascertained whether this precipitate effervesces:or not with a al all >. eye ener a Miese iA ANALYSIS OF MINERAL WATERS. 265 with diluted muriatic acid, and whether it is entirely dissolved. If it is, the precipitate is of course carbonate of barytes, the weight of which, when it is dried, gives the quantity of carbo- nic acid ; 100 grains containing 22 of acid. If it do not ef fervesce, it is sulphate of barytes, the weight of which, in like manner, gives the quantity of sulphuric acid ; 100 grains, dried at a low red-heat, containing 34 of acid. If it effervesce, and is partially dissolved, it consists both of carbonate and sul- phate. To ascertain the proportions of these, let the precipi- tate be dried at a heat a little inferior to redness, and weigh- ed; then submit it to the action of dilute muriatic acid ; after this wash it with water, and dry it by a similar heat, its weight will give the quantity of sulphate, and the loss of weight, that of carbonate of barytes. By this operation the carbonic and sulphuric acids are en- tirely removed, and the whole salts in the water are converted into muriates. It remains, therefore, first to discover and esti- mate the quantities of the bases present, and then, to complete the analysis, to find the quantity of muriatic acid originally contained. Add to the clear liquor a saturated solution of oxalate of ammonia as long as any turbid appearance is produced. The lime will be thrown down in the state of oxalate. The preci- pitate being washed, may be dried, but as it cannot be expo- sed to a red-heat without decomposition, it can scarcely be brought to any uniform state of dryness with sufficient accura- cy to admit of the quantity of lime being estimated from its weight. It is therefore to be calcined with a low red-heat, by which it is ‘converted into carbonate of lime, 100 grains of which are equivalent to 56 of lime. But as a portion of car- bonic acid may be expelled, if the heat is raised too high, or a little water retained if it is not high enough; it is proper to Vou. VIIL P. I. pot el convert 266 A GENERAL FORMULA FOR THE convert it into sulphate, by adding sulphuric acid to a slight excess, and then exposing to a full red-heat. ‘ihe dry sul- phate of lime will remain, 100 grains of which contain 41.5 of lime *. red et The next step is to precipitate the magnesia. With regard to this there is some difficulty, particularly as connected with the design of the present formula. The principle on which it is founded is, first, to remove all the acids but the muriatic, and, secondly, to remove the bases, or otherwise estimate their quantities. The lime and the magnesia may be removed by precipitation ; the soda cannot. ‘The process, therefore, must be so conducted, as to leave it at the end in the state of mu- riate of soda. Hence it is necessary either to remove any new product introduced in the previous steps of the analysis, or if any such remain, to be able to estimate its quantity with pre- cision. In decomposing the muriate of lime by oxalate of am- monia, muriate of ammonia is substituted, which can be after- wards dissipated by heat. The object, therefore, is to decom- pose the muriate of magnesia, and remove the magnesia, either by some similar method, or, if not, by some other in which the muriate substituted can be accurately estimated ; and to attain one or other of these conditions, gives rise to the difficulty to which I have alluded. The * The only source of error to which this step of the analysis is liable, is that which will arise if more barytes has been used in the first operation, than was necessary to precipitate the sulphuric and carbonic acids. It will be thrown down in the state of oxalate of barytes, and be converted into carbo- nate and sulphate, and thus give the apparent proportion of lime too large. This is obviated, of course, by taking care to avoid using an excess of bary- tes. To render the operation of the oxalate of ammonia as perfect as possible in precipitating the lime, the water should be considerably reduced by evapora- tion, taking care to avoid any separation of any of its ingredients. ae | 5 . . : Z . . 4 ANALYSIS OF MINERAL WATERS. 267 The decomposition of the magnesian salt by ammonia would have the former advantage, as the muriate of ammonia would be expelled at the end of the process by heat; but this de- composition, it is well known, is only partial. Sub-carbonate of ammonia causes a more abundant precipitation of magnesia, but still its action is likewise partial, a ternary soluble salt be- ing formed after a certain quantity has been added. It seem- ed probable, that this might be obviated, by adding the sub- carbonate of ammonia as long as it occasioned any precipita- ‘ tion, then evaporating the clear liquor to dryness, expelling the muriate of ammonia, and any excess of ammonia, by heat, re-dissolving, and again adding the sub-carbonate of ammonia to decompose the remaining magnesian salt. Proceeding in this way, I found that a copious precipitation took place on the second addition, and even at the fourth a small quantity of precipitate was thrown down. But the decomposition, after all, was not perfect, for the quantity of magnesia obtained was not equal to what was procured by other methods. Sub-carbonate of soda or potash has been usually employed to precipitate magnesia from its saline combinations. The precipitation, however, is only partial, unless an excess of the precipitant be employed (and even then, perhaps, is not alto- gether complete); and as this exces cannot easily be estima- ted, it introduces a source of error in estimating the quantity of muriate of soda at the end of the operation, against which it is not easy to guard. The method proposed by Dr Woxtaston, of precipitating magnesia from its solution, by first adding carbonate of am- monia, and then phosphate of soda, so as to form the insoluble phosphate of ammonia and magnesia, is one much more per- fect ; the whole of the magnesia appears to be precipitated, and as a method, therefore, of determining the quantity of this. L112 base, 268 A GENERAL FORMULA FOR THE base, it is probably unexceptionable. It does not, however, altogether accord with the object of the present formula. The soda of the phosphate of soda serves to neutralize the muriatic acid of the muriate of magnesia ; a quantity of muriate of soda is of course formed, which remains with the muriate of soda of the water, and the amount of which, therefore, it is necessary to determine with accuracy. This may be done from the quantity of phosphate of magnesia obtained giving the equiva- lent portion of muriate of soda, either by means of the equiva- lents of the acids, or of the bases. But still this renders the method somewhat complicated ; and it may be liable to some error, if any excess of phosphate of soda be added, which, in order to precipitate the magnesia entirely, it may be difficult to avoid ; this excess remaining with the muriate of soda, and rendering the estimate of it incorrect. And independent of these circumstances, it would be preferable to give uniformity to the operation, by employing some method by which the product in this, as well as in the previous steps, is removed, at the end of the analysis, leaving only the muriate of soda. It seemed probable that this might be attained, by employ- ing phosphoric acid with the carbonate of ammonia, to form the triple phosphate of ammonia and magnesia, such an excess of ammonia being used, as should both be sufficient for the constitution of this compound, and for the neutralization of the muriatic acid of the muriate of magnesia; muriate of ammo- nia would thus be substituted, the same as in the preceding step of precipitating the lime, which at the end would be ex- pelled by heat, leaving muriate of soda alone. I accordingly found, that when this variation of the process was employed, the clear liquor, after the precipitation, was-not affected by the addition either of phosphate of soda with ammonia, or of sub- carbonate of soda,—a proof that the separation of the magnesia had i i Gilattie 20 te? 2 ANALYSIS OF MINERAL WATERS. 269 hhad been complete. To establish its accuracy with more cer- tainty, the following experiments were also made. Twenty grains of muriate of soda (pure rock-salt), which had been exposed to a red heat, and ten grains of crystallised mu- riate of magnesia, were dissolved in an ounce of water, at the temperature of 100°. The phosphate of soda and carbonate of ammonia were then employed .to precipitate the magnesia in the mode proposed by Dr Worzasron, that is, a solution of the ammoniacal carbonate was first added, and afterwards a so- lution of phosphate of soda, as long as any precipitation was produced, taking care to preserve in the liquor a slight excess of the ammonia. ‘The precipitate being washed and dried, af- forded, after exposure tod a red heat for an hour, 5.4 grains of phosphate of magnesia, equivalent to 2.15 of magnesia. The clear liquor being evaporated, muriate of soda was obtained, which, after exposure to a red heat, weighed 25.77 grains. Phosphate of magnesia being composed of 39.7 of magnesia, with 60.3 of phosphoric acid, 5.4 grains of it are equivalent to 6.4 grains of muriate of soda, and this deducted from the quan- tity obtained 25.7, leaves 19.3 as the quantity originally dissol- ved. , - A solution perfectly the same was prepared, and a solution ‘of carbonate of ammonia was added to it as before. A strong solution of phosphoric acid was then dropped in, as long as any precipitation was produced, observing the precaution of _ having always an excess of ammoniacal carbonate in the li- quor. ‘The precipitate being washed and dried, afforded, after exposure to a red heat, 5.5 grains of phosphate of magnesia equivalent to 2.19 of magnesia. The clear liquor being evapo- rated, and the dry matter being exposed to a heat gradually raised to redness, weighed, when cold, exactly 20 grains. ba ever In 270 A GENERAL FORMULA FOR THE In both experiments, the quantity of muriate of soda is ac- curately obtained, or as nearly so as can be expected. They correspond, too, as nearly as can be looked for, even in a repe- tition of the same experiment, in the quantity of magnesia which they indicate. To ascertain how far this corresponded with the real quantity, I converted 10 grains of the crystallised muriate of magnesia into sulphate by the addition of sulphuric acid, and exposed it to a low red heat; the product weighed G.4 grains, equivalent to 2.13 of magnesia. This may be re- garded as a perfect coincidence, and as establishing the accu- racy of the other results *. It thus appears, that phosphoric acid with an excess of am- monia may be employed to precipitate magnesia from its sa- line combinations ; and in a process such as the present, it has the advantage, that the muriate of ammonia formed, can be af- terwards volatilised by heat, and the quantity of any residual ingredient can of course be easily ascertained. Neutral phos- phate of ammonia would also have this advantage ; but it does not succeed, phosphate of magnesia not being sufficiently inso- luble. On adding a solution of phosphate of ammonia to a so- lution of sulphate of magnesia, the mixture became turbid in a minute or two, and in a short time a precipitate in crystal- line grains formed at the bottom and sides; but it was not considerable, and did not increase. Phosphate of ammonia, however, with an excess of ammonia, or with the previous ad- dition of carbonate of ammonia, may be employed with the same * According to the result of this last experiment, 100 grains of crystallised muriate of magnesia would give 64 of real sulphate of magnesia, composed of 21.3 of magnesia, and 42.7 of sulphuric acid. This quantity of sulphuric acid is equivalent to 29.4 of muriatic acid. Hence 100 grains of this salt crystallised (in which state its composition, I believe, has not been determined) consist. of 21.3 magnesia, 29.4 muriatic acid, and 49.3 of water.. ANALYSIS OF MINERAL WATERS. 271 same effect as phosphoric acid. In applying the phosphoric acid to this purpose under any of these forms, it is necessary to be careful that it be entirely free from any impregnation of lime. n There is one other advantage which this method has, that if even a slight excess of phosphoric acid be added, the error it can introduce must be extremely trivial ; for the effect of it will be only to decompose a small portion of the original mu- riate of soda; and as the difference is very inconsiderable in the proportion in which phosphoric and muriatic acids com- bine with soda, any difference of weight which may arise from this substitution, to any extent to which it can be supposed to happen, may be neglected as of no importance *.. To * For the sake of comparison, and to ascertain the accuracy of different me- thods, I submitted a similar solution of muriate of magnesia and muriate of soda to analysis by sub-carbonate of ammonia. ‘To the saline liquor, heated to 100°, a solution prepared by dissolving carbonate of ammonia in water of pure ammo- “nia, was added, until it was in excess. A precipitation rather copious took place; the precipitate being collected on a filtre, the clear liquor was evaporated to dryness, and the saline matter was exposed to heat, while any vapours ex- haled. Being redissolved, a small portion remained undissolved, and on again adding sub-carbonate of ammonia to the clear liquor, precipitation took place, rather less abundant than at first. ‘This was repeated for a third, and even for a fourth time, after which the liquor was not rendered turbid. Being evapora- ted, the muriate of soda obtained, after exposure to a red heat, weighed 20.5 grains.. The whole precipitate washed, being heated with sulphuric acid, af- forded of dry sulphate of magnesia 4.8 grains, a quantity inferior to that ob- tained by the other methods, evidently owing to the less perfect action of the ammoniacal carbonate as a precipitant. A similar deficiency in the proportion of magnesia was found in the analysis of sea-water by sub-carbonate of ammo- nia, as has been already stated; while, on the other hand, in its analysis by phosphate of soda and carbonate of ammonia, a larger quantity of muriate of so- da was obtained than by the other methods, probably from the difficulty of avoiding an excess of phosphate of soda in precipitating the magnesia. 272 A GENERAL FORMULA FOR THE To apply this method, then, to the present formula; add to the clear liquor poured off after the precipitation of the oxa- late of lime, heated to 100°, and, if necessary, reduced by eva- poration, a solution of carbonate of ammonia; and immediate- ly drop in a strong solution of phosphoric acid, or phosphate of ammonia, continuing this addition with fresh portions, if necessary, of carbonate of ammonia, so as to preserve an ex- cess of ammonia in the liquor as long as any precipitation is produced. Let the precipitate be washed ; when dried by a heat not exceeding 100°, it is the phosphate of ammonia and mag- nesia containing .019 of this earth ; but it is better for the sake of accuracy, to convert it into phosphate of magnesia by calci- nation for an hour at a red heat: 100 grains, then, contain 40 of magnesia. Evaporate the liquor remaining after. the preceding opera- tions to dryness, and expose the dry -mass to heat as long as any vapours exhale, raising it towards the end to redness. The residual matter is muriate of soda, 100 grains of which are equivalent to 53.3 of soda, and 46.7 of muriatic acid. It is not, however, to be considered necessarily as the quantity of muriate of soda contained in the water; for a portion of soda may have been present above that combined with muriatic acid, united, for example, with portions of sulphuric or carbo- nic acid ; and, from the nature of the analysis, this, in the pro- gress of it, or rather in the first step, that of the removal of these acids by the muriate of barytes, would be combined with muriatic acid. It does not, therefore, give the original quan- tity of that acid; but it gives the quantity of Sopa, since no portion of this base has been abstracted, and none introdu- ced. The quantity of muriatic acid may have been either greater or Jess than that in the muriate of soda obtained. If the quan- tity ANALYSIS OF MINERAL WATERS. 273 tity of soda existing in the water exceeded what the propor- tion of muriatic acid could neutralise, this excess of soda being combined with sulphuric or carbonic acid, then, in the remo- val of these acids by muriate of barytes, muriatic acid would be substituted, which would remain in the state of muriate of soda ; and if the quantity considered as an original ingredient were estimated from the quantity of this salt obtained, it would be stated too high. Or if, on the other hand, more muriatic acid existed in the water than what the soda present could neutralise, the excess being combined with the other bases, lime or magnesia, then, as in the process by which these earths are precipitated, this portion of the acid would be combined with ammonia, and afterwards dissipated in the state of muri- ate of ammonia, if the original quantity, were inferred from the weight of the muriate of soda obtained, it would be stated too low. . To find the real quantity, therefore, another step is necessa- ry. The quantities of bases, and of acids procured, (taking the quantity of muriatic acid existing in the muriate of soda obtained), being combined according to the known proportions of their binary combinations, if any portion of muriatic acid has been abstracted, the bases will be in excess, and the quan- tity of this acid necessary to produce neutralization, will be the quantity lost ; or, on the other hand, if any portion of mu- riatic acid has been introduced, and remains beyond that ori- ginally contained in the water, this quantity will be in excess above what is necessary to produce neutralization. The simple tule, therefore, is to combine the elements obtained by the analysis, in binary combinations, according to the known pro- portions in which they unite ; the excess or deficiency of mu- riatic acid will then appear; and the amount of the excess being subtracted from the quantity of muriatic acid contained Vou. VIII. P. 1. Mm in 974 A GENERAL FORMULA FOR THE in the muriate of soda obtained, or the amount of’ the deficit being added to that quantity, the real quantity of Murzartic Aci will be obtained *. There is one deficiency, however, in this method. If any error has been introduced in any previous step of the analysis, either in the estimation of the bases or of the acids, this error will be concealed by the kind of compensation that is made for it, by thus adapting the proportion of muriatic acid, to the results such as they are obtained ; and at the same time, an incorrect estimate will be made of the quantity of muriatic acid itself. When any error, therefore, can be supposed to ex- ist, or, independent of this, to ensure perfect accuracy, it may be proper to estimate directly the quantity of muriatic acid in a given portion of the water, by abstracting any sulphuric or carbonic acid by nitrate of barytes, and then precipitating the muriatic acid by nitrate of silver or nitrate of lead. The real quantity will thus be determined with perfect precision, and the result will form a check on the other steps of the analysis, as it will lead to the detection of any error in the estimate of the other ingredients ; for when the quantity is thus found, the quantities of these must bear that proportion to it which will correspond with the state of neutralization. Thus, by these methods, the different acids, and the differ- ent bases are discovered, and their quantities determined. To complete the analysis, it remains to infer the state of combina- tion in which they exist. It will probably be admitted, that this must be done on a different principle from that on which the composition of mineral waters has hitherto been inferred. The compounds which may be obtained by direct analysis, cannot * The analysis of sea-water in a preceding paper, will afford an illustration of this (page 237.) ee ee aa. a | . 2 ee, Roe ANALYSIS OF MINERAL WATERS. 275 cannot be considered as being necessarily the real ingredients, and to state them as such would often convey a wrong idea of the real composition. There are two views according to which the state of combination in a saline solution may be inferred, and in conformity to which, therefore, the composition of a mineral water may be assigned. It may be supposed, that the acids and bases are in simultaneous combinations. Or if they be in binary combinations, the most probable conclusion with regard to this, as I have already endeavoured to shew, (p. 230.) is, that the combinations are those which form the most soluble - compounds, their separation in less soluble compounds, on evaporation, arising from the influence of the force of cohe- sion. In either of these cases, the propriety of first stating as the results of analysis the quantities of acids and bases obtain- ed, is obvious. On the one supposition, that of their existing in simultaneous combination, it is all that is to be done. On the other supposition, the statement affords the grounds on which the proportions of the binary compounds are inferred. And there can be no impropriety in adding the composition conformable to the products of evaporation. The results of the analysis of a mineral water may always be stated, then, in these three modes : Ist, The quantities of the acids and bases: 2dly, The quantities of the binary compounds, as inferred from the principle, that the most soluble compounds are the ingre- dients ; which will have at the same time the advantage of ex- hibiting the most active composition which can be assigned, and hence of best accounting for any medicinal powers the wa- ter may possess : And, 3dly, The quantities of the binary com- pounds, such as they are obtained by evaporation, or any other direct analytic operation. The results will thus be presented under every point of view. Mm 2 It 276 A GENERAL FORMULA FOR THE It is obvious that the process I have described, adapted to ‘the most complicated composition which usually occurs, is to be modified according to the ingredients. If no lime, for ex- ample, is present, then the oxalate of ammonia is not employ- ed; and in like manner with regard to the others. I have al- so supposed the usual and obvious precautions to be observed, such as not adding an excess of any of the precipitants, bring- ing the products to a uniform state of dryness, &c. having mentioned only any source of error less obvious, or peculiar to the process itself. With regard to other ingredients, either not saline, or more rarely present, it will in general be preferable, when their pre- sence has been indicated by the employment of tests, or by re- sults occurring in the analysis itself, not to combine the inves- tigation to discover them with the general process above de- scribed, but to operate on separate portions of the water, and to make the necessary allowance for their quantities in es- timating the other ingredients. ‘The quantity of iron, for ex- ample, in a given portion of the water, may be found by the most appropriate method. Silica will be discovered by the gelatinous consistence it gives on evaporation, and forming a residue insoluble in acids, but dissolved by a solution of pot- ash. Alumina may be discovered in the preliminary application of tests, by the water giving a precipitate with carbonate of am- monia, which is not soluble, or is only partially soluble in weak distilled vinegar, but is dissolved by boiling in a solution of» potash, or by its precipitation from the water sufficiently eva- porated by succinate of soda; or in conducting the process it- self, it will remain in solution after the precipitation of the lime by the oxalic acid, and be detected by the turbid appear- ance produced on the addition of the carbonate of ammonia previous to the addition of the phosphoric acid to discover the magnesia. ! P » ANALYSIS OF MINERAL WATERS. 277 magnesia. Its quantity may then be estimated from its preci- pitation by carbonate of ammonia, or by other methods usual- _ly employed. Silica will also be precipitated in the same stage of the process ; its separation from the alumina may be effected by submitting the precipitates, thoroughly dried, to the action of diluted sulphuric acid. Potash when present, which is very seldom to be looked for, will remain at the end, in the state of muriate of potash. Muriate of platina will de- tect its presence, and the muriate of potash may be separated by crystallization from the muriate of soda. . Ture is another mode in which part of the analysis may be conducted, which, although perhaps a little less accurate than that which forms the preceding formula, is simple and easy of execution, and which may hence occasionally be admit- ted as a variation of the process ; the outline of which, there-- fore, I may briefly state. | - The water being partially evaporated, and the sulphuric and carbonic acids, if they are present, being removed by the addi- tion of muriate of barytes, and the conversion of the whole salts into muriates effected in the manner already described ; the liquor may be evaporated to dryness, avoiding an excess of heat, by which the muriate of magnesia, if present, might be decomposed ; then add to the dry mass six times its weight of rectified alcohol (of the specific gravity at least of .835); and agitate them occasionally during twenty-four hours, without applying heat. The muriates of lime and magnesia will thus be'dissolved, while any muriate of soda will remain undissol< ved. 278 A GENERAL FORMULA FOR THE ved. ‘To remove the former more completely, when the solu- tion is poured off, add to the residue about twice its weight of the same alcohol, and allow them to stand for some hours, agi- tating frequently. And when this liquor is poured off, wash the undissolved matter with a small portion of alcohol, which add to the former liquors. Although muriate of soda by itself is insoluble, or nearly so, in alcohol of this strength, yet when submitted to its action along with muriate of lime or of magnesia, a little of it is dis- solved. ‘To guard against error from this, therefore, evaporate or distil the alcoholic solution to dryness, and submit the dry mass, again, to the action of alcohol in smaller quantity than before ; any muriate of soda which had been dissolved will now remain undissolved, and may be added to the other por- tion ; or at least any quantity of it dissolved must be extreme- ly minute. A slight trace of muriate of lime or of magnesia may adhere to the muriate of soda, but when a sufficient quan- tity of alcohol has been employed, the quantity is scarcely ap- preciable ; and the trivial errors from these two circumstances counteract each other, and so far serve to give the result more nearly accurate. Evaporate the alcohol of the solution, or draw it off by dis- tillation. To the solid matter add sulphuric acid, so as to ex- pel the whole muriatic acid ; and expose the residue to a heat approaching to redness, to remove any excess of sulphuric acid. By lixiviation with a small portion of water, the sulphate of magnesia will be dissolved, the sulphate of lime remaining un- dissolved, and the quantities of each, after exposure to a low red heat, will give the proportions of lime and magnesia. The quantity of soda will be found from the weight of the muriate of soda heated to redness ; and the quantities of the acids will be determined in the same manner as in the general formula. This ANALYSIS OF MINERAL WATERS. . 279° This method is equally proper to discover other ingredients which are more rarely present in mineral waters. Thus, alu- mina will remain in the state of sulphate of alumina along with the sulphate of magnesia, and may be detected by preci- pitation by bi-carbonate of ammonia. Silica will remain with the muriate of soda after the action of the alcohol, and will be obtained on dissolving that salt in water. And iron will be discovered by the colour it will give to the concentrated li- quors, or the dry residues, in one or other of the steps of the operation. . 6 Tue general process I have described may be applied to the analysis of earthy minerals. When they are of such a compo- sition as to be dissolved entirely, or nearly so, by an acid, that is, where they consist chiefly of lime, magnesia, and alumina, its direct application is sufficiently obvious; where they re- quire the previous action of an alkali from the predomi- nance of siliceous earth, on this being separated, the excess of alkali may be neutralised by muriatic acid ; and the remaining - steps of the analysis may be prosecuted, with any modification which the peculiar composition will require. As the quanti- ties of the ingredients are capable of being estimated with so much precision, it may be employed with more peculiar ad- vantage where a small quantity only of the mineral can be sub- mitted to analysis; and when it is employed, such a quantity only, ten grains, for example, ought to be made the subject of experiment. END OF PART FIRST. ores ; er t eevlaenint oF ayia: stom tae eatibhe x . r . i on a a ra a ides 9 lice’ > erroie odiertiv ls 4) aoe Ti py? RE aS) ore St vr (Tir eer S 2 4 iy ats f-heinhe b eet repre Syst Medotie rm bb fy a Sra “hi : peaeererc ew weritia’eaicrorre ts outers ci oF i ORY i Gneghltadliee Ye woiisa edit rosin bor io =) ect. Orte eae fii again Sine hdl eri lost, Ab rote hi» AVS a oo LP tthe! ove a ee ee sees NS Ge pivots i] hatemiadenos orld eyvin, ey pies fo} roe F Jl iot rd i 4 2 wm bade’ at athena ta a> toon AE ee bNST Pid Sse Srorp gic) rage Hollaté * ‘ ‘ t hepa katie : ; walt XV. On the Effects of Compression and Dilatation in altering the Polarising Structure of Doubly Refracting Crystals. By Davin Brewster, LL. D. F. B.S. Lon. & Enry. (Read November 17. 1816.) Ta a paper which I had the honour of submitting to the So- ciety, at the end of last session, I gave a detailed account of the effects of mechanical compression and dilatation, in com- municating to glass and other uncrystallised bodies, all the properties of doubly refracting crystals. I had at that time at- tempted, without success, to alter the polarising structure of doubly refracting crystals, although I applied the force of _ powerful screws to Topaz, Rock-crystal, and Calcareous spar. All the specimens which I employed were crushed to pieces by the pressure, but exhibited no traces of the coloured. rings: when exposed to polarised light. ‘The cause of the failure of these experiments did not occur to me, till I was. engaged in examining the phenomena pro- duced in the direction of the resultant axes of regular crystals. I then saw, that the pressure formerly applied, had actual- ly developed a new polarising force, but that it had been Vou, VIII. P. II. Nn applied 982 ON THE EFFECTS OF PRESSURE IN ALTERING THE applied at such an angle with the axis, that the compound force arising from the combination of the new force with the ordi- nary polarising force of the crystal, produced tints far beyond the limits of Newron’s scale. In order, therefore, to observe the influence of the polarising force generated by pressure, it became necessary either to use a crystallised plate. which was so thin as to exhibit tints within the limits of Newron’s scale, or to apply the force at right angles to the axis, and to transmit the polarised light, either along the axis, or at such an angle with it as corresponded to a tint below the fifth or sixth order. I therefore took a plate of Caleareous spar, (one of the nega- tive class of crystals), bounded by planes perpendicular to the axis of double refraction, or to the short diagonal of the primitive rhomb; and having exposed it to polarised light, I observed the beautiful system of circular and highly coloured rings which it produced. The force of a screw was now applied to the sides of the plate, and the rings instantly began to lose their circular shape, to swell and contract in different places, and to bend into curves of contrary flexure at the points of pressure. By continuing the pressure, the plate was broken to pieces.; Instead of oriniding ppb the te obtuse solid snipes of the rhomboid of calcareous spar, 1 took a complete hoes and cemented upon two of its parallel surfaces a prism of flint- glass, whose refracting angle was 45°. When a polarised ray was incident almost vertically upon one of the faces of the prism, so as to be refracted parallel to the diagonal of the rhomb, the system of coloured rings was distinctly seen. I now pressed. together, by means of screws, the other four parallel surfaces of the rhomboid, and observed in a very satisfactory manner the change of form induced upon the circular system of rings. Similar POLARISING STRUCTURE OF DOUBLY REFRACTING CRYSTALS. 283 Similar experiments were made with Quartz, a crystal of the positive class, and with various other crystals, both with one and two axes of double refraction ; and in every case the tints were either raised or depressed in the scale of colours. The same effects were obtained at various angles with the axis, either by reducing the thickness of the plates, or by bringing the tints within the limits of Newron’'s nd by the opposite action of plates of sulphate of lime. ~We may therefore consider it as an established fact, that the phenomena produced by the polarising forces of all crystals, whether they have one or more axes, and whether their action is positive or negative, are very considerably affected by sub- jecting the crystals to compressing or dilating forces. The effect which we have now described may arise from two causes, either from an actual modification of the original polarising force of the crystal, or from the developement of a new force, which merely combines its effects with those of the original force. The first of these cases is exemplified, when we subject to pressure a plate: of glass along which heat is in the act of being transmitted. The pressure which is thus ap- plied, alters the state of aggregation into which the glass is thrown by the passing heat, and produces a real modification of its former polarising force. When, on the other hand, we combine a plate of sulphate of lime with a plate of didisaduis spar, the resulting tint arises merely from a @ombination of the tints which these crystals produce: separately ; ; the po- larising foree’ of the calcareous spar remaining mie same as be- fore. In order to determine whether pressure modifies the origi- nal force, or creates a new one in doubly-refracting Feil I cut the crystals into different shapes, and found that the ef- fect produced by pressure varied with the external shape of Nn 2 the 284 ON THE EFFECTS OF PRESSURE IN ALTERING THE the specimen, in the same manner as in plates of glass. Hence it follows, that since the polarising force of crystals is in no re- spect influenced by their external shape, a new and moveable polarising force is generated by pressure, which increases or di- minishes the effect of the permanent force, according to the di- rection in which it is anplied. The effect, therefore, of a cry- stallised plate subjected to pressure, is the same as if we com- bined it, when free from pressure, with a similar plate of the same substance, destitute of any polarising force, and pressed in a similar manner. The force residing in the ultimate par- ticles of the crystal is unchangeable, and the pressure deve- lopes the new force, by merely altering their state of aggrega- tion. With the aid of these views, we may now predict all the changes which can be produced upon positive and negative crystals, by mechanical compression and dilatation. When the two parallel surfaces of a transparent solid are brought nearer each other by pressure, the tint, in the direction of a line perpendicular to these surfaces, which may be called the axis of compression, is negative, and therefore the polarising force produced by compression is negative, like that of calcare- ous spar, &c. When the two surfaces are, on the other hand, separated from each other by dilatation, the tint in the direc- tion of the perpendicular, which may be called the awis of di- latation, is negative, and consequently the polarising force pro- duced by dilatation is positive, like that of ztrcon, &c. Hence, if we take plates of crystals, and apply the forces to parallel surfaces, we shall obtain the results contained in the following Table : - TABLE a POLARISING STRUCTURE OF DOUBLY REFRACTING CRYSTALS. 285 ~Tasze, shewing the Effect of Compression and Dilatation upon Positive and Negative Crystals. Axis of Compression or | Axis of Compression or ‘Dilatation parallel to Dilatation perpendicu- the Axis of the Crys- | lar to the Axis of the tal. © Crystal. Positive crystals, compressed, | Tints rise, Tints descend. dilated, Tints descend,| Tints rise. Negative crystals, compressed, | Tints descend, | Tints rise. ~ —— dilated, Tints rise, Tints descend. Now, since every compression is accompanied with a dilatation in a direction perpendicular to the axis of compression, and vice versa, it is obvious from the Table, that these simultane- _ ous changes in the state of aggregation of the particles, will act in combination, that is, they will conspire in producing either a positive or a negative polarisation. The preceding results, which are deducible, a priori, from the principles already established, I have confirmed by direct experiments upon calcareous ‘spar, quartz, and various other doubly-refracting crystals, cut into different shapes ; and I have obtained analogous results, by the application of pressure to crystals with two axes of extraordinary refraction. If the axis of compression is perpendicular to the axis of double refraction, the crystal is converted into a crystal with two axes, the poles of the two resultant axes or diameters of no polarisation being distinctly visible. The 286 ON THE EFFECTS OF PRESSURE, &c. The tints discovered by M. Bior along the axis of Rock Crystal, and supposed to arise from a rotatory motion of the particles of light, suffer no other change from pressure, than that which they experience by being combined with the tints produced by any other crystal. When the state of aggregation of the particles of doubly-re- fracting crystals, is altered by the agency of heat, their polar- ising forces suffer analogous changes ; but these changes are less perfectly developed than in glass, owing to the great conduct- ing power of regularly crystallised bodies. XVI. ES a XVI. Experiments on Muriatic Acid Gas, with Observations on its Chemical Constitution, and on some other Subjects of Chemical Theory. By Joun Murray, M. D.F.R.S.E. (Read 15th Dec. 1817, and 12th Jan. 1818.) PART J. Sone years ago J proposed, as decisive of the question which has been the subject of controversy on the nature of Oxymu- riatic and Muriatic Acids, the experiment of procuring water from muriate of ammonia, formed by the combination of dry. ammoniacal and muriatic acid gases. Muriatic acid gas be- ing the sole product of the mutual action of oxymuriatic gas - and hydrogen, it foHows, that if oxymuriatic gas contain oxy- gen, muriatic acid gas must contain combined water ; while, if the former be a simple body, the latter must be the neal acid, free from water. When muriatic acid gas is submitted to the action of substances which combine with acids, water is obtain- ed ; but though the most simple and direct conclusion from this is, that the water is deposited from the muriatic acid gas, the result may be accounted for on the opposite doctrine, by the 288 EXPERIMENTS AND OBSERVATIONS the supposition, that it is water formed by the combina- tion of the hydrogen of the acid with the oxygen of the base. Ammonia, however, containing no oxygen, if water is obtained from its combination with muriatic acid gas, we obtain a result which cannot be accounted for on this hypothe- sis, but must be regarded as a proof of the presence of water in the acid gas. And this, again, affords a proof equally conclu- sive of the existence of oxygen in oxymuriatic gas. The results of the experiment which I had brought forward, were involved in much controversial discussion: And a brief recapitulation of the objections that were urged to it, is neces- sary, as an introduction to the experiments I have now to sub- mit; and to the consideration of the present state of the ques- tion. The original experiment was performed by combining thir- ty cubic inches of muriatic acid gas, with the same volume of ammoniacal gas carefully dried. The salt formed was exposed in a small retort with a receiver adapted to it, to a moderate heat gradually raised. Moisture speedily condensed in the neck of the retort, which increased and collected into small globules *. ; Cy anew This result was admitted by those who defended the new doctrine, when the experiment was performed in the manner I have described,—water being obtained, it was allowed “ in no inconsiderable quantity.” But, to obviate the conclusion, it was asserted, that this is water which has been absorbed by the salt from the atmosphere. This was affirmed by, Sir Humpnry Davy, who stated that the salt absorbs water in this manner to a very: considerable extent; that it is only from the salt in this state that water can be procured, and that when it is formed from the # Nicwoxson’s Journal, vol. xxxi. p. 126. ———_ ee eee ON MURIATIC AcID Gas, &e. 289 the combination of the gases in a close vessel, and heated with- out exposure to the air, not. the slightest trace of water ap- pears, even when the experiment is performed on a sa scale. The reverse of this I was able to demonstrate by farther ex- perimental investigations. It was shewn, that the salt absorbs no moisture from the air in the common state of dryness and temperature in which the experiment is performed: when weighed immediately on its formation, in an exhausted vessel, it gains no weight from exposure, but remains the same after a number of hours ; and when exposed to the air in the freest manner, it remains, after many days, perfectly dry. It was far- ther shewn, that when the other circumstances of the experi- ment are the same, it yields no larger portion of water when it has been exposed to the air, than it does without this previous exposure. And, lastly, it was proved, that when the salt has been formed, and is heated without the air having been admit- ted, water is obtained from it. This last result was even at length admitted by those who had advanced the opposite as- sertion, in an experiment performed with a view to determine the fact. The quantity of water was indeed less than what is procured in the other mode; but this was obviously owing to the circumstances of the experiment being unfavourable to its expulsion,—more particularly to the difficulty of applying a re- gulated temperature to a thin crust of salt, so as to separate the water without volatilising the salt itself,—and to the effect arising from the whole internal surface of a large vessel being encrusted with the salt, so that if the’ heat is locally applied, the aqueous vapour expelled from one part is in a great mea- sure condensed and absorbed at another, or if the heat is ap- plied equally, is retained in the elastic form, and, as it is cool- ed, is equally condensed.. Accordingly, when the experiment Vou. VIII. P. II. Oo . was 290 EXPERIMENTS AND OBSERVATIONS was repeated, obviating these sources of error as far as pos- sible, the water obtained was. in larger quantity. And as no fallacy belongs to the conducting the experiment in the more favourable mode in which it was first performed, (the assertion of the absorption of water from the air being altogether un-. founded), the quantity procured in that mode is to be regarded as the real result *. The argument was inaintained; that the water might be deri- ved from hygrometric vapour in the gases submitted to expe- riment. This it was easy to refute. Dr Henry had shewn, that ammonia after exposure to potash, and muriatic acid after exposure to. muriate of lime, retain no trace of vapour what- ever. And these precautions had been very carefully observed. The assertion was brought forward, too, only to account for the minute quantity of water obtained in that mode of conducting the experiment which affords the least favourable result, and were it even admitted to all the extent to which it can be sup- posed to exist, is inadequate to. account for the larger en obtained in the other. That the entire quantity of water contained in the muriatic acid gas, is not to be looked for, is evident from the nature of the ammoniacal salt, particularly its volatility, whence the due degree of heat to effect the separation of the water cannot be applied. If the other muriates yield the greater part of their water, only when raised nearly to a red heat, (which is the case), it is not to be supposed that muriate of ammonia ‘shall do so at a temperature so much lower, as that which it can su- stain without volatilization. What is to be expected, is a cer- tain portion of water, greater as the arrangements employed are better adapted to obviate the peculiar difficulty attending ; ‘the * Nicrotson’s Journal, vol. xxxik p..196, &c. ; vol. -xxxiv. p. 271. 1 ae {> —* 4 ; | | ; : ON MURIATIC ACID Gas, &c. - 29): the experiment. There is a production of water in every form of it; and there exists no just argument whence it can be in- ferred, that the quantity is less than what ought to be ob- tained. On the opposite doctrine, none whatever should ap- pear. To effect the more perfect separation of the water from the muriate of ammonia, I had performed the additional experi- ment of passing the salt formed from the combination of the two gases, in vapour through ignited charcoal, on the principle that by the interposition of the charcoal, the transmission of the vapour would be impeded, and it would be exposed toa more extensive surface, at which a high temperature would operate, while some effect might also be obtained from the af- finities exerted by the carbonaceous matter. To remove any ambiguity from the effect of the charcoal, it was previously ex- posed in an iron tube toa very intense heat, until all produc- tion of elastic fluid had ceased ; and removed, while still warm, into a tube of Wedgwood’s porcelain, containing the muriate of ammonia, which was then placed across a furnace, so as to be raised to a red heat. As soon as the vapour of the salt passed through the ignited charcoal, gas was disengaged, which was conveyed by a curved glass tube adapted to the porcelain one, and received in a jar ovez quicksilver. Moisture was at the same time pretty copiously deposited, condensing both in the glass-tube in globules, and being brought in vapour with the gas which it rendered opaque, and condensing on the sur- face of the quicksilver within the jars. The elastic fluid con- sisted of carburetted hydrogen, and carbenic acid, products evidently of the decomposition by the ignited charcoal of a portion of the liberated water. In this experiment, then, the result was still more satisfactory than in the other. That no ambiguity arose from any effect of the charcoal in affording Oo 2 water, 992 EXPERIMENTS AND OBSERVATIONS water, is evident from this, that the water appeared at the mo- ment the salt began to pass in vapour, and at a temperature far below that at which the charcoal had ceased to afford any gas. In another variation of the experiment, muriate of ammonia was passed in vapour, through an ignited porcelain-tube alone. Water was obtained in larger quantity than when the salt had been exposed to a heat short of its volatilization ; and even the salt which had yielded water by that operation, afforded an ad- ditional quantity in this mode,—a proof of the more perfect se- paration of the water by the effect of a higher temperature *. By all these results, then, 1 consider the existence of water in muriate of ammonia, and of course in muriatic acid gas, as demonstrated. . Dr Une has lately laid before the Society the result of ano- ther mode of conducting the experiment,—that of subliming the muriate of ammonia\over some of the metals, at the tem- perature of ignition. Water is thus stated to be obtained in considerable quantity, with a production of hydrogen gas. No objection appeared to Dr Urr’s experiment, except, per- haps, that the salt operated on, was not that formed by the di- rect combination of its constituent gases, but the common sal ammoniac, in which water might be supposed to exist, either as an essential, or an adventitious ingredient, as it is abundant- ly supplied to it in the processes by which it is formed. I had found, indeed, in some of my former experiments}, that sal ammoniac yields no water when exposed to a heat sufficient to sublime it, but affords it only when exposed to a red heat by transmission of its vapour through an ignited tube,—that, _ therefore, (owing no doubt to its previous sublimation,) it con- - tains * Nicuorson’s Journal, vol. xxxi. p. 129. + Id, vol. xxxiv. p. 274, “ ON MURIATIC ACID Gas, &c. 293 tains apparently even less water than the salt formed by the combination of the two gases. Still, objections entitled to less consideration than this one, had been maintained in the course of this controversy. I therefore thought it right to repeat the experiment, with the necessary precaution to obviate it, and to observe the actual result. Thirty grains of muriate of ammonia, formed from the com- bination of muriatic acid and ammoniacal gases, were put into a glass tube with a slight curvature. Two hundred grains of clean and dry iron filings were placed over it. The tube was put'in a case of iron with sand, and placed across a small fur- nace, so that the middle part, where the iron filings were, was at'a red heat, the extremity, terminating in the mercurial trough. The salt, from the heat reaching the closed extremi- ty of the tube, soon passed in vapour through the ignited iron. Gas issued from the extremity, and moisture appeared in the cold part of the tube. A large quantity of gas was collected, which had the odour quite strong of muriatic acid, and was in part condensed by water; the residue burned with the flame of hydrogen. The tube, for several inches, was studded with glo- bules of water, and was bedimmed with vapour farther. I did not prosecute the experiment, so as to ascertain the weight of water produced, as' I had other experiments in view, which I conceived might afford more conclusive results. But it proves the point. it was designed to establish, that water is obtained’ from the salt formed by the combination of the gases, as well as from the common sal ammoniac. My: attention having been thus recalled to the subject, I have again executed the experiment in its original and simplest: form,—that of obtaining water from the salt by heat alone; and to this I was led more particularly, as it had occurred to me, that a more perfect abstraction of its water might be ef- fected, 294 EXPERIMENTS AND OBSERVATIONS fected, by conducting the experiment in an apparatus some- what on the principle of the instrument invented by Dr Wot- LAsToN, which he named the Cryophorus. In a retort of the capacity of seven cubic inches, fitted with a stop-cock, and ex- hausted, sixty cubic inches of ammoniacal gas were combined with the requisite quantity of muriatic acid gas, each previous- ly carefully dried,—the former by exposure to potash, the lat- ter by-exposure to muriate of lime. . The stop-cock was then detached from the retort ; the excess of ammoniacal gas was removed by a caoutchouc bottle, and replaced by atmospheric air; the salt was pushed down from the neck ; and it was con- nected with another similar retort, the joining of the two be- ing secured by cement. This last retort was also fitted with a stop-cock adapted to a tubulature at its curvature,and heat be- ing applied to it, a little of the included air was allowed to escape. It was then placed in a mixture of muriate of lime and ice, while the other, containing the muriate of ammonia, was pla- ced in warm oil. The heat of this was raised to 420° ef Fahrenheit: moisture condensed at the upper.part of the neck, when the heat had.been raised to 220°, and continued for some time to increase. It then diminished, from the continued application of the heat, :carrying it forward. into the cold retort, and at the end of the.experiment a considerable part of the body of this was encrusted with.a thin film of ice. This result, therefore, coincides entirely with what had been before obtained *. Another * A foreign chemist, who has continued to support the old doctrine of the na- ture of muriatic acid, has observed, (Annals of Philosophy, vol. viii. p. 204.) that the water of the muriatic acid gas cannot be supposed to be obtained by the combination of the acid with ammonia, for no neutral ammoniacal salt, he adds, can be obtained free from water, and the water of the acid gas becomes the wa- ter ON MURIATIC ACID GAs, &c. 295 Another form of experiment occurred to me still more di- rect and simple, that of transmitting muriatic acid in its gase- ous form over ignited metals. If water be obtained in this ex- periment, it is a result which would prove subversive of the new doctrine ; for muriatic acid gas is held to be the real acid, free from water, and the only change which can happen, is that ea. of il ae i a te ter essential to the salt. I did not think it necessary to make any reply to this observation, founded entirely, as it appeared to me, ona mistaken assumption. - But I may take this opportunity of remarking, that there is no necessary truth in the supposition that, the ammoniacal salts must contain water which they can- not yield. When acids combine with bases, the water of the acid does not ne- cessarily remain in the compound. © On the contrary, it is capable of being dri- ven off from the greater numberof them, by an elevated’ temperature ; and there is no principle on which it can be inferred, that: ammonia should in this respect be different from other bases. That it is incapable, as the same chemist remarks, (Annals, vol. vii. p. 434.) of combining with a dry acid, so as to.form a neutral compound, is of no weight ; for the same thing is true of other Bases, which yet, when combined with such an acid by the aid of water, allow this water to escape from the combination. He. himself observes, that well-burnt lime, free. from: water, does not absorb dry: carbonic acid gas, but absorbs it rapidly if aqueous vapour be admitted, though water is not retained in the composition of carbo- nate of lime. And F have found, that dry magnesia does not absorb muriatic acid gas; though with the aid of water it forms a combination from which the water can be expelled: by heat.. That, ammoniacal salts exist without water, is. evident from the combination of carbonic acid gas and ammoniacal gas, being effected with the greatest facility ; ; and the circumstance that this compound is aot neutral, is one not depending on the peculiarity of the ammonia, and its not containing water, like other bases, but on that.of the carbonic acid, which, with all the alkalis, e even where water is present, has.a tendency to form compounds. with excess of base. The reason why the ammoniacal salts do not yield the eombined water of their acids so conipletely as that. of other salts, is, that from their volatility, or their susceptibility of decomposition, they do not bear that de- gree of heat which is necessary to produce it. I cannot, therefore, but consider the observation alluded to, as one altogether unfounded, and which ought not on mere speculation to have been brought forward against a positive result. Q Sapefi 296 EXPERIMENTS AND OBSERVATIONS © of the-metal decomposing the acid, attracting its chlorine and liberating its hydrogen. And the experiment is farther free from the only resource which remained to the advocates of that doctrine, in the case of water being obtained from mu- riate of ammonia, that it might be derived from the decompo- sition of the elements of ammonia, regerding it as an alkali containing oxygen. If water were really obtained from the combination of muriatic acid and ammoniacal gases, it would rather indicate, it was said, the decomposition of nitrogen than the existence of water as a constituent of muriatic acid. No weight, I believe, is due to such an assumption, but if any importance were attached to it, it is precluded if water is ob- _ tained from the action of metals on muriatic acid gas. I have executed the experiment in several forms; and in all with a more or less satisfactory result. One hundred grains of iron filings, clean and dry, were strewed for a length of five or six inches, in a glass-tube which was placed in an iron case, across a small furnace, so as to ad- mit of being raised to a red heat. This tube, of about two feet in length, was connected with a wide tube eight inches Jong, containing dry and warm muriate of lime; and this was farther connected, at its other extremity, with a retort afford- ing muriatic acid gas, from a mixture of super-sulphate of pot- ash and muriate of soda. The open extremity of the long tube, dipped by a slight curvature in quicksilyer. On the iron being raised to ignition, and the transmission of the acid gas being conducted slowly, elastic fluid escaped from the extre- mity of the tube, which was found to be hydrogen, and though no trace of moisture appeared in the anterior part of the tube, it immediately condensed in that part which was cold, beyond the iron filings. This accumulated in globules, and at length run ON MURIATIC aciD Gas, &c. 297 run into a small portion in the bottom ; the sides were bedew- ed for a length of six inches, and a thin film of moisture ap- peared beyond, nearly its whole length. By the muriatic acid gas being extricated in the preceding experiment from nearly dry materials, and by its previous transmission over an-extensive surface of loose muriate of lime, it was inferred, that it would be free from hygrometric vapour ; and that it held no moisture, was apparent from no trace of it appearing in the anterior portion of the tube. To obviate, however, entirely, any ‘supposed fallacy from this source, the experiment was performed in the following manner. One hundred grains of clean and perfectly dry iron filings were put into a long glass tube, which was placed, as before, across a small furnace. Muriatic acid gas had been kept in contact with dry muriate of lime for three days, in a jar with a stop~ cock adapted to it. This was connected, by a short tube with a caoutchouc collar, with the tube containing the iron filings ; and a little of the muriatic acid gas being passed through the tube to expel the air, the temperature was raised to ignition, The slow transmission of the gas was continued by the pres- sure of the mercury in the quicksilver trough, and fresh quan- tities, which had been equally with the other exposed to mu- riate of lime, were added, as was necessary. Water almost im- ‘mediately appeared in the tube beyond the iron filings, it col- lected in spherules, and continued to accumulate as the gas continued to be transmitted for a length of about seven inches. A portion of the gas which escaped from the extremity, was _ clouded, and deposited a film of moisture on the sides of the jar in which it was received over quicksilver. The quanti- ty of gas transmitted amounted to about thirty-five. cubic inches. Vou. VIL P. U.. Pp There 298 EXPERIMENTS AND OBSERVATIONS ‘There are some difficulties in conducting the experiment in the manner now described, from the consolidation of the me- tallic matter, and the volatilization of the product. It was also of some importance to vary the experiment. I therefore performed it in another mode. Metals scarcely act on muria- tic acid gas, at natural temperatures, but from such a degree of heat as could be applied by a small lamp, both iron and zine were acted on; the gas suffered diminution of volume, hydro- gen was formed, and a sensible production of moisture took place. The simplest mode of exhibiting this, is to introduce iron or zinc filings, previously dry, and warm, into a retort fitted with a stop-cock ; exhausting it ; then admitting dry mu- riatic acid gas ; and applying heat, by a small lamp, to the filings in the under part of the body of the retort. Moisture soon appears at its curvature in small globules, and increases on successive applications of the heat with the admission of the requisite quantities of gas. To conduct the experiment, however, on a larger scale, I em- ployed a different apparatus. A tubulated retort, of the capaci- ty of twenty-five cubic inches, was connected with a jar, con- taining muriatic acid gas in contact with muriate of lime, on the shelf of the mercurial trough, by a tube bent twice at right angles, and fitted by: its shorter leg with a collar of caoutchoue to a stop-cock at the top of the jar, its longer leg passing into the tubulature of the retort, so as to terminate within an inch of its bottom, and the joinings being rendered air-tight. The retort is so placed, that heat can be applied by a lamp to the bottom, and its neck dips, by a short curved tube, under a jar filled with quicksilver, which, by the reverted posi- tion of the retort, may be placed beside the other, on the shelf of the trough. At the commencement of the experiment, the metallic filings, previously dry and warm, having been put into the retort, the atmospheric air is expelled by a moderate heat, and ae MELA ON MURIATIC-ACID Gas, &e. 299 and'small portions of the muriatic acid gas are admitted, until the retort is filled with the pure gas. The stop-cock is then clo- sed, and heat is applied by a lamp to the bottom of the retort, under a considerable pressure-of mercury ; any small portion of gas, expelled at the extremity, being received. in the small jar. The heat. can thus be successively cautiously applied, and this, as the experiment proceeds, to a greater extent, in consequence of the diminution of volume that takes place. [Fresh quantities of muriatic acid gas are admitted from time to time from the jar, and the stop-cock being closed when the heat is applied, the hydrogen gas produced is expelled, with-any muriatic acid gas not acted on. , In the principal experiment I alae zine filings were used i in preference to iron, from the. consideration, that muri- ate of zinc is less volatile than muriate of iron, and therefore sl admit of a- higher heat being applied to expel any wa- - One hundred grains of clean and dry,zine filings were in- el an warm, into the retort ; the air was expelled, and muriatic acid gas was admitted from the jar. On applying heat: to the zinc, the retort, which was before perfectly dry, was bedimmed with moisture at its curvature, and small spherules collected at the top of the neck. These increased in size, and extended farther as the experiment advanced. After.a certain time, part of this disappeared in the:interval of cooling, being absorbed by the deliquescent product ; but when the heat was again applied, it was renewed, and this in increased quantity, until at length, at the end of four days, during which heat had been frequently applied, the whole tube of the retort, seven inches in length, was studded with small globules of fluid. When the heat had been raised high, a beautiful arborescent crystallization appeared in a thin film on the body of the’re- tort, but no part of ‘this reached the neck. The retort was now. detached ; the gas it contained was withdrawn by a caout- Pp2 chouc 300 EXPERIMENTS AND OBSERVATIONS choue bottle ; a small receiver was adapted ; and a slight heat having been applied, to expel a little of the air, the joining was made close by cement. The receiver was surrounded with a freezing mixture, and heat was applied by a choffer to the re- tort, as far as: could be done, without raising dense vapours, Globules of liquid, perfectly limpid, collected pretty copious- ly towards the middle and lower part of the neck, and the re- ceiver, on being removed from the freezing mixture, was co- vered sntawinally with a film of moisture. ‘The globules in the neck of the retort were absorbed by a slip of bibulous paper, and the quantity was found to amount to 1.2 gr. The recei- ver being dried carefully, and weighed, lost by the dissipation of the moisture within, 0.4 grain. Distilled water, in which the bibulous paper was immersed, was quite acid; it gave no sensible turbidness on the addition of ammonia, or of carbo- nate of soda, and held dissolved, therefore, merely pure muria- tic acid. The mass in’ the retort was of a grey colour, with metallic lustre, in loosely agg sregated laminae, somewhat flexi- ble. It weighed 114.8 grains. Adding to this increase of weight, which the zinc had gained, the weight of the water and the hydrogen gas expelled, it gives a consumption of muriatic acid gas of about 16.8 grains, equivalent to about 43 cubie inches. Supposing the weight of water to be doubled, or near- ly so, by saturation with muriatic acid, this gives the product of water in the experiment, as equal to nearly one grain; or about one-fifth of the whole quantity of combined water, which muriatic acid gas is calculated to contain *. ™ ® The action of the metals on the muriatic acid gas, taking place in the above experiments at a heat comparatively moderate, it occurred to me, that they might exert a similar action with no higher heat on the acid, in muriate of am- : monia, exqrs ON MURIATIC ACID GAs, &c. 301 ' In all the preceding experiments, water has been procured from muriatic acid gas. It is obvious, that such a result can- not be accounted for on the hypothesis, that-it is the real.acid free from water, a compound merely of chlorine and hydrogen. On the opposite doctrine, as muriatic acid in its gaseous: form. is held to contain water, it may be supposed. to aa a portion of it. siltk may be cata however, in this, as it was in the ex- periment of obtaining water from the muriate of ammonia by heat, that the water produced is derived from hygrometric va- pour in the gas. To obviate this, it is sufficient to recur to the fact established by the experiments of Henry and Gay Lussac, that muriatic acid gas contains no hygrometric vapour ; and to the obvious result in the experiment, that no quantity that can be assumed, would be adequate to account for the quantity. ramen nibtaihied: The circumstances of the experi- _ Ment, monia, and that this might afford an easy mode of exhibiting the results. I ac- cordingly found, that on mixing different metals with sal ammoniac in powdery, - previously exposed to a subliming heat, and exposing the mixture to’ heat by a lamp, so regulated as to be short of volatilization, the salt was decomposed, am- moniacal gas was expelled, and moisture condensed in the neck of the retort ; covering @ space of several inches with small, globules, and at length running down. . The metals I employed were iron, zine, tin, and lead; 100, 150, or 200 grains of each metal, dry and warm, being mixed with 100 grains of the salt,, likewise newly heated. To obviate any fallacy from common sal ammoniac be- ing employed, I repeated the experiment with the salt formed from the combina- tion of its two constituent gases, and obtained the same result. But although this affords an easy mode of exhibiting the production of water, it is not favour- able to obtaining a perfect result, the heated ammoniacal gas carrying. off a :con- siderable post of the water deposited ; and accordingly, the quantity, instead. of increasing as the experiment proceeds, at length diminishes, and the ammoni- acal gas deposites a portion of water in passing through mercury, or in being con- veyed through a cold tube. 302 EXPERIMENTS AND OBSERVATIONS ment, too, are such as to preclude any such supposition ; and this more peculiarly so, than in the experiment of obtaining’ water from the muriate of ammonia by heat; for in the present: case, the acid gas is alone employed, while in the other there isan additional equal volume of ammoniacal .gas, which may be supposed to afford a double quantity of hygrometric vapour.: In the latter, both the gases are condensed into a solid pro-» duct, and any hygrometric vapour may be supposed to be li- berated; but in the present experiment, there remains the hy-" drogen gas, capable of containing hygrometric vapour, while. the muriatic acid gas contains none ; and the quantity of it thus transmitted over the ;humid surface, and expelled frem the apparatus, must have carried off more vapour than the. other, introduced at a lower temperature, could have convey-; ed.._ These circumstances, independent of the quantity of wa-; ter deposited, precluded the supposition of any deposition from, * the condensation of hygrometric vapour. And there is no other external source whence it can be derived. In this re- ‘spect nothing can be more satisfactory than the experiment with the zinc in the apparatus described. The muriatic acid. gas rises from dry mercury in contact with muriate of lime,’ passes through a narrow bent tube, thirty inches in length, without exhibiting the slightest film of moisture, is received. into the retort perfectly dry ; and when the action of the metal. on it is excited by heat, humidity immediately becomes appa-: rent in the curvature of the retort, and this even while the gas is warm, and of course capable of containing more water dissolved, than it could do in its former state ; and the quanti-. ty increases as the experiment proceeds. No arrangement can be supposed better adapted to prove, that any deposition of wa- ter must be by separation from its existence in the gas in a combined state. 3 ‘cas But ' ON MURIATIC ACID GaAs, &c. 303 But though TI consider this conclusion as established, there -is a considerable difficulty attending the theory of the experi- ment. The result of water being obtained is actually different from what is to be looked for, on the doctrine of muriatic acid gas containing combined water ; and even when the fact is established, the theory of it is not easily assigned. On that doctrine, it must be held that in the action of metals:on muriatic acid gas, the metal ‘attracts oxygen from: the water, the corre> sponding hydrogen is evolved, and the oxide formed combines with the- real acid. No water, therefore, ought to be deposi- ted, for none is abstracted from the acid, but what is spent in: the oxidation of the metal: This will be apparent, by attend- ing to the proportions in a single example, from: the scale of chemical equivalents: 100 grains of iron combine:with 29 of oxygen, and in this state of oxidation unite with. 99 of real mu- riatic acid. This quantity of acid exists in 131.8 of muriatic acid gas, combined with 32.8 of water ; and this portion of wa- ter contains 29 of oxygen with 3.8 of hydrogen... There is pre- sent, therefore, exactly the quantity of oxygen.which. the me- tal requires to combine with the acid; and no. water remains above this: Or it may be idleagnated: under another point of view. Muriatic acid gas is composed of oxymuriatic gas and hydrogen. A: metal acting on it must attract the oxymuriatic -acid,—that is, the muriatie acid-and oxygen, and liberate the hydrogen. No water, therefore, aught to appear, more, on this theory, than: on the other; but the real products in both must be a dry muriate, or chloride, and hydrogen gas. In the action of ignited metals on muriate of ammonia, it. is equally evident,'on the same principle, that no water ought to be ob- tained. . How, then, is the production of water to be account- ed for ? ~-Though the water obtained in. these experiments cannot be derived from hygrometric vapour in the gas, there.is another view 304 EXPERIMENTS AND OBSERVATIONS view under which it may be regarded as present, as an adven- titious ingredient. The acid having a strong attraction to water, may be supposed, in the processes in which it is usually prepared, to retain a portion not strictly essential to its con- stitution as muriatic acid gas, but still chemically combined,— that is, combined with it with such an attraction as to be libe- rated only when it passes into other combinations, and it may be this portion which is obtained in the action of metals on the gas ; the other portion, that essential to the acid, being suf- ficient to produce the requisite oxidation of the metal. The question with regard to the existence of water in this state, Gay Lussac and Tuxnanp' have already determined. From an extensive series of experiments, they found reason to ‘conclude, that muriatic acid gas, in whatever mode it is pre- _ pared, is uniformly the same. From the quantity of hydrogen gas which combines with oxymuriatic gas in its formation, it follows, that it contains 0.25 of water, essential to its constitu- tion. But the gas obtained by the usual processes, afforded, they found, exactly 0.25 of water, when transmitted over. oxide of lead, or combined with oxide of silver ; and the same com- pounds are formed, as by the action of oxymuriatic acid on sil- ver and lead in their metallic state. They prepared muriatic acid gas, by heating fused muriate of silver with charcoal mo- derately calcined. It contained just the same quantity of wa- ter as muriatic acid obtained from humid materials, as it af- forded the same quantity of hydrogen from the action of po- tassium. And instead of being capable of receiving the small- est additional portion of water, a single drop of water being in- troduced into three quarts of it, did not disappear, nor even diminish, but, en the contrary, increased in volume *, These ; facts (6h SS eee ta ee, * Recherches Physico-chimiques, t. ii. p. 133. a -ON MURIATIC AcID Gas, &c. 305 facts establish the conclusion, that. muriatic acid gas can re- -ceive no additional-portion of water, but that which is essential to it, and hence preclude the solution of the difficulty under consideration by the opposite assumption. And it is to be re- marked, that should even such a portion of water exist in the | -gas, it cannot be supposed that the acid should carry this with it into its saline combinations, and retain it so, that it should not be expelled by heat. It cannot be supposed: to exist, there- fore, in muriate of ammonia thus heated, and of course cannot account for the water obtained. by. the action of the metals on this salt.. When it is proved, that no extrinsic water exists in muriatic acid gas, there remain apparently only two modes on which the production of water can be explained,—either, that the metal may require less-oxygen’ than is supposed:in combining with the acid, so. that. a portion of water will remain undecomposed, to be deposited:: or, that the oxide attracts more real acid, so as to liberate a larger proportion of water.. The-first of these suppositions is improbable, from the consideration of the law which regulates:the combination of metallic oxides with acids, —that the quantity of acid is proportional to the quantity. of oxygen,. so that if an oxide were formed. in these cases, at-a lower degree of oxidation, it would only combine with a pro- portionally smaller quantity of acid, and the quantity of. water. . detached from the combination: would be the same. No improbability is attached to the second ‘supposition ; and it has even some support from the consideration, that many metallic saline compounds, form with. an: excess:of acid; and that: it is difficult, with regard to a number of them, to procure them neutral. Metallic muriates, with excess:of acid, seem in particular to be established with facility. And although an ex- cess of metal be present in the action exerted on. muriatic Vor. VIE. P. I Qq acid 806 EXPERIMENTS AND OBSERVATIONS acid gas, this may not prevent the formation of a super-muriate, more especially as the excess is in the metallic form, and ex- erts no direct action, therefore, on the real acid. To ascertain if a super-muriate were formed in these cases, the product obtained from the action of the muriatic acid on the metal was raised to a heat as high as could be applied with- out volatilization, so that no loosely adhering acid might re- main, and the air in the retort was repeatedly drawn out by a caoutchouc bottle. The solution from the residue both of iron and zinc was very sensibly acid. Some fallacy. however, at- tends this, from the circumstance, that the liquid state is ne- cessary to admit of the indications of acidity, and in adding wa- ter to produce this, a change occurs in the state of combina- tion, in a number of the metallic muriates ; a super-muriate be- ing formed, which remains in solution, and a sub-muriate being precipitated, so that the acidity of the entire compound cannot justly be inferred from that of the solution. I found, accord- ingly, that on adding water to the product from the action of the acid gas on zinc, this change occurs ; a little of a white pre- cipitate being thrown down, while the liquor remained acid. But the fallacy can be obviated, by adding only as much water as produces fluidity, without subverting the combination. Por- tions, therefore, of the residue were exposed to a humid atmo- sphere, until by deliquescence, liquors were formed transpa- rent, without any precipitation ; and these were strongly acid, reddening litmus paper when it was perfectly dry and warm. I farther found, that the product of the solution of zinc in li- quid muriatic acid, when digested with an excess of metal, and evaporated to dryness, afforded by deliquescence a liquor sen- sibly acid. And in both cases, even when the solid product was retained liquid by heat, acidity was indicated by litmus pa- per. Lastly, What is still less liable to objection, the residue — in y 4 z , 4 b i 4 ON MURIATIC ACID Gas, &c. 307 in the experiment of heating the muriate of ammonia with the different metals, afforded similar indications of acidity. These results appear to establish the production of a super- muriate in the action of these metals on the acid, and this ac- counts for the appearance of a portion of water, since, suppo- sing water to exist in muriatic acid gas, the quantity combined with that proportion of acid which would establish a neutral compound, is the quantity required to oxidate the metal to form that compound ; and if any additional portion of acid en- ter into union, the water of this must be liberated, or be at least capable of being expelled. It was of importance, in relation to this question, to ascer= tain the quantity of hydrogen obtained from a given quantity. of muriatic acid gas; for, if the whole water essential to the acid is decomposed by the action of the metal, half the volume of hydrogen ought to be obtained,—muriatic acid gas being composed of equal volumes of oxymuriatic gas and hydrogen gas. I made this repeatedly the subject of experiment, by heat- ing zinc and iron in muriatic acid gas. There are difficulties. in determining the proportion with perfect precision; but the quantity of hydrogen always appeared to be less than the half; and on an average, about twelve measures were obtained, when thirty measures of the other had been consumed, a result con- formable to the liberation of a portion of the combined water of the gas. Whether the production of water in these experiments is sa- tisfactorily accounted for, on the cause now assigned, may be subject of farther investigation. In the sequel, I shall have to: notice another principle, on which perhaps it may fall to be explained. Whether accounted for or not, it is obvious, that the fact itself is not invalidated by the theoretical difficulty ; and also, that in relation to the argument with regard to the na- Qq2 ture 308 EXPERIMENTS AND OBSERVATIONS, Cc. ture of muriatic and oxymuriatic acids, it remains equally con- clusive. In the doctrine of the undecomposed nature of chlo- rine, muriatic acid gas contains neither water nor oxygen, and the metal employed certainly contains none. These are the only substances brought into action, and it is impossible that water | should be a product of their operation. On the opposite doc- trine, water is held to exist in muriatic acid gas to the amount of one-fourth of its weight ; and it is conceivable, that by some exertion of affinities, a portion of it may be liberated. If we were unable to explain the modus operandi, this would remain a difficulty no doubt, but not, as in the opposite system, an im- possible result. It is to be admitted, indeed, that in none of these cases, is . the entire quantity of water which must be supposed to exist in muriatic acid gas obtained ; and so far the proof is deficient. But neither from the nature of the experiments is this to be. looked for ; and I give more weight to the argument, from ha- ving always found certain portions of water to be procured, while, on the opposite doctrine, there should be none. In those cases where supposing water to be present in muriatic acid gas, it ought to be obtained in the full quantity, it uni- formly is so, though the proof from these is rendered ambigu- ous, by the result being capable of being explained on a differ- ent hypothesis. PART —~— ae . { 309 ] PART II. OBSERVATIONS ON THE CHEMICAL CONSTITUTION OF MURIATIC ACID GAS, AND ON SOME OTHER SUBJECTS OF CHEMICAL THEORY. ApmirtTine water to be procured from muriatic acid gas in those forms of experiment, direct or indirect, in which the agency of no other substance that can afford it, is introduced, the conclusion seems necessarily to follow, which forms the ba- sis of one of the two systems under which the relations of oxy- muriatic and muriatic acids have of late years been explained, —that oxymuriatic acid is.a compound of muriatic acid with oxygen; and that muriatic acid in its gaseous state, contains combined water. This doctrine, accordingly, may be main- tained, and may even perhaps be just. It is not, therefore, from the consideration of any deficiency in its support, that I depart from it in the following observations, but that I consi- der the view I have to propose as perhaps more probable, or at least as, on the whole, according better with the present state of chemical theory. In a science such as Chemistry, the prin- ciples of which rest, rather on probable evidence, than on de- monstration, it is of importance to. present a -subject in every point of view under which it may be surveyed ; and this must serve as an apology for the speculations I have now to offer. There 310 OBSERVATIONS ON MURIATIC ACID, There are, I believe, only two arguments to which any weight is due in support of the opinion that chlorine is a simple substance, which by combination with hydrogen forms muriatic acid. One is drawn from the analogy resting on the general fact, sufficiently established, that acidity is in different cases the result of the agency of hydrogen ; the other, from the analogy in the chemical relations of chlorine and iodine. Sulphur forms with hydrogen a compound unequivocally acid. The compound radical of prussic acid Cyanogen, disco- vered by the able researches of Gay Lussac, likewise acquires acidity when it-receives hydrogen. . Acidity, therefore, is a property not exclusively connected with oxygen; it is also communicated by hydrogen; and when chlorine with hydro- gen gas, forms muriatic acid gas, the agency exerted may be considered as similar to that arising in other cases, of the pro- duction of an acid from the action of hydrogen. This is confirmed by the relations of iodine. It, too, forms an acid by combination with hydrogen; and the chemical agencies of iodine are in several other respects similar to those of chlorine. When the one, therefore, is considered as a simple body, (and there is no absolute proof that iodine is a compound,) the other is, with probability, placed in the same class. And certain analogies existing between sulphur and io- dine, serve to connect and confirm these views. Each of them forms an acid with hydrogen; each of them also forms an acid with oxygen. But chlorine exhibits precisely the same points of resemblance: with hydrogen, it forms muriatic acid; with oxygen, it forms chloric acid. Its chemical relations, with regard to acidity, being thus similar, seem to require the same explanation to account for them. These facts lead undoubtedly to views of chemical theory, different from those which had before been established; and on which ——— AND ON SOME SUBJECTS OF CHEMICAL THEORY. 311 which the old doctrine with regard to the nature of muriatic and oxymuriatic acids rests. It may be well, therefore, to in- quire how far they may modify the conclusions to be drawn, admitting even that oxymuriatic acid contains oxygen, and that _ Mnuriatic sabia gas affords water. When water is obtained from muriatic avid gas, it does not necessarily follow, that it has pre-existed in the state of water. It is equally possible, a priori, that its elements may be pre- sent in simultaneous combination with the acid, or its radical, —that the acid is a ternary compound of a radical with oxy- gen and hydrogen ; and that it is decomposed in those proces- ses by which water is procured, the hydrogen, with the requisite proportion of oxygen, combining to form water ; and its radical, with any excess of oxygen, remaining in union with the sub- ‘stance by which the change has been effected. If this view were adopted with regard to muriatic acid, the same view might, on the same grounds, be applied to the other acids which appear to contain water in intimate combi- nation, and: in a definite proportion. And such an acid, the radical and precise constitution of which are known, may be best adapted to illustrate the hypothesis. Sulphuric acid affords water when it is submitted to the ac- tion of an alkaline base ; and the quantity of this water appears to be definite, amounting to 18.5 in 100 of the strongest acid which can be procured in an insulated state ; 100 parts of this acid, therefore, are considered as composed of 81.5 of real acid, (consisting of 32.6 of sulphur, and 48.9 of oxygen,) with 18.5 of water. But if, instead of this view of its constitution, it be considered as a ternary compound of sulphur, oxygen, and hy- drogen, its composition will be 32.6 of sulphur, 65.2 of oxy- gen, and 2.2 of hydrogen. In those processes by which water is obtained from it ;—in the action, for example, of an alkaline base, 312 OBSERVATIONS ON MURIATIC ACID, base, and subsequent exposure to heat, the composition is sub- verted by the affinities exerted; the hydrogen unites with the requisite proportion of oxygen, forming water, and the remain- ing oxygen with the sulphur unite with the base. In the ac- tion of a metal on the acid, there is the same result ; only by the attraction of the metal to oxygen, the whole of that ele- ment is retained, and the hydrogen is disengaged. Mauriatic acid gas, then, according to this doctrine, is the real acid, a ternary compound of a radical (at present un- known) with oxygen and hydrogen, exactly as sulphuric acid in its highest state of concentration, is the real acid, a ternary compound of sulphur, oxygen, and hydrogen. When it is sub- mitted to an alkaline base, the action exerted causes its decom- position ; its hydrogen, and part of its oxygen, combine to form water, and its radical, with its remaining oxygen, unite with the base, forming a neutral compound, analogous to what other acids of similar constitution form. When a similar re- sult is obtained from the action of a metal, its whole oxy- gen must be considered. as retained, and its hydrogen is libe- rated. Nitric acid in its highest state of concentration, is not a de- finite compound of real acid with about a fourth of its weight of water; but a ternary compound of nitrogen, oxygen, and hydrogen. Phosphoric acid is a triple compound of phospho- rus, oxygen, and hydrogen ; and phosphorous acid is the proper binary compound of phosphorus and oxygen. The oxalic, tar- taric, and other vegetable acids, are admitted to be ternary compounds of carbon, oxygen, and hydrogen, and are there- fore in strict conformity to the doctrine now illustrated. A relation of the elements of bodies to acidity is thus dis- covered, different from what has hitherto been proposed. When a series of compounds exists, which have certain com- mon AND ON SOME SUBJECTS OF CHEMICAL THEORY. $13 mon characteristic properties, and when these compounds all contain a common element, we conclude with justice, that these properties: are derived more peculiarly from the action of this element. On this ground Lavorsrer inferred, by an ample induction, that oxygen is a principle of acidity. Berrnotuer brought into view the conclusion, that it is not exclusively so, from the examples of prussic acid and sulphuretted hydrogen. In the latter, acidity appeared to be produced by the action of hydrogen. The discovery by Gay Lussac, of the compound radical cyanogen, and its.conversion into prussic acid by the addi- tion of hydrogen, confirmed this conclusion ; and the discovery of the relations of iodine still farther established it. And now, if the preceding views are just, the system must be still farther modified.. While each of these conclusions is just to a certain extent, each of them requires to be limited in some of the eases to which they are applied; and. while acidity is. some- times exclusively connected with oxygen, sometimes with hy- drogen,, the principle must also be admitted, that it is more frequently the result of their combined operation.. There appears even: sufficient reason to infer, that from the united action of these elements, a higher degree of acidity is. acquired than from the action of either alone. Sulphur affords. a striking example: of this.. With hydrogen it forms a weak: acid. With oxygen it also forms an acid, which, though of su- _ perior energy, still does not display much power. With hy- drogen and oxygen it seems to receive the acidifying influence: of both, and its acidity is proportionally exalted. Nitrogen with hydrogen forms a compound altogether desti- tute of acidity, and possessed even of qualities’ the reverse. With oxygen in two definite proportions, it forms oxides; and it is doubtful, if in any proportion, it can establish with oxygen an insulated acid.. But with oxygen and hydrogen in Vou. VIII. P: IL Rr ~~ union 314 OBSERVATIONS ON MURIATIC ACID, union it forms nitric acid, a compound more permanent, and of energetic action. Carbon with hydrogen forms compounds which retain in- flammability without any acid quality; with oxygen it forms first an inflammable oxide, and with a larger proportion a weak acid. But, combined with both hydrogen and oxygen, in dif- ferent proportions, it forms in the vegetable acids compounds having a high acidity. These acids, therefore, are not to be re- garded, according to the theory of Lavoisizr, as composed of a compound base of carbon and hydrogen, acidified by oxygen, but of a simple base, carbon, acidified by the joint action of oxygen and hydrogen. Mnuriatic acid itself presents the same result. Oxymuriatic: acid must be considered, according to this doctrine, as a com- pound of an unknown radical, (Murion, if the term may be al- lowed), with oxygen, analogous in this respect to sulphurous acid, except that in the latter there is an excess of base, in the former an excess of oxygen: And oxymuriatic acid, with the addition of hydrogen, forms the ternary compound muriatic acid, as sulphurous acid with the same addition forms hydro- sulphuric acid, with a deposition of the excess of sulphur. There is, accordingly, the strictest analogy between muriatic acid and those other acids, the sulphuric, nitric, &c. which contain both oxygen and hydrogen; while there is none, as Berzetius re- marked, between it and those, such as the prussic acid or sul- phuretted hydrogen, which contain merely hydrogen. This prin- ciple solves the difficulty which has always presented itself in the relation of muriatic and oxymuriatic acids on LavoisrEr’s theory of acidity,—that the latter, though it has received an addition of oxygen, is inferior in acid power to the former. It is so precisely as the binary sulphurous acid is one of less energy of action than the ternary hydro-sulphuric acid, or as the carbonic is less powerful than the oxalic acid. The pro- per AND ON SOME SUBJECTS OF CHEMICAL THEORY. 315 per analogy is that of the oxymuriatic with the sulphurous acid, and the muriatic with the sulphuric ; and under this point of view there is no anomaly, but strict conformity. And thus also is accounted for, what is at variance with the hypothesis of Gay Lussac, the total want of analogy between chlorine and sulphur, which he classes together, except in the single cir- cumstance of acidity being communicated to both by hydro- gen; while there exists a close analogy between sulphurous acid and oxymuriatic acid, in their most essential properties,— their gaseous form, their specific gravity, their suffocating odour, their power of destroying vegetable colours, their solu- bility in water; their remaining combined with it in congela- tion ; their acidity, their combining weights, and their being attracted to the positive pole of the voltaic series ; and any de- viation from this analogy evidently arises from the excess of oxyen in oxymuriatic acid *. It is obvious, that it would be in vain to seek for the disco- very of real muriatic acid in its insulated form. It exists no more than real sulphuric or real nitric acid. The oxygen and sulphur, or oxygen and nitrogen in union with a salifiable base in the sulphates and nitrates, may not be in direct combina- Rr2 tion, * It is curious with regard to the most important of these analogies, that of the equivalent or combining weights, that oxymuriatic acid stands next to sul- phurous acid; the former in Dr Wottasron’s scale being 44, while the latter will be found to he 40. The acidity of oxymuriatic acid is fully established by the most unequivocal acid property, that of combining with alkalis, and forming neutral compounds. The saline nature of these compounds had been shewn by Bertuoittet; that with lime has been demonstrated by Mr Daxton, who also pointed out the probability from the results, by double decomposition, that the acid combines in a similar manner with other salifiable bases; and the existence of these compounds has been established by Mr Witson. 316 OBSERVATIONS ON MURIATIC ACID, tion, nor capable of existing as a separate binary compound. The insulated binary compound of the radical of muriatic acid with oxygen is oxymuriatic acid, as the binary compound of sulphur and oxygen is sulphurous acid, and of nitrogen and oxygen, nitrous and nitric oxides, Iodine, the discovery of which and its relations, is for a time given predominance to the new doctrine of chlorine, con- forms sufficiently to these views. Some have considered it as a body belonging to the same class as chlorine ; others regard it as more seaippond to sulphur. It has little analogy to either, except in stad property of forming acids with oxygen | and with hydrogen. It differs remarkably from chlorine in its comparative inertness, its solidity, specific gravity, and great weight of its equivalent quantity. And it differs from sulphur in its want of inflammability, its solubility in water, and its be- ing attracted to the positive pole of the voltaic series. All these analogies are preserved, and its relations connected, by considering it as an oxide, which, both from its specific gravity, the colour of its compounds, and the great weight of its equi-. valent quantity, has probably a metallic base ; and which ac~ quires acidity by an addition of hydrogen on the one hand, and on the other by the addition of oxygen, or of oxygen and hydrogen. In these respects, and in many of its chemical pro- perties and relations, a considerable analogy exists between it and oxide of arsenic or oxide of tellurium. Or if it were to be classed as a simple substance, (on the ground of its not having been decomposed,)—which forms an acid with hydrogen, and another with oxygen and hydrogen; it does not in these respects offer any deviation compared with other acidifiable bases, or afford an argument of much weight in support of the undecomposed nature of chlorine. The AND ON SOME SUBJECTS OF CHEMICAL THEORY. 3lT The doctrine I have illustrated, affords a satisfactory expla- nation of the properties of the compounds fermed by oxymu- riatic acid with certain inflammables, particularly with sulphur and phosphorus. These undoubtedly present an anomaly in the other views that have been given ef their constitution. In the old doctrine, they are considered as compounds ef two real acids ;—one of muriatic, with phosphorous or phosphoric acid ; the other of muriatic, with sulphurous or sulphuric acid. But they have none of the properties which would be looked for in such a combination; they have no acidity, or if any appear in one of the compounds with phosphorus, it is to a very limited and doubtful extent ; and they are substances even which have little energy of chemical action. In the. new doctrine they are cable as compounds of chlorine with their bases, sulphur and phosphorus. Of course, as these bases form powerful acids with oxygen, and as chlorine is considered as an element of similar agency as oxygen, communicating similar powers, and conferring acidity even on hydrogen, they might, with not less reason than on the other doctrine, be expected to be acids of the greatest strength. The view I have stated accounts for their characters. They are ternary compounds, of the radical of mu- riatic acid with the particular inflammable,—sulphur, or phos- phorus, with oxygen. The oxygen is not in sufficient quantity to communicate acidity, or, in one of the combinations of phos- phorus, does so only to a very slight extent. But when water is added, a sufficient proportion of oxygen is supplied to pro- duce this result, and the acidity is exalted by the correspond- ‘ing hydrogen entering into the combination. ' What has been called Phosgene Gas, procured under certain circumstances from the action of oxymuriatic gas and carbonic oxide, may be regarded as of a similar nature, the agency of a small por- tion of w water or of hydrogen being probably essential to its for- . mation, 318 OBSERVATIONS ON. MURIATIC ACID, mation, a circumstance which serves to account for the discor- dant results with regard to its production *. It deserves remark, that while there runs through the whole series of acidifiable bases in relation to their combinations with oxygen and hydrogen, a general analogy, there is also some deviation, and something with regard to each that is specific. Sulphur affords the most perfect example of their agency. It forms an acid with hydrogen ; it forms another with oxygen ; and a third, still more powerful, from the joint action of oxy- gen and hydrogen. Carbon forms an acid with oxygen ; it also forms a series of acids of greater strength with oxygen and hy- drogen ; it acquires no acidity, however, from hydrogen alone ; and with an inferior proportion of oxygen it forms an oxide. Phosphorus bears a strict analogy to sulphur, except that its combination with hydrogen does not give rise to acidity, a cir- cumstance in which it resembles carbon. Nitrogen is peculiar in forming two oxides with different definite proportions of oxygen; it is doubtful if it forms a free acid with oxygen alone ; but it conforms to the general law, and forms a powerful acid with oxygen and hydrogen. Assuming the existence of a simple radical of muriatic acid, it resembles sulphur, phospho- rus and carbon, in forming an acid with oxygen, and one still more * The difficulty of entirely excluding water and hydrogen from the consti- tuents of this gas is sufficiently apparent. And the fact, that it cannot be form- ed from them by the action of the electric spark, but only by the continued ac- tion of solar light, is favourable to the above opinion. ‘The conversion of car- bonic oxide into carbonic acid, by the joint action of oxymuriatic gas and hydro- gen, an experiment which I performed when the new hypothesis with regard to the nature of chlorine was brought forward, and which. was attempted to be in~ validated by some singular controversial methods, I consider as depending pro- bably on the same principle. a cored, ee Pe cts AND ON SOME SUBJECTS OF CHEMICAL THEORY. 319 more powerful with oxygen and hydrogen ; but it differs in the peculiarity, that. the proportion of oxygen to the base in the binary combination is considerably larger than in the ternary, so that the addition of hydrogen converts the one into the other; and also in its combining apparently with more nume- rous proportions of oxygen than any of the other acidifiable bases,—two circumstances which, as well as the difficulty of effecting its decomposition, probably depend on the same cause, the strength of its attraction to oxygen. The fluoric are similar to the muriatic compounds, except that the binary com- pound of the radical with oxygen cannot be obtained in an in- sulated form, and that its combinations with oxygen are less numerous. ‘The relations of iodine or its radical are similar to those of the radical of muriatic acid, or perhaps rather to sul- phur, except that its binary compound with oxygen does not appear to have acidity, in which it approaches to the metals. The metals usually combine with oxygen so as to form oxides} some of them also form acids with oxygen, or with oxygen and hydrogen ; and these last usually also combine with hydrogen alone. This fact, of some of the metals forming acids, is so far an anomaly, since their compounds with oxygen rather form alkalis, and no other substances give rise to both results; the greater number of the substances, too, which form saad with oxygen or hydrogen, are evidently, from the smallness of their combining quantities, not of a metallic nature. Still the con- nection between the two classes is in some measure establish- ed on the one hand, by nitrogen, which with hydrogen forms an alkali, and on the other by iodine, which has properties and relations common to both. In some cases it is probable, that there is a variation in the proportions of these ternary combinations, giving rise to a di- versity of products, which exist only in combination with those _ bodies 320 OBSERVATIONS ON MURIATIC ACID, bodies by which their formation is determined, and, being mo- dified by any process causing their evolution, are not easily ob- served. It is doubtful if the same base in any case forms dif- ferent acids by combination with oxygen in different propor- tions, or by combination with hydrogen in different propor- tions. But the example of the vegetable acids seems to shew that this may occur in the united action of oxygen and hydro- gen; carbon acidified by different proportions of ‘these ele- ments, constituting the composition of these acids. Other ba- ses may present similar results. The radical of muriatic acid may unite with other proportions of oxygen and hydrogen than those which form muriatic acid; and this might afford a solu- tion of the theoretical difficulty of the production of water in the experiments in the first part of this memoir, independent of the explanation of it from the formation of a super-muriate. A compound may be formed with less oxygen and hydrogen than what exist in muriatic acid, in combination with the me- tal acted on, and thus a portion of water may be liberated. Nor will it be easy to establish this by any difference in the product, as it can scarcely be submitted to any examination, but by processes which change the result. The chloric acid which, according to Gay Lussac, cannot exist insulated with- out water, may be in like manner a ternary compound of these elements in other proportions. Prosecuting the same analogy, the glacial or fuming oil of vitriol may be, not what has lately been asserted, real sulphuric acid, (for probably no such sub- stance as that to which this term has been applied, can be ob- tained insulated), but a compound of sulphur with oxygen and hydrogen, in proportions different from those which constitute common oil of vitriol. Nitrous acid, if it cannot be formed without water, may be a compound of nitrogen with a smaller proportion — or AND ON SOME SUBJECTS OF CHEMICAL THEORY. 321 proportion of oxygen and hydrogen, than nitric acid. And some of the acids lately described, of which phosphorus is the base, may arise from variations of proportions of this_ kind. The view which I have now illustrated, I must add, is not to be regarded as mere speculation. The evidence in support of it, is just as conclusive as that from which the opposite opinion is inferred. The obtaining water from a compound is no ne- cessary proof that water pre-existed in it; and conversely, the causing water to enter into combination in a compound, is no necessary proof that it remains in the state of water in the product. In many cases we draw the reverse conclusions, con- sidering water as being formed where it is obtained, and as de- composed where it is communicated. And in the case of its re- lation to acids, it will be found that there is no strict evidence of its existing as water in combination with what is considered as the real acid; and of course the conclusion is equally open to be drawn, that it exists in these combinations in the state of its elements, and that when obtained, it is a product of a change of composition. It is even more probable, a priori, that the ultimate elements should act on each other where energetic affinities are evident- ly exerted, than the immediate principles, and the relations of these elements will determine the combinations, and the pro- portions. And by admitting this view, we avoid the anomaly which is presented in ascribing to the agency of water effects so different from those to which it usually gives rise. In ge- neral, water operates on bodies simply as a solvent, overcoming cohesion in solids, diluting liquids, or absorbing gases, without otherwise modifying their properties, or communicating to them any important chemical powers. But in the particular cases now referred to, it is supposed to produce the effects of Vou. VILL P. II. Ss. the 322 OBSERVATIONS ON MURIATIC ACID; the most energetic chemical agent ; it enters into combination in proportions strictly definite, is retained by the most power- ful affinities; communicates new and characteristic properties ; and is essential even to the existence of these compounds, in an insulated form. Berzextius and Gay Lussac have stated, that it is to be considered as a base necessary to retain the ele- ments of the acid combined, though without neutralising the acid properties,—an opinion which in itself, and still more with this condition, is certainly sufficiently incongruous. And both theories admit equally of incongruity in the supposed presence and energetic action of water in acids. The old doctrine ad- mits its influence in sulphuric, nitric, phosphoric, and muriatic acids, though at variance with its principle, that oxygen is the element which confers acidity, or at least having no conformi- ty to that principle, nor receiving explanation from it. The new doctrine refuses to admit it with regard to muriatic acid, but admits it in all the others,—an exception which serves only to render the system more objectionable by the violation of analogy; while the admission with regard to the others is equally incapable of being accounted for on any principle it af- fords. By considering oxygen and hydrogen as elements conferring acidity, a satisfactory solution is afforded of the ef- fects produced in these cases by their joint operation; and in- dependent of this, it is much more probable, a@ priori, that such effects should arise from the action of elements so powerful, than from the agency of water, which, in its general relations, exerts such feeble powers. Lastly, The principle on which the presence of combined water in these acids has been supposed. to depend, —that of the strong attraction of the acid to water, seems altogether fallacious; for on this principle sulphurous acid should also contain combined water, and sulphuretted hy- drogen, and even carbonic acid, might be expected to retain a small . oer Re AND ON SOME SUBJECTS OF CHEMICAL THEORY. 323 small portion. The whole evidently depends on difference of constitution. Sulphurous acid, sulphuretted hydrogen, and carbonic acid, are binary compounds, and therefore yield no water, nor retain any in intimate combination; and in the others, the proportion of water supposed to exist will be found to have no relation to the attraction of the acid to water, so far as this can be inferred, as is evident from the example of phos- phoric acid affording as much as sulphuric or nitric ; but to the relations of its elements, and more particularly of its oxygen, to the radical. This last fact affords nearly a demonstration, that the constitution is that of simultaneous combination of the ele- ments, and not that of water and acid. That water may also exist in immediate combination with acids, without being resolved into its elements, is sufficiently possible; and it probably is in this state, in those cases, in which there are no indications of an intimate combination, or definite proportion. It may then be considered as in solution similar to that in which it holds salts dissolved, or, what is a closer analogy, similar to that in which it holds dissolved the vegetable acids, which are admitted to be ternary compounds -of carbon, hydrogen, and oxygen. The opposite view applies only to that portion of water considered as essential to the body in an insulated state, and in which it is combined in a de- finite proportion, observing in its relations, or the relations of its elements, equivalent proportions to other bodies. In the last place, Considering this opinion in relation to the _ two opposite views which have been maintained with regard to the constitution of oxymuriatic and muriatic acids, while it has all the evidence in its favour from which the existence of wa- ter in muriatic acid gas is inferred, and all the analogies by which this is confirmed ; it has the support which the doctrine of the undecompounded nature of chlorine derives from the re- Ss2 lations 324 OBSERVATIONS ON MURIATIC ACID, lations of sulphur, iodine, and cyanogen; and from the indue- tion that hydrogen, as well as oxygen, communicates acidity. It avoids, at the same time, the improbability which attends that doctrine, in its leading principle, that muriatic acid con- tains no combined water, though other powerful acids are held to contain it, and though it affords water by the very same pro- cesses by which they yield it; and in the still greater violation of analogy, (the most extraordinary perhaps ever admitted in chemical reasoning), involved in the conclusion, that the com- pounds which this acid forms with salifiable bases, though the same in all generic properties with those formed by other acids, are not of similar constitution, and are not even ofa saline nature. It unites the advantages, therefore, of both doctrines, and con- nects under one system facts which are otherwise insulated, and partial generalisations, which, instead of having any rela- tion, seem opposed to each other. The same general view, I have still to add, may be farther extended. Alkalinity, as well as acidity, is the result appa- rently of the action of oxygen; the fixed alkalis, the earths, and the metallic oxides, which all contain it as a common ele- ment, forming a series in which it is difficult to draw any well defined line of distinction. Ammonia alone remains an excep- tion: it contains no-oxygen, and yet possesses in a very mark- ed degree all the alkaline properties,—an anomaly so great, as to have led almost every chemist to infer that oxygen must ex- ist as an element in one or other of its constituent principles ; and as nitrogen is the one apparently least elementary, it has been supposed to be a compound containing oxygen. ‘The re- sult may be accounted for, however, on a very different prin- ciple. As hydrogen, in some cases, give rise, as well as oxy- gen does, to acidity, so it may in other cases give rise to alka- linity. Under this point of view, ammonia is a compound of which ee q J y : : wie AND ON SOME SUBJECTS OF CHEMICAL THEORY. $825 which nitrogen is the base, deriving its alkaline power from hydrogen ; it stands, therefore, in the same relation to the other alkalis, that sulphuretted hydrogen does to the acids. And thus the whole speculation with regard to the imaginary me- tallic base Ammonium, and the existence of oxygen in ammo- nia, and in nitrogen, falls to the ground, while the anomaly pre- sented by this alkali is removed. If the claim of the lately discovered principle in opium, Morphia as it has been named, to the distinction of an alkali be established, as from its origin it must probably have a compound base, it may, if it contain hydrogen, bear the same relation to the other alkalis, that prus- sic acid does to the acids; or if it contain oxygen, it will be analogous to the vegetable acids. The fixed alkalis, and the alkaline earths, are considered as containing water in intimate combination, in a definite propor- tion ; and it is doubtful if they can be obtained free from it in an _ insulated state, retaining at the same time their alkaline pro- perties. It is obvious, however, that the elements of water may exist in combination with the base: that potash, for ex- ample, is not a compound of an oxide of potassium with water, but of potassium, oxygen and hydrogen. Hence when, on add- ing water to peroxide of potassium, potash is produced, and oxyen gas is disengaged ; this is not owing, as has been suppo- sed, to the excess of oxygen in the peroxide being expelled, and the water taking its place; but to the water being decom- posed, and a portion of its hydrogen entering into the combi- nation; to form the alkali, while the corresponding oxygen is liberated. If hydrogen were brought to act on peroxide of potassium, the alkali would in like manner be formed. With .the peroxide of barium, this very change, from the action of hy- _ drogen, takes place ; the hydrogen, according to the usual ex- planation, combining with its oxygen, and forming water, which unites 326 OBSERVATIONS ON MURIATIC ACID, unites with the real earth, forming the hydrate ;—in other words, and according to the strict expression of the fact, the hydrogen entering into the composition, and forming the ba- rytes ;—a result perfectly analogous to the formation of muri- atic acid from oxymuriatic gas by the agency of hydrogen. The evidence in support of this doctrine, it is evident, is of the same kind as that with regard to the doctrine applied to the acids. There is the same superior probability in favour of the conclusion, that the elements of water, rather than water itself, exist in these compounds, from the consideration, that modifications of properties so important, are more likely to arise from the agency of these elements, than from any action which water can exert. And that water does not exist in them, in consequence of the strength of attraction which the real al- kali, as it has been considered, exerts towards it, is evident from this, that on the same principle ammonia ought to con- tain combined water in its insulated form, which is not the case. The combination of water, therefore, or rather of its principles, in these compounds, depends on relations subsist- ing among the ultimate elements, not on an affinity exerted by the alkali itself; and this adds confirmation to the conclusion, that these elements are in ternary union. Their superior alkaline energy, compared with the common metallic oxides, may obviously arise from the joint action of the hydrogen and oxygen, in the same manner that the acidity of the ternary, compared with the binary acils, is increased by a similar constitution. Thus the class of alkalis will exhibit the same relations as the class of acids. Some are compounds of a base with oxygen: such are the greater number of the me- tallic oxides, and several, probably, of the earths. Ammonia is a compound of a base with hydrogen. Potash, soda, barytes, strontites, and, probably, lime, are compounds of bases with oxygen AND ON SOME SUBJECTS OF CHEMICAL THEORY. 327 oxygen and hydrogen ; and these last, like the analogous order among the acids possess the highest power. Many of the me- tallic oxides, however, in the state in which they combine with the greatest facility with the acids, are hydrates,—that is, sup- posed compounds of the oxide with water, but probably ter- nary compounds of the metal with oxygen and hydrogen; and their facility of combination, may depend on this constitution. The same principle explains the necessity, not otherwise easi- ly accounted for, of the presence of water, to enable some of the earths, as barytes, to combine with acids. There are two views under which the neutral’ salts may be considered in the preceding theory. It has been shown, that when water is obtained in the action of a salifiable base, whe- ther alkali, earth, or metallic oxide, there is reason to infer that this water is formed by the hydrogen and part of the oxygen of the acid entering into binary combinations ; and when water is obtained from an alkali by the action of an acid, there is the same reason to believe, that it is formed by the combination of the hydrogen of the alkali with a portion of its oxygen. In these cases it may be supposed, that the radical of the acid combines with its remaining oxygen, forming a binary com- pound, which may still be considered as an acid; and that the radical of the alkali combines with its remaining oxygen, form- ing a binary compound, which may be regarded as an alkali; and these two compounds may unite with each other, forming the neutral salt. This is conformable nearly to the common doctrine. But there is another point of view under which the subject may also be considered. A ternary combination, into which oxygen and hydrogen enter, gives rise apparently to a higher state of acidity, and to a greater degree of alkaline ener- gy than is acquired from a mere binary combination into which ‘oxygen enters. It is doubtful, therefore, if such binary com- pounds 328 OBSERVATIONS ON MURIATIC ACID, &c. pounds were formed, if they would constitute either acid or al- kali. And there is at least no proof of their formation. In all these cases, while the hydrogen present combines with the re- quisite proportion of oxygen forming water, the radical of the acid, and the radical of the base, may enter into union with the remaining oxygen, and form a ternary compound. And where hydrogen is not present, such a combination may be at once established. It is not easy to determine which of these opinions is just. The reason above stated, renders the latter, perhaps, more pro- bable ; and the view which leads to the conclusion, that in the constitution of the acids and alkalis, the three elements, when present, are in simultaneous combination, leads also to a similar conclusion with regard to the constitution of the neu- tral salts. If this be adopted, neutralisation is not the satura- tion of acid with alkali, and the subversion of the properties of the one by the opposed action of those of the other ; but is the change of composition of both, and the quiescence of the ele- ments, in that proportion in which their affinities are in a state of equilibrium without any excess. The compounds, therefore, have little activity ; and energy of action is restored only by the reproduction of substances, which, by their mutual attrac- tions, tend to the same state of quiescence. All these results display more fully the extensive relations of the two elements, oxygen and hydrogen. They do not act merely in opposition, as had been imagined, but more fre- quently in union, producing similar effects. Hydrogen is of nearly equal importance with Oxygen, and the principal details of chemistry, consist in their modified action on inflammable and metallic bodies. XVII. SS XVII. Experiments on the Relation between Muriatic Acid and Chlorine ; to which is subjoined the Description of a New Instrument, for the Analysis of Gases by Explo- sion. By ANprew Ure, M. D. Professor of the An- dersonian Institution, and Member of the Geological Society. (Read Nov. 17. 1817.) PART IL. ia Chloridic Theory, though more limited in its application to chemical phenomena, than the Antiphlogistic, may justly be regarded as of scarcely inferior importance. If established, it leads to the adoption of entirely new views concerning com- - bustion and many of its. products ; it removes the muriates, a set. of apparently well characterised saline bodies, from the class of salts altogether ; and it has given birth, by analogy, to two new genera of compounds, in which iodine and fluorine, like chlorine, act a corresponding part with. oxygen, in the sys- tem of Lavoisier. This new era in chemical’ science, unquestionably origina= ted from the masterly researches of Sir Humpury Davy on Oxymuriatie Acid Gas; a substance which, after resisting the most powerful means of decomposition which his sagacity could invent, or his ingenuity apply, he declared to be, according to the true logic of chemistry, an elementary body, and not a Vou. VIII. P. ID. Te compound. 830 EXPERIMENTS ON THE RELATION compound of muriatic acid and oxygen, as was previously ima- gined, and as its name seemed to denote. He accordingly as- signed to it the term Chlorine, descriptive of its colour ; a name now generally used. Chlorine when combined with an equal volume of hydrogen, forms Muriatic Acid Gas, the Hydrochloric of Gay Lussac. This muriatic acid gas, hygrometrically dry, unites with its own bulk of dry ammoniacal gas, to constitute the dry pulverulent solid called Sal Ammoniac. Hence this saline body is ulti- mately composed of chlorine and hydrogen, for its acid; and of azote and hydrogen, for its base. By comparing the weights of muriatic acid and ammoniacal gases, in equal volumes, we obtain the proportion of 67.8 muriatic acid gas, to 32.2 ammo- nia, for the composition of 100 parts by weight of the solid salt. If we saturate liquid muriatic acid with gaseous ammo- nia, or with the base of the ammoniacal carbonate, and evapo- rate carefully to dryness, we find the resulting salt to have pre- cisely the same constitution, namely, in 100 parts, 51 of dry muriatic acid, equivalent to 67.8 of the acid gas, and the re- mainder 32.2 ammonia. This concurrence of results, whatever way the salt may be obtained, is fully demonstrated in my re- searches on the ammoniacal salts, (Annals of Philosophy for September 1817), and proves it to be a substance of very uni- form and determinate composition. Those chemists who consider chlorine to be oxymuriatic acid, must suppose, when a volume of it weighing 44.13 unites with an equal volume of hydrogen, weighing 1.32, that, in the resulting hydrochloric or muriatic acid gas = 45.45, this hy- drogen exists combined with 10.00 of oxygen, its saturating quantity, forming 11.32 of constituent water. In this view, uriatic acid gas, like gaseous, sulphuric, and nitric acids, con- tains water as an essential element. There seems to be no violation BETWEEN MURIATIC ACID AND CHLORINE. 331 violation of chemical analogy in this supposition. The quan- a oa! ¢ . 11.32 : tity will be represented by the fraction sins being nearly one- fourth. If chlorine, however, be a simple body, which forms with hydrogen, muriatic acid gas, then sal ammoniac is rightly na- med Hydrochlorate of Ammonia. And since ammonia itself results from three volumes of hydrogen and one of azote, con- densed into two volumes, that saline body can contain neither water, nor its indispensable element oxygen. On the other hand, if chlorine be oxymuriatic acid, then the fourth part of water existing in the resulting muriatic acid gas, must necessarily enter into the sal ammoniac as an essential constituent ; for the whole ponderable matter of that gas, as well as of the ammonia, passes into the salt. This water being as indispensable an ingredient of sal ammoniac as it is of oil of vitriol ; heat alone can no more separate it from the former,. than it can from the latter compound. Moreover, if we decompose sal ammoniac by the agency of any body containing oxygen, an evident source of fallacy exists relative to the watery product, which may be referred by the supporters of the chloridic theory, not to the salt itself, but to the hydrogen of the hydrochloric acid, united with the oxygen of the decomposing substance. This ambiguous interpretation, is experimentally illustrated, in my paper on the Ammoniacal Salts. If, however, we shall decompose that. equivocal salt, by means of a substance, which certainly contains no oxygen; and if we still obtain water in nearly the above proportions, then this re- sult is no longer equivocal, nor will it admit of two interpreta- tions. We must thenceforth be: compelled to recognise in mu- ‘ viatic acid gas, as in the other acid vapours, waTer as an ingre- ite 2 dient $382 EXPERIMENTS ON THE RELATION dient essential to its constitution ; and to acknowledge that chlorine consists of a base united to oxygen, or is in fact oxy- genated muriatic acid, as Lavoisier and Bertuo.zer taught, and as the whole chemical world believed, till their faith was late- ly shaken or subverted, by the predominating genius of Sir Humpury Davy. With the view of deciding the above important controversy, I performed the following experiments. Of sal ammoniac, kept for some time in a platina capsule at a subliming heat, to remove every particle of adhering mois- ture, a known quantity was put into a glass tube, and made to slide down to the one end, which had been hermetically sealed. Over it a given weight of bright metallic lamine, cut into slen- der segments, was lightly pressed. The salt occupied in gene- ral about one inch of the tube; the Jamine four or five inches. Silver, copper, and turnings of iron made with a dry tool, were employed in successive experiments. The open extremity of the tube was drawn out to a point, and recurved, so as to pass under a vessel inverted on the mercurial pneumatic trough. Between this and the portion containing the metal, there was a length of six or more inches of tube, which was kept cool. In one variation of the experiment, a tube of Reaumur’s por- celain was used for containing the materials, to which was firmly luted by a collar of caoutchouc, a glass tube, with a little globe blown in its middle, and its loose end plunged, as usual, into the mercurial trough. . When tubes of crystal glass were employed, the part con- taining the materials was lodged in a semicylindrical case of iron, which traversed a small charcoal furnace, five or six inches in diameter. The metallic laminz being raised to full ignition in day-light, the case and tube were slightly moved forward, BETWEEN MURIATIC ACID AND CHLORINE. $33 forward, in order to bring a little of the salt within the sphere of the heat. Great nicety was required in the advancement of the sealed extremity ; for the glass tube being perfectly soften- ed in its middle, too sudden volatilisation of the salt never failed, by inflating and bursting it, to spoil the experiment. - This accident frequently happened. On the other hand, if the central part of the tube was exposed to merely a dull red, the experiment would not succeed with silver and copper. At this temperature they did not decompose the sal ammoniac. When, however, the above-mentioned precautions were obser- ved, dew could be perceived to settle speedily on the cool por- tion of the tube. This dew became more and more visible as the sublimation advanced, till, finally collecting into distinct drops, it trickled down the sides in strize, and formed a fila- ment along the bottom. ‘To obtain good results of this kind, four or five hours must be devoted to one experiment, in which 20 grains of salt, and from 60 to 100 of metal, are em- ployed. More rapid transmission of the salts effects mere sub- limation. Bubbles of gas come over, which, with silver and copper laminz, are found to be a mixture of ammonia and hy- drogen. In this case, the liquid condensed, is water of ammo- nia. The metallic laminz are evidently heavier than before their introduction ; but the increase of their weight could not be ex- actly ascertained, because a portion of the silver or copper is impressed on the inner surface of the tube, giving it a very beautiful iridescent and metallic lustre, similar to the colours of the diamond beetle, viewed in a microscope. The silver la- minz, have for the most part exchanged their native brilliant white, for a dull-brown or greyish hue}; and instead of being eminently tough and ductile, have become more brittle than any substance with which I am acquainted. The slightest touch 334 EXPERIMENTS ON THE RELATION touch of the finger breaks them across. Digested in pure ni- tric acid somewhat dilute, the segments only partially dissolve, bits of muriate of silver, of their own shape, being left in the liquid. . The ignited copper turnings, after experiencing the action of sal ammoniac, are found to have lost also their original lustre, and have acquired a dull brown colour. Digested in water, a liquid muriate is obtained, which gives the characteristic brown precipitate with prussiate of potash. The most considerable of my experiments with turnings was made with the tube of Reaumur’s porcelain, which, as it con- tains no oxide of lead, is not liable to any ambiguity on this. score, and being capable of sustaining a very high heat with- out fusion, permitted me to obtain very satisfactory results in- deed. Thirty grains of recently heated sal ammoniac being put down to the sealed end, 200 grains of bright turnings of very pure soft iron were introduced over it, so as to occupy six inches of the tube. The glass tube above described, was at- tached by the elastic gum collar. The part holding the iron being brought to bright ignition, the sealed end of the tube was advanced by degrees almost imperceptible. As soon as the salt began to exhale, moisture began to condense in the glass tube, though none ever appeared prior to heating the sal ammoniac. The evolution of gas was much more copious: than in any of the experiments with the other metals. When allowed to escape through the quicksilver into the air, it exhi- bited the dense cloud, and had the odour of muriatic acid. Received into a tube over mercury, and then exposed to the action of water, ;4, parts of the volume were absorbed, which on trial were found to be pure muriatic acid. The remainder was a mixture of azote and hydrogen, in the proportions very nearly Bid ve BETWEEN MURIATIC ACID AND CHLORINE. 335 nearly that are known to constitute ammonia, I analysed this mixed gas, by explosion with half its volume of pure oxygen, in a peculiar apparatus, which I shall describe in the sequel. On firing 100 measures with the electric spark, ‘76.2 disappear- ed, 2 of which, = 50.8, are hydrogen. Before explosion, the hundred volumes consisted of 662 ammoniacal gaseous matter, + 331 oxygen. Of these 662 parts, 50.8, are hydrogen, and 15.86 azote ; or in the 100, 76.2 4+ 23.8. But, by Gay Lus- sac, 1 volume of azote unites with 3 volumes of hydrogen to form ammonia. Hence 23.8 measures of azote should have been accompanied with only 71.4 of hydrogen, instead of 76.2 actually obtained. This excess of hydrogen is due to the de- composition of a little of the watery product, in the formation of the muriate of iron. That muriate of iron is formed, is pro- ved by many circumstances. First, the disappearance of the acid in the gaseous products. Sal ammoniac being decompo- sed with its ultimate gases, will consist of two measures of those constituting the alkali + one measure of the muriatic. Hence 100 volumes should contain 333 of this acid gas; but they actually contained only about 5. Therefore about 28 measures, which form the difference, were condensed with the iron. Secondly, the iron turnings had increased in weight ; they deliquesced speedily on exposure to the atmosphere, and, digested in water, they yielded an acerb-tasted solution of mu- riate of iron, giving with prussiate of potash a copious blue | precipitate. The quantity of muriate produced in the experiment, will depend on the proportion of turnings which have been but moderately heated; for the ammonia, in its passage over the strongly ignited iron, may be conceived to separate the oxy- gen, and thus prevent the formation of muriate. Water 336: EXPERIMENTS ON THE RELATION Water impregnated with muriatic acid equal in weight to nearly one-sixth of the sal ammoniac decomposed, is uniform- ly obtained by the above process. Scarcely a particle of am- monia seems to escape entire decomposition. The evolved muriatic acid, amounting to -£,; of the whole gaseous products, must carry off with it a portion of its constituent water. Hence we ought to find a little less water here condensed, than, by my experiments on the ammoniacal salts above refer- red to, sal ammoniac, viewed as a muriate, is shewn to con- tain. It seems evidently to follow, from this experimental detail, that chlorine is oxygenated muriatic acid. Since dry sal am- moniac consists of ammonia and muriatic acid gases, both hy-. grometrically dry ; and since water is obtained in its decompo- sition by pure metals; this water must have existed in the ga- seous acid ; for all experiments concur.in proving ammonia it-. self to contain nothing but azote and hydrogen. And, finally, since muriatic acid gas is a compound of chlorine and hydro- gen, the water derived from the resulting muriatic acid, de- monstrates the presence of oxygen in the chlorine, or, in other words, that it is really oxymuriatic acid *. All the experimental phenomena hitherto adduced in the ehloridic controversy, were susceptible of explanation on both the old and new doctrine. Thus, the hydrogen which remains after tin is subjected at a high temperature to muriatic acid gas,, * If the Chloridic Theory be still retained, then the production of water in the above circumstances can be ascribed only to the decomposition of azote into oxygen and hydrogen, as has been already indicated in my paper on the Ammo- niacal Salts. It is possible that this alternative may eventually be found the true one; yet in the present state of our knowledge, such an inference would be il- logical. cade S ee BETWEEN MURIATIC ACID AND CHLORINE. 337 gas, could be regarded with Davy, as resulting from a metallic analysis of hydrochloric acid ; or it might be derived from the _combined water of muriatic acid, of which the oxygen became fixed in the muriate of tin. When chlorine also at high heats was made to act on earths or common metallic oxides, the evolved oxygen, could be referred with equal probability either to the solid or to the gas. And though we ignite by the strongest voltaic power, char- coal or other combustibles in chlorine, still we shall not be able to convert it into muriatic acid gas, for want of the essen- tial constituent water ; no more than we can, without the same water, obtain oil of vitriol. Present water to chlorine, then light alone will separate its oxygen, and leave muriatic acid. Such, indeed, is the affinity existing between the muriatic acid basis and water, that those muriates which of themselves resist decomposition at a red heat, when exposed at that tem- perature to the vapour of water, are speedily resolved into ga- seous muriatic acid, and. their peculiar bases. By restoring the theory of Lavoisier and BerrHo.ier, we get rid of those mysterious and almost incomprehensible trans- formations which a drop of water has been lately conceived to produce on some of the muriates. Dried sea-salt, for example, when viewed as a compound of chlorine and sodium, is no sooner moistened, than. a portion of water resolves itself into oxygen and hydrogen, whence result soda and hydrochloric acid, and a solution of muriate of soda. Expel the drop of water, we have a chloride of sodium once more; and we may repeat this invisible change for an indefinite number of times by the addition or subtraction of a little moisture. Thus we must consider dry salt and moist salt to be bodies widely and essentially different, the former containing neither alkali nor Vou. VIII. P. Il. Uu acid, 338 EXPERIMENTS ON THE RELATION acid, while the latter contains both. This supposition, which the chloridic theory compels us to make, must surely be rec- koned somewhat violent. Description of an Apparatus for the Analysis of Gaseous Matter by Explosion. The analysis of combustible gases, and supporters of com- bustion, reciprocally, by explosion, with the electric spark, furnishes, when it can be applied, one of the speediest and most elegant methods of chemical research. The risk of fai- - lure to which the chemist is exposed, in operating with the simple tube, from the ejection of the mercury, and escape or introduction of air; or of injury from the bursting of the glass, by the forcible expansion of some gaseous mixtures, has given rise to several modifications of apparatus. Votra’s mechanism, which is employed very much at Paris, is complex and expensive *, while it is hardly applicable to ex- periments over mercury. Mr Perpys’s ingenious contrivance, in which the glass-tube is connected with a metallic spring, to diminish the shock of explosion, is liable also to some of the above objections. A very simple form of instrument occurred to me about two years ago, in which the atmospheric air, the most elastic and economical of all springs, is employed to receive and deaden the recoil. Having frequently used it since that time, I can now * The price of the apparatus is about three guineas. PS et SE ag ~~ diameter of from 32; to 34; of an bali Its legs 9 inches long. ‘The open extremity is slightly BETWEEN MURIATIC ACID AND CHLORINE. 339 now recommend it to the chemical world, as possessing every requisite advantage of convenience, enamine safety and pre- cision. It is represented on the margin. It consists of a gine ephon, having an interior ’ are of nearly eat ieeeth, each being from 6 to funnel-shaped ; the other is hermetically sealed ; and has inserted near it, by the blow-pipe, two platina wires. The outer.end of the one wire is incurvated across, so as nearly to touch the edge: of the aperture ; that of the other is formed into. a little hook, to allow a small spherical button. to be attached to it, when the electrical spark is to be transmit- ted *. The two legs of the syphon are from } to-} inch asun- der. The sealed leg is graduated, by can ai successively. equal weights of mercury from a measure glass-tube. Seven ounces Troy and.66 grains, occupy the space of a cubic inch ; and 34+ grains represent. +4; part.of that volume. The other Jeg may be graduated also, though. this.is not necessary. The instrument is then finished. To use it, we first fill the whole he with mercury or water, which a little practice will render easy.. We then intro- duce into the open leg, plunged into a pneumatic trough, any convenient quantity of the gases, from a glass-measure tube containing them previously mixed in determinate proportions. Applying a finger to the orifice, we next remove it from the trough in which it stands, like a simple tube; and by a little dexterity, * In the figure, the ball should have been represented pendent from a hook. 340 EXPERIMENTS ON THE RELATION dexterity, we transfer the gas into the sealed leg of the syphon. When we conceive enough to have been passed up, we remove the finger, and next bring the mercury to a level in both legs, either by the addition of a few drops, or by the displacement of a portion, by thrusting down into it a small cylinder of wood. We now ascertain, by careful inspection, the volume of included gas. Applying the fore-finger again to the orifice, so as also to touch the end of the platina wire, we then ap- proach the pendent ball or button to the electrical. machine, and transmit the spark. Even when the included gas is consi- derable in quantity, and of a strongly explosive power, we feel at the instant nothing but a slight push or pressure on the tip of the finger. After explosion, when condensation of volume ensues, the finger will feel pressed down to the orifice by the superincumbent atmosphere. On gradually sliding the finger to one side, and admitting the air, the mercurial column in the sealed leg will rise more or less above that in the other. We then pour in this liquid metal, till the equilibrium be again re- stored, when we read off as before, wi:hout any reduction, the true resulting volume of gas. As we ought always to leave two inches or more of air be- tween the finger and the mercury, this atmospheric column serves as a perfect recoil spring, enabling us to explode very large quantities without any inconvenience or danger. The manipulation is also, after a little practice, as easy as that of the single tube. But a peculiar advantage of this detachable instrument, is to enable us to keep our pneumatic troughs and electrical machine at any distance which convenience may re- quire ; even in different chambers, which, in the case of wet weather, or a damp apartment, may be found necessary to en- sure electrical excitation. In the immediate vicinity of the water pneumatic cistern, we know how often the electric spark refuses or ae BETWEEN MURIATIC ACID AND CHLORINE. 341 refuses to issue from a good electrophorus, or even little ma- chine. Besides, no discharging rod or communicating-wire is here required. Holding the eudiometer in the left hand, we turn the handle of the machine, or lift the electrophorus plate with the right, and approaching the little ball, the explosion ensues. The electrician is well aware, that a spark so small as to excite no unpleasant feeling in the finger, is capable, when drawn off by a smooth ball, of inflaming combustible gas. Even this trifling circumstance may be obviated, by hanging on a’slender wire, instead of applying the finger. We may analyse the residual gaseous matter, by introducing either a liquid or a solid re-agent. We first fill the open leg nearly to the brim with quicksilver, and then place over it the substance whose action on the gas we wish to try. If liquid, it may be passed round into the sealed leg among the gas ; but if solid, fused potash for example, the gas must be brought round into the open leg, its orifice having been previously clo- sed with a cork or. stopper. After a proper interval, the gas being transferred back into the graduated tube, the change of its volume may be accurately determined. With this eudio- meter, and a small mercurial pneumatic cistern, we may per- form pneumatic analyses on a very considerable scale. It may be desirable in some cases, to have ready access to the graduated leg, in order to dry it speedily. This advantage is obtained, by closing the end of the syphon, not hermetically, but with a little brass cap screwed on, traversed vertically by a platina wire insulated in a bit of thermometer tube. . After the apparatus has been charged with gas for explosion, we con- nect the spherical button with the top of the wire. With the above instrument I have exploded half a cubic inch of hydrogen mixed with a quarter of a cubic inch of oxy- gen ; 842 EXPERIMENTS ON THE RELATION gen; as also, a bulk nearly equal of an olefiant gas explosive mixture, without any unpleasant concussion or noise ; so com- pletely does the air-chamber abate the expansive violence, as ~ well as the loudness of the report. Projection of the mercury, or displacement of the gas, is obviously impossible.. . PART | Hil ee a > [ 343 ] PART IL (Read Jan. 19. 1818. ) EXPERIMENTS MADE WITH THE VIEW OF DETERMINING THE RELA~ TION BETWEEN MURIATIC ACID AND CHLORINE. To the inferences which I have ventured to draw, from the experimental results detailed in the preceding part of this pa- per, two objections may be offered. First, That the aqueous product obtained in the decomposi- tion of dry sal ammoniac, by ignited metallic laminze, may pos- sibly be derived from the azote of the ammonia, supposing azote not to be a distinct elementary substance, but a peculiar oxide of hydrogen. This notion occurred to me at an early period, in consequence of the anomalous, and unaccountable disap- pearance, of a portion of ammonia, and the concomitant pro- duction of water, as described in my experimental researches on the ammoniacal salts. ‘To determine how far this view was correct in the present instance, I made the following experi- ment: Into a tube of green glass, sealed at one end, I put 30 gr. of desiccated sal ammoniac. Over it 200 gr. of pure iron turnings were placed, which occupied 5 inches of the. tube. The open end of this was connected by a collar of caoutchouc, with a narrow tube of crystal glass, having a small : sphere 344 EXPERIMENTS ON THE RELATION sphere blown in its middle, and its other extremity iia into pure water, in a glass pneumatic cistern. When the part ar the green glass tube where the turnings Jay, was brought to ignition very visible in day-light, it was moved forward with its supporting semi-cylinder of iron, by imperceptible degrees. Thus the salt was exhaled from the bottom, so slowly, that its vapour, in traversing the numerous convolutions of the iron laminz, was almost entirely decompo- sed into its constituent gases. The muriatic acid gas was (as formerly stated) partly condensed into muriate of iron, partly into liquid acid in the bulb, and partly into the water in the glass cistern. Of permanent gaseous matter 106 cubic inches were collec- ted, after the whole salt had been sublimed from the bottom of the tube. One hundred cubic inches of these were found by explosion with oxygen in my eudiometer, to consist of 77 hy- drogen + 23 azote. Hence the total product of 106 cubic inches was composed of 81.62 hydrogen, and 24.38 azote. Now 20 grains of sal ammoniac contain 9.66 gr. of ammo- nia. And since 18.178 gr. of this alkaline gas occupy the vo- lume of 100 cubic inches, but are resolvable into double that volume, or 200 cubic inches of constituent gases; therefore 9.66 gr. of ammonia will give by their entire decomposition 106.28 cubic inches of gaseous products. Of these, one-fourth according to M. Gay Lussac’s theory of volumes, is azote, and three-fourths hydrogen ; or 26.57 of the former, and 79.71 of the latter. Hence we see that the total bulk of evolved gases, coincides very nearly with the quantity known to exist in the ammonia. The azote, therefore, is not concerned in the production of the water. The deficiency of about two cubic inches of this gas, may be fairly ascribed to a small portion of the salt having escaped ae Sere Se ee eee eee BETWEEN MURIATIC ACID AND. CHLORINE. 345 escaped decomposition. The excess in the proportion of hy- drogen, is due to the decomposition of the water of the muria- tic acid, in the formation of the muriate of iron. The muria- tic acid was precipitated from the dissolved and filtered muri- ate of iron, as well as from the liquid of the bulb, and of the trough, by nitrate of silver, and the muriate of silver corre- sponded very nearly with the quantity which 30 grains of sal ammoniac ought to afford. Of ignited red oxide of iron, treat- ed with nitric acid, there was obtained 8.8 grains. These are equivalent, as we shall find in the sequel, to 19.06 gr. of the peculiar white muriate of iron formed in this process. Having thus, I presume, given a satisfactory answer to the. first objection, I shall proceed to the second. This may be ur- ged by those who conceive that common sal ammoniac tho- roughly desiccated by heat, and the salt resulting from the combination of the acid, and alkaline gases, in a dry state, are not identical in their composition. Though the very numerous experiments which I had. for- merly made on the ammoniacal salts, had entirely satisfied me that well dried muriate of ammonia is uniform in its composi- tion, in whatever way prepared ; yet I deemed it a duty I ow- ed to those who might entertain doubts on the subject, to make the analysis by ignited iron, of sal ammoniac formed from dry gaseous matter. Accordingly, muriatic acid gas was evolved without heat from dry muriate of soda, and concentrated sulphuric acid ; and ammoniacal gas, from a mixture of dry lime and dry sal am- moniac. Each gas being shewly generated, and slowly passed along a tube of thin ies) three feet long, surrounded with pa- per, kept moist with ether, was brought! into contact with the other, in a small glass globe, furnished with two tubulures. Thirty-five grains of a brilliant white and very light pulveru- Vox. VIII. P. I. Xx lent 346 EXPERIMENTS ON THE RELATION lent matter, like magnesia, were obtained. These being heat- ed for some time in a platina capsule, on a sand bath, to a temperature just under sublimation, lost exactly half a grain. The salt was found perfectly neutral by litmus paper. Twenty grains of this hot and dry salt, were pressed down to the sealed end of a green glass tube ; and 120 grains of pure iron turnings being put over them, the former arrangement of furnace, communicating tube, and mercurial trough, was adopt- ed. After some hours of careful igneous decomposition, about three grains of liquid were obtained. A similar portion of muriatic acid gas, to what is formerly stated, was evolved, along with the gaseous elements of ammonia. Thus I conceive the second objection to be done away. To place the identity of the two differently prepared salts, in the clearest light, I shall state one additional experiment. I took 5 gr. of that made by gaseous combination, and 5 gr. of the common kind, both well dried, and dissolving them in wa- ter, precipitated the whole of their acid, by nitrate of silver. The gently ignited muriate of silver, obtained from each, was almost exactly equal; the minute fractional difference, being an excess on the side of the ordinary sal ammoniac. Hence we see, that the latter contains as much acid, and consequent- ly as little of the base or ammoniacal hydrate, (as we may now term it), as the former. Doctor Murray, in the able critique which he has given, in his valuable System of Chemistry, on the chloridic hypothesis, adduces some experiments of his own, which he conceives establish the opposite, or oxymuriatic doctrine. They consist- ed in procuring by heat a visible portion of aqueous. matter, from the saline compound of ammoniacal and muriatic acid gases, BETWEEN MURIATIC ACID AND CHLORINE. 347 gases, both dried previous to their union. He heated the salt by itself, or passed it through hot charcoal. ‘ I have exposed the above salt, as well as ordinary sal ammo- niac, to very numerous and diversified trials of the same kind, but never could obtain in similar circumstances, any satisfac- tory product of water. Nor can I imagine on what principle this profound and ingenious chemist should have expected to obtain water from such sal ammoniac, by the agency of heat, or of heated charcoal. The water present in muriatic acid gas, by the old theory, which he espoused, is evidently combined, not hygrometric water ; and ammoniacal gas certainly contains none of that liquid. Mains when the two dried gases unite to form a solid salt, their whole ponderable matter is condensed or fixed in it ; and whatever existed in both these components, has become a permanent and essential constituent of the com- pound. One hundred cubic inches of muriatic acid gas, weigh- ing 38.04 gr., unite to 100 cubic inches of ammoniacal gas, weighing 18.17 gr. ; together affording exactly 56.21 gr. of sal ammoniac. ‘ Now, whatever water existed in the acid gas, is indissolubly attached to the very existence of the salt, and will always sub- lime along with it, when heat is applied. Nay, though by a. very intense heat, we resolve the solid into its ultimate ele- mentary constituents, we shall recover nothing but hydrogen, azote, and muriatic acid gases, each as hygrometrically dry as before. It would, indeed, to my apprehension, be as reason- able to hope, to extract, by the agency of heat, the combined water of concentrated oil of vitriol. We shall only vaporize or distil; the water rising infallibly with the oxygen and sul- phur ; as it rises with the sal ammoniac, being essential to its first formation, and future existence. In both these instances, it is solely by fixing the acid with a base, in some salt, which x2 requires 348 ‘EXPERIMENTS ON THE RELATION requires no water of composition, that we can ever expect to obtain the combined or latent water of sulphuric acid, or of muriate of ammonia. By this general principle, all my efforts have been directed. I shall now endeavour to demonstrate, by particular experi- ments, the accuracy of these views. 1, Sal ammoniac was put down to the sealed end of a glass- tube; ‘over it was placed a few inches of river sand, which, af- ter having been digested with muriatic acid, had been well edulcorated with water, and ignited, in a platina crucible. On passing the vapour of the salt, through the ignited sand, liquid of a reddish-brown colour was copiously condensed in the pro- jecting and cool part of the tube. This liquid was acidulous muriate of iron. I naturally ascribed the origin of this to the red oxide of iron, still contained in the sand after the above operations. 2. To verify this idea, 1 then took ‘pounded flints, and ob- tained from the same quantity of salt, in various repetitions of the process, a very small quantity of blue liquid, which seemed to be an ammoniacal solution of copper, by its colour and smell. 3. I next had recourse to quartz nearly pure. The quanti- ty of liquid obtained in the same circumstances, was now very inconsiderable indeed ; and I conceived it might be ascribed to some interspersed particles of mica and felspar, whose alu- mina might fix a little of the dry acid, and leave water of am- monia. 4, When pure rock-crystal was employed, the aqueous pro- duct became almost evanescent. The salt sublimed through the ignited quartz powder, without any apparent decomposi- tion. 5. When 0 Eee BETWEEN MURIATIC ACID AND CHLORINE. 349 © 5. When strongly calcined charcoal was employed, I obtain- ed no traces of water at all. It will, moreover, be readily ‘granted by every chemist, that, from the equivocal nature of common charcoal, as prepared with greater or less care, and from the uncertainty of expelling the whole gaseous matter, and moisture it so greedily imbibes, no important inference can be drawn from any results in which it is concerned *. The traces of moisture which Dr ‘Murray observed in his experiments, must have been the adhering or hygrometric wa- ‘ter‘of the sal ammoniac. He has indeed assigned some hypo- thetical reasons, why sal ammoniac owght not to attract mois- ture from the air. I shall confront them with the results of experiments * If mere heat can separate the combined water of sal ammoniac, then the salt, which, after passing through ignited quartz, has concreted on the verge of ignition, being nearly anhydrous, will, in an equal weight, contain more acid than before transmission. It will in fact bear the same relation to common sal ammoniac, that ignited sulphate of soda does to the crystallised salt. Having transmitted, in the state of vapour, the salt condensed from the dry gases, through ignited quartz, I took 10 gr. of the cake, consolidated just beyond: the quartz ; and dissolving them in water, decomposed by nitrate of silver, when I obtained 27 gr- of dry muriate of silver, being the quantity precisely equivalent to 10 gr. of ordinary muriate of ammonia. (See Wott. Scale of Chem. Equiv.) Hence it is evident, that ignited sal ammoniac has undergone no change in its constitution. There was obtained one-tenth of a grain of liquid in that experi- ment, in which 20 gr. of salt had been passed through the quartz; but this, though colourless rock-crystal, betrayed the presence of iron in its composition. For, the liquid stained the paper on which it was withdrawn, of a yellow colour; and the sublimed salt had, faintly, the same hue. ‘The resulting muriate of sil- ver partook, a little, of the brown tinge, of peroxide of iron. I therefore ascrib- ed the produetion of liquid to the action of the oxide of iron on the bydepgen of. the ammonia, $50 EXPERIMENTS ON THE RELATION experiments very carefully conducted ; and we shall find, that though this salt, is not, perhaps in strict chemical language, deliquescent, yet it is capable of absorbing or attracting from the atmosphere a very notable portion of water. This, how- ever, may be totally expelled, by keeping the salt for a short time in a temperature of from 200° to 300° of Fahrenheit, when it resumes exactly its pristine weight. Pulverised sal ammoniac was desiccated in a platina capsule, at a heat somewhat below that of its sublimation. It was then found to weigh 49 gr. I placed the capsule on a shelf in my apartment. On re-weighing it, at the end of two days, the salt was found to have become heavier by 3.1 gr.; which amounts to more than six parts in the hundred. Sal ammo- niac from gaseous combination exhibits the same phenome- non; and probably, from the extreme comminution of the powder, to a still greater degree. It even becomes pasty. The quantity of this adhering or hygrometric water, will vary no doubt with the weather or climate, as is the case with muriate of soda *. It may be said, Since our sole object in decomposing sal am- moniac, by metallic lamina, is to obtain from its acid consti- tuent the water which it is supposed intimately to contain, and to carry into that salt ; why not employ directly dry muriatic acid gas, in such researches? My only answer is, that in de- siccated sal ammoniac, we conveniently find the acid in a state hygrometrically * In clear frosty weather, or in a very dry apartment, where muriate of lime would crystallise, the ammoniacal salt acquires weight very slowly. Fifty grains of that from gaseous combination, just heated in a platina capsule, to near its subliming temperature, being put into the scale of a sensible balance, became heavier by half a grain in two minutes ; after which, in the above circumstances, no further absorption of moisture was perceptible for an hour. The experiments detailed in the text were made, when the air was considerably loaded with mois- ture. wae: - BETWEEN MURIATIC ACID AND CHLORINE. 351 hygrometrically dry. Unwilling, however, to shelter myself behind such an apology, I have thrice made the experiment with this acid gas, and have obtained each time a most satis- factory result. Pure iron turnings were introduced into a green glass tube about 4 feet long; and they were made to occupy about 6 _ Inches of it, near one end. To this was luted, the tube of com- munication with the mercurial trough. The part containing the turnings, rested on the semicylinder of iron, within the fur- nace. To the other end, which was about 3 feet from the furnace, the beak of a tubulated retort was luted. Into this, which con- tained dry muriate of soda, and which was furnished with a sy- phon-tube of safety, concentrated sulphuric acid was slowly drop- ped. ‘The projecting green glass tube, with the neck of the re- tort, altogether about four feet long, were surrounded with pa- per kept moist with ether, as was also the tube of communica- tion, on the other side, with its bulb. As soon as I found that the gas escaping in the pneumatic trough was muriatic acid, free from admixture with common air, the charcoal furnace was kindled. The heat being gradually raised to bright igni- tion, whilst the acid gas was slowly disengaged, in the cold retort, I found at the end of a short period, that liquid was condensing i in the bulb, though no traces of moisture ever ap- peared within the long tube, between the retort and the fur- nace. The moisture seta 2 in a very slow, but regular pro- gression. At the end of three hours the quantity had become considerable. In one case, it amounted to nearly 6 grains. It was liquid muriatic acid. During the whole process, hydrogen and muriatic acid gases escaped through. the mercury, in the proportion, by volume, of 13 of the former to 1 of the latter. This acid gas, as it issues hot from the furnace, i is very apt to take up the deposited moisture, unless we screen the tube from 352 "XPERIMENTS ON THE RELATION from the fire, and attend diligently to the application of the ether. Dry muriatic acid gas, and common air, do not affect iron in the cold, at least during a period equal to their joint application in the present case, as [have found by experiment ina graduated glass-tube over quicksilver ; and as the whole atmo- spheric air was expelled, before the application of heat, the ef- fect is solely due to the acid gas, as, indeed, its progressive in- crease, with the duration of the process, sufficiently attest. The oxygen of the atmosphere could have no influence on the result *. ' There was found within the tube, near the end farthest from the retort, on the verge of the ignited part, a white pulverulent matter, glistening like snow, and the adjoining laminz of iron, were encrusted with the same substance, in spangling crystal- . line plates. This powder dissolves readily in water. Into recently boil- ed water, when a little of it was put, and a small fragment of crystallised prussiate of potash was added, a greyish cloud ap- peared, speedily becoming blue. Tincture of galls dropped into a similar solution, gave the characteristic purple tinge of iron. Thirteen parts of it by weight, being ignited in a small platina tray, evolved copiously a dark-brown smoke, smelling of muriatic acid, and left 6 parts, which were red oxide of iron. But 13 of green muriate, by Dr Wot.asron’s scale, are equiva- lent to 8 of red oxide. Does the above muriate contain the atomic * M. Gay Lussac, in his Recherches Physico-chimiques, describes a similar experiment, but without the production of water. If the utmost precautions be not taken, to keep the condensing tube at a very low temperature, the expanded and heated acid gas will readily carry off the moisture, as I found in one experi- ment. The neglect of these precautions will account for the difference of M. Gay Lussac’s result. BETWEEN MURIATIC ACID AND CHLORINE. 3538 atomic protoxide of iron, hitherto unknown? This question must be answered by future researches. I tried to determine the proportion of muriatic acid in the above muriate of iron, by nitrate of silver. The quantity on which I operated was, however, too small to permit me, to place much confidence in the result. But one circumstance arrested my attention. A portion of revived silver was found at the bottom of the glass capsule, on pouring off the prep tated muriate. On the general principle of research, above stated, the pro- duct of water or liquid, will be proportionate to the quantity of muriatic acid gas, condensed into muriate of iron. Hence, to obtain large results, it is proper to have a considerable por- tion of iron laminze, placed just at, or a little beyond, the limit of ignition. _ From the whole of the preceding experiments, we may legi- timately conclude, that muriatic acid gas hygrometrically dry, contains much combined water. And since that gas results from the union of chlorine and hydrogen in equal volumes, each likewise hygrometrically dry, the above water must be formed in consequence of the hydrogen finding oxygen in the chlorine, for its saturation. Chlorine is therefore Sara tic, or Oxygenated muriatic acid. My experimental examination of iodine, has further led me to conclude, that this curious substance is not entitled to rank in the same class. with chlorine, but with sulphur. The details. will form the subject of a separate memoir. Vou. VIII, P. II. Yy XVIII. . hee " : dus wil a ot i yak): gearst. + i ¥ Jogurt \ ea | aedbweida be ps ye au | ‘ a . > +n iq’? - : »> § ‘ : c . , | : fe tf beget 5 2 F F oan : we . Ly Qu ; tnd ’ sd , 3 % ‘ - Pon ‘a fF naa 2 “ i ‘ ! i : ttt F r ° : a | : ba ’ names. Sites : $ Y : a ss 7 Ni ; ‘ f t i j ‘ ni 4 J ' ‘ . ; 8) ‘ ane he XVIII. On the Laws which regulate the Distribution of the Polarising Force in Plates, Tubes, and Cylinders of Glass, that have received the Polarising Structure. By Davin Brewster, LL. D. F. B.S. Lonp, & Eni. ( Read June 17. 1816.) I. the Philosophical Transactions for 1816, I have described at great length the various. phenomena which are exhibited by glass and other substances to which the property of double re- fraction has been communicated by heat, by rapid cooling, by evaporation, or by mechanical compression and dilatation. In pursuing the same subject, I have observed many singular facts respecting the developement of new axes, by a:change in the form and condition of the plates; and by submitting the phe- nomena to accurate measurement,. I have succeeded in deter- mining the laws which regulate the distribution of the polari- ‘sing force. A brief account of these results will form the sub- ject of the following paper.. 1. On Plates of Glass with One Axis of Polarisation: If we take a plate of glass perfectly circular, and communi- cate to it the polarising structure, either transiently, by the transmission of heat from its circumference to its centre, or permanently, by cooling it rapidly, when it has been made red hot, we shall find that it will exhibit, when exposed to pola- rised light, a system of rings traversed by a black rectangular cross. This system of rings is precisely the same, both in ap- pearance and in the character of its tints, as the system seen : yA a along 354 ON THE DISTRIBUTION OF THE POLARISING FORCE along the axis of Ice, Quartz, &c. and other crystals of the po- sitive class. If the circular plate of glass, on the contrary, receive the po- larising structure transiently, by heating it uniformly in boil- ing oil, and allowing it to cool rapidly, it will exhibit a similar system of rings ; but this system has a negative polarisation, like the rings formed by Calcareous spar, Beryl, &c. and other crystals of the negative class. This opposition in the character of the two plates may be finely observed, by combining them together. ‘The resulting system of rings, when two positive or two negative plates are combined, will be the same as that which would have been produced by a plate equal to the sum of their thicknesses ; but when the one is positive, and the other negative, the resulting system will be that which would be produced by a plate equal to the differ- ence of their thicknesses. Hence, when the negative system is exactly equal to the positive system, they will destroy each others effects, and the compound plate will have no action whatever upon polarised light. By comparing the value of the tints with their distances from the centre of the plate, I have found, that they vary as the © squares of their distances from the axis. Hence if T is the tint which corresponds to any distance D, the tint ¢ correspon- ding to any other distance d, will be found by the formula “Te wt 2. On Plates of Glass with Two Aves of Polarisation. When a plate of glass deviates from the circular form, and is either elliptical or rectangular, it has two axes of polarisation, one of which is perpendicular to the plane of the plate, and the other at right angles to it, and lying in the plane of the plate. When the plate has received the polarising structure transiently, by the transmission of heat, or permanently, by being IN PLATES, TUBES, AND CYLINDERS OF GLASS. 355 being cooled rapidly from a red-heat, the axis perpendicular to the plane of the plate (which is always the principal axis), is positive ; but when the polarising structure is communicated by heating the plate in boiling oil, and then cooling it rapidly, the principal axis is negative. By measuring carefully the distances of the tints from the centre of the plate, I have found the following formula, dedu- ced from the supposition of two axes, perfectly correct, viz. t= Toa » where D is the distance of either of the black fringes or Jines of no polarisation from the centre of the plate. The term Se represents the influence of the principal axis, and would have given us the tint ¢ if that axis had existed alone. But as the axis in the plane of the plate produces an uniform tint T in every part of the plate, which acts in oppo- sition to the other tint; the tint ¢ must be equal to the differ- 2 ence of these tints, or to T— age In examining the relative intensities of the two axes in rec- tangular plates of considerable length, and in elliptical plates, in which the conjugate axis is very small when compared with the transverse axis, I have found that D, or half the distance between the black fringes, is a function of the breadth of the plate, that is, if B is the breadth of the plate 2D: B= 10: 16.02, and D=.312B*. As the excentricity of the elliptical plate diminishes, the value of D diminishes, or the polarising force of the axis in the plane of the plate diminishes ; and when the conjugate and transverse axes are equal, D is equal to 0, or the axis in the plane of the plate is destroyed. In elliptical plates, the black fringes which are seen when the transverse axis is inclined 45° to the plane of primitive polarisation, are convex towards the transverse axis, and their curvature is such, that they 356 ON THE DISTRIBUTION OF THE POLARISING FORCE they cut perpendicularly every similar ellipse drawn within the: plate. Hence, when the ellipse is nearly a circle, the distance of the fringes will be almost nothing, and each of the fringes will form two straight lines at right angles to one another, as in elliptical plates, when the transverse or the conjugate axis is in the plane of primitive polarisation. The lines of equal tint at the angles of rectangular plates of glass, are highly deserving of attention. They are produced. by the external fringes, and the maximum tint at the angles is always less than at the edges, and generally higher than the maximum tint in the middle of the plate. When the external fringes are two in number, viz. ab, ab’, de, d’e’, as shown in Plate VII. Fig. 1. ; the outermost, ab, a’b’, terminates at c¢, e, and the other, de, d’e’, branches off at e, e’, so as to form | the ellipsis efe’e. The tint increases from this elliptical line to its centre 0, but decreases from o to p, and from o to q. When the glass plate is a perfect square, the curve efe’e is a circle *. In a plate whose maximum tint, in the middle, was a Blue of the 2d order ; the tint at o was a Pink of the 2d order ; and that at p and g a White of the 1st order. 3. On the Lines of Equal Tint formed by the Transverse _ Combination of Plates of Glass. In the Philosophical Transactions for 1816, I have repre- sented the Jsochromatic lines, or lines of equal tint, form- ed by the transverse combination of plates of glass, when the principal axes are both negative, or both positive + ; when the principal axis in one is negative, and in the other positive |; when the two plates receive their structure by bending || ; and when a bent plate is combined with a plate formed by heat §. In these various cases, the lines of equal tint ee SS ane. = San La ee * See Phil. Trans. 1916, Plate IV. fig. 29. + Id..Plate II. fig. 3, 4. + Id. Plate If. fig. 8. || Td. Plate IX. fig. 9. § Id. Plate IX. fig. 10. PLATE VI. Engraved bor the Royal Scotety Tran. Vol. Vill Page 356. | ee Engraved. by Wik D.Lizars E dint ¢ % IN PLATES, TUBES, AND CYLINDERS OF GLASS. 357 tint will be found to be Hyperbolas, Circles, Ellipses, Straight Lines and Parabolas. Let us now suppose, T T’= the maximum tints of the two plates. B B’= the breadths of the plates. x =the distance from the centre of the plate of any. point where the resulting tint is required. y = the distance of the same point from the centre of the other plate. t ¢ = the tint produced by each plate separately at the distances « and y, and ¢ = the resulting tint. . Then, substituting .312 B instead of its equal D, we have : Tax 2 q’ 2 i Pe al fue dy eet 312 Be?“ 312 B®’ But, since the Bie eye tint + arising from the combination is equal to the difference of the two tints, we have Pgh Lig* 312 B2 + —— 312 312 B® 9 and me yh ws =") T .312 B? x’ sige ak (= TT" 312 Be z— T’—T— Consequently, the lines of equal tint are Hyperbolas. When feed yl and.B = B, the Sik ae are equilateral, and of = .312 B? +a%. When a plate whose Same axis is negative, is crossed with a plate whose principal axis is positive *, the resulting tint * Phil. Trans. 1816, vol. II. fig. 8. 358 ON THE DISTRIBUTION OF THE POLARISING FORCE tint will be the sum of the ee tints. Hence, in this case we have urate Ulam 3128? 312 B? V+T—- Tots Be oo ve — y? = .312B TY ) “7-319 BE * The lines of equal tint will therefore be El/ipses, as shewn in Plate VIL. Fig.2. when either the maximum tints, or the breadths. of the combined plates are not equal. But, when T = T’ and B = By, we have —-T+T — , and ye =.312 B? (2 eet —a", Consequently, the lines are in this ease Circles, as shewn in Phil. Trans. 1816, Plate IT. Fig. 8. When the two combined plates receive their structure by bending, the tints do not vary, as the squares of their distances. from the centre, but simply as their distances. Hence, T being the maximum tint at the edge of the plate, and B B’ the breadths of the plate as formerly, we have = :Toa:t; and Pp a :T’=y:t, which give c= a and ’ = ay. Consequently, a 2Te + 2Ty LS +r a » and Be TR I= oP — TR | Hence, the lines of equal tint will be Straight lines. The i IN PLATES, TUBES, AND CYLINDERS OF GLASS. 361 . The angle ¢, which the straight lines of equal tint form with the edges of the plate, will be found by the formula, iE B Tang. sS Oi = Py When x:y=B: By, and when similar sides of the plates cross each other, we shall have += 0, that. is, the line of no- polarisation will be the diagonal of the parallelogram formed by the sides of the two plates *. When B= By’, and T =T, then Br Y= op and. the straight lines of equal tint will be inclined 45° to the edges of the plates, for - = 1, which is the tangent of 45°. When a plate of glass with two axes is combined with a plate of bent glass +, we have ay op a Bs 2 aR a) v= .312B(1— 7 + ape), when the concave side of the bent plate crosses a plate with two axes, in which the principal axis is negative ; or,, 2 2 : 2 1 Ae Gio: |, aie Be OO 2— 312 B a _ 2Ty Po we Ge ee, when the convex side of the bent plate crosses a plate with two axes, in which the principal axis is positive, and vice versa. Hence, it follows, that the lines of equal tint are here Parabolas. Vou. VIII. P. IT. ZZ When * See Phil. T'rans. 1816, Plate IX. fig. 9. + Id. Plate IX. Fig. 10. 362 ON THE DISTRIBUTION OF THE POLAR!SING FORCE When T = T’ the line of no-polarisation is a complete para- bola, passing through the angles of the parallelogram, and ha- ving its vertex at the very edge of the bent plate. The curves within it will also be complete parabolas, but all those without it will be only parabolic segments. 4. On the Distribution of the Polarising Force in Tubes and Cylinders of Glass. We have already seen, that circular plates, or cylinders of glass, have one negative axis, like Quartz ; but when the cylin- der has the form of a tube, like AB, Plate VII. Fig. 3. the pola- rising force is distributed in a very remarkable manner. A black circular fringe mp no forms the line of no-polarisation, and the coloured fringes are placed on each side of this dark ring, and concentric with it. The structure on the outside of mp no is negative like Calcareous spar ; and the structure on the ‘inside positive, like Quartz, &c.; and the effect is exactly the same as if a plate of glass had been bent into a circular form, and kept in that position by force. The breadth of the positive annulus ao is always less than that of the negative annulus Ao, the former decreasing, and the latter increasing, as the bore of the tube diminishes ; and when the bore becomes extremely small, as in Fig. 4. the posi- tive structure is also extremely small, and sometimes can scarcely be seen without the aid of a microscope. In comparing the values of the tints with their distances from the line m pn o, I have found that they vary as the distan- ces, in the same manner as in bent glass. Hence it is obvious, that the glass is in a state of compression within the black ring mpno, and in a state of dilatation without that ring, and that the particles are held in a state of violent constraint, en- tirely different from that position of equilibrium in which they are placed in plates of glass with one or two axes. With IN PLATES, TUBES, AND CYLINDERS OF GLASS. 363 With the view of confirming these results, I took a file with a very sharp edge, and cut the tube entirely through by a notch EF, Fig. 5. By this operation the particles were freed from the state of violence in which they were held, and assumed the very same arrangement which they never fail to take in rectangular plates of glass. By exposing the tube, thus divi- ded, to polarised light, it exhibited the appearance shewn in Fig. 5. where mp no, m’p’n’o’, are two dark fringes having a negative structure on the outer side of each, and a positive structure between them, as in plates of glass with two axes. I obtained the same result with a tube of a very large bore, ha- ving its exterior diameter 0.875 of an inch, and its interior dia- meter 0.816 ; so that the thickness of the glass was only 0.059 of an inch. When the tube is cut into two or more pieces, each piece has the same structure as a plate of glass with two axes. By a number of measurements, I have found that the diameter op, Fig. 3. of the black fringe or circle of no-polarisation, is a geometrical mean between the interior and exterior diame- ters of the tube, that is, op = »/ AB xab, If a tube of glass is brought to a red heat, and then cool- ed by inserting in its bore a cylinder of iron, or any other conducting body, the structure will then be the same as is re- presented in Fig. 5. If a solid cylinder of glass which has only one structure, is - perforated in its centre, it will exhibit the appearance in Fig. 3., and if it is divided by a notch, it will acquire the structure shewn in Fig. 5. When polarised light is transmitted through a Jong cylinder of unannealed glass, in a line perpendicular to its axis, after it is immersed in a fluid of the same refractive power, it exhi- bits the same phenomena as rectangular plates of glass, having a positive axis perpendicular to its length, and a negative axis perpendicular to the positive one; but in the cylinder, the ex- Zz 2 ternal 364 ON THE DISTRIBUTION OF THE POLARISING FORCE ternal tints do not rise so high, from the diminution in the thickness of the glass. The same phenomena are exhibited by a glass-tube AD, Fig. 6. similarly placed. In this case, however, the maximum tint does not appear along the line mm, the axis of the tube; but it is seen both in the lines 6d and dd, equidistant from mm. This effect is obviously occasioned by the greater thick- ness of the glass in these directions ; for a and cd are each greater than Ao-+pm, and the difference is sufficiently great to overbalance the diminution of the tints at a greater distance from the principal axis. In examining very carefully the structure of glass tubes, when exposed to polarised light, it will be found that they are as it were divided into different elementary concentric tubes ; and that in some cases there is an actual separation between them. Hence, there arises a remarkable singularity in the progression of the tints. Instead of shading into one another by imperceptible gradations, each elementary tube has an uni- form tint of its own, as is represented in Fig. 7. where the tube AB is divided into four tubes 1,1; 2,2; 3,3; 4,4; the tube 4,4 is in every part of it a white of the first order ; the tube 3,3 is every where equally dark, being the black cir- cular fringe mpno of Fig. 3.; the tubes 2,2 and 4,4 are a white of the first order; and the tube 1,1 is a yellow of the first order. Hence it follows, that in tubes which possess this peculiarity of structure, each elementary tube is uniformly dense throughout, and that the variation of density takes place by leaps. If a portion of a glass tube perfectly annealed, is exposed to pressure, it exhibits the tints shown in Fig. 8. when the line mn, joining the points of pressure, is parallel or perpendicular to the plane of primitive polarisation ; and the tints shown in Fig. 9. when the same line is inclined 45°to that plane. 5, On —— Or IN PLATES, TUBES, AND CYLINDERS OF GLASS. 365 5. On the Conversion of Plates of Glass with One Axis into Plates with Two Axes. From the different experiments which I have described, both in this and in other papers, it appears, that in almost every case where polarising forces are developed, two negative structures are separated by a positive structure, or two positive structures by a negative structure, both of which are simulta- neously produced, like the two opposite polarities in electrici- ty and magnetism. When the two structures are disposed in a different manner, or when only one structure is developed, the regular arrangement of the polarising forces may be effec- ted by a slight change in the form or in the mechanical condi- tion of the plate. If we take a piece of unannealed glass perfectly circular, we have only one axis, or one structure, as shewn in Fig. 10., where AB, CD is the black cross, which preserves the same appearance by turning the plate round its centre. But if we grind the smallest quantity from any two opposite sides CB, AD, so as to induce a slight degree of ellipticity, a new axis is created; the tint which it produces appears at the centre of the plate, and the system of rings has the form shewn in Fig. 8., where the inter- nal structure within the black fringes AD, CB, is negative, and the two external structures without AD, CB, positive. If, on the contrary, we now grind a small quantity from the sides AC, BD, so as to reconvert the elliptical plate into a circular plate, we shall find that the new axis which was gene- rated by the change of form, has entirely disappeared, so that the plate exhibits the figure shewn in Fig. 10. This singular experiment, in which one of the axes may be extinguished and revived at pleasure, is worthy of the most attentive 66 ON THE DISTRIBUTION OF THE POLARISING FORCE ts attentive consideration. If the polarising forces depend solely on the mechanical condition of the particles of the glass, then it necessarily follows, that the central parts of the glass, which were in a state of variable expansion when it had a circular shape, are in a state of variable compression when the glass has received an elliptical form, and we are presented with a new law relative to the equilibrium of the cohesive forces in solids of variable density. But if the variation of density is merely the means of developing a new agent in the same manner as heat excites electricity in the tourmaline, or as pressure excites it in calcareous spar, then we cannot avoid regarding this agent in the same light as the electrical and magnetical fluid which are decomposed by certain mechanical operations, and distri- bute themselves according to regular laws. But whatever be the origin of the polarising forces, it be- comes a matter of great importance to discover the law of their distribution, when they are not controuled by opposite actions, and to apply this law to the explanation of the phenomena which they develope when they are either modified or extin- guished by the external form of the body in which they re- side. Those who have studied the papers to which I have already referred, cannot have failed to remark, that when the polari- sing forces are unconstrained in their developement, a negative structure is generated in the middle of the plate, when a posi- tive structure is generated at one or both of its edges ; and that the intensity of the negative, is to the intensity of either of the positive structures, as 10 to 16.02. In order to apply this principle to a circular plate, let KLHFG, Tig. 12. be a plate of this description, whose centre is O. Then if this plate were a part of the rectangular plate ABDC, mn, op would be the lines of no-polarisation which separate the internal negative IN PLATES, TUBES, AND CYLINDERS OF GLASS. 367 negative structure from the two external positive structures. The tint at a, or any part of the line bc, would be Te —— 32 BE but if the circular plate were part of a plate si- milar to, and at right angles to ABCD, the tint at a, or any part of the line EOF, would be equal to T; and as this tint is ‘rectangular to the other tint at a, the resulting tint will be equal to the difference of these tints, or to ete Td ae | ee ada Beale He In like manner, it may be shewn, that in every point of the 2 circular plate, the tint is represented by ae which is the experimental expression for it already found. In plates, therefore, that have only a positive structure, the negative structure still exists, but is overpowered by opposite ac- tions. We are now prepared to understand how the negative struc- ture re-appears, as shewn in Fig. 11., by giving an elliptical form - to the plate. For, the maximum negative tint produced at O, in the direction gh, is no longer counterbalanced by the tint in the direction ef; and therefore the difference of these tints appears at O, with a negative character. As the points e, f re- move from O, oras the ellipticity increases, the tint at O gradual- ly rises till it becomes equal to T, or a times the tint at g, when the action of the edges at e and f has no longer any influence at O. The very same results are obtained by the conversion of a sphere into a spheroid, and they are explicable upon the same principles. The ’ 368 ON THE DISTRIBUTION OF THE POLARISING FORCE The distribution of the polarising force at the angles of square or rectangular plates, characterises. a very remarkable state of equilibrium among the cohesive forces ;. and this state of equilibrium is not am accidental result of the mode in which the heat either enters or leaves the angles of the glass plate, for the very same distribution takes place when a new angle is formed, by cutting the plate into two parts.*. In all these eases, the lines of equal tint are the lines of equal density. As the two kinds of polarising forces seem to be co-existent in every part of a glass plate, and as each of them, when it ap- pears to exist alone, is merely the resultant of two opposite forces, it is easy to assign a reason for the singular phenome- na which are exhibited, by dividing a plate of glass into two parts. The two forces which reside in every part of the glass cannot be in equilibrio, unless a negative structure is placed between two positive structures ; and therefore each half of the elass plate, or each portion of it of the same shape as the whole plate, must acquire the same property as ‘the plate itself, or have the forces distributed in the same manner. This view of the distribution of the polarising forces is analogous to Cov- romx’s theory of the construction of the magnet. Every ele- mentary portion of the magnet has a north and south pole, and therefore wherever it is broken, the fragment must have a north and south pole, like the magnet of which it formed a. part. 6. On, * See Phil. Trans. 1816, p. 82. IN PLATES, TUBES, AND CYLINDERS OF GLASS. 369 4 6. On the Intensity and Distribution of the Polarising Force in Plates of Bent Glass. . In order to ascertain the intensity of the polarising force, as produced by different degrees of flexure, I placed together two similar plates A B, C D, Fig. 13, and separated their extremi- ties by two pieces of glass A C, B D, of equal thickness. After pressing them into contact at M and N, I observed the maxi- mum tints which they exhibited at these points, as given in the following Table. Length of Plates, Distance of Extre- Thickness of Breadth of the Maximum or AB. mities, or A C. the Glass. Plate. Tint. 16 inches 0.16 0.133. 0.35 4 13 0.16 0.133 0.35 9 12 0.048 0.207 0:967 10.6 6 0.054 0.133. . 0.35 10.5 With the view of ascertaining the tints which they yielded be- fore they broke, I took plates, whose thickness was 0.1383 of an inch, and breadth 0.33. One of these broke when the tint was 10.4, another when the tint was 12, and a third when it had reached 13.55. In the phenomena of bent glass, the polarising force is distributed in such a manner, that the lines of equal tint are the lines of equal compression or dilatation, and the tint at the edge is every where inversely proportional to the radius of cur- vature. In order to compare the effects produced by the application of the same force to plates of. different thicknesses, I placed them as in Fig.13. The thickness of A B was 133, and its tint 3.4. Vox. VIII. P, Il. 3A ...- The 370 ON THE DISTRIBUTION OF THE POLARISING FORCE The thickness of CD was .230, and its tint 10.2. But 133? : 230? = 3.4:10:2; so that the tints and the elasticities were, in this case, inversely as the squares of the thicknesses. ‘The preceding experiment furnishes us with the principle of anew instrument, which may be called a Teinometer, for ascer- taining the elasticities of bodies. The-tints of AB and CD are obviously measures of the elasticities of the two plates ; so that the elasticities of plates of glass of different dimensions, or form- ed of different materials, may be readily determined. The power of the instrument however, is not limited to glass; for, by using a glass plate AB as a standard, the other plate CD may be a plate of metal, or any other opaque substance, whose elas- ticity it is required to ascertain. The tint of AB, when op- posed by a plate of equal elasticity, is known by experiment ; and therefore, the tint which it affords, when opposed by a si- milar plate, of a substance possessing a‘greater or a less elasti- city than itself, is a measure of this elasticity. Although I ‘consider the variation of the-tint as an excellent means of de- termining the degree of curvature, yet the principle o exhibiting ‘ the relative elasticities of two plates, by the application of the same force, may be employed in an instrument entirely me- chanical, in which the sagitta of the inflected plate is actually measured, as in the ingenious machine invented by S’Gravzs- ANDE. The chromatic Teinometer is represented in Figs. 14, 15. and 16. where AB is the standard plate, of well annealed glass, having its edges highly polished. Along this plate, there are moved two brass pieces, Sabc, S'a' b'c’, which-can be fixed in any position, by means of the screws S,S. The plate CD, where elasticity is to be measured, rests with its lower edge upon the projection bc, Fig. 15. and with one of its faces against ab. It is then pressed into contact with the plate AB, and IN PLATES, TUBES, AND CYLINDERS OF GLASS. 371 and kept in this position by the wooden holdfast H; the brass: pieces Sac, S’a'b'c’, having been previously placed at such a distance from each other, that the two plates will meet at H, without breaking, or without any permanent change of form. . The apparatus ER, for observing the tint, is shewn sepa-_ rately in Fig..16. It consists of an eye-piece E, to which is at-- tached a reflector R, made of several plates of the thinnest. glass, about 14 long and an inch broad, and placed close to each other. The eye-piece E consists of two tubes, one of which is moveable within. the other. The moveable tube contains an achromatic prism, mn, of calcareous-spar, with a convex lens, op, about an inch in focal length, placed either above or below it. When.this apparatus is set upon the edge of AB, by means of the forked arms e, f; the reflector R is turned round, till the plane of reflection is cut at an-angle of 45°, by the plane of the plate AB, and is placed at such an.angle, that the light which it reflects through the edge of the plate AB, and up the tube, is completely polarised. The moveable tube is then turned round, till the tints appear on the edge of one of the images of the glass plate. In order to avoid the confusion arising from two images, the achromatic prism may be constructed in such a. manner that only one of the images is visible. 3A 2 XIX OD TEI Da ES ee EEE XIX, Remarks, illustrative of the Scope and Influence of the Philosophical Writings of Lord Bacon. By Macvey Napier, Esq, F. R. S. Lond. & Edin. and F. A. 8. Edin. (Read February 16. 1818.) Tur obligations of Experimental Physics to the labours of Lord Bacon, have been largely acknowledged by the genera- lity of those who have treated of the History of Modern Sci- ence; insomuch, that the title of Father of Experimental Philosophy has been oftener conferred upon him than upon any other of its benefactors. There are some, however, who seem to think, that there is no good ground for honouring him with this title, either on account of the merits or the effects of his writings. They do not indeed deny, that his views as to the proper objects and method of philosophizing were exten- sive and just ; but they contend, that he had no peculiar merit in having stated these views; that all that he taught was vir- tually and more effectually taught by the discoveries of some of his contemporaries ; and that, in fact, there are no traces of his agency to be found in the discoveries that followed *. These opinions, though they are to be met with in respect- able “#¢¢ Atqui Veruamuus ille, qui Germanz Philosophie Restitutor, quin etiam, si Superis placet, Parens a Bruxero aliisque habetur, quid aliud in Anglia presti- tit, 374 - ON THE SCOPE AND INFLUENCE OF THE able books, and in the conversation of intelligent men, seem to involve no small portion both of error and misconcep- tion. It cannot be denied, indeed, that at the time when Bacon wrote, there was a growing tendency to abandon the ancient systems, and that some successful essays had been made in that course of inquiry which he recommended ; but, on the other hand, it appears to me equally clear, that his labours for the advancement of Science were of such peculiar importance, and attended with such extensive effects, as to entitle him to a pre-eminent station among its early reformers and promoters. It is the object of this paper to offer some remarks, and to collect some proofs, in support of these views; but, as much has been already written in illustration of the merits, and but little in illustration of the effects produced by his philosophical writings, I shall content myself, at present, with a slight indi- cation of their general scope, and shall devote the greater part of my paper to the proofs of their influence. Upon the latter point, indeed, there seems to exist more of doubt and of mis- apprehension than upon any other connected with his philo- sophy*. In tit, nisi, ut, qua ratione philosophari deberemus, eo tempore admoneret, quo Ga- ritzus eadem ipsa ratione philosophari jam in Italia coeperat, ac ceteris, ut idem facerent, non modo verbis, verum et rebus ipsis gravissimus auctor esset ?°—Fa- sroni, Vite Italorum doctrina excellentium qui secults xvii. et xvili. floruerunt, vol. i. p- 223. ——“ C’est Gauiter,” says a French Philosopher of the present day, “* quia montré Vart de V’interroger par ’expérience. Ona souvent attribué cette gloirea Bacon; mais ceux qui lui en font honneur, ont été (a notre avis) un peu pro- digues d’un bien qu'il ne leur appartenait peut-étre pas de dispenser.” —Biogra- phie Universelle, Tom. xvi. p. 329, Art. Gauiteo; written by M. Brot. * There cannot be a stronger proof of the misapprehensions alluded to, than what is furnished in the following passage,’of the interesting article above mentioned. SS Eee sy (ae Vo | ne Lay PHILOSOPHICAL WRITINGS OF LORD BACON. 375 In order to clear the way for this inquiry, I shall begin with a few remarks-on a late estimate of Bacon’s Philosophy, evi- dently intended, not merely to depreciate, but to vilify it ; in- somuch, that it stands remarkably at variance with almost all that has been hitherto published on that subject. The esti- mate alluded to is the more worthy of notice, that it has ob- tained a place in a Literary Journal of great respectability, and which is supposed by many to speak the sentiments of the ' English Universities in matters of philosophy. It is pretty well known, I presume, that Bacon’s writings have been recently commented upon by two of our most eminent philosophers ; by the one, in reference to their connection with the Philosophy of the Mind *; and by the other, in reference to their more apparent object, the explaining the method by which to extend our knowledge of the Material World +. Both of them represent Bacon as the first who clearly and fully pointed out the legitimate rules and ends of philosophical in- quiry ; mentioned. ‘¢ Si Bacon a eu tant de part aux découvertes qui se sont faites aprés lui dans Jes sciences, qu’on nous montre donc un seul fait, un seul résul- tat de son invention, qui soit de quelque utilité aujourd’hui: ou, si ses prin- cipes généraux sont tellement feconds, qwils aient pu, comme on l’assure, lui faire pressentir un grand nombre de decouvertes modernes, il est présumable qu’on n’ a pas encore épuisé tout ce que contient son Livre; et dans ce cas, ceux qui disent que nous lui devons tant de choses, devraient essayer d’en tirer d’avance quelques-unes des découvertes dont la methode de Gatitez nous enrichit tous les jours.”—Biog. Universelle, in loc. cit. * See Mr Srewart’s Dissertation on the Progress of Metaphysical, Ethical, and Political Philosophy, prefixed to the Supplement to the Encyclopedia Britannica. + See Professor Prayratr’s Dissertation on the Progress of Mathematical tee Physical Science, prefixed to the same work. 876 ON THE SCOPE AND INFLUENCE OF THE quiry ; and both consider his writings as fixing a new and important era in the history of Modern Science. The obser- vations made by the former upon these points, have been exa- mined at considerable length in an able article of the Journal referred to; and the following passage contains the sum of what is there advanced in regard to the general scope and cha- racter of Bacon’s Philosophy. “ The topic on which Mr “ Srewarr chiefly dwells, while panegyrizing the Philosophy “ of Bacon, is the respect which it pays to the limits, the laws, “ and resources of the human understanding ; and this is sure- “ ly the most extraordinary topic of any which he has select- “ ed. There is scarcely a page in the Novum Organum, that “ does not furnish a contradiction to it.—So little, indeed, “ can Bacon be considered as having risen in any great de- “ gree above the age in which -he lived, with respect to his “ views as to the proper aim of philosophy, or the proper “ limits of the human understanding, that he even goes “ so far as to give us formal receipts for the making of “ gold, and performing other prodigies, which he tells us he “ judges very possible. With the exception of the disciples of “ Raymonp Lutty and Jorpano Bruno, the extravagant spe- “ culations in which Bacon wished to embark philosophy, had “ been long abandoned by sober inquirers *.” It * Quarterly Review, No. xxxiii. p. 50.—The writer of this article seems to have been anxious to find some great names to countenance what he has advanced in regard to the very inferior merits of Bacon’s philosophical writings. What his success has been in this endeavour, the following extract will shew. « IT remember, said Sir Josuva Reynoxps, that Mr Burke, speaking of Ba- eon’s Essays, said, he thought them the best of his works. Dr Jounson was of opinion, that their excellence and their value consisted in their being obser- vations of a strong mind operating upon life; and in consequence you find there a Sp ee aren * . ‘ PHILOSOPHICAL WRITINGS OF LORD BACON. 377 It is to be wished, that this writer had explained to us, to what delusion it has been owing, that so many enlightened persons have, for more than a century and a half, concurred in extolling Bacon, for his endeavours to withdraw philoso- phy from “ extravagant speculation,’ and to give it a di- rection and a method, calculated to improve the condition, as well as the knowledge, of mankind. Have they all been in error, and must Bacon be branded with the imputation of ignorance of the business of philosophy, and the limits of the understanding, merely because he has speculated upon the possibility of making gold? Is this circumstance enough to establish an affinity between the general aims of his philo- sophy and the extravagant pursuits of the Alchymists? A very few words will suffice upon this point. Wor. ViIlb-P. 11. 3B There there what you seldom find in other works.”"—Account of Sir Josuua Rey- wotps, prefixed to Marowe’s edition of his Discourses. “ We are glad,” the Reviewer adds, “‘ to be able to defend our opinions con- cerning the inferior merits of Bacon’s philosophical writings, compared with his other works, from the charge of singularity or presumption, by eet our- selves under the authority of such names as Burke and Jounson.” It is very observable, that, so far as Dr Jonnson’s authority is concerned, he does not appear, in the conversation referred to, to have made any compa- rison whatever between Bacon’s Essays and his other works: he only made a re- mark descriptive of the Essays, in which every one who has perused them will rea- dily concur ; and besides, the Reviewer ought to have known, that Jounson has, in one of his papers in the Adventurer, represented Bacon as the only Modern worthy of being compared, in a philosophical point of view, with Newron ; thereby showing, that he must have held the philosophical works of the former in the highest possible degree of estimation. Great as the excellence of the Essays undoubtedly is, it is difficult to believe, that such a man as Burke could deliberately rate them as of higher merit than the De Augmentis Scientiarum and Novum Organum. There is need of some better evidence, surely, that he had formed a deliberate opinion to that effect, than what is furnished by the scrap of conversation which forms the Reviewer's only document of proof. 378 . ON THE SCOPE AND INFLUENCE OF THE There can be no doubt, that Bacon did believe in the possi- bility of discovering the means of converting other substances into gold; a belief, which was far from being so complete- ly abandoned by all “ sober inquirers,” as this writer imagines ; for it was entertained by Boyz, and some other experimen- talists, and not greatly discouraged even by Newron, at a period when experimental philosophy was much farther ad- vanced *. There was no man of his day more thoroughly ap- prised than Bacon was, of the follies of the Alchymists, or who has mentioned them in terms of stronger ridicule and reproba- tion +. He nowhere holds out the making of gold as a prime object of philosophical inquiry ; on the contrary, he point- edly censures the Alchymists, with whom he has been so ab- surdly classed, for directing their main views to such an ob- ject {. The belief which he entertained as to the possibility of making gold, had a very different foundation from that upon which it rested among this fantastical fraternity. With him, the belief in question formed part of his general belief, that the essences of all material substances were capable of be- ing discovered by the inductive process. It was a belief which flowed from his lofty notions of the yet untried resources of experimental science. There was then no sufficient stock of experience to authorise any one to lay it down as an esta- blished principle, that the knowledge of these essences is placed * There is a curious letter upon this subject from Newron to Mr Otpen- pore, Secretary of the Royal Society, printed in the account of Boyxe, in the Historical Dictionary. His remarks apply wholly to a particular process of trans- rautation, and not to the impossibility of the thing itself. See General Historical and Critical Dictionary, vol. iii. p. 558. + See Novum Organum, Lib. i. Aph. 85. 87. * Ibid. Lib. i. Aph. 70. PHILOSOPHICAL WRITINGS OF LORD BACON. 879 placed beyond. the reach of scientific discovery. It is not very surprising, therefore, that Bacon should believe, that a series of skilfully conducted experiments might ultimately lead to the detection of the nature or essence of gold; and that having thus discovered its constituent nature, it would then be possible to superinduce it upon any other substance. There is nothing in all this that any way impeaches his respect to the “ laws and limits of the human understanding.” He recommended no inquiry upon any other principles than those of Induction; and he proposed no object to philoso- phy, which any thing but experience could shew to be unat- tainable. But we are farther told, that there is “ scarcely a page in * the Novum Organum” which does not afford proofs of Ba- con’s ignorance of the laws and limits of the understanding ; and that his miscellaneous philosophical pieces seem to have been written in express contempt of them *. Had this writer | contented himself with stating, that there are many things in Bacon’s miscellaneous pieces, which show that he was not ex- empt from credulity, that his understanding, resplendent as it was, bore some stains of the scurf and seum of an ignorant age; or had he only stated that Bacon’s metaphysical notions ‘are sometimes vague and unsound, and his use of language fanciful and uncertain. his observations might have been: allow- ed to pass unnoticed, as neither new nor objectionable. But when he goes so far as to charge the Novum Organum as every where manifesting a total ignorance of the fundamental condi- tions of philosophical reasoning, the only respectful conclusion, I must say, that can be adopted in regard to such an asser- 3B2 . tion * Quarterly Review, No. =xxiii. p. 50. 380 ON THE SCOPE AND INFLUENCE OF THE tion is, that it has proceeded from a very imperfect acquain- - tance with the work in question. For my own part, I confess myself wholly unable to conceive, how any man of ordinary: judgment could read the Novum Organum with ordinary atten- tion, without carrying away an impression directly the reverse of that of Bacon’s ignorance and disregard of the laws and li- mits of the human understanding. ‘The first sentence of the work contains an emphatic declaration of homage to these ve- ry laws: Homo Nature minister et interpres, tantum facit et in- telligit, quantum, de Nature ordine, re vel mente observaverit ; nec amplius scit, aut potest. The grand lesson which it every where inculcates is, that all false philosophy had sprung from the too high notions hitherto entertained, of the powers of the mind ; these notions having led to the disregard or contempt of the only means by which true knowledge can be obtained. Causa vero, et radix, fere omnium malorum in scientia ea una est, quod dum mentis humane vires falso miramur et extolli- mus, vera ejus aucilia non queramus. Bacon saw more clearly than any preceding inquirer, the folly of supposing the mind ca- pable of explaining the constitution of Nature by means of prin- ciples of its own invention, and reasonings a priori ; and his main aim in the Novum Organum was, to withdraw philoso- phy from such airy speculations, and to employ it in a way more - suitable to its purposes, and the limited nature of our faculties. Employed in this way, that, namely, of inductive inquiry, he showed that philosophy would greatly extend the compass of our knowledge, and multiply the instruments of our power. It is not, therefore, without good reason, that Mr Srewarr pa- negyrizes the author of the Novum Organum, for his know- ledge of “ the laws, limits and resources of the human un- derstanding,” and for the general soundness of his views as to the ends and rules of philosophical investigation. The oe PHILOSOPHICAL WRITINGS OF LORD BACON. 381 ay The truth is, that this writer is, after all, ‘constrained. to make an admission, which of itself sufficiently proves the groundlessness of his general censure of Bacon’s philoso- phy. ‘“ That the rules of investigation which it lays down, “ are wise and salutary with reference to physics, we are “ happy,” says he, “ to admit*.” Now, the Novum Or- ganum is almost wholly occupied with the exposition and illustration of these very rules; and yet it is branded by this writer with the imputation of manifesting disrespect “ in “ every page” to the laws and limits of the understand- ing, and a total ignorance of the purposes of science. It would prove a rather perplexing task, I should imagine, to show how any one could methodize a set of “ wise and sa- “ Jutary rules of investigation with reference to: physics,” who, yet, had no sound views of the nature. and: objects of philosophical inquiry. There must either, in short, be something in the nature of physics to take that great branch of knowledge out of the general category. of philosophy, or it must be absurd to say, that Bacon could unfold the true prin- ciples of physical investigation, he being at the same time ig- norant of the nature and aim of genuine science. His rules with respect to physical inquiry were “ wise and salutary,” precisely because they were conformable to the laws and limits of the human understanding ; because “ he saw well,” to use his own words, “ that the supposition of the too great suffi- ** eiency of man’s mind had lost the means thereof +.” It is besides to be observed, that there is no ground whatever for the limitation of the wisdom and utility of Bacon’s logical precepts to the physical sciences alone. He who admits that they, * Quarterly Review, No. xxxiii. p. 52. + Filum Labyrinthi, Works, vol. i. p.. 400. 4to edit. 382 ON THE SCOPE AND INFLUENCE OF THE they are “ wise and salutary with reference to physics,” must goa step farther, and admit that they are also wise and salu- tary with reference to inquiries regarding the mind. The ob- ject of philosophy, and the principles of philosophizing are the same, whether the investigation relates to the laws of matter or the laws of mind ; and thus the logic of the Novum Organum cannot be useful with reference to the one, without having the same character with reference to the other. It is upon this ground that Bacon himself represents his logic as equally ap- plicable to the advancement of the moral and metaphysical as of the physical sciences. ‘“ Atque quemadmodum vulgaris Lo- “ gica, que regit res per Sy/logismum, non tantum ad naturales, ** sed ad omnes scientias pertinet; ita et nostra, que procedit “ per Jnductionem, omnia complectitur *.” In adverting to the question as to the influence of Bacon’s philosophical writings upon the subsequent progress of phy- sical science, this writer observes, that it presents a “ point *“ as to which it is very difficult to form an explicit opi- * nion. But this,’ says he, “ is sufficiently clear, that if Ba- * con’ is to be allowed any considerable share in the honours “ which modern experimentalists have acquired, he may, in “ many respects, be compared to the husbandman in Aisop’s “ fable; who, when he died, told his sons that he had left “ them gold buried under ground in his vineyard; and they “ digged all over the ground, and yet they found none; but by “ yeason of their stirring and digging the mould about the “ roots of their vines, they had a great vintage the following “ year.” It would, if I do not mistake the matter, be as diffi- cult to explain, how this simile could assist any one to form a correct opinion upon the point in question, as to explain how Bacon * Novum Organum, Lib. i. Aph 127. PHILOSOPHICAL WRITINGS OF LORD BACON. —- 883 Bacon could deliver a wise system of rules for the advance- ment.of physics, without having any just notions of the true nature of philosophical inquiry. ‘The object to which Bacon directed the attention of his followers, was the very object he was desirous they should accomplish,—the regeneration of philosophy by means of a well-regulated use of observation and experiment. The benefits, if any, which accrued to man- kind from his. directions, were obtained precisely in the way, and were precisely of the kind, which he pointed out and pro- mised. Thus, the case of A‘sor’s husbandman is so far from furnishing an illustration of Bacon’s connection with the ad- vancement of physics, that there is evidently no ground what- ever for such a parallel; and the writer who institutes it only proves, that he has altogether mistaken the true bearings of the question. But, before proceeding to state the proofs ‘of this connection, it will be proper to show somewhat more fully, that Bacon’s philosophical merit was of the highest kind, om that. it was wholly unshared by any other person. Bacon’s grand distinction, then, considered as an improver of physics, lies in this, that he was the first who clearly and fully pointed out the rules and safeguards of right reasoning in physical inquiries. Many other philosophers, both an- cient and modern, had referred to observation and: experi- ment in a cursory way, as furnishing the materials of physi- cal knowledge; but no one, before him, had attempted to systematize the true method of discovery ; or to prove, that the Inductive, is the only method by which the genuine of- fice of philosophy can be exercised, and its genuine ends ac- complished. It has sometimes been stated, that Ga itro was, at least in an equal degree with Bacon, the father of the Inductive Logic; but it would be more correct to say, that his discoveries 7 384 ON THE SCOPE AND INFLUENCE OF THE discoveries furnished some fortunate illustrations of its princi- ples. To explain these principles was no object of his; nor does he manifest any great anxiety to recommend their adoption, with a view to the general improvement of science. The Ari- stotelian disputant, in his celebrated Dialogues, is made fre- quently to appeal to observation and experiment; but the in- terlocutor through whom Gatitro himself speaks, nowhere takes occasion to distinguish between the flimsy inductions of the Stagyrite, in regard to the subjects in dispute, and those which he himself had instituted ; or to hint at the very differ- ent complexion which philosophy must assume, according as the one kind or the other is resorted to. Thus, though Gaut- LEO wasa great discoverer, it cannot be said that he had any distinction from having taught the principles of the art by which discoveries are made. That distinction belongs wholly to Bacon. ‘No man,” says one of the most eminent of our earlier philosophers, “ except the incomparable Veruiam, has “ had any thoughts of an art for directing the mind in physi- “ cal inquiries *.” Some late writers have, elite advanced an opinion, that this: distinction does not belong exclusively to any of the moderns +. ‘“ It is an error,” we are told, “ to represent Bacon “ as professing his principle of induction to be a discovery. “ The method of induction, which is the art of discovery, was “ so. far from being unknown to Anistot.e, that it was often “ faithfully pursued by that great observer. What Bacon aim- “ ed at; he accomplished; which was, not to discover new “ principles, but to excite a new spirit, and to render observa- “ tion * Hooxe.—Posthumous Works, p. 6. + See some admirable remarks on this subject, in the second volume of Mr Srewart’s Philosophy of the Mind, Chap. 4. sect. 2.—On the induction of Arts- TOTLE compared with that of Bacon. See: tS an ee ee ee PHILOSOPHICAL WRITINGS OF LORD BACON. 385 ** tion and experiment the predominant character of philoso- phy *.” Itis withconsiderable diffidence that I dissent from any statement made on the subject of Bacon’s philosophy by the author of the splendid and instructive essay here referred to. But I must be permitted to express some surprise, that Ae should represent Bacon’s aims and labours as having been professedly limited to the revival of a method of discovery which had been well known to, and successfully practised by Anistorue. Nothing can be more certain, than that Bacon rests the whole hopes of his philosophy, upon the novelty of his logical pre- cepts +; and that he uniformly represents the ancient philo- sophers, particularly Arisrorie, as having been wholly re- gardless of the inductive method in their physical inquiries. Bacon does not, indeed, say, that the ancient philosophers ne- ver employed themselves in observing Nature ; but.he main- tains, that there is a wide difference between observation as it was employed by them, and the art of observing for the purposes of philosophical discovery. “ Alia enim est ratio “ naturalis historize, que propter se confecta est ; alia ejus, quee “ collecta est, ad informandum intellectum in ordine ad con- “ dendam philosophiam }.” Bacon does not accuse AristTo- Tir of having always reasoned without any reference to facts; but he contends, that Aristorte has nowhere stated the rules for aiding and regulating the understanding in the process of discovery by means of facts ; and that the use which he has made of them in his philosophy, is very different from the use which is made of them in the philosophy of induction. “ Ille “ enim prius decreverat, neque experientiam ad constituenda Vou. VIII. P. IL 3C “ decreta * Edinburgh Review, No. liti. p. 186. + Novum Organ. Lib. i. Aph. 82. 95. 97. 125. + Ibid. Lib. i. Aph. 98. : 386 ON THE SCOPE AND INFLUENCE OF THE “ decreta et axiomata rite consuluit ; sed postquam pro arbi- “ trio suo decrevisset, experientiam ad sua placita tortam cir- “ cumducit, et captivam *.” It should always be recollected, that Bacon’s call was not merely for observation and experi- ment ; but for observation and experiment conducted accord- ing to certain forms and rules ; which forms and rules were first delineated by him, and constitute the body of the Inductive Logic. There may be nothing im this logic that can be called a discovery in the strict sense of the word ; but the statement of its precepts, was certainly a grand and important step to- wards the advancementofv2n uine science. ut It would require a complete analysis of the Novum Organum. to furnish an adequate idea of the value of Bacon’s services in this important department of philosophy ; but the fundamental rules of his method may be comprehended in a few sentences. They seem all to be founded upon the following principles : first, That it is the business of philosophy to. discover the laws. or causes that operate in Nature, in order thereby to explain. appearances, and produce new effects}: next, That we are incapable of discovering these laws or causes in any other way than by attending to the circumstances in which they operate: and, lastly, That the mind is naturally disposed to run into general conclusions, and to form systems, be- fore * Novum Organum, Lib. i, Aph. 63. + Novum Organ. Lib. i. Aph. 117. Throughout the whole of the first book, the object of science is represented to. be the discovery of Axioms ; by which term Bacon eyidently means those general laws or truths which form the basis of our physical reasonings. Newron, as Mr Srewanrt observes, has, after Bacon’s ex- ample, applied the term Axtom to the laws of motion, and to. the statement of certain general truths in Catoptrics and Dioptrics. See Philosophy of the Mind, vol. ii. Chap. 4. They who are engaged in the study of the Novum Organum, will derive much valuable information and assistance from the perusal of this part of Mr Srewarr’s work. PHILOSOPHICAL WRITINGS OF LORD BACON, 387 fore having made all the inquiries necessary to truth. In confor- mity with these principles, he shows, that all sound philoso- phy must proceed from facts; that the facts in every case must be carefully collected and compared ; and that in all our reasonings about them, the natural tendency of the mind to generalize must be carefully repressed. The spurious method of induction is that which proceeds suddenly from particulars scantily collected or ill examined to the most general conclu- sions. The érue method is that which lays a wide basis in ob- servations and experiments, and which generalizes slowly ; ad- vancing gradually from particulars to generals, from what is less general to what is more general, till the inquiry énds in truths that appear to be universal *. _ Nothing could be more encouraging or animating, than Ba- con’s recommendations of this plan of inquiry. Though he held that the noblest end of philosophy is the discove- ry of truth}, he taught that there is a correspondence be- tween this and another end, also of great dignity,—the im- provement of the outward accommodations of human life. He showed, that, when the principles of science should really be derived from the knowledge of Nature, their discovery would prove beneficial to man, as well in respect to the increase of his power as of his knowledge ; because the ptinciples so discovered would lead to new inventions in the useful arts, and to new rules for the improvement of all the operative parts of knowledge. He endeavoured to stimulate the spirit of inquiry, by represent- ing the field of scientific discovery, as yet almost wholly uncul- B.C 2). tivated * Nov. Organ. Lib. i. Aph. 100, 101, 102, 103, 104, 105. + Ibid. Aph. 124. 129. He takes some pains here and elsewhere to guard against the supposition that he valued science only as it was calculated to aug- ment the outward accommodations of life. 388 ON THE SCOPE AND INFLUENCE OF THE tivated, and by assurances that it only required to be cultivated’ with attention to his rules, in order to yield an endless increase: of knowledge and of inventions. “ Let it be believed,” says he, and appeal thereof made to time, with renunciation, never= theless, to all the vain and abusing promises of the Alchy- mists, and such like credulous and fantastical sects, that the new found world of land was not greater addition to the old; than there remaineth at this day a world of Inventions and’ Sciences unknown, having respect to. those that are known, with this difference, that the ancient regions of knowledge will seem as barbarous compared to the new, as the new re- gions of people seem barbarous compared to many of the “ old *.” It is in these confident anticipations of the future triumphs of science, so often repeated as encouragements to its. faithful prosecution, that we more particularly perceive the grandeur and reach of his views. His predictions of improve- ment were not the vague or casual surmises of a happy enthu- siasm; they were evidently grounded upon an enlightened conviction, that the business of philosophy had. hitherto beer mistaken, and that her labours would prosper, when they: should be employed with. constancy and. skill upon their legi~ timate objects. Is it not unreasonable to doubt the utility of a system of logical instructions, in which the true art of discovery was, for the first time, explained? These instructions were of fered at a period in every respect opportune: There was a growing disposition to revolt against the Schools, and: a wise leader was wanted to raise the true standard of reform, and to give a salutary direction to the pursuits of those who should emancipate themselves from their authority. The improve- ment ee * Of the Interpretation of Nature, Chap. ii—Works, vol. i. p. 376. 4to edit. = eer - _ eet ee PHILOSOPHICAL WRITINGS OF LORD BACON. 389: ment of some branches of physics was already in part begun ; but there was no general agreement as to the rules of inquiry.: The truths which Bacon taught are now, it is true, known, and their authority acknowledged by all; but this was far from. being the case in the early part of the seventeenth century. One of the most intelligent of his friends, Sir Tuo- mas Boprey, to whose judgment he submitted an early sketclr ef his plan, appears to have been. wholly unable to. distin- guish between the loose procedure of the: Empirics and that regulated procedure which it recommends. ‘ As for that,” says he, “‘ which you inculcate of a knowledge more excellent “ than. now is among us, which experience might produce; “if we would but essay to extract it. out of Nature by particu- ‘« lar probations; it cannot, in reason, be: otherwise thought, “« but that there are infinite numbers which embrace. the course “that you propose, with all the diligence and care that ability can “ perform. I stand well assured,’ he concludes, “ that tor the “ tenor and subject of your main. discourse, you. will not be “able to impannel. a. substantial: jury in any university,. that “ will give up a verdict to acquit you: of error*.” But that which places the importance of Bacon’s logical instructions in the strongest light, is the fact, that one of the most celebrated of his contemporaries, who also professed himself a reformer of. philosophy, employed the better part of his life, in teaching doctrines as diametrically. opposite in principle as in tendency. ‘This. was Descarrss. ‘“ Never,” says an eloquent philosopher, “did two men, gifted with such genius, recommend paths of in- “ quiry so widely. different.. Descartes aspired to deduce an ex- “. planation of the whole system of things by reasoning a priori “ upon * Sir Tuomas Boptey’s Letter to Sir Francis Bacon aut his coGiTaTA ET: visa.—Bacon’s Works, vol. iii. p. 242, 243, 244, 390 ’ ON THE SCOPE AND INFLUENCE OF THE 5 . upon assumed principles: Bacon, on the contrary, held, that “ it was necessary to observe Nature thoroughly before at- “ tempting to explain her ways; that we must ascend to prin- “ ciples through the medium of facts ; and that our conclu- “ sions must be warranted by what we observe. Descarres “ reasoned about the World, as if the laws which govern it had “ not yet been established, as if every thing were still to “ create. Bacon considered it as a vast edifice, which it was “ necessary to view in all directions, to explore through all its “ recesses and windings, before any conjecture even, could be “ safely formed as to the principles of its construction, or “ the foundations on which it rests. Thus, the philosophy of “ Bacon, by recommending the careful observation of Nature, « still continues to be followed, whilst that of Descarres, «« whose essence lay in hypothesis, has wholly disappeared *” Nor was Descartes, I may add, ignorant of what Bacon had taught as to the principles of philosophizing. It appears, on the contrary, from his correspondence, that he was well acquaint- ed with Bacon’s writings ; and, in one of his letters, he seems to admit, that provided the Experimental were the true Me- thod, there was nothing that could be added to increase the utility of Bacow’s precepts f. Having made these remarks, with a view to point out, in a ge- neral way, the nature and importance of those helps and encou- yagements which Bacon’s writings furnished to physical inqui- ry, Lam next to endeavour to show, that the subsequent pro- gress of physical knowledge was greatly accelerated by the ef- fects which they produced. And here I beg to observe, that 2 * Baitiy.—Histoire de ? Astronomie Moderne, tom. ii, Tiv. 4. § 2. + Lettres de M. Descartes, tom. iv. p. 201, Paris edit. 1724. a ee ae a PHILOSOPHICAL WRITINGS OF LORD BACON. 391 that I have no argument with those who hold, that the re- formation of philosophy by the adoption of the Inductive Method would have taken place in time, though Bacon had never written; any more than with those who hold, that physical science owes nothing to him, on the score of any discovery of importance made by himself, or deduced by others from his sug- gestions. I have before stated, that this reformation was al- ready in progress, and that the Inductive Method had been happily ewemplified in the discoveries of some of his contem- poraries. The proposition here maintained is, that Bacon did more to forward its general adoption than any other per- son; and this,—because his writings contributed more than the labours of any other individual, to complete the abandon- ment of the scholastic methods and systems,—to generate a re- lish for experimental inquiries,—and to imbue the minds of the ingenious with the views and principles requisite to conduct these inquiries with suecess. The way to prove that Bacon’s writings were powerful agents in the advancement of physical knowledge, is to prove that they produced: these effects; and the proof that such effects were actually produced by them, must necessarily be derived from the testimony of thee who early experienced, or became otherwise acquainted with their operation. _ The reputation which Bacon had acquired from his Essays, a work early translated into various foreign languages; his splendid talents as an orator, and his prominent place in public life,— were circumstances strongly calculated to attract the curiosity of the learned world to his Philosophical Writings ; and from some of which, he derived advantages in regard to their circu- lation, not possessed in that age by ordinary men. These wri- _ tings accordingly appear to have been early read by the learn- ed at home, and early transmitted to the learned abroad ; and it 392 ON THE SCOPE AND INFLUENCE OF THE it farther appears, that the important truths which they disclo- sed did not remain long unperceived, or barren of consequen- ces. ‘* Dr Coxuins, Provost of King’s College, Cambridge, “ a man of no vulgar wit, affirmed unto me,” says Bacon’s Chaplain, Dr Rawxey, “ that after reading the Advancement of “ Learning, he found himself in a case to begin his studies “ anew, and that he had lost all the time of his studying be- “ fore *.” Of his more recondite work, his distinguished con- temporary Ben Jounson speaks ag follows: “ The Novum “ Organum is not penetrated or understood by superficial men, “ who cannot get beyond Nominals, but it really openeth all “ defects of knowledge whatsoever ; and is a book «* Qui longum noto Scriptori proroget vum *.” Sir Henry Worron, another of the most eminent men of that day, thus warmly expresses his opinion of its merits: “I have “ received,” says he, in a letter to Bacon, written from Ger- “ many, three copies of that work, wherewith your Lordship “ hath done a great and everlasting benefit to all the children of “ Nature, and to Nature herself in her utmost extent and lati- “ tude,who never before had se true an Interpreter, or so inward “ a Secretary of her Cabinet f.” In this letter, Sir Henry gives an interesting account of an accidental meeting which he had lately had with the celebrated Kepier, in Upper Austria; to whom, he adds, he was about to send one of his copies of the No- vum Organum, for the honour of England. It is not surprising, that a writer who entertained such sentiments in regard to the importance * Life of Bacon, prefixed to Raw ey’s Resuscitatio, or bringing to light seve- ral pieces of the Works of Lord Bacon. + Ben Jonson’s Discoveries.— Works, vol. vii. p. 100. Wxattey’s edition. + Reliquie Wottoniana, p. 299. 3d edition. PHILOSOPHICAL WRITINGS OF LORD BACON. 393 importance of Bacon’s Philosophy, should have been led to predict the speedy downfal of that of the Schools. “ Sir Henry “ Worron,” says Dr Beate, in a letter to Mr Boy gz, written about forty years after this period, “ would often please him- “ self in lashing the Schoolmen; and would often declare it “ as a serious prediction, that in ¢his age their reputation ** would yield to more solid philosophy.” Dr Beare adds, that he had himself been weaned.from the errors of the Schools, by the early perusal of Bacon’s philosophical writings *. In a letter to King James, written about the period of the publication of the Novum Organum, Bacon states, that the Advancement of Learning, had been very favourably received in the Universities; and he thence draws the con- clusion, that the Novum Organum would also be acceptable to them; because, says he, “ it is only the same argument “ sunk deeper f.”. In an address presented to him by the University of Oxford, in the year 1623, he is represent- ed.as a “mighty Hercures, who had by his own hand “ greatly advanced those pillars in the learned world, which, “by the rest of the world, were supposed immoveable + ;” and this piece of homage, it is to be observed, was offer- ed at a time when all motives to interested adulation had been done away by his lamentable fall. These facts seem to evince, that Bacon’s writings had earlymade a strong impression, even in quarters where favourable effects were not likely to be speedily produced; and accordingly, we are informed by . Vox. VIII. P, I. Satven BD ‘ Bishop eee eee eee * Boyue’s Works, vol. vi. p. 355. : + Bacon’s Works, vol. iii. p. 584. + Tennison’s Baconiana, or certain Genuine Remains of Sir Francis Bacon, p- 206. 394 ON THE SCOPE AND INFLUENCE OF THE Bishop Sprat, that when some of those ingenious men who afterwards assisted in forming the Royal Society, began, about the end of the Civil War, to establish a weekly meeting at Oxford for philosophical discussion, they found, that the new spirit of “ free inquiry” had already made considerable pro- gress among the members of the University *. When one’of Bacon’s friends asked him, Whether he thought the Churchmen likely to oppose his intended reformation of philosophy, his answer was—“ I have no occasion to meet “ them in my way, except it be, as they will needs confede- “ rate with AristorteE, who, you know, is intemperately “ magnified by the School-Divines +.” We are told by Os- BORN, a contemporary observer, that the “ School-Divines” did endeavour to cry down his philosophical writings, by represent- ing them as favouring atheism {. This was their usual mode of warfare when the established tenets of the Schools were at- tacked by any formidable patent The Aristotelians of all descriptions, * Sprat’s History of the Royal Society, p. 53 ; also p. 328. This spirit } appears to have made still greater progress at Cambridge. Gutanvitt, who became a student of Exeter College, Oxford, in 1652, ‘* lamented,” says Antnony Woop, ‘ that his friends did not, send him to, Cambridge; because, he used to say, that the new philosophy, and the art of philosophizing, were more cultivated there, than here at Oxford.”—Athen. Oxon. vol. ii. p. 662. —« After the way of free-thinking,” says Baxer, “ had been laid open by Lord Bacon, it was soon after greedily followed.” See his Reflections on Learn- ing. This work was first published in 1699. The author, who was a Fellow of St John’s College, Cambridge, was deeply read in the history of that University. His extensive collections upon that subject are deposited in the British Mu- seum. + Bacon’s Letters to Sir Tosy Marraew, in his Works, vol. iii, p. 247, 257. + Introduction to Oszorn’s Miscellany of Essays, Paradoxes, and Discourses.” ee! ogee PHILOSOPHICAL WRITINGS OF LORD BACON. 395 descriptions, appear to have early manifested a decided hosti- lity to his philosophy ; and their criticisms are sometimes ex- pressed in a way which plainly testifies that it had made con- siderable progress. The examination of his Sy/va Sylvarum, by ALExaNDER Ross, now much better known by Burten’s sarcas- tic allusion in the poem of Hudibras, than by any of his own multifarious productions, furnishes a curious example. It was published in the year 1652, that is, about twenty-five years after Bacon’s death. .“ I have,” says he, “ cursorily run over my ** Lord Bacon’s New Philosophy, and find that philosophy is “ like wine, the older the better. For, whereas ArisroTLe “ had, with infinite pains and. industry, and not without. sin- “* cular dexterity, reduced all entities into certain heads, and *- placed them in ten classes or predicaments. to, avoid confu- “ sion, and that we might, with the more facility, find out. the “ true genus and difference of things; which. Aristotelian ‘* way hath been received and approved by all, Universities, *“ and the wise men since his time in all ages, as being the * most consonant to reason: yet these New Philosophers, as if “* they were wiser than all the world besides, have, like fantastic “ travellers, left the old beaten path, to find out ways unknown, “and have reduced his comely order, into chaos; jumbling “ the predicaments so together, that their splisthcsioe can never “ find out the true genus of things.” The examples which he adduces in illustration of this disorder, are in fact proofs of the growing taste for experimental inquiry ; and it is clear from the context of the whole passage, that Bacon was consi- dered by the Aristotelians as having been its chief promoter. “‘ Sometimes,” he continues, “these New Philosophers tell us, “ that heat, cold, &c. are spirits, consequently substances ; “ sometimes, again, they will have them to be qualities ; some- * times to be motions and actions. Thus, Proteus-like, they 3D ny “ turn 596 ON THE SCOPE AND INFLUENCE OF THE * turn themselves into all shapes, so that we know not in what “ predicament to put their heat, or what genus to give it *.” That New Philosophy, which had already produced so muclt embarrassment among the followers of Aristorter, had already also led to the formation of a Philosophical Society, destined, at no distant day, to realize, in some sort, one of Bacon’s favourite projects. In his letter to King James, written on the publication of the Novum Organum, he states, that his chief object in publishing the work, before completing'it according to his original plan, was, to try to procure help towards com- piling an “ experimental history of Nature fT.” He more than once alludes, in the work itself, to the great things that might be accomplished in philosophical inquiries, by a conjunction of Ja- bours ; and in a romantic piece, called the New Atlantis, he gives an account of a feigned College or Society, magnificently endow- ed, and whose business was the improvement of all the depart- ments of physical knowledge. To this College he gives the name of Solomon’s House. The intention of this piece evidently was, to exhibit a grand and alluring representation of the ad- vantages that might be derived from the co-operation of num- bers in scientific pursuits, and of the renown that a Prince might acquire by forming an establishment directed to such purposes. These views and schemes were not forgotten by his followers. in the year 1645, a Society was formed in London, for the pur- pose of discussing subjects connected with Natural Philosophy, at. stated weekly meetings ; and the name first given to this So- ciety appears to have been that of the Philosophical College t. Some * Ross’s Arcana Microcosmi, or the hid secrets of Man’s body discovered ; with a refutation of Lord Bacon’s Natural History, p. 263, 264. ‘+ Bacen’s Works, vol. iii p. 584. + See Boyte’s Life, prefixed to his Works, p. 34. This Society was some- times called the Invistble College.—Ibid. p 40. 42. PHILOSOPHICAL WRITINGS OF LORD BACON. 397 Some of its members being soon thereafter appointed to Profes- sorships in the University of Oxford, a similar Society was established. by them in that place. In the year 1659, the prin- cipal members of the Oxford branch having returned. to, Lon- don, the two Societies were united ; and hese on the Resto- ration, extended their views to the obtaining a public esta- blishment, they, in. 1662, succeeded in accomplishing that ob- ject, by being erected into a corporate body, under the title of the Royal Society. Wy There can be no doubt Pe aerate of the influence pe Bacon’s suggestions, as to the utility of such an institution, upon the minds of those who planned the establishment of this illus- trious Society... Its earliest. panegyrists and historians bear, tes- timony to this fact. ‘“ Solomon’s House, in the New Ailantis, was “ a prophetic scheme of the Royal Society.” »These are the words of GuanviL1, in his address to that body, prefixed to, his Scepsis Scientifica, published in 1665*, . Bishop Srrar, whose ik? Pe reave / , . »History., ' DD ae e188 | * ‘The Sepsis Seientifiea i is a republication, with some: adidion of : Guan- vitt's first philosophical work, The Vanity of Dogmatizing, ' published i in 1661. The 20th chapter of this work contains a very distinct statement of the import- ant doctrine so often ascribed to Mr Hume,—that we never percedve causation in the succession of physical events ; a-déoctrine which fixes the object of ‘physical science to be, not’ the inyestigation of the efficient causes of phenomena, but of the general laws by which they are regulated; and for which statement of its le- gitimate objects, it is always to be remembered, that physics is indebted to meta- physics. The Aristotelians were provoked by the free spirit of inquiry, and‘ disregard of the authority of their Master, wliich kis work disclosed ;- and an answer to it appeared in 1663, in a book entitled Sczrz, stve Sceptices et ‘Sceptico- . rum a@ jure disputationis exclusio. 'The author was Tuomas Axsius, (Wuite), a secular priest of the Romish Church, and a noted Aristotelian. ‘ Hosses,” says A. Woop, “ hada great respect for Waite, and when he lived in W est- minster, he would often visit him, and he Honses; but they seldom parted in cool blood: for they would wrangle, squabble and scold about. philosophical matters like young sophisters, though either of them was eighty years of age. Howses 398 ON THE SCOPE AND INFLUENCE OF THE History of the Society, published in 1667, received its public. sanction, expresses himself as follows: “* The Royal Society ““ was a work well becoming the largeness of Bacon’s wit to ** devise, and the greatness of CLarENvon’s prudence to esta- “ blish *.” Sprar also informs us, that the Tract published in 1661, by Cowxery, entitled, A Proposition for the Advancement of Experimental Philosophy, “ very much hastened the contri- “* vance of the platform of the Royal Society ;” and this Tract bears internal evidence that its author’s views were originally derived from the New Atlantis. But it is of more importance to show, that the philosophical spirit which actuated the founders of this institution, was chiefly owing to the effects produced by Bacon’s writings. And here, again, I must appeal, in the first place, to the testimony of those to whom. we are indebted for all that we know of its early history. The fullest account of its origin is given by the cele- brated mathematician Dr Joan Wattts, who was one of those who instituted the weekly meetings begun to be held in London in 1645; and his narrative distinctly points to Bacon, as having given a beginning to the taste for experimental science in Eng- land. ‘ Our business,” says he, “ was to discourse and consi- “ der of things appertaining to what hath been called the New “ Philosophy, which, from the times of Gatixo, and Lord “ Veruzam, hath been much cultivated abroad, as well as with Hoszes being obstinate, and not able to bear contradiction, those who were sometimes present at their wrangling disputes, held that the laurel was carried away by Wurre.”—Athene Oxon. vol. ii. p 665. The Scepsis Scientifica has, appended to it, a reply to the animadversions contained in Wuire’s Scirt upon the Vanity of Dogmatizing. * History of the Royal Society, p. 144. Copies of this work were sent, by the Society, to foreign Princes, and other eminent persons abroad, in order to furnish them with an authentic account of its history. See Dr Bircn’s History of the Royal Society, vol. ii. p. 207. \ ce mat ORIEL SO ee ee — i 2 PHILOSOPHICAL WRITINGS OF LORD BACON. 399 * with us in England*.” Sprar always speaks of Lord Bacon, as the founder of that experimental school, which came to be embodied in the institution whose history he wrote + ; and the testimony of Mr Oxpensure, its first Secre- tary, though a foreigner, is equally explicit. “ The enrich- “ ment of the storehouse of Natural Philosophy, was a work,” says he, “ begun by the single care and conduct of the ex- “cellent Lord Verutam, and is now prosecuted by the joint “ undertakings of the Royal Society t.” Guanvint, whose zeal in defending this establishment, against the attacks of its enemies, well entitles him to respectful notice in the history of philosophy, makes frequent acknowledgements to the same purpose. The following passage contained in the work which he wrote in its defence, and which was published in 1668, under the title of Plus ultra, or, the Advancement of Knowledge since the days of AxistorLe, is too remarkable to be omitted on the pre- sent occasion. “The philosophy that must signify either for light ** or use, must not be the work of the mind turned in upon itself, “ and only conversing with its own ideas; but must be rai- * sed from’ the observations and ae of sense, and 47 : “ take * See his Account of his own Life, in a Letter published in the Appendix to Hearne’s Preface to Lanetort’s. Chronicle, Number IX. ft + See particularly p. 35. History of the Royal Society. + Philosophical Transactions, No. 22. p. 391. Mr O.peneurc frequently alludes to Bacon as the chief forwarder of experimental philosophy. ‘ When our renowned Lord Bacon had demonstrated the methods for a perfect restora- tion of all parts of real knowledge, the success became on a sudden stupendous, and effective philosophy began to sparkle, and even to flow into beams of bright shining light all over the world.”—Pref. to Philosophical Transactions tor 1672. —** Many of the chief Unversities in Christendom have formed themselves into _ philosophical societies, and have largely contributed their aids to advance Lord Bacon’s design for the instauration of arts and sciences.”—Pref. to Philosophical Transactions for 1677. 400 ‘ON THE SCOPE AND INFLUENCE OF THE “ take its accounts from things as they are in the sensible * world. The illustrious Lord Bacon hath noted it as the “ chief cause of the unfruitfulness of the former methods of “ knowledge, that they were but the exercisés of the mind “ making conclusions, and spinning out notions from its own “ native store ; from which way of proceeding nothing but dis- “ pute could be expected *—He therefore propesed another “ method, which was, to reform and enlarge knowledge by ob- “ servation and experiment ; to examine and record particu- “ Jars; and to rise by degrees of induction to general :proposi- “ tions ; and from them to take observation for new inquiries ; “ so that nature being known, may be mastered, and used in “.the service of human life. This was a mighty design, “ groundedly laid, and happily recommended by the glorious “ author; but to the carrying it on, it was necessary there “ should be many heads and many hands, and those form- “ ed into an assembly that might inter-communicate their “ trials and observations. This the great man desired, and “ formed a Society of experimenters in a romantic model ; “ but he could dono more ; his time was not ripe for such per- “ formances. These things, therefore, were considered by the “ later Virtuosi, who several of them combined together, and “ set themselves to work upon his grand design +.” s . Similar * Guanvitx’s Plus Ultra, p. 52. + Ibid. p. 87, 88.—There are some who would fain persuade us, that the taste for experimental philosophy was introduced into England from the Conti- nent, and that the first idea of the Royal Society was copied from similar asso- ciations abroad. This, certainly, was not the language of the founders and early historians of that Society. It is curious to remark, that while some of our own writers ascribe its origin, and the philosophical spirit which gave it birth, to foreign excitements, there are, on the other hand, foreign writers who trace the Academies of the Continent to the effects produced by the writings of PHILOSOPHICAL WRITINGS OF LORD BACON. 401 _ Similar testimonies occur in many other publications of that day ; in the more obscure as well as the more noted. Indeed, there is no room whatever for doubt, that Bacon was generally considered as the chief promoter of genuine physics, at a pe- riod when the erection of the Royal Society, was of course "likely to bring forward. the name of any individual, whose la- bours had contributed, in a remarkable degree, to foster the growth of physical science., Cow ey, surely, will not be re- jected as an evidence of the general sentiment, merely be- cause he has recorded his testimony in verse. He was, as al- ready mentioned, a zealous advocate for a public institution, directed to the purposes of experimental philosophy ; and, on the establishment of the Royal Society, he addressed to it that celebrated Ode in which he represents Bacon as its Legislator. Dr Heynry Power calls Bacon “ the Patriarch of experimental “ philosophy ;” in a work published in 1664, in which he de- Vou. VIL. PLT. - BiBndy vids tails © of Bacon. The following passage is extracted from a very learned History of one of the earliest of these Academies.—*+ Sed, quz superest dicenda, supremam, et, ut nobis videtur, proximam condende Academiz enarrabimus occasionem. Scili- cet postquam, ineunte circiter priori seculo, non inter Britannos solum, sed universi quoque orbis incolas, immortalitati commendatissimus, Franciscus Baco de Ve- rulamio, supremus regni Britannici Cancellarius, variis jisque ad sapientiz normam elucubratissimis scriptis, utilissima emendande atque instaurandz historiz natu- ralis dedisset consilia, et absolutissimis rationibus firmasset : non Angli modo haud tncassum se monert atque excitart passt sunt, sed exter quoque gentes, imprimis Galli Italique, sanioris consilii patientes, tanta contentione cum qualibuscunque scientiis generatim, tum przcipue rerum naturalium studio animum intenderunt, adeo, ut ex illo tempore visi sint homines nihil, vel remotissimis naturz visceribus ab- strusum, quod non captis ex Baconis mente experimentis curiosius rimarentur, relicturi. Atque hic ardor, hac studia magnam quoque partem condiderunt Acade- miarum Soctetatumque hactenus memoratarum.” Bucuners, Academ. Nature Cu- wiosor. Hist. cap. i. § Ts 402 ON THE SCOPE AND INFLUENCE OF THE tails the discoveries of Gatmero, Torricent1, and Pascat *. “ It is certain,” says Mr Havers, in the preface to a work also published in that year, entitled, Philosophical Conferences, “ that Lord Bacon’s way of experiment, as now prosecuted “ by sundry English gentlemen, affords more probabilities of ** glorious and profitable fruits, than the attempts of any other ** age or nation whatsoever t.”” Dr Josnua Cuiwprey, in the introduction to his Natural Rarities of England, a book of the same period, and which gave rise to a new class of publica- tions in Natural History, states, that he had given it the title of Britannia Baconica, in order to indicate its connection with those studies which Bacon had originated {. Anruony Woop has pre= served a letter from the same person to Mr OLpEnzvre, Secreta- ry of the Royal Society, in which he says, that he had long been engaged in the philosophical inquiries “ which form the busi- “* ness of that body; in consequence of having fallen in love with “‘ Lord Bacon’s Philosophy as early as the year 1646 ||.” Mr Evezyn, one of the most active and respected of the early mem- bers of the Society, has, in several of his works, alluded to the beneficial effects produced by Bacon’s philosophical writings. In: the introduction to his Sylva, which work he published in 1664, at the request of the Royal Society, he takes oc- casion to state the philosophical principles by which it profes- sed to be guided, in terms which clearly point to the quarter from whence they were derived. ‘“ They are not hasty,” says he, “ in pronouncing from a single or incompetent number of “ experiments ; * Power’s Experimental Philosphy, p. 82. + Philosophical Conferences, translated from the French, by G. Havers, in two volumes folio. . + Britannia Baconica, or the Natural Rarities of England, 1661, 8vo. ‘ From this work,” says A. Woop, “ Dr Pror took the hint of his Natural History of Oxfordshire.” \| Athen@ Oxonienses, vol, ii, p. 468. Saal al PREYS CEI en' oe Ia > ele — PHILOSOPHICAL WRITINGS OF LORD BACON. 403 “ experiments ; but after the most diligent scrutiny, and by « degrees, and by wary inductions faithfully made, they re- “ cord the truth and event of trials, and transmit them to po- “ sterity. They resort not immediately to general proposi- tions upon every specious appearance ; but seek light and in- .* formation from particulars, that they may gradually advance “ to general rules and maxims.” In an after work, he speaks of Bacon’s services in the following expressive terms: “ By “ standing up against the Dogmatists, he emancipated and set “ free philosophy ; which. had long been a miserable cap- “ tive; and which hath ever since bide conquests in the ter- “ ritories of Nature *.” It was about this period, that Mr Boye was honoured with the appellation of the second Bacon +, in: compliment to his exertions to advance the knowledge of experimental physics ; and there can be no doubt, that his discoveries and exertions did contribute essentially to establish the credit of the Eng- lish School. Neither can there be any doubt, as to the influ- ence of Bacon’s writings in determining the nature and objects of his philosophical pursuits. This is admitted, or implied, in many parts of his works f. It is clear, indeed, that he was considered by his contemporaries as a marked disciple of Ba- con. “ You have,” says Dr Beatr, in one of his letters to him, upon the subject of his discoveries, “ particularised, “* explicated, and exemplified, those fair encouragements, and “ affectionate directions, which Lord Bacon in a wide generali- 8 E 2 cert * Evetyn’s Numismata. ~ + See Guanviux’s Plus Ultra, p. 57. { Boyze’s Works, vol. i. p. 305, 6.; vol. ii. p. 472. ; vol. iii. p. 422.; vol. ix. p. 59, 246.; vol. v. p. 567. 404 ON THE SCOPE AND INFLUENCE OF THE “ ty proposed *.” Tn another letter, to Mr Hartrrs, who like himself was an early and zealous promoter of the Royal Socie- ty, Dr Beare thus rapturously expresses his feeling of the plea- sure which Boyie’s experimental labours were calculated to afford to the followers of Lord Bacon. “ To those that have “ been tired and wearied, as I have been in the several ways ‘ of former philosophers ; to those who have condescended to * take deep notice of the insufficiency of conjectures, and un- “‘ grounded ratiocinations, and who have submitted their pa- “ tience to the severity of Lord Bacon’s inquisitions, here are ‘ offered such pleasing refreshments, as give us the relish of ‘ that Virgilian simplicity, which was so highly admired by “* ScanicER in these verses : o « ral cal ‘¢ Tale tuum carmen nobis, divine poéta, «* Quale sopor fessis in gramine, quale per estum * Dulcis aque saliente sitim restinguere rivo +.” They who have overlooked or disregarded the proofs of the connection between what Bacon enjoined, and Boye perform- ed, are not likely to have recognized any traces of the lights held out by the former, in the philosophy of Newron. Yet it appears undeniable, that the latter was guided by principles which Bacon alone had taught; and that his philosophy derives its imperishable character from his rigid adherence to them. To begin with the examination and comparison of phenomena in order to rise to the knowledge of general truths, and to pro- ceed * Boyue’s Works, vol. vi. p. 405. + This letter is printed in the Life of Boruer, prefixed to his. works, p. 63.— Dr Beate was elected a Fellow of the Royal Society in 1662. Several of his papers are printed in the Transactions. He was a man of excellent parts, and great public spirit; and the character which his friend Mr Harri gave of him was, that there was no man in the island who could be made more universally use- ful."—Bircn’s Hist. of the Royal Society, vol. iv. p, 235. SO pe ean PHILOSOPHICAL WRITINGS OF LORD BACON. 405 ceed gradually from truth to truth, till we reach the most ge- neral that can be discovered,—these are the principles of phi- losophizing which. Bacon unfolded, and which Newron has, in the most emphatic terms, embodied with his discove- ries. * Quel témoignage,” exclaims an eminent French philoso- pher, “ rendu par le génie inventeur au génie des méthodes* !” Such, indeed, was the connection between the logic of the No- vum Organum, and the philosophy of the Principia, that it was only where the one was followed, that the other prevailed. The sublime Geometry of the Principia, says Mact.aurin, was admired by all, but it was only among minds trained by Ba- con’s. precepts that it found a ready reception for its Philo- sophy +}. To these proofs of the influence of Bacon’s precepts and exhortations, reflected in the acknowledgments, the views, and the discoveries of the early founders of the English School: of Experimental Philosophy, I have yet to add those which are furnished by the writings of its opponents and detractors. The public countenance given to that School by the erection of the Royal Society, early excited an extraordinary degree of jealousy on the part of the Universities; and a keen spirit. of opposition among the remaining supporters of the Aris- totelian philosophy. Sprar accordingly found it necessary, in his History of the Society, to employ a long argument to _ prove, that this new establishment would be attended with ar fom iy we * Deceranno— Hisloire comparée des. Systemes de Philosophie, tom: i. p.396.— The introduction to Dr Pemperton’s Account of Newton's Discoveries, a work, ‘< the greater. part of which was read and approved,” as we are told inthe preface, by Newton himself, contains a summary of the doctrines of the Novum Organum ; and its author is represented as the first who taught those rules of philosophizing which Newton followed, and which his discoveries so nobly eonfirmed. + Mactavrin’s Account of Newton’s Discoveries, p. 59, 60. 406 ON THE SCOPE AND INFLUENCE OF THE no bad consequences either to religion, or to the existing se- minaries of knowledge. Guanvitt was obliged to enter into a serious refutation of an assertion, that “ ArisrorLE had had “ more advantages for knowledge than the Royal Society, ei- “ ther had, or could have*.” ‘The panegyrics which these writers bestowed upon the Institution, and upon Lord Bacon as its Master, appear to have filled the followers of AristoTLE with a still more envenomed hate to both. The most forward of their champions was Dr Henry Stusse, who, after study- ing at Oxford, had served for some time in Scotland with the Army of the Parliament; but having on the Restoration made his peace with the Government, he was appointed King’s Physician for the Island of Jamaica, from whence he had late- ly returned, to practise in his own country. He was, according to Antuony Woop, “ the most noted Latinist and Grecian of “ his age, and a singular Mathematician ;” but he seems to have been as deficient in judgment as he was violent in temper ; which last defect, his biographer 1 in great simplicity ascribes to his “carrot-coloured hair +.” His publications against the Royal Society, and the whole body of Eenermientatines, were nume- rous, _— * « L desire the reader to know, that after Mr Josers Guanvitt had writ- »ten certain things against Aristorie, it was the desire of some scholars, that Rosert Crosse, a noted philosopher after the ancient way, should be brought acquainted with him. In 1667, Guanvitt was therefore conducted to his house, where Crosse did in a sufficient manner vindicate Aristorte; and did plentifully declaim against the proceedings of the Royal Society. Guanvitn being surprised, he did not then much oppose him ; but afterwards he did, to the purpose ; especially against this hypothesis of Crosse, that Artstorie had more advantages for Mistolede than the Royal Society, or all the present age had or could have, because he did totam peragrare Asiam.”—Athene Oxontenses, vol ii. p. 753. See the account ves Guanvitt himself gives of this conference, Plus Ultra, p: 4, 5. + Woon’s Athen. Oxon. vol. ii. p. 562, 563. PHILOSOPHICAL WRITINGS OF LORD BACON. 407 rous, and. all of them replete with misapplied learning, and ve- hement abuse. The course of his reasoning is not a little cu- rious. ‘ Ihave so small a regard,” says he, “ for deep and “ subtle inquiries into natural philosophy, that could physic “ be unconcerned, could religion remain unshaken, could edu- “ cation be carried on happily, I should not intermeddle; but if “ we look de facto upon those experimental philosophers, and “ judge how little they are fitted for trusts and managements. “ of business, by their so famed mechanical education, we must “ rise as high i in our resentments as the eoricams of the pre- “ sent age and of posterity can animate us.” ‘The grounds which oe more Pe assigns for entertaining these “ high «e resentments” against the experimentalists, are, first, their neglect and contempt of the Aristotelian logic; “ that art,” says she, “ by which the prudent are discriminated from fools ; “ which informs us of the validity of consequences, and the ct probability of arguments, and which forms statesmen, di- “ vines, physicians, and lawyers.” In the next place, he con- tends, that the innovating spirit of their ey eee. would lead to ‘dangerous revolutions. “Tn such times,” says he, “ as I = thought it our interest to subvert the monarchy of England, “and the repute of the clergy, I was passionately addicted to « ‘this new philosophy ; for 1 “did not question but the autho- « ‘rity of all antiquity in spiritual affairs would vanish, when it “ appeared how much churchmen were mistaken in the com- “ mon occurrences and histories of nature. How rational this “ opinion of mine was, and how it is verified in these days, let “ the Hierarchy and Universities judge *.” With s * Stupze’s Legends no Histories ; or, a specimen of some animadzersions upon the History of the Royal Society. Pref. 4to. Lond. 1670. 408 ON THE SCOPE AND INFLUENCE OF THK With such views of the new philosophy, this infatuated Ari- stotelian could not but wish to decry the authority of any one who was more particularly considered as its author. That he himself looked upon the experimentalists of that day as the disciples of Bacon, is sufficiently evident from this, that his common mode of designating them, is to call them in derision “« a Bacon-faced generation*.” To abuse Lord Bacon, and to de- preciate his philosophical character, are accordingly his favourite topics. Nor does he leave us in any doubt as to the cause of his enmity. It was,as he expressly tells us, “‘ because the repute “ of Lord Bacon was great in that age + ;’ and because “ the “ Royal Society pretended to tread in his footsteps }.” He al- lows that Bacon was a wise and eloquent man; but with re- spect to his censures of the philosophy and methods of the an- cients, there, says he, he was insufferably in error. ‘“ Who “ knows not,” he asks, ‘‘ how Herbary had been improved by « Turorurastus, Dioscoripes, the Arabians, and other Peri- “ patetics ? who can deny that Physic, in every part of it was “ improved, by Gaxen and others, before the Lord Bacon “ ever sucked ? and what accessionals had not Chemistry recei- “ ved by the cultivation of the Aristotelians, before his House “ of Solomon was dreamed of ? Let us, therefore, not be con- “ cluded by the aphorisms of this Lord. Let his insulse ad- “¢ herents buy some salt, and make use of more than one grain «« when they read him; and let us believe better of the an- “ cients, than that their methods of science were so unfruit- “ ful ||.” It was the confident belief of this misguided man, that pel Dae odo aw naa pee a * Srusse’s Epistolary Discourse concerning Phlebotomy, passim. 4to. Lond. 1671. ; + Lord Bacon’s Relation of the Sweating Sickness examined, p. 2. 4to. Lond. 1671. + Legends no Histories, p. 29, }) Lord Bacon’s Relation of the Sweating Sickness examined, Pref. p. 5. PHILOSOPHICAL WRITINGS OF LORD BACON. 409 that Bacon’s fame was wholly owing to the false notions of phi- losophy then entertained, and that it could not fail to fade with the recurrence of sounder views. “The Lord Bacon,” says he, “ is like great piles; when the sun is not high, they ** cast an extraordinary shadow over the earth, which lessen- “ eth as the sun grows vertical *.” How vain the prophecy involved in this uncouth simile! The fame of Bacon has brightened as Science has advanced, every new discovery bring- ing a fresh proof of that transcendent sagacity which enabled him so unerringly to plan and predict the indefinite enlarge- ment of her Empire. ee The preceding illustrations of the influence of Bacon’s wri- tings, are confined to the effects which they produced in Eng- land. It remains to be inquired, Whether they were atc. tive, in any degree, of any similar effects, in the other coun- tries of Europe? It is the opinion of some, who are far from being otherwise sceptical as to their influence, that these writ- ings were, for a long period, but little known upon the Conti- nent ; and consequently, that all their effects, of a direct kind, were limited to England. This opinion has been lately avow- ed by one of the most enlightened and ardent of Bacon’s ad- mirers; one whose extensive knowledge in regard to the his- tory of learning, I shall hardly, I trust, be suspected of any in- tention to bring into doubt, by dissenting from his statements on this particular question. “ That the works of Bacon,” says Mr Stewart, “ were but “ little read in France till after the publication of D’Atem- Vou. VIII. P. II. 3F S BERT’S * Sruser’s Legends no Histories, p. 28. 410 ON THE SCOPE AND INFLUENCE OF THE * pert’s Preliminary Discourse to the Encyclopedic, is, I be- lieve, an unquestionable fact ; not that it necessarily follows “ from this, that, even in France, no previous effects had been “ produced by the labours of Bortz, of Newron, and of the “ other English experimentalists, trained in Bacon’s schodl.” Mr Srewarr farther observes, generally, “ that the merits of “© Bacon failed, for a century and a half, to command the ge- “ neral admiration of Europe. Nor was Bacon himself,” he continues, “ unapprised of the slow growth of his posthumous “ fame. No writer seems ever to have felt more deeply, that “ he properly belonged to a later, and more enlightened age ; “a sentiment which he has pathetically expressed’ in that “ clause of his testament, where he ‘ bequeaths his name to “¢ posterity after some generations shall be past *.’” In making these statements, Mr Srewarr seems to have overlooked a crowd of testimonies, which prove in the most. satisfactory manner, that Bacon’s philosophical fame was early established, not only in France, but in all the other countries of Europe, where letters were cultivated. I must farther be per- mitted to express some doubt, whether Mr Stewart has rightly. interpreted that truly affecting clause of Bacon’s Testament to which he so eloquently alludes. There are no contemporary publi- cations which give any countenance to the supposition, that Ba- ‘CON * Dissertation on the Progress of Metaphysical, Ethical, and Political Philoso- phy, p. 58, 85. 5 prefixed to the Supplement to the Encyclopaedia Britannica.— These statements have been already questioned, in part, in the article of the Edinburgh Review before referred to. ‘The able author of that article contends, that Bacon’s fame was early and generally established throughout the Continent ; but he admits, that it was late before any beneficial effects were produced by his philosophy. PHILOSOPIIICAL WRITINGS OF LORD BACON. 411 con himself thought his writings had not met with due atten- tion from the learned world. We have, indeed, his own evi- dence to the contrary, in regard to the most important, and, as he himself says, the most “ abstruse” of them,—the Novum Or- ganum. “ I have received,” says he, “ from many parts be- “ yond the seas, testimonies touching that work, much beyond “ what I could have expected at the first in-so abstruse an “ argument *.” It is probable, therefore, that the bequest of his Name to future generations, referred rather to his public than to his philosophical character. In his act of submis- sion presented to the House of Peers after his disgrace, he im- plored them to recollect, that there are “ vitia temporis as well as “ vitia hominis ;” and he perhaps soothed his wounded spirit with the hope, that posterity would find an excuse for his frail- ties, in the lax notions and practices of the age; and would look upon his fall, to use a comparison of his own, “ but as a “ little picture of night-work, among the fair and excellent “ tables of his acts and works +.” The exact terms of the clause, besides, seem to countenance the interpretation, that his hopes pointed to the greater candour, rather than to the greater intelligence of after times. “ My name and memory,” says he, “ I leave to men’s charitable speeches, and to foreign “ nations, and the next ages {.” But whatever opinion may be entertained upon this point, it will, I hope, appear eviden . 3F 2 in * Epistle to Bishop Anprews, prefixed to An Advertisement touching an Holy War, written in 1622, and published by Dr Rawxey in 1629, in a collection entitled, Certain Miscellany Works of Lord Bacon, Ato. + Epistle to Bishop Anvrews, prefixed to his Holy War. ¢ Bacon’s Works, vol, iii. p. 677. 412 ON THE SCOPE AND INFLUENCE OF THE in the sequel, that Bacon’s works were well known, and their beneficial effects largely acknowledged, in foreign countries, lone before the period pointed at in the statements of Mr Srewarr. In the first place, then, I must observe, generally, that the tes- timony of such of Bacon’s contemporaries as allude to his writ- ings, as well as of his earlier Biographers and. Editors, stands de- cidedly opposed to the supposition, that his fame was of slow growth upon the Continent. The information which they give upon this point, rather, indeed, supports a contrary conclusion, —that the early celebrity of his writings abroad, contributed to enhance their credit at home. Thus, Gusaws tells us, that it was the voice of foreign fame which silenced the cry of atheism, raised against them by some of the School-Divines of his own country *. Mr Srewarr dates the full acknowledgment of his philosophical merits in England from the period of the esta- blishment of the Royal Society +. Now, in the account of Bacon’s Life, published in 1657 by Dr Rawrzy, who had been for many years his domestic Chaplain, it is distinctly stated, “ that his fame was greater, and sounded louder in fo- “ yeign parts than at home ;” and it is added, “ that divers of “ his works had been translated more than once into other “ tongues, both learned and modern, by foreign pens f.” Dr Rawxry had, some years before, received a strong proof of the early celebrity of his late Patron’s writings abroad, in a letter from Isaac Gruter, which contains the following pas- sage: “ Lewis Exzevir wrote me lately from Amsterdam, that “ he i EEEIENEEEee * Oszorn’s Miscellany of Essays, Paradoxes and Discourses, Preface. +- Dissertation, p. 158. + Life, prefixed to Rawury’s Resuscitatio, first published in 1657. LALLA PLEA LLL A INE: PHILOSOPHICAL WRITINGS OF LORD BACON. 418 “ he was designed to begin shortly, an edition in quarto, of all “ the works of Lord Bacon ; and he desired my advice, and * any assistance I eould give him; to the end that, as far as “ possible, these works might come abroad with advantage, which have been long received with the kindest eulogies, and “ with the most attested applause of the learned world*.” ‘This letter was written in 1652, only twenty-six years after Bacon’s death ; and the important statement which it contains, in re- gard to the early impression made by his writings in foreign countries, will be found fully corroborated by a more particu- lar examination of their literary records. With respect to France, the only direct authority to which Mr Srewarr refers, when he states it as “ an unquestionable “ fact,” that Bacon’s writings were little known in that coun- try till after the publication of the Encyclopedie, is that of Montvucra. After quoting a short passage to that effect from the preface to this writer’s History of Mathematics, he farther remarks, in a Note, that “ Bayrz has devoted to Bacon only « twelve lines of his Dictionary +.” But, surely,no weight what- ever can be attached to this circumstance, when it is recollect- ed, that Bayie has not devoted even one line of that work, in the shape of a separate article, either to Gatmro or Des- cartes. I must, besides, observe, that his notice of Ba- con, scanty as it is, yet contains enough to show, that Monructa’s observation is not well founded. The article mentions, generally, that Bacon’s writings “ had been favour- “ ably “cc * Tennison’s Baconiana, p. 229.—Dr Wars, in the Dedication prefixed to his translation of the De dugmentis Scientiarum, published in 1674, speaks of Bacon “as an author well known in the European world.”—Dr Suaw, in the Preface to his edition of Bacon’s works, published in 1733, says, that “ foreigners appear to have extolled him in a superlative manner.” + Dissertation, p. 58. 4 414 ON THE SCOPE AND INFLUENCE OF THE “ ably received by the world.” It states, that the Treatise De Augmentis Scientiarum had been reprinted at Paris in 1624 ; that is, the year after it was published in London; and re- ference is made to some high eulogiums, which had been pro- nounced by French writers upon that important work. It far- ther mentions, that a number of editions of a French trans- lation of his moral and political pieces had been called for, within a short period after its publication; a circumstance which Baye casually notices in another of his works, the Reponse aux Questions dun Provincial *. | That Bacon’s philosophical views were well known in France, before his death, is a fact, for which we have an authority the more satisfactory, that it is that of the biographer and disciple of his great French rival, in the reformation of knowledge. “ While Descartes,’ says Aprian Batter, in his copious and instructive life of that philosopher, “ was in Paris in 1626, “ he heard the news of the death of the Lord Chancellor “ Bacon, which happened in April of that year. The intel- “ ligence very sensibly affected those who aspired to the re- “ establishment of true philosophy ; and who knew, that Bacon “ had been labouring in that great undertaking for several years “ before his death. The accomplishment of this heroical de- “ sign,” continues this devoted Cartesian, “ was reserved for “ a still more extraordinary genius; but the praises which “ Bacon received were justly due, even from those who did “ not approve of his plan for the reformation of philosophy +.” The * Chap. 9.—Troisiéme partie—Bacon’s Essays, and his Advancement of Learn- ing, were translated into the French language a considerable time before his ae His Natural History, and New Atlantis, were translated into that lan- guage by Pierre D’Amoorse in 1631. Bacon’s works, says this writer, ‘‘ de- serve a place in all oes and to be ranked with the noblest literary mo- numents of antiquity.” + La Vie de M. Descartes, par Battier, tom. i. p. 147, 148, 4to. oi a” ‘ PHILOSOPHICAL WRITINGS OF LORD BACON. 415 The same writer admits, that Bacon’s example may have been of some use to his French rival ; inasmuch as it was calculated to encourage him in his design, to abjure the authority of the ancients, and to re-establish the sciences upon a new founda- tion *. He farther observes, that Descartes thought Bacon’s method very well suited to the views of those who were willing to incur the expence and trouble of instituting experiments 7. In- making this observation, he refers to some remarkable passages in Descarres’s letters to Father Mrrsrnnr; one of which is as follows: “ You formerly wrote me, that you “knew persons, who were willing to labour for the advance- “ ment of the sciences, at the cost of all sorts of observations “ and experiments; now, if any one who is inclined this way, “could be prevailed upon to undertake a history of the ap- “pearances of the Heavenly Bodies, to be drawn up accord- “ ing to the Verulamian method, without the admixture of hypo- “ thesis ; such a work as this would prove of great utility, and “ would save mea ae deal of trouble in the prosecution iad wee GEOLOGY OF THE base to the tip of the spire; columella with three plaits ; beak short and slightly bent. Shell turrited, strong, with six whorls deeply divided by the suture, with seven strongly ‘ warted longitudinal ribs; fine- ly striated transversely; aper- ture oblong, beak short ; inner lip slightly reflected, with four knobs ; outer lip with a row of strong teeth within. 18. dentatus. Pl. X. f.1. TROCHUS. 1. Pharonius. Lister, t. 638. f. 26.—Dillwyn’s Conch. p. 772. Q. corallinus. Adanson’s Senegal, p.183. t. 12. f. 4. —Dillwyn, p. 773. 3. Guineensis. Schroeter Bin, I. p. 712.—Dill- wyn, p. 773. 4. Modulus. Lister, t. 653. f. 52.—Dillwyn, p. 775. 5.tumidus. Montagu, p. 280. t.10. f. 4,.— p- 777. Tro. Patholatus, 6. fasciatus. Schroeter, I. p. 747—Dillwyn, . 783. 7. solaris. ee t. 622. f. 9.—Dillwyn, p. 786. 8. crenulatus. Brocchi, p. 354. t. 4. f. 2. 9. miliaris. | Brocchi, p. 153. t. 4. f. 1. 0. tessalatus. Schroeter, I. p. 693.—Dillwyn, . 794. Dillwyn, p. 782.—Donovan, Br. Sh. v. t. 155. f. 3. ‘Shell conical, umbilicated, with five abrupt volutions ; body large, in proportion to the other whorls; a deep grove runs spirally from the outer __ lip to the apex, in the: centre of the volutions ; above which is a regular row of large tuber- cles ; the whole shell is spiral- ly striated ; and above the tu- bercles there are regular spots of a yellowish brown. Diam. ths, length the same. . cinereus. 12. torosus. Pi KO. TURBO. 1. acutus. Risso in Jour. des Mines, No.200. Aout 1813. p. 6. Rissoa acuta. Risso in Journal des Mines, p. 6. Rissoa violacea. Risso in Journal des Mines, p. 7. Rissoa plicata. 2. violacea. 8. Rissoa. 4. costatus. ENVIRONS OF NICE.——APPENDIX. 4, costatus. Dillwyn’s Conch. p. 860.—Wal- ker’s Minute Shells, f. 4’7. Maton and Racket im Linn. Trans. viii. p. 180.-Montagu, p.362. 5. labiatus. : t. 11. f. 6. 6. turgida. Shell turrited, with five volutions; Pl. X. f. 3. very much inflated; separa- ‘ ted by a dee strong longitudinal ribs ; and very fine regular transverse strie ; apex very sharp. Shell pointed, with strong longi- tudinal ribs and transverse strie; inside ribbed; body whorl, about equal to the length of the spire. Length 13 aghth of an inch. Shell pone strong, with five longitudinal and transverse strie ; inside ribbed; outer lip thickened ; body longer than the spire. Length 1} eighth of an inch. — Shell subulate, with ten glossy well defined whorls, white, aperture sub-rotund. _ Shell conic, im large and tur- 8. discrepans. Pl. X. f. 4. T Nh 9. glaber. — ff 2; 10. minutus: suture, with } 463. ovate, pillar-lip smooth ; out- er lip thin and crenated. Length jth, breadth not quite an eighth of an inch. Maton and Racket in Linn. Tr. p-177.—Montagu, Test. Br. p- 300. t. 10. f. 7. 12. truncatus. 13. pullus. Dillwyn, Br. Sh. p. 822.—Do- noyan, Br. Sh. I. t. 2. f. 2. to 13. cimex. Dillwyn, p- 821.—Da Costa’s Br. Conch. p. 104. t. 8. £. 6.& 9. Turbo cancellatus, Dorset. Cat. p. 59. t. 14. £6. & 9. 14. phasianella. Risso in Journal des Mines, No. 200. Aout, p. 6. Phasia-. nella rubra. 15. geniculus. Brocchi, p. 659. t. 16. f. 1. 16. elegantissimus. Vid. p. 458. 17. striatus. Brocchi, p. 383. t. 6. f.'7. 18. Ulve. Dillwyn’s Conch. p. 840. Pen- nant, Br. Zool. iv.. p. 182. t.86. £120. Dorset Catal. . 49. t. 18. f. 12. 19. interruptus. Dillwyn’s Conch. p, 841.—Mon- ae Test. Br, p. 329. t. 20.. 3 PLX. £13. gid;. spire short, with four | 20. parvus. —_ Dillwyn’s Conch. p. 85'7.—A- ‘) moderately rounded volutions3. by, dams in Linn. Trans. iii. ees apex rather obtuse ; the whole ae m p. 66. t. 13. £.29. & 30. Tur-. oy shell is covered with fine spi- | ‘- bo zreus, Donovan, Br. Sh.. ih ral striz, and clouded with| = t. 90. T. lacteus. pale honey-yellow ; aperture | 21. cancellata. Brocchi, p. 377. t.'7. f. 8. nearly round; pillar-lip slight- | 22. pusillus. Brocchi, p. 381. t. 6. f. 5. ly reflected, and forms a sub- | 23. conoides. Brocchi, p. 660. t. 16. f. 2. umbilicus ; outer lip thin. | 24. verrucosus. Shell with a ventricose body ; ee Length about j,th of an PL.X. £12. spire with four very distinct ~ inch, breadth. about half its volutions ; the whole shell is i-'% hy ength. ail ° covered with elevated knobs _ the spire having only ‘four _ volutions, and in the aperture being rounder. P Shell longitudinally ribbed ; strongly striated transversely between the ribs; body large and spire short, with five well defined “a aperture 11. breve. PL X. f.10.— in regular rows; the intersti- ces deeply punctured ; aper- ture ovate; outer lip strong ; Lae slightly reflected to- wards the base; inside ver glossy. Length about 3th, breadth somewhat less. 25. gracilis. Brocchi, p. 382. t. 6. £..6. 26. striatulus, Dillwyn’s Conch. p.85'7.—Mon- tagu’s Test. Br. p. 306. t. 10. £5. There is also a variety of this shell with strong, elevated, longitudinal varices. 27. rugosus. ci 464 27. rugosus. Dillwyn’s Conch. p.829.—Lis- ter’s Conch. t.647. f. 41.— Gualtieri, t. 65. f. F. & H. Shell with strong longitudinal and transverse striz ; the lon- gitudinal striz terminate Ww ere the outer lip joins the ody, and give it the appear- ance of fine papillae : the body is large and ventricose ; spire with five short whorls ab- ruptly tapering to a sharp- ened pats aperture ovate ; outer lip thin and strongly crenated; pillar-lipsmoothnear the base, and slightly reflect- ed, formmg a sub-umbilicus. Length, an eighth and a half, ' breath 3th of an inch. — Broechi, p. 981. t.6.£.4. 28. tigerina. Pl. X. f.11. ae a 99. acinus. HELIX. 4 1. vitrea. Dillwyn’s Con. p.919.—Chemnitz 383. t.15. £15.16. 2. polita. Dillwyn, p.881. Tur. polita, Linn. Trans. viii. p.210. Donovan, Br. Sh. t. 177. era 3. haliotoidea. ple ‘on! ee 570. Bt otoidea, NERITA. — x J. Glaucina. Dillwyn, p.978.—Donovan, Br. Sh. I. t. 20. f. 1.—Gualtieri, | t. 67. f. A. and B. HALIOTIS. : 1. striata. Vid. p. 458. ¥ DENTALIUM. 1. Entalis. Vid. p. 458. MADREPORA. 1. striata. Corals nearly straight ; divergent, covered, with fine longitudinal strize. 2, pistularia. Clavate, turbinate, base, with small pustules, and undated ; hori- zontally ridged; centre con- cave; gills about 36, with in- termediate ones, oval. ‘_ e x if Triquetra. Linnzus, Syst. Nat. p. 1265.— Ms zoornyrs GEOLOGY OF THE ENVIRONS OF NICE.—APPENDIX. PATELLA. 1. Virgmea. Dillwyn’sConch. p.1052.—Linn. Trans. LV. p. 235.—Donovan, _ Br. Sh. I. t. 21. f. 2. . 2. Greca. Linnaeus, Syst. Nat. p. 1262.— ~ Dillwyn’s Conch. p. 1056.—Do- novan, Br. Sh. I. t. 21. £.3. Pat. reticulata. 3. pellucida. Linneus, Syst. Nat. p. 1260.— Dillwyn’s Conch. p. 1042.—Do- novan, Br. Sh. I. t. 31. f.1. Linnzus, Syst. Nat. p. 1258.— Dillwyn’s Conch. p. 1032.—Do- novan, Br. Sh. I. t. 14 Linnzus, Syst. Nat. p. 1261.— _ Dillwyn’s Conch. p. 1054.-Do- ~ novan, Br. Sh. I. t. 3. f. 2. 6. saccharina. Linnzeus, Syst. Nat. p. 1258.— __ Dillwyn’s Conch. p. 1023. illwyn’s Conch. p. 1015.—Lis- _ ter’s Conch. t. 546. f. 38. SERPULA. ~ 4. vulgata. 5. fissura. 7. equestris. Dillwyn’s Conch. p. 1073.— 3 Martini Conch, III. t. 24. f. A.—Pulteney in Huch. Dor- set, p. 53. t. 22. f. 5. | 2 vermicularis. ba inn. Syst. Nat. p. 1267—— Iwyn’s Conch. p. 1083.— Z ; Donovan's Br. Sh. ii. t. 95. 8. anguinia. Linnaeus, Syst. Nat. p.1266.— ' ~ Martini, 1. 1.2. £13. B, C— Dillwyn’s Conch. p. 1080. 4. arenaria. Linneus, Syst. Nat. p. 1266.— Martini, I. t. 8.19. A.—Dill- ; -__ _ wyn’s Conch, p. 1078. 5. lumbricalis. Linnzus, Syst. Nat. p. 1266,— ai tin, It. 1.f 12 B— Sbllleyns Conch. p. 1077. ye tai, ‘ : a \... and a half eighths, breadth three eighths of an inch. There is a variety of this with only 26 gills. Turton’s tian iv. p. 630.—— Shaw, Nat. Miscell. t. 194. Turton’s Linné, iv. p. 631.—Pal- las El. Zooph. p. 313. No. 182. 3. ramea. 4. hirtella. aR a se ow 1 PLATE Ix. Engraved tor the Royal Soctely Tran VolVill. Page 464 = Prawn by Capt= Drown Tograved Dy WED larare hanburgh ats x. PLATE Engraved by WD. Liaers Edinburgh @ by Capt Hrown. a XXI. On certain Impressions of Cold transmitted from the Higher Atmosphere, with the Description of an Instrument ad- apted to measure them. By Joun Lesuiz, F.R.S.E. and Professor of Mathematics in the University of Edin- burgh. (Read March 16. 1818. ) pnt distribution of Heat over the surface of our Globe, is a capital object in the economy of Nature. The infusion of that active element communicates to bodies the principle of mo- tion, and quickens the ceaseless revolution of the circle of ge- neration and decay. But Heat, unlike air, water, or earth, appears never in a distinct and separate form: It exists only in a state of combitation with other tangible substances ; among which, it migrates from one to another. On the re- gulated tide of this transmission, depends the stability of the present order of things. A very small portion of the vast scale of heat is requisite and salutary for vegetable or animal life. A genial warmth fosters the powers of vegetation,—but push- ed farther, it soon dries up the juices, and ‘shrivels the leaves and tender shoots; on the other side, again, when reduced to a low temperature, it benumbs the energy of production, and finally stifles the expansion of life. If the transfer of heat among bodies were much slower, therefore, than what actually obtains, its inequalities would ac- cumulate, and the greater part of this fair globe would be- Von. VII. P. II, 3N come 466 ON IMPRESSIONS OF COLD come a desert. The tropical countries. would be burnt up by unmitigated fervour ; while eternal frost, usurping the polar re- gions, would extend its dominion within the temperate zone. The little portion of the surface left to animation, would be blasted by the excessive inequalities of the seasons, and of the diurnal vicissitudes. The sultriest days would have invariably closed in nights of pinching cold, and this mild climate would have exhibited all the rigours of a Canadian winter, succeeded by the fervid heat of an oppressive summer. The opposite condition leads to results still more appalling. If heat encountered no impediment. in its internal motions, but diffused itself with almost instantaneous effect, it might amuse the fancy to contemplate for a moment the vast and tremendous consequences. An uniform and unyarying tem- perature would then pervade the globe ; no distinction of cli- mate would exist, no vicissitude of seasons, and no grateful alternation of day and night. The azure vault of heaven, per- tually serene and cloudless, would lose all its animated charms. If snow and hail would be unknown, so would likewise the re- freshing influence of rain and dews. The face of the earth would present a monotonous picture of sterility ; no verdure to relieve the eye, —no vegetation,—and no sustenance for ani- mals. All the springs of life would be locked up. The bene- ficial effects,—the very existence, of artificial heat, would for ever have been concealed; since the instant this was genera- ted, it would spread and ingulf itself in the general mass. It is, therefore, an important study, to discriminate the cir- cumstances which modify and regulate the distribution of heat among bodies. ‘Towards a correct knowledge of the subject, very considerable advances have been made, though some vague and crude notions are still suffered to prevail. To comprehend rightly the observations and reasonings contained in : Py ‘ Fs ‘S ‘io~= oh FROM THE HIGHER ATMOSPHERE. 467 in the paper now. submitted to the Society, it will be hence expedient to take a retrospect of the facts which have been disclosed relative to the communication of heat, In framing this abstract, I shall abstain from all hypotheses, which might assist, only to deceive, the imagination, but content myself with stating the facts really ascertained, and with tracing out be sarwelgpicgean to which they distinctly lead. I have observed, that Heat never appears in a detached form. Yet its materiality is evinced, by the expansion which it invariably communicates to the substances with which it unites. _ While it is attracted by any bodies, therefore, it must introduce into them some repulsive force, which had previously existed among its own particles.. Heat must hence be a fluid of extreme tenuity, yet endued with an_ irresistible elastic force. . But when a substance, either from a chemical or. me- chanical impression, suffers a sudden change of constitution, and makes a copious discharge of heat, this emission is al- ways accompanied by an effulgent light. On the other hand, when the rays of the sun, or even those of a bright lamp, are intercepted by any body, and seem lost or extinguished, a corresponding increase of warmth is immediately betrayed at the absorbing surface. It follows from this and similar facts, that heat is the same fluid as light, only in a state of rest and combination. In short, heat is latent, invisible, light,— the agelov gus of the ancients,—which has been arrested in its rapid flight, and cannot again be liberated, without such a . violent change of condition, as will leave entire the repulsion of its own particles, to create the requisite projectile force. In ordinary cases, however, the light remains imprisoned in the substance with which it combines, and only migrates from one portion to another. ; aie 3N 2 The 468 ON IMPRESSIONS OF COLD The progress of heat through different bodies, depends on their peculiar constitution, and varies extremely in its rate. To examine this phenomenon more closely, it will be proper to distinguish the conducting media into the three classes of —solid—liquid—and gaseous. J. In the case of a solid conductor, if one end of a rod be heated, the effect will gradually advance, yet not with a con- tinuous flow, to the other end. If the rod were conceived to be distinguished into elementary spaces, each of these in the progress of communication must experience, within imper- ceptible limits, an alternate accession and reduction of heat, and must consequently first expand and then contract. In fact, it absolutely could not receive and deliver heat at the same instant of time, for a contemporaneous expansion and contraction—the necessary result—would imply an absurdity. But contraction naturally succeeds to expansion, as a part of the same vibratory impression. Those elementary conducting spaces, must therefore undergo an alternating hot and cold fit ; so that the communication of heat through a solid sub- stance, is performed by a series of minute articulate motions, resembling the progressive vermicular action by which the creeping insects are enabled to advance along the ground. The celerity of the transfer of heat through any solid is hence determined by the extent of such articulations, and the rapid succession of the internal oscillations ; which again depends on the elasticity of the conducting substance, modified by the influence of its density. 2. In the communication of Heat through liquids, an auxili- ary principle, originating in the internal mobility of the me- dium, concurs to accelerate its progress. The warmed portions of the fluid, acquiring expansion, rise upwards by their conse- quent FROM THE HIGHER ATMOSPHERE. 469 quent buoyancy, and spread over the surface. Ina short while, therefore, the heat is distributed through the whole liquid mass, in successive strata, from the bottom to the top. But liquids also conduct heat by a slow process in every direction, like solids. This protracted diffusion of influence, which is’ exert- ed in restoring the equality of temperature through the body of the liquid, succeeds to the operation of the principle of buoyancy. While the surface becomes again colder, the bottom grows gradually warmer ; the heat working downwards, by a continual transfer, from stratum to stratum, of the stagnant Flak sit v" ' The diffusion of heat, then, depends chiefly on the expan- sion and internal mobility of the liquid medium. Thus, alco- hol rapidly diffuses heat, while the viscid oils, especially at low temperatures, clog its motions. The circulation is in general quicker when the liquid is very warm, its expansibility, and’ its aptitude for internal: migrations being now increased. In-ap- proaching the boiling point, water expands largely by equal’ac- ‘cessions of heat ; but near congelation, its-expansions or contrac- tions are extremely small. The conducting power of water at a very low temperature, is hence nearly the same as if it were a solid, or remained motionless; the Same, in short, as if by the addition of isinglass, it were changed into a thin jelly. Such are the conducting powers which a liquid substance combines when at rest, or left merely to the play of its internal motions. But if made to flow in a stream, it will evidently, in consequence of the frequent renewal of contact, abstract heat more quickly from every warm solid body which is immersed in it. Thus, I find, that, in ordinary circumstances, water, advancing at the slow rate of a mile in three hours, will yet conduct away heat twice as fast as when quite stagnant. Consequently a cur- rent 470 ON IMPRESSIONS OF COLD rent of three miles an hour would accelerate tenfold the trans- fer of heat. It isof essential importance, however, to remark, that in all cases where the medium of communication is a liquid, the na- ture of the hot surface, whether vitreous or metallic, rough or polished, has no influence whatever m modifying the rate with which the heat is drawn off and dispersed. Thus, a hollow tin ball filled with hot water, will lose its heat just as fast when immersed naked in cold water, as if it were cover- ed with linen, or paper, or a coat of any sort of pigment. 3. Heat is transferred through a gaseous medium by a more complex process. It is partly conducted, as in the case of li- quids, by successive communication through the stagnant mass, joined to the more copious effect of the buoyant streaming of the heated portions of the fluid. But another auxiliary prin- ciple, depending merely on the nature of the heated surface, now comes into action. Let two equal hollow balls of bright thin silver, the one naked, and the other covered with a fold of cambric or paper applied closely to its surface, be filled with warm water, and sitspended in a close room. The former will be found to lose ii: parts of heat, in the same time that the latter sheds 20 parts. Of the heat thus spent, 10 parts, from each of the balls, are communicated in the ordinary way, by the slow recession of the particles of air, as they come to be successively heated by their proximity. The re- maining portions of heat, consisting of 1 part from the bright metallic surface, and 10 parts from the cambric, are pro- pagated through the aérial medium, by some peculiar pro- cess. In like manner, two equal hollow balls of glass, the one gilt with gold or silver leaf, being filled with warm water, and suspended in a room, the naked one will discharge 13 parts of heat, while the gilt one will lose only 7 parts; 6 parts be- ing spent by each, in the same way as if they had been im- mersed a SS” ee = FROM THE HIGHER ATMOSPHERE. 471 mersed jin a cold liquid, while the vitreous surface projects 7 parts, and the metallic surface only 1 part. The same dif- ferences depending on the nature of the superficial boundary, are observed to take place in the heating as well. as in the cooling of bodies. Thus, if the silver balls be filled with wa- ter colder than the:temperature of the room, they will acquire heat in the same proportions as they before lost it. The na- ked' ball will gain only 11 parts of heat, while the coated will receive: 20. parts , ; 9 10 But the air is still an: essential vehicle:of didi various im- pressions of heat or cold. An absolute: vacuum is unattain- able'in Nature ; but the dispersive effects are always diminish- ed, though slowly, by rarefyimg the medium. Thus, when the: air is rarefied about 200 times, the abductive power from the glass balls will be reduced from 6 to 14; while the peculiar discharge of heat at the naked surface is lalepititindd from 7 to 5, and that at the gilt surface from 1 to 2; the: naked ball now i 62 parts of heat, and’ the gilt one only 23. > ns ocThe: offsite ‘are baliemisatiad a differ ent gaseous. mmadium, Thus; dae same balls, with a vitreous and a metallic surface; would discharge 31 and 25 parts of heat, if immersed in hydrogen: gas ; both of them now losing. 24 parts by the powerful abduc- tion of this gas. But: if the medium be rarefied. about 200: times, the’ quantities of heat emitted, from the naked. and the: gilt ball will be hae ane to 13 and 83.. As igesfinedoe oe ate or, still ‘ines one of ‘inert paper, or vegetable pigment, projects. heat the most ‘copiously ; so those- surfaces likewise intercept the impressions most effectually. But a bright metallic surface detains only the tenth part of these- impressions, and reflects all the rest. Hence the power of a me- tallic speculum, contrasted with that of a glass mirror, in con- centrating ° 472 ON IMPRESSIONS OF COLD centrating the heat or cold projected from any remote body. Hence also the construction of the Pyroscope, a delicate instru- ment, adapted to distinguish and measure those peculiar impres- sions of heat or cold. It-consists of a differential thermometer, having one ball naked, and the other coated with gold or silver leaf; this metallic surface reflecting the greatest part-of the projections, while the vitreous surface absorbs almost the whole effect. Ifa broad plate of glass be interposed before a cubical canister holding hot or cold water, the action on the pyroscope, though concentrated by a reflector, will yet'be very much redu- ced. But, on removing the plate farther from the canister, and therefore nearer to the reflector, this action will be still more diminished ; so as at last to become.almost extinguished. Hence the projected influence of heat or cold consists not in any streaming matter, for the same proportion of the warm or fri- gid rays would evidently be intercepted by the glass screen in whatever part .af the route between the canister and the re- flector it was planted. But the question is completely decided, by varying the ex- periment. Let two glass plates be covered, each on one side with tin-foil ; applying the metallic surfaces now together, place the double sereen immediately before the hot canister, and the effect on the pyroscope will be greatly reduced ; re- verse the position of the plates, by exposing the coated sides, and the action on the sentient ball will be entirely extinguish- ed. The interposition of a screen would in every case detain the whole impressions, if it did not itself become affected by | them, and therefore come to act as a secondary but feeble pro- jecting surface. Hence the different influence of a metallic screen, in comparison with one of glass or paper. The impressions of heat or cold emitted from a body are not sent equally in all directions. Those projected perpendi- cular FROM THE HIGHER ATMOSPHERE. 473 cular to the surface of a cubical canister containing either warm or iced water, are the most intense, and the rest appear to di- minish in the ratio of the sine of obliquity. Hence the action exerted on the sentient ball of the pyroscope, is always pro- portional to the visual angle subtended by the propellent sur- face. Nor are those i impressions necessarily propagated in straight lines. If connected rings of pasteboard be fashioned into a sort of cornucopia, its mouth being directed towards the fire, notwithstanding the twisted form of the passage, a very consi- derable action will be indicated on the ball of the pyroscope, presented at the narrow end. From all these combined observations it follows, that the portion of heat or cold, of which the discharge depends on the quality of the surface, is propagated by the vehicle of its gaseous medium, though not by any actual streaming of fluid matter. No alternative then remains, but to admit that the impressions of heat or cold are conveyed through the air with a spreading and progressive tendency, in the same, manner as the pulses of sound. The aerial medium, by a series of internal oscillations, successively transfers its charge, and delivers an impression at the end of the chain of communication, of the same kind pre- cisely as it had received at the beginning. This rapid transmission of Heat to a distance from its source, has been hastily termed radiant, and various inaccurate concep- tions are entertained concerning its mode and extent of action. 1. In the first place, then, the process now described never ob- tains, unless where a difference of temperature occurs ; and it only contributes, along with other active causes, to restore the equilibrium of heat. 2. But, in the next place, it has in every case a subordinate share only in the diffusion of heat. When the air is perfectly still, and of the ordinary density, the tide of heat vibrated from a vitreous surface amounts scarcely Vou. VIII. P. II. 30 to 474 ON IMPRESSIONS OF COLD to half of the whole discharge, and from a surface of polished silver, it exceeds not the twentieth part of the entire expendi-_ ture. But such are the accelerating effects of a current. of air, that, in a high wind, the pulsations of heat darted from a vitre- ous and a metallic surface may not form the twentieth and the two hundredth part. In a medium of hydrogen gas, those pulsations are comparatively feebler, reaching, in the case of a stagnant atmosphere, only to the eighth or the eightieth part of the full discharge, with a proportional diminution when the af- fected surlace is exposed to the action of a current. The influence of the pulsatory: emission of heat or cold, has, therefore been greatly exaggerated. It comes merely as an auxi- liary to the other modes of restoring the equilibrium of the ig- neous fluid, and it often contributes a very small share only to- wards the general effect. But whenever a body, left to itself in the atmosphere, is observed to change its temperature, some pulsatory action may be presumed to combine with the OY he eS Mm — operation. It is easy, in any case, to ascertain the real direction of the aérial pulses. Whether a substance acquires or loses heat, it al- ways approaches to the temperature of the ambient medium by the very same process. The hot or cold pulses are pro- jected from this approximating surface with an expansive sweep. ‘On the contrary, when a body maintains either a higher or a jower temperature than that of the surrounding atmosphere, like the sentient ball of the pyroscope in the focus of a re- Hector fronting a charged canister, it receives and absorbs the impressions vibrated at a distance. ‘the intervention of a pa- per screen does not prevent the spontaneous emission of hot or cold pulses, but will effectually obstruct their passage from a remote object. . Some theorists have imagined, that the escape of heat re- ? ; . np ees vil quires free space or vacuity. But a body will either.lose gain lt rte os cag FROM THE HIGHER ATMOSPHERE. 475 gain heat with the same facility, in a small closet, as in a spa- cious room. Let a glass ball of 3 inches in diameter, and filled with hot water, or a frigorific mixture, be suspended in the centre of a balloon of 18 inches in diameter, and it will be found to change its temperature almost at the same rate as in a close apartment. If the balloon were much smaller, however, the effect would become sensibly diminished, because the whole of the included air, being rendered somewhat hot- ter or colder than before, would excite a feebler action at the surface of the ball. A similar modification would take place if the ball were formed of hollow silver. Yet this large shell of glass evidently forms a complete screen, which will absorb all the impressions emitted within it. The sun is the great fountain of that heat which vivifies our planet. Of the solar beams, part are detained in their passage ‘through the atmosphere, and the rest are absorbed at the sur- face of the earth. From experiments with the photometer, it follows, that, even when the sky is most serene, only one-half of the sun’s light, sloping at an angle of 25°, will reach the ground ; and that, at an angle. of 15°, the proportion is redu- ‘ced to one-third ; but with an obliquity | of 5°, only the twen- tieth part of the whole can gain the surface. The effect of this absorption during the day, is to raise the temperature of the external crust of the globe. Very few of the incident rays are again reflected from the surface. An expanse of sand, or even of chalk, however offensive by its white glare, yet scarcely sends back a fifth part of the light into the mass of air. A green sward, or a dark soil, absorbs almost the whole of the lumi- nous particles. Of the heat thus accumulating at the earth’s surface, a imal portion penetrates into the soil, but the greatest share is dispersed by communication to the ambient air. In the progress of the 302 } day, 4716 ON IMPRESSIONS OF COLD day, therefore, the ground always becomes warmer than the incumbent stratum of atmosphere. This: effect is greatest in the tropical countries, where the sun gains a higher altitude, and pours his light in a full stream. Winds very mate- rially check the accumulation of heat at the surface, and the calorific action is besides diminished in cloudy weather. A ploughed field is more affected by the sun’s rays than a grassy plot, since a loose or spongy superstratum, by exposing multiplied surfaces, dissipates more quickly the impressions of heat communicated to it. The best mode of examining the difference between the tem- perature of the surface and that of the incumbent air, is by means. of a pendant differential thermometer, from one to three feet in length. It consists of a ball and long stem, to which ano- - ther similar ball, with a short portion of tube, having its bore swelled into a narrow cylindrical reservoir, is hermetically join- ed. The reservoir exceeding not the tenth of an inch in dia- meter, detains and supports the tinged sulphuric acid by its capillary attraction, (see fig. 5. Pl. XL) This instrument be- ing suspended in a vertical position, the lower ball approach- ing or resting on the ground, while the upper ball, at a moderate” elevation S, is enci ‘cled by the incumbent stratum of air, the rise of the coloured liquor in the stem will mark the excess of warmth below, and indicate very minute dif ferences of temperature. Last summer I made some ob servations of that sort, but not so extensive as I have since projected. The effects were found to be extremely various. In sun-shine, and calm, weather, the ground was sometimes thirty millesimal degrees warmer than the air only a few inches above it *. But when the sky happened to be much overclouded, or when strong winds swept over the surface, the eo SN aa ee ee ee eS * It may be proper to repeat, that, in all the combinations of the differential thermometer, the divisions of the scale are made to correspond with the thousand parts of the interval between freezing and boiling water. oe PLATE XI. i Secreyy Tran. Vol VT Page 476 ] Eng hy WED Liars Bane FROM THE HIGHER ATMOSPHERE. 477 the accumulation of heat would sometimes hardly reach to three degrees. Under like cireumstances, but especially when the air was still, the differential thermometer indicated more than twice as much effect on fresh ploughed land as on fine pasture. Nor was this inferiority of a surface of turf owing to the waste of heat produced by a more copious exha- lation of moisture; for, on spreading a layer of dry hay, or even wool, over a part of the naked soil, the temperature of it was in a: few minutes reduced to the same degree as that of the. grassy sod.. The influence of reflex light, from the clouds and the sky, in heating the ground, is often very considerable. The rays sent from a fleecy canopy may sometimes amount to the half or the third part of those which would be received directly from the sun.. But a stratum of dense black clouds intercepts almost the whole of the scattered light. A similar effect: is produced by another. sort of screen. Thus, when. the sky. was overcast, but the wea- ther calm, the: pendant differential thermometer intimated scarcely two degrees of heat at the surface, in a small fir wood; but marked eight or ten degrees, when carried to a neighbour- ing glade. ) In this climate, about two hours after sunrise, the-ground kas the same temperature as the incumbent mass of air, but grows commonly warmer than it, till nearly two-hours after. noontide; from which time, it again declines, and becomes relativel y cold- er than the air, perhaps two hours: before sunset ; sinking still Jower during the night. The differences are thus comparative- ly very small between the temperature of the ground and that of the conterminous air, seldom exceeding the fifth, or perhaps even the tenth part of the whole diurnal change. The hot or cold pulses discharged from the ground, must, therefore, in all cases, be only trifling, and quite insufficient to produce that rapid approximation to an equilibrium which is actually observed. I was 478 ON IMPRESSIONS OF COLD was hence still inclined to think, that the statement which I had’ formerly made, of the existence of an ascending warm current in the atmosphere, combined with a descending cold current, was adequate to the explication of all the phenomena. It is: obvious, indeed, that the lower portions of air, becoming heat- ed, in the progress of the day, by their contact with the ground, must rise upwards, and their place will consequently be sup- plied, by like portions of cold air which descend from the high- er regions. These opposite currents, though set in motion du- ring the flood of light, will continue their play long afterwards, perhaps through the greater part of the night, till again vigo- rously excited by the presence of the sun. Hence the ground is only heated to a certain limit during the day, and grows al- ways colder as the night advances. But my late ingenious and learned friend Dr Wexts, by the. publication of his Essay on Dew, which contains some acute ob- servations, conjoined with a few striking experiments, though performed in the gross way, had contributed to revive the no- tion of a copious radiation, or pulsatory discharge of heat from the earth’s surface. It was, therefore, desirable to ascertain the existence and real extent of such pulsations. The accu- rate means of determination were within my reach, though I had hitherto, in a great measure, neglected their application ; for though the pyroscope measures those impressions with great delicacy in a close apartment, it is liable out of doors to some derangement from the influence of light, and has its ac- tion diminished by the sweep of violent winds. To avoid as much as possible these disturbing influences, I constructed a small pendant pyroscope, the lower ball being left naked, and the upper ball gilt with silver-leaf, to reflect almost the whole of the incident light. This instrument I fixed to a short arm, made to slide along a staff which could be stuck in the ground, In the month of August last, I carried it, with some other FROM THE HIGHER ATMOSPHERE, 479 other apparatus, into the country, for the greater convenience of making observations. This pyroscope being let down with- in a few inches of the ground, generally indicated an impres- sion of heat during the day, seldom exceeding, however, three er four millesimal degrees. But I remarked, with surprise, in more than one instance, that towards evening, when the sky be- came clearer, the liquor would fall a degree or two. Yet the ground was still warmer than the air, and ought consequently to have augmented, rather than diminished, the calorific pulsa- tion. \ I now began to suspect that an opposite impression was somehow showered from the atmosphere, and therefore set about examining the subject closely ; though a tract of cloudy and boi- sterous weather greatly retarded my inquiries. I fitted, a little below the sentient ball of an ordinary pyroscope, a small circu- lar: plate of tin, hammered into aslight concavity. The instru- ment, having its action thus more than doubled, put the main fact beyond.all doubt. The object now was to discover, if those cold pulses shot downwards from an azure sky, were subject to variation, and whether they prevailed during the day, as well as at night. I had a segment of a sphere hammered ont of tin, about nine inches wide, and three inches deep, with a vertical arch, to which the pendant pyroscope was attached, the sentient ball being placed in the middle between the centre and the bottom. But the indications were not altogether satisfactory, owing partly to the influence of strong light, though chiefly to the disturbing effects of the violent winds which happened then to prevail. I therefore resumed the erect pyroscope, and augmented its action, by adapting under the sentient ball an eee pnerieal tin-cup of about 2 inches in diameter. To screen the instrument from the sun and the wind, I placed it in the middle of a wide earthen pitcher set behind a north wall. The weather 480 ON IMPRESSIONS OF COLD weather being very unsteady, I had to watch the intervals of an opening sky. Covering the mouth of the pitcher with a pane of glass, the pyroscope would sometimes indicate one or two degrees of heat ; but, on removing that screen, it always mark- ed impressions of cold amounting perhaps to five or six de- grees, as often as the clouds parted, and left a blue space near the zenith. The continual darting, by day and night, of cold pul- sations from the sky was thus ascertained; and nothing seemed wanting but to improve the construction of the instrument, and ~ render it commodious and portable. I resolved to inclose both balls within the same cavity ; the lateral ball being gilt, and of the same colour as that of the annexed reflector;.and the naked sentient ball being placed in the focus. By this disposition, the influence of light was almost completely destroyed, its ac- tion being made equal on both the balls. But, to protect those balls from the disturbing effect of wind, it was requisite, that the cup containing them should be deep and rather nar- row. If the cold pulses to be measured were darted only in a vertical direction, the parabolic conoid would certainly be the proper form of the reflector. I was convinced, however, from some imperfect trials, that such impressions were likewise sent down at different angles of obliquity. Supposing their inten- sity to be equal in all directions, an hemispherical reflector would answer best. But the focus, instead of a single point, would then have branched into the diverging arcs of the caustic curve, and the sentient ball of the pyroscope would have required half the dimension of the reflector itself, (see fig. 11. P]. XI.) The main cbject, however, was to measure the impressions received from the upper portion of the atmosphere, that part near the horizon being generally obstructed by clouds or vapour. I therefore a- dopted an intermediate plan, and selected for the reflector a trun- cated oblong spheroid, cut through the upper focus by a plane per- pendicular 4 FROM THE HIGHER ATMOSPHERE. 481 pendicular to the axis, and having the sentient ball of the py- roscope placed in the lower focus, (see fig. 2, 3. and 4.) It is evident that the impressions which pass through the first focus in every direction, must be reflected towards the second focus. But since the upper focus occupies the middle of the aperture, all the cold pulses which enter the spheroid will be nearly col- lected on the sentient ball of the pyroscope. The more oblique impressions, however, striking the sides of the reflector at a greater angle of incidence, will be less copiously reflected ; and consequently this compound instrument will indicate more fully the action of that quarter of the heavens to which it is turned. Of these truncated spheroids, I had two made of planished tin; the one being eight inches high, with an extreme width of the same, and its focus two inches from the bottom; and another nine inches high, and six inches broad.; the focus be- ing only an inch from the bottom. I had one or two more reflectors, constructed of plated copper, after the same forms, but with only half those dimensions. The more eccentric spheroid being mounted on pivots, was better fitted to. explore any particular portion of the sky, (see fig. 2. Pl. XI); To this inquiry my attention. was now drawn. Watching when the sky appeared most serene, I directed the instrument, first to the zenith, and then. successively declined it, till it came within. twenty degrees of the horizon. But the instrument continued to indicate the: same frigorific impression, or about forty or fifty millesimal degrees: at all inclinations. It was, therefore; ascertained, that the action of a given section or angular por- tion of the sky, is the same at every obliquity.. With the erect spheroid, I found, in cloudy weather, that the: frigorific impression diminished, in proportion as the humid mass, floating in the atmosphere, seemed to descend. When the sky was canopied with high fleecy clouds, the effect on the Vor. VIII. P.IL 9 instrument 482 ‘ON IMPRESSIONS OF COLD instrument might amount to twenty degrees ; but when the congregated vapours sunk so low as to hover on the hilly tracts, the impression would frequently not exceed five degrees. It was evident, therefore, that the effect depends on the altitude of the lowest range of clouds, and might seem to result wholly from the difference of temperature which prevails there, com- pared with that of the surface. But the same conclusion was drawn from another set of ob- servations. In a calm day, when a mass of dark clouds was spread at no great elevation above the surface of the ground, the spheroid indicated only five millesimal degrees in a verti- cal position, and yet marked still the same quantity, when de- pressed to an angle of thirty degrees above the horizon. But had this impression of five degrees penetrated directly through the clouds, from the higher regions of the atmosphere, scarce- ly one-half of a degree could have escaped through the mass of vapours by the oblique passage. A range of clouds hence acts as a complete screen, absorbing and extinguishing all the hot or cold pulses received on it. Since clouds consist merely of dispersed aqueous globules, their influence, I conceive, may be safely inferred from that of water itself. I therefore inclosed an inverted pyroscope in a spheroidal cup, and suspended it a few feet above the ground, while the sky appeared clear and blue, (see fig. 7. Pl. XL.) ; then passing a silver tray under it, the reflected impression of cold amounted to twenty-five degrees: on interposing a plate of glass, this was reduced to two degrees ; but on removing it, and pouring a sheet of water over the silver, the effect was absolutely extinguished. Most of these observations and experiments were made du- ring the months of September and October 1817 on the top of the Tower at Raith,—a spot very favourable for such researches, and FROM THE HIGHER ATMOSPHERE. 483 and endeared to me by many pleasing associations. The re- sult of them has been the construction of a delicate instrument, which will be deemed, I hope, a valuable accession to meteo- rology, and indeed to physical science in general. From the term «aiéeioc, which, in reference to the atmosphere, signi- fies at once clear, dry and cold, I have appropriated the name of ithrioscope to this new combination of the py- roscope. The sensibility of the mstrument is very striking, for the liquor incessantly falls and rises in the stem with every passing cloud. Under a fine blue sky, it will some- times indicate a cold of 50 millesimal degrees; yet on other days, when the air seems equally bright, the effect is only 30°. The causes of these variations are not quite ascertained. The action is in general greatest under a clear and translucid at- mosphere. But particular winds, blowing at different altitudes, seem to modify the effect, and so may perhaps the transition. from summer to winter. There are three principal forms of the Athrioscope: 1. Erect: 2. Sectoral ; 3. Pendant. 1. Erect.—All the requisite conditions for measuring the at- mospheric impressions are attained, by adapting the pyroscope to the cavity of apolished metallic cup, of rather an oblong spheroidal shape, the axis having a vertical position, the lower focus being occupied by the sentient ball, while the section of a horizontal plane; at the upper focus, forms the orifice, (see fig. 3. Pl. XL.) The cup may be made of thin brass. or sil-. Very. either hammered or cast, and then; turned and polish-. ed on a lathe; the diameter being from two. to four inches, and’ the eccentricity of the elliptical figure varied. within. certain li- mits.according to circumstances. The most convenient propor- tion, however, is, that the eccentricity should be equal to half. the transverse axis, or that the focus should be placed at the 3P2 third’ 484 ON IMPRESSIONS OF COLD third part of the whole height of the cavity, the diameter of the sentient ball having likewise nearly the third part of the diame- ter of the orifice of the cup. In order to separate the balls of the pyroscope, the gilt one may be carried somewhat higher than the other, and lodged in the swell of the cavity, its stem being bent to the curve, and the neck partially widened, to prevent the risk of dividing the coloured liquor in carriage. The instrument. is adjusted to its position by a clasp which slides along the stalk. A lid of the same thin polished me- tal as the cup itself, is fitted to the mouth of the ethrioscope, and removed only when an observation is to be made. The scale may extend to 60 or 70 millesimal degrees above the zero, and about 15 degrees below it. 2. Sectoral.—To ascertain and measure the cold pulses shot obliquely, as well as those in the vertical direction, the zethrio- scope may be constructed to turn towards any portion of the sky, (see fig. 1. and 2. Pl. XI.) To effect this, the form best fitted for reflexion would be that of an hyperbola, whose asymptotes have an inclination equal to the visual angle of the space to be explored. Fig. 1. may give an idea of the construction. But to obtain accurate results, the focal ball must be small, and the hyperbolic conoid wide and much extended. It will answer nearly the same purpose, however, to adopt a truncated sphe- roid, of great eccentricity. Let the height of the focus, for in- stance, be one inch, that of the entire cavity nine inches, and, consequently, the widest diameter six inches. The shape re- presented in fig. 2. is rather more distended, its extreme width being equal to double the eccentricity, and the focal ball dividing the height of the orifice in the ratio of 1 to 3+ 8,or of 6 to 35 nearly. The pyroscope inserted has a peculiar twist- ed form, and receives its adjustment from a moveable socket. While the sentient ball remains always in the same position, the FROM THE HIGHER ATMOSPHERE. 485 the axis of the instrument can, by means of a screw acting on the limb of a quadrant, be depressed or elevated to any given angle. But the effect will chiefly be produced by the direct impressions: for the lateral pulses, striking less obliquely against the cavity of the spheroid, will be feebly reflected. This moveable axthrioscope was placed in a convenient si- tuation out of doors, when the sky appeared free from clouds, and had assumed a clear blue tint. The spheroid being turn- ed first upright, the effect was noted ; but this continued still unchanged, on depressing the axis successively, till it had ap- proached the limit of energetic range, or within 20 degrees of the horizon. From every portion of the sky that subtends a given visual angle, there is hence received the same quantity of the frigorific pulses. But such would likewise be the result, if they were showered from the horizontal surfaces of the successive strata which divide the atmosphere ; since, although the intensity di- minishes in the ratio of the sine of obliquity, a propellent space broader in proportion is, for each elemental angle, brought into action, as appears from the inspection of Fig. 10. Let BC represent the boundary from which hot or cold pulses are darted: A being the point at which these are recei- ved, let BS and Ce denote minute portions of the vibrating surface. A perpendicular Ck to AC would send impres- sions in the direction CA, equal to those emitted by Ce. But that the effects produced at A, from the projections of Ck and Bd should be equal, the distances CA and BA must be pro- portional to those breadths ; wherefore the triangles CA & and BA 6 are similar to the elemental angles CA c and BA d equal. It hence follows, that the impressions sent from a cluster of such angles, amounting perhaps to ten or fifteen degrees, near the vertical position, are equal to those contained within the. same aggregate angle in an oblique direction. This entire agreement : 486 ON IMPRESSIONS OF COLD agreement between theory and observation is most satisfac- tory. 3. Pendant.—The zthrioscope might be reduced to a small- er and more compact form, by conjoining with it a pendant differential thermometer. Neither of the glass balls in this case requires to be gilt. But of the Pendant A‘thrioscopes there are two varieties. In the first, the balls of the pyroscope are enclosed by hemispherical brass cups. (See Fig. 6. Plate XI.) These, however, may be a little deeper, forming seg- ments about 10 or 15 degrees more than the hemisphere. The pyroscopic balls, with two-fifths. of the diameter of the cups, should be placed in the middle, between the centre and the bottom. In the second variety, the lower ball of the pyro- scope is encased by a hollow sphere of brass, composed of two pieces which screw together, and the upper ball occupies the focus of the cup, which needs scarcely be more than two inches wide. (See Fig. 4.) This variety of the instrument is more portable than any of the rest, and equally accurate; but owing to the brass casing, it is, under a change of temperature, rather slower in its action. The construction is rendered still more commodious, by having the stem of the differential thermome- ter inserted through a projecting circular piece, somewhat lar- ger than the upper ball, which screws into a perforation at the bottom of the cup, and then forms part of the same reflecting cavity. This arrangement allows not only the standard of the :nstrument to be occasionally detached, but also the cup itself, _-a circumstance at once conducive to the safety of carriage, and to the preservation of the metallic lustre and polish, On replacing the metallic lid, the effect is entirely extin- guished, and the fluid in the stem of the differential thermo- meter immediately sinks to zero. A cover of pasteboard has at first precisely the same influence ; but after it has itself be- come chilled by this exposure, it produces a small secondary ac- tion FROM THE HIGHER ATMOSPHERE. 487 tion on the sentient ball, scarcely exceeding, however, the tenth part of the entire and original impression. A lid of glass or of mica intercepts the impressions like one of paper ; for the admis- sion of light has no deranging effect, ifthe athrioscope be rightly constructed and highly polished. The minute secondary ac- tion is almost ‘extinguished, if screens of paper, glass, or mica, be held at some distance above the mouth of the instrument. The variety composed of two hemispherical cups will answer, as an inverted zthrioscope, for measuring, at some elevation, the warm pulses sent up from the lower strata. It is only re- quisite to cover the upper hemisphere during the observation with its metallic lid. ‘The same form of the instrument might likewise conveniently be employed, when its altitude is not very considerable, to determine the difference of the tempera- ture of the surface of the earth, or of the sea, from that of the superincumbent stratum of air. This difference, it would ap- pear, from some unfinished observations which I have made, is expressed, on Fahrenheit’s scale, by two-thirds of the millesi- mal degrees indicated by the compound pyroscope. Nor is this effect sensibly altered by the proximity of the terminating surface, because its indefinite expansion will always present nearly the same visual angle. Hence the relative temperature of the surface of the sea, may be easily discovered from an eethrioscopical observation performed at the stern or the prow of a ship while under full sail. In the Pendant Atthrioscopes, both the glass balls are left naked ; but, in the Erect and Sectoral kinds, the lateral ball is always gilt. This condition, however, is not essential, since the concentration at the focus would be sufficient, by its excess alone, to produce an adequate effect. Hence the observations may be varied, by introducing within the reflector a differential thermometer, either consisting of translucid balls, or composed of balls blown from black glass. When the latter kind is used, the 488 ON IMPRESSIONS OF COLD the liquor will indicate merely the difference of opposite ef- fects, and will rise or fall according as the impressions of cold or heat sent from the sky chance to predominate. If the light reflected down from the heavens be profuse, it will excite more heat than the simultaneous frigorific impressions can de- stroy. Under a canopy of fleecy clouds, a considerable excess of heat is hence excited on the black ball ; but when the sky is clear, the influence of cold generally prevails, increasing as; the sun declines. The question is now to discover the cause of the phenomena which have been thus revealed. I have already stated, that different experiments appeared to concur in indicating the cold- ness of the superior atmosphere as the source of those effects. Since pulses are darted from such various surfaces, and since the softness of the external coat, and its tendency to fluidity, seem vastly to augment their power ; may they not likewise be excited from a boundary of air itself? This extension of a great principle in the economy of Nature, has never yet been surmised ; nor can it be readily brought to the test of direct experiment, since a body of air, whether hotter or colder than the general medium, would evidently not remain station- ary, but continually rise or fall. I sought accordingly to examine the effect of directing the zethrioscope to a hot stream of ascending air. I placed on bricks before that instrument, the lower part being screened, a large ~ mass of iron carried from the fire, at almost a red heat. The zthrioscope then gave impressions of heat or cold, ac- cording as its aperture was without or within the warm cur- rent, or was affected by the anterior or the posterior boundary. But this experiment proved very troublesome, and occasionally turned out alittle unsatisfactory. Another experiment per- formed out of doors, to try the action of hot smoke raised from a omy i—_ ve Ss EY aver 4S" ine saith FROM THE HIGHER ATMOSPHERE. 489 a train of damp straw set on fire, was, from the difficulty of managing it, found to lead to no certain conclusion. But during winter, a much easier mode occurred for decid- ing the question. In a room where a steady fire was kept up, the sectoral aethrioscope was set on the inside of the window, and directed to the upper part of the opposite wall; but on throwing up the window, the instrument being now surround- ed by a body of cold air, which, however, did not penetrate far into the room, the liquor sank 5 or 6 degrees, indicating im- pressions of heat, caused evidently by the excess of tempera- ture of the remote air of the room above that which was con- tiguous to the aethrioscope. It need hardly be observed, that the effect increased in colder, and diminished in milder, weather. A similar experiment is readily performed by help of the erect zthrioscope. In a close apartment, where a good fire is con- stantly kept up, the ceiling and the floor may be discovered by the pendant differential thermometer to have exactly the same temperature with its adjacent stratum of air. Yet the upper portions of the confined air of the room will be found several degrees warmer than the lower. Instead of being divided only into opposite ranges, the whole mass, from the floor to the ceil- ing, will, in consequence of the expansion and buoyancy of its heated particles, form a series of intermediate strata, not dis- tinguished, however, by any very precise boundaries. But the intensity of action being proportional to the difference of tem- perature, the effect on the zthrioscope must evidently be the same, whether it is produced by a single set of large pulses or by several sets of smaller ones. If, for example, instead of one bounding surface, above which the air is seven degrees warm- er than immediately below it, we suppose seven such boundaries, each having an excess of temperature of only a degree: the pulses excited at the first of these intermediate surfaces, and ‘successively augmented as they reach the second, third, and Vor. VIII. P. If. 3Q fourth, 490 ON IMPRESSIONS OF COLD fourth, &c. surfaces, will at last acquire the same energy as if the ageregate difference of seven degrees had been all exerted at once. Thus, the under surface of the stratum G (see fig. 2. Pl. XI.) darts pulses downwards, which, being augmented in succession at the under surfaces of the strata I’, E, D, C, B, and A, may have finally the same intensity as if they had originated from the opposition of the extreme strata G and A. Accord- ingly, having planted a large screen immediately before the fire, and placed a delicate pyroscope about the middle of the room, with a broad circular piece of metal suspended a few inches above it; on withdrawing this canopy after some time, the instrument indicated a small impression of heat, seldom exceeding, however, one degree. But the effect may be ren- dered more sensible, by a moderate concentration of the power excited. Thus, the hemispherical pendant athrioscope (fig. 6.) will, in the same situation, mark a very sensible calorific impres- sion, amounting, at least in ordinary cases, to three or four degrees. Hot pulses are, therefore, actually shot downwards from all the upper strata of the confined air of a room in which a fire is kept steadily burning. The experiment can be likewise reversed. Let an inverted zthrioscope, composed of a pendant differential thermometer, have its sentient ball fitted with a small hemispherical cup which is turned downwards, (see fig. 7.) This instrument being set on the floor, will remain at zero ; but if lifted only a few feet, it will indicate a visible impression of cold received from below, which will increase to three or four degrees when the zethrioscope is suspended near the top of the room. Wherefore, the upper surfaces of the successive decumbent strata, being comparative- ly colder, send upwards a series of chilling pulsations. Each of the conterminous boundaries appears thus to perform a double operation, ‘shooting downwards impressions of heat, and darting upwards equal impressions of cold. Such a mutual exchange PSS oe FROM THE HIGHER ATMOSPIERE. 49] exchange of influence must evidently tend to accelerate that progress to an equilibrium which the gradual intermixture of the different strata, if left quite undisturbed, would in time produce. The air of a close apartment, exposed to the action of a steady fire, is hence kept agitated through its whole mass by a series of opposite tremors, which continually disperse, in all directions, the irregularities of temperature. _ If the action of the pulses excited in the air of a small room be made thus apparent, how much more striking should we expect to find the effect produced by the mingled tide of commotion collected from the vast body of the atmosphere itself? Taking even the lowest range of strata, to the height perhaps of two miles, including scarcely one-third part of the whole aérial mass, the difference of temperature between its extreme boundary will amount to 20 centesimal degrees, or 36 on Fahrenheit’s scale. The order of the series, however, is exactly the reverse of what takes place in a close room, the air of the superior regions being invariably colder than at the surface of the earth. Accordingly, the simple pyroscope, ex- posed in calm weather to a clear and open sky, will, at all times, if not disturbed by the influence of a strong light, indi- cate large impressions of cold, amounting to 5 or perhaps even 10 degrees. In most cases, it may be sufficient to screen this instrument from the direct action of the sun’s rays. But the ac- tion of light will be almost neutralized, by opposing a diapha- nous ball to one gilt with silver, or contrasting a ball of the different shades of green or blue, to another coated with pure gold leaf. But to procure consistent results, it is still more necessary to guard against the deranging influence of winds. The same sectoral form of the athrioscope discloses also the peculiar influence of clouds in obstructing the frigorific pulses excited in the atmosphere. When the sky was completely ob- scured by a dense canopy of clouds, the instrument being 3Q2 pointed 492 ON IMPRESSIONS OF COLD pointed to the zenith, marked only five millesimal degrees ; but, on lowering it successively to the angle of 30 degrees above the horizon, it continued to indicate still the same effect. Water almost completely absorbs the pulsatory impressions of heat or cold ; and may not clouds, consisting of diffuse aque- ous particles, produce a similar effect ? But the feeble action of five degrees, amounting scarcely to the eight part of what is observed in clear weather, could not be any remnant of the pulses from the higher celestial regions, which had penetrated through the mass of vapours ; because, if the vertical transit, through the obstructing range, allowed only an eighth part to escape, the oblique passage of 30 degrees, redoubling the ex- tent of absorption, would have reduced the final discharge to five-eighths of a degree. The impression measured by the zthrioscope, in this case, must therefore have originated wholly in the strata of air between the under surface of the clouds and the ground. But in that narrow space, the extreme diffe- rence of temperature would be comparatively small. Hence the frigorific action is found always to diminish as the clouds descend. Nor does their variable denseness appear materially to affect the result, which is often the least, when a very thin, whitish, but low vapour, gathers in the atmosphere. Hence the ethrioscope might, with great facility, be employed in es- timating the altitude of clouds. As the higher strata of the atmosphere thus dart cold pulses downwards, so the lower strata must evidently project equal pulses of heat upwards. But to measure these, it would re- quire, as in fig. 7. the zthrioscope to be inverted and furnished with a pendant differential thermometer. The instrument, now carried to the top of a lofty mountain, and directed to the plain below, would indicate a considerable impression of heat, nearly proportional to the quantity of ascent ; and, therefore, amount- ing, for example, on the summit of Chimboraco, to perhaps 20 millesimal FROM THE HIGHER ATMOSPHERE. 493 millesimal degrees. But, in the same situation, the common z- thrioscope might, be expected to mark an impression of cold from above, as just so much diminished. No opportunity, however, has yet occurred, on a large scale, for making these interesting observations. The ascent of a balloon would afford the readiest mode of verifying and extending the theory. | . The nature and intensity of the cold and hot pulses excited in the several strata of the atmosphere, may be easily under- stood from (fig. 9. Pl. XI.) Let two equal and opposite circles touch the straight line AB, which divides a stratum of cold, from another of warm, air.. While the opposite dia- meters CD and Cd represent the forces of the perpendicular pulses of cold darted downwards, and of heat shot upwards, the chords CE, CF, CG, and CH, and Ce, Cf, Cg, and Ch, will likewise exhibit the strength of the Pulees which are transmit- ted with various obliquity. - The:inverted zthrioscope likewise disiayews the quality and measure of the pulses projected from the ground. These, in general, are: very feeble, seldom in this:climate exceeding three or four degrees. In the progress of a bright day, as the ground grows warmer than the incumbent air, it excites hot pulses ; but, as the sun declines, the effect gradually diminishes ; till this again returns, increasing with a contrary character, when the surface of the earth has become relatively colder. The same instrument being suspended a few feet above the ground while the sky appeared clear and blue, a silver tray was laid upon it, and the reflected impression of cold amount- ed to 25 degrees ; but, on interposing a plate of glass, it was re- duced to two degrees; and on removing this, and pouring a sheet of water over the silver, the effect was absolutely extin- guished. The absorbent influence of water, and consequently of clouds, was thus distinctly shown. The 494 ON IMPRESSIONS OF COLD > The zthrioscope thus opens new scenes to our view. It ex~ tends its sensation through indefinite space, and reveals the condition of the remotest atmosphere. Constructed with still greater delicacy, it may perhaps scent the distant winds, and detect the actual temperature of every quarter of the heavens. The impressions of cold which arrive from the north, will pro- ‘bably be found stronger than those received from the south. But the instrument has yet been scarcely tried. I am anxi- ous to compare its indications for the course of a whole year, and still more solicitous to receive its reports from other cli- mates and brighter skies *. All those effects are no doubt more conspicuous in the finer regions.of the globe. Accordingly, they did not escape the ob- servation of the ancients, but gave rise to opinions which were embodied in the language of poetry. The term Azg was ap- plied only to the grosser part of the atmosphere, while the highest portion of it, free from clouds and vapour, and border- ing on the pure fields of ether, received the kindred appella- tion of Aide. But this word and its derivatives have always been associated with the ideas of cold. The verb c&asbeimZm is adopted by Athenzeus, to signify the cooling of a body by mere exposure * In this stage of the inquiry, it may be proper to notice a singular observation, which I have not yet had an opportunity of repeating. An ethrioscope exposed to the free air, on a platform projecting towards the north, from the window of my ex- perimental room in Queen Street, stood a few weeks since, in a clear frosty day, at about 25 degrees; but, on the approach of evening, a light wind having suddenly turned to the opposite point of the compass, the atmosphere became at once obscu- red by a body of very thick and dark smoke: the liquor, contrary to all expecta- tion, immediately rose more than 10 degrees, and remained stationary till the dense mass again disapersed. This stratum of fuliginous matter would no doubt absorb the frigorific impressions showered from the sky ; yet being precipitated by its collected weight, it would bring down intense coldness from the superior re- gions, and therefore dart new impressions, rendered the more powerful from the proximity of their source. FROM THE HIGHER ATMOSPHERE. 495 exposure under a serene sky. Homer uses the term Ajégos, in speaking of the reception of his hero, when overcome with cold and toil*. The same graphic poet applies the epithet Aibenyevns or Aidenyevélns, or frigorific, to Boreas, the north wind f. The Chorus, in the Antigone of Sornoctes, deprecates alike the pelting storm and the cold (aiégia) of inhospitable frozen tracts t. The word asdgios is employed by Herovorus, to signi- fy a chill, as well as a dry, Of the same import is the expression in Horace—Sub Jove yaar But the facts discovered by the athrioscope are nowise at variance with the theory that regulates the gradation. of heat from the equator to the pole, and from the level of the sea to the highest atmosphere. The internal motion of the air, by the agency of opposite winds, still tempers the dis- parity of the solar impressions ; but this effect is likewise ac- celerated by the vibrations excited from the unequal distribu- tion of heat, and darted through the atmospheric medium with _ the celerity of sound. Any surface which sends a hot pulse in. one direction, must evidently propel a cold pulse of the same intensity in an opposite direction. The existence of such pul- sations, therefore, is in perfect unison with the balanced system of aérial currents. ee Ot A, Sh ee ee Bhs i pe * Albeo wok xara Dedpentecvov ley & olxoy. Odyss. Lib. xiv. 318. T (Qs OF are recePetcel uPeédes Ards exzrostovlecs, Yuet imal frags aibenlevios Bogieo Iliad. Lib. xix. 357-8: Keel Boging wibenyeverns, wiya xtux xvawday. Ody lyss. Lib. v. 296... $ Avoabaray motryor cebgsa Kas durope Bee Pevryety Bern. Antigone, 357. |] QOsguedlegos yag On ess ro bdwe vs ve aiderec naa rhs Ogore. Euterpe, XXII. el a tae Mone A a rolenene oda th ve gta Feel faa rere titer eo Deiriaiise 7" srenert li; od pened ia en ty oi “a rg bt oh Rae “TRI le 14 ay beh ie AG LEK ce tiga ier Po ee 4 XXII. A Method of determining the Time with Accuracy, from a Series of Altitudes of the Sun, taken on the same side of the Meridian. By Major-General Sir Tuomas Bris- ‘BANE, Knt. F. R.S. E. (Read Feb. 2. 1818. ) i: for a number of years been constantly moving about, in situations where I could not convey large astronomical in- struments, I have repeatedly tried to what extent of accuracy and consistency I could arrive with the smaller ones. The re- sults have convinced me, that a great deal of accuracy may in that way be obtained; and that the sextant is an instru- ment, which, if perfectly understood, would be in higher esti- mation, and more general use, than it is at present. The ob- servations I am about to submit, were made with a ten inch sextant of Troughton’s, divided on platina to 10”, (No 1200). The manner of using it, which I am now to describe, is what T have pursued for a great length of time, both at sea and at land, and I can recommend it as uniting simplicity with accu- racy, and at the same time as serving to discover errors, if they happen to exist. Our climate does not admit of obtaining equal altitudes very frequently, but I conceive that the mode which I wish to see adopted, will admit of equal accuracy, and I am Vou. VILL. P. II. ee ie justified 498 ON FINDING THE TIME ACCURATELY justified in this conclusion, by the results of many hundred trials, verified by calculating as simple altitudes those from which I had deduced the time as equal altitudes. Indeed I am rather disposed to give the preference to the simple altitudes for ac- curacy, if a considerable change of temperature has taken place between the morning and evening observations, as the conse- quent change of refraction is seldom taken into account in the calculation of the equations to equal altitudes, though it may produce a sensible effect on the determination of the time. To overcome these difficulties, has been my sole.object, and my only wish, in making this communication, is to enable every observer to put this method to the test, in the hope that he may derive the same satisfaction from it that I have done. In the morning, when the sun has nearly 10° of altitude, and farther from noon than two hours, if far advanced in the season, but otherwise, the nearer the prime-vertical the bet- ter, I observe eleven successive altitudes of the sun’s lower limb, reflected from quicksilver, where the situation will admit of it; where it did not, I have employed with equal success pure limpid oil covered by one of Troughton’s plate-glass an- gular roofs ; but in most situations it may be used in a room, without any cover; always taking care, in the morning obser- vations, to set the index, with the utmost accuracy, to an even 10’ or 20’ greater than the sun’s altitude, and then to wait the contact. If I use a chronometer, I have an assistant, who counts the seconds aloud, which I direct him to note, with the fractions, &c. at each observation. In the afternoon I pro- ceed in the same way, only setting the sextant 10’ or 20’ less than the sun’s altitude, and carefully noting the barometer and thermometer, for each series of observations, in order to cor- rect the mean refraction. I WITHOUT EQUAL ALTITUDES. 499 I send you a type of the calculation complete, in order that any one who wishes to pursue it, may easily be enabled to put it in practice. As the altitudes are all successive, the inter- vals ought to be nearly equal ; by which means, merely casting the eye over the results, you readily discover any inconsisten- ey, if it should exist. Although there may appear a number of figures in the work, it is extremely simple, as I have only to combine the error of the instrument with the refraction, paral- Jax, and semi-diameter of the sun, for the first and last obser- vation, the tenth part of which difference must be equally dis- tributed throughout the series, in order to obtain each altitude ; and the same system applies to the rest of the work. As the al- titudes increase or diminish by a uniform quantity, their natural sines are all taken out at the same opening of the book, and the proportional parts for seconds, applied as appears in the mode I have adopted, and have herewith transmitted. The Table entitled Logarith. Rising, in the Requisite Tables, al- though perfectly equal to all nautical purposes, I did not consi- der as sufficiently extended to give the tenths of seconds, which modern instruments and Logarithmic Tables afford the means of arriving at. I therefore computed a Table entirely a-new, from the formula sin. (co. lat. + dec. ©) — sin. (alt. ©) , cos. lat. x cos. dec. © i 2 sin.* (4 a) = but taking the logarithms from tables to ten places of figures, although only retaining eight for those in the computation, as being sufficient to give me the last figure correct. These Tables begin at 2h. from Noon, and are carried on to 6 h., and to every 10’, with the differences corresponding. The re- sults were proved by the first and second differences, and lastly, by comparing the first five figures with those given in the Requisite 500 ON FINDING THE TIME ACCURATELY, &Xc. Requisite Tables. The Table of natural sines given in the Ap- pendix to that work, is most convenient for the calculation of the time by this method. If this communication is thought worthy of a place in the Transactions of the Society, of which I have the honour to be a member, I shall have the satisfaction of making another, respecting the mode of determining lati- tudes by the sextant most correctly, by a series of observa- tions made near noon. [I should also wish to submit a paper on the Repeating Circle, and the extraordinary accuracy of the results I have obtained from observations made with a circle of Troughton’s, twelve-inch in diameter, if the Society shall think the matter deserving of its attention. Paris, 23d November 1817. The [ Vol. VILE. Part II.—p. 501.] The following are the Times and Altitudes of the Morning and Evening Observations, from which the Calculations of the Times Srom 8h 41’ 49".7 23° 10° 42 34.3 43 17.3 4413 44 46.3 45 30.3 46 16.3 47 13 47 45.3 48 29.3 49 15.3 50 13 50 46.3 oe Gd! 8 0 thc 2» 20 30 40 50 0 10 20 ~ 30 40 50 0 10 Equal and Simple Altitudes have been deduced, as referred to in the respective Calculations. Qh 56’ 39''.3. - 55 54.3 - 55 10.3 Ana og a o 54 25,0 53 41.4 52 58.3 52 11.8 51 26.0 40 42.0 49 57.0 49 12.0 48 26.4 47 40.7 Barometer, Morning Observation, 748.30 Thermometer, do. Barometer, Evening Observation, 745.60 Thermometer, do, 10.3 14,00 8b 41/ 49'".7 2 56 39.3 11 38 29.0 40 14.5 14.3 13.8 13.2 13.8 14.3 13.8 13.6 13.7 13.1 13.7 13,8 13.5 49.1 _——_ 11 49 13.77 Calculation of Time, from Equal Altitudes. © Longitude 74 14° 7 34.3 17.3 13 46".3 30".3 167.3 1.3 45°3 29°83 15°83 13 54.3 10.3 25.0 41.4 58.3 11.3 26.0 28.6 27.6 26.3 Q1.7 28.6 27.6 27.3 143 13.8 13.2 13.8 14.3 13.8 13.6 11 49 13.77 + 17.68 11 49 31.45 42.0 57.0 12.0 26.4 27.3 26.3 27.3 27.7 13.7 13.1 13.7 13,8 8n 46’ m. Time, Morning Observations. 14 52 m. Time, Evening Observations. “6 06 Interval, 3 03 4Interval. [Vol. VILL. Part I1.—p. 502.] CALCULATION FOR FINDING THE 81.2 Mean E. A. T. = 10/28” .12 Chateau de Sainte, Pas de Calais. Morning Observations. Very Clear. 841497 42343 49178 444 15 44-463 45 903. 46.168 47 15 OT - 3100 320 2330 93 40 23.50 2% 0 410 220 24 SI — 6 Error. { Daily var. @’s decl. 17 55 = ot FREE ; 5 19 15 ; 37 36 0513841 4.052805¢ 23 040 se led 0 i 24 50634863 5.063486 23 040 85224 8 59 49 $.1462789, 2.1287H07 11 32 0 307 36-3 00 11 140 0 GEN + 11 45.5 lH 45 1148473 1153491 1158509 123527 128545 1213 564 1218 58 ©'s declin. first obser. 16 14 17 co-sine 9.9823202 @’s declin. last obser.16 14 22 5 Co-sine, ean Co-ar. co-sine, co-lat. 50 19 57 0.9149539 - - - - - - - - . 0.2126337 0.2126371 ©’s declin, first obser. 16 14 17 Last observ. 16 14 22.5 Co Latitude, 39 40 3 39 40 3 @'s meridian alt. = 23 25 46 Nat. sine 397619 93 25 40.5 Nat. sine 397594 Differ. 25 *s mer. alt. Ist obser. 23 25 46 Nat. sine 397619 397617 397614 397612 397609 397607 pase Seale a ll 43 455 “7 203072 204496 205920 207343 208765 210187 194547 193121 191694 190269 188844 nBeeu Prop. parts for seconds of alt. 45.5 9 = 216 225 233 243 251 259 194331 192896 191461 190026 188593 187161 Log. - = = = 9.288542 9.285323 9.282080 9.278813 9.275526 9.272215 Co-ar. co-sine, co-lat, ©’s declination, 0.212634 212634 212654 212634 212635 212635 Horary. - - - 9.501176 497957 494714 .491447 Ee 61 484850 ; 0975 H $ t TWAS — | i H } 1454} H i H t ; H H 556 | i 3.7428 3 6586 3 6143 3 52993 4455 3 4 09 852172 853014 85345.7 854301 8 55 59.1 8 5559.1 8 41 49.7 42 34.3 4317.3 44 13 4446.3 45 30.3, 10275 10271 10984 10288 10282 10 98.8 Q7.1 28.4 28.8 28,2 28.8 27.6 274 28.5 28.9 TIME WITHOUT EQUAL ALTITUDES. @ Tth Nov. 1517, Lat. 50°19 57” Long. 2’ in ‘Time west of Pans. Error of Inst. — 6’ 48.293 49155 Ther. 103 9.9995 9.9995 24-40° 2450 Bar. 74830 9.9931 9.9981 Error, — 6 8D. - %8 2.4280. ‘77 2.3986 28 172 38 218 24 44 12 22 24378 2.4080 +1236 - re 2741 Refrac. 255.9 12 343 6 87 Paral. 86 12 25 59.9 12°29 1.8 965 4 Ref.- 247.3 - — 425 4 Par. + 4 75 ©’s semi-diameter, + 16 10°9 16 10.9 4-11 45 5 + 12 03.6 ©’s declin. at noon, 16 16 37 16 16 37 3) 7 36 “= 2 20 SOP = 2 14.5 16 14 17 16 14 22.5 897604 3897602 397599 397597 897594 211609 213030 214451 216156 217575 185995 184572 183148 181441 180019 269 276 285 8 17 185726 184296 182863 181433 180002 9.268873 9.265522 9.262126 9.258716 9.955277 212635 212636 212636 212636 212637 481508 478158 474762 471352 467914 } } } $ 471 H H H H 761)443(5.8 { } ; H 3805 ; H H { H 625 $ ; ‘ $ 3 3161 3 23135 8 1462 3111 8 0158 85643.9 85728.7 858138 358589 859442 4616.3 47 1.3 47 45.3 48 29.5 4915.3 10 27.6 10 27.4 10 28.5 10 29.6 10 28.9 CALCULATION FOR FINDING DHE LIME WinHouT EQUAL ALTITUDES. Calculation for the Evening Observations. (Vol. VIII, Part IL—p. 503.) Times, = 249120 49570 50420 51260 52 s 113 52583 538414 54250 55103 55 643 56 39 3 Th . 14 0 = 9.9934 Altitudes, we! a0 24400 24300 24200) 24100 24 00 23500 98400 23800 982900 98100. Bar 745 60 = 90916 eee . Error— 6 3D. 77 = 2.3936 78 = 2.4280 } 24 44 0 O's daily var. 17 89 Log. = 3.0253059 17 39 Log. =8.0258059 283. 04 pHing = 112 *}2 22 0 25941 40326590 3 78 4.050304 11 82 0 2.4004 2.4302 24 5.0634863 24 5.0634863 } 45} 7 269’ 3 21214512 2.1390946 H — bey UJ 1823 =2123 137 8 =2178 i 242 7 260 6 Leroi, 1 a 0 — 4 27 Refrac. Paral.— 4 20 6 + 11 503 16 10 . idi 12 22 0 + 16 9 ©’s semidiam. + 16 10 9 + 1282 11 43 503 12 82 11 503 Altitudes corrected, 125482 12 29964 122446 121928 121410 128592 123575 1158557 1153539 11 48521 n 43 50 3 ©’s declination, 1st observation, = 16 18 49 Co-sine = 9.9821530 Last GEGRLBES WY 18 55 Co-sine = 9.9821493 Co-latitude, co-sine, ar. co. 839 40 08 0.1949539 = a - - 0.1949539 0.2128009 0.2128046 ©’s declin. 1st observation, 16 18 49 Last observation, 16 18 55 cosme Co-latitude, = = 39 40 03 = e 2 39 40 03 23 21 14 N. sine 396409 23 21 08 Nat. sine = 396383 ©’s mer. alt. 23 21 14 Nat. sine 396409 396406 396403 396401 896398 396395 396393 396390 396388 396385 396383 12 34 8 217575 216156 214735 213315 211893 210187 208765 207343 205920 204496 203072 178834 180250 181668 183086 184505 186208 187628 189047 190468 191989 193811 Proportional parts, - - 39 80 17 13 5 281 QT2 265 257 247 239 178795 180220 181651 183073 184500 185927 187356 188782 190211 191642 193072 Logarithm, - - 9.252355 9.255803 9.259238 9.262624 9.265996 9.269343 9.272668 9.275961 9.279236 9282491 9.285719 Ar, co. co-sine, co-lat, — sun’s decl. 0.212801 0.212801 0.212802 0.212802 0.212803 0.212803 0.212805 0.212804 0.212804 0.212805 0.212805 9.465156 9.468604 9.472040 9.475426 9.478799 9.482146 9.485471 9.488765 9.492040 9.495296 © 9.498524 4418 i $ H i { j i 058 == 3 H 3 H = 764)73809 7 H H H i i ; H 780)466(6 4 6876 H H i ; i { i 4380 soo i H i i i i i 280 ‘ 30%9 $1102 31850 5 2399 3 3 246 3492 8 4536 8 5879 8 6228 37 64 ata a 3 34057 0 250420 251260 262113 52583 253414 254250 255103 255 543 256393 10° 27 7 1027 9 10282 10 290 10 286 10 263 10278 10 286 10276 10280 10271 27 9 28 2 29 0 28 6 26 3 aren recerees E. — Apparent Time, - = 10’ 27’88 27 8 Es E. — by mean morning pbseryation: 10 28 12 98 6 Mean of both, " - 1 ai " 10 28 00 Apparent noon simple alti- 28 0 aR tudes, vt - ll 49 32 00 27 1 Ditto by cul altitudes, same 11)306 8 day, 11 49 31 45 Difference from equal altitudes, + 65 (Vol. VIII. Part II.—p. 504.) ‘Times, =) 8*1'524.8 2 R8".2 3/3'.8 53 39.3 4 18.4 4 48.3 5 24.3 5 59.3 6 36.3 tf 11.8 q 46.8 Altitudes observed, 38° 195 88° 20) 88° 80’ 38° 40 88° 50’ 39° 00' 39° 10’ 89° 20 39° 30 39° 40 39 ne Suecein farcnntink ea un’s declin. at noon lod $*46' 48" before noon, + 3.41 — 8354 oe of Refraction — Parallax — 2/37".4 Also — 2 29.7 a fd Fae ane F Semi-diameter, +15 59-5 15 59.5 un’s . corrects 44 30 0 44 36.6 Correction for Refr. Parallax, 13 22 & semi-diameter. ee re Ms 4 ss + 18 29.8 Semi-diam. Paral. & Refrac. Cosine, - ; 9999636 i 635 ibe 3 298 re coe 1981520 01951520 ; eee sees Ae 221 + 99, . co, cos, Lat. 1.195152 . 52 True Altitude, - 19 15 22 20 05 29.8 True Alt. Sun’s Centre. eo . 0.1951884 0,1951885 Co.-Latitude, - 39° 38/45” 89° 38 45” Sun’s declination South, 0 44 30 0 44 35.6 Sun’s Meridian Altitude, 38 54 15 38 54 09.4 Nat. Sine, - - 627963 627963 Proportional parts for /’ + 59 Diff, proportional parts, = 23 36 628022 62799 $ H H Co-Latitude, a 39° 38° 45! FER REREETAREREHAHSERESES FRESHEST U ERE EES R eR HEE EEE EEREEE HEE BEBESESE EEE HEHEHE SESE EES EDERESSMENESSOREEY ? seneeegeee Petre ee eeeee Dense etna een eae shemerawennee Seen eee ee eeeeee ¥ in. S. - 7 t wot Me Sun's 0 4430 The 23 Proportional Parts for difference of Sun’s declination to be equally distributed from first to last Observation. Fans Meridian Altitude, 38 54 15 at. Sine, 5 = 628022... 628020 628017 628015 62 3 pay ts 0 28013 628010 628008 628006 628004 N, sine Ist Alt..19°16/ 22 629691 331068 332436 333807 335178 336548 337917 539285 340653 ee ite Difference - - 298331 296957 295581 % j 1 = ’ Aa b 94208 292835 291462 290091 288721 Prop. parts for N. sines, 100 103 107 il 114 118 121 125 kis er 7 ae Log. : 298231 296854 Q95474 294097 2 a : ets 296 295 29409 92721 291344 289970 288596 28722: ASR ei a eubas parahae 9,4705194 9.4684906 9.4664539 9.4644662 9.4623531 9.4602903 SASERI0S 9. 4561852 9. ree . dat. 0.192 1951884 0.1951884 0.1951884 0.1951884 0,1951844 0.1951885 0.1951885 0.1951885 0.1951885 0.1951885 9.6697412 9.6677314 ——— —— : iva ui 9.6657098 9.6636790 9.6616423 9.6595946 9.6575416 9.6554788 9.6534078 9.6513237 9.6492342 —- 9839 572)4288(7'.4 a503( 4004 590)2508(4.2 2360 234 Lee 143 Time from Noon, - 3 51 17.4 3 50 42.3 3 50 0 ¢ Times of Observation, 8 8 426 TL 3 49 31.9 3 48 56.7 $ 48 21.3 8 47 46.10 8 47 10, ‘ cktanceaeter "Tinea, niniiscts 8 oe a : 9 52.9 8 10 98.1 811 33 8 11 38.7 8 12 140 8 iz ra 3 ie Pe 3 4 ong 3 is aes SAE 2 S§ 8 38 8 3 398 8 413.4 8 04 48.3 8 5 243 8 5 593 8 6 363 8 7118 8 7 463 Chronometer — App. Time, 6 49.8 6 49.5 6 49.6 6 43.8 6499 e504 Py = —— a 7a i 6 49.7 6 50.1 6 48.5 6 48.9 6 49.5 49.6 u 48.8 ans Result of Equal Altitudes observed the same Day with Sextant. Sun’s Longitude 6s 2° 0’ 50.4 10» 42’ 057.3 28°3 11’3 BY 35".3, 120°.3 4.3 49.7 1 2554 108 a8. i d ) ‘ rae ys tei Middle Observati 3 50.1 iiss = pes, ee ge 20,0" 33.3 50.6 "73 ete le Observations, 48.9 11 45 40.7 39.1 39.8 41.6 39.6 40.3 37.6 "89.0 589. 38.6 49.5 == 49.5 49.9 50.8 47.8 gon a) Bao i ee 11 52 50.3 : et oe a2) 494 49.8 eat 10)6 496.2 49.5 ll 52 49.77 d , — 49.9 + 18.03 Equation of Equal Altitudes. Men, - - - = 6 4962 50.8 zeadies Rate to Noon, =~ 61 49.8 11 53 07.80 Mean of Apparent Noon, by Equal Altitudes. Difference of Meridians, — .06 DO EM hes tenatehecares 11 53 07.80 —_—_——. Simple Ragin with Sextant. Reduction of Equation to Noon, + 3.25 48.8 H a 49.5 0 6 52.20 49.4 i 11 53 07.80 by Chronometer. 49.8 $ App. Noon, rs CALCULATION FOR THE TIME WITH AND WITHOUT EQUAL ALTITUDES. Valenciennes. % 25th September 1817. Valenciennes, 25th September. Very clear. Mode of determining the Time by a Sextant of TnrovcHton’s, No. 1200. Latitude 50° 21/15” Longitude East of Paris 4’ 44!” in time. 11 52 49.77 Mean.....-+ App. Noon 1]» 51’ 41".7 ie XXIII. Observations on the Junction of the Fresh Water of Rivers with the Salt Water of the Sea. By the Reverend Joun Fiemine, D. D. F. R.S. Eni. ( Read June 17. 1816.) I. is possible, that the following observations may contain little that is new to those who are familiarly acquainted with the details of the science of Hydrostatics. But as I have not met with any remarks on the subject, in the course of my li- mited reading, the experiments which were performed, and the conclusions to which they lead, are here submitted to the con- sideration of the Royal Society. When the flux of the tide obstructs the motion of a river, the wave has been supposed to produce its effects in the same manner as a dam built across a stream. This popular opinion, however, appears to have been adopted without sufficient con- sideration, as it can only hold true, in those cases, where the opposing fluids are of equal density, but never at the junction, of opposite currents of fresh and salt water, which are of diffe-. rent densities. In this last case, where currents of fresh and salt water come in opposition, the lighter fluid, or the fresh water, will be raised upon the surface of the denser fluid, or. Vou. VIII. P. I. 358 the 508 JUNCTION OF THE FRESH WATER OF RIVERS the salt water, and when the stronger current of the tide has reversed the direction of the stream, the salt water will be found occupying the bottom of the channel, while the fresh water will be suspended or diffused on the surface. This view of the matter occurred to me in 1811 ; but it was not until the 29th of September 1813, that I had an opportunity of verify- ing the conjecture, by an examinatien of the waters of the Frith of Tay. Flisk Beach, opposite to which the experiments were made, is situated a considerable way up the Frith, being upwards of sixteen miles from Abertay and Buttonness, where the Frith of Tay actually joins the German Ocean. The channel of the Frith at this place is about two miles in breadth ; but upwards of a mile and a half of this extent consists of sand-banks, left dry at every ebb of the tide, and during flood, covered with from three to ten feet of water. These banks are separated from one another by deep pools, or /akes as they are termed, which occasion great irregularities in the motion of the cur- rents. The channel of the river is near the south side. It is about half-a-mile in breadth, having in the deepest part about eighteen feet of water, when the tide has ebbed, and upwards of thirty feet during flood. The apparatus which I employed was very simple: It con- sisted of a common bottle, with a narrow neck, having a weight attached to it. Besides the cord by which the bottle was low- ered, there was another connected with the cork, in such a manner, that I could pull it out when the bottle had sunk to the place of its destination. . The weather was favourable, and, on the day of the experiment, there was no wind to disturb the surface of the stream. With this apparatus, I proceeded to the middle of the chan- nel of the river, at Jow water, when the current downwards had ceased. » WITH THE SALT WATER OF THE SEA. 509 ceased to be perceptible in the boat at anchor ; and I obtained water from the bottom, the middle, and the surface of the stream. The water taken from the surface of the stream, was fresh, and tasted like ordinary river water. The water taken from the middle, was not perceptibly different ; but that which was brought frem the bottem was sensibly brackish. The wa- ter from the surface did not coniain any salt, as a thousand grains of it, when evaporated with care on a sand-bath, left on- ly a grain and a half of residue, apparently mud, which, when applied to the tongue, communicated no impression of salt- ness. The water from the middle of the stream yielded two grains of residue, when the same quantity was evaporated, of a whiter colour than the former, and having a perceptibly salt taste. ‘The water from the bottom, which was saltish even to the taste, yielded four grains of saline matter. According to these experiments, the layers of water were arranged accord- ing to their densities, the heaviest water occupying the bottom of the stream, and the lightest floating on the surface. At halflood, I repeated the experiments on the waters ob- tained from the same situations as before. The water at the surface had now become very sensibly salt to the taste, and thus gave decided proofs of the progress of the tide. The three bottles of water now obtained, yielded results, not in unison with those already taken notice of. The arrange- ment of the different strata of water, according to their den- sities, as observed at ebb-tide, was in some degree rever- sed; for here the water at the surface was salter than that which was obtained from the bottom, and the water from the middle was salter than either. A thousand grains of water from the bottom, yielded by evaporation only ten grains of sa- line matter, while the water from the surface yielded eleven grains, and from the middle twelve grains, by the same pro-. cess. S5'2 This 510 JUNCTION OF THE FRESH WATER OF RIVERS This anomaly is easily accounted for. Were the current of the tide confined entirely to the channel of the river, an ar- rangement of the waters, similar to that which existed in the first experiments, would have prevailed. But during the flow- ing of the tide, the sea-water soon occupies more than the channel of the river, and spreads itself in various streams among the hollows of the sand-banks. These streams reunite at different places with the principal current, and, in this man- ner, prevent the salt and fresh waters from gaining their natu- ral relative position. But as soon as these sand-banks are co- vered with water, the tide proceeds with regularity in its course, so that the different layers of water can then arrange themselves according to their specific gravities. A thousand grains of water obtained from the bottom, at the height of flood, yielded by evaporation twenty-three grains of salt, while the same quantity of water from the middle yielded only eighteen grains; and from the surface only seventeen grains. This was a difference of no less than six grains, and seemed to afford a decisive result. In order, however, to complete the series of observations, I examined the conditions of the currents at half-ebb. The same irregularities prevailed, as before observed at half-flood. A thousand grains of the water, from the bottom, yielded after evaporation eleven grains of salt ; from the middle, nine grains, and from the surface, twelve grains. At this time the densest water was at the surface, and the lightest occupied the middle. The cause of this was obvious. Extensive portions of the sand-banks had already been left dry by the receding tide, and various currents of water, disjoined from the main stream by the inequalities of these banks, were now re-uniting with it, through various channels, and disturbing the natural arrange- ment which had prevailed during the time of flood. Although WITH THE SALT WATER OF THE SEA, 5it Although the Frith of Tay is very ill calculated for experi- ments of this kind, from the circumstances already taken no- tice of, still the premises which we have stated seem to war- rant the conclusion, that when the wave of the tide obstructs the motion of a river, and causes it either to become station- ary, or to move backwards, the effect is produced by the salt water presenting to the current of the river an inclined plane, the apex of which separates the layer of fresh water from the bed of the channel, and suspends it buoyant on the sur- face *. < 7 . It may here be observed, that this inferior current of salt- water, will never reach that point of the bed of the river, which is intersected by a line drawn perpendicular to the altitude of the wave of the tide, in the ocean, at the mouth of the river. This point is undoubtedly the place at which the salt-water would arrive, at every flood, were there no fresh-water current, as has been demonstrated with regard to the waters of the Tay, by the accurate observations of Mr James Jarprne. But as the motion of the current of salt-water is retarded by the opposite current of the fresh-water, and the apex of the wedge which it forms, also washed away by the same agent, the point which the salt-water reaches will be considerably lower than the summit of the tide-wave with which it is con- nected. The surface of the higher part of the river, whose elevations and depressions are influenced by the movements of the tide, will necessarily attain a higher level than the summit of the tide-wave, in consequence of the lower specific gravity of the river-water, when compared with the denser column of sea- water, * T understand that my friend Mr Rosert Srevenson has made similar obser- vations at the mouth of the Dee, near Aberdeen, and also on the Thames, and that his conclusions and my own nearly coincide. 512 JUNCTION OF THE FRESH WATER OF RIVERS which it counterbalances ; and this, independent of the pro- gressive motion of the tide in the river. If the view which we have taken of this subject, in reference to the progress of the salt water, be considered as just, it will enable us to explain some of the phenomena of nature, at pre- sent rather perplexing, and may even be useful in its practical application. In examining the vegetable productions of the banks of ri- vers, at their junction with the sea, we are sometimes surpri- ed to witness the growth of plants, considered as the natural inhabitants of the sea-shore. But our surprise will cease when we reflect, that the sea-water proceeds farther up the river at every flood-tide than the sensible qualities of the water at the surface indicate ; so that the plants, which we hastily conclude to be out of the reach of the salt-water, are still within the sphere of its influence. Thus, at the Beach of Flisk, and even farther up the river, the Fucus vesiculosus, (the species commone ly cut for making kelp) not only vegetates, but in its season appears in fructification. But that which proves in a still more decisive manner, the action of the inferior stratum of salt-water at the place, is the growth of the coralline termed T'ubularia ramosa (Exx1s’s Co- rallines, Tab. xv. fig. A.), and another of a different genus, closely resembling the Sertularia gelatinosa of Pattas. There are likewise some traces of Flustre. A knowledge of the facts which we have already stated, may be of use to those who are engaged in the erection of salt- works at the mouths of rivers. In such situations, the open- ings of the pipes for obtaining the salt water, should be placed as near the bottom, or as deep in the water as possible; and water ought only to be drawn during the height of flood-tide, when the fresh-water is diffused over the surface. Even eee eee ae Se oe WITH THE SALT WATER OF THE SEA. 513 Even to navigators, an acquaintance with this subject may sometimes be of use. Thus, for example, when entering a creek in an unknown coast, they may easily ascertain whether any streams of fresh water flow into it, by examining the com- parative density of the water taken from the surface and from below. These experiments appear to give countenance to the opi- nion which supposes that the water at the surface of the sea contains less salt than the water at the bottom. This may be expected to take place in the neighbourhood of continents, at - least, whatever may be the case in the open ocean. During winter, the difference is probably very considerable, as at that season the rivers incessantly pour vast quantities of fresh wa- ter into this great reservoir, while but a small portion is ab- stracted by evaporation. In the Frith of Forth, the difference between the dense water of summer and the diluted water of the winter season, is as eighteen to sixteen, and that even as. _ far down as Prestonpans. Manse oF FLIsx, 11th March 1816. } XXIV, os XXIV. Memoir of the Life and Writings of the Honourable ALEXANDER Fraser Tyrier, Lord Woodhouselee. By the Rev. Axcurpatp Atison, LL. B. F. R. S. Lonp.. & Ep. (Read June 3. 1816, and January 6. 18177. ) Rcrosari TyrLer was born at Edinburgh, 15th October 1747. He was the eldest son of our late venerable associate Witiram Tyrier, Esq. of Woodhouselee, in the county of Mid-Lothian, and of Anne Crarc, daughter of Jamzs Craic, Esq. of Costerton, in the same county. ? If the most important education is that which is received beneath the paternal roof,—if it is there that the principles and tastes of future life are chiefly formed, the education of Mr Tyrer began under fortunate auspices. His father was a man of high honour, of generous affections, of cultivated taste, and of distinguished eminence in his profession. His mother was a woman of elegant manners, of great gentleness and ten- derness of disposition, and of still greater firmness of moral and religious principle. And the society in which they lived was nearly that of all those who then were distinguished in Vou. VIII. P. I. 3T this 516 MEMOIR OF this city, by their manners, their talents, or their accomplish- ments. These advantages were not lost upon Mr Tyrter; and in this domestic school he early acquired that taste in life, or that sensibility to whatever is graceful or becoming in con- duct or in manners, which ever afterwards distinguished him, and which forms, perhaps, the most important advantage that the young derive from an early acquaintance with good so- ciety. In the year 1755, he was sent by his father to the High School, then under the direction of Mr Marnerson. In that school he remained five years, distinguished to his school-fel- lows by the gaiety and playfulness of his manners, and to his. teachers, by his industry and ability ; and, when he left it, he left it with the highest honours which the school ean bestow, as Dux of the Rector’s, or highest class. The High School, however, although then a respectable se- minary of education, had not yet acquired the eminence which it has since attained, by the zealous activity of the late Dr Apam, and, more recently, by the enlightened improvements of the present Rector, Mr Prrrans. To complete the classical education of his son, Mr Tyrer, therefore, determined to send him to one of the academies of England; and for this purpose he chose the Academy at Kensington, then under the care of Mr Expuinston, a man of learning and of worth, and distinguished by the friendship of Dr Samvet Jounson. It was in the year 1763, when he was fifteen years of age, that Mr Tytier went to Kensington. He was himself at that time conscious of the imperfection of his classical knowledge ; he felt that he had yet much to learn, particularly in the articles of Prosody and of Composition, and he entered the academy with the ambition of returning an accomplished scholar. The pro- gress of youth, and the instructions of his father, had now awakened ee ‘LORD WOODHOUSELEE, 517% awakened him to a sense of the beauties of classical composi- tion; and the names of Jounstone and Bucuanan reminded him, that the accomplishments which he now travelled to ac- quire, were once the produce of his own country. With this ambition, he soon distinguished himself among his school-fellows of the Academy. He became the favourite pupil of Mr Exrnrysron, and received from that worthy man all that cordial assistance and encouragement which knowledge has so fortunate a pleasure in affording to the ardent and aspi- ring mind of youth. A little incident, at this time, too, oc- curred, which served to confirm Mr Tyrter in his love of Latin poetry, and in his ambition to excel in it. The celebrated Dr Jorrin was at that period vicar of Ken- sington. Upon some occasion, when Mr Tyrer had particu- larly gratified Mr Exrurnston, by a copy of Latin verses, the good man carried them in exultation to Dr Jorrin. The ver- ses pleased Dr Jontin so much, that he requested to be made acquainted with the author. Mr Tyrier was accordingly in- troduced to him. He received him with the greatest kindness, and, after praising the composition, and encouraging his assi- duity, he took down a copy of his own Latin poems, and re- quested Mr Tyrer to accept of it, as a memorial of his ap- probation and regard. This volume, with a little inscrip- tion in the author’s handwriting, Mr Tyrier ever afterwards preserved with veneration, and often acknowledged, that much of his attachment to Latin verse was owing to this little inci- dent. It is among the most important effects of these studies in early life, that they awaken the minds of the young to a new sense of the beauties of Nature, and of the charms of poetical imitation. Both these effects Mr Tyrizr seems at this period to have experienced. It was during his residence at Kensing- 3T2 ton, 518 ' MEMOIR OF ton, that he first began the art of drawing, and the study of landscape-painting ; a pursuit which he continued ever after- wards to follow, and which formed one of the most favourite amusements of his future life. At the same time also, in his hours of leisure, he began by himself the study of the Italian language ; and in the early admiration of the poetry of that country, with which his industry was then repaid, opened to himself a field of elegant and of refined amusement, which he never ceased to cultivate with increasing delight. There was another acquisition which Mr Tyrier accidental- ly made at this time, of which he always spoke with gratitude. It was the love of the science of Natural History. When he went to Kensington, he was particularly recommended by his father to his early friend Dr Russet, the celebrated physician of Aleppo, who at that time resided in the neighbourhood of Kensington ; and with this respectable and intelligent man Mr Tyrer used always to pass his holidays. Dr Russrri was then engaged in the pursuits of natural history ; and seeing the ardour of his young friend for knowledge, he made him ac- quainted with the general principles of the science, associated him as his companion in study, and delighted him, in their leisure hours, by his accounts of the scenery and productions of the East. To these studies Mr Tyrie was then alone led by the charm which, in his eyes, they threw over Nature, in the illustrations they every where afforded of the wisdom and benevolence of its Author. He did not foresee that they were afterwards to become to him the source of unfading consola- tion, and to relieve many an oppressive hour of lassitude and pain. In 1765 Mr Tyrter returned to Edinburgh, after two years passed at Kensington, with equal happiness and improve- ment. Of these years he always spoke with pleasure, and of Mr LORD WOODHOUSELEE. 519 Mr Expuinston with the most grateful and affectionate regard. He continued ever afterwards occasionally to correspond with him ; and so little did the lapse of time, or the business of ma- ture life, diminish the remembrance of early obligations, that when Mr Expurnsron died, he had the satisfaction of associa- ting himself, with his respectable widow, in erecting, in the church-yard of Battersea, a monument to his memory. In the close of the year 1765, Mr Tyruer entered the Uni- versity of Edinburgh, and upon a new field of knowledge and of study. The profession to which his own disposition, and the wishes of his father inclined him, was that of the Law; the profes- sion, of all others connected with literature, most.attractive to . the ambition of a young man, both by the variety of powers which it demands, and the importance of the distinctions to which it leads. It was to this end, accordingly, that his stu- dies were now chiefly directed ; and although he attended the lectures of Mr Russet upon Natural Philosophy, and of Dr Brack upon Chemistry, yet he seems to have limited himself to a general knowledge upon the subject. of physical science, and to have reserved the vigour of his attention for those clas- ses that more immediately related to his future profession. While he was pursuing, therefore, the study of Civil Law, un- der the tuition of Dr Dicx, and afterwards of Municipal Law, under that of Mr Wanxzack, he followed with interest the use- ful and perspicuous prelections of Dr Srevenson in the science of Logic: he improved his taste by the celebrated lectures which Dr Buarr was then delivering upon the subject of Rhe- toric and Belles Lettres ; and he listened with ardour to that memorable course of Mixa Science, in which Dr Fereuson il- Justrated, with congenial power, the various systems of ancient philosophy,. 520 ‘MEMOIR OF philosophy, and occasionally exhibited all the splendors of an- cient eloquence. Of the progress or success of Mr Tyrxen’s studies during these years, no record, indeed, remains in the annals of the University. It has been the practice, and perhaps the wisdom: of the Professors of that distinguished Seminary, to seek more to gratify the desire of knowledge in the young, by the instruc- tion they convey, than to stimulate it by the distinctions they confer ; and to look for their reward rather in the future emi- nence of those they instruct, than in the display of early and premature exertion. Of the dispositions or attainments of the young, however, there is, at this age, one unfading proof to be found, in the character of the friends and associates whom they select. The circumstances of the times, and the celebrity of the Professors, had at this period excited in the young men of the University, an unusual spirit of literary ambition, and many of those who have now arisen to the highest distinctions in their country, were at this time laying the foundations of the eminence to which they have attained. It was in this class that Mr Tyrier sought for friends, and it was in this class he found them. The vivacity of his temper, the variety of his at- tainments, and the high spirit of honour which distinguished even his earliest years, rendered him acceptable to all the young and spirited of his own age; while his zeal for know- ledge, and his ambition of distinction, conciliated the regard of those who were older. It was in these years, accordingly, that the great friendships of his life were formed ; and it was his peculiar happiness, that among those to whom the affections of his youth were given, the course ‘of his mature life was passed, and its final period was closed. The list is an ample one, and will not be heard in this Society without emotion ; for it contains the names of Henry Mackenziz, of ALEXANDER ~~ ABERCROMBIE ' LORD WOODHOUSELEE. 525 Apercromere (late Lord Axercromste), of Writram Crarc (late Lord Craic), of Arran Maconocute (late Lord Mea- powzank), of Wittram Apa (now Lord Chief-Commissioner), of Rosert Lasron, of ANprew Dawzet, of Wittram Rosgert- son (now Lord Rozertson), of Joun Prayrarr, of Dr Gre- cory, and of Duéatp Srewart,—men, whom in this place it would ill become me to insult with praise, but from whose friendship, I may be permitted to say, there is no name so il- lustrious that would not derive distinction. If the seasons of academical ‘study were thus happily and usefully employed by Mr Tyrter, the seasons of the summer vacation were not less so. Upon these occasions, he retired to Woodhouselee, the beautiful seat of his father, near Edin- burgh, a scene endeared to him by the remembrances of in- fancy,—by all the ties of domestic affection,—by the improve- ments which his father was then annually adding to it,—and, perhaps, by those anticipations of greater embellishment which it was afterwards to receive from his own hands. Amid the solitude and quiet of this romantic residence, and at a distance from the prescribed routine of academical labour, he felt all the: happiness that arises from the freedom of study, and was at liberty to follow out, without interruption, those literary pur- suits to which inclination and taste most strongly inclined him. The character of his age, and of his mind, led him naturally to. those compositions which, as addressed to: the imagination and. the heart, constitute the polite literature of every country. His knowledge, both of the ancient and the modern languages,, enabled him to indulge this desire; and in the course ‘of * successive summers, he seems to have formed and to have exe- cuted,-with this view, a plan both of comprehensive and of systematic study. $22 - MEMOIR or He began with the great writers of antiquity—the Poets, the Orators, and the Historians of Greece and Rome, to whose works he now returned with that increase of knowledge, and that improvement of taste, which enabled him more fully to seize and to appretiate their various excellence. He next resumed, (though with more enlightened views), the study of Italian literature, and perused with new admiration the writers of that brilliant period which succeeded the revival of letters in Europe, and who, though formed, in the great principles of composition, upon the models of classic taste, have yet added to them all the splendid courtesy of feudal manners, and all the romantic interest of chivalrous adventure. After the ex- tinction, or (as I trust) only the slumber of Italian genius, he followed the progress of taste into France, and pursued the singular history of composition in that country, from the pe- riod that the genius of CornerILix first gave to its imperfect language the dignity of poetry, to the time that the eloquence of Feneton, of Burron, and of Rousseau, rose above the level of its poetic diction, and gave to prose composition all the powers and all the pathos of poetry. The study of foreign literature led Mr Tyrxer naturally to that of his own country, and, in comparing the great writers of England with those of the different nations of the Continent, he was enabled to form a more accurate estimate, both of the _ extent of English genius, and the powers of the English lan- guage. While engaged in this pursuit, his curiosity was led into a field at that time little cultivated in this country, I mean to the study of the ancient writers of England, those original mas- ters of composition, in whose writings the genius of the people ‘ and of the language is most strongly displayed, and who con- ducted him (in the language of Spenser) to “ the pure well of “ English undefiled.” The pursuit not only rewarded him at the LORD WOODHOUSELEE. 528 the time, but tended to form his taste in future days; and he was among the first literary men of this country, who felt the beauty of our language in its first stage of improvement, and foresaw the advantages that the study of our earlier writers would give to modern composition, by introducing greater unity of character, a purer analogy of construction, and the peculiar energy that arises from idiomatic expression. The same taste which guided the studies of Mr Tyrer at this, period, directed also his amusements. The art of Draw- ing, which he had at first begun to practise at Kensington, he now resumed with ardor, amid the beautiful scenery he inha- bited. The love of Music, which was hereditary in his family, had been cultivated by the example, and under the instruc- tions of his father, and he willingly became a performer, not only to indulge his own taste, but that he might add his assist- ance to the little family concerts with which that excellent man loved always to close his active day. But the amusement in which at this period Mr Tyter peculiarly delighted, was that of making excursions to visit the remarkable scenery, either of England,.or of his own country. He had an early love of the great and beautiful in Nature; and his sensibility in this respect had been increased by his study of landscape painting. But his taste was not of that servile kind, which looks only to the art of imitation: and he felt that there were many other sources of beauty in the scenery of Nature than the painter can em- ploy. His mind was open, not only to all those moral expres- sions which form what has been called the poetry of Nature, but to all those local and accidental expressions which it re- ceives from the events of time; and he loved to mingle in such scenes, with the sensibilities of taste, the associations of poeti- cal description, and the memory of historical events. In this manner, Mr Tyrrzr used always to pass some parts of the Vou. VIII. P. IT. 3U summer 524 MEMOIR OF summer or autumnal months ; and, in the course of a few years, there were few scenes, either in England or in Scotland, which he had not visited, that were distinguished, either by natural beauty,—by poetical celebration,—by the residence of eminent men,—or by the occurrence of memorable transactions. In such employments, to him (as to all who are capable of it) there was something more than amusement; and he never returned from them, without feeling his taste improved, his ar- dour in study animated by the memories of illustrious men, and his love of his country increased, both by the monuments of its former glory, and the appearances of its progressive prosperity. In the year 1770, Mr “Tetcacing was called to the Bar; and in the spring of the succeeding year, he accompanied his friend and relation Mr Kerr of Blackshiels on a tour to Paris, from which they returned by Flanders and Holland. The year 1776 was marked by the most important as well as the most fortunate event of his life, by his marriage to Miss Anne Fraser, eldest daughter of Witt1am Fraser, Esq. of Balnain,—an union which Fan long been the object of his se- cret wishes,—which now stata licked all the hopes he had formed of domestic happiness,—and which, after the long pe- riod of thirty-six years, unclouded almost by misfortune or dis- tress, closed at Jast in more grateful and profound affection than it at first began. At this period, when the business and the duties of life were opening fully upon him, Mr Tyrier seems to have made a very deliberate estimate of the happiness that was suited to his character, and to have marked out to hiniself, with a very firm hand, the course he was afterwards to pursue. His profession opened the road both to professional fame, and to civil distine- tion, and the circumstances of the times were of a kind to ani- mate LORD WOODHOUSELEE. 525 mate all his ambition of literary distinction. The period to which I allude, was perhaps, indeed, the most remarkable that has occurred in the literary history of Scotland. The causes which, since the era of the Union, had tended to re- press the spirit of literature in this country, had now ceased to operate: the great field of England was now opening to the ambition of the learned; and the ardour with which they ad- vanced into it, instead of being chilled by national prejudice or jealousy, was hailed by the applause of that generous people. The fame of Mr Hume was now at its summit of celebrity. After the honours with which the Histories of Mary and Charles V. were crowned, Dr Rozertson was laying the foun- dation of new claims to historical reputation ; and in the soli- tude of his native village, Mr Smrru was preparing that illus- trious work which was afterwards to direct the laws, and to regulate the welfare of nations. The different Universities of the country were vying with each other in the ardour of scien- tific pursuit, and in the dissemination of useful knowledge ; and from them there were annually advancing into life, some of those men who have since supported or extended the repu- tation of their country. The profession of law partook in the general spirit of improvement: the pleadings of the Bar began to display a more cultivated taste, and the decisions of the Bench to be directed by a more enlightened philosophy. The eloquence of Mr Locxuarr was still occasionally heard ; and Mr Erskine was beginning that brilliant career which so late- ly only has been closed. Lord Hares was carrying into the obscurity of our antiquities the torch of severe but sagacious criticism ; and Lord Kames was throwing over every subject almost of science or of literature, the lights of his own original and comprehensive genius. 3U 2 These 526 MEMOIR OF These were circumstances sufficient to excite and to justify ambition ; but although Mr Tyrrer was ambitious, it was not so much of fame he was ambitious, as of usefulness. The mo- desty, as well as the benevolence of bis nature, disqualified him for those adventurous speculations, in which nothing but perso- nal celebrity is attained; and in looking at the literary scene before him, the path that invited him, was not that which rises amid dangers and difficulties into solitary eminence, but that which follows out its humbler and happier way amid the duties and charities of social life. In all his ambition, too, there was (if I may use the expression) something always domestic. The honours to which he aspired were those which he could share with those he loved, and the “ eyes” in which he wished fo read his history, were not so much the eyes of the world, as those of his family and friends. It was with this moral and chastised taste that he looked even to the honours of his pro- fession: And when he recollected the brightest distinction it ever received, it was not Cicero in the Forum or in the Senate House, that was so much the object of his admiration, as Cicero at his Formian or his Tusculan Villa, amid the enjoy- ments of domestic friendship, and the delights of philosophic study. With these dispositions, Mr TyrLzr soon found, that the share of business which a young man can acquire at the Bar, was insufficient to employ the activity of his mind, and that the merely occasional attention which particular cases requi- red, was at variance with those habits of continued study in which he was accustomed to be employed. To consider law as a science was more congenial to his mind, than to consider it only as a profession ; and he became desirous, therefore, of engaging in some continued work, where (like some eminent men before him) he might entitle himself to the honours of his LORD WOODHOUSELEE. 627 his profession, rather by the labour of solitary study than by the celebrity of actual practice. While he was forming this resolution, the advice of his patron and friend Lord Kames, not only encouraged him to execute it, but suggested to him also a subject in which it might usefully he executed. As this incident gave origin to the first work which Mr Tyrtrr pu- blished, and as it is descriptive of the benevolent attention of that distinguished man to his younger friends, I am happy to be able to relate it, in Mr Tyrier’s own words, from a little manuscript account of the principal events of his life, which he has left for the instruction of his family. ——< The first time (says he) I became intimately acquaint- “ ed with Lord Kames, was, I think, in autumn 1767, when “he asked my father and me to accompany him on the South- “ern Circuit. We passed a few days with him at his estate of “* Kames, and thence travelled to Jedburgh and Dumfries. “ From that time I had the satisfaction of perceiving that. I “had some share in his good opinion, of which he gave me “many proofs. While prosecuting my studies in the law, I ** was wont frequently to resort to him for his advice, and in “the vacations I made many excursions to Blair-Drummond, “ where I staid for ten days or a fortnight at a time, and par- ~“ took in all his occupations either of study or of amusement. “ Having read to him alittle literary Dialogue which I had’ “composed, with which he was pleased, he gave me his. ad- ~ vice, to fill up my intervals of leisure by composing a set of “ Literary Essays: In consequence of which, I wrote a few de- “ tached sketches, which I shewed him from time to time. | It was upon one of these visits to Blair-Drummond, about three “ years after I had put on the Gown, that, in talking of some “of his Law Works, he asked me if ever I had attempted to “ write any thing in the way of my profession. I told him * that §28 MEMOIR OF “ that I had not, but that I was at that time meditating some- “ thing of that kind. He then proposed to me to write a Sup- plemental Volume to his Dictionary of Decisions, bringing * down that Work to the present time. I told him, that the “‘ boldness of the undertaking terrified me ; but that the good “ opinion he had shewn of me by making such a proposal, was “ certainly a strong inducement to me to make the attempt. “ T took, however, some time to deliberate upon it; and ha- “ ving at length resolved to undertake the work, I went out “ again to Blair-Drummond, to inform myself of the method “ he had followed in abridging and arranging the cases. These “ he communicated to me, and I set to work under his eye. “ The simple abbreviation of the printed cases occupied me “ above four years, and during all that time I read over occa- “ sionally to Lord Kames, the sheets of my abstracts, on which “ he gave me his notes and emendations. The arrangement “ of the cases gave me another year’s employment ; and while “ this was going on, I shewed the sheets, from time to time, to «“ Lord Kames, a great part of them to Mr Inay Campsexz, “ as also to the Lord President Dunpas, to all of whom I was “ much indebted. When the Work was completed and print- «« ed, I was much gratified to find that Lord Kags was plea- “*sed with it. Some passages in the Preface, apologizing for * defects, he desired that I would strike out. ‘ The Work, “ (said he,) does you honour; and a man ought not too much to ' “ yndervalue his labour, or depreciate his own abilities.” This volume of the Dictionary of Decisions was published in folio, in 1778; and of the character and value of the work, no other testimony is necessary after the sanction of the great Lawyers that have been mentioned. _ Mr Tyrter had now avowedly dedicated his life to the pur- suits of Literature, and his friends became anxious to see him placed a . LORD WOODHOUSELEE. 529 placed in some one of those public literary stations, where his talents and his industry might be more conspicuously displayed than in the retirement of private study. An opening of this kind soon occurred, which Mr Tytxer willingly embraced. The late Joun Prinexe, Esq. had been recently appointed to the Professorship of Universal History and Roman Antiquities in the University of Edinburgh ; but finding the discharge of the duties of it incompatible with his other employments, had ex~- pressed his inclination to resign it. The Class, (I believe,) in. its original institution, in this and in other Universities of Scot- land, had been intended as subsidiary to the study of the Civil Law. It had been taught always by Members of the Faculty of Advocates, and attended by students of that description : And it had, therefore, that degree of relation to Mr Tyt1izn’s own profession, that forfeited none of the hopes or expecta- tions he might form of its future distinctions. An arrange- ment was soon made with Mr Prinexe. In 1780, Mr Tyrrer was appointed Conjunct Professor, and in 1786, sole Professor: of Universal History. From that period until the year 1800, Mr Tyr1ter devoted his life almost exclusively to the duties of his Professorship ; and ten years of assiduous study were employed in the com- position and improvement of the Course of Lectures which he annually read in the University. - Of the character and value of that Course of Lectures I should have felt it a duty to have attempted some slight de- scription, if I were not prevented by the presence of many, to whom every attempt of this kind would be superfluous, and by the recollection, that while they remain unpublished, they cannot be the objects of public criticism. I may be permit- ted, however, to offer to the Society a few observations upon the views with which Mr TytLex entered upon his Professor- ship, 530 MEMOIR OF ship, and upon the plan he pursued in the conduct of his Lec- tures. The Class had hitherto been taught chiefly in relation to the Science of Law, to which it was considered as subsidiary. It was not so much Universal History that was the subject of prelection, as the History of Rome; and the views that were exhibited of Roman Antiquities, were chiefly those that were illustrative of the principles or progress of the Civil Law. Mr Tyruer felt that it became him to take a more comprehensive view of the subject ; to aim at higher utilities than those of a single profession ; to adapt his Lectures to the more libe- ral opinions which had arisen with regard to education, and the increasing celebrity of the University where they were to be delivered ; and in the course of them, (as he has himself ex- pressed it,) to exhibit a progressive view of the state of mankind from the earliest ages, of which we have any account,—to deline- ate the origin of states and empires,—the great outlines of their history,—the revolutions which they have undergone,—and the causes which have contributed to their rise and grandeur, or ope- rated to their decline and extinction. In the execution of a design so extensive, Mr Tyrxer’s at- tention was first directed to the choice of a Plan, or to the formation of a system of arrangement, by which he might be able to give some degree of unity and consistence to the great mass of materials that were before him. In examining the methods in which Academical Lectures on this subject had hi- therto been conducted, either in this country or on the Conti- nent, he perceived that there were two different systems which had chiefly been followed, and which may, perhaps, not impro- perly be styled the Narrative, and the Didactic Systems. In the first, the principle of arrangement was simply that of Chro- nology : the only order observed was the order of time, and the LORD WOODHOUSELEE. 531 the only object.of the teacher was to convey to the student the knowledge of the succession of historical facts. In the second, the principle of chronological arrangement was :alto- gether disregarded: the events of history were considered not as a branch of knowledge in themselves, but as a ground. work for the conclusions of science; and the great object of the teacher was to convey to the students the knowledge of the general puncinles of public law and of political philose- . phy. , In neither of Saniss systems did Mr Tyrrrr find the utilities which it was his ambition to derive from the subject of his lec- tures. The first appeared to him only a barren detail of chrono- logical events, in which nothing more was conveyed than the mere knowledge of the succession of these events ; and all that is included under the name of the Philosophy of Fass was 11e- cessarily omitted. In the second, he feared that too wide a field was opened to the ambitious speculations of the teacher, and that while the attention of the student was liable to be occu- pied by hasty or by unfounded theories, the interest of his- torical narration was necessarily lost, and all the moral instruc- tions of history neglected. » The system which Mr Tyrter finally ncléipted for his own course of lectures, was one which combined the advantages of both these systems, and was very happily adapted, both to maintain the interest and to consult the instruction of the stu- dent. In surveying with an attentive eye, the ancient history of the world, he observed, (to use his own words,) that it was distinguished, in every age, by one prominent feature; Thai one nation or empire was successively predominant, to whom all the rest bore as it were an under-part, and to whose history, we Jind that the principal events in the annals of other nations may be referred from some natural connection. In this remarkable Vox, VIII. P. II. 3X feature 532 MEMOIR OF feature Mr Tyrter saw that a principle of natural arrangement was afforded him, which might give to his course a sufficient degree of unity and order ; aad which, while it preserved to the student the interest of historical narration, gave to the teacher the opportunity of exhibiting those general views of the progress of the human race, which form the most import- ant instruction we can derive from its history. It was on this principle that his course of Ancient History was conducted. After some general prospects of what is known of the Assyrian and Egyptian Empires, he began with the bril- liant and interesting subject of Greece. He treated at length, the events of its civil and political history, and in conduct- ing his marr ative, brought occasionally into view the situation oft the nations by vibes it was surrounded. He then exami- ned the nature of the various governments which distinguish- ed it;—the different political institutions which they had adopt- ed,—the character of their military establishments,—their principles of colonization, and of internal regulation: And when time had conducted him to the ssielanieioly period of the extinction of their independence, he took a retrospective view of its literary history,—of the state of its attainments in arts and science, and, above all, of the nature and causes of that unequalled excellence which it attained in all the arts of taste. The next great subject which presented itself was the his- tory of Roi and in the views he took of this magnificent. portion of his course, he followed the same arrangement, and employed the same method of instruction. After recounting its obscure origin and infant institutions,—after tracing the progress of its political constitution, until it terminated in that. ilustrious Republic, which, though so long extinct, still reigns, as by some magic spell, over the minds and imaginations of mankind, LORD WOODHOUSELEE. 533 mankind,—he followed the progress of its arms through a world hitherto unknown 5 and thus gradually. introducing to the ob- servation of his students, those various nations of the North, that were destined i in future years to overturn this mi ighty fa- bric,. he made the easiest, but the most fortunate, transition to the history of Modern Europe, and: to the examination of the causes that produced the fall of Rome. . At this. eventful period, he again availed himself of the pause which history af- forded him, to take a retrospectiy e view of this great people, —to consider. their attainments in arts and arms,—to compare their. progress . in science and in literature with that of the mighty. people. that had preceded them,—and to indulge him- self in that illustration, of the excellence of their greater wri- ters, which he was so well qualified , to give, and which, far bet- ter than mere critical examination was wert to excite the admi- ration, and t to form the taste, of the young who heard] him. | The history | of Modern Europe : affor ded not to Mr‘ Tyrie the same fortunate principle of arrangement which he had found i in. the Ancient ; But another principle of connection presented . itself, of which he willingly availed himself. To the historian ‘of Modern Europe, the natural place of observa- tion is his own countr y. It isthe point . of view to which all his interests 1 most obviously conduct him, and from which all the events ¢ a the surrounding world f fall into somewhat of SYS- tematic order and harmonious d distance. ‘Tt was on this prin- ciple, therefore, that ; Mr Tyner conducted ‘his views | of mo- dern history. Considering ‘the history « of. their « own country as the, subject most important in the instruction o ‘of his stu- dents, he began by the ‘narration. ¢ of. the great e events of its ci- vil and military. story : He traced the : successive steps. of its progress i in ‘industry, i in legislation, in opulence, and i in refine- ment ; and | unfolded. y with, care the gradual 1 rise ‘of its political 3X 2 Coasieation, 534 MEMOIR OY constitution, until it terminated in the memorable era of the Revolution. From this central point of observation, he took occasion, at different times, to direct the attention of his stu- dents to the contemporary history of mankind,—to mark to them the successive changes that were occurring upon the Con- tinent of Europe —to introduce to them those new empires which at one period the frenzy of fanaticism, and at another the avarice of commerce, had revealed to the European eye,—and to awaken their attention to the mighty consequences which the establishment of Christianity, the invention of printing, the discovery of the New World, and the spirit of the Refor- mation, have had upon the general character and manners and happiness of modern times. With these great subjects he gladly at times interwove the history of literature and sci- ence ; and while his attention was chiefly directed to the pro- gress of British literature, he led the observation of his stu- debts to the contemporary history of learning upon the Eu- ropean Continent, and to the examination of those general causes which had influenced the successive steps of its pro- gress, from the time of the revival of letters to the brilliant period when his lectures closed. The success of this course of lectures was sufficient, (as Mr Tyrxer has said,) “ to compensate the labours of the author.” They came to form an important part in the system of general education ; and he soon numbered among his students, not only those who were destined to the profession of the law, but the young of every different description, whose education was con- ducted upon liberal and philosophical principles. The little vo- lume which he published in 1782, under the title of Outlines of a Course of Lectures, for the assistance of his students, became so popular, that he found himself called upon to present it to the world, in a larger form, under the title of Elements of Ge- neral LORD WOODHOUSELEE. 535 neral History, in two volumes. This work has since pass- ed through four editions, and has been found so useful‘ by those engaged either in the business of private or public edu- cation, as affording a concise and luminous arrangement of historical events, that it is now used as a text-book in some of the principal seminaries of education in England, and has Become (as I understand) the ground-work of historical study in some of the Universities of America.—Of the lectures them- selves, while they remain unpublished, it would be preposter- ous to offer any opinion: yet, when they are given to the world, I shall be much deceived, if they are-not found to fill up an important desideratum in English literature,—to afford. to the minds of the young more pleasing and more enlighten- ed views of the history of Man, and the progress of the Hu- man Race, than any other similar work in our language pre- sents them, and to accomplish the generous ambition of their author, in rendering the study of history subservient to the great end of all education, that of forming good men and good citi- zens. . ‘The labours im which Mr Tyrer was thus employed, were: sufficient to occupy, but not to engross, his attention. Hecon- tinued assiduously his practice at the Bar; and he followed, with the interest of a man of letters, the progress of Science - and Philosophy around him: ~The reputation which his taste and talents had now acquired, created many appeals to him for literary advice or assistance, and to him every labour was wel-. come, in which he could serve the cause either of literature or: of friendship. In 1778, when Dr Grecory was publishing an edition of the: Works of his Father, Dr Joun. Grecory, he solicited Mr Tyt- ter to prefix to it a short account of his life and’ writings. It was a task which Mr Tyrer willingly undertook, from his early: 536 - . MEMOIR OF early acquaintance with that eminent and amiable man, and he executed it with the simplicity almost of filial reverence and affection. The year 1779 was distinguished in this country by the ap- pearance of the celebrated periodical paper, The Mirror. :Ot the progress of a work which, both in its design and execution, did so much honour to Scotland, Mr Tyrier could not be an indifferent spectator. Although not properly a member of the Society, he was yet the friend of all who were known to be members of it. To the beauty and excellence of the serious papers in this work, Mr Tyrzer felt that nothing could be added ; but it seemed to him that something was wanting up- on the side of levity and gaiety ; ; not only for the purpose of temporary popularity, but to give to the serious papers them- selves their proper importance and relief. With this view, he contributed tothe Mirror the papers, Nos. 17.37. 59. and 79. ; and in 1785, to the Lounger, the papers, No. Tai 24. 44, G7. 70. 79. Of these papers the original manuscript happens still to re- in, fetta Mr Tinos was accustomed ta; pass his most ‘vacant hours. The manuscript occupies the blank Jeaves of some -sketch-books with which Mr Tyrer always, travelled, for the ‘purpose of ,landscape-drawing, and was written at inns, in the evenings after the journeys of. the day ,were.done. Tt was in this manner,that.the chearful activity of his mind found em- ployment and amusement every where ; and that the hours which most men pass in indolence or fretfulness,. were passed happily by him, in the offices of friendship, or in the enjoyments _of elegant composition, On the institution of the Royal Society in the year 1783, Mr Tyrer was,one of its constituent members, and was un- animously LORD WOODHOUSELEE. 587 animously élected one of the Secretaries of the Literary Classy —an office which he continued to fill with zeal for many years ; and in the execution of which he drew up that “ Account “ of its Origin and History,” which is prefixed to the Ist vo- lume of its Transactions. In 1788, he contributed to the Royal. Society a biographical Memoir of the Tate Roser Dundas of Arniston, Lord Presi= dent of the Court of Session,—a paper valle: not only for the just and vigorous delineation which it gives of the charac= ter of that eminent Judge, but for the interesting account it pis some of the earlier branches of a family, so long and so honourably distinguished in the legal annals of Scotland. In 1789, Mr Tyrirr read a paper to the Royal Society up- on the Vitrified Forts in the Highlands of Scotland. Of these singular antiquities, the prevailing theory had been, that the vferiremttaet was produced i in the process of their erection, and that it was the substitute of a rude age forcement. The theory which Mr Tyrier suggested was Hie aVEHSdemr ths | ;—that the vitrification was the result, —not of their erection, but of their: destruction,—and that it was produced by the efforts of ene- mies in attempting this destruction by fire. The theory is cer- tainly not without some appearances of probability : it assimi- lates sufficiently with the period of society to which such build-. ings undoubtedly refer; and Mr Tyrier was able to support it with learning and ingenuity. Of the impression it made at ihe time upon ‘the Society, I am happy to be able to refer to: an evidence of no little weight, in a letter from our late illus- trious associate Mi Smrru to Mr Tytier upon the subject and, althougl 1 the letter is very short, I persuadé myself that it will not be unacceptable to. the Society, both because there are unhappily very few letters of this. great man remaining, and becaiise it involves also. the memor 'y of some other men, , whose: 588 _. MEMOIR OF whose names can never be listened to in this place without emotion : Dear Sir, “ T have read over your paper with the greatest pleasure. The composition is what it ought to be, simple, elegant, and perfectly perspicuous, and will be avery great ornament to our Memoirs. Some of my chemical friends, however, are of opi- nion, that the degree of vitrification which takes place in the specimens of these forts, is too great to be the effect of any ac- cidental fire, such as you suppose, and could be produced only by a great accumulation of wood, heaped upon the wall after it was built. This is a subject of which Iam ignorant. You had convinced me, who fancied that this imperfect vitrification was more likely to be the effect of accident than of knowledge. The friends I mean, are Dr Brack and Dr Hurron, who in every other respect entertain the same high opinion of your composition which Ido. You had better converse with them : you may convince them, or they may convince you; and even though neither of these two events should happen, the offence, I apprehend, will not be great, either to them or to you. I have the honour to be, Me . “ Apam Smit.” In the year 1790, Mr Tyrer read in the Society those pa- pers on Translation, which they who heard them will remem- ber to have been listened to with so much pleasure, and which he soon after published without his name, and under the mo- dest title of an Essay on the Principles of Translation. The work was scarcely published, when it occasioned a correspon- dence with the late learned and ingenious Dr Campsext, Prin- cipal LORD WOODHOUSELEE. 539 cipal of Marischal College, Aberdeen, from which, however painful at first, Mr Tyrier might easily have foretold its fu- ture fortune in the literary world. Dr Campzeti had, some time previous to this, published his Translation of the Gospels, to which he had prefixed, in a preliminary dissertation, some very acute and ingenious observations, upon the principles of translation. Upon the publication of Mr Tytier’s anonymous work, he immediately procured it, and was so much struck with the coincidence of their views upon the subject, that he wrote to his printer Mr Creecu, to know who was the author; and while he acknowledged himself “ to have been flattered not a “ little to think, that he had in these points the concurrence in judg- “ ment of a writer so ingenious,’ he expressed at the same time some suspicion, that the author might have borrowed from his Dissertation, without acknowledging the obligation. Mr Crrecn, with great propriety, communicated the letter to Mr Tyter; and he instantly wrote to Dr Campsex, acknowledging himself to be the author, but assuring him, that the coincidence of sen- timent was purely accidental, and that the name of Dr Camp- BELL’s work had never reached him until his own had been composed. “ The coincidence of our general principles, (says “ Mr Tyrer), is indeed a thing flattering to myself; but I can- “ not consider it as a thing at all extraordinary. There seems “ to me no wonder, that two persons, moderately conversant in “ critical occupations, (I am far from thinking equally so ), sitting “ down professedly to investigate the principles of this art, should “* hit upon the same principles, when in fact there are none other “© to hit upon, and the truth of these is acknowledged at their first “* enunciation. In my opinion, there would, on the contrary, be just “ matter of wonder if they did not hit upon them. But in truth, “ (concludes Mr Tyt Er), the merit of this little essay, (if it has “ any ),does not, in my opinion, lie in these particulars. It lies in the _ Vou. VIL P. IE “i “ establishment 540 MEMOIR OF establishnient of those various subordinate rules and precepts,which apply to the nicer parts and difficulties of the art of translation ; in deducing those rules and precepts which carry not their own authority in gremio, from the general principles which are of acknowledged truth, and in proving and illustrating them by evamples. How far you may have anticipated me even in this respect, I cannot say, until I have perused your Dissertations. They appear to contain a rich mine of philological and critical learning ; and I am confident, that if my book comes to a se- cond edition, I may be able to profit much by your remarks. In that case, f shall most cordially, and with the highest pleasure, acknowledge my obligations.” To those that are acquainted with the character of Dr Camp- BELL, it will be unnecessary to add, that he received Mr Tyr- Ler’s explanation with the most candid and polite liberality. s . « o 2 r The lelier you favoured me with, (says he), made me both ashamed and vexed, that F should have been so rash as to ex- press myself to Mr Creecu in a manner which could give a moment's uneasiness to a man of merit, especially one whom I consider myself as having the honour to call a friend. When I wrote that letter, I neither knew nor suspected who the au- thor of the Essay was. Had I known what I now know, the name of the author alone would have convinced me that the co- incidence was merely accidental.—Your arguments are good, but I was sorry you had recourse to them; sensible as I am, that if your declaration had not been sufficient to satisfy me, I did not deserve to be satisfied. Mathematical demonstration, - were you to attempt it, would not give me stronger conviction than I already have, that what you say is the truth. But to have done with the disagreeable part of this mistake, (he con- cludes), J cannot avoid mentioning one circumstance in this in- cident, which to me is always extremely agrecable, the evidence © which LORD WOODIIOUSELEE. 54] “ which it gives of a concurrence in sentiment upon critical sub- Re ects with persons of distinguished ingenuity and erudition. “ Such a discovery makes a man more confident in the justness of “ his own sentiments. I have only to add, that your illustrations “ of the general si and your examples fr om the ancients, “ please me exceedingly.” The opinion of Dr Campsett was very soon justified by the voice of the literary world ; and 1 believe that there is no work of literary criticism which this country has produced, that so soon attained celebrity in England, as the Essay on Translation. The different reviewers of the day, contended with each other in the earliness of their notice, and in the liberality of their praise. The most celebrated scholars of England, Dr Mari«nam, Arch- bishop of York, Dr Dovcxas, Bishop of Salisbury, Dr Percy, Bishop of Dromore, Dr Vincent, of Westminster, and Dr Wat- son of Winchester Schools, wrote to the author in terms of high approbation. “ Were I not afraid,” says Mr Murpny, the well- known translator of Tacitus, in a letter to the author, “ of be- “ ing thought a dealer in compliment, I should say, that I esteem “ it the best performance I have ever seen on the subject. In- genious hints, and cursory remarks, are to be found in many “ authors, ancient and modern; but they remained scattered, and “ nothing like a regular system has been formed until now.” And Mr Cumpertanp, the extent of whose learning, and the fertili- ty of whose genius gave so much value to his opinion, was so much delighted with the work, and so grateful for the just praise which Mr Tytter had bestowed upon his admirable translations from the fragments of Greek comedy, that he wrote to his friend Sir Wittiam Forsrs, to beg of him to pro- cure Mr Tytxer’s permission to dedicate to him a translation of The Clouds of AxisrorHanes, which he was then preparing, and which the praise of so distinguished a critic had encouraged 3Y2 him 542 MEMOIR OF him at first to undertake. To the opinion of these eminent men, it may be supposed I very willingly subscribe; yet, I must add, that the work has always appeared to me as entitled even to a higher praise. In its plan, indeed, it appears to re- late only to the principles of translation ; but in its execution, it necessarily involves the principles of composition in gene- ral; and in the nature and variety of the examples he adduces, and the acuteness and delicacy of the criticism he employs, Mr Tyrer seems. to me to have made use of one of the happiest methods to lead the minds of his readers to a sense of those fine and evanescent beauties in composition, which abstract language can so imperfectly express, and which affords. the best preparation, not only for the task of translation, but for the higher purpose of original composition. The Essay on the Principles of Translation has now passed through five editions, in each of which the author has been anxious to repay the approbation of the public, by the addi- tions he has made; and after the experience of fifteen years, it may now be considered as one of the standard works of = lish criticism. While Mr Tyrrer was thus actively and usefully Sinjohayel, the Government of Scotland began to consider him as one who was fitted to share in its administration, and Lord Mezviixe thought himself now entitled, by the character which Mr Tyt- Ler had established, to testify to the public the sentiments of his private friendship. His practice at the Bar, though not extensive, had been respectable, and, in the conduct of it, he had shewn sufficiently the talents he possessed for business. His honour was high,—his integrity acknowledged,—and_his manners amiable and conciliating. His political opinions were those of hereditary loyalty ; and in the acceptance therefore of office, he had none of those sacrifices of principle to make, by which LORD WOODHOUSELEE. 543 which the course of political. ambition has been sometimes de- graded. In the year 1790, he was appointed een Sete ‘af Scotland, in the room of Mr Cuartes Hope. The office of Judge-Advocate, it had: hitherto, (I belicre), been usual to execute by deputy; but Mr Tyrer was not of a character to. make any compromise with duty, or to accept of office, without accepting of all its obligations. He made it his _ business, therefore, to attend upon every trial: he-gave to every case his most careful and considerate attention ; and so anxious was he-to fulfil his duty to the utmost, that he took the trouble of drawing up, for his. own direction, a Treatise upon Martial Law, which afterwards, when he retired from the office, he gave to:the public, and which has (I-understand) been found of the: most bn use in. - decision of cases: of this ery 5 ae Into the: detail of Mr Dveenicn’ s conduct in the — of this delicate but important office, it would be presumptuous in me to enter; but I may. be permitted to relate, from his corre: spondenee, a.single incident, which illustrates both the con- sciousness with which he discharged his duty, and the respect in which his, opinion was held by those who were then.ati a head of the Military Department. _A court-martial had been held‘at Ayr, with the sentence of ville Mr Tyrier-was extremely dissatisfied, and to the injus- tice of which, he had: anxiously, but.in vain, endeavoured at the time to awaken the attention of the Court. Upon trans- mitting the proceedings to London, Mr Tyrirr thought it his duty to communicate the grounds of his dissatisfaction. with: the sentence to Sir Cnartes Morean, then Judge-Advocate-. General, and, in the most earnest terms, to implore his atten- tion to the case, if his Majesty should (as was probable) refer it to his decision. Sir Cartes Morean cheerfully undertook the 544 MEMOIR OF the revision of the case: his opinion coincided in every respect with that of Mr Tyrer; and to the letter in which Sir Cuarzes communicated to him his Majesty’s disapprobation of the sen- tence, Mr Tyrrer added the following note: “I have thus “ had the satisfaction of procuring from his Majesty a disap- ** proval of this very unjust sentence, and a rectification of it “in every point where it was wrong.” In the year 1792, Mr Tyrrer had the misfortune to lose his father, at the advanced age of eighty-one. Of the character of this excellent man, the Society already possesses a description by Mr Mackenzie, which no one will attempt to improve. The loss to his son was of a kind which it is the fortune of few men to experience. Their connection had subsisted for the long period of forty-five years, undiminished by distance, and un- broken by misunderstanding ; and there was so singular a cor- respondence in their tastes, their pursuits, their principles, and even their prejudices, that Mr Tyrurr felt he had not only lost a father, but his best and oldest friend. His first employment was to design a little monument to his memory, which he soon after erected in the pleasure-grounds of Woodhouselee, upon a spot which his father had particularly loved ; and he engraved upon it the following inscription, which so well expresses the filial tenderness of the author, and so happily obeys that pro- found and merciful propensity of sorrow, which leads us stilk to fill the scenes we love, with the presence of those we have lost. LORD WOODHOUSELEE. ; 545 M.S. GULIELMI TYTLER, de Woodhouselee, H. L. P. F. En virides aras, en hance quam ponimus urnam, Tu, fil ex manibus respice dona, Pater ! Sie, venerande Senex, olim qua rura placebani Sint eadem busto nunc decorata tuo. _ Neve Tibi desit post funera sueta voluptas, Proximo ab umbroso cantet avis nemore, Et qui Te placido lenibat murmure rivus, Dulcia perpetuis somnia portet aquis- By the death of his father, Mr Tyrier had succeeded to ‘the- estate of Woodhouselee ; and some years before that period, Mrs Tytxer had, in a similar manner, succeeded to the pater- nal estate of Balnain in Inverness-shire. He was now in cir- cumstances of aifluence,—his friends were numerous,—his own. disposition in the highest degree hospitable and kind,—and he felt himself at liberty to attempt to realise some of those visions of retired and rural happiness, which had long played in his ima- gi ation, and which form, perhaps, one of the earliest reveries: ae generous or cultivated mind. He began, therefore, immediately to embellish his grounds, to extend his plantations, and in the enlargement of his house, to render it more ade- quate to the purposes of hospitality; and in the course of a short period, he succeeded in creating a scene of rural and do- mestic happiness, which has seldom been equalled in this coun- try, and which, to the warm-hearted simplicity of Scottish manners, added somewhat of the more refined air of classical | elegance. 546 MEMOIR OF elegance. It was here, from this period, that all his hours of enjoyment were passed,—that all his works were composed,— and that, in the bosom of his family, and amid the scenery and amusements of the country, he found the happiness that was most congenial to his character and disposition. His morning hours were uniformly given to study; but his studies were of a nature that tended rather to animate than to fatigue his mind. It was not in abstract or metaphysical spe- culations he was engaged, where the understanding only is ex- vercised, and where the progress of discovery is so little propor- tioned to the time or labour that is employed ; nor in works .of imagination, where the mind is ever in pursuit of that ideal ‘excellence which it is never destined to attain. The historical, the antiquarian, or the critical studies in which he was engaged, required no painful concentration of thought, and no laborious processes of reasoning. They related to the deeds and lan- guage of men, where it was not the understanding alone that was employed, but where the imagination and the heart were per- petually exercised ; and he could rise from them to the com- mon business or offices of life, with a mind undistracted by doubt, and unfatigued by abstraction. The employments to which he gave his hours of exercise, were of the same gentle and cheerful kind. He had little relish for the sports of the field, unless angling, in which, like the amiable and contem- plative Watton, he had from his early days delighted; but he took great delight in gardening, in the embellishment of his pleasure-grounds, and, more than all, in improving the dwellings, and extending the comforts of his cottagers,—an occupation, in which taste so fortunately combines with bene- ficence, and in which, fer all the labour or expence he bestow- ed, Mr Tyrer found himself every day rewarded, by seeing the face of nature and of man brightening around him. ' The : i ‘ LORD WOODHOUSELEE. 547 The society that assembled at his table, was the best that at that period this country afforded,—his own famil} y-relations,— the families of the neighbouring proprietors in the populous county of Mid-Lothian,—most of the men eminent in science or in literature, of which our metropolis was then so profuse,— and occasionally those strangers of distinction, whom the love cof science or of nature had induced to visit Scotland. His hos- pitality was cordial, but unobtrusive,—his attentions were so uunostentatious, that his visitors found themselves at once at home,—and he himself appeared to them in no other light than as the most modest guest at his own table. The conver- sation which he loved, was of that easy and unpremeditated kind in which all could partake, and all enjoy. To metaphy- sical discussion, or political argument, he had an invincible dislike ; but he gladly entered into all subjects of literature or criticism,—into discussions on the fine arts, or historical anti- quities, or the literary intelligence of the day; and when sub- jects of wit or humour were peated, the hearty sincerity of his laugh, the readiness of his anecdote, and the playfulness of his fancy, shewed to what a degree he possessed the talents of society. His sense of humour was keen, but at the same time characteristic: it was the ludicrous, rather than the ridiculous, in character or in manners, which amused him: those excesses rather of the amiable than of the selfish or sordid passions, which are observed with a sentiment of tenderness as well as of disapprobation, and which the poet has so happily express- ed by the phrase, circum precordia ludit. The humour of most men is unhappily mingled with qualities which add little to the amiableness, and still less to the respectability of character. From the gayest conversation of Mr Tyrzer, on the contrary, it was impossible to rise, without a higher sense of the ed of his taste, and the benevolence of nt nature. VouVvil ee ee 3Z it IO B94 His 548 MEMOIR OF His evenings were always passed in the midst of his family, either in joining them in the little family concerts with which, like bis father, he always wished to close the day, or in read- ing aloud to them some of those works by which he thought their tastes or their minds might be improved; or, not unfre- quently, when none but his more intimate friends were pre- sent, in sharing with his younger children in those various youthful amuseinents which contribute so much to the gaiety of domestic life, and in which the affections of kindred, and the love of home, are so well, though so insensibly cultivated. Of this scene of simple and virtuous happiness, there are some present who will not easily part with the remembrance, though accompanied with the melancholy reflection that they can meet it no more; and Mr Mackenzie will, I trust, forgive me for reminding him of an expression which he used to me many years ago, when I accidentally met him upon the road as he was returning from Woodhouselee, and which conyeys so much better than any thing I can say, the character of the scene. “ I hope,” said he, “ that you are going to Wood- “ houselee ; for no man can go there without being happier, “ or return from it without being better.” To this picture, however, there is yet another feature to be added : it is in the sentiments with which Mr Tyrer felt the prosperity he enjoyed. In the little MS. volume from which I have formerly quoted, (and from which I should more fre- quently quote, if I did not feel it a kind of profanation to ex- pose to the eyes of the world that train of secret thought which was intended. only for the eyes of his children), I find the fol- lowing passage, for the introduction of which, I am sure I need no apology, and which expresses, in a manner which no bio- grapher can do, the governing principles and persuasions of his mind. It was written on his birth-day, 15th October 1795. 6h I LORD WOODHOUSELEE. 549 «“ | have this day (says he) completed my forty-eighth year, and the best part of my life is gone. When I look back on “« what is past, [am humbly grateful for the singular blessings “ T have enjoyed. All indeed that can render life of value, “ has been mine. Health, and peace of mind;—easy, and even “ affluent circumstances ;—domestic happiness ;—kind and af- “« fectionate relations ;—sincere and cordial friends ;—a good “* name ;—and, I trust in Gop, a good conscience. What “ therefore on earth have I more to desire? Nothing; but if “ He that gave, so please, and if it be not presumption in me “* to pray,—a continuance of those blessings. Yet, if it should “ be otherwise, let me not repine. I bow to His commands, “ who alone knows what is best for his creatures; and I say “ with the excellent Grorivus, a o «¢ Hactenus ista: latet sors indeprensa futuri ; Scit, qui sollicitum me vetat esse, Devs. Duce genitor me magne! Sequar, quocunque vocabor, Seu Tu lata mihi, seu mihi dura, paras.— Sistis in hac vita? Maneo, partesque tuebor Quas dederis. Revocas, Optime? Promptus eo.” The melancholy change for which Mr Tyrrer seems thus to have prepared his mind, was soon to take place. In the au- tumn of the year 1795, he was seized with a long and dange- rous fever, accompanied with delirium, and tending frequently to relapse. Under the anxious care of his friend and physi- cian Dr Greeory, he recovered from the fever; but in one of the paroxysms of the disease, he had the misfortune to rupture some of the blood-vessels of the bladder,—an accident which not only protracted his recovery at the time, but which threa- tened to degenerate into one of the most painful diseases to which the human frame is subject. . 3 Z2 In 550 MEMOIR OF In the state of weakness and suffering which succeeded this severe illness, Mr Tyrier was for a long time incapable of re- turning to his professional studies: but his mind was incapable of inactivity; and he turned willingly to those pursuits in na- tural history which had formed the amusement and the delight of his youth, and which are perhaps of all others the most suit- able to the grateful feelings of convalescence. Among the works with which he now amused himself, was the once celebrated treatise of Dr Dernam, entitled Physico- Theology. In perusing it again, with all the affecting associa- tions which the past .and the present afforded him, he could not but lament, that it was in some degree rendered obsolete, by the innumerable discoveries with which science has been enriched since its publication, and that its popularity among those to whom it might be most serviceable, was restrained by the number of Latin quotations which remained without a translation. It occurred to him that his hours of convalescence could not be better employed than in remedying these defects, and in thus extending the usefulness of a work of which he had himself felt the value. This pleasing and unfatiguing task he executed with his usual ardour, and prefixing to it a short but valuable dissertation on Final Causes, published it in the year 1799. Of this work, it is unnecessary for me to enter into any fur- ther detail; but I cannot omit a passage relating to it, which I find among Mr Tyrxer’s papers, and which marks distinctly the great principle by which his studies as well as his conduct were governed. “ Of all my literary labours, (says he,) that which affords me “ the most pleasure on reflection, is the edition which I pu- “ plished of Derham’s Physico-Theology. ‘The account of the “ Life and Writings of Dr Dzruam, with the short disser- “ tation LORD WOODHOUSELEE. 55k ** tation on Final Causes, the translation of the Notes of the Author, and the additional notes, containing an account of ‘those more modern discoveries in the sciences and arts “which tend farther to: the illustration of the subjects of the work, are all the original matter of the edition to which I have any claim ; so that the vanity of authorship has a very small share in the pleasure I enjoy from it. But when en- ‘gaged in that work, I had a constant sense that I was well employed, in contributing, as far as lay in my power, to- ‘those great and noble ends which this most worthy man proposed in his labours, by enforcing on the minds of man- -kind-the conviction of an all-wise and. all-beneficent Author of Nature. The» demonstration, in short, of that great and ‘central truth, on. which depends our present happiness and -our future hopes. Since the publication of this edition, some other excellent works have appeared upon the same » subject, from which many valuable additions may be made to the Notes.on Deruam; and-I intend, accordingly, to make: those additions, if a-new edition should be wanted in my “ lifetime.” The year 1799 was distinguished by the agitation of the great question with regard to the Union with Ireland ; and in attend- ing to the debates it occasioned; Mr:'Tyrtxer thought that no: view of the subject.could be better fitted to conciliate the minds: of the Irish people to this important measure, than a represen-. tation of the benefits which Scotland had derived: from the Union with England. These observations he threw: into the. form of a letter; and they were published at Dublin, with the title of Ireland profiting by Example ; or the Question consider- ed, Whether Scotland has gained or lost by the Union? Of this. little work. it is enough to say, that.such was its merit, or its: - popularity, 552 MEMOIR OF popularity, that three thousand copies were sold upon the day of its publication. ; In the year 1801, a vacancy occurred in the Bench of the Court of Session, by the death of Lord Sronerrerp. The ‘ friendship of Lord Mrtvite had a new opportunity for its display ; and the friends of Mr Tyrrer had now the satisfac- tion of seeing him elevated to the highest honours of his pro- fession. On the 2d of February 1802, he took his seat upon the Bench with the title of Lord Woopuovuseter. Of Lord Woopnovseter’s qualifications for this important office, it would be presumptuous in me to offer any opinion ; and I feel, with gratitude, that it is unnecessary, as, of all the honours which the Government of this country has to bestow, those which have been in the estimation of the public most purely won, and most honourably. worn, are those which belong to the Administration of Justice. He brought not the Bench, indeed, either that profound acquaintance with the details of law, which nothing but continued and extensive practice can give; nor that metaphysical acuteness, which so often seeks to distinguish itself by subtlety of distinction, or novelty of inter- pretation ; nor that impatient eloquence, which loves to find in the most trivial cases, an opportunity for ifs own display. But he brought to it qualities, in a country like this, of higher va- lue, and of more genuine usefulness,—a just and enlightened adiniration of the laws he was called to administer,—the most conscientious patience in the investigation of truth,—and a mind incapable either of being intimidated, in the discharge of duty, by the dread of censure, or of being misled by the love of praise. In his conduct on the Bench, the characteristic in- tegrity and modesty of his nature were apparent. In this, as in all other situations, his highest ambition was to be par ne- goltis, non supra,—to be able to fulfil his duty without seeking for LORD WOODHOUSELEE. 55E for personal fame; and to accommodate his conduct, not so much to the opinion of men, as.to that higher standard, which existed in his own breast. There-were, however, occasions when his. powers were more peculiarly called forth ; and, upon some of these appearances from the Bench, there are many of us who can remember the high praise that was bestowed by the late Lord President Brairn,—a man whose praise was fame, and who was of too proud an integrity to bestow it where he did not feel it was deserved. From the period of his. elevation to the: Bench, Lord Woop- HousELEE devoted his time exclusively, (while the Courts were sitting,) to the business that arose; but, during the vacations, he was always happy to return to his private studies. The so- litude of the country, (to which he then always retired,) invited him to labour; and as he was now free from his academical engagements, and from that continued attention which the im- provement of his lectures occasioned, he had time to return to the consideration of some of the literary projects which he had formed in his earlier days, and which he hoped he might now be able to resume. One of these, I find, was the literary and political Life of Bucnanan ; a subject which was interesting to him from many associations, and in which he proposed to do. ample justice to his genius as a poet, and his merits as a histo- rian, but to examine, with firmness and accuracy, his conduct: as a man, and as a politician. Another was to give a faithful translation of Campen’s An=. nals of Elizabeth, iliustrated with notes, and comparing it with. the best accounts of her time that have since been published. The subject had been suggested by Dr Campzett in the Bio- graphia Britannica, and in the view which Lord Woopnouse- LEE took of it, it promised him the opportunity of exhibiting a fuller and more faithful picture of that interesting period in. English. 554 MEMOIR OF English history, than had yet been accomplished in any one performance in our language. The most important, however, of these literary projects, was that of a continuation of Lord Hartes’s Annals of Scotland, from the period when Lord Hares’s researches closed, to the accession of James VI. to the Crown of England; a work to which no common talents were adequate, and of the difficulty of which no stronger evi- dence can be given, than that, however desired, it has yet re- mained unattempted. All these projects, however, yielded to another, which was much more interesting to Lord Woopnouserre himself, and to the accomplishment of which he was animated by some- thing more than the hope of literary fame,—this was the Life of his earliest friend and patron Lord Kamrs. ‘ He had wait- “ ed, (as he says,) with his usu-] modesty, for more than twen- “ ty years, in the hope of its falling into abler hands.” He was now raised to the same Bench isi had been dignified by the presence of Lord Kames ; and the business in which he was engaged, served every day to bring him to his remem- brance, and to afford him the new opportunities of appretiating his learning and his genius. From this fortunate concurrence _of circumstances, Lord Woopuovse.re felt himself emboldened to undertake the task, and having determined upon his plan, he entered with eagerness upon the study of his works, and the collection of materials; and in the course of the vacations of only four years, he was able to accomplish his design. The work was finally published in two volumes, quarto, in the year 1807, with the title of Memoirs of the Life and Writings of Henry Home, Lord Kamrs. It is impossible not to admire the motives which led Lord Woopuovsetze to this undertaking, and it is impossible also not to respect the ability with wont amid the distractions of public LORD WOODHOUSELEE. 555 public business, and the sufferings of infirm health, he has been able to execute it; yet 1 know not if the friends of Lord Woon- HOUSELEE’s literary fame have not some reason to lament his choice of a subject ; and there are circumstances in the extent and variety of Lord Kames’s powers, which seem to me to place him almost beyond the reach of the biographer. The fortunate subjects of biography are those, where some powerful and uniform interest is maintained,—where great minds are seen advancing to some lofty and determinate ob- ject,—and where, amid the toils or the difficulties they have to encounter, the mind of the reader feels somewhat of the same anxious and unbroken interest, with which we follow the pro- gress of the drama, or the narrative of the epic poet. The lives -of conquerors, and of legislators,—of discoverers in science, _or of inventors in the arts,—of. the founders of schools in phi- losophy, or of sects in religion, it is impossible even for the rudest hand to trace, without awakening an interest which ail men can understand, and in which all can participate; and even the history of inferior men can yet always be made inte- resting, when one object of ambition is seen to be steadily pur- sued, and one correspondent sympathy is awakened. Of this unity of pursuit, and of interest, the Life of Lord Kames was singularly destitute. There was a vigour in his powers, and an elevation in his ambition, that were incapable of being re- ‘strained within the limits of any one pursuit ; and he seems to have felt it to be his peculiar destiny, to take the lead in every science by which the reputation of his country could be -exalted, and in every art by which its prosperity could be in- creased. To delineate the progress of such a mind; to follow his steps in all the various fields of inquiry through which he travelled,—to mark with precision the accessions that science derived from his labours, or the arts from his suggestions, was Von. VIII. P. II. 4A a ied 556 MEMOIR OF a task to the execution of which, few men could bring adequate knowledge or capacity ; and, even if it could have been execu- ted, there were still fewer readers who could preserve any con- tinuity of interest in a progress so eccentric, or be able to make perpetual transitions from the subtleties of metaphysics to the details of husbandry, or from the refinements of philo- sophical criticism, to the technical questions of Scotch law. The emblem of Lord Kames’s genius was not that of the Gan- ges or the Indus, which roll forward their condensed streams, and fill the eye of the spectator with their simple and increa- sing’ majesty ; but that of the Rhine or the Nile, which divide the volume of their waters into innumerable branches, and, while they fertilize a wider surface, yet perplex the eye, that labours to number and pursue them. What fidelity and affec- tion could do, upon a subject so difficult, Lord WoopnovusELEE, I apprehend, has done. He has given the portrait of Lord Kanes, with all his various and characteristic features ;—he has surrounded him with his contemporaries, and sketched out, in many pleasing and interesting details, the literary history of the age in which he lived ;—and his work, like those of Pia- ‘ro and of Xrnornon, will descend to posterity with an interest which no other can now possess, that of being executed from the living subject, and of blending the veneration of the dis- ciple with the fidelity of the historian. In the year 1811, Lord WoopuovsELEE was appointed to the Justiciary Bench, on the elevation of the Lord Justice- Clerk Horr to the President’s chair. Although Lord Woonuovserner was now advancing in age, and his strength declining, yet the publication of the Memoirs of Lord Kames did nat put a period to his literary activity. It was now too late, indeed, for him to resume any of the lite- rary projects which he had once hoped to accomplish : but he returned LORD WOODHOUSELEE. 557 returned willingly to another occupation, with which he had always intended to close his literary career. This was the re- vision of his lectures upon history. In the composition of these lectures, the best years of his life had been employed, and at the distance of time that had intervened, he was now able to review them with the eye of impartial criticism, and to make such additions or alterations as might better fit them for that general usefulness for which they were .originally intend- ed. To this pleasing occupation all his remaining seasons of leisure were devoted ; and with the usual chearfulness of his temper, he flattered himself, that he might be able to accom- plish a revision of the whole of the lectures that composed his Academical Course. As the first great subject of these lectures related to Grecian History, he now began anew the study of the Greek historians ;, and as his views included the history of science, of literature and of the fine arts, he was Jed insensibly to the study of the moralists, the orators and the poets, of that interesting period. So fascinating to his mind was the occupation, that, in the course of a few vacations, he was able to compose anew the whole of his lectures upon Grecian History, and to be rewarded by that peculiar delight, (which has been so often observed in the later years of literary men,) the delight of returning again to the studies of their youth, and of feeling, under the snows of age, the chearful me- mories of their spring. In the year 1812, the death of his friend and relation Gene- ral Sir James Crate, (the late Governor of Canada,) and the property to which he succeeded. by his will, rendered it neces- sary for Lord WoopuouseELze to undertake a journey to Lon- don. -As Sir James Craic had been distinguished by the Order of the Bath, it became the duty of Lord WoopuousEteExz, as his nearest relation, to return to the Prince Regent the ensigns of 4A2 the 558 MEMOIR OF the Order ; and for this purpose his Royal Highness was piea- sed to grant him an audience. Of this interview Lord Woop- HOUSELEE always spoke with gratitude, not only as it afforded. him the opportunity of observing that dignified courtesy by which the manners of the Prince Regent are distinguished, but as it shewed him the intimate acquaintance which his Roy- al Highness possessed with regard to the affairs of Scotland, and the interest which he took in her progress in science and in literature. Some time after the interview with the Prince Regent, it was intimated to Lord Woopuouszxez, that, if agree- able to him, the dignity of Baronet would be conferred on him, which he requested permission to decline,—an instance of mo- desty, which surprised no one to whom Lord WoopuousELEE was known; and which (I am proud to say) was to none so ac- ceptable as to his own family, to whom no illustration could be so dear as that of their father’s name. I am led, besides, to mention this journey of Lord Woop- I0USELEE to London, as it gives me the opportunity of intro- ducing a little composition to which it gave occasion, and which ought not to be omitted in any account of his life. He had for some time believed, that the disease under which he Jaboured was soon to be fatal; and a little before this, he had given or- ders that his family burial place should be repaired, and had inscribed upon it an epitaph, full of tenderness and of affec- tion, to the memory of his father and his mother. In leaving. London for the last time, and returning to his own country, it was natural for him to look forward to the event which he had long thought approaching, and to that final home where he was to rest with his fathers. Under these impressions the follow- ing lines were composed, as he was returning homewards; and as they afford a picture of his mind which no Biographer could ' reach, LORD WOODHOUSELEE. 559 reach, I trust I need no apology for introducing them in this place. . i ae The Verses are entitled : I~ Sepulchrum meum avitum, in Cemeterio Francisconorum, Edinburgi, nuper re-zedificatum. Jam duodecimum condere lustrum Contigit,—et jam cernere canos Vertice summo, dum fatiget impigra quondam membra gressus, ony Nec oculi vigeant nec aures, ty? - Hebeat et prorsus sensuum acumen.— —Hee sunt nec tarde indicia mortis.— Hisce admonitus Fati nunciis, Refici avitum denuo Sepulchrum ° Curo, et cineris protegi injuria Mistz ut amicis reliquiis cubent,, —Hic enim juncti quondam vita (Nec sivit divelli fatum), Dormiunt una Pater et Mater, ‘2 Purusque et pius ordo Parentum.—— Salve ! O vitai Anchora et Portus-!’ | Salve ! laborum terminus et quies! Salve ! brevi subeundaque tecta. Hospitium viatori fesso ! Te specto impavidus ; te longam. Per noctem fidus sis custos, Et reddas (precor) incolumem DEO. The event to as Ford Woopnousetze thus steadily look- ed forward was now approaching. In June 1812, after super- intending 560 " -MEMOIR OF intending his workmen in some improvements he was making at Woodhouselee, he felt that he had fatigued himself, and he was soon sensible of the recurrence of the same unfortunate accident which had laid the foundation of so many years of suffering. From this period, the remainder of his life was a scene of coittinued pain and increasing debility,—borne, in- deed, with the most calm and even chearful resignation, and relieved by every thing that filial and conjugal tenderness could supply, yet too visibly approaching to a period which neither tenderness nor magnanimity could avert. In the beginning of winter, he was prevailed upon to leave his favourite Woodhouselee, and to remove into town; and from this time his disease appeared to make a more rapid pro- gress. On the 4th of January 1813, he felt himself more than usually unwell ; and in the evening, when his family, with their usual attentions, were preparing to read to him some work of amusement, he requested that they would rather read to him the evening service of the Church, and that they might once more have the happiness of being united in domestic devotion. When this was finished, he spoke to them with firmness, of the events for which they must now prepare themselves: He assu- red them that to him death had no sorrow but that of leaving them: He prayed that Heaven might reward them for the un- interrupted happiness which their conduct and their love had given to him; and he concluded, by giving to each of them his last and solemn blessing. After the discharge of this last paternal duty, he retired to rest, and slept with more than his usual tranquillity, and in the morning, (as the weather was fine,) he ordered his carriage, and desired that it might go out on the road towards Wood- houselee. He was able to go so far as to come within sight of his ——— = —. LORD WOODHOUSELEE. 561 his own grounds; and then raising himself in the carriage, his ‘eye was observed to kindle as he looked once more upon the hills, which he felt he was so soon to leave, “and which he “ had loved so well.” There was an influence in the scene which seemed to renew his strength, and he returned to town, and walked up the stair of his house with more vigour than he had shewn for some time; but the excitement was momen- tary, and he had: scarcely entered his study, before he sunk down. upon. the floor, without a sigh or a groan. Medical as- sistance was immediately procured, but it was soon found that all. assistance was vain; and Dr Grecory arrived in time only to close his eyes, and: thus. to give the final testimony, of a. friendship which, in the last words that he wrote for the press, Lord Woopuousetze had gratefully commemorated as heniog borne the test of nearly half a century... _ His remains were interred. im. the family butialsplace.i in), tlie Gucabiics Church-yard, beside those of his father and. mother, to whose memory it was then found, that his filial, piety had so exclusively dedicated it, that their epitaph occupied the whole of the tablet, and no room. was: left: for any fusctiptiag: to himself. > Jawa Vi > *4h ~ Thave very ill executed the melancholy task I have under- ‘taken, if it is now necessary for me to conclude this account: with any laboured delineation of the character of Lord Woop-: HOUSELEE. I am Speaking to some, in whose memories his vir- tues are written in better characters than those of words; and. “I am too conscious of the partiality of friendship, to trust my- self to any other ni pape igs than that ot his ‘own life: (rey ‘and 562 MEMOIR OF and conduct can supply. Upon his literary character, it will be the province of posterity to pronounce ; and to it I willing- ly leave to determine the rank he is to hold among the writers of his country. To us in these moments, when we are again, as it were, leaving his grave, there are other reflections that belong ; and there are recollections of no vulgar kind that arise, when we review the life of which we have seen the close. It was a life, in its first view, of usefulness and of honour. He was called to fill some of the most important offices which the constitution of human society affords,—as a father of a fa- mily,—a possessor of property,—a man of letters,—and a Judge in the Supreme Courts of his country; and he filled them all, not only with the dignity of a man of virtue, but with the grace of a man whose taste was founded upon high prin- ciples, and fashioned upon exalted models. It was a life, in its second view, of happiness as well as of honour: happy in all the social relations which time afforded him,—in the esteem of his country,—the affection of his friends,—the love and the ‘promises of his children: happy in a temper of mind which knew no ambition but that of duty, and aspired to no distinc- tion but that of doing good: happier than all in those early and elevated views of Religion, which threw their own radiance over all the scenes of man or of Nature through which he pas- sed, and which enabled him to enjoy every present hour with thankfulness, and to look ferward to every future one with hope. The records of this Society contain the histories of greater men,—of none, I believe, more virtuous, more amiable, or more happy: And while the lives of these illustrious men, ' (written =. LORD WOODHOUSELEE. 563 (written by men of kindred genius,) will, I trust, long continue to inspire in this place the spirit of philosophical ambition, I dare to hope, that even the faint outline which I have now gi- ven of the character of Lord Woopuovse.er, may tend to che- rish that moral ambition which all men are called to indulge ; without which learning is vain, and talents are dangerous, and to which rewards of a nobler kind are assigned, than either the praise of men or the splendors of literary fame. Vor. VIII. P. Il. 4B APPEN- er HET e q r q 5 Loh. est / ¢ 71 Fe ASTD Ml ts fiw ay \ ; t ti ry ' as | 4 oy vy rte treme etenn ven ptlreer eases. Set ey. 62 ~ git Ws & @ ‘ 7] ‘ o teIO=2? ‘ ie Py Tal j - > . = c ¢ . is . 4 , 4 : { , ' s ; ne t ' « ‘ ne 7 i f ’ 7 ‘ ° , ' \’ i. — o eo ( ; ( 565°) APPENDIX. Containing Lists of the Orricr-Brarrers and Mempers elected since November 1815. November 1815. OFFICE-BEAREBRS. Sir James Hatt, Baronet, President. Lord Mrapowzank, l ia Right Honourable Lord Gray, oe Professor Piayrarr, Secretary. James Bonar, Esq. Treasurer. Tuomas Attan, Esq. Keeper of the Museum and Library. PHYSICAL CLASS. Sir Grorce Macxenziz, Baronet, President. Tuomas Cuartes Hort, M. D. Secretary. Counsellors. James Bryce, Esq. del Davin Brewster, LL. D. 4B2 Sir 566 APPENDIX. Sir Witu1am Forzes, Baronet. Awprew Coventry, M. D. Professor Leste. Lord Wess Szymouvr. LITERARY CLASS. Henry Mackenziz, Esq. President. Tuomas Tuomson, Esq. Secretary. Counsellors, Reverend Dr Jamreson. “et, Watter Scort, Esq. Lord GLen ee. Dr Tuomas Brown. Witiiam Arzurunot, Esq. Lord Provost. James Pitians, Esq. 22d January 1816. MEMBERS ELECTED. Captain Tuomas Cory, Royal Engineers. Leonarp Horner, Esq. F. R. S. Lond. Henry Co.esrooke, Esq. Rev. Grorce Cook, D. D. Laurencekirk. Right Honourable Witiram Avam, Lord Chief Commis- sioner. Joun Fuiierton, Esq. Advocate. Tuomas APPENDIX. 567 Tuomas Jackson, LL.D. Professor of Natural Philosophy, St Andrew’s. Joun Rostson, Esq. Henry Dewar, M. D. Mr Hvuew Morray. Mr Roserr Witson, Accountant. November 1816. OFFICE-BEARERS. Sir James Hartz, Baronet, President. Lord GLEenLez, ae, Right Honourable Lord Gray, } a ast Professor Prayrair, Secretary. James Bonar, Esq. Treasurer. Tuomas Azan, Esq. Keeper of the Museum and Library. PHYSICAL CLASS. Sir Grorce Mackenzie, Baronet, President. Tuomas Cuarzes Horr, M. D. Secretary. Counsellors. Sir Wiru1am Forzss, Baronet. Anprew Coventry, M. D. Professor Lxsutr. Lord Wess Seymour. Colonel Imrie. Professor JamMEsoN. LITE- 568 APPENDIX.. LITERARY CLASS. Henry Mackenzie, Esq. President. Tuomas Txomson, Esq. Secretary. Counsellors. Dr Tuomas Brown. Witiiam Arsutunot, Esq. Lord Provost. James Pitians, Esq. Professor Dunrar. Reverend Dr Macxknient. Reverend ArcuiBaLp ALISON. 27th January 1817. MEMBERS ELECTED. The Honourable Baron Cuerx Rarrray. — Right Honourable the Earl of Wemyss and Marcz.. The Honourable Davin Douctas, Lord Reston. Francis Bucnanan, M. D. F. B.S. Lond. Joun Wirson, Esq. Advocate. Davw Hosack, M.D. F. R. S. New York. Right Honourable Avexanper Maconocuir, Lord Advo- cate. Joun Freminc, M. D. late of Calcutta. Davin Joun Hamittron Dickson, M. D. Clifton. Wiuiam P. Arson, M. D. James SKENE, Esq. of Rubislaw. Dr Howe. , Rey.. APPENDIX. 569 Rev. Rozert Moreneap. Roserr Batp, Esq. Civil Engineer. Tuomas Sivricut, Esq. of Meggetland. November 1817. OFFICE-BEARERS. Sir James Hatt, Baronet, President. Lord GLEenLer, Vice-Presid i t Je Right Honourable Lord Gray, i 7 eae Professor PLayrarr, Secretary. James Bonar, Esq. Treasurer. Tuomas Auian, Esq. Keeper of the Museum and Library. PHYSICAL CLASS. Sir Grorce Macxenziz, Baronet, President. Tuomas Cuarzzs Hore, M. D. Secretary. Counsellors. © Lord Wess. Seymour. Professor Lrstir. Colonel Imriz. Professor JamEson. Davin Brewster, LL. D. Mr James Jarprne. LITE-. 570 APPENDIX. LITERARY CLASS. Henry Mackenzix, Esq. President. Tuomas Tuomson, Esq. Secretary. Counsellors. James Pitians, Esq. Professor Dunzar. Reverend Dr Macxnieur. Reverend Arcurpatp ALIson. Lord Reston. Rey. Dr Jamigson, 26th January 1818. MEMBERS ELECTED. Tuomas Mackenzix, Esq. younger of Applecross. Wittiam Ricuaxrpson, M. D. Harrowgate. Honourable Captain Wituiam Napier, R. N. of Merchi- stoune. Harry Wittiam Carrer, M. B. Oxford. Parrick Miter, M. D. Exeter. Nartuanret Bownrtcu, Esq. Salem, Massachusetts. Joun Craic, Esq. Joun Warson, M. D. Captain Tuomas Brown. Joun Hors, Esq. Advocate. Major James Auston. Wiiu1am Fercuson, M. D. Inspector of Hospitals. Sir Witu1am Hamitton, Baronet, Advocate. END OF VOL. VIII.