; ' d or oast* c c> .JR Hgg g§P |p||§B gas :~gjl |o|13 j§ > * K >» >»:> ~-m. KT1 © - LIBRARY U. i 1 4* ■ / .. • : : 5. PATENT OFFICE. JVo. Class Case ! C Shelf i !*&) \ ■« I I PROCEEDINGS OF THE LITERARY AND PHILOSOPHICAL SOCIETY OB' MA NCHESTER. VOL. VIII. J Session 186S-9. MANCHESTER : PRINTED BY THOS. SOWLER AND SONS, RED LION STREET, ST. ANN’S SQUARE. LONDON : H. BA.ILLIERE, 219, REGENT STREET. 1369. NOTE. The object which the Society haye in view in publishing their Proceed- ings is to give an immediate and succinct account of the scientific and other business transacted at their meetings, to the members and the general public. The various communications, are supplied by the authors themselves, who are alone Responsible for the facts and reasonings con- tained therein. 1 N D E X. Alcock Thomas, M.D, — On Gonoplax angulata, p.77. Bailey Chaeles, Hon. Lib, — On tlie Vegetable Remains found in the Crevices of the Mountain Limestone at Aldby, Cleator Moor, p. 55, On Scirpus parvulus, from Wicklow, p. 103. On a Deposit in Dog’s Bay, Connemara, destitute of Foraminifera, p. 199. Baxexdell J., F.R.A.S, Hon. Sec.- — On Observations of Atmospheric Ozone, p. 21. On the Lunar Spot IV Aa 17, IVA£ 39, p. 46. Observations of the Transit of Mercury, Nov. 5th, 1868, p. 47. The Bleaching Action of the Atmosphere on Ozone Test Papers, on the day of the Colliery Explosion at Hindley Green, p. 58. On a Diurnal Inequality in the Direction and Velocity of the Wind, apparently connected with the Daily Changes of Magnetic Declination, p. 95. On the Fall of Rain at Different Periods of the Day, in connection with the Diurnal Changes of Magnetic Declination, p. 111. On the Aurora of April 15th, 1869, p. 186. Bickham Spenceb H., Junr. — Remarks on the Flora of Cheshire, p. 165. Binney E. W., F.R.S., F.G.S.— Note on Professor Williamson’s Paper “On an Undescribed Type of Calamodenclron from the Upper Coal Measures of Lancashire,” p. 49. On Explosions of Fire Damp in Collieries, p. 57. Note on the Organs of Fructification of Calamo- dendron, p. 82. On a Specimen of Lepidoscrobus, p. 92. On the Rise and Progress of the Trade in Petroleum, p. 135. The Earth- quake of March 15th, 1869, p. 161. Beockbank W., F.G.S. — The Hematite Iron Ore Deposits of Whitehaven ; Notes on the Aldby Limestone, Cleator Moor, p. 51. Beothee A., F.R.A.S. — Observations of the Occupation of 119Tauri, p. 107. Cockle Chief Justice, M. A., F.R.S., F.C.P.S. — On Convertent Functions, p. 2. Ckompton S., M.D. — On the Deformities in the Legs of Young Children, p. 186. Daxcek J. B., F.R.A.S. — Observation of the Transit of Mercury, Nov. 5th, 1868, p. 48. Remarks on War Rockets, p. 89. On Microscopical Examination of Dust, p. 105. On the Markings on the Pleurosigma Angulatum and on the Lepisma Saccharina, p. 156. On Specimens of Euplectella aspergillum, p. 199. VI Darbishire R. D., F.G.S. — On a Collection of Land Shells and Sluggs made at Gibraltar in March, 1883, p. 78. Darling W. H. — Researches on Di-Methyl, p. 59. Dyer J. C., Y.P. — Remarks on the term Commerce, and on the Sources of Wealth, p. 121. Remarks on the Nature of Wealth, and on its Uses, p. 139. On the Principles of Free Trade, p. 164. Felt Charles Wilson. — On the Use of Logotypes, p. 150. Forrest H. R. — Has the Human Mind Progressed or Retrograded since the time of Augustus, p. 94. Gladstone T. S. — Results of Observations of Temperature and Rainfall made at Drumlanrig and Capenoch, in the year 1868, p. 193. Gladstone Murray, F.R.A.S. — Observation of the Transit of Mercury, Nov. 5th, 1868, p. 48. Harley Rev. Robert, M.A., F.R.S. — On the Rev. T. P. Kirkman’s Method of Resolving Algebraic Equations, p. 4. Hart Peter. — On a Method of Making Rapid Determinations of Free Oxygen, p. 188. Hereord Rev. Brooke. — The Earthquake of March 15th, 1869, p. 176. Heys Richard. — Observations on Anguillula tritici, obtained from Wheat of various Harvests, p. 158. Hunt G. E. — Notes of the Rarer Mosses of Perthshire and Braemar, p. 130. Hurst H. A. — Notes on Plants Occurring Spontaneously on Newly-turned Land in Tatton Park, p. 200. Jack Professor W., M.A. — On Professor Tait’s Work “ On Thermody- namics,” p. 39. Jevons Professor W. Stanley, M.A. — Remarks on Mr. Baxendell’s “ Laws of Atmospheric Ozone,” p. 33. Remarks on Mr. Dyer’s paper “ On the Nature of Wealth,” p. 149. Joule J.P., L.L.D., F.R.S., P. — On Objectionable Covenants in Conveyances of Land near Large Towns, p. 148. On a New Magnetic Dip Circle, p. 171 and p. 190. Kipping J. S. — The Earthquake of March 15th, 1869, p. 176. Mackereth Thomas, F.R.A.S. — On the Mode of Registering the Direction and Force of the Wind, p. 109. Results of Rain-Gauge and Ane- mometer Observations made at Eccles, near Manchester, during the Year 1888, p. 117, On Atmospheric Ozone, p. 194. Morris Walter. — On Pediculie pubis, p. 158. On a Pair of Kangaroo Eats from Australia, p. 191. Nasmyth James, C.E. — On War Pockets, p. 84. Oxley William On a New Anemometer, p. 107. Roscoe Professor H. E., F.E.S., Hon. Sec. — On Janseen’s and Lockyer’s discovery of tlie Visibility of the Spectral-Lines of the Red Solar Prominences, under ordinary circumstances, p. 35. On Measurements of the Chemical Intensity of Total Daylight made during the recent Total Eclipse of the Sun, by Capt. J. Herschel, R.E., p. 42. On MM. Graebe and Liebermann’s Discovery of the Artificial Preparation of Alizarin, p. 163. Schunck Edward, Ph.D., F.R.S., V.P. — On the Chemical Formula of Aliza- rine, p. 173. Sidebotham J. — On Cynips Lignicola, and the Comparative Value of English and Aleppo Galls, p. 71. Further Notes on some of the Rarer Plants found near Llandudno, p. 72. On the Moth Anaphe reticulata, p. 155. On the Nest of the Mason Spider, p. 156. Simpson Henry, M.D. — On Acanthocinus sedilis, p. 76. Spence Peter, F.C.S. — On Sulphurous Acid in the Air of Manchester, p. 137. The Earthquake of March 15, 1869, p. 162. On the Aurora of April 15th, 1869, p. 186. Vernon G. V., F.R.A.S. — On the Rainfall of 1868, at Old Trafford, Man- chester, p. 159. Vize Rev. J. E., M.A. — On the Kangaroos of Beeston Castle, p, 190. Watson John. — On the Plumules of Lepidoptera, p. 132. Wilde Henry. — On a Property of the Electric Current to Control and render Synchronous the Rotations of the Armatures of a number of Electro-Magnetic Induction Machines, p. 62. On the Controlling Power of the Magneto-Electric Current over the Rotation of a number Armatures, and that of the Voltaic Current over the Oscillations number of Pendulums, p. 81. Wilkinson T. T., F.R.A.S.— The Earthquake of March 15th, 1869, p. 162. Williamson Professor W. C., F.R.S. — On the Structure of an Undescribed Type of Calamodendron from the Upper Coal Measures of Lan- cashire, p. 36. Additional Notes on the Structure of Calamites, p. 153. On the Structure of the Gizzards and Teeth of the Rotifera, p. 176. Wood Wm. Rayner.— On the Earthquake of March 15th, 1869, p. 175. viii Meetings of the Physical and Mathematical Section. — Annual, p. 193. Ordi- nary, pp. 45, 46, 95, 107, 159. Meetings of the Microscopical and Natural History Section. — Annual, 200. Ordinary, pp. 69, 70, 72, 102, 130, 155, 165, 190, 198. Report of the Council. — April 20th, 1869, p. 179. PROCEEDINGS OF THE LITERARY AND PHILOSOPHICAL SOCIETY. Ordinary Meeting, October 6th, 1868. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair. The President, in announcing the loss which the Society had sustained in the lamented death of its late Treasurer, Mr. Robert Worthington, F.R.A.S., referred to his long con- nexion with other Literary and Scientific Societies and Institutions, and to the active and encouraging interest he always took in scientific subjects, especially those relating to astronomy, and stated that his observatory at Crumpsall Hall had attained a high position among the private obser- vatories of Europe. The work done comprised many valu- able observations of planetary, cometary, solar, and lunar phenomena; some thousands of observations of variable stars ; the discovery of ten new variables ; the determination of the places, and mapping down, of most of the stars in several of the more interesting of the large clusters ; and occasional observations of some of the nebulse. In conse- quence of the effects of an injury to his right eye, Mr. Wor- thington had not been able for several years to take an active part in the work of the observatory, and the observations have been made by his friend Mr. Baxendell, who has pub- lished some of the results in the Society's Memoirs and Proceedings— Lit. & Phil. Society. — Vol. VIII. — No. 1. — Session 1868-9. 2 Proceedings, in the Monthly Notices of the Royal Astrono- mical Society, and in the Astronomische Nachrichten. Mr. Thomas Garrick was elected Treasurer of the Society in place of the late Mr. Worthington, F.R.A.S. A long conversation took place on the high rate of mor- tality which has prevailed in Manchester and Salford for some time past, and an opinion was generally expressed that its true causes had not yet been clearly indicated. In spite of their excellent systems of street paving and sewering, their plentiful supply of pure water, and wholesale but pro- bably not well considered interference with private petties, ashpits, and water closets, the death rate of these towns continued to show a steady increase, and still stood above that of any other town in the United Kingdom. “On Convertent Functions.” By Chief Justice Cockle F.R.S., &c., President of the Queensland Philosophical Society. Communicated by the Rev. Robert Harley, F.R.S. The theory of the conversion of integrals, of which I have given outlines (see supra vol. vii., p. 67; Phil. Mag. for July and December, 1867) will, I believe, be found to give an additional means of finitely solving differential equations. It is not necessarily restricted to the case in which tfie in- tegral to be converted is a single integral. Thus suppose that we have given the double integral J'dv fdu ' (f) ( x , v, u) or, more shortly, fdv Jdu ’ (f) , we first treat M' u by forming the convertent equation df du SFW)s“S=*"'(2> where the coefficients F (a, b) are functions of x and v only (excluding u) and the a’s and the b’s are zeros or any posi- 3 tive integers and either equal or unequal, and wherein, if the differential equation in which x is the independent variable is to be linear, we may give b the value unity in one term and zero in all the rest. If we so deal with b then (2) may be replaced by dti ^ . . dnd> df i + aF(«)«^2 = ^-(8) any number of values being assigned to a. Taking the in- tegration with respect to u as definite we shall thus obtain, in the practicable cases, f — fiji — rfdv we may repeat the process of conversion which, tentative to a certain extent though it be, may enable us to express by indefinite integrals the roots of trinomial algebraic equations. My paper — “On Certain Rational Fractions,” in the Mes- senger of Mathematics, No. 15, 1868, contains results which may be useful in the application of this theory of conversion. In the last two equations above given the repetition of the process of course takes place on the functions which con- stitute the dexters of those equations. 4 “ On the Rev. T. P. Kirkman’s Method of Resolving Alge- braic Equations.” By the Rev. Robert Harley, F.R.S., Corresponding Member of the Society. In two papers published last March in the Proceedings of this Society (vol. vii, pp. 183-7, 141-8), the Rev. T. P. Kirkman proposed a method of resolving algebraic equations of all degrees. A few weeks ago I pointed out to Mr. Kirkman in a private communication that his method, when applied to the higher equations, fails. I objected in particular that in dealing with the general quintic he assumes that certain functions which are only symmetrical in four of the roots, are symmetrical in all five, and that this false assumption vitiates his solution. Mr. Kirkman has since acknowledged (vol. vii, p. 222) in the most full and sufficient manner the validity of my objections. I find by a letter received yesterday that my distin- guished friend the Chief Justice of Queensland has taken substantially the same view of Mr. Kirkman’s method as myself. His remarks are so interesting and instructive that I venture to lay them before the Society, I take the liberty also to append thereto some remarks of my own : The Chief J ustice of Queensland to the Rev. R. Harley. “ Brisbane, Queensland, Australia, “July 30, 1868. “I am not disposed to assent to Mr. Kirkman’s views on the quintic, i. e., not to the validity of his alleged solution. His assumed form, at p. 134 of the Manch. Proc., vol. vii., is not the same as Lagrange’s. Compare Serret Gouts, 2nd ed., p. 567. Let us put — Xq + ClX^ + Cl -r Cl X 3 -f- Clb/4, then the Lagrangian theory gives xh = | 'ZiX 4- a~k(a,x) + a~ 2k(ci2,x) + a~2k{cd,x) + a~4A’(ci4,#) | which seems to be different from Mr. Kirkman’s formula. As I understand it, the theory of the resolvent is this, — 5 the four expressions (a,x), (a2,x), (a3,x), (a4,#) constitute a group of four, viz., the group 1234 2413 3142 4321 wherein the numbers have reference to the suffices ol the xs. This group has a further peculiarity. Effect a cyclical permutation to the cycle 01234 in the group. This is effected by changing the four expressions into a(a,x ) j a2(a2,x ) \ a3(a3,x) ; a4(a4,x ) respectively. Let 7 r be the product of the first four expres- sions, (ci,x), (a2,x), &c. Then 'the product of the latter four, viz., a(a,,x), a2(a2,x), &c.} IS equal to a.a2.a3.a4.7r = a107r = 7r. Ill other words, n is unchanged by the cyclical substitution, and is at once a group of four and of five, and has — — or six values. Similarly the four expressions, j (a2#)}5, &c., are severally equal to the four, {a (a,#)}5 {a2(a 2x)}5, &c., and any symmetric function, say, (a,x)5 + ( a2,X )5 + (a3,#)5 + (a4,#)5, is also a group of five and of four. Let (a >) = Q,., and for a moment put This is a very different system from the system given by Mr. Kirkman, at p. 134 (op. cit.), which is x0 = *2® + I(pf y + &c. = is* + i(s + H, j * + (fee. Mr. Kirkman says (ib.) that Hj is unaltered by the cyclical permutation of XqX^x^. But what of H2 and H3 and H4 ? And if H2 and H3 and H4 are not also unaltered by the same cyclical permutation, all connection with the theory of Lagrange or the method of symmetric products seems to be lost. I think that in our correspondence some ten years ago I said a great deal (or something, at all events) about the disruption of cycles. It might be worth while 6 for you to see, and also for you to compare Mr. Kirkman’s system of permutations, at p. 141 (ib.), with that in my “ Notes on the Higher Algebra,” Q. J., vol. iv., p. 53, and to turn to my “ Supplementary Researches,” &c., in the Manch. Memoirs. In forming the system Hf+ &c. =(A % . . . H2\+ &c. =(F )i (ib., p. 142), Mr. Kirkman has only taken account of permutations of %i,x2,x3, and x±. He takes no account whatever of the permutations of x0, further than observing (ib., p. 142) Hx is invariable for the cyclical permutation of x0,xx,x§x3,xg He neither asserts nor denies that H2, H3 and H4 are invariable under that permutation. I suspect that it will ultimately appear that Mr. Kirkman has only succeeded in expressing Hx, &c., as functions of x0, and not in terms of symmetric functions of all the roots. And functions of x0 are useless for the purpose of solving the quintic. You speak of Mr. Kirkman’s presenting a solution of the general equation of the 7th degree. I think you are right in believing that he is quite wrong. Probably the same error runs through it as in his paper on quintics and sextics. Even if Mr. Kirkman has not solved the quintic, still if he has made the solution of a sextic depend upon that of a quintic, that will be an advance in the theory of equations. Rut I am as little able to assent to Mr. Kirkman’s theory of sextics as to his theory of quintics — in which latter, I may add, there is an internal variance ; for at p. 134 he seems to derive H1,H2,H3,H4 from the group 01234 (H,) 02341 (H2) 03412 (H3) 04123 (H4) while at p. 141 he seems (compare p. 142) to derive those four H's from the group 1234 2143 3412 4321 7 which is the group over A on p. 141, and to each member of which we may, I presume, prefix a 0. By the way, ought not the group over C to be written 1423 4132, not 4123, which occurs over F? 2314 3241 But to proceed to his theory ol sextics. He appears to desire to construct his expression for x0 at p. 144 on the groups’ of p. 145. If so, there is an inaccuracy, which may be corrected by writing 0Co=l^+l X0 X3-\- &c. | 6 )s + 6 „ « i 6 \ 6 }•)* + + X0 #4+ &c. X() X5-\- &C. x0 — xl-\-a (x,l — x3) + a2(x5 — x3) x0 — x2-\-a (x5 — x3) + a2(^! — #4) 6 \ 6 1 6 \ 6 there are errors (I think) in the lines corresponding to the last two at p. 144. Now Mr. Kirkman says, that Hb H2, &c., after involution are invariable by the cyclical permutations of x0x1x2x3x^x5. But I think that is not the case. If Hj is so cyclical, then S-f is so (see p. 144, for meaning of S and H). But 1, S+H1= ^ | xo — xz + a (xi — xi ) + cl2(x2- — x5) | °y ; x 6 \ 6 now make the cyclical permutation and = k | — (*o— x3)+a(x!— x4)+a2(x2— x5) for a is an unreal cube root of unity, and a3=a6=l. Now S + Hj and (S 4- ^1)51234^ differ, for the quantity (x0 — x3) has 8 changed its sign, and the difference is not obliterated by in- volution. Hence is not cyclical, and I think the method fails. Again, I do not assent to the principle contained in the words at p. 146, “that the involutions cannot destroy the symmetry in the roots.” For instance, the expression (x0 -j- xx) + (x2 + x3) = Sx is symmetric, but (x0 + aq)2 + (x2 + x2)2 = 2x2 -j- 2(x0x1 4- x2x3), and is not symmetric but has three values. Next as to Hargreave’s Posthumous Essay. The British Association have paid a tribute to departed worth, and also to you in naming you to report on it. You will, of course, examine it carefully. I read it some time ago and made a brief communication to you about it. You as well as I seemed disposed to think that Hargreave recog- nised -J- and — as radical signs, where he excluded others. But it is necessary to be careful in criticising him, as he cannot now explain his meaning, and very likely where he uses + and — it is on the express understanding that the radical is capable of extraction. I looked at the Essay be- fore the last mail left on the chance of being able to render you some assistance, but in vain. Since then I have looked at it more narrowly. Many observations will have occurred to you in perusing it, and I can now only give you my pre- sent opinion respecting it, which after all is but a mere opinion, and subject to correction or modification. I can- not give assent to all his views. On arts. 9 and 10, pp. 12- 14, every one must form his own opinion. I propose to go rather into special points. I cannot feel so strongly as that able man seems to have done, the necessity for uniqueness of expression (see pp. 45, 48, 51-2, &c., 77 and, probably, other places). There seems to me to be a capacity for re- storing the uniqueness, even when the quantic is conditioned. Thus, by way of illustration (the illustration being capable probably of any requisite extension). Suppose that we have given the fact that, a certain quadratic wanting its middle 9 term, and whereof the roots are x1 and x2 has both its roots expressed by the formula 2 ^ 4xxx2 > now we know that this formula may be cleared from radicality. There is a way, and it seems to me a unique and perfectly definite way, of doing so. Since the quad- ratic is imperfect x1-\-x2 — 0 ^ and since we may introduce a zero (additively) under the radical sign, we may put the radical formula under the form JO — 4xxx2— J(cc i+#2)2 — 4xxx2= J(x1—x2)2=±(x 1 — x2), and then 0±.(xx — xi)=xx<\-x.1±.{x x — x2)=2xx, or 2x2, and thus - J—4xxx2 may be made to yield the roots. More- over, there seems no other way of obtaining the roots, and the result and process are each unique. We may always supply zero functions whether simple as a = 0, or complex as a? — 6 = 0, and the conditions which they are to satisfy are such as to enable us to extract the roots of the radical expressions in a^, x2, &c., for Hargreave (see p. 121) does not dispute Abels principle, but rather regards his theorem as a truism (ibid). Again, I cannot concur with Hargreave in supposing that there is an impassable gulf between the trinomial quartic or quintic, and the perfect forms (see, for instance, pp. 90, 100-1). Surely from Zn+AZ+B=0 we can, by assuming C— «0Z”— 1 a1Z,i~2-f- . . • pass to the n- ic &c.=0 whose n co-efficients will involve n arbitraries a0, ah . . a,^. and, therefore, be arbitrary, and the equation consequently general. With regard to Hargreave’s theory of the cubic, the formulse at p. 24 seem to show that, interesting though his theory be, it ultimately coincides with Lagrange’s, for 10 Lagrange determines the ratios of Ah A2, . . . Bb &c. a priori. With respect to quartics, Hargreave seems to have thought that he had obtained new results, indeed a new solution. He sees an objection (pp. 100-101), and seeks to obviate by saying that there has been a change in the framework of the root. Far be it from me to contradict him dogmatically, but one cannot refrain from the observation that if we have xi-\- &c.=0, y—p-\-qx-^r . . +sx% and, consequently, by division and reduction <»=P+QH- • • 4- Sy3, we must not be surprised to find in the last expression for x any radicals that we may have introduced into p, q, &c., and which will reappear I suppose in P, Q, & c. and the accompanying y°, y, &c., but (as I take it) in such a manner as that when development takes place all those radicals will disappear from the final expression for x leaving only the usual radicals. Hargreave however relies (p. 100) on the “ special or singular forms of \p (x) which,” &c., (and see p. 101). He does not miss or ignore the objection, but seeks to obviate it. I am only expressing a mere opinion of what the final expression would contain, and am unable to give you (what would really assist you if not too late) the actual calculation of the final expression. If n be the discrimi- nant of the quartic in x so that n = (x0 — x^\x0 — x2)2 . . . then the discriminant of the quartic in 0 or (p (x) is (conform- ing more closely to Hargreave’s notation, p. 63) | k(xl^-x2) + 1 | (xx — x2) | h(xx-\ -x3)+l | (#!— #3) rz:7r | k(xx-\-X^)-\-l j ^(Xy—'X^)— -7T "I 7c(X] -p Xo) j Q 7T denoting the product of the various values of the expres- sion which follows it (compare pp. 63-64). And we see that so far as the discriminant of the equation in 0 is concerned the new radicals multiply the old radical, and probably or certainly the old radicals will appear (considering for a 11 moment only the term Q y of x) both in Q and in y. But, this is what I suppose might in any circumstances be ex- pected (compare Serret, 2nd ed., p. 562, equation (1) and lines which follow). If it should turn out that Hargreave’s second solution of the quartic does not essentially differ from the old one, will not the validity of his solution of the quintic be disprobabilized ? In the instance given at p. 4 can we not extract the roots of the algebraic formula so as to obtain 2, and 3+ J — 1 (see Gamier, Analyse, 2nd ed., ch. 15, p. 321)? As to linearity of results, Hargreave uses the principle of articles 9 and 10 (p. 12 to p. 14) to account for the linearity. But the fact of the principle accounting for certain results in the case of cubics and quartics or per- haps of quadratics, scarcely proves the universality of the principle. Hymers (Equations, 1837, p. 54) speaking of the equation xn — qx+r— 0, says, it ‘which has necessarily n — 2 imaginary roots, will have two real roots or none, according as (l) 7 or ^Gr~l) (e^ v^e ibid. p. 52 and pp. 99-100, and compare Hargreave, p. 115). But the existence of a cubical function of this kind does not appear to have sug- gested an algebraic solution of the equation — though per- haps we might (probably enough) conjecture that such functions would enter into the expression for the root even were such expression transcendental. Moreover, I am at present unable to attach the same importance as Hargreave does to the system of 3 cubics, (p. 28), of 2 quartics (p. 41), (p. 53), (p. 99 ?), and of the 5 quintics (p. 72). Hargreave does not overlook objections (see p. 32, foot note, to which references I would add one to Waring’s Misc. An., pp. 38-9, to my paper on Approximation, &c., in Diary, arts. 56 and 57, and elsewhere). Supposing that we adopted a system of 5 congeneric quintics, should we account for all the va- lues of the root ? Suppose, for example, that the root of an imperfect quintic is a sum of 4 quintic surds, Waring ob- 12 serves (see my paper on Equations of the 5th degree in Diary, art. 32) that stich a sfim would be the root of an equation of 625 dimensions [not of 25 only]. Let (sc) be an algebraic root (assumed for a moment to exist) of a trino- mial quintic. We know that a (sc), a2(x), &c. ( a being an unreal fifth root of 1), will be the roots of the correlated quintics. But this is no more than the very form of the quintics shows (p. 86). The multiplication of (sc) by a makes no alteration in the internal distribution of the radi- cals in (sc), and it seems to me that all that can be said is that if (sc) be a root of sc5+ A4sc-f- A5, then a(sc) is a root or the root of sc5 + aA4sc-f- A5. Using A to denote the discrimi- nant of the quintic (p. 68), we may of course put A, and hence get h — +^A S2 = — Is = + y/~l y/ — \/>— 1v4/A. Hence, for instance, — £2=2^ A, and if v denote the discriminant of the quartic in £ we see that when A=0 then v— 0 (compare pp. 63, 89, 90). But as Hargreave probably (or rather certainly, see p. 70) was aware, there is nothing in this. What Hargreave relies on is — and now I fall in with his notation — that when %, — y — (51) we then have the system of p. 85 and the result mentioned at the top of p. 86. In estimating Hargreave’s argument we ought now not to forget the argument of Mr. Cayley as given at p. 100 of Mr. Salmon’s Higher Algebra (1859), art. 130. But how far can such an argument be carried ? Turning to p. 91 and taking y7r=B1-f- we have by involution ;y==:Ri+10R^R2+5R1R2+(5R4+10R2R2+R2) ^ and therefore (see p. 91), R1(R;+10R12R2+5R^)=S5 ..... (a), (5R1+10R^R2-1-R^2R2=R10 (b). Ro being of two dimensions only, cannot have so few as six values. How is the sinister of (a) symmetric ? Now, though I think that perhaps (b) furnishes the stronger ground for conjecture that Hargreave’s conjecture (I so call it 13 not to undervalue his research, but because at p. 87 he says that the fact that the Y’s are perfect fifth powers ‘ probably cannot be proved otherwise’ than from, I suppose, a priori argument as opposed to calculation — his conjecture may nevertheless be a justifiable one) is not borne out by fact than (a), yet the latter affords some ground for remark. Rx must be unsymmetric (as indeed Hargreave seems to imply), for if we consider Ri as symmetric and solve (a) for R2 we shall find R2 = a two valued function, which cannot be, for R2 is of two dimensions only in the roots, and cannot therefore be two valued for a quintic. Again, solving (a) with respect to Rx we see that the number of values of Ri is a multiple of 5, and therefore that Rx is not cyclical. And we know it is linear. If therefore, since S5 is symmetrical, we are to regard the bracketed quantity on the sinister of (a), viz. RH-10R?R2+ 5R| as the product of the remaining values of the Rx outside the bracket we must regard Rx as of the form A-j- Bzr, z being some one root, and the bracketed quantity Rf as equal to (A+B<)(A+B0,) . . .=7r(A+B?)-(A+B?r), 2S zt, &c., being the remaining roots. Hence (a) would be- come 7t(A+B^)=S5. But how is such a form consistent with the fact of R2 being unsymmetric ? It must not be said that R2 may be symmetric, for if that were so, then Rx being a five-valued function, the sinister of (b) would be a five-valued function, and therefore R10 would be five- valued. But that is not so ; for ^,/Rl0= A— £/ tt{xx — #o)2 Therefore Rxo=tt(#i — x2) = a two-valued function, But apart from this argument, which may however (as it stands or with more elaboration) be conclusive, let us turn to (b). What ground is there for saying that R10, or what is the same thing, tt(xi — x2) or, the same, {X 1 Xi) (Xl X:i) (xi x:>) is of the form P2Q as indicated by (b) ? (b) is equivalent to 14 iv( (5R? + R2)2— 20R* | =^(*I— Xt) (c) and R l='2ar%r and R2= -'2larxl-\-'2bxrxs But does the square root of the discriminant of a quintic admit of being put under such a form ? At present I can- not assent to the proposition that Hargreave’s process suc- ceeds in solving the quintic.” Mr. Kirkman’s method does not differ essentially from that employed by Vandermonde in his Essay on the Resolu- tion of Equations in the Memoirs of the French Academy for 1771. Both start from the same identical equation, and both, proceeding by involution, seek to express one root of the given equation by means of a finite combination of radicals and rational symmetric functions of the roots. Such functions, it is well known, can be expressed rationally in terms of the coefficients.* The following illustrations of the method may not, perhaps, be altogether devoid of interest. The Quadratic. Let OCfy t )C\ be the roots of the equation. x2 + bx + c = 0 ; then 2x0 = %x + (xQ - xx) 2_ = 2x + (x0 — Xi) 2 = 2# + (XV - 2x0x1)i = - b + (b2 - 4 cf ; # Vandermonde, in the Memoir above referred to, gives tables of such functions up to ten dimensions in the roots of an equation of any degree, ex- hibiting their values in terms of the simple symmetric functions 2A, HiX0X^ &C. The last-named functions are respectively equal to — 6, c, —d, (fee. in the equation xn + bxn~l + cxn~2 4- dxn~z 4- &c. = 0 ; so that the tables at the end of Meyer Hirsch’s Algebra which give the sym- metric functions of the roots in terms of the coefficients, may be immediately deduced from Vandermonde’s, by simply changing the signs of the numerical coefficients in the tables if odd dimensioned functions. I may here mention also that Professor Cayley, in a Memoir on the Symmetric Functions of the Roots of an Equation, {Phil. Trcms. for 1857), has joined to Hirsch’s tables another set, giving reciprocally the expressions of the powers and products of the coefficients in terms of the symmetric functions of the roots. 15 1 7 1 . . xx~ - _ o + _ 2 2 and since 2#! = 2a: — (#0 — x^) ; 'b2~4cy. The Cubic. Let x0, xh x2 be the roots of the equation. xz + bx* + cx + d = 0, and let a be an unreal cube root of unity ; then 3^0 — "SiX 4~ (Xq 4" ClXj_ 4" Cl x%) + (Xq + cl'“Xi H- ctX^) 3 3. — ^jX + (oCq + o.x^ + cCx^j 4" (xq + cdx-^ + cix^j = %x 4- (Sr3 + 6x^X0, 4- Scl'Si'XqXi + 3a2S/^o072)i 4- (2 + 3a2S/^Q.r1 4- SaS'fl?2^)** where, for shortness, I have introduced my cyclical symbol S'. (See Society’s Memoirs, second series, vol. xv., p. 185. See also Phil. Trans, for 1861, p. 333.) Now S'4ci+21a9»* ~ = — (be — 3c?), and ( /y& /y I I _ ry-Q /y> \ aj (A/Qf/t/g — ^(ri\w(r2 I ^i^o 1 / — /yi^/y* /y* /y>2 y»2/y,2\ — 1 tA/Qcv ^2 1 | - tA'QiAs'j^ ^ tft/Qbft/jxft/g / /v»4/y» /y> | V /yi^ /y>^ I. ^ /V^ svQ /y:2 = ^_6M+c3+9^ Whence it appears that S 'x\xi and S'afe are the roots of the quadratic equation S/2+(6c — 3^)2' -p&3d — 66cc?-|-c3-|-9 L. /y» sv> / ■ — /%• ry> I _ y> ry\ / — — => /yi /y» ( /y* /W tq — ■■■ ■ rd > 6 .. 0-519 17 55 18 .............. 0-685 6 ?? 7 .. 0-439 18 55 19 0-592 7 V 8 .. 0-505 19 55 20 .............. 0-657 8 9 .. 0-490 20 55 21 0-527 9 10 .. 0-605 21 55 22 0-560 10 11 .. 0-549 22 55 23 0-339 11 55 12 .. 0-569 23 55 24 0-456 On looking over these numbers it will be seen that the least amount, ’339, occurs between 22h. and 23h., or in the hour immediately succeeding the moment when the mag- netic needle passes its mean position in the morning; and that the next amount in magnitude, ‘439, is between 6h. and 7h. or in the hour immediately following the needle’s passage through its mean position in the evening. Taking the two hours from 22h. to 24h. and the two from 6h. to 8h., the sum of the amounts is T739, which is less than that of any four of the remaining 20 hours. Taking now the four hours from 21h. to lh. and the four hours from 5h. to 9h., the sum of the amounts is 3‘860, which is less than that of any eight of the remaining sixteen hours. Next, taking the five hours from 20h. to lh. and the four from 5h. to 9h., 114 the sum of the amounts is 4*387, which is less than that of any nine ot the remaining fifteen hours ; and in fact eight out of the nine amounts are the lowest eight in the whole twenty-four. It appears therefore from the means of all the years that the amount of rainfall is least at those times when the declination magnet is at and near its mean posi- £ tion for the twenty hours, and it will he seen from the following table that this relation also holds good for each separate year. Sums of Hourly Amounts of Rainfall. -- .. 1861 1862 1863 1864 1865 1866 h. h. 20 to 1 5 to 9 in. 2-904 1-727 in. 2-938 2-471 in. 1-806 1-750 in. 1-821 1164 in. 2171 2-930 in. 2-962 1-677 Sums 4-631 5*409 3-556 2-985 5-101 4-639 Hourly means . •514 •601 •395 •331 •566 ■515 Sums of remain- ing 15 hours. . . 8-316 11-444 8-547 6-906 11-769 12-201 Hourly means.. "554 •762 •569 •460 •784 •813 In every year, then, notwithstanding the great irregu- larities presented by Mr. Glashier s curves, the mean hourly amount of rainfall was less during those periods of the day when the declination magnet was in and near its mean position than during the periods when it was at and near the extremes of its daily oscillations. A valuable series of bi-horary observations of rainfall was made at the Lisbon Observatory during the nine years 1856-64, the results of which are given in the first and second volumes of the Annals of the Observatory. The mean annual bi-horary amounts of rainfall were as follows • h. h. mm. h. h. mm. 0 to 2 55-9 12 to 14 65-9 2 „ 4 68-1 14 16 81-5 4 „ 6 57*3 16 18 75-3 6 „ 8 62*4 18 20 77*5 8 „ 10 61*3 20 >> 22 68-4 10 ,,12 62*8 22 24 52*3 115 The mean hourly rainfall is 32*86mm. A principal mininum takes place during the two hours immediately following the passage of the magnetic needle through its mean position in the forenoon, namely from 22h. to 24h. ; and a secondary minimum during the two hours imme- diately preceding the afternoon passage, namely from 4h. to 6h. The mean amount per hour during these fnur hours is 27’40, or 5* 46 below the general mean. Taking the two hours before and the four hours after each passage the mean hourly amount for these twelve hours is 29 ‘80, while the mean hourly amount for the remaining twelve hours is 35*92. It appears, therefore, that at Lisbon, as well as at Green- wich, the curve of daily rainfall has two maxima and two minima, the times of minima corresponding with or very closely following those when the declination magnet is in its mean position. The six consecutive hours of greatest rainfall, both at Greenwich and Lisbon, are from 14h. to 20h. The twelve consecutive hours of greatest fall are from 9h. to 21h. at Greenwich, and from lOh, to 22h. at Lisbon. During this period the north end of the declination magnet is to the east of its mean position, and the wind passes through its phase of minimum velocity. Comparing the amounts of rain which fall at both Green- wich and Lisbon during the two maximum and the two minimum periods of the day we have the following results : s Amount at Green- wich. Mean Hourly Amount Ratio to Mean Hourly Amount for the Entire Day. Amount at Lisbon. Mean Hourly Amount Ratio | to Mean Hourly Amount for the Entire Day. h. h. in. in. mm. mm. 1 1 1st max 1 to 5 2-879 •719 1-19 124-7 31-17 0-94 1st min 5— 9 1-953 •488 0-82 121-7 30-42 0-92 2nd max 9 — 20 6-982 •634 1-06 393-65 35-78 1-08 2nd min 20—1 2-434 •483 0-82 148*65 29-73 0-90 From the numbers in columns 5 and 8 it will be seen 116 that the difference between the relative amounts in the different periods at the two stations is greatest in the first period and is almost inappreciable in the third; while in the second period it is very nearly the same as in the fourth. During the eleven hours of the third period the fall of rain at both stations is almost exactly half the amount for the entire day, the exact proportions being for Greenwich *490, and for Lisbon, *499. At some of the Russian meteorological observatories measures of rainfall have been taken twice daily — generally at 8 a.m. and 8 p.m. ; and at several of these stations the same law of distribution prevails as at Greenwich and Lisbon, namely, the fall of rain during the night exceeds that of the day ; but at others the day amount exceeds that of the night. Thus at St. Petersburg and Sitka the amounts are 8 a.m. to 8 p.m. 8 p.m. to 8a.m. Inches. Inches. St. Petersburg 6 '090 * 7*945 Sitka 36*618 43*976 while at Bogoslovsk, Lougan and Tiflis they are as follows : — 8 a.m. to 8p.m. 8 p.m. to 8 a.m. Inches. Inches. Bogoslovsk 8*071 6*962 Lougan 8*368 5*388 Tiflis 10*833 7*601 It seems probable, from the results of the above discussion of the Greenwich and Lisbon observations, that in the cases in which the amount of rainfall during the day period exceeds that of the night, the excess will be found to be due not so much to a diminution in the maximum of the night as to an increase in the maximum of the day. It is, however, very desirable that this point should be deter- mined by observations made at suitable hours for a period of not less than a year ; and that the atmospheric conditions upon which the difference between the day and night amounts is dependent should be ascertained. U7 “ Result of Rain-Gauge and Anemometer Observations made at Eccles, near Manchester, during the Year 1868,” by Thomas Mackereth, F.R.A.S., F.M.S. The following amounts of rainfall are obtained from two gauges 8 feet from the ground and 145 above mean sea level, and one gauge 84 feet from the ground. One of the lower gauges has a round receiver lOin. in diameter, the other has a 5in. square receiver ; the edges of both are turned inward. These two gauges stand close to each other, 75 feet from my house or any building, and free from every obstruc- tion. The higher gauge has a 5in. square receiver, like the one near the ground. It is 4 feet above the ridge of my house and free from every obstruction. First I represent the rainfall for 1868, as measured by the lOin. gauge. This I have compared with the average fall for 8 years at Eccles. Quarterly Periods. 1868. Fall in Inches. Average of 8 Years. Differ- ences. I Quarterly Periods. Average of 8 Years. 1868. Average of 8 Years. 1868. Days Days in. in. \ J anuary 2-995 2-650 +0-345 7 51 63 ] February 2-228 2-247 —0-019 [ 7-614 8-936 l March 3-713 2-717 +0-996 3 c April 1-472 1-918 —0-446 7 43 36 < May 0-980 2-081 —1-101 $ 6-598 3-122 l J une 0-670 2-599 —1-929 3 c July 0-441 2-951 —2-510 7 50 36 < August 3129 3-269 —0-140 £ 10138 5-423 ( September 1-853 3-918 —2-065 3 r October 4-998 3-723 +1-275 7 56 73 j TVovember 2-719 3-302 — 0583 V 10-366 15-441 December 7-724 3-341 +4-383 200 208 Totals 32-922 34-716 —1-794 This table shows that though the Spring and Summer months were so exceedingly dry, yet the rainfall for the year was only about 1 Jin. below the average fall of 8 years. The wettest months, as is usual, were at the beginning and end of the year. In this respect the rule of rainfall for this dis- trict was not departed from. The departure from rule is to be found in the rainfall of the Summer and Winter months especially. The one in its deficiency, the other in its excess. 118 The next table shows the monthly amounts that fell in each gauge, and the number of miles of horizontal move- ment of the air. 1868. Rainfall in lOin. round , gauge, 3 feet from ground. Rainfall in 5in. square gauge, 3 feet from ground. Rainfall in 5in. square gauge, 34 feet from ground. Amount of horizontal movement of the air in miles. J anuary 2-995 2-987 1-941 5,942 February. 2-228 2-149 1-717 6,359 March 3-713 3628 3-007 4,754 April 1-472 1-402 1-142 2,749 May 0-980 0-919 0-758 2,626 June 0-670 0-625 0-506 1,671 July 0-441 0-398 0-400 4,157 August 3-129 3-036 2-693 5,038 September 1-853 1-824 1-603 4,130 October 4-998 4-965 4162 4,335 November 2-719 2-762 2137 4,356 December 7-724 7-813 6-460 6,148 32-922 32-508 26-526 52,265 This table, like the one I read to this Section of the Society last year, shows that the greatest horizontal movement of the air happens in the Winter months, or from about Sep- tember to March. It likewise shows, what I pointed out last year, that an excess of windy weather in any month is nearly always attended with an excess of rainfall. In the next table I have given the average daily fall of rain in each kind of gauge, and the ratio of the amounts, when the velocity of the wind has ranged between the number of miles indicated in the first column. Daily movement of wind. No. of days on which rain fell. 3 feet from the ground. 34 feet from the ground. Difference between A and b. Ratio of b to A. 5 inch square gauge. A 5 inch square gauge. B Miles. In. In. In. 0 to 50 14 '114 •106 •008 •929 50 to 100 36 •117 •105 •012 •897 100 to 150 44 •126 •105 •021 •833 150 to 200 39 •159 •142 •017 •893 200 to 250 36 •184 •147 •037 •798 250 to 300 19 •181 •139 •042 •767 300 to 350 9 •212 •161 •051 •759 350 to 400 5 •155 •094 •061 •606 Above 400 6 •332 •196 136 •590 Mean 200 to 250 23 •175 132 043 •785 119 This table shows what a similar one did last year, that rainy days are most numerous when the horizontal move- ment of the air 34 feet above the ground is about five miles per hour, though the heaviest falls of rain happen as the movement of the air increases. Last year I lound the mean difference of the rainfall 84 feet from the ground, and three feet from the ground to be -032 inch per day. This year the mean difference is *043 inch. But like last year this difference increases as the horizontal movement of the air increases. Below I represent the rainfall during the day time of each month, or from 8 a.m, till 8 p.m. ; and the rainfall during the night of each month, or from 8 p.m. till 8 a.m. 1868. Rainfall, from 8a.m. to 8p.m. Rainfall, from 8 p.m. to 8a.m. Difference between Night and Day Fall. Inches. Inches. Inches. January 1-629 1-358 — 0271 February 0-659 1-490 + 0-831 March 1-427 2-201 + 0-774 April 0-622 0-780 + 0-158 May 0-785 0-134 — 0*651 June 0-532 0-093 — 0-439 July 0-162 0-236 + 0-074 August 1-773 1-263 — 0-510 September 0-540 1-284 -J“ 0'744 October 2-833 2132 — 0-701 November 1-085 1-677 + 0-592 December 3-570 4-243 + 0-673 Sums ............ 15-617 16-891 + 1-274 The a/bove table is the first for a whole year that I have had the means to prepare. No special rule appears to be manifest from it as to the excess of the night rainfall over the day fall. The greatest part of the excess, however, appears to fall in the colder months of the year. In the following table I represent the rainfall for 1868 at the Salford Town Hall. The gauge is a 5in. square one, 7ft. from the ground and 105ft. above the sea. 120 Quarterly Period. - 1868. Fall in Inches. Fall at Eccles. 5in. Square Gauge. Difference from Eccles. Days. Days at Eccles. January 2-928 2-987 — -059 62 63 .February ...... 2-148 2149 — -001 March 3-786 3-628 + -158 April ............ 1-370 1-402 — 032 43 36 May 0-768 0-919 — -151 June ............ 0176 0-625 — -449 July 0-499 0-398 + -101 34 36 August 2-359 3-036 — -677 September 1-906 1-824 + -082 October 4-770 4-965 — -195 72 73 November 2-631 2-762 — -131 December 7-707 7813 — -106 211 208 Totals ......... 31-048 32-508 — 1-460 121 Ordinary Meeting, February 9th, 1869. Edward Schunck, Ph.D., F.R.S., &c., Vice-President, in the Chair. Mr. Walter Whitehead, M.R.C.S., was elected an Ordinary Member of the Society. “ Remarks on the term Commerce , and on the Sources of Wealth/’ by J. C. Dyer, Esq., V.P. It may be useful to offer a few words on the common acceptation of the term Commerce , as taken to signify in itself a source of wealth, but which, if rightly interpreted, will be found to convey no such meaning ; because we find that all transactions of a commercial or trading nature are distinct from the creation or origination of material wealth of any sort, notwithstanding which it is continually asserted as an admitted fact, that the vast accumulations of wealth in these Islands, is due to the enormous expansions of our National “ Trade and Commerce.” Now what are the opera- tions of the merchants and traders, except those concerned in aiding and carrying into effect the transfers of the com- modities dealt in from one ownership to another, or from one place to another ? But these transits create nothing de novo. They may, and generally do, add to their market value, which becomes wealth to the owner, or new owner of them ; but this merely proves the excessive production of the goods in one place beyond the local consumption to such extent as to oblige the producer to pay for their transit to the place of their scarcity, and to obtain from thence some Proceedings — Lit. & Phil. Society.— Vol. Till — No, 10. — Session, 1868-9, 122 of the productions found to be in excess of the local wants there, and which return goods can be used or disposed of in the sender’s t)wn country or vicinity. In such cases, the merchant and his ships, or the travellers for orders and local carriers, are thus employed from necessity , for such produc- tions could not go on without those expensive and circuitous means of sales and exchanges of merchandise. The like necessity creates the small traders or shopkeepers, being the general medium through whom consumable goods find their way from the producers to those who require them for use. This medium, though costly, is indispensable, to the continu- ous production of the wares distributed by retail dealers, but they create nothing de novo. It is true that the profits of the merchants and traders are. often such as to leave wealth in their hands, in return for their talents and labour, beyond the expenses incurred by them as carriers, and thus clear gain or wealth is obtained and may be accumulated ; but those gains for their services in helping forward the needful exchanges of production are no more creatives of wealth than are the fees received by the doctor or the lawyer ; the one for preserving our health, the other for protecting our property. In one sense it may seem too trivial thus to draw these nice distinctions between the actual producers of wealth and its necessary distributors; that is, between the tool and machine maker, manufacturer and farmer on the one hand, and the merchant ship owner and carrier on the other ; still it must be of use in reasoning upon such questions, as the causes that lead to the growth or decay of wealth in a state, to have them, if possible, clearly set forth. Hence the terms employed in treating of them should be free from ambiguity or looseness of construction. I would by no means call in question the value or real im- portance of trade and commerce to a state, still it seems expedient to guard against the too common fallacy of citing them as the source , in place of being merely effects of the 123 redundant creations of wealth by the entire community. Whenever wealth does accumulate in a nation, the annual production of it must, to that extent, be in excess of the entire consumption by its people ; and this after defraying all costs of its distribution or trading costs. It is not the sum of wealth produced, but its surplus over consumption, which decides the question as to whether a nation gains or loses in respect to its national wealth. For example, the aggregate products from the land and labour of India , with her 150 millions of people, must be enormous, and yet India is a poor country, because the productions of her people are barely sufficient to feed, clothe, and lodge them in a sta- tionary condition. In fact her wealth has been declining for ages past, by natural decay, because of the near balance between the production and consumption of her people. I here pass by the causes of limited production, as also those of their high cast appropriation, so destructive to all classes. Whilst on the other hand the produce of a small state or community may far exceed its consumption, and thus become a rich state, by reason of the continually ac- cumulating surplus which becomes, in some way, fixed National Wealth. Whether it be placed in a useful form or not, will of course depend on the wisdom or folly of the rulers or guides of public opinion. With respect to Com- merce, it is evident that if the foreign consumers of our surplus — say of cotton goods, woollens, hardwares, potteries, and the like, would bring to our doors the produce of their land and labour, and take back, in exchange, the same goods that they now accept from us, when sent at our ex- pense to their doors, we should, in such cases, be gainers to the extent of the merchant’s charges and profits over and above the present trade profits in our dealings with foreign customers: In all cases the articles purchased by us — such as food and raw materials — whether brought to our doors or sent for from the places of production, would always be 124 such only as we require for use or sale ; and our sales, as now, would consist of such things as are wanted abroad. Therefore our boasted “ commercial profits” are actual draw- backs from those profits on our productions which they would yield in the above supposed case. In fact, an expense which nobody would incur but as the means of selling his goods in the best market. Thus we may freely admit the necessity of this expense, and submit to it as an evil, but only to avoid the greater evil of not selling our goods at home except by greater reductions in price of them than the cost of the exports. The cases above put are so self-evident that it may seem impertinent to offer them in the way of causes and effects in relation to the sources of wealth, yet they will not be found irrelevant upon a careful enquiry into the actual fountains from whence our vast accumulations of national wealth have, in recent times, so rapidly sprung. The wealth and the population of Great Britain remained almost stationary during nearly all of the 18th century, but towards the close of that and in the first quarter of the present century the spirit of industrial enterprise began to spread its influence over the whole face of society. This spirit had its rise in and was mainly fostered by the great inventions and discoveries — mechanical and chemical — -then gradually beginning to unfold their mighty powers, destined to be so widely subjected to man’s will, and to become sub- stitutes for his feeble handicrafts, through so many branches of labour, for supplying the wants of society, which we have since witnessed. To duly appreciate the vast importance of employing these new powers, we must look back to the difficulties that were to be met with and overcome by the chief leaders, in rendering them subservient to man’s uses, namely, to James Watt, to Richard Arkwright and Jede- diah Strutt, to Robert Fulton, and a few years later to the elder Stephenson. These men were truly the pioneers in 125 those movements that have since changed the face and structure, as it were, of society throughout all of the civi- lised nations. I shall not here enter into any of the details of the succes- sive inventions and discoveries that followed in rapid succession those above referred to, but merely notice some of the marvellous effects resulting from them, on wlmt we call trade and commerce. It would indeed be a very important work, for anyone competent to the task, to give a succinct account of the many great inventions and improve- ments that have come into use since those above mentioned. It would however require far more time and space than in a casual paper like this. I venture then to invite my friend Dr. Fairbairn to undertake such a work. I consider him to be more able and likely to do justice to the subject than any other now left among us in this district or else- where that I knew of. The labour of giving even a brief account of them forbids the thought of engaging in it by one of my age, or to attempt making my further contribu- tions towards “A History of Modern Inventions,” than those already made in the several papers read before the society in past years. Nearly all of the tools and implements used in aid of labour remained for many ages in their simple primitive forms, down to nearly the end of last century; when, as before said, the new system of using “power driven machinery'' ’ took its rise, and attracted the enterprise of capitalists. Before that remarkable epoch Great Britain and all the nations of Europe had made but little real progress, either in the increase of her wealth or of population. This progress, too, was greatly hindered by the many wars, im- peding all steps towards advancing civilization. Wherefore the fixed capital of the nation fell far short of the surplus productions over the consumption of the people, the balance being thus squandered in foreign wars. If this continuous waste of wealth had not taken place the entire surplus pro- 126 ductions might have become realised wealth, in some of its useful forms — such as the building of houses, improving lands, highways, and harbours, erecting mills, manufactories, and other industrial establishments, building ships, engines, and the like. In place, however, of any great extensions of such national wealth, a huge public debt was contracted, wherein was absorbed most of the savings of the wealthy classes of the nation, thus not only spending all the surplus creations of wealth of the passing generations but bequeathing a heavy burden to be borne as a drag upon the productive labour of the present and future generations. Let us be thankful that we are not crushed by this weight, and try to avoid the vices and follies of the past, and make better use of our surplus productions in future. It would seem worth while to enquire how it happens that the nation can now sustain such heavy drawbacks from the proceeds of its industry, and yet be able to accumulate wealth so rapidly and in .such abundance as we have seen in these later years. On this question a short retrospect will be useful. The great work of Jacob Leopold — “Theatrum Machinarum ,” published at Amsterdam about 200 years ago (I forget the exact date), contains a full description, with engravings, of all the tools and machines then used or known in Europe. It is curious to observe how few of either kind had been in any essential degree changed , either in their forms or prin- ciples of action before the beginning of the present century; as also how few of them had been superseded by new in- ventions for the same mechanical processes. Then com- menced the new era for employing the power driven machines in place of manual labour, for so many important purposes. We may thus see why a nation, however largely favored by its natural sources of wealth, may continue in nearly a stationary condition for long ages, until some awakening 127 stimulus may call forth its dormant energies, such as were witnessed “in the days of my youth.” In recalling these changes we should keep in view the pervading influence of the new powers of production so rapidly extending of late years, nor fail to look forward to their future effects upon the history of nations. By reason of the countless numbers of engines, machines, and new processes employed, along with our highly skilled labour, this latter being created by the former, the surplus productions of the nation have become so vast as to freight our “ merchant fleets ” to all parts of the world, supplying the nations with our wares in exchange for the productions of their lands and labours. By these mutually beneficial exchanges we may continue to expand our productive powers, and augment our fixed wealth by a wise frugality, for our surplus production of wealth is sure to increase itself \ if not diverted to idle or vicious purposes. A poor nation may abound in natural productions and yet remain poor ; but when surplus wealth aids the arts and skilled labour of its people, they will find means, by the same acts, for its distri- bution by trade and commerce ; neither of which could exist without such surplus productions. We do not build steam engines and ships for consumption, but to enable us to produce and distribute the wealth created by our machinery and skilled labour ; the employment of costly machinery implies the spread of intelligence and skill among all of the wealth creating classes, including alike both head and hand work. No one can fail to perceive the great advances of late years, made in moral restraint and mental culture among the great body of “ operatives ” in this country ; wherefore instead of calling them the “ working classes,” and ranking them as “ mere mechanicals,” we may soon discover that they constitute the thinking classes or portions of society. In great engineering and machine making works, the mental and physical powers exerted are 128 so far blended, often largely combined in the same person, that no line of separation can be made applicable to them, as a whole, the working classes are thus all “ operatives,” and as such they may be taken to constitute a distinct “ order,” and I venture to suggest the propriety of calling this the “ wealth producing order,” and if we are then to rank as of “ the lower orders ” be it so, but I know of no higher order of citizens than those whose productive labours sustain the wealth and power of the nation. In the business of farming, mining, and several kinds of simple mechanical labour, the products are but slightly increased in proportion to the numbers employed, by improvements in such bran- ches of industry, whilst over the wide field of “ power driven machinery ” the products of labour have been in- creased to a vast extent— -say to double, quadruple, ten to twenty, and in some cases even a hundred fold — compared with what the same number of hands could produce if de- prived of the new machines and powers now in general use. In statistical tables besides giving the rates of increase of the population, exports, imports, and the kinds of goods com- posing our foreign trade, &c., with the growing wealth and revenues of the nation, it would be highly instructive to have tables, showing the increasing productive powers of labour realised in our times. Manufacturers and others employing labour would readily afford the data for such tables as to the leading articles of export — -say the money cost of labour for each class of goods. This information would enable us to form sound opinions as to the chances of our continued prosperity in competing with foreign nations in the like branches of industry. We have taken the lead in making and using superior engines and machinery, and with wisdom and prudence in our councils, may hope to keep ahead of other nations for many ages to come, especially as we have now a well trained army of workers, as well as builders of complex mechanisms in sufficient numbers for 129 home service, and to spare many to go abroad and instruct others to follow in our footsteps, without shrinking from a free competition with other peoples. This proves “the ex- pansive force of freedom” thus to protect itself and diffuse its spirit among others without impairing its native force. Besides, we have many natural advantages tending to pro- long our fair ascendancy in many branches of national industry which I would not here attempt to point out. Wherefore we may safely conclude that the onward progress of the wealth and power and the stability of England’s true greatness, along with the freedom and happiness of the British People of all classes , will depend upon the wisdom and firmness of her rulers, in justly appreciating and firmly protecting the wealth* producing classes. The reading of Mr. Dyer’s paper was followed by an interesting and animated discussion, in which Mr. Pochin, M.P., Mr. Hunt, Mr. Binney, F.R.S., the Bev. Brooke Her- ford, Mr. Nelson, Dr. Smith, F.B.S., Mr. Spence, &c., took part. MICROSCOPICAL AND NATURAL HISTORY SECTION. February 1st, 1869. J. B. Dancer, F.R.A.S., President of the Section, in the Chair. Dr. Alcock exhibited some objects from Australia, lent to him for the purpose by the Lower Mosley Street Natural History Society. They were presented to that Society by Mr. Albert Me. Donald, of Pioneer’s Rest, on the River Mary, Queensland, and consisted of the skull of a native Australian, and a stone tomahawk which had been found in the ground by a neighbour of his, and at Mr. Me. Donald’s request it had been furnished with a proper native handle by one of the blacks. It was a very interesting specimen, as genuine implements of this kind are now very rare in the country, the use of iron having quite superseded them. He also exhibited some of the ordinary weapons of the natives, a shield made of very light wood and painted by a native artist, two war clubs or nulla-nullas (aboriginal name koo thaar), and some boomerangs. He read a few interest- ing particulars relating to the objects from Mr. Me. Donald’s letters. Mr. G-. E. Hunt read a paper entitled “ Notes of the Rarer Mosses of Perthshire and Braemar,” of which the following is an abstract. Three alpine regions in Scotland stand pre-eminent for the variety of their cryptogamic flora; 1st, Ben Lawers in 131 Perthshire, with the adjoining peaks ; 2nd, the Clova dis- trict in Forfar ; 3rd, Braemar. All these were long since searched by able botanists, as Hooker, Gardiner, Drummond, Wilson, Arnott, Greville, and others, but such is their rich- ness that a year hardly ever passes without some discovery. There are several causes for this richness, viz., elevation, moisture of climate, and nature of soil. Ben Lawers is the highest mountain in Perthshire, and attains an elevation of 3,984 feet above the level of the sea : its lower slopes consist of extensive moors, interspersed with peat bogs, which are the favorite abodes of various species of Sphagnum, Splachnum, Dissodon, Bryum, Mnium, and Hypnum. Its upper portion is composed of micaceous schist ; there it is that most of the great treasures of the mountain lie concealed — some of the species grow on preci- pitous ledges of rock, others in deep crevices, and others again on grassy turf, The additions of the last four years to the British flora from this ground are sufficient to attest its richness, viz : Tortula fragilis, Leskia nervosa, Mnium spinosum, Hypnum sulcatum, Timmia megapolitana, „ Bambergeri. Neither the preceding species nor the following, viz., Hyp- num plicatum, H. cirrhosum, H. Oakessii, discovered at dates varying from 1823 to 1850, have yet been found in Britain elsewhere than on Ben Lawers. Altogether about 180 species of mosses have been recorded from this mountain ; and when those of the woods, rocks, and walls round its base are added, the total of species for the district will amount to about 300. In Braemar the character of the soil completely changes, and with it the vegetation. The valleys and lower ridges are principally composed of slaty rocks; the higher moun- tains of the Cairngorm range of granite. In the valley Dr. Dickie has been fortunate enough to discover, on the 132 decayed wood of dead fir trees, the very rare Buxbaumia indusiata, and he gathers the other species, B. aphylla, at a somewhat higher level, on debris. The moors, streams, and rocks of Glen Callater and Loch Kandor are notable for their rarities, conspicuous among which stand Audreoea falcata Hypnum dilatatum Grimmia at rata „ arcticum Tetraplodon augustatus Mielichoferia nitida The latter species is specially interesting from the fact of its having been re-discovered, in 1868, by Messrs. Fer- gusson and Boy, in the same station when, in 1830, a single tuft had been found by Dr. Greville. The only other British locality is above Ingleby Greenhow, in Yorkshire, where Mr. Mudd (now of the Botanic Gardens, Cambridge) col- lected it in 1862. Ba-mac-dhui, the loftiest of the Cairn- gorm range, produces several very rare species abundantly, viz. : — Polytrichum sexangulare Dicranum arcticum Sch. (D. Audreoea nivalis Starkii /3 molle Wils) ,, grimsulana Hypnum molle Dicks. The last-named species was, until very recently, almost unknown to botanists generally, and is still, as regards its synonomy, enveloped in considerable doubt. Short as the preceding sketch is, it will suffice to show the great difference between the micaceous mountains of Perthshire and the slaty and granitic ones of Braemar. Either region will richly repay the naturalist who may devote his time to its exploration, whilst the scenery around him must excite his intensest admiration, and of itself will amply repay him for a visit. Mr. John Watson exhibited upwards of 200 drawings from slides sent by him to Mr. Tuffen West, hereafter to be lithographed with others for his intended treatise on the 133 plumules (so called) of the Lepidoptera ; they were princi- pally of the Pieridse family, all being drawn by the camera to one magnifying scale of 350 times linear measurement. He also showed a number of these insects which yield the plumules, and drew attention to their similarities and differences ; noticing that some butterflies, closely allied in all other respects, display corresponding but distinctive resemblances in this also, while others as nearly allied possess very different forms of plumule ; and that the size of the insect does not govern the size of the plumule, some large species having small plumules, and some small species having large plumules; some striking examples of these facts were exhibited. About 30 species of the insects them- selves, with drawings of their own plumules placed by their side, afforded an easy mode of observation of the marvel- lously varied types of form displayed in these curious scales. Besides the drawings of the Pieridse family were a few of the Danaidse (Genus Euploea) and Nymphalidse, and Mr. Watson expects to exhibit shortly a large number of drawings from these families, and from the Heliconidse, Satyridm, and Lycsenidse. He drew attention to some hair- like scales tufted at their apex, which occur on some species of the Genus Argynnis (to one of which he had previously alluded in his last paper), and showed drawings of them side by side, with the true plumules and specimens of the insects themselves, from which both were taken. Whether or not these hair-like scales possess value for the determina- tion of species is at present uncertain, but there can be no doubt of the plumules wherever found in all genera serving for that purpose. The feathery tip of the plumules is very fragile, more so in some species than in others : slides are often covered with the debris : the drawings cannot represent their natural luxuriance in life. 134 Mr. John Barrow read the following note "On a Com- parative Analysis of English and Aleppo Galls.” When Mr. Sidebotham brought before the notice of this Section the subject of the large increase in the production of galls upon the oaks of this country, he expressed a' wish that some member would make an analysis of them so as to confirm his experiments as to their value. I requested Mr. Watson Smith, F.C.S., who is at present engaged in my laboratory, to undertake this task, and have pleasure in submitting to the Section his results. In order to make the analysis of practical value I suggested to him that he should examine both the English and Aleppo galls, and he has therefore experimented on the best sample of Aleppo galls I could procure, and English galls obtained fresh from Cheshire. The process used in both cases was that of Pelouze, viz. by crushing with ether; and although this process is not absolutely accurate, it is the best one that Mr. Smith or myself could discover. The results are Aleppo Galls. English Galls. Gallo-Tannic acid ..... 61-65 .. .... 26-71 Gallic acid .... 1-60 .. Woody fibre ..... 15-68 .. .... 47-88 Water ..... 12-32 .. .... 20-61 Colouring matter and loss. ..... 8-75 .. 100-00 ft—* o O o ob o o Probably more gallic acid would be found if the galls had been gathered a longer time. This analysis confirms Mr. Sidebotham’s opinion of the value of the English galls, but does not make them quite as valuable as he puts them. 185 Ordinary Meeting, February 23rd, 1869. R. Angus Smith, Ph.D., F.R.S., &c., Vice-President, in the Chair. Mr. Robert B. Smart, Surgeon, was elected an Ordinary Member of the Society. The Rev. William Gaskell, M.A., was elected a Vice- President of the Society. Mr. E. W. Binney, F.R.S., F.G.S., said the most remark- able rise and progress of a trade in modern times was that of petroleum. Twelve years ago the article was almost unknown as an article of commerce. In 1861, according to the trade circulars, the export of it from the United States was 1,194,682 gallons, while in 1869 it reached 99,148,947 gallons. The daily produce of the wells of crude oil for the last year has varied, at times falling to 9,000 barrels, and at other times rising to 13,000. The average daily production for the year may be put at 10,200 barrels. The home con- sumption in America must be immense, but it is not given. In 1843, when he read a paper before this Society, show- ing that petroleum could be produced from the decomposi- tion or rather distillation of peat at a low temperature, little was known of the origin or utility of this product. This . paper, was not printed in the Transactions of the Society. In the minutes of the meeting of 3 1st October, 1843, is the following entry, “ Read a paper by Mr. E. W. Binney, entitled ‘An Account of the Petroleum found in Down- holland Moss.’ ” This paper having the name of Mr. W. H. Proceedings — Lit. & Phil. Society. — Yol.YIII— No. 11. — Session, 1868-9, 136 Talbot, who had assisted him in making the bores and ob- taining considerable information respecting the moss, asso- ciated with it, was printed with the Annual Report of the Manchester Geological Society for 1843. After describing at length the beds of peat and the deposits of silt dividing them, the authors conclude, 10-385 4-714 —5-671 ( Sept. .. 1-760 3-230 —1-470 io 3 c Oct ... 4-505 3-827 -j-O-678 24) 49 68 < Nov... 3-108 3-475 —0367 15 c 10-615 15-736 4-5-121 l Dec . . . 8123 3-313 4-4-810 29 ) 188 188 32-225 35-403 —3-178188 35-403 32-225 —3-178 161 Ordinary Meeting, March 23rd, 1869. The Rev. William Gaskell, M.A., Vice-President, in the Chair. E. W. Binney, F.R.S., F.G.S., said that he was sitting in his dining room, Spring Bank, Crumpsall, reading at the time he felt the earthquake on the loth instant. The height of his house above the sea would be about two hundred and forty feet, and the drift deposits underlying it consist of fifty feet of sand and about the same thickness of till or brick clay resting on the pebble beds of the trias. His sensation of the shock was as if the bed in the room over him had been drawn from east to west, and immediately afterwards the chair in which he was sitting on the west side of the room moved as if the foundations of the house were giving way. The shock did not last more than a second. The windows in the house rattled, but no one in it besides himself noticed the occurrence, which took place about nine minutes past six p.m. The feeling he experienced at the last, of the foun- dations of the house appearing to give way was extraordinary, but the other sensations felt would not have attracted his attention, and he is of opinion, that very few people in the neighbourhood of Crumpsall would have known it to have been the shock of an earthquake had they not been told, or seen it described in the newspapers of the following morning. He is convinced that the shock would be felt much stronger in those houses which were built upon the pebble beds at Cliff Point, in Lower Broughton, as was the case at the residence of our president, Hr. Joule; the vibrations of the bare rock being very different there from what they Peoceedings — Lit. & Phil. Society. — V ol. YIII — No. 13. — Session, 1868-9. 162 would be where it was covered with one hundred feet of plastic clay and soft sand, at Crumpsall. As far as he has been able to learn, the shock appears to have been felt in an east and west direction between Hudders- field and Manchester, and from Stockport to Burnley along the line of the pennine chain, which forms the high land of Lancashire and Yorkshire. The tract of land lying betwixt the two great dislocations of the earth’s crust in the neighbourhood of Manchester, running nearly parallel to the pennine fault, namely, those of Smedley and Clayton, and the Great Irwell faults, dis- placements of the strata to the extent of between three and four thousand feet, would lead us to expect that any dis- turbance of the earth’s surface would be felt with greater intensity between those two great lines of fracture. Now Smedley Hall and our President’s residence at Cliff Point both lie in this tract, and being placed on or near the solid rock, the vibrations would be much more jarring and severe as was he believed the case at both places, than where he r (Mr. B.) felt them at Crumpsall, on a thick cushion of clay and sand. Mr. Spence stated that he and several members of his family also felt the shock on the 15th instant, at his resi- dence, Smedley New Hall, and that it was accompanied by a loud noise as if a heavy package had fallen on one of the chamber floors. The following communication from Mr. T. T. Wilkinson, F.R.A.S., was read : — A very smart shock of an earthquake was felt at Burnley on the 15th March, 1869, at about 6h. 8m. p.m. I was standing in my room at the time with my face to the S.E., and was startled by a rumbling sound behind me. It ap- peared to pass from about N.W. towards the S.E., or almost exactly in the plane of the magnetic meridian. At first I imagined a wall was falling down in the next apartment ; 163 but in an instant I was thrown forwards — then came a vio- lent tremor — and lastly a settling back into my original posi- tion. The duration of the shock was not more than four or five seconds. On making inquiry I found that many others had experienced similar sensations, and that much alarm had been created by the shock. In some of the mills the looms appeared to be heaved up — doors were displaced — and the more delicate machinery thrown out of gear. House bells were set ringing, and the crockery rattled as if about to fall from the cupboards. The dogs howled as if in alarm — the canary-birds fluttered about in their cages — and several horses refused to move on for some time after the shock. In the higher parts of the town the walls of the houses swayed to and fro, and now exhibit cracks ; and the twist split a strong supporting beam in one of the shops in Manchester Road. The stalls in the open market were much shaken ; and one of the hucksters ran round his can- vas with the intention of catching the youngster who was playing him a trick. So far as I can judge, the magnitude and duration of the shock were very similar to those in the earthquake which passed through this district in July, 1839. Professor Roscoe, F.R.S., reported to the meeting the important discovery made by MM. Graebe and Liebermann, of the artificial preparation of alizarin, the colouring matter of madder, from anthracene or hydrocarbon found in coal tar. It appears that the formula given for alizarin many years ago by Dr. Schunck, viz. C14H10O4, corresponds closely to the composition which the substance is now found to possess, viz., C14H804 We are as yet unaware how alizarin is obtained from anthracene C14H10. The artificial colouring matter appears to possess all the properties of the madder alizarin, and the ordinary mordants yield the well known colours in every respect identical with those obtained in the well known processes of madder dyeing. The importance of this discovery can hardly be over estimated. 164 The following communication from Mr. J. C. Dyer, Honorary Member of the Society, was read : — • The extensive knowledge of the economical sciences, and the eminent talents, of Professor Jevons, give to his opinions the highest authority on the several questions treated in my two papers, to which the Professor referred, at the last meeting of the Society, as given in the proceedings of the 9th. I am very glad to perceive that Professor Jevons “ concurred generally with most of the remarks ” in those papers, whilst protesting against some of them concerning Free Trade. In tendering my thanks for the concurrence of his views as therein expressed, I trust he will not take it amiss that I now submit a few words, in explanation of my application of the terms — “ Free Trade, viz., that the principles of Free Trade “were not consistent with the existing imposts referred to.” Those principles, if adopted in practice, would apply alike to our domestic trade and manufactures, as to the importations from other countries; “taking the case, stated by Professor Jevons, that the Customs and Excise Duties — on some twelve articles — raise nearly two-thirds of the Revenue the present Revenue, as given for the year 1868, is over seventy- two millions, and two-thirds of this sum, say £48,000,000, would leave the sum of four millions per month as taken mostly from the producing classes, and applied to the public expenditure. Such a constant with- drawal from the surplus wealth of the country must greatly impede our wealth- creating powers ; and thus far at least those taxes are in violation of Free Trade principles. In fact, those principles are set aside just as much in the cases of taxing Tea, Coffee, Sugar, Molasses, Malt, Tobacco, and Snuff, as they are by “ the small remaining duty on corn.” It would be a great benefit to the middle and working classes if the taxes were remitted, and free production and consumption allowed, as to the articles above-named. 165 The policy of Free Trade in those articles is quite a different question, and one far too large to he here treated. The substitute suggested in my last paper, may or may not he the hest to he adopted ? It is sound in principle, and may yet he deemed expedient in practice some thirty or forty years hence. I have lived to witness even greater changes in the national mind, and in the policy of the Government, than that anticipated from raising the public revenue mainly by a direct tax on realised wealth. MICROSCOPICAL AND NATURAL HISTORY SECTION. March 1st, 1869. [Continued from page 155.] “Remarks on the Flora of Cheshire; with Notices of the New and Rarer Plants of the County,5’ by Mr. Spencer Bickham, Jun. The following list of Cheshire plants includes such species as have not hitherto to my knowledge been recorded as occurring in the county, or, if noticed, the station has not been verified for some years ; as well as new localities for some of the rarer species. Teesdalia nudicaulis. This species formerly grew at Bowdon, 15 years ago, and is recorded in the Manchester Flora as existing on Knutsford racecourse, but I have not noticed it for some years in either situation. It grows in the greatest profusion on banks about Delamere. Draba verna, var. brachycarpa, grows on banks at the east end of Oakmere. The normal form of this species is far from common in this district, and I am not aware of the var. brachycarpa having been before recorded. 166 Camelina sativa has been very rarely met with in this neighbourhood. It is often imported with flax seed and has no claims to be considered even naturalised in any part of our island. I found it in July last, in considerable quantity, in a field at Bowdon. Saponaria officinalis grows on the road side just under Delamere church. Cerastium aquaticum occurs near Rostherne. It covers the bramble bushes with its angular, long and straggling stems which are dichotomously branched, and on the upper portion of the plant very viscid. Cerastium arvense. This is a rare plant in the county; I discovered it in several places round Oakmere, on the sandy hedge banks, in the lanes leading to the lake. Hypericum elodes, Fish pool, Delamere Forest. Geranium lucidum I have seen in several places about Bowdon. This species has doubtless escaped from the gardens, having probably been brought with the limestone so commonly used for rock work. Ononis arvensis, occurs in abundance near the edges of a pond, on Dukinfield Hall Farm, Mobberley. Melilotus arvensis , from Timperley, must be looked upon much in the same light as Camelina sativa. Trifolium striatum is marked in the supplement to the “ Cybele Britannica ” as absent from subprovince Mersey. Mr. Watson however informs me that it has since been discovered. I have the pleasure to record its existence on Eddisbury Hill, near the remains of the Saxon camp; it grows among the grass and would not readily be noticed ; it is however plentiful, and has no appearance of being a mere waif. Cicuta virosa. For many years I have looked for this plant in the localities mentioned by Buxton, namely, Buck- low Hill and Knutsford Moor, but have never been able in either station to discover its hiding place. It was only last . .. ... " V season, after repeated visits to the neighbourhood of Mob- berley, that I found it in considerable quantity in the pits or pitsteads near the boundary of Tattoii Park. Pimpinella magna may be again added to our local flora. Owinof to the alteration in the road, it has ceased to exist in Long Lane, Bowden, the only locality given by Mr. Grindon, but I find it in great abundance in the fields by the railway between Knutsford and Plumbley. Galium verum occurs on a sandy bank by the road side between North wich and Delamere; for probably a hundred yards the bank was covered with its golden flowers, for its growth was as luxuriant as I ever saw it, while on the other side of the road, and in the lanes and hedges about, not a leaf of it was to be seen. The nearest station in this district that I know of is Whaley Bridge. Tragopogon porrifolius grows on the railway banks near Chester. It has certainly no claim to be looked upon as a Cheshire plant. Campanula rapunculoides is now quite naturalised in the fields and hedge banks about Bowdon. Doubtless, originally an escape from the refuse of the gardens, its straggling, creeping roots have enabled it to get secure hold on the light sandy soil, and it is year by year becoming more plentiful. In one field alone last season several hundred specimens might have been gathered. Mentha piperita, near Hale, probably possesses more claim to be considered a Cheshire plant, but, although I found it some distance from any house, I look with great suspicion upon it. Scutellaria minor was found on the edge of a small piece of water called the “ Fish Pool,” which lies a little to the south of Oakmere. This plant used to be plentiful on Hale Moss and Lindon Common, but from both of these localities it has disappeared. It is interesting to find that the locality where the specimens came from is mentioned 168 in “Lyson’s Magna Britannia” as being the station for it sixty years ago. Utricularia minor was flowering most freely at Oak- mere in the small ponds made by digging out the peat for fires. It seldom blooms, although found in several places in this district. I have seen it for many years on Hale Moss, but was never able to gather a single flower. By the side of a rivulet near Rostherne the ground was carpeted with Lysimachia nummularia , whose bright-yellow flowers were in great profusion. On stiff soil this species, when once introduced, grows readily, and would probably be much commoner were it not that, like many other creeping plants, it seldom produces seeds. In the higher parts of Cotterill Clough there are some fine shrubs of Daphne Laureola , which was supposed to have been nearly destroyed by the herbalists. I expected to be able to record an addition to our local flora, in Orchis conopsea. I have known of it for some years on Knutsford Moor, where it blooms so freely, that I was first attracted by the scent. I find, however, that it is recorded as growing in the same situation in the work I have referred to. It is singular that neither Buxton nor Grindon have noticed it in this locality. I may state that in the same book the following stations are given for species, which are well worth the attention of botanists. Villarsia nymphceoides , Delamere Forest. This species is not now known to exist in the county. Alisma ranunculoides. Kelsail. Limosella aquatica. Frodsham. Pilularia globulifera. Congleton Moss. Saxifraga aizoides. Beeston Castle. Lathyrus Nissolia. Blaconpoint. 169 Statice reticulata. Hiltree Island. Listera cordata. Stayley Moors. Trollius europceus, in great plenty, in a wood between Stayley Hall and Scout Mill. Galamagrostis stricta. Oakmere is now the only known British locality for this grass ; for although it was formerly found by Mr. Hon in two places near Forfar, it has long since been extirpated by drainage. The plant grows very abundantly on the boggy shore at the north-west end of the lake. I see no probability of its extinction in this locality. Thousands of specimens could have been gathered last June without exhausting the supply. Air a caryophillea and prcecox. Both of these species are found in every county in Britain, and yet neither are common in Cheshire. A. caryophyllea may be considered a rare plant with us ; it is therefore .somewhat remarkable to find such extremely luxuriant examples as those I exhibit. On May 1st, last year, the side of the road near the Abbey Arms Inn, Helamere, was covered for upwards of half a mile with its beautiful silvery panicles ; in less than a month afterwards there was not a vestige of the grass to be seen. Possibly the fact that they fade so soon is one reason they are not more frequently noticed. Festuca pseudo-myurus attracted my attention near the farm entrance to Dunham Park. It differs from the typical form (which I exhibit from Oakmere) in being more slender, and having a very long, attenuated, and drooping panicle. In Cotterill Clough I had the pleasure of seeing Hordeum sylvaticum, for which this has long been named as the only station in our local flora, and of late it was by most supposed to have ceased to exist even here ; it was not abundant, but was flowering very freely. Lycopodium inundatum grows at the edge of the Fish- pool, Delamere, and I also found it on Lindon Common. The last station again adds the species to our Manchester flora, it having ceased for some time to exist at Baguley the place given by Buxton and Grindon. But the most interesting discovery at the Fish Pool was Pilularia globulifera, which was in far greater perfection than usual. It covered many yards of a partly dried-up pond, the edges of which were fringed with equally luxu- riant specimens of Hypericum elodes. Claytonia perfoliata, Anchusa sempervirens (Mons. R. Du Parquet), Saponaria Vaccaria (Mr. Joseph Sidebotham) have all been found in the neighbourhood of Bowdon, but must be looked upon as mere waifs of cultivation. 171 Ordinary Meeting, April 6th, 1869. E. W. Binney, F.R.S., F.G.S., Vice-President, in the Chair. Mr. A. Brothers and Mr. J. S. Kipping were appointed Auditors of the Treasurer’s Accounts. Thomas Alcock, M.D., was elected a Member of the Council, in place of the Rev, William Gaskell, M.A., elected a Vice-President. Professor Edward Frankland, Ph.D., F.R.S., fee., was elected an Honorary Member of the Society. Dr. Joule, F.R.S., gave an account of his endeavours to improve the instrument known as the dip circle , which, notwithstanding what had been done by Lloyd and others, was not comparable in delicacy to the declinometer. The ordinary mode of causing the axis of the needle to roll on agate planes first claimed attention. He found it possible to obtain a steel cylinder of beautiful accuracy as follows : — A steel wire, stretched by a weight hanging from one extremity, being heated to redness, draws out a certain length, and in so doing becomes perfectly straight. The wire is then divided into pieces each about two inches long, which are ground true and then polished by rolling them against one another. If the operation has been care- fully conducted, one wire laid across two others will roll Proceedings — Lit. & Phil. Society.— Vol. VIII — Ho. 14.— Session, 1868-9. 172 noiselessly down an almost imperceptible gradient. The plan of suspension thus indicated appeared better than the use of agate planes, inasmuch as dust and moisture were less likely to interfere with the delicacy of the indications. Nevertheless it was impossible altogether to avoid the effects of these impediments to free rotaton, and the more so as the obstruction to rotation is proportional to the square root of the height of any small particle between the rolling surfaces. In fact, on narrowly watching the periods of oscillation they were invariably found to become sensibly quicker when the arc was very small, showing that the needle was rocking on two points. The suspension by inclined silk threads was then tried, but soon abandoned, as it was found that the violent torsion at the points of attachment could not be certainly allowed for, owing to the viscosity of the threads. The system brought now before the Society was free from the above-named evils. In it each end of the axis of the needle is suspended by a fibre of silk, on which it rolls. Small washers on the axis serve to keep the fibres in a definite position. The ends of the fibres are supported by the extremities of a delicate balance beam, placed at the top of the instrument. Small pins, &c., are used for adjusting the length of the fibres and to regulate the centre of gravity of the beam. The needle itself is a piece of softened watch main spring, sufficiently long to extend completely across the graduated circle. It is seven inches long and weighs 18 grains. A glass plate fastens before the instrument by a notch. By the reflection of the eye of the observer from this glass parallax is avoided, #hile the position of each edge of the needle is read off by an eye-glass to a minute of arc. There is no difficulty in adapting the reflecting system for the purpose of registering minute magnetic disturbances. A sketch of the instrument is appended. “On the Chemical Formula of Alizarine/’ by Edward Schunck, Ph.D., F.R.S., &c. The discovery of a mode of preparing alizarine arti- ficially, lately made by MM. Graebe and Liebermann, and brought before the notice of the Society at its last meeting by Professor Roscoe, is not only of the highest importance 174 from a practical point of view, but is also of great interest as being the first recorded instance of the artificial formation of a natural colouring matter. The formula to which I was led in my examination of the colouring matters of madder, viz., C14H10O4, approaches very closely, as Professor Roscoe observed, to the one now adopted by Graebe and Lieber- mann, C14H804. My formula was not founded on theoretical views, but simply expressed the composition to which my numerous analyses of alizarine and its compounds conducted. I have until now seen no reason whatever to adopt any other, notwithstanding that Strecker’s formula, C10H6O3 has been preferred by most chemists, and was even pronounced by Laurent to be the only one possible. That my analyses do not in the least correspond with the latter formula, but are not inconsistent with that of Graebe and Liebermann, will be seen by a glance at the following numerical results of some analyses of alizarine from various sources : I. II. III. IV. V. Mean. C 69*15 69-37 69-59 69-66 69-73 69-50 H 4-04 4-07 4-26 4-00 3*71 4-01 0 26-81 26-56 26-15 26-34 26-56 26*49 Of these analyses I. was made with material obtained directly from madder, II. and III. with specimens derived from rubian by decomposition with acid and with ferment, IV. with alizarine from rubianic acid (its glucoside), and V. with sublimed alizarine. The three formulse, C14H804, C14H10O4, and C10H6O3, require the following per- centages of C, H, and O : C14H804. c14h10o4. C10H6O3. 0 70-00 69-42 68-96 H 3-33 4-13 3-45 O.. 26-67 26-45 27-59 175 ! It will be seen that my results are not reconcilable with the last formula, whereas in some cases, especially in that of sublimed alizarine, the composition found agrees tolerably well with the new formula C14H804. The great excess of hydrogen found even in the case of well crystallised and apparently quite pure alizarine remains to be explained, and though unwilling to throw any doubt on the complete identity of the natural and artificial product, I confess I look forward with great interest to the full confirmation of this remarkable discovery. The following extract of a letter from Mr. Wm. Rayner Wood, to the Chairman, dated April 3, 1869, was read : — “ Having read the notices of the earthquake of the 15th March in the Society’s proceedings, I think that a state- ment of my own experience may be interesting in connection with them. “In consequence of indisposition, I had gone to bed about half-past five, and was asleep. I was awakened a few minutes past six by a noise which I at first thought was thunder, but which seemed much beyond thunder or any noise I ever heard. My next thought was that a stack of chimneys must have fallen upon and through the roof and successive floors below. I mention these successive thoughts as indications of the violence of the sound and the length of time that it continued. The noise ceased with a great rattle of the window shutters, such as I have never heard in any wind, however high, though I have occupied the same room for five and twenty years. I felt no shock, probably from my being in bed. My servants who were in 176 the house did so. They do not seem to have been much alarmed, but two wives of married servants, who were alone in their own houses with young children, were so much frightened that they had not recovered themselves an hour afterwards. This seems more in accordance with what is stated in regard to Burnley than with your own observa- tion at Crumpsall. My house, as you know, stands three miles north of Manchester, on the old road to Bury. It is situated just at the junction of a bed of clay with a large extent of sand, and in fact the house stands partly upon clay and partly upon sand. There is red rock near the surface about 200 yards north-east of the house/' The earthquake shock was also felt by Mr. Lowe, at his offices in Lever-street ; by Dr. Crompton, at his house, near Fern Acre, Cheetham Hill Road; and by Dr. Schunck, F.R.S., in his laboratory, at Oaklands, Kersal. Mr. Kipping stated that no unusual noise was heard, nor shock or vibration felt, at his house in Kersal Clough. The Rev. Brooke Herford said that some friends of his who were waiting for a train, at the Handforth Railway Station, rushed out of the waiting room, under the impres- sion that the noise and vibration proceeded from a train coming into the station. This he regarded as good evidence that the shock of earthquake was really accompanied by a considerable noise. Professor W. C. Williamson, F.R.S., gave an account of the present state of knowledge in reference to the structure of the gizzards and teeth of the Rotifera. After pointing out the discrepant accounts given by various writers on the 177 subject, including his own examination of the teeth of Melicerta, he showed how all appeared to have failed in decyphering their anomalous appearances with perfect accuracy. He then directed attention to the very successful investigations made by the Rev. the Lord Sidney Godolphin Osborne, respecting the teeth of Rotifer vulgaris, and having not only studied with care his Lordship’s preparations, but also compared them with his own examinations into the same animal, he was prepared to endorse the chief conclu- sions at which his Lordship had arrived. This dental organ consists primarily of two slightly arcuate jaws, broad at their upper extremities and narrow and pointed at their lower ones. Elastic ligaments bind these together at each end. The front or convex margin of each jaw is crenulated, the projections corresponding with the transverse parallel ridges usually regarded as the teeth of the animal. These jaws form the two lips of a sac, the lateral parts of which consist of a separate tissue, which overlaps each jaw at its anterior margin, hooked on, as it were, to the crenulations and thrown by them into permanent parallel corrugations. Each of these corrugated organs passes first outwards and then downwards and backwards, where they are bound together by another broad membrane, which completes the sac posteriorly. The food enters this sac by a passage from the oesophagus, at its superior extremity, is crushed between the two jaws, and then passes out again by a similar orifice at its opposite or lower end to enter the stomach. Of these tissues the jaws are the hardest and are capable of being dissected out, as Lord S. G. Osborne has succeeded in doing. The lateral corrugated organs, have a concavo-convex form, 178 which they appear capable of retaining after dissection; they appear less dense than the jaws, but more so than the membranous tissues of the gizzard, to which they are united. The central corrugations are always the largest. Professor Williamson also called attention to the fact, originally noticed by Leeuwenhok and afterwards confirmed by Spallanzani and others, of the possibility of reviving these animals after protracted desiccation. He exhibited some small glass tanks or Rotiferous aquaria, some of which had been prepared by Lord S. G. Osborne, which had been dried up again and again. One of these, in a dry state as it had been for five months, was moistened by the addition of a little water, and in five minutes the animals were in full activity, looking thin and hungry, but perfectly vigorous. The experiments of Lord S. G. Osborne confirm the state- ments of Spallanzani, that these Rotifers may be dried up for years without vitality being destroyed. Tanks for the preservation and examination of these objects are readily made by joining two ordinary microscopic glasses on three sides by means of electric cement, and then stocked by the introduction of a little Rotiferous dust. In such tanks they multiply rapidly, the occasional addition of a few drops of water to counteract evaporation being all that is needed for their preservation. The above communication was further illustrated by some beautiful models constructed by Lord S. G. Osborne, and kindly lent for the occasion. 179 Annual Meeting, April 20th, 1869. R. Angus Smith, Ph.D., FRS., Vice-President, in the Chair. The following Report of the Council was read by one of the Secretaries : — The Council have again to report that the Society’s finances continue in a satisfactory state; the general balance of the Treasurer’s account on the 31st of March last being £252. 16s. 9d., against £267. 19s. 2d. on the 31st March, 1868, and £250. 2s. Id. on the 31st March, 1867. The number of ordinary members on the roll of the Society on the 1st of April, 1868, was 174, and 7 new members have since been elected. The losses during the year have been— deaths, 3 ; resignations, 7 ; defaulters, 4 ; and one ordinary member elected an honorary member. The number on the roll on the 1st of April instant was therefore 166. The deceased members are Mr. Robert Worthington, F.R.A.S. ; Mr. J. Macfarlane; and Mr, J. S. Perring, C.E. Mr. Worthington for several years filled the office of Treasurer, and discharged its various duties with unfailing care and regularity. He had long taken an active and useful part in other societies besides this for the promotion of literature and science, and the lively interest which he felt in astronomical studies was shown by the erection of his excellent observatory at Crumpsall Hall, which attained a high position among the private observatories of Europe, and has been the means of making not a few important contributions to the branch of science on which his attention was more especially fixed. The Library of the Society continues to receive numerous and very valuable contributions of Memoirs, Proceedings, and other publications of the many learned and scientific Proceedings— Lit. & Phil. Society.-Yol.YIII— No, 15.— Session, 1868-9. 180 societies and public bodies with which the Society is in communication ; and the Council believe that it will soon become necessary to provide additional library accommoda- tion, and to print a supplementary catalogue. The increase in the number of Photographic Societies having outstripped the progress of photographical invention and discovery, it has become very difficult to procure original papers and communications for discussion, and only two meetings, therefore, of the Photographical Section have been held during the session. The Microscopical and Natural History, and the Physical and Mathematical Sec- tions have, however, maintained their usual activity and interest, and their meetings have been well attended. Some of the papers brought before them during the session have been passed by the council for printing in the Society’s Memoirs. The system of admitting Sectional Associates continues to work satisfactorily, and the Council therefore recommend that it be continued during the ensuing year. The following papers and communications have been read at the ordinary and sectional meetings of the Society during the session now ending : — October 6th , 1868.— On Convertent Functions,” by Chief Jus- tice Cockle, F.R.S., &c. Communicated by the Rev. Professor Harley, F.R.S. “On the Rev. T. P. Kirkman’s Method of Resolving Algebraic Equations,” by the Rev. Robert Harley, F.R.S., &c. October 20i th, 1868. — “On Observations of Atmospheric Ozone,” by Joseph Baxendell, F.R.A.S. November Srd, 1868. — “Remarks on Mr. Baxendell’s Laws of Atmospheric Ozone,” by Professor W. Stanley Jevons, M.A. “ On the Structure of an Undescribed Type of Calamodendron from the Upper Coal Measures of Lancashire,” by Professor W. C. Williamson, F.R.S. November 9 th, 1868. — “ A Resume of the More Important Papers bearing upon Microscopical Research which have appeared 181 during the Past Year,” by J. B. Dancer, F.R.A.S., President of the Microscopical and Natural History Section. November 10th, 1868. — “On the Lunar Spot IVA« 17, IVA£ 39,” by Joseph Baxendell, F.R.A.S. “ Observations of the Transit of Mercury, Nov. 5th, 1868,” by J. Baxendell, F.R.A.S., J. B. Dancer, F.R.A.S, and Murray Glad- stone, F.R.A.S. November 17 th , 1868. — -“On the Boiling Point of the Isomers C4H140,” by Professor Gustavus Hinrichs, of Iowa City, United States. Communicated by Professor Roscoe, F.R.S. “ On Measurements of the Chemical Intensity of Total Daylight made daring the recent Total Eclipse of the Sun, by Lieut. J. Herschel, R.E.,” by Professor H. E. Roscoe, F.R.S. December 1st, 1868. — “ Note on Professor Williamson’s Paper c On am Undescribed Type of Calamodendron, from the Upper Coal. Measures of Lancashire,’ ” by E. W. Binney, F.R.S., F.G.S. “ The Hematite Iron Ore Deposits .of Whitehaven : Notes on the Aldby Limestone, Cleator Moor,” by W. Brockbank, F.G.S. December 7th, 1868. — -“Further Notes on Some of the Rarer Plants found near Llandudno,” by Mr. J. Sidebotham. December 15 th, 1868.-— “On Explosions of Fire Damp in Coal Mines,” by E. W. Binney, F.R.S., F.G.S. “Researches on Di-Methyl, Part II.,” by William H. Darling, Dalton Scholar in the Laboratory of Owens College. Communi- cated by Professor H. E. Roscoe, Ph.D., F.R.S. “On a Property of the Electric Current to Control and render Synchronous the Rotations of the Armatures of a Number of Electro-magnetic Induction Machines;” Illustrated by Working- Models, by Mr. Henry Wilde. December ^th, 1868.— “Note on the Organs of Fructification of Calamodendron,” by E. W. Binney, F.R.S., F.G.S. “On War Rockets,” by James Nasmyth, C.E., Corresponding- Member of the Society. January 4 th, 1869.— “ Ceylon : its Climate, Natural History, &c.,” by Mr. C. Heelis of Dimbala. Communicated by Mr. H. A. Hurst. January 5th, 1869. — “On a Diurnal Inequality in the Direction and Velocity of the Wind, apparently Connected with the Daily Changes of Magnetic Declination,” by Joseph Baxendell, F.R.A.S. 182 January 12^, 1869.—' “ Remarks on War Rockets,” by J. B. Dancer, F.R.A.S. “ Has the Human Mind Progressed or Retrograded since the the Time of Augustus 1” by Mr. H. R. Forrest. January 26th, 1869.— “ On the Microscopical Examination of Dust,” by J. B. Dancer, F.R.A.S. “ On the Flora of Gibraltar,” by Mr. H. A. Hurst. February 1$£, 1869. — -“Notes of the Rarer Mosses of Perthshire and Braemar,” by Mr. G. E. Hunt. “ On a Comparative Analysis of English and Aleppo Galls,” by Mr. John Barrow. February 2nd, 1869. — “ Observation of the Occultation of 119 Tauri by the Moon, January 24, 1869,” by A. Brothers, F.R.A.S. “ On a New Anemometer,” by Mr. William Oxley. “ On the Mode of Registering the Force and Direction of the Wind,” by Thomas Mackereth, F.R.A.S., F.M.S. “ On the Fall of Rain at Different Periods of the Day, in con- nection with the Diurnal Changes of Magnetic Declination,” by Joseph Baxendell, F.R.A.S. “ Results of Rain-gauge and Anemometer Observations made at Eccles, near Manchester, during the year 1868,” by Thomas Mackereth, F.R.A.S., F.M.S. February 9i th, 1869. — “ Remarks on the term Commerce, and on the Sources of Wealth,” by J. C. Dyer, V.P. February 23 rd, 1869.— “On the Rise and Progress of the Trade in Petroleum,” by E. W. Binney, F.R.S., F.G.S. “On Sulphurous Acid in the Air of Manchester,” by Peter Spence, F.C.S. “ Remarks on the Nature of Wealth, and on its Uses,” by Mr. J. C. Dyer. March 1st, 1869.— “ Remarks on the Flora of Cheshire; with Notices of the New and Rarer Plants of the County,” by Mr. Spencer H. Bickham, Jun. “ On the Markings on the Pleurosigma Angulatum and on the Lepisma Saccharina,” by J. B. Dancer, F.R.A.S. “Observations on Anguillula tritici, obtained from Wheat of various Harvests,” by Mr. Richard Heys. March 2nd , 1869. — “ On the Rainfall of 1868, at Old Trafford, Manchester,” by G. V. Vernon, F.R.A.S., F.M.S. 183 March 9th, 1869. — “ On the Use of Logotypes,” by Mr. Charles Wilson Felt, of Salem, Massachusetts. Communicated by Pro- fessor Jevons, M.A. “ Additional Notes on the Structure of Calamites,” by Professor W. C. Williamson, F.R.S. March 23rd, 1869. — “ On the Earthquake of March 15th, 1869,” by E. W. Binney, F.R.S., F.G.S., Peter Spence, F.C.S., and T. T. Wilkinson, F.R.A.S. “On the Artificial Preparation of Alizarine,” by Professor H. E. Roscoe, F.R.S. “On Free Trade Principles,” by Mr. J. C. Dyer, March 39th, 1869. — “On Atmospheric Ozone,” by Thomas Mackereth, F.R.A.S., F.M.S. April 9th, 1869.— On a New Dip Circle,” byJ. P. Joule, LL.D,, F.R.S., &c., President. “On the Chemical Formula of Alizarine,” by E. Schunck, Ph.D., F.R.S., Y.P. “On the Earthquake of March 15th, 1869,” by Mr. William Rayner Wood, Mr. Lowe, Dr. Crompton, Dr. Schunck, F.R.S., Mr. Kipping, and the Rev. Brooke Herford. “On the Structure of the Gizzards and Teeth of the Rotifera,” by Professor W. C. Williamson, F.R.S. The third volume of the third series of the Society’s Memoirs has been published, and a considerable portion of a new volume has already been printed. Some of the papers in the above list will appear in this volume. The Librarian reports that the binding of the works in the Library has progressed during the past year, 338 volumes having been newly bound. This matter becomes of increasing importance, not only from the protection thus given to the Society’s valuable Library, but from the necessity of econo- mising space in the already overcrowded shelves, and the Council purpose proceeding with this work as far as* the funds permit. The third volume of the Society’s third series of “ Me- moirs,” just completed, as well as Yols. Y., VI., and YU. of the “ Proceedings,” are about to be distributed to the various 184 learned bodies with whom the Society is in correspondence ; these now number 282, 203 of which are foreign, and 79 British. The various works named in the last annual report con- tinue to be purchased for the Library. On the motion of Mr. W. B. Johnson, seconded by Mr. S. C. Trapp, the Annual Report was unanimously adopted. On the motion of Mr. J. Francis, seconded by Mr. P. Hart, it was resolved unanimously, “ That the system of electing Sectional Associates be continued during the en- suing Session.” The following gentlemen were elected officers of the Society for the ensuing year : — JAMES PRESCOTT JOULE, LL.D., P.R.S., F.C.S., &c. fice-ftmktdA EDWARD SCHUNCK, Ph.D., E.R.S., E.C.S. ROBERT ANG-US SMITH, Ph.D., F.R.S., F.C.S. EDWARD WILLIAM BINNEY, F.R.S., F.G-.S. Rev. WILLIAM HASKELL, M.A. HENRY ENFIELD ROSCOE, B.A., Ph.D., F.R.S., F.C.S. JOSEPH BAXENDELL, F.R.A.S. THOMAS CARRICK. Ihtotmtt. CHARLES BAILEY. pjemtaf oi ifre totuih PETER SPENCE, F.C.S., M.S.A. GEORGE YENABLES YERNON, F.R.A.S., F.M.S. JOHN BENJAMIN DANCER, F.R.A.S. WILLIAM JACK, M.A. WILLIAM LEESON DICKINSON. THOMAS ALCOCK, M.D. p$ m H 03 . • w ^ o £ <1 q o EH F3 (— i O o 02 <1 o M Ph O 02 O l-P o w H 05 CD CO W u ft H EH tfl i— I co o H CO CD 00 W Ph p <1 P3 -© © rH rH 00 rH rH cq © cq io t>» tJH CO 00 t>- rH rH (MtH©© IQ nH 'HH t>- © VOIO*0 © rH rH to rH© ■HH rH co • • • . © © • 5?S S§ w O 5 §< 5> P -ri> g s © « ™ =oP aftcs S\£ ® 2 g< gftfdg 2 gQ^^iPn >5 PQ co 02 +3 ft *3 o o> Ph d q d O •^5 |fi *1 ih ■§ .sh a ?U ^ H ^ d 00 P ft n* fj^OPSH ►» n o i« g »o i. <« ft ft so « ° o S a rig t, ® St S -» oS^t: .§ a) 0,dP-i «m » a _ SS1^ « d >. t.'HS-h •g to ft fee Q g o a cj o •jg bC0-P^j |£h£| >5 PQ 02 bJO .3 "3 (D O O Ph Ph CO 05 CD PO 00 00 C5 | 05 b£ .9 '> d Ph bJD a ro H 02 q ^ bfl c3 bo.S 5° Pd.9 • p P o Isa a o » to aj J g go tSft.S St « 5 -ri> O S9as -Sift'd >i n d d •a .a o - stS to oS ° a ft § bo S3 .SI ftp .a o D2 ■+» . a 03 O *d +2 ..Oft 5v3'pJ tgjs isS-S-s ^PhcoA t>> n o’ a <43 to g ■g as q _q I £« Sm| q td a) Sow ill ft JM § 0h3 o q rS *3 PQ >» PP q cS JZJ S3 § 03 «sS Ph Eh 05^3 PD P 00 % «« CD i>. oo co o o t— 1 O o rH O © © ID •— I co o. o O r3 q q (D fti PP "d o o * & w •• Co - oq ©cq cq ‘O 8 ? rH rH t-H ^ II # to >H * 03 CD • ^ ' 03 ©OO© ©OO© rH rH rH © CO iH © © © t-H © rH ©Dq ©05 rH rH CO +3 rH cS »o Ph rrt d S £ 02 n -y s q ^ qp£- a g a a§g o o„2 ®ft •s-c,- :»ogg S b B A* e« s s g a 0 - Eh * 1 00 St fl ft < as +3 ft g aj'B gP Sft 3-g p -P rq ^*5 St St 41 & co „ ^ © fH © .5 oo r— < Is 8^ l| 02 P3 gp low Ph cu Ph Ph ft d a I'd a . d u <>t o >— i S^_ o d ■H d ® o to a 8 ’w £. O o S>> ^ rd S 8^P eg CO o Eh o § M s>» ft td cu {£ o ft d OQ'O ft!2i M M K& ggg ftW« ^ O o CO cq CO X> o ID ID CO o Cd rH rH r— i rH rH rH rH d ’Sh Ph go © © • rH Ph 03 O HO O o pq PfH O o O © o © oo O 53 « ^ pH pm 3 Td S i Ph to o d o PfH o c3 d P-- d o Ph '"a © r-H Ph «3 m © fcC c3 HO ax O PM nd § Ph O o m O 5H o C+H o m U r“H d © Ph • rH O d • pH d • rH Ph PM M4 O o pq © d cr1 © rd o HO OX HO tn c3 ax O © O Q EH O o O 00 O Ph pq Td o o E. > 00 e? H d d •-o S H w M O HO © © Ph Ph 0 © “T3 d d <8 nd 1 Td © d 1 m « pq w Ph H O i*H FM Ph W W2 O W H £ nd © bo 206 The election of Officers for the session 1869-70 was then proceeded with, and the following gentlemen were declared elected : IPresi&ent. MR. JOHN WATSON. Uicc^restttents. MR. J. B. DANCER, F.R.A.S. MR. JOSEPH BAXENDELL, F.R.A.S. MR. JOSEPH SIDEBOTHAM. treasurer. MR. H. A. HURST. Secretaries. DR. ADCOCK. MR. SPENCER BICKHAM, JUN. Council. PROF. W. C. WILLIAMSON, F.R.S. MR. SAMUEL COTTAM. MR. THOMAS COWARD. DR. SIMPSON. MR. J. BARROW. MR. A. O. LATHAM. MR. CHARLES BAILEY. MR. THOMAS H. NEYILL. Mr. William J. Rideout sent for exhibition one of J. D. Moller’s “ Diatomaceen-Typen-Platte,” the beauty of which was greatly admired. Mr. Rideout promised to present one of these slides to the Section as soon as he could procure one. Mr. Joseph Sidebotham exhibited some fresh specimens of Scilla verna, Myosotis collina, Orchis Morio, and Gera- nium pusillum, collected by himself at Llandudno. l;i & L-i ' ' t I !: . PROCEEDINGS OF THE LITERARY AND PHILOSOPHICAL SOCIETY OF MANCHESTER. VOL. IX. Session 1869-70. MANCHESTER : PRINTED BY THOS. SOWLER AND SONS, RED DION STREET, ST. ANN'S SQUARE. LONDON : H. BAILLIERE, 219, REGENT STREET. 1870. / NOTE. The object which the Society have in view in publishing their Proceed- ings is to give an immediate and succinct account of the scientific and other business transacted at their meetings, to the members and the general public. The various communications are supplied by the authors themselves, who are alone responsible for the facts and reasonings con- tained therein. INDEX. Bailey Charles, Hon. Lib. — On Pollen : considered as an Aid in tlie Dif- ferentiation of Species, p. 51. On the Natural Ropes used in Packing Cotton Bales in the Brazils, p. 88. Baxendell J., F.R.A.S ., Hon. Sec.— On the Influence of Changes in the Character of the Seasons upon the Bate of Mortality, p. 159. On Infant Mortality in Manchester, p. 177. On the Mortality Returns of Scotland for the ten years 1859-68, p. 179. Binney E. W., E.R.S., E.G-.S., Y.P. — On Saxicava rugosa, p. 4. On the Permian Strata of East Cheshire, p. 21 and p. 60. On the Aurora of January 3rd, 1870, p. 55. On Stray Boulders on the Slopes of the Pennine Chain, p. 75. On the High Death-rate of Manchester and Salford, p. 112. Extracts from MS. Journal of Mr. George Walker, p. 151. Calyebt E. Ceace, E.R.S. — On Artificial Alizarine, p. 101. Cockle Sir James, E.R.S. — On Convertent Functions, p. 86. Coward Thomas. — On Podostemacese, p. 36. Cueey J. — On the Hades, Throws, Shifts, &c., of the Metalliferous Veins of the North of England, p. 44. Dancer J. B., F.R.A.S. — On the Microscopical Examination of Milk under Certain Conditions, p. 37. On the Molecular Movements of Micro- scopic Particles, p. 82. On Spores in the Air, p. 111. Dawkins W. Boyd, E.R.S., — On some Old Mining Tools from the Tur- quoise Mines of Sinai, p. 4. Settle Cave Exploration, p. 154. On the Exploration of the Hyaena Den at Wookey Hole, p. 181. Dickinson W. L. — On Three Occultations of Saturn by the Moon, p. 149. On the Eclipse of the Sun, December 21-22, 1870, p. 158. Geeland Dr. B. W. — On Combinations of Phosphate of Lime and Sul- phurous Acid, p, 25. Geeen, A. H., M.A., E.G.S.— On the Nature of the Boundary between the Carboniferous and the Triassic or Permian Rocks of Cheshire, p. 55. Green Beenaed Haetley. — Presents to the Society the MS. Journal of Air. George Walker, one of the original Members, p. 151. Hart Petee.- - Description of a New Anemometer, p. 152. VI Hull Edward, F.B.S. — On the Nature of the Boundary between the Carbon- iferous and the Triassic or Permian Bocks of Cheshire, p. 58. Hurst H. A. — On the Use of the Ordinary Circular Bail way Beading Lamp for Illuminating Microscopical Objects, p. 194. Joule J. P., LL.D., F.B.S. , P. — On an Appearance of the Setting Sun, p. 1. On Disturbances pf Magnetic Dip, p. 55. Determination of the Horizontal Magnetic Intensity, p. 61. On the Progressive Bise of the Freezing Point of a Thermometer, p. 101. Jevons Professor W. Stanley, M.A. — On the so-called Molecular Move- ments of 'Microscopic Particles, p. 78. On a General System of Numerically Definite Beasoning, p. 84. Lund Edward, F.B.C.S. — On the Sources of the High Death-rate of Manchester, p. 114. Mackereth Thomas, F.B.A.S. — Besults of Bain-gauge and Anemometer Observations made at Eccles, near Manchester, during the year 1869, p. 124. Morton E. H. — On the Composition of the Water of the Irish Sea, p. 146. Bansome Arthur, M.D., M.A. — On the Organic Matter of Human Breath in Health and Disease, p. 106. On the Germination and Early Growth of Plants, p. 184. Reynolds Professor Osborne, M.A. — On the Suspension of a Ball by a Jet of Water, p. 115 and p. 133. Roberts William, M.D. — On Cystine Calculi, p. 61. Routledge B. — On the Suspension of a Ball by a Jet of Water, p. 133. Schunck Edward, Ph.D. F.B.S., Y.P. — On Vogelsang and Geissler’s Experiments on the Nature of the Liquids enclosed in certain Minerals, p. 4. On Artificial Alizarine, p. 106. Sidebotham J. — On Varieties in Lepidoptera, p. 112. On Besinous Vapour in Cabinets made of Pencil Cedar, p. 34. Notes on the Pupa and Imago of Acherontia atropos, p. 62. On Pholas-bored Bocks, p. 110. On some Shell Deposits at Llandudno, p. 121. Smith B. Angus, F.B.S., V.P. — On Organic Matter in the Air, p. 65. Spence Peter, F.C.S. — Heating Saturated Saline Solutions to their Boiling Points by Steam at 212°, p. 87. Thomson Sir William, F.B.S, — On the Size of Molecules, p. 136. Thorpe T, E., Ph.D. — On Nontronite, p. 1. On a New Chromium Oxychloride, p. 15. On the Composition of the Water of the Irish Sea, p. 146. Yll Yeenon Gf. V., F.R.A.S. — On the Mean Monthly Temperature at Old Trafford, Manchester* 1861 to 1868, and also the Mean for the Twenty Years 1849 to 1868, p. 46. On the Rainfall of 1869, at Old Trafford, Manchester, p. 123. Watson John. — Address to the Microscopical and Natural History Section, p. 9. Wilde H. — On the Suspension of a Ball by a Jet of Water, p. 133. Williams W. Caeleton. — On the Determination of Phosphoric Acid, p. 141. Williamson Professor W. C., F.R.S. — On a New Form of Calamitean Strobilus, p. 7. On the Structure of Calamites, p. 76. Meetings of the Physical and Mathematical Section. — Ordinary, 46, 123, 124. Meetings of the Microscopical and Natural History Section. — Annual, p. 189. Ordinary, 9, 34, 54, 61, 110, 121, 181. Report of the Council — April 19th, 1870, p. 169. PROCEEDINGS OF THE LITERARY AND PHILOSOPHICAL SOCIETY. Ordinary Meeting, October 5th, 1869. E. W. Bxnney. F.R.S., F.G.S., Vice-President, in the Chair. The following extract of a letter from Dr. J OULE, F. R.S., dated Southport, October 5th, 1869, and addressed to the Chairman, was read : I enclose a rough drawing of the appearance of the setting sun. Mr. Baxendell noticed the fact that at the moment of the departure of the sun below the horizon, the last glimpse is coloured bluish green. On two or three occasions I have noticed this, and also . near sunset an appearance like what I have rudely depicted. Just at the upper edge, where bands of the sun’s disk are separated one after the other by refraction, each band becomes coloured blue just before it vanishes. | On Nontronite,” by T. E. Thorpe, Ph.D., communicated by Professor H. E. Roscoe, F.R.S., » Prep. I. 49-30% Cr. 49-25 % Prep. II. 48-45% 48-62 % Mean 48-91 % Hence the percentage composition of the substance is as follows : — Chlorine Found. ... 21-06 . Ratios. 2 ... Calculated. ... 21-86 Chromium ... ... 48-91 .. . . . , , 3 . . . ... 48-54 Oxygen ... 30 03 . ..... 6 ... ... 29-60 100-00 10-000 18 I have attempted to control the above empirical formula (Cr306Cl2) by heating a weighed portion of the substance in hydrogen. The action of hydrogen upon the new chloride when heated is extremely energetic. At a comparatively low temperature it takes fire, combustion proceeds rapidly throughout the mass, and ultimately the substance is con- verted into chrome sesquioxide, hydrochloric acid, and water. Care must be taken to regulate the current of the hydrogen, since, if too rapid, particles of the finely divided sesquioxide are apt to be mechanically carried away, From an experiment, in which the gas was carefully purified from oxygen by passing it through strongly alkaline pyrogallate solution and over heated metallic copper, and then dried by transmitting it through tubes containing pumice moistened with strong sulphuric acid, the following numbers were obtained - 0*8715 grm. substance gave 0*6150 grm. chrome sesquioxide. Found 70*58 °/o Cr203. Cr306Cl2 gives by calculation 70*72 °/Q I had an additional object in thus studying the action of hydrogen upon the new chloride. I considered that this action might possibly throw some light on the constitution of this compound. The new oxichloride may in conformity with the analytical results be regarded as a compound of chromous chloride with two equivalents of chromium trioxide. Now, chromous chloride, according to Moberg, may be heated in hydrogen to the softening point of glass without suffering decomposition, and if it were found that water was the only volatile product of the reaction, we should possess a certain amount of evidence for supposing that the formula CrCl2, 2Cr03 represents the constitution of this substance. Experiment showed, however, that the chlorine was not so firmly united in this compound as in the chromous chloride : on gently heating the substance in hydrogen, hydrochloric acid was immediately evolved. 19 Pdligot has described a series of salts to which are assigned the general formulae M Cl, Cr03 and M"C12, 2Cr03, where M represents a monovalent metal and M" a divalent metal. The following are the names and formulae of the salts pre- pared by Peligot : K Cl, Cr03 Potassium chlorochromate. Na Cl, Cr03 Sodium chlorochromate. NH4C1, Cr03 Ammonium chlorochromate. Mg Cl2, 2CrOs Magnesium chlorochromate. Ca Cl2, 2Cr03 Calcium chlorochromate. Now the new oxychloride stands in a very evident rela- tion to these compounds. Supposing fora moment that the formulae given to these substances correctly represent their constitution, then the new oxychloride may be regarded as the chromium term of the series— -divalent chromium re- placing magnesium or calcium, Cr"Cl2, 2Cr03, a formula identical with that of which I have just attempted to show the impropriety. But there is still another reason for supposing that a compound thus constituted could not exist. Chromous chloride is one of the most energetic deoxidising agents known, and we can hardly conceive it to be united in a stable compound with a substance which so readily parts with its oxygen as chromium trioxide. Hence I am disposed to regard the constitution of th e salts of Peli- got as very different from that implied by the above method of representation : indeed to the best of my knowledge the general formula assigned to these salts expresses not a single experimental fact, unless it be the mode of their decomposi- tion by water ; probably it had reference to the views of Rose and Berzelius respecting the constitution of the so- called chlorochromic acid. The following structural formulae better represent in my opinion the constitution of these compounds and their relation to chromyl dichloride* Magnesium Chlorochromate. Cl. 20 Chromium Chlorochromate. Cl. Cr09 CrO. i 0 1 0 i j Mg 1 Cr." 1 0 i 1 0 Cr02 i j Cr02 i 1 Cl. 1 Cl. These substances may also be thus represented : Oro/jS1 I Cr" I Cr02 | C1 The relation of the new oxychloride to chromyl dichlo- ride is thus very apparent. Three molecules of chromyl dichloride when heated are resolved into one molecule of chromium chlorochromate and four atoms of chlorine. Cr02 | o I Mg f I Cr02 \ 0 ( Cl 21 Ordinary Meeting, November 16th, 1869. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair, Professor Osborne Reynolds, B.A., of Owens College, was elected an Ordinary Member of the Society. “ On the Permian Strata of East Cheshire,” by E. W. Binney, F.R.S., F.G.S. In communications to this Society, and printed in its Memoirs, most of the sections of permian strata in the counties of Lancashire and Cheshire were given. These had been found by amateur geologists, who rambled over the country at their leisure, but when the Geological Survey came into the district, and went over every parish, it was to be expected they would make some discoveries. Accordingly we find in the Memoir explaining the map of the district lying between Macclesfield and Stockport, Mr. E. Hull, F.R.S., describes what he terms a patch of permian strata at Torkington, in the following words: “ Torkington. — A curious little patch of permian beds occurs at Torkington, near Hazel Grove. The beds are only to be seen in the two brook courses, and as far as it is possible to make out their relationship to the coal measures they appear to lie in a trough formed in the lowest beds of the middle series, in fact over the Redacre coal, “The patch appears to be about one-fourth of a mile in breadth from east to west, and is bounded on both sides by carboniferous grits and shales. If we follow the brook eastward from Torkington we find the following series in descending order, all the beds dipping westward. Proceedings — Lit. & Phil. Society.— Yol. IX.— No. 4.— Session 1869-70. 22 Permian Beds. —1. Red marls. 2. Soft red breccia, a sandy matrix containing angular fragments of coal measure grits, shales, and pieces of earthy haematite. Coal Measures. — 3. Soft purple grits, red shales, with bands of earthy haematite. Owing to the amount of drift over this part of the country it is impossible to determine the exact northern and south- ern limits of this little outlier of permian beds.” As it is desirable to collect all the sections showing the relation of the permian strata to the underlying coal mea- sures, probably one may be excused in bringing this portion of Mi-. Hull’s labours before the Society. The section is exposed in a small brook course called Ockley Brook, flow- ing between the Green Clough and Blackwood farms on the estate of Mr. Legh of Lyme, less than a mile to the north- east of the High Lane Station of the Manchester and Bux- ton Railway. When I lately examined it only about one hundred yards of the strata were exposed. They occurred in the following descending order : Permian Beds. — 1. Red marls. 2. Red breccia, chiefly composed of coal mea- sure sandstones, some of them two inches in diameter, for the most part quite angular, with small pieces of haematite, in a paste of sandy clay, about ten yards in thickness. Permian ? — 3. Variegated shale and bright red sandstone. 4. Middle coal measures. The dip of the strata was to the N.N.W. The permian beds at about an angle of 10°. and the coal measures at about 20°. No. 3 appeared more like permian than carboniferous strata, from its characters, but there was no decisive evidence to class it with certainty. Such a bed of breccia has not, to my knowledge, been exposed in Cheshire. In the section described by me many years ago at Norbury Mill, a little to the south-west, the breccia there (more of a conglomerate 23 character) was only 5ft. Sin. in thickness, and separated from the underlying middle coal measures by 12ft. of red clays. In the Ocldey Brook, as well as the Norbury section, there appeared to be no evidence of a fault, but only the covering up of the inferior by the superior strata. As a great portion of the future supply of coal must, most probably, be looked for under the penman and triassic for- mations in Great Britain, it is very essential that all the circumstances under which the carboniferous strata disappear under those deposits should be carefully ascertained and correctly described. When permian or triassic beds are found on the rise of the strata they indicate a fault where the coal measures have been thrown down, but when they are met with on the dip of the strata they may indicate a down-thrown fault similar to the one last mentioned, or else an overlap of the permian or triassic strata simply resting unconformably on the carboniferous strata. Some authors have described both these as faults. In the beginning of this century certain, geologists and practical miners often supposed that when the coal measures disap- peared under the permian and triassic strata, generally then known as “red ground," they were cut off by a fault, and it was useless trying to follow them. “ Bed rock faults ” were then used in the same sense whether found on the rise or dip of the strata. Now it is of the utmost importance that these two classes of phenomena should be carefully dis- tinguished, and accordingly most geologists have done so, and termed the former a fault because the strata are there displaced, and the latter an overlap because the underlying strata are not displaced, but simply covered up by the superior strata. Of course when coal measures disappear on their dip under superior beds, they can generally be followed, pro- vided there are no faults, and if there are faults the beds can be found at some depth or other. Owing to these cir- 24 cumstances permian and triassic strata have been often supposed to indicate tlie presence of coal under them. No doubt they do where profitable seams of coal disappear under them, but when millstone grit or mountain limestone in Lancashire and Cheshire disappear on their dip under permian or triassic strata, such strata do not give any evi- dence of the existence of profitable coal seams under them, but only of beds of mountain limestone or millstone grit seen near them. This holds good only for the southern or midland districts of England, so far as profitable coal is con- cerned, for it is well known that in Scotland both these deposits contain valuable seams of coal. Mr. Hull in his map of the district lays down the country from Macclesfield to Stockport so far as it relates to the coal measures, by supposing the latter strata on their dip as being bounded by what he terms the “ red rock fault,” whereas I have in all my papers described the coal measures in that district as only overlaid by permian or triassic strata, there being in my opinion no evidence of “ a fissure along which relative displacement of the adjoining rock masses has taken place”; such not having been given, it can only be put for- ward as hypothetical and without any evidence of facts to sanction it. When my papers were published there was plenty of evidence in support of my views in other districts, but not so much near Stockport. However, this has lately been supplied on the line of the so-called Red Rock Fault, in a shaft and. bore hole at Brinnington, where, under a. soft red sandstone without pebbles, most probably trias (lower soft red), the coal measures containing seams of coal were met with, thus clearly showing that such strata there were not dislocated by a fault, but simply overlaid by trias. In works of such authority as the geological maps and memoirs of the Survey, every care should be taken to ascer- tain the boundaries of the workable coal fields in a manu- facturing district, where a supply of coal is of such vital 25 importance. A mistake under an official survey can hardly be rectified by an amateur geologist like myself, but it is desirable that the exact nature of this so-called “ Red Rock Fault” should be more carefully investigated, and where necessary rectified in the Government maps. So far as my knowledge extends there is no more evidence of a fault between Macclesfield and Stockport, where the trias and permian beds cover the coal measures, than is to be found on the eastern side of the Pennine chain between Sandyacre and Sunderland, where carboniferous strata disappear under permian. “ On the Combinations of Phosphate of Lime and Sul- phurous Acid,” by Dr. B. W. Gerland, Macclesfield. Communicated by Professor Roscoe, Ph.D., F.R.S. Phosphate of Lime, in whatever state it may be, readily dissolves in an aqueous solution of Sulphurous acid. The solution can be obtained of great strength ; thus, from freshly precipitated Tribasie Phosphate ol Lime a liquor was prepared of 1*3 specific gravity, and from Bone Ash one of 1*1708 specific gravity. The former contained in 1000 cc. Sulphurous Acid ......... ......... 218*38 grm Sulphuric Acid ......... 0*70 Lime 101-79 v> Phosphoric Acid ..... ......... 82*89 403-76 55 These figures agree tolerably with the formula SCaO, P05+6 S02 as the comparison with the calculated table shows : 3CaO ... 84 ... 98*20 P05 ... 71*4 ... 82*89 6S02 ... 192 ... 224*45 405*54 26 The solution of Bone Ash in Sulphurous Acid of IT 708 specific gravity was found to contain in 1000 CC. Sulphurous Acid Sulphuric Acid . Phosphoric Acid Magnesia Lime 141 '82 grm. trace 47-42 2-79 59-69 •n 251-72 „ The formula 3CaO, P05, 6 S02 requires for 47'42 P05 : Lime 55-78 grm. Phosphoric Acid .... 47*42 „ Sulphurous Acid .. . 127*50 ,, — 230-70 The excess of Lime in the Analysis is 3-91 and Magnesia 2-79 These two would require Sulphurous Acid. . . 8*73 Excess of Sulphurous Acid 5-58 251-71 The Bone Ash which was left undissolved by the Sulphurous Acid, had lost all its Magnesia, a circumstance which accounts for the large amount of Magnesia in the liquor. The proportion of 3CaO P05 and S02 varies according to the strength, of the liquor: if the latter is for instance 1-060 specific gravity, 5eq S02 dissolve 3CaO, P05, and in still weaker solutions we find only 4eq S02 for 3CaO, P05 These solutions possess very interesting reactions, some of which are the following : A neutral solution of Ferric Chloride precipitates straw- colored Phosphate of Iron, and if added in proper quantity the liquor is free from both Iron and Phosphoric Acid. The precipitate, after washing and drying over Sulphuric Acid is free from Lime and Sulphurous Acid. Its analysis agrees well with the formula Fe2 03, P05-f 5HO. Acetate of Copper colours the Sulphurous Acid solution, when added in small quantity, intensely green, a further 27 addition produces a thick yellow precipitate, which rapidly changes in contact with air and thereby becomes green. Acetate of Lead also produces a thick precipitate of white colour. These precipitates contain, besides the metallic oxide, Lime, Phosphoric and Sulphurous Acids. Chloride of Barium precipitates the solution directly, and Chloride of Magnesium after some standing. The solution of Phosphate of Lime in Sulphurous Acid possesses the taste and smell of the acid, but to a much smaller extent than an aqueous solution of the acid contain- ing the same amount of Sulphurous Acid. Under the influence of boiling heat the Phosphate solution is decomposed slowly, Sulphurous Acid escapes, and a heavy white crystalline precipitate is formed. Under the micro- scope it appears as composed of crystals of the hexagonal system, like those of rock-crystal. Washed and dried over Sulphuric Acid, it contained : Sulphurous Acid 15*61 Sulphuric Acid 0 °2 3 Lime 39*89 Phosphoric Acid 34*48 Water 9*08 99*29 These numbers agree with the formula 3CaO, P05, S02, 2HO, the calculated numbers of which are SQ2 ... 32 ... 15*58 3CaO ... 84 ... 40*89 P05 ... 71*4 ... 34*76 2HO ... 18 ... 8*77 205*4 100*00 This Sulphited Phosphate of Lime has no smell or taste, and is distinguished from all sulphites by its stability. Heated in an air bath for three hours to 130 C it lost 0*64 per cent of water, but the amount of Sulphurous Acid remained un- changed, neither had a humid atmosphere the slightest 28 effect upon it. The water is held in intimate combination, and is only expelled at a higher temperature when it is accompanied by fumes of Sulphur, Sulphuric and Sul- phurous -Acids. The residue contains, besides Lime and Phosphoric Acid, Sulphate and Sulphide of Calcium. Cold water has no effect upon the Sulphited Phosphate ol Lime. After long continued boiling, the air being ex- cluded, a partial decomposition takes place, which is shown by the following analysis. 1000 CC of the water contained: 502 Q’268 grm. 503 0*047 „ P05 0-1181 „ CaO 0-2045 „ and an undetermined quantity of the undissolved residue contained : S02 0-03464 P05 0-12393 CaO 0-13916 The constituents are therefore in the following proportions* In the solution: leq P05 ; 4*35eq CaO ; 5‘07eq S02 ; 0’71eq S03 and in the residue: leq P0.5 ; 2-85eq CaO ; 0-623eq S02. The Sulphite, which withstands the action of the atmos- phere indefinitely, is rapidly oxidized when incorporated with soil. A quantity was buried in a heavy clay soil (which, as was ascertained previously, contained no Lime and Phos- phoric Acid soluble in dilute Hydrochloric Acid), and was exhumed after two months, when it was found to be free from Sulphurous Acid. The sample was selected for analysis with the least possible quantity of soil. It contained so3 ......... P05 ......... 24-58 CaO ......... ......... 33-66 „ 29 The oxidizing process which has taken place in this in- stance may be expressed by the formula: 3CaO, P05, S02, 2 HO + 0 = 2CaO, HO, P05 + CaO, S03 + HO. The original substance contained 34'5 per cent. P05 and 15-8 per cent. Sulphurous Acid, equal to 19 '75 per cent. S03. The sample for the last analysis ought therefore to contain for 24*58 per cent. P05, 14 per cent. S03, but according to the analysis it contains 18*59 per cent., that is 4J per cent, more. This excess of Sulphuric Acid proves that it is dis- solved at a slower rate than the Phosphoric Acid. Calcu- lating the amount of Lime which the acids of the analysis require, we find for 18*59 S03 as CaO, S03 13 '01 per cent. CaO and for 24*58 per cent. P05as 2CaO, P05 ... 19*28 „ ,, Total 32 '29- per cent. This number is less than the quantity of CaO found, by 1*37 per cent., which excess is to be accounted for by the ten- dencies of the Dibasic Phosphate to undergo a partial de- composition under the action of water, in consequence of which a compound of higher basicity is left undissolved. It is therefore evident that the new compound will, in the soil, act as a soluble Phosphate of Lime. It has in fact for several seasons been used as Manure, and has given great satisfaction. Strong mineral acids dissolve the Sulphited Phosphate of Lime under effervescence of Sulphurous Acid. Acetic Acid has no effect in the cold, and dissolves it only after long con- tinued boiling, but much easier when the air has access. Oxalic Acid decomposes it a little quicker. Chlorine gas is readily absorbed by the new Phosphate. After the action is completed it contains no more Sulphurous Acid, but only traces of Sulphuric Acid. Of the Phosphoric Acid only a small portion has become soluble (about 1-X2th). This de- composition still occupies my attention. so A weak solution of Iodine, such as Mohr’s standard solu- tion, acts readily upon the Sulphited Phosphate of Lime, as represented by the formula 3CaO, P05, S02, 2HO + I - CaO, 2HG, P05 + CaO, S03 + Cal. The colour of the Iodine disappears as long as there is sub- stance left undissolved. This is a convenient method for estimating the Sulphurous Acid of the compound, but as the last portions are only slowly acted upon by the Iodine, it is advisable, in order to save time, to add a drop of Hydro- chloric Acid when the Iodine begins to disappear slowly. It does not interfere with the accuracy of the experiment. The Sulphited Phosphate of Lime, exposed to an atmos- phere containing Ammonia, rapidly absorbs the latter; but at the same time an equivalent quantity of Sulphurous Acid seems to be oxidised. A sample of the substance was placed under a glass shade, with pieces of Carbonate of Am- monia and water for four weeks, and subsequently over Sul- phuric Acid for two days, and yielded by analysis the fol- lowing results: Lime 39-08 per cent. Sulphurous Acid ... 2-50 „ Ammonia 5 “60 ,, The new Sulphite possesses remarkable antiseptic and disinfecting powers, and on this account will command a general interest. The efficacy of Sulphurous Acid as a dis- infectant is well known; it would be more appreciated if it could be conveniently applied. The aqueous solution is expensive by transport, it is very changeable, and in many cases it is unavailable on account of its pungent smell; whilst for medical purposes it can only be used in excep- tional cases, in consequence of its irritating action. The Sulphites are still more changeable. Exposed to the air they are acted upon by Carbonic Acid and b}^ Oxygen, and when mixed with decaying organic matter for disinfecting pur- poses they very often increase the mischief, and sometimes 31 cause an abundant escape of Sulphuretted Hydrogen. The compound of Phosphate of Lime with Sulphurous Acid has none of these disadvantages. Acids, as well as Ammonia, are neutralized by it. From a sanitary point of view Ammonia is particularly objectionable; being a product of putridity, it helps to accelerate it, and also serves as a vehicle for dis- seminating other products, which, without it, would not be volatile, or only so to a less degree. The Sulphited Phosphate, when applied to putrid matter, will probably do its first service by neutralizing the Ammonia present (including compound Ammonias), and also prevent its further formation, as the test paper will show. The smell will soon cease, or at least be greatly diminished and altered, and the mass will be safe for a long time, so that it may be removed or dried without danger or inconvenience. I must here remark that large quantities of putrid matter in open spaces are more completely and speedily disinfected by small portions of the Phosphate, than samples in glass bottles. The compound recommends itself as a disinfectant by its physical properties. It is a clean white powder, which stains and soils nothing, dusts off garments or carpets, leaving no mark ; it is free from smell and taste, and harmless to animal life. It proves itself invaluable in stables and shippons. The air of these localities is generally highly charged with Ammonia, yet the tenants are expected to live and thrive. A regular application of a small quantity of the Phosphate will prevent the loss of Ammonia, it will sweeten the air, and enrich the manure with Phosphoric Acid, thus being of threefold advantage. The loss of Ammonia from the dung is not inconsiderable, it is also the most valuable constituent of it, being worth more than 9d. per lb. to the farmer. The solution of Phosphate of Lime in Sulphurous Acid also possesses disinfecting powers, and acts in many cases even with greater energy than the powder. It might be 32 used with advantage as being applicable to places which could not be reached by the other. The neutrality, regularity of composition, utter harmless- ness, and freedom from smell and taste, recommend the Sulphited Phosphate of Lime for trial in Therapeutics. It would be of interest to investigate it in relation to putrid puerperal fevers, Pyaemia, &c. It appeared to me not unlikely that a compound of Phosphate of Lime with 2eq Sulphurous Acid might exist. Numerous experiments, made with a view of preparing the same, have entirely failed, but some of the results are interesting as showing unexpected reactions of these com- pounds. The Sulphite of Phosphate of Lime is not acted upon by the solution of Phosphate of Lime in Sulphurous Acid. Sulphurous Acid Gas is only absorbed in very small pro- portion by either dry or wet Bone Ash. This Phosphate of Lime is not even converted into the Sulphurous Acid com- pound by digestion with the Sulphurous Acid solution. If Sulphurous Gas is passed through water holding an excess of Phosphate of Lime in suspension, the latter remains unchanged. Under the receiver of an air pump the Sulphurous Acid solution forms good-sized crystals, probably belonging to the hexagonal system. Analyses of crystals of different preparations gave varying results, which however agreed tolerably with the formula x( 3CaO, P05, S0252H0) + y(CaO, S03, 2HO) + z(CaO, S02 + 5HO) The more crystals separate from the solution, the more the Phosphoric Acid accumulates in the latter. In one instance. Lime, Phosphoric Acid, and Sulphurous Acid were almost in proportion of their equivalents. Alcohol precipitates the solution of Phosphate of Lime in Sulphurous Acid. The analysis of the precipitate gave 33 2 4 '8 per cent of water, and no more Sulphurous Acid in proportion to Lime than the above described powder. The solution is also precipitated by a current of an indifferent gas like Hydrogen. The analysis of the precipi- tate gave figures from which no simple formula can be calculated. The amount of Phosphoric Acid in proportion to the Lime is greater than that corresponding to Tribasic Phosphate, and the amount of Sulphurous Acid is much less than that of the precipitate obtained by boiling. In accordance with the foregoing, the solution after treatment with Hydrogen Gas, was found to contain less Phosphoric Acid in proportion to the Lime than before. Under reduced pressure the Phosphate solution boils easier and the separation of the precipitate takes place more readily. This precipitate contains less Sulphurous Acid and more water than corresponds to the formula 3CaO, P05, S02, 2HO. I experienced so much difficulty in preparing pure Tri- basic Phosphate of Lime, that I was obliged to use for most of my experiments the Phosphate offered by nature in Bones and Bone Ash. The Compounds of Phosphate of Lime with Sulphurous Acid undoubtedly possess great scientific interest. This consideration, as well as the importance they are likely to attain for agricultural and sanitary purposes, as they have now become articles of commerce, -has induced me to lay before you the results obtained so far in my investigation, with the prosecution of which I am still occupied. 34 MICROSCOPICAL AND NATURAL HISTORY SECTION. November 8th, 1869. Joseph Baxendell, F.RA.S, Vice-President of the Section, in the Chair. Mr. W. J. Hideout presented the Section with one of the “ Diotamaceen Typenplatte/’ prepared by J. D. Moller, of Holstein, and containing 408 separate types of Diatoms, beautifully arranged within an area of an eighth of an inch. A vote of thanks was passed to Mr. Hideout for his valuable and acceptable present, the Section at the same time offer- ing him its congratulations upon his escape from shipwreck by the loss of his yacht “ Creusa,” off Cherbourg. Mr. J. B. Dancer sent for the inspection of the members a young cuckoo, which had been caught by a cat in his garden, Old Manor House, Tipping-street, on the 19th August. Some fifty years since cuckoos might have been common objects there, but now that the place is surrounded by factory chimneys and the atmosphere so changed that vegetation has to struggle for existence, such visitors were not to be expected. The Taxidermist imagined that the bird had been wounded, which had possibly induced it to take refuge in one of the poplars, and being seen by the cat, had become easy prey. The following note was read from Mr. Joseph Side- BOTHAM : — About fifteen years ago, I had a large cabinet made of forty-five drawers, to contain shells and carpological specimens, the drawers being made of pencil cedar. Very soon I found that the resinous vapour from the wood became deposited on some of the fruits and shells, making them appear as if they had been dipped in varnish. Chloroform appeared to be the only solvent, and the specimens were obliged to be washed with it. This became 35 so bad that I had the whole of the drawers removed, and replaced with drawers of baywood. Sometime afterwards, Mr. Carter advised me to have the cedar drawers sized and papered inside, and a new cabinet made to contain them ; accordingly he made me one to contain thirty drawers. These drawers were exposed to the air for twelve months, and very well sized inside, and papered, but the resinous vapour is still deposited on the objects in the drawers as before, and so far is a warning to every one never to use pencil cedar for such a purpose. I should not, however, have thought this matter worthy of mention before the Section, had it not been for the very curious and capricious way in which some objects are coated with this resin, while others are left entirely free, and for which I am totally unable to account. In shells the genera Conus and Oliva are never touched by it, nor are Cyprea or Mitra, whilst Helix , Bulimus, and Pecten, are coated- over; this is the case when there are specimens of these and other genera in the same drawer. As this deposit is on the genera I have named, and never on the others, it would seem to indicate that the texture of some shells would attract the vapour and not others. But in the case of birds’ eggs, the very strange manner in which some species are picked out as it were and others left, is most remarkable. In the owl’s eggs, for instance, the barn owl is always free, while the tawny owl is covered with the varnish, although side by side. The song thrush is never attacked, and the missel thrush always. Trays exhibiting these peculiarities were passed round for inspection. Mr. Sidebotham also sent a living Death’s Head Moth, bred from a pupa, which he had obtained at Lytham, and exhibited that the members might hear its curious cry or squeak when touched. Mr. H. A. Hurst deposited in the Library a copy of a rare botanical work by a Jesuit Priest, the Rev. J. Barrelier, 86 which contained upwards of thirteen hundred carefully engraved plates of plants, which he had collected in France^ Spain, and Italy. The work was edited by Antonio de Jussieu, and published in Paris in 1714. Mr. Hurst also exhibited some dried plants, recently collected by Mr. Wanklyn in the Southern States of America. Mr. Coward exhibited the following species of Podos- temacem, collected by Gardner, in India and Ceylon.— London: Jour. Bot ., vi., 60. Podostemon griseum TV alii r>T» i i Gardn. R Br ,rl i r>Ti Unm n m Gardn rigidum Gardn. — — -- — - sabulatum .... Gardn. Dalzellia ceylandica Wight. Hydrobryum olivaceum Tul. Dicrsea elongata .... .Tul. The Podostemaceae, a little known order of Tropical Aqua- tics, closely resemble the Liverworts in habit and general appearance, but possess phanerogamous flowers and dicotyledonous seeds. The order was placed by Yon Martins amongst Endogens, in the near neighbourhood of the Naidacese, and by Lindley in his Rutal Alliance of Exogens. Gardner considers it to be nearly allied to the pitcher plants — Nepenthacese. The difficulties attending the position of the order were well illustrated in the specimens exhibited, which presented a singular resemblance in foliation to Jungermannia and Riccia, and in the first view of the pedicillated ribbed capsule to the fructification of a moss, but in essential characters the true place appeared to be amongst the aquatic Endogens, with the anomaly of possessing a dicotyledonous seed. i 37 Ordinary Meeting, November 30th, 1869. Rev. William Gaskell, M.A., Vice-President, in the Chair, “ On the Microscopical Examination of Milk under cer- tain Conditions/’ by J. B. Dancer, F.R.A.S. In August and September last an account appeared in one of the newspapers (and also in other periodicals), which had been copied from the “Journal des Connaissances Medi- cales,” of some microscopical observations made by M. V. Essling on Milk, in which the author stated that “ if the surface of fresh cream be examined under the lens, one per- ceives, amid myriads of milky and fatty globules, a number of either round or oblong corpuscles, sometimes accompanied with finely dotted matter, being neither more nor less than germinative masses of vibrios — -just what is seen in most sub- stances in a state of putrefaction. In summer these corpuscles make their appearance within 15 or 24 hours after milking; in winter they will be perceptible after the lapse of two or three days. If the observation be continued until the moment of coagulation we see these corpuscles increase in number, bud, form ramified chains, and at length be transformed into regular mushrooms or filaments composed of cells placed end to end in simple series, and supporting at their extremi- ties a spherical knob filled with granulous matter. M. V. Essling thinks that they may be classified among the Ascophora. But the important point is, that the first ap- pearance of these spores occurs before the milk gets sour , and as this substance is almost the exclusive aliment of Proceedings — Lit. & Phil. Society. — Vol. IX. — No. 5. — Session 1869-70. 88 children, there is reason to suppose that many of the gastric affections to which they are subject are owing to this state of the milk. To prevent these evil consequences, M. Y. Essling recommends the milk to be drunk as soon as possible after extraction, and at all events to keep it closely bottled during the interval, so as to keep out the smallest particle of air. Moreover, the temperature should be kept as nearly as possible the same as that which the milk had in the teats/’ Having for many years been familiar with the microsco- pical appearance presented by milk and cream, and not having seen the changes as described by M. Y. Essling, I was desirous of satisfying myself on this point, more espe- cially as it affected a very important article of food. The composition of ordinary milk, as stated by Fownes, is as follows : — Water 873-00 Butter 30*00 Casein 48*20 Milk Sugar 43-90 Phosphate of Lime 2-31 Phosphate of Magnesia 0-42 Phosphate of Iron 0-07 Chloride of Potassium 1 -44 Chloride of Sodium 0’24 Soda in combination with Casein 0-42 1000-00 Composition of Casein in 100 parts : Carbon Hydrogen Nitrogen ... Oxygen j Sulphur j 53-83 7-15 15-64 23-37 100-00 39 Composition of Albumen in 100 parts : — Carbon 53*5 Hydrogen 7’0 Nitrogen 15*5 Oxygen . . 22-0 Phosphorus 0*4 Sulphur 1*6 100-00 Casein and animal albumen are remarkably similar in composition ; casein differs in not being coagulated by heat, and is precipitated by acetic acid. Certain animal sub- stances cause its coagulation, such as the dried stomach of the calf, known as rennet, used in the manufacture of cheese. When a thin film of milk is examined with the microscope, it is found to be a transparent fluid, in which are floating numerous transparent globules of fat ; these are surrounded by a thin pellicle, and when this pellicle is broken mechani- cally, as by churning, the fat is liberated and forms butter. The fluid part consists of casein, saccharine matter, and salts in solution. The proportion of these organic principles varies in different animals, and also in the same animal when fed under different conditions. Human milk usually contains a larger proportion of sugar than cow milk, and is coagulated with greater difficulty. It is well known that the secretion and quality of milk is influenced by the men- tal emotions. Milk as obtained in towns is frequently adul- terated, and as foreign matter would alter its microscopical characteristics, it was necessary to procure pure milk. One of our members, Mr. Kipping, kindly supplied me with a bottle of fresh drawn milk. The cow had calved about three months previously, and had been fed on grass, bran, and bean flour. This milk was examined soon after I re- ceived it, and was found to be very rich in oleaginous 40 globules, forming a plentiful supply of cream. There was no appearance of dotted matter or any fungoid growth when examined by powers varying from 200 to 1500. The small- est oil globules exhibited (as usual) great molecular activity. A bottle was filled with some of this milk and securely corked, other portions of the milk were placed in open cups, one cup was kept in a cabinet which was closed during the day, the milk of the second cup was placed in a closet the atmosphere of which I knew to be favourable to the growth of fungi, the Mucor Mucedo being the most abundant and of the same family as that mentioned as having been found in cream by M. V. Essling. The milk in the bottle and that in the cups was examined daily, precautions being taken to close the bottle speedily after a portion was removed. On the third day the milk in the open cups was sour to the smell, but no change appeared visible under the microscope ; the upper portion of the milk in the bottle had become very rich in oil globules by the formation of cream. On the fourth day the casein had coagulated in the milk in the open cups, and the flaky precipitate was visible under the microscope ; the pellicle surrounding the oil globules now appeared to be very easily ruptured, and with the slightest pressure some of the globules could be joined together— sometimes a number of globules which had been ranged in line by a current would coalesce by a slight movement of the fluid, and form an elongated mass. Fifth day, no appre- ciable alteration. Sixth day, the milk which had been placed in the closet had patches of mould visible on its surface; a microscopical examination of this mould showed it to be the Mucor Mucedo, such as I had frequently found on fruit which had been left in this closet. The fungi appeared on the surface only, no trace of it could be found in the milk taken from various depths. The milk in the cup kept in the cabinet exhibited no appearance of the Mucor Mucedo or any other vegetable or animal organism ; 41 it had become thickened into a pasty mass with an intensely sour odour. These observations were continued for eleven days, and the only difference observable was in the oil glo- bules - — they began to lose their spherical form, as if the investing pellicle had been weakened in parts and had become expanded. These experiments were repeated with a second supply of milk which Mr. Kipping kindly supplied, and the results were alike in both cases. The range of temperature during the experiments was from 45° to 63° F. These experiments would lead me to believe that vegetable organisms do not as a rule make their appearance in pure unadulterated milk unless it is exposed for some time to atmospheric influences ; most probably the spores are supplied by the atmosphere. Further experiments are wanting to decide the question. The microscopical examinations should be continued in hot weather. I hope to be able to resume the enquiry next summer under different conditions, which have suggested themselves during the examinations 1 have detailed. In any case M. Y. Essling’s suggestion to bottle the milk is very good, and in my opinion cream pans with covers would be a very great improvement on the open ones as at present employed, at the same time having due regard to the clean- liness of the apartment and vessels in which the milk is kept. In a microscopical examination such as I have recorded it is quite necessary to have pure materials. The milk as supplied by vendors we know to be very frequently adul- terated, and the most simple and easy method is by the addition of water. We know also that in towns where the water has a high character for purity, it sometimes happens in dry hot weather the reservoirs are charged with vege- table and animal organisms. Milk may not always have town’s water added to it ; in this case there may be an extra quantity of vitalised matter introduced. What a surprising 42 account a microscopist might furnish from the examination of milk containing such an importation ! In the cold wea- ther, such as we have at present, animal organisms are not so abundant, and this may account for their absence from a sample of milk obtained in this town, in which I found algse, but not belonging to the pure milk. One curious circumstance was noticed in this milk, no Mucor Mucedo appeared in or on it, although exposed in the closet for the same length of time as Mr. Kipping’s milk, which showed signs of this growth on the sixth day, and on the twelfth day the town milk had none visible. I may mention that pure milk in a bottle securely corked remained fresh twelve days; possibly the low temperature favoured its preser- vation. 43 Ordinary Meeting, December 14th, 1809. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair. Sir Charles Lyell, Bart., LL.D., D.C.L., F.R.S., &c., and Henry Clifton Sorby, F.R.S., F.G.S., were elected Honorary Members of the Society. Mr. Robert Routledge was elected an Ordinary Member. Mr. William Boyd Dawkins, F.R.S., exhibited some old mining tools, brought over by Mr. Bauerman from the tur- quoise mines of the promontory of Sinai, consisting of a stone-hammer and rude splinters of flint. The turquoises occur in a bed of a quartzose mottled sandstone in Wady Sidreh and Wady Maghara, in joints running for the most part north and south. They were worked, according to the evidence of the hieroglyphic inscriptions on the rock, by the Egyptians from the third to the thirteenth* of the dynasties mentioned by Manetho. In and around the workings there are still the tools with which they were carried on. Innumerable splinters of flint, with their points blunted and rounded by use ; stone-hammers, some of which are broken; and rounded pebbles with a concavity on either side caused by the friction of the thumb and finger charged with particles of sand, and segments of small wooden cylinders, lie together. The flint flakes exactly coincide with the grooves in the rock made in the excavation, and evidently have been blunted by such use. The fragments of wooden cylinders are believed by Mr. Bauerman to have been por- tions of the sockets into which the flakes were fitted. The round pebbles were probably used for driving the rude chisel formed by the flint inserted into the wooden socket, while the large stone-hammers were used for breaking up the rock. There was no evidence that metal of any kind was used in the work, Mr. Bauerman also satisfied himself that the hieroglyphs were cut with implements similar to those used in the mining. This discovery is very important, because it opens up the question as to what tools the Proceedings — Lit. & Phil. Society. — Vol. IX. — No. 6. — Session 1869-70. 44 Egyptians used in working tlieir wonderful monuments of granite and syenite. If it were worth their while to con- duct turquoise mining with flint flakes in the Sinaiitic pro- montory, and if they used the same tools in the hieroglyphs that fix the date of these mines — -and of this there can he no reasonable doubt — it is very probable that they employed the same means for the same end elsewhere, and that, to say the least, a part of their marvellously minute sculpture in Egypt has also been wrought with flint. There is no evidence that they were acquainted with the use of steel. Iron and bronze are not hard enough for the purpose. The minute and delicate sculpture left behind by the Mexicans, which can be proved to have been worked with stone tools, adds to the probability of this view. “ On the Hades, Throws, Shifts, &c., of the Metalliferous Veins of the North of England,” by Mr. J. Curry, of Bolts- burn, Eastgate, County of Durham. Communicated by E. W. Binney, F.RS., F.G.S. That part of the lead mining district of the North of England, to which the author’s observations on vein phenomena more particularly apply, is situated on the eastern slope of the Pennine chain, and includes Alston Moor, East and West Allendales, Derwent, Weardale, and Teesdale. Millstone grit caps most of the ridges in this area, but the principal strata are of the carboniferous limestone formation, and consist of alternating limestones, sandstones, and shales, with an intercalated bed of basalt. (Whin Sill.) The chief ore bearing series of strata is stated as overlying this basaltic bed. After making a few remarks on the prevalence of veins in this area, and on their bearings and widths, he describes and illustrates the characteristics of hades, throws, shifts, and bent positions of strata, in connection with veins. Hades are greatest in shales, or argillaceous strata. It is found, especially in the Alston Moor district, that the throws and shifts are greatest at, and near the surface, and that they diminish in descending into the earth. This is probably the case with the bent forms of strata. 45 The new views, contained in this paper, are embraced under the consideration that the hades, throws, shifts, &c., may have been chiefly accomplished by peculiar modes of depositing of the sediments, during the contemporaneous building of the veins and strata. Such modes are minutely described and illustrated by diagrams, which are * requisite to convey a clear conception of the processes. The contemporaneous building of the veins and strata is assumed as commencing from straight fissures on the granitic floor, at the bottom of the ocean. Such fissures are viewed either as occasioned by real breaches of the solidified granite, or as effected partly by interchanges between the internal heat and that on the bed of the ocean. The heat eliminated from these fissures, and from the fis- sure-like vein structures, gives rise to a series of marine currents, that control the sedimentary deposits, in such a manner, on the sides and on the tops of the building veins, as to produce the varied phenomena connected with veins, namely, hades, throws, shifts, and bent positions of the strata. In a brief abstract, like the present, the author’s ideas respecting the causes productive of the vein phenomena, under question, cannot be satisfactorily shown without the aid of diagrams, but the following may suffice. Veins, in general, most probably take the directive tendency of their hades from, and in agreement with the original fissures from which they build. Thus, one building from a fissure, which has a north and south course, and which hades over to the east at the top, may, in all likelihood, continue hading over to the east during its upward construction. While building, during the deposition of a shale stratum, the eliminating heat will, at the top of the underlying cheek, show much force, by driving the loose light particles back, and, conse- quently, cause the aggregating mass to form and face back from the perpendicular. Should the next be an arenaceous deposit, then the sedimentary particles would be heavier, so that the power of escaping heat, at the top of the under- lying cheek, would not be so effective in forcing them back, therefore, the face of the aggregating arenaceous mass would 46 form nearer the perpendicular. Thus the different hades in the varied deposits may he accounted for. Throws are described as being due to a thicker deposit taking place on one side of a vein than that on the opposite side. The north and south vein, just cited, will answer to show the mode of explaining the throws. The rising of heated water, from the top of the fissure, would not only oppose the falling of the sediments, but would collect and carry them upwards and away from the perpendicular to the east. The sediments, thus gathered and lifted, would fall on the underlying side of the fissure. Under such con- ditions, the underlying side would build up faster than the overhanging one, and would, after a period of continued deposition, attain a higher level. This higher level of the underlying side is in agreement with a very general law respecting metalliferous veins and faults. Thus throws may begin at nothing, in deep lying rocks, and continue to aug- ment upwards until they ultimately become very con- siderable. Shifts and bent positions of the strata, like the throws, are considered as beginning from nothing, and as being mostly accomplished during the contemporaneous building of the veins and strata. Without the aid of diagrams, justice can scarcely be done to an explanation of the mode of operation; but the most noteworthy characteristic con- ditions are, the powers of evolving heat along the courses of the several veins, and the agencies of numerous complex marine currents. PHYSICAL AND MATHEMATICAL SECTION. December 7th, 1869. E. W. Binney, F.R.S., F.G.S., President of the Section, in the Chair. “On the Mean Monthly Temperature at Old Trafford, Manchester, 1861 to 1868, and also the Mean for the Twenty Years 1849 to 1868/’ by G. Y. Vernon, F.R.A.S., F.M.S. 47 In vol. 1, 3rd series, of the Memoirs of the Society, in a paper “ On the Irregular Oscillations of the Barometer at Manchester,” I gave reductions of the mean monthly temperatures observed by myself from 1849 to 1860, and in the present communication I give the values for the succeeding years down to the end of 1868, completing a period of 20 years. It is scarcely necessary to remark that these values have all been carefully reduced to the Green- wich standard, and corrected by means of the tables of diurnal range computed and published by Mr. Glaisher. As will be seen by the notes appended to Table I., I have been indebted for a few months' results to Mr. Mackereth’s observations made at Eccles, and which closely represent those made at Old Trafford. Table II. contains the differences of the mean tempera- ture of each month from that of the whole period 1849 to 1868, but unfortunately the month of August is almost entirely deficient in the earlier series, and this is a gap I see no chance of filling with observations made at any station which would be at all fairly comparable with the remainder of the series. The mean temperature of the months of the various periods have been as follows : 1849 to 1860. 1861 to 1868. 1849 to 1868. O O O January 38-3 37-2 37-8 F ebruary 37-8 38-9 38-2 March . . 41-3 40-1 40-8 April 46-6 46-8 46'6 May 51-8 517 51-7 June 575 56-4 57-0 July 60-5 58-3 59-6 August — 57-6 58-7* September 55-2 55-1 55-1 October 48-5 49-0 48-7 November 41-2 41 1 41-2 December 389 40-4 40-4 Mean 47-3 47-9 * From 9 years only. The mean of the period 1861 to 1868 appears to have been on the whole rather colder than the average of the last 48 twenty years, and apparently chiefly owing to the lower mean temperature of the month of July: July only exceed- ing 60° in two years, 1865 and 1868, whilst in the earlier period July in six years exceed 60J,0, viz., in 1850, 1852 (67°'9), 1854, 1855, 1857, 1859. On examination of the mean variations of temperature for each month (Table II.), we find that the greatest amount of variation of the mean monthly temperature may be ex- pected in February, and the least in October, or, arranging the months in their order of amount, we have — ■ o o October . . . . .. 1-50 March ... 2-17 April .. 1-67 J My ... 2-35 September . .. D89 November ... ... 2-37 May .. 1-91 August ... 2-61 January .... .. 2-02 December . . . ... 3-01 June .. 2-06 February ... ... 3-26 One point in this seems somewhat curious, and that is, that the wettest and driest months should be liable to about the same changes of temperature. The distribution seems very irregular, months widely apart coining next one another as regards this element of temperature. At the bottom of Table 2, 1 have given the values of the Probable Yariation of Mean Temperature for each month, computed from my own observations for the twenty years, and, as the late Manuel J. Johnson gave similar values com- puted from Dalton’s Observations, 1794 to 1818 (Radcliffe Observations, vol. xv., 1854), I annex them for comparison 25 Years. 20 Years. Dalton, Old Trafford, 1794 to 1818. 1849 to 1868. January ±27 ± D8Q February T8 3 ‘50 March P6 1*93 April 2*1 T49 May T9 1*70 June T6 T84 July 1-8 2-09 August 1‘2 2 ’48 September 1'6 P68 October 1-7 D33 November 2*0 2'11 December ±1*8 ± 2-68 49 There are evidently great discrepancies between the two series of values, which it is quite out of my power to explain, but reference to the monthly means for Old Trafford show that the probable variations during the period 1849- 1868, must have been much greater for some of the months than those given from Dalton's earlier period, especially in the month of February ; in 15 years of the Old Trafford observations the variation of the mean temperature of February, from the mean of the period, exceeded 1Q,8 the amount from Dalton’s observations, very considerably. The same may be said of other months, but not to the same extent. Table I. & Mean Monthly Temperature at Old Trafford, Manchester, 1861-1868. Year. Jan. Feb. Mar. Apr. May. June. July. Aug. Sep. Oct, Xov. Dec. o o o o o o O o O O o o 1861 35-0 40-0 43-0 44 ’4 49-3 56-6 59-3 — 55-2 52-8 38-0 39-5 1862 38-1 41-0 42-0 41'2 47-8 48-0 56-7 58-0 54-7 49-1 36-8 43-0 1863 42-4 41-8 43-8 47 6 50-9 57-0 51-5 52-4 47-7 48-9 45-0 42-9 1864 35-6 35-2 38-8 48-3 5A2 56'0 58'3 55-6 54-7 49-0 43-0 48-5 1865 35-0 35-5 365 50-5 53-9 59-8 61-6 58-1 60-9 49-0 43 1 41-9 1866 39'7 34-7 35-5 .47-3 48-9 59'6 57-0 57-5 53-8 490 43-7 416 3 867 33-2 39-9 37-2 48-7 53-3 56-6 5.8-4 60-5 56-2 47-7 38-7 38-4 1868 38-9 42-8 43-8 462 553 57-5 63-3 61-3 57-6 46-6 40-8 44-1 Means, 1861tol868 37-2 38-9 40-1 46-8 51-7 56-4 58-3 57-6 55-1 49.0 41-1 40-4 - August, 1862. Determined by reduction from the Ob- servations made at Eccles, by Thomas Mackereth, Esq., F.R.A.S. I may remark here that our observations are nearly identical, or where different seem to be so almost by a constant difference. January, 1863. From Mr. Mackereth’s Observations. April, May, June, July, August, September, 1868, taken from Mr. Mackereth’s Observations. 50 Table II. Difference between the Mea.n Temperature of each Month, and the Average of the same Month for Twenty Years. Year. Jan. Feb. March April. May. June. July. Aug. Sept. Oct. Nov. Dec. O o o o O o o o o O o o 1849 4-2-0 00 —1-9 4-1-6 —1-2 —0-7 4-0-2 -j-0"8 4-i-o —1-2 —0-6 4-2-7 4-3-7 —1-8 1850 —3-4 4-5-9 4-2-1 4-1-6 —3-1 —0-9 1851 •4-3-6 -j-1-2 -f-i-7 —1-0 —1-4 —1-5 4-2-8 —5-6 4-0-3 1852 4-2-2 4-1-8 4-0-3 4-1-4 4-i-o 4-1-6 4-8-3 —0-8 —4-1 4-3-8 4-4-8 1853 4-2-8 — 5-4 — 2-6 —l-o — 01 4~T6 —TO —1-0 4-0-5 -5-2 1854 —0-1 +0-8 4-3-2 4-2-8 4-0-6 4-o-i 4-0-7 4-2-1 —1-7 —0-9 —0-6 1855 —IT — 9-6 —2-6 —0-5 —3-2 -1-0-1 4-2-2 —0-2 —0-2 4-0-3 —4-8 1856 —0-1 4-2-9 4-0-3 4"0"6 —1-5 —1-3 —0-9 —0-9 4-3-1 —2-0 —1-9 1857 —1-3 4-i-i 4-i-o —02 4-io 4“4"2 4-i-o 4-4-2 4 — 2"6 4-3-3 — | — 2*6 4-4-8 1858 4-o-i -2-9 —0-2 —0-2 -1-8 4-6-3 —1-7 4-3-0 -j-4'1 —0-5 —2-0 -j-0-4 1859 _i_3-3 4-2-9 4-4-0 —1-4 4-2-6 4-3-2 4-4-7 4-o-i —0-2 —1-6 —6-3 1860 lo-i —3-7 —TO —2-2 4-2-8 _l-8 —2.0 —3-4 —01 — 1-2 —5-9 1861 _2-8 4-1-8 — | — 2*2 —2-2 —2-4 —0-4 —0-3 4-o-i 4-4*1 —3-2 —0-9 1862 4-0-3 4-2-8 4-1-2 —5-4 —3-9 —9-0 —2-9 —0-7 —0-4 4-0-4 — 4*4 4-2-6 1863 4-4"6 4-3-6 4-3-0 4-1-0 —0-8 o-o -81 -6-3 —7-4 4-0-2 4~3"8 4-2-5 1864 —2-2 —3-0 —2-0 +T7 4-2-5 —1-0 -1-3 —3-1 —0-44-0-3 4-1-8 4-8-1 1865 —2-8 —2-7 —4-3 4-3-9 4-2-2 4-2-8;4-2-o — 0"6 4 — 5*8 -j-0’3 4-1-9 4-1-5 1866 4-1-9 —3-5 —5-3 4-0-7 —2-8 4-2-6 —2-6 —1-2 _ 1-3I4-0-3 4-2-5 4-1-2 1867 —46 4-1-7 —3-6 4-2T 4-l'6 —0-4 —1-2 4-1-8 4-1-1 — TO —25 —2-0 1868 4-1-1 4-4-6 4-3-0 —0-4 -j-3-6 4-0-5 4-3-7 -1-2-6 4-2-5 —2-1 —0-4 4-3-7 Means. _2 a -\ 2-02 3-26 217 1-67 1-91 2-06 2-35 2-61 1-89 1-50 2-37 301 ’■J3 -2 / 03 -t-3 ( rb 03 y O -g ( £ s3 \ P8 > J 1-80 3-05 1-93 1-49 1-70 1-84 2-09 2-48 1-68 1-33 2-11 2-68 51 Ordinary Meeting, December 28th, 1869. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair. “ On Pollen ; considered as an Aid in the Differentiation of Species,” by Charles Bailey, Esq. Having recently examined the pollen of several thousand species of plants, I am led to think that the characters pre- sented by these grains might prove useful as a means of differentiation in allied species; my researches, however, have not been sufficiently extensive to form any positive conclusions, but as leisure permits I hope to prosecute the subject further. In the meanwhile the following notes are thrown out as indications of some of the more noticeable distinctions to be drawn from a careful comparison of these organs, and they may serve to draw the 'attention of others to the matter. There are four points, in one or other of which pollen grains of plants belonging to the same genus may be found to differ from each other, viz., form, markings, dimensions, and colour. 1. Form. It has long been noticed that certain types of pollen are characteristic of the natural order to which the plants which produce them belong, as for instance, the peculiar pitted polyhedral pollen of the Caryophyl'acece , the spherical spiny pollen of the Malvacece , the large triangular pollen of the Onagracece, the peculiar pollen of the Coniferoe, or the elliptical pollen of the Liliciceoc and other monocotyledonous orders; in fact, most orders possess a type sufficiently marked to be character- istic of each. This statement, however, must be accepted with limitations ; the Compositce, for instance, have three or more well-marked types, represented by the beautifully sculptured pollen of the Chicory, the minute oval spiny pollen of the Asters, Calendulas, Cacalias, &c., and another form wholly destitute of spines as in the Centaurea Scar Proceedings — Lit. & Phil. Society. — Yol. IX. — No. 7. — Session 1869-70. 52 biosa. There are, besides, other natural orders where similar variety occurs. But differences of form are met with in plants of the same genus, by which the one species or the other is readily marked off by its pollen ; thus the pollen grain of Anemone sulphured is roundish, but that of Anemone montana is elliptic ; the pollen of Aronicum Doronicum is much more elongate than that of A. scorpioides; and while the grains of Ranunculus philonotis are round and yellow, those of R. platanifolius are elliptic, white and smaller. 2. Markings. Here again there is endless diversity, and a boundless field lies open for the researches of tired-out dot and line hunters of diatom- valves. A few instances only of the more striking differences can be given here. The pollen of the Geraniacece and Gampanulacece is for the most part globular, but while some of the grains are quite smooth others are covered with spines ; thus the pollen of Campanula Media has a number of short spines sparsely scattered over the surface of the grain, but C. rapuneuloides is wholly destitute of them. In other plants these spines are replaced by tubercles, and both spines and tubercles vary greatly in length and number ; for example, in Vale- riana tuber osa the spines are only half the length of those on the pollen of F. montana, the grains being also slightly smaller. The pollen of the Liliaceoe is often covered with a more or less prominent reticulation, which is subject to much variation ; compare, for example, the coarse network which invests the pollen of Lilium croceum with the finer reticulation of L. eanadense, the grains of the latter species being much more globose and smaller. 3. Dimensions. Some instances of the differences obser- vable in the size of pollen grains have already been pub- lished by Professor Gulliver, whose measurements of the pollen of various species of Ranunculus show the help that may be derived from this character ; R. arvensis is nearly 53 twice the size of R. hirsutus, their dimensions being respec- tively o and ah of an inch. I have not had the time to make similar careful measure- ments with the micrometer, but I have seen sufficient to be satisfied that while there is considerable variation in dimen- sions between the pollen of one species and that of another, they are tolerably constant in size in the same species. For some noticeable differences compare the smaller pollen of Epilobium brachycavpum with the larger pollen of E. Fleischeri or that of Senecio gallicus with S. incanus, the spines on the latter species being also much coarser. Again, the pollen of Silene acaulis is but half the size of that of 8. alpina, the latter having some beautiful markings in addition; the pollen grains of this genus differ from the usual caryophyllaceous type in not having the pits or depressions common in the order, so that the grains become spherical rather than polyhedral. 4. Colour. This is not so reliable a character for differ- entiation as the others noticed, since species differ amongst each other according to the soil, &c., of the place where they have grown. I remember gathering some years ago, near Ashbourne, Derbyshire, a variety of Stellar la Holostea having a dark purple pollen instead of the ordinary pale yellow. An example or two under this head will suffice. The pollen of Ajuga genevensis is yellow, but that of A. pyramidalis is usually white ; again, while the grains of Ornithogalum umbellatum are large and yellow, those of 0. nutans are small and white. Some objection may be raised to any reliance being placed upon the dry shrivelled-up grains of herbaria speci- mens— such specimens being in most cases the only ones obtainable for purposes of investigation ; but the structure of pollen is such as to bring into greater prominence the pores, folds, valves, and other markings which are met with on their surface after the grains have collapsed by the dis- charge of their contents. 54 In regard to the mounting of these objects for the micro- scope, they show to the best advantage when put up per- fectfy dry; the cells should be sufficiently shallow to admit of no more than a single layer, and at the same time deep enough to permit the grains to move about. If pollen is mounted soon after it has been discharged from the fresh anthers the fo villa is apt to condense on the cover- ing glass, and the slide soon becomes useless. The stamens taken from an unopened flower-bud furnish the best and cleanest pollen, and these should be selected in preference to those taken from the fully developed flower. Canada balsam, glycerine, and other media are occasion- ally helpful in making out structure ; thus the pores of Campanula rotundifolia, Phyteuma Halleri, and other allied species are made much more distinct when mounted in balsam. A large series of slides illustrative of the above remarks O was exhibited at the meeting. MICROSCOPICAL AND NATURAL HISTORY SECTION. December 6th, 1869. John Watson, Esq., President of the Section, in the Chair. Mr. W Boyd Dawkins, M.A., F.R.S., was elected a member of the Section. Mr. Charles Bailey read a paper “ On Pollen, consi- dered as an Aid in the Differentiation of Species.” [This paper was afterwards read at the Ordinary Meeting of the Society, held December 28th, 1869. See page 51.] Mr. J. B. Dancer, F.R.A.S., read a short paper on some of the new Hydro-Carbon compounds from which he had ob- tained very beautiful polarising objects for the microscope. These were exhibited to the members, and a more detailed account promised when the experiments are complete. 55 Ordinary Meeting, January 11th, 1870. E. W. Binney, F.R.S., F.G.S., Vice-President, in the Chair. The Chairman said that he had observed at Cheetham Hill on the evening of Monday the 3rd inst. at 7-30 p.m., a singular display of the Aurora Borealis. It consisted of an arch of white light, four to five degrees in breadth, a little south of the zenith extending from east to west, and passing through the Pleiades ; and a column of a deep crim- son colour, nearly due north, extending from the horizon to about 40° altitude, having slightly the character of streamers. The white arch also moved slowly to the south. The intensity of the red colour in the pillar was greater than any he had previously observed. Dr. Joule, F.B.S., said he had not seen the aurora of the 3rd instant, referred to by the Chairman, but having been engaged on the same day in making observations with his new dip circle, he had noticed some remarkable disturbances of the magnetic dip which no doubt were connected with the auroral display. He had also noticed similar disturb- ances of the dipping needle during the gale on Saturday, the 8th instant. The following letters addressed to the President were read by one of the Secretaries : — Belmont, Monk Bretton, Barnsley, December 31st, 1869. Sir, — I have just seen in “Nature,” No. 7, a notice of a paper read by Mr. Binney, on November 17th, 1869, before Pkoceidings— Lit. & Phil. Society. — Vol. IX.— No. 8.— Session 1869-70. 56 the Literary and Philosophical Society of Manchester, on the nature of the boundary between the Carboniferous and the Triassic or Permian rocks of Cheshire. The subject is of the highest importance from both a scientific arid economical point of view, and though Mr. Binney does not exactly agree with the results arrived at by my colleagues on the Geological Survey and myself I am very well pleased that he has called attention to the matter. Though Mr. Binney has spoken very modestly of the value of his labours, I need hardly say that the criticisms of a gentleman of such large local experience are always welcomed by us. Remarks coming from such a quarter demand an answer, and so give us a favourable opportunity of bringing before the public the results of our labours, and restating more fully our views. I venture to think however that Mr. Binney has scarcely acted in a manner worthy of his great and well deserved reputation, when he attempts to settle the geology of an obscure tract of ground by the evidence afforded in that tract alone, and neglects the light thrown upon its structure by an examination of adjoining districts. I shall try and avoid this error, and begin my examination of the evidence at a point south of Congleton. Between this point and Macclesfield a number of sections were obtained along the boundary, the most important of which are figured by myself in Figs. 1 — 4 of the Geological Survey Memoir on the country round Stockport, Macclesfield, Congleton and Leek. These sections are faithful representations of ivhat was actually seen , and in no case has any attempt been made to fill up hypothetically gaps where the rocks were hidden from view. In one case, Fig. 2, I actually saw the 57 fault : and 1 do not think that the lie of the rocks in the other sections can be explained except on the supposition that the boundary is faulted. The accounts of the colliers at Macclesfield also led me to the same conclusion. As far north then as Macclesfield I think the evidence is conclusive for the boundary being a fault : northwards from this town the fault decreases in throw and at last dies out, and the boundary becomes an overlap. The point in dispute is — Where does the change happen ? The following considerations led us to conclude that the boundary continues to be a fault for some distance to the north of Macclesfield. 1st. Though we have not data for estimating the exact amount of the throw at that time, a boring into the new red sandstone shows that it could not he less than sixty yards. A fault of this size will require some distance for its gradual decrease and final disappearance. 2nd. The boundary north of Macclesfield is remarkably straight, and is a direct continuation of the line, known to be a fault, which parts the two formations south of that town. Both these facts are in favour of the view taken by the Survey. I must deny altogether that there is any ground for the parallel drawn by Mr. Binney between the boundary we are now considering and the junction of the Carboniferous and Permian Rocks on the east of the Pennine Chain. The radical difference between the two is clear at a glance to any one who has learned to seize upon the geological meaning of physical features. In the latter case, the Per- mian beds rise, all along the junction, from the Carboniferous plain in a low hut well-marked escarpment, which winds 58 back down each valley, and throws out a projecting spur along each plot of rising ground. This configuration alone shows that the one formation rests on the other, without the intervention of a fault, and would be conclusive inde- pendently of the evidence given by natural sections and coal wakings. In the other case, the boundary line is straight and shows a marked disregard to hill or valley; and this, in the absence of any evidence to the contrary, would justify us in looking upon it as probably a fault. That Mr. Binney has brought forward any evidence to shew that it is not a fault, I cannot see. The boring at Brinnington seems to shew no more than this : that if there be a fault its throw is there probably small ; and this is just the view taken by the Geological Survey (see Memoir, already quoted, p. 11). You will, I am sure, be glad to give the Society the opportunity of hearing both sides of the question, and I therefore venture to request that this letter may be read before the next meeting. Possibly you may think it worth while printing it in your Transactions, as a note to Mr. Binney’s paper. — I am, yours, &c., A. IT. G&een. Geological Survey of Ireland, 51, Stephen’s Green, 4th January, 1870. Dear Sir, — From a copy of the “Manchester Guardian” of 1st December, 1869, forwarded to me by a friend, I find that Mr. Binney has called in question the correctness of the Geological Survey maps in representing the boundary between the Carboniferous and Permian and Triassic rocks, east of Stockport, as a fault, or dislocation of the beds. As far as I can understand, Mr. Binney’s argument rests upon the fact which he states, that coal has been reached below the red sandstone (which he calls new red sandstone, but which I believe to be permian sandstone) at Brinning- 59 ton. I wish to point out that this fact in no way invalidates the view which the Geological Surveyors have adopted ; but that the occurrence of coal at Brinnington under the sand- stone is quite compatible with the existence of a fault along the line of boundary to the eastward. A fault may produce a displacement of the beds of any indefinite amount, from one foot up to 5,000 — and the only effect of such a fault at the junction of the Carboniferous and Permian rocks at Brinnington, supposing the dip constant, would be to produce a greater or less vertical displacement of the beds, and to deepen the base of the red sandstone by that amount. On reference to the map of the Geological Survey it will be seen that at Harden Hall, and under the valley of the Tame to the northward, the boundary of the red sandstone is represented as a natural overlap, and not as a fault. That the red rock fault continues northward through the sandstone itself was, I think, proved at the col- liery worked some years since by Mr. Peten Higson, and I should be glad if this gentleman would give his views on the subject. From his statement I gathered that there was a fault to the westward of the pit, along which the beds were thrown into a vertical position. Further south, opposite Boynton Colliery, a tunnel was driven westward from one of the pits, which crossed a large fault, along which the measures were dislocated and oxidised. In the Appendix to the Memoir alluded to by Mr. Binney (“ On the Geology of the Country around Stockport, Maccles- field, &c.”) will be found an account of this fault as given me by Mr. Greenwell, F.G.S. There is every reason for supposing that this was “the red rock fault,” or one in proximity to it ; for a great fracture such as that I here refer to is often accompanied by minor dislocations. South of Macclesfield the fault was actually seen by Mr. Green, of the Geological Survey, who has represented the section by a figure in the Memoir (Fig. 2). From this spot the amount ■o 60 of “ throw,” or displacement, probably decreases northwards, and becomes of comparatively small amount east of Brin- nington. How far Mr. Binney’s strictures upon the character of the work executed by myself or my colleagues of the Geological Survey are deserved, I am quite willing to leave to the judgment of the public, but I cannot admit that he has shown any grounds for stating that there has been any want of care in the work. — I remain yours, &c. Edward Hull. The Chairman said he had a great respect for the opinion of Mr. Green, but neither he nor Mr. Hull, had produced any evidence of a “red rock fault” between Stockport and Macclesfield. The evidence afforded by the sections at Beat Bank Bridge, Brinnington, Fogbrook and Norbury, shewed that Permian or Triassic strata covered up previously elevated coal measures, but there were no signs of a fracture in the last named strata. Twenty years ago he had shewn this in memoirs published in the quarterly journal of the Geo- logical Society of London, and in the transactions of this Society. The natural sections are there to speak for them- selves and any one who felt an interest could go and judge for himself. Messrs. Hull and Green had impugned his published views, and he in return had denied the correctness of their map and sections so far as the “ red rock fault ” was concerned. Of course if is well known to all persons con- versant with the subject that the numerous faults which intersect the coal measures extend equally, when those strata disappear under Permian and Triassic beds, and that the latter frequently lie in great dislocations of the former, but these are very different things from the straight north and south “ red rock fault ” laid down on the Survey Map between Macclesfield and Stockport. He did not wish to follow Mr. Green further south than Macclesfield, but he strongly suspected that Triassic strata 61 covered up Carboniferous beds between Leek and Rocester much in the same way as Permian strata overlapped Carboniferous between Knaresborough and Bramham Park, Yorkshire. He had given his views to the public, and there was no further occasion to occupy the time of the Society, but he might state that, he was prepared to main- tain his position on the ground where the sections were exposed between Stockport and Macclesfield. Dr. Joule, F.R.S., exhibited his current meter, and with it, in connexion with a galvanometer, made an experiment to determine the horizontal intensity of the earth’s magnetism in absolute measure; the result gave 3'83 as the value of this element in the hall of the Society. The current employed was produced by a single cell of a Bunsen’s battery. MICROSCOPICAL AND NATURAL HISTORY SECTION. January 3rd, 1870. R. D. Darbishire, B.A., F.G.S., in the Chair. Dr. Wm. Roberts exhibited some specimens of urinary calculi, composed of cystine ; also some crystals of the same, obtained by evaporation in the open air of the ammoniacal solution. Six-sided plates of mother-of-pearl lustre were obtained in this way, which formed brilliant objects for the microscope. 62 Dr. Roberts remarked on the great rarity of cystine calculi, many large museums not possessing a single specimen. He had in his own collection three specimens, and in the museum of the Manchester School of Medicine there were portions of two very fine calculi. A certain historical interest attached to one of the latter, a piece of which was presented by the late Mr. Ransome, to Baron Leibig, during one of his visits to Manchester. The analysis of this piece led to the rectification of a curious error in the original formula for cystine, published by Front and Lassaigne ; these eminent chemists had deduced the formula C6H6N08, but the Giessen analysis discovered 20 per cent of sulphur, which brought the true formula to C6H6NS204, the two atoms of sulphur having been before erroneously reckoned as four atoms of oxygen. Mr. J. Sidebotham read the following paper : — “ Notes on the pupa and imago of Acherontia atropos.” The peculiar cry or squeak of the death’s head moth is very well known, and in conjunction with the mark of a human skull on its thorax, has no doubt contributed to pro- duce the aversion and terror with which the insect is regarded by the ignorant and superstitious. No other Lepidoptera are known to utter any cry whatever, and although many scientific men have engaged in the inquiry, it is still uncertain how the moth produces the sound. This may seem strange, but as the only observations which can be made on the living creature are confined to the outer organs, it can only be proved that the sound is not produced by the wings, proboscis, palpi, legs or antennae. These can be separately or together confined, and still the sound is produced, and as to dissection of the insect when dead, the only results to be arrived at, are that the sound may be produced by certain organs, not that it is. It has been by some observers thought this sound is produced by 63 the friction of the joints of the pro thorax and mesothorax; this conclusion is, I think, much strengthened by the follow- ing circumstance : — A few weeks ago, when I was replacing some damp moss on some pupge, I heard the peculiar cry of the moth, but much weaker. On examining the pupse I soon selected the one from which the cry proceeded and placed it in the palm of my hand ; when at rest there was no sound, but the pupa at once produced it on being touched or pressed gently; on taking hold of it between the finger and thumb, if the head alone were confined, there was no sound, but if the tail, the motion of the joints was more energetic and the sound louder. In five days afterwards a very fine female moth emerged from the pupa, apparently none the worse for my experi- ments. Nothing beyond the bare fact of the pupa of Atropos sometimes uttering the sound has, I believe, been previously recorded, and it must be very rarely that it does so, as although I have reared scores of the moths I have never observed it before, nor do I know anyone who has done so. The fact of the pupa ever producing this cry must, I think, disprove all the ideas as to its being produced by expelling air through cavities, against a membrane, since in the pupa state all the muscles are as it were bound up in a horny case, and only those able to move which work the joints of the thorax and body, and besides this the amount of air which could be taken through the spiracles of the pupa would be obviously insufficient to produce such a volume of sound. It may be of interest to some of the members to know the plan I adopt in rearing Atropos from pupae. I take a large flower pot and fill it about one-third with light soil, on this I place the pupae, and cover them with damp moss ; on this pot I invert another of the same size, wrap these 64 round with several folds of flannel, and place them near the hot water pipes in the hothouse, damping the moss three or four times a week with warm water. By this plan I have been very successful, and have only had one specimen this year otherwise than quite perfect. Mr. W. Boyd Dawkins, F.R.S., sent for exhibition some very interesting microscopic sections of Eozoon Canadense, which are the more valuable as being those which have passed through the hands of Sir W. E. Logan and Dr. Carpenter. Mr. J. B. Dancek, F.R.A.S., presented the Section with a box containing twelve new polarizing objects. These partly consisted of some of the hard fatty acids which form very effective objects, and partly of crystalizations of some of the hydro-carbon compounds which compete with the best specimens of polarizing objects of the present day. Ordinary Meeting, January 25th, 1870. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair, “ On Organic Matter in the Air/’ by Dr. R. Angus Smith, F.R.S. &c. I have worked and written so constantly on impurities in air and water, that last year I was told by a periodical of high position that I was quite regardless of the impression made on timid persons, and I began to compare myself to a collector of “ varieties,” who is often obliged to bring up his curiosities every five years. When I read of the new experi- ment by Professor Tyndall, showing to the naked eye the numberless bodies in the air, I was abundantly gratified, as I obtain them only by a laborious although simple process. When however Dr. Tyndall began to show the character of these bodies it “ smote the chord of self,” as I imagined that I had long ago proved that not only organic and inorganic, but organised forms exist in the atmosphere. Neither do I claim this as my original idea, looking rather to the fulness of proof and quantitative results as mine. I think therefore I may remind my friends of some of my work, as I find that they forget, and even I forget the exact words used by myself, and must read up. Proceedings — Lit. &Phil. Sooiety.— Vol. IX.— No. 9.— Session 1869=70, 66 But as people don’t read much on a subject, I will begin at the end. I have been for two years attempting to measure the amount of putrescible matter in the air ol the towns and country places, and I have succeeded to a considerable extent. I also measure the amount that has putrefied and left its remains in the air— -the sewage of the atmosphere. Some of my results are published; I have promised some very soon, and some have been ready for printing, under the head of Chemical Climatology. The proof of organic matter is old. I seek the quantity in various towns and parts of towns. I shall not here give a history of the enquiries. So many people claim to have something to say in the matter, that I might amuse myself, if not the public, by a long account. At present I profess to keep almost entirely to my own work. The knowledge of organic matter in the air has never been absent entirely from men’s minds in historic times ; but the words of Bishop Berkeley are so clear that I prefer to quote them. Besides he is far enough back for the purpose. He says in Siris (par. 140) : — “Nothing ferments, vegetates, or putrefies without air, which operates with all the virtues of the bodies included in it, that is, of all nature. * * * The air, therefore, is an active mass of numberless different principles, the general sources of corruption and generation; on the one hand, dividing, abrading, and carrying off the particles of bodies, that is, corrupting or dissolving them ; on the other, pro- ducing new ones into being, destroying and bestowing forms without intermission.” And in paragraph 141 he says : — “ The seeds of things seem to be latent in the air, ready to pair, and produce their kind whenever they light on a proper matrix. The extremely small seeds of ferns, mosses, mushrooms, and some other plants, are concealed and wafted \ ' 67 about in the air, every part whereof seems replete with seeds of one kind or other The whole atmosphere seems alive. There is everywhere acid to corrode and seed to engender. Iron will rust and mould will grow in all places.” No man has before or after him expressed this truth more completely and beautifully. It is hard to improve it by one word. Still, this age demands more detailed know- ledge and exact theory ; besides, the work of every few years requires to be done again to suit modern methods, although it must be confessed that there is room for the cynic to say that Bishop Berkeley and all the ancients and moderns might be classed with Topsy who think they have explained all by saying “ It grows.” I began to examine the air in 1846, and I brought a short notice before the Chemical Society : ‘ a simple mode of obtaining organic matter in the condensed breath on windows is recorded in their transactions. On account of this commencement, which promised favourably, the British Association requested me to report on the subject. My report, published in 1848, was considered to have made advance, and was marked out for special mention by the President of the succeeding year, so that the words were not hidden. I quote a part, “ That animals constantly give out a quantity of solid organic matter from the lungs, may readily be proved by breathing through a tube into a bottle, when the liquid or condensed breath will be collected at the bottom of the bottle ; or by breathing through a tube into water, when a solution of the same substance will be found in the water. This would scarcely require proof if we consider that breath so frequently has an organic smell.” “ If this condensed breath be put on a piece of platinum, or on a piece of white porcelain and burnt, the charcoal which remains and the smell of organic matter will be con- 68 elusive. If it be allowed to stand for a few days (about a week is enough), it will then show itself more decidedly by becoming the abode of small animals. These are rather to be styled animalcules, and very small ones certainly, unless a considerable quantity of liquid be obtained : they may be seen with a good microscope. Animalcules are now generally believed to come from the atmosphere and to deposit themselves on convenient feeding places ; that is, they only appear where there is food or materials for their growth, and they prove of course the existence of that con- tinuation of elements necessary for organic life. At the same time their presence is a proof of decomposing matter, as their production is one of the various ways in which organized structure may be broken up.” “I mentioned some time ago that I had got a quantity of organic matter from the windows of a crowded room, and I have since frequently repeated the experiment. This matter condenses on the glass and walls in cold weather, and may be taken up by means of a pipette. If allowed to stand some time it forms a thick, apparently glutinous mass; but when this is examined by a microscope, it is seen to be a closely matted confervoid growth, or in other words, the organic matter is converted into confervse, as it probably would have been converted into any kind of vegetation that happened to take root. Between the stalks of these confervse are to be seen a number of greenish globules constantly moving about, various species of Volvox, accompanied also by monads many times smaller. When this happens the scene is certainly lively and the sight beautiful, but before this occurs the odour of perspiration may be distinctly per- ceived, especially if the vessel containing the liquid be placed in boiling water. “If air be passed through water a certain amount of this material is obtained, but I have found it difficult to pass a 69 sufficient quantity through. If it is made to pass rapidly, absorption does not take place , and evaporation of the water is the consequence; if it passes slowly, it requires several weeks to pass a hundred cubic feet through a small quantity of water. I continued the experiment for three months, but although I obtained sulphuric acid, chlorine, and a substance resembling impure albumen, I did not get enough to make a complete examination; and indeed this could not be expected, as I found that in that time less than a thousand gallons of air had passed through. “When this exhalation from animals is condensed on a cold body, it in course of time dries up, and leaves a some- what gelatinous organic plaster; we often see a substance of this nature on the furniture of dirty houses, and in this case there is always a disagreeable smell perceptible.” — Mems.: Brit . Association , Meeting held in August , 18 AS. I quote the words used by the President of the Associa- tion simply to show that the paper was well known : “ F or instance, the causes which in our great cities hasten the death and debase and embitter the life of so many, have at last been forced by chemists and physiologists on the notice of the public. Look at Dr. Smith’s report on the air and water of towns, in this volume ; and when we think that the victims of the deadly influences which are there revealed are chiefly found among the people whose industry is the foundation of our greatness, — that every year cut off from the life of each of these is so much subtracted from national wealth, — even were all moral sense and religious feeling dead in us, we must confess that the knowledge which is capable of averting them ‘ is of use.’ ” Looking over these words at this distance of time it seems to me scarcely possible to write more clearly, although some of the words I should prefer to see changed. Still the subject was a continued study, and it was my strong desire to measure exactly the amount of organic matter. 70 Not to detail all the attempts, I may come to the report to the Cattle Plague Commission in 1866, in which I give some general views and allude to the works of others. The following may he quoted : — “ It has often been asked — Will a sewer produce cholera, or plague, or cattle disease ? We cannot say so, or that every kind of disease may be produced from such accumu- lations of organic matter. The great epidemics that have passed over Europe seem always to have come from some extraneous source, to act as if planted by some seed , and not to have risen up spontaneously here. Without attempt- ing to examine this matter carefully, the result would seem to be, that whilst the decomposition of organized beings after death produces gases and vapours that are opposed to health, these gases or vapours are incapable of originating, although they may be capable of feeding, some of those diseases, such as cholera or plague, which have been observed at all times to come from a warmer climate. There must, however, be some first origin of these diseases, and we cannot prove that the first origin might not take place in our climate, although it seems probable that it requires a warmer sun and a richer vegetation than is to be found in the north. This, however, is sufficiently made out — that, when these diseases do come amongst us, they take root with most effect in those places where decomposing matter is found. If we were to suppose a seed of disease planted in a rich, fertile soil of decomposing matter, we should give a pretty fair description of the fostering effect of impurity on disease. It would in fact appear as if the putrid matter itself took the disease, and transferred it to the living. There seems to be nothing entirely opposed to this view of the case. The question, however, is and has always been — What is the nature of that substance which may be said to form the seed or germ of the disease ? Chemists have been inclined to consider it a substance in 71 process of decay, as the quotation from Liebig already given shows. Physiologists and microscopists have been more inclined to consider it as an organised substance. When Gay Lussac passed a bubble of air into the juice of grapes, and found that fermentation began at once, it was believed that the oxygen was the prime mover, and that, when once begun, the action did not cease. When, however, Dusch and Schroeder found that flesh did not decompose if the air was previously passed through a good filter of cotton wool, some difficulty was thrown on the subject. It would appear as if oxygen were not the only agent in the atmosphere causing decomposition. The investigations of M. Pasteur, who found the subject in this uncertain con- dition, have advanced it so far that we may now with certainty reason in the belief that organized substances are really found in great abundance in the atmosphere (in all places), and that they are the cause of some hitherto entirely mysterious phenomena, putrefaction included. His object was first to inquire into the possibility of spontaneous genera- tion, and he found that carefully filtered air allowed no organisms to appear in vegetable solutions, He found that near the usual surface of the ground these organisms were so numerous that whenever a vessel containing vegetable matter fit for their growth was opened for a very short time they were found to enter, that in cellars and damp and quiet places, where there was no air or dust floating about, these organisms were fewer, and that, as he ascended the sides of the Alps and the Jura, they diminished in number. A commission of the French Academy confirmed his results. If *we examine previous enquiries into the compounds resulting from the decomposition of organic substances, we shall find nothing which is at all calculated to bring out such an intelligible rational view of the origin of many diseases, and also of some phases of putrefaction. Chemists, when they have examined products of the latter action 72 have found sulphuretted hydrogen, carburetted hydrogen, hydrogen, carbonic acid, nitrogen, hydrogen, ammonia, acetic acid, lactic acid, butyric acid, and numerous uncertain bodies having no activity, and utterly incapable of produc- ing those prodigious results that are found when that force begins to work which produces plague, small-pox, or black death.” I did not enter on Pasteur’s ground, — the action of organ- isms in producing fermentation. After these opinions and the detail of many facts one is mentioned which was the culminating point of the enquiry, and has led to a mode of collecting the organic particles of air, which I may call established. This word established is used because the experiment has been done by others. It is given in these few but plain words : “ The air of cow- houses and stables is to be recognised as containing more particles than the air of the street in which my laboratory is, and of the room in which I sit, and that it contains minute bodies, which sometimes move, if not at first, yet after a time, even if the bottle has not been opened in the interval. There is found in reality a considerable mass of debris with hairs or fine fibres, which even the eye, or at least a good pocket lens, can detect. After making about two dozen trials, we have not been able to obtain it other- wise. Even in the quiet office at the laboratory there seemed some indications.” “ I found similar indications in a cowhouse with healthy cows ; so I do not pretend to have distinguished the poison of Cattle Plague in these forms ; but it is clear that where these exist there may be room for any ferment or fomites of disease; and I do not doubt that one class is the poison itself in its earliest stage. It would be interesting to de- velope it farther.” I do not detail the examination made of the condensed air brought from a cowhouse by Mr. Crookes, nor do I detail 73 ilie examination of the cotton through which Mr. Crookes had passed the air, nor the glycerine surfaces exposed to the air of cowhouses, which also was done by Mr. Crookes. My object at present is not to give a history, but a few of the prominent points so far as relates solely to my own part. These experiments were repeated on air in Manchester. A paper was read on the 30th March, 1868, to the Lit. and Phil. Society, Manchester. Dr. Scliunck in the Chair. To quote a part — “ Lately I tried the same plan on a larger scale. A bottle of the capacity of 4'990e.c. was filled with air and shaken with water. The bottle was again filled and shaken with the same water, and this was repeated 500 times, nearly equal to 2J millions cb.c., or 2*495 litres. As this could not be done in a short time, there was considerable variety of weather, but chiefly dry with a westerly wind. The ope- ration was conducted behind my laboratory, in the neigh- bourhood of places not very clear, it is true, but from which the wind was blowing to ?J1 parts of the town. I did not observe any dust blowing, but if there were dust, it was such as we may be called on to breathe. The liquid was clouded, and the unaided eye could perceive that par- ticles very light were floating. When examined by a microscope the scene was varied in a very high degree — there was evidently organic life. I thought it better to carry the whole to Mr. Dancer, and to leave him to do the rest, as my knowledge of microscopic forms is so trifling compared to his.” Having for years therefore convinced myself of these results, I took the air washings to Mr. Dancer, of Manches- ter, whose experience in microscopic objects is so great that I was certain to be corrected if I erred, and if I did not err I should be taught more. His examination is very beautiful, and it shews not only organic substances, but very 74 many in quality and inconceivably many as to quantity. The whole cannot be quoted, but the following will suffice. “The water was first examined with a power of 50 diameters only, for the purpose of getting a general know- ledge of its contents. Afterwards magnifying powers varying from 120 to 1,600 diameters were employed. “ During the first observations, few living organisms were noticed ; but, as it afterwards proved, the germs of plant and animal life (probably in a dormant condition) were present. “1st. Fungoid Matter. — Spores or sporidise appeared in numbers, and, to ascertain as nearly as possible the numerical proportion of these minute bodies in a single drop of the fluid, the contents of the bottle were well shaken, and then one drop was taken up with a pipette ; this was spread out by compression to a circle half an inch in diameter. A magnifying power was then employed which gave a field of view of an area exactly 100th of an inch in diameter, and it was found that more than 100 spores were contained in this space ; consequently, the average number of spores in a single drop would be 250,000. “ On the third day a number of ciliated zoospores were observed moving freely among the sporidise. “Some of this formed a very interesting object, with a high power, and the greater portion exhibited what is called pitted structure. The larger particles of this had evidently been partially burnt and quite brown in colour, and were from coniferous plants, showing with great distinctness the broad marginal bands surrounding the pits; others had reticulations small in diameter. They reminded me of perforated particles so abundant in some kinds of coal. “Along with these reticulated objects were fragments of vegetation, resembling in structure hay and straw and hay seeds, and some extremely thin and transparent tissue showing no structure. “ A few hairs of leaves of plants and fibres, similar in ap-. pearance to flax, were seen, and as might have been expected in this city, cotton filaments, some white, others coloured, were numerous ; red and blue being the predominant colours. A few granules of starch, seen by the aid of the poloriscope, and several long elliptical bodies, similar to the pollen of the lily, were noticed. After this dust from the atmosphere had been kept quiet for three or four days, ani- malculse made their appearance in considerable numbers, the monads being the most numerous. Amongst these were noticed some comparatively large specimens of paramecium aurelia, in company with some very active rotiferse; but after a few days the animal life rapidly decreased, and in twelve days no animalculse could be detected. “For the purpose of obtaining a rough approximation of the number of spores or germs of organic matter contained in the fluid received from Dr. Smith, I measured a quan- tity by the pipette, and found it contained 150 drops of the size used in each examination. Now I have previously stated that in each drop there were about 250,000 of these spores, and as there were 150 drops the sum total reaches the startling number of 37 J millions.” After these examples, the first being twenty-four years earlier than the last, I need not add that my certain know- ledge is that particles both organic and inorganic are found in air. Further, that some of the organic particles are organized. Lime, soda, sulphates, and chlorides have been mentioned in another paper as being found, coal ash and of course car- bon, and to some extent the amount measured. In railway carriages we even breathe rolled plates of metallic iron which are large enough to be seen by the naked eye. Some of the most difficult particles to remove are those of coal smoke, they are oily or tarry or both. These are in- stances of organic and not organised particles. For two years I have been endeavouring to measure with certainty the amount of nitrogen in the organic matter, separating it from the inorganic. Some of the results are in the last “ Report of the Proceedings under the Alkali Act/’ and have been pretty extensively published. Other results are soon to be published. I have not yet spoken of my work, “ On the Air of Mines,” where drawings of the particles of solid matter are given (in a long report published by the Mines Commission in 1864), because the air was from exceptional places. Still similar results are got above ground. In the small tubes containing air from the mines and solids I was able to detect very distinctly organic matter and to measure the ammonia. Still the best proofs are in the sight of actual forms and the moving objects. In finding these with many accessories I consider their existence in the air of such places as were tried proved beyond all doubt, also long ago proved. We now require good microscopists to examine the individual forms and to find if every disease has one peculiar to itself, as Mr. Bailey finds every class of plants has its own peculiar pollen. That is probably the next most prolific field for those who desire something move on the subject. We must not be panic-stricken because of these forms. Some are hurtful, but it may be that others are required for the maintenance of healthy animal life of the highest order, exactly as in vegetable fermentation. We must purify the air within the limits of natural intention, and be careful that we do not overstep its boundaries. Professor Williamson, F.R.S., exhibited some specimens affording additional information in reference to the organi- sation of Catamites. Through the perseverance of his fellow-labourer Mr. Butterworth, he had now obtained, what he had some time ago expected to do, examples whose struc- 77 ture was intermediate between that of Calamodendron and Calamopitus. In the general arrangement of their separate parts these new specimens corresponded most closely with the well known type figured by Mr. Binney ; but they differ in two important particulars. All their fibrovascular tis- sues are of the reticulate type seen in Calamopitus and Dictyoxylon. with here and there a few scalariform vessels interspersed. The cellular laminae separating the vascular wedges again exhibit remarkable variations even in the same specimen; their cells being sometimes elongated into vertical forms of prosenchyma — at others they are extended trans- versely, parallel to a tangential section — whilst still more fre- quently they consist of ordinary parenchyma. In another feature also the specimens exhibit considerable variations In some the fibro-vascular tissues of the vascular wedges are separated by masses of cellular tissue, not only at the nodes but also at the internodes. These tissues which, viewed physio- logically, can only be regarded as modified medullary rays, are so numerous in one example that more than two vertical vessels can rarely be found in contact without the interven- tion of one of these vertical rows of mural cellular tissue. In some other examples these medullary rays are much more scanty, as if connecting the type under consideration with that figured by Mr. Binney. The verticillate medullary radii of Calamopitus are wholly wanting in these new ex- amples. Additional proof is thus afforded that all the three types referred to may be but variations, possibly having no more than specific value, and perhaps not always even that, of the common type of Calamodendron : and it thus becomes increasingly demonstrable that in the Lancashire coalfield, whatever may be the case elsewhere, we have no evidence of the existence of an Equisetiform type of Calamite distinct from the Calamodendroid one. Professor Williamson further announced the discovery by Mr. Butterworth of a young Calamite in which the cortical 78 layer is well preserved. This important fact has long been a desideratum in connection with English Palseo-phytology. This investing layer proves to be, as Professor Williamson in his previous memoir on Calamopitus had suggested was probably the case, a pareuchyma of somewhat remarkable structure, and of a thickness equal to that of the ligneous zone which it invests. But as the investigation of this new tissue is not yet completed, all further description of it must be reserved for some future occasion. “On the so-called Molecular Movements of Microscopic Particles,” by Professor Wm. Stanley Jevgns, M.A. Robert Brown, the celebrated botanist, first pointed out, in the year 1827, that minute particles of unorganized matter suspended in water exhibit movements which may easily be mistaken, and were formerly mistaken, for the movements of living animalcules. This motion is exhibited more or less by all substances which are reduced to a sufficiently fine state of division (5oVo inch in linear mag- nitude to 50000), and the phenomenon is familiar to all occupied in microscopic observation. Vague suggestions have been often put forth that the motion is due to heat, to electricity, or to chemical affinity, but I have been able to find few published experiments on the subject, and those not of a conclusive kind. In investigating this phenomenon, I did not learn much by varying the solid suspended substance. The silicates, indeed, appeared to be generally the most active substances, and the purest quartz crystal when reduced to fine powder oscillated rapidly ; but such different substances as charcoal, red phosphorus, antimony, and sulphur were also very active. I cannot affirm that any substance is free from movement, but the metallic oxides, and the earthy salts such as car- 79 bonate of lime, appeared to me somewhat less active in comparison. In varying the liquid, however, by dissolving different salts therein, I was soon struck by the fact that the purest distilled water alone gave the movement in the highest perfection. With a few exceptions, soon to be noticed, all acids, alkalis, or salts tended to diminish the movement in a manner wholly independent of their peculiar chemical- qualities. The inquiry was much facilitated by discovering that the microscopic movement is closely connected with the suspension of fine powder in water.* Clay and pounded glass which are most active in the microscope are also capable of remaining long in suspension. All acids, alkalis, or salts which checked the motion under the microscope were found also to have a power which has not been sufficiently noticed, of precipitating suspended matter. At the same time gum arabic, which possesses a most extra- ordinary power of exciting the molecular movement, is also capable of maintaining powder in suspension, and has long been used for this purpose in the manufacture of ink. The molecular motion does not directly affect the gravity of the particles, but it prevents the particles from aggregating together into larger bodies and thus overcoming the resist- ance of the liquid. That the motion is due to electricity I was soon con- vinced, by the close analogy with the circumstances in which electricity is produced by the hydro-electric machine. Armstrong and Faraday found that pure water in this machine alone produced much electricity, and that almost any salt, acid, or alkali prevented the action by rendering the water a conductor. Ammonia, however, is a remarkable * I have since found that the microscopist Dujardin noticed this connec- tion. See “ Manuel Complet de l’observateur au Microscope.” Paris, 1843, p. 60. 80 exception, because it does not render water a good con- ductor, and does not prevent the hydro-electric machine from giving off electricity. In trying ammonia as an experimentum crucis, I found that it did not stop the mi- croscopic movement, and had almost an inappreciable effect in precipitating suspended matter. A solution of 10 per cent, of ammonia would have less effect than too per cent, of sulphuric acid. The proof is rendered practically certain by the fact that boracic acid which was also ascertained to be a non-conductor by Faraday, does not precipitate matter from suspension. It is right to add, however, that in the case of acetic acid there is a discrepancy; Faraday stated that it does not render water a conductor ; but I find that in common with the other vegetable acids which I have tried it occasions precipitation. The conducting qualities of the substance have not been determined with sufficient accuracy to render a mistake impossible. It is probable that silicic acid does not render water a conductor, as I find that silicate of soda tends to increase * rather than diminish microscopic movement, and is another remarkable exception to the general precipitating power of soluble substances. I entertain no doubt that microscopic movement is closely connected with the phenomena of osmose so fully investi- gated by the late Mr. Graham. The connection is that of action and reaction ; for if a liquid is capable of impelling a particle in a given direction, the particle if fixed is capable of impelling the liquid in an opposite direction by an equal force. The earthenware jars used by Graham in many of 81 his experiments are composed of a substance highly active under the microscope, and the fact that osmose is most shown by very dilute solutions (1 p.c. or less) is entirely in accordance with the electric origin of the phenomenon. I consider it to be established experimentally that the microscopic movement is due to electric action, and if I may venture to suggest a somewhat speculative explanation of the action I would point to the experiments of M. Wiede- mann on electric osmose. It was first observed by Mr. Porret that when the poles of a battery are placed in two portions of water separated by a porous division, not only is some of the water decomposed, but another and far larger portion is impelled towards the negative pole. M. Wiedemann having exactly investigated the phenomenon found that for one part of water decomposed 5,000 parts were transported through the porous septum. This impulsion is greater as the resistance of the liquid is greater, and ceases altogether when sufficient acid or salt is added to render it a good conductor. Every particle which is thrown into a polar condition by the action of water must be capable in a minute degree of exerting a similar force. In ordinary osmose the particles being fixed cause a transportation of the fluid ; in microscopic movement, on the other hand, the particle is free to move, and the reaction of the liquid probably produces those movements which are visible in the microscope. Although I have chiefly confined my attention to in- organic substances, I have also found that all organic solid particles which are sufficiently small exhibit the movements in a high degree. Albumen, dextrin, grape or cane sugar, 82 starch solution, alcohol, &c., seem to have little or no power of destroying the motion ; and the extraordinaiy properties of gum arabic have been noticed. I think it not unlikely that when these phenomena are fully investigated they will give strong support to a theory lately put forward by M. Becquerel, that the movements of fluids in animals and plants, which have often been attributed by Graham and others to osmose, are really due to minute electric currents. Mr. Dancer, F.R.A.S., stated, that the subject which Pro- fessor Jevons brought before the meeting, was one to which he had paid attention at intervals for the last thirty years. He had repeated Dr. Robert Brown’s experiments with the majority of the substances named in his paper, and had also experimented with a great number of other substances and different solutions. The particles approaching a spherical form gave evidence of the greatest activity, with some few exceptions. The activity and duration of the movements vary according to their magnitude and also the solution in which they are suspended. For instance some of the metallic oxides would exhibit the movement for some time, and then gradually get aground on the glass plate, and cease to move. There was some difficulty in reducing metals to particles sufficiently small and regular in form, for the exhibition of the molecular movement ; even hardened steel, when rubbed on a very fine hone, appears fibrous, and soft metals such as platinum and copper, like shavings, under a high magnifying power. Those siliceous particles of the hone which have their lines of cleavage favourably situated are frequently detached in thin plates during the act of grinding and form 83 brilliant objects when viewed by polarised light. Metals reduced in this manner require re-grinding several times before they lose their fibrous character, and become suffi- ciently minute for successful experiments. Metallic oxides vary considerably in their form and magnitude, according to the solutions from which they are precipitated. By practice it would be possible in many cases, by their microscopical appearance, to name the solu- tions from which they had been precipitated. The activity of these, when of favourable size, say from the s-o&ooth to Toovoth of an inch, is very different, being great in water, solution of gum, sugar, &c., but quite inactive in oil. Mercury and sulphur when sublimed assume a spherical form, and although these spheres could be obtained from ToVoth to 5 o o o oth of an inch in diameter, they do not exhibit any movement in water. He has sublimed them on to a drop of water, but they refused to sink. Possibly their polished surfaces retained a film of air which floated them. So transparent and perfect in form are the sulphur spheres that they distinctly exhibited the image of a lamp flame at their focal point. Triturated or precipitated sulphur will exhibit active movement in various solutions. As regards the cause of this so-called molecular movement, Mr. Dancer thinks that chemical action will not account for it. Diamond dust, graphite, and other refractory substances, are found to be active in water and solutions of gum. Nor is electricity a satisfactory explanation to him. He has found that parti- cles did not show a marked alteration in their movements, when exposed to electrical influence. The results of many experiments point to heat as a probable cause, and although 84 the peculiar movements of these particles appear like elec- trical attraction and repulsion, similar movements might be caused by the changes of temperature of the particles, transmitted through the solutions. “ On a General System of Numerically Definite Reason- ing,” by Professor William Stanley Jevons, M.A. The system of numerical reasoning described in this paper arises from the combination of arithmetical or algebraical calculation with logical reasoning. Its purpose is to deter- mine as far as possible the numbers of individual objects which may compose classes or groups of objects under any given logical conditions, the data consisting in those logical conditions and the numbers of individuals in certain other related classes. 85 Ordinary Meeting, February 8th, 1870. J. P. Joule, LL.D., F.R.S., &c., President, in the Chair. E. W. Binney, F.R.S., F.G.S., said that in Vol. III., page 14, of the Society’s Proceedings, he had noticed the occur- rence of stray boulders without traces of clay, high up the western slopes of the Pennine chain, and he described one at the extreme end of the valley of the Tame near New Year’s Bridge, above Denshaw, in Saddleworth. Many years since he had observed large blocks of greenstone without any clay or sand on Pikelow, to the east of Macclesfield. Both these places were about 1,000 feet above the level of the sea. Mr. A. H. Green, M.A., F.G.S., and his colleagues/ in their valuable memoir on the Carboniferous Limestone, Yoredale Rocks, and Millstone Grit of North Derbyshire and the adjoining parts of Yorkshire, just published by the Geo- logical Survey, after describing some stray boulders found by himself and Mr. Sorby, F.R.S., near Rotherham and Shef- field, at p. 133 says, “ Our knowledge of the portion of the eastern plain from Sheffield through Chesterfield down to Belper is meagre ; we believe we are right in representing as in the main free from drift, but whether any isolated patches or erratics are to be found in it we cannot say.” During a residence of five or six years he (Mr. B.) had often searched for these boulders in the neighbourhood of Chester- field. The only foreign rock which he met with in that district was a large block of greenstone several hundred pounds in weight. This he found above the valley of the Hipper near Spring Bank and below the Waterworks station, Chester- field. The stone was well rounded and polished. He men- tioned the fact to direct the attention of observers to this Proceedings — Lit. & Phil. Society,— Yol. IX.— No. 10. — Session 1869-70. 86 subject on both the eastern and western slopes of the Pen- nine chain. Probably they have only to be more diligently sought for in order to be found in greater abundance. “On Convertent Functions/’ by Sir James Cockle, F.R.S., President of the Queensland Philosophical Society. Communicated by the Rev. Robert Harley, F.R.S. The present paper is a supplement to my paper “ On Con- vertent Functions,” printed in the Proceedings [supra, vol. VIII., pp. 2 — 3). The convertent equation (3) contains in substance only one disposable arbitrary, and the sign of summation S does not increase, and may be expunged from it without diminishing, its generality. Consequently the process would fail to convert the Boolian integral for the cubic and lead only to illusory results. But a recognition of this failure has led me to another form of convertent equation. And, first, if to the several dexters of (2) and (3) we add a term h, then the conversion will be possible, even though h be not a perfect differential coefficient, provided only that fhdu be assignable within the limits of the inte- gration. But the following is the mode in which I wish to present the process with reference to a class of integrals wherein all the Boolians are included. Suppose that we seek to convert fym v)dv where full and interesting account of the struc- ture of one of these stems, the Stigmaphyllon emarginatum 94 (“Mdmoire,” &c., pp. 103, &c.,) and Gaudichaud (“Recher- ches,” &c., pi. xviii., fig. 11, p. 129,) figures an allied species, but I have not, as yet, identified either amongst those coining with cotton. I exhibit however a stem which ap- pears to be the Tetrapterys Guilleminiana , referred to by Jussieu, and figured by him in his monograph, plate iii., fig, 5, p. 106; but this species does not exhibit the sinuosities so characteristic of most of the lianas of this family. As a general rule, the woody matter is developed un- equally round the central pith in the form of irregular lobes, the bark closely following all the sinuosities of the stem. If the lobes increase on one side of the stem only, the pith soon becomes eccentric ; but, on the other hand, in many species, while the pith retains its central position, the irregular growth of the woody lobes — each of which is closely invested by the bark— causes some to grow beyond their neighbours, and these latter, in the progress of growth, become imbedded, with their bark, in the midst of the woody matter produced by the more vigorous lobes. A stem in this adult state therefore presents the greatest irregularity of form particularly in the genera Banisteria and Heteropierys. Sapindacece. In this natural order we meet with some wonderful aberrant forms of dicotyledonous stems, but I shall here notice only two which are met with on cotton bales. One of these is most probably the Serjania cuspidata figured by Duchartre (“Elements,” &c., fig. 82, p. 170) and Schleiden (“Principles,” fig. 168, p. 253), and easily recog- nized by its triangular form and compound character. It consists of a primitive stem not specially noticeable for any divergence from the usual type of a dicotyledonous stem ; but round this stem are arranged three other lateral stems, each of which has its own bark separate from the rest, but 95 united to the bark of the primitive central stem. These lateral portions are circular in outline, save that they are flat on the side by which they are attached to the central stem, which latter is in consequence hexagonal. The attach- ment of the lateral portions to the central mass is not very firm, as most of the ropes of this species reach this country with their strands separated, but this is due to the rough usage to which they have been subject in packing; but Gaudichaud points out that in certain parts of the stem — most likely at the nodes, for he is not very clear upon the point — the lateral strands have an organic attachment to each other, since some of the woody fibres of the central mass are continued in one of the lateral strands, and vice versa . (“ Recherches,” pi. xiii. figs. 2 and 3, p. 110.) A still more remarkable example supplied by this family in the form of a natural rope, is one which might have served our telegraph engineers as the model of a submarine cable. Like the Serjania, there is a central woody mass possessing a medullary sheath and pith, woody layers, and a cortical system; but surrounding this central core and arranged parallel with it is a series of eight lateral strands each sur- rounded by its own bark, the whole being consolidated so as to form a rigid cylindrical axis, which presents no exter- nal manifestation of its peculiar internal organization. It is represented in the last figure of Gaudiehaud’s “ Recherch.es” (pi. xviii, fig. 21, p. 130) and has been copied into most of our text books, in some cases incorrectly described as a Malpighiaceous plant, as by Professor Balfour in his “ Class Book,” figs. 186 and 1429. On examining such stems of this order as I have been able, the pith and medullary sheath with its characteristic tracheal vessels appear to be met with in the central mass only, and some botanists, contrary to the opinion expressed by Jussieu (“Memoire,” pp. 116 — 117,) doubt the existence of these organs in the lateral strands. Nevertheless, one of 96 the most recent observers of these stems, Herr Nageli, has recently demonstrated their presence in each of the sur- rounding woody masses (Dickenwachsthum des Stengels... bei den Sapindaceen. Munich, 1864). A short summary of their mode of growth, communicated to the French Academy by Monsieur Netto, will be found in “Comptes Rendus,” t. 57, pp. 554 — 55 7, 21 Sep., 1863, from which it would appear that a young stem, two to three weeks old, exhibits a number of fibro-vascular bundles in the midst of an outer zone of cellular tissue, one bundle being formed opposite the innermost portion of each of the external groves of the stem ; so that from its very earliest stage the stem exhibits all the rudiments of the lateral strands which surround the core. Around each of the fibro-vascular bundles a mass of liber is formed, at first crescent shaped, but afterwards annular ; and by the growth and union of these several parts the stem soon assumes its peculiar composite character. Leguminosoe. Another group of lianas, presenting some external resem- blance to the sinuous Malpighiads, is met with in plants which belong to this natural order of the genera Bauhinia and Schnella. In the Brazils they bear the name of Oipo cl’Escada , from their resemblance to a ladder, but Jussieu restricts this name to the Schnella macrostachys (“Memoire,” p. 118.) They are chiefly remarkable for depositing their woody fibres on two sides only of the central pith, so that their stems have a singular flat tape-like appearance, presenting in section the outline of an elongate ©©, the position of the pith being at the intersection of the two loops. The pith however by no means maintains its central position, for according to the researches of M. Netto, the growth of branches brings about a lateral deposit of woody matter, 97 sometimes on one side and sometimes on the other, so that the pith soon becomes eccentric. The pith is generally in the form of a small Maltese cross, formed of two unequal arms, the longest of which lies in the direction of the largest diameter of the stem. There are many other forms of Bauhinia, many of which will be found figured in the standard works of Bindley, Schleiden, Richard, Duchartre, &c. Aristolochiacece. It is very likely that this natural order has representa- tives amongst these ropes; at least to it I refer for the present two species remarkable for their very striking medullary rays. In both species these rays proceed from the pith to the bark, increasing in breadth and volume as they recede from the pith, so that by the time they reach the bark they become of considerable thickness. In one species, whose wood has a reddish tinge, there are about nineteen or twenty of these magnificent rays in a stem exceeding half an inch in diameter ; the intermediate spaces are filled up with woody fibres in which occur large vessels. In this species secondary medullary rays rarely make their appearance. But in the other species, which has a beautiful cream-coloured wood of the shade of our common holly, secondary and tertiary medullary rays make their appearance, so that in a stem three quarters of an inch in diameter there will be as many as thirty primary rays, and as many more secondary rays. In this, the commoner species of the two, the cortical system is much thicker than in the first-mentioned species. Both bear much resemblance to a wood-section in my cabinet which is called “ New Zealand Pepper,” a plant of which I am quite ignorant, 98 Ampelidece. Gaudichaud in his memoir (“ Recherches,” plate xiii, fig. 5, p. 109) gives a figure of the Cissus hydrophora as one of the common lianas of the Brazil, but I am not sure whether it occurs amongst the ropes which reach this country. It is described by M. Netto (Annales des Sciences, 5th ser. Bot. t. vi., p. 320 ; Comptes Rendus, tom. 62, p. 1076,) and a short summary is worth transcribing, as he had the advan- tage of studying the living plant. v In the section of a young stem, beginning with the bark, we have first a suberous layer, then a thick cellular layer containing very little chlorophyll ; and having at the side nearest the bark a mass of dotted cells whose walls become very thick. On the inner edge of this cellular layer we meet with a number of liberian bundles in front of some woody bundles ; the latter are strikingly subdivided by the adjacent parenchyma into separate groups so as to cause it to look more like the arrangement generally seen in a monocotyledonous plant. M. Netto mentions that the structure of the woody mass is even more remarkable, since in the place of the ordinary medullary rays, cellular bands are projected from the bark towards the pith which form cortical rays. Another pecu- liarity of the woody part is that, notwithstanding it may be two years old, the woody fibres are so loosely held to- gether that they readily detach themselves from the cellular tissue in which they are imbedded. The stem must be at least three years old before it attains anything like con- sistency; this weakness, as contrasted with other lianas, probably leads to its not being so frequently used for pack- ing purposes. There is one histological character however presented by this liana which will lead to its identification, and that is the abundant quantity of raphidian crystals contained in all parts of the stem. M. Netto describes the form of these 99 crystals as needle-shaped, hut bifurcate at one extremity— which is peculiar. However abnormal many of the stems belonging to these various orders may become, and however difficult it may be to trace their divergency from the normal structure, there can be no doubt that the characteristic elements of the di- cotyledonous stem are all present during some portion of their lives. Their unequal development may be brought about either by the vital energy of the growing tissue of the bark being in excess of that of the wood, or vice versa, from which circumstance will arise the curious outlines presented by the relative distribution of each; or else it may be pro- duced by a much more copious deposition of woody tissue at some points of the circumference than at others, from which will result the curious forms presented by the Bau- hinias and many of the Malpighiacese. The monocotyledonous division of the vegetable kingdom has also its representatives amongst these ropes. There are two species, perhaps belonging to the grasses, which I have met with ; but in neither case is the entire stem used. One species is much larger than the other, their diameters being about two inches and four inches respectively; both are hollow and are divided into strips for use. There are many other species found amongst these ropes which belong to other natural orders, such as the Menis- permacese, Gnetacese, Asclepiadacese, &c., but our knowledge of them is too limited to assign them to their respective orders. Most of my specimens have come from bales of Santos Cotton, and it would be as well to keep a record of the localities from whence they are derived. I am very anxious to get some from the Pacific coast, where many species differing from Brazilian species must be found. Gaudichaud mentions the neighbourhood of Guayaquil, in Ecuador, as being particularly prolific in these lianas. 100 I will conclude with a notice of another species which was sent me from the Liverpool docks by Mr. Griffiths, whose structure is so puzzling that I know not whether to call it dicotyledonous or monocotyledonous. It consists of a central spongy mass of woody tissue apparently without medullary sheath, pith, or medullary rays, and arranged in the form of a pentagon formed of semicircular lobes, the whole being surrounded with what appears to be liber which has shrunk away from the very thick and hard external bark, so as to leave the woody core isolated within it. The core consists of woody fibres, but half its area is taken up with wide-mouthed vessels. I may add that the whole of these lianas furnish beautiful objects for the microscope. Mr. F orrest suggested that useful dyes might be obtained from the plants described by Mr. Bailey. In reply to a question from the Rev. Brooke Herford, Mr. Bailey stated that owing to a difference in the structure and general appearance of some of the stems in his posses- sion he had been led to suspect that they were aerial roots of some of the plants he had exhibited and described. 101 Ordinary Meeting, February 22nd, 1870. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. The President referred to the observations he had made in former years on the progressive rise of the freezing point of one of his thermometers, published in the Proceedings for April 16, 1867. He had made a further observation on the 12th February instant, and found that a rise, which though very small was unmistakable, was still taking place after a lapse of time of 26 years since the bulb was blown. The results are as follow in indications of the thermometer, calling the first observation in April, 1844, zero. 12 ‘9 divisions of the thermometer correspond to one degree Fahrenheit. April, 1844 0 Feb., 1846 5-5 Jan., 1848 6*6 Feb., 1853 8-8 April, 1856 9-5 Dec., 1860 Ill March, 1867 IDS Jan., 1868 11 -92 Feb., 1870 12*02 Dr. F. Grace Calvert, F.R.S., stated that he did not intend to read a paper on artificial alizarine , some of the facts he was going to bring before the notice of the o o o meeting, being well known to his colleagues the chemists of this district, but he hoped it might be interesting to the gene- ral members of the Society to have an idea of the progress that had been made during the last few months in the produc- tion of this substance. They were aware that alizarine was the essential colour- giving principle of the madder root. Peooeedin&s — Lit. & Phil. Society. — Vol. IX. — No. 11. — Session 1869-70. 102 Every cultivated mind in Lancashire ought to be acquainted with each step made in the artificial production of this dye, owing to the immense capital involved in the cultivation of the madder plant in the working of it up in this country, as well as the revolution it will effect in our commercial relations and the important new branches of manufacture it will create. It was well known to the members of this Society that about 12 months ago Messrs. Graebe and Liebermann had discovered a method of producing alizarine from a coal-tar product which up to that time had attracted very little attention, even in the scientific world, viz., anthracene CuHl0 and that by oxidation they transformed it into anthraquinone C14H802i which in turn was changed into bibrom-anthra- quinone C14HGB202, this being converted into alizarine C14H304 by the addition of 2 equivalents of oxygen and the formation of 2 equivalents of Hydrobromic Acid. It was felt by all chemists that this discovery was one of great importance, though it was too complicated to be com- mercially useful, but the Gordian knot, being now cut the commercial production of artificial alizarine was merely a question of time, and what he would now relate showed the marked progress which had been made toward this end. There were already three patents published, and one process, the details of which are kept secret, is being worked by Messrs. Meister, Lucius & Co., of Hoechst, near Frankfort. The patents are those of Messrs. Brsennan and of Gutzkow, of Messrs. Caro, Graebe, and Liebermann, and Mr. W. H. Perkin. It was curious to notice that the patent of Messrs. Caro was dated the 25th of June last, and Mr. Perkin's the 26th of the same month ; and that all these patents effect the same purpose by simply employing different oxidizing agents. Messrs. Braennan and Gutzkow oxidize the anthracene into anthraquinone by means of the nitrate of protoxide of mercury, Messrs. Caro by peroxide of manganese,' and Mr. Perkin, I believe, by bichromate of potash, and then all by further processes converting this substance into alizarine. ] 03 As it might be interesting to many of the members to have an outline of one of the methods employed, he would therefore describe a process detailed in the specification of Messrs. Caro, Graebe, and Liebermann. One part of anthra- cene is heated with four of sulphuric acid, of specific gravity 1-845, for three or four hours, to a temperature of 212° F., and then for about an hour at 300°. The mixture is allowed to cool, and to it is added water equal to three times the weight of the anthracene employed, and manganese equal to four times that weight. The whole is boiled for three hours and milk of lime added, which gives rise to a deposit consisting of the excess of lime and manganese used and protoxide of manganese, while there remains in solution a double sulphate of anthraquinone and lime. This solution is now acted on by carbonate of soda in . slight excess, car- bonate of lime separates, and the salt of soda thus produced is evaporated to dryness. This solid mass is then mixed with tAvo to three parts of caustic potash or soda and a small quantity of water, and the whole heated under pres- sure in suitable vessels at a temperature of 350° to 500° F. for one hour, Avhen the anthraquinone is further oxi- dized and converted into alizarine. The alkaline mass on cooling is dissolved in water and sulphuric or acetic acid added in slight excess, Avhen an orange-yellow fiocculent substance precipitates, which, when properly washed and dried, is artificial alizarine. If this process can be carried out on a practical scale (and there is no doubt that it will be under the direction of such clever chemists as Messrs. Perkin, Caro, and others), Ave may then fairly consider the production of artificial alizarine aS having reached the sphere of commercial application; though I may add from personal experience that some time must elapse before it can be manufactured in quantities suffi- cient to affect the present applications of madder, garancine, Schunckts artificial alizarine, &c., &c. 104 There is another great difficulty yet to be overcome be- fore the artificial alizarine can become a commercial article, that is, the obtaining of anthracene in larger quantities, and this question is of some importance to us: England being the great tar producing country. Anthracene does not appear to exist in greater proportion than one in a thousand of tar, and is only liberated or produced during the latter part of the distillation of the tar. In fact if the distillation be stopped so as to leave a very soft pitch, the oils obtained give little or no anthracene. If on the other hand it is carried on so as to get 10 or 15 per cent, more oil off, there remains a hard pitch which has little or no value at the present day, the quantity of anthracene obtained varying very much according to the nature of the coals employed in the pro- duction of the tar, ranging from 1 J to 8 per cent, of the heaviest oils separated; it will scarcely be worth the while of the tar distiller to depreciate the value of one of the staple articles of his trade to produce it, and even when the heavy oil is obtained the separation of the small quantity of anthracene it contains, and its purification for use accor- ding to the above patents will yet require much time and research. It is well known to all who have worked on the coal-tar products that each well defined compound is mixed with homologues which renders its separation and purification a work of extreme difficulty, thus aniline is mixed with picoline and several other alkaloids, benzol with toluol and other hydrocarbons, carbolic acid with cresylic and other acids, and anthracene is also mixed in a similar manner with homologous compounds. The mere distillation and filtration of the solids obtained and their hot or cold pressing or even their sublimation, do not effect the complete purification of the substance. The purest product I have been able to obtain on a moderate commercial scale has contained, when cold pressed about 40 per cent, and when hot pressed about 70 per cent of 105 anthracene. One of the chief difficulties in its prepara- tion is the fact of its great solubility in its liquid homo- iogues at a moderate temperature, thus an oil, at 40° or 45° F. will yield a comparatively large quantity of anthracene by filtration, but if its temperature be raised to 70 or 80 degrees, the anthracene will be completely dis- solved. I am aware that it has been proposed to distil soft pitch so as to obtain the volatile products that are given off in coaking it, but the expense, difficulty, and danger of such an operation are such that I doubt if they can be overcome so as to produce anthracene of comparative purity on a com- mercial scale. Papers have been published respecting the identity of the alizarine produced by the process of Messrs. Meister, Lucius, and Co., with natural alizarine, by Dr. Schuncb, Professor Bolley, and Messieurs Emile Kopp, Camille Koechlin, La Fraisse, G. Wallace Young, and J. Christie. The opinions of these chemists vary. Dr. Schunck and Professor Bolley consider it identical, the other gentlemen considering it not identical, some of them maintaining it to be a mixture of purpurine and alizarine. The product made according to the patents mentioned I have not had an opportunity of examining, nor have I seen any papers on the subject in any of the Scientific Journals which have reached my hands; but as doubtless it will shortly be before the public, I shall take an early oppor- tunity of laying before the Society the results of my own experience as well as those of others. In conclusion, I think many years must elapse before artificial alizarine can replace madder and its preparations in all their varied applications in calico printing, but ere long the purity of the substance, artificially obtained, may prove of great service to the calico printer, by enabling him to produce at a cheaper rate than now certain styles of prints as well as new styles and effects. 106 Specimens of Anthracene, Artificial Alizarine, and Dye Fabrics were exhibited. Dr. Schunck, F.R.S., remarked that the practical success of the new process would in a great measure depend on the price of the raw material, anthracene, and on the amount of colouring matter to be obtained from it. The process itself was, however, as far as the few experiments he had made allowed him to judge, a very simple and easy one, re- quiring the use of no costly materials. He was convinced himself that the artificial product was identical with the natural alizarine of madder, the only difference being that the former was generally contaminated with some impurity which prevented its crystallising easily. Purpurine was not formed along with alizarine, as had been supposed. He also exhibited to the meeting some specimens of Turkey-red dyed with artificial alizarine, which had been sent to him by Mr. Perkin, and stated that the latter had already manufactured several tons of the new product. In connection with this subject Dr. Schunck referred to a notice contained in the last number of the Chemical News, giving an account of a process for preparing pure alizarine from Turkey-red dyed cotton. The author, M. Schiitzenber- ger, does not state that the process is new, though he seems to claim it as his own. Almost the same process was however described many years ago by Dr. Schunck, who claims indeed to have been the first to point out that Turkey red, madder pink, and all the finer madder colours are simply compounds of alizarine and fatty acids with bases. The experiments on which this conclusion was founded were described in the edition of Ures Dictionary of Arts, pub- lished in 1859, under the heads of “Madder'-'’ and “ Turkey Red,” but the experiments themselves were made at a much earlier date. “ On the Organic Matter of Human Breath in Health and Disease,” by Dr. Arthur Ransome, M.A. The vapour of the breath was condensed in a large glass 107 flask surrounded by ice and salt, by which a temperature of several degrees below zero was obtained. The fluid collected was then analysed for free ammonia, urea and kindred substances ; and for organic ammonia — the method employed being that invented by Messrs. Franklyn and Chapman foi; water analysis. The breath of 11 healthy persons and of 17 affected by different disorders was thus examined, and the results were given in two tables. The persons examined were of different sexes and ages, and the time of the day at which the breath was condensed varied. In both health and disease the free ammonia varied considerably, and the variation could not be connected with the time of the day, the fasting or full condition. Urea was sought for in 15 instances — three healthy persons and 12 cases of disease — but it was only found in two cases of kidney disease, in one case of diphtheria, and a faint indica- tion of its presence occurred in a female suffering from catarrh. The quantity of ammonia, arising from the destruction of organic matter, also varied, possibly from the oxidation of albumenous particles by the process of respiration ; but in Wealthy persons there was a remarkable uniformity in the total quantity of ammonia obtained by the process. Amongst adults the maximum quantity per 100 minims of fluid was 0'45 of a millogramrne, and the minimum was 0*35. A rough calculation was given of the total quantity of organic matter passing from the lungs in 24 hours — in adults about 3grs. in lOoz. of aqueous vapour, a quantity small in itself, but sufficient to make this fluid highly decomposible, and ready to foster the growth of the germs of disease. In disease there was much greater variation in the amount and kind of organic matter given off. In 3 cases of Catarrh, 1 of Measles, and 1 of Diphtheria, the total ammonia obtained was much less than in health — less than 0*2 of a millogramrne — a result probably due to the 108 abundance of mucus in those complaints, by which the fine solid particles of the breath were entangled. In two cases of Whooping Cough it was also deficient, but as they were both children, the lack of organic matter may have been due to their age. In cases of Consumption also the total ammonia was less than in health ; but in one case of this disease associated with Bright’s disease a large amount of organic matter was given off, a portion of it due to urea. In Kidney Diseases the largest amount of organic matter of all kinds was found in the breath. The ammonia in one case of Bright’s Disease was 1*8 millogrammes in 100 minims of fluid, and urea was largely present. Perhaps this fact might be taken as an indication of the need of measures directed to increase the activity of other excretory organs. In one case of Ozona or Offensive Breath the total quan- tity of ammonia obtained was greater than in any healthy subject, but the excess was chiefly due to organic matter. One convalescent case of Fever was examined, and the total ammonia was found to be deficient. The air of a crowded Railway Carriage, after 15 minutes’ occupation, was also tested b y this method and in about 2 cubic feet 03 millogrammes of ammonia and 3 millogrammes of organic matter were found. © With reference to the presence of organic matter in the atmosphere, it was pointed out that the subject was in no way a novel one, and that it had, during the last 30 years? been very fully investigated by many observers, more es- pecially by Schwann, Dusch, Schroeder, Helmholtz, Yan den Broeck, Pasteur and Pouchet, but it was shown that it is to Dr. Angus Smith that we owe the discovery of the readiness with which living organisms are formed in the condensed breath of crowded meetings, and the determination of the actual quantity of organic matter in the air of different localities. Mr. Dancer’s calculation of the number of spores contained in the air was noticed, but a source of error was pointed out in the readiness with which organisms are developed in suitable fluids, even in the course of a few hours. Observa- tions upon the organic particles of respired air had at different times been made by the author. 1. In 1857 glass plates covered with glycerine had been exposed in different places and examined microscopically. Amongst others in the dome of the Borough Gaol, to which all the respired air in the building is conducted, organized par- ticles from the lungs and various fibres were found in this air. 2. During a crowded meeting at the Free Trade Hall air from one of the boxes was drawn for two hours through distilled water, and the sediment examined after 86 hours. The following objects were noted : — fibres, separate cellules, nucleated cells, surrounded by granular matter, numerous epithetial scales from the lungs and skin. 3. The dust from the top of one of the pillars was also examined, and in addition to other objects, the same epithe- tial scales were detected. 4. Several of the specimens of fluid from the lungs were also searched with the microscope. In all of them epithe- tium in different stages of deterioration was abundantly present, but very few spores were found in any fresh speci- men. On the other hand after the fluid had been kept for a few hours myriads of vibriones and many spores were found- In a case of Diphtheria,, confervoid filaments were noticed, and in two other cases, 1 of Measles and 1 of Whooping Cough, abundant specimens of a small celled torula were found, and these were seen to increase in numbers for two days, after winch they ceased to develope. These differences in the nature of the bodies met with probably show some difference in the nature of the fluid given off ; but it wTas pointed out that they afford no proof as yet of the germ theory of disease. They simply show^ the readiness with which the aqueous vapour of the breath supports fermentation, and the dangers of bad ventilation, especially in Hospitals. Dr. E. Lund and Dr. H. Browne stated that they had also made experiments, the results of which were, in general, confirmatory of those obtained by Dr. Hansom e. 110 MICROSCOPICAL AND NATURAL HISTORY SECTION. January 31st, 1870. John Watson, Esq., President of the Section, in the Chair. Mr. Charles Bailey read a paper “ On the Natural Ropes used in Packing Cotton Bales in Brazil.” [This paper was afterwards read at the Ordinary Meeting oi the Society, held February 8th, 1870. See page 88.] Mr. J. Sxdebotham exhibited some photographs of Pholas- bored Rocks, and made the following remarks thereon. In October, 1857, Mr. R. D. Darbishire read a paper here on some rocks bored by Pholas which he had discovered on the Little Ormes Head, and exhibited specimens. Last Spring I examined the rocks on both the Great and Little Ormes, and found many rocks so bored, of several of which I took photographs, some of which I now exhibit from both places. The holes are most abundant near the tops of the moun- tains, and I met with none whatever very low down. At first sight one is rather confused, the holes on the surface of the rocks having been weather-worn, and some- times connected by channels with the natural fissures in the rock, so as to render it difficult to say which or whether any of the holes have been caused by boring shells. When these holes occur, however, in overhanging rocks, or rocks protected from the weather, there is no doubt as to their origin ; but to obtain photographs of them is very difficult, as the camera has to be supported with stones, and the operator has to lie on his back on the ground to obtain the focus. An interesting collection of Australian Plants from Dr. Mueller, of Melbourne, was exhibited by Mr. H. A. HURST. Ill Ordinary Meeting, March 8th, 1870. J. P» Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. Sir James Cockle, M.A., F.R.S., President of the Queens- land Philosophical Society, was elected a Corresponding Member of the Society. The following letter from Mr. Dancer, F.R.A.S., dated March 5, 1870, was read : — - I was not present at the last ordinary meeting on Feby. 22nd, but seeing my name mentioned in the printed report of Dr. A. Ransome’s paper “On the Organic Matter of Human Breath,” in which it is stated “ that Mr. Dancer’s calculation of the number of spores in the air was noticed, but a source of error was pointed out in the readiness with which organisms are developed in suitable fluids even in the course of a few hours,” in reply I have to state that this very obvious source of multiplication did not escape atten- tion, which a few extracts from the printed paper in the Proceedings of March 31st, 1868, will suffice to show. It is stated that “ during the first observations, few living organ- isms were noticed, but as it afterwards proved, the germs of plant and animal life (probably in a dormant condition) were present.” Again, at the bottom of the same page- — “ When the bottle had remained for 36 hours in a room at a temperature of 60° the quantity of fungi had visibly increased, and the delicate mycelial thread-like roots had Proceedings— Lit. & Phil. Society. — Yol. IX. — No. 12. — Session 1869-70. 112 completely entangled the fibrous objects contained in the bottle and formed them into a mass,” I may add that the contents of the bottle were very frequently subjected to critical examination for any change in their appearance from the time I received it from Dr. R. A. Smith until all appear- ance of vitality had ceased. The amount of solid matter suspended in the atmosphere is exceeding variable — after continued rain the air is comparatively free, whereas in very dry weather with high wind, in localities where dust and decomposing matter are abundant, it will be found at a con- siderable altitude. E. W. Binney, F.RS., called the attention of the meeting to the frightfully high death-rate of Manchester and Sal- ford, which continued to increase, notwithstanding the appointment of officers of health, and the doings of the councils of the two towns. He noticed the lamentable state of the poor as to habits of cleanliness and their igno- rance of the nourishing properties of the food they con- sumed, the adulteration of their food and drinks, and the overcrowding of dwellings; but these evils were common to most large towns. Manchester was not now to such an extent as it once was a cotton spinning town, so the neglect of infants by the absence of mothers at work was not so great as it had been here, and now is in some other places; but the sudden change of light-clad females from the high temperature of a fine spinning mill to the cold of the open air must have a very injurious effect on their health. The city authorities complained of the owners of property not improving the dwellings of the poor and looking after their tenants, whilst the owners retorted on the authorities by saying that many of their tenants would not pay for decent habitations and would certainly not keep their houses clean if they could get their landlords to do it for them, and they wished the sanitary reformers of the Council to become owners of cottage property and try their hands practically 113 with managing dirty and improvident tenants. No doubt Manchester and Salford landlords were pretty much the same as those in other large towns, and the sanitary state of the poor must always in a great measure depend on them- selves, for it is impossible for other people to be continually looking after and protecting their poorer neighbours. The ministers of religion may do some good in preaching provi- dence and cleanliness to their congregations, but the mis- chief is that the great bulk of our dissolute and improvident poor is connected with no religious body whatever. Manchester and Salford, when compared with other large towns, had two great disadvantages, namely, the subsoils on which they were built, and the filthy open sewers which flow or should flow past them. The chief parts of both towns stand on a thick bed of cold brick clay quite imper- vious to water, and valley gravel at the lower boundary of such clay and betwixt it and the adjoining streams. The only exceptions are the higher portions of Harpurhey, Cheetham Hill, Higher Broughton, and Pendleton, which are for the most on dry sand. Nearly thirty years ago he had first called attention to the evils of polluting the streams near Manchester, and then damming them up as if it were desirable to stop the filth from flowing away. The following is an extract from his report, published in the Health of Towns Report, for 1845 : — - “ The river Irwell, after having, by its tributaries, afforded drainage and sewerage to the towns of Bolton, Bury, Roch- dale, and numerous other places, and pent up in countless reservoirs and dams for manufacturing purposes, approaches Salford by the Adelphi in a pretty tolerable condition as to purity, inasmuch as small fish live in its waters— -a very rare circumstance in any other of the streams, except the upper part of the Medlock. At the Adelphi is a high weir, built across the river ; after passing this impediment, it is polluted by the numerous works upon its banks in the 114 eastern and south-eastern parts of Salford, and it receives the waters of the Irk at Hunt’s Bank, in a condition much worse than its own— in fact, as filthy as waters can well be ; thence the river flows sluggishly along the western part of Manchester to Hulme, where it receives a portion of the waters of the Medlock and Shooter’s Brook, charged with the contents of the sewers of the eastern and southern parts of Manchester, and is then stopped at Throstle Nest by a dam across its stream. For many miles in its course towards Runcorn it emits offensive smells and bubbles of light carburetted gas, which rise to its surface.” As the weirs then were so they now are simply traps set for the purpose of catching the filth in the streams. Of late years, many fine schemes have been proposed for preventing the floods, but why not first try the taking away the weirs and giving the streams fair play. Instead of removing the obstructions to the streams, our authorities have ever since been pouring fresh sewage into them, and all the towns above us have followed our bad example; so the Irwell, in place of approaching us in a state fit for fish to live in, as it formerly did, is in as foul a condition as the dirty Irk. Of course, it is for the most part out of the power of the municipal authorities altogether to remedy the disadvan- tages of the subsoil, but surely they ought to do something towards improving the sewerage and drainage of our city and town. In reply to a question from the President, Mr. Lund, F.R.C.S., stated he was of opinion that if it were possible to obtain, for drinking purposes, chemically pure water, it would not be so wholesome for constant use as water con- taining a small admixture of calcareous matter to give it some degree of hardness. Potable water ought to be absolutely free from organic matter, or any of the products of decomposition, and, especially 'from sewage contamination. The sources of the constantly high death-rate in a large city like Manchester, were not to be discovered by tracing 115 out any one set of influences exclusively. We must take into account the habits of the people and their peculiar occupations ; the ages at which the greater number of the deaths occur, and the probable exciting causes; such as insufficient clothing, sudden changes of temperature, from the heated atmosphere of the mill to the cold external air ; adulterated, badly-selected food; intemperance; small ill- ventilated dwellings; inefficient nursing of the sick, and inattention, if not positive neglect, of the young and the delicate ; all these agents contribute their portion, in varying degree, to the aggregate result. It would help greatly to direct attention to the importance of some of these, as elements in the enquiry, if, in the public returns of the death-rate, or the number of deaths in a given time, the deaths at each period of life were separately stated ; and, it would not be inappropriate for general readers if the classifi- cation took in the “seven ages of man,” in septennial ranges’ each having its own peculiar risks and dangers. In this way, more intelligible and suggestive lessons would be taught by such returns, than the mere crude records now given of the proportion to each thousand or ten thousand of the population, irrespective of all attending circumstances and possible causes. “On the Suspension of a Ball by a Jet of Water,” by Osborne Reynolds, M.A., Professor of Engineering, Owens College. Some years ago I was led to consider this somewhat common though striking phenomenon, and at the time I arrived at what seemed to be a perfectly satisfactory ex- planation of it. I did not then suppose this explanation was new, but as I cannot find that anything like it has been published, I have presumed to take this opportunity of bringing it before the Society. Although everyone will have watched with interest the performance of the ball as it is acted on by the jet, and be 116 more or less familiar with it, I shall recount the principal things I noticed whilst observing it critically. The ball was very light and had a wet surface. The jet, when free from the ball, would rise about three feet. The ball was not kept in one position, but oscillated up and down. The centre was not necessarily over the jet, it often re- mained for a long time on one side of it. In fact it appeared to be in equilibrium when struck about 45° from its middle. In this way, for some seconds at a time, the ball appeared as though it were hanging to the jet, and then it would oscillate about this position so far, that at times it would be struck underneath, and at other times almost on the hori- zontal circle; indeed sometimes it would be forced so much to one side that the jet missed it altogether. In this case it would immediately drop down, but such was its determina- tion not to be thrust aside, that it generally came back into the jet almost instantly. Occasionally, however, it would fall down into the basin. Being a light ball the friction of the water caused it to spin, and as it moved about the jet it would spin sometimes in one direction and sometimes in another, always about a horizontal axis. Of the water which strikes the ball, part is immediately splashed off in all directions, part is deflected off at a tan- gent, and part adheres to the ball, and is carried round with it until it is thrown off by centrifugal force. There are many other things that attract attention, but I think I have noticed those which bear on the explanation. The vertical force caused by the action of the jet is no doubt amply sufficient to support the weight of the ball, and did the centre of the ball remain vertically over the jet there would be no difficulty. 'The only explanations I have ever heard have been based on the same supposition : 117 the jet is supposed to strike the ball underneath, and form a cup in which the ball rests. A few seconds’ observation, however, will show that the above is not satisfactory : before any explanation can be complete, it must show how it is that the ball will remain in equilibrium on one side of the jet ; nay, that it will fly back into the jet, when driven out of it. I will first point out the nature of the forces which act on the ball. Its weight acts at its centre in a vertical line, and is the only force which is not due to the water. If the water strikes the ball directly underneath its centre, it will produce a force acting upwards in a vertical line, the magnitude of which will depend on the height, and may therefore be made to balance the weight of the ball. In this position the ball would by the action of those two forces be in equilibrium in the same way as if it were balanced on a point ; the slightest deviation would upset it, and then the jet would strike it on one side. If so struck there would be two forces at the point of contact, the one normal or through the centre of the ball, due to the impulsive action of the water, which I shall call P ; and another in the tangent due to the friction of the water, which I call R If W be the weight of the ball, then P, R and W are the only forces which at first sight appear to exist, and the question is, can P, It and W be in equilibrium ? This is easily answered ; for, these three forces are necessarily in the same plane, but they do not all pass through the same point and therefore they are not in equilibrium. Hence there must be some other force acting on the ball which does not pass through its centre, or the point in which it is struck. Since this force cannot arise from the action of the water as it strikes the ball, or the weight of the ball, it must be due to the action of the water as it leaves, and since that water which is splashed off or deflected at the point of contact does not touch the ball again, the force must be due 118 to the water which adheres to the hall, and is subsequently thrown off. Now whenever a drop leaves the ball there will be a tangential reaction in a direction opposite to that in which it leaves, and if many drops are leaving the ball at the same time, there will be a force equal to the sum of all their reactions opposing the rotation of the ball, and a force equal to the resultant of all their reactions acting on the centre of the ball. If the water be thrown off equally all round, this latter force will be zero ; but if more drops leave in one direction than in another, the resultant force will be opposite to this direction. As this force is essential to the equilibrium of the ball, the question arises, is there any reason why most of the water should leave the ball in one direction ? and if so, in which direction will that be ? Now the water comes on the ball at p, and as it passes over the top of the ball, the action of gravity or the weight of the water will be to keep it on the ball, but after it has passed the top, the conditions for its leaving become more and more favourable — so that it appears as though the water would begin to leave as soon as it had passed over the top of the ball and go on until it was all thrown off In this way most of the water would leave between the top of the ball and that side which is opposite the jet, which on examination I find to be the case. It was the discovery of this fact which has enabled me to explain the phenomenon, for this water causes a resultant reaction which is the additional force necessary to maintain the equilibrium of the ball. Let this resultant reaction be called Q, it will act upwards and towards the jet, and its effect will be, first, to force the ball into the jet and so will help to counteract the obliquity of P ; secondly, it will assist in supporting the ball ; and thirdly, since it opposes the rotation, it will balance the tangential force R caused by the friction at p, and provided it have 119 the proper magnitude, together with the forces P, It and W, it is all that is requisite to explain the equilibrium. Position of Equilibrium. With regard to the position of the ball when in equili- brium I cannot establish anything definite, as there are no known laws of adhesion, but I can show by general reasoning that there are limits between which the point in which the ball is struck must lie, so that there may be equilibrium. Let the point p be at a fixed height, and let P' equal the full force of the jet at this height when acting on the bottom of the ball or on a perpendicular plane. Then if a be the angle which the normal at p makes with the vertical P = P'cosa and the horizontal component p/ p/ Psina — — 2sina COSa = ^ sin2a ; 2 2 * therefore and Psina = - and is a maximum when a — 45° 2 Psina = 0 when a - 0 or a - 90° So that the tendency of the jet to force the ball to one side P' increases from nothing to as p moves from the bottom to a point at which the normal makes an angle of 45° with the vertical and then decreases to nothing as p moves to the middle of the ball. The force Q may be fairly assumed to increase as the speed of rotation increases, and this will be as the point of contact moves from the bottom to the middle of the ball. In the same way the force F, which will necessarily increase as Q increases, will increase as p moves from the bottom to the middle of the ball, and its horizontal component will follow nearly the same law as that of P. Considering then the horizontal forces only, there must be some position for p in which the horizontal component of 120 Q and F will be equal to that of P, and if a horizontal circle be drawn through this point it will limit the part of the ball in which equilibrium is possible. For any deviation without this circle the equilibrium will be stable, i.e. if the centre of the ball gets so far from the jet that the ball is struck in some point without this circle, it will come back again. As to the nature of the equili- brium for any deviation within this circle, I cannot speak positively, but it is probably nearly neutral all over the enclosed area. This seems to agree very well with the appearances I have described, namely, that the ball appeared to be in equi- librium when struck at a point about 45° from its middle, about which point it oscillates. When the oscillations become so big that the ball leaves the jet, I have said that the ball instantly jumps back again. To account for this we have only to consider that the force P ceases as soon as the contact ceases, but not so with Q, for there will still be some water to be thrown off, so that perhaps for half of a revolution after the contact has ceased, the force Q will continue undiminished and so bring the ball back into the jet. 121 MICROSCOPICAL AND NATURAL HISTORY SECTION. February 28th, 1870. John Watson, Esq., President of the Section, in the Chair. The following extract from a letter to Mr. H. A. Hurst from Dr. Mueller was read : — “ I should be obliged if you would procure for me seeds (or roots) of Sagittaria, Hottonia, Butomus , Lysimachia vulgaris and thrysiflora, Menyanthes, Villarsia, Lychnis, Flos-cuculi, Caltha palustris, all of which I should much like to naturalize in a lake of this garden. I will gladly send a good collection of Australian seeds in exchange.” The Secretary will be glad to receive seeds of any of the above-named plants which members may be able to collect during the ensuing season. “On some Shell Deposits at Llandudno,” by Mr. Joseph SlDEBOTHAM. The author referred to a paper by Mr. Darbishire, published in the Society’s Memoirs in 1867, where these deposits are mentioned and considered to be the refuse -heaps of former inhabitants. The object of the present paper was to enter more into detail as to the composition of these refuse heaps and to fix a probable date as to their being formed ; the deposit specially examined is situated at the foot of the Great Ormes Head, on Conway Bay, and has been partially washed away by the sea, a section of it is best seen from the beach; photo- graphs of it were exhibited. This deposit consists chiefly of shells of patella, purpura, and littorina, and bones of animals, with pieces of charcoal. Mr. Boyd Dawkins, F.R.S., had 122 identified the bones as belonging to the ancient homed sheep, the Keltic short-horn, the horse, and the dog. Many of the bones were split up, apparently for the purpose of extracting the marrow, and some bore the marks of the teeth of dogs. Some of the bones of the horse had been exposed to the action of fire ; the charcoal appeared chiefly to consist of burned stems of Ulex Europeus. No traces of weapons, or implements of stone or metal were met with, but Mr. Darbishire found a single fragment of bright red pottery, apparently of Roman manufacture, and from its shape probably being a portion of a small drink- ing cup. The absence of all bones of wild animals, birds, and fish, seemed to indicate a very low state of civilization. The author then proceeded to show from historical and legendary evidence, that the place where the shell deposit now exists was within historical times far removed from the shore, and quoted from Mr. Hall's paper before the Liverpool Geological Society, in 1864, as to the supposed ancient coast line, and submergence of the plain which once existed between the Great Ormes Head and Bangor, which is said to have taken place in the fourth century, when the lands and castle of Helig - ab - Glanawg were destroyed* The author also described Mr. Hall’s visit to the supposed ruins of this castle, marked “ Llys Helig ” on the ordnance map, only to be seen at very low tides, and submitted a diagram, copied from the plan of the walls and tower then taken ; he also gave the legend of the destruction of this castle, which is still told by the old Welsh people living near. The author concluded that when the refuse heap of' shells and bones was deposited, the coast line must have been somewhat the same as it is now, as patella, purpura, &c., being rock shells, could not have been found on a flat sandy coast; if, therefore, the plain was submerged in the fourth century, these shells must have been deposited subsequently; as besides the absence of rocks, the coast 123 would, before that time, have been too distant to render it likely the inhabitants should bring their food so far from where it was found. The very large size of many of the shells of patella, would seem to prove that the coast had been some considerable time in its present rocky condition, when the shells were gathered, whereas the absence of all traces of bones and teeth of the hog, which are found in such abundance in later deposits, seems to point to the seventh and eighth century as the probable date of the formation of this shell deposit. PHYSICAL AND MATHEMATICAL SECTION. January 4th, 1870.' E. W. Binney, F.R.S., F.G.S, President of the Section, in the Ohair. “ On the Rainfall of 1869, at Old Trafford, Manchester,” by G. Y. Vernon, F.R.A.S, F.M.S. The rainfall of 1869 exceeded the average of the last seventy-six years by 0'043 inches, so that the fall was almost exactly the average amount for that period. Rain fell upon 197 days in 1869, or upon nine more days than in 1868. During the first and last quarters of 1869 the rainfall exceeded the average of the corresponding periods for the last seventy-six years, and during the second and third quarters the rainfall of 1869 was below that average. As compared with 1868, there was 3'221 inches more rain in 1869. January, February, April, May, September, November, and December, 1869, had a rainfall in excess of the average, especially F ebruary and September, the latter month having nearly double the average rainfall. 124 The remaining months of 1869 had a deficient rainfall, especially March, June, and July, the latter month not having one third the average fall. The months in which rain fell upon the largest number of days were January, February, September, November, and December; September reaching the large number of twenty-six days. OLD TRAFFORD, MANCHESTER. Rain Gauge 3 feet above the ground, and 106 feet above the sea. Quarterly Periods. 1869. Fall in Inches. Average of 76 Years. Difference. No. of Days Rain- fall in 1869. Quarterly Periods. Differ- ence. 1868. 1869. 76 Years. Inches. 1869. Inches. Days. Days. c Jan. ... 2-686 2-498 ■4-0-190 21 ) 57 52 3 Feb — 4*436 2-418 4-2-018 21 [ 7-210 8-392 4-1-182 l March. 1-270 2-296 —1-026 10 ) c April... 2-096 2-028 4-0-068 14 ) 33 40 3 May . . . 2-726 2-336 4-0-390 17 [ 7-191 5-944 —1-247 l June .. 1-122 2-827 —1-705 9 ) c July... 1-131 3-550 —2-419 8 ■) 30 44 < August 2633 3-560 —0-927 10 [ 10-381 10-084 —0-297 l Sep 6-320 3-271 4-3.049 26 ) c Oct 3119 3-818 —0-699 19 ) 68 6! Nov.... 4-284 3-846 4-0-798 22 > 10-621 11*026 -j-0-405 ( Dec. . . . 3623 3-317 4-0-306 20 ) 188 197 35-446 35-403 4-0-043 197 35-403 35-446 4-0-043 March 1st, 1870. E. W. Binney, F.R.S., F.G.S., President of the Section, in the Chair. “Results of Rain-gauge and Anemometer Observations made at Eccles, near Manchester, during Jhe year 1869,” by Thomas Mackereth, F.R.A.S., F.M.S. The following amounts of rainfall are obtained from two gauges 3 feet from the ground and 145 feet above mean 125 sea-level, and one gauge 34 feet from the ground. One of the lower gauges has a round receiver lOin. in diameter, the other has a 5in. square receiver; the edges of both are turned inward. These two gauges stand close to each other, and 75 feet from any building, and free from every obstruction. The higher gauge has a 5in. square receiver, like the one near the ground. It is four feet above the ridge of my house, and free from every obstruction. First, I represent the rainfall for 1869, as measured by the lOin. gauge. This I have compared with the average fall for nine years at Eccles. Quarterly Periods. 1869. Fall in Inches. Average of 9 Years. Differences. Quarterly Periods. Average of 9 Years. 1869. Average of 9 Years. 1869. Days Days « ( January 2-491 2-632 —0-141 ) 53 56 j February 3-997 2-441 -f-1-556 [ 7-644 7-888 (, March 1-400 2-571 —1171 ) ( April 2-292 1-959 4-0-333 \ 41 44 } May 2-974 2-180 4-0-794 [ 6-589 6-524 f June 1-258 2-450 —1-192 ) (July 1-122 3192 —2-070 ) 50 48 < August 3-115 3-363 —0-248 [ 10-726 10-432 (. September 6-195 4-171 4-2-024 ) ( October 3-129 3-657 —0-528 ) 56 62 < November 4-285 3-411 4-0-874 [ 10-420 10-857 December 3-443 3-352 4-0-091 ) 200 210 35701 35-379 4-0-322 This table shows that the rainfall for the year was very nearly the average amount for nine years. The fall in each month has been somewhat irregular, but a glance at the quarterly periods for the year, and the average fall, will show that the rainfall for 1869 was seasonably regular. September was an unusually wet month, and from the average fall it appears to be the wettest month of the year. Nearly two thirds of the rainfall of last year fell from August to December. The least amount of rain and the fewest number of wet days happen in the spring months, at 126 least from the beginning of April till the end of June. The wettest season sets in in September. The next table shows the monthly amounts that fell in each gauge, together with the number of miles of horizontal movement of the air. 1869. Rainfall in lOin. Round Gauge, 3 feet from Ground. Rainfall in 5in. Square Gauge, 3 feet from Ground. Rainfall in ; 5in. Square Gauge, 34 feet from Ground. Amount of the Horizontal Movement of the Air in Miles. January 2-491 2-538 1-762 4-996 February 3-997 3-971 2-884 5-920 March. 1-400 1-365 1-035 4-735 April 2-292 2-257 1-842 2-861 May 2-974 2-920 2-888 2-848 June 1-258 1-222 1-045 1-410 July 1-122 1-086 0-838 1-355 An crust 3-115 3-106 2533 2-021 September 6-195 6-218 5-039 3-516 October 3-129 3-073 2-610 3-644 November .. ... 4-285 4-209 3-389 3145 December 3-443 3-441 2-755 3156 Totals 35-701 35-406 28-620 39-607 This table, like previous ones I have read to this Section, shows that the greatest horizontal movement of the air happens in the winter months, or from about September to March. And as may be expected, the maxima occur at or about the time of the equinoxes. It likewise shows that an excess of windy weather is attended with an excess of rain- fall. I would also draw attention to the close similarity of amount of rainfall measured by the lOin. round, and the 5in. square gauge. The small difference is almost identical with those of previous years. In the next table I have given the average daily fall of rain in each kind of gauge, and the ratio of amounts, when the velocity of the wind has ranged between the number of miles indicated in the first column. 127 Daily Movement of Wind, 3 feet from the Ground. 34 feet from the Ground. 5in. Square Gauge. A. 5in. Square Gauge. B. Ratio of B to A. Miles. In. In. 0 to 50 •123 •114 •926 50 to 100 •175 •144 •822 100 to 150 •138 112 •811 150 to 200 •201 •165 •820 200 to 250 •246 •206 •837 250 to 300 *162 •106 •654 300 to 350 •310 •217 •700 350 to 400 •172 •109 *634 Above 400 •090 •090 1-000 MEAN 200 to 250 179 •140 •782 This table shows, as previous ones have done, that the heaviest falls of rain happen as the movement of the air increases. Though on carefully examining this and other tables I have produced, there is a limit to' this law. The maximum of fall with high wind appears to be attained when the wind moves at an average rate of about 12 miles per hour. The ratio column shows, what my other tables have done, that about three quarters of the amount of rain for the year falls at the height of 34 feet above the ground. The next table represents the rainfall during the day time of each month, or from 8 a.m. to 8 p.m,; and during the night, or from 8 p.m. till 8 a.m. 1869. Rainfall from 8 a.m. to 8 p.m. Rainfall from 8 p.m. to 8 a.m. Difference between Night , and Day Fall, January. February March April May June July August September October November December In. 1137 1-609 0- 898 1- 021 1-957 0-307 0-730 0- 833 3-198 1- 093 1-858 1-360 In. 1-401 2362 0- 467 1- 236 0-963 0- 915 0356 2273 3-020 1- 980 2- 351 2-081 Inches. -J-0‘264 +0-753 —0-431 +0-215 —0-994 +0-608 —0-374 +1-440 —0-178 +0-887 +0-493 +0-721 Sums 16001 19-405 +3-404 128 This table, like the one I communicated to the Section last year, seems to show that the night fall is mostly in excess in the coldest months of the year. I now submit a new set of tables relating to wind and rainfall. The elements from which the tables respecting the wind are deduced have been obtained from a self- registering pressure anemometer made by Mr. Oxley, and Dr. Kobinson’s anemometer. Very curious though not unexpected results are found on an examination of these tables. The first table represents the mean daily direction of the wind grouped under eight points of the compass. The amounts of horizontal movement of the air in miles for each day are grouped under the months of the year, and placed under the mean direction whence the movement came, and so arranged as to indicate whether the mean direction has been against or with the sun’s course. The direction of the wind is said to be against the sun’s course on the west side of the compass when the mean direction of one day is nearer the south point than it was on a previous day ; and with the sun’s course on the same side of the compass when the mean direction is nearer the north point than on the previous day. The reverse of these directions happens on the east side of the compass. The results of these directions appear at the foot of the respective columns, and they show that when the wind is blowing on the west side of the compass with the sun’s course, the horizontal movement of the air is greater than when it is blowing against the sun’s course. But when the wind is blowing on the east side of the compass with the sun’s course, the hori- zontal movement of the air is less than when it is blowing against the sun’s course. But the monthly results show that in every month of the year, excepting May, there has been an excess of horizontal movement of the air with the sun’s course ; hence that the westerty winds greatly prevail over the easterly ones. | Ratios! 1-150 1-879 1-056 1-410 0- 767 1- 061 1-247 1-446 1-858 1-375 1-579 1-098 m a m •ung 9in tiiiav pniAl Movement in Miles. 2.673 3,864 2,433 1.674 1,237 726 752 1,195 2,286 2,110 1,926 1,652 22,528 0* rH CO rH ■ung oqq. Isure.oL1 puiAV 2,323 2,056 2,302 1,187 1,611 684 603 826 1,230 1,534 1,219 1,504 17,079 F3 •ung 9ii; puiAv Movement in Miles. 314 25 207 18 15 85 21 324 1,009 N •ung aqi ■jsurexft? puiAV 76 38 608 172 662 12 142 52 1,762 to •ung eq* qpAi puiAv Movement in Miles. N 05 CD 05 CD © N : : ^ oo i— i n • o • •ung 9qi ^SUI'B.g'B PUIAV 1,025 202’ 1 4 194 1,425 cp QQ •ung eq^ PnTAY Movement in Miles. 1,216 382 201 9 ! 174 358 31 547 00 ,H CD of N •ung eq* ^suingn putAY 772 926 192 5 273 17 590 126 638 3,539 ' 00 U1 •ung eq; qqA puiAY Movement in Miles. 694 846 94 236 387 45 616 115 54 235 3,322 0 rH •ung eqq. IsureSn puiAY 228 568 206 163 215 35 407 129 320 85 CD ID CO cq rH Is •ung sq^ q^iAv putay Movement in Miles. 427 2,082 135 213 9 219 219 548 1,021 678 369 135 6,055 0 •ung 9qY ^sureg'B puiAY 244 471 205 139 408 34 262 122 737 666 191 3,479 i>, rH fc f5 •ung eqq. q^m puiAY Movement in Miles. 67 554 855 528 S9 454 116 584 177 429 1,229 162 5,244 CO ID co 00 •ung 9qi ^suroSu puiAY 471 173 106 69 165 302 50 228 1,564 £ 1 •ung aqi q^uv putAY Movement in Miles. 637 276 252 9 1 18 15 281 171 217 *>• X> 00 T— 1 i> 00 •ung 9q;» '^sui'bS'b puiAY 389 171 60 2 19 14 103 57 235 0 ID O rH x>- pH 1869. Jan.. . Feb... Mar. . April May.. June . J uly. . Aug. • Sep. .. Oct.. . Nov... Dec. .. Sums. Ratios 130 The next table represents the rainfall in inches in a simi- lar manner to that in which the horizontal movement of the air is represented in miles. The results of this table bear a most striking analogy to the previous one respecting the wind. More rain falls when the wind is blowing on the west side of the compass with the sun’s course than when it is blow- ing against it; and the reverse happens, as with the horizontal movement of the air, when the wind is blowing on the east side of the compass. And the monthly results are very similar to those respecting the wind, June and July being the only exceptions to the rule ; hence more rain falls during westerly than easterly winds. The ratios of the two tables are almost identical in kind though differing in amount. 00 O M PS 1-802 3- 880 1-243 1-980 4- 199 0792 0- 895 8-215 1- 661 1-063 1- 373 2- 980 Sums. •uns OTft qqAt pmAl Rainfall in Inches. 1-602 3178 •776 1- 523 2- 402 "556 •530 2- 777 3- 867 1- 613 2- 480 2-578 •uns etu ^smugu putAV •214 •322 •010 •811 •200 1-557 OQ •uns ©q* if«* PUFAV Rainfall in Inches. [ -199 •089 •027 •089 •153 •033 •047 CO cp CO 00 •uns eq^ ^sureS'B putAi •262 •035 •242 L • I - •539 pH GO •uns sip* q«AV puiAi Rainfall in Inches. •717 •187 •176 •562 •392 •047 •546 CM CO CO •uns ®qi ijsurrSu puiAi ■217 •512 •064 •267 •122 1*086 •106 •428 rH 1869. Jan ... Feb... Mar .. April. May.. June . July.. Aug.. Sep... Oct. .. Nov... Dec... Sums. Ratios 132 In the next table I represent the rainfall at the Salford Town Hall for 1869. The difference between this amount of rainfall and that at Eccles is about the same as last year, which is doubtless due to the different heights at which the two gauges are placed. The Salford gauge is about 8 feet above the ground. Quarterly Periods. 1869. . . Fall in Inches at Salford. Fall in Inches at Eccles. Difference from Eccles. 1 Days of ! Rainfall at Salford. Days of Rainfall at Eccles. ( January 2611 2-538 ■f0-073 53 56 < February 4-181 3-971 -j-0-210 ( March 0-985 1-365 —0-380 C April 2-245 2-257 —0012 43 44 < May 1-484 2-920 —1-436 (.June 1-313 1-222 +0-091 (July 1181 1-086 4-0-095 46 48 ■< August 2-794 3-106 —0-312 (.September 6-181 6-218 -0-037 C October . 3-061 3073 —0012 61 62 < November 4-223 4-209 +0-014 (. December 3-508 3-441 4-0-067 203 210 33-767 35-406 —1-639 Ordinary Meeting, March 22nd, 1870. E. W. Binney, F.R.S., F.G.S., Vice-President, in the Chair. Mr. James Teale, of Springfield, Sale, was elected an Ordinary Member of the Society. A letter from Mr. H. Wilde was read, stating that since the last meeting he had made a few experiments “ On the Suspension of a Ball by means of a Jet of Water,” and had found that the behaviour of the ball was the same in vacuo as it is in air. Mr. R Routledge stated that he had also made a few simple experiments, and had found that when a string was attached to the ball in such a manner as to prevent or impede its rotation about a horizontal axis, it was no longer continuously sustained by the jet. Also when the jet (directed horizontally to avoid the interference of the falling drops) was brought very near to the light ball suspended by a thread, the ball showed no tendency to move towards the jet. This invalidates the surmise that the jet is accom- panied by a current of air which tends to carry the ball into the jet. Professor Osborne Reynolds, B.A., said : After the discussion which followed my paper on this subject at the last meeting of this Society, I thought it would be well to substantiate as far as I could the truth of my hypothesis by experiments ; and the following is a description of what I have done in this way. Before describing the experiments, I will mention the immediate objects for which they were severally undertaken. First, I wished to show that the air was not the medium by which the water acted on the ball, Peoceedings — Lit. & Phie. Society. — Vol. IX. — No. 13. — Session 1869-70. 184 and this I have done by showing that the jet would pro- duce no effect on the ball unless actually touching it. Secondly, I wished to show that the horizontal equilibrium of the ball was due to its rotation; and thirdly, to find the limiting positions of that point on the ball in which it might be struck and remain in equilibrium, and moreover the nature of the equilibrium. The apparatus employed in these experiments consisted of a wheel three inches in diameter and half an inch broad at the rim, made of painted wood, capable of turning very freely about its axis, and suspended by two wires with its axis horizontal, so that it could swing like a pendulum. A vertical jet of water was so arranged that it could be made to strike the reel at any point from below, or to miss it altogether. This was done by bringing the jet out of a horizontal pipe which would slide backwards and forwards in the same direction as the wheel could swing. This pipe was furnished with a cock, so that the force of the jet might be altered. In experiment No. 1, the pipe from which the jet issues was pushed so forward that the jet missed the reel by about an inch, and the jet was turned on to rise about six feet above the reel ; the pipe was then brought back until the water passed as near as possible to the reel without touching it — but there was no apparent effect produced on the reel. The tap was turned so as to increase and then diminish the height to which the jet rose — still, without any effect. Experiment No. 2 was made with the same apparatus as No. 1. The reel was then changed for one six inches in diameter and the same experiment repeated. The jet was placed so that it missed the reel (when hang- ing freely) by about two inches, and the water was turned 135 on to rise about six feet. The reel was then pushed forward until it touched the jet and then let go; it immediately began to turn about its axis, but left the jet swinging back- wards and forwards, touching the jet each time, and each time gaining in speed of rotation. This went on for several oscillations, but as it got to turn faster it appeared to stick to the jet for an instant before letting go, and having done this once or twice, it stuck to the jet altogether and remained in contact with it, spinning rapidly. The experi- ment was then repeated with the jet at different distances and with the larger wheel : the result was the same in all cases. I found it possible however either to increase or to diminish the force of the jet enough to prevent the reel from remaining in contact with it. The limits were about 2 and 8 feet. In experiment No. 8, the position of the reel when free was carefully marked, so that the least alteration could be noticed, and the jet was placed directly under its centre. In this position the jet did not cause the reel to move to either side in particular, but to oscillate backwards and for- wards. The jet was then pushed slowly forwards, and the motion of the ball watched. At first it moved away from the jet slightly, and remained away until it was struck about 60° from its lowest point, after which it gradually came back to its initial position, which it reached when struck about 65° from its lowest point. The forward motion of the jet being continued, the ball began to follow the jet ; the point in which it was struck moving upwards very slowly. When the reel finally fell from the jet and came back into its initial position, the jet missed it by about 2J inches. This clearly shows that the position of equilibrium is about 25° from the middle of the ball, and for any deviation below this point the equilibrium is much more nearly neutral than for any deviation above it. 136 During the experiment the force of the jet was altered, hut within moderate limits this did not affect the position of equilibrium. The following extract of a letter, dated March 21st, 1870, from Sir Wm. Thomson, D.C.L., F.R.S., Hon. Member of the Society, to the President, was read : — I have now at last got into good working order measure- ments of electrostatic capacity (which, perhaps, you may remember I was working on the first time you ever came to see me, and more or less almost ever since.) I have two students of last year, junior assistants in my laboratory, measuring electrostatic capacities of condensers, and varia- tions of specific inductive capacities of resistance, with sensibility of to per cent, and with constancy in spite of accidental variations, generally within \ or J per cent. My occupation on the Kinetic Theory of gases has led me at last to come to definite terms as to the size of molecules. Ever since about the first year of my professorship I have taught my students that Cauchy’s theory of Dispersion proves heterogeneousness, or molecular structure, to become sensible in contiguous portions of glass or water, of dimen- sions moderately small in comparison with the wave lengths of ordinary light. I have spoken to you also, I think, of the argument deducible from the contact electricity of metals. This, I now find, proves a limit to the dimensions of the molecules in metals quite corresponding to that established for transparent solids and liquids by the dynamics of dispersion. In experiments made about ten years ago, of which a slight sketch is published in the Pro- ceedings of the Literary and Philosophical Society of Manchester, I found that a plate of zinc and a plate of copper kept in metallic connection with one another (by a fine wire or otherwise) act electrically upon electrified bodies in their neighbourhood, and upon one another, as they would if they 137 were of the same metal and kept at a difference of potentials equal to about three-quarters of that produced by a single cell of Daniell’s. Hence, and from my measurement of the electrostatic effects of a Baniell’s battery, published in the Proceedings of the Royal Society, for February and April, 1860, I find that plates of zinc and copper held parallel to one another at any distance, D, apart which is a small fraction of the linear dimensions of their opposed surfaces, and kept in metallic communication with one another, exercise a mutual attraction equal to A 2 x 10-10 x jy2 grammes weight. Hence if they were allowed to approach from any greater distance, I)', to the distance D, the work done by their mutual attraction is 2 x 10-10 x A(D' — D) D'D centimetre grammes ; which, if D is very small in comparison with D', is very approximately equal to 2 x 10-10 x ~ Now suppose a pile to be made of a great number (N + l) of very thin plates alternately of zinc and copper, kept in metallic connection while they are brought towards one an- other. Let their positions in the pile be parallel, with narrow spaces intervening. For simplicity let the thick- ness of each metal plate and intervening space be D. The whole work done will be 2 x 10-10 x Ng- The whole mass of the pile (if we neglect that of one of the end plates) is NAD P, where p denotes the mean of the densities of zinc and cop- per. Hence, if h be the height to which the whole mass must be raised against a constant force equal to its weight 138 at the earth’s surface, to do the same amount of work, we have NADp/i. = 2 x 10_l° x Ng> which gives 7 2 x 10-10 h~ pD2 ’ or, as o=8, nearly enough for the present rough estimate, h - 1 . (200000D)2 Hence if D = 2 o-oVoo- centimetre, h— 1 centimetre. The amount of energy thus calculated is not so great as to afford any argument against the conclusion which general knowledge of divisibility, electric conductivity, and other properties of matter indicates as probable : that, down to thicknesses of tooVoo of a centimetre for the metal plates and intervening spaces, the contact electrification, and the attraction due to it, follow with but little if any sensible deviation the laws proved by experiment for plates of mea- surable thickness with measurable intervals between them. But let D be a two-hundred-millionth of a centimetre. If the preceding formulae were applicable to plates and spaces of this degree of thinness we should have h = 1,000,000 centimetres or 10 kilometres. The thermal equivalent of the work thus represented is about 248 times the quantity of heat required to warm the whole mass (composed of equal masses of zinc and copper) by 1° cent. This is probably much more than the whole heat of combination of equal masses of zinc and copper melted together. For it is not probable that the compound metal when dissolved in an acid would show anything ap- proaching to so great a deficiency in the heat evolved below that evolved when the metallic constituents are separately dissolved,* and their solutions mixed ; but the experiment * Will you try this experiment ? You would easily make a good thing of it. 139 should be made. Without any such experiment however we may safely say that the fourfold amount of energy indi- cated by the preceding formula, for a value of D yet twice as small, is very much greater than any estimate which our present knowledge allows us to accept for the heat of com- bination of zinc and copper. For something much less than the thermal equivalent of that amount of energy would melt the zinc and copper; and therefore if in combining they generated by their mutual attraction any such amount of energy, a mixture of zinc and copper filings would rush into combination (as the ingredients of gunpowder do) on being heated enough in any small part of the whole mass to melt together there. Hence we may infer that the electric attraction between metallically-connected plates of zinc and copper of only 40070- 0075-00 of a centimetre thickness, at a distance of only ro-07000700-0 of a centimetre asunder must be greatly less than that calculated from the magnitude of the force and the law of its variation observed for plates of measurable thickness, at measurable distances asunder. In other words, plates of zinc and copper so thin as a four- hundred millionth of a centimetre, and placed at as short a distance as a four-hundred-millionth of a centimetre from one another, form a mixture closely approaching to a mole- cular combination, if indeed plates so thin could be made without splitting atoms. Wishing to avoid complication, I have avoided hitherto noticing one important question as to the energy concerned in the electric attraction of metallically connected plates of zinc and copper. Is there not a change of temperature in molecularly thin strata of the two metals adjoining to the opposed surfaces, when they are allowed to approach one another, analogous to the heat produced by the condensation of a gas, the changes of temperature produced by the appli- cation of stresses to elastic solids which you have investi- gated experimentally, and the cooling effect I have proved 140 to be produced by drawing out a liquid film which I shall have to notice particularly below ? Easy enough experi- ments on the contact electricity of metals will answer this question. If the contact-difference diminishes as the tem- perature is raised, it will follow from the Second Law of Thermodynamics, by reasoning precisely corresponding with that which I applied to the liquid film in my letters to you of February 2 and February 3, 1858,* that plates of the two metals kept in metallic communication and allowed to ap- proach one another will experience an elevation of tempera- ture. But if the contact difference increases with tempera- ture, the effect of mutual approach will be a lowering of temperature. On the former supposition, the diminution of intrinsic energy in quantities of zinc and copper, consequent on mutual approach with temperature kept constant, will be greater, and on the latter supposition less, than I have estimated above. Till the requisite experiments are made, farther speculation on this subject is profitless : but what- ever be the result, it cannot invalidate the conclusion that a stratum of 2-5-07000^-0-0 of a centimetre thick cannot contain in its thickness many, if so much as one, molecular con- stituent of the mass. Besides the two reasons for limiting the smallness of atoms or molecules which I have now stated, two others are afforded by the theory of capillary attraction, and Clausius’s and Maxwell’s magnificent working out of the Kinetic theory of gases. In my letters to you already referred to, I showed that the dynamic value of the heat required to prevent a bubble from cooling when stretched is rather more than half the work spent in stretching it. Hence if we calculate the work required to stretch it to any stated extent, and multi- ply the result by f, we have an estimate, near enough for my present purpose, of the augmentation of energy experienced Proceedings of the Koyal Society for April, 1858. 141 by a liquid film when stretched and kept at a constant tem- perature. Taking ’08 of a gramme weight per centimetre of breadth as the capillary tension of a surface of water, and therefore T6 as that of a water bubble, I calculate (as you may verify easily) that a quantity of water extended to a thinness of 2to-o5o;dto of a centimetre would, if its tension remained constant, have more energy than the same mass of water in ordinary condition by about 1,100 times as much as suffices to warm it by 1° cent. This is more than enough (as Maxwell suggested to me) to drive the liquid into va- pour. Hence if a film of ro-o^b 070-00 of a centimetre thick can exist as liquid at all, it is 'perfectly certain that there cannot be many molecules in its thickness. The argument from the Kinetic theory of gases leads me to quite a similar conclusion. I need not trouble you with it at present, as I am writing a short sketch of those of the results of Maxwell and Clausius which I use in it, to form part of an article on the Size of Atoms for “Nature.” Mr. R. D. Darbishire, F.G.S., exhibited a number of beautiful specimens of electroplate reproductions of some of the Roman plate lately found at Hildesheim, and gave a summary of Mr. Wieseler s very interesting discussion upon this find. “ On the Determination of Phosphoric Acid,” by William Carleton Williams, Student in the Laboratory of Owens College. Communicated by Prof. Roscoe, Ph.D., F.R.S. Of the many methods proposed for the separation of phosphoric acid from the alkaline earths, few are better than the one devised by W. Reissig, founded upon a process originally described by Reynoso. This method, although used in many German laboratories, has, strange to say, found but little favour among English chemists. This is probably 142 owing to the somewhat complicated and tedious nature of the operations required. The modifications described in the following communication considerably simplify the process, and may possibly lead to its more general adoption. Reissig’s method depends upon the fact that, when metallic tin is added in excess to a solution of the phos- phate of the alkaline earths in nitric acid, the stannic acid formed by the oxidation of the metal combines with the phosphoric acid and completely removes it from solution. On filtering, therefore, we at once separate the alkaline earths which remain in solution from the insoluble combi- nation of stannic and phosphoric acids. In order to deter- mine the amount of phosphoric acid contained in the tin oxide, the compound is dissolved in a small quantity of concentrated potash solution, when the two acids dissolve as meta-stannate and phosphate of potassium : the fluid is now saturated with hydrogen sulphide, a small quantity of ammonium pentasulphide added, and, lastly, a slight excess of acetic acid. The tin sulphide is then separated by fil- tration : all the phosphoric acid is contained in the filtrate, and its amount may be determined by the ordinary method as magnesium ammonium phosphate. The chief disadvantage of this method arises from the necessity of employing a large excess of metallic tin, in order to completely remove the phosphoric acid from solution. The bulk of tin sulphide obtained is therefore very large, and its filtration and washing is an exceedingly long and tedious operation. In order to shorten the process, Reissig recom- mends that the alkaline solution of the phosphate and stannate be transferred to a weighed flask of 1000 cubic capacity, and then diluted with water until the fluid measures about 900 cubic; the solution is next saturated with hydrogen sulphide, then ammonium sulphide and acetic acid in slight excess added, and the tincture diluted until the whole weighs 1000 grams. After standing for a 143 few hours the clear supernatant liquid is carefully poured through a niter, taking care not to disturb the precipitate. In the filtrate the phosphoric acid is estimated as magnesium pyrophosphate. The amount of the fluid employed in the determination is ascertained by again weighing the flask. On substracting the weight of the tin sulphide calculated from the quantity of the metal originally employed, we have all the data required to determine the amount of phosporic acid in the entire solution. This method of proceeding is not altogether faultless in principle. (1) It presupposes that from a known weight of tin-foil we are able to calculate the amount of tin-sulphide it will yield. Now the tin-foil of commerce is seldom or never pure, it almost invariably contains a considerable proportion of lead, often amounting to ‘ one-third of its weight,* and this of course passes into the nitric acid solution of the alkaline earths. (2) Since only a por- tion of the phosphoric acid present is actually weighed, the remainder being deduced by calculation, the chances of ultimate error are considerably increased. These sources of error are removed by simply filtering and washing the tin sulphide by means of the Bunsen “ water-pump,” an operation of comparative short duration. We thus obtain the whole quantity of phosphoric acid in solution, and entirely obviate the numerous weighings, involving, too, the very uncertain correction for the amount of tin sulphide present. In order to test the trustworthiness of the method thus modified, the following experiments were undertaken. A quantity of pure calcium phosphate was prepared by adding calcium chloride to an excess of sodium phosphate, and the precipitate washed, dried and ignited. About 0-5 gram, of this compound was weighed out into a porcelain basin, and dissolved in a small quantity of nitric acid; the solution * The tin-foil employed in my experiments contained 31*35 per cent lead. 144 was then concentrated, and the strongest nitric acid (boiling at 86° C) added until the calcium nitrate commenced to separate out. This was immediately redissolved by the addition of a few drops of dilute nitric acid. The nitric acid solution is now in the highest possible state of concen- tration : on throwing a small quantity of tin into this solution, the metal is rapidly oxidized to stannic acid, and the supernatant liquid remains perfectly clear. The pre- liminary heating of the solution is indispensable, since in the cold the metal is apt to become passive, when it com- pletely resists the action of the acid. The precipitate is now dissolved in a small quantity of caustic potash, and saturated with hydrogen sulphide : on adding acetic acid in slight excess the tin sulphide is precipitated. The preci- pitate is then separated by means of the Bunsen '■‘filter- pump,” and the whole of the phosphoric acid is contained in the filtrate. After concentrating the solution, and again filtering from a minute precipitate of tin sulphide, which invariably separates out (tin sulphide being slightly soluble in solutions containing hydrogen sulphide), the phosphoric acid may be precipitated as the magnesium ammonium salt, and weighed as pyrophosphate. I. Katio of tin to phosphoric acid, 4 to 1. 1. 0*5135 grm. cal. phos. gave 0*405 Mg2 P207 = 50*4 5°/0 P205 II. 0*447 „ „ 0*358 „ 50*78 „ Mean 50*61% P205 The lime was determined as caustic lime after removal of the lead by means of hydrogen sulphide. The mean of two concordant analyses gave 49*65% lime. Hence the composition of the calcium phosphate is Phosphoric Acid 50*61 Lime 49*65 100-26 \ 145 It is therefore evident that the amount of pure tin re- quired need not exceed 4 times the weight of phosphoric acid present. The following experiments show that this is moreover the minimum quantity that can be used. II. Ratio of tin to phosphoric acid = 3*0 to 1. 0-477 grm. cal. phos. gave 0*307 M g2 P207 = 4T53°/o P206 III. Ratio of tin to phosphoric acid = 3*5 to 1. 0-598 grm. cal. phos. gave 0*388 Mg2P207 = 41'570P205 0-434 „ „ „ 0-304 „ 44-82 „ In order to confirm the above results I have determined the proportion of lime and phosphoric acid contained in the calcium phosphate employed in the analyses, by dissolving the compound in hydrochloric acid, and adding sufficient sulphuric acid to precipitate the base. To each volume of the liquid two volumes of alcohol were added, and the mix- ture allowed to stand about 12 hours, when it was filtered and the precipitate thoroughly washed with alcohol. The filtrate containing the phosphoric acid is evaporated to dry- ness, the residue dissolved in water, and the acid precipi- tated as the magnesium ammonium salt. The lime was weighed as sulphate. I. 0*525 grm. gave 0*411 Mg. P207 = 50-08 °/Q P2Ch II. 0-507 „ 0-396 „ „ -49*96 °/o PA The lime amounted to 50 per cent. Hence the composition of the calcium phosphate is P205 50-02 CaO 50-00 100-02 exactly agreeing with the determinations made by the tin method. 146 “ On the Composition of the Water of the Irish Sea/’ by T. E. Thorpe, Ph.D., and Mr. E. H. Morton. Thanks to the investigations of Forchhammer, Yon Bibra, Bischof, and others, our knowledge concerning the nature and distribution of the saline constituents of sea water and of the causes of the variations in its composition as observed in various parts of the world, is tolerably extensive and pre- cise. English chemists however have contributed next to nothing to the general stock of our information on this sub- ject. This is not a little remarkable, especially when we consider the peculiarly favourable condition in which this country is placed for researches of this kind, by reason of its insular position. A few observations by John Davy made in the course of his long voyages, two memoirs by Marcet in the Philosophical Transactions for 1819 and 1822 on the temperature and saltness of various seas, and an elaborate analysis by Schweitzer of the water of the English Channel made in 1838, constitute by far the chief portion of the work done in this direction by English chemists. The chemical history of the sea is mainly to be derived from the researches and observations of chemists principally French and German, the majority of whom were located at consider- able distances from the sea-board, and who laboured therefore under all the disadvantages which this circumstance neces- sarily entails. So far as we can learn the water of the Irish Channel has never been analysed. We have been induced therefore to undertake its analysis in the hope of supplying information respecting the nature and extent of the modifica- tions effected in the composition of the sea by its proximity to our coasts. Accordingly Captain Temple of the “ Bahama Bank” Light Ship kindly collected for us a quantity of the water in the immediate neighbourhood of his vessel. The vessel is situated in lat. 54° 21' N. and long. 4° 11/ W., seven miles W.N.W. of Ramsey, Isle of Man, and is placed nearly equi-distant from the shores of England, Scotland, and Ireland, 147 During the greater part of the day a strong current setting in from the south, probably from the Atlantic, flows past the ship into the North Channel, and thence again into the Ocean. The water therefore taken for analysis was origin- ally that of the deep ocean, which had traversed almost the entire length of the Irish Channel, and had consequently been exposed to all the influences due to the neighbouring sea-board, and to the influx of the numerous rivers along the coasts. The water was obtained in the early part of January, 1870; the meteorological conditions at the time of collec- tion, and for some time previously, were in no wise remark- able. The analysis was commenced immediately on receipt of the water. Its specific gravity compared with distilled water, free from air, and possessing the same temperature, was found to be At 0° C 1-02721. At 15° C 1-02484. These numbers differ but slightly from that usually accepted as representing the mean specific gravity of the water of the ocean. The water of the Atlantic, according to Yon Horner, possesses the specific gravity 1-02875 at 0° C : that of the English Channel at 15°-5 was found by Schweitzer to be 1-0271 : on nearing the land the specific gravity fell to 1-0268. Full details of the methods of analysis employed are given in the original paper. The following synopsis shows the mean results of the determinations : the numbers express the amount of the various ingredients in 1000 grams of the sea-water. 1 Chlorine 18-62650 2 Bromine ‘06133 3 Sulphuric Acid (S04) 2-59280 4 Lime (total) -57512 5 Calcium Carbonate -04754 148 6 Magnesia 2*03233 7 Mixed Alkaline Chlorides .. . 27*18363 8 Potassium *39131 9 Sodium 10*40200 10 Ferric Oxide -00465 11 Ammonia *00011 12 Nitric Acid -00156 13 Fixed Constituents 33*83855 These substances arranged on the assumption that the strongest acid is united with the strongest base, yield the following numbers : — Sodium Chloride 26*43918 Potassium Chloride *74619 Magnesium Chloride 3*15083 Magnesium Bromide -07052 Magnesium Sulphate 2-06608 Magnesium Carbonate traces. Calcium Sulphate T33158 Calcium Carbonate *04754 Lithium Chloride traces. Ammonium Chloride *00044 Magnesium Nitrate *00207 Silicic Acid traces Ferrous Carbonate *00503 33-85946 Amount directly determined 33*83855 The water employed in the foregoing analysis was collected in midwinter. It becomes interesting to know if its composition is uniform during the various seasons of the year. Fortunately we can offer some evidence on this point. In August, 1865, after a continuance of exceptionally fine weather, one of us collected some sea water in the neighbour- hood of the “ Bahama Bank” Light Ship, and determined the total quantity of its saline constituents, together with the amount of chlorine and sulphuric acid. The proportion 149 of solid matter contained in the water of the Irish Sea is somewhat greater in summer than in winter — the variation amounting to (H)144yo — hut the relative amount of solid matter present in the water of the Irish Channel is invari- ably less than is contained in the water of the Atlantic Ocean lying between the same parallels. According to Forchhammer, the mean proportion of the leading constituents of the water of the Atlantic far away from the shores is as follows : — Cl. so3. CaO. MgO. Total Salts. Absolute amount in ) 1,000 grams 3 19-885 2-362 0-588 2-199 35-976 Relative amount 100 11-89 2-96 . 1107 181-10 Arranged in this manner, our determinations on the water of the Irish Sea give the following proportions : — | Cl. S03. CaO. MgO. Total Salts. Absolute / Amount ' l Summer ... 18-735 2-187 34-082 per 1,000 grams. < Winter ... 18-627 2-161 0-575 2-032 33-838 Relative j Summer . . . 100 11-67 181-91 Amount J „ Winter 100 11-83 3-09 10-93 18209 Mr. W. L. Dickinson communicated a paper containing the results of calculations relative to the three Occupations of the Planet Saturn by the Moon, April 19, July 10, and September 30, visible in England during the present year. The calculations have been made for the Observatory of the late Pobert Worthington, Esq., F.P.A.S., Crumpsall, near Manchester, Lat. 53° 30' 50r/*0 N., Long. 0h 8m 56s T6 W. The 150 Elements used in the computations have been obtained from the Nautical Almanac. 1870. Sidereal Time at Observatory. Mean Time at Observatory. Mean Time at Greenwich. Angle N. Point from Vertex April 19. h. m. s. h. m. s. h. m. s. o First contact 16 36 31 14 44 32 14 53 28 106 95 Disappearan ce. . . 16 37 12 14 45 13 14 54 9 Reappearance . . . 17 44 0 15 51 50 16 0 46 Last contact .... 17 44 42 15 52 32 16 1 28 237 235 July 10. First contact 20 15 58 13 0 58 13 9 54 57 81 Disappearance ... 20 16 38 13 1 38 13 10 34 Reappearance . . . 21 14 15 13 59 6 14 8 2 Last contact .... 21 14 53 13 59 44 14 8 40 295 325 Sept. 30. First contact 18 27 3 5 49 57 5 58 53 88 97 Disappearance ... 18 27 37 5 50 31 5 59 27 Reappearance . . . 19 40 36 7 3 18 7 12 14 Last contact .... 19 41 9 7 3 51 7 12 47 258 277 The Angles are reckoned towards the right hand round the circum ference of the Moon’s image as seen in an inverting telescope. 151 Ordinary Meeting, April 5th, 1870. J. P. Joule, D.C.L., LL.D., F.RS., &c., President, in the Chair. Mr. J. S. Kipping and Mr. W. Mellor were appointed Auditors of the Treasurers Accounts. Mr. Binney, on behalf of Mr. Bernard Hartley Green, of Hopwood Avenue, presented to the Society the MS. Journal of Mr. George Walker, one of the original members. This contained many useful and interesting meteorological and other observations, with lists of prices of cotton, and notices of the first steam engines in Manchester. As to cotton is the following : — Sep. 8th, 1779 — This day expresses arrived at Manchester with the news of the Grenadas being taken by the French : this raised the price of cotton as follows — Grenada from l4§d. to 16Jd. Manchester. Tobago 15 17 St. Domingo 16 18 Oct. 14, 1779 — Prices of cotton at London, Smyrna 15J-d., Grenada 18d., Tobago 19d., Domingo 21d. Octr. 23. Smyrna 15fd., Grenada 19d., Tobago 20d. Deer. 16. Smyrna 16d., Grenada 20d., Tobago 2 Id. This extract shows the limited supplies of cotton at that early period. With respect to steam engines is the following : — Sep. 26th, 1788 — -Fire engine or steam engine, Shade hill, to raise water on the old construction. Examined this day in com- pany with the eldest son of Sir John Stanley. Cylinder in dia- meter 64 inches. Two pumps of cast iron each 31 inches. Makes 11 strokes in one minute, and each stroke is 7 ft. 9 inches depth PuociEDiNas— Lit. & Phil. Society.— Vol.IX.— No. 14.— Session 1869-70. 152 in the pumps. Mr. Barton told us the quantity of water raised by each stroke was about 64 gallons. He reckoned the power Of pressure on the piston equal to 81b. per inch square. Two boilers 14 ft. 6 inches and 14 ft. 4 inches in diameter. Depth of water in these boilers about 3 feet. About five tons of coal consumed every 15 hours, or one day’s work. 64 x 64x '7854-3217 square inches the piston 8 lbs. 25736 power to work the engine. But the water raised at each stroke is only 512 lbs. average, for 31 x 31 x 7 "75 = 7 447*7 5 + 7447 '75 = 14895'5 inches or 64 gallons. On the motion of Mr. Binney, seconded by Mr. Dickin- son, it was resolved unanimously — That the thanks of the Society be given to Mr. Green for his interesting and valu- able donation. “Description of a New Anemometer,1 ” by Mr. Peter Hart. On the appearance of Mr. Fletcher’s admirable paper “ On the Speed of Air in Flues,” it appeared to me that an anemo- meter more easily read and less costly than his was desirable. With this view I devised the present one, which may be broadly described as a common U tube gauge laid in a sloping position so as to form the hypotenuse of a right- angled triangle, the perpendicular of which is the true reading. The following description will explain its construction : — It consists first of a base board furnished with levels and levelling screws ; to this is hinged the board carrying the U tube, which may be called the sloping base ; on this sloping base is secured the U tube furnished with a scale and ver- nier capable of being read to the rwotli inch. By means of a screw passing through the sloping base, and resting on the lower base board, the former can be made to assume any angle with the latter, the angle being determined by a quadrant fixed to the lower base board. 153 By this arrangement a very great degree of accuracy in reading is obtainable. Thus in the present instrument the quadrant is set 5 inches distant from the hinge, and when set at 0-5 inches on the quadrant it gives a rise of 1 in 10 ; consequently the ether in the U tube has to move 10 inches for 1 inch of vertical rise. The rule for getting the result may be stated thus : — Divide the space between the hinge and the quadrant by the quadrant elevation, now divide the movement of the ether by the quotient, and the product is the true vertical movement nearly. Thus, suppose, as before, the quadrant elevation to be 05 inch, the distance from hinge to quadrant 5- 0 inches, and the ether’s movement 1 inch : then J5_ 0-5 TO = 10 and — - = 0T 10 inch. Or again, the quadrant elevation being 0*2 inch, the other quantities the same : then 5 TO A O = 0*25 and — = 0'04 inch. 0-2 1-25 These results, though not absolutely correct, will in most cases be sufficiently so ; but where rigid accuracy must be had, the following table will supply the means : — Quadrant Elevation in Quadrant Elevation in 10 inches. Hypotenuse. 10 inches. Hypotenuse. '1 inch ... ... 10*00049 IT inch ... ... 10-06035 •2 „ ... ... 10-00199 1-2 „ ... ... 10-07174 •3 „ ... ... 10-00449 1-3 „ ... ... 10-08414 ■i „ ... ... 10-00799 1-4 „ ... ... 10-09752 •5 „ ... ... 10-01248 1-5 „ ... ... 10-11187 •6 „ ... ... 10-01799 1-6 „ .... ... 10-12714 •7 „ ... ... 10-02447 1-7 „ ... ... 10-14347 •8 „ ... 10-03199 1-8 .... ... 10-16061 •9 „ ... ... 10-04049 1-9 „ ... ... 10-17888 1-0 „ ... ... 10-04987 2-0 „ ... ... 10-19803 hirst find what aliquot part of 10 the quadrant elevation was ; find this in the quadrant column. Opposite this will 154 be found a number which is the hypotenuse. Then, as this number is to 10, so is the number obtained by the first method to the true number. Thus, to take the first illustration, of 0'5 in 5 inches : this is equal to 1 in 10. The hypotenuse of 1 in 10 (see table) = 10'04987. Now, 01 inch was the result obtained. Then, as 1004987 ; 10 : ; 01 ; 0 09955, which is the true vertical rise. I had no little difficulty in my first efforts to restrain the excessive oscillations of the ether column, owing to the almost constant fluctuations of draught in flues. To obviate this the tube was choked to a narrower bore at the bend. This proving insufficient, I overcame the defect by the very simple means of inserting a piece of sponge at this part. It is perhaps needless to add that it is necessary to employ Mr. Fletcher’s tubes for insertion into the flue, and also his tables. Settle Cave Exploration. Mr. W. Boyd Dawkins, F.R.S., described the results of the preliminary investigation undertaken by the Settle Cave Exploration Committee. The cliffs of mountain limestone in the neighbourhood of Settle are penetrated by numerous caves, some of which are empty, some traversed by water which is silting up their lower chambers, while others have been filled in some places up to the very roof with debris of various kinds. All these caves have been at some time or other subterranean watercourses, and have been formed partly by the friction of the substances brought down by the stream, but principally by the chemical action of the carbonic acid in the rain water by which the insoluble carbonate of lime of the rock is converted into the soluble bicarbonate. Some have been inhabited at various time®, by man and wild beasts, and therefore may be expected to furnish valuable evidence of a condition of things 155 that has now passed away. The last recorded case of their being used by man as a place of refuge was in the rebellion of 1745, when the eldest son of one of the gentle- men in the neighbourhood was hidden in a large cave, in the fear that the Scotch would pass southwards in that direction, instead of by the Preston route. The first cave chosen by the committee for exploration is that found by Mr. Jackson on the coronation day of our Queen, and which is therefore known as the Victoria cave. It consists of a series of large chambers and passages, which are nearly filled to the roof with reddish grey clay and stones. It must at one time have been of wonderful beauty, for there are the remains of massive stalactites and of thick pavements of stalagmites ; but now they are so decomposed by the carbonic acid that they are reduced to the condition of very soft mortar. Curiosity hunters have also been doing their usual ruthless mischief. Mr. J ackson obtained, when it was first opened, a remarkably large series of ornaments and implements of bronze, iron, and bone, along with pot- tery and the remains of animals, from the chamber at the original entrance. They were all derived from a superficial deposit, and could not be assigned to any earlier date than that of the Roman occupation. The pottery was of the same kind as that so commonly found in the refuse heaps round Roman villas, and some of it was Samian. There were also Roman coins. The broken and in some cases burnt bones belonged to the Celtic short-horn ( bos longi- frons), the sheep or goat, the horse, dog, red deer, and roe-buck. The two former animals were by far the most abundant. The exploration committee resolved to follow up this discovery by a thorough examination of the cave, which they are able to undertake by the courteous per- mission of the owner, Mr. Stackhouse. Outside the entrance of the cave, and at lower level is a small plateau, composed of debris, which lies at the exact 156 point where daylight could be seen through chinks from the inside of one of the large chambers. As both the plateau and the chamber were undisturbed, the committee deter- mined to begin work by removing the debris, and making a new entrance into the cave. While this was being done, the following section was exposed. On the surface there was a stratum of fragments of limestone that had fallen from the cliff above, in thickness about two feet. This rests on a layer of dark earth 18 inches thick, that furnished large quantities of bones, nearly all of which had been used for food, and several articles of bronze, iron, and bone of the same kind and age as those described above. The pottery is also of the same Roman character. Fragments of char- coal also were abundant, and some stones bore the marks of fire. There can be no doubt that this was the place where the dwellers in the cave during Roman or imme- diately post-Roman times in Britain kindled their fires and cooked their food. Underneath is an accumulation of lime- stone fragments, that had dropped from the action of the atmosphere on the cliff above, from six to seven feet in thickness. In some places they were coated with decom- posed stalagmite. It rested on a layer of grey clay. On the junction line between them and close to the entrance that is now being made into the chamber, two rude flint flakes, a remarkably large jawbone of bear, the broken bones of (Bos longifrons) the Celtic shorthorn, and of the red deer were found. On 4th April a most remarkable bone harpoon was dug out from the same horizon. It is between 4in. and 5in. in length, and is furnished with two barbs arranged on each side opposite each other, that compose the head of the implement. The base presents a form making its attach- ment to the handle secure, which, so far as my knowledge goes, is new to Britain. Instead of having a mere projec- tion to catch the ligatures there is a well-cut barb on either 157 side, that points in a contrary direction to those on the head. Were the bases of a barbed arrow head and of a harpoon joined together, the resultant would be a form analogous to this in question. There can be no doubt that man occupied the spot before the accumulation of the over- lying of stones. Ample use for his harpoon he would find in the mere, now drained and turned into green fields, which lie but a short distance away. So far as the work has proceeded there is no trace of metal at this horizon in the section. The value of the evidence hitherto obtained lies in the fact that the Roman stratum is separated from the lower bed from which the flints, harpoon, and bear were found by the talus of angular stones. And this in a rough way will enable a computation to be made of the lapse of time between them. If we allow that for a con- siderable time past the disintegration of the cliff has been equal in equal times, the accumulation of stones above the Roman stratum is an index to the date of the lower horizon. This amounts to a maximum of two feet. If then in 1,200 years — to put it at the lowest — only a thickness of two feet has been accumulated, it would take 3,600 years for a deposit of six feet to be formed. And thus the harpoon and flint stratum would be about 4,000 years old allowing about 400 years for the accumulation of that which contained Roman remains. The accuracy of this calculation is indeed injured by the possibility that the winter cold was more intense, and the splitting action of the frost greater then, than during the last 1,200 years. Never- theless, the change from the Arctic severity of the post- glacial winter to the climate which we now enjoy in Britain, has been so gradual, and spread over such a length of time, that it may be assumed to have been very small in so short a period as 4,000 or 5,000 years. 158 Mr. W. L. Dickinson read a paper “ On the Eclipse of the Sun. December 21-22, 1870.” This eclipse begins in the North Atlantic Ocean ; the line of central and total eclipse moving in a south-easterly direction, crosses Portugal a little to the south of Lisbon ; passing over part of Spain and the Mediterranean Sea, it enters Africa near Oran, and soon afterwards attains its extreme southern limit ; the shadow of the moon, now moving in a north-easterly direction leaves Africa, and crossing the island of Sicily, the south of Turkey, the Black Sea, and the Sea of Azof, disappears ; the penumbra of the moon, decreasing rapidly, leaves the earth with the setting sun in Arabia, The sun will be centrally and totally eclipsed at noon, in Lat. 36° 28' N., Long. 5° 1' W., a little to the north-east of Gibraltar. The Eclipse as seen in England will be partial ; and as the sun will be at its greatest southern declination, it has not been considered requisite to perform the labour of computing from the Elements of the Eclipse. The subjoined particulars are the results of a calculation made for the Observatory of the late Robert Worthington, Esq., F.R.A.S., Crumpsall, near Manchester, from the following numerical equations given in the Nautical Almanac. The geogra- phical position of the Observatory is Lat. 53° 30' 50//o0 N., Long. 0h 8m 56ST6 W. For any place not far distant from Liverpool, whose Geocentric North latitude is l and East longitude X, the Mean Greenwich time t of beginning may be computed by the formulae, cosw = 1 -4612 — [0*2241 2] sin £ + [9*88272' £=lh3m438— [3*65845] sin ^ — [312314 cos (A + 73° 15'-9) Contact on sun’s limb, to — 9° 52' 3 from the North towards the West. cos£cos(A + 142° 33;*9) sin l — [3*91792] cos l Also the Mean Greenwich time t of ending by the formulae, cosw- 1*5480— [0*22908]smT+ [9*85616]cos£cos(A + 193° 32/*0) t = 0h lm 38s + [3*66027] sin w— [2*72415] sin l— [3*92440] cos l cos (A + 111° 58N>) Contact on sun’s limb, to + 3° 54L6 from the North towards the East. Eclipse begins Dec. 21, 23h 5m 22s ] Greatest Phase „ 22, 0 21 3 r Eclipse ends „ 22, 1 36 57 ) Mean Time at Greenwich. 159 Magnitude of the Eclipse (suns diameter - 1) 0-803. f first contact, 94° towards the West. Angle, ii om North Pole, of | jag^. contact?1073 towards the East. ( first contact, 85° towards the W est Angle, fiom Yeitex, of ^ contact, 95° towards the East for direct image. “ On the Influence of Changes in the Character of the Seasons upon the Rate of Mortality,” by J oseph Baxendell, F.R.A.S. In the summer of last year, I undertook a discussion of the Rainfall Observations made at the stations of the Man- chester Corporation Water Works during the 14 years 1855-1868, and among the results obtained, I found that although the total amount of rainfall in different years appeared to be governed by no regular law, yet that the proportional amounts in the different seasons during the eight years 1855-62, exhibited a marked contrast to those in the six years 1863-68, — the amounts in the spring and summer months exceeding those in the autumn and winter months during the former period, while in the latter, the autumn and winter amounts exceeded those of spring and summer. The results for the central station, Arnfield, are as follows Total Fall of Rain during the Spring and Summer Months. INS. Total Fall of Rain during the Autumn and Winter Mouths. INS. Difference. 1855 .... 17-36 .... 13-27 1856..., .... .... 21-OS .... 21-53 0-45 1857.. .... 22-37 .... ..... 14-22 1858 .... 19-66 .... ..... 16-48 -f- 3*18 1859 .... 20-46 .... ..... 19-74 .... 0-72 1860 .... 24-02 .... ..... 15-56 ..... .... -j- 8-46 1861 .... 17-71 .... 14-72 .... + 2-99 1862 .... 21-31 .... 17-68 ..... -J- 3 63 1863 .... 15-37 .... 22-82 .... — 7-45 1864 .... 14-54 .... ..... 16-80 — 2-26 1865 .... 13-48 .... ..... 15-89 . . — 2-41 1866 .... 20-71 ... 26-79 . — 6-08 1867 18-71 .... 20-75 .... — 2-04 1868 .... 12-61 .... 22-86 .... —10-25 It will at once be seen that during the first eight years the differences, with one unimportant exception, have all 160 the sign plus; while during the remaining six years they have all the sign minus. The average value of the differ- ences in the first eight years was + 3 ‘8 4 ; and the last six years — 5’ 08 inches. The returns from the other stations of the Manchester Corporation Water Works exhibit similar results. It is evident, therefore, that at the end of 1862, a marked change took place in the character of the climate of this locality ; the spring and summer seasons becoming much drier, and the autumn and winter months wetter than they had been during the previous eight years. I may add that this altered character of the seasons was continued through the last year, 1869, the total rainfall at Arnfield during the spring and summer months having been only 12-48 inches against 27'57 inches in the autumn and winter months — thus showing a difference of — 15 09 inches. In considering the differences in the temperature, humi- dity, and pressure of the atmosphere, and in the direction and force of the wind in the two periods, as indicated by this marked difference in the distribution of rainfall, it seemed to me highly probable that corresponding differences would exist in the state of the public health, and that the mean rate of mortality during one period would be sensibly different from that during the other. I therefore extracted from the annual reports of the Registrar General the rates of mortality in Lancashire, Cheshire, and the West Riding of Yorkshire during the years included in the two periods, omitting the last year of the series,- 1868, as the report for that year has not yet been published. These rates are as follows r — - Annual Rate of Mortality per cent, in Lancashire. Cheshire. West Riding. 1855...... 2-680 ..... 2-197 ... 2-223 1856 2-464 2-048 ... 2-212 1857 2-628 2-269 ... 2-368 1858...... 2-719 .... 2-267 ... 2-491 1859 2-454 2-169 ... 2-396 1860 2-371 2-173 ... 2-360 1861 . 2-592 .... 2-164 ... 2-321 1862 2-560 2-246 ... 2-364 1863 2-629 .... 2-396 ... 2-573 1864 2-718 2-300 ... 2-656 1865 . .. 2-832 ..... 2-328 ... 2-667 1866 . .. 3-016 2-538 ... : 2-684 1867 2-688 ..... 2-252 ... 2-443 161 Taking the means for the eight years 1855-62, and the live years 1863-67, we have Average Annual Rate of Mortality per cent, in Lancashire. Cheshire. West Riding. 1855-62 2-558 2-191 2*342 1863-67 2-775 2-363 2-605 Differences... 0'2l7 0-172 0’263 These numbers show that the average rate of mortality in Lancashire, Cheshire, and the West Riding was decidedly greater during the live years of dry springs and summers with wet autumns and winters, than during the eight years when the seasons were of an opposite character. The differ- ences are equivalent to an increase of 8 '4 per cent in the number of deaths in Lancashire, 7*8 per cent in Cheshire, and 11*2 in the West Riding; the mean amount of increase being 9T per cent, which, in Lancashire alone, represents an increase of more than seven thousand in the total number of deaths in one year. Observations of rainfall were commenced at the Gorton station of the Manchester Water Works in 1847, and Mr. Wilson having kindly furnished me with copies of the monthly amounts for the eight years 1847-54, I have grouped them in six-monthly periods as I had done the returns for 1855-68, and have obtained the following results : — Total Fall of Total Fall of Rain during Rain during the Spring the Autumn Difference. and Summer and Winter Months. Months. INS. INS. 1847...... ...... 17-22 .... 24-72 .... — 7-50 1848...... 19-25 .... 21-71 .... — 2-46 1849 ...... 13-59 .... ..... 19-82 — 6‘23 1850 14-59 .... ..... 15-18 ... — 0-59 1851...... 17-14 .... 13-20 ..... .... -f 3-94 1852 13-38 .... 23-96 . . — 10-58 1853 15-72 .... 14-10 ..... .... -f 1-62 1854 13-94 .... 20-03 .... — 6-09 In six years out of the eight the fall of rain during spring and summer was less than during autumn and winter, while in two only was it in excess. The mean difference 162 for the entire period was — 3 '48. It is evident therefore that the general character of the climate during this period was similar to that of the period 1863-68, and therefore I inferred that the mean rate of mortality would be found to be correspondingly high. The following figures for Lanca- shire will show that this inference was correct : — - Annual Rate of Mortality per cent in Lancashire. 1847 3-582 1848 2-765 1849 3-037 1850.. .... 2-464 1851.. . 2-647 1852 2-889 1853. 2-818 1854.. . 2-766 Mean Rate = 2-871 The mean rate 2-871 is slightly above that of the five years 1863-67 which was 2-77 5, and is 0-313 above that of the favourable years 1855-62. This difference of 0*313 is equivalent to an excess of 12*2 per cent per annum in the number of deaths. It thus appears that during a period of eight years, 1847-54, in which the spring and summer rain- fall was considerably below that of autumn and winter, the average rate of mortality in Lancashire was 2-871; and that in the next following eight years, 1855-62, in which the rainfall of spring and summer was considerably above that of autumn and winter, the rate of mortality fell to 2‘558 ; but that during the five following years 1863-67 when the spring and summer rainfall again fell decidedly below that of autumn and winter, the mean rate of mortality rose to 2*775 in spite of all the sanitary improvements that had been made in almost every town and district in the county. Looking to the enormous sums of money that have been expended of late years by boards of health, and town coun- cils, in making sanitary improvements, these results show clearly that the effects of meteorological changes upon the public health far exceed those arising from defective drain- age, ill-contrived privies and water closets, crowded dwell- 163 ings, and an insufficient supply of good water ; and that no material and permanent reduction in the rate of mortality can reasonably be hoped for until a close and careful study of the influence of changes in the state of the atmosphere upon the production and development of disease, has led to the discovery of the best means of guarding against and coun- teracting the effects of unfavourable changes of the weather • O O j and the people have been induced to avail themselves of such means to ward off or mitigate attacks of disease. In the reports of the Registrar General the causes of death are divided into five classes. I. Zymotic. II. Constitutional. III. Local. IY. Developmental. Y. Violent Deaths. The following table shows the number of deaths of males in Lancashire, in each class, during the years 1855-67 : — YEAR. I. II. CLASS III. IV. ! V. Total Deaths from ascertained Causes. 1855 6,909 5,548 12,194 3,968 1,589 30,208 1856 6,814 5,444 11,049 3,598 1,495 28,400 1857 7,628 5,476 11,901 3,859 1,648 30,512 1858 9,559 5,296 11,603 3,899 1,513 31,870 1859 6,964 4,862 11,976 3,769 1,574 29,145 1860 5,500 5,049 12,876 3,988 1,609 29,013 1861 7,166 5,394 13,553 4,477 1,600 32,190 1862 7,958 5,304 13,460 4,157 1,487 32,366 1863 9,606 5,319 13,045 4,071 1,642 33,683 1864 9,738 5,506 14,119 4,284 1,792 35,439 1865 11,068 5,958 13,849 4,700 1,926 37,501 1886 11,899 6,207 15,720 4,868 1,987 40,681 1867 9,039 6,162 15,050 4,968 1,809 37,028 Tlie mean annual numbers for the eight years 1855-62, and the five years 1863-67 are : — 1855-62 7,312 5,297 12,325 3,964 1,564 30,463 1863-67 10,270 5,830 14,356 4,578 1,831 36,866 The ratios of the numbers in each deaths are as follows class to the total number of 1855-62 •240 T73 •404 T30 •051 1863-67 •278 T58 •389 •124 •049 " 164 A glance at these numbers shows that the greater mor- tality in unfavourable years arises from an undue increase in the number of deaths from zymotic diseases, or those which are commonly regarded as preventible. An impression prevails very generally that when the rate of mortality is above the average the excess is due to a dis- proportional increase of deaths among infants and young children ; but if the increased mortality is due to meteoro- logical causes we should expect that the increase would be relatively less among the very young and the very old, who are least exposed to the vicissitudes of the weather, than . among the more actively employed and exposed classes of the community. To test this point, however, I have col- lected in the two following tables the number of deaths at different ages which occurred in Lancashire during the years 1855-67. The first table shows the number of deaths of males and the second that of females : — Deaths at different Ages.— Males.— Lancashire. Year. Total Deaths. Under 5 Years. i 5 to 15. i 15 to 25. i 25 to 35. i 35 to 45. 1 45 to 55. 55 to 65. 65 to 75. i 75 to 85. 85 to 95. TO .^3 a £ lO g* Oi 2 1855.. . 1856.. . 1857.. . 1858.. . 1859.. . 1860.. . 1861... 1862... 1863.. . 1864.. . 1865.. . 1866.. . 1867... 30,525 28.693 30,770 32,447 29,686 29,639 32,789 32,933 34,295 36,099 38,275 41,530 37,786 15,049 14,496 15,684 16,437 14,522 13,773 16,345 16,364 17,161 16,614 18,032 19,216 18,067 2,072 1,935 2,015 2,628 1,799 1,544 1,761 2,159 2,497 2,540 2,451 2,809 2,390 1,892 1,857 1,895 1,949 1,724 1,753 1,923 1,940 1.852 2 083 2,189 2,553 2,091 1,836 1,727 1,815 1,833 1,755 1,875 1,929 1,895 1,931 2,241 2,506 2,785 2,363 1,999 1,887 1,942 2,039 2,005 2,207 2,239 2,168 2,355 2,782 2,782 3,114 2,642 2,089 1,971 2,091 2,169 2,241 2,334 2,342 2,371 2,415 2.839 3,072 3,336 2,808 2,103 1,868 2,035 2,115 2,285 2,401 2,441 2,407 2,479 3,002 3,114 3,326 3,012 2,012 1.690 1,827 1 ,871 1,959 2,167 2,174 2,106 2,132 2,371 2,467 2,651 2,697 1,212 1,064 1,223 1,171 1,177 1,357 1,387 1,292 1,219 1,359 1,383 1,435 1,449 247 189 233 222 210 218 239 221 241 258 271 289 258 14 9 10 13 9 10 9 10 13 10 8 16 9 165 Deaths at different Ages.— Females.— Lancashire. Year. Total Deaths. Under 5 Years. 5 to 15. i 15 to 25. I 25 to 35. 35 to 45. 45 to 55. 55 to 65. 65 to 75. id 00 O -4-3 85 to 95. m 73 2 d pt lO a d 1855.. . 1856.. . 1857.. . 1858.. . 1859.. . 1860.. . 1861... 1862... 1863.. . 1864.. . 1865.. . 1866.. . 1867... 29,363 27,356 30,041 31,560 29,084 28,093 31,375 31,482 32,907 34,485 36;418 39.254 35,157 13,222 12,638 13,818 14,744 12,750 11,704 14,461 14,139 15,247 14,693 15,879 17,148 15,529 1,925 1,764 1,830 2,528 1,787 1,542 1,705 1,889 2,282 2,435 2,288 2,503 2,177 2,048 2,017 2,109 2,102 2,024 1,898 2,170 2,019 2,033 2.186 2,409 2,469 2,169 2,206 2,047 2,225 2,116 2,179 2,224 2,279 2,246 2,306 2,580 2,745 3,160 2,544 2,058 1,915 2,100 2,186 2,229 2,221 2,273 2,295 2,341 2,568 2,816 3,023 2,644 1,916 1,781 1,941 1,953 2,054 2,134 2,119 2,286 2,197 2,598 2,783 2,967 2,499 2,086 1,803 2,093 2,026 2,151 2,297 2,273 2,496 2,405 2,765 2,879 3,065 2,846 2,083 1,880 2,052 2,099 2,138 2., 237 2,291 2,330 2,258 2,667 2,616 2,819 2,641 1,453 1,222 1.490 1,382 1,432 1,481 1,511 1,465 1.490 1,619 1,605 1,703 1,702 346 268 346 342 323 337 259 300 323 348 379 378 383 20 21 27 22 17 18 34 17 25 26 19 19 23 The mean annual values for the two periods, 1855-62, and 1868-67, and their ratios to the mean annual number of deaths at all ages, are as follows : — MALES. Yeai i i g g d . w § S d ® « flrSA CS 02 u H 03 C3 73 ® dfx ^ to IO rH o ■43> in id O ■+» in rH in CO O in CM in xH O IO CO id in o o in co o in in in o -4-3 in CO in GO O -4-> in u- id O o -4-3 m 00 m . 73 73 fH d g IO os d 1855 to 1862 30,935 15,333 1,989 1,867 1,833 2,061 2,201 2,207 1,976 1,235 222 10-5 1863 to 1867 37,597 17,818 2,538 2,153 2,365 2,735 2,894 2,986 2,463 1,369 263 11-2 Eatios 1855-62 •495 •064 •060 •059 •066 •071 •071 •063 •039 •007 •0003 Eatios 1863-67 •473 •067 •057 •062 •072 •077 •079 •065 •036 •006 •0003 FEMALES. 1855 to 1862 29,794 13,434 1,871 2,056 2,190 2,159 2023 2,153 2,140 1,429 315 22-0 1863 to 1867 35,644 15,699 2,336 2,253 2,667 2,678 2,609 2,792 2,600 1,624 362 22-4 Eatios 1855-62 •451 •062 •069 073 •072 •067 •072 •072 •048 •010 •0007 Eatios 1863-67 •440 •065 •063 •074 •075 •073 •078 •073 •045 •010 •0006 166 From these numbers it is evident that in unhealthy years the increase of mortality is relatively greater between the ages of 25 and 76 than at any other age, and that very young and very old lives are relatively much less affected than in years when the general rate of mortality is below the average ; thus confirming the view I have taken that the excess of deaths in unfavourable years is principally due to meteorological causes. It has long been admitted that the state of the public health is affected by changes in the state of the weather ; and for many years the Registrar General has regularly included in his reports statements of the weekly, quarterly, and annual mean and extreme values of the various meteorological elements as observed at Greenwich; but these statements as usually given are of little value to sani- tary science. To be of use, the results of meteorological observations ought to be regularly grouped and discussed with reference to the various questions which arise in connec- tion with the origin and development of diseases ; but this obvious and very important course of proceeding appears to be entirely neglected by boards of health, health committees, and officers of health, and as a natural consequence, their misdirected efforts, made without a due regard to the true principles of sanitary science, have hitherto failed entirely to effect any improvement in the state of the public health, or any reduction in the general rate of mortality, as is clearly shown in the mortality returns. Thus during the 15 years, 1838-52, the average annual rate of mortality for the whole of England was 22*35 to 1,000 persons living ; and during the succeeding 15 years, 1853-67, it was 22*47. It is there- fore evident that notwithstanding the so-called sanitary improvements, made, at great cost, in almost every town and district irs the kingdom during the latter period, the public health remained in the same unsatisfactory state in which it had been during the previous 1 5 years ; and the death rate still showed a tendency to increase. From a table at page xlii of the 30 th Annual Report of the Registrar General, it appears that during the six years? 167 1857-1862; the average annual rate of mortality in 142 dis- tricts and 56 sub-districts, comprising the chief towns in England, was 23‘70 per 1000 living, while in the following five years, 1863-1867, it was 2 5 -3 5 ; and in the remaining districts and sub-districts of England and Wales, comprising small towns and country parishes, it was 19 '74 in the former period, and 20‘41 in the latter. Now, as the character of the weather is rarely, if ever, the same over the whole of England and Wales as that which may happen to prevail in the Manchester Water Works district, but will often be widely different in some localities, it is evident that the whole of the differences between these numbers cannot fairly be attributed to meteorological causes alone, and that therefore during this period of 11 years the general rate of mortality was slowly increasing both in town and country districts ; but in a much higher ratio in the former than in the latter; and yet it is in the large towns that what are supposed to be sanitary improvements have been carried out to the greatest extent, and where, therefore, had the schemes adopted been based on sound principles, their effect in checking the increase in the rate of mortality would have been most apparent. It will, no doubt, excite surprise in the public mind to find that after so many years’ trial, and the expenditure of so much public money, the schemes carried out by our sanitary authorities have produced absolutely no improvement what- ever in the general sanitary condition of the people, nor even prevented an increase taking place in the average rate of mortality; but, as I have indicated above, our sanitary authorities seem never to have made any serious and systematic attempt to discover the true causes of the fluc- tuations which take place in the rate of mortality, and trace out the modes of operation by which their effects are produced. Almost all that has been done in this direction has been accomplished by private individuals, and I may refer, as a noteworthy instance, to a valuable paper in vol. I, series HI, of the Society’s Memoirs, by Dr. A. Ransome, and Mr. G. Y. Yernon, F.R.A.S., “On the Influence of Atmospheric Changes upon Disease.” Sanitary officials, however, seem, for the most part, to act as if they were 168 strangely ignorant of the value and importance of applying modern methods of scientific research to questions relating to health and disease ; and were content to aim at no higher object than that of discharging the duties which properly belong to nuisance inspectors and scavengers. Until these gentlemen form a much higher estimate than they have hitherto done, of the dignity and importance of their pro- fession, and of the difficulties they have to overcome, we cannot reasonably hope to see any real and permanent im- provement in the general state of the public health.* The general results of the above investigation may be briefly recapitulated as follows : — 1. — That the influence of meteorological causes in pro- ducing fluctuations in the rate of mortality is much greater than that of any other recognised influence. 2. — That the class of diseases which is most affected by meteorological changes is class I., Zymotic diseases. 3. — That the relative increase in the number of fatal cases of disease at different ages, in unfavourable seasons, is greatest between the ages of 25 and 75 years, or amongst those classes of the community who are most exposed to vicissitudes of weather. 4. — That the sanitary measures which have been carried out during the last 15 to 20 years by boards of health, health committees, and officers of health, have produced no perceptible improvement in the state of the public health, nor checked the growing increase in the rate of mortality, notwithstanding the enormous outlay they have involved ; and that, therefore, a thorough reform of our existing sanitary system is urgently required. * In justice to the corporation of Salford I must state that at the suggestion of the Mayor, Thomas Davies, Esq., a meteorological station was established within the borough at the front of the Town Hall at the beginning of the year 1868 ; and that observations have since been regularly made under the super- intendence of Thomas Mackereth, Esq., F.R.A.S., for systematic comparison with the weekly returns relating to the sanitary condition of the borough. Mr. Mackereth informs me that these comparisons have already yielded deci- sive evidence of a close connection between meteorological changes and the development of certain diseases which are unfortunately too prevalent in Salford — thus confirming the results arrived at by Dr. Kansome and Mr. Vernon, and proving the soundness of the view taken by the Mayor when he urged the desirability of establishing a meteorological station in or near the centre of the borough. I believe this is the only instance of the establishment, by a public body, of a meteorological station in the centre of a large town. 169 Annual Meeting, April 19th, 1870, J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. Mr. Charles Lowe was elected an Ordinary Member of the Society. The following Report of the Council was read by one of the Secretaries : — • The Council have again the satisfaction to report that the Society’s finances continue in a healthy condition. From the copies of the Treasurer’s account already in the hands of the members, it will be seen that the income of the past year has exceeded the expenditure, and that the general balance on the 31st of March last was £268 Is. 2d. against £252 16s. 9d. on the 31st of March, 1869. The number of ordinary members on the roll of the So- ciety on the 1st of April, 1869, was 166, and 5 new members have since been elected. The losses during the year have been — deaths, 3 ; resignations, 5 ; and defaulters, 2. The number on the roll on the 1st of April instant was, therefore, 161. The deceased members are Dr. James Prince Lee, F.R.S., Lord Bishop of Manchester; Mr. Eddowes Bowman, M.A.; and Mr. George Parr, jun. James Prince Lee, F.R.S., Bishop of Manchester, was elected a member of the Society in the year 1849. Although, from his failing health, he has been unable for the last few years to take any active part in the institutions for its promotion, he had from the time of his residence here shown a deep interest in all that concerns the advancement of science amongst us. He was a ripe scholar, and few men were better acquainted with Greek literature, and the early history of the Church. He was Proceedings — Lit. & Phil. Society. — Vol.IX. — No. 15. — Session 1869-70. 170 one of the founders of the Manchester Photographic Society, and filled the office of president from its commencement up to the time of its division, and manifested his interest in its publications by throwing open his valuable collection of works of art for the use of some of its members. He was also one of the early members of the Microscopic Section of the Literary and Philosophical Society, to which he pre- sented a set of valuable objectives for its instruments. He was likewise himself an assiduous worker with the microscope, his investigations being directed chiefly to the structure of insects and annelides. Within ten days of his death his interest in the various scientific societies of the city was evinced in a long conversation which he held on the possible union of these, and on the desirableness of forming some plan by which the naturalists among the working men, so numerous in Manchester, yet so little known to each other, might be brought together. Mr. Eddowes Bowman, who was born on 12th November, 1810, at Nantwich, after a thorough school education under Mr. T. Wright Hill of Birmingham, entered the profession of a Mechanical Engineer, and for five years held the office of submanager of the Yarteg Iron Works at Pontypool. Here he distinguished himself by the philanthropic interest which he took in raising the social condition of the work- men. The Yarteg works being given up in 1840, Mr. Bowman resolved to resume his pursuit of classical litera- ture, and entered the University of Glasgow, where he graduated as Master of Arts. He afterwards attended at Berlin for several years the lectures of the most distin- guished German Professors, and his studies were marked by great earnestness and thoroughness. Thus qualified, he was appointed, in 1846, to the Chair of Greek and Latin Classics and of Grecian and Roman History, in Manchester New College, on the resignation of Mr. F. W. Newman, to whom he was acknowledged to be a not unworthy successor, in a 171 post which had also been filled by our Corresponding mem- ber the Rev. John Kenrick. This chair he continued to hold until the removal of the College to London in 1853. Though his professional labours thus ceased, he did not abandon the occupation of teacher, which had always had great attractions for him, and he now devoted much time to giving private instruction not only in classics but in physical science, especially in astronomy, optics, acoustics, and mechanics. His instruction in these branches, though it did not pretend to be more than elementary, was charac- terised by accuracy and clearness. For illustrating his lessons he possessed a valuable cabinet of physical apparatus, as well as many home-made contrivances ; he also purchased a Cooke’s 7i inch refractor, which was fitted up in an observatory at the top of his own house. It should likewise be recorded how cheerfully Mr. Bowman responded, often at much sacrifice of time and labour, to invitations to lecture at mechanics’ and other institutions which could not pretend to offer any remuneration. He was elected a member of the Society January 23, 1855, and died July 10, 1869. The Library of the Society continues to increase rapidly, and it vail be necessary to provide additional accommoda- tion during the ensuing year; and also to devote a con- siderable sum to bookbinding. The following papers and. communications read at the ordinary and sectional meetings during the Session now closing will show that there is no falling off in the activity and usefulness of the Society : — October 5th, 1869. — “On Nontronite,” by T. E. Thorpe, Ph.D., communicated by Professor PI. E. Roscoe, F.R.S. “On Pholas Borings,” by E. W. Binney, F.R.S., F.G.S. October \lth, 1869. — “On Varieties of Lepidoptera,” by Mr. Joseph Sidebotham. October 19 th, 1869. — “On a new form of Calamitean Strobilus,” by Professor W. C. Williamson, F.R.S. 172 November 2nd , 1869. — “On a New Chromium Oxychloride,” by T. E. Thorpe, Ph.D., communicated by Professor H. E. Roscoe, F.R.S. November 1 6th, 1869. — “On the Permian Strata of East Cheshire,” by E. W. Binney, F.R.S., F.G.S. “ On the Combinations of Phosphate of Lime and Sulphurous Acid,” by Dr. B. W. Gerland, communicated by Professor H. E. Roscoe, F.R.S. November 36th, 1869. — “On the Microscopical Examination of Milk under certain conditions,” by J. B. Dancer, F.R.A.S. December 7 th, 1869. — “On the Mean Monthly Temperature at Old Trafford, Manchester, 1861 to 1868, and also the Mean for the twenty years 1849 to 1868,” by G. V. Vernon, F.R.A.S., F.M.S. December 14 th, 1869. — “On the Hades, Throws, Shifts, &c.; of the Metalliferous Veins of the North of England,” by Mr. John Currey, communicated by E. W. Binney, F.R.S., F.G.S. December 28th, 1869. — “On Pollen; considered as an Aid in the Differentiation of Species,” by Mr. Charles Bailey. January 3rd, 1870. — “Notes on the pupa and imago of Acherontia atropus ,” by Mr. Joseph Sidebotham. January 4 th, 1870. — “ On the Rainfall of 1869, at Old Trafford, Manchester,” by G. V. Vernon, F.R.A.S., F.M.S. January 2 5th, 1870. — “ On Organic Matter in the Air,” by Dr. R. Angus Smith, F.R.S. “ On the so-called Molecular Movements of Microscopic Par- ticles,” by Professor Wm. Stanley Jevons, M.A. “ On a General System of Numerically Definite Reasoning,” by Professor Wm. Stanley Jevons, M.A. February 8 th, 1870. — “On Convertant Functions,” by Sir James Cockle, F.R.S., communicated by the Rev. Professor R. Harley, F.R.S. “ On the Natural Ropes used in packing Cotton Bales in the Brazils,” by Mr. Charles Bailey. February 22nd, 1870. — “On Artificial Alizarine,” by Dr. F. Grace Calvert, F.R.S. “ On the Organic Matter of Human Breath in Health and Disease,” by Dr. Arthur Ransome, M.A. 173 February 28 th, 1870. — “On some Shell Deposits at Llandudno,” by Mr. Joseph Sidebotham. March 1st, 1870. — “Results of Rain Gauge and Anemometer Observations made at Eccles, near Manchester, during the year 1869,” by Thomas Mackereth, F.R.A.S., F.M.S. March 8th, 1870. — “ On the high Death-Rate of Manchester and Salford,” by E. W. Binney, F.R.S., F.G.S. “ On the Sources of the high Death-Rate of Manchester,” by Edward Lund, F.R.C.S. “On the Suspension of a Ball by a Jet of Water,” by Professor Osborne Reynolds, M.A. March 2 2nd, 1870. — “On the Size of Molecules,” by Sir W. Thomson, F.R.S. “ On the Determination of Phosphoric Acid,” by Mr. W. C. Williams, communicated by Professor H. E. Roscoe, F.R.S. “On the Composition of the Water of the Irish Sea,” by T. E. Thorpe, Ph.D., and Mr. E. H. Morton. “ On the Occultations of the Planet Saturn by the Moon, April 19, July 10, and September 30, visible in England during the present year,” by Mr. W. L. Dickinson. March 28th, 1870. — “On the Exploration of the Hysena-den at Wookey Hole,” by Wm. Boyd Dawkins, M.A., F.R.S. “ On the Germination and Early Growth of Plants,” by Dr. Arthur Ransome, M.A. April 5th, 1870. — “ Description of a New Anemometer,” by Mr. Peter Hart. “On the Settle Cave Exploration,” by Wm. Boyd Dawkins, M.A., F.R.S. “On the Eclipse of the Sun, December 21-22, 1870,” by Mr. W. L. Dickinson. “ On the Influence of Changes in the Character of the Seasons upon the Rate of Mortality,” by Joseph Baxendell, F.R.A.S. Some of these papers have already been printed in the current volume of the Society’s Memoirs, and others have been passed for printing, and will complete the volume. The system of electing sectional associates still works satisfactorily, and in recommending that it be continued 174 during the ensuing year the Council venture to express a hope that its advantages will become more generally known and appreciated among the class of students and lovers of science for whose convenience and benefit it was intended. The Librarian reports that the third volume of the So- ciety’s third series of Memoirs, as well as the fifth, sixth, and seventh volumes of the “ Proceedings,” have been forwarded during the past year to the Honorary and Corresponding Members of the Society, and to the various learned societies who send their publications in exchange. The list of these latter is yearly increasing, and the total number now in relation with the Society is 311, viz. — Societies in Great Britain 79 Societies abroad 2 32 311 The binding of the works in the Library has not been carried on to the same extent as last year, 78 volumes only having passed through the binder’s hands. The number of new works received during the year has been so great as to entirely exhaust the shelf-accommodation, and one of the first matters requiring the attention of the new Council will be to make adequate provision for the various publications coming to hand daily. The serials subscribed for by the Society continue to be purchased by the Librarian, and in addition several very valuable works have been added to the Library at the joint expense of the Society and of the Microscopical and Natural History Section. On the motion of Mr. J. Barrow, seconded by Mr. H. Wilde, the Annual Report was unanimously adopted. On the motion of Mr. J. S. Kipping, seconded by Mr. J. Francis, it was resolved unanimously — “ That the system of electing Sectional Associates be continued during the ensuing session.” 175 The following gentlemen were elected officers of the Society for the ensuing year : — EDWARD WILLIAM BINNEY, F.R.S., F.G.S. Witje-fmifojent#. JAMES PRESCOTT JOULE, D.C.L., LL.D., F.R.S., F.C.S., &c. EDWARD SCHUNCK, Ph.D., F.R.S., F.C.S. ROBERT ANGUS SMITH, Ph.D., F.R.S., F.C.S. Ret. WILLIAM GASKELL, M.A. HENRY ENFIELD ROSCOE, B.A., Ph.D., F.R.S., &c. JOSEPH BAXENDELL, F.R.A.S. %xmmx. THOMAS CARRICK. Iptomtu CHARLES BAILEY. tfrje tonal PETER SPENCE, F.C.S., M.S.A. GEORGE VENABLES VERNON, F.R.A.S., F.M.S, JOHN BENJAMIN DANCER, F.R.A.S. WILLIAM LEESON DICKINSON. HENRY WILDE. 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(N «« 00 d fl eg to Vi © H3 -»a O $H PQ c o £ © H« a s M’S © •« rfl § -♦3 i? 00 ■HH CO , * 00 OO OO 00 1 I 00 rH I 05 rH i-H Him 1 1-1 1 00 ^ C5m tHO Hjm | a s'g a o % o ,S & s s ooh5 % 05,-* tO'H oo }< H-3 © O -+3 © -G» ©^3 in u © rO is ^© 5 fl PhO cS © u 3 © © © © pH 6 fl fl O O fl M ■OH e. s 11 v! •d'd co o © co £ $, © P.S H &HPH © ►g to 8 tao &H fl ss| 'SflS H glia 2 Sm° •r3 ©hh ••^->242 fl *rH P® _j E^ S-^S © a 1 I'd go A0!!* o ?fl^1S.2 'd o .2 © -e g-H M H ^ J-g &2S CO ©£ fl o 0a2A4MG Eh « O ,i4 SmU? s§5 AmP* Sh& .'C3W §■8^ A “ 2 W 2 o os o Eh -fl M fl ft O O %-t HH ^ «c § ■dj'd 02 CO'S O B Eh o N- OO H *E ^3 o IO rH CO ««« q rd S © P © ^ § c,fl O eg ;.gpq '3^2 o g ft id as o © OO 177 Mr. Binney, F.R.S., on behalf of Mr. Mortimer L. Tait, exhibited some specimens of Coprolites from a quarry at Ashwell, near Baldock, Herts. “On Infant Mortality in Manchester/’ by Joseph Baxen- dell, F.B.A.S. It has been repeatedly and very confidently stated that the high death-rate of Manchester and other towns in the cotton manufacturing districts is due to the mortality among infants and young children being relatively much greater than in large towns in other parts of the country ; and writers in newspapers and serials have, at various times, taken up the statement and commented, in very severe terms, upon the negligent and unfeeling conduct of Lancashire, and especially Manchester, mothers in being tempted by the higher wages they can earn in the cotton mills to leave their children during working hours to the tender mercies of careless nurses, and thus deprive them of the natural sustenance and motherly care which they so much require. A few months ago this serious charge against Manchester mothers was repeated in a lecture delivered by a gentleman holding an official position, who moreover added that it was the principal reason why the efforts of health committees and sanitary officials in Man- chester and other cotton manufacturing towns had been attended with so little success, and had failed to make any reduction in the death-rate. As however no facts were adduced by the lecturer in support of the statement it occurred to me that it had probably originated in a hasty and imperfect examination of the mortality returns, and that it might be useful and instructive to ascertain the 178 exact amount of infant mortality, and the effect it had on the general death-rate of Manchester and several other large towns where little or no cotton manufacturing is carried on. From the form in which the mortality returns are given in the Registrar General’s Reports this could readily be done, and selecting the towns of Birmingham, Bradford, Dudley, Sheffield, Wolverhampton, Leeds, New- castle-upon-Tyne, Nottingham, Stoke-on-Trent, Stourbridge, and Leicester for comparison with Manchester ; and taking the returns for the seven years 1861-87, I was surprised to find that the portion of the total death-rate which was due to infant mortality was relatively less in Manchester than in any of the other towns. Thus out of every 1,000 deaths of males at all ages the number due to infants under 1 year of age was : — Dudley 347 Stourbridge ......... 298 Leicester 341 Sheffield 296 Bradford 322 Leeds 285 Stoke-on-Trent 309 Birmingham 277 Nottingham 307 Newcastle-upon-Tyne 274 Wolverhampton. . . . . . 304 Manchester 253 And including young numbers are : — children up to 5 years of age Dudley 531 Bradford 507 Wolverhampton ... 526 Sheffield 505 Stourbridge 518 Leeds 485 Leicester 517 Nottingham ......... 475 Stoke-on-Trent ...... 516 Newcastle-upon-Tyne 471 Birmingham 508 Manchester 465 I have also compared Manchester with the five large cotton manufacturing towns of Ashton, Bolton, Blackburn, Oldham and Preston. The results are - 179 Under Under 1 Year of Age. 5 Years of Age, Preston ...... ...... 312 .... 503 Ashton 297 485 Oldham ......... 287 499 Bolton KJ g • . . . c 276 493 Blackburn 272 487 Manchester . . . . , . 253 ..... 465 In all the lists the numbers for Manchester are much less than those for any of the other towns, and in some cases the differences are very striking. It is clear therefore that the stigma which has been cast upon the mothers belonging to the working classes of Manchester is most undeserved ; and that, in fact, infants and young children are better cared for, and attended to, in Manchester than in any other leading manufacturing town in England. It is also evident that excessive infant mortality is not the cause of the alarmingly high death-rate of Manchester, since a much, larger proportional number of deaths of infants and young children takes place in other towns where the general death-rate is decidedly lower. Some other cause must therefore be sought out to account for the failure of the attempts made by the sanitary authorities to reduce the death-rate of Manchester. Mr. Baxendell, referring to the paper he had read at the last meeting, said that as considerable surprise had been expressed at the facts he had given showing that the carry- ing out of the schemes of the sanitary authorities through- out England had produced no diminution in the general rate of mortality, he had since examined the mortality returns for Scotland for the ten years 1859-68, and found 180 that the average annual death-rate during the first five years 1859-63 was 21*5 per 1000 persons living, and during the last five years 1864-68 it had risen to 22’5. It appeared, therefore, that so far as ten years’ experience extended, our present sanitary system had failed quite as signally in Scotland as in England to produce any improvement in the state of the public health. \ 181 MICROSCOPICAL AND NATURAL HISTORY SECTION. March 28th, 1870. John Watson, Esq., President of the Section, in the Chair. A paper “ On the Exploration of the Hysena Den at Wookey Hole,” was read by Mr. W. B. Dawkins, M.A., F.R.S., F.G.S. The author gave an account of his exploration of the ossi- ferous cavern at Wookey Hole, a village on the southern flanks of the Mendips, about two miles to the north-west of the city of Wells, begun in 1859, and carried on from time to time till 1866. The ravine, in which the cave is situated, runs horizontally into the mountain side until it is closed abruptly to the north by an ivy-covered perpendicular cliff, at least a hundred and fifty feet high ; at the bottom of this is a cave, in which Dr. Buckland discovered pottery and human teeth, and from which rises the river Axe in con- siderable power and volume. In cutting a passage in the ravine side to convey the water to a large paper mill close by, the mouth of the hyaena den was intersected about 1851 or 1852. When the exploration began in 1859, about twelve feet of the entrance had been cut away, and large quantities of the earth, stones, and remains had been used in the formation of an embankment for the canal that now runs past its present entrance. The workmen state that at the time it was discovered the ravine side presented no con- cavity that would indicate its position, so completely was it filled with debris up to the very roof. Resting on the floor Proceedings— Lit. & Phil. Soc.— Vol. IX.— No. 16.— Session 1869-70. 182 there was a layer of bones and teeth about twelve inches thick, while in the overlying mass of stones and red earth they were somewhat rare. When the systematic exploration began, the contents of the cave were undisturbed except a very small area close to the entrance, where curiosity hunters had been looking for teeth and some of the workpeople had been setting traps for badgers. Mr. Boyd Dawkins gradually dug his way into the cave, and then proceeded to clear out all the deposits in the great chamber or antrum close to the entrance. It proved to be about thirty feet in width and eight feet in height, and about forty feet in length. It was filled with red earth conveyed in by water, stones that had fallen from the roof, and large quantities of bones and teeth of animals. These, for the most part, formed two or three bands gradu- ally coming together that evidently indicated the position of the old floors on which they were dropped. The frag- mentary and gnawed condition of the remains pointed to the fact that the animals to which they belonged had fallen a prey to the hy senas. The large quantities of coprolites also that occurred in the layers of bone, indicated that these animals dwelt in the cave. Underneath these layers there were flint flakes and well fashioned implements of flint and chert, which showed that man had been in the cave, to say the least, during the time that the hyaenas were living in the country. Numerous fragments of burnt bone showed that he had been kindling his fires close to the entrance. One fragment, which belonged to the woolly rhinoceros, was carbonised in such a way as to indicate that the bone had been burnt while it contained its gelatine. These traces of man were found in the undisturbed earth, and by no possibility could have been placed into the cave after it had been filled. As the workmen cut their way inwards the chamber gradually narrowed into a passage about eight feet wide, 183 which eventually bifurcated until at last it ended in branches which were too small to be explored. In these passages there were three masses of bones and of teeth compacted and matted together, the largest of which was about nine feet long, six feet wide, and about four inches thick. The following list will give an idea of the animals that were found in the cave, and the numbers appended to each representing the specimens taken to Oxford by Mr. Boyd Dawkins in 1862, after one season’s digging, show their relative abundance, Paleolithic Man The Cave or Spotted Hysena 467 The Cave-lion -. 15 The Cave-bear 27 The Brown Bear 11 The Grizzly Bear 11 The Wolf 10 The Fox 8 The Mammoth 40 The Woolly Rhinoceros 433 Rhinoceros hemiioeclms 2 The Horse 411 The Urns 36 The Bison...... 35 The Irish Elk 56 The Reindeer 50 The Red deer 4 The Rabbit The Norway Lemming The Water Rat The flint and chert implements were of precisely the same type as those found in the Reindeer caves of The Dordogne, and those of Kent’s Hole, and Brixham. This discovery proves that man was living in Somerset at the time when the above animals occupied the South of 184 England, during the post-glacial epoch. How long ago it is impossible to guess, because the geological past cannot be measured by the historical unit of years. A detailed account of the exploration of the first three years is to be found in Quart. Geolg. Journ., London, Yols. xviii. p. 115, and xix. p. 260. “ On the Germination and Early Growth of Plants,” by Arthur Ransgme, M.D., M.A. The following statement with reference to the conditions of growth was quoted from Prof. Draper’s works : — “ If growth be conducted in darkness, heat, air, and water can- not cause the young plant to add anything to its substance. It is feeding on the seed. Indeed, when the experiment is carefully made, it is found that there is an actual loss of substance, the resulting plant, if dried, weighing less than the dry seed from which it came Growth in darkness leads to one result, and growth in the sunshine to another.” — Human Physiology, 1856, p. 458. The truth of this observation was tested as follows Given weights of fresh mustard seed were taken, each portion was divided into two equal parts ; one part of each was crushed and moistened, to set free any volatile oil, and then carefully dried in a water-bath, or in Dr. Calvert’s silk conditioning apparatus which he kindly allowed to be used ; the other portions were sowed upon well- washed old flannel, placed upon inverted saucers, and watered with distilled or town’s water. The experiments were carried on through the months of June, July, and August of 1858. In four instances, the seeds were left to the full influence of diffused daylight. In two others the saucers were placed in a perfectly dark cupboard, and watered at night by artificial light ; and in one case the seeds were placed in a dark wine cellar. After growth the plants were carefully dried and weighed. 185 The following table gives the results of all the experi- ments : — TABLE I. — Gteowth of Mustard. No. Conditions of growth. Number of days of growth. l Loss or gam per cent., after drying. Remarks. 1 2 None In Light, town’s None . . — 12 The seed was crushed and moistened, before drying. water and air only 8 — 22-5 Plants £in. long, green leaves, just emerging. 3 4 Ditto In Light, distilled 10 — 29 ‘8 Plants l£in. long, strong and healthy. water used ...... 14 — 26-7 Small amount of growth, about Hin. 5 6 Ditto In Darkness, town’s 17 — 37'9 Stalk and leaves about 2in. long, strong and healthy water and air only 10 — 27‘8 Etiolated but strong plants, about 2in. in length. 7 Ditto 13 — 40 Plants very weak, about 2£in. to 3in. in length. 8 Ditto 17 — Length of plant about 4in., dead and decomposed. These results show that during the germination and early growth of mustard, Professor Draper’s statement does not hold good : — 1. In every case, whether in light or darkness, the plants (root, seed, stem and leaves) when dried had lost a certain amount of solid matter. 2. Up to the period of cultivation observed, the amount of loss was in close relation to the degree of growth. 3. Up to a certain stage of growth, there is but little difference in the extent of loss in the light or in the dark. These experiments were afterwards repeated with the bulbs of hyacinth, crocus, and snowdrops ; and at different periods kidney-beans and peas were grown in garden mould, carefully washed and dried after growth, and tested in the same way. It was found that peas and beans began to gain in weight when the plants were from Sin. to 12in. in height. The results with the bulbs are given in tables II.. III., and IV. 186 TABLE II. — Growth of Hyacinths. No. Weight of Bulb. Bate. Weight of dried bulb plant, &c. Loss per- cent. Date. No, of Days’ Growth. Conditions of Growth. Remarks. 1 grains 888 1865. Oct. 27. grains 330 62-7 1865. Oct. 29. None None Just germinating. 2 960 380 60-4 93 33 3 609 1865. Oct, 27. 160 73-8 Mar. 5, 1866. 129 In dark cellar — water and air only. Leaves 6in. long — flower stalk lOin. long — buds about to burst — whole plant light yellow. 4 5 835 671 1865. Oct. 27. 269 177 67-8 621 Jan. 31, 1866. Feb. 26, 96 122 In light — water and air only. Ditto Plants 5in. long — strong and healthy —flower buds ap- pearing. Leaves lOin. long — flowers withered and dried. Two large spikes of flowers, lOin. to 12in. long — strong healthy flowers & leaves. Green leaves 3in. long. Green leaves 5in. long — buds well formed. Healthy plant — had completed flower- ing. 6 794 187 76-5 1866. ' Mar. 12, 136 Ditto 7 960 not 410 57-4 1866. ' not noted Ditto 8 890 noted 320 64-2 Ditto 9 1020 240 76-5 Ditto .......... TABLE III.— Growth of Crocus. No. Weight of the Fresh Bulb. Date. | Weight of Dried Bulb, | Plant, &c. Loss per Cent. Date. No. of Days’ growth. Conditions of growth. Remarks, grains grains 1 150 Oct. 20, 88 42-4 Oct. 20, None. None, Just sprouting. 1865. 1865. 2 116 33 70 39-7 33 33 33 33 93 In Darkness. 3 148 Oct. 20, 82 44-6 Jan. 22, 94 Earth and cocoa 4 inches long — plant 1865. 1866. fibre. yellow — otherwise healthy. In Light. 4 116 Oct. 20, 57-5 50-5 Dec. 20, 61 Earth and cocoa 4in. long — slightly 1865. 1865. fibre. singed in drying. 5 HI 46 58‘6 Jan. 17, 89 Ditto. 4in. long — flowers 1866. just formed in sheath. 6 126 62-5 50-4 Jan. 26, 98 Ditto. Diseased. 1866. 7 115 53 54-7 Mar. 3, 134 In diffused light, 7in. long. 1866. in cellar, earth and cocoa fibre. 187 TABLE IV. — Growth of Snowdrops. No. Weight cf Fresh Bulb. Date. Weight of Dried Bulb, Plant, &c. Loss per Cent. Date. No. of Days’ growth. Conditions of growth. Remarks. grains 1885. grains 1 48 Oct. 24. 22-5 53*2 None. None. No growth. 2 48 33 21 56-3 33 33 33 3 3 3 3 3 37 Oct. 20. 17 60 Dec. 29 70 In Light. In sand, in cel- lar. About 2|in. long — burnt in drying. 4 42-5 33 14-5 65-5 Jan. 5, 1866. 77 Ditto. About Sin. long— ■ slightly burnt in drying. 5 42 3) 17 59.6 Jan. 8, 1866. 80 Ditto. Ditto. It was found that in every case the result was the same — in darkness and in light, whether water, sand, earth-mould, or cocoa-fibre were used — the loss of substance up to the period of cultivation observed was constant, and to some extent increased with the growth of the plant. In the darkness, in some instances, the loss of weight was less than in the light, in others there was little or no difference. In the case of bulbs it seems probable that it is only when the plant has ceased flowering, and when the secondary bulbs are being formed, that there is any material gain in weight. Mons. Boussingault’s experiments ( Gomptes Rendus , vi, p. 102) on the absorption of nitrogen by plants were quoted, and it was shown that they were in general accordance with the results obtained by the author, and they indicate moreover in which of the elements the chief loss takes place. Tables were shown giving the results of these analyses. In the early stages of growth there was little variation in the quantity of nitrogen contained in the plant, but that little was on the side of increase ; the hydrogen also was only slightly altered by diminution, but the carbon and the oxygen both disappear for some time in proportion to the extent of growth. In the later stages of cultivation of both 188 wheat and clover, the carbon, hydrogen, and oxygen again increase ; in the clover the amount of nitrogen also increases, but in the absence of all manure the nitrogen of the wheat remains stationary. The bearing of these facts upon the subjects of nutrition and development was pointed out, and the analogy between the physiology of plants and animals in these functions was indicated. As in the animal ovum, so in the seed, the genesis of life receives its first impulse from the constituents of the seed, and most plants continue for some time to draw from this source a portion at least of their powers of growth. The experiments might perhaps lead to more definite views regarding the distinctions between growth, development, and nutrition. The source from which the power of growth appears to spring was pointed out by an appeal to M. Boussingault’s experiments. The elements which are used up during early growth are the carbon and oxygen and to a certain extent the hydrogen of the seed. During germination the starchy portions of the seed, by a species of fermentation, under the influence of warmth and moisture, and also probably by the molecular action of the nitrogenous germ, become changed into sugar and other soluble substances, and these are slowfy disinte- grated and burnt by a kind of respiration, and heat or other energy is developed. The most important agents in assist- ing the processes of growth are hydrocarbonaceous particles in their course of transformation, and there is little doubt that the heat-energy of these compounds bears some import- ant relation to active life. This fact was placed in apposition with the recent inves- tigations of Messrs. Fisk and Wislieenus, Frankland and Haughton, upon the sources of mechanical power in animals. It seems probable that the oxydation of carbonaceous com- pounds in animals has something to do, not merely with the 189 phenomena of muscular contraction, but also with many- other vital processes. In like manner plants perhaps owe not a little to the same sources. It was shown by the observations detailed in the tables that the plants lost weight during growth almost equally in the light and in the dark. It was thought possible there- fore that the processes of development and growth might receive their stimulus not only from the direct heat and light of the sun, but also from the energy lying hid in the carbonaceous compounds already stored up within the seed or bulb. It was remarked that it would be interesting to compare the conditions of early growth of plants with the constituents of their seeds. Light is probably essential to the proper nutrition of a plant, but it may not be necessary to some kinds of develop- ment and growth ; and in this sense the words quoted from Professor Draper at the commencement would be literally true that — “ Growth in darkness leads to one result and growth in sunshine to another.” Annual Meeting, May 9th, 1870, Joseph Baxendell, F.R.A.S., in the Chair. / Mr. Adolph Meyee was duly elected an Associate of the Section. The following report of the Council and Treasurer’s Account for the past year were read and passed : — Your Council have to report that the subjects brought under the notice of the Section during the past Session have been of as interesting and valuable a character as in any previous year, and that the attendance at the meetings has on the whole been satisfactory. 190 The following papers have been read : — 1869. Oct. 11. — “On a new form of Calamitean Strobilus.” — Prof. W. C. Williamson, F.R.S. “ On Varieties in Lepidoptera.” — Mr. J. Sidebotham. “ On the occurrence of Statice spathulata on Hilbree Island.” — Dr. Henry Simpson. Nov. 8. — “On the Resinous Vapour exuding from Pencil Cedar.” Mr. J. Sidebotham. “Notes on the Natural order Podostemaceoe.” — Mr. Thomas Coward. Dec. 6.—“ On Pollen considered as an aid in the Differentiation of Species.” — Mr. Charles Bailey. “ On some Australian species of Drosera — Mr. H. A. Hurst. “ On an Abnormal Form of Primula sinensis.”— Mr. A. G. Latham. “ On some Polarising Objects obtained from the new Hydro-carbon Compounds.” — Mr. J. B. Dancer, F.R.A.S. “ On the Microscopic Examination of Milk.” — Mr. J. B. Dancer, F.R.A.S. 1870. Jan. 3. — “On Urinary Calculi composed of Cystine.” — Dr. William Roberts. “ Observations on the Pupa and Imago of Acherontia Atropos .” — Mr. J. Sidebotham. “ On Eozoon Canadense.” — Mr. W. B. Dawkins, F.R.S. 31. — “On Natural Ropes used in Packing Cotton Bales in the Brazils.” — Mr. Charles Bailey. “ Remarks on some Pholas-bored Rocks on the Great Ormes Head.” — Mr. J. Sidebotham. Feb. 28. — “ On some Shell Deposits in the neighbourhood of Llandudno.” — Mr. J. Sidebotham. Mar. 28.' — “ On the Exploration of the Hyaena Den at Wookey Hole.” — Mr. W. B. Dawkins, F.R.S. “ On the Germination and Early Growth of Plants.”— Dr. Arthur Ransome, 191 April 25. — u On the repens group of the genus Trifolium” — Mr. H. A. Hurst. Notwithstanding the hope expressed by your Council in their last report, that purely microscopical subjects would receive greater attention, it will be seen from the list of papers that but few can be thus classed ; this your Council regrets, as it believes that greater interest would attach to the meetings, if members engaged in microscopical research would bring the result of their investigations before the notice of the Section. The Section has to lament the death of one of its mem- bers, the late Lord Bishop of Manchester, to whom it is indebted for several contributions to the microscopical cabinet, and who showed an invariable wish to promote its best interests. The Section is now composed of 37 ordinary and one corresponding members, and nine associates. During the Session several valuable additions have been made to the cabinet and library ; amongst others, the thanks of the Section are more especially due to Mr. W. J. Rideout, who has presented one of J. D. Moller’s Diatomaceen Typen Platte, and to Mr. EL A. Hurst, for his gift of a rare botanical work, by Rev. J. Barrelier. Acting on the arrangement entered into with the Parent Society, to which reference was made in last year’s report, your Council have purchased several desirable works, the most noticeable of these being 58 vols. of Annales des Sciences Botaniques, and the following Colonial and Tropical Floras : Bentham’s Flora Hongkongensis ; Giesbach’s Flora of West India Islands; Hooker’s New Zealand Flora; Bentham’s Flora Australiensis ; Oliver’s Flora of Tropical Africa. As will be seen from the accompanying statement the Treasurer’s report is satisfactory, there being a balance in hand of £20 4s. 9d. 192 The election of Officers for the Session 1870-71 was then proceeded with, and the following gentlemen were elected : ^rcstlreM. JOSEPH BAXENDELL, F.R.A.S. Ftcc=lprcstU£nts. JOHN B. DANCER, F.R.A.S. JOHN WATSON. R. D. DARBISHIRE, B.A., F.GKS. ^rfasurcr. HENRY ALEXANDER HURST. 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