^*t^ ^v>. \r ■y-: L. R i m* & ZTt^ayed- by E.Mackenzie, ttotw an Original. (^^r/16^,:) THE PHILOSOPHICAL MAGAZINE: COMPREHENDING THE VARIOUS BRANCHES OF SCIENCE^ . THE LIBERAL AND FINE ARTS, AGRICULTURE, MANUFACTURES, AND , COMMERCE. BY ALEXANDER TILLOCH, BONORAEY member of the KOYAL IRISH ACADEMY, &C. &€. &C. " Nec aranearum sane textus Ideo melior quia ex se fila gignunt, nee nost«r vilior quia ex alienis libamus ut apes." Just. Lips. Moiiit. FQlit. HIt^J, ran, i, VOL. XXX. For FEBRUARY, MARCH, APRIL, and MAY, 1808. LOND ON: PRINTED FOR JOHN MURRAY, FLEET STREET J AND A. CONSTABLE AND CO. EDINBURGH : And sold by Richardson; Cadell and Da vies; Longman, HuriTj Rees, and Orme; Symonds; Vernor, Hood, and Sharpe; Harding; Highley ; London: Bell and Bradfutk, Edinburgh : Brash & Reid, and D. Niven, Glasgow: and Gilbert and Hedges, Dublin. Printed by Richard Taylor and Co, Shoe Lane. CONTENTS OF THE THIRTIETPI VOLUME. !• On the two Systems of Musical Temperament recom- wended hy Earl Stanhope^ — Mr. Hawkes's System, C!^c. By Mr. John Farey 3 II. Essay upon Machines in General. By M, Carnot, Member of the French Institute, ^c. c^c, . . . . 8 III. Additional Memoir upon living and fossil Elephants, ByM.CuviER 15 IV. Observations upon the Employment of M. Guyton- MoRVEAu's Fumigations for preventing contagious In- fection. By M. A. Hedouin, Physician . . . . 26 V. Letter from M. Guyton de Morveau upon the Effects of Fumigations in Epidemics of Cattle, and for the Destruction of putrid Miasmata 28 VI. Experiments upon the liquid Sulphur of Lampadius. By Messrs. VAuauELiN and RoBiauET . . . . 30 VII. Letter from the Right Honourable Earl Stanhope, relative to Dr. Callcott's Pamphlet on the Stanhope Temperament 34 VIII. Upon the Decomposition of the Acetate of Barytes ly means of Soda. By iV/. Darcet 36 IX. Upon the Preparation of pure Barytes. By M. Ro- BiaUET 40 X. Observations upon the Combination of the fixed Oils tvith the Oxides of Lead and the Alkalies. By M. Fremy, Apothecary at Versailles 42 XI. Description of the Mountain Barometer, invented by Sir Henry C. Englefield, Bart. F.R.S. and made by Mr, Thomas Jones, of Mount Street, Berkley Square 46 XII. On E. V.'s Article " On the Means of gaining Power in Mechanics " . . 62 XIII. Extract (f a Memoir upon the Products which result from the Action of the Metatlic Muriates, the Oxy-mu- riatic Acid, and the Acetic Acid, upon Alcohol. By M. Thenard . . . . , , . . 64 XIV. Upon a peculiar Property in camphorated fVater. By M. Cadet 66 XV. Letter from Gavin Lowe, Esq., on the Comet of 1807 .. ,. 67 XVI. A Second Letter from E. V. on the Means of gaining Power in Mechanics 70 XVII. On the Use of Sulphur as a Fermifuge. By Joseph Hume, Esq., of Long- Acre, London 71 Voi. 30. No. 120. M(7?/'l80S. a XVIII. Ex- CONTENTS. XVIIT. Experiments for investigating (he Catise of the co^ loured CQJicentric Rings discovered ly Sir Isaac Nkwton, between two Object-glasses laid upon one another, Bij William Herschel, LLD. F.R.S. .. .. 72 XIX. Report of Surgical Cases in the City and Finslunj Dispensaries for September 1807. By John Taun- ton, Esq 90 XX. Proceedings of Learned Societies 91 XXI. Intelligence and Miscellaneous Articles . . . . 93 XXII. On Blasting Rocks and Tamping. By John Tay- lor, Esq 97 XXIII. Extract of a Memoir vpon the Muriatic Ether ^ as read at the French Institute, nth of February, I8O7. By M. Thenard . . , . . . 101 XXIV. Memoirscf the late Et^asmusDarwin^ M.D. JO9 XXV. Experiments for investigating the Cause of the co- loured concentric Rings, discovered by Sir Isaac Nkwton, letweeu two Object- glasses laid upon one anothen-. By William Herschf.l, LLD. F.R.S 1I5 XXVI. Observations upon Sulphureous Mineral Waters. By M. Westrumb . , , , . . ] 291 XXVII. On the Preparation of' Calomel. By Mr. Joseph Jewel . , , ^ 133 XXVIII. On the Contraction which takes place in Mercury at low Temperatures by Abstraction of Heat ; — and on the Ratio of Contraction between Mercury, Alcohol, Water y and Silver, ^y John Biddle, Esq. of Birmingham 134 XXIX. Essay upon Machines in General. By M. Carnot, Member of the French National Institute, '&'c. &c. 154 XXX. On Caloric, and the Heat evolved during Combustion, By James ScHOLES, Esq., of Ma?ichestcr .. .. 138 XXXI. On the Cause of the diffei-ent apparent Magnitudes of the same Objects seen under different Circumstances. By Ez. Walker, Esq 163 XXXII. On the. Identity of S'llex and Oxygen. By Mr. Hume, of Long- Acre, London ., 165 XXXIII On the public UtiUiy of Medical Insfitutio?is for the Benefit of the Diseased Poor 1 71 XXXIV. On the constituent. Principles of Potash. By ^Mark Taero, Esq. of Beeston, near Shrewsbury 17*.«J XXXV. On the best Means for preventing the fatal Con- sequences that so frequently occur frorn the Dresses of ^ Females and Children taking fire 1 7 3 XXXVI. Letter from Sir H. C. Englefikld respecting his Mountain Barometer .. , 176: XXXVII. Reports of Surgical Cases in the City and Finsbury Dispensaries, for October 180J -, with some Remarks on the CONTENTS, the Dissection of the Brain of a Person who died insane* % John Taunton, Esq 17^ XXXVIII. Report upon a Memoir read at the French Insti- tute, bi/ M. Thenard, upon the Nitrous Ether, By Messrs. GuYTON, Vauquelin, and Berthollet . . 1 77 XXXIX. Proceedings of Learned Societies . . . . 182 XL. Intelligence and Miscellaneous Articles .. .. 189 XLI. Experiments on the Influence of Time, as a chemical Agent, in depriving an elastic Fluid of its Elasticity/. In a Letter f'lom M. BioT to M, Berthollet . . J93 XLtl. Experiments for investigating the Cause of the cO' Loured co7icentric Rings, discovered hy Sir Isaac Newton, between two Objert- glasses laid upon one another. By William Herschel, LLD. F.RS 295 XLIIl. Essay upon Machines in General, By M. Car not. Member of the French National Institute, &c. &c. 207 XLI V. Processes employed for finishing the Inside of the Palaces of the Native Princes in some Parts of the East Indies 221 XLV. Notice upon the Analyses of the Chr ornate of Iron^ and upon the Fariety of the Epidote called Zoysite. By M. Hauy ,, ..* .. 223 XLV'L On drying Articles of Manufacture, and heating Buildivgs, by Steam, By R. Buchannan^ Esq., Civii Engineer^ Glasgow .. .• .. 225 XLV J I. On the ceconomical Uses to which the Leaves and Pruning s of Fines may be applied in this Country 22(5 XLVllI. Observations on the Nature of the new celestial Body discovered by Dr. Olbers ; and of the Comet which was expected to appear last January in its Return from the Sun. By William Hebschel, LL.D. F.R.S. 227 XLIX. An Account of a remarkable Shower of Meteoric Stones, at JFeston in America. By Mr: Silliman, Professor of Cliemistry, and Mr. Kings ley. Professor of Languages, in Yale College .. 232 L. Me77toir Upon the Torpidity of Monkeys and other Ani- mals. Translated from the Italian of M. Mangajli, Professor of Natural History at Pa via . . . . 245 JLI. The reformed Sexual System of Liiniams. By Robert John Thornton, M.D., Lecturer on Botany at Guy's Hospital 253 LI I. Account of the Mamfactures carried on at Bangalore ^ and the Processes employed by the Natives in Dyeing Silk and Cotton 259 LIU. On the Means of gaining Power in Mechanics 272 LIV. On the Identity of Silex and Oxygen. By Mr. Hume, ofJU>ng'Acre. London 275 ^ LV. Pro- CONTENTS. LV. Proceedwgs of Learned Societies 280 LVI. Intelligence a7id Miscellaneous Articles ... 284 LVII. Reduction of the Observation of the Transit of Mer^ citry over the Sun, observed at the Royal Observatory, Greenwich^ on the Sth of November, 1*802. Commu^ nicated byT. FiRuiNGEK, Esq 289 LVI IF. Geological Journey to Mount Ramazzo in the Ap- penines of Liguria ; Description of this Mountain ; Dis-^ covery of' the true Variolite in its Bed ; of Lime ; of the Arragonile ; and of Martial, Magnetic, Cupreous, and Arsenical Pyrites, in the ^Steatitic Rock ,• Mamfacture of the Sulphate of Magnesia. By M. Faujas St. Fond 296 LIX. Essay upon Machines in General. By M. Carnot, Member of the French National Institute, &^c. &c. 310 I.X. On Chemical Nomenclature. By a Correspondent 320 LXI. Account of the Manufactures carried on at Bangalore , and the Processes employed by the Natives in Dyeing Silk and Cotton . . . . . . 322 LXI I. Description of the Bermuda Islands , and particularly the Island of St. George. Addressed to the Directors of the French Museum of Natural History, by M. A. F. Mi- ch Aux, temporary Agent of the French Imperial Ad- ministration of Woods and Forests in North America 331 LXin. Facts upon which to found a History of Cobalt and Nickel. ByM.PROVST. Extracted by M.Chevreuil 337 LXIV. The mean Motions of the Sun and Moon, of the Su7l's Perigee, the Moon's Perigee and Node ; the Times of their several Revolutions, both in respect to the Equinox and to the fixed Stars, and in respect to each other : de- duced from the New Tables of the Sun and Moon lately published by the French Board of Longitude. By James Epps, Esq 347 LXV. Mineralogical Account of the Island of Corsica ; con- tained in a Letter from M. Rampasse^ formerly an Officer in tke Corsican Light Infantry, to M. Faujas de St. Fond .. 351 LXVI. On the Identity of Silex and Oxygen. By Mr. Hume, of Long-Acre, London 356 LXVIL Report of' Surgical Cases in the City and Finsbury Dispensaries , for November 1807; containing a Dissection of a Case of Hydrocephalus in t emus. By John Taun- ton, Esq 363 LXV III. Notices respecting New Books 365 LXIX. Proceedings of Learned Societies 366 LXX. Intelligence and Miscellaneous Articles ... -370 THE THE PHILOSOPHICAL MAGAZINE. I. On the two Systems of Musical Temperament recorn- jnended hy Earl Stanhope, — Mr, Hatvkes's System, &c. By Mr, John Farey. To Mr, Tilloch. TT ''''' XIaving bestowed some pains to illustrate the System of Musical Temperament described by Earl Stanhope in your xxvth volume, as applicable to keyed Instruments, by the help of a Monochord, whose divisions are according to geometric mea?i proportionals, I beg now to present to your readers, the notes of the other System, described by his Lordship in the same Essay, to be effected by making three successive tempered Fifths, and two successive major Thirds^ in p C>< 1 + + + 1 + Is The Eq'ual'Bcaiiiig System of Earl Stanhope, expressed in ► QO' 612-0000 2 4- 12 f + 53 m 5550000 2 + 11 f + 48 m 50«-0000 2 + 10 f 4- 44 m 453 3248 2 + 9 f 4- 39§ m 405-7725 2 + 8 f + 35 m 358-0000 2 + 7 f 4- 31 m 301-7725 2 + 6f 4- 26 m 254-0000 2 4- 5 f 4- 22 m 197-0000 2 4- 4f + 17 m 151-7725 2 + 3f + 13 m 98-9726 2 -r 2f + 8| m 47-7725 2 -h f + 4 m l-^ •5000000 •5333333 , -5625 •5984261 •6315480 '6666666 •7104915 •75 •8 -8420638 •8941170 •9473220 I -0000000 o . 3 CO CO Ot-vococor^ocoOO'* «f CTi O O C7-, C\\— O -T C^. '-'i O O CO en •*■ O X 5-0 O r- O CO — V; "JO uo -. CO Q O) CI u'^ i^ O CM «C t^ O C-1 IT 1- C5 <^ t^ l^ t^ 'X> II ^1 lO 8 S CO p 9 Q'? 9 b o T ? 9 C O i' -< O O '^ O O '^ 00 cfo O ^•|>^|SS=^| •8'4JB|M c^ ueq«'<' employ the best .professional Tuners to tune his instruments, without any intimation to the Tuners, of his intentions or object ; and before such instruments are put out of tune by use or standing, to ascertain exactly, by the heats of the dilferent conchords, by a monochord ; and by other methods also for further satisfaction, the exact value of every interval in an Octave, using single strings only : these experiments varied and repeated, on Organs and Piano-Fortes, tuned by as many good tuners as possible, would, by their results, enable us to say, how far any one system whatever has been adopted, or can be accomplished, by the method of tuning in use, and within what limits the different tuners, or the same persons at different times, do in practice fix each note. Such an one would doubtless perform the most valuable piece of service to the practical musician, and perhaps enable him to profit from the labours of theorists in harmonics, by enabling him with more certainty and facility, to ac- complifch the '^tuning,*' with which by practice his auditors are become acquainted, and wherewith most of them are satisfied*, if the same did not lead to an amelioration of the system* With such information before them, the musical public would perhaps 'be enabled to judge, of the preten- sions of the many musical quacks, who are almost every year bringing forth some new and fanciful system of tem- perament, (of which an almost inexhaustible fund yet lay behind,) and crying up the same with a confidence, equalled only by that with which rival empirics condemn them: until at length the Science of Harmonics^ and the valuable discoveries of Dr, Robert Smith oh the nature of imperfect * Let It always be recollected, that performances on perfect InsfnLmcnls of by Voices, are free from defects %n harmony if skill and goed ears but direct them, and that the present inquiry is limited to the use of Instruments with 12 strings or pipes in an octave, where, or evcu with double that nmmber of fixed sounds, tcijiperameQts, or errors in harmony ere impossible to be Qvoitled. A 4 consonances * S On Machines in General, consonances, and of Mr, Maxtvell on the system of perfect consonancijy arc in danger of falling into utter contempt. 1 beg here to mention, respecting the new notation for musical intei»als, which I have explained vol. xxviii. p. 140, that the Octave, happening to contkin just 12 of the lesser fractions f, and one of these to fall near each note of the equal temperament ; in almost all calculations respecting DoJizeaves, the temperaments or results, are free of f, and two only of the three independent or prime terms, of which every accurate notation must consist, are in general found at last ; while the smallness of the most minute, m, it being less than the ttj^^ P^i^t of the Schisma, 2, which is itself but a very trifle more than -y^th part of a Comma, c, (6r 7?T 2 + -rV I") render it allowable in most practical cases to neglect m, and to consider the S s as elevenths of a comma, in the results ; although I would advise the pre- vious calculations to be always carried on strictly, in 2, f and m, especially, as the number of f s will generally point out, to what finger-key or number of half notes, any step in the process answers. I am, sir, your obedient servant, John Fa ret. 12, Upper Crown-Street, Westminster, l?€bruary I, 1808. II. Essay upon Machines in General. By M, Carnot, Member (f the French Institute, &c, &c.* Preface, ■ AuTHOUGH tlie theory to be discussed be applicable to every subject which concerns the communication of motion, I have given to this work the title of Essay upon Machines in General ; — in the first place, because it is principally machines I purpose to treat of, as being the most important ♦ For a 'f ranslat Jon of Carnot's " Reflections on the Theory of the Infini- fpsimal Calculus," see Phil. Mag. vol. vjii. p. 222, and 335 j and vol. ix. p. 89. ' branch On Machines in General, § branch of mechanics ; and in the second place, because I do not mean to treat of any machine in particular, but solely of the properties which are common to all. This theory is founded upon three principal definitions : the first regards certain movements which I call geometrical, because they may be determined by the principle of geome- try alone, and are absolutely independent of the rules of dynamics. I have not thought that we could easily pass over them without leaving some obscurity in the elucidation, of the principal propositions, as I have particularly shown with respect to the principle of Descartes. By the second of my definitions, I endeavour to fix the signification of the ie,vm6 force soliciting and force resisting : we cannot, in my opinion, perspicuously compare causes with effects in machinery without a marked distinction be- tween these difierent forces ; and this is the distinction upon which I think something vague and indeterminate has been always left. Lastly, my third definition is that by which I give the iiame of moment of activity of a power, to a quantity in which a power is mentioned which is really in activity or in movement, and where we also take account of each of the instants employed by this force, i. e. of the time during which it acts. Whatever it be, we cannot refuse to allow- that this quantity, under whatever denomination we de- signate it, is not to be continually met with in the analysis of machines in movement. With the assistance of these definitions, T arrive at pro- positions which are very simple : I deduce all of them from one same fundamental equation, which, containing a cer- tain indeterminate quantity, to which we niay attribute dif- ferent arbitrary values, will give successively m each par- ticular case, all the determinate equations required for the- solution of the problem. This equation, which possesses the greatest simplicity, generally extends to all imaginable cases of equilibrium and movement, whether the movement changes hab^tiiv, or va- j;\es by insensible degrees : it is even applied to atl bodies, whether hard, «r endowed with a cerbin degrc^ti of elaslicilv ; at>d 10 On Mathines in Generate and if T am not deceived, it is sufficient of itself, an4 inde- pendently of every other mechanical principle, to resolve all the pHFticular cases to be met with. I easily draw from this equation a general principle of equilibrium and movement in machines properly so called, and from the latter naturally flow o>her principles more or less general, several of which are already known and very celebrated, but which have been hitherto eirtier inexactly or vaguely explained, rather than rigorously demonstrated. Without departing from general principles, I have united in a scholium, and as clearly as possible, the most useful remarks for practice, and which, ^om their importance^ appeared to me to merit a par:icular development. Every person repeats, that in machines in movement, we always lose in time or in velocity what we gain in power; but after perusing the best elements of mechanics, which seem to be the true place where the proofs and explanation of this prin- ciple should be found, — Is its extent or even its true, signi- fication easy to seize ? Has its generality, with most readers^ that irresistible evidence which should characterize mathe* rnatical truths ? If they exhibit this striking Conviction, ought we not to see mechanics instructed in th *^?^^ ^^^ bodies are supposed to be in motion, the one from top to bottom, and the other vice versa, jt is evident ihat the first member of this equation is the vertical velocity of the centre of gravity ot" the system : thus this centre of gravity will not descend, and therefore by the preceding position there must be an equilibrium. [To be continued.] III. Additional Memoir upon living and fossil Elephants, By M. CuviER. [Concluded from vol. xxix. p. 254.] Article VII. Comparison of the Crania of the Elephant of India and that of Africa — External Characters taken from the Ears — Parts of tile Cranium susceptible of Variation in one and the same Species. JL HAD the good fortune to be the first to remark, in 1795, the distinctive characters presented by the crania of the two elephants, and which are so much the more interesting, as they may be applied to living, or entire individuals, without being obliged to examine their jaws*. I was able to re- cognise them at first only by the comparison of' a cranium of each species ; I have -now verified these observations by inspecting seven real crania, (five of which are Indian, and two African,) and several drawings. When these crania are separated from their lower jaws and placed upon the grinders, and upon the edges of the alveoli of the tusk;5, the zygomatical arcades are nearly ho- rizontal in both species. If we next view them laterally^ what is very striking is, • Plate II. was long ago engraved from my own drawings. I gave a proof Impression of it several years ago to M. Wiedeman of Brunswick, who copied it into his Archives de Zootomie, tome ii. cah. I. pi. I. — The Author* that 1 G Memoir up6n livmg and fossil Elephants, that the summit of the head is almost round in the African elephant, and that it rises in the Indian elephant into a kind of double pyramid. This summit answers to the occipital arcade of man and other animals, and is so high in the elephant merely for the purpose of giving to the occipital face of the cranium a suf- ficient extent for a cervical ligament and occipital muscles, proportionate to the weight of the enormous mass they have to support. This difference in the form of the summits proceeds from the difference in the inclination of the frontal line, which retreats much further in the African elephant, where it forms with the occipital line an angle of 115°, than in the Indian elephant, where it makes an angle of 90° only. From this come the principal differences of the profile, such as, 1st, The proportion of the vertical height of the head at the distance from the end of the bones of the nose to the occipital condyles, which are nearly equal in the African elephant, (being as 33 to 32,) and the first of which is nearly one-fourth larger in the Indian elephant (being as 24 to 19). 2d, The proportion of the distance from the edges of the alveoli of the tusks at the summit to a line which is perpendicular to it and goes from the end of the bones of the nose to the anterior edge of the occipital hol- low. The first of these lines is almost double that of the other in the Indian elephant (being as 26 to 14). It is little less than one -fourth larger in the African elephant (being as 21 to 16). Besides these in the proportions, there are also differences in the contour: Ist, The front of the Indian elephant is followed into a sinking and concave curve ; that of the African elephant is on the contrary a little convex. 2d, The sub-orbitary hole is larger in the Indian dephant. In the African, It resembles a channel rather than a simple hole. 3dly, The temporal hollow is rounder in the African ele- phant ; and the apophysis, which distinguishes it from the orbit, is thicker than in that of India, in which this hollow has g,p oval contour. When Memoir upon livi?ig and fossil Elephants, if When observed by their front view^ these crania also pre- sent very remarkable diflferences. 1st, The greatest length of this front, taken from the summit to the edge of the alveolus, is at its greatest breadth, taken between the post-orbitary apophyses of the fronial bone, as 5 to 3 in the Indian elephant, and as 3 to 2 in th^ African elephant. 2d, The aperture of the nose is nearly in the middle of the iacc in the Indian elephant; it is one-fitth further re- moved from the edge of the alveolus than from the summit of the head in the African elephant. When seen from above, these crania differ, particularly by their zygomatical arcades j they Ifre more salient in the African than in the Indian elephant. When we look at them behind, we are struck with new- characters : l3t, The height of the v/mgs of the sphenoidal bones, forms in the Indian elephant more than three-fourths of that of the occipital surface, while in the African elephant it scarcely forms one half, 2d, In the African elephant the posterior extremity ot the zygomatical arcades is nearly on a level with the occi- pital condyles ; in the Indian elephant it is mtich lower. 3d, The occiput is terminated in the upper part in the African elephant, by a semi-elliptic curve, and its base is formed by two lines in a very open angle. In the Indian elephant, the sides are in convex arcs, and the upper part of the arc is slightly concave. ■ The grinders are placed in both species upon two lines which converge before; they differ only by their laminae, as we have said above. Most of the characters we have described, contributing to the -general configuration of the head, are sensible externally ; there is one still more prominent^ and which may, distinguish the two species at the first glance. 1 think T was the first to remark it : it consiiJts in the size of the ears. The Indian elephant has middling-sized ears : — they are so large as to cover the whole shoulders in the African elephant, , Vol. 30. No. 117. Feb. 1808. B I made 1 8 Memoir upon living and fossil Elephants, I made myself certain of the first point : 1st, In three elephants which I saw alive ; and I dissected two of them : two were fi*oni Ceylon, and the third from Bengal. 2d, In two other individuals which I saw in a state of preserva- tion. 3d, In all the figures well known to belong to the Indian species, particularly those of Buffon, Blair, and Camper. 4th, In the figure of a foetus elephant from Cey- lon, described by Zimmermann, in a quarto volume upon the subject *. ^ Upon the second point, I have the following proofs : 1st, The elephant from Congo, dissected by Duverney. We may see its figure in the Memolre pour scrvir d VHist. des Anim. par. iii. j and I tm sure that the ear is not exagge- rated, for it is still preserved in the Museum, and I have seen and examined it. 2d, An ear preserved in the king of Denmark's cabinet, and taken from an elephant killed at the Cape of Good Hope by captain Magnus Jacobi, in 1675. It is three feet and S half long, and two feet and a half broad f. 3d, A young African elephant in our Museum ; its ears, although shrivelled up by being dried, are still as large as its head. 4th, An embryo elephant from Africa, in our Museum. 5th, All the well-known figures of the African elephants. From these characters we may be assured from what species those figures have been drawn the origin of which is unknown, or such as are to be seen on antient monu- ments. Thus' that of Gessner J, copied by Aldrovandus §, is an Afirican elephant. That of Valentine ||, copjed by Labat^, and altered by Kolbc **, is equally so. On the contrary, those of Jonston ff, which are very good, and which have served as a model to those of Har- tenfelsjt, from which Ludolph §§ afterwards borrowed • Erlang, 1783, in 4to. f Oliger Jacobaeus, Mus. reg. Dan. 1697, fol. p. 5. f Quad. p. S77. § Quad. lib. i. p. 465. \\ AmphitheAtr. Zoot. tab. i. f. 3. 5 Afr. Occ. iii. p. 27 1. ** Relation du Cap. trad. Fr. in 12mo, tome iii. p. II. ff 'Qttadr. tab. vli. viii^ ?tix. \\ Elephantograph. curious, passim. §§ .^thiop. lib. i. c^^p. 9. his; Memoir Jipon living and fossil Elephants. I9 his ; that of Neuhof *, the tusks of which are too high ; that of Edwards f, the head of which is too round, because it is taken from a young subject, to which it was necesssary •to add tusks, are all Indian elephants. The two figures in BufTon J, copied by Schreber §, and by Alessandri||, are the two sexes of the Indian species, Mayer gives a tolerable figure of a male dauntelah^ (vorstell. allerh. thiere, i. pi. Ixix. ;) but the skeleton (ib. Ixx.) is copied from Blair, without any correction. The elephant foetus preserved in the East India Com- pany's house at Amsterdam, and represented by Seba, (tome i. pi. cxi.) is also of the Indian species. The limits between the Indian and African species was already distinctly enough traced with respect to the various parts of the head, and without having occasion to resort to the other characters, which we shall point out by and bye, and which are supplied by the number of the nails, and the forms of various bones of the limbs ; but before being able to apply with certainty the osteological characters of the cranium to the fossil elephant, we must determine what are the variable parts of one individual from the other, in one and the same species. 1 have therefore subjected my Indian crania to a comparison with each other, and I did the same with my African ones. The latter presented me with scarce any appreciable dif- ference. As to the former, T found svme with respect to the occiput and the alveoli of the tusks. The occiput is more swelled in every direction in the former than in the latter, without regard to» the length of the tusks. The alveoli of the tusks of th^ dauntelah are a little more oblique in front ^ those of the mookna are a little straighter towards the bottom. The latter are a little smaller, but by no means so much so in the proportion ^ of . the tusks themselves. What is * Ambass. Orient. Descr. Gen. de la Chine, p. 94. f Av. 221, f. 1. \ Hiit. Nat. xi, PI. L ct Suppl, § Quad. ii. Jab. 78. {| Quad. i. PI. ii. B 2 deficient ft<^ Membir upon living and fossil Elepkantsx ^cRfcrcnt in the size of the tusks is compensated by a greater thickness in the osseous substance of the alveolus. The Teason is, that the alveolus, serving as a base and a socket f6r the muscles of the proboscis, could not shrink as well as the tusks, without the proboscis losing the strength and thickness which is necessary for it. Lastly, There is a little variety in the length of the alveoli; and, what is very remarkable, even without any reference with that of the tusks. Our large mookna skeleton has riiem longer than our two dauntelahs, although its tuska are the smallest of all. To conclude, — this increase in length does not exceed an inch. It could not be considerable without the organisation of the proboscis being essentially changed, because the mus- cles of its lower part are inserted under the lower edge of the alveoli of the tusks, and those in the upper part are in the front, above the bones of the nose. The base of the proboscis has therefore necessarily for its Vertical diameter the distance between these two points ; and if the alveoli are prolonged beyond a certain measure, the proboscis would assume a monstrous size. It is very important to notice this article, because it fur- nishes the most distinctive character of the fossil elephant. If we compare together the small number of figures of elephants* skulls found in the works of naturalists, I do not think any stronger differences will be found than those I have riientioned. The table annexed to the succeeding article expresses ^ese differences by numbers. A celebrated author has supposed a difference between the crania of males and females, which we have not men- tioned, but he has been deceived by simple external ap- pearances. Our small mookna from Ceylon had, at the root of the proboscis, a very perceptible protuberance, which the female bad not. M.^ Faujas, imagining that this protuberance be* longed to the osseous parts, has represented these two heads in PI. xii. of his Essais de Geologic, *' In order to avoid/' he says, p. 238, <* falling into an error, when we find Memoir upon living and fossil Elephants, 21 find the heads of a male and female fossil elephant, we must not mistake them for two different species." Dissection has shown us, however, that this protuberance was only produced by two cartilages peculiar to elephants, which cover the entrance of the canals of the proboscis into the osseous nostrils. These cartilages were a little more swelled in this indi- vidual than in the others. It is not even a character common to all males. The dauntelah of Bengal had it not. The same learned geologist has given to his figures much larger tusks than these two individuals had in reality, ^^ In order," he says, p. 26j^, ^^ to make those understand, who never saw an elephant, the manner in which these animal* carry their tusks." It was not necessary, however, to give large tusks to the female, which never has any in the Indian species. Article VIII. Examinatioji of the Cranium of the fossil Elephant, The cranium was very cellular 3 the osseous laminas com- posing it were too thin to be preserved in the fossil state : they are therefore found in innumerable fragments ; but three only are mentioned as being in a state of good preser- vation, and the most entire of the whole wants a part of the occiput. They belong to the Petersburgh Academy * ; the best was found upon the banks of the river Indigirska, in the most eastern and coldest part of Siberia, by the learned and intrepid Messerschniidt of Dantzick, who gave a drawing of it to his countryman Breynius. The latter had it en- graved at the end of a memoir he inserted in the Philo- sophical Transactions fj and to this day it is the only public document ne have upon this part of the skeleton of the fossil elephant. I have copied the figure of Breynius in PI. ii. fig. \, be- sides the African and Indian crania; and I have reduced the three to the same size nearly, in order to facilitate their * Pallae, Noy.Com. Petrop. xui. | Vol. xl. n. 446, pi. i. and Ji. B 3 comparison. 29 Memoir upon living and fossil Elephants, comparison. The first glance shows that the fossil ele- phant resembles, in its cranium as well as in its teeth, the Indian species rather than any other. Unfortunately the drawing is not correct enough for an exact comparison, and it is not made upon a weil-deter- mined projection. The part of the alveoli, that of the con- dylon for the lower jaw, and the anterior edge of the temporal hollow, and of the orbit, are seen a little obliquely behind, while the occiput and the grinders are in a rigorous profile. We see distinctly enough, however, a striking difference in proportion in the extreme length of the alveoli of the tusks. It is treble what it would be in an Indian or African cranium of the same dimensions ; and the triturating sur- face of the grinders prolonged, in place of meeting the alveolary edge, would intersect the tube of the alveolus at one-third of its length. This difference is so much the more important as it agrees with the form of the lower jaw, as we see below ; and, as we have already said, it would of necessity produce an- other conformation in the proboscis of the fossil elephant ; for where the sockets of the muscles of the proboscis were the same, i. e, the upper part of tjpe nose and the lower edge of the alveoli of the tusks ; in this case the base of that organ was three times larger in proportion than in our living elephants ; or rather the sockets of the muscles were different, and a fortiori its total structure was different. If we could trust entirely to drawings, we should also fjnd> 1st, That the zygomatic arcade is differently figured; 2d, That the post-orbitary apophysis of the frontal bone is longer, more pointed, and more crooked; ,3d. That the tubercle of the lacrymal bone is much larger and more salient. As to the absolute size of the fossil cranium, compared with our living crania, we may form an idea of it from Plate iv. fig. 9, MO, 11, where I have represented the three crania in front, and upon the same scale, We may form a still more correct idea of their size from the following table, in which I have collected the dimen- iions of all th? crs^nia with which I am acquainted. TsiblQ Memoir upon living and fossil Elephants, 2» Separate ditto of the African Skeleton. • o •o «o CO r-« CO lO «o »o o> C^ lO CO o 6 CN CO CO »o "^l* ^ 6 6 6 6 6 o nium to can ton. ' CO 00 CO C« -^ Ol ai »o CO g 2--SS-3 b^ CH • OQ »0 »0 • • • ^ . O G1 fO If »^. CO 1-^ f-, (O CO CO CO CO CO <» ^ CO 6 6 6 6 6 6 6 ? ■ j:; . V ■ .^-B rt o o ^ S fO '^ ^^ Tt* ^ O 0^ -^ t— t *>* CO • "* t^ O iO -^ ^ '«! 6 o 6 ■ 6 6 6 6 CO CO T> tJi "^ »o •»• «o ^. •S ti-^ t> o w C3 »o ^•-|H 00 '^l^ Tf t^ CO CO rf 6 6 6 6 6 6 6 „§ nium e grea Skelet short eth. »o t^ «0 CO 00 CO Oi a to »--. ^* 00 Tt< -^ a ) CO CO »o 6 6 6 6 6 6 6 .-2 c«i i ll"^ 00 CO 00 rani ol ersc 11. T xl. t^ s CO 00 " p-l K^ 6 6 ^ § fci ranium of the :ersbiirg .cademy sured fr( Drawin * •> 00 1—4 CO cc c > . " ^^3| '^ 6 6 o *-> 4) o 1i • 1 • c o -o • *S *^J-I rj *§, . s ^ ' u-1 • *"^ : ^4-4 * o y *o t ^ 9m> • o • o aj e 3 in o • .£ c o o '3 5-S 5 ^ * 4^ * '(in M "*^ CO O w .T-. S -1 o a o o si ! 8:1 tii > CO p. !? : 2 >. g S 5 Q.^ 2 ^ rt I JQ 1 u O cc fa J w-a ^ o c« f« -;i cS _i b o Q B4 But $4 Memoir vpcni living and fossil Elephants, But in order to infer from any one of these crania the dimension^ of the animal to which it belonged, it is not necessary to refer to its first dimensions, into which the excessive length of the alveoli of the tusks enters ; these oiily should be taken into consideration which are really homol.)p;ous. Now, by comparing them with those of the cranium of our Indian skeletons of the mookna and comerea, we find that the fossil animal must have been nearly twelve feet high. A comparison with the skeletons of the Indian dauntelah and meyfiBe would give a little more to the fossil. As soon as I was acquainted with this drawing of Messer- schmidt, and added to the differences it presented those I had myself observed in the lower jaw and in some isolated teeth, I no longer supposed that the fossil elephants were of a different species from those of India. This idea, which I first announced in a memoir to the Institute, opened quite new views to me upon the theory of the earth ; a hasty glance at other fossil bones induced me to presume every thing I have since discovered, and determined nie to devote myself to the assiduous researches and tedious labours in which I have been occupied these ten years past. I ought therefore to acknowledge, that it is to this draw- ing, buried as it were in the Philosophical Transactions for seventy years, that the public are indebted for all those Works upon which I set so high a value. I must not dissemble, however, that the characters it presented me required to be confirmed by some other speci- men, in order that they might not be considered as the same species, and in spite of their agreement with those of the lower jaw, I was happy to find a drawing of another cranium. I ap|1ied to the Petersburgh Academy; and this illustrious body, to which I now belong, complied with my wishes, with a generosity worthy of a Society to which science is so much indebted. The Academy ordered a superb coloured drawing of the natural size to be transmitted to me of another fossil cranium from Siberia, in their collection also. It was accompanied with Memoir upon living and fossil Elephants. 25 with a drawing of the lower jaw of a cranium of a rhino- ceros, in two positions. In these drawings I found a con- firmation of what I had conceived from seeing Messer- schmidt. The cranium, which served for the model, is not so com- plete. The grinders, and a part of their alveoli, are want- ing, as well as the middle part of the zygomatical arcade. Nothing characteristic is however missing : there is the same'length and the same direction of the alveoli ; the same size of the lacrymal tubercle_, and the same general form : every thing in fact convinces us that the fossil skulls partake of the same characters. I have carefully engraved this fine drawing in my Plate viii. fig. 2. The parallelism of the grinders is a difference which may be established independently of the drawings of Messer- schmidt or of the Petersburgh Academy. / M. Jaeger assures me of the same fact, with reference to a portion of a cranium in the Stutgard cabinet, and which may be found in my Plate \v, fig. 4 : another piece, drawn by Peter Camper, shows the same character*. I have copied his figure, Plate iv. fig. 3, and I have placed beside it fi^. 1 and 2, those of Indian and African crania, seen from below, in order to show the more remarkable convergency of their front teeth. We have in our Museum a portion of the occiput and of the temporal bone of a fossil elephant, brought from Sibe- ria by the astronomer Delisle, which aflforded me an oppor- tunity of comparing these parts more closely than the others, of which I had drawings only ,• but I found some very trifling differences ; I have given a back view of it in fig. 7, and a lateral one in fig. 8, of Plate iv. This specimen be- longed to an elephant ten feet high. * Mem. de Haarlem, torn, xxiii. P1.D. IV. Ob- ■ [ 36 ] IV. Observations upon the Employment of M. Guyton- MoRVEAu's Fuinigations for preventing contagious In* fection. By M. A, Hedouih, Physician*, 1. HE prison of Mont Sanit Michel, from its situation, stood more in need that any other of some chemical agent to correct the numerous locial vices in point of salubrity. Putrid and malignant fevers, so familiar among individuals crowded together in the same place, using food of slender succulency, and overwhelmed with grief and sorrows, raged with unceasing fury in the prison of Mont Saint Michel. Juniper berries and incense were frequently burned in the cells ; but instead of changing the atmosphere and neutrali- zing the vapours exhaled from the bodies of the sick prisoners, these means only disguised the sniell. From the moment M. Morveau's method was resorted to, the number of these fevers, and of course the mortality, sensibly diminished. . In ocder to be convinced of these truths, it is sufficient, in my opinion, to inspect the necrology of this prison, and to compare the mortality of various years, having an eye to the increase and diminution of the number of prisoners. Necrology of the Prison of Mont Saint Michel, from the Year 1 802 . to the Year 1 807. Years. Number of Number of Prisoners. Deaths. Observations. 1802 from 96 24 The oldest had not attained his to 100 70th year; all of them died of putrid fevers, with few exceptions. 1803 100 11 The oldest not 50. 1804t from 96 21 The putrid fever carried off 17-: to 100 two prisoners who survived it lost all their toes. 1805 120 9 Two only died this year of putrid fevers. 1806^ No putrid fevers during these and V 140 6 fifteen months, being the 1807 J whole of 1806 and three months of I8O7. ♦ Ann^ de ChimiCy torn. hii. p. 113, f Jn this year the regular use of fumigations was ordered, and the prison was furnished with two sets of jVI. Dumontier's apparatus. It On Fumigations for preventing contagious Infection . 27 ' f It was ill the year 1801 that I succeeded M. Komilly, who fell a victim to a putrid fever, which he caught while administering relief to the prisoners ; and 1 was astonished to find more than one half of these unfortunates attacked with this species of fever. ^._4;^,«s^^*^c. The cells of the prisoners had a fetid smell, of so pungent and tenacious a nature that my clothes retained it four-and- twenty hours after their exposure to the i'rQc air. In these circumstances I hastened to employ M. Guyton's process* A mixture of muriate of soda, black oxide of manganese, and sulphuric acid, was put into proper vessels, which I ordered to be taken into the cells several times. This process was repeated the following day by M. Ifidou. These experiments were attended with no accident what- ever, and produced a very seasible diminution of the fetid smell with which the air of the prison was impregnated -, and we had the satisfaction v^ery soon of seeing the epidemy of putrid fevers also diminished. In order to obviate the dangers which this mode of cleans- ing the atmosphere presents, particularly where there are no other apartments to remove the patients into, M. Costaz, prefect of the department, furnished us with the large apparatus of M.' Dumontier, since which period these machines are carried through the hospital several tiiijes daily. Since the commencement of 1804, the number of pri- soners has increased one-third ; the structure of the cells • has not been changed, the same misepy pervades every corner of them, nor has the amelioration in the food of the miserable inhabitants arising from their labour, been suf- ficient to change the nature of the diseases vvitli which tjiey are infected ; and yet putrid fevers have almost entirely dis- appeared, I am certainly of opinion that M, Guyton*s process was \^ the means of extinguishing the putrid fever in the prison. 1 am the more inclined to believe in its efficacy from ilie • circumstance of this fever being epidemical in several neinh- bouring districts, which occasioned an order by the prefect to fumigate the churches; and from the year 1804 to this period, v> 98 On the Effects of Fumigatmjjs period, there have been only four cases of putrid fever m the prison ; a striking difference, when we consider the mor- tality frorn epidemies in the preceding years. V. Letter from M. Guyton de Morveau upon the Effects of Fumigations in Epidemies of Cattle^ and for the Destruction of putrid Miasmata *. 14th of April, 1807. X HE communication of M. Hedouin has induced me to think that it would be interestirig to publish an account of the advantages resulting from the employment of my anti-contagious process on other occasions. I am extremely sorry to observe, however, that in spite of the solicitation of the government, this method is not generally known or practised j for in the Journal de Paris of the 1 7th instant, we find that a contagious- disease appeared in the prisons of Dreux, and that all the judges of the tribunal of criminal justice had been seized with it and died. The following two facts I have received from undoubted authority : 1. About the end of last autumn, the rot made its ap- pearance in some parishes in the department of Loire and Cher. Madame de P., the proprietor of two flocks of Merino sheep, ordered fumigations of oxy-muratic acid to be made in the folds and stables : at first in open vessels, by pouring sulphuric acid upon the mixture of sea-salt and oxide of manganese ; and afterwards, by means of the large apparatus. The success of this induced her to intimate throughout the parish, that she would lend the apparatus to those wlio had diseased sheep. A farmer in the same commune had al- ready lost several sheep, and he applied the preservative. He opened the apparatus twice a-day, for three minutes at each time, according to the instructions he had received. The rot became mild ; one half of the flock were not affect- ed with it, and he did not lose a single sheep. * AnTu de Chimitf torn. liu. p. 119. Two in the Epidemies of Cattle, 29 Two other farmers of the same commune made a simi- larly successful experiment. Their diseased flocks were al- lowed to pasture along with the heahhy, the latter having been previously fumigated in the folds, and no contagion was communicated. The apparatus has of course become . of general use in the department. 2. The second fact was communicated to me by th6 di- rectors of the hospitals at Besangion. Several hundred weights of meat had been left neglected for some tinle in the cellar of the public hospital : it diffused so infected a smell that it was impossible to enter the place to carry it away, and a pitch-fork was used for that pur- pose. They afterwards introduced into it, with the same precautions, a flask of anti-contagious gas, the flap of which was opened and the door of the cellar was closed. When this flask was withdrawn a few hours afterwards, there existed no smell whatever, except that which was diffused by the oxy-muriatic. Its emanations having been very strong, the window was opened, in order to procure a current of fresh air. The cellar was then so completely purified that fresh meat was pat into it and completely pre- served. The stench occasioned by the carcase of a dead rat was also destroyed in a few minutes, by the use of the same apparatus. The hospitals of the department have been since provided with the regular fumigating apparatus ; and glass bottles, containing a supply of sulphuric acid, nitre, and sea-salt, are placed in the halls, with which the fumigations are repeated every evening. The benefits resulting from these precau- tions have been felt in an astonishing degree. Besangon is always crowded with prisoners of war and, wounded sol- diers, among whom no contagion whatever has made its appearance since the adoption of this salutary process. VI. Ex^ [ 30 ] VI. ILxptrlments upon the liquid Sf/lphur of Lampadins* By Messrs, VAuauELiN and KoBiauET *'. Process, X-rfAMPADius, who was the first, to observe this particular fluid, which he callcd*//(/7/?c? .udphnr, obtained it by the disi illation of pyritous turfs, and pyrites mixed with a cer- tain quantity of charcoal or saw-dust. Messrs. Clement and Dcsormes employed the charcoal and sulphur in order to form completely the liquid sulphur, which M. Lampadius considered as a combination of sulphur and hydrogen ; but these chemists announced the process as bfeing very difficult in its execution, since they had only succeeded once out of twenty times. Nevertheless, three successive experiments have furnished us vi'ith results equally satisfactory, and we have not remarked that they have any other essential pre- cautions than that of cooling the flasks adapted to the ap- paratus, in order to avoid the volatilization of 'this singular substance. We therefore took, as Messrs. Clement and Desormes directed, finely pulverized charcoal ; we employed it in a very dry state, and introduced it into a porcelain tube, to which was adapted, by one of its apertures, a small retort containing sulphur; at the opposite extremity we placed a large tube with a simple curvature, which was in- serted into a flask three-fourths filled with water; care was taken to make a hollow in that part of the tube which en- tered into the water, in order that it might serve as a tube of safety for the porcelain tube; this first flask, which ought to have three tubulures, has a straight tube at one of them, and at the third, a tube communicating with a second flask surrounded by snow or pounded ice ; to this last \\q adapted a tube, crooked so as to collect the gases. Things being thus arranged, the porcelain tube is stropgly heated in a reverberating furnace ; when it is red-hot the sulphur vo- latilizes ; after a certain time, there passes into the first flask a liquid of a citron yellow colour, having the appear- aince of an oil, collecting into globules upon the surface of • Ann, ie Chimie torn. kl. p. 14^, Expeiiments upon the liquid Sulphur of Lampadins, 31 the water, and falling to the bottom of the liquor whe^i they have acquired a certain volume. If we pass too great a'quanlity of sulpliuFj a portion joins this oil and gives it more colour and density ; the other is condensed in the first glass tube, and is fixed the instant it comes in contact with the water. If the first flask is so near the furnace as to make the temperature exceed 20 or 25 degrees of Reaumur, the liquid sulphur boils, is volatilized, and passes into the second flask, when the cold water completely condenses it. We remark, that when we heat the charcoal alone, there is continually liberated carbonated hydrogen gas mixed with carbonic acid ; that as soon as the sulphur passes, sul- phuretted hydrogen gas is disengaged in very great quantities, and that as soon as the liquid sulphur begins to be formed, little or no gas is liberated. Physical properties. — The liquid sulphur obtained in the first operation is of a citron yellow colour, which seems to be merely accidental, and owing to a superabundant portion of sulphur, siuce by a new distillation we obtain it perfectly colourless, very transparent, and of great fluidity ; there remains in the vessel where it has been rectified a portion of sulphur, which unites in a mass or in small regular cry- stals if the distillation has not been carried too far. The density of liquid sulphur is considerably more than that of distilled water ; it has a very strong, fetid, sulphurous, pun- gent, and garlic-like smell. It has an extremely sharp, pungent, and very cold taste. The astonisbing facility with which this fluid decomposes the light announces its great combustibility. Chemical properties. — When exposed to the air in anv vessel, it vaporizes very speedily, and without leaving any residue, Wh^n it is very pure : if we bring it within a few inches of an ignited body it takes fire very rapidly, yields a white flame, which latterly becomes purple; it difl^uses a suffocating smell of sulphurous acid, and deposits upon the sides of surrounding bodies a yellow dust in every respect resembling sulphur. The water in which the liquid sulphur has been received assumes a milky appearance in a few hours; and the vessels are 32 Expo'iments tipon the liquid Sulphur of Laynpadius. are spotted with some deep black specks. This water has the same smell with the hquid sulphur, although much weaker, it possesses the property of precipitating several metallic solutions, and particularly those of lead in an orange yellow, that of oxigenated nmrcury in white, that of tin in brick-coloured yellow ; it does not redden turnsole. Concentrated sulphuric acid does not seem to have any very remarkable action upon this substance ; latterly, how- ever, it dissolves a certain quantity, and acquires a fetid smell. The nitric acid seems to make it undergo more alteration ; the liquid sulphur at first occupies the upper part of the liquid, but upon agitation it is divided into globules, which unite with great difficulty. Upon placing this mixture in a convenient apparatus, so as to make the gas pass through lime-water at a heat of 13 or 18 degrees, an elastic fluid is liberated, which dots not disturb the lime-water, and which inflames with the same colour as oxide of carbon. But the combustion takes place instantly, and sulphurous acid is extricated after a very pungent smell : the heatiiiust be extremely well managed, otherwise the sulphur would pass into the lime-water. The nitric acid employed in this operation contains no trace of sulphuric acid ; when we put it nUo oxy-muriatic acid gas it acquires a citron yellow colour, and in a few seconds that of the gas disappears ; and if we place it in contact with the atmospheric air, it diiiuses a very fetid and arsenical -like smoke in great abundance. It has the property of taking fire upon being bror.ghi near an ignited body this gas when well washed also aifloimes, and after combustion exhales a smell of i^ulphurcus acid, stronger or weaker in proportion as it has been more or less washed. We poured upon the liquid isulphur a mixture of the sul- phuric and nitric acids, but there was no inflammation, and the action even seemed to be confined to a simple solution, at least by diluting it with a certain quantity of water the whole became perfectly clear. Some experiments seem to show that the weak acids have more action upon this sub- jitance then the concentrated ones. I Pure Experiments tipon the liquid Sulphur of Lampadm. 33 Pure caustic potash acts very feebly upon liquid sulphur : after some time, however, it is coloured^ and acquires the property of precipitating several metallic solutions in colours peculiar to this combination. .... \ Ammonia seems to dissolve it a little more easily, it assumes a deep yellow colour, and also precipitates the me- tallic solutions : caustic bar)'tes dissolves it also in a greai proportion, and . assumes an orange colour ; it precipilalei the metallic solutions in the same manner. jfUftv-r-Tt Alcohol seems to dissolve it in any proportion, the solu- tion is abundantly precipitated by water, and the sulphur unites in small globules, which fall to the bottom of the liquid. < We sec from these first efforts, that nothing Whatever in- dicates the presence of carbon in liquid sulphur, and they authorize us to think that it is only hydrogenated sulphur, if not to suppose that sulphur itself is a compound body, ■ The action of the oxygenated acids upon this substance ap- pears very remarkable, and seems to indicate a state of sul- phur analogous to that of the charcoal and the azot in the gaseous oxides of carbon and azot. Nbte by M. Vmtqzielin. — The above experiments were made at my request, by M. Robiquet. They are still far from demonstrating the nature of the elements of liquid sulphur : we should have continued them if M. Berthollet ]un. had not announced to the Institute that he was en- gaged in a similar investigation. I should not now have published these facts, if I had not.also informed the Insti- tute that I was of the same opinion with M. Berthollet, having been busy in examining the composition of liquid sulphur, and that I had even given M. Biot a considerable quantity of it in order that he might expose light to its action, and determine if possible, by its refra'ngent power, the portion of hydrogen it contained. Vol, 30. JJq. 117. F^l, 1808. C Vri. Let' [ 34 ] VII. Later from the Right Honourable Earl StAnMopE, relative to Dr. Callcott's Pamphlet on the Stanhope Ternperameut, To Mr, TillocL -, SIR, Stratford Place, Feb. 3, 1808. 1 HAVE just read the paper *^ On the Stanhope and other Temperaments of the Musical Scale " which is written by Mr. John Farey, and published in the last number of your Philosophical Magazine. The inaccuracy of Mr. Fa- rcy's statement obliges me to inform you correctly what the facts were. Some months ago I received from Dr. Callcott a printed copy of a pamphlet, entitled, " Plain Statement of Earl Stanhope's Temperament, by Dr. Callcott" He begged me to look it over, and to correct it, previous to its publication. But, at that time, I was extremely busy about my nautical and other important pursuits, which made it very incon- venient to me to comply with his request. I received from the Doctor a letter, dated June 10th> 1807, of which the following are extracts, viz. " Curiosity has been so strongly excited by the Stanhope Temperament, that I thought it my duty even to record mv own errors on the subject ; and therefore have printed 500 copies of the pamphlet, not to sell, but merely to distribute hereafter, as evidence how incorrect, imperfect, and in- complete my notions were, compared with the improve- ments now making by the superior mathematical and expe- rimental researches of Earl Stanhope." *' I have ordered the advertisement of publication to be inserted in all the papers for the 26th of June, and I pledge myself to print it exactly conformable to your lordship's corrections, which real copy will be sufficiently distinguished from the spurious one, by the sole insertion of the four pages of music at the end. *' Immediately on the receipt of your corrected proof, I shall commence my Letter to the duke of Cumberland, to whom of course I have not yet applied 5 and I have also considered Letter from Barl Stanhope. '' "^ 35, considered that the duke of Cambridge ought to have a separate and particular address on the subject ; and therefore another pamphlet, containing a narrative of my original disHke and subsequent recantation, will be (I am sure) in- teresting to his royal highness and all the world." Finding by that letter that Dr. Callcott had already ordered *^ the advertisement of piilUcatlon to he inserted in all the papers for the 26th of Jime," 1 resolved to take the trouble to correct that printed copy ; and, when I had cor- rected it, I returned it to Dr. Callcott. I did this merely out of good nature, and in order to prevent an imperfect statement of 7ny temperament from being published, wheri. it was in my power to make it more correct. Dr. Callcgtt did himself send, by Mr. Fergusson, that corrected copy of the '' Plain Statement,'' to Mr. McMillan the printer, with directions from him (Dr. Callcott) to print the same. He also sent, by the same person^ to the same printer, the manuscript of his letter to the duke of Cumberland. These facts are a sufficient refutation of the idle reports which have reached Mr. Farey upon this subject. As Mr. Farey has obliged me, nmch against my wish, to take up my pen again on his account ; I must freely confess that I can perceive no merit in his calculations. I have expressed the length of the wire which yields the sound of the perfect qidnt G, in the correct, precise, and plain language of two thirds of the length of the wire which yields the sound of the key-note C. This docs not, how- ever, satisfy Mr. Farey. He is not contented till he has told us, that two thirds may be expressed by '6066666 ad infinitiim. ^ He is not even content with this; for he introduces, moreover, what he terms a '^ new iwtaiion ;'' and he ex- presses ^^ the relation ivkich the note G hears to the funda- mental note C, according to the Stanhope Temperament,'^ as follows, namely, by 338 2 {ox schismas), + 7 f (or lesser fractions) . + 31m [ox the most miJiute). This he no doubt considers as greatly advancing the cause C 2 of 36 On the Decomposition of the Acetate of Barytes of science, and as rendering the study of music both more pleasant and uueliigible !!! What would any man think of a mathematician who should express the number 8O91 in the following manner? 8000 + 600 + 3 score + 2 dozen 4- 7. The difference between a man of real science, and one who has the ambition to be thought so, is very great. The first seeks to render difficult subjects, perspicuous and clear. The other, on the contrary, envelops even the most simple ideas in the mysterious garb of hard words and scientific jargofi. If Mr. Farey he of the first of those two classes, I should recommend to him to simplify and amend his tables. I am, sir, your most obedient servant. Stanhope. VIII. Upon the Decomposition of the Acetate of Barytes ly means of Soda. By M, Darcet*. jLn a late number of the Annales de Chimie f, M. Porperes says, when speaking of the formation of the acetous acid in bad digestions, that in 9rder to ascertain the presence of this acid, '^ he saturated it with pure soda, and afterwards decomposed the acetate of soda by barytes ;" and he adds, '^ that having set the soda free, he dissolved it in alcohol, which, by seizing upon the water of solution, operated the precipitation of the acetate of barytes which was formed.'* ^The result of this experiment is necessarily inaccurate, as the following details will prove. I suppose that .we have a solution of barytes saturated .bot: if we pour it into acetate of soda, there is immediately precipitated an infinity of small brilliant and iridated laminas. * Ann, de Chimie^ torn. l»i. p. 247. f See Phil. Mag. vol. xxvii. p. 352. hj means of Soda. 37 If we separate them from the liquor after its complete cool- ing, if we wash them in the smallest quantity of water possible, and dry them speedily by squeezing them between several sheets o^' blotting paper, we shall have nothing but pure crystals of barytes without mixture of acetate. I as- certained this in the following manner : 1st, T exposed a part of these crystals to the air : in a few days, the distilled water with which I washed the carbonate obtained, gave no more precipitate by the a-ddltion of the sul* phuric acid, the carbonates, or alkaline sulphates. The whole mass of crystals had therefore been converted intocarbonatCj which would not have taken place if they had contained acetate of barytes. 2d, I dissolved two or three grammes of these same cry- stals in distilled watery the solution blued turnsole paper which was reddened by an acid ; there was an excess of al- kali therefore. I added some drops of sulphuric acid to this solution, and there was formed a solution of sulphate of barytes. I tried the liquor again with the reagent paper, and I still found an excess of alkali. I added by degrees siil phuric acid, until there was a slight excess of acid in the liquor : I filtered it, and found no more barytes, but a little free sul- phuric acid ; this would not have happened if the crystals had contained acetate of barytes : for upon this supposition^ at the moment when the excess of acid beo;an to become sensible to the reagent paper, there must have been only a very small quantity of acetate of barytes decomposed, and acetous acid set at liberty. The filtered liquor should there- fore have contained a slight excess of acetous acid, and more acetate of barytes not decomposed; which is contrary to the result of experiments. 3d, Tlje mother water of the crystals employed in the preceding experiments, should contain nothing except the little pure barytes which the cooled liquor could hold in solution, besides the whole of the acetate of soda which had been employed. What also demonstrates the analysis of these mother waters, is, to pour alcohol into them as- M. Porperes points out* The brilliatit lanunce which are Xiomod^l C3 deposited 38 On the Decomposition of the Acetate of Barytes deposited are nothing else than crystals of barytes : when tried as I have pointed out above, they only give very pure carbonate of barytes, and not an atom of acetate. If we also try these mother waters with the sulphuric acid, or with the alkaline carbonates, we immediately ascertain that they contain but little barytes, and plenty of acetous acid : this becomes still more perceptible if we evaporate them to dryness, and redissolve the residue in distilled water : for this solution no longer contains an atom of barytes, but merely acetate of soda ; the little barytes in it being carbo- nated during the evaporation. Hence it follows, that barytes does not decompose the acetate of soda, and that, on the contrary, if we try the inverse experiment it will succeed. In fact, we shall decom- pose the whole of the acetate of barytes by adding a suffi- ciency of pure soda for saturating the whole acetous acid. It is not my object to invalidate the conclusion in M. Por^ peres's memoir: they appear to be just, and conformable to what is already known. I criticize one of the proofs onlv they have furnished, and I proiit by this occasion to mention that M. Aufrye and myself have already published, in the Annales de Cliimie, a memoir upon the Affinities of Barytes ; wherein we have proved that in the classification of the alkalis, barytes Should not be placed before potash and soda, except with respect to the sulphuric and carbonic acids ; that in every other circumstance, potash and soda have affinities superior to that of barytes. How docs it hap- pen, then, that notwithstanding the facts so clearly demon- strated in our memoir, various authors have continued barytes in its old order of affinities ? In my opinion, the results published of experiments ought to be adopted, or refuted by repeating them and showing their errors. i shall conclufle this note by calling to my assistance one of the processes, the excellence of which has been demon- strated in our operations upon barytes on a large scale ^-r-it is naturally inferred from the facts above laid down. , The decomposition of the muriate, the nitrate, and the acetate of. barytetf, by potash and soda, is so complete and easy, thai it is qcrtSiinly the sipiples^ \vay pjf procuring in a laboratory hj means of Soda, ^9 laboratory the barytes we require. For this purpose we strongly calcine^ in close vessels, 100 parts of sulphate of barytes well mixed with 20 parts of charcoal in powder. After an hour's calcination the crucible is allowed to cool ; the residue is separated from it ; it is then diluted in water, and a sufficient quantity of rutrie acid, muriatic acid, or acetous acid, is added to it : the mixture is then slightly heated, which liberates a great quantity of sulphuretted hy- drogen and carbonic acid, of which we must be upon our guard. When the effervescence ceases, and the reagent paper announces in the liquor a slight excess of acid, we filter and evaporate it, in order to decompose the sulphuretted hy- drogen, and to precipitate the sulphur which was held in solution*. The residue is re-dissolved in the least possible quantity of water, and we add to this solution a saturated so- lution of caustic potash. There is precipitated, even at the moment of mixture, a great quantity of crystals of barytes ; the whole is then allowed to settle at the lowest possible tem- perature for an hour or two : the mother water is then de- canted, the crystals are washed with a little distilled water, and dried by pressing them between several sheets of blotting pa- per, and they are dissolved in the necessary quantity of boiling v^^ater : the filtered liquor deposits the barytes upon cooling, which by this process is far purer and cheaper than that ob- tained by decomposing the nitrate of barytes, by exposing it alone to a high temperature. It must be observed, that we ought to prefer the employ- ment of the muriatic or acetous acid to that of the nitric acid ; in the first place, because the first two acids form with barytes, salts more soluble than the nitrate, and the washing is easier in this case : secondly, because in the so* lution, the nitric acid, on being decomposed, oxygenates a part of the sulphuret of barytes, and there is then a portion of acid lost, and a part of the barytes absorbed by the sul- phuric acid which is formed. As to the caustic potash required in this operation, it is # * We may more easily obtain thd same end by pouring into the liquor some drops of nitrate of copper or lead, by allowing the metallic sulphuret to subside, and by filtering over again, &c. C 4 essential ,4^ Upon ilie Preparation of pure Barytes* essential that it should be prepared with cirbonate of potash free from sulphate ; we may render it caustic by following the process published by M. Descroizilles in the Annales de Chimie^, I have frequently pursued the methods he points out, and I have done so with increasing advantages. i Observaiions ly one of the Editors of the Annales de Chimie upon the foregoing Article, I have examined the liquor of the flask transmitted by M. Darcet along with his paper. It was more than half filled with small white crystalline lamince; the liquor greened strongly paper coloured with the petals of mallows. I poured sulphuric ajcid into it in a slight excess ; there was formed an abundant precipitate of sulphate of barytes ; at no time was there the least smell of acetic acid. After having fil- tered the liquor in which the precipitate was formed, I eva- porated it in a gentle fire in a platina crucible, and it left no traceof neutral salt. There does not remain a doubt, there- fore, that the acetate of barytes is radically decomposed by soda.— L. B. G. IX. Upon the Preparation of pure Barytes. By M. Roj?iciUETt« In a note inserted in a late number of the Annales de Chi- mie X, upon the decomposition of the acetate of barytes, by means of soda, M. Darcet points out as a more ceconomical and more certain process of procuring pure barytes, to de- compose any barytic salt, and principally the muriate, by a caustic alkali : I do not think the preference he gives to this process over the generally employed one, namely, the de- composition of the nitrate by heat, is w«ll founded. On considering the matter in an ceconomical point of view, wc see that in both cases we must first oi>taia a soluble salt of barytes; that in the first wc cannot employ the liquors so * .See Phil, Mag. vqi. x?^iii. f Ffom Annates de Chimie, torn, Iiii. p r>i. J See the preceding article, much Vpon th Preparatlbfi'^df'plTe Bar?/feL '^l much concentrated that no barytcs remains hi solutian ; that whatever precaution we may take in the preparation of the '«anstic alkah by Hme, if not during the fihrations, there will alwavs be a portion of it carbonated; consequently, the t^ame quantity will be w:inting in the quantity of baryte^j we ouglit to obtain: that, besides this, during its precipitation, as we are obliged to shake the liquor, it carbonates a certain (|uah- tity of it: that by washing also we experience a feal loss,; and lastly, that by a hew soiutit)n in boiling water it carbo- nates still more of it ; ' it is visible that all these subtrac- tions united leave but a small quantity, while by the de- composition of the nitrate we absolutely obtain 'tfate %hoTb quantity of barytes it contains, and which amoiints to very near the half of the weight of dry salt j and that besides, this operation is neither difBcult nor expetisive, when we know how to manage it properly. Nov/ the following arc the precautions necessary to ensure success : Fill near two thirds of the crucible with dry and pulve- rized nitrate ; place the crucible with its lid in a common furnace, in a gentle heat, so as merely to melt the salt rn Its water of crystallization; increase the fire progressively and with caution, on account of the swelling up which latterly takes place: when the mass, which should be then of a cherry red/ lets no more bubbles escape, cover the cru- cible with an inch or two of charcoal; adapt to the furnace its dome provided with a pipe of gun metal : heat it thus for a quarter of an hour; take the crucible from the fire; 'break it, and pack up the barytes as quickly as possible. I also treated by this process seven pounds* 6f iiiiraie, which I had divided into three common crucibles and placed in one furnace : I produced the complete decomposition in two hours, and T obtained three pounds six ounces of per- fectly pure barytes. But it must be observed, that if the ba- rytes is kept too long in the fire after the decomposition of the nitrate, it is carbonated considerably, and it is afterwards completely impossible, whatever heat we employ, to deprive it entirely of carbonic acid. This is the whole difficulty at- tending my operation. I am therefore of opinion that it is p I really 42 Upon the Comlination of the fixed Oils really more oesonomical to extract barytes from the nitrate by means of fire than to follow M. Darcet's process ; for, even supposing that the quantity of barytes was equal in botJi cases, what I have demonstrated could not exist — the price of the potash I was obliged to employ would have cost me almost double the expense. As to the purity of the article, as we are obliged to manage the washings carefully, I do not see that the process of M. Darcet merits the preference in this respect j for it is very probable that the barytes thus obtained should retain a little of the salt contained in the mother water ; and, on the contrary, that extracted from the nitrate is extremely pure, if before decomposing it we take the precaution of calcining it slightly and redissolve it, in order to separate a portion of the iron proceeding from the sulphate employed. X. Olservations upon the Combination of the fixed Oils with the Oxides of Lead and the Alkalis, By M. Fremy, Apothecary at Versailles*, fccHEELE was the first who observed that the water which serves as an intermedium, when we treat the fat oils or the fats by litharge, retains in solution a substance to which he has giv^ the name ef sweet principle of oils ^ because it has, in fact, a very decided saccharine taste. But, according to. the observation of this illustrious chemist, this water hold- ing also in solution a certain quantity of oxide of lead, may we not think that the taste, which suggested to him the name of the sweet principle, proceeds from the property pos- sessed by this metal of communicating a saccharine taste to most of its combinations ? Where experience has demon* Strated the contrary, would it not be interesting to inquiry how this principle came to be formed ? What are its proper- ties ? In what state the oil exists after having abandoned thq principles which should have given rise to it? If this sub- traction it) absolutely indispensable for forming the combi- • From Annales de Chimie, torn. Ixii. p. 25. nation with the Oxides of Lead and the Alkalis, 43 natioa of the oil with the oxide of lead ? And upon the ex- periments which these inquiries would produce, might we i)ot establish the theory of one of the most important opera- . tions of pharmacy, and the relations which its results must have with the alkaline soaps ? Such are the considerations which led me to the follow- mg experiments : I placed in a tubulated bell glass equal parts of olive oil,- litharge, and water: I adapted to the orifice of the bell oj^ss a tube inserted into lime water, with a bladder at the orifice to prevent the access of the external air ; this bladder was so disposed that I could move a spatula in the interior of the bell glass, in order to keep the matter from sticking to the bottom of the vessel. The mixture having been brought to the boiling point, I saw the oxide of lead successively pass from red to yellow, and from yellow to white. During the time the experiment lasted carbonic acid was almost always liberated. I allowed the apparatus to cool, in order to exa- U)ine successively the results of this experiment. The water which had served as the intermedium had a strong metallic taste. When placed in contact with yeast at ihe necessary temperature, I was never able to produce fermentation*. It precipitated evidently by the sulphuric acid and the hydrogen-ited sulphurets f. I passed sulphu- retted hydrogen into it, until no more precipitate was formed; and I filtrated it in order to separate the sulphuret of lead. The filtered liquor had also a very strong saccharine taste; it was evaporated to the consistence of a syrup -, the acetate of lead at this moment did not demonstrate the presence of sulphuretted hydrogen. My attempts to ferment it were equally fruitless as before the separation of the oxide of lead ; exposed to the air, it strongly attracts its humidity ; when f \ was for a moment led into an errqr, because I had inadvertently used yeast, which still contained some alcohol, not having been properly washed. •f 1 was convinced by various experiments that it was of no importance whether in tha solution of the oxide of lead the fats or oils were rancid or not, although Scheele thinks they should be rancid. In fact, it v/ill be seen in the course of this paper that this circumstance is completely foreign ro the sqlutioii. \ projected 4 i ' Uf^h the Comlination of the fixed Oils pt'Ojectcd upon live coals, it burns like the oils : on boiling it with the red, yellow, and white oxides of lead, it only dissolves the yellow one : when distilled several times with the nilric acid, it produces in it the formation of the oxalic acid ; when distilled in a retort in the open fire^ a part ascends in distillation, as observed by Schcele : on increising the fire, it gives cmpyreumatic oil as a result, acetic acid, carbonic acid, carbonated hydrogen gas, and a slight spongy charcoal, which does not contain any oxide of lead. From what I have described, it is strongly to be presumed that oil, when combined with the white oxide of lead, is no longer in the same state as it was before this combination. In order to separate it from this oxide J made use of the acetic acid, because the solubility of the acetate of lead af- forded me an easy method of separating it from the oil, the properties of which I was about to examine. This oil has the consistence of fat, having also the same lancid taste : it is insoluble in water, and soluble in alcohol, and Is precipitated by w^ater in the same way as the volatile oils, and like these last is volatilized in part with the oil in distillation*. The slightest ebullition is sufficient for combining it per- fectly with the white oxide of lead, and gives it a strong em- plastic consistence, which does not take place with litharge and massicot. The yellow and white oxides of lead cannot he combined with the common oils ; I ascertained this fact by an ebulli- tion much stronger than if I had employed litharge. It rejjults, therefore, from these experiments, that when we treat the fat oils with litharge, the oxygen of the latter carries off their carbon, and previously their hydrogen, in order to form water and carbonic acid. That this subtraction, rendering oxygen more abundaat in the oils, gives rise to that saccharine s'.ibstance which Schecle calls the sweet volatile principle of oils. That this sweet principle differs from the mucoso-saccha- * All tlie fat oils are dissolved in alcohol ; those, however, which have been treaty with litharge are much more s,tropgly characterized with this propejty. fine with the Oxides t)f Lead and the Alkalis, 4 J rine by the property it possesses of dissolving the yellow- oxide of lead 5 that its saccharine taste is independent of the presence of the oxide ; that it differs from sugar by its vo- la«Hty, and by the impossibility to ferment it. That oil deprived of the principles which have given rise to the sweet principle, and of the quantity of hydrogen and carbon which constitutes it a fixed oil, acquires several of the properties of the volatile oils. Finally, that this last state of oil is the only one which can be combined with the white oxide of lead. ' From the knowledge I have acquired of the theory'of this combination of the oils, I did not think it right to neglect to ascertain to what extent the opinion of several chemists is founded, who consider the plasters as true metallic soap€. The analogy between the plasters and the soaps can only h^ verified by observing in their respective combinations a re- semblance in the phaenomena, or at least in the results. I mixed some pure soap-makers' ley with olive oil ; I ex- posed this mixture to the air under a bell glass. Eight days afterwards there was only a slight absorption -, the soap had still a strong alkaline taste, and the oil of this soap was not entirely dissolved in alcohol: but at the end of six weeks the absorption of the oxygen was complete; the soap was very white, of a good consistenc:e ; the alkaline taste was but feeble; diluted sulphuric acid liberated carbonic acid frouri it ; the oil proceeding from this decomposition had the same consistency with that from the plasters, was dissolved cold in alcohol with the greatest facility, and was precipitated from it by water. I made soap in the same way as the soap-makers j I exa- mined with the greatest care the liquor remaining afier the operation was finished, but I could discover no trace of sweet principle. As the absence of this principle in the alkaline soap-ma- ; king probably depends only upon a greater or less subtrac- ; tion of carbon or hydrogen, and the action of oxygca wpon oil, and the state of the oil, are ^baoluiely the same ia - the making of.plafit,ers as ia soap-making, 1 thiuk the plas- ters 46 Description of the Mountain Barometer *. tcrs should be considered relatively to tlic soaps as the inso- luble metallic salts are relative to the alkaline salts. I am convinced that the defect in the consistency of the soaps of potash by no means depends upon the state of the oil, but rather upon the kind of combination ; for I never obtained any thing but a soft soap on treating by potash some oil proceeding from a very dry soap of soda. Xf. Description of the Mountain Barometer , invented ly Sir Henkt C. Englefield, Bart, F,R,S, and made hy Mr, Thomas Jones, of Mount Street, Berkley Square, To Mr, TillocL X HE various advantages which are likely to be derived from taking altitudes of every description, in a short time, with very little trouble, and at a small expense, gives me every reason to suppose the curious and enlightened mind will be pleased with a description of a new portable moun- tain barometer, contrived, and most peculiarly adapted, for that useful purpose, by a gentleman well known in the phi- losophical world. Its great simplicity in use, as well as portability, renders it superior to any barometer yet made. The celebrated experiment devised by Pascal (says the French National Institute, in their Transactions of 1S05,) and which proved, that a column of mercury decreased in proportion as the barometer was carried to a greater height, after having proved the gravity 6f the air, must have made the mercury be considered as a scale capable of measuring the height to which it is carried. But this scale being very small, in comparison of the heights which it ought to mea- sure, it was soon perceived, that it would be necessary to improve the construction of the barometer, so far as to render sensible and appreciable the smallest changes in the heiirht of the mercurv. The ncccssit v of avoiding: or of cal- culating the continued variations which the barometer ex- periences, even without changing its place, presented an- other obstacle, much more formidable, and which seemed . to Description of the Mountain Barometer. 47 to take away all hope of approaching the truth, or coming near it : these difficulties, however, philosophers have been able to surmount; so that barometric measures, properly employed, may vie in exactness with the trigonometrical measures, to which they are superior, on account of their facility and generality of the method. On this subject it is not necessary that I should add any- thing further, the inventor of the instrument, of which a drawing is herewith sent, having satisfactorily and correctly detailed every thing connected with it, in the paper, of which, by his desire, I send you a copy subjoined. The paper alluded to appeared in a respectable periodical work * nearly two years ago, but it has since been revised and received some considerable improvements from the au- thor, which renders its republication desirable. I flatter myself, that the section which I have likewise sent, of the principal and most essential improvement, will not be unacceptable to the gentleman, nor the person who may wish to make such an instrument, a, a, a, a, (Plate I) represents the cistern, made of box -wood ; — c, c, c, the cover, made of brass, which screws on, and is prevented from being unscrewed (by idle curiosity,) by four small screws, t. — e e represents the stem of the cistern, into which the glass tube, n w, is firmly glued ;-— R R represents the ma- hogany tube, in which is inserted the stem of the cistern, where it is secured by the screws, t t, passing into it. I am^ sir, your very humble servant, Thomas Jones. An expeditious Method of determining Altiitides, of every Denomination, ivith a new portable Mountain Barometer ; with a Description of the Instrument, The mensuration of heights by the barometer has been, by the labours of M. Dc Luc, sir George Shuckburgh, general Roy, and several other scientific men, brought to such perfection, and affords so much an easier mode of as- certaining the elevations of the different parts of the surface * Nicholson*s Journal. of 4s Description of the Mounialn Barometer* of the earth, to a considerable precision, than any other known process, that it might have been supposed that, in the course of thirty years, which have elapsed since this branch of science has been perfected, a very great number of observations would have been made, and the heights of almost the whole surface of our own country ascertained by the numerous travellers who continually traverse it. The contrary is however the case; and the small number of ob- servations of this kind may be attributed to several causes. The instruments are of considerable expense, and, from their complicated construction, easily liable to be out of order in the course of a long journey. The observ^atifens themselves, though each not taking up any very long time, yet, when multiplied on every hill and valley, as they ought to be, for the purpose of obtaining a just idea of the face of the country surveyed, in the aggre- gate consume much of the traveller's time; and the consvtant unpacking and re-packing the instrument, becomes a greater labour than our natural indolence easily submits to. It has moreover been generally supposed, that two instru* ments and two observers making simultaneous observations at the upper and lower stations of the height to be measured, are indispensably necessary. This, of course, would put it out of the power of a solitary traveller to make any obser-5^ v^tions at all. Whether from these, or other causes, the fact is, that whoever reads the numerous Tours, Surveys, and Reports of the different parts of our island, published within these last twenty years, and many of them professedly with a view to science, either of agriculture, mineralogy, or geology, will be perpetually disappointed, by meeting with mere guesses at the elevations of the tracts of country described : though a knowledge of those elevations is almost indispen- sable to the geologist, mineralogist, and military surveyor; , highly iiseful to the scientific agrictdtiirist, and very inter- esting to every one, who, from mere motives of enlarged and enlightened curiosity, rends books of travels, or cm- ploys his own leisure in traversing the countries described by other voyagers. I cannot. Description of the Moujil am Barometer, 40 I cannot, therefore, but hope, by simplifying the baro- meter, and thereby rendering the instrument much less ex- pensive, and its u?e at the same time more easy, and show- ing that very considerable accuracy n)ay be attained by a single observer, this most useful branch of science may be cultivated, to so great an extent, that, in the course of a few years, we may have almost as perfect an idea of the re- lative heights CrF the dilfercnt j)arts of IJngland, as we now have of their horizontal di/tance. A barometer, nearly similar to that which I am now about to describe, was constructed, several years since, by Dr. Hugh Hamilton, and is by him dcseribed at large in the fifth volume of the Transactions of the Irish Academy. I saw the instrument, in his hands, nearly seventeen years ago, and was much pleased with its performance. I do not know, however, that any more were then made. I have lately coustructcd the barometer, whose description I shall now give, which is still more simple than Dr. Hamilton's, and much cheaper, and which, in many trials I have made of it, appears tO' unite solidity, lightness, and ease of ob- servation, to as great a degree as can be wished. The barometer lube is about 33 j inches in length ; its bore is a teaih of an inch in diameter, and its external di- ameter is three-tenths of an ir.ch. This sized bore is fullv suflicient to allow the free motion of the mercury*. Tlie \Mstern is of box-wood, turned truly cylindrical, 'aiid is one inch in its external diameter, and an inch in depth; a short stem projects from its lop (the instrument being in a posi- tion for making an observation), for the purpose of giving a firmer hold to the tube : this stem is perforated \yiih a hole sufficiently large to admit the tube, which is glued to it in the usual mode. The ttibe projects into the cistern i * Several barometers haveliecn lately constructed by Mr. Jones, with the lower part of tlic tube only a iwe.itietfi of ;ui incti in bore, something on tlie principle of the marine barometers. This alteration was made because ia some few instances when very carelessly used, air had {^ot into the tube. In the form now adopted, this defect seems compk-tely remedied, and the mo- tion of the mercury, thonj^h full free enough for accuracy, »<> rendered so equable, that observations in a carnage are much easier. 1 therefore, on the ■ wliolc, prefer this construction. Vol. so; No. 117. Feb, 1608. D exactly 50 Description of the Mountain Barometer, exactly^p half its depth. The bottom of the cistern is closed by a strong lid of box, which screws on the cistern, and, pressing against a leather glued to the inside of the lid, ren- ders the whole perfectly impervious to the mercury in every position. The tube being filled and boiled in the common way, and the instrument held inverted in a perpendicular position, mercury is poured into the cistern till it is filled within two-tenths of an inch of the top. The lid is then firmly screwed on, and secured from being opened, (by idle curiosity,) by a small screw passing through its side. The essential part of the instrument is now finished. The end of the tube, in the cistern, can never be uncovered by the mercury in any possible position, and, of course, no *air can ever enter into it; and, as the areas of the cistern and tube are as the square of the diameters, the diameter of the bore of the tube being -1, its external diameter -3, and the di- ameter of the cistern I'O, the area of the cistern is 100 — 9 91, and there beins; two-tenths of an inch left empty in the cis- tern, the mercury must fall ISS-tenths, or 18 inches and two-tenths, before the cistern is quite full ; a space adequate to the measure of greater heights than any known mountain on the earth, much more to that of any height in this coun- try. It- will not easily be believed, by those who have not seen it, that the air will act on a cistern thus completely closed,- and of which the wood, in its thinnest part, is above a quarter of an inch in thickness ; but the fact is, that even wlien the pores of the box wood are closed by thick varnish (except in that part which touches the mahogany tube,) in order to-prevent the wood from being affected by damp, the mercury, on turning up the barometer, takes its level almost instantaneously, certainly in less than haU" a minute; and that, when the instrument is suspended by the side of the best mountain barometer, ofKamsucn's construction, with an open cistern, no difference whatever can be perceived in theirsensibility to the variations of the atmosphere. It is •obvious that the variations of altitude in this instrument, its dimensions being as above stated, will be one ninety-first part less than, in a barometer furnished with an apparaius for bringing the surface of the mercury-.in the cistern to a C\Ktd C ' .. . level: Desci'iptidn of the Moimtain Barometer. 5 i level : this defect might be remedied by dividing the scale ac- cordingly ; but it is much more convenient to divide the scale to real inches, and make the necessary allowance in the result* The tube and cistern being thus prepared, are mounted iil a mahogany tube or frame of the size of a common walking- f?tick. The stem of the cistern goes into the mahogany tube, and is there secured by a piece of brass tube, which fits to the cistern and mahogany frame to which it is screw- ed ; or the stem may be on the outside, cut into a malti screw, and so be screwed into the mahogany tube. The tube is secured in the mahogany case by passing through per- forated corks in the usual way. For the observation of the height of the mercury, two Opposite slits are cut in the mahogany tube, reaching from about 32 to 20 inches for the long scales; /and 32 to 25 inches for the short ones ; which are sufficiently long for any purpose in this country. The front slit has its sides bevelled, and is, exteriorly, about three- fourths of an inch wide 3 on one side is fixed a brass scale, divided as usual to inches, tenths, and twentieths. On this scale a nonius slides, moveable by a small knob, which reads off, as in other barometers^ to 500th of an inch. To this nonius a small portion of brass tube is attached, which embraces the barometer tube, and its ld\ver edge is, in observation, made a tangent to the convex surface of the mercury, as in other well -constructed barometers ; and the very narrow slit behind gives abundant light for observation. On the bevelled side of the front slit, opposite the scale, a thermometer is placed for taking the heat of the instru- tnent ; and there is room for the scale of correction, placed on Ramsden's attached thermometers, as wellas Fahrenheit^ scale. This thermometer is so contrived as to take out of its place, and answers the purpose of the attached and detached thermometer. A thin brass tube, \Vith slits in it, turns half round, on two pins, in the usual manner, and covers the apertures above described in the mahogany tube when the barometer is not in use. The mahogany tube is made rathet tapering, and with a i> 2 ferrule 52 Descr'iption of the Mountain Barometer, ferrule at the end opposite the cistern. This ferrule un- screws^ and shows a steel ring, by which the barometer may be suspended when convenient. Along tlie mahogany tube is a scale of feet, carefully divided to inches ; the feet being accurately laid down by small dots, on the heads of brass pins, sunk into the wood. A scale of this kind is alw.iys convenient, and may often be of great use. To those travellers whose pursuits may lead them to the measures of the higher class of mountains, I would venture to recommend a barometer constructed with a tube of tv/o feet lonaj onlv : so that the whole instrument should not much exceed t!5 inches in length. This barometer would not of course be useful until the mercury fell below 24 inches, which would be at a height of about 6000 feet in the atnxosphere : but its great portability into regions where from both the difficulties of the path, and the rarity of the air breathed, every ounce of incumbrance becomes a serious evil ; and moreover, the great security to the instrument itself arising from its shortness, would, I am persuaded, render it well worth 'while to carry such instruments where great altitudes are to be measured; and it is to be remem- bered that the instrument loses no part of its accuracy when it once comes into action, by being thus shortened. Having thus described the instrument, a few practical remarks on the manner of using it may not be superfluous. When I am about to make an observatfon, about five minutes before I arrive at the place I take out the thermo- meter, holding it by the upper end at nearly arm's length from my body, and, if the sqn shines, xyi the shade of mv person, fi very soon takes the temperature of the air, and Is not sensibly aff"ected by the heat of the hand. The heat being observed and written down, the barometer is luriied up ; the brass tube half turned ; and the instrument held be- t'.veen the finger and thumb of the left hand aboue the slit, so as to let it hang freely in a perpendicular position. Few persons, if any, have sufficient steadiness of hand to pre- vent little vibrations in the mercury in this position : the hand, therefore, should be either rested against any fixed body, Description of the Mountain Barometer: 53 bodv, or, ir no such occurs, by kneeling on one knee. The cistern sliould be let down so as to touch the ground, the left hand holding the barometer in a vertical position, which a little practice will render very easy. The index must then be moved by the knob till its under surface, as before stated, is tangent to the mercury. A few light taps should be given to the tube, to ascertain that the mercury has fallen as low as it can. The height being then read off and registered, together with that of the attached thermometer, tiie brass tube is turned back, so as to cover the slits ; the instrument gently inverted, and the whyle is finished. All this may be done in two minutes. It may not he improper here to add, that I have found by experience that it is not necessary to quit the chaise in order to make observations with this b-trometer; it is only requisite for the horses to stand still. The thermometer, if held at arm's length out of the chaise window, v»-ili give the temperature exactly, before the order is given to slop the carriasfe: and the delav to the traveller will not much ex- ceed a minute, as the observation may be read off and writ- ten down while the carriage is again going on. The most convenient mode for deducino; the heiizhts from the barometrical observations is, certainly, by the common logarithmic tables ; and it is unnecessary here to detail tlie method, wliieh may be found in nunjcrous hooks. It is, however, necessary for this method to carry the tables of lo- garithms, which is sometimes inconvenient. Tlie engraved table formed by Mr. Ramsden is on a single narrow sheet, and extremely portable, besides being very easy in its use; but it may be lost or mislaid when wanted. Several inge- nious formulce have been devised, which 'niciy either be en- graven on the instrument itself, or committed to memory. Of the former, sir Georgx; Shuekburgh has given a very con- cise one, in his second paper on the measurement of heights by the barometer, in the (3Sth volume of the Philosophical Transactions ; and Mr. Professor Leslie has invented a very elegant one of the latter sort ; but these, though very simple in form, require a considerable number of figures in the ope- ration, and are, on that account, inconvenient. For the D 3 purpose. 54 Description of the Mountain Barometer^ purpose, therefore, of computing on the spot, and very near to the truth, any observations made on a journey, and that, almost without the necessity of writing at all, I have caused the following short table to be engraven on the scale of the barometer. It expresses the value of the difference of the tenth of an inch in the height of the mercury at the tempe- rature of freezing, in English feet. Feet. Q2 ' 91 90 89 SB S7 86 85 84 83 82 81 The method of using it is as follows : — 1st, Add the two observed heights of the barometer, and halve the sum to obtain the mean height. 2d, Subtract the lesser height from the greater, the remainder is of course the difference of height in tenths, &c. of an inch. 3d, Enter the table with the mean height, and take out the feet answering to it, making a proportion, if the mean heiglu does not exactly answer to a foot. (This proportion may be made bv head.) Multiply the number thus obtained by the tenths. Sec. of an inch of difference of height. The result will be nearly the nunibcr of feet, answering to the difference of height be- tween the two barometers at the temperature of freezing. When the lower barometer stands between 29 and 30 inches, and the elevation docs not exceed 1500 feet, this rule will give the height wiihin one foot of the result from the loga^ rithniic method. When the elevation is about 3000 feet, the error will be nearly three feet, and at heights greater than 2000 feet, the error increases in a higher ratio. It is ^Iwavs in defect. In this country, however, such eleyations do Inches. Feet. Inches. Feet. Inches. Feet. 1 Inches. 20-05 130 22-25 117 25-05 104 28-35 '20 129 -45 116 •30 103 j 'Q5 •35 128 •65 115 '55 102 •93 •50 127 •85 114 •80 101 29-27 •66 126 23-05 113 26-05 100 •61 •82 125 •?5 112 •30 99 1 -95 21-00 124 •45 111 '57 98 30-30 •18 123 •65 no •85 97 ! •65 •35 122 •87 109 27-15 QQ ! 31 '00 •53 121 24-10 108 •45 95 '37 •70 120 -32 107 •75 94 •75 •87 119 ^55 106 28-05 93 32-10 ?2-05 lis •sp 105 Description of the Mount am ^arimeier . i;^ do not exist ; and in., those parts where a knowledge of the comparative heights of the difterent hills is the most gene- rally useful, they seldom exceed 1000 feet ; at all events, such observations as relate to great elevations may be alvyjLye recomputed. by more rigorous methods at leisure. The correction of the heights thus obtained, for the tepi- perature,of,.th9 air above freezing, is by sir George Shuck- burgh SLipposed to be as the height of the thermometer, and to be 2-44 thousandth of the approximate height for each degree of Fahrenheit, additive when the temperature is above freezing, and subtractive when below freezing. General Roy's, observations and experiments lead to a supposition tl^>t|.^h9;icp;:Tection is not exactly as the height of the ther- mometer, and that at about the temperature of 50 degrees it amounts to 2*3 — thousandths, and is less, both much above and much below that temperature. For the purpose of immediate computation, I take the correction at 2*5,- which, though certainly rather too great, will in general be productive of very small error, and affords a rule which is easily remembered and quickly applied. It is this ; For every four degrees that the mean temperature of the two detached thermometers exceeds 32 degrees, add one hundredth of the approximate height, as before obtained, to it ; for every 40 degrees one tenth, and so for any greater or lesser number of degrees. * , I have not hitherto mentioned the correction, which i-n fact ought to be the first in order, viz. that i'or the differ- ence of temperature of the- t^vo baromelers themselves : but this cbfrection is in general so small, ^s"' to be safely neg- lected. Should it, howev^er, be thought necessary to apply it in this approximate method of coniputing heights, the rule deduced^ from sir George Shuckbui^gh's mtfthod'^r'^^ate follows, and it wants no'-t4ble, thou^^h be "h^^ gl'i^eti^'8& ^•qj. j^^ \ ■ /HfiMiO'' . U id tk:v'. li^*' ■ ■'■ •■ ■. 3 ''When the barometer slihds at 2i[> inche^'^ tfier expansrdh of the mercury for one degree of Fahrenheit is two-thou- sandth of aTi inch, when it stands at 30 inches it is three- thousandths, and for the intermediate inches it increases (f^- D 4 actly 56 Description of the Mountain Barometer, actly as the height of the mercury; that is, at 21 inchc? it is 'OOiJl, at 22 inches '00^2, and so on; so that the height in inches is the number of ttni thousanchhs oF expansion for one degree of Fahrenheit. This is very easily remembered. The expansion for any other number of degrees is in propor- tion to the degrees themselves ; that is, for two degrees it is twice as much, for ten degrees ten times as much, and so on. Take therefore the difference oF height of the attached thennomelers at the two stations, and multiply the expan- sion for one degree at the coldest barometer (which will al- most always be the one at the highest station) by the num- ber of degrees of difference between the heal of the two ba- rometers, and add the quantity to the observed height of the coldest barometer, and it is corrected for the expansion of the mcrcuj-y by the heat of the instrument. An example will make the whole clear. Inche-'!. Therm, attached. Observation at bottom 29*400 - 50^ Observation at top - 25*190 - AG Difference 4 Expansion for 1® at 25 inches - '0025 Multiply by difference - - 4 •0100 One hundredth of an inch is therefore to be added to the observed height of the upper barometer 25*190, so the cor- rected height is 25*200. It is, however_, to be observed, that the application of this correction is of doubtful accuracv in practice; as it is by no means certain that the attached ther- mometer, be it placed where it may in the mounting, will give the real heat of the column of mercury in the barome- ter, and therefore I had at first paid that it niight on the whole, in general practice, be neglected. If much accuracy •is wished, and time permits, the surest way is*to leave the barometer in the shade so long as for the whole inslrumeut to Description of the Mountain Barometer. 57 to acquire the temperature of the air, and then to make this correction according to the rule given above, from the dif- ference of the two detached ther77iomctcrs ; and this baro- meter, from the lightness of its mounting, will have the advantage of taking the temperature oF the air sooner than those formerly made with solid wooden cases. It may not be improper to give an example of the method already detailed. Observation at bottom 29*400 Therm, in air 45 . at top - 25.200 Therm, in air 41 2 I 54-600 2 I SQ Mea^ - 27*300 Mean heat - 43 Standard - 32 Difference - 42 tenths — Value of a tenth by the table 95*5 feet. Difference J 1 1910 3820 Approximate height - 4011-0 feet Do. by sir G. Shuckburgh 401 6-0 Error - 5 feet Correction for Temperature. For 8° = 2 hundredths - - 80 feet For 3** = 3 four hundredths - 30 Correction -f 110 Ditto by sir G. Shuckburgh - 107*4 ^ Error -j- 2-6 Approximate height by me 4011 By Sir G. $. 4016 Correction for temperature 110 107*4 Result - 4121 4123-4 Example 58 Description of the Mounlain Barometer, Example second. Observation at bcttbm 30*017 Thertn. M'dif" 60** ., at top - 29 334 Therm, m air 37 2 I 59-331 Mean - 29*773 Difference 4*83 Value of a tenth by • the table } . ^^*' 330*0 70-00 2-623 Approximate height - ^422*623 Ditto by G. Shuckbiirgh ~422*9 2 1 JI7 ' Mean - - 38*5 Standard - 32 DiiFerence - 26*5 , Error 00 3 2 = Correction for. Temperaiure. For 24° = 6 hundredths - - 2 four hundredths - 1* eight hundredth - Correction + Ditto by sir G, S. Error i!];^: 23*3 2*0 0-3 27*8 27-2 0*6 Approximate height by nje 422-6 Correction for temperature + 27-8 By sir G. S. 422*9 27*2 430-4 430-1 These two examples show how near the truth tlie method here recommended will come, even in considerable heights.; It has- been already observed, that in observations made with the barometer I have described, a small correction is necessary on account of the rise of the mercury in the cis- (ern^ as the barometer falls. Altitudes being in all cases measured Description of the Mountain Barometer. 5^ measured by the differences of the heights of the mercury at the two stations, and these differences being evidently al- ways too small in this barometer, the correction is obviously always additive. As in constructing different barometers, the interior and exterior diameters of the tube will not al- ways be exactly similar, though the cisterns may be turned always alike ; this error, and of course the correction for it^ should be in each instrument deduced from a comparison with a barometer of known accuracy at different heights, . It will probably vary in different instruments from a nine- tieth to a seventieth. Indeed, if it were always taken at an eightieth, in instruments constructed as above directed, the possible error could only amount to about one foot on a thousand ; a quantity of very little importance. It now remains to say a few words o« the necessity of two barometers for the mensuration of heights, and the pro- bable error to be incurred by using a single one. There is no doubt, that when very great accuracy is required, two barometers ought to be used ; but even with every precau- tion, altitudes cannot be taken by barometers sufficiently near for the purpose of carrying water, either by pipes or canals ; and for the purpose of the geologist, military sur- veyor, or agriculturist, it is of very little importance whe- ther a mountain is 1000 or 1010 feet high, though it is of the highest utility that he should know whether it is 800 or 1000. I have, during the course oF many years, been in the hai)it of taking observations of altitudes by a single ba- rometer, and have had many opportunities of repeating my observations on the same hills when the barometer has been at different heights, and either falling or rising during the time of observation ; and more than once I have observed heights which had been trigonometrical ly taken by the best instruments; and I can safely say that the difference be- tween these observations has seldom amounicd to so much as two feet on a hundred. The mode I use is this : — At setting out, I take the height of the mercury, and note the iinie of observation ; \ likewise note the time of the second observation, and on returning to the first station, observe again, 3 Co Description of the Mounta'm Barometer. again, and note the time. IF the baromelcr has altered in the interval, a simple proportion eoirects cither oi" the three observations, and reduces the height to what would have (>ccn observed had the nicrenry been stationary. . It is true that this method supposes the motion of the mercury to have been uniform during the interval of observation ; but except in very variable weather, wliich does not often occur, par- ticularly in summer, when the greater numl)er of these ob- servations will naturally be made, this supposition is liable to but small error. It is also true, that a traveller has often jio opportunity of making a second observation at the spot he sets out from. Even in this case, a near ap[)roximatiou ^nay oflen be made by observing, for example, at a stream on eueh side of the hill to be measured. Jf also he observes the barometer repeatedly in the morning before he sets out, and sets its tendency, and does the same at every halt, during the day, he will have data whereon to found a nearly accu- rate correction. But if all tliis should be out of his power, even under the most unfavourable circumstances, barome- trical obi«crvations will give a much more accurate idea of the outline of a country than any we now ptjssess; and it should be ever remembered, that observations though defec- tive, if carefully made, and faithfully recorded, are valua!)le, and if repeated by diflerent travellers the errors vvill, in most cases, compensate each other, and from the whole very ac- curate conclusions may be drawn. I have entered into a greater detail than would be neces- sary for a greater part of your readers, in the liope of being intelligible to those who are less acquainted wiih the sub- ject, and who may wish to employ any instrument-maker for the construction of barometers sinular to that which I have described. Injustice to a very ingenious young artist, permit me.to add, that I h:i,ve employed in making those which 1 have, Mr. Thomas Jones, of No. li?4, Mount-street, Berktlcy- fcqnare (pupil of the late Mr. Kamsden), and who makes them complete at the price of three iz;uineas and a half, wiih ^ short scale reading from 25 to 31 inches 3 and four gui- ' 'i neas Description of the Mountain Barometer, 61 ncas for those with a long iscale reading from 20 to 31 inches. I am, sir, your humble servant, H. C. Englefield. P. S. On comparing several havoiiieters made by Mr. Thomas Jones, since this description was .first written, I find that in some of them ihc mercury does not take its true height on turning up the instrument, quite so quick as in the two which he first constructed for me. This difference is owing; to the greater closeness of fibre in some pieces of box wood than in others, but it does not affect the accuracy of the in- strument. In order to give a quicker action to these baro- meters I advised Mr. Jones to bore a small hole or two in these cisterns, and insert a j)in of open grained wood into them. This answered perfectly well; but a curious circum- stance occurred : when deal or willow wood pins were in- serted, the mercury, when shaken for some time, passed through the pores of these woods in the form of a fine black powder, and it was necessary to substitule ashen pins to confine it in the cistern. It may not be superfluous to say, ihcit the weight of this barom(;ter is less than a pound and a half. The weight of Ramsden's last improved barometer ' is 44" pounds, and that of his earliest about G';- pounds. [ subjoin a few observations by which the accuracy of this barometer may be fairly estimated. On R'lclnnond HilL iSOfT. Barom. T.herm. Results. Jan. 1, Hill top - - 29'540 44 Thames* side 2i)-68G Feet. - 133 134 * •14G - > Jan. 2, IliUtop - - 29-708 38 Thames' side 29-8f)0 •152 - - Jan. 31, Hill top - - 29-301 36 Than^es' side 29*453 37 'i5i - ... 137 Feb, 62 On the Means of gaining Power in Mechanics. Barom. Therm. Results. Feb* 23, Hill top - - * - - 29*758 51 Thames* side - - - 29*912 Feet. •154 139* Feb. 24, Hill top - - - - -« 30*180 53 Thames* side - - - 30-334 54 • 154 - - . . HO On the Signal Hill at Bright helmsf on* In 1796 with a barometer of Ramsden*s. Signal House above High water mark - • 4 Id In 1806, with my barometer ^ * - - - 403 416 418 Devil's Dyke, near Brigkfhehnston, In 17S85 with a barometer of Ramsden's - -^ 697 In I8O6, with my barometer ----- 695 Lord Ahercorn*s Lodge, at Staimiore, above the Strearft in Ed g ware Town, Feet. Jan. 3, ----- 306 Jan. 7, - - - ^ - 306 The observations from which this height was deducec^^ were made in the chaise, both on Jan. 3 and 7. XII. On E. V.'s Article '^ On the Means of gaining Power in Mechanics^* To Mr, Tilloch, sin, J\ coRRESPONDENNT asserts in your Magazine for last month*, that he has a machine with which, by the appli- cation of 2lb. descending through three h^it, he raises 20lb* through two feet. He wishes to have some person's opi- nion of it through the same medium. You possibly may * Phil. Mag. Vv>l.ixlx. p. 351. have On the Means of gaining Tower in Mechanics, 63 have many ; and on so extraordinary an assertion, I could not forbear giving mine. As the gentleman has neither given a description nor drawing of his machine, it is impossible to give any other opinion of it than a general one, and that must be against it: for it is not very likely that the gentleman should haVe discovered any latent property in the mechanical powers; ^ince they have been tried in so many different ways and forms, and by so many ingenious persons, that, had there been such latent power, surely some of them would have discovered it. But they have hitherto found, that these powers act according to certain Immutable laws, beyond which, not one jot can they be forced. The mechanical powers, by a little consideration, may all be reduced to the effect of a lever, or a combination of levers ; and I can, with safety, affirm that the lever possesses no such powder as that which he attributes to his machine. . I should limit this last expression a little, for I do not attempt to deny what he so positively asserts, but this I can with equal confidence assert ; that though his machine may perform as above related, it is impossible that it should con- tinue to do so ; that is, ihat it should continue to produce a rotary motion, with that power with which it set out. It must sooner or later come to a state of rest, and will then require as much external power to restore the machine to its former state, as it had apparently gained power beyond the laws of mechanics, by its first eflbrt. Then where ,is^. the advantage of the machine ? If the geiulemaii would be so obliging as to favour us with a -drawing and description of his machine, we may judge of the fact much better ; and if it convinces the world of its great power, and overturns my argument, it will very much improve my knowledge in mechanics, and I shall •yery gladly subscribe myself his much obliged humble servant, T. SWANWICK. Commercial Acr.dcmy, Derby, February 17, 180S. :KIII. Ea- C 61 ] Xin. Exfract of a Memoir upon the Products which result from the Action of the Metatllc Muriates, the Ory-mn- riatic Jgid, and the. Acetic Acid, upon AlcohoL By M. Thknakd*. ^Vl. TiiKNAiiD demonstrates in this memoir, that the me- tallic muriates form with alcohol only a very small quantity of ether J that this ether, which is at first dissolved in a great quantity of alcohol, may be separated from it by a gentle heat in the form of gas, jiarticularly by means of warm water, which seizes upon the alcoholic part, and puts the ethcratcd part at liberty to a certain point ; that this ethereatcd gas has a very great analogy to that obtained with the muriatic acid and alcohol ; that in both cases it has the same smell and taste, the same solubility in water, the same maimer of burning with a green tlame diffusing vapours of the muriatic acid, although before the combustion no re- agent indicated the presence of the gases ; in short, that they only differ from each other bv the etherated muriatic gas not liquefying, except at a heat of 12*5 of the centigrade thermometer, while the other becomes liquid at + )G*5. This difference being very slight, M. Thenard thinks we can no longer hesitate to acknowledge the nature and mode of formation to be the same in both : thus in the metallic muri* ntes, it is only the excess of acid which aces upon the alcohol, Sec. that for this reason alcohol cannot be converted into ether except by a great quantity of metallic muriate, and that this cor. version is the easier, the greater excess of acid the mu- riate contains, and the more it is soluble in alcohol : the muriate of tin therefore will succeed better in this operation than anv other. In all cases the oxide of the muriate is not de-oxid.ited, and a portion only of this oxide is precipitated. IVoceedine to consider the Action of the oxy-muriatic acid upon alcohol, he shows that in the re-action of these two bodies upon each other, v/hich is very brisk, almost all the oxy-muriatic acid is decon^posed, and that much water is produced, plenty of nmriatic acid, undecomposed akoho). * From ylnn. de Ckimic, tom. ixi. p. 308* a great Action of t lie Metallic Muriates, ' &c, upon Alcohol, 'G5 a great quantity of oily matter thicker than water, having a cool taste ftke mint, and a peculiar smell completely diffe- rent from that of ether : further, a small quantity of car- bonic acid, a matter easily charred, and prohably acetous acid, but no ether : — ^that the oxy-muriatic ether of Scheele is merely muriatic ether properly so called, when made of a mixture of alcohol, muriatic acid, and black oxide of manganese; or of muriatic ether and sulphuric ether, when made with the black oxfde of manganese, sea -salt, alcohol, and sulphuric acid : — that Pelletier's is also of this nature, since he made it by using the foregoing mixture ; and that the oxy-muriatic ether said to be obtained by passing the oxy-muriatic acid through alcohol, is nothing else than a solution in alcohol of a greater or less quantity of oily mat- ter. We may even separate the oil from the latter by means of water, and we re-form it all at once by dissolving this oil in a determinate quantity of alcohol. The novelty in this part of the author's labours does not consist in this formation of oily matter, water, acetous acid, &c. ; for Scheeic, in his Memoires de Chimie, speaks of the oily matter ; and M. Berthollet, in the Memoires de I'Academie for 1783, speaks of this matter, and besides of water, acetous acid, &c., as produced in this operation* M. Thenard's claim to novelty consists in his having proved* that the oxy-muriatic acid could not with alcohol form ether; and he has explained why Scheele and so many other chemists happened to obtain it. In the last place, being anxious to examine the formation of the acetic ether, M. Thenard mixed together 120 gram- mes of highly concentrated alcohol, and 120 parts of acetic acid, of an acidity determined by the quantity of pot- ash required by this acid for its saturation; he distilled this mixture, cohobated it twelve times, and thus sensibly de- composed the whole of the alcohol employed, and 66' \Q grammes of acetic acid, representing 32 grammes of dry * M. Berthollet, in the Memoires de VAcadcmie for 1785, has even an* nounced that the muriatic acid and alcohol produce but very little ether ; and we may perceive that he is inclined to regard this small q^uantity of ether -as foreign to the re-action of these two bodies. Vol. 30. No. 117. Fel, 1808. E acid, €6 On a peculiar Property in Camphorated IVdter, acid, or as it exists in the acetite of potash well melted. About 1 20 grammes only of acetic ether were formed, how- ever, although no gas was liberated ; and the operation when, terminated presented a loss of seveii grammes only : from this M. Thenafd is led to think that a portion of the oxygen of the acetic acid is combined with a portion of the hydro- gen of the alcohol, while the other principles of the acid and those of the alcohol unite to constitute ether. Otherwise, if no water w.^s formed, it would be necessary, in order to ac- <;ount for this operation, to admit that the best rectified al- cohol contains nearly one-fifth of its weight of water, which is scarcely probable. This ether has a pleasant smell of ether and acetic acid, and yet it neither reddens turnsole tincture nor turnsole paper; it has a taste peculiar to itself, and very different from that of alcohol. Neither its specific gravity nor its tenuity, has been as yet exactly taken ; all we know is, that it is lighter than water, as it floats above it, and more turbid than alcohol. Water seems to dissolve more of it than of the sulphuric ether. It burns with a yel- lowish white flame, producing an acid, which is probably the acetic. FinaUy, in a sealed flask, it does not seem to alter upon standing for a length of time ; at least M. Thenard had a six months experience on this point, XIV. Upon a peculiar Vroperty in Camphorated Water. By M. Cadet*. JL HREE years ago a surgeon in Madrid announced that the carbonic acid favoured the solution of camphor in water, and that the water had very remarkable medicinal properties In diseases of the bladder. Leaving it to physicians to judge of this matter, I was merely desirous of ascertaining the chemical fact. I made a solution of camphor in distilled water, and another in water saturated with carbonic acid by Mr. Paul's method, in order to estimate the quantity of camphor dissolved. I weighed the camphor before and after the solution, and I found that the distilled water had ab- sorbed 1 6 grains of it per pint, and the carbonic acid only * 'StomAmtt'di Chimict torn, Ixil. p. 132, ' ' 15 grains. On the Coviet of \SOf\ 6f 15 grains* As I had been obliged to filter the liquors and to dry the filters, I thought that the camphor not dissolved must have lost its weight by evaporation, and that the ba-* lance did not give me the just quantity absorbed by the water ; I therefore sought for a reagent, which evinced to me the presence of camphor in the water. -.» I found that potash precipitated the camphorated wat«r^ while soda or ammonia did not affect it; i^ut the potash must be pure and caustic. If it contains carbonic acid, it docs not precipitate the can^phor ; and if after having pr^* 4ipitated it we expose the vessel to the air, the liquor absorb* ing carbonic acid resumes its transparency. w/vi ::d Here, therefore, is a new method of distinguishing^jjbt- ash from soda. Camphorated water is in this respect A more certain reagent than the nitro-muriate of platina, and more easily procured. But the metallic salt is more con- venient, as it precipitates the carbonate of potash. On trymg by caustic potash camphorated water charged 1^'ith carbonic acid, I obtained no precipitate, except by put- litig in a great excess of alkali : this precipitate did not seem to be greater than tliat obtained in distilled water. I think| therefore, . that carbonic acid does not sensibly favour the Solution of camphor in water ; but it at least results from these experiments, that the water does not merely charge itself with the aroma of the camphor, as some chemists think, and that this concrete volatile oil is dissolved in a proportion lufficient for the purposes to which it is applied. When the camphor is reduced very small by trituration with some drops of alcohol, water takes up more of it than 1 6 grains fet pint, and some chemists have dissolved even 30 grains. XV. Letter from Gavin Lowe, E^q., on the Comet of 1807. To Mr, TilhcL JL HE comet that made its appearance about the latter 6nd of last September, and continued visible during the thretf Succeeding months, has no doubt been carefully and ^issi- duously observed by the astronomers, not only ia this coim- K 2 ^ uy. ^8 ^ On the Comet of 1 807. try, but by many others in different parts of the world ; aa that the elements of its orbit will be ascertained with great precision. I had an opportunity of observing it fourteen times be- tween the 4th of October and the 12th of November, but none afterwards. The right ascensions and declinations were corrected for refraction, and from them the geocentric longi- tudes and latitudes were deduced. With these data I eoia- puted the elements of the orbit according to the rules laid down in sir Henry Englefield's excellent Treatise upon Co- mets, and hope that, though not quite accurate, they will not be found to err much. The drawing (see Fig.) represents the comet's orbit simply applied to, but not projected on the plane of the ecliptic. The outer circle t> 25,=^, "l^, is drawn at pleasure with any radius. — A B C D is the earth's, and E V F part of the comet's orbit : X S V its axis : © gj the line of nodes ; V the perihelion point, and S V the perihelion distance. The elements of the orbit are nearly as follows : The perihelion distance = 0-64802; the distance of the earth from the sun S A or S B being = 1*00000. The time of the comet's passing the perihelion at V wa^ September 1 8th, 22 hours 10 minutes M. T. The longitude of V on the orbit was 28° 4l' in Scospio. The longitude of the ascending node 26° 3(5' in Sagit- tarius. The comet passed the ascending node September 29th, 18*^48'". The longitude of the axis S X as seen from the sun,, was in 13° 11' af Gemini; and its elevation or north latitude 24° 43'. — The inclination of the orbit 63° 15': — this is easily conceived, by supposing the visible part of the orbit from n to F to revolve upon the line of nodes gj n till any point in the orbit, as F, is elevated 63^-° above the plane of the ecliptic. The comet was seen here soon after it passed V; the earth at that time was nearly at A, moving from thence towards B ; while at the same time the comet moved from V towards F ; and consequently its motion was direct. On the Comet of 1807. ^9 Owing to the oblique position of the axis, it was impos- Tsible to see the comet in the inferior part of its orbit E V, on its approach to the perihelion. I ara, sir, your most obedient servant, Gavin Low«. ,, Islington^ , ^ Feb. 15, 1808. E3 XVI. A [ 70 ] • XVL A Secf.jid Letter from E. V. on the Means of gain'mg Power in Mechanics, g^j^ To Mr, Tilloch, IVlucH as the moderns are reckoned to surpass the antients in nnathematical knowledge, and notwithstanding the ex- perience and improvements in mechanics, during the later and more enhirhtened an;es, it is a mortiFvin':i: truth that we arc even at this day totally ignorant of the means formerly employed, and very extensively in use, to move to vast di- stances, and raise to great height, prodigious masses and weights, such as the celebrated columns of Kgypt, Rome, &c.^ and that with all our advantages over the antients, v^e still remain unable to equal their practice in these respects. It does not appear that our predecessors were gifted with su- perior intellect or strength to the present race -, their means inuit have been mechanical, and therefore must be within our reach. — Why then should we not attempt and expect to do as much as they did ? It is truly surprising that an art of so useful and important a nature, so nearly allied to the me- chanical powers in constant varied use and progressive im- provement among us, has so long been lost and escaped discovery ! Perhaps the time is not distant when this mighty secret shall again be common for the general benefit of so- ciety. My hunible endeavours have occasionally been di- Y rected to this f^nc] ; and vyith this view I have contributed any mite, and ^i;all continue so to do by the communica- f\cjn, through your valuable Magazine, of relative experi- me^its and results which may be novel, in the hope of sti- mul^ing the exertions of the more scientific ; — for, as '' great cv.ent'j oft owe their rise to trivial cause,'* my hints may haply fi;rnish abler heads with ideas which may lead further than I can pretend to penetrate j and thus, between us, the period of success may be accelerated. In my last, I gave account of an engine of my contri- vance, which gained considerable power : — this engine has since been so improved, that with the same moving power, the same velocity, kc, it raises a weigjit of thirty pounds instead On the Use of Sulphur as a Fermifhge, 7i infitead of twenty, and there is consequently reason to be* lieve that it may yet be made far more powerful. Aware of the reception which this extraordinary fact, so contrary to estabhshed opinions, is Hkely to meet, I have aoqght, and been so fortunate as to find, additional support, in further experiments, and the construction of another engine materially different from the first, which, however, produces similar, and indeed greater effects. More of this shall be the subject of my next paper ; and in the mean time, those of your numerous readers, whp' may think with me, that the means of gaining power cannot be limited to the two which I have thus announced, have a wide field opened for the exercise of their genius in this re- search. I have the honour to be, sir, Bracknell, y®"^ Very humble servant, Feb. 23, 1808. E. Y. XVII. On the Use of Sulphtr as a Vermifuge* By Joseph Hume, Esq,, of Long- Acre y London* To Mr. Tilloch. AViNG been favoured with some additional information respecting the efficacy of sulphur, and the proper way of applying it to vegetables, I now fulfil the conditional pro- mise I made in my last letter*. The method is truly sim- ple ; for nothing more is required than to sprinkle sublimed aulphur, or, as it is commonly called, flowers of brimstone, over the leaves of the tree or plant, wherever the effects of worms or insects prevail, or may be expected to come. This may be sq easily accomplished, that it seems super- fluous to point out any particular plan or apparatus. The sulphur may be tied up in a piece of muslin or linen, and with this the leaves and young shoots should be dusted ; or it may be thrown on by means of a common swandown puff, or even a dredging-box. However, if this practice become general, no doubt some convenient instrument, ? Phil. Mag. vol. xxlx. p, 353. E 4 . probably 7ft* Experiments for investigating probably a pair of bellows, constructed on purpose, will be contrived, so as to prevent unnecessary loss of the sulphur. By the same friendly communication 1 have received fresh assurances, not only of the powerful influence of sulphur as a vermifuge against the whole tribe of worms and other in- sects, which infest, and prey upon, vegetables ; but I also find, that in other respects this substance is even congenial to the health of those trees and plants on which it is sprin- kled— that peach-trees in particular were remarkably im- proved by the sulphur ; they absorbed it, and, it may be said, Were even fond of it ; for it was evidently absorbed, and must hive entered into the vegetable system. It was like- wise noticed, that the verdure and other healthful appear- ances were perceptibly increased ; for the quantity of new shoots and leaves formed subsequently to the operation, and having no sulphur on their surfaces, served as a kind of comparative index, and pointed out distinctly the accumu- lation of health. Upon the whole, it may be observed, that, independently of its deleterious effects on the vermin, the question respect- ing these sanative powers of such an insoluble substance as sulphur, seems to be one of the utmost importance ; and, I should think, must be highly interesting to the physiologist, and, indeed, to all men of science. \ remain, sir, your obliged and obedient servant, Long-Acre, Jos. HuME, Feb. 24, 1808. XVIII. Experiments for investigating^ the Cause of the co- loured conctntriQ Rings, discovered bij Sir Isaac Newton, between two Object- glasses laid upon o,ne another. By William Herschel, I^LD, F.R.S.* J. jiE account given by Sir I. Newton, of the coloyred arcs ^cl rings which he discovered by laying two prisms or ob- * From Philosophical Transactions fp.ir i807, Part 11. ject- the Cause of coloured concentric Rings, 73* ject-glasses upon each other, is highly interesting. He very justly remarks, that these phsenomena are " of difficult con- sideration,," but that *' they may conduce to further disco- veries for completing the theory of light, especially as to the constitution of the parts of natural bodies on which their colours or transparency depend*.'* With regard to the explanation of the appearance of these coloured rings, which is given by Sir I. Newton, I must confess that it has never been satisfactory to me. He ac- counts for the production of the rings, by ascribing to the rays of light certain fits of easy reflection and easy trans- mission alternat.ly returning and taking place with each ray at certain stated intervals f. But this, without mentioning particular objections, seems to be an hypothesis which can- not be easily reconciled with the minuteness and extreme velocity of the particles of which these rays^ according to the Newtonian theory, are composed. The great beauty of the coloured rings, and the pleasing appearances arising from the different degrees of pressure of the two surfaces of the glasses against each other when they are formed, and especially the importance of the subject, have often excited my desire of inquiring further into the cause of such interesting phsenomena ; and with a view to examine them properly I obtained, in the year 1792, the two object-glasses of Huygens, in the possession of the Royal Society, one of 122 the other of 1 70 feet focal length, and began a series of experiments with them, which, though many times interrupted by astronomical pursuits, has often been taken up again^ and has lately been carried to a very considerable extent. The conclusions that may be drawn from them, though they may not perfectly account for all the phaenomena of the rings, are yet sufficiently well sup- ported, and of such a nature as to point out several modifi- cations of light that have been totally overlooked, and others that have never been properly discriminated. It will, there- fore, be the aim of this paper to arrange and distinguish the various modifications of . light in a clear and perspicuous * Newton's Optics, i± ed.. p. 16D. f Ih'id. p. 956. order. 7** Experiments for investigating order, and afterwards to give my sentiments upon the cause of the formation of the concentric rings. The avowed in* tricacy of the subject *, however, requires, in the first place, a minute detail of experiments, and afterwards a very gra- dual development of the consequences to be deduced from them. As the word modification will frequently be used, it may not be amiss to say, that when applied to light, it is intend- ed to stand for a general expression of ail the changes that are made in its colours, direction, or motion : thus, by the modification of reflection, light is thrown back ; by that of refraction, it is bent from its former course ; by the modi- fication of dispersion, it is divided into colours, and so of the rest. I. Cff different Methods to make one Set of concentric Rings visible. In the beginning of my experiments I followed the New» Ionian example, and having laid the two object-glasses of Huygens upon one another I soon perceived the concentric rings. It is almost needless to say that I found all the New- tonian observations of these rings completely verified ; but as his experiments seemed to be too much confined for draw- ing general conclusions, I endeavoured to extend them ; and by way of rendering the methods I point out very clear, I have given one easy particular instance of each, with the addition of a generalization of it, as follows : First Method, On a table placed before a window I laid down a slip of glass the sides of which were perfectly plain, parallel, and highly polished. Upon this I laid a double convex lens of 26 inches focal length, aiid found that this arrangement gave me a set of beautiful concentric rings. I viewed them with a double convex eye lens of Sj inches focus mounted upon an adjustable stand, by which simple apparatus I could examine them with great ease ; and as it was not material to my present purpose by what obliquity of incidence of light I saw the rings, I received the rays ♦ Newton'3 Optics, 4th ed, p. 288; endofObs. 12. Irom the Cause of coloured concentric Rings. 75 from the window most conveniently when they fell upon the lens in an angle of a^bout 30 degree^ from the perpeadicu^ jar, the eye being placed on the opposite side at an equal angle of elevation to receive the reflected rays. Gmeralization. Instead of a plain slip of glass, the plain side of a plano-concave, or piano-convex lens of any focal length whatsoever may be used : and when the convex side ofanylensis laid upon it, whatever may be the figure of the other surface, whether plain, concave, .or convex, and whatever may be its focal length, a set of concentric rincrs" will always be obtained. I have seen rings with lenses of all varieties of focus, from 1 70 feet down to one quarter of an inch. Even a common watch-glass laid upon the same plain surface will give them. To ensure success, it is necessary that the glasses shoulxl be perfectly well cleaned from any adhering dust or soil, especially about the point of contact ; and in laying them upon each other a little pressure should be used, accom- panied at first with a little side motion, after which they must be left at rest. If the surface of the incumbent lens, especially when it is of a very short focal length, is free from all imperfection and highly polished, the adjustment of the focus of the above-mentioned eye-glass, which 1 always use for vicwino; the rings, is rather troublesome, in which case a small spot of ink made upon the lens will serve as an object for a suf-r ficient adjustment to find the rings. 'iviixvi,^ Second Method. Instead of the slip of glass, I laid down a well poiished plain metalline mirror; and placing upon it the same i;'6-inch double convex lens, I saw again a conj^ plete set of concentric rings. It is singular that, in this case, the rings reflected from a bright metalline surface will appear fainter than when the same lens is laid on a surface of glass reflecting but littlo light ; this may however be accounted for by the brilliancy of the metalline ground on which these faint rings are seen, the contrast of which will ofluscate their feeble appearance. Generalization. On the same metalline surface every va- riety of lenses may b« laid^ whatever be the figure of their uppe 76 Experiments for investigating ^''■ upjjtr surface, whether plain, concave, or convex, and whatever be their focal lengths, provided the lowest surface renoains convex, and concentric rings will always be ob- tained ; but for the reason mentioned in the preceding para- graph, very small lenses should not be used till the experi- mentalist has been familiarized with the method of seeing these rings, after which lenses of two inches focus, and gradually less, may be tried. Third Method, Hitherto we have only used a plain sur- face upon which many sorts of glasses have been placed ; in order therefore to obtain a still greater variety, 1 laid down a plano-convex lens of 15 inches focal length, and upon the convex surface of it I placed the 26-inch double convex lens, v/hich produced a complete set of rings. Fourth Method. The same lens placed upon a convex metalline mirror of about 15 inches focal length gave also a complete set of rings. j Generalization. These two cases admit of a much greater variety than the first and second methods ; for here the in- cumbent glass may have not only one, but both its surfaces of any figure whatsoever ; whether plain, concave, or con- vex ; provided the radius of concavity, when concave lenses are laid upon the convex surface of glass or metal, is greater than that of the convexity on which they are laid. The figure of the lowest surface of the subjacent substance, when it is glass, may also be plain, concave, or convex ; and the curvature of its upper surface, as well as of the mirror, may be such as to give ttiem any focal length, provided the radius of their convexities is less than that of the concavity of an incumbent lens; in all which cases complete sets of concentric rings will be obtained. Fifth Method. Into the concavity of a double concave glass of 8 inches focal length I placed a 7-inch double con- vex lens, and saw a very beautiful set of rings. Sixth Method. Upon a 7-feet concave metalline mirror I placed the double convex 26-inch lens, and had a very fine set of rings. Generalization, With these two last methods, whatever may be the radius of the concavity of the subjacent surface, provided the Cause of coloured cmcentrlc 'Rings, 77 provided it be greater than that of the convexity of the in- cumbent glass ; and whatever may be the figure of the upper surface of the lenses that are placed upon the former, there will be produced concentric rings. The figure of the lowest surface of the subjacent glass may also be varied at pleasure,: and still co;icentric rings will be obtained. ,^ II. Of seeing Rings ly Transmission, The great variety of the different combinations of these differently figured glasses and mirrors will still admit of fur- ther addition, by using a different way of viewing the rings. Hitherto^ the arrangement of the apparatus has been such as to make them visible only by reflection, which is evident, because all the experiments that have been pointed out may be made by the light of a candle placed so that the angle of incidence and of reflection towards the eye of the observer may be equal. But Sir I. Newton has given us also an observation where he saw these rings by transmission, i» consequence of which I have again multiplied and varied the method of producing them that way, as follows : First Molkod, On a slip of plain glass highly polished on both sides place the same double convex lens of 26 inches, which had already been used when the rings were seen by reflection. Take them both up together and hold thein against the light of a window, in which position the con- centric rings will be seen with great ease by transmitted light. But as the use of an eye-glass will not be convenient in this situation, it will be necessary to put on a pair oi spectacles with glasses of 5, 6, or 7 inches focus, to mag- nify the rings in order to see them more readily. Second Method, It would be easy to_ construct an appara- tus for viewing the rings by transmission fitted witii a pro- per eye-glass ; but other methods of effecting the same pur- pose are preferable. Thus, if the two glasses that are to give the rings be laid upon a hollow stand, a candle placed at a proper -angle and distance under them will show the rings conveniently by transmitted light, while the observer and the apparatus remain in the same situation as if they were to be seen by reflection. i Third 78- Experiments for investigating Third Method. A still more eligible way is to use daylight received upon a plain metalline mirror reflecting it upwards to the glasses placed over it, as practised in the construction of the common double microscope : but I forbear entering; into a further detail of this last and most useful way of seeing rings by transmission, as I shall soon have occr«iion to say more on the same subject. Gejieralization, Every combination of glasses that has been explained in the first, third, and fifth methods of see- ing rings by reflection will also give them by transmission, when exposed to the light in any of the three ways that have now been pointed out. When these are added to the former, it will be allowed that we have an extensive variety of ar- rangements for every desirable purpose of making experiments upon rings, as far as sine;le sets of them are concerned. III. Of Shadows, When two or more sets of rings are to be seen, it will re- quire some artificial means, not only to examine them cri- tically, but even to perceive them ; and here the shadow of some slender opaque body will be of eminent service. Ta cast shadows of a proper sise and upon places where they are wanted, a pointed penknife may be used as follows : . When a plain slip of glass or convex lens is laid down, and the point of a penknife is brought over either of them, it will cast two shadows, one of which may be seen on the first surface of the glass or lens, and the other on the lowest. When two slips of glass are laid upon each other, or a convex lens upon one slip, so that both are in contact, the penknife will give three shadows; but if the convex lens should be of a very short focus, or the slips of glass a little separated, four of them may be perceived; fbr in that case there will be one formed on the lowest surface of the incum- bent glass or lens ; but in my distinction of shadows this will not be noticed. Of the three shadows thus formed the second will be darker than the first, but the third will be taint. When a piece of looking-glass is substituted for the lowest slip the third shadow will be the strongest. Three slips of glass in contact, or two slips with a lent upon ihcni, or also a looking-glass, a slip and a' lens put together. \ the Cause of coloured concentric Rings. 79 together, will give four shadows, one from each upper sur- face and one from the bottom of the lowest of them. In all these cases a metalline mirror may be laid under the same arrangement without adding to the number of sha- dows, its effect being only to render them more intense and distinct. The shadows may be distinguished by the following me- thod : When the point of the penknife is made to touch the surface of the uppermost glass or lens, it will touch the point of its own shadow, which may thus at any time be easily ascertained ; and this in all cases I call the first sha- dow ; that which is next to it, the second ; after which follows the third, and so on. In receding from the point, the shadows will mix to- gether, and thus become more intense ; but which, or how many of them are united together, may always be known by the points of the shadows. When a shadow is to be thrown upon any required place, hold the penknife nearly half an inch above the glasses, and advance its edge foremost gradually towards the incident light. The front should be held a little downwards to keep the light from the underside of the penknife, and the sha* dows to be used should be obtained from a narrow part of it. With this preparatory information it will be easy to point out the use that is to be made of the shadows when they are wanted. IV. Of two Sets of Rings, I shall now proceed to describe a somewhat more com- plicated way of observation, by which two complete sets of concentric rings may be seen at once. The new or addi* tional set will furnish us with an opportunity of examining rings in situations where they have never been seen before, which will be of eminent service for investigating the cause of their origin, and with the assistance of the shadows to be formed, as has been explained, we shall not find it diffi- cult to see them in these situations. First Method, Upon a well polished piece of good look- ing-glass lay down a double convex lens of about 20 inches focus. When the eye-glass has been adjusted as usual for seemcf 80 Experiments for investigating seeing one set of rings, make the shadow of the peilknife, in the order which has been described, pass over the lens; then, as it sometimes happens in this arrangement that no rings are easily to be seen, the shado\^ will, in its passage over the suiface, show where they are situated. When a set of them is perceived, which is generally the primary one, bring the third shadow of the penknife over it, in which situation it will be seen to the greatest advantage. Then, if at the same time a secondary set of rings has not yet been discovered, it will certainly be perceived when the second shadow of the penknife is brought upon the primary set. As soon as it has been found out, the compound sha- dow_, consisting of all the three shadows-united, may (hen be thrown upon this secondary set, in order to view it at leisure and in perfection. But this compound shadow should be taken no further from the point than is necessary to cover it ; nor should the third shadow touch the primary set. The two sets are so near together, that many of the rings of one set intersect some of the other. When a sight of the secondary set has been once obtained, it will be very easy to view it alternately with the primary one by a slight motion of the penknife, so as to make the third shadow of it go from one set to the other. Besides the use of the shadows, there is another way to make rings visible when they cannot be easily perceived, which is to take hold of the lens .vith both hands, to press it alternately a little more with one than with the other; a tilting motion, given to the lens in this manner, will move the two sets of rings from side to side ; and as it is well known that a faint object in motion may be sooner perceiv- ed than when it is at rest, both sets of rings will by these . means be generally detected together. It will also contribute much to facilitate the method of seeing two sets of rings, if we receive the light in a more oblique angle of incidence, such as 40, 50, or even 60 de- grees. This will increase the distance between the centres of the primary and secondary sets, and at the same time oc- caaion a more copiou:* reflection of light. instead of a common looking-glass a convex glass mirror may the Cause of coloured concentric Rings, SI may be used, on which may be placed either a plain, a con- cave, or a convex surface of any lens or glass, and two sets of rings will be obtained. In the same manner, by laying upon a concave glass mirror a convex lens, we shall also have two sets of rings. The generalizations that have been mentioned when one get of rings was proposed to be obtained, may be easily ap<^ plied with proper regulations, according to the circumstances of the case, not only to the method by glass mirrors already mentioned, but likewise to all those that follow hereafter, and need not be particularized for the future. In the choice of the surfaces to be joined, we. have only to select such as will form a central contact, the focal length of the lenses and the figure of the upper surface being variable at pleasure. Second Method. On a plain metalline mirror I laid a pa- rallel slip of glass, and placed upon it the convex surface of a 1 7-inch plano-convex lens, by which means two sets of rings were produced. Upon the same mirror the plain side of the plano-convex glass may be laid instead of the plain slip, and any plain, convex, or concave surface being placed upon the convexity of the subjacent lens, will give two sets of rings. The plain side of a plano-concave glass may also be placed upon the same mirror, and into the concavity may be laid any lens that will make a central contact with it, by which arrangement two sets of rings will be obtained. Third Method. Upon a small well polished slip of glass place another slip of the same size, and upon them, lay a 39-inch double convex lens. This will produce two sets bf rings ; bne of them reflected from the upper surface of the' first slip of glass, and the other from that of the second. Instead of the uppermost plain slip of glass we may place' upon the lowest slip the plain side of a plano-oonvex or plano-concave lens, and the same variety which has been explained in the third method, by using any incum- bent lens that will make a central contact, either with the convexity or concavity of the subjacent glass, will always produce two sets of rings. Vol. 30, No. U7. Feb. 1808. F Fourth ^%, Experiments for investigating Fourth Method. A more refined but rather more difficult way of seeing two sets of rings, is to lay a plain slip of glass on a piece of black paper, and when a convex lens is placed upon the slip, there maybe perceived, but not without par- ticular attention, not only th'e first set, which has already been pointed out as reflected from the first surface of the slip, but also a faint secondary set from the lowest surface of the same slip of glass. It will be less difficult to see two sets of rings by a reflec- iion from both surfaces of the same glass, if we use, for in- stance, a double concave of 8 inches focus with a double convex of /j inches placed upon it. For, as it is well known that glass will reflect more light from the furthest surface when air rather than a denser medium is in contact with it, the hollow space of the 8- inch concave will give a pretty strong reflection of the secondary set. Fifth Method. The use that is intended to be made of two sets of rings requires that one of them should be dependent upon the other : this is a circumstance that will be explained hereafter; but the following instance, where two indepen- dent sets of rings are given, will partly anticipate the subject. When a double convex lens of 50 inches is- laid down with a slip of s^lass placed upon it, and another double convex one of 26 inches is then placed upon the slip, we get two sets of rings of different sizes ; the large rings are from the 50-inch glass, the small rings from the 26-inch one. They are to be seen with great ease, because they are each of them primar}\ By tilting the incumbent lens or the slip of glass these two sets of rino^s may be made to cross each other in any direc- tion ; the small set may be laid upon the large one, or either of them may be separately removed towards any part of the glass. This will be sufficient to show that they have no con- nection with each other. The phaenomena of the motions, and of the various colours and sizes assumed by these rines, when different pressures and tiltings of the glasses are used, will afford some entertainment. With the assistance of the shadow of the penknife the secondary set belonging to the rings from the 26-inch lens will be added to the other two" sets; the Cause of coloured concentric Rings, 83 sets ; but in tilting the glasses this set will never leave its primary one, while that from the 50-inch lens may be made to go any where across the other two. KV •'/; 'ii> ■:):;^f(fj •■\\ V. Of three Sets of Rings. To see three sets of concentric rings at once is attended with some difficulty ; but by the assistance of the methods of tilting the glasses and making use of the multiplied sha- dows of a penknife, we may see them very well, when there is a sufficient illumination of bright daylight. '' ^^Wtrst Method. A 26-inch double convex lens placed upon three slips of plain glass, will give three sets of rings. The slips of glass should be nearly 2-tenths of an inch thick, otherwise the different sets will not be sufficiently separated. When all the glasses are in full contact, the first and second sets may be seen with a little pressure and a small motion, and, if circumstances are favourable, the third, which is the faintest, will also appear. If it cannot be seen, some of the compound shadows of the penknife must be thrown upon it 5 for in this case there will be five shadows visible, several of which will fall together and give different intensity to their mixture. Second Method. When a single slip of glass, with a 34- inch lens upon it, is placed upon a piece of good looking- glass, three sets of rings may be seen : the first and third sets are pretty bright, and will be perceived by only pressing the lens a little upon the slip of glass ; after which it will be easy to find the second set with the assistance of the proper shadow. In this case four shadows will be seen ; and when the third shadow is upon the first set, the fourth will be over the second set and render it visible. Third Method. When two slips of glass are laid upon a, plain metalline mirror, then a 26-inch lens placed upon the slips will produce three sets of rings ; but it is not very easy to perceive them. By a tilting motion the third set will ge- nerally appear like a small white circle, which at a proper distsfnce will follow the movement of the first set. Ais soon as the first and third sets are in view, the third shadow of the penknife may be brought over the first set, by which means F 2 the S4 Experiments for investigating the fourtli shadow will come upon the second set, and in this position of the apparatus it will become visible. Fourth Method. On a plain ujetalline mirror lay one slip of glass, but with a small piece of wood at one end under it, so that it may be kept about one-tenth of an inch from the mirror, and form an inclined plane. A i'6-inch lens laid upon the slip of glass will give thrqe ?ets of rings. Two of them will easily be seen ; and when the shadow of the pen- knife is held between them, the third set will also be per- ceived. There is but one shadow visible in this arrange- ment, which is the third ; the first and second shadows being lost in the bright reflection from the mirror. Fifth Method. I placed a 6f-inch double convex upon an 8-inch double concave, and laid both together upon a plain slip of glassw This arrangement gave three sets of rings. They may be seen without the assistance of shadows, by using only pressure and tilting. The first had a black and the other two had white centres. VI. Of four Sets of Rings. The difficulty of seeing many sets of rings increases with their number, yet by a proper attention to the directions that are given, four sets of concentric rings may be seen. First Method. Let a ^lip of glass, with a 26 -inch lens laid upon it, be placed upon a piece of looking-glass. Under one end of the slip, a small piece of wood one-tenth of an inch thick must be put tokeep it from touching the looking- glass. This arrangement will give us four sets of rings. The first, third, and fourth may easily be seen, but the second set will require some management. Of the three shadows which this apparatus gives, the second and third must be brought between the first and fourth sets of rings, in which situation the second set of rings will become visible. Second Method. When three slips of glass are laid upon a metalline mirror, and a plano-convex lens of about 17 inches focus is placed with its convex side upon them, four sets of rings may be seen ; but this experiment requires a very bright day, and very clean, highly polished slips of plain glass. Nor caa it be successful unless all the fore- going the Catcse of coloured concentric Rings. 65- golng methods of seeing multiplied sets brings are become familiar and easy. I have seen occasionally, not only foiif SMlS^e, Ml.^ven six sets of concentric rings, from a very simple arrarigemetii of glasses : they arise from reiterated internal reflections j but it will not be necessary to carry this account of seeing midtiplied 'Sets of rings to a grfcater length. ^^■"^^'"^' VII. Of the Size of the Rings. \ ''^I'he diameter of the concentric rings depends lljioit the'ra- dius of the curvature of the surfaces between which they are formed. Curvatures of a short radius, cafteris paribus, give smaller rings than those of a longer; hiit sit Isaac Newtoti having already treated on this part of the subject at lafge, it will not be necessary to enter further into it. '*' I should however remark, that when two curving are con- cerned, it is the application of them to each other that will determine the size of the rings, so that large ones may be produced from curvatures of a very short radius. A double convex lens of 2^- inches focus, for instance, when it is laid upon a double concave which is but little more in focal length, gives rings that are larger than those from a lens of t6 inches laid upon a plain slip of glass. YUi, Of Contact. rt^J;/ The size of the rings is considerably affected by pressure. They grow larger when the two surfaces that form them afe pressed closer together, and diminish when the pressure is gradually removed. The smallest ring of a set rpay be in- creased by this means to double and treble its former dia- meter: but as the common or natural pressure of glasses laid upon any flat or curved surface is occasioned by their weight; the variations of pressure will not'be vcrf consiclerable when they are left to assume their own distance or cbntact. To produce that situation, however, which' 'is 'geiifeiPally^ called contact, it will always be "necessary to' giVe a liftle'motidh backwards and forwards to the incumbent lens q'i' glass, ac- companied with some moderate pTessiTr6,'^fter'Wh'icli it nr'aV beieft-io settle prop^riy -by its -oXv^'w^r^hi:^ 'O- ; n v..a£.i?ifr ' F3 IX. Of 86 Experiments for investigating IX. Of meastiring Rings. It may be supposed from vvhai has. been said concerning the kind of contact which is required for glasses to produce rings, that an attempt to take absolute measures must be liable to great inaccuracy. This was fully proved to me when I wanted to ascertain, in the year 1 792, whether a lens laid upon a metalline surface would give rings of an equal diameter with those it gave when placed on glass. The measures differed so much that I was at first deceived ; but on proper consideration it appeared that the Huygenian ob-» ject glass, of 122 feet focus, which I used for the experi" ment, could not so easily be brought to the same contact on metal as on glass ; nor can we ever be well assured that an equal distance between the two surfaces in both cases has been actually obtained. The colour of the central point, as will be shown hereafter, may serve as a direction ; but even that cannot be easily made equal in both cases. By taking a sufficient number of measures of any given ring of a set, when a glass of a sufficient focal length is used, we may however determine its diameter to about the 25th or 30th part of its dimension. nnjni^' Relative measures for ascertaining the proportion of the different rings in the same set to each other, may be more accurately taken ; for in that case the contact with them all will remain the same, if we do not disturb the glasses during the time of measuring. X. Of the Numler of Rings, When there is a sufficient illumination, many concentric rings in every set will be perceived ; in the primary set we see generally 8. 9, or JO, very conveniently. By holding.the eye in the most favourable situation I have often counted near 2Q, and the pumber pf them is generally lost when they grow too narrow and minute to be perceived, so that we can never be said fairly to have counted them to their full extent. In the second set I have seer^,,as,jmany as in the first, and they are full as bright. The third set, when it is seen by a metalline mirror under two slips, will be brighter than the second. the Cause of coloured concentric "Rings, 87 second, and almost as bright as the first: I have easily counted 7, 8, and 9 rings. XT. Of the Effect of Pressure on the Colour of the Rings, When a double convex object glass of 14 or 15 feet focus is laid on a plain ?lip of glass, the first colours that make their faintest appearance will be red surrounded by green ; the smallest pressure will turn the centre into green sur- rounded by red : an additional pressure will give a red centre again, and so on till there have been so many successive al- terations as to give us six or seven times a red centre, after which the greatest pressure will only produce a very large black one surrounded by white. When the rings are seen by transmission, the colours are in the same manner subject to a gradual alternate change occasioned by pressure ; but when that is carried to hs full extent, the centre of the rings will be a large white spot sur- rounded by black. The succession and addition of the other prismatic colours after the first or- second change, in both cases is extremely beautiful; but as the experiment may be so easily made, a description, which certainly would fall short of an actual view of these phaenomena, will not be necessary. When the rings are produced by curves of a very short radius, and the incumbent lens is in full contact with the slip of glass, they will be alternately black and white; but by lessening the contact, I have seen, even with a double convex lens of no more than two- tenths of an inch focus, the centre of the rings white, red, grfcen, yellow, and black, at pleasure. In this case 1 used an eye-glass of one inch focus ; but as it requires much practice to manage such small glasses, the experiment may be more coi^vcniently made by placing a double convex lens of two-inch focus on a plain slip of glass, and viewing the rings by an eye-glass of S-J- inches ; then having first brought the lens into full con- tact, the rings will be only black and white, but by gently Jfting up or tilting the lens, the centre of the rings wilL as- suipe various colours at pleasure. F4 XII. Of fi* Experiments for investigating XII. Of diluting and concentrating the Colours. Lifting up or tilting a lens being subject to great uncer- tainty, a surer way of acting upon the colours of the rings is by dilution and concentration. After having seen that very small lenses give only black and white when in full contact, we may gradually take others of a longer focus. With a double convex lens of four inches the outward rings will begin to assume a faint red colour. With 5, 6, and 7, this appearance will increase ; and proceeding with lenses of a larger focus, when we come to about 16, 18, or 20 inches, green rings will gradually make their appearance. This and other colours come on much sooner if the centre of the lens is not kept in a black contact^ which in tjiese experiments must be attended to. A lens of 26 inches not only shows black, white, red, and green rings, but the central black begins already to be di- luted so as to incline to violet, indigo, or blue. With one Qf 34, the white about the dark centre begins to be diluted, and shows a kind of gray inclining to yellow. With 42 and 48, yellow rings begin to become visible. With 55 and 59, blue rings show themselves very plainly. With a focal length of 9 and i 1 feet, orange may be distinguished from the yellow, and indigo from the blue. With 14 feet, some violet becomes visible. When the 122 feet Huygenian glass is laid on a plain slip, and well settled upon it, the central colour is then sufficiently diluted to show that the dark spot, which in small lenses, when concentrated, had the appear- ance of black, is now drawn out into violet, indigo, and blue, with little admixture of green ; and that the white ring;, which used to be about the central spot, is turned partly green with a surrounding yellow, orange, and red-coloured space or ring ; by which means we ^eein to have a fair ana- lysis of our former compound black and white centre. One of my slips of glass, which is probably a little con- cave, gave the rings still larger when the 122 feet glass was firmly pressed against it. I used a liti)e side motion at th^ sanie time, and brought the glasses into such contact that they adhered sufficiently to be lifted up together. With this adhesion I perceived a colour surrounding a dark centre .^Vt':J^^tT^'|fo Cau^e of tolmired concenfnc i^/w^^r- ' ^^^'- S^ tcentre which T httvti iifever seen in any prismatic spectrum. It is a kind of light brown, resembling the colour of a cer- taifi'sort of Spanish snuff. The 170 feet object glass showed the same colour also very clearly. XIII. Of the Order of the Colours. The arrangement of the colours in each compound ring or alternation, seen by reflection, is, that the most refrangible rays are nearest the centre ; and the same order takes place when seen by transmission. We have already shown that when a full dilution of the colours was obtained their arrange- ment was violet, iridigo, blue, green, yellow, orange and red; and the same order will hold good when the colours are gradually concentrated again ; for though some of them should vanish before others, those that remain will always be found to agree with the same arrangement. If the rings should chance to be red and green alternately, a doubt might arise which of them is nearest the centre; but by the method of. dilution, a little pressure, or some small increase of the focal length of the incumbent lens, there will be introduced an orange tint between them, which will immediately ascertain the order of the colours. In the second set of rings the same order is still preserved as in the first j and the same arrangement takes place in the third set as well as in the fourth. In all of them the most refrangible rays produce the smallest rings. XIV. Of the alternate Colour and Size of the Rings belong' hig to the primary and dependent Sets, When two sets of rings are seen at once, and the colour of the centre of the primary set is black, that of the secondary will be white; if the former is white, the latter will be black. The same alternation will take place if the colour of the centre of the primary set should be red or orange ; for then the centre of the secondary one will be green ; or if the former happens to be green, the latter will be red or orange. At the same time there will be a similar alternation in the size of ringy ; for the white rings in one set will be of the diameter of the black in the other ; or the orange rings of the forniA will be of equal magnitude with the green of the latter. When three sets of rings are to be seen, the second and third 00 Surgical Cases in the City and Finshury Dispensaries, third sets will be alike in colour and size, but alternate in both particulars with the primary set. The same thing will happen when four sets are visible ; for all the sets that are formed from the primary one will resemble each other, but will be alternate in the colour and dimensions of their rings with those of the primary set. [To be continued.] XIX. Report of SurgicQl Cases in the City and Finshury Dispensaries for September 1807. J5y John Taunton, E^^. JLn the month of September there were admitted on the books of the City and Finshury Dispensaries 237 surgical patients. Cured or relieved - - 205 Died - - - - 4 Under cure - - - 28 237 .Since which time there have been admitted 963. One of the fatal cases was that of Mrs. M. S. aet. 67^ who, soon after the birth of her ninth and last child, was seized with femoral hernia : the tumour was small, but painful, attended with sickness and inclination to vomit; these symptoms did not last long, as the hernia receded without assistance : she had another attack in about six weeks, which was also of short duration ; the hernia soon became irreducible, and she had been exposed to similar attacks for the last sixteen years of her life, for which time it had never been completely returned : these were occasionally longer and more severe ; the symptoms frequently continued for two or three days, but were removed without any operation or medicine, except some Daffy's elixir. On the 22d of August she was seized with the usual symptoms, viz. pain over the whole belly, particularly in the region of the stomach, with a sensation of heat, vomit- ing, cold sweats, intermitting pulse, and suppression of stools for four days : the tumour was now much larger than before, being nearly the size of a child's head at birth : at ..|his period she had a motion of a small quantity of feculent matter. Royal Society, 91 matter, after which the bowels were confined for ihr^ days, when she was taken with diarrhoea, an acute pain in the bowels, cold sweats, pulse variable, vomiting of feculent matter ; but the hiccup was not very distressing : — these symptoms continued for nine da\'S, being sixteen from the attack, when she sunk under the disease. The medicines given during this illness were, opium, calomel, extract, colocynth. cum calomel, enema communis, and the enema cum nicotiana. She could not be prevailed on to submit to the operation. On dissection, the intestines were distended with flatus, the colon was much enlarged and inflamed, part of the syg- moid flexion was contained in the hernial sac, but not the whole circumference of the intestine, which left thecdnal per- vious. The adhesions were firm around the mouth of the sac, from which the intestine could not be separajled, and the coats were much thickened'by inflammation which approached to gangrene. The omentum was much inflamed and adhered to the hernial sac ; and that part of the omentum within the sac was much enlarged and more firm, which, together with the adhesions, had rendered this an irreducible hernia, John Taunton, Surgeon to the City and Finsbury Grevllle-street, Hatton-garden, Dispensaries, Lecturer on Ana« February 23, 1808. • tomy, Surgery, Physiology, &c. XX. Proceedings of Learned Societies , ROYAX SOCIETV. On the 5th of February, a letter from Mr. Knight, to the president, was read, on the inconvertibility of the bark of trees into the alburnum. The author, as usual, detailed the effects of a great many experiments made to confirm this opinion, which he announced in the conclusion of a letter read before the Society last season, (see Philosophical Magazine, No. 109, vol. xxviii. p. 43.) One of the most obvious reasons assigned for the truth of this opinion was, that many trees having barks very dissimilar, have wood very similar; and that, had the alburnum been formed «f the bark, the wood must consequently have been as different as 2 the 92 Roijal Society, the l^ark was. On the other hand, many trees with bark very shnilar, have wood very different. These facts, in con- junction with some minute expcTiments, Mr. Knight con- cluded as decisive that the hark is not transmuted, as MaU pighi supposed, into alburnum ; but that each performs its peculiar function in the ceconomy of vegetation. February 11 and 18. Several mathematical papers on the properties of a circle, Slc , were presented to the Society fcy the astronomer royal, but were not of a nature to be read. A curious paper on cranites^ or the idiotism of the inhabitants of alpine regions, who are affected with goitres, or swellings about the head, was read. From the author's researches among the people of Switzerland, and his inves- tigation of the supposed connection between this species of mental imbecility and. goitres, (which are generally ascribed la the effect of using snow-wa,ter on the glands,) he was led to conclude that cranites exists frequently where there are no goitres, and that many families suffer the latter complaint without experiencing the former. February 25. A. Marsden, esq-., in the chair. A ge- ological paper on the whin-dykes in the north of Ireland, in a letter to Mr. Davy, was laid before the Society. A continuation of Mr. Home's experiments on the func- tions of the spleen was read, in which this able naturalist operated on asses with extract and tincture of rhubarb, as related in his former experiments on dogs. The spleen and the colon were found impregnated with the rhubarb, when none was found in the liver. Several curious experiments were made to ascertain the quantity of serum and of rhubarb found in the blood in the vena cava, the left auricle of the heart, and other members : but the results are not satis^ factorily established. /orjin-'M; A letter from Mr. Mutdoch, to the president, was read, containing an account of the origin, progress, and present irtate of gas-lights. It appears that so long ago as 1739 Dr. Clayton, in the Philosophical Transactions, discovered the inflammability of gas procured from coals : but this knowledge was never adapted to practice till about sixteen years ago, when the author, at a foundry in Cornwall, first •\^\ proposed New Process for preparing Calomel, 9t proposed the application of this gas-light to ceconomical pur- poses, and actually carried it into eftcct. In 1798 he also cstahlished it on a larger scale at Messrs. Bolton and Watts, Soho, Birniingham. But at Messrs. Phillips and Go's cotton factory it has been carried to the highest degree of perfection, and on the most extensive scale, of any place \i\ the kingdom. From a statement of the relative expense of candles and gas, it appears that for the light which that manufactory required, 2000/. a year would be expended in candles; whereas ihe wear and tear and expenses oF gas- lights do not much exceed 600/. a year, amounting to about one-third the expense of candles. . 1 IMPERIAL ACADEMY OF SCIENCES AT ST. PETERSBURGlti^- '^This Academy has published the 13th volume of their Memoirs, It coii tains, among other interesting articles, a description of the celebrated silver mine of Zuseoff, ou Mount Athol, in Siberia, with an account of the total pro- duce of that mine from 1747 to 1793 inclusive. UNIVERSITY OF WILNA. ,j This body has announced the following as the subject of a prize question : ^< What are the chief diseases of plants, and what analpgy exists between them and those of ani-i malsr" The prize is 100 ducats; and the memoirs, written in Latin, French, or Polish, must be sent before the first of September 1808 to the rector of the University, under cover to Messrs. IJeiser or Karner, bankers in Wilna. The prize will be adjudged in the month of January J8O9. " .-.; : ■ :-v' -r ' ',T. .f•:^f•^W):,-^.^^-^■^rt ""^^ XX r. Intelligence and Miscellaneozis Articles. NEW PROCESS tOT^ PREPARING CALOMEL. xjLn important improvement in the preparation of that es- sential article of the pharmacopoeia, calomel, has been re- cently introduced by Messrs. Luke Howard and company, chemists. It consists in a peculiar mode of conducting the final suliimation by fire; by which the vapour of the calo- mel. 94 MisccUdneous, mel, instead of being suffered to concrete, as usual, into a folid cake at the upper part of the vessel, is thrown out into water, where it is instantlv condensed into a white powder possessing the impalpable fineness of a precipitate. The imperfect operations of grinding and levigating are thus su- perseded, and the defects which have so generally been complained of in the medicine from this cause remedied. The product is lighter than levigated calomel, in conse- quence of its greater comminution, three parts by weight occupying the same space a.s Jive of the latter. M. Douett Richardott, a French agriculturist, has long practised with success a new method of curing cattle whose stomachs are swoln from having fed upon wet forage. It consists in administering to the animal the twentieth part of a pound of gunpowder, mixed in a pint of milk, when first seized with the colic from eating grass or clover highly charged with dew. This remedy was long agO' an- nounced in the French Journals, but M. Richardott has been the first to publish the results of its application. M. Allaire, a French chemist, has published a new me- thod of scouring wool, which consists in dipping it repeat^ edly in a ley of quick-lime. The chalky earth forms an animal soap with the grease. By this means the wool is speedily and oeconomically scoured, and without altering its qualify. LIST OF PATENTS FOR NEW INVENTIONS. To Willis Earle, of Liverpool, in the county of Lancaster, merchant, for his invention of certain improvements in the tillage and dressing of land, and the cultivation of plants. — January 13, 1808. To James Lee, of Plaistow, in the county of Essex,^ merchant, and John Perrin, oF the same place, esq., for their new invented method of preparing certain kinds of hemp ; by which the value and the utility of the articles are much increased. January 13. To John Wilkinson, of Bradley Iron Works, in the liberty of Bilston, in the county of Stafford, esq., for his new^ List of Patents for New Inventions, 03 new invented method of making pig or cast metal from the ore; which, when manufactured into bar iron, will be found equal in quality to any that is. jjp ported from Russia or Sweden. January 23. To Andrew Johansen, of Hommerlon, in the parish of Hackney, in the county of Middlesex, gent., for certain improved methods of manufacturing a kind of tablet or ar- tificial whetstone, for whetting or sharpening razors, pen- knives, surgeons* instruments, and other cutlery, and which he usually denominates ^* Cotific Tablets." January 23. To Edward Moore Noble, of Birmingham, in the county of Warwick, surgeon, for his new method of making of carbonate of lead, commonly called white lead. Jan. 23. To Samuel Phelps, of Cuper's Bridge, Lambeth, in the county of Surry, esq., for his improvements in manufac- turing soap. January 23. To Thomas Preston the younger, of Tooley-street^ South- wark, in the county of Surrey, lead merchant, for his im- proved method of setting boilers for steam engines, pans for melting lead, tin, pewter, and other metals of easy fusion ; and a new method of discharging the pans for melting lead, tin, pewter, &c., as before named, when full, and setting coppers and boilers of every description. January 26. To George Savage, of Huddersfield, in the county of York, watch-maker, for his improved method of regulating or equalizing the force or power of the main-spring in watches, or other machines for measuring time. Jan. 26. To William Stewart, of Limehouse, in the county of Middlesex, builder, for certain improvements in making bricks and tiles. January 26. To Joseph Johnson and John Wilmot, of Birmingham, in the county of Warwick, manufacturers, for their new invented warming-pans, which are not only applicable to the purpose of airing and warming beds, but also for airing and warming rooms or carriages, or for other purposes requiring a long and protracted heat. January 28. To William Newberry, of St. John-street, in the county of Middlesex, gent., for his improved machinery for the purpose of sawing wood^ splitting or paring skins. Jan. 30. METEORO- 96 Meteorology, meteoro^^ogical table, By Mr. Cakev, op the Strand, For February 1808. Thermometer. Mi . ^ Days of the JVIonth. , ;z. 8 c 1 Height of the Baiom. Inches. " (U >. c OS: Xa >^ Weather- • Jan. 27 26^^ 37" 41^' 29-30 6 Cloudy 28 46 46 34 •25 11 Fair 29 34 42 42 •62 30 Fair 30 46 49 48 •70 17 Showery 31 49 52 49 •70 14 Cloudy Feb. 1 48 53 48 •71 13 Cloudy ■ 2 43 50 40 '55 30 Stormy 3 38 42 3b •90 18 Fair 4 32 41 36 30-30 16 Fair 5 41 47 37 •10 10 Fair 6 42 50 47 29-78 12 Stormy 7 48 49 44 •89 30 Cloudy 8 33 39 34 •73 0 Rain 9 32 39 32 •82 25 Cloudy 10 28 35 30 30-03 21 Fair U 29 40 38 29-75 16 Cloudy 12 28 29 25 •50 0 Great fall of snow 13 28 30 25 •80 8 Fair 14 24 30 24 30-01 15 Fair 15 19 33 33 29-98 0 Snow 16 34 42 34 •88 4 Cloudv 17 32 39 40 30-02 11 Cloudy 18 42 43 38 •03 0 Rain ' 19 33 41 32 •28 21 Fair 20 30 38 30 •45 16 Fair 21 29 37 31 •50 20 Fair 22 30 39 32 •46 18 Fair 23 32 38 35 •37 10 Cloudy 24 35 37 33 '57 15 Cloudy N. B. The Barometer's height Is taken at one o'clock. [ 97 ] XXir. On Blasting Rocks, and Tamping. By John" Taylor, Esq, To Mi\ TillocL SIR, A LETTER from an engineer of celebrity to Mr. Nicholson, and published in the ninth volume of his Journal, introduced to the public some time ago an account of the use of sand in blasting rocks or other hard substances : a letter from another gentleman, published in your Magazine soon after, continued the subject, and mentioned other modes of con- fining the gunpowder employed for this purpose ; and we have been lately informed of the result of experiments made in France upon what Mr. Nicholson calls Mr. Jessop*s me^ thod of blasting rocks with sand, by a notice published in the Philosophical Journal of July last. As the process has long been known, however, in this neighbourhood, and the constant experience of the work- men in the mines and quarries agrees pretty nearly with the French report, it may not be useless to detail the instances in which it may be advantageously employed, and to point out the cases where it is not likely to be effectual ; and in mines the latter are more numerous than the Ibrmrr. As another substance has been lately introduced into use here, which possesses advantages occasionally overall others, it will likewise give me pleasure to fnake it more generally ;icnown, especially as this is an operation on the easy execu- tion of which often depends the safety of the lives of the persons conducting it. The new process I allude to, is that of closing the hole, upon the proper charge of gunpow- der, with clay wrought to rather a soft consistency, and rammed- in in suOicient quantity, which, where the resis- tance is not too great, possesses the following advantage^. It may be applied to holes bored in all directions ; may be perforated for the fuse w iilmul danger,' and is^peculiarly adapt- ed for rock in which gunpowder is liable to be rapidly in- jured by water. Sand can only be used where the rock is bored perpendicularly or nearly so ; and in mines but few holes of this description occur> the effect of a given <^uan- Vol. 30. No, 118. March 1808, G ti^r yS On Blasting Rocksy and Tamping, lity of gunjjovvder being certainly greater in those holes the mouths of which are lower than the end which contains the charge. This fact has frequently been shown by a charge in a detached piece of rock confintd by tamping, as the miners call it, in the usual way, and fired with the mouth of the liolti upwards. A certain quantity of tamping will in this position be blown out, and the rock remain entire. tf ihe same hole be recharged with the same quantity of powder, and tamped so as to present an equal resistance, the rock will be torn to pieces by merely altering its posi- timi, so that the charge may lie higher than the mouth of the hole. Thus it may be inferred, that in firing artillery there is more danger of bursting guns when they are laid with their muzzles depressed, than when pointed at any degree of elevation. Holes for blasting in mines are so frequently very wet as to preclude the use of sand where other circuni stances would favour it; for though, by violently compressing tough clay into the fissures, the portion of the hole that is to con- tain the gunpovvder may be made dry, yet to render it so throughout its whole length would be aprocess considerably too tedious. Here the advantage of applying clay for tamp- ing is very great. The hole is instantly filled up with a water-tight substance, and an opening for the fuse is made through it with an iron rod, by a pressure so gentle as to hazard no explosion in the performance. Clay is likewise more likely to be used by miners than sand, if they are acquainted generally with its effect, from its being always at hand, it being so necessary to the other operations of boring and charging holes that it is always in use where blasting is 2:oing on ; and the difficulty of intro- ducing any substance that requires the least exertion to pro- cure or manage among workmen is well known, whatever safctv crease it may afford them. The French engineers pretty accuTately describe the cases in whi .■•.•^.i)ivhich is thcrinearjy equivalent to two fifths of the liquor from which it comes-. M. The- nard even thinks, that if, by means of a straight tube going to the bottom of the retort and of a proper length, we could pour from time to time warm alcohol into the latter, the ethe- rized gas would be formed in still greater abundance ; for wc should conceive that there is every moment more alcohoj volatilized than muriatic acid, and that we should thus re* establish between these two bodies the primitive proportions,, which are more proper than anv other for the success of the operation. In all cases the njanagenient of tlic fire is of the greatest importance : if it be too weak, no etherized gas is produced j if too strong, but very little is produced. Be- sides, we do not etherize the alcohol sensibly by chargimr it with muriatic acid gas, nor do we obtain ether more scn- * The centigrade thermometer is the one intended. — Edit. sibly On the Muriatic Ether, 103 sibly by bringing together the acid and the alcohol in va^ pours into a tube about the temperature of about SO*'. It is therefore by preserving a just medium in the application of the fire that we succeed completely. All this proceeds from too small or too great an elasticity in the alcohol, and the muriatic acid prevents their reaction upon each other. One precaution we must also take, is to use the same water for collecting the gas, and to employ the least quantity P9S7 sible, because itdissolves it in a remarkable degree. This gas is absolutely colourless ; the smell of. it is strongly' etherized, and the taste sensibly saccharine. It has no kind of action either upon turnsole tincture, syrup of violets, or lime-water. lis specific gravity compaKcd to that of air is 2*219 to -f is" of the centigrade thermometer, and; at O™ 75 of pressure at the same temperature, and at the same pressure water dissolves its own volume of it. At this same ilegrce of pressure also, but at + 11° of teinperature, the etherized gas becomes liquid. We may procure a great quantity of it in this state, by using an apparatus similar to that we b^ve just described ; simply, in place of fixing the last tube under a flask full of water, we must plunge it to the bottom of a lopg, straight, well dried probe, and sur- rounded with ice, which we must renew in proportior]^.a$ it melts. It is in this probe that the etherized gas alone arrives and is entirely liquefied ; for, when once the vessels co«itain no more air, we niay wiihout the least danger spp- press its communicaiion with the atmosphere. ..;?, Wlibn thus Tujucfied, this ether is of acjemarkable limpi- dity, as in the state of gas it is without colour and with- out action upon turnsole tincture and syrup of violets; as well as the etherized gas, it is very soluble in alcohol^ from which we may in a great measure pep^rate it by water-; like this gas, it has also a very decided smell, and a very distinct taste, wliich has something analogous to that of sugar, and which is particularly remarkable in vv'ater which is saturated with it, which may perhaps be employed sug* cessfully in medicine. When poured upon the hand, it suddenly evaporates and produces a considerable cold, leav- jng a small whitish residue. At -f- 5" of temperature (cenii- Cj 4 grade 101 On the Muriatic El her, grade thermometer) it weighs 874, water weighing 1000. Thus, aUhough it is far more volatile than the jtulphuric ether, and, a fortiori, than alcohol, not only is it thicker than the fornier, but even than the latter oF these two bodies. Lastly, it does not congeal at a temperature of — 29^ (cen- tigrade thermometer). Hitherto we have seen nothing in this ether which does not perfectly agree with that presented by other matters ; it is nothing else than a substance curious from its nor velty, and particularly from the facility with which it is gasitied and liquefied. When wc reflect upon it a little more, it appears one of the most singular and extraordinary compounds we can produce. It does not in the least red- den turnsole tincture ; the strongest alkalis have no action upon it ; the solution of silver does not meddle with it at all ; and all this, whether we employ it in the gaseous or liquid state, or dissolved in water : if we set fire to it, there is suddenly developed such a quantity of muriatic acid, that this acid precipitates in a mass the concentrated nitrate of silver, suffocates those who respire it, and even appears in the form of vapours in the surrounding air. Is the muriatic acid formed in this inflammation, as. we are induced to think, or is it only set at liberty? This is the question which the author of the memoir afterwards en- deavours to resolve. If the muriatic acid be formed in the combustion of the etherized gas, the radical of this acid must exist in the gas; 3nd this radical necessarily comes froqi the alcohol, or from the muriatic acid decomposed by the alcohol, or, what is not very probable,' although not impossible, from both. In the iirst case, by distilling a mixture of alcohol and muriatic acid, we ought to find after the distillation all the muriatic acid employed, besides that which appeared in the com- })UStion of the gas formed ; in the second case, on the cout trary, a greal quantity of acid ought to disappear in this di-* ^tillatiim ; but by keeping an account of that which is de- veloped in the combustion of the gas formed, this quantity of acid precisely, ^nd no more, ought to reappear entirely. Ju the t:hird ca^q^, ffom this distillation a loss of acid shou'd *ilSQ On the Muriatic Ether. lOi also result ; but this loss should be more than compensated by the quantity of acid which the combustion of the ga« formed ought to produce. Now, on performing this distil- lation upon 450'937 grammes of muriatic acid of a specific gravity of 11-349, at 5° temperature (centigrade thermo- meter), and upon a volume of highly rectified alcohol equal to that of the acid, there are formed 23 litres of etherized gas al the, temperature of 21° of the ccntio;rade tiijermome- tcr, and at the pressure of 0"" 745, and there disappear 122*288 grammes of acid. The first hypothesis is consequently false, since it is de- monstrated that, even should the radical of the muriatic acid exist in the etherized gas, this radical would proceed not merely from the alcohol, but rather either from the muriatic acid alone, or from the muriatic acid and alcohol. " Let us inquire if it proceeds from the muriatic acid alone, as supposed in the second hypothesis : but here there are two ways of considering the phcenomenon : either the mu- riatic acid must have been decomposed by the alcohol, so that its radical, without its other principle, is to be found in the etherized gas; or this decomposition will have been such, that all the principles of the muriatic acid will be found in the etherized gas, not united, and not forming muriatic acid, but combined with the principles of the alcohol, and in the same stale in which hydrogen, oxygen, carbon, and azot exist in animal or vegetable matters. Now if the radi- cal of the muriatic acid exists alone in the other principle, or without a portion of the other principle of the muriatic acid ii; the etherized gas, we ought, by decomposing this gas in a red-hot tube, and deprived of the contact of the air, to obtain no acid at all, or else less of it than has disap- peared in the experiment which produced it : and if this gas contains not only the radical of the muriatic acid, but also all the constituent princij)les of that acid ; as those princi- ples, whatever they are, have a strong tendency to combine, we should conceive that by destroying the etherized ga^ » y fire, without the contact of the air, we shall probably ob- tain the whole quantity of muriatic acid v\hich has disap-- pcared m the c:iOf etherized' gaa, and nearly 250 grammes of acid ought lohave disappeared in the first place, yet all the acid except four grammes rc-ap))eared in the red-hot tube, and carbc to; be dissolved in the two flasks of the apparatus. Thus, of all the suppositions hitherto formed of the mu- riatic acid being a compound body, one only is admissible, which infers that the elements of the muriatic acid exist in the etherized gas combined with the elements of the alco- hol, in the same manner as the elements of water, carbonic acid, ammonia, Sec, exist in vegetable and animal sub- stances. Now if we suppose the muriatic acid to be a simple body, we must then necessarily regard etherized gas as formed of nmriatic acid and alcohol, or of a body con ing from the decomposition of alcohol; for alcohol is perhaps decon)- posed v.'hen we distil it with the muriatic acid. In all cases, the question is thus brought to a choice of the two hypotheses. Let us now try their merits as well as we can. One, namely that which we have last mentioned, prcr S'Mts us with phienomena of difl^cult explanatio:i. In fact, it must be supposed that alcohol, or the body w Inch re- presents it, acts upon the muriatic acid with much more energy than the strongest alkali, since tl^is alkali cannot take On the Muriatic Ether. 1 07 take it off from it, and since, as will ^be subiequently de- jnonstratcd^ the muriate of potash contains less acid than the etherized gas ; and how can we cc-sccive, on the other hand, that the nitrate of silver, which takes up all the mu- riatic acid from the muriate of potash, cannot take it dp from the etherized gaS;, which contains more than the muriate of potash does ? In the other hypothesis, on the contrary, every thing if i^aturally explained. We see the reason why the etherized gas does ncit redden turnsole tincture, and the alkalis do not alter it; why the nitrate of silver produces no precipitate from it; and why, on taking fire, so large a quantity of mu- riatic acid is produced, that it appears in the air. in the forn^ of vapours: — in short, we can reconcile every thing with the phaenomona of other bodies, .nqioiz-jq j:)^! «*Jib ^s =• . . M. Thenard, however, is far from admtttthg t-he^ one and rejecting the other in a decided manner. Both deserve to be investigated ; and whatever happens, the results must be very important, \.i-*.- Not^ Upon the DJscovenj of the Muriatio Ether. . V^iiE'k t'rek^ tlife foregoing memoir' t(1*tWe Ytl'stftute, the "whole of the members, among vvliOmAvei'e'' Messrs. Bcr- ^Jbollet, 'Chaptal, Devoux, Fourcroy, Guj^toh, Vauquelin, Gay-Lussac", he, regarded the results it contained as being cxtremclv novel, and Wlt with the exception of the fusion of the salt, has been pointed out by several chemists. I think myself therefore entitled to conclude, that in Great Britain, as well as in France and Spain, the muriatic ether was unknown, and that, being ignorant of M. Gehlen's labours, I have at least the merit of publishing it. How often does it happen that a discovery is made in one country, which had been known in another long before! and this happens because all learned men do not speak one language, and their works are not always translated. This is the case with M. Gehlen's discovery*. XXIV. Memoirs cf the late Erasmus Dakwin, M.D. [Continued from vul. xxix. p. 339.] . DARWINIANA. In Doctor Darwin's First Class, Ord. I. Gen. 1, irientioning arterial .hre?norrhage, he suggests the breathing an air wiih less of oxygen. In the hcemopioe of arterial bluod,^ he pro- poses, besides the reduced air, making the patient sick by whirling round in a chair suspended by a rope j- actual vo- niitinir, a practice we believe (irst introduced by the I'amous Dr. Willis ; bathing in cold \vattiou with the muria'tic acid and iilcohoi long ago, a-thouj^h he never gave publicity to hi? ex{>€rin3eia'S, because he d d not think they were so complete as they ought to have been. I am proud to have an opportunity of doing justice to M. Boullay. Note by M. TarNARu. -•^^ ^ put no Membhs of Erasinus Darwin, M. D, put up the nostrils ; or a solution of steel iu brandy ap* plied to the vessel by means of lint. Arriving at Gen. ^', mentioning sudor calidus, warni sweat, he has the following curious observations on the use of calico and flannel : *' If an excess of perspiration is induced by warm or stimu- lant clothing, as by wearing flannel in contact with the skin in the summer months, a perpetual febricula is excited, both by the preventing the access of cool air to the skin, and by perpetually goading it by the numerous and hard points of the ends of the wool ; which, when applied to the tender skins of vounp:; children, frequently produce the red gum, as ii is called ; and in grown people, either an erysipelas, or a miliary eruption, attended with fever. ^' Shirts made of cotton or calico stimulate the skin too much by the points of the fibres, though less than flannel ; whence cotton handkerchiefs make the noV-e sore by fre-^ quent use. The fibres of cotton are, I suppose, ten times shorter than those of flax, and the number of points in con- sequence twenty times the number; and though the manu- facturers singe tlicir calicoes on a red-hot iron cylinder, yet I have more than onec seen an erysipelas induced or increas- ed by the stimulus of calico, as well as of flannel. ■ " The increase of perspiration by heat, either of clothes of of fire, contributes much to emaciate the body; as is welf known to jockeys, who, when they are a stone or two too heavy for riding, find the quickest way to lessen their weight is by sweating themselves between blankets in a warm room ; but this likewise is a practice by no means to be recom- mended, as it weakens the system by the excess of so gene- ral a stim.ulus, brings on a premature old age, and shortens the span of life ; as may be further deduced from the quick maturity and shortness of the lives of the inhabi- tants of Hindostan and other tropical climates. " M. Buff on made a curious experiment to show this cir- cumstance. He took a numerous brood of the butterflies oi silkworms, some hundreds of which left their eggs on the same day and hour ; these he divided itito two pareels ; and placing one pared in the soutfi window, and the other in - the Memoirs of Erasmus Darmitf M, D, ill the north window of his house, he observed, that those iu the colder situation hved many (hiys longer than those in the warmer one. From these observations it appears, that the wearing of flannel clothing next the skin, whi<:h is now so much in fashion, however useful it may be in the winter to those who have cold extremities, bad digestions, or ha- bitual coughs, must greatly debilitate them, if worn in the warm months, producing fevers, eruptions, and premature old age." He makes the following ingenious and unfortunately too true observations respecting the diarrhoea infantum, gripes in infants : " Milk is found curdled in the stomachs of all animals, old as well as young, and even ot carnivorous ones, as of havvkft (Spallanzani). And it is the gastric juice of the calf which is employed to curdle milk in the process of making cheese. Milk is the natural food for children, and must curdle in their stomachs previous to digestion ; and as this curdling of the milk destroys a part of the acid juices of the stomach, there is no reasfon for discontinuing the use of it, though it is occasionally ejected in a curdled stale. A child of a week old, which had been taken from the breast of its dying mother, and had by some uncommon error been suffered to take no food but water gruel, became sick and griped iu twenty-four hours, and was convulsed on the second day, at)d died on the third ! When all young quadrupeds, as well as children, have this natural food of n)ilk prepared for them, the analogy is so strong in favour of its salubrity, that a person should have powerful testinxjny indeed of its disagreeing, before he advises the discontinuance of the use of it to young children in health, and much more so iu svckness. The farmers lose many of iheir calves, which arc brought up by grud, or gruel and old milk ; and among the poor children of Derby, who are thus fed, hundreds are Carved Into the scrophula, and either perish, or live in a state of wretched debility. *' When young children are brought up without a breast, they should for the first two months have no food but new Hiilk 3 since the addition of any kind of bread or floiar is liable i\it ^lemoirs of Erasmus Darwin, AT, D, liable W ferment, and produce too much acidity , as appears by the consequent diarrhoea with green dejections and gripes ; the colour is owing to a mixture of acid with the natural quantity of bile, alid the pain to its stimuhis. And they should never be fed as they He upon their backs, as in that posture they are Necessitated to swallow all that is put into Hieir mouths ; but when they are fed as they are sitting up, or raised up, when they have had enough they can permit the rest to run out of their tnouths. This circum- stance is of great importance to the health of those children who arc reared by the spoon, since, if too much food is given them, indigestion, and gripes, and diarrhoea, are the conse- quence; and if too liftlc, they become emaciated ; and of this exact quantity their own palates judge the best." His observations are no less curious rcs^tcUn^ perspirath fcetida, fetid perspiration : ''^ The uses of the perspirable matter are to keep the skin soft and pliant, for the purposes of its easier flexibility du- ring the activity of our limbs in locomotion, and for the preservation of the accuracy of the sense of touch, which is difluscd under the whole surface of it to guard us against the injuries of external bodies ; in the same manner as the se- cretion of tears is designed to preserve the cornea of the eye tnoist, and in consequence transparent : yet has this cu- taneous mucus bet II believed by many to be an excrement ; and I know not h(nv many fanciful theories have been built Qu its supposed obstruction. Such as the origin of catanh^, coughs, inflanmiations, erysipelas, and herpes. " To all these if may be sufficient to answer, that the an- tient Grccian&r oiled themselves all over ; that some nations have painted themselves all over, as the Picts of this island ; that the Hottentots smear themselves all over with grease. And lastly, that many of our own heads at this day are co- vered with the fi(7ur of wheat and the fat of hogs, according to the tyranny of a filthy and wasteful fashion, and all this wiihout inconvenience. To this must be added the strict analogy between the use of the pcr3j)irable matter and the mucous fluids, which are poured for similar purposes upon >all the internal memhrancii of the body; and besides its 3 being Memoirs of Erasmus Darwin, M. D. - 113 'feeing In its natural state inodorous ; which is not so with the other excretions of faeces, or of urine. ^' In some constitutions the perspirable matter of the lungs acquires a disagreeable odour ; in others the axilla, and in others the feet, emit disgustful effluvia ; like the secretions of those glands, which have been called odoriferae ; as those which contain thccastor in the beaver, and those within the rectum of dogs, the mucus of which has been supposed to guard them against the great costiveness which they are liable to in hot summers ; and which has been thought to occasion canine madness; but which, like their white ex- crement, is more probably owing to the deficient secretion of bile. Whether these odoriferous particles attend the perspirable matter in consequence of the increased action of the capillary glands, and can properly be called excremen- titious ; that is, whether any thing is eliminated, which could be hurtful if retained ; or whether they may only con- tain some of the essential oil of the animal ; like the smell which adheres to one's hand on stroking the hides of some dogs ; or like the effluvia, which is left upon the ground, from the feet of men and other creatures ; and is perceptible by the nicer organs of the dogs, which hunt them, may admit of doubt. *^ M. M. Wash the parts twice a day with soap and water ; with lime water; cover the feet with oiled silk socks, which must be washed night and morning. Cover them with charcoal recently made red-hot, and beaten into fine pow- der and sifted, as soon as cold, and kept well corked in a bottle, to be washed off and renewed twice a day. Inter- nally rhubarb grains vi. or viii. every night, so as to procure a stool or two extraordinary every day, and thus by in- creasing one evacuation to decrease another.*' He gives a cure for the tape-worm* ^' The tape-worm is cured by an amalgama of tin and quicksilver, such as is used on the back of looking-glasses ; an ounce should be taken every two hours, till a pound is taken; and then a brisk cathartic, of Glauber's salt two ounces, and common salts one ounce, dissolved in two wine-pints of water, half a pint to be taken every hour till Vol. 30. No, 118. March 1808. H it 11 4 Memoirs of Erasmus Darwin^ M. D» it purges. The worm extends from the stomach to the anuJ^ and the amalgama tears it from the intestine by mechanical pressure, acting upon it the whole way. Electric shocks through the duodenum greatly assist the operation. Large doses of tin in powder. Iron filings in large doses. The powder of fern- root seems to be of no use, as recommended by M. Noufflier.*' He makes the following judicious observations on the cure of the ascarides, or thread- worm : ^^Ascarides are said to be weakened by twenty grains of cinnabar and five of rhubarb taken every night, but not to be cured by this process. As these worms are found only in the rectum, variety of clysters have been recommended. I was informed of a case, where solutions of mercurial oint- ment were used as a clyster every night for a month without success. Clysters of Harrowgate water are recommended^ either of the natural, or of the factitious, as described be- low, which might have a greater proportion of liver of sulphur in it. As the cold air soon destroys them, after they are voided, could clysters of iced water be used with advantage ? or of spirit of wine and water ? or of ether and water ? Might not a piece of candle, about an inch long,, or two such pieces, smeared with mercurial ointment, and introduced into the anus at night, or twice a day, be effec- tual by compressing their nidus, as well as by the poison of the mcircury ? '' The clysters should be large in quantity, that they may pass high in the rectum, as two drams of tobacco boiled a minute in a pint of water. Or, perhaps, what might be still more efficacious and less inconvenient, the smoke of to- bacco injected by a proper apparatus every night, or alter- nate nights, for six or eight weeks. This was long since recommended, I think, by Mr. Turner of Liverpool • and the reason it has not succeeded, I believe to have been owing to the imperfections of the joints of the common apparatus for injecting the smoke of tobacco, so that it did not pass into the intestine, though it was supposed to do so, as I once observed. The smoke should be received from the appa- ratus into a large bladder ; and it may then be certainly in- jected Experiments for investigating , &c, 1 1 5 jetfed like the common clyster with sufficient force; ot^'ef- wise oiled leathers should he nicely put round the joints of the machine, and a wet cloth round the injecting pipe, to prevent the return of the smoke by the sides of it. Clysters of carbonated hydrogen gas, or of other factitious airs, might be triced. ' '' '' Harrowgate water takert into the stonlach, so as to indiifc^ six or seven stools every morning, for four or six weeks, \ji perhaps the most efficacious method in common use. A factitious Harrowgate water may be m^lde probably of greater efficacy than the natural, by dissolving one ounce of marine «alt, (called bay salt,) and half an ounce of magnesia Glau- ber's salt, (called Epsom salt, or bitter purging salt,) in twenty-eight ounces of water. A quarter or half a pint of this is to be taken every hour or two hours in the morning, till it operates, with a tea-spoonful of a solution of liver of sulphur, which is to be made by putting an ounce of hepar sulphuris into ha! fa pint of water." ' [To be continued.] XXV. ExperimeJits for investigalmcf the Cause of the co- loured concentric Rings y discovered by Sir Isaac Newton, hetiveen two Object-glasses laid upon one another. By William Herschel, LLD. F.R.S, ■ ' ' [Continued from p. 90.] XV. Of the sudden Change of the Size and Colour of the Mings in different Sets. Wme^ two sets of rings are viewed vrhich are' dependent upon each other, .th<^ colour of their centres and of all the rings in each set, may be made to undergo a sudden change by the approach of the shadow of the point of a penknife or other opake slender body. To view this phsenomenon pro- perly, let a 16-inch double convex lens be laid upon a piece of looking-glass, and when the contact between them has been made to give the primary set with a black centre, thiat of the secondary will be white." To keep the lens in this H 2 contact. 116 £xperime?itsjbr investigating contact, a pretty heavy plate of lead with a circular hole in it of nearly the diameter of the lens should be laid upon it. The margin of the hole must be tapering, that no obstruc- tion may be made to either the incident or reflected light. When this is properly arranged, bring the third shadow of the penknife upon the primary set, which is that towards the light. The real colours of this and the secondary set will then be seen to the greatest advantage. When the third shadow is advanced till it covers the second set, the second shadow will at the same time fall upon the first set, and the colour of the centres, and of all the rings in both sets, will undergo a sudden transformation from black to white and white to black. * The alternation of the colour is accompanied with a change of size, for as the white rings before the change were of a different diameter from the black ones, these latter, having now assumed a black coloqr, will be of a different size from the former black ones. When the weight is taken from the lens the black con- tact will be changed into some other. In the present ex- periment it happened that the primary set got an orange- coloured centre, and the secondary a green one. The same way of proceeding with the direction of the shadow being then pursued, the orange centre was instantly changed to a green one, while at the same moment the green centre was turned into orange. With a different contact I have had the primary set with a blue centre and the secondary with a deep yellow one; and by bringing the second and third shadows alternately over the primary set, the blue centre was changed to a yellow, and the yellow centre to a blue one ; and all the rings of both sets had their share in the transformation of colour and size. If there are three sets of rings, and the primary set has a black centre, the other two will have a white one ; and when the lowest shadow is made to fall on the third set, the central colour of all the three sets will be suddenly changed, the first from black to white, the other two from white to black. A full explanation of these changes, which at first sight 1 have the Cause of coloured concentric Rings, 1 1 7 have the appearance of a magical delusion^ will be found in a future article. XVI. Of the Course of the Raj/s hj which different Sets of , Rijigs are seen. In order to determine the course of the rays, which giv-e the rings both by reflection and by transmission, we should begin from the place whence the light proceeds that forms them. In figure I, (PI. VI.) we have a plano-convex lens laid upon three slips of glass, under which a metalline mirror is placed. An incident ray, 1,2, is transmitted through the first and second surface of the lens, and comes to the point of contact at 3. Here the rings are formed, and are both reflected and transmitted : they are reflected from the upper surface of the first slip, and pass from 3 to the eye at 4 : they are also transmitted through the first slip of glass from 3 to 5 ,• and at 5 they are again both reflected and transmitted ; reflected from 5 to 6. and transmitted from 5 to 7 ; from 7 they are reflected to 8, and transmitted to 9 ; and lastly they are reflected from 9 to 10. And thus four complete sets of rings will beseen at 4, 6, 8, and 10. The most convenient way of viewing the same rings by transmission, is that which has been mentioned in the se- cond article of this paper, when light is conveyed upwards by reflection. In figure 2, consisting of the same ar^range- ment of glasses as before, the light by which the rings are to be seen comes either from 1, 2, or 3, or from all these places together, and being reflected at 4, 5, and 6, rises up by transmission to the point of contact at 7,' where the rings are formed. Here they are both transmitted up to the eye at 8, and reflected down to 9 ; from 9 they are reflected up to 10, and transmitted down to 11; from 11 they are re- flected to 12, and transmitted to 13; and lastly, from 13 they are reflected to 14 ; so that again four. sets of rings will be seen at 8, 10, 12, and 14. This being a theoretical v/ay of conceiving how the rays of light may produce the effects, it will be required to show by experiments that this is the actual progress of the rays, H 3 and ^^f Experiments /or investigating and that all the sets of rings we perceive are really reflected or transmitted in the manner that has been pointed out ; but as we have so many reflections and transmissions before us, it will be necessary to confine these expressions to one particular signification when they are applied to a set of rings. When the centre of the rings is seen at the point of con- tact, it is a primary set ; and I call it reflected, when the rays which come to that point and form the rings undergo an immediate reflection. But I call it transmitted, when the rays after having formed the rings about the point of contact are immediately transmitted. Th\is in figure 3 and 4 the rays a h c, d ef, give reflected sets of rings j and the rays g h i, k I m, in figure 3 and 6, give transmitted sets. In this denomination, no account is taken of the course of the rays before they come to a, d,. g, k ; nor of what be- comes of them after their arrival at c, f, i, m : they may either come to those places or go from them by one or more transmissions or reflections, as the case may require j .but our donomination will relate only to their course immediately after the formation of the rings between the glasses. The secondary and other dependent sets will also be called reflected or transmitted by the same definition ; and as a set of these rings formed originally by reflection may come to the eye by one or more subsequent transmissions ; or being formed by transmission, may at last be seen by a reflection from some interposed surface, these subsequent transmis- sions or reflections are to be regarded only as convenient ways to get a good sight of them. With this definition in view, and with the assistance of a principle which has already been proved by experiments, we may explain sonie very intricate phaenomena; and the satis- factory manner of accounting for them will establish the truth of the theory relating to the course of rays that has been described. The principle to which I refer is, that when the pressure is such ^s to give a blapk centre to a set of rings seen by reflection^ ihe Cause of coloured concentric Rings, 1 1 9 reflection, the centre of the same set, with the same pres- sure of the ji^lasses, seen by transmission, will be white *. I have only mentioned black and white; but any other alternate colours, which the rings or centres of the two sets; may assume, are included in the same predicament. XVI I. Why two <^n?iected Sets of Rings are of alternate Colours, It has already been shown, when two sets of rings arc seen, that their colours are alternate, and that the approach of the shadow of a penknife will cause a sudden change of them to take place. I shall now prove that this is a very obvious consequence of the course of rays that has been proposed. Let figure 7 and 8 represent the arrangement given in a preceding article, where a 1 6-inch lens was laid upon a looking-glass, and gav€ two sets of rings with cen- tres of different colours : but let figure 7 give them by one set of rays, and figure 8 by another. Then, if the incident rays come in the direction which is represented in figure 7, it is evident that we see the primary set with \U centre at 2 by reflection, and the secondary one at 4 by transmission. Henc€ it follows, in consequence of the admitted principle, that if the contact is such as to give us the primary set with a black centre, the secondary set must have a white one ; and thus the reason of the alternation is explained. But if the rays come as represented in figure 8, we see the primary set by transmission, and the secondary one by reflection ; therefore, with an equal pressure of the glasses, the primary centre must now be white, and the secondary one black. Without being well acquainted with this double course of rays, we shall be liable to frequent mistakes in our estima- tion of the colour of the centres of two sets of rings ; for by a certain position of the light, or of the eye, we may see one set by one light and the other set by the other. XVIir. Of the Cause of the sudden Change of the Colours, Having thus accounted for the alternation of the central • See Article XI. of this Paper. H 4 colours. 120 lExperiments for investigating colours, we may easily conceive that the interposition of the penknife must have an instantaneous effect upon them. When it stops the rays of figure 7, which will happen when its second shadow falls upon the primary set, the rings will then be seen by the rays 1, 2, 3, 4, and 1, 2, 3, 3, 6, of figure 8. When it stops the rays of figure 8, which must happen when the third shadow falls upon the primary set, we then see both sets by the rays 1, 2, 3, and 1, 2, 4, 3, qf figure 7. When the penknife is quite removed both sets of rays will come to the point of contact, and in some respects interfere with each other ; but the strongest of the two, which is generally the direct light of figure 7, will prevail. This affords a complete explanation of all the observed phge- nomena : by the rays of figure 7 the centres will be black and white ; by those of figure 8 they will be white and black ; jmd by both we shall not see the first set so well as when the third shadow being upon it has taken away the rays of figure 8 : indeed we can hardly see the secondary set at all, till the shadow of the penknife has covered either the rays of figure 7 or of figure 8. ,,, As soon as we are a little practised in the managemeht of the rays, by knowing their course, we may change the co- lour so gradually as to have half the centre white while the other half shall still remain black ; and the same may be done with green and orange, or blue and yellow centres. The rings of both sets will also participate in the gradual change ; and thus what has been said of the course of rays in the l6th article will again be confirmed. XIX. Of the Place where the different Sets of Rings are to le seen. By an application of the same course of the rays, we may now also 'determine the situation of the place where the dif- ferent sets of rings are seen : for according to what has been said in the foregoing article, the situation of the primary set should be between the lens and the surface of the looking- glass : and the place of the secondary one at the metalline coaling of the lowest surface. To try whether this be ac- tually as represented, let us substitute a metalline mirror with the Cause of coloured concentric Rings, 121 with a s-lip of glass laid upon it in the room of the piece of looking-glass ; and let there be interposed a short bit of wood, one-tenth of an inch thick, between the slip of glass and the mirror, so as to keep up that end of the slip which is towards the light. . This arrangement is represented in fi- gure 9, where both sets of rays are delineated. Then if we interpose a narrow tapering strip of card, discoloured with japan ink, between the slip of glass and the mirror, so as to cover it at 7, we do not only still perceive the primary set, but see it better than before : which proves that, being situ*- ated above the slip of glass, the card below cannot cover it. If on the contrary we insert the strip of card far enough, that it may at the same time cover the mirror both at 4 and at 7, we shall lose the secondary set; which proves that its aituation was on the face of the mirror. When several sets of rings are to be perceived by the same eye-glass, and they are placed at different distances, a par^ ticular adjustment of it will be required for each set, in order to see it well defined. This will be very sensible when we attempt to see three or four sets, each of them situated lower than the preceding ; for without a previous adjust- ment to the distance of the set intended to be viewed we shall be seldom successful : and this is therefore a corrobo- rating proof of the situation that has been assigned to differ-* pit sets of rings. XX. Of the Connection between different Sets of Rings ^ It will now be easy to explain in what manner different gets of rings are connected, and why they have been called primary and dependent. When the incident rays come to the point of contact and form a set of rings, I call it a pri- mary one : whenT tl\is is formed some of the same rays are continued by transmission or reflection, but modified so as to convey an image of the primary set with opposite colours forward through any number of successive transmissions or reflections : whenever this image comes to the eye, a set of rings will again be seen, which is a dependent one, Many proofs of the dependency of second^ third, and fourth sets 122 Exper'wientsfor investigating sets af rings upon their primary one may be given ; — I shaU onlv mention a few. When two sets of rings are seen by a lens placed upon a looking-glass, the centre of the secondary set will always remain in the same plane with the incident and reflected rays passing through the centre of the primary one. If the point of contact, by tilting is changed, the secondary set will follow the motion of the primary set ; and if the look- ing-glass is turned about, the secondary will be made to describe a ciroie upon that part of the looking-glass which surrounds the primary one as a centre. If there is a defect in the centre or in the rings of the primary set, there will be exactly the same defect in the secondary one ; and if the rays that cause the primary set are eclipsed, both sets will be lost together. If the colour of the primary one is changed, that of the secondary will also undergo its alternate change, and the same thing will hold good of all the dependent rings when three or four sets of them are seen that have the same primary one. The dependency of all the sets on their primary one may also be perceived when we change the obliquity of the inci- dent light ; for the centres of the rings will recede from one another when that is increased and draw together when we lessen it, which may go so far that by an incidence nearly perpendicular we shall bring the dependent sets of rings almost under the primary one. XXI. To account for the Appearance of several Sets of Rings with the same coloured Centres, It has often happened that the colour of the centres of different sets was not what the theory of the alternation of the central colours would have induced me to expect ; I have seen two, three, and even four sets of rings, all of which had a white centre. We are however now sufticiently pre- pared to account for every appearance relating to the colour of rings and their centres. Let an arrangement of glasses be as in figure 9. When this is laid down so as to receive an illumination of day^ li^ht. the Cause of coloured concentric Rings. 123 light, which should not be strong, nor should it be very oblique, the reflection from the mirror will thfen exceed that from the surface of glass ; therefore the primary set will be seen by the rays 6, 7, coming to the mirror at 7, and going through the point of contact in the direction 7, 2, 3 ; which proves it to be a set that is seen by transmission, and it will therefore have a white centre. The rays 1 , 2, 4, passing through the point of contact, will also form a transmitteci set with a white centre, which will be seen when the reflec- tion from 4 to 5 conveys it to the eye. But these two sets have no connection with each other; and as primary sets are independent of all other sets, I have only to prove that this secondary set belongs not to the primary one which is seen, but to another invisible one. This may be done as follows ; Introduce the black strip of card that has been mentioned before, till it covers the mirror at 7 ; this will take away the strong reflection of light which overpowers the feeble illumi-^ nation of the rays 1,2, 3 ; and the real hitherto eclipsed primary set belonging to the secondary one with a white centre, will instantly make its appearance with a black one. We niay alternately withdraw and introduce again the strip of cardj and the centre of the primary set will be as often changed from one colour to its opposite, but the secondary set, not being dependent on the rays 6, 7, will not be in the least affected by the change. If the contact should have been such as to give both sets with orange centres, the introduction of the strip of card will prove that the set which is primary to the other has really a green centre. Another way of destroying the illusion is to expose the same arrangement to a brighter light, and at the same time to increase the obliquity of the angle of incidence : this will give a sufiicient reflection from the surface of the glass to be no longer subject (o the former deceptive appearance ; for now the centre of the primary set will be black, as it pught to be, XXJL Of 184 Experiments for investigating^ XXII. Of the reflecting Surfaces, The rays of light that form rings between glasses must undergo certain modifications by some of the surfaces through which they pass, or from which they are reflected j and to find out the nature of these modifications, it will be necessary to examine which surfaces are efllicient. As we see rings by reflection and also by transmission, I shall be- gin with the most simple, and show experimentally the situation of the surface that reflects, not only the primary, but also the secondary sets of rings. Upon a slip of glass, the lowest surface of which was de- prived of its polish by emery, I laid an object-glass of 21 feet local length, and saw a very complete set of rings. I then put the same glass upon a plain metalline mirror, and saw likewise a set of them. They were consequently not reflect- ed from the lowest surface of the subjacent glass or metal. It will easily be understood, that were we to lay the same object-glass upon a slip of glass emeried on both sides, or upon an unpolished metal, no rings would be seen. It is therefore neither from the first surface of the incumbent ob- ject-glass, nor from its lowest, that they are reflected ; for if they could be formed without the modification of reflec- tion from the upper surface of a subjacent glass or metal, they would still be seen when laid on rough surfaces ; and consequently, the efficient reflecting surface, by which we see primary sets of rings, is that which is immediately un- der the point of contact. To see a secondary set of rings by reflection, is only att inversion of the method of seeing a primary one. For in- stance, when a lens is laid upon a looking-glass, the course of the rays. represented in figure 8, will show that the rays 1, 2, 3, 5, 6, by which a secondary set is seen, are reflected about the point of contact at 3, and that the lowest surface of the incumbent lens is therefore the efficient reflecting one ; and thus it is proved, that in either case of seeing re- flected rings, one of the surfaces that arc joined at the point of contact contributes to their formation by a certain modi- fication of reflection. xxiir. Of the Cause of coloured concentric Rings, IS9 XXITT. Of tlie transmitting Surfaces. .Jt would seem to be almost self-evident, that when a set of rings is seen by transmission, the light which occasions them must come through all the four surfaces of the two glasses which are employed ; and yet it may be shown that this is not necessary. We may, for instance, convey light ii^io the body of the subjacent glass through, its first surface, and let it be reflected within the glass at a proper angle, so that it may come up through the point of contact, and reach the eye, having been transmitted through no more than three surfaces. To prove this I used a small box, blackened on the inside, and covered with a piece of black pasteboard, which had a hole of about half an inch in the middle. Over this hole I laid a slip of glass with a 56-iuch lens upon it ; and viewed a set of rings given by this arrangement very obliquely, that the reflection from the slip of glass might be copious. Then guarding the point of contact between the kns and the slip of glass from the direct incident light, I saw the rings, after the colour of their centre had been changed, by means of an internal reflection from the lowest surface of the slip of glass ; by which it rose up through the point of contact, and formed the primary set of rings, without ha- ving been transmitted through the lowest surface of the sub- jacent glass. The number of transmitted surfaces is there- fore by this experiment reduced to three; but I shall soon have an opportunity of showing that so many are not re- quired for the purpose of forming the rings. XXIV. Of the Action of the first Surface, We have already shown that two sets of rings maybe seen by using a lens laid upon a slip of glass ; in which case, therefore, whether we see the rings by reflection or by trans- mission, no more than four surfaces can be essential to their formation. In the following experiments for investigatinor the action of these surfaces I have preferred metalline reflec- tion, when glass was not required, that the apparatus might be more simple. Upon a plain metalline mirror I laid a doubk convex lens, having 196 Experiments for invesiigating having a strong emery scratch on its upper surface. Wheii I saw the rings through the scratch, they appeared to have; a black mark across them. By tilting the lens, I brought the centre of the rings upon the projection of the scratch, so that the incident hght was obliged to come through the scratch to the ritigs, and the black mark was again visible upon them, but much stronger than before. In neither of the situations were the rings disfigured. The stronger mark was owing to the interception of the incident light ; but when the rings had received their full illumination the mark was weaker, because in the latter case the rings themselves were probably complete, but in the former deficient. I placed a lens that had a very scabrous polish on one side, but was highly polished on the other, upon a metalline mirror. The defective side being uppermost, I did not find that its scabrousness had any distorting effect upon the rings. I splintered off the edge of a plain slip of glass 5 it broke as it usually does with a waving striated, curved slope com- ing to an edge. The splintered part was placed upon H, convex metalline mirror of 2-inch focus, as in figure 10. The irregularity of the striated surface through which the incident ray 1,2, was made to pass had very little effect upon the form of the rings ; the striae appearing only like fine dark lines, with hardly any visible distortion ; but when, by tilting, the returning ray, 2, 3, was also brought over the striated surface, the rings were much disfigured. This ex- "pcrimcnt therefore seems to prove that a very regular refrac- tion of light by the first surface is not necessary ; for though the rings were much disfigured when the returning li^ht came through the splintered defect, this is no more than what must happen to the appearance of every object which is seen through a distorting medium. I laid the convex side of a plano-convex lens 2*8-incIi focus with a diameter of 1*5 upon a plain niirror, and when I saw a set of rings I tilted the lens so as to bring the point of contact to the very ti\gQ of the lens, both towards the Fight and from the 'light, which, on account of the large diameter of the lens, gave a great variety in the angle of incidence to the rays which formed the rings ; but no diffe- rence the C&use of coloured concentric Rings, I2f rence in their size or appearance could be perceived. This seems to prove that no modification of the first surface in which the angle of incidence is concerned, such as refrac- tion and dispersion, has any share in the production of the rings, and that it acts merely by the intromission of light ; and though even this is not without being influenced by a change of the angle, it can only produce a small difference in the brightness of the rings, A more forcible argument, that leads to the same con- clusion, is as follows : Laying down three 54-inch double convex lenses, I placed upon the first the plain side of a plano-convex lens of f inch focus ; upon the second, a plain slip of glass ; and upon the third, the plain side of a plano-concave lens also |- inch focus. I had before tried the same experiment with glasses of a greater focal length, but selected these to strengthen the argument. Then, as nothing could be more different than the refraction of the upper surfaces of these glasses, I examined the three sets of rings that were formed by these three combinations, and found them so perfectly alike that it was not possible to per- ceive any difference in their size and colour. This shows that the first surface of the incumbent glasses merely acts as an inlet to the rays that afterwards form the rings. To confirm the idea that the mere admission of light would be sufficient, T used a slip of glass polished on one side but roughened with emery on the other : this being laid upon a 21 -feet object-glass, I saw a set of rings through the rough surface ; and though they appeared hazy,, they were otherwise complete in figure and colour. The slip of glass when laid in the same manner upon the letters of a book made them appear equally hazy; so that the rings were probably as sharply formed as the letters. Having now already great reason to believe that no modi- fication, that can be given by the first surface to the inci- dent rays of light, is essential to the formation of the rings, I made the following decisive experiment : Upon a small piece of looking-glass I laid half a double convex lens of l6-inches focus, with the fracture exposed to the light, as represented in figure 11. Under the edge of tke 1?8 Experiments for investigating, &c. the perfect part of the lens was put a small lump of wax^ soft enough to allow a gentle pressure to bring the point of contact towards the fractured edge, and to keep it there. In this arrangement it has already been shown that there are two different ways of seeing two sets of rings : by the rays ], 2, 3, we see a primary set; and by 1, 2, 4, 5, the secon- dary set belonging to it : by the rays 6, 7, 2, 3, we' see a different primaiy set ; and by 6, 7, 2, 4, 5, we see its secon- dary one. That this theory is well founded has already been proved ; but if we should have a doubt remaining, the in- terposition of any small opaque object upon the looking- glass near the fracture will instantly stop the latter two sets of rings, and show the alternate colours of the two sets that will then be seen by the rays 1, 2, 3, and 1, 2, 4, 5. Re- move in the next place the stop from the looking-glass, and bring the second shadow of the penknife over the primary set, and there will then only remain the two sets of rings formed by incident rays which come from 6, and which have never passed through the upper surface of the lens. Now, as both sets of rings in this case are completely form- ed by rays transmitted upwards from the coated part of the looking-glass without passing through the first surface of the incumbent lens, the proof that the modifying power of that surface is not required to the formation of the rings is established. It can hardly be supposed that the first surface of the lens should have any concern in the formation of the rings when the rays are reflected from the looking-glass towards the eye; but the same experiment, that has proved that this surface was not required to be used with incident rays, will show that we may do without it when they are on their re- turn. We need only invert the fractured lens, as in figure 3 2, when either the rays 1, 2, 4. 5, or 6, 7, 2, 4, 5, will convey the image of the rings after their formation to the eye without passing through any part of the lens. [To be continued.] xxvr. Ob- JcXVi. Olservations upon Sulphurous Mineral WaterSi \ By M, Westrumb*. jyi. Westhumb has been employed in making researches upon several kinds of sulphurous waters, and latterly upoii those of Eilsen in the county of Schaumbours:. '" ^ ^ One of the most interesting facts he has discovered is, that all sulphurous waters contain a greater or less quantity o£ hydro-sulphuret or hme. In order to ascertain it, he boiled the mineral water ex- cluded from the contact of the air, in order to expel from it the sulphuretted hydrogen gas and the carbonic acid. He afterwards poured into the residue— 1st, Sulphuric acid, which liberated sulphuretted hydro- gen gas from it ; and sulphat of lime was precipitated. 2d, Smoking nitric acid, which separated sulphur from it. 3d, Oxalic acid, which liberated sulphuretted hydrogen gas from it; and oxalate of lime was formed. 4th, The water evaporated with the contact of ^he dlf^ precipitated sulphat of lime; and the sulphuretted hydro^ii gas was liberated. In order to determine rigorously the quantity of the sul- phuretted hydrogen gas and of the carbonic acid, M. West- rumb proceeds in the following manner : — He introduces sulphurous water into a matrass to a certain point, putting a mark upon the level of the liquid ; he adapts a curved tube to it, entering into a long cylinder, which is at one time filled with lime-water, and another time with acetate of lead, with excess of acetic acid. The apparatus being thus arranged and well luted, he boils the water, and continues the ebullition until there is no more gas liberated. In the first experiment it is the carbonat of lime which is precipitated, 20 grains of which correspond to ten cubic inches of carbonic acid; and in the second case it is oxidated hydro-sulphuret of lead, 19 grains of which indicate ten cubic inches of sulphuretted hydrogen gas. * From M. Gehl^n's new Journal of Chemistry, vol. v. Vol. 30. No. 1 1 8. March 1 808. I Another iSO Ohservatiojis vpon Sulphurous Mineral IVatcrs, Another observation equally remarkable concerns the suvT- phtirettcd hydrogen gas. M. Ginibernatj a Spanish chemist, has asserted, that the hot springs of Aix-la-Chapelle contain sulphuretted azotic gas, — M. Schaub attempted to extract it from the sulphu- rous waters of Nenndorf in Hesse. The following charac- ters have been attributed to this gas : — 1st, A smell similar to the sulphuretted hydrogen gas; 2d, Being indecomposa- ole by the carbonic acid gas ; 3d, Not being inflammable ; ♦Jth, Being improper for supporting an inflamed body ; 5th, Being indecomposable by the nitrous gas ; 6ih, Being de- composed by the concentrated nitric acid, which separates sulphur from it; Jth, Decomposing the metallic solutions, and forming sulphurets ; 8th, Having a great affinity for water, from which it cannot be separated, except by long ebullition. But M. Westrumb has found that when we wash sul- phuretted hydrogen gas with lime-water, or when we pass a current pf this gas through slaked lime, it acquires all th^ above properties. Whether the sulphuretted hydrogen gas be obtained from sulphurous waters, or be prepared in any other way in use, the same phaenomena take place. On bringing back t!ie lime-water by an acid, sulphuretted hydrogen gas is liberated, which is inflanniiable, and which possesses its ordinary properties. Sulphuretted azotic gas is therefore a product of the ope- ration. M. Westrumb does not yet know if this new gas be pro- duced by the action of quick-lime upon sulphuretted hydra- gen o-as, or if this substance does not contain sulphuretted azote. Lastly, a third observatron not less interesting Is the pre- sence of carbon aiid carbonated substances in the sulphu- rous mineral waters. ' ":M. Westrumb has discovered a new principle In them-^ 0, fetid resin of sidpfnir, (Stlnkendes schwefelharz.) In order to obtain it, we must evaporate the sulphurous -^ater excluded froui fhe contact of the air, and afterwards take Otservdtions Upon Sulphurous Mineral Waters* 131 tJp the residue by alcohol, which dissolves this resin more X{\k\\ the earthy niuriates. By the evaporation of the alco- holic liquid, the substance at first looks like a yellowish fat, it it successively coloured brown, and becomes resinous. By repeated solutions in alcohol, and by evaporations, it is decomposexl into sulphur, and into a' resin of a blackish- brown. It has a garlic smell, which becomes very strong, and si- milar to assafcetida, when we pour water into the alcoholic solution. Its solution acts like an acid. Its tcsin is dissolved in ammonia, and communicates a yellow colour to it; the liquor acts like that of Beguin. With lime-water wc obtain a hydro-sulphuret. All these solutions act upon the metallic combinations like sulphuret- ted hydrogen. As sulphurous mineral waters have their orFgin in beds of pi't-coal, we might perhaps find the source of this bitu- minous principle in pit-coal itself. Around the baths of Eilsen,- like those of St. Amand, there is accumulated a kind of crust, which gradually be- comes of a dark colour, and latterly black. By analysis, there have been extracted from it sulphuretted- fetid resin, hydrq-sulphuret of lime, sulphur, lime, alu- mine, magnesia, charcoal, and sand, with some fibrous substances, a little sulphuretted hy.drogen gas, and car- bonic acid gas. Whatever be the origin of the bituminous principle in sulphurous waters, M. Westrumb succeeded in producing charcoal and fetid resin, by employing sulphur perfectly pure. For this purpose he digested sulphur precipitated by an acid in alcohol. By distilling the alcoholic liquor, there i.* separated yellow crystalline sulphur, or a yejlovvish gray powder : the fetid resin is then completely formed in the liquor floating above, and possessing all the above proper- ties. We might attribute its formation to the presence of the alcohol, and dfortioriy because, softer its separation- fiv)m the i^O .1!///:, I 2 residue 132 Olservations tcpon Sulphurous Mineral IFaters. residue of the evaporated sulphurous water, the penetrating arnell is manifested, when it is taken up by the alcohol. But several observations lead M. Westrumb to think that the alcohol does not contribute to the formation, and that it rather derives its origin from the sulphur itself. Letter ofM^RoLOFF, of Magdehourg, upon the foregoing Suljj^ct^, I HAVE recently recognised in an unexpected manner the sulphuretted fetid resin of M. Westrumb. M. Michaelis, after having precipitated the golden gul- phat of the hydrogenated sulphuret of antimoniated potash, evaporated the liquor floating above containing the sulphat of potash. ' When the ley began to concentrate, a vapour was deve- loped, which very much embarrassed the artist who was stirring the mass. There was at the same time manifested an insupportable smell, analogous to that of burnt assa- foetida. The saline mass evaporated to dryness had a gray colour, and the remarkable smell we have mentioned. It was put in digestion with alcohol, which acquired the taste and smell of garlic. The alcoholic liquor evaporated spontaneously, yielded a gray gluey rar.ss, possessing the same smell and taste, I am desirous that this experiment should be made pub- lic, not knowing if M. Westrumb is acquainted with the' formation of a large quantity of fetid resin which may be easily procured by this process. As the smell is mainifested before putting in the alcohol, we may conclude, with M. Westrumb, that the alcohol does not contribute to its formation. ■ "* From Gehlen's cevv Journal of Chemistry. XXVII. On XXVII. O/z the Preparation of CalomeL r j^j i>y Mr. Joseph Jewel. 'In our last number, page 93, we mentioned that Messrs. Howard and Co. had introduced an important improvement in the preparation of this essential article of the pharmaco- poeia. It is the discovery of Mr. Joseph Jewel, one of the partners, who gives the following specification of his in- vention, for which he has taken out a patent : __„ - '^ Calomel, or mercurlus dulcis, as usually prepared, is at first a hard crystalline substance, and requires to be pounded and triturated with water, either in a mortar or on a slab with a muller, or in a mill. After having been ground or triturated for a considerable time, more water is added, and the whole well stirred up. The finer particles, which remain suspended for a short time, being poured off with the water into another vessel, and left to subside, the water is then decanted, and the fine powder dried for use. The coarser particles arc again submitted to the operation of grinding and washing ovcr^, until the whole be finished. Now the nature of my invention is to produce the effect of the grinding or trituration above described, in a more per- fect manner, during the last sublimation of the calomel ; which I do as follows : ■ '' *^ ''■"^'*' o *' I take calomel, or mercurius dulcis, broken into small pieces, and put into an earthen crucible of the form of a long barrel, so as to fill about one half thereof. I place the crucible on its side in a furnace provided with an opening, through which the mouth "of the crucible projects about an inch. I then join to the mouth of the crucible an earthen- ware receiver, having an opening at its side to receive ihe open end of the crucible. This receiver is about half" filled with water. I lute the joint with a mixture of sand and pipe-clay. The receiver has a cover, v/hich cover has a side continui'd upwards for containing water, with a chimncv or tube in it, to allow the escape of steam from the water be- low. I then apply a fire around the crucible, sumcient to rai^e the calomel in vapour, and force it through the mouih .of the .crucible into the receiver; v. here, by the water,* ^^ J 3 while 134 On ike Cknitractiorl which takes place in Mercury while cold, or assisted by the steam when it tjecomes hot, it is instantly condensed into an impalpable powder, pos- sessing all the qualities of calomel in its most perfect state. The calomel, when thus prepared, is purer, whiter, and more attenuated, than that obtained by grinding. It is proper to wash the product over with water, before it is dried, to rid it of any coarser particles which n^ay forip about the mouth of the crucible. XXVIII. On the Contraction which takes place in Merciiry at low Temperatures by, Ahstrcctlon of Heat ; — and on the JRatio of Contraction between Mercury, Alcohol, Water^ and Silver. By John Biddle, Esq, of Birmingham, Birmingham!!, Fp]t)ruary, 1808. To Mr, TiMoch, SIR, -^ LETTER frorri M. Tardy de la Brossy, dated Joyeuse, (Ardeche) October 13th, 1805, addressed to Professor Pictet, of Geneva, has appeared in your M.'^gazine [vol.xxiv. p. 322] . It contains observations on some experirncnts which I had the pleasure of showing to the Philosophical Society here on the specific gravity of mercury in its frozen state, which experi- inents were communicated to. the public through the me- dium of Mr. Nicholson's Journal for April 1805. The observations of M. Tardy de la Brassy have induced me tp look over the original papers, containing the results of those experiments, with som^. atUntion; and, with deference to the opinions of that gentleman (though I fc^ar spme in- accuracy exists), I must, in defence of my experiments ge- nerally, and the deductions piade from them, request you to commvmicate a fe\v experiments and olpservations through the channel of your Magazine. M. Tardy dc la Brossy, after a^vowing tb^ object of his communication to be *' the extension of truth, and the re- moval of error,**, proceeds to describe the result of some of mv former experiments, and to make his obscpvations on iny calculations trom them, to which I wpuld refer; but if " ' , ' ' ' ' - ^ at low Temperatures, 135 he had added experiment to his calculations, he would have been convinced that the principles on which I proceeded are just, and that one source of difference in our opinions arises from the partial application of the mode of reasoning which he uses. For, admitting with him the specific gravi- ty of the alcohol employed to be '810 nearly, or -814 1 where water is 1*000, and that 1000 grains of mercury would exhihi^ ^lossofweiglit in alcohol of the temperature stated, of 39*8, when weighed by the hydrostatic balance, vet it does not ap- pear to me necessary to suppose, a priori, so long as each of these substances remains in a fluid state, that the ratio of their densities should differ when uniformly subjecicd to the lower degrees of heat. As, however, my fornier experiments were not made with a view to discover the contraction of the volume of the alcohol, I made no observation relating to it, and now think it right to investigate the subject by experiment. A. I first distilled mercury as before, with great care, using only that 30 per cent, of the whole which first came over in the distillation, esteeming it the most pure. I found, by the hydrostatic balance, the specific gravity of this to be- 13*613, as 1000 grains lost in distilled water 73*4 at the tem- perature 50 of Fahrenheit's scale. B. I took alcohol frou) the same parcel which I had used in my former experiments, and filling a light glass bottle formed with a long narrow neck for the purpose, it was lound to weigh 'SMI, when water weighed- 1 -000 at the tempera- ture of 48° nearly. C. Having obtained a mass of very pure silver, procured from luna cornea, 1000 gr. lost in distilled water 07s, the specific gravity of which was thereby found to be 10'225; but bv hamn)ering it into a form convenient for mv purpose the specific gravity increased to ]0'3C)'-2, the loss of ut-iohf Ut'in^ {)Cy9 at 30® of temperature. At the following tempera- tures the variations of loss of weight- are expressed in the second column, the conseht Specific gi'aviiY of siKcr whrn water is 1-000. Loss of v.'ci<;-hl according to Fahrenheit's scale. of 1000 p-. of .'ilveria distil! eu water. oflOOOj,rr,o/sii- ver weighed in alcohol. 200 94 10-63S 185 9^-4 10-593 173 94-6 10-5/0 158 95''2 10-504 150 95-3 10'4y3 130 95-5 10-471 75-4 302 95-9 10-42S 76-2 80 96-3 10-334 77-6 66 96-4 10-373 78-5 55 06-4 10-373 50 96-3 10-362 78-0 34 965 10-362 79-4 21 — : 60 9 — 80-5 0 — -^ 81 20 — 81-6 32 — ; .82-5 5\ — 83 5Q — 83-1 D. By the following experiments I then proceeded tQ ascertain the specific gravity of mercury and silver at various temperatures, from 1 00'^ above zero to more than 40° below it, with a wish to obtain a ratio of contraction between mer- cury and silver, and between eacVi of the§e and alcohol. For this purpose two hydrostatic balances were so placed that the metals suspended from thern might fall into a glass vessel containing alcohol. I then attached 1000 grains of silver to one balance, by a wire 12 inches long, weighing only iV ^^ ^ grain; and to the other 1000 grains of. mercury, in a small glas^i bucket weio;hing lOl-jSg. grains, suspended by a wire nearly 4 inches long, weighing y^- grain. Then also suspending in the alcohol a good thermometer, marke4 '*.■ ••• V <1^ low Tejnperatures, "^^^ ^^ 187 marked for low temperatures, and having provided a quan- tity of murij^te of lime and snow, I reduced the temperature of the alcohol and metals, as in my former experiments the subject of M. Tardy de la Brossy's observations, and ob- tained the results expressed in the following table. ' 2 ■^' 1 4 5 6 7 ' ^ — ^ ■*.,_ — U- 4J ^i C O ,3 3 a< o •- i a, O u o U o ^ 2 ^ \ ^-■o S^ «^-§s ^-^J «?^ >^'%9 " o ^ .xz-7. 8 ^ //> — ^ u to ^ 0) .- tj h 1 pecific grav Ivcr if theal oes notincre ensity. 1 ^11 I if o '-i ^ '-' ;■« •5 ""To • o5 g2-2 . 1 11 il CO -^ •:;-rJ J -. & ^ J2 h 5^ -;^ ^^ -,-5 rt - H^ b cfi c-o.S 1(V6B0 76-2 100 82-6 24-3 58-3 13-963 10-318 77-4 60 85-0 25-3 59-7 13-63t> 10-36:2 78-56 50 85-3 25-3 59-8 13-613 10-359 78 3 44 85-5 25-6 59-9 13-589 10-208 79-7 20 86-6 ^C) 60-6 13*433 10' £90 79-9 6 or 7 86-7 26-1 60-6 13-433 10*037 81-1 0 86-9 26-2 60-7 13-411 In an examination of the 1st and 2d columns of this table relating to silver, it being previously known that 10*362 is the specific gravity of silver, and that -8141 is ihe specific gravity of alcohol at 50^ of Fahrenheit, where watej^ \s !-000, it appears, following the general mode of calcu- lation in which the loss of weight is made the divisor pf the quantify weighed, and the quotient expresses the specific gravity, thai as at 100 degrees of heat the divisor for the quantity of metal is less, apd at zero greater, that at zero the specific gravity is less, and at 100 degrees above it the specific graviiy is greater : — A conclusion opposing a general law, which therefore we cannot admit. 'I'o account for this apparent inaccuracy of result, we must direct, our attention to the alcohol employed, and see if, in the comparison of the /?//./"(y alcohol and the solid gilver, this appearance of contradiction to an established law does not arise from the contraction of the fiuid. Of this it will be ditficidt to bring visible proof to the extent required; tor if I put into a glass tube alcphol, of wljich the weight is known. 138 Oft the Contraction which takes place in Mercury known, and expose it to dificrent temperatures from 100 to 50 degrees, it will contract ; but whilst the fluid con- tracts, the glass which contains it contracts also, and shows only the difference of the contraction between the fluid and glass : — however, as we know that silver by hcatiniir cannot become specifically heavier, or by cooling specifically lighter, in these experiments which are evidently a coniparison of densities, the alcohol mu»t become more dense by depriva- tion of heat. The third column of this table contains the temperatures. In the 4th column the 1000 gr. of mercury and the glass bucket containing it appear together to have varied at the two extremes in loss of weight 4-3. By the 5th column it is shown that the glass bucket alone varied at the two extremes in loss of weight rg. By the 6th column it appears that 2*4 only can be stated to belong indispensably to a variation of the respective den- sities of the mercury and alcohol in the changes of tem- perature from 100° to zero. The other variations, J presume, arise from some inaccuracy, such as making the observa- tions when the fluids w^re at different temperatures. By the 7th column are shown the different gijiccific gravi- ties of the mercury, by calculation from the loss of weight, supposing the density of the alcohol the same throughout : f;om this it appears that the density of mercury is greatest at the highest temperature, and least at the lowest ; but as this cannot be actually the case, it is obvious that the alcohol increases in density ; and this appears also from the results of the 2d column relating to. silver, at C. For the specific gravities or alcohol at various tempera- tures, 1 must refer to the calculations at L, made from the following experiments, and which are contained also '\\\ a general table of results. E. I procured the bladder of a rabbit, and washed it well with alcohol. It weighed 7 grains in air; and having an- nealed a wire about 9 inches long, the weight of wliicli was -,«f,lhsof a'grain in air, I found that 'the bladder and wire, when sunk in alcohol to a certain mark on ilie wire, weighed 2'5 grains only, at tlic temperature Ab^, 4 This at low Temperatures, 139 This bladder was filled with mercury, not quite pure, then suspended by the wire 5 and when one end of the wire was attached to the balance, it was found to contain 5276 grains; weighed in alcohol, it lost 321*5, from which de- ducting the weight of the bladder and wire in alcohol, 2-5, it appears that the loss of the 5276 grains of mercury, whea rhe thermometer is suspended in the alcohol at 45° of temperature, is SI 9 93 -^ — 100 — — J12 — — 118 — — 125 — ^ 130 — ^^ \ 135 ... .^ 130 -r- -r- 125 -r- ^ 123, r— — 120 — «^ 118 — — 117 -^ -r- 113 — — 111 ^ — |08 — -r- 104 T- — 100 r- •— 97 — — 93 — — ey — — 85, r- — 83 — — 80 — — 78 — — 76 — — ^ 7Q — — $8 ^ ^ 315 le ss by 4 312 — 7 311 — 8 309 — 10 308 — 11 307 — 12 306-5 S06 306-5 — 12-5 rThe alcohol now in 1 q J agitation by the heat "^S could make nohigher (^observation. 12-5 307 — 12 307-5 — 11-5 308 — 11 308-5 — 10-5 309 — 10 309-5 — 9-3 310 — 9 310-5 — 8-5 314 — 8 ^ 311-5 — 7-5 •> 312 — 7 312-5 — 6-5 313 — 6 313-5 — 5-5 » 314 — 5 • f 315 — 4 316 — 3 ,: 317 — 2 317-5 — 1-5 2\U -r- X . i 140 On the Contraction which takes place in Mercury at 65 the mercury loses 318'5 less by 0-5 62 — — 3iy _ 0 50 — — 320 more by 1 45 — ., — 320-5 — 1-5 40 — — 321 — 2 36 — — 321-5 — 2-5 ^4 — — 322 — 3 27 — — 323-5 — 4-5 14 — — 324 — 5 5 ^ — 324-5 -— 5-5 O — — 325-5 — 6-5 5 below zero 326*5 — 7*5 J8 — — 327-5 — 8-5 21 — — 328 — 9 We may observe in this experiment that some difference is cJccasioned by the direction in which the heat passes, whether from without to the alcoliol, and thence to the mercury, as in the first part of these observations from 45® to 135^; or from within from the mercury to the al- cohol, as from 135^ lo zero and 21'' below : and it appears that the temperature was not the same in these two fluids when the observations were made j for when I weighed the same mercury with a hole in the bladder to introduce the bulb of a thermometer, that I might observe the variation of loss of weight when the alcohol and mercury were at the same temperature exactly, it showed the mean of these va- riations to be correct. So that in comparing 52/6 parts of mercury with alcohol, there is a variation in the contraction of these two fluids expressed by 22 of loss of weight in passing through 156 degrees of temperature. In comparing 1000 parts of mercury with alcohol, it follow:^ that there is a variation of loss of weight in 156 degrees of temperature expressed by 4' 17, which shows -0267 is the loss of alcohol in each degree greater than that of mercury. If Uiese two fluids were to contract by deprivation of heat in the ratio of their specific gravities, it is obvious tliat the Joss of weight shown by the hydrostatic balance would be the same throujih all the changes of temperature, the changes Ibting the &amc in both fluids at the lime of obscrvatfon. It at hid Temper aturei, ^ 141 It is therefore of matcFial consequence to this inquiry to know in what degree equal bulks of mercury and alcohol increase together, without the hydrostatic balance denoting the alterauon by any change of loss of weighty for this purpose we must look to D, and forward to the experiment G, and the calculations from them at L and \, where we shall find a rule for discovering the specific gravity of al- cohol. F. To find the proportion of contraction between mercury and water, I took 3024 grains of mercury in a bladder, as before ; and weighing it in distilled water by the hydrostatic balance, the mercury and water heated to the temperature 200themercuryIost2i7-4i:t.Tun:Si:fT^™! 193 *— 217-6 ( ^thewaterhavingrisen ^90 185 — 217*8^ in vapour and con- densed on the balance. ■ — 218 1 80 — 218-2 175 — 218-4 170 — 218-6 J 165 — 218-8 160 — 219-1 135 — 219*4 150 — 219*7 145 — 220 133 — 220-3 130 — 220-4 123 — • 220-5 120 — 220-6 110 — 220-8 98 — • 221-1 88 — , 221-3 78 — 221-5 ^8 — 221-7 " 5^ — 221-9 50 — $22-1 Thus, at 200° of temperature mercury would appear of greater specific gravity than when- at 50°, following the general mode of calculation; but if we suppose the water is more i contractejl 142 On the Caiitr action which takes place in MercunJ contracted than mercury by abstraction of treat, and attri- bute to that the difference of loss of weight, then, in com- paring 30i24 of mercury with water, there is a variation in the contraction of these two fluids expressed by 4*7 loss of weight in passing through 150 degrees of temperature. In comparing 1000 of mercury with water, a variation of loss in 150* is expressed by l'554i?. G. The following experiment was made before many of my philosophical friends with mercurv, described before, of the specific gravity of 13*613, suspended by a very fine wire 10 inches long, weighing only ^V of a grain ; — the baro- meter standing at 29*8, the thermometer at 35. 1000 grains of mercury with 750 grains of alcohol, as be- fore described, were put into a thiri glass vest^el, made for the purpose, round at the bottom, and increasing in diameter gradually to near the top, so that the mercury might l«e easily suspended in the alcohol by a wire introduced into it whilst fluid. These were placed in the centre of a mix- ture of 4 pounds of snow and 4 pounds of muriate of lime, at If o'clock at noon : at 5 minutes past a thermometer placed in the frigorific mixture fell to 5^° below zero, then to 54 and to 60. The mercury in the tube of the thermome- ter appeared frozen : it was withdrawn, and when exposed to the air a few seconds, suddenly fell to 140*^ on the scale, in consequence of the mercury in the tube again becoming fluid, and occupying the vacuum which had been occasioned by the contraction of the mercury in the bulb after that which was in the tube had become solid : it was then immediately returned to its place in the mixture of snow and nmriate of lime ; it had remained at 1 40° for several minutes when taken out and exposed to the air, so that the mercury still in the tube was airain made fluid j it instantaneously sunk into the bulb much below 270^, the lowest point on the scale. During this time the mercury and alcohol, very much reduced in temperature, were removed from the above mixture^ and placed in a second mixture of 3 pounds of snow and 3 pounds of muriate of lime : the whole was then placed in the first mixture; and at the moment of the crystallization of the mercury, the wire, already partly attached, was by raising at low Temperatures. 143 raising It gently, drawn from the side to the centre of the surface of' the mercury. When it was fixed and the whole was solid, it became necessary to withdraw the glass, and expose it a moment to the air of the room, until that paj-t of the mercury attached to the glasswas softened; then, by keeping one hand drawing gently at the wire, the whole oF the mercury was suspended, and, with the al- cohol, immediately returned to its place in the cooling mixture ; the mercury was now suspended from the hydro- static balance by the wire fixed in it, and weighed with great, accuracy ; — and the following observations were made from ; the time the second quantities of muriate of lime and snow were lilixcd. In 5 minutes the mercury was crystallizing. JO became nearly solid. 30 quite solid — withdrawn. 40 ^ having been replaced. 50 suspended in the alcohol, and weighed by the hydrostatic balance with great care, lost 60-8 6o minutes the mercury and alcohol having been a little withdrawn, the mercury lost 6o 85 minutes the mercury lost 59*9 it was now so nearly fluid, there was splendour on the surface. 130 minutes the mercury lost 60*8 1)5 CO-3 150 60-1 160 CO-3 ( having been withdrawn, 1 70 • ■ ■ ■ ■ ' ■ 60* 1 ^ and the temperacureia*- ^ crease^. 175 — 60-r 180 61 As I could not decrease the heat so as to indicate a greater loss than 6 1 , and my own body dufing these three hours having suffered an unusual and partial deprivation of heat, I withdrew the mercury and alcohol, not doubting, if it could have at^- swert^d any purpose, by these means to have been able to have kept the mercury solid some hours longer, the sur- rounding substances having lost so much heat. AVe see from the observations made in this expepimootj that 5U-9 144 On the Contraction which takes place in Mercury 59*9 is the least diminution in the weight of mercury when weighed in a solid state in alcohol, and that it is at this moment when their spccific'iiraviliesare furthest from each other; for we may observe that at ahiiost the next degree of temperature to that ill which the mfrcury loses its fluidity, v;hilst the alcohol preserves its fluid form, the mercury appears to become of less specific gravity, as it loses 60; which gives, according to calculation at L, only 11 ; but the fact appears to me to be, that alcohol proceeds m the ratio of a fluid by decrease of temperature, and that mercury, having obtained a solid form, follows the ratio of contraction of a solid ; therefore their densities approach each other. I should have ascribed this greater loss of weight to the particles of the mercury at •the moment of .crystallization occupying, in consequence of their new arrangement, more space than at the moment be- fore it became solid, as with some of the metals is known to be the case, had I not carefully observed the passage of this metal in other experiments, where I had an opportunity of seeing the contraction proceed very distinctly; and had not the mercury, also proceeding to still lower temperatures, lost from €0, 60-1, 60-3, GOT, 60-8, and 6l, long after the whole had becoire solid, and was suspended by the wire : thus, 61 is the greatest diminution of weight by the abstrac- tion of heat which I could obtain, and I am of opinion that the space described by these changes of loss of weight demotes a. rangeofmany degrees of temperature: how much greater the density may then be than that stated at L, I cannot presume to say ; but as it takes, with some probability, a proportion of contraction approaching to that of silver, it certainly appears improbable thai it should reach the specific gravityvvhich my former calculation Irom a single observation led me to at- tribute to it. I am therefore inclined to believe there was some inaccuracy in weighing the silver by the hydrostatic balance, when by my former cxjKTiments I gave S8'I, the quantity of loss of ICOO gr. of silver: — from many observa- tions in this laborious train of inquiry, it seems hardly possible that the former could have been correct; for if the alcohol and silvercontinuedto contract inthe samcproportionfrom56°be- low zero,as they do from64"aboYe zero to that temperature, it would appear that an abstraction of heat must necessarily have taken ..^50.^ ^^^ .^ ^^ femperaium. ^ ^^ ^^ lii' tlkert pladi equal to 1^5^ mdre, o/'tpl 76^ below zero, which I can hardly suppose, though the mercurial thermo- meter used in these experiments fell lower than 270^* below zero. If my former statement be erroneous^ it cer-' tainly is not attributable to the mode of calculation, as ap- prehended by M. Tardy de la Brossy. As it does not appear that he had made any experiment on the subject, he could not have anticipated this inaccuracy in the weight of silver: and as he says that only a few grains of the increased gra- vity of the mercury was attributable to the alcohol, he could not be aware of the great increase of the specific gravity of alcohol shown at I, by the same mode of calculation used' in my essay, the subject of his animadversions. "-'"^ It is still, however, obvious, that mercury would not be of the specific gravity which I attributed to it, unless it had followed the same rate of contraction after it became solid a^ it did whilst fluid : tiie evidence of the increased loss of weight'' is so much against me, that I cannot defend that experi- ment; and I would now be understood to carry my observa- tions on the specific gravity of mercery, with accuracy, t'or tbe point of congelation only; or to slate that near 56^ be- low zero its specific gravity is 14*465, as by calculation at L, Then, if we attribute to mercury in a solid state nearly' double the contraction of silver as at H, or '00100 in each degree, as it is near to its point of fluidity, we shall arrive only at the specific gravity 14*483, as is shown at M. To ascertain whether the silver at C, with which I pro- posed to compare the mercury, had expanded or contracted by the deprivation of heat to which it had been exposed, H — I took an ingot of silver, \6 inches long, 2 inches wide, and half an inch thick, weighing nearly 100 ounces; and provided an instrument for the purpose of measuring accurately the contraction and expansion of the silver, by fixing in a piece of well baked wood two centre pins, exactly 15 inches from each other, one of them very find, for the purpose of striking an arch of a. circle on the surface of the silver, when the other was fixeld in a perforation made in the silver by the centre itself. Then, on the surface of the bar of silver, heated to a pale red, an arch was described with V^ol, 30. No. U8. March 1808. K this 14-6 On the Contract io?i irh'icJi lakes plfce in Mercury this instruynent; and. when again reduced to the temperature o]F50 degrees, another arch was drawn : — the contraction of th^eiar of silver hetween the two points appeared to equal •Birth part of its dimensions. T ,1' I he silver wag then heated to 2CjQ*' of temperature of^ Fahrenheit's. ^sc^Tile, by boiling it in \vater, and gradually coplmg; an, arch of a circle was then struck on the surface of _ the silver :, reducing it to 150^ of temperature, another arch was struck with the same unvaried centre pins, which Showed evident contraction in the bar of silver: agaip, at 100° of temperature another arch was described ; and a fourth, at 50^ showed that the silver had contracted in the deprivation of 15(^^ of temperature -g-i^jth part of its length. _ Tlien, similar parallelopipedbns being to each other as the ciibes of their homologous sides, the increased specific gra- vity, is shown "by multiplying the specific gravity at 50% namely, 10'362, by the cube of v^41; and dividing it by, the cube of 340^ which equals 10-4537; '0917, therefore, is the difference \p.^ 150^ of heatj or '90061 14 is the contrac- tion of silver in each degree; which, from the way this ex- periment is perfqrnied, I call its visible contraction. From it .the specific, gravities at the several' temperatures below are calculated ; — /,„ At 200 _ silver is oi the speciijc gravity ] 0*2702; , , V^P/o 1, ■ 10-3908 135 10-3100 117 . 10-3210 100 \ 10-3314 j^"5p.^^ / , 10-3620 ,' "of' 10-3925 50 below zero 10-4231 52 — . 10-4243 56 10-4268 I. Then, if 10-4268 be the specific gravity of silver at 56^ below zero, and weighed in alcohol at that temperature, by. calculation from its loss of weight at C, it will appear tgi be 9*796; by taking '8141 as the supposed density of al- •cphol,, dividing the quantity 1000 by the loss 83-1, multi- plying]; the quotient l£-033 by '81 41 ^ and dividing by 1-000, the :-m'>ts\'l^ K\ at do0^ Temperatures* - mO«^Vj^ 147 the specific gravity df-vv^ei-,^ the result bf this being 9'796; What then is the speelfic gi-mity of the dicohol — if not 8141? ^ It is fbun(l|Vtl^i?:ru)e,;~ Divide 1000, the quantity weighed, by the loss of weight, and by the quotient divide the density of silver, according to its visible qontll^elion ; the quotient will be the specific gravity of the alcohol, or fluid in which it is weighed. ».Xhus,at the temperature 56' below zero, ihc loss of weight i#3i^*;l ) by whic));,t itrrJiOOO (the quantity weighed) be di- vided, tl\e quotient is l^-OSS, by which 10-4268 (ihe density ^f silver, according to its visible contraction) is divided ; and tl?^t^otient is '8665, the specific gravity of the alcohol at 56^ below zero. Thus, -0524 is the sum of variation of the speciiic gravity of alcohol in 106% or 00049434 is the varia- tip4j in each degree of temperature : from it the specific grfiyities at these N^everal temperatures are calculated. At 135^ the specific gravity of alcohol is -77208 >iJ} i: 117 -78098 j^EBp 100 — 4l-^c^ -78938 ' 50 •' : ■ '" -81410 zero — -83882 50 below zero -66353 52 ■ -86482 56 -86650 K. Then taking the specific gravity of the alcohol at anv certain temperature, and the loss expressed at C ; What will be the specific gravity of the silver according to C ? It is found by this rule : — Divide 1000 (the quantity weighed) by the loss of weight, and multiply the qudtient by the specific gravity of the al- cohol or fluid in which it is weighed. Thus, at 5Q^ below zero the loss of weight is 63-1, ac- cording to C ; by which if 1000 be divided, the quotient is 12*0337 ; which, multiplied by "8665, the density of alco- hol, as at I, in that temperature the product is 10-427, the specific gravity of silver at 5Q' below zero. Then, having ascertained the specific gravity of silver and K2 of I4t On the Contraction ivJdch takes place hi Mercunj of alcohol at several points of the scale 6f temperature by calculations at I, from ej^pcriments at H, the calculation of ihe-spt'ct/Ic gravity of mercury is thus perforjiied : — L. — Divide the quantity by the loss, and multiply the quotient by the specific gravity of the alcohol at such tem- perature. Thus, mercury at G, in the temperature of 56^ below zero, appears to be of the specific gravity 14-465. For divi- ding 1000 by 59*9, the least loss in the solid state, and mul- tiplying the quotient 16'694 by *S665, the specific gravity of alcohol at that temperature^ the product is 14*465. Then if mercury in 106% from 50^ above to Gb'^ below zero, increases in specific gravity from 13*613 to 14*465, namely *852, which gives *O0SO4 each degree; this sum, multiplied into the number of degrees from 50^ above zero, gives the specific gravity of mercury at that degree, if de- ducted when above 50 from 13*613, or added to the same when below 50^. Thus at ISS'' above zero, which from 50° is 85% if the sum *00804 be multiplied by 85, the product is *6834; which subtracted from I^'6l3, the specific gravity of mer- cury at 50% gives 12*9296, the specific gravity of mercury at 135^ of temperature. At 200° the specific gravity of mercury is 12*407 150 12*809 335 . 12*929 117 13*074 100 13*211 50 - — - 13*613 0 14015 50 below zero — — . 14*417 52 14*433 bQ 14*465 'Then, to see if the alcohol in which the mercury was weighed at G obtains by the same mode of calculation a. specific gra- vity, according with the calculations at I, from the experi- ments at H on silver, — observe the rule at I. At the temperature 5^^ below zero, the loss of weight is 59*9 on the quantity 1000; by which if it be divided, 16*694 is (tt low Temperatures* 14^ i^ the quotient ; this again dividing the specific gravity of the mercury 1 4*465, the quotient is at this temperature •8665, the specific gravity of the alcohol according to G, which agfecs with the calculations from the loss of weight of silver by experiments at H, and calculations at I, it there appearing that '86G5 is the specific gravity of the alcohol. M. Supposing the mercury weighed by the hydrostatic balance at G in a solid form, during the variations in the loss of weight from 59-9 to 61, to have passed through 20' of temperature to 76^ below zero, and to have ipcreased • 117 '9537 ]{)() '(jc^Gl ' 50 ^ 1-0000 and as '1080 is the sum of difference in 150^, this sum *0007£? expresses nearly the variation in each degree. Wc find from !he data obtained in these experiments a rat'fn of contracimn between mercury, alcohol, water, ai>d silver of e(|ual volume. Mercury at L is -00804 Alcohol at T is '0004943 Water from F above -0007200 Silver at II is •0006114 , What will he the proportionate contraction of each, that gf mercury being supposed ICO? As the increased specilic gravity of mercury is to the sup-^ posed number, so is the increase4 specific gravity of either to the number required. ( 0004943 = ()'144 ContraciionofalcohGl IfOOS04bel0O,wliatwilU;OO372OO=: 8-955, waler /0006j14==7u04 silver of equal voiun.e, when th.'at of macury is JOQ.. ^'^ If- we suppose water to be 1 OOOO .7 ^ '* *" ' ' then mercury will be IV 1^^^ ■ alcohol' • <^^ ^^'^-i'es^S silver - ■'•6491' As in the hydrostatic balance the comparison relates to Qqual vahiines-u^' the thing weighed, and the fluid in which . it is weighed ; What will be the ratio of contraction oi' eqi/al weights of each of the above ? As the specific gravity of cither is to the specific gravity of mercury, so is the ratio of contraction of equal voKmics to the ratio of contraction of equal weights. As .*8M1 : 13613 :: 0004943 = 008265 alcohol. I As 1-000: 13613 :: 0007200 = OO96OI AvateiV As; 10'36i' : U6I.3 :; 0C06i 14 =000803 sifW. OOSO'U) mi^r-eufy. ' Table Table of Results of the foregoing Experiments^ with some Calculations from them. liic gravity of o/f 1000. of !/?•]/ weighed in alcohol and G. ihc gravity of meratry ilatc• rs £ 200 -4 S re ai jy a re tfl C fl 71-88 list 10-270 12^107 -8920 >t» h'i.'v ; 175 7226 10 300 l.';0 12-809 72*65 -9306 j^2d'' '16-240 10 310 135 75-4 130 58 12'929 7276 •9-il9 7810 io-2;6 10 321 7(> 117 58-47 13074 ci ii i^ -•4 108 . ■ '■ 7SCi3' 102/6 10331 \ -7 77 100 95 58-3 13-214 73-10 •9661 —•6 82 TfiOD 1C> lon-i ^ i> . '^ ■• —•9 70 59-5 y\. ■■ , I , . .«.' 78 68 — 1 64 \ 8141 10-357 10-302 — 6 50 59-8 13'6l3 73-459 roooo ^ , 79 — 2 -6 HO — 5 45 40 32 21 9 59-9 ma 8388 10-355 10392 81 —4 zero 10 60-7 14-015 —•7 21 Xi\o gorr ;g ^ijvf e.Hm 822 28 . . ^ . —3 31 —•5 —•5 32 ^A::^v1i raN^T.' — -G 4o —7 48 8635 10-427 10-423 —■fa 50 14-417 8045 10-428 10-424 83 ' 52 T 54 y 599 14-433 ' ....J 66(i5 J 0-427 10-4'27 83-1 56) 14^-465 -^ .* JA (i> --jdj T,;>;tcv petit c >7/C 61 14-485 K 4 To t^^ On the Conir action which takes place in Mercury To recapitulate the foregoing Experiments-^ Observe, ^t A, mercury Is of the specific gravity 13'6l3 at the tern* perature 50. At 3j afcohol is of the specific gravity 'SHI at the tempera- ture 50. At C, silver is of the specific gravity 1 0*362 at the tempera^ ture 50. At C and D there is error shown to exist in estimating the ..^specific gravity of bodies in the usual mode, without hav* t (ing regard to a fixed point of temperaturcj at which the medium chosen to compare other bodies with should be estimated at rOOO j and without having regard to the ratio of contraction in the body weighed, and the medium in which it is weighed. At E, a variation of contraction between mercury and al- cohol expressed by 22 in weighing 5276 of mercury. At F, the error of common practice noted at D is confirmed, the increased loss of weight showing the contraction of water to be greater than that of mercury of equal volume; it is expressed by 4*7 in 150^ on the quantity 3024. At G, mercury in its frozen state weighed by the hydro- static balance lost 59*9 to 61 on the quantity of 100. For the calculations from these facts, see L and the annexed table. The mercurial thermometer felhbelow 270^ on the scale below zero. At H, silver, going down 1 50 degrees of Fahrenheit's scale, contracts -j^-^^h, part of its dimensions, which is called its visible contraction^ The silver at 117 above zero is 10*321 -^-^ 50 10-362 . r- 56 below zero 10*426 The increase of silver in its specific gravity is '0006114 each degree. At I, the error of general practice observed at D and F is con- firmed. A rule is given for finding the specific gravity of the al^^ohol. When '8141 at 50 above zero it appears to be •86G5 at bQ below zero. At ai low Temperatures , I S3 At T, the Increased specific gravity of alcohol each degree is '0004934. For the further variations of gravity see the annexed tdhle. At K, a rule for finding the specific gravity of silver from loss of weight at C^ and the specific gravity of alcohol att. If silver at 50 above zero he 10'363, it will be at 56 below zero 10*427. At L, a rule is shown Ibr finding the specific gravity of mer- cury .-—-At 200 above zero it is found lo be 12*407 50 J3-613 56 below »— 14'465 The increase each degree is *00804 . A comparison of C and G as it relates to alcohol ; and by the rule at I it appears they accord in the number '8665, the specific gravity at 56 below zero. At M, the contraction of mercury in its solid state, sup-^ posed to be near twice that of silver, or '001 each degree, because near the point of fluidity. Alcoholof the specific gravity *8854 at 76 below zero. Mercury in a solid form of the specific gravity 14*485 at 76 below zero. The mode of calculating this is shown. The increase of specific gravity of alcohol in each de- gree not shown by the hydrostatic balance, when mercury is weighed in it in a solid form, is '000061. At N, rule for finding the increase of water of equal bulk to that of mercury. It appears from F to be *0007^ each degree. Rule for finding the ratio of contraction of mercury, alcohol, water, and silver, of equal volume ; mercury being supposed 100. A ratio of contraction also of water, mercury, alcohol, ftnd silver; water being supposed 1*000. Rule also given to find the ratio of contraction of alco» Jiol, water^ silver, and jnercury, of equal weight. XXIX, Essay L ^54 ] XXI)C. Essaf/upon M^ckinds-mghncrr'ail' Bij'M. CarnoT; Member of the French Institute^ &C^&c, ! > . ) r ; t~ • ' J : ' '' [Cominued iroirt p: 1*5. J'^' ' ^ " ' ' * ' . X HE .sepond principle upoi> vvnicn-w;e purpose making some observations, is ilic celebrated liw oV equilibrium of Descartes. Tt tonics to this, that two powers in equilibrium are always in reciprocal ratio tp their velocity, es-timated in the direction of these forces, wlicn we svippose l^hat one of the two comes to take it from tlic other in an infiiiitely small degree ; so that a small movement arises from it. But although this proposition be very beautiful, and we generally regard it as the fundamental principle of equili- brium in machines, it is nevertheless infinitely less general iRa'ii that which has been quoted in the first plaqe ; becaj^se it is applied solely to the case where tliere are only two powers in the system : and besides, it is very easily deduced ffeiifi-'what has been said upon the subject of the two weights A and B, since v/e evidently approximate the one case to the other by substituting, by means of pulleys, weights in pface of the forces which we wish to value. Moreover, it is to be remarked, that this principle does not cjjpress the conditions of the eq^uilibrium between two powers 'sb'cQihpletely as that \vhicK has teen quoted in the first'place; 'for it only gives the accouiit of the quantities of forccj cpmposino- equilibrium, at the place where the latter also gtVe^, m some soh'^ ^thc account of'tjieir diVections ; — for ex- ample, in the case of equilibrium between two weights, the principle of Descartes solely teaches. that the weights should te6 'in the reciprocal ratio to their, vertical velocities j but it tlocs not indicate, like the first, that one of these bodies should necessarily ascend, while the other descends. In ftrder thai an ail^e, fcir instance, to the wheeh and cylinder of which weights ar6 suspended by cords, should reniaiu Tit ''eiqitili brill ni, it i;?^not sufficient that the weight applied to the wheel be 16 thrii of thti cylFiider'as the radius of the cylinder is to the radius of the wheel :— it must also hap- pen that these weights tend to make the machine turn in a contrary direction to each other ^ i. e, that thev are placed io ui|[e rent sides with respect to the axis ^ else their efforts, l'-'- ^ ■ % ^ *' being Oil Machines in General, 1 55 being mutual, will put the machine in motion. It is therefore evident that what renders the principle of Des- cartes incomplete is, that by determining the reference of the powers, as to their values or intensities, he does not express that these powers should make opposite efforts, nor in what consists this opposition of efforts: it is clear, in fact, that for an equilibrium one of the forces must resist while the other solicits : now, this is not what happens in the ca^e of the' example of the axletrce; — But what is it in general that distinguishes soliciting from resisting forces ? This in my opinion has not yet been determined. We shall see in this essay that the characteristic difference of these forces consists in the angle they form with the directions of their velocities, so that the one form always acute angles with their velocl-^ ties, while the others form obtuse ones with theirs. Lastly. One fault with which we may reproach the princi- ple of Descartes, as well as all those where we are discuss- ing the small movement which would arise in the system if the equilibrium was disturbed, is, that they do not indicate the method of determining this small movement. Now, if for this purpose we must have recourse to some new me- chanical principle, the former is not sufficient ; and if we can determine it by pure geometry, What is the method of doing so ? This is what the principle does not say : and let us not say that the proportion indicated by the principle al- ways takes place whatever the movement is, provided it is possible, i,e. compatible with the impenetrability of bodies; for this would be an error: and we shall by and by show that these movements are subjected to certain conditions, int consequence of which I think it right to give them the nami of geometrical movements. We may make the same remark upon all the principles upon v/hich we propose to consider a machine in' two states infinitelv near each other; for, in order to detctiTirne what arc those two states ; i. e. what movement the machine should take in ordqr to pass frbn^ the 'one to the'odiifr,'\ve inust either employ new mechatiical principles tonjiinctlv with that proposed, which would render the latter insuffi- cient ; J 5$ On Machines in General, eient; or else geometry is sufficient; and in this case it is a defect in the principle, not to make known the geonij^^ trical conditions to which this movement is subjected. VI. The two laws mentioned are confined to the case of equilibrium. We pass easily from this case to that of the movement by M. D'Alembert's principle in dynamics. But we have found several others which are immediately applied to the case of movement ] such as that of the preservation of living powers under the shock of perfectly elastic bodies 5 which is so much the more gener^^l, as it extends even to the case of the movement passing rapidly from one state to the other: but it would seem that people have little dreamed of the use that might be made of it in the theory of machines properly so called. It is, however, evident, that this law should have its analogy in the shock of hard bodies : and as we generally take the latter to use it as a term of conjparison, this principle, transferred to hard bodies with the modiii- catipn which the difference of their nature requires, cannot fail to be more useful than the preservation in question. We shall show, in fact, that we may dedilce from it several capital truths with the greatest facility, and particularly the preservation of living powers in a system of hard bodies, the movement of which changes by insensible degrees ; a prin- ciple of well-known utility in the theory of machines. We shall thereby see, at the same time, an intimate relation between these two preservations of living powers; — we draw from it also the principle of DeiScartes ; and even, by gene- ralizing it, the law of equilibrium in machines with weights above mentioned. This principle, in short, after having given to it the extension of \vhich it is susceptible, appeared to us to contain all the laws of equilibrium and of movement: and >vp have not found a better for the basis of our theory. VII. This essay will be dividc(J into two parts: In the first we shall treat of the general principles of equilibrium and of movement in machines; and in the second we shall examine the properties of machines properly so caHed, without ever stopping at any particular machine. PART On Machines in GoneraL 157 •PART FIRST. General Pri?icipk'S^ When one body acts upon another, it is always imme- diately, or by the agency of sISme intermediate body: This intermediate body is generally what is called a machine : the movement lost every instant by bodies applied to this ma- chine is partly absorbed by the machitVeitseU*, and partly re-. ceived by the other bodies in the system ; but as it may hap- pen that the object of the question is simply to find the re- ciprobal action of bodies applied to intermediate bodies, without having arty occasion to know the effect of it upon the intermediate body itself, it has been thought, in order to simplify the question, to make an abstraction of the very mass of this body* preserving to it on the other hand all the other properties of matter. Hence the science of machines has become in some measure an isolated branch of me- chanics, in which it is required to consider the reciprocal action of the different parts of a system of bodies ; among which there are found things which, when deprived of the inertness common to all parts of matter such as exists in na- ture, have retained the name of machhies. IX. This abstraction may simplify in certain particular cases, where circumstances indicate those of bodies, the mass of which it is convenient to neglect, in order more easily to attain our object; but we conceive that the theory of ma- chines in general has really become more complicated than formerly : for this theory was once contained in that of the movement of bodies, such as nature presents them to us ; but at present we must consider at once two kinds of bodies;, the one as they really exist, and' the other as deprived in part of their natural properties. Now, it is clear, that the first of these problems is a particular case of the latter; therefore the latter is more complicated : further, although we easily suc- ceed by similar hypotheses, in finding the laws of equili- brium and of movement in each particular machine, such aj» the lever, the axle, and the vice, there results an assemblacre of facts, the connection of which is perceived with diffi- culty, and solely by a kind of analogy ; which should ne- cessarily ^8 On Caloric, and. the Heat evolved ^during ComtusfioH, cessarilv happen, as often as we have recourse to the particu- lar figure of each machiiie/ in order to demonstrate a pro- perty which is coninjon to it- with all others. These common properties being ^hqse whiych \^e;.have,,i;x;\5icy/ in this essay, it is clear that v^^# shall only succeed in fuidingj ihera by the abstraction of particular forms* Let i>s begin,- lherxifore,J^y;simplifyin;g the. state of, ^he.q^^^^ ing to consider under one and the same system, bodies dij:- fcring in. their natuiq. , Finally,, let us restore to niachines, their visinertice, ^Jt^ ^\\\ j:)e^.ej\sy^ , ai^e^^,.^his,.^o ,|C^^ their mass in the result : we shall have the choice of doing SQ- or not; and, in setting out, the soluli9i| of the probler^ T^ill be • eqvially. , geni^ral, at the same ;l|i|i)e,,tlxat it will be simpler. .^a oi [To be continued.] XXX, On Caloric, and the Heat evolved during Comhisiion^^ By James, Scholes, Esq,, JMctnchester. To Mr. rilloch. '^^"^ SIR, ,1, J- y,', xIaving been induced to pay particular attention to co^ii-; bustion for some time past, i have insensibly imbibed prin- ciples diffcpent iVom the generally received theory, I very coon began to suspect caloric as a compound substance, and six months ago had recognised two fluids of electricity for its component parts. The only demonstrative grounds I then had for my ideas was the production of hght and heat, parti- cularly the latter, and for the purpose of measuring the quanti ty thereof I had an apparatus constructed. But when Mr. Davy's recent experiments were noticed in your JNIagazine, 1 im- n^ediately saw them as an additional support of my peculiar principles, and prepared a lecture, which was delivered to a Society in this town on the 29th of January, laying down the whole system, as supported by facts deduced from elec- tricity and the experiments of Mr. Davy, which I intended to publish when more matured ; but on looking over the monthly publications yesterday, I found a communication in Mr. Nicholson's to a similar purport, which has induced me me to trouble y^u w^th mv cOjrr^i^uu}icayioi),^s^^^ imendcd. If you ^eem it wor.thy a place In yo4.ir'work, I; shall feci obn2i;c(l iVy .the insertion.. Y()i) wilt sec that T come to ^imilc^r conclivsjous to Mr. Gibbcs,. i[rpm a very diflfere-nt investigation, and from different pncrnamena ; so ibat there is no sameness in our productions. With respect to the me-. rH'*6feacn (being somewhat diiTercnt), I can si'vihis, th^it I' have 'candidly considered wh^t Mr. Gibbes ha3 adyarnct^d^,^. but T shall not be disposed to admi^ withovU lurther inforii^ar- ticfh one of his deductions: viz. that water js a sirnplesub-r slahce, and the ba3e of both hydrogen nnd oxygen. i^^^' ■:■..' ':' T ' • - 1 ]•'' 111 • '■' ' t"^i" J am^ sir, your obedient humble servant,^ ^ ■./,.'.. James Schole;s, 'Manchester, March 4, 1808. ON CALORIC, &( CALORIC, 6CC. ^^. ^theory to be, just, ought to elucidate and exhibi^i.thtc; cause of every phsenomena with which it is connected: if it will .not do this, I shall even be inchned to believe that its principles are erroneous, or at least very im perfect,,, ^Utis an undoubted fact that there are many effects which the pre- sent doctrine , of caloric does not pretend to explain at all ; and again, , tbjsre, i jare raany others which it explains oiily upon principles inexplicable in themselves. And if we take a view, of the doctrine as applicable to combustion (which is perhaps its forte)^ reflection cannot but produce dissatis- faction with it. The present doctrine of combustion is founded upon this basis : first, (which is undoubtedly just,) that oxygen in every case unites with the combustible j se- condly, that the caloric and light is produced by a dilTerence in the capacity for heat of oxygen and the combustible, be- fore and after combustion. But that this second part of the doctrine is not so obvious, appears from the conjbustion of gunpowder in vacuo, and many similar facts. Whcre^ ac- cording to the present theory, caloric ought to be absorbed instead of evolved, it is directly contrary to the system ; for the products of combustion have considerably greater ca- pacities, for caloric than the combustible and i^r.pporter of combustion thcmsej\TS. Other 160 On Calorkyand the Heat evolved during Comlustion, Other phjcnotncna might be adduced to the same purport; but this is the strongest proof, the best known, and suffi- cient for my purpose. It will, I presume, be seen, that though, one part of I^voisier*s doctrine is probably just, yet the other is as likely to be erroneous ; and, from a retrospect of the success of various fallacious theories, from their being always established on s«[ihistical reasoning from experi- menia! proof, which is as liable to deceive mankind now as aforetime, we shall be justified in this conclusion; that though Lavoisier's theory appears to coincide with experimental proof, yet it may not be just, and that, failing to account for many phaenomena with which it is connected, it is at best imperfect, if not materially erroneous. It indeed accounts for the emission of heat and light in common cases of com- bustion plausiblv enough, it i^iust be admitted; — But where is tliep-QofP Plausible reasoning is often sophistical ; and I cannot by any means think we have sufficient grounds for believing that the caloric and light of common combustions are produced agreeably to this doctrine. It appears to me that the evidence thereof is mt^rely presumptive, and in many in- stances it is evident that the heat and light nmst be derived from another source. That the state of combustible, &c., and product of combustion, before and after the process, must have material influence in the quantity of heat and light ciyen out_, is not to be denied ; b*ut in rapid combustions I am disposed to think the effect is not great in proportion to the quantity generated by the process. Since T perceived the deficiency of Lavoisier's theory, I have been induced to pay particular attention to this subject. Reflection soon taught me that oxygen and caloric must have some remarkable relation to each other, as oxygen is the only known supporter of combustion in nature : — what kind of relation this can be, does not appear so ready to deter- mine. Yet I am inclined to believe that it will be brought to light before long, and that it will be discovered in the new field of investigation opened by the" recent experiments of Mr. Davy ; at least it is there I have looked for it. I ju3t noted that there was a remarkable relation between oxy- gpi and caloric, or rather between oxygen and the genera- 9 lion On Catdrw, ami the Hm 'evolved during Coinlustion . l6l tion of caloric by combustion. According to rny conccrptiotl of the experiments of Mr. Davy, they show that combusti"- hies on decombusiion jabsofb the electric fluid : and as we know that no quantity of electric fluid is given out on com- bustion, it appears probable that this will lead us to the dis- covery of this relation between oxygen and combustion. We cannot for a moment consider the electric fluid and caloric as synonymous : we must therefore draw this Conclusion ; That the electric fluid is probably instrumental in producing the caloric of combustion, and that as it disappears therein, it must disappear to form something else. The combustible unites with oxygen, and we tind that a large quantity of ca* loric appears as a large quantity of electric fluid disappears ; it is therefore extremely probable that the electric fluid which disappears, forms the caloric which is generated. This is the result I infer from it ; and the manner in which I conceive it is effected, I shall now lay down : viz. that there are two electrical fluids in nature ; and that the peculiar relation ox^ ygen has to combustion consists in this — that oxygen is the only substance with which one of them combines, and that the other unites with the atoms of combustibles only ; — that caloric is generated during combustion by the union of these two fluids; consequently, that caloric is not a simple sub- stance, but that its particles are composed of the two fluids of electricity — this brings combustion to be a double de- composition and combination, one of the products of which is caloric ; that the electric fluids in some form or other are blended with the atoms of matter, and like the atoms of alkali and acids in salts veiling each other's properties; that on the combination of oxygen with the atoms of the combustible body, the electric fluids severally combined with each, unite^ and form caloric, which is disengaged as gas is set at liberty in other decompositions. As gas lighter than atmospheric air is forced to rise up when at hbertv to do so, so caloric, when disengaged, is by some power dispersed on all sides. It appears probable from a varrety of circurpstances, that it is the vitreous fluid of electricity that unites with oxygen, and the resinous with combustibles. If we note, therefore, Vol, 30. No. 1 1^8. March 180^. L that 1 62 On Cal(X)ic, and the Heat evolved during Comhustion. that gunpowder, containing one of these fluids in large quantity in potash, and the other to a requisite extent in sulphur, it will not be surprising, that gunpowder should burn in vacuo, nor again that it should give out so much heat and light on deflagration. These principles not only account for every phajnomenon of combustion re- lative to gunpowder, and by applying them to combustion by acids, &c., likewise, but at the same time for the heat emitted during combustion in air. Whereas, to reconcile Lavoisier's system, wc are obliged to suppose an 'unnatural chemical union of oxygen, different from its general pro- perties, for which there is no other ground, than the con- venience it is of, only to deceive ourselves, by regarding as a property of nature, what is in reality only a property of human imagination, and which, if persisted in, must effectu- ally put a stop to this branch of science. It must be obvious that these principles will in a most simple and beautiful manner account for the light and heat produced by electrical experiments and friction. To enter in- to particulars would exceed the, limits of this paper. I shall therefore conclude with a view of the process of revifica- tion or decombustion. Suppose the body acted upon is iron ; A quantity of resinous fluid unites with the metal, and the oxygen of the oxide of iron is .separated in the process; it is therefore as strictly a chemical union as that effected in com- bustion. If we examine the process for therevification of ores, we find it peculiarly adapted to produce this decomposition. A layer of charcoal, then a layer of oxide, is alternately depo- sited. The heat that is first produced by setting fire thereto^ carries off the oxygen of the charcoal in carbonic acid gas : the carbon thus heated has an affinity for, and combines with, oxygen. When, therefore, the oxygen of the charcoal is exhausted, it unites with, and carries off in gas, the oxy- gen of the ore, at the same time that the resinous electric fluid of the carbon unites with the atoms of the metal. Thus it is that fire both burns and unburns substances. The fire acts no otherwise than by placing the particles of carbon and oxide in a situation in which they have power to act on each other: one part only of th« combustibility of the char- coal On the different apparent Magnitudes of the same Oljects, 1 63 coal supplies the heat requisite to this purpose, whilst the other literally undergoes no con^bustion at all, but is trans- ferred unaltered from the carlwn to the iron, or whatever substance is employed; that is, part of the rei/inous fluid which charcoal as a combustible contains., is expended in the production of heat and gas, whilst the other part unites with the iron (if such was employed) of the oxide, and renders it combustible. The metal is rendered combustible at the expense of the combustibility of the charcoal; and the reason that the iron does not undergo combustion when rendered combustible, is owing to the well-known chemical fact, that substances alter in their propertiesby different combinations. In this case we find that the resinous fluid (the principle of combustibility) becomes more fixed in the fire by uniting with the particles of iron, &c., than it was when united with the particles of carbon. It appears, therefore, that the re- sinous fluid (the^rinciple of combustibility) is more or less fixed in the' fire, according to its combination with difl^erent substances ; and that it is owing to this that to burn one combustible one degree of heat is required, and another an- other. XXXI. On the Cause of the different apparent Magnitudes of the same Objects seen under dfferent Circumstances, By Ez. Walker, Esq. To Mr, Tilloch, SIR, At the conclusion of a paper which was printed in the Philosophical Magazine for last October, I mentioned that the apparent magnitudes of all objects are variable, as well as those of the sun and moon. This, however, is not a new discovery, for M. le Cat mentions it in several parts of his Physical Essay on the Senses, printed in the year 1739. This philosopher says, p. 234, " I looked through the glass of a casement, at a very remote country-seat, which appeared to me sufficiently large. I afterwards fixed my eyes on the glass itself; and it L 2 seemed 1 6-1 On the dlffereJit apfmrent Mag?iitudes of the same Ohjccts, seemed to me a great deal smaller than when T looked at it directly. Since that time I have made repealled experiments of this matter, and always found the same circumstances.*' In another place he says : ^* I shall recount still something more extraordinary on this variation of the magnitude of the visual angle, or of the image of objects. 'S Last winter \ was in the country. In the night it froze hard, and there fell a little snow. On going out of my chamber in the morning, all objects appeared to me sensibly smaller than they had done the evening before. ^*. Since I made this discovery, and have been guard- ed against the rule of comparison, T plainly perceive that a very illuminated object seems smaller, arvd an object feebly supplied with light appears 4arger, The reason of this is evident. A strong liirht puts the whole globe of the eye on contracting itself, and a feeble one leaves it relaxed and dilated.'* This author is very correct in his observations ; but his explanation is founded on a false theory. The true reason is this : A strong light contracts the pupil oF the eye, in which state it forms a small picture of an object upon the retina; but in a weak one the pupil is ddated, and all ob- jects then appear larger. This property of vision will, I think, appear evident, from the following experiments. It is diflicult to enlarge the pupil of the eye to any parti- cular dimension, but it may be contracted at pleasure, by means oF perforations made either in a thin plate or a slip of paper. Now, if an object be viewed through an -aperture, about ...Vjj. of an inch in diameter, it will appear much smaller than to the naked eye, in consequence of the aperture of the crystalline lens being contracted ; but if the perforation be removed from "l>efore the eye, the object will instantly appear increased in magnitude: and as no change can take place in any part of the eye instautajiemisl?/, it is therefore evident, that, the apparent magnitudes of all objects arc in- creased by an increase in the aperture of the crystalline lens, and consequently by an enlarged pupil. 4 The On the Idenllty of Silcx and Oxygen. J 63 The same thing: may also be proved by looking at an object th()ii(2,h perioralions of dilVerent dimensions 5 tor it will appear snialier through a perforation of yJi-jj- of an inch, than through one that is four times as large; and an object viewed through a perforation as large as the pupil, appears of the same magnit-ideas to the naked eye. Whence it is manifest, that all tenestiial objects appear larger to the naked eye in the mornings and evenings, when the pupil is large, than at noon when the pupil is leis ; and for the same reason they appear larger in winter than in summer. I ani; sir, your humble servant, E. Walker. Lynn, March 18, 1808. -^ XXXII, On tlw Identity of Sllex and Oxygen. By Mr, Hume, of Long- Acre, London, ' 7b Mr, Tilloch, SIR, JL o inculcate any science with success, there is nothing so essential as a simple and perspicuous display of its lirst prin- ciples ; and if there be any department in j)hil()Sophy to which this observation is uiore peculiarly applicable, it is certainly the study of chemistry, than which there is, pro- bably, none more useful to man. The present period is, of all others, the most opportune for an improvement in chemical theory, as, from the very brilliant discoveries of Professor Davy, it is ob-.''ous that a most material revolution is now dawning upon tlic modern system of chemistry, anfl, possibly, an entirely new struc- ture must eventually prevail. 1 now allude to the word oxygen particularly, which, in its present limited sense, stands as a solecism in language, and a mere absurdity in the nomenclature of the day, since it has been lately proved to be at once the principle of acidity and likewise that of alkalescence, Jn all modern authors, the classification of simple and L 3 eknien- t66 On the identity of Silex and Oxygen, elementary bodies is, I presume, too diffuse, in respect to the number of subdivisions ; and many of the titles employed might, with propriety, be expunged. But, though there are many other imperfections in chemical arrangement that require reform, T mean on this occasion to confine the following observations to one article only 5 and shall endeavour to prove that, in this instance at least, we should revise the list of simple substances, aS far as re^ gards silex; which is still continued, I think, with great impropriety, to rank as a species of earth. To include in any one genus both silex and the other earths, as they are now called, seems extremely improper and palpnbly erroneous; nor can this classification be sup- ported by any reasonable argument whatever. The defini- tions given frpm time to time, to distinguish an earth .from any other elementary body, have never been sufficiently ex- plicit, for they do not precisely exclude the alkalis : they make a useless division under the name of alkaline earths; and, as salifiable bases, an earth, a metal, an alkali, and silex, may be said to range as fotir distinct species of the same genus. -. t All earths are declared to be salifiable bases, snd this I take to be the most essential clause in every definition; for, generally speaking, the earths have a ready affinity for every acid, even from the weakest, particularly the carbonic acid, to the most powerful that exists. Indeed, as far as concerns the combination with carbonic acid, with which the earths form nearly insoluble compounds, this peculiar property alone might have served to distinguish an earth from an al- kali. Here, however, the principal force of the definition fails, the exception to silex is decisive; there is nocarbonate of silex; no nitrate, no sulphate, nor, in short, any other salt, in which the acid is saturated by this simple element : neither art nor nature ever produced a perfect neutro-saline compound, in which silex could fairly be considered as a real and independent base. To constitute a true salt, we know, there must not he less than one acid and one base, reciprocally saturating each other; and when the nmnber of either exceeds, and the salt On the Identity of Silcx and Oxygen; \^ salt is not a binary compound, we may then fairly suspect an imperfection ; for, one of the elements at least is fre- quently in the state of mere suspension, and not in chemical union with either of the other ingredients. There are, indeed, numberless examples of such salts, and, I am ready to allow, some in which silex is found, whether as a mere contingency or otherwise ; but it never exists as a perfect base, that is, possessing the capability of saturating the whole, or any part of the acid in sivch com- positions. If silex be, what I have long considered it, not only dis* similar to every elementary ponderable material besides, especially in generic characters, but, also, so vastly superior in its importance and bulk, as to leave no room for compa- rison ; surely it ought then to be instantly removed, and no longer suffered to remain in the list of earths, but should be placed in the most prominent station in the arrangement of elements. Such is its consequence, that nothing in na- ture is so predominant or so universally disseminated ; no compound solid substance of any magnitude is exempt from it, but contains always some, if not a very large portion of this insinuating, and as I conjecture, most essential of all terrestrial matter. All organised bodies either contain silex, or, what I shall consider as a modification, oxygen. If there be any excep- tions to this conclusion, they are so few and of such trivial import, that when they do occur they should be rated as anomalies ; and it may happen, that the apparent absence of silex or oxygen is rather to be attributed to our want of means, and the imperfection of science to discover it. In a geological view of this subject, where can we turn our eyes or employ our thoughts, without meeting this grand and multifarious cement' — this bond of aggregation, that fixes the solidity of all tangible nature ? The very outlines of our planet are traced out with it; and all primitive matter, from the most stupendous mountani or rage^ed precipice to the deepest cavern, even to the centre of gravitation, we arc warranted to say, is replete with silcx. If we contemplate the nature, volume, and importance of this, and then rccol- L 4 lect l!68 Oa the Identitij of Silex and Oxygen, hct the insignificance of zircon, glucinc, anJ indeed the whole of the species of earths, none of which exists without an association of silex — all comparison vanishes, there is no estimate ; these are as the mere spots to the brightest of luminaries, and therefore, in all systematic classification, should be separately arranged. Where then ought silex to be placed in the arrangement of simple elements? — should it link with any other ponder- able body as a species of the same genus, or preserve a station to itself? Were I asked for an answer to such a question, I would say — that seeing^ nothing to which it has the slightest resemblance but oxygen-gas, of which I con- ceive it to be the true base, here I would not only assign its proper rank, but give it alao a precedence to all other elemen- tary matters that had resisted decomposition. It is hardly necessary for me now to add, that I do not consider o^-ygen in the state o'i gas to be a simple body ; for whatever is susceptible of spontaneoiis change should al- ways be deemed a compound of at least two elementary siib- ^jtances. If one instance of this can be adduced, we may naturally infer that others will be found; and, fortunately for my present purpose, a most appropriate example has lately occurred, which confirms this conclusion : I allude to the experiments of Messrs. Allen and Pepys*, upon carbon and carbonic acid, which appear to have been conducted with unconniion precision and genius, Froni these gentle- men we learn, that oxygen-gas is subject to spontaneous change, pr, as they very properly express it, a deterioration; /ind that this will happen, though the gas be of the purest kind, that obtained from oxy-muriale of potash ; and even when seciircd in glass vessels with glass-stoppers, paving assumed silex and the base of oxygen gas to be synonymous and simple bodies, I shall now proceed, as far as my humble pretensions and Jcnowledge of this subject wiU permit, tqsubstantiate this position, by ofiering a few only of the numberless lacts, which seem to confirm this identity. It is a task, I confess, I have imposed upon myself; foi;', ^laving nearly three years ago permitted my opinion to he *. Fljiioaopliical Transactions iS07. pub-! On tJie Identity of Silex and Oxygen. 1 69 published, though unaccompanied with any explanation or proof, and as the work * has now arrived at 'us second edi- tion, it becomes my duty to absolve its author from all re- sponsibility 'y and, rather than any blame should attach to him, avow myself as the only person, who is accountable for promulgating tenets, which to many philosophers must have appeared to be visionary. It is scarcely necessary to explain what Is here meant by the word silex. But, that I may be clearly understood, I shall define it to be, the very pure part of rock-crystal, and that which constitutes by far the greatest portion of all sand, flint, gravel, and other well described rocks, stones, and minerals : a substance common in every spot of the globe, in every zowQ^ anjd in every climate; and an article so obvious and familiar to the meanest capacity, that any further descrip- tion would be superfluous, I shall just observe, that 'in rock-crystal, in quartz, and in hot-springs, silex is nearly in its pure and primitive stale of perfection. There is no subject, in which analogical reasoning is more admissible or more conducive to arrive at the truth, than the one before us : and indeed, whenever the discussion has for its object the works of nature, as in chemistry and its sister- science, geology, I do not see it possible how this mode of argument can be wciravoided. It was analogy that led the penetrating mind of a Newton to some of the most brilliant of his discoveries ; and it was the same faithful guide that conducted this immortal philosopher to predict some of the most important truths, which have since been so completely established by the experiments of his successors. The com- 'bustible nature of the diamond, and likewise that of water, are among these examples : they are facts that will for ever bear testimony to the great advantages that may be derived from this nicthod of searching into the secrets of Nature*s unerring works^ and the laws which these obey. Now, to apply this mode of reasoning to the present object of research, let us consider this our sublunary world under its three grand divisions. The first, is the at- piosphere, which surrounds and compresses the whole of the others; an4 this may be called iht^ aerijorrn division of * " Clicii^ical Cjitechisnx." nature 1 70 On the Identity of Silex and Oxygen, nature. Here, it Is allowed, the principal element x^ ox- ygen ; but it is now in the gaseous state, that is, it is sa- lurated with caloric. I have said, the principal element, because it is the most important of all others :— it is tht^ matrix of fire, it is the pabulum of life ; in short, such is its consequence and value to the very being of all orcjanized matters, whether in the animal, vegetable, or mineral king- ■dom, that surely some more appropriate name might have been devised, than what it now bears. Though it is a di- gression, and remote from my plan, I shall take the liberty to hint, that i^erely by modifying, that is in soirie measure reversing, the theory which first employed the word phlo- ghtoni both this word and the theory itself might with thfe greatest propriety be revived: and the word phlogiston, even in the theory of the present day, would more aptly suit our comprehension of all the properties of pure air, than that oi oxygen, which implies merely the generator of vine- gar or sourness, a derivation of all others the most puny and incomplete. The second grand division, is the ocean, sea, or water, which we may name the aqueous portion of the whole. Here we again recognise our oxygen, not only as the princi- pal ingredient in magnitude, being about four- fifths of the whole, but in all other respects claiming our first atten- tion. In this water, the oxygen is further concentrated, having lost a part of the caloric which it possessed in the gaseous form, or in the atmospheric state ; so that, in this case, we may tiow conceive it to be, in regard to density, midway between earth and a:r; and that, by an abstraction of more of its caloric, it must approach nearer to a state of solidity. •V If oxygen, therefore, constitutes such a prominent and ^hiking feature in two-thirds of the works of the Au- thor x>f all creation— -which, in these cases, is a truth that admits of no controversy. Why, it may be aptly demanded, should it not, also, form the most conspicuous ingredient in the other third, that is, the solid or real terrestrial portion of this material world ? Analogy and the general complexion of all the phasnonjcna of nature seem to answer in the afiirmative, and, I think, will aflord &ome of the oipst legiti- 1 piate On the Tullic Utility of Medical Instituthm. 171 mate proofs, in confirmation of the doctrine I have as- sumed, the identity of silex and oxygen. This theory seems to be supported by such a mass of evi- dence, that it is diffieuh to say where we should begin. GeoJogy is, however, a source so prolific, that every spot of the globe teems with examples : There is not a rock, frorti the most huge and congregated lumps of matter, that rendet the face of nature at otice awful and magnificent, tb the rnoflt thfling pebble ; nor ii there a morsel of any mineral com- ()ound, whether Jt be the brilliant gem or the most unfruitful and degraded soil, where, if there bfe an earth, a metal, an alkali, or any other salifiable or oxiuable element, the saturation is not always due either to silex alone or to some acid^ that is, consequently, something -conlainihg oxygen. Such seems to be their equivalence, that when silex is ab^ sent some acid must prevail ; and it neither be found in the ass6ciation, then the earth, metal or alkali, whether potash or soda, puts on its obvious and peculiar character, such as taste, solubility, density, and the other generic qualities proper to each species '■^■ ^ After silcx, there is no substance so plentiful as lime, but this is never found pure; it is either saturated with an acid, c>f dwindles into a tasteless inert state of aggregation with other bodies, where it is subdued and locked up by silex ; so that, there is not a vestige remaining of its primi- tive qualities, especially those of taste and solubility. That lime, even when pure, is a compound, there is little room to doubt ; and that carbonate of lime, or chalk, is pro- duced at the expense, and through the means, of the degra- dation of silex, may probably (Reserve a candid and minutfe inquiry. [To be continued.] \ XXXIII On the Public UtiUhj of Medical Listilufions for the Benefit of the Diseased Poor, To Mr, TillocJu SIR, JL HE foundation and support of the many medical esta- blishments for the benefit of the diseased poor, not only iu the 1 72 On the Public Utility of Medical Institutions, the metropolis bul ibroughout the kingdom, reflects the highest honour on the national character. This has long been acknowledged; and it could not fail to be highly grati- fying to the public, who contribute so largely towards their support, to have a statement published annually of the re- ceipts and disbursements of each institution, vvith an account of the benefits derived from them to the diseased poor, f do not think this desirable object is sufficiently attained, by the committees of a few charities circulating a report of the finances of the institutions over which tliey preside, among their own members or subscribers The object in view would, I conceive, be best attained by means of sonve periodical work, where the reports should be recorded and referred to ; by which the advatitages of each charity to the diseased poar \\ou\(\hQ. made evident; and a liberal public would in a few years be enabled to form a correct judg- ment as to what kind of charitable institutions was best entitled to their munificence. .The frequent, and in some instances successful, attempts to depreciate the utility of dispensaries, have led to these re- marks ; and when it is known that for an annual sum of 2,OOOZ, upwards of 9,000 of the diseased poor are an- HUiilly admitted and attended in three of these institutions ill London, (those persons being visited at their own houses who are too ill to go to ihe charity,) it must be confessed th2L\ dispensaries d^^t son\t\\!h'A\ more \\v3A\ '''so many hot- beds calculated to rear and cherish their plants* for the public service" It is not my intention at present to analyse the motives which probably gave rise to the above and many similar observations, it being sufficient to record the fact; neither do I mean to advance any thing that should militate in the least against the many truly valuable public hospitals; but only to observe, that the great l3E^'EFlT derived by each ia- dividnal inhabitant of these asylums prevents its being ex- tended to the numbers requiring aid, their establishnient not being of sufficient magnitude to lodge and feed all the 4is<:a:>ed poor : nor would it be sound policy to extend their * The rn?d closed above her head. The flames will thus most certainly be extinguished. This may be done in five or six seconds — in the time that a per- son can stoop to the ground and rise up again,— and no ether method can he so ready, expeditious, and effectuaU The sufferer will facilitate the business by folding her arms close before her. Should it happen that no pCiSon is at hand to assist the sufferer, if she has presence of mind, she may in most cases relieve herself by throwing her clothes over her head and rolling or laying upon them. This method was always communicated to those with whom I conversed on this subject, who all expressed the greatest satisfaction at the probability, and confidence it^ gave them, of being thereby, better than hitherto, enabled to rescue fellow-creatures from agonizing premature death ; and esteemed it a valuable addition to their small stock of rxpedients. '"* The extending this communication to your readers may be productive of the happiest consequences to them and the community at large, and materially reduc<; the list of human afflictions. I am, sir, your very humble servant, March 22, ises. E. V, XXXVI. Ui^ t no ] XXXVI. Letter from ^/r 11. C. Englefilld, respecting his Mduntain Barometer. To Mr, Tillock. SIR, In a note at the bottom of page 1 9 of your last number, I preferred having the lower part of the tube only a twentieth of an inch in the bore, something on the principle of the marine barometer. Upon a mare minute investigation, I do not find that this would answer the purpose so well as I then thought, nor is it so good as the simple tube. J there- fore beg your insertion of this for the information of your numerous readers. I am, sir, &c. H. C. Englefield. March 21, 1808. XXXVIT. Report of Surgical Cases in the City and Fins- bury Dispensaries, for October 1807; loiih some Remarks on the Dissection of the Brain of a Person uho died in' sane. By John Taunton, Esq, An the month of October there were admitted on the books of the City and Finsbury Dispensaries 21 1 surgical patients. Cured or relieved — 193 Died — — 2 Under cure — 1 0 211 Since which time there have been admitted 969. A few days since, I was requested to examine the head of a person who bad been insane for some months preceding death, which took place suddenly, letat. about 35. The general appearance of the body, which was robust, indicated a high degree of health and strength. On removing the upper part of the scull, the dura mater formed a considerable projection over the posterior and su- perior part of the left hemisphere of the cerebrum, near the course of the longitudinal sinus. On cutting through the ex- ternal Report upon a Memoir on the Nitrous Ether, 177 ternal lamina of that membrane^ a granulated substance ap- peared, like a great number of small tumours adhering to the dura rtiater, tunica arachnoidea, pia mater, and even to the cortical substance of the brain, aboui two inches in length, half an inch in breadth, and nearly half an inch thick. The other part of the dura mater was of the natural appearance. The arachnoid membrane was more opake than usual, arising partly from lymph deposited on its Under surface, and partly from an effusion of a serous fluid between that membrane and the pia mater. The cerebrum and cerebellum appeared natural, but the lateral ventricles contained about four ounces of a straw-co- loured fluid ; the surface of these cavities was every where covered with a layer of coagulable lymph, having that aspe- rated appearance peculiar to recent inflammation. Many small hydatids were attached to different parts of the cho- roid plexus. Is it not highly probable that the symptoms of insanity took place in consequence of the pressure produced by the tumour upon the brain? and also that the inflammation was excited by the same cause? If these positions be ad- mitted. Would not the antiphlogistic mode of treatment, carried to an extent agreeable to the apparent stamina and strength of body, which have been rarely exceeded, have produced a more favourable termination ? Since I exainined this case, I have heard from the medi- cal gentlemen who dissected the body of Simmons, the murderer, that half an ounce of water was found in the la- teral ventricles of the head. I believe it was never doubted that this unhappy person laboured under a brutal and fero- cious insanity from his infancy. XXXVIII. Report upon a Memoir read at the French Insti- tute fly M, Thenard, tip07i the Nitrous Ether. By Messrs. GUYTON, VAUaUELIN, and BbRT HO LLET*. iJiFFERENT kinds of ether have been formed by the action of some acids upon alcohol. Volatility, inflammability, * Ann. de Chimie^ torn. Ixi. p. 2 ^. Vol. 30. No, 1 1 8. March 1 808. M and 178 Report upon a Memoir on the Nitrons FAhef,- and a specific smell, give to ethers a decided character, which does not admit of their being confounded with other substances. We know but imperfectly, however, the differ- ences which distinguish them from each other; aiMl in par- ticular, we have but an imperfect theory upon their produc- tion. Messrs. Fourcroy and Vauquelin have indeed thrown a great deal of light upon the production of the sulphuric ether ; but their explanation cannot be extended to that of some other ethers. It was therefore important to resume the subject, in order to treat it in a general manner. This is whatM. Thenard undertook; — In the first memoir present- ed to the Institute, he treats of the nitric ether. He will afterwards proceed to the others ; and will examine why some acids have the property of producing ethers, while others are deprived of it. M. Thenard first brings under review the processes re- commended by chemists for producing the nitric ether. These are very discordant, and only have for their object the etherized liquof, which we may obtain without any analysis ©f the gaseous products, nor any consideration of the cir- cumstances of the operation, unless we except the Dutch chemists, in a memoir which has particularly occupied M* Thenard*s attention, at the end of his own, M. Thenard began by distilling a mixture of equal weight of alcohol and nitric acid, both being of a determinate con- centration, in an apparatus proper for separating the liquid products from the gaseous ; a slight heat is sufficient, and even the action becomes so brisk that it is soon necessary to check it. He afterwards examined the residue of the retort, the liquid produce, and the gases. The residue wa;? composed of nitrous acid, acetic acid, alcohol, water, and a little of a matter the nature of which is not determined, but which chars easily. The proportions of these sub- stances are established by ingenious and precise means. But we are obliged to pass over the details necessary for a cfear idea of the numerous operations M. Thenard's experiments require ; — if we push the distillation to dryness, the viscous residue contains oxalic acid, and probably malic acid. The liquor distilled, which has been regarded in laboratories as Report ilpoH a Memoir on the Nitrons Ether, 1 79 as the nitric ether, is found to be composed of water, ni- trous acid, acetic acid, ether, and probably alcohol. The gaseous product has in particular required much pa- tience and dexterity^ in order to separate it into different ele^ ments ; to assign to each of these elements the properties which belong to it ; and to explain the differences which result from the circumstances in which this gas is placed. It was composed of the nitrous gas, azote, oxide of azote, nitrous acid, carbonic acid, and of etherized gas, which it was particularly necessary to detach from the rest, in order to examine its properties. The author was led by these pre- liminary experiments to the following^ process, in order to separate the pure ether^ and to examine it, whether in its liquid or gaseous state. He put into a retort five hectogrammes of alcohol> and as much nitric acid. To the retort were successively adapted^ by means of glass tubes, five long flasks half-filled with wa- ter saturated with muriate of soda. The last had a tube> which opened under a bell-glass, filled and destined to collect the gaseous part. All the flasks were surrounded with a mixture of pounded glass and sea-salt, which was stirred from time to time. The operation began by means of a little fire; but it soon became necessary to extinguish it, and even to cool the retort. The liquid remaining in the retort was analogous to that in the first-mentioned experiment. There was found upon the surface in all the flasks a yel- lowish liquid, and which, when collected, weighed 255 grammes. That contained in the first flask was a mixture of alcohol, ether, acetic acid, and nitrous acid ; that con- tained in the other flasks was nitric ether, free from alcohol. In this state the nitric ether possesses a strong smell ; it is specifically lighter than water, and heavier than alcohol ; it is dissolved in the latter in any proportion, but it requires nearly <18 parts of water to dissolve it, and yet the latter dis- solves it partly as we subsequently find. It presents in a strong degree the^roperties of combustible bodies. Never- theless, this ether strongly reddens turnsole tincture; and it owes this property to a little nitrous acid and acetic acid, Ms which ISO Report upon a Memoir on the Nitrous Ether » which it retains, and which we may separate from it by means of Hme. The volatiHty of the ether thus prepared is such, ihat the tension it indicates is 0-73 metres, while that of the best sulphuric ether in the same circumstances is no more than 0*46 metres, at 21° in the centigrade thermometer, and 0.*76' metres of atmospheric pressure. We see, therefore, that at this temperature and pressure it i5 at the limits of its ex- istence in th(5 liquid state. But if we can deprive the nitric ether of its acidity by means of lime, it hastens to become acid again, whether we distil it, leave it in contact with the air, or keep it in welt stopped battles. This formation of acid also takes place when we treat ether with water, particularly if the tempe- rature is from 25° to 30° of Reaumur. The author explains- the formation of the acid, by the reciprocal action of the principles which constitute ether, and which are there feebly retained by combination. M. Thenard afterwards proceeds to the decomposition of the nitric ether by heat, and he analyses the gases which proceed from it, founding his calculations upon the most exact data hitherto found : he obtains as a result, that 100^ Dirts of nitric acid is composed (laying aside fractions) of A^ote — 16 Carbon> — 39 Oxygen — 34 ^ Hydrogen — • J); From this^ he concludes what passes in the reciprocal ac- tion of alcohol and nitric acid. The oxygen of this acid ia combined with a great part of the hydrogen of the alcohol, and with a very small quantity of its carbon. From this there results, 1st, A great deal of water and gaseous oxide of azote, a litile caibonic acid, and a little nitrous gas and ni- trous acid; 2dly,The separation of a small quantity of azote> and the formation of a great deal of nitric ether, by the combination of a sufficiently large quantity of the two prin- ciples of the nitric acid with the de-hydrogenated and slightly decarbonized alcohol ; 3dly, The formation of a little acetic acid, and a small quantity of a substance which is- Report upon a Memoir on the Nitrous Elfier, 181 is easily carbonized by a combination of one part of hy■ C Weathef. Feb. 25 26 27 28 29 March 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 34' 30 40 38 45 47 49 47 83 35 33 32 32 32 32 32 33 38 35 34 37 32 32 32 40 36 36 31 33 25 32 37° 36 49 48 52 52 53 49 51 43 45 4i 38 43 41 42 39 42 41 44 41 34 34 37 47 39 41 36 36 36 42 30° 39 39 45 46 48 46 41 35 34 33 33 32 33 33 35 37 3b 35 36 32 29 29 36 40 37 30 31 29 32 35 30-69 •49 •38 •35 •15 •28 •31 •35 •44 •42 •42 •28 •28 •32 •34 •32 •30 •19 •10 29*99 •98 •99 •87 '6b 'bb '7b •92 . '92 •90 •92 •96 26 20 31 25 10 11 24 31 15 27 30 38 21 23 19 21 15 25 19 26 25 15 15 14 5 8 16 27 25 30 15 Fair Fair Fair Fair Cloudy Cloudy Cloudy Cloudy Fair Fair Fair Fair JFair Fair Cloudy Cloudy Cloudy Cloudy Cloudy Fair Fair Cloudy Cloudy Cloudy Cloudy Cloudy Fair Cloudy Cloudy Fair Fair N.B. The Barometer's height is tak^n atone o'clock. Xii I III 'I'.^.V: ^ [ 193 1 • *-^— »ir,0 ^« t ,. .J\tr . - fies them no less by reflection; which may be seen by foU bwing the course of the rays 6, 7, 2? 4, 5 ; for as they do not pass through the defective place of the lens, they can only receive their modification from it by reflection. This opens a field of view to us that leads to the cause of all these intricate phsenomena, of which in a second part of this paper I shall avail myself. < -Sjtj^^^y. N3 XXVI. Of 1 $8 Experiments for investigaihtg XXVI. Of the Action ef the third Snrfoce, When a double convex lens is laid upon a plain metalline mirror that happens to have an emery scratch in its surface, we see it as a black line under the rings that arc formed over them. This shows, that when a defect from want of polish has not a power to reflect light in an ii regular manner, it cannot distort the rings that are formed upon it. When I laid fi good 21 -feet object glass upon a plain slip that had some defects in its surface, the rings, in every part of the object glass that was brought over them, were always' disfigured ; which proves that a reflection from a defective third surface has a power of forming distorted rings, and that consequently a reflection from one that is perfect must have a power of forming rings without distortion, when it id combined with a proper second surface. When the defective slip of glass, with a perfect lens upon it, was placed uppn a metalline mirror, T saw the secondary stt affected by distortions of the rings that were perfectly like those in the primary set; which proves that a polished defect in the third surface will give modifications to the rays, that form the rings by transmission as well as by reflection. XXVII. The Colour of the reflecting mid transmitting Sur- faces is of no consequence. I laid seven 54-inch double convex lenses upon sevea coloured pieces of plain glass. The colours of the glasses were those which are given by a prism, namely, violet, indigo, blue, green, yellow, orange, and r^d. The rings yeflcctcd from each of these glasses were in every respect alike^ at least so far that I coxdd have a black, a white, a red, an orange, a yellow, a green, or a blue centre with every one of them, according to the degree of pressure I used. The lenses being very transparent, it may be admit- ted that the colours of the glasses seen through them would m some degree mix with the colours of the rings; but the action of the cause that gives the rings was not in the least affected by that circumstance. I saw the rings also by direct transmission through all the coloured glasses except a dark red, which stopped sq . "-"/y -. much the Cause ^ toloured concentric Rings, 199 much fight that I could nxrt perceive them. The co- lour of the glasses, in this way, coming directly to the eye, gave a strong tinge to the centres of the rings, so that in- sreadof a pure white I had a blueish white, a greenish white, and so of the rest ; but the form of the rings was no less perfect on that account. XXVIII. Of the Action of the fourth Surface. We have already seen that a set of rings may be com- pletely formed by reflection from a third surface, without the introduction of a fourth : this, at all events, must provt that such a surface is not essential to the formation of rings ; but as not only in direct transmission, but also When two sets of rings are to be seen, one of which may be formed by transmission, this fourth surface must be introduced, I have ascertained by the following experiments how far the same has any share in the formation of rings. jotll In direct transmission, where the light comes from l)e- low, the fourth surface will take the part which is acted by the first, when rings are seen reflected from a metalline mirror. Its office therefore will be merely to afford an en- trance to the rays of light into the substance of the subjii^ cent glass ; but when that light is admitted through the iirst, second, and third surfaces, the fourth takes the office of a reflector, and sends it back towards the poirit of con- tact. It will not be required to examine this reflection, since the light thus turned back again is, with respect to the point of contact, in the same situation in which it was after its entrance through the first surface when it proceeded to the same point ; but when two sets of rings are to be formed by rays, either coming through this point dirfcCtly towards the fourth surface, or by reflection from the same point towards the place where the secondary rings are to be seen, it will then be necessary to examine whether this sur-^ face has any share in their formation, or whether these rings, being already completely formed, are only reflected by it to the eye. With a view to this, I selected a certain polished defect in the surface of a piece of coach-glass, and when :MAA. N4 a 26-inch (UPD ETpetiments for investigating ' ^ a 56- inch lens was laid upon it, the rings of the set it pro- duced were much distorted. The lens was then put upon a perfect slip of glass, and both together were laid upon the defective place of the coach-glass. The rings of the secon- dary set reflected by it were nevertheless as perfect as those of the primary set. It occurred to me that these rings might possibly be reflected from the lowest surface of the perfect slip of glass, especially as by lifting it up from the coach- glass I still continued to see both sets. To clear up this point, therefore, I took away the slip, and turning the de- fective place of the coach -glass downwards, produced a set of perfect rings between the lens and the upper surface of the coach-glass, and brought it into such a situation that a secondary set must be reflected from the defective place of the lowest surface. This being obtained, the rings of this set were again as well formed and as free from distortions as those of the primary set. Upon a plain metalline mirror I laid down two lenses, 'one a plano-convex, the other a plano-concave, both of 2*9 inches focus, and having the plain side upwards. When two 21 -inch double convex glasses were laid upon them, the secondary sets of both the combinations were of equal size, and perfectly like their primary sets ; which proves that the refraction of the fourth surface is either not at all concerned, or at least has so little an effect in altering the size of the rings that it cannot be perceived. The result of the foregoing experiments, relating to the action of the several surfaces, is, I. That only two of them are essential to the formation of concentric rings. II. That these two must be of a certain regular construc- tion, and so as to form a centra! contact. III. That the rays from one side or the other, must either pass through the point of contact, or through one of the sur- faces about the same point to the other to be reflected from it. IV. And that in all these cases a set of rings will be formed, having their common centre in the pl^ce where the two surfaces touch each other. XXIX. Coa- ike Cause of coloured concentric Rings. 201 Considerations t/tat relate to the Cause of the Forma- tion of concentric Rings. It is perfectly evident that the phseiiomena oF concentric rings must have an adequate cause, either in the very nature or motion of the rays of light, or in the modifica- tions that are given to them by the two essential surfaces that act upon ihem at the time of the formation of the rings. This seems to reduce the cause we are looking for to an alternative that may be determined ; for if it can be shown that a disposition of the rays of light to be alternately re- flected and transmitted cannot account for the phaenomena ■which this hypothesis is to explain, a proposition of ac- counting for them bv modifications that may be proved, even on the very principles of Sir I. Newton to have an ex- istence, will find a ready admittance. I propose, therefore, now to give some arguments, which will remove an obsta- cle to the investigation of the real cause of the formation of the concentric rings ; for after the very plausible supposi- tion of the alternate fits, which airrees so wondcrfullv "weli with a nuniber of facts that have been related, it will hardly be attempted, if these should be set aside, to ascribe some other inherent property to the rays of light, whereby we might account for them ; and thus we shall be at liberty to turn our thoughts to a cause that may be found in the mo- difications arising from the action of the surfaces which have been proved to be the only essential ones in the forma- tion of rings. XXX. Concentric Rings cannot he formed Ij/ an alternate Reflection and Transmission of i lie Rays of Light. One of the most simple methods of obtaining a set of concentric rings is to lay a convex lens on a plain metalline mirror ; but in this case we can have no transmission of rays, and therefore we cannot have an alternate reflectioo and transmission of them. If to get over this objection it should be said that, instead of transmission, we ought to substitute absorption 5 since those rays which ifi glass woulii have SOS ^xp^iments/orinvestigaimg have been transmitted will be absorbed by the metal, we may admit the elusion ; it ought however to have bten made a part of the hypothesis. XXXI. Alternate Fits of easy Reflection and easy Trans- mission, if' they exist, do not exert themselves according to various Thicknesses of thin Flates of Air, In the following experiment, I placed a plain well po- lished piece of glass 3*6 inches long, and 2*3 thick, upon a plain metalline mirror of the same length with the glass ; and in order to keep the mirror and glass at a distance from each other, I laid between them, at one end, a narrow strip of such paper as we commonly put between prints. The thickness of -that which I used was the 6l0th part of an inch; for 128 folds of them laid together would hardly make up two-tenths. Upon the glass I put a 39-inch double convex lens ; and having exposed this combination to a proper light, I saw two complete sets of coloured rings. In this arrangement, the rays which convey the secondary set of rings to the eye must pass through a thin wedge of air ; and if these rays are endowed with permanent fits of easy reflection, and easy transmission, or absorption, their exertion, according to Sir I. Newton, should be repeated at every different thickness of the plate of air, which amount^ to the y-ir4<3ir P^i't of an inch, of which he says *' Haec est crassitudo aeris in primo annulo obscure radiis ad perpendi- culum incidentibus exhibito, qua parte is annulus obscuris- simus est." The length of the thin wedge of air, reckoned from the line of contact, to the beginning of the interposed strip of paper, is 5*2 inches, from which we calculate that it will have the above-mentioned thickness at -J^ of an inch from the contact ; and therefore at -^, -^, -^^, ^, -^f^ ^-|-, &c. we shall have the thickness of air between the mirror and glass, equal to tW^^, TT-^oins-^ -rr^'oinr* tt^oo o> &c. of which the same author says that they give ^^crassitudines aeris in omnibus annulis lucidis, qua parte illi lucidissimi sunt.'' Hence it follows that, according to the above hy- pothesis, the rings of the secondary set which extended 8 over 'th^ Cause of coloured coTwentr'w Rings, SOS- over a space of '14 of an inch, should suffer more than seven interruptions of shape and colour iu the direction of the; wedge of air.. .^^.^..y/ In order to ascerUin whether such an effect had any ex^ i^tence, I viewed the secondary set of rings upon every part of the glass-plate, hy moving the convex lens from one end of it gradually to the other; and my attention being parti- cularly directed to the 3d, 4th, and 5th rings, which were extremely distinct, I saw them retain their shape and colour all the time without the smallest alteration. The same experiment was repeated with a piece of plain glass instead of the metalline mirror, in order to give rooni for the fits of easy transmission, if they existed, to exert themselves; but the result was still the same ; and the con- stancy of the brightness and colours of the rings of the secondary set, plainly proved that the rays of light were not affected by the thickness of the plate of air through which they passed. XXXI T. Alternate Fits of easy Reflection and easy Trans^ " mission, if' they exist, do not exert themselves according to various Thicknesses of thin Plates of Glass. I selected a well polished plate of coach-glass 1 7 inches long, and about 9 broad. Its thickness at one end was 33, and at the other 31 two-hundredths of an inch ; so that in its whole length it differed -J-^ of an inch in thickness. By measuring many other parts of the plate I found that it was very regularly tapering from one end to the other. This plate, with a double convex lens of 55 inches laid upon it, being placed upon a small metalline mirror, and properly exposed to the light, gave me the usual two sets of rings. In the secondary set, which was the object of my attention^ I counted twelve rings, and estimated the central space be- tween th^pi to be about J -^ times as hroacj as the space taken up by the 1 2 rings on either side ; the whole of the space taken up may therefore be reckoned equal to the breadth of 40 rmss of a niean size : for the 12 rings, as usual, were gra- dufuly contracted in breadth as they receded from the centre j and, by a measure gf the whole space thus taken up, I found 204 T xperimcnt$ for investigating found that the breadth of a rin^ of a mean size was about the 306th part of an inch. Now, according to Sir I. Newton's calculation of the ac- tion of the fits of easy reflection and easy transmission in thick glass plates, an alternation from a reflecting to a trans- mitting fit requires a difference of yj-^Vrr part of an inch in thickness*; and by calculation this diflfercnce took place in the glass plate that was used at every 80th part of an inch of its whole length : the 12 rings, as well as the central colour of the secondary set, should consequently have been broken by the exertion of the fits at every 80th part of an inch ; and from the space over which these rings extended, which was about '13 inch, we find that there must have been more than ten such interruptions or breaks in a set of which the 308th part was plainly to be distinguished. But when I drew the glass plate gently over the small mirror, keeping the secondary set of rings in view, I found their shape and colour always completely well formed. This experiment was also repeated with a small plain glass instead of the metalline mirror put under the large plate. In this manner it still gave the same result, with no other dif» ference but that only six rings could be distinctly seen in the secondary set, on account of the inferior reflection of the subjacent glass. XXXIII. Coloured Rings may he completely formed without the Ass'istance of any thin or thick Plates, either of Glass or of Air, The experiment I am now to relate was at first intended to be reserved for the second part of this paper, because it properly belongs to the subject of the flection of the rays o£ light, which is not at present under consideration ; but as it particularly opposes the admission of alternate fits of easy reflection and easy transmission of these rays in their pas- sage through plates of air or glass, by proving that their assistance in the formation of rings is not rcijuired, and also throws light upon a subject that has at diflferent times been * Newton's Optics, p. 277. considered th^fyuse of. coloured concentric Rings, SOS considered by some of our most acute experimentalists, I have used it at present, though only in one of the various arrangements, in which I shall have occasion to recur. Uv it hereafter. Sir I. Newton placed a concave glass mirror at double its focal length from a chart, and observed that the reflection of a beam of light admitted into a dark room, when thrown upon this mirror, gave *^ four or five concentric irises or rings of colours like rainbows*." He accounts for them by alternate fits of easy reflection and easy transmission ex- erted in their passage through the glass- plate of the con- cave mirror f. The duke de Chaulncs concluded from his own experi- ments of the same phaenoraena, " that these coloured rings depended upon the first surface of the mirror, and that the second surface, or that which reflects them after they had passed the first, only served to collect them and throw them upon the pasteboard, in a quantity sufficient to make them visible J.'* Mr. Brougham, after having considered what the two authors I have mentioned had done, says, ^* that upon the whole there appears every reason to believe that the rings are formed by the first surface out of the light which, aj'ter re- flection from the second surface, is scattered, and passes on to the chart §.'' My own experiment is as follows, I placed a highly po- lished 7-feet mirror, but of metal instead of glass, that I might not have two surfaces, at the distance of 14 feet from a white screen, and through a hole in the middle of it one- tenth of an inch in diameter I admitted a beam of the sun into my dark room, directed so as to fall perpendicularly on the mirror. In this arrangement the whole screen remained perfectly free from light, because the focus of all the rays which came to the mirror was by reflection thrown back into the hole through which they entered. When all was duly prepared, I made an assistant strew some hair-powder ♦ Newton's Optics, p. 2G5. f Ibid. p. 577. \ Priestley's History, &c. on the Colours of thin Plates, p. 515- § Philosophical Transactions for 1796, p. SI 6. .. : P^ with 50(J Erpermentsfor invest'} ^aibig, &c, tvith a puflT into the beam of light, while t kept my atten- tion fixed tipon the Screen. As soon as the hair-powde^ reached the beam of hght the screen was suddenly covered with the most beautiful arrangement of concentric circles displaying all the brilliant colours of the rainbow. A great variety in the size of the rings was obtained by making the Assistant strew the powder into the beam at a greater distance from the mirror; for the rings contract by an increase of the distance and dilate on a nearer approach of the powder. This cxpei-imcnt is so simple, and points out the genera! Causes of the rmgs which are here produced in so plain a man^ ner, that we may confidently say they arise from the flection of (he rays of light on the particles of the floating powder, mo- dified by the Curvature of the reflecting surface of the mirror. Here we have no interposed plate of glass of a given thickness between one surface and another, that might pro- duce the colours by reflecting some rays of light and trans- mitting others; and if \Ve were inclined to look upon the distance of the particles of the floating powder from the mirror as plates of air, it would not be possible to assfgn any certairi thickness to them, since these particles may be Spread in the beam of light over a considerable space, and perhaps none of them will be exactly at the same distance from the mirror. I shall not enter into a further analysis of this experi* ment, as the only purpose for which it is given in this place is to show that the principle of thin or thick plates, either of air or glass, on which the rays might alternately exert their fits of easy reflection and easy transmission, must be given up, and that the fits themselves of course cannot be shown to have any exisistence. XXXIV. Conclusion. It will hardly be necessary to say, that all the theory re- lating to the size of the parts of natural bodies and their in- terstices, which Sir I. Newton has founded upon the e:ti^- tence of fits of easy reflection and easy transmission, exerted differently, according to the different thickness of the thin plates of which he supposes? the parts of natural bodies to consist. On Machines in General* koi consist, will remain unsupported ; for if the above-men- tioned fits have no existence, the whole foundation on which the theory of the size of such parts is placed, will be taken away, and we shall consequently have to look out for a more firm basis on which a similar edifice may be placed. That there is such a one we cannot doubt, and what 1 have already said will lead us to look for it in the modifying power which the two surfaces, that have been proved to be essential to the formation of rings, exert upon the rays of light. The second part of this paper, therefore, will enter into an examination of the various modifications that light receives in its approach to, entrance into, or passage by, differently disposed surfaces or bodies ; in order to discover, if possible, which of them may be the immediate cause of the coloured rings that are formed between glasses. XLIII. Essay upon Machines in General, Bij M. Carnot, Member of the French Institute, ^c. ^c, [Continued from p. 158.] X. J. HE science of machines in general is therefore re- duced to the following question r ** Being acquainted with the virtual movement of any system of bodies {that is to say,, that movement which each of these bodies tvaidd take if it ivere free), find the real move^ ment which will take place the instant following, on account of the reciprocal action of bodies^ by considering them suck as they exist in nature y i.e. as endowed with all the inertness common to all the particles of matter,** ;/ Wij) I XI. Now, as this question evidently contains, the whole of mechanics, we must, in order to proceed with precision,. go back to the first laws which nature, observes in the com- munication of movements. We may reduce them in general to two, which are the following : FUNDAMENTAL LAWS OF EQUILIBRIUM, AND MOTION. First Law.— ^c^iow and Reaction are always equal and contrary. This fiOS On Machines in GeJicraL This law consists in this, that every body which changes its state of repose or uniform and rectilinear motion, never does sd except by the influence or action of some other body, upon which it impresses, at the same lime, a <}iianlity of motion eqnal and directly opposite to that which it receives from it ; that is to say, that the velocity it assumes the instant afterwards is the force resulting from that which this other body impresses upon it, and from that which it would have had without this last force. Every body therefore resists Its change of state ; and this resistances^ which is called vis inerticey is always equal and directly op-; posite to the quantity of motion it receives, i, e. to the quantity of motion which combined with that which it had immediately before the change, produces, as the result, the quantity of motion which it should really have im- mediately afterw-ards. This is also expressed by saying, that in the reciprocal action of bodies, the quantity of mo- tion lost by the one is always gained by the others, in the fame time and in the same ratio. Sfxond Law. — IVhen two hard bodies act upon each other, hy shock or pressure, i. e. in 7'irtue of their inpene- trabiliti/, their relative velocity y immediately after the reci- procal action, is always juilL In fact, we constantly observe, that if I wo hard bodies give a shock to each other, their vefocities, immediately after the shock, estimated perpendicularly to their commoft surface at the point of contact, are equal, in the same way as if they were drawn by inextensihle wires, or pushed by incompressible rods ; their velocities, estimated in the ratio of this wire or rod, would necessarily be equal : whence' h follows that their relative velocity, e. e, that by. which they approach or recede from each other, is in every case null at the hrst instant. From these two principles it is easy to draw the laws of the shock of hard bodies, and consequently to conclude the two other secondary principles, the use of which is continual in mechanics, viz. 1. That the intensity of the shock, or of the action which 18 I On Machines in General. 20$^: id exercised between two bodies which meet, does not de-' pend upon their absolute movements, hut solely upon their^ relative movements. 2. That the force or quantity ofmov^-^^ ment which they exercise upon each other, hy the shock, is' always directed perpendicularly to their common surface at the point of contact. ^>Vi3biP XII. Of the two fundamental laws, the first generally agrees with all the bodies of nature, as well as the two se- condary laws which we have seen ; and the second solely regards hard bodies ; but as those which are not hard have different degrees of elasticity, we generally refer the laws of their movement to those of the hard bodies, which we take for a term of comparison, i. e. we regard the elastic bodies as composed of an infinity of hard corpuscles separated by small compressible rods, to which we attribute all the elastic virtue of these bodies ; so that, properly speaking, we do not consider in nature any other than bodies endowed with different moving forces. We shall follow this method as the simplest : we shall therefore reduce the question to the investigation of the laws observed by hard bodies, and shall afterwards make some applications of them to cases in which bodies are endowed with different degrees of elasticity. XIII. This essay upon machines not being a treatise upon mechanics, my object is not to explain in detail, nor to prove the fundamental laws I have related ; these are truths which all the world knows, as to which they are generally agreed, and which are most strongly manifested in all the phsenomena of nature. This is sufficient for my object, which is merely to draw from these laws a simple and exact method for finding the state of rest or of move- ment which results from them in any given system of bo- dies, i. e, to present the same laws under a form which may facilitate their application to each particular case. XIV. Let us suppose therefore any system of hard bo- dies, the virtual given movement of which is changed by their reciprocal action into another which we wish to find ; and in order to embrace the question in all its extent, l?t us suppose that the movement may either change suddenly, or ; Vol. 30. No. 119.^/?n7 1808. O vary S^Qf, On MacUnes In General. vary by in&enslbilip degrees : finally, as fixed points or some obstacles may be met with, let us consider them as they really are,ii^;fi§i,9tj that is to say, as ordinary bodies of them- selves,^ i^ali^ing ,pfirt of the system proposed, but firmly ar- rested iu.the spot where they are placed. XV. In order to. attain the solution of this problem, let u^^fi/^t,of3^eurv;e, tlxat, all the parjti^^-oi;' the system being sup- posed perfectly hard, i. e. incompressible and inextensible, we may visibly, whatever it may be, regard it as composed of an infinity of hard corpuscles, separated from each other either by small incompressible rods, or by small inextensible wjres;. for when two bodies strike, push, or tend in gcne- rjj. to approach each- other without being able to doit, on account of their impenetrability, we can conceive between tl)e two a small incompressible rod, and suppose that the njp.Vemj^pt^^ is,trau&miUed From the one to the other accord- ing to this rod : and in the same way, if two bodies tend to separate, we may conceive that the one is attached to the other by a small inextensible wire, according to which the movement is propagated : this being done, let us conjider successively, the action of each of these small corpuscles upon all those which are adjacent to it, i, e. let us examine two by two all these small corpuscles separated from each other by a small incompressible rod, or by a small inextensible wire, and we shall sec what ought to result in the general system of all these corpuscles. Let us name for this purpose, 77/ and m" The masses of the adjacent corpuscles. V and V' The velocities they ought to have the follow-^ ing instant. F' The action of m^^ upon m\ that is to say, the force or quantity of movement which the first of these cor- puscles imprt-sses upon the other. F'' The reaciion of ?»' upon ni\ q[ and q' The angles formed by the directions of V and F and by thJse of V' and F^'. This being done, the real velocity of m' being V, this velocity estimated in the direction of F will be \' cosine q*; in the same manner the velocity of tt^' estimated in the direction of V will be W^ cosine g". Therefore, since by the On Machines in General, 211 the second fundamental law bodies should go in company* we shall have V cosine q' + V" cosine q" = 0 (A) : thus by the first fundamental law, we shall also have F' V co- sine q' + F" V" cosine q" t^ 0 (B) : for if m' and rti!' are both moveable, it is clear, by this law, that we have F" = F"; therefore on account of the equation (A) we shall also have the equation (B) ', anal if one of the two, 7n' for instance, be fixed, or form part of an obstacle, we shall have V co- sine ^' = o ; therefore on account of the equation (A) we shall also have Y" cosine^' = 0^ therefore the equation (B) will still take place : therefore this equation (B) is true for all the corpuscles of the system taken two by two. Imagining therefore a similar equation for all these bodies taken in fact two by two, and adding tT)gether all these equa- tions, or, what comes to the same »hing, the integral equa- tion (B), we shajl have for the whole system, s Y' V' cosine q' -{• s ¥' V" cosine ^" = o : that is to say, the sum of the products of the quantities of movement which are reciprocally impressed by the corpuscles separated by each of the small inextensible wires or incompressible rods; from these quantities, I say, each of them multiplied by the velocity of the corpuscle on which it is impressed, estimated in the direction of this force, is equal to zero. This being done, abandoning the preceding denomina- tions, let us name The mass of each of the cc^rpuscles of the system - m Its virtual velocity, i. e. that which it would assume if it were free, ------- W Its real velocity - - - - - - V The velocity which it loses in such a manner that \V is the result of V and of this velocity - - U The force or quantity of movement which each of the adjacent corpuscles impresses upon tti, and by the inter- medium of which it evidently receives all the move- ment that' is transmitted to it from the different parts of the systQm, -- - - • - -F The antvle comprehended between the directions of W 'and> - - X The angle comprehended betweea the directions of WandU Y 0 2 Tbc 212 On Machines in General, The angle comprehended between the directions of V and U - Z The angle comprehended between the directions of V and F q We shall therefore have for the whole system 5 F V co- sine q = Of or sV F cosine ^ = 0 (C) : at present we must observe that, the velocity of 7S before the reciprocal action being \V, this velocity estimated in the direction of V will be W cosine X ; therefore V— W cosine X is the velocity gained by m in the direction of V: therefore m (V — W cosine X) is the sum of the forces F which act upon 7n, estimated each in the direction of V : therefore m and V (V — W cosine X) is the same smn multiplied by V, Now to each molecule a similar sum answers ; and further, the sum total of all these particular sums is visibly for the whole system ^ V F cosine q ; therefore s mY (V — W cosme X) = s FV cosine q : adding to this equation the equation (C), there comes 5 m V (V — W cosine X) = O (D) ; but W resulting from V and U, it is clear that we shall have W cosine X = V 4- U cosine Z : substituting therefore this value of W cosine X in the equation (D), it will be reduced to 5 m V U cosine Z = 0 (E) ; first funda^ mental equation. XVI. Let us imagine that at the moment when the shock is about to be given, the actual movement of the system is at once destroyed, and that we make it take instead of it successively two other arbitrary movements, but equal and directly opposite to each other, i, e, let us make it set out successively from its actual position, with two movements, such that, in virtue of the second, each point of the system has at the first instant a velocity equal and directly opposed to that which it would have had in virtue of the first of these movements: this being done, it is clear, 1st, That the figure of the system being given, this may be done in an infinity of different ways, and by operations purely geome- trical ; this is the reason why I shall call these movements geometrical movements ; i. e. that if a system of bodies sets out from a given position with an arbitrary movement ^ but 7jet of such a nature that jt is possible to make it take another ?n every respect eqiial and directly opposite^ each of these movementi. On Machines in General, 213 movemejits will he named a geometrical movement *, 2dly, I say that in virtue of this geometrical movement, the adja- cent corpuscles, which may be regarded as being pushed by a rod, or drawn by a wire, will not approach nor recede from each othe.r at the first instant, i. e. at the first in- stant of this geometrical movement the relative velocity of these adjacent corpuscles will be nothing : in fact, it is clear, in the first place, that if m be separated from an ad- jacent corpuscle by an incompressible rod, it will not be able to approach it ; and that if it be separated from it by an inextensible wire, it will not be able to recede from it : secondly, I say that if it be separated from it by an in- compressible ♦ In order to disdnguish by a very simple example those movements called geometrical from those which are not so, let us imagine two globes which push each other, but in other respects free and disengaged from ever^ obstacle : let us impress upon these globes equal velocities, and moved in the same direction according to the line of the centres ; — this movement is geomt' trical, because the bodies could even be moved In a contrary direction with the same velocity, as is evident : but let us now suppose that we impress upon these bodies movements equal, axKl directed in the line of the centres, but which, in place of being, as formerly, moved in the same direction, tend on th« contrary to recede from each other ; these movements, although possible, are not what I mean by geometrical movements ; because if we wished to make each of these moveable powers to assume a velocity equal and contrary to that which it receives in this first movement, we should be hindered fronj doing so by the impenetrability of bodies. In the same way if two bodies are attached to the extremities of an inex- tensible wire, and if we make the system assume an arbitrary movement, but so as that the distance of the two bodies may be constantly equal to the length of the wire, this movement will be gcometricaly because the bodies may as- sume a similar movement in quite a contrary direction ; but if these moveable bodies approach to each other, the movement is not geometrical, because t]»«y could not take a movement equal and contrary without receding from each other; which is impossible on account of the inextensibility of the wire. In general it is evident, that whatever be the figiire of the system and the number of bodies, if we can make it assume a movement so as there should result no change in the respective position of the bodies, this movement will be geometrical ; but it does not follow from this that there is no other me- thod of satisfying this condition, as we shall show from several examples. Let us imagine an axle, to the wheel and cylinder of which are attached weights suspended by cords : if we turn the machine in such a manner that the weight attached to the wheel should descend from a height equal to its circumference, while that of the cylinder will ascend from a height equal to its circumference, this movement wiU be gFometricali because it is equally 0 3 possible 214 On Machines in General, compressible rod, it cannot recede from it any more ; for, if it receded, it is clear that in virtue of the equal and directly opposite movement, which is also possible by hy- pothesis, it would approach it ; which could not be on ac- count of the inconipressibility of the rod : for the same, reason finally it is obvious, that if it he a wire which sepa- rates m from the adjacent corpuscle, it will not approach, because then it would be possible to remove it by an equal and directly opposite movement : now this cannot be, on account of the inextensibility of the wire : therefore, what- ever may be the geometrical movement impressed upon the possible to make the weight attached to the cylinder descend from a height equal to its circumference, while the weight attached to the wheel would mount from an equal height to its circumference^ but if while we cause th? weight attached to the wheel to descend from a height equal to its circumfe- rence, wp should cause the weight attached to the cylinder to ascend from a height greater than its circumference, the movement would not be ^cnmctricalf because the equal and contrary movement would be visibly impossible. If sevjral bodies be attached to the extremities of different wires united by the other extremities to one and the same knot, and if we make the system assume such a movement as that each of the bodies remains constantly re- moved from the knot of one and the same quantity at t'le length of the wire to which it is attached, this movement will be geometrical, even when the different bodies approach to each other; but if some of them approach the knot, the movement would not be geometrical, because, the wires being sup-r posed to be inextensible, the equal and contrary movement would be visibly impossible. If two bodies are attached to the extremities of a wire into which is intro- duced a moveable particle, it will be sufficient, in order that the movement be geometrical, that the sura of the distances from the moveable particle to each of the two other bodies is constantly equal to the length of the wire ; so that if these two bodies are fixed, the moveable particle will not depart from an elliptical curve. If a body be moved by a curved surface, for instance, in the concavity of a spherical shell, the movement will be geometrical, while the body will move in a tangent form to the surface •, but if it be separated the movement will cease to be geometrical, because the equal and contrary piovempnt is visibly impossible. Vrom all this it is evident, that although on giving to a system a. geometrical movement, the different bodies of this system may be brought near to each other, yet we may say that the adjacent corpuscles, considered two by two, do not tend at the first instant cither to approach or recede, as I shall prove at length in the text. Bodies therefore exercise no action upon each olher in virtue of a similar movement : these movements are therefore absolutely in- dependent of the rules of dynamics, and it is for this reason that I have called them geometrical. " system. On Machines in GensraL ^515 system, the relative velocity of all these adjacent corpilstlfcs which act upon each other^ taken two by two^ will be tid- ihing at the rirst instant. This being granted, let us callow the absolute velocity which m will have in the first rnstant, in virtue of this geometrical movement, and z the angle coiii- prehended between the directions of tc and U ; it is clclir that the corpuscles m will not tend to approach or recede from each other in virtue of the velocities 2/, if we su'ppose them animated at the same time with these velocities u and velocities U ; nor will they tend more to approach or recede if animated with the mere velocities U : thcretbrc the re- ciprocal action exercised among the different parts of the system will be the same, whether each molecule be anima- ted with the sino-|e velocitv U, or with the two velocities u and U : but if each molecule was animated with the single velocity U, it is plain that there would be equilibrium': thus, if it was animated at once with the two velocities U and ?/, or with a single velocity the result of both, U will still be the velocity lost by tn ; and u will be the real velocity after the reciprocal action : thus, by the same reasoning by which we had the fundamental equation (E) we shall also have srritiU cosine z = 0 (F) ; second fundamental equa- tion. It is very easy at present to resolve the problem which we propose for the preceding equation necessarily taking place, whatever be the value of u and its direction, provided the- movement to which it refers be geometrical : it is clear that by successively attributing to that indeterminate different values and arbitrary directions, we shall obtain all the ne- cessary equations among the unknown quantities, upon which depends the solution of the problem and of quantities either given or taken at pleasure. XVII. In order to place this solution in the clearest light, • it will be sutlicient to give an example of it. Let us suppose therefore that tlie whole system is reduced to an assemblage of bodies united to each other by inflexible rods, in such a manner that all the parts of the system should be forced always to preserve their same respective 0 4 positions; •.fJL6 On Machines in General. , positions; but that there is no fixed point or any obstacle; . ,the equation (F) gives us the solution of this problem on ^attributing successively to 7i different values and directions. |,, 1st. As the velocities 2/. are not subjected to any condi« ^lion, unless the movement of the system in virtue of which .Ithe corpuscles m have these velocities be geometrical, it is .jCvident that we can at first suppose all of them equal and pa- ,,Tfillel to one given line : then u being constant, or the same ij^ith respect to all the points of the system, t]»e equation (F) .will be reduced to s m U cosine 2: = 0; which informs us that the sum of the forces lost by the reciprocal action of the bodies in the aibitrary sense of u is null, and that conse- quently that which remains is the same as if each body had been free; this is a well-known principle, Sdly. Let us now imagine that we make the whole system turn round a given axis, so that each of the points will de- scribe a circumference round this axis, and in a plane which shall be perpendicular to it ; this movement is visibly geo- metrical; therefore the equation (F) takes place: hut then on calling R the distance from vi to the axis, it is clear that we have 21 = AR'', A being the same for all the points ; therefore the equation (F) is reduced to 5 w R U cosine z — 0; that is to say, that the sum of the momenta of the forces lost by the reciprocal action relatively to any axis is null ; this is another well-known principle, 3dly. We might also attribute to u other values ; but this would be useless, and might lead to equations already pon- tained in the preceding; for we know that the latter are sufficient for resolving the question, or at least fqr reducing it to a matter cf pure geometry. First Remark, XVI IT. The object we propose by giving a geometrical movement is to change the state of the system, without al- tering however the reciprocal action of the bodies which compose it, in order i hereby to procure relations between these exercised and unknown forces and the arbitrary velo- cities which bodies assume in virtue of these different geo- metrical On Machines in General. 217 metrical movements : but it must be remarked that there \^ a case where geometrical movements are not the only ones which can answer the same purpose, and where some other movements may be employed in the same way, in order to extract from the general equation (F) determinate equations: this happens when these other movements, without being absolutely geometrical, become so, nevertheless, merely on suppressing some of the small wires or rods we have sup- posed to be interposed between the adjacent particles of the system, at the time, I say, when these rods or wires supposed to transmit the movement from one corpuscle to another, transmitted none at all in fact ; i. e, when the tension of some of these wires, or- the pressure of some of these rods, is equal to zero ; for then by suppressing these wires or rods, the tensions or pressures of which are null, we evi- dently change nothing at all of the reciprocal action of the bodies, and nevertheless it is possible that we may thereby render the system susceptible of some geometrical move- ments,which could not otherwise take place : there is nothing therefore to prevent us from regarding these rods and wires as annihilated, since they have no influence upon the state of the system ; and as we consequently employ as geometrical the movements which, without being so effectively, become so nevertheless by this suppression. Further, when two bodies are contiguous to each other, it is evidently the same thing to suppress the small rod which we have imagined 'to be interposed between two, to hinder them from approaching, or to suppose that these bodies are permeable to each other^ i. e. that they may be penetrated as easily as the empty space is penetrated by all bodiesf; whence it evidently follows, that in general, in any gystem of bodies acting upon each other, immediately or by wires and rods, i. e. by the intermedium of any machine, if there be any wire, rod, or other part of the machine which exercises no action upon bodies applied to it, i, e, which may be annihilated without any change resulting in the reciprocal action of these bodies, we shall be able to treat as geometrical all the movements which, without being so effectively, would becopae sq by this suppression, iu 5V8 On Machines in General, in the same way as those which would become so also, re- garding as freely perTneable to each other, those of the bodies among which no pressure is exercised, although they Are adjacent. l>ie,iof]owing, however, shows the utility of this observation : If, when we undertake the solution of any piobleni, we know beforehand that a certain part of the machine does not exercise any actioa upon the other parts of the system, we shall be able to suppose that this part of the machine is totally annihilated, and ascertain the movement of the sy* ^tem according to this hypothesis, i. e. by treating as geo- metrical all the movenw.nts which would really become so by this supposiiion ; and in the same way, if one of the given conditit)ns of the problem is, that certain adjacent bodies d« not exercise any p e^^sure upon each other, we shall express this condition by regarc^ng these two bodies as permeable to each other, i, e. by treating as geometrical the move- ments which would in fact become so by this supposition. But if it happens that we arc ignorant whether this pres- sure be real or null, wc must ascertain the movement of the system, by first supposing the one or the other at plea- 6ure : we shall suppose therefore, for example, that this' pressure is real : then, if on inquiring, according to this hypothesis, the value of this pressure, we find it real and positive, we shall conclude that the hypothesis is legitimate, and the exact result; or else we shall be assured that the pressure in question is null, and that we may consequent- Iv treat as geometrical^ motions which would become so in fact, iF the two bodies in question were freely permeable to each other. Further, if there was a machine in the system, a wire for example, and that we were ignorant if the tension of this wire is null or real, we might make the calculation by at first supposing that there really is tension ; then, if we find for the value of this tension a real and positive quantity, we shall conclude that the supposition is legitimate, and that the result is exact; or else, we must recommence the cal- culation, setting out from the conh-ary supposiiion, i. e, guppGsing that the tension of the wirc is equal to zero; . which ( On Machines in GeneraL 21 D xvbich will be done by supposing the wire annihilated, i. e. by treating as geometrical the motions which would be so effectively if the wire in question did not exist. From this it follows, that in order to extract in each par- ticuJar case from the general equation (F) all the determi- nate equations which it can give, we must first make the system assume all the geometrical movements of which it is susceptible; secondly, to treat also as such all those which would become so by suppressing some machine or part of a machine, the action of which upon the rest of the system is null, or by regarding as permeable to each other, the bodies among which, although adjacent, no pressure is ex- ercised. 3dly. In the last place, if we are in doubt whether a certain wire, rod, or any part of the machine has or has rot a real action upon the other parts of the system, or that there was a real pressure between two adjacent bodies, we must first clear up this doubt, by supposing the thing in question as we have above explained it, and by treating as • geometrical the movements which these suppositions shall have discovered as being capable of being taken for such. According to this remark, it seems proper therefore to extend the name of geometrical, to all the movements, which, without being so effectively, become so on suppress- ing some machine or part of a machine which has no in- fluence upon the state of the system, and on regarding also as perfectly permeable to each other, bodies in contact, without any pressure being exercised among them, i. e, without there being any ihing except a simple juxtaposi- .tion : thus we shall presently comprehend all these move- ments, under the title of geometrical movements, since in tact they are equally well determined by operations purely geometrical, and are employed in the same way for extract- ing from the general equation (F) determinate equations, ^whilc the general and exclusive property* of these move- ments * It Is evident that this property belpngs successively to the movements -'vvhlch I here cali geometrical, and that it woyld consequeutly be a very false idea of them to regard them as movements simply possible, i.e. compatible with the iiDpen«trability of matter: for, suppcsi rg, lor instance, that all the syatena 930 On Machines hi General, ittents is ta change the state of the system, without altering the reciprocal aptioii of the bodies which compose it. To leave, however, some distinction between them, we may Call the first ahsolute geometrical movemciitSy and the others geoinetrkal movements hy supposition: but when I speak simply of geometrical movements, without otherwise de- signing them, I shall imply both indifferently. This being done, — since we have explained how we may determine, without the assistance of any mechanical prin- ciple, all the geometrical movements of which a given sy- stem is susceptible, it follows that the general problem which we proposed is entirely reduced by the general equation (F) to operations purely geometrical and analytical : we must, however, observe, that it is not sufficient to attribute to the arhitrarles u different values, but we must also attribute to them different relations or directions; for, if we are con- tented to attrii)ute different values to them without changing any thing in the relations or directions, we should obtain different equations, quite true and correct, but which would be evidently reduced to the same on multiplying them by different constants. Second Remark, XIX. As we are only speaking of hard bodies here, it is clear that among the different values which we may attri- bute to u, the velocity V is itself comprehended ; i, e. that the real movement of the system is itself one of the geome- trical movements of which it is susceptible : the first equa- tion (E) is therefore contained in the indeterminate equa- tion (F), and consequently we may reduce to this single equation (F) all the laws of equilibrium and of movement in hard bodies. Now we have seen, that this equation is nothing else than the first (E), to which we have succeeded in giving system be reduced to two adjacent globes, and pushing each other, i t is clear, that if we force these bodies to separate or to move in a direction contrary to each other, this movement will not be impossible, but that at the same tiqie bodies cannot assume it without ceasing to act upon each other. This move- ment, therefore, is not proper for attaining the object proposed, which is to (ph^inge nothing in the reciprocal action of bodies. _ . n-iorc OnJinisUng the Inside of Palaces, V^ ^ iH more extension by means of the geometrical movements; tut as we shall soon see (XXIV) the analogy of this equa- tion (E) with the principle of the preservation of the moving powers in the shock of perfectly elastic bodies becomes Striking by a slight transformation ; and we shall see (XXVf), that in fact it is nothing else than this principle itself* transferred to hard bodies, with the modification re* quired by the diifcrcnt nature of these bodies : it is therefone this preservation of moving powers which will serve, as we have premised, as a basis to the whole of our theory of machines, whether at rest or in motion. According to these remarks we shall briefly recapitulate the solution of the preceding problem, in order to bhow at one glance the course of the operations indicated. [To be contiuued.3 XLIV. Processes employed fm' finishing the Inside of the Palaces of the Native Princes in^^^^ne Parts of the East Indies^, A j,v;| y^ X HE principal workman employed by colonel Clo^se in re- pairing the palace in the Laul Bang, gave me the following account of the processes used for finishing the inside of the palaces at Seringapatam, At first sight, one would imagine that much gilding is used in the ornaments ; but, in truths not a grain of gold is employed. The workmen use a paper covered with false gilding. This they tut into the shape of flowers, and paste these on the walls or columns. The interstices are filled up with oil colours, which are all of European preparation. — The manner of making this false gilded paper is as follows : Take any quantity of lead, and beat it with a hammer into leaves, as thin as possible. To twenty^four parts of these leaves add three parts of English glue, dissolved in water, and beat them together with a hammer, till they be * From Buchannan'» Journey, from Madras thvovgh ike Mysore^ Canara, ' and MalalaT, thoroughly f22 O71 finishing the Inside of East Indian Palaces, thoroughly united, which requires the labour of two persons for a whole day. The mass is then cut into small cakes, and dried in the shade. These cakes can, at any timt.', be dissolved in water, and spread thin with a hair brush on common writing paper. The paper (when dry) must be put on a smooth plank, and rubbed with a polished stone till it acquire a complete metallic lustre. The edges of' th« paper are then pasted down on the board, and the metallic surface is rubbed with the palm of the hand, which is smeared with an oil called giirnUy and then exposed to the sun. On the two following days the same operation is re- peated ; when the paper acquires a metallic yellow colour, which, however, more resembles the hue of brass than that of gold. Tht gurna o\\ is prepared as follows: — Take three quar- ters of a maund (about 18 lib.) of linseed oil, half a maund (12 lib.) of the size called cfmnderasny and a quarter of a maund (6 lib.) oimusamhra, or aloes prepared in the country. Boil the oil for two hours in a brass pot. Bruise the mit- sambra'y and, having put it into the oil, boil them for four hours more. Another pot having been made red-hot, the cfmnderasu is to be put into it, and will immediately melt. Take a third pot, and, having tied a cloth over its mouth, strain into it the oil an.l musambra : these must be kept in H gentle heat, and the chunderasu added to them gradually. The oil must be strained again ; and it is then fit for use. The chunderam is prepared from the milky juice of any of the following trees : ( flcus glomerata Roxb.), goni^ (a tree \\\\\q\\ \ c->x\\ ficus gonki) , Bayla, Bayvina, Gabali, &c. It is therefore an elastic gum. The oil used for painting consists of two parts of linseed, and one part of chunderasu. In white-washing their walls, over the chunam, or lime plaster, the workmen of Seringapatam first give a thin coat of S7iday, or fine clay ; which is mixed with size, and put on with a hair brush. They next give a coat of whitening, made of powdere'd lalapum or pot-stone ; and then finish -with a coat composed of eight parts of ahracum, of mica, oae part of powdered lalapum, and one of size. The On the Analyses of the Chromate of Irony &c, 223 The abracum is prepared from white mica,, by repeated grindings, the finer particles being removed iior use by wash- ing them from the grosser parts. The wall, when finished in this manner, shines hke the scales of a fish ; and when the room is lighted has a splendid appearance: but in the day-time, the wall washed with the powdered potstone alone, in my opinion, looks better ihaa when waslied with either quick-lime or mica. XLV. Notice ztpon the jlvahjses of the ChrtMate of Irouy and. iLpon the Fariety of ike Epidote called Zmjsile. By Ji. Haoy*. -iVI. Laugier has published in a former number of these Aiinales t, the result of the analysis he made of the chro- mate of iron of Siberia, and this result was similar to that obtained by M. Vauquelin, when examining the chromate of iron discovered by M. Pontier in the department o^* Var. M, Klaproth lately repeated the analysis of the sanie substance upon a piece which came from Krieglach, in Styria ; and his results having been communicated to M^ Laugier, we now insert it, as presenting a confirma,tion o£ the two preceding analyses. KLAPROTH. LAUGIER. rAUQUELIX. Chromate of Iron of Styria. • Chromate of Siberia. Chromate of Van Oxide of chrome 55'5 53 43 Oxide of iron - - 33 34 34'T Alumina - - - ^ . H 0Q.3. Silex - - - - 2 1 2 O 0 Waste by roasting * 2 0 Loss - - _ 55-5 33 2 2 1-5 100 100 100 We find in a subsequent number the result of another analysis made by M. Laugier upon a grayish substance- • From Annales du Musmm d^Uisioire, tome ix. p, 103. f See Phil. Mag, vol. xriv. p. 3 brought i24 On the Analyses of the Chromate of Iron, ^c. brought from the Valais, which I recognised from its struc- ture and physical properties to be a variety of the epidote'/ although it differed in its external characters from the cry- stals of this species hitherto observed. M. Laugier found that the respective quantities and qualities of its component principles were the same as in the epidote of Arendal, and in that of France, analysed by M. Vauquelin and M. Des- costils. The same variety also exists in Carinthia and in some of the neighbouring countries ; and M. Werner has since given the name of zoysite to it in honour of barofi Zoys. The distinction which M. Werner establishes between this substance and our epidote is in some measure a consequence of the nomenclature adopted by this celebrated naturalist ; for he gives to the epidote ihe name of Pistazite (Pistachio stone) because it is g'^nerally of a more or less deep green. Now this name seems to exclude the zoysitc, the colour of which is gray, brown, or brownish yellow, but never green ; at least it is so in those specimens we have seen. M. Laugier has been informed that Messrs. Klaproth and Bucholz have recently analysed the zoysite ; and the follow- ing are their results, compared with those of the French chemist. KLAPROTH. LAUGIER. BUCHOLZ. Gray Epidote, said to be The same Substance. The same Substance. Zoysite. Silex - - - - 45 37 40*25 Alumine - - - 29 • ^Q'Q 30*25 Lime - - - - 21 • 20 22*5 Oxide of iron - 3 13 4*5 Oxide of manganese o 0-6 0*0 Water - - - - o 1*8 2 Loss - - - - 2 1 0-5 loa 100 100 If wc compare these three results either with each other or with the others which have for their objects the epidotes of Norway and France ; and if on the one hand wc consider tiie- agreement which exists, between chemistry and the geometry On drying Articles of Manufacture, <^c. 225 geometry of crystals, we shall find the most convincing proofs that the zoysite should be joined to the epidote, like the mineral of Norway, which a deceitful indication of its cha- racters had made to be placed in a particular sj)ecies under the names of arendalite and akanticonc. XLVr. On drying Articles of Manufacture, and heating Buildings, hij Steam, By R. Buchannan, Esq,y Civil Engineer, Glasgow. To Mr. Tillocfu SLRf JVxANY additional facts with regard to heating by steam have lately been ascertained in this neighbourhood, and its application to various processes in manufactures continues to increase. Mr. Richard Gillespie is highly pleased with its effects upon copper-plate callica-printing at his works, as also for heating his calenders* For this last purpose, and to warm his warehouse and counting-house, the steam is conve}Td to a distance of above ninety-three yards. Steam was, I believe, tried many years ago at Leeds, for drying goods, as a substitute for stoves ; but for some reason, of which I am ignorant, was abandoned. Mr. Lounds, at Paisley, however, has for a considerable time used it with gieat success in drying fine muslins. Messrs. Leys, Mason and Co. now also use it at their bleaching works, at Aberdeen. Some kinds of muslins have for several years been dried by being rolled round cylinders of tin plate filled with steam, but I do not here allude to that mode. For drying of dyed yarn and pullicates, (a kind of co- loured chequed cotton handkerchiefs,) a higher temperature than for fine muslin is required. I am glad, however, to Lave it in my power to say, that Messrs. Muir, Brown, and Co., at their dyeing and bleaching works here, have found steam to answer those purposes much better than the usual mode by stoves. Mr. Muir informs me, that, al- though they formerly gave out their pullicates tol)e bleached Vol. 30. No. 119. v%// isoe. P " to ^26 On tJie Uses of Leaves and Pru?ii?igs of Vines, to some of the local bleachers in this part of the country, they never had their colours in the same perfection which they now have, and which they attribute entirely to the superior effect of the steam. It occurs to me, that steam might be appHcd for warming buildings in I-.ondon, in many instances, with great advan- tage. For instance, the bed-rooms of large inns and hotels ; as also large warehouses or shops, where a number of neigh- bouring buildings might be warmed from one boiler, which would save much in attendance and fuel, as well as in the cost of the apparatus. It is also well adapted to the pur- pose of warming churches, hospitals, and other large pub- lic buildings. I am, sir, your most obedient servant, Robertson Buchannan. Glasgow, , April 2, 1808. XLVII. On the ceconomlcal Uses to which the Leaves and. Prunifigs of Fines may le applied in tins Country, To Mr. Tilloch, SIR, X* ROM experiments which I have made, I find that, on being dried, which should be done in the shade, and infused in a tea-pot, the leaves of the vine make an excellent sub- stitute for tea. I have also found that, on being cut small, bruised, and put into a vat., or mashing-tub, and boiling water poured on them, in the same way as is done with malt, the prunings of the vine produce a liquor of a fine vinous quali- ty ; which, on being fermented, makes a very fine beve- rage, either strong or weak, as yoii please; and, on being distilled, produces an excellent spirit of the nature of brandy. In the course of my experiments I found that the fer- mented liquor from the prunings, particularly the tendril$> when allowed to pass the vinous and to run into the acctoua fermentation^ makes uncommonly fine vinegar. If not in- tended to be distilled soon after they are lopped off, or if it should not be convenient to do so at the time, they should be Observations on the neiv celestial Bodyy ^c* 227 be dried in the shade. When intended to be used, an ex- tract should be made with hot water, as in the common process for distilling from grain. As this is the season when the vine puts forth its leaves,, and many thousand cart-loads of the prunings, where ther^ are not goats to eat them, are yearly thrown away as user less, your stating the above in your highly, interesting and useful Magazine may be of use to many of your readers, and to the public in general. I am, sir, your constant reader, London, JA^fES HsALL. April 8,. 1808, XLVni. Observations on the Nature of the new celestial Body discovered by Dr, Olbers ; and of the Comet which was expected to appear last January in its Return from the Sun, By William Herschel, L.L,D F.R.S, * JL HE late discovery of an additiortal body belonging to the. solar system, by Dr. Olbers, having been communicated to me the 20th of April, an event of such consequence en- gaged my immediate attention. In the evening of the same day I tried to discover its situation by the information I had obtained of its motion ; but the brightness of the moon, which was near the full, and at no great distance from the object for which I looked, would not permit a star of even the 5th magnitude to be seen ; and it was not till the 24th that a tolerable view could be obtained of that space of the heavens in which our new wanderer was pursuing its hither-, to unknown path. As soon as I found that small stars might be perceived, I made several delineations of certain telescopic constellations, the first of which was as represented in figure 1, and I fixed upon the star A, as m6st likely, from its expected situatipn and brightness, to be the one I was looking for. The stars ia this figure, as well as in all the other delineations I Ji§d • From Philosophical Tr9ns^ctip,ns,Jf|^r, 1J(07« P^^^ P2 . > -c/ made. ^4b Ohervattofis on the new celestial Body made, were carefully examined with several magnifyiilg powers, that in case any one of them should hereaiicr ap- pear to have been the lately discovered object, I might not lose the opportunity of an early acquaintance with its con- .dition. An observation of the star marked A, in parti- cular, was made with a very distinct magnifying power of 46o, and says, that it had nothing in its appearance that differed from what we see in other stars of the same size ; indeed Dr. Olbers, by mentioning in the communication which I received, that with such magnifying powers as he could use it was not not to be distinguished from a fixed star*, had already prepared me to expect the newly dis- covered heavenly body to be a valuable addition to our in- creasing catalogue of asteroids. The 25th of April 1 looked over my delineations of the preceding evening, and found no material difference in the situation of the stars I had marked for examination ; and in addition to them new asterisms were prepared, but on ac- count of the retarded motion of the new star, which was drawing towards a period of its retrogradation, the small change of its situation was not sufficiently marked to be readily perceived the next day when these asterisms were again examined, which it is well known can only be done with night-glasses of a very low magnifying power. A long interruption of bad weather would not permit any reofular examination of the situation of small stars : and it was only when I had obtained a more precise information from the astronomer royal, v^ho, by means of fixed in- struments, was already in possession of the place and rate of motion of the new star, that 1 could direct my telescope with greater accuracy by an applcaition of higher magni- fying powers. My observations on the nature of this se- cond new star discovered by Dr. Olbers arc as follow. April 24. This day, as we have already seen, the new celestial object was examined with a high power; and since * Der neue planet zeigt sich als ein stern zwischen der 5ten und Gten grcisse und Ut im fernrohr, wenigsten mit den vergrisserungen die ich^au- wsnden kann, von cinen fixstern nicht zu unterschelden. ' discoveredji/ Dr, oilers, &c, 229. a magnifier of 460 would not show it to be different from, the stars of an equal apparent brightness, its diameter must be extremely small, and we may reasonably Expect it to be an asteroid. May 21. With a double eye-piece magnifying only 75 times the supposed asteroid A makes a right-angled triangle with two small stars a h. See fig. 2. ^..With a very distinct magnifier of 460 there is noj^% pearance of any planetary disk. ; i, ,^ May 22. The new star has mowd away from a hy ,^i>d is now situated as in fig. 3. The star A of figure 1 is no longer in the place where I observed it the 24th of April, and was therefore the asteroid. I examined it now with gradually increased magnifying powers, and the air being remarkably clear, J saw it very distinctly with 460,, 577, and 636. On comparing its appearance with these powers alternately to. that of equal stars, among which was the 4'63d of Bode's catalogue of the stars in the Lion of the 7th magnitude, I could not find any difference in the visible bize of their disks. By the estimations of the distances of double stars, con- tained in the first and second classes of the catalogues I have given of them, it will be seen that I have always considered every star as having a visible, though spurious, disk or diameter : and in a late paper 1 have entered at large into the method of delecting real disks from spurious ones : it may therefore be supposed that T proceeded now with Vesta (which name I understand Dr. Olbers has given the aste- roid), as 1 did before in the investigation of the magnitudes of Ceres, Pallas, and Juno. ,- The same telescopes, the same comparative vaews, by >yhich the smallness of the latter three had been proved, convinced me now that I had before me a similar fourth celestial body. , The disk of the asteroid wliich I saw was clear, well de- fined, and free from nebulosity. At the first view I was inclined to believe it a real one; and the Georgian planet being conveniently situated, so that a telescope might with- P 3 out 230 Olservations on the new celestial Body 6ut loss of time be turned alternately either to this or to the Asteroid, I found that the disk of the latter, if it were real, would he about one-sixth of the former, when viewed with a magnifying power of 460. The spurious nature of the ^steroidal disk, however, was soon manifested by an in- crease of the magnifying power, which would not propor^ tionally increase its diameter as it increased that of the planet ; and a real diek of the asteroid still remains unseen with a power of 636. May 23. The new star has advanced, and its motioti i$ direct; its situation with respect to the two small stars a b, is given in figure 4. Its apparent disk with a magnifier of 460 is about 5- of 6-tenths of a second ; but this is evidently a spurious ap* pearance, because higher powers destroy the proportion il bears to a real disk when equally magnified. The air is not sufficiently pure this evening to use large telescopes. May 24* With a magnifying power of 577 I compared the appearance of the Georgian planet to that of the asteroid, and with this power the diameter of the visible disk of the latter was about one 9th or 10th part of the former. The apparent disk of the small star near /3 Leonis, which has been mentioned bpfore, had an equal comparativ^e magni- tude, and probably the disks of the asteroid and of the stat it resembled are equally spurious. The 20 feet reflector, with many different magnifying powers, gave still the same result; and being already con» vinced of the inipossibility, in the present situation of the asteroid, which is above two months past the ojiposition, to obtain a better view of its diameter, I used this instrument chiefly to ascertain whether, any nebulosity or atmosphere might be seen about it. Fc^r this purpose the valuable quan- tity of light collected by an aperture of 1 ST inches directly received by an eye-glas> of ihe fropt-view without a seconcj reflection, proved of eminent use, and gave me the diameter of this asteroid entirely free from all nebulous or atmospheric appearances. Tlie result of these observations is, that we now are in posgessipi^ discovered lij Dr. Olbers, &c. 231 possession of a formerly unknown species of celestial bodies, which, by their smallness and considerable deviation from the path in which the planets move, are in no danger of disturbing, or being disturbed by them ; and the great suc- cess that has already attended the pursuit of the celebrated discoverers of Ceres, Pallas, Juno, and Vesta, will induce us to hope that some further light may soon be thrown upofi this new and most interesting branch of astronomy. Observations of the expected Comet. The CG_met which has been seen descending to the sun, and from the motion of which it was concluded that we should probably see it again on its return from the perihelion, was expected to make its reappearance about the middle of last January, near the southern parts of the constellation of the Whale. January 27. Towards the evening, on my return from Bath, where I had been a few days, I gave my sister Ca- rolina the place where this comet might be looked for, and between flying clouds, the same evening about 6^^ 49' she saw it just long enou2:h to make a short sketch of its situa- tion. January 31 . Clouds having obscured the sky till this time, I obtained a transitory view of the comet, and perceived that it was within a few degrees of the place which had been assigned to it; the unfavourable state of the atmosphere, however, would not permit the use of any instrument pro- per for examining it minutely. There will be no occasion for my giving a more particular account of its place, than that it was very near the elec- trometer of the constellation, which in Mr. Bode's maps is taWed inac/tina elect rica ; the only intention I had in look^ ing for it, being to make a few observations upon its physi- cal condition. February 1. The comet had moved but very little from the place where it was last night ; and as the air was pretty clear, I used a 10- feet reflector with a low power to ex- amine it. There was no visible nucleus, nor did the light which is called the coma increase suddenly towards the cen- tre. 232 An Account of a Shotuer of Meteoric Stones, tre, but was of an irregular round form, and with this low power extended to about 5, 6, or 7 minutes in diameter. When I magnified 109 times it was considerably reduced in size, which plainly indicated that a further increase of mag* nilying power would be of no service for discovering a nu- cleus. On account of cloudy weather I never had ^n op^ portunity of seeing ihe comet afterwards. When I compare these observations with my former ones of 13 other telescopic comets, I find that out of the 16 which J have ckamimcd, 14 have been without kny visible solid body in their centre, and that the other two had a very ill defined small central light, which might perhaps be called a nucleus, but did not deserve the name of a disk. XLIX. An Account of a remarkable Shower of Metewic Stones, at IVeston in America. By Mr. Silliman, Professor of Chemisti-y , and iVfr. Kingsi^ey, Professor of Languages^ in Yale College^, Yale College, Dec. 2G, 1807. .As imperfect and erroneous accounts of the late phaeno-r menon at Weston are finding their way into circulation, we take the liberty of enclosing for publication the result of an investigation into the circumstances and evidence of the event referred to, which we have made on the ground •where it happened. That we may not interrupt our narra- tion by repeating the observation wherever it is applicable, we may remark, once for all, that we visited and carefully examined every spot where the stones had been ascertain- ed to have fallen, and several places where they had been only suspected without any discovery; that we obtained specimens of every stone-^ conversed with all the principal original witnesses ; spent several days in the investigation, and were, at the time, the only persons who had explored the whole ground. Benjamin Silliman, James L. Kingsley. ^ Conimunlcatedbv the right hon. Charles Grevillc, F.R.S, &c. Tlie An Account of a Shoiver of Meteoric Stones. 233 The meteor which has so recently excited alarm "in many, and astonishment in all, first made its appearance in Wes^ ton, about a quarter or half past six o'clock, A. M., on Monday the 1 4th instant (Dec. 1807). The morning was somewhat cloudy ; the clouds were dispersed in unequal masses, being in some places thick and opaque, in others light, fleecy, and partially transparent ; while spots of un- clouded sky appeared here and there among them. Along the northern part of the horizon, a space of 10 or 13 de- grees was perfectly clear. The day had merely dawned, and there was little or no light, except from the moon, which was just setting. Judge Wheeler, to whose intelligence and observation, apparently uninfluenced by fear or imagination, we are indebted for the substance of this part of our account, was passing through the enclosure adjoining his house, with lu§ face to the north, and his eyes on the ground, when a sudden flash, occasioned by the transition of a lu* minous body across the northern margin of clear sky, illu- minated every object, and caused him to look up. He im- mediately discovered a globe of fire, just then passing be- hind the first cloud, which was very dark, and obscured, although it did not entirely hide the meteor. In this situation its appearance was distinct, and well defined, like that of the sun seen through a mist. Jt rose from the north, and proceeded in a direction nearly per- pendicular to the horizon, but inclining, by a very small angle, to the west, and deviating a little from the plane of a great circle, but in pretty large curves, sometimes on one side of the plane, and sometimes on the other, but never making an angle with it of more than 4 or 5 degrees. It appeared about one half or two thirds the diameter of the full moon. This description of its apparent magnitude is vague, but it was impossible to ascertain what angle it sub- tended. Its progress was not so rapid as that of common meteors and shooting stars. When it passed behind the thinner clouds, it appeared brighter than before : and when it passed the spots of clear sky it flashed with a vivid light, * yet not so intense as the lightning in a thunder- storm, "but 6 ' rather 234 j4n Account of a Shower of Meteoric Stones, rather like what is commonly called heat lightning. Its surface was apparently convex. Where it was not too much obscured by thick clouds, a conical train oF paler light was seen to attend it, waving, and in length about 10 or 12 diameters of the body. In the clear sky a brisk scintillation was observed about the body of the meteor, like that of a burning firebrand carried against the wind. It disappeared about 1.5 degrees short of the zenith, and about the same number of decrees west of the meridian. It did not vanish instantaneously, but grew, pretty rapidly, fainter and fainter, as a red-hot cannon ball would do, if cooling in the dark, only with much more rapidity. There was no peculiar smell in the atmosphere, nor were rfny luminous masses seen to separate from the bodv. I'he whole period between its first appearance and total extinc^ tion was estimated at about 30 seconds.. About 30 or 40 seconds after this, three loud and disthict reports, like those of a four-pounder, near at hand, were heard. They succeeded each other with as nuich rapidity as was consistent with distinctness, and^ all together, did not occupy three seconds. Then followed a rapid succession of reports less loud, and running into each other, so as to produce a continued ruitibling, like that of Jl cannon ball rolling over a Hoor, sometimes louder and at other times fainter; some compared it to the noise of a waggon, running rapidly down a long and stony hill ; or- to a volley of mus-*- quetry, protracted into wh.it is called, in military language^ 2. running jire. This noise continued about as iotig as the bbdy was in rising, and died away, apparently in the direc- tion from which the meteor came. The accounts of others corresponded substantially with this. Time was differently estimated by difiVrent people> but the variation was not material. Some augmented the number of Joud reports, and terror and imagination seem, jti various instances, to have magnified every circumstance of the phaeriomenon. The Only thing which seemed of any importance beyond this An Account of a Shower of Meteoric Stones, 235 this statement, was derived from Mr. Elihu Staples, who said, that when the meteor disappeared, there were appa- rently three successive eflbrts or leaps of the fire-hall, which grew more dim at every throe, and disappeared with the last. Such were the sensible phaenomena which attended this meteor. We purposely avoid descrihing the appearances which it assumed in other places, leaving this task to others who have the means of performing it more accurately ; while we proceed to detail the consequences which followed Ihe explosions and apparent extinction of this luminary. We allude to the fall of a number of masses of stone in several places, principally within the town of Weston. The jplaces which had been well ascertained at the period of our investigation, were six. The most remote were about 9 or 10 miles distant from each other, in a line differing little from the course of the meteor. It is therefore probable that the successive masses fell in this order, the most northerly first, and the most southerly last. We think we are able to point out three principal places where stones have fallen, corresponding with the thrte loud caimon-like reports, and with the three leaps of the meteor observed by Mr. Staples. There were some circumstances common to all th^ cases. There was in every instance, immediately after the explo- sions had ceased, a loud whizzing or roaring noise in the xiir, observed at all the places, and, so far as was ascertained, at the moment of the fall. It excited in some the idea of a tornado ; in others, of a large cannon-shot in rapid motion ; and it filled all with astonishment and apprthension of som6 impending catastrophe. In every instance immediately after this was heard a sudden and abrupt noise, like that of a ponderous body striking the ground in its fall. Excepting one, the stones were more or less broken. The most inj- portant circumstances of the particular cases were as fol- low : }. The most northerly fall was within the limits of Hunt- ington, on th.e border of Weston, about 40 or 50 rods east bf the great road from Bridgeport to Newtown, in a cross tba(ll. and contiguous to the house of Mr. Merwin Burr. Mr. Burr S3<5 jinAcvouniqfaShowerqfMeleorieS(o?W5. Mr. Burr wa;^ standing in the roatl, in front of his house, when the stone fell. The noise produced by its collision villi a rock of granite, on which it struck, was very loud. Mr. Burr was within 50 feet, and immediately searched for the body, but, it being still dark, he did not lind it till half auhour after. By the fall, some of it was reduced to i)owder, and the rest of it was broken into very small fragments, which v^'cre thrown around to the distance of 20 or 30 feet^ The granite rock was stained at the place of contact with a deep lead colour. The largest fragment which remained did not exceed the size of a goose-egg, and this Mr. Burr found to be still warm to his hand. There was reason to concKide from all the circumstances, that this stone must hare weijxhed about tw^entv or twenty-five pounds. Wr. Burr had a strong impression that another stone fell in an adjoining field, and it wasi confidently believed that a large mas*^ had fallen into a neighbouring swamp, but nei- ther of these had been found. It is probable that the stone whose fall has now been described, togelher with any other masses which may have fallen at the same time, was thrown froni the meteor at the first explosion. S, The masses projected at the second explosion seem to have fallen principally at and in the vicinity of Mr. William Princess, in Weston, distant, about five miles, in a southerly direction, from Mr. Burr's. Mr. Prince and family were still in bed, when thei/ heard a nnise like ike fall of a very hearty lodyy immediately after the explosions. I'hey formed TarioHS unsatisfactory conjectures concerning the cause—r nor did even a fresh hole made through the turf in the door- yard, about twenty-five feet from the house, lead to any conception^ of the ca\isc, or induce any other inquiry than .why a new post-hole should have been dug where there was no use for it. So far we?e this family from cQuceiving of the possibility of such an event as stones falling from the clouds. They had indeed formed a vague conjecture that the hole might have been made by lightniug, but would probably have paid no further attention to the circumstance, had ibey not heard, in the course of the day, that stones had fallen th^t n^orning in other parts, of the town. Thi^ induced ^n .Account bf.a Shoucr of Meteoric Stone£y. ii3.7'? iiKiLicecl them, towards evenings to search the hok \i\ the yard, where they ioiiiul a stone buried in the lootsc earth- which had fallen in upon it. It was two feet from the sur- face— the hole was about twelve inches in diameter; and as the earth was soft and nearly free from stones, the mass had sustained little injury, only a few small fragments having been detached by the shock. The weight of this stone was about thirty-five pounds. From the descriptions which wc have heard, it must have been a noble specimen, aiid men of science will not cease to deplore that so rare a treasure should have been immediately broken in pieces. All that remained unbroken of this noble mass, was a piece of twelve pounds weight, since purchased by Isaac ikonson, esq., of Greenfield, with the liberal view of presenting it to some public institution. Six days after, another mass was disco^^ered, halFamile north-west from Mr. Prince's. The search was induced by the confident persuasion of the neighbours that they heard' it fall near the spot where it was actually found buried in the earth, weighing from seven to ten pounds. It was found by Gideon Hall and Isaac Fairchild. It was in small fragments, having fallen on a globular detached mass of gneiss rock, which it split in two^ and by which it was it- self shivered to pieces. The same men informed us that they supected another stone had fallen in the vicinity, as the report had been di- stinctly heard and could be referred to a particular region somewhat to the east. Keturning to the place after an ex- cursion of a few hours to another part of the town, we were gratified to find the conjecture verified, by the actual dis- covery of a mass of thirteen pounds weight, which had fallen half a mile to the north-east of Mr. Prince's. Having fallen in a ploughed field, without coming into contact with a rock, it was broken only into two principal pieces, one of which, possessing all the characters of the stone in a re- markable degree, we purchased ; for it had now become an article of sale. — It was urged that it had pleased Heaven to rain down this treasure upon them^ and they would bring their 238 An Account of a Shower of Meteoric Stones, their thunderbolts to the best market they could. This was^ it must be confessed, a wiser mode of managing the business than that which had been adopted by some others at an earlier period of these discoveries. Strongly inipressed with the idea that these stones contained gold and silver, they subjected them to all the tortures of ancient alchemy, and the goldsmith's crucible, the forge, and the blacksmith's anvil, were employed in vain to elicit riches which existed only in the imagination. Two miles south-east from Mr. Prince's, at the foot of Tashowa hill, a fifth mass fell. Its fall was distinctly heard by Mr. Ephraim Porter and his family, who live within 40 rods of the place, and in full view. They saw a smoke rise from ihc spot, as they did also from the hill, where they are positive that another stone struck, as they heard it di- stinctly. At the time of the fall, having never heard of any such thing, they supposed that lightning had struck the ground ; but after three or four days, hearing of the stones which had been found in their vicinity, they were induced to search, and the result was the discovery of a mass of stone in the road, at the place where they supposed the lightning had struck. It penetrated the ground to the depth ot'two feet in the deepest place ; the hole was about twenty inches in diameter, and its margin was coloured blue from the powder of the stone struck off in its fall. It was broken into fragments of moderate size, and from the best calculations might have weighed 20 or 25 pounds. The hole exhibited niarks of much violence, the turf being very much torn, and thrown about to some distance. It is probable that the four stones last described were all projected at the second explosion, and should one be dis- cpvered on the neighbouring hill*, we must without doubt rttfer it to the sam€ avulsion, 3. Last of all, we hasten to what appears to havebcea ihe catastrophe of this wonderful phaenomenon. A mass of stone far exceeding the united weight of all ♦ Which has since been found, weighing- thirty-six poupds apd a quarter. 1 have seen and wcighe<^ it myself. G. Burr. which An Jccount of a Shower of Meteoric Stones. 23l> which we have hitherto described, fell in a field belonging to Mr. Elijah Seely, and within 30 rods of his house. A circumstance attended the fall of this which seems to have been peculiar. — Mr. Elihu Staples, a man of integrity, lives on the hill at the bottom of which this body fell, and witnessed the first appearance, progress, and explosion of the meteor. After the last explosion, a rending noise like Ihat of a whirlwind passed along to the east of his house and immediately over his orchard, which is on the declivity of the hill. At the SAme instant a streak of light passed over the orchard in a large curve, and seemed to pierce the ground. A shock was felt, and a report heard like that of a heavy body falling to the earth ; but no conception being enter- tained of the real cause, (for no one in this vicinity, with whom we conversed, appeared to have ever heard of the fall of stones from the skies,) it was supposed that lightning had struck the ground. Three or four hours after the event Mr. Secley went into his field to look after his cattle. — He found that some of them had leaped into the adjoining en- closure, and all exhibited strong indications of terror. Pass- ing oUj he was struck with surprise at seeing a spot of ground which he knew to have been recently turfed over, all torn up, and the earth looking fresh, as if from recent violence. Coming to the place, he found a great mass of fragments of a strange-looking stone, and immediately called for his wife, who was second on the ground. Here were exhibited the most striking proofs of violent collision. — A ridge of njicaceous schistus lying nearly even with the ground, and somewhat inclining like the hill to the south-east, was shivered to pieces, to a certain extent, by the impulses of the stone, which thus received a still more oblique direction, and forced itself into the earth to the tlepih of three feet, tearing a hole of five feet in length and four feet and a half in breadth, and throwing large masses of turf and fragments of stone and earth to the distance of 5Q and 100 feet. Had there been no meteor, no explosions, and no witnesses of the light and shc^ck, it would'have been im- possible for aiiy person contemplating the scene to doubt that 240 An Atcoiuit of,a Shower of Meteoric St-one's, that a large and heavy body had really fallen from the skies with tremendous momentum. This stone was all in fragments, none of which exceeded the size of a man's list, and was rapidly dispersed by nume- rous visitors who carried it away at pleasure. Indeed we found it Very diflicult to obtain a sufficient supply of speci- mens of the various stones, an object which was at length accomplished principally by importunity and purchase. From the best information which we could obtain of the tjuantity of fragments of this last stone, compared with its specific gravity, we concluded that its weight could not have fallen much short of 200 pounds. All the stones, when first found, were friable, being easily broken between the fingers ; this was especially the case where they had been buried in the moist earth, but by exposure to the air they gradually hardened. Such were the circumstances attend-* iog the fall of these singular masses. We have named living witnesses 3 the list of these may be augmented, but we con- sider the proof as sufficient to satisfy any rational mind. Further confirmation will be derived from the mineralogical description and chemical examination of these stones. The spejcimens obtained from all the diffi^rent places are perfectly vsimilar. The most careless observer would in- stantly p\:onouncc them portions of a common mass, and different from any of the stones commonly seen on this globe. Of their form nothing very certain can be said, because only comparatively small fragments of the great body of the meteor have been obtained. Few of the specimens weigh one pound — most of them less than half a pound, and from that to the fraction of an ounce. Mr. Bronson*s piece is the largest with which we are acquainted ; we possess the next, which weighs six pounds, and is very perfect in its characteristic marks, and we have a good collection of smaller specimens, many of which are very instructive. They possess every irregular variety of form which might be supposed to arise from accidental fracture with violent forces On many of them, however^ and chiefly on the large speci-- mens« An Acctnint of a Shower of Meteoric Stones, 241 fhens, may be distinctly perceived portions of the external part of the meteor. It is every where covered with a thin black crust, desti-* tute of splendour, and bounded by portions of the large irre- gular curve which seems to have enclosed the meteoric mass. This curve is far from being uniform. It is sometimes de- ()ressed witli concavities such as might be produced by pressing a soft and yielding substance. The surface of the crust feels harsh like the prepared fish skin or shagreen. It gives sparks with steel. There are certain portions of the stones covered with the black crust, which appear not to have formed a part of the outside of the meteor, but to have received this coating in the interior parts, in conse- quence of fissures or cracks, produced probably by the in- tense heat to which the body seems to have been subjected. The specific ojravity of the stone is 3*6, water being 1. The colour of the mass of the stone is principally a dark ash, or more properly a leaden colour. It is interspersed with di- stinct masses, from the size of a pin's head to the diameter of one or two inches, which are almost white, resembling in many instances the crystals of feldtspar in some varieties of granite, and in that species of porphyry known by the name of verd antique. The texture of the stone is granular and coarse, resem- bling some pieces of grit-stone. It cannot be broken by the fingers, but gives a rough and irregular fracture with the hammer. On inspecting the mass, four distinct kinds of matter may be perceived by the eye. 1. The stone is thickly interspersed with black globular masses, most of them spherical, some arc oblong and irre- gular. The largest are of the t>ize of a pigeon-shot, but generally they arc much snialler. They can bfe detached with any pointed iron instrument and leave a concavity in the stone. They are not attractable by the magnet, and can fee broken with the hammer. 2. Masses of yellow pyrites may be observed. Some of them are of a brilliant golden colour, and are readily di- stinguished with the eye. Vol. 30. No. 1 1 9. April 1 808. Q s. The «42 An Account of a Shower of Meteoric Stones^ 3. The whole stone is thickly interspersed with metallic pointSj many of them evident to the eye, and they appear numerous and distinct with a lens. Their colour is whitish, and was mistaken by the discoverers of the stone for silver. They appear to be chiefly malleable iron alloyed with nickel. 4. The lead-coloured mass which cements these things together, has been described already, and constitutes by far the greater part of the stone. After being wet and exposed to the air, the stone becomes covered with numerous red- dish spots, which do not appear in a fresh fracture, and arise manifestly from the rusting of the irv>n. Finally y the stone has been analysed in the laboratory of this College according to the excellent instructions of Howard, Vauquelin, and Fourcroy. The analysis was hasty, and intended only for the purpose of general informa- tion. The exact proportions, and the steps of the analysis, arc reserved for more leisure, and may be given to the phi- losophical world hereafter. It is sufficient at present to ob- serve that the stone appears to consist of the following in- gredients : — sileXy iron, magnesia, nickel, sulphur. The two first constitute by far the greater part of the stone — :the third is in considerable proportion, but muclt ks9 than the others — the fourth is probably still less ; and the sulphur exists in a small bot indeterminate quantity. Most of the iron is in a perfectly metallic state ; the whole stone attracts the magnet, and this instrument takes up a large proportion of it when pulverized. Portions of me- tallic iron may be separated, &o large that they can be readily extended under the hammer^ Some of the iron is in combinatioii with sulphur in the pyrites, and probably most of the iron is alloyed by nickel. It remains to be observed that this account of the appear- ance of the stone accords very exactly with the descriptions^ now become considerably numerous, of similar bodies which have fallen in other countries at various periods; and with specimen?^ which one of us has inspected, .of stones -t^at have fallen in India, France, and Scotland. The chemical analysis also proves that ihcir composition is the same ; and it An Atcourd of a Shower of Meteoric Stones, 243 It 18 well known to mineralogists and chemists that no such stones have been found among the productions of this globe. These considerations^ together with the facts that are im- mediately to be mentioned, raust> in connection with the testimony, place the credibility of the facts asserted to have recently occurred in Weston, beyond all controversy. The falling of stones from the clouds is an event which has frequently happened in Europe, in Asia, and in South America^ The accoutits of such phsenomena were, fcJr a long time, rejected by philosophers, as the offspring of igno- rance and superstition. Several facts of this kind, how- ever, within a few years, have been proved by evidence so unexceptionable, as to overcome the most obstinate incre- dulity. It is now admitted not only that such phaenomena have existed in modern times, but that the accounts of si- milar events in former ages are in a high degree probable. As this is the first time that stones are known to have fallen in this part of America, it may not be uninteresting to those who have paid little attention to this subject, or who still hesitate to admit that such things have happened, to see a statement of several similar events in other countries, and some of the eviderrce by which they are supported. In 1492, on the 7th of November, at Eniisheim in Up- per Alsace, a stone fell from the atmosphere which weighed 260 pounds. Contemporary writers agree in stating, that on this day, between 1 1 and 12 o*clock in the morning, a loud explosion was heard at Ensishcim, and that this stone was soon after seen to fall in a field at no great distance from the town. This stone, till within a few years, was preserved in the parish of Ensisheim. In 1762, two stones fell at Verona, one of which weighecf 200 and the other 300 pounds. Three or four hundred persons were witnesses of the event. In 1790, on the 24th of July, a shower of stones fell near Agenin, Gulenne. About nine or ten o'clock at night a meteor was seen moving through the atmosphere with very great velocity. A loud explosion was soon heard, which •was followed after a short interval by a shower of stone* over a considerable-extent of country. ' Q 2 la 244 An Account of a Shower of Meteoric Stones^ In April 1802, the same thing happened at L'Aigle, Biot, a member of the French National Institute, who visited the place to ascertain the fact, , writes to this effect. Persons of all professions, manners and opinions,-— ecclesiastics, sol- diers and labourers, men, women^ and children, — agree in referring the event to the same day, the same hour, and the same minute. They say they saw the stones descending along the roofs of the houses, break the branches of the trees, and rebound after they fell upon the pavement. They say they saw the earth smoke around the largest of them, and that the stones were still hot after they had taken them in their hands. The mineralogical collections formed on the spot with the greatest care contained nothing of the kind. On a sudden, and only since the time of the meteor, these stones have been found, and within a certain extent. Within fifteen years past the falling of similar bodies, under similar circumstances, has happened in Portugal, Bohemia, France, Great Britain, India, and South America. To account for the existence of these stones, various theories have been formed by philosophers. Some have supposed them to be only common stones struck with light- ning and partly melted. But this theory has now no advo- cates. A less fanciful hypothesis is, that they are masses of matter thrown from volcanoes. But to this there are serious objections. No such bodies are found near the craters of volcanoes, or are known to be projected from them. And in many instances these bodies have fallen several hundred and even several thousand miles from any known volcano. Mr. Edward King has varied this theory, and supposes that these substances are thrown from volcanoes not in stTlid masses, but in the state of ashes or dust. He supposes that these ashes descending in a cloud become condensed, take fire, and produce numerous explosions. According to him, the pyritical, metallic, and argillaceous particles melt, are suddenly crystallized and consolidated, and fall in masses to the ground. This explanation evidently involves as great difficulties as those which it is intended to obviate. Some philosophers have supposed that these stones are thrown from terrestrial comets. Not to mention any oilier objec- tion On the Torpidity of Monkeys andotlier Animals, 245 tion to this hypothesis, it will by no means account for such a phaenomenon as appeared at Sienna in 1 794, when stones descendt'd, not from a moving meteor, but from alu- minous cloud. Other philosophers, ascribing to these stones an origin still more extraordinary, suppose them to be pro- jected from the moon. Admitting that bodies can be pro- jected beyond the sphere of the moon's attraction, they must move round the earth in one of the conic sections, and all the difficulties attending the preceding hypothesis em- barrass this. The sul)ject must be acknowledged to be in- volved in much obscurity, and the phaenomenon, till we are possessed of more facts and better observations, must be considered inexplicable. L. Memoir upon the Torpidity of Monkeys and other Ani^ mals. Translated from t/ie Italian of' M. M^ngali, Frofessor of Natural History at Pavia^. Une of the phjenomena most worthy the attention of na- turalists, is the profound sleep called lethargy, to which a great number of cold-blooded animals are subject during winter, and several warm-blooded animals also, such as monkeys, bats, dormice, hedgehogs, Sec. Several authors, both aniient and modern, have treated on this subject ; but as they have not made proper observations and experiments, their writings leave us in much uncer- tainty. The National Institute of France has therefore in- vited the learned of Europe to examine carefully, 1st, the phaenomena presented in winter by the lethargy of animals ; Sdly, the cause of this lethargy ; Sdly, why it is peculiar to these animals. Without pretending to give a complete solution of a problem, which, as it is announced, appears to me to be attended with difficulty, a:ul particularly the latter part of it, I shall detail what I have remarked respecting several of the animals in question. • From Annales (lu Mustum d'Histoke Naturelle, tome ix. p. 106. g 3 " I flatter 246 On the Torpidity of Monkeys and other Animals, I flatter myself that the results of my observations will communicate to the learned the principal phaenomena which attend the lethargy of these mammifcrous animals, the order pursued by their principal organic functions, and the nature of the action of a high or low temperature upon their in-^ ternal oeconomy. I shall say nothing of the habits of these animals in the jiatural state, and in the state of slavery ; I shall perhaps have occasion to speak of this at another time :^— at present I mean to confine myself to an account of what I have ob- §erved tn monkeys, which are the most remarkable^ among the animals subject to periodical lethargy. ^ The principal object of my observations has been to ex-? amine the various phaenomena presented by monkeys during their lethargy, far different from the mortal lethargy, which may take place in all animals from the effects of cold. I have particularly studied the progress of their principal or^ ganic functions, because physiologists are generally at va- riance upon this subject; some pretending that these func-» tions are entirely suspended, and others that they continue, although in a languishing manner, scarcely sufficient to evince the existence of the vital principle. A celebrated naturalist of the last century expresses him^ self in the following manner :-r- *^ When sleep commences, the respiration then becomes less ; it ceases when the lethargy is complete. The eyes of the monkey are then closed, its body is bent in the form of a bow, it is immoveable and entirely cold. We may roll it about, throw it up into the air, and use it ill without giving the smallest signs of life.'' The same author asserts that a sharper degree of cold, in place of awakening monkeys, ren- ders their lethargy much more profound. I shall not quote what other authors have since written upon the subject, as it is evident they have not made the observations necessary to enable them to decide upon the cause. On the first of December 1803, there were brought to me at Milan three male moi^keys, taken in the Alps which se- parate On the Torpidity of Monkeys and other Animals, 247 parate the territory of Chiavenne from that of the Grlsons^ One oF the three was a little awake: I preserved it two years, in order to study its habits. The other two were in the lethargic state. The same day I weighed the latter, in order to ascertain how much of their weight they lost in a given time of con- stant lethargy ; the one weighed 25 Milanese ounces, and the second 22 ounces 3 deniers *. At first sight they seemed as if totally deprived of life ; they were rolled up like a ball, with the nose applied to the anus, their eyes closed, the teeth locked, and they felt perfectly cold when taken into the hands. When pinched, however, or shaken, they gave unequi* vocal signs of irritability ; and sometimes, although rarely, I perceived a feeble dilatation and a successive sinking in the flanks, or other signs of a languishing respiration. The two monkeys remaiiiled in the most profound lethargy until January 3d, 1804. Reaumur's thermometer, placed in the room where they were, having varied from five td nine degrees above zero, on the evening of this day the largest awoke and removed from its companion, in order to find a place where it might be more secure from the cold. As soon as I saw that it was awake, I weighed both ; and I found that the largest had lost 18 deniers of its primitive weight, and the other 17|. At the end of 24 hours, the monkey which had awoke, again fell into a lethargy, and remained in this state until the Uth ; t|^e temperature of the room being from 5 to 8 degrees. On the 11th in the evening, the external temperature being about 4 degrees, I exposed the same animal to the free air on the sole of my window. A short tintfe after- wards it began to tremble and give signs of pain. I also remarked a small indication of breathing ; and fearing lest a greater cold should waken it entirely, I replaced it in its bed in about an hour. In spite of my precaution its respiration became more frequent. In fact, two hours afterwards I J?aunes, by moving from side to side in great pain throughout the night. 1 visited it several times, and found it always trembling i jts eyes were half closed. It did not sleep, however, al- though I left it exposed to the same cold till nine o'clock next morning. I am convinced that a sharper cold would in a short time have plunged it into that lethargy which is followed by death, when no assistance is given to prevent it. I have here detailed only the general outlines of my ob- servations upon monkeys. In a subsequent menjoir 1 shall publish my experiments upon bats, hedgehogs, Sec. : and I flatter myself that their result will be an accurate know- Jege of the causes which plunge animals into a torpid sleep. LI. The [ 253 ] LI. The reformed Sexual System of Lhincpus* By Robert John Thornton, M,D., Lecturer on Botany at Guy*s Hospital*, CLASSES. !• iVioNANDRiA one stamen. n. DiANDRiA two Stamina. III. Tkiand.ria three stamina. IV. Tetrandria four stamina. V. Pentandria five stamina. VL Hexandria six stamina. VI r. Heptandria seven stamina. VI 11. Octandria eight stamina. . IX. Enneandria nine stamina. X. Decandria ten stamina. XI. DoDECANDRiA 1 2 to 1 9 Stamina. XII. PoLYANDRiA , „ 20 OF more stamina. XIII. Cryptogamia concealed stamina. Orders. I. Orders taken from the Number of Fist ilia, I. Monogynia one pistillum, II. Digynia two pistilla. ' III. Trigynia three pistilla. IV. Tetragynia ^ . four pistilla. V. Pcntagynia five pistilla. VI. Hexugyvia six pistilla. Vn. Heplagynia seven pistilla. VIII. Octogynia eight pistilla. IX. Enneagyjiia nine pistilla. X. Decagyriia ..>..,. ten pistilla. XI. Dodecagynia 12 to 1 y pistilla. XII. Polygynia 20 or more pistilla. ♦ Extracted from Dr. Thornton's Neuj Illustration of the Sexual System of \Linnieus, just publislied; containing a great number of picturesque botanical coloured plates of select plants, illusttative of the sexual systen;; the most ij-icndid botanical work that has yet appeared in any part of the world. II. Orders 254 The reformed Sexual System of Linnceus, If. Orders taken from some curious Particularity in the Stamina, XIII, Didynamia , . . four stamina, two long, two short* XIV. Tetradijnamia six stamina, four long, two short. XV. Icosajidria .... twenty or more stamina, inserted on the calyx or corolla. XVI. Monadelphia . . filaments united in one body. XVII. Diadelplda . . . filaments united, forming two bodies. XVIII. r^hjadelphia ,. filaments united, forming three or more bbdies. JXIX. Syngenesia , , , five anthers united. XX. Gynandria . . , stamina arising from the pistil. XXI. Monoecia stamina apart from the pistil on the same plant. XXII. Dloecia stamina apart from the pistil on different plants. XXIII. Polygamia .... bisexual flowers, and unisexuaL Class Cryptogamia has the Natural Orders, 1. Fiiices, II. MuscL III. Algce. IV. Fungi^ REMARKS. T. — ^The Class IV. Tetrandria, being a numerous one, Linnaeus chose to separate it into two, and an opportunity presented itself from the consideration of the difTefences which occur in plants having four stamina, from the pro- portion oi ihtst. Didynamia expresses this ifierence; and the flowers are either ringent ,or personate, a natural tribe. But as all the ringent flowers are not included in the class Didynamia, some coming under class II.Diandria, there can be no good reason for not making this real division of a class into an order. The system hence becomes more easy and regidar, and in fact, freq^iently, more natural. II. — ^The Class VI. Hkxandria, also readily separates into two parts, from the like consideration of the proportion in the stamina, and Tetradynamia contains the natural trihe of cruciform plants. III.— The The reformed Sexual System of Li/lnetus, 253 ITT. — ^The Class XIII. Polyandria, also readily divides into two parts, IVom the consideration of the insertion of the stamina ; and one of these, the Icosandria of Linnseus, possesses many edible fndts ; but ad it is not altogether a natural class, therefore no one can regret seeing this part distinguished as an order. IV.— In theMoNADELPHiA of Linnaeus, many of the nu- merical names, which bad been used to characterize the classes, are employed to distinguish the orders, or subdi- visions, as Pentandria, Decandria, &c., and hencje arises a confusion unavoidably perplexing to the young student, and which our method, as is evident, completely removes. The same observation applies to the classes Diadelphia^ Polyadelphia, Gyna?idria, Moncecia, Dioecia, where the «ame (may I call it so) impropriety occurs. This class in Linnaeus is not natural, hut, being made into orders, many ef them then become natural a.s orders, as the Colum- KIFER^. V. — The Papilionaceous Flowers, as they are generally termed, form the order Decandria in the class Diadelphia of Linnaeus ; but the author, unvv'illing, as it would seem, to make any breach in so natural an assemblage of plants, has so far deviated from the principles of his system, as to refer to that class several genera, which strictly belong to the preceding class, being in fact Monadelphious, This in- convenience is entirely obviated in the present scheme, where Monadelphia 3ind Diadelphia constitute two successive orders in our class X. Decandria. Vr. — Polyadelphia is a small, and, as Doctor Smith observes, " rather an unnatural class,** Most persons are shocked to sec Citrus, the orange, in this class, and not in the Icosandria class; for Linnaeus describes it of the class XVIII. Polyadelphia, order III. Icosandria, Now in our Reformed Sexual System, it comes under class XIII. Polyandria, order Icosandria, in juxta-position with other edible fruits, in the subdivision Polyadelphia. VII. — Class V. Pentandria, a very numerous class, is subdivided by Svngenesia, and so formed into two classes by Linnaeus,, the latter of which, however, as containing an i56 The reformed Seocuat System of Linnceus, an order Monogamia, is not therefore altogether a nahtrat class. Wc obviate this by making Syngenesia an order^ and the subdivision Polygam'ia to contain the natural tribts of compound flowers ; whilst, under another subdivisioui Monogamiay many plants, not having compound flowers^ arrange themselves. VI II. Against Gynandria, which Doctor Smith calb ** an odd and miscellaneous class," there lies the same ob- jection, as we observed above, as against the class Dia- DfiLPHiA, the numerical names of Classes being applied to Orders, In our scheme, class 11* Diandrta, has an order Gyiiandria^ which contains the natural tribe of Orchises ; and thus the mind is delighted to see a natural assemblage embraced in an order, if not in a class. The separation of the remainder cannot be regretted, as not possessing amongst each other the smallest affinity, IX. Moi\cECiA is a miscellaneous class, and borrows the names of its secondary divisions from most of the other classes, as Monandrioy Dia?idr'ia, &c., nay even from Monaddphia^ Syngenesia, and Gyiiandria ; for all these become, in Linnseus's Sexual System, orders. In our scheme, class Triandria, order Monoocia, contains mostly gTcisses : hence we retain this natural assemblage in the same class at least, if not in the same order* X. DicEciA. The same remarks apply here, as in Mo- KCECIA. XI. PoLYGAMiA subdivides the classes Moncecla and Dioecia-, therefore in the logic of science it is in reality an order. " Pascitnr in vivis livor, post fata qriiescit. Turn suis e\ mciitis cukjue tuctur hoiios." Lunn. Some apolos^y is certainly necessary, after any endeavour to reform so celebrated and established a system as the Sexual System of the illustrious Linnreus. Many ; altera- tions in this system have been attempted. The enlight- ened pupil of Linnseus, Thunbcrg, abolished the classes XX. Gynandria y XXI, Mo?iascia, XXI J, Di(ecia, and XXIir. Po- The reformed Sexiial Spstem of Linnceits. 237 XX III. Polygamia. Gmelin, professor at Gottingeu, to the alterations introduced by Thunberg, in publishing a new- edition of Linnasus's Systenia Naturae, added the abolition of class XTl. Icosandrin ; and the no less celebrated Doctor Smith, preserving the rest of the system entire, has abo- Jished order V. Monogamia, in class IX. Syngenes'ia, and class XIII. Pvlygamia. *' To his class Polygamia," says Doctor Smith, " many students of tropical plants jifstly objected in his lifetime, and he, as well as his son, listened to their observations." Dr. Withering, in his Arrange- ment of British Plants, has followed the system of Gmelin. Professor Martyn, speaking of the changes introduced by Schreber, in his new edition of Linnasus's Genera Plan- tarum, says, that his reduction of class XX. Gynandriay appears " reasonable,'^ yet the singularity of the order Di- andria surely dL4nanded a separate place to itself. But when he comes to mention the' incorporation by Gmelin of the class Icosnndria into the Pohjundria^ he declares this change to be ^* abominable.'* I am aware, thaf venturing to reform in such a degree the Sexual System, as 1 have done, will bring upon me> with some, much severe reproach. T am conscious, in- deed, as well as others, that the credit of the Sexual System of Linnaeus, as an invention, surpasses all power of praise, and hence has found enthusiastic admirers ; ''and with timid hands I have ventured to take to pieces the superstructure he raised, and build up from the old matci'ials, which I have carefully and religiously preserved, a new edifice, suited to modern improvement and convenience ; hoping, how- ever, that those who may, hereafter, publish the works of Linnaeus, will cdite the Sexual System as delivered by him- self, and not bring forward, in the works said to be those of Linnaius, what he never either thought or wrote. For a full defence of the Rtformed Sexual System, vide my '* Prac- tical Botany, being a New Illustration of the Genera of Plants, with Dissections of each Genus," where this subject has been particularly considered and discussed. In a word, as by system is only meant a plan io facilitate the acquirement of the knowledge of plants, the more easy Vol. 30. No. 1 1 9. Jpril 1808. • R this tJ5S The reformed Sexual System of LinncmiSt this is contrived to accomplish the proposed end, the better such £i system will be accounted ; and I have endeavoured so to contrive this, that I hope no longer any very great obstacles can arise in the way of the student, and that this will plead my excuse with a discerning and indulgent publi-c for venturing to step out of the beaten path, to attempt the rc/brma^/o7z of a system which has conferred immortal ho- nour upon the inventor, and received the general plaudits and admiration of the learned throughout Europe. It ap- peared to me more advisable to reform the whole, than to make any partial amendments ; either to adopt the system as fklivered to us by Linnaeus, or to have the present sy- stem, as erected out of the materials of the old -, a system which I hope may not moulder, like the o-lher sys^tems*, into the sand of which they were composed, but resemble the youthful Phoenix arising from the ashes of its parent ; or, as a rock in the midst of the ocean, may remain until ** the wreck of matter and the crush of worlds/' It is certainly a great satistaction for me to lind, that al- though the learned and venerable Professor Martyn has long openly disapproved of the changes made in the Sexual Sy- stem by the several reformers, yet he writes to me — Hxtract €f a Letter to Dr, Thornton from the Reverend Mr. Martyn — '^ T by no means disapprove oi your new attempt to ren- clerthe Sexual System, by the manner in which you have done it, an easier 7nediitm of attaining a knowledge of plants; and have been long convinced in my own mind, that we stri-ve in vain to unite a natural with an artificial arrange^ ment. Upon yo2ir plan, I see 7/0 impropriety in bringing the OHCHiDE^ into the second class : nor can 1 even objeci to your altering, as you have done, the separated classes of Linnxus, Icosandria and Polyani^ria. Yo[ir method is ably considered throughout ;. for along with you I hold our great master's system as sacred, and can never approve of * Not less than fifty-two systeitis of Botany have been published, several of tliera of very considerable merit, tut not practically good j hence most of them are now forgotten. those On the Manufactures cairiedon at Bangalore, ^^c, ^55 those greater alterations" (he might have sa\d mutilations) *'' which some of his pupils have niadc,-i-so diflerently is to be estimated the conduct of persons engaged in the same; object." The rev. Doctor Mihie, the learned author of ^^ A Bo- tanical Dictionary,** writes to me — Extract of a Letter to Dr, Thornton from the Reverend. Dr. Colin Milne-— *' Your Reformed Scheme of the Linncean System has my entire approbation. It possesses all the admirable and ele- gant simplicity of that of Rivinus, which has always been a great favourite with me, from the steady adherence of the author to the principles of his method, and is eminently adapted for practice* Your remarks respecting the Sexua} System are truly excellent; your New Illustration admi- rable/' Doctor Shaw, of the British Museum, a gentleman not less eminent as a botanist than a naturalist, declares "that he believes^ had Linnoeus been alive, the Reformed Sexual System "would be that which he himself would have instantly adopted." Similar are the flattering opinions also of several other distinguished botanists, who have expressed their approval of the Reformed Sexual System. But with extreme diffi- dence I submit it to the judgment of the world. LIf. Account of the Manufactures carried on at Bangalore, and the Processes employed by the Natives in Dyeing Silk and Cotton*, JlSangalore, or Bangalura, was founded by Hydcr, and during the judicious government of that prince became a place of importance. Its trade was then great, and its manufactures numerous. Tippoo began its misfortunes by prohibiting the trade with the dominions of Arcot and Hy- derabad, because he detested the powers governing both * From Buchannan's Journey through the Mijsore^ &c. R 2 countries. 260 On the Mamtfactures carried on at Bangalore, countries. He then sent large quantities of gpods, which he forced the rnerchant? to take at a high rate. These op- pressions had greatly injured the place ; but it was still po- pulous, and many individuals were rich, when lord Corn- wallis arrived before it, with his army in great distress from want of provisions. This reduced hinfi to the necessity of giving the assault immediately, and the town was of course plundered. The rich inhdbitants had previously removed their most valuable effects into the fort ; but these too fell a prey to the invaders, vvbei> that citadel also was taken by storm. After the English left the place, Tippoo encouraged the inhabitants- to conve back, and by promises allured them to collect together the wrecks of their fortunes, from the different places to which these had been conveyed. No sooner had he effected this, than, under pretence of their having been frie^idly to the English, he surrounded the place with troops, and fleeced the inhabitants, till even the wo- men were obViged to part with their mos^t trifting ornaments. He then kept them shut up within a hedge, which sur- rounded the town at the distance ofa coss, till the advance of the army under general Harris made the guard withdraw* The inhabitants, not knowing wh&m to tru&t, immediately dispersed, and for some months the place continued de- serted. The people, however, are now flocking to it from all quarters ; and although there are few rich individuajs, trade and manufactures increase apace ; and the imports and exports are estimated already to amount to one fourth of what they were in its most flourishing state. The manu- facturers and petty traders are still very distrustful and timid; but the merchants, many of whonr have been at Madras, and are acquainlfd with British |)()licy, seem- to have the utmost confidence in the protection- of our government. The trade of the country not havmg been yet opened a year since the inhabitants had deserted the place, no proper estimate can be formed of the quantity of exports and im- ports ; but it is on the increase every montli, and is now about one fourth of the quantity that was exported and im- ported in the most flourishing time of Hyder's governments The son of the person who had then charge of the custom- house and the Processes used in Dyeing Silk and Cotton, 261 J)Ouse states the following particulars of the trade at that period. In one year there were imported 1500 bullock-load^ of cotton wool; 50 bullock-loads of cotton thread; 230 bullock-loads of raw silk ; 7000 bullock- loads of salt ; fo- reign goods from Madras 300 bullock -loads. At the same time were exported of betel-nut 4000 bullock-loads, and of pepper 400 bullock-loads. From the quantity of the raw materials some estimate maybe formed of the extent of the manufactures : 1500 bullock-loads of cotton wool, and 50 of cotton thread, make ; rather more than 5100 hundred weight, worth about 8l6o/., and 230 bullock-loads of raw silk make 47,437ilb8., worth about 27,000/. The cloths here being entirely for country use, and never haviiTg been exported to Europe, arc made of different sizes, to adapt them to the dress of the natives ; and the Hindus seldom use tailors, but wrap round their bodies tbe cloth, as it comes from the weaver. 1. The cloth which the women wrap round their haunches, and then throw over their heads and shoulders like a veil, is from 14 to 17 cubits long, and from 2 to 2^ cubits wide. It is called shir ay, 2. If these cloths are for the use of girls, they are called kirigay ; and are from 9 to 12 cubits long, and from 1^ to • II- cubit broad. 3. The little jacket which the women at this place wear, is made up in pieces containing 12 jackets, and called ai" pissa tan. These are 14-1- cubits long, and two cubits or two cubits and a nail broad. 4. Men wrap round them a cloth called dotra^ which is from 10 to 12 cubits long, and from 2^ to 2.l cubits broad. 5. The wrappers of boys, called hitcha khana, are 6 or 7 cubits long, and 1^ or If cubit broad. 6. Cloth for wrapping round the head and shoulders of men, like shawls, is named shalnama ; and is 6 cubits long, and 2\ broad. Smaller ones are made for children. 7. Paggooy or turban pieces, are fron) 30 to 60 cubits long, and f of a cubit broad. Haying assembled the different kinds of weavers, I took R 3 from 26iJ On the Mamifactures carried on at Bangalore^ irom tberji the following acpount of their various irjanu* fact urea : The pj^tti/cgars, or sjlk- weavers, make cloth of a very rich strong fabric, The patttrns for the first five kinds of dresses arc similar to each other, but are very much varied by the different colours employed, and the different figures woven in the cloth ; for they rarely consist qf plain work. Each pattern has an aj)propriate name, and, for the com- njon sale, is wrought of three different degrees of fiueness. If any person chooses to commission them, whatever parts of the pattern he likes may be wrought in gold thres) of water ; boil them for about two hours. Thjen wash the boiled silk in some hot water, and dry it. In this operation much care is necessary, as by too much of the soda the silk is apt to be spoiled ; and if it be boiled too short a time it will not be sufficiently white. The workmen judge of the time by taking up a few threads on a stick, and putting on them a drop of eold water: whenever they appear of a proper colour, the silk must be immediately washed in clean water. To give the red dye with lac, take ]l-maund (38^y^lb.) of lac, cleared from the sticks, 1^ seer (O-jSgy-g-lb.) of lodu bark, l-i- seer of suja car a, or soda, and two dudus weight* (J S-f'y^o?^ drachms) «f turmeric. Put them into a narrow- i^iouthed pot, capable of holding 80 seers (5492 cubical inches), with 40 seers (2746 cubical inches) of water, and boil them four hours; then de/:;ant the liquor, which is impregnated with the dye ; and having to the same ma- terials added 20 seers (1373 cubical inches) more of water, boil them again for three hours ; decant this liquor into the former, and then, for three hours, boil the materials a third time, with 10 seers (686^ cubical inches) of water. Decant this^ also into the two former, and pre- aerve, in a covered pot, the whole liquor for eight days. At the end of this period the workman judges how much silk his materials will dye. If the lac has been good, it will dye 5 seers (3TVcV^b')> ^"^ ^^ ^^ be poor, it will not dye more than 3-i. seers (2-i-VA^t)). For 3 seers of silk take 20 seers (IS-jJ^^o^lb.) of tamarinds, and for two days infuse them in 18 seers (1235 cubical inches) of water. Then strain the R 4 infusioft 364 On the Ma?mfactures carried on at Bangalore, infusion through a thick cloth, till about 5 seers (343 cu- bical inches) of clear infusion are procured. Put this into a large open pot with the silk, and warm the^ii until they be raiher too hot for the hand. Take out the silk, and pour into the warm infusion of tamarinds three quaricrs of the decoction of lac, slraiued through a cloth. Then return the silk, and boil it for three hours. After this, examine the silk. If it have received a proper colour, nothing liiore is added ; but if the colour be not deep enough, the remaining decoction is strained, and added by degrees > till the colour is" completed. The pot must then be taken from the fire, and from time to time this silk must be examined with a stick. If the colour be blackish, some tamarind infusion must be added. If too light, it must be again boiled with some more of the decoction of lac: when cool, the silk must be washed in cold tank water, and dried in the shade. This is the finest red dye in use here : in some places cochi- neal is used ; but it is much more expensive. The lac dye is not discharged by washing. The puttuegars dye their silk of a pale orange colour, with the capilipodi, or dust collected from the fruit of the roller la tinctoria. For 5 seers of silk (S-ToVo^^*) prepared tor dyeing, take three seers (l-iVoV'^O ^^ cap'di reduced to a fine powder, and sifted through a cloth ; 4 dudus (l^^j_9^oz.) weight of scsamitm oil; 1-^ seer (t2-{Si>--^ oz.) of powdered soulu, or soda; 1 seer (iOtVo^q-oz.) of suja cara, another kind of soda, and three dudus weight (1.^3^3^ oz.) of alum ; — and put them in a pot. Then take 2-^ seers (l-rVoV^b.) of soulu, and boil it in about 3^ seers (240 cubical inches) of water, till it be dissolved. With this solution moisten the powders that are in the pot, and form them into a paste, which is to be divided in three equal parts. Put one of these portions in the remaining so«r lution of soulu, and heat it, but not so as to boil. Then put in the silk, prepared as before, and wet it thoroughly. Take it out, and add a little water, and a second portion of the paste. This being dissolved, soak in it the silk as be- fore. Then put in the remainder of the paste with 18 seers (1235 cubical inches) of water; and, replacing the silk, boil and the Processes used for Dyeing Silk and Cotton, 265 boil it for two hours. Then cool it, and having washed it in the tank, dry it either in the shade or 'Sun, indiflerently. This is a pretty colour, fixes well, and is cheaper than that of the lac. To dye their silk yellow, the piitivegars use turmeric. For 3 seers {\^^zji-\h.) of silk, take 4 seers (2-j*bVo^b.) of tur- meric, powdered and sifted : make it into a paste with water, adding 4 dudtis weight (f-p'o-Jo-^^-) of sesamumoW. Divide the paste iiUo three portions, one of whi.-h is to be put into a pot with 8 seers (549 cubical inches) of warm water. In this immerse the silk prepared as before, and continue the operation cxacily in the same manner as with the capUi paste. It must, however, he dried in the shade, and thie colour then stands very well; which it would not do, were it dried in the sun. The piittticgars give their yellow silk to the niiigaru, who dye it with indigo. It is then washed by the puttuegarsix^ the infusion of tamarinds, and jiftervvards is of a fine creen colour ; which, if it be dried in the shade, is tolerably weli fixed. The jiiUgaru dye all the other colours ; such as light and dark blue, sky blue, and purple. The silk is never dyed m, the piece. The red and orange- coloured silks are mostly in demand. Some weavers called cuttery, who pretcn^ to be of the Kshatriya cast, manufacture exactly the same kinds of good* as the puttuegars, ^ The whole of the demand for these goods, according to the account of the manufacturers, is in the counrry formerly belonging to Tip^:)oo : Seringapatam, Gubi, Nagara, Chat- rakal, and Chin'-rayapattana, are the principal marts. When the goods are in much deniand, it is customary for the merchant to advance one half, or e%'en the wholc^ of the price of the goods which he commissions ; but when the demand is small, the manufacturers borrow money froiii the bankers at two per cent, a month, and n)ake goods, which they sell to the merchants of the place. They never carry them to the public market. The silk is all imported in the r^w state by the merchants of this place, Tliale dress 5 and is made of various lengths, from eight to sixteen cubits, according to, the age and size of the wearers. In tliis way three different kixids of weavers are employed ; the shaijnagarv, the canara devangas, and the teliga de- vQ}7ga$. These people buy the thread at the public markets. The red thread comes mostly from Advany, Balahari, and other places near the Krishna river : the various shades of blue are dyed by the niligaru. The weavers themselves dye part of the red thread with the mudd't root, which is that of two species oi morinda ; the citrll'olia of Linnaeus, and the tern'ifoUa described in my manuscripts. The colour is dark, but stands washing hi cold water. In boiling, it fades. The following is the pro- cess used : — The thread must be divided into parcels eack weighing one seer (lO-pVoVoz.)- For each parcel take \. secr- (2yi..-_.Hg. oz.) of powdered soulu, and dissolve it in 4 seers (274^)^ cubical inches) of water. Put into the solution ^ seer of sheep's dung, and \ seer (S-J^^yV oz.) of sesamnm oil, and with the hand mix the whole well. Wet the par- cel of thread in this mixture tjioroughly, and let it hang up. in the house all night to dry. Next day expose it on a rock to the sun ; and during the four or five following days it must be dipped nine times in a solution of -J- seer ( 1 -^J^-^ 02.) of wid the Processes used for Dyei?tg Silk and Cotton. 287 oi souluy in one ^eer (a little more than (58 cubical inches) of water. Between each immersion it must be dried in the sun. After this, the thread remains in the house ten days ; it is then taken to a tank, and well washed by beating it on a stone, as is the usual practice of this country. When it has been dried, soak each parcel in a solution of two pago- das weight (1-rJVo- drachm) of alum in one sccr of water, and jthen dry it again. Infuse one see?' measure (74-fV cubical inches) of powdered bark of muddi root, in i seers of cold ^vater, and in this soak one parcel of thread; then throw into a large pot the whole of the parcels that have been treated in a similar manner. Next day take them to a tank, beat them as usual, so as to wash them clean, and then dry them again in fresh infusions oi' miiddi powder. This mus^ be daily repeated, till the colour is sufficiently strong ; which, if the bark be from the roots of an old tree, will re- quire six infusions ; but nine infusions of bark from a young plant will be requisite. These weavers dye cotton thread green in ihe following manner .- They send it to the niligaru, who dye it maviy or a kind of sky blue. The weavers then wash it, and put it into two seers (1374- cubical inches) of water, containing ^T seer {5'~^^^x>z.) of powdered turmeric, five myrohalans^ powdered, and the juice of ten limes. Here the thread is l^ept four hours, and the operation is finished. The colour is a fine green, but very perishable. It is said that the ??///- garu have the power of fixing it; but they keep their art a profound secret. The devangas dye cotton cloth of a fine red colour re-' sembling that of the pomegranate flower, and ealled gale- nari. This is done with the coss2imla, or flowers of the carihnmus tinctorius. The same gives another red colour, called simply cossumba. Neither of the colours are vi^ell ^xed. The demand for the cossumba dye being much greater than the country can supply, much of it is imported. 7'his is always done in the form of powder, which povi'der is adulterated with the flowers of the yecada, or asclepias gi- gantea -, on which, account it is cheaper than the flowers produced in the neighbourhood. The powder is made by drying 268 On the Manufactures carried on at Bangalore, drying the flowers in the sun, and beating them in a mor# tar, and will not keep longer than one year ; the flowers, if carefully packed iii sacks. and well pressed^ may be pre- perved for five years. The cossumha colour is given in the following manner : — Take \5 sultany seers (9Vr,lb.) of pure cossvmba powder, and put it on a cloth strainer. Clean it by pouring on wa- ter, and rubbing it with the hand, till the water runs through dear. The coss?imba is then to be spread on a blanket, and mixed with 13 dudus weight (fyrAh^^') ^f ^m'^ car a, and an equal weight oi' soulu, both powdered. They are gather- ed together in the centre oF the blanket, and trodden for an hour by a workman's feet. They are then put upon a cloth utrainer, supported as usual by sticks at the corners y and water is poured on them until it passes through the strainer without colour. This water is divided into three portions : that which came first, that which came in the middle of the operation, and that which can}e last ; the first being of the strongest quality. Then take Oo good limes, or 100 bad ones, cut each into two pieces, beat them in a mortar, and strain their juice, through a cloth, into the pot containing the dye of the first quality. Then put a little water to the skins, beat them again, and strain off the water into the pot containing the second quality of the dye. Then add jTiore water to the lime-skins, and having beat them, strain it into the dye of the worst quality. The cloth to be dyed, having been well washed, is put into this last pot, and boil- ed for an hour and a half. It is then dried in the sun, and dipped into the second quality of dye, but not boiled. It is then dried again, and afterwards kept half an hour in the dye of the first quality. At the end of this time, should the colour not be sufficiently strong, the cloth must be boiled in the dye. It is then dried, and the operation is finished. The cloth commonly dyed is for turbans ; and a turban 60 cubits long requires 1 5 seers of cossumha. The only differerice, in the process for dyeing the gulenari, is, that to the pot of the first quality, as prepared for dye- ing cossiimba, is added half a seer (A41 cubical inches) of a decoction of tundu flowers {cedrella toona Roxb. MSS.) prepared and the Processes used for Dyewg &ilh and Cotton, 26^ prepared as follows : — Take 24 dadiis weight {9^J'^<^'z.) of dried Hindu flowers, beat them in a mortar, and boil them for half an hour in 2 seers (137-i- cubical inches) of water. Then strain the decoction through a cloth for use. The devnngas frequently make a very dark blue, which they call black, by means of the bark of the swamy, or Sweilenia febrifuga Koxb. MSS. This colour is ciieap j but its intensity leaves it on the first washing ; whereas the very deep blue imparted by repeated immersions in indigo, and approaching near to black, is very high-priced, and durable. Ir is ihe colour most esteemed by the natives, who call it black. The devangas take cotton thread or cloth that has been dyed blue by the nUigarii witi) indigo, and sprinkle it with a decoction of swamy bark. This is made by powderlna^ the dry bark, and boihng it for an hour and a half. While the cloih or thread is sprinkled, it must be moved with the hand, so as to imbibe the colour equally in every part. Tliese weavers say, that they obtain advances from the merchants, and borrow money from the bankers, exactly on the same terms as the puitnegaru. They Sell their goods lo merchants, or to private customers, and never carry them to the public markets. None of them follow any other business than that of weaving, and many are in good circumstances. The shaynagaru are the richest. The ser- vants are paid by the piece, and make about 20 faimms (13i. b\d,) a month. A kind of weavers called hily mugga by the Mussulmans, but in Tact consistingof the casts called Shaynagam, Padma^ sh(day, and Samay-shalay, weave many kinds of white muslins, I. Dutary, striped and chequered muslins, cal^ed in Ben- gal durias. They are from 28 to 32 cubits long, and from 2 to 1^ broad; and, if commissioned, flowers of cotton, or gold thread, are frequently woven in them. ir. Soda sJdllay or plain muslin, like the mvfmiils of Bengal. These are from 26 to 32 cubits in length, and 1-^ to 2 cubits in breadth, III. jisto cwmhi, a cloth like the cossaks of Bengal^They ' have HJO On the Mantifacture^ carried on at Bangalore, have sometimes striped or silver borders^ and are always oriiamcuteci with silver at the euds. They are used by men to wrap round their shoulders. IV. Turbans IVom 30 to 100 cubits in length, and from -J^ to 1 cubit in widths and ornamented with silver and gold thread at the cnds^ Each kind ot cloth has several patterns, and each pattern is of three degrees of fineness^ which, in the technical lan- guage of European merchants in India, are marked by the letters A. B. and C* These people say, that they receive advances from the uicrchants, and borrow money from the bankers, in the same manner as the pnttuegars Aoi Where the cloth is made on the weaver's own account^ it is sold partly to mer- chants and partly in the weekly markets. When a weaver receives advances, he cannot sell any cloth till his contract be fullilled. Among the Padma shalay there are few ser- vants employed; but all the males of a family live together, and work in the same house, very seldom engaging them- belves to work out for hire. The Samay shalay keep more servants. The people of these two classes live better than those employed in agriculture* A man at fine work can gain difanain (rather more than 8eir masters, and are consequently bound in the same manner as the servants of the fiirmers* This circumstance is applicable to journeymen weavers of every kind. The togotaru are a class of weavers that make a coarse, thick, white cotton cloth with red borders, which among the poorer class of inhabitants is used as the common waist- jqloths of all ages and sexes. This kind of cloth goes by the name of the maaufacturcrs who weave it, and is also of three degrees of fineness. The same people tnake rornah, or handkerchiefs with red borders, from three to five cubits square, that arc commonly used by the poor as a head-dress. The pieces are about twenty cubili long, and are divided into a greater or smaller number and the Processes used for Dyeing Silk and Cotidn. ^\ number of handkerchiefs, according to their width. They are also of three degrees of fineness. The weavers of this class are poor, and say that they can- not aflford to make the cloth on their own account. They in general receive the thread from the women in the neighbourhood, and work it up into cloth for hire. For weaving a piece that is worth Sfujiams, or 5s. 4iJ., they get e^fanamSy or is. 8d. This occupies a workman four or five days ; «o that his daily gains are from four to five pence. They never cultivate the ground. The luhalliaru make a coarse, white, strong cloth called parcaUa. It serves the poorer male inhabitants, throughout the country, as a covering for the upper parts of their bodies. The pieces are from 24 to 28 cubits long, and from 1-^ to 1^ broad, and as usual of three different degrees of fineness. Weavers of this kind live scattered in the villages, and fre- quently hire themselves out as day-labourers to farmers, or other persons who will give them employment. At the weekly markets the cotton wool is bought up, in small quantities, by the poor women of all casts, except the Brahmans ; for these never spin, nor do their husbands ever plough the soil. The women of all other casts spin, and at the weekly markets sell to the weavers the thread that is not wanted for family use. The thread that is brought from Balahari, and other places toward the Krishna, is much coarser than that which the women here spin. Such is the account given me by the various weavers ; but the cloth agents, who are ail of a cast called Nagarity say, that it is not customary to make advances for goods of an ordinary kind, unless the demand from a distance be very great. When this is the case, or when goods of an un- commonly high price are wanted, in order to enable the manufacturer to purchase the raw materials, one half of the value is advanced. The credit is for three months, and for this time there is no interest paid ; but if the goods are not then delivered, monthly interest is demanded at the rate of I per cent, until the contract is fulfilled. The commission here on the purchase of goods is. only two per cent., and the agent is answerable for all the suras advanced to the weavers, 8 On iff On the ^fectns of gahibtg Power in Mechanics. On confronting some of the richer Shaynagaru with the Kaoaritt they acknowledged that this statement was true. The places from whetice agent?; are at present employed to purchase cloths are, Na^ara, Chairakal, Seringapatam, Chin*-raya-pattana, Sira, Wadhngiri, and Devund-hully. A small quantity of cotton and silk cloth for women*9 jackets goes to the lower Carnatic. This h the account of the Nagarit; but I have good reason to think, that a very kir2:e quantity of goods, especially »f the silk manufacture called combaivuftics, are sent to ihat country, and are much in request an)ong the women of the rich Br^hmans. The Na^arit say, that the merchants, who import cotton, take away silk clotlis for ihfe dresdof theBrahmans of both sexes, and also blue and red cotton stuiTs ; but not in a quantity sufficient to repay the whole cotton. Daring the former government of the Raja's family, much cloth went from this neighbourhood to Tanjore, Ncgapatam, and other parts of the southern Carnatic : but since to that period, this com- merce has been entirely at a stop. The Mangalore merchants send hither for every kind of cloth. The dress of that country requires cloth only eight cubits long. The pieces intended for that market have therefore a blank left in their middle. In Hyder's time tliere was a great exportation of cloth to Calicut : but the troubles in Malabar have put an entire stop to this branch of conuiierce. [To be continued.] LIII. On the Means of gaining Power in Mechanics, To Mr, Tilloch, SIR, In reply to the observations and opinion of one of your correspondents in Number cxvii. of your Magazine, relative to the means of gaining mechanical power, i regret having to remark, that instead of the instruction, or satisfactory infornjaiion, to be expected from an academician, he has only gtven us antiquated and superfluous objections and conclusions^ On tfw Means of gaining Power in Mechanics, 273 conclxisions which are quite erroneous and ill founded : — for as to the former, I had pointedly remarked that this novelty (of gaining power) was inadmissible on the esta* bii.^^hed principles of mechanics : and respecting the latter, his arguments, against his own supposition, concerning la- tent propertied in the mechanical powers, of which I never had any idea, by no means proved the impossibility of my discovering what had escaped the superior abilities of other men ; because things full as unlikely do sometimes happen. Nor is he more successful in his confident assertion, that the engine I have constructed will, at a certain period, require as much external power to restore it to its former state, as it had apparently gained power beyond the laws of mecha- nics by its first effort; because this engine is announced as an exception to the rules on which he forms his opinions : and the facts are, that it effects what the established max- ims held out as being impossible, and that it does not re- quire such great external poiver to restore it as he supposes. Hence it may properly be called a novelty. It is, however, what has long been sought, and what great numbers of well-informed geniuses in this and other countries are even now assiduously endeavouring to gain, with the established principles at their fingers' ends. To give a drawing or particular description of this engine in any Magazine, or taking out a patent, would be making it too public, by putting our continental neighbours, who are now most closely confederated against us, and intent on doing us all the injury in their power, on the same footing with ourselves ; and perhaps give them advantages, which, being the birth-right of my countrymen, shall, as far as rests. with me, be wholly secured to them. It will therefore suffice, f(>r the immediate gratification of your readers particularly interested in this subject, to state in general terms, that this engine is a singular, though very sim- ple, combination and disposition of the mechanical powers. I lake this opportunity to request the favour of an ansvver from some of your ingenious and obliging correspondents to the following question : Is it possible so to dispose a moving power, (suppose a Vol. 30. No. 119. ^pW/ 1 SOS. S one 274 On the Identity of Sllex and Oxijgen, onie pound weight,) as that, during its progress through a given space, its force shall be constantly increasing, and thereby produce an accelerated motion exceeding that oi the moving power at least ten to one ? I am, sir, your very humble servant, Bracknell, Berks, £. VlDAU March 22, 1808. LIV. 0?i the Identity of Silex and Oxygen, By Mr, Hume, ff Long- Acre, London, [Conlinuedfrom p. 17I.J To Mr, Tillock, . SIR, JLiixME., in xU general attractions, aud in its capacity to neutralize acids, possesses a very superior energy to clay, and, therefore, is a more decided salifiable base : hence, I' shall give it the preference in any example, in which an car,th, as belonging to a distinct genus, is to be contrasted with silex, whose habitudes and character are so totally dis- similar. Nothing is so frequent in nature as an association of two or more contending elements to form one homogeneous compound, or to effect some material purpose : thus, an acid with an alkali, sulphur with a metal, and metals with earths, niay be adduced as instances, in which this coexistence of opposites is, perhaps, as essential as two contrary poles to the same magnet, or the negative and positive wires af the Voltaic pile. This proximity is no where more -obvious and frequent than in substances composed of silex and lime, in which the caustic pungency and other inherent distinctions of the lime are coerced into such a state of neutrality, as to- evade every mode of detection, unless the purity of the com- pound be destroyed and the lime eliminated. Silex is not only found alone with lime, but follows it throughout, and in nearly all its modifications; and, gene- rally speaking, this seems the primary cause of the saturated condition of lime in all the native carbonates, such as in chalky On the Idenliiy of Silex and Oxygen. 67A thalk, marble, lime-stone, and other fossil bodies, of which carbonate of lime forms an extensive portion, so much so, as to render this class of minerals extremely importatit in all , geological discussions. This singular coincidence has not escaped notice, and many very respectable men have advanced opinions Upon the subject. It has, indeed, been supposed, that there is £t transmutation of one of these elements into the othef, or 1 graduation of lime into silex ; and it is asserted that th6 recent formation of flint had been perceived, near the sur- face, in a calcareous mountain, in which, also, animal and vegetable substances were found petrified by the silex ^ and that rhomboidal crystals were likewise present, passing from the state of carbonate of lime to nearly pure silex. It is evident, such a theory as this is not tenable, but must be involved in difficulty, since it assumes a case, of all others, the most improbable ; for, according to these pre- mises, wc are compelled to admit, that the diamond, the oxygen and the lime, that is to say, the real ingredients of the chalk, all contribute to the formation of sileX, which is, avowedly, one of the most perfectly indecomposable of ele- mentary bodies, and, certainly, much more so than lime* This conversion of lime into silex is, I presume, quite in- consistent with general facts, and contrary to every object in nature which contains these two ingredients among its constituent principles. In chalk particularly, which is one of the most plentiful of nature's productions, as well as in all the other carbonates oF lime, there is, usually, a very copious assortment of srlex, under one shape or another ; and this is either so intimately blended as to be hardly perceptible to the sight, and, often, can only be extracted by analysis ; or it occurs in the form of sand, gravel, or what, in common terms, are called^z/z/- stones» It is necessary to observe, that these stones are chiefly of an obtuse and rounded figure, and never pointed and angular; they are frequently found alone, and, from their appearance and other circumstances, seem to have suffered a. diminution of ihf^ir original bulk, by yielding up S"^ a portion, O", 76 0?i the Identity of Silex and Oxygen, a portion, from their surfaces, to the surrounding Hiedwim in which they are imbedded. The degradation of these flint-stonea is, likewise, strongly marked by a peculiar opacity, not unlike white glass-enamel or the superior kinds of porcelain ; and this forms a well- defined stratum, which covers entirely the whole surface of the stone, penetrating it to a greater or Tcss depth. It cannot be considered as a very forced explanation, to aay, that this, may, probably, be the very point of contact, where this de- clension of sHex is the commencement of a new modifica- tion ; and that this terminates eventually in the perfection of a carbonate, or even of the lime itself, of which silex would their be considered as the independent progenitor. That the blunted and nodular shape of the generality of siliceous stones, is a mark of loss in the primitive mass it- self, may be explained by many examples. Thus, even ia common experiments, a sharp or crystal -formed piece of any substance, capable of solution in an acid, soon loses it* projecting corners, and, as the action of the acid proceeds,, gradually becomes less indented, and more smooth or globu- lar. It is rather a gratuitous conclusion, when the convex .«hape of pebbles, gravel, and all othet siliceous- stones, is ascribed to attrition : in some instances this argument may appear just, but in the more hnportant cases it is, I con- ceive, extremely fallacious. The true nature of clay, or, as it is now generally called, alumincj. vvh«n eonsidered as a primitive earth and simple element, seems very questionable ; for, notwithstanding various met^hods have been employed to obtain it ma state of purity, still this doubt remains. Even, in one of the most celebrated systems of chemistry, after detailing the best BBode to accomplish the end, the ^author adds, that the »lumine ^ will then be nearly pure." One of the specific characters, peculiar to clay, tends very much to confirm this suspicion ; it is that particular odour, constantly evoI«* ving from it, ])erceptible on all occasions, such as ploughing or stirring upland or garden-groimd, and which is familiarly known by. the term earthy smelL It On the Identity of Silex and Oxygen, 277 It is true, there is also 2i flinty smell, or what the French -call ** odeiir quarlzeuse;'* but this arises only when the flint is employed in the act of collision with steel, or against some Iciml of stone containing this scintillating ingredient, the silex ; and, on such occasions, I have reason to believe, ■some new compound is the result, in which the presence ot oxyg-en may be traced to this origin and to no other. The' e nec:essary caloric from the atmosphere. If an ore consist chiefly of lime, silex and metal, and, if 4his metal be saturated witii oxygen, t^e lime and^ indeed, von A. G. "Wernex, 179 J. + Beschreibunp^ des Giuben Gchaiides Hininiclsfiirst, von F. Mohs. 1804. \ Mineralogy Bcinerkiingen bei gelcgenhcit einer Rclse durch den Merk- •wurdigstcJi Thcil dcs Harz-geberges von Fricsleben. 1795. § Mineralo^ical Description of Diimfriesihire; — and Ele.nenU of Geognosy. Lothian, IVernerian Natural History Society. 283 Lothian, belong to the transition rocks, or the newest flsetr trap formation ? 2. Docs clay-stone occur in beds or veins in the coal- fields of the Lothians ? 3. What are the geognostic characters and relations of th» porphyritic rock oF the Ochil hills? 4. Is Inch Keith, in the Frith of Forth, entirely composed ,of rocks belonging to the independent coal formation? 5. Are the geognostic relations of the porphyry slate or elink-stone porphyry of East Lothian the same as in other countries? 6. What are the geognostic relations of the clay-stone, compact felspar, and striped jasper of the Pentland hills? 7. Are the upper parts of the Lommonds in Fifeshire, of Tinfo in Lanarkshire, and of the Eilden hills in Roxburgh- shire, composed of rocks belonging to the newest flaetr trap formation ? 8. What is the extent and mode of distribution of the sienite of Galloway ? 9. Does the Craig of Ailsa in the Firth of Clyde, and the Bass rock in the Frith of Forth, belong to the newest flaetr trap formation ? 10. Does the pitchstone of Ardnamurchan belong to the newest tlretr trap formation ? .11. Is the granular quartz in the islands of Jura and Isla subordinate to mica slate, or does it constitute a distinct formation? 12. Are the Cullin mountains in the island of Skvc composed of rocks belonging to the newest flaetr trap and second porphyry formations? . 13. What are the geognostic characters and relations of the Scure Eigg in the isle of Egg, one of the Hebrides ? 14. Of what rock is the isle of Staffa composed 3 and what are its geognostic characters and relations? 15. Is the porphyry of the isle of Rasay porphyry slate ? 16. What are the geognostic relations of the tremolite of Glen-Elg, in Inverness-shire? J 7. Does the upper part of Ben-Nevis belong to the second ^84 Intelligence and Miscellaneous Articles, second pori>hyry formation : — and if this be the case, on what does the porphyry rest ? 18. Does the por])hyry of the Brauer near Blair in Athol belong to the second porphyry formation ? 19. Does the granitic rock in the vicinity of Aberdeen belong to the granite or sienite formations ? 20. Docs the sandstone of the Shetland islands belong to the independent coal formation, or to any of the formations described by Werner ? 21. In what species of mineral repository are the ores of Sandlodge in Shetland contained; and what are the orycto- gnostic and geognostic characters and relations of these ores ? 22. Does the clay-stone of Papa Stour, one of the Shet- lands, belong to the new flaetr trap or coal formations ? 23. Does the serpentine of the islands of Renst and Fet- lar belong to the first or second serpentine formations? LVI. Intelligence and Miscellaneous Articles, THE MAMMOTH. With the present Nnmber of the Philosophical Maga- zine we have given a representation of the skeleton of this stnpendous animal. Having, in our previous volumes, given many particulars respecting the mannnoth, we shall not here repeat them, but content ourselves with the fol- lowing references to the volumes in which they may be found : Vol. xiii. p. 206; vol. xiv. p. 162. 228. 332; vol. xvi. p. 154. 1/0; vol. XX. p. 100; vol. xxix, p. 141, See also Plate V, vol. xiv. The committee to whose management the members of the association for the discovery of the interior parts of Africa have intrusted the direction of their affairs, has engaged aiiolher traveller in their service; a person now in this country, highly accomplished ibr such a purpose, possessed of LiteUigence- and Miscellaneous Articles, SSA of a strong vigorous constitution, great ardour in the pur^ suit oF knowledge, with a temper of mind ready to suhmit to great privations, and prepared to accommodate himself to the various trying situations to which the prejudices of the inhabitants of that part of the world may possibly ex- pose him'. .Great expectations are formed of his success. Mr. Parkinson is expected to publish the second volume of Organic Remains of a former World, in the beginning of June. It will contain twenty plates, with the representations of nearly two hundred fossils of the remains of zoophytes, coloured from nature ; among which are several proving the existence in the former world of at least twenty species of the encrinus. It must be gratifying to the admirers of this branch of natural history, to learn that great numbers of these fossils are to be found in different parts of this island. LECTURES. Mr. Brookes's Summer Course of Lectures on Anatomy, Physiology, and Surgery, will commence on Saturday, the 1 1th of June, at Seven o'clock in the Morning, at the Theatre of Anatomy, Blenheim -Street, Great Marlborough- Strcet. In these Lectures the Structure of the Fluman Body will be demonstrated on recent subjects, and further illustrated by preparations, and the function of the different organs will be explained. The surgical operation's are so performed, and everv part of surgery so elucidated, as may best tend to complete the operating surgeon. The art of injecting, and of making anatomical prepara- tions, will be taught practically. Gentlemen zealous in the pursuit of zoology, will meet with uncommon opportunities of prosecuting their researched in comparative anatomy. Surgeons in the army and navy aiay be assisted in renew- ing their anatomical kowledge, and every possible attention will be paid to their accommodation as well as instruction. Anatomical conversaziones will be held weekly, when the different subjects treated of will be discussed fanuliarly, and the 286 Lectures, the students* views forwarded. — ^To these none but pitpifs can be admitted. Spacious apartments, thoroughly ventilated, and replete with every convenience, are open from five o'clock in the morning, for the purposes of dissecting and injecting, where Mr. Brookes attends to direct the students, and demonstrate the various parts as they appear on dissection. An extensive museum, containing preparations illustrative of every part of the human body and its diseases, appertain* ,. to this Theatre, to which students will have occasional ad- mittance.— Gentlemen inclined to support this school by contributing preternatural or morbid parts, subjects in natu- ral history, &c. (individually of little value to the possessors) may have the pleasure of seeing them preserved, arranged, and registered, with the names of the donors. Tei^ms. — For :i course of lectures, including the dissections, 51, 5s, For a perpetual pupil to the lectures and dissections, 10/. \0s. The inconveniences usually attending anatomical investi- gations are counteracted by an antiseptic process, the result of experiments made by Mr. Brookes on human subjects at Paris, in the year 1782; the account of which was delivered to the Roval Society, and read on the 17th of June 17S4. This method has since been so far improved, that the florid colour of the muscles is preserved and even heightened. Pupils may be accommodated in the house.— Gentlemen established in practice, desirous of renewing their anatomical knowledge, may be accommodated with an apartment to dissect in privately. Dr. Clutterbuck, Physician to the General Dispensary, Aldersgate-street, will commence his Summer Course of Lec- tures on the Theory and Practice oF Physic and the Materia Medica, on Monday the 30th of May, at Eight in the Morn- ing, precisely, viz., on the Theory and Practice, on Mondays, Wednesdays, and Fridays : and on the Materia Medica, on Tucsdavs and Thursdays, at the same hour. In these lectures will be given an outline of the structure and functions of the human b(Kly, as an indispensable preli- • mi nary List of Patents for New Inventions, 28/ minary to the knowlege of the nature and treatment of its various disorders. The lectures on the materia mcdica will contain the me- dical and pharmaceutical history of the articles in general. use ; with an explanation of iheir mode of acting, and their application to the cure of diseases. The subjects will be illustrated by occasional reference to the practice of the Dispensary. For further particulars, application maybe made at the Dispensary, or at No. 17, St. PauKs Churchyard. Dr. George Pearson, Senior Physician to St. Gcorge'i Hospital, will begin his Summer Course of Lectures on the Theory and Practice of Physic, MateriaMedica, and Chemis- try, at his house in George-street, Hanover- square, the first week in June: — viz. the Medical Lecture at Eight, and the Chemical at Nine. — Particulars may be known in George- street, or at St. George's Hospital. Mr. John Taunton, Surgeon to the City and Finsbury Dispensaries, &c., will commence his Summer Course of Lectures on Anatomy, Physiology, Pathology, and Surgery, on Saturday the 28th of May at Eight o'clock in the Evening, at his house in Grevillc- street, Hatton Garden, where further particulars may be known. LIST OF PATENTS POR NEW INVENTIONS. To William Francis Snowden, of Oxford-street, in the county of Middlesex, esq. engine-maker, for certain im- provements in an engine for cutting hay anj straw into chaff, and for cutting other articles. February 4. To John Shorter Morris, of Pancras Place, in the parish of Pancras, in the county of Middlesex, geut., for his machine for nfiangling. Febi-uary 4. To Ralph Wedgwood, of Oxford- strebj, in the county of Middlesex, gent., for his apparatus for producing several ori- ginal writings or drawings at one and i^he same time, which' he callsapennexpolygTaph; or pen and sylograpjnc manifold writer. February 52. To Samuel Thomson, of Addle-street, London, calen- dcrcr; for a machine, engine, or frame for the purpose of widening or stretching to the width, leather, linen, cotton^ and woollen stufls. March 3. . METEORO-^ S8S Meteorology^ METEOROLOGICAL TABLE, Bv Mr. Carev, op the Strand, For April 1 803. Xy,\\% of the iVlonth. Thermomerer. P 5 « ^ ! Height of ^ '^j the BaioiTi. 'c '*^ \ Inchtb. Weather. March 27 28 29 30 31 April I 2 3 4 5 6 7 8 9 10 U 12 13 14 15 17 18 19 $0 21 23 24 ?5 26 35^ 34 33 33 36 32 27 33 42 51 52 53 39 3S 46 48 47 40 48 16 39 37 U 40 34 4l 39 40 4i ^ 39 i s« ! 35*^ 37 42 39 41 42 40 48 46 54 57 58 51 52 55 54 47 57 58 63 51 53 46 33 47 47 4/ 49 49 4^ 45 35^ 32 33 32 31 30 30 40 49 5i2 52 50 46 45 50 49 39 4G 47 j 46 I 35 ! 36 I 35 ! 32 j 40 I 35 I S•? 2 36 18 47 2 3^ 2 15 3-3 10 21 26 31 2 3i 7 15 7-3 13 1 29 10 2 3 22 14 59-6 14 40 30 49 2 2{ 17 14 36-6 34 6 50 12 2 1 2 13 27-5 39 46 55 51 2 0 7 12 52-p 40 33 56 38 2 0 2 12 49*0 42 19 58 23 1 9\ 12 12 37*5 44 21 22 0 25 1 9 24 12 27*5 ** From 12^ 50"" to 13^ 40"" per clock, or from 21^ 56"^ to 25^ 46"^ apparent time, I measured the horizontal diameter of Mercury, which, from a- mean of 26 observations upon the scale, amounted to 1 1-646 of the vernier; and from a mean of 27 off the scale, it amounted to 15*255 parts of the vernier; the mean of both amounts to 11*646 parts of the vernier, or 8^'*1 7 ; aild the correction of the vernier is— 0"-95 of its parts, or — 0^^*73. "By a mean of 21 measures the Sun's horizontal diameter was 5 inches 0^- tenths 8*253 vernier, which diminished by 0'95 the correction of adjustment leaves 5 inches Of tenths 7*3' vernier = 5*0646 inches, answering to 32' 25 "*4, the apparent diameter of the Sun ; from which we derive the value of the scale. *' At 14^ 51"" 36'*8, or 23^ 57"* 2r*4 apparent time, I observed with the 46-inch achromatic telescope the thread of light between Mercury and the Sun's limb to break, or the Transit of Mercury over the Sun, 291 the true inlernal contact at the exit of Mercury. Mr. Richard Best*, who was observing near nie with a five-feet achromatic telescope, made the same observation exactly at the same time. The regular circumferences of Mercury and the Sun appeared in contact about two seconds later, the small ligament joining the limbs of Mercury and the Sun being for that space of lime plainly visible. * ' The external cbntact of Mercury and the Sun wds otDserved at 14^ 53"* \6^'S or 23'-^ 59"" P*l apparent time by myself, 14 33 13-8 23 58 58'1 by Mr. Best. T. FlRMINGER." Method employed in reducing the Measures of the Distances taken lij the Micrometer^ hetween the nearest Limbs of the Sun and Mercury. (See Plate VIII.) LetO (Fig. 3.) be the centre of the Sun, AC the apparent path of Mercury, A O, BO, C O, any three observed distancesj C D a perpendicular to AC, B F a perpendicular to A O, and B E a right line parallel to C O meeting A 0 in E. Then, because the differences of times between the observations are given, and the planet's relative motion is nearly uniform, the proportion of A C to A B, or of C O to B E, or A O to A E, is given^ being as the time between the first and third obser- * To this gentleman, who is extremely fond of astronomy, I was greatly indebted for the assistance he afforded me during the whole time of the transit : his readiness in reading off the scale of the micrometer enabled me to pro- cure at least double the number of measures I could otherwise have done; Throughout the whole of the measures, every possible care was taken in making the exterior circular limb of Mercury to touch the nearest interior limb of the Sun ; but in the middle of the observation, and at a time when these distances were most wanted, I was prevented from, proceeding with so much accuracy, or acquiring so great a number as I could have wished, in consequence of a part of the micrometer coming up against one of the sup- porting pieces of the object end of the telescope -, a Circumstance I was un- prepared to meet, having never used the micrometer before, or understood that such a defect existed. I mentioned this to Dr. Maskelyne when he re- turned, (he being in Wiltshire at the time of the observation,) who said he had often met with the same circumstance when observing the lucid parts of the Sim in a solar ecUpse. This defect was soon afttf.- remedied by Mr. George Doliond, by a very simple plan I suggested to him of making the sup- port of the object end of the telescope to shift, by conneciing it to a move- able collar; T 8 vaiions 292 Reduction of the Observation of the vations to the time between the llrst and second. Therefor* A E, B E^ and O E, are given. But O E is to (B 0 + BE) as (B O - B E) to (O F -^ F E),and B'F^'lfc '(B E -K F E) x (B E - F E) ; whence A F, iB F, and the angle O A D he- Softie known, and conse(|ucntly the nearest distance O D oF lh6 centres,. as also A D the distance Merfciiry' his to move from the tirst obsefvatioa to the middle of the transit, vvhicli distunce divided by the horary motion will give the time. The horary motion may be -either taken from the tables,- or found from the observations, being = A B x 3600'^, and divided by the time elapsed between the first and second observations taken in seconds, and is the method here used In determining the nearest approach of the centres, and ap- parent middle of the transit. But they may with equal ease be determined from the following algebraic formula which the analysis gives us. t^et A, B, D, be the first, second, and third distances, and x, y, z, the elapsed times between the tirsi and second, second and third, and first and third observations ; then .will the time between the first ohservatio!) and the middle of the transit be _ y ^ '^~+~^' X A^ - z" B"- + .^' D Aud the nearest distance of the centres will be had from this ibrmula : J/ A + z B -f xD^ y A - a ii- 4- .t D x y A -|> g 13 - x D x s- B - i, A 4- rl) 4X1/Z X 2/ A^ - 2 B' Vjc D^ Assuming the apparent horary motion of Mercury = 355'^-37o, the nearest apparent approach of the centres comes out = 6o'^'l37, at 21'' 14'" 4()'\d apparent time, as deduced from the following set of observations. Several others were calculated, which do not agree so well *, thouoh their mean approximates to nearly the same quantity. Jf the horary- motion be deduced from the observations, and not taken from, the tables, the middle of the transit will come out about six seconds sooner. * Owing to the defect arising' from the micrometer not being prdpef! v VI. ;•. nag cable, as Ims been already itnted. '1'. F. ■■• -- Observations, It. nearest dist. Appt. time. // h. m. s. 60-215 21 14 40-3 60-213 40 4^ 60-171 40- 5" 60-437 39'4 59-648 42-8 Transit of Mercury over the Sun. 293 Olservatidns. 1st, 1 Ith &c 12th - 1st, llt1i & I6th - 1st, nth & 15th - 1st, 11th & 14th - 1st, lOlh & 18th Mean 60-137 21 14 405 Tf S'^'S be taken for the mean parallax of the Sun, the horizontal parallax of Mercury from the Sun on the rlay of the transit is 4^'' 1221 3, and at 21*^ 14^ 40'-5, the parallax in longitude will' be — 2"-6775, and the parallax in latitude + 2".9923 to be applied to the apparent place : therefore the geocentric nearest distance of their centres was 62''- 7 1 at 21^' U*" 10' apparent time. From the above data several theorems have been given for computing the effect of parallax in accelerating or retarding the time of the beginning or end of a transit. The follow- ing method, which is here employed, is as simple as any, and will be found sufficiently accurate. Let O (Fig. 4.) represent the centre of the Sun, M D the relative path of Mercury, M its geocentric place at .egress, and D at the nearest approach to the Sun's cehlfe : joih O D, O M, and in D O take D 0, equal to the parallax at the egress perpendicular to the path ; draw ^'jx, meeting the Sun's limb in |Lc and parallel to D M, and ^ p perpendicular to D M, and take p m in D M produced equal to the parallax at the egress in^ the path ; then will ^u, be the apparent place of Mercury at the egress, and m its place seen from the P^arth's centre, as is manifest from the construction. Now the egress is accelerated or retarded by the time Mercury takes to describe M w, which is = mp +, pM; and as the: M O D -h a O D, angle |u. M p is = ~ — — p M = ftp x cot } (MOD + ju^OD), and M 7?i = M p + y. p x cot i (MOD + jw, O D) ; but if m C the parallax in longitude be put = TT, ftC the parallax in latitude = |S, and the angle M m C or the angle which the relative path makes with the T 3 ecliptic 294 ReducitoH of the Observation of the ecliptic =z (p^ m p will be = tt cos

e^ when the Sun's true place from the mean equinox by Mayer's tables was 7** 16^ 17' 13"*3, or 7" 16^ 17' 8"*5 if we take into account the correction to be made in the tables which the Greenwich observations make — 5" nearly. Hence the place of the node is found to be 1* 13^ 5S' 56"-3. LVIir. Geological Journey to Mount Ramazzo in the Jp- pcnines of Ligurm ; Description of this Mountain; Dis- covery of' the true VarioUte in its Bed ; of Lime ; of the Arragonife ; and of Martial, Magnetic, Cupreous, and Arsenical Pyrites, in the Steatitic Rock ; Manufacture of the Sulphate of Magnesia, By M, Faujas St. Fond*. Xn 1780, Messrs. de Saussure and Pictet visited the moun- tain Madona della Guardia, elevated 422 toises above the level of the sea, and of which mount Ramazzo forms a part. 2\fter having given an excellent lithological descrip- tion of the first mountain, Saussure thus expresses himself f: *' On ascending and descending the mountain della Guardia, we had a view to the westward of a mountain, from which we were separated by a very deep ravine, and from whicU we were informed that martial vitriol had been extracted ; but I had no knowledge of the substance in which it was found. At the distance from which we saw this mountain, it seemed mixed with slate and ferruginous earths." It was this mountain, (known by the name of Mount Ramazzo,) thus neglected by Saussure, which principally occupied my attention for two reasons : in the first place, because I had been told that trenches were dug at the sum- mit of this mountain, and that a manufacture of sulphate of magnesia had been established there : secondly, because, the steatitic and serpentine rocks of this mountain being united to lime in certain points, I was anxious to visit this curiositv so seldom discovered. * "From Annates du Mushim d* HJstoire Naturelle, tome viil. p. 313. t ^'"!i"S^ acy^'auisurt dans tes Jlpes, tome iv. p. 145. M. Max!- in the Jppenines of Liberia. 297 . -M. Maximilian Spinola of Genoa, who is skilled in seve- ral branches of natural history, M. Viviani a botanist, and my friend M. Marozari of Vicenza, an excellent minera- logist, were anxious to accompany me. We took our depar- ture at six o'clock in the morning from Genoa : we went in a carriage to Cornigliani, where we visited M. Durazzo's rich collection in natural history : from thence we proceeded to Sestri, where M. Alberto Anseldo conducts a manufac- tory of sulphate of magnesia with great spirit. This gentle- man acted as our guide in the arduous excursion we were about to rnake : our route lay through narrow by-ways, profound ravines, and we were obliged to climb from rock to rock, which were so flinty and slippery, that they re- quired some experience in alpine travelling to surmount them. We left our carriages at Sestri, and immediately en- tered the bed of the river Charavagna on foot. We ascended this torrent for about an hour. Its bed is broad, and wholly covered with blocks of serpentine and other round stones; which shows that it is subject to dreadful torrents ; but there is scarcely any water in it in dry seasons. The follow- ing are the remarks I made on ascending to a lime-kiln, which I shall speak of by and by. Notice upon the Stones in the Torrent of Charavagna, 1. Various pieces, larger or smaller, of a grayish steatitic rock, of a drier grain than that of the other steatites, of which I shall soon take notice. This rock has fissures or cracks filled with greenish crystallized epidole, similar to that of the alps at Oisan in the ci-devant Dauphine. I am surprised how this rock escaped the attentive and vigilant eye of Saussure. It is probable, since he has not mentioned it, that the torrent of Charavagna was not then ])assable, or at least when he visited the mountain della Guardia. 2. Tender serpentine of a blackish green shaded with light green, and shining as if varnished, soft and even unc- tuous to the touch, radiating into white streaks, wiih a striated and undulous fracture, having a talcky appearance, and strongly obedient to the magnet. 3. Serpentine, soft, aud analogous to that of No. 2, as to the f ^^ Geological Journey io Mount RdiHazzo the constituent parts; but its colour is of a clearef gre^n : its surface is much rrtore glossy than that of the preceding, and its fracture mare gcntrr-liy imduF^tfed : but! what parti- cularly distinguishes this beautiful speciihcri, which is sev^rt inches long by five broad, is, that it is not only very attraict- able by the magnet, but endo\<^ed with a Strong polarity throughout its wholfe length ; and it attracts keenly al! one. end, v^'hile it even repels with the Other. 4. Serpentine of a deep green^ with some sliadeS of ^ cTeai'er green, soft to the touch, but harder than (he pre- ceding, having one of its facets striated, and something like asbestos. 5. Another serpentine somewhat hard, of a greenish black, with small spots of a greenish white near to each' other,' anid which seem to have a tendency to the parallelo- pipedon form, which gives to this variety of serpentine a false aspect of black and white antique porphyry. But what renders the latter remarkable, is, that it coritains in its sub- sta-^ce, as well as upon its external facets, a multitude of very brilliant small silvery scales of metalloidal appestrance {dial- iage), the brilliancy of which is the more lively, as it shines upon a black ground. This serpentine is strongly attracted by the magnet. 6. Semi-hard serpentine, attractable, of a deep greenish black, with some laminae of metalloidal appearance like silver, and small layers more or less thin, but some of them a line in thickness, of a substance of the nnctubus appearance of Steatite ; and its colour being olive-green, shining, and of an equal and rich tint, seems to be owing to chrome. 7. Semi-hard serpentine of a blueish-gtay, with longi- tudinal compressed streaks, covered with a slight and trans- parent couch, or rather with a kind of varnish of a deaf azure blue. We also distovet* rn the fractures bf this beau- tiful serpentine, some scales of a metalloid diallagc, and of a silvery hue ; it is attractable by the magnet. 8. Serpentine of a deep greenish-gray, semi-hard, feebly attractable, with small round globules, sometimes oblong, of a compact white or greenish substance, harder and more tiojnogeneous than that of the stone which contains them, of in the Appenlnes of Liguria, 299 of a steatitic aspcgt, and presenting, when we look at it through the microscope, very fine lineaments which unite aboiU the centre of each globule. Here we have a true va^ riolite, which ought not to be confounded with an amygda- loid. The specimen I have described, and which was con- founded with the other stones I have mentioned in the bed of the Charavagna, is more remarkable from the globules being distinct, a little projecting and distinct from each other, a^ in the variolites of Durance, occupying one-third of the size of the specimen ; they are also much nearer together, and seem to touch, and they are confounded afterwards 5 forming at the extremity of the piece but a single couch where the globules have disappeared, Jind where the same substance of which they are composed no longer affects the regular form. This stone fixed my attention, since it gave me reason to expect a variolite analogous to that of Durance, in a place where no jierson had met with it, or even suspected it to exist. As the globules, however, of the true variolitfe belong to a substance very like feldspar and fusible like it, and as I have neither met with compact feldspar, (petro-silex of the Germans,) nor feldspar under other forms ; I think the round variolite which I found, was one of thofe stones transported in great revolutions of the earth, and out of its proper place. I made these refjections when advaricing up the bed of the torrent ; but I suddenly discovered a stony mass of a white or greenish hue, weighing more than thirty pounds, which, at fjrst sight, awakened in my mind the idea of feld- spar : it may be described as follows : 9. Compact stone, with fine paste, translucid upon the edges, soft to the touch, of a white slightly tinged wjth asr paragus green, having the appearance of jade, breaking into scales rather lamellous than conchoidal, scratching glass strongly, and emitting some sparks when struck with steel ; but it is not so hard as the jade. In the blow-pjpe it bub» bles up almost as soon as the fire touches it, and melts very soon into a yellowish transparent glass. On breaking this 2 stone. 300 GeologJcal Journey to Mmint. Ramazzo stone, we perceived, some partsf, of a lively apple-grccn, ar- ranged in small elongated laminae, flat arfd of a silky lustre, owing to the diallagc. I consider this stone as a true compact feldspar, mixed with a little steatitic- serpentine, and with iridescence {(iiallage): it is this mixture which contributes, perhaps, to its great fusibility. I found another piece of it weighing more than twelve pounds. With the blow- pipe I made a comparative trial of the greenish-white globules of the variolite No. 8, which I found in the bed of the torrent, and they bubbled up and melted with the same facility as the stone I have described. Now, as the latter was of a large volume, and did not ap- pear to come from any distance, for its angles were scarcely abraded, I presumed that it should abound in some parts of the neighbouring mountains, in the direction of the torrent which had received these fragments, and that it v/as perhaps found in a furrow, or mixed into the paste itself of some of the serpentines, which T thought 1 should find in its proper place. In fact, it was natural to think that the junction of the molecules of feldspar in globules, at the time of the formation of these mountains, might have given rise to va- riolltes analogous to those known by the name of varioUtcs (f Durance ; and thence I did not lose hopes of finding this kind of stone in the same rock which contributed to its formation. 10. Finallv, the bed of the torrent, in proportion as I ad- vanced, presented me with various fragments of a compact calctreous stone, hard and of a fine paste, susceptible of beinn; polished, with some veins of calcareous spar which traversed it ; I saw also some of the same spar adhering to a rein of white quartz. These calcareous stones found in a considerable number, beside the serpentine, magnesian, and feldsparry stones I have mentioned, left me also some hope of being able to observe the points of contact of the magnesian with the calcareous rock in a country quite free of wood, and torn up by tor- rents, presenting great hills and deep ravines. Reflecting in this manner, I advanced a little further, and in a deep in the Appunines of Liguria. 'doi , recess formed by the 'torrent of the river, I perceived upon an eminence on the right ban4c of the Charavagna, a rustic habitation, and a large lime -kiln at work. Of the Calcareous Stone proper for being converted into Lime: of its Bed beside Serpentines, The lime-kihi used for calcining the stone, the singular situation of which 1 shall soon describe, is of so peculiar and unusual a construction, that it is worthy, of pur atten- tionl In consequence of the extreme scarcity of Wood, the saving of fuel has been their principal object : he;ith and broom only of a large size are used for this pur- pose ; these give a brisk but not a durable fire, and it be- comes necessary to endeavour to preserve the heat as much as possible. For this purpose, they have constructed of strong and good masonry, a kind of square tower, sur- niounted with a pyramid-formed capital of solid stone, which s.erves as a kind of roof, and forces the heat to reverberate upon the calcareous stone divided into fragments and in- tended to be calcined. A simple straight aperture towards the top of the vault serves for letting out the smoke, and the humidity which exhales from the calcareous stone and combustible; and it establishes a current of air necessary for keeping up the fire, which being concentrated in a great measure by the obstacles opposed to its wasting, acquires a greater and steadier intensity. If, in some peculiar circum- stances, they require a greater current of air, it may be easily obtained by opening a small door placed, in one of the faces of the pyraniidal wall, which serves as a roof to the furnace. The lime-stone is introduced by a door made behind 'the furnace, and it is withdrawn by the same aper- ture when it" is calcined : the combustibles are placed below upon a grating.. The quarry of Hme-stone is not far off, and is to be seeri in the kind of ravine which serves for the bed of the torrent. As my intention was to follow it in several points, so as to become well acquainted with its situation, 1 continued to asfccnd the torrent of Charavagna, by a route which becomes more rapid as we advance. The soil was every where loaded 7 i ' with 302 Geological Joimiey to Mount Ramazzo with serpentines of various kinds similar to those I have mentioned : but there were also found considerable blocks of amass composed of fragments of the serpentines above de- scribed, and of the same lime I have mentioned, and similar in every respect to that of which the lime is made : this mass is strongly united by a calcareous sparry cement. A second kind of mass, also arranged in large blocks, is to be found in the neighbourhood of the first : both have been detached from the neighbouring mountains, and do not seem to have been brought from any distance : the one in question is composed only of larger or smaller fragments of different kinds of serpentine, which have entered into the composition of the neighbouring mountains ; but we find no lime in it as in the first mass, and the cement which has imited these serpentines has lime in it, being entirely stealitic. We soon met with these two varieties of masses again upon the edges of one of the ravines of the torrent, on the one edge beside some serpentines, and on tlie other adhering to lime. It seemed at first sight as if these masses served as intermedia, and were passing from one genus to another : but in examining them again, and reflecting that they must have been formed at the ex- pense of the calcareous and steatitic rock, both of which must have had at this period the same consistency and the same hardness as at present, we could only attribute this formation to an accidental revolution, long subsequent without doubt to events of another order, which have given birth to these mountains of serpentines, and to the calcareous beds adhering to them, and which have furnished the materials for these two masses. But let us now cast a glance upon the lime in its bed, and see if it be cotemporary with the serpentine rock, or if it be subsequent. At a certain distance from the lime-kiln, and not far from the hamlet of Serra, placed in an amphitheatre near the precipice which hangs over the torrent of Chara- vagna, we may observe in a very distinct manner a part of the calcareous layers in their points of contact with the mag* nesian rock. I give the preference to this spot over that which is noarertbe lime-kiln, because vye see more distinctly the ijhfye Appenines cf Llgip'ia. 303 the junqtiou of bpth s,ubstances ; and the doubts we might raise as to the lime-stone placed against it secondarily, and afterwards .against the serpentine rock, disappear entirely uf>on examining the. j:acts T haye mentioned. In short, when the torrent in its various overflowings, and when after storms its waters are' precipitated from precipice to precipice with a violence and impetuosity car- rying every thing before it, and laying bare the calcareous and serpentine beds, ^so as tp present \.\q \vhole at full view ; w,e then remark tVie gPfiy, hard, and .compact lirne-stQue, which is modified into white calcareous spar, and forms large strings or lineaments, which are joined and interlaced with v^ry .small layers ot linea^iients of ateatitic serpentine. These lineaments sometimes increase, and are developed Ipngituflinally, and like stripes of a gray or greenish colour around longitudinal or circular laminae of calcareous spar of a white colour. In other parts adjacent, the two substances forip a Iqind of net work. In a word, we think we can per- ceive in the union and in the play of these two substances, so different in their nature, the results of the movement of the fluid which held both in solution at one and the same time; and we only know the waters of the sea, and their long. continuance upon these regions, at very remote periods, as having acted upon masses which, constitute chains of mountains. Every thin^, therefore, inclines us to think, that.in this case the lime-stone has been attached, or rather joined, to the magnesian rock, not by an after process, but in one and the sarpe operation, when, great accumulations of dis- solved calcareous matters being, in the neighbourhood of substances which have given bnlh to the serpentine rock, their mplecules floated in the same fluid, which gave rise to points of meeting, contact, union, and mixtuie, similar to those we observe here. Nothing proves ipnore completely that tbis mixture is ma^e f*jmultancously than the ehemicaf state of these two substances ; for the purest of the lime-stone contains 6, 7, .ai)d even 8 pi;r cent, of magnesian earth, while the serpentine rQckibfUi as much lipac-^ioue i;;v ii^^piass. Saussure. 304 Geological Journey to Mount Ramazzo SaussLire had reinarked upon the mountain della Guardia, an alternation of calcareous and serpentine layers ; whicli, is perfectly analogous to what I have here described. . But as such an operation could not be performed at a single jet, we cannot refrain from remarking here also that nature never takes into her account the operations of time. Of the true Variolite (Variolites viridis verus) in the same Rock in tvhich it has been produced. As our object was to visit the quarrying of the materials used in the manufacture of sulphate of magnesia upon th^* highest part of Mount Ramazzo, M. Alberto Ansaldo, who guided us, informed us that we must leave the bed of the Charavagna, pass to the hamlet of Serra, and ascend over shelving precipices into a direction opposite to that of the torrent. The road, or rather the pass, was strait, rapid, and slippery 3 we were surrounded on all sides by ser- pentine rocks more or less green ; some were hard, others S'jft : the grain of them also varied ; in some places it was dry, and in others greasy and unctuous : enormous masses, placed upon still huger masses, spread spontaneously, some into irregular leaves more or less turned, and others into striated pieces imitating asbestos : the d'lallage was distinct^ in some fractures, and exhibited a silvery lustre ; in others - this was not to be seen ; and in this case the heart of the stone, being of a deep blackish green, presented shades of a clearer green. We had ascended at least six hundred feet in height from the hamlet of Serra; when being at this height, not far from a small stream of water which runs through the pass, and might serve as a point for reconnoitring, I per- ceived a detached piece of serpentine, the surface of which was covered with small globules of a whitish green, a little projecting, and harder than the paste of the stone. I saw with pleasure that it was a vavlolite not rolled nor trans- ported from its place, but detached spontaneously by the effect of moisture, or th«r alternation of heat and cold, from an enormous mass of serpentine which was contiiruous. ^ This in the Jppenines of Liguria. 305 This fine specimen is five inches \oug by three bl-oad ; one of its facets presents the whole characters of a fine green variohte, with small grains projecting a little, and of a green much clearer than the heart of the stone, while the opposite part is a true serpentine of a dark green, without globules or variolitic spots* We could not doubt, after looking at this specimen, that the substance which was joined in glo^ bules in order to form this variolite, was the result of an as* semblage of a certain quantity of feldsparry substance, the elementsof which had been mixed in the serpentine rock at the time of its formation. This kind of separation may be con- sidered as the result of a globulous imperfect crystallization, determined by the attractive force of the feldsparry mok- cules, which had more affinity fcr each other than for the jnagnesian earth J and if these variolitic globules are only superficial as it were, (for the bed m which we remark thera is little more thajn three Unes thick,) it is because the sub- stance of the feldspar was not abundant. In short, the identity of th€ globulous substance is absolutely the same with that which I found, separated and in voluminous pieces, in the bed of the Charavagna, and which I have mentioned in No. IX of the description of stones found in this torrent. In fact, having attacked with the blowpipe son>e globules of the variolite in question, they swelled upon the first at- tack of the d-re, emitted some air bubbles, and formed a yellowish transparent glass, like the fddsparry stone abov<3 mentioned. A^ variolite equally well characterized,^ in the ucighbour* hood of the rock of which it had once formed a part, gave me good hopes of meeting with some more of them. These hoj^s were soon realised ; for after we had ascended 300 feet higher, we found beneath our feet several flat pieces, but angular, and of hard serpentine of a lighter or darker green fiUed with vK^iolitie globules, the grains of which were much thicker, and penetraitcd into the whole mass of the serpentine. I gathered several fi;;e specimens, some of which are six or eight inches loi^ by^n inch in thickness, and of so decided a character that we eaa easily distinguish with Vol. 30. No. IftO. May 1 808. U the 306 Geological Journey to Mount Ramazzo the microscope the commencement of the kind of radiated crystallization which is peculiar to each globule. The higher we ascended, the more of these specimens did we find at the foot of the rocks of serpentine. T ob- served with interest the general tendency these rocks natu- rally have to divide into sphnters, or into large flat and scaly fragments ; (this I attributed to a peculiar alteration of the iron so abundant in this kind of stone;) when I suddenly perceived upon the right of the pass, a mass of serpentine in its bed more than eighteen feet high, with a base of 40 feet broad, and which seemed as it were iso- lated, either by natural and spontaneous decomposition of the most tender parts of the rock, or by some other cause. 1 perceived upon this large mass some parts much greener than others, penetrating deeply into the heart of this enor- mous block, which was of a very dull blackish green. I approached very close, and I ascertained that most of the spots were produced by parts abounding in true variolite of a grass green colbur, and white spots or grains, shaded from an extremely clear green. All these parts formed in variolites seemed extremely hard : I had soon some proofs of this, when I struck them with a hammer, and it was with great difficulty f obtained some good specimens. Several of these pieces had a multitude of globules ana- logous and similar in every respect to the variolite of Du- rance : sometimes, however, the variolitic spots only en- tered to the depth of an inch and a half into the stone, and the rest seemed to be nothing else than a pure serpentinous rock ; at other places the vanolite entered deeper into the mass : in some places the granulous surface was not much larger than the palm of the hand ; in others it was double this size; in short, by continuing to observe more vario- lites in other blocks, I was convinced that this singular stone is not in a vein in the masses of serpentines, but that it exists indifferently, sometimes in one place and some- times in another, without order or regularity. It is the same with the arrangement of the globules : we see them huddled together upon some pieces, and as it were arranged in i?i the Jppenines of Liguria, 30/ in an equal and distinct manner, while they are thinly scattered upon others, or sometimes so close together that they are confounded, and form merely a large whitish spot. I shall finish these details by observing, that I possess among my numerous specimens a remarkable piece, which will demonstrate to those acquainted with the composition of rocks, that the variolite of Mount Ramazzo took its rise in a true serpentinous rock. I shall now describe this rare and curious specimen in few words. Its colour is the same with that of the other serpentines I have mentioned ; but the rock from which 1 detached it with the hammer was very hard, its texture very close 5 but striated at the same time in gi scaly manner; and its scales frequently interposed between the streaks, and intersecting them transversely, render this rock difficult to break : it is torn in some measure rather, than broken, and requires heavy blows with the hammer. In this way I procured this fine specimen with a fracture a little undulous, but pure and clean, and which admits of our seeing upon the two large faces of the stone its texture, as well as upon the rock it- self. We see perfectly upon a part which forms almost the half of the piece, and not only upon the faces but through- out its whole thickness, a multitude of variolitic globules of almost equal size, of a clear green, issuing every where from the streaks and scaly parts of the stone, as if they were sown in it : these globules become smaller afterwards in proportion as they approach that part of the specimen which has none of them ; and this last part is then nothing but pure serpentine mixed with some irregular and thin- lineaments of a white colour, not belonging to the variolite, and some of them slightly effervesce with the nitrid acid. From the above facts we see that the true variolite exists in Mount Ramazzo, and that it is cotemporary with the serpentines in which we find it at the height of more than 1500 feet above the level of the sea. It is to be presumed we shall find it at a greater elevation, and perhaps in still greater abundance, in other parts of the Ligurian Appe* oines. Us 0/ SOS Geological Journey to Mou7it Ramazzo Of the Mine of Magnesia upon the highest Part of Mount Ramazzo, The route becomes more and more difficult as we approach the rugged summit, where the quarries and establishment of M. Alberto Ansaldo are situated, nor do we lose sight of serpentine rocks the whole way : these are more or less compact, lamellous, streaked, glossy, unctuous, or dry and friable. We pass several ravines, and mount from precipice to precipice, until we come to about 1800 feet above the kvel of the sea, being the summit of Mount Ramazzo, where we find a small flat piece of ground, upon which are built some penthouses for preparing the mineral, and ap- paratus for stamping, roasting, leying, &c. ; — in a word, for extracting the sulphate of magnesia in a simple and in- teresting manner. This operation consists in carefully collecting a very py- ritous steatite, which is found rather in heaps and large fragments than in regular seams : they afterwards roast it, after reducing it to pieces, in order to evaporate a little of the arsenic which is combined with it. It is in this operation of Toasting that the sulphur which is combined with the iron is disposed to quit its base, and attaches itself to- the magnesian earth of the serpentine, in order to form the sulphate of magnesia. They pound this roasted pyrites in a rough man- ner ; it is then arranged in large heaps, which they water slightly : the combination with the magnesian earth is then; finished by a slow fermentation which the matter under- goes : these earths are afterwards leyed, and a very abun- dant sulphate of magnesia is obtained, which is purified and refined in another establishment belonging to M.. Alberto* Ansaldo, at Sestri. After having examined the first preparation of the ferru- ginous and arsenical pyrites of Mount Ramazzo, we entered the galleries of the mine, which are close to the penthouses t they are large, but the working of them is not regulated : they follow the pyrites and the pyritous steatite wherever they meet it, sometimes in a straight line and sometime* laterally, just as it presents itself. The excavations are made , - in in the Appenines of Liguna* 309 in an Irregular manner, and without any precautions for the safety of the workmen : the pickaxe, however, alone is used. The explosion by gunpowder would certainly bring down the roots of the quarries, which are no where supported by props or bulwarks. The various specimens I collected here w^re : 1st. A greenish steatite, the surface of which, as well as its interior texture, is penetrated with a kind of pyritous varnish of a bronze colour^ but so light and so efflorescent (if I may use the expression) that it seems as if the heart of the steatite, which is black, was shown through this kind of varnish. This pyritous steatite is very heavy ; it blackens paper, and moves the magnetic needle strongly. It cou- tiins a small proportion of copper, but scarcely percep- tible. 2d. The same steatite, still richer in pyrites, with the flight yellowish or bronze varnish I have mentioned, which seems to gild the black serpentine rock, is soft to the touch, blackening -the fingers, and forcibly obedient to the magnet. ,We find in the same rock arsenical magnetic pyrites, very tieavy, and with a metallic fracture of a grayish white. 3d. This is a rare and superb specimen, being five inches nine lines long by four inches broad : the base of it is a ser- pentine of a dee^i black, a little glossy, blackening paper, without a pyritous appearance; but very heavy, and strongly attractable by the magnet, remarkable from needles of trans- parent white arragoniie, one crystal of which is two inches three lines Ions; and four lines in diameter, of a hexao'onal figure, but always without a pyramid. Other crystals of a still greater diameter are to be seen, sometimes in kinds of cavities in the specimen, sometimes in the mass irself of the pyritous serpentine, and seem to have been formed si- multaneously with the pyritous and magnesian elements of which this rock is composed. 4th. We find a few yards from the quarries, and a little lower down, some old excavations, but not so deep : here there is a striated and silky-like pyrites, with beautiful green efflorescences qf carbonated copper. This steatite is Us soft 3 IP On Machines in General. soft to the touch, and has yellow ochrey spots in it, app$» rently proceeding from grains of altered cupreous and ter* ruginous pyrites. M. Ansaldo informed me, that this py- rites was formerly wrought for the sake of its sulphate of copper, but abandoned on account of its poverty. LIX. Essay upon Machines in General, By M. Carnot^ Member of the French Institute , &c, &€, [Continued from p. 221.] Problem, XX. 1 HE virtual movetnent being known of any given system of hard bodies^ (i. e. that ivhich it would assume if each of the bodies were free^) to find the real movement which it should have ihefolloujing instant. Solution. Let us denominate each molecule of the system, - - - - - m Its virtual given velocity, - '- - W Its real velocity sought, - , - V The velocity it loses, in such a manner that W is the result of V and of this velocity, - - U Let us now imagine that we make the system assume an arbitrary geometrical movement, and let the velocity which m will then have be - - - u The angle formed by the directions of W and V, X The angle formed by the directions of W and U, Y The angle formed by the directions of V and U, Z The angle formed by the directions of W and u, x . The angle formed by the directions of V and «, y The angle formed by the directions of U and u^ z This being done, we shall have the equation s m u\J cosine x = O (F) ; by means of which we shall find in all cases the state of the system, by attributing successively to the indeterminates u different relations and arbitrary direct' lions. Definitions. XXI. Let us imagine a system of bodies in movement \r\ any Oh Machines in Genet aL 311 any given manner : let m be the mass of each of these bodies, and V its velocity ; let us now suppose that we make the sy- stem assume any geometrical movement, and let u be the ve- locity which w will then have, (and what I shall call its geo- metrical velocity,) and let y be the angle comprehended be- tween the directions of V and u \ this being done, the quan- tity 772 7/ V cosine y will be named the momentum of the quantity of movement mW^ with respect to the geometrical velocity u ; and the smn of all these quantities, namely s m uY cosine y, will be called the momentum of the quantity of movement of the system with respect to the geometrical movement which we have made it assume : thus the momentum of the quantity of movement of a system ef bodies, iv'ith respect to any geometrical movement, is the sum of the products of the quantities of 7novement of the ho- dies which compose it, multiplifd each ly the geometrical velocity of this body, estimated in the ratio of this quantity ^ of movement. In such a manner that by preserving the de- nominations of the problem, s m uW cosine x is the mo- raentum of the quantity of movement of the system before the shock ; s muV cosine y is the momentum of the quantity of movement of the same system after the shock ; and s m u U cosine z is the momentum of the quantity of movement lost in the shock (all these momentabeing referred to ihesamegco- Jiietrical movement). Thus, from the fundamental equation (F) we may conclude, that in the shock of hard bodies, whether these bodies be all moveable, or some of them fixed, or, what comes to the same thing, whether the shock be immediate, or made by means of any machine without spring, the momentum of the quantity of' movejnent lost by the general system is equal to zero, W being the result of V and U, it is clear that we have W cosine x = cosine y •\- \] cosine z, or m u W co- sine X — m uY cosine y -\' m 2l\] cosine z, or lastly, s mu\Sl cosine x = smuY cosine y •\- s m u U cosine z : now we have found s m 7t \] cosine 3; = .0 ; therefore s m uW cosine x -i- s muV cosine ?/, that is to say, in respect to any geometrical movement, the momentum of U 4 the 3-1 2 On Machines in General^ the qucnitUy of movement of the system^ immediately after the shock, is equal to the momentum of the quantity of move- merit immediately htfore the shock. When we decompose the velocity which a body would assume if it were tree, into two, one of which is the velocity it actually assumes, and the other the velocity it loses ; and reciprocally if we decompose the velocity it loses, into two, one of them being that which it would have taken if it had been free, the other will be the velocity it gains : whence it visibly follows, that what we understand by the velocity gained by a body, and what we understand by its velocity lost, are two quantities equal and directly opposite :^ this being done, the momentum of the quantity of movement lost by 7n, with respect ^o the geometrical velocity «, being, according to the preceding definition, m u U cosine 2, the momentum of the quantity of movement gained by the same body will be — w z/ U cosine z ; for there is no dif-^ ference between these two quantities, except in this, that the angle comprehended between u and the velocity gained is the supplement of that comprehended between u and U ; so that one of these angles being sharp, the other will be obtuse, and its cosine equal to the cosine of the other, taken negatively. Hence it follows^ that the momentum of the quantity of rnovement lost by the general system, with respect to any geometrical movement, (which is null, as we have seen above,) is the same thing as the difference between the mo- mentum of the quantity of movement lost by any part of the bodies which compose it, and the momentum of the quantity of movement gained by the other bodies of the same system : thus this difference is equal to zero, and thus the one of these two quantities is equal to the other ; that is to say, the momentum, of the quantity of movement lost in the shock hy any part of the bodies of the system, with respect to any geometrical mpvement, is equal to the momentum of the quantity of movement gained by the other bodies of the same system. We may, therefore, from the preceding definition, col- lect the thre^ propositions contained in the following Theorem. On Machines in General, 313 Theorem. XXII. In the shock of li(D-d todies, whether this shock le immediate, or whether it he made lij means of amj machine jvithont spring, it is clear that in respect io> ajiij geometrical 7novement, — \st. The momentum of the quantity of movement lost ly lite whole system is equal to zero, 2d, The momentum of the quantity of movement lost ly any pait-of the bodies of the system, is equal to the momen- turn of the quantity of movement gained by the other part, 3d. The momentum cf the quantity of real movement of the general system, immediately after the shock, is equal (a tlie momentum of the quantity of movement of the same sy- stem, immediately before the shock. it is clear, from the preceding definition, that these three propositions are radically the same, and are nothing else than the same fundamental equation (F) expressed in dif- ferent ways. We may also remark that these propositions bear a great relation to those we extract from the consideration of the Tuomenta relatively to different axes ; but the latter are less general, and are easily inferred from those established in XVII. There is, therefore, as we see by the third proposition of this theorem, in every percussion or communication of movement, whether immediate, or caused by the intermedium of a machine, a quantity which is not altered by the shock : this quantity is not, as Descartes thought, the sum of the quantities of movement ; nor is it the sum of the active forces, because the latter is only preserved in the case where the movement changes by insensible degrees, as we shall see lower down, and it always diminishes when there is percussion, as will be proved in the second corollary. When the system is free, the quantity of movement estimated in any ratio, is in truth the same before and after the per- cussion; but this preservation does not take place if there are obstacles, any more than that of the momenta of quan- tity of movements referred to different axes : all these quan- tities 314 On Machines in GeneraL titles are therefore altered by the shock, or at least are only preserved in some particular cases. But there is another t^uantity, which neither the various obstacles opposed to the movement, nor the machines which transmit it, nor the intensity of the different percussions can change ; it is the momentum of the quantity of movement of the general sy- stem, with respect to each of the geometrical movements of which it is susceptible ; and this principle contains in it- self alone all the laws of equilibrium and of movament in hard bodies: we shall even see in corollary 1\^, that this law equally extends to other kinds of bodies, whatever be their nature and degree of elasticity. If the shock destroyed all the movements, we should have V = 0 : therefore the equation would be reduced to s m W u cosine x = 0 ; which shows us that this case hap])ens ; namely, that all the movements are reciprocally destroyed by the shock, in the case where, immediately before this shock, the movientum of the quantity of movement of the general system is null, relatively to all the geometrical move- ments of which it is susceptible. First Corollary. XX TIT. Among all (he movements of ivhich any system of hard bodies acting upon each other is susceptible, whether by an immediate shock, or by any machines without spring, that movement ivhich shall really take place the instant after- wards will be the geometrical movement, which is surh that the sum of the products of each cf the masses, by the square of the velocity which it ivill lose, is a minimum, i. e. less ihan the sum of the products of each of these bodies, by the velocity it would have lost, if the system had taken any other geometrical movem'^nt. Here it must be remarked, that, by giving for the mini- mum the sum of the products of each mass, by the square of its velocity lost, I understand solely that the diffe- rential of this sum is null ; i, e. that its diflerence from what it would be if the system had a geometrical move- ment infinitely little different froni the first, is equal to zero : thus On Machines in General. Z\% thus Ibis sum mav be sometimes a maximum, or even nei- ther a maximum nor a mi?iimum ; and 1 have only to establish d s m U* = 0. Demonstration. — It is at first evident that the true move- ment of the system after the shock should be geometrical ; for geometrical movements being those which do not alter the action which is exercised among bodies, it is clear that the first in order is the same movement as assumed by the system : it is therefore required to know, which, among all possible geometrical movements, is the one that should take place. Now, supposing that it should take another infinitely Jittlc different from that which we are seeking, the velocity of each molecule m would then have been V; let us decom- pose V'' into two, one of which shall be V, i. e. the real ve- locity, and the other V' : this being done, it is evident that if the bodies had not other velocities than these last V, the movement would be still geometrical, for V^^ is visibly the riesult of V' and of a velocity equal and directly opposite to V: now, bv hypothesis, the molecules taken two by two do not tend, either in virtue of V, or in virtue of —V, to approach or recede, since in these two cases the movement is geo- metrical: thus, by. supposing that the molecules w have at once the velocities V and — V, or their result V', they will neither knd to approach nor to recede; and therefore the movement will then be geometrical : thus, if we call z' the angle comprehended between the directions of V" and U, we shall have by means of the fundamental equation (F) s m U V' cosine 2 = 0: on the other side, let us call U' the velocity which m would lose if its effective velocity were V, so that W would be the result of V and U^ it would necessarily follow that U' would be composed of U and of a velocity eq.ial and directly opposite to V'; whence it evidently follows, that V'—U or d U z= — V' cosine 2"; therefore the equation s m U V' cosine z' — 0, found above, becomes s 7?i \J d U -= 0 or d s jn U' = 0. Suppose, for cxaniple, tv\o globes A and 13 striking each other obliouely, I demand their movements after tlie phock. Suppose 316 On Machines in General, Suppose that the velocity of A, estimated according to the line of the centres, was before the shock g, and after the shock V ; that the velocity of B, also estimated according to the line of the centres, was before the shock I, and after the shock u; that {he velocity of A, estimated perpendicu- larly to the same line, was before the shock a, and after the shock V ; finally, that the velocity of B, also estimated per- pendicularly to this line of the centres, was before the shock l\ and after the shock u' ; this being done, by our proposi- tion, the movement being necessarily geometrical, we must at first have V= 7^; thus the velocity lost by A, according to the line of the centres, will be a — w, and that lost by B, in the same direction, will be Z' — 2^ : besides, in the direction per- pendicular to the line of the centres, the velocity lost by A will be a' —V', and that lost by B will be h'—u'; there- fore i/(a — «)* + (a' — V')* will be the absolute velocity lost by A , and that lost by B will be // (i — u) ^ ^ {h' — u') *: therefore, according to the proposition, we should have J [A (a - uY + A ((?' -Vy + B {h^uy + B (^' - w) ^] = 0,orA(a-z/) d u •{• K (a'-V) dY' + B {h'-u)du-\-E ^I'^u") d u' = Oj an equation which should generally take place, 2. e. whatever be the values of du, dY\ and d u' : therefore the co -efficient of each of these differentials must be equal to zero ; which gives V = g', u' ~ h' ^ and u—Ka + Bi. a.E.D. ;^^^ It is clear that this proposition contains all the laws of the shock of hard bodies, whether this shock be immediate, or be made by means of any machine, since it assigns the character nnder which we recognise, among all possible movements, that which should really take place at each in- stant : this principle has a considerable analogy with that found by M. Maupertuis, and by him called prindpe de la snoindre action. See his "Essai de Cosmologie.'* Second Corollakf. XXIV. In the shock of hard bodies, whether some of them ,uref.xcd, or all moveable, or {iv hat comes to the same thing) whether On Machines in General, 317 whether the shock be immediate^ or given hj means of any machine without spring, the sum of the active forces before the shock is always equal to the sum of the active forces ajter the shock, plus the sum of the active forces which would take place if the velocity which remains to each moveable body were equal to that which it has lost in the shock. That is to say, we must prove the following equation , 5mW* = 5 Tw V* -f 5 771 U^ Now it is easily deduced from the fundamental equation (E) ; for W being the result of V and U, it is clear that W V and U are proportional to the three sides of a certain triangle : thus by trigonometry we have W^ = V* 4- U* + 2 V U cosine z : therefore s wW* = s mV^ + s mU^ + Q s mVlJ cosine Z : now by the equation (E) we have s mV \J cosine Z = 0 ; therefore the preceding equation is reduced to s m VV^ = smV^ + s m U*. Q. E. D. We see, therefore, as has been said (XXT), that by thi:^ transformation the analogy of the equation (E) with the pre- servation of the active forces becomes striking : we may also easily demonstrate the one by the other, as we shall see in XXVI. The analogy of this same equation with the preservation of the active forces in a system of hard bodies the move- ment of which changes by insensible degrees, is still more evident, since it then regards a case peculiar from that we have examined ; it is in fact visibly the particular case where U is infinitely small, and therefore U^ is infinitely small of the second order ; this reduces the equation to s m W* =^ s 7n V* : but this preservation will be explained more at length in the following corollary. Third Corollary. XXV. When any system of hard bodies changes its move- ment by insensible degrees ; i/', for a moment^ we call m the Tuass of each of the bodies, V its velocity, p its vis motrix, R the angle comprehended between the directions ofV and p, u the velocity which m would have if we made the system take any geometrical movement, r the angle formed by u and p, 3 ythe S 1 8 On Machines in General, y the cm gle formed by V and u, d t the element of the time ; tee shall have these two equations: smVpd /cosineR — s wVfl^ V=0: smup d t cosine r— s mud (V cos y.) = 0. Demonstration. — In the first place, pdt cos R is visibly the velocity which the vis motrix p would have impressed ujx)n w in the direction of V, if this body had been free .- besides, dY \s the velocity which it would in reality receive in the same direction ; therefore pdt cosine R — (i V is the velocity lost by 7n in the direction of V, in virtue of the reciprocal action of the bodies : it is therefore this quantity that we must put for U cos. Z in the fundamental equation (E), which becomes by this substitution s mV p d t cosine. R ~ 3' m V dV = o', being the first of the two equations which we had to demonstrate. Secondly, pdt cosine r is the velocity which the vis mo- Irix p would liave impressed upon m in the directioDj of 7/, if this body had been free ; besides, V cosine y being the velocity of m in the direction of ^^, d (V cosine y) is the quantity which this velocity estimated in the same direction auiiments : therefore pdt cosine r -^ d (V cosine y) is the velocity lost by m in the direction of 2i, in virtue of the re- ciprocal action of the bodies : it is therefore this quantity which we must put for U cosine z in the second equation (F), which becomes by this substitution s mup d t cosine r — smu d {Si cosine y) = 0, which is the second of the twa equations we had to demonstrate. These equations are therefore nothing else than the fun- damental equations (E) and (F) applied to the case where the movement changes by insensible degrees, and therefore- thev contain all the laws of this .movement : we may re- mark also, that the first of th^se two equations is only a par- ticular case of the second, for the same reason that the equation (E), whence it is extracted, is contained in that (F) whence the second is extracted. Bui this first equation s mV p d t cosine \{ -- s mV dV = 0 deserves particular attention; because it contains the famous principle of the preseiration of active forces in a system of hard bodies the movement of which chanirei bv insensible degrees : thus ; Let On Machines in Genei'aL 319 Let us first call d s ilie element of the curve described by the corpuscle m during d t ; this being done, we shall have V d t — d s f and therefore the preceding equation assumes this form smpd s_ cosine R — 57?iVt?V = 0. Now let us suppose for a moment that the curve described by m is an inflexible line, ihat m is a. moveable grain interwoven with this curve, that it traverses it freely, i, e. without being pressed by the re-actions of the other parts of the system, that it experiences at each point of this curve the same vis motrix as that with which it was animated in the first case; and that, finally, in this first case the initial velocity of w is K, while in the second it will be null at the first instant, and V'' after an indeterminate time / ; this being done, by integrating the preceding equation, in order to have the state of the system at the end of the time /, we shall have for the first case s' s m p d s cosine R — 5' 5 m V c? V = 0, s' designating the sign of integration relative to the duration of the movement, while s is the sign of in- tegration relative to the figure of the system : no\v_, s' s m s mV^ . V fi V = • therefore the equation may be placed ia jt this form s' s m p d s cosine R — 5 ?» V* -f C = 0 ; C being a constant added to con)plete the integral : in order to determine it, we shall observe that at the first instant we have V = K and s' s m p d s cosine R = 0 ; therefore smYJ- C = — - — 5 therefore Is' s m p d s cosine R — 5 tw V* s mYi} = 0 : by the same reasons we have for the second case 2 s' s m p d s cosine R — 5 ?« V' * = 0, without a con- stant, because we suppose V' as null at the first instant: taking away therefore this eo\ro drachms) of castor oil ; then boil it for two hours, all the while carefully stirring the whole. The cloth is then taken out, and dried in the sun. At night it is soaked in a mixture of sheep's dung and water, next morn- ing washed, and then bleached all day. At night it is again put into the mixture of sheep's dung and water, and next day is again bleached. The operation is then finished by starching it with Jiavji. The black is a fixed colour, but the red is perishable. With the pa/W77^fi wood these Rungaru dye cotton cloth of a red colour, which is bright, but does not stand wash- ing. It is said that the people of Madras have the art of fixing it. The process used by tli£ Rungaru is as fgllows : Prepare the cloth by soaking each piece in a seer of water, containing six diuh/s weight of powdered myrolalajis. Then dip it into two or three seers (about two quarts) of a decoc- tion of patunga wood, in which have been dissolved two diidus weight of aUun. Then dry the cloth in the sun. The operation must be repeated four or five times, until the co- lour be deep enough. The decoction of paiunga is made as follows t Beat two seers (It^oVM^s*) of patu/iga wood, put it into a pot with 20 sccjs (about 5 gallons) of water, and boil for six hours. 'Jlie Niligaru are another class of dyers, of the same cast with the potmakers, and derive their name from their dyeing with the iiilaox indigo. The whole of this dye that is used here comes from the lower Carnati^:, or northern CIrcars. In order to make a vat, the Niligaru take ten seers (fi/uVo'^s.) of indigo, ground with a little water to a fine powder ; put it into a pot capable of containing 50 seer^k measure (or a little more than 12 ale gallons) ; and add a decoction of to gasliay lijay or seed of the cassia torn, which is made as follows: Take 4 seers measure (t^^oV Winchester gallon) of the seed, and boil it for 6 hours in four or five seers of water (about an ;ale gallon). The boiled seed, as well as the decoction^ must X3 be 326 On the Manufactures carried 07i at Bangalore, be put into the vat ; and then there must be added 10 secr^ (6yVirg-lb.) of powdered soiduj or impure soda, 12 setrs (7tVJ^0 of quicklime, and two seers of ihe ley of pot-ash (137 cubical inches). The whole is then stirred with a stick, and the mouth of the pot is covered up. Every even- ing and morning, for four days, three seers (206 cubical inches) more of the icy must be added ; and in the last por. tion must be put about the size of an apple of quicklime. The vat now rests for three days ; when four or five seers of boiling waier must be added to it, and the vat is then ready for dyeing. The ley of potash is prepared as follows : Burn to ashes the branches of the ctf//i {euphorhmm tirucalli), or of the titrayena {achyranthes muricata) : of these ashes put 2 seers (I iVo-o^^-^ ^^"^^^ ^ P°^ ^" ^^^ bottom of which there IS a small hole. The hole is covered with a small inverted cup, and that by some rice husks or chaff. Above these are put the ashes, and on them are poured by degrees 23 seers, or about 6 ale gallons of water, which filters through the hole in the bottom of the pf)t, and forms the ley. It must be observed, that the water used by the Niligaru is al- ways either that called here salt; 6r that which is found in places abounding with calcareous tttffa. The indigo vat having been prepared, an estimate is formed of the number of seers weight of cotton that it will dye. For every seer weight of cotton thread pass a seer measure of water through the pot containing the ashes, and in this weak ley dip the seer of cotton ; wash it well, and then wring out the water. The solution of indigo is then divided into five equal parts. The thread is dipped, by seers weight at a time, into these pots, till the colour in each is exhausted ; and what does not obtain a proper co- lour in the first, after being dried, receives repeated dips, until the colour arrives at the required intensity. The so- lution of indigo is kept for a month, and every night a little lime-water is added : this enables it to give some more co- Jour, which next day is again exhausted by dyeing some more cotton. The colour given by one dip is called mavi, and is a sky-blue ; that which is given by five dips in a strong pot, is of an intense colour, nearly approaching to ^ ^ blacky and the Processes used for Dyeing Silk aTid Cotton. 327 black, and is in fact called black by the natives, among whom it is in great esteem. From (he weavers the N Hi gam receive cotton, and silk thread dyed yellow with turmeric, and return it to them ol a green colour, which it obtains by a dip in a weak pot. At Bangalore, as well as in all the neighbouring country, goni is a considerable article oF manufacture. It is a coarse but very strong sack-cloth, from IS to £2 cubits in length, and from \ to I- of a cubit broad ; and is made from the janupa, ov crotalariajuncea. It is divided into three kinds, which differ in value according to their strength and to the closeness of the fabric. The same people, who are a par- ticular cast of i33en, cultivate the plant, ami carry on the manufacture, until the go7ii be fit for sale ; the price of the hemp cannot therefore be ascertained, as it is not sold in that state. The gojii-maker hires from some farmer as much high ground as he thinks will raise a quantity i\^ janiipa suf- ficient.to employ his family to manufacture in one year. The soil ought to be red or black, like the best kinds used for the cultivation of ragy. It is allowed no manure ; and the seed is sown broad-cast on th-e ground, without any previous cultivation, at the season when the rains become what the natives call male, that is to say, when they be- come heavy. After being sown, the field is ploughed twice, once lengthwise, and once across ; but receives no further cultivation- At other times the jafmpa is cultivated on rioe- ground in the dry season ; but it must then be watered from a canal, or reservoir. It requires four months to ripen, which is known by the seeds having come to full maturity. After being cut down, -it is spread out to the sun, andxlried. The seed is then beaten out by strikingthe pods with a stick. After this the stems arc tied upin largx? bundles, about ^wo fathoms in circumference, and are prese,rved in stacks^ . or under sheds. The bundles are taken out as wanted, and put in the water, at which time their bands are cut, and the stems being opened out are kept down to the bottom by stones or mud. According to circumstances, ihey re- <^uire to be kept in the water from six t() eight days. They ^r^ known to be ready, when the bark separates easily &oa> X4 . "the 328 On Ihe Alanufaciures carried on at Bangalore , the pith. It is then taken out of the water, and a man, taking it up hy handfuls, beats them on the ground, oc- casionally washes them until they be clean ; and at the same time picks out ivith his hand the remainder of the pith, un- til nothing except the bark be left. This is then dried, and, being taken up by handfuls, is beaten with a stick to sepa- rate and clean the fibres. The hemp is then completely ready, and is spun into thread on a spindle, both by the men and women. The men alone weave it, and perform this labour in the open air with a very rude loon). Leather is tanned here by a class of people esteemed of very low cast, and called Madigaru, - To dress the raw hides of sheep or goats, tlie Madigaru in the first place wash them clean, and then rub each with the fourth part of a kind of soft paste, made of 6 dudus weight of the milky juice of the yccada {asclepias gigantca), about () dudus \\c\^-\t (2-j-*^f-j/'g- ounces) of salt (nmiiate of soda), and twelve dudus weight of ragij savguty, or pudding of the cynosurus coracanus, with a sufficient quantity of water. This paste is rubbed on the hairy side, and the skins are then exposed for three days to the sun ; after which tl)ey are washed with water, beating them well on a stone, as is usual in this country. This takes off tlie hair. Then pow- der 2 seers (nVdV^t).) of arulay myrolalans^ and put them and one skin into a pot with 3 or 4 seers measure of hot water, where it is to remain for three days. 'Jlie skin is then to be washed and dried. This tanned skin is dyed black as follows : Take of old iron, and of the dross of iron forges, each a handful : of plantain and lime-skins, each fiv^e or six ; put them into a pot with some ragy kanjiy or decoction of ragy^ and let tiicm stand for eight days. Then rub the liquor on the skins, which immediately become black. These skins may be dyed red by the following process : Take of ungarbled lac 2 dudus weight (about 13 drachms), oi' suja caray or fine soda, 1 dudu weight, and o^ lodu bark 2 dudus weight. Having taken the slicks from the lac, and powdered the soda and bark, boil them all together in a seer of water (68|- cubical inches) for J -.^ hour. Rub the skin,. after and the Processes used in Dijewg Silk avd Cotton, 32^ after it has been freed from the hair as before mentioned, \vith this decoction ; and then put it into the pot with the tnyrohalans and water for three days. This is a good co- lour, and for many purposes the skins are well dressed. The hilJes of oxen and buffaloes are dressed as follows : For each skin take 2 seers (ItVoM^O ^^ quick -lime, and 5 or () seers measure (about J-j ale gallon) of water ; and iii this mixture keep the skins for eight days, and rub off the hair. Then for each skin take ten seers, by weight, (al>out 6 lb.) of the unpeeled sticks of the iayvgadu {cassia auriai- lata), and 10 seers measure of water (about 2^ ale gallons), and in this infusion keep the skins for ft>ur days. For an equal length of time, add the same quaniity of taijngaduand water. Then wash, and drv the skins in the sun, stietching them out with pegs. Thi^ leather is very bail. The oil-makers at Bangalore are a very considerable chss of people, and are of the kind that use two bullocks in their mill, of which a drawing is jriven (Plate VIII *). The mortar is a block of granite. This class of people are called Jotypha- 7iaday or Jotynagnrada Ganagaru. They express ihe follow- ing kinds of oil : wuli'-ellu, Jmts*-dluy haralu^ cohri^ ip^yx and hoiiigay. , The wjiW-ellu oil is expressed frou] two varieties or species o^ sesarnum seed, called here suruiianrt nuCi cari ellus. They are the same with the wnllay and phnlugana ellus of Scringapatam. The first gives the least oil; but for the table it is esteemed the best of any in the country : the price, however, of the two kinds is the same. T^.e mill re- ceives at one time about seventy seers measure (2-p\*g- Win- chester bushels) of sesamum seed ; and, in the course of grinding, ten Cuclia seers measure of water (S^oV ale quarts) are gradually added. The grinding continues for six hours, * A, A, (Fig. 1 and 2) the mortar, J feet G inches outside measure from rt to h. The inside cavity is L' feet wide. The heig-ht from the p^round to the top of the mortar is 6 feet 3 inches from the ground, and the block of which it is made descends into the earth G feet i) inches. The pestle B, B, IS 5 feet 1 inch in length. The cross hH.ndle of the pestie C, is 'S feet 7 incites long, by whicli, with the help of a cord, the pestle is attached to the post D, 4 feet 8 inches long, fastened into the beam E, F, which measures Jg feet Ifom £ to G, and 5 feet 5 inches from G Co F. •svhen 330 On the Manufactures carried on at Bangalore, &c, when the farinaceous parts of the seed, and the water, form a cake; and this having been removed, the oil is found clean and pure in the bottom of the mortar, from whence it is taken by a cup. Seventy Pucka seers (^y%\ Win- chester bushels) of surugafiaf or 65 seers of cari-ellu seed (^tVoV Winchester bushels), give 2 ,Cucha maunds (rather more than 54. ale gallons) of oil. The mill requires the-la- hour of two men and four oxen, and grinds twice a day, Thu oxen are fed entirely on straw, and are allowed none of the cake ; which is sometimes dressed with greens and fruits into curry, and at others given to milch cattle. The huts' 'cllu is managed exactly in the same manner as the sesamum. The seventy seers measure require a little more water than the other ellu, and give 65 seers of oil (or a little more than 4^ gallons). This also is used for the table. The cake is never used for curry, but is commonly given to milch cattle. The harulu, or castor oil, is made indifferently from either the lart^e or smiill varieties of the ricinus. It is the o common lamp oil of the country, and is also used in medi- cine. The oil made by boiling is only for family use; all that is made for sale is expressed in the mill. To form the cake, seventy seers of the seed require only five seers, Cucha measure (ItV^ ^^^ quarts), of water, and give 60 seers (4VoV ^^^ gallons) of oil ; which, after being tak^ii out of the mill, must be boiled for half an hour, and then strained through a cloih. The cake is used d,5 fuel. Coh'i oil is that made from the dried kernel of the coco- nut, which is called colri. This oil is chiefly used for anointing the hair and skin. Cakes are also fried in it, and it is sometimes used for the lamp. The mill receives 6 maunds weight of the cobri (almost 93 lb.), and 1 1 Cucha seers measure of water (a little more than 3 ale quarts). This produces three maimds (about 7-/o ^^^ gallons) 'of oil. The natives eat the cake dressed in various ways. The ipay oil, made from the fruit of the hassia longifolia, is used for the lamps burned before the gods, being esteemed of a better quality than that of the ricinus. The mill takes 70 seers Description of the Bermuda Islands , &c. 33t 70 seers measure, and the seed requires to be moistened with 12 Cucha seers (34- ale quarts) of tamarind water, in which 2 seers of tamarinds have been infused. The produce is 70 seers (4-^^^^^ij' ale gallons) of oil. The cake is used as 6oap to wash oil out of the hair of those who anoint them- selves. The lioingny oil, produced from the seed of the robinia mitis, is used for the lamp ; but it consumes very quickly. It is also used externally in many diseases. Take 70 seers, Pucca measure, of the seed freed from the pods, add 4 Cucha seers measure of water (ixVo- ale quart), and beat them in a mortar into a paste. Then tread the paste with the ieet; and, having kept it for two or three days, dry it in the sun. It is then put into the mill with one Cucha seer (19-jeg. cubi- cal inches) of water. It produces 40 seers (2f ale gallons) of oil. For fuel, the cake is mixed with cow-dung. The English weight, to which all the native weights are reduced^ is the pound avoirdupois. LXII. Descriplion of the Bermuda Islands, and particularly the Island of St, George. Addressed to the Directors of the French Museum of Natural History, by M,A. F. Mi- CHAUX, temporary Jgmit of the French Imperial Ad- ministration of IVoods and Forests in North America'^, X EMBARKED at Bourdcaux on the 5th of February, 1806, for the United States; my voyage having for its object to collect and transmit to the administration in the department of woods and forests, a great quantity of seeds and plant* of sucli forest trees as might be naturalized in Franco, or succeed in those uncultivated districts where our own indi- genous trees refuse to grow. On the 23d of March the American vessel, on board of which I was, fell in with the I.eander, an English man-of-war, commanded by captain Whitby, who, suspecting our cargo to belong to French jnerchants_, sent the ship to Halifax, in Nova Scotia. I * From Annalcs du J^lnsvum d'HisioiTe NaturelUi tome viit. p. 355. -was 632 Description of the Bermuda Islands, "Was the only one of all the passengers who was ordered on board the Lcander, where I remained for 43 days, during which time the cruize lasted. This disagreeable event re- uioved me more than 600 leagues from Charlestown ; but it gave me ait opportunity of visiting the Bermuda Islands, where the Leander anchored on the 7th of April, to take in water. We remained there eight days, and I obtained per- niission from captain Whitby (who always treated me with the utmost politeness) to go on shore frequently : upon these visits I made the observations I am about to com- municate*. The number of islands composing the Archipelago of the Bermudas is so considerable, that the inhabitants say they are equal to the days of the year. The largest are only from 12 to 13 miles long, The smallest look l,ike lime rocks just rising above the surface of the sea. The whole occupies an extent of about 35 miles in lent^th by 20 or 25 broad. To- wards the north himiense strata of rocks extend from 30 to 40 miles, rendering the approach of vessels dangerous. These islands, although much lower than tht^ Azores, present nearly th^ same appearance at a distance,, and re- semble long and high ridges of hillocks covered with a darkish verdure. They are not surrounded by ^ t^at and sandy beach like the Floridas, but skirted by high rocks, against which the waves are continually breaking. The island near which the English ships of war generally anchor is called St. George's, which is also the name of the chief town. The town of riamilton is in another island, ilfteen miles off; these two arc tht^ only towns in the Ber- ynudas. There are no bouses so close together in any other place as to entitle them even to the name of villai^es. St. George's island is situated at the north end of the Archipelago, and it was the only one on which I landed. It is of the second class in point of size, being nine miles long by three broad in sonie places, and only a quarter of a mile in others. The straights, which separate its southern shores from the islands of St. David, forni the harbour, and * M. Michaux was liumantly released at Halifax, by captair^ Whitby, ^nd prDccedcd to New York.— i'V*/jr/t Editor, its and paTtlculdrly the Island of St, George, 333 its entrance is strongly barricadoed by the projecting point of another island. It is edged round with blackish rocks, varying in height from 5 to 25 feet. When viewed at a distance, these rocks resemble a long hillock, the inequali- ties in which constitute so many small valleys. Upon the heights the soil is dry and sandy, and frequently ihe bare rock is seen : in the low grounds, on the contrary, the earth 15 a brown clay slighily moistened, and its vigorous vegcta* tion announces its extreme fertility. Three fourths of the island are covered Vvlth wood ; the rest is partly cultivated, or so barren that it is not suscepti* ble of cultivation. The plants peculiar to the island arc few in number : and although my journeys through the island were very rapid, I think I may safely affirm that the number of species does not exceed 140 or loO. Among these plants we find seve- ral bclonffincr to the antient continent, which do not sccni to have been of a nature to occasion them to be tran.-jplantcd here : these are, the verbascum thapsus, anagaUis arvensis, mcrairialis annua, leontodon taraxacum^ pUnitago major, urtica urcns^ gcntiana nana, oxalis acetosclla, Sec. We also find here the great cabbage palm tree, chamccrops pal- meto^ and the rhm toxicodendruvi of North America. As to other plants, I could only ascertain a small number of them ; but I collected seeds of all those which had been preserved the year before, among others a strawberry plant, the aromatic flowers of which resemble sage, and it is on this account called sage-bask by the inliabitants ; a beautiful species of veibcna, and a small medicago, each foot of which scarcely occupies an inch of ground ; this is ihe most com* nion plant in the country, forming almost the whole of the verdure every where; the surface of the ground not beintr, as in Europe and the United States, covered chieHy with the grasses, of which last there are very few kinds in the Ber- mudas. The juniperus Bermudiana, called by the inhabitants ce^ dar, is the only forest tree in these islands : the whole arc nearly covered vviih them ; and it is this tree which, when seen in clumps at a distance, gives a dull and sombre ap-^ pearance S34 Description of the Bermuda Islands, pearanco to the islands. It grows throughout the whole island, in every kind of exposure ; but in the valleys its ve- getation is more vigorous than upon the summit of the hills, and the primordial branches .attain to a great height, its elevation does not exceed 40 or 50 feet, and its diameter is from a foot to 15 inches. Although the branches have a tendency to expand from the trunk, those of the full-grown trees touch each other ; which may give an idea of the di- stance at which they are placed. Upon the heights, and in places which having been recently laid bare are replenished with young trees from the seeds of the old, one fourth of the young trees forms a thicket ; the branches shoot out very close to the earth, and extend eight or ten feet around the parent tree. These cedar trees are not felled at any regular season i they cut down a tree whenever they think it of a sufficient size for their purpose, leaving it to nature to till up the va- cancies made by these occasional removals ; and to this im- providence may in a great measure be ascribed the high price to which the wood of these trees has risen. It was the tlourishing season when I was at the Bermudas. The female trees were discernible at the distance of 15 or 20 paces by the darker colour of their foliage : the seeds are ripe about the end of October, but they fall during win- ter; so that I could find only a very few upon the trees. I am very anxious to see them cultivated, and have no doubt that this tree woidd be a valuable acquisition, either for the island of Corsica, or for some parts of our de- partments of the South near the Mediterranean. They make a syrup of these seeds, said to be extremely useful in cer- tain pulmonary complaints. Thtjimiperi/s Bermiidiana is very much esteemed, bn ac- count of the quality of its wood * ; it is fine grained, com- pact, and more resinous than the jjiniperus Virginiana. As in the former species the sap is only five or six lines thick in a tree of 1 2 or 14 inches diameter, this wood is employed * We may judge of its colour and smell from the black lead pencils called English crayons : the juniper tree of the Bermudas and that of Virginia are equally employed in their fabrication. in and particularly the Island of St, George, 335 in building sloops, which has been the principal branch of the industry of the Berraudians for a long period. These vessels are remarkable for their quick sailing, and last for a long time. It is said, however, that they are more liable to go to pieces than oak vessels when they strike. Six luggers, or cutters, from 120 to 140 tons, and copper- bottomed, have been built at the Bermudas by order of the English government. The cedar tree is the sole riches of the inhabitants ; and the fortune of every individual is estimated by the number of trees he possesses. They are sold on the ground at a gui- nea each. 1 was told there were no quadrupeds natural to the coun- try. The only birds I saw in the woods were, the cardinal, loxia cardinaliSy and the blue bird, motacilla sialis, which they say belongs to the continent of North America. Every year, in the months of March and April, the Ca- chalot whales approach very near the shores, where some of the inhabitants, but particularly the men of colour, fish for them. The shell-fish which are most common belong to the genera of turbo, donax, and mytilla. The latter are very abundant, and arc only 5 or (> lines long. Agriculture, which is now entirely neglected in the Ber- -mudas, once flourished there, as is proved by the records of the custom-house, which mention the quantity of sugar and wines annually exported from the colony. The present inhabitants employ the small number of negrf>es they possess in cultivating pot-herbs and maize, and in feeding poultry. They have very few cattle or horses, and I saw only about a dozen cows on the island, which were deriving a scanty maintenance from the medkago 1 have mentioned. In the country there are enclosures which might form a better sort of pasturage, but they are all planted with cedar trees. ^ Pro- visions of every kind are so rare, and so dear, thai the ships of war which are constantly arriving at ilie Bermudas can only procure potatoes and onions. There is but one kind of stone in the island, which i» found in great abundance a few feet below the surface. Upon S3G Description of the Bermuda Llands, ^c. Upon coming out oF the quarry it is very white, and so ten- der that it may be reduced to powder between the fingers; uhcn exposed to the air it becomes of a deep gray and in- durates. When seen through the microscope it appeared to me as composed of a very fine sand and of shells. Two t]uarrics are wrought near the town, in each of which eight or ten negroes or mulattoes are emplovcd, who earn from a piaster to a piaster and a half daily. Their labour is easy : the stones when detached from the mass are sawn into pieces> of about one or two feet broad by six or eight inches thick. Neither at St. George's island nor at any other of the Bermudas are there any springs or rivulets, and experience has shown that wells cannot be dug ; rain water, therefore, is alone made use of, which, from the precautions used, is not only sufficient for the inhabitants, but also for supply- ing the ships of war which put in there for the purpose. About 100 yards from the sea, there are constructed upon an inclined plane two immense terraces of a triangular form, destined to receive the rain water, which flows into cisterns, around which the empty casks are rolled, and lillcd by means of hand pumps. The walls of these terraces are of mason work ; and al- though each occupies a space of 450 or 500 fathoms, they are not always sufficient for the &up[)ly of the shipping. The distance of these government cisterns Irpm the town is about a mile. The road to them is eight or ten feet broad, and is shaded by cedar trees. vShips of v\'ar of the first and second rate cannot enter the harbour, but arc anchored one or two miles off. The town of St. George's has only 'ibO or 300 house?. It is intersected by a dozen of narrow street? not paved, and one of which only admits of a carriage to pass : the houses, which mostlv consist ot only one story above the ground, are generally coloured yellow. The wliolc are of stone, and covered with tiles, with a gutter round the roof to receive the rain water : this roof, which is painted white, reflects the ravs of the sun so strongly as to be very injunous to the eyesight. Several houses have small gardens^ the walls of which are On Colalt and NickeL 337 are eovered with the cactus opuntia. The most common pot-herbs, however, are alone cultivated in them. In some I have sten the carica papaya, the melia azedarachf the La- Tianier, and the geranium roseum and zonale. We meet with very few people in the streets, and the in- habiiants seem to be extremely indolent. There are only live or six shops in the town, where spices, trinkets, and cloths, are sold at a very high price. The Americans im- port into the place planks, maize, flour, butter, and some other provisions, for which they receive ready money. The money of the country is the heavy piaster. They estimate the population of the Bermudas at eight or nine thousand souls. I do not know the proportion of whites to negroes, but the latter are said to be more nume- rous. The lower classes are accused of misleading ships in stormy weather, in order to pillage those who have the mis- fortune to be thrown on their shores ; and the Bermudian pirates have always been proverbial for their barbarity. These islands are said to be very healthy ;. which cannot be doubted from their situation. LXIIf. Facts upon which to found a History of Col alt and NickeL J3y M.Proust. Extracted iy M.Chexilevil*^ 1 HE sulphuric, muriatic, and nitric acids oxidize metals in the same manner. There is a disengagement of hydrogen with the first two. Sulphates. — Of these there are two ; the one simple, an4 the other tripled by some neutral salt with a base of potash or ammonia. 1st. The simple sulphate has a slightly pungent taste, a little bitter, and somewhat metallic. Its crystals, not voluminous, are heaped up sections of irregular octae- drons : they are of a gooseberry red, unalterable in the air ; they lose 42 hundredth parts of water upon distillation ; •,From AnnaJes de Chimie, torn. Ix. p. 260. VoK 30, No. li^o. May 1808. Y they 338 Facts upon which to found a History they are then red coIaureJ and opaque. In this state they can support a red heat without being decomposed, except in those points at which they touch the retort. 2d. When we mix sulphate of potash with the fore- going-, we obtain more vohmiinous crystals, which are rhomboidal cubes. This triple salt is less soluble than the simple 5 it only loses 0:26 of water upon distillation. Carbonate, — The carbonate of potash gives from 0*40 to 0*42 of carbonate of cobalt with the simple sulphate. An excess of alkali dissolves a great part of the precipitate. Ebullition and cold water decompose this solution. Oxide at the minimjim. — 100 parts of carbonate leave,. after the separation of the water and carbonic acid, from 0*60 to 0*62 of greenish gr;iy oxide. In order to have it very pure, we must charge the retorts as full as possible, and heat them gradually. Without these precautions, we ob- tain an oxide mixed with oxide at the maximum, which, in this case, gives oxygenated gas with the muriatic acid, while that which is pure does not give an atom of it. The gray oxide is dissolved with effervescence in the nitric acid, without giving nitrous gas ; when heated in the open air. It 'becomes black immediately. We easily discover aa oxide, some parts of which are raised to the maximum by the application of a weak acid, which dissolves only the minor oxide. Ammonia operates the same separation as Thenaid remarked. Oxide by Precipitation, — 1st. Some drops of nitrate of cobalt, poured into boiling water with a little potash in it, give a blue precipitate, which at last becomes red if the ebullition be continued :. in this case a hydrate is formed ! 2d. If we employ alkali^Jed water cold, the blue precipi- tate is formed ; but in place of making a hydrate it passes to the green, without the contact of the air being able to obscure its shade : it preserves this colour after being dried» 3d. If v/e boil this green precipitate, while it is fresh, ia water with a little potash, it becomes a reddish gray, and does not change any more. The weak aci^s, vinegar for instance, dissolve the first ' i • precipitate cf Cobalt and Nickel, '^-'^ ^3§ precipitate totally : applied to the other two, they separate black oxide from them. Lastly, the blue oxide does not give any gas with the muriatic acid, while the green does. From this we mfcwt coi>clude, that the blue oxtd^id oxy- genated at the expense of tlie air contained in cold Hquids-, and that the grec'n oxide is a mixture of blue oxide and black oxide, M. Proust thinks nevertheless, that there is some- thing more than a simple niixture ; for the blue and black" colours would not give this shade of grass green, which, distinguishes it from every other oxide. Nothing but a true combination can yield a colour foreign to that of its components, and Kirtder the action of the air from elevating to the maximum the portion of blue oxide which forms part of the greeii precipitate. In order to oxidize thi^ precipitate completely, we must dry it by means of heat, as Thenard has shown. The reddish gray precipitate, in the third experiment, is a mixture of hydrate'and black oxide. It is only the minirmim oxide that can be combined with the acids : the green oxide is never obtained from any so- lution, and cannot become the base of any saline combina- tion. Ammonia and Oxide of Cobalt. — ^The gray oxide put into a well-closed flask, along with ammonia, communicates to it a slight red colour, which does not become higher, however long the flask is kept : this oxide is therefore but very difficultly soluble in ammonia. But if the flas-k remain uncorked the ammonia is very quickly coloured^ because it attracts carbonic acid from the air. We mar operate this solution in a very short time, by placing the flask in a large bason, in which we put a salt of carbonic acid. If we only saturate the Ammonia with acid, the solution is that of the oxide in the carbonate of ammonia. If we continue to make the carbonic acid pass, we obtain a solution oi carbonate of cobalt in the carbanate of ammonia* Thiy solution^ when kept in a flask full and corked, deposits cry- stals of metallic carbonate j it abandons a part of them by the addition of water : an excess of volatile alkali redissolves this precipitate. We may make this solution \tiry speedily, by throwing carbonate of cobalt into carbonate of ammonia. Y2 If $40 Fads upon which to found a History If wc pivt pure ammonia upon carbonate of cobak in ex- cess, this alters the ease eompletely. The carbonate of' co- balt is divided into two parts : the one yields its acid to the ammonia and becomes hydrate, which is precipitated to the bottom of the vessel, while the portion not decomposed is dissolved into alkaline carbonate. Here we have already two kinds of ammoniaca) solutions of cobalt. There is a third discovered by Tassaert, but in general very little remarked hitherto. We obtain it by put- ting hydrate well washed, or blue oxide, into a flask full of ammonia and well closed. The solution is made in 24 hours. It is red like the former; but differs from them in this respect, that if we pour a drop of it into boiling water, blue oxide is immediately precipitated ; when we operate with cold water we obtain green oxide. If ammonia dis- solves the hydrate of cobalt, or the fresh blue oxide, more easily than the gray oxide, it is because the two former are in very minute division. Distillation of the arnmoniacal Solution. — When we distil the solution of carbonated cobalt, carbonate of ammonia passes over ; the liquor in the end deposits an oxide at first of a dirty green, but which afterwards becomes black. This is a mixture of gray oxide and black oxide. How happens this byper*oxidation ? M. Proust merely states the fact, and abstains from explanation where data are wanting. Hydrate of Cobalt, — The crystals of sulphate, or of ni- trate, thrown into a flask full of liquid potash, and im- mediately closed, are there decomposed : a blue precipitate is formed, which passes to the violet, afterwards to the red_, by becoming hydrate. If we boil hydrate with potash, the latter dissolves oxide, and is tinged with a fine blue colour. This solution is de- composed upon the addition of water. In the air the oxide becomes black, and is deposited. The hydrate is dissolved cold in the cafbonate of potash, and tinges it red. The oxide is not dissolved. The hydrate of cobalt is of the colour of a dead rose leaf: Ihe acids dissolve it with heat, and without effervescence. The hydrate is not decomposed by ebullition, either in pure of Cobalt and Nickel. 34 1 pure water or in alkalized water. It loses from 20 to 21 of water by heat, and is reduced to very pure gray oxide. It keeps very badly under water : when it is in contact with the air it becomes black. The dry hydrate is better preserved, but attracts carbonic acid. When we throw crystals of sulphate into a flask full of ammonia and immediately closed, they give a blue preeipi- ^ tate, which d(K?s not become red a« in the potash. M. Proust asserts that the hydrate is formed, but that it is dissolved in some proportion in ammonia ; so that it is the hydrate which colours the solution, and not the simple oxide. Valuation of the Oxygen in the minor Oxide. — 100 parts of gray oxide, reduced with proper precautions in a closed crucible, give 63| of metallic grains. The quintal of cobalt seems therefore to absorb 19 of oxygen, in order to become minor oxide. Major oxide. — If we distil a nitric solution of cobaU, black crusts are deposited upon the sides of the retort, ni- trous gas is disengaged, and we obtain from 1 25 to 1 26 of black oxide as the residue. Hence we may conclude, thai the maximum of ihe oxidation of the cobalt exists about 25 or 26 in 100. This oxide is not dissolved in the nitric and sulphuric acids, except by losing the portion of oxygen which consti- tuted its maximum. It gives oxygen gas with the mtlriatic acid. it is inso-luble in ammonia and potash. The black oxide, heated for half an hour at the bottom Df a crucible, again becomes gray oxide by losing its oxvgen; we may then tinge the vitrescible matters blue. Messrs. Proust and Thalaker found the black oxide at Pavias, in a journey to Valentia. It is also found in cobalt ores, which have been called vltrecus or Hack ores. The carbonate and hydrate of cobalt is changed into black oxide, by the contact of the oxy-muriatic acid. The nitrous and sulphurous acids dissolve the black oxide, and form with it nitrate and sulphate at the minimum. Muriate of Cobalt. — The gray oxide is dissolved with heat in an acid of 15°. The warm or cold solution is of a deep Y 3 blue: 342 Fads 7ipG7i ivhkh to found a History blue; it crystallizes easily ; the crystals arc blue; it is the dc-hydratcd muriate. As soon as it absorbs huniidity it be- comes red. The muriatic acid at 15^ yields a great deal oF gas with black oxide. This solution is green while it retains the gas; but as soon as it has lost it, it becomes blue. The blue traits of the muriate of cobalt, dried upon paper, are nothing else than de-hydrated muriate. When they are green, it is because the salt still contains muriate of nickel, which tinges it yellow, and forms green with the blue. Its Distillation. — When brought to a red heat in a luted retort, those parts only which touch the glass are decom- posed : the products then are muriatic acid in vapour, mixed with oxygenated acid. The glass is tinged blue. The non- decomposed muriate is sublimed, after being melted in gray flaky flowers ; these undergo a kind of condensation, which renders them insoluble in water for at least 12 hours. Lat- terJy, they give a solution of common muriate. Arsenil-c and Arseniatc. — Thearsenite of cobalt is -prepafed bv pouring a solution of cobalt well diluted into a solution of arsenlte of potash. W^ obtain a red precipitate, which preserves this colour upon drying. Character of the Ars-cnite, — 1st. Heated in a tube closed at one end, it is decon^posed ; the oxide of arsenic is sub- limed, and the glass is tinged blue. 2d. The nitric aeid dissolves it, and there is nitrous gas. 3d. The nmriatic solution is decomposed bv sulphuretted hydrogen, which precipitates orpiment. 4th. Pure potash, with the assistance of heat, sets free the blueoxide. Arsenlate. — We obtain it by using arseniate of potash in place of arscnite. The precipitate is red, like the arsenitc. Characters. — 1st. Heated in the tul>e, it does not give any sublimate; it becomes violet, without tingeing theglass. 2d. The nitric acid dissolves it without nitrous gas. Sd. Its muriatic solution is not disturbed by the sulphu- retted hydrogen until two hours after the mixture. 4th. Pure potash sets inx tlie blue oxide, and is combined with the acid. The vf Cobalt and Nickel. 343 The red efflorescences which we find upon minerals con- taining cobalt arc formed of arseniate. IM. Proust found llie arsenite in the heart of some pieces only. Hydro svlphnret ted Oxide. Siilpkiiret oj Cobalt. — The gray oxide, the hydrate, and carbonate, take from water the sul- phuretted liydrogen, and become hydro-sulphuretted oxide* The latter is not dissolved in ammonia; it give? water and sul- phnrous acid upon distillation. The remainder is sulphiiret. The oxides when heated with sulphur become sulphuret. Cobalt absorbs 40 per cent, of sulphur. The authoj h^s still some doubts upon this subject. Facts respeciiug the History of Nickel, Nitrate, — 100 parts of metal dissolved in the nitric acid, and distilled until perfectly decomposed, leave from 123 to 126 of greenish gray oxide at the viinimum. The nitric acid cannot make this oxide pass to the muximum. In order to ascertain the purity of the oxide of nickel, we must dissolve it in the muriatic a<:id and heat it. If it contains a littJe oxide of cobalt, ther« will be an extrication of oxygenated muriatic gas : if it be pure, none will be dis- engaged. The gray oxide is dissolved in all the acids, and gives the same solutions as the metals. Nitrate at the min'minm. — By (tistilling the nitrate of nickel with the same precautions as the nitrate of copper, we obtain, as with the latter, a nitrate with excess of base, which is insoluble in water, 100 parts of nickel give 142 of this nitrate : on deducting the 25 parts of oxygen ab- sorbed by the aaetalj we have 1 7 parts of acid .fixed upon this oxide- 100 parts of iry nitrate of nickel gave upon distillation 5^0 of water, and 25 of oxide : therefore 53 of acid. These proportioniJ are not rigorously exact, because the last^ por-f: tions of water are a little acid. • Muriate of Nickel, — ^This is a gramilous crystallization of an apple green, and very deliquescent. The traces of this salt, when dried upon paper, are yellow. Y 4 This 341 Facts itpon which tofcund a History This muriate loses 55 of water. What remains is a yel- low de-hydratcd muriate, which again becomes green in the air, by aI)soibing water. The dc-hydrated muriate, when fire is applied to it, does not melt : those parts only which touch the glass are decom- posed : there is then an extrication of simple muriatic acid afid oxygenated acid : the salt not decomposed is sublimed under the form of pearl-like flowers of a golden yellow. These flowers in two days absorb Immidity, and become green. The muriatic acid dissolves them with difficulty. 100 parts of muriate of nickel gave, by means of carbo- nate of potash, from 61 to (52 of carbonate; which supposes from 33 to 31 of oxide. Sulphates of Nickel. — ^Th ere are two, the one simple and the other potashed. The first crystallizes in hexaedral prisms terminated by«an irregular pyramid ; the second in rhomr boidal prisms. The simple sulphate loses 46 parts out of the 100 of water. The de-hydrated residue again becomes green on absorbing humidity. When strongly heated for an hour, and at a red heat, in a luted retort, it is partly reduced to the state of sulphate with an excess of base : water takes away that part which has not lost its acid. 100 parts of ibis sulphate gave 6i of carbonate of a clear green. The potashed sulphate loses 24-lOOdths of water. The re- sidue acts like that of the sin]|)le sulphate. The potashed sulphate only gives from 27 to 28 of carbonate for 100. The two sulphates of nickel are transparent, of a fine eme- rald green ; they are unalterable in the air. M. Proust thinks that the sulphate of potash is united to that of the nickel in a constant proportion. Extraction of the Nickel on a large Scale, — Let there be an ample solution of ore first calcined, and afterwards vi- triolized with the residues of ether. It is requisite to sepa- rate the nicke) from iron, copper, arsenic, bismuth, and cobalt. The iron is at the 7naximum : in this state it has Uttle affinity for the acids. We may then precipitate it to the of Colalt and Nickel. 345 !he state oF arsenlate, by means of potash, which we must add gradually. Ammonia, or a prussiate^ afterwards proven if all the iron has been precipitated. Into the filtered solution we make a current of sulphuretted hydrogen to pass j the copper, hismutli, and the whole of the arsenic arc precipitated in the form of sulphurets. When the sulphuretted hydrogen occasions no more pre- cipitate, we reduce the liquor in order to crystallize it. The potashed sulphate of nickel, less soluble than the potashed sulphate of cobalt, is the first to crystallize. On repealing the crystallizations, we succeed in separating the two salts; as to the last portions of the salt of nickel, washing them in cold water takes off the sulphate of cobalt they contain. All these crystallizations require a bason of fine silver, if we wish to proceed smoothly. We ascertain that a salt of nickel is pure, when the preci- pitate dissolved in ammonia abandons this solvent with- out OUT finding any cobalt in it. When we jM-ceipitate a sulphate of nickel, we must not be too sparing of the potash : without this precaution we might run the risk of precipitating sulphate with excess of base ; which would alter the purity of the precipitate. Carlonale of Nickel. — 100 parts heated in a retort give from 54 to 65 of grccnislr gray oxide at the minimum. When we heat it in contact with the air, the oxide i^ .black. The minor oxide becomes carbona^te when exposed to the air. Hydrate of Nickel. — All the salts of nickel when thrown into boiling potash are changed into green hydrate ; boiling does not alter the shade of them. Potash neither dissolves the hydrate nor the oxide of nickel. The hydrate heated is reduced to gray oxide. The oxide is in the state of hydrate in the saline com- binations. The alkalis precipitate it in this state. Major Oxide of NickeL — The carbonate and hydrate rise jto the maTi'mum, when we put them in contact with the x)xygenated muriatic acid. Jt is itiore difficuU to oxidize the gray oxide. The 346 On Coledl and Kkkel. ; The dry major oxide of nickel is black ; when in a mass its fracture is vitreous. This oxide, preserved in ammonia, gives out bubbles, re- turns to the state of gray oxide, and is dissolved in the alkali. It gives a considerable quantity of oxygenated acid, with a muriatic acid at 15°. The solution is greenish yellow : crystals are formed upon cooling. The oxides of nickel are reduced like those of cobalt. They are melted in the same way, with this difference only, that the cobalt gives a larger globule. This metal hns taken a surcharge of sulphur from 46 to 100 ; but the author has still his doubts on this subject. Arsentie and Arseniate. — They are formed like those of cobalt, and are of a fine apple-green colour. The arsenite healed in the tube loses its colour with water, sets at liberty some white oxide, and passes to the olive-green. Charcoal is necessary in order to take away all the arsenic. When heated in a platina spoon, the arsenic is speedily dissipated. An oxide at the minimum remains. The arseniate heated in a gun-barrel loses its colour with water ; becoming of a hyacmth and transparent appearance: but at a red heat it passes to the clear yellow, and remains unalterable. In the spoon the arseniate becomes white, reddens with- out melting, or emitting the smallest arsenical fumes ; we must avoid flame in order to decompose it. Recapitulation. M. Proust concludes from the foregoing facts, and from those he has published in other memoirs, that cobalt, nickel, and most of the other known melals, have only two degrees of oxidation distinctly marked : he has not asserted, how- ever, that a metal can only absorb two proportions of oxygen : he only says that it is not yet time to admit all the oxides hitherto spoken of, and in which we have neither seen the quantity of oxygen ascertained, nor the combinations which they are susceptible of forming with the acids ; and he adds that colour is not a sufficient character by which to distin- guish them. 8 There The, mean Motions of the Sun and Moon, ^c. 347 There are only two metals which have as yet presented to the author more than two oxidations : these are tin and lead : notwithstanding this, the quantity of oxygen in the ox'idi: of t'm {ihchastoi' aurumimisivum) is not yet known, nor that oF the oxide in the nitrate of lead which has been boiled with plates of this metal. It seems that the different oxides of one and the same me- tal may be intermediately dissolved, and form true combina- tions. Thus the green oxide of cobalt is a combination of blue and black oxide. May not minium be a combination of brown oxide and of oxide at 9 in 100, and analogous to the foregoing? Finally; all the magnetic ores of iron and the attractable sands arc mixtures or combinations of this order : if this were not the case, what could prevent the minor oxide from rising to the maximum P The oxide of the gun-barrel which has served to decompose the water is also in the same case ; it is formed of the two oxides. LXIV. The mean Motions of the Sun and Moon, of the Sun's Perigee, the Moon's Perigee and A^ode ; the Times cfflieir several Revolutions, both in respect to the Equinox and to the fixed Stars, and in respect to each other: de- duced from the New Tables of the Sun and Moon lately published by the French Board of Longitude. By James Epps, Esq, To Mr. Tilloch. SIR, C *^HOULD you think the enclosed paper deserving a place ia your Magazine, it is at your service. It contains the result of very tedious though not difficult calculations; and, as it exhibits^ an interesting view of the modern solar and lunar astronomy, will, I think, prove acceptable to your astrono- mical readers. 1 am, sir, yours &c. James Epps.* No. 4, Commercial Road, May 14,1806. The 3 JS Tke mean ^lotions cj the Sun and Moon, The sun's mean motion in i a „• p -§ "I respect to the equmox, in j^ - io Q ^ co 100 years^ or 36524 days - 99 11 29 46 36*73 ,....,..,. in one year, or 365 days - - - — 11 29 45 40'368W The sun's mean diprnal motion - - - - — -^ — .59 8*3297763 The motion of the sun's perigee in respect to the equinox, in 100 years, or 36524 days - - I 43 11' , in one year, or 365 days - - 61-8693188 The diurnal motion of the perigee - - - -— — -^ — 0*16950498 Hence, the motion of the sun's mean anomaly, in 100 years, or 36524 days - 99 1 1 28 3 25*75 in one year - — 1 1 29 44 38*499 The diurnal motion of the sun's mean anomaly ^-^59 8*1602713 The moon's mean motion in respect to the equinox, in 100 years, or 36524 days 1336 9 24 42 8-2 , in one year, or 365 Jays - - - 13 4 9 23 4*8755 The moon's mean diurnal motion - - - 13 10 35*0270561748 The motion of the moon's perigee in respect to the equinox, in 100 years, or 36524 days - - - 11 3 iff 5fl 44*4 in one year, or 365 days - - - — j 10 39 45*79 The diurnal motion of the perigee - - - ^ 41*05695979 Plence, the motion of the moon's mean anomaly, in 100 years - - 1325 6 5 45 23*8 And of the Sun*s Perigee , &fc* 349 And the motion of the K » 5 moon s mean anomaly, m ^ c^ q i§ •f.i to one year, or 365 days - 13 2 28 43 19*085 The diurnal motion of the mean anomaly - - 133 53'9700fll638 The retrograde mean mo- tion of the moon's node, in respect to the equinox, in 100 years, or 36524 days - 5 4 14 8 31*4 in one year, or 365 days - - • 19 19 43*360557 The mean diurnal mo- tion of the node - 3 10*63934344 The mean diurnal motion of the moon from the sun 12 11 26*697280 The mean diurnal motion of the moon from hernode 13 13 45*666400 From the above mean motions are deduced the following revolutions : The sun's mean revolution in ^ i; ^ 4 5^ >^ s « respect to the equinox, called the ^ J ;^ b mean astronomical, solar, or tro- pical year - - - . 365 5 48 51*58732 The sun's mean revolution in respect to the fixed stars, or the mean sidereal year ; (supposing the mean annual precession 50'* 1) 365 6 9 11*49648 The sun's mean revolution in respect to the perigee, or the mean anomalistic year - - 365 6 13 58*074 The entire revolution of the sun's perigee, in respect to the equinox, is therefore 7645793 days, nearly, or 209 Gregorian centuries and about 33 years. Since the progressive mean motion of the perigee in one year, in respect to the fixed stars, is only U"*7693188, the sidereal revo- iutlon 350 The mean^ Motion of the Sun and Moon, &Co lution of the perigee will therefore be more than five times that of the tropical. The time required bv the sun <.• g "§ "I in passing over one degree or ,§ :5 § cc mean longitude - - - — 24 20 58*1433 The time required by the sun's perigee, in performing the same, is above 58 years, or more exactly 2123S 7 31 42*3205 The mean |>eriodical revolution of the moon in respect to the equinox 27 7 43 4-64670 • The mean sidereal revolution of the moon, or the revolution in re- spect to the fixed stars - - 27 7 43 ll'477IO The mean syiKxiic revolution, or the revolution of the moon to the sun, called a mean lunation Q9 19 44 2*850426 The mean anomalistic revolu- tion of the moon - - - 27 13 18 33-3391155 The mean revolution of the moon in respect to her node - 27 5 5 35*6053 The mean revolution of moon*s perigee in respect to the equinox 3231 11 4 6*69936 The sidereal revolution of the ., moon's perigee The mean revolution of the moon's node in respect to the equinox - - The sidereal revolution of the node - - - ~ ." Time of moon's describing 1"" mean motion - - - - Time required by moon*s pe- rigee in describing I'* motion by moon*s anomaly - by moon's node Mean motion of sun's anomaly during a synodic revolution, or one lunation, 29^- 6' 19"-96ll066, Mean 3232 13 36 41*26610 6798 4 H 14 51*1556 6793 2B 19'8rp3 — 1 49 17-17978 8 23 95 50-68531 — 1 50 13-0936 18 21 13 49*475 MiTieralogical Account of the Island of Corsica. 351 Mean motion of moon's ano- . .j | •« maly for the same intervaf, « j| § c§ 385^ 49' 0"- 8 186293. Mean motion of the moon from her node for the same interval, 390° 40' 13"-9587lCO. Periodof 12 mean lunations - 354 12 48 34*205X Period of 223 mean lunations, for the restitution of eclipses - 6585 7 42 35*6450 LXV. Mineralogieul Account of the Island of Corsica ; con^ tained in a Letter from M, Ram passe, formerly an Officer^ in the Cars lean Light Infantry^ to M. Fa u J as de St» Fond*. 1 SHALL novv endeavour to gratify your desire, commum- cated to me on my leaving Paris, of having some detaik of my mineralogical^ inquiries in Corsica, and particularly upon the orbicular granite of that island, of wbich a single isolated block only has yet been recognised. In order to make myself master of the subject, it was ne- cessary to visit the interior of the Pieve d*Orexza. and I first proceeded to reconnoitre the high mountain called Santo-Pie- tro-de-Rostino, from which proceed the enormous masses of quartz mixed with green diallage, with which the bed of the rivulet of the village of Stazzona is encumbered. I shall not at present enter upon a detail of the reasons which should incline us to reject the improper denomination of verdc antico di arezza, which was at first given to this stone. After this visit, I wished to direct my steps ta Liamoiie by the Vleve de Caccia ; but the extremely warm temperature which then reigned hindered me, and it was not until the end of August following that I undertook this journey. Before entering into the details of my excursion to Lia- mone, allow me to mention a new rock which I disco- vered in the Niolo : it is of a peculiar texture and composi- ♦ from Annalis du Museum tTHistoire XatureHe, tome vUi. p. 470. tion> 352 Mifieralogical. Account of the Island of Cor sled, tion, and I never met with it before. The following is the route I took to the place where I found this beautiful rock. By moving in the direction which I traced out to myself when leaving Basiioj I not only followed some chains of mountains from N.W. to S^and from E. to W. but I also tra- versed several valleys, and turned considerable gulfs which se- parate them in various directions. When I was in iho. Pieve (TOstriconiy where the chain commences which divides the island through its whole length to its southern extremity, I traversed the highest mountains which presented themselves to me, and among others that of Niolo, called in the language to the country Monte- Per tusato, because it is pierced at its summit. Its base seemed to be intersected by some de- tached masses, and others adhering to it, of jaspers and por- phyries of great variety. I followed the valley which leads to the place called Santa- Maria-la- Stella. Between these two points, south-east from the former and south from the latter, and at an equal distance from both, there is a high mountain covered with wood, upon the western brow of which I discovered a block of stone, almost square, about four feet and a half long. It was sunk into the ground, and exhibited globular bodies on one of its side?, remarkable from their disposition and colour, and fixed in the stony mass : some were about an inch in diameter, whW^ others •were larger or smaller : all of them presented^ a peculiar character which I had never seen in any stone. Not more than six inches of this rock was exhibited above ground; and in order to ascertain its dimensions I took away the earth which surrounded it. I then found that it was two feet and some inches in thickness. I also observed that its angles were entire and acute ; which made me think that it had never been removed sipce placed there, and particularly be- cause the part of the slope of the mountain where it was is bare ; and because, among the various blocks and masses which surround it, it is the only one which is covered with vegetable earth. I could only bring away a piece weighing about 24 pounds ; the rest was too large and heavy. When the specimen was detached and exposed to view, it seemed to me so beautiful and so extraordinary an appendage to Mlnerahgical Jccount of the Island of Corsica. 353 tx) the magnificent orbicular granite of Corsica, the celebrity of which is so well known. You may perhaps think I am exaggerating, but the fol- lowing is the accurate description of the stone taken upon the spot : The rock, the heart of which seems to be porphyroiclal, has its paste composed of stony elements of a petro- siliceous nature, irregularly disposed in small grains, in points and in lineaments more or less rounded off, tying as it were with each other, and varying in colour in proportion to the va- rious degrees of alteration the ferruginous principle, which is very abundant in this rock, has undergone : nevertheless its general aspect, when seen at a certain distance, is the reddish brown mixed with white spots shaded with red. It is in the midst of this paste that we observe regular spheroidal bodies, from one to three inches in diameter, scattered here and there at imequal distances, and imbedded in the mass : the system of ibe formation of these kinds of balls can only be considered as the result of a globulous cry- stallization, which must have taken place rapidly; and not like geodites, which would have been formed apart, and en- veloped subsequently in a porphyritical substance. The method of crystallization in question is so far remark- able, that we can form no idea of it except by representing a circle into which a multitude of small stony bodies, oblong and compressed, of a petro- siliceous nature, very close to each other, must have been directed in radii, and as it were from end to end, from the circumference towards the centre of the circle, which gives them the appearance of divergent radii; and there has resulted from it a globulous solid, which with the hammer we may drive out from the place it occupies, leaving a hole of its own form behind it. The tendency of the crystallization has been such, that we see around the spherical bodies in question, in the paste of the stone, and round the spheres, the matter of the paste itself, which, according to the tendency it had to approach it, has formed a kind of aureolus, or zones, which surround several of the bowls, which may be more easily remarked than de» Vol. 30. No. 120. May 1808. Z scribeds 3 54 Mineralogical Account of the Island of Corsica, scribed : indeed, no precise or just idea can be formed without seeing the stone itself. The dimensions of my specimen are as follows : It is 1 7 inches broad, 1 2 high, and seven inches thick at its base : the side which I have got cut and polished presents l.*! or 16 of these globules, among which we may remark several that are enchased as it were into each other. After spending a considerable time on the spot where I found this specimen, I proceeded towards Liamone on the gulf of Valinco. Having arrived at the village of Olmetto on this gulf, the place pointed out to me as containing the orbicular granite, I proceeded to Taravo. 1 dug np the makis covering a part of the hillock on which Stazzona is situated, and minutely examined every corner. I sounded the small lake in the neighbourhood : I visited the sea- shore : I also sounded the river, and explored it in various points by means of divers : I even followed its course upon the two banks for more than a league and a half: and finding nothing by these means, I formed the resolution of exploring 45 miles of ground beyond Stazzona. I endeavoured to assure myself of the composition of the eranites Iving upon the heights surrounding the great valley of Taravo : T attacked every rock I saw, and found some specimens the composition of which resembled the granite in question. After having pursued my researches still further, I entered the bed of the Taravo, and traversed the two banks for more than tvvo leagues : at the moment when I was re- doubling my efforts to finish my investigation, I was obliged to desist on account of the rain and snow, it being now December. I collected the various specimens of rocks which I pro- cored at Valinco : and after having made a comparative ex- amination of them w ith the orbicular granite, I ascertained that in some of these specimens there were hornblend and feldspar, but not in the same order, nor in the same arrange- ment: nevertheless, I think we may inicr from these spcci- mens:, Mineralogical Account of the Island of Ctyrsica, 355 mens, that by finibhing the object of the visit I paid to the two banks of the torrent, we shall perhaps succeed in dis- covering the primordial masses of the beautiful orbicular granite of which a small partial mass only has been hitherto dicovered : ih^ angles of it were rounded, and it was found isolated upon the beach of Taravo, half a league from the sea, in the gulf of Valinco. "From the information I procured on this occasion, I think I proved to a certainty that the small mass of this gra- nite, already known, comes from no place except Corsica ; for you know that several naturalists have formed various conjectures upon the subject. In the course of this tedious journey, I had also an op- portunity of discovering an ore of iron, the stratum of which is half a league in length. After having passed "the river Oposata, in order to arrive at Calvy, in a plain above the village of Calenzana, to the eastward of Galeria, I found a stratum of iron ore, placed horizontally in a yellow earth, which at times disappears throughout the whole length of the ore, and the mineral of which is presented in three diflerent views. At first it ap- pears under the character of scaly iron, arranged in thin layers, mixed with a yellowish ochrey earth ; afterwards it appears as a heavy blackish iron, compact, and almost en- tirely disengaged from every heterogeneous substance ; and under a third aspect, in elongated spheroids from four to five inches in diameter, exfoliating at its surface, and com- pressed at the two sides : this gives it angles at intervals ; and the sandy character and composition of it made me deno- minate it arenaceous iron : and I procured the necessary specimens for the experiments I intended to try upon it. Having ascertained from these trials that this ore Was very productive, I transmitted to the council of mines several specimens of the above stratum, begging them to publish the result of their assays. Z 2 LXVI. On [ 356 ] LXVr. On the Identity of Silex and Oxygen, By Mr, Hume, of Long' Acre ^ London, A [Continued from p. 280.] To Mr, Tilloch, SIR, MONG these promiscuous observations, it would be un- pardonable to omit iron, which is one of the more constant associates of silex. These two ingredients seem to be al- most inseparable companions, especially in every thing of a primeval nature ; for, in all original districts, mountains, rocks, and soils, and in every native compound of any con- sequence and extent, whatever the aspect, situation and contents may be, these two elementary bodies are sure to present themselves, and, T may add, are always united ; for, though the silex maybe elicited from the mineral in its simple form, the metal, on the contrary, is always oxidized. So universally is this metal dispersed through the works of nature, that very few instances occur in which it is to- tally absent ; its ubiquity is truly proverbial, and is exceeded by nothing, if we except silex or oxygen ; indeed it pervades almost every solid substance, and even animal and vegetable bodies are seldom exempt from its influence, but often exhibit iron evidently as a constituent in their s^j'stem. Hence, the history of iron becomes a most interesting subject to the physiologist, and, if we add its wonderful property of mag- netism, it seems to be one of the most fertile for the ima- gination of every philosopher. As this metal is never dis- covered in the pure state, but is more frequently conjoined with oxygen than any other body; and as this process seems to have been effected in the immediate vicinity of silex, I see no particular or unreasonable objection, if, in all such instances, we assign the genuine cause of the oxidizement of iron, solely to this prototype of oxygen. I feel less diffi- culty in admitting this conclusion, when it is consi- dered, that the more cogept examples are dcducible from originally Jormed matter, from the real primordial rock, coeval \vith the globe itself, and made tangible, probably, soon On the Identity of Silex and Oxygen, 357 soon after, or even at that very period when, the ^^ Earth was without form and void.** The inlimacy between silex and iron, and the consecutive oxidizement of the latter, need not be further urged ; it oc- curs in such numberless cases, that whoever is at ail conver- sant in mineralogy, and will take the trouble to search with candour, can be at no loss for evidence, sufficient to establish this singular concomitance. Thus, let us take, as an instance, that substance, familiarly known by the name of emery. Here, the iron is truly united to the silex in a very close man- ner, and not as a mere mixture, for the metal is oxidized and imbedded in this surplus of oxygen. "This,** says M.Haiiy, speaking of emery, " is a true combination of quartz and iron, in which the two substances contract a stronger ad- herence than a mere interposition of their molecules.*' Though iron is considered ^s a pure metal and a simple substance, that is, when divested, by the usual methods, of the common impurities, to which it has a habitual affinity, particularly of these, viz. carbon, phosphorus, and silex; still, there is strong reason to believe that it has never been totally exempt from one or other of these substances. Indeed, it ap- pears that some of these very impurities are required to render the metal more perfect, to add to its splendour, ductility, and other properties, which the arts demand. Thus, to make good steel there must be an addition of carbon as well as silex ; and, if brilliancy, hardness, and a susceptibility of higher polish are to be considered as improvements, the carbon and the silex, in this case, seem to render the metal still more metallic, if such a term may be allowed. In an analysis of four different specimens of steel, by M. Vauquelin, the result was this, taking it on an average to avoid fractions : that one hundred thousand parts of these samples of metal consist of 9817 of iron, 723 of carbon, 870 of phosphorus, and rather more than 288 of silex. That it is very difficult to deprive iron of all foreign matters, may be readily conjectured from this philosopher's labours, and the following observation confirms this truth, that iron is never pure. " The analysis of the varieties of steel,** says this very accurate chemist, *^ is one of those parts of the. Z 3 science 35 S On the Identity of Silex and Oxygen, science the least advanced and the most difficult, especially when our object of research is the exact estimation of the principles which they contain : — it is thus, for example, that, in dissolving steel in dilute sulphuric acid, the hydrogen which is evolved, dissolves and carries off a part of the carbon, the quantity of which varies according to a multi- tude of circumstances." From this and other authorities, and from a prejudice, which, I acknowledge, 1 have long been disposed to che- rish, it may be inferred, that whatever emits smell cannot be considered as a simple body, and hence, the purity of hydrogen as an clement must be doubted ; that species, however, which we obtain from the decomposition of water by the metals, is certainly very objectionable, if there be any truth in this observation ; for the gas is never free from a ver^ perceptible odour, whether it has been procured by means of zinc or iron. It is certainly not always prudent to generalize too freely upon these subjects, yet it is difficult on some occasions to avoid it entirely. The hydrogen gas, alluded to by M. Vau- quelin, in these analyses, was undoubtedly impure, as it contained a certain portion of carbon from the metal, though not the whole ; for, finding this mode of operating inconclusive, he at last had recourse to the sulphurous acid, with which he apparently succeeded in separating the whole. Fluoric acid, from its peculiar effects upon the siliceous compounds, deserves a particular notice in the present in- quiry, especially as its whole history remains still clouded with inconsistency and ambiguity] for, either the tables of affinity respecting its habitudes are erroneous, or the acid itself must be considered as a monstrous anomaly in the doctrine of chemical attractions. These tables begin with lime, and go on progressively with some of the earths and alkalies to silex, the very last in the enumeration, with which, by the way, it has never yet been united so as to produce a true salt. From Bergman's experiment, we learn, that he dissolved silex in fluoric acid, and that after the so- lution had remained undisturbed for two years, a number of crystals had formed at the bottom of the liquor in the • • vessel. On the Identity of S ilex and Oxygen. 359 vessel. But, what were these crystals? They were pure silex, aod had deserted this very acid, which, in all other cases, would have seized on it and dragged it into even aeriform existence. The native fluate of lime is so very generally con- taminated with silex, if this expression may be allowed, that it is probable no fluoric acid exists without some of this ingredient; it may indeed owe its origin to this body, so uniformly are they associated. But, that singular influence of fluoric ^cid upon silex, the corrosion of glass, is what has been chiefly noticed by most authors, for it does not appear that a direct application to the mere silex has yet been attempted, at least, with thai precision which might have obtained a satisfactory result. T-hat this acid should prefer the silex to the alkali, and in a case of single elective attraction too, is contrary to every table that has yet been published, and hence, in this ex- ample at least, it forms an exception to the general rule. But if, in similar experiments, the acid selects the silex from lime, a substance which is placed at the top of the list, in all arrangements, how much further does this error extend? Though in making experiments with this very curious li- quid I have employed various species of glass, ^principally with a view to improve this method of etching, I have generally preferred plate- glass, on account of its form, con- venience, and greater capability to endure the necessary pressure, so as to secure a number of perfect impressions. This glass is always, without exception, composed of lime, silex, alkali, and, occasionally, some other ingredients of less consequence in the present question. It is astonishing, that in all the accounts of the decom- position of glass by fluoric acid, and even by other means of still greater energy, by electricity, little notice has been taken of the oxide of lead, and the subseqient disposition of the whole of the ingredients. I make no doubt, that flint-glass has been more frequently employed than any other, but I do not find that silex has ever put on that pe- culiar character of an earth, an alkali, or a salifiable base, ajid attached itself to the negative pole. On this subject, I confess, I feel extremely solicitous, as, in the late very Z 4 splendid 300 On the Idejitity of Silex and Oxygen^ splendid discoveries, which now, and probably will ever continue to, engross the attention of the scientific world, the decomposition of glass and consequent disposal of all its ingredients, form a question, to nie al least, of the ut'* most interest; since, as far as I can judge of the pheno* mena, which have already been described, there appear cir* cumsiances more likely to confirm, than invalidate, my opinion of the nature of silex. There is a remarkable similitude in the effects of oxygen and silex on the metals, particularly in that process called vitrifcatio??, which is, in every meaning of the word, a coniplete saturation. By means, of these, particularly the silex, all the metals, perhaps, with no exception, from being the most opaque bodies in the universe, may be ren<» dered quite pellucid, affording an endless variety of the most charming tints, as useful as they arc elegant, smce it is chief- ly from metals and metallic. substances that the most durable and valuable colours arc obtained for staining glass and mak- ing artificial gems. The best op.ike colours, such as are most suitable for enamel, water, oil, crayon, and all other descrip- tions of painting, are derived also from the metals, combined with one or both of these substances ; and though alumine and other bodies are occasionally present, they are as ofter^ absent. Even the precious stones and the less valuable peb- bles, spars, and an infinite list of fossil productions, seem to derive their intrinsic value, beauty and other excellen- cies, entirely from the power of silex on the metals. Thus, the dull opacity of lead is as effectually changed by the sand, used in the composition of flint-glass, and the whole com- pound appears not less diaphanous, than the very same metal is, when, by means oi oxygen ^ it is dissolved in nitric acid, properly diluted with water ; such, however, is the infe- rence I would draw from these premises. The near connection between potash and silex, is not less manifest than in the other associations which have been already noticed ; indeed, seeing with what avidity the base of potash (according to the late discoveries) clings to oxy- gen, I am furnished with this plea, that its original and necessary quantity had been obtained from silex ; for all the potash On the Tdenlity of Silex and Oxygen. 3^1 potash ^of commerce contains silex, and retains it with some di'gree oF force, not as an adventitious ingredient, but ra- ther as the superabundance oi' that primitive store, from whence it had derived that portion which is essential to its existence as potash. Now, that the constitution of potash no longer remains in doubt, and that oxygen has been proved to be as essential to the formation of potash as it is to that of sulphuric acid, I see no explanation more congenial and satis-,- factory than what I have here ventured to suggest, especially uhcn it is proved that the primitive seat of potash is in rocks ^nd stoneSy and in the very centre of such bodies, where the ^itmosphere can have had no influence ; for, as far as regards its vegetable and animal existence, all is merely secondary, and, consequently, does nut apply so forcibly in this theory, though, even here also, we need be at no loss for proofs. The power which silex exercises over potash, soda, and. ^ variety of other substances which enter into the compo- sition of glass, is a notorious instance of its neutralizing efficacy ; for no acid more completely obtunds the acrimgny of alkaline bodies and disarms them of their corrosive clija- racter. The effervescence, which resvills when silex and the alkali enter into fusion, and form this insipid compound, is not observable till the materials are on the point of per- fect conibinalion : hence, as son)ething is apparently evolved, neither oxvgen nor any other aeriform fluid can be supposed to enter ; so that the acidity, if the term may be applied, to coerce the alkaline matter, is alone due to the sand which is usually employed in the making of this beautiful and use- ful compound. Indeed, vitrification, in all instances, seems to be accon)plished by silex or by oxygen ; and the glass of lead, of antimony, of phosphorus, borax, or of any other body, is due to one, as much as the glass in common use, is to the other of these oxygenating agents. In many very trite and familiar experiments, upon bodies containing either silex, an acid, or oxygen in some con- dition or other, tfee phenomena which succeed may be traced to the same cause. Thus, scintillation of hard bodies on collision again'st each other, as flint against seel ; that of two siliceous stones, which emit not only light but the pe- culiar 362 On the Identity of Silex and Oxygen. culiar quartzy or rather sulphurous smell, already noticed ; the effects produced by various species of phosphor! ; fric- tion of two pieces of borax ; the electric nature of glass ; that of amber, tourmaline, and of resinous bodies ; the light evolved by friction and collision of bonnet-cane and other vegetables which contain silex ; and, in short, all other • analogous examples may be adduced as additional illustra- " lions on this subject. If I were to select a case, in which silex seems to be de- posited as it were, and deprived of the caloric which had suspended it in the state of gaseous oxygen, it would be ^ that of a natural hot-spring, such as the Bath-waters, which • are confessedly impregnated with sand or silex, not merely • in suspension as an accidental material, but perfectly dis--' solved so as to be imperceptible to our sight. Besides these ^ waters, all other hot springs contain silex In solution ; that of Carlsbad; the Geyser, and Rykum, in Iceland; and many others, which, it is said, issue, for the most part, from granitic and other siliceous rocks. If these waters were cold the argument might fail, but while the temperature of the ambient medium can be taken into the account, I should not be willing to retract this opinion, as far as it concerns the nature of all hot-springs. It is f;tated from good autho- rity, that in the kingdom of Portugal alone, there are up- wards of 200 of these springs, the greater number of which, and the hottest, originate where silex is most abundant. The presence of nitrogen in the Bath- waters, and, pro- bably, in all other hot-springs, is a curious occurrence, and furnishes a proper theme for speculation. Whether it be the remainder of decomposed atmospheric air, which has been bereft of its oxygen, and that this is disposed of in the water, in the way I have supposed, is a question I shall not urge. The late Doctor Black analysed the hot-' springs of Iceland, but the analysis, I believe, was not performed upon the spot, and, consequently, no notice could be taken of nitrogen gas. In the gallon of Geyser water, he found upwards of 31 grains of silex ; and in the other, that of the Kykura spring, the proportion was 29 grains of the same ingredient in the English gallon. The Dissection of a Case of Hydrocephalus intermis, 363 The effect of silex in various cases is the same as an acid, and in some situations, where an acid or acid properties really exist, no other cause is present. All acids we know are not sour, some on the contrary, are insipid, and, there- forcy it would he too much to expect silex to possess this property. It is, however, a strong support to this question to see my idea of its general acid quality corroborateilr by others, for it has lately been observed, (Journal des Mines, tome XX. p. 245.) that " in the analysis of ores, silex acts very sensiidy as an acid.'* [To be continued.] LXVII. Report of Surgical Cases in the City and Finshury Dispensaries, for November 1807; containing a Dissec- tion of' a Case of Hydrocephalus internus. By John Taunton, Esq, In the month of November there were admitted on the books of the City and Finshury Dispensaries 237 surgical patients. Cured or relieved — 229 Died — — 3 Under cure — 25 257 Since which time there have been admitted 1007. - Some time since I was requested to examine by dissec-^ tion, the head of J. W. aetat. about 9 years. It was remarked at the birth of this child, by a very intelligent surgeon, that the head was large, and that it was probable there was water contained in the brain. The child grew, and enjoyed good health till the 1 7th month after birth ; but the head continued large. He was then seized with the hooping-cough, which was very violent, and he lost his sight for some time. It was now pronounced decidedly, to be a case of hydrocephalus internus. On his recovering from the hooping-cough he regained his sight and strength, so as to enable him to walk with tlie hand of his nurse, or in a^ go-cart : his appetite was goody and 364 Dissection of a Case of Hydrocephalus intemus. and his evacuations regular : but his head increased in size beyond the proportion it ought to have borne to the other parts of the body. He was naturally of a lively turn, and reasoned with great acuteness for his years, — observing, that it would be very difficult to regain his present lime, which -was lost, in point of education. About two years before his death he wore a quicksilver girdle, and took some very stimulating snufF, from which he appeared to be relieved for some time. About six months preceding death, he fell, and struck the back part of his head; from which he complained of great pain, which brought on violent vomiting, fits, and sometimes a loss of all sensation; as in a kind of lethargv. About ten weeks before death, a blister was applied be- tween the shoulders, from which he appeared to receive consicjerable relief; the head was shaved, and some stimulat- ing oils rubbed in, as ol. origan, 8cc. : after one of these rubbings he lost his speech entirely, and remained insensible till his death. The child was of a spare habit of body ; but independent of the head, which was greatly enlarged, had a healthy appear- ance, and was moderately tall. The bones of the scull were unusually thin, to which the dura mater did not adhere with the common degree of firmness; the vessels were turgid ; otherwise the membrane and its sinuses were natural. On raising the dura niater, the brain presented an uni- form smooth surface, without the least convoluted appear- ance; the tunica arachnoidea and pia mater were healthy,, the vessels lying upon the surface of the latter membrane. The cerebrum was flaccid, and the undulation of the water could be distinctly perceived : on removing the upper part of the right hemisphere, although the incision was made more than two inches above the corpus callosum, it ppened ihq lateral ventricle: tne two lamiuje forming the septum luci- dum were separated from each other more than half an inch. The lateral ventricles were greatly enlarged, and contained thirty-two ounces of a siraw-colourcd fluid; but theve w^s not Notices respecting New Books, 365 not any appearance of inflammation on the membranes lining these cavities. On exposing the cerebellmn, the right lobe appeared somewhat flaccid, in which a cist was placed containing eight ounces of a brown straw-coloured fluid, not having any communication with the fourth ventricle or other outlet. The optic nerves were small, soft, and of a brown colour. The other parts of the brain and nerves were natural. We perceive that the reasoning faculty was more complete than could have been expected. From such extensive de- rangement of parts, is it not probable that the early and slow- formation of the fluid, and consequent distension of the lateral ventricles before the bones of the scull were com* pletely ossified. Or capable of affording that resistance which they are in the adult state, prevented in a great degree the effects of pressure, by allowing the bones to enlarge from the gradual pressure from within daring their more membra- nous state ? as we see a comparatively trifling pressure on the brain in the adult, when the bones are iucapable of exten- sion, whether it be in consequence of external violence or of inflammation, by which a fluid is effused into the lateral ventricles, productive in a short time of the most serious consequences. We also perceive that nearly one half of the substance of the cereLelhim was destroyed, by its place being occupied by a cist which contained eight ounces of a fluid; and yet the ca- pability of associating ideas remained, which was also observed in the case of miss M. See Phil. Mag. vol. xxix. page 169. Greville street, Hatton Garden, JOHN TaUNTON". Mav 24, 1808. LXVIII. Notices respecting Netv Books, i\j.R. Parkes has for some time been engaged in revising and correcting the Chemical Catechism, in order toaccom- tnodate every part of that work to the new discoveries of Davy and others. A new edition thus amended, and with other very considerable additions, is in the press, and will be-ipfiady for delivery some time in June. Mr, 366 Royal Society, Mr. Carnuchael proposes to publish in the course of the ensuing summer, the second edition of his Essay upon the ^Effects of the Salts of Iron upon Cancer, with many addi- tional cases, and several interesting practical observations upon that disease. ' Mr. Carmichael has received some communications from practitioners, concerning their experience of those prepara- tions, for which he begs to return his warmest thanks; and he at the same time takes this opportunity of earnestly re- questing such of the profession as have deemed the remedy he recommended worthy of a trial, to inform him (addressed to No. 3, Gardener's Place, Dublin,) of their experience of its effects, before the end of June next, in order that he may insert their observations in his Essay, and that thus the merits of the remedy may be justly appreciated. LXIX. Froceedings of Learned Societies, ROYAL 50CIETV. April 28. — This society met after the Easter recess, the president in the chair. A mathematical paper, by Doctor Young, was read, on the motion of fluids in flexible tubes, and the resistance of angular tubes to such fluids. A num- ber of hydraulic experiments were performed ; but the re- sult was not of a nature to be stated here. This paper was merely designed as prefatory and introductory to this author's next Croonian lecture on muscular motion. May 5. — A letter from Mr. Cadell, at Paris, to H. Davy, Esq., secretary of the Royal Society, was read. In this letter Mr. Cadell states, that the French chemists have success- fully repeated Mr. Davy's experiments upon the decompo- sition of the fixed alkalies ; and that they have found a re- markable confirmation of his discovery in the action of heated iron upon potash and soda. This chemical result has been obtained by Messrs. Gay Lussac and Thenard. These gentlemen introduced potash into the\)ottom of a gun-barrel bent in the form of an S : iron filings filled the middle of it, which was strongly heated. By Royal Society, 3G7 By the action of the potash upon the healed, iron, it is de- composed, and the metallic base partly distils over, and is partly found in a state of alloy with the iron. — ^The same letter states, that Mr. Berthollet jun. has read a paper to the Institute, in which he endeavours to confirm his father's analysis of ammonia. May 12 and 19. — ^The president in the chair. These two evenings were occupied in reading an interesting and able paper containing the results of an analysis of numerous spe- cimens of different calculi, by Mr. Brande. The object of the inquiry was to ascertain the relative quantities of uric acid, and phosphats of magwesia and lime ; and to determine the effects of the usual solvents, alkali and acids, for calculi in the bladder and kidneys. It appeared that out of 150 stones, 60 were found composed of phosphoric acid and ani- mal matter, and that only 12 were found of pure uric acid ; the phosphats of magnesia and of lime, with a slight por- tion of uric acid and animal matter, were the most common. Some of the stones had pieces of bougies, hazel-nuts, and peas for nuclei. To Mr. Brande's experiments Mr. Home added some practical observations, tending to prove that, if alkaline solvents were used, they might dissolve the uric acid ; but that ihe phosphoric, which is always the most plentiful, would thereby be increased, and the virulence of the disease, however mitigated for the moment, would eventually become much more dangerous. The same ad- verse effects were ascribed to the use of acids as solvents : so that we have yet to discover a safe and efficient remedy for calculous diseases. May 26. — The president in the chair. The reading of a paper, by Messrs. Allen and Pepys, on the effects of respira. tion on the atmosphe're commenced. The authors took a ge- neral view of what the principal philosophers have written on this subject, as an introduction to their observations ; and expressed a hope of ascertaining with more accuracy than preceding experimenters, by means of their eudiometer, the quantity of oxygen consumed, and carbonic gas emittcd,^ by the lungs in ^ given period. UNIVERSITY 368 University of Ed'mlurgh. — JVernerian Society, UNIVERSITY OF EDINBURGH. We congratulate the lovers of science, as well as the pub- lic in general, on the Sj>lendid acquisition which this Uni- versity has just now made by the magnificent collection of minerals bequeathed by the late Dr. Thomson of Naples. This celebrated mineralogist, during a long residence in a country extremely fertile in the most interesting products of the mineral kingdom, has lost no opportunity of forming a most splendid collection, which, having lortunately escaped every danger, has arrived in Edinburgh untouched. Go vernment not only indulgently remitted the duties> but allowed the whole to pass unsearched. The liberal endowment (with which Dr. Thomson has ac- companied this l^equest) of 1500'., the interest of which he has destined for the payment of a lecturer on mineralogy, and the support of the cabinet, we hope, will be the means of handing it do-wn to posterity in its present high state of preservation. — It is contained in forty very large boxes, •which are deposited in the museum of the University ; and, we understand, proper cases are making for the reception of the specimens. The interesting and valuable collection of the late inge- nious Dr. Hutton, of this place, has also been deposited in the museum. WERNERIAN NATURAL HISTORY SOCIETY. At the last meeting of the Wernerian Natural History Society (14th May), Mr. P. Walker read an account of the Birds that frequent the neighbourhood of Edinburgh. He enumerated 178 species; of which 11 belonged to the. genus Faleo ; 4 to the genus Strix; 1 to Lanius ; 8 to Corvus ; 1 toOriolus; 1 to Cuculus ; 1 Picus ; 1 Alcedo; J Upupa ; I Certhia ; 2Sturnus; 6 Turdtis; 1 Ampelis ; 2 Loxia ; CEmberhiza; 8 Fringilla ; 1 Muscicapa; 3 Alauda; 15Mo- tacilla ; 4 Parus ; 4 Hirundo ; 1 Caprimulgus; sCoIumba; 1 Phasianus; 6 Tetrao; 3 Ardea; 6 Scolopax ; 7 Tringa ; 4 Charadrius ; I Hasmatopus ; 3 Rallus ; 3 Fulica; 4 Po- ^iiQcps ; 4Alca; 6 Colymbus : 2 Sterna 5 12 Lai us: 1 Pro- 3 cellaria; JVer^erian Natural History Society, 369 cdkria ; 5 Merganser; 20 Anas; 4 Pelecanus. This account Was accompanied wiih interesting observations on the di- stinctions of several of the species, their changes of plumage at different ages and times of the year, and their kind of food 5 and specimens of some of the dubious species were exhibited. Mr. Jameson, at the same meeting, read the following mineralogical queries, and stated the reasons that induced him to consider the objects pointed out by them as deserving the particular attention of mineralogists. Mineralogical Queries, I, In what species of rock are the metalliferous veins of tyndrum situated, and what are the minerals they contain ? 9. Are the leadglance veins of strontian situated in sienite, and what are their other geognostic relations ? 3. Are the trap-veins that traverse the mining field at Strontian, basalt, porphyry-slate, or green-stone ; or do ail these different species of rock occur in that district? 4. Does the quartz rock of Scuraben and Morven in Caithness, and of Portsoy in Banffshire, occur in an uncon- formable and overlying position, or does it belong to the conformable primitive rocks, as clay-slate or mica-slate? 5. Does not the granular rock of Ben Nevis rather be- long to the sienite than the granite formation? 6. Does the rock of the Hill of Kinnoul near Perth be- long to the floetz-trap of newest floetz-trap formation ? 7. Is the mountain of Cairnsmuir in Galloway composed of old granite ? 8. What are the extent and particular geognostic relations of the black pitchstnne of Eskdale-muir in Dumfries-shre ? 9. Does the black pitchstone of the Cheviot Hills belong to the newest flcetz-trap formation ? JO. On what formation does the porphyry-slate of Braed Hills near Edinburgh rest, and what are the venigcnous aud imbedded fossils it contains ? II. What are the geognostic characters and relations of the edge and flat coal bed? or seams in Mid-Lothian ? Vol. 30. No. 120» May 1808. A a if. Oa 370 London Royal College of Surgeo?is. — M, Carnot, 12. On what formation does the CaUon Hill near Edin- burgh rest ? 13. Does the greenstone of Corstorphin Hill belong to the independent coal formation? 14. Does the hill on which the town of Stirling is built belong to the coal formation ? 15. What are the geognostic characters and relations of the veins that traverse or are included in the greenstone of the independent coal formation ? 16. What are the characters of the transition greenstone of the south of Scotland ? 17. What are the particular species of petrifactions that occur in the transition limestone near the Crook, on the road from Edinburgh to Moffat ? P. N. Sec. ROYAL COLLEGE OF SURGEONS, LONDON. The Royal College of Surgeons have adjudged the Jack- 507/za/z prize for the best dissertation on '^Diseases of the Eye and its Appendages, and the Treatment of them,'' to John Hvslop, Esq. Surgeon, Fenchurch-street. The same gentleman obtained the prize in 1 805, for the best disser- tation on " Injuries of the Head." LXX. Intelligence and Miscellaneous Articles, M. CARNOT. W iTH our present number we have given a head of the above celebrated French author, whose ^cellent Treatises on the Infinitesimal Calculus, and on Machines, have ap- peared in this work. Of a character so well known among men of science, it is unnecessary that we should say more than merely that he has been successively a member of the first Legislative Assembly, the National Convention, the Directory, and the National Institute of France. In 1800 he was the French minister of war. Besides the works al- ready enumerated, M. Carnot is the author of an Eulogium en Marshal Vauban, a discourse which gained the prize of the Dijon Cotton. — Travels. — Pyrosoma Atlanticum, 371 Dijon ac ad einy in 1784; a Collection of Fugitive Poetry; and of several Reports to the Convention, and Speeches made while President of the Directory ; all of which have been j)rinted and extensively circulated. M. Carnot was born the 13th of May, 1733. COTTON. M. Louis Dupoy, a colonist of St. Domingo, lately ar- rived in France with a variety of seeds and specimens of the cotton plant. The seeds have been distributed among the members of the agricultural society of Paris; and at a late meeting, several reports were read from members who had attempted the cultivation of this commodity in France : all these reports concur in giving a most flattering account of ' the success of the experiment. In Provence and Languedoc in particular, the crop of cotton was very abundant, and equalled in quality the production of the West Indies, as has been certified to the Frfnch legislature by several colonists. TRAVELS. M. Michaux, the author of Travels through North Ame- rica, has been recently sent by the French government, a second time, to explore the forests of that vast continent. He is now actively engaged in fulfilling the object of his mission, and has transmitted to the professors of natural history in the French Institute, several specimens of seeds, with a view to the cultivation in France of the American oak and other useful trees. PYROSOMA ATLANTICUM. M. Peron, in his late voyage, observed this animal, not described before by naturalists, in between the 3d and 4th degrees of N. latitude. Its luminous property renders it one of the most splendid of all known zoophites. The darkness was intense when it was first discovered, the wind blew with violence, and the progress of the vessel was rapid. All at once there appeared, at some distance, a vast sheet of phosphorus floating upon the waves before the vessel. The ship having passed through this brilliant part, the crew disco- vered that the light was occasioned by an immense number A a 2 of 372 Chinese 'Radish. -^Lectures. of small animals, which swam at difierent depths, and af3- . Sumed various forms. Those which were deepest looked like red-hot shot, and those on the surface resembled tubes of red-hot iron. Some were soon caught, and they were found to vary in size from three to seven inches. All the exterior surface was bristled with thick oblong tubercles, shining like so many diamonds, and these seemed to be the principal seat of phosphorescence. In the inside there ap- peared a multitude of oblong narrow glands, which pos- sessed the phosphoric property in a high degree. The co- lour, when at rest, is an opal yellow mixed with greeny but on the slightest motion, or spontaneous contraction, the animal instantly becomes luminous. As it loses its phos- phorescence it passes successively through a number of tints, ^uch as red, orange, green, and azure blue. CHINESE RADTSW. Experiments lately made at Venice show that the oil of the Chinese radish is preferable to any other kind known, not only for culinary purposes, and giving light, but also is a medicine. From the experiments lately madti by Dr, Oliviero, it is found to be extremely usefyl in rheumatic and pulmonary affections, and has been employed with much success in convulsive coughs. It is not liable to spoil by keeping, like other oils, nor is the plant injured by the strongest frosts. The^ seed, which is very abundant, is gathered in May and June, LECTURES. Dr. Satterby and Dr. Young propose to gire two Courses of Medical Lectures next winter at the Middlesex Hospital, Dr. Satterby's will be Clinical Lectures, and any of the pupils of the hospital attending them will have the privilege of seeing the patients whose cases are discussed. He will be assisted in the department of morbid anatomy by Mr. Cart- Wriorht. Dr. Young's Course will be on the Elements of the Medical Sciences in general, and on the Practice of Physic in particular. It has been erroneously stated in se- VSriil periodical publications, that Dr. Young had a large medical Lectures.— Patents for New Inventions, sfS iwpdical work nearly ready for the press : the mistake arose from his having been for some time engaged in the prepa- ration of these Lectures. Mr. George Singer is now constructing a powerful Vol- taic Battery; to be employed in a Course of public Lectures ou the Chemical Agencies of Electricity. These .Lectures will comprise the Exhibition of all the recent Discoveries ; and are arranged for delivery early in the month of June, at the Scientific Institution, No. 3. Prince's-slreet, Cavendish- square. Dr. George Pearson, F.R.S., and Senior Physician to St. George's Hospital, will recommence his Summer Course of Lectures on Physic and Chemistry, on Monday June 6, at No. 9, George- street, Hanover- square, at the usual Morning Hours j viz. the Therapeutics at a quarter before Eight: the Practice of Physic at half after Eight ; and the Chemistry at a quarter after Nine. — Clinical Lc<:tures are given, as usual, on the Patients of St. George's Hospital every Saturday morning, at Nine o'clock ; and the Prac- tice of Vaccination \\\\\ be taught at the Institution in Broad-street, Golden-square, during the Summer Course. j;iST OF PATENTS FOR NEW INVENTIONS. To Eichard Willcox,of the parish of St. Marv, Lambeth, mechanist; for certain niachinery, whereby all objects in the sea or clear water can be discovered from the surface thereof with accuracy; and for raising, suspending, and towing into harbour ships of war, and every other descrip- tion of vessels that are or may be sunk at sea or near the sea- coast, channels, harbours, road -steads, or other places, and removing sunken rocks or other obstructions in rivers, har- bours, and channels. March 3, 180S. To John Cowden and John Partridge, of Francis- street, Tottenham Court Koad, stove-grate manufacturers; forcer- tain improvements in register and other stoves. March 3. To Thomas Jeflerson, of the parish of St. Saviour, Souih- wark, tanner and leather-dresser; Joseph Ellis, of the same parish, tanner and leather-dresser; and Alexander Galloway, ofHolborn in the county of Middlesex, mechanist and engi- A a 3 neer ; 374 List of Patents for New Inventions » neer; for a machine for the purpose of finishing, glazing, and glossing of leather. March 7. To Marc Isanibard Brunei, of Chelsea ; for certain im- provements on circular saws for sawing wood in an easy and expeditious manner. March 14. To Henry Maudslay, of Margaret-street, Gavendish- squ^re, mechanist ; for a machine for printing calicoes and other articles. March 14. To Bryan Donkin, of Fort Place, Bermondsey, gent, j for a pen upon a new construction. March 14. To George Nathaniel Pollard, of Queen-street, South- wark, lapidary ; for certain improvements in machinery for grinding, smoothing, and polishing plate and other glass for looking-glasses, mirrors, and various other articles. March 14. To Edward Weeks, of Llaveny Hall, in the parish of Hen- lau and county of Denbigh, in North Wales, gardener; for a forcing-frame on a new and improved construction, for raisins; and forcino; of cucumbers, melons, strawberries, and other fruits and plants. March 17- To Anthony Thomas, of Duke-street, St. Jameses; for a method of manufacturing hats, bonnets_, and other articles of the like description. March 26. To Benjamin Cook, of Birmingham, manufacturer; for a new method of making barrels for fowling-pieces, muskets, pistols, and other similar fire-arms, and ram rods for the same. March 26. To John Dickson, of Edward -street, Southwark, engineer; for an improved method of constructing cocks for stopping fluids, and which cocks by one motion or operation will per- mit such fluids to pass in different directions. March 29. To Charles Dibdin, of Cranford, in the county of Mid- dlesex, gent. ; for his method of facilitating the learning of music. April 9. To Daniel Dering Matthew, of Upper Marylebone-street, in the county of Middlesex, esq. ; for certain improvements in the construction of watches and chronometers. April 27. To William Chapman, of the town and county of New- pastle-iipon-Tyne, civil engineer; for his methods of con- vevins; List of Patents for New Inventions, — Meteorology, 375 veying. coals and other minerals in the working of mines, or below ground, and of returning the empty vessels and car- riages. April 27. To William Bell, of Birmingham, in the county of War- wick, engineer; for his improvements in making pipes, or pumps, for conducting water and other liquids. April 30. To Edward Coleman, Professor at the Veterinary College, in the parish of St. Pancras, in the county of Middlesex ; for certain improvements in the construction and application of a horse-shoe, which will completely prevent several dis- eases to which the feet of horses are subject, more espe- cially that very general disease called contraction of the hoof; and is also particularly adapted for flat convex feet,' for horses of cavalry, and for hunting ; and for all other purposes where the loss of a shoe is productive of great in- convenience. April 30. ^ METEOROLOGY. Meteorological observations in a tabular form compress so much information in a small compass, and facilitate com- parisons in such a manner as to render them highly useful. In both of these views the following tables cannot but prove acceptable to many of our readers. The estimate of rain has been given to the public for several years : Dr. Clarke's meteorological table did not commence till last June, but we understand that gentleman means steadily to pursue the game plan. To facilitate pursuits of this kind, it is of importance that such a rain gauge should be provided as may collect all the snow as well as rain that may fall, and so arranged that the danger of bursting in a time of frost may be averted. A correspondent suggests that this object may be gained by ad- mitting the common gauge into a hot-house kept at the tem- perature of 60"" of Fahrenheit's thermometer, placing the large end of the cone at the top, in one of the squares now . occupied by a pane of glass. Should any better method for pbtaining such a desideratum present itself to any of our readers, we shall be happy in being enabled to communicate \i to the public. Qtiantity 376 MeleoroIogTf, Quantity of B-ahiy which fell at the following Places in the Year 1807. In Inches and Decirfials. By the Rev. J. Blanch- ARD, of Noifins^harn*. 1807. u 1 • I-l U o 0 it H 0-82 II * a (J a 2 "re 1 1 2 To c •J 1 Jan. 2-4 '. 0-64 1-S7 1-40 1-50 0 85 3-33 2-73 2 92 2-38 073 FeL: 2-44 l-i8 1-ec 1-79 2-77 2-(M 2 09 3 59 4 59 5 5.S 4 00 1 23 Mar. 0-23 0-50 1-36 044 1-69 1-21 2 60 112 1 52 2-21 0-57 073 Apr. o\r) J -02 0-81 0-G7 2-:56 1-77 1-17 3-19 S G6 2-90 1-72 094 May, 5-4V ;^-:^!; 3-47 5-26, 2-80 2 5S 4 70 3 75 3 97 4-47 2 86 5 03 Jujiey O-.'lS 1-74 1-92 2-8 i! 2-52 M3 2 65 1-25 2 26 2-27 400 3 00 Jail,, 1-6^ O'SS 1-54 2-26 2-25 i-n 2-43 3-50 3 74 4-48 3 43 2-55 ''Ug. 3-in 1-94 l-fi4 1-57 1-27 3-31 2- 18 1 2 92 3 49 4 58 1 40 Sf:pt. •>2£' 2-18 2-17 1-27 1-45 2-86 3 34 > 10-08 10-27 7 92 6-86 1-70 Oct. 2-4S 0-94 0-9J 3- IS 1-78 1-93 1-60 S 6 08 7 09 5-15 1-70 /Vw. 7-54 S'tiS 2-27 1-18 3-83 6-Oy 5 57 4-00 4 93 5 07 5 50 3-33 Dec. 0-8S 0'76 IDS 2-67 0-91 26-9-, 0-8G 3-20 3 26 4-53 2 6-i 0-93 Total, J9-9S 18-20 20-17 24-45 25-13 30 04 .3701 49 93 52-93 43-69 23 32 A Meteorological Talle from June to Decemler, 1807. By Dr. Clarke, of Nottingham. ts^ The followuig observations on the thenuometer are made at 8 A.M 2 P. M and 1 1 P. M and on the barometer at 2 P, M. The former instru- ment is placed in the open air, exposed to the west, but in a situation sur rounded by buildings, which prevent any alteration of temperature from cur- rents of air. The direction of the \ vind is taken from the vane of St. Peter's church ; and the numbers state how o ften it has been observed in anv particular quarter auringf the month. 1 1807. i KEtCMOMf.Ti-R BAROMKTER. 1 WEA. 1 WJNDS. 1 1 Is 0 Is u >. csi ^ 'hJT; 1 c > JZ to '^ 0 .1 2 c 0 0)' c 5 2 1 X 75" :2 46^ S 0 E -1 0 20 10 5 C/2 24 iz; June, 57«-85 100 30 31 29-531 i9 ^-^ •33 37 July, -0 52 64 00 « 30-50 29 52 29-90 •56 17 H 11 8 55 19 August, 78 ^3 S4-98 9 1 30- 18 2959 29 85 34 28 s 11 11 53 18 Seplemier, 67 40 51-93 10 30 i5 29-21 29-69 ■55 15 15 5 1 43 41 October, 65 40 53-29 14' 30- 15 29-19 29-83 -51 23 8 8 8 51 26 Xovcmber, 50 z6 88-93 M 30 10 9S 43 29 44 •80 14 16 16 2 41 31 December. 50 24 38-14 13 30 24 29- 11 29 84 ■55 25 142 6 72 2 77 9 44 48 315 34 Avr. for | 7 Mont, f 52" -73 — ^978 Totl. 206 * A-ny communications on this branch of Meteorology will be thankfully received by the Rev. J. Blanchard, Master of the Academy, Nottingham. METEOilO- Meteorology. METEOROLOGICAL TABLE, Bv Mr. Carev, of the Strand, , For May 1808. 377 Days of the rvlouth. Thermometer. ■^1 c Z Height of tnc Barom. Inches. Weather. April 27 May 28 29 30 I 2 3 4 5 6 7 8 9 10 U 12 13 M4 15 16 17 18 19 £0 21 22 23 24 25 26 37" 40 39 41 49 46 59 54 bQ 57 bQ 58 52 51 52 bb bQ 57 60 69 61 55 46 52 51 60 53 54 54 bl 40" 46 43 50 b9 Q'i 69 73 68 70 69 61 52 57 58 6b 68 76 79 SO 73 58 59 65 64 62 60 65 70 64 38 38 46 47 b9 47 bQ 57 bQ 57 50 45 49 48 54 bb 64 67 68 bb 49 48 -49 bb 54 52 52 b1 bl 29*67 •89 •90 •90 •95 •90 •84 •84 •80 •74 •60 •60 •75 30-06 •20 •38 •19 •19 •02 •06 •15 •21 29*98 •80 •60 •72 •09 •89 •07 o 16 31 46 51 64 59 72 47 62 bl 46 0 27 15 25 45 79 70 92 70 39 45 bb 35 20 19 40 52 15 Kam Cloudy Cloudy Cloudy Fair Fair Fair Fair Cloudy Fair Fair Cloudy Rain Stormy Stormy Cloudy Fair Fair Fair Fair P'air Showery Fair Fair Cloudy Showery Showery Fair Fair Showerv N. B. The Barometer*s height is taken atoi^e o'clock. C 378 ] INDEX TO VOL. XXX. ACABEMT, SLPetershurgg^ ^Icetate of Birytes. On decom- position of by soda 36 j^cidi acetic^ with dcohol. On 64 ylc'idy muriatic. On radical of 105 Mhumen and hark. On 91 Alcohol. Experiments with on muriates, Sec. 64 Alkalies, Combination of with oils 42 • . Composition oF, 366 Allen on respiration, 367 Jlfrlcan Society 284 Analysis of chromate of iron 223 Angelica antiseptic to cattle 190 Antiquaries. Society of 182 Ardent siprit made from' leaves and prunings of vines 226 Astronomy. 67, 127, 227, 347 hangalore. Manufactures at 2^^ Bark and albumen. On 91 Barome'er. Englefield's 46, 176 Barytes, acetate of. On decom- posing - 36 • , pure. On 40 Basaltes. On 182 £fl/j. On torpidity of, 249 Bermuda islands. Description ^^' 331 Berthollet on time as a chemical agent 193 Biddle on contraction of mercury by cold 1 74 Blancbard's meteorological table Booh. Ntw 1S8, 285, 365 Botany 253, 280, 333 Brandt on calculi 367 Buchamian on uses of steam 225 Buildings in hidia. Internal de- corations of 221 Calculi. On, 367 Cadet on camphorated water, 66 Calomel. New process for pre- paring, 93, 133 Caloric. On, 158 Camphorated water. Peculiar property in, d^ Carefs meteorological tables, 96, 191,288,377 Carnot. On machines, 8, 154, 207, ^10. • Works of, 270 Cattle, remedies for, 94, 190 Cement which resists fire and wa- ter, 190 Chemical agent. Time one, 193 Chinese radish. Oil of, 372 Chromate of iron. Analysis pf, 223 C/^r-^A meteorological table, 3^6 Cobalt. On, 337 Combustion. On, 158 Comet oi \%o''^. On, 67, 182 Corsica. Account of, 351 Cotton. On dyeing in India, 259, 325, 373 ; culture of, in France, 373 Cranites. On, 92 Cuvier on elephants, 15 Darcet on decomposition of ace- tate of barytes, 36 Darw'miana, 109 Davy's bases oT alkalies confirm- ed, 366. Diseases, contagious. Fumiga- tions for, 26 Diseases of plants, a prize ques- tion, 93 Dispensary Reports, 90, 176, 363 Elephants. Living and fo'^sil, i , Englefeld'sh^LYomeier, 46, 176 Epidote. On a variety of, 223 Epps's solar and lunar motions, 347 Ether, acetic. On, 64 3 muriatic, 101', nitric i 177 i^jr^ on musical tenmperament, 3 Fire, to extinguish in the dresses of females, 173 Firminger on transit of mercuiy in 1782, 289 Fremy Fremy on combining lead and alkalies Fumigation to destroy infection I N D oils with 42 26 Gas-Ughls. On, 92 Geology^ 182, 187,282, 296 Geological Society, i ^3 Gilding, /ill se, to prepare, 221 Hall on oEconomical uses of vine leaves and prunings, 226 Hawles^s system of music. On, 3 Her schtl on Newton's concentric rings, 72, 115, 19^. On comet of 1 807, 182. On Olbers's new planet, 227 H'tdeSf how dre.^sed in India, 328 Home on functions of the spleen 92 Honvard and Go's new prepara- tion of calonicl 93, 133 Hume on sulphur as a vermifuge, Hume on the identity of silex and oxygen, 165, 274, 356 India. On buildings in, 221 j manufactures of, 259,322 Indigo cultivated in France, 1 89 Insects. On destroying, 71 Iron, Chromate of, 223 'Jameson on cotemporaneous or enclosed veins, 1 87 J onminera- logical maps, 281 j queries, 369 JeweVs new calomel, 133 Kingsley on meteoric stones, 232 Knighton bark and albumen, 91 Lampadius's liquid sulphur. On, Lrj 328 Lectures J 28^, 372 E X. 379 Linn a an Soc'ety, 280 Linna^us^s ssxu.d system reform- ed, 253 Lowe on the comet of 1807, 67 Machines. Essay on, 8, IJ4, 207, 310 Magnesia. Mine of, 208 Mammoth. On the, 284 Mangali on torpidity, 245 Manufactures in India, 259, 322 Mechanics. New power in, 62, 72, 272 Medical Inslitut.ons. Utility of. Medical Soafty, hondon^ lS6 Mercury. On contraction of, by cold, 134 Mercury. Transit of, in J 782, 2f89 Meteoric Stones. Remarkable shower of, , 232 MHeorology, 96, 191, 288, 375 Mica applied to walls as a pig- ment- 222 Michaux's description of Ber- muda, 3 31 Mineral waiers. On, 1 29 Mineralogy, 182, 187,282, 296, Monkeys. On torpidity of, 24 J Moon. Motions of, 347 Morvcaus fumigations, 26 Mosaic pwuement, 1 82 Mountain barometer. Engle- field's, 46, 176 Muriatic ether. On, loi Muriates, metallic, with alcohol. On, 64 Musical temperament. On, 3 Nautical invention f 191 Nickel. On, 337 Nettles antiseptic to cattle, 1 90 Nezvton^s concentric rings. On, 72, 115, 195 Nomenclature, chemical. On, 320 0/7, manufacture, of in India, 329 Oil of Chinese radish. Uses, 372 Oils. i8o I K D £ X. OUs, Combination of, with lead and alkalies, 4!^ Olbers's miu planet. Herschel on, ia; Optics. Experiments on, 72,11^, 195, 163 Oxidation, Only two degrees of. Oxygen, identity of, with silex, 165,274,356 Oxymuriat'ic acldiv'itb alcohol, 64 Patents. List of, 94, 19 1, 287,373 Pi rperes* d cwipositiofi of acetate cfbarytes. On, 36 Ptpys on respiration, 367 Petersburg Academy, . ^.«3 Potaib. On constituent princi*- pies of, 173 Prize questionsy 93 Fyrosoma ailaii.'iciim, 371 Rain. Quantity in 1807, ^"^6 Rampasse's history of Corsica, Richardson's geological observa- tions on Ireland, 182 Robiquet on liquid sulphur, 30 on pure barvtes, 36 Rocks. On blasting, 97 Po!off on mineral waters, 132 Royal Sociefy, 91, 18 ,280, 366 Ryul College of Surgeons^ London , SchoJcs on caloric, 1^8 SileXf identity of, with oxygen, l^'5» 2 74' 30 Silk. On dyeing in India, 259, 324 SUHman-'OVi meteoric stones, 232 Skins, how dressed in India, 328 Socieliesy Learnedj gi, 182, 280, 366 Spirits made from leaves and prunings of vines, 226 Spltcn. On functions of, 92 St, F(?/-7/' J journey lo mount Ila- mazzo, 296 Stains, to remove from linen, 189 Stanhope Temperament. Ort, ^ Steam employed to heat build-* ings, and to dry articles of manufacture, 225 Stones from clouds, 232 Sulphur of Lamp adtus. On, 30 Sulphur a good vermifuge, 7 1 Sulphurous mineral waters. On, 129 Sun. Motions of, 347 Surgical CaseSy 90, 176, ^6^ Siuanivick on new mechanical power, 62 Taerg on constituent principles of potash, 173 Tamping. On blasting rocks by, 97 Tanning In India> 328 7"^ wK/cff'i Dispensary reports, 90^ 176,363 Taunton on medical institutions, i7r Taylor on blasting rocks, 97 Thi-Tiard on cihers^ 64, loi, 177 Tkornton^s reformed sexual sy- stem of Linnaeus, 253 Time^ influence of, as a chemical On, 245 271 agent. Torpidity of animals. Travels, University of Edinlurgh, 34S Varioiite. On, 304 Faiiquelin on liquid sulphur 30 Fermifuge. A good one, 7I Vidal on new power in me- chanics. 12, 272 Vines. G^'.conomical uses of prun- ings and leaves of, 226 Walker on apparent magni- tudes, 163 JVernerian Society, 186, 281,368 ^7/;«OT(^ on mineral \^aters, 129 iVilna, university of, 93 IVool. New method of scouring 94 Zoophit. s. New species of, 3 7 J Zoysiti, a variety of epidote, 223 END OF THE THIRTiETH VOLUME. printed by liirhard Tgijl