JOURNAL AND PROCEEDINGS OF THE ROYAL SOCIETY OF NEW SOUTH WALES, 1898. oy ee EDITED BY THE HONORARY SECRETARIES. THE AUTHORS OF PAPERS ARE ALONE RESPONSIBLE FOR THE STATEMENTS. MADE AND THE OPINIONS EXPRESSED THEREIN. 1896. SYDNEY: PUBLISHED BY THE SOCIETY, 5 ELIZABETH STREET NORTH. LONDON : GEORGE ROBERTSON & Co., 17 Warwick Squarz, Paternoster Row, Lompon, E.C. NOTICE. Tue Royat Soctery of New South Wales originated in 1821 as the “Philosophical Society of Australasia”; after an interval of inactivity, it was resuscitated in 1850, under the name of the “ Australian Philosophical Society,” by which title it was known until 1856, when the name was changed to the “ Philosophical Society of New South Wales”; in 1866, by the sanction of Her Most Gracious Majesty the Queen, it assumed its present title, and was incorporated by Act of the Parliament of New South Wales in 1881. NOTICE TO AUTHORS. The Honorary Secretaries request that authors of papers (to be read before the Royal Society of New South Wales) requiring illustrations by photo-lithography, will, before preparing such drawings, make application to the Assistant Secretary for patterns of the standard sizes of diagrams &c. to suit the Society’s Journal. CORRIGENDA. Page 114, In value of R read + instead of — »» 116, In value of ¢ read 2 R,», in denominator », 182, Note 4, read Rodger for Rodgers. » 523, Footnote for page 532, read 530. PUBLICATIONS. oO Scceopars ny of the Philosophical Society, N.S. W., 1862-5, sae 374, out of print. L. Transactions of the Royal Society, N.S. W., 1867, pp. 83, ei 1 ; 33 ” ” > pg ’ a 3 iil ” ” 29 ” 2” 1869, 7) 173, ” ” ty. ” ” ” ” ” 1870, ” 106, ” ” ™, ” ” 2? ” ” 1871, ” 72, ” ” vi ” » ” ” ” 1872, ” 128, ” > Vil ” ”? ” ” ey 1873, ” 182, ” ” vill 2” ” ” ” ” 1874, ” 116, ” oe) ” 1875, ” ’ ’ iy X. Journal and Proceedings s a 1876, ,, 333, 5 ” ” ” ” ” ” ” 3 ” XIl 7 ” ” ” > 1878, 3° 324 price 10s 6d. 3? XIII 99 ” ” ” 3° 1879, LP) 255, 3? »” XIV. 2” ” 2 ” ” 1880, ” 391, 29 10s. 6d. ” XV. ” ” > ” ” 1881, ” 440, ” 10s. 6d ” XVI ” 2” ” ” ” 1882, ” 327, ” 10s. 6d 2” XVII 2 ” ” bby ” 1883, 2? 324, ” 10s. 6d. ” XVIII ” ” ” ” ” 1884, ” 224, ” Os. 6d. ” XIX 0 ” ” ” ” 1885, ” 240, ” 10s. 6d. ” XX ” 29 ” ” ” 1886, ” 396, ” 10s. 6d. ” xXXI ” ” ” ” ” 1887, > 296, ” 10s. 6d. ” XXII ” ” ” ” ” 1888, ” ” 10s. 6d. ” XXIII ” ” ” ” ” 1889, ” 534, ” 10s. 6d. ” XXIV ” ” ” ” ” 1890, ” 290, ” 10s 6d. ” XXV ” ” ” ” ” 1891, ” 348, ” 10s. 6d. ” XXVI. ” ” ” ” ” 1892, ’ ” 10s 6d. ” XXVII 7 ” ” ” ” 1893, ” 530, ” Os. 6d. »XX VII 2? ” ” ” ” 1894, ” 368, ” 10s. 6d. CONTENTS. VOLUME XXIX. Orricers FoR 1895-96 ... ee sa cis aad cis pee List oF print &e. ART. I.—PRESIDENT’S is DRESS. os B. Threlfall, » M.A., Professor of Physics in the University of Sy dney . IL—A —— to the oe of Aisstondiien Mie Pears Kinos. By J. H. Maiden, F.1.s., and H. G. Smith —Paper on » Aeronantiel Work. sid Lawrerioe nr a ‘Nine Plate gt IV.—Not S hee. Mi vara Substances toon the Aceteuas Broken Hill Consols Mine. By E. F. Pittman, A.R.8.M., Government Geologist, Sydney... . V.—The Cuibhe Parabola as applied to the Wasa of Circular Curves on Railway Lines. By C.J. Me ld. (Communi- eated by Mr. G. H. Knibbs). 1 Oni Plat : .VI.—The History, Theory, and jes of ‘the Vis- e ae | . VII.—On the Physiological A of the Venom of the ns ek Black Sn — rae porphyrinen ws). me C. J. Martin, B.Sc., M.B. en Considerations 9 on ur Baveiving ‘Cahigees in see s of Ancient Antarc nae Some By C. patent gh ceccbenks in Zoology to the tralian Museum go eg in oo Sonthern a By H. C. ‘Russell, M.G., F.B [One Plate] . 4 ame ” ome hb joa cy haps ie Minecats, Note No. 7. A. Liversidge, M.A., F 7, Profiesat of a in the Guivéenity ‘of Sydney ... . XI.—On a Natural Deposit of Aisa Succinate in the Timber of Grevillea robusta, R. Br. bes AH. oe F.L.S., and Henry ith ae on ok Amount of Gola poe ahve in Sea-Wate Liv M.A., Professor of Chemistry, Duiveieny Of peaney, N. sv ales UII.—The removal of rope and Gold pene Nei wrabe be Muntz Metal Sheathi A. Liversidge, M.A., F.R.S., Professor of Chemistry, S niveraity of Sydney, N.S. "Wales . XIV. agen — and sec chars from Samoa. staf John XV. ust hie “ae No. 1. “bd ve a ‘laden, » ¥.L.805 _ _— G. Smith ... o* Arr. XVI yes age smeetaha niet Notes, No. 1. By Rev. J. Milne Cur Art. XVII.—On — occurrence ‘of Kikai Brabuct in oaks iar By than Cretaceous Edward F. Pittman, a.R.s.m., Govern- i ist ogist ... Art. XVIII.—Note on the Grint of Malach ite—Observations made in an abandoned Coppe sabaust By sian ca Hall. (Com municated by Professor Liversidge Arr. XIX.—A comparison of the Languages of Pennie sae Hawaii.:'By the late: Rev. E. T. Doane; with additional notes and illustrations fe Sidney i. as Memb. Anthrop. Inst. London Art. XX.—The Tensile ‘aa [Compressive Stechoth: of Magnesium. By 8. H. Barraclough, Art. XXI.—Note on some i santa pat thes Fruit of 3 Piltosporum ee and from the leaves of the Pepper Tree ( Schinus We). By R. Threlfall, M.A., Professor of Phyeles in the Univernts of Sydney Art. XXII.—Notes on a ae Rocks acta, by Mr. we By T. W. E. or of Geology; W. F. Smeeth, m.a., Page A.RB.S,M., Lecturer in ese dae and Demonstrator” in Geology; and J. A. Schofield, peels in Chemistry, eee, of Spies Three “Plates es | ArT. XXIII.—Notes on the Rainfall of the Soatheen : Riverina, ie to 1894. By Hugh Charles Kiddle, F.R. Met Art. XXIV. ere a ee Meteor of wed 7th, 1895. “By H. C. Russell, 8 ART. oui oo Climate of Lord Hiawe too By H, ©. Tasieil: ART. et. cds ty ‘hisralinn Weathe er. = Heirs A. Hun Second Meteorological Assistant, sila Olhervatory [Forty Diagrams. | Arr, XX VII.—Timber Bridge Construction in ese Souths Wales. Allan, A. M. Ins By Percy Art. XX VIII.—Fas ak as curio oe ‘Gy ae Public Works Department of "New South Wal By T. E. adits L.S. chats: d by J. W. cinta: M.1.C,E.) ue PROCEEDINGS PROCEEDINGS OF THE itiusiiies guorit . PROCEEDINGS OF THE MepicaL SEcTION ADDITIONS TO THE LIBRARY ... per ac ae abs DEX TO VOLUME X XIX. ts ee EXCHANGES AND Publi MADE BY THE ‘Rovar Socrety or New SoutH Wags, 1895. Pace. 453 456 Rovul Society of New South elales. ——— | OFFICHRS FOR 1895-96. Honorary President: HIS EXCELLENCY THE RIGHT HON. HENRY ROBERT VISCOUNT HAMPDEN. President: Pror. T. W. E. DAVID, B.A., F.G.8. ee F. B. KYNGDON. ROF. ANDERSON STUART, m.p- CHARLES MOORE, F.1.5., F.Z.8. Pror. THRELFALL, m.a. . Treasurer: Ay GAs sane M.R.C.S. Eng., L.8.a. Lond. Hon. Secretaries: J. H. MAIDEN, F.u.s., &e. | 4. WwW, GRIMSHAW, M. Inst. C.E. embers of Council: H. A. LENEHAN, F.&.a.s. W. CHISHOLM, m.p. Pror. LIVERSIDGE, M.a., F.R.8. Cc. W. DARLEY, M. Inst. C.E. HENRY DEANE, u.a.,M. Inst. CE.| E. F. PITTMAN, Assoc. 8.8.M. | | H. C. RUSSELL, B.a.,0.M.G., F.E.8. | ALFRED SHEWEN, m.D. W. M. HAMLET, F.c.s., F.1.c. G. H. KNIBBS. Assistant Secretary: W.H. WEBB. NOTICE. Members are particularly requested to communicate any change of address to the Hon. Secretaries, for which purpose this slip is inserted. Correct Address. Name Titles, &c Address Date To the Hon. Secretaries, The Royal Society of N.S.W., 5 Elizabeth-street, Sydney. LIST OF THE MEMBERS OF THE Hopal Society of Ae South Wales. . P Members who have contributed pavers which have been published in the Society’s Far pra ns or Journal; papers published in the Transactions of the Philosophical weg are ro so pera to The numerals indicate the number of such contributions. t Life Mem Elected, 1877 | | Abbott, The Hon. Sir Joseph Palmer, Knut. m.u.a., Speaker of the at eared Assembly, Castlereagh-street. 1877 | P4 pio W. E., ‘ Abbotsford,’ Wingen. 1864 Adams, P. F., ‘Casula,’ — rpoo 1895 Adams, J. H. M., heap m Club, Castlereagh-street. 1878 Ale ny Geor » Grosvenor Hotel, Church Hill. 1890 | Pl Allan, P, ercy, ice = te ape Roads and Bridges Branch, ai | orks Departm Sydne 1885 | Allworth, "Joseph Witter, gore! Barvapee. East Maitland. 1881 | s, Robert, ‘ Kin -_ geo 1877 | haterons a 61 Macquarie-street. 1890 : Anderson, William | | 1878 gee shorn oe P., u.a., District Court Judge, ‘ Melita,’ | zabe reg ie 1877 'B 1894 Reker Hhara = F.L.s., Assistant Curator, Techno- lo 1814. | {Ralslle, George Sandymount, Dunedin, New Zealand. 1895 | r Some roft, T. L ., Deception Bay, vid Burpengary, Brisbane, Ginsensin nd. 1895 | Pd} Barraclough, 7 , Lecturer on Applied Physics, Technical College, Pa 16 Poxte th Road, Glebe Point. 1876 Bassett, W. F., Eng., George-street, Bathurst. 1894 | =e xter, William Caen, Chief Sur rveyor Existing Lines Office. | Railway Department, p.r.‘ Hawerby,’ Carrington Avenue, Strathfie 1888 | ‘Bedford Alfred Perceval, Manager Permanent Trustee Co. 16 O’Connell-stree 1877 | Belfield, "Algernon He; ‘ Eversleigh,’ Dumaresq. i | Belisario, John, M p., Lyons’, Terrac page Park. 1876 ' Benbow, Cle eae A 263 Elizabe re eet. 1869 | P 2! aes 8. L., op 0" Gouceliatwant, "Box 411 G.P.O. 1895 _Bensusan, A. J., A.R.8.M., F.c.s., Laboratory, 12 O’Connell-st. Berney, pening 74 Alberto Terrace, =, Dating h Road. 1889 | | oa George Augustus, 74 Alberto Terrace, v Daclinghurat { Road. Pot err Herbert, m.x.c.s. Eng., u.R.c.P. Lond., Hospital for e Insane, Callan Park, Balmain Pe Resayy Meee. F.R.C.8. Eng., Leon. ] Lond., Broken Hill. “om —- Charles E., B.c elb., Water _ Conservation nch, Public Works De pate anend Hillst tBond, aback, 131 Bell’s Chambers, Pitt-stre relgeeti oat James W., Superintendent of Pala Waterin Plac —_ cas Dorie, Dapackiins of Mines ind rinesrsd ciate a Archer - c.z., The Boulevarde, Strathfield. Bowman, John Sowa, Reginald, M.B. et Ch. M. Edin., Parramatta. Brady, Andrew John, Lie. K. - oT Phys. [rel., Lic. R. Coll. Sur. Trel., 3 Lyo enr market Branch, City. {Brooks, Sas F.R.G.S., F-R.A.8., ‘ Hope Bank,’ Nelson-st., Woolla ra, Brown, David, ‘ Kallara,’ Bourke. Brown, Henry Jo Joseph, Solicitor. Newcastle. parang Anthony a olling, M.B.,Ch. B. Melb., 285 Elizabeth- Par Bruce, Soho Leck, Teaknical College, Sydney. Bundock, W. C., ‘ Wyangarie, Casino. Bu oe py ra Ormsby, M. Inst.C.E., Engineer-in-Charge of Railway Surveys, Fitz Johns, Alfred:st N.. No abies ee Burne, "De a ate ntist, 1 Lyo s’ Terrace, Liverpool-st Bush, Thom Engineer’s 3 Office, Australian Gas- Light rte 163 Kent-street. Cadell, Alfred, Dalmor Cameron, Alex lagen Walgett, N. S. Wales. Campbell, George S. Campbell, John Honeyford, vm Mint, se baa 5 Campbell, Rev. Joseph F.G.8 . St. Nicola’s C w Campbell, W. Duga ald, Assoc. M, Inst.C.E,, Assoc, King’s Coll. Lond. F.q.s., 46 Leinster-street, Pad ington. Cape, Alfred us ., M.A. Syd., ‘ Karoola,’ Edgecliff Road. Carleton, Henry R., gree * Alameda,’ ackak. Bondi. eT David, F.1L.A. Gt. Brit. & Ir vel. » PF. - — Australian tual Pro vident Society, 87 Pitt stre Chambers Thomas, F.R.C.P., F.R.C.8. Edin., i Lyons! Terrace, © Hyde Par Pt tChard, 5. 8, Licensed pe ding — E le. Chisholm, Edwin, A. Lond., Chisholm, William, i as ei 3 Mac ecoarie athe Work. larke, Gaius, c.E., Boro car Baceoe, Town Hall, Rockdale. a = P. B., u.x.c.p. Lond., M.R.c.s. Eng., 195 Macquarie- Codrington, John Frederick, m.z.c.s. Eng., u.R.c.P. Lond. L.B.c.P. Edin., Orange. 8 bg! P4 Sagat P8 Cohen, Algernon A., m.s., M.p. Aberd., M.R.C.8. Eng., 71a Darlinghurst Road. Collingwood, David, m.p. Lond., ¥F.R.c.8. Eng., * Airedale,’ Hill. conueee te eorge, Crown Solicitor, *Rossdhu,’ Belmore Road, Harstville. Colyer, J. U. C., Australian Gas-Light Co., 163 Kent-street. Comrie, Pee ‘Northfield, Kurrajong Heights, vid Rich- on Cor bes Samuel, Australian Brewery, Bourke-st., Redfern. Cottee, W. Alfred, 2 a Coutie, W. H., M.B., Ch. I v. Melb., ‘ Warminster,’ Canter- bury Ro Road, Peter shine Cowdery, George R., Engineer for Tramways, p.r. William- street, Burwood. . Cox, James, m.p. Edin F.L.S., 39 Hunter-street. Cox, The Hon. a 5 ssc i. L.c., Mudgee Cr: — a ae ge M.R.C.S. Eng., L.R.C.P. Lond., 34 ‘College-street, Oxsodt The Hon . J. Mildred, M:L.C., M.B.C.8. ase Edin., ‘ Ravenscraig,’ bil neh gpa Woollahra reiehoseg Thomas ton urran, Rev. J. ‘Milne Lec eology, Technical College, Ryaaeg p.©: BBT en ae City. sree Fred. H., c/o Messrs. Dangar, Gedye, & Co., Mer- antile gone Cheagt pe eel sis street. Dare, Henry H M.E., Assoc. M. I E., Roads and Bridges Branch, Public Wicks Dapertoss Darley, Cecil ~~ Fm Inst. C.E., Sis -Chief, Public Works Departm Darley, hing Hon. ay Frederick, Knt., B.A., Chief Justice, Supreme Cou David, T. Ww. Edge rth, B.A., F.G.8., Professor of Geology wot box tga “ncography ‘Sydney University, Glebe. eis. omen M. Inst. C.E., pe antag ha Engineer, Sewerage Branch, Department of Public Works. Dean, Alexander, 3.P., 54 Castle sna star Box 409 G.P.O. Deane, Henry, MAM. Inst. CE., Engineer-in-Chief for Railways, Railwa Construction Branch, fhm ‘Works Department p.r. ‘ Blanerne,’ ie alena Road, Hill. Ded, Joke serosa p. Univ. St. And., mene Lond., M.R.C.8. Eng De Salis, The Hon. Leopold Fane, M.L.c., ‘Tharwa, Quean- n. Dick, Ji ames Adam, ™.D., ¢.m. Edin., ‘ Catfoss,’ Belmore-road, wick. P 12 Dixon, w_ A.,F F...c., Fellow and Member eee of Chemistry 0 of G reat Britain and Ireland, Chemistry, The Technical College Laboratory, mace hi xii. Elected 1880 Dixson, Thomas, M.B. eae Mast. Surg. Edin., 287 Eliza- | ‘pat dtacst, Hyde P 1879 | Docker, Wilfred L., ‘ Pri bla,’ Darlinghurst Road. 1876 | Docker, Ernest a M.a. Syd., District Court Judge, ‘ Car- hullen,’ Granville 1873 Du Faur, E., r.z , Exchange Buildings, Pitt-street. 1891 |P 1) Dunstan, iced ae F.a.8., Techni y “i ese, Sydney. 1892 Dymond, Edmund R., Assoc. M. Inst. C.E., t. Elect, Eng. of Gt- Brit., King’s College, Parramatta. 1890 Eddy, E. M. G., Assoc, Inst. C.E., A ce Commissioner of Rail- ways, ‘Colebrook,’ Double 1894. | oa ee Gordon Reade ’ Bridges, and Sewerage h, Public Works Department. 1874 | Biohler, ” Chacien F., m.p. Heidelberg, m. B.C.S. Eng., 56 Bridge- 1876 | Eldred, W. H., Consul General for Chili, ‘Flinton,’ 186 | Glebe Road. 1879 |P3 Head es Robert j ee Curator, Australian Museum 1876 orge, ‘ Glen Ayre,’ Glenmore Road, Paddin ngton. 1881 a ans, Tho mas, M.R.¢.8. En ng. ., 211 Macquarie-street, North. 1892 Everett, W. Frank, Roads and Bridges Oftice, Muswellbrook. 1877 ‘{Fairfax, Edward Ross, 8. Ds ya Office, Hunter-street. 1868 "Fa airfax, James R., S.M. Herald Office, Hunter-street. * 1887 | ham ar £39 L., m.p. New Yok ig "Phys. & Surg.) L.R.C.P., Lond., 5 Lyons’ Terra 1889 Farr mage shua J. ns. Be, te nie Evan, Addison Rd., Marrickville. 1881 Fiaschi, Thos., m.D., M.Ch. Univ. Pisa, 39 Phi li ip- sreterie 1891 Firth, Thomas Rhodes, Principal feces t Engineer, Rail- way £ggcagantag Department, Sydney; p.r. ‘ « @lenevin,’ rncliffe. 1891 Fitzgerald, Robert D., Roads and Bridges Branch, Department of Public. Works, Sydney 1888 Fitshardinge, Grantly Hyde, m.a. Syd. District Court Judge, ‘Nunda,’ Birchgrove, Balmain. 1894 Fitz Nea, A. = Roads and Bridges Branch, Public Works Department, p.r. ‘Thaluya,’ ve go N. woth 1892 Flint, and "Alfred, M. es King’s School, Parrama’ 1879 \fForeman, Joseph, M.R.¢c.s, Eng., L.R.C.P. Edin., 315. "Mac- Bat quarie-street. Foster, The Hon. Mr. Justice (W. J.) 9.c., Enmore Road, ewtown. 1883 | P5| Fraser, John, 3.a Edin., Délégué ep aaa Bee" ’Océanie), Al Reais Seiontifig ue de Paris ; te of tbe. viene (Philosophical) “institute of hecat B Britains Elected 1890 1881 | ww xii. sag rs Francis B., m.a. Syd., Solicitor, ‘Carmena,’ Wya- -street, Burw Forbes oT. Bs Surveyor General’s Office, 218 Victoria-street. Gale, ridge ge F.R.A — & BAA, Savings’ Bank of N. 8. Wales, Barracks Garran, ged ob M.A., LL.D. Syd, noinigr sien Square, Eliza- beth Bay bigs Garrett, Henry Edward, m.x. * s. Eng., c/o Messrs. Sly and Russell, Solicitors, Pigs. va eet. Garva 1 Ca slereagh stre Gedye, Charles perro) cjo M = Dangar, a & Co., Mer pr le Bank Chambers, Mavealet-a George, W. R., 318 George-street. Gerard, Francis, c/o Messrs. Du Faur & Gerard, Box 690 Gill, ‘Rev. William Wyatt, B.a. Lond., Lup. St. Andrews, ‘ Persica,’ Illawarra Road,. Marek: lle. Gill. Robert J., Resident eager, Rinks and Bridges, layne Gilliat, Henry A., Australian Club, Sydney. Gipps, F. B., c.z., ‘ughenden,’ Cheltenham Road, Bur M. N So ey ; Mew. Brit. Med. Assoc.; Lecturer on Medical Ju apruiaies, University a Sydney, 159 Maequarie-st. Goodlet, John H., terbury House,’ Ashfield. Gordon, Charles ray + Ber latie? East Crescent-street, North Sydne. ¥ Graham, spi ‘ei M.B., C.M. Edin., M.L.A., 4 Hyde Park Ter a Livee ae et. Griffiths, G. Neville, 869 George-street. Grimshaw, cape Walter, M. Inst.C.E., M.I. Mech. E., &c., Australian Club, Sydney. Hon. Secretary. Gundlach, pois Richard, a.m.1.c.z., Whistler-street, Manly. Gurney, T. T., ma. Cantab., Profes sor of Mathematics, Sydne y University, 149 0 Micequarie-tree Guthvie, ps eat kb. F , Department of Agriculture, Sydney. Halligan, Gerald H., c.£., ‘ Riversleigh,’ Hunter’s Hill. Halloran, Henry Ferdinand, t.s., 28 Castle srage hgirm ee Hamlet, William M., F.C.8., F.1.C., — ber of the Society of Public Analysts; Government Analyst, Governmen ernment aboratory, Kesainily Buildings. : Hankins, George Thomas, m.k.c.8. Eng., ‘ St. Ronans,’ Allison Road, Ran as Elected _ 1891 | | Hanly, Charles, t.s., Resident Engineer, Roads and Bridges Office, Crookw ell. 1890 | Harris, Rev. Edward, m.a. Oxon. and Syd., D.pD. Oxon. 1881 | \tHarris, John, ‘ oh Sogo any -street, Ultim 1877 P13tHargrave, Lawrence, J.p., Sta ~~ pony Otfora, 1884, = elt, — Abhi, 404, DS Professor of and Comparative Anatomy, "Univelaity. Sydney. 1890 | | Hagaone ‘timo — Cc, ueen’s Univ. Irel., Assoc. M. Inst. | ‘ Fontenoy,’ gree street, Woollahra 1876 | | Heaton, J. ¥ Henniker, u.P., St. Stephen’s Club, Westminster, 1891 aa 1| eige Charles, F.L.S., Assistant in Zoology, Australian useum, Sydne oy 1893 | ‘Hendenon, sche. 1890 | ‘Henry, Arthur p Ber M.B., Ch. M. > Resident Medical | | Owce r, Callan Park Asylum alm. 1884 | Henson, Joshua B., c.z., Hu nter District Water Supply and Sewerage Bo ard, Neweas e. 1891 | | har a Robert, M. Inst, C.E., Under Secretary, Public Works | bane; por. The e Pines,’ Bondi. 1876 pe 2) Hirst, Otetks e D., 377 George-street 1891 | | Hood, Alexander J arvie, M.B., Mast, peng: Glas., 2i9 Macquarie- | | street, City. 1892 | Hodgson, Charles George, 157 Macquarie-street. 1886 (Holme es, she r Harrison, ‘The Wilderness, Allandale. 1891 Houghton, Thos. . Harry, A.M.I.C.E., M.I.M.E., 12 Spring-street. 1879 | Houison, Andre “ne A MB, M. Edin., 47 Phillip-street. 1891 |P 1) peers “William F. lust. CE, ™ I. Mech, E., Wh. Se, Mutua: 1 Life uildinge, : vacates 1877 Hume, J. K., ‘ Beulah,’ Cam pbel llto 1894 |P2 Hunt, "Hen ory fg Second cticellosivel Assistant, Sydney Observatory. 1882 Hurst, George, m.a. Syd., m.B. Univ. Lond., u.B., o.m. Univ. Edin., Bathurst. 1886 Hutchinson, W. A., Bond-street, p.r. oo Glebe Point. 1891 Hutchinson, William, M. Inst. (.E., Supervising Engineer, Rail- bie: Construction Branch, Bnblis Works Department. — 1895 Jacob, Albert Francis, a.m.1.c.z., 8 The Terrace, Shepherd’s Hill, Newcastle. 1891 Jamieson, Sydney, B.A., M.B., M.R.C.S., L.B.C.P., 157 Liverpool- street, Hyde Park. 1884 Jenkins, Edward Johnstone D. Oxon., M.R.C.P., M.R.C.8. L.8.a. Lond., 213 Macauscie-treek, North. 1879 Johnson, James W., Norwich Ch eed poems 1887 Jones, George Mander, m.R.c.s. Eng., i Pp. Lond., * Viwa,” Burlington Road, Homebush 1874 Jones, James, ‘ Miltonia,’? Randwick. ¢ 1879 Jones, John Trevor, c.z., ‘Tremayne,’ North Shor 1884 Jones, Llewellyn Charles Russell, m.u.a., Solicitor, 130 Pitt-st. Elected 1867 1876 1891 1875 1874 1883 1872 P3 P2 rs P 45 XV. Jones, P. Sydney, u.v. Lond., 8. Eng., 16 College-street, Hyde Park, p.r. ‘Llandilo,’ "Boulevard Strathfield. Jones, Richard Theophilus, m.p. Syd., u.R.c.P. Hdin., ‘ Caer Idris,’ Ashfield. Jones, RibetE, M. Inst.C.E., Roads Department, Muswellbrook —— Js Percy, Assoc. M. Inst, C.E., ‘ Moppity,’ George-st., J Poe "N uma, Hunter’ s Hill. Kater, The Hon. H. E., m.t.c. sige Seam Los vation Bay Rd. Keele, ae William, M, —_ C.E., Dis Engineer, Har- bours and ives s Department, Ballina, "Ric hmond River Keep, Hog Bronghton Hall, tas hhardt. Kendall, Theodore M., — lbs L.R.C.8. Lond., u.M., 28 ollege-street, ee oe alter MacD 2% enc, L.B.C.8. Hdin., L.F.P.8. , 265 Eli ma Re Souk Hoces Oi ed ig s Chambers, aty Pitt-street. Kiddle, Hugh "Cha . Public School, Seven Oaks, ehh sane ite River. ae Christopher Watkins LC 8., Roads and Bridges Public Works gr aay e* dne King, re a Philip G., M.u.c., ‘ fextek William-street, Double Kirkaldie, Davia, Chief Traffic Manager, New South Wales overnment eg Sydney. Knaggs, Samuel T., Aberdeen, ¥.8.0.8. Irel., 16 College- street, Hyde Pa Peg Knibbs, G. H., r.n.a.s., L.s., Lecturer in Surveying, University Sydney, p.r. ‘Avoca ‘House,’ Denison Road, Petersham. d W i f Knox, The Hon. Edward, m.t.c., O ‘Sree or Kopsch, G., re Boulevard, Petersha Kyngdon n, F. B., ¥.B Lond., Deanery as Bowral. Vice-President. Lenehan, ar ed Alfred, F.R.A.8., ee, aor aitoari Lingen, J. T., M.A. Cantab., 167 Phillip-s Archibald, - . ee +f Sa Min aie . Roy. Sch, s Lond.; F.E.G.S. ; Fel. Inst. Chemiaiey of Gt. Brit. ple, Soak: Han Fel. Roy. Historical Soc. Lond.; Mem. Phy. Soc. Loni: Mineralogical Society, Lond. ; Edin. Geol. Soc.; Mineralogical Society, France; Cor. Mem. Edin ; Roy. as.; Roy. 3 Sen berg Institute, Frankfurt ; . @ Acclimat. Mauritius; Hon. Mem. - Vict.; stitute ; K. Leop. Carol. Acad. Halle a/s; Professor of Chemistry Cc in the University of Sydney, The University, Glebe ; p.r. ‘The Octagon,’ St. Mark’s Road, Darling Point. Xvi. | Lloyd, Lancelot T., ‘ Eurotah,’ William-street East. | Lloyd, 'The 4 George Alfred, M.u.c , F.R.G.8., ‘ Scottforth,’ Elizabe h Bay P 2} Loir, Adri Long, Alfred Parry, Land Titles’ a bamentcorh ee Low, Hamilton, H. M. Customs, Sydne MacAllister, eden ta M.B., B.S. Melb., ‘ Ewhurst,’ Stanmore R MacCarthy, Shicdaa W., M.D., F.R.¢.s. Ivel., 223 Elizabeth- t, Hyde ark. McCormick: Alexander, M.D., c.m. Edin., M.R.c.s. Eng., 125 Macquarie-street Nort a | MaoCullock,: Stanhope H., c.M. Edin., 24 College-street. | M‘Cutcheon, John Whence, ‘Saeneee to the Sydney Branch | of the Royal a nae eD sag crs hn M., M.D, M.R.C.P. Lond., F.R.c.8. Irel., | 173 acdaniatnect No rth. | MacDonald, Ebenezer, ‘ Kamilaroi,’ —' Point. MacDonald, John A., M. Inst. C.E., M. Ins , M. Am, Soe MacDonnell, William J., eae ojo M Vis Ok Goddard, N ey amber MacDonnell, Samuel, Cape’s and na 3 Bond-street. MecDo ‘oa Herbert Cx ae M &.C.8. Eng., b.B.c.P. Lond, Hospital for 8 eines ag McKay, Charles Univ. St. Andrews, t..R.c.s. Edin., y McKay, Robert Thomas, McKay William J. Siawaek: BSe., M.B. Ch.M., ‘Glengower,’ Fae street, Petersham Mackellar, The Hon. Charles innard, M.L C., M.B., C.M. Glas., 183 Liverpoo “nla Hyde P Mackenzie, John, r Cp tails Club, 8 Sydne Mackenzie, Rev. P. r. "The Manse, Fohnston-st, Annandale. M‘Kinney, Hugh Giffin, m.z. Roy. Uni M, CE. Chief tee re for Water prom cots vol A itiaaa Club? Castlereayh-street. ss "The | ee Henry Norman, , M.A., M,D. Edin., s. Edin D. Univ. St. Andr 3° 155 M acquarie-st. McMillan, William, » MLA; f St. Albans,’ ‘Allison-st, Randwick. adsen, Hans. F., ‘Hesselmed House,’ Queen-st., Newtown. Maiden, moar H. 1» PES, 20.8 ne orr. Memb. Pharm. Soe. Great ot and of Roy. Soe. .,8.A.; Hon. Memb. Phila. Coll. of Pharm. and Royal Netherlands Soc., (Haarlem); Superintendent of Technical Education, Sydney. Hon. Seer gi ae Maitland, Duncan Mearns, a ee of Lands, Ss ;dney. oe G. E.. haar Square, Be rrima. nfred, Edmund C » Montague-street, Goulburn. pests John F., ‘ Ferepanu, ” Neutral Bay. ae Frederic Norto m.D. Univ. St. And., M.R.c.8. Eng.) _ A. Lond., Hunter’s Hin. P3 P3 x7 Et XVii, — G. —— Martin Chambers, Moore-stre o, G. V., m-p. Univ. Naples, Clarendon Pee Eliza- of P logy. “Sydne y University, * ¥, 986 Macquavi-st iieoncas "Robert t Chr., She a by Ma — . ‘ ae LB sii Fi by i” Meggin mu. Edin., 147 P ailaabeits atre et. Millard, Reginald Jeffery, oa ch. M, Syd., Hospital for Insane Callan Park, Balmai Miles, oe E., 1.8.0. : “ Lond., M.R.c.S. Eng., Hospital for s astle — ss u.D. Heid elbe ergs 3 k.c.s. Eng., 3 Clarendon Ter- e, 295 Blizabeth- stree Milson, Jam et ‘Elamang,’ North Shore. mis 23 Jo .H., F.c.s., M.AI.M-E., oo and Analyst o the Department of Mines, Sydne Mollison, James Smith, m.t1.c.z., Roads, kaon 5 Sewerage Branch, Department of Public Works, Sydne Moore, prsnetes ye Fe Be irector of the Saas Gardens, ydney. Mie Presiden Moore, Frederick H.., ilawarea pe Co., Gresham-street. Moir, James, 38 ae Money, Angel, M.D., F.R.C.P. 340 Hunter-street. Morris, William he Pg tee and Surg. Glas., F.R.M.S8. ond., 5 Bligh-str Moss, eens a fee Kalool, ; besos et Seetag Shore. nilba {Mullens, Josiah, F.R. Mullins, John Francis Sue M.A. Syd., * : Killoonten,’ Challis Avenue, Pott’s Poin Mullins, George Lane, Mm... p. Trin. Coll. Dub., u.v. Syd., F.B.M.s. Lond., ‘Murong,’ ‘Aibion-street, Waverley. Munro, William John, m.B., . Edin., M.B.C.8. Kak Bea 8 Glebe Road, Glebe. Myles, Charles Henry, ‘ Dingadee,’ Burwood. Nangle, James, Architect, t, Australia-street, Newtown Neill, Leopold Edward Flood, M.B.,Ch.M. Univ. Syd., No. 3 Bay mater Houses, Double Nicholls, "William Hawkins, Roads ; Ole. Muswellbrook. : N — — George, 60 Louisa Road, Longnose Point, Norton, Th The Hon. ‘aioe, M.L.C., LL.D., Solicitor, 2 O’Connell- street, p.r. ‘ Beclesbourne Double y: Noyes, Edwar rd, ¢.E., ‘Waima,’ Wentworth Road, Point Piper, Sydney. Ogilvy, James L., cert Hote Melbourn O’Neill, G. tant. & ., CM , 291 Rlizabeth-strest. Oram, Arthur Mu cine M.D. nv, Edin., 213 Macquarie-st., North. 1876 P 4 P4/P 1 ahi * P3 XVlii. O’Reilly, W. W. J., M.D. M.ch.Q. Univ. Irel., m.nz.c.s. Eng., 197 oe t, Osborne, Ben. M., ‘ Hopewood,’ Bowral. Osborn thes F., Assoc, ie Inst.C.E. Roads and Bridges Office, Cowr Owen, inne Percy Thomas, Assistant Engineer, Military Works, Australian Club. Palmer, J. H., ‘ Hinton,’ aa te Burwood. Palmer, Joseph, 133 Pitt-st., p.r. Kenneth-st., Willoughby. Park, Archibald John, Own Local Land Board, rece hepkabewengaee enry W., pened eee Brisban Paters erokty ander, din., 146 Gryntal-atseeks Pe eae Paterson, Hugh , 197 Liverpool-street, Hyde Park. Pedley, Berooval, R., 227 Macquarie-stree Perkins, Henry A ‘ ore Saag Cov ventry Road, Homebush. Philip, Alex., L.K.Q.C P. Irel., u.R.0.8. Irel., 574 Crown-street, Surry Hills. Piskbarn, Thomas, M.D., c.m. Aberdeen, m.p.c.s. Eng., 22 College-street. a ai ei Geologist Department 3 peice eps Frederick, District Surveyor, Toiawe rth. Pockley, Francis Antill, m.s., u.c. Univ. Edin., m.x.c.s. Eng., "Mac acqu ac ge? eet. Pockley, Thomas F. G., Commercial apie a on Pollock, James ee thur, B.e. Roy. Uni BSc. Syd., Demonstrator in Playas, Sydney Uni ie burs William dr., ter soe at Sach, Depart- ent of Public Woke Bou — Pringle, Adam Thompson, Government Inspector of Vine- yards, ‘ Albma Villa,’ Barramatta Road, Concord. Purser, Cecil, B.a., M.B., ¢ Valdemar,’ Boulevard, Petersham Quaife, Frederick H Mas ‘ Hughenden,’ is p cons evi Wooll ERTS Edward P., uu.p. Univ. St. And. beter F.R.S.E+> » c/o Australian Museum, College-s eae i: Mem. Odon ogee ” Hileaheth- peel Hyde Park, p-r. Fullerton- aout ees llahra Ng.» L.B.G.P. Lond., L.D.8. g. a Rennie, Edward Syd., D.Se. Lond., Professor of Chemistry, Duvokey Adelaide. ter of ipa ane Glas, . ahra s P4 rik P 57 P3 Rennie, George E., a mu.D. Lond., u.R.0.8. Eng., 16 College-street, ityde e Par marks he Hon. Sir ferion M.L.C., B.A. Syd., M.D. F.R.C.8. ., 295 scape! Roberts, ‘Sir Alfr ed, M ,» Hon. Mem. Zool. and Bot. oc. Viennr, 125 Macquarie-sérect North. pee W. S. de Lisle, c.z., Sewerage Branch, Public Works Department, Phillip-street. Rolleston, are C., c.g., Harbours and Rivers Branch, Dept. of Public Works. Rossbach, William, Assoc, M. Inst. C.E., Chief avian ese bours and Rivers Branch, Public Bie ks Depar Ross, Chisholm, m p. Syd., u.B., c.M. E Atal 9 ‘the Insane, ‘ peg near Goulbur Ross, Colin John, B.Sc., B.E., Assoc. M. Inst. . Ez, Borough Engineer, Town a Herbert E., yee, 17 ; Mining Engineer, 121 Pitt-st. s, J. Grafton, * O’Connell-st oem W. H., Colonial Sugar Pee O’Connell-st., and Union Clu Rowney, George Henry, A.M.1 Water and Sewerage ard, oo p.r. 12 alinceiecek. Dachiohnesk Russell, Hen » BA A. Syd., C.M.G., F-B.S., F.R.A.S., P.R. Met. Soc., Me oy. Soc South Australia, Cece on. in onomer, Sydney Observato ory. Rygate, Phillip W., m.a., B-£ . Syd., 14 O’Connell-street. Sahl, Carl L., German Consulate, . gee otgie ag te James Alexander, F.C.s., s.m., Sydney Univer- y. Gle tSoott, one. Willia , M.A. Cantab., Kurrajong Heights. Scott, Walter, nis ’ Oxo ONn., Professor of Greek, University, Sydney. Seaver, ba s Whitchurch, B.c.z. Roy. Univ. Irel., Water Conservation Branch, Pu “ at Works Department, p-r. Underclife-strost North Selfe, Nor 0.5. M, oe or ae Victoria Chambers, 279 eo. ners Sellors, R. P., B.a. Syd., ¥.R.A.8., Sydney Observator, Selman, D. Codrington, Wh. Sc., St. James’ Chaisbeta ‘King- street, City. Shaw, — William, c.z., ‘Seswell,’ Torrington Road, Stra Shellshear, ‘Walter, M. Inst. C.E., Divisional Engineer, kane Departme oulburn Shepard, A. D., Box 728 G. P. oO. ey Sheppard, Rev. G., B.a. Syd., ‘ Shewen, Alfred, m.v. Univ. tak per c.s. Eng., 6 Lyons’ Park. errace, Simpson, Benjamin Crispin, M. Inst. C.E., 113 Phillip-stree' Sinclair, Eric, m.p., c.m. Univ. Glas., Hospital for the ak Gladesville XxX. Elected ' ; ‘ 1893 sear Russell, m.1.m.n. &c., Consulting Engineer, 97 Pitt- 1884 | Siivcieg, Robert Scot, m.B., cm. Edin., Elizabeth-street, H Park. 1877 | rRltone Frederick Evans, 94 oe Paddingto 1891 P | Smail, J. M., M.Inst.©.E., Chief Engineer, Metropolitan Board | f Wat er ete y and ey ny ‘34 Pattatreet 1893 | |? 3| Smeeth, William Frederick, M.A., B.E., ev A.R.S.M., Demon- | rator in at Sydney Universi 1893 | P 7 Smith ya G., MEicteahoa lee, Technological Mus | edac 1874 1 P P 1 \{¢Smith, sera Rea. Denison-street, Woollahr ® | "8 mith, Robert, m.a. Sydney, Marlborough Diasistaie 2 et. °C 1886 — Smith, Walter Alexander, M. Inst.c.E, Roads, Bridges and Sewerage Branch, ra pao Department, N. Sydne Speak, Savannah J., Assoc 1892 | | 1893 | | Spencer, Photnds William: Taube: Resident Engineer, | ds and Bridges, Armidale. 1879 | | Spry, James Monsell, Union Club. 1892 P 1: Statham, Edwyn Joseph, assoc. M. Inst.C.k., ‘ Fenella,’ Frederick- | street, Rockdale. 1892 | | Statham, nso Pipa gy — cage Blayney. 1882 | | Stee . = - BS. Univ. Melb., 3 | Taek ‘Beas Pa a 1889 | Besphee: Arthur Winbourn, t.s., Mulgo 1879 | Stephen, sie Hon reas bees s A., M.L.c., 12—14 O’ ee 1891 | | Stilwell, A C.k., ‘ ‘Strathroy,’ "ast Ora 1892 | St rest poste ‘MaDouncil, B.E. Queen’s Univ. fiers va Inst, C.E. * Dunsevirick,’ Pymble. 1883 P3| oO Pi = P. Anderson, Univ. Edin., boo ase of logy, University ¢ of Sydn ae coe a 1892 | ‘Sturt, Clifton 2 8. Edin., .F.P Wistaria, Bulli. 1883 | Styles, George Mildinhall, Commercial Bank, George-street. 1887 | Sulman —— 1876 'P 1| Sutter, The Hon be ears , 264 N orwood Villa, Ocean- | street, Paddington ag Eo 1893 | ‘fTaylor, James, B.Sc, A.R.8.M., Government Metallurgist, ba ol Adderton Road, Dundas. 1862 9 Tebbutt, John, ¥.z.a.s., Private Observatory, The Peninsula, | | Windsor, New South Wales pet oy | Thomas, F. a unter River N. S. N. Co., Sussex-street. Thomson, gald, m.u.a., c/o Messrs. Thomson Bros., 9 sok Castle ni eet. Thompson, oe 159 see jatar cnn Woolloomooloo. Thompson, Thom es, Eldon Chambers, 92 Pitt-street. 1885 | P2 Thompson John Aabeerte on, M.D. Bruz., Health Departed acquarie-s 1892 Thow, William, Locomotive Department, Eveleigh. Elected 1886 | FA Threlfall, Richard, m.a. Cantab., Professor of Physics, Uni- versity of Sydney. hem President. Thri see Rees shows the method of curving the surfaces on the supposition that tore lift is obtained thereby, which is very doubtful with a calico of After A, B, Cand E had been successfully flown, a rather flimsy joint at the right hand lower corner of the forward cell of C gave 46 L. HARGRAVE. way, this necessitated hauling down E and C, and toggling on D in place of C. Two gentlemen assisted and it was safely accom plished. A, B, D and E were now flying, E being about six feet from the ground, the lot pulling one hundred and eighty pounds E was secured by a guntackle purchase to the spring balance and the spring balance to two sacks of sand. The sling seat was toggled on and the writer got aboard with ® hand anemometer and a clinometer. James Swain, the assistant, slacked away the tackle fall to the end. The apparatus was then forty-two feet to leeward of the sand bags and veering with the wind round an arc of 40°.. This was unexpected, as the wind bs: well to the eastward of S.S.E., and the coast trends N NE. and §.S.W. At this stage there were only a few pounds weight u» : ’ supported by the kites. The velocity of the wind was 14-7 miles | per hour. The pull on the spring balance one hundred and twenty q pounds, and the slope of E with the horizon was 15°. | In about a quarter of an hour the wind freshened and raised the experimenter, when he found the velocity of the wind to be L 18-6 miles per hour, the spring balance reading one huner® — and eighty pounds maximum. The wind falling lighter, kit® and experimenter came down. Several more ascents were q but not of sufficient duration to read the anemometer, which a & two minutes and glass. However, a long and strong pu eventually came and sent everything up like a shot. A careful 4 reading showed the wind velocity to be twenty-one miles pe hour, with two hundred and forty pounds maximum pull o@ oe : spring balance, the total weight aloft being two hundred and eight pounds five ounces. The angle at which A, B and D we” — flying above was measured from E to be about 60°, and also te z height from the sling seat to the ground, sixteen feet. The upP™ kites and E were sloped to the horizon at about the same angles 7 so that the forward ends of the cells were open to view from Es J ees On coming to the ground, the -writer, whilst still on the sling seat, was just able by the aid of the guntackle purchase to bal — himself and the kites to the moorings. ‘The descent in every © AERONAUTICAL WORE. 47 was of the gentlest description. D was the most difficult kite to haul down. ‘The kite line used is common Manilla clothes line, and is not easy to handle when strained. A small winch on the sling seat will make an ascent possible without any assistance whatever. From experiments previously made with the three cornered calico kite in Plate 4, it is gathered that an increase in the velocity of. the wind on this occasion would have brought A, B and D nearer and nearer to the zenith, when a point would have been reached where the kites and line would begin to lean over side- ways and come nearer to the ground, making @ considerable azimuthal angle with the direction of the wind. Supposing the twenty-one mile wind to have a force of two pounds per square foot : then two hundred and thirty-two square feet of kite at 15° slope would exert a lift of two hundred and seventeen pounds and a drift of fifty-eight pounds. If the line were moved further for- ward so that the slope became 10°; an equa! velocity of wind would only produce one hundred and fifty-three pounds of lift, and the drift would be reduced to twenty-seven pounds. So that, if the kites are merely to lift weight, the line might with advantage be moved aft. If the kites are to be driven by a motor on board the lowest one, the weight must be moved forward when the thrust of the motor exceeds the drift. It is thought that this experiment marks an epoch in the series of aeronautical contrivances recorded in our Journal. Although the altitude attained was trifling, the conditions would be identical if the kites had been held by a mile of piano wire instead of the clothes line. The particular steps gained are the demonstration that an extremely simple apparatus can be made, carried about, and flown one man ; and that a safe means of making an ascent with a flying machine, of trying the same without any risk of accident, and descending, is’ now at the service of any experimenter who Wishes to use it, 48 E. F. PITTMAN. By E. F. Prrrman, a.R.s.M., Government Geologist, Sydney. [Read before the Royal Society of N. 8.. Wales, June 5, 1895 } Ix November 1893, a new mineral named Willyamite from the Australian Broken Hill Consols Mine was described at a meeting : of this Society, and the following notes relate to two new mineral : substances, which are somewhat remarkable in their composition, — and which are from the same interesting mine, having been for — warded to me by Mr. Geo. Smith, the General Manager. Although both these substances differ materially from anything hitherto — described, neither of them is regarded as a distinct mineral species. ‘ They appear to be merely mineral mixtures and may be described as alteration products, the one having evidently been derived — from the mineral dyscrasite and the other from argentiferous : galena. I.—The first substance was found at a depth of from one hundred to one hundred and forty feet (vertical) in a limonite gangue and was associated with stromeyerite, bindheimite, volgerite, and azurite. One specimen found by Mr. Smith was encasing a kernel of dyscrasite. The substance is massive, the colour is greyish-brows but when a surface is cut and polished on a lapidary’s wheel, OF when a thin section is examined under the microscope it is see? to have a finely banded structure, the bands having a somewhat metallic lustre. The substance is sectile. The specific gravity of the specimen on the table is 4-9. Two analyses of the substance were made in the Geological Survey Laboratory, No. 1 being bY — Mr. J. C. H. Mingaye, r.cs., and the’ other by Mr, Harold P- : White, F.c.s. a : Norres on two New MINERAL SUBSTANCES rrom THE AUSTRALIAN BROKEN HILL CONSOLS MINE. : ; TWO NEW MINERAL SUBSTANCES. 49 Ey ii, Moisture at 100° C. aie D6 sid ‘13 Combined water... ee 4-04 Ue 4°37 Silver in vis 1 = 47°46 igee 45°87 Antimony . 16°87 20°72 Copper 11 48 Lead 62 31 Arsenic trace trace Gold dis trace Lime (CaQ) sie 3°78 va 4:25 Magnesia (MgO) ... mee 117 ai 20 Ferric Oxide (Fe,0,) ike 2-11 me “45 Chlorine... a a5 ee ae 12°27 Insoluble matter (gangue)... 1-01 se ‘90 Oxygen (by difference)... 8:58 a 10-05 100-00 100-00 Mr. Mingaye added that the silver is present as chloride, and also in combination with antimony, as antimoniate (with possibly Some antimonite) of silver. The lime, copper, lead and magnesia are also probably present as antimoniates. The analyses taken in conjunction with the somewhat banded _ §ppearance which polished sections of the substance presented, - Pointed to the probability of its being a mixture and not a mineral of definite chemical composition, and with the object of settling ” question it was suggested to Mr. Mingaye that he should s digest Some of the finely powdered mineral with strong ammonia. was done with the result that practically the whole of the chloride of silver was dissolved, only a trace remaining at the end of forty-eight hours. An analysis by Mr. Mingaye of the residue insoluble in “mmonia yielded as follows :— Silver a Hoe ac ke | Gold... ae vel ... trace D—June 5, 1995, Mo. Bot. Garden, 50 E. F. PITTMAN. Antimony ... ao ee 3642 Arsenic hee ae a i traes Lead... ate mes aoe 2-79 Copper is eo ads 52 Tron ... oe ea ae 5-18 Calcium Se But sae 4°84 Magnesium .. , “Xs Insoluble matter (g Se i 5-20 Chlorine ke Fre 14 peer 6-0] ( mean of va eee eee eee experiments | q Oxygen ae ae ee yt by direct | weighing. — 99-37 At the suggestion of Professor Liversidge a polished surface of | | the substance was then etched by allowing a solution of strong | ammonia to stand on it for some hours. ‘The result clearly shows | that the chloride of silver has been removed leaving the am moniate of silver in relief. II.—The second substance is clearly an alteration product derived from argentiferous galena. It is dark grey in colour— has a cubical structure, being in fact pseudomorphous after gale It is sectile—has a variable specific gravity—that of the specimen on the table being 6°38. Its chemical composition is chiefly sulphate of lead and sulphide of silver in widely varying propor tions, with small quantities of sulphide of iron, sulphide of cop and sulphide of lead. Altogether four analyses of this interesting substance have P* made in ihe Geological Survey Laboratory, Nos. I., IL. and! being by Mr. J. C. H. Mingaye, and No. IV., by Mr. Harold White. I. IL. II. IV. Moisture ws 08 'S8b,8, -44 Moisture -14 FeO. Ag.S Sulphide of Silver77-99 7662 13-25 1068: Cu u,S_ ” Copper 62 32. 1°82 THE CUBIC PARABOLA. 51 Li Ti. iit. IV. FeS, SulphideofIron 1°42 “45 “42 PbSO, Sulphate of Lead 19°36 19°80 77°60 84°61 PbS Sulphide of Lead ... 710) 2-20 ‘96 Insoluble matter °30 1:60 4°50 1:00 99°77 99-73 99°93 99-93 see a It will be seen from these analyses that the composition of the substance is too variable to allow of its being classed as a mineral species. A polished surface of the substance was treated for some hours with a solution of acetate of ammonia with the result that some of the sulphate of lead has been removed, Jeaving the sulphide of silver in relief. _ Tue CUBIC PARABOLA As APPLIED TO THE EASING or CIRCULAR CURVES on RAILWAY LINES. : By C. J. MERFIELD. (Communicated by Mr. G. H. KNIBBs. ) [With Plate X.] [Read before the Royal Society of N.S. Wales, June 5, 1895.] Tue cubic parabola having been adopted by engineers and Surveyors of this Colony, as an easing curve to the circular arcs railway and tram lines, exact and extended tables will be : Fequired. The following investigation and tables are intended to supply this want. Many of the methods that have been published are defective, and unsuited to the requirements of the engineer. The use of the cubic parabola, as a transition or easing curve, is by no means new. The American and Continental Railways are mostly so located, that a curve of varying radius may be 52 C. J. MERFIELD. applied to the circular arcs. The advantage of such a system cannot be overestimated. It is however not the object of this paper to discuss these matters. Mr. Shellshear in his paper read before this Society, has given nearly all that can be desired about this particuiar curve, and his method of location is carried to a fair degree of approximation. For transitions of from one to two chains in length, his procedure is practically exact, provided that the radius of curvature be large at the point of contact with the circular arc. Increasing the transition to say four chains, the error becomes noticeable, and seems to require a more exact method of location. In the following pages the necessary equations are deduced, - which upon solution, will give data for the location of the cubi¢ parabola to any circular arc, so that the radius of curvature will be equal to that of the circular are at the point of contact. Table No. 1 gives the offsets, and other quantities, according to this exact method, in several useful cases. This degree of accuracy may not always be required, it depends upon the solution of an awkward equation, which would perhaps deter some engineers from employing the formule. During the author’s duties in the Railway Construction Branch Public Works, N.S.W., he was called upon to prepare tables of the offsets to this curve, for several cases, to be used by the surveyors of the department. The method adopted in their preparation, was to comput? the offset, at the point of contact, from the equation Yor 3 { R- / R?— ) . \ the intermediate offsets being varied as the cube of the distance along the axis of X. This would represent a cubic parabola, but the radius of curvature is in error, de small extent, at the point of contact with the circular are. This error is however not sufficiently large to injuriously affect the usefulness of this approximate method. To many the method of locating curves by a system of offsets is tedious. Tables of the angles, contained between the radius THE CUBIC PARABOLA. 53 vector and the axis of X, for every ten links from the origin along the curve, have been computed. Other useful data are added. Table No. 3 contains these quantities, computed by the exact method. Table No. 4 is similar to the above, and corresponds to the parabola given by the offets tabulated in Table No. 2. The values of log ““m” for various cases are given in Table No. 5. The deduced formule will not only be found useful in the pre- paration of tables, but will be advantageous in many of the problems that beset the engineer or surveyor, in the location of this curve. For this purpose the equations are collated, so that a selection may be made for particular cases. NorarTIon. p= Radius of curvature at any point. R= Radius of circle =p at point of contact C. “z= Values along axis of X. y= Values along axis of Y. %:= Value of x at point of contact C. Ye= Value of y at point of contact C. O= Origin of curve. K=c=Constant. «=Length 7 K=E B. y=LengthCK. (See fig. 1) H = Distance of parallel tangent. $= Angle contained between the tangent to the curve, and the axisof X=C DB. (Fig. 1) 9= Angle contained between the radius vector and the axis of X. = Particular value of 6. Length of cubic parabola =O C. *= Any length along curve. *=AngleOL0O'. (See fig. 2.) A= Area contained between x, y, and the curve. 9= Angle 0 C B. g = Gauge. *,=O B= 2, — x. 4 : " v = Velocity. 54 C. J. MERFIELD. Where differential or integral calculus is employed the usual notation. THE Cusic PARABOLA. To overcome a train’s centrifugal force, the outer rail of all © railway curves should be elevated, Every change of curvature — should have a corresponding alteration in the cant of the rails. _As this alteration can be made only gradually, changes of curva- ) ture should be gradual. The cubic parabola, owing to its easy : application, seems to be especially suited for this purpose. In | the following pages, data necessary for their location are deduced. Let the gradual superelevation of the outer rail be taken uniform, for distances from 0 along the axis X, or let + be the rate of rise, then the rise at any distance « will be “. (See fig. !) If p be the radius of curvature at the corresponding point om the curve, we have the superelevation equal to gauge x velocity” 32:17 x radius ” | the gauge being expressed in inches, the velocity in feet per second, and the radius in feet. 2 o Therefore Now for a given velocity and rate of rise +, the quantity a7 a becomes a constant, let it be represented a Be te a eee Ee eer Therefore ¢ = ie, and a ! 41+(5%)" 53 a oe ee a d s* But 5 s dae dy Let us for simplicity ne d s=d « then we have vhs ey ee = rr “. = = integrating twice we ar = -. eae This is an eciiadion to the cubic parabola, which may be written y= m o* ica ag Mt ey Tog cae THE CUBIC PARABOLA. 55 in which m = . It is in this form that we will use the equation, to deduce the formule necessary for the location of the curve. In the equation to the curve, the constant “m” may be fixed at pleasure, according to the requirements of the case. Now it is necessary that the radius of curvature at some point, shall be a particular value, so that we must give to the constant a numerical value, so that when placed in a particular equation, the desired result will be obtained. The radius of curvature in any curve equals d f {1 + sty" (3) 38 i da? Cubic Paiabola y= mx oy = om ee 3 d= 4 2 Behar 6 Mm 2 da : Therefore p = (149m? 24) : 6me From this equation we may find m, if we know p and a, by a method of approximations, until the correct value is obtained. The method adopted is as follows :— tan ¢ = £4 3 m ae? eee. CNet ater ealgy 6m tan Reducing we ep 5% = Sin $ Cos? ¢ cieseeeenes S _ A value of the acer ¢, such that its sine multiplied by its cosine _ “Mared, will equal 5% can soon be found. If the tangent of this angle be placed in the equation tang = 3mz We obtain the value of m required. (See table 5.) Produce the arc CC’, which has the same radius as the curve *t C, to the point 7, until its tangent becomes parallel to the axis of Zz, (See fig VY CB=y, =m ae? 56 Cc. J. MERFIELD. The co-ordinate y varies as the cube of the distance A: tho axis of X. Angled =CDB=CFG tan d = 3m 2,? = EB = R Sin ¢ y =GT=R- RCos¢ H=TH=y,-GT EO=2, — 2 : The preceding investigation is an exact method of locating the cubic parabola, as applied to the easing of circular ares. . Before explaining an approximate method, we will deduce some — useful formule from the equation to the curve. y=m saa 2' tan ¢ = =3mz2,? 3 From equation 2’, m = = ; and by substituting this value of m in equation 3 we have i 3 tan ¢ = — 6 Therefore the tangent at C, if produced to D, makes an angle with the axis of X, the tangent of which equals ove Further — than this we see from equation 6, that D B= 4 xc, and O D=3te Again DC = y, Cosec Tec Cot 4 ~s Therefore DC = Ye/ Lee, os v 208 ed Se § a Let the angle contained nitheae reg radius vector, and the 4 axis of Y be denoted by @. tan 9 = ¥=me* Therefore tan 6 = m x?.. 8 The tangent of the sates varies as the square of the distanc® — along the axis of _Y. tan ¢ = 3 m 2? 3 eee eee Comparing this last equation with number 8 we have THE CUBIC PARABOLA. 57 tan ¢ = 3 tan #6. | tan 6 tan d 4 a = ye SATE Se Jom peers 1 Length of Parabola y= moi. m = —, dy ae ae is = 3m 2x ds / dy \2 tat Sg tte) Therefore $s age & af 1 +9m2a2*t de Expanding, and integrating the individual terms we find 8=2+ +5; m’ «* — $m* x” ete Qa Remembering that m = we find 2 4 reer E 2% Dividing both sides of equation by x we obtain © ih cided te Remembering that tan 6 = 4, we have s=a (1+ 5% tan?0— 2 tan*d...) 10 The first two terms of any of the above expressions will give the length of the curve approximately. In the computation of the tables, the third term has been taken into account. The area A contained between the co-ordinates, «, y and the curve is easily obtained. Area A = f/ydx = /m2° dx , integrating, and remembering that m = —";, we find that 9 A=2¥ it oy 4 ‘The area therefore equals, one fourth « multiplied by y Length of Circular Are. The length of circular arc CC’ is obtained in the following manner, (See fig 2 58 _ C. J. MERFIELD. If the circular measure of the angle ¢ is now taken, and — multiplied by the radius of the circular arc, we obtain the length — of are 7’ C or 7’ C’. Now length of are 7’ 7" equals the circular measure of the angle — w multiplied by the radius. Hence the following formula CC'= R§[o—2 (Sin —1 £)]}-0002909 12 The angle within brackets being expressed in minutes. Approximate Method of Location. We shall now proceed with the investigation of an approximate — method 2 pas = ga: 1 6 me 1 Therefore x = eI ead OF In the preparation of the tables (excepting table la and 16) # has been taken equal to four chains, this being the value adopted — by the Railway Construction Department. But really « could be varied inversely as the radius. That is to say, if we use four chains as the length of transition to the ten chain radius arc, W — would obtain the same result, by taking two chains as the length ‘ of easement to a twenty chain radius are, providing the velocity — is the same. However it is perhaps as well to keep « a constant value, and so avoid complexity. To locate the position of the parabola. Let the circular are ¢ C be produced to 7, where its tangent becomes parallel to the axis of X. Then the angle CDBe Crt => Now tan > = aes == au om 3 7 Be" ¥o = | 5" 7% = Be Therefore tan ¢ = ee 6 The tangent at the eh C, if ~— to the axis of X, cuts it at D making O D = 3,, and D B= ia, (See fig. 1) AgainCG=EFB=(R- GT) tan ¢ Approximately H B= FR tan 4, taking G 7’ as a small quantity THE CUBIC PARABOLA. 59 Substitute for R the value ,— on es 12 Also for tan > the cages 3 mm @,* Therefore E B=°* 7 fe = “5 approximat tely hates 13 From equation 13 we find that the point Z at right angles to Ya divides O B into two equal parts nearly. To find 7 FE = H OD 2 ¥, ( ° and G 7 = \2 approximately, taking G 7’ as a small quantity ‘eres 4 1 oa &o* eo ean. Therefore G T = jy, ...- 14 TE =H = Yo — i¥e Therefore H = } y¢....---- 15 | Again 7 FE = KB=}CB } Pe CB + CA ; Therefore K B= 1CK Now C K = R - £0 Therefore C B = =#{2 = 2) de = (2)? \ oe 16 * This completes the arenehanene method of location. The length of the curve can be found by equation 9 or by 10. Length of are C . ' may be found from the equation number il. _‘Ifwe take EB = 5 this equation may be written oO = Rife- 2(8in 2) ] } -0002909.......--ser \7 : The radius of curvature may be obtained approximately by the following ba P = 6me Substitute for m the value = and we obtain c Be Se eon Oo 18 6 Ye 60 C. J. MERFIELD. To find the exact radius of curvature in terms of « and y. ie 3 +9 m? nett means 4 6m2z substitute for m its value —**, “3 and we obtain sotaye V (ae? +9 ye?)® p= R= JES x“) = < fae. ieeeks 19 ee ci To obtain p at any point on the curve, it is only necessary to place the values of the co-ordinates x and y in equation 19. TABLES. Table 1 contains the data necessary for the location of the transition by the exact method. The first column gives the dis- tance x’ = EF B,EO =x —EB. H equals the distance TL of the parallel tangent, this quantity is to be set inwards, after the lines O LZ, L O', have been fixed. This latter distance 18 obtained in the following manner LH=LE' = tan © (R+H) LO=L0O = tan > (R+H)+£O (See fig. 2.) The angle ¢ is also tabulated. The offsets at various distances then follow. OC equals length of transition. equals twice the circular measure of angle ¢, | this quantity is taken from the circular measure of the angle % the result is the circular measure of (o — 2¢). This quantity being multiplied by the radius, gives the length CC’, All dis tances are in links, except where mentioned. Table la and 16. These tables are constructed in the same manner as above, and will be found useful to the tramway engineer. Comparing these two tables with Table 1, it will be found easy to extend, as may be required. Table 2 is similar to Table 1, but by taking « = 2, we eliminate the first quantity given in Table 1. The angle ¢ is not tabulated, but may be obtained from the equation tan ¢ = sa a ak a a a a a a pe THE CUBIC PARABOLA. 61 Table 3. Extending over several pages, contains the angle 4 for every ten links along the curve. Also other data necessary for the location of the parabola. The radius of curvature to the nearest chain is also tabulated. The following example will illustrate its use. Having decided upon the radius of the arc C C’, (See fig. 2.) compute the length LO = LO’ = tan o(R+H ) + (@_—@’). Say & = 10 chains Angle w = 50° “~L0= L10' = 66014 Set instrument at O and for the further illustration, say that the mileage of the point O is 320 m. 4.¢. 14:51. The next chain to be set out is therefore at a distance 85:5 links from 0. Consulting the table we find at 80 links the angle is 9’ 48". To obtain the angle corresponding to 85-5 we must multiply the difference 15-6” by 5:5 = 1’ 25:8". Adding this to 9’ 48” we obtain 11’ 14”, neglecting the decimal, this is the angle to be laid out. In a similar manner we obtain the angles corresponding to the mileages 320 m. 6c. = 52’ 43” 320m. 7c. = 2° 4’ 33° 320 m. 8c. = 3° 45’ 38” The angle 4° 4’ 40’, and the distance 401-818, brings us to the point C. It will now be more convenient to move the instrument to 4. (See fig. a) DA = Sec> (R+H)-R . The are C ’ can then be located in the usual manner. We may set out the arc C C’ from the point C. Having set the instrument at C, sight to 0. Revolve the telescope, towards the axis of X, through the angle = (¢—6), the telescope will then point in the direction of the tangent to C. The curve C Cc’ may then be located. 62 C. J. MERFIELD. Table 4 is similar to Table 3. The value of y used in the” equation to obtain the angles, is found by the formula No. 16. This table may be called the approximate as it is exactly the | same parabola, as that given by Table 2. The radius of curvature ; being in error to a small extent at the point of contact C. ‘Table 5 contains the exact value of log “‘m,” to be used in the rigorous method. These values have been computed from equ® — tions 3 and 4. Table 6. This table gives the log cubes, also the log squares | of the distance along the axis of X for every ten links. The us? — of these quantities will be made apparent by the following examples. : Required the offsets to the transition to the ten chain radius arc at the distances 3-50, 3-60 and 3:70 from O along the axis of X. = me: takes = 4< log m. = 7°6489271 (See table ‘. ) log x, = 1-8061800 log y, = 9°4551071 Yo = 0°28517 Yo = 94551071 = 9°4551071 = 9-4551071 : en 50) =9-8260240 (3-60) = 9:8627275 (3-70)= 9°898425! [log offset = 9-2811311 9-3178346 9-3535322 offset = 0:19104 0-20789 0-22570 Again required the angles 6’, for a transition to the twelve chai | radius arc, %, = 4. The distances along the axis of X being 3:60, 3°70 and 3-80, We find from the equation tan @ = ma,? = ° that log tan 9 = 8-7477807 approximate — ; log tan CO B=8-7477807 = 87477807 = 8-7477807 Table (3-60) = 9-9084850 (3- 70) = 9-9322834 (3-80) =9- 9554472 log tan 6’ =8-6562657 8-6800641 87032279 @ =2° 35’ 41-0” 9° 44’. 26-4” 9°, 53’. 260° THE CUBIC PARABOLA. 63 The angles for every ten links along the curve are not so easily obtained. In the computation of their values, the method adopted was a mechanical one. After computing the values as above, for dis- tances along the axis of X, also the corresponding distances along the curve, take the difference (x-s) and interpolate. To be more exact, this difference should be multiplied by the cosine of some angle, the tangent of which is about equal to 3, before the interpolation is commenced. Table 3 has been eccieal in this way. Table 4 has been calculated, having no regard to the cosine of this angle, the angle is small, its cosine is nearly unity, so that it can be eliminated, without having much effect on the result. The second difference has been taken into account in the interpolation. It may be found impossible to locate the whole curve from the point 0. In sucha case, the curve may be laid out from the point C. Let ZO = 2, OB = x, asbefore. 6 = angle BC O. Then we have tan 625, let m ta ~@,*) Appended will be found a list of the formule collated. FoRMUL. yu me 1+9 m?2+)? erase ee 2 p= * cele a yee p = ——.(nearly) « 6zuy oy R = p at the point C. tand = 3mz2,? or tan ace PBattn OD = 4 % = Sin ¢ (os? 4 = RSind. FEO=2, - x’. GT =R-— RCos¢ Pape ey OP DC = y, Cosec . or DC = EN Te tan G= mag. = os 64 Cc. J. MERFIELD. tan ¢@ = 3 tan 6 tan @ or | tan ee (ren . m Peg cc ae tan 0 = iat Area A = |. 2 4 g= a+r - 4% .; etc. x x s = (1+ 1% ma* — § m*x* etc.) a= 20 + o tan? § — 2% tan* @ etc.) s = «(1+°1 tan® ¢- -0138 tan* ¢ etc.) CC' = R{[o-2 (Sin *)]t -0002909 CC = Ri [w-2 (Sin 2, lt 0002909 taking a’ = * 3 CB om al By Et (*@) \ taking 2’ =“ and a, = /6Ry. — 2 y” L O' = tan ie (R+H) + (a, - “) LB =LE = ton” (R+H) DA= Sec © (R4+H) -— R LV=LV'=tan“ H Lo = 2| wo THE CUBIC PARABOLA. ‘SUIBYO UL UOALS OIv OIA “ItpVa oyy ydooxe ‘sUI[ UI OI’ sptlouledtisvout [TV ‘gd — O WIZ J CE 0} SOTSUB FYSTA YB JNO Jos OG OF S}OSHO jo qurod oy} 03 yUe8UB] oy] WoaMyoq poureyUOS o[sUY ae peas di 8) *AAIND WOTJISUBAY JO q4suey = "XY JO STx¥ oy} pue ‘QoR}U0D *jueSuyy oypeavd Jo couvysiy ‘d W oouvgstd SPIC6EG- ‘| 8682 72e- a 8086266- a PILZ8918- | SLOFZ0G.| BPVEETZ-| SOSSEEE- 308 | Z1F-00F | 8SP- 00% | rasp OOF LLG. 00% | GS9.00F | OL: 00% | 898- 00% | 810: TOF | O18: = LO¥- si 818-108 | PEE-ZOP | TOT-8OF PSST 8z2-FT OT-ST €0-9T 80-LT 82-8T | 19-61 08-16 | ¥S-E% | 09-3 Zo-82 L2-88 8-18 CG.21 €6-E1 00-FT 98-FL €8-ST | %6-9T Pe-81 PL-61 | GS-16 | ZL-8S F-96 16-62 09-98 T9-1T PZ-eL G6-6L PL-ST ~9-FT 49:ST | £8-9T 92-8L | 86-61 | F616 “P-7e | (L9-L6 00-28 22-01 | O81 | $6-IT | 89-8L | 9-81 | LP-FT | 1¢st | 98-91 | OF8T | 92.08 | 29-28 ¥9-9% | 9-66 18-6 TF-0l | 10-1f | 89-IT | G¥-8T | 88-81 | FE-FT | SST 6-91 | 99-81 | 64-08 89-86 | T8-LB 10-6 99-6 61-01 | $01 PV-IL G26 | 81ST LOFT | LGST | STLT OL-61T | 89-12 00-93 18-8 L138 16-6 8-6 6P-0L €¢-1T | 80-61 80-8T LG-¥T 6L-ST TS-41 68-61 BG-26 09-4 20-8 8F-8 | 00-6 69-6 | L46-0T | 0-11 ; 96-11 $0-8T | 12-71 | TO-9T | 8t-8T | 96-02 £6-9 8-4 eL-4 18-8 8 | 986 | 40-01 | 16.01 , 06-1 | OT-€T | O9-FT | 89-91 | IT-6I 08-9 79-9 £0-4 | 9F-4 c6-4 | 198 | 916 | 266 68-01 16-11 16-81 60-21 8e-L1 TLS 30:9 | 8-9 94-9 16-4 TZ | 088 | 66:8 18-6 08-0T 0-61 19-81 91ST OF-F 19-4 | 16-4 12:¢ cG.G P6-S 68-9 26-9 Go.4 18-8 LB-6 6F-01 | SL2l 18-8 6h | 69-8 16-8 LLP OF. 08-% 08-S 19-9 | $8.9 96-9 8s-L IL-6 re) foe) Oe | See | Oe | ee 648 | FF | 99+ | 209 | PLE | 19-9 69-1 64-1 68-T 00-2 €1-2- | 68-3 OFS 99-6 162 | 088 99-8 £0-F 19-8 14-0 GL-0 08-0 8-0 06-0 | 960 | *OT | SLT 21 | 98-1 G1 OL-T L6-1 12-0 26-0 2-0 2-0 26:0 | 600 | TO | 88.0 98-0 OF-0 SF. 08-0 89-0 £0-0 £0-0 £0-0 | 80-0 20:0 | 70-0 | 70.0 | 70-0 | 900 | 90-0 |! 90.0 | 900 10-0 ‘SLAUSAIO See OS ere eran og ly 9 jer 9 9 [e 9 er Le 9 or 1g 9 te Lb 96 SF 4 |9€ £7 8 Orr 6 | Tee ‘Ld: e 1 eee” é ae re coe r 89. oe ee 1s. o rae 202 ET ae 90-80% [oa z0z | 99.706 68. a3 Be. Ee QL. as 98-60% | TT-90%_| 80-908 8.208 o1-608 84:1 11z_| 89- 99-918 0 81 | as P ene NES ed i See sow 40D jo (U10g 9¥ SHIpUsy “(pouTe ee GAvoo NOLLISNVUL SIV HOES & SLA. C. J. MERFIELD. TABLE Ia.—Taste or Orrsets Two-CHaIn TRANSITION CURVE. (Exact Method). } Radius at Point of Contact. age | 2 . el ee ee Ee ee *82 [e| 1078s | 10468 | 10304 | 10218 | 10164 _ Bee |H| 385 a 2°06 aA ee ree ° ? 7 fe) 7 7 s) 7 W os ANS || 1538 25|12 421 | 9 5319 | 8 23 36 | 717 57 | Seg es NE ae 20 0°02 0-01 O01 | O-OL 0°01 ed ead O11 | O09 | 0°08 0:07 50 0°22 O18 | 0-15 0°13 60 0°50 0°38 0°31 026 0°23 70 | 0°80 0°61 0-49 0-4 0°37 80 1:20 0-91 O74 - 0°63 0°55 90 re; Ye 1:06 0-90 0-78 100 S385 | 1-78 1°45 1-23 07 110 3°10 | 2°37 | 1:93 1-64 1-42 120 403 3-08 | 2°51 2°12 1:84 130 eis oer 19 2°70 2°34 40 6°40 4°89 | 3:98 3°37 2°93 150 7-87 | 601 | 490 415 3°60 160 9°55 730 | 5:95 5°04 4°37 170 11°46 8-76 - | 7°14 6°04 5:24 13°60 10°39 8°47 717 6°22 190 1600 | 12°22 9-96 8°43 7°32 200 1866 | 1426 | 11°62 984 ie OC | 201-551 | 200-909 | 200-605 200-434 200°328 ~ 200-328 K | 054594 | 042141 | 0-34517 029298 | 0° “025479_ Footnotes same as on Table I. TABLE Is.—Tastez or Orrsets ONE-CHAIN TRANSITION CuRVE (Exact Method i Radius at Point of Contact. dee tBu 8 oe 9 Eg @| 6892 | 5152 —-Bu"s2 | BRE ddl ae eye Te ae A | @SsZ Fg? Sones” SSR AGREE NRA SRN | AAS $15 38295| 95819 71757 } or eee ee | OOS 40 0°60 0°37 0°27 50 1°17 072 0:53 / 2-02 125 | 0-92 0 Fs ea 1:99 1-46 Ob ey 2:97 2-18 90 6:30 4° pe i ; 100 9°33 5°81 4°27 | | “Od 100-775 | 100-303 | 100°164 __K | 054504 | 084517 | 0-25479 Footnotes same as on Table I. THE CUBIC PARABOLA. oq [ITM surper Aq partdryynu Sureq szopurvmed 94} ‘m of ‘TIPBI OT} 4ooxS SUIT UI OAV S]TOMOINSvETT [TV ‘TF SPIVMOZ O WOIJ JF CO O} SOTSUB 4TLS1I 7B JNO 4Os OG 07 8}O8FO “0 © PATO JO YASUOT [2407 OT} OG TA DO+008 *,0 0 9x8 Jo YyBUET ONY “moTpIsuRsy Jo YASUE = 9 O Suv oy JO oINsvaM IV[NOATO MIOTJ poqovayqns oq 0} JUBISMOH = YF ‘spuesuey joyeaed Jo soueysiq = H 8FSE00Z-| TL160TB-) 0Z89ZZS-| COPSGES-/ 9E9908- ZEIFLOT.796998Z- | ZETG80E-| CIGBPEE-| 8219298. GITLEOF-| GOBTSPF-| SO9ESOS-| | OF-00F | SF-00F| 09-00F| 99-00F| £9-00F 21.008 | 28.008 | £6.00F | ZI-10F | &8-T0F €9-T0F | 10-20% | 99-20¥ | 90 | Ze-et | 80-FT | 98-4T | PL-91 | S491 | 98-L4T | ST-6T | #902 | 88-22 | SF | 6-92 | 00-08 | 48-86 | OOF 62-21 | GOST | L480 | 6S-FT | T¢-ST | $¢9-9T | G4-4T | €1T-6L | ¥2.08 | 99-28 | 16-52 | 18-46 | 68-18 | O68 9F-IT | 20-21 | 4-8E | OS-ST | G8-FT | TEST | THOT | 69-21 | GI-6T | 96-02 | OT-€¢ | 4:93 | 40-62 | 088 83-01 | FLIT | 9411 | OFT | PS-ET | SIFT | ST-ST | S8-9T | TL4I | S86T | 28-18 | S488 | 18-98 | O18 $L-6 92-01 | 28-0t | SPIT | O@ZT | ZO-8T | 96-8T | #O-ST | 18-91 | @8-LT | $9-6T | 148-18 | 69-76 | 098 96-8 &h-6 96-6 GG.ol | 12-11 | 96-IT | 88-21 | 28-8 | 66-FT | 88-9T | GO-8T | OT-0 | 69-26 | OS8 12-8 #9-8 &1-6 19-6 9-01 | 46-01 | 94-11 | 29-20 | FLT | TO-9t | #9-9T | eF8T | ‘08-08 | OF8 Tg-4 06-4 g8-8 $8:8 OF-6 €0-01 | SZOT | 69-IT | Z29-8E | 824-81 | SI-ST | $8-9f | 0-61 | 088 58-9 13-4 19-4 90-8 13.8 P16 08:6 19-01 | 9F-IT | 29-2T | G4-8T.| 98ST | %8-2T | O68 26.9 99-9 C69 e624 61-4 1&8 16:8 19-6 CP-OL 88-11 $9.61 16-81 41-90 | O18 #9-G P6-¢ LE-9 9-9 90-2 g¢-2 80-8 14:8 PPG T8-0T 48-11 99-281 62-FL | 008 PEF Lo.¥ £8-F 61-9 PPG 08:9 2-9 11-9 LBL P6-L ¢L-8 CL.6 TOIT | 922 92-8 PPS €9-8 P88 60-F 98-F L9-% ¥0-9 9F-G 169 89-9 68-4 46-8 | 083 88-3 19-3 G9-8 08: 86-6 sI-e | Th8 19-8 86-8 cE. 6L-F FE 609 | 9% 19.1 94-1 98-T L6-T 60-2 £2-3 68-2 89.3 6L- 90-8 18-8 GL-8 £2-F | 008 04-0 FL-0 84-0 €8-0 88-0 PG. 10-T 60-T 8T-1 62-1 aP-T 89-T 6L-T | OST 12-0 3-0 £2-0 GZ.0 9@-0 82-0 08:0 ze.0 98.0 88.0 BF-0 Lv 0 €9-0 | OOT £0-0 80-0 £0-0 £0.0 £0-0 #0-0 $0-0 0-0 #0-0 0-0 0-0 90-0 40-0 | 0g ‘SLESLAQ | se |¥8-8= H| 9-8=H | 8L-8= H|6-8= H | StF = 1 | 9%- = H | 6L-=H | 91-9 =H [69-9 = H | 11-9 =H | €49=H|09-4=H |468=H i | ome Co Me eR Aa ee $I $I ar II or .. 4; m8 Z ‘SUIvVY,Q UL SNIPB ee eee el *(poyqeyy opemrxoaddy) TANNOO NOLLISNVGL NIVHO'ANOT SLASAAO FO aTaVL— Il ATAV ‘68 C. J, MERFIELD. TABLE III.—Four-CHain TransitTION CuRVE VALUE OF AN LO CURVE. GLE @ ror EVERY TEN LINKS ALONG : (Exact. Method.) sae 8 . Radius 8 Chains. Radius 10 Chains. | 5 Bag bbe Sg ie oo Diff ; : Diff 2a5 S’ a for 1 Link, R 6 for 1 Link. f = i A Secs ° , “a ” ° , ” u” a Pty ee B Cc: 0° 36 1-2 CSA 20 Oo 0-9 ree) rd 0 |0 oO 12 3-6 0 0 9 28 8 Pee 20 |0 0 48 an, 0 0 37 ac @ 8 og 30 |0 1 48 re 92° 3 no oe 4.0. 3 1B 168 077327 $3 qsee 50 [0 & Is} yao | 68 O~ B-60-| 404 | 7) 4 aime ee Se Re ser oY ace. Foe > 35: 7. | Oc 92 4 Toy 7 ae esi 08. | 0-98 let aes 0---0--48.-| Fae oi BAe 90/9 16 14 | O59 0.12 2% | ie $yee is : ee - 35-3 | 29 }9 25 19 | 359° | 871 Be ge ; 0 18 32 ; ; | ee ae See ee ee ota iso | 0 $3, 63 | 30% ae a 8. SAE 149 |0 39 17 | 326 OnMek Tylon oS ue 150 [0 45 6 | 575 | 20/0 36 27 ae |e gM ee car eee 0 30 12 | 908 one | oer 0 44 15 cul oe 180 | 1 55 0-40-3874 Be cea 19 11 12 19 | 444 4 33°9 ay d 15? ° 38’ 35" 12° 4' 21" io b a! 215°68 15 wm ) 7-71 6°40 a 0° 0°4214090 " THE CUBIC PARABOLA. TABLE III.—Continued Radius 12 Chains. Radius 14 Chains. s’ Y erriim |S fort tanke| JR” ° ’ “ “ °o , “” ” ee ee 210030] 23 oo ii, <2 Sela. i) 4. to Sf 0 0 87 33 4010 2 0 2 oo ae Pe M10. 6 ela? o> Sth 8 |0 7 59 | ll? 0 6 4 o6 9 |0 10 7 | 128 o0 s 34 | 108 100 |0 12 29 | 1*2 |aglio 10 34 | 120 | 54 10 1/0 15 6 | 157 6°13 47. | 283 1200 }0 17 59 | 173 0 15 13 | 1*6 130 |0 21 6 | 187 0 17 52 | 29 140 | 0 24 28 | 202 0 20 43 | 171 10 |o 98 5 | 27 | 31/0 46 | 283 | a6 170 |0 36 4 | 247 0 30 32 | 22? 180 |0 40 26 | 262 0 34 14 | 22 19 |0 45° 3 207 0 38 8 23:4 200 |o 49 55 | 272 |ogiio 42 15 | 247 | a7 210 |0 55 2 | 30°7 Site mi | ee 2200 |1 0 ag | 821 om YY. | eee ise ~@ 33°7 0 55 62 28°5 ar FT: gp, | BOT : BS | 208 250 |1 17 57 | 366 | ag iia 6 |: ote tae 260 |1 24 17.-| 380 ¥°Sy: gac {oes 270 | 1 52 | 395 1 56 or. | Be 280 |1 37 43 | 421 y Ss ab tree 200 |1 44 48 | 425 oe WO ji-se og: |: $82 bas tee by: | 222 lade 310 |1 59 41 | 454 '°sa SB, sees 820 |2 7 29 | 268 1 ay 8. |. 330 |2 15 31 | 482 "ss 4 | 80 (2 35 48: | 8 hie Be: 80 |2 32 19 | 511 jigs 9 4 | He | 16 360 2 41 4 52°5 2 16 30 44-6 70 |2 bo 3 | 589 cums @ | ae 380 2 59 16 55'3 2 31 58 47-0 380 3 8 42 56°6 2 40 0 45°23 1400 | 3 18 a2 | 80 |isiia 48 14 | ** | 16 ° 1:21 . 3° 19’ $3"! 9° 48! 56"! Be 9° 58! 19” s° 93’ 36" | = Pit rink ie St 0°3451738 Cc. J. MERFIELD. TABLE III.—Continued. Radius 15 Chains. Radius 16 Chains. s’ 6 fforttink| BR’) 6’ for ttn) ieee. e job | bel or & fo OS om 20 |0 0 | 38 G0 310 ge 3 10 0 63 | 3% OG 0 oe iiss 1G; 1 sees BS O51 8 lo oe |e So /o 227 | gs |u7/o 2 18 | go |! 3 32 as iects s 77 72 sleet Vase lee oO 10.7 1-209 G7 96 luce wo1g 6 40: (ots bea! o°'9. 1021/20) te 110 | 0.31 68. | step oh 6 7ang Siesta) len te 140 |0 19 15 | 74 017 9 | 59 | 4 oe tag ots Sagal Brg 170 10 38 a: | 225 6°56 mh fosce 190 |0 31 49 | 276 6°39 a8: fate 190 |0 35 a7 | $35 Owe 7 toes 200 |0 39 16 | $29 | 29/0 36 41 5; |e 210 |0 48 17 | S28 6: © ieee Sige Slay | [oe S| ae 240 | 0 56 82 | 588 0 62 40: | seq | Go ~ : 1 20 | go9 | 2319 57 18 | geo | 0 1th 3 ob Hie - ob 280 |1 16 54 | 328 10h hi 1s 200 | 1 22 2 | 34-6 107 | e504 ee ie | me [|i B & | St | : 128 2 370 34°6 soo (ous a et ;oee te | 988 900 | 1 Be 16: |e 1 45 5o | 368 = Ln @ me itt ee ee $70 |3 14 o | Se care oo 39'9 380 |2 21 18 ks 212 3 jot 390 |2 28 47 | {49 $0 & ne 400 |2 36 26 15/2 26 13 16 8 400-750 0 a7 - -' 4" ? a Aa a’ * 203° H 4°38 411 K 02725225 0-2547898 sy ecg BSS lid ala Bec eb ce bee DN THE CUBIC PARABOLA. TABLE III.—Continued. Radius 18 Chains. Radius 20 Chains. ' : “Difference, py | Dit ‘ S A for ; I Link. R 7 for oral R ° , ” ” ° t ” uw met OO : eros" oe : Dn Bee ore tte ee ee mio. 0 19 | 36 a Oat ae mG Os | 3. 61 0°80 7 has mie reise | 2, 6) 140 | pas @ jo sis | 5: lio 1:40 | ogg |e O10 2°55 | oes 0 2 37 os 70 10 8 58 nt O° 861 oe gio 5s 1 _ ‘to ne 9 |0 6 34 ae 0 5 58 i Meo gy | OS, (AO P88 | opel eo wi io 940 | 0. 6a | ang 1200 |0 11 41 me 0 10°88 | aug 30 |0 13 42 ra Ss Te | ee 16°ts | a4 6 1 oS | cae ; Bio -18-34 | 8?) | a0 16°88 | age | © | » 10 20 45 er 0.16087 | sua | ris 39 | Se. Gera.) See 6 eee | ito 0 23 oe Pie sie | 355 0 9°15 | see 0 | 0 32 26 0 | 35 || 0 5 oD 310 |0 35 46 | 20° jag 290 |o 39 15 | 209 pea | Soe m6 se | 3{* 6 30558 | eer 4166 a | 5 6 a | we 250 |o 50 40 | 28 | 298]/0 45 27 | O99 | 32 260 |0 54 48 24°8 0 49 #9 ‘ : 270 |0 59 6 | 28 g 16a eee 280 3 38 6.568 | wee 10 oe: : 300 |1 12 56 | 3S |oai1 5 2% | 3eg | 27 310 ww | 2 1 9-80 | Oa 820 we | le 114 % | gas 330 28 138 re i 198% ; 350 30 12 | 33°4 | 29/1 28 58 9 | 2 90 11 tw 2 | 3 cai <0 1/1 seo | 33 ime | oe 400 [2 9 | 8! | isi 06 5 rigid 400°4 1° 56' 19" 6°. 47’ 86" 331 (2024078 71 72 i C. J. MERFIELD. TABLE IV.—Four-Cuain Transition Curve VALUE OF Anete @ ror Every Ten Links ALONG CURVE. A pproximate Method.) e332 ; Radius 8 Chains. Radius 10 Chains. £ ie ee ee ee —| —| 2 oe S' OW lori tink| R | 4 fori Link| & Zes | a8o8 | ° , ” u" t o , ” “ ‘3 Ag vd oj}0 0 0] yo |e lo 0 0} of |» | Sear 1,0). Oe) Te 0 0:9 26 [Aa 20 |0 O 43 5:5 0 0 35 43 a Se Se 7 ae tae | oF 2 9 SO} 0: a gs | ee ae tae 1 mip ae lo Po. Bae oe oe ag Ke ve a ee ie ak | abo hel 9 0 | es ce eer | hee , oe ie ie ee ae (Oo 11. @ | ‘je. Aaa 18 12 | 59.9 | 82/0 14 28 : 40 | On 98 110 |0 22 1 18°2 ef) 120 0 26 251 0 17 30 19°0 | asaqts 1 te oo a | st 0 20 50 | gir Soe ae eo ae ae 0 24 87 -| Soa 2 wes | 150 [0 40 65 | 18 fog oo 33 | 282 | oy | Beas | i |0 ome | ms [7/8 ee | eo or | Sala te: 0 oe 33 38-2 0 41 48 ei Ak we 3 foo he : er 40°3 0 46 52 | 364 _ oan 210 |1 29 9 | 446 | 26) 9 57 51 | 35.5 | 20] . oBae 220 |1 97 56 | 467 , a 1 are 3 ee 230 |1 36 5 | 489 ice | SRO woe az 240'|1 44 36 | 511 eae 2 ze ee ; j 3 O80 we (h Oe a8 | eee dali 90-19 Sl ae er ao |e ma | ore | [2 8 1 St | | Bnd 0 |g ee | oes tO 8 9 oe | C8) ie ee go |a gee} re 2 18 35 be 542 s00 ke ia ae | 22 i oem 340 [3 28 42 | 716 2 | Br > Aasa 350 |3 40 57 | 735 2 46 28 | 59.0 ofa a00 | sh ne | teen 72 ae | el $228 870 (4 6 27 | 775 : = | ert Boe 380 | 4 19 79:3 5 16 4 | ps6 at 390 | 4 33 9 | 809 oe) eee S oM% 0 1a 82:3 3 12 : Ae 4652 sis 49 30 | 8 |10/ SS, ; aie - f 0 4° es tt 033 «i 24 3° Bl! 10! bd H 8°47 - K THE CUBIC PARABOLA. TABLE IV.—Continned. Radius 12 Chains. Radius 14 Chains. Ditference' i af | 8’ | ve for Link | R' 7 for 1 Link. ° ! u” " ° , | uw le 3 ol oles 8 ol es oib oo | 2. oe ms l\ecy. et 3? ere ae ye me Os. 1 8 sabe 41 ei oe a ee ae 65 jogo 2 34 ond 6 10 4 19 79 b's a 1 RE 7 |0 5 58 9°4 bss Se io: > a fee oc em oe my loro a6 |. 128 |. Les le i006 |} @:) 42 3 ce | ae ee wea ; bo (eas ee U8 | Vl ecas Boe 10 10 17 19 | 166 pits ae toe 130 |0 20 19 | 180 oeny, ge | eee 140 0 23 33 19°4 i 0 20 16°6 150 |0 27 2 | 209 | s2i0 23 ts 160 |o0 30 46 | 224 |o 26 19 170 |0 34 44 | 238 lp as ee 180 |0 38 56 | 222 lovms & | ote 1909 |0 43 93 | 267 lV ocay oy eee 900 |o 48 4 | 2) |oslo 41 7 |. Sop no |o 52 69 | 275 |” |o 45 20 | See wo togs 9 | 8° | lego 2.1 20 |12 3 a3 | 824 | lo ne oo | 227 oy lacce ty | S88 1. Sore me [fee Gor tava es (SO Tyg ace oe bee 260. }a-9) io 38% | backs ae oes s70 faee7 ay | S22 | Vase 8 826 280 |1 34 6 | 395 too a | ee 200 [2040 sp | 2? | 1 26 2 ol 300 | 47 58 | 423 |ag ia 32 24 | 302 WO laces ig | OY | 1 38 39 | 325 330 |2 10 31 | #5 | 1-61 46 | a0. lace ao (oa? a ae ee 3590 |2 96 42 | 492 lyuaie 5 38 | 222 870 |2 43 46 | 519 e390 1s | “2 380 |2 52 39 | 533 pcey BB | oes 0 feo a | 88 a65 a6 one 13 1 § | ©? fils 2 8 401°1 400°8 0 3° 12! 8'' 9° 44,' 25!' x 200 200 H 5-59 4°79 pe 0-3348962 0°2866951 Cc. J. MERFIELD. TABLE IV.—Continued. Radius 15 Chains. Radius 16 Chains. * U Ditter , , | s 6 Sig ener "| Re 6 hag ig rary ° , ” a { o , u” a Cte Oo: vB ; e710. 0 0 10 |@, 0 6 pid }0 O 5 05 20 10 0 28 | 30 |0 0 52 29 : : pe a4 40 | 3:8 40 |0 1 32 ao bat pe 50 |0 2 24 2 iy0| 0. 2 15 60 |0 3 27 63 lo 3 14 59 70 | 4.48 | 7S Lae a we tt 7S 80 |0 6 | 5 : iol ig p 9-8 Oo & 45: | 9-2 10°9 0 y ellie yy 10°2 106/019 Be 1 5c, | solos 9 | ts no 10.11 99 0 10 52 am 120 | 0 13 49 | 133 12% an oT 130 |o 16 13 | 144 18% nin Gas 0S 140 |0 18 48 | 0 17 387 oo 150 |o 21 35 | 167 |apllo oti ee 20 18 ” 160 |0 24 33 | 0 23 be 170 |0 27 43 | 190 ge [328 0 25 58 : ie [ora 4 [202 0 29 tied 190 |0 34 37 | 213 0 32 ode 22:4 | piece 0 200 | 0 38 21 30 |0 35 57 23-6 21 210 10 42 17 | = 0 39 38 2200 |0 46 24 | 247 23'1 0 43 29 230 |0 50 43 | 209 10 ass pa |0 47 31 240 |0 55 18 7 edie et at sia 56 8 260 4 47 : 126 £& 27°5 270 |1 9 52 | 305 1 g | 285 ry 316 5 28 ef 280 |1 15 8 , 1 0 oe | ee 290 |1 20 35 | 327 Lois HO}? 349 | 20||1 20 48 310 32 2 9 ice ve (8S? 340 co ae | 888 po ae Hee 350 57 18 | 875 | wy ly gy | 370 370 |2 10 55 | 416 $3 gg Oe 330 |2 18 9 | 427 2 pte 390 | 2 25 21 . . 16 wf » % : 2 32 50 16 1.2.28 17 43 r; 400°72 400° : 2° $3) 22! 2° 23! 43! - 4°46 4°18 0°2674632 0: ca THE CUBIC PARABOLA. TABLE [V—Continued. Radius 18 Chains. Radius 20 Chains. @ | @ Bruel BR]. leet ee | 9 ‘ a“ “ut fo} 7 “ vy iO a One : oe) i eae | hie i : a) 11/0 0 5 Ma fs « pi 20 0 oO 19 24 ao 4 2-9 30 |0 oO 48 94 0 oO 39 3-0 40 |0 1 17 43 ae ee 3-9 56 Og CO pe «|i44/0 1 48 4-7 | 160 60 |0 2 52 6-3 0 2 35 5-6 70 |0 83 55 79 oe te 65 cai a UME a J 81 0 4 36 3 99 10 6 28 91 0 5 49 g-3 100° 0 °7 69 | 49, | 72} 0 °% Al 9-9 | 80 110 |0 9 40 110 On Bat 9:9 120 |0 11 30 120 |; 0 10 20 10:8 130 ;0 13 30 12-9 oe -4a>"'s 116 140 |0 15 39 13-9 Gan” wea 12°6 150 |0 17 58 is ||| 16 9 a4: | o 160 |0 20 26 158 9: 18. 2 14-3 170 |0 23 4 168 0 20 45 151 180 |0 25 52 7-7 0 23 16 15°9 199 |0 28 49 18-7 0 25 55 168 200 |0 31 56 19-6 | 36] 0 28 48 17-7 | 40 210 |0 35 12 20-6 0 31 40 18-5 220 |0 38 88 21-6 0 34 45 19°4 230 | 0 42 138 23-5 0 37 59 20'2 240 |0 45 58 23-4, 0 41 21 21-1 250 |0 49 52 244 | 29||0 44 52 sig | Of 260 |0 53 56 5-4 0:48 St 29-8 270 |0 58 10 26:3 0 52 19 23-7 280 } 1° 2 38 27-9 0 56 16 24-6 290 | 1 7.6 28:9 1 21 25-4 800 |1 11 47 29-1 | 24 || 2 35 aa ee 310 | 1 16 38 30'1 1 57 27-0 320 | 1 21 39 31-0 1 2837 27-9 330 1 26 49 31-9 : is 6 38-8 340 | 1 32 8 32-9 1 22 54 29'6 350 | 1 37 387 33-8 | 20| 1 27 50 305 | 23 360 | 1 43 15 : 1 32 55 : 370 | 1 348 313 Oe | 957 1 38 8 | 391 380 | 1 55 0O é 1 48 29 0 We cg | 368 1s @o | = 37°5 33°38 400 12 7 21 18 || 1 54 37 20 J aera eteetiesnee pe soos mecca s 400° 6 2° 7! 40!! 1° 54! 50! x 200 200 H 372 3°34 ee Sd 0-2226820 0:2003348 Cc. J. MERFIELD. TABLE V.—Va.vues or Loe *m.”’ ee MEER SAR OW HOODIATHWL bs) (Argument R and z.) |z=4|e=3|e=2|e=1) | 89699750 642285 ehh 8°6303900 509871 | 8°5295623 80157325 : ie 1686 7197 8 thd 7°76585. "028: , 7026316. 7 8099861 pit 6489271 | 7°7602863 | 7-9275024 oe 76761475 75222665 | 7639761 748769 60680: Ls 7°57538197 7 76019691 | 7-7160541 3 TABLE VI.—«=4 CHaltiy Dist. in| Log Cube of Chains, 10 Log 84 a Distance. | of Distam F "51938200 se : 6.0969100 | 7°39798) | 6°6251839 | 7°750128) 0000000 7: 8.00000 | 7-2907300 | 8193820), Bi Li 8 ais 777201140 496070) 900 9 8°7220939 88061 8°8851667 89596375 9-0300808 9-0969100 9:1604779 \9 9°2210881 9:2790034 | 9 VISCOSITY OF WATER BY THE EFFLUX METHOD. 17 Tue HISTORY, THEORY, anp DETERMINATION oF THE VISCOSITY or WATER sy tHE EFFLUX METHOD. By G. H. Kyrsps, Lecturer on Surveying, University of Sydney.. [With Plate XI] [Read before the Royal Society of N. 8. Wales, July 3, 1895.) I.—History. II.—The Theory of Efflux. III.—Determination of the Viscosity. IV.—Indications for a further Determination. I.—Hisrory. 1. The recognition of the existence of internal friction in fluids, and of its physical importance, was naturally followed by investi- gations to determine its amount. Each observer's measurements are in general, fairly consistent among themselves, but when compared with others, discrepancies are found ranging over some- what wide limits. This is true, even where the schemes of observation have been identical: where they have differed the divergence of results is very marked. In the case of water, the measure of the internal friction, expressed by the coéfficient of viscosity, has been deduced from observations of the following types, viz. of— (a) the decrement in the oscillations in U-shaped tubes : (6) the decrement in the oscillation of submerged dises : (c) the volumes of efflux from capillary tubes : (a) the decrement in the torsional oscillations about an axis of spheres filled with water : () the tangential force on the inner one of a pair of coiixial cylinders, exerted by the liquids lying between, when the outer one is rotated : (f) @ method similar to (e) the cylinders being replaced by sph In regard to the third method, (c), with which we are here more immediately concerned, it may be said, that although the 78 G. H. KNIBBS. general theory of flow in small tubes, which contributed the — formule employed in its analysis, leaves little to be desired, that of the application of important corrections to the experimental — data has been considerably improved, and the whole problem been brought more into line with rational mechanics. This, ~ less than the fact that former reductions are sometimes not entirely free from error of principle, indicates the desirableness of a more rigorous analysis of observations by the efflux method, and an inquiry as to the most suitable disposition of apparatus when accurate results are desired. It will be shown also, that to reach the highest possible degree of precision obtainable from expert mental data, corrections heretofore ignored must be considered, and that the magnitudes of corrections already recognised theory, are to some extent uncertain, so that for measurements of great precision recourse must be had to methods of observation permitting of their elimination. The manner in which this may be effected will be illustrated, and a new reduction of the numer- ous observations will be undertaken, in which so far as the data permit, all the necessary corrections will be made. 2. History and Literature.—The recognition of the importance of a measurement of the viscosity of water seems to have originated in the practical requirements of hydraulicians ; the efforts of Mariotte,! Guglielmini, Daniel Bernouilli,? Couplet,? D’Alembert,’ Bossut,> and Dubuat,® to establish a satisfactory theory of the flow of water compelled their attention to the subject. Prony’ expresses 1 Traité du mouvement des eaux—Paris, 1686, * Theoria nova de motu aquarum per canales quécunque fluentes.— pes St. Petersbourg, 1726. echerches sur le mouvement des eaux.—Hist. Acad. roy. des — Poco 1783. ssai sur la résistance des fluides, 1752. 5 Traité élémentaire d’hydrodynamique—Paris, 1775; and Nouvelles expériences sur la resistance des fluides, 1777. § Principes @’ hydraulique, verifiés pair un grand nombre d’ expériences+ —Paris, 1779. 7 Recherches physico-mathématiq la théorie d arantes: —Paris, 1804. VISCOSITY OF WATBR BY THE EFFLUX METHOD. 79 his regret that Euler, who in the course of his great labours often directed his attention to physico-mathematical problems, failed to treat the theory of the motion of fluids having regard to molecular cohesion and to some sort of internal friction (quelque espéce de frottement). The first attempt to measure the viscosity of water, so far as I am aware, was Lambert’s,! about 1784, and was made by observing oscillations in U-shaped tubes. _Coulomb’s* celebrated measurements by means of oscillating discs followed about 1799 or 1800. He expressed the frictional resistance under the form au +bu*, w denoting lineal velocity and a and 6 constants depend- ing upon the physical constitution of the liquid, a form earlier employed by Newton,’ Bernoulli, and s’Gravesande* to express the resistance of the atmosphere. Coulomb practically ignored the influence of temperature in -his experiments, stating that between the limits 10° and 16° Reaum.’ its effect was insensible. Gerstner® however, had in 1798 noticed that the flow of water in small tubes varied very perceptibly with temperature, demonstrating the fact : by a series of experiments at Prague. In 1816 Girard’ continued the observation of flowin capillary tubes and deduced a formula, which however had no generality and must be regarded as errone- _ ous. Nothing in the way of experiment seems then to have been _ Made till about 1840, but it should be remembered that in this © PSS gems ye ne a a 1 Ny j ci eae : me ae relativement 4 l’hydrodynamique.—Mém. 3 ale ss! ey " . miences destinées & déterminer la cohérence des fluides et les lois tio resistance dans les mouvements trés lents.—Mém. de I’ Institut : a t. 3, Pp. 261. gp en teed au} but + cu*.—Vide the Principia Lib II. Prop. xxxt, by deere Newtonaniz Institutiones. 5 Loc. cit. p. 349. Peraturen, — die Fliissigkeit des Wassers bei verschiedenen Tem- th. p. 14] 78 dhm Gesell. der Wiss. Prag Bd. 3, phys-math. ~160, 1798 Filia 3, Mouvement des fluides dans les tubes capillaires et 188-274, température sur ce mouvement.—Mém. I’Acad. t. 1, p. 80 G. H, KNIBBS. interval Navier' published his celebrated memoir in which the theory of the motion of a viscous fluid is mathematically treated The memoir was read in January 1817 at the French Academy of Sciences. Shortly before 1835 the attention of Poiseuille? was strongly directed to the subject of venous and arterial flow, to establish the laws of which on a rational basis,’ he undertook, about 1838, a lengthy investigation of flow in capillary tubes This enabled him to correctly enunciate the law of flow for such tubes, and to furnish an expression for the efflux therefrom between the temperature limits 0° and 45° centigrade. His experiments remain, I venture to think, unrivalled even to-day, % regards their general precision. Girard’s formula previously mentioned, and Navier’s intrinsically identical therewith, bub theoretically established, were shown to be inapplicable in regard to efflux from capillaries. These researches were published in great detail in 1846, in the Mémoires des savants étrangers, and, as we shall see later on, supply material for determining the viscosity with a high degree of precision, and for testing the validity of and evaluating the constants of necessary corrections to be applied to the immediate data of any observation. Poiseuille himself did not, however, deduce the viscosity coéficient, not recognize the necessity for the corrections, and his enunciation of the law, though accurate, left the matter in the empirical stage- Before the above mentioned publication tolerably complete information had already appeared from time to time in the ‘Comptes rendus’ as to the scope and results of these researches and in April 1845, that is before the detailed results had appeared) Stokes,* in his contribution to the mathematical theory of internal iyi i eo Mémoire sur les lois du errant des fluides.—Mém. de ro Sane Coe 440, 1 2 Recherches e Rabe sur _ mouv ement des a tubes de trba.petit diiecae —Mem. des Sav. étrang. t. 9, P % Physiologists and pathologists had A * tame ous movement to blood mits iach apiegreny the power 0 a n the theories of the internal friction of fluids in motion and of ti equilicinen and motion of elastic solids,— Cambridg® Vol. 8, p. 287 - 319, 1849. Denon tl Bers VISCOSITY OF WATER BY THE EFFLUX METHOD. 81 friction, gave I believe, the first rational interpretation of the law of flow in long narrow tubes. In 1847 Moritz followed with some observations on Coulomb's! method. Seven years later (1854) Hagen” attempted a more general solution of flow in narrow tubes, following much on Gerstner’s lines. In 1858 Ludwig and Stefan* made an important contribution to the theory of this subject, but it was not until January 1860, that the viscosity coéfficient appearing in the equations of Navier was included in an exact and general formula for the efflux from tubes: it then appeared in Jacobson’s* contri- bution to haemodynamics. This furnished the results of a some- what extensive series of efflux experiments, and gave an exposition, credited to Neumann, of the theory of flow in cylindrical tubes of circular section. The date of the first publication of this expo- sition I have not been able to ascertain, but it must have been prior to 1860. It contained an accurate and complete deduction of the law of velocity in a right circular cylinder, on the assump- tion of a velocity at the boundary of the liquid ; employed terms to represent the internal friction and that at the boundary ; and showed that when the boundary velocity was zero Poiseuille’s law was obtained. It dealt moreover with the fall in pressure at the entrance to a tube, basing the formula for its amount on Newton’s value for the coéfficient of flow for short cylindrical adjutages. It is also worthy of remark that the viscosity is expressed in the absolute system in Jacobson’s treatise, and that he experimentally showed that the law held for larger tubes than were used by _ Poiseuille, OEE EEN a 1 Einige Bemerkungen iiber Coulomb’s Verfahren, die Cohiision der lissigkeiten zu bestimmen.—Pogz. Annalen. Bd. 70, p. 74—85, 1847. 2 Ueber die Bewegung des Wassers in ges cy ee Rohren.— Abhandl. d konigl. Akad. d Wiss. zu Berlin, 1 ichtung ausiibt.—Sitzber. Akad. Wien., Bd. 32, p. 25 - 42, 1858. bate zur Haemodynamik.—Archiv fiir Anat. und Physiol. 1860, * Vortriige itber Hydrodynamik. F—July 3, 1895, 82 G. H. KNIBBS, Hagenbach’s! memoir was published in March 1860. He deduced the general formula for flow in indefinitely long narrow tubes of circular section, in which the velocity is zero at the sides | of the tubes, and considered the fall of pressure occurring at the | entrance of the tube, for which he furnished a formula. This | formula, though somewhat inexact, has been used for correcting observed differences of pressures, at the tube terminals, by nearly all subsequent observers. Almost contemporaneously with Hagenbach’s memoir, the date : of publication being but one month later, the results of Helmholtz’ and Piotrowski’s? researches appeared, the latter dealing with the | experimental, and the former with the theoretical side of the subject. In their joint memoir Helmholtz developed an expression for flow in narrow tubes of circular section intrinsically identical | as regards its first term with Hagenbach’s, but containing 1 addition a second term representing the influence of friction ab j the boundary of the flowing liquid. This Helmholtz and his : colleague deemed necessary in a complete formula, in view of the fact that their experiments pointed to the existence of a relative movement and’ consequent frictional effect at the boundary com mon to the liquid and the containing vessel, at any rate as betweel a polished gilt surface and water, and their formula is substantially identical with the earlier formule of Neumann or J acobsom Neither Hagenbach wor Helmholtz refer to any earlier corte expression for steady rectilinear motion in pipes of circular sectio! and it is somewhat remarkable that it is generally credited tot latter, although so far as I can ascertain, Stokes, Neumann, Hagenbach all have a prior claim to this credit. A second 4 very valuable discussion by Jacobson? of the theory of rectilineat flow and evaluation of viscosity was communicated in Septe”t ay Ueber die Bestimmung der Zihigkeit einer Fliissigkeit durch de? Ausfluss aus Rohren. —Pogg. Annal. Bd. 109, p. 384 — 426, 1860. * Ueber prise. sesganiel Flissigkeiten—Sitzber. k. k- aia ‘Wien., Bd. 40 sag 3 Zur Bialng in die a anena —Archiv. fiir Anat. und Page| a 1861, p. 304 - VISCOSITY OF WATER BY THE EFFLUX METHOD. 83 1860 to a meeting of physicists at Kénigsberg, and in this the results of measurements of efflux for temperatures up to 71°5 a were given. Magnus? experiments in 1850 and 1855 should perhaps have been mentioned as affording physical illustrations of viscosity ; they contributed however nothing of moment in regard to its numerical evaluation. At this period the general significance and importance of the viscous property of fluids was forcing itself strongly upon the attention of physicists, particularly perhaps in the direction of chemical physics, and in 1861 Graham’s* essay appeared “On liquid transpiration in regard to chemical compo- sition,” an early contribution in that department of research. Graham’s work is of interest to our present purpose mainly because in his measurements of flow through capillary tubes he also greatly extended the range of temperature beyond Poiseuille’s limits, carrying it as far as 70° C.—i.e. 25° beyond Poiseuille— and also because he made measurements for every degree up to 5°. Had his experiments been more accurate they would have afforded an opportunity of examining whether the mathematical expression of the law of viscosity showed any peculiarity at the temperature of maximum density. a the same year (1861) Meyer's’ first contribution to the theory : of internal flnid friction, and to experimental research therein, Was published. Seven years later (1868) at Bonn, Rellstab’s* dissertation on the transpiration of similar fluids traversed the subj oa ject, and gave also the results of some new measurements by i ee 1 - ong die Bewegung der Fliissigkeiten.—Pogg. Annal. Bd. 89, p ca "§ eg Hydraulische Untersuchungen.—Pogg. Annal. on i OD. a : gem Roy. Soc. Lond., Vol. 151, p. 373 - 886, 1861. e ‘sie die Reibung fed siovear ets (Theoretischer Teil). —Crelle é ‘s ay h. Bd. 59, p 1861, and ee title, Pogg. Annal. Bd. tu 86, ie: oo are 383 - 245, ber die ce homologer eg —tnaagucadioser ah 84 G. H. KNIBBS. the efflux method. In 1876 Sprung! made a series of experiments 5 with water in connection with his physico-chemical resent The following year Meyer communicated the results of ie cranz’s? observations, the latter having died at Breslau in Febru ; of that year, i.e. in 1877. Rosencranz’s investigation, ce which | measurements up to 90° C. were made, had for its object tt extension of the values of the viscosity coéfficient beyond Poiseuille | limits, with the view of ascertaining how far Poiseuille’s formtly ) accurately expressing the effect of temperature under a 7 algebraic form, could be safely extrapolated. a The viscosity research in the department of chemical alas | was continued by P¥ibram and Handl? in 1878 and 1879, s08¥am Grotrian* in 1879, the latter furnishing further observations y the efflux method, and drawing attention to an analogy aie 7 fluidity and electric conductivity. Slotte® in 1881, and. Wag? ] in 1883, the latter continuing a line of physico-chemical research commenced by him in 1876, both supply efflux measurements foe 3 : : ; ‘ corte eas intern | water made in connection with their investigation of the 1 : frictions of chemical solutions. In the year last mentioned, Reynolds’? demonstrated afresh : 7 the law of flow in capillary tubes held also for larger tubes, provi 4 Oe ee | Experimentelle Untersuchungen iiber die Flissigkeitsreibums © Salzlosungen, Bd. 159, p. 1- 35 Meyer.—Wied. Annal. Bd, 2, p. 387-406, 1877. ? $ Ueber die specifische Zahigkeit der Fliissigkeiten und ihre Bezieb" zur chemische Constitution.—Sitzber. k. k. Akad. Wien. Bd. 78, AP p. 113 - 164, 1878, and Bd. 80, Abt. 2, p. 17 - 57, 1879. * Analogien zwischen der Fluiditit und dem galvanischen Lett™’ vermigen.— Wied. Annal ; 29 — 554, 1879 5 Ueber die innere Reibung der Lisungen einiger Chromate.—W* Annal. Bd. 14, p. 13 — 22, 1881. 6 Ueber die Zihigkeit von Salzlésungen.—Wied. Annal. Bd. * : 259 - 289, 1883 7 An experimental investigation &c., &c., and of the law of resistal™ in parallel channels.—Phil. Trans. Vol. 174, p. 935, 1883. VISCOSITY OF WATER BY THE EFFLUX METHOD. 85 the velocities were sufficiently small. He was under the impress- ion that this had not already been done, but as previously pointed out Jacobson had anticipated him. Although Reynolds’ experi- ments are not suitable for the derivation of an exact value for viscosity, it may be observed that his results are consistent with Poiseuille’s. In 1884, Réntgen' and Warburg and Sachs’ examined the influence of pressure and density upon this coéfficient and the year following Kénig® ascertained that there was no sensible difference in the time of efflux when it took place in a powerful magnetic or electric field. He made some further measurements* in 1887 but not by the efflux method. The next important contribution is Couette’s® whose experiments embrace two methods, viz. that of measuring the tangential force on an internal cylinder exerted by liquids lying between it and a coaxial outer rotated cylinder—method (e)—and that of efflux (¢). In regard to the latter it may be said that he considerably advanced the theory of the correction of the pressures registered by the manometers in the vessels at the terminals of the tubes, and indicated a method of observation by which the corrections may be entirely eliminated. Couette’s correction for the fall of pressure at the entrance of the capillary, though more exact than Hagen- bach’s 8 (1860), and very much more exact than Reynold’s s (1883) i evenetroted hy Bonstinesn’ in 1891 to be true sr “pig Einfluss des Druckes auf = ——, der Fliissigkeiten, —Wied. Annal. Bd. 22, p. 510-518, 1884. Ueber den Ristiks der Dichtigeit si ae Vinsostt tropfb Flunigte pfbarer ote iten.— Wied. Annal. Bd. 22, p vee ok einiger Reibu Sait HT rad View tiber den |-Plissigk, sas Magne tisirung und Electri: rey! auf die Reibung der eee oy 0 eee al. Bd. 25, p. 618 — 625, 1885. : bien mi ung v n Reibungscoéfiicienten tropfbarer Fliissig- : mittelet de Sateanes Schwingungen.— Wied. Annal. Bd. 32, p. 193 vat eee me SS de liquides.—Annal. de Chim. et de Physique § Su tireulaine " sais oe a iteesée dans un tube cylindrique de section AUX ¢ Pe aboot ’son entrée, se distribuent depuis cette entrée jusqu’ vit se trouve établi un régime uniforme.—Comptes Rendus, ; Ulaire, évasé 4 son : bl t : entrée eg qu’ un régime sensiD! emen Bement dee reese’ tt de Ia dépense d e charge qu’y dniaaine V8 établis- PA Ne Te Teste FIL Asean ee rs ae Perea Mee 86 G. H. KNIBBS. only to a first approximation: a higher approximation require that it be increased about one-eighth, and it will be shown that : Boussinesq’s theory is experimentally vindicated. In the same year (1891) Brodmann! published the results of his researches 4 with the sphere and cylinder methods—(/) and (e)—and showed | were obtained for the viscosity according to the size of the sphere or of the cylinder, confirming Elie’s? observation that values for | the viscosity deduced from experiments with concentric spheres by Kirchhoff’s formula, increased with the velocity of rotation. — In 1892 Cohen,? employing the efflux method, continued the — research in respect of the influence of pressure on the coéfiicient, 4 for the temperatures 1°, 15°, and 23° C., and for pressures up t atmospheres. His results therefore add to the material for comparison. Many other contributors either to the theory or observation of the viscosity of liquids, or cognate matters, might be mentioned~ as for example, Hiibener 1873, Baumgartner ’74, Guerout 74 and 76, Villari 76, Koch ’81, Grossmann 783, Graetz ’88, Wirtz 89, : Whetham ’90, Briickner 90 and ’91, and Rayleigh ’92—but the above sketch of the course of the investigation embraces its main historical outlines and subsequent references will be made only such of the above as especially bear upon the particular cme of any question under review. 4 Ii.—Tue Turory or Erryvux. fluid be established in a long cylindrical capillary tube, mee see 1Un ntersuchungen iiber den Reibu ungscoéfiicienten von " Fliissighe! 5 Le Gottingen, 1891,—Wied. Annal. Bd. 45, P- 1” : nee a 4 Sitzber. Akad. Wiss. Wien. Bd. 40, p. 653, 1860. VISCOSITY OF WATER BY THE EFFLUX METHOD. 87 a circle of radius R, and the pressure in a length L of the tube. fall from p, to p,, the volume q flowing in a unit of time across any right section of the tube is expressed by the equation :— T(Po—- Ps) 4 : 3 G2 aa i: (R* +46 R*) in which &? is a constant determined by the internal resistance of the fluid, b one depending on the friction at its boundary, and x is 314159 etc. In recent treatises on hydrodynamics’ the equation is usually written q = “RP (Rea 4t eee (1). y, or Helmholtz’s k?, being the coéfficient of viscosity, and B that of sliding friction. This latter form is the earlier and the better, and is essentially that deduced by Neumann some time prior to 1860. The reciprocal of the viscosity, f = 1/7, has been called the coéfficient of fluidity and 1/8 that of slipping. Limitation of the Equation of fluz.—The movements of liquids may be ciassed under two régimes, a fact clearly recognized by Darcy? in 1857, and since illustrated in a striking manner by the experiments of Reynolds? in 1883, and confirmed by those of Dometic! in 1888. In the first régime no eddies are formed, and the liquid, if limpid, has what has not inaptly been called a “plate-glass” appearance. In the second, eddies or vortices are lanes and the « sheet-glass” appearance may be noted, the ‘Tefraction of the liquid being varied by the eddies. It is to flow ‘under the first régime, that is to flow without vortices, that the 1Ki Bante oo iiber mathematische Physik (1883 edit. dit.) p. 373. reatise on Hydrodynamics, 1888 Edit. Vol. 11.,p. 305. Lamb— tp his pf or ree ike of fluids, 1879 Edit. p. 224. Lamb uses p/p for - Matical cous, ett’sy, being what has been called by Maxwell the kine- cient of viscosity, i.e. 1 /p, p denoting the density of the fluid. twa relatives au mouvement de l’eau dans les 857. See also Mém. des Savants étrangers t. 15, p. 215 go emacs Vol. 174, p. 935 - 982. de Chimie, 6 Sér. t. 21, p. 464. 88 G. H. KNIBBS. above equation applies. The physical characteristic of such a flow in a cylindrical pipe, is that the motion of all particles i parallel to its axis, and points of equal velocity lie, if the section : bea circle, in the circumference of a circle concentric therewith, the | velocity of course diminishing with increase of distance from the | axis. The liquid may therefore be imagined to be divided into a | series of coiixial circular cylinders, and the internal friction tobe the sum of the resistances exercised by each cylindrical stratum upon the interior and more rapidly moving cylinder. It is this conception, viz. that of steady rectilinear motion, which, together with the consideration of the boundary condition, leads to “ formula written. ‘4 5. Definition of Viscosity.—Navier,! in his treatise, gives an explanation rather than a definition of the meaning of 4 (€ 12 bis equations), which may be thus expressed :—If we imagine 4 ful to be divided into a series of planes parallel to some fixed plane the motion in each being identical in direction, and in velocit] ’ equal to its distance from the plane, then the constant 7 repre sents in units of weight, the resistance per unit of surface to the sliding of one stratum on another. Hagenbach’s? definition 18:— By viscosity we denote the force necessary to move with unifor | velocity and in a unit (second) of time a stratum of fluid on molecule in thickness and of unit surface, the distance of sais the latter being moreover dependent upon a particular concep?” as to the physical constitution of a fluid. The following is ptr posed as obviating these objections :—The coéfiicient of vise : expresses the ratio, per unit of surface, of the tangential resista between parallel strata of a fluid moving with different velocities to the rate of variation of their velocity measured perpendicul to the direction of movement. The resistance is ge supposed to vary as the difference of the velocity, an assump 1 Mém. Phd des Sciences, t. 6, p. 416, * Pogg. Annal. Bd. 109, p. 425. The translation is nearly literal. VISCOSITY OF WATER BY THE EFFLUX METHOD. 89 which has been experimentally justified between somewhat wide but ill-defined limits. 6. Coéfficient of sliding friction for glass and other tubes.— Navier assumed that a flowing liquid would glide or slip with a finite velocity at its bounding surface, and Piotrowski’s experi- ments—by method (d) § 1—interpreted by Helmholtz,” confirmed this view to a limited extent, for although there was no slipping in the case of ether and alcohol in contact with polished gilt surfaces, with water and some other liquids slipping apparently occurred, and values for the coéfficient were deduced.® Piotrowski’s experiments did not include cases of flow through tubes under pressure, but Helmholtz, after developing the theory of Piotrowski’s method, turned his attention thereto, and deduced the formula to which we have already referred. He concluded from an examina- tion of Girard’s observations that sliding friction, the assumed existence of which seemed to explain Piotrowski’s results, must also be postulated in the case of flow through tubes, at any rate when their dimensions were somewhat larger than those used by Poiseuille, and when they were of copper instead of glass. He further deduced a value for his coéfficient 6—in our first equation —by applying the formula on the assumption that the motion might be deemed steady.* The legitimacy of these conclusions was questioned by Whetham in 18905 who judged, from his experiments by an efflux method, that no slip occurs, at any rate in the case of surfaces which are wetted by the liquid. But Brodmann—in 1892—has demon- _ Strated, I think beyond doubt, that water in contact with a gilt surface does not adhere thereto and that under such circumstances ‘siege oC eae na kes aa BBE SE ge ee eee a ree ne a L Mém. de l’ Académie, t. 6, p. 389. * Sitzber. Akad. Wien., Bd. 40, p. 607 - 658. 3 Loc. cit., p. 621. * Thid, p. 656, where = b in the equation previously given. 5 On the alleged slipping at the boundary of a liquid in motion. Trans., Vol. 181, p. 559. * Thid, p. 582. —Phil. 90 G. H. KNIBBS. slipping does occur, so that Whetham’s conclusion must ie restricted. That it occurs in cases of flow in glass tubes hag certainly not been shown, but in regard to copper tubes the inter- — pretation of Girard’s experiments seemed to require that slipping be postulated,” and it is somewhat singular that a recent deter — mination by Brodmann of the value of 7/8 for water by the sphere and cylinder methods gives a result?—7/ = 0- 0409-—very nearly identical with Helmholtz’s value‘ = 0:03984—deduced from : the efflux observations of Girard. On the other hand it has Be ; pointed out by Jacobson that Helmholtz in criticising Girard’s experiments failed to apply any correction to the pressure, and : that his own—Jacobson’s—experiments with copper tubes lend 1 no support to the opinion that slipping occurs.6 The general theory of flow in tubes being however beyond the scope of this 4 discussion, it will suffice to show that Helmholtz’s view is unsup | ported by experimental results in cases of steady rectilinear * in glass tubes, such as are used in observations of efflux having for their object the determination of the viscosity. If we put . _ TP - pps 1) 2 anda = 46 = te then we shall have from Be by transposition, 7 = m (1+ =) the term a/R depending on the existence and influence of sliding | friction, so that, if the viscosity be computed without reference? thereto, we shall obtain the results 7» instead of », and these will: 4 show a variation with widely different values of /, since ais constant. From the results hereinafter quoted, obtained from Poiseuilles experiments on the assumption that slipping does not occur WO 1 Wied. Annal. Bd. 45, p. 184. oie | 2 As against this view see Couette’s memoir Annal. de Chimie, 6 9% : t. 21, 1890, p. 492 - 494, : ' § Wied. Annal. Bd. 45, p. 179. * Sitzber. Wien. Akad. Bd. 40 40, p. 656. 5 Achiv. fiir Anat. u. Phys., 1861, p. 306. VISCOSITY OF WATER BY THE EFFLUX METHOD. 91 take the mean values for Poiseuille’s tubes the ratio of whose radii varies between the limits 1 and 47. Glass Tubes. Meanof. Rapprox.c.m. 4,at10°C. Authority. M M, (2) 0007 01313 Poiseuille EE, (2) 0015 01341 do D-D, (4) 0022 01305 do C-C, (4) 0042 01308 do. B-B, (4) 0056 01310 do A-A, (4) 0071 01308 do F-F, 3) 0326 01315 do The constancy of 1, shows that it must be supposed identical with 7, that is to say @ is zero for cases of efflux through glass tubes, as indeed is admitted by Helmholtz.1 Nor does a more extended comparison of values similarly deduced lead to a different con- clusion. In the table hereunder tubes of different materials are included, and of larger radius, that of the greatest being 907 times that of tube M above. Tube. No. Expts. Rapprox.c.m. 7 at 10°C. Authority.” Glass 1 0140 01400 _Hagenbach ” 0172 701320 Grotrian D 0182 01318 ‘ ; 2 Q198 01311 Konig 3 0199 01291 ‘ ss 4 0290 01331 Slotte Copper 2 0297 01356 Couette Glass 4 0302 01319 Wagner z 1 0309 01400 Hagenbach White metal 3 0504 01341 Couette Inge 1 “0525 01324 Hagenbach m 1 0550 01287 ‘s Paraffine 3 0685 01360 Couette Sait On ee eee 1 Sitzber. Wien. Acad. Bd. 40, p. 654. 2 These values I have reduced from the data published by the investi- gator whose name is appended. The same remark applies to the preced- "2 values obtained from Poiseuille’s experiments. 92 G. H. KNIBBS. Tube. No. Expts. Rapprox.c.m. 7 at 10°C. Authority. Glass 8 ‘0877 01323 Jacobson 5 1147 01334 ” Brass Z 1433 ‘01313 ‘y Lead 8 3075 01360 Reynolds : 8 6350 01365 . These results give no indication of slip, for though the final — value is somewhat larger than the mean, the difference is infini- tesimal in relation to the supposed magnitude of the slip cosfiicient.’ It may be remarked that Coulomb’s experiments also appeared to indicate an adhesion of the liquids to the submerged oscillating discs,’ and that despite considerable alteration in the nature of the substances with which they were covered: so also did Meyer's But what is more to the point, is that when the motion is undoubtedly steady and rectilinear, all experiments by the efflux method with glass tubes—and it appears from the above that there — is but a doubtful necessity even for this qualification—agreé in negativing the idea of slip, not only in the case of water which wets the tube, but also in the case of mercury which does not. The observations of Warburg,‘ Villari,> and Koch® on the efflux of this latter substance, may be taken as determining the question of slip in regard thereto in the negative, and a fortiori in the cas? : 1 Taking the values for tube M and for the largest lead tube, in ordet to caleulate the supposed slip, we would obtain for 7, ‘0136 5+ and for 8, 1 This is sensibly infinite as compared with its value in Helmholtz s. remo ih preies to that authority n/B is 03984, whereas ly -00000' pias in en several values of 7 may be hig On eines” for. 2 Mém. l'Institut National, t. 3 a ee die Reibung der eld seks —Pogg. Annal., Bd. 113, P- e * Ueber den Ausfluss des Quecksilbers aus gliisernen Capillarrébrea— Fogg. Annal. Bd. 140, p. 367 — 379, 1870. 5 Sull ’efflusso = as per tubi di vetro di —— diametro— Mem. dell ’Accad. d. Sci., Bologna, Ser. 3, t. 6, p- 1 ° Ueber die Abhingigkeit der Si abeniante. he Quecksilbers = der Temperatur.—Wied. Annal. Bd. 14, p- 1 - 12, 1881. ail oe er Sate = ie Sis a ig EGE AO, Se VISCOSITY OF WATER BY THE EFFLUX METHOD. 93 of water. But apart from such theoretical deductions from experiments, it may be noticed that the strong adhesion of the bounding film to the tube was visually demonstrated in the experiments of Duclaux.!_ We may therefore in dealing with the theory of flow in glass capillary tubes, when the motion is recti- linear confidently assume that the coéfficient 8 in equation (1) is infinite—or in other words that there is no slip—that the velocity at the boundary of the section is consequently zero, and that the term in &* vanishes, and this assumption will generally be correct for any tube whatsoever for steady rectilinear flow. LT. The reduced equation of flua.—Denoting by P’ the difference* Po —Px, the original equation (1) becomes for zero velocity at the boundary a formula first given by Neumann, then by Jacobson, Hagenbach,* and Helmholtz. If K be substituted for x/(2'y) and D the diameter for R the radius, Poiseuille’s formula*— inca! “te derived experimentally about 1840, is obtained. The earlier formule viz. Girard’s (1813), and Navier’s (1822) were erroneous, making the efflux proportional to the third instead of the fourth power of the diameter. 8. The determination of the fall in presswre.—In large tubes, in which flow is established, the fall in pressure due to viscosity or other resistances between two cross sections any distance apart, may be measured manometrically, or by observing the vertical 1 Recherches sur les lois des mouvements des liquides dans les espaces capillaires.—Annal. de Chimie, 4 Sér. t. 25, 1872 ? We use P’ instead of P as the latter is hereinafter used to denote a Pressure directly observed but subject to certain corrections. 3 Pogg. Annal. 109, i ‘a is p. 397, 400, 401. In our notation ' = 7/9 Hagenbach’s k/n o * Com; hina t. 11, p. 1046, 1840. Mem. des Savants étrang. t.9, cara The relations of K, P » for arbitrary or for absolute units are to hereafter: here we regard only the form of the expression. 94 G. H. KNIBBS. height to which the liquid will rise in tubes attached normally to” the surface of the pipe,! the connecting orifices being very small _ in relation to the sectional area of the flow. Such an arrange ment cannot be realized with capillary tubes so that the fall in pressure must be deduced from measures of the pressures in the — reservoirs supplying and receiving the flowing liquid. The sectional areas of these should be, and will be assumed to be, very large in relation to the sectional area of the capillary. 3 In Fig. 1, in which A denotes the supplying and B the receiving reservoir—i.e. the flow being supposed to take place in'the direc tion A B—the points A and Blie in the axis of the tube ZH’ FP, supposed horizontal ; to these points the measures of the pressures in the reservoirs are referred, P being the difference of those pressures. It is immediately evident from the principle of col servation of energy, that, neglecting losses from frictional resis tances, the pressure at the section ee’ where the régime of parallelism of flow is established, is less than the pressure in the reservoir A, owing to the change from potential to kinetic energy in the effluent liquid. This was not overlooked either by J acobson or by Hagenbach as already pointed out. The latter divided the head, or charge as it is often called, as measured by the difference of pressures, and expended in overcoming resistance into two' parts, the velocity-head (Geschwindigkeitshéhe) and the head due to frictional resistance within the tube (Widerstandhihe). Hagenbach’s formula? may be written, if we adopt an absolute notation, or C.G.S. units? } 1 This is a called the piezometric measurement of the prewar by hydraulici 2 Pogg. ‘ear Bd. 109, p. 408, 1860. * Using C.G.8. units we shall express P in dynes per square centime thus P= pg, if p be the pressure in grammes per square centimetre, and the unit o ntly in dessin the prunmaea the portalatios ¢ tiles of | the viscosity 7 me erred to the above by the equation 7’ = yig- The absence of the § term in the quotation of Hagenbach’s equation is thus explained. VISCOSITY OF WATER BY THE.EFFLUX METHOD. 95 1 93 7? ia 5 seed p g” Q's « L q p being the absolute density—grammes per cubic centimetre—of 1) oles the effluent. This will more clearly exhibit the reduction of the pressure if put in the form ay a { Pe | Shel” (ka: RK) so that the term in brackets denotes, according to Hagenbach, what might be called the reduced pressure,! say P,. Hagenbach justly observed that this correction more particularly applied where the end of the tube is in the form of a conoidal adjutage. Since we propose to consider the value of the coéfficient of the correction, the reduced pressure P, may with greater generality be written— PG Py £22 (3) T According therefore to Hagenbach the value of the factor m for @ conoidal terminal is, m = 2-5 = 0-79370 ‘ Reynolds,’ remarking that Poiseuille, though he measured the _ pressures in the vessels supplying and receiving the flowing liquid, -“hevertheless neglected the correction, states that, if U denote the Mean velocity in the pipe and g the acceleration of gravity, it will ~ either U* (2g) or 1-505 U? /(2g) according as the entrance ; pemial of the tube is trumpet-shaped or cylindrical. He also ys that, as Poiseuille definitely affirmed the latter condition to v5 been realized in his experiments,? the application of the “orrection would have made them consistent,' a dictum however Se —— It is hereinafter show n that Po, may be generally supposed to be ; (2), but that this su ition may be set aside b — evidences of its : 7 . y ; a ’s treatise, p. 439. La soudure est faite de telle sorte avee du + utube D (the capillary) se dilatant ex abrupto, est en rapport enflement G (a bulb at the end of the tube forming the reservoir _ fIse ct, p. 981, 96 G. H. KNIBBS. which must be received with considerable limitation. Reynolds 3 proposed correction is evidently based on the results of experi ments with sharp-edged cylindrical adjutages of 2 or 3 diameters | length applied to orifices, the effect of which is to cause a discharge _ of about 0°815 of that theoretically due to the pressure on the | supposition that frictional and other resistances may be’ neglected. This loss of head, arising from the contraction! at the entrance dt the adjutage, and the subsequent expansion to its full diameter, | together with the loss from slight frictional resistance and that involved in establishing the flow, gives according to treatises practical hydraulics U?/[2g (0:815)?] = 1-506 U2/(2g). Tf the edges of the cylinder be rounded off at the connection with the discharging vessel at Z’, Fig. 1, the value becomes very nearly | U? |(2g), the coéfficient 0-815 increasing almost to unity, a according therefore to Reynolds, for the condition assumed by Hagenbath, m=0-500, or for the reduction of Poiseuille’s work m= 753. This statement is not justified hy an analysis of the experiments referred to. The objection to unconditionally assuming that ~ Square of the mean velocity in the section may be regarded a | equivalent to the mean of the squares of the velocities at diferet points throughout the section, in estimating the loss of necessary to establish flow, is obvious. Couette,” treating the problem more exactly, deduced for m the value unity, obse that it is just double that obtained by the application of Da Bernoulli’s theorem, which attributed to all the molecules of fluid a velocity equal to the mean velocity. He proposed tn fore the more rigorous formula P,=P 5, This had eae previously given under another form by Jace Bienes Kirchhoff’s Vorlesungen (22nd) for a solution in two dimens his treatise on Hydrodynamics, Vol. 1, p. 139. - solution of the problem in three dimensions exists so far as he was 8” afapand whi —_ by Boussinesq in 1872, see his “‘ Essai sur la™ : courantes.”—Mém, des Savants étrangers, t. 23, p- 562, } Annal. de Chimie, 6 sér. t. 21, chap. iii., p. 494, 1890. VISCOSITY OF WATER BY THE EFFLUX METHOD. 97 in September 1860, in his Introduction to Hemodynamics, the development being credited, as I have previously said, to Neumann, whose formula may be written in our notation,’ m however being assigned the value unity, gh = mU*+ 8 7 OR h denoting the pressure at die entrance to the tube expressed as height of a column of liquid of the same density as the effluent, and U the mean velocity in the transverse section. Couette was evidently unacquainted with Neumann’s or J acobson’s work, but in this respect he is not singular.” Boussinesq? has attacked the problem with greater rigour, and —while admitting that Couette’s solution, which is the same as Neumann’s, is legitimately derived, and to a first approximation is accurate—shews that a higher approximation gives for m the value 1:12. Thus according to the several authorities mentioned, m = 0:50 Reynolds (after Bernoulli) 1883 m = 0°79 Hagenbach oe ... 1860 m = 1:00 Neumann prior to ... 1860 m = 1:00 Couette ... ies ... 1890 m = 1-12 Boussinesq Kae “4 nee Poiseuille’s series of measurements, at different pressures and at 10° C., for a number of tubes afford a means of ascertaining the value of this coéfficient for each series : and it may be remarked that, a priori, one would expect the deduced values, if not identical with, to be somewhat greater than Boussinesq’s coéfiicient, inas- much as it is said that the tubes retaining their cylindrical form a eee : } Archiv. fur Anat. und Phys. Reichert’s, 1861, p. 321. Jn the original — both sides of this equation is multiplied by 2. That Hagenbach’s correction should have been so invariably used, is ‘in itself an indication of how little is generally known of Neumann’s fine exposition of the theory of flow in a tube. rere Rendus, t. 110, p. 1160—1166, et p. 1238 - 1242, 1890. Ibid 18, p. 9-15 et p, 49 ect. 1801. ‘Théorie du régime permanent gradu- filets varié qui se produit prés de l’entrée évasée d’un tube fin ot les @un liquide qui s’y écoule n’ont pas encore me lour inégalités. Bormales de vitesse, etc, G—July 3, 1896, 98 G. H. KNIBBS. throughout, terminated abruptly, and in such cases the resistances are greater. Poiseuille in each series, measured the time necessary for a certain volume to flow at different pressures. If this volume be denoted by Q, and the total efflux time by 7, gin the preceding formuls—being the volume per unit of time—is equal to Q/T for each pressure. Hence m denoting general value of the coéfiicient, i.e. 1°12 theoretically, and supposing that the value P, in (3) may be substituted for P’ in (2), we obtain the following expression for the viscosity, viz. 4 In this formula Q/7' may be substituted for q, that is we may write 7’ in the numerator, and @ instead of qg in the denominator, and in this way may obtain by transformation an expression for what may be called the corrected time of total efflux, viz. oe a OTe x | eee Pate : C=P,T=PT, =Pii mee pe A very large number of experiments have been corrected, as bela stated, by means of the equivalent of formula (5), Hagenbachs value for m however being used. The time 7’, is the total efflas time, when the loss of head at the entrance to the tube divided © the product of the pressure into the time is negligible, and equa tion (6) shews that we may correct either the pressures, OF os times. Reverting to Poiseuille’s work, if the pressures in a, series of observations made at a uniform temperature with the one tube, be multiplied by the corresponding times of efflux, the series © products P7' is obtained, which, since the right hand member a (6) under the supposed conditions is a constant, differ only by ye 1 See also formula (40) § 21 hereinafter. . 2 For the calculation of 79 when Q is unknown see § 21, formula (43). a TES rea eres ee Wwe have from (6) VISCOSITY OF WATER BY THE EFFLUX METHOD. 99 corrective term whose factor is 1/7, the other part being also a constant. Hence (6) may be written Coro (6a). y a To determine C, the number must be found towards which PZ’ approaches when 7’ is increased without limit, and therefore P diminished without limit. The equation PT =C+—7 (6b). is that of a straight line, such that if the several values of 1/7’ be regarded as abscisse and the corresponding values of PT as ordinates, the line passing through the points so determined will intersect the axis of ordinates at the distance C from the origin, and make with the axis of abscisse an angle whose tangent is ¢. This value C corresponds io the value 1/7’=9, or T=, the corrective term therefore vanishing.| Fig. 2 shews the plot for Poiseuille’s tubes A, A, B, and C;. Should the products PT shew no progressive increase, as is sometimes the case,” no value can be assigned to c, nor consequently to m, for, when c is found, m is determined from (6) and (6a) by the equation m= 6 ae ia ree (7) for absolute units. If the pressures be ees by the lengths in centimetres of the columns of liquid in the manometers, h, it will be generally convenient to form the products h 7’ instead of PT. Let » denote the density in grammes per cubic centimetre of the liquid in the manometers, and g the acceleration of gravity in centimetres per second, then from the relation P=pg = phg ae fe ig! Ae ig ae -as-(8) : 4 no + and writing 3 idee gh Me, ae 1 Ao a zero when 1/T = 0, or T= %. £0 great es of the members of the series may be, and often are, ee obliterate, as it were, all evidence of the progression. — 100 G. H. KNIBBS. in which therefore c’ =c/(ug), we obtain 4 m=c B gee: (9) If the density of the liquid in the manometers (2) be identical with that of the effluent liquid (p), /p will be unity. ; By formula (8a) and (9), I have ascertained where possible, the values of m from Poiseuille’s measurements with tubes A tof — Those given hereunder are derived from a combination of numerical — and graphic methods. Through the points whose codrdinates 1/7 and P 7' were drived from Poiseuille’s series, as for example, the ” series A,, A;, B;, C;, shewn in Fig. 2, a mean line was drawn. — Two members of the series most nearly agreeing with this line were usually then selected and the values of ¢ and C found by the formule Se Fa kale a0 ~~ C=P,T, - 7 (11) When for each tube designated by the one letter as Ay, 4s, c — been determined, its multiplication by the fractional fact in (9)—a constant for the tubes so designated—gave the values of i m. The radius used was not the mean for the whole tube but tht mean radius’ at it entrance. ' Values of m deduced from Poiseuille’s experiments. Length i Leng abe, Mengt Madina) Valnon ing, Length Satan | A, 255 00708 104 3B, ‘39 00567 i yes S 5 102 C, 60 00427 Pera Ppa e 115 F, 20:00 -03267 : ie eee Ay AO Tk LR Ol ee Fig ke 8 re y, Pgeaee F, 0 Mean 1-14 : ad rejecting C.P.,P. 113 : eager t 1 Actually h,c' and C’ were used. Thus in (10) c’ replaced c, and hyP : In (11) C', hh and ¢' replaced C, P and c. . greatest and least radii. If the section be truly an ellipse the ™ radius so defined will be that of a circle of equal area. ; VISCOSITY OF WATER BY THE EFFLUX METHOD. 101 Tubes A, and A,, B, to Bs, C to C,, D, to Dy, H to L,, and F give no satisfactory indication as to the value of this factor, For tubes A and D the following results were obtained, viz., 0-4 or 0:5, and 1-2, these values however are entitled to but little con- fidence inasmuch as they depend on lines the directions of which are determined by the positions of three points only, two of these being close together so far as the abscisse are concerned, but in regard to the ordinates, not sufficiently concordant to warrant confidence. For tubes A, and B the results depend respectively on 2 and 3 points: in the other cases on from 7 to 10. It is difficult to assign a reason for the values 0°82 for /’, and F; ; possibly the flow was turbulent ; the values for the viscosity —see the table hereafter—point to that. But one would have expected that A, would also have given similar indications, which it does not excepting for the last member of the series. The value is of course that for the fall of pressure known to occur in efflux through a short adjutage. The value for C’, may perhaps be accounted for by the presence of a particle at the entrance of the tube interfering with the flow. The general result however agrees remarkably well with Boussinesq’s deduction from kinetic theory, and since in the instances of some of the tubes showing discordant values the amounts of the corrections are much smaller than the discrepancies among the observations themselves, no doubt need be entertained as to the propriety of its application where there is no evidence of the particular value of m. It may here be noticed that in illustrating his theory of the Correction to the pressure Couette selects series A, and A, to exhibit the advantage of his formula over Hagenbach’s'. For these tubes m is respectively 1-02 and 1-08. For the former the factor is sensibly unity and therefore the agreement with Couette’s wealt is Satisfactory ; in regard to the latter the progressive merease of the corrected values of » is clearly a consequence of the fact, that the correction factor is too small. This leads me DUO eos ce ee 1 Annal. de Chimie, 6 sér. t. 21, p. 502, 1890. 102 G. H. KNIBBS. to remark that this correction must be not only well ascertained | but also small, for accurate measurements of viscosity, since there is ample evidence that it is variable in amount even under con ditions where one would anticipate constancy. In illustration of this we take for data the results of several series of measurements of pressure-heads and velocities at constant temperatures made by Jacobson,' with his brass tube C, whose radius and lengths were respectively 0-14328, 62-04, and 15-76 c.m., and which was so fitted that its influx terminal was flush with the inner surface of the large reservoir which supplied the effluent.?2. For measure ments of pressure-head and mean ae | we have, sinceU/ = q/(7# E — ater fi in which c’ =8 ZL n/(pg R?), and is oes constant while the temperature is so. The value of m was found by the graphic method, the above being a linear equation.’ Values of m deduced from Jacobson’s experiments. No. of experiments in series 5 i 7 5 9 Deduced value ofm .... 1:38 1:25 1-44 1:30 158 Another result from a series of five measurements with a tube of 0°12516 radius and 15-77 c.m. length,* was m= 1-08. The fall in pressure at the entrance of the tube was also directly observed by Jacobson,® his experiments being made with 4 brass tube of 0-2545 radius and lengths as shewn, and the temperature maintained constant for the measurements of any one series. tube was bored through at a point 0°15 c.m. from its infos terminal? and the fall in pressure ascertained from the differen 1 Archiv. fiir on u. Phys., 1860, p. 93 and 1861 p. 327. 2 Thid. 1860, p. § 3 Jacobson’s alle t. p. 94, said to be obtained from the sheet tions by the method of least squares, should, when multiplied by ee give values sensibly equal to these. They are nearly so. * Ibid. 1861, p. 327. 5 Thid. p. 309. 4 6 It should be mentioned that the coéfficient ¢ p. 322 of the 1861 volume i Archiv. f. Anat. &c., when multiplied by g and expressed in the one : units 18 our m, and that its values for Poiseuille’s tubes, p. 326, are are ver : nearly identical with those hereinbefore given. - os VISCOSITY OF WATER BY THE EFFLUX METHOD. 103 in the height of the water in the reservoir, and in the manometer attached at the bore near the terminal. I have computed the coéfficient by the formula g m= 2%. (h-h J, (hho) h being the height, above the axis of the tube, of the water in the reservoir, and fA, that in the manometer: the derivation from formula (4) is evident. Values of m deduced from Jacobson’s measurements of the differences of pressure between the reservoir and within the tube near its entrance : b= 134". 71 7.912 10]. 10). 2a ee m=1-06 1:09 1:22 1:10 1:38 91 93 1-09 O01 245.219. -3é 2-28-1700: Bh 6 131 £26: 04 (1-54.06 079 1288 89) «1-41 “82 1-40 1-42 The mean of these 28 results is 1-10, of these with the 6 pre- ceding, 1:14; this average gives a general confirmation to Boussinesq’s theory, but the individual results shew how, even under circumstances in which uniformity might be expected, it is not realized. The differences are certainly not due to mere errors of observation. We see therefore that Hagenbach’s correction must be increased 41%, Couette’s 12%, and that Reynolds’ dictum — is negatived : and further, that if this correction be of sensible magnitude, the deduced viscosity is to the extent of the uncertainty therein unreliable.1 9. The correction to the length of the tube.—In the preceding article it has been shewn how the product of the pressure and time of efflux of a given volume of fiuid may be found, when the loss of head at the entrance of the tube vanishes or is eliminated. Following Hagenbach it has usually been assumed that this Correction is the only one necessary, or that the corrected differ- ences of pressures may be regarded as the differences at the ‘erminals of the tubes; and Reynolds tacitly admits this view 104 G. H. KNIBBS. when he affirms that the correction 1:°505 U?/(29) will make ‘ Poiseui peri ts consistent. Clearly however the corrected pressure for the entrance of the tube gives the value, not for the | - section EE’, but ee’, Fig. 1, the distance between these, however 4 being unknown, and probably somewhat uncertain as to constancy. It is however unlikely that it ever reaches two diameters where the end is sharply cylindrical or even one where it is conoidal ot | rounded off. Couette,! Boussinesq approving his view, with q | greater rigour takes into consideration the features of the flow : not only at the entrance but also at the point of efflux from the tube. He recognises (a) that its length should be reduced for the 1 distance between the sections EZ’ and ee’; (6) that frictional | resistance is suffered by the liquid before it reaches this latter section—where parallelism of flow is fully established : (°) that the effluent liquid penetrates that in the receiving reservoil, and maintains for an appreciable distance its cylindrical form without d sensible change: (d) and that the surrounding liquid offers frictional resistance to this penetration by the effluent. If lengths of tube whose resistances are equal respectively to the resistances : (6), and (d) above mentioned, be denoted by /, and /4, and the distances He=E'e' and Ff= F'f’ respectively by /1 and J, the q corrected length Z, will be ‘ hoe be ite tablets c.. ee eae (12) Couette argues that the part of the ‘charge’ expended by frictional 7 resistances in the vicinity of the extremities of a tube ought to be at least approximately proportional to the efflux, as is the cai with regard to the tube generally, and he therefore expresses consequent reduction of the pressure under the form 84 lq/ («h so that / will denote the algebraical sum of the terms /, to 12a is affirmed by Couette! that this quantity / may be assumed to ys always positive : we shall shew however that it appears sometimes to be negative and therefore we consider its sign to be undeter 1 Annal. de Chimie, 6 sér. t. 21, chap. iii, p. 494. . 2 FF' to ff! Fig. 1. a 3 Ibid. p. 501. 4 Ibid. p. 500. : VISCOSITY OF WATER BY THE EFFLUX METHOD. 105 mined in the general case. Let P’, denote the pressure corrected for these frictional resistances etc. at the terminals, then since L, =L +1, we obtain from (2) wR*P, _«R* 8 yl 8nq 8nq ah I, as we have said being either positive or negative. Combining this result with (3) and (4) and remembering that /, a function of R, denotes a small length of tube producing an equivalent loss of pressure to that arising from the friction at the ends, at the same time taking account of the positions of sectionsee’ and //,;’ and . therefore that it may legitimately be put under the form /=n &, the general formula for the evaluation of the viscosity may be expressed :— bE A Sa (12a) (Po - w R* y= Rathaus (P-—m in which n may have a positive or negative value, since 1 may be positive or negative. P'then in this formula, is the measured differences of pressure in the reservoirs, and Z the actual length of the tube. It remains to ascertain whether 2 has a constant value as supposed, and if so what the value is. (13) Pg” \ aw? R*’ Assuming that C has been found from J’, reduced by (3), or from 7’, reduced as indicated in (5), or preferably perhaps by extrapolation of a series of measures (11), we have at once from (13) crit C’ be used instead of C the numerator’ of the left hand member will be x gC’ R*. Ifnow the values of R/L be regarded 48 abscissze and those of the first member of this equation as — ordinates, aline passing through the points so determined will ‘ntersect the axis of ordinates at the distance 7 from the origin, ‘and this line will make an angle with the axis of abscisse whose tangent divided by » is n, the required factor. The intercept on the axis of ordinates corresponds to the values R=0, or de a te, for the condition when the correction for resistances at the terminals of the tube is infinitely small in relation to the resistance 106 G. H. KNIBBS. of the tube itself. Fig. 3 illustrates the method applied to Poiseuille’s series B and F, the former giving a negative and the — latter a positive value for n, viz. about — 5°2 and + 11-2, these q however, especially the latter, being subject to considerable uncertainty, as is manifest from the figure. The opposition of the sign of mis very evident in the following values for the | viscosity (7) computed without regard to the corrective term a2. : R . Tube. . xX 10° (1) Tube. : x 10° (7) B 56 013202—« CF t=« = Ra (l +5) (1—e*) With sufficient precision. This last equation enables us to replace er &.,, that is by the radius determined from actual measure- t of the Capacity of the tube. After some reduction and snag RTD NE Ne certs : Bn in this formula has of course the same value as in (26) in the Section and p=4(b+c). is 118 ‘ G. H. KNIBBS. rejection of terms in p and « higher than the square, we obtain P, = 8nq i Ln (1 + 2c? + 4p?) approx......... (28) . T # ba which may be used whenever «* and p* are negligible. This | limitation is not so serious as might at first appear, for one would q select for the purposes of a viscosity experiment a tube closely — approximating in form the right circular cylinder, or, if an oval and conical tube must perforce be used, one would be chosen in ' which the ratio of the axes was subject only to slight variation, _ and in which the axes themselves were of nearly constant magn- tude throughout its length. | The fall in pressure may also be approximately expressed of : terms of the mean of the diameters by substituting the value of R; in terms of R},. This gives re = 8g ‘ af + 3e2 4p?) (29) Rr T 4 Tf the « and p terms be written in the denominator they must have the negative sign. This formula will sometimes serve 354 - rough check on (26). | 16. General result.—The equations of Sections 10 to 15 not ’ only supply the requisite mathematical material for an accurate 3 computation of the viscosity from experimental data, but “ i furnish also ready means of estimating the consequence of eh observed or hypothetical defect of form in a tube proposed t0 s : employed for that purpose. And at the same time they indicate ; that the method of measuring the mean radius of capillaries only by contained volumes of liquid, is unsatisfactory when an ac a determination is required, for if the tubes be even slightly elliptical 4 in section, or conical longitudinally, the volume of efflux pet 4 of time may sensibly differ from that of a right circular of equal length and volume. The degree of precision with which gs : "mean radius of efflux’ must be ascertained will always be fou Pimes as great as that required in the deduced viscosity, that i8 say, if the latter is to be exact to say 1 in 1000, the mean radilS must be accurate to 1 in 4000. For, if we put é for the ratio of me Seaitice eo se4 es: rie eRe es VISCOSITY OF WATER BY THE EFFLUX METHOD. 119 the uncertainty in the value of FR, so that the radius is # (1 + &), we have fR(1+€é)}* = Bt(1+4é+...) The other elements in a measurement are involved only to the first power, and therefore their determinations need be only to one fourth the precision of that required in the case of the radius, perhaps the most difficult of them all to accurately measure. III.—DeErERMINATION OF THE VISCOSITY. 17.—General—Units.—C.G.8. units have been used thronghout, and the viscosity is expressed in absolute measure, .e. it is related to pressures expressed in dynes per square centimetre. Density of Water—The relative densities of water are derived from Mendelejeff’s table based on his formula! rie ATS) (94:1 +7) (703-51 —7)1°9 Pr denoting the relative density at the temperature 7 centigrade. The absolute density at 4° C. has been taken as 1:000013 grammes per cubic centimetre. pr=l Density of Mercury’—The density has been computed on the assumption that its value at 0° C. relative to water at 4°C. is 135956, and its absolute density at 0°—grammes per cubic centi- metre—therefore 13-5958. The density at other temperatures has derived through Broch’s value for the coéfficient x of total cubic dilatation, viz. _X= (181808 +0-175 + +.0-035125 72) 10... eeeeeeeee (31) * being the temperature in Regnault degrees? z.e. the 1/100 part of the expansion 0° to 100° C. ‘The volume for the temperature ; —— Russian Physical and Chemical Society, No. 5, 1891. Prati ‘i - ormation concerning the density of mercury at 0° C. see Traité 37 Pa tau, thermométrie de précision: par Ch. Ed. Guillaume, p. 36, ‘s aris 1889, “Sar veer et Mémoires du Bureau International des Poids et following ; wie - The expansions 0° to 100° C. are according to the tia... authorities Bosscha -018241, Wiillner ‘018253, Levy ‘018207 + Ve coéfficients give -018217. 120 G. H. KNIBBS. t, that at 0° being unity, is therefore simply 1+7 x. For the ait thermometer the coéfficients are respectively 181792, 0°175, and 0-035116, according to the same authority. f Dilatation of Glass.—Poiseuille adopted! for the coéfficient of cubic dilatation for glass, £, Dulong and Petit’s estimate viz., €=0-0000258 (32) to which, though somewhat less than later determinations,” I have nevertheless adhered as being sufficiently exact for the purpose in hand. Thermometry.—The degree of rigour in the thermometri¢ element of the various measurements of viscosity has not beet explicitly indicated by each observer. Most of the measurements 4 however are to an order of precision which rendered this of little moment. In the future it is to be hoped that rigorous methods of thermometry will be employed’ and that the determination will be carried to a higher degree of precision: merely verificatory Measurements are of little value at the present stage of the : investigation. : a 18. Poisewille’s experiments 1846. Volumes of the effin. the volume discharged in a given time was measured by the content | of bulbs, such as that shewn in Fig. 4, in which V denotes ™ bulb. These were filled with mercury and weighed with a precisio® of about 0°5 milligramme,‘ the temperatures being recorded. The results were then reduced so as to express the volumes at ee Poiseuille assumed the density of mercury at 11°.5—the temp® ture of one of the experiments, vide p. 515 of his memoir—to 13-569675. By the constants used by me this should be 13-567 : Mém. des Sav. étrang. t. 9, p. 515 et 526, 1846. For the cubie dilatation of glass 0° - 100° C, Rossetti and Levy ® B ai 0000262, “0000267, and the mean of Regnault, Wiillner, and Levy's is 0000269 : VISCOSITY OF WATER BY THE EFFLUX METHOD. 121 The volumes given by Poiseuille have therefore been multiplied by the factor 13-5697/13-5674 = 1-00017. Pressures.—Pressures under 15 centimetres of mercury or 200 centimetres of water were measured by a water-manometer, those above that amount by a mercury-manometer.’ The relative density of mercury to water at 10° ©. was assumed by Poiseuille to be 13:576981.2 I have taken it as 13°5746, and since the effect is to make Poiseuille’s pressures under 15 centimetres too small, have multiplied them by the factor 13°5770/13-5746 = 1-00017. In the case of tube /’ the uncertainty of the times of efflux is relatively so large that the application of this correction would be futile. The acceleration of gravity for the place where Poiseuille made his experiments is given by him as 980°8 centimetres per second.® Taking the absolute density of mercury at 10° C. to be 13-5711, and of water to be 0:99975, we get for the absolute pressures FF; by multiplying these numbers into the value of the acceleration £2 138100 Ay = 98050 Ay icieicnsicas (33) hm being the pressure expressed in centimetres of mercury, and Aw in centimetres of water, both at 10° C. Dimensions of tubes and bulbs at different temperatures.—The dimensions of the tubes and bulbs used by Poiseuille were evalued a the temperature 10° C.4 Four of the tubes were tested by filling with mercury and finding the area of the section from the Volume.5 The results were then compared with the direct Measurements of the diameters of the sections, on the assumption that their contours were ellipses, for it is on this assumption and m the direct measurement alone that the dimensions of the tubes, may be found. In the illustrative case given by Poiseuille er 1 ‘ay cit., p. 460 (note), and § 65, p. 4 id. p. 448~ 452: table 11, p. 475; i § 16, p. 532. : Tid. p. 531, This is oily stated by Poiseuille, vide § 83, p- 497 of his memoir: See also § 32 457. ips Pp. 457. 122 G. H. KNIBBS. the volume method gave for the diameter of a circle of equal area : 00376 c.m., while direct measurement and the assumption of an elliptical contour gave ‘00377. The difference 1/376 is small but by no means insensible, for since the diameter is raised to the — fourth power this difference will lead to an error of 1/94 in the — deduced value of the viscosity. Computation of mean radius of efflux.—Poiseuille used for the mean radius the half sum of the geometrical means of the terminal radii! But it has been shewn in § 11—formule (18) and (J8a)—_ that the geometrical mean is too great, and in § 12 and § 15—_ formulz (23a) and (29) that the mean of the terminal means is | also too great. I have computed the ‘mean radius of efflux’ by : the principle of formula (24) using formula (26) and occasionally checking by (29). With regard to the neglect of small terms in the computation dc., the condition has always been secured that — the error shall be small in relation to the probable uncertainty the data. Dimensions of the tubes.—Poiseuille measured the lengths ds the tubes used by him by means of a beam compass*—compas 4 verges—reading by a vernier to ‘005 em. and permitting, by estimation, a record.to half this amount. When a series of efflux experiments with a given length of vabe was completed, a portion of the free end was cut off by means of a file? a procedure that was several times repeated. This permitted the measurement of transverse sections at different distances along the axis, and the regularity of these gave & general indication of the symmetry of the tube. The measure : ments of each section are taken in account by me in the comp tation of the ‘mean radius of efflux.’ ; Effect of temperature on ‘dimensions. —When, as was the cast ‘ in Poiseuille’s experiments, the whole of the reservoir of supply— the bulb V Fig. 4—the flowing liquid, and the capillary are mail tained at the one temperature by immersion in a bath, or otherwi . ‘Thia. § § 114, p.513. 2 Ibid. § 83, p.497. 3 Ibid. VISCOSITY OF WATER BY THE EFFLUX METHOD. 123 no correction is necessary for temperature, so far as the dimensions of the apparatus are concerned, assuming that their original evaluations are all for the one temperature. This is evident if we consider the effect on the elements of the fundamental formula (4). For supposing the factor (1 + ¢) to express the linear correc- tion for expansion for the particular temperature to which all the parts are subject, then, on substituting for ¢ its equivalent Q/T, we shall have! eee Cty rt hi ie SL(I+He+O* 8Le This indicates the desirableness of securing this condition. 7 Evaluation of the viscosity at 10°C. from Poiseuille’s experiments. —The results of the computations for the values of the viscosity at 10°C. are giyen in the table in§ 9. It is worthy of remark that the satisfactory determinations depend on tubes whose radii and lengths range between somewhat wide limits, viz., R=0:0006975 L=0125em. Tube 1, £=0-032537 L=38-382 Tube / that is, for the radii the range is from 1 to 47, for the lengths 1 to ‘$0. The whole series of observations given in one of Poiseuille’s tables is involved in the determination of 1 wherever the extrapolation method—formule (6a) and (6b) § 8—has been used. These cases are distinguished in the table by the absence of an asterisk. Those marked with an asterisk give the mean result deduced from the first three members of the series,” as I TEU ieeremeese ee a oe uille’s method of reduction, vide his memoir, § 142 - 144, p. 526 rading =~ pn y unnecessarily operose, i oneous. He applies the the } ange (1 + ¢)* and the volume correction (1 + ¢)*» but neglects inten ee orrection (1 + (): see his note p. 525. He computes the mass 2 The ASS cahelie three exceptions to this statement. There is only one tem t each, in the case of tubes M, and Mi. In the case of 41 the of the first experiment was not 10°, so that the following ee were taken. * 124 G. H. KNIBBS. believe them to have the greatest weight. The corrections to the : pressures in these instances have been applied on the ann 4 that m in formula (3) is 1°12. a There are thirty-six tubes in the series, the flow in the last four q is probably unsteady, and therefore the formula of reduction is of doubtful application, as it applies only to the case of steady motion. : The general result is F 9 = 0013107 and seems to be reliable to four significant figures. 20. Values of the viscosity and relative fluidities between 0 and 45° C. as deduced from Poiseuille’s experiments.—Interpolatioms. - —Poiseuille’s measurements with tubes A, C, D, and Z, give, to q quarter seconds, the times of efflux, for a volume constant for each — tube—excepting in so far as it is modified by the expansion of the apparatus—under pressures ranging between 77°3 and 77°6 cm. of mercury at 10° C.,! and their reduction to a common pressure — viz., that last mentioned. These reduced values I have taken a data. The temperatures are about 0:5°, 5°, 10° ete. to 45°, but frequently differ 0-1 or 0-2 from the whole number of degre The efflux times have consequently been corrected by interpol tion, having regard to second differences, so as to give their value for flow exactly at each fifth degree from 5° to 45°. These agail have been corrected for the fall in pressure at the entrance of the tubes, by formula (5) assuming m to be 1°12,” the results bel expressed to 0-1 second. The efflux times so corrected are ® follows :— sea aie ee a 1 I do not remember that this is explicitly stated by Poiseuille, but may be observed that the values at 10° are those of the earlier e coe moir, and the method of reduction indicates what I have 2 In § 8 it is mentioned that tube A indicated a value for m of 04a 0'5, and that C, D, andE gave no satisfactory indication whatorer A of its value. Ihave not used this value for A because it depends on & 8" mination by three points only, and in the case of the other three ! ‘hi the correction mentioned is the most probable. : VISCOSITY OF WATER BY THE EFFLUX METHOD. 125 Corrected times of efflux (seconds ). Temp. C. Tube A. Tube C. Tube Di. Tube £. 0: *2308°7 *2848-7 $3409°7 *2735°8 0:5 2327:0 2809-2 2697°3 5 2014-6 2416°1 2894°1 2314°6 10 1739°7 2087°5 2501°3 2000-7 15 1518-2 1830-2 2191-0 1751-4 20 1337°0 1607°9 1923-0 1542-0 25 1186°7 1427-6 1713-2 13718 30 1061-2 1279-7 1531:°0 1227°1 35 954-1 1148°5 1374°3 1101°8 40 862°3 1041°3 1243°8 998-4 45 782-2 947-4 1136°9 906°8 It happens, somewhat curiously, that if we take the reciprocals of the efflux times their progression may be represented with considerable exactitude by a curve of the second degree. Simplicity _ of treatment, and a convenient comparison of the results obtained from each tube, may be simultaneously secured by expressing the fluidity for 0° C. as unity. We therefore divide the efflux times for 0° by those for the other temperatures, the quotients so obtained are entered in the following table. two he value for 0° C. marked + is the mean determined by ... (a) and (b) the results differing, it happens, only 0-2 second. iia od (a) was extrapolation through the points determined by the efflux 8 sees oy, 15 and 20. The method (b) was:—the sum of the the ha sat 0° for tubes A, C and E divided by the similar sum for the OT between the limits 5° to 45° inclusive, was multiplied into this ext ciara ve the times for tube D,. In regard to the legitimacy of extrapolation see § 25 hereafter. 2 ig ; Pm fluidity / has already been defined, § 3, as the reciprocal of the constary,, the Pelative fluidity f’ will therefore be 1/1 multiplied by some 126 G. H. KNIBBS. - Relative fluidities of distilled water, 0° to 45° C. as determined y, from Poiseuille’s experiments with glass tubes. F Temp. Tube 4. Tube C. Tube Di. Tube E. Mean. Compu od 1:0000 1:0000 1:0000 1:0000 = 1-0000 4 05 10136 1-0141 10143 1-0140 10170 © BS Pius Ltrer 1782" 11820 PES 11756 10 1:3558 1:3647 1:3632 1-3674 1-3628 1:3630 ” 15 15536 15565 1:5562 15621 1:5571 1:5621 3 90 1:7642 1-°7716 1°7731 1:7742 17708 17m 4 95 19876 19955 1:9903 19943 11-9919 1-956 q 30 229297 22961 22971 2:2295 2-2264 2-2300 a 35 24721 24803 2-4816 2-4830 2-4793 2-4762 4 40 2°7354 2°7357 27414 27402 92-7382 2-734 4 45 30155 3-:0069 2-9991 3-0170 3-0096 30036 4 — > Taking out the second differences from the column of mea values, we find no definite law of progression, that is to say the third differences are irregular and variablein sign. As the second differences are small, a curve of the second degree will express the results with considerable precision. We therefore put ; Sf’ =1+a7r+ Br? (35) jf’ denoting relative fluidity, r temperature in degrees centigrade, and a and £ the constants to be determined. The mean of he second differences for the 5 degree intervals is 0-01174, s0 that | 28x52 =0-01174 or B=0-000235! ‘ By subtracting from each value of the relative fluidity the corre ponding value Br? we eliminate the second term from the ¥ ue of the function, and may thus obtain that of a. This is nee conveniently effected by the process represented in the follo —— a 1 More accurately 0:0002348. The change to 0:000235 is not wit advantage, for when the first term is subsequently evaluated, the limi number of figures used, more exactly expresses the observed values ® if the change had not been made. I venture to think that for P purposes the type of solution above indicated, together with the com ation of the reciprocal effect of small changes in the coéfficients, with view to securing a simple numerical expression that will repres* é observed values, is preferable to the usual method by least squares ns] VISCOSITY OF WATER BY THE EFFLUX METHOD. Par formula oe Mi B 207? (36) The application of this te to he case in hand gives a = 0-03395, The fluidity is therefore J’ =1+40-033957 + 0:0002357? (37) The values in the final column in the above table of fluidities are computed by this formula. With the exception of the values at 0-5° and 40° they lie between the extremes of the observed values. The absolute values of the viscosity at 10° C. deduced from these — experiments are! Tube A 0013124 » - C...0°013026 » D, 0-013010 » £ 0-013252 This mean corresponds to the value 1°3628 in the relative fluidity: in order to make it agree with the result from the whole of the experiments it must be corrected so as to correspond with the value 1:3630 of the computed curve. Multiplying therefore by the factor 1-3628/1-3630 it becomes 0:013101, and this is the value Of 719 best representing the whole of these experiments. The mean of the thirty-two determininations at 10° C. in $9 gave 0013107. Taking the mean of the two we have for the value of the viscosity at 0° OC. No = 1:3630 x 0-013104 =0-017861 os and thus ir the general absolute value in C.G.S. units as deduced from the whole series of Poiseuille’s observations? we obtain Mean 0:013103 n of a number. The mean of the four “ Sutaa oo. 581 of his memoir—a formula = 1836-724 (1 + 0-0336793 7 + 0° 9002200086 7?) HD*/L hy of remark that, accepting his results as pie vents the simple expressio q' = 1832'4 a + -0339 + -00022 7) HD*/L more exactly expresses them. It is aie relatively 4 4 : ‘4 ¢ ‘a : 128 G. H. KNIBBS. 0-01786 : (38) It 79-0290 2 1 O00) 2F 1 +.0-03395 7 + 0-000235 72 The expression of the result to any higher order of precision wield be misleading. The general exactitude of Poiseuille’s experiments leaves little to be desired : it is to be regretted however that the dimensions of the tubes were not obtained to a much higher degree : of accuracy, and that the character of the thermometry has not been more explicitly stated. That it was very good is manifest both from an examination of his menioir and from a comparison of the results. For from (37) and (38) we have for the relations ofa — variation df” in relative fluidity and a variation bor of the vino to a variation in temperature dr df’ = (0-03395 + 00047 +) dr (39) — dy = (0-000606 — 0:0000328 7) dz (39a) hence a difference of 0°.1 will account for the difference between the mean and computed values of the fluidity at 0°.5 and at 45°, Moreover 0°.1 will alter the last figure in the coéfficient of viscosity for 0° C. by its whole amount. To determine the viscosity t0 1/1000 the measurement of the temperature at 0° C. would have to be to within 0°.03, and at 100° to much less than 0°.01, so that to reach a higher order of precision than Poiseuille’s results seem to indicate has been attained, will involve an attentive consider tion of each element in a determination, and a complete discussion of the attainable accuracy at every stage of the processes of measurement. 21. Other measurements of viscosity. Jacobson, 1860: Jacobson’s measurements of efflux were made with glass and brass tubes, the pressure under which the flow took place being that of the water in the reservoir of supply. His data in addi to the dimensions of the tubes are the ‘ heads’ and velocities th latter being computed from the weight of the efflux in a giv time, Hagen’s values! of the density of water at different tempe™ tures being used and the expansion of the glass and brass being oe 1 Abhandl. Axed: Berlin, 1855, Math. Abt. p. 1-28. VISCOSITY OF WATER BY THE EFFLUX METHOD. 129 taken into consideration.! Hagen’s values are so nearly equal to those of later determinations that corrections were unnecessary. The viscosity was calculated from the formula ghop Rk? ected ee The variations of the dimensions with temperature have not been taken into account, so that they are uncertain to the extent of the correction + ¢ see section 18 hereinbefore : this however will not materially affect the result, and the data are certainly not of sufficient precision to make the matter worth consideration. The results have been reduced from the temperatures quoted to 0° C. by formula (38). The value of g for Kénigsberg, where these measurements were made, has been assumed to be 981°44. Hagenbach, 1860.—Hagenbach reduced his own and other experiments by the application of a formula, which, for C.G.S. units and an absolute value of », may be written a ea aces ets RR ( 1 FOL (40) This was theoretically deduced and is identical with (4) if k =m/8, hence & should be 0:140—see § 8. Hagenbach however used y 24°, 4¢.0-0992, instead. The lengths of his tubes were measured directly, and their radii computed from the contained volumes of mereary.! The acceleration of gravity is not given, but I assume | Wt to be about 981-0 centimetres. The value for n at 0° C, given ; yg is the mean of the results for four tubes of different ii, Graham, 1861 -—Graham measured the efflux times with two —D and E—at frequent intervals of temperature, never ates than 5°, from 0° to 70° C., recording generally to whole amg a half second however being occasionally shewn. From 83 values he gives for (), Z and R, I have reduced his observed ‘eas formula (5), casting the results to 0°1 second. The two en ee anything like identical values for », the results : Archiv. fur Anat. u. Phys. 1861, p. 315. ie we Pogg. Annal. Bd. 109, p.398. 8 Ibid. p. 400. TJuly 3, 1995, 130 G. H, KNIBBS. for 10° ©. being, for tube D -0112, and for tube Z -0081, instead of ‘0131. Isuspect that the dimensions are in error, which if — true, prejudices the correction of the times—the reduction of T' to 7’,—a correction of considerable magnitude in these experiments Despite this, they are valuable as to some extent confirming— — contrary to Rosencranz’s measurements—the propriety of extt polating beyond its major limit, the curve expressing the results : from 0° to 45°C. Both bulb and tube were immersed in the heating bath, so that no dimensional temperature corrections were required. Rellstab, 1868.—According to the specific viscosities quoted by Wagner,! Rellstab’s experiments give for the relative fluidities for : each 5° from 0° to 50° the following values, that at 0° being 1000, 1000, 1172, 1361, 1587, 1802, 2053, 2222, 2500, 2688, 2899, 3205. These agree well with Poiseuille’s values, but in the absen® of the experimental data I have been unable to apply the revised correction for fall in pressure at the tube entrance. | Sprung, 1876.—Sprung’s observations have been reduced 0B the assumption that the dimensions of the tube and bulb are gi¥@ — pressure in grammes per square centimetre. Sprung used Hagenbach’s correction to the pressure.2 The reservoir and capillary being both immersed during the experiments, dimens! corrections were not required.® Rosencranz, 1877.—In Rosencranz’s apparatus the reservoir | supply, a bulb by means of which the volume of efflux bigs capillary. This complicates the reduction. Let @ denote volume of the reservoir at the temperature for which the dimen sions of the tube are given, and p the density of water at oe temperature, then the effluent volume Q’ at 7 degrees abo temperature, the density being then p’, will be 1 Wied., Annal. Bd. 18, p. 263. 2 Pogg. Annal. Bd. 159, p. 6. 3 Ibid, p. 5, 6. a Sa ities hn a calamea sae Saenees : pap y es Soap ial ee on ES ee Oe ee ee Be ee eng on Lee Weert eR) ST Eee Re ean rm et Mater te Pee) th SN See eee am eR wey ey: VISCOSITY OF WATER BY THE EFFLUX METHOD. 131 ge Ry 7 = — = —_- —=E +7 . "Soh ocd cli ore eg & being the coéfficient of cubic dilatation. Thus, for measurements of dimensions at all ordinary temperatures we have with ample precision 4 . 2 ho T(1l+7ré+p'— p) - oo , ae \ Be ae (41) The correction represented by the term ré is rejected by Meyer, in his reduction of Rosencranz’s observations, as negligible!: its maximum value is however about 1 /500, and it affects the com- puted values of » from 4 to 7 units in the last place of figures, viz. the fourth, The pressure registered by the manometer was throughout 59°3 centimetres of mercury at 18°C. Meyer takes this to be of 13-415 density and equivalent to a column of water of 795-6 c.m. height : to this has to be added 9-0 c.m., owing to the disposition of the apparatus, thus making a total of 804-6 c.m.?. But this value for the density is, I suspect, an error, and I have therefore recomputed the pressure, obtaining the result 812-59 grammes per square centimetre. The bulb measuring the influx contained 111-03 grammes of water, which [ take to represent a volume of 111-178 cubic centimetres at 18° C., the laboratory temperature.* The capacities of the tubes were found by filling with mercury and the mean radius so determined.‘ The reduced results can be expressed in the form> 0 Ie Tear but they do not appear to be satisfactory either intrinsically, when Compared with Graham’s observed values, or with those obtained by extrapolating the curve given by Poiseuille’s measurements. 1 . in ag Annal. Bd. 2, p. 399—* doch kann diese Correction ihres ger- 2 Ths Bes Wegen unterbleiben.” M =< P. 397. 3 Ibid. p. 397. ; See also Pogg. Annal. Bd. 148, p. 36, 1873. Tube ut. To WAS “01854 and « -04635 132 G. H. KNIBBS. 4 The values given by me are obtained by interpolation: in the — original work the temperature-intervals are irregular. Phibram and Handl, 1878.—I have not reduced the observa- tions of these investigators. The times of efflux are short, about — 84 to 199 seconds, the temperatures are at irregular intervals from _ 13-9° to 56°4°.1 : Grotrian, 1879.—The lengths of the two tubes used by Grotrian were measured by a cathetometer to 005 c.m., at what temper — ture is not stated, and their sections were derived from measure ments of their capacity.2 The content of the measuring bulb was 40°3465 grammes at 16°.57 C.: its capacity was evalued by — Grotrian for 28° the middle temperature in his efflux experiments. 3 Assuming however that the other measurements were also made at about 16°.57 I have, as is requisite, found the capacity for that temperature, the result being 40°390 c.cm. The apparatus was wholly submerged in the heating bath. Slotte, 1881.—With the one tube Slotte measured the efflux four times at each of the temperatures 10, 20, 30 and 40 degrees C., these being registered by a corrected (justirtes) thermometer, graduated to tenth degrees.2 No information is given in the account of his experiments as to the conditions under which he dimensions of his apparatus was ascertained. The apparatus and method of using it was similar to Sprung’s, hence dimensional temperature corrections are not needed. Slotte proposed "7 formula by which the viscosity might be put in the form* —C. i B+r He used Hagenbach’s correction.5 eee 1 Sitzber. Akad. Wien., Bd. 78, Abt. 2, p. 113 - 164. 2 Pogg. Annal. Bd. 160, p. 264. ti 3 Wied. Annal. Bd. 14, p. 13. 7 orp? 4 According to the Chemical News, Vol. 69, No. 1790, p. 123-—~"" and Rodgers in the Bakerian Lecture of the Royal Society, give Fer for preferring Slotte’s formula n= e/(1 +br)". I have not ot paper. 5 Loe. cit., p. 17. VISCOSITY OF WATER BY THE EFFLUX METHOD. 133 Wagner, 1883.—Wagner’s measurements of efflux were all with one tube, four experiments being made at every 5° from 15° to 50°. His apparatus was similar to Wiedemann’s' and Sprung’s, I assume, as I did in reducing Slotte’s work, that Wagner’s dimen- sions are evaluated for the one temperature, though definite information on the point is not given. He used Hagenbach’s correction, In regard to the pressures, I conclude that H indicates grammes per square centimetre. Reynolds, 1883.—Two of the tubes used by Reynolds were leaden pipes whose radii were 0°3075 and 0°635 cm. In these the fall in pressure between two points 152-4 cm, apart was measured by the vertical height of columns of water sustained at those points, i.e. by the ‘hydraulic gradient’ of the pipe. Though not exactly equivalent to the fall per unit of length expressed in grammes per square centimetre, the agreement is sufficiently approximate in relation to the order of precision in the data, to render the application of a correction unnecessary, In my reductions I have assumed the acceleration of gravity to be 981: cm. The temperatures do not appear to have been measured with great precision so that the deduced value of 7 must be considered as merely approximate. It is worthy of remark however that it does not differ more than 1/27 from the value obtained from a tube (M, Poiseuille’s) the area of whose section was only about 1/800000 of the larger of these tubes. Rénigen, 1884.—The object of Réntgen’s experiments was to “Scertain the effect of pressure on the viscosity. He measured the times of the efflux under pressures varying from 19 to 29 atmospheres, as well as those under pressures of 1 atmosphere, = temperatures being approximately 6° and 11°C. There is Cae information to determine the absolute or relative Sat these tem peratures, nevertheless the effect of variations Pressure can be fairly well ascertained. The change in the ite with such variations is so slight that the correction for ip _ *°88. Annal. Bd. 99, p. 221, 1856. 134 G. H. KNIBBS. loss at the entrance to the tube is sensibly the same for efflux at constant temperatures under any pressure,! for the times of efflux are very nearly equal. The results have been reduced to their values at 6° and 11° C. by formula (37), and the higher pressures to the value for 24 atmospheres. | Konig, 1885.—Using two tubes of nearly equal sectional area, Kénig made five efflux experiments between the temperatures 155° and 18-1° C., correcting by Hagenbach’s formula. In my ~ reduction I have assumed g to be 980-95: its value was not mentioned in Kénig’s account of his work. a Couette, 1890.—In his interesting ‘Etudes sur le frottement des liquides,’ Couette gives a method of observation by which the corrections for fall in pressure at the entrances of tubes and fot | their end conditions—see (12a) and (13)—are eliminated. By means of selected capillary tubes of equal radii, but of vey ‘ different lengths, he connects three reservoirs, through which & 4 ‘flow from a still larger reservoir is established under pressure, the efflux through both tubes finally becoming equal. The pressures 4 in the three reservoirs are then measured by a manometer of ae 4 branches. Putting y =mpq?/(x? R*), / having the same significe 4 tion as in § 9, P, denoting the fall in pressure betweet the reservoirs connected by Z,, and P, the corresponding fall betwee? the reservoirs connected by Z,, we have ; oe. Le eee ee? : hence if, as there is reason to believe, y, =y. and 1, =ls, and if also it were possible to employ two tubes of equal radius BW should have =-——, 1? (42 8 7 L, -L, i ) z that Couette’s formula.? But more rigorously it may be assumed ae this is not possible ; and therefore we are involved in considering ea cinahmeettietatnleel hcl cree ai pa asia tg te pee 1 The difference in the correction will probably always be les* ans -the unavoidable errors in the recorded times of efflux. ? Annales de Chimie et de Physique, 6 sér. t. 21, p. 468- 472+ VISCOSITY OF WATER BY THE EFFLUX METHOD. . 135 the application of Couette’s method when an inequality in the radii is known to exist. Let, as in § 12 and § 14, R, denote the ‘mean radius of efflux’ of tube 1, etc.—i.e. the radius of a right circular cylinder of equal discharge—then putting, similarly to our previous notation, 4 4 Ri ZK Ri R* =} (R{ +R?) ande = RigRt we obtain 8 0 P,- P,- Pith et sey | (43) 8q L,-L, that is, the correction / is eliminated, but not y. The term 2ey is probably however always negligible, but not so (2: +P,)e. This result is important as shewing that when the radii are unequal the deduced value of the viscosity depends not merely upon the difference of pressures in the reservoirs, but also upon their absolute amounts. I have not from Couette’s data reduced afresh the values of the viscosity, but accepting them for the particular temperatures of his own observation, reéxpressed them for other temperatures by formula (37). Cohen, 1893.—Cohen’s extended series of experiments, by the efflux method, to ascertain the effect of pressure on the viscosity of liquids, cannot be used to obtain absolute measures, as only the approximate dimensions of his tube,! and of the fall in pressure therein,? are given. In his own reduction his times are uncorrected ee although this does not sensibly affect the results, for the Suestead pointed out in referring to Réntgen’s experiments, the Boy of experiments seemed well worth rigorous reduction. For ~ purpose of the reduction of the times, the volume of efflux— oumeh Was not given—may be computed from the known value of | the Viscosity, so that instead of finding 7’, by (5) we must use® Sole d. Annal Bd. 45, p. 666. 2 Ibid. p. 669. cca formala is of course derived by substituting for Q? in (5) its Only iin - equivalent in terms of the other quantities, supposed known Sufficient accuracy for the purpose of the correction. 136 G. H. KNIBBS. mpPT R* 64 L? 95 which is quite satisfactory since the corrective term is small. Pen P (1 +ar+ Br?)? Pisisteacsenees (44) 22. The value of »o.—The value of the viscosity of water a Orc. —viz. 79 = 0-01786 formula (38) corresponding to = 0-013103, and deduced by a rigorous reduction of Poiseuille’s efflux measure — ments—is among the smallest of those obtained from the exper: ments of different observers, see the second table of § 6. This is probably attributable to the fact that, of all tubes of equal 4 sectional area, the right circular cylinder gives the greats) — discharge, whence it follows that where the radii have beet computed from the measurements of capacity on an erroneous assumption of that form, the departures therefrom must necessarily, as shewn, in § 11 to § 16, give values greater than the true me — Poiseuille’s tubes seem to have been the only ones whose sections — were measured directly, and at several points along the ax consequently it is to be expected that the value of », deduced 7 from his experimental data by the application of corrections fot 4 the departure from the circular cylindrical form, will be appros 7 mately the minimum. Its smallness, as compared with the resull of other observers whose data do not include material for the corrections, in no way diminishes our confidence in it as 4 relia! value, and one really representing, in numerical form, a phys! property of water; whereas in regard to the larger values one very properly suspects that had such data been to hand, the appropriate, corrections, then possible, would have made the results more accordant, since they are always negative in sign. At the a time we do not prefer the smallest value because errors ¢ measurement, either of dimensions, pressures or times, are aS likely to be negative as positive. For purposes of comparison the following values of the viscos!t] at 0° C. have been recomputed from the original data using Boussinesq’s value for m in (5), the reduction to 0° being by multiplying by the relative fluidity f’—formula (37). temperatures quoted are those of the experimnts. VISCOSITY OF WATER BY THE EFFLUX METHOD. 137 Viscosity of Distilled Water at O° C., computed from the efflux measurements of various investigators. Observer. Date. Expts. Tube. Temp. No: Poiseuille 1846 series glass 0°- 45° 001786 Jacobson 1860 4 x 16°.7 1808 s > 4 : 15-2 1800 ” ” 3 ” 11°3 1867 % iy 2 Z 122 1770 ” » 3 brass 13°4 1755 ” 5 3 7 15-7 1809 % s 1 ie 16-7 1806 ” ; 5 : 15-2 1786 ” i 4 ‘ 12°8 1778 ” ; 7 ; 16-5 1794 Sg ” 5 ” 16°4 795 Hagenbach 1860 4 Pa 17°4 1844 Sprung 1876 21 eee Ty 1773 Rosencranz 1877 2 a 42°55 1797 Srottin 1879 2 14.9 —«:1798 Slotte Oo ea 10° 1814 Wagner 1883 4 . 15° 1797 Reynolds 22 lead 5° — 12° 1834 Konig O86... k glass 16°.8 1771 Couette 1890 2 copper 16-4 1819 3 ” 3 white metal 18-5 1817 3 paraffin 12-6 1853 23. The relative fluidities of distilled water at ordinary pressures : temperature 0° to 50° C.—Small errors in the dimensions of tubes prejudice but slightly the reduction of the relative fluidities, IMasmuch ag they affect only the correction for the fall of pressure at the entrance of the tube. That the dimensions given are, with the exception of Graham’s, sensibly correct, is evident from the that the absolute values of the viscosity derived from them se nearly identical, The results however do not exhibit as ms ect an agreement as one might perhaps have expected. The ue for 0° C. has been taken as 1000 instead of unity. 138 G. H. KNIBBS. Relative Fluidities of Distilled Water 0° to 50° C., computed fi the efflux measurements of various investigators. | Temp. Psl816. Gd186l. Gel861. 841876. Gil879. Gii1879. Sl41881. Walsh o°c. 1000 1000 1000 1000... oes 1000" 5 ott. s2008 118s Hi6.... “i sk oe 10 1363 1364 1373 1366... -... 1363 3a 15 1557 1582s 1575 1566 15572 15632 ... 1568 20 1771 1802 1791 1775 17652 1767 1795 25 1992 2053 1990 1983 “sda 1996: a 30 2226 2272 2207 2218 2227s .. 2213 2263 35 2479 2535 2452 2457 95115 2494: 2509 40 2738 2781 2736 2705 27242 2728: 2719 2769 f 45 3010 3041 2985 2957 se A . . 50 3285* 3337 3279 3218 - — * Denotes that the value is extrapolated. The small numbers : 4 etc., denote the number of experiments on which the value is based. Pe Poiseuille: Gd=Graham, tube D: Ge = Graham, tube E: S=Sprung Gi=Grotrian, tube 1: Gii = Grotrian, tube 2: Sl= Slotte : w= Wagner 24. The relative fluidities of distilled water for temperature above 50° C.—So far as I am aware, only two observers have gre. measurements from which the fluidity for temperatures above 50°C. ; can be ascertained, viz. Graham and Rosencranz. Meyet, who reduced Rosencranz’s data, concludes that above 50° the sui is related to the temperature by a linear function, viz. fr=fo (1+ 47) | but Graham’s results do not tend to confirm this view. In# table hereunder, the design of which is to illustrate this point, first column Px contains the values of the fluidity obtained extrapolation from the results of Poiseuille’s experiments, form (37): the second and third columns those of Graham with tu Dand E£, his measurements being made at the temperatures qu? : the final column Rx, contains the values roughly interp® from Rosencranz’s measurements. The fluidity at 0° C. is OEE as 100. e temperature ietareads- were irregular and as the rong not be closely represented by a curve without PP ERE | interpolations were possible VISCOSITY OF WATER BY THE EFFLUX METHOD. 139 Relative oi of Distilled Water, 50° to gt C. Temp. Gd Ge 50° C. a 334 328 nie 55 358 360 349 354 60 388 387 380 372 65 420 415 418 398 70 453 448 444 421 75 487 443 80 522 462 90 - 596 546 The results indicate that the form of the curve best representing the relative fluidity, is not well determined for temperatures above 50°, and that further experiments are required. Probably it will be found that a in formula (37) 0 must be slightly increased and B diminished. 25. Relative fluidity y of distilled water near the temperature of maximum density—The curve of relative fluidity gives some indication of an inflexion at about the temperature of maximum density 4° ©. as will be seen from the following results for temperatures 0° to 10° C. temp. Pa Pe Pe Gd ss Ge Ss Mean. 0 1000 1000 1000 1000 1000 1000 1000 me os. 4014 1014: =. cise _ 1014 pe 108e gs sy ce ms 1022 l ce au i TORR Tega 26 1050 1091 1076 .. 1084 : 1198°01168>. oe 4 Re es SS LA ae 1157 : £992-21179. 1189~ 1187°:1180: 1176 HA 1258 1265... 1261 '. 10 1356 1365 1367 1364 1373 1366 1365 Ga Notr.—Pa, Pe and Pe, are results from Poiseuille’s tubes A, C and E; ; and Ge from Graham’s tubes D and E; and S from Sprung’s. oe the values obtained by assuming that the fluidities m 0° to 10°C. are given by the expression 1000+ 36-57, from 140 G. H. KNIBBS. those in the last column—the means—we obtain Tap © 00 06 1 2 3 4 5 Oe Dif, O-4 04+13411+104+11-34+6 8 that is the differences are generally positive and are 8 The curve best representing the mean values must therefore t the form : F's = 1000 (1 + ar - f’r”) between these limits, and since from 5° to 45°C. the coéflicient 8, was positive—formula (37)—there is an inflexion : the curve. To determine the point of inflexion, extremely accum® measurements of the viscosity would be necessary. The chang in the form of the curve from 0° to 5° somewhat vitiates extrapolation—though it be for only a half degree—by bs efflux time for 0° C. was obtained in § 20. 26. The variation of the fluidity with presswre.—The sna pressure is to increase the fluidity or to diminish the viscosity, ¥ least for temperatures under 30°C.!_ This is best shewn by method of expressing the value at each temperature for atmosphere as unity: in this way the results become indepe! of the relative fluidities for the different temperatures” values for a pressure of 24 atmospheres are from Rantgen's ® those for higher pressures from Cohen’s experiments.” Effect of Presswre on Fluidity at 15° C., according to Cone Experiments. : Atmos. = 100 200 300 400 500 600 700 I. +0072 0127 0150 0219 0208 —— 0280 IT +-0051 0126 0161 0223. 0258 —— 024 ete. 60162 — 0239 = Mean +-0057 0127 0154 0221 0233 0239 0237 © oe -—The flui idity under a pressure of one pers sigs is unity: # at any other pressure is 1+ the decimal in the t es A 1 Under 40° C. according to Cohen— Wied. Annal. Bd. 45, P- oak 2 The relative fluidity cannot be accurately determined from the ¢ . * The figures are not alwa this h ys identical with Cohen’s: ~ beta to the — of the small correction to the tim VISCOSITY OF WATER BY THE EFFLUX METHOD. 141; The only anomalous result in the above table is that for 700 atmospheres ; the value is probably too small. Effect of Pressure on the Fluidity at various Temperatures, according to Réntgen’s and Cohen’s experiments. Temp. Pressure in Atmospheres. ! 24 100 200 = 30 600 700 900 YY — 0215 —— 0327 —~— —— 0670 —— —— — cine 9 Hines lS Crem OO — —— — 15° —— 0057 0127 0154 0221 0233 0239 0237 0277 23° —— 0047 0077 — 0100 —— —— Nore.—The fluidity under a pressure of one atmosphere is unity for nse temperature: that at any other pressure is 1 + the decimal in the e. The available information is insufficient for the deduction of a general formula expressing the fluidity as a function of temperature and pressure, for as pointed out by Cohen it is yet undetermined whether at higher temperatures the viscosity instead of being diminished by pressure, is increased.1 21. The value of the viscosity by the rotating cylinder method.— The values of the viscosity of water as found by other methods have differed greatly from that obtained by the efflux method. In @recent investigation by Brodmann, this difficulty though not completely is at any rate partially resolved. From experiments _ of type (6) § 1, using three cylinders of different sizes,” he obtains ~ following values (i) and (ii) for the viscosity at 15° C. respec- mrely from the smallest and middle, and smallest and greatest Cylinders. Poiseuilie’s value (iii.) as deduced herein is indicated also for comparison (i.) a5 = 0-01265 + 0:00049 | (ii) m5 = 0-01228 + 0-00011 (iii) 5 = 0-01143 7 ute ets p. 684, Wied. Annal. Ba. 45, p. 178, see also p. 179. 142 G. H. KNIBBS. 1V.—InpicaTIONS FOR A FURTHER DETERMINATION, 28. Apparatus.—Some observations in regard to the gener disposition and dimensions of apparatus for a further determin tion by the efflux method of the viscosity constant, may notlt : inappropriate in concluding this examination of the subject — Fig. 4 indicates the general arrangement of the essential pa | best adapted to the purposes of accurate measurement'—it i ; essentially Poiseuille’s. The pipe P is connected with the sour of pressure—compressed air contained in a large reservoir it : Poiseuille’s' experiments,—continuous with it is the pipe Mf cm municating with the manometer. When the cock-valves X and are turned the pressure compels the contained liquid in the reservoir bulb V, to flow through the tube JA, the capillary 44, | and the efflux tube B HZ, whence it emerges into the water in 8 | heating bath W, carefully maintained at constant temperature and height, the temperature—that at which the viscosity is to be : determined—being measured by the thermometers T, 7. boul tubes JA and B E ought to be of the same diameter, and ee terminals 4 and B of the capillaries may if possible be inset — well within them. The small bulb U7 is intended to hold suffice liquid to permit the flow to be thoroughly established under al general conditions of an experiment, before the measure actually commences, and, with the rest of the apparatus men ion is wholly submerged in the heating bath. 2 is a micros¢ short-focus telescope—for noting the instant at which the ! of the concave surface of the fluid crosses the line J on the we This microscope after the observation has been made should lowered exactly the distance IJ, so as to observe the instant passage across the line at J, the interval between the two ™ the time of efflux (7). A chronographic record of these inst is the more satisfactory. The valves X and LZ should be closed immediately on the term ation of an experiment, so that impurities may not entet © - The figure is not even approximately to-scale; it is essentially oO . VISCOSITY OF WATER BY THE EFFLUX METHOD. 143 capillary. It is almost unnecessary to say that the water used in the flow should be most carefully freed from organic particles. The pressure and temperature, which should be sensibly constant, ought to be read at intervals during the efflux, and also the height of the surface of the water in the heating vessel above J and J at its commencement and termination, the latter in order to afford material for correcting the pressures registered in the manometer. The terminals A B of the capillary must be set exactly horizontal, say by means of a cathetometer, and the parts K to A and Bto # firmly connected’ with the heating vessel, in such a way however as to permit of their adjustment—not shewn in Fig. 4. hd The tube BZ serves to ensure constancy in the terminal con- dition of the efflux. It should be mentioned that the method of allowing the effluent to drop from the tube terminal is unsatis- « The corrections to the immediate data of an experiment are :— (#) Corrections of the thermometers. (6) Reduction of the pressure registered in the manometer on account of the pressure conditions in the apparatus. In regard to (a) if we propose a precision of a higher order than lina 1000, we must read to -001 degree C., and therefore must - follow the methods of rigorous thermometry. With respect to {b):—if the bulb V be symmetrical in form, then since the general height of the water in the bath is not sensibly altered by the addition thereto by the efflux, we have—putting / for the height _ of the water surface above J at the beginning of the experiments _ 4nd Xi’ for the similar height above J at the end—for the mean __ Pressure Px fon te 1). ae ee sh sr P=g (nH-p@*") (45) H being the mean value of the sustained column in the manometer, ee * See Mém. des Say. é : tt 2 . . trang. t. 9, § 10, p. 440. Also Hagen, Abhandl. Akad. Wiss, Berlin, 18, P. 398. 54, p. 17 ete.: and Meyer, Wied. Annal., Bd. 2, 144 G. H. KNIBBS. p the density of the mercury therein, and p that of the water, both — at their own temperatures at the time of the measurement.’ As already pointed out no correction for change of dimensions in bulb or capillary is needed, but these must be given for 4 common temperature. The only further corrections then are :—(c) the correction for — fall of pressure at the entrance of the capillary, (d) that for fall in pressure producing the flow in the tube J A and B Z, and(@)a — possible correction to the length of the tube to equate the terminal ‘ resistances—§ 9. Of these (c) and (e) have been already fully discussed: (d) only requires attention. Let R and S§ denote — respectively the radii of the capillary and supply tube, and Z and : Z their lengths, then the fall in pressure p, in the tubes JA + BE : a= ey =. (46) This must be so small as to be practically negligible. ; 29. Dimensions of apparatus.—The general principle which — determines the relation of the several parts of the apparatus is that the resultant precision should be uniform throughout. The following measurements are merely suggestions as toa suitable — size for the essential parts : ‘they serve also the purpose ¢ of illus trating the application of the above principle. We shall assum E for g the value 980°6 c.m. and for p 13-5958. : Pressure in manometer H = 100 cm. mercury: hence P= 1333200 : Radius of capillary R=0 ‘Olem. Length 2=50 cm. Bulb V in Fig 4 Q=50cem. Rad. bulb 2:28 cm, about Supply tube not less than S=0-lem. Totallength Z= 25 cm. say a In apparatus of these dimensions the fall in pressure in the | supply tube J A+B a Z will be not more than = pein ea ‘ 3 i ae Sey aD le (Fu)* x ae 133320 = 67 or 1/20000 th. formula (46). The rate of flow even for 0° C. would be sulticiently ee 1 The variation in the loss of pressure at the entrance to the tube is? small that it may be computed from this mean pressure, without ici VISCOSITY OF WATER BY THE EFFLUX METHOD. 145 rapid to allow of a record to a small fraction of a second,' whereas the total time of efflux is more than 8000 seconds or over two hours. The correction of the efflux time for fall in pressure at the entrance of the tube is about 24900 sec./7’, or about 1/2700th for 0° C.—formula (5)—or the correction to be applied to the deduced viscosity about 0:0445/7'—formula (40)—-so that a small uncertainty as to its proper magnitude will not greatly vitiate the result. The volume of the bulb V would be ascertained readily and with sufficient accuracy from its capacity, by using quicksilver. The measurement on the accuracy of which the result mainly depends is the capillary radius, 0-1 millimetre.. To obtain its value to considerably under 1/10000 th part? is not an easy task. The whole volume of the tube represents only 0-214 gramme of mercury, so that on this element of the work—zi.e, the evaluation of the ‘mean radius of efflux’ of the tube—by far the greatest expenditure of effort to attain precision will be required. This applies when the absolute determination of the viscosity is required The following series of experiments seems to me to meet the requirements of a thorough determination : Temp. every 5°, 10°— 95°C.; H = 100; LZ = 50 every 0°.5,0°-10°C. H= 50; L = 50 and H = 100; ZL = 25 also at 4°C. H = 100, 50, and 25; Z = 50 and H = 100 LZ = 50, 25 and 125 Such @ series ought, with care as to dimensions, careful ther- mometry and generally good manipulation, to satisfactorily settle . MAREE SOR ‘1The supply tube may be of any convenient size, but it is always “mad that at the points I and J the velocity shall be sensible when ed by the microscope R. If constricted great care should be taken that then nstricted diameters are equal so that the concavity of the water may be the same at each point. y ding to a precision of over 1/2500 th. J—Iuly 3, 1895, 146 G. H. KNIBBS. the value of the constant, and determine with precision the form of its variation with temperature.’ 1 J regret that the pressure of other duties prevents me from un taking this task, and of availing myself of the very kind offer of the Professor of Physled—Richand Threlfall, .a.—to place the resources of a his laboratory at the University of Sydney at my disposal for this pur 4 pose. I may be permitted also to express my thanks to that gentleman for some critical observations on the first two parts of this paper. * Ox raz PHYSIOLOGICAL ACTION or raz VENOM or THB AUSTRALIAN BLACK SNAKE (Pseudechis porphyriacus) By C. J. Martin, B.Sc., m.B. Lond. (From the Physiological Laboratory of the University of Sydney. ‘ [Read before the Royal Society of N. S. Wales, July 3, 1895.] I.—Inrropuction. | THe mechanisms associated with the life of higher animals are 8? complicated and at the same time so interdependent, that it is : always a matter of extreme difficulty to ascertain, with anything — 4 approaching to precision, which part or parts of the intricale : machinery are influenced by the introduction of a disturbing element from without. When such disturbing element in th? q form of a poison is introduced, the observer can see without : difficulty the end result, but the unravelling of the process requires | Z the closest observation and the assistance of every met : analysis known to the physiologist. Even then, how far wé are from a complete understanding of the process! Our conception | of the method of operation of any particular poison is necessarily a limited by the present condition of physiological science, and the : most an observer working in any particular corner of this great f field can do, is to attempt to bring the level of knowledge eal, particular phenomena he is studying up to that of the scienc? : generally, and perhaps to elucidate in some small way by obser ee PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 147 yations on particular cases, the larger problems with which physiology is concerned. The research, the results of which form the subject of this paper, was conducted entirely by experiments upon the lower animals. Conclusions as to exact physiological action drawn from the observation of cases of snake-bite in the human subject, while of oy PRE 4 - great importance, owing to ignorance and want of control of so many factors concerned. When con- fronted with a case of snake-bite our principal duty is to treat the patient, and although we may carefully observe clinical symptoms, the employment of those more accurate analytical methods which can be performed on the lower animals, is im- possible. Another disadvantage is that no single observer can hope to witness a sufficient number of cases of snake-bite, but must base his conclusions to a large extent upon the observations of others. | On the other hand, it is true, that it is a mere inference that results obtained upon lower animals can be applied to man. Nevertheless when one considers the identity of mechanism which underlies what differences do exist, together with the fact that the higher mammalia react to snake poisons with striking similarity _ to mankind, the inference would not appear to be an unfair one. I.—Meruops or Inrropuction or THE VENOM. Venom may enter the body by a variety of channels. The time of ee and the train of symptoms vary according to the rapidity “ its absorption. Usually in cases of snake-bite the poison is deposited in the subcutaneous tissues, whence it reaches the Seneral circulation principally by absorption through the blood- oe In some experiments I made with the object of determin- ‘ing the relative absorption through the blood-vessels directly, and ‘“hrough the lymphatics, I found that the symptoms of poisoning ‘Were not appreciably delayed by previous ligature of the thoracic : he poison was in each case injected into the subcutaneous Missue of the thigh. The venom is more rapidly absorbed when 148 C. J. MARTIN. introduced into a serous sac, such as the pleural or peritoneal cavity, and its effects are most rapidly manifested when it introduced directly into a vein. Absorption of venom takes a from such mucous surfaces as the corneal conjunctiva. Whether venoms can be absorbed by the mucous membrane of : the alimentary canal has been much discussed. Weir Mitchell’ came to the conclusion from numerous experiments on pigeons, that Crotalus-venom was not absorbed from the crop. If howevel lly produced, symptoms of poisoning result ing in death occurred. Fayrer? and Richards,® on the other hand, found cobra-venom was absorbed to some extent, from the alimentary canal. Mitchell has confirmed these statements of Fayrer and Richards, but found that absorption through this . channel was very slow. Tie: Fed abrasions were I have repeated Mitchell’s experiments, to determine whether _ Pseudechis venom was absorbed from the alimentary canal. In ; my own experiments I used rats instead of pigeons. 4 Two white rats were fed daily for one week on bread ad i milk, containing one hundred times a fatal dose of vend, supposing it to have been administered subcutaneously. the end of the week both rats were in excellent health. Wi ; half an hour after partaking of the last poisoned meal, ™ mucous membrane of the stomach of one of them was @ i abraded. This rat died in two hours thirty-five minutes wards with the usual symptoms of snake poisoning. : abrasions produced in a rat on unpoisoned diet were fol by no untoward symptoms. The whole of the feces of th rats were collected and examined for venom. The filtrate treated with a large excess (ten volumes) of absolute alcohol, the precipitate which formed allowed to remain under alcohol fourteen days. The precipitate was then extracted ' 1 Researches upon the venoms of poisonous serpents. »_Smith ——— to Knowledge, Vol. xxv1. “Thanatophidia of India.”—Churchill, London, 1872. 3 “On the nature of snake poison and its action on the blood.” PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 149 dilute saline solution. The extract which contained some proteid’was quite harmless when injected under the skin of frogs and mice. If any quantity of the venom had been absorbed by the rats from the amount contained in their meals, they must have shown symptoms, and had the fceces contained any of the venom, symptoms of poisoning would have occured in the small animals injected with the last saline extract, for Psewdechis venom is unaltered by sojourn under absolute alcohol. Accordingly, one must conclude that the venom was either not absorbed, or if so only to a small extent, and that the greater part was destroyed in the alimentary : canal. The venom is destroyed by artificial pancreatic digestion, and that the same happens in the intestine is extremely probable. The toxic properties of this venom are however not destroyed by artificial gastric digestion, and the results of the experiments on the rats show that the poison exists in the stomach in an active | condition. The walls of this organ are lined by a continuous ‘ layer of living epithelium cells, and cannot be reckoned with as if they were composed of a dead membrane. Indeed there is abundant evidence to show that in the process of absorption from the alimentary canal physical processes (osmosis, diffusion) are overborne by physiological ones,! and that the lining cells exere ise 4 selective control over the process of absorption.? The toxic _ Proteids of some of the infectious diseases also, are not absorbed from the alimentary canal, for Tizzoni has shown that the most “irulent tetanus toxines produce no ill effects when administer ed by the mouth, Absorption does however probably occur to 4 Small extent, for the remaining white rat, was after the lapse of 5 week, injected with one and a half times a lethal dose of venom, — Jenaische Zeitschrift, Bd. xviii, 1885; Rohmann, hi. 1894 v., Bd. xli. 1887; Heidenhain, ibid., Bd. xliii., 1888; Bd. 2 ‘ ‘hes Tappeiner, Wien. Sitzungsberichte, Bd. Ixxvii., Abtheil. iii., 1878; edkins, Journ. of Physiol., x1r., 1892; v. Mehring, Ver —— Congress £. imnere Med. z. Wiesbaden, 1893, p. 471. 150 C. J. MARTIN. This resistance may be accounted for by the immunising effect the absorption of small quantities of venom from its food during the previous week. Before considering the experimental results obtained animals it is necessary to emphasise the fact that the effects of venom introduced directly into the circulation may be ver different to those which follow subcutaneous inoculation. These differences although no doubt essentially dependent upon tl varying rapidity with which the poison reaches the blood, are from the peculiar nature of its action on this fluid, of such a kind as to be misleading, On reference to the portion of this paper devoted to the consideration of the action of snake-poison on blood-plasma it will be seen that the venom of Pseudechis if introduced with adequate to cause thrombosis, either when directly introduced into the circulation or if subcutaneously injected in sufficient quantity in a situation favourable for absorption. When one sees an animal, within a few seconds or minutes after the introduction of the poison, seized with convulsions 0% which artificial respiration has no influence, and closely follo by death or a condition of profound depression, one might natur imagine that the poison had exerted its influence directly the nervous system. In the case of such symptoms following introduction of the venom of the species of Australian snakes have hitherto examined, such a supposition would be erro for by opening the animal just prior to death, the venous SY would be found to be the seat of more or less extensive throm» Intravascular clotting is also in my opinion the exp. the convulsions which have been observed by Wall’ and othe® to rapidly follow the introduction of viperine venom into Ma" ws and which form such a marked feature in the experiments ip os Wall, Indian snake poisons, their nature and effects.—Allen & ; ndon, 1883; Proc. Roy. Soc,, Lond., Vol. xxx11., 1881. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 151 the venoms of this class of snakes. Such early convulsions must not be confused with those due to failure of the respiration, which immediately precede death from cobra poisoning. With subcutaneous injection, the venom does not, as a rule, reach the blood with sufficient rapidity to occasion any extensive thrombosis, but under these circumstances the blood is found to have its coagulability greatly diminished or lost. These opposite conditions are in reality two phases of the same operation. As thrombosis in different regions of the circulation produces a great variety of sudden and surprising effects, which are generally absent after subcutaneous injection of the poison, the comparison of results obtained by the two methods of introduction of venom must be made with a due amount of caution. III.—Actioy or VENom on THE Bioop aNp Boop VESSELS. Through whatever channel the poison may be absorbed it sooner : or later reaches the blood stream, and is distributed thereby through all the tissues and organs of the body. Accordingly it is necessary to ascertain in the first place what changes it may occasion in the blood itself. Without such knowledge it-would be impossible to differentiate those effects produced on the various organs of the body which are to be attributed to the primary Sf Spération of the poison from those which are secondary to its Interference with the normal constitution of the blood. When the literature of this part of the subject is examined, one Notices the entirely different results obtained by observers experi- eating with various kinds of snake poison. Cobra poison would ‘Appear to exert little effect upon the blood, but that it does have Tome XXXVL, .) . 154 C. J. MARTIN. exhibited no ameeboid movements. At the end of this time # nuclei in some of them were very distinct, as if fixed by swell and their outlines to grow less distinct until they disappeared, leaving a small heap of granules to mark their grave. D this time, control specimens situated under similar circumstane showed no change, and the leucocytes were exhibiting acti amceboid movements. The action of the poison on the corpuscles of pigeon’s bood similar to the above, but the dissolution of the red cells, ' poison of this concentration proceeds more slowly. The blood corpuscles of different mammals present remarkable diversity in their power of resisting the destructive effects of venom. Dog’s blood is much more sensitive to this action of the venom than that of any other animal I have experimented Wi : The readiness with which the corpuscles of this animal aré troyed approaches that of the frog. Some idea of the small quantity of venom which is neces to determine the destruction of the red corpuscles of dogs m gathered from the fact that if 1 c.c. of fresh defibrinated blot be mixed with an equal volume of ‘9% NaCl solution con tal "0000002 gramme of venom, and allowed to stand for four hou at the temperature of the laboratory (15° C.) the serum w covers the corpuscles becomes deeply stained with haemo and if a little of the sediment be examined under the mic numbers of crystals of haemoglobin are to be seen, togeth' Some corpuscles. A control specimen under similar circums except that the salt solution contained no venom, showed corpuscles to be well preserved and the serum was only § tinged with haemoglobin. If the concentration of venom in the solution be im the blood be kept at body temperature, the haemoglobin out much more readily, and in a few hours no corpuscles found. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 155 Haemoglobin which has been dissolved out of the corpuscles under the influence of the venom possesses a more than ordinary tendency to crystallize, as is exemplified by the following experi- ment :—10 c.c. of defibrinated blood of a dog were poured into a dry test-tube containing ‘0001 gramme of venom, and placed in an incubator at 38°C. over-night. When examined in the morning the contents of the tube were solid with haemoglobin crystals, so that the mass could only be removed with a spoon, The haemoglobin in the crystals was in part converted into methaemoglobin. A solution of well washed crystals showed the absorption spectrum of methaemoglobin as well as oxyhaemoglobin, so that it would appear that both derivatives of haemoglobin were present together in the crystals. As time went on, the amount of oxyhaemoglobin in the crystals diminished and that of methaemo- globin increased. This conversion of oxyhaemoglobin into methaemoglobin does not occur under the influence of the venom itself but is due to organisms. It occurred in all the control tubes which were not sterile, but took place in these much Jater than in those that con- tained venom. This is probably to be explained by a much greater growth of the organisms in the blood which had received a small admixture of venom. I shall presently show that venom destroys ' the power possessed by normal serum to inhibit the growth of Some micro-organisms, which would explain why they should grow more readily in those test tubes to which venom had been added. : The process of corpuscle destruction can be observed on a warm : Stage under the microscope, in the same way as with frog’s blood. : When mixed with salt solution containing ‘017, of venom the field is markedly coloured with haemoglobin after thirty minutes. Tn two hours the corpuscles are largely destroyed, and in ten hours have entirely vanished and crystals of haemoglobin sabe — They do not swell up, but become globular, the haemo- globin passes out of them and the stromata become less and less distinguishable until they can no longer be discerned. 156 c. J. MARTIN. As I shall presently point out the same extensive destruction of corpuscles occurs when the venom is injected into dogs | quantities of -0001 gramme per kilogramme of the animal’s weight or even less. The lowest limit of concentration necessary to r0- duce this destruction is about the same both within the body 3 in vitro, viz.:—-00001 gramme of venom per 100 C.C. of blood! The corpuscles of rabbits, guinea-pigs, cats, and white rats: ae my own blood, even when this was kept at body temperature When the strength of the venom was increased much beyond this amount, disintegration of corpuscles occurred, but proceeded slowly. The disparity in the amount of blood destruction following injection of the venom into animals of different species, products a corresponding variation in symptoms, and is associated with marked difference in their susceptibility to the occurrence of intravascular clotting. Dogs are, weight for weight, about ten times as sensitive to this action of the poison as any other mammal with which I have experimented, (6)—Ezxamination of the blood of animals after the injection Y venom. The injection of much above a minimum fatal dose of ve produces some destruction of red corpuscles in every animal which I have experimented. When dogs are the animals however, destruction of red corpuscles is very considerable & with one-fifth a minimum fatal dose, and the escaped haemog presents the same increased tendency to crystallize as I have cribed to be the case in vitro, The haemoglobin crystallizes within the body. The urine nearly always contains such and on three occasions an animal has died two or three days the injection of the poison with suppression of urine, and ! Raa nea ey iE _ =o at this conclusion I have assumed that on animal’s weight consisted of blood.—(Welcker) PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 157 scopic examination of the kidneys has shown the tubules to be completely blocked with haemoglobin crystals. Haemoglobinuria is a frequent symptom with animals of other species, except with minimal or sub-minimal doses. Professor Halford and Dr. Ralph many years ago noticed changes in the corpuscular elements of the blood of animals which had died from the bite of the Australian tiger-snake (Hoplocephalus curtus). Their attention was particularly drawn to the enormous number of leucocytes together with granular debris present under these circumstances. They described the leucocytes as frequently heaped together like masses of grapes. Halford also described some large transparent nucleated cells which he found in the blood of animals eight to twelve hours subsequent to death from snake-bite, but which were not present immediately after that event. Halford at one time attached considerable importance to these cells, which are indeed swollen leucocytes, the condition of which must be attributed to post- Mortem phenomena. ‘They are, moreover, as was ‘first pointed out by Dr. Ralph, of Kew, Victoria, also seen in the blood of animals poisoned by prussic acid, when it is examined at a similar interval after death and cannot therefore be considered as patho- gnomonic of snake poisoning. On examining the blood of animals, immediately subsequent to death from the injection of Pseudechis poison I have, except in those cases which have succumbed within a few hours after the injection, always found increase in the number of leucocytes and the occasional gathering together of these in grape like masses. (¢)—Observations on the Hone S corpuscles after injection of nom To obtain a measure of reg ‘Wan to which the red cells are _ destroyed, and also of the progress of the leucocytes, under the influence of Pseudechis poison, I have made a series of observations : ~ the number of both the red and the white corpuscles present in the circulating blood before, and at different periods subsequent to the injection of the poison. : 158 - Cc. J. MARTIN. The animals used were dogs and in all cases the number of the red corpuscles was diminished. The diminution commenced directly the poison reached the circulation, and progressed to such an extent that in some cases the number of the red cells was reduced within a few hours to less than one half of that originally present. As regards the leucocytes, I expected to obtain evidence of some : degree of leucocytopenia immediately following the injection of the poison, and preceding the onset of the leucocytosis which had ‘been observed in the later stages of poisoning. I was surprised — however to find that when the venom was introduced directly into the circulation a great decrease in the number leucocytes, amounting in many cases almost to their complete disappearant -occurred immediately after the injection. This disappearance of ‘the leucocytes from the circulating blood was, however, only temporary, and, in a time varying from one-half to five hours, their number in samples of blood slowly increased until it reached | and often far exceeded the quantity originally present. I have always observed this extensive diminution in the number of the leucocytes in those cases where the poison was introduced directly into the circulation. - Such a sudden disappearance of leucocytes from the circulation : is not, however, peculiar to snake venom. A precisely similar result has been observed to follow the intravenous injection peptone (albumoses), and Sampson Himmelstjerna,’ 4 pupil of se Alexander Schmidt, attributed the diminished coagulability peptone blood to this absence of leucocytes. Lowit? and Wrigh e have also drawn attention to the same fact. Both of these authors were of opinion that the diminution of leucocytes was tot -accounted for by active leucolysis. Leucocytes are, however, no -disintegrated in vitro by solutions of venom or of peptone of much greater concentration than they would ever encounter in the OF ae -cumstances under which these bodies were injected into the vel” 2 * Inaug. Diss. Dorpat., 1882. ? Stud. zur Physiol. u Path. des Blutes, Jena, 1892. ws 3 Proc. Roy. Soc. Lond., Vol. u11., 1893. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 159 Rieder! has, on the other hand suggested, and Bruce* has _ adduced evidence to show, that these cells are not destroyed but only temporarily withdrawn from the circulation, and are to be found crowding the tissues of the liver, lungs, and medulla of bone. A similar temporary disappearance has also been found to follow the intravenous injection of a variety of other bodies among which may be mentioned nucleo-albumens,’ nuclein,* tuber- culin,® bacterial proteins,® and carmine in suspension.? With all these bodies the leucocytopenic phase is soon followed by one in which the number of leucocytes is increased. The cause of this disappearance of leucocytes after intravenous injections of venom, I am inclined for the following reasons to attribute to their collection in the tissues, and not to their rapid destruction :-— : (1) Solutions of venom one thousand times as strong as any they could possibly come in contact with in the blood-stream, under the conditions of the experiment, exert no disintegrating effect upon them in vitro. (2) It is almost inconceivable that the rapidity of their dis- Sppearance and reappearance can be explained, if one supposes them to be destroyed. In one of my experiments, a sample of blood taken immediately after the venom injection was so devoid of white cells, that it was necessary to search through many hundred ‘Squares of the haemocytoineter in order to find one ; whereas a oe mmple of blood taken fifteen minutes after from the same Animal contained nearly as large a number as was found previous ‘to the injection, (3) Sections of the organs especially the liver and lungs appear to contain an excessive number of leucocytes. (I have not made “@ny accurate quantitative observations. ) 7: Beitriige z. Kenntniss d. Leucocytose, Leipzig, 1892. th verte Soe. Lond., iv., 1894. urton & Brodie—Journ. of Physiol., 1894. 5 Tehisto wski, M. f. Chem., Vienna, 1891, Vol. x11., p. 221. 4 witsch, Berlin Klin. Woch., 1891, p. 838. chner. 7 Werigo, Ann. l’Inst’ Pasteur, 1892. 160 C. J. MARTIN. (4) It occurs to a trifling extent only, when the poison is cutaneously injected. Sherrington! pointed out that most of the substances which when intravenously injected occasion marked leucocytopenia also lymphagogues. Bayliss and Starling? demonstrated lymph flow was a function of capillary blood pressure and the latter depends much more upon venous than on the arterial pressure in the region concerned. The injection of venom intot circulation produces an immediate diminution of blood flow, low arterial and high venous pressures, and it appears to me improbable that such a condition of diminished flow together WI high pressure, is accompanied by greatly increased diapedesisa corresponding decrease of circulating leucocytes. If the animal continues to live, the arterial blood pressure, after an interval of a few minutes, steadily rises and the number of leucocytes in the blood concurrently increases. A mechanical - explanation however, insufficient, for the introduction of fine particles carmine produces no alteration in the circulation, but is never: theless the cause of the collection of leucocytes in internal organs. The experiments form two series: (1) In which the venom ™ introduced directly into a vein; and (2) In which the venom ™ injected subcutaneously. Enumeration of the corpuscles was accomplished in the follo’ way :—0°5c.c. of blood just withdrawn from an artery, was up in a carefully graduated pipette and mixed with 99°5 c.c. 8% solution of MgSO, slightly tinged with methy! violet. drops of the mixture were placed in the cell of a haemocyt® and the red corpuscles in ten squares and the leo hundred squares of the instrument, counted by two 0D® The numbers counted by each observer usually agreed ie and the numbers given in the protocols are the means ns 1 Proc. Roy. Soc - Lond., tv., p. 197. 2 Journ. of Physiol. xvr., 1894. 3 The number of corpuscles in ten squares multiplied by ten tl gives the number in one cubic millimetre of blood. a PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 161 observations. In those few cases where there was any marked disagreement, two more counts were made, and the average of the whole four observations was adopted. Protocols of Series 1. Ex. I.—Slut, weight 6-8 kilos. ; grain 1 of morphia acetate sub- cutaneously injected. 4:10 p.m., samples of blood drawn. 4:20 000025 gramme of venom per kilo. of body-weight injected into jugular vein. 4°35 ,, same quantity injected. 455 ,, same quantity injected. 457 ,, sample of blood drawn. 735 ,, sample of blood drawn. 100 ,, sample of blood drawn. ” Number of Corpuscles. Red in10 | White in 100 squares. Time. squares. Before injection of venom ... 540 24°5 87 minutes after first injection ve venom.. 466 35 hours 15 minutes, do. do. do. ... 296 2 A ee ee. ee ee Ex. II.—Dog, weight 8-2 kilos.; 2 grains morphia acetate. 3°50 p.m., sample of blood taken. 40 ‘000025 gramme of venom per kilo. of body-weight injected into jugular vein. 410 ,, sample of blood drawn. 420 ,, sample of blood drawn. 50 ,, ‘0001 gramme per kilo. injected. ” 60 ,, sample of blood drawn. os sample of blood drawn. : : Hamber of et Time, | Red 2 10 | White in in 100 Defense. ‘ie ioctice ee ce =e 603 i 105 10 minutes after injection | 517 | be 20 minutes after injection | 497 15 Shoursafter injection .. | 414° | 7S 5 hours |» hours after injection ae 365 wae 5 a ee) 2 se K—July 3, 1895, 162 C. J. MARTIN. Ex. III.—Dog, weight 15 kilos. ; 2 grains of morphia 2 injected subcutaneously. 12°35 p.m., sample of blood drawn. 12-40 ,, -000025 gramme of venom per kilo. of body we injected into jugular vein. 12:55 ,, sample of blood: drawn. 1:0 ,, :00005 gramme venom per kilo. injected. ~ 1D so sample of blood drawn (coag. 38 mins.) 1:20 ,, 00005 gramme venom per kilo. injected. 1°22. ,, dead. Number of Corpuscles. {oh 0 | White in 100 | squares. Time, squares. Before injection of venom __.... 684, 21 15 minutes after injection... 550 16°5 _35 minutes after injection... 604 | 1407 Ex. IV.—Dog, weight 10-3 kilos.; 2 grains morphia injected subcutaneously. 12-50 p.m., sample of blood drawn. 10, 000025 gramme venom per kilo. of body ' injected into jugular vein. 110 ,, sample of blood drawn. ey sample of blood drawn. 30 ,, sample of blood drawn. 40 ,, sample of blood drawn. 50 ,, sample of blood drawn. Number of Corpuscles. : ee ee * Red in 10 | White in 100 Time. squares. squares. Before injection... ...... 564 15 10 minutes after injection 483 1 1 hour after injection 421 65 2 hours after injection 369 35 3 hours after injection re 322 10° 4 hours after injection... ...) 297 155 PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 163 I next made some observations on the number of red and white corpuscles in animals which had received a much larger quantity of venom, but in which the poison was subcutaneously introduced. The amount given was such that some of the animals recovered, while others succumbed. The experiments show the same diminu- tion in the number of red corpuscles. The quantity of white corpuscles increased almost immediately after the injection of the poison. The leucocytosis reached a maximum on the second or third day of illness, when the leucocytes were often present in four or five times the normal amount. The number from this time onward gradually decreased, but the leucocytosis persisted to some extent, in the single case in which observations were taken over so long a period, for a fortnight after the complete recovery of the animal. The number of the red cells was least, twenty-four to thirty-six hours after the introduction of the poison, at which time they were reduced to about one half their normal number. This decrease in red corpuscles was associated with the passage of a large quantity of haemoglobin into the urine. The urine often had the appearance of blood, but contained few or none of the red cells. .The bile also, in those cases which died contained haemoglobin. Series II. In these experiments 5 cub. m.m. of blood were taken from the _ ear and mixed with 995 cub. m.m. of the MgSO, solution and the _ Corpuscles counted as before. Ex. I.—Dog, weight 7:7 kilos. Sep. 21, 11-25 a.m., sample of blood taken. ae 11:30 ,, injected subcutaneously in lumbar region with 023 gramme venom. ie 12-0 ,, sample of blood taken. és 30 p.m., sample of blood taken (urine pare haemoglobin). ; « 50 ,, sample of blood taken (walks with difficulty). 164 Cc, J. MARTIN. Sept. 22, 8-30 a.m.,(more lively, had passed half a pint of haemo- globin stained urine during night). 12:0 mid-day, sample of blood taken, (drank one pint ; of milk, diarrhea). 530 (lively, runs about, drinks plenty of milk, urine contains haemoglobin). ” = 12-0 mid-day, sample of blood taken. eee (quite lively but weak, urine contains haemoglobin; eats well), sample ds blood taken. » 25, ” (urine contains haematin and albumen), sample of blood taken. » 26, ” apparently well, urine albuminous, sample of blood taken. er ane = Nee eeee » 27, 9 (urine albuminous), blood examined. » 28, ” (urine contains a trace of albumen), blood examined. » 29, 9 urine normal, blood examined. Oct. 1, oy blood examined. Number of Corpuscles. : Red in 10 | White in 100 Time, waeitils squares. Peta Before injection ... eee oc 583 | 20 30 minutes after ... ee os 503 18°5 urs after 427 36 5t hours after 365 | 48% 1 da 202 46°5 2 » 217 65 Be is 197 80 4 ” 237 | 73°35 . os 264 | 79 6 ”» a: 294 54 342 48°5. 8 ” 346 49 10 » 358 48 14 a 402 | 39 PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 165 Ex. I].—Dog, weight 11-5 kilos. 11:25 a.m., sample of blood taken. 11:30 a.m., (0065 gramme venom injected in lumbar region, 10 p.m., sample of blood taken. 3°30 ,, sample of blood taken. 50 ~=,, sample of blood taken. Number of Corpuscles. ee Red in10 | White in 100 Time. squares. squares. Before injection ... Be a 540 12 1} hours after... $e Se 492 15 4 hours after $6 if iB 441 31 Sthoursafter ... _... ae 402 33 Ex, III.—Dog, weight 11:2 kilos. Sept. 29, 10-30 a.m., sample of blood taken. ” 10°35 ,, ‘Ol gramme venom injected in lumbar region. ” 5°0 p.m., sample of blood examined (had vomited, and passed urine stained with haemo- globin). » 30, 10-0 am., sample blood taken, (very ill, refuses food but drinks eagerly; can walk . with difficulty. Urine contains haemoglobin). Oct. 1, 10-0 a.m., sample of blood taken, (condition the same). ss sample of blood taken, (condition worse, urine intensely coloured by haemoglobin). The dog died during the day. Number of Corpuscles. i Red in 10 White in 100 Time, ‘< squares, SRE TAREE hans ere ee Ee Before injection .. .., ...| 548 16 Shoursafter .. ... ...| 967 34 = Fs Hes ag Sosa 57 48 ‘ oe tec omer ree 67 | es oe ve Retina ON TS A tae ane e 166 C. J. MARTIN. Ex. LV.—Slut, weight 8°4 kilos. 10°0 a.m., sample of blood taken. oS 10:30 ,, 01625 gramme of venom subcutaneously injected — : in lumbar region. : 11°50 ,, (very drowsy, vomited, shivering). a 12°30 p.m., sample of blood taken. ' 3°30 ,, delirious, temperature 99-4, heart irregular. 60 ,, (comatose, temperature 95-6) 8:0 ,, sample of blood taken. | 90 ,, (comatose, temperature 90-3). 4:0 ,, sample of blood taken, (comatose). : i 100, “hed, Number of Corpuscles. | | Red in10 | White in 100° : = ian | oan Before injection ... het aA 546 155 4 2 hours afterwards bs te 471 25 54 hours afterwards _ Bess 382 27°5 9: hours afterwards me 361 | : au I have mentioned that venom, when mixed with blood on # ( slide prevents the display of amceboid activity on the part of _ . white cells. That the same interference with the vital activity experiment, which is one of a series with similar results. Two small pieces of sterilised sponge about 1 m.m. cube were aseptically introduced into the abdominal wall of a guinea-pis: One of these little sponges had been soaked in a “77% solution NaCl containing | %, of venom, the other in the saline without the venom. Both sponges were pushed about a centimetre awa) from the incision, which was afterwards drawn together by [ horse-hair suture, and covered with collodion. After two hours swelling arose round the venom-containing sponge, whereas © | other remained of the original size. At the expiration of five hours the animal was killed and both sponges very withdrawn and plunged into absolute alcohol. AO je coat’ in eas ee z a ‘methods of handlin PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 167 Sections of the two sponges treated in the same way presented very different appearances. The control was infiltrated with leucocytes which stained well with ordinary nuclear stains; the other contained leucocytes only near the margins, and many of these were broken down and took the stain badly, or not at all. From these sponge experiments I conclude that whereas into the control sponge the leucocytes could by their amceboid move- ments penetrate unharmed, in the other their activity was paralysed, they succumbed, and were eventually disintegrated by the solution of the venom. To recapitulate : the effects of the venom when introduced into the body on the blood corpuscles are :— (1) More or less destruction of the red corpuscles, the haemo- globin of which escapes by the urine. (2) A great increase in the number of leucocytes which may be preceded by a certain amount of diminution. (3) Inhibition of the vital activity of those white cells which come into contact with the venom in sufficient concentration. Alterations in the blood-plasma after the injection of venom. In the previous section of this paper I have shown that venom exerts a destructive action upon the red blood corpuscles whereby their disintegrated products are set free in the plasma. The haemoglobin circulates in solution in the plasma and is eventually discharged by the urine and bile. I do not know that there is any evidence that haemoglobin exercises any baneful influence by its presence in plasma, and I have not noticed any ill effects to follow the injection of two or three grammes of well washed crystals, dissolved in ‘9% NaCl solution, into the circulation of : The remaining portion of the red blood corpuscle, the Stroma, consists of a highly complex substance which by various : g may be made to yield products which are not 80 Innocent, By extraction with various solvents, stromata yield cholesterin, lecithin, a globulin, and a proteid compound of nuclein, which is — 168 C. J. MARTIN. compared by Wooldridge,' who first separated it from stromata, to the substance found by Plosz in liver cells, and named by nucleo-albumen. Wooldridge refers to this body as—* Eiweisskérper der mit einem anderen an phosphor reichen moleeil verbunden ist.” He came to this conclusion from the fact tha by digesting this body with gastric juice, peptone, and a phosphor ous-containing body which he compares with Miescher’s nuclei, were formed. It would be an unwarrantable assumption to suppose that when venom is injected into the blood stream, it produces precisely the same decomposition in the stromata as can be effected by extract ing blood corpuscles with ether, alcohol and sodium chloride solution outside the body. Nevertheless we have evidence, as will be seen shortly, that bodies of the nature of nucleo-albumens are, under these conditions the part result, and that some of the changes which the plasma undergoes, after the introduction snake venom into the circulation, are to be attributed to the presence of these particular products of the disintegration of the red corpuscles. : oe Effect on the coagulability of dog’s blood. In the general enquiry, I have frequently had occasion to Us such methods as are commonly employed for obtaining grap! records of the blood pressure in arteries and veins, and have P struck with the remarkably satisfactory manner in which blood has behaved as regards clotting. On more than one 00 a tracing of the venous pressure in.a dog has continued for hours, without coagulation occurring in the cannula. : This behaviour suggested some inhibition of the normal clot power of extravascular blood. During several experiments, accordingly drew samples of blood. In all of these coast was retarded, the specimens clotting only after the lapse of - to twenty hours, or not at all. At this time I was working ¥ as 1 Du Bois Reymond’s Archiv. 1881, p. 387- PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 169 the intravenous injection of very small quantities of the poison, viz.—0-00001 to 0-00002 gramme per kilogramme of body weight.’ Tam aware that such an observation on the fluidity of the blood, following the introduction of snake poison into the system, is by no means new. Fontana,? more than one hundred years ago, noticed that the blood remained fluid in animals dead of viper bite, and Brainard,® writing forty years back, states, that when death occurred im- mediately (the italics are mine) in animals bitten by rattle snakes, the blood was found at the post mortem examination to be clotted, but if some time elapsed before the animal succumbed, the blood remained fluid in the vessels. These observations of Brainard “were confirmed by Weir Mitchell* in 1860, who explained the difference by the hypothesis that in cases of very rapid death the poison had not had time to affect the blood. A few years later, Halford’ observed the same continued fluidity of the blood to follow the injection of the venom of some Australian species.° More recently Feoktistow’ has confirmed Fontana’s observation on the condition of the blood after the injection of viper poison (V.ammodytes and V. berus ). The continued fluidity of the blood after death from the bite of the Indian viperine snakes, has been frequently noted during past years by numerous observers in that country, and contrasted with the negative results in this respect following the injection of cobra poison in animals. In death from rss rs ' The weights refer to the poison in the dry condition. The method of acquiring the venom has been described in a previous communication in eonjunction with Mr. McGarvie Smith.—Proc. Roy. Soc. N.S.W. 1891. ?“ Fontana on Poisons,” Translated by J. Skinner, London, 1787. 3“ Smithsonian Reports,” 1854. : Smithsonian Contributions to Knowledge,” Vol. xu. : apa Times and Gazette,” 1873, Vol. 11. dimi uite recently Dr. Skinner of Beechworth, Victoria, has recorded — coagulability of the blood during life, in a case of snake bite occurred in his practice.—“ Australian Medical Gazette,” March 170 Cc. J. MARTIN. cobra bite in the human subject the blood is however very frequently fluid, and non-coagulable. On other occasions, when taking carotid pressure tracings during the injection of larger doses of venom (0-0002 gramme per k or above this quantity), within a minute of the time when the poison was introduced, the record of the rise in pressure due to the heart’s beat disappeared, but the pressure in the manometer remained considerably aboye zero. On investigation it was found that there were no clots in or near the cannula, but in each cas? the artery, at some little distance from the cannula, contained ® solid core of clot extending into the aorta, and left ventricle. On — further dissection, the blood in the whole vascular system, except ing only the pulmonary veins and the left auricle, was found to be solid. The clot in the portal venous system was particularly = hard. These experiments I have repeated very many times, in : fact one or the other phase of coagulability occurs every time this . i snake poison is injected into a vein of a dog. ! Pseudechis venom is not the only kind of snake poison which influences the coagulability of blood-plasma. From the examine tion of the literature of snake poison in the light of knowledge gained from the above experiments, I felt convinced that some the results obtained by other observers working with different venoms, which results they attributed to quite other causes, ¥™ in reality due to intravascular clotting. Within the last : also, [ have had the opportunity of reading a paper by Heidens dealing with the same subject. This author found that Cro venom first raised the tendency of the blood to coagulate, that this increase was followed by a diminution in coagula He was of opinion that an excessive increase of coagulability ¢ occasion considerable thrombosis and the death of the 90” Heidenschild considers that the sudden death from large — venom which has been-observed by so many experimenters ¥° be explained in this way. : 1 Untersuchungen iiber die Wirkung des Giftes der Brillen und def Klapperschlange—Inaug. Dissert. Dorpat 1886. ee esha i Fs c to observe it, PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. ye Owing to the fact that Heidenschild’s results formed the subject - of an inaugural dissertation, and were not as far as I am aware, published in any journal, I had not the advantage until recently of consulting his paper in Sydney, and I regret that on this account I omitted to mention his work in a previous publication of my own on this particular aspect of the physiological effect of the injection of Pseudechis venom.! We were however, both forestalled by Fontana,? who more than one hundred years ago noticed that in those experiments which were followed by the sudden death of the animal, the blood was solid throughout the greater portion of the venous system, and who expressed his opinion that the clotting of the blood in the living animal caused death by arresting the circulation. Fontana, as previously mentioned, also noticed the permanent fluidity of the blood in other cases of viper poisoning, and he would appear to have wondered greatly that two such apparently opposite effects could be produced by the operation of the same agency. Immediately after the introduction of the venom into a vein, the coagulability of the blood increases, and this increase of coagulability, in the case of moderate or large doses (more than ‘0001 gramme per kilo.), culminates in intravascular clotting of greater or less extent. The smallest dose which I have found to produce complete clotting in the systemic circulation was 9:00015 gramme per kilo. Such a dose, however, usually in dogs gives rise to thrombosis limited to the portal vein and its branches, and inhibition of coagulability elsewhere. The injection of small doses,—i.e. below 0-0001 gramme per Kilo.—also gives rise to a condition of increased coagulability of - the blood. This increase however, only manifests itself for an extremely short time, and samples must be drawn within two minutes from the time of the introduction of the venom, in order This transient positive phase is succeeded by a Prone re: Prepac na en 1 Journal of Physiology, Vol. xv., p. 380. Stars -—This observation of Fontana’s was also unknown he Pe er *eently, as a copy of his work was not procurable in Sy 172 C. J. MARTIN. negative phase, for blood drawn three minutes after the injection, either fails to clot at all, or does so only after the lapse of several hours. The negative phase continues for one or two days aitet : the introduction of the poison in dogs which have received a neatly : fatal dose of the venom subcutaneously. . It is interesting to note that the duration of the phase d diminished coagulability corresponds under such cireumstant 4 with the period of blood cell destruction. When this cell destrue ‘ tion ceases, the coagulability of the plasma rapidly returns to the normal. The blood in all parts of the vascular ‘system does not 3 exhibit the same tendency to clot in the vessels, When dogs . are the subjects of experiment, coagulation, when present, always occurs in the portal venous system, and the thrombosis 8 frequently confined to this area. It also occurs more readily : with venous than with arterial blood. Dogs evince varying degrees of susceptibility in this respech the same dose per kilo. producing in one animal intravasculat clotting, in another inhibition of the coagulation of the shed blood. . Results with animals other than dogs. . T have examined the condition of the blood after the intravenoe injection of snake poison in rabbits and cats. In these both positive and negative phases occur as with dogs. Cats apP more resistant to the action of the venom than dogs and rahi ; Conditions modifying the effect upon the blood plasma of the injection of venom. : (1) Influence of Respiration. T have previously mentioned that I have on no occasion 05 : the blood, which has just traversed the capillaries of the lungs participate in an otherwise general thrombosis. Whatevt "= may be effected in the plasma during its passage through : pulmonary veins and left auricle, where it remains fluid, e oo transient for the blood in the left ventricle and aorta is often ae When complete clotting of the blood in both systemic om and veins follows injection of the poison, respiration cont" a PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 173 often for a minute or more after the circulation is at a standstill. If records of the arterial blood pressure and of the respiratory movements be taken in these experiments, the moment of clotting in the arteries is indicated on the tracing, by the disappearance of heart-beats, and the straight line described by the style some distance above the abscissa. I have in my possession a number of tracings showing the continuance of respiration for periods up to two minutes after the circulation must have been completely blocked. These experiments show that as long as the blood will flow through the pulmonary artery and its branches, there is nothing to prevent its normal gaseous interchange, as far as the respiratory movements are concerned. That it takes up oxygen as usual is seen by the colour of the blood in the left heart. To ascertain whether the modification of the coagulability of the blood during its passage through the lungs depended on its altered gaseous condition, I followed the method which Wright used, to determine the cause of the distribution of thrombosis after injections of Wooldridge’s tissue fibrinogen. This observer rendered animals dyspneeic by compression of the trachea previous to the injection of doses, which, as he had determined would, without this treatment, only give rise to a very limited intra- Vascular clotting. The results of injecting “tissue-fibrinogen sg into the circulation when in this venous condition were strikingly altered. My experiments were performed on rabbits of like weight. Several were intravenously injected, under exactly similar circumstances, with gradually decreasing doses of venom, until a dose was found which produced a very limited clotting or hone at all. Other rabbits of the same weight were then rendered dyspneic by compression of the trachea continued for one minute before the subminimal dose of venom was introduced. These Subminimal doses produced in every case complete clotting throughout the whole vascular system. 1 e Journal of Physiology, Vol. x1t., No. 2. 174 C. J. MARTIN. Professor Wright has recently extended his observations an shown that it is the increase in CO, and not the diminution! the contained oxygen, which determines the greater tendency t coagulate which occurs in venous blood.! (2) Influence of Digestion. : I find I have records of eleven experiments in which 0-0002 gramme per kilo. was injected into the jugular vein of ado Seven of these animals died within eight minutes, from extensite venous and arterial thrombosis. Three others died within two hours, and one lived for upwards of four hours. The post mortél examination of this last animal discovered no intravascular clotting and the shed blood remained fluid until it putrefied. In the three which lived from one to two hours after the injection, there a more or less thrombosis of the portal venous system, but the from the rest of the body remained fluid for several hours. These experiments were not performed with the sole object af observing the effect of venom on the clotting of the blood, aul every one of them records, including one of arterial blood press were taken on a kymograph. Consequently I have in each cas the exact time and duration of the injection to refer £95 Inal the experiments the above mentioned amount per dissolved in 2 c.c. of a7 7% solution of NaCl, and the time occup by the injection, as registered on the tracing, was from five eight seconds. ‘The importance of the knowledge that the F injection was fairly constant, I shall discuss later on. At the time of these experiments I attributed the variation results to idiosyncracies in the dogs. On reconsidering the ma ; however, I am inclined to attribute them to the effect of ¢ di The seven first mentioned experiments were performed i ine and the four last also in sequence. During the former was working in the afternoon, whilst the experiments form latter series were performed in the forenoon, and I find that dogs have always been fed at 11 a.m. Thus, for the first’ 1 Proc. Roy. Soc. Lond., Vol. Lv. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 175 dogs which had had a meal three hours previously were used, whereas the last four experiments were made upon animals which had fasted for nearly twenty-four hours. (3) Influence of Rapidity of Injection. The variations in effect caused by alterations in the rapidity of injection are very marked. So much so, that it is impossible to compare the results from different experiments, unless the rate with which the poison is introduced is a constant factor. Intra- vascular clotting is produced most readily if the dose be rapidly thrown into a vein near the heart (e.g. the jugular). On increas- ing the time of delivery of the poison into the circulation, either by employing diluted solutions, or by pressing down the piston of the syringe more slowly, the positive phase (increased coagulability of the blood), is less and less pronounced. Tf the duration of the injection be still further prolonged, the positive phase, if present, is so rapidly succeeded by the negative variation that this latter appears to be the only result. . The negative phase becomes more and more pronounced as larger quantities of the venom are allowed to slowly enter the circulation. For slow injections I have con- nected a burette containing a very dilute solution of venom in _ ‘TY, NaCl with the cannula in the vein, by a piece of rubber tube, the calibre of which was controlled by a screw clamp. With this arrangement I have been able to introduce large doses (0 005 gramme per kilo.), without producing intravascular clotting. The discovery that the effects on the blood plasma after slow : injections, are vastly different from, in fact exactly opposite to, : those following rapid introduction of the venom, explains why, in ‘My earliest experiments, I did not obtain the same fluid condition _ Of the blood as Halford,! who used either subcutaneous injection of the venom, or else allowed a snake to bite the dog. By these methods delivery into the circulation would necessarily be slow, ~ comparable with results obtained by intravenous injection only in cases in which such injection was very gradually 1 Loc. cit. 176 C. J. MARTIN. (4) Influence of previous injection of the venom into an animal, — on the result of a subsequent injection. If a small dose of venom (less than 0:0001 gramme per kilo.) be introduced into a dog, the blood, as previously mentioned, exhibits a for about two or three minutes after the completion of the injee — tion, an increased coagulability. That is to say, samples drawn i! | during this period clot sooner than control samples taken previous 4 to the injection. At the same time the arterial blood pressute falls to one half or one third of its former height. After twenty 4 or thirty minutes the pressure begins slowly to rise, and thirly ‘ minutes to one hour from the time of the injection may have ; reached or even exceeded its original height. During the whole of this period, with the exception of the first two or three minutes samples of blood taken from an artery show very marked retarda- tion in coagulation. If now, one hour or more after the first injection, a second injection containing a much larger quantity (ten or twenty times the first dose) be made, the introduction of this second dosé increases the coagulability of the blood during the subsequent! ht minutes, but samples of blood drawn five or ten nine after the a second injection clot however only after the lapse of | bout and in many cases spontaneous coagulation is altogether in abey- ance. I have always introduced, at the second injection, a quantity of the venom which would inevitably produce complete arterial and venous thrombosis in an animal which had not beet pre viously subjected to an injection of a dose sufficient to establish # negative variation. On other occasions I have given a dog yet a third injec containing comparatively speaking, a very large dose, viz.i— gramme per kilo. This amount, dissolved in 3 c.c. of 77, ™ solution was injected, as rapidly as possible, into the femoral jugular vein. This third injection failed to produce any i ae coagulability of the blood, and the samples drawn immediately after the injection did not clot at all. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 177 It would thus appear that the establishment of a negative variation confers an immunity, as far as intravascular clotting is concerned, against further injections of the venom. This immunity is very speedily produced ; how long it may last I am at present not in a position to say. These facts explain how it is that one can introduce large quantities of the venom into the circulation, provided this be done slowly, without producing intravascular clotting. The first portion of the injection causes a transitory positive phase, 7.¢., increased coagulability, but not sufficient to cause actual thrombosis. This is immediately superseded by a negative phase and the establish- ment of this inhibitory phase confers immunity against the remainder of the injection. Before discussing the bearings of these facts, I shall indicate the results of an examination of shed blood which has been sub- jected to the action of the venom, and of some of the reactions of the non-coagulable blood, itself. Action of a solution of venom on the coagulation of shed blood. To determine whether a solution of venom were capable of exerting any influence upon shed blood, I dissected out three inches of the femoral artery of a dog, and bled from this directly into a solution of the poison. The cut end of the artery was immersed in a ‘9% solution of NaCl, containing 0°1% of venom. ’ By relaxing the compression of the fingers, a small amount of | blood—equal to the volume of the salt solution—was allowed to flow into the vessel. The two fluids were at the same time freely mixed by agitating the end of the artery. The blood began to thicken in fifty-six seconds, but clotting did not proceed in a ‘ormal manner. At the end of an hour, a small soft clot formed, which on shrinking failed to entangle all the corpuscles. The Vessels containing the mixture of blood and venom solution could at no time be inverted without upsetting the contents, as could be done to the vessel in a control experiment with salt solution L—July 3, 1995, 178 C. J. MARTIN. 3 On no occasion have I been able to prevent coagulation altogether, as was done by Weir Mitchell and Reichert! with the venomd the rattle-snake. These authors drew the blood directly intos vessel containing a solution of venom (a stronger solution than : mine), surrounded by a freezing mixture. On allowing the temperature of the blood to rise gradually they found it remained q permanently fluid. , : Examination of samples of blood exhibiting the negative : variation. ‘ Negative phase blood always shows marked retardation in : clotting. The delay is so great in some cases that putrefaction : sets in before coagulation has occurred. The loss of coagulability is the more pronounced the greater the amount of venom which has been introduced. There is not the slightest difficulty in pro ducing this negative phase ; it is only necessary to introduce the poison sufficiently slowly at first, in order that the initial positive variation may not reach the pitch when intravascular = occurs. a ae ey The blood of the negative phase takes up oxygen and gives it up in the usual manner, and with the exception of its loss of spontaneous coagulability, and the fact that some of the heemog!¢ is dissolved in the plasma, does not obviously depart huge -normal. In my examination of this blood, the corpuscles . separated from the plasma by the centrifuge. The — a which the coagulability of the plasmas was diminished % according to the amonnt of venom which had been in eu and also, to some extent, according to the time which had me between the injection of the venom, and the withdrawal of sample of blood. In most cases I found that the greatest of in clotting occurred in blood drawn about an hour after the duction of the poison. By increasing the dose of venom, be i been able to obtain plasmas in which coagulability was m to any degree, from slight delay in the onset of clotting, gett = 1 Loe. cit. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 179 disappearance of spontaneous coagulability. Those samples in which clotting is delayed for a few hours, but which subsequently clot well, I shall refer to as ‘‘ weak negative phases,” while those in which spontaneous coagulation is entirely in abeyance, and which can only, be made to clot under a few special conditions, I shall designate “pronounced negative phases,” but it must be borne in mind that individual samples show every degree of loss of coagulability between these extremes. In plasmas which exhibit only a weak negative phase, clotting can be induced more or less readily by the addition of the following (1) Solution of nucleo-albumen (Wooldridge’s tissue-fibrinogen). (2) Calcium chloride. (3) Dilution. (4) Passage of CO, through the liquid. (5) Alexander Schmidt’s fibrin ferment. These are arranged in the order in which they are most active. As the negative phase becomes more and more pronounced, they lose their capacity to hasten or occasion clotting usually in the inverse order, although exceptions are not infrequent. Ina really | Pronounced negative phase, each and all of these additions are _ incapable of inducing coagulation. Such plasmas contain fibrinogen, for by heating, after previous < neutralisation, they yield a considerable precipitate at 55° C. The : fibrinogen would appear, however, to be present in a somewhat altered condition, for it is now no longer thrown out of solution by half saturation with NaCl. These plasmas although absolutely devoid of spontaneous Seagulability, can be made to yield fibrin, though the amount Fielded ®ppears to me to be very much less than that obtainable from an equal quantity of blood plasma, previous to the injection ‘the Poison ; but as I have not made any quantitative determin- on of the amounts, Iam unable to speak with certainty on 180 Cc. J. MARTIN. Plasmas which have lost all spontaneous coagulability m however be made to clot by the following means— (1) Addition of a saturated solution of NaCl up to an volume. (2) Addition of an equal volume of a saturated solution a MgSO, = é (3) Addition of acetic acid, until the plasma is just faintly acil (4) Similar addition of weak sulphuric, hydrochloric, or p phoric acids. (Oxalic acid is ineffectual). The addition of the saturated solutions of NaCl and MgS0. occasions a faint turbidity, and the plasma clots on standing# few minutes. The acids must be carefully added, just to acidif cation, when turbidity occurs. Until this point is reached, clotting ever occurs, and if too much be added, the fibrinogen s precipitated. This precipitate readily redissolves in excess of the acid, and when so redissolved I have never succeeded in producing coagulation. The fibrin formed under these circumstances has the appearance of ordinary fibrin. It is insoluble in weak sal” solutions, or dilute HCl (-2%), but swells up in the latter, digesting with pepsin it dissolves, leaving a perfectly clear sol Since the observations of Arthus and Pagés! the influenc? calcium in coagulation has been recognised to be of the ) importance. Blood, decalcified by drawing it into a solution soluble oxalate, or fluoride (Arthus and Pagés), has lost its cap® to clot, although this may be restored by the further addi calcium salt. The intravenous injection of sodium ° (Halliburton and Brodie),? or soap (Munk), also renders the incoagulable. Pekelharing® is of opinion that the din coagulability of blood after the intravenous injection of : and sometimes of nucleo-albumens is to be explained in the way. 1 Archiv. de Physiol., Ser. v., T. 11., 1890, p. 739. 2 Journal of Physiology, Vol. xvir., 1894. 3 Centrbl. f. d. Med. Wiss., Bd. 45, 1892. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 181 As the fluid plasma of the negative phase after venom injections presents, in many respects, the closest analogies with the plasmas obtained by both of these means, I made a series of experiments to determine the influence of calcium on the coagulability of the blood of animals after injections of venom. The effect of calcium salts on plasmas in vitro, has already been mentioned. I found that the results of these experiments could be arranged in three classes— (1) The cases where only a very moderate negative phase has been produced, and the clotting of the shed blood is delayed from thirty minutes to two or three hours. (2) Cases in which the negative phase is more pronounced and the shed blood clots only after some hours or days. (3) Very pronounced negative phases in which the blood never clots spontaneously, and in which the addition of saturated solution of sodium chloride etc. only occasions a very small amount of coagulum. The addition of a few drops of calcium chloride to a sample of blood from the first class, causes almost immediate solidification and if a few cc. of a 1% solution of this salt in ‘9% NaCl be Injected into a vein, the coagulability of the blood is raised above the normal, and very frequently the animal dies in a few minutes from extensive thrombosis. 2 a a ah With the second class, the calcium chloride is without influence i the extravascular plasma, but raises the coagulability of the ireulating blood towards the normal. . ‘With the third class, CaCl, has no effect either when injected or added to the plasma in vitro. ; = following three experiments, chosen from a large number, illustrate these effects of calcium salts. In these experiments the ala artery and jugular vein were dissected out, and cannule lied in both. The former was used for taking samples of blood, nd the latter for the introduction of the venom and calcium 182 C. J. MARTIN. chloride solutions. -After the withdrawal of each sample of boo from the artery, the cannule was carefully cleaned out. Experiment I.—Dog, weight 4:8 kilogrammes. 11-45 a.m., 0-13 gramme of morphia acetate subcutaneously. — 12°30 p.m., 000025 gramme venom per kilo. of body weight (dissolved in 5 cc. of -9% NaCl solution) injected slowly into jugular vein. 10 ,, *00035 gramme venom per kilo. injected into eae vein. 1:10 ,, sample of blood withdrawn. (A) 115 ,, 5 ce. of 1Y solution of OaCl, in 9% NaCl solution e injected into jugular vein. This was fo by immediate thrombosis and death. Sample A centrifugalised. (1) Plasma clotted alone in thirty-five minutes. (2) Plasma + 4 drops of ‘5% solution CaCl, clotted almost immediately. Experiment IT.—Dog, weight 5-3 kilogrammes. 11 a.m., 0-13 gramme morphia acetate subcutaneously. 12 p.m., 000025 gramme of venom per kilo. of body Messe 5 cc. 9°% NaCl solution, slowly injected 2 iat jugular vein. 1 p.m., 00035 gramme of venom per kilo. injected into jugular vein. 2°45 sample of blood Srithideatii (A) 250 10 ce. 1Y solution CaCl, in ‘9% NaCl solution into jugular. 2°55 sample of blood withdrawn (B), which clotted ip minutes ; the clot was a soft one, and never 0° a firm jelly. i. Sample A centrifugalised. Tay eer ee ae = peraine RNMae iee SSuidik Ce / all Meee nal cask Whe ate ae Pen Pik Saye EO re see Lieto 4 Plasma A clotted slightly and spontaneously after 20 age Plasma + CaCl,, clotted in the same time. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 183 Experiment I1I.—Dog, weight 14:4 kilogrammes. 11 am., 0:15 gramme morphia acetate. 12°10 P. m., 000025 gramme venom per kilo of body weight in 5 cc. 9% NaCl solution slowly injected into jugular vein. 20 ',, ‘00035 gramme venom per kilo. injected into jugular. 215 ,, sample of blood withdrawn, (A 2:30 ,, -00035 gramme venom per kilo. injected into jugular. 30 ,, sample of blood withdrawn. (B) 310 ,, 10cc.1% solution of CaCl, in 9% NaCl solution, injected into jugular. 3°30 ,, bled todeath. (0) All the samples of blood were centrifugalised. The plasmas A, B, C clotted under the following circumstances :— A—Plasma clotted spontaneously in 4 hours 14 minutes Plasma diluted with water, in 2 hours 30 minutes - Plasma + CaCl, in 4 hours. B and O—Plasma did not clot spontaneously, nor on dilution. Plasma + CaCl, no clot. Plasma + CaCl, and 1 ce. of nucleo-albumen solu- tion (from testis)—precipitate, which next morning was partially converted into fibrin. Plasma acidified with acetic, hydrochloric, sulphuric and phosphoric acids until turbidity was pro- duced, clotted in less than fifteen minutes. Plasma + equal volume saturated solution NaCl, clotted in oe ten minutes. Plasma + equal volume saturated solution MgsSO,, clotted in twenty-two minutes. As in those cases where the negative phase is well pronounced, ‘alcium is ineffectual in producing coagulation, both in intra- and extra-vascular plasma, it cannot well be maintained, as Pekelharing, Supposes to be the case with peptone blood, that this disappearance 184 C. J. MARTIN. of clotting power is due to the absence of free calcium salts from the blood. The analogous behaviour of blood after snake venom snjootia ? with peptone blood, is not however, in this respect departed from; for I find that both peptone plasma and the plasma obtained after the slow injection of nucleo-albumens, behave in a manner identical with snake venom plasma, provided a sufficient quantity of these bodies have been introduced to produce a complete disappearance of all tendency to spontaneous coagulation. As Pekelharing’s inviting hypothesis only explains the partial phenomena of peptone injection, one cannot accept it as an inter- pretation of the facts. 7 Significance of these phenomena. These phenomena of intravascular coagulation exhibiting positive and negative phases, together with the conditions W. I have found to modify the result, show the closest parallelism with the effects observed by Wooldridge, Wright?and Halliburton! to follow the introduction of tissue-fibrinogen (nucleoalbune) into the circulation. This parallelism is still further evident when one compares the behaviour of the fluid blood, drawn from animal poisoned with venom, in which the negative phase is pre 1 “On intravase. coag.”—Proc. Roy. Soc., 1886. “ Ueber intra’ Gerinnung ”—Du Bois Reymond’s Arch. 1886. is poate a der Blutgerinnung ”—Ludwig’s Veatackerift, 1887. ‘On he Infarction of the Liver”—Proc. Path. Soc. 1837. ‘‘ The Nata Coagulation ”—Hainsworth & ee! London 1888. “ Ueber Schutaimh = chemischem Wege ’—Du Bois Reymond’s Arch. 1888. “On the conditions which determine the distribution of = c0 ie following the intravascular injection of Woo ldridge § fibrinogen.” —Journal of Physiol., Vol. xm., No.2. “A na fibrinogen.”—Proc. Roy. Irish Acad., 3rd Series, Vol. 1, i tissue or cell fibrinogen in its relation to the pathology ‘a Lancet, Feb. 27 and March 5, 1892. Vo 3 “ . . . 3° of Ph: peer a The proteids of kidney and liver cells. —Journal ee —— Number. “The chem. physiol. of the a Goulstonian Lectures, lecture 3, B.M.J., March 25, 189 PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 185 nounced, with the reactions which have been found to characterise the blood drawn during the corresponding phase following the intravenous injection of “ tissue-fibrinogen.” Wooldridge in one of his papers' thus summarises the results obtained by injecting tissue-fibrinogen :—“ If a solution of tissue- fibrinogen be injected into a dog in varying quantity, the effects observed are: with very small quantities no discoverable intra- vascular clotting occurs, but the blood drawn off after the injection clots very slowly, 1 — 2 hours intervening ; with larger quantities intravascular clotting takes place, being, as a general rule, chiefly confined to the portal venous system—the extent of clot being greater as more tissue-fibrinogen is injected. The shed blood (from other areas) will not clot. The more tissue-fibrinogen there . has been injected, the more complete is this prevention of the (extravascular) clotting —the interval between the drawing off and the clotting varying from two to thirty hours. In most eases the blood can be readily made to clot firmly by additions, such for instance, as the ordinary fibrin-ferment, and in the great majority of cases it clots firmly on standing.” A few pages further on in the same paper, he says :—‘ Further, the injection of a very large quantity of tissue-fibrinogen always leads to the production of a shed blood entirely noncoagulable, either spontaneously, or on addition of leucocytes or tissue- fibrinogen. The only difficulty is this, that frequently the circu- lation is arrested before the required quantity is got in, and then only marked slowing of the shed blood is produced.” A summary of my experiments, showing the effect on the ‘Seagulability of the blood from the intravenous injection of different amounts of venom, could well enough be given in the ape words as those used by Wooldridge, substituting only, venom” for “ tissue-fibrinogen.” 2 Wooldridge also found that variations in the condition of an _ animal were followed by alterations in the amount and distribution 1 “ Nature of Coagulation,” p. 31. 186 C. J. MARTIN. of the thrombosis, and Wright,!in following up the researches of — this observer, has very considerably extended our knowledge in this respect, as regards both dogs and other animals. One of the modifying conditions observed by Wooldridge was that in fasting dogs, unless large quantities of the “ tissue fibrinogen ” were injected, the intravascular clotting was limited to the portal area ; whereas the same dose given to an animal in — full digestion produced clotting extending to the general venous — system, right heart, and even into the arteries. I have shown — reasons for believing that the blood of animals in full digestion exhibits the same increased sensitiveness towards the action of the venom. om Ihave previously had occasion to mention an experiment of : Wright's, in which he rendered an animal dyspneic by compressioa of the trachea before injecting tissue-fibrinogen. Wright fount that the injection of an amount of “ tissue-fibrinogen ” which would, in an animal not so treated, give rise to clotting only in : the portal venous system, under these circumstances followed by intravascular clotting throughout the whole vascular system. Similar experiments with venom produced results corresponding, in every case, with those detailed by Wright. | Another experimental condition which influences in an eX corresponding manner the results from injections of both “ iss fibrinogen” and venom, is the rapidity with which they introduced into the circulation. Wright! has already drav attention to this factor as influencing the results from the inj of “tissue-fibrinogen.” I have experimented with “tissue fibrinogen” in order to determine this point, and I find that I have indicated to be the case with vénom, one can produce § will the positive or negative phase by the injection of the s# amount of “tissue-fibrinogen,” simply by varying the - which it is allowed to enter the circulation. Both “Hee® 1 Loc. cit. 1 Proc, Roy. Irish Acad., 3rd Series, Vol. 11., No. 2. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 187 fibrinogen,” and venom may be introduced in great quantity, without increasing the coagulability of the blood, once the initial positive phase is passed, and a negative phase established, if the solution be allowed to flow very slowly into a vein. In 1888 Wooldridge published a remarkable result he had obtained with the injection of his “ fibrinogens” viz.—that the injection of one dose conferred upon the animal immunity from further injections. Exactly the same occurs with the venom. The first injection produces an immunity, as far as the clotting of the blood in the vessels is concerned, from the effects of future doses, even when those are very large. I have had many opportunities of confirming this statement of Wooldridge. An analogous result has been obtained with the intravenous injection of albumoses, although the effect of these upon the blood is of the reverse order. Schmidt Mulheim? found that when the coagulability of the blood had reappeared after it had for the time being vanished owing to a first large injection of albumoses, it was not influenced by a second injection. The first injection must however be a full one or the immunity is not complete. The parallelism, as far as the coagulation of the blood is con- cerned between the results of the injection of “ tissue-fibrinogen” and of venom, is, as has been pointed out, maintained when one examines the conditions under which the two kinds of fluid blood may be induced to clot. Both these kinds of blood remain fluid, or clot only after the lapse of some hours, the time intervening before the onset of coagulation depending in both cases on the amount of the agent injected ; and by injections of nucleo-albumens and of venom, one ean obtain a series of plasmas which, as regards the circumstances under which they may be made to yield fibrin, exactly correspond. ee eee 1«g. * * ’ . 1888 Schutzimpfung auf Chemischen Wege.”—Du Bois Reymond’s Arch. 2 ‘ A Du Bois Reymond’s Arch., 1880, Se 52. 188 C. J. MARTIN. So close is the parallelism between the two series of phenomena, that one is inevitably driven to enquire whether after all there may not underlie both an actual identity of process. But in thus enquiring, one is confronted by the very striking fact that — in the venom experiments, only an exceedingly small quantity of ; the active agent is required to produce an effect negative or positive on the coagulability of the blood. ; Wooldridge stated that it required 1-5 to 2 grammes of his “ tissue-fibrinogen ” to produce intravascular clotting, ina medium — sized dog. ‘This I imagine, from my own experiments with “ tissue-fibrinogen,” is a rather high estimate. However this may be, it is certain that in the one case we are dealing with the — injection of grammes, and in the other with thousandths, or ten thousandths of a gramme. He also found that his “ fibrinogen” disappeared in the process of coagulation and presumably took — part in the formation of the clot.' : On account of the minute quantity of venom required to pre duce the intravascular clotting, it is hard to conceive that it cal operate by any such direct action. An important differen 2 ‘between the two series of phenomena which I have always noticed is, that whereas with injections of “tissue-fibrinogen” the clotting ; occurs practically instantaneously, so much 80, that it frequen®y causes blocking in the vein before one has had opportunity “ finish the injection, with venom injections there is an interval of at least 90-100 seconds before clotting occurs in the a but notwithstanding this delay in onset, the clotting in ast : venom injections is much firmer and more extensive than I ha ever been able to obtain with “ tissue-fibrinogen.” Pekelharing,? Wright,® and Halliburton,* have recently sho¥™ that the bodies Wooldridge designated 2 eae 1 hour after injection tension of CO, in femoral artery = 7 42") . Ba vein = 8:58 i e artery = 6°65"/ Ps 33 Bo ” ”> ed 1 hour 30 minutes © Darine chi oye cL a we maintained. The g this last determination artificial respiration was were well inflated with warmed air 15 times per minute. ” ” > In this experiment the aérotonometer tubes contained al the commencement. . With the exception of Experiment I. the absolute quantity CO, contained in the venous blood was not decreased. * contrary, the amount of CO, was, in those cases where the ES was severely affected by the venom injections, conside aoe excess of that found previously. Under the same circit” the tension of CO, was very much higher than has been ® for normal venous blood. In most of the experiments the ; representing both the absolute amount and the tension he a rose together as the condition of the animal became yee worse. After peptone injections, whilst the tension of | me PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 201 the absolute amount of the gas contained in the blood was on the contrary, decreased. I therefore conclude that although the capacity of the blood to carry CO, may be, as one might expect from the analogy to other blood-corpuscle-destroyers, somewhat diminished, this is not a prominent feature of poisoning by the venom, and is entirely masked by the operation of other and more potent factors. The gradual increase in both the tension and amount of CO, in the venous and also in the arterial blood of the poisoned animal is to a large extent accounted for by the enfeeblement of the circulation and respiratory movements. Before this occurs it is not manifested, but afterwards it progresses hand in hand with the circulatory and respiratory depression. The exudation and hemorrhage into the lungs which is almost an invariable sequel to the injection of the poison, and whereby con- siderable areas are for the time being rendered useless, does no doubt also contribute in some degree to the same end. The existence of this factor is indicated in Experiment V., in which artificial respiration was ineffectual in reducing the high tension of CO, in the blood of the femoral artery to any great extent, and it is interesting to note that examination of the chest of this dog immediately after the experiment, discovered very extensive edema and hemorrhages throughout the greater part of the lungs. This pathological condition had evidently so curtailed the avail- able respiratory surface, that the larger portion of the blood passed through the lungs without an opportunity of coming in contact with the air in the alveoli. So that although the alveolar air was maintained of a high degree of purity by artificial inflation, the blood was not enabled to rid itself of its contained COp. a ie i 4 i . (f)— Influence of the venom on the germicidal action of serum. Weir Mitchell has drawn attention to the fact that the bodies " animals dead from rattle-snake poisoning putrefy with extreme rapidity, and that during life the local extravasations which are istic of this class of snake poisoning, as 4 general rule 1 Loe. cit. 2 Loc. cit. 202 Cc. J. MARTIN. into healthy animals produced no effect. Last year Dr. Ewing’ repeated some of Nuttall and Buchner’s observations on the germicidal power of serum, and instituted a series of comparative experiments with the serum of animals poisoned with Crotalus venom. Ewing found that the normal germicidal power of serum : was entirely lost after poisoning with Crotalus venom. : To ascertain whether the same loss of germicidal power was” occasioned by Pseudechis venom, the following experiments were made :—A healthy dog, weight 10 Kilos., was injected under the skin of the back with -0065 gramme of venom, dissolved in 2 ee of weak salt solution, at 11°30 a.m. At 3 p.m. he was etherised and Nese taken from the femoral artery. In the mean time he had’ vomited considerably, and at 2-45 p.m. he was very sleepy and weak, although he could still walk. The blood was draw into a sterilised jar under conditions of the strictest asepticism. — At the same time the blood of another dog was drawn under exactly similar conditions, except that this animal had not received . a venom injection. Both samples of blood were placed in an 10 contamination with any micro-organisms. 5 cc. of each kind serum were then placed in two sterilised test-tubes. The test organism employed to determine the relative germici powers of the two serums was a twenty-four hours’ growth ¢ broth culture of Bacillus anthracis. This was a pure culture the organism and contained no spores. Each test-tube — inoculated with a platinum wire loopful of the culture and shaken up. The serum tubes containing the organisms were at the laboratory temperature 24-— 25°C. The effect pro 1 «* Med. Record,’ May 26, 1894. SP te ee Ce Poe ee Cae eee ae eee PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 203 upon the organism by sojourn in the serums, was ascertained from time to time by withdrawing a wire loopful and mixing this with 10 cc. of nutrient gelatine and making a plate cultivation of the mixture. An indication of the extent to which the growth of the bacilli had progressed in the serum tubes was obtained by counting the number of colonies appearing in the plate cultivations after definite intervals. 2 The following notes represent some few of the results of these experiments in tabular form, and clearly show that whereas the growth of the organism was as usual hindered by the normal serum, on the other hand the serum from the poisoned animal formed an excellent culture medium. In this particular case the damaging influence of the normal serum was less than is usually the case. The tables represent. the number of colonies of the organism which developed in the plate cultures after various intervals of time,! I.—After Five Minutes Sojourn in Serum. Number of Colonies after 18 hours. | 21 hours.| 48 hours. Normal serum ....|_——-22 | 123 Venom serum _...|. 39 | 464 | 560 ! II.—After One Hour’s Sojourn in Serum. Number of Colonies after 17 hours. | 20 snes 42 hours. [i | sf x Normal serum 12 672 ge . _ Venom serum _ 987 | 2000 | countless ee TII.—After Two Hours’ Sojourn in Serum. : Number of Colonies after d 16 hours. 19 hours,| 41 hours. Normal serum... 5 | 560 Venom serum 1450 | 2416 | countless | : Sa a ent we teeretientinie ale nee Sa 1 For the of greater portion of the troublesome details of the the performane Mr. R. — I ses 1 indebted to my friends Dr. F. — and ‘ 204 C. J. MARTIN. IV.—After Three Hours’ Sojourn in Serum. Number of Colonies after 15 hours. 18 hours. | 40 hours. Normal serum i — | countless 19 | Venom serum ...| 2420 | 4244 | countless Other agents which cause destruction among the blood corpuscles would appear to produce a similar result. Gottstein’ found that the injection of pyrogallol and acetyl-phenyl-hydrazin into the — circulation of animals naturally immune against definite micro organisms rendered them susceptible to invasion. Under the same circumstances pathogenic germs which locally affect the organism are capable of spreading throughout the whole body. ACTION OF VENOM ON THE BLoop VESSELS. The situation in which the poison is injected is always the seat of some edema. On cutting into the edematous tissues, a serous fluid, more or less stained with hemoglobin, escapes. This - itself is an indication of some alteration in the walls of the blood vessels in the vicinity of the injection, by which the normal transudation processes are affected. Rattlesnake venom produces changes which are of a similar nature, but in which the degree of damage to the endothelial lining of the vessels is much greater. That this venom was capable of playing considerable havoc with the cells lining the blood vessels, was demonstrated by War Mitchell and Reichert.2. These authors moistened the mesentery of animals with Crotalus venom and observed under the microscope the rapid formation of extensive capillary hemorrhages. © few minutes the whole mesentery became by the coalescence of the numerous hemorrhagic foci absolutely infiltrated with I have repeated these experiments, using Pseudechis Y , and although the action of this poison is less rapid than isha: case in Mitchell and Reichert’s experiments the results Bas identical. The mesenteries of cats and dogs were od unt the microscope so as to obtain a good view of the circulation © 1 “ Deutsche Med. Woch., 1890, 24. 2 Loc. cit. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 205 the capillaries. A minute fragment of the poison was then placed near to that portion of the mesentery in the field of the microscope. | . ' 7 i at In a few moments without any previous clouding of the field, or stasis, small hemorrhages appeared. These invariably occurred first in those positions where the hydrostatic pressure was greatest, viz., from the wall of the capillary near to its origin from an arteriole, and where these capillaries branched or joined one another at right angles. These tiny hemorrhages increased in number and extent until the whole field was one mass of corpuscles, These appearances are very characteristic and altogether distinct from the escape of corpuscles in diapedesis, and I think there is no doubt that the venom first damages the capillary wall, and that the pressure within causes an actual solution of continuity, the blood escaping through this rupture. One of the prominent symptoms in animals, after the intraven- ous injection of a small dose of venom (i.e, so small that the animal may live a sufficiently long time, for the full development of the symptoms), is the occurrence of extensive hemorrhages. I have often seen more than half the substance of the lungs solid from hemorrhage into the alveoli and inter-alveolar tissue. If such an affected lung have its blood vessel washed out with saline solution immediately after removal from the body and be then injected with some colouring matter such as indigo-carmine, the fluid injected will not enter the hemorrhagic portions of the organ to any extent, so that it is probable that thrombosis in the small _ branches of the pulmonary artery plays some part in these lung ~ hemorrhages. Silbermann! has described an analogous condition m the lungs after intravenous injection of various corpuscle destroying agents. Ragotzi,? using the same method as Silbermann, found small thrombosed areas in the lungs of animals poisoned by cobra venom. Hemorrhages of greater or less extent are nearly always to be found in the kidneys, liver, and the walls of the alimentary canal, 1 Ueber das Auftre r} ‘ P LEE De : ch Arsen treten multipler intravitaler Blutgerinnungen nac Y Loe posPhor, und einige Blutgifte.—** Virch. Arch.” Bd. 117, 1889. cit, : a 206 C. J. MARTIN. e and the intima of the aorta and large blood vessels. There is : also another situation where a small hemorrhage is almost invari- _ ‘ ably found, viz.: under the endocardium of the left ventricle, Feoktistow! mentions the constant occurrence of a heenion hana ce this situation in his experiments with viperine venom. , The full development of all these hemorrhagic phan onicll requires some hours. When venom is intravenously injected, the : immediate great fallin blood pressure prevents for the time being ; the damaged condition of the vascular walls being demonstrated. — Subsequently, the escape of blood takes place more and noe i the pressure gradually rises after the initial fall. All kinds of snake venoms which have hitherto been examine(, ? have been shown to contain in varying amount amongst their albuminous constituents a proteid or proteids coagulable by heat. It is of iderable i t that the viperine poisons which contain coaguable proteids in largest amount, exercise this destructive — action on blood corpuscles and the walls of blood vessels, to the greatest extent, whereas cobra venom, which contains less than 2’of coagulable proteid, only exerts such action to a comparatively slight extent. Boiling, or indeed raising the temperature of the solution to 80 — 85° C. deprives venoms of much of their action ae this direction, and at the same time largely does away with t capacity of Psewdechis poison to produce intravascular clotting. The power of this venom to both destroy blood cells and occasi thrombosis is however not entirely lost, for by increasing dose of heated venom to at least five hundred times that of the | unheated poison which is required to produce instant oat: thrombosis, the same result is attained. The whole toxle po” of the venom is not however attenuated to this extent. large series of experiments on rabbits I found that the min! dose of Pseudechis poison which when subcutaneously i injee : was sure to occasion a fatal issue, was ‘0005 gramme of: per kilogramme of rabbit. When the solution of the veno™ "— : q 1 Loc, cit. —- PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 207 previously heated to 85° C. for five minutes, the corresponding amount required to kill was -0030 gramme. These observations show that either (1) Heating vo 85° destroys the component of venom which possesses the power of destroying corpuscles to the greatest degree, —or (2) Heating attenuates the toxic properties of venom in this particular direction to a much greater extent than it does its toxic power generally. Heating to 85° C. does indeed separate one of the proteid con- stituents which at this temperature is coagulated and rendered inert. It is therefore quite possible that the difference in the action of venom before and after heating to 85° O. may be so explained. We must however bear in mind that the action of heat on solutions of toxic proteids is a twofold one— (1) By converting some of the proteids into an inert precipitate. (2) By impairing their toxic power, without influencing their solubilities, or indeed changing them in any way recog- nisable by chemical tests. The first method of action is sudden. When the solution is : aed to a definite temperature, some portion of the proteid con- : : stituents is coagulated. ‘The second is gradual, and the extent of attenuation depends on the duration of the heating, and the Yemperature and dilution of the solution. 7 th the case of Crotalus venom Mitchell and Reichert have shown “9 the coagulable proteids are the constituents which produce a destructive effect on the blood cells and vessel walls to the greatest es but I have not yet determined for Pseudechis poison to “an ®xtent the difference in physiological action between venom ett heated to 85° C. and unheated venom is to be attributed ati “een of one of the constituents or to gradual attenu- tae of its power in a particular direction. 208 C. J. MARTIN. TV.—Errect or VENoM oN THE CrrcULATORY MECHANISM. The poisons of all snakes with which experiments have hitherto been made, depress the circulatory mechanism. Different venoms however exercise this action in different degrees, so that whereas interference with the circulatory apparatus plays a very important réle in the general phenomena of poisoning by some species of snake, with others such interference is, compared with its action in other directions relatively unimportant. In experiments with the frog’s excised heart, when the orgat is fed with a solution containing defibrinated blood, by means ofa Ludwig and Coat’s apparatus, the introduction of all kinds of venom into the feeding mixture, soon brings the contraction toa — standstill. If this has once happened, the further substitution of fresh defibrinated blood for the venom-containing solution does not effect a recovery. By direct observation of the heart in the opened thorax of mammals, in which artificial respiration was maintained, Feoktistow! observed great diminution in the cardiac contrac: tions, after the introduction of the venoms of Crotalus and Vipera berus. When these poisons were intravenously introduced, the contractions of the heart were at first diminished, and after: wards increased in number, becoming at the same time weaker and weaker until death occurred. S The best indication we possess of the efficiency of the circule tion is the arterial blood pressure curve. A variation in any the factors concerned in the general circulation will sooner later be manifested in this curve. It possesses the additions advantage that it lends itself in an admirable manner to the method of graphic record. A tracing of the pressure of ané may be allowed to run for hours, and at the end of the eee : are in possession of a record of every change of pressure which : occurred. Of course the chart has to be interpreted, and into that interpretation errors may creep, but by simultaneous © 1 Loe. cit. EAS aie ke Wi eee LR Whe une Se wet PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 209 of the volumes of abdominal organs such as the kidney and spleen, and by judicious variation of the conditions of the experiment, by means of which the operation of a particular factor can be eliminated, one is generally able to ascertain to which of the factors concerned in the maintenance of the blood pressure the change is to be ascribed. The effect of several kinds of snake venom upon the blood pressure in the higher animals has been investigated. Brunton and Fayrer,! and Ragotzi,? worked with cobra poison. Mitchell, and Reichert? made a large series of experiments with the venoms of species of Crotalus and Ancistrodon, Daboia russellii, and also cobra. Feoktistow’st observations were made with the poisons of Crotalus and Vipera berus. Weir Mitchell and Reichert confirmed those results which had already been obtained by Brunton and Fayrer, with cobra poison ; and the more recent work of Feoktistow and Ragotzi entirely Supports the older observations as regards the main characteristics of the blood pressure curve after poisoning with either rattlesnake or cobra venoms. The work of Weir Mitchell and Reichert is the Most important as they pursued their investigations with the venoms of a very large number of different species of snakes, thereby giving us the opportunity of comparing the action, in this respect, of a variety of poisons. The results of these observers Possess the additional advantage of having been obtained from an admirably varied and extensive series of experiments. They found that when the venoms of all these species of serpents Were intravenously introduced, there was a distinct lowering of the blood pressure. It fell immediately after the injection, and Indeed Sometimes before this was completed ; and the fall was Benerally So marked as to indicate a most profound action of the Polson upon some part or parts of the circulatory apparatus. If the dose were not immediately fatal, the pressure gradually rose, but finally underwent a more or less steady decline until death. At 1 ‘ MEW YF Loe. cit. 3 Lae clk ¥ Loe. HE N—July 3, 1995, 210 C. J. MARTIN. other times the pressure sank without subsequent rise until death ensued. With subcutaneous injection of the venom, the primary sudden fall was in most cases absent. The tendency in cobra poisoning was to a decided rise of pressure, following the primary fall. In five out of six experiments with the venom, the primary fall was followed by a rise which went above the normal during the asphyxial condition preceding death. After section of the pneumogastrics, they found that the same alterations occurred in the blood pressure as those observed in animals in which these nerves were intact. When the cord was severed in the cervical region, the primary fall of pressure was not so marked, but the subsequent slow, y* deadly fall occurred. ‘In experiments with cobra poison, 02 the contrary, even under these conditions, a rise in blood pressute usually preceded death, Feoktistow found that when a very large dose of the venom of Crotalus, or Vipera berus was subcutaneously administered, the blood pressure fell as suddenly as when the poison was intr venously introduced. After the pressure had been greatly lowerst by the poison, he was unable to produce any effect by stimulating : the peripheral ends of the splanchnic nerves, from which he con cluded that the peripheral ends of these nerves were paralysed This he considered was the explanation of the “ collosale sinking of the blood pressure. | Brunton and Fayrer found that the intravenous injection of cobra poison, occasioned a sudden temporary drop in the arterial E blood pressure, which, under most circumstances speedily regained the previous height. Sometimes, however, this fall was a recovered from, and the animal died in less than sixty . : from the time of the injection, but the arterial blood remained considerably above zero. This was considered noteworthy : ‘by these authors, and they thought it showed “that the — : : or capillaries must have been much contracted, thus opposing | barrier to the exit of blood from the arteries into the veins pene Fy oth oe ae a) 2 ees eg Min Sach PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 211 In a previous section I have mentioned a similar occurrence in many of my experiments with the intravenous injection of Pseudechis venom. At first this maintenance of a considerable pressure in the arteries after the sudden death of the animal puzzled me greatly. There could be however only one explanation of the phenomenon, viz.: that the blood cowld not empty itself as usual into the veins. In my experiments the reason was that the arterial system was blocked by the occurrence of intravascular clotting, and it is quite possible that this was also the explanation in Brunton and Fayrer’s experiments. In the experiments made by these observers death usually occurred from asphyxia, during which the blood pressure curve exhibited the same rise of pressure above the normal as obtains when an unpoisoned animal is asphyxiated. Speaking of this maintenance of circulatory efficiency, Brunton and Fayrer say,—‘ The long continuance of the cardiac pulsations after apparent death excludes failure of the circulation as the usual cause of death ; and we are thus brought, by exclusion, to regard death caused by the bite of the cobra, or by its poison introduced into the body in any other way, as death from asphyxi1. The truth of this view is well illustrated by a series of experiments which show that the vitality of the heart may be retained for a considerable time if the respiration is kept up. It shows also that the convulsions which have been remarked by Russell and all subsequent observers as almost always preceding death are not due so much to the action of the poison itself on the nervous centres, as that they depend on the irritation which is produced in them by the venosity of the blood.” (0)—The effect of Pseudechis venom upon the excised heart of cold- blooded Vertebrates. Thave experimented with the excised hearts of frogs and turtles. In the case of either of these animals a perfusion cannula was mserted in the ventricle and tied. The cannula was connected with a Ludwig and Coat’s apparatus, and the record of the heart- 212 C. J. MARTIN. beat taken on a slowly moving cylinder covered with smoked paper. One of the Marriott’s tubes of the apparatus was pre viously filled with a mixture of defibrinated mammalian blood one part, and “65% sodium chloride solution, containing 1 in 1,000 Na,CO;, two parts. The other tube was filled with a similar solution containing a known proportion of venom. The — amount of venom contained in the solution was either 0-1 or 1}. The former appeared to at first stimulate the heart, but it speedily began to beat more slowly, then became irregular and feeble, and eventually stopped in diastole after about thirty mmutes. The stronger solution of venom produced immediate slowing and enfeeblement of the contractions, which became diminished i rate and extent until in a few minutes the heart ceased to beat. If the stronger venom-containing solution was allowed to flow through the heart for only ten seconds, the substitution of the unpoisoned feeding mixture failed to produce any recovery of the cardiac contractions. Two experiments were made with the hearts of small turtles by — means of a Ludwig and Coat’s apparatus. In the former ‘17, of venom was employed, and in the latter a feeding solution col taining 1% of the venom was allowed to flow through the heart for one hundred seconds, and then replaced by the blood solution ; only. This had however, no effect, and the beats became rapidly less and less apparent until they were imperceptible in twelve minutes from the introduction of the venom. (b)—Effect on Mammals. I commenced my investigations into the action of f the circulatory apparatus, by taking tracings of the pressure an artery, both during and after the introduction of the poise The venom was introduced by injection subcutaneously, peritoneal cavity, or directly into the circulation through 4 Ye th, becaus? or artery. I chose intravenous injection to begin W! the method of subcutaneous inoculation introduces 4? the venom 02 : ee Skat eh ey mea into the quantity—vie, rate of absorption. ‘This mothod bas MW = PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 213 the disadvantage that the injection of even very small quantities of the venom directly into the circulation occasions so great an increase in the coagulability of the blood, that this fluid frequently clots in the vessels. When this occurs at all extensively the circulation is speedily terminated and death ensues. It is indeed very difficult to prevent intravascular clotting, and before we can draw conclusions as to the action of the venom upon the heart or other portion of the vascular mechanism we must be sure that thrombosis has not occurred.!_ In wy earlier experiments I was not aware of this action of venom upon blood plasma, and the inconsistent results I obtained puzzled me greatly. The whole matter was however cleared up when I discovered that the extraordinary lack of uniformity in, and frequent sudden termin- ation of my experiments, was due to the arrest of the circulation by solidification of the blood. The animals used were dogs and rabbits. The results were substantially the same with both animals. The effect of the poison on the blood pressure was investigated under a variety of experimental conditions with and without curari. In some experiments the vagi were previously severed, in others not. Two experiments were made on animals in which the cord had been divided at the level of the third cervical vertebra. In five cases a simultaneous record of the volume of either the kidney or the spleen was obtained, and in nearly every case the condition of the respiration was recorded at the same time by connecting the trachea with a Marey’s tambour and writing lever. The records were taken on a Hering’s kymograph. In those experi- ments which lasted many hours a continuous record was not taken, ee the kymographion was stopped, and set going again for a few minutes at intervals of fifteen or thirty minutes, or less as occasion demanded, : The general features of the blood pressure record following the intravenous injection of Pseudechis venom are the same as those ies : ee esc Y of the results of previous experimenters with snake poisons vitiated by their ignorance of this possibility. 214 C. J. MARTIN. observed by Weir Mitchell and Reichert, and Feoktistow, to follow the introduction of the venom of Crotalus, Ancistrodon, Daboia russellii, and Vipera berus into the circulation. Directly the venom reaches the heart there is a sudden great fall of the arterial blood pressure. This fall is accompanied by diminution in the extent of the accession of pressure due to each beat of the heart, and is the more marked the greater the rapidity with which the solution of venom is introduced, and the nearer the vein chosen for its introduction is to the heart. The extent of this fall is dependent on the degree of concentration with which the poison reaches the heart. When its dilution with blood is accomplished, by introducing it into a vein far removed from the heart, its effect ~ is lessened, and if the injection be carried out sufficiently slowly, this steep descent is absent, and the pressure declines slowly and steadily until death. Also when the venom is injected into the carotid or vertebral artery, so that it is carried away from the heart and well diluted with blood before it is returned to this organ, the effect is diminished, notwithstanding the fact that under these circum stances the poison reaches the nervous system in the greatest : concentration. If the fall in pressure is to be ascribed (a8 Mitchell and Reichert concluded was the case in their exper ments) to the sudden relaxation of the arterioles in the abdominal area, by paralysis of the vaso-motor centre in the medulla, one would expect to obtain the most marked result when the poison was enabled to operate upon the medulla in greatest concentration and not the reverse result, as I have always obtained. . The initial fall of pressure may be only temporary, ean course of a few minutes to one hour may rise again to nearly normal, as is shown in the majority of the experiments. This recovery, when it occurs, does not however last long if fatal dose has been injected. After remaining as high, OF pe as high as before the injection, for a period varying from 4 ug minutes to some hours, according to the dose whi | PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 215 injected, the pressure begins to slowly decline, and continues to do so until it is only equal to a few millimetres of mercury, when the enfeebled circulation is no Jonger adequate to support life, and the animal dies. This fatal fall of blood pressure also invariably occurs in those cases where artificial respiration is maintained. Without this assisted respiration the pressure declines more quickly as the cardiac depression is accentuated by a diminished supply of oxygen, due to simultaneous failure of respiration. Up to within a very short interval before death, when the cir- culation is almost ended, vagus stimulation produces the usual slowing or stoppage of the heart. (of. Exs. 10, 11, and 14.) The intravenous injection of the poison, however, neutralises that normal retarding influence which is exercised by the vagus, and is so marked in some dogs. In these animals the large slow cardiac contractions are almost immediately superseded by con- tractions increased in rate, and much diminished in force after the injection of venom. Section of the vagi under these circumstances is without effect. When the venom is subcutaneously injected, the decline of the blood pressure is more gradual, and the primary sudden fall so characteristic of intravenous injection is absent. The time which elapses before the pressure begins to fall depends upon the amount injected and the rapidity of absorption. A small dose (-005 gramme per kilo.) when introduced under the skin, may not materially affect the blood pressure for three hours subsequent to the injection, whereas the same amount introduced into the Peritoneal cavity may cause a marked fall in pressure during the first fifteen minutes, Larger doses however act much more rapidly, and if a sufficient quantity is injected the blood pressure often falls to one half of its previous height in three or four minutes after the introduction of the poison. 216 C. J. MARTIN. (c)—Explanation of the fall in blood pressure. Weir Mitchell and Reichert, who observed the same diphasic : character in the blood pressure curve after intravenous injection of various kinds of snake poison, were of opinion that the primary fall was chiefly due to the depressant action of the venom upon the vaso-motor centres in the medulla oblongata, and slightly upon the heart, but that the ultimate fall of pressure was cardiac in origin. From the results of experiments the details of which are given at the end of this section of the present paper, I have come tothe conclusion that in both cases the fall in pressure is mainly due to a direct action of the poison upon the heart. The most important evidence which has led me to this conclusion is drawn (1) From observations on the blood pressure in experiments in which the cervical cord had been previously divided, and (2) From those experiments in which observation of the volume of the spleen or kidney were made at the same time as 4 record of the arterial blood pressure. In experiments 16 and 17, the intravenous injection of 0009 and ‘0008 gramme of venom into two dogs with severed cervical 3 cord, produced precisely similar results to those which I ~~ frequently obtained with normal dogs. The only difference was: that in the experiments in which the cord had been previo _ divided the blood pressure was reduced to almost one h original height before the introduction of the venom. In exper ment 16 the larger dose killed the animal in ten minutes, and the pressure fell steadily until death, whereas in experiment li, which the dose was smaller, the animal lived for nearly t with moderate doses of the poison. Were the numbers ta in these two experiments multiplied by two, they would ¢ respon it te in wo hours, . and the blood-pressure record exhibited the same temporary a recovery as had been observed in the majority of the experme™” “6 ice pulated ; ibe r radon SS ED Otte ete aE eS EE ae on | ae eae DO at exactly with those of experiments in which the cord was intact. Experiments 30, 31, 32, and 33, in which a simultaneous Fe" : or of the arterial blood pressure and the volume of the kidney PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 217 spleen was obtained, show that both curves decline and rise together. The fall in pressure is accompanied by a simultaneous and equally abrupt diminution in the volume of the spleen and kidney, and in those experiments in which the arterial pressure recovered, the volume of these organs increased at the same time, and again diminished as the pressure in the arteries finally fell. Had vascular dilatation (provided it affected these organs), been the explanation of the fall in pressure, the two curves would have crossed one another and not run in a parallel direction. I think these organs, and especially the spleen, may be taken as fair samples of the area in which vascular dilatation due to vaso- motor paresis would occur, and this evidence, taken in conjunction with the results of the experiments on animals with divided spinal cords, justifies the conclusion that the fall in blood pressure is cardiac in origin, and that any result of vaso-motor paralysis is insignificant in comparison with the direct weakening of the cardiac contractions. Such a direct effect upon the heart would not be unexpected, for, as I have mentioned, all venoms act as cardiac poisons when supplied to the excised heart of cold blooded vertebrates, Diminished peripheral resistance, owing to vaso-motor paresis, does no doubt contribute a share to this final fall in pressure, but that vaso-motor action is not altogether in abeyance, and may still be called into operation by sufficient stimulus is shown by the effect of asphyxiation on a curarised animal in which the Pressure has sunk to less than one-half its previous height. In ®xperiments 14 and 15, the pressure was in both instances, under such circumstances, doubled by suspension of the artificial respir- en. In other experiments upon rabbits, as soon as the respir- ation showed signs of incipient failure, artificial inflation was employed. Directly this was discontinued, and the animal had to depend on its own inadequate respiratory movements for a “upply of oxygen the pressure rose at once. The only cause of ae : rise is that brought about by the vaso-motor mechanism. This is stil capable of about doubling the arterial pressure for 218 C. J. MARTIN. the time being, even within a few minutes of the death of an animal. Far from considering interference with the vaso-motor centre important, in the phenomena of poisoning by this venom, I think that the manner in which this centre, and also the vagus centre 4 escapes, when, as I shall presently show, the activity of a closely 4 situated group of cells, the respiratory centre is absolutely im abeyance, is one of the most remarkable instances of the selective operation of a poison, with which I am acquainted. Ragotzi' has pointed out that the vaso-motor and vagus centres enjoy the same comparative immunity from the action of cobra poison. That the enormous fall in blood pressure is not due to paralysis of any peripheral termination of the splanchic nerves as Feoktistow believed was the explanation of the corresponding fall in his expe ments with Crotalus poison, is shown by Experiment 5, in which stimulation of the peripheral ends of these nerves, produced in the late stages of poisoning, as great a rise of pressure propor tionatel, as under normal circumstances. Feoktistow does not givé * detailed account of the experiments from which he drew his ee clusions, but it is not improbable that he had occasioned extensiv? thrombosis in the portal area by his intravenous injection, which would be an excellent reason why any further peripheral resistance in the same area, should not be manifest in the blood pressure curve. There is a further interesting point shown by the blood pressure record, ia those experiments in which I have given at intervals two or three injections of venom intravenously. The inject?” a very small quantity of venom (00005 gramme per kilo.) pre duces a very considerable and immediate fall of blood presi which is, however, recovered from. If, after the lapse of 07° sat : when the pressure has regained, or almost regained its fom 1 Virchow’s Archiy., Bd. cxxm., S. 232, 2 Loe. cit. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 219 height, a further injection, containing ten or twenty times the former quantity be made, this causes.a second drop in the blood pressure. The fall is, however, in no way so great as in the first instance, notwithstanding the fact that the quantity injected is so much larger, and whereas the recovery from the cardiac depression due to the first dose, was not complete until from forty minutes to one hour, the pressure regains the normal, or about the normal, in fifteen minutes after the second injection. If, after this second recovery, a third dose of the poison, of the same quantity as the second injection (or even double that quantity) be introduced, it has little or no effect upon the blood pressure. The only explan- ations of such results are either that the cardiac muscle has become much less sensitive to the operation of the poison, or that in the meantime, some body possessed of properties which interfere with the operation of the poison, has become present in the blood plasma. This point, however, opens up the whole problem of immunity and the protective reaction of the organism against the poison, which I hope to discuss at some future time. Precisely the same result was observed by Wooldridge when nucleo-albumens were repeatedly injected, and the enormous fall in blood pressure produced by injecting albumoses into a vein, does not occur if a second injection be made after the animal has recovered from the first. . Protocols of Experiments showing the influence of the Venom upon the Arterial Blood Pressure. These experiments were performed on dogs and rabbits. The Poison was introduced either intravenously, subcutaneously, or Into the peritoneal cavity. Most of the experiments in which the Poison was injected into a vein were made upon dogs, whereas in those cases where subcutaneous injection was employed, rabbits Were used. Graphic records of the blood pressure were taken "pon a Hering’s kymograph by means of a mercury manometer. — The time and duration of the injection was indicated by raising the signal line. Underneath the signal line a time marker con- nected with a seconds clock gave the value of the abscissa. In 220 C. J. MARTIN. those experiments which lasted some hours, a continuous res was not taken, but the kymograph was stopped and set going again for a few minutes, at intervals of fifteen or thirty minutes or less as occasion demanded. In tabulating the curves, the height of the pressure tracing at any particular moment above the abcissa was measured in mm. and this number doubled. In every case the mean pressure between the limits of the respiratory and cardiac undulations was taken. (1) Experiments with dogs in which the vagi had been previously severed. Experiment 1—Dog, weight 4:1 kilogrammes, ‘065 gramme of morphia injected hypodermically ; ether during operation. Sra a “ae sade hrs, mins, secs mercury = f 4 n gacenn of 0002 gramme per kilo. 0 cue 2.0 114 1 16 0 80 yay 0 81 4 =? 64 | respiration greatly diminished in extent 30 * _o° 14 | dead. Respiratory gasps after cessation of — circulation. 222 C. J. MARTIN. Experiment 5—Dog, weight 3-2 kilos., ‘075 gramme of morphia hypodermically ; ether during operation. When the pressure had been reduced from 136 to 38 mm, stimulation of the left splanchnic at its entrance into the abdomen by a faradaic current caused the pressure to rise to 61 mm. Time, | Blood pressure in mm. of Remarks, hrs, mins. secs. | Normal 136 = 0004 grammes per kilo. wi body Te | injected into Soni carotid artery. I | n lasted 3 onds. 0 O 30 120 A EF 96 ee 8 | o 16 6 64 | heart beat very small 0 30 0 72 eart beat improved 0 45 =O 100 _ heart beat improved aoe 8 108 _ respiration much slower 10:0 63 respiration very slow £16: 0 48 | respiration very slow a 6 38 _—_ left abdominal splanebis stimulated 3010 61 St -0 40 | an 6 4 2 0 0 26 2 30 O 18 2 40 O 14 dead . Experiment 6—Dog, weight 4 kilos., 065 gramme of morphia ; hypodermically ; ether during operation. a Time. _{ Blood pressure! in mm. of Remarks. ee hrs. mins. secs. mercury Ce Normal 142 ‘0003 mmes per kilo. of body weight i o ted i ected jugular vel. Injer 63 minutes. Ee AR respiration slow and slight dee | ae | 42 respiration slow and slight : 0 respiration very vie oteht E 0 46 respiration very slow and slight | = = 0 30 O 49 10 2 2" /3 solutions of CaCle injected ‘ jugular vein, caused pense 7 bosis of the whole vascular syste™ _— This experiment was terminated after thirty minutes by ie ing a solution of CaCl, which occasioned extensive intra ‘clotting. ; re e “ 3 4 Bs PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 223 Experiment 7—Dog, weight 7:7 kilos., ‘1 gramme morphia Spatioinically ; ; ether during operation eo ood pressure mm. o Remarks. hrs. mins. secs Panouty. Normal 204 Sasa pee per kilo. injected. into -daohaaes Injection lasted 14 minute ie i 105 respiration i increased 0 3 0 139 9 10 0 181 0 35 0 194 respiration slower — normal LoeOsi 0 160 respiration inspiratory in charactor 1 30 0 126 diminished respiration ringers in character 1 45 0 108 i Pe * 2. Or) 103 » 2 15 0 07 respiration nearly ce sed 2 16 0 95 esi mre Sonali: dating which pressure 0 143 2 17 0 135 2 18 0 21 dead this experiment the respiration was affected to a much In greater extent than is usual wit dogs under the experimental nimal died of asphyxia. During the xia the pressure rose considerably. 8—Dog, weight 15 kilos., -15 gramme morphia hypodermically ; ether during operation. Remarks. conditions, and the a asphyxi Experiment Time, Blood pressur hrs, mins. secs a nanly “ a eaten ensines | binemtniaciein Normal 186 0 20 127 0 30 114 oa) 6 99 6-0 89 0 10 O 92 9 15 0 105 0 30 0 127 7 a 0 158 1 00 164 1 20 101 2: 6 0 83 110 0 130 1 20 0 159 1 30 0 162 2-00 156 oe ee 142 = oo 140 2 10 0 148 = 16 6 148 2 30 0 151 3 0 : “00005 gramme per kilo. injected into jugular vein. 0005 gramme per kilo. injected 0005 gramme per kilo. injected bled to death 224 (2) Experiments on dogs with vagi intact. Experiment 9—Dog, weight 94 kilos., ‘1 gramme morphia — hypodermically ; ether during operation. J. MARTIN. Exe ‘4 1 tthe stil - Time. pressure et at : Remarks in rt beat! hrs, mins. secs. mm. | ; Normal 95 21:0 | -00001 gramme per kilo. injected into de sawed vein; injection lasted 2) 0 2 30 64 1:0 | aN Gee I 52 8 e170 8 65 10 | right and left vagi cut; no effect 0 10 30 65 1:0 The restraining effect of the vagus on the heart beat was vely marked in this dog. It disappeared in one minute after the injection of the poison, and when the vagi were severed this was followed by no alteration in heart beat or blood pressure. Experiment 10—Dog, weight 4 kilos. -065 gramme morphia hypodermically; ether during operation. Oe gp loner: pressure ws rot : Remarks. : in mm. heart beat hrs. mins. secs, in mm. Normal 152 8-0 8 grammes per kilo. of body weight eet —— ne jugular vein ein. Injection lasted 1 nut 0: 10:6 90 2-0 : 0 12 0 94 2:0 | right and left vagi cut. No effect. 3 0 13:20 94 20 | peripheral end peice vagus stimulated, 3 pressure fell to 3 0 22 0 116 2°5 + 70-0 40 7 2, 380 41 7 be Se 18 lees { 1 56 0 14 less | dead a Shortly after introduction of the poison the vagus beats dis: appeared. Subsequent section of vagi produced n0 effect. — Stimulation of peripheral end of right vagus stopped the > PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 225 Experiment 11—Dog, weight 13-5 kilos., ‘15 gramme morphia hypodermically ; ether during operation, Excursion Blood ofthe style _ hpi at each Remarks, hea. ch beat oc: | | 90 00008 a as kilo. injected into jugular v SES me he or trachea clamped. right and left vagus cut. cooococoooso bo OUk ies) or Aan WSs er c8o8oS8wrcobSgwo SES cooooococcooooooo ocoooeooose ~7 —_ —— end of right Mas dons (ponagee pressure to fall t -00045 | wenities per kilo. tee 0005 gramme per kilo. injected ou ror) Cm How cree cr oth crt OorPwWwWNnNNnW NNN HH Ree Ht 31 19 Fae ceptible dead _ Oo Vagus beats disappeared in two minutes after the injection of the venom, Twenty minutes after injection of poison pressure ®qualled 68 mm., and clamping trachea raised it to 170 mm. Severing both Vagi produced no effect. Stimulation of peripheral - tnd of right Vagus stopped the heart. O—~July 3, 1895, 226 Experiment 12—Dog, weight 15°8 kilos., ‘15 gramme morphia : hypodermically; ether during operation. . C.J - MARTIN. Remarks. rs nc Time. pressure ae rd 4 in mm., /heart beat hrs. mins. secs. in mm. Normal 110 28 0+ 0:20 146 32 Woe 96 22 3 camer ale & 83 4 OF.) 74 3 nian: a 66 ii 0 o 0 60 1 G10: 20 "25 G16. 0 59 “75 0 30 0 84 1 Ay 0 114 2 0 49 O 113 2 0 650 O 114 15 Ca 0 76 1 0 { 0 58 1 0 58 O 64 1 0 54 O 74 1 O 55 0 80 1°23 0 56 O 88 15 1 0-0 108 15 a es | 114 1°75 1 a OO 112 15 BO ate 15 + .20...01°- 106 1-25 135 6)... 1668 15 1. 2-0 113 2 -00008 grammes per kilo. injected into jugular vein. Injection lasted 1_ minute. : oa -0005 gramme per kilo. injected 0005 gramme per kilo. injected Experiment 13—Dog, weight 6°8 kilos., ‘1 gramme morphia hypodermically ; ether during operation. jugular vein. bled to death es : Curare injected into Co ee Time. Blood pressure| in mm. of Remarks. hrs. mins. secs.. mercury. SS Normal 150 001 gramme per kilo. injected in : vein. Injection lasted 10 seconds. O20 90 et) 2..9 40 Oo .3-0 70 a 0 40 92 intravascular clotting occured o 6.0 dead PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 227 ~~ (3) EZuperiments on curarised dogs, with artificial respiration, and vagi severed. Experiment 14—Dog, weight 10-2 kilos., *125 gramme morphia hypodermically ; ether during operation. Curare injected into jugular vein. Time, Blood pressure in mm. of Remarks, Normal 150 ‘000075 gramme per kilo. of body w injecten § in jugular vein. Injection vsited 50 seconds. CUNT OU Ne 8s o artificial respiration suspended _ artificial respiration continued re fell to 20m SB oBPSeoSoBoSoSoSoRS coo coocoocoocoooseeoocooSesSooSsSocoSoSsS " tw) tb 41 view end of ini rhe stimulated, press laa~s TWAAMMNNKHEPWWNHNHROCOOCoOoCoCOoOSSSO | _ oo dead Suspension of artificial respiration for one minute raised the Pressure from 48 to 101 mm. 228 C. J. MARTIN. Experiment 15—Dog, weight 15-9 kilo., 2 gramme morphia hypodermically ; ether during operation. Curare injected into f jugular vein. . Time. Blood pressure in mm. of Remarks, hrs. mins. secs. ercury. Normal 136 ‘00005 gramme per kilo. Gf ee weight — pct into jugular vei 0 O 30 100 Go T..8 78 2 | ae en © 62 CS St 56 20 40 Or 25:6 64 0 30 O 103 gS i a 128 0025 gramme per kilo. injected jn? apa 76 ee OD 65 boos) 54: Bes aa I 71 + ee 62 artificial peupiesiias suspended ae Oo 128 artificial respiration continued ee ef 90 28 @ 53 2 0 37 2 40 O 28 2 43 -0 19 dead a Suspension of artificial respiration for one minute raised the pressure from 62 to 131 mm. (4) Experiments on dogs after severing the spinal cord in the — cervical region. ; Experiment 16—Dog, weight 6°6 kilos., -1 gramme of morphit given hypodermically ; ether during operation. Time, Blood pressure in mm. of Remarks. hrs. mins. secs. mercury oo Normal 101 | cord rptanaote at level of 3rd cervical vertebra 0: 6. 6 50 + 00008 mme per kilo. injected into j G § 30 42 pe 0 836 36 O72 6 30 G:. - 8. 0 29 slight inspiratory iit oe: 2.6 20 oe : 18 8 14 deed a : : . & | ' ae ae Ee PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, Experiment 17—Dog, 229 weight 7 kilos., ‘1 gramme morphia hypodermically ; ether during the operation. Remarks. cord severed at level of 3 3.d cervi vical ve vertubra. ‘00005 gramme per kilo. injected into jugular vein. Time. Blood pressure} in mm. of hrs. mins, secs.| mercury. Normal 127 ao 68 oS 80 54 [i one Seed) 47 oe CO 41 Oo hs. iO 34 0-10: 0 40 O° Ss 6 45 0 20 O 48 0 30 O 56 0 45 O 57 sae ee 44 oe ae 38 1 30 0 33 1 40 0 26 © 80-0 22 hi he 0 13 dead (5) EZuperiments on rabbits, vagi intact ; without artificial respiration. Experiment 18—Rabbit, weight 1 kilogramme ; ether during Operation. i Time, Blood pressure tre a in mm. of . Mins, secs, mercury. Normal 107 0 0 30 "0 Oe ae 29 At i 2 sina: | ing Operation. Rear ga OE Remarks. 00006 kilo. of body weight mjectad Mats extort jugular vein. In- jection lasted 30 seconds. intravascular clotting. dead Remarks. Time Riaaa pressure hrs. mings, secs, ‘Wire : Normal 105 0 0 30 83 Sa 0 49 e820 53 ay 69 > a 00004 gramme per kilo. injected in jugular vein. Injection lasted 30 seconds. intravascular clotting. " dead wf ee ee ee 230 C. J. MARTIN. Experiment 20—Rabbit, weight 1 kilo. ; ether during operation, Time. | Blood — | in Remarks, hrs. mins. secs. | oo caseg Normal | 97 2 gramme per kilo. injected into jugular vein. Injection lasted 30 seconds. O70". 30) 76 LESAN Beta 1 64 Os 2 Ol 51 Coe Be 53 O10 70:4 60 0 15 O 74 0 30 0. 68 | 0 45-0 71 respiration increased in rate and extent. 1 0 0 62 ” >> 1 15 0 54 ” > »” 1 30 0 45 ” ” 3” 145 0] 44 2-0 0| 40 respir iration diminishi ng e386 33 respiration still greater in both rate and extent than no 2 30 O 27 convulsions. 2 38 OF 20 dead. 2 ee In the next two experiments the amplitude and rate of the respiratory excursions of the tambour-lever is placed opposite the numbers representing the arterial pressure at the time being. From these it will be seen that the fall in blood pressure is not in any way dependent upon diminished respiratory efficiency. eek Winans 21—Rabbit, weight 1:6 kilos.; ether during opera : Essai Near NOME ASR Mele es a Bl Respiration. oh Time. Picard RIT PEPE ; Remarks. 1 am rate i hrs. mins. secs caaihauename reg —_. pe el Normal 126 15 58 -00002 2 gramme per kilo. oa — a injected jugular oe eg 114 ry 72 O--) 30 06 16 66 : 15 0 124 52 52 kilo. 45 0| 130 42 84 | 00003 gramme per jected into ate = 2 PR 9 fame 1 84 48 56 yes ies | 95 51 60 iL 46. 0 92 50 60 2 16° 6 65 45 55 as 8 a 9 | 40 40 53 2 42) 26 — pat convulsions, 2 48.0 21 65 12 2 43 30 16 27 21 PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 231 In this experiment the respiration was well maintained for two hours forty-two minutes, when asphyxial convulsions occurred, due to the feeble circulation. Experiment 22—Rabbit, weight 1°75 kilos.; ether during operation. Time, Blood ces clepaneeart pressure amplitnc de rate per Remarks, hrs. mins. secs. eure Normal 107 13 72 ‘000005 gramme per kilo. in- jected into jugular vein 0:58 0 96 1l 60 071830 84 ud 69 0 48 O 80 10 52 jee at) 82 9 4:4, | Mae) enae 0 72 10 36 a 380 80 ll 40 5 grm. per a lepapiaie 1 40 0 55 1l 4d nice slow cme a4 6 23 50 67 convulsi 1 41 10 58 65 val 1 41 30 20 12 52 1 12 2 1 48 20| 11 55 4 eee 6 | | heel In this experiment the respiration showed signs of failure, but the asphyxial convulsions must be attributed to the simultaneous enfeeblement of the circulation. Tn the next two experiments the venom solution was raised to the temperature of 85° C. for a moment previous to injection. } 5 a 23—Rabbit, weight 1-4 kilos.; ether during Operation Time. —_| Blood pressure! ; in mm. of ; Ars. mins. secs, iiercusy. 4 —— eh) he i ie pe ee Mormal 106 pieetice of -0035 ome per kilo. into 0 19 os rnal jugular vein aa 74. er oe) 68 ak? 78 —? 104 30.0 112 pO 105 . 90 102 20 | 106 _| killed by bleeding. 232 C. J. MARTIN. ae Experiment 24—Rabbit, weight 1:8 kilos.; ether during operation. Venom solution heated to 85° C. previous to injection — Time. Blood pressure| - in mm. 0: Remarks. le hrs. mins. secs. mercury. Normal 102 "01 gramme per kilo. injected into bo he vein. Injection lasted 3 minutes OS. 82 0.54" 80 OG. 6 0 79 2 atc doubled in rate and extent. 0 6 0 44 j A ae 36 . Go BO 40 respiration diminishin ng. ‘ a: 9 6 33 ee cence : but greater than : r 0 10 0 56 | convulsi : eee 8 eae 12 long cae csaviie respiration. 4 0 12 0 8 | dead. 4 In this experiment when the pressure had fallen to 33 mmy asphyxial convulsions occurred, although the respiration at the ; time was above the normal, both in rate and extent. Observations on the blood pressure after subcutaneous injection of E the poison. When the poison is subcutaneously introduced, the effect aon the blood pressure is complicated by the results of simultaneous 4 paralysis of the respiration, to a much greater extent than under i the previous experimental conditions. The cause of this differ: ence will be discussed in the section devoted to the consideration of the effects of the venom on the respiratory mechanism, but it is necessary to mention the fact now. Blood pressure records taken from an animal into which the poison has been subeutane : ously injected exhibit the effects of the primary asph Seon of the vagus and — centres, and the 2 necessary to eliminate these secondary results due to its 0 at the same time upon the respiratory mechanism, by PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 233 artificial inflation of the lungs. The effect upon the blood pressure without artificial respiration can, however, be seen on reference to the experiments at the end of the section on the effects of the venom upon the respiration. In the detailed account of those experiments, the pressure in the carotid artery at intervals during the course of the experiment, is enumerated, together with the rate and amplitude of the respiratory movements. On com- paring the experiments with and without artificial respiration, it will be seen that life is only prolonged to a very short extent by maintaining the respiratory efficiency of the animal by mechanical inflation. Tf death from asphyxia be prevented by such means, the animal succumbs within a few minutes from heart failure. Experiments 26, 27 and 28, in which the artificial inflation was suspended for a few seconds at intervals in order to ascertain the extent of the action of the poison on the respiratory mechanism, show that the heart ceased to beat within five minutes from the time when natural respiration had completely ceased. The animals upon which these experiments were performed Were rabbits. They were anesthetised with ether, and the carotid artery connected with a mercury manometer. The trachea was connected with a Marey’s tambour and the artificial respiration pump. The air was warmed by being passed through coils of lead Pipe immersed in hot water before being pumped into the lungs. The arrangement of these connections was such as to admit of changing from artificial to.natural respiration or vice versa by turning a tap, and without interfering with the registering tambour. A tracing of the normal blood pressure was first obtained, = then the poison dissolved in 1 cc. of normal salt solution, injected, Further tracings were taken at intervals of fifteen ae or less, during the course of the experiment. The poison Was injected into the peritoneal cavity in two experiments and in the others under the skin of the abdomen. The result of all the 234 C. J. MARTIN. experiments was the same. The pressure fell slowly at first, and rapidly at the end of the experiment. With large doses, Experi- ments 25, 26, 27, it fell considerably, even during the first ten minutes, but with the smaller quantities it remained nearly at the normal for the first two hours and then fell rapidly until death. Y At the same time the excursions of the style occasioned by each beat of the heart were very greatly diminished until they became imperceptible. Experiment 25—Rabbit, weight 1-3 kilos. Time. Blood pressure in mm. “a Remarks, hrs. mins. secs. mercwu Normal | 90 ‘01 gramme of poison per kilo. of Pris: 7 | injected into peritoneal cavity. USO GG ae | 61 0°25 0 59 0.35 0 25 0 40 0 22 0: 55.0 23 Oo Sr: | 81 Bo 628 24, bs 536-70 | 13 | dead. Experiment 26—Rabbit, weight 1-6 kilos. ues Time, Blood pressure : in mm. of Remarks. hrs. mins. secs.) mercury. Slrsemigess LS Normal 94 | -0075 gramme per kilo. of body weight it- jected ‘aks peritoneal cavity. G16 4 89 0-15 '@ 94 0 30°98 82 0 45 O 88 Beat 74, 1 10 0 50 artificial respiration pegs et i ee sooo natural respiration slight 1 a0. 19 89 vagus beats. he. 0 51 1 20 0 44, artificial respiration s Na 1 respiration toe8 epi 1 30 0 28 artificial respiration suspenders 5 Natural respiration a 1 32 0 10 dead. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 235 Experiment 27—Rabbit, weight 1-25 kilos. Remarks. Time. | Blood pressure} in mm. of hrs. mins. secs.| mercury. Normal 91 OB). 85 0:10 0 90 1p 0 94, 0 30 0 88 0 45 0 87 Pong 6 82 4 Sse 1 78 Eso oO vai 1 0 64 1 # 0 55 27:5 0..0 42 Y Giese 7b 28 2100 20 3-13... 14 ‘0075 gramme per kilo. injected subcutane- ously into abdominal wall. pear respiration suspended during “i conds. Natural cee very feeble. — respiration suspended during 7 onds. Natural respiration absent. dead. Experiment 28—Rabbit, weight 1-75 kilos. Remarks. Time. Blood pressure : in mm. of hrs. mins. secs, mercury. Sy NaeepmeereD Normal 98 0 30 Oo 99 0 45 6 90 a 89 A 25. 0 88 2a 92 {Se Ce 92 en a 91 2.16 0 96 2 30 0 92 245 0 84 0 @ 56 3°15 0 22 a a 6 uy 0035 gramme per kilo. of na weight in- jected under skin of abdome artificial respiration suspended 5 seconds. Natural respiration feeble. artificial respiration suspended 5 seconds. Natural respiration very feeble. ificial respiration s 236 C. J. MARTIN. Experiment 29—Rabbit, weight 1-2 kilos. Time. Blood pressure] ; in mm. of Remarks. hrs, mins. secs, mercury. : Normal 102 ‘0035 gramme per kilo. of body weightim jected under skin of abdomen. Uo 75.00 100 9 30 0 97 0 45 0 97 poe, | Fae 93 bee 90 1 30 0 87 1 45 0 89 A | OBR A, 84 RS Sie 78 2 30 O 75 2 45 O 75 ps eae SL 69 & 15° 0 52 38 25 0 bl 3 30 0 26 3 35 O 22 3 40 0 17 3 44 0 15 dead. Simultaneous observations on the arterial blood pressure and the : ? volume of the kidney or spleen following the intravenous — injection of the venom. These experiments were performed on dogs. The animals wet® given a hypodermic injection of morphia half an hour previously and inhaled ether during the operative procedure. The carols artery and jugular vein were dissected out. The former e connected with a mercury manometer, and a cannula tied in 7 vein by means of which the venom containing solution was in’ duced. The kidney was reached through the loin, and placed _ a Roy’s oncometer and surrounded by hot cloths. I . using oil as Roy originally did, hot water was used and = membranes enclosing the organ were previously soaked py The oncometer was connected to the piston-recorder by an ini rubber tube with stout walls. Unfortunately the range of ma ment of the piston-recorder I have worked with is insufficient ® register the great variations produced in the volume of the kidney by the injection of snake venom. The spleen was reached by ® ES paso vret Vaat yeni ee PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 937 long incision at the outer border of the rectus muscle, and placed in Roy’s spleen box. Hot water was used to surround the organ, which was prevented from cooling in the same manner as before. In these experiments, however, the piston recorder was discarded owing to its insufficient range, and the end of the rubber tube farthest from the spleen box was connected with a small burette graduated in 34;ths of acc. The level of the water in the burette was adjusted so as to be three inches above the level of the spleen box, in order that the pressure on the outside of the organ should approximately equal the pressure in the splenic vein. During the progress of the experiment, the graduation opposite the level of the water in the burette was read off by an assistant, and at the same time an indication was made on the blood pressure record by raising the signal line. An increase in volume of the organ, due to increase in the capillary pressure within the organ, is indicated by the water flowing into the burette. Diminution in volume is indicated by a corresponding flow out of the burette. By reading off the increase or diminution in the water in the burette, a measure of the alteration in volume is obtained. In tabulating the graphic records, the height of the arterial Pressure curve has been measured as before, and in the spleen volume experiments, the volume in cc. by which the organ was diminished, has been placed opposite the value of the arterial blood pressure at the moment. With the kidney experiments the value of the ordinates on the curve in cc. was ascertained by observing the extent of rise or fall of the lever of the piston recorder which corresponded with the entrance or exit of | ce. of fluid into the piston box. This tabulation is not quite accurate, Owing to the lever moving in an are, and therefore the value of the ordinates is not uniform, but this error may be neglected for the present purpose. Tn observing the volume at any particular time, the maximum value and Minimum value of the respiratory undulations were both recorded and the mean taken. With the spleen experiments the Variations in volume caused by the rhythmic contraction of the 238 C. J. MARTIN. organ itself, were accounted for in the same way. These contrac- tions diminished or disappeared when the arterial pressure sank greatly after the introduction of the poison, and reappeared in those cases in which the pressure temporarily recovered, to vanish again as the pressure finally sank. Experiment 30—Dog, weight 13:5 kilos. ; curarised ; artificial : respiration ; carotid connected with a mercury manometer; vag! — cut; poison introduced through a cannula in the external jugs vein ; right kidney placed in oncometer. Time. Blood | Volume pressure of hrs. mins. secs.| in mm. | kidney. Normal 146. | normal | °000035 a per kilo. injected into jugular ve 0= 0° 30 103 -1 ce. CO peas 0 81 — 21 ce. Oe 0 64 ° Oa 55 * Dich OD 52 * O60 44 * 0: 16) =) 40 = 0 10 .0 32 ah OG: 4626 30 * ee oe 18 * dead * Denotes that the diminution in volume of the organ is ~~ than the piston-recorder could indicate. Experiment 31—Dog, weight 9 kilos.; hypodermic injection & 2 grains of morphia acetate ; ether ; vagi cut; carotid con with mercury manometer; poison introduced through a canna : external jugular vein ; right kidney placed in oncometer. Time. Blood Volume — | of hrs. mins. sees. mm. | kidney. SS ee SSRN ‘ected inte Normal 120 | normal | -000015 Aare sag per kilo. inj jugular vein aa Seay i 96 -1'8 cc OB. @ 73 * 0 10-6 75 * 0:20 0 90 * 0 25 0 106 —1°8 ec. 0 30 0 112 0 42 0 Remarks. oli i lr Remarks. -6 ce. 7 ie 108 —7 ce. | animal bled to death. o PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 239 * Denotes that the diminution in volume of the organ is greater than the piston-recorder could indicate. During this time its lever described a straight line on the drum. As the pressure again rose the piston recommenced to describe the characteristic volume curve, exhibiting the cardiac and respiratory undulations, Experiment 32—Dog, weight 3°6 kilos.; 4 grain morphia injected hypodermically; ether; vagi cut; carotid connected with a mercury manometer; poison introduced through a cannula in external jugular vein; spleen placed in oncometer. Volume of spleen when dead = 30 cc. Time, Blood | Volume pressure ° Remaris hrs, mins. secs.| in mm. | spleen. Normal 133 | normal | 0001 gramme per kilo. injected into jugular vein. 0 O 30 112 |-0°8 ce ee Se 1 82 |-18 ,, Ws SO 68 |—2°1 ,, ih :.0 s..i4st... 010 0 79 1-16 ,, 0 20 0 105 |-0°9 ,, 0) 198 |-94 , 0 45 O 101 |-08 ,, 1 0 0 5 -08 ” eeODHED 63 |-16 ,, ee 41 |-1-9 ,, 210 0 $1 |-20 ‘,, 21 Oo 28 |-20 ,, a2 17.0}. 23 |-2°0 ,, | dead. Experiment 33—Dog, weight 4°3 kilos., 1 grain morphia hypo- dermically ; ether; vagi cut; carotid connected with a mercury manometer ; poison introduced through a cannula in the external Jugular vein ; spleen placed in oncometer. Volume of the spleen when dead = 36-5 ce. Time, Blood | Yolume_ 0 f hrs, mins. secs. 38 mm. spleen. Remarks, | ic ae Normal 120 | normal | ‘000075 gramme per kilo. injected into jugular vein. 0 oO eae ~2U yy —31 »”» 240 C. J. MARTIN. Time. Blood | Volume | pressure | of Remarks. hrs. mins, secs.) in mm, spleen. ae 0 10 0| 102 |-08.,, Oo 165.0 110 p08 x G38 6 | 108 |-03 ,, 0 45 O 103 |- 04 ,, Lo 8 96 |-09 ,, a es! eee & | vi. |-0°9 ", 2 rO OF 91 |-1'0:',, 2° 307-0 | 65 |-2:2 ,, 240 0/ 68 |-29 ,, 2 50 O| 564 |-31 ,, P 3° O.. 0 OM |= oo 45 4 $ 80.°0| 1 48 1-40, B40. 04 36 |-40 ,, S80. 2 |-40 ,, | 4°00 | Si |-41-.,, oe 8} 18 |-42 ,, | dead. : V.—Errect or VENOM ON THE NERVOUS SYSTEM. The venoms of all snakes directly, or indirectly affect the nervous system. The introduction of snake poison is followed by depression, : faintness, loss of co-ordinating power, and ultimately by paralysis : These symptoms point to alteration in either the nervous centres or the peripheral nerves. Brunton and Fayrer concluded, from their experiments, that 4 the peripheral termination of the motor nerves were actually paralysed by cobra venom. These authors repeated Claude Bernard’s classical experiments by means of which he demonstrated that curare paralysed the peripheral terminations of motor nerve ’ The results with cobra venom showed that this poison exerted & ; similar effect. They were however, of opinion that paralysis ¢ ; motor nerves was not the only effect of cobra poison oP oe nervous system, but that the spinal cord was also paralysed. a some instances paralysis of the spinal cord appeared to cause death, when little or no affection of the motor nerves could be observed, but in other cases the peripheral paralysis was So? — marked. They thought it was doubtful whether the ete was directly affected by the poison, as the intelligence both = 7 man and in animals often remained unimpaired to the last, a a PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 241 the stupor and drowsiness which were sometimes noticed, might have been caused indirectly. According to Wall,’ the principal action of cobra poison on the nervous system, consists of an extinction of functions extending from below vpwards, of the various nerve-centres constituting the cerebro-spinal system ; and though, no doubt, other parts of the nervous system suffer, this poison acts especially on the respiratory centre, and on those other ganglia allied to it in the medulla oblongata, which are in connection with the vagus, the spinal accessory, and the hypo-glossal nerves, and it is directly to this destructive action that we have to attribute death in most cases of cobra poisoning. Wall found, however, that there were marked differences between the actions of the poison of the cobra, and Daboia russelii, (a viperine snake) upon the nervous system. The poison of the latter almost always occasioned violent convulsions, which were not due as in cobra poisoning to failure of the respiration. They occurred quite suddenly, and were in no way obviated by artificial inflation of the lungs. Sometimes the animal died at Once, sometimes after a partial recovery. Wall thought these convulsions were caused by the direct operation of the poison on the nervous system and not by asphyxia. Nevertheless, I feel convinced that they were in reality asphyxial convulsions, and due to intravascular clotting, whereby the circulation was impeded, or altogether stopped. Another very interesting fact discovered by Wall was that if Daboia venoin was heated to 100° C. its power of producing these convulsions was abolished. Injection of the boiled poison caused @ gradual cessation of the respiration, followed by a few convul- sions, due to respiratory failure. Exactly the same result is obtained by heating Pseudechis venom to 85° C., and I have already shown that this is because its capacity to occasion intravascular clotting has thereby been aimost destroyed. 1 “Indian Snake Poisons.” P—July 3, 1895, 942 C. J. MARTIN. Feoktistow on the other hand, experimenting with the venoms : of Crotalus and Vipera berus, found that even when complete — paralysis of the extremities had occurred, faradisation of the — peripheral end of a nerve produced perfectly normal contractions : of the muscles, and he was unable to find any interference with ; the passage of nerve impulses to voluntary muscles. (No curare : effect). P These venoms produced a gradual paresis, involving, asa rule, — the hinder extremities first, and soon passing into a condition of — complete paralysis. The reflexes disappeared either before, or at : the same time as the onset of paralysis. He was unable to restore — the diminished or lost reflex activity of the cord by even intra- venous injections of strychnine ; nor could he produce any move ment of the opposite limb by faradaic stimulation of the central end of the sciatic nerve, even when the paralysis of the hind limbs was still incomplete. During the later stages of poisoning he observed dilation of the pupil. Ragotzi' has-recently, by an extensive series of experiments — frogs, confirmed the results obtained by Brunton and Fayrer, 8 4 the action of cobra venom on the peripheral termination of the motor nerves. He has also by some ingenious experiments shown — aoe 3 “ 5 Re mi i etl ti tT ns that the same occurs in mammals, and is of opinion that to this — peripheral paralysis the nervous symptoms are almost entirely due. : In summing up the results of his experiments he says—“Ieh glaube daher, dass durch das Najagift eine specifische primaire Lahmung der nervésen Centra nicht hervorgebracht wird. Tn sie irgendwo in die Erscheinung, dann ist sie wohl nur secundarer Natur, d. h. die Folge von schweren Circulationstérungen.” When Pseudechis venom is introduced into an animal, after?” period of uneasiness which varies according to the amount injected, it becomes sleepy and lethargic, and if a dog, it vomits. bret lethargy increases, and is succeeded by weakness, which is at — ) most_manifest in the hind quarters. The animal remains quiet, — 20 I Loc. cit. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 243 and disinclined to move. If made to walk its gait is unsteady, and accompanied by incoordination of movement. At the same time it responds less readily to any form of stimulation, and its senses appear dulled. Later it is quite unable to stand, the pupils become dilated and insensible to light, and the breathing shallow and slowed. In this condition it responds sluggishly to painful stimulation, although the skin and corneal reflexes, and movements evoked by stimulation of the sensitive hair of the snout, are still rapidly produced. Eventually no response can be evoked by stimulation from any of the surfaces, and the corneal reflex disappears last. By this time the respiratory movements have become very sluggish, and with the exception of occasional long inspiratory gasps, greatly diminished in extent. The respiration ultimately ceases when with or without a few feeble convulsive movements, the animal succumbs. [ have already shown that the venom paralyses the heart, and thereby gradually depresses the circulation, and it is quite con- ceivable that all these nervous symptoms could be produced by a gradually diminished blood supply to the central nervous system. Accordingly, before we can draw any conclusions as to how far these results are due to a direct interference with the function of the nervous system, it will be necessary to eliminate the operation of this factor. By varying the conditions of the experiment, it is however easy to show that, although in many cases the circulatory depression contributes to the gradual extinction of function of the nervous system, the venom does itself exert a very powerful action upon the medulla and cord, and more especially upon the respiratory centre, When the venom reaches the circulation in a considerable quantity at one time, the heart is the more affected, whereas the respiratory centre is sensitive in a higher degree to the continuous °peration of the poison in small concentration. This conclusion as arrived ut from the fact that in those cases where the poison 'S rapidly introduced into the circulation, as when small quantities 244 C. J. MARTIN. intravenously, or large quantities subcutaneously, are injected, the more obvious effect is that produced upon the heart, butif the delivery of the venom be slower, as when it is subcutaneously injected, in not too large amount, the function of respiration is the one more particularly interfered with, whilst the circulation may be well maintained. In fact, were two separate observers to experi- ment, the one with intravenous, the other with subcutaneous injections, the conclusion of the former would be that the principal action of the venom was that of a cardiac poison, while the latter might consider -that any interference with the circulation was altogether subsidiary to the action of the poison on the respiratory mechanism. Different species of animals also exhibit some variation in the relative degree of sensitiveness of their vascular and respiratory mechanisms to the poison. In dogs the effect on the vascular mechanism is, under similar conditions, generally more manifest than in rabbits, whereas the latter appear to be particularly sensitive to the influence of the poison in that portion of the nervous system connected with respiration. It must, however, be distinctly understood, that in all animals the venom produces @ profound paralysing effect upon the heart, and even in rabbits, life can be prolonged but a few minutes by means of artificial 3 respiration. In those experiments in which immediately @Y signs of diminished respiratory activity were obvious, artificial inflation with warmed air was resorted to, the blood pressure fell to within a few mm. of zero, and the animal died very shortly . after extinction of ordinary breathing had occurred. It would appear as if the poison must reach a certain proportion ‘ in the circulating blood, before it can seriously interfere bigs cardiac contractions, but once this proportion is reached, the heat’ ; is very speedily and profoundly affected. When the meee of the venom is slow, it may however effect a gradual paralysis re the more sensitive respiratory nervous mechanism, before aS present in the blood in sufficient concentration to produce ~ appreciable diminution in cardiac activity. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 245 It is not, however, so easy to eliminate the influence of deficient circulation, as a possible cause of the symptoms of general paralysis of the cord which occur in poisoned animals, because the rest of the nervous system does not exhibit the same degree of sensitiveness as the respiratory centre. Nevertheless, one may infer that a poison which produces so deadly a paralysing effect upon a special group of nerve cells, will exert the same influence though in lesser degree upon the rest of the nervous system. ‘There is indeed absolute evidence of this, in the case of cold-blooded vertebrates, such as frogs, and although with mammals the evidence is not so completely satisfactory, it nevertheless leaves no reasonable doubt that a diminution of the reflex activity of the cord, due to the direct action of this venom on the nerve cells, exists after the injection of the poison. In the section devoted to the consideration of the effect of the poison on the circulation, I stated that after the introduction of venom into a vein, a great fall of blood pressure occurred, which was accounted for by a direct paralysing effect of the poison upon the heart. When, however the quantity injected was a small one, the blood pressure very soon regained its former height, and the circulation was as well maintained as previously. Nevertheless the condition of the nervous system of the animal is very different to that immediately preceding the injection. When removed from the table it shows great weakness, and is often unable to walk, or even to stand, but lies helplessly in any position in which it may have fallen after a few incoordinate attempts to regain 4 normal attitude. Its tendon reflexes are feeble or altogether aesent, and it reacts sluggishly to any form of cutaneous stimulation, Rabbits of about two kilogrammes in weight, which have received “01 gramme of venom subcutaneously, die in from two to three hours. The immediate cause of death, as I shall presently om, is due in most cases to respiratory failure. If, directly the respiration becomes shallow, artificial inflation of the lungs be employed, they live some fifteen or twenty minutes longer. In 246 C. J. MARTIN. three experiments in which under these conditions a tracing of the arterial blood pressure was taken, this ‘was maintained at, or a very little below the original height, for some ten minutes after the power of the animal to breathe, had absolutely disappeared. In these experiments shortly before the cessation of ordinary e respiration the abdominal skin reflex which is so strongly marked in rabbits could no longer be elicited, and its disappearance was followed by that of the corneal reflex also, while at the same time the efficiency of the circulation was maintained, as was shown by the blood pressure remaining as high, or nearly as high as at the commencement of the experiment. (a)—Effect of venom on the reflex activity of the spinal cord in Frogs. After the introduction of ‘01 gramme of venom into the dorsal lymph sacs of frogs, the animals soon show signs of advancing paralysis. In about ten to fifteen minutes after the inoculation, the respiratory movements become slow, and eventually ceas It now responds only sluggishly to cutaneous stimulation, and if turned over on its back can with difficulty regain the prone position, on account of the incoordination of its efforts. A few minutes later the animal is quite unable to turn over, when placed on its back, and responds slightly or not at all to every form cutaneous stimulation. In about twenty minutes it is absolutely : paralysed, and even stimulation of the central end of a divided a Sciatic nerve is unable to produce the slightest reflex response. :. Now it is obvious that one cannot draw any conclusions concert ing the direct action of the poison upon the nervous system from such an experiment, as suspension of the circulation produces the : ae ag a If a frog in this condition be opened, the heart may be beating : feebly, but in most cases the whole circulation is thrombosed. same result. Thrombosis may however be obviated, as I have : previously mentioned by raising the temperature of the venom — solution to 85° C. before injecting it. In the remainder of my experiments on frogs this was done; ‘Ol gramme of this venom never produced thrombosis, but the animals show od the PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 247 same symptoms of gradual extinction of function of the nervous system as those inoculated with the unheated venom. When the animals were completely paralysed, the heart was found to be still beating fairly strongly. To test the effect of venom on the reflex activity of the cord, Ture’s method was employed. The brains of seven frogs were destroyed, and the animals were then hung up in a row by the lower jaw. About every five minutes the foot of each frog was dipped in a -4% solution of sulphuric acid. The moment the foot touched the fluid a chronograph was started, and the moment there was any movement of the leg, it was stopped. The chronograph measured to one-fifth of a second. The time intervening between the commencement of the stimulation and the beginning of response, (latent period of response ), was then noted, and the foot of the frog washed in a beaker of water. The whole process was then repeated with the next frog. Ags the activity of the cord diminished, the latent Period increased. When the seven frogs had been tested three times in this way, ‘01 gramme of venom dissolved in °5 ce. salt solution, and previously heated to 85° C., was injected into the dorsal lymph sac of three of them, and the hearts of two were cut out, while the remaining two served as controls. The effect of the poison, and also the effect of cessation of all circulation upon the latent period of response is shown in the following table, where the columns of figures represent this latent period of response in seconds. et: rk: Frog 2 Frog 3 Frog 4 Frog 5 Treg 7 | Frog 7 Seconds | S ds. | 8 ds. | Seconds, | S ds. | Seconds. | Seconds. Se" 26 | is |" 26 | 20 | 20 | 16 bee ob “1 +e 2°2 2-4. 13 ~~ 1-4 16 10 ,,/} © 28 26 Be 1:2 ‘8 1:8 es ag ee heartcuti/heartcut|'01 gramme heated venom t u injected into lymph-sac. : : P bi a 6 30 28 1-0 1:4 1:0 18 3-30 it he 28 2-4 1-0 1-2 18 22 eo... © 22 26 1-2 46 3-4 40 349 ” 6 22 4:0 ~ |no response} 5 no respons? 345 8 3-0 10 response = no response ” = 30 ee 10 response a ” a Next day 3-4 4-9 oT or s : wee 248 C. J. MARTIN. While with the control frogs there was no very marked altera- tion in the reflex excitability of the cord until the next day, those frogs in which the circulation was abolished failed to respond in twenty-five and twenty minutes after the suspension of the cireu- lation. For the few minutes previous to the absence of response to stimulation, the latent period was increased. The poisoned frogs whose hearts were still beating moderately after the cessation of all reflex activity, however, ceased to respond after fifteen and 3 twenty minutes ; that is sooner than those in which the cord was deprived of all blood supply. Under these circumstances the effect on the nervous system must have been a direct one, and wholly independent of any interference with the vascular mechanism. (6)—The effect of the venom on motor nerves. The general features presented by an animal poisoned with the venom are strikingly similar to those which follow the injection of curari, The gradual cessation of all motor phenomena either of a spontaneous or reflex origin might very well be due to the poison operating in this way. The conclusion of Brunton and Fayrer, and Ragotzi, that cobra poison paralysed the peripheral ends of the motor nerves, lends additional support to such a view. With the object of investigating this point, I made a number of observations on frogs poisoned with the venom, in the same — way as the action of curari was determined by Claude Bernard. I also determined whether there was any evidence of such inter ference with the terminations of the phrenic nerves, and also” with the motor nerves of the brachial plexus of rabbits. Ragotat 4 found that the terminations of the phrenics were more sensitive : to the action both of curari and of cobra poison, than the other motor nerve endings ; and he sees in this increased sensitiveness the reason why so many observers have attributed a selective action upon the respiratory centre to cobra venom. Ihave both with frogs and mammals been quite unable of ~ discover any indication that Pseudechis venom produces a0 PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 249 upon motor nerve terminations. The symptoms of interference with the nervous system cannot be accounted for in this way. (i.)—Eaperiments with Frogs. In all these experiments the sciatic nerve on one side was dissected out fora length of about 1 cm. and a ligature passed under it and tied around the limb, but so as to exclude the nerve. The poison was then introduced either into the dorsal lymph sac, or into the peritoneal cavity, and was unable to reach the ligatured limb which was cut off from all circulation. As soon as all move- ment either voluntary or reflex had ceased, the lower half of the frog was cut off at the waist, the skin removed from the lower . half of the body and the sciatics of both sides stimulated as they lay beside the urostyle in the abdominal cavity. The capacity of the nerve to conduct impulses to the muscle, was ascertained by stimulating it with the induced current from a Du Bois Reymond’s coil, and recording the greatest distance of the secondary from the primary coil when a contraction of the gastrocnemius was caused by breaking the primary circuit. This — circuit contained one Daniel cell, and a moderately constant rapidity in opening the circuit was obtained by allowing a rotating cylinder to make and break a metallic contact. The cylinder was kept rotating at a uniform speed, and made and broke circuit with each revolution, The secondary circuit was short circuited by a Du Bois Reymond key. This was opened, when it was wished to stimulate the nerve, during one revolution of the cylinder, and then closed again. As only the minimal stimuli requisite to pro- duce * contraction were employed, the closing of the primary circuit just previous to its opening, failed to cause any contraction of the muscle. Experiment I.—Large male frog, weight 21 grammes ; left leg ligatured but so as to exclude the sciatic nerve. 237 p.m., -25 ce, of a 1% solution of Pseudechis venom injected into dorsal lymph sac. 320 ., both legs kicked when foot was pinched. areata Oe iatectere a 250 C. J. MARTIN, 4-0 p.m., both legs kicked when foot was pinche 5-0 ditto ditto 70 ,, responds sluggishly to stimulation; recovers with difficulty when placed on back. Next morning the frog was quite lively. In this experiment the condition of the nerves was not tried as an insufficient amount of venom had been inoculated. Experiment I1.—Sturdy male frog, weight 18 grammes prepared as in Experiment I. | 12:2 p.m., 5 ce. of 1% solution of venom injected into dorsal lymph sac. 12:20 ,, respiratory movements ceased ; pinching foot of un- ligatured limb causes it to be drawn away slowly. 12-21 ,, when turned over on its back makes no attempt to regain the prone position. 12:24 ,, corneal reflex gone. 12°25 ,, sciatic nerves prepared for stimulation. Maximum distance of secondary from primary coil when gastrocnemius contracted. Electrodes on | Electrodes on sciatic nerve. dorsal cord. Ligatured limb... 47 cm. | 32 em. | Unligatured limb 58 em. 88 cm. Experiment I[1.—Large female frog, weight 19 grammes, prepare as before. aioe: 12°40 p.m., 5 cc. of 1% solution of Pseudechis venom injected into dorsal lymph sac. 12°56 ,, respiratory movements ceased. 10 ,, when turned over on back unable to recover prone position. » allreflex movements absent ; sciatic nerves P Maximum distance of secondary from primary coil when gastrocnemius contracted. Electrod Electrodes on iatic pes dorsal cord. Ligatured limb.. 63 cm. 33 cm. Unligatured limt 59 em. 33 cm. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 251 I found that the venom had occasioned intravascular clotting in both these frogs. The blood in the whole vascular system was coagulated, except in the ligatwred limb. It therefore appeared quite likely that the venom had not been circulating sufficiently long to produce any influence on the nerve terminations, In the remainder of the experiments intravascular clotting was obviated by using venom which had previously been heated to 85° C. for a minute. Nevertheless the same paralysis followed, but it took considerably longer to develope when the same weight of poison was employed. Experiment [V.—Large male frog, weight 20 grammes, prepared as usual. 12°15 pm., ‘5 ce. of 1% solution of venom previously heated to 85° C. injected into dorsal lymph sac. 4:30 ,, respiratory movements feeble; recovers with diffi- culty when placed on back. 5°30 ,, respiration ceased. ro KS response to stimulation ; sciatics dissected out. Maximum distance between coils when gastrocnemius con ed. | Blectrodeson | Electrodes on | sciatic nerve. | dorsal cord. Ligatured limb...| 22 em. | 19 cm. | Unligatured limb| 62°5 cm. 27 cm. Experiment V.—Lusty frog, weight 18 grammes prepared as usual. 3:20 p.m., *75 cc. of a 1¥% solution of venom previously heated to 85° ©. injected in dorsal lymph sac. 330, respiratory movements ceased. Moves both legs slowly when feet are pinched; turns over with difficulty when placed on back. 334 ,, remains on back without attempting to recover. $37 4, all reflex response gone ; sciatics dissected out. Maximum distance between coils when gastrocnemius contracted. Electrodes on | Electrodes on | ciatic nerve. | dorsal cord. Ligatured limb...) 53 em. | 34 cn. | Unligatured limb 60 cm. 39 cm. 252 C. J. MARTIN. Experiment VI.—Frog (male), weight 20 grammes, prepared as usual, 4°30 p.m., 5 ce. of a 2% solution of venom previously heated to 85° C. injected into dorsal lymph sac. 3 4:45 ,, respiratory movements ceased ; recovers with difficulty when placed on back. 4:50 ,, all reflexes absent ; sciatics prepared for stimulation. Maximum distance between coils when gastrocnemius -ontracted. Electrodes on | Electrodes on sciatic nerve. dorsal cord. | Ligatured limb... 75 cm. 37 cm, Unligatured limb 79 cm. 34 cm. Experiment VII.—Frog (female), weight 18-5 grammes, prepared as usual. 4:30 p.m., ‘5 cc. of a 2% solution of venom previously heated to 85° C. injected into dorsal lymph sac. a 4:40 ,, respiration shallow; reflexes dull; recovers with — difficulty when laid on back. 5°35 ,, no reflex response ; sciatics dissected out. Maximum distance between coils when gastrocnemius | Electrodes on | Electrodes on sciatic nerve. | dorsal cord. ; | Ligatured limb... 61 cm. 32 cm. : | Unligatured limb} 58 cm. 33 cm. ‘ In nearly the whole of these experiments the contraction of the gastrocnemius was induced by a less stimulus in the poisoned is in the unpoisoned limb. Had the poison exerted any acs analagous to that produced by curari, the opposite result W si have been observed. The diminished sensitiveness of the muscles in the ligatured limb is explained by the fact that all cireulatio® L had been cut off since the application of the ligature. The long? the time which had elapsed since the limb was tied, the gre was the difference in sensitiveness between the two sides. PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 253 Experiments to determine whether the venom affects the motor nerve terminations of mammals. Ragotzi came to the conclusion that the terminations of the phrenic nerves in the diaphragm were more sensitive both to the action of cobra venom and curari than the endings of the motor nerves in the muscles of the limbs. I accordingly chose the phrenics for the purpose of ascertaining whether Pseudechis venom in any way affected the passage of nervous impulses through motor-nerve terminations. When a dose of 005 to ‘01 gramme of venom per kilogramme of the animal’s weight is injected either subcutaneously, or into the peritoneal cavity of a rabbit, within a few hours the respiratory movements are much diminished both in rate and in extent The diaphragmetic contractions become progressively weaker, until they disappear altogether, and after a few feeble convulsions, the animal dies of asphyxia. If artificial respiration be resorted to, the convulsions speedily cease. Nevertheless, artificial inflation does not prevent the death of the animal, which occurs within a few minutes from circulatory failure. Thave already shown that this gradual failure of all respiratory movement is not essentially dependent upon any alteration in the circulation. It might however, be occasioned either by paralysis of the respiratory centre, or by interference with the passage of herve impulses along the phrenics to the diaphragm, as Ragotai maintained was the case in cobra poisoning. To test the latter alternative, I arranged a series of experiments m which I determined the least stimulus which, when applied to the Phrenic, would cause a contraction of the diaphragm, both i before injection of the poison and at intervals afterwards, until Spontaneous respiration had entirely disappeared. _ As the venosity of the blood from the failing respiration would Itself Produce a diminution in the excitability of the muscular mres of the diaphragm, the complete aeration of the blood was “cured by artificial inflation of the chest with warm air, and as 254 C. J. MARTIN. enfeeblement of the circulation would also operate in the same — manner, a simultaneous record of the blood pressure was taken in — order to keep a check on this possible source of error. Rabbits of about 1} kilogrammes in weight were used. The carotid artery was connected with a mercury manometer, anda — glass cannula tied into the trachea, The glass cannula communi — cated with a Marey’s tambour, the artificial respiration apparatus, and the external air by three taps. By means of the tap connected — with the respiration apparatus, artificial inflation could be iy on or off at a moment’s notice. The lever of the tambour and : float with scribe on the mercury manometer registered ona travel: ling surface, the respiratory movements and the blood pressure respectively. The left phrenic nerve was dissected out inthe — - neck, and placed upon electrodes. The nerve was prevented from s drying by being, together with the electrodes, again covered with the skin. The phrenic was stimulated by the induced current : from the secondary terminals of a Du Bois Reymond’s coil, : and the primary circuit was broken by the same arrangement, a was used in the experiments with frogs, described above. In the ] primary circuit was a Daniel cell. At the commencement da each experiment a record of the respiration, blood pressure, and the greatest distance between the coils of the inductorium vie a contraction of the diaphragm followed stimulation of the phrenle, was obtained. It was not found necessary to open the abdomen and observe the diaphragm directly, as when a contraction of : left half of the diaphragm occurred, there was an unmistakeable sharp movement of the fur on that side, owing to the ue retraction of the lower ribs. The same series of observations were made every fifteen minutes after the injection of the eae and as soon as the respiration exhibited any signs of filet artificial inflation was brought into action by turning the 2 connected with the respiration pump. ‘The animal’s : to breathe by itself was recorded every fifteen minutes by lei off the artificial respiration for a few seconds. In the tabula’ account of experiments I have employed the extent of the resp FT, Cone tl as SE NT nie Vee eR aes 5 a TA ¥ aoae putes PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 255 ratory excursions of the tambour, as a measure of the condition of its respiratory mechanism. This does not however, indicate the total disablement, for the respirations were diminished in number as well as extent. Experiment I. Distance pred ica of between sor Remarks, coils cord, Before injection... 46cm. | 12 mm. 15 mi inutes after 1p 49 30 45 ” l hour 10 ms 47 cm. ete oe 49 ,, | 10 mm. | respiration slowed. ” 30 2” 49 ” 85 2 ” eed a” 45 ”> 49 ” 6 3” 2” 29 2 hours 0 a pe 55s, ‘ very slow. » 15 ve 45°, fe circulation began to fail. ” 30 ” 44 ” 2 2? ” 45 ” 42 ” 5 ” 8 hours 0 » 36 0 » Experiment II. SS es ST Sea Distance 'Amplitude of between | respiratory Remarks. coils. record. Before snore... Sem. | 14 mm. 5 minutes after me 30 * respiration much slower 45 ”» 36 cm 15 93 »” ” Lhour 0 » 6 14°65. ;, yy very slow. » 15 » 29°53, agen blood pressure fallen; corneal reflex gone; respiration very slow. Ht 90 = 30 ,, "BD sy oe | | 8 Experiment III. re ee a ie CT) apie +) Tae el ae oe aks ee zs mek Seb gs i a wee Dista A litude of between H respiratory Remarks. Before injection... | 41cm. | 15 mm. 15 minutes after ih pao 4 ” 41 re vo ee fe 40° 5, [26° S » - ” 42 Sy De ver » is 2» 42 ae 43 : a * 68 5 AAD 24s r.spiration slowed. 256 C. J. MARTIN. Experiment III.—continued. Distance |Amplitude of between | respiratory Remarks. coils. record, 2 hours 0 minutes after | 42 cm. | 10 mm. | respiration slowed. — » 15 > 42 ” 7 2” ”» 30 ” ” 4 ” ” 45 2” 41 ;; 35 2 3 hours 0 me 40 7 ee corneal reflex gone. ¥ 15 fo rs Ee 0 blood pressure as high} as at beginning of experiment. a Spe Re a6 0 blood pressure falling.| _ aE Experiment IV. a ict “ ee agey e between | respiratory Remarks. coils. record. ; a Before injection... ...| 42'¢.m.| 16 mm. 15 minutes after| 42 ,, | 19 ,, 30 ” AD 2? . s iS blood pressure falling. | lhour 0 6 UE Dee aes ee ” ‘ tage a ae ee abdominal reflex gone) 30 yy SOF: 5; 8 5 corneal reflex gome;| — pressure fallen to half.) 2? 45 ” 30 ” 0 ay Tn all of these experiments, the strength of the stimulus requisite Ss to cause a contraction of the diaphragm, when applied to the : phrenic nerve, was slightly greater at the end of some hours. big difference was however, very slight, and it is noteworthy that! the only case where the circulatory efficiency was maintained, tae strength of stimulus required was the same as at the beginning of the experiment three and a half hours earlier, whereas ® spontaneous respiratory movement had ceased fifteen me before. One would expect to find that the mere fact of ee nerve on electrodes all this time would in itself have produced diminished sensitiveness to stimuli. The experiments : “ show conclusively that Pseudechis venom in no way affects ee transmission of impulses from nerve to muscle. | VI.—Errect or THE VENOM ON THE RESPIRATORY Mucnanis® e The effect of cobra poison on the respiration has ber investigated by Wall who has published some interesting * tethor - PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 257 metric charts, taken from animals injected with this venom. The first change he noticed in an animal after the introduction of cobra poison, was a decided quickening and deepening of the respiratory movement. This increase was no longer to be seen after the section of the vagi. The quickening was only temporary, and after an interval of uncertain duration, the respiratory move- ment, became slower, and less in extent. This diminution con- tinued until the blood was no longer: oxy ted, when the animal ° died with the usual symptoms characteristic of asphyxiation. When a large dose (1 cc. of fresh venom), was introduced directly into the circulation of a dog, Wall found that thirty seconds after the injection, the animal was suddenly seized with asphyxial con- vulsions, in which it died in about one hundred seconds. Wall attributed these convulsions to a stimulation of the respiratory centre prior to extinction of the function of the same. This may be the correct explanation of the phenomena, but the injection of Pseudechis venom directly into the circulation produces pre- cisely the same series of events, and the explanation in this case is that the whole vascular system is quite suddenly thrombosed. The gradual extinction of all respiratory movement is, accord- to Wall, due to paralysis of the respiratory centre. Brunton and Fayrer! ascribe it partly to this cause, and partly to a curare-like action of the poison on the terminations of the phrenics in the diaphragm, whereas Ragotzi is of opinion that it is due to the latter alone, Wall’ has also investigated the action on the respiration, of the poison of the viper Daboia russellit. Its action in producing convulsions has already been discussed. If only small doses are subcutaneously injected, or if the venom be previously boiled, the respiration, after a preliminary acceleration, becomes slower and slower, until death occurs, Mitchell and Reichert? found that the venoms of Crotalus and Ancistrodon caused a primary increase in the number and extent 1 Loe. cit. 2 Loe, cit. 3 Loc. cit. Q—July 3, 1995, 258 C. J. MARTIN. of the respirations, followed by a decrease in both. These venoms affected the respiratory rhythm to a much greater extent than the respiratory excursus in the majority of cases. Feoktistow' found a tremendous increase in respiration, followed by asphyxia, after intravenous injection of the poisons of Crotalus — and Vipera berus. His conclusions as to the explanation of these phenomena are not very valuable, as he was undoubtedly dealing with cases of intravascular clotting, although he was quite — unaware of such a contingency. He does not appear to have made any observation on the respiration after the subcutaneous injection of the poisons. After injection of Pseudechis venom the respiratory movements become less and less, and ultimately cease. As I have shown that this action of the nervous system may occur independently of any effect on the circulation, and also that the venom has n0 effect on motor nerves, or their endings in muscle, it must exert its action directly upon the respiratory centre in the medulla. Its action in this respect is best seen when the venom is sub- cutaneously introduced in rabbits. Under these conditions, the : paralysis is often preceded by a period in which the respirations: are increased both in number and in extent. The period increased respiratory activity is much more strongly manifested in some experiments than in others, and is indeed not infrequently — entirely absent. Both Brunton and Fayrer? and Mitchell and Reichert’ state that the primary acceleration of the respirations was absent after cutting the vagi, and the first mentioned observers accordingly 4 attribute this increase in respiratory rhythm to the operation of : the poison upon the peripheral terminations of the vagi in the lungs. My results with Pseudechis poison are however not 12 accordance with such a view. The primary acceleration is often absent both in animals with severed, and in those with intact vag, but occurs with about equal frequency under both conditions. In mes 1 Loe cit. 2 Loc. cit. 3 Loc. cit. i PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE. 259 experiments in which the acceleration in rhythm and increase in amplitude of the respirations have been very pronounced, sever- ance of both vagi has had no influence upon the amplitude, and only a slight retarding effect upon the rate. The diminution in frequency of the respirations so produced, have not however been proportionately more than occurs after severance of the vagi in unpoisoned animals. I therefore conclude that the increase in respiratory activity which so frequently occurs after inoculation with Pseudechis venom, is due to a primary stimulating effect of this poison upon the respiratory centre. Sometimes these two phases of increased activity and diminished activity alternate, but the latter gradually obtains the ascendency. Eventually the respiratory movements become imperceptible, and unless artificial respiration be immediately resorted to, the animal dies of asphyxia. Just previous to the final cessation of all respiratory movement, it is not infrequently the case that the respirations occur in little groups separated by periods when the breathing is in abeyance. When the respiratory movements have ceased, the animal is - usually seized with afew feeble convulsions during which it makes Some inspiratory gasps of very considerable extent, showing that although the respiratory centre fails to respond rhythmically to the stimulus of blood of such venosity as to powerfully stimulate both the vagus and vaso-motor centres, it does still respond when this becomes excessive, The more rapidly this cessation of the respiration is effected by the operation of the venom, the more powerful are the convulsive movements just preceding death. In cases of slow poisoning they are altogether absent, In Experiment 1 of this section, the respiration ceased before the efficiency of the circulation was in any way diminished. This, however, is not generally the case, and although suspension of the Tespiration usually precedes cessation of the heart-beat, the activi- es of both these mechanisms decline together. The gradual 260 C. J. MARTIN, enfeeblement of the circulation contributes to the respiratory failure, and vice versa, and the simultaneous paralysis of the rest of the nervous system prevents in most cases any marked ls indication of its asphyxial condition. pa et ra Pa Details of experiments to ascertain the effect of the venom upon the respiratory mechanism. The experiments with this object were performed upon rabbits and dogs. The results were substantially identical with both — animals, but the former are much more suitable for the determin _ ation of this point, as their respiration is, under normal circuth- stances, more regular, and the individual respirations do not exhibit the same variations in amplitude as is the case with dogs, Hight experiments on dogs, in which the vagi were previously divided, were made. Of these, only two are here tabulated; the remaining six curves exhibit the same general characteristics as those tabu- lated, but the respiration both before and after the injection of the poison was so irregular, that although the general effect of the venom is clearly enough seen on looking at the curves themselves, these are unsuitable for reduction to a numerical form. This — difficulty is chiefly owing to the fact that after the vagi were severed the respirations occurred in groups. Four or five small respirations occurred together and were succeeded by @ deep : sighing respiration. In making a table it would be necessary — to state the variations ‘in amplitude and rhythm of both kinds of respiratory efforts. Such a table would be difficult to follow, and I have therefore decided to omit the records of thes? : experiments. ; The animals were anzesthetised with ether, and the carotid artery — connected with a mercury manometer, and the trachea with 9 Marey’s tambour. The style of the manometer and the lever of the tambour wrote upon a Hering’s kymograph. The experiments a1? arranged in three groups: in the first the venom was injected under : the skin, in the second into the peritoneal cavity, and in the thimt series it was introduced directly into the circulation through - PHYSIOLOGICAL ACTION OF VENOM OF BLACK SNAKE, 261 jugular vein. In some cases the vagi were previously severed, in others left intact, or cut during the course of the experiment, Graphic records were obtained in each case, both before and after the injection of the poison, and these curves have been measured and the numbers tabulated. Opposite the time indicated in the first column are placed the amplitude of the respiratory excursion of the tambour-lever, and the number of respirations per minute, together with the blood pressure for the time being. (a)—Observations on the respiration after subcutaneous injection of the poison. Experiment 1—Rabbit, 1-6 kilos, ; vagi intact. Time, ___ Respiration. ie Amplitude| Rate per pong Remarks. hrs. mins. secs.) inmm. | minute. | i#™m CAAT MR ee Normal 17 68 106 ‘005 gramme per kilo. injected under skin of abdomen 0 15 0 15 84 106 0 30 0 10 68 101 0 45 0 9 32 6 Sh a Be ae 28 95 7-6 01m 21 108 _| large slow cardiac contractions (vagus) 0 Or 4 28 96 2 15 0 12 32 91 = 80. 0°) TN 36 86 cw 9 |S 33 92 a0 0 2°5 24 113 | large slow cardiac contractions 3 5 20 112 ditto a7 0 os 101 ditto, slight convulsions ro) n =| ° ra 3) an a | | ® — a2 3 Pa i?) S a) aor quq Suryjou ‘sSaoqeor £q papunoasims ATozo[du00 ens se “* puvpsuq Jo 1eyg /Z6st 61 °99O | &F . ° ° : : ‘ON ‘Sycvure yy ‘opngrsuory ‘epngiqery eutNn s,drigg | a7" | 0m ‘NVHOO NUAHLOOS AHL NI SOUAEAOL cE ae a ea 2 Sik, Co ea as ake at Pi H. C. 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(|S SL-9F |" — PTSBO AOYRMOTT | CEST “F Tady| 96 ‘apIM Joo] porpuny ouo pue YStYy Joog AZJY Juoqe Yous sSxoqeor eeayy poyystg | “AT ss ‘Sep jt empog Jo yQatT |cest Tady| o6 "SpAVA1A}JV TES e1om ou ‘sooord [[eWs [BIeAOS puV 8.10q201 euo posseg | ‘GW 02-98 ‘S GL-PF |" te 2g G6st ‘8 Tudy ‘OUIT} OUO 4B 4 SIS UL SuLeq seo HIV] OULU ‘sSroqaor ssed 07 esInod s.diys sz0jTv 09 pee | ‘WH OF-08 ‘So pp ft ae Be e6sT 9 Tady ‘@pIS FIV TO $519q001 OSIV] [eioaos posse ‘A 93 ‘'S pp ol eae ea c6st ‘¢ Tudy ‘passed saoard [[ums [vIeANS pUR SHdOqooI INO | “W OF-ZZ ‘Sp i ats BYl2[NZ | CEST “Ff [Ady] 6 "Buoy arr JTBy puw ysry goog AQueaes 07 posuss S519 aor OY} ‘eor Jo JU SIS ULSAUp 9o144 SBA [OSSOA f NGOS SH1IqQeOI XIG ‘9-12 'S:09-PP |'"* “* QTBpspaea T, GEST ‘8Z “AVI! 86 ‘901 PlOH JO JOT B PUB SSrAqadI OMY Pass¥g bre oe ouhy fee af CEST ‘LT “APN sS10q [[BUIS snoremINU pUuy asav[ OAY passed | ‘| OF-OG |S 8o-FF) cs IIMOYS eBgl ‘ST AVA] B6 *saoerd Jo JOT & PUY SSAoqooI OMY passug | ‘WY OS-Sh | 'S OG-BF | * o1muBUey |¢6gtT ‘qorvyy] 16 ‘a01 JO SOTIMI poapuNny 4YS19 Jnoqe Yonoayy peyies S i ; ‘ “ON Bi cel. | ‘opngysuery | ee omen 8.4008 ond | jou a ee eee Oe PERT ey Lee re fas Breen ee ew ive Ee Ce a eam ‘NVSO0O NUAHLOOS AHL NI SOUMAAOr H. 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[TVS xIs puv osav, 10a oUO possed 08v4O Woz soprUt OGL‘ ‘Mopuo'T 07 purpvoz Mon ‘eSvoa UK | — ee! i ‘* adTysaareN |e68t “er Arne} SIT ‘poFY SIS SH19qooy Coayy YIM UT UOTTwy WoLBea Koy “HS 8 9F aordeA JO JINH /S68T ‘OL ‘Sny} F11 *9ep ‘urd g qu ate Jo oangvaod “wey, ‘9p urd ¢ qe “oF ‘urd F 4v “Of woom 4e 109RM vas Jo oanqvaodmay, ‘wd OT.g ye Queqstp sopim u00qzy ° ° * e ‘ON ulead ‘opngrsuory | ‘opngyywy omen, 8.drq8 | wd ‘PU ‘NVGO0O NYUHHLOOS AHL NI SOUAAHOI 314 ~ ICEBERGS IN THE SOUTHERN OCEAN. 315 On reference to the chart of icebergs given with this paper and the tabular statement, it will be seen that between January and July 1895, a vast number of icebergs were reported between the Cape of Good Hope and Australia, and it is remarkable that from the end of July to the present time, (November 28th) no ice has been reported in this region, except three icebergs sighted on August 10, by the Gulf of Venice (No. 114), Lat. 45°S., Long. 54° E. The only reason for the sudden disappearance of these vast fields of ice that I can suggest, is the prevalence of strong North-west winds over the Southern Indian Ocean, this is shown by the logs of ships traversing these waters. It is noteworthy that the ice which came with the great out- burst in 1854-5 also disappeared quite suddenly, as we are told by Towson, writing in 1858, who says, ‘‘ Since April, 1855 however, the only reports of icebergs are much farther south.” In the reports of various ships in the foregoing list, the question of change of temperature in air and water in the neighbourhood of ice is left in a very undecided state, the reports being very contradictory, (Nos. 29, 32, 34, 36, 38, 63, 69, 89, 103, and 113). Icebergs more or less discoloured are reported in Nos. 14, 19, 19, 26, 27, 38, 46, 55, 63, and 86, and in No. 46 it is suggested that “ Vigias ” may originate by the grounding of one of these aig icebergs, thus giving rise to the report of an uncharted d. Very large icebergs are reported in Nos. 10, 13, 17, 24, 26, 27, 29, 33, 34, 39, 47, 48, 55, 56, 57, 58, 69, 70, 73, 80, 81, 83, 84, 86, and 103. In the foregoing list of icebergs the one farthest north (No. 31) was In 37°§. We learn from “Towson,” page 6, that in January ey an iceberg was in sight from the Cape of Good Hope in latitude 34° g, 316 A. LIVERSIDGE. On some NEW SOUTH WALES anp otner MINERALS. (Note No. 7.) By A. LIvERSIDGE, M.A., F.R.S., Professor of Chemistry in the University of Sydney. [Read before the Royal Society of N. S. Wales, November 6, 1895.] ANTIMONITE—Queensland. A hard splintery variety, breaking with a conchoidal fracture with somewhat hackly surfaces; noticeable as containing silica and barytes in thin veins or joints. Analysis. Antimony a oe : 64°47 Sulphur... a oth a3 aii 26°69 Tron ... ous wi i 1-00 Silica ao de ba bis i Barium sulphate... da A a) ee Undetermined and loss... vas leiee eee 100-00 The above is the mean of two analyses. Sp. gr. 4°43. Apatite, PLumprrerous—Calcium fiuo-phosphate. Broken Hill. Some specimens of apatite containing lead were forwarded me by Mr. 8. Harris, from Block 14 Mine for examination. The apatite is in the form of small grey imperfect erystals, (some however are symmetrical hexagonal prisms closed by the pyramid and terminal pinacoids) about js” long, in cavities ina matrix of dark blue-black honey-combed crystalline zinciferous galena ; the freshly fractured apatite has somewhat the lustre and appearance of pyromorphite. It is probable that part the calcium phosphate of the apatite is replaced by the isomorphous lead phosphate. +: ae fre * ; : . ie eS Be RBI ena gO IU SOME NEW SOUTH WALES AND OTHER MINERALS. 317 The crystals of apatite were separated as carefully as possible from the galena, but this could not be done completely, as small crystals of galena are seen within the apatite crystals, 7.¢., when sliced and examined under.the microscope. Mr. Harris states that pyromorphite was met with in the shallower parts of the same portion of the mine in considerable quantities. He found 3-97 of fluorine, -57/ manganese monoxide, and 36:25 of phosphoric pentoxide, but as all the specimens I examined showed enclosed lead sulphide, I do not quote his amounts of lead and lime; the proportions of phosphoric oxide and fluorine indicate that the mineral answers to the general formula of $ Ca,P,0,, CaF, in which part of the Ca is probably replaced by Pb. BarkLyITE—Two Mile Flat, Mudgee, N.S. W. Collected by the late Prof. A. M. Thomson, Sydney University. The specimens were in small well rolled pebbles, not more than ¥' long. Most are of a kind of dull magenta colour and usually show one or two light streaks or veins, in others, the colour might be referred to that of lean beef. Hardness about 8°5, i.e., less than 9. Sp. gr. 3°738 at 18°5° C. The mineral is tough, and the fracture granular and of a pink tint, the powder is also of a pale pink tint. Before the blowpipe it darkens a little and returns to its former colour on cooling. After ignition it is a little more opaque, probably due to slight disintegration, When strongly heated, it becomes brilliantly luminous and gives a blue colour with cobalt nitrate. Large quantities gave the chromium reaction with micro-cosmic salt and borax beads. The precipitate of Al,O,3H,0, fused with NaKCOs gave the Dianganese reaction in one case but not in others. No full description of this mineral appears to have been pub- lished ; the name Barklyite was given to it by Mr. Geo. Milner Stephen, F.G.8., after the then Governor of Victoria. In a Catalogue of his collection, and in a lecture, he refers to 318 A. LIVERSIDGE. them as violet rubies, or barklyite, from the Ovens district in Victoria.2 Apparently, too, it has never been met with in any quantity, and the variety does not appear to be sufficiently distinet to warrant a special name. It consists principally of alumina, (Al,O;) but the analysis in hand is not yet completed. Curysoconta—Hydrous copper silicate. Broken Hill, N.S.W. As incrustations and stalactitic forms, with mammillated sur faces, of a sky blue and green colour. Vitreous lustre in parts. Conchoidal fracture. Hardness 4. Streak, pale blue. Effervesces slightly on warming with HCl, from the presence of a little copper carbonate. Before the blowpipe, it darkens and breaks up slowly with decrepitation. In tube it gives off much water and a nitro- genous odour. Soluble in HCl and HNO, with a residue of silica. Breryt— Vegetable Creek, New England, N.S. W. Described in a paper read before this Society, December 2, 1891. Sp. gr. 2°80. Hardness, 7°5. Analysis. Silica Rs eh 1 OS eee Alumina... ae as Ne pe Beryllia —_... dis a ie eres Tron sesquioxide ... sus es ove 6 Lime ais ‘ik we she ... traces. 99-4 Crocois1re—Dundas, Tasmania. In brilliant crystals of a deep orange-red colour, about 3" 6 seated on a mangano-ferruginous matrix. The Dundas mne% have yielded some fine groups of crocoisite crystals, with the prisms several inches long ; associated with cerussite, galena and occasionally anglesite and other lead minerals. Hardness, 2°5. Sp. gr. 5-92, 1 Trans. Roy. Soc., Vict., 1865, p- 70. en ee ee SOME NEW SOUTH WALES AND OTHER MINERALS. 319 Analysis. Lead monoxide ... on an aoe 66°86 Chromium tri-oxide aes ee Spe 30:99 Tron sesquioxide ... ay “as a 1-02 98-87 Which corresponds with the formula PbCrO,. FaHLerz— Wiseman’s Creek, via Brewongle, N.S.W. Occurs in quartz veins. Collected in September, 1888. No crystals were obtained. Analysis. Copper iia oe 33004 ead 630 Tron 2-844 Zine ‘ ps a 2 s 3-693 Antimony ... ae nae ope oe £020 Sulphur. sul LL Pe Nickel Aes a oe aye Fes trace. Cobalt e65 os ee eG wae (OPBCS. 99-998 The above corresponds approximately to + CuS, + (FeZn) §, Sb,S,. Some silica was obtained in the analysis, but this was deducted and an allowance made for it in the calculation, as it obviously belonged to the matrix, A special examination was made for gold and silver on a larger quantity, when 31 ozs., 17 dwts., 0 grs. of silver, and 2 ozs., 13 dwts., 8 grs, of gold per ton were found. ILMentrz—Cloncurry River, Queensland. Black, with traces of crystal planes, breaks with well-marked Metallic lustre, : Analysis. Titanium dioxide, TiO gw: ik .. 49°85 ilicon : Si BiOy ak ee Iron monoxide, FeO : 3576 Tron sesquioxide Fe,O, . 13-22 320 A. LIVERSIDGE. Manganese and magnesium are usually met with, hut they and other metals, although specially sought for, were not found in this specimen. Dana gives the following extremes :— TiO, = 59-20 to 3°55 / FeO = 46°53 to 3:26 7 Fe,0, = 93°63 to 1:20 /% ZINCIFEROUS GALENA. This mineral was sent to me from Broken Hill as clausthalite, the selenide of lead. Before the blowpipe it yielded the reactions lead, zine, and sulphur, with a little arsenic, but I could not get any reaction for selenium. Decrepitates strongly. It appears to occur in nodular masses. The mineral, in certain lights has a dull grey colour and scoria- ceous appearance, but in other positions the light is reflected from it brilliantly with a bluish-grey metallic lustre ; this is due to the fact that the surface is covered with minute cubical crystals, which have their planes more or less parallel, although at different levels ; my specimens only exposed about two square inches, but I think it would be found to extend over larger surfaces. The effect is something like that of “shot” silk. Under a 1” objective, the cubical character of the crystals are clearly recognisable, so also are the well -.marked cubical cleavag? planes, which have a strong metallic lustre. The mineral appears to be homogeneous, and no separate portions of blende were detected in it, so that the two sulphides seem to have been deposited t gether ; thin tilms of arborescent copper pyrites occur on some ¢ 3 the surfaces, and within crevices. Sp. gr. at 18°6-72. Itis slightly harder than galena. The nodules only contain a little zine ; but they have not yet been analysed ; On assay they proved to be very rich in gold, gave me 5 ozs. 17 dwts. 4 grs. per ton, and 0 oz. 19 dwts. ‘= of silver per ton; lead minerals are usually richer in silver than in gold. The vein stuff gave— SOME NEW SOUTH WALES AND OTHER MINERALS. 321 Analysis. LE IF. IlI Insoluble... tc oc BG 3°47 ea 60-20 61:014 Zinc... 15°50 14:85 Sulphur 18-94 Iron ... 2°62 Copper 205 Arsenic traces Antimony ... ... traces. 100-625 The proportion is about 3 PbS, 24 ZnS. Tt seems to be related to the minerals huascolite and kilmacooite! but with fairly well marked differences. I do not, however, think it need be named ; the term zinciferous galena describes it accurately without adding to the already excessive list of so-called new Species of minerals. LIMESTONE wiTH ConeE-1n-Cone Srructure—Picton, N.S.W. Evidently very impure, of a brown colour, and argillaceous appearance. An analysis of this was made in 1876, and for- warded to the Mineralogical Society, but lost in transit. IA a Vets on oe ee ee eee me ee? eee ee a Composition. Portion soluble in HGL wc ee a rem diets, 00, .. 4. . «S001 Silica, SiO... 1-63 Tron sesquioxide, Fe,0, ... 9 0. ss. 4°88 Manganese oxide, MnO... ... ws “BD en NO is so ig eae eo Pena eae gp OD ee ay a ye Paes Ma O.552) 2x, i Portion insoluble in HCl ai parene ew byt aw Ghat, a i‘ 10071 . _ nount of calcium carbonate being 68°20. The portion “Mile in hydrochloric acid was not further examined. - 1 Dana’s System of Mineralogy, 1892, p. 51. U—Aug. 7, 1595, PRE Pie ee eS ey eee, OES one A. LIVERSIDGE. The specimen was from a layer about three inches thick; the cones are fairly regular in size and shape, and run right through the deposit in vertical columns, like piles of small closely packed conical paper sugar bags; the average diameter being about half- an inch, and the length perhaps a little more, the angle of the cone being between fifty and sixty degrees, and incipient crystal- lisation is visible in parts. The upper surface of the deposit presents pits with thickened edges over some of the columns of cones, Mr. A. J. Sach, F.c.s., published an account of this deposit (with an analysis) in the Report of the Australasian Association for the Advancement of Science, Hobart Session, 1892, p. 328. MOLYBDENITE. This was described in Note No. 6, read before this Society, December 2, 1891, as occurring in large crystals 3 x 3} x 5} long from the Eleanora Mine, Kingsgate, near Glen Innes, N.S.W. Composition. ve MNO oi es, oe BT SL meee RO ee Tron ee ee ae eo ae 39 100-81 100-28 Another specimen yielded about 6°%/ of manganese oxide ; but this was probably mechanically enclosed between the plates of molybdenite. Sp. gr. 4:6. Proustite—Silver Sulpharsenide. ee ere Ty ee oe eer ae eee ote Mr. Edgar Hall, r.c.s., sent me, in August last, some specimens d from his United Mine at Rivertree, in which he had found som? minute red crystals. I have examined the crystals, and agree with him in regarding them as proustite. They are quite micro” scopic, and it is difficult to examine them and still more to separa? them from the matrix. Mr. Hall states that they occur in a narrow vein, about hal an-inch thick on the hanging wall, and that they have been SOME NEW SOUTH WALES AND OTHER MINERALS. 323 met with at seventy feet, one hundred and ‘twenty feet, and one hundred and eighty feet levels, in fact all the way down so far. The lode is a contact one, between a dyke of quartz diorite and the massive granite of the country. ‘The fissure is about eight feet wide at the one hundred and twenty feet level, of which about four feet is quartz carrying argentiferous minerals ; the yield of silver is found to be much greater where the prou- stite crystals are present. : The crystals are on a bluish quartz, containing mispickel ; they are of a full red colour, translucent, with vitreous lustre, and about 4; to + millimetre in length. I was able to obtain the reactions for arsenic, sulphur, and-silver, but no attempt was made to make a quantitative analysis as it was only with diffi- culty that a few hundredths of a grain were obtainable. Proustite is reported by Mr. C. Marsh! to occur also at Broken ScuHEELirE—Calcium tungstate, CaWO,. Lady Hopetoun Mine, Glen Innes, N.S.W. Massive, coarsely crystalline, of a pale brownish stone colour. Hardness, 5, Sp. gr. 5-93, another portion 5:3 only. A fairly pure calcium tungstate, containing a little water, 223%, of Silica, 1:52 of iron sesquioxide, and a trace of manganese, ‘ Tiystonz Crysrats—Elsmore Mine, Inverell, N.S.W. In stout pyramids, usually about half-an-inch through, but Some of them are much larger. Very slightly water-worn at the edge, otherwise the crystals have the faces of the pyramid well ‘developed and of a high metallic lustre. Yielded a white powder. Sp. gr. 6-68, Hardness, 6°5. Analysis. Tin oxide, SnO, wee 9 Silica, SiO, ... ds 1 a tent ree sea Geology of the Broken Hill Lode, &c., by J. B. Jaquet, p. 90. Sydney, ig94, 324 A, LIVERSIDGE. Tron sesquioxide, Fe, wy ie aes mis? Manganese oxide, nO ins 25 Tungstic acid, Wo, ‘a net “oe 06 98°58 Another specimen from the same locality, but water worn, was found to be harder = 7, with a sp. gr. of 6°54. The powder of this was brown. . Analysis. Tin oxide, SnO, ..... soe oe sii ee Silica, SiO, i Oxide of manganese, “Mn0.. ‘98 Tron sesquioxide, Fe,O, ... cn a0 oS Tungstic acid, WO,. ve an a 36 98°75 The loss of 1-25 on this, and 1-42 on the previous specimen, may indicate the presence of some of the rarer elements not specially sought for, and that the specimens are worthy of further examination. Topaz—Shoalhaven District. In the form of short columnar prisms, the terminal pyramidal planes not well developed, seated on granite. Of a greyish tint, more or less opaque, but translucent in parts. Most of the crystals were about 4” to 3” in diameter, and about 3” long, closely packed together so as to form a solid layer of topaz next to the supporting rock. The crystals are brittle, some of the faces are slightly rough, as if etched. Hardness, 7°5 only. Sp. gr. 3°56. Before the blowpipe it decrepitates, darkens, but become — nearly colourless again on cooling. Gives off a little water when heated in tube. a Analysis. Silica ee a ea ee is Alumina... 6% yes Si ... 62°66 Fluori 1401 uorine... oes es a Water at 100° eve evi os vice cee NATURAL DEPOSIT OF ALUMINIUM SUCCINATE IN TIMBER. 325 The above are the mean of the results of two closely agreeing analyses. The oxygen equivalent to the fluorine must be allowed for in the above analysis. In the foregoing paper I was assisted by Mr. A. O. Black, & student in the Chemical Laboratory, who, under my direction, made several of the analyses ; Mr. C. Walker, another student, analysed the ilmenite; Mr. J. A. Schofield, a.r.s.m., F.c.s., Demonstrator, the zinciferous galena; and Mr. J. M. Petrie, Junior Demonstra- tor, the fahlerz. _ ON 4 NATURAL DEPOSIT or ALUMINIUM SUCCINATE IN THE TIMBER or GREVILLEA ROBUSTA, R. Br. : By J. H. Marpey, F.u.s., and Henry G. Smira. (Read before the Royal Society of N. 8. Wales, November 6, 1895.] a THE material upon which this investigation has been made was obtained from a Sydney timber merchant who was engaged in Cutting up the well-known Silky Oak (Grevillea robusta, R. Br.) tnto planks. Finding a deposit in the middle of a log which “looked like whiting,” as he expressed it, and thinking it curious, he sent it to the Museum, but before the log could be examined om whole of the deposit collected, the planks had been sent _ 4Way from the mill, and further examination of them could not ade. N evertheless, about six ounces of the deposit had been _ ‘Secured, the examination of which forms the subject of this paper. - large Proportion of the substance must have been lost ; what fhe amount was that the cavity originally contained we have no hen - knowing. The investigation of this deposit has proved interesting, that we would like to take this opportunity of “ting the attention of those who are likely to become p sy ese Coes ; S2G J. H. MAIDEN AND H. G. SMITH. of like material, to the importance, from a scientific point of view, of submitting for investigation earthy-looking deposits which may be found in timber. Physical Description. The material is quite soft and almost white in colour, except on the exterior of the lumps, where they are slightly stained brown in places, by some organic substance. It has a sourish, rather unpleasant odour, arising most probably from the presence _ of acetic acid. The whole of the cavity appears to have been filled with the material ; the largest lump measures in the thickest part 2 cm. or about three quarters of an inch, and impressions of : the tissue of the wood can be easily seen. The original material is crystalline in part, minute acicular crystals being seen between crossed nicols with a quarter inch objective. The harder and more solid portion appears to contain the crystals in very small quantity. © The very soft portion col- tains them in abundance. The best method to observe them, is to mount a portion on a slide under a cover glass with water, 10 other material answering so well for this purpose. These acicular crystals were found to polarize when revolved between crossed nicols, but were altogether too minute to determine their mode ot 4 crystallization. The material is thus not quite amorphous. Determination of the Base. The organic matter is with difficulty entirely removed from : the original substance by burning, the last traces of carbon requiring the heat of the blowpipe before being entirely removed: : The residue is perfectly white in appearance, and shows 10 signs of fusion with the greatest heat obtainable with the gas-blowpipe: : The residue is, when thus ignited, insoluble in acids, and requires ; fusion with bisulphate of potassium or other suitable substance — before solution can be obtained. This residue contains no OMe — — than alumina ; absolutely no trace of lime could be detecte im several determinations, and only the slightest trace was obtaine when testing for magnesia. Quantitative determination aie a NATURAL DEPOSIT OF ALUMINIUM SUCCINATE IN TIMBER. 327 almost exactly one hundred per cent. of alumina in the ignited residue, as the result of two determinations. The method adopted was to fuse the ignited residue with bisulphate of potassium until solution was effected, and to dissolve in water when cold; the solution was then acidified, the alumina precipitated in the usual manner, and ignited before the blowpipe until of constant weight. The base therefore consists of alumina. Iron is absent. Determination of the Acid. In the systematic search for the acid, experiment showed the absence of oxalic, tartaric, citric, malic and benzoic acids in the solution obtained by boiling the acid solution of the original material with carbonate of soda, filtering, and proceeding in the Usual manner; succinic acid alone being indicated, exclusive of a trace of acetic acid. The crystals obtained, as described below, answered all the tests for succinic acid. When the original substance is treated with a small quantity of nitric acid, it wholly dissolves, (the trace of organic matter other than the acid being destroyed); the solution is of a pale amber colour. On cooling, a mass of crystals separates out. These were filtered off, drained on a porous slab, and when dry, again heated with 4 small quantity of nitric acid, the crystals obtained by cooling, filtering, and drying on a porous slab as before. These opera- tions were repeated three times, and at the conclusion the crystals were dissolved in water, a small quantity of animal charcoal added and filtered. The solution thus obtained was ‘olourless ; this was evaporated in the air after concentration on a the water bath, white crystals being thus obtained. Although *pParently pure, yet, on ignition, a small residue was left, for it *Ppears to be exceedingly difficult to remove the whole of the lumina by solution and recrystallization of the acid. The “Ystals thus obtained were used to identify the acid, and for the {ualitative tests generally, but for material for combustion sub- limation between watch glasses was resorted to, the sublimate boiled With water for some time, concentrated, and allowed to “rystallize at the ordinary temperature. (Of course this — 328 J. H. MAIDEN AND H. G. SMITH. ment was not resorted to until qualitative tests had satisfactorily indicated that the acid was succinic acid only.) By boiling the sublimate with water, the succinic anhydride formed at the tem- perature needed for sublimation is converted into the ordinary acid, as is proved by the melting point, the sublimate before boiling with water melting at irregular temperatures between 125° C, to 150° C., while the normal acid, as obtained in crystals, melts at 177° C. to 178° ©. uncorrected. As the melting point was determined in an open beaker in glycerol, the actual temper- ature for the column of mercury could hardly be accurately taken for correction of melting point, so the figures are given as obtained, but the melting point may be considered as closely approximating 180° C. The crystals are acid to the taste. The adherent mois ture was removed from the crystallized acid by ‘heating on the water bath before taking samples for combustion. The combus- tions were made of the acid obtained as pure as possible, absolutely free from residue on ignition, and melting at 178° C. uncorrected. 2090 gram. gave ‘3097 gram. CO, and -1000 gram. H,O equal to 40°413 per cent. carbon 5°316 s hydrogen 54:271 o oxygen 100-000 equal to 3°368 C. 5-316 3392 O. from which we may deduce the formula C,H,0,, whichis eet succinic acid. Another combustion gave almost identical results. Theory gives for C,H,O, 54°238 0. 100-000 © NATURAL DEPOSIT OF ALUMINIUM SUCCINATE IN TIMBER. 329 Besides these results of melting point and combustion, the acid gave perfectly all the qualitative reactions necessary for succinic acid. When the succinic acid was crystallized in the most . successful manner, good monoclinic crystals were obtained. Solubility and other tests with the original substance. Besides the property of solubility in nitric acid, taking advantage of which was found the best method of isolating the succinic acid, the original substance is almost entirely soluble in hydrochloric acid, a small brownish residue being left, the succinic acid being precipitated on cooling the solution, providing the hydrochloric acid is not too dilute. The original substance is also soluble in sulphuric acid, with the exception of a small brownish residue, the succinic acid separating from this solution also on cooling. It is also soluble in both potassium and sodium hydrate. When boiled with solution of ammonia, a portion of the succinic acid is PE a Ff oe te ee ee dissolved, forming succinate of ammonium, a more basic salt being left. The material acts in this way the same as ferric succinate does when boiled with ammonia. When the original substance is boiled with carbonate of ammonium for a long time, filtered, ammonia added, to precipitate alumina, and evaporated to crystallization, with the occasional addition of ammonia as evaporation proceeds, good crystals of Succinate of ammonium are obtained. When the original substance is heated in a closed tube, succinic acid is not given off, the water being in fact quite neutral at a low temperature. When the temperature is raised, the water is found to be acid, but when dried in the tube, no solid residue is left, Indicating that the trace of acid given off is volatile. Sufficient Material was taken to give a few drops of this acid liquid, which Save the reaction of acetic acid with F e,Cl., but gave no precipi- tate with that reagent in a neutral solution, showing the absence of succinic acid, : When the powder is heated with bisulphate of potassium, the Suecinic acid sublimes, principally as the anhydride. When the 330 J. H. MAIDEN AND H. G. SMITH. powder is directly treated with acids, the temperature rises con- siderably as it goes into solution. When the powdered original substance is boiled for a long time in distilled water, practically nothing dissolves, nor is anything dissolved when it is boiled with alcohol. There appears to be no free acid in the material as determined by its insolubility in H,0 and C,H,O, and because it is not possible to obtain succinic acid when distilled in a tube without previously adding to the powder some bisulphate of potassium, or some suitable substance, so that the whole of the acid is present in combination with the base. Nitrogen was sought for in the original material but was found to be absent. Determination of the presence of Acetic Acid. When the original substance was first received, it had a sour and rather unpleasant odour, which diminished somewhat 0 keeping. In the systematic examination for acids, acetic acid was detected in minute quantities. To determine the presence of this acid, a portion of the original substance (between three and four grams.), was dissolved in sulphuric acid and distilled ; the distillate was distinctly acid to test paper, had a slight odour of acetic acid,and gave the reactions for that acid with ferric chloride. Only a small quantity was present, as the distillate was readily neutralized with a very small quantity of an alkaline solution. When the original material is dissolved in sulphuric acid, alcohol added, and the whole boiled, the odour of acetic ether is distinctly detected, especially on shaking as the liquid cools. When dissolved in soda and the solution acidified with sulphune acid, alcohol added, and boiled, the odour of acetic ether is more readily obtained. The identification of acetic acid in the original substance is of some importance, as perhaps indicative of the mode of formation of the succinic acid by fermentation. Composition of the original substance. When heated in a closed tube much water is given off. A Portion of the powder was heated at 100° C. to 110° C. for on® See yee a NATURAL DEPOSIT OF ALUMINIUM SUCCINATE IN TIMBER. 331 hour; the loss indicated 25-089 per cent. of water. Heated again for one hour from 110° C. to 120° C. no further loss was found to occur, neither when heated for one hour from 145° C. to 150° C. The powder was then ignited before the blowpipe until constant in weight, when it was found that 43:464 per cent. had been burnt away, leaving 31:447 per cent. of alumina ; 100 per cent. of alumina being found, as stated above, in this ignited residue. As no other acid was detected other than succinic acid, with the exception of a trace of-acetic acid, we may consider the compo- sition to be Organic matter as Succinic acid = 43:464 per cent. Alumina 31°447 m Water 25-089 100-000 From these figures we may look upon the material as a basic aluminium succinate, corresponding to a ferric succinate, and having the following formula : Al, (0,H.O); ‘Al, GO. On ignition we get 2 Al,O, and C,,H..0> removed by burn- ing, which, calculated out and allowing the same percentage of water as obtained by experiment as above, we have Organic matter taken as (C,.H,,0.) =44484 per cent. meee StALOs) ke ee SAT ay Water’... e ote 25-089 100-000 (We take the atomic weight of alumina as 373) It would appear that in no previous investigations on natural salts of succinic acid found in vegetation has aluminium succinate _ ' The water present has been ignored in the formula, as we do not know 8 ere form it is present, or whether it is an essential component of the terial. The amount found indicates a quantity which, if combined, vould Tepresent between nine and ten molecules of water. pe J. H. MAIDEN AND H. G. SMITH. been discovered, although succinic acid in combination with lime has been detected as an exudation on the stem of the White Mulberry tree ( Morus alba). In another reference’ to the presence of succinate of lime occurring in this exudation, the statement is made that the occurrence of succinic acid in the juices of a large number of herbs had long been known, but that it had not hiterto been found in liquids from trees. It was thought in this instance that the presence of a brown, humus-like substance, pointed to the fact that the succinic acid in this case was the product of a patho- logical process and not a physiological secretion. The occurrence of succinic acid was considered to be due toa fermentation process, in consequence of which the malic acid occurring in the juices of the mulberry tree (Gmelin, 10,206) was converted into succinic acid, a metamorphosis which according t0 Fitz (Ber., 12,481) takes place somewhat readily in schizomyceti¢ fermentations. The following formula represents the change 3C,H,O, = 20,H,O, + C,H,O, + 2CO, + H.0 (Malic Acid) (Suceinic Acid) (Acetic Acid) As we have found acetic acid in the original substance from Grevillea robusta, we suggest that the succinic acid in this case is also the effect of fermentation of malic acid, as this acid is of very common occurrence in plants, and is by fermentation readily con” verted into succinic acid. We have not yet succeeded in obtall- ing the fresh sap of Grevillea robusta, so that we are unable a present to state whether malic acid is present or not in the grow ing tree, and any more definite statement as to its mode of form tion must be held over for the present. If malic acid be found to occur in the sap of Grevillea robusta, we think there can be but little doubt as to the origin of succinic acid contained in the Present material. Not only is the material of interest from the Presence of succinic acid, but that the base of the salt should be * Gmelin, Handbook of Chemistry, Cavendish Soc., Vol. X., P- 108- 2 Journ. Chem. Soc., XLI., 602 (1882). S iis PaaS | oN aGg ee) Ca ae Sere eee Rene Ne SS eo eae NATURAL DEPOSIT OF ALUMINIUM SUCCINATE IN TIMBER, 333 aluminium makes it doubly interesting, because of the rare occur- rence in plants of this element. The following extract is from a recent work.! “In spite of the wide distribution of clay in soil and in rocks, its chief constituent, aluminium, is confined in its occurrence to very few plants (lichens and club-mosses).” Another statement of the same kind is made by G. Bunge,? as follows, “ Aluminium is one of the elements most frequently met with. . . . It is therefore remarkable that alumina has scarcely anything to do with the nutrition of living beings. It has been shown positively to exist in any notice- able quantity only in a few plants, especially in a few kinds of Lycopodium.” We have also failed to obtain any evidence from other sources, of the presence of aluminium having been detected in material similar to which we now bring under your notice. That a salt of aluminium has been circulating through the vessels of this tree, Grevillea robusta, appears evident, but in what form it was origin- ally deposited in the cavity of the wood it is now impossible to decide. The probability that it was as a malate, is indicated by the perfect solubility of aluminium malate in water, and the total insolubility of aluminium succinate in that liquid. We may also here point out that no inorganic acid could be detected in the portion taken for investigation. In reference to the formation of artificial salts of aluminium succinate little information can be gathered. “According to Gehlin and Bucholz,t succinate of soda precipitates hydrochlorate of alumina (not however according to Bansdorff from very dilute Solutions), Wenzel obtained by direct combinations an insoluble “alt which crystallized in prisms.” Chemical text books as a rule are silent as to the existence of any aluminium salt of euccinic acid, ae __ Treatise on the Physiology of Plants—Dr. Paul Sorauer. (Weiss’ transla- tion 1895) page 36, 2 . , ; Physiological and Pathological Chemistry, p. 27, 1890 (Kegan Paul). See also Text Book of Botany by Julius Sachs, 2nd Edition, p. 695. * Gmelin, x., 108, 334 J. H. MAIDEN AND H. G. SMITH. Attempt to prepare an artificial Aluminium Succinate. When a neutralized solution of succinic acid is added toa solution of aluminium hydrate dissolved in hydrochloric acid, and ‘ neutralized with ammonia as much as possible without causing 4 precipitate, a dense white amorphous precipitate quickly forms. When this is thoroughly washed, dried at 120° — 125° O. until the © weight is constant, then powdered and ignited, it is found that 66-4 per cent. of this dried residue is removed on burning, leaving 33°6 per cent. of alumina. This does not correspond to the theoretical quantity of either the normal or basic salt of aluminium succinate. When this dried powder is heated in a tube, before charring commences a liquid collects in the tube, which soon crystallizes into prisms of succinic acid, showing that succinic acid is given off in this way while the same experiment with the natural succinate of aluminium failed to give off succinic acid when thus heated as described above. The artificial salt also appears more harsh and brittle than the natural one. The three following percentage results obtained by various observers! on succinic acid from various sources may be useful for comparison with our results. D’ Arcet. | Zwerger. Piria. C = 41-22 C = 40°62 C = 40°34 H= 5°33 H= 5:28 H= 5°22 O = 53-45 O = 54:10 O = 54*44 D’ Arcet analysed the acid from Amber, Zwerger that from Wormwood, and Piria the acid obtained by fermenting an impure solution of Asparagin. It is with pleasure that we place the results of our investigation before you, because it enables us to describe a salt of an organ’ acid rarely found except in small quantities, and forming @ com - bination with aluminium that does not appear to have ever bee = found before in any tree, whether indigenous in Australia or not. : Although it is quite possible that this is an accidental and rare Fe ESTEE ES Gro ut ake 1 Gmelin, loc. cit. GOLD AND SILVER IN SEA-WATER. 335 deposit in this particular tree, there appears to be no reason why other trees of this and other species may not be found to contain material identical in formation and composition, and all that appears to be required is careful search now that attention has been drawn to the matter. Ox tae AMOUNT or GOLD anp SILVER 1x SEA-WATER. By A. LiversIDGE, M.A., F.R.S., Professor of Chemistry, University of Sydney, N. 8. Wales. [Read before the Royal Society of N. 8. Wales, October 2, 1895.] In the following paper are given the results of some experiments made with the object of determining the amount of gold in the sea-water off the coast of New South Wales. The only reference that I can find in Sydney libraries relating to the presonce of gold in sea-water, are those of Sonstadt,' which Will be made use of later on in this paper, and a reference by Dr. T. Sterry Hunt? to a paper read before the American Associa- yea for the Advancement of Science in 1866, by Professor Wurtz, m which he expressed an opinion that gold would be found in “water, but I cannot trace Professor Wurtz’s paper. Then in 1894, Mr. E. C. C. Stanford, President of the Society eo Industry, in his address to the membefs,’ stated :— ® Presence of gold has not been satisfactorily proved ; it was “xpected it might accumulate in the copper sheathing of ships, and Messrs, Muntz obliged me with specimens of old sheathing, “opper and muntz metal. Mr. Inglis, who kindly examined 1 Chom EPR Pam ees ee ical News, 1872, pp. 159, 160. pe and Geological Essays, London, 1879. eurn. Soc. Chem, Ind., x111., July 31, 1894, p. 697. 336 A, LIVERSIDGE. these for me, found both gold and silver, but not in larger pro- portion than usual.” The results were, per ton :— Copper Sheathing. Muntz Metal. oz. dwt. grs. oz. dwt. grs. LO Baas 3 eae ame 9 | U °°. ie Silver £439 5 S28 Professor Judd, ¥.R.s., informed me that a paper upon this subject was published in a Norwegian journal by Miinster, about 1891, but I can find no reference to it in our Sydney libraries. Sonstadt, in his paper on the presence of gold in sea-water gives various methods for the detection of the gold, and in a later letter to the Chemical News, March 11th, 1892, refers to his previous communication of 1872, and states that the amount of gold is “far less than one grain per ton.” His first process is as follows :—Two or three decigrammes of pure ferrous sulphate are dissolved in the water, which is acidu- lated by two or three drops of hydrochloric acid. The solution is heated in a chemically clean well glazed porcelain dish, over # small flame, so managed that the flame may touch the under part of the dish without causing ebullition. Under these circumstances a lustrous film of iron oxide forms in the dish, commencing from tho portion directly heated by the flame. The heat is continued, without boiling, until the sea-water is evaporated to about half, or so long as the film increases in extent and in lustre. The liquid is then poured off, the strongly adherent film is rinsed with a little water ; and then about 50 cc. of strong chlorine water 18 allowed to stand i in the dish for an hour or two, after which it is slowly evaporated down (over the film) to a few drops, # drop dilute hydrochloric acid being added towards the end of the evaporation. The liquid, which should be nearly colourless, - then poured into a test-glass containing a few drops of solution’ stannous chloride, when, after a few minutes, the liquid takes # bluish or purplish tint, which may be exactly matched by a drop or two ofa suitably diluted solution of gold added to 4 corre ponding portion of tin-salt in another glass.” GOLD AND SILVER IN SEA-WATER. oor The sea-water first examined was collected from the coast at Coogee, away from any fresh water or other drainage. Eleven trials of this water were made with 200 cc. as recommended by Sonstadt, but no trace of a purple or even pink tint was obtained; but, with 600 cc. a faint amethyst tint was obtained after stand- ing some time. As a rule, after adding the stannous chloride, a white or grey precipitate came down in the course of a few days, and this precipitate in many cases became pink, purple or slate coloured. To check Sonstadt’s method, various experiments were carried out. Gold chloride (from pure metal dissolved in chlorine water) was added to Coogee sea-water in the proportion of one grain of gold to the ton, and 200 cc. of this was treated by Sonstadt’s process on March 19th, 1895, when a light brown precipitate was thrown down by the stannous chloride; on the 27th the precipitate was of a red colour below with a pale pink layer above; on the 3rd April the pink tint was more decided. Hence if allowed to stand for a few days, the test will detect in 200 cc. the presence of added gold in the proportion of one grain to the ton of sea- water, the gold originally present only being recognisable in 600ce. On December 11th, 1894, a litre of the Coogee sea-water was oncentrated and the test applied, no trace of pink or purple | *ppeared, but on February 8th, 1895, a slight brown sediment had formed, which may have been due to gold. Next two litres were treated on December 28th, 1894, and allowed to stand until February 8th, 1895, when a faint pink tint was observable on the surface of the white precipitate. The second chlorine water extract of the film yielded a white precipitate which also had acquired a pink tint on February 8th. On August 14th, 1895, two more samples each of two litres of ee water were tested. On the 15th the precipitates were brownish, the brownish tint seems to be due to the presence of gold. The contents of the two test tubes were mixed together, dried and scorified with’ 250 grains of assay lead free from gold, when a small bead of gold was obtained. V—Oct. 2, 1895, 338 A. LIVERSIDGE. Sonstadt’s second method was also tried, 7.¢., with barium chloride as follows :—‘ From half a litre to a litre of sea-water should be taken for the experiment. As much solution of pure chloride of barium is added to the water as will give a grain of precipitate. A day or two should be allowed for the precipitate to settle. The precipitate is collected, dried, mixed with borax and lead, and the button of lead obtained before the blowpipe on charcoal is cupelled. The bead obtained is yellowish-white, of the same colour as an alloy of sixty parts of gold to forty of silver, — or thereabout. For confirmation of the presence of gold the bead — may be dissolved in a very small test tube, in a few drops of aqua regia, which is then evaporated, at a gentle heat, nearly to dryness. A few drops of pure hydrochloric acid are added, and the solution again evaporated, to destroy the excess of nitric acid. The solu- tion is evaporated very nearly, but not quite, to dryness, a few drops of water are added, and the mixture warmed, and when the chloride of silver is settled, a drop of solution of stannous chloride — is allowed to fall down the side of the tube into the liquid, when | the characteristic gold reaction is obtained.” Sonstadt’s barium chloride method was tried on sea water from off Jervis Bay as well as from the coast at Coogee, but the yield of gold was either much less than by the ferrous sulphate method (see further on) or no gold at all was obtained, even when two % more litres were used. Similar results were obtained from the use of stannous chloride and mercuric chloride together. Mercurie ; chloride alone and afterwards precipitated by hydrogen cup gave fairly good results. It was thought that the prevmt 7 addition of sulphurous acid, oxalic acid and other reducing sub- stances might increase the amount of gold obtained, but this was not found to be the case, on the contrary the yield was reduce : the As the result of a very large number of experiments with , film test upon gold chloride in distilled water and in sea-wale was found that :— it 1, All the gold is not carried down by the film—not eve? oY : repeating the process and obtaining a second film ; 4 little gold : still being obtainable by a third film, i ‘ es, ‘ 5 We ee ae GOLD AND SILVER IN SEA-WATER,. 339 2. Neither is all the gold extracted by one treatment of the film with chlorine water. 3, Some of the gold is left on the dish in evaporating the chlorine water solution. 4, Several days and even weeks were required, in many cases, for the colour reaction to appear. Gold in Sea-water along the Coast of New South Wales. Next a set of experiments was made upon water collected out at sea; twelve samples, two Winchester quarts of each, were kindly collected for me by Captain Hutton, of the N. S. Wales Government steamer “Thetis,” by direction of Mr. C. W. Darley, then Engineer-in-Chief for Harbours and Rivers, to whom my thanks are due for the ready assistance he has given me in this and other similar matters. Prior to being sent out, the bottles were carefully cleaned, numbered and packed in cases (each hold- ing two bottles) so as to ensure purity and prevent error, and each bottle was rinsed with sea-water when about to be filled. Southern Sea- Waters. In examining the southern sea-waters, in the first batch, a litre (teach was treated and. the characteristic reaction for gold obtained from Nos. 1, 2, 4, 5, and 6. In the next batch of two litres each, 1, 2, 3, and 5, showed the presence of gold ; the films were treated a second time with chlorine water, when Nos. 3, 4 and 5, gave the gold reaction. In the third batch, Nos. 1, 2, 3, and 6 reacted for gold, and on a second treatment Nos. 3 and 6 again gave the reaction for gold. The details are as follows :— No. 1, South—Collected 26th November, 1894, one mile east of South Head Lighthouse. Latitude 33° 43’ 8. Test No, 1. -Upon one litre. SnCl, was added on December 11th, 1894, a white sediment was formed; this, on February 8th, 1895, had changed toa slate colour: the slate colour was probably due to the presence of gold. Test No. 2, Upon two litres. December 22nd, 1894, the white Precipitate on February 8th, 1895 showed a pinkish ringat upper a 340 A, LIVERSIDGE. part evidently due to the presence of gold. The film from. the ferrous sulphate was extracted a second time with Cl water, on December 31st; the solution became opalescent on the addition of the HCl and SnCl, and acquired a bluish tinge (probably due to gold) but by February 8th, this blue tint had disappeared and only a white sediment remained. Test No. 3. Upon 1500 cc. June 12th, 1895. On the 21st June the white precipitate showed a pinkish layer at the top } deep, the pink colour was more decided on the 24th. On July 3rd and 4th it began to turn violet, and on July 7th, was of a distinct violet tint, and on the 10th July the upper part of the precipitate had darkened to a purple colour, which was doubtless due to the presence of gold. No. 2, South—Collected 26th November, 1894, three miles off Bulli. Latitude about 34°. ‘Test No. 1. Gave a slight white sediment, on the 8th February this was yellowish with a dark reddish-brown ring. Test No. 2. On two litres. Put up on December 22nd, 1894. On December 31st, the sediment was white ; but had acquired a pinkish tinge on the surface by February 8th, 1895. The iron oxide film was extracted a second time with Cl water on Decem ber 31st, this gave a brownish coloured solution and a white precipitate, which had not changed by February 8th. Test No. $. Upon 1500 ce. June 12th, 1895. On July 6th there was a slight red tint on the sediment, and on July I this had become brown. No. 3, South—Collected 27th November, 1894, five miles from Black Head, Shoalhaven Bight. Latitude about 34. Test No.2. Upon one litre. Clear, bluish’ tinge; seam slightly coloured. Test No.2. On two litres. A slight amethyst tint within thre? minutes after adding the SnCl,. On February 8th, 189, sediment was bluish below with the pink colour above un¢ ol Spares etce : et ae er Re ake Pa La cae ee fee Coes MEDC igin 5 Nr hae Fas tee GOLD AND SILVER IN SEA-WATER. 341 The second Cl water extract of the film, on adding the SnCl, became opalescent with a faint amethyst tinge; on February 8th, 1895, the sediment was white with light reddish-brown ring, Test No. 3.1900 cc. June 21st, 1895. A buff sediment with a pinkish tint at top; on the 24th the pink tint was deeper, a pale violet on July 3rd, and on the 6th July had become a full violet ; on the 10th July this had become purple—the buff below remaining unchanged. No. 4, South—Collected 27th November, 1894, from one mile off Cape St. George Lighthouse, Jervis Bay. Latitude about 35° 8. Test No. 1. Upon one litre. December 11th, 1894. After standing five hours the solution was clear with a bluish tinge ; sediment slightly coloured. On 8th February, 1895, the white sediment was marked by a reddish ring. Test No. 2. Two litres, on 22nd December, 1894. No colour on the 29th nor on the 8th February, 1895. Nor from the second Cl water extract ; afterwards yielded a bluish tinge with pinkish colour to sediment. Test No. 3. 1900 cc. 21st June, 1895. A bluish tinge on top of white sediment observed 5th J uly, 1895. No. 5, South—Collected 27th November, 1894, from two miles off Brush Island. Latitude about 35° 5’ S. Test No. 1. Upon one litre, 11th December, 1894. Clear bluish tinge ; on 8th February, 1895, the white sediment showed a bright pink ring. Test No. 2. Gave no indication of gold, neither did the second Ol water extract. Test No. 8. 1300 ce., 21st June, 1895. On addition of the stannous chloride this gave a bluish tinge; on July 10th the white sediment was almost black at the base. No. 6, South—Collected 28th November, 1894. From twenty- Seven miles off Broulee near Moruya. Lat. about 36° 5’ 8. 342 A. LIVEBSIDGE. Test No. 1. Upon one litre, 11th December, 1894. No colour nntil 8th February, 1895, when the light brown sediment showed a reddish ring. Test No. 2. Upon two litres. Amethyst tinge. Second extract with Cl water gave a bluish tinge and the sediment had a slight pink colouration. Test No. 3. 1225 cc., 21st June 1895. On the 24th June, the white sediment showed a pink tinge at top +3;" deep ; on July 10th 1895, the sediment was pale brown with an onyx-like layer near the top, with faint purple tinge. On April 3rd, 1895, the precipitate in each test tube of the first batch of southern waters had changed to a dirty, almost black, colour, 7.e,, after an interval of nearly four months from the ‘initiation of the experiment, viz., from 18th December 1894 to 3rd April 1895. It was noticed, in some instances, that after long standing the pink or violet tint gradually faded, especially on the side exposed to the brighter light of the window, in some cases the colour disappeared totally. Northern Sea-Waters. No. 1. Collected February 19th, 1895, about one and a half miles off Sandy Point, Richmond River, Lat. about 28° S. No. 2. Collected at North Solitary, Lat. about 29° S., February 19th, a strong southerly current. No. 3. From about four miles off Smoky Cape, Lat. about 30°, on February 20th. No. 4. From two miles off Tacking Point, Lat. about 31° 30; February 20th. No. 5. From two miles off Cape Hawke, Lat. about 32° 2, February 20th. Wo. 6. About five miles off Port Stephens, Lat. about 3% February 20th, il ie i aoe ee ihe ei aie i enclave Lynn tia a Soa Sapa naling sto : 4 { | | . ; : : ; : : : j | a GOLD AND SILVER IN SEA-WATER. 343 All six samples of northern sea-waters also gave the reaction for gold; the details are omitted for brevity. As in the case of the southern samples, some gave the reaction readily, others required from one to several weeks. I should not however, like to say that this is a sufficient indication of some being richer than others, for the test appears to be wanting in precision. QUANTITATIVE TESTS. Unfortunately all the samples had been used up in making qualitative tests for gold, but, in default of more water, the chlorine-water solutions and precipitates yielded by the stannous chloride from each batch of tests were mixed together and evapor- ated to dryness and then scorified and cupelled so as to determine the amount of gold. The assays were not done separately on each test, as it was thought that the gold beads, if any, would be too small to weigh. Southern Sea-waters.—The first batch of tests, Nos. 1 to 6, 2.¢.s the extracts from six litres, gave ‘003 grain of gold, 2.¢., 508 grain of gold per ton, or ‘38 grain per cubic yard, or ‘032 mgm. per litre. Second batch.—The precipitate from twelve litres used for the second set of tests gave -009 grain, i.e., “76 grain of gold per ton, or ‘57 grain per cubic yard, or ‘048 mgm. per litre. The film was treated twice with chlorine water, and the two extracts added together. Third batch.—9-025 litres gave ‘0069 grain of gold, 2.¢., 1:09 grain per ton, or -58 grain per cubic yard, or ‘049 mgm. per litre. Northern Sea- Waters. 8100 litres gave 0060 grain of gold equal to ‘75 grain per ton, or “56 grain per cubic yard, or 048 mgm. per litre. In calculating the amount of gold per ton or cubic et the Specific gravity was in each case corrected to 1-026, i.¢., the mean results obtained by the “Challenger ” Expedition, corrected to 155° ©. for Sea-water off the coast of New South Wales. : 344 : A. LIVERSIDGE. Before proceeding with further determinations of gold in sea- water, experiments were made to ascertain what loss of gold was sustained in the case of solutions containing known quantities of gold. . EXPERIMENTS witH DistILLED Water AND ADDED GOLD. The following experiments were made to ascertain whether small quantities of gold in dilute solution could be recovered by treatment with ferrous sulphate and other reagents. After adding the ferrous sulphate the solution was exposed in large new shallow photographer's developing dishes for some days, so that the ferrous sulphate might be slowly oxidised and precipitated ; in some cases glass cylinders were used and air blown through the solution. To ' complete the precipitation ammonia was added, the precipitate collected, washed, dried, scorified, and cupelled. From the following results it will be seen that there was but little loss in some cases, but a good deal in others, partly due to imperfect precipitation by the ferrous sulphate, and partly to the loss during cupellation. In most cases the treatment with ferrous sulphate, oxidation and precipitation was 2 upon the filtrate from the first precipitate. 1000 ce. distilled water and 1 cc. of 01% AuCl, solution = “00154 grains gold. ; (1) Treated with -5 gram. FeSO, and NH, yielded 0015 gt. (2) Filtrate treated with -25 gram. FeSO,& NH, ,, ‘0000 » Gold = 0015 , 1000 ce. distilled water (containing 30 grammes NaCl) and | &. of 01% AuCl, solution = -0015 grain of gold. (1) Treated with -5 gram. FeSO, and NH, yielded ‘0011 gt (2) Filtrate treated with -25 gram. FeSO,&NH, ,, ‘0000 » Gold = ‘0011 » 4.¢., a loss of -0004 grain gold or 266% The presence of the N aCl Seems to increase the loss of gold. POSTE SCD eR re ag et ee Ee Ue ae Re in MN ee eg BE Cor eae yo Regs MT oe PT ere Re Se : a GOLD AND SILVER IN. SEA-WATER. 345 1000 ce. distilled water and 100 ce. of -01°%/ AuCl, solution = 1543 grain gold. (1) Treated with 1 gramme FeSO, and NH, yielded -1253 gr. (2) Filtrate treated with -5 gram. FeSO, & NH, ,, ‘0010 ,, 1963 i.e., @ loss of ‘0280 grain gold or 18-14%. 1000 ce. distilled water and 100 ce. of 01% AuCl, solution = 1543 grs. gold. (1) Treated with 1 gramme FeSO, and NH, yielded ‘1327 gr. (2) Filtrate treated with -5 gram. FeSO,&NH, ,, ‘0010,, ‘13ST. 6 1.. & loss of -0206 grain gold or 13-35%. EXPERIMENTS with Sea-WaTER AND ADDED GOLD. 1000 cc. Coogee sea-water and 100 cc. of ‘01% AuCl, solution ='1543 grains of added gold. (1) Treated with -5 gramme FeSO, and NH, yielded -1430 gr. (2) Filtrate treated with -25 gram. FeSO, & NH, ,, 0020 ,, 1450 ,, 4.¢, @ loss of 0093 grain gold or 6-027%. 1000 ce. Coogee sea-water and 100 ce. of ‘01% AuCl, solution ='1543 grains gold. (1) Treated with -5 gramme FeSO, and NH, yielded -1415 gr. (2) Filtrate treated with -25 gram. FeSO, &NH, ,, °0020 ,, : 1435 4, *é5 a loss of 0108 grain gold or 7%. 500 ce, Coogee sea-water and 10 cc. of 01% AuCl, solution = ‘0154 grains gold. (1) Treated with 1 gramme FeSO, and NH, yielded 0095 gr. (2) Filtrate treated with -5 gram, FeSO,&NH, ,, 0000 », . 0095 3 “€y & loss of *0059 grain gold or 38°317%. 346 A. LIVERSIDGE. 500 ce. Coogee sea-water and 10 ce. of -017 AuCl, solution= 0154 grains gold. (1) Treated with barium chloride yielded -0013 gr, (2) Filtrate treated with 1 gram. FeSO, & NH, ,, 0069 ,, 0082 ,, i.e. a loss of 0072 grain gold or 46°75%. 2000 cc. Coogee sea-water and 50 ce. of -01% AuCl, solution = 0771 grains gold (1) Treated with 1 gramme lead acetate in acetic acid and precipitated by sheet zinc, yielded ‘0708 gr. (2) Filtrate treated with 1 gram. FeSO, & NH, ,, “0000 0708 ,, i.¢.. a loss of (0063 grain gold or 8'17%. 2000 ce. Jervis Bay sea-water and 25 cc. of 01% AuCl, solution _ ='0385 grains gold. (lt) Treated with 1 gramme lead acetate and precipitated by sheet zinc, yielded -0235 gr (2) Filtrate treated with 1 gram. FeSO, & NH, ,, 0010» 0251 » 2.¢., a loss of ‘0134 grain gold or 34°8%. It must be borne in mind that to the loss of gold sustained in ld also : tained : the above experiments should be added the amount of go present in the sea-water. The smallest loss seems to be sustal™ when the gold is precipitated by ferrous sulphate and ammonia, but even that process is far from satisfactory. Additional determinations of gold in sea-water from Coogee. 2000 ce, treated with -5 gram. FeSO, and NH, yielded 00198 =0°76 grains per ton. (1) 9000 ce. treated with 2°5 gram. of FeSO,, air blown through NH, added, yielded 0028 gr.- 0-31 gr- PP an (2) Filtrate treated with 1 gram. FeSO, and NH, added yielded -0035 gr. = 0°39 ge 2 Total -0063 gr. =07 gh = Sy A en Ee alah ilies an Mf ale Lil 2a aaa os ae GOLD AND SILVHBR IN SEA-WATER. 347 (1) 2000 ce. treated with i gram. lead acetate and precipitated by sheet zinc, yielded 0003 gr. = 0°152 er. (2) Filtrate treated with 1 gram. FeSO, and NH, yielded “0002 gr. = 0°101 gr. ” ” Total -0005 gr. =0°253 gr. +P It was found when large quantities of Coogee sea-water, ¢.9., forty-five litres were treated with from 1:5 to 5 grammes of ferrous sulphate, followed by exposure for oxidation, scorification, and cupellation, that the amount of gold obtained was very much less in proportion than that yielded by treating one or two litres. Several trials were made, a larger quantity of ferrous sulphate would doubtless have given results similar to those obtained from two litres ; but I have not had time to repeat the experiments with large quantities of ferrous sulphate—as dealing with large quantities is slow and laborious with ordinary laboratory appliances, The inside of the thirty-six gallon cask which had contained the Coogee sea-water was scraped; but very imperfectly, about two ounces of scrapings obtained, they were incinerated, scorified and cupelled when a bead was obtained containing— 0070 grain of silver = 5 dwt. 5°43 gr. per ton we, po ey By Only a part of the barrel was scraped, and that not deeply, but the above results are quite sufficient to show that the gold and river in sea-water are precipitated by the wood &c., hence water Which has been kept in wooden vessels does not yield the full amount of these metals, and the very small amount of silver found (10 Sea-water by Malaguti may have been due to his keeping the *a-Water in a wooden cistern, All my experiments were made upon sea-water collected and Coo n glass vessels, with the exception of the later ones on Water, which had been kept in the barrel. 348 A. LIVERSIDGE. Gold in Sea-water collected off Jervis Bay. (1) 2000 ce. treated with 1 gramme of FeSO, yielded ‘0001 gr. = 0-05 gr. per ton (2) Filtrate treated with ‘5 gramme FeSO, and NH, yielded 0002 gr.=07101 , Total -0003 0151 ‘4 (1) 2000 cc. treated with 1 gramme lead acetate and precipitated by sheet zinc, yielded -0020gr. = 1-016 gr. perton (2) Filtrate treated with 1 gramme FeSO, and NH, yielded 0000gr.=0°000 5, Total -0020 1-016 1000 ce. treated with chlorine, and then with 5 cc carbon disul- phide, to dissolve out any iodine or bromine which might have been set free; decanted 1 gramme lead acetate added and precipitated by zinc, yielded -0005 gr.=0°508 gr. per ton. 1000 cc. treated with two grammes mercuric chloride for four days and then precipitated by H,S, yielded -508 gr. gold per ton. Experiments with other processes are now being carried out; but as they are not complete the results are deferred for a later paper, To test the ordinary Sydney water supply, collected over # sandstone area, 124 ths. weight of the laboratory tap water was tested for silver and gold by adding 100 cc. sulphurous acid, five grammes ferrous sulphate and allowing to oxidise for several = the iron hydroxide was then precipitated by ammonia and cupelled—but neither gold nor silver was found. The amount of gold obtained from sea-waters in the forge : experiments must necessarily be less than the total amount of gold present in the water, since it was found that know? quant ties of gold chloride solution added to distilled and sea-wate™ and then estimated by precipitation, scorification and cu! PARTS Ero TRE AE EM Sree Soy Cede ORES cea BOy] 2 ary gin aoe TR Pe or, aoe, kT hele eee OE SIREENY OO) aT epee OL nt tae neeeocee TEINS Se Een | hs es ee Pt GOLD AND SILVER IN SEA-WATER. 349 tion nearly always showed a loss, and sometimes a very consider- able one. All the above evidence is in favour of gold being present in sea- water off the New South Wales coast in the proportion of about ‘D to 1 grain per ton, or in round numbers from 130 to 260 tons of gold per cubic mile. This of course means an enormous amount for the whole of the ocean, the cubic contents of which used to be put down at 400,000,000 cubic miles, and if the gold be uniformly present at the rate of 1 grain per ton the total amount would be over 100,000,000,000 tons of gold; a later estimate is 308,710,679 cubic miles, this even would mean over 75,000,000,000 tons of gold. But at the present day it would ‘probably not pay to extract the gold by itself, although it might asa bye product in the manufacture of salt, bromine, &c. The fnormous amount of gold in the sea is, however, probably very small in comparison with the amount scattered through sedi- mentary and crystallised rocks, i.e., apart from gold in veins and other deposits, SILveR IN Sea-WATER. All the sea waters gave some silver, usually from one to two grains per ton, but I consider the scorification and cupellation Process lacking in the necessary precision for the exact determin- ation of silver in such minute quantities as it exists in sea-water, I have therefore omitted all the determinations of silver from this paper, but I may publish them later on with the results of other experiments now in hand. Malaguti estimated the amount of silver in sea-water at 001 sramme per 100 kilos of sea-water, or at only ‘15 grains per ton; - Thave quoted him more fully in the next paper in this volume the removal of Gold and Silver from Sea-water by Muntz Metal Sheathing.” 350 A. LIVERSIDGE. Tut REMOVAL or SILVER anp GOLD rrom SEA-WATER spy MUNTZ METAL SHEATHING. By A. LIversIpDGE, M.A., F.R.S., Professor of Chemistry, University of Sydney, N. 8. Wales. [Read before the Royal Society of N. S. Wales, October 2, 1895.] Amoncst the writers upon the occurrence of silver in sea-water, we have Malaguti, Durocher, and Sarzeaud in 1850, Fred. Field in 1856, and Forchhammer in 1865, and as it is difficult for many, especially in this part of the world, to obtain or see the originals, I quote the following extracts from their papers. None of them make any mention of the presence of gold in sea-water of of its removal. The following extract is from a paper by Messrs. Malaguti, Durocher et Sarzeaud, entitled—-Recherches sur la présence du plomb, du cuivre et de Vargent dans Veau dela mer et sur Peaistence de ce dernier métal dans les plantes et les étres organiques.” “ Estimation of silver in sea-water.—A considerable quantity of sea-water was taken from off the coast of St. Malo, 4 i leagues from land, and preserved during the course of the expert ments in a wooden cistern, from which it was taken out as occasion required, in glass vessels. The presence of silver in this water was first demonstrated by the sulphuretted hydrogen process above described ; but in order to obtain a more exact estimation of the quantity, fifty litres of the water were evaporated to dryness, and the crude salt thence obtained, weighing 1,300 grammes, ¥%® divided into thirteen equal portions, and each portion fused with thirty grammes of pure litharge and 1:13 grms. of lamp-b oe This mixture, which was made very intimate by long trituratio® in a porcelain mortar, was gradually heated to dull redness 10 4 1 Journ. Chem. Soc. m1., 1851, pp. 69-70, extracted from Ann. Ch Phys. (3) xxvirt., 129, REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 351 crucible, and maintained at that temperature for fifteen or twenty minutes; the heat was then gradually raised till the mixture fused, and afterwards increased to whiteness; as soon as that temperature was attained, the crucible was withdrawn from the fire. Thirteen operations of this kind yielded 124 grams. of lead, and the silver contained in this was found by cupellation (deduct- ing that which was yielded by the lead alone, in a test experiment) to amount to 0:0005 grm. Now, as this demi-milligramme of silver was extracted from fifty litres of sea-water, it follows that one hundred litres—or for simplicity, say one hundred kilo- grammes of sea-water—contain one milligramme; hence the pro- portion of salt in sea-water is, approximately, one part in 100,000,000, so that a cubic myriametre of sea-water contains 1,000 kilogrammes, or a cubic mile (English) contains about 23ibs.! avoirdupois. This estimation must be regarded as a minimum ; for all the preceding operations are attended with slight loss.” - In the same paper, they refer to the presence of silver in certain fuci, amounting to yov'svo; in various trees such as oak, birch, beech and apple, also in the blood of an ox and the vegetables upon which it had been fed. They also found it in rock salt and in coal, but as the coal contained pyrites, they do not attach the Same importance to its presence in this case. “On the existence of silver in sea-water, by Frederick Field, F.C.8.” He examined the sheathings of certain traders as follows :— “Ana Guimaraens,” a Chilian vessel, trading up and down the South Pacific for seven years. Yellow metal from the bottom of Vessel ; 5,000 grains were dissolved in pure nitric acid and the ‘olution diluted ; a few drops of hydrochloric acid were added and the precipitate allowed to stand for three days. A large ee ee “ada sea-water represents over 40 tons of silver per cubic mile, not “ara » 48 given in the above translation. Malaguti is not respons! r, as it does not occur in the original, where however, there kilos op Crent CIFOR: since “0005 g. for 50 litres is said to be equal to 1000 . of silver per cubic myriametre instead of to 10,000,000 kilos. Proe. Royal Society London, Vol. vitt., 1856-7, p- 292. 352 A. LIVERSIDGE. quantity of white insoluble matter had collected by that time at the bottom of the beaker. This was filtered off, dried, and fused with 100 grs. pure litharge, and suitable proportions of bitartrate of potash and carbonate of soda, the ashes of the filter also being added. The resulting button of lead was subsequently cupelled and yielded 2-01 grs. silver, or 1 lb. 1 oz. 2 dwts. 15 grs. troy per ton. A piece of new yellow metal with which the vessel was being repaired, yielded only 0 oz. 18 dwts. to the ton. Nina,” a brig just arrived in the Pacific from England. The experiments were performed as before with results:—1,700 ars. of the new metal kept in the cabin for possible repairs gave ‘051 grs. = 003% = 19 dwts. 14 grs. per ton.; 1,700 grs. from the hull, where it had been three years, gave ‘400 grs. = 023% = 7 om. 13 dwt. | gr. per ton. The amount of silver in the new metal for the “Nina” and “Ana Guimaraens” are unusually low, being both under one ounce per ton. “ Bergman,” a piece from the hull gave 5 ozs. 16 dwts. 18 grs. per ton ; a piece from the cabin gave 4 ozs. 6 dwts. 12 grs. per tol. “ Parga,” 200 grs from a piece from the hull gave ‘072 grail, and a piece of fresh metal -050. “Grasmere,” only coppered a few months ; 610 grains from hull gave ‘075 and from the cabin -072 grain. Mr. Field remarks :—“ It will be observed that the amount of silver in the above specimens of fresh metal is very high, and itis probable that most of these are merely the re-rolling of masses metal melted down from old sheathing, and have derived the greater part of their silver from the sea on former occasions. It is well known that the copper used in the manufacture of y ellow metal is very pure, containing two or three dwts. of silver per frequently not so much, and silver is very seldom associated the other constituent, zinc. In order to arrive at more certalD results, however, I have granulated some very pure copper, reser” ing some in a glass stoppered bottle, and suspended the remainder 4 Me ee eps byte ee Tae REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 353 (about ten ounces) in a wooden box perforated on all sides, a few feet under the surface of the Pacific Ocean. When occasion offers the box is towed by a line at the stern of a vessel which is trading up and down the coast of Chili. It is almost too soon to expect any decisive results at present, but in a few months I hope to be enabled to send both the original copper, and that which has been ' exposed to the action of the sea.” Ido not know whether Mr. Field ever published the results, but I have not come across any reference to them. “On the composition of sea-water in different parts of the ocean, by Professor Georg Forchhammer.!—‘“ Silver—Malaguti first showed that silver occurs in the organisms of the sea; I have subsequently proved it to exist in a coral, a Pocillopora, and several chemists have since tried to prove that silver is precipi- tated by the galvanic current between the copper coating of a vessel and sea-water. If the last determination is confirmed, the existence of silver in sea-water is proved by direct experiment. From the Pocillopora alcicornis I have separated it in the follow- ing manner :—I dissolved the coral in muriatic acid, precipitated the solution by hydrosulphate of ammonia, and dissolved the pre- tipitate, which consisted of sulphurets, of phosphate of lime, and fluoride of calcium, in very weak cold muriatic acid, which left the sulphurets of silver, lead, and copper probably mixed with those of cobalt and nickel. ‘These sulphurets were separated from the solution, evaporated to dryness with a little nitric acid, to Which were added a few drops of muriatie acid, and dissolved in Water, which leaves sulphate of lead and chloride of silver undis- ‘olved. When the filter which contained the latter substances is burnt, the silver is reduced to metal; a solution of pure soda will . dissolve the sulphate of lead and leave the silver, which, when. dissolved in nitric acid, can be tested with muriatic acid. I obtained from Pocillopora alcicornis about scot ove, oF from & ‘lid cubic foot of the coral about half a grain of silver.” ‘ 1 Phil. Transactions, 1865, pp. 211, 212. W—Oct. 2, 1595, 354 A. LIVERSIDGE. Old Muntz Metal Sheathings. Mr. Cecil W. Darley, late Engineer-in-Chief for Harbours and Rivers, was kind enough to obtain for me some pieces of old muntz metal sheathing from the piles of wharfs undergoing repair. ‘These were examined for gold and silver with the results given below. The method used for assaying was as follows :—In each case ’ 2,000 grains, except where otherwise stated, of the sheathing in ‘strips were dissolved in 1500 cc. of pure nitric acid (1 to 3 aq,), free from chlorine. After being cut into strips, the sheathings — were boiled in water, beaten, and scrubbed with a brass scratch brush so as to get rid of the dirt and scale as far as possible ; this probably also had the effect of removing part of the portion richest in gold and silver, as the assays of the separated scale show that it contains more of the precious metals than the body of the ‘Sheathing. In most cases, the residue was grey and contained much lead. The clear nitric acid solution was decanted and filtered off and some sodium chloride solution added to ensure the precipitation of all the silver ; in the few cases where there was _ an additional precipitate of silver chloride, this was added to the gold and other insoluble matter on the filter. The solutions varied from green to blue. The filter and residue were dried, — wrapped in special assay lead free from gold, scorified, cupelled and checked in the usual way. In certain cases, the sheathing — was dissolved in sulphuric acid, (but, as the solution took place more rapidly in nitric acid, the latter was preferred) when @ yellow ‘substance was generally found on the clock glasses used for cove ing the beakers ; this was found to consist of sulphur containing a little copper, the latter carried up mechanically by spirting» the sulphur was doubtless derived from the sulphuric acid by part of the acid being reduced by the nascent hydrogen given off from the zine of the alloy or more probably by the reaction between the hydrogen sulphide and sulphur dioxide evolved. Sheathing from an old trader, purchased in Sydney about 1874. ‘The solution was made in sulphuric acid as already mentioned. REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 355 Silver. Gold. 4 ozs. 15 dwts. 9-2 grs. per ton. 1 dwt. 2-4 grs. per ton. This sheathing was referred to in a paper on the “ Origin of Gold Nuggets,”! and was remarkable for containing a good deal — of iodine, but none of the other sheathings, since examined, have yielded any iodine. (a) From pile in Mr. Thomas Nobbs’ wharf at Ballina, N.S. Wales, between high and low water mark. Exposed four years ‘to sea water. Corroded but not so deeply as (d). Silver. Gold. 2000 grains gave 6 ozs. 9 dwt. 8 grs. per ton. 11-8 grs. per ton. Metallic copper 647. (6) From longitudinal brace in Ballina Government wharf, N.S. Wales, between high and low water mark, Exposed six years to sea water. Silver. Gold. -2000 grains gave 2 ozs. 2 dwt. 22 grs. per ton. 4°7 grs. per ton. Metallic copper 64°/, (c) From piles in Government wharf, Ballina, N. 5. Wales, between high and low water mark. Exposed six years to sea water. Not much corroded and fairly thick metal. Silver. Gold. 4 7 2000 grains gave 3 ozs. 19 dwt. 5 ors. 19-6 grs. per ton. 2158 grains gave 4 ozs. 5 dwt. 14 grs. Ldwt 7 grs. » 2394 grains gave 4 ozs. 12 dwt. Ogrs. 1ldwt. 22 gr Metallic copper 60°3%/, Th the last, the solution was made with sulphuric acid. (2) From the pile of Mr. Fenwick’s wharf, Ballina, N. S. Wales, wholly submerged for thirteen years in sea-water. So brittle as to break readily between the fingers, with a copper coloured granular fracture, hence in parts most of the zinc has 4, 1 Journ. Roy. Soc. N. 8. Wales, 1893, p. 331. 356 A, LIVERSIDGE. apparently been dissolved out. The sheet is much corroded, and very thin on the edge, stained green and brown. Heated in a tube it emits a.“ sea-shore” odour, and gives off water which has an acid reaction ; it also yields a fusible subli- mate of tarry matter mixed with sulphur. Dissolves entirely in nitric acid, one to three water. The metal when boiled with water, yields a solution containing chlorine and a trace of sulphuric acid from sulphates. After boiling with pure dilute sulphuric acid, the metal acquires a copper-red colour and shows a granular or crystalline structure ; a black residue is left, and the solution, on cooling, deposits crystals of lead chloride. Silver. Gold. 2000 grains gave 3 ozs. 14 dwt. 21 grs. 9 grs. per ton. Metallic copper 62°27. The scale, first treated with nitric acid. 227 grains gave 1 oz. 10 dwt.4-4grs. 15 dwt. 19-5 grs. (e) From Irvington, N. 8. Wales. Exposed to fresh water; very little corroded. Silver. Gold. 2000 grains gave 5 ozs. 6 dwt. 8 grs. 19-6 grs. per ton. Metallic copper 62:37. The scale, extracted with nitric acid and the residue scorified and cupelled— 70 grains gave 1 oz. 7dwt.23-10grs. 9 dwt. 8-22 grs. per to” (f) From Coraki, N. 8. Wales. Exposed to brackish water, Silver. Gold. 2000 grains gave 5 ozs. 6 dwt. 12 grs. 13 grs. per 00m Metallic copper 63-5 ye (g) From Newcastle and Hunter River Steamship Company ’ upper wharf at Morpeth, N. S. Wales. Supposed to have been on piles about four years, exposed to brackish water. Very li corroded. Silver. Gold. 2000 grains gave 5 ozs. 15 dwt. 20 grs. 11 gre. pet OE Metallic copper 62-57. REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 357 (h) From Neweastle and Hunter River Steamship Company’s upper wharf at Morpeth, N. S. Wales. Supposed to have been on piles four years in brackish water. Clean, 7.¢., not coated with green or red scale as usual, and but slightly corroded. Salver. Gold. 2000 grains gave 5 ozs, 7 dwt. 10-2 grs. per ton, Metallic copper 62°47/. (1) From front of pile, No. 1 jetty, (between Nos. 4 and 5 cranes) Bullock Island wharf, N. S. Wales. Submerged about twenty years in sea-water. Green, somewhat corroded, but still fairly thick and solid. Silver. Gold. 2000 grains gave 4 ozs. 1 dwt. 16 grs. 16-5 grs. per ton. Metallic copper 61-6%. (j) From Circular Quay, Sydney, N. S. Wales. Submerged about forty years. The old Tank Stream, now a sewer, has its outfall at Circular Quay, but I do not know how near to the samples of sheathing examined. Much corroded, the sheets being eaten into large holes, Silver. Gold. 4000 grs. gave 7 ov, 19 dwt. 18 grs. 6-5 gr. per ton. The following were treated with sulphuric acid :— Silver. Gold. 2000 grs. gave 3 oz. 17 dwt. 8-4 grs. 11-90 gr. per ton. 0, 4 oz. 15 dwt. 8-5 grs. 8°62 gr.» Metallic copper 61-6°/. Metallic zinc in the much corroded Parts = 34-687, in the thicker parts 35-49%. The Scale, extracted first with 500 ce. of nitric acid (1 - 3 aq.)— viii Gold. oz. dwt. a grains gave 4 ‘16 ll per ton. 0. a 18-5 per ton. me 6°12 191 4 0, a oe 8” 7 10165 ,, 0 S48. 150 ” RT ca es oO 7 186 ” br b 2. 8 189! LE 0:8 1b2 B ; 7 10168 ,, 0:10 108) > Average 7 618 v8: 19 358 A, LIVERSIDGE. ‘The loose easily removed scale of a second lot of sheathing from Circular Quay was assayed, but was first roasted and then extracted with pure sulphuric acid before scorification and cupellation. As will be seen from the results, this scale was richer in silver, the gold was very irregular, and was found to contain platinum derived . from the H,SO,, hence the amounts are omitted. The H,S0, had probably taken it up from the platinum stills used in concen- trating it. Silver. oz. dwt. grs. 100 grains gave 25 12 5:12 per ton. 100 2 19-84 ” 99 2 17 19°8 200 : BS 8 56, 200 s Mm Vise <; 100 a 16 410-562, 100 ; 18 11 10-08 __,, (k) Mr. Hickson forwarded to me a supply of sheathing from the square piles of the original Queen’s Wharf, Newcastle, where it had been exposed for probably thirty-five years. The outer scale, which could be removed by a spatula, was dissolved as usual in pure nitric acid and the residue scorified and cupelled. Two assays of 150 grains each gave 2 oz. 8 dwt. 18 grs. per ton of silver, but no gold 1 oz. 3 dwt. 11 grs. Then 200 grains of the hard and adherent scale a this, with scrapings of the metal itself gave— 6 oz. 10 dwt. 16 grs. per ton of silver. 6 ” 1 ” 12:4 ” el Next the metal sheathing itself, dissolved in sulphuric acid, a after removal of the above two scrapings, gave— 6 oz. 8 dwt. 15-3 grs. of silver per ton. 134 ? a The amounts of gold are omitted since the ee were found . contain platinum, (/) Mr. Hickson also forwarded some of the old sheathing fro” a the bottom of the lighter « Topsy ” which was built in 1881, had been employed at Newcastle. ee ier REMOVAL OF SILVER AND GOLD BY MUNTZ METAL, 359 Two assays were made of the scale from this, and first treated _ with nitric acid as usual ; unfortunately there were only sufficient for seventy five grains for each assay. The results obtained were : Silver. : Gold. 20z. 3 dwt. 13-2 grs. 0 oz. 1 dwt. 17°8 grs. per ton. mee yy -.63.,, 0%, 0-8 ee ‘ The metal dissolved in sulphuric acid yielded— 5 oz. 4 dwt. 9:5 grs. silver per ton. me 14 Is 7 The gold is omitted on account of its containing platinum ; but an assay on 1000 grains dissolved in nitric acid gave 5 oz. 5 dwt. 12 grs. of silver and 15-68 grains of gold per ton. Experiments with New Muntz Metal. Mr. Darley was also kind enough to have plates of muntz metal Placed for me on the piles of certain wharves, according to the following list, so that they might be examined from time to time, to ascertain whether they really do become richer in gold and ‘ilver; each plate was divided as shown by the accompanying | diagram, the central stri 6” x 14” was sent to me for assay, and Ps the two other pieces 21” x 14”, were placed on a Southern and Northern wharf respectively, numbered and marked so that they can be readily identified when wanted for examination. Poe : : & = 1 foot 9 inches, 6 inches 1 foot 9 inches. N - SE Spaeue apap et cco a 4 feet by 14 inches. Os assays of the new muntz metal, before exposure to the sea- § » Were made for me in the University Laboratory by - peak, A.R.s.m., lecturer in Metallurgy and Demonstrator 1n Ch . mistry, now of J ohannesberg. 360 A. LIVERSIDGE. They were dissolved in nitric acid (one to three parts water) free from hydrochloric acid; a few drops of hydrochloric acid were afterwards added to precipitate the silver, allowed to stand, then filtered, and the residue scorified with 500 grains of granulated lead and cupelled. No. 1. Richmond River.—Placed on back of fifth pile in middle row from eastern end of twenty ton crane wharf, south training wall, Ballina, Richmond River. Fixed 1st November, 1893; in salt-water. The assay of the new metal gave— Silver Gold. 1000 grains gave 5 oz. 1 dwt. 6 grs. 11-8 grs. per ton. 1000 39 4 9 19 ”? 11 ” 4 re The trial sheet No. 1 after exposure at Ballina, as above, from November 11th, 1893 to September 30th, 1895. or about twenty- months gave the following results— Scale—Consisted mainly of organic matter, 211 grains gave neither gold or silver. Metal—Dissolved in sulphuric acid gave— Stlver—4 oz. 17 dwt. 19 grs. per ton. Gold contained platinum. No. la. Moruya.—Placed on the pillar pile of the crane at the town wharf, say five miles from the heads. Fixed J 1th November, 1893; in salt water. No. la. Moruya. The plate was taken off in October, 1895, after being exposed to the sea-water for twenty-three months, and on assaying, it yielded the following results. Four assays were made, 1000 grains being taken ; two of these were first treated with sulphuric acid and the other two with nitric acid, and the residues scorified and cupelled separately. By sulphuric acid, mean of two assays— Silver. Gold. 5 oz. 0 dwt. 11-5 grs. 1 dwt. 1°8 grs. per By nitric acid, mean of two assaysS— 4 oz. 8 dwt. 5:5 grs. Le te ” REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 361 It is noticeable that the treatment with nitric acid gives a lower amount than that with sulphuric acid. The scale from this plate (110 grains) gave no gold, and under two ounces of silver per ton, but as the scale was largely organic matter, and copper oxychloride, much importance need not be attached to the per- centage of silver, The inner scale from this (100 grains) treated with sulphuric acid gave— Silver—9 oz. 4 dwt. 5-76 grs. per ton. (‘old contained platinum. No. 2. Clarence River.—Placed on No. 4 pile, Yamba wharf. Fixed 3rd November, 1893, in salt-water. No. 2a. Shoalhaven River.—Placed on back of second pile, eastern end of public wharf, Nowra. Fixed 31st October, 1893, in brackish water. The new metal gave— Silver. Gold. 1000 grains gave 11 oz. 6 dwt. 17 grs. © 16 grs. per ton. (Dup.) iy 8 eee 16 ” (Trip.) hc So ee 16 ” No. 3. Macleay River.—Placed on front tier of piles at back side of pile from front of Belmore River wharf, and on second pile on up stream of wharf. Fixed 20th November, 1893, in brackish water. No. 3a. Newcastle.—Placed on No. 5 pile, from west end of Newcastle and Hunter River Steamship Company’s upper wharf, Morpeth, at low water spring tides. Fixed 24th November, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 10 oz. 10 dwt. 6 grs. 10 grs. per ton. (Dup.) i. Se oS (Trip.) 16 11 3 8 ,» : No. 4. Richmond River.—Placed on sixth pile from easte end of middle row of twenty ton crane wharf, south training wall Ballina. Fixed 1st November, 1893, in salt water. No. 4a. Shoalhaven River.—Placed on back of second pile, *astern end of public wharf, Terrara. Fixed 31st October, 1893, 362 A. LIVERSIDGE. in salt water. The new metal gave— Silver. Gold. 1000 grains gave 6 oz. 3 dwt. 19 grs. 1 dwt. 7°3 grs. per ton, No. 5. Clarence River.—Placed on No. 3 pile, second row, Tluka wharf. Fixed 3rd November, 1893, in salt water. No. 5a. Newcastle.—Placed on third front pile from end of wharf at Pilot Station, Newcastle. Fixed 30th November, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 12 oz. 18 dwt. 17 grs. 1 dwt. 4:1 grs. per ton. No. 6. Macleay River.—Placed on fourth pile in second tier, front of Jerseyville wharf, and on front of pile, Fixed 25th ' November, 1893, in brackish water. No. 6a. Shoalhaven River.—Placed’ on back of corner pile of Government wharf, Appletree. Fixed 30th October, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 10 oz. 5 dwt. 3 grs. i dwt. 7°3 grs. per ton. No. 7. Richmond River.—Placed on second pile northern end of middle row, low level wharf, Coraki. Fixed 4th November, 1893, in brackish water. No. 7a. Newcastle.—Placed on N o. 45 pile (front) near No. 11 Hydraulic Crane, Bullock Island. Fixed 30th November, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 6 oz. 15 dwt. 10 grs. 1 dwt, 2°6 grs. per ton, Plate No. 7 was taken off on September 25th, 1895, after having been exposed about twenty-three months, and examined with the following results— Silver, Gold. By H.S80, 5 oz. 19 dwt. 3-8 grs, Contained platinum. BYHRNO.G, 6, 35 . 1 dwt. 15-2 gr. per ton. The seale (30 grains) from the plate exposed at Coraki for twenty-three months gave 4 oz. 13 dwt. 15-5 grains silver per ton-; REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 363 2 dwt. 4:2 grs. gold per ton., but the amount available, thirty grains only, was so small that the results are of but little value. No. 8. Newcastle.—Placed on No. 11 pile from west end of Newcastle and Hunter River Steamship Company’s wharf, Morpeth, at low water spring tides. Fixed 24th November, 1893, in salt water. No. 8a. Moruya.—Placed on an iron bark pile (sleeper) western _ end of Pilot’s Main boat-shed at the heads. Fixed 11th November 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 6 oz. 7 dwt. 14 grs. 1 dwt. 2°6 grs. per ton. No. 9. Clarence River.—Placed on No. 3 pile, Bushgrove wharf. Fixed 3rd November, 1893, in salt water. No. 9a. Moruya.—Placed on centre pile of third pier of Moruya bridge, counting from Mullenderree side. Fixed 11th November, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 11 oz. 10 dwt. 2 grs. | 1 dwt. 41 grs. per ton. No. 10. Moruya.—Placed on the pile of Pilot’s tide gauge at the heads. Fixed 11th November, 1893, in salt water. No. 10a. Shoalhaven River.—Placed on the back of third pile from south end of wharf (front row of piles). Fixed 28th October, 1893, in salt water. The new metal gave— Silver. Gold. 1000 grains gave 5 oz. 18 dwt. 21 grs. 15°6 grs. per ton. No. 11. Clarence River.—Placed on second row Lower South- gate wharf, No. 4 pile. Fixed 3rd November, 1893, in salt water. No. lla. Macleay River.—Placed on second tier of piles from face of Stuart’s Point wharf, on second pile on up stream side, also nailed on up stream side of pile. Fixed 18th November, 1893, in brackish water. The new metal gave— Silver. 1000 grains gave 11 oz. 19 dwt. 18 grs. 1 dwt. 773 grs. per ton. 364 A. LIVERSIDGE. No. 12. Richmond River.—Placed on back of fourth pile, middle row from southern end of High Level wharf, Coraki, Fixed 4th November, 1893, in brackish water. No. 12a. Macleay River.—Placed on middle pile of outside tier and on back of pile from front of Central Kempsey wharf. Fixed 21st November, 1893, in brackish water. The new metal gave— Silver. Gold. 1000 grains gave 11 oz. 14 dwt. 5 grs. 23-5 grs. per ton. Only three of the experimental plates have been removed and assayed, viz., No. 1 Ballina, No. la Moruya, and No. 7 Coraki, after an exposure of twenty-three months ; the others will be left on fora longer period. In all three cases there was a loss in silver and an increase in the amount of gold. It is unfortunate that the presence of the platinum in the otherwise pure sulphuric acid was not detected earlier, as T have not the time now to repeat the determinations of gold which had to be rejected on that account ; but even without them there are perhaps sufficient assays to settle the question. , The average amounts of gold and silver obtained are :— Silver. Gold. ‘ oz. dwt. grs. oz. dwt. grs. 12 specimens new muntz metal 9 4 7:6 0 0 23 per ton ~ » old 9 413 19 0 0 1627, Average decrease ... £1 es 00 68 4 It is not quite satisfactory to have to compare the assays of old Specimens of metal with those of new ones, but the old specimens of muntz metal are not likely to have originally contained less gold and silver than the new, in fact they probably contained — very much more, so that the difference is all the more striking The assays of the metals from the “ Topsy,” the second lot from the Circular Quay and from Newcastle are omitted from the above : because some of them were made with the sulphuric acid after- wards found to contain platinum. Tee A Ree ar ips sss agi re . bl gee VB Pent S MAS Ree SEA Seen Sey A a ele ac a en a i See ee eae REMOVAL OF SILVER AND GOLD BY MUNTZ METAL. 365 Next the scale from the ten old sheathings gave an average of Silver. Gold 5 oz. 17 dwt. 8 gr. per ton. 8 dwt. 1°8 gr. per ton. or an average increase in round numbers of over 7 dwt. of gold, and an average decrease of 4 oz. 6 dwts. 23 grs. of silver as com- pared with the new muntz metal. The amount of gold yielded by the old metal and the scale is probably understated, since the chlorides could not be entirely removed from the old metal and they were very abundant in the scale, hence on dissolving in nitric acid some of the gold passed into solution as chloride and was lost. The results do not altogether agree with the previously pub- lished views nor with my own before I commenced the investiga- tion. The silver has not accumulated, but on the contrary decreased, the scale however, contains a larger amount of gold. The increase of gold in the scale may be due to the deposition of gold from the sea-water on to the surface of the metal, or it may _ be due to the comparative non-solubility of gold in sea-water; the muntz metal having been corroded and dissolved away, together with much of the silver leaving the gold behind ; it is probably due to both causes, 7.e., partly to deposition and partly to accumulation, for the superficial parts of the experimental plates Nos. 1; la and 7, obtained by scraping them, show an. increase in the amount of gold and a decrease in the amount of silver, the increase in the gold cannot in these cases, well be due to mere accumulation, since the plates do not appear to have lost sufficient weight to materially increase the proportion of the residual gold. Under the microscope some of the old sheathings show minute specks of what looks like filmy gold, they may be particles of bright muntz metal, which have been deposited on the crust of oxychloride, oxide and other compounds forming the scale, for Tass is deposited electrolytically ; on treatment with nitric acid they disappeared in the effervescence set up by solution or other- 366 A, LIVERSIDGE. wise—these filmy specks are quite distinct from the points of bright muntz metal which are seen on the old sheathing, and penetrating, as it were, the scale or crust, and I am inclined to regard them as gold. As I have pointed out elsewhere, under certain conditions gold is thrown down from very dilute solution by the action of reducing agents, in the form of bright particles or crystals—the amount of gold in such a particle might be extremely small, for 300,000,000 grain of gold leaf is visible under the microscope, a piece of cor- responding size set free from gold lace would of course be far less in weight. I hope to investigate this matter further, and in the course of another two years it may be desirable to complete this series of experiments by examining the twenty-one plates which have been left on the piles for a longer exposure. SOME FOLK-SONGS ann MYTHS rrom SAMOA. By Joun FRAsER, LL.D. [Read before the Royal Society of N. 8. Wales, August 7, 1895.) ‘O LE TALA I LE SEGA. “The story about the Senga bird.” (Taree Versions, Nos. xXXv., XXXVI., XXXVII.) ROAR Sine Intropuction.—The three myths, which I now present to you, about the Senga parroquet, again show us how intimately Fiji and Samoa wer? connected in the minds of the early myth-makers. The incidents of the story are laid in the time of Ta‘e-o-Tangaloa, the first king of the Samoa? group, and the immediate successor of the gods who had previously ruled there. And yet in this myth, as in several others, there is a coming going between Fiji and Samoa—a black race and a brown race—#? : there is a familiarity of intercourse which draws me to the opinion ~ +5 p pl £4) , es ad ae history- In another Psst . UlleiL pie as or ALS S): ces aaa ae e Se ty RL RSS eer ets Leia “Pee ie aaeah Os tae lee See ace ee MON Ne ie Sek Ie es A Se ah eA ERS 88g eS Na pe FOLK-SONGS AND MYTHS FROM SAMOA. 367 myth Tangaloa, the great creator-god of the Polynesians, is said to have had two sons, the one black in colour and the other reddish. So it may be that the brown inhabitants of the islands of the eastern Pacific are only the descendants of a fair race grafted on to a black race, the original ‘occupants of these isles. The Senga of the story is a parroquet, having a remarkably bright crimson plumage. It is still common in Fiji and Samoa; its feathers are used for personal and artistic decoration, but those from Fiji are the most valued. This particular Senga, however, is the first progenitor of the present breed, for it was born, not hatched, in the first heavens, and was the child of semi-divine parents. So says this ‘tala.’ Nor let us ‘wonder at that; for such fables have a place in many old mythologies; the classical scholar will remember the parentage of the Cretan Minotaur, -and even Livy’s history has now and again chapters which tell of prodi- gies of a similar kind. And from the Samoan Story of Creation and other Samoan myths which I have read to you on former occasions, it is evident that the Polynesians thought of the heavens as peopled by men and women such as we are, all except the Ninth Heavens where Tangaloa, the Supreme, sits alone in his Fale-ula, his ‘ Palace of Brightness,’ far removed from the turmoil and storms and passions of earth and the lower heavens. These heavens are occupied by the Sa-Tangaloa, the children of the creation of Tangaloa; they behave there like ordinary men, for they feast and chat together round the fire-light at night; they lie down to sleep, and the cocks crow to tell them that the day is-coming; they “narry and are given in marriage; up there they have the food of mortals, but of a more excellent kind—‘taro’ and yams and bread-fruit to eat, and ‘Kava’ to drink ; they hold fonos or councils and talk there to their heart’s ‘content; they have visitors from the earth below; for, if you go round by the north, Says this myth, you can easily get up to the sky; these Visitors Sometimes cheat the Sa-Tangaloa, or rob them, or steal from them ; sometimes they fight them and overcome them and carry off the Spoils of victory, as is shown in the myth (No. 31) about Losi and Malae- La, ‘the war of the gods and the giants.’ The heavens also have natural features, such as those we see on earth; there is a vaitina, a pool in which, it seems, the Sa-Tangaloa may bathe ; there is a puna-langi, ‘ a heavenly Spring,’ which issues from a cave; near this there is a raised heap of Stone, Something like an altar, on which offerings may be laid. In short, "88 $0 on there in Tangaloa’s heavens very much in the same style as on the Polynesian islands below. All these views of heaven show them- Selves in this myth and in the others which I have published. 368 . J. FRASER. Lhave said that the Senga bird has bright crimson feathers ; that colour associates itself with sun-worship ; and besides its birth in the first heavens where the sun is, the tenor of the rest of this story proves that there was something divine in the bird; for, on one occasion, when buried along with its master, it still lived on in the grave, and sprang up again when it chose; it perched on a tree and nothing but the supernatural power (mana) of Le-Folasa, ‘the prophet,’ could induce it to come down. For these reasons I think that the Senga, to the Polynesian mind, was an emblem of the sun and connected with sun-worship. In the Vedic hymns, its colour isasun-colour. The sixth hymn of the Rig-Veda (first book) has many passages to that effect; such as:—The red birds (of the Asvins) came back by day; The red birds shield you (the Asvins) around by day from the heat; The night retires from her sister the dawn, the dark one yields the path to the red; May the winged beautiful horses, may the red birds bring you (the Asvins) back near to us; Like the red child of heaven [ie., the sun]; The red [i.e., the sun], with beautiful wings; The red horses, the beautiful, are seen bringing to us the dawn; Shine, O Agni, red among the dark ones; Powerful red horses, drawing together, draw him, Brihaspati [i.e., fire, the sun], horses clothed in red colour like the sky; Agni, born red in the place of the altar; They yoke the bright red horse [i.e., the sun]; Agni yoked the two red horses; and soon. Even the Fijian and Samoan languages tell the same tale; for the Samoans, when the sun shines dimly say, ‘senga-vale’; in Fiji ‘ singa’ is daylight and ‘ mata-ni-singa’ is ‘ the sun.’ Having thus disposed of the surroundings of this tala, I will now give you the gist of the narrative itself. Ua, the daughter of Tangaloa of the second heavens, was the mother of the Senga. She expected a son, but it was a bird—the Senga,—which at once took to the Heavenly Pool as its place of abode. There Ua and her husband faithfully fed their feathered child night and morning with ‘taro’ and breadfruit and . When full-grown, it loved to wander about. One day it went down to earth below and visited Fiji; there its brilliant plumage charmed Tui-Fith ‘the king of Fiji,’ and, like many a despot, he resolved to possess it. he got two of his strong men to go up to the heavens to get hold of it by craft and bring it to him. Thus it was brought to Fiji and lived there. About this time Ta‘e-o-Tangaloa, the first king of Samoa, who, like some of the Homeric heroes, was both Avorpéfys kai Avoyévns BactAevs, —_— to visit his sister, the wife of Tui-Fiti. He too saw the bird and coveted it; but, as the nobility of bis birth and rank made him disdain to steal, he asked it from Tui and got it. He took it back with him to Manws of Samoa. ae | eee ee ee FOLK-SONGS AND MYTHS FROM SAMOA, 369 A sneaking fellow of Tutuifla, a neighbouring island, next desired to have it; for the fame of the bird’s beauty had spread far and wide. So he came to King Ta‘e pretending disinterested friendship, and brought him a present; for, in Samoa if you give a present, etiquette requires that you get a present in return, especially from a king. But the stingi- ness of the visitor was such that he thought to gain his end by present- ing a superannuated hen, now quite unable to hatch. Tangaloa saw through his craftiness and gave him like for like—some roots of kava so stale as to be unfit for growth, when planted. Finding that the kava roots did not grow, he came back to Tangaloa, and, on the confession of his fault, he got the Senga and took it away to Tutuila. Upélu, another island of the group, now wished to have the wondrous bird, and a man whose name was End-of-the-Sugar-cane-leaf thought to get it, but he stole a canoe—‘ the Rainbow,’ its name—to be the purchase money for it. The beauty of this ‘ Rainbow’ canoe was too much for the possessor of the Senga; so he gave the bird forit. But ill-gutten gains do not carry a blessing with them; for the Upolu man had scarcely gut home rejoicing in his success, when an aitu—‘a spirit-god’—struck him dead because he had stolen the canoe. These old Samoans evidently had some sense of the equity of divine justice. He died and was buried, and they buried the Senga with him as part of his property. But the Senga’s heavenly origin enabled it to live still in the grave, and soon it was up among the trees again and flying about from island to island. One day it visited the island of Savai‘i and king Malietoa saw it; the usual effects followed ; he must have it; so he sent for the whole priestly power of his island to charm the Senga to come down and be his bird ; but they could not. Like the imperious Nebuchadnezzar in dealing with his magicians when they failed to interpret his dream, Malietoa ordered all these priests to be bound, ready to be slain and feasted on at the bidding of the man who could prove himseif able to charm the Senga, me one suggested that such a man could be found only in Manu‘a. So an ambassador was sent to fetch Tangaloa who was the Tui-Manu‘a; he readily came, and by his divine power soon brought the bird down and Save itto Malietoa. ‘The Savai‘ian magicians were spared, but they were Converted into courtly barbers and family-priests. And so ends this tala, XXXV.—Tue ‘Sunca’—A ‘ Tala.’ 1. The ‘Senga’ was the child of O and Ua. © was the son of Tangaloa-pu‘u of the first heavens, and Ua was the daughter of Tangaloa-lua-lua of the second heavens. Ua conceived, and X—Oct. 2, 1895, 370 J. FRASER. brought forth; it was not a man-child but a bird, the ‘Senga’; it sprang into the fresh water of the Heavenly Pool. Then they (two) gave it food ; in the evening they fed it before sleep ; in the morning they went early to feed it. They used to go witha tray, and cut up the ‘taro’ and bread-fruit and fish ; they placed [the food] on the tray when they went to feed the ‘Senga’; they laid it out on a raised heap of stones at the stream which sprang _ from a cave at the end of the pool. 2. The bird was [soon] full-grown ; it sprang down ; it went about [on earth] below. [One day,| it stood in the boat-opening of Fiji; Tui-Fiti saw it, and desired it. He summoned the Fijians to assemble; so Fiji held a council. ‘ Who is a strong man that will get this bird for me’? Olo and Faua offered themselves. Tui-Fiti showed them [what to do]: ‘ You two will go by way of the north side’ [said he]. They went and found the road to the heavens ; they arrived there ; it was fire-light [time]. The family were talking [and said to them], ‘Have you two come”! ‘ Yes.’ “What is your errand’? ‘Is it true that there is a Senga sleep- ing there’? ‘Yes, the child of Ua and O, which is fed night and morning. ‘What isit fed on’? ‘It is fed on bread-fruit and taro and fish, placed on a tray.’ Just then the Senga came gliding down behind the cave [to be fed]. 3. The family took their fish [to it]; but they two went off and hid ; and thus they saw [where] the tray of the family [was put]. The cooks crew [that is, morning was coming on], and they ran off with the tray. They placed it on the heap of stones at the pool, along with the things which they had prepared. The bird came gliding down [for ts morning food], and they at once seized it. Then they ran away with the Senga. They took it to Tui-Fiti. It remained with Tui-Fiti. - It was there at the time that Ta‘e Tangaloa visited his sister Moe-u‘u-le-Apai. He saw the Seng and desired it. And when the Fijians had gone inland [to work} he told Moe-u‘u-le-Apai that he desired it. Then Moe spoke Tui-Fiti, and he gave it to Ta‘e-o-Tangaloa. He came back to Manu‘a and placed it in Fiti-uta. FOLK-SONGS AND MYTHS FROM SAMOA. ye | 4, Langafua came from Sita or Nu‘v-uli in Tutuila. He ~wanted to become the bosom friend of Ta‘e-o-Tangaloa. He came with a crowing-hen. Then Ta‘e-o-Tangaloa [guessed his errand and] brought the ‘kava.’ He divided it and left the knot, but he threw to Langafua the ‘ va-i-ata’ [rooty fibres ?] to pay for the fowl which does not hatch. Langafua went to Sita with the ‘va-i-ata.’ He thrust them [into the ground] and they did not grow ; the [roots] were rotten, for they were stale. Then he came again. Tangaloa asked, ‘ What is become of your kava? is itdead’? ‘Yes. «I gave you the ‘va-i-ata,’ because you brought the hen that does not hatch ; but, come now, take the Senga if you wish it.’ Then he went off with the Senga ; he took it to Sita or Fanga-fu‘e. | 5. Then tidings came to Upolu that Langafua had the Senga at Fanga-fu‘e. Then they greatly coveted it. Then a purchaser came from Ua-fato [in Upolu]; it was the son of Le-Anga that ame, whose name was Ngata-lau-tolo. He came with a canoe ‘that was stolen ; it was called Se-mata-e-‘emo. Then Langafua ‘coveted the canoe and he gave the Senga for it. Immediately thereafter the Upolu man died, [for] the ‘aitu’ was angry because the canoe was stolen. Then he was buried and the Senga was buried with him ; but the Senga still lived. There is a Solo {ie., song] about that ; [as follows | :— The ‘Solo.’ Langafua entered into friendship with him. He desired a family alliance with Ta‘e-o-Tangaloa. He brought the bird that does not hatch ; He brought the crowing-hen ; He brought it and Tangaloa guessed his mind. He gave him the ¢ vaiata,’ but left the knot in Manu‘a. The ‘ Rainbow ’ canoe went out a-fishing. [With it] Ngata-lau-tolo bought [the ‘Senga’] of his desire. - Then the ‘Senga’ went [with him] to Ua-fato, . “Malietoa, receive now your bird.” - The son of Le-Anga was gone [i.¢., he died]. ww N De wh Ded ft peel SS es 2 372 J. FRASER. 13. They buried the Senga with him ; they two slept together ; 14. The bird lay [there] with rottenness— 15. [But soon] it sprang up with a desire to eat. 16. [Thus] the Senga hatched through Malietoa’s [care], 17. And overspread the whole group of islands. 18. ‘Malietoa, receive your bird.” O! The Narrative continued. 6. The Senga lived on in the grave, and fed on the body of the man. But [soon] it went up into a ‘pua’ tree, among the hollow roots of the tree; it sprang into the ‘pua.’ It moved about from place to place; it wandered to Upolu ; it wandered to Savai‘i, Malietoa saw it and greatly desired it. Then he called a council; he collected the whole divine power of Savaiil [to ascertain] whether the Senga would come down ; whatever [person having] divine power should be able to bring down the Senga, he shall have command and kill those who are not able. [They tried, but] the Senga did not come down, and all the priests were about to be put to death. Then Malietoa said that I‘ite should come to this Manu‘a to seek for a priest to bring down the Senga. So I‘ite came to Tui-Manu‘a. Then Tui- Manu‘a said to Tangaloa-le-Folasa that they two should go with Tite. They went, and were invited by Foisia, the god of Ofu, to eallin. ‘Leave thy title and report to Pili-tafao.” 7. They got to Upolu. Malietoa was set on high on a seat ; & great multitude of people was gathered together ; all the priests were prostrate on the ground ; they were bound ; they were about to be killed, because they were not able to bring down the Senga- They were covered over with native cloth. They were lying down for the blow at the direction of Pili-tafao. 8. Then Tangaloa-Tui-Manu‘a stretched forth his hand; it perched upon his hand ; then first he saw its head ; the feathers on its head were short. He said to Malietoa, ‘‘That’s your bird.” Malietoa said, “Take the authority over these priests; if decide that they are to be killed and eaten, it is well.” Tangalos FOLK-SONGS AND MYTHS FROM SAMOA. 373 replied, ‘Don’t; but let them live.” Then Malietoa said, “Leave them to be my barbers and my priests.” Sea SS Swe fed oO — XXXVI.—TueE ‘Seneca ’—A ‘ Solo.’ Folasa came from Anga‘e ; He was invited by Foisia to call in— “Call in and signify your royal will And report it to Pili-tafao, Because I wish to be directed” [what to do]. The two guests [enter and] are pillowed on the threshold. [Now by their power] the Senga that was borrowed is coming The Senga that was so famed is coming. [down ]— . The Senga wandered to the heights of Atua ; . The Senga wandered to Tuamasanga ; . The Senga comes down and perches on the cocoa-nut tree ; . The Senga comes down and perches on the house’s ridge pole; . The Senga comes down and perches on the house’s upper beams; - The Senga comes down and perches on the middle beams ; - The Senga comes down and perches on the lower beams; - The Senga comes down and perches on lowest tier of thatch; - The Senga is about to alight. - “O Malietoa, there is thy Senga [says Le-Folasa]; - Let it suffice to turn aside thy wrath, - And let these sacred priests live, - And let the rain, the showers, and the sun still come on them,” - He unloosed the priests that were bound ; . The priests lived through Tangaloa - From the wrath of Malietoa. - “Change them [said he] into a band of barbers and house-priests - To shave off your offensive [hair] and cut your beard.” - O Savai‘i and Atua and A‘ana and Tuamasanga, - You had Folasa afterwards ; I was first, I was first. QO! XXX VII.—Tue ‘Senca’—A ‘ Solo.’ * Va and O were princes of the Sa-Tui-Atua. oo a we COI ranrr wb J. FRASER. When you go to Atua seek for the land—an inland place, . And you will find it ; [then] speak about O and Ua. As to the Senga, they gave birth to the child ; They grasped it [in their arms]; it was not there ; It had been changed into a Senga and sprang into the water, And became the god of the water, Moe-u‘u-le-Apai [his wife] said, - “O Tui-Fiti, do you bring the Senga here,” . When [her brother] Ta‘e-o-Tangaloa came to visit them. . It stood fast inthe Le-tau-potu of Fiji, . And in the midst of their daily labour in fishing, . And at the fresh-water where they went [to bathe]. . It bathed in the small boat-opening of Fiji. . When it was noon, it flapped its wings ; . The Senga did not come down ; it was cold. . Tangaloa the chief took it [away with him], . And let it go about over Savai‘i. - “O I'ite, if you seek divine power, seek it in Taele-fanga.” . Atua and A‘ana with Tuamasanga came [and their priests}, - [But] the Senga did not come down ; it was not familiar. - [Then] it wandered over Fale-ata [in Upolu]. - “O Tite, if you seek power divine, seek it in Manu‘a ; - When you come back with the divine power of Tui-Manu'’s, - Upolu will laugh at the beaching of your canoe. - To your right is the thing you are to look to ; . Its hair is short ; it has been clipped.” . The red bird is jumping up and down ; . The divine power lies in the front part of the house. . Tui-Manu‘a holds out his hand for the Senga. - It stands on the back of his hand ; he places it on a perch. - “ Malietoa, [says he,| there is your Senga; - Tam going away, and shall not return ; - Allow the Senga to wander about [at liberty] ; - Hide it away when there is continual war. - Look up to To‘elau, [for] FOLK-SONGS AND MYTHS FROM SAMOA. 375: 37. From Fale-‘ula all honours come. 38, [If you donot, | you will put me in danger [of losing my honour}, 39. For my honour will be scattered to and fro, 40, And, dispersed, will disappear ; 41, For, from this achievement comes my title of Pe‘a. 42. [So, I say,] unbind the wise men of the long hair, 43, But let the short-haired ‘ folasa’ have the divine power.” 44, Upolu, this is the [real] tale of thy ancestors, 45, [Although now] you are a troup of idle talkers. 46. So also is Tui-A‘ana— 47, The Tui-fa‘atu-Lalofata— 48. The child of the worm and the rotten ‘fue.’ 49. [I assure you] this Senga grew up in Manu‘a; 50. ‘The Senga came down through my divine power. 61. Bring him along and place him on his perch ; 52. Put him to rest on his sleeping place. 53. [But] in vain do you contend with our Manu‘a ; 54, You will grasp at [the honour] in vain ; 59. [For] the Senga did grow up at Fiti-uta. Notzs to No. XXXV. Par. 1. Senga (pronounced saynga) is a small crimson parroquet, much valued for its bright-coloured feathers which are used for adornment. It Seems to have come originally from Fiji, but is quite common both there and in Samoa. The feathers from Fiji are the most valued. Child; fanau; son, ataliti, ‘a commoner’s son,’ but alo is ‘a chief’s son’; short, pu‘u; second, tua-lua. A man-child; se tagata; Heavenly Pool, puna-lagi, ‘the spring of heaven.’ Tray; laulau, which is a plaited cocoa-nut leaf. Cut up ; tofi-tofi, «to split up,’ ‘to divide’; the food is cut up for the Parrot’s use; the islanders still feed birds thus on bread-fruit. To feed the Senga ; ‘feed,’ taumafa, a chief's word, in honour of the Senga. The Samoans often address their pet birds in chiefs’ language ; oo is used here, I think, from a feeling of reverence for the a. . Spread it, &c.; the whole clause here is—‘ fofola i Je au tanu 0 le vai, °30 Mai mai le ana i le mulivai.’ There seems to be something sacred 376 J. FRASER. . about this ‘au tanu,’ ‘heap of stones’; it may have been an old altar. Stream and pool are both ‘ vai,’ ‘ fresh-water 2. He summoned the Fijians to assemble; ‘ ua fond ia potopoto Fiti.’ Strong man; fita-fita, courageous.” There is something divine about the Senga, and he who attempts to capture it runs a great risk. Olo is a ‘fortress.’ Faua may be from fau ‘ to tie together, to build’ By way of the north; ‘i le itu i matu *; itu is ‘side’; ef. ‘the sides of the north It was fire-light; mumu afi, ‘ the fires were burning. The family were talking ; ‘talatala le aiga’; that is, the Sa-Tangaloa were seated round the fire and were chatting Have you two come? ‘po ua ouluao mai.’ sh common Samoan welcome is, ‘You are come’; 3 of. our welcome. What is your errand ? ‘se & le feau’? Night and morning; ‘ po ma taeao.’ 3. The family took their fish, &c. ; 3 ‘ua ave e le aiga la la i‘a, a ua la tun ua nana; their, they; that refers to the two visitors. The cocks crew; ‘ua iho moa,’ for daylight was now approaching. Desired it; ‘mana “gone inland,’ that is, when they were gone off to the piantations we or Gone ; liu, ‘turned.’ A crowing hen; ‘ ufa-u edie’, ; a crowing hen that does not breed, feunks: as a present in expectation to get something in exchange Left the knot; «tun le pona’; it is the knot that sprouts; divided #} “vaea’; vaiata are the root- branches that do not sprout. For information about the ‘ kava,’ see e Nos — XIV. Were rotten; ‘ua pala’; stale, ‘mati,’ from being too long kept. I gave; avatu. Anga, ‘ action ’; ioe ares end of a sugar-cane leaf.’ Se-m mata-e-‘emo, ‘a flas He died; a punishment for ae THE Sond—1. Entered into Friendship; fa‘aud. 2. Family epee sie 3. The bird that does not hatch; ‘le manu e lé fofoa 8. ‘ Rainbow’; sti 0, the name of Langafua’s canoe 12. Gone ; maliu, ‘ e, dead ;’ son, ‘alo,’ a chief’s word. 14. Lay with fad ceceks “e toaga i le palapala.’ £ - Eat ; taumafa,‘to eat or drink,’ a shies word. This inciden hows the divine power of the bird, Par. 6. Among the hollow roots; ‘i a‘a 00 0 le laau.’ Moved about from place to place; eva-eva; wandered ; ya. nd ine power ; mana; the ‘taula aitu,’ that is, ou magicians 4 priests are Summoned. Kill all that are not able ; the doings of despots ; Put to death alt the Tite means « I or ‘ma fasi ie ua 1é mafai.’ This is quite like ef. the history of Daniel. Priests ; ‘a fafasi mana uma.’ & seer, a prophet’; ite, ‘to know.” T= Set eee ena A spel Ad Baca. ee a De | F | FOLK-SONGS AND MYTHS FROM SAMOA. 377 God; aitu, ‘a spirit, an inferior god’; to call in; afe. Leave thy title or signify thy will; the original here is,—‘ tuu lou ao sei logo ia Pili-tafao.” The meaning is not clear. Pili-tafao or Mo‘otagao was the sister of Ta‘e-o-Tangaloa and wife of Foisia, an aitu or god of Ofu. 7. Sit on high on a seat ; ‘ua ti‘eti‘e i le nofo.’ All the priests were prostrate; ‘taatitia mana uma,’ waiting their doom. Native cloth; u‘a; made from the bark of the paper mulberry. 8. And eaten; ‘e fai taumafa,’ a cannibal feast ; don’t; ‘aui.’ Notrs to No. XXXVI. Line 1, Royal will; observe that a king was in a sense sacred; for, where he sat, nobody else could sit; no one could touch his food. On each side of a king sat a ‘tuafale,’ the head man of a family. Chiefs were termed pa‘ia, ‘not touched by work, sacred.’ Folasa, ‘a prophet.’ Angae is a district in Manu‘a. ‘2. ‘Invited ; velaau-ina; as when persons are passing by and are in- vited to come in and partake of food. 3-5. The text of these two lines is :— v. 3. Afe mai sei tuu lou ao; v. 4. Sei logo ia Pilitafao; v. 5. Aua ni tonu mo au; or T'autua na ni tonu mo au 6. Guests ; ‘tataluma,’ which is the front part of the house, and honoured guests are set there; pillowed, ‘aluga a,’ used as a verb, There must be and may thus be used like the wooden pillow of the natives; lago me ‘to raise on supports,’ 4 laai is ‘ to pass over.’ With this Skod: Sleep, compare the superstitions in many countries about stepping on and over the threshold; compare also I. Sam. v., 4 7. Borrowed ; nono; referring to its first coming from Fiji. 8. Reported ; logo; that is, ‘ much heard of, famous.’ - Wandered ; abe word thus translated here and elsewhere is the cau- Sative ‘ faa-eva, += 16. These lines represent tie gradual descent of the bird under the magic influence of the ‘ folasa Perch; ‘tu,’ stand; ridge-pole, ‘au-au’; beams, ‘tausoaga’; upper, ‘luga’s 3 middle, * loto’; lower, ‘lalo’; lowest tier of thatch, ‘ lagolau.’ 17. Alight ; & tapa; the translation of this word is conjectural. 19, 20, 21, 25. The text of these lines is :— tau ane ai lou toasa; v.20. Ae soifua mana sa; v. 21. Fa‘aua ma fa‘atimu ma fa‘ata; v. 25. Ina ’é liu falesoga ma liu falemana. 26. Offensive ; soesa; the text i no word for hair. °8. I was first ; Masi says this. 378 J. FRASER. Notes ro No. XXXVII. Line 1. Princes; tui; Sa-Tui-Atua is ‘the race of the princes of Atua.’ — 2. Land ; laumea—the land which is the birth-place of the Senga. Water; vai, ‘fresh water’; ‘god,’ atua; ‘ changed,’ liu. 8. Moe, &c.; she hears of the Senga from her brother; she hears of the - beauty of the Senga of Atua in Samoa and covets it; but when brought to Fiji, it ‘stood fast,” it would not come down to them (v. 11). 12. Daily labour, &c.; faiva o tili; tili is the casting of the small net. 13. Fresh water; they bathe in a swamp or lagoon of fresh water. 14. Small boat-opening ; ava-ava 15. Noon; ao-uli; the original of this line is :—‘O ao-ulia sua taili; which may also mean, ‘ At noon (or at full tide) a wind springs up.’ 19. Bathing place; taele faga. 20. Atua, &c.; that is, all the priests of these districts in Upolu came. pa Familiar ; lata; it did not feel at home. - Power divine; mana; power to charm the bird, which the priests of ean had been unable to do. Laugh; ataina; as scoffers and unbelievers when you land there. - To your right, &c.; this line may also be translated, ‘ Consider the Sie ade mark it has,’ [for] 28. Jumping ; this is the effect of the Folasa’s mana. 29. Front part ; talaluma. 35. Continual war; utu tau; the Senga seems to be a bird of peace, probably as an emblem of the Sun, the beneficent orb of — 37. All honours; ao; the line is ‘ Faleula e tutupu ai ao. Fale-ula is the bright palace of Tonpktnn in the highest heavens; and To‘elau is & group to the N.W. of Samoa, but it seems to mean something else here. 39. Scattered; e fa‘a-eva-eva, ‘made to wander about.’ 40. Dispersed; that is, scattered to the winds; disappear; maulu, ‘dive under.’ 41. Pe‘a, ‘a bat,’—a title of SS in Samoa ; the line is, Tupu ai tonu mai Pe‘a. 42, Wise 44. Opolu, &e.; the Niobe a sonalnas as usual, with some lines to magnify the importance of his own islands 48. Rotten fue ; ge for explanation a ae read the Samoan Story of Creation, No. xx 51. Perch; sunuaga. XXX VIII.— Tur Story or Mor-u‘v-Le-APAI AND HER HUSBANP Tur-Fitt, rue Kine or Fis1—A ‘ Yala.’ [S Seemed IntTronr ki j,i SOS io ae ee £11 1 Paka te f the characters who appeared in ec previous pee semi-divine Ta‘e-o-Tangaloa and FOLK-SONGS AND MYTHS FROM SAMOA. 379 his sister, Moi-u‘u-le-Apai; and the time of the story is again the grey dawn of Samoan history, when T'a‘e was the first king. Ta‘e was a bigamist ; he had two wives at once, and they seem to have made the family home so uncomfortable to poor Moi that she fled from it, and, committing herself to the deep, she at last reached Fiji; here her charms as a brunette captivated Tui-Fiti and he married her. To this hour the Fijian princes like to marry brown Polynesian women, and, the Tongan group being nearest to them, they get wives fromit. But in these myths Tonga is of no account ; it is Samoa only that has intimate relations with Fijii—a black race with a brown one. But this foreign lady was not ac- ceptable to the subjects of Tui-Fiti; for, had her presence not brought on that land this sore dearth of food from which they now suffered so much! And so, in heathen lands, it is the stranger among them who is accused of bringing the destructive epidemic, and he must be driven away that it may be stayed. Some philologists say that the Latin word hostis, ‘enemy,’ originally meant only ‘a stranger,’—truly a striking glimpse of the philanthropy of the time when every stranger was reckoned an enemy. So poor Moi was again a wanderer ; for the king of Fiji had to send her away to satisfy the clamours of his people. And yet, when she Was gone, the famine still remained. We see her tramping on inland towards the high mountain ranges of the island, carrying her own little boy on her back, and leading by the hand Tui’s sister’s son, an adopted child. At last they reached a spot where they thought to rest; they sat down and wished for a house, when, lo! at the wish, a band of artificers, ‘tufunga,’ came down and built a house for them, sent for that purpose by the great god Tangaloa, her ancestor, who hears all the wishes of his own people. But he did yet more for her. Dwelling in that forest, how was she to get food? The family of Tangaloa in the heavens consulted together, and Ufi, ‘a yam,’ offered to go down and plant herself around the house, and bear fruit. Next morning, the exiled queen saw the yam, dug up a branch, took it into the house, roasted it and ate thereof, she and her two children; thus they did for many, days—all through the beneficence of the great god. Meanwhile her brother Ta‘e-o-Tangaloa in Manu‘a had dreamed a dream, also sent by the supreme god of the Polynesians—does not Homer also say that dreams come from Zeus? kal yap 7 évap ix Alos éstwv—and by it he knew that his sister in that far off land of Fiji was in distress. He ag at once go to her help. A canoe belonging to a neighbour of his, neo was about to start for Tutuila, with four oarsmen and Afono self the fifth on board as steersman. Knowing what he meant to do, was he not semi-divine ?) he took in his hand a stripped cocoa-nut 380 J. FRASER. stem and a bread-fruit branch, and, reaching the spot just as they were getting off, he hailed the canoe and said, ‘I want to go with you!’ Afono churlishly refused and pulled out of the harbour. Tangaloa hurried by land to two points which they had to pass in succession, and from each of them repeated his request, but thrice in all he had the same refusal ‘The canoe now got out tosea; but Tangaloa, irritated by Afono’s repulses, called to his sea-boys (mermen, [ suppose) and ordered them to bring the vessel by force back to the rock where he stood; thrice this was done, but to no avail; for Afono still refused ; until his men expostulated with him on the danger they ran; then he yielded so far as to let one of them say to Tangaloa, ‘Come here.’ So Tangaloa jumped on board. But it did not suit him to let the canoe go on to Tutuila, for he wanted to get to Fiji; so he enveloped that island in thick darkness and made the light to shine clear upon Fiji in the far distance to the south-west. The crew passed Tutuila as if it were not there and continued heading onwards for many days. Food and water began to fail them. Hungry and thirsty, Afono and his men cried to their miracle-working passenger. He bade them look into the hold; there they found bread-fruit to eat, and young cocoa-nuts from which they got water to drink. The branches which Tangaloa carried in his hand when he leaped on board had been placed in the hold, and they had speedily grown there, and now they supplied food and drink to the weary crew! At last the canoe reached the Fijian shore, but here fresh dangers wer? before them. It was a charmed land, and three obstacles had to be over come by those who would enter there; first, outside on the reef was # snare called ‘ the coral-that-wrecks-canoes,’ probably something like the Symplegades rocks which of old so bothered the Argonauts when they essayed to sail between them; then inside there was a second danger in the shape of shoals of mullet which, by some magic influence, were made to leap on board with the intention of swamping the canoe; the as a last and inmost bulwark stood on a promontory Tui-Fiti himself, with his pointing finger, to lead astray and to destruction those who would. steer by his directions. From all these daugers Tangaloa, by his and foreknowledge, delivered Afono and the crew. At the last point, he "laid his mana or divine power on Tui-Fiti for punishment; for he had o"Y to point his finger upwards and the Fijian king fell prostrate and stu? and the whole land of Fiji was scorched with heat. From this incident it appears that he who possesses the mana is superivr to magic and p we : and thus the wickedness of the wicked only recoils with double force up? 4 their own heads. : : i a : 2 2 by : FOLK-SONGS AND MYTHS FROM SAMOA, 381 As Ta‘e had now no further need of the canoe, he dismissed the Tutui- lans with the assurance that he would enable them to get back to their own land in a few hours; but, if they wished to have prosperity and happiness, they were not to clear out the hold of their vessel till they were ashore; for the scales of the fish, and the skin and refuse of the ‘taro,’ bread-fruit and cocoa-nuts that they had eaten would be of much valuetothem. Perversity and unbelief seem to be congenial to the mind of men everywhere, for, although the crew said ‘ Aye, aye, sir,’ to his in- junctions, the men were scarcely out of his sight than they threw the whole lot overboard. And Tui-Afono thus missed having the plenty and comfort which the fruitful growth of these things would have given him. Meanwhile, Ta‘e was moving about on Fiji in search of his sister; at last he found her; they fell on each other’s necks and wept. Next morn- ing he commenced to plant her land with everything good to eat, and while there was miraculous abundance there, Tui-Fiti and his people on the coast were still pinched with the famine and dying of hunger. In these circumstances, Moi resolved to return to her husband good for the evil she had received at his hands, and, taking a present of food with her, she went down to the coast, got the sick man to eat, and, as he was too weak to travel inland, she had him carried up next day to her home; all his people soon followed and settled inland there, and thus escaped the famine. Then Tangaloa returned to his own Manu‘a, and, in memory of his journey in search of his sister, he gave to a district in it the name of Fiti-uta, ‘inland Fiji,’ and that name remains till this day. The ‘ Tala.’ An account of the praises of the boy of Moi-ulu-le-Apai, the relation by the mother’s side of Ta‘e-o-Tangaloa ; an account of his going to Fiji. 1. Probably Moi-u‘u-le-Apai went away [from home] at the time when her brother, Ta‘e-o-Tangaloa, married Le-lau-lau-a-le- Folasa and Sina, She travelled on and reached Fiji, and married the chief of Fiji, who was called Tui-Fiti. 2. And so Moi, the daughter of Tangaloa-a-Ui, became the wife of Tui-Fiti ; and she brought forth a son and he was called Le- Ata‘ata-a-Fiti, There was a famine in Fiji at that time, and it = very great. Then the people said to Tui-Fiti, ‘ What do you think ¢ should we drive away the lady? for she is not a human being but a god ; because, since she came, we have constant famine; our food is gone.” Then she was sent away by the chief. — 382 J. FRASER. 3. Then the lady caught hold of her boy, and carried him on her back; she went away also with her child whom they two had — adopted ; it was the child of the sister of Tui-Fiti; Fili was the — name of that boy ; these are the three that went. They walked far inland to the backbone of the island, to the place called Tan- potu of Fiji; they dwelt there ; they got a house because they expressed a desire for it; thus they spoke as they walked :— *O a‘u, ‘0 a‘u lava ‘o Moi-ulu-le-A pai; Matou o atu lavaia, o tumai se fale; Matou te nonofo ai, ma si a‘u fanau. “Tam, I am indeed Moi-ulu-le-Apai ; We came and a house appeared ; We dwelt there, I and my child. 4, Then Tangaloa looked down from above. He appointed a great many to hasten down to build a house for the lady. Then the sons of the Sa-Tangaloa went down; they built the house; the lady with her sons went there and the building of the house was finished, and the Sa-Tangaloa went back to the heavens ; then the lady dwelt there and her sons. When morning light was come, # ‘council was held in the heavens of those who built the house, together with all the Sa-Tangaloa, about food for the lady. Then Tangaloa said, ‘ Present an offering of food to her quickly, because . the lady is hungry.’ Then Yam offered herself saying, ‘I here {I this) am Uti-tolo-tie.’ . 5. Then the Sa-Tangaloa said, ‘How will you go’? She said [the yam], ‘I will go and grow at the side of the house, spreading there ; when the lady goes out to look for food, then will her foot be pierced by me ; then shall I be observed ; she will look down and perceive that I am good ; she will then take me to eat.’ The Sa-Tangaloa were agreeable. Then the yam went down to the ‘Side of the house and spread itself along. When it was morning light, the lady said to Fili, ‘Come here and stay with your young brother," while I go and search for something to eat for us three; it is doubtful if I shall get any in this great forest.’ When she ‘came behind the house, the yam was spreading there, and her foot was at once pricked by the yam. The lady looked dow?; ! FOLK-SONGS AND MYTHS FROM SAMOA. 383 the branch of the yam was broken ; it was scattered about ; she took hold of it; broke it with her teeth and tasted it to see whether it was sweet ; she perceived that it was good ; then she dug it up. Then she went into the house, bearing the branch of the yam in her hands. Thus she brought it and roasted it for herself and her children. And they ate of it. Thus she did every day ; that yam became food for the lady and her children for many days. 6. Then it became known to Ta‘e-o-Tangaloa by a dream ; for he dreamt that his sister had been ill-used by her husband, the king of Fiji. Then he prepared to go there; but there was, towards the east, a travelling party from Tutuila ; the travelling party of the king of Afono had come to his friend, ‘O Le-puia-i- Then came Ta‘e-o-Tangaloa at the time when the travel- ling party was about to return to Tutuila ; he seized hold of two things of his, a cocoa-nut stem from which the nuts have been Picked and a bread-fruit branch with leaves and blossoms on it. The travelling party of Tui-Afono went on board, and Ta‘e-o- Tangaloa said, ‘I will make a sixth in your canoe.’ Tui-Afono Was unwilling [that is, refused]. Then his canoe passed through the boat-opening, and the chief (i.e, Ta‘e) went inland. The “anoe passed through behind the breakers, but the chief went by land ; the chief came and stood by Le-Loto ; that isa rock on the Seaside of the Pu‘e-mapusanga. The canoe came there, and the chief said to Tui-Afono, ‘ Let me be a sixth to your crew. He Was unwilling ; Tui-Afono would not answer. The canoe went on; but the chief went by land. He came and stood on a xeef- Tock ; its name was the ‘to‘a’ of Tangaloa ; it is on the sea-side of Ana-lefu in Fale-asao. The canoe went on and reached it. angaloa said to Tui-Afono, ‘ Let me be a sixth in your canoe.’ fanoe went on ; for Tui-Afono was unwilling. It went on, and Was far out at sea. i. The heart of Tangaloa was pained. Then he called to his — Who were there in the sea, Au-salia and Au-fanua-mai, boys there give heed to me (Jit., turn your eyes towards me); 384 J. FRASER. I am tired of this fellow, who has been fooling me; come now, do you two bring him to me; bring him to the place where I stand, Then his men went; they brought the canoe; notwithstanding the sail and the paddling with oars; they brought the canoe to the place where the chief stood. Then he called again, ‘ Tui-Afono, let me be a sixth in your canoe.’ He was unwilling; and the canoe went on; the chief let it goon. They went on and reached the spot where they had been [a little before]; it was brought back again ; it was brought to the place where the chief stood. He called again, ‘O Tui-Afono, let me be a sixth in your crew. Tui-Afono did not speak. Then one of the crew—Gai-uli-m- gai-sina it was—said, to Tui-Afono, ‘Let us say the word that the chief may come’ [on board]. He was unwilling and said, ‘Pull away.’ They reached the spot where they had been before; then the canoe was brought back to the place where Tangaloa stood. Then he cried, ‘Tui-Afono, let me be a sixth in your crew. Tui-Afono was unwilling. Then stood up his steersman and said, ‘Tui-Afono, the chief, do you say the word to that chief ; for, in consequence of your acting thus and your provoking ways; the end of it will be that we shall all be made to suffer for it.’ Tut Afono was unwilling, but answered, ‘One of you, call out.’ So one called, ‘Come here.’ Then the chief came and jumped into the canoe. . 8. Then Tangaloa performed a miracle; he covered the sky and all the lands with darkness; only Fiji remained bright sky; there was light there; and the prow of the canoe was directed toward it; the crew and Tui-Afono were frightened; they thought they were turned towards Tutuila. Then they voyaged on; they continued to voyage on; the food was all consumed and the drink, and the days of the canoe were ended. The crew grumbled ; Tangaloa asked, ‘What is it’? Tui-Afono answered, ‘Tangalos this crew is going to die; there is no food ; the food is all con- sumed.’ Tangaloa answered, ‘Look into the hold of the cau% towards the starboard side.’ Then they looked carefully; the bread-fruit branch had fruited and become a live bread-fruit, and | . FOLK-SONGS AND MYTHS FROM SAMOA. 385 now bore fruit. They brought it out and ate; for there was a cooking place in the canoe. Then the crew murmured for water. Tui-Afono again called out, ‘There is plenty of food; but this crew is dying of thirst and there is no water.’ Then Tangaloa bade them examine the port side of the hold. And when they exaniined, the cocoa-nut stem had fruited ; it bore fruit well, both the young cocoa-nut and the full-grown nut. 9. The canoe continued its course and reached Fiji; it reached the back of the surf in Fiji. Then Tangaloa told them of the might of Tui-Fiti. Tangaloa gave them his final instructions. But he first said to the crew, ‘In this land are the spirit-gods called the ‘ Wrecking Coral,’ and the ‘Leaping Mullet,’ and the ‘Fiti’s Finger ; that is the pointing-hand that makes canoes to err and be broken, and the men die, but they do not altogether die; they only lie stretched out ; this implies the divine power of Tui-Fiti, that a canoe should come safely to land,’ Then Tangaloa madea last command, ‘When we reach the boat-opening and I say, ‘Pull lustily,” see that you obey me at once ; for there, in the boat- Opening, is the mullet that leaps, the ‘anae-oso’; when you see that you have enough of [them for] food, do you bid me cover up the hold, because of the pointing of Tui-Fiti; when you see me paddling on the right side, do you paddle also on the right-hand side ; when you see me paddling on the port side, do you also paddle on the same side ; do you paddle as I do; thus will ye paddle.’ 10. So then the canoe entered the opening in the Fiji [reef]. Tangaloa stood on the half-deck and called, ‘ Paddle the canoe.’ They pulled stoutly ; the coral reef {that is the dreaded Panga- Solo-va‘a| was at once pierced and broken through, and the canoe Went through the middle of the opening. Then the ‘anae-oso’ fishes jumped up and the canoe was nearly swamped. The crew shouted, ‘Tangaloa, cover the hold.’ Then the mullet jumped up [on deck] and wriggled about, and fell back into the sea. ‘They Went on, but there they saw the pointing [finger] of Tui-Fiti. “nen Tangaloa paddled on the port side and all the crew paddled Y—Oct. 2, 1895, 386 J. FRASER. likewise. Then came the pointing of Tangaloa ; and Tui-Fiti fell prostrate and was stunned. Then the Fijians directed their attention to their chief and gave no heed to the boat ; they did not stand and look towards it. 11. Tangaloa at once jumped ashore and placed the canoe on the supports there; the Fijian supports were at once broken; and now [the crew] turned the canoe seaward and went away. Hence is the song about the voyage of Tangaloa, thus :— “The fleet of Afono prepared to go a-fishing. Tangaloa stood up with the food for the journey. The ‘tusi’ of Fiti pointed down ; Tangaloa paddled on the larboard ; [The canoe] swerved with its crew and went too far; The ‘tusi’ of Tangaloa pointed up ; All Fiti was swamped by that.” 12. Then he said, ‘Now, you Tutuilans here, you will reach land in this very hour ; you will not sleep [another night] on the deep; don’t bale out your canoe; don’t remove the refuse from it} you Tutuilans here, drag up the canoe at once and its cargo; bale out the canoe for the first time when you reach the land.’ They answered, ‘ Aye, aye; let it be so.’ He said also to them, ‘There is great happiness in store for you, if ye do these things ; for that [refuse] will produce fruit greatly—bread-fruit and cocoa-nut— and fish will grow also from the scales.’ But they did not obey; for they baled out the canoe and threw out the refuse at the back of the breakers. Thus their happiness was wasted. Hence the proverbial saying, ‘They have despised the good fortune of Tut Afono.’ 13. Then they speedily arrived at Tutuila. They were near the land ; the surf was behind them; they rejoiced that they had come so quickly, But they had baled out the hold and collected the refuse and thrown it into the sea, before they beached the boat. Then they reported to the people of Afono all the tale of the journey, and the great usefulness of the food of Tangaloa, and the final injunctions of Tangaloa ; and how they were grieved because : FOLK-SONGS AND MYTHS FROM SAMOA. 387 they had baled the canoe, and gathered up the refuse [to throw it away |; because if they had brought these things with them, that is, the scales of the fish and the skins of the ‘taro’ and of the bread-fruit, and the stems of the cocoa-nut, they all would have had great plenty. Therefore the people said, ‘Tui-Afono, you have made light of your good-fortune’; hence sprang the proverb, ‘The good-fortune of Tui-Afono was made light of.’ 14. But Tangaloa went on for the place where his sister was ; it was far off, far off inland. He reached [a house| about fire- light time, and went on early in the morning. When he got to the place, they were having a dance to the praises of Moi-u‘u-le- Apai and her son Le-ata-ata-o-Fiti ; thus :— 1. “The fleet of Afono prepared to go a-fishing. 2. Tangaloa stood up with food for the journey. 3. The fleet of Afono prepared to go a-fishing; 4. There was a search for Moi-u‘u-le-Apai ; 5. The whole lands were covered over [with darkness]. 6. The Sa-Tangaloa voyaged ; 7. They voyaged and he stood up at the boat-opening ; 8. [There were] the mullet and the coral-that-wreck-canoes. 9. First the pointing of Tui-Fiti went down [7.¢., south]; 10. Tangaloa paddled to larboard and so did the crew. 11. [Then] the pointing of Tangaloa was upwards [7.¢., north] ; 12. The whole of Fiti was scorched : 13. The Samoan group was covered [i.¢., protected ].” They [brother and sister, | greeted each other and wept; he stayed there, for it was night. 15. When the morning light dawned, Tangaloa said to Moi-u‘u- Je-Apai, ‘Shut down the flaps of your house; let me prepare and Plant your ground.’ Then he planted the land everywhere. Bread-fruit lived there, and cocoa-nut and papaw-apple, and banana, and taro, and yams ; everything grew abundantly. He kept on planting, and very great indeed was the quantity of food. They were free to use everything on the land ; only the bread- 388 J. FRASER. fruit crop was forbidden until the first fruits of it were taken to Tui-Fiti, who was oppressive to his lady. And Tangaloa’s injunctions were obeyed. 16. In course of time, the crop became ripe, and the boy was grown up. But the famine continued in the towns in Fiji; one man was almost eating another; and Tui-Fiti was nearly dead with hunger. Then said Ta‘e-o-Tangaloa, ‘ Gather some bread- fruit at sleeping-time, and early in the morning go and take it to Tui-Fiti.’ Then they went and gathered the bread-fruit ; four of these were a burden for the one boy and the lady. And with it they went down towards the sea to Tui-Fiti ; they made their oven ; there were three of them; they made their oven; the fruit was cooked and they took it down to the chief who was oppres- sive to her; the chief and his family partook of it and were strengthened. 17. Then the lady told Tui-Fiti that she was going back [home] with her child ; and that if there were any who were still strong in his land, that they should come with her and carry the abund- ance of food that was inland—taro, bread-fruit, bananas. The chief replied, ‘What does my lady think about carrying the sick man inland to be taken care of there.’ The lady said, ‘ Please yourself ; only your people will not be able to carry you, the sick man, inland until to-morrow ; when to-morrow comes, you, the: sick man, shall be taken; but to-day, if there are any that are strong, let us go ahead to bring down food to satisfy the hunger of the people.’ Then a great number crowded up and went inland—men, women, and_ boys. They reached the plantations and saw white bananas ; they ate, but did not gather burdens take to the town ; they ate; they were gorged ; they were sick ; then they slept inland and dia not go down to the town. When the morning arrived, the sick man Tui-Fiti was brought up; thet they remained inland; gradually all the houses of the Fijians were brought up ; they took up all the town to the place where Moi-u‘u-le-Apai lived,—to the abundance which grew in the plas- tations of Ta‘e-o-Tangaloa. FOLK-SONGS AND MYTHS FROM SAMOA. 389 18. They all went inland, and Ta‘e-o-Tangaloa was there still. Then Ta‘e-o-Tangaloa said to Tui-Fiti and Moi-u‘u-le-Apai, ‘Come now, set your country in order, but I will go away; I have got a name for my country; it is Liu-Fiti-i-uta “ Changed-into-Fiji- inland”; that was shortened into Fiti-uta. Then he came here with that name for his land, Liu-Fiti-uta ; ; he came and dwelt in it. I suppose that was at the time when Ta‘e-o-Tangaloa was a young man. Notes to No. XXXVII. Par. 1. Moi-ulu-le-Apai ; sometimes the 1 is dropped and the name be- comes Moi-u‘u; the praises of her boy is ‘faa-nana-aga,’ a ‘song of praise.” At that time; ‘ po,’ night. 2. Le-ata-ata-a-Fiti ; ‘the after-glow of Fiji.’ Human being, tagata; god, aitu. 3. Backbone; a ridge of hills. 4. He appointed a great many, &c.; “tofia lea ni e toa-tele e nati-n a € toai se fale.” The word ‘nati-nati’ means ‘to be busy about;’ urgent, to be importunate.’ Present an offering of food ; ‘fe-ofoai mai ia ni ‘ai’; ‘ofo’ means ‘to make an offer of food and services to visitors.’ Uji-tolo-ti‘e ; «the yam which spreads along on the surface of the ground.’ 5. Morning light; malama. Scattered about ; pae-pae, lit., ‘piled up.’ It was sweet ; some are bitter. Every day; many days; aso-uma. 6. Afono is in Tutuila ; his friend; ud, ‘a bosom companion’; Le-puia-i- lama, « Shut-up-torch.’ Cocoa-nut stem from which the nuts have been picked is au-loso-loso ; only fit for firewood when the nuts are gone. Bread-fruit branch with the leaves and blossoms on is tau-‘ulu-‘ulu. : Le Loto; ‘the pool’; Pu‘e-mapu-saga, ‘ the pu‘e (a spreading tree) rest- mg place.’ Reef-rock ; to‘a; Ana-lefu, ‘ cave-bad.’ 7. Au-salia or Au-agae, ‘ cross-current to the east’; Au-fanua-mai, “cross- — cote towards the land.’ eyes; pula, an abusive term for ‘eyes’; pula, ‘to shine,’ like ripe fit Matos, playing tricks. Chief; ali‘i; the gods also are chiefs. Gai-uli-ma-sina, ‘ Gai- black Pagers *; gat, as a verb, means ‘to be in- jured internally’; gaigai, ‘to be exhausted’ as by work in the sun. Let us say; lit., let your ase go aaa Pull away; that is, ‘paddle.’ Sites fa‘a-masei-sei; masei,‘to be uncovered as the body ’; use words giving offence,’ epiads not so intended; masei (adj.) Ungrateful, i Improper conduct 390 J. FRASER. 8. Hold; Lit., ‘ bottom.’ Young cocoa-nut is full of liquid; the full grown nut is full of food. ’ ht; lit., ‘troops’; parting command, ‘ tofiga,’ like the injunctions which a dying father gives to his sons. God; aitu, ‘spirit-god’; Punga-solo-va‘a, ‘ the coral (that makes) canoes slip’; Anae-oso, ‘the mullet that leaps’; Tusi-a-Fiti, ‘the pointing of Fiji’; this pointing is done to direct the steersman and the rowers in passing through the reef, or coming inshore. 12. The refuse or rubbish; this is explained further on, Par. 13. 14. Fire-light time; about 7 p.m:; praises, ‘fa‘a-nana-aga,’ as in the title of this ‘ tala.’ 15. Flaps; these are moveable flaps, next the ground as in our canvas tents, which are raised in the morning for ventilation to the house. Prepare and plant ; chiefs work in their own plantations. Papau apple; Eugenia malaccensis. Forbidden; tabu. Sick man ; lit., ‘ your sickness.’ 17. White bananas ; that is, thoroughly ripe. Be able; ‘sava’ (a Tutuila word) for ‘ lava.’ Set your country in order; that is, appoint magistrates, &c., for orderly government. XXXIX.—Vanua anp Trapa—A ‘ Solo.’ fied ef IntRopuction.—Some persons may perhaps say that there is no evi- dence to show that these myths are not recent creations of the Samoan mind. To that I reply that the general cast of the stories proves them to be brethren of the ancient folk-lore tales of other nations, although modified by the tale-teller to suit his Polynesian environment. A wine- ‘taster at once knows the quality of the wine offered to him and perhaps also the district from which it comes; so likewise can a folk-lorist discer from its very setting that a tale is genuine. Sometimes also there is in- ternal evidence to the same effect ; the language is old-fashi d hard to understand ; there are frequent allusions to old occurrences in the his- tory of the nation, well-known to them, but scarcely intelligible to 85 national proverbs are quoted, and such sayings are usually of very ancient date ; and conceptions of the gods and their doings present themselves, which are quite foreign to the current modern ideas of the race- Occasionally, however, we have a Folk-song like this, which looks jike & charter of nobility taken from the muniment chest of some noble family. Such a solo tells of the rival claims to precedence made by some islands © the group, and the song is of such antiquity and well-known authority FOLK-SONGS AND MYTHS FROM SAMOA. 391 that mere quotation from it is enough. Of this nature is the following song about Valia and Tiapa, founders of the tribes of Savaii. Some of the people of that island deny the statement that Valua and Tiapa came from Manu‘a, but to settle the dispute you have only to say ‘ Ia, fai mai se soifua,’ ‘Come, tell us the story of a life,’ for this story is called a soifua and decides the question. Some of the references in it are so old that the present generation does not understand them. The Solo. 1, O Manu‘a se nu‘u au mamala. Manu‘a is a land bringing calamity [if slighted]. 2. Folau aitu, folau tagata : [From it] spirits go a-voyaging, men go a-voyaging 3. I Saua ma Sopo-Le-Malama— To Saua and Sopo-Le-Malama 4. Ile atu Toga, ma le atu Fiti— To the Tongan group, and to the group of F iji; 5. Folau i le atu To‘elau, They voyage to the Tokelau group 6. Ma Sa-Vavau. And to Sa-Vavau. 7. Fesili Nonoa le ava ; _ Nonoa asks for the boat-opening ; 8. Ai la outou folauga na. That, I think, is the place you have to go to. 9. A outou oi A‘ana; You are about to go to A‘ana; 10. Tou afe a‘e i Aleipata ; You will call in at Aleipata ; 11. I tua le Moso ma Le-Laulala, Behind it are Moso aud Le-Laulala, 12 Ta mata‘utia i Utu-fala-fala. Who are dreaded in Utu-fala-fala. 13. So‘n fesili po ua tonu. Let me ask whether that is the correct [route]. 14. Lo outou tali mua na. That is your first answer. 15. Ai ia Savai'i lafa-lafa— hen on to Savai‘i which is level— 16. Na ‘uuna Valua ma Tiapa. [A land] which Valua and Tiapa took possession of- 392 J. FRASER. i) ~I . Se la‘i egase i luga ;— [From it] a westerly wind rustles on high ; 18. E agi ma ofaga i Manu‘a. It blows and nestles on Manua. 19, Ai lau tali mua ua uga. My first answer is ended. 20. So‘u fai tala ia Manu‘a Let me [now] tell the facts (‘tale’) about Manu‘a 21. I le Faletolu ma le Fiti-uta. To Fale-tolu and Fiti-uta— 22. E te Aopo e, ma Asau, You are a mixed travelling party ; 23. Tiga lou tala vavau Notwithstanding your ancient tale 24, E te u‘u mai ia te a‘u You will lay hold on me (i.e., Manu‘a) 25. E te fai matua i Manu‘a— [For] your parents are in Manu‘a— 26. I Fongo-olo-ula ma Malae-a-Vavau, In Fonga-olo-ula and Malae-a-Vavau, 27. Ma Sopoaga a le to‘elau. And Sopoanga of the trade-winds. O! Such is the ancient Solo, but Tauanu‘u of Manu‘a the ‘fale-tala’ or legend-keeper of Manu‘a gave the following as the popular way of accounting for the name Savai‘. “ Savai‘i and this Manu‘a are one ; for Le-Fatu and Le-ele‘ele peopled this Manu‘a; they two begot I‘i and Sava—I‘i the girl and Sava the boy; who peopled the island which ig called Savai‘i.” He also stated that Fatu and Ele-ele were the first pair who came dow? from heaven; that they alighted at the east end of the village of Tau at @ place called Malae-a-Vavau, a few minutes’ walk from the teacher's house there. They gave birth to a boy and a girl named Tidpa and Valu‘a; these went and peopled the island of Savai‘i by giving birth to girl I'i anda boy Sava; hence the name Savai‘i. Another acco : Says that Fatu and Ele‘ele were the parents of Fai-malie and Fai-tama) Vavau and Tele or Nu‘u and Tele, Mamao and Laveai or Ilu, Valu‘a and | . | | | AUSTRALIAN VEGETABLE EXUDATIONS. 393 Norges to No. XXXIX. Line 1. Causing calamity; auma aaa causing mala’; that is, any one am disrespect to this land will perish. - ypo-le-Malama means ‘ Pf ae: ae is one of the heroes of the ‘ War of the gods and Giants,’ q.v. 15. Level, lafa-lafa ; that is, the island has no chief of its own. 26. Fongo-olo-ula, ‘ face-of-the-red-fort’; Sopoanga, ‘ the passing over.’ CONTRIBUTIONS ro s KNOWLEDGE or AUSTRALIAN VEGETABLE EXUDATIONS. No. l. By J. H. Marve, F.L.s., &.,and H. G. Smira. [Read before the Reyal Society of N. S. Wales, September 4, 1895. ] Unper the above title we submit some notes on gums, resins, &e., which we trust will be of value, either because the exudations are entirely new to science,! or because, if their existence has already been recorded, their composition has not been determined. The notes are of various degrees of fullness; in some cases the sub- stances promise to be of such interest, that we hope at some future time to deal more fully with them. _ Exupations Deatt WitH—Guwms. Bosistoa sapindiformis, F.v.M.; Rutacez. ° Melicope neurococea, Benth.; Rutacee. Getjera Muelleri, Benth.; Rutacee. Pentaceras australis, Hook. f.; Rutacex. Capparis nobilis, F.v.M.; Capparide. Acacia Oswaldi, F.v.M.; Leguminose. Acacia retinoides, Schlecht ; Leguminose. Acacia Bakeri, Maiden ; Leguminose. ee Ag the present paper all the exudations are new to science, except of Eucalyptus Planchonia 394 J. H. MAIDEN AND H. G. SMITH. Acacia Maideni, F.v.M.; Leguminose. Albizzia pruinosa, Benth.; Leguminose. Kinos. Eucalyptus hemastoma, Sm., var. micrantha, Benth. ; Myrtacex, Eucalyptus Planchoniana, F.v.M., Myrtacez. Schizomeria ovata, Don, Saxifragew, Gum-resin. Medicosma Cunninghamii, Hook. f.; Rutaceze. GuMs. Bosistoa sapindiformis, ¥.v.M. (N.O. Rutacez). Collected at Mullumbimby, Brunswick River, N. 8. Wales. This gum, which is transparent and pale coloured, does not wholly dissolve in water, although a large percentage goes into solution after some time ; this is arabin. The insoluble portion dissolves in a dilute alkaline solution, which becomes yellowish in colour ; this is precipitated as arabin, thus the insoluble portion consists of metarabin. There is no difference in the physical characteristics of this gum and those of the other Rutaceous gums described in this paper. Resin is absent. The amount of this gum at our disposal was not large, so that it was not possible to make further inquiries respecting it. Gevjera Muelleri, Benth. (N.O. Rutacee). “ Axe-breaker.” Collected at Lismore, N. S. Wales. This gum is in large tears of a light amber to light brownish colour, transparent, with a very bright fracture. It is brittle, and although somewhat tough, powders fairly well. The fine powder, when placed in cold water, does not readily dissolve, nor does much more go into solution on boiling. The aqueous solution, when separated from the insoluble portion, has fairly adhesive properties, although the viscosity is not very high. The insoluble portion when treated with dilute soda solution becomes yellowish and darkens slightly. On continued gentle heating the whole slowly goes into solution. ‘The soluble portion AUSTRALIAN VEGETABLE EXUDATIONS, ° 395 consists principally of the lime and magnesia salts of arabic acid, as the arabin, when precipitated from its solution by alcohol, heated with dilute sulphuric acid, the acid solution neutralised by carbonate of lime, then precipitated with hot alcohol, yields a filtrate which when evaporated to a syrup, gives arabinose. The portion dissolved by dilute soda solution was metarabin, as when dissolved it changes into arabin. This is precipitated from the alkaline solution by the addition of alcohol. This precipitate — when filtered off, washed with alcohol, dissolved in water, acidified, and again precipitated by alcohol has all the appearance of arabin. When this precipitate is heated with dilute sulphuric acid, treated in the usual way (above described), a crystallized sugar is obtained having the rhombic character of arabinose, and which when dis- solved in water is dextro-rotatory. This gum may therefore be considered as belonging to the arabin group, the portion not soluble in water being metarabin. This gum contained 17:23 per cent. of moisture, while the per- centage of ash was only 1:94, which is low fora gum. ‘The ash consisted of the carbonates of lime and magnesia, and a small quantity of potassium; it also contained both sulphuric and phos- phoric acids. The colour of the ash is white. It contains a small percentage of albuminoids, as the presence of nitrogen was readily detected by the ordinary method. When heated with strong nitric acid a large quantity of mucic acid is formed; as much as 29-98 per cent. was obtained from this specimen. The method followed in estimating the mucic acid in these gums, is to treat about two grams. of the powdered gum with about 8 cc. of nitric acid in a beaker, gently heating until a clear Solution is obtained. The heat is then slightly increased until the greater portion of the acid is driven off; the remainder becomes turbid. After standing some hours, to allow erystalliza- tion to take place, about 5 cc. of nitric acid is added, the mucic acid filtered off, washed with water, dried and weighed. The filtrate (with the washings) is evaporated down, again treated 396 J. H. MAIDEN AND H. G. SMITH, with nitric acid and the process repeated. A small quantity of mucic acid is usually obtained in this second treatment. The portion of the gum soluble in water gives only a small precipitate with ferric chloride, nor does it give any marked reactions with mercuric chloride, stannous chloride, or with a saturated solution of borax. The gum is interesting, primarily because it belongs to the Rutacez, a Natural Order very few of whose genera have, up to the present, been recorded as yielding gums. Commercially it cannot be looked upon as a substitute for gum arabic or gums of that class, as a Jarge proportion is insoluble in cold water. The large percentage of mucic acid formed is very remarkable. Melicope neurococca, Benth. (N.O. Rutacez). Syn: (Bouchardatia neurococca, Baill.) Collected at Lismore, N. S. Wales. This gum is in large tears and globular masses of a light amber colour, very bright and transparent looking. © It is brittle and breaks with a very bright conchoidal fracture. It much resembles the gum from Geijera Muelleri, except that this sample is more bright in appearance. It also behaves in the same way in water, a portion only going into solution, while the remainder is soluble when heated in a dilute soda solution. The precipitates of arabin and the formation of arabinose, are produced exactly in the same way as described under Geijera Muelleri. Our sample contained 14-68 per cent. of moisture and 2°54 per cent. of ash; this ash is white, and consists of the carbonates of lime and Magnesia, with sulphuric and phosphoric acids. Only 4 slight trace of nitrogen was detected, indicating the almost entire absence of albuminoids. The yield of mucic acid in this gum was very large, no less than 42°48 per cent. being obtained. This is remarkably high. Ferrie chloride in the portion soluble in water gave no precipitate, and only darkened the solution slightly. Other reagents gave 9° results, oh ee oe os Lee at al Oe oe ee ie i ahi OR ai ss Sgt Li Ca f . x . ; : . : AUSTRALIAN VEGETABLE EXUDATIONS. 397 Pentaceras australis, Hook.f. (N.O. Rutacez). “Serub Hickory.” Collected at Mullumbimby, Brunswick River, N. S. Wales. The colour, appearance, and physical characteristics of this gum almost exactly resemble the gum of Melicope (Bouchardatia ) neurococca, with the exception that the tears are slightly longer. Tn water a portion only goes into solution, while the remainder is soluble in dilute soda solution on heating. The solutions give the arabin precipitates, with formation of arabinose when treated with dilute sulphuric acid, as described already under Geyera Muelleri. A soda solution when heated becomes quite dark. No nitrogen was detected in two determinations. The gum contains 11-12 per cent. of moisture, and only 1:73 per cent. of ash. The ash is white, and contains the same con- stituents as that of Geijera Muelleri. Ferric chloride gives no precipitate and only darkens the solution slightly. The other usual reagents gave no marked reactions. The aqueous portion possesses little adhesiveness. The yield of mucic acid is very small, thus showing an important difference from the other gums of the Rutacex here described. These three gums belonging to the Rutacew, viz, Geijera Mueller, Melicope (Bouchardatia) neurococca, and Pentaceras australis, resemble each other in a marked manner, by their solubility in water and soda, low ash, brittle nature, and bright conchoidal fracture, the latter differing from the other two by not Containing albuminoids and giving only a very small quantity of mucic acid on treatment with nitric acid. Capparis nobilis, F.v.M. (N. O. Capparidez). ‘Wild Lemon.” Collected at Woodburn, Richmond River, N. S. Wales. This sample is in small particles, or small vermiform tears, Semi-transparent, and of a horny texture, does not dissolve in cold water but swells up to an enormous extent. On boiling, the ‘Particles partly disintegrate but do not dissolve. 398 J. H. MAIDEN AND H. G. SMITH. In dilute soda solution it does not dissolve, but partly forms a mucilagenous thick syrupy liquid, which is precipitated by alcohol as a slimy mass, but no arabin appears to form even on long boil- ing, neither does the solution become yellow with alkali. This precipitate when dissolved by boiling in dilute hydrochloric acid solution, is precipitated apparently as arabin by alcohol. The original swollen mass is also dissolved on heating with dilute hydrochloric acid, forming arabin, and is precipitated apparently as arabin on the addition of alcohol. The amount of material at our disposal was too small to deter- mine whether arabinose could be formed by treatment with dilute sulphuric acid, but the mode of formation, appearance, and behaviour of the gum to reagents, indicate that it consists almost wholly of pararabin, which does not form arabinose when thus treated. From the above it will be observed that this exudation resembles in its properties the gums of the Australian Sterculiacez.? Acacia Oswaldi, F.v.M. (N. O. Leguminosz). “ Miljee.” Collected at Nelyambo, Darling River, N. 8. Wales. This sample has all the appearance of ordinary commercial gum arabic ; some of the pieces are colourless. In appearance, taste, 4 solubility and reactions with reagents, it differs in no respect from gum arabic. It is however very acid in aqueous solution, and is perhaps deficient in adhesiveness and viscosity to the best gum arabic. It is identical with the gums obtained from several other species of Acacia growing in the dry western portion of New South Wales, which have great commercial possibilities, providing they are obtained in sufficient quantities. It gave no precipitate with ferric chloride, nor did it form a jelly with that reagent. It became of a lemon colour when treated with dilute soda, it gave - ho reaction with HgCl, nor with borax solution. This sample when examined contained moisture equal to 15-307 per cent. and ash equal to 2-21 per cent, 1 Of. Sterculia gum ; its similarities and dissimilarities to Tragacanth- Occurrence of Pararabin in Sterculia Gum.—Pharm. Journ. [3] XX» 35) AUSTRALIAN VEGETABLE EXUDATIONS. 399 Acacia retinoides, Schlecht. (N. O. Leguminosw). Sample from Victoria, kindly sent by Baron von Mueller, This gum is in tears of an amber colour, transparent, bright and somewhat brittle. It dissolves entirely in water, the solution being slightly tinged with brown. It is fairly adhesive being of good viscosity. It gives a slight precipitate with ferric chloride, and slightly darkens to a lemon colour when heated with dilute soda. It may be considered a promising specimen of the arabin gums, unfortunately the specimen we have is too dark in colour to be of first rate quality. The other tests, usual with a gum of this class, were not carried out on account of the small amount of material at our disposal, as a portion was required for permanent display in the Gums Collection in the Technological Museum. Acacia Bakeri, Maiden (N.O. Leguminose). Collected at Mullumbimby, N. 8. Wales. Our specimens of this gum are principally in tears, very bright and transparent, dark amber coloured, very brittle and bright in fracture, It is entirely and readily soluble in cold water, and is in this respect one of the best of the coast Acacia gums of this Colony ; it is very adhesive and its comparative viscosity is high. Unfortunately our samples darken much in aqueous solution. The solution is slightly acid to litmus paper. Ferric chloride gives *cream coloured solid mass exactly resembling in bulk and colour that from A. Maideni, and it behaves in the same way as that gum with a saturated solution of borax, mercuric chloride and basic acetate of lead. Both these gums belong to the arabin Sroup, and if obtainable in quantity would be of some commercial Value. As far as our samples show at present, the gum of 4. Maiden has a better colour than that or A. Bakeri, but it is inferior to it as regards its adhesive properties. When warmed With dilute soda solution, the aqueous solution of the gum darkens *onsiderably - The ash of this gum is remarkable in that it con- icc large proportion of manganese. It contains 15-2 per cent. and 3-6 per cent. ash. von 400 J. H. MAIDEN AND H. G. SMITH. Acacia Maideni, F.v.M. (N. O. Leguminose), “ Broad-leaved Sally.” Collected at Woodburn, N. S. Wales. Our sample of this gum is in small pieces of a light amber colour, rather brittle, with very bright fracture, but without the dark brown objectionable portions so common in the Acacia gums, especially A. decwrrens. When treated with cold water, almost the whole of the gum slowly goes into solution, forming a very pale coloured liquid which is very adhesive, of good body or having a high viscosity. It is however, rather tedious to dissolve. The solution is slightly acid to test paper. It forms a solid cream- coloured jelly with ferric chloride, thus showing absence of tannin, It does not thicken with borax solution, nor does it undergo any change with mercuric chloride. It gives a precipitate with basic acetate of lead. It gives a dense white precipitate with alcohol in acid solutions. It slightly darkens to a canary colour when warmed with dilute soda solution. It contains 16:15 per cent. water and 4:67 per cent. ash ; the ash consists principally of the carbonates of lime and manganese and potassium, with sulphuric acid, and only the merest trace of phosphoric acid. The ash con- tains fusible salts and is difficult to incinerate, it contains only a trace of manganese. Albizzia pruinosa, Benth. (N. O. Leguminose). Usually known as “ Stinkwood.” Collected at Cumbulum, near Tintenbar, N. 8. Wales. This sample is in small amber coloured pieces, and is very much admixed with woody matter. It is fairly transparent and breaks with a bright fracture. It is only partly soluble in water the soluble portion being arabin ; it forms a fairly adhesive liquid. It gives no precipitate with ferric chloride nor does it form a jelly, and only slightly darkens when heated with dilute soda. ‘The insolwble: portion.ia:scluble in dilate alkalis, andvie pocnueee as arabin on acidifying with acetic acid and adding alcohol. nM ae 2 ea a Be wer AUSTRALIAN VEGETABLE EXUDATIONS. 401 Kinos orn ASTRINGENT EXUDATIONS. Eucalyptus hemastoma, Sm., var. micrantha, Benth. (N. O.. Myrtacez). “White Gum,” “Cabbage Gum,” “Brittle Gum.” Collected at Bungawalbyn, Richmond River, N.S.W., July 1895. This kino is freshly exuded for the most part. It belongs to the ruby group of kinos, being practically identical with the kino of the normal species described in the proceedings of the Linnean Society. Eucalyptus Planchoniana, F.v.M. (N. O. Myrtacez). We have two small samples. The first was received from F, M. Bailey, ¥..s., Colonial Botanist of Queensland, and is of Queensland origin. When received, this kino was rather dark in colour, evidently through having been collected some time. It is in small pieces, Principally in portions of tears, breaks with a bright fracture, and is shiny on the outside. It dissolves in alcohol to a clear liquid, bright but dark, it is very tough and difficult to powder. It belongs to the ruby group. Our second sample collected on the Evans River, N. 8. Wales, - is unfortunately also nota good sample for complete examination, since it is old and much dried up, while phlobaphenes have formed to a very large extent. From experiments independently made it falls in the ruby group, being another addition to that fairly large group of Eucalypts giving exudations that entirely dissolve when fresh in both alcohol and water. We hope to obtain a better specimen for further examination. Schizomeria ovata, Don. (N.O. Saxifragez). Collected at Evans River, N. 8. Wales. 1 Proc. Linn. Soc. N. S. Wales, (2) 1v., p- 614. Z—Nov. 6, 1895, 402 J. H. MAIDEN AND H. G. SMITH. - This exudation has the appearance of kino." When treated with alcohol the greater portion of the tannic acid goes into solution. This tannin gives a brownish green colour with ferric chloride, when a fairly strong solution of the kino is tested, but on sufficient dilution (in a very dilute aqueous solution), it gives a purple colour with the same reagent; an aqueous solution of the tannin was the material tested. The insoluble portion has the appearance ofa gum, but is insoluble in water on heating until a small quantity of dilute soda has been added. When the original substances treated with water the tannin dissolves, while the gum remains insoluble, but much swollen. This insoluble portion is soluble in dilute soda, and is precipitated on acidifying the solution, or on the addition of alcohol. It is thus found to be metarabin. The reactions and composition of this exudation show it to be identical with that yielded by the Ceratopetalums® and the exudations thus confirm the affinities of these trees belonging to different genera -of the Saxifragez. Gum Resins. Medicosma Cunninghamii, Hook. (N. O. Rutacez). The tree is locally known as “Glue Gum.” ‘Collected at Mullumbimby, N. 8. Wales. This is a red, brittle, resinous substance with a very bright fracture, in small transparent pieces, and of a bright rather light, ruby colour. It is very brittle and readily powders, the colour cee CG OU) Se 1 A number of our Eucalyptus and _ —_—- exudations of variable composition have been called “kinos,” because of their rese™ blance, more or less strong, to the en eout Rae of Pter marsupium, known in medicine as “kino.” The use of the term is co venient, and is used in these papers “ without prejudice.” It seems to™ -quite ee a Snags to coin anORHEr: term ~~ astringent exudar tions the original kino; we aleo look upon it as cundedeable, until very many more have been examined, and before those who lay stress upon nom menclatare of this kind are in a nese to select a suitable eh or terms. 2 Ob tions on the gums yielded by two species of Ceratopetalum— Proc. Aust. Assoc. Aas. Sci., 11., 381, (1890). os 0 Se epee LAP ES erd Re 8 AUSTRALIAN VEGETABLE EXUDATIONS. — 403 of the powder being a dark pink. It was apparently very liquid when exuding, as the adherent wood and bark are varnished with it. It burns with a very smoky flame, resembling ordinary resin in this respect, and burns away almost without residue. When treated with ether the resin slowly dissolves, forming a lemon coloured solution. The powder acts in a very peculiar manner in ether, agglutinating itself at once into an elastic ball which can be stretched in the same way as caoutchouc, thus preventing the solution of the resin in the interior portions. In rectified alcohol the resin goes into solution, forming a bright orange coloured liquid, the residue not agelutinating. When the resin has been removed and the residue dried, it powders readily to a light brown colour. The resin is of an orange brown colour. The gummy portion, after thoroughly washing with alcohol, is much swollen and somewhat elastic. When dried until of con- stant weight it was found to amount to 20-02 per cent. of the whole. The original substance in powder on being heated in an oven until of constant weight, 2°14 per cent. was lost ; this was Probably moisture contained in the gummy portion, as no volatile oil appeared to be present. The resin when evaporated to dry- hess and heated till of constant weight equalled 77-2 per cent, While the ash only amounted to -2 per cent., so that the proximate Constituents may be stated as meth thc: ... 77:20 per cent. Gummy substance? 20-02 Moisture, etc. ... 214 y Ash deh vane ‘20 ” 99-56 : The gummy portion contains some albuminoids, as indicated by ‘Presence of nitrogen. The dried portion after separating ie — 18 not soluble in water on boiling in any degree ; when boiled a = dilute soda it becomes brown, but only a small portion goes to solution, nor is it soluble in dilute acids. From the above it 404 J. H. MAIDEN AND H. G. SMITH. appears that this insoluble substance contained in this resin is a body of some interest, and when sufficient of the exudation shall have been obtained, it will be desirable for its composition and constituents to be determined. For the present we are only able to describe it as ‘‘gummy substance” ? The collector (Mr. W. Biuerlen) says that, when fresh, this exudation is exceedingly sticky, hence the local name of the tree. Tt is not abundant, but is widely diffused, and well known locally because of its brilliant colour. It readily stains the fingers 4 vermilion colour, and that, when dry, it reminded him of grass- tree gum (Xanthorrhea). GEOLOGICAL LABORATORY NOTES—No. 1. By J. Minne Curran. [Read before the Royal Society of N. S. Wales, November 6, 189%.] I—On Senentum Associatep witH Gop aNnp BisMvT#, . From Mount Hops, N. S. WALES. © Some twelve months ago I received a box of gold bearing stone from the Mount Allen Mine near Mount Hope, in this Colony: The stone was packed loosely, and on opening the case, @ peculiar smell suggestive of selenium was easily detected. The same odour could be produced at any time by shaking the stones together. The material is being mined for gold, and is part of an auriferous belt of slate, interbedded with Silurian slates to the north of Mount Hope. The slate is of a rich red ale colour, and splits readily into laminae, which correspond with, or are gene parallel to the original bedding planes. Occasionally strings knots of a harder clay-slate occur, not so bright in colour, ©” rather inclining toa chocolate brown. Through this last nodules — of quartz are sometimes developed. So far no sulphides = ad but GEOLOGICAL LABORATORY NOTES. 405 been detected in the stone, although there can be little doubt that this oxidised lode-stuff has been derived from some form of pyrites. The gold is noted as occurring in three ways. 1. In plates and patches spread out along the laminae of the slate, appearing bright and burnished-like in lustre, but in thick- ness hardly more than a mere film. 2. In specks and grains associated with quartz. 3. In grains and irregular masses enclosed completely in an aggregate of bismuth oxide and carbonate. The selenium is irregularly distributed through the stone. There is no character that I could recognise, to guide one in identifying the portions richest in this rare element. Heated in a closed glass tube most of the stone gives a black sublimate with the characteristic odour of volatilized selenium. When the portions of the stone richer in selenium are so treated, the subli- mate shows a red ring, inclining to crimson below the black. Any samples of the stone when rubbed briskly together emit the h 1 char: istic di le smell suggestive of bisulphide of carbon. Oo The oxide and carbonate have evidently been derived from some mineral not now determinable. It is probable that the selenium and the bismuth existed as a selenide or a sulphide of bismuth. This sulphide or selinide of bismuth was probably auriferous, as in the case of the telluride of bismuth described by Professor David and Mr. Mingaye.! As work is progressing at the Mount Allen Mine we may hope for further information in regard to this occurrence of selenium. ' IL—Oy a Grapurric Stare From Yaucocrin, N.S. WALES. Graphitic slates crop out at a point about twelve miles north- west of Yalcogrin Station. They are interstratified with slates of Silurian age. These are again succeeded unconformably by Devonian Sandstones and quartzites. The lustrous and polished ‘Appearance of the slate would lead one believe that it contained a high percentage of graphite. It marks paper readily when eae 1 Records of the Geological Survey, N. S. Wales, Vol. 1. pp- 26,29: 406 J. MILNE CURRAN. abraided in the direction of its cleavage. The cleavage surfaces of some of this slate are pitted with obscure markings which may prove of organic origin. On analysis the slate gives 12:57 of graphite. IIT.—Anatysis oF WATER FROM WYALONG. A remarkable feature in the Wyalong goldfield is the great depth to which the prevailing rock, granite, is decomposed. Shafts have been put down to a depth of one hundred and fifty to one hundred and ninety feet through a granite decomposed in situ. A tract of country of this description must absorb a large percentage of the rainfall, with little chance of an outlet underground to completely drain the saturated decomposed rock. Mr. Farant Cox found a very considerable supply of water sufficient for a six foot Huntingdon mill without making any impression on the available supply. The water was highly mineralised, and as one would expect, holds in solution magnesia, lime, soda, and potash. A preliminary examination showed that the water held close on 2,000 grains of total solids per gallon. through a half inch pipe into the still. The oil obtained by distillation has at first a rather acrid odour, but this is possibly due to traces of the accompanying water, for on drying by means of fused calcium chloride the odour quickly improves, and in a few days becomes almost the same as that of the bruised fruit. On submitting the dried oil to fractionation the following results Were obtained. The oil began to boil at about 174° C., and 60—65 ce. were treated. 460 R. THRELFALL. Fraction from 174° to 180°2° C., 22 cc., colourless. 180-2° to 185° C., 20°5 ec., colourless. 185° to 190° C., 8 ec., colourless. Pe 190° to 200° C., 5 ec., colourless. is 200° to 210° C., 3:5 cc., colourless. - 210° to 250° C., 1:0 ce., faint greenish-yellow. a 250° to 280° C., 08 cc., bright yellow-green. Above 280° C., residue ‘57 cc., red with fairly strong green fluorescence. During the process it was noticed that the oilappeared to begin to decompose slightly at about 200° C., this was also shown by the distillate changing sensibly in its odour above this temperature. The distillates below this temperature had sensibly the same odour as the oil before it was distilled. The residue when burned emitted the same odour as the green resin already referred to. The density of the oil was determined at 24-5 C. by weighing a bit of glass in it: the result was -848 (24). The refractive index was measured by means of a hollow prism and also by means of the refractometer as a check. The results hatch Pp . 1:4742 at 26° C. Pr . 1-4830 at 26° C. The action of Pittosporwm oil on polarised light was studied by myself to some extent, and thoroughly by Mr. Pollock with the assistance of Mr. Grant. The results of these observations is t0 show that Pittosporum oil in the crude but dry state rotates the plane of polarised sodium light in the same direction as cane sugar and to the extent of + 79°850° per decimeter at 244° C. I have to thank Professor Stuart for allowing us to use ® polarimeter belonging to the Medical School. The leaves of the introduced Pepper Tree (Schinus molle) were also examined with a view to discovering the source of the pungent odour so noticeable when the leaves are bruised. By distillation in steam I obtained 8-3 cubic centimetres of a thick oil from three NOTES ON ANTARCTIC ROCKS. 461 and a half kilos of the green leaves gathered in June. The oil was slightly yellowish and nearly as thick as vaseline oil. It had a pungent resinous and bitter taste, and a very strong scent 0 the pepper tree leaves. Owing to the small quantity as yet obtained, no steps have been taken towards an examination. From the very strong scent of the oil, however, it is not unlikely that the odour of the leaves of the pepper tree may be wholly owing to it. NOTES ON ANTARCTIC ROCKS COLLECTED BY MR. C. E. BORCHGREVINK. By T. W. E. Davin, B.A, F.G.8., Professor of Geology; W. F. SMEETH, M.A., B.E., Assoc. R.S.M., Lecturer in Metallurgy and Demonstrator in Geology; and J. A. SCHOFIELD, F.C.S., Assoc. R.8.M., Demonstrator in Chemistry, University of Sydney. [With Plates XIII. - oid.) [Read before the Royal Society of N. S. Wales, August 7 and December 4, 1895. ] Part I.—Inrropucrory Notes aBouT ANTARCTICA. (1) Introduction.—The region to which this paper refers is by far the largest unexplored land area in the world, its area being estimated by Dr. John Murray to be at least 4,000,000 square miles, and therefore greater than that of Australia. Situated between the voleanic zone of the Andes and the Taupo zone in New Zealand, it supplies several links to that chain of fire which, Commencing at the north-western extremity of Antarctica, runs around the earth along the Andes and the volcanoes of Central America and Alaska, through the Aleutian Islands, Japan, the Kurile Islands, and various islands of the Pacific, through north- 462 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. eastern New Guinea, the Tonga Islands and New Zealand back to Antarctica, ending in the volcanic zone of Victoria Land. About fifteen extinct, five active, and three dormant (’) volcanoes have been recorded as occurring in the Antarctic Regions, (if the South Shetlands be included under this term), the highest known peak, Mount Melbourne, attaining an altitude of about 15,000 feet. (2) Summary of the History of Antarctic Exploration.—Want of access to the necessary literature precludes us from doing more than traversing cursorily the records of a few of the chief Antarctic Explorers. The honour of being the first man to discover the Antarctic Continent probably belongs to Captain James Cook, who in the year 1772 reached latitude 71° 10’S., in longitude 106° 54’ W., where he sighted the Great Ice Barrier, which forms the seaward boundary of Antarctica. Speaking of this discovery Sir James Ross says!:—“I confidently believe with D’'Urville that the enormous mass of ice which bounded his view, when at his extreme south latitude, was a range of mountainous land covered with snow.” In 1819 William Smith in the brig William discovered the Archipelago of the South Shetlands, South of Cape Horn. In 1820-23 Weddell visited the South Shetlands, including the the active volcano Bridgman. Powell, the discoverer of the South Orkneys, visited the volcanic island of Bridgman in 1822, and found it to be at that time two hundred feet high. Weddell, who visited it during the following year, estimates its height at four hundred feet, and describes the island as being of sugarloaf shape, whereas at the time of Powell’s visit there was a crater 0” the west side of the island. Possibly the crater had disappeared at the time of the subsequent visit of Weddell, as he makes 10 mention of it. Weddell penetrated to 74° S. in 1823, thus attaining a higher latitude than Captain Cook, but he s4W no land anywhere in that neighbourhood. agin pe 1 Voyage in the South Seas. By Sir James C. Ross. Vol. 1., p- 276 NOTES ON ANTARCTIC ROCKS. 463 In 1831 Biscoe in the brig Zula discovered Enderby’s Land. In 1839 Balleny discovered Balleny’s Island, a volcano 12,000 feet high, and adjoining it the active (?) voleano of Buckle Island. In 1839 the important French Expedition, under Dumont D’Urville explored the South Shetlands.’ Syenite, occurring in needle-like pinnacles, was found at Smith Island, while this island as well as Livingstone, Greenwich, Roberts, King Georg? and Elephant Islands were proved to be of primary schistose formation, traversed by intrusive igneous rocks. The trend of these rocks was ascertained to be north-east and south-west, dipping (?) at from 29° to 30°. Powell Islands were discovered to belong to a somewhat similar formation, being composed of phyllite-like talcites and quartzose talc rocks. In the South Orkneys near Laurie Island the occurrence of a greyish-white limestone is recorded, as well as that of phyllite-like schists, their strike being north-north-west and south-south-east, and their angle of dip over 60°. The granites and syenites, of which the New South Orkney Islands consist, were found to have contributed the greater number of the erratics observed on the coast of Terra del Fuego. An interesting description is given in the above work of the remarkable volcanic crater, among the South Shetlands, known as Deception Island. The basin of the crater is submerged, the sea being sixty-seven feet deep at the centre of the basin, and the latter being about five miles in width measured at sea level : the maximum diameter of the crater ring measured at sea-level across its outer circumference is about eight miles, thus giving an average width of about one and a half miles for the portion of the crater rim above sea level. The crater is described as being built up of alternate layers of ice and volcanic tuff. Fumaroles were discovered to the number of at least one hundred and fifty, a... ws Voyage au Péle Sud et dans l’Oceanie. Sur les corvettes L’ Astrolabe pr ae Zélée, exécuté pendant les Années 1837-40. Géologie, Minéralogie phie physique du Voyage, Vols. xx11.-xxt., Paris, 1848. 464 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. the temperature of the water flowing from some being 140° Fahr. This expedition discovered Adélie Land. The mainland appeared to be completely swathed in snow and ice, but nine small islands off the mainland were found to be more or less free from ice, and to consist of granite and gneiss, the folia of which strike in an east and west direction. In 1840 Commander Wilkes in the U.S.A. Corvette Vincennes discovered Wilkes Land. In January 1841, Sir James Clarke Ross made his memorable discovery of Victoria Land. With the object of trying to find the South Magnetic Pole, as he had already found the North Magnetic Pole, he forced his well fortitied ships through the heavy pack ice which he encountered in latitude about 67° S., and longitude 1744° E. It was a very formidable pack. In four or five days, however, he forced his way through it, and entered comparatively open water beyond, a great ocean pool about six hundred miles in diameter. Bounding this on the west was the magnificent chain of snow clad volcanoes of Victoria Land. Ross traced the coast for five hundred miles southwards until he encountered the Great Ice Barrier terminating seawards in a sheer wall of ice, from one hundred and eighty to two hundred feet high, through which, in Ross’ words, ‘‘he could no more sail his ships than he could sail them through the cliffs of Dover.” His dredgings showed that marine forms of animal life, especially polyzoa, were abundant right up to the edge of the Great Ice Barrier. Ross states (op. cit.) that on January 19th, 1841, when off the coast of South Victoria, in latitude 72° 31’ S., longitude 173° 39’ E., “the dredge was put over in two hundred and seventy fathoms water, and after trailing along the ground for some time was hauled in. It was found to contain a block of grey granite, composed of large crystals of quartz, mica and felspar, with apparently a clean and recent fracture, as if lately broken off from the main rock, and had probably been deposited by the agency of an iceberg. McCormick, the surgeon of the Hrebuss frequently found fragments of granite in the stomachs of the penguins,” NOTES ON ANTARCTIC ROCKS. 465 In 1874, H.M.S. Challenger visited the neighbourhood of the supposed Termination Land of Wilkes, and drift fragments were brought up by the dredge of granite, dioritic rocks, quartzites, clay shales etc. Tetrasporew were so abundant over wide areas as to give the sea a peculiar green colour, and the sea swarmed with diatoms. In 1883! the Zalisman dredged from depths mostly of between 4,000 to 5,000 métres, common granite, horn- blendie granite, pegmatite, granulites rich in muscovite and microcline, with two specimens respectively of diorite and diabase, and numerous specimens of gneiss and hornblendic gneiss. The gneisses were found to be more abundantly represented than the volcanic rocks. The following minerals are recorded as having been observed in the gneiss :—microcline, zircon, sphene, apatite, rutile, garnet, tourmaline, biotite, muscovite, magnetite, epidote, amphibole, pyroxene, diallage, and enstatite. Amongst rocks probably of volcanic origin may be mentioned seven specimens of augitic labradorite rocks, two of basalt, and eight of andesites partly hornblendic, besides five specimens of pumice, eight of basic scorie more or less palagonitic, and ten Specimens of very basic tuffs. Amongst metamorphic rocks dredged by the Talisman, may also be mentioned five specimens of mica schists with tourmaline, microcline, sphene and epidote, fifteen specimens of sericite and very epidotic quartz schists rich in rutile, besides argillaceous schist with erystals of biotite and garnet and numerous particles of graphite. Amongst other rock specimens dredged were many representing undoubted sedimentary rocks, ¢.g., sixteen of arkose very quartzose, nineteen of sandstones, and sixty-three of limestone. Some of the limestones are marble, some are oolitic, and thirty-one are fossiliferous, the fossils consisting chiefly of indeterminable bivalve shells. Some fragments of hard yellowish magnesian limestones contain sections of Gyroporella, and are therefore very probably J *Fouqué and Lévy—Comptes Rendus de I’Académie des Sciences, anvier — Juin, 1886, cir., pp. 793 — 795. Dp—Dee. 4, 1895, 466 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. of Triassic Age. Three specimens are almost entirely foraminiferal limestones of a markedly tertiary facies. In 1893-94 the whaler Jason (Captain C. A. Larsen) visited ' the north-western portion of Antarctica. The important discovery was made by Dr. Donald,! of Lower Tertiary rocks with the fossil shells Cucullea, Natica, and Cytherea, in situ at Cape Seymour. Fossil wood was also found imbedded in the Tertiary rocks ata level of three hundred feet above the sea. A new active volcano, named by Captain Larsen, Christensen Volcano, was discovered in latitude 65° 5’ S., longitude 58° 40’ W. On the sketch chart accompanying Captain Larsen’s paper, another active volcano, Sarsee,” is shown, also Lindenberg Volcano [extinct (?)], and the four Seal Islands, all of which are considered to be of volcanic origin, if not dormant or extinct volcanoes. We now come to the subject of the latest piece of Antarctic Exploration accomplished by Mr. C. E. Borchgrevink in the whaler Antarctic. The following account is partly taken from the Standard of 2nd August, 1895, partly from notes kindly be us by Mr. Borchgrevink :— The Antarctic was well fortified for ice work, her timbers being nowhere less than three feet in thickness, and actually not less than nine feet thick at the bows. She sailed from Melbourne on the 20th September, 1894. Mr. H. J. Bull accompanied the expedition as manager of the Antarctic Whaling Company, and Mr. C. E. Borchgrevink finding that there was no room on board for him in the capacity of scientific collector, pluckily engaged himself as an ordinary seaman. The pack ice was sighted on the 7th December, and on the following day the Antarctic was in latitude 58° 45’ S., longitude 171° 30’ E., and with vast streams of ice driving all around. When the Antarctic entered the pack ice the temperature of the air was 25° Fahr., and that of the water 1 J. Murray—Geogr. Journ. Vol. ut., No. 1, Jan. 1894, pp. 10, 11. 2 Geogr. Journ. 1894, rv., No. 4, p. 333. NOTES ON ANTARCTIC ROCKS. 467 28° Fabr. Penguins were about in great numbers, and no difficulty was experienced in killing some of them, On the 14th December, in latitude 66° 44’ S. and longitude 164° 0’ E., as the Antarctic approached Balleny Island, the ice floes greatly increased in size, and some of them were observed to carry stones and earth. So thick and dangerous was the ice that a vessel, dependent wholly upon sails, could not have existed, and even with steam those on board ran very considerable risk, and had one or two narrow escapes. They decided to run eastward, following in the track of the Erebus and Terror, On Christmas Eve they saw the midnight sun in latitude 66° 47’ S. and longi- tude 174° 8’ E., and at midnight on the 31st December the sun was again shining brightly. Altogether they were thirty-eight days in working their way through the pack ice, and then they got into a clear, smooth, open expanse of sea. They steered straight for Cape Adare in Victoria Land, which they first sighted on Jan. 16. Mr. Borch- grevink describes it as a square bluff of basaltic rock. The temperature of the air here was 32°, and of the water 30, and the sky was perfectly clear. Cape Adare rose to a height of 3,77 9 feet. Near Mount Sabine a peak was sighted clear of snow, con- sidered to be a volcano recently in eruption. On January 18th, they sighted Possession Island, where Sir - James Ross landed fifty-four years before and planted the British flag. They found an immense quantity of penguins, and a large portion of the island, which they judged to be about three hundred and sixty acres in extent, was covered with a deep layer of guano, Small plants were found there by Mr. Borchgrevink growing on the rocks up to thirty feet above sea level. These have subse- quently been identified as lichens. On the 20th February they steamed still further sonth ward, and sighted a new cape which they named Cape Oscar, in honour of the King of Sweden and Norway, whose birthday it happened ~ tobe. On the 22nd they were in latitude 74° S., and no whales 468 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. being visible they decided to return northwards to Cape Adare, where they landed, being the first human beings who had ‘ever set foot on that territory. Their landing place was a sort of peninsula, which formed a complete breakwater for the inner bay, through which they steered. Immense swarms of penguins were on the cape, on which they nested as high up as 1,000 feet. Mr. Borchgrevink and his party after landing, collected specimens of the rock, and they also found some signs of vegetation, consisting of lichens (?) like those met with by them at Possession Island. Throughout the whole of their voyage they had a comparatively high temperature, and they met with great numbers of sperm whales. The minimum temperature which they encountered within the Antarctic circle was 25° Fahr., and the maximum was 46°, while all through the ice pack it kept at 28°. The mean temperature for January 1895 was 32°5° Fahr., and for February 30° Fahr. ~ While at Possession Island and Cape Adare Mr. Borchgrevink collected specimens of the different varieties of rock obtainable at those localities. Several of the specimens from Cape Adare are in the form of waterworn pebbles, which were picked up by Mr. Borchgrevink on the shores of that headland. (3) Summary of Antarctic Geology.—The observations of the Antarctic explorers mentioned above prove that (a) eruptive, (b) sedimentary, and (c) metamorphic rocks are well represented in Antarctica. If the (a) Hruptive rocks be divided into respectively plutonic, and volcanic groups, we find that the former comprises granite, pegmatite, granulites rich in microcline and muscovite, syenite, diorite, diabase etc., and the latter pumice, andesites partly hornblendic, augite-labradorite rocks (augite-andesites ), basalts, basic scorie, palagonite tufts. (b) Sedimentary rocks—These comprise the Cucullea rocks of Cape Seymour, with fossil wood of Lower Tertiary Age, numerous fragments of limestone, partly molluscan, partly foraminiferal, the latter Tertiary, the former of doubtful geological age, some more NOTES ON ANTARCTIC ROCKS. 469 or less incoherent, some oolitic, some in the condition of marble. Besides these are the fragments of hard yellowish magnesian limestone with Gyroporella, probably Triassic, the Paleozoic (‘) greyish-white limestones of the South Orkneys, fragments of various sandstones, arkose, quartzites, and clay shales. (c) Metamorphic rocks—These appear to be abundantly repre- sented and comprise :—gneisses, some hornblendic, containing zircon, microcline, sphene, apatite, rutile, tourmaline etc., mica- schists with tourmaline, microcline, sphene and epidote ; sericite quartz-schists, epidotic quartz-schists rich in rutile, argillaceous schist with crystals of biotite and garnet, and numerous particles of graphite, phyllite schists and tale schists. With regard to the volcanic zone of Antarctica the following is a list of the volcanoes at present known to us :— 1. Balleny Island ... Dormant (?)... ... 12,000 feet high, 2. Buckle Island ...Active (7)... ... small. 3, Mount Sabine —_... Extinct 49 gee ... 9,500 feet, 4. Cone observed by Borchgrevink near Mt. Sabine apparently recently in eruption, Active (). 5. Mount Herschell ...Extinct ... ... 14,000 feet (?) ,, 6. Mount Melbourne... Extinct(? large crater). 7. Mount Erebus _... Active is ... 12,367 feet (?) 5, 8. Mount Terror ...Extinct (1) ... ... 10,884 feet 5 9. Mount Haddington Extinct (?) ... --» 7,050 feet 10. Cockburn Island ...Extinct (7)... +» 2750 feet 55 11. Paulet Island CO Oe FAs ihe 750 feet 5 12. Etna Island ... Extinct (7) ... soe 1,300 £006... ...44 13, Bridgman Island ... Active cone ... 400 feet (?) », i, Apsland Island... Extinct crater.. 15. Astrolabe Island ... Extinct crater ... 1,000 feet (?) » 16. Deception Island—Large partly submerged crater with numerous fumaroles, dormant (?) 800 — 1,800ft. », ui. Christensen Volcano Active... ..- Small. 18. Sarsee Voleano ... Active... ay 470 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. 19. Lindenberg Volcano Extinct (?)... ©... Small 21. é 3 29, The four Seal Islands, extinct (1) * 23. As regards the general distribution of these volcanoes, we may here quote from a previous paper by one of us forming part of his. Presidential Address to the Linnean Society of New South Wales for 1895, pp. 155 - 156 :—‘The volcanoes of Victoria Land show a tendency to linear arrangement. From Mount Sabine to Mount Melbourne the trend is south-south-westerly. Mount Erebus and Mount Terror lie almost due south of Mount Sabine. Further north from Mount Sabine the great earth-fold, on the septum of which this chain of volcanoes is situated, probably bends a little westwards, as shown partly by the surroundings, partly by the position of Balleny’s Island. North-west of Balleny’s Island the great fold trends perhaps to the knotting point between the Tas- manian axis of folding, described in the address just referred to, and that of New Zealand, the former perhaps running through Royal Company Island, and the latter through or near Auckland Island and Macquarie Island. The knotting point would probably be somewhere (approximately) near the intersection of the 60th parallel of south latitude with the 150th meridian of longitude east from Greenwich. It would thus join the line of extinct volcanoes along East Australia on the west, and perhaps the active volcanic zone of the North Island of New Zealand, or ab all events the fold which bounds that continent, on the east. Traced in the opposite direction, the volcanic zone probably runs through Seal Islands, the active volcanoes of Christensea and Sarsee, and through Mount Haddington, an extinct voleano in Trinity Land, to Paulet and Bridgman Islands, active volcanoes. The volcanic zone bends easterly from here on account of the easterly trend in the fold, which appears to make a loop towards South Georgia before it swings back towards Cape Horn. That there is a real easterly trend in the earth-fold at Trinity Land NOTES ON ANTARCTIC ROCKS. 471 and the South Shetlands is proved by the observations made by the Astrolabe and Zélée expedition, which record a strike in a north-north-east and south-south-west direction for the greyish- white limestones and phyllite-schists at the South Orkneys. Towards Cape Horn from near South Georgia the fold probably trends west-north-westerly, then follows an approximately meridional direction parallel with the chain of the Andes. It may be noted, however, that whereas the Hrebus chain of Victoria Land is on the east side of the fold, the Christensen-Bridgman group are apparently on the opposite side. This may be due to the fact that at the latter locality the eastern slope of the fold is steeper than the western, as seems probable from the presence of _ the deep ovean abyss east of Graham’s Land, as shown on Dr. Murray’s map. It is probable, therefore, that the volcanic chain of Victoria Land will continue towards the South Pole, probably bending somewhat to the eastward, and will thence change its position to the fold on the other side of the Antarctic continent, so as to run through the Christensen-Bridgman line of volcanoes. In any case it is almost certain that high land, covered of course more or less by snow and glaciers, will be found at the South ~ Pole.” The additional information as to the geology of Antarctica fur- nished by the collections submitted to us by Mr. Borehgrevink is detailed below :— Part I—Prrronoay or tHE Rocks cotuecteD By Mr. C. E. Borcucrevink rrom Cape ADARE, VicrorIA LAND, AND FROM Possession IsLAND. A.—SprEcIMENS From CAPE ADARE. Garnetiferous-Granulitic-Aplite, (No. 4). This rock is the only representative of the acid-group among the Specimens. In the mass it is a white, holocrystalline, aggre- Sate of quartz and felspar granules. Numerous small, well- “rystallized red garnets are present, also numerous crystals of black tourmaline. In section the granulitic texture is very 472 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. marked, and the felspar granules are seen to consist largely of microcline. The hatched twin lamelle are very irregular and wavy and suggest that the rock has been under pressure. There isa small amount of triclinic felspars which appears to lie between albite and oligoclase. One section of the latter shows a remark- able twin structure (Plate 13, fig. 1), the outline is rudely rec- tangular and the grain is divided into four equal areas by lines joining the middle points of the sides. Each area is finely lamellar, and extinguishes simultaneously with the one diagonally opposite to it. A possible explanation may be that it is a section approxi- mately parallel to the macropinacoid (100) divided into two halves according to the Carlsbad law, and again divided into two halves, one of which is reversed on the other by turning round a normal to 001, according to the Mannebach law. In addition to this each of the four areas exhibit albite lamellation. Some of the felspars show numerous fine parallel cavities probably of the nature of solution planes. The quartz grains have some liquid enclosures but not many, and also some very tine needles of a mineral which has not been ‘determined. Stray flakes of muscovite have been noticed. Among the accessory minerals the garnets do not require further notice. The tourmaline occurs in well shaped prisms the pleochroism being pale pinkish-brown to very dark slaty-purple. Included in the other minerals are numerous highly refracting grains and prisms, all practically colourless. Some of these must be referred to topaz, although the optical sign appears to be negative instead of positive, as is more usual. One piece in pat ticular, (Plate 13, figs. 2a, 2b) has the outline of a cross section of topaz and gives a good figure in convergent light. In this, from the shape of the section, it can be seen that the optic axial plane is the macropinacoid, and that the sign is negative while the axial angle is somewhat smaller than usual. If this mineral is a topaz, it would appear that in addition to the change of sign, the plane of the optic axes has taken a position at right angles od the normal one. Itisan interesting point in connexion with this, NOTES ON ANTARCTIC ROCKS. 473 that we have found, among some sections cut for stauroscopic investigation, a specimen of topaz in which the optic axes make a very small angle with each other (not more than a few degrees) and that the optical sign is negative. It may be that under certain conditions topaz changes its axial angle, and after passing through zero the axes open out in a plane at right angles to their former position with changed sign. Besides some apatites and zircons there are some grains with extremely strong double refraction. One of these, a small prism showing pyramid faces at one end, gives colours of the seventh order in polarized light (Plate 13, fig. 3). The presence of some prismatic cleavage lines render it probable that it is rutile. There are a few tabular crystals of anatase, and some grains, with somewhat lower double refraction and without cleavage, may most probably be referred to cassiterite. : Trachyte, (Nos. 1 and 2). Compact, greenish-grey in colour, somewhat fissile. Sp. gr. 2°49. Analysis yielded the following composition :— SiO, = 61-01 Al,O; = 16°62 Fe,O,; = 3°59 FeO = 281 MnO =. "00 CaO a Bal : MgO es” 08 Na,O = $92 K,0 & 5°22 Water (ignition)= 1°13 100714 Phosphoric acid and chlorine present in small quantities. Under the microscope the rock is seen to be composed principally of sanidine microlites. There is a small proportion of lath-shaped triclinic microlites and of cryptocrystalline interstitial material. 474 T. W. E. DAVID, W. F. SMEETH, AND J. A, SCHOFIELD. (Plate 14, fig. 1), The sanidines are apparently all tabular ih form, some slices showing nothing but tabular sections while others yield only lath-shaped ones. . The ferro-magnesian constituent is represented by an egirine — which is present in considerable quantity (probably nearly 25/ of the whole bulk), It exhibits brownish-green to bluish-green — pleochroism with a small extinction angle. It is uniformly dis — tributed in minute angular patches moulded on the felspars with here and there a tendency to an elongated prismatic habit. In — places it shows ophitic structure on a small scale. The only porphyritic constituents are a few rounded grains of this same eegirine and a few large grains of magnetite. As accessory constituents there are a number of minute flakes of a brown biotite, some needles of apatite included in the felspars, a few zircons and a little magnetite. q Glassy Augite Andesite (1) No. 11. Greyish-black in the mass and has the appearance of a fine — grained andesite or basalt. a There are but few porphyritic constituents. Some corroded fragments of felspar, apparently monoclinic, and some grains ofa pale augite with faint pleochroism—yellowish- to pinkish-brow a There are one or two patches of magnetite (opacite) granules with 6 traces of brown hornblendic material remaining. Next to these in point of size we have a sparsely scattered “ ‘ of small lath-shaped felspars, the majority of which are silt | twinned, but a few show lamellar twinning and appear to be oligoclase, The base appears to be glassy, but is generally 0 quite isotropic and gives the impression of being in @ near, strain. It is quite colourless and in many places indefinite plates” of felspar material seem to have partially developed. This base is filled with very minute augite crystals. They 3 for the most part well formed crystals, with short prismatic 8°” pale green in colour, and appear to have a small angle ofextinctio® — | NOTES ON ANTARCTIC ROCKS. 475 They are too minute to be certain of pleochroism. In addition to these there is much magnetite dust. This rock ought perhaps to be classified as a trachytic andesite owing to the number of apparently monoclinic felspars present. The amount of glassy base present renders its nomenclature a matter of uncertainty which can only be settled by chemical analysis for which there has not been time up to the present. Vesicular Andesite Glass, No. 13. This is a highly vesicular fragment which on examination proves to have many points in common with the glassy andesite No. 11, and may well be considered as a portion of the same flow. The porphyritic constituents are quite similar to those in No. 11, with the exception that we have here some hornblendes preserved with a ring of opacite granules round them, while in No. 11 the horn- blende has practically completely disappeared, The lath-shaped felspars are not so numerous, but are still for the most part simply twinned. The base is faintly coloured and somewhat more glassy while the incipient felspar plates are not noticed. The minute augite crystals are perhaps quite as numerous as in No. 11, but are even smaller while the magnetite and opacite dust is more diffused. Basaltic Andesite (No. 6). In the mass fine-grained, very dark grey in colour, with but few porphyritic crystals. Sp. gr. 2:78. Th sections the ground mass is eryptocrystalline, and contains a dust of magnetite and minute augite granules. Above this in 86 scale of crystallization is a crop of forked triclinic microlites, Siving extinction angles approximating to labradorite. There are also many small square and rectangular sections of felspar, most of which show only simple twinning. Some large crystals of magnetite are present, and a number of ee sized’ yellowish brown augites. One or two grains of olivine were noticed enclosed in augite. There are also some - 476 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. corroded crystals of a rich brown hornblende, which are sur- rounded by a ring of magnetite (opacite) dust, which varies in amount from a thin layer to a complete absorption of the original mineral. (Plate 14, fig. 3.) : Olivine-Dolerite, No. 14. This rock has suffered considerable alteration. The felspars are lath-shaped, not much decomposed, but the broken and irregular lamelle give evidence of considerable crushing. These felspars have a tendency to aggregate into radial or fan-shaped groups which might be considered as a poor attempt at ‘ centric’ or ‘ocellar.’ structure. | The augite is brown in colour, the depth increasing toward the periphery of the grain. It occurs in irregular grains partly moulded on the felspars, and giving rise in places to ophitic structure. Most of it is fairly fresh, but in places it has been converted into a felted mass of chlorite fibres, and possibly also serpentine or other ferruginous silicates. The olivine is in large grains, frequently with idiomorphi¢ contours. These have for the most part been converted into serpentine, without separation of magnetite dust, but coloured in patches by homogeneous aggregates of chlorite fibres. Magnetite crystals are present, together with irregular masses of secondary magnetite. Specular hematite seems to be present also, the brilliant faces of the crystals being noticeable in reflected light ; some of this is possibly micaceous ilmenite. Numerous slender needles of apatite traverse all other com stituents, and there are needles of what appears to be actinolithic mineral also present. Olivine Basalt (Nos. 3a, 3). Compact, greyish-black with phenocrysts of augite, olivine, and plagioclase. Sp. gr. 2-92. In section the rock is clear and fresh. The ground-mass fine in texture and composed of plagioclase microlites, minute grains Ri DLE ee NOTES ON ANTARCTIC ROCKS. 477 of brownish-green augite moulded on the felspars, and magnetite dust. The porphyritic constituents are :—Plagioclase (chiefly labro- dorite), some of the crystals being zoned and others appear to be made up of patches of felspar of different composition, forming a large lath-shaped section. Some of these patches have all the appearance of sanidine. Augite, pale brown in section with idiomorphic contours. Olivine, generally in rounded grains, occa- sionally idiomorphic, and showing no alteration to speak of. There are also some large grains of- magnetite. Some of these have a coarsely arborescent structure, the spaces between the branches being occupied by felspar and augite similar to the ground-mass. This would seem to point to the constituents of the ground-mass having started to crystallize before the grains of magnetite had completely separated out. (Plate 14, fig. 2.) Olivine Basalt, (No. 7). This specimen is a vescicular pebble of a reddish-brown colour. Sp. gr. 3-07. Under the microscope the rock is seen to consist of a fine-grained ground-mass much stained with ferruginous decomposition pro- ducts, and carrying numerous phenocrysts of augite, olivine and Magnetite. The scarcity of felspar is at once apparent, no crystals of any appreciable size being present. The ground-mass however, contains a considerable number of very small felspar microlites. These together with much very finely granular augite and magnetite dust make up the ground-mass, little if any glass being discernible, At first the comparative scarcity of felspar would suggest that the rock approached a limburgite in composition. The following analysis shows that it must be retained in the basalt group : SiO, = 45°137 Al,O = 1813 Fe,O, = 12:94 CaO = 11°23 478 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. MgO = 7:33 BO ee 7 8S Na,O. = , 2-14 H,O = 2:18 100-06 The percentage of Al,O, is high and implies the presence of felspar, either actual or potential. As there is little glass present it is probable that the augite, which is by far the most prevalent constituent, is itself highly aluminous. The porphyritic augites are frequently broken but not much corroded. All exhibit shelly zoning, there being generally two or three thin shells round each crystal. In some cases where the crystal has been fractured these shells continue round the fractured edge, showing that they have formed subsequently to the breaking of the original kernel. This kernel is frequently twinned and is greenish-yellow in colour. The anglec:¢ = 45°; this increases in other outer shells up to 55° in the outermost. Zoning is apparent in ordinary light, owing to the outer shell being of 4 decided yellow colour, but whether this is due to change in com- position or merely to staining is not clear, though the former is probable, from the sharpness and uniformity of the coloured shell. One crystal differs from the majority in having a well marked shell with a greater angle of extinction than the kernel and out side this a thin shell having the same extinction as the kernel. The olivine is all porphyritic, idiomorphic outlines being ¢om mon. All the crystals exhibit a curious structure. They at? traversed by a dense rectangular network composed of strings of magnetite grains which here and there show octahedral faces but are less regular than skeleton crystals. (Plate 13, fig. 4.) The main axes of these strings are apparently parallel to the axes, a, and 6, the shorter offsets being parallel to the vertical axis. The olivine matrix is perfectly colourless and fresh, show ing no decomposition and none of the usual irregular cracks. In NOTES ON ANTARCTIC ROCKS. 479 places there are thin films of what is probably micaceous hematite making the olivine a brilliant transparent red. In many of the crystals the enclosed iron oxides have been attached and converted into opaque red hematite, so that the whole crystal appears of an opaque red by reflected light. The | larger crystals of magnetite have suffered in the same way, and ’ the opaque red dust has spread over much of the ground-mass. Limburgite (No. 9). In the mass this rock is of a dark grey colour, compact with minute irregular cavities, and shows phenocrysts of augite and olivine. Sp. gr. 2-94 It has very much the appearance of an ordinary olivine basalt. On microscopic examination, however, felspar was found to be entirely absent. Porphyritic augjtes and olivines are abundant ; they are clear and fresh, and show crystal boundaries. These augites are yellowish to pinkish-brown in colour, generally zoned and frequently twinned. Then we have a large crop of much smaller augites with a few small olivines, and finally there is a base of fine granular augite and greyish to brown intersertal glass dusted over with granules of magnetite. (Plate 15, fig. 3.) The colour of the glass varies in patches; in places it seems almost entirely absent, and elsewhere we find it in brown angular petebes filling the spaces between the second generation of augites. This glass is perfectly isotropic, but contains a dust of dark particles, Throughout the mass there are little irregular cavities which would appear to be contraction rifts consequent on crystal- : tion. Into these the augites of the second generation project with very good crystal boundaries. These cavities are filled with a colourless isotropic mineral with a few needle-like inclusions. is most probably analcime. ‘Treated micro-chemically with HCl it is decomposed, yielding a good crop of NaCl crystals and gelatinous SiO,. The separated silica is richly stained by malakite green, 480 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. As to the nomenclature of this specimen, its mineralogical con- stitution practically entitles it to a place among the limburgites, though it is undoubtedly more stony in texture than is usual with these rocks. A partial analysis gave the following results :— SiO, = 38-447 Al,O, = 19°88 Fe,O, = 13°46 Some oxide of manganese is included with the alumina. This shows that the rock is ultrabasic in composition. The high per- centage of alumina is accounted for by the analcime which is present in considerable quantity. Limburgite, (No. 10). This rock is not unlike No. 9 in general appearance, but its texture is finer. Sp. gr. 2°91. Under the microscope it is seen to be a highly glassy rock, the glass being very free from crystallites and of a rich brownish yellow colour. Contained in the base are porphyritic augites and olivines, and a second generation of smaller augites similar to No. 9. Numerous small granules of magnetite are also present. (Plate 15, fig. 4). It is possible that this rock is but a more glassy portion of the mass from which No. 9 has come, and that this glass holds potentially the granular augitic base which is seen developed 12 the latter rock. A partial analysis, for comparison with No. 9, gave the follow: ing :— SiO, = 38-997 Al,O, = 11-72 Fe,O,; = 15:26 The percentage of alumina in this is much less than in No 9, and probably represents more accurately the common magia bd in this rock no analcime, so prevalent in the other, is observed: NOTES ON ANTARCTIC ROCKS. 481 Basic Tuff, (No. 8a, 8b). A hardened tuffaceous material, light-brown in colour, contain- ing numerous darker angular fragments. Under the microscope is seen to be composed of numerous irregular fragments of various basic volcanic glasses. These vary in colour from light to dark brown, and are all amygdaloidal, the vescicles being filled or partially filled with colourless isotropic material. Some of the lighter fragments are almost pumiceous in texture, while a few consist of almost compact dark brown glass. All the fragments contain minute lath-shaped felspars with a parallel arrangement in each piece, while the more glassy ones contain trichites in addition. The matrix is comminuted material of the same nature as the fragments, and contains a wie tas, , angular pieces of felspar. No. 8¢ is very similar to the foregoing but is more porous, the vesicles being without amygdaloidal infillings. Nos. 12 and 15 are fragments of scoriaceous lavas, some of which approach pumice in character. They are probably of intermediate composition, but have not been examined in il Mica Schist, (No. 5.) A fine grained rock, consisting of quartz and dark brown mica, _ strongly marked schistose characters and easily fissile. In thin sections the rock appears to be made up principally of clear —— of quartz and flakes of biotite (Plate 14, fig. 4). The biotite forms about 20% of the whole mass and is perfectly fresh Bees strongly pleochroic. In addition to these constituents there ‘Sasmall amount of a white mica which appears to be muscovite. There are also numerous small but beautifully formed prisms of brown tourmaline as well as zircon, apatite, magnetite, some Pseudomorphs of pyrites in oxide of iron, and a few grains of a — Spinel, probably pleonaste. Some felspar is also present, and possibly a member of the scapolite group. Ee—Dec. 4, 1995, 482 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. The bulk analysis of the rock yielded the following results :— sid, ao =71-437% | Al,O, (P,0,). =11°03 Fe,O, ie =. 18] FeO hi = 2°56 MnO me “D2 CaO = 407 MgO see = 2°44 Na,O "ee = 2°10 K,O et oe 277 H,O (on ignition) = 1-44 100-17 Phosphoric acid, chlorine and fluorine aré present in small quantities. The percentage of lime is notably large and a partial analysis of the biotite was made to see whether it contained any lime. This yielded the following :— SiO, =37-707 Al,O, = 20-74 Fe,0, =19-03 MnO = 2:03 MgO = 8-06 The iron present as FeO was not determined. It was found to contain no lime. The above analysis shows that the mica, which has a decided bronze lustre, lies between biotite and lepidomelane in composition: It was also found to be uniaxial. The high percentage of Mn0 is noteworthy and probably accounts for all the manganese found in the bulk analysis of the rock. (We may mention incidently that all the specimens of these Antarctic rocks which have so fa been submitted to analysis contain appreciable quantities of manganese). Lime being therefore excluded from the mica it became — sary to search for it elsewhere. No trace of twinning, whi FOR coe PERE Ce ae ees A a ae URS aa tr ae Teer ; | | | = NOTES ON ANTARCTIC ROCKS. 483 would indicate a felspar, is to be found among the colourless granules; nevertheless some of them were found to be biaxial in convergent polarized light. Further, in the neighbourhood of joint planes, some of these granules are seen to be slightly decom- posed, indicating that they are silicates and not quartz. These silicates, from their resemblance to the quartz grains, when not decomposed, may be either felspars or scapolites or both. The fact that many of them are biaxial may reasonably be taken as indicating felspar, notwithstanding the absence of twinning, for the secondary felspars in schists are frequently untwinned and much resemble quartz in thin sections, The question then arises as to whether a member of the scapolite group is also present. To try and settle this, a prolonged separation of the mineral con- stituents was made. A few heavy minerals came down first, then the tourmaline; close on this came the dark mica, and immediately after it the muscovite. The bulk of the rock, which now .consisted of colourless grains only, remained. For a long time we tried to separate this into its different constituents but failed, as they all floated or sank together. It followed therefore that the quartz, felspar and other silicates, not only resembled each other under the microscope but were also of equal density. _ Separation by this method having failed, and the silicates being but slightly attacked by acids, the isolation and identification of a Scapolite (if present) is not feasible. Nevertheless certain general arguments render the presence of such a mineral very probable. In the first place a felspar with the sp. gr. of quartz would have & composition approaching that of oligoclase or andesine. In _ a felspar the proportion of CaO does not exceed that of Na,0, and if we assumed that all the Na,O was present in felspar, this would account for only 2:1% of CaO, leaving a balance of PTZ, unaccounted for. We are therefore in need of a silicate Which, under the microscope resembles quartz, has the same sp. gT- “8 quartz, and in which the amount of CaO, or the proportion of CaO to Na,0, is large. 484 'T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. Now certain members of the scapolite group are the only minerals with which we are acquainted which entirely satisfy the conditions, and on these grounds we think it highly probable that such a mineral is present. The question of the pre-metamorphic condition of a schist, such as the present one, is of great interest, but unfortunately little can be done towards its elucidation from mere hand specimens. One or two suggestions may, however, be made. From the bulk analysis this mica schist appears to have the composition of an acid igneous rock so far as its more stable constituents (SiO, and Al,0;) go. In other constituents there are important differences. For example, the amount of CaO and of Mg0O is largely in excess of, and the amount of alkalis falls far short of, that usual in acid igneous rocks. Now this diminution of the alkalis and increas? of the alkaline earths is suggestive of denudation and sedimenta- tion, and lends colour to the suggestion that this rock may be metamorphosed sediment. Again the numerous tourmalines present indicate, probably, thermal metamorphism under the influence of an highly heated acid rock from which boric acid and fluorine might be derived. (In the granulitic aplite No. 4, we have evidence of the presence of such an igneous mass—containing much tourmaline—in the district). One may therefore suggest with some probability that this mica-schist has been previously a sedimentary rock which has taken its present form under the influence of a neighbouring mass of highly heated acid magma. B,—Sprctmens From Posszession IsianD. Amygdaloidal Trachyte, (No. 9). Grey in colour with numerous irregular cavities, many of which are filled with yellowish and white materials. The texture uniform, giving in section a mass of small lath-shaped felspat which appear to be sanidine and oligoclase. Between these there is a fair amount of colourless glass containing magnetite and very minute grains of highly-refracting greenish material, probably Jy : “ NOTES ON ANTARCTIC ROCKS. 485 augite. The flow structure is distinct, and the cavities and amyg- daloids are irregularly elongated parallel to its direction. These amygdaloids consist of a very irregular layer of brownish doubly- refracting material which fuses easily and gelatinizes easily with HCl even in the cold, and is most probably natrolite. The portions inside this layer are generally filled with colourless sectors of material which exhibits faint anomalous double-retrac- tion, and may probably be analcime. In some of the larger ones the centre is occupied by calcite surrounded by analcime which is again surrounded irregularly by natrolite. The natrolite exists in minute fan-shaped aggregates. Augite Andesite, (No. 12). Rock brownish in colour, considerably decomposed and porous. Small red grains indicate oxidation of magnetite crystals, and the general brownish tone due to oxidation of magnetite dust. There is not much actual staining of other constituents. Under the microscope appears to be an andesite of fine texture. The base consists of felspar microlites, a great number of smaller prisms and grains of yellow augite and magnetite (mostly converted to reddish oxides), and a fair amount of granular inter- sertal glass, almost colourless ond containing highly refracting globulites. There are some porphyritic crystals of brownish augite the outer shells of which are of a strong yellow colour similar to that of the small augites in the base. This is probably due to oxidation of the FeO. There are some dark patches in the base, some with regular outlines, which may represent the debris of another constituent, possibly a hornblende. Basalt, (Nos. 1 and 2). These are specimens of a fine, dark, compact basalt, with a few porphyritic crystals of black augite. Sp. gr. 2°82, 2°86. In section, flow structure is apparent from the parallel arrange ment of the sniall lath-shaped felspars, The texture is micro- “rystalline with a certain amount of intersertal glass of a brownish 486 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. colour. Numerous small brownish-red olivines are present as well as minute crystals and grains of a pale augite, and much magnetite dust, The glass contains numerous globulites and microlites, but nothing of special interest. Basalt, (Nos. 3 and 7.) These specimens seem identical, save that No. 3 is slightly vesicular, while No. 7 is fairly compact. Colour greyish-black. Base glassy with patches of finely granular augite. Small lath- shaped felspars abundant, also small brownish-red olivines. Por- phyritic constituents scanty, consisting of one or two rich brown hornblendes surrounded by a considerable resorption layer of opacite granules mixed with granules of augitic material ; and a few fair sized grains of a greenish augite. These specimens beat a strong resemblance to Nos. 1 and 2 in mineralogical constitution. Basalt, (No. 5.) Fine in texture with glassy base containing magnetite, minute pale augite, felspar microliths, and some small olivines decompo> ing into brownish-yellow serpentine. The usual small lath-shaped felspars are present ; some porphyritic grains of pale augite, and some pseudomorphs of hornblende in opacite and augite granules. One of these represents a large crystal of hornblende, and some of the original mineral remains. This is clear and fresh, and shows a greenish-yellow to brown pleochrism (Plate 15; fig. 1). Near the centre of the pseudomorph a large patch of the rock base isincluded. The constitution of this pseudomorph is peculiar. There is an outer zone of opacite, and almost colourless augite granules preserving the idiomorphic outline of the original horn- blende. Inside this there is a zone of varying width formed of fucoid-like growths standing at right-angles to the sides. are dark brown in colour, translucent, and slightly pleochroie ()) and apparently traversed by strings of opacite granules. be probable that they consist of thin leaves of a brown oxide of ir0s Basalt, (No. 6). : Fine in texture, with glassy base nearly colourless and contall: ing numerous globulites and grains of highly refracting materi : . j NOTES ON ANTARCTIC ROCKS. 487 which is probably augite. Also magnetite dust, a large crop of lath-shaped felspar microlites and many small brownish-red olivines. Porphyritic constituents absent. There is, however, in one of the sections a crystal of zoisite, about 0°75 mm. long by 05 mm. broad (Plate 15, fig. 2). This is perfectly colourless and conspicuous by its very low double-refraction, high index of refraction, and rhombic characters. The sectién is six-sided, show- ing two prism faces and four pyramid faces. The cleavage parallel to 010 is well shown and a series of somewhat curved parting planes at right angles to the vertical axis. In this particular section the greater elasticity is parallel to the axis c. There are some smaller sections of this mineral giving rhombic and trapezoidal outlines. Basalt, (No. 8). This rock in the mass presents a curious foliated appearance. It seems to be made up of little irregular ovoid lumps, about 5 mm. by 2 to 3 mms., together with less regular fragments into which it easily breaks up. The ovoid pieces all lie with their longer axes parallel and a face at right angles to these axes was polished. It was then seen that the ovoid lumps gave rise to dull round spots fairly regularly distributed over this surface. They are of softer material than the portions surrounding them, and form centres from which irregular cracks radiate out through the sur- rounding layers (Plate 13, fig. 8). “y would thus appear that the rock has split up into a number of irregular ovoid lumps, the longer axes of which are all parallel, that most of these have a kernel of softer material the outer evelope being traversed by irregular radial cracks. We have not “een anything exactly like this structure before, and no definite *xplanation has up to the present suggested itself. Doubtless Contraction on cooling together with lateral pressures and subse- quent percolation of waters along the cracks to the kernels have ® their share in its formation. In thin sections the slice splits - into a number of rounded and polygonal pieces, but no dis- Unction is observable between those forming the kernels and those 488 T, W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. forming the surrounding shells. The rock isa fine grained basalt composed of a felted mass of felspar microlites with minute grains of greenish augite, magnetite, and brownish-red olivines. The presence of any glassy material is doubtful. The texture is very fine and quite uniform, no phenocrysts having been met with. All the basalts described so far bear a striking resemblance to each other, both in general characters and in mineralogical con- stitution. Their differences consist in the varying amount of glassy base and slight changes of texture, some having a few por- phyritic constituents, and some being vesicular. _ The small brownish-red grains of olivine form a peculiar feature common to all. Were it not for these olivines, the general characters of these lavas, and the fact that most of the felspars indicate a composition not lower in the series than labradorite, would suggest that they should be placed among the basaltic andesites. On the other hand the olivine is not present in suffici- ent quantity to make them olivine-basalts. In the absence of chemical analysis their exact classification is not ascertainable, and we have therefore left them with the somewhat indefinite designation of basalt. Olivine Basalt, (No. 10). A dark scoriaceous rock with numerous large olivines and black crystals of augite. Under the microscope the ground-mass is fine in texture, containing a number of very minute lath-shaped felspars. With higher magnifying power the base is seen t0 be glassy, slightly greenish-brown in colour, with numerous globulites and highly refracting grains. Intermediate in size between these and the felspars are numerous grains of pale brown augite, and also of brownish-yellow olivine. These olivines have a granulat appearance. There are also many small magnetite grains. Coming next to the porphyritic minerals we have :—Larp? crystals of magnetite. Large rounded grains of olivine, which are colourless but turning to a brownish-yellow along the crac™ Finally, very large crystals of augite. These have idiomorphi¢ j NOTES ON ANTARCTIC ROCKS. . 489 contours, are frequently simply twinned and slightly pleochroic. The colour varies from a greenish-brown to a violet-brown in different crystals and frequently in the same crystal. Sometimes this change of colour takes the form of zoning, the kernels being greenish and the outer shell violet, and sometimes the two colours seem irregularly intergrown. There are also a few corroded remnants of a brown hornblende. The original hornblende crystals are in several instances repre- sented by remarkable pseudomorphs, similar in many points to those described in Basalt No. 5. There are, however, some features present in these which render a separate description desirable. The ground-mass of these pseudomorphs consists @f granules of almost colourless augite. These granules have in their interstices or intergrown with them little specks of colourless isotropic material, numerous elongated and branching parones of dark brown to opaque material similar to the fucoid-like in- clusions described in No. 5, and finally many prismatic and granular pieces of brownish-yellow olivine similar to those in the base of the rock. A small piece of the original brown horn- blende may or may not remain in the centre. The augite framework, which appears to be in irregular granules owing to the number of these inclusions in it, is in reality optically continuous. In one case it is twinned, one half of the pseudo- morph extinguishing at a different angle from the other. As = hornblende remains, it cannot be ascertained whether this twin- ning occured in the original mineral. Further, it appears from ‘wo of the pseudomorphs that this secondary augite has its plane of symmetry coincident with that of the hornblende. In one of these (Plate 13, fig. 5) which appears to be a section parallel to 010, the hornblende extinguishes at an angle of 16° with 508 *ertical axis (shown by the prismatic cleavage), while the augite extinguishes at 43° on the opposide of the vertical axis. In the other case (Plate 13, fig. 6) we have a section approximately - right angles to the vertical axis as shown by the shapely defined 490 T. W. E. DAVID, W. F. SMEETH, AND J. A. SCHOFIELD. prismatic cleavages of the hornblende, and here the hornblende and augite extinguish simultaneously. The dark brown to opaque inclusions do not occur in the original hornblende, but are confined to the surrounding altered portion. They do not appear to have any very definite arrange- ment, irregularly elongated and platy forms being common. On the edges, and when in thin films, they are translucent and of a dark brown colour. Associated with these are prisms and irregular patches of brownish-yellow olivine ; and in some cases a layer of this olivine appears to fringe some of the brown inclusions, and one material seems even to pass gradually into the other (Plate 13 fig. 7.) It is a suggestion perhaps worth making that this dark material is silicate of iron allied to ilvaite, which would resemble a fayalite in which some of the iron was peroxidised. The trans- ition from this to a ferrugineous olivine, or vice versa, is easily conceivable. Nos. 11 and 13 are: fragments of basic scorie, varying from black to red in colour. Some are very highly vesicular and may be intermediate in composition. No. 11 is more compact and most of the vesicles are lined with zeolitic material. SUMMARY. The collections submitted to us by Mr. Borchgrevink, in addi- tion to proving the existence in Victoria Land of a group of trachyte lavas containing soda-augites, and other interesting rocks such as the ultra-basic limburgites and the mica-schist already described, appear to us to strongly confirm the conclusion already arrived at by Dr. Murray and several eminent biologists a8 the existence within the Antarctic Circle of an Antarctic Con tinent rather than an Antarctic Archipelago. The schistose and granitic rocks collected by him at Cape Adare are distinctly of continental origin, and imply a strong probability of the com tinuity of Victoria Land with Adélie Land. In speaking of Mr. Borchgrevink’s work we can but echo the sentiments already expressed by Dr. Murray, that it is imposs NOTES ON ANTARCTIC ROCKS. 491 to overestimate its importance as bearing on the whole subject of the geography and geology of Antarctica ; and we here desire to express to him our warmest thanks for his courtesy in allowing us the privilege of examining and describing his collections. Our thanks are also due, for help kindly given us when preparing material for this paper, to the following : .—_Mr. H. 8S. W. Crummer, the Hon. Treasurer of the New South Wales Branch of the Royal Geographical Society of Australia; Mr. E. F. Pittman, Assoc. B.S.M., the Government Geologist ; Mr. G. W. Card, Assoc. R.S.M., Miner. alogist ; Mr. W. S. Dun, Assistant Paleontologist and Librarian to the Geological Survey of N. S. Wales; and to the following geological students of the University of Sydney: :—Miss Montefiore, Miss Flavelle, Miss Haslam, Miss Noakes, Mr. H. J. 8. Brook, and Mr. Graham Officer, B.Sc. EXPLANATION OF PLATES. PLATE XIII. Fig.1. Triply-twinned grain of felspar showing Carlsbad, Mannebach and Albite types. Two of the sectors are shown extinguis Fig. 2a. Basal section of topaz, showing usual position of a axes, the sign being positive. Fig. 2b. Section of topaz, in Granulitic Aplite, A. No. 4, showing position of optic axes, the sign being negative. Fig.3. Prisms of rutile and anatase from Granulitic Aplite, A. No. 4, Fig. 4. Crystal of aiden from Olivine Basalt, A. No. 7, with inter- 8town meshwork of magne Figs. 5,6. Pseudomorphs of hornblende composed of granular augite, colourless isotropic material, brownish-yellow olivines, and dark none a inclusions. These latter may be oxides of iron or possibly 4 ate allied to ilvaite. Some of the hornblende remains in ¢ ach. The augite granules are optically continuous and have the plane of try and vertical axis coincident with those of the horblende. a. 7. A portion of Fig. 6 enlarged; the dotted grains represent Fig. 8. Polished surface of basalt B. No. 8, at right angles to axes of nitrate i i ne softer kernels of these lumps represe ented by lighter Repeats which irregular cracks radiate through the surrounding 492 HUGH CHARLES KIDDLE. PLATE XIV. Fig. 1. Trachyte A. No. 1 and 2, composed principally of sanidine and egirine. A porphyritic crystal of egirine is shown X 30 . Olivine Basalt A. No. 3a, 3b, showing, near the centre, an arborescent grain of magnetite X 45. Fig. 3. Basaltic Andesite A. No. 6, sein a large brown hornblende surrounded by a layer of opacite granule Fig. 4. Mica Schist A. No. 5, section at ite angles to plane of foliation X 30 PLATE XV. e Fig. 1. Basalt B. No. 5, with large pseudomorph of hornblende. On the left of the centre a patch of the original mineral is seen X 20. Fig. 2. Basalt B. No. 6, showing crystal of zoisite X 20. Fig. 3. Limburgite A. No.9, showing miarolitic structure, the cavities Heise filled with analcime. The dotted crystals are olivin lass | is in dark brown angular patches or filled with fine granular augite X 30. | Fig. 4. Limburgite, A. No. 10, glassy base without rs fine granular augite of No. 9. This is studded with a second generation of small 3 ; B augites anda few olivines. Two large porphyritic aia are shown X 30. Notes on tae RAINFALL or tue SOUTHERN RIVERINA 1872 ro 1894. By Hueu Cuarues Kipp ie, F-R. Met. Soc. : [Read before the Royal Society of N. 8. Wales, December 4, 1895.] In order to carry out an investigation of the rainfall of a larg? tract of territory, two essential conditions must be complied with, firstly, there must be a number of willing observers, well cad tributed throughout the district, and secondly, some one to under- take the task of collecting and digesting the records thus made ‘: available. I have undertaken the task of doing this for souther® ' Riverina, and in the pages which follow I have endeavo RAINFALL OF SOUTHERN RIVERINA. 493 make this an exhaustive enquiry into the rainfall of the district lying between the Murray and the Murrumbidgee. Out of one hundred and twenty-five stations herein discussed, the Government Astronomer has furnished me with the particulars of seventy-three stations; for the remaining fifty-two I am indebted to the proprietors of these stations who very kindly responded to my request for copies of their records. I.—Area under consideration. II.—Divisions. III.—Tables. IV.—Summary. (I.) The district which, for the purpose of this paper, is termed the Southern Riverina, embraces all the area between the Murray and Murrumbidgee Rivers, and extending as far east as the meridian of 147° 30’. The locality to the eastward of that Meridian is termed the western slopes of the southern table- land. The records of the town of Aibury, situated in the extreme south-east of this area, have been omitted. The reason for doing this is that the township is surrounded by hills, a fact, which, in My opinion, considerably affects the rainfall. I mention this to show that only stations which may be said to belong to the Southern Riverina have been selected, and that the results are not simply a large collection of statistics irrespective of locality. As Albury has a very long and valuable rainfall record, you might be sure that there was a valid reason for omitting it. The area of the district is approximately 19,700 square miles, or embracing about twelve and a half millions of acres of the finest wool and wheat growing lands of New South Wales. ‘he length is about two hundred and thirty miles, and average width about eighty- ind miles. The surface may be characterised as a generally sloping plain falling from east to west. The ‘altitudes on the eastern side are given thus for Wagga Wagga 615 feet, Albury 530 feet, the level at Deniliquin is 320 feet, while at Balranald about 230 feet, being a fall of about two feet per mile for the first mterval and one foot per mile for the second, 494 HUGH CHARLES KIDDLE. (II.) Divisions.—The area has been divided into four sections, the dividing lines being the meridians of longitude. They are designated— ' Section. From. To. Junction ooh Sat Sneeey | ° A snd) Marrombiagee | 145° E. B 146° E. Cc 146° ‘ 147° E. D 147° E. 147° 30’ E. This method of division was selected as it was found to be more workable than taking the square degree or other arbitrary anit, and it also conformed to the geographical nature of the district. The first three sections are essentially part of the Southern Riverina, but Section D encroaches somewhat on the southern tableland. For this reason only those stations situated on the northern, central, and western sides were used for the purpose of computing the Table No. 4. (III.) The Tables numbered 1, 2, 3, 4, have been compiled for each year by taking the sum of the available rain records for each month in that year and dividing by the number of stations. I may say that the stations are well distributed throughout each section, so that the average for each year, although the result of a constantly increasing number of stations, is a very true one. One pleasing feature is the large number of stations represent ing Section A. I have obtained twenty-nine records for 1893 for this section. In all sections where there are two or more reports from the same place, either only one of them, or else the averag® of the two has been counted in the mean. For instance Wagg* Wagga has two records, both dating from 1873. In such a casé I take the mean of the two records and call it one station. The reason is obvious, for the results would otherwise probably be misleading. Table (1) gives monthly and annual results for all stations 1? Section A. Table (2) same for Section B. Table (3) same for Section C. Table (4) same for Section D. aero ae RAINFALL OF SOUTHERN RIVERINA. 495 Taste I.—Results of Monthly and Annual Rainfall, 1872 to 1894, for Section A.—Balranald to Long. 145° E. : No. ; | Soe: Sie Jan. | Feb.| Mar.|April| May | June} July| Aug.|Sept = jer er 1872| 31°37) -07 50) 43) -92 4-05 1°31 {1-241 Bees, Pe PPS Pea i . 1873| 3 |5:01|3-16| -10 2-29|1-40 1-29| -82|2-69|1-92| “88 -88| -65 nee (1874 8 |884) — 4°81 1-83 )1-36/1-67| -63) “51 229 ‘50| °81| +12| 1637 wi 4 | -16|2°04| -78/1-71 |2°97 3°13 |1°20|2°44.|1°01 |1°81| °57/1°37 | 19°19 6) 5 | 65| °51|1°68| -16|2-91| -16| -10|2-07 |1-01 |1°31/3-77) °22| 14°55 isa 9 | 501-05 |2°35| -46 [1°85 1-21) -68| “12 /2°62| -63| “85) -37| 12°14 —— {3878 ) 11.) — j4-58|5-96|1-83) -25/ -99 2-42) -44) -61|1-77) -67| — | 18-47 1880 | 14 al bide 72 |1-32 1°29) -80|1:04.|1°61 |1°29 |2°81 |1°60| -60) 13° send mal 61 |2-36 |1-48 2-87 “48 | ‘76| °2 1-41| °59| *38 12°10 sr nd he 1:96 | -23 |2-05/1-61| -40/1°18 [1°57| °73) °75) 45 13°71 | aaa ge "02 | -02| -09 2-83 |1-00/ -88 |1-04|1°79 (0-29 2-29 2-46) -97 13°68 Tee | oo | OE] (8641-67 | -73/1°77 |1-20| 58 |1-42 180/131) °87) “30 12°27 | 1885 ped “B1) °28 1-15] -49'1-74 1-46] 04] “53 1 73/1°34| -21) 9°34 amal 3 he 1-82| -82|1°73| -59'1:41| -92| -74|2°32| -68) *17|2°08 | 13°63 1887 | 24 39) “06 -25| -08 1:09 | “68 {1°73 |2°86 1-63 |L-11| °57/2°57 | 14°02 of | (28 [2-88 [1-47 [2-21 [1-09 2°68 [1-61 1°36 -95/|1:95 '419 1-88 21°98 1889 | 96 Ph 62} “32 -41|1:77) -59| “4 ‘54| -98| -22| -26| *76| 7°3 ~ - 2:95| — [3-73 4°12 2-11] 27 3:02 1-71 |1°39 1°99) -06 | 23°51 vet a To 33 |2°89| -76 |218 2°69 |2-62/1-46 | -59/1-75/1°58| *71 17°61 rn ed *80| -88 1-77 |1-52/1:99 | -65 |1°72| 29 16°89 1893 | 39 ost "20 | -23| -66 2°86| *79 [1-45 |1°72 |1°45 |3°08 |136| 25 14°18 1894| 96 a UL | 52] -90|8-24/1-38] -99/1-23 1-49 °78|1°89) “40 12°88 eka! of | oe ag 2°72 |1-45 8 (290 1:31|1'95 | “88 352 “35 4°32) 21-21 oii 20 hd Re OE LO ee es la Tr ee —— ABLE se Results of Monthly and Annual Rainfall, 1872 to 1894, for ae ection B.—Longitude 145° E. to Longitude 146° E. Year. (2.041 | ; ear bl ag Mar.|April thes Liao July | Aug.|Sept Oct. | Nov.| Dec. Total. 1872| 3 | — I 3 \. 24 | = "52 |1°63 [4-71 |1-46 |1-44 |1°75 [2°81 3°32 58) 19°15 187 2a) “ogi ees - L|1°30| -50|2°27|1:56) -72 79 | 56) 19°55 ne ara “47 |1°71|1-95 ‘87 |2°31| *38) 02) 04) 15°04 1876! bn 3-16 | 61 |1°70|3-07 |4°73 |2-02/ 2°56 |1-30 |1-27) *95 148) 23°25 1877; § | os} 29 1-49] “02 |2'86| -25] -22/1'81| “87| 60/908 “37/126 1878 | vr aed 81| -23/1-67/1-67| -97| -23|2°83| -40| *56/ “57, 11-24 ae ab ab Cay 3 bat 20 Ego ven eaear os 416 880 3 ‘97| °76|1°56 \1°56 |1°46 |2°87 1°66, *47| 1881 14 | -33 ob 1:95 |4-14 |1-06|1-06| °58| °57 173 92| -21) -28, 15°15 8821 17 | tel ne ree 1 |t 92|1°74| “45/106 [1-45 ) 84/005 “56 15°66 |1883' 17 | .o9 8 | ‘10 3:12 /1°59| -88| -98|2°33| *24 |2°78|2°07 |L32 15°60 |194) 1g | 02201 1-15 | -62 [1-96 j1-56| “68 |1-49 [1-64 [1-92 94) -26 13°25 11885! 17 |yree | 22/108 [Laz Lar 2-26) -24 [1-13 1-08 [1-56 [1°37 | 50) 12°64 '1886 19 |}-45 13)" °62/2-78 | -61/1-59| *81| “60 /2°6 11°35 | °27/1-76| 15°80 1887 99 | go lat |g:3t| 15) 89 -87|1-48 [3:36 |1-50|1°39 65236 14°62 1888 99 | 2928.25 8:48 1-63 1-65 (2-45 [1-79 |1-63 1-06 2°31 8.88 219 26°01 11889 21 [psp |ped| 28) 362-44) -62) +52) -63)1:1 3 +29) -50|1-04) 9°61 1890 22 | -95 sd Ol 3°67 5°15 3:06| 39 |3°68/1-95 1°62 1°88) 25 27°31 ‘1891 29 3.97 ‘32 2°71 [1041-95 3°27 [2-51 [1-35 |1-09 1-70 1°45) -72| 18°16 (1892 24 |'.gq) 02/202 8°57 |1°17 '2°68 [2°59 |1°80 [1-25 [1°38 1°28 36 21°46 | (1898 26 | -o4| 95) 0788297 | “92 2641-48 3-36 1°86) -28) 16°78 (A804 9g | “Be| “08! 92 |2-20 [3-40 1-70 1-02 |1-531-76 14 175) °78) 15°36 Mean of | 99 | 48 /3°42 2:80 1-89 [3-70 [1821-78 | “88 3°71 “31 |2°83 | 23°80 er ie Pas [ae ee ee 496 HUGH CHARLES KIDDLE. Taste III. Eom of Monthly and ees — via to sai tude Section C.—Longitude 146° E. t 147° E eas be dan ae Mar.|April) May | June| July i Aug.|Sept | oct tion: | | 1872} 2 1:00 -86/1-20| -12/3°36 6°10 |2°53 | -82 1°70 4°35 1873| 2 |382 2°80) -05|2-27| -91/3°10| -42 |2-48|1-:12) -73 1874| 2 2-42) — |4-25| -80/3°09 2-00 |1-06 |1-45 |2°75 | *48 1875| 3 °10 3°76 |1°43 |2°81 3°64 /4°41 |2-01 |3-13 |1°39 /1°53 |1 1876| 5 | -08) -65/1°35| -07 3°18) 36) *10/1-76 |1-54/1°37 |2° 1877| 6 | °77| -97|1:03| 59 |1°88 |2°20 |1-05 | 27 12-84 1°16 1878|. 6 | — [3-99 |4°19|1°84| - 91 2°69 -99 |3-08 |3°63 1879| 8 | ‘47 /1°71|1°38 |2°59/1°53| °81 2°18 1-86 |1-68 3°40 880| 12 | °75 1:80 2°12 4-67 |1°48|1-58| +45) 741-77 1:54 1881| 13 | -43 2°33 3°85| -83 2°05 /1-77| -48 1°15 |1-40 |1-05 1882 | 18 | “82, -17| -37/3-49|2°39| -78|1-16|2-69| -28 3°67 1883 | 21 | -01 1:06 1°57) -79/1-65|1-91|1-10 1°55 1°58 |2°84 1884| 26 | -35| -54/1-08| -73|1°48|1°57| -10| -65| -98] °99 1885 | 32 |2:26/1-64) -57 1-67) °70|2°20) -59) -90 3:17/1-34 1886 | 36 14d ‘30 84 40 “921-02 |1-74 |4-03 1-76 |2 1 41 | ‘94 4°12 4-27 1:26 1°80 3°03 |2°64 1°74 1-202 1888| 43 |1:10 219) -23 -30 2°62| -96/1-:02 -86/1-00| - 1889 | 44 |2°49/2-95| -02 2°79 5°77 3° 82 3°33 2°31|1 1890 | 44 | -09|1-36 2°74 1-04 2°58 3-04 2-45 1-42 1-65 2 43 \4-40 ‘11/197 3 6\1 2 6 11:58 |1°34.|1° 1892 | 43 (1°54) -22| -19/1-71 2°55 |1 78 |3°05 |1-97 |2° — 1°66 1-84 4°19 |2-08 |1°68 |1-98 |2°31 |1:87 ees bP Ea 23 eae io dee TaBLe LV.—Results of ‘Meuieie and Annual Rainfall, hg ie 1994, for Section D.—Lo ngitude 147° E. to.Long tude 147° as and Jan.| Feb.) Mar.| Ay al ae J June July | Aug./Sept.} Oct. Noy. tions. | 1872| 1 |1-66{1:53 |2:87| -02|2-94 |6-62 1-81 |1-71 2-09 |3°51 [3°17 873| 1 |8-18/1-27| — |2°65| -77|3-54 1-12 |1°54/1°70 |1°09 |2°73 1874} 1 |4°10| -55 4°88 |2-75 |2-39 3-05 3-10 |2°85 |3°80 |1°65 | “15 1875| 1 |1:22/3-20| -57|3-20|3-20 3°86 1-44 |1°93 1°76 |1°68 2°05 1876) 2 | -27| -$9|1-52' — |3-62| -55| -79|/2-45 |1-38 |1°35 [2°83 1877) 2 1:04) -57 |1-37|1-68 |2°55 3°05 /1-01| -55 2°80 1°33 “45 1878| 2 | -03|3°81|3°33/1:84)| -35 3-00 3-02 1-07 2°54 |4-02 2°21 1879) 3 | -60/1:87|2-45 2°77 2°71 |1-05 2°54 2-48 [2-64 |2°33 2°75 1880| 2 | -82|2-26 |1-77 4-00 |1°54 {1°81 | -69|1-04|1-04 2°11) “41 1881| 3 | -40/2-43 |2-91| -55|2°55/2°60 -73|1-16|1-46 |1-43 1°65 1882] 4 | -70| -63| -83 3°65 |2-94 1°51 1-77 |3°71| °50 |3°38 3°32) 1883} 5 | -05)1:41|1-98 76 |1-63 |1-78 |1-39 |1-67 |2-28 |3°81 1-41 1884| 7 | 45) -49/1-29'1-52|1-13 3-64 46 (1°12 |2°00 1°52 1885| 9 3°59 /2°60| -44 1-:08| -69'2-98| -56|1-18 3°12 |1°43 |1°53 1886} 11 1:43) 52) -47| -61|1-21 1-01 2°08 |4-94 2°25 |3°89 |1°63 2° 1887) 11 1:26 4°58 5°39 59 1:44 3°77 3°33 |2-05 |1°56 |2°90 |6 0}: 1888 | 12 | -92/2°85| 52) +15|2-13/1-72/1-70| °72/1°48| °33| “71 1889 | 12 2°70 /2°72| — 2-78 16-09 4°48 1-23 |3°39 2°62 |2°21 |3°38 |l 1890| 14 -21 2°17 3°55 1-27 |2-96 |3-83 2°12 |1°77 |2°23 |2°55 |2°05 2" 1891 | 15 5:80) -14|1-85 3-01 |1-22 14-62 5-20|1-77 1°66 |1°68 2°89 1892) 15 2:08; -28 78 2-05 |2-79 |1 2-09 3°88 2°48 |2°48 [3°14 Saal i4 as way [et 200 [8:92 [9°72 [2:64 [2-28 2°50 [2-51 a Mean! of | 23 lvear's... |. 4, ng ies 3°14./1°88 |4 vie pas 2 RAINFALL OF SOUTHERN RIVERINA. 497* (IV.) Summary.—In dealing with a subject so uncertain as rainfall, the most important feature to be discovered is its periodicity. In fact I think that this is the only point of impor- tance in connection therewith. The question of periodicity has been dealt with by many writers, and the number of different theories advanced is somewhat per- plexing. There are periods of three, five, eleven, nineteen and thirty-three years ; all of these have their supporters. In many instances an agreement exists between one of these periods and the figures representing the rainfall, and this agreement is im- mediately set forth as a positive theory. As it is orthodox to assume that rainfall is governed by certain laws, more or less proven, argument on the matter is out of place in these notes. Suffice it to say that I do not consider that the records of twenty- three years which I have now set before you, show definitely any periodicity, for the simple reason that T do not think the observa- tions cover a sufficiently long series of years to actually prove anything. I beg to draw your attention though to the fact that the amounts of the annual totals coincide closely and conform to the period set down as a nineteen year cycle. By taking the monthly values I find that the period shows eighteen years two months. For instance, the dry period commencing in October 1874, and lasting for four months is repeated in December 1892, when a dry period of three months set in. The annual results agreeably conform to the nineteen year cyele as shown by the following examples :—1875, 1894, and the three years immediately preceding these years respectively. These oe what may be called all good years or years of a plentiful rainfall, Unfortunately our series for this district does not give us an opportunity of comparing the recurrence of the dry years. viegne Tam correct in stating that the nineteen year period Fig = our Government Astronomer Mr. H. C. Russell, mention this to show the excellence of the authority i quote when applying the cycle to this discussion. Fr—Deec. 4, 1995. 498 HUGH CHARLES KIDDLE. The periodicity may therefore be summed up as indicative ofa recurrence of similar seasons at intervals of about eighteen or nineteen years. Taken alone this knowledge may prove of much service to both the pastoralist and the agriculturalist, and if so, one of the objects aimed at will have been accomplished. But apart from the knowledge of the periodicity, these tables afford the means of working out the relationship between the amount of rainfall and the resulting crops. This may be effected by com paring the amount registered in any particular season, that is from ploughing time to harvest of any particular year, with the recorded average yield per acre of the crop under consideration. For instance bushels per acre would be assumed in discussing wheat crops, tons per acre if vines. The tables are particularly useful in this respect, as by dividing the period the crop is in the ground into sections, the most bene- ficial amount of rainfall and opportune season for‘it to fall may be discovered. A wheat crop for instance, may be divided into (1) ploughing and sowing period, (2) growing period and, (3) ripening period. The fact that the same annual amount of rail- fall will not necessarily produce the same result in the crops in any two years is so apparent as to need no enlargement thereon In conclusion I may say that although the period of twenty- three years is short from a meteorological point of view, the results deduced therefrom will I hope be found not altogether unworthy of notice. At some future period I hope to be in a position to place before you not only the rainfall results of this district, but results of the investigation of rainfall, pressure, temperature, winds, et¢., CO bined, and not only for this district but also for any other i2 which it may be my lot to reside. Finally, before I close my remarks, I must take the opportunity of thanking all those gentlemen who have supplied me with coples of their records; without their assistance this paper could not have been produced. I must also thank the Government Astronomeh . THE GREAT METEOR OF MAY 772, 1895. 499 Mr. H. C. Russell, F.x.s., for his kindness in supplying nearly two-thirds of the data to me, more especially for the year 1894, for by his kind assistance in that’ direction I have been enabled to bring the subject matter up to date, and thus render it more interesting, and I hope useful. THE GREAT METEOR OF MAY 71, 1895. By H. C. Russetu, B.A., C.M.G. F.R.S. [Read before the Royal Society of N. S. Wales, July 3, 1895.] From time to time we get reports of earthquakes on the western plains, and various circumstances connected with them convinced me that they, or at least some of them, result from meteoric explosions, and I have at last obtained what seems to me to be clear and definite proof that what was accepted by a large number of persons as an earthquake, was simply a vibration in the earth, caused by a terrific explosion overhead. Some of the observers, indeed describe it as like the explosion of a magazine. Sturt was ence startled at 3 o’clock in the day (Feb. 7, 1829) when on the Parling, by a great explosion “like the discharge of a heavy iri of ordnance five or six miles away,” and in the early days, 1789 (17 Jan.), all Sydney was agitated by what was supposed to be the explosion of a gun outside the heads, and everyone who could get a horse or a gig went off to South Head with all speed, to see the ship, looked for. but no ship was in sight, anxiously as she was | The source of the great explosion this year was fortunately — ny a great number of persons under conditions which ary point to the explosion of a meteor as the cause of the oe and the earthquake. The first intimation I received of it Bones telegran from Mr. Thomas Cadell, who happened to be at 500 H. C. RUSSELL. Bedooba Station, some sixty miles south of Cobar, and while sitting at a table reading, distinctly heard the glasses rattle together as a rumbling noise passed the house. Many others in Nymagee and Gilgunnia had a similar experience. Later Mr. Cadell got reports from the Cobar mailman that at the time he had seen a great meteor pass over, and from Mr. Edgar who was startled out of his sleep by the noise, and thought he saw the moon falling; these reports pointed clearly to the cause of the earthquake, and I wrote to the daily papers asking for informa- tion. Thanks to many correspondents to whom I am indebted for valuable reports, I have now been able to trace the meteor over this colony so well that I think it ought to be placed upon record. I have never before heard of such a magnificent meteor in Australia, and it is not often that any part of the world is visited by such a fine one. Unfortunately no one has referred its path to the stars; if they had, it would give us more exact inform- ation of its path in the heavens, and there are still some points to clear up which the publication of what follows may bring out, at least it will place upon record all that I have been able to learn of this truly magnificent meteor, and show that at its explosion 4 distinct tremor of the earth was experienced in the houses near. No. 1, Vyngan—Mr. C. Maclean reports to Mr. Edwin Lowe of Wilgar Downs, that he was camped at Nyngan with sheep, he was on watch about 11 p.m., when a gigantic meteor passed over head travelling about due south-west, the ball of fire was twice the size of the moon and had a long train after it, travelled slowly and was in sight for several minutes. At Wilgar Downs 4 brilliant light was seen by Mr. Lowe junior after he had retired, but at the time he did not know what it was. No. 2, Vymagee.—Mr. G. Robinson was on the night of May 7, on his way from Nymagee to Gilgunnia, at a point marked by a cross on the map. At the moment he was driving due west, “when suddenly and without any warning a dazzling patch of light about twenty feet in diameter appeared 0” the ground just to the right of the horses’ heads; the horses THE GREAT METEOR OF MAY 77h, 1895. 501 46 7. 48 : 14g 50 J COBARs vices THE CREAT METEOR e MERYULA MAY 771895 R a *specially if they show no appreciable forward motion for a day ortwo. When anticyclones move in low latitudes the con- — favour dry weather, in high latitudes, wet weather, specially it they rest for a time south of South Australia. aang examples of weather phases which follow have been rom the Sydney Weather Charts, and illustrate each Bs : a originals were carefully traced, and then reduced from ‘‘ to the size used in this essay by means of the camera. GG—Dec, 4, 1895, 514 HENRY A. HUNT. Ordinary symbols have been used, except the circle half filled for thunderstorms, and the straight line shading ; parallel lines indicate the area of rainfall under one inch, crossed shading over one inch, TYPE I.—MOVING ANTICYCLONES. a One of the best marked features of Australian weather is the steady easterly progression of all the types, and the governing : type, that in fact about which all the other types seem to congre — gate, is the anticyclone ; it-has therefore been placed first in the series, with three charts to show the progress made by a quick moving one in forty-eight hours. The average daily progress of anticyclones is four hundred miles per day, but the speed at times - rises to one thousand miles.! Investigation so far leaves no room to doubt that in these lati : tudes a series of anticyclones surround the globe ; the latitude of the average one varies with the season, being farther south in summer than in winter. The normal circulation about an anti- cyclone brings southerly winds in front of them, and northerly winds in the rear, hence our cold and our hot winds. Chart No. 1 shows the position, on 15th August, 1893, of the eastern half of an incoming anticyclone; it rests over Western Australia, while the departing one is seen over the Tasman Sea; between these is seen the usual , depression, which is of average . intensity, and a dormant tropical low pressure to the north. IB : Chart No. 2 the anticyclone has moved nearly nine hundred miles : in the twenty-four hours, the centre being located near F owlers Bay, north of the Australian Bight; the antarctic A depressio® is well across the Tasman Sea, while the tropical or monst”™ isobar depicted in the previous chart has apparently merged nt the high pressure system, a curious and not unusual kink being formed to the north-east of it, following the contour of the Gulf of Carpentaria. On Chart No. 3 the anticyclone is shown © have moved a further seven hundred and fifty miles, or 4 total of 1 Russell—Quarterly Journal R. M. S., Vol. xrx., No. 85. TYPES OF AUSTRALIAN WEATHER. 515 TYPES oF AUSTRALIAN WEATHER dé ‘o AUQUEST. NBs... 5008 S Moving Antieyelones Ito 3 one ee eam) | comer TYPES : ‘ ot oF i bk fy MN 2a e AUSTRALIAN WEATHER, 4 ; ~~ j one thousand six hundred and fifty miles in forty-eight hours; ve | , | = monsoonal dip is still noticeable south of the Gulf, while i Saat depression has its centre to the east of New Zealand, 516 HENRY A. HUNT. TYPES ; | OF fs c AUSTRALIAN WEATHER 03 —AIGG SS *y The passage of this anticyclone was an unusually rapid one, and is presented as portraying with a minimum number of charts the easterly motion of anticyclones over Australia. TYPE Il.—MONSOONAL RAIN STORM. This type is undoubtedly the chief rain agent in the Australian Continent. Monsoonal depressions or tongues may occur at any time of the year, but particularly between the months of September and April, and most frequently during January, February and March. The readings of barometers in the depression seldom fall very low, the grade from the surrounding areas to the centre of the tongue ranging from one to three-tenths of an inch generally; the depression may intensify, that is the tongues between ig) A y protrude further south anywhere during their pass? across Australia, but show a preference to do so after they - crossed central Australia, a fact which suggests that the hea interior has at least some influence in‘their development. When and wherever the tongue is well defined, rain certainly follows in its track, and thunderstorms as a wide spread ‘simultaneous feature are never experienced without it. TYPES OF AUSTRALIAN WEATHER. 517 | On April 18th and 19th, 1894 (Chart Nos. 4 and 5) occurred one | of the finest monsoonal rain storms on record, the area affected being very extensive, embracing the whole of the eastern colonies, Tasmania, and the greater part of South Australia. Many inches —up to five and six—of rain were recorded on the north-east coast of Queensland, and over the eastern half of the rain area the country benefitted to the extent of over two inches generally before the storm was over. TYPES oP . u AUST ; ; No sonrnnah A2ELIB 00% 9 NR a ae Fo, ; p TN a dh ty tY 7 jo xi Y7| Yo, a ee we On this Chart No. 4 the monsoonal isobars, after passing the est southern part of the tongue, are shown sweeping round & high Pressure of considerable energy, situated over the Great Bight. Following these isobars to the eastward, we find them 7 — Over another high pressure of greater energy in the man Sea. On Chart No. 5, both anticyclones will be noticed to a Worked northward, and while so doing they have lost some on ae Pressure, and the low pressure tongue has extended a ° and broadened ; at the tip, two cyclonic rain centres will be ed to have formed, 8 antecedent to 18th April presented the general : mistics of Chart No. 1, except that the antarctic A depress- 518 HENRY A. HUNT. a ion was a considerably less active feature, but on the other hand the monsoonal dip was somewhat more pronounced, and possessed two instead of one isobar. Following the 19th, the chart of 20th revealed no sign of the monsoonal tongue, and the continent was covered with a high pressure of very slight energy. TYPES oF AUSTRALIAN WEATHER 4 vy bin APRIL... 1804 vy NY at ++ ims Fito Git St] Au, MAL Yak 1] TYPE Ill.—DEVELOPMENT OF A CYCLONIC STORM IN LOW LATITUDES FROM A MONSOONAL DEPRESSION. 2 In Type No. 3 we have the development of a cyclonic aie out of a monsoonal depression. The seasonal peculiarity of he phase of the tropical low pressure is similar to that in Type No- - , . The cyclone seems to develop when the southern extension of the monsoon is out of proportion to its width, and it become me narrow at one part of it that the opposing winds which circulate ie round it interfere, set up the cyclonic circulation, and it a | progresses eastward as a rain storm. (See Charts 6 and 7.) These storms frequently develop in South-east Queenslansh and they are generally most severe there; the quantity of ee which sometimes comes with them is very remarkable, as in case of the phenomenal fiood in Brisbane in 1893, which wa - result of one of these storms. TYPES OF AUSTRALIAN WEATHER. 519 The example selected and shown in Charts 6 and 7 took place on September 28th and 29th, 1892; on the 28th (Chart 6), it appears that one of these storms had developed in the previous twenty-four hours, at the southern end of a narrow tropical or monsoonal tongue of low pressure. An anticyclone of good energy lies to the east of it, with its isobars extending well to the north and contracting the width of the tongue in the north; another anticyclone lies to the west, and this also seems to be pressing on the narrow monsoonal tongue and helping to contract its diameter, at the same time the energy in both high pressures is adding force to the circulation of the wind, and so aiding in the development of the cyclonic circulation. A modified , depression exists to the south-east of the Australian Bight, and there is another over New _ Zealand. TYPES or AUSTRALIAN WEATHER ° mpiaet: © 2, 169% Cae : aA oy a G bat Yelone from Monsoonal Se, . eee? tow Se, go ne 29th, (Chart 7), the small cyclone has extended ica nd energy on its way to the coast, but its motion of et heen rapid, and this probably accounts in a measure ~ comparatively small area over which rain has fallen, althou, gh, in this instance, over an inch of rain fell in the central 520 HENRY A. HUNT. and eastern parts of New South Wales. The winds circulating about the western isobars of this storm are rather stronger than usual in such cases. In the twenty-four hours both anticyclones have lost a considerable portion of their energy, while that of the : depression in New Zealand is about the same as on the previous day. ee ome A TYPES. : BF as ‘& oF 5 8 rm’ AUSTRALIAN WEATHER ¢ > \ N°7 rae SEPTEMBER 29.1892 “ae a NG Nj a 2 & © e TYPE IV.—DEVELOPMENT OF A CYCLONIC STORM IN HIGH LATITUDES FROM A MONSOONAL DEPRESSION. These are somewhat similar to Type 3, but the rainfall is usually not so heavy, and the wind much more violent. Chart No. 8 shows the development of one of these cyclones on April 15th, 1889; in this case the monsoonal depression had : extended across Australia into the Australian Bight. go development of one of these storms is heralded by the strong easterly gales on the south-east coast of South Australia and south coast of Victoria. The energy of wind circulation increases over South Australia, and as the whole system moves bodily @* ward from the Australian Bight to the mainland, the circulation * seen to be that of a fully developed cyclone of small area, wit fT Oe PLS = SA a MT ale PP ms aga MRE Mame Te TYPES OF AUSTRALIAN WEATHER. 521 diameter three to five hundred miles, formed out of the southern part of the extensive monsoonal depression. In Chart 8 a high pressure is shown over the south-western part of Australia, and evidently encroaching on the moonsoonal about central Australia. TYPES OF AUSTRALIAN WEATHER Nes vee yelp APRIL 15.1889 oN , = } ‘ \G p{CH | o) y 0 B we x Cyclone in high latitudes from uy » fi onsoonal depression & tol0 4 e 522 HENRY A. HUNT. In Chart 9, the western anticyclone has extended northwards and has seriously contracted the diameter of the monsoonal low pressure, thereby facilitating or helping to cut off and start the — cyclonic storm in the south ; which has now developed a much steeper barometric grade and an energetic wind circulation, and is moving eastward without extending the rain area. Chart No. 10 shows comparatively little motion in the cyclone, but it is considerably distorted, especially to the west, where the anticyclone is compressing the isobars by its easterly progress and in its endeavours to maintain its rate has overridden the cyclone in the north. As will be seen by a glance at these three charts, the rain resulting from this storm was most extensive and bene- ficial, and the winds under its influences were strong. z TYPES oF é. AUSTRALIAN WEATHER Nol = APRIL It. 160% TYPE V.—CONDITIONS FAVORABLE FOR THUNDERSTORMS. Upon comparison of charts setting forth this type with those of cyclonic thunderstorms, they will be found very similar } the main difference being the absence in this set of the cyclonic -_ at the end of the monsoonal tongue. The chief feature indicating £ Bs Se Sp ONE eh a tee Cer gg ec un Sree oh SPIO ks ee ee ERT Ey ay see eee TS sia Ban Best eek g s TYPES OF AUSTRALIAN WEATHER. 523 thunderstorms is the narrowness of the col’ and somewhat con- gested state of isobars in the high pressures west and east of it, resulting in opposing winds. Those of the tropical tongues are hot and charged with moisture, while those of the 4 depressions are strong and dry. This type is met with during the monsoonal season. The rains resulting from this feature are not generally heavy, and though thunderstorms may be experienced over exten- sive areas of Queensland, New South Wales, and Northern Territory, a number of them may occur without any rain falling. Chart No. 11, January 17th, 1893, shows an extended and narrow tongue lying between two relatively high pressures, @ A depression similarly situated also exists in the south, this col or area of low pressure separating these two depressions is very small, and opposing currents of wind are noted there as blowing within close limits. Thunderstorms were occurring or had occurred in Northern Territory generally, over 4 great part of Queensland and in central parts of New South Wales, the rains upon this occasion, as is often the case, were not heavy, though they fell over an extensive and generally unfavoured area. TYPES oF AUSTRALIAN WEATHER NeW ALANUA Su hs . : i lm rea he @ sb S < re 544 HENRY A. HUNT. is shown in full force in front of the anticyclone, which by the way has lost none of its energy since the previous day; the depression is well off the coast and on its way to New Zealand. This burster reached a velocity of forty-nine miles per hour, and lasted thirty-five hours. TYPE XV.—THE BLACK NORTH-EASTER. This is a somewhat uncommon but nevertheless well known type of weather on the coast about Sydney. Its characteristics are a very strong and persistent north-east gale, continuing day a and night for two or more days; it has been known to last five days and nights, and it ends with the advent of a southerly burster. Its cause is found in an extensive col, the rear of one anticyclone being at rest over this coast, while another lies over the Australian Bight. Ifthe grade is rather steep and the system at rest for several days, then the north-east wind persists with force proportionated to the grade, until the whole system mové forward ; the southerly winds in the front of the approaching high pressure then displace the north-easter and the storm is over. There have been no good examples of this type since weather charts have been printed here. Chart 33 shows the necessaly forms of isobars, but the grade is not steep enough for a gale. TYPES OF AUSTRALIAN WEATHER. 545 TYPE XVI.—WIND BLOWING CONTRARY TO ISOBARS, In this type the wind blows with considerable force in a direc- tion directly opposed to that which the isobars would lead us to expect. For instance in No. 34, it will be seen that an extensive high pressure rests over the east coast, and the isobars are com- paratively close together. The normal circulation with these isobars would be fresh north to north-west winds, when, as a matter of fact, strong southerly winds were blowing as far as Sydney with a velocity of thirty miles per hour. Such conditions are rather troublesome in forecasting ; fortunately they do not come often, and the fact is not confined to southerly winds. The general direction of the coast line is northerly bearing east a little, * Tange of mountains from two to four thousand feet high = nearly paralled to it, and this local formation has a very mpstinnt effect on the circulation of the wind ; as in Chart 34 it seems to have more effect than the isobars, and probably the dees was rapidly intensifying and had not been long enough in Sxlatence to fully control the winds. It seems probable, so far as this type has been studied, that we should find that when the wind blows contrary to isobars, : it does so because of some impulse siven to it before the new grade had time to control the circulation. TYPES. oF AUSTRALIAN WEATHER é Ne SEPTEMBER I3.1005 MO a ‘ 546 HENRY A. HUNT. TYPE XVII.—SUMMER ANTICYCLONES. One of the most marked features of weather in Australiais the ‘regular easterly motion of it in all seasons of the year, addedt? this the anticyclones—the controlling element in our weather— change with the sun, so that the latitude they follow in their easterly progress is further south in summer than in winter.’ The summer latitude is about 40° south. They are less extensive in summer than in winter, and do not so completely control out weather as they do in winter, for their southern position leaves room for the southerly extension of monsoonal low pressures, which make a great deal of our weather; but the anticyclone makes the change from hot northerly to cool southerly winds, the bursters of the east coast. 4 smal acid TYPE XVIII.—WINTER ANTICYCLONES. During the winter months the antiyclones are much large ot they are in summer, and their latitude about 30° 8.; vey ere monly their area is equal to Australia, and their control of the weather more complete than it is in summer. Fine wea Se aol eee : 1 Moving Anticyclones—Quart. Journ. R.M.S., No. 85, Jan. 189% WS Ge oe Sena et ee TYPES OF AUSTRALIAN WEATHER. 547 marks their centres, and the rains come chiefly from the low pressures between each pair of anticyclones, and the strong westerly gales are but part of the circulation about these high pressures. (See Charts 29 and 30.) The one selected for illustration occupied the whole of Australia on June 4th, 1895, Chart 36. Its form was remarkably sym- metrical, and in the central area the barometers read 30°6, which is somewhat unusual, hence the circulation is active, and in northern Australia where the trade wind adds force, it is very strong. Under the central influence of these great anticyclones the whole of Australia enjoys fine weather. TYPES % TUNE... 1085 . oF AUSTRALIAN WEATHER ai 0 TY PE XIX.—SQUARE HEADED A DEPRESSION. is type j bene suficiont] cay ® variation of the usual , depression, but is c fats , ey om aracteristic to be placed by itself as a type or rather ence to — isobaric peculiarity, as may be seen by refer- » 18 that there is a flat top or square A, the usual form of. which is a sharp a marked feature of this is that under arkably squally and charged with thunder 548 HENRY A. HUNT. and hail storms, and deluges of rain. This type is not peculiarto : any season of the year, and the country they affect is usual : south of Lat. 30°. The particular square headed A i under discussion occurred in July, 1891. Its effects were wile spread and its life persistent, and its peculiarity in a moe or less distinctive form was maintained during its passage over six degrets of longitude, and its effects most severe in Victoria. In Chart 37, July 8th, 1891, the square headed A is —_ when over South Australia. The gradients about it excepting those on its eastern side were moderate; winds were from fresh to strong. Following it is a high pressure of decided energy, and preceding it to the east an anticyclone of little or no character ; on the previous day rain fell over greater part of the southern seaboard and in Tasmania. B 7 at Square-Headed | depression hereto iin Chart 38, J uly 9th, the depression has become more 7 but has lost energy. The relative powers of the antiey : raid remains the Same, winds were generally lighter, but the ie | covered a much wider area than on the previous day. a : storm moved to the east its characteristic weather was mal” : | TYPES OF AUSTRALIAN WEATHER. 549 TYPES on AUSTRALIAN WEATHER ri ° nf ee wK *. TYPE XX.—THE ADVENT OF AN ANTARCTIC STORM. This is a type of weather that does not often visit Australia hat its severity makes it noteworthy for the winds and weather which come with it are very destructive, and the cold severe, it might almost be called a southern blizzard; yet the warning is short and often difficult to read, for it comes from the Antarctic where we have no out stations. Foe —— consideration began to affect the south coast 1age (Chass making the winds fresh to strong on June 2st, _’ \~aart 39), yet the season (winter) and the general conditions. i < wal winds, and said nothing definite of the storm €graphed on the morning of June 22nd, (Chart 40). an. were then seen to be four-tenths lower in Tasmania finties Be iy on the 21st, and the wind had increased < a tad the ay aren south coast of South Australia and Victoria, ile bias é TS Indicate a very steep grade commensurate with a Pi mote also the wind rose in places to hurricane and trees bio rat, in western Victoria, buildings were unroofed own down. So severe was it there that the storm is 4s the Ballarat storm. 550 HENRY A. HUNT. oF AUSTRALIAN WEATHER 39 me 1892 *» In South Australia and New South Wales the wind did a gres# deal of damage without reaching the intensity it had in Victoria. ra isobars show a retreat of the anticyclone and a tilting of the ve axis, and a very remarkable increase in the number a isobars on the south coasts of South Australia, Victoria, and = TYPES i TYPES OF AUSTRALIAN WEATHER. 551 Tasmania. It looks as if the low pressure had retreated and its western parts forced their way north. What probably did take place was that a storm centre south of the Australian Bight and indicated by the northerly winds in Chart 39, had in the interval surged northwards on to the west coast of Victoria, bringing with it all its antarctic energy and severe cold. This view is sup- ported by the fact that there was in the twenty-four hours but little change in the New Zealand isobars, and further by the upward tilting of the eastern part of the anticyclone caused by the northing of the antarctic storm, and lastly by the blizzard- like cold which was so marked a feature of this storm. LIST OF TYPES OF AUSTRALIAN WEATHER. I.—Moving Anticyclones, Charts 1, 2, 3. IL—Monsoonal Rain Storm, Charts 4, 5. IIT.—Development of a Cyclonic Storm in Low Latitudes from a Monsoonal Depression, Charts 6, 7. IV.—Development of a Cyclonic Storm in High Latitudes from a Monsoonal Depression, Charts 8, 9, 10. V.—Conditions favourable for Thunderstorms, Charts 11, 12. VI.—Cyclonic Thunderstorms, Charts 13, 14. a and nearly straight Isobars, Charts 15, 16. -—Uyclones from North-West, Charts 17, 18, 19. TX.—Cyclones from North-East, Charts 20, 21, 22. X.—Tornadoes, Charts 23, 24. XI.—South-Fast Gales, Charts 25, 26. XIL—Development of Cyclones from a 4 Depression, Charts x , 28 Caan Winds, Charts 29, 30. Pe eam Bursters, Charts 31, 32. i. North-Easter, Chart 33. a noting Against Isobars, Chart 34. i a” Anticyclone, Chart 35. . inter Anticyclone, Chart 36. any Headed , Depression, Charts 37, 38. , vent of an Antarctic Storm, Charts 39, 40. PROCEEDINGS ROYAL SOCIETY OF NEW SOUTH WALES. WEDNESDAY, MAY 1, 1896. AnyuaL GENERAL MEETING. Prof. R. THRELFALL, M.A., President, in the Chair. Fifty-three members and nine visitors were present. The minutes of the preceding meeting were read and confirmed. The following Financial Statement for the year ending 3lst March, 1895, was presented by the Hon. Treasurer, and adopted :— GENERAL ACCOUNT. REcEIPTs. £s. d se One Guinea... Pe -- 155 8 0) Subscriptions — ae see < 3 ’ ’ “es Advances eke uke ‘ve 3.3 0 Entrance Fees and Compositions a his ee “4s 56 14 0 Parliamentary Grant on Sihecrint: ived during 1894 500 0 0 Meteltit § a ee ee. be” ee ae Total Receipts ic a ee : : ance on Ist April, 1894 Bed £1298 2 § ——— : PAYMENTS. £3. c Se Advertisements iS ts be 2716 6 Assistant Secreta 250 0 0 Books and Periodicals 100 13 10 kbindin : 6116 0 Conversaziong «_. oe cae co we 69 13 1 wien, Chatges Pisking ggg ae iture and Effects ... sas : 410 0 Carried forward ee wu. S028 14. 8 PROCEEDINGS. 553 AYMENTS—continued. rae Spe can ae ae ase sa wai «. 523 14° 0 Gas . eds beak oe Boteckoeper ane a8 ee mS isa 10070 urance ... obs ie sa ae ee 10 14 0 Office Boy . cia ise | oak eRe gee ee Petty Cash Be pensos ves Wis 4 1894. 95 ; Vol. xxvi1., Nos. 1-3, 1895; Vol. xxvur., (Geological Series, Val III.) No. 1, July 1895. Memoirs +» No. ; Vol. xvurt., 1895. The Museum 28S oie sche oie schule. Programm fiir das Stu- er rod 1894-95, Tobecanphes fiir das das Wintersemester Inaugural-Dissertations (6) 1893-94. The Director Can —Fersin fiir Naturkunde. Bericht, Vol..xxxix., 1892 1894. The Society Canvits—Naturwiseoschaftliche Gesellschaft. Bericht, Band 1, 1889-92, : Cutca¢o—Chicago ge ad emai * Seer Vol. 1., Nos. 1-10, 1883-86; Vol The Academy . Field Columbian eas ae i ans 1., No. 1, 1894. The Museum i Soong du Chili. Actes, Tome 11., a ter ; Tom , Liv. 4, 5, 1893; Tome Iv., Liv. 2 - nk 4. e Society ae he eden he BP ag tang tose Commiss-_ i de me Roce tate der im Sommer 1894 in m sii iihieten 1 Theile Norwegens ausgefiihrten Pen delbeobachtungen von O. E. gens Rag ‘ Beobachtungen, 1895. ssociation orwegische Pomniesio on der Europiischen Gradmessung. Resultate er im Sommer 1893 in dem nordlichsten eile hts me ausgefiirten Pendelbeobachtunge en “ von 0. E. Schidt he Commission ee Royale de No orvege. Jahrb iaceaeaeiel eg orologischen Instituts fiir 1891. 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The Wo mbat, Vol.1., No. August. 1895. The College seare lnatiint National Genevois.. Bulletin, Tome xxxIt., The Institute ee Calendar for the year 1895-96. The University wana ae gliche Gesellschaft der ee ichten, Math-phys. Classe, Nos. 3, 4, 1894, Nos. Maasie4 Colonia Museum. Bulletin, March, July, 1895. Nuttige Indisch e Planten heats M. Greshoff, Aflever- ing 1, [Extra Bulletin, 1 94]. The Musewm eae: ee Archives, Sion 2, Vol. 1v., Parts iii., iv., Société Ce . e des Sciences. Archives rs des Sciences Reectos et — —— XVIIL., se v. 3-5, 1894-5; Tome xxix., Liv. 1 The Society Hatz A/ yb Leopold-Caro Deutsche bee emie der Natur- er. Nov Vol. byit.—uLxtr., 1892-1894. Tepe rium, Band . [Act 1.—x., Nova Acta Band 1, Leopoldina, Heft 28-30, 1892 Katalog der Bibliothek, Lieferung 4, (Band 11., 1) 1893; iefer g 5, (Band 11., 2 Geschichte der Biblio- thek und Naturaliensammlung von Dr. Oscar Grulich, OE ate The Academy AX, N.S.—Nova Scotian Institute of Science. Proceedings d Transactions, Second Series, Vol. 1., Part iii., Session 1899-93. The Institute 2 Deutsche Seewarte. Archiv, Jahrgang xvil., 1894, tgebnisse der Meteorologischen Beobachtungen, Jahr- KE—Dee. 4, 1995, 578 ADDITIONS TO THE LIBRARY. Hampure—continued. gang XvI., 1893. begs ried iart iiber Thatigkeit der Ho aes “Nordatlantischen Ozeans [Quadrat 78] No. X1v., he Sesirealacks Gesellschaft. Mittheilungen, Heft 2, 1891-92. The Naturhistorische Museu unig ios Jahrgang bade Hilfte 2, 1892 ; Jaieeganin x1., 1893. usewm a aahacliicha Verein. ‘Abfandlungétt aus dem Gebiete der hie ie wens gma xu., 1895. ; Vubenilenedn, Folge u1., Heft 2 The Society Vereins fiir “roy ea uensbageb ot ia Untoratong Ver- handlungen, Band viir., 1891 ” Hamitron—Hamilton Association. pase and ae oe No. 10, Session 1893-94. Associaton . Herpetberc—Naturhistorisch - ae ee Pe is handlungen, N.F. Band v., Heft 3 ” a des Sciences de sptaaiiabs. Acta, idrag, Hiftet, 54 - 56, — 95. Obeid Forhandlingar ol, xxxvi., 1893- sneer Météorolo cnet ag on 1889-90. Guia ns Météo- peiocianes te faites 4 Helsingfors en 1893. mcontione nag ene of Mines. Report of the fore Mines for 1894-5 Secrcary for Mn | Royal Backs ety of Toimanis, The Tasmanian ie eon. XVIIL, ae No. 958, Nov. 30, 1895. The Society casera! N. J.—Stevens Institute of Technology. Annual Catalogue, 1894-95. The Institue JaLapa—Observatorio Meteorologico Central del Estado de Vera etn Boletin, Jan., Feb., Mar., and Resumen en See onigng risen ig Cy h-N serie aig peterson Gesellschaft. Jen- = ische Zeitschrift fir Nat schaft, Band ait F. we'd mri Heft. 4; 5 aig et ye N. F. Band xxu., ihe Heft. 1, 2 The Society Kew—Royal ee tik ker’s happens ee Fourth Series, Vol. rv., Pa rts ii. - The Bentham Trusted Kaxosrox—Institute o a Jamai ph eat i 11., No. ; op 895—A A Handbook of "Information or Lh situ tending settlers and o The . Knin—Société oar toe eae Starohrvatska Prosvjeta. The Socey God. 1., Br. 1- LANSING. Mich. —Mi ites a ‘School. Reports of the The Sebo Director for 1890 — 1892. La Prata—Facultad de Agronomia y Veterinaria. Revista, pocsllt Nos. 5 - 7, 1895. . Revie : ADDITIONS TO THE LIBRARY. 579 Lavsanne—Société Vaudoise des Sciences Naturelles. Bulletin 8e S. Vol. xxx., Nos. 115,116, 1894; Vol. xxx1., No. 117, 1806, The Society Leeps—Conchological Society of Great Britain and Ireland. Jou rnal, Vol. v ty; No. 12: 1894 “oy Leeds Piiscophicai and Literary aay. Annual Report (75th) for 1894-95. naan eoreges penal. sake (20th) 1893-4. The College Lerezia—Ki ft der Wissenschaften. Si de die Verhagen, =e classe, Heft. 2, 3, 1894; Heft. 1 and 4 The Society Vereins fiir Erdkunde. Mitte, ne Wissenschaft- liche Verdffentlichungen, Band 1 ” Lifiar—Société Géologique de Belgique. Annales, Tome xx., v.3, 1892-93 ; ‘Tome xxr1., Liv. 3, 1893-94; Tome xx11., 894-95. Société one des Sciences. Mémoires, Serie 2, Tome XVIII., 1895 » Lirtie a et tell Survey of pee: Annual Report 1 Vol 11., for 1892 Vo oe The Survey ci. xia Institut: Great Britain and opr Journal, Vol. xxrv., Nos. 1-4; Vol. xxv., No. ‘ PNG Institute British ae (Natural History). A Monograph of the Mycetozoa by Arthur Lister, F.L.s The Museum : ears pg vee Baer Journal, Vol. t., No. 4; Wer LI. 203, 1895. List of Pallows, ‘n % Nov. 1894. ii ogical Literature added to the Society 8 Library during the half year ended Dec. 1894. The Society Highland and bag gros oe Scotland. Trans- actions, Fifth Series, Vol. v India Office Kéfiristin. and ite a iy G. 8. Robertso Ms Seer —— of Stat eater India Institute of Chemistry of a Britain and Ireland. » Parts i. and ii., 1894. Register, aoe 1896, : 1895 ~ 1896, The Institute oe ge of Civil Engineers. Minutes of P. ol. exrx Tron and Steel In stitute. Journal, Vols. xv., sees Nos. »2,1894. Brief Index of Papeie in Journal 1869 - 1894. The Institute ary Society. Journal, Botany, Vol. xxx., Nos. 209, 1904-92: Zoology, xO set Nos. 158, 161, 1894-95. FE dings, from Nov. 1893 to June 1894. List of ellows, 1894-95. The Society tio logical Office. Meteorological Observations at sa ns of sel —- Order for the year 1890. Repo: ca eteorological — to the Royal Society for the year ending 31 March, 1 . The Council 580 d ADDITIONS TO THE LIBRARY. Lonpon—continued. Minera Gierteat Society. Mineralogical Magazine and Journal Vol. x., Nos . 45 and 48, 1892-94; Vol. x1., Nos. 49, 50, The 8 Pharmaceutical Society of Great iene Se Jour 8 Ser. Vol. xxv., Nos. 1266-1317, 1894-9 . 1, Nos. 1319 - 1321, 1895. Calendar 1895. Physical Society of London. Proceedings, Vol. xu1., Parts x., Nos. 51 - 60, 1894-95. List 7 Officers and Mem- tik April 2, 1895. nsec [eet ies po — Ser. 2., Vol. v., No. ; Vol. vi., No. 3 coe agseatana Society 7c ea lend Journal, ee Series, Vol. v., Parts ili., iv., 1894; Vol. v1., Part iii., 18 895. ” the Socey : Royal ye Society. Monthly Notices, Vol. Liv., No. 9, 1894; Vol. uv., Nos. 1—8, 1894-95. Royal College of Physicians. List of phe ag Members, ra-Licentiates and Licentiates, 1 Royal Colles of Surgeons of England. Caicndas July 12, uly 11, 1895. mye Colonial Institute. eee Vol. xxvi., 1894-95. alogue of the Libra The Institule Royal Graphical Society. “The Geographical Journal, Vol. 1 re petal Vol. v., Nos. 1-6, 1895; Vol. Aree Ro eval ‘Historical “Seciciy. Transactions, New Series, vol. 1894: ibbon Com a ation 1794 - 1894. Royal Thotitution . Great Britain. _ Procee dings, hoe XIV. Part ii., No. 88, March 1 TOee, ge he Inst Royal Meteorological Society. Quarterly Journal, Vol x No. 92, 1894; Vol. xx1., Nos. 93, 94, 1895. Mateo: bs i Royal Society. Indian Meteorologica cal Memoirs, Vol. Vil, Parts i. and ii., agen ipmapeee Transactions Vol. XXxv., Parts i. and ii., each A and B Pr c sag = =a aud LVIl., “1894-95. List er are 30 Royal Cited Service Institution. Journal, Ns XXXVIII., Nos 1894; Vol. xxxrx., Nos. — 209, res = 5 94-953 os mens ‘Institute. eakiy Vol xv., Parts i. —iv., 18 ) ol. xv1., Parts i., ii., 1895. South Kensington iueav: rset for 1895. Catalogues of Percy Fy; of Light on Water Colou Report ke agga Metal Work, &e. by Prof. W. Zoological Societ ety of London. Proceedings Parts iii., IV» Parts i., ii., 1895. Transactions, Vol. xIII., | y ee 1894 -95. The Club The Society gi dl itution : 7 Socidy = ADDITIONS TO THE LIBRARY, 581 Lusrck—Geographische Gesellschaft und des Naturhistorisches eums. Mittei eilungen, Zweite Reihe, Heft 7, 8, 1895. The Museum a. Institut Royal Grand-Ducal. Publications, eee Send Sciences Naturelles et Mathématiques, Tome The Institute ag Observatory. Madras Meridian Circle Utes rvations, Vol. vir., 1883-1887. Errata, Vols. 1 The Observatory Madras et cacack Museum. Bulletin, Nos. 1-3, 1894-95. The Museum Manson, A eg oF ag consin Academy of Sciences, Arts, and Let . Transactions, Vol. rx., Partsi., ii., 1892-93. Ths Keallany asst Concho Society. Journal, Vol. viir., Nos. 1-4, 1895. The Bookety Manche a Society. Transactions, Vol. xxrmt., Si, 1894-95. Hao iSacasy and vem geeesed Society. Mem and Pr geet da 4. Ser + Mies » Nos. 3, 4, 1893.94; Vol. rx., Nos 1894 * Mansur G—Konieliche Unive “hagas Inaugural Addresses 8 (73) 15 August, 1893-9 The University Gesellschaft zur Beforderu ung der gesammten le ade Schaften. Si itaungaberichte, ch emt 189 “The Society MaRseriies—Faculté des Sciences de Marseille. Annales, Tome It., Fasc. Supplémentaire 1893 3; Tome tv., . 1-3, 1894, Sur l’ Existence et la Bt igtete des oscillations dlestro-magnétiqnee dans I’ air, par M. A. Perot. The Faculty Institut ee Hhlogune Colonial, Annales, Ser. 1, Lo ” The Institute Sanaa soe of ome. Vol. rx., Nos 106 - 108, 1894; Vol. x., Nos. 109-119, 1895. The Publishers Broken Hill a petnty Gs . Ld. Reports and Statements of A t for Half Sone ending 30 Nov. 1894 and 31 May 1895. The Secretary Department of Mines. Annual Report of the ——T _ Mines for 1894, Report on the loss of gold i reduction Se —— veinstone in Vieoein, ty ales, G.8., 1895. Reports on the Victorian Coal Fields, ate 3 and 4, by James Stirling. | The Department Field oe Club of Victoria. The Victorian Naturalist, Vol - 7-12, 1894-95; Vol. x11., Nos. 1-5, 7, 105 The Club ," D ibrary, Museums, and National neon | of Victoria. €scriptive Catalogue of the specim n the Indus- th and ‘era logical Magen um, | cae Hiinatedtingy Plan wonom Woods of Victoria. Select Extra-Tropical 1895, “ by Barn Ferd. von Mueller, Ninth. Baition, _ 582 ADDITIONS TO THE LIBRARY. MELBOURNE—continued. Royal Society of Victoria. ore ape of the Victorian Institute, Vol. 1., Sessions 1854-55. eerie of ophi Tra actions and Pro aT toe, of the Royal Socaty i Victoria ol. viu., Part i., 1867; N.S. Vol. vir., 1894. Trans- : actions, Vol. rv., 1895. _ The Society Mérmpa—Universidad de los Andes. Annuario, Tomo bd : 31 Dec. 1893. The University Mertpen Conn.—Meriden Scientific Association. Transactions a Vol. v., 1893. e Association gic sags coige Aas oe zu Metz. Jahresbericht, Band ; The Society Maxico—Oteeratoro oS Nacional de Tacubaya. Anuario, Afio xv., 1895. Bo letin, Tomo 1., Nos. 18- : 21, 1895, The Observatory Sociedad ee “Antonio Alzate.’ Memoriasy Revista, : Tom 12, 1893-94. The Society Mixax—Roal nea a peesaiage m omen e Lettere. Rendi- 4 nti, Serie 2. Vol. x ; Vol. xxvi., 1893. Indice Suiarais 1803 — 1888. The Institute Societa Italiana di Scienze Naturali. Atti, Vol. xxxv., Fase. ; 1, 2, 1895. The Society MrynzaPotis—Geological and Natural History Survey of Min : nesota. First Report of the State Zoblogist, Zodlogical je eries, Vol. 1., 189 The Survey nnesota Academ . t Natural Sciences. Occasional Papers, Vol. r., No. 1, 18 The Academy Sega Sige ire Gulia ns Polytechnic Society. Pro- 8, New Series, Vol. x1, Parts 4 and 5, 1894. The Sociely Moves Regn cademia ne Scienze, Catia ed Arti. Memorie, © Seri Pes Ix., 1893. Opere inviate alla R. Accademia 1892, 1 The Academy ne conan été Météorologique de Uruguay. Résu des er are ns nde, cease es settee pendant ‘ Socily Saison d’ été de P a Mownenizien— Academic ak pelea et Let ie es. Mémories, érie 2, Tome 1., Nos. 3 and 4, 1893; Tome 1., No.1, The Academy MontrEat—Natural 1 History S The Cana- apie ry Society of mag" e : dian Record of Science, Vol. v 1893. The St Royal Society of Canada. Pro fiat ais oe icc Vol. xit., 1894, and Galeorat 2 ly Vols. I Moscow— Observatoire Météorologique de l’ Galver 66 Imps — : Meteorolo 1 Obse atin, Sdn: e 4 March, 1895 ae cs The Observatory Société aperiele des Naturalistes. een OE 8. Vol, vitts Society : 8. 2- 4, 1894; Vol. rx., Nos. 1, 2, 1895. The 2 MorasiiaSecch: Industrielle de Midian. Bulletin, Vol- dd +» Oct. - Dee s Vor 94; Vol. raid Jan. — June, 1895. rogramme des Prix, 29 Mai, 1 ADDITIONS TO THE LIBRARY. 583 eee ee Botanische Gesellschaft, Berichte, Band The Society King Taye Akademie der Wissenschaften. Ab- lungen der Math-phys. Classe, oes xvit., Abth. 4 1895." Si itmgsberihte, Band xxitt., Heft 3 cae B. 1894. Ueber a6 Bedent Micethatitiohe: anne von L. Sohncke, 1894 The Academy ee eae des Naturell VOuest dela France. Bulletin, sien ING; Serparurenye se 4, 1894; Tome v., ee 1, 1895. The Society a Reale di Napoli. Rendiconto dell’ a del omen Fisiche e Matematiche, Ser eRe 12, 1894; Ser. 3, Vol. 1., Fase, ee $1 Zoologische Station zu Neapel. Mittheilungen, le Xi; Heft 3, 1894. The Director Newcastis-uron-Tyne—Natural History Society of Northum- berland, tain and Fiprecerntest -upon-Tyne. Trans- actions, Vol. x Part ii 1894. The Society North of England ‘tasibeis of Mining and Mechanical Engine - Report of the Proceedings of the Flameless arts ases Dy A.C. ayll. Transactions, Vol, xtiv., Part 1. —1v., 1894-95. The Institute New Havew—Connecticut eg cag! of Arts and Sciences. Transactions, Vol. 1 «ys Part 11;,° 1805: The Academy New Yous—Ameicin Chemical Society. Journal, Vol. Nos. 10-12, ; Vol. xvit., Nos. 1-10, 1895. The Society saat Geograph ne aie Bulletin, bi xxvi., Nos. 8 and 4, Parts i. and ii., 1894; Vol. xxv, Nos. i., ii., 1895 ” American a of Mining Engineers. Transactions, Vol. xx1v The Institute American eal of Natural a. ta Bulletin, Vol. r., 1881 ~ =O6 > Vol. i1,, 1887 = Vol 1893; Vol. vI., eae Annual Report of the. Presidont &e., for the year 189 The Museum New Tot Academy of Sciences. Annals, ben vuit., Nos. ~ 12, 1894-95 ; Indexes to Vols. vr. and v The Academy New York “coppigy bel het Journal, a x., No. 4 1894 ; ., Nos 1895. The Society Omavs Gulia Survey of eon Annual Report, New Series, Vol. v1., 1892-93 The Survey xo acl eae Gaiiieds of Books added during The Trustees Raastine ite anne : & gee Stars for the +. Poch 1890 by E. J. Stone ” Sy oe nome de gene “at France. Comptes N a oo cx1x., Nos. 12 - 27, 1894; Tome cxx., 0s. ; Tome cxxt. =) Ros. i- 13, 1895. The Academy 584 ADDITIONS TO THE LIBRARY. Paris—continue Comptoir Gstogiane = Paris. A ire Géologiq ‘Une Tom ~» PP —612, 1892 ; Tom , Fase 1893. y Expositi i publiqn et temporaire ay detaatiiee ‘Géo. ea logiques “2 r. 1894) The Editor wees v Asthepolgi de Paris. Revue Mensuelle, Année . 9-12, 1894. Bulletin, No. 3, Juillet — Sept. ‘ The Director Boole. N ationale des Mines de Paris. Statistique de l ustrie Minérale et des appareils & vapeur e nce th Algérie pour année 1893. JMinistére des Travaue Publica : Ecole Polytechnique. Journal, Cahier 63, 64, 1893-94. Feuille vse Jeunes Naturalistes. Revue Mensuelle d’ Histoire relle A Nat 3 Ser. Année 24, No. 288, 1894; 3 Ser. Année en 5, “Now. 289 300, 1894-95. The Editor L’ Observatoire de Paris. Rapport Annuel pour Il’ année, F The Observatory — Museum a Histoire Naturelle. Bulletin, Nos. 1-8, Bo wae ; Revue de I’ a Tome v., 1892; Tome v1., Liv. 1 Per and 3 The Editor — Socidté = ‘Anthropslo ie. Bulletins, ae 4, Tome v., Nos. Mémoires, Serie 3, Tome r., Fasc. 2, 1894. ue ae ae ‘iologi, Comptes meg ‘Serie 1 0, Tom Nos - 35, 1894-95 ; Ser. 10, Tome 11., Nos. re 27; 1895. ” Société . Encouragement = Yr Industrie Nationale. Bulletin, 4 Série, Tome 1x., 1894. Société Entomologique de Pics: Bulletin, Vol. ux1., 1893.» Société ie de rane oes, Toe ee Tome xvit., Nos. 7s ) ., Nos. — 6, 1895. oo “Fran de: Physique, Sultott in Bimensuel, Nos. 1894; Nos. 988 ba 1895. Séances, Année 1894 alte rs 4; 1895, Fas sipep = bee ba Ballet, Ser. 7, Tome xv., Trimestre 894; Tom , Trimestre 1, 2, 1895. Comptes sy ai Nos 15 19, ; 1894; Nos 3, 7-12. 5 4: Société ren sep de France. Bulletin, coe Tome XXL, No. 6, 1898; Tome xx11., No. 6-9 ; Tome Xxull, Nos. 1-3, 1895. Compte-Rendu an gihee 3 Ser, Tome xxu., Nos. 14- 18, 1894. = Société Zoologique de France. Bulletin, Tome x1x., 18%. Mémoires, | VIt., 1894. i Prntaxce—Royal Geo logical ‘Shaely of Cornwall. Transactions, Vol. x1., Part ix., 1894. Laws and Rules xy of Natural Sciences. py eedings, 8 ii, and iii., 1893 ; Parts i. - ili., 1894; Part is =a - American Sul rag ee 1894; Vol. PunavnemaAcadom Par Nos. 3 ol. xxxi1., No. 143, 1893; pt 8. 144 -146,1894. List of Surette rslaaheeh ADDITIONS TO THE LIBRARY. 585 PHILADELPHIA—continued. Franklin Institute. Journal, Vol. cxxxvit., Nos. 826 — 828, 1894; Vol. cxxxix., Nos. 829-834, 1895; oxn., Nos. 835, 837, 838, 1895. The Institute Wagner gal Institute of Science. Transactions, Vol. 111., Part ii 1895. ” gaan Sic ety. Annual Report (28rd) of the Board of hactiira, Apel 25, 1895. The Society Preu—Societa Toscana di Scienze Naturali. Atti, Processi Ver- bali, Vol. rx., pp. 183 - 242, 1894-95. » Pe py couik h Institution and Devon and Cornwall Natural History Society. Annual Raper and Trans- actions, Vol. x1., Part ne 1893-94. ” Port rhe gen Alfred Observatory. Results of Meteor cal Giesivabone fakes during the year 1893. The Ctenvatony CS Preuss. Geoditisches Institutes. Astronomisch- Geodatische ‘Arbeiten I. rdnung. ip get in f F 4° Berlin, The R, inabioull Pracon—Konigl. i. “ns Gesellschaft der Wissenschaften. 3 “cium fir das Jahr. 1892 and 1893. Sitzungs- erichte, ma w. classe, 1892 and 1893; sae histor.-phi ilolog. Be aly 1892 and 1893 e Society Bio Dz Janztro—O Observatorio. Annuario 1893 and 1894. idee Otero Muse useu Nacional de Riode Janeiro. Archivos, Vol. vim1. The Muse Rocursrzr, N.Y.—Geological Society of America. an letin xe ols, IV. — VI., 1893-95. List of Officers and Fellows for 1894, he Society _*wouE—Accademia Pag ia de Nuovi Lincei. ey eel dal segretario, Anno xzvit., Sessione 2, 3, 5-7, 1894; Anno xivirt., ena 1 - 6, 1895. The Academy Ministero dei Lavori Pubblici. Giornale = Genio Civile, Anno x XX11., Fasc. 8-12, 1894; Anno xxxut1., Fasc. 1895. Minister of Public Instruction, Rome R. Accademia - Lincei. Atti, Serie 5, Rendiconti, ibe Itt. Fasc. 6—12, Semestre 2, 1894; Vol. 1v., Fasc. 1-12, Semestre a 1895 : | Vol. v., Fasc. 1-5, Semestre 2, TAOB. 1 1895. esata Giugno R. Comitato Geologico d’ Italia. oie Vol. xx Nos. 3, 4, 1894; Vol. xxvr., Nos. 1, 2, 1895. The Committee Societa gai Dante Alighieri “ Ganiditte 8). Revista ca Italiana, Anna’ ., Fase. 5, 6, 1895. sider : Vol. v.. Pacte i i., 1895. The Society . Googratie Italiana. Bollettino, Ser. 3, Vol. v1, asc. 9-12, 1894; Ser. 3, Vol. vim., Fasc. 1-9, 1895. » 586 ADDITIONS TO THE LIBRARY. RomE—contin Ufficio Cantrile Meteorologico e aro Italiano. nnali, Serie 2, Vol. xu1., Parte ii The Director ogemenge Ai Lick Observatory. Pub ns of th en , vatory of the sdeipecese of Confrtee: Vol. Ss ol tv., 1895 The ‘Ohmeewiie Sr. Apnaaiee “University. ‘-Calonday for the year 1895-96. The Senate Sr. Urban igen sae Science o St. Louis. Preece Vol. v A Ne 9 16, 1893- ne Academy Missouri etectioal Garden. Gani Report (5th) 1894. ‘* Director St. Pererssurc—Académie Impériale des Sciences. Bulletin, N.S., Vol. rv Seri. ) Nos. 1, 2, 1893-94; Serie 5, Tome 1., Nos. 1 — 4, 1894, ., Nos. 1 —4, 895 Mémoires, Serie 7, Tome x., Part ii., 1893; Tome xtr., Nos. 2-9, 1893; Tome x11 - 1-12, The Academy Comité Stic a bea erie ig Sora roger Tome x11., Nos. 8-9, 1893; Tom , Nos. 1-9, 1894 and Supplement ; ag XIv., Sg 1-8, a0 Mémoires, vul., Nos. 2,3; Tome 1x., Nos. 3,4 xX, : No. 3, Tome xrv., Nos. 1, 3, 1895. The Committee ihe ogy a Gesellschaft. Verhand- lungen, Ser. 2, Ban 1894. The Society Suuex—Ameriean eRe Ss the Advancement of sue Proceedings, Vol. xnir., 1893, Madison Meeting; Vol. XLut., 1894, Brooklyn Meeting. Bhi Pree Essex Institute. Bulletin, Vol. see Nos. 1 - 12, Historical Collections, Vol. xx Bee Dee. rs The Institute San ee ornia enemy a Saimin. Pineke di in Vo ae . Parts i. and ii., 1894-95. Memoir pei No, ne Academy California. State Mining Bureau. Twelfth Report of ‘the State ng eralogist (second biennial) two years ending Sept. 15, 1894. The Bureaw San Viens ages servatorio Astronémico iy Meteoroldgico. Observaciones Meteorologicas del aio de 1892, 1893, . The Observatory Pa.—The a Engineer Co. Ihe Colliery Pe sein eta Mi vas Bh v., Nos. 3-12, 1894-95; Vol. Rae The College i Aarsberetning for 1893. ne Mon ockHOLM—Kongl. Svenska Vetenskaps-Akademi Hand- 3 ngar, gee xxv., Haftet 2, 1892. po int ary Afd. , 1894. Lef —_ ningar, Ban Hite 2 2. 1894, _ovesit sles 1894. ‘ acuatioul katalog, 8, 9, m Sveriges zoologiska hats- station Kristinbong af Hjalmay . The Acaden STRASSBURG, i. x—Centralstelle des Pk es nae: dienstes in Elans-Le othringen. Ergebnisse der Meteoro- logischen _ en im Reichsland Elsaas-Loth ne ringen im Jahre 1893 Sowravitin, Ma Mas. Put College. Tufts College neo te > 2, 3, ADDITIONS TO THE LIBRARY. 587 ere ee nigliches Bt ger rad Sendouan Wiirttem ergische, Heft The ‘ Landitant” Vereins a ney “Natorkund in Wirttemberg. Jahreshefte, Band u., Jahrgang 18 The Society SroneAsartinn Museum. Report of the © asap for the 1894. Records, Vol. 1i,, No. 6, The Trustees Deymztnent - Mines and Agriculture, Pi ae Gazette a New South Wales, Vol. Parts x. - xii., Ne Vol. obi — x., 1895. ptt Report for 1894. Memoirs of the Geological a ey of N.S. Wales gine oleate 8, Ree of the Geological Survey of N.S. f den, F.L.s., &c. and W. 8. Campbell. The Department Department of Public REEF Report of the Minister of Public Instruction, 1894. Technical Education ranch, Series sia ind wind ae Wales Binet - 6, Engineering Association of ite South Wales. Minutes of ceedings, Vol. viir., 1893. se Association a ora Pri nter. The Statutes of New South W. on “6 lic and Private) passed during the ponte of 18 e Go eho Printer nda Statistician. Statistical Regiter ia 1893 and previous years (complete), and Parts vi., viii. — xi. ; 894 and previ ye Parts i. - viii. 189: d ious S, -—viii. A Statistical Survey of New South Wales, 1893-94. Statistics of t Seven Colonies of Australasia, 1861 - Wealth se Progress of New South Wales, 1894, ag issue, Vol. e Go els ‘Statistician cing = Surveyors, New South Wales. The Surveyor Vol -, Nos. 11 and 12, 1894; Vol. vitr., Nos. L- ie The Institution Linnean Society of New pe — Proceedings, Second Serie 8, Vol. x., Parts i., 1895. ee of Proceed- ity, 5 1894 : March - sg a Nov. The Society New South Wales Board of Health. Ant itoxic Serum for ive). Vaccination, Report for 1894. Vessels arriving at — — e ports of New South Wales, Returns eg 894. e President ie. South Wales — Board. Register of ota Practitioners for The Secretary Observatory 5 Recen i of Double Stars made at ydney by H. C. Russell, 8.4., F.8.s. Results of Rain, River, and Evaporation Observatio ons made in New South Wales, during 1893. The Observatory 588 ADDITIONS TO THE LIBRARY. SypNEY— continued. saan Free Public Shae: Report from Trustees oe Trustees Universi eae of the Sydney University for a The University ‘oh eae Astronémico Nacional. Boletin, Tomo 1895. The oe Tarpinc—Perak Government Gazette, Vol. vit., rip 21 - 26,1 Vol. viir., Nos. 1 — 26, 1895. etary to the "Covers Toxio—Asiatic Society of Japan. Asean dies v6 xxir., Part ii 1894. General Index, Vols. I. = XXII, Ae he Society Imperial University of Japan. Calendar 1893-94. J ae of the College of Science, Vol. vi1., Parts ii. - v., Be 894; Vol. vit 1., Parts i., 1895. he University nig tot aanealoiang Cplenda for 1895-96. ” TovuLouse—Académie des Sciences, Inscriptions et Belles- Lettres. onic, Serie 9, Tome v1., 1894. The Academy Trreste—Museo Civico di Storia Naturale. Atti, Vol. 1x., — he Musewm Sereno reg eee rit dag aa Rapporto ijaiee Vo er ’anno 1892, The Observatory Tosis—Insttut 2 Carthage. Revue Tunisienne, Année 1., No. The meee Tosix—Osserraorn della R. io Osservazioni pee rologiche fatte nell’ anno 189 Oboe R. orca Hard Scienze di et Atti, Vols. xIv., We —XXIL, XXIV. - XXIx., 1878-94; Vol. Xxx., Disp. i AL, 1894. 95. The Academy — Haat Heals Istituto Veneto me herp epee. ed Arti. Atti, Serie 7, Tomo m1., Disp. 4-10, a d Appendices 1 and 2, 1891. -92; Tomo tv., Disp. 7. 10, 1892-93 ; Tomo v., Disp. 1-3, 1893-94. The Institwlt ee penbrepslogiache Gesellschaft. Mittheilungen, Band N.F. oF Hott 5,6, 1894; Band xxv. (N.F. cial Ba. xv.) Heft + <4 The Si : — Akademie Pg ‘Wissenschaften, Sitzungsber- . Cla th.-naturw ‘Abth, I., Band my “5 ne mes We 1893 ed Ia, Ee cil > ” 110, » cit, ” ae ef. 2 2”? 2” bas aoe CEE., 5s = 10, ” 2» 9 CRs a 2 = 8, 1804, 1 Gs 5s Og a Bes as wy ORs 3s Lee PN AR tak aici gt eee aren midlet | 7 on). = K. K, cnt caine fiir Meteorologie und Je Erdm magnet ‘ rbiich B xxix. onan er {oct Publication) N. TH Institute K. K. Geographische Gens M social ittheilungen, Ban ‘: Vi., (N.F. xxv1.) 1893 The ADDITIONS TO THE LIBRARY. 589 Virnna—continued. K. K. eologische Reichsanstalt. dorsbhen Band xu1., Heft. 4 — Band xuu11., Heft. 2 1893; Band xurv. Heft. , 1894. Verhandlu mgen, ‘Nos. 6- 10, 1898; Nos. ae ts, 1894; Nos. 1-7, 1 The “ Reichsanstalt ? K. K. Gradmessungs- Bureau. dia: Arbeiten, Band sg ‘en The Bureaw K. K. Gradm wii he maga Verhandlungen, Proto- koll 11, 12 poe. The Commission K. K. Nalarhstrischo fea ’ Annalen, Band rx. she Museum K. u se K. ee BEceias Ministerium ‘‘ Marine Sectio av Schwerebestimmungen durch Pendelbeabach- tungen, 1892 —1894. he Department K.K. Zoologisch- Botanische Gesellschaft. Vechuetniiines, oo XLII., Quartal 3, 4, 1893; — XLIV., Quartal 1 4, 1894; Ba wir tv., Heft 1 ee The Society Bootie” fiir Naturkunde des PAB wine te et en Clu oa “Mitthellonges, Jahrgang 111., 1891; Jahrgang I, The Section eS cae erginge Association. Annual;Report or the year 1893 The sof Bureau of Ethnolo ogy. Annual et (9th - 12th) 1887-8 1890-91. An ancie ak qua pcden| here L by - H. Holmes, n Jam and P, awe re wg Gerard Fowke. “Biblio graphy >B oF eo S 519 sS8 ° ewe ae 4 rs) Dm ae oS Chinook Texts by Franz Boas. Contributions to North American Ethnology, Vol. 1x., 1893. List of the publi- s of th cation e Bureau of Ethnology by V. Hodge, - The Maya Year by Cyrus Thomas. The Pa- . munkey Indians of Virginia by J. G. Pollard. The Bureaw Chief of Engineers, Me Ba : ey ea We Topical Index te 8 , Vol. u1., 1888-1892. Annual Come ePort for 1894 ce six ae rts). The Department mmmissioner of Education. ig for the year rag ols., aoe Nos. 211, 2 e Commissioner us S. Departmen t of yeti cay cena of Ornithology , Mammalogy—North Am Fauna, No. w and Annual Sum mary for 1894. Report of gic Chief of the Weather rg for 1893. Report of th Agriculture, 189 of gricultu Sectio eign Mar i Bulletin, No. 4, 1 .: ircular, Nos. 1, 2,3, 1895. The Department partment of the Interior (C fice). Com oo of the Eleventh Census, 1890, Part ii. Report on Indians taxed and Indi t taxed in a United States (Ex- ce ; rt on Insurance Busi in hese States, Part I. Fire, Marine, and Inland Insur- ce at the Eleventh Céabes 1890. Report on Popu- lation and Resources of Alasiw at the Eleventh Census, 590 ADDITIONS TO THE LIBRARY, WaAsHINGTON—continued. U.S. Geolo seal nites. Annual or og (ie ihe Parts i., Hat gree 1891- ~~ ae aS, oy letin, oF Min Nos. he ae oe peng "i kaeanka Vols. XIx., ng 5 eee 1892-93. The Survey meee of the Mint. Annual Report (22nd) for the fiscal ended June 30, 1894 The Director National Academy of Katctusen. Memoirs, Co vI., 1893. i Nav See partment —Office of Naval ee Notes the r’s Naval eae July 1 The Department Aikiwinian Institution. nual el of the Board of racy or for rig oy aie ly 1893. Circular No. Dia a Journey sieoad Mongolia and Tibet i in n 1891 a 1893 by W. W. Rockhill. Report of he U.S. National Museum 1891-92: Smithsonian Con- tributions to g peterrseam No. 884—[The Internal Work of the Wind by S. P. ‘Lan gley]. Smithsonian Miscel- laneous Collections, Nol. xxxv., No. 854; Vol. XXXVIIL, ‘ No. 970, The Institution Treasury Ste ment. Annual Report of the Secretary of the Treasury on the state of the Finances for the year ee he Department U.S. Coast and Geodetic Survey. Bulletin, No. 1895 Report of the Superintendent for the Anon pe dine Fon 30, 1892, Part ii. ae Survey U.S. Hydrographic Office. Notice to Seprieinoninig Nos. 27 - 1894, and Index to Vol; Nos. 1 wo eg Pilot chee States and Canada, thir Erie and Ontario; Nos. 1494, : West Coast of Lower California, San Ignacio ay eT S. _Hydrographer War Department. Annual Report of the snciutacy of War for the year 1893, Vols. 1., 11. (Parts i. —vi.) Il., Me oll WELLINGTON, N.Z.—Department of Lands and Acatl Report of the Survey Department, N.Z. for 1892-93. Report of the Department of Lands and Survey N. 7, “for 1894-95. a The Land Districts, 1894. The Depart Mining Geologist. Older suriferous drifts Xt — ia ng Depa go, New Zealand I Institute. Bfa:se mga and Proceedings stitute (ND. VON x Polynesian Society y- Journal, Vol. ur., No. 4, 1894; Vol. ciel 3, 189 The § Winving“istarial pa Pager Society of Manitoba. r Nos 47, 1894. Annual Report fo the year 1893. 2 ZuricH—Naturforschende nc apegpegeronl Vierteljahrechett: Jabrgang xxxix., Heft 3 ; Jahrgang Xt., Heft 1, 2, 1895. Neujahrablatt, No "of, 1895. ADDITIONS TO THE LIBRARY. 591 MIscELLANEOUS. Ne a of Donors are in Italics.) Acland, Sir Henry W.., K.c —The oe of the Statue of Syden ie in in ths Oxford Museum, Aug : by the Marquis of Salisbury, K.c., with an s by. Annual Rao od the City Engineer—City of Newton, Mass. for yea The Engineer Aslan Anition for the Advancement of of the Fifth Meeting held at Adelaide, Fie F. Wiesener beta Medica Gazette, Vol. 11., No. 8, 1883; Vol. XIrr., tog he Publisher el Prt A. W.—Some recent evidence in favour e im- pact, 1894. Copy of lethoes sent to “ Pata on partial ee 1879. A New Story of the The Author ccm tba Roland— esata rae jen Assemblées ratiques en Sui 1890. Les Variations Pério- tigues es Glaciers ualeidis 1891. Une Excursion en Bourke, Capt. John G.—Folk-Foods of the Rio Grande Valley and of Northern Mexico. Popular Medicine Co and ‘Supersti Goin of the Rio Gr an The s of Spain in their application to the American tndians. ” Brown, Robert—Roberti Brownii Prodromus Flo Nov Hollandiae et <7 ulae Van-Diemen ge neie an Reprint) 4° Londini W. Woolrych ‘Cameron, Alex. M. igh as the Interpretation of “ at of Gravity, 1895 The Publishers Council, Edward —Maxins: political, philosophical and moral, (2nd Edition) The Author and Squier, Dr. G. O.—Experiments with a new Polashitne Photo-Chronograph, applied to the Measurement of the Velocity of Projectiles, 1895. The Authors Cudmore, P.—Buchanan’s oo acy. ae Nicaragua Canal and Reciprocity. New York, 1892. The Author Cunow, oo Sarwan iaciahie Ogeioe der Aus- negar n Serpentine pseudomorphs, and other og ag ‘the Tilly — feng ot Mine, Putman Co., d Meventaods, Cambrian an 592 ADDITIONS TO THE LIBRARY. Dana, ea James D.—conti rchean-axes of Eastern North America. Rocky Moun- mes Protaxis and the ing Cretaceous Mountain-making along its course. Som he features of non-volcanic Igneous s Hjections as illustrated in the four “ Rocks ” . ura-Trias trap-belts of "Central Connecticut, with e upturn re or mountain-making dis- farbance of the formation. On Subdivisions in Archean Philadelphia, 1 1852. U.S. Exploring oe X111.,:Par and ii., and ‘Atlas—Crust he Author Dresdner Journal, ay 107, 11 Mai, 1894. me pars eet — P. F.—A een on the Principle of Sufficient ason, 8° London, 1887. The Author Viitedtic, Dr, sagt Die eiheeistchirs Localabweichungen bei ree ne eg ihre Beziehungen zur dortigen—Local- Geinitz, i, i= OP ricwitks fiir eine neue Wasserwerks-aulage. uf Tolkewitzer Fiur bei Dresden Gengephisno a eae heraus. von Dr. Alfred Hettner, J: Ba ‘ se 1895. he Editor Heche erate us M:D,, L.D. Gelltribations to pare ; The Author Janet, oo sur wie -Spriecine Les Guepes and Les eilles, Notes 10 a & Katalog te “Puna el hea’ x ante Geographentages. os ae a | K. K. i. Astronomische Arbeiten, Band Iv., chair 1892. JW. 6 Klossovsky, Prof. A.—Organisation de l’Etude criti Spéciale de la Russie et probléms de la Meteorologie agricole. ~ - «Sie annuelle des orages & la ‘surface du globe terr he Author Kosmopolan, No. 25, a : 1895. The "Paiies Kuntze, Dr. Otto—Geogenetische Beitriige, 1895. The Author Mayr, Dr. shia von—Referat-Statistif der beutschen Binnen- erungen. blisher Medical Peter a Vol, 1., No. 11, May 1893 (4° London). The Pu ” Medical Press, N.S., Vol. ux., No. 2941, 18 Sept. 1895. Minerva, Ano 11., Nim 1, Marzo 1894, 8° Puebla. Modigliani, Dott. ira eyes dal-Danielli Dott Jacopo s tudiati dal Cra oon! ossa lunghe di Abitanti dell Isola Co aur Bognnge: The A Mullins, G. L., p.—Notes on Hydatid Disease in New South Wales’ 1895. Notes on Phthisis in op a South e Wales and other Austr siaatan Colonies. emic Diseases and their prevention in the Eastern Suburbs of Sydney, 1895. ADDITIONS TO THE LIBRARY. 593 Nangle, James—Roof Coverings. The Author Nowlan, James—Darwin’s ‘aun of the ——— of the Moon. sj Oliver, peste A, —A new series of Berlin wools for the cientific Relation of prac ormal eaiditene Wak feilbar blindness). Description indie a revolving astig- matic ulpha i ciliary muscle. Third Annual Report of the Ophthal- mological Department - the State Hospital at Norris- for town, Pa. the year ” Oserihiche ae admessungs- eer Spee eee Pro- Koll 11, 13, adie 1894. he Commission Peek, Cuter E., F.S.A.—Meteorological Onaeration at he Rou doa Observatory, Devon, for the yea poe oe 1894, Vols. x. and x he Author Puga, Guillermo B. Y.—T pestades del Fin del Invierno, 1895. _,, Ramond, G. —Geologie Asie et Océanie, 1891, Ramond, - — "ghia E.—A note sur la cloche gypseuse de Revue Tp des Alcaloides, Année iv., No. 37, 189% ris ‘Publisher Smith, J. 1p ieGarvie—Investigation of the composition of the air the Sewers of eeu y, with special reference to the presence of ger The Author Societa ar ratione Sauk in Africa, Anno x., Fase 5 The Soccety ia, New Ser., Vol. xvz., No. 8, 1895. The Publisher Todd, sir C, » K.C.M.G., M.A., F.R.S.—Meteorological Work in Aus- t ralia PA Beet The Anthor Transactions of the Bridie Association, Vols. x. - xrx., 1878 ~ 1887, 8° Plymouth, 1885-87. Extra Volume The Beachire Domesday, uiat: 3,4, ese k Rev. Dr. Harris, M.A.. Rev. James S., M.A., n Theory and Practice. The tend: ek a thes ae last in —. = tion considered. The Author ide, Henry, ?.x.s.—On the Multiple akon laa of the Atomic Weights of Elementary Subst: in relation to the unit of Hydrogen. 1895. On the ams afforded by nr law of a permanent ee ion of the Radii W; ectores of the Plansaey Orbit sy gee ‘D., M.R.C.P.— An gbalien of the fallacies of the terialistic ' Theory of Physiological Psychology, 1894. ,, White, Pi Donations To THe Socrery’s CaBrners, &c. Bh (fra (fra Ri eteg scacgy Men of Rejener of Pag at Titain livi n the years 1807-8. Hon E. Kater, M..¢. ay ofa ag a lightning two niilin long pies at the weary Observatory, 16 September, 1895. H. C. Russell, B.A., C.M.G., F.B.8e - Lande, 4, 1895, 594 ADDITIONS TO THE LIBRARY. Periopicats PURCHASED IN 1895. \merican Journal of Science and Art, engeras \merican Monthly Microscopicai Journa lys y Z Analys ‘Annales des — et de Physique. f An y: 4 .stronomischo Nachrichten. Athen ahs “Mining Standard. British Medical Journal Building and Engineering Journal of Australia and New Zealand. Chemical News. Curtis’s Botanical Magazine. Dingler’s Polytechnisches Journal. Electrical Review. Engineer. Engineering. f Rania and Mining Journal. Engineering eee English Mechani Fresenius Zeitschrift fiir Analytische Chemie. Geological Magazine. Industries and Iron. Journal and tan mec of the Photographic Society. Journal de Méd of Anatomy ‘and Physiology. B oS ail ne 8 the ‘Shenson Socie ournal of the Institution oF E trical Engineers Journal of the Royal Asiatic Aen of Great Britain and Ireland. Journal of the Society of Chemical Industry. Knowledge. L’ Aéronaute. Lancet. Medical Record of New York. Mining Journal. Nature. Notes and Queries. Observatory. Petermann’ s Erginzungsheft. etermann’s Resuraphlanen Mittheilungen. Frosedeas: Magazine. Proceedings cf the Geologists’ Association. anes Journal of Microscopical Science. ADDITIONS TO THE LIBRARY. 595 . rican tific Gece Supplement. Zoologist. Booxs Purcuasep In 1895. American Institution of ap tig i Sree Vols. 1. Annals of British sorime 4 y Blake, Vols. r. - Iv., 1890- 93. Australian Handbook, say: epee 6 R.—Technisch-Chemisches, Jahrbuch, Vol. xv1., 1893-4; Vo 894-5, Brthwate, R British Moss Flora, Part 1 Braj — —The Retrospect of "Medicine, Vol. ox., 1894; Vols. cxt., British 1 actin Rep rt J ayn W.—Larvee of the Baltic Butterflies and Moths, Vol. v1., Part iii. Ray Soc.) Chalienger Report—Summary of Results with Appendices. oe ot fiir Analytische Chemie, Index, Band xxt. - xxx., ae ‘hada peony ae Origin of Plant Structures, 1895. (Inter. Sei. oe Se Index Kewensis, Parts i International Bcontitie rote ld Vol, LXXVII. Jahresbericht der Technologie, 1894. mene rar Pierre—Lectures on Diseases of the Spinal Cord. (New Syd. Soc. 0 Medico-Chirurgical nce Transactions Vol. txxvir , 1894. Nautical Almanack for Bist _Srdenham Boalety’s 8 Poldictien, Vol. ot., &e., Atlas of Pathology, esis es Vol. xxxvi., 1894. Pathan oerephical Society, V Society — atten ¥ Vol. xiv., 1894, ha Society’s Publications, Vol. vr., 1893. Deter Bpend der Diatomaceen-Kunde, Hef. 50. + Whitaker’s Almanack, 1896. Year Book of Scientific and Learned Societies, 1895. J Journal Royal Society of N.S.W, Vol. XXIX. 1895. Plate 1 {¥e. 2t Plotor. Blivateor) Diagram. iB Fo ~ jie "} r Serut holler fe re Ph Kenn g: checerriter Plate Il. iiwon screw gear J Mo. 21 Motor. i Plan } , Engune and Tank weigh 4S cuereces 2 : c nd Shaft : oS : es Baler and Connections * 18% j Burner and Spcrel Jank 3 # Water ; * 10 - Spirit ” bas 8 Total weight O56 Us- F7eunces ae 95 XU. 18 | Vo ciety of NSW, ete Se ral eine | us Pe { ore pug IW V2. W mal Royal Society of NSW, Vol. XX!IX. 1895 Plate IV. &lb. Calico Kite . ciety of NSW, Voi.XXIX. 1895. oya Soc 44th. Redwood Kite. Kite with springy paper sails Vv. . Diagram oyal B eciety of NSW, Vol. XXIX.. 1895. Plate Vi. | 3 3 : : 2Q3zeoz. hile. Kite flies from A to B.C%D. March St 1894 Journal Royal Saciety of NSW, Vol. XXIX. [895 Plate Vil t at -- Fate six =. Gena athe ienenenst anil ccinaak ee eee ee / a y (belivecre clecks } Gelweenr the Ueeght o Main -frame DRumnds sonnel « Booms & bah en a F Sticks : Se Bending vee ; Seay ee , Totul Weight ‘ : : 1 Diagram. Vil. 09 thekgoceeeer tl | | : rae Sn ereieeee Maipiueerreertne | . tin ; ae ! Boy aay mpygeD ‘ so 167 Plate IX... ls jewer) Fae Side View~ of Kites. Anemometer 16 Mare 166th Ww os ge ead co >< es P< “oO cs RB > Bligh ia). : yi | R . re fa ae 1 ny > rompers Broyry | 9 1118 |B ad '. ays YP Day ae . ' i? | mL] 09] 9 Jeo ; = agry my ayFron | oy cd a AIn|s o | uany pry Pypp 0 Juomeyowye so Pinjmiain|e o «| Teed ee 09 Revs | 2 ae 3 pus peomay my wor nung | Ql=| =| cjeler bad Sool Ina ad bo Ee) 3 eee ak oO £ i ELS] OL ep le WF Ny 2131 SISbvlo — & 2? yowe yo yyfaT > 2) g ut) co 8 : Bim] pap ecto. m~ oO Bilal of Belo oc 99 yowrje YIPOMT J) */ 2] Hela come \ &| =| =] m}ol}o ow | bs = re mercnatees Bae ot eins Ab AQYVININ Royal Society of NSW, Vol. XXIX.. 1895. oS Bg tor! idleton. RE eegr I. % Campdell I 2 ek 1 & Emerald I (D) (PD* Se «Wake 1 » Jokneton I DScdgjetman BP 9 gobs If @ Dawson Piempe? Radon 10° ® Legiep® * ew Year , Tydia's, SPpan tt * Kar pe) ‘ a bs ‘ MARSHALL I* : Etmore ‘Pedder peo pap ra alla Bingmon Sh . B Pi okt “aa ° “tone- — L Indiana Rr Touching? Matthew * Charlotte if $B _ Howland or _ GILBERT 1? Hopper Sahat Pleas «Ocean, & 9 ae Pr *YKean® 9 Phenix + 9S L. E owe vA sep 2 * ater fanny oD of Srk It WEN. eC ; Roof Carne F? L Tore |: ¥ = yl SS ‘6 #S*Cruz r eGHamron %, ay eas ry - ~~ ' *Tucopia sd Samoa or Nay; e: % 7. § 10 Py Banks It 5 Varna Lave p ~~ he M : : go, a “heer Palme, qtragura bia. Varo al te Hapai —_———_ Beveridge a = syfongatabu Pyltaart Ra ° ey Me Kast Lemgiemte 170" (a? m #8°9S-6) aa : “Fa HARoo, asl “Fo sarpwicu 19 -d bomen fuss THE /- Piva Revi Pe C. de Verde I* Pad Bronte Siin i Pabryra tS. — a9 mth vals "aaa “— ll ot in iiss 2 SST GE Rer 1, s padre! ; : Aree, Bom , © LoRe pe omumjed @ Filippo toe” ohggts B.Com poet 2008)" , fee Ascension I is te 1 daaaoad pence ame StPael a: Flint I. a howarrow) I* EAE NGS, ‘ i £. Belling shaie,, Ming Cte H “Sita Lit Fish e Sociog, * ace S Fabeaivun it *StHelene ‘oe “28, : ees < . i Tatakoto (3708) Gt Fish B. ee ES ae, a. — a ag nth Pe - Z Pray Pe aaigr Stier Be reads ida 2080) ae ee Saad P oo. ge ee Fs ee ys ta" we << MM ae Ss O U . H — *Dusie a gerne Ble cal fopa eo oMaretirt Ss 0 U su H P A C I F A a IL, A N T I C Maria Theresa Rs ~ imac “Nightingale I O C E A N | | g | | | | % | | VVDOGOODQDVVNDUY | 89 39 | } : 42 44 Lindsay ¢ ‘agure Yo £ © Nimrod. Group!D, © @ ae @ 9 ® Cy “()) “D) W) @ O “) — wi OO @ eat South a) 1 ds ce chs ® Ai) © @® ta, @ Nay) a ue _* 5 ee ‘ Cremation Pere 70 o ew ot sed ‘2557 atencaaes eee Sa ICEBERGS IN THE S$ 69 C. Gockdnrn. “hes Wes pt} pall Appearance of Lund i hasse “Ripa tioms 2 ? Yate ole I883™ ? ae ae iz (ee a Od © ®@ €@1{|@ vs 1888 1891 i892 1893 1894 | 1895 aa. Alaconder 18) le 160° 150° 40 130° or | 10" 100° 90° 80° Li 10° 60° 50° 4 30° 20° West Longimde 10° Merid of O° Greenwich 10° H 1 1 j An Aduirality Chart used PHOTO-LITHOGRAPHED AT THE GOVT. PRINTING OFFICE, SYONEY, NEW SOUTH WALES. Journal Roy. Soc. of N.S.W., Vol. XXEX., 1895, Plate X11. Wajanga eG es ze Setimanh § 69 - Desert, ¥ F Au . 2 we 4 sinan Str Tw Degres Chan $M ekar Nicobar i "9 z ‘ ESS 2d i : é Par “ ilo ia Ape aeare Natal? ce vf ck yy CSink BS Press vf FF F Wy : of a ys po y> # 3 * oa a ¥ » ¢ Christmas Le . <1 ¢Xentonge si SW A Ko CO% rae lel nieeee ca ote DAGASCAR pz, Maire ————— “2 Mauritias ——— st ‘3900 heurt Reanion ne hoose; ae WS Heard I. OUTHERN OCEAN Ts x se oe see Barrver and igh vail es ed > Od gd By i 3 Kerap Laad H.C.RUSSELL GOVERNMENT ASTRONOMER SYDNEY ast Longitude 20° 30° 40° al 60° 70° 80° od 100° Neg 120° ymal Royal Society of NSW, Vol. XXIX. 1896 : Plate Xill * PlateXlV. ty of NSW, Vol. XXIX. 1895. Pin Royal Socie Plate XV. Tournal Royal Society of NSW. Vol XIX. 1895. Journal Royal Society, N. S. Wales, Vol. XXTX., 1895. [ENGINEERING SECTION. | Fate |, 4 4 ; PLAN Of STRINGER a a 2" | i Pi Mew BO Me (ge 2e72-95-6 } Journal Royal Society, N.S. Wales, Vol. XXIX., 18965. [ENGINEERING Section. | PEATE 2. SECTION a Neatee _. d O sate \) eis ‘ renege yl cat Bs aR a Be ll uh SuPer + three WEES: SPIN GE Pa Oa SS SS persess | eae =i + —____<—____+__1— . pone Pe = Bees SS SS SS ; : & Selgin i es Pea nae Tet ey ; ¥ oF ¥ ; iis I. ee , a> nanan = ———. -€ — ee ——e——- —-— 00: 6 ~-—- ae we —-— -—— ¢ — -~- &F&— ~ ae aencenctlath deemed + - ———— ' ist RENE R ep tine eTo EM SEN 2 STS RPE str BF YY ae eet 4 aT aaa apie telepsrashccti ere aon sa SiSe 5 EY Siem Ss a 7] a | |S esc Leeann Ss ROSS LS a ne, IX yn : LEER SECTION AA secTION Be : PLAN OF DISTANCE PrEcE F SCUPPERS BD id Seale | tw linsh per c Tress S; Aporarch Spaws oP (9e272-95-6) Journal Royal Society, N. S. Wales, Vol. XXLX., 1896. : [Eneinkerine Sxcrion. | ee ? PLATE 3. ai ea ————_ tt a oe Mp apne sg ngs yoga ELEVATION PSUR eee Saas, 1. PEER ee Fe sD) eterna A i = we aay AA eT 7 a rH I . ys A a a LAP PH Cre. OM SORBATE Se IL SP AIS BT ais - COVER PLATE Fon Ter cHoRD COVER PLATE Fon seTTOM CHORD i req? | ‘ Ca : ' ‘ ve te ce yy eee Pll ate ome | : ane 44° - 5 i ee Less ee 5 — TURMED BOLTS — seus — pate panne a ange? RRR Camel ae ANOLE narleianni —_. eee DEPARTMENT OF PUBLIC WORKS ne ne PT ete q { 9€272-95-6) Journal Royal Society, N. S. Wales, Vol. XXIX., 1895. [ENGINEERING SECTION. | RS Tr ee eye eee ee eae eee | | | | | . | 7 | | I. | | | | bs | l | | | a } | | . l Se. a ene, | ‘ Lt. | | | l | | Ee | [ee | | a | | | | | l | 48:51 | 37-72 ag pre fs | 62-37 | 69:3 Fy fe ce + 21-T2r0ns 10 {9e ee ae oe gernorens cere Re ee en = 20-79 Tons aaa -—-—:—- > k— - —-— -7 13°86 tons 30'—-— -— — 6-93 Tons 10° | Journal Royal Society, N. S. Wales, Vol. XXIX., 1895. [ENGiNEERING Sxctioy.] PLATE 5. FIG. 2. ( 92272- 95-6.) scone Journal Royal Society, N. 8. Wales, Vol. XXIX., 1896. [ENGINEERING SEcTION. | PLATE 6. ak Pe Saal ar gerne: © 4 ae LT SECTION AA. 39.9" 4 aie - ee —3 0 —- —Hs i "Oe 2722-95-68) Journal Royal Society, N. S. Wales, Vol. XXIX., 1896, [ENGINEERING SxcrTion. | PLATE Ne =~ Zs }}) Vy, Mf Mii > | BRR hs PY SL} =r Tipe = N u ZN Fail | (9€272-95-6) Journal Royal Society, N. S. Wales, Vol. XXTX., 1896. [ENGINEERING SEcTION. | PLATE 8. —= DIAGRAM = —= OF @& —" ANNUAL CHARGES — ————P ® Gime IRON BRIDGE TIMBER BRIDGE SHOWN THUS SHOWN THUS MAINTENANCE INTEREST RENEWALS TOTALS o> 9e 272-95-6 Testa Le q 4 eran ie : Peas = Tee 4 Journal Royal Society, N. 8. Wales, Vol. XXIX., 1896. [Eneinrertne Section. ] N —-FASCINE WORK— Bae —— CROSS SErION: OF ORDINARY DYKE— ———~- CROSS| SEC TION <.. ORDINARY cyace— —— WiTH STRE si AOE = 1 foe ———--— Bes o-# : - = . 60 ' i — lc a ee - ee aes Faas Severs = ~ . SS HN AVAL SH SSS S — \\S ANN = NX aa see te c- Otte LWILS, 3 _ Exccratea trench 18f wide —— CROSS SECTION OF LONG COVE CANAL — —_—————————— AFTER SUBSIDENCE ak 4} a" ao m } HW. M.S. T. RiL.-$0.00 wal "s Taseine ie Ai hana eM, | 4 L WMT. ee eons and. ai no, : | so ze | i en oN S| S20 c ve dl s298_ | : ar. q 59-8! Ge 1 ‘ 2" . S HO} td 3 . 40 yy 7 ie I; ie SOFt hal, Batra is High Watr 4 7 4 7 ne is SOF? balow some Journal Royal Society, N. 8. Wales, Vol. XXX [EncIvEERING SzcTron, ] Sos Hokk PLATE 10. Soha Xe onahet Meo yy Kange Ke Sele r™ «\ Spek 4 TIMBER BRIDGE CONSTRUCTION IN NEW SOUTH WALES By Percy ALLAN, Assoc. M, Inst. C.E. [With Plates 1-8.] 4 [Read before the Engineering Section of the Royal Society of N. 8S. Wales, : September 18, 1895.] _ Tue necessity for the economical designing of timber bridges in the Colony of New South Wales, may be gauged from the fact, a that in the last ten years some 680 timber structures have been erected at a cost of £634,000, so that any economy in a type - design means a very large saving in the annual expenditure of _ the Colony. For many years Plate 1, was the type of truss for 69 feet, 75 feet, 90 feet, and 100 feet spans. The defects in this design may e briefly summarised—weakness in suspension rods, no means of taking up slackness in braces, caused by shrinkage of timbers, | and tendency of top chord to incline inwards owing to want of lateral stiffness. Although this type of truss has for many years carried the traffic without accident, yet in view of the increase in settlement and the greater risk of the structures being subjected to heavier oads, it was thought desirable in 1886 to adopt the design shown in Plate 2 for 65 feet, 75 feet, and 90 feet spans. _ These structures were designed for a distributed live load of & bs. per square foot of roadway and a traction engine weighing 16 tons, on a 10’ 4” wheel base having 94 tons on the leading Wheels, The improvements in these trusses are the increased sectional ‘Mea of suspension rods, the providing of means of taking up slackness i in braces, increased lateral stiffness imparted to truss 1—Sept. 18, 1895. is PERCY ALLAN. by splaying principals, the introduction of iron in lieu of timber side braces, the more general use of sawn timber free from heart, and the more effective splicing of chord. In 1823 to replace the 1886 type of truss bridges, Mr. Hickson, M.I.C.E., Engineer-in-Chief for Public Works for New South Wales, approved of the author’s designs for new standard type of truss bridges for 70 feet and 90 feet spans, Plate 3. The’ 90 feet span is designed for a traction engine of 16 tons and a distributed live load of 18°8 cwts. per foot run, or 74 cwts. per lineal foot more than for the 90 feet truss bridge previously in use. The truss is divided into nine panels of 10 feet with a depth of 13 feet measured between centres of triangulations, and carries a 15 feet carriageway and two 5 feet footways. The timber generally employed is tallowwood for the planking and ironbark for the stringers, floor beams and trusses, the timber in trusses being cut free of heart ; but in many districts the local timber, with a somewhat shorter life could be used for the planking and stringers. The flat decks in the old type of bridges, resulted in water lying in pools on the surface of the planks, more especially in the centre of the roadway, where the wear is greatest ; 3 inch scupper pipes along kerb line, even if not choked up, are therefore of little ‘service. To provide against this a camber of 13 inches in cross section of deck is provided in the new type of bridge, permitting of the quick escape of water through the large gratings at ends of spans. Unlike previous designs, 4 inch transverse planking spiked to longitudinal stringers has been adopted, thus permitting of shorter lengths being obtained at a cheaper rate and of their being replaced with less trouble than diagonal planking. Longitudinal stringers varying from 103” by 5” to 9” by 6” (to give camber in deck), pitched 3 feet apart, are bolted to the floor beams, in lieu of the intermediate floor beams used in all previous designs, effecting a saving in cost, and permitting of the conceD- — TIMBER BRIDGE CONSTRUCTION IN N.S.W. II. trating of the loads at the apices ; thereby relieving the bottom chords of secondary stress. __ Inall the old types of trusses, the suspension rods passed through | ‘the floor beams, and as the braces were also butted against the ' floor beams, the renewal of these timbers was rendered practically out of the question. In the later design, Plate 3, the floor beams 15” by 12° spaced 10 feet apart are placed between the suspension rods, ‘admitting of easy renewal, and at the same time saving the expense of boring large holes through floor beams for the passage _ of suspension rods. - With a view to renewals, the horizontal thrust from the braces “is taken up by means of castings, having lugs 14” deep let into - the chords, and where two lugs are necessary it will be noticed that the deeper lug is at the back of the casting, so as to distribute the thrust over a larger area and reduce the risk of failure by = ‘shearing between the lugs. 7 ; The advantage in using castings in lieu of a number of timbers bolted together to form butting blocks for the braces, is the doing Way with to a great extent of one of the most troublesome uestions in connection with timber bridge work, viz., the lodge- ment of water. No matter how carefully the timbers may be bolted » seed and reaiact water will, ae a aber time, find its way bet ffects; again, in the endeavour to get a a joint sine ve ee surface the butting surfaces will oftentimes be made slightly concave, in such cases when the water does penetrate—there being no escape the evil will be intensified. The batter braces, which consist of two 14” by 6}” timbers wed and stiffened with hardwood distance pieces have been tituted for principals ; thus reducing the horizontal thrust to such an extent as to permit of the introduction of castings lieu of the large timber butting blocks, with the heavy bolts, ‘Previously necessary. IV. PERCY ALLAN. In most of the American Howe trusses counterbraces are introduced, with a view of stiffening laterally the main braces, however the braces in the truss under consideration are compara- tively short, and as columns require no lateral stiffening ; counters in the end bays are therefore not provided. As all the braces in the truss are at the same angle, any shrinkage in the timbers can be taken up by means of the suspension rods ; the iron wedges in the 1886 design are therefore not arranged for in this later type of truss. The main braces are formed each of two timbers 8” by 42” bowed to prevent warping and twisting and connected together with bolts and hardwood distance pieces, all the timbers being connected to the cast-iron shoes at the top and botton with f° bolts. Formerly it was the practice to have the top chord in one piece 16” by 14” by 42’ long, which having to be bored for the suspension rods, rendered renewal very costly, if not impracticable. As one of the objects in designing a new type of truss was to permit of renewals, a chord, consisting of two timbers 14” by 63” bowed and stiffened with hardwood distance pieces was adopted, thus securing better timber and giving greater stiffness as @ column. The side braces adopted in previous trusses being a source of inconvenience when footways had to be provided, the author decided to design this chord as a column with a varying load, unsupported in a lateral direction; none of the text books however, consulted by the author treated of such a case. The stress in the top chord of a 90 feet span ranges from 69°3 tons in the centre to 27-72 tons in the end bay. As the maximum stress extends only over a length of 10 feet of the chord, it would be obviously incorrect to take this stress 0D a column the total length of top chord, nor could it be assumed that this maximum stress was acting only on a column 10 feet long. ; TIMBER BRIDGE CONSTRUCTION IN. N.S.W. V. The author therefore has dealt with the case in what he submits, isa practical way of looking at the question. _ Starting with the end bay there is a stress of 27-72 tons which _ extendsfor the whole length of the chord (70 feet). Taking the least di meter, the ratio of length to least diameter is 48 to 1 and the ultimate buckling strength of a timber column of this proportion, ing 2-36 tons per square inch, the area required on the point of buckling would be 11-74 inches, whilst at the ends of the column the area required, when on the point of failure by direct crushing would be 5-87 inches. ‘Setting up these ordinates and plotting in as a parabola, the area shown on diagram, Plate 4, is obtained ; in the second y the stress is 48-51 tons extending for a length of 50 feet but as part of this stress (27°72 tons), has already been vided for, it leaves only 20-79 tons to be dealt with ; ing the ratio of length to diameter this gives a column he proportion of 36 to 1, requiring an area of 6°77 square es when the column is on the point of buckling at the centre, an area of 4:4 square inches when on the point of failing by t chrushing at the ends, the required additional area being © on the diagram, Plate 4. Th the third bay there is a stress of 62°37 tons extending over distance of 30 feet, 48°51 tons of this stress has already been ealt with, leaving only 13-86 tons to be provided for, proceeding s before, the area shown in green is arrived at ; in the middle bay € stress is 69-3 tons extending over 10 feet of which 62°37 tons been provided for, leaving 6°93 tons to be arranged for. The whole of the varying stresses having now been dealt with, is heavy dotted black line, represents the total area required When the column would be on the point of failing. The actual net area of timber provided is 156-16 square inches, te 4, and as the maximum area required at the centre is only “09 square inches, the column has a factor of safety of 6°6 buckling, irrespective of the stiffness imparted by the Ying of the feet of braces. VI. PERCY ALLAN. The bottom chords of the 1886 type of trusses for 90 feet spans 14” by 18” were built up of four 14” by 44” flitches, planed on all surfaces to ensure good butting, the whole being drawn up with § inch bolts. This is a costly and undesirable design of chord, offering as it does, after a few years, an entrance for water between the flitches, causing decay, which is especially serious on account of the design of truss being such that the bottom chord cannot be renewed, thus necessitating in some cases the replacing - of the whole structure, which under other circumstances—with a few new flitches—might have lasted for several years longer. _ Again, some of the flitches are 53’ 6” long and, having to be free of heart and sapwood, are difficult to obtain, and this oftentimes occasioned delay in the erection of the structures, the simple-minded sawmill proprietor supplying all the short and profitable sizes in the bridge, and then pleading inability to supply the more costly flitches. The bending stress in the bottom chord of the new truss having been eliminated by the omission of intermediate floor beams, only a direct stress has to be provided for, resulting in a considerable reduction in the sectional area of the bottom chord, which consists only of two flitches 12” by 5” placed 6 inches apart, thus being _ always accessible to the brush, and permitting of the renewal of these important members ; again, the longest flitch is only 36 feet, a length easily procurable. Perhaps the most important connection in a timber truss is the bottom chord joint. Plate 5, fig. 1, shows the eover adopted for the very old types of truss, which can at a glance be seen to be of little assistance in making up the loss of section caused by the joint in the chord. Plate 5, fig. 2, shows the cover used in the 1886 type of truss; this is a much superior connection, but is expensive and difficult to fit. Plate 5, fig. 3, shows the cover adopted for the new type of truss. TIMBER BRIDGE CONSTRUCTION IN N.5.W. VII. ___ As the two flitches in the bottom chord are independent of one another, the whole stress in each flitch has to be taken by the two 12” by 3%” wrought-iron plates placed on either side of the beam ; on each of these plates four wrought-iron strips 12” deep _ by 13” wide by 1” deep are rivetted ; these strips are let tightly into the timber and are designed’to take up the whole of the _ stress, and as the stress in each flitch is 31°18 tons and there are four strips giving a total bearing area of 48 square inches, the crushing strain is only -65 tons per square inch, thus giving a 4 factor of safety of 7} against crushing, whilst for shearing along _ the grain a minimum factor of 15 is provided. Following American practice, the bolts passing through cover : plates are not in any way relied upon, being simply provided to j keep the plates up to their work, however as the bolts had to be _ provided the author determined to obtain the benefit of them, and "arranged for the bolts to be turned and passed through drilled _ holes in the plates. | te The above joint has also met with the approval of the Engineer- — in-Chief for Railways and has been adopted for some of the Proposed bridges on the Narrabri-Moree line, whilst in some of the later American railway bridges it has proved successful, ’ despite the fact of it being necessary in some of these pine : bridges to arrange for fitting in, eight strips in each plate, instead of four as shown in Plate 5. _ With this joint, requiring as it does only a straight cut, no difficulty is found in obtaining an almost perfect bearing with ironbark timber, and so far in the 146 joints in the bridges Already erected in this Colony, no trouble has been found in effectively making this connection. _ The suspension rods, which in the author’s design of truss have 4 minimum diameter of 2” and 1}” respectively, are placed on - tither side of floor beams, and pass through the space between the : chords, thus saving the boring of holes through chords and floor VIII. as PERCY ALLAN. beams, and permitting of easy removal in connection with the system to be adopted in renewing chords. One of the features of the new type of truss is, that any member can be renewed without staging from below, a matter of import- ance when deep gorges or fast running streams have to be crossed. Briefly stated, the top and bottom chords being in two pieces, the Suspension rods are removed and re-arranged so as to throw the whole weight on one flitch ; there being no strain on the remaining flitch, any member of the top and bottom chord can be replaced with sound timber ; and by slacking the suspension rods and inserting temporary struts, any of the braces can be renewed, whilst the renewal of the cross girders is obviously a simple matter. In the superstructure of one of the new 90 feet spans carrying a 15 feet deck, there is 500 cubic feet less timber than in the 1886 type of truss, which, in conjunction with the greater ease in framing together (notably in the bottom chord, where no fitting is required) the fewer bolt holes to be bored and the short lengths of timber employed, effects a saving of over £100 in each 90 feet span. The economy is more marked when it is considered that the old trusses were designed to carry a 15 feet carriageway, whereas the new trusses are designed to carry two 5 feet footways in addition to a 15 feet carriageway. Thus it will be seen that the later design of truss bridge offers greater facilities for traffic at a much reduced cost. The piers carrying truss bridges vary in accord with local Mea cumstances ; one of the heavy type is that shown in Plate 6, Consisting of nine vertical piles 12” by 12” arranged in groups of four under heels of trusses, also one short vertical pile upstream and two short vertical piles downstream, carrying up and down- stream struts. The pier is stayed with wales and braces 12” by 6” and internal compression struts 12” by 12” seated on hardwood chocks secured to piles with bolts, the chocks being set end on t0 do away with shrinkage, the previous system of seating butting TIMBER BRIDGE CONSTRUCTION IN N.S.W. Ix. 3 blocks on the wales not being satisfactory, the blocks shrinking q away from the struts, resulting in a slackness in the bracing. At Glennies Creek, near Singleton, the superstructure of one of the 90 feet spans cost, erected in position, £450, whilst in the : ag bridge a pier of the design above described 28 feet 4 inches F high from bottom waling to capwales, driven about 16 feet to 4 tock, cost £200. The timber for this bridge was brought from : pepe Hawke to Newcastle by sea 61 miles, thence forward by . to Singleton 49 miles, thence by road 9 miles, or a total ‘ carriage of 119 miles. _ & Late in the year 1892, it was decided to erect a new bridge over the Murrumbidgee River at Wagga Wagga. Designs were ; pmitted for a light iron lattice girder bridge, carrying @ timber deck resting on iron croés girders, but the amount available being : insufficient, the author’s design for a timber truss bridge was : decided upon, and a contract for construction let to Mr. 8. Stokes on 4th October, 1893, at shedule rates, totalling £12,604. aring completion, and, reckoned by by far the largest a short description trusses, forming e: As this bridge is now ne . floor space per span (3,165 square feet) is 4 timber structure yet attempted in the Colony, aa be of interest :—The bridge consists of six timber Yesting on iron cylinder piers and concrete abutments, ” centres, also nine approach spans each and three spans each of 110’ 3 of 35 feet. The trusses stand 27’ 1” apart, centre to centre, “are connected by a top and bottom system of lateral bracing, 4 angle and portal brackets being introduced in the top system. ; Each truss contains seven panels of 15’ 9° and being 21 feet deep between centres of triangulations enables full provision to be - Mnade for a loaded wool waggon, which requires 17’ 6” head room. : The truss spans are designed to carry 4 distributed live load of 1-2 tons per foot run, or a concentrated load of 16 tons. ‘The carriageway is 24’ 4” whilst one 4 6” footway is arranged _ for, so that the requirements of the wool traffic will be fully met; _ ® wool waggon measuring 11’ 6” when loaded and 6’ 6” when empty. ey i eterna ge tae PRN ee ghee ia td rere. a VES ey ee oe x. PERCY ALLAN. The wind pressure allowed for is 56ibs. per square foot, on the exposed surfaces of kerbs, stringers, and ends of planking, and on twice the area of the handrails, ends of girders, top and bottom chords, braces and verticals, the whole being taken as an uniform moving load. : Whilst the author is aware that on the occasion of the Dandenong gale, September, 1876, the wind is recorded at the Sydney Observatory to have attained a velocity of 153 miles per hour, equal to a pressure of 115ibs per square foot, yet the author considers there would be no justification for assuming that such a phenomenal pressure would extend over such a large area as that occupied by such a bridge as that under consideration, and — in support of this opinion, points to the existing structures throughout the Colony, few if any of which would be now standing if ever subjected to anything approaching even the pressure allowed for in the Wagga Wagga bridge. The minimum factor of safety adopted for timber in the trusses is 7 for the stresses due to combined dead and live loads. Although this factor may appear to be somewhat liberal, yet it must be borne in mind that the ultimate strength of ironbark has been taken from tests made on small specimens of picked timber, and that a reduction in strength is only to be anticipated in large scantlings, again the flitches being sawn, the grain will run more or less across the line of the sticks, and as defects in timber are so liable to escape even the most severe inspection, it is necessary, in the opinion of the author to make a liberal allowance to cover such contingencies. The floor system adopted in this bridge presents some novel features, which, so far as the author is aware, have not previously been adopted in any structure in any part of the world. (8 Plate 7). The main points kept in view were :— Ist. The necessity of having a camber in deck to permit of the quick escape of water. ‘ 2nd. The desirability of having a lower lateral system Of windbracing, so arranged that the triangulation lines of the TIMBER BRIDGE CONSTRUCTION IN N.S.W. XI, windbracing and the triangulation lines of the truss members would intersect at a common point in the bottom chord. 3rd. The distribution of the load, so as to get each pair of the floor beams to act as one. 4th. The necessity of concentrating the loads at the apices, as, with the Section employed, two 14” by 7” timbers, no additional stress was permissable in the bottom chords. The deck adopted consists of 4” tranverse planking spiked to 12” by 6” longitudinal stringers, seated on the lower lateral struts. The lower lateral strut is 12” wide by 8” deep at centre, adzed down on top surface to 6 inches at ends (to give camber in deck), the centre line of strut being placed in the same plane as the centre line of the bottom chord. The ends of the lateral strut are secured to bottom chords by wrought-iron brackets, and to these brackets are attached the diagonal tie rods, the centre lines of which, if produced, would intersect at the centre of bottom chord; the triangulation lines of the wind-bracing and truss mem- bers thus intersecting at a common point and avoiding all bending stress. The lateral struts are tightly dapped one inch over nine 12” by 4” sawn packing blocks 2’ 5” long, resting on the floor beams. These blocks not only pack the lateral struts up to the same plane as the centre line of chord, but what is of just as much importance, equally distribute the whole load over the pair of floor beams. ; With a panel length of 15’ 9” and a span of 27 feet the resulting load is so great as to necessitate the use of two floor beams, each 14” wide by 16” deep, spaced one inch apart (to permit of a current of air and avoid boring for stringer bolts), and connected together with 11 {” bolts passing through one inch cast-iron distance washers. As the overall width of these two floor beams is 2’ 5” it was impracticable, without fouling the braces and suspension rods, to rest them on the upper edge of the chord. They are therefore xi. PERCY ALLAN. suspended from the chords by sixteen beam hangers 1} inches diameter passing on either side of the flitches of chords. The author is of opinion that for timber railway bridges of large span, the floor system above described offers some advantages, inasmuch as shock from trains would be reduced by the lateral strut and distributing blocks acting as a cushion ; whilst the beam hangers being so short a large allowance could economically be made for dynamic action, which: action would be materially lessened by the time the main suspension rods were reached. In connection with the construction of timber bridges, the financial aspect of the question is of the utmost importance. Like all engineers, the author would prefer (if economy had not to be considered) to construct metal bridges, but in a new Colony where the trend of the traffic is likely to be diverted by many circumstances, difficult, if not impossible, to anticipate, it would seem preferable in such localities to construct timber structures with a small capital outlay, rather than spend large sums on works of a more permanent character. For many years there has been a disinclination in this Colony to build other than permanent traffic bridges out of loan funds, yet as harbour works and railway works, in which timber struc- tures, sleepers, fencing, etc., represent no inconsiderable portion, are built out of loan funds, the author submits there is no reason why traffic bridges should not also be constructed out of borrowed capital, provided it can be shown, first, that they are more economical not only in prime cost but in annual charge, and secondly, that provision be made for their renewal or repayment out of revenue. It may be urged in these days of cheap steel, that it is against the practice of other parts of the world to construct timber bridges, but in what other country could be found timber with a tensile strength of 8 tons per square inch, a crushing strength of 47 tons per square inch, and a shearing strength along the grain of 1 ton per square inch ; or bridges totally unprotected from the TIMBER BRIDGE CONSTRUCTION IN N.S.W. XIII. weather with a life approaching anything like, amongst others, the following :— a Bridge over Cox’s River, at Glenroy ............ 28 years old. Bridge over Bell River 32 years old. Bridge over Macquarie River, at Dubbo......... 32 years old. Bridge over Murrumbidgee River, at Wagga ...33 years old. Bridge over Duck River, at Parramatta ..... ...34 years old. Bridge over Cudgegong River, at Rylstone...... 34 years old. Bridge at Berrima 35 years old. Bridge over Murray River, at Albury............ 36 years old. The first metal bridge in the world, is said to have been erected over the Severn at Colebrook Dale in 1779, this bridge consists of a cast-iron arch of 100 feet span, the structure being thus 116 years old. Wrought-iron and steel bridges are however of a much later date, and the fixing of the life of such structures, is to a great extent only a matter of conjecture; in connection with this matter Waddell says, “There is no reason why a well-designed iron highway bridge—when properly cared for—should , not last for ever.” ‘Under loads which are light and slowly moving com- . pared with those of railway bridges, the iron cannot possibly wear . out, and when properly protected from the weather cannot rust.” The author therefore to make everything favorable to the metal bridge in a comparison of its cost, with that of a timber bridge, has assumed the life of the former as infinity ; whilst the timber __ bridge has been taken at only 25 years—a life—it is only reason- _ able to expect will be much exceeded, with the better type of Structure, the more careful inspection of timber, and the greater care in erection that now obtains. L The whole of the timber for the Wagga Wagga bridge was 3 brought from the Northern Rivers to Darling Harbour, about 150 miles by sea, thence by railway to Wagga Wagga 310 miles, ra total carriage of 460 miles. _ The contract cost for one timber truss span at Wagga Wagga | is £1,300 and the estimated cost of one span of the iron lattice XIV. PERCY ALLAN. girder design, complete on bearings was £2,800 (Colonial manu- facture). Now, to compare the relative cost of these two bridges on the basis, that the planking in each bridge will require renewal every 12) years, the remaining timberwork every 25 years and that the ironwork is everlasting, it is necessary to ascertain how much per annum it will take to keep these bridges “ traflicable” for ever, in other words to ascertain how much per annum it will cost in each case for interest on the prime cost, tarring, painting, removal of old material and renewing of each portion as it wears out. Having obtained the annual charge for each bridge, the difference represents the saving effected. The comparison is as follows :— ANNUAL CHARGE FOR IRON DESIGN. : | a a Fund 4 zs 3 . Hom. = jPriage),; Tutercet. BP ant renewal of | 84 sda peop timber. a | Rate | Amount. al Life. | Amount. a &., £ dj£s.d.j£ s. d. Planking...| 180 4°), 7 4 i £220 brig yrs. |13 18 Bshesiee 21 2-2 Stringers --| 1380/4 5, | 5 0} £17 4D Bhi, aves 9 5 8 Ironwork.../2490 |4 ,, [99 is ce) rit i Imai Nib Tae 99 12 0 Painting ...|...... ‘| 60 0 260 0 2 | eine oe £12800) Total annual charge ... £190 0 90 0 0 ANNUAL CHARGE FOR TIMBER DESIGN. a nee Be Fund me FS a a Pee | Pca r | dsj eae : a ea | Rate} Amount.| & oe om a oe £ £8, d. £s. difadj/£ 5. a mking..., 180 |4°/,) 7 4 0 £220/123 yrs.|13 18 2......... 21 2 2 Stringers, sses, floor-beams and re- mainder of timber ij superstruc- Ure «....... 630 |4 ,, 125 4 0) £950/25 ,, (2216 3)........48 0 3 Ironwork...) 490 |4 ,, /19 12 0| Nil. |Infinity) Nil. |.........19 12 9 Painting ...)::../: : WecdT vnrsan 51.5 751.5 7 £/1300 Total annual charge ...... £140 0 0 TIMBER BRIDGE CONSTRUCTION IN N.S.W. XV. Thus it will be seen that there is a saving of £50 per annum in favour of the timber bridge, which has at 4 per cent. interest, a capital value of £1,250. See Plate 8. The author has also designed timber trusses for spans of 130 feet and 153 feet. The latter truss altogether differs from the Wagga Wagga bridge, four flitches instead of two being placed in the top and bottom chords, and as for purposes of renewal a larger sectional area is provided than is actually required for direct tension, the floor beams can in this case be seated directly on the upper edge of the bottom chord. The flitches of chords being spaced only three inches apart whilst allowing of a free current of air, and room for painting, permits of the adoption of channel iron gib-plates for suspension rods in lieu of the heavy forgings used at Wagga Wagga, whilst the castings are, from the same cause, much lightened. Again, in the lower lateral system diagonal timbers and trans- verse tie rods have been arranged for, which is somewhat more economical than the diagonal tie rods used at Wagga Wagga. In conclusion the author desires to record his acknowledgments to Mr. Hickson, .1.c.£, for his courtesy in lending models, plans, and photographs to illustrate the several works mentioned in the foregoing paper. DIscussIoN. Mr. Deane said that in a design for a timber bridge, in the first place there was the proportioning of the amount of material in the trusses, and beams to the strain to which they were sub- jected. That of course should be made as near to theory as possible, although it was hardly possible to strain right up to theory. The different parts should be capable of separate erec- tion, and ought to be put together in a proper manner, for instance, the trusses should be stayed, and should be capable of erection separately ; they should be complete in themselves, and braced together before any attempt is made to put on the plat- XVI. DISCUSSION. form of the bridge. After the trusses are erected then the platform should be added. The old practice used to be on the interlacing principle, leading to something like a Chinese puzzle, and very difficult to deal with in case of renewal. Another point to be considered was the replacement of the separate pieces of the truss, one or other might decay, and they ought to be so fixed that these particular pieces could be easily taken out, and what was of great importance, was the construction of the joints, so that there should be no lodging of water in them, and that they could be examined, and attended to when necessary. With regard to the comparison of the cost of the bridge, the illustration — of which the speaker exhibited, with that of Mr. Allan’s, the conditions were different, as his was intended for road traffic, and the other for railway purposes. In the road bridge one of the largest items of expense was decking, which the railway bridge was made very much narrower, but having to carry heavier loads was much stronger. Mr. Burce—He intended to refer to-night only to the author’s comparison between the ultimate cost of timber as against iron or steel in bridge construction. With regard to the cost of the two kinds of structures, a comparison of which was shewn in the table exhibited, the quotation for iron was for colonial manu- facture. It might be the view of some people that it was a wise thing to pay something extra in order to encourage manufacture in the Colony, but the extra amount so given was given for that purpose only, and it should not be added to the actual cost of the bridge. Moreover, there was no doubt that Mr. Allan had proved his case, without thus surcharging the ironwork with regard to the preference of the timber over the iron bridge, but — if we came to smaller bridges the difference between the per- manent design and the temporary one was not so great. In preparing railway estimates he had made the following caleula- 4 tions, which illustrated these views :— Comparison of timber as against permanent bridge work assuming no repairs to latter, and in the former about one-fifth, ERG Yee eet Ee ST Lt 44i as ee OIE ee ee Te Mardy Se SST RENTS TY OREN Toe oe Ree ee ae ee WED ee et a RS Cree ent ie PY OS ONE Be ow MLE, Se TIMBER BRIDGE CONSTRUCTION IN N.S.W. XVII, that is the more exposed parts, required renewal in 11 years, and _ that the whole had to be rebuilt in 22 years—£100 is provided. £100 The permanent work is assumed to cost ... The timber work one-half, viz. ... 0... 0 see ee 50 Balance remaining, should the timber bridge be WOR occper vee ahaa vee Ne te ee eee Of this balance £7 is placed at compound interest at 47/ pro- ducing in 11 years £11, with which about one-fifth of the bridge is renewed—£43 remains which, at same interest in 22 years, becomes £102. The whole bridge is now rebuilt for £50, leaving balance of £52 by which the renewal fund is more than kept up. The depreciation is therefore about 4}7/ per annum on the actual capital expended. If, therefore, the permanent work costs not more than twice the timber work, it should be preferred from a financial point of view, independently of the objection, in railway work, to renewal as interfering with traffic. This is about the proportion of cost of small openings at 3ft. to 4ft. between concrete or brickwork 3 and timber. Mr. Sma said—one thing he noticed in the new design, was that any member of the truss could be renewed without staging below, while with the old. style of bridge when this was being done a temporary one had frequently to be built. The speaker mentioned that in 1876 he erected a bridge of the 1866 design, in which the very best timber procurable was used. It occurred to him then that from the way the bridge was designed, if any part had to be renewed, practically a new bridge had to be built. He thought it would be far better to build small bridges, Culverts, &c., with stone or concrete. Mr. BarractouaH said there was one point he would like to refer to, and it was the method shewn in one of the diagrams of treating the top member as a long column, and he would like to know if Mr. Allan had compared the method which he had employed with the theory of long columns, as the variable load 2—Sept, 18, 1895. XVIII. DISCUSSION. on the column in question would make the matter a very complex affair. Mr. SrarHam remarked that there were a great many points in favour of Mr. Allan’s design in comparison with the old ones. It was a great defect that so many timbers were in contact in the chord, the damp got into the joints and caused great damage, which practically meant the renewal of the chord, and when the chord was done the bridge was practically done, but in this new design there were a great many improvements. The new method of making up the top chord of smaller scantlings utilised the best part of the timber. Such bridges as these should last 30 years which was the life of the best ones. Mr. Simpson—One thing that struck him was the comparison of prices. It was not a fair thing to compare colonial iron work with timber work, because the former is not of the cheapest kind. He assumed that the price of timber work included the painting, at 4s. per cubic foot, and that of the iron was at 23s. per ton, erected. Then taking Mr. Allan’s margin of safety, he found that for the 90ft. span the price of steel work was 7s. per foot of the top chord, as against 3s. for timber, so that these comparative prices were in favour of timber. Personally, he would prefer to deal with a steel or iron structure. As regards the extra prices and renewals, a certain proportion of this timber work had to be renewed in a few years, and it seemed the renewal prices had == been calculated upon the same basis as for the original, which was quite incorrect. A timber bridge requires constant inspec- tion, which would add greatly to the cost, and for these reasons he thought he would prefer larger works to be of steel instead of timber. . Mr. Borer, in explanation, said that the Chairman had remarked upon the cost of renewals being taken as the same as the original provision of the timber, but Mr. Allan had provided for the extra cost. He had put down the cost of the renewal of planking at £220 as against £180 original cost, and of the rest £950 as against £630. As to his own (Mr. Burge’s) comparison; — Careeth a. poe Sos eae TIMBER BRIDGE CONSTRUCTION IN N.S.W. XIX. he had made no extra allowance in the railway bridge, and for a very good reason. The material for the original bridge had frequently to bear long road cartage, but the train brought the renewal mentioned to the spot at a very low rate. Mr. ALLAN, in replying, said that the exhibiting by Mr. Deane of the plans of the truss bridges to be erected on the Narrabri- Moree railway line, clearly showed how economically Australian hardwoods could be utilised for railway structures. Mr. Burge, whilst agreeing that in any case a saving in favour of the timber bridge at Wagga Wagga had been shown, thought the _ timber structure should have been compared with an imported : metal bridge. He could not follow Mr. Burge in this, the iron- work in the timber bridge costing £490 was not only manufactured but rolled in the Colony, the iron bridge was also stipulated to be manufactured in the Colony, therefore the estimated actual cost to the country, irrespective of colonial rate of wage, duty, or other similar contributing causes was, Mr, Allan held, the only basis on which a comparison could be made. He could not with confidence make any remarks on Mr. Burge’s comparison, as to the relative financial results of small concrete and timber railway culverts, without looking into the question. The experiences of Mr. Smail as to the difficulty of renewing tim- ber in the old type of trusses agreed with his conclusions. The complex character of the theoretical investigation of the strength of a column, carrying different loads throughout its length, remarked upon by Mr. Barraclough, was the reason of reference being made to the case in the hope that information might be given by some of the members on the question, The Author's practical method of treating the subject was based on actual experiment as to the buckling strength of ironbark columns of different ratios of length to diameter. Mr. Statham’s opinion that the using of flitch pieces permitted of matured timber being utilised, thereby ensuring cheap supply and increased durability, is of considerable importance, the benefit of which has been recognised in the new type of trusses. 2 DISCUSSION. The Chairman was in accord with popular opinion, that in the long run a steel bridge was cheaper than a timber structure, but the Author pointed out that this popular opinion only held good when pine or other soft wood with a short life was used, in lieu of the much more durable Australian hardwood, and that the Chairman did not support his opinion with the necessary tabulated statement, similar to that submitted by the Author, shewing the comparative cost of interest, renewals, and maintenance of a steel and timber structure. As previously reasoned, Mr. Allan considered it would have been incorrect to compare the Wagga Wagga timber bridge with an iron bridge based on imported prices, but even supposing it possible that by importing the iron bridge the cost could have been reduced by £1,000, there would still be a saving of £10 per annum in annual charge, equal to @ capital value at 47% of £250 per span in favour of the timber structure. As the decks in each bridge were similar, the incon- venience to traffic during renewals would be common. to both designs, whilst the timber truss members could at the end of twenty-five years (if then decayed) be renewed without -interrup- ting traffic. -FASCINE WORK as CARRIED OUT sy ran PUBLIC WORKS DEPARTMENT in NEW SOUTH WALES. By T. E. Burrows, is. (Communicated by J. W. Grimshaw, M. Inst. C.E.) [With Plates 9, 10.] [Read before the Engineering Section of the Royal Society of N. S. Wales, October 15, 1895. | Tue history of embankments for river training purposes in New South Wales, in which the use of fascines of Ti-tree, or similar a scrub form part, commenced as far as the author is aware only Rie geen: amas ah he Meee pS FASCINE WORK IN N.S.W. XXI. ten years back; but the principle of using fascines of a bushy nature, to bind clay or soil together, has been availed of in many and various instances, either for rough mining dams, or to form mattrasses upon which roads or light tram lines might be carried across swampy ground. Indeed the first fascine work with which the author was con- nected, was the construction of a temporary dam of fascines and untempered clay, at a breakaway in the town dam (on western end) at Parramatta about 1880; and owing to the force of the water, the river being in flood at the time, it can safely be asserted that only through the use of fascines, for binding the clay, and easing off the power of the stream, the work of repair to the main dam would have been much more expensive than was actually the case. Fascine work was introduced when Mr. E. O. Moriarty was _ head of the Harbours and Rivers Department, but the greater portion was carried out under the Engineer-in-Chief, Mr. C. W. Darley. The credit of the introduction of this class of work into New South Wales is due to Mr. Alfred Williams, M.Inst.c.E., under whom the author had considerable experience, and as Mr. Williams had the advantage of employing this description of river bank protection in England, at the river Severn ; where the range of tide is considerably more than our six feet, he saw to what advan_ tage such work could be put, in the proper alignment of our rivers with their unsightly, useless, and muddy Mangrove flats ; where the use of stone embankments would prove too costly to allow of the work being undertaken ; especially in such places were soft bottoms are met with, as the entrance to the Long Cove Canal at Leichhardt. . Two notable descriptions of fascine work, have been constructed under the supervision of officers in the Public Works Department, and these the author will designate as “ Fascine Embankments ” and ‘“ Fascine Wall.” XXII. T, E. BURROWS. Fascine EMBANKMENTS. The embankment work has been carried out in the following localities, and an approximate statement of the extent of each is also given— District of Sydney. ms th Height Area ~ Local Length. rage. average. Purpose. reclaimed. Cook’s River... 520 chains 14 feet 9 feet reclamation 14 Shea’s Creek! 130 ,, » 9 4 do. & canal ‘413 acres Muddy Creek 125 ,, 14 ee DD re Leichhardt ... 153 ,, 12 ,, 9 ,, reclamation 81 acres Callan Park... 12 ,, 1A. sh gs - i Homebush Bay 210 _,, 44 2S i 201. ;, Duck River ... 18 ,, Se. wig comenks +f 41.4, Tarban Creek 16 _,, es an are ee (ea Newcastle District. ch. , ; Purpose. Horseshoe Bend 13 heli 50 feet atk feet protection of river bank Belmore Bridge 17 ,, 20 ” 2” ” ” Hawkesbury District. Sackville Reach 1 chain 8 x 16 feet Grafton District. Public School, 7 chains, 10 x 12 feet, protection of river bank. Great Marlow Embankment, 60 chains of combination bank, part earthwork only; protection of river bank, Moruya District. Moruya River, left incomplete and damaged by floods, length 58 chains, by 14 feet by 9 feet; for training wall purposes. Of the larger works two may be practically called complete, that at Iron Cove, Callan Park, and also the one at Long Cove ; the areas between original high water mark and the present sea face of the embankments, having in each case been filled in to a height of three feet above high water mark by the sand-pumps “Groper ” and “ Neptune.” 1 Shea’s Creek refers only to original creek affected by tidal waters. SS Sh ee pe ee Le ene at eee FASCINE WORK IN N.S.W. XXIIl. The embankment on the western side of the Long Cove Canal has been one of the most difficult of any of these works to deal with, owing to the soft bottom met with in places, which in no case developed when the bank was being constructed, but when the filling was being placed behind. The weight of filling being greater than the weight of an equal bulk of bank, pressed the soft mud out from beneath the bank into the canal. Section herewith showing the fascine work only slightly disturbed, yet a considerable cavity at back with a cor- responding rise in front. To curb this subsidence of the filling, piling along the toe of the bank has been resorted to, and only one subsidence has since been reported, which is attributable to the piles being of insufficient length to reach beyond the liquid mud underlying the bank, although twenty-six feet long. In one instance at the mouth of the canal, ballast was tried, but after 3,500 tons of stone had been deposited over an area of 444 square yards, the ballast was still sinking, at the same time displacing the mud as shown by an upheaval in the canal near by. The following is a detailed description of the method of con- struction of fascine embankment ; after the alignment has been done, and the author can state from severe personal experience, that the setting out of the work is no trifle, when over your knees in mud and still sinking, you are uncertain whether to tell the chainman to come and pull you out, or go on with his distances. A trench 18 feet wide is made to a depth of 1 foot below low water mark, spring tides, and then the first layer of fascine is laid for a length of about 50 feet with the bushy ends out, bearing in mind that the next layer has to bond over them. A layer of mud 9” to 1’ deep is then deposited on the fascines, and the work carried up ina similar manner until the requisite height is reached, attention being given to breaking bond with the fascines, by using long or short bundles as required, ALY, T. E. BURROWS. A shrinkage of the fascines usually takes place under the weight of the mud, and during the first twelve months amounts to 12” or 18", and this shrinkage is made up with silt or other good surface material obtainable. | The first cost of fascine embankment work——at the section given—is under 3/- per cubic yard, inclusive of backing with silt for an average width of 3’; and when the fact that such small subsidence has to be allowed for, and a very small expenditure for maintenance, the embankment may be considered a cheap training wall with a life of over twenty years. Some of this work con-— structed at Cook’s River, nearly ten years ago, bearing out the probability of this statement. When a scour occurs or the proximity to a steamer’s wash is : unavoidable, it has been found advisable to face the embankment : with fascines, as shown in Section “A”; that is, with a liner or stretcher fascine staked down along the face of each layer of silt. Embankment work of this nature, has been considered as specially liable to damage from fire; but the experience of the author is against this theory, and where the bank has a good top layer of mud, and the fascines are kept to high water spring tides level, it is almost impossible to seriously damage the work by fire. Timber shoots or box drains are used to relieve the banks while in their early stages, from the water pressure caused by falling tides: the shoots being fitted with a hinged flap, which opens outward only ; and where large areas are dealt with, or consider- able back water has to be released, a self-acting sluice door is used for the same purpose. ; In concluding the remarks on embankment work it may be mentioned that where the banks have been constructed by truck- ing the material for the work ahead, over that recently constructed — behind, greater consolidation and security are gained at a very slight additional cost. The Great Marlow Embankment was a combination of earthwork with a fascine face, where height of : bank exceeded 5’ and was constructed for protection of river banks from erosion (section herewith). FASCINE WORK IN N.S.W. XXV. FascinE WALL Work. This class of work differs materially from that already described, as this is a thin wall or fence which acts the part of a screen, pre- venting the silt or similar material deposited at the back of same in a liquified condition, from obtaining access again to the river channel. This work has been constructed at the Myall River, and was carried out by Mr. H. D. Walsh, m. mst. c.x., under Mr. Darley’s instructions, and has been very successful. It is formed by driving a row of piles, from 6” to 8’ diameter— of either turpentine or ti-tree with the bark left on—battered slightly inwards, and 3’ apart, and driven 8’ or 10’ into the ground. By using a 12” x 12” ironbark ram and steam driving plant on punt, as many as 50 piles could be driven per day, but the author may here remark that where sand is met with, by | using a steam pump the piles could be put in much faster and more batter given if required. Continuous ropes were then formed of pliable ti-tree—from 10° to 15’ bushes—and as the rope was formed on the punt, it was bound by 14 gauge wire every 18”, and then woven between the piles, and well pressed into place. It was found necessary to place a small bank of stones, shells, or other suitable material, outside of this fence, to keep out the * Teredo,” which are very plentiful in this river. Plan and sections herewith marked, ‘“B.” Discussion. Mr. Dar ey, said, there was nothing very novel about the use of fascine work; it wasa very old class of work, but had only been introduced into this Colony during the last ten years ; it had been used for enclosing reclamations, training banks, and strengthening river banks, for which latter work it had proved exceedingly satisfactory. The banks of the Mississippi River are protected by endless fascine mattrasses of about 20 ft. wide, laid on the surface, and then loaded with stone. Experience here 3—Sept. 18, 1895, XXVI. DISCUSSION. proved to him that it would be worse than useless to use fascine for training banks of channels again. The work at Moruya was an utter failure, the fascines were laid on a sand bottom, and when the very first flood took place the sand scoured away and the whole bank floated out to sea, this was anticipated by the then Engineer-in-Chief, Mr. Moriarty, who reported strongly against the use of fascine for such a purpose. The work of this class at Long Cove has not been the success it might have been, | piles had lately been driven in, and he believed that they are | being pressed forward. He thought that in many cases it would have been cheaper, and more economical to carry out the work with stone, for when the water in front deepens, the stone will run down and check the scour ; this is very noticeable at Newcastle, where there is a dyke of a mile and a half in length. This dyke was laid out by the speaker, the construction being commenced i L ] at low water, there is now over twenty feet of water close beside it. The stone does not sink with the sand, but as the scour takes place the stone runs down off the face of the dyke and so i A checks further erosion, and it is a simple matter to make good the loose stone again till the full depth is reached. In this country where in the majority of cases, our coastal harbours have Ee sci tac, aes ee ca sandy bottoms, fascine work would be quite useless. In the case of some rivers, say the Hunter, some excellent work has been done with fascines, and it has been found a very effective protec- tion against flood, but there it is made of layers of fascine and stone, loaded and coated with stone. Mr. DEANzE, said the first cost of work was put down as being under three shillings per cubic yard, but he was under the impres- ‘sion that the work costa great deal more, and he would like to know from Mr. ste viet where fascine work came cheaper than stone. Mr. Darley said in reply to Mr. Deane’s pene “in what way — fascine work came cheaper than stone”? that stone would be very _ costly to make large dykes of. In our river banks the introduction of the fascine and stones proved itself very effective, where you E y : te a d FASCINE WORK IN N.S.W. XXVII. have stone only it is very apt to slip forward, owing to excessive weight on the toe when a scour takes place in the river. A mixture of fascine, clay, and stone will stand a heavy rush’ of water, and has proved to be very successful, it is light, and does not put too much weight on the toe of the bank, that is speaking of a bank of forty to fifty feet in height, alternate layers of stone and fascines have proved very successful. When commencing work at the Tweed River, great pressure was brought to bear to have fascine work introduced, this was not done, as he pointed out what must happen if this class of work were adopted, it would be sure to scour away. It ended that he carried out the work cheaper than any work of a similar kind in the Colony, certainly everything was favourable to this end, and it is now a permanent, lasting, and cheap work. Formerly there were ten to twelve inches of water, but now there is a depth of over fourteen feet, and in cases of that sort stone is the proper thing to use. In cases like Cook’s River where stone is scarce and would have been very costly, fascine work was suitable, but if the channel is to be deepened eventually the banks must be faced with stone to make them permanent. Mr. Grimsuaw agreed with Mr. Darley’s remarks, but did not consider that the author had written the paper with any view of making a comparison. between stone and fascine work, or mis- leading anyone in believing that facine work was superior to stone, but simply with a view of describing where and how fascine work was being used by the Public Works Department of this Colony. Some of the failures mentioned were attributable +o the fact that fascine is used on mud flats, or where the bottom is very soft and difficult to deal with. He had no doubt what- ever, that for a first class work stone should be used, but in many cases it was quite out of the question on account of the expense, although stone ballast is much cheaper now than it was. Most of the fascine banks had stood very well indeed, though in places where washed by the salt water they could not get any protection from vegetation, which forms a great protection XXVIII. DISCUSSION. in fresh water. The slips described by the author have given a great deal of trouble, the slip at Long Cove occurred in spite of piles having been driven twenty feet into the mud, they invariably occurred when the dredges were filling in at the back of the bank, and at low tide. It was the weight at the back of the bank that pushed the mud through and underneath the bank, and the same occurred in a lesser degree in stone dykes. In the case of the Moruya work, mud and silt in the ends of the fascine dyke were washed away by sea waves, leaving the bushes only ; and no doubt stone should have been used. Still in his opinion the work was started from the wrong end, it should have been commenced at the shore or upstream end, instead of which it was com- menced at the sea end. When the flood came down the river it got at the back of the dyke and washed a great portion of it away. In swampy country, such as Cook’s River, an immense amount of stone would have been absorbed as there is no saying to what depth it would have sunk in the soft mud. In the case of Rozelle Bay it sank over eight feet, and in Long Cove it disappeared altogether. There was no more expense in keeping the fascine work in good order than was experienced with the sides of an ordinary river, when once the reclamation was complete. He was quite of opinion that the facing of fascine banks should be of stone, if possible, and where there was a rocky or hard bottom stone should be used entirely. Mr. P. ALLAN said, where you have to dredge a channel to a considerable depth, it is inadvisable to use anything but stone, as he believed it to be very doubtful whether successful work could otherwise be done. Mr. Simpson said that he quite agreed with the remark that more is sometimes to be learned from failure than from success, but as it has been pointed out by members there are cases in which — fascine work would be quite inappropriate, and in other cases fascine work should undoubtedly be adopted. Mr. Burrows in reply, stated, that the primary reason of this paper was to give information, as to the purposes for which fascine F FASCINE WORK IN N.S8.W. XXIX. work is used in New South Wales, and not for any comparison with stone embankments. For if stone can be used, from an economical point of view it should be. In the case of Long Cove, at one point stone was used with no success, as it was found that the stones kept sinking. Piles were afterwards used, and were put down to a depth of forty-seven feet, the last strata was softer than the upper crust, so that the building of a stone dyke at a one to one slope section, would cost infinitely more than the fascine work, The slips occurred through using the bank as a dam, a purpose for which it was never intended, large lakes of water were formed behind them by the use of sand pumps. This water would have at least a six feet head at low tide. Mr. Grimshaw pointed out in the case of the Moruya work, and he agreed with him, that it was started at the wrong place, and that it had not only the ordinary run of the tide but when a flood came there was nothing to protect it from the scour, consequently the water got both back and front of it, and gave it no chance whatever. The dykes of Holland are constructed largely of mud, and only faced with mattrasses of something similar in character to ti-tree ; weighted with stone or rip-rap, certainly they have much flatter slopes, which are necessary on account of their abutting on the open sea. An instance of the cost of stone ina finished dyke is Rozelle Bay, this is six feet wide on top, with a one to one slope on both sides, the bottom is fairly soft, the stone used was tipped over the ends of the bank, and the cost of stone here compared to fascine work, allowing for a subsidence of the latter of three feet, would be about two to one. He found that the stones had displaced the silt to a depth of from something like ten to fifteen feet, the average being eleven feet for a length of 1,650 feet of dyke. Fascines sometimes give a very ragged appearance to a bank, and the cost of facing up is about fifteen shillings per rod, but when a bank will stand about five years without having anything done to it, this extra payment for maintenance is very inconsider- able. The percentage of shrinkage is about 15% on the section of the bank during the first twelve months. ‘Allon, Per aera , Ti mbe bridge eauminnis New 8 es ae eke Albizzia p sa. 304, 400 Aluminium succinate . tev Amygdaloidal trachyte pasa of water from Wyalong 406 Ancient Antarctic life .. 7 Asdecite, tlaany augite . 474 — au . 485 —— ba . 475 saltic —— vesicular elas 475 Angophora lanceolata 31, 37, 38, 39, 40 Anniversary Addre é hs yale exploration, history of 462 461 = Anti , 316 Apatite, plombiferous 316 os 39 Abonaae 4 ndri Artesian waieean in LN. sige other than oo 6 retaceo 8 Astringent exudations.. i Australian black s = kinos... one tence nake — vegetable acetates ae perp ak ypes of... aS oving Anticyclones ii _—Mo msoonal Rain Storm il—Development of of a Cyclonic in Low a from a Monso 1 De- iv eben of a Cyclonic Storm in High Latitudes from a Monsoonal De- pression y.—Conditions favourable for : Thunderstorms vi.—Cyclonic Thunderstorms S. Wales ‘fe 596 INDEX. INDE. A PAGE mL oN ariece) ed nearly straight oe nooner Fund 3, 7, 553 viii —Cyclones from North-west Acacia 3, 399 ix.—Cyclones: from North-east ge swa 393, 398 x ee am at Gal etnies one 3938, 399 co coolciueeaat of Cyclones — Maideni ... 394, 400 ee stroma 4 Dep 72 xiii.— Westerly Wi te: vy pancagard to the Library 5 C se AP ee te 8 xv.—Black North-easter rs xvi.—Winds Blowing against Isobars xvii.—Summer Anticy plot a se —Winter Aciavels rc eauere He abe A : Depression mt of a etic Storm «« Axe-breaker” 394 Barraclough, 8. H., M.E., the aig ‘and compressive pee: of ma ven 453 a Barkl We : Basalt, o — es yee 476, 488 = Basaltic saircite oa . 475 ; Basic tuff x 481 eryl , 318 Bismuth aecociated with selen- ium lack-snake ne — sir blood véssels, action _ nake v c @” All, Blythesdale Erayetone’ pea Borchgrevink, C. E., Antarctis ak rocks collected bj pr Bosistoa sapindiformi 293, . Bouchardatia newrococ Bridge ome construction in New Wales + “ Britis & su e “ce Broa d- * 400 jeaved Sally” am Building aaa Lara Fund 553 Bur; L . - rge, 0: Ov, the preparation o of En eer- ing specifica ationsandgeneral aaa for oy ra e works 567 Burrow e is, Wass sat as pose ee by ba Public Works Departm ment in New South Wales 568, 5% INDEX. PAGE fe bb . 40 . 320 Capparis nobilis 393, 397 Cape Laas f geological nee gh to ri Chryso 318 Peace cares, easing 0 of a ‘al Fu nd reaps of ‘Lord } Howe island. ii. Onag co: ,N. S. Wal iii. Analysis of water from gatouis 408 iv. On br trachy mes ot ~~ Can sou anele A eis .. 407 a David, SS, 1. W.E n Antarctic rocks collected ies Mr. C. E. Borch- rocks pe victoria and — Possession see yl a ‘s cp Inst. C Some recent Engineering developments in _— nd America . 567 Dick, J. A., M-D. p., Notes on nacase = inalignent disease of the a 0 piphtberia,. Resorein treatment 570 « Divi Di 37 Doan late, a ia russellit paccraagicroige * the “derelict 284 EB Echidna, embryology and de- velopmen Ellagic _ from Angophors lanceo Z| Hargrave, Lawrence, paper 0 a 37 ork . 597 Ellagic acid from “ Divi Divi” —— ection ... 3, opments in fngtand — Planchoniana gogo al composi itic ion Exhibits iat again Meetings 557, 560, 564 Exudations, astringen a _— Australian vegetable Zz Paithful, R. i “M.D , Si enifi- e of albu éniwarte more especially as regarded by sth st miners for Life Ins Fascine coe e N. Ss. Wales 568, 2 ° John on p., some fo 1k- and myt ths fecal Samoa on Galena zinciferous . 320 Garnetife rous- -granlitio-aplite 471 7] a 3, 394, 396, ot base eological “isboratony notes Gia ee andes «Glue g Gee associated with selenium 404 n sea-w i: . 474 r removal by 3 “Muntz- Gum-resi Ho Edgar. note on the er. . Hall, of Malachi ronautical wor 40 598 INDEX. PAGE M PAGE Hawaiian haan age 420 | Magnes esium, tensile oy com- ey, Cs, -F.E8.; Considera- pressive strengths o te s Malachite, origin of .., ... 416 ledge of Australian vege Huxley Mem -. 564 s : 8 Hydrous ftiics silicate ... 818 tet 2 natura epost of ys aluminium succin nthe : t € Grevillea robust Icebergs in the Southern ocean poi gad yee ich ea ee ured ick aoa or discolo Martin, C. J., B. Se., M.B., ve the physiological action f the ve of acca bla oe age ( pal ere porphyriacus) its oo Sydney , On m _ iinstrating the Introductio its syphilis on the ii, cop iene va t introduction of central “lb system ... 571 the v 147 iii. pe oft venom on the plood and blo ye sels 151 iv. Effect of venom on the cir- i ee (oveatea N.S.W. 7 culatory 1 mechanism 208 Kidd] wa v. Effect of eee on the lies on ney aren of the _ nervous ‘sys vi. Effect of venom on the res- oe — Riverina, 1872 — piratory mechanism 256 ag we 492 vii. Effect of dono on the e body Hite Ae --- 894, 401 tempera ; —— myrtaceo viii. Furthe om thological effects 26 Knibbs, G. H , L.8., The history ix. Comparis of exp erimental e results with shee m toms theory and determination of Pseudechis panies, sen in of the viscosity of water by man he efflux m tho Appendix—The toxic value of Medal, Society's sawardof ... 6 edi Be, <4 sf o 5 iS ® BH L eae of ther, sale and Ha- wa Lemons wild a ‘ gs 387 Melicope neurococca 393, 396, 397 Library = Merfield, C. J., Th par: —— additions to. : Me bola as applied to the easing Limburgite 479, 480 of circular curves on railway Lim Spomey with cone-in-cone ines oe ucture . 321 | Meteor of fay 7th, 1895 ... 499 ihenause Prof. 7c E.R a Mica schist .- 481 On e amount, of pod and Milford, F., on the silver in sea-water treatment of ‘tiptheria age —— On some New Sou Wales es Resorcin and other Wines (Note iljee >» No. 316 | Minerals, N.S. Wales and other 316 —— The removal of silver and Mineral substances, n go “ie 7 m sea-water by Mol Mite ue . 822 Muntz metal s sheathing .. - 350 | Morus alba ee one ,. 882 Lord tows Toland, climate of 512 Myths, Samoan... ... «.. 366 INDEX. N E w mineral substance eee New South Wales paent uvedl6 Obituary 1894 el ae ree 476, 477, 488 we .. 476 Olivine basalt -doleri : Original Researches ae we eD a my Pentaceras australis 393, — Pepper tree Pittman, E. ols R.S.M., t. Notes n ineral sub- stances feo the Australian roken dure ew Is Mine 48 Pilbara un 456 san "embryology ‘and de- Paitin raion . 858 Ponape languag: 420 Possession “Island, geological specimens from ce Piosasdiugs of me Sections ... 566 — us Society ... 552 Pro so eee Puadechis ‘porphyriacus .. 7 . 146 Railway lines, easing of curves on 51 Rainfall in Southern Riverina 492 Sidne d illus- the om tty 8 of Net ~ Hawaii by the late Rev Ne pee Renn , On Sect vaier! hand injures. 570 . 461 Russell, H. ae peoheret in Phe ‘aoutoen 599 AGE Sea-water, gold and silver in... 335 Sections, Proceedings of the 566 a ociated with gold an rt 1. 404 Senga bird : . 366 sree = — ater 349 val sa Muntz metal ing he underdraining of the Filter Beds at the eres Sewag Smeeth, Ww. sate . AR Notes on Antaretie r rocks Smith, Henry tion * 461 to ‘ce chemistry of sp ogni = a natural depodt of set ata succinate in the tim _ of Grevillea demer . 825 — Contributions + ledgeof age nig vegetable s, No. 393 exudatio: Southern Ovean, icebergs in ... 286 wood ” .. 400 « Stink . esheets ornate .. 285 rabilis + 285 ol Teniopteris Daintreet vem 410, 412 Thinnfeldia cE ORE . 410 f. PoP tree ere = Presi a ntial Addr —s ak Timber bridge construction in Oce — The © sinkake ‘of Lord Howe Tinston none ” 323 I oe ne BAe Ne ae aseil 82 —— The great Met f May7 am i 1895 ae e ace , on 499 Teachytes of f the Canoblas an nd mbungle Mountains 407 Ss arian ciaeatieims _ ~~ 366 , 323 456 Scho vofeld, oA F.C.8 hah tes gett Antaretie Sake. Schizo 394, , Serub m iickory ” Vv —— exudations ... yong ee Venoms, toxic v: f bi 277 A ey e blood ... 161 — ity oe black — agent of introduction... 2 3 600 INDEX. GE PAGE Venom, effect on the siheeialeieg. Water from Wyalong, analysis echanism OS! of -. 406 —— — body hep. ste oui rors —— viscosity of ra eae nervous sys Weather, Australian ... 513 respiratory Sahence 356 “White gum” ... xe 1 Tank berus wa --- 209 | White eens tree ... Viscosity of water va .. 77) Wildlem ie oh Ww Z Water, artesian in N.S. Wales 7! Zinciferous galena_ —— —— in rocks other than Cretaceous . . 408 EXCHANGES AND PRESENTATIONS MADE BY THE ROYAL SOCIETY OF NEW SOUTH WALES, 1895. The Journal and Proceedings of the Royal Society of N.S.W. for 1895 Vol. xxrx., has been transmitted through the New South Wales Government Board for International Exchanges, Public Library, yaney :— The Smi be Ne Institution, Washington, United States, am ey figs Messrs, George Robert Co., 17 Warwick Square, Paternoster Row, w, Lon ieee to receive and forward to ‘gyan ey all tert eer per ene i Wales. ao to the Society are acknowledged by letter, and in the Society’s Annual Volum j eee of dap nines have been received from the Societies and Institutions distinguished by an asterisk. Afri 1 Tunis c. ...*Institut de Carthage. Argentine estonia 2 CoRDOBA ... ...*Academia Nacional de Cien 3.La Puara.. laste seems de Statistique de la Province uénos Ayres 4 > S *Maseo. de La Plata, Provincia de Buenos Aires. . Austria—Hun : 5 Aaram (Zagrab) ...*Société Archéologique Croate. 6 B a Pitcher der Gewerbeschule. 7 CRA .*Académie des Sciences. 8 yeni bes ‘*Naturwiseonschaftliche Vereins fiir Steiermark n Gra 9 PRAGUE ... - *Koniglich Bohmische Gesellschaft der Wissen- 10 TRENCSIN ... : Oietacs ees Verein des Trencsiner Komitates. a TRIESTE ... .*Museo Civico di Stor ia Naturale. a ...*Societa Adriatica di Scienze Naturali. i3 Vimwa kes vs knteantioghelc Gesellschaft. 14 ey ...*Kaiserliche Akademie der Wissenschaften. 15 ee ae he de Cen aCaneats fiir Mataseologia ‘and agnetismus. 1 py oe ..*K. K. Geographische Gesellschaft. # hes or es K. Geologische er naga 18 2” IS ee radmessungs-Burea 19 s os or K. ' Natarhistorische Hofmaseums ae tei ...*K. K. Zoologisch- e Gesellschaft. 21 ‘ es ce “*Section fiir Matasisde tas Osterreichischen- Touristen Club Belgium. 22 BRUSSELS ... ..*Académie Royale des Sciences, des Lettres et de Beaux Arts. i EXCHANGES AND PRESENTATIONS. 23 BRUSSELS .., 28 Lrfaz Luxeasouna 29 Mon 30 Rio pE JANEIRO... 31 SANTIAGO ... 32 CopENHAGEN 33 BoRDEAUX... 34 CAEN 41 Paris ae 43, eine BB: ng " 46 3” ss, cero ye SSSSSIAALSSLES £8 oe Be “asocieté Géologique ...* Société e des Sciences de Lié ége. ...*Institut Ro bacco Grand-Ducal de Luxembour Musée Royale d’Histoire Naturelle de Belgique. xelles ee “sObeervat Royale de Bru e Malacologique de Belgique de Belgiqu -* Société des Sciences, des Arts et des Lettres Sa "tabs aut. Brazil. *Observatoire Impérial de Rio de Janeiro. hili. ...*Sociedad Cientifica Alemana. Denmark. ...*Société Royale des Antiquaires du Nord. France. ...¥Académie Nationale des Sciences, BelJles-Lettres rts e : ...¥ Académie Nationale des Sciences, Arts et Belles- ettres, ...¥Académie des Sciences, soba et Belles-Lettres. andie. ..*Société Géologique de Nor ord. a 1 ien - Marseille ...*Académie des Sciences et Lettre ...*Société des Sciences Waivclics a VOuest de la rance ... “Académie des Sciences on Institut de France . Bibliothéque de PUnive ité : la Sorbonne. -*Comptoir Géologique ae ar *Depot des Cartes et Plans cm i. Marine. ...*Ecole d’ A Anthropologie ue Paris. Min eee Hc sap des Ecole Nor ea Supéricure : ...*Ecole yoyteeh . Faculté de Mice de Paris. a ..* Feuille des Jeunes Naturalistes. pink ---*Société d’ Anthropologie. am -*Société de Biolo té di . Société tite e de Pari a. #Société = _eanadalebeg pour Y Industrie onale. Nat *Société Entomologiqne de France. el ...* Société Frangaise de Minéralogie. EXCHANGES AND PRESENTATIONS. 65 Paris ify Pe ment Francaise de Physique. O62 oy en = iété de Géographie. GF » ia Ma “Société Géologique de Fran 68 i» > iété Météorologique de Tebhbe. C8553 oes Société Philotechnique. BO ve ...*Société Zoologique de ter sac 71 St. ErrENNE ...*Société de Industrie Min 72 TouLousE ag Ane des Sciences, feanicidies et Belles- ttres 73 VILLEFRANCHE- -MER cap { Laboratoire de Zoologie. Germany. 74, BREMEN .. _..*Naturwissenschaftliche Vereine zu Bremen. 45 BERLIN ... ... Deutsche Chemische Gesellschaft. 76 % aus es .*Gesellschaft fiir Erdkunde. 77 Z ae ...* Koni aiglt ‘er espescepy ee Akademie der Wissen- 78 ” ig _Wkeoigiies Pranasioche an Se Instituts. 79 Bonn ek ...*Naturhistorischen Ver der Preussischen Rheinlande, Westfalens all des Reg.- Bezirks Osnabrii 80 Brunswick ...*Vereins fiir Naturwisse sonachatt zu Braunschweig. 81 CARLSRUHE ...*Grossherzoglich-Badische P olytechnische Schule. 82 re ‘ eo ake Sopot 20 na cher Verelis m ror et 5 83 CASSELL ... .- 2 Vers Naturkunde. 84 CHEMNITZ FE vor etiohe Gesellschaft zu Chemnitz. 85 DRESDEN ... ea “Koni glic ste See und Praehistorisches a 86 is vat ts foftentlichs > Bibliot 87 53 gis _..¥*Statistische Bureau eo Ministeriums des Innern u Dresden. 88 ‘3 He = *Vereins fiir Erdkunde zu Dresden 89 Exp *Naturwissenscheftlicher Verein in Elbe rfeld. alm. Sen eich a ische Naturforschende sia 91 FrererG(Saxony) K Nich-Sachsische Berg-Akademi 92 nach (Baden *Natnsforchon nde Gesellsc .* Ober! 7 e Gesellschaft ri Natur-und-Heil- . *Na ade Ecueds Gesellschaft in Gorlitz. 94. GORLITZ ... ; 95 GoOTTINGEN Ja _.*Kénigliche — der Wissenschaften in Gotting 96 Haute, AS. ...*Kaiserliche * Leopolina—Carolina Akademie der Deutschen Naturforse 97 HaMBURG... ...*Deutsche Meteorologische Gesellschaft. 98 Fi ot << oamaCne Seewarte. Ma ...*Geographische hey poser in Hamburg. 100 se at gigi sine waa seum. 101 pal sy *Verein fir fiir = Here ee cpamuahatiticks Unter-haltung urg. 102 HEIDELBERG eae Medicinische Verein zu Heidel- erg. 103 *Medicinisch Nat nschaftliche Gesellschaft. JENA ae Gs 104 KonIGsBERG ‘ *Konigliche poh -Okonomische Gesell- 105 Lerpzie 109 eis 110 Mertz Ns 111 Mu.yHovuse 112 Mounic# ... 113 is sue 114 SrurregarRt 115 re eet 116 = EXCHANGES AND PRESENTATIONS. eee ao Gesellschaft der Wissen- hafte we *Vorein afar ‘tr dkunde. ..*Na tushinboblichio Museum. ..-*Gesellschaft. ~— Beforderung der dummies urg. senschaften in Marbur *Univ ive ity. < erenaine fiir Erdkunde zu Metz. #S0i8t6 Industrielle de Mulhou ...*Koniglich soap Pocgrnaary ‘der - Wissen- me ften nchen é Botani ane vg si .. Soe “"'#Konigliches Statistische rT agiilult ; #*Verein iad Vaterlindische Naturkunde in er, Wiir » Sey dittemmberpiashe Vereins fiir Handelsgeo- graphie. reat 117 BrruingHamu 2” 119 Brisron ... 120 CAMBORNE 121 CAMBRIDGE 122 33 123 i> 124 PP 125 Kew 126 Leeps 127 128 Livenroon 129 Lonpon 130 ee 132s, ey ie ee eee 186): i 137 ly 18 meg 140 33 ee me M43, 144s, 146, i a ee 148s a Mee ee a Britain and the Colonies. .*Birmingham and Midland} phono ety. ...* Birmingham Philoss Sods Soc ...*Brist ol Nat secpeed Soci ning Association and Cawiak of Cornwall. Begg et “-*Bhilosophieal Soci fet ublic fae — ary. : “eUaion Soc es University brary yal Garden ds Philosophical and Literary Society. *York shire Colleg "eit and Philoso ophical Society. ...¥Aéronautical Society of oN at Britain. gent-General (two copie “4 Anthropological Lussivdte, of Great Britain and Tre 2 Briti Baer ; Sante Socie . Colonial Office, Downing Str iE . Institute of pants of Great Britain Trelan 5 Winatibation ‘of Civil Engine ..-*Institution of Mechanical Drigineate: ""“#Institution of Naval Architects. ...*Iron and Steel Institute ...*Library, S outh Kensi ington Museum. ...* Linnean ie vik — Institut: ...*Lords Com ainiacbnavi of the Admiralty. Offi vi sedbetioe : ...*Mineralogical Societ: we *Physical Society of Lon .--*Quekett Microscopical Gleb, u eyes eco History). Stor ,Encyclope Gi BMeannics, i ‘Soho patie *M *Pharmaceutical Soci ioty of ee Britain. ~ EXCHANGES AND PRESENTATIONS. 152 LONDON .. ..*Royal Agricultural Society of England. 153 ys ay: ...*Royal Astronomical Socie 154 3 ...¥Royal hb of Physicians 155 is eed ‘oyal College of Surgeons. 156 en ...*Royal Colonial Shs bday 157 »s ...*Royal Geographical teat 158 4 ...*Royal Historical Socie 159 3 ...¥ Royal Institution ssa Britain. 160 a ...*Royal Meteorological Society 161 3 ...*Royal Microscopical Society 162 55 Loyal § f Mi 163 oi ae ...*Royal — 164 os a cel ‘oyal Socie of Literat 165 oy oo ...* Royal aaerd Service Institn tio 166 a * anitary gers of Great Britain. 167 mm 7 Tes ety of A 168 35 ie = ivan of E ondon 169. ‘5 ea ...* War Offic o— (Intelligence oe 170 s evs ...¥*Zoological Socie 171 Mancuester _ ...*Conchologica al he 172 x ...*Literary and Philos ephieal a 173 io ..*Manchester ae ogical Society. 174 2S Owens Colle 175 Mirr LE ..¥ Yorkshire Gaaloatcal and Polytechnic Society. 176 Neweastus-vP0%- \ ‘*Natural History Society of No a TYNE.. exe Durham and Ne ee n-T'yn 177 se ...¥ North ee England — e of Mining and Mec nginee 178 ae . Society of Chemical taceairy. 179 OXFORD ... *Bodleian Library. 80 PA ee "*Radcliffe Lee: 181 ~ aes eal ca Observatory. 182 PENZANCE *Royal Geolo. coed ‘tay of Cornwall. 183. PurymouTs ee Plymouth Institution eve Devon and Cornwall atural History Society. 184 WINDSOR ... . The our s Libra “CAPE OF GOOD Bore. 185 Cape TOWN _..*South African Philosophical Society. CEYLON. 186 CoLOMBO... ..*Royal Asiatic Society, bende Branch). DOMINION OF CANA 187 ge saith (Nova »*Nova Scotian pepe ee Y Hetatine, 188 HaminTron (Ont) i geal Assoc 189 MonTREAL al History Socisty of Montreal. 90 ” eee ast o : 191 OTTAWA ... eae and Natural cngomat Survey of Canada. Society. ay o 192 QUEBEC .... ... * Literary ails torical a. TORONTO ... ...*Canadian Inst ita. « ...* University. 195 Winwipre ‘""*Manitoba Historical and Scientific Society. 196 CALCUTTA ...¥Asiatic Society of Bengal. 197 » eve ...*Geological Survey of India. EXCHANGES AND PRESENTATIONS. 198 DuBLIn 199 32> 201 Kineston... 202 Port Louis 203 33 204 Ricumonp SYDNEY ... 207 ” 208 209 2? 210 ry) 211 re 212s 213_—(ss, 214 2 215 re 216 » oe SS 218 2 219 ” 220 ra 221 i 222 AUCKLAND 223 saath ego 2 NE a 225 A gett 226 >» 227 e » 228 BRISBANE... 230 ue ; 23 1 2? 232 Pe 233 ne 234 ABERDEEN 235 EpINBURGH 236 se IRELAND. Royal Dublin Soc iety. yal Geo eclogieal wate of Ireland. .--*Royal Irish Academ AMAICA. ...¥*Institute of Jamaica. MAURITIUS. ...*Royal Society of Arts and Sciences. Société d’Acclimatation de le Maurice. NEW SOUTH WALES. Hawkesbury Soman College. ...* Australian Mus ...™Department of "Mines and Agriculture. ""t0hservatory ...*Public a Sone me of Public Instruction. --’ Engineering Association of tee South Wales. atistician. a } 4 © a 8 B & ae, of el “sLincan Society vo New South Wales. .*Min me. hearse eh vec Railways Institute. hikes ...*Public Works ; ent. ...¥Royal Geographical Society of Australasia (New nch). South Wales Bra ... School of Arts. ne _ rechnologica Muse *United 1 Servic patina of New South Wales. Pee eee ie . eUnive NEW Cem *Auckland Ins oe Philosophical institets of Canterbury. Ota — “goto a eala: ae aida ety. . : eke dion Socie UEENSLAND. Beg" a Society of a -*Geologi urvi and. plas al. Society of Australasia Bg Coreen, Branch). ...*Royal Society of Queensland. SCOTLAND. e rsity. * eBdinberoe h Geological Socie oan and eo dr itagaggy Seolaty of Scotland. tani ‘Sa Sbacreaie ...*Royal Physical acids. EXCHANGES AND PRESENTATIONS. 240 EpINBURGH 241 ” 242 Ps 243 GLASGOW ... 244 a ee 245 m gh 246 St. ANDREWS 247 ADELAIDE... 250 >» 251 ap 252 » 253 ”» 254 » 255 SINGAPORE HOBART ... 257 LAUNCESTON 258 BALLARAT 259 YBOROUGH 260 MELBOURNE 261 ” 262 ”» 263 ”» 264 ” 265 ” 266 » 267 ” 268 ” 269 » 270 ” 27rl ” 972 STAWELL ... 273 PERTH 274, PortT-AU-PRINCE .., 275 BOLOGNA ... 277 FLORENCE... “ oye Scottish Geographical Society. = :* .*Roy cad *Unive i “eGoologioal Society of Glasgow. ...*Philosophical Society of Glasgow. -*University. "..* Universi ity. SOUTH AUSTRALIA ess Beckie ose paca Ne South Australia. vee OW sGorernment oH rinte tory. ...#Obse iy "*Publie Tekin: Museum, and Art Gallery of Sou th Australia. ...*Royal bet’ graphical sea d of Australasia ranch). (South ralian B ...*Royal Society va South Australia. ...* University. STRAITS SETTLEMENTS. .. *Royal Asiatic Society (Straits Branch). TASMANIA. .*Royal Society of Tasmai 2 ‘*Geological Survey of Piohaia VICTORIA. ...*School of eon and Ind ustri . District School of Mines, Industries and Science. f Vi ...*Field Naturalists’ Club o ctori ae rnment B i eral. e “Royal ‘Geogeaphical Society of Australasia (Vic- Sea ‘Society ra Victoria. ...*Unive VIS alan Institute of Surveyors. ...* Working Men’s College. ...*School of Mines, Art, Industry, and Science. WESTERN AUSTRALIA. ...¥ Museum. Hayti. Société de Sciences et de Géographie. Ital y: ccademia ee Scienze dell’ Istituto. fF xa a. i. rsita di “ *#Societd. pracy d’Italia (Sezione Fiorentina). EXCHANGES AND PRESENTATIONS. 278 FLORENCE .--*Societa pores gre Italiana cS te ..*Soc — Italiana di | Antropologin e di Etnologia. 280 GENOA : ...*Museo Civi ie a Naturale. 281 Minan ... 5 een Istituto ikabasae di Scienze Lettere ed 282 ts a : a alin di Scienze Naturali. 283 MopEna ... Pees cademia di oe Lettere ed Arti. 284 NAPLEs ... 0 ak Pinca at 285 S Ae Jagr Reale di Napoli (Accademia delle Scienze Fisiche e Matematiche). 86 i vas *Statione teologion rrr Ts De hrn). 287 PaLerRMo... F .*Re ale is wage Palermitana di Scienze Lettere e 288 Pisa ie ... Reale a tuto Teenic a sae ...*Societa Toscana di eketind Natura i. 290 Rome ies ...*Accademia Ponti ficia de Nuovi Lincei. 201. a ...*Biblioteca e peasetn itsnaiec (Ministero dei Lavori Pubblico is Zoe 2 eee fsent-qeaeh dei Lin a! 5 eae ay .*R. Comitato Gelogico 2 Italia ee igen we ; _#R. ee son fen rale di Meteorologico e di Geo- dinamico. ...*Societa Geograsia Tt 4 oe talia 296 SIENA... ...*R. Accademia dei Fisiocritici in Siena. 207 Topin: -.-*Reale gained della Scienz 298 a ...*Regio Osservatorio della payin Universita. 299 VENICE oe ot “*Resle Istituto Veneto di Scienze, Lettere ed Arti. Japan, 300 Toxto ease eect e nd oo (formerly in Yokohama) Sel a rial University. 302s, eR Rac os erate elas of Japan. Java. ~ 303 Batavia ... rtd |e Natuurkundige Vereeniging. in Nederl-Indié Mexico. 304 Mexico .,, ...*Sociedad Cientifica “Antonio Alzate.” Netherlands, 305 AMSTERDAM -*Académie Royale des noite d -ASoiets Zimslo de Zoolo 307 HaaRuem... “Bibliotheque de Musée vie. *Col a wei olonial Museum. 309 - or *Bocibté Hollandaise des Sciences. Borway. 310 Bercen ... ee 311 CHRISTIANIA ""*Kongelige Norske Fredericks barreepoet 31 es i Christian 313 Tromso ..*Museu oumania. 314 BucHarzst ...*Institutul Meteorologic al Rouminiei. EXCHA NGES AND PRESENTATIONS. sia. ..*Société des Sciences de Finlande. 315 HELSINGFORS 316 KrIeFrF si *Société des Naturalistes 317 Moscow -.*Société Impériale des ‘Naturalists. 318 s "_.*Soeiété Impériale des Amis des Sciences Nat elles d’ An Pcalnoia: “at d’ Ethnographie Moscow (Section @ Anthropologie). 319 Sr. Pererspure ...*Académie Impériale des Sciences, 320 Fe ...*Comité Géologique—Institut des Mines. n. 321 Maprip . Instituto geografico y Estadistico. Sweden. 322 SrocKHOLM Si ee Svenska Vetenskaps-Akademien. 323 is .*Kongliga Universitete 324 UPpsaLa . Kongliga Vetenskaps Societeten. Switzerla nd. 325 BERNE ...* Société de Géograp steed poe: 326 GENEVA _*Institut National pe 327 LAUSANNE *Société Vaudois - Sclcnies Nature 328 NEUCcHATEL *Société des Sci s Naturelles de N renee 329 Ic . ‘Shatectorwhones "G@esellabhatte United States of America. 330 .*New York nor Library, Albany. 331 Awsaronis( (Md.) a a: Academ, 332 *Johns Ho opkina University. 333 Beworr (Wis) *Chief Geologist. 334 Br pesca of Californ 335 Bos’ merican Academy of Arts soa Sciences. 336 oe pie Sooke of Natural Histo 337 ‘ ibrary of Massachusett 338 geste: (Ind.)* Brookville Society of Natural History 339 Academy of Se 340 Burra ALo (In Buffalo Society of Natural Sciences Ent ct 2» 343 CHICAGO ... 344 a ree d.) . CAMBRIDGE (Mass. ahaa ollege. is Academy of Scienc : n Medical iccintien ~The Newberry of Com ear ‘ra rary. *Cincinnati Society of Natural History. 345 CINCINNA’ 846 CoLpWwa ichigan Library Association B47 alae ale (Iowa)*Academy of Natural Sciences 348 DENVE olorado Scie Society. 349 Fort Mowsss(Va. ye Jnited States Artillery School. 350 H n (N.J.) ...*Steven’s Institute of Technology 351 Iowa Crry (Iowa) *] director Iowa Weather Service logi poate of Missouri ademy of Sciences, Arts 354 355 NewHAVEN (Conn) bps pd New Yor 357 am 358 » ..*Am ga sna Institute of cieae Divine: esota ciate emy of N e ‘onnecticut Academy of Arts and Sciences. *Am eric. an Chemical Saniaty. an Geographical So ur- a Letters. EXCHANGES AND PRESENTATIONS. 359 New Yorr : - American Museum of Natural erik Pr ..." American Ssugprie of Civil En 361 = "#Rditor Journal of Calwaticg "Medicine and stanky Archives. 362 re -.-*New York Academy of Sciences. roy Box York Microscopical Society. chool of Mines, Columbia College pee Pato Auto (Cal. ¥ “*Geologieal Survey of Arkansas 366 PHILADELPHIA ... *Academy of Natural Science. 367 * -.-*American Entomological Set 368 a -..-* American tberrirt ay cal Socie 369 “A ...*Franklin I 370 _ seen see of Sie 371 si Ps de can a ee Institute of Science 2 oologi 1 Society of cai ia. 373 RocuEstsr (N. Y. ) «Geological Society of Am 374 Satem (Mass.) . i : 75 a “Tasttiats *Academ 376 Sr. Louis see ss x ] den. 878 San Francisco ...*California Academy of Sciences. 37: a alifornia State Mining Bureau. 380 Scranron (Pa.) .. The Colliery Engineer Co. 381 oe “y sureau of Waucation! Hotdctacnt of the Interior). 382 ...™ Bureau of Ethnol 383 a ...*Chief of Engineers (War Department). 384 Pe ---*Chief of Ordnance (War Departme se 385 F -..*Department of Agriculture, Libra. 386 oe ...* Department of ier ea Wea thee Bureau. 387 i ...-* Director of the M dosecenged Department). 388 si ... “Library (Navy Depattrs ae 389 au ...*National Academ y of ont 390 ia ...* Office a Indian ” Affai irs (Denegtii ale of the Interior). 391 2» Ps inal Piilncobicsl Society. 392 . ...*Secretary Depatacas of the Interior). 393 a ..*Secretary (Treasury Departm ment), 394 ne ...*Smithsonian Institution. 395 ‘3 ...*Surgeon peers (U.S. Army). 396 re ..*U. S. Coast and Geodetie Survey (Treasury 397 pa wea ae eee | 398 ae we National Minas ( Department of the Fs nterior 399 rs -U: -: Puttak Office. r Department. N anaber of PON sent to a Britain i Be » » India = the Colonies i ee a 5s Ameri ie ete i é 2» 2 Baise vice 2 168 2 9 Asia, Africa, ‘&e. oe 33 2» Editors of Periodic: als eos 4 a J. H. yet Ceniae } Hon. Se Sicrebasios Spdnep: F. W. Ware, Printer, 39 MarKeT STREET. — 1896,