fe*^ ^^^ ^ '-k ^fc?'^' o^ii^Lt HARVARD UNIVERSITY. LIBRARY OF THE MUSEUM OF COMPARATIVE ZOOLOGY. L- ^ A^^V ^l^^i^v\^^^' PROCEEDINGS OF THE AMERICAN PHILOSOPHICAL SOCIETY HELD AT PHILADELPHIA FOR PROMOTING USEFUL KNOWLEDGE. VOL. XXXVI. JANUARY TO DECEMBER, 1897. PHILADELPHIA : THE AMERICAN PHILOSOPHICAL SOCIETY -^1897 ^ O"^ iv^ JUN 2 1897 PKOCEEDINGS AMERICAN PHILOSOPHICAL SOCIETY, HELD AT PHILADELPHIA, FOR PROMOTING USEFUL KNOWLEDGE. Vol. XXXVI. January, 1897. No. 154. Stated Meeting^ January 1, 1897. The President, Mr. Fraley, in tlie Cliair. Present, 16 members. Correspondence Avas submitted and letters of acknowledg- ment presented. Letters of acceptance of membership were received from Prof. W. F. Magie, Princeton, N. J.; Mr. G. Albert Lewis, Philadelphia ; Prof. B. W. Frazier, South Bethlehem, Pa. The death was announced of Gen. John Meredith Eead, Paris, France ; born Feb. 21, 1837 ; died, Dec. 27, 1896, ^t. 59. The Judges and Tellers of the annual election reported the following officers elected for the ensuing year. President. Frederick Fraley. Vice- Presidents. E. Otis Kendall, J. P. Lesley, William Pepper. Secretaries. George H. Horn, Persifor Frazer, I. Minis Hays, Frederick Prime. Curators. J. ChestonMorris, Benjamin S. Lyman, Henry Pettit. Treasurer. J. Sergeant Price. PROC. AMER. PHILOS. SOC. XXXVI. 154. A. PRINTED APRIL 5, 1897. ^ MINUTES. f Jan. 15, Councilors. George E. Morehouse, William C. Cattcll, William P. Tat- ham, Patterson DiiBois. Mr. Ingham proposed an amendment to the LaAVS to be considered at the next meeting. And the Society was adjourned by the President. Stated Meeting^ January 15^ 1897. Vice-President, Dr. Pepper, in the Chair. Present, 36 members. The nsual correspondence was submitted with the letters of envoy and of acknowledgment. Accessions to the Library were reported. The following Eeport was read on the part of the Henry M. Phillips Prize Essay Fund Committee : The Henry M. Phillips Prize Essay Fund Committee respectfully re- port, that they have found discrepancies existing between the published minutes of the Society of December 7 and 21, 1888, establishing the "Rules and Regulations" in reference to the Henry M. Phillips Prize Essay Fund, and other copies of the same printed in authorized form by the Society, one of these discrepancies presenting a serious embarrass- ment and hindrance to the ett'ective administration of the Fund. They also find that an incorrect copy of said Rules and Regulations has been improperly included amongst the Laws of the Society in certain pam- phlets called "Laws and Regulations of the Society," printed in 1890 and 1894. They therefore recommend that the Society adopt the following reso- lutions ; 1. Resolved, That the Rules and Regulations adopted for the manage- ment of the Henry M. Phillips Prize Essay Fund as set forth in the cir- cular officially issued by the Committee May 1, 1893, and published in No. 148, Proceedings of the Society, Jul}^ 1895, pages 174 and 175, are hereby established and adopted, viz. : First. The Prize Endowment Fund shall be called the "Henry M. Phillips Prize Essay Fund." Second. The money constituting the Endowment Fund, viz., five thousand dollars, shall be invested by the Society in such securities as 1897.1 MINUTES. 3 may be recognized by the laws of Pennsylvania as proper for the invest- ment of trust funds, and the evidences of such investment shall be made in the name of the Society as Trustee of the Henry M. Phillips Prize Essay Fund. Third. The income arising from such investment shall be appropri- ated as follows : (a) To making public advertisement of the prize, and the sum or amount in United States gold coin, and the terms on which it shall be awarded. (6) To the payment of such prize or prizes as may from time to time be awarded by the Society for the best essay of real merit on the Science and Philosophy of Jurisprudence, and to the preparation of the certificate to be granted to the author of any successful essay. Fourth. Competitors for the prize shall affix to their essays some motto or name (not the proper name of the author, however), and when the essay is forwarded to the Society, it shall be accompanied by a sealed envelope containing within the proper name of the author, and, on the outside thereof, the motto or name adopted for the essay. Fifth. At a stated meeting of the Society, in pursuance of the adver- tisement, all essays received up to that time shall be referred to a Com- mittee of Judges, to consist of five persons, who shall be selected by the Society from nomination of ten persons made by the Standing Committee on the Henry M. Phillips Prize Essay Fund. SixtJi. All essays may be written in English, French, German, Dutch, Italian, Spanish or Latin ; but, if in any language except English, must be accompanied by an English translation of the same. Seventh. No treatise or essay shall be entitled to compete for the prize that has been already published or printed, or for which the author has re- ceived already any prize, or profit, or honor, of any nature whatsoever. Eighth. All essays must be clearly and leg ibli/ written, and on one side of the paper only. Ninth. The literary property of such essays shall be in their authors subject to the right of the Society to publish the crowned essay in its. Transactions or Proceedings. Tenth. A Standing Committee, to consist of five members appointed by the President, and ex, officio the President and the Treasurer of the Society, shall continue in office during the pleasure of the Society, and any vacancies that may occur in said Committee shall be filled by new appointment by the President. Eleventh. The said Committee shall have charge of all matters con- nected with the management of this endowment and the investment of the same, and shall make such general rules for publishing the terms upon which said prize shall be competed for, and the amount of the said prize, and if it shall deem it expedient, designate the subjects for com- peting essays. It shall report annually to tlie Society, on the first Fri- day in December, all its transactions, with an account of the investment, of the Prize Fund, and of the income and expenditures thereof. 4: MINUTES. [Jan. 15, 2. Resolved, That any and all Rules and Regulations relating to the Henry M. Phillips Prize Essay Fund which appear in the printed min- utes of the meetings of the American Philosophical Society of December 7 and 21, 1888, or other dates, be, and they are hereby, repealed so far as they are inconsistent with the Rules and Regulations herein contained. The report was accepted and ordered to be spread upon the minates, and the resolutions appended were adopted. It was moved that the Secretary cast a ballot for Dr. G. H. Horn as Librarian for the year 1897. Adopted. The Secretary reported the ballot cast, and Dr. Horn was declared unanimously elected Librarian for the ensuing year. Mr. Price moved that Dr. Hays be elected Librarian pro tem.^ to perform the duties of the office until the return of the Librarian. Unanimously adopted. A paper by Samuel H. Scudder, entitled " The Species of the Grenus Melanoplus, ' ' was read by title and referred to the Secretaries for action. Mr. Mercer then read a paper on ' ' The Fossil Sloth of the Big Bone Cave, Tennessee," which Prof. Cope and Mr, Cush- ing discussed. Dr. Frazer presented a "Eeport of a recent visit to the Black Hills of South Dakota." Mr. G. T. Bispham offered the following : Resolved, That a committee consisting of Hon. George F. Edmunds, W. P. Tatham, Esq., W. A. Ingham, Esq., Samuel Dickson, Esq., and Richard L Ashhurst, Esq , be appointed to consider and report whether any, and, if any, what amendments or alterations should be made in the laws of the Society. Unanimously adopted. Dr. Frazer moved that Mr. Ingham's proposed amendment to the Laws be referred to that committee. Seconded by Mr. Ingham, and unanimously adopted. Prof. Cope moved that the President be authorized to appoint the Standing Committees for the current year, and that, with the view of increasing the interest of the mem- bership in the work of the Society, it be respectfully sug- 1897.] THE SPECIES OF THE GENUS MELANOPLUS. 5 gested, as far as is possible, not to duplicate the liolding of official positions. Unanimously adopted. The death of the followino- members was announced : Dr. Theodore G. Wormley, of Philadelphia, on January 3, 1897, ^t. 71 years. Dr. William Henry Pancoast, of Philadelphia, on January 0, 1897, ^t. 61 years. The Society was then adjourned by the presiding officer. THE SPECIES OF THE GENUS MELANOPLUS. BY SAMUEL H. SCUDDER. {Read January 15, 1S97.) In a memoir to be published by the United States National Museum I have described in detail all the species of Melanoplus known to me, whether new or old. As, however, some delay has occurred in the printing of that paper, I am permitted to give here a table for the determination of all the species and their distribution into series, following it with such portion of the synonymy (given in detail in the memoir referred to) as will enable one to understand the latest determinations made after careful study with abundant material. The genus, it should be said, is characteristically American, and is widely disseminated. Some confusion has resulted in former times by not recognizing the dimorphism which occurs in this and the allied genera in the length of the organs of flight, a subject dis- cussed at some length in my detailed memoir, where also will be found remarks on their geographical distribution. Although the prime division in the table separates the macrop- terous and brachyterous species, the same series and sometimes the same species may appear under both divisions, and the final arrangement of series following the table is independent of this dis- tinction. I have given the name of furcula to the processes of the last dorsal segment of the male abdomen. ' THE SPECIES OF THE GENUS MELANOPLUS. [Jan. ir>, Table of the Species of Melajioplus. A^. Tegmina conspicuously shorter than the abdomen, often no longer than pronotum ; furcula almost always developed feebly, generally no longer than the last dorsal segment from which it arises. b'^. Cerci of male expanding and bullate from the base outward, abruptly tapering and bent inward at tip ; subgenital plate of male abruptly elevated apically (Lakinus series). . Cerci of male regularly subfalciform, by both margins being uniformly and distinctly curved rather than bent, and more than twice as long as median breadth alaskanus. h . Cerci of male nearly straight as viewed later- ally, or slightly bent upward in apical half, rather than curved. /\ Cerci of male distinctly more than twice as long as median breadth, the apical half subequal but narrower than the basal half. J \ Hind tibiae normally pale glaucous ; when red, pale red. k^. Larger, robust ; median carina usually as distinct between the sulci as on the ante- rior portion of the prozona affinis. k^. Smaller, slender ; median carina usually obsolete or subobsolete between the sulci . . iftterjnedms. J'. Hind tibiae bright red bilitiiratus. P. Cerci of male not more than twice as long as median breadth, the apical half not only nar- rower than the basal half, but itself tapering throughout, obliquely truncate beneath ; hind tibiae usually red.* y\ Tegmina brief, not nearly reaching the tips of the hind femora ; apical margin of subgenital plate of male greatly elevated defecius. y^ Tegmina reaching, generally considerably surpassing, the tips of the hind femora ; apical margin of subgenital plate of male moderately elevated atlanis. g-. Tegmina extending beyond hind femora by the length of the pronotum or nearly as much, often by the length of head and pronotum combined ; pro- zona of male generally strongly transverse ; cerci of male not more than half as long again as broad spretus. . nov. Dawsoni series. A somewhat heterogeneous group with both macropterous and brachypterous species and one dimorphic. They are seven in number and occur almost wholly in the great interior region between the Mississippi and the Rocky mountains, and extend from Alberta to central Mexico. They are reflexus sp. nov., meridion- alis sp. nov., militaris sp. nov., uigrescens Scudd. {zimmennamii Sauss.?), daii'soni '^Q.w^^., {iellustris Scudd., ahditiini Dodge), g/ad- stoni Brun. MS., and /^/;;/ a o O" 3 o n ^ o cr B- in *< a> O —. St o a 5 ? ^ a T3 0! •I 3; O a ^ a -i c 2. p 5 "S ^ ^. 25 ^. g o HT. » 3 o 3 ^ O y) C M 3 o § B- CD fJ ' ^. D' ^D. a m" O ' — o n> t/) O rs rt "< 1- o' o* ^ ?r 3 a r: o 3- s- — "^ c rt 5^ p TO 5- o' ? ft ■". 3 (^. p rt ~~ o o 3 < g CD rt > ^ oq 3 o' O 46 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15, equally fresh in appearance and referable to a young animal (because of the loose epiphyses) may well be believed to constitute skeletal portions of the same individual.^ These subsequently arrived at conclusions, however, did not con- cern us when first pausing in the candle light, we placed our tools and baskets upon the ground to listen to the account of Priest. Our hope of finding more bones depended upon the chance that he had not dug up the whole floor and that other remains, resting beyond the limit of his digging, had escaped him and remained to reward our search. Down through the manure and nitrous earth resting beneath it, from nine in the morning till five in the afternoon, beginning where the consistency of the deposit showed that Priest and other diggers had left off, we worked in the dim candle light, until our hunting had accomplished its object, and until the walls of our trench revealed the facts herewith described, and first that of a se- quence in time marked by the layers that had accumulated upon the foothold, and of which two epoch-denoting divisions confront- ed us. They consisted of (below and older) a water-deposited nitrous clay, resting upon the bottom rock, standing for a time when the cave was wet, and (above and later) the manure previously re- ferred to, testifying to an epoch when the cave was dry, and to the latter division with its subdivisions described as Layers i, 2 and ^ Dr. Richard Harlan (see Medical and Physical Researches, hy Richard Harlan, Philadelphia, 1835, p. 321) describes the set at the Academy of Natural Sciences in 1835, He speaks of and partially figures " two claws of the fore feet, a radius, a humerus, a scapula, one rib and several remnants, an os calcis, a tibia, a portion of the femur, one lumbar and four dorsal vertebrae, the portion of a molar tooth, to- gether with several epiphyses, the bones of a young animal imperfectly formed at the extremities." Distinctly noting the cartilage on several of the specimens, he calls par- ticular attention to the nail on one claw (see Fig. 3 ). According to him , they were ob- tained by Mr. Dorfeuille (proprietor of the Cincinnati Musem) from a Mr. Clifford of Kentucky, bought from Dorfeuille by Mr. J. Price Wetherill, and presented by the latter to the Academy of Natural Sciences. Harlan had in another paper referred to these bones as coming from White cave, Kentucky, and after repeating the state- ment here corrects it at the last moment with a footnote which says, *' According to the recent observations of Dr. Troost, these bones were derived from the Big Rone cave, Tennessee." My guides' Priest and Johnson had heard of the discovery of other sloth bones at the cave in the early part of the century, and for the reasons above given I have no doubt that the nitre diggers (of 1812 probably) found them at the site of the other discoveries, and that Clifford obtained them through intermedi- aries. Interesting details of this first discovery would probably appear in Dr. Troost's communication to Dr. Harlan if it could be found. 1897.] THE FOSSIL SLOTH AT BIG BONK CAVE, TKNX. i7 Fig. 4.— Diagram showing a vertical section of the gallery in Big Bone cave where the sloth bones were found. Layer i (2-3 inches), disturbed surface rubbish with charred torch ends. Layer 2 (2 to 2^ feet), dry loose rat excrement, animal and vegetable remains, etc., with sloth bones. Layer 3 (i foot), crusted lower portion of rat excrement and vegetable remains formed before the advent of the sloth bones. Layer 4 (of undetermined depth), loose pieces of nitrous clay, dry and hard, mixed with manure. The disturbance resulting in the intrusion of torch ends and other objects into the deposit as far as Layer 4, caused by burrowing rats, is seen against the left cave wall. 48 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15, 3, and hence to the later time belong the sloth bones here shown. One after another they were found in the dry manure, which, lying invariably under Layer i above described, I have called LAYER 2. {^2 to 2\ feet thick. See Fig. 4.) As we worked forward through this layer with shovel, hands and trowel to where it thinned out and the saltpetre earth now removed had formed the foothold beyond it, we found it to consist almost entirely of well-preserved, dry excrements of the cave rat, Neotoina magisier, which, intermixed in lesser quan- tity with coprolites of porcupines, Erethizon do7^satus, formed the conspicuous ingredients of the mass. In consistency like a bin Fig. 5 (x >4 ). — First bone found (in Layer 2, depth.about 18 inches), epiphysis or unknitted end of the humerus of a young sloth, Megalonyx. Photographed, resting upon the characteristic rubbish of Layer 2 found around it. i. Bat's ]?L\S', Adelonycteris fusca. 2. Hickory nut and fragment gnawed by rodent, Hicoria glabra. 3. Excrement of large mammal, possibly sloth. 4. Felted hair of bats, rats and porcupines mixed with a woolly fur, possibly belonging to the sloth itself. 5. Bones of the bat, Adelonycteris fusca. The background is composed of a mass of dry coprolites of cave rats, brown dusty earth, and fragments of hard cave clay, " petre dirt." THE FOSSIL SLOTH AT BIG BOXE CAVE, TENX. 49 of oats, the deposit answered every disturbance with a cloud of pun- gent dust. Nuts, sticks, fur and moss were easily seen in it by candle light, but more minute search in the cave and a subsequent study of the speci- mens preserved, revealed at vari- ous points, the seeds, grass, bark, leaves, hair and small botanical fragments de- scribed later. In the midst of this interesting rub- bish, often in contact with seeds, nuts and hair, appeared the twelve sloth bones here shown, pro- truding from the vertical side of the trench at depths of from eight to fourteen inches. No fear of break- ing them, hard, dry and strong as they were, and I question whether they needed the dose of hardening solution which all but four of them have since received, and which has somewhat discolored them. In the dusty dimness we saw the cartilage, marked the signs of rodent gnawing,^ and numbered each bone with India ink as it came out. 1 The bone gnawing of rodents, done with tlieir incisor teeth, often characteristic of bones found by me in American caves, differs greatly from the traces of mastication of the larger carnivoras. The latter, as dogs for instance, working sideways with PROC. AMER. rniLOS. 80C. XXXVI. 154. D. PRINTED APRIL 21, 1897 Fig. 6 (.x %). — The second bone found (in Layer 2, depth I foots inches). Dorsal vertebra. A minute fragment of attached cartilage is not visible in the photograph. The marks of gnawing are upon the opposite side of the specimen. 50 THE FOSSIL SLOTH AT BIG BOXE CAVE, TENX. [Jan. 15, The first bone found (See Fig, 5) was an epiphysis of a humerus. Then came a well-preserved vertebra No. 2 (see Fig. 6), found at a depth of one foot eight inches below the surface and one foot from the right wall of the cave. The small coprolites touched it on all sides. Just above it lay a small twig of wood, and close to it sev- eral bones of bats, described later, while both above and below it we noticed wads of fine hair. The deposit was exceedingly dry, and its removal filled the cave with suffocating dust clouds. Immediately in contact with bone No. 2, as we worked horizontally into the bank, lay bones Nos. 3, 3^ and 4, two unseparated vertebrae with a loose epiphysis resting between tliem (see Figs. 7 and 8), directly under which we found two gnawed hick- ory nuts and an acorn. As we advanced vertically into the manure, another vertebra, the fifth bone found (see Fig. 9), bone No. 6, the heel bone (calcaneum) (see Fig. 10), and bone No. 7 (the astra- galus), (see Fig. 11), were revealed lying but a few inches apart. With deep interest I removed them. Just below the fifth bone, at which point the Fig. 7 (x 3/2)-— Third bone found (in Layer 2, depth 20 inches). Dorsal vertebra. Signs of rodent gnawing not shown in photograph. Cartilage is seen attached to the base of the right projection. their sharp canines and edged molars, dent the bones, or tear their corners irregularly, while the rodents furrow the points of vantage neatly, with numerous unmistakable parallel grooves, resembling the work of a coarse file held evenly. 1897 THE FOSSIL SLOTH AT BIG EOXE CAVE, TEXN 51 deposit had hardened considerably (Layer 3) and was mixed with fine pieces of saltpetre earth, another acorn was found, and still another under the astragalus. On that day, May 6, 1S96, at 3.15 in the a fternoon, with the wind blowing from t h e north, a slight draught of air wafted the currents of dust inward as we worked, while, to testify to the open c o m m u n i - cation of that part of the gal- lery and the outer world by means of the roof holes, a small cricket appeared, crawling upon the disturbed earth as we worked at the third bone. A consider- a b 1 y gnawed rib fragment, (see Fig. 17), was followed by a loose epiphysis (see Figs. 12 and 13) and a final vertebra, the tenth bone found (see Fig. 14), lay against the rock wall on the right, not much more tlian eight inches below the surface, where, close to the top of the deposit and still against the wall, the wads of hair were best preserved. Here also Fig. 8 (x ^-2 ). — Tlie fourth bone found (in Laver 2, depth 20 inches). Dorsal vertebra and its loose epiphysis (unknitted plate), illustrating, because not yet ossified together, the unde- veloped backbone of a young animal. The photograph fails show the signs of rodent gnawing and the bits of cartilage attached to the bone below the orifice. o'i THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15. were found a gnawed butternut, several pieces of grass, several small bat bones and dung as usual. The position of these latter objects close to the wall caused us to suspect that they had slid down from the surface, just as close to the left side twigs of leaves had proba- bly been in- truded i n the rat holes. But the ob- jects found at or below the position of the other bones we re- garded as of equal age with them, and as truly Fig. 9 (x y^ ). — The fifth bone found (in Layer 2, depth about 14 inches). Dorsal vertebra. The signs of rodents gnawing, clearly visible in the original, show faintly on the left projection. The cartilage shows indistinctly in the illustration on the upper surface of the left circular plate below the large orifice. indicative of the nature of the layer. Our observation of the position of all the bones showed that they were not (with the exception of the two vertebra and epiphysis (Figs. 7 and 8) in skeletal order : several epiphyses were loose ; the calcaneum (heel bone) lay close to the vertebrae; the single rib found was broken and turned. Unquestionably the bones had been dragged and twisted out of place (inferentially by the gnawing rats or the porcupines) since their deposition. Some THE FOSSIL SLOTH AT BIG BOXE CAVE, TEXX. 58 Fig. io (x y^ ). — The sixth hone found (in Layer 2, depth about i foot). Calcaneum (heel bone) of the extinct sloth Megalonyx. The cartilage (of a bright red toning into yellow in the origi- nal) rests as a thick film, considerably cracked, on the left articular face. Marks of rodent gnawing are shown around the lower circumference. :^ Fig. II (x -/i). — The seventh bone found (in Layer 2, depth about i foot). An astragalus (joint or hinge bone of foot). A layer of cartilage (yellowish red in the original) covers the round face and protrudes in brittle flakes from the hollow. 5i THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15. Fig. 12 (X % ). — The ninth bone found (in Layer 2, depth about i foot). Two vertebral epiphyses indicating, because unwelded upon the larger bone, a young animal. The cartilage is plainly seen above the break. Fig. 13 (x %).— The ninth bone found (in Layer 2, depth about i foot). Fragment of the vertebral epiph- ysis shown in Fig. 12. The attached cartilage is plamly seen. The color of the latter in the original is semi-translucent red. may have been car- ried away to hid- den crannies through burrows noted later communicating with the rubbish. Long before we had pulled the last bone out of the dust, our attention was at- tracted to the lower or older portion of the manure, which, owing to its peculiar consistency, I have called ZA YER 3. {i foot thick.) In it we observed no porcupine quills or tufts of fur, and for the rea- son below stated suspected that this lower subdivision of the dry ex- 1897. THE FOSSIL SLOTH AT BIG BONE CAVE, TEXX, 00 crement had become hardened and caked together just under the bones, into what it seemed reasonable to suppose had constituted the foothold of the cavern when the extinct animal appeared. Objects found in it, therefore, a further series of nuts, seeds, twigs, leaves, bat jaws, and fur described below, together with the dry carcass of the window fly, were to be reasonably regarded as older than the sloth. How may we better account for the character and position of this crust, than by supposing that it represented that portion of the once lower floor where the carcass of the animal had for a time rested and into which the juices had fil- tered, caking to- gether the copro- lites during the consumption o f the flesh by rats and porcupines ? This not im- probable suspi- cion was strength- ened when we considered the number of bones found at the spot, not simply the twelve exhumed by us, but those previously excavated by Priest and Johnson, now in Prof. Saf- ford's possession, and we may add the eighteen other remarkable cartilaginous specimens, presumably from the same spot, at the Fig. 14 (x Yz ). — The tenth bone found (in Layer 2, depth about 8 inches). Dorsal vertebra more wasted than most of the other specimens. Discolored by a preservative preparation applied since its excavation. The signs of rodent gnawing are not shown in the photograph. 56 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15, Academy of Natural Sciences. If the whole combined series fails to duplicate or contradict the construction of a single fossil sloth skeleton, then all, because all indicate a young animal, and because all show cartilage as no other sloth bones elsewhere found have yet done, can be reasonably referred to the same indi- vidual animal. Many other bones, originally near or upon the surface, may have been removed by Indians or carried away by salt- petre diggers and lost. Rats may have made off with others. And, notwithstanding the fact that the sets belonging to the Academy and Prof. Safford, together with my specimens, may fail to recon- struct the animal's skeleton, the three sets together include enough bones to indicate that the creature had once lain there in the flesh. Because the tooth marks seem to refer to the work never of carnivora, but always of rodents, less to the efforts of large than of small animals not strong enough to have carried a skull such as Priest found, or a scapula like that at the Academy, from any other resting place in the cave, it seems reasonable to suppose that the bones reached their position by the most natural of agencies : that the sloth, lost or overcome by sickness in the dark- ness, had lain down to die at the place in question. Reasonably doubting that it had shambled into the cave after the helpless club-footed manner of the modern Ai or Unau, shall we speculate further and imagine that the animal, less clumsy and slug- gish than its modern South American relatives and presumably her- bivorous from the structure of its teeth, was attracted to the spot by the smell of grass and leaves, brought thither by porcupines and rats ? If not, we must believe that its choice of a deathbed in the only rat den in that part of the cave was a coincidence. But, however the position of the bones is to be accounted for, let us believe that if the carcass lay upon the manure, the number of visiting omnivorous rodents increased until the process of devouring the flesh had been succeeded by the gnawing of the bones. If these suggestions explain how the bones came to be where we found them, we next ask. How old are they ? When did they reach their position ? An inquiry above all de- pending upon the study of the objects dug out of the earth with them. These are to be divided into three classes : First, objects of later age than the bones, or of doubtful antiquity ; second, objects as old as the bones, and third, objects older than the bones. To the first class belong the torch ends of cane. THE FOSSIL SLOTH AT BIG BOXE CAVE, TEXX. Ot Arundinaria tecta, hazel ; fragments of clay, coprolites, and bits of charcoal, mentioned above, as belonging to Layer i, and, second, objects artificially intruded into Layer 2. Objects of Later Age Than the Bones, or of Doubtful Antiquity. The hoarding habit of the underground rat had helped our inves- tigation at Big Bone cave, but his burrowing perplexed and vexed us, confronting us with one of the dangers that often threaten exact observation in caves. The slowly formed accumulation of dry ex- crement had been undermined and disturbed by the tunneling of its makers against the right and left walls, where several rat holes were revealed by a variation in the texture of the neighboring layer. Pushed and wadded into these burrows (see Fig. 15) we FlC. 15 (x Yo ). — Specimens of displaced rubbish found stuffed into and filling the rat holes. I, 2 and 3. Burnt sticks, pieces of charred cane, Arundinaria tecta, and charred hazel twig, Corylus americana, representing the ends of burnt-out torches cast away by white men or Indians, often found at a greater depth in the layer than the sloth bones, having been intruded into the burrows from the surface by small animals. o8 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15, found a bunch of moss, Hypnum ; ten twigs from three to eight inches long, charred at the ends and evidently the remnants of torches, used by Indians or white men, of the hazel, Corylus americana ; five fragments, one of them charred and three inches long, of resinous yellow pine, Finns mitis ; a fragment of charred cane stalk, Arun- dinaria macrosperma^ and another twig about eight inches long, not burned, of the cane, Ariindinaria tecta ; a gnawed pig nut, Hicoria glabra, and a shellbark, Hicoria ovata ; a piece of hickory nut, Hicoria minima ; a chokecherry stone, Priinus virginiana Linn.; a piece of hazel nut, Cory/us americana ; a fragment of an acorn of the pin oak, Quercus palustris, and three pieces of winged seeds of the blue ash, Fraxinus quadrafigiilata, besides a piece of bark, prob- ably hazel, and fragments of unidentified grass and bark. Besides these botanical specimens kindly identified (with all others referred to in this paper) by Mr. Stewardson Brown, of the Academy of Natural Sciences of Philadelphia, Mr, S. N. Rhoads, and Dr. Har- rison Allen, of the Academy, have further settled the identity of twenty quills of the porcupine, Erethizon dorsatus, with its numerous excrements, (See Fig, i6) and a piece of hair, which had found their way info the holes, be- sides the upper jaw with por- tions of the skull of a bat, Vesperti- lio gryphus ; and a lower and up- per jaw, with teeth and cartil- age attached, of a larger bat, Adelonycteris fusca. More excrements of porcupine seemed to have worked into the choked -up holes than were observed in the undisturbed portion of the layer, while with them was found a fragment of the brain case of a large mammal, smaller, according to Mr. Rhoads, than an adult bear. If this small specimen, not an inch in length, cannot be regarded as a portion of the remains of the Megalonyx, it represents the only trace of any Fig. i6 (actual size). — Quills of the porcupine, Erethizo7i dorsatus, found with other intruded rubbish at various depths in the rat holes. No signs of the porcupine were found in the lower part of the manure (called Layer 3). Coprolites of cave rats and pieces of clay form the background. 1897.] THE FOSSIL SLOTH AT mCr ]K)NE CAVE, TEXN. 59 Other large animal that we, or our guides previously, were able to find at the spot. But the objects found in the rat holes could not reasonably be associated with the bones. Though positively testi- fying to the presence of men as well as of animals in the cave, the charred torch sticks and other articles had been transported from their original position in the manure; and while it was certain that objects found in the superficial Layer i (including the torch ends, see Fig. 2), were more modern than the sloth bones, the rat-hole specimens had lost their true time relation to the sloth. If not all intruded downward from above, and so presumably more modern than the bones, the collective age of all the specimens was doubt- ful and offered no evidence of the contemporaneity of man and the Megalonyx. On the other hand, no sign of disturbance was presented by the texture or contents of the middle portion of Layer 2. There the objects found at various points, and particularly close to the bones, seemed fairly to be regarded as ingredients of the deposit. Un- doubtedly they represented plants and animals in existence at the time the bones had been deposited. As we dug on with shovel, hands and trowels, narrowly observing that part of the manure (in many cases preserved by us in bags) lying in immediate contact with the bones, our work revealed by reasonable inference a series of Objects as Old as the Bones. In the handfuls of refuse removed from close proximity to the sloth bones and preserved in bags were found, as identified by Mr. Rhoads (see Fig. 23), numerous tufts of the fur (also found in the rat holes), a comparatively large excrement quite unlike the other coprolites in size and shape, attributed by Mr. Rhoads to an her- bivorous animal (see Fig. 17 object 8 and Fig. 5 object 3). Of the common coprolites previously mentioned, the larger and scarcer ones containing fine shining particles of undigested hulls and skins of nuts, showed that the porcupine {^ErcthizoJi dorsatus), guided by other senses than sight, had been continually present during the formation of Layer 2. So testified a hair from the back of one of these animals (Fig. 17 object 16). Eight beautifully preserved minute jaws and several little bones were identified by Dr. Harrison Allen as the remains of two kinds of still existing bats, Adclonycteris fusca (see Fig. 17 objects 17) 60 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN [Jan. 15, and the smaller Vesperiilio gryphus. Unfossilized and fresh look- FlG. 17 (x Vo). — Eighth bone found (Layer 2, depth about one foot). A rib show- ing signs of rodent gnawing along its edges. A part has been broken off at either end, and the specimen appears to have been much dragged through the refuse. Its color is light brownish yellow. No cartilage was attached to it. The rubbish of Layer 2 forms the background. Noticeable ingredients of the layer are ranged on either side of the bone. I and 14. A felted mixture of rodent hair with woolly fur, possibly of sloth. 2. B3.X]2c^, Adelonycterisfus- ca. 3. Beech nut, Fagus amer- icana. 4. Winged seeds of blue ash, Fraxinus quadran- qulata. 5. Acorns of red oak, Quercus rubra. 6. Acorn cup of Spanish oak, Quercus digi- tata , sunflower, Helianthus an- imus and alder, Alnus incana, seeds. 7. Hickory nuts, Hic- oria minima. 8. Coprolite ot arge animal, possibly Mega- onyx. 9. Gnawed shellbark, Ilicotia ovata. 10. Twigs, II. Fragments of skein of maize silk, Zeamaiz, excluded from the evidence for reasons given in the footnote to page 63. 12. Gnawed hickory nut. 13. Another coprolite of large animal. 15. Jaw with teeth ol cave rat, Neotoma magister. 16. Porcupine hair, Erethizon dorsatus. 17. Bat jaw and bones, Adelonycieris fusca, with twigs of dogwood, Cornus aKeniifolia, just below. 18. Hazelnut, Corylusamericana. ing, the bones, according to Dr. Allen, represent individuals which 1897.] THE FOSSIL SLOTH AT BIG ]iOXE CAVE. TEXN HI Fig. i8 (actual size). — Speci- men of Layer 2. An acorn cup of the pin oak, Quercus palus- tris, and a gnawed mocker nut, Hicoria alba, rest upon frag- ments of cave clay and a mass of drv rat manure. butter nut. had fluttered througli the congenial blackness of the gallery in geologically recent times, though we ad- mit that the species referred to are an- cient and probably existed at the epoch called post-glacial. In the very close neighborhood of the bones, as further identified by Mr. Stew- ardson Brown, we found fragments of the acorns of the red oak, Quercus rubra Linn. (Fig. 17 object 5), and of the white oak, Quercus alba Linn.: an acorn cup of the pin oak, Quercus palusiris Duke (see Fig. 18); half of a nut gnawed by rodents of the thick-shelled, small-kerneled mocker nut, Hicoria alba Linn., Br., (see Fig. 18) several gnawed nuts of shellbark, Hicoria ovata Mill, Br., and the gnawed nut of the Juglans cinerea Linn. With these lay several fragments of winged seeds of blue ash, Fraxiuus quadrangulata Mich, (see Fig. 19 and Fig. 17 object 4) ; two seeds of the horn beam, Fraxiuus caro- liniana Walt.; a piece of bark of the chokecherry ; a seed of the gum Nyssa sylvatica ; two small twigs of dogwood, Cor mis aliernifolia Linn.; fourteen lit- tle fragments of sticks and leaves and several pieces of bark undetermined, together with two wild cherry stones, Prunus pennsylvanica Linn. ; while re- corded as exactly under one of the sloth ^^"g^^ ^^^^" °^ ^^^ ^'"^ '^'^^' , ,,1 1 ,- 1 , 1 Fraxinus quadrangulata, and in- bones we pulled out a seed of the alder, ^j^^ ^^ ^ ^^^^^^ ^^^^^ ^^ ^^^ AhlUS incana Linn, (see Fig. 20), and red oak. Quercus rubra, rests a another of the horn beam, Ca7-pinus \i&^c\in\x'i,Fagusamericana.l\\&%& caroliniana Walt., with a nut of the ^^"^^ ''^'^ unearthed near the , , . large bones and had probably beech, ragus a?nericaua bweet (riff, k r, 1.-^ M,f \^*r. ti.^ oo„o f^V ' o V o been brought mto the cave lor 19 '• food or nest building by the cave There was no reason for doubting rat, Neotoma viaglster. that these objects had reached their position at or about the time of Fig. 19 (actual size).— Rat ex- crement, clay and vegetable rub- bish characteristic of Layer 2. Against two fragments of the 62 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 15 the deposition of the sloth bones. Many of the nuts had been gnawed by cave rats (see Fig. 17 object 9), Neotoma magister, and the same agile pilfering animal, helped possibly by the porcupine, had doubtless dragged in by way of the roof holes, whether for nest building, for food, or in pursuance of its eccentric hoarding habits, many of the other objects scattered at various points in Layer 2. In this mass of excrements of the cave rat, which, dry as they were, were crushed with some difficulty between the thumb and finger, together with the lesser porcupine coprolites, we found a hair from the back of the porcupine and a portion of the right side of the upper jaw with molar teeth of the cave rat (see Fig. 17 ob- jects 16 and 15). Scattered irregularly through the layer, as identi- fied by Mr. Thomas Meehan and Mr. Brown, lay an acorn cup of the Spanish oak, Qiiercus digitata (Marsh) Sud. (see Fig. 20); two fragments of acorns of the pin oak, Quei^cus palustris; a seed of the horn beam, Carpinus caroliniana Walt.; and fragments of seed of the blue ash, Fraxinus quadrangidata Mx.; a fragment of hickory nut, Hicoria minima /of hazel nut, Corylus amer- icana, Walt, (see Fig. 17 object 18), and of beech nut, Fagus americana Sweet (see Fig. 19); a valve of the hop horn beam, Ostrya virginica Willd.; an awn of wild rye or lyme grass, Elymus Linn.; and a piece of the stipe of common brake, probably Ptcris aquelina Linn. With these were two seeds of the blue ash, Fraxinus qiiadrangulata, others of thehorn beam, Caj'pinus caroliniana (see Fig. 21), alder, Alnus incana (see Fig. 20), beech, Fagus americana, and gum, Nyssa sylvatica (see Fig. 21), two wild cherry stonts, Pru?tus pennsylvani- cus, a piece of chokecherry bark, twigs of dog wood, Cornus alternifolia, frag- ments of sticks (see Fig. 17 object 10) and leaves, and, according ro Prof. Fig. 20 (actual size). — Chaiacter- istic portion of the rubbish of Layer 2. Coprolites of the cave rat and pieces of dry clay form the back- ground. The vegetable remains carried into the cave by rats and porcupines w^ere found buried in the undisturbed layer near the sloth bones. i. Acorn cup of Spanish oak, Quercus digitata. 3. Two seeds of the alder, Alnus incana, and, 2. Seed of the sun- flower, Helianthus annuus, a plant supposed by botanists to have been transplanted by Indians from South America or the trans-Missis- sippi plains. Omitted from the evidence for reasons given below. 1897.] THE FOSSIL SLOTH AT BIO BONE CAVE, TKXX. (>::^ Heilprin, one of the bead-like stem segments of a crinoid character istic of the carboniferous lime- stone of the cave walls. Judged by this botanical asso- ciation, the age of the sloth re- mains was that of the flora of the surrounding hills, and that had not changed since seeds, nuts and bones came together. These specimens of well-known trees and plants common to the forest of eastern North America still flourished upon the moun- tain above us. But over and above the gen- eral significance of this fact, two objects discovered — the fur and the large coprolite had a particu- lar bearing upon the investiga- tion.^ Fk;. 21 (actual size). — Ob- jects which were imbedded in the cave earth about the time that the sloth bones reached their position, i. Gnawed seed of the gum Nyssa sylva- iica, and 2, gnawed seeds of the hornbeam, Carpinus carolinl- ana, found in the unhardened later part of the manure (Layer 2) around the resting place ot the sloth. Cave rat coprolites and characteristic ingredients of Layer 2 in the background. L, 1 Not in the underground darkness, but seven months later, during the exam- ination of the contents of two muslin bags, brought from the cave, labeled Layers 2 and 3, and finally placed in glass jars, I found (as identified by Mr. Brown) two fragments of maize silk, Zea mais, (see Fig. 17 object 11, and Fig. 22 object 2), and a seed of the sunflower, Helianthus annuus, (see Fig, 20 object 2). If unquestionably bedded as deeply in the undisturbed deposit as the sloth bones, these specimens might well have testified to the existence of an aborig- inal cornfield or sunflower plantation rifled by cave rats on the hill above, or in other words (if with recent investiga- tors we suppose maize to have been in- digenous to southern Mexico, the sunflower to South America or the trans-Missis- sippi plains, and disseminated North and East by Indians), to the contemporaneity of the red ma'n with the sloth. But as several ears of corn in the husk came from Tennessee in contact with the specimen bags, there is a chance that skeins of the former, clinging to the outside of the muslin bags may have fallen into the glass jars,, when the latter were filled from the bags— while a mischance in the process of afiix- FlG. 22 (actual size). — Objects which reached their position in the cave earth before the advent of the sloth bones. I. Jaw and bone of the bat, Vespertilio gryphus. 3. Hair of the cave rat, Neo- toma mngister, and 2. Skein of maize silk, Zea mais, excluded from the evi- dence for reasons given in the footnote. 64 Fig. 23 (actual size).— Mass of felted hair of rodents, together with a fine wool belonging possibly to the extinct sloth, found scattered through Layer 2, and often near the large bones. On this lies a jaw from the same layer of the bat, Adelonycterisfusca. The back- ground shows the mass of rat manure and clay fragments characteristic of Layer 2. Sometimes close to the bones, and generally scattered through ihe whole mass of manure in Layer 2, felted like tufts of carpet dust in an unswept room, lay wads of hair or fur (see Fig. 23, Fig. 5 object 4 and Fig. 17 object 14), exceedingly fine, slightly crinkled, with a reddish brown color, pos'^ibly due to contact with the cave earth. To what animal shall we attribute them? Certain fine bits may, according to Mr. Rhoads, be referred to the bat and a few straight hairs to the rat or porcui)ine. But as none of the rat fur has this crinkle, and as the under fur of the porcupine, according to Mr. Rhoads, is coarser than these specimens and always straight, this crinkled cave wool is attributable to neither animal. Shall we suppose it to be the under fur of the buffalo, or of any of the ani- mals of the outer forest carried down into the cave in predominant quantity by rats? Is it sloth fur, and if so, why its extreme fine- ness? Where are the large, limp hairs, flattened in appearance and grayish white in color, characteristic of the living sloths ? Shall we fancy the fossil sloth fine-furred as a seal? Yet if this discovered fur, which in all reason is contemporary with the sloth bones, be not sloth fur, what became of the sloth fur if the animal, as we suppose, perished here? Leaving the significance of the fur in doubt, we are left to account for the comparatively large excrement of a herbiverous animal, like- wise found in Layer 2, and altogether too large for the porcupine or cave rat (see Fig. 17 object 8 and Fig. 5 object 3). Because no other trace of a herbiverous animal of the size indicated was observed at the spot, and because of the herbiverous character of the sloth itself, it has seemed to Mr. Rhoads and myself possible to refer it, modern as it looks, to the latter mammal rather than to ing labels makes it doubtful whether the sunflower seed belongs to Layer 2, or came from a rat -hole. For these reasons, I abandon the hope of positive demonstration involved in the presence of the sunflower (used by Indians for food and oil, and o f maize, his favorite plant) , that sloth and Indian were contemporaries at Big Bone cave. 1897.] THE FOSSTT. SLOTH AT ]ilG J^ONK CAVE. TKXX. Of) the exceptional presence of any other grass-eating creature at tliat part of the cave. On the other hand, it appears small for the great sloth, while its unbroken contours infer that it must have been transported when dry and hard if we are to ascribe it to the deer or any animal of the outer forest, and suppose that the hoarding rat carried it down the roof holes into the cave. In the compact lower portion of the manure called Layer 3, form- ing, as before described, a crust suggestive of an older floor immedi- ately under the bones, we found what by a reasonable inference were regarded as Objects Older Than the Bones. Here in the dense mass of rat excrement, rested a lower jaw of the bat, Adelonycteris fiisca (see Fig. 25 object 7), as to which, in completing the list of bat remains found in the cave, Dr. Allen says that the bats here described seem larger than our common eastern forms, though no marked variation in bats has been observed since the Pleistocene.^ Not far from this, and as kindly identified by Mr. C. M. Johnson, of the Wagner Institute, lay a well-preserved dry carcass of the small " window "fly (see Fig. 24), common in the United States, first described in America by Say, in 1828, as a new species, Scenopinus pallipes, but afterwards recognized as iden- tical with the European Scenopinus fenesartlis Linn., the window-haunting adult insect of the so-called carpet worm. Entomologists have left us in doubt as to its life and habits, but we may suppose that its food quest led it so far under ground as a consumer either of decayed wood, of dried wooly or animal matter (like carpets under which its thin larvc^ are often found), or according to Willaston, of the minute tinidce, or the true wool-devouring ^^^'- ^4 (actual size). moths, psocidcE, who would have attended the . , „ „ _ ^ window fly, Scenopinus decomposition of animal skins and furs at the /enestralis Linn., em- spot. However the fly's visit to the subterra- bedded in the cave nean darkness is to be accounted for, there can ^^^^^ before the sloth 1 T.^i J 1 X ^1 . •. J .1 1 ^1 bones reached their be little doubt that it came down through the ^ position. roof holes like the cricket above mentioned, ^ Of the few fossil bats found in America, Lund discovered four species of Vampyrus, one species of Molossus and one species of Peropteryx in Pleistocene PROC. AMER. PHILOS. SOC. XXXVI. 154. E. PRINTED APRIL 26, 1897. 66 THE FOSSIL SLOTir AT BIG JiONE CAVE, TENN. [Jan. 15, while its position at this depth in the cave refuse would testify to its presence in America before the coming of Columbus, were entomolo- gists not sufficiently sure that it had not followed the white discov- erers in their ships across the Atlantic. Near by were found bedded in Layer 3 small pieces of bark, nuts, grass, twigs, and plant fibre unidentified, pieces of horn beam seed, Cai'pinus caroliniana (see Fig. 25 object 5); a seed of the blue ash, Fraxinus quadraiignlaia ; two shellbarks, Hicoria ovata, and four fragments well gnawed by rodents ; a gnawed bitternut, Hicoria minima, showing orifices for extracting the kernel made by a small rodent ; and six pieces of the acorn of the pin oak, Quercus palusiris (for all of which see Fig. 25). Judging by the absence Fig. 25 (actual size). -^Objects which reached their position in the cave earth before the advent of the sloth bones, i. Shellbarks, Hicoria ovata. 2. BitternHt, Hicoria mifiima, gnawed by rodents. 3. Acorn of pin oak, Quercus palusiris. 4. Fragment of seed of blue ash, Fraxitius quadrangulata. 5 and 6. Nut and seed of the hornbeam, Carpinus caroliniana. 7. Lower jaw and bone of the bat, Ade- lonycteris fusca. The background consists of the characteristic ingredients of Layer 3. Brazilian caves ; and Marsh gives two species oi Nyctetestes and one of Nyctetheriuni from the Eocene of the United States (see Catal. de Mamiferes, Tronsaert, Paris, 1879, extr. Rev. et Mag. de ZooL, 1878). TITK FOSSIL SLOTH AT BIG BONE CAVE, TEXX. 67 of quills, hairs and coprolites, the porcupine had not visited the cave during the formation of Layer 3. Neither were we able to find in the latter layer the wads of fine fur so characteristic of Layer 2 above it, but if these were specimens of sloth fur, their absence is what we might have expected since the fur of the sloth could not well have been scattered over a lower depth than the resting place of its carcass. The absence of these ingredients, these differences in character, together with its position, were sufficient to assign an older date to the lower layer, whether its crusted consistency was due to the infiltration of animal matter or not. According to the order of formation of the different refuse, the lower layer preceded the upper, and the gnawed nuts, the seeds, the fly preserving intact its delicate wings, comparatively modern as they seemed, had reached their position before the deposition of the bones. Faint from continual inhalation of the noxious dust, we had lost the energy to excavate to its bottom, the last and lowest layer, LA YER 4, {Depth unknown.) a mass of fine water-laid clay, broken in lumps ranging in size from six inches to a quarter of an inch in diameter (see Fig. 26), covering the whole floor of the gallery and evidently the equivalent of the ni- trous earth which had been else- where removed. By their lami- nated structure the lumps gave evidence of their aqueous deposi- tion, while hard as they now were they dissolved immediately on im- mersion in water. Some pieces showed an irregular texture as of the caking together of various par- tially hardened muds, while others, in the opinion of Mr. George Vaux, Jr., revealed small fragments (irre- ducible by boiling in water), of adulterated carbonate of lime, prob- ably aragonite. After digging sev- eral holes in the mass to learn that the manure had infiltrated downwards for at least two feet through Fig. 26 (actual size). — Characteris- tic specimens (of Layer 4) under the sloth bones. Photograph of angu- lar fragments of dry cave clay, " petre dirt," between which rat coprolites are seen. The fragments grew larger and were less mixed with manure as the excavation went deeper, but the bottom of this lowermost layer was not reached. . 68 THE FOSSIL SLOa^II AT ma BONK CAVE, TENN. [Jan. 15, its interstices, we abandoned it where the configuration of the cave walls, widening as we went down into a crevice of unknown depth (see Fig. 4), rendered further work under the circumstances hopeless. We left with the reasonable inference that a depth of five, ten or fif- teen feet would have laid bare the whole bottom, as it had been laid bare elsewhere in the gallery. Doubtless the process of drying, which succeeded the deposition of the layer by water, had broken it into lumps, between which the upper refuse, as remarked before, had penetrated, thus adulterating it without obscuring the fact that in its true constitution, for the eighteen inches examined, it con- tained no trace of man or animals. Allowing the dust to settle for the last time, we turned away from the mysterious spot, and, threading our way wearily through the chilly gallery, came with sudden shock upon the dazzling glow and severe heat of a southern evening. With difficulty we toiled home- ward, resting often in the warm woods. At the last remaining point of significance we had examined layers which probably present all the evidence that will ever be collected as to the antiquity of the fossil sloth of Big Bone cave. Let paleontology enlighten us as to the probable character and habits of this animal which we must reasonably regard as one of the common inhabitants of the American forest in Pleistocene times. Comparing the large vertebrae, the skull, the proportion- ately shorter claws and stouter limbs with the skeletons of the existing South American sloths, as here shown (thanks to the kindness of Dr. H. C. Chapman), we may well disbelieve that this animal hung, like the latter, back downward for days upon a single bough, or lagged in one tree or grove until moss formed upon its fur. How shall we imagine the creature, weighing from twelve to sixteen hundred pounds, moving from tree top to tree top in any known North American forest, when on the blowing of wind, according to the saying in Brazil, sloths travel. On the contrary, as the contin- ual falling of so large an animal by the breaking of boughs is not to be imagined, we must deny the creature a strictly arboreal life, rather supposing, with Prof. Cope, that the boughs came down to the sloth than that the sloth went up to the boughs. In place of moss-covered clumps of motionless fur not easily distinguished from leaves, that a keen eye recognizes in South American tree tops, we fancy animals inhabiting the earth and proclaim- ing their presence by the crash of saplings and outlying boughs, 1897.] THE FOSSIL SLOTH AT ]5IG BONE CAVE, TENN. 69 as, rising upon their hind legs or climbing to the forks of heavy trunks, they tear their fodder to the ground. If they despised water, like the Ai and Unau, they licked salt, as their fossil bones bedded in the Petit Anse salt pit in Louisiana and the mire of Big Bone Lick testify. As terrestrial animals continually on the defensive against the foes of the forest, probably little less active than bears, the great sloths would hardly have rolled helplessly upon their backs when attacked like the Unau, or yielded up their dinner with a melancholy drone. On the contrary, though we must imagine them inoffensive and by no means agres- sive enemies of animals or man, the thrust of the powerful arm, and scratch with the claws that brought down saplings, might well have defended them against powerful and active foes. A categorical demonstration that this individual animal was a contemporary of the geologically recent Indian in Tennessee must be abandoned. But the reasonable inference of such association remains. Though the human handiwork, in the form of charcoal and torch refuse (except the rat-hole specimens), lay really on the surface (Layer i), from six inches to one foot above any sloth bone found ; we may justly be satisfied with the recent significance, broadly regarded, of the whole record, and with the absence of plants and smaller animals of any extinct or positively ancient form. Gradually a thin sprinkling of rat excrement upon the clay floor had thickened into a dry dense mass. Before the deposit had reached a depth of two feet, the sloth had appeared and perished, and while the duration of this manure-making process, which finally, rising round the bones, covered them to a depth of one foot or eighteen inches, cannot be safely guessed at in terms of centuries, there can be no doubt that it is geologically recent, and that its construction which preceded and followed the deposition of the sloth bones is continued by the visits of existing cave rats at the present day. The manure formed, the leaves, nuts, grass and seeds found their way in, without the interruption of any important in- terval of time or geological event changing the topography of the cavern. The roof holes had probably remained open continuously. The subterranean temperature of fifty-five degrees Fahrenheit, with an extreme dryness, had probably persisted. The same flora had con- tinued to flourish upon the mountain. The same visiting animals had continued to find the same plant food, while the same bat species had sailed in from the open entrance. PROC. AMER. PHILOS. SOC. XXXVI. 154. F. PRINTED APRIL 2G, 1897. 70 THE FOSSIL SLOTH AT BIG BONE CAVE, TENN. [Jan. 5, Had these bones lain within reach of the percolating chloride of lime, this mineral filling the cavities vacated by animal matter might have hardened them as cave bones are often hardened, but lying where we found them we may well doubt whether they ever would have fossilized. Under such circumstances, let us believe that a nut, a seed, a leaf, or even a fly, would preserve the fresh- ness of its structure for a long time, and hence that the interestmg remains found with the bones may not be so modern as they seem. With this reservation, and without attempting to deal definitely with dates, it seems safe to class the evidence not only as geologi- cally but as historically recent. Not more ancient in appearance, not more brittle than the bones of animals found by me in the In- dian midden-heaps of several caves, the position of the bones in the upper and later part of the rubbish, their gnawed condition, and their association, as described above, offer nowhere a suggestion of great antiquity. Separated from all association with the remains of other Pleistocene animals, they fail to lend the color of antiquity to the situation. On the contrary, like the peccary bones found at Durham cave,^ like the remains of tapir and mylodon discovered in Lookout cavern,'^ they seem modernized by their surroundings. Let us infer that we have found a species which, long surviving its day and earlier relationship, had become an anomaly ; that we have modernized the fossil sloth, if we have not definitely increased the antiquity of the Indian hunter, whose first coming the animal doubtless witnessed in the woods of Tennessee. 1 An exploration of Durham cave by H. C. Mercer. Publications of University of Pennsylvania, Vol. vi. Ginn & Co., Boston, 1897. 2 Bulletin distributed by the Department of American and Prehistoric Archaeology at the University of Pennsylvania. January, 1894. 1897.] XEW PALEOZOIC VEKTEBRATA. Vl ON NEW PALEOZOIC VERTEBRATA FROM ILLINOIS, OHIO AND PENNSYLVANIA. {Plates I-III.) BY E. D. COPE. {Read February 5, 1897.) The following pages contain descriptions of new and little-known species of Fishes and Batrachia from the Catskill and Coal Measure epochs. These are based on specimens which are for the most part contained in the private collection of Mr. R. D. Lacoe, of Pitts- ton, Pa. Mr. Lacoe's collection is in this field, and in that of the fossil plants of the region in question, one of the best in existence. I have already described and figured from it the remarkable (?) Eu- ryptoid, Mycterops ordinatus^^ from the Coal Measures of Cannelton, Beaver county, Pa., and the Holonenia riigosa of Claypole from the Catskill of Bradford county.' In the present collection I report the first Batrachian remains found in the Pennsylvania Coal Meas- ures and describe a new genus of Stegocephali from Cannelton (Ctenerpeton). I also note the occurrence of Glyptolepis in the United States for the first time, and by it extend the range of the Catskill fishes in Wyoming county, Pennsylvania. The occurrence of a large species of Coelacanthus in the Mazon Creek, 111., deposit is also shown by specimens in this collection. PISCES. HOLOPTYCHIUS SERRULATUS Sp. nOV., PI. II, Fig. I. That the more distinct species of Holoptychius can be distin- guished by their scales is the opinion of those palceichythologists who have studied them. The variety of such scales which is found in the Catskill beds of Pennsylvania and New York is considerable, iCope, American Naturalist, i886, p. 1029, PI. XV, Fig. 3. ^Proceeds. Avier. Philos. Soc, 1892, p. 223, Plate VII, Fig. 2. 72 KEW PALEOZOIC VERTEBKATA. [Feb. 5, and I have endeavored to identify among them the species of authors. The H. granulatus of Newberry appears to be based on an inferior side of a scale of some species, whose true characters will remain unknown until the superior face is discovered. The follow- ing species seem to be well founded, and to differ as follows : I. Basal part of scale smooth. a. Ridges entirely broken up into tubercles H. tuberculatus Newb. aa. Ridges partially broken into tubercles . Z^. gigajiteus Ag. aa. Ridges not broken into tubercles. Ridges moderate, inosculating, no intermediate tubercles H. nobilissimus Ag. Ridges moderate, inosculating, small tubercles between the ridges proximally H. dewalkei Loh. Ridges moderate, not or little inosculating \ no tubercles H. americanus Leidy. Ridges moderate, parallel, no tubercles, small.. ZT. radiatus Newb. Ridges very wide with fine grooves H. hallii Newb. II. Basal part of scale with rows of tubercles. Ridges subparallel ; tubercles it\N, in a small tract ; size small .... H. flemingii Ag. Ridges coarse, inosculating, 25-30 ; tubercles less numerous, in 25-30 rows ; large H. i?iflexus Loh. Ridges fine, inosculating little, 40 ; tubercles more numerous, in about 40 rows ] large H. serrulaius Cope. III. Basal part of scale with coarse radiating ridges. Distal ridges coarse, numerous, interrupted, passing gradually into the rather fine, proximal ridges which are not cut by cross ridges ; large H. filosiis Cope. IV. Basal part of scale with fine radiating and concentric ridges (Glyptolepis). Size smaller. Distal ridges coarse, few, closely placed, without lines between ; no radiating lines of tubercles H. latus Cope. Distal ridges coarse, more numerous, closely placed, without lines between; proximal radiating lines of tubercles, forming a fan. H. flabellatits Cope. Distal ridges fine, with thread lines between, proximal radiating lines of tubercles H. leptopterus Ag. 1897. J NEW PALEOZOIC VERTEBRATA. 73 These species are distributed as follows : Europe. N. America. H. nobilissimus. H. a77iericanus. H. giganteus. H. gtga?iteus. H. dewalkei. H. tuber cidatus, H. flemingii. H. radiatus. H. inflexus. H. hallii. H. leptopterus. H. serrulatus. H. paucidens, H. filosus. H. flabellatus. H. latiis. H. quebecensis. The H. nobilissimus, H. giganteus and H. flemingii are described by Agassiz in the Poissons Fossiles. The H. tuberculatus, H. amtr- icanus, H. radiatus, H. hallii and H. giganteus are described by Newberry in The Paleozoic Fishes of N. America. The H. dewalkei, H. inflexus and H. flemingii are described by Lohest in the Ann. de la Soc. Geol. de Belgigue, t. xv, 1888. I described the H.fllosus in the Proceeds. Amer. Philos. Soc, 1892, p. 228. I now give de- scriptions of the H. serrulatus, i\\Q H. latus,^2in& the H. flabellatus. The Holoptychius seri^ulatus is based on a nearly perfect scale on a piece of brown argillaceous sandstone, from Mansfield, Tioga county. Pa., probably of Catskill age, although the color is rather unusual. The scale is represented by a very clean cast, of which a mould is figured in PI. II, Fig. 2. The species is one of the large forms of the genus, the entire scale measuring about two inches in vertical diameter. In characters this scale is of the H. flemingii type, but the dimensions far exceed those of that species, resembling in this respect the H. inflexus of Lohest. It differs from that species in the more numerous, finer and less inosculating ridges of the exposed part, and in the larger batch of tubercles con- sisting of more numerous series, as pointed out in the analytical table. The distal ridges become more prominent near the centre of the scale, and terminate in some elevated portions which may be cut off from the remainder of the ridges, one or two of them becoming tubercles. The tubercles of the proximal part of the scale are sharply defined cones, which increase in size as the series radiate from the centre towards the proximal border of the scale. The tract of tubercles extends over the entire base of the coarse ridges, and not over a part of them only as in the H. inflexus and is 74 NEW PALEOZOIC VERTEBKATA. [Feb. 5, half as wide or more, than the width of the tract of coarse ridges. In this character and in the finer and less inosculating coarse ridges it differs from the H. inflexiis. Measurements. mm. Vertical diameter of scale 46 Longitudinal diameter of distal ridged area 22 '' " *' proximal tubercular area. . . 11 Five coarse ridges in 5 Five rows of tubercles at base of tract in 4 Seven tubercles in. 5 From the collection of Mr. R. D. Lacoe. HoLOPTYCHius LATUS, sp. nov. PL II, Fig. 2. Represented by the two scales from the greenish clay rock of Factory ville, Pa., said to be of Catskill age. The species prob- ably belongs to the section Glyptolepis Ag., and is the first one found in this country. The distal part of the scale presents eight coarse ridges, which are separated by grooves narrower than them- selves, and which do not inosculate. One of them appears to be interrupted. The central part of the scale is smooth, being only interrupted by the tube of the lateral line. The circumference from one side of the tract of coarse ridges to the other presents a wide band, which is primarily sculptured by fine ridges which radiate to the margin, and which are cut by concentric ridges of different degrees of coarseness, but which are coarser than the radi- ating lines. These characters are more exactly defined by the fol- lowing : Measurements. mm. Vertical diameter of scale 20 Transverse diameter of scale 17 Three distal coarse ridges 3 Seven proximal concentric ridges 3 Width of border of concentric ridges 6 Eight radiating ridges in i The scales of this species differ from all those hitherto described in the coarseness and small number of the distal ridges. Their par- allel course distinguishes them from some species, and their failure to reach the center of the scale separates them from others. In size 1S97.] XEW PALEOZOIC VEKTEBRATA. 75 the type of the H. latus is smaller than the full-sized scales of the European species thus far described. HOLOPTYCHIUS FLABELLATUS, Sp. ROV. PI. II, Fig. 3. Established on a nearly perfect scale from a green clay lamina from the supposed Catskill of the '* Narrows " at Coxton, near Pittston, Pa. The scale is in perfect preservation, the finest details of the delicate sculpture being exactly preserved. In the coarseness and parallelism of the distal ridges the scale represents those of the H. latus, rather than the H. leptopterus. In form the scale is longer than deep, and oval in outline, while that of the H. latus is as deep as long, and is rounded quadrate. Whether this difference depends on the position of the scale is not yet determinable. The border of the scale from one side of the distal ridges to the other, is occupied by a broad band which is marked by concentric grooves separated by wider convex inter- spaces. From the proximal end of the coarse distal ridges radiates a perfectly symmetrical fan of twenty-one ridges, each composed of a series of small tubercles, which increase in size to the end of the series. This fan measures half the long diameter of the scale between the coarse ridges and the proximal border. The entire' surface, except that occupied by the coarse ridges, is sculptured by delicate line ridges and grooves of equal width, from the coarse ridges to the circumference, as in the H. pUcatilis. The coarse ridges are twelve in number, and two of them are bifurcate. They are parallel in direction. Measurements. mji. Vertical diameter of scale 11 Long diameter of scale 14 Three distal coarse ridges 2 Seven proximal concentric ridges 1.25 Width of border of concentric ridges 3 Eleven radiating ridges in i From the collection of Mr. R. D. Lacoe. Sagenodus occidentalis Newb. Rhizodus occide?italis Newberry. Report of the Geological Survey of Illinois, Vol. ii, 1866, p. 19, Fig. 2. Three species of Sagenodus have been distinguished by scales 76 NEW PALEOZOIC VEKTEBKATA. [Feb. 5, from the Carbonic system of Ohio and Illinois by Newberry, viz.: S. occidentalis and S. reiiculatiis from the concretions of the Coal Measures of Mazon Creek, Illinois, and S. quadratus from the Coal Measures of Linton, Ohio. The collection of Mr. Lacoe contains twenty-two scales with their reverses in clay concretions from Mazon Creek, and I have recognized the two species described by New- berry from this locality in nine of them. The remaining thirteen belong to several other species which differ widely in the size, form, and sculpture of the scales, no less than six species being apparently represented. Within the limits of these there is considerable varia- tion, largely dependent on the part of the body from which the scale has been derived. They all present a more or less reticulate or tessellate structure, and a sculpture of very fine, closely placed lines, which radiate to the free border, the latter sometimes forming the only sculpture near the latter. This tessellate structure resem- bles that of the existing genus Osteoglossum, and its Eocene repre- sentative Dapedoglossus Cope. Dr. A. S. Woodward refers ( Catal. Fishes B. M.) Newberry's species to the Dipnoans genus Sageno- dus, and the species described below may be ultimately so referred. However, no teeth of Dipnoans have been found thus far in the Mazon Creek beds, while scales are abundant. The reference then remains uncertain, and the species should be determined for iden- tification of the bed at other localities. The species of the Lacoe collection differ as follows : I. Concentric lines conspicuous ; tessellation and radii not con- spicuous. Scales medium to large ; subround S. occidentalis Newb. II. Concentric lines fewer, marginal ; tesselation conspicuous, radiating from a center. Scales medium to large, acuminate distad ; tessellation very fine. . . S. foliaius, sp. nov. Scales small to medium, elongate, subacuminate ; tessellation elon- gate without regular radii or concentric ridges ; center at extremity S. reticulatiis Newb. Scales medium to large, parallelogrammic ; tessellation radiating, radii and concentric ridges extending to free edge ; center at end S. conchiopsis, sp. nov. Scales very large, elongate, tessellation confined to center, from which . issue numerous well-spaced radii , ^. lacovianus, sp. nov. 1897.] NEW PALEOZOIC VERTEBRATA. 77 Scales medium, truncate ; tessellation coarse, diamond-shaped, quincuncial -5". quinciinciatus, sp. nov. Scales medium, truncate ; tessellation coarser parallelogrammic .... S. broivnicB, sp. nov. III. No concentric lines or center ; a border of fine radii. Very large, elongate, tessellation very fine .... .5". magister, sp. nov. IV. No concentric lines or radii ; tessellation extending to pos- terior border. Scales deep, smaller ; center submedian ; tessellation of medium coarseness S. gicrleianus, sp. nov. Of the S. occide?iialis there are three scales (Figs. 1-2, 19-20- 99), which agree well with the descriptions of Newberry. They evidently belong to a large species very distinct from the others here enumerated. I have not identified the S. quadratics Newb. found at Linton, O., in the Mazon Creek specimens. One scale presents a broadly truncate posterior margin, and it is even slightly concave. The size is rather large, appropriately to the S. quadratus, and the sculpture is strongly marked. I suspect that it is a scale from near the shoulder-girdle, and of entirely exceptional form. Newberry's type is incompletely preserved and described, and it will be necessary to secure other specimens from Linton in order for its full characterization. Sagenodus foliatus, sp. nov. PI. I, Fig. i. Founded on two scales in excellent preservation. These differ from those of all the other species here described in their elongate oval form, with subacuminate distal border. The proximal border is strongly convex. The sculpture consists, first, of a wide border of very fine radii, crossed by rather distant concentric lines ; second, of a narrower band of coarser but rather close radii ; and thirdly, of a rather large area of fine reticulations, of which the center marks the proximal fourth of the length of the scale. The marginal band is marked by a reticulation much coarser than that of the center. Measuremenis. mm. Diameters of scale ^1 , . '." ' * ( longitudinal 39 Three tesserae of area i Width of marginal band 6.5 Type No. F. 9 and 10, Lacoe's collection ; Cotypes F. 53, 54. 78 NEW PALEOZOIC VEKTEBRATA. [Feb. 5, Sagenodus reticulatus Newberry, Geol. Sur. of Illinois, iv, 1870, p. 349, PI- ni, Fig. 9. PL I, Figs. 2, 3. I refer four scales to this species ; one of them differing some- what from the other three, a difference which may be due to differ- ence of position. The characters in which all agree, are the very elongate form, with medium to large size, and the coarse and rather homogeneous tesselation, in which the areas partake of the elongate form of the scale. The distal border is narrowly rounded and is marked by a border of fine longitudinal striae, which are not inter- rupted by concentric lines or reticulations. The single scale referred to has a lobe of the distal margin which projects beyond the remaining portion, but which has the sculpture identical with that of the latter. The proximal end is rounded in all and is marked in two of the scales by a few coarse radii. Three of them are further characterized by the presence of an oblique groove near one of the long margins. In two of them this groove cuts off a lanceolate area, passing from one long margin to the distal bor- der, which is unsymmetrical by reason of its presence ; in the scale above mentioned very much so. The center is near the proximal extremity, and is not conspicuously marked. It is possible that the grooved scales belong to the lateral line, but if so, the latter must be very irregular. The diversity in the grooves leads me to suspect, however, that all of them do not belong to the lateral line. This is a large species. Measurements. mm. T^. XT ^ • 1 X (vertical 10 Diameters No. i (groove incomplete) -, , . ,. , ^ ^^ ^ ^ (longitudinal . 36 Four tesserse transversely measured in. ... , 3 T-.. XT ^ I . , (vertical 14 Diameters No. 2 (complete with groove) \y . ,• , Three tesserae (transversely measured) in 2 Nos. F. 175, 176; 57, 58; F. 55, 56; F. 59, 60; Lacoe collec- tion. Prof. Newberry, at the place above cited, includes in this species two scales of different form from those here described, and from the one which he represents at Fig. 9. I should have preferred to have retained his name for the species, to which these two scales 1897.] NEW PALEOZOIC VERTEBRATA. 79 belong, were it not for the fact that he states in his description that the S. rcticidatus is characterized by the elongated form. '' This is best shown," he says, 'Mn some of the smaller specimens, which are more than twice as long as broad, and spatulate in outline." The two scales represented in Figs. 13, 14, belong probably to my S. quinamciatus ; No. 13 is, however, larger than any scale of it which I have seen. Sagenodus conchiolepis, sp. nov. PI. I, Fig. 4. Two scales of peculiar form represent this large species. They are parallelogrammic in outline, the extremities being about equally wide and equally moderately convex. There are two features of the sculpture which are conspicuous ; first, the presence of minute striae, both radiating and concentric, and second, the extension of the tessellate area to the edge of the scale, without border of striae only as in the last species. The ^. conchiolepis differs also from the S. reticulatus in that the terminal boundaries of the area, are also concentric, giving a characteristic appearance. The sculpture, as in the S. reticulatus, radiates from near the proximal end, which is not marked by radii. Measurements. mm. ■r>,. ^ T^T (vertical at middle 20 Diameters No. i - . (longitudinal 42 Tesserae, width 5 to 1.5 T^- X AT ( vertical i -^ Diameters No. 2 - ^ (longitudinal 29 Type F. 15, 16; Cotype F. 17, 18; Lacoe collection. Sagenodus lacovianus, sp. nov. PI. I, Fig. 5. A well-preserved scale indicates another species larger than the S. conchiolepis, and one which resembles more the .S". reticulatus. The scale is an elongate oval with strongly convex extremities. Although one edge is damaged enough remains to show its parallel- ism to the opposite edge. The sculpture is also peculiar. The usual fine radiating lines are present, but there are no concentric lines, either fine or coarse, excepting a coarse one which is one- sixth the length from the distal border, and runs quite close to the long border. The areas are confined to a central tract, which extends from the proximal border over two-fifths the length from it. The space between the concentric ridge and the lateral borders is also 80 NEW PALEOZOIC VERTEBRATA. [Feb. 5, segmented. The remainder of the surface is marked by rather close lines, which radiate from the reticulate center to the borders, and which are rarely connected by cross lines. A coarse groove enters proximad at one-third the width and extends across the scale towards the long margin without reaching it. This reminds of the groove in the S. j-eticulatus. Measuremefits. MM. Diameters of scale 3^^^ C longitudinal 57 Five interradial spaces, transversely measured, in ... . 4 Nos. F. 47 and F. 48, Lacoe collection. The only species with which it is necessary to compare this one is the S. reticidaius. The latter is without the radiating lines seen in this species, and the scales are more contracted distally ; there is also no distinct center. The size is less, but that may be indi- vidual. Dedicated to Mr. R. D. Lacoe, to whom science is indebted for the very fine collections he has made, and to the liberality with which he has furnished them to students for research. Sagenodu^ quincunciatus, sp. nov. Rhizodus reticulatus New- berry, Geol. Sur. of Illinois, iv, PL III, Figs. 13, 14. PI. I, Fig. 6. Represented by six scales, two of them in mutual relation. Size moderate; form wide, one extremity broadly truncate, the other narrowed oval. No concentric lines (an exception noted later) crossing the very fine radii. Reticulation coarse, quincun- cial, areas diamond-shaped, the radial septa only continuing to the truncate or distal margin ; the areas continued and becoming finer to the proximal or narrowed margin. No distinct center, unless the large tessellated area be considered as such. The areas are coarser towards the long margins. There are some lines parallel with the latter, which turn inwards parallel with the truncate border and then cease. In one of the scales these lines continue inwards 50 far as to constitute parts of concentric lines. Measurements. mm. Diameters of scale \ ( longitudinal 28 Width of areas, from 5 to . 75 1897.] NEW PALEOZOIC VERTEBRATA. 81 Three of the scales are smaller than the one measured. Type F. 39, 40 ; Cotypes 6^, 64; 43, 44; 67, 68; 23, 24. This species is figured very imperfectly by Newberry as above cited. His Fig. 13 presents a larger scale than any of this species which I have seen. Sagenodus BROWNI.E, sp. nov. PI. I, Fig. 7. Represented by a single scale in excellent preservation. It approaches the form of those of the S. quincunciatus , but has a widely different sculpture. Scales as deep as long with truncate undulate free margin, and broadly rounded proximal margin. Minute longitudinal and no concentric stri^. Coarser sculpture, consisting of subparallel lines which radiate from a short transverse line near the proximal end to the proximal and distal margins, which are connected by transverse lines, which are not continuous with each other and hence not concentric. It follows that the areas are parallelogrammic. The cross-lines disappear near the dis- tal margin, leaving only the radiating sutures. This scale is wider in relation to its length than any of the species except S. occidentalis and S. gurleianus, and is more broadly rounded proximally, and more undulate distally than its ally, the .S". qidn- cunciatus. The areation is coarser than in any other species and of a unique pattern. Measurements, MM. Diameters of scale J ' [ longitudinal 21 Three areas measured transversely in 3 Type No. F. 13, 14. Sagenodus magister, sp. nov. PL I, Fig. 8. Founded on two scales which exceed in dimensions those of any of the species here described. They differ somewhat in form, one being slightly truncate at both extremities, while the other is more regularly rounded. I regard the former as the type, but suspect that they belong to the same species, as the sculpture agrees closely. There is the usual minute longitudinal striation ; besides, there are no concentric lines, but a fine and irregular areolation extend- ing over the entire surface, except in the type specimen for a short distance at the distal margin ; in the other some of the coarse radii 82 • NEW PALEOZOIC VERTEBRATA. [Feb. 5, ■extend to the margin. There are coarse radii at the proximal mar- gin in the type ; in the other this edge is broken away. In both there is a very coarse areation along the long borders. Measurements. mm. Diameters of type I ^^'•"<=^' 3^ C longitudinal 60 Diameters of areas from 5 to i Diameters of F. 7 ( ^'=«''==^' 36 • C longitudinal 62 Type No. F. 5, 6; Cotype F. 7, S. Sagenodus gurleianus, sp. nov. PL I, Fig. 9. This peculiar species is represented by a single scale. It is at least as deep as long, and the entire surface is covered with reticu- lations. The character of the sculpture is such that I cannot orient the borders of the scale. Its general outline is that of a very obtuse-angled equilateral spherical triangle. Along one of the bor- ders the areation is more minute than along the other two, where it is rather coarse. In a large central tract the areation is interme- diate, but as it is centrally placed, it does not aid in the orienta- tion of the scale, as to the anterior and posterior borders ; while the disposition of the areas indicates which is the vertical, and which the longitudinal diameter. There are apparently none of the fine longitudinal striae usual in this genus, and there are a few concentric ones near the margin with coarse areas. The areolar septa are not regular except a few which are subradial to one of the subhorizontal margins. Measurements. mm. -p.. , r 1 (vertical 18 Diameters of scale . . . . A (transverse 17.5 Coarser areas , 75 Finer areas 2 Type F. 21, 22. Lacoe collection. This species is dedicated to Mr. W. F. C. Gurley, State Geolo- gist of Illinois, to whom I am under much obligation for the oppor- tunity of examining important material. 1897.1 NEW PALEOZOIC VERTEBRATA. 83 BATRACHIA. Ctenerpeton alveolatum, gen. et sp. nov. PI. Ill, Fig. i. C/iar. gen. — Limbs present ; neural spines and chevrons of caudal vertebrae fan-shaped. Ribs present, not alate. Abdomen protected by dermal scuta in series, which form chevrons directed forwards, which terminate on each side of the belly in a series of prominent, elongate and flattened scuta, which form a ledge or shelf on each side. This genus is founded on a specimen on a block of coal shale which is so broken that the head is wanting, and no thoracic plates are preserved, although a considerable part of the right fore limb is present. A trace of bones of a hind limb appears, and it is prob- •able that these members were present, but of small size. The affinities of Ctenerpeton are with Oestocephalus, Ptyonius and Uro- cordylus, as indicated by the characteristic caudal vertebrae. It differs from the first two in the robust scales which protect the belly, and from all three in the presence of an external series of longer flat scales, which form a prominent border, perhaps more or less free, on each side. These resemble the closely placed teeth of a coarse comb, and give the name to the genus. I have not observed this character in any other genus of Stegocephalia. Char, specif. — Each abdominal dermosseous rod consisting of three segments; the median, which forms the angle of the chevron, the intermediate, which is long and slender, and the marginal, which differs in form from the others. It is wider at the base, and is curved gently backwards, terminating in a gradually contracted obtuse apex. It is marked with delicate grooves which run out on the posterior margin, and on the extremity. The anterior edge is slightly overlapped by the posterior edge of the plate immediately preceding. The anterior plates of the external series are short and obtuse. The posterior edge of the rods of the median and inter- mediate series is impressed by a single series of small pits like the shallow alveoli of closely placed small teeth. The neural fans of the caudal vertebrae are considerably wider than the haemal fans, and are divided nearly to the base by a shallow groove, which is not present on the h^mal fan. The fans are of about the same length, and about twice as long as the body of a vertebra. The marginal portion is marked with ten or a dozen short longitu- .dinal grooves, which cut the truncate edge. 84: NEW PALEOZOIC VERTEBRATA. [Feb. 5, The ulna or radius is short, and there is no indication of osseous carpus. The digits are long and slender, and parts of four are pre- served. The first and second phalanges are slender, subequal, and a little shorter than the metacarpal. The species had a short leg and a long foot. The only trace of posterior limb is a bone (per- haps both bones) of the leg. This is quite short, and in appropri- ate proportion to the fore leg, but the piece is too obscure for posi- tive determination. The general proportions are salamandrine with indications of the long tail which characterizes the group of which Urocordylus Hux. is the type. Measurements. mm. • Width of belly at middle 28 Length of median rod of ventral armature 6 '' '< intermediate rod of ventral armature 6 Width '^ '' '' '' " .... I Length " external " '' '' 9 Width " " " " " 2 Length '' (?) ulna 6.5 " " metacarpal 5 *' " phalange i 3 <« <' " ii 2.5 " (?) tibia 5-5 " " a caudal vertebra, body 4.5 ** '' '^ " neural spine 8 " '' *^ " haemal spine 7 From the Coal Measures of Cannelton, Pa. ; from the collection of Mr. R. D. Lacoe. This interesting batrachian is about the size of the Oestocephalus remexj but it appears to have had a lateral crest on each side bor- dering the abdomen, which is wanting in that and all other forms of the subclass Stegocephalia known to me. The lateral rod-plates of the abdominal armature look as though they were in life closely invested by the integument, or even projecting more or less from it. The forms of the abdominal rods and their alveoli are different from anything in the order known thus far. 1897.] NEW PALEOZOIC VERTEBRATA. 85 Ceraterpeton tenuicorne Cope, Report of the Geological Survey of Ohio, *'II. Paleontology," 1874, p. 372, PL XLII, Fig. 2 (by error on plate C. recticorne). PL III, Fig. 2. A partially preserved specimen of this species occurs in Mr. Lacoe's collection. It includes not only the head but the vertebral column as far as the caudal series exclusive, in bad preservation ; part of the thoracic buckler and the greater part of the right hind leg and foot. As this species has been thus far known from a skull only, this specimen is very useful. The^late is so split that the greater part of the surface of the skull is concealed in one of the slabs. On one of them, however, the presence of rows of fossae is evident on the dentary and squamosal bones. The latter are convex outwards as in the type. The horns are placed wide apart and differ from those of the type in being a little incurved to the acute apex. The lateral pectoral shield exhibits a sculpture of radiating lines of small fossae. There are small equal teeth on the premaxillary bone. The orbits are in the anterior half of the skull, and the nostrils and pineal foramen are distinct. The posterior foot is nearly equal in length to the leg, and the slender digits are four and probably five in number. The accompanying measurements give a good idea of the pro- portions of this species. Measurements. mm^ Length of head to occiput, about 16 Greatest width of head 20 Length of horn from base 7- ^* " skull to line connecting posterior border of orbits 8 *' orbit 3 Interorbital width 3.5: Length of vertebral column to femur ^^ " '' femur 5.5, " " lower leg 3 '' '' second digit (not complete) 7 " '^ metatarsal of do 2- " '^ phalange i *' i.5 ** " phalange ii ^' 1.5 PROG. AMEE. PHILOS. SOC. XXXVI. 154. G. PRINTED MAY 18, 1897. NEW PALEOZOIC VERTEBRATA. [Feb. 5, This is the smallest species of the genus. It differs besides from the C. ptmctoUneatum in the smoothness and acuteness of its horns, and in the weaker sculpture, where visible. It has the orbits more anterior and the horns shorter than in the still larger C. divarica- tmn.^ The specimen shows that in this species, and probably in the others referred by me to this genus, both limbs are present ; that the thoracic buckler and ribs are present, and that the spines of the vertebrae, though wide, are not sculptured. The digits are long and were probably connected by a natatory web. The block on which the specimen lies, contains several scales of fishes of the genus Coelacanthus. From Cannelton, Pa., Mr. R. D. Lacoe. Sauropleura latithorax, sp. nov. PL III, Fig. 4. Represented by the anterior half of the animal, with the skull, on a block of coal shale from Linton, Ohio. The superior aspect of the ventral armature and of the thoracic shields is displayed, with the superior surface of the skull. The vertebral column is therefore wanting, but a number of ribs are preserved, as are also parts of both anterior limbs. Hind limbs wanting. In the characters of its ventral armature, ribs and extremities, this species agrees with the type of the genus Sauropleura, S. digi- tata Cope. In the character of the skull, thoracic and ventral armature, and limbs it agrees with the genus Colosteus Cope. It is probable that the latter name must be regarded as a synonym of Sauropleura (as I have suggested in the paleontology of the Geol. Survey of Ohio, 1874, p. 406), although further material will be necessary to determine this point positively. < In any case it may be assumed that Sauropleura had a thoracic armature from marks on the original specimen, and this is the only character in which it was supposed to differ from Colosteus, where it is present. The ventral armature consists of longitudinal series of short scales, which series form chevrons directed forwards. The median scales are rounded in front on the superior side, viewed from above. The thoracic shields are rather wide for their length. The inter- clavicle (? praesternum) is rounded posteriorly, with a regularly oval outline, and the width is subequal for a distance anteriorly equal to the width. Each of the clavicles is as wide as the inter- clavicle posteriorly. The anterior extremities of all are concealed in the matrix, and the sculpture cannot be made out, as only the supe- iCope, 1897.] NEW PALEOZOIC VERTEBRATA. 87 rior surface is visible. The interclavicle displays a low median longitudinal keel upwards. The tympanic notch of the skull is feeble if present ; it is quite possibly absent, as in the genus Acheloma. The muzzle is broadly rounded. The orbits are rather large, and the posterior borders fall a little behind the line which divides the length of the skull into two equal parts. The frontal is excluded from the supraorbital border by the large postfrontal. The postorbital is a longitudinal oval, acuminating to a point posteriorly. The cranial bones are honeycombed with fossae, which are considerably wider than the diameter of the intervening ridges. The fossae are generally elon- gate in a direction radial from the centre of the bone to which they belong. There is a long tooth near the extremity of the den- tary bone. ^Most of the remaining teeth are concealed, but some very small ones on the premaxillary and maxillary bones are visible, and parts of some larger maxillary teeth appear below the posterior part of the orbit. The bases of the teeth are coarsely incised grooved, /. e., the surface is inflected. The legs are robust and the digits rather slender. The only ungual phalange preserved is slender, acute, and slightly curved, like that of many lizards. The humerus is robust and considerably expanded at the extremities. The ulna and radius are of usual pro- portions, and about three-fifths the length of the humerus. The metacarpals and phalanges are slender. No osseous carpus. Four digits are preserved ; whether there is another cannot be ascer- tained. The ribs are long, rather slender, and not alate. Measurements. mm. Length of skull to occipital condyles 46 " '' " *' " table, posterior border. 35 Width '' ^' at angles of mandible '^d Length '' *' from posterior border to orbit (axial) 26 "■ " orbit 15 Width '' '' II "■ "■ interorbital space 17 Length *' long mandibular tooth 6 Width " interclavicle above 23 ^'' *' clavicle above (greatest) 19 Five abdominal scales in oblique line 10 Length of humerus 20 88 NEW PALEOZOIC VERTEBRATA. [Feb. 5, Measu7'einc7its. MM. Length of ulna 1 1 '' *^ first finger, total 15.5 " '' *' metacarpal 6.5 ** " '' phalange i 5 " " '' claw 4 The inequality of the lengths of the teeth with long ones anteri- orly and medially, is what is seen in the type of Colosteus, C. scutel- latiis Newb., and in Anisodexis Cope. The lower jaw of the spe- cies from Linton which I called A. efichodus is not longer than that of the present species, if as long; but it is much more robust, and the elongate teeth are much longer, relatively and absolutely. It may belong to the same genus. As compared with the Sauropleura (^Colosteus) scutellata, this species differs in having a median V-shaped series of abdominal scales, and in the more slender digits. From the two other species referred to Colosteus, on the strength of thoracic scuta, this species differs, in the rounded posterior out- line. In those species {C. foveatus and C. pauciradiahis) the pos- terior borders are sharply convergent to an obtuse angle. As compared with Sauropleura digiiata Cope, this species has relatively a much shorter forearm. In that species the ulna is five-sixths the length of the humerus, and the digits are less slender than in the S. latithorax. From the collection of Mr. R. D. Lacoe, to whom I owe the opportunity of studying the unique specimen. REPTILIA. IsODECTES PUNCTULATUS Copc, American Naturalist, 1896, p. 303 > Tuditanus punctulatus , Trans. Amer. F kilos. Soc, 1874; Geo I. Survey of Ohio, ii, 1874, p. 392, PI. xxxiv. Fig. r {Tuditanus longipes in explanation, by error). PL III, Fig. 3. A collection from Linton, Jefferson county, Ohio, obtained from. Mr. Samuel Houston, contains the greater part of the skeleton of what I suppose is this species. The head, scapular arch and one fore limb are lost. The remainder agrees very well with the typical specimen which was obtained by Dr. Newberry from the same locality and horizon. 1897.] NEW PALEOZOIC VEKTEBRATA. 89 There are eighteen dorsal and twenty-three caudal vertebrae, and parts or wholes of twenty-two dorsal and three caudal ribs, preserved. The vertebral bodies are amphiplatyan or amphicoelous, but which, is not readily determined. Where the centra are split, an indication of notochordal canal is visible, but the impression may be that of the external right face of the centrum, and not that of the cast of that canal. Most of the centra expose the left side, displaying low and contracted neural spines on the lumbar region, and none on the dorsal. There are two sizes of caudal centra, a longer and a shorter. Where these occur in pairs they might be supposed to be the halves of a divided centrum, such as occur in the Lacertilia, but several of them are single, and in place. No trace of chevrons is to be seen. The ribs are slender, not alate, and recurved. The caudal ribs are shorter and more strongly recurved. The sacrum and pelvis are too much obscured for description. The posterior limbs and feet are the most interesting part of this specimen. The femur is moderate, with expanded extremities, the distal divided by a popliteal groove. The tibia has the usual tri- angular head and contracted distal end, and has a straight shaft. The fibula is slightly curved, the interosseous border being strongly concave, and the distal end is oblique, and is wider than the proxi- mal. The tarsus includes but two elements in the proximal series, of which the internal (intermedium all or in part) articulates with both tibia and fibula. The fibulare is a little the larger, and has a longer distal articular border. Distad of these there are six ele- ments, one opposite each metatarsal, except the fifth, which has two. If we call the internal No. i, and the external No. 6, they are arranged in the order of size as follows, beginning with the smallest, 6-3-1-5-2-4. No. i is considerably proximad of the others, as is the case with some existing salamanders. No. 3 is separated from contact with the proximal elements, by the large No. 2, which thus has the position of centrale carpi ^ but which gives attachment to the second metacarpal. The subdiscoid No. 4 articulates with both astragalus and calcaneum, but most extensively with the calcaneum. This tarsus is quite regular, and every bone is in place. That of the opposite side is turned over on the leg, and the astragalus is missing. The posterior digits are long and slender, and of various lengths, although the metatarsals are of subequal length. The first and / 90 NEW PALEOZOIC VERTEBRATA. [Feb. 5, fifth digits are the only ones with all the phalanges preserved. These number two and four respectively, with a possible doubt as to the first digit. The other toes are represented by the following numbers of phalanges : second, 3; third, 3; fourth, 5. Enough remains of the manus to show that there were at least four digits, composed of segments rather shorter than those of the pes. Three carpals remain, perhaps centrale, and c. i and ii ; c. i is proximad to c. ii, and on the inner side of the centrale. As a result it appears that the tarsus is very different from that of the Pelycosauria. How nearly it approximates the other Cotylo- sauria it will be my object to show shortly. It is primitive and only lacks identity with the batrachian tarsus in the absence or fusion of the tibiale. Measurements. mm. Length of specimen 128 Expanse of ribs 18 Length of rib, on curve 14 *' *' centrum of fifth vertebra anterior to sacrum 4 Depth " do, with arch 4 Length *^ femur 15 Distal width of do 4 Length of tibia 7 Width "■ head of do 3 *' " distal end of fibula 3.5 '* " tarsus 6 Length " metatarsal iv 4.5 '' *' phalange i of digit iv 4 II II (( ii " *^ . -21; (( (( {( jjj (C i( ^ - ** *' digit V, with metatarsal 16 " " median caudal vertebra ... 3 This specimen is of importance as pertaining to the oldest known reptile, and the only one which has been thus far positively identi- fied from the Coal Measures. I announced this identification in the American Naturalist, 1896, p. 303. 1897.] NEW PALEOZOIC VERTEBRATA. 91 EXPLANATION OF PLATES. Plate L Scales ofSagenodus from the Coal Measures of Mazon Creek, Illinois, natural size. Fig. I. S.foltattcs Co'^Q XjT^Q', 2-3. S. reticulatus ^Qwh.] 4. S. conchiolepis Co^Q type; 5. S. lacovianus Cope type; 6. 6". quin- cunciaius Cope type; 7. 6". brownice Cope type; 8. S. magister Cope type; 9. S. gurleianus Cope type. Plate II. Figs. 1-3. Scales of Holoptychius, nat. size, except Fig. 2X2. Fig. I. H. serrulatus Cope type ; 2. H. latus Cope type; 3. H. flabellaius Cope type. Fig. 4. Sauropleura latithorax Cope type, natural size. Plate III. Fig. I. Ctenerpeton foveolatum Cope, from below, natural size; 2. Cer aterpeton te7tidcorne Co'^e, from above, natural size; 3. Iso- dectes punctulatus Cope, natural size. [The Secretaries deem it proper to state that when the proofs of the plates of this paper were taken to Prof. Cope he was too ill to examine them, and owing to his subsequent death they have been compelled to print the plates as drawn, without the benefit of his correction.] 92 MINUTES. [Feb. 5, Stated Meeting^ February 5, 1897. Vice-President, Dr. Pepper, in tlie Chair. Present, twenty -five members. A letter was received from Prof. Goldwin Smith, resigning membership in the Society. The resignation was accepted. The Standing Committees for the coming year, as ap- pointed by the President, under resolution of the Society, were then announced as follows : Finance. — William P. Tatham, William V. McKean, Philip C. Garrett. Hall. — J, Sergeant Price, William A. Ingham, Joseph M. Wilson. Publication. — Daniel G. Brinton, George li. Horn, Persifor Frazer, I. Minis Hays, Frederick Prime. Library. — Edwin J. Houston, Frederick Prime, AVilliam H. Greene, Albert H. Smyth, Thomas Hewson Bache. Michaux Legacy. — Thomas Meehan, William M. Tilghman, Angelo Heilprin, William Powell Wilson, Arthur E. Brown. Henry M. Phillips Prize Essay Fund. — William Y. Mc- Kean, Craig Biddle, Joseph C. Fraley, C. Stuart Patterson, Maj^er Sulzberger, the President, the Treasurer. Programme. — William Pepper, Persifor Frazer, William A. Ingham, Joseph C. Fraley, I. Minis Hays. The death was announced of Horatio Hale, of Clinton, Ont., December 29, 1896. Prof. E. D. Cope presented a paper on " New Paleozoic Yertebrata from Illinois, Ohio and Pennsylvania," which was read by title. The following papers constitute the discussion prepared for this meeting by those invited to present the various aspects of the subject selected, viz., " The Origin and Chemical Com- position of Petroleum." Prof. Sadtler read a paper on ' ' The Genesis and Chemical Relations of Petroleum and Natural Gas." 1897. PETROLEUM AND NATURAL GAS. 93 Prof. Peckliam, of Ann Arbor, read a paper on " The Nature and Origin of Petroleum." A communication from Mr. David T. Da)^-was read, en- titled "A Suggestion as to the Origin of Pennsylvania Petro- leum.'' The Secretary read by title two papers by Prof. Phillips on " The Genesis of Natural Gas and Petroleum," and on " The Occurrence of Petroleum in the Cavities of Fossils." Prof. Mabery then presented his views on the composition of Petroleum. Eemarks in discussion were then made by Dr. Sadtler, Mr. Wharton, Prof. Mabery and Prof. Peckham, and Prof. Ma- bery closed the discussion with a warm recognition of Dr. Sadtler's and Prof. Peckham's work. THE GENESIS AND CHEMICAL RELATIONS OF PETRO- LEUM AND NATURAL GAS. BY SAMUEL P. SADTLER, PH.D. {Read February 5, 1897.) Of natural products in the mineral kingdom, few have excited the interest of geologists and chemists in the same degree as what in the broad sense we call bitumen. Occurring as it does in solid, liquid and gaseous condition in almost all parts of the world, and in amount varying from the slight bituminous impregnation of shales, limestones, sandstones, and other rocks to the great petro- leum deposits which are now worked in this country and Russia, it has furnished ever-new and interesting material for scientific study and discussion. This widespread occurrence and the varied forms under which it is brought to our attention would be quite sufficient to explain its interest from a geological point of view, but when we add to this that in its main forms of production, petroleum and natural gas, chemists find represented those simplest forms of organic compounds, the hydrocarbons, we have an additional element of interest. 94 PETROLEUM AND NATUEAL GAS. [Feb. 5, Cinder these circumstances, it would be hard for the scientific student to refrain from theorizing as to the origin and conditions of formation and storage in nature of this great class of products. And if these theories already possessed interest in the earlier half of this century, might we not suppose that the great economic value which petroleum and natural gas have attained in the last few decades would add greatly to this? The question has indeed become a very large one, and the mass of literature pertaining thereto has already become so great that it would be impossible in the brief limit of time assigned me to cover it even in outline. Leaving therefore the broad subject of natural bitumens, it has been thought well to take for such discussion, as time allows, the narrower ques- tion of ^* the origin and chemical character of petroleum." And as the Society is honored this evening by the presence of several gentlemen who are known by contributions already made to this question, and have consented to favor us with papers specially pre- pared for this occasion, I shall merely state in brief outline the several well-known theories that have been advanced from time to time, and add an account of some experimental results that I have myself obtained which I think will have a bearing upon some of the views now held. The theories as to the origin of petroleum may be divided broadly into those which attribute it to Inorganic Sources and those which consider it to be derived from Organic Sources. Under the first of these heads, we may again distinguish between the theories which consider it merely as a natural emanation and those which attribute it to the result of definite chemical reactions. The first suggestion of the emanation theory for the origin of petroleum seems to have come from Alexander von Humboldt, who in 1804, in describing the petroleum springs in the Bay of Cumaux on the Venezuelan coast, throws out the suggestion that '^ the petro- leum is the product of a distillation from great depths and issues from the primitive rocks, beneath which the forces of all volcanic action lie." Rozet (1835), Prott (1846), Parran (1854), and There (1872), in writing upon the asphalt and petroleum occur- rences in France, all seemed inclined to connect these formations with volcanic, or at least igneous and eruptive, agencies. Somewhat similar was the theory advanced by the French geolo- gist Coquand, who, because of the association of mud volcanoes with the occurrence of petroleum in Sicily, the Apennines, the peninsula 1897.] PETROLEUM AND NATURAL GAS. 95 of Taman and the plains of Roumania, concluded that mud vol- canoes produced petroleum and other forms of bitumen by convert- ing marsh-gas into more condensed hydrocarbons. This deriva- tion of liquid and even solid bitumens like ozokerite from marsh- gas as an original source was also advanced as a theory by Grabow- ski, who has made special studies on Galician ozokerite. The simplest of the emanation theories, however, is that of the Russian geologist Sokoloff, who believes that petroleum is a cosmic product, formed in the crust of the earth as bitumens are formed in meteorites and comets by direct union of the elements hydrogen and carbon. According to this theory, the liquid and solid bitu- mens represent successive stages in the condensation and oxidation of simpler gaseous hydrocarbons. These emanation hypotheses do not find much acceptance at present. The connection between the petroleum occurrence and volcanic activity or hot springs seems to be far from general, and may indeed be classed as local and fortuitous; the oil does not issue from the earth at any higher temperature than that of the sur- face, as it might be expected to if connected with deep-seated vol- canic or cosmic activity ; and lastly, the most abundant oil deposits are not located in the regions where upheaval and fracture of the earth's crust show most strongly. More interest perhaps has been awakened by the theories of inor- ganic origin which involve definite chemical reactions. Foremost among these was that of Berthelot, who, in 1866, advanced the theory that the interior of the earth contained free alkali metals, and that these, when acted upon by carbonic acid or an earthy carbonate at high temperatures, would form acetylides or carbides of the alkali metals which decompose with water to form hydrocarbons analogous to those found in petroleum. If, then, water contain- ing carbonic acid gas were to reach these metallic masses by infiltration and act upon them at high heat and under pressure^ both liquid and gaseous hydrocarbons would result. The produc- tion of metallic carbides as a product of the electric furnace, and their ready decomposition for the production of acetylene gas, now carried out on a commercial scale, has added new interest to this theory of Berthelot's. This line of hypothesis was farther developed by Byasson in 1871, who obtained petroleum-like products by the action of steam and carbonic acid gas upon iron and its sulphide at a high tempera- ^6 PETKOLEUM AND NATUKAL GAS. [Feb. 5, ture. Cloez, in 1877, also obtained petroleum-like hydrocarbons by the action of dilute acids, and even of boiling water, upon the carbides of iron such as exist in spiegeleisen. In the paper of the Russian chemist Mendelejeff, however, published also in 1877, this theory is most fully elaborated. The existence of metallic carbides in the depths of the earth he considers likely from the fact that similar carbides are found in meteorites, and that metallic iron may occur in large deposits in the interior of the earth he considers possible, because the mean specific gravity of the earth, 5.5, is notably higher than that of ordinary rock material. If, then, water be supposed to have infiltrated through fissures in the earth's crust, we have the conditions shown by experiment as capable of yielding petroleum-like hydrocarbons. The same steam which, acting upon the metal or metallic carbide, was capable of forming the petroleum, could also force its vapors when formed through the fissures until on cooling they condensed and were absorbed in strata capable of holding them in liquid form. The eminent geologist Abich, who had made a study of the Caucasian oil field, also joined in the acceptance of this theory of Mendelejeff, and it may be said to be the one of the inorganic theories that has found the most general indorsement. The great preponderance of belief is, however, at the present time against this or any other theory based upon purely inorganic materials or reactions. The entire absence of petroleum from the archaic formations, from which traces of fossil life are also absent, and the occurrence of the petroleum in sedimentary formations which have been free from any volcanic or metamorphic disturb- ance, go to render these emanation theories improbable. The fact, moreover, that while the hydrocarbons of petroleum show a range of temperature of condensation from 0° to 300°, which would necessarily distribute them in different strata if they rose from the interior in vapor form, we find them all, from the highest to the lowest, admixed in one and the same oil-bearing formation, also speaks against the probability of the theories stated above. Turning now to the theories of the organic origin of petroleum, we note first the belief that it comes essentially from vegetable sources. Thus Prof. Lesquereux considered that the Pennsylvania oil was formed from the remains of marine algae, because the Devo- nian shales which accompany the oil formation contain an abund- ance of fossil fucoids. It is pointed out, however, by Hofer and 1897.] PETROLEUM AXD NATURAL GAS. 97 Other critics of this theory that in many localities fucoid remains are abundant without a trace of bituminous products accompanying them. E. W. Binney having observed petroleum oozing from a decom- posing bed of peat in England, which had been covered in with sand, considered that it came from a decomposition of the peat out of access of air. However, it has been pointed out that this was an isolated observation, and that in many other peat bogs similarly covered no evidence of petroleum has been found. Wall and Kruger, after studying the asphalt occurrence in the island of Trinidad, proposed the theory that asphalt and petroleum were formed by the decomposition of woody fibre, of which they found abundant traces in the asphalt deposits. A later observer, Rupert Jones, however, on extracting Trinidad asphalt with hot turpentine found animal remains so clearly that a derivation from these is at least as probable. We may mention also the earlier views of Reichenbach, who viewed petroleum as formed by a destructive distillation of vegeta- ble remains simultaneously with the formation of the coal deposits, but in answer to this it is only necessary to note that the petroleum and the coal do not occur together in the majority of instances and that petroleum differs essentially in chemical composition from either wood-tar or coal-tar as ordinarily obtained. The eminent French geologist, Daubree, also found a vegetable origin for petroleum. He says that '* it appears not to be a simple product of dry distillation, but to have been formed with the con- current action of water and perhaps under pressure." He adduces in support of his view the fact that by the action of superheated steam upon wood he had obtained both liquid and gaseous products analogous to petroleum. The belief in the animal origin of petroleum has had advocates equally as positive and persistent. In this country, J. D. Whitney, the former State Geologist of California, and T. Sterry Hunt, who was well acquainted with both the Canadian and Pennsylvania oil fields, were its chief advocates. The latter has produced many strong illustrations in his study of Canadian formations of his view that fossiliferous limestones, the remains in which are mainly if not exclusively of animal origin, were the original beds in which the petroleum was formed. In Europe, the most prominent advocates of the animal origin of ^8 PETROLEUM AND NATURAL GAS. [Feb. 5, petroleum have been Hofer and Engler. The former of these writers in his work, Das Erdoel und seine Verwandten, published in 1888, summarizes the arguments for believing petroleum to be of animal origin as follows : 1. We find petroleum in original deposits with animal remains, but not or with only the smallest traces of vegetable remains, as for -example in the fish shales of Carpathia and the limestones of Can- ada studied by T. Sterry Hunt. 2. Shales which, on account of their high per cent, of bitumen, are adapted for the production of oil or paraffine, are also rich in animal and poor or entirely void of vegetable remains, as for example the bituminous shales of the Lias formation in Swabia and Steierdorf (Banat). The copper-bearing shales of Mansfield, which contain as high as twenty-two per cent, of bituminous matter, also carry an abundance of animal remains, but only very rarely any vegetable remains. 3. Rocks which are rich in vegetable remains as a rule are not bituminous, but they become so if animal remains accompany the other. 4. By the decomposition of animal remains it is possible to form hydrocarbons analogous to those of petroleum oils. 5. O. Fraas observed petroleum oozing from a coral bank on the borders of the Red Sea, where it could only have had an animal origin. The fact that origin from animal remains makes it necessary to account for the nitrogen, is met by the fact that most asphalts and bitumens, including petroleum, do contain nitrogen. That they do not contain more is explained, according to Hofer, by the circum- stance that the nitrogen is lost in volatile compounds like ammonia. Of course animal remains are found in many formations that do not contain bitumen or petroleum, but the conditions may have been unfavorable for its accumulation and retention in these cases. The actual formation of petroleum-like compounds from animal pro- ducts had been carried out experimentally some years before Hofer' s publication, by our countrymen, Warren and Storer, who distilled the lime soap of menhaden (fish) oil, and obtained mem- bers of the methane, ethylene and benzene series of hydrocarbons, such as are found in petroleum. However, Hofer' s theory was taken up as the suggestion for experimental study by Engler, of Carlsruhe, and at his hands it 1897.] PETROLEUM AND NATURAL GAS. 99 has received a more definite statement. Engler distilled 490 kilos, of menhaden oil at a temperature beginning at 320° C. under a pressure of ten atmospheres, and increasing to 400° under a pressure of four atmospheres. He obtained about sixty per cent, of an oil distillate of 0.815 specific gravity. Thirty- seven per cent, of the distillate was taken out by shaking with sulphuric acid, indicating unsaturated hydrocarbons, while the remainder yielded, on fractional distillation, pentane, hexane, normal and secondary hexane, normal octane and nonane. A burning oil fraction was separated, and in his latest experiments solid paraffine was also obtained from the heavier portions. Prof. Engler gave a resume of his experimental results at the World's Fair Congress of Chemists, in Chicago, in August, 1893, and I had the pleasure of hearing it and examining his specimens at that time. In consequence of this work of Engler, which he extended later to lard oil as well as to menhaden oil, and to artificial tri-oleines as well, the belief in the animal origin of petroleum has become quite the prevalent one. Let us, however, take up for a moment the idea of the joint ani- mal and vegetable source. This joint origin was advocated first of all by Prof. J. P. Lesley, the Director of the Second Geological Survey of Pennsylvania, and an honored Vice-President of this Society. He believes that ''it is in some way connected with the vastly abundant accumulations of Paleozoic sea weeds, the marks of which are so infinitely numerous in the rocks, and with the infini- tude of coralloid sea animals, the skeletons of which make up a large part of the limestone formations which lie several thousand feet beneath the Venango oil-sand group. ' ' The same view was held by the late C. A. Ashburner, of the Pennsylvania Geological Survey. Prof. Edward Orton, of the Ohio Survey, summarizes his views in the following postulates: (i) Petroleum is derived from organic matter; (2) Petroleum of the Pennsylvania type is derived from the organic matter of the bituminous shales and is probably of vege- table origin ; (3) Petroleum of the Canada type is derived from limestones and is probably of animal origin. Prof. Peckham, in his report on Petroleum for the Census of 1880, also makes a distinction in the origin of different classes of petroleums. He divides all bitumens into four classes : I. Those bitumens that form asphaltum and do not contain par- affine. 100 PETROLEUM AXD NATURAL GAS. [Feb. 5, 2. Those bitumens that do not form asphaltum and contain par- affine. 3. Those bitumens that form asphaltum and contain paraffine. 4. Solid bitumens that were originally solid when cold or at ordinary temperatures. '* The first class includes the bitumens of California and Texas, doubtless indigenous in the shales from which they issue. The exceedingly unstable character of these petroleums, considered in connection with the amount of nitrogen that they contain and the vast accumulation of animal remains in the strata from which they issue, together with the fact that the fresh oil soon becomes filled with the larvae of insects to such an extent that pools of petroleum become pools of maggots, all lend support to the theory that the oils are of animal origin. ''The second class of petroleums include those of New York,. Pennsylvania, Ohio and West Virginia. These oils are undoubtedly distillates and of vegetable origin. The proof of the statement seems overwhelming." Leaving the question of origin for the present with this rapid survey of the views of the more prominent writers on the subject, and reserving for the end of this paper the mention of some few experimental results of my own which bear on it, I will briefly allude to the other question of the conditions of formation of the bitumen or petroleum. Here of course we practically leave the theories of inorganic origin to one side and assume that its source is organic. Was it formed where it is now found in situ or is it a distillate from lower-lying formations ? As already stated, Sterry Hunt believed that the fossiliferous lime- stones were the source of the Canadian oil, and he also strenuously insisted that they were formed in this same formation and did not come into it from an outside source. This view of the production of the petroleum i?i situ is also in the main supported by Profs. Lesley and Orton, although both seem to admit that under some circumstances a modified distillation takes place. The latter says : *' Different fields have different sources. We can accept without inconsistency the adventitious origin of the oil in Pennsylvania sandstones and its indigenous origin in the shales of California or ia the limestones of Canada, Kentucky or Ohio." On the other hand,. Profs. Newberry and Peckham have advocated the theory that the oils of New York, Pennsylvania, West Virginia and Ohio at least 1897.] PETROLEUM AND NATURAL GAS. 101 were products of a slow fractional distillation. Prof. Newberry speaks of black Devonian shales as the source of supply in this pro- cess, while Prof. Peckham takes in both beds of shale and limestone containing fucoids and animal remains as subjected to the distilla- tion process. In concluding, I have a small contribution to offer to the experi- mental data which bear upon the question of possible origin, and upon which we can theorize as to conditions of formation. Engler, as already mentioned, distilled menhaden oil under pressure, and afterwards extended his experiments to lard oil and artificial oleins. From his results he is led to believe in the exclusively animal origin of petroleum. I have found that linseed oil, and presumably the other vegetable seed oils, may be made to yield similar products, and have even obtained solid paraffine from this source. While it has long been known that inflammable vapors are given off when linseed oil is boiled for varnish making and similar purposes, very little attempt has been made to collect and study the composition of these vapors. Schaedler, in his exhaustive work on the vegetable and animal oils, simply makes the statement that small quantities of hydrocarbons are present in the vapors resulting from this destructive distillation. Finding that in one case that came under my attention linseed oil was being boiled for varnish making under pressure, and that considerable quantities of a liquid distillate were being condensed in the dome of the large still and returned to the body of the oil, I arranged for the collection of these condensed vapors and col- lected them for examination. At first the odor of acrolein was very pronounced and powerful, showing that the glycerine of the glycerides composing the oil was being decomposed ; later the odor was more that of a cracked petroleum oil, showing that the linoleic and other acids of the oil were undergoing decomposition. The raw distillate collected after this acrolein odor had nearly disappeared, I found had a specific gravity of 0.860 and had changed so thoroughly from the original linseed oil that it showed a saponification equivalent of only 1.09, indicating that it was mainly a neutral oil and presumably made up largely of hydrocarbons. I might say here that I examined the linseed oil which was used in this test. It was a clear " old pro- cess " oil, of specific gravity 0.929, and showed a saponification equivalent of 183, which is normal for linseed oil. PROC. AMER. PHILOS. SOC. XXXYI. 154. 11. PRINTED MAT 21, 1897. 102 PETKOLEUM AND NATUKAL GAS. [Feb. 5, The distillate above referred to was then redistilled from a small iron retort and two fractions collected, leaving a residue in the retort which had the appearance and odor of a reduced petroleum oil or residuum, such as is used in the. manufacture of vaseline and similar products. The two fractions were found to resemble what are known as paraffine oils in considerable degree, showing the characteristic fluorescence of these. They were given a partial treatment with sulphuric acid and the results are shown. From a portion of one of these fractions, on chilling in a freezing mixture, scale paraffine was also separated, of which a sample is shown. Of course the frac- tions must be obtained on a sufficiently large scale to admit of thorough purifying before the character of the hydrocarbons can be studied. At present they contain impurities such as aldehyde-like and possibly ketone products. They reduce ammoniacal silver solu- tions and indicate thus the presence of these impurities. These results, which of course are only preliminary, are sufficient to show that we have hydrocarbon oils analogous to the natural petroleum or mineral oils formed when linseed oil is distilled under pressure. It is difficult then to see how we can avoid widening Engler's theory so as to include the vegetable seed oils as probable additional sources of petroleum. Moreover, I see no reason, if lard oil will yield the results which Engler has obtained, to doubt that vegetable oleins like olive oil and its class may also be found to be capable of the same changes. We are thus brought from an experimental point of view to come to the acceptance of the theory of the joint animal and vegetable origin of petroleum that the majority of geologists have settled upon as according best with their study of its local occurrence. 1897.1 NATURE AND ORIGIN OF PETROLEUM. 103 ON THE NATURE AND ORIGIN OF PETROLEUM., BY S, F. PECKHAM. {Read Fehruary 5, 1S97.) Concerning the nature and origin of petroleum, I think we may- say, after forty years of study and discussion, that we have not yet learned its alphabet with certainty. As petroleum is one of the forms of bitumen, in the line from natural gas to asphaltum, I do not think it has an origin independently of the other forms, and I shall therefore discuss the origin of bitumens together, as including petroleum. Since I indulged my '' Retrospect," ^ two years ago last summer, two works have appeared which notably discuss the origin of bitu- mens, and I have in the course of my investigation of asphaltums and California petroleum, during the same period, noted a number of facts that bear upon the solution of this problem. In closing the ''Retrospect" that I wrote while in southern California, and which was in part a reply to criticisms made by our friend. Prof. Orton, I remarked that I did not consider it necessary to represent in terms of Fahrenheit's thermometer the temperature at which any given specimen of petroleum was produced nor to produce the coke that resulted from the distillation. On reading over the paper since it appeared in print, I have feared that perhaps it had impressed some readers as dogmatic or as begging the question. It is some- times difficult to express deep convictions with enthusiasm and not at the same time appear dogmatic. The Devonian shales, where they outcrop at Erie, Pa., have not apparently been subjected to alteration ] yet, a number of wells drilled into them, have yielded an oil somewhat dense and of a bright green color. I believe that that oil was a product of distillation at a low temperature and under comparatively little pressure, the heat required being generated spontaneously within the shales. In Ventura county, southern California, metamorphism, that has resulted from sOme sort of action that has generated heat, has left masses of originally highly bituminous shale not only void of volatile matter but void of carbon as well. The expulsion of carbon is complete. The tem- perature must have been adequate, be the source of heat whatever ^ Am. Jour. Science (3), xlviii, 389 ; Nov., 1894. 104 NATURE AND ORIGIN OF PETROLEUM. [Feb. 5, it may, yet there is no coke and no evidence that the temperature approached that of a brick kihi, nor such a temperature as in the ordinary processes of technology is found necessary to produce similar changes within periods of time upon which such processes are contingent. It was in the midst of such phenomena as I have just described and in the light of these facts that I then asserted that we cannot '' reason from the processes of technology, bounded as they are by time and space, to the infinity of nature which it is impossible to imitate;" meaning that such reasoning cannot be applied to details. A book was published in 1895, of which the eminent Swiss geol- ogist, M. August Jaccard, was the author. The fact that it was a posthumous work leads one to pass lightly over mere blemishes of manner and style, and to note only those errors of judgment which led the author to erroneous conclusions. The book manifests a wide range of reading within the limits of publications in the French language, which has made it necessary that the author should con- fine himself to translations of the many memoirs that have appeared by English and American authors, and while the notices of such authors are frequently inadequate, few, if any, are omitted. M. Jaccard passes in review all of the different theories that have been proposed as a possible explanation of the phenomena observed in relation to the occurrence of bitumens in the Upper Valley of the Rhone, and discards all of those that regard bitumen as resulting from any cause or causes other than the alteration of animal remains by a special process of bituminization that has converted the organic matter directly into bitumen. He says, *' distillation is an hypoth- esis absolutely destitute of proof" (p. no), and, referring to the views of MM. Daubrae, Lartet and Coquand, he says further that *' Their error consists in the fact of having confounded the forma- tion of bitumen with the phenomena of its appearance {reappari- tion) at the surface which is posterior to it." M. Jaccard then proceeds to set forth a system of nomenclature of his own and says, *'It is in vain to wish to attempt a rational and systematic classification of natural hydrocarbons, solid and liquid and gaseous. It is in vain to set forth the multiplicity of names that have been applied to them by different authors. The expressions naphtha, petroleum, maltha, glutinous, viscous or solid bitumen, asphalt or pisasphalt, etc., are employed concurrently and without determined reasons. Their state, whether solid, liquid or 1897.J XATURE AXD ORIGIN" OF PETROLEUM. 105 gaseous, often depends upon the temperature at which they are at the moment when they are observed Petroleum becomes solid when it has lost its light oils by exposure. They designate as asphalte a calcareous rock impregnated with bitumen, whilst if it be mixed with sand or gravel they apply the term petroleum " (P- 113)- ''In presence of this uncertainty, it has appeared to me prefer- able to proceed to the study of the deposits by groups, and to adopt thus a purely methodical system. '' To this end I have established the four following groups : '* I. The asphaltic and bituminous deposits. ''2. The bituminous schists. '' 3. The petroliferous and bituminous deposits. " 4. The natural combustible gas." He then proceeds to discuss the subject along these inadequate and purely artificial lines, which time will not permit me to analyze in detail. It is sufficient for my purpose to say, that he concludes that bitumens have been produced in every case by a special decom- position of animal matter at the points where they are now found. He thinks that because the bituminous limestones of Seyssel and Val de Travers are intercalated between beds of barren rock that the bitumen must have been formed i7i situ. That is by no means a necessary conclusion. The bitumen in a state of vapor, and probably accompanied by steam, expanded into the porous beds laterally, while passing through fissures in the compact and barren beds. When the Seyssel rock has been exhausted of its bitumen by chloroform and is examined under a microscope, it is found to be an amorphous mass of coarse-grained chalk with the finest parti- cles one ten thousandth to one twenty thousandth of an inch in thickness — so fine that they pass through fine filter paper. Any one familiar with the sea-shore has found shells of the com- mon clam {cardtiivi) filled with sand and saturated with the pro- ducts of the decomposition of the soft parts of the bivalve dissolved in water. It is not an infrequent occurrence in regions where bitu- men is abundant upon sea-coasts to find the shells of such bivalves filled with sand saturated with bitumen. The carbon contained in the solid or semi-solid bitumen required to saturate the dry sand that fills such shells is many times that found in the dried soft parts of the animal that occupied the shell. Such shells are common on and near the coasts of southern California. T^I. Jaccard calls atten- 106 NATURE AND ORIGIN" OF PETROLEUM. [Feb. 5, tion to such shells as occurring in various places, but especially in the Val de Travers and its neighborhood, and seems to think they offer convincing proof that the bitumen originated where it is now found. Such an argument would never occur to one familiar with the sea-shore. The shells are first filled with sand and then satu- rated with bitumen, which enters them either as a liquid or hot vapor. I have seen multitudes of shells filled with bitumen and mixed with sand, fragments of shells, dirt, and crystallized carbon- ate of lime, none of which are a part of the animal that occupied the shell. The second work to which I refer is the late monumental publi- cation by Boverton Redwood, on Petroleum. After the most com- plete and wholly fair as well as the latest i-esunie of all the theories that have been advanced by the writers of both Europe and Amer- ica, he sums up as follows : " From the account given in this section, it will be seen that there has been an abundance of speculation as to the origin of bitu- men and that, in regard to some of the theories, a considerable amount of experimental proof has been forthcoming. Probably, on the whole, the Hofer-Engler views at present have the largest number of adherents, and in respect, at any rate, to certain descrip- tions of petroleum, are the most worthy of acceptance. At the same time, a careful study of the subject leads to the conclusion that some petroleum is of vegetable origin, and it therefore follows that no theory is applicable in all cases." Engler, like Warren, distilled fish oil and obtained petroleum- like products. He then distilled dried fish and other animal remains, and obtained altogether different products. " Dr. Engler therefore considers that some change in the animal remains must have taken place in the earth, whereby all nitrogenous and other matters, save fats, were removed, the petroleum being formed from this fat alone, by the combined action of pressure and heat or by pressure only. "In summing up the evidence as to origin, Hofer expresses the belief that petroleum is of animal origin, and has been formed without the action of excessive heat, and observes that it is found in all strata in which animal remains had been discovered." Combining these two statements, we arrive at this conclusion as the Hofer-Engler theory, that bitumens are of animal origin, formed 1897.] NATURE AND ORIGIN OF PETROLEUM. 107 at low temperatures from fats alone by the combined action of pressure and heat. Steam is left out of this formula and it is therefore inadequate. There is no evidence whatever that any portion of the crust of the earth has ever been subjected to the combined action of heat and pressure without the presence of steam or hot water, and in my judgment the steam has been a very potent factor in determining not only the formation but the transference of bitumens. I have been many times told that the Turrellite of Texas consists of a mass of loose shells cemented together with bitumen. As it had that appearance, I never questioned the statement, until lately I had occasion to examine a specimen of this mineral. I pulver- ized some of it and proceeded to analyze it by solvents. I found that a portion of the mineral matter passed through fine filter paper. I then digested a piece of it in successive portions of chloroform, until the chloroform was no longer colored. There remained a white shell-rock, or coquina, quite firm and strong, very light in weight, with the cavities of some of the shells partly filled with crystallized rhomb-spar; together with fragments of shells and dust. Under the microscope some of the dust was only one twenty thousandth of an inch in thickness. The shells had been subjected to the action of hot water after all traces of the soft parts of the animals had disappeared and a part of the lime had been dissolved and redeposited in the cavities of the shells and between them, thus cementing them together ; and this anterior to the entrance of the bitumen, which must have filled the shell-limestone as a vapor or in a fluid or semi-fluid condition. When separated from the shells the bitumen is very pure and uniform in its composition, containing many times the amount of carbon that existed in the soft parts of the animals that made the shells > their home. The porous shell-rock simply aff'orded an adequate receptacle for the bitumen that was distilled or sublimed into it. I have lately examined California petroleums more closely than I ever had before. I have distilled off the lightest portion from some Wheeler's Canon green oil that I took from the Canon in 1866. I also distilled about fifty per cent. — the lightest portion — from some Pico Canon oil that I got from there two years ago. While in Cali- fornia in the fall of 1894, I distilled from several samples of black oil, taken from wells in the Sespe and Torrey Canons and near Bards- dale, about twenty-three per cent, of the lightest portion. The distil- 108 NATURE AND OEIGIN OF PETROLEUM. [Feb. 5,. lation was conducted in a common tubulated glass retort with a ther- mometer introduced into the tubulure in such a manner as to indicate the temperature at which the condensing vapor passed over. This was the first time I had ever distilled these oils in such an apparatus, and some of the results observed were exceedingly interesting. The crude oils contained a little water, as all petroleums do, which came over with the light distillate, at or below ioo° C. As the boiling point of the oil and the temperature of the condensing vapor arose, at i2o°-i4o° C, water again appeared. The two portions of water distilled over at temperatures separated by at least 30° C. The last portion appeared, in part, as an emulsion that collected in white drops upon the neck of the retort, and, gathering, ran through the condenser to the receiver, where it fell through the column of oil and collected as water at the bottom of the receiver. On standing twelve hours, small spots and patches in the neck of the- retort appeared of a purple color, and a deposit that resembled argol appeared as a precipitate in small quantity at the point of contact between the oil and water in the receiver. While an appreciable amount of this precipitate appeared in the distillate from the black oil, only a trace was present in the distillates from the oils from the Pico and Wheeler's Canons. With sulphuric acid, followed by so- dium hydrate, this precipitate gave a qualitative reaction for one of the esters of the pyridin bases ; that is to say, dilute sulphuric acid dissolved a part of it, leaving a purple residue, and from the sul- phuric acid solution sodium hydrate precipitated white flakes hav- ing the odor of pyridin. The distillates also gave the usual reac- tion for these esters in small quantities. Fractionated in a bulb ap- paratus with beads, the distillate from black oil has yielded " heaps" corresponding to the boiling points of the benzoles and naphthenes. This work is still incomplete. The facts of greatest interest, however, in reference to these oils, that this latest work has demonstrated, relates to their sulphur content. An observation that I made many years ago has been often quoted, that in one instance I distilled a California oil that contained so much sulphur that the sulphur condensed in the neck, of the retort. As I remember the experiment, the amount of oil distilled was about half a litre ; and a button of pure sulphur con- densed in the neck of the retort at least half a centimeter in diameter. This oil was from the Canada Larga spring, which issues from strata containing a large amount of free sulphur. I have never seen an- 1897.1 NATURE AND ORIGIN OF PETROLEUM. 109 Other California oil from which this experiment could be repeated > and I have long since concluded that the sulphur was in this instance dissolved in the oil. While in California a few years ago, I was engaged in distilling these petroleums in quantities ranging from a few gallons to thou- sands of barrels. I looked in vain for any evidence that they were sulphur petfroleums. It was only after I had begun fractioning the light oils — a work for which I had not the proper appliances in California — that I began to suspect that there were sulphur com- pounds present, and at last discovered that, with the thermometer bulb immersed in the condensing vapor, even at a temperature as low as 1 00° C, the distillates were decomposed and hydrogen sul- phide disengaged. This decomposition of the oil was accompanied by a deposition in the flask of carbon, or a compound so rich in car- bon that it remained undissolved in either the distillate or residual oil, and also by condensation of the residual molecule, as indicated by a continual rise in the boiling point of the oil remaining in the flask. These observations have led me to conclude that sulphur as well as nitrogen plays a part in the changes which are active in the nat- ural conversion of petroleum, through maltha, into asphaltum. That the esters exist as acid salts of the basic oils is quite probable ; that polymerization of the molecules occurs to some extent cannot be doubted ; that decomposition of the sulphur compounds takes place very slowly and at comparatively low temperatures with con- densation of the residual molecules is almost certain ; and that re- moval of hydrogen in the oil through deoxidation of the sulphates in the water with which the bitumens are in constant contact, with substitution of sulphur, may all be accepted as the prime factors of the problem involved in these changes. The lines of investigation above indicated have led me to some very interesting work upon the sulphur content of other bitumens than petroleum, which work is as yet incomplete. Closely related to these factors are some observations made dur- ing my last visit to California. It was noticed that when the oils conveyed through pipe lines were distilled in summer, the yield of naphtha was much less than was obtained from the same oils in winter, although the extremes of temperature were not great. Upon investigation I found that in October, 1894, the oil, flowing through the blackened pipes laid upon the surface, was discharged 110 NATURE AXD ORIGIN OF PETROLEUM. [Feb. 5, into the tanks at a temperature of 90° F. I also found that an oil fresh from a well, kept in an open vessel at a temperature of about 100° F. for four days, ceased to lose weight and decreased in vol- ume twenty-five per cent. In another experiment, one litre of oil was exposed to the sun in a pan placed in a window seat for three days. The temperature was at no time above 90° F., and over half of the time was below 70° F. The loss was twenty per cent, by volume, and the specific gravity changed from 28.5° B to 20.2° B. These re- sults show that at the surface, natural evaporation is also a potent factor in the conversion of petroleum into maltha and asphaltum. I wish to note here several facts of a different order bearing upon these questions. In 1865-6 the carcasses of several whales were ly- ing half buried in the sand of the Pacific coast, between Point Con- ception and Ventura, California. They furnished food for numer- ous vultures and buzzards, and while the odor was not agreeable, it was the odor of rancid fat rather than of putrid flesh. During the summer of 1894 a vast number, weighing many tons, of deep sea fish, in a dying condition, came ashore upon that same coast for at least two hundred miles. Many of these fish were of large size, and among other species was a basking shark, twenty-six feet in length. An examination by one of the officers of the State Fish Commission led to the discovery that the gills of these fish were more or less filled with bitumen, which constantly rises from the bed of the ocean ■off this coast. The destruction of animal life was enormous. The first gale with a high tide buried nearly all of the fish in the sand of the beach. Complete skeletons of whales have been repeatedly discovered in the petroleum-bearing strata of that region, some of them saturated with bitumen. One hundred miles due north of this coast, on the other side of the Coast Ranges, I have examined some of the most extensive veins of asphaltum yet discovered. They have been traced across the country continuously for miles and have been mined to a depth of more than three hundred feet. In chemical composition the asphaltum bears a specific relation to the petroleums of Ventura county. They both contain the esters of the pyridin bases. These asphaltum veins lie on one side of and irregularly parallel with a stratum of sand- stone, which, like all of the strata of that region, stands nearly vertical. Along this sandstone stratum bitumen exudes for a long distance. Against it, and on the other side of it, rests a bed of infusorial earth, at least 1000 feet in thickness, in some places satu- 1897.] NATURE AND ORIGIN OF PETROLEUM. Ill rated with bitumen, but for the most part clean and white. These formations extend across the country, parallel for miles with the general trend of the Coast Ranges. Enormous springs of maltha, issuing therefrom at intervals, have produced at several points flood-plains of asphaltum that fill the small valleys like a glacier, many feet in depth and square miles in extent. The maltha is in- variably accompanied with water, and at several points there are evidences that at some period in the past history of those outflows the springs that are now cold have been gigantic hot springs of sili- cated water, similar to those that I believe produced the famous Pitch Lake of Trinidad. I went to Trinidad prepared to find abundant evidence of the direct conversion of wood into bitumen, as described by Wall and Sawkins. I saw nothing of the kind ; nor could I find any one else who had. A superstition among the natives ascribes to the black mangrove the power of secreting bitumen. This shrub grows with its roots in sea water and often covered with oysters. The move- ment of the tide, the most nearly eternal phenomenon in nature, bears the bitumen that rises from the bottom of the sea against the oyster shells, and their jagged edges gather the floating particles. The entire deposit of pitch, both within and without the lake, contains on an average ten per cent, of partially decayed vegeta- tion, and also an amount, difficult to estimate, of branches, trunks and stumps of trees, some of the latter of enormous size, much larger than any now standing in the vicinity. I did not see the outcrop of the lignite bed to the south of the lake that dips at an angle that would send it under the lake, as described by Manross, but I was told by one who had seen it, that this lignite bed, twelve feet in thickness, contained branches, trunks and stumps of trees that were in exactly the same condition as those found in the pitch — that is, they were still wood — not having been changed into lig- nite, and therefore not capable of being distilled by hot silicated water into pitch. The circumstances of my life have brought me into personal con- tact with deposits of bitumen over a very wide area, and under such conditions as have afforded me very unusual opportunities for a careful study of all the phenomena attending the appearance of bitumen at the surface of the earth ; the result of which has been to confirm the opinion that I have heretofore expressed, that, in the majority of instances, bitumens, from natural gas to asphaltum. 112 ORIGIN OF PENNSYLVANIA PETROLEU^E. TFeb. 5, are, where we now find them, distillates. In making this declara- tion I do not wish to be understood as calling in question the cor- rectness of either the observations or opinions of those who have reached different conclusions. Perhaps fifty years from now our ghosts may sit here with our grandchildren and hear them dogmatize concerning the origin of bitumen. For myself, the longer I study the subject and the wider my experience becomes, the less I am prepared to assert that any formula is capable of universal application. I would therefore suggest, that, as we now find them, bitumens are in some instances Still where they were originally produced by a process of decompo- sition of animal remains, that is at present being illustrated on a small scale in the shallow bays of the Red Sea. Further, that other deposits contain primary distillates from the vegetable and animal remains enclosed in geological formations that have been invaded by heat, steam and pressure in past periods of the earth's history ; and finally, that in some instances, as we now know them, bitumens have been transferred and stored by a secondary invasion of bituminous deposits by heat, steam and pressure. The details of these various movements await for their expression a vast amount of chemical and geological research by those who are to come after us. A SUGGESTION AS TO THE ORIGIN OF PENNSYL- VANIA PETROLEUM. BY DAVID T. DAY, {Read February 5, IS 97.) The three general classes of theories as to the origin of petro- leum are so well known as to call for no especial description. I refer to (i) the inorganic origin by the action of water on metallic carbides ; (2) by the slow decomposition of vegetable remains with insufficient supply of air, with or without simultaneous production of coal ; and (3) the distillation of the fatty portion of anima organisms under pressure, in accordance with the discoveries gener- ally credited to Engler. It is pleasant, however, to recall attention to the fact, which has frequently been lost sight of, that Warren and Storer first distilled petroleum from animal fats years before ; that is by the distillation 1897.] ORIGIX OF PEXXSYLVAXIA PETROLEUM!. 113 of menhaden oil soaps under pressure they made good kerosene and actually sold the product — an achievement remarkable for the time at which it was done and gratifying to us as the work of American investigators and far in advance of any similar work abroad. The work of the German chemist, Engler, is thus simply confirmatory, and in extension, of what had been already done in this country. Concerning these theories of origin, it seems to me extremely probable that the conditions required for the production of bitu- mens by inorganic means must have occurred repeatedly in the earth's crust, and that, therefore, bitumens have been formed by such means. The evidence of the actual occurrence of bitumens produced from inorganic sources is not complete, but in addition to the bitumens occurring in trap rock in eastern New York and Connecticut, it is well to call attention to the fact that water asso- ciated with the Trinidad asphaltum has been shown by Mr. Clifford Richardson to contain significant amounts of boracic acid com- pounds, which is some evidence of volcanic origin. Again, bitu- mens occur in the vein quartz of quicksilver deposits in various parts of the world, and such occurrences are frequent in California. If we take into consideration the organic life available for yield- ing petroleum, it seems easier to believe that the supply of oils found in the Silurian limestones has come from the distillation of fats associated with animal remains, than that they were derived from vegetable matter. On the other hand, general opinion tends to associate the Penn- sylvania oils with a vegetable source, and it is against this that I wish to make a few suggestions, based upon the observations of Rev. John N. MacGonigle, formerly a stratigrapher in the employ of the Forest Oil Co. Mr. MacGonigle's opinion is that the Pennsylvania oils were originally contained in the Silurian measures, as are the Ohio oils, and that a redistillation, accompanied by a transfer to rocks of the Devonian age, resulted in a change of the character of the oils. In his own words, as written to me, ]\Ir. MacGonigle states : '^ It may be admitted that the marvelous deposits found in the Trenton and Clinton limestones and widely diffused in the other limestones and shales of the Silurian period are indigenous. It is a well-known fact that the series constituting the Silurian age, as the result of one of nature's wonderful convulsions, sweeps toward the eastward under the Devonian and Carboniferous areas, forming 114 ORIGIN" OF PENNSYLVANIA PETROLEUM. [Feb. 5, the floor of the basin in which the measures of these periods were deposited. The uplift which forms the Appalachian chain occurred at the close of the Carboniferous period. This was due directly to heat action. It is, therefore, at least suggested that the petroleums of Pennsylvania owe their origin to the effect of this heat upon the underlying limestones and shales of the Silurian age. The theory is, that the same force which caused the Appalachian chain to uplift, passing through the limestones and shales of the Silurian age at a modified temperature, distilled the oil already contained in these shales and conglomerate sands of the Devonian age, where it was condensed and filtered and found its home in the open, porous conglomerates which characterize the Catskill, Portage and Chemung periods of the Devonian age. ^' There are many reasons why this theory seems to be more satis- factory, to me, than any of the others. In the first place, the pecu- liar characteristic of the Silurian oil is its well-known sulphur com- pound, which for many years presented almost insurmountable difficulty to the refiner. The low specific gravity is its second characteristic quality, and a uniform quality marks it everywhere. In the oils of the Pennsylvania region and the Devonian horizon we have a range of color from light amber to black, a higher spe- cific gravity and almost entire freedom from sulphur compounds. '' In addition to what has been said with reference to the Silurian period, it may also be added that at its top lies the Corniferous limestone, which is the source of the petroleum of western Canada. This limestone has been reached by the drill in Pennsylvania in the well at Erie and at the Conway well, which, piercing the Venango- Butler group, reaches the Corniferous limestone. In neither case was any trace of oil discovered in the Canadian measure. In addi- tion to the varieties of color and specific gravity, together with the freedom from sulphur which characterizes the Pennsylvania petro- leums and indicates the process of filtering, it is also extremely doubtful whether the measures of the Devonian age and particularly those in which the Pennsylvania petroleums are deposited, ever con- tained any life which could have given rise to the petroleum. It is generally conceded that the great volume of the oil which is found in the Trenton and Clinton limestones is due to chemical action upon the organic life of that period. The experience which has been the result of many years of drilling in Pennsylvania has failed to discover any evidence of organic life in the period in which the 1897.] ORIGIN OF PENNSYLVANIA PETROLEUM. 115 Pennsylvania measures were deposited that even suggest^a sufficient source for the great bodies of petroleum which have already been brought to the surface in that region." In a communication received from Mr. MacGonigle to-day he calls attention to the fact that a line drawn from Brady's Bend to Waynesborough, Pa., will show the eastern limit of profitable oil pools in that region. East of that line, however, some of the most prolific gas pools of Pennsylvania have been developed, notably, Murrysville, Grapeville, Latrobe, etc. This would at least suggest a side light in favor of the theory above mentioned, showing that as the area approached the line of greatest upheaval and conse- quently greatest temperature, the volatile oil (gasj was, without condensation, retained in its condition as it came up from Silurian horizons. I believe that this theory of Mr. MacGonigle is more probable than any that has been advanced as to the present condition of oil in Pennsylvania. It does not seem, however, necessary to intro- duce the idea of any redistillation whatever from the fact that if sufficient cracks existed in the cover over the Silurian limestones, the oils would leak through the shales to their present position with- out the application of any heat, and by experimental work it may easily be demonstrated that if we saturate a limestone such as the Trenton limestone with the oils characteristic of that rock and exert slight pressure upon it, so that it may flow upward through finely divided clay, it is easy to change it in its color to oils similar in appearance to the Pennsylvania oils, the oil which first filters through being lightest in color and the following oils growing darker. Further, if we examine oils in the new fields of Tennessee and Kentucky, we find as we go lower that oils which were light in color at the surface are dark in color when we go through the shales and find them in the lower limestones. In fact it is possible to watch the process of filtration from dark oils similar to the Ohio sulphur-bearing oils to the lighter oils of Pennsylvania found nearer the surface. The means by which the sulphur has been taken from the Ohio oil is far more difficult to explain, although the ease by which sulphur compounds and unsaturated compounds can be re- moved from petroleum by the use of aluminum chloride points to the chloride of some metal as a means by Avhich this may have been accomplished. 116 GENESIS OF NATURAL GAS AND PETROLEUM. [Feb. 5, ON THE GENESIS OF NATURAL GAS AND PETROLEUM. BY FRANCIS C. PHILLIPS. {Read February 5, 1897.) If it were possible to demonstrate that the original source of petroleum and natural gas is to be looked for in the rock strata in which they are now found to occur, an important advance could be made towards the establishment of a satisfactory hypothesis to account for the genesis of these hydrocarbons in nature. It has often been supposed that the relationship of the hydro- carbons to the rocks in which they occur is of an intimate kind, and that the geological record should supply all the data upon which a conclusion as to the origin of gas and oil is to be based. It does not necessarily follow, however, that they are products of Devonian or Silurian time because of their association with certain sandstones, limestones or shales. The presence of a gaseous or liquid hydrocarbon in a particular rock is perhaps due to the fact that the region of this rock, on account of its open texture, has been one of least resistance to the movement of a fluid under pressure. It is possible that gas and petroleum may have invaded the Devonian strata from greater depths and that their present position is wholly due to the pressure to which they have at some former period been subjected. Other circumstances may have been factors in determining their present location. An abundance of subterranean water may have caused a transfer to a higher level. Differences of temperature might involve a partial fractionation or distillation and removal to distant regions. Hydrocarbons of different character and from different sources might become mingled and thus intrinsic signs of different modes of origin be obliterated. In view of these inherent difficulties, which impede a solution as viewed from the geological standpoint, the question seems to resolve itself for the present into a broader but less definite one which might be formulated thus : What are the chemical processes which, being logically assumed in connection with known facts of geology, could have produced from the compounds of carbon and hydrogen in the rocks the vast quan- tities of bitumen, petroleum and natural gas ? 1897.] GENESIS OF NATURAL GAS AND PETROLEUM. 117 Of the hypotheses proposed many have been based upon pheno- mena which are more or less local when geologically considered, even if occurring in terranes of wide extent. One hypothesis attributes to petroleum and natural gas an origin almost cosmical. This hypothesis, suggested by Berthelot and afterwards developed by Mendeleeff {Principles of Chemistry, Vol. i, p. 364), and restated by this author in 1889, supposes that metallic carbides have been produced deep in or below the earth's crust, and that these carbides have been decomposed by steam giving rise to the various hydro- carbons of oil and gas. Mendeleeff supposes that carbides of the heavier metals, and among these especially iron, have been mainly instrumental in the process. The correctness of this hypothesis, which depends upon so direct an appeal to chemical facts, must be tested by a consideration of the laws of chemistry in so far as they bear upon the question. According to the experiments of Moissan (^Compts Rendus, Vol. 122, p. 1462), a few only of the metals are capable of forming definite carbides, even at the temperature of the electric arc. These are chiefly the alkali, alkaline earth and earth metals. Alumi- num and beryllium are the only metals whose carbides yield a hydro- carbon of the paraffin series alone (methane) on decomposition by water. The action of water upon the carbides of the metals of the alkalies and alkaline earths produces acetylenes. In the case of the carbides of some heavier metals methane is produced in admix- ture with free hydrogen and ethylene. The results of this author's experiments would seem to lead to the conclusion that the carbides of the earth metals only can be assumed to have participated in the process of petroleum and gas formation, in accordance with Mendeleeff's hypothesis, if the chemical composition of natural gas as found in western Pennsylvania is taken into consideration. There are few elements known to chemistry whose relationships towards carbon at high temperatures are better known than iron. The action of steam upon iron in its pure state and when in com- bination with carbon is also sufficiently well understood to justify a criticism of the hypothesis upon chemical grounds. It is a fact of importance that the product of the action of superheated steam upon cast iron consists mainly of free hydrogen with small quantities of hydrocarbons, including olefins, paraffins and others of unsaturated character. It may be assumed, but hypothetically, that iron exists in the rocks PROC. AMER. PHILOS. SOC. XXXVI. 154. I. PRINTED MAY 20, 1897. 118 GENESIS OF NATURAL GAS AND PETROLEUM. [Feb. 5, in form of a carbide richer in carbon than is producible in the electric furnace, and therefore resembling the carbides of aluminum as regards its action upon water. In such case a gas somewhat similar to natural gas might result. Published analysis of meteoric iron and of iron found in plutonic rocks do not tend to show, how- ever, that the iron found in nature ever contains carbon in such quantity as to lead to the belief that a definite carbide of this metal exists comparable to the carbides of aluminum, akaline earth, and alkali metals. If aluminum carbide and the carbides of related metals are to be regarded as the source of natural gas, we must look for the occur- rence of the lighter metals at depths at which the hypothesis of Mendeleeff would require us to suppose that the heavy metals pre- dominate. It seems, therefore, probable that a few only of the metals in form of carbides could have been concerned in the pro- duction of natural gas, and these are the very metals which on account of their lightness are supposed by this hypothesis to give place to those of high specific gravity in regions where the chemical changes in question have occurred. On account of its stronger affinity for oxygen, aluminum may be supposed under all conditions tending towards oxidation to assume the form of an oxide more readily than iron, and where aluminum occurs in presence of the heavier metals it will probably precede these in the order of time in uniting with oxygen. But its oxidation would remove it from the sphere of action leading to the produc- tion of hydrocarbons. The conclusion seems justified that where aluminum occurs in a metallic state, or as a carbide, below or in the earth's crust, the heavy metals will also abound and notably iron. If the chemical composition of natural gas is such as to warrant the belief that its production was due to the action of steam upon iron carbide, the hypothesis of Mendeleeff would at once receive strong support. If, on the other hand, chemical considerations show that iron cannot have been concerned in the process, the question then arises. Why has iron carbide been suppressed in the subterranean reactions giving origin to natural gas ? The term iron carbide has here been used to signify iron contain- ing a little carbon, such as cast iron, but not implying a real com- pound containing iron and carbon in atomic proportions. Analytical data concerning natural gas drawn from deep-lying 1897.] GENESIS OF NATURAL GAS AND PETROLEUM. 119 Strata must prove of importance in the discussion of the subject. The hypothesis of Mendeleeff would suggest that if free hydrogen occurs among the hydrocarbons contained in any geological forma- tion it must be looked for in those strata which are nearest above the Archaean rocks, and where protection against loss by diffusion upward is as nearly as possible assured by great thickness of com- pact overlying beds. Believing the composition of natural gas from formations of con- siderable depth to be a matter of interest, some tests were made during August, 1896, of natural gas from a well drilled down through the Trenton limestone at Stevensville, countj of Welland, Ontario, Canada. This well is twenty-nine hundred feet deep and stratified formations below its bottom are locally of slight depth, so that, according to Mr. E. Coste, the engineer for the gas com- pany, the drill has in the case of this well penetrated to within a short distance only of the Archaean rocks. Shales sixteen hundred feet in thickness shut off possible communication between the Trenton limestone and the upper gas-producing rocks (the Medina sandstone, Clinton limestone and Niagara limestone), and there seemed every reason to suppose that the gas was derived exclusively from very deep-lying measures. The tests were made at the well, and thus the possibility of errors due to leakage during transporta- tion of a sample were avoided. The method employed I have described in the American Chemical Journal {ox 1894, page 258. Tests were also made at the well by methods which have been devised for such purposes, and which have been described in the same volume of the journal named, for acetylene and carbon mon- oxide. The results of all these trials were negative. Numerous tests have been made of gas from wells scattered over various parts of western Pennsylvania which seem to justify the conclusion that free hydrogen, acetylene and carbon monoxide are not found in the natural gas of the region. The absence of free hydrogen in natural gas might be explained upon the assumption that although originally present, it has, by reason of its extreme lightness and ready diffusibility passed out through overlying rock strata and made its way to the upper regions of the atmosphere. In such case we must suppose that as a result of the production of free hydrogen in the interior of the earth, the atmos- phere now contains in its more rarified portion a considerable and gradually increasing volume of this very light gas. 120 GENESIS OF NATURAL GAS AND PETROLEUM. [Feb. 5, Mendeleeff's hypothesis implies that the production of natural gas still continues, there being no reason to suppose that the iron or other metallic carbides below the earth's surface are exhausted. Consequently much importance must be attached to the question of the presence of free hydrogen. Accepting provisionally the hypothesis of Mendeleeff, it may be asserted that if natural gas is a contemporaneous product sufficient time has not yet elapsed for the escape by diffusion of the free hydrogen through some hundreds or thousands of feet of shales and limestones. The free hydrogen originally present should still occur in the gas of different regions and be recognizable by chemical tests. If, on the other hand, natural gas is a stored product, shut in for long ages, it might seem possible that comparatively impervi- ous rock strata would not have sufficed to prevent the escape of this highly diffusible constituent in the course of time. No hypothesis regarding the origin of natural gas can be accepted as satisfactory if it should require the assumption that the chemical changes involved in the process are such as to lead to the production of much free hydrogen, unless it can be positively demonstrated that free hydrogen occurs as a common constituent of the gas which flows from a drill hole. The foregoing criticisms have been directed more particularly to the hypothesis in so far as it relates to natural gas. The author of the hypothesis has apparently avoided a distinction between natural gas and petroleum, and to the various hydrocarbons, liquid or gaseous, he assigns a common origin. It has been common to consider such compounds as closely related genetically. Yet this supposition may not have sufficient basis. Mabery {American Chei?iical Journal, 1896, p. 43) has shown that benzene and its homologues occur in some of the Ohio and Canadian petroleums. Lengfeld and O'Neill {American Chemical Journal, 1893, p. 19) have also discovered members of the same series of hydrocarbons in petroleum from southern California. Similar observations have been made by other authors. The composition of natural gas is such as to suggest that it has been produced by reactions occurring at low temperature, and there is reason to suppose that it has not been exposed to temperatures exceeding 500° C, since the time of its formation, as experiments demonstrate that at temperatures ranging from this point up to that of melting gold, its constituents suffer more or less complete dissoci- 1897.] PETROLEU.AE IX THE CAVITIES OF FOSSILS. 121 ation, yielding hydrogen and carbon together with small quantities of unsaturated hydrocarbons, notably acetylene. On the other hand, petroleum has been shown by the important researches of Mabery to contain a series of hydrocarbons which are usually char- acteristic of reactions at high temperatures. The fact that such hydrocarbons occur in petroleum, whether in small or large quanti- ties, is of very great interest and should have due weight in the selection of any hypothesis proposed to account for its origin. At present this fact can hardly be considered to furnish evidence either for or against the views of Mendeleeff in regard to the origin of natural gas. ON THE OCCURRENCE OF PETROLEUM IN THE CAVITIES OF FOSSILS. BY FRANCIS C. PHILLIPS. {Bead February 5, IS 97.) In the study of geological facts bearing upon the history of petro- leum, much interest has been aroused during recent times by the discovery of petroleum enclosures in the cavities of fossils in lime- stone rocks. Such occurrences, observed in many places, and in deposits of different geological age, from the Silurian onward, have been regarded as furnishing proof that the genesis of oil is to be attributed to chemical changes taking place in the tissues of the origi- nal organism of the fossil, and therefore as strengthening a com- monly accepted belief that the hydrocarbons contained in the rocks have originated from animal remains stored in the sediments which afterwards became consolidated into rock. The relationship suggested between the petroleum and the fossils is all the more interesting and important since the oil-bearing sand rocks of the Devonian age do not, as a rule, contain remains of animal life, and furnish no satisfactory clues as to the origin of oil and gas. As tending to confirm the evidence which such facts have been supposed to furnish, numerous instances have been cited where hydrocarbons are apparently produced from remains of more recent animal life, as in coral reefs and in the accumulations of organic remains buried under marine or fluviatile sediments. In certain 122 PETKOLEUM IX THE CAVITIES OF FOSSILS. [Feb. 5, districts local accumulations have apparently led to the formation of petroleum and natural gas, and where evidence of so direct a character is at hand it has been argued that chemical changes of similar kind have been concerned in the production of hydrocar- bons upon a larger scale in the rocks. But the fact most suggestive of a genetic relationship between the hydrocarbons of the rocks and the tissues of animal bodies is found in the frequent association of petroleum and bitumen with fossil remains. A remarkable instance of this kind has been discovered at Wil- liamsville, Niagara county, N. Y., by Mr. F. K. Mixer, of Buffalo. Corals in large masses, constituting a reef of considerable propor- tions, have been exposed in a limestone quarry at this place. The structure of the coral is well preserved and its rounded forms are standing erect as they grew in the original reef. In many parts the cells contain petroleum in a somewhat thickened or dried condition and the walls of the fossil seem to be saturated with oil. In other parts of the reef the cells contain a black substance resembling pitch or asphaltum, the color of which gives great distinctness to the delicate white lace-like partitions separating the cells. The distribution of petroleum and solid bitumen throughout the coral is somewhat irregular. In viewing this reef, as it stands exposed in the quarry, various questions suggest themselves as to the origin of the hydrocarbons. If these have resulted from the carbon and hydrogen of the bodies of the polyps, how has it occurred that the organic matters were con- verted into paraffins instead of undergoing the usual process of oxi- dation and decay ? The growth of the reef was undoubtedly slow, as a portion only of the polyps could have been living at any given time, the greater number of the cells being empty, the quantity of animal matter available for petroleum production must always have been small as compared with the total extent of the reef, and being scattered among separate cells oxidation of the remains of the iso- lated polyps would have been more likely to occur than their accu- mulation in masses. There does not seem to be any reason in this case for supposing that the corals in their living state were buried under masses of sediment. On the contrary, the limestone extend- ing around and above the corals indicates a period of quiet and clear water. It is, therefore, difficult to understand how the soft tissues of dead coral animals could have been protected against destructive oxidation. 1897.] PETROLEUM IN THE CAVITIES OF FOSSILS. 123 Pieces of this fossil taken from the quarry are on examination readily seen to contain an amount of petroleum at least equal in bulk to the cells of the coral. The solid bitumen occurring in other parts suffices to nearly fill the cells. These facts would render it difficult to account for the hydrocarbons on the supposition that they are due to chemical changes occurring in the tissues of the original organisms. Le Bel (^Notice sur les Gisements de petrole a Fccheldronn, Col- mar, 1885, p. 4) has observed that fossils frequently contain in their cavities a quantity of petroleum greater than could be pro- duced from the organic matter of the original animal, even suppos- ing that this organic matter had been converted wholly into petro- leum. Fraas (Jaccard, Le Petrole, 18^^, p. 60), in describing the occur- rence of petroleum in a coral reef in the Red Sea, refers to the fact that oil collects in parts of the reef growing in shallow clear water and states that this oil is so abundant that it has been carried by Bedouins to Suez, where in 1868 it had become an article of com- merce. Fraas believes that the oil is being produced by the decom- position of the organisms of the coral. If the source of this petroleum is correctly interpreted, its occur- rence under such conditions can hardly be considered to represent an isolated case. The reactions which take place during the con- version of animal remains into petroleum must be typical of changes occurring elsewhere, and must result normally under given conditions as to temperature, pressure and oxidizing influences. Wherever the same conditions exist in other reefs they should give rise to a similar constant production of petroleum and we should be justified in speaking of a " petroleum fermentation " coordinate with other naturally occurring organic changes. It seems doubtful whether this petroleum can have originated in the coral where it is found and it is improbable that such an occur- rence can serve to explain the origin of hydrocarbons in the Silu- rian fossils. I have been unable to learn that petroleum is found in the reefs at Bermuda. Dr. W. H. Dall, of the Smithsonian In- stitution, informs me that no occurrence of petroleum has been reported in the reefs of the Florida coast. If in the case of the Silurian coral at Williamsville the process of conversion into hydro- carbons was rapidly completed after the destruction of the animals, the oil would have floated to the surface of the water and little 12ri PETROLEUM IN THE CAVITIES OF FOSSILS. [Feb. 5, would be left to impregnate the calcareous skeleton. If, on the other hand, the process was continued until the organic matters were buried under deep sediments and exposure to oxidation had ceased, then more distinct 'signs of a deposit of sediment over the entire reef should be looked for. The conditions for effective oxidation of organic matters are rendered more complete under water by the presence of bacteria, and these must have aided greatly in promoting the final change of the tissues of the dead coral animals into nitrates, ammonia, car- bon dioxide and water. In stream beds and under sediments the products of the decay of animal matters are mainly gaseous, and the contents of the coral cells must have been almost wholly lost in volatile form before a process of change into petroleum could have been begun in the much diminished residue of the original organ- isms. It is possible that the occurrence of petroleum in the cells of a modern coral reef may find an explanation in a phenomenon often observed in the case of natural gas. I have elsewhere (^Journal of the American Chemical Society, 1895, p. 801) called attention to the fact that on stirring the gravel which lies at the bottom of many streams in western Pennsylvania, it is common to find that gas bub- bles are disengaged, and that such an accumulation of gas may occur where the stream flows over sandstone, covered by gravel a few inches only in depth, and where the character of the gravel renders it unlikely that gas could have originated locally. In such cases it is probable that the occurrence of gaseous hydrocarbons is due to an escape to the surface from deep-lying rock strata. Petroleum escaping from the interstices of a rock might accumu- late in the cavities and cells of dead corals. A slow oozing of petroleum from the surface of the ground is a well-known phenom- enon in various parts of the oil regions. The occurrence of petroleum in cavities of fossils might be traced to a former condition of wide distribution of oil throughout the rock, that is, in a form in which it is known to be present in limestones and shales in many places. The gradual access of moist- ure to the pores of a rock so impregnated would tend to cause a slow displacement of the oil. Water, insufficient to appear in liquid form upon a surface of fracture, might still suffice, as it grad- ually saturated the rock under the influence of capillary attraction, or of pressure, to displace the oil and cause it to accumulate in liquid 1897.] PETROLEUM IN TPIE CAVITIES OF FOSSILS. 125 form in the cavities of fossils or in other open spaces. Moisture in such quantity as is absorbed by many dense rocks would tend slowly to remove liquid hydrocarbons, just as it might drive them from the cells of vegetable tissue. The region of least resistance to the movement of the oil would be a cavity. The accumulation of oil in open spaces in fossils would thus result from its displacement from adjacent, or perhaps distant, parts of the rock by water, which would tend to produce a retreat of the oil. If thus impelled by the movement of moisture through the rock the oil would grad- ually assume the liquid form if it passed into a cavity. The cells of corals and other open spaces might thus become reservoirs capable of holding collectively considerable quantities of oil. It is true that before the original sediment became hardened into rock, the proportion of water present must have been considerable. In accordance with a commonly accepted view the process of petro- leum formation was not completed until long after the sediments with their enclosed organic matters had been consolidated. The oil would then have been expelled from the rock, little by little, as it was being gradually produced. In this case also the movement of the oil might have led to its being caught in liquid form in cav- ities, or if it oozed out at the surface of the rock stratum it might have been absorbed by a more porous rock, or caused by pressure of water to flow off through sand-rocks of more open texture. The movement of the oil through the rock, displaced from the interstices in which it had originally collected, would have been accelerated as the transition from solid organic tissues to liquid oil had become advanced. Water, if present in a rock of fine texture, could not by the action of capillarity alone be drawn upward so as to collect in liquid form in a cavity. The same statement is true of petroleum. But the presence of moisture in the interstices of a rock in which petroleum is being generated or in which it is stored in minute pores or spaces might lead to a gradual accumulation of oil from the bulk of the rock into relatively larger spaces such as the cavities of fossils. Jaccard {Le Fetrole, 1895, P- ^34) ^^^^ described the occurrence of bitumen in the cavities of fossil moUusks in the Val de Travers in the Jura mountains. Such cases might be regarded as represent- ing a later stage in a series of changes, the original liquid petroleum having passed into solid bitumen long after it was accumulated in 126 COMPOSITIOX OF AMERICAN PETROLEUM. [Feb. 5, cavities, where its solid condition would tend to its permanent pres- ervation. The sedimentary limestones contain frequently crystalline calcite cementing together the grains of amorphous mineral matter. Changes in temperature, causing unequal expansion of this calcite in different directions, by reason of the form of its crystals, might in the course of time modify the process by changing the internal structure of the rock. The presence of salt in solution and the solvent action of carbonic acid would no doubt exert an important influence, although its nature could not be foreseen. The occurrence of petroleum in the fossil shells of mollusks and in the cells of corals would then have no more geological signi- ficance than its occurrence in geodes, or in cavities in rocks, or the presence of solid bitumen in hollow quartz crystals or in sphalerite, as all such cases are perhaps attributable to one and the same source, namely, to its presence formerly in a state of wide distribu- tion in the pores of the rock. ON THE COMPOSITION OF AMERICAN PETROLEUM. BY CHARLES F. MABERY. {Read February 5, 1S97.) Petroleum is found in Pennsylvania in sandstones of various formations ; in southern Ohio in the Berea grit and other sands ; in Ohio in the Trenton limestone ; in Canada in the Corniferous sand- stone; in California, Texas, Colorado, and other American fields in shales and sandstone formations, which represent in general the geological strata in which are the various oil fields in Russia, Roumania, Germany and Austria, Japan, India, etc. Crude oils show great variation in their physical properties, such as color, specific gravity and odor, and differences in their chemical reactions de- pending on variation in composition. The first systematic investigation for the purpose of ascertaining the composition of American petroleum was made by Pelouze and Cahours, who referred the entire body of crude oil, including paraf- fine, to the series homologous with marsh gas, CnH2n+2- At about the same time, 1862, C. M. Warren began a study of Pennsylvania 1897.] COMPOSITIOX OF AMERICAN PETROLEUM. 127 oil, in which he subjected the various refinery distillates to a pro- longed course of fractional distillations in a special form of regu- lated condenser which he devised for such distillations. He sepa- rated distillates at o°, 8°-9°, 30°, 37°, 6i°, 68°, 90°, 98°, ii9°.5, 1 2 7°. 5 and at 150°. 8, of the series CnHgn + i., and of the series CnHan, members at 174°. 9, 195°. 8, 216°. 2. In connection with the discovery by synthesis of the hydrocarbons, hexane and heptane, Schorlemmer, in 1865, separated the hydro- carbons CgHi^ and C^Hig, boiling at 60° and 90°. After Warren's results were published, he admitted the others at 38°, 6S° and 98°. Schorlemmer also separated an octane at 125°. He corrected the work of Pelouze and Cahours with reference to boiling points. At about the same time in 1880, Beilstein and Kurbatiff and Schutzenberger and Jonine undertook an examination of the Caucasus petroleum, and identified hexahydro-aromatic compounds at 97° and at 118°. The former chemists also found hexahydroi- soxylol at 118° in American petroleum. Soon afterward Markowni- koff separated a long series of the naphthenes at 69°, 97°, 118°. 5, 136°, 162°, 182°, 216°, and several members with higher boiling points. Markownikoff also found numerous aromatic hydrocarbons of the series C^H.^.g, and of other series with less hydrogen. Various examinations of lesser magnitude have been undertaken, in a more or less superficial manner. Engler showed the presence in small quantities of mesitylene and other aromatic hydrocarbons in Pennsylvania petroleum. Among other bodies present in small amounts are the nitrogen compounds, the oxygen compounds, concern- ing which there is still some question as to the form in which they exist in the crude oil. Recently Zaloziecky has attempted to show the presence of the terpenes, which I recognized by their odor seven years ago {Proc. Ainer. Acad., Vol.. xxv, 1890). I began the study of petroleum in 1884, and in 1885, soon after the Trenton limestone oil was discovered, I undertook to separate the sulphur con- stituents. The sulphur compounds in Canadian petroleum were undertaken in 1891, and are still in progress. In 1893, through aid granted by the C. M. Warren Committee of the American Academy of Arts and Sciences, the scope of my work was extended to include broadly the composition of American petroleums with especial reference to Pennsylvania, Ohio and Canadian crude oils. The great field for research includes the portions of petroleum with boil- ing points above 220°, but there are serious difficulties in the way 128 COMPOSITION OF AMERICAN PETROLEUM. [Feb. 5, of reaching satisfactory results with these bodies. In a paper recently published in the Proceedings of the American Academy an account is given of the composition of Pennsylvania, Ohio, Canadian petroleums below 220°. The series C^Han + s represents the main body of Pennsylvania and Ohio oils, and of Canadian oil below 195°. Aromatic hydrocarbons of the series C^Hon-e, are present in considerable quantities. Careful study of petroleum from different sources with reference to its occurrence and composition indicates that no precise classifi- cation of crude oils can be based on these particular features. Ac- cepting Pennsylvania petroleum as typical in its occurrence as a sandstone oil, in its composition, and in the fact that it is a low sulphur oil, even the numerous varieties from different sections and different strata in the same field present great variations in the pro- portions of the individual constituents. Such oils as the light amber variety from the Berea grit sandstone (Mabery & Dunn, Amer. Chem. Journ., xviii, 1896) in southern Ohio and Virginia show larger proportions of volatile constituents below 150°, and those dis- tilling above 250°, but less of the intermediary constituents which are looked on in refining as the more valuable illuminants. In at- tempting a classification with reference to the proportion of sulphur compounds, it appears that the principal components of the typical Pennsylvania oil form the main body of such oils as those from Ohio Trenton limestone, and the Canadian Corniferous limestone, although below 150°, in the limestone oils the proportions of the hydrocarbons CnHjn + i are relatively smaller and the aromatic hydro- carbons CnH2n_6 rclativcly larger. These statements are made on the basis of results recently published (Mabery, Froc. Ajner. Acad., xxxii, 131). Study of the higher portions of Pennsylvania petro- leum above 220° is now in progress for the purpose of separating without decomposition by distillation in vacuo, with consequent diminution of boiling points and exclusion of air, the constituents between 216° and 400°. This work has progressed sufficiently to show that the aromatic hydrocarbons of the series CnH2n_6, form only a comparatively small proportion of the distillates at least within the lower limits of temperature. It should be borne in mind that nothing is known concerning the principal or the subor- dinate constituents of American petroleum above 250°, except the possible presence of certain aromatic hydrocarbons, and these were recognized in products of ordinary distillation in which there is in- 1897.] COMPOSITION OF AMERICAN PETEOLEUM. 129 variably much decomposition. To illustrate the effect of air at high temperatures on distillates with high boiling points, in a course of distillations in vacuo of Russian crude oil, accidentally air was allowed to enter a still in which distillation was proceeding without decomposition under a tension of 50 mm. at 250''. As soon as the air came into contact with the hot vapors, there was a violent ex- plosion sufficient to send the thermometer out of the still and shatter it against a brick wall several feet distant. Air let into a still under similar conditions in which Pennsylvania oil is distilling usually causes flashes of light, but no explosion. From these observations it is evident that the advantage of distillation in vacuum depends as much at least on exclusion of air as on the reduction in temperature. Definite statements relating to the composition of petroleum from diff'erent American fields must, at present, be limited to the distil- lates below 216°. But so far as it is possible to draw conclusions from data collected there seems to be no possibility of distinction based on geological occurrence and composition. High percen- tages of sulphur constituents are usually associated with limestone formations as the source of occurrence of the crude oils. But study of the varieties of crude oil from widely different sources leaves no basis for this distinction. A petroleum from South America occur- ring in a system of shales and sandstones contained 0.70 per cent, of sulphur (Mabery and Kittelberger, Proc. Amer. Acad., xxxii, 185). Another variety from Oregon having no connection with a limestone formation also gave a high percentage, 1.19 per cent of sulphur. A specimen of petroleum from Japan, now under exam- ination in this laboratory, gave 0.5 per cent, of sulphur. The im- mense deposits of petroleum in Roumania occurring in shales and sandstones are mostly high sulphur oils. No distinction can there- fore be based on sulphur contents and geological occurrence. It seems doubtful whether a distinction can be based on specific gravity and geological occurrence. The Pennsylvania oils differ from most ethers in their low specific gravity, varying in the main between 0.80 and 0.82 ; such light oils as the amber variety from Berea grit sandstone is as low in specific gravity as o. 79 (Mabery and Dunn, American Chemical Jour?ial, 1896, 11). The limestone oils are higher, those from the Trenton limestone giving 0.82 to 0.85, and those from the Canadian Corniferous limestone 0.85 to 0.88. But the Russian oil, the South American oil mentioned above, the Japanese oil, and the Roumanian oil all show a high 130 COMPOSITION OF AMERICAN PETROLEUM. [Feb. 5, specific gravity. With reference to the proportion of sulphur con- tents and specific gravity, it seems that all the high sulphur oils have a high specific gravity. There is some hope of arriving at a general system of classifica- tion on the basis of the series of hydrocarbons which constitutes the main body of the crude oils. While more must be known con- cerning the composition of the constituents with higher boiling points before such a distinction can be made with desirable precis- ion, I have seen sufficient of the behavior of the higher constituents to believe that such a basis is reasonable. As types of such a classi- fication I should select on the one hand Pennsylvania oil, and on the other, Russian oil from the Baku district. The difference in specific gravity of the crude oils is borne out by the difference in specific gravity of the corresponding distillates, and individual con- stituents with the same boiling points. The typical constituents of Pennsylvania oil, at least below 216°, are members of the series CnHan + a, but the components of the Russian as defined by the researches of Markownikow are the naphthenes of the series C^Han. With reference to the ethylene series CJi,j„ which has seemed to be accepted by some as constituting the main body of American petro- leum, so far as my observation has extended, those hydrocarbons are not contained in any petroleum, at least below 216°, in more than minute quantities. Results which I have yet to publish show that these bodies are contained only in small proportions in lime- stone oils. A classification of pretroleum from all known sources evidently demands as its basis conclusive evidence as to the series of hydrocar- bons of which each is chiefly composed. The methods to be pursued in reaching this knowledge have been indicated in my examination of Pennsylvania, Ohio and Canadian oils between 150 and 216 {^Proc. Amer. Acad., xxxii, 121). That the series CnH2n_^2> constitutes the chief body of Pennsylvania crude oil below 150° was well established long ago by independent investigations. Above this point the evi- dence was less satisfactory. To accept the results of Pelouze and Cahours which continued the series C^H^^^a through the entire range of distillates to paraffine, it is necessary to ignore the fact that American petroleum is not composed exclusively of a single homologous series of hydrocarbons, but of a mixture of bodies that require for their separation, not only very prolonged fractional dis- tillation, but searching and vigorous means of purification. 1897.] COMPOSITION OF AMERICAN PETROLEUM. 131 At the time when the French chemists conducted their investiga- tions on American petroleum, both Pennsylvania and Canadian products were to be obtained in the European markets, especially in France, where Canadian oil seems to have been more easily obtained at times than Pennsylvania oil. In the papers of Pelouze and Cahours, allusions are made to American petroleum, and to Canadian petroleum. Their second paper {Compi. Rend., 56, 505, 1863), begins with the following paragraph: ''Dans un premier examen que nous avons fait des produits les plus volatils de I'huile provenant des forages qu'on pratique depuis quelques annees sur plusieurs points de I'Amerique, et notement au Canada, nous avons signale I'existener d'un homologue du gaz des marais dont la composition est representee par le formule Cj-Hi^ = 4 vol. vap." With no previous knowledge as to the properties of crude oils from these different sources it would not be surprising if they were used indiscriminately. At any rate an examination of the papers of Pe- louze and Cahours does not reveal the source from which their crude oil was obtained. But a comparison of their results as to specific gravity and percentage composition, together with their method of purification, with the same properties of distillates more thoroughly purified (Mabery, Inc. cii., p. 171), presents conclusive evidence that Pelouze and Cahours had in hand, in at least a portion of their work, distillates from Canadian oil. Furthermore, in some of their distil- lates showing a higher specific gravity than it is possible to obtain after suitable purification, even from Canadian petroleum, analytical values correspond closely to the series CnH.,n_2 ; CuH.^g at i96°-2oo°, and C13H28 at 2i6°-2i8°. That Canadian crude oil was to be ob- tained in England at that time is evident from the work of Schor- lemmer, who demonstrated the presence in oil from Canada of the aromatic hydrocarbons CnHgn-e- The series C^Hoq, found by Warren in Pennsylvania petroleum, has been accepted by some as showing the presence of the ethylene hydrocarbons, and by others as indicating the naphthenes. That the naphthenes are excluded below 216° in Pennsylvania oil by the wide difference in specific gravity has been pointed out (Mabery, loc. cit., 125). The ethylene hydrocarbons are also excluded by the want of additive power in these distillates for the halogens. Indeed, after removal of the aromatic hydrocarbons C^H,,„_6, the series C^H.^ disappears altogether from distillates within these 132 COMPOSITION OF AMERICAN PETROLEUM. [Feb. 5, limits, leaving the series CnH.^+g, as representing the main body of Pennsylvania petroleum within these limits. The individual repre- sentatives of this series, when properly collected by fractional distil- lation and purification, include a decane at 163°-! 64°, normal de- cane at i73°-i74°, undecane at i95°-i96°, and undecane at 214°- 216°. From Canadian petroleum a hydrocarbon collects at 196°- 197° whose percentage composition and molecular weight, as well as the composition of the monochlor-derivative, corresponds to the formula CnHaa, and another at 2i4°-2i6°, with the formula C12H24. The composition of all these hydrocarbons was ascertained by anal- ysis, molecular weight determinations, analysis of chlorine deriva- tives, and molecular weights of the chlorine derivatives. The impression that the higher portions of Pennsylvania oil are composed of naphthenes was perhaps not wholly without a reasonable foundation. After finding hexahydroisoxylol in Russian oil Beil- stein and Kurbatoff identified the same body in Pennsylvania oil. Since no further attempts were then made to ascertain the composi- tion of the higher portions, it was natural to infer that the results of Warren leading to the series C^Han should be best explained by assuming that his bodies were naphthenes. After the discovery of thenaphthene series in Russian oil by Markownikoff, this belief was strengthened by the erroneous assertions of Hoefer and other anthors of German publications on petroleum that Markownikoff had established the naphthene series in Pennsylvania oil. A critical comparison of the specific gravity of Warren's hydrocarbons with those of Markownikoff without further work would have sug- gested doubts as to the presence of naphthenes in Pennsylvania oil at least below 216°. It has long been an open question with oil men as to whether Ohio and Canadian petroleum is identical with Pennsylvania oil as regards the principal constituents. With respect to the portions distilling between 150° and 216°, this question has now been answered. The observed differences in the properties of distillates within these limits before purification concern, as has been shown, specific gravity and percentage composition. Before purification, however carefully the distillates have been separated by fractional distillation, analytical values correspond fairly well with the series CnHan- After removal of the aromatic hydrocarbons the specific gravity is much reduced, and in the Pennsylvania distillates it cor- responds to the specific gravity of the same hydrocarbons synthet- 1897.] COMPOSITION OF AMERICAN PETROLEUM. 133 ically prepared. Similar changes are produced in composition, the series changing to CuH,n + .i. The series of aromatic hydrocar- bons is represented in all the oils under consideration by numerous hydrocarbons, beginning with mesitylene at 163°. The higher homologues include cumol, pseudocumol, durol, isodurol, cymol, isocymol, and doubtless other higher members. Larger proportions of these bodies appear in Ohio than in Pennsylvania petroleum and still larger proportions in Canadian crude oil. After the most thorough purification with nitric acid and fuming sulphuric acid the distillates from Ohio and Canadian petroleum have a slightly higher specific gravity than the corresponding bodies from Pennsylvania oil, and the hydrocarbons from Pennsylvania oil show a specific gravity slightly higher than that of the hydrocarbons synthetically prepared. Schorlemmer thought that these differences in specific gravity were due to slight differences in isomerism, but it is quite possible that these oils contain very small percentages of naphthenes, especially if those bodies are slowly attacked by reagents, as Mar- kownikoff observed in products from Russian oil. ' If Pennsylvania petroleum, as typical of this class of crude oils, is composed within the limits between 150° and 216° of the series CnH2n+2, the individual hydrocarbons should resemble those pre- pared by synthetic methods. Unfortunately the structure of the synthetic hydrocarbons has not been determined in all instances with desirable precision, although they have been obtained from different sources. Normal decane boiling at 173° has a specific gravity 0.7456 at 0°, somewhat lower than the decane I have sepa- rated from petroleum. The boiling point of the latter body is 1 73°. 5, and the specific gravity at 20°, 0.7486. The decane found in petroleum boiling at 163° may be diisoamyl since its specific gravity after the removal of mesitylene is not very different from that of diisoamyl. Its boiling point is somewhat higher than the boiling point of diisoamyl assigned by Wurtz. Hendecane from petroleum agrees fairly well in its properties with normal hendecane prepared by Krafft from rautenol. The boiling point of petroleum dodecane is the same as that of normal dodecane from laurinic acid, although the specific gravity of the petroleum hydrocarbon is some- what higher than the other. Since nothing has been done toward defining the butanes in petroleum except the rather superficial examination of the most vola- tile distillates in the early days of the petroleum industry, these PROC. AMER. rilTLOS. SOC. XXXVT. 154. J. PRINTKD MAY 20, 1S07. 134 COMPOSITION OF AMERICAN PETROLEUM. [Feb 5, portions of the crude oil evidently invited further examination. The most volatile distillates of Pelouze and Cahours gave with chlorine a chlorbutyl boiling at 65°-7o°, but nothing further was done toward identifying the hydrocarbon. Ronalds {London Chem. Soc, 1865, p. 64) recognized a butane at 0°, but its form was not determined. Warren collected a distillate at 0°, and another at 8°-9°, which he inferred from analogy was a butane, but no further examination was made of these distillates. In our examination, after very prolonged distillation, using freezing mixtures for conden- sation, no distillate remained between 5° and 20°, thus excluding a butane at 8°-9°. At 0°, a large quantity of a hydrocarbon was obtained which gave a chlorbutane boiling at 67°-68°, the boiling point of isobutyl chloride. By decomposition of the chloride with alcoholic potassic acetate, an acetate was formed, and from the acetate an alcohol was obtained boiling at io7°-io8°, which gave the percentages of carbon and hydrogen required for isobutyl alcohol. These facts, with the formation of isobutyl sulphide by treating the chloride with alcohol potassic sulphide, indicate that the hydrocar- bon collected at 0° was isobutane, but they do not accord with the properties of butane and isobutane, the former of which, prepared by Frankland from ethyl iodide, boils at 0°, and the latter, pre- pared by Butlerow from tertiary butyl alcohol, boils at -17°. Petroleum butane was prepared several different times from the most volatile refinery distillates we could procure, and always with the same results (Mabery and Hudson, Froc. Amer. Acad., xxxii, 1 01). In reviewing the octanes in petroleum, we found one boiling at 1 1 9°. 5, confirming the statements of Warren, and another boiling at 124°-! 25°, but no distillate remained above 125°. From the results of my work recently published, and what I have now in progress, it can, I think, be stated with confidence that it is useless to attempt to separate the constituents of petroleum boiling above 220^ by the ordinary process of distillation, and whatever results have been published concerning distillates obtained in this manner shed no light on the constituents of the crude oils. Of course this is cold sympathy for those who desire to know more of these higher portions, since there is only one method, fractional distillation, for such separations, and this method can only be applied without decomposition by excluding air and reducing the boiling points. To illustrate its tediousness, early in October, two assistants started a distillation of 125 liters of Pennsylvania crude 1897.] COMPOSITIOX OF AMERR'AN i'KTlJOliEUM . 185 oil applying a vacuum of above 150°. At present eight distillations have been made within 2° limits, up to 300° under 50 mm. Many repetitions within single degree fractions will be necessary to bring together the individual constituents. The question is frequently asked whether parafifine is a normal constituent of the crude oil or is it a product of cracking. The answer is easy ; parafifine is not obtained by cracking the crude oil, but it can itself be destroyed by cracking. If paraffine be con- tained in the crude oil it may be separated by distillation, ])rovided cracking be not carried far enough to destroy it entirely. The presence of paraffine seems to be closely connected with the dis- tinction mentioned between the series CnHsn and the series CnH.,n_|.o. Higher distillates in vacuo of crude oils containing the series CnH._,n4_o, so far as I have observed, invariably deposit paraffine. Those oils consisting below 216° of the series CnHgn deposit no paraffine even when the highest distillates that can be collected are cooled to — 20°. It may be interesting to apply this distinction to those oils that have been care fully studied. With reference to the appearance of paraffine in distillates, it should be mentioned that it is observed only in the absence of serious cracking, and that it is easy in vacuum distillation to recognize the point where cracking begins. In distilling 125 liters of Pennsylvania crude oil mentioned above for the purpose of separating the higher constituents, approximately forty liters of residue above 275° under 50 mm. became nearly solid from the amount of paraffine deposited. With the hope that more distillate could be obtained without decomposition, the semi-solid mass was put back into the still and again distilled under 50 mm. Approximately two liters were collected in three distillates, none of which deposited paraffine, and the residue, on cooling, had the con- sistency of a thick tar, with no indication of paraffine. Paraffine separates from the higher distillates of Berea grit petroleum, as well as from all specimens of Ohio and Canadian oils that I have exam- ined ; but none separated from South American petroleum, from Oregon petroleum, nor from Russian Baku oil. Since I began the study of petroleum, twelve years ago, I have devoted , considerable time to it, especially during the last seven years. Yet my results barely indicate the enormous field that awaits investigation in the examination of American petroleum. There is no field in industrial chemistry that offers greater induce- ments for fruitful results, both of scientific interest and practical 136 DISCUSSION. [Feb. 5, advantage, than the study of the portions of petroleum with high boiling points. There are immeasurably greater inducements for the establishment of a petroleum laboratory for research on Ameri- can petroleums than have led to the opening of similar laboratories abroad. Such a laboratory, established solely for research, with funds equivalent to twenty thousand dollars a year, and employing a corps of ten competent research chemists, in five years would add greatly to the honor of American research, and would establish the composition of American petroleum. The lines of work that I have in sight, and have started experimentally, would be sufficient to occupy the attention of such a body of workers at least during two years. I should be glad to resign a considerable portion of this work to such a laboratory, or to any other competent investigators. Discussion. Dr. Sadtler : I would like to say that there are one or two items referred to in Dr. Day's paper that may require a word. A paper appeared six months ago in a German journal by a gentle- man named Heusler, in which he reported upon the action of aluminum chloride on the unsaturated series and perhaps on the aromatic series of hydrocarbons ; and he claimed that by the heating of such mixtures with aluminum chloride (of course anhydrous aluminum chloride is meant), followed by distillation, carefully excluding moisture, he could readily and completely clear it by resinifying the unsaturated hydrocarbons and the aromatic hydro- carbons ; any sulphur compounds could also be resinified ; and he could then get by rectification absolutely pure hydrocarbons of the paraffin series. That seemed to be a remarkable statement and one exciting attention ; and a second article by the same author followed in the next number of the journal, in which he theorized a great deal upon Engler's menhaden oil products, and acknowledged having received from Engler by personal gift some portions of the distillates which he had obtained from these distillations of menhaden oil. He claimed that Engler's oils, when submitted to his treatment with aluminum chloride, had been purified and finally given the saturated hydrocarbons in rather small amounts. He then proceeded to theorize in what might hardly be called careful German style, but 1897.] DISCUSSION. 137 rather a free and unguarded kind of way, having a theory of his own supplementing that of Engler, his theory being that Engler's distil- lates in their original conditions were more like the bituminous shale oils than true petroleum ; and that it needed this after-treatment witli the aluminum chloride to bring them at all in character to corre- spond to petroleum oil. He therefore believed — assuming Engler's theory of the animal origin of oils — that these animal remains had first of all been subjected to a distillation analogous to that with bituminous shales ; and that a supplemental reaction with heat and contact with certain metallic chlorides — like the aluminum chloride, had transferred them into a secondary product, that is, the mixed petroleum or rock oil. The thing looked like a very fine solution of the question, but I have also noticed within the last six weeks two other articles published in the same journal, in which other authorities have claimed that this aluminum chloride re- action is a fallacy : that it does not by any means give a pure mixture of hydrocarbons belonging to the paraffin series and is absolutely worthless as a means of purification. It is stated that it cannot be carried out in the hands of any one except the gentleman who first published it. Prof. Day alludes to the possibility of sodium chloride playing an important part in the matter of produc- ing these hydrocarbons of the Pennsylvania type from sulphur and oils similar to the Ohio type of oil. I doubt very much whether it is worth while to bring that in j because the thing seems to be dis- credited and that part, of course, will have to drop away. There is something to be said in favor of the question of filtration that Mr. McGonigle speaks of. As to whether the sulphur could be eliminated by that or any sodium chloride reaction I doubt ex- tremely ; and therefore the theory which is presented by Dr. Day has several quite important breaks in it. I need hardly make any comment upon the very interesting papers we have heard, first of Prof. Peckham and afterwards of Prof. Mabery. I have been acquainted for some time with Prof. Peck- ham's views with regard to liquid asphaltum and the way in which the change from petroleum may take place ; and there is an immense field, doubtless, there, to be opened and studied ; and then of course the whole thing is modified and very much complicated by the existence of what he calls hydrates of certain of these organic acids which are present ; and then the presence of these pyridine bases also has some modifying effect. 138 DISCUSSION. [Feb. 5, With regard to the very full statement which we have had from Prof. Mabery, I need only say that he has accomplished an immense amount of work; and nobody except those who undertake fractional distillation will understand anything of the enormous difficulty that he has had in this work and the amount of labor he has put upon it ; the results which he has already attained and published are, in my opinion, far beyond the combined work of the several inves- tigators who have previously published results on Pennsylvania oil and American petroleum without specifying its origin, as in the case of the two or three European investigators. Mr. Joseph Wharton : I should like to ask whether any gentle- man here can throw any light as to the physical condition of natural gas at the low depth at which it is found ; whether it exists as gas at the depth of 2000 to 3000 feet, or whether it is condensed into a liquid form at that depth. Is there any one here who has knowledge upon that point ? Prof. Mabery: It seems probable that the gas should be lique- fied under the great pressure to which it is subjected. That the pressure is enormous we know. It depends somewhat, doubtless, upon the structure that exists in those lower strata. Some very inter- esting experiments have been made in studying those strata, and I think it is probable from what is known that natural gas has existed in the liquid form. Mr. Wharton : Does any one know what the critical point of natural gas is ? Prof. Mabery : I should say it would depend largely on the critical point of marsh gas. Liquefaction of this gas takes place under 180 atmospheres at 11° degrees Centigrade. Mr. Wharton : Has there been any experiment as to artificial liquefaction of natural gas ? Prof. Mabery : Yes; all those gases have been liquefied. Prof. Peckham : The sulphur in petroleum may be derived from two different sources : where there is a very small percentage, a fraction of one per cent., it may be that the sulphur was a constitu- ent of the original material from which the petroleum was produced ; but where the sulphur content has arisen to several per cent., as is often the case in the more dense liquid and solid bitumens, I think the sulphur has been produced by a reaction between the material of the bitumen itself, and salts — sulphates — in natural waters. It seems hardly possible that from any source — any animal or vegeta- 1897.] DISCUSSION. 139 ble source — that as much as seven per cent, of sulphur could become a constituent of a bitumen ; and I have found that amount in natural bitumen. Prof. Mabery : I am much interested in the results Prof. Sadtler has presented. Although Engler should receive much credit for obtaining petroleum products by the distillation of men- haden oil under pressure, it should be remembered that Warren and Storer demonstrated many years ago that a lime soap formed' from menhaden oil gives by distillation the petroleum hydrocarbons. Now Prof. Sadtler has shown that the same products may be obtained by distillation of vegetable oils under atmospheric pressure. This overthrows the favorite theory of the German authorities based on Engler' s results, that petroleum was formed exclusively from animal remains. The formation of petroleum hydrocarbons from vegetable oils is extremely interesting, and we should congratulate ourselves that it has been done so near the early home of the petro- leum industry. In the work of Prof. Peckham, I am especially interested just now, because I have been trying for several years to procure speci- mens of California oil, to ascertain whether it is composed of the series CnHsn or the series CnHan + 2. I was recently informed that ten gallons of this oil is on its way to my laboratory. I examined an oil from Oregon which I was told resembles the California oil, and from comparison with small samples of the California products in my possession, that seems to be the case. The Oregon oil, and another from South America, contain the series CnHan, but none of the series CnHan + 2. Pennsylvania, Ohio and Canadian petroleum give paraffine in abundance. Oils containing the series CnHan secui to givc uo paraffiuc, so far as I have examined them. Prof. Peckham has a great field for investigation in the California oil, both on account of the large amount of nitrogen compounds, and the question as to what series of hydrocarbons constitutes the main body of'the crude oil. Prof. Peckham : In reference to this matter of paraffine in petro- leum, there have been two classes of petroleum discovered in Cali- fornia ; one produced in the neighborhood of San Jose, the other in the Santa Clara Valley of the South. The great bulk of Califor- nia petroleum comes from that southern valley ; and so far as I know no traces of paraffine have ever been obtained from any of 140 DISCUSSION. [Feb. 5, it in any form— either what are known as the liquid nor the solid paraffines— not a particle of it has ever been obtained from any of the petroleum of the southern regions, but from that from the neigh- borhood of San Jose, scale paraffine has been obtained. Prof. Mabery : Shale oil does not separate much paraffine ; even in distillates above 350°. PROCEEDINGS OF THE AMERICAN PHILOSOPHICAL SOCIETY BEIB AT PnilADELPlIlA FOR PROIIOTISG I'SEPUl KNOWLEDGE. « YoL. XXXYI. ' May, 1897. No. 155. Stated Meeting, February 19, 1897. The Treasurer, J. Seegeant Price, in the Chair. Present, 23 members. Correspondence was sabmitted and letters of envoy and accessions to the library were reported. A bronze medal, commemorative of its Sesqui-centennial, was presented by Princeton University, for Avhich the thanks of the Societ}^ were given. The following deaths of members were announced : Dr. Henry Hartshorne, of Philadelphia, at Tokio, Japan, on February 10, 1897, set. 73. Hon. J. Kandolph Tucker, of Lexington, Ya., on February 13, 1897, ret. 73. Prof. Henry D. Gregory, of Philadelphia, on Februarv 14, 1897, ait. 77.' The stated business of the meeting being the election of members, the nominations were spoken to, and the ballots cast, Secretaries Hays and Prime acting as Tellers. Prof Cope presented a " Communication on Some Pale- ozoic Vertebrata from the Middle States." A communication was laid before the Society, consisting of a sketch of an act to be presented to the Legislature of Penn- sylvania setting apart three areas of -40,000 acres each on the water sheds of the Delaware, Susquehanna, and Ohio, for a State Forestry Keservation. PROC. AMER. PHILOS. SOC. XXXVI. 155. K. PRINTED JUNE 15, 1897. 142 MINUTES. [Mar. 5, Judge Sulzberger moved tliat the American Philosopliical Society lieartilj approves of the jDurpose to secure State Forestry Keservations for the Commonwealth and recommends to the Legislature the passage of the measures necessary to carr}^ this purpose into effect. Adopted. The Tellers reported that the following nominees had been elected to membership : ♦ 2302. Morris Jastrow, Philadelphia. 2303. Ferdinand J. Breer, Philadelphia. 230-i. William H. Furness, 3d, M.D., Wallingford, Pa. 2305. Edwin Grrant Conklin, Ph.D., Philadelphia. 23u6. Plorace Howard Furness, Jr., Philadelphia. 2307. H. M. Hiller, M.D., Philadelphia. 2308. John Sartain, Philadelphia. 2309. Henry Trimble, St. David's, Pa. 2310. George W. Biddle, Philadelphia. 2311. Alexander C. Abbott, M.D., Philadelphia. The meeting was then adjourned by the presiding officer. Stated Meeting, March o, 1897. The Vice-President, Dr. Pepper, in the Chair. Present, 12 members. Prof. Trimble and Dr. Abbott, newly elected members^ were presented to the Chair, and took their seats. Acknowledgments of election to membership were received from Prof. Morris Jastrow, Jr., Mr. Ferdinand. J. Dreer, Prof. Edwin Grant Conklin, Dr. H. M. Hiller, Prof. Henry Trimble, Mr. George W. Biddle and Dr. Alexander C. Abbott. Donations to the Library were reported. Prof. Arthur W. Goodspeed exhibited some recent radio- graphs, and made a comparison of them with the work of a year ago. Dr. Pepper, Mr. Ingham and Dr. Hays participated in the discussion following Prof. Goodspeed' s remarks. 1897.] MINUTES. 143 Stated Meeting^ March 19^ IS 97. Vice-President, Dr. Pepper, in the Chair. Present, 12 members. Acknowledgments of election to membership were received from Mr. John Sartain, Dr. W. H. Furness, 3d, Mr. II. H. Furness, Jr. The announcement of the decease of the following mem- bers was made and obituary notices of them were ordered to be prepared : Mr. Arthur Biddle, at Atlantic City, on March 8, ret. 44. Prof. James J. Sylvester, at London, Eng., on March 15, tet. 83. Prof. George Stuart, at Philadelphia, on March 16, tet. 66. Donations to the Library and Cabinet were announced, and in connection with the latter. Dr. Morris moved " That Mr. Patterson's deposit of the Illustrated Catalogue of the Peale Collection of the Stone Age to be returned on his demand, be accepted, and that it be placed in charge of the Curators." Adopted. Prof. Edwin J. Houston and Dr. A. E. Kennelly read a paper entitled " The Insulating Medium surrounding a Con- ductor, the Keal Path of its Current." Dr. Hays moved that a Committee of five members be appointed to consider and report upon the advisability of the Society publishing a Calendar of the Franklin Correspon- dence in its possession, and if found advisable, to recommend a plan for such a calendar and its publication. Also to con- sider and report on the historic relation to the original docu- ment of the manuscript copy of the Declaration of Indepen- dence sent by Jefferson to Kichard Henry Lee, and now in the possession of this Society, and whether its historic im- portance renders desirable its reproduction by the Society. Adopted. Dr. Pepper, Judge Mitchell, Mr. Carson, Mr. Stone and Dr. Bache were appointed the committee under the above reso- lution. 144 HOUSTOX, KEXXELLY — THE PATH OF A CURREXT. [Mar. 19, THE INSULATING MEDIUM SURROUNDING A CON- DUCTOR THE REAL PATH OF ITS CURRENT. BY EDWIN J. HOUSTON, PH.D., AND A. E. KENNELLY, SC.D. {Read March 19, 1897.) Up to the commencement of the i^resent century our knowledge of electricity and its action was almost entirely confined to the phenomena of electric charges and their dissipation by discharge. The conception of an electric current as a steady condition of dis- charge had not then been clearly ai^prehended. It was observed that dissimilar bodies, when placed in contact with, or rubbed against, each other, manifested electric excitation. It was assumed that the electric charges thus acquired resided upon the exterior surfaces of the charged bodies, and that charged bodies evidenced mutual electric attractions. and repulsions at a distance. The idea of action at a distance was, therefore, inseparably connected with early conceptions of electricity and electrical phenomena. Action at a distance was explained by some on the hypothesis that an elec- trified body emitted an invisible electric effluvium which acted upon electrified bodies in its vicinity. It was observed that elec- tric charges were transmitted through certain bodies called conduc- tors, and failed to be transmitted' through other bodies called non- conductors or insulators. In a similar manner the phenomena of magnetism, as developed up to the commencement of the present century, pointed to the seeming attraction and repulsion of mag- netic poles. According to the views then existing, a magnet was a skeleton of iron or steel for supporting two opposite poles at its extremities. These poles manifested peculiar properties to which the intervening skeleton was considered as merely subordinate. This- magnetic action at a distance, by which the magnetic poles of the earth were assumed to direct the compass needle, was supposed by some to be effected through the medium of a magnetic effluvium emitted from the poles of the magnet. Up to the commencement of the present century, therefore, electric and magnetic phenomena were studied apart, and each was accredited with the possibility of action at a distance, except in so far as some physicists endeavored to explain such action by the intervention of material electric and magnetic effluvia. About the commencement of the present cen- 1897.] HOUSTOX, KEXXELLY — THE PATH OF A CURRENT. 145 tiiry, the discovery of the voltaic pile brought to the notice of elec- tricians the development of an electric current, or a steadily main- tained discharge. The phenomena produced by the electric current were apparently so different from those produced by electric charges that they were at first believed to be essentially distinct. The elec- tric current could only be produced when a complete conducting path or circuit was provided, any breach of continuity in the con- ducting circuit immediately interrupting the current flow. Conse- quently, it appeared that the electric current passed through the conductor, usually a metallic wire, in a manner somewhat similar to that in which a liquid flows through a pipe. Moreover, the electric current was apparently restricted to the conductor, and could not pass through the insulating medium surrounding it. In 1820, not long after the discovery of the voltaic pile. Oersted announced the first known connection between electricity and mag- netism. Using the usual language, when a wire, through which an electric current is flowing, is brought into the neighborhood of a suspended magnetic needle, the poles of the needle are attracted and repelled in a manner depending upon the direction of the cur- rent and its position relatively to the needle. Here an electric current apparently acted at a distance on the needle ; for, in the insulating medium, usually the air, in which the magnet was sus- pended, no electric current could flow, and yet the magnet's poles could be acted upon at a very considerable distance from the wire carrying the electric current. Up to the middle of the present century, therefore, the phenom- ena of electricity, magnetism and electromagnetic action, suggested both action at a distance, and that electric currents pass solely through the mass of a conducting wire independently of the exter- nal insulating medium. It is true that the idea of action at a dis- tance was regarded as illogical, and as contrary to the fundamental principles of dynamics, ever since the days of Newton, but despite this unwillingness of physicists, the old notions of actions at a dis- tance continued to be thus passively employed and promulgated, and, even to-day, they still permeate scientific literature. Another reason for the retention of the recognizedly erroneous ideas of action at a distance is to be found in the fact that, up to the middle of this century, all the mathematical processes adopted for dealing with the phenomena of electricity, magnetism and electromagnetic action, tacitly assumed the principles of action at a distance just as 146 HOUSTOX, KEXNELLY — THE PATH OF A CURKENT. [Mar. 19, the mathematical processes of astronomy at the present time tacitly assume the same law, without pretending to explain the mechanism by which such action may be conveyed. Consequently, it was only too easy for students to imbibe, with the mathematical ideas for study- ing quantitative electromagnetic facts, the fundamental hypoth- esis of action at a distance upon which this idea was based. Thus the mechanical forces existing between charged electrified bodies, between magnet poles, between electric currents, or between elec- tric currents and magnets, were all referred to the mutual actions of elementary portions of imaginary electric or magnetic substances, each of which exerted an influence proportional to its quantity, and inversely proportional to the square of its distance from the element acted on. About the middle of the present century, Faraday first paved the way for a change in our views on these questions. He suggested the theory that an electrified body or a magnet did not emit any material effluvium, but exerted an influence on the invisi- ble medium in its vicinity ; namely, the universal ether ; that this influence was of the nature of a stress, and that the ether sur- rounding an electrified or magnetized substance was in some manner strained along certain directions which he called lines of force. Consequently, an electrified body produced lines of electric force along which the ether was strained, while a magnetized body similarly produced lines of magnetic force along which the ether was strained, but in a manner different from electric strain. It was this strained ether that connected the electrified or magnetized bodies with bodies in their neighborhood, and permitted attraction and repulsion to be set up between them without necessitating any action at a distance. Clerk Maxwell developed the ideas of ether strains and stresses mathematically. While retaining the original methods of quanti- tatively determining the mechanical actions between electric and magnetic bodies, by summing up the effects of all the elements of those bodies on each other, in reference to the inverse squares of the distances, he developed, at considerable length, the action of the intervening medium, and showed how the strain in such medium could produce the mechanical effects observed. In the treatment of this subject he noticed that a disturbance of the electric or mag- netic condition of the ether was controlled by a formula similar to that which controls a disturbance in an elastic solid. He was, therefore, led to believe that electromagnetic disturbances in the 1S97.] HOUSTON, KEXXELLY — THE PATH OF A CURRENT. 147 ether were propagated in all directions like disturbances in an elastic solid, and were, therefore, transmitted in waves. Maxwell, therefore, was the discoverer of the probability of electromagnetic waves in ether. He also suggested that light might be a purely electromagnetic phenomenon of very high frequency, and adduced experimental evidence in favor of this belief. The actual existence of these electromagnetic waves has since been abundantly dem- onstrated by Hertz and many others. Though invisible to the unaided eye, electromagnetic waves can be traced by the aid of sen- sitive electromagnetic apparatus constituting what has not been inaptly styled the electric eye. As the result of both the experimental and mathematical work of the latter half of the present century, especially that of Mr. Oliver Heaviside, it is now believed that electric currents are transmitted as electric waves through the ether surrounding a conductor, being guided by the conductor, but not transmitted through it. Notwithstanding the fact that the more modern views have been in existence for upwards of thirty years ; that their truth is practi- cally undisputed, and that, on the contrary, within the last ten years, strong experimental evidence has been adduced in their behalf, yet both the old phraseology and the old methods of treatment are still almost universally employed even in the modern text-books of the day. In view of the preceding facts, the authors consider that a brief description of the manner in which an electric current is now believed to be transmitted, may aid in disseminating the more modern views. All electric, magnetic or electromagnetic phenomena are now believed to be referable to two conditions of stress in the ether, one of which is called electric flux, and the other, ?nagnelic flux. The exact nature of both is unknown. Though invisible, the presence of each may be manifested in a variety of ways. So inti- mately are the electric and magnetic fluxes correlated, that any dis- turbance in one immediately calls the other into existence. Elec- tric flux exists between two electric charges. Thus, a positively charged sphere, situated at rest in a room, radiates streams of elec- tric flux, towards all parts of the room, along lines called stream lines, which may be readily mapped out. The ether is strained or dis- turbed in some manner along these stream lines. So long as the charge on the insulated body remains at rest, electric flux will per- 148 HOUSTON, KENNELLY — THE PATH OF A CURRENT. [Mar. 19, meate the air and ether in the room, but there will be no magnetic flux present, except that due to the earth's magnetism. As soon, however, as any motion occurs in an electric flux, either by moving the charge on the body, or by causing it to increase or decrease in density, the disturbance in electric flux temporarily produces a magnetic flux; and, generally speaking, any variation or motion of electric flux produces magnetic flux. A permanent magnet produces magnetic flux, both in its sub- stance and in the space surrounding it. So long as the distribu- tion of magnetic flux remains quiescent, no electric flux is pro- duced. As soon, however, as any change takes place in the mag- netic flux, either, by bodily moving the magnet, or by weakening or strengthening the magnet, electric flux is temporarily produced.. Generally, any variation or motion of magnetic flux produces elec- tric flux. Magnetic flux is always circuital, or is distributed in stream lines which form closed curves, or have reentrant paths. Electric flux, when established between opposite electric charges, is not circuital, but terminates at one end in one charge, and at the other end in the opposite charge. When, however, electric flux is established by magnetic disturbances in a space free from conductors, it is circuital, like magnetic flux. Both electric and magnetic flux possess both direction and polarity ; that is to say, each is developed along definite stream lines, and each possesses different properties up and down such stream lines. An analogy is presented mechanically in a stream of water. Water in a river flows in stream lines, and is directed in its motion down stream. In the case of electric flux the polarity is manifested by what are called positive and negative charges, these charges being developed where the electric flux terminates. In the case of mag- netic flux the polarity is manifested by what is called north-seeking poles and south-seeking poles. These poles are developed where the magnetic flux terminates on the magnet. For this reason electric flux is conventionally assumed to leave a positive charge and, to terminate, on arrival at a conductor, at a corresponding negative charge. This, while being a purely arbitrary assumption, is, never- theless, advantageous in fixing ideas. Similarly, magnetic flux is assumed to issue from a magnet at its north-seeking pole and to reenter it at its south-seeking pole. This assumption is also purely arbitrary. 1897.J HOUSTON, KEXNELLY — THE PATH OF A CURRENT. 149 Both electric and magnetic fluxes contain energy. Work must be charged on the flux to establish it, and this work is liberated when the flux disappears. The energy in the ether varies as the square of the flux density, so that if we crowd uniformly twice as much flux through a given area of cross-section, we quadruple the amount of energy which resides in that portion of space per cubic inch, or per cubic centimetre. The electric transmission of power consists in transferring electric and magnetic flux to a distance and allowing these fluxes to be ex- pended in liberating, at the receiving end of the line, the energy they contain. An electric generator is a machine for producing electric flux and thus transferring electric energy to the ether. This electric flux, or energized condition of the ether, is transferred to a distant point along wires, the ether being deprived of its energy at the receiving end of the line. The electric flux is there absorbed, and the work which was expended by the generator is recovered to a greater or less extent. The electric flux is transmitted from the generator to the receiver, through an insulating medium, being guided on its passage by a pair of conductors, extending all the way from the generator to the receiver. Such a pair of conductors, with the associated insulating medium between them, is called an electric circuit. The curious fact exists that while the old conception of an electric circuit held that the electric current passed through the conductors, and was retained in position on those conductors by reason of the insulating medium surrounding them, the modern view holds, on the contrary, that the electric current flows through the insulating medium and is held in position, or guided to its destination, by the two conductors. In other words, the modern theory completely reverses the relative functions of the insulator and the conductors in the old theory. There are three standard types of pairs of conductors, and their associated, intervening, insulating medium; viz., 1. An aerial conductor, such as a telegraph wire, supported sensi- bly parallel to the surface of the ground. Here the wire forms one conductor, the ground the other conductor, wliile the ether asso- ciated with the air between them is the medium through which the electric current flows. 2. Subterranean or submarine conductors separated from the surrounding conducting earth or water by a uniform layer or coat- ing of insulating material. Here one conductor is formed by the 150 IIOUSTOX, KEXNELLY — THE PATH OF A CURREXT. [Mar. 19. interior wire, while the other conductor is the sheath of metal, liquid or ground, and the medium through which the electric cur- rent flows is the ether in the insulating coating of rubber, gutta- percha, paper, etc., with which the interior conductor is invested. 3. A pair of overhead wires supported sensibly parallel to each other, on suitable insulating supports ; as, for example, a pair of tele- phone or electric-light conductors. Here the two wires are the con- ductors, and the medium through which the electric current flows is the ether in the air between them. When an electric source is connected to any such pair of conduc- tors, an electric flux is established in the insulator between them; or, more correctly speaking, in the ether permeating the insulator. The density of the electric flux, or the quantity of flux per normal square centimetre, will depend upon the nature of the insulator, on its dimensions, and on the electric pressure or voltage of the source. An increase of voltage is attended by a proportional increase in the density of the electric flux ; while an increase in the thickness of the layer of insulating material between the conductors dimin- ishes the density. Figs, i, 2, 3, are diagrams of the distribution of electric flux for the three types of circuit mentioned. \ J- / ^ ^• tt.ttTtttttttttTttttTTtrTtT ,'' ^^ '^f^ ^^^^ tnttrtffttttTfttntttttTt / / / i J ^^ ^ ^ vsr (^ a- Fig. I.— Electric Flux Surrounding an Aerial Wire with Ground-Return Circuit. In Fig. T, AB, represents the aerial wire, and GG, the ground. The flux stream-lines are represented on the right-hand side in a plane perpendicular to the wire. These stream lines are arcs of circles, on the supposition that the ground, GG, is conducting, and has a level surface, such as might be presented by the surface of water in a lake. On the left-hand side the flux is represented as 1897.] KOUSTOX, KEXXELLY — THE PATH OF A CURREXT. 151 being distributed in straight lines; /. e., in sections of planes, per- pendicular to the wire and to the ground. The wire being nega- tively charged, by convention the flux streams converge towards it. 8 S ifltHntHittnttittfmtrtttttmT^wnittlitr Fig. 2. — Electric Flux Permeating Insulator of Cable. In Fig. 2, CC, is an insulated conductor, usually of copper, separated from the conducting sheath SSSS, which may be of lead or other metal, by the cylindrical insulating jacket IIII. Here the flux is represented as emerging from the wire which is, therefore, re- garded as positively charged. The density of the flux is greatest in the vicinity of the interior conductor, and diminishes uniformly as we proceed towards the sheath. This is represented diagrammatic- ally by the length of the flux arrows. On the left-hand side the flux is seen to be distributed in planes perpendicular to the length of the cable. ■ I AL l!!n!liillin|ll!!i;!,. ir.rT'^i.-'.'Mi' "^ ,[UtirtrfninnTninTTnTif 3B CL ID Fig. 3. — Electric Flux Permeating Insulator between Two Parallel Wires. 152 HOUSTOX, KENXELLY THE PATH OF A CURREXT. [Mar. 19. Fig. 3, represents two parallel wires, AB and CD, the latter posi- tively and the former negatively charged. Here the flux issues from the wire CD, and converges upon the wire AB, in curves, which are all arcs of circles. The flux density is greatest in the neighbor- hood of each wire and least in the intermediate portions. On the left-hand side, the longitudinal section shows that the flux is dis- tributed uniformly in planes perpendicular to the two wires. The electric flux, which thus permeates the insulating medium, per- sists as long as the insulation is maintained, even in the absence of the original electric source. Thus, if a pair of wires be perfectly insulated from each other, and are charged as represented in Fig. 3, by connection to an electric source ; then, so far as is known, the electric flux, which will be developed between them in the insulat- ing medium, will be indefinitely maintained, although in practice there is always sufficient leakage to permit the charge to gradually disappear. In order to study the electric transmission of power over a cir- cuit, we may suppose that a pair of perfectly conducting wires exists extending between two cities. These conductors may be, say, of the third type; /. e.^ may consist of a pair of parallel wires supported in air. Let AB and CD, Fig. 4, represent such a pair of conductors Fig. 4 „E„ -D Fig. 5 E A B _ ^^ liiMO **■ J. Fig. 6 E ^ A SlA^ Figs. 4-6. — Movement of Electric Flux in Circuit of Perfect Conduction and In- sulation. between the terminal stations AC, on the left hand, and BD, on the right. At the middle of the line E, we may suppose that suitable 1897.1 HOUSTON, KEXXELLY — THE PATH OF A CURREXT. 153 short lengths of each of the two wires; namely, fg and hj, each one metre long, are insulated from the rest of the system, and elec- trically charged by a momentary connection to a dynamo or other •suitable source, to a pressure of say, looo volts. An electric flux will thus be established between the two short lengths of wire of the type represented in Fig. 3, and shown in Fig. 4, by the arrows; fg, being positive, and hj, negative. Strictly speaking, the flux dis- turbance would not remain in parallel planes at the ends of the short lengths, but would bulge outwards considerably, from the ends ; but this peculiarity is of no consequence to what follows, and we may, therefore, suppose that the simpler geometrical distribution is preserved. If the metre lengths at E, be perfectly insulated from -each other, the block of electric flux resident in the ether between them would be indefinitely maintained at 1000 volts pressure. Suppose, however, that at some instant of time the discontinuities existing between the metre lengths of the conductors and the rest of the system are suddenly bridged over. In other words, the metre- lengths are connected electrically at both ends to the rest of the circuit. Then instantly the flux tends to rush towards the ends of the circuit as represented by the arrows k and 1, in Fig. 5. The metre block of flux instantly subdivides into two metre blocks, each under 500 volts pressure, and each with half the original density and, therefore, one-quarter of the original energy. At the same time, the moment that the flux commences to run, a magnetic flux distribution is brought into existence ; for, as we have already mentioned, a motion of electric flux can never occur without pro- ducing magnetic flux. While then the metre block of Fig. 5, divides into two separate metre blocks, moving in opposite direc- tions, as in Fig. 6, each block becomes invested with magnetic flux in the manner represented in Fig. 7. Here the curves of magnetic flux distribution, indicated by arrows, are circles eccentric to the wires. One-half the energy of each moving block is electric and is resident in the electric flux, and one-half is magnetic and is resident in the magnetic flux. It will be observed that the magnetic flux is so directed as to pass through the loop formed by the two wires, in planes perpendicular to the wires. Moreover, the curves of mag- netic flux stream-lines are all perpendicular to the curves of electric flux stream-lines, which, already shown in Fig. 2, are here repre- sented by dotted lines. The magnetic flux at each point is due to the movement of the electric flux through the ether at that point, 154 HOUSTOX, KENNELLY — THE PATH OF A CURRENT. [Mar. 19, and is not due, as the old theory supposed, to an assumed current in the wire. The passage of the electric flux over the wires consti- tutes a momentary electric current, which in this case would have a strength of roughly two amperes. The velocity with which the flux blocks move in Fig. 6, is the velocity of light in air ; approximately, 300,000 kilometres per second. If the distance from E, to the ends of the wires is exactly 300 kilometres each way, the metre blocks of ■■' \-v-^M^-l. ^ / • ••• ^\ .^■ -.^^-^-J^is, .•'^- •■' "^ . Fig. 7. — Magnetic Flux Accompanying Moving Electric Flux between Two Par- allel Wires. flux will traverse this distance in y^Q-th of a second. The metre blocks will, therefore, pass by any particular point on the line in "3o"o"."oTo",oTo^^^ of a second, and the electric current, which this flux rush constitutes, would, therefore, have this duration at any particu- lar point. Fig. 8, represents the metre blocks of flux in the act of arriv- ing at the termini of the line. The two conductors are open-cir- 1897.] HOUSTON, KP:XXELLY — THE PATH OF A CUREENT. 155 cuited, or insulated, at both ends. The arrows v and v', represent the direction in which the blocks have arrived, and the curved arrows mm, and m'm^ represent the direction of magnetic flux which has been generated by the movement of each block, and which has been carried bodily along with the moving blocks. If the original metre block of flux in Fig. 4, represents an amount of energy resi- dent in electric flux, amounting to say 1000 ergs, then each of the two metre blocks into which this is divided, assuming no dissipation of energy, carries with it 500 ergs, 250 in magnetic flux and 250 in electric flux. Fig. 8 m m' giuiiiit^^ ZL^-lMj) m ni' F/g.9 ^j(Mu7_ _aJMj) Figs. 8-10. — Reflected Movement of Electric Flux in Circuit of Perfect Conduc- tion and Insulation, On arrival at the termini, the flux is compressed into a half metre at each end, as represented in Fig. 9. The density of electric flux IS doubled, as represented by the closeness of the arrows. At the same time the magnetic flux vanishes, while the pressure rises momentarily from 500 to 1000 volts. There is, therefore, half the volume of flux with twice the density; and, therefore, four times the voluminal electric energy, but no magnetic energy. Conse- ruently, there remains 500 ergs of purely electric energy in each block. Fig. 10, represents the conditions of afl'airs immediately after- wards. Here the blocks expand again into metre lengths and are reflected from the termini, or move back towards the centre of the line. The magnetic flux reappears, but in the reversed direction, as shown by the curved arrows. The electric flux retains its origi- nal direction from the upper to the lower wire, and the pressure has fallen from 1000 to 500 volts as before. The current represented 156 IIOUSTOX, KEXXELLY — THE PATH OF A CURRENT. [Mar. 19, by the flux rush is, therefore, reversed in direction, since the mag- netic flux, by which it is measured, is reversed, but the electric potential difference, as measured by the density of electric flux, remains unaltered. The two metre blocks now rush towards the centre of the line with the speed of light. They may be consid- ered as solitary waves of light, that is to say, disturbances traveling with the velocity of light waves, but not periodic, and leaving the medium quiescent the moment they pass by. After the lapse of another ^q^Qpth of a second, the two metre blocks, which will again arrive at E, the middle of the line, as shown in Fig. II, where the two arrows v and v', indicate that the blocks are about to collide. The curved arrows show that the magnetic flux is oppositely directed in the two blocks, those on the left-hand side at mm, being directed into the loop, as seen by the observer, while those on the right-hand side at m^ii^, being directed out of the loop. Fig. 11 m mm' dT C "^ ^^utUJH^ j^w\^ ^ ^Q m mm' m' Fig. 12 E v^^ liiM "^ jj Fi• 'in m m' m' FlGS. 17-19. — Collision, of Reflected Electric Flux Waves in Circuit of Perfect Conduction and Insulation Short-Circuited at Termini. 'The two metre blocks then separate out by passing through each -THE PATH OF A CURRENT. 159 Other as shown in Fig. 19, where the two blocks are seen to be withdrawing from each other with the speed of light. They again rush to the termini of the line, where they undergo reflection with reversal of electric flux and persistence of magnetic flux. This condition of reflection and collision would continue forever, under the conditions assumed. We have hitherto assumed that the insulator insulated perfectly and the conductor conducted perfectly. Neither of these two con- ditions is attained in practice. We will first assume that there is imperfect insulation in the insulator, with perfect conduction in the wires. For convenience, we may change the type of circuit to the second ; namely, a cable composed of a central wire and annu- lar external conducting sheath. This is represented in Fig. 20 f.9 20 A u— F^q.. 21 c A u = = = ?iq. 22 C A C a, •.Ul ..">'■ ; ^-< ivUUiuU-.- '::i^:- u^ K ^^ "^i ^ Figs. 20-22. — Movement of Electric Flux in Cable of Imperfect Insulation and Perfect Conduction. where AB, is the central conductor and CD, CD, the external con- ducting sheath. Let us suppose that a metre block of flux, at 1000 volts, is, as before, called into existence, and released from the centre of the line. The flux block immediately starts with the vel- ocity of light in the ether of that particular insulator, which may be, perhaps, 200,000 kilometers per second, instead of 300,000 kilo- meters per second, as in free ether. The block, as before, subdi- 160 HOUSTON, KENNELLY — THE PATH OF A CURRENT. [Mar. 19, vides into two metre blocks, each with half the density and each with its attendant magnetic flux, as represented by the straight and curved arrows of Fig. 21. Instead, however, of pursuing their paths as sharply defined blocks, the two blocks are subjected to attenuation by leaving stragglers or remnants along the road, since the insulator is somewhat leaky. That is to say, the path through which they pass is strewed with reflected or oppositely directed electric flux, of reduced density, which immediately turns around and moves back towards the centre of the line with the velocity of light in that medium. Consequently, the two metre blocks undergo a process of decay ; their density is diminished ; their energy is dissipated in the insulator as heat, and in "supplying the straggling reversed fluxes ; and the distribution, instead of being in planes perpendicular to the cable, is bent backwards in a manner which is exaggerated in Fig. 21. In fact the flux behaves as though it got entangled in the insulator instead of moving freely through it, and by reason of the entanglement^ a number of shreds or straggling particles are detached from the advancing main body. If the leak- age be sufficiently great, the blocks of flux may be completely dis- sipated before they arrive at the termini of the line, the degree of attenuation depending entirely upon the amount of leakage. Fig. 22, represents the condition of affairs at a later stage of the first outward movement of the flux blocks. Here Vj v'2, represent the movement of the heads of the columns ; U2 and u'2, represent the backward movement of the stream of stragglers thrown off by the heads in the course of their motion. Consequently, the entire field between the two separating heads is filled with a confused and straggling mass of attenuated flux, and a very complex state of aff'airs is reached. The original blocks are entirely absorbed after they have traveled a greater or less distance. We may next assume that the insulator insulates perfectly, but that the wires do not conduct perfectly. This is a condition which is very nearly represented in many practical cases. In Fig. 23, the metre block of flux starts from the centre as before. The interior conductor being positively, and the sheath nega- tively, electrified. The curved arrows represent the direction of accompanying magnetic flux, produced as soon as the motion takes place. Here the imperfect conduction of the wire sets up a series of straggling reflections of electric flux, in the same direc- ion, however, as that in the moving blocks, instead of the oppo- 1897.] HOUSTON, KENNELLY — THE PATH OF A CURRENT. 161 site direction, as in Figs. 21 and 22. The electric flux is bent from the perpendicular in the direction of motion, as represented in exaggeration at Fig. 24. Consequently, the metre .blocks are sub- jected to a process of attenuation or decay, by throwing off attenu- ated electric flux as they advance, the straggling flux so thrown off immediately commencing to rush backwards with the velocity of light in the medium as represented by the arrows Ui u\. The metre blocks, therefore, lose definition as they advance, becoming weaker and weaker, the energy being lost into the conductor and into straggling flux. If the wires conduct sufficiently imperfectly, the two metre blocks may be completely absorbed before they reach the terminals of the line, the degree of attenuation depending entirely upon the degree of imperfection in conducting power, for a given electric cable; /. e., a given geometrical distribution of in- sulating medium. The fact of imperfect conduction, may be rep- resented roughly by supposing that the flux, instead of slipping freely along the surface of the conductor, becomes entangled in the surface of the same, and friction between the base of the mov- ing flux and the surface of the wire detaches some of the flux and leaves the detritus in the pathway. Fig. 23 p^^ff— f^m_ p FiQ 24 .--— ^"-^ ^^^y^rrrt^- "■■..•......•■•■frrr r: ^ ai ''' n •°- ^_ l .>tu^w^v;:,-x'--r-jc";::.".-:^^^ ^ .-v^^ ^ ^ ^ ._^._. * ~ iiumi:- ■..■■■.;...>. .-^iUUv ''' . ^ ^-^ . ____ ^ Fiq 26 C u, u^ U;. g^ TV D Figs. 23-25. — Movement of Electric Flux in Cable of Perfect Insulation and Im- perfect Conduction. Fig. 25, represents the condition of attenuation at a later stage. 162 HOUSTON, KENNELLY — THE PATH OF A CUKRENT. [Mar. 19, Here the original metre blocks have diminished considerably in density, and in their stock of energy, their motion being indicated by the arrows Vg and v^. 1I2 and u'2, are arrows representing the mo- tion of the straggling flux, or tails, as they have been called, thrown off bv the advancing blocks. After a certain distance has been traversed by these blocks they become completely absorbed and the tails only remain, the subsequent motion being very complex. All the best electric conductors with which we are acquainted ; namely, the metals, conduct imperfectly at the temperatures at which they exist on the earth. It has been shown that pure copper would apparently conduct to perfection, or have no electric resist- ance, at the temperature of absolute zero, or — 273° C. It is pos- sible that some means may eventually be found to artificially pro- duce in copper, at ordinary temperatures, the electric conducting, power it possesses at or near the absolute zero of temperature, but at the present time we have to content ourselves with the compara- tively imperfect conducting power of copper, which is practically the best electric conductor available. Consequently, we cannot attain in practice to the distortionless transmission of electro-mag- netic waves such as represented in Figs. 4 to 19. It is, however, possible to so unite imperfect insulation with im- perfect conduction; /. e., leakage with conductor- resistance, as to cause the tailings due to leakage to exactly annul the tailings due to conductor resistance; for, the comparison [of Figs. 20, 21 and 22, with Figs. 23, 24 and 25, will show that these tailings are oppositely directed as regards electric flux, the tailings from leak- age being reversed, and the tailings from conductor resistance being similarly directed, to electric flux in the main blocks. A cir- cuit in which the leakage and conductor resistance are so balanced as to leave no tailings, is called a distortionless circuit, and no other means of obtaining a distortionless circuit is known at the present time. Although such a circuit is distortionless, since no tailings are left, as the blocks of flux move on without leaving stragglers, yet en- ergy is expended both into the insulator and into the conductor, and, consequently, the fluxes diminish in density and attenuation goes on. This is represented in Fig. 26. Here the metre block of flux is started from the centre of the line as before, the directions being indicated by the arrows. In Fig. 27, the electric flux is seen to- have a double curvature, being partly bent outwards and partly bent inwards. Energy is being dissipated sideways into the insulator. 1897.] HOUSTON, KENNELLY — THE PATH OF A CURRENT. 163 and sideways into the conductor, as the blocks move on. Conse- quently, the electric density and the accompanying magnetic density are diminishing, but no straggling electric or magnetic flux is left to mark the passage of the blocks. If the original stock of energy was looo ergs, the energy which may reside in the two blocks, when they reach the ends of the line, may be, perhaps, only IOC ergs, depending entirely upon the amount of electric resistance in the conductor, and the corresponding amount of leakage which must be given to the insulator in order to balance the same. Fig. 26 v-«- mm ■m^ iWimiflt \_( v^ -^v' IMIlJUklMiJ ■ _^ f^ — — ■ — -.-,_. JtrsKtax. , — ■ — ., .. ... ~. — — - .. ., T\ F19.27 -^ . ^jMuji^ Mmi\^ , ;7~" Fiq.28 Figs. 26-28. — Movement of Electric Flux in Distortionless Cable. Fig. 28, represents the condition of attenuation without distortion at the later stage in the process. We have hitherto assumed that only a metre block of electric flux was started from the centre of the circuit, and that this was called into existence in some special manner. We shall now con- sider what takes place when an electric source, such as a dynamo or battery, is connected permanently between the wires at one end of the circuit. In Fig. 29, a dynamo is supposed to be con- nected at the end A, the positive pole to the upper wire and the negative pole to the lower wire. The dynamo is assumed to have no resistance, and the distant end of the line is short-cir- cuited at B. The moment the connection is effected, electric 16-i HOUSTON, KENNELLY— THE PATH OF A CURRENT. [Mar. 19 flux is supplied from the dynamo to the insulating medium between the two wires. The rush of electric flux which escapes from the dynamo constitutes the electric current which it supplies, and if a certain imaginary unit quantity of electric flux constitutes a coulomb of electricity (the practical unit of electric quantity), then the number of coulombs of electric flux, uniformly supplied per second from the generator, represents the number of amperes of electric current supplied to the circuit. If the pressure of the generator is I coo volts, then the difference of potential between the wires at A, is I GOO volts, and these two wires we may first assume to be per- Fig.29 A g .^=^0' 'K Fig. 39. — Distribution of Electric Flux Streams in Conformity with Ohm's Law in a Perfectly Insulated Closed-Circuit. Again at the BD end, the electric flux streams are indicated at Eg. First come two opposite arrows Cg, representing the first arrival of the stream and its immediate reflection with reversal. Then follow successive pairs of oppositely directed shortened arrows. The sum of all these is clearly zero, so that the resultant flux den- sity at BD, is zero, and there is no resultant voltage or potential difference. At B'D', therefore, the dotted lines indicating poten- tial fall to zero or join the lines A'B' CD'. Again, in the middle of the line at Eo, there is a series of succes- 168 HOUSTON, KENNELLY — THE PATH OF A CURRENT. [Mar. 19, sive arrows, none of which entirely cancel. Their sum, however, is half ei, and at ad, rhe voltage E'.,, E'^^, falls on the dotted lines E'l B', E'\ D'. The same is true for any other point on the line. Consequently, the pressure falls steadily from AC to BD. It is otherwise, however, with the magnetic flux which under- goes Ro reversal. The development of this is shown at M^, M^ and Mg. The arrows are all of equal length to the corresponding elec- tric flux arrows at E^, E2 and E3, but there is no reversal of direc- tion. The sum of all these sets of arrows is constant at all points of the line, and this condition of constancy in total magnetic flux is represented by the horizontal straight lines m, m, m, m, m, m. In other words, the current strength is constant. The rate at which energy is being transferred from the dynamo along the circuit past any point is simply the sum of the electric and magnetic energies contained in the various passing streams of flux, the summation being made with regard to the direction of these streams. Thus the first stream may carry past the point considered 1,000,000 ergs in each second, half in magnetic energy, and half in electric energy, the second stream may carry 500,000 ergs back- ward, the third 250,000 forward, and so on; the resultant stream in this case being 666,667 ^^S^ P^^ second forward, and this is the activity of the circuit at the point considered. According to these views, therefore, the electric current, which is electric flux-rush, is invariably transmitted with the velocity of light in the ether of the particular insulator considered. But the actual velocity with which an electric impulse travels along the cir- cuit, as measured by the time which elapses between the connection of the source at the generating end and the appearance of energy at the receiving end, always tends to be less than this velocity, because, owing to attenuation and distortion, the first impulse or block of flux may be completely absorbed and dissipated before it can reach the distant end with the velocity at which it travels, and further flux must gradually come up from the source and suffer attenuation and distortion, before the vanguard can finally arrive at the receiv- ing end and perform its allotted function. It is for this reason that a submarine electric cable between say Ireland and America, takes nearly |th of a second before an electric signal or impulse trans- mitted from one end will make its first appearance at the other, although the time that an electric wave would take to traverse its length would be only say about ■g^o'^h second. The original impulse 1897.1 HOUSTON, KEXNELLY — THE PATH OF A CURRENT. 169 traveled so far as it went with the velocity of light in the ether of gutta-percha, but the vanguard was completely dissipated and the successive vanguards were attenuated with complete dissipation for a comparatively long time before the distant end could be reached. It is only on long circuits, such as are afforded by telegraph and telephone wires or submarine cables, that the phenomena of electric transmission with their attendant distortion and attenuation are most clearly evidenced. In the comparatively short circuits em- ployed for transmission of electric light and power, the phenomena of distortion and attenuation of electric and magnetic flux are of little practical importance. Fig. 40, represents the signals sent over T r an s m i tte d Fig. 40. — Distortion of Signals Received Over Last- Laid Atlantic Submarine Cable. the last laid Atlantic cable and the corresponding signals which were received at the distant end. The two should be exact facsimiles and should, therefore, be capable of actual superposition if no dis- tortion occurred in the electric impulses. jN'ot only the delay or retardation in the received signals, but also the great distortion which is noticeable, are due entirely to the fact that there is very little leakage in the insulator, while there is very appreciable resist- ance in the conductor. This cable, laid in 1894, has a published length of 1847.5 nautical miles. The copper conductor offers a resistance of 1.68, or about if, ohms per nautical mile, while the insulator has a resistance of 85,000,000,000 ohms in each nautical mile. This cable has a working speed of over forty-five words per minute, which is much faster than any other previously laid Atlan- tic cable, owing to the greater conductance of the circuit. This cable possesses, of course, enormous distortion, although such dis- tortion does not prevent signals being read until a speed of over 225 letters per minute is attained. If, however, the insulation, instead of being 85,000,000,000 ohms in each nautical mile, were reduced to about 500 ohms in the nautical mile, the leakage tailings would 170 probably balance the tailings due to imperfect conductance and the cable would be distortionless. The signals received would, there- fore, be the exact counterpart of the signals sent, and an indefin- itely high speed of signaling should be possible. In respect to absence from distortion, such an Atlantic cable would transmit tele- phonic speech waves perfectly. It would, however, possess so much leakage that the received signals would be far too attenuated and feeble to perceive. The conductor would only oifer at the sending end a resistance of, approximately, 28 ohms, instead of 3108 ohms, the total conductor resistance, and the current strength which would flow from the receiving end to ground would be, ap- proximately, 5x10^^ times less than the current entering at the gener- ating end. No telegraphic or telephonic instrument at the present time could detect so feeble a current as this. Moreover, if any accident happened to such a cable it would be impossible to localize the position of the fault unless the same occurred within a mile or two of either end. Consequently, the distortionless circuit does not provide at the present time a practical solution for trans-Atlan- tic telephony. About one hundred miles is, probably, the limiting length of this particular cable, with its good insulation, over which telephonic speech can be carried. We have not considered the mechanism whereby the electric and magnetic flux, when it reaches the receiving end, is absorbed and its energy utilized for the performance of any kind of work, such as the operation of a motor, the production of signals, or of articulate speech. It has been sufficient to point out that the electric current runs through the insulator from one end of the circuit to the other, and is guided by the two conductors, which with the insulator form the circuit. If it were not for these two conductors, any elec- tric wave or impulse would radiate out into space in all directions, like light from an unprotected candle. The wires do for the elec- tric wave what a reflector does for the search light ; namely, local- izes and concentrates the beam into a single path, whereby it may be transmitted to the desired point with the minimum attendant loss in transmission. Discussion. Mr. Paul A. N. Winand said : I have been very kindly invited by the authors of the paper to participate in its discussion. I wish to express first my appreciation of the remarkably thorough, clear and original manner in which 1897.] HOUSTOX, KEXXELLY — THE TATII OF A CURREXT. 171 they have accounted for the conditions which exist in the space sur- 7'oiinding the condticior in the phenomenon called electric current. In fact I could not attempt to add anything to this very clear ex- position. I have therefore collected the objections that can be raised against some of the views and conclusions of the authors. We first encounter a difficulty as long as we do not bear in mind the dual nature of the electric flux considered in relation to elec- trostatic conditions. The flux is to be taken, respecting one of its manifestations, as a measure of electric quantity inasmuch as, when rushing, each unit will produce the same magnetic flux, but this effect is independent of the difference of electric potential. The energy transferred is, however, proportional to this difference. In the case represented by Fig. 39 of a perfectly insulated closed circuit, the quantity of flux, owing to the perfect insulation, must remain unchanged as it rushes along the line, but the other factor in the transfer of energy, due to the rush of flux, the difference of potential, decreases as the energy is transformed into heat in the conductor. If I understand the authors correctly, they consider the process as entailing a diminution of the first factor (quantity) by partial reflexions constituting the imperfect conduction, while the second factor remains unaltered. It is difficult to see how, with perfect insulation, at any point of the line, where such reflexions occur (the reflected fractions of flux returning towards the origin), energy will cease to be electric and become thermic, since the re- flected fractions will carry their energy away undiminished from that point, while the unreflected part of the flux will carry its share away in the primary direction of main rush. As to the view held by the authors that the electric current runs through the insulator, or, more broadly, through the space outside the conductor, and is merely guided or localized by the latter, it seems to me open to some grave objections. It is true that the old view, which considered the conductor as the only real seat of the phenomenon, is not tenable. But there is another intermediate position, which has been expounded by Poynting, Lodge, J. J. Thomson and others, which is : that while the current flows through the conductor, the energy, which is generally transferred simul- taneously, travels through the space surrounding the conductor. As stated by Lodge : '' We must learn then to distinguish be- tween the flow of electricity and the flow of electric energy ; they do not occur along the same paths Electric energy is not 172 HOUSTON, KENNELLY — THE PATH OF A CURKENT. [Mar. 19, to be regarded as pumped in at one end of a conducting wire and as exuding in equal quantities at the other. The electricity does indeed travel thus, whatever the travel of electricity may ultimately be found to mean, but the energy does not." Poynting expresses it thus : ** Formerly a current was regarded as something traveling along a conductor. But the existence of induced currents and of electromagnetic action at a distance from a primary circuit, from which they draw their energy, has led us, under the guidance of Fara- day and Maxwell, to look upon the medium surrounding the conduc- tor as playing a very important part in the development of the phenomena." I am not prepared to abandon this intermediate point of view for the reasons which I shall presently state. It naturally depends to a great extent on what we are to understand by an electric cur- rent. The nature of electricity being unknown, this phenomenon can only be dealt with as a sum of correlated effects. Some of these occur in the conductor, some in the space outside of it. One fundamental relation was obtained when it was proved by experiment that the translatory motion of a charged conductor pro- duced the external effects of a current ; the effects otherwise found in the conductor being then absent because the conductor moved with the charge and with its external condition or electric flux. It might be argued that the conducting body, say a charged sphere, should be considered as being mainly a discontinuity in the surrounding insulating space and that the displacement of this dis- continuity created the effects by disturbing the space. The experi- ments of Rowland, however, have established that a rotary motion of a plane conducting disc around its axis produced the same ex- ternal effects as a current and in this case the conductor, considered as a discontinuity in the insulating space, did not change its posi- tion. Does this not- tend to show that the unknown condition which moves bodily with the substance of the conductor in the one case moves along the conductor in the other case, which is called current proper ? On the other hand we find that in the case of current proper, effects are produced within the conductor, and we find also that these effects occur not merely at the boundary between conductor and surrounding space, but throughout the cross-section of the conduc- tor. This is undoubtedly true of the heating, the electrolytic effects, osmotic effects, migration of the ions, actions at the 1897.] HOUSTON, KEXXELLY — THE PATH OF A CURRENT. 173 electrodes, some luminous effects (as in gases), thermo-electric effects broadly and of some magnetic effects. It is an estab- lished fact that when a conductor carries a so-called current the magnetic lines of force or flux do not exist only in the space around it, but they are present also within the cross-section of the conduc- tor. Their density is, however, smaller at points inside the cross- section than at points immediately outside of it and at the centre of a circular homogeneous cross-section this density is equal to zero. Does this not clearly point to the conclusion that the action which produces the field in the surrounding space has its seat in the cross section of the conductor and extends throughout the same ? Even for effects such as those of so-called free static electricity which seem clearly to have their seat at the boundary between the con- ductor and the space surrounding it, can we disregard the conductor which is an essential part of the apparatus, though the effects so far discovered in such cases seem to reside in the surrounding space ? Turning now from the consideration of continuous currents to that of very rapidly alternating or freely alternating currents which generate waves of electromagnetic disturbance in space, as first demonstrated by Hertz, we find that, on connecting the charged conducting bodies, the disturbance originates on these bodies and gradually spreads into space with the velocity of light. The phe nomenon starts with a current having its seat on the conducting bodies and the surrounding space is affected subsequently, 'as by light emanating from a spark. Is it then not natural to consider the conductor as the seat of the current and as the primary factor in the apparatus ? In view of these considerations, I cannot but retain the point of view stated above, though I am ready to admit that, as the changes of distribution of energy take place through the surrounding space, the latter may be considered as more important than the conductor. It should not be forgotten, however, that we can only postulate but not demonstrate the travel of energy, while we can measure its dis- appearance at one point and its appearance at another. We can only find changes in the distribution of energy. Now if we con- sider a conducting circuit of inappreciably small resistance; a current of any strength can be existent without a comparatively appreci- able change in the distribution of energy, which shows that even the practical importance of this action is not always evident. PROC. AMER. PHILOS. SOC. XXXVI. 155. M. PRINTED JULY 29, 1897. 174 HOUSTON, KEXNELLY — THE PATH OF A CURRENT. [Mar. 19, Dr. a. Macfarlane : I wish first of all to express my sense of 'the admirable manner in which the authors have carried out the aim which they set before themselves. Behind their descrip- tion of the manner in which an electric current is now believed to be transmitted there is a great amount of mathematical analysis and experimental verification. In a work on the Applications of Electricity, written by Count du Moncel before the beginning of the great industrial development of electricity, he refers to a fanciful plan of a M. Charles Bourseul for transmitting speech by electricity. The Count makes great fun of the idea ; yet he lived to write a book on the telephone. What struck him as especially absurd was that vibrations produced by the human voice could be thought capable of transmission through a solid wire of copper. And indeed it is wonderful how electri- cians have been so long content to regard the current of electricity as transmitted by the copper molecules, or even by the ether in the wire between the molecules. In the study of electrotechnics there is nothing more important than clear ideas about the relation of the electric current to the associated magnetic flux. It is important to observe that there are many analogies between the two ; but it is also important to observe that the analogy is not complete. The electric current involves in its idea the element of time in a way that the magnetic flux does not. Now observe how the theory expounded explains this. We have the complementary ideas of electric flux and of magnetic flux and also the other two ideas of rush of electric flux and rush of magnetic flux ; the electric current in general meaning motion of the combined flux. For some time it was customary to neglect the study of static electricity because its connection with current electricity was not evident. But observe that the one idea — electric flux — comes from the old science of static electricity, and the other idea — magnetic flux — from the old science of magnetism : together they explain the phenomena of the flow of electricity along a conductor. In the text-book of Electricity and Magnetism which I studied there was an article headed " Velocity of Electricity." Account was given of some experiments made to determine the time required for the transmission of signals along conducting lines; the dis- agreement of the values obtained was pointed out, and the writer concluded that properly speaking there was no such thing as the 1897. J MINUTES. 175 velocity of electricity. But observe how the theory expounded rests on that very idea, how it explains all the seeming contradic- tions, and shows what in certain cases reduces the velocity of elec- tricity from that of the velocity of light in the ether. Stated Meeting, April ;?, 1897. Vice-President, Dr. Pepper, in the Chair. Present 45 members. Correspondence was snbmitted. Mr. Pettit, on behalf of the Curators, presented a i^eport, recommending that the Xorth Room be fitted up for the use of the Cabinet. Dr. Pepper presented the report of the Special Committee on the Needs of the Library. The following resolutions were then adopted : 1. That the immediate needs of the Library demand that the Nortli Room be devoted to its purposes. 2. That the Peale Collection be maintained in the North Room for the present. 3. That the collections of plants be transferred in trust as a deposit, subject to recall, to such institution as may be ordered by the Society. 4. That the duplicate collection of rocks be submitted to a Committee of Geologists (Messrs. Lyman, Prime, Frazer and Piatt), to report to the Society their recommendation as to its disposition. 5. That a Special Committee of nine (Dr. Pepper, Messrs. Harris, Pettit, T. H. Bache, Price, Frazer, Stone, Jos. M. Wilson and Hays) be appointed to adopt plans for the adaptation of the North Room for the above purposes and to make suitable provision for the other objects of the Society, and that the Hall Committee be empowered to expend a sum not exceeding one thousand dollars in carrjdng into eftect the plans so adopted. A letter from Judge Mitchell on behalf of the Commission to collect and print the Statutes at Large of Pennsylvania, from the foundation of the colony to the year 1800, asking that the Society grant it the privilege of using a volume of 176 MINUTES. [April 2, MS. copies of laws prior to 1700, in the possession of tlie Society, was received. Dr. Hays stated, in connection with Judge Mitchell's letter, that he had a few days ago incidentally called the attention of Dr. Frederick D. Stone to a manuscript volume of laws of the Province of Pennsylvania, passed prior to November, 1700, which had been presented to the Society in 1835, by the late Joshua Francis Fisher, Esq. Dr. Stone at once recog- nized that the volume might have a very important bearing on the work of the Commission appointed in 1883 by the State of Pennsylvania to examine and collate, and authorized ■some years later to publish, the complete text of the Statutes at Large of Pennsylvania from the foundation of the Prov- ince, 1^82 to 1801, of which the second volume (the only one yet issued) has just been presented to the Society by the Com- mission. The principal reason why the Commissioners had delayed the printing of the first volume was due to the fact that certain laws, twelve in number, noted in the minutes of the Provincial Council as having been passed prior to l^ovem- ber, 1700, which date was adopted as the starting-point of the second volume, could not be found. Official inquiries made at Harrisburg, and at the Public Kecord office in Lon- don, elicited replies that no such acts were in the possession of the State or of the English Government. Fraitless search was also made at West Chester, at N'ew Castle and at Dover, as certihed copies of the acts, as passed, were then usually sent to the clerks of the several counties. The Penn papers and the early manuscripts in the collection of the Historical Society of Pennsylvania Avere carefully examiiied in vain, and the Secretary of the Commission, Mr. Charles K. Hildeburn, personally made a thorouoli but fruitless search in the Public Eecord Office in London for these missing laws. Of all this Dr. Stone was fully aware, and he at once suggested that the attention of the Commission be called to the volume shown him. Mr. Justice Mitchell, the Chairman of the Commission, and Secretary Hildeburn, upon being informed of the exist- 1897.] MINUTES. 177 ence of tins valuable and important volume in our Library, at once subjected it to careful examination and found that it contained many of the laws passed prior to November, 1700, including the twelve missing ones, viz., one act passed June 9, 169-1 ; two acts passed February 10, 1699-1700 ; one act passed May 16, 1700, and eight acts passed June 7, 1700. Some in not quite as satisfactory form as could be desired, but most of them duly attested by the Speaker of the Assem- bly, signed by Governor Fletcher, and the later acts by Governor Markham, and sealed Avith the " Lesser Seal " of the Province. It is interesting to note, in this connection, that the use of the " Lesser Seal " for such a purpose was a most extraor- dinary proceeding, and can bear no other explanation than that it was done by William Penn's orders Avith a view to his claim to a veto power, which was subsequently denied him by the Crown, as the later acts are all passed under the " Great Seal " of the Province. The only copies of the laws passed prior to November, 1700, possessed by the State and from which the Commission had intended to print, consist of unattested copies made by Patrick Robinson, Secretary of the Council. Hence the Com- missioners now desire to print from the duly attested copies of these laws belonging to this Society, rather than from the unattested copies belonging to the State. It is surmised that the copies contained in the volume belonging to the Society may have come into the office of Andrew Hamilton during the period when he was Attorney - General of the Province, and were acquired by Mr. Fisher in the course of his examination of the Hamilton papers depos- ited at " The Woodlands." The finding of these acts will place the Commonwealth of Penns3dvania in possession of a complete set of its legislative enactments, from the founding of the Province to the readily accessible " Pamphlet Laws " beginning with 1802. All but two of the original thirteen States of the Union have, at one time or another, attempted to make and publish similar collec- 178 MIXUTES. [April 23, tions, but not one lias succeeded in gathering together all its laws, but now, with the use of the volume which Mr. Fisher Avith intelligent discrimination rescued from oblivion or worse, and which the American Philosophical Society has so carefully preserved, Pennsylvania will be the only American Common- wealth that is able to present to the world an unbroken series of its own laws. The following resolution was then adopted : That permission be given to tlie Commission for the Compilation of the Laws of Pennsylvania prior to 1800, to refer to and to copy, if they so desire, the MS. volume of original laws of Pennsylvania from 16