PBOCEE DINGS OP TEE MANCHESTER LITERARY AND PHILOSOPHICAL SOCIETY. YOL. XVIII. Session 1878-79. MANCHESTER: PRINTED BY THOS. SOWLER AND CO., 24, CANNON STREET. LONDON : BALLIERE, 219, REGENT STREET. 1879. NOTE. The object which, the Society have in view in publishing their Proceedings is to give an immediate and succinct account of the scientific and other business transacted at their meetings to the members and the general public. The various communications are supplied by the authors themselves, who are alone responsible for the facts and reasonings contained therein. INDEX. Axon William E. A., M.E.S.L., F.S.S — The Poisonous Qualities of the Yew, p. 67. Baxendell Joseph, F.E.A.S.— Observations of Dr. Klein’s new Lunar Crater near Hyginus, made at the Observatory, Birkdale, p. 96. On the Meteorological Effects of the position of the Moon with respect to the Sun, p. 99. Bell Alfred, F.G.S The Area of the Middle Drifts as determined by their Contents, p. 51. Bevan E, J. — Note on Certain Thionates, p. 7. Binney E. W., F.E.S., F.G.S. — On a Eucalyptus Globulous, p. 2. Ee- marks on a Fossil Plant found at Laxey, in the Isle of Man, p. 19. On Boulders of Clay from the Drift, p. 40. On an Old Letter of Sir Walter Scott, p. 43. On a Gigantic Tooth of a Fossil Shark, p. 118. Bottomley James, B.A., D.Sc. — On a copy of the Principia of Newton, p. 63. Colorimetric Experiments, Part II., p. 137. Burghardt Charles A., Ph.D. — Mineralogical Notes, p. 111. Dale E. S., B.A., and C. Schorlemmer, F.E S. — On the Combinations of Aurin with Mineral Acids, p. 29. On Aurin, Part II., p. 88. Grimshaw Harry, F.C.S. — On the Water of Thirlmere, p. 4. Note on the Intensity of Moonlight, p. 39 On a further Analysis of the Water of the Mineral Spring at Humphrey Head, p. 45. Hannay J. B., F.E.S.E., F.C.S. — On Silicious Fossilization, Part II., p. 75. Hartog Marcus M., F.L.S.— A Preliminary Abstract of an Investigation of the Nervous System of Cyclops, p. 48. VI Heelis James. — Two Deductions from Mr. G. H. Darwin’s Letter in Nature, Feb. 6, 1879, upon Sir W. Thomson’s Equation of Cooling, v — Vo + p X 'J 7T 4 kt e 0 dz p. 83. Hurst H. A. — List of the Leguminosse of the Riviera collected by Joseph Sidebotham, Esq., in the Winter of 1877-78, p, 133. Ishimatsu Saduma. — On a Chemical Investigation of Japanese Lacquer, or TJrushi, p. 52. Mackereth Rev. Thomas, F.R.A.S., F.M.S. — On the Mean Temperatures of the Winters of the last 29 years, p. 78, Melvill J. Cosmo, F.L.S. — An Account of Three Visits to the Breidden Hills, Montgomeryshire, North Wales, in May, June, and July, 1877, p. 26. Nasmyth James, C.E., F.R.A.S. — Relative Brightness of the Planets Venus and Mercury, p. 2, Plant John, F.G.S. — The Great Sheatfish, Silums glanis, in Loch Bad- a-Luacrudli, Ross, p. 107. Planta Pv. — On the Grasses of Egypt, p. 134, Poynting J. H., B.A., B.Sc. — On the Estimation of Small Excesses of Weight by the Balance from the time of Vibration and the angu- lar Deflection of the Beam, p. 33. Arrangement of a Tangent Galvanometer for lecture-room purposes to illustrate the laws of the action of currents on Magnets, and of the resistance of wires, p. 85. Rawson Robert, Assoc. I.N.A. — Screw Propulsion, p. 90. Reynolds Professor Osborne, M.A., F.R.S. — On the Bursting of the Gun on Board the Thunderer, p. 58 Rogers Thomas. — On Specimens of Ballast Plants collected at Cardiff in September, 187 8, p, 71. Stewart Professor Balfour, LL.D., F.R.S. — On a Modification of Bun- sen’s Calorimeter, p. 66. Waters Arthur Wm., F.G.S, — The use of the Opercula in the Determi- nation of the Cheilostomatous Bryozoa, p. 8. On the Naples Zoological Station, p. 128, Wilde Henry.— -On some Improved Methods of Producing and Regula- ting Electric Light, p. 12. On some Improved Methods of Producing and Regulating Electric Light, Part II., p. 22. Williamson Professor W. C., F.R.S.— On a Section of the Eucalyptus G-lobulous, p. 94. On the Oval Scars on the Stems of the Carboni- ferous genus Ulodendron, p. 94. Meetings of the Physical and Mathematical Section.— Annual, p. 96. Ordinary, pp. 63, 78, 137. Meetings of the Microscopical and Natural History Section.— Annual, p. 130. Ordinary, pp. 25, 26, 48, 71, 106, 107. Report of the Council.— April, 1879, p. 119. . ■ - ■ ■ ■ 4 I ' . . ■ . . ■ •; PROCEEDINGS OF THE LITEEAEY AND PHILOSOPHICAL SOCIETY. General Meeting, October 1st, 1878. J. P. Joule, D.C.L., LL.D., F.B.S., &c., President, in the Chair. Mr. James Ballantyne Hannay, F.RS.E., Assistant Lec- turer on Chemistry in the Owens College; and Mr. John Priestley, Demonstrator and Assistant Lecturer in Physio- logy and Histology in the Owens College, were elected Ordinary Members of the Society. Ordinary Meeting, October 1st, 1878. J. P. Joule, D.C.L., LL.D., F.RS., &c., President, in the Chair. Among the Donations announced was a portrait of Dr. Percival, presented by Mr. Francis Nicholson, F.Z.S., Hono- rary Librarian of the Society. On the motion of Mr. C. Bailey, seconded by the Kev. Wm. Gas kell, it was resolved That the cordial thanks of the Society be given to Mr. Nicholson for his valuable donation of a portrait of Dr. Percival, the first President of the Society. Proceedings — Lit. & Phid. Soo.— Vol. XVIII.— No. 1.— Session 1878-79. 2 Ordinary Meeting, October 15th, 1878. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. Mr. Binney, F.R.S., F.G.S., said that at a meeting of the Society held on the 1 4th day of November, 1876, he gave an account of a Eucalyptus globulus growing in his garden at Douglas in the Isle of Man. In that year (1876) it had grown 7ft. Sin. in height. In the following year 6ft. 8in., when it unfortunately lost its leading shoot by accident. Up to the 7th of this month it had grown 6ft. Thus in the three years it had reached 20ft. 4in. in height. The tree was planted in a sheltered situation close to the sea, and its foliage at the present time, notwithstanding the recent severe gales, presents a most luxuriant appearance and yields a pleasant odour. No manure has been supplied to the roots, which have grown in a soil formed of the debris of Manx schist. “ Relative Brightness of the Planets Venus and Mercury,” by James Nasmyth, C.E., F.R.A.S., Corresponding Member of the Society. On many occasions when observing Mercury and Venus separately in full daylight, I have always been impressed with the strikingly inferior brightness of Mercury as com- pared with Venus; and as such a condition is the very reverse of what might be expected by reason of Mercury being so much nearer to the sun than Venus, I awaited the rare event of a very close conjunction of these two planets that occurred on the 26th and 27th of September last. With the advantage of a perfectly clear sky I had 3 the two planets before me for several hours, so to speak, side by side in the field of the telescope at the same time, thus affording me a most perfect opportunity for making a com- parison of their relative brightness. It is difficult to convey in words an exact impression of the difference in the bright- ness of such objects, but I may attempt to do so by stating that Venus looked like clean silver while Mercury looked like lead or zinc. Were I to indicate my impressions by way of number I would say that Venus was fully twice as bright as Mercury. So remarkable an inferiority in the brightness of Mercury, notwithstanding his much greater nearness to the sun, appears to me to indicate the existence of some very special and peculiar condition of his surface in respect to his capability of reflecting light, a condition that may be due to the nature of his envelope, if such exist, or of that of his surface, by which the fervid light of the sun’s rays falling on him are in a great measure quenched or absorbed so as to leave but a small residue to be reflected from his surface. If this be so, it appears to me to be reasonable to suppose that the absorption of so much light must result in a vast increase in the heat of the surface of Mercury beyond what would have been the case had Mer- cury possessed the same surface conditions as Venus. Whether in the progress of spectroscopic investigation we shall ever be enabled to detect some evidence of metallic or other vapours or gases clinging to or closely enveloping the surface of Mercury that might in some respect account for so remarkable an absorption of the sun’s light, we must be content to await the acquirement of such evidence if it ever be forthcoming. It appears to me, however, to be well to raise such a question, so that our astronomical spectroscopists may be on the outlook for some evidence of the cause of so very remarkable a defective condition in the light-reflecting power of Mercury to which I have thus endeavoured to direct attention. 4 “On the Water of Thirlmere,” by Harry Grimshaw, F.C.S., and Clifford Grimshaw. The samples of water of which the following details are given were taken by us on August 23rd, 1878, from what may be termed the “ upper and lower lakes,” meaning, above and below the narrow waist of the lake, where crossed by the small bridge. The first taken was the “lower” sample, which was obtained on the west side of the lake about twenty yards below the bridge. The “ upper” sample was taken about three quarters of a mile below the head of the lake on the east side. The results of the two samples so far as position affects them should therefore be sufficient to show any possible divergency which could occur in the quality of the water on that account. These two positions are shown upon the sketch map accompanying the paper. The two samples were analysed separately except as re- gards the amounts of ammonia (determined August 28th), for which equal parts of each sample were taken, as there was not a sufficient quantity for separate analyses. The following are the numbers obtained : Free ammonia — half a litre of water distilled took T5 cc. standard NH4C1. Albumenoid ammonia — half a litre of water distilled took 3*0 cc. standard NH4C1. Total hardness — 70 cc. water took 1 cc. standard soap solu- tion. Permanent hardness — 70 cc. water boiled 1 hour and made up took 1 cc. soap. — (The ammonia analysis common to both samples, hardness same in each). Solid matter — 100 cc. lower sample gave 0*0045 grams resi- due, which blackened on ignition and lost 0‘0025 gram. Solid matter — 70 cc. upper sample gave 0*0022 grams resi- due, which blackened a little on heating, not so much as lower sample, and lost on ignition 0*0007 gram. Chlorine — 25 cc. lower sample took (1st) 0*25 cc. (2nd) 0.25 cc. standard AgN03 ; 25 cc. upper sample took (1st) 0*15 cc. (2nd) 0*15 cc. standard AgNO . 5 The foregoing figures give the following tabulated results : — Grains per Gallon. Lr. Sample. Up. Sample. Dr. Roscoe’s. Total solid matter 315 ... 2 20 ... T45 Mineral matter 1 '40 ... 1 '50 ... — Loss on ignition 1*75 ... 0*70 ... — Total hardness 1*00 ... 1*00 ... 0'50 Permanent hardness 1*00 ... 1*00 ... 0'50 Chlorine 0*70 ... 0'42 ... 0’42 Nitrogen as nitrates and nitrites.. — ... — ... 0'0247 Free ammonia 0'0021 0'00 Albumenoid ammonia 0'0042 04)049 The “ ammonias” expressed in parts per million are 0'03 and 0'06 respectively; the chlorine equals 0*7 and 1*16 grains per gallon of salt. The water was very clear and sparkling, practically free from sediment, and its reaction perfectly neutral to litmus. There was no reaction for heavy metals, copper, lead, iron, &c., although we observed that there ran in close to the top of the lake a small stream of a very turbid milky appearance, upon which is situated on the side of the hill towards Hel- vellyn, a lead mine; which stream could be traced by its colour for at least 20 yards into the clear water of the mere. These mining operations we understand will of course be completely done away with on proceeding with the water scheme. We may offer the following brief remarks upon the above analysis of the water of Thirlmere. In the first place it is evident that the water is one of the very purest description found in nature, not being surpassed by that of any locality in Great Britain of which analyses have been published. As regards its use for manufacturing purposes it practi- cally could not be improved. For drinking purposes also it is perfectly free from anything which could be con- sidered objectionable, of either an organic or mineral nature, though we are not prepared to assert that a water considered “solely” as to its suitability for this purpose 6 attains any particular advantage from having its amount of lime salts lower than some 10 or so grains per gallon, though doubtless it is better that this should be very small, than that it should be excessive. To give a fuller indica- tion of the quality of the water of Thirlmere, we have taken the liberty of appending to our results, those obtained by Dr. Roscoe from a sample of the same taken in February of this year. Now it will be seen that there is a certain difference between the results of these samples, more espe- cially with regard to our “lower” one. On examination, however, the difference will be seen to be one of “ degree” only, and not of “kind,” and entirely confined to the mineral, and in this case the least important items. It is explained by the fact that the rain-fall some little while before the taking of the respective samples had been very different, the longest period of dryness perhaps which we have had this year having occurred just before the taking of those of the present paper. We should therefore expect that the solid matters would be higher, and find them to be so by about one and a half grains per gallon, the total in either case being insignificant. It would perhaps not be wide of the mark if we said that the analyses of Dr. Roscoe and ourselves show the water at its best and its worst as regards ordinary variation. This variation it will be seen is not greater than may occur at the same time in different parts of the lake, as shown by our upper and lower samples, these analyses also indicating a slight gradual increase of dissolved material as we approach the foot of the lake, where the solvent action of the water upon its bed will have accumulated and the fresh water received from the tributaries is lowest in amount. This gradation of quality will, of course, only be true of the lake under its present natural conditions. The variation of the organic constituents of the water at the different dates is not so marked. From the behaviour of the solid matter during ignition we should say that the carbonaceous matter, of which there is a perceptible amount, is almost entirely of a vegetable nature. 7 Ordinary Meeting, October 29th, 1878. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. “Note on certain Thionates,” by E. J. Bevan, Student in the Owens College. Communicated by Professor H. E. Roscoe, F.R.S., &c. Thallium Triothionate. When thallium carbonate is treated with an equivalent quantity of trithionic acid, pre- pared by precipitating potassium tritbionate with tartaric acid, and the aqueous solution so obtained evaporated over strong sulphuric acid, thallium trithionate separates out in long colourless needle-shaped crystals isomorphous with those of the corresponding potassium salt. Thallium tri- thionate decomposes slowly at the ordinary temperature, quickly on heating, and is with difficulty prepared free from sulphate. Analysis showed it to contain 08% of thallium, whereas the formula K2S306 requires 67'95%. Hypovanadic Dithionate. — If an aqueous solution of barium dithionate be precipitated with the requisite quantity of hypovanadic sulphate, and the blue filtrate from the barium sulphate concentrated in a vacuum over strong sulphuric acid, crystals of hypovanadic dithionate separate out. If concentration be continued after the first appearance of these crystals, decomposition takes place, sulphur dioxide is set free, and hypovanadic sulphate remains. This easy decomposition prevents hypovanadic dithionate being pre- pared in the pure state. Aniline Dithionate — This salt is obtained in beautiful long needles, by the double decomposition of barium dithionate with aniline sulphate. Aniline dithionate is comparatively stable, its aqueous solution may be boiled without decomposition, when the dry salt is cautiously heated in a vacuous tube it sublimes, a portion, however, undergoing decomposition. It is freely soluble in water and alcohol; 100 c.c. of water at 16° dissolve 7’89 grms. of the salt. Its alcoholic solution, treated with sodium amalgam, yields aniline sulphite. Analysis showed this Proceedings— Lit, & Phil. Soc,— Yol. XYIIL— No. 2.— Session 1878-9. 8 body to contain 18*60% of sulpliur, whilst (C6H3NH2)2 requires 18*40% S. “The Use of the Opercula in the Determination of the Cheilostomatous Bryozoa,” by Arthur Wm. Waters, F.G.S. In the determination of the Bryozoa various authors have attached very different importance to the characters used, but the form of the aperture has been recognised by all to be of use. D’Orbigny rightly used this very largely, and Hassall pointed out that it was much less varying than many points. Busk of course mentions the form in most cases, but Professor F. A. Smitt, the first authority on the Bryozoa, has used it much more largely, and has based his classification of the Lepralia and allied genera principally upon the form of the aperture. Dr. Hincks also has re- cently proposed a new classification in many points similar to Smitt’s, in which the form of the aperture is largely made the basis. It seemed to me that as the shape ot the oral-aperture can only indicate the form of the operculum, which closes it, the opercula themselves might furnish more reliable in- formation, and I therefore prepared a series from the material I had available, and I find it may be even more useful than I at all expected. Besides indicating the form of the aperture, there are also many other characters shown, so that in the first 35 examined and figured all have an easily distinguishable operculum. The operculum is closed by means of two muscles, which in some cases, as Myriozoum truncatum, fig. 15 ; Lepralia pertusa var., fig. 4 ; Lepralia arrogata, fig. 6, &c., &c., are attached at the side, in some quite from the edge, in others, as Cellepora, fig. 8, from a muscular boss on the rim ; but in most of the Celleporidse, and some Lepralia, &c., the muscular attachment is on the interior surface as in Lep- ralia Cecilii, fig. 1 ; Cellepora, fig. 5, &c. 9 In many it would seem that the opercula move upon a sort of hinge, as in Myriozoum truncatum, fig. 15 ; Lepralia arrogata, fig. 6, and a large number figured. In others it seems that a membrane attached at the proximal end retains it in its place. The opercula of some are curved into a saddle-shaped form, as Hetepora Couchii, fig. 22, Eschara foliacea in stadium Eschara and Hemeschara, fig. 24, 25, and these have a concave proximal edge. In some the operculum consists of two separable layers, and this apparently causes the peculiar light portion of a part in Lepralia cucullata. In Tub ucell aria cereoides a light oval patch is seen in the centre, and in section fig. 36 this is shown to be caused by the chitinous operculum being double elsewhere ; in fact it is like a meniscus with a con- cave stop in front. I have every reason to think there is no membrane enclosing this oval space, but cannot speak with certainty, as I have confined my attention to those points I deemed useful in determination, though a complete study of the structure of the opercula, generally, would no doubt repay the trouble. Tubucellaria hirsuta is not double in the same way, and has the long muscular bosses further from the edge. In a large number of the Bryozoa the old and young zooecia are known to vary so much as not to be recognisable as the same species if discovered separately, but the oper- cula of both arn the same ; also the operculated aperture is in many surrounded by an elevated peristome, in other words, is deep down in the throat, so that the shape cannot be seen on account of the projecting lips. In such a case the examination of the operculum will reveal the true form. The determination of the Celleporidse has seemed to be an almost hopeless task, as the form of the colony varies greatly, and the avicularia and other characters are difficult to use, but I believe the opercula may assist very much to bring this family out of its present confusion. In Cellepora 10 the outside cells are decumbent, while the central ones are erect, so that often no similarity is apparent, but so far as my examination goes the opercula of both stages are the same. The size seems to vary but little, and in a slide of 6 or 7 in many cases all would exactly correspond with the draw- ing of the one figured, and in few cases was the variation over a tenth of the size. I was also much surprised to find how closely the measurements of these Naples specimens corresponded with the sizes of the aperture as given by Smitt in his description of the Northern forms. Although only groups allied to Lepralia have now been brought under examination, it is by no means in these families only that the shape of the oral aperture is of importance, as in nearly all genera it is specifically charac- teristic as may be seen in Membranipora, Diachoris, Bugula, Flustra, &c., and a little more attention to this would have made the British Museum Catalogue of much more value, and prevented uniting under one name as Lepralia spinifera species with different shaped apertures, which it has since been necessary to separate. There are also other points which may be of use, as for instance I find in one Eschara from Australia that the operculum has 7 teeth in front, the central one the largest, and in Cellepora sardonica, fig. 27, it is strange to find lines on the edge corresponding with the minute teeth in the aperture. I should propose to divide the opercula into (a) those with a straight proximal edge 27, 28, 29, 30, 31, 34 ; (6) those with a straight edge and a sinal projection 1, 2, 3, 4 ; (c) those with a subtriangular proximal end 5, 6, 7, 8, 15 ; (cl) those with a rounded proximal end 9, 10, 11, 12, 16; (e) saddle shaped, mostly with a concave end 22, 23, 24, 25, 26; (/) suboblong 17, 18, 19, 20. That the opercula may be of the greatest use in specific determination there is now no doubt, and thus intimate -Proc.fflartc/b. Fit £ ThzL. Soc-. Vol 18. Pi'. I. / \ / .Pig. 5 . Ty. 9 Fig 13. Tig 17. Fig. 18. 19 ■ 7ig 22. .Fig 23. F ig 24- C\ t- J Fig. 30 Tiff. 31. N A i V) _ i ■ V ) \ ... - > lig 35. Fig.3G. Fig 37. 71 iFItPlcrs, h t/i/ 11 relationship will be indicated, but how far general classifi- cation may be assisted must remain open until larger series have been examined. EXPLANATION OF PLATE. Opercula of 1 Lepralia Cecilii, Aud. 2 ■ vulgaris, Moll. 3 pertusa, var. 4 — — , var. 5 Cellepora. 6 Lepralia arrogata, Waters. 7 linearis, Hass, var typica SmitJ. 8 Cellepora. 9 Lepralia errata. 10 Cellepora Hassallii, John. 11 verruculata, Smitt. 12 Cellepora. 13 Lepralia auriculata, Hass. 14 cucullata. Busk. 15 Myriozoum truncatum, Pall. 16 Lepralia. 17 Lepralia Pallasiana, Moll, var projecta, W. IB coccinea, Abild. 19 Pallasiana, Moll. 20 lata. Busk. This is larger than most opercula of lata. 21 Eschara contorta, Busk. 22 Retepora Couchii, Hincks. 23 cellulosa, Jam. 24 Lepralia foliacea, stadium Hemeschara. 25 Eschara foliacea, Ell & Sol. 26 Lepralia reticulata, Macg. var ophidiana, W. 27 Cellepora sardonica. Waters. 28 Eschara verrucosa, Peach. 29 Lepralia ciliata, Pall. 30 Malusii, Aud. 31 bimucronata, Moll. 32 Brongniartii, Aud. 33 rectieulata, Macg. var inequalis, Waters. 34 G-attyae, Lands. 35 Tubucellaria hirsuta, Busk. 36 cereoides, Ell & Sol. (in section). 37 Ditto do. All magnified 85 times. 12 “ On some Improved Methods of Producing and Regula- ting Electric Light,” by Henry Wilde, Esq. Among the manifold functions which the elementary substance carbon performs in organic nature, not the least important is that by which it becomes the great source of artificial illumination, whether derived from oils, coal gas, or from coke rendered incandescent by the action of powerful electric currents. Since the time when Davy first produced the voltaic arc, between two points of wood charcoal, through which was transmitted the current from the great battery of 2000 plates belonging to the Royal Institution, many ex- periments have been made to determine the best kinds of carbon for developing the electric light. The carbon which, until recently, was most commonly employed for this pur- pose, is obtained from the sides of gas retorts, where it ac- cumulates in the form of coke during the destructive dis- tillation of coal. The shells of coke from the retort are sawn up into pencils from one quarter, to half an inch square, and from six to nine inches in length. Although very good results are obtained from carbon of this kind, it is a difficult material to work on account of its hardness, and it some- times contains impurities which interfere with its conduct- ivity. It is also liable to fracture when suddenly heated by the transmission of powerful electric currents. These defects have led to the introduction in electric lighting of artificial carbon, composed of powdered coke and lamp black, formed into a paste with molasses and gum. This material is pressed into cylindrical forms, and subjected for a given time to a high temperature in a special furnace. The manufacture of these carbon pencils has attained great perfection in the hands of Carre of Paris, and they can be made into perfectly straight and cylindrical forms of from two to sixteen milli- metres in diameter, and half a metre in length When the electric light is to be used for illumination, it is necessary that it should be as continuous as other modes 13 of lighting. For this purpose nbt only should the current be regular in its action, but the distance between the carbon points must not alter, which necessitates the use of some arrangement for bringing them nearer together in propor- tion as they are consumed. Much ingenuity has been displayed by electricians in solving this problem, and the automatic contrivances invented by Staite,Duboscq, Foucault, Serrin, and others, leave little to be desired in regard to the steadiness of the light, when the regulators are in good order, and in the hands of intelligent operators. All auto- matic instruments, however, from the delicacy of their mechanism, are liable to derangement, and their action is not easily understood by persons not having a special knowledge of their construction. To obviate the objection to the use of such instruments by unskilled attendants, I devised, a few years since, a regulator for use on H.M/s ships of war, to be actuated by hand. In this arrangement the carbons are made to approach and separate from each other by means of a right and left handed screw connected with the carbon holders. Each of the screws, with its car- bon holder, can be actuated independently of the other, for the purpose of adjusting the points of the carbons to the proper focus of the optical apparatus used in connection with it. The regulator, with its carbon points, is placed in the focus of a dioptric lens, which parallelises the divergent rays of light into a single beam of great intensity. The lens with the regulator is pivoted horizontally and verti- cally on the top of a short iron column, fixed on a raised platform above the deck ; and the beam of light may be projected upon any distant object within its range. This special application of the electric light, however, as will be seen, requires the frequent adjustment of the carbons by the operator ; but as he is always required to be in attend- ance to manipulate the projector, no inconvenience is expe- rienced through the absence of the automatic arrangement. 14 This method of regulating the electric light has now been in use in the Royal Navy for more than three years, and has proved very satisfactory. Simultaneously with the progress of improvements in the mechanism for regulating the electric light, experiments have been made with the object of dispensing with the regulator altogether. The most recent, as well as the most successful, of these attempts has been made by M. Jablochkoff, a Russian inventor. In the specification of his letters patent of 1877, he proposes to place the carbons side by side (as had been previously proposed by Werderman in 1874), and to separate them by an insulating substance to be consumed along with the carbon. The inventor states that the insulating substance for separating the carbons may be kaolin, glass of various kinds, alkaline earths, and silicates, which he prefers to apply in the form of powder rammed into an asbestos cartridge case containing the carbons. A powder which the inventor found serviceable, consists of one part lime, four parts sand, and two parts talc. These materials are rammed into the cartridge case surrounding and separating two parallel sticks of carbon placed in the case, at a little distance apart. One of the carbons is made thicker than the other to allow for its more rapid waste. The lower ends of the carbons are inserted into pieces of copper tube or other good conductor, separated from one another by asbestos, and the ends of the tubes are pinched between two limbs of a screw vice, connected respectively to the conducting wires. This combina/tion of carbons and insulating materials the inventor terms an electric candle, which, when mounted on a stand or candle- stick, has the appearance of the Roman candle of pyro- technists. The inventor further states that the heat pro- duced by the electricity fuses the material between the carbons and dissipates it ; and the freedom of the passage afforded by the fused material to the electric current per- 15 mits the subdivision of the light by placing several lamps in the course of one electric circuit. It is also stated that the construction of the candle may be varied ; and, among the forms described, is one in which the carbons, instead of being contained in a cartridge case, are separated by a par- tition of kaolin or other similar insulating material. I have thought it well to describe, as nearly as possible in the words of the inventor, the electric candle, which is now the subject of so much attention in its application to electric lighting ; so that its relation to what follows may be more clearly perceived. A remarkable peculiarity of the direct current in electric lighting is that of its consuming the positive carbon at twice the rate of the negative one, and while the negative carbon is a pointed cone, like that of a pencil, the positive pole takes the form of a hollow cavity or crater. M. Jablochkoff’s early experiments seem to have been made with the direct current, and hence his carbons are described as being of unequal thickness in order that the positive and negative carbons of the candle might be evenly consumed. When the alternating current is used for pro- ducing electric light both carbons are of the same thickness, and are consumed at an equal rate, and both points termi- nate in regular cones. This property of the alternating current, besides other advantages, always maintains the luminous point in the focus of any optical apparatus used in connection with it, that is, when the carbons are placed end to end, as I had occasion to point out in a former paper read before the Society in 1873, on an Electro Magnetic Induction Machine for producing alternating currents. M. Jabloclikoff, in the course of his experiments, would appear to have met with some difficulties in adapting the direct or continuous current to a system of lighting with his electric candles, and now uses the alternating current for this purpose. The candle has also been simplified by 16 substituting a slip of plaster of Paris for the cartridge and partition of kaolin formerly employed. To produce the alternating currents, however, to supply a number of lights, it was found necessary to employ power- ful electro magnetic induction machines, excited by the currents from other smaller machines, according to the principles laid down in my paper read before the Royal Society, and published in the Philosophical Transactions of 1867. From 16 to 20 lights are produced from one of these electro magnetic machines, each light absorbing about one horse power. The system of electric lighting above described would now seem to be definitely established in some places as a substitute for gas, and visitors to the French capital during the present summer, will have been struck with the fine effects produced in the avenues and squares where the light is displayed. My connection with the history of this system of lighting, placed me in a position to make some experiments with the Jablochkoff candle, and led to the discovery of the following facts. One of the conditions necessary for producing a con- stant light from the candle, in its most recent form, was that the quantity and intensity of the alternating current should be such, that the carbons consume at a rate of from four to five inches per hour. If the electric current were too powerful, the carbons became unduly heated, and pre- sented additional resistance to the passage of the current; the points at the same time lost their regular conical form. If, on the other hand, the current were too weak, the electric arc played about the points of the carbons in an irregular manner, and the light was easily extinguished by currents of air. In the course of these experiments I was struck with the apparently insignificant part which the insulating material played in the maintenance of the light between the carbon 17 points ; and it occurred to me to try the effect of covering each of the carbons with a thin coating of hydrate of lime, and mounting them parallel to each other in separate hol- ders, and without any insulating material between them. The use of the lime covering was intended to prevent the light from travelling down the contiguous sides of the car- bons. On completing the electric circuit the light was maintained between the two points, and the carbons were consumed in the same regular manner as when the insula- ting material had been placed between them. Two plain cylindrical rods of carbon three sixteenths of an inch in diameter, and eight inches long, were now fixed in the holders parallel to each other, and one eighth of an inch apart. The strength of the alternating current was such that it would fuse an iron wire 0 025 of an inch in diameter and eight feet in length. On establishing the electric current through the points of the carbons by means of a conducting paste composed of carbon and gum, the light was produced, and the carbons burnt steadily down- wards as before. Four pairs of naked carbons mounted in this manner were next placed in series in the circuit of a four-light machine, and the light was produced from these carbons simultaneously, as when the insulating material was used between them. The light from the naked carbons was also more regular than that from the insulated ones, as the plaster of Paris insulation did not always consume at the same rate as the carbons, and thereby obstructed the passage of the current. This was evident from the rosy tinge of the light produced by the volatilisation of the calcium simul- taneously with the diminution of the brilliancy of the light from the carbons. The only function, therefore, which the insulating mate- rial performs in the electric candle, as shown by these experiments, is that it conceals the singular and beautiful 18 property of the alternating current to which I have directed attention. As I have already said, the strength of the alternating current must hear a proper proportion to the diameter of the carbons used, and when a number of such lights are required to be produced in the same circuit, the quantity and property of the current will remain constant, while the tension will require to be increased with the number of lights. This simple method of burning the carbons will, I believe, greatly further the development of the electric light, as the carbons can be used of much smaller diameter than has hitherto been possible. They may also be of any desired length, for as they are consumed they may be pushed up through the holders without interrupting the light. One of these developments will be a better method of lighting coal and other mines. In this application the alternating currents or waves from a powerful electro- magnetic induction machine may be used for generating, simultaneously, alternating secondary currents or waves in a number of small induction coils, placed in various parts of the mine. The light may be produced in the secondary circuits from pairs of small carbons enclosed in a glass vessel having a small aperture to permit the expansion of the heated air within. Diaphragms of wire gauze may be placed over the aperture to prevent the access of explosive gas. By generating secondary currents or waves without interrupting the continuity of the primary circuit, the con- tact breaker is dispensed with, and the subdivision of the light may be carried to a very great extent. 19 Ordinary Meeting, November 12th, 1878. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. E. W. Binney, V.P., F.R.S., said that on the 22nd January last he communicated to the Society a Notice of a Fossil Plant found at Laxey, in the Isle of Man, which was published immediately in the Proceedings. Now in Nature of the 81st of October appears a letter from Dr. Dawson, F.R.S., dated McGill College, Montreal, October 5, 1878, as follows: “ A Fossil Plant — Misquotation. In an article on a fossil plant from the Isle of Man in Nature, Yol. XVIII, p. 555 (September, 1878), the following sentence is attribu- ted apparently on the authority of Mr. Leo Lesquereux to my Report on the Devonian and upper Silurian plants of Canada ‘ that these fragments are probably originating in the upper Silurian of Gaspe ; that as they are found in the lower part of the limestone which underlies the Devonian Gaspe sandstone and become more abundant in the upper beds, this suffices to indicate the existence of the neighbour- ing land probably composed of Silurian rocks and supporting vegetation.’ On referring to the report in question I find that the original of this strange statement stands as follows : ‘ These remains of Psilophyton occur in the lower part of the limestone but are more abundant in the upper beds, and they suffice to indicate the existence of neighbouring land probably composed of lower Silurian rocks and supporting Proceedings— Lit. & Phil. Soc.— Vol. XVIII.— No. 3.— Session 1878-9. 20 vegetation/ I have no doubt that Mr. Lesquereux quoted from memory, and probably supposed that he was expressing my meaning, but an English writer should have referred to the original. I may add that the specimen referred to in Mr. Binney’s article does not exhibit the characters of my genus Psilophyton , which does not contain Mucoids’ but land plants of the rank of acrogens and of which not merely the exter- nal forms but also the internal structures are described and figured in the report referred to. The plant in question much more closely resembles Buthotrephis Harknessii of Nicholson from the Skiddaw slates/5 With all due deference to Dr. Dawson I fail to see why I should send to London in order to consult his original re- port. Professor Lesquereux had sent me a copy of his (the Professor’s) paper on Psilophytum cornutum published in the Transactions of the American Philosophical Society. This I received early in December, and immediately noticed the great resemblance, if not identity, of his P. cornutum with my Manx specimen. In noticing the latter I stated that I should give his description at length, and I accord- ingly gave it in inverted commas, word for word, including the part Dr. Dawson complains of. Surely he cannot seriously charge me with misquotation under such circum- stances ! However, the Professor’s offence, if any, was pub- lished in the Transactions of the American Philosopical Society for November last year, I believe, and it appears the Doctor does not set the public and himself right by commu- nicating with that society, but, without a moment’s delay, in October of this year, sends over to Nature his so-called mis- quotation and its correction, adding that I “as an English writer should have referred to the original.” Now as no 21 direct reference was made by me to the Doctor or any speci- men of his Psilophyton , none of which resemble the fossil plant described by me, I think he has no right to compel me to read over all his learned and voluminous works how- ever much he might think that I should be benefited by so doing. As to the Doctor’s opinion that my Manx plant resembles the Buthotrephis Harknessii of Nicholson, all I can say is that I have carefully compared the two figures of the speci- mens— Dr. Nicholson having kindly sent me a copy of his paper published in the Geological Magazine for November, 18G9 — and I see no reason to change my views. My Manx plant is without question the most like Professor Lesquer- eux’s figured specimen of Psilophytum cornutam, whatever that plant may prove to be, of all the fossil plants that have ever come under my notice. Any one may judge for him- self by comparing the published figures of the specimens. General Meeting, November 26th, 1878. J. P. Joule, D.C.L., LL.D., F.RS., &c., President, in the Chair. Mr. Francis Jones, of the Manchester Grammar School; Mr. Sidney Trice Martin, No. 1, George Street, Manchester; Mr. Peter Phillips Bedson, D.Sc., Owens College ; and Mr. Joseph Davies, Engineer, Manchester, were elected Ordinary Members of the Society. 22 Ordinary Meeting, November 26th, 1878. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. “On some Improved Methods of Producing and Regu- lating Electric Light,” Part II., by Henry Wilde, Esq. In a former communication to the Society, I directed attention to the fact, that when the electric light is pro- duced from the ends of two carbon pencils placed parallel to each other, if the strength of the electric current, the thickness of the carbons, and the distance between them are rightly proportioned, the carbons will burn steadily downwards until they are wholly consumed, without any insulating material between them. To initiate the light by this method, it is necessary to complete the electric circuit between the carbons by means of some conducting sub- stance, which volatilises on the passage of the current, and establishes the electric arc between the points. When a number of such lights are produced simulta- neously from the same source of electricity, any interrup- tion in the continuity of the current extinguishes all the lights in the same circuit, and each pair of carbons requires to be reprimed before the lights can again be established. This defect, as will be obvious, would cause great inconve- nience when the lights are not easily accessible, or are at considerable distances apart. In the course of my experiments it was observed that when the electric circuit was completed at the bottom of a pair of carbons close to the holders, the arc immediately 23 ascended to the points, where it remained so long as the current was transmitted. My first impression of this pecu- liar action of the arc was, that it was due to the ascending current of hot air by which it was surrounded. This how- ever was found not to be the cause, as the arc travelled towards the points in whatever position the carbons were placed, whether horizontally or vertically in an inverted position. Moreover, when a pair of carbons were held in the middle by the holders, the arc travelled upwards or downwards towards the points, according as the circuit was established above or below the holders. The action was in fact recognised to be the same as that which determines the propagation of an electric current through two rectilinear and parallel conductors submerged in contact with the terrestrial bed, which was described by me in the Philo- sophical Magazine , August, 1868. In all the arrangements in general use for regulating the electric light, the carbon pencils are placed in the same straight line, and end to end. When the light is required, the ends are brought into momentary contact, and are then separated a short distance to enable the arc to form between them. The peculiar behaviour of the electric arc when the carbons are placed parallel to each other, suggested to me the means of lighting the carbons automatically, notwith- standing the fact that they could only be made to approach each other by a motion laterally, and to come into contact at their adjacent sides. To accomplish this object, one of the carbon holders is articulated or hinged to a small base plate of cast iron, which is so constructed as to become an electro-magnet when coiled with a few turns of insulated wire. The carbon holder is made in the form of a riofit- O 24 angled lever, to the short horizontal limb of which is fixed an armature placed over the poles of the electro-magnet. When the movable and fixed carbon holders are brought into juxtaposition, and the carbons inserted in them, the upper parts of the two carbons are always in contact when no current is transmitted through them, as shown by the dotted lines in the engraving. The contact between the carbons is maintained by means of an antagonistic spring inserted in a recess in one of the poles of the electro-magnet, and reacting on the under side of the armature. One extremity of the coil of the electro- magnet is in metallic connection with the base of the carbon holder, while the other extremity of the coil is in connec- tion with the terminal screw at the base of the instrument, 25 from which it is insulated. The coils of the electro-magnet are thus placed in the same circuit as the carbon pencils. When the alternating current from an electro-magnetic induction machine is transmitted through the carbons, the electro-magnet attracts the armature and separates the upper ends of the carbons, which brings them into their normal position, and the light is immediately produced. When the circuit is interrupted, the armature is released : the upper ends of the carbons come into contact, and the light is produced as before. When several pairs of carbons are placed in the same circuit, they are, by this arrangement, lighted simultaneously. MICROSCOPICAL AND NATURAL HISTORY SECTION. October 7th, 1878. Charles Bailey, Esq., President of the Section, in the Chair. Professor W. C. Williamson, F.RS., made remarks on a series of Lepidodendroid Macrospores from the Halifax Coal Measures, as well as a series of reproductive crypto- gamic conceptacles from the same measures, and also exhi- bited some of these under the new Oil Immersion Lens of Zeiss of Yena, Mr. Plant exhibited a so-called Tree Onion from Canada. 26 November 4th, 1878. Charles Bailey, Esq., President of the Section, in the Chair. Mr. Plant, F.G.S., exhibited as additions to the Fauna of Cymmeran Bay, Anglesea, fine specimens of the Portuguese Man of War (Physalia pelagica), which came in with a S.W. gale, accompanied by many specimens of the Vellella. Mr. J. Cosmo Melvill, F.L.S., read an account of three visits paid by him to the Breidden Hills, Montgomeryshire, North Wales, in May, June, and July, 1877. The Breidden hills form an isolated range in the extreme north-east corner of the county, where it joins Salop, about ten or twelve miles due west of Shrewsbury, and three miles distant from Welshpool, from which town the best view of them is obtained, and where they are the most conspicuous objects to the north-east. The rocks are Lower Silurian, igneous and crystalline. Moel-y-Golfa, the southernmost peak, attaining an altitude of nearly 1500 feet, is formed of felspathic Trap and Ash; while Craig Breidden, the northernmost summit, and the intermediate hill, are both of Igneous Greenstone. The county of Montgomery being one of the nine men- tioned by Mr. Hewett C. Watson in his latest work — “Topographical Botany” — as being completely unworked, so far as Botanical data are concerned, renders any list of the plants interesting. Among a total of over 800 observed, the following catalogue represents the rarer species only : Ranunculus parviflorus (L.) Meconopsis Camhrica (Vig.) Corydalis claviculata (D. L.) Fumaria Borgei (Sm.) 27 Hesperis matronalis (L.) Cheiranthus cheiri (L.) Arabis — an hirsute varietas? — a form approaching A. arcuata of Grenin and Godron, and A. alpestris (Gor.), both of the flora of France — found sparingly by the waterfall, Craig Breidden. Teesdalia nudicaulis (Sm.) Lychnis Viscaria (L.) Moenchia erecta (Sm.) Cerastium semidecandrum (L.) Stellaria media (L.) var. neglecta. Hypericum Androssemum (L.) Geranium sanguineum (L.) Geranium lucidum (L.) Trifolium filiforme (L.) Spiraea salicifolia (L.) Potentilla rupestris (L.) On damp ledges in almost inaccessible spots near the waterfall, Craig Breidden. The only British station. Sedum Telephium (L.) Sedum anglicum (Hudson). Sedum Forsterianum (Sm.) Cotyledon umbilicus (L.) Saxifraga granulata ( L. ) Saxifraga hypnoides (L.) Helosciadium inundatum (Kosh.) Heracleum sphondylium (L.) B. angustifolium. Centranthus ruber (D. C.) Doronicum Pardalianches (L.) Centaurea montana (L.), naturalised near Welshpool. Erigeron acris (L.) Hieracium Pilosella (L.) B. pilosissimum, very hairy form with- out stolons, confined to Craig Breidden and the Channel Islands. Hieracium lasiopl^dlum (Koch.) Hieracium pallidum (Sm.) and its form maculatum. Veronica hybrida (L.) 28 Veronica scutellata (L.) Veronica raontana (L. ) Ajuga rep tans (L.) var. alba. Euphorbia Lathyris (L.) nr. Criggion. Ornithogalum umbellatum (L.) Likewise the Laburnum — Cytisus Laburnum (L.) occurred in a quasi-naturalized state on Moel-y-Golfa. Among Ferns and Fern allies the only ones observed were : Pteris aquilina (L.) Asplenium Ruta muraria (L.) Asplenium Trichomanes (L.) Asplenium adiantum nigrum (L.) Athyrium Filix. fcemina (Berch). Lastrea Filix. Mas. (Aich). Polypodium vulgare (L.) Polypodium Dryopteris (L.) Equisetum arvense (L.) Pilularia globulifera (L. ) Mr. M. M. Haktog (who was present as a visitor) said that when examining Desmids lately taken from a jar con- taining Chara, he had discovered a decided nucleus in the species known as Closterium aggregatum. 29 Ordinary Meeting, December 10th, 1878. J. P. Joule, D.C.L., LL.D., F.R.S., President, in the Chair. Among the Donations announced was a portrait of the late Professor Eaton Hodgkinson, presented by Sir Thomas Fairbairn, Bart. On the motion of Mr. Binney, seconded by Dr. Schunck, it was resolved unanimously : That the thanks of the Society be given to Sir Thomas Fairbairn, Bart., for his valuable Donation of a portrait of the late Professor Eaton Hodgkinson. “ On the Combinations of Aurin with Mineral Acids,” by R. S. Dale, B.A., and C, Schorlemmer, F.RS. In our last communication* we stated, that by the action of acetyl chloride on aurin, we obtained a colourless crystal- line compound, which we intended to examine more closely. We have since found that this body is identical with a compound, which Grabe and Caro~f° obtained by the direct union of aurin and acetic anhydride and having the formula C19Hl403+aH603. We also mentioned that the purification of this substance was found to be beset with several difficulties. The cause of this was found out after some trouble, but at the same time we were rewarded by the discovery of a series of re- markable bodies, consisting of combinations of aurin with mineral ^cids. * Proc. Lit. and Phil. Soc. — 1878, 141. t Ber. Deutsch. Chem. Ges. — xi., 1,122. Proceedings— Lit. & Phil. Soc.— Yol. X YIII.— No. 4.— Session 1878-9. 30 These salts, as we may call them, are "beautiful bodies, crystallizing exceedingly well, and although some of them are decomposed by water, they are very stable in dry air. To their discovery we were led by the following observa- tions. On heating aurin with glacial acetic acid and acetyl chloride, tire crystals lose at once their steel-blue lustre and assume a pale red colour. To obtain the compound thus formed in a pure state, acetyl chloride was added to a satu- rated solution of aurin in acetic acid. The liquid assumed at once a much lighter colour, and soon pale red needle- shaped crystals having a diamond lustre separated out. On recrystallizing these repeatedly from alcohol, we obtained oblong six-sided plates, which as analysis showed were pure aurin. On treating the original crystals with water, they become dull and brownish red, the solution containing acetic and hydrochloric acids. It therefore seemed not improbable that an additive product of aurin and acetyl chloride had been formed, containing however also acetic acid, as a superficial examination showed, that the liquid contained, to one mole- cule of hydrochloric acid, much more than one molecule of acetic acid. We therefore tried to obtain an analogous benzoyl -compound and to determine in it, after decompo- sition with water the relative quantities of hydrochloric and benzoic acids. On adding benzoyl chloride to a hot solution of aurin in acetic acid, similar crystals as before were obtained, which, after being dried on filter paper in dry air, were decompo- sed by water, but only hydrochloric and acetic acid went into solution, and on heating the product with water or alkalies but a mere trace of benzoic acid could be detected. These facts, coupled with the observation that the bright red needles which, as we stated in our former paper, are formed by crystallising aurin from hot aqueous hydrochlo- 31 ric acid, retain the latter obstinately, led us to the con- clusion that this acid forms a definite compound with aurin. Such a body could be formed under the above conditions, as our glacial acetic acid contained a little water. More- over, Mr. Charles Lowe had informed us that the splendid specimen of aurin which he exhibited at Paris was obtained in the following way. The crude but crystalline aurin, which is obtained by heating pure phenol with sulphuric and oxalic acids, was dissolved in alcohol and some strong hydrochloric acid added, by which a crystalline precipitate was formed, crystallising from hot acetic acid in beautiful red, glistening, flat needles. He was kind enough to give us a sample, and on examining it we found that water acted upon it in the same way as on our crystals. In order to prepare a pure compound for analysis, a hot solution of aurin in acetic acid was saturated with hydro- chloric acid gas ; the colour of the liquid changed into a light yellowish red, and soon the compound separated out in glistening needles, which, even when perfectly dry, smell strongly of acetic acid. When exposed to the air, they soon assume a steel-blue lustre and gradually crumble into a reddish brown crystalline powder. The same properties are shown by the crystals obtained from acetyl chloride and those obtained from Mr. Lowe. When heated to 110° in a current of dry air they gradually lose all the acetic acid, which plays the part of water of crystallisation, and assumes a dull red colour. On passing hydrochloric acid gas into an alcoholic solu- tion of aurin, similar but smaller needles are formed, con- taining alcohol, which is given off at 100° ; the dull red residue can, like the preceding one, be heated to 190° in a current of dry air without losing hydrochloric acid, which only begins to escape at 200°. Analysis of these compounds showed that the dried sub- stance consists of C19Hu03, HC1, while the crystals obtained 32 from an acetic acid solution have the composition C19H1403, HC1+2C2H402, and those from alcohol 2C10H19O3, HC1 + 3C2H60. When sulphuric acid is added to a hot alcoholic solution of aurin, small red needles are formed on cooling, which consist of (Ci9H1403)2 S04H2-f Alcohol. Under the same con- ditions an acetic acid solution yields fine prismatic crystals or flat, very glistening needles, which are an acid sulphate, its formula being Ci9Hi408, S04H2-f- Acetic acid. We have also prepared a nitrate which is readily formed and crystallizes well but have not analysed it yet. In our first communication to the Chemical Society, we described a compound of aurin and sulphur dioxide, which is easily obtained in bright red crystals by passing sulphur dioxide into a saturated alcoholic solution of aurin. Our former observation that this body contains water, but no alcohol, we found confirmed; on heating it decomposition easily takes place, pure aurin being left behind, but it ap- pears to be quite stable when exposed to the air, and even on heating it with water no sulphur dioxide is given off, but a drop of sulphuric acid added to the mixture is suffici- ent to evolve the gas abundantly. Aurin sulphite has the composition (Ci9H1403)2S03H2+4H20, As we have already showed, aurin forms very character- istic compounds with the acid sulphites of the alkali-metals, which in accordance with the newly established formula of aurin must now be written as follows : c19h14o3, so3kh C19H1403j S03NaH C19Hl4035 S03(NH4)H We have also found that rosolic acid, or the next higher homologue of aurin forms compounds with mineral acids which crystallize well. Being therefore a base like aurin, we think its name ought to be altered and, as it has only been obtained from rosaniline, propose for it the name rosaurm. 33 “ On the Estimation of Small Excesses of Weight by the Balance from the time of Vibration and the angular Deflec- tion of the Beam/’ by J. H. Poynting, B.A.; B.Sc. While working last year on an experiment to determine the mean Density of the Earth by the balance, I had to measure such an exceedingly small difference of weight, that I could not at that time estimate it by means of a rider but was obliged to adopt the method described in this paper. Stated generally it consists in treating the balance as a pendulum. Knowing the nature of the pendulum (that is its moment of inertia), and its time of vibration, we can calculate what force acting at the end of one arm of the beam will produce a given angular deflection. It is in. fact an application to the common balance of the method which has always been used with the torsion balance when it has been necessary to calculate the forces measured in absolute measure. I cannot find any record of a previous applica- tion of the method, and as it might be of use in very delicate weighings, or in verifying the small weights in a laboratory. I have thought it worth while to give a full account of it. When small quantities of the second order are neglected and the oscillations are of the first order, it will easily be found that the equation of motion of the beam of the balance is (MP + 2 Pa2) Q + (2P& + M glc)Q — ap (1) 9 where MI2 = moment of inertia of beam about central knife edge M = mass of beam a — half length of beam. P = weight of either pan and the mass in it. h — distance of line joining terminal knife edges below the cen- tral knife edge. h - distance of centre of gravity of beam below central knife edge. p = small excess in one pan. 34 0 = angular deflection in circular measure produced by p. 9 = gravity. If 0 = 0 we have the position of equilibrium given by. e = 2 MW* <2> The semi-periodic time is /MI2 + 2Pa2 ,=V mV+Mgl ^ From equations (2) and (3) we can eliminate 2P/&-f- Mgh, obtaining M^P + 2Pa2 0 p = id— 35 (4) M ag r w From this expression it appears that if we know the moment of inertia of the beam, its length, and the weight at each end, we can find the excess p from the time of vibration and deflection. The results given in this paper were obtained with a 16-inch chemical balance by Oe idling. The exact length of the half beam (a) measured by a dividing engine is 20*2484 centimetres. To find the moment of inertia MI 2 of the beam — The simplest way theoretically would appear to be this. Find the times of vibration tx t2 and the deflections 0i 02 due to the same excess p with two different loads Pi P2 in each pan. Equating the values of p given for each by equation (4) we have MyP 4- 2 Pi (I 02h2 MyP + 2P2n2_ 0p22 An equation which will give M(/I2 in terms of known quantities. But on trial it was found that a very small proportional error in the observed time made a large error in the value of Myl2, and the following method, that usually adopted in magnetic observations was employed in prefer- ence. A stirrup was suspended by a platinum wire and its 35 time of vibration (ti) against tlie force of torsion Qi) of the wire was observed. The moment of inertia of the stirrup being S we have ti = 7T^S fX The time of vibration (ti) was then observed when a cylin- drical brass bar of known moment of inertia B was inserted in the stirrup. We now have ti = 7T2(S + B) The bar was then removed and the balance beam inserted in its place, and the time of vibration (tf3) gives ti = 7T2(S + MI2) From these three equations eliminating S and fx we obtain Mp_Bfe2-^) iVJ~L “ / 2 / 2 Now Bg was calculated from the weight and dimensions of the bar to be 6332.83 (in centimetres and grammes). The observed times were tx = 3.6792// ; U = 4.495" ; tz-l.\ 483" ; From these values we find My I2 = 35651.6* To measure 6. The angle of deflection was measured by the number of divisions of the scale which the pointer moved over. As the length of the pointer is 32T006 centi- metres, while 20 divisions of the scale measure 2*5658 centimetres, a tenth of a division, in terms of which the deflection was measured corresponds to an angle of 0’0003996. The oscillations were observed from a distance of 6 or 8 feet by a telescope. The resting point (i.e. the point where the balance would be in equilibrium) was found in the usual way by observing the three successive extremities of two swings and taking the mean of the second and the * To this a small correction should be added if the adjusting bob is not in its lowest position. This amounts to 7.6 for each turn of the screw and may therefore in general be neglected. 36 mean of the first and third. Five determinations of the resting point were usually made with the excess to he measured alternately added and removed. From these five, three values of the deflection (n) due to the excess were calculated in a manner which will be seen from the example below. The time of vibration.. — This was found from several determinations of the time of ten oscillations. The method will be seen from the example. No correction was needed for the resistance of the air as long as the vibrations did not exceed two divisions of the scale. When however they were much more than that the time of vibration was found to increase with the arc. As the time of vibration fre- quently changes slightly, probably through variations of temperature, it was usually observed before and after the determination of the deflection (n) and the mean of the two taken as the true time. The following example of the determination of the value of a centigramme rider by placing it half way along the beam wifi sufficiently explain the details of the method. TIME OF VIBRATION AT COMMENCEMENT, POINTER APPARENTLY MOVING FROM POINTER APPARENTLY MOVING FROM LEFT TO RIGHT. RIGHT TO LEFT. No. of Vibration. Observed time of passage of pointer through resting point. No. of Vibration. Observed time of passage of pointer through resting p’t. Time of 10 Vibrations. No. of Vibration. Observed time of passage of pointer through resting point. No. of Vibration. Observed time of passage of pointer through resting p’t. Time of 10 Vibrations. 0 llh 15' 36" 10 17' 43" 127 1 llh 15' 49" 11 17' 56" 127 2 16' 1" 12 18' 8" 127 3 16' 14" 13 18' 21" 127 4 16' 25"-5 14 18' 33"k5 127, 5 16'39"-5 15 18' 46" 126-5 6 16' 52" 16 18' 59" 127 j 7 17' 5" 17 1 19' ll"-5 126-5 Mean value of 10 vibrations.. 1271 1 Mean value of 10 vibrations.. 12675 Mean of means 126-875. i, = 12-6875" 37 DETERMINATION OF DEFLECTION U. Excess Weight. Extremities of Oscillation. RestingPoint. Mean of prece- ding and succeeding resting points. Deflection due to Excess. Added 109 96 ]09 102.5 i Removed 93 40 92 66.25 102.25 36 Added | 152 53 150 102 66.75 35.25 Removed 80 55 79 67.25 102.5 35.25 Added 147 60 145 103 Mean value of n — 35.83. TIME OF VIBRATION AT END. POINTER APPARENTLY MOVING PROM , POINTER APPARENTLY MOVING FROM LEFT TO RIGHT. | RIGHT TO LEFT. No. of Vibration. Observed time of passing of pointer through resting point. No. of j Vibration. Observed time of passage of pointer through resting p’t. Time of 10 Vibrations. i No. 'of Vibration. Obstrved time of passing of pointer through resting point. t/5 Observed § 1 time of .43 passage of o g pointer ^ £ through resting p’t. Time of 10 Vibrations. 1 0 llli 26' 19" 10 28' 27" I 128 1 1 26' 32-5" 11 28' 39" 126.5 2 26' 44"- 5 12 28' 53" 128-5 3 26' 58" 13 29' 5" 127 4 27' 10" 14 29' 18" 128 5 27' 23-5" 15 1 29' 30"-5 127 6 27' 35"-5 16 29' 44" 128-5 7 27' 49" 17 29' 56"-5 127-5 Mean value of 10 vibrations.. 128-25 ■ Mean value of 10 vibrations.. 127 Mean of Means=:127-625. ^=12-7625. — — — I Remembering that one tenth of a division of the scale is an angle of *0003996 in circular measure formula (4), ex- pressed in milligrammes, becomes 11 i/2 p = -p 0-3996^-(Mc/I2 + 2 Pa2) 38 In our present example n — 35-83 tz=h±h = 12-725" Myl2== 35651 2Pa2 = 94704* p = 5’ 724 milligrams. The length of time occupied in this determination was not quite a quarter of an hour. The following table contains a series of results which I have obtained of the weight of two centigramme riders, the first of which was accidentally destroyed after the conclu- sion of the 4th determination. As the rider was always placed at division 5 on the beam, the values given in the table are double those actually obtained. No. of Experi- ment. M0l2+2Pa2 t in seconds. n Weight of rider in milligram- mes. Mean Value. 1 145364 8-921 13*458 9*78 \ 2 309356 1765 25*49 10-05 3 519769 20-435 19-12 9-55 f / 9*96 mgms. 4 130355 13‘10 34-71 10-47 J 5 130355 12-87 36-6 11-44 6 130355 12-72 35-50 11-35 7 130355 12-725 35-83 11-45 / z1 11*35 mgms. 8 ! 130355 12-81 35-5 11-20 9 130355 12-903 36-37 11-31 / 10 , 454405 19-406 , 22-08 10-58 * For this as for several other cases I removed the pans and hung the weights directly by fine wires from the suspending-pieces. By this means the resistance of the air was very much diminished. 39 Ordinary Meeting, December 24th, 1878. J„ P. Joule, D.C.L., LL.D., F.RS., President, in the Chair. “ Note on the Intensity of Moonlight,” by Harry Grim- SHAW, F.C.S. At the meeting of this Society held on the 26th of November of the present year, some remarks were made upon the relative intensity of moonlight, daylight during a thick fog, and the diffused light of the electric arc. The opinion was then expressed by some members that it was very doubtful whether it was possible to read printed type of anything like a small size by the brightest moon- light in this country. The light of the moon on the 8th of the present month (December) being of considerable intensity, I took the opportunity of making the experiment, which I have pre- viously, at different times, performed more roughly, with sufficient accuracy to form some standard of comparison. The result was that I found it possible to read with cer- tainty a still smaller type than I had previously known it possible to peruse. The types on which I experimented were those of a newspaper, and known technically by the printers as “ minion,” “bourgeois,” and “nonpareil.” These are all smaller than the letters of the “Proceedings” of the Society, which I believe is called “small pica.” The two first are what are ordinarily used for such printing as that of news- papers and the cheaper periodicals, whilst the last (“non- pareil”) is a very small letter indeed. The last paragraph of this note is printed in the type in question. The printed matter in the “minion” and “bourgeois” letter was read with Peoceedings— Lit. & Phil. Soc.— Yol. XYIII — No. 5.— Session 1878-9. comparative ease ; the “ nonpareil” had to be perused slowly, but could be made out with certainty. The time at which the above experiment was performed was 8.15 p.m., and the evening of course bright and cloudless. The moon was full at 7.49 p.m. the following evening. The observers were three in number, who ail succeeded in reading the three types, and it should perhaps be added, as a quantity affecting the results, that the “ eyes" were all comparatively young, being under the age of thirty. Ordinary Meeting, January 7th, 1879. J. P. Joule, D.C.L., LL.D., F.R.S., President, in the Chair. “ On Boulders of Clay from the Drift,” by E. W. Binney, F.B.S., F.G.8. In making the new railway from Manchester through Cheetham Hill to Kadcliffe, a fine section of the drift depo- sits has been exposed in the cutting at Moss Bank, south of the bridge near Crumpsall, at an elevation of 207 feet above the level of the sea. The beds occur in the descending order as follows : ft. 1. Clay containing a few pebbles , . . . . 12 2. Sand with beds of fine gravel 20 3. Clay containing the boulders of clay exposed. 1 2 The first-named bed would be termed by Professor Hull, F.B.S., upper boulder clay, the second middle sands and gravel, and the third probably lower boulder clay. — See his paper on the Drift deposits in the neighbourhood of Man- chester, published in vol. II. (third series) of the Society’s Memoirs. In No. 2, which is composed of fine stratified sand parted by thin beds of gravel and deposits of drifted coal, are found some basin-shaped deposits of gravel about 3 feet long and 1 foot 6 inches deep, which not only contain the pebbles usually found in the till much rounded, but also 41 rounded pieces of till or boulder clay of lenticular and sphe- rical shapes, varying in size from one to three inches through their major axes. The specimens on the table are three taken out of the cutting by myself, and are a fair sample of the average boulders. There is not a section of the whole of the drift deposits at Moss Bank, but at the Manchester Workhouse, about quarter of a mile distant, the following deposits occur, the second being the equivalent of No. 1 in the preceding sec- tion : ft. in. Clay with a few pebbles 21 0 Quicksand 26 0 Loam 0 4 Clay 30 0 Clay in laminae 5 0 Clay with stones 4 0 Hard clay 0 6 Sand 2 0 Gravel 7 6 Clay (till) 25 0 Sand with small stones (thickness not given). Rock (trias). To my knowledge no instance of boulders of clay in drift beds has been published. Many years since, when, obser- ving the fine cliffs of till at Blackpool, I noticed how the waves rounded the stones from that deposit which fell down on the shore, and I also saw a few of the pieces of clay rounded as well. In the last December number of the Geological Magazine is a description of some clay boulders by Mr. T. Melland Reade, F.G $., lately observed by him on the Crosby shore near the river Alt. After describing a trench about 50 yards long, 5 feet wide and 2 feet deep, cut in the blue clay which underlies the peat and forest bed,* and which formerly had only a deposit of sand at the bot- * Quart. Jour . Geol. Soc., vol. xxxiv. p. 447. 42 tom, he says “ that at the present moment it is filled up nearly to the surface with an agglomeration of rounded lumps of clay more or less compacted together. The clay boulders, for such they are, vary in size from 18 inches on the longer axes to the size of a bean, and from a spherical to an ellipsoid figure/’ “ We have not far to seek for their origin, as a visit to the lower edge of the peat frayed into a sort of a subtidal cliff or series of cliffs by the encroachments of the sea, shows a deposit of similar clay boulders at its base. In the neigh- bourhood of the beach the river Alt, meandering over the shore, has made inroads on the post-glacial deposits which compose the substratum, forming a subtidal river cliff of blue clay at its western margin. Lumps of this clay under- mined by the currents fall, break up into pieces, and get rolled into boulders by the action of the tide. The trench has formed a sort of trap for catching and retaining them. The clay boulders are in contact, and become in the trench compacted together into one solid mass, so that if it were converted into rock its structure would show in some cases distinct argillaceous boulders in a sandy argillaceous matrix, and in others an imperceptible shading of the boulder nucleus into the matrix.” The boulders of clay found at Moss Bank have in all probability been formed in a similar manner to those de- scribed by Mr Reade, as they are found in a hollow in the sand of a basin-shape in vertical section, which would be somewhat like the trench described by him, having fallen from an old cliff of till and been rolled by water into the place where they are now found. In the sand are sometimes found minute fragments of shells, but in such a state that it is impossible to determine what they are. 48 Ordinary Meeting, January 21st, 1879. J. P. Joule, D.C.L., LL.D, F.R.S., President, in the Chair. “On an Old Letter of the late Sir Walter Scott.” E. W. Blnney, Y.P., F.R.S., F.G.S., said that on March the 16th, 1868, he exhibited at the Society’s meeting an original letter of the late Sir Walter Scott, dated the 4th June, 1802, on the subject of an old Scotch Ballad called Jock o’ Milk. Since that time he had come into possession of another letter of the baronet’s, as well as one from Mr. Liddesdale. They are as follow : — “Sir, — I am honored with your very obliging favour, and beg leave to express my best thanks for the information which it so handsomely communicates. In the late Mr. Riddell of Glenriddle’s MS., which I have frequently re- ferred to in the late compilation, there is a copy of the Ballad called Jock of Milk , which I examined very atten- tively. I was only deterred from publishing it by the strong doubts I entertained of its authenticity, as it appeared to me to bear more the character of an imitation than of a real ancient ballad. It is very possible, however, that I may be mistaken, or that the copy I have seen may be interpolated, and I shall be very much gratified indeed by your furnishing me with the copies which you have so handsomely offered to send me, with as much of the tra- ditionary history as you recollect. I should be also much interested to know whether the verses were taken down from recitation or from a MS., ancient or modern. I have been very desirous as far as possible to ascertain the authenticity of the old poems which I have given to the world, as literary forgeries have been but too often and too justly imputed to the Scottish antiquaries. The Galliard Proceedings — Lit, & Phil. Soc. — Vol. XYIII. — No. 6. — Session 187S-9 44 mentioned in your fragment was, I believe, a castle upon the Seine belonging to the French monarchs, which gave a name to the favourite dance there practised, just as a more modern dance was called the Louvre , and as we call our Highland dance a Strathspey. I beg you to believe that I am extremely sensible of your polite attention to the re- searches of a total stranger, and that I feel myself very much gratified by the interest you have taken in them. “I have the honor to be, Sir, “Your obliged and faithful servant, “Walter Scott/7 “ Laswade Cottage, “ near Edinburgh, “2 April, 1802.” “ R. Cleator, Esquire, “ Cropton Lodge, near Pickering, Yorkshire.” “East Wood, 9th April, 1802. “ Hear Sir,™ I am this morning favoured with your letter of 7th, and lose not a moment in complying with your desire. The old ballad of Jock o’ Milk was given to me by Mr. Bell Irving, of Whitehill, and the notes thereon were collected from old tradition, but really not having a copy by me I cannot bring the whole to recollection. Mr. Bell Irving’s grandfather, old Whitehill, was many years factor or steward to the family of Castle Milk, and having access to the Repository of all the deeds and papers belonging to that antient place, lie found this ballad amongst them, so the present Mr. Bell Irving informs me. From many enquiries amongst veiy old people now no more, I could perceive there had been such an old ballad, but of which they had a very imperfect idea, but some time it strikes me that two verses are added by the present Mr. Bell Irving. This, however, you can easily detect by writing to him for every 45 particular, and you can then see that if it tallies with what he told me. His direction is W. Bell Irving, Esquire, of Whitehill, near Ecclefechen, N.B. If you have leisure, and could take the trouble to copy the old ballad, with notes, &c., I should then be able to point out something more satisfactory than the above imperfect account is. — Believe me ever “ Yrs truly, “ ft, Liddesdale” “ William Cleator, Esqre, “ Cropton Cottage, near Pickering.” From the letter formerly published it does not appear that Sir Walter Scott had ever his doubts removed as to the genuineness of the old ballad. The above letters are published in the hope that some reader may possibly take up the subject and clear up the doubts, if this has not already been done. “On a further Analysis of the Water of the Mineral Spring at Humphrey Head,” by C. Grimshaw and H. Grimshaw, F.C.S. At a meeting of this Society held on November the 28th, 1876, one of us, in conjunction with Mr. J. Barnes, read a paper on some analyses of this mineral spring, samples having been taken in the month of August in 1875 and 1876 respectively. The above quoted paper also referred to an analysis of the water of this spring by T. E. Thorpe, F.R.S., in the year 1868. It was noted that during this period the composition of the mineral matter contained in the water had remained remarkably constant during this period of eight years ; and it was also proposed to ascertain, after the lapse of another period, whether this constancy was still maintained. The results of analyses performed with this view on a sample taken on August 16th, 1878, we now beg to lay 46 before the Society. The following are the numbers ob- tained : (1) Total solid matter— -50 cc. evaporated and dried at 100°— 110° C. gave 03735 grms. (2) Chlorine — (a) 5 cc. took 16-6 cc. standard silver nitrate (1 cc. = 1 mgrm Cl). (b) 5 cc. took 16-8 cc. standard silver nitrate (1 cc. = 1 mgrm. Cl). 300 cc. of the water gave (3) Silica .. 0'004 grms . Si02, (4) Iron and alumina — equal .. 0-009 „ Pe203 (5) CaO— .. 0-2125 „ CaO (6) Mg2P207 — 0-1665 containing... .. 0-06 MgO (7) PtKaCV- 0-142 „ .. 0-0433 „ KC1 A calculation of these figures gives the following results : Silica (Si02) 0-90 grains per gal. Iron and alumina, as (Fe203) . 2-10 Lime (CaO) . 49-58 Magnesia (MgO) . 14-00 5) Sulphuric acid (S03) . 76-58 5? Chlorine (Ci) .233-80 >> Alkaline metals and carbonate .. .145-94 522-90 A recalculation of the above results on the assumptions as to combination of our previous analyses gives the fol- lowing : Silica 0.90 grains per gal. Iron and alumina . 2-10 Calcium carbonate . 8-40 }) Calcium sulphate .109-72 }f Magnesium sulphate . 18-06 ft Magnesium chloride . 19-00 5) Potassium chloride . 10-11 Sodium chloride ,354-22 522*51 47 By an oversight in our analysis of November, 1876, the potassium chloride is made 84 instead of 8‘4, which of course affects the proportions of the two alkalies, but does not alter the relations of the other salts. The potash in the present analysis was determined directly, but in the former by difference from the total alkali and chlorine. On comparison, the water of this spring in the different years alluded to will be found to contain a very constant amount of mineral matter, which does not vary in compo- sition to any great extent. The respective amounts of dif- ferent years are as follows : 1868 — Thorpe 508 '5 grains per gal. 1875 — J. B. and H. G 5 10 ’3 ,, 1876— J. B. and H. G, 514-6 „ 1878— C. G. and H. G 522-5 „ The flow of water on August 16th, 1878, was at the rate of half a gallon per minute. This is just half the rate found by Thorpe in 1868, who during the previous two years had found the flow very constant. A long period of small rainfall occurred just previous to the date of our sample. We may add, that in a paper read before this Society (Second Series, Yol. XII.) by Mr. Binney, F.B.S., will be found some additional information as to the geological strata of the locality of Humphrey Head, accompanied by a section of the Head and the neighbouring point, which agree with the remarks on this point in our previous paper. 48 MICROSCOPICAL AND NATURAL HISTORY SECTION. December 2nd, 1878. Charles Bailey, F.L.S., in the chair. Mr. Plant, F.G.S., stated that a specimen of the Black- throated Wheat-ear (Saxicola stapazina, Temminck.) had been shot at Raw tens tall, near Bury, Lancashire. Professor W. C. Williamson, F.R.S., remarked that the ' supposed Radiolarium from the coal measures that he had lately brought before the notice “of the Section, had been submitted to Professors Haekel and Strassburger, and pro- nounced by them both to be a spore. Mr. Marcus M. Hartog, F.L.S., read a paper entitled “ A Preliminary Abstract of an Investigation of the Nervous System of Cyclops.5’ Two descriptions exist of the Nervous System of Cyclops ; one by Zenker, who describes a chain of ganglia ; another by Claus, completed by Leydig, correct so far as it goes, of a brain, an aesophageal ring, and a ventral cord, only seen in the last two thoracic segments, after which it is described as forking. These last observers also describe the anten- nary nerves as having each branch thickened in its course into a ganglionic ring. I am able to confirm this, and to add the following points : — The ganglionic swellings are found near the terminations of all sensory nerve fibres. I have succeeded in seeing the central nerve cord more fully, i.e., from the 2nd thoracic segment onwards. At the end of the 3rd segment it gives off a pair of nerves which pass 49 superficially over the ventral surface of the next segment to the integument. At the end of the 4th segment not only are there a pair of sensory branches given to the rudimen- tory appendages, but just before a pair are given off to the two large ventral muscles (originating from the sternum of the 5tlr segment), on which each ends in a beautiful nucleated Doyerian eminence. In the 1 st abdominal seg- ment is the fork described by the two German observers, but this takes its origin from the superficial (ventral) aspect of the cord which is continued onwards under the colleterial gland. After running obliquely outwards each branch of the fork subdivides into two, an anterior sensory and a posterior muscular branch. At the commencement of the third abdominal segment the ventral cord forks, its branches diverge slightly in this segment, but more in the next, rising to the sides of the intestine, and having the ventral muscles of this segment superficial to them. In the last segment they have left the intestine and run about the horizontal median plane straight into the axis of either branch of the furca. I have only been able to detect two crystal spheres in the eye of Cyclops; the anterior one in Cyclopsine is here absent. What seemed to me to be pits with a small mouth so as to form a nearly complete sphere occurring in the rudimen- tary legs of the last thoracic segment are probably sense organs. The ventral cord in Cyclopoids contains the elongated nuclei everywhere found on nerve cords, but no ganglion cells ; it has lost its significance as a sense organ, and is purely commissural. No transverse commissures are found any- where, even after its bifurcation. The cells on the sensory nerve fibres suggest a functional displacement outward of the local nerve centres. Note added January 20th, 1879 ; In the above abstract I have referred to a vesicle seated at 50 the base of the hfth segment, and apparently opening exter- nally. Further work has shown to me that this is always seated on the ganglionic enlargement of the nerve that supplies the appendage ; that it opens at the ring marking the insertion of the appendage ; that in the male it contains one or several irregular brightly refractive bodies, floating freely in its cavity. Hence I regard this organ as an ear, less developed in the female than the male. At p. 180, vol. 15, of the Proceedings of the Literary and Philosophical Society Mr. Plant described a “Beetle of good omen from Yucatan,” at which time he was unable to give the generic and specific name. This can now be sup- plied, as a similar specimen has been shown at a meeting of the Entomological Society of London, by Mr. Randolph Clay, from Mexico, and recognised as Zopherus Bremei. 51 Ordinary Meeting, February 4th, 1879. E. W. Binney, V.P., F.R.S., F.G.S., in the Chair. “ The Area of the Middle Drifts as determined by their Contents,” by Alfred Bell, F.G.S. Communicated by R. D. Darbishire, F.G.S. The author, in working out the area of the middle drifts, commenced by pointing out the confusion produced by the sands, gravels, and boulder clays of the kingdom being con- sidered, as has been done by some geologists, of the same age. In proving this he has quoted the various forms that characterise the different deposits, showing that in some, as at Wexford, Bridlington, and in Scotland, the fauna under- lying the boulder clay contains many arctic forms which are wanting in the sands immediately above. These sands he further traces by their contents over the middle east coast of Ireland, the western and midland counties of England and Wales, the Isle of Man, and the east and south coasts of England. Having enumerated some of the derived rocks, obtained in one pit alone, with numerous crinoids and corals, a brief reference was made to the number and com dition of these latter forms, 35 species of which he had found in one collection alone. Having pointed out the character of the middle glacial marine fauna, he proceeds to show that the land fauna has been subject to the same mutations, the fauna following the climate. A list of shells, about 140 species, obtained from the drift gravels, forms an appendix to the paper. Proceedings— Lit. & Phil. Soc.—Vol* XYITL- No. 7.— Session 1878-9, 52 Ordinary Meeting, February 18th, 1879. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair. James Bottomley, B.A., D.Sc., and Richard S. Dale, B.A., were appointed Auditors of the Treasurer’s Accounts. “On a Chemical Investigation of Japanese Lacquer, or * Urushi,’ ” by Sad amu Ishimatsu. Communicated by Professor Roscoe, LL.D., F.RS. During a few months last year I had the opportunity of examining roughly into the nature of “Urushi” in the Laboratory of Tokio University. The specimen of lacquer which I had under my examina^ tion was obtained from Kuyemon Nakamuraya, in Tokio, a large lacquer merchant. It is a milky juice of pale grey colour, and gives out a certain kind of poisonous volatile gas. Some persons are terribly attacked by this poison, producing a great swelling where the acid comes in contact. During my examination in the laboratory one of the apparatus keepers was terribly attacked by this gas, producing ugly swellings all over the face. He told me at the time it was exceedingly itchy. By using the solution of chloride of sodium, carbonate of soda, acetate of lead, &c., he was said to have recovered within a week. This poison acts only on certain persons. I had to work with it for many days, yet never had any attack of the kind nor felt any uneasiness from it. It has a sweetish characteristic smell and has an irritating taste. It burns with very luminous flame, evolving dense black smoke like oil of turpentine. 53 It is to a great extent soluble in benzole, ether, absolute alcohol, &c., leaving behind a blackish grey residue in which gum was found. Lacquer on exposure to the atmosphere rapidly loses its weight and at the same time blackens on its surface ; although this loss is different in different specimens, yet on the average of those which I have examined it seems to vary from 25 to 37 per cent. When the lacquer is exposed to the action of sunlight in hermetically sealed vessels in the atmosphere or in carbonic acid, blackening does not take place, but a large quantity of moisture collects on the sides of the vessel. The loss of weight in the atmosphere is almost if not en- tirely due to the escape of water, with a minute quantity of carbonic acid which may be formed by the oxidation of some organic compound existing in the lacquer. The attempt has been made to estimate the relative amounts of carbonic acid and water, yet it was not successful at the time, being too difficult, and it must be left open to some future inves- tigation. It is by many supposed to be due to the combined action of light and air that the blackening of lacquer in the air takes place ; but this seems to be erroneous from the follow- ing experiments. First, I made a square box which had a well fitting sliding door and the inside of which was made perfectly black, so that practically no light is admitted to enter. In it was placed a small quantity of lacquer at dark and the door closely shut ; on looking at it the next morn- ing it was observed that the lacquer had turned perfectly black, proving that it is not the light that blackens the lacquer. Second, the bottle in which I kept my lacquer for more than three months during my examination was exposed to the incident light of the laboratory; the surface of the lacquer was turned perfectly black, forming a wall as it 54 were, while those portions which were in contact with the sides of the bottle, which receive as much light as if there were not any glass sides before it, were not at all blackened. This phenomenon is just complementary to the first one, proving that the blackening in the atmosphere is in all probability due to the oxygen of the air, but not the light alone, nor the combined action of light and air. The lacquer when distilled with water gives a colourless distillate which is slightly acid to test paper, and the attempt has been made to examine the acid, but not successfully on account of too minute quantity of the sub- stance evolved. Distillation by itself and in a current of steam was tried also, but the results in both cases were the same as the first one. Lastly distilled with a small quantity of dilute sulphuric acid, to aid the substance to distil over, into sugar of lead, scarcely any precipitate was obtained. Lacquer mixes with any kind of fixed oil in all propor- tions ; hence oil is often added as adulteration, but some- times it is purposely added to increase its mobility. The specimen of lacquer which I examined consisted of the following three substances : Part soluble in absolute alcohol I. II. (resin) 58*24 58*23 Gum 6*34 6*30 Residue 2-24 2*30 Moisture and other volatile matter 33*175 33*170 100-00 100*00 As I have already mentioned, the lacquer loses its weight very rapidly when exposed to the atmosphere. For the above determination I weighed out each time samples from well stoppered bottles, and determined the weight by difference. Then this was treated with absolute alcohol and 55 the filtrate evaporated to small bulk and dried in an air-bath at 1 00° C. until the weight remained constant. This is put down as the part soluble in alcohol in the above analysis. The residue was then treated with hot water and the filtrate evaporated and dried at 100° and weighed as gum. The residue after the gum had been removed was then washed and dried on weighed filter at 100° C. and weighed as residue. The moisture and other volatile matter were of course determined by the difference. The estimation of the amount of part soluble in alcohol after the lacquer has been exposed to the sunlight in open vessel for some 20 or 30 days shows that the soluble part increased up to 72-82 per cent. This number when calcu- lated for the substance to have lost 28 per cent moisture and other volatile matter during exposure, then equals to 58*3 per cent, which is nearly equal and practically the same as the analysis previously given, hence there seems to have been no material change in the amount of matter soluble in alcohol. Now the perfectly dried lacquer after finely powdered was dried at 100°, and analysis gave Fart soluble in absolute alcohol 18*07 Gum 3*63 Kesidue 78-30 100-00 Altogether from this analysis, the residue being increased, the lacquer seems to have undergone some change, but pos- sibly this is owing to the fact, that the alcohol as well as water seem to have had less complete access to the material. Thus the “ Urushi” consists of three principal constituents, (1) a resinous part soluble in alcohol, (2) gum, and (3) residue. Although there are, in addition to these, water and volatile matter, as they go away sooner or later before it is used, they are not properly called the constituents. (1.) Part soluble in alcohol (resin) seems to be the principal 56 portion, and has a smell like ordinary lacquer, but it never dries as the original does. It is brownish black, and slightly sticky to the touch. When treated with potash solution it forms a bluish black precipitate, but nothing is obtained on addition of sulphuric acid to the filtrate. When boiled with hydrochloric acid the resin is transform- ed into a substance elastic while hot, something like the mass obtained when heated sulphur is dropped into cold water. When boiled with nitric acid, nitrous fumes are given out, and the mass gradually becomes yellow, and finally a beautiful orange coloured mass was obtained. This mass was washed with hot water several times and then treated with absolute alcohol; the mass was to a great extent soluble in the alcohol, leaving behind a small quantity of a yellowish body (which I think to be part not sufficiently acted upon by the acid.) This alcoholic extract forms a beautiful yellow pre- cipitate with both nitrate of silver and acetate of lead. I took a quantity of alcoholic extract, precipitated it with acetate of lead, and the precipitate was thoroughly washed with abso- lute alcohol and then decomposed by means of dilute sulphuric acid. (It might be better to decompose this salt with sulphuretted hydrogen, but we cannot do so on account of reducing action of this gas.) The mass was dissolved again in absolute alcohol, then separated from sulphate of lead. Now then this separated alcoholic extract was again pre- cipitated by sugar of lead, and after filtering and washing, the precipitate was dried partially in an air-bath and carried under the receiver of an air-pump and dried over sulphuric acid. This lead salt exploded when heated. The amount of lead was estimated as oxide by igniting it with nitric acid. 57 And the salt was subjected to organic combustion. Nitro- gen was determined by Dumas’ method. The following numbers were obtained as the mean results : — Carbon 2 6 ’9 3 Hydrogen 4T1 N02 18-44 PbO 47 42 Oxygen 3*10 100-00 Now I prepared the silver salt of the same and obtained 18*5 per cent of silver as the result. It seems to give no help as to the formula of this body. As such was the case, I took alcoholic extract of the original lacquer and precipitated it with acetate of lead, and after requisite purification and drying the precipitate was analysed. Lead determined as before. The following is the mean of the results of two experiments which I was only able to try : Carbon 50 ‘450 Hydrogen , 5*705 PbO 3-775 Oxygen 40-070 100-000 (2.) The gum is soluble in cold as well as in warm water. It has no smell, almost no taste, it has a yellowish or rather brownish colour, and is of a non-crystalline body. It is quite insoluble in alcohol. On subjecting this substance to organic analysis I got the following percentage of hydrogen, carbon, and oxygen : I. II. Carbon 41-20 41-45 Hydrogen 6-51 6-58 Oxygen 52-29 51-97 1C0-00 100-00 58 These analyses yield a formula approximating to the composition of common gum. (3) The residue is, I think, nothing more than the mixture of cellusose, bark, dust, &c. In concluding my paper I must say that I am not at all satisfied with my present analyses, but I thought it might be of some interest to some of you from the point that, although the varnished articles from this juice are so celebrated, yet as far as I am aware, this is the first analyses of the kind that has been heretofore attempted, and might be of some use to those who are interested upon this subject. Mr. William E. A. Axon called attention to the interest- ing brochure on the arbre-d-lctque, by M. Paul Ory, pub- lished in Paris in 1875, a copy of which he exhibited. M. Ory was the first to give in a European language (French) an accurate account of the method by which the tree was cultivated and the sap extracted, and his description was illustrated by many woodcuts from Japanese drawings. “ On the Bursting of the Gun on Board the Thunderer,” by Professor Osborne Reynolds, F.RS., Professor of En- gineering, Owens College, Manchester. In the interval which elapsed between the bursting of the gun and the report of the Committee much thought and some trouble has been expended in divining the possible causes which might, under one set of circumstances or another, have led to such a result. It now appears however that different as have been the various suggestions they all resembled each other in one particular, namely, that they were all wrong. 59 It is to be hoped, however, that all the ingenuity that has been expended will not have been thrown away and that some improvement may result from the pointing out of such numerous defects. That in some respects, such as the increasing twist and the sudden steps or shoulders on the outside of the gun, the present system is defective is shown quite apart from the recent accident; and although it now appears that the moving forward of the shot as the rammer was withdrawn had probably nothing to do with this acci- dent, it cannot be considered satisfactory that this moving forward should be so much the rule as it is shown to have been in the experiments recently undertaken. Although at first sight it may appear that the fact of the gun having been loaded with two charges of powder and two shot is amply sufficient to explain the bursting, it may not be useless to examine somewhat closely into what would result under such circumstances. The bursting of a 38-ton wrought-iron gun is an experiment of which we should make the most, as we cannot expect to have it often repeated. From the first accounts of the accident it appeared as though the gun had simply broken in two, like a carrot, at the first step, and that the front half had gone into the sea. Such a failure would not have implied an excess of pressure. It might have been caused by a great end strain, such as would have resulted had the shot jammed when in full career and carried away the fore part of the gun, or it might have resulted from the gradual weakening of the section of the gun at the shoulder owing to the different degrees of expansion immediately before and immediately behind. One or other of these causes appeared to afford the most probable explanation of the phenomena as described in the 6 0 early accounts. In various subsequent reports, however, it was stated that fragments of the fore part of the gun were blown about in all directions. So that the gun, instead of having simply broken in two, must have burst like a shell in front of the first shoulder. This fact placed the pheno- mena in an altogether different light. The explosive burst- ing of the zone of the gun into fragments implied an enormous excess of pressure at this point of the gun. In order to cause the tube of the gun to burst longitudi- nally at all would require several times the normal pressure, and the breaking up of the wrought-iron tube into fragments would show that the force was largely in excess of what was necessary to burst it. After seeing these reports it appeared certain that the gun had been subjected, at the point of rupture, to a pressure enormously excessive, and the question became, whence could such a pressure have arisen ? To me it appeared that nothing short of such an action as might, with a detonating fuse, result from the explosion of gun cotton or dynamite would explain the breaking of the gun into fragments. Had the shot become jammed the pressure might have been raised sufficiently to burst the gun, but with pebble powder even this seemed doubtful, and such an action seemed alto- gether inadequate to explain the breaking of the gun into fragments. It appeared, therefore, that there was but one conclusion to be drawn — there had been something abnor- mal in the loading. Had the gun been loaded with small grained powder, gun cotton, or dynamite, instead of pebble powder, such a result might have been produced; but then, the gun would, if it had burst, have burst at the breach unless the shot had slipped forward, and that there should have been two accidents appeared highly improbable. Be- sides, it was necessary to consider what sort of a mistake was most likely to have occurred; and the only possible mistake that could have been made on the spot appeared to be that of double loading. 61 Tlie fact that if two complete charges were put into the gun, the powder of the second charge would he directly beneath the point of rupture appeared in favour of this, the easiest mistake. But would, supposing the powder to have been pebble powder, the pressure from the two charges have been sufficient to cause the result ? At first it seemed to me that even supposing that the second charge had been ignited by the first, which was doubtful, this would not explain the suddenness or magnitude of the pressure. But on further consideration it appeared certain that the second charge would not be ignited by the fire from the first ; and it then became clear that in this very fact we should have an amply sufficient explanation of the excessive pressure. My object in writing this paper is to point out the proba- bility of this explanation, and so, if possible, to induce the authorities to test it. It occurred to me several days before the report of the Committee appeared, and in spite of the improbability of such a mistake as double loading, I could not shake off the conviction that it afforded the true expla- nation. As I have pointed out, the blowing into fragments of a wrought-iron tube implied an explosive action such as might result from gun cotton or dynamite but which could not be produced by the slow burning of pebble powder. The point to be explained then is how the second charge could be brought into such a condition that it would explode like gun cotton. To understand this it must be remem- bered that in the usual way the grains of gunpowder burn from their outside only, so that the thicker the grains the longer will be the time occupied in burning, and for the same weight of powder the slower will the gas be given off. The reason why gun cotton is so much more destructive than gunpowder is not that it gives off more gas weight for weight, but that when ignited by a flash it burns so much quicker. If, therefore, by any means the whole mass of gun- powder could be heated up to the firing point at the same 62 instant, so that the grains fired simultaneously inside as well as out, the action of the powder would be as quick or quicker than the gun cotton. And still further, if besides being heated the powder was compressed into a fraction of the space it usually occupies, the gases so confined would be capable of a still greater pressure. Now if the after cartridge were fired and the forward cartridge were not ignited by the flash, and considering the length and fit of the shot it could hardly have been so ignited, then the after shot would be driven forward closing on to the forward shot and compressing the powder between until the pressure on the forward shot was at least half as great as the pressure of the gases behind the after shot, which would be between 10 and 20 tons on the square inch. Thus the powder would be subjected to a squeeze between the two shot such as would result from a blow. It would be compressed to a fraction of its former volume. The cubes would be crushed into a cake and the work of compression would be sufficient to heat the powder far beyond its point of ignition. Thus the entire mass of powder would be simul- taneously ignited in a highly compressed and heated state. The force of such an explosion would be practically unlimi- ted and would be located at the very point at which the gun burst. Hence in such an action we have ample cause for the effect produced. But it will be asked why does not the same thing happen when a rifle is doubly loaded ? It is said that in that case the second cartridge is generally blown out before it ignites, and this may be so, for in the rifle the pressure of the gas on the shot can never exceed above a twentieth part of what it is in the 12-inch gun, and hence in the case of the rifle its pressure may well be insufficient to ignite the powder between the shot. This view of the action resulting from the firing of powder by percussion appears to me to be one which it would be 63 well worth while to test, for if proved it would completely re-establish confidence in the strength of the guns, which has been somewhat rudely shaken. Let a 12-inch gun be loaded with a double charge of pow- der and a double charge of shot, or a shot of double weight, and fired. If, as is probable, the gun does not burst, confi- dence in the gun will be re-established. Then let it be loaded twice over with the powder between the shot so as to ascertain whether the action of the powder when fired by percussion would not produce an effect similar to that which we are here considering. The destruction of one gun for the purpose of establishing confidence in all the rest would not seem to be an unworthy sacrifice. PHYSICAL AND MATHEMATICAL SECTION. January 28th, 1879. E. W. Binney, F.R.S., F.G.S., in the Chair. Dr. Bottomley called the attention of the Section to an interesting copy of the Principia of Newton. In addition to being an impression of the first edition it contains the autograph of Edmund Halley. It was a present from Halley to the Abbot Nazari. Nazari was the editor of a scientific journal at Rome from 64 166Stol681. The following is the entry in Halley’s hand- writing : — Illustrissimo Duo Dro Abbati Nazario Romse humillime offert Edm. Halley. Subsequently the book was in the possession of Hr. Dalton, and its value is enhanced by his autograph. It was con- sidered desirable by the Section that some notice should appear of this interesting book. 65 Ordinary Meeting, March 4th, 1879. J. P. Joule, D.C.L., LL.D,, F.R.S., President, in the Chair. Professor Reynolds, F.R.S., exhibited on behalf of Dr. Roscoe, F.R.S., two samples of steel, one a piece of tungsten steel, the other a piece of crystalline steel presented to Dr. Roscoe with the following letter : — 44, Chorlton St., City, February 28th, 1879. Dr. Roscoe, B.A. F.R.S. Dear Sir, I send by bearer a piece of crystalline steel ingot made here, melted in the usual way and poured into a metallic mould. I consider it a good specimen of its class, in fact the best I ever remember seeing. When in this crystalline state it is technically called “ struck” metal, and requires great care in re-heating and hammering, or else it comes to grief. I have seen the interesting and varied collec- tion you have for the use of students and send this as an addition to the same, the acceptance of which will oblige, Yours very respectfully, WM. ANN ABLE. Professor Reynolds also reported that Mr. W. Watts had brought him some stalagmites of ice, of a mushroom shape, quite clear, and about an inch in diameter. They were found at the bottom of the puddle trench at Denshaw, 60 feet deep, and 7 feet broad. These stalagmites showed that the mushroom shape is the result of being formed from spray, and their transparency shows that water spray de- posited on ice freezes into solid clear ice and hence confirms the view that hailstones are an aggregation of ice particles. Proceedings — Lit. &Phil. Soc. — Vol. XVIII. — No. 8. — Session 1878-9; 66 “ On a Modification of Bunsen’s Calorimeter/’ by Professor Balfour Stewart, LL.D., F.R.S. One object of the calorimeter devised by Professor Bunsen is to measure the amount of heat given out by a small body when cooled from the ordinary temperature of the air to 0°C. For this purpose the body is dropped into ice-cold water contained in a small tube which is then closed with a cork to prevent change of air. Now the weight of the body being small compared with that of the ice-cold water into which it is plunged, the temperature of the latter never reaches 4°C. or the point of maximum density of water. The heated water will therefore be specifically heavier than that above it and will remain at the bottom. Nothing can be better than this arrangement for preventing the dissipation of the communicated heat by convection or otherwise, but the method employed by Bunsen of utilizing this heat has proved difficult in practice. It is well known that he makes use of this heat to melt ice contained in a vessel surrounding the bottom of his tube and measures the change of volume produced by the melting of the ice. I should propose to surround this tube with mercury instead of ice. In the above diagram t represents the tube and M a vessel full of mercury into which the tube is tightly inserted, the mouth of the tube extending above this vessel 67 and remaining open at t or being closed with a cork. The vessel M is in fact a large thermometer of which the stem and scale are at T. There is an air space which envelopes the vessel M, and finally, around this, we have an outer space filled with melting ice. W e may therefore suppose that at the beginning of the experiment the water in the tube t as well as the mercury in M will be at the temperature of melting ice. Now let the small body whose specific heat we wish to determine be dropped into the tube t. The heat which it carries with it will remain at the bottom of this tube and will be spent in very slightly heating the large mass of mercury in M. This mercury being surrounded with melting ice will receive no heat from any other quarter. Its expansion will therefore be a measure of the heat com- municated to the tube t , and although the whole rise of temperature of the mercury will not be great yet the mass being large it will act as a very open thermometer and the heating effect will be indicated by a rise of mercury in the stem T. “The Poisonous Qualities of the Yew,” by William E. A. Axon, M.R.S.L., F.S.S. At our meeting, on the 9th Jan., 1877, Dr. Bottomley made an interesting communication to the Society on the real or supposed toxic qualities of yew leaves. The subject recurred to my mind when on a recent visit to Stonyhurst, for the failure of the main line of the Sherburnes, the ancient owners of that mansion, is attributed to a similar cause. Richard Francis, son of Sir Nicholas Sherburne of Stonyhurst, died in 1702, at the age of nine, through eating some yew tree berries, in the fine avenue at the eastern end of that hall.* This tradition led me to make further inquiries. I was in- formed by Mr. Thomas Kirk, farmer, of Whittingham, near Preston, that he has known cases of the poisoning of cows * Hewitson’s Stonyhurst College, 1878, p. 9. 68 and other cattle by yew leaves. In the spring of last year a young horse came to an untimely end from the same cause. The poisonous qualities of the yew tree has in that district at least passed into a commonplace of agricultural belief. It then occurred to me that I had read something on the subject in our older botanical writers, and on turning up the fine old folio of Gerarde’s Herbal, enlarged by Johnson, and published 1636, I found this passage The yew tree, as Galen reporteth, is of a venomous quality, and against man’s nature. Dioscorides writeth, and generally all that heretofore have dealt in the faculty of herbes, that the yew tree is very venomous to be taken inwardly, and that if any doe sleepe under the shadow thereof it causeth sicknesse, and oftentimes death. Moreover, they say that the fruit thereof being eaten is not only dangerous and deadly unto man, but if birds doe eat thereof, it causeth them to cast their feathers, and many times to die. All of which I dare boldly affirme is altogether untrue ; for, when I was young, and went to schoole, divers of my schoole-fellows, and like- wise myself did eat our fills of the berries of this tree, and have not only slept under the shadow thereof, but among the branches also, without any hurt at all, and that not at one time, but many times.” He adds on the authority of Theophrastus that “ labouring beasts die, if they do eate of the leaves ; but, such cattell as chew their cud receive no hurt at all thereby. * * Pena and Lobel also observed that which our author here affirmes, and dayly experience shewes it to be true, that the yew tree in England is not poysonous, yet divers affirme, that in Province in France, and in most hot countries, it hath such a maligne quality, that it is not safe to sleepe or long to rest under the shadow thereof.”* A writer in Hardwicke’s Science Gossip, May, 1865, states that thirty or forty deer in the park of the Duke of Beaufort, * Gerarde’s Herbal, enlarged by Johnson, 1636, p. 1370. at Badminton, were poisoned by nibbling the leaves of a yew tree, the branches of it having borne down within their reach by the weight of heavy snow. A lady (Helen Watney) writing in July, points out that this is contrary to the idea that the leaves are not poisonous to deer, sheep, or goats. She mentions as a well-known fact, that leaves, whether fresh or withered, are toxic in their influence upon horses. Its juice, she adds, was considered a remedy for the bite of a viper, and that in Germany, it is still a popular remedy for hydrophobia. Dr. Taylor cites a case of a child having been poisoned by eating yew berries. Death appears to have ensued in a few hours. He names also a case of a lunatic who died from eating yew leaves. “There is no doubt,” he says, “ that the yew is a cerebro-spinal poison. The symptoms produced by the leaves and berries are pretty uniform in character : convulsions, insensibility, coma, dilated pupils, pale countenance, small pulse, and cold extremities are the most prominent. In two cases, the subject of one — a girl about five years of age — died in a comatose state in four hours after she had eaten the berries, and the other a boy, aet. four years, died nineteen days after taking the berries, obviously from severe inflammation of the bowels.”* Dr. Taylor adds that “ the nature of the poisonous princi- ple is unknown, and it is not certain whether, with respect to the berry, the poison is lodged in the pulp or the seed, although it is most probable in the latter.” It may be exhibited in another form, for Caesar, in the Commentaries on the Gallic War, tells us that Cativolcus, King of the Eburnones, unable to endure the fatigue either of flight or of war, poisoned himself with the juice of the yew tree, of which there is great abundance in Gaul and Germany. (B. G. vi., c. xxxi.) # Taylor on Poisons, 2nd edition, 1859, p. 843. 70 The poets share the popular belief. Father Newman in a recently published poem, speaks of some dark, lonely, evil-natured yew, Whose poisonous fruit — so fabling poets speak— Beneath the moon’s pale gleam the midnight hag doth seek.* M. Mavine has found a poisonous alkaloid in the leaves and seed of the common yew (Taxus baccata ), which is named Taxine. It is nitrogenous, and evolves ammonia when ignited with freshly-ignited soda-lime. Taxine is present in greater quantities in the leaves than in the seeds. — (Science Gossip, 1877, p. 141.) It will be seen that there is considerable diversity in the evidence as to the reality of the poisonous qualities of the yew, both as to its leaves and berries. It seemed worth while to bring this fact out in the hope of inducing some chemist to turn his attention to a matter which still appears to invite definite and decisive investigation. We all know Pascal’s famous saying, that if Cleopatra’s nose had been an inch longer or shorter, the entire course of subsequent history might have been different. As a smaller example may be mentioned, that popular belief at least regards a childish feast on fatal yew leaves, as one of the main links in that chain of events which has given Lancashire the famous Jesuit College of Stonyhurst. # Lyrics of Light and Life, edited by F. G. Lee, second edition, 1878, p. 8. 71 MICROSCOPICAL AND NATURAL HISTORY SECTION. January 8th, 1879. Charles Bailey, F.L.S., President of the Section, in the Chair. Mr. Hastings Charles Dent, of the City Surveyor’s Office, Town Hall, and 112, Bury New Road, Manchester, was elected a member of the Section. Mr. Thomas Rogers read a paper on, and exhibited many specimens of, ballast plants collected at Cardiff in Septem- ber, 1878. The following list shows that the majority of the plants collected are of South European origin, interspersed with a few North American and Eastern Indian species. Foreign Plants— Cardiff Ballast. Natural Order. Native Country. London Encyc, RanunculaceEe ...Nigella damascena South Europe Cruciferse Berteroa incana „ „ Camelina foetida ,, „ Bunias orientale Levant Sisymbrium pannonicum . . . Hungary Iberis umbellata probably an escape from gardens Erysimum orientale Levant Resedacese Reseda Durisei Algiers Malvaceae Lavatera punctata Italy Malva nicoeensis „ Limnanthaceee . . . Limnanthes sulphurea California Zygophyllacese ...Tribulus terrestris South Europe Leguminosse Anthrolobium scorpioides . . . „ ,, Cicer arietinum ,, ,, Coronilla varia Europe 72 Scorpiurus sub villosus Europe Medicago littoralis Italy Melilotus coerulea Switzerland Astragalus hamosus Spain Trifolium nigrescens Italy Melilotus alba... „ Hedysarum coronarium... ... „ Caryophyllaceee ...Saponaria vaccaria Germany Onagracese Clarkia pulchella North America CEnothera biennis „ „ „ odorata South America Composite© Scolymus hispanicus ..Spain Nardosmia fragrans Italy Inula viscosa South Europe Centaurea melitensis Malta Xanthium spinosum South Europe Erigeron Canadense North America Actinomeris squarrosa 1 „ „ Solidago lanceolata „ „ Scrophulariaceee . . . Scrophularia canina var South Europe „ green flowers ?... Linaria elatine var. Sieberi. . .Gandia Labiatae Sideritis montana Austria Salvia verticellata Germany Stachys Italica Italy Boraginacese Heliotropium europeum ...Europe Echinospermum Lappula ... „ Plantaginacese ...Plautago arenaria Hungary Amaranthacese . . . Amaranthus chlorostachys. . . South Europe ,, retroflexus North America Chenopodacese . . . Chenopodium ambrosiodes . . . South Europe „ Botrys „ „ Euphorbiacse Euphorbia segetalis „ „ Urticacese Cannabis sativa India Narcissus Tazetta Spain Gramine&e Crypsis schoenoides South Europe Zca mays India 73 Panicum miliaceum East Indies Lep turns incurvatus iEgilops ovata South Europe Alopecurus utriculatus „ „ Phalaris paradoxa Levant , , cserulescens Spain The following British plants occurred on the Cardiff Ballast Heaps. British Plants. Papaver somniferum and P. argemone. Lepidium Draba and L. ruderale. Sinapis nigra. Senebiera didyma and S. coronopus. Nasturtium terrestre. Erysimum Cheiranthoides. Sisymbrium Sophia. Arenaria serpyllifolia, var. leptoclados. Cerastium arvense. Herniaria glabra and H. ciliata. Polycarpon tetraphyllum. Reseda alba. Lavatera arborea. Lavatera sylvestris. Linum usitatissimum. Geranium rot undifolium. Melilotus vulgaris. Trifolium fragiferum, and T. resupinatum. Trifolium suffocatum, and T. stellatum. Trifolium incarnatum, and T. Ochroleucum. Trifolium maritimum, Medicago falcata and M. denticulata. Yicia lutea. Lathyrus aphaca. Lythrum hyssopifolium. Epilobium. Coriandrum sativum. 74 Eryngium campestre. Bupleurum rotundifolium. Centranthus ruber. Cnicus marianus. Gnaphalium luteo-album. Artemisia campestris. Solanum nigrum, in large bushes. Datura stramonium. Hyoscyamus niger. Senecio squalidus. Lactuca virosa. Anthemis arvensis. Veronica Buxbaumii. Linaria spuria. Linaria elatine and var. Sieberi. Scrophularia Scorodonia. Salvia clandestina. Chenopodium rubrum. Cynodon Dactylon. Digitaria humifusa and D. sanguinalis. Panicum crus-galli. Setaria viridis and S. glauca. Gastridium lendigerum. Polypogon Monspeliensis. Agrostis spica-venti. Agrostis alba, var. stolonifera. Lolium temulentum. Poa loliacea. 75 General Meeting, March 18th, 1879. J. P. Joule, D.C.L., LL.D., F.R.S., &c., President, in the Chair, Mr. Hastings Charles Dent, 112, Bury New Road, Man- chester, was elected an Ordinary Member of the Society; and Monsieur A. Letourneux, Conseiller a la Cour d’Appel d’Alexandrie, Egypte, was elected a Corresponding Member, Ordinary Meeting, March 18th, 1879. J. P, Joule, D.C.L., LL.D., F.R.S,, &c., President, in the Chair. “ On Siliceous Fossilization, Part II.,” by J. B. Hannay, F.R.S.E., F.C.S., Assistant Lecturer on Chemistry in the Owens College. In a former paper it was shown by chemical and optical means that the fossil siliceous rods Hyalonema Smithii were identical in constitution with those from modern sponges, and that the curious nodulised appearance of some of the rods was due not to the original form of the rods, but to certain physical and chemical changes which have passed over them since they were deposited where they were found. It was also shown that of the three forms of silica, transparent, gelatinous, and opaque, the first and second were easily acted upon, and retained the original structure of the organic silica, whereas the last was in the truly mineral form and had lost every trace of organic structure, and was not easily acted upon by chemical means. Mr. John Young, F.G.S., having kindly Proceedings— Lit. & Phil. Soc.— Yol. XYIII.— No, 9.— Session 1878-9. 76 supplied me with several specimens of the fossils from the limestone quarry at Kilwinning, which are very different from those I previously examined, and which throw more light on the changes which siliceous fossils may undergo, I beg to give an account of them to the Society, One piece of limestone simply contained (instead of rods) a number of cylindrical holes where the rods had lain. In Fig. I, which is a woodcut from a photograph, are seen these cylindrical holes which plainly show that the rods have been dissolved away. The solvent must have been a strong calcareous or other alkaline solution, as the calcareous fossils are not in the least disfigured. In. Fig. 2 we see a beautifully pre- served sample ofFenestella, and we know that a very slight solvent action would have destroyed the structure of these delicate organisms. From other internal evidence, such as little shells and diatomaceae, it is clear that the calcareous portion of this limestone has not been at any time dissolved to any extent, and yet such an obdurate substance as silica has been completely removed. Then as to the cause of its removal. The solution was no doubt highly calcareous, but we know that highly calcareous water may run over quartz crystals for a very long period without having the slightest effect upon the faces. I think that Fig. 3 will explain how the rods came to be so easily dissolved. This is a photograph of a hollow where a rod has lain which still contains some rounded nodules of silica. It will be seen from my former paper that these nodules are anhydrous inorganic silica, crystallizing out of the hydrated silica after the rod has undergone a little dehydration since it was alive. Now here we see the whole rod dissolved except such portions as were entirely mineralised, if I may use such a term, so that we see that the reason these silica rods were so easily dissolved by the calcareous solution was because the silica of which they were composed was in a hydrated easily soluble form. Thus the existence of those nodules which had before puzzled naturalists now gives us the clue to the state of the rods at the time of solution. Fig. 4 will still further elucidate this subject. Here it will be seen we have a large number of rods partially dis- solved. I have examined by the means given in my former paper above twenty samples of these partially dissolved rods, and I have not found one sample containing water, so that again we see the whole of the thoroughly mineralised silica is left behind, and those portions which were very probably hydrated dissolved. I say very probably, for we see that the solvent action has gone on in a very irregular manner and in a manner which could not be accounted for on any circulation hypothesis, but just in such a manner as 78 would be caused by the irregular manner in which the rods get mineralised. It might be expected that since the rods were so neatly and perfectly dissolved out, the spaces might get filled up with carbonate of lime and reproduce the silica rod as a cal- careous fossil ; but although 1 have examined some hun- dreds of those fossils, I have not found one case of this nature. The only cases I have found even approaching to this is when the centre of the rod is dissolved it is some- times, as in Fig. 5, filled in with carbonate of lime. I have noticed that when carbonate of lime is deposited in the cavity where the rod lay it is highly crystalline, and could never be mistaken for anything organic. Fig. 6 is from a photograph, showing the carbonate of lime in the silica centre. As the above remarks border on a subject which has been discussed very extensively, I may be allowed to point out that they settle one half of the discussion, namely, that silica may be dissolved in presence of calcareous fossils; but the other half, namely, whether or not the spaces so left may be filled up with carbonate of lime so as to look like fossils, is still an open question. PHYSICAL AN I) MATHEMATICAL SECTION. February 25th, 1879. E. W. Binney, F.RS., F.G.S., in the Chair. “ On the Mean Temperatures of the Winters of the last 29 Years,” by the Kev. Thomas Mackereth, F.R.A.S., &c. It may be considered somewhat premature to institute a comparison of the mean temperatures of the last 29 years 79 when the colder of the extreme of the winter months has not yet been entered upon, viz., the month of March. In a meteorological sense winter may be considered as including five months of the year, viz., November, December, Janu- ary, February, and March. But January, so far as low temperature is concerned, is the pivotal month of the winter, and March has a mean temperature slightly below that of November. The difference is so small, only about 0-7 deg. Fahr., that in comparing the mean temperature of winters the mean temperature of these two months may be practically neglected. The mean temperatures deduced from my own observations extend over only 17 or 18 years; but the late G. V. Yernon, Escp, F.B.A.S., was kind enough to furnish me with the weekly temperatures he had deduced from the year 1850 onwards till 1861, when I began to make my own observations and deductions. That the mean temperatures here presented may have a common basis I have calculated them upon the weekly mean temperatures of the last 29 years, which of course include those of the late Mr, Yernon. The results are as follows for the winters extending from the first week of December in one year to the last com- pleted week in February of the year following. Winter of .Mean Temp. Winter of Mean Temp. 1850-1 ... 40-3° 1865-6 ... 41-9° 1851-2 ... 39 ’8° 1866-7 ... 39-9° 1852-3 ... 39*9° 1867-8 ... 400° 1853-4 ... 37-3° 1868-9 ... 43*6° 1854-5 ... 35-1° 1869-70 ... 37-1° 1855-6 .. 37-3° 1870-1 ... 35-6° 1856-7 ... 37*9° 1871-2 ... 40’3° 1857-8 ... 39-4° 1872-3 ... 39-2° 1858-9 ... 41-0° 1873-4 ... 40*6° 1859-60 ... 35-4° 1874-5 ... 38-6° 1860-1 ... 36-4° 1875-6 ... 38-8° 1861-2 ... 39-3° 1876-7 ... 42-3° 1862-3 ... 41-9° 1877-8 ... 39-6° 1863-4 ... 37*9° 1878-9 ... 31*4° 1864-5 .. 36-6° 80 From the above table of winter mean temperatures it will be seen that the coldest winters of the last 29 years were in 1854-55, 1859-60, 1870-71, and in 1868-69; and that the present winter is colder than the coldest of these, viz. 1854-55 by 3’7 deg. or 12 per cent. The mean temperature of the winter months for 29 years is 3 8 *7 deg. And whilst the winter of 1854-55 was 3'6 deg. or a little over 9 per cent below the average temperature, the present winter is 7*3 deg. or 19 per cent below the average winter tempera- ture. The accompanying diagram sets forth the ratio of all the winters from 1850-51. w ( ! C0 | « CD I m i IfJ 1 Q Ifi 1 Q 1 in I m VJ 03 to !«> «*■> 03 CO 00 CO GO 03 WINTER 0 38-7 MEAN BBaHHinHIHBIBHBBHHHIIBBHIiH flflflBflfl«BflBBBflflBBB»HBBBflBBBBH| flBBBflBHBBBBBBBflBBU«BHBBBBBHflfl BBBBBBBBBBBKliBBBWBMMBBmBBBMKlBB SflBBBBBB«BBrJBBBIHB!flNBV!BRBBFJKBB KBBBIIKflLlirailHIiSHBiil^ViKBlLWBBiBB BflHBflRBBllBrJBBBrBBRHBBflflBRflBBlflfl ■■■NRaHBBBfJBB^BBBHBBriflflBBBB&VB BflBUrJBBMHJSflBBBflBflBMKBBBflBBflllB BflfllflBBBBBBBflUnHHIBflBBBBlg HWWBMWIIHWWHI YEARLY 480 MEAN BBBIIflBBBBflBBHMKMHBIBHBHflBBi ■■■■■■■■MBaBamamaiMMiian niiiiiunBiinimmnni ■■■■■■■■■■■■■■■■■■■■■■■■■■■■a SUMMER 0 58-1 MEAN BBBBBBHflBBBBBBBBKBflBBflBBBRBBfl BIBflBBBBBBBBBBBflMklRBiBflBBBBflB mmmrnmummmwimmmmmmmmrA^rd^mmwMWAmu BBBBBBBIBBBklBflKIBiSflHBBflBBBBKBBI iiiiiiiiiiiaiiiiiniiiiiiiiii ■■■-■■■■aWMBMMi—MaM tn u s m h' CQ 03 ea 09 •»* 81 Here it will be seen that five years elapsed between the cold winters of 1854-55, and 1859-60; but that six years elapsed between the cold winters of 1864-65, and 1870-71, and that eight years elapsed between the present cold winter and the previous one of 1870-71. It is now known that the sun spot period is irregular and not so nearly an interval of 10, 11, or 12 years as was imagined. The minimum of the sun spot period happened about two years ago, but it is still at a minimum, and very seldom have spots been seen on his disc during the past year. Whether these cold winters are traceable to this solar inactivity or not, the pre- sent coincidence is very striking. In the same diagram I have presented the ratios of the mean summer temperatures of the last 18 years. These ranges are included in the weekly mean temperatures of June, July, and August, and will be seen to be far less than the ranges of the winter mean temperatures. This perhaps may be accounted for by the relative difference of the amount of atmospheric vapour existing in the air in the two opposite seasons of the year. In the winter season the ratio of atmospheric vapour reaches 87 per cent, whilst in the summer season it reaches only about 75 per cent. But whether this is so or not, there is the fact. Here it will be seen that between the hot summer of 1861 and the still hotter one of 1868 there is an interval of seven years ; since then the coming summer will make an interval of 11 years. In the interval of 7 years there was only one sum- mer with a temperature slightly above the average, 1865; all the other summers of this interval were mostly far below the average ; but in the 11 years’ interval all the summers, with only two exceptions, have either been above or equal to the average summer temperature. The ratios of the summer and winter temperatures have not the slightest relationship to each other. Hence it is impossible to form 82 any idea from the temperature of a winter what kind of summer temperature may follow. I have shown on the same diagram the mean tempera- ture of each year from 1861 to 1878. The mean of all is 48‘0 deg. The ratios of their differences are extremely small, so small indeed as to be of no practical value ; for between the coldest year and the warmest of the last 17 years there is a difference of only 2*9 deg., and the mean difference of temperature of all these years amounts to only 0 3 deg. These differences do not, from the data I have, seem to observe any definite rule. 83 Ordinary Meeting, April 1st, 1879. Edward Schunck, Ph.D., F.R.S., &c., Vice-President, in the Chair. Among the Donations announced was a Portrait of Mr. E. W. Binney, F.R.S., &c., painted by Mr. William Herbert, Johnston, and presented by the President, Dr. J. P. Joule, F. RS., &c. On the motion of Dr. R. Angus Smith, F.RS., seconded by Professor W. C. Williamson, F.R.S., it was resolved That the cordial thanks of the Society be given to Dr. J oule for his valuable donation. Mr. J. H. Poynting, B.A., exhibited an autograph dedica- tion to M. Humbolt, of “Extrait d’un mdmoire sur la Thdorie des tubes capillaires,” by M. Laplace, of which the following is a copy : Pour Monsieur Humbolt. De la part de l’auteur. Je prie Monsieur Humbolt d’agre'er ce petit mdmoire comme un hommage de tons mes sentimens d’estime et d’attachement bien sinceres. M. Berthollet, qui est avec moi dans ce moment, me prie d’y joindre les siens. Nous nous rappellons l’un et l’autre au souvenir de M. Gay Lussac. “Two Deductions from Mr. G. H. Darwin’s Letter in Nature , Feb. 6, 1879, upon Sir W. Thomson’s Equation of Cooling, * = V0 + 2V X — -Z 2 Jkt dz by Mr. James Heelis. Proceedings — Lit. &Phil. Soc. — Yol. XVIII. — No. 10. — Session 1878-9. 84 If the expression be integrated we get r<-i 2 V v = Y0+—ze V 1 + 2 ?} + 22 24 + 23 7 r 1-3 1-3 1*3. 5 *7 -z 6 + >, 1878-9, 6 at £2 2s. ,, Half Subscription, 1877-8, 1 at £1 Is. ,, Subscription, 1878-9, 6 at £2 2s Old Members, 1878-9, 136, at £2 2s 1878-9. £ s. d. £ 1726 8 8 0 2 2 0 12 12 0 110 12 12 0 285 12 0 To One Compounder To Two. Associates’ Sub. (for Library) 10 0 To Sectional Contributions, 1878-9 : — Physical and Mathematical Section 2 2 0 Microscopical and Natural History ditto 2 2 0 To Use of Society’s Booms to 31st March, 1878 : — Manchester Geological Society 30 0 0 Manchester Scientific Students’ Associa- tion 22 0 0 Manchester Field Naturalists’ Society 9 0 0 To Sale of Society’s Publications To Natural History Fund : — - Dividends on £1225 Gt. Western Stock... To Capital Fund : — Natural History Society’s Donation.. 322 5 61 2 60 To Bank Interest, less Bank Postage, to 31st December, 1878 10 1877-8. s. d. £ s. d. £ s. d 4 3 247 19 9 7 0 332 17 0 26 5 0 10 0 2 2 0 2 2 0 4 0 — — 5 4 0 30 0 0 11 10 0 0 0 - 41 10 0 1 10 2 10 0 13 68 16 9 1500 0 0 1568 16 9 17 4 11 10 £2186 19 11 £2229 14 4 Compounders’ Fund : — Balance in favour of this Account, April 1st, 1879 .. .. Natural History Fund Balance, April 1st, 1878 Dividends as above, in 1878-9 £ s. d. £ 1611 18 7 . 60 1 3 s. d. . £ s. 125 0 d. 0 : Expenditure on this Account, 1878-9 Balance against this Account, April 1st, 1879.. General Fund : — Balance against this Account, April, 1st, 1878 Expenditure, 1878-9, as above 1671 19 10 1675 8 11 9 9 1 o 10 14 4 503 1 0 Keceipts, 1878-9, as above 513 15 4 400 14 5 Balance against this Account, April 1st, 1879 ... 113 0 11 116 10 0 Balance in favour of the Society £8 10 0 PHILOSOPHICAL SOCIETY. from 1st April, 1878, to 31st March, 1879, with a Comparative for the Session 1877-1878. Q£x. 1878- •9. 1877-8. 1879. — March 31. £ s. d. £ s. d. £ s. d. £ s. d. By Charges on Property : — Chief Rent 12 13 6 12 15 2 Insurance against Fire 12 17 6 13 7 6 Property Tax 3 10 10 2 2 6 Repairs, Whitewashing, &c 3 14 0 2 0 2 32 15 10 ■ 30 5 4 By House Expenditure : — Coals, Gas, Candles, and Water 17 0 11 18 17 9 Tea and Coffee at Meetings 7 18 18 10 18 14 6 House Duty 6 7 6 6 7 6 Cleaning, Brushes, Sundries 4 17 9 6 2 7 47 5 0 - 50 2 4 By Administrative Charges : — Wages of Keeper of Rooms 57 4 0 57 4 0 Postages and Carriage of Parcels 20 7 2 26 17 4 Attendance on Sections and Societies 14 11 6 15 14 0 Stationery and Printing Circulars 12 12 6 8 9 3 104 15 2 - 108 4 7 By Publishing : — Printing Memoirs 50 9 6 74 4 6 Printing Proceedings 57 11 0 63 15 0 Wood Engraving and Lithographing 14 11 0 6 3 3 Editor of Memoirs and Proceedings 50 0 0 50 0 0 172 11 6 ■ 194 2 9 By Library : — Binding Books... 78 10 6 35 2 6 Books and Periodicals 50 4 6 11 2 6 Assistant in Library 12 4 0 11 6 0 Old Memoirs of the Society 1 12 0 Geological Record for 1876 0 10 6 0 11 2 Palseontographical Society for 1879.... 1 1 0 1 1 0 Ray Society for 1877, 1878, and 1879 3 3 0 145 13 6 - 60 15 2 By Natural History Fund : — Investment — £1225 Great Western Railway Stock ' 1489 18 0 Brokerage on ditto 7 9 0 Legal Charges 41 12 0 Works on Natural History 36 9 11 * Grant to Microscopical and Natural His- tory Section for Books 100 0 0 1675 8 11 60 0 0 By Balance 8 10 0 1726 4 2 £2186 19 11 £2229 14 4 1879. — April 1. — To Casli in Manchester and Salford Bank £8 10 0 April 8, 1879, Audited and found correct, (Signed) JAMES BOTTOMLEY, R. S. DALE. 128 The following letter, dated April 24th, 1879, from Mr. Arthur W. Waters, F.G.S., was read : — On February the 9th, 1876, I wrote you a letter, which was published in the Proceedings of the Literary and Philo- sophical Society, giving an account of the Naples Zoological Station, and as the Mittheilungen aus der Zoologischen Station zu Neapel shows that it has expanded since then into a more important establishment, I send a few supple- mentary particulars gathered from this first volume. Since the date of my last the Station has received a small steamer for dredging purposes, partly through the liberality of the Berlin Academy, which voted 18,000 marks for the purpose, and the Prussian Government 6,000 marks. Dr. Dohrn has also made a more satisfactory arrangement with the Italian Government, who granted him the lease of the land for thirty years, and have now extended the term to ninety years. The accomodation has been increased so that now, tables for 26 naturalists can be furnished, and the staff is very materially larger, there being now 25 constantly employed about the station. The increase has taken place in all departments, though the most material is in the scientific staff, which has been doubled. Dr. Berth old has charge of the botanical section, and Dr. Paul Mayer has the task of seeing after the zoological collections, and some other changes and sub divisions have been made, but Dr. H. Eisig from whom the naturalists who have already visited the Aquarium have received material assistance, still represents Dr. Dohrn in the detail control of the entire establishment. The addition of the steamer has caused changes among the engineers, and necessitated several more boys about the place. These boys are much more important than would at first thought be supposed, for an intelligent lad soon learns to distinguish the animals which the specialists are investi- gating, and after a time knows the scientific names of a large proportion of the animals brought in., and in fact will soon have a wider superficial grasp than most of the naturalists, and able to quickly “spot” the animals required. The eldest boy (Torillo) when I was there had devoted himself diligently to increasing his knowledge, and was able to give valuable assistance, and I see he has had more important duties assigned to him, and Dr. Dohrn speaks of the increas- ing knowledge of the other boys. The first volume of Mittheil ungen contains several valu- able papers. The continuous observations of Mr. Schmidtlein on the habits of the animals in the Aquarium bring out much that is interesting, and such observations are much needed in all aquaria. Dr. Dohrn discusses the zoological position of the Pycnogonidae. Dr. P. Mayer has in each part a ps.per on Carcinological studies, and in the second he follows up Mr. Bullar s investigations on the Isopoda, and supports most of his conclusions, showing the curious hermaphroditism of the group, the young being active males, while as they grow older most of the male organs wholly or partially disappear, in connection with which the female organs are then developed. Dr. Falkenberg gives a synopsis of the fucoids of the bay of Naples. Most but not all of the papers in these two parts are by the staff, but the number of papers giving the result of studies made in the Station by naturalists is now very con- siderable, and is spread over the periodical literature of all scientific Europe. As the institution now lays itself out more and more for supplying material to naturalists, prepared according to their instructions, the list with prices which is given at the end of the second part, will be of service to anyone requiring such aid. This is much the largest zoological station, and may be looked upon as to a great extent the parent of others now springing up in many directions. Quite recently the Triest zoological station has also published three parts of a volume, containing a series of most valuable results attained there. There is also the station at RoscofF, which supplies the “Archives de zoologie experimentale” of M. Lacaze-Duthiers with many important papers. There is a more or less per- manent station on one of the islands near Denmark, and it 130 is proposed to start one in Sydney, and if the ideas of the promoter are carried out, this will only he one of a series of stations confederated together in the southern hemisphere. The extension of the Naples station has of course materi- ally added to the expense, and as it is now so generally felt that biological science is very largely indebted to Dr. Dohrn’s indefatigable perseverance, it is to be hoped that he will receive all the support he expects. MICROSCOPICAL AND NATURAL HISTORY SECTION. Annual Meeting, April 7th, 1879. Charles Bailey, Esq., in the Chair. The Treasurer s Account and Report of the Council were read and passed. The Election of Officers for the ensuing year then took place as follows : ^prcsfrcnt. C. BAILEY, P.L.S, Utcc=qj3 residents. THOMAS ALCOCK, M,D. H. A. HURST. A. BROTHERS, F.R.A.S. treasurer. T. II. BIRLEY. Secretary. J. COSMO MELVILL, M.A., F.L.S. (Eourtctl. W. C. WILLIAMSON, F.R.S. JOSEPH BAXENDELL, F.R.A.S. JOSEPH SIDEBOTHAM, F.R.A.S. R. ELLIS CUNLIFFE. JOHN BOYD. JOHN BARROW. E. W. BINNEY, F.R.S. , F.G.S. W. BOYD DAWKINS, F.R.S., F.G.S. List of Members and Associates of the Section : — - J^tcmtms. Alcock, Thomas, M.D. Bailey, Charles, F.L.S. Barratt, Walter Edward. Barrow, John. Baxendell, Joseph, F.E.A.S. Bickham, Spencer H., Jun. Binney, E. W., F.B.S., F.G.S. Birley, Thomas Hornby. Boyd, John. Brockbank, W., F.G.S. Brogden, Henry. Brothers, Alfred, F.E.A.S. Cottam, Samuel. Coward, Edward. Coward, Thomas. CuNLIFFE, BoBERT ELLIS. Hale, John, F.C.S. Dancer, Jno. Benjamin, F.E.A.S. Dent, Hastings Charles. Derbyshire, E. D., B.A. Dawkins, W. Boyd, F.E.S., F.G.S. Deane, W. K. Higgin, James, F.C.S. Hurst, Henry Alexander. Latham, Arthur George. Martin, Sidney Trice. Melvill, J. Cosmo, M.A., F.L.S. Mooke^ Samuel. Morgan, J. E., M.D. Nevill, Thomas Henry. Nix, E. W„ M.A. Egberts, William, M.D. Sidebotham, Joseph, F.E.A.S., F.L.S. Smith, Eobert Angus, Pli.D., F.E.S., F.C.S, Williamson, Wm. Crawford, F.E.S., Prof. Nat. Hist., Owens College. Wright, William Cort. Associates. Becker, Wilfrid, B.A. Hartog, Marcus M., B.Sc., F.L.S. Kimmins, C. W. Labrey, B. B. Linton, James. Peace, Thos. S. Perciyal, James. Plant, John, F.G.S. Eogers, Thomas. Stirrup, Mark, F.G.S. Tatham, John F. W., M.D. Young, Sydney. 132 Eh o h— Eh O W. >-i Ph O Eh Tfl HH w 1—3 Ph p Eh < Ei A {2J < A H O HH P© o o m o A o HH £ P3 m Eh pH EH H o o OQ hA h Ph <1 Ph P H HH P P3 H H m H a o a Ph £> m H H Ph H PS HH PH w OQ H 3 O H EH H H EH E E O o o <1 p ° ^d rH O O P0 rH rH • d o ® PD O 03 rH rH 00 cq si ® cq ©3 PO ^ rH rH rH co cq cq HP rH «rt m © E Pi „ ..HH HH Pi c3 &o _, o d d ci rrH HH Cl Rc» -© d M pp r-> O Hh hi r. rd P r 1 1 1 . oo 1 05 p 1 Tj © d • rH Ih r— H CO Ph rH JH. © CO Ph rH d a c3 M Ph ft rd -P <1 R ■d © O HP O O © m O O Cq CO © rH lO CO Ph H ft O ^ §o d • c6 Jx] p "d c3 rip dM O'm a PPH^ o ^ „ Eh ~ - xn JO 02 t© aco co oo 00 00 rd © Ph Ph O c3 O rH © ^ P OP ^ 03 Oi 03 © K? drS^ © O ?H O • rH •©Nrfj a g ^ a s g a.s s •rH 'H O m JP> mm . © d ?H P (O ca ^ p- rd p . oEhj owcuoo cq cs oq Jt>,io rH CIQ^OO o .S§ o HH O xn. © d © _ H ^1 c3 o Ph d s6 rt 02 bo £n o $P — i ca O H-3 02 O ft CO eq cq rH o p .2 © © d ’3 -g.-S g So o rd 03 ft^ *C «a S d P 03 03Q3R © o as c© • Hs Po Vh co d # d 00 CO h!> i — I c3 o EE cq r-l Cq o d © © R .05 -d © 00 Ph i — I c3 133 Mr. Hurst gave a list of the Leguminosse of the Riviera collected by Joseph Sidebotham, Esq., in the winter of 1877-78. Argyrolobium Linnseanum, Walp. Genista Germanica. L. „ sericea. Wnlff 1 Spartium junceum. L. Cytisus albus. Link, a J.S. „ Ursulas. L. Ononis minutissima. L. Anthyllis tetraphylla. L. „ vulneraria. y. rubriflora. L. Medicago littoralis. Rhde. „ minima. L. ,, orbicularis. All. Very fine. „ maculata. Will. Melilotus officinalis. Desr. Trifolium stellatum. L. „ montanum. L. „ patens. Scbreb. „ scabrum. L. Dorycnium suffruticosum. Mill. „ hirsutum. X). C. Lotus ornithopodioides. L. ,, edulis. L. Psoralea bituminosa. L. ^ Astragalus monspessulanus. L. do. Imperfect. Scorpiurus subvillosa. L. Coronilla Emerus. L. „ valentina. L. „ minima. L. ,, varia. L. Arthrolobium scorpioides. L, 134 Ornithopus compressus. L. Hippocrepis unisiliquosa. L. Onobrychis. Resembles 0. equidentata in foliage. Yicia bybrida. L. Ervum nigrescens. L. Lathy ms sativus. L. „ setifolius. L. „ 1 imperfect. Orobus tuberosus. L. Mr. Hurst likewise read a communication from Pv Planta on the Grasses of Egypt, enumerating as follows those found : — ■ Graminees cVEgypte. Andropogonece. Imperata cilindrica (Hoat) M. Tell, Sembaleven. Piraymides. Saccharnm iEgyptiacum (Wild). Sicile. Rosette. Sorghum halepense (Pers). M. Ramie. Andropogon annulatum(Del). (deM. Letourneaux). M. Damenhour. Panicece. Panicum turgidum (Del). M. Mokatham. Panicum crus galli (L). G. Rosette. Panicum numidianum (Lam.) (muticum Forsk.) M. Rosette. Panicum cruciforme Sibth. M. Rosetta. Setaria verticillata (Pers). M. Ramie. Pennisetum dichotomum (Dei). M. Mokattam. Phalaridece. Phalaris paradoxa (L). M, Piramides Sembaleven. Phalaris aquatica (L). M. Gabari. Phleicce. Crypsis Schoenoides (Lam). M. Ghizah, Mandara. A grostideae. Polypogon monspeliense (Deof). M. Gabari. Agrostis pungens (Zehreb). M. Ramie. (Sporobolus pungens) (Kunth). 135 Agrostis verticillata (Vill). M. Ramie. Agrostis spicata (Del). M. Ramie. Stipcicece. Stipa tortilis (Desf). M. Ramie. Aristida plumosa (L). M. Mokattam. Milium vernale (Rehb). M. Alexandria. Arundinacece. Arundo isiaca. (Del). M. Rosette. Phragmites communis (L). G. Rosette. Amophila arenaria (LR). (de M. Letourneaux). G. Mandara. Chloridece Cynodon Dactylon (Pers). G. Ramie. Dactyloctenium iEgyptiacum. Sicile. Ramie. Agrostidece. Aira minuta. M. Ramie. Avena neglecta (Savi). (Trisetum neglectum, RS) M. Ramie. Avena hirsuta (Wood). Sicile. Ramie. (Avena sterilis L. var. hirsuta) Avena arundinacea (Del), de M. Letourneaux. M. Mandara. Festucacece. Kocleria phleoides (Pers). M. Alexandria. (Lophocloa phleoides (Will). Schismus calycinus (Wood). Schismus marginatus (Beau). Festuca calycine (L). M. Ramie. Poa annua (L). G. Alexandria. Poa cynosuroides (Vahl). M. Piramides. Eragrostis megastachya (LK). M. Ghizeh. (Briza eragrostis) (L). Chrysurus aureus (Pers).) (Lamarkia aurea) (Melh). M. Ramie. Dactylis repens (Desf). (Dactylis littoralis) (Wilde). Festuca fusca (Del). M. Sembeleven. Festuca divaricata (Desf). M. Ramie. Bromus confertus (M.B) M. Mex. Bromus rubens (Del). M. Ramie. Bromus madriteusis (L). Ramie. Bromus polystachyos (DC). M. Ramie. /3 136 Hordeacece. Trachynia distachyos (LK). (Bromus distachyos (L). Ramie. Lolium figidum (Goud) M. Ramie. Lolium siculum (Wood). Sicile. Ramie. Lolium arvense (With). G. Ramie. Triticum bicorue (Forsk). AE. Ramie. Catapodium loliseceum (LR). M. Ramie. (Triticum loliseceum (Smith). Aegilops triaristata (Wild). M. Ramie, Mex. Hordeum murinum (L). G. Sembeleven. Hordeum maritimum (Vahl). G. Ramie. Rottboelacece. Lepturus incurvatus (Tr.) (Rottbolha incurvatee (L). G. Ramie. Lepturus filiformis (Tr.) Rottbollia filiformiee (Rottb). G. Ramie. Cyperacce. Cyperus glaber (L). (de M’Letoumeux) M. Cyperus articulatus (L). (de M’Letourneux). M. Cyperus conglomeratus (Rattb). (de M’Letourneux) Cyperus mucronatus (Rottb). M. Rosette^ Cyperus panonicus (Rottb). (?) Alexandria. Cyperus longus (L). M. Alexandria. Cyperus fuscus (L). M. Alexandria. Cyperus Dives (Del) M. Rosette. Scirpus macrostachyus (Wild). M. Rosette. Scirpus Michelianus (L). G. Alexandria. Scirpus littoralis (Schrad). fimbrisetus (Del). M. Alexandria. Scirpus maritimus (L). corymbosus (Forsk). G. Alexandria. Schoenus mucronatus (L). Scirpus Kalis (Forsk) M. Ramie. N. B. — G signifie que la plante se trouve dans differentes parties et zones de l’Europe. M. — Fiore dite de la Mediterranee. Quand I’M est sum d’un point, la plante appartient a cotte categorie de la flore qui a sa limite Nord a Trieste a Faenza, en Ligurie, en Provence. A E. — Plantes trouvees en Egypte seulement ou dans la zone ^Egypto-Arabique, et Indienne. 137 PHYSICAL AND MATHEMATICAL SECTION. April 22nd, 1879. E. W. Binney, F.R.S., F.G.S., President of the Section, in the Chair. “ Colorimetric Experiments, Part II.,” by James Bottom- ley, B.A., D.Sc., F.C.S. In a short note which I read before this Society (Vol. XV., p. 63) I proposed to measure quantities of colouring matter in solution, using the formula qt=qt' in the calculation, ^ and g denoting quantities of colouring matter, and t} t' lengths of columns of coloured fluid \ the colouring matters being dissolved in equal volumes of water. Last session I gave the results of some experiments which I had obtained two years previously. Lately I have made some further experiments, which I give in this paper, along with some additional remarks on colorimetry. In my last paper I took 0001 grams as the unit of measurement. For comparison I have retained it in this, although the quantities used can can no longer be considered as traces. The colouring mat- tei used was ammonio-sulphate of copper. A solution was made by dissolving 10 grams of crystallized sulphate of cop- per in a mixture of 200 cubic c. of water and 50 cubic c. of ammonia. Mixtures of various degrees of intensity were made by taking portions of this solution and mixing with water so as to make up 500 cubic c. As in my last paper, A denotes the amount of the colouring salt present, B the length of the column of fluid, and C the amount of the colouring salt thence derived by calculation. Standard solution 4000 in 500 cub. g. of water (depth of disc 8’3) ABC 6000 4*3 7721 138 a result considerably remote from tlie correct value. Also when the disc was placed inside the solution at the depth given by theory, it seemed too dark. Next, a comparison was made by looking through the cylinders at external white surfaces. Standard solution 4000 in 500 cub. c. of water, length of column 8'4. ABC 6000 5-1 6588 Thus the result is considerably different from the real value. Also both experiments concur in giving too high a value. The theoretical depths moreover were tried with external surfaces, and seemed slightly too great. My next experi- ments were made with solutions containing 2400 and 1600 of sulphate of copper. The discs being inside the results were as follows : standard solution 1600 in 500 cub. c., depth of disc 8*3. ABC 2400 5-6 2371 The number under B was the result of seven trials. The value under C is a fair approximation to the real value. I also tried external surfaces with these solutions. Standard solution 1600 in 500 cub. c., length of column 8*4. ABC 2400 6*2 2161 somewhat further from the correct value than we might expect. I also tried the theoretical length of column ; with external discs it appeared a little too light. The results obtained with the last standard solution are inconsistent with the results obtained with the first. In the latter case the results are too low, while previously they were too high. Errors of observation arising from imperfect percep- tion of colour, from imperfection of instruments and unfavourable conditions of light (for many of the experi- ments were made during the winter months, sometimes on gloomy unfavourable days) would no doubt contribute to 139 this result, yet allowing for all these, there seemed to be some other cause. In my last paper I mentioned that an ammonaical solution of copper, when largely diluted, became turbid, and that to carry out the experiment an additional quantity of ammonia was necessary. This small quantity was added at hazard, as I did not think it would have any influence on the result. It seemed to me afterwards to be a point worth examining in connection with the above experiments. Two solutions were made, each containing 5 cub. c. of the previously mentioned copper solution with 245 cub. c. of water. The solutions were placed in similar cylinders — to one of the cylinders more ammonia was added : it appeared perceptibly darker than the other. Hence it appears that the excess of ammonia has some influence on the result. I presume that ammonio-sulphate of copper has a tendency to be decomposed by water, and that some change is effected even before it becomes obviously marked by the formation of a turbidity; moreover it seems likely that the excess of ammonia has the power to counteract this property of water, and to restore the original compound. Two solutions were made, the bulk of each being 545 cub. c., one containing 4000 of copper sulphate, along with an additional 20 cub. c. of ammonia, the other containing 6000 of copper sulphate with 30 cub. c. of additional ammonia. The comparisons were made in new cylinders graduated to millimetres. An experiment with white surfaces, external, gave the following results : Standard solution 4000 in 545 cub. c. of water, length of column 23 cm. ABC 6000 15-5 5955 thus the result is very near the real quantity. I also took shorter lengths of the standard solution, namely 18 cm., 13 cm., and 8 cm., the corresponding lengths of the other solution were 12-4 cm., 8*5 cm., and 5*3 cm. Reduced to 23 cm. 140 of the standard, the lengths would be 15 '8, 15, 15*2, numbers not far removed from 15 ‘5, which was got by observation. I repeated the experiment with fresh solutions, the bulk of the liquid being 500 cc. Standard solution 4000 in 500 cub, a, length of column 2T2. ABC 6000 14-1 6000 The number under B is the theoretical quantity, and was the mean result of four trials. Also with shorter columns of the standard liquid, namely 15*2 cm., 10'2 cm., 5*2 cm., the corresponding lengths of the stronger liquid gave similar tints. At the same time lengths differing a little from the theoretical would also satisfy. With these solutions I also tried an experiment with discs inside. Standard solution same as last : ABC 6000 12*3 6894 The number under B was the mean of 15 trials, thus the result with discs inside was not so good as with discs out- side. Also 14*1 cm. the theoretical depth when tried seemed slightly too dark with discs inside. I repeated the experiment with a solution containing 2400, using one containing 1600 as a standard. In preparing these solu- tions to the stronger I added 12 additional cub. c. of ammonia, and to the weaker 8. With external white sur- faces the results were as follows : — standard solution 1600 in 500 cub. c. of water, length of column 21*2 cm. ABC 2400 13-8 2458 The number under B was the result of fifteen trials. Thus we get a good approximation to the real quantity. With discs inside the results were as follows. Standard solution same as last : ABC 2400 12 2824 The number under B was the mean of twelve trials. The 141 value got with discs inside is not so good as with discs outside. Also the theoretical depth 14*1 cm. when tried seemed to be slightly too great. From the foregoing experi- ments it would appear that with considerable additions of ammonia the results with discs outside were much improved. Why the results were not equally good with discs inside may, I think, be accounted for, and will be considered further on. I also compared the solution containing 4000 with the one containing 1600. Standard solution 1600 in 500 cub. c., length of column 21 2. ABC 4000 8 4240 The number under B was the mean of eight trials. The theoretical length was 8 ’5 ; with the standard solution on the left hand this length seemed to give a similar tint, but with standard solution on right it seemed a little darker ; and now I remarked for the first time, or, if I had previously remarked it, had not thought it worthy of notice, that even an apparently so trivial circumstance as altering the posi- tions of the cylinders from right to left had a perceptible influence in the determination of colour. I afterwards made some experiments to test this. Next I compared solutions containing 1600 and 6000. Standard solution 1600 in 500 cub. c., length of column 21*2. ABC 6000 5T 6682 The number under B was the mean of eight trials. The result is not so satisfactory as the others. I also tried these solutions with white surfaces inside. Standard solution same as last : A B C 6000 3-9 8697 A widely remote result, and much further from the rea] value than with discs outside, also a disc placed in the solu- tion at the depth assigned by calculation seemed too dark. It seemed possible to me that a more satisfactory result 142 than this experiment had yielded might be obtained. The excesses of ammonia used in the experiments were nearly proportional to the quantities of sulphate of copper in solu- tion ; but if we regard water as an agent whose tendency is to diminish the intensity of the colour, and ammonia as an agent whose tendency is to restore the colour, it would seem reasonable that the ammonia should be proportional to the water. The difference of the excesses of ammonia in the last two solutions was large, being 22 cub. c. I pre- pared fresh solutions, one containing 4 cubic c. of the copper solution with 30 cub. c. of additional ammonia and suffi- cient water to make 500 cub. c. The other solution con- tained 15 cub. c. of the copper solution with 30 cub. c. of additional ammonia, and sufficient water to make 500 cub. c. The quantities of the copper solution taken should cor- respond to 1600 and 6000 of copper sulphate ; to guard against imperfect measurements from the burette; I also weighed the solutions. The 4 cubic centimetres weighed 3‘9854 grams, and the 15 cubic centimetres weighed 14-99 grams. The ratio of the volumes is 375, and the ratio of the weights is 3-761, so that the error of measurement would be but small. With discs outside the results of experiments were as follows. Standard solution 1600 in 500 cub. c. of water, length of column 21*2. A B C 6000 6 5653 The number under B was the result of eight trials ; also the standard solution was on the left hand. With the standard solution on the right the results were ABC 6000 5-4 6283 The number under B was the mean result of eight trials. In one case the value got by experiment is too high, and in the other too low. The theoretical length is 5-65, and 1 43 5*4 is not very far from it. When I actually tried a column of the theoretical length it seemed to give the required tint when the standard solution was on the left; when the standard solution was on the right it seemed a little darker. The mean of the two values previously obtained is 5968, which is near to the real value. From the above experi- ments it seems that when excesses of ammonia are added, very fair approximations may be obtained by colorimetry to the quantity of copper sulphate in solution, the white surfaces being external. Also that with white surfaces internal the results are more remote. In my last paper I stated that when there was much difference between the standard solution and the one to be compared with it, the discrepancies when internal discs were used were consi- derable. Then I was using very small quantities of colour- ing matter. From these experiments where the colours were intense and the quantities of colouring matter used considerable, a similar conclusion follows. The reason for this is not far to seek, and it also suggests a correction that must be applied to the formula when the white surfaces are inside. A white disc inside a column of coloured liquid looks darker in colour than a white disc outside, placed a few inches below a column of the same length. This may be tried by looking through different columns, or through the same column, and having inside a white disc of smaller diameter than the cylinder ; the inside disc will then appear surrounded by a rim of lighter colour. When the disc is internal, it is evident that the light which illuminates it has previously passed through the solution, so that we are look- ing not at a white disc, but at a coloured disc through a coloured solution. Some allowance must be made in the calculation for this coloration of the disc. The formula qt = qt' is applicable to the case in which the surfaces are outside ; to adapt this formula to the case when the discs are inside, suppose x to be the length of the column of fluid 144 which would cause the difference in colour between an external and an internal surface, then the formula would he q(t + x) = q(t' + x). To find the value of x experimentally, I took a solution containing 2400 and sunk a small disc in it until the inside and outside colour seemed the same ; for the outside the length of column was 22f5 ; for the inside 17 7, this being the mean of eight trials. The difference is 4-8. With a solution containing 1600, a white surface out- side, with length of column 21 % seemed to give the same colour as white surface inside with length of column 16*2. The difference is 5. 1 also tried to get the value by the following combination. A solution was taken, containing 2400 with disc inside, and compared with a solution contain- ing 1600 with a disc outside ; length of column in latter case was 21*2, in the former case a column 17*5 seemed to give a similar colour. From the formula q(t+x) = q't' the result- ing value of x would be 5 2. I also tried the following com- bination. Solution containing 2400 and disc outside was compared with solution containing 1600 with disc inside — the mean of eight trials gave length of column 17 in the latter case, equivalent to 21 2 in the former; from the for- mula 1600 (17 + $)=2400 X 21*2, the resulting value of x is 4’3 — finally we get for the approximate value of x, taking the mean of the four determinations, x=4r8 The experi- mental determination is not easy, but the value obtained gives better results when we use it in the formula ; for in- stance, on a former occasion with discs inside, when a solution containing 1600 and length of column 21 ‘2 was used as a standard, and there was compared with it a solu- tion containing 2400, the length of column was 12; from the uncorrected formula the result is 2824 ; from the for- mula ^(12 + 4-8) = 1600(21-2 + 4*8) the resulting value of q is 2476, which is not far from the proper value. When the fluids compared differ much in 145 strength, the value of the correction will probably vary. It will be better not to have the difference large, whether the discs be external or internal, for when the differences are large any errors in the determination of the lengths of the columns have a greater effect on the calculated result. I also tried to make a rough estimate of the length of the cylinder, which might be covered without any perceptible darkening of the disc. I found that a black cloth cover investing the cylinder might be drawn down until it was about 3 5 or 32 cm. from the disc; this would vary with the dimensions of the window and the relations of the cylin- der to it. Also the length given is less than the value of x previously deduced ; but it ought to be so, for the light from a vertical window to illuminate a horizontal disc must pass obliquely through the solution. It would a]so follow that parts of the disc more remote from the window are darker than parts nearer, hence if the cylinders are of moderate radius, either the discs should be small and should be kept with their centres moving along the axes of the cylinders, or in the case of larger discs the determination of colour should be made by a comparison of similar parts of the discs. In the estimation of colour it is also not a matter of indifference, when we are given any tint as a limit, how we approach that limit. Suppose we have two cylinders, a and j3, full of coloured liquid, that in a being the darker. Now pour out from a until the colour seems the same as in (3 ; before reaching the theoretical division sight will fail to discern any difference of colour. Now if we proceed cautiously, as we approach the limit there will be a natural hesitation and tendency to stop, and it seems likely that in most cases in obedience to that feeling we shall stop with a column a little too long. Now suppose we start with the cylinder a empty, and pour fluid into it; as we again approach the limit cautiously we shall again have a tendency to stop, and inasmuch as before reaching the limit we pass 146 through tints which we cannot distinguish from it, we are likely to take a column of fluid too short. In my own case I have noticed this on several occasions ; for example, in trying to estimates particular colour the mean of seven trials made by pouring out from the cylinder gave 141 as the length of the column, the mean of seven trials made by pouring into the cylinder gave 13*7 as the length, and with discs inside the mean of six trials made by moving the disc from below upwards gave 12 5 as the length of column, while moving from above downwards the mean of six ex- periments gave 11*7. In trying to estimate a colour it seems to me that it would be well to approach the limit by both ways, and then take the mean of the results. In a previous part of this paper I stated that altering the position of the cylinders made a little difference in my perception of colour. I made some experiments to try this. I took a solution containing 2400 and poured from the cylinder on the right hand into the cylinder on the left hand- the columns ought to be equal. The mean of nine trials o-ave length of column on right hand 112 ; length of column on left hand 10-61. In these experiments, the judgment was made using both eyes. I next tried using one eye only — with the right eye the results were, length of column on right hand 1 0*86, length of column on left hand 1109; these numbers were the mean of nine trials. With the left eye alone, the results were, right hand cylinder 10-78, left hand 1101, being the mean of nine trials; thus using one eye only, the results are nearly the same in both cases ; they also tend to make the right hand a little less, thus reversing the case of two eyes. These experiments were made in a room with a small window facing the south. I afterwards repeated the experiments, using two eyes, in another room having a window of larger dimensions and facing the north. A solution was used containing 1600, the mean of nine trials gave right hand cylinder 11*16, left hand 1055, nearly 147 the same results as I got before. Why I should have this tendency to make one column a little larger than the other I do not know; possibly it may be some peculiarity of vision confined to myself. In the course of my experiments I have also noticed the following curious phenomenon, and this repeatedly, when working with solutions coloured with bichromate of potash, and with ammonio-sulphate of copper ; look steadily with one eye, say the right, through the solu- tion at a white surface, after the lapse of abour a minute suddenly turn the head so as to bring the left eye close over the cylinder, then the colour will seem more intense than it did with the right ; having looked with the left eye for about a minute, bring again the right eye suddenly close over the cylinder, and the colour will seem more intense than it did with the left, and so on alternately. It would seem as if the first impressions of colour on the eye were the stronger, and as if there were a gradual and imperceptible decrease in intensity — perhaps alterations in the aperture of the pupil may contribute to this. Another matter for consideration in colorimetry is the nature of the incident light. On some occasions we have the light from a blue sky; on other oc- casions the sky is invested with clouds of various depths of grey, or sometimes tinged by the sun with a variety of tints, from yellow to red ; while the light of the sun itself is fre- quently yellow or orange. All these variations of light are likely to have some influence in our judgment of colour, especially when the tints to be compared are light. Of the disturbing influence of colour in the incident light, anyone may convince himself by comparing yellows on a morning when the sky is enveloped in a yellow fog. In some experi- ments which I made with bichromate of potash during such fogs, I found it much more difficult to decide at what depth equality of colour was effected ; the disc in the stronger so- lution could be moved through a very considerable range without any change of colour being perceived. A similar 148 result happened when I hung up yellow screens and tried to make determinations of colour behind them ; also when looking at light yellow external surfaces, differences in the lengths of the columns failed to give any difference in tint, although when looking at white external surfaces they did so. But in quantitative determinations of matter by colo- rimetry, the excellence of the results require sensible varia- tions in colour when we alter slightly the length of the column ; hence when the incident light is tinged with the colour we wish to determine the advantage of the method is diminished. Such a consequence may also be deduced from the formula which I obtained in my last paper. For sup- pose white light to consist of yellow, blue, aud red (as far as the reasoning is concerned we might have considered it also composed of green, red, and violet, as some physicists do). Let I denote the incident white light, and B, Y, It the intensities of blue, yellow, and red necessary to produce white light, so that we may write : I = B + Y + E. Let there be two solutions containing q and q' of yellow colouring matter, and t and t' the corresponding lengths of columns; then the intensity of the light transmitted through one cylinder will be (1 - mqt) Y + (1 - mxqt)R + (1 - mxqt) B, m denoting the amount of yellow light absorbed by a unit layer, and mx the amounts of red and blue absorbed by a unit layer. Also the light transmitted by the other cylinder will be (1 - mqt1) Y + (1 - miqt'JR + (1 - mqt') B. Since both cylinders are of the same colour these expres- sions will be equal, m will be less than mx because the transmitted light is yellow ; let m = mx - fi. Then we shall have 1(1 - mxqt) + fiqtY - 1(1 - mxqi) + fiqt! Y) (A) The expression on the right hand denoting the light trans- mitted through one cylinder, and the expression on the left 149 hand denoting the light transmitted through the other cylinder. Each expression consists of two terms, the terms of the form 1(1 — m-yqt) denotes the white light transmitted, the term of the form pqtY denotes the excess of yellow ; this term we may call the effective yellow, for it is the only portion which produces the sensation of colour. Now sup- pose the light before passing through the cylinders to pass through a yellow screen, suppose the composition of the incident light after transmission through the screen to be pY + piB + pih, p being greater than p1} say p = p1+r, so that the composi- tion of the light may be written Pil + rY, rY being the effective yellow after passing through screen. After using the screen the left hand expression of A would become I/o1(l - mxqt) + Yr - Yrmxqt + pxqtYfi. Since qt = q't', if we substitute eft' for qt in the last expres- sion, we shall get the light transmitted by the other cylinder after using a screen; hence if the columns be adjusted so as to produce equality of colour with white light, they will still be in adjustment if the light should become tinged with yellow. Let yx and y 2 denote the effective yellows in one of the cylinders with white incident light and with yellow light ; then we shall have y1 = fiqYt y2 = Yr - Yrniiqt + Y pXfiqt Now suppose the length of the column of coloured liquid to be altered a little so as to become £ + §£, let Syx and Sy2 de- note the alterations in the effective yellow in each case, then hy% = (Ypi \xq - Yrmxq)U tyi = Y pqU Hence <^2 ~ tyi= “ { Yrvthq + /JLqY(l - pi)}&5 Therefore Sy is less than Sy1} that is to say, we shall not see 150 so much difference of colour for a given alteration of depth when the light is tinged with yellow as when it is white ; therefore the sensibility of the method is diminished. This may he put in another way. When the incident light is tinged yellow, the expression for the effective yellow after transmission through the cylinder is Y r - Yqt(rm1 - px/i) Suppose the term in brackets to vanish, then the expression for the effective yellow becomes Y r, which is independent of the quantity of colouring matter and of the length of the column. I