Digitized by tine Internet Arciiive in 2010 witii funding from Lyrasis IVIembers and Sloan Foundation http://www.archive.org/details/reportofjameshig1849mary [ Document G. ] BY THE HOUSE OF DELEGATES, January 220(1, 1850. Read, and three thousand copies ordered to he printed. February 19ih, five thousand extra copies ordered to be printed — five hundred of which to be placed ai the disposal of Dr. Higgins. REPORT OF JAMES HIGGINS, M. D. STATE AGRICULTURAL CHEMIST, to THE HOUSE OF DELEGATES OF MARYLAND. ANNAPOLIS: KtLBr AND DAVIS, PRINTER »■ 1850. REPORT The Legislature of Maryland at the session of 1847, 48, crea- ted, the office of Agricultural Chemist by the following act: CHAPTER 249. An act entitled, an act lo provide for the appointment of an Agri- cultural Chemist for the Slate. Section. 1. Be it enacted by the General Assembly of Mary- land, That the Governor by and with the advice ami consent of the Senate, shoU hereafter annually appoint and commission a per- son of ability, integrity and suitable piactical and scientific attain ments, as Agricultural Chemist for the State, and if (he Senate shall have adjourned before the Governor shall make the appoint- ment for the present year, or if a vacancy shall hereafter occur during the recess of the Senate, then the Governor alone shall make such appointment, which shall be good and valid until the tenth day after the meeting of the Senate. Sec. 2. Beit enacted, That the State shall be divided into three districts ; the fiist shall comprise that part of the Stale now comprised in the first Gubernatorial district ; the second that of the third Gubernatorial district ; and the third that of the second Gu- bernatorial disliict. Sec. 3. Be it enacted, That the said Agricultuial Chemist, shall spend one year, the firs tbeginning on the date of his appoint- ment, in each of said districts in the order named, it shall alse be his duty to spend one month in each county and Howard District, and visit each election district. Sec. 4. Be it enacted, That it shall be the duty of said Agri- cultural Chemist, to analyze specimens of each variety of soil of the county in which he shall be, that may be brought to him or that he may find to exist, and also to examine and if necessary analyze specimens of each kind of marl or other vegetable or mineral deposit that may come to his knowledge, in order that his instructions may be of more practical utilil3^ Sec. 5. Be it enacted, That it shall also be his further duty to deliver one public lecture, after having given timely notice there- of, in each election district in each count}'^, and then to deliver a course of public lectures at each county town, and at some central place in Baltimore county, after having given also sufficient notice [G] 4 thereof in each election district, and he shall also pennit the clerk of the lev}^ court or the comnnissioners of tax as the case may be, to tiilce a copy of sucli couise of lectuies, to be retained and kept for the use and benefit of the county, and published by said levy court or commissioners of the tax if to them it shall seera ex- pedient. Sec. 6. Be it enacted. That the said chemist shall make an annual report to the House of Delegates if in session, and if not then to the Governor, whose duly it shall be to cause the same to be published, of his proceedings, and such other matters touching the agricultural interest of the State, as may be consder- ed necessary. Sec. 7. And be it enacted. That for the faithful discharge of his duties, the said chemist shall receive the annual salary of fif- teen hundred dollars, to be paid as the salaries of other ofiicers are or may be paid, and for the purchase of chemical implements and materials, the said chemist shall be allowed for the first year, the sum of two hundred dollars in advance, and on each succeeding year a sum not exceeding fifty dollars, out of such monies as may be in the Treasury not otherwise appropriated. I had the honor to receive the appointment under the above law, and as soon as the necessar}'- apparatus, tests and reagents coidd be procured, commenced the discharge of its duties. A p;ut of those duties was to analyze the varieties of soil to order to determine the presence or absence of the necessary con- stituents of crops; — to see whether they existed in sufficient quantities, — to recommend the application of such particular sub- stances as would most economically supply whatever defects might exist; to render barren soils fertile, and retain the fertility of those which might be productive at the present. To determine the necessary constituents of crops, we have only to examine thorn by the aids which analytical chemistry affords, and when we find particular substances always present in them, when we find that alihough in different plants they exist in varia- ble proportions, yet that they are always present, we must con- clude that they are the substances necessary to the existence of vegetable life. There are certain substances to be described hereafter, which are always found in plants; in no clime, in no * country, under no circumstances do we ever find the one without the other. The conclusion then is, that these substances are necessaiy to the existence of plants. But tl^.ere is another and a stronger proof. The object and aim of all cultivatioji is to sus- tain by the food wdiich it produces, the human body. This food then, must contain all of ihe elements which enter into the com- position of the body, if it did not, it could not subserve the pur- poses of nutriment. The human body is always losing some- thing by exercise, some hing by disease, nay, something by breath- ing— (the very act of life.) which is again supplied to it by the food which it takes undei the instinct -of the appetite. If this food did not contain all of the elements thus lost, some part of 5 [G] the body would not be renewed and life would end. Food must contain not only the elements of blood and bone, but of all the tissues of the body; and as all food,i5 either directly or indi- rectly supplied by plants, the plants must contain them. These sulistances ihen arc the necessary conslituenl:-- of plants. It is out of place here to speak of tiie manner in which the dements of vegetable structure are converted info the different substances which enter into the composition of animal bodies, and I shall say nothing on thai subject. The necessary constituents of soils are determined by a know- ledge of what plants require. The food of plants is derived from the air which surrounds them, and from the soil in which they grow. We shall not in this place say of the atmosphere any more ihaa that if the soil cannotobtain the proper food from it, then thai food must be supplied artificially, or sterility will be the inevitable con- sequence. A certain portion of the elements of plants cannot from their nature exist in the atmospliere; they must then be pre- sent in the soil or vegetation cannot be produced, because witliout them plants cannot be formed. We can in this manner perfectly as- certain what substances are necessary to the plants that are used for food, from our knowledge of the matter in a human body which is furnished by that food, and also perfectly ascertain what are the necessary constituents of soils from a knowledge of the materials which those plants require for their complete develop- ment. The hQil proportions necessary to constitute a fertile soil can only be determined b}"^ the chemical analysis of a large num- ber of fertile soils. With each examination one certain step is gained in the solution of this great question. As examinations become more numerous tlie minimttm quan- tity, that will produce the largest yield v/ill be ascertained, and then the perfection of Agriculture will be attained. Of the substan- ces to be described hereafter all must be present to constitute a fertile 50?/and they not only be/)rese«^, but they must be in sufficient quan- tities, and in a form to supply the v/ants of the crop. What the best quantity is has not yet been exactly ascertained. Vv^e must not reject the aid of science, because it cannot ai once give us a perfect system, we must compare what it affords with what exists with- out its aid. The one system is possessed of a degree of certainty continually approaching to perfection, the other is altogether em- pirical, and never takes one certain forward step. I have said tliat all of the necessary substances must be present, and I moreover add that an excess of any one cannot compensate for the absence or deficiency of another. So tliat we have this general rule, that the fertility of a soil depends not on the quantity of several of the necessary constituents, but upon the proper pt^o- portion of them all. To show this, I submit the following table, the facts of which are taken from numerous analyses made in England and Ger- many, by men whose reputation vouch for their truth, and from some made by myself in this State. [G] 6 It is only by faclsofthis kind, well established and indisputable facts, that principles in agriculture or in any art or science can be de- monstrated. The creations of fancy however beautiful cannot now satisfy the human mind in its yearnings for truth. It seeks for and is only contented with what is proven by exact demonstration. Now no mere hypothesis however brilliant, can be received with blind confidence. No theory now, however fascinating, can be tolerated, that is not founded on legitimate deductions from indu- bitable facts. Experimental inquiry and scientific invesiigations must be appealed to, to satisfy all doubts; for the human mind is not satisfied with explanations of that which it does not under- stand by assumptions more incomprehensible than that which is sought to be explained. A soil may contain any or even all save o}ie of the constituents of a good soil, in the large proportion indicated below and yet be unproductive. Lime, 1.65 *1.80 *6.2o Humus, 3.98 *4.10 *3.60 *3.88 Magnesia, .16 .28 .73 .80 *1.25 Potash, .05 .15 .30 *1.20 Soda, *.10 *30 *.85 *1.65 «2.13 Phosphoric acid, .19 .198 .36 .40 .20 Animal and vege- table or Organic matter, *1».12 *25.00 *32.16 *52.17 Chlorine, .06 .08 *.U *6.21 *.42 Sulphuric acid, .051 *.082 *.255 *267 Alumina or pure Clayi 5.25 7.97 *13.21 *18.50 Silica or Sand, *92. *95.6l ^97.84 *98.00 Iron as per Oxide, *8.14 *10.30 «17.75 *29.00 All these soils were unproductive so that it h proven by the above facts, that a soil may contain five hundred and forty, or even eighteen hundred and seventy-five bushels of lime, distributed to the depth of twelve inches, that it may contain three hundred and seventy-five bushels of magnesia, that it may contain sixty bushels of phosphoric acid, equal to about two hundred and forty bushels of bone dust, or that it may contain three hundred and sixty bush- els of potash and yet be barren, sterile and unproductive and not repay the cost of cultivation. The sanie is equally true of any number, save all of the constituents of a gDod soil. On the other hand it is proven that soils very productive partic- ularly for wheat, may contain the small proportions of any one Those marked thus* are soils of our own State. N. B. .1 or .1 0 is the one tenth of one per cent., and is equal to about thirty bushels to the acre of the substance it represents, the specimen being taken to the depth of twelve inches. It is equal to the one-thousandth part of the specimen. 4 7 [G] of (lie necessary constituents, the rest being present in proper pro- portions. This is shown below. .02 Lime, .29 *.32 *.40 Magnesia, *.21 *=.18 *16 *.12 Potash, .12 .10 .08 .06 Soda, ' .09 .03 .018 Pliosphoric acid, .02 .01 Organic matter, .67 Chlorine, •003 •002 Sulphuric acid, •005 •008 Silicia (sand,) 64.5 59.21 Alumina, 1. l.TO 2.60 Iron as per Oxide, 1.25 1.06 •69 It is shown from the above that a very fertile soil may contain only eight-seven bushels of lime to the acre, to the depth of twelve inches, or only two one-thousandth of a bushel of chlorine, or as little as six bushels of potash, or three of phosphoric acid, to equal to about twelve of bone dust. Hence on the examination of a soil, if we find the above pro- portion of any one of the necessary constitutents, in a form capable of being used by plants, we must conclude that enough of that particular constituent is present. If the soil be unproductive we have to look for and counteract some other chemical or mechani- cal deficiency. To letainthe fertility of a soil already productive, it is neces- sary to add to it a quantity of fertilizing matter equal to that which is taken off by the crop, allowance being made for the por- tion which may be lost by percolation through the soil. By doing this we can in a very cheap manner alw;ays retain soils at whatever point of production, they may have, and even have their productiveness increased, a soil which from its texture, is particu- larly good for wheat, may thus be kept in a condition to produce a crop every year without any rotation. The same is true with regard to corn or any other crop. SOIL. f By this term is understood in an agricultural sense that portion of the earth's surface which serves or may serve for the produc- tion of crops. Under all circumstances where a blade of grass and the smal- lest seed are produced, there axe present all of the necessary consti- tuents of fertility. The quantity of these things present, when taken in connec- tion with its physical character determine the fertility of a soil. In all soils which are not absolutely barren we have the follow- ing constituents they being in fact the soil, the things out of which the soil is made. Those marked thus * are soils of our own State. [GJ 8 ORGANIC MATTER. This is animal and vegetable matter considered, without refer- ence to its inorganic constituents, and is composed of the remains of plants or animals which existed on the soil. It is called orgaiiic, because it has at bne time entered into a form capable of perfonning the functions of life and has become a part of those things which are called organs, whose duty it is to perform pro- cesses, without which there cannot exist that system of vital func- tions which we call Life. At one time very great importance was attached to vegetable matter in soils, many teaching that it was the indispensable thing to fertiHty, and that lands were productive in proportion as they contained a greater or less quantity of it. This hds been shown by numerous examinations not to be the case, for the productive- ness of soils bears no relation to the quantity of organic matter which they contain. Its use is now restricted to giving the necessary degree of porosi- ty to stiff compact soils^ and by its decomposition to render raiaj water or dew better solvents of Jhe mineral constitutents of a soil. Every grain of sand contains some, sometimes all of the necessary constituents of crops, which are however of no use until they be- come dissolved into a state capable of being taken up by plants. Whatever will effect this is of service in a soil. Vegetable matter contains a large proportion of carbon, (charcoal,) which an ex- posure to the air is changed into carbonic acid. Water impreg- nated with this substance, has the property of powerfully dissolv- ing all the minerals found in a soil, and by this means rendering it inore productive. Its quantity varies greatly in different soils. in some I have found less thari one percent, and in others, "the Black Gum Swamp Soils" of Worcester and Somerset as much as sixty-two per cent. Secondly, SILICA, OF SILICOUS EARTH OR SAND, Exists abundantly in all soils. Though having none of the sen- sible properties of an acid, it nevertheless belongs to this class of bodies, and combines with bases to form salts. It very rarely exists in a pure form in the earth, being almost always in union with some other substance, and forming a class of bodies called silicates. With alumina and the per oxide of iron, it forms our red and yellow clays, it most generally is associated with lime, mag- nesia, potash or soda. The "grains of sand" in soils are compos- ed of pure sand, (silicic acid) in combination with some of the above substances. In pure water these combinations are quite in- soluble, but water charged with carbonic acid, dissolves them in a sensible degree. When in the nascent state, that is, when first set free from its combinations, water dissolves pure silicic acid very readily. Besides its determining the mechanical properties of soils and when in a very fine state of division acting as a substitute for 9 [G] iron ond cla}' in tlieir absorbent capacity , it has a morfe particular use, thai of fofjuing the stalk and stem ot plants and the husk or out- ward envelope of llie grain. In combination with potash, soda, lime and magnesia, but more pariiculaily witli po'.ash, it gives hardness andiirmness lo ihe stalk of grasses, indian corn, wheat, rye, oats, etc. It gives strength to tiie stalk to support the weight of the blades and ear, forms chaimels for the circulation of the sap, and for the trnnsn^ission from the root of whatever nutriment other pans of the plant may require. Without the presence of thia substance, and that loo in a suitable state to be taken up by ih© roots, whatever quantity of the other constituents of plants might be present in a soil, vegetation could not arrive at any perfection. If the materials for the grain or ear existed, still theie would be no stalk to support them. The quantity in different soils varies from thirty-five pet cent in the "Black Gum Swanip Soils" of Somer- set and Worcester, to ninety-two and seventy-four liuudreihs in some of the soils of Cecil, Kent, Q.ueen Anne's, Talbot, Caroline and Dorchester counties. The soils which in common parlance are called "Sandy Soils" frequentlv contain no more sand than those which are called ''White Oak Soils, or Pipe Clay Soil." The difference in their texture is due to the size of the indi- vidual grains of sand and not to the quantity which actually exists. Other things being equal, the finer the grams of sand the better the soil. As the growing crop can only use such materials as are already in or can be reduced to a soluble state; whatever can con- duce to the slate of solution will benefit them. The finer the grains of sand the more easily they are acted on by atmospheric agency, and the more speedily will they yield whatever substan- ces they may contain. But there is another and a very great dif- ference in the value of coarse and fine sand. A large part of the food of plants is derived from the atmosphere. This food must be absorbed wholly by the soil in the early growth of the plant, and if the soil has not the power of absorption, the plant will pine, lan- guish and die, unless it be supported by applied manures. Sand m a very fine state of division has powerful absorbent qualities, it absorbs and retains atmospheric food for plants and to a very great extent supplies that place of alumina (clay) and the per oxide of iron, which are famous for this property. IRON. Another constituent substance of soils is iron. It always is present though not in the form of metallic iron, but in the state or condition of an oxide of iron. When metallic iroQ is exposed to air and moisture, it becomes rough and covered with reddish or brown scales. This is what is called in common lan- guage rust of iron, the process is called rusting. In chemical language it is called the oxidation of iron and the product an oxule of iron. In soils it is generally in the condition of per oxide or its highest degree of oxidation and gives a reddish or 2 [G] 10 brown color to them. It is this which gives our red and yellow clay soils their peculiar color and frequently also tinges $and — which thus colored is called Ferruginous sand. It has several imporlaot uses in the soil. '. 1st. It is one of the necessary constituents of tlie human body being always found in the blood of healihy persons. From ihe impossibility of its existence in the air, we know tiiat the body must be supplied with it from the food which it consumes; but the plants used for food can no more obtain it from tiie air, than ani- mals can, hence they must obtain it from the soil, and it is there- fore a necessary constituent of soils. Not only is it itself food for plants, but it is a gatherer of food for them from the atmosphere. Baron Liebig, oaeof the ablest writers on agricultural chemis- try, of this or any other day, thougli oveilooking the first use of ironin a soil, so cleaily and satisfactorily explains the second, that I cannot do belter than use his own words: * "Per oxide bf iron and akimina" says this able and eloquent writer, "are distiiTguished from all other metallic oxides," (i- e. rusts of metals,) "by their power of forming solid compounds with ammonia. The precipitates obtained by the addition of ammonia to salts of alumina or iion are true salts in which the ammonia is contained as a base. Minerals containing alumina or oxides of iron, also possess in an eminent degree the remarkable pioperty ^ of attracting ammonia from the atmosphere and retaining it.' # # # a; Soils therefore 'containing the oxides.of iron and- burned clay, n>ust absorb ammonia, an action vrhich is favored by their porous condition ; they further prevent by their cliemical pro- perties the escape of the ammonia once absorbed. Such soils act indeed precisely as a mineral acid would do if extensively- spread over their surface." ' "The ammonia absorbed by the clay of ferruginous oxides is separatedby every shower of rain and conveyed in solution to the- soil." -.iwAf^Bi' Our red and yellow clays need not burning, the iron in them being already m the state of per oxide, heat would not benefit them. It isonly in the white or dark clays where the iron is in the state of protoxide, that heat would be of any use li applied. The per oxideof iron in a soil, also absorbs and retains mois- ture, and whatever else of the food of plants which exists in the air. .3rd. It gives firmness and compactness to the soil, afld better fits it for those plants v/hich flourish besi in those soils. 4lh. It gives color to soils vv'hich makes them absorb heat bet- ter, and in this way it gives crops a quick, early growth.. The quantity of the peroxide of iron, which exists in soils is very variable. In the red clay lands of Cecily I have found as much as (4.80^,) four and eight tenths of one percent. In some of ♦Chemistry in its Applications to Agriculture and Physiology. (Edited by Lyon Playfair and Dr. Gregory, 4th London Edition.) 11 - . [GJ . .'ii: ;:;:vf;f:i!., the while oak lands as liillo as sixty eight hinidredihs of one per cent, la some of ihe lio^ht sandy soila in CuroUne, Dorchester, Souierset, VVor(;e3ter, and in those lying on ooth sides of the Chester livef, occasionally a fraction less, .04. As a general rule, the quantity of it in the soil decreases, as we go down the Shore. ALUMINA. Pnre clay or alumina is another of the constituents of all soils. It, like iron, is the oxide or rust of a metal call aluminum whifth never exists naturally in ks pure state. "The diOerent kinds of clay of which pipes, procelain and earthenware are made, consistfe of hydrate of aUnnina, in a greater or less degree of purity." Il has not the same important action as iron in the human economy, but Its uses in the soil are very nearly the same, giving it tenacky. and firmness, absorbing, like it, moisture and food from the sit'- mosphere, forming "true salts" with ammonia, and having, like it, the properties of an acid or an alkali ; of an acid, by uni- ting with alkaline bases such as potassa, lime and baryta; and of an alkali, by forming salts, with acids. Our red and yellow clays are by no means pure alumina, but silicates of alumina and the per oxide of iron, united with lime, magnesia, and eome- limes with potash, and very rarely with soda — that is, pure sand chemically united to these substances. It varies in soils from (.72) seventy-two hundteths of one per cent, in light sand soils, to as much 5.25 in others. In those soils which are common- ly called '-pipe clay or white oak soils," it is not in such propor*- tions as persons usually imagine, being very rarely over 3.75 pei- cent, and sometimes as little as 1.02 per cent, in them. Where it exists in the proportion of fiom nine to ten per cent, good buildin<»" br'cks may be made. In the clay from which tbe best Baltimore bricks are produced, 1 have never found more than 19.50 per cent, of alumina. Sand in a very fine state of division, as is the .case in ihe "pipe clay or white oak soils" ma}'' be a substitute to a certain extent, for both iron and clay. LIME. , '^i'he great use of this substance as a manure, and the frequem benefits that result from Its application, make almost superfluous the bringing forward of any proofs of its necessity in a soil. Lime, like alumina, is the oxide or rust of a metal, never existing naturally in its pure state. The metal of lime is called calciqra. Lime exists in a soil sometimes as carbonate, that is air slaved lime, but most generally as silicate, that is chemically united to silicic acid, or sand. In the human body in union with phd5]iho-- lie acid, it forms a very large part of the bones. ' It exists itf Com- bination with diflferentaCTds in the root, stalk, blade, and giiiin of all plants. ' . i - . Besides the necessity of its presence to form the structure of plants, it performs many other important functions in a ^oil. It promotes the decomposition of vegetable matter, and thus causes [G] 12 to yield the different miueral substances which it contains, as means for the production of another growth. It improves the mechanical texture of land ; this is but one of its smallest uses. It powerfully aids the disintegration of the minerals (grains of sand,) in a soil, whicli contain many of the necessary elements of plants, and which, without ihe, finxing or fusing power of lime, would still retain them. This is one of its greatest and most im- portant uses, and we cannot yet say, whether or not, lime, when applied to a soil, does not act more beneficially in this way than iu any other. More investigations by chemical analysis, assisted by practical experiments, must be made than have yet been, to settle this question, and lo determine in what manner, under what cir- cumstances, and in what quantities lime acts best. In none of the soils which I have examined, has it been found in sufficient quan- tities, except where, at some time or other, it has been applied artificially. For other information — see the airicle on it, under the head of Manures. MAGNESIA. Magnesia is the oxide of rust of a metal called magnesium^, which never exist naturally in a pure state. It is one of the neces- sary constituents of soil, being found in the bones of animtds, and in the roots, stalks, leaves, and gr-ain of plants. It has, in many respects the same action as lime, and lo a certain extent can be substituted for it. The quantity of it varies in different soils. In some I have found as much as one per cent equal lo about three hundred bushels to the acre, to the depth of twelve inches, and in others but a mere trace. The facts to show what the best quantity is in a soil, are very meagre. As far as my knowledge extends, I believe that where it exists in a less quantity than one- tenth of one per cent in a soil, magnesian lime is the best appli- cation for that soil. There have, as yet, been no experiments on the subject, and no means taken any where as far as I know, save in Maryland, to lay down any foundation for experiment that will be worth any thing when made, ftly own knowledge, as to the action of it, is derived from gentlemen who have used both mag- nesian and oyster shell lime on their lands, and from analyses of the soils which I subsequerrtly made, have led me to the above opinion, and are the only data yet given to the agricultural community on this subject. POTASH. Potash, the oxide or rust of a metal called potassium, is another of the necessary constituents of soils. In union with silicic acid it gives strength and firmness to the stalk, and to the husks or en. velopof the grain. The proportions in which I have four^d it to exist in soils are very variable, from a mere trace in some, to as much as (1.20) one and two-tenths of one per cent in others. But a very small quantity is absolutely necessary. I have known a very productive 13 [GJ soil to contain aa little as (.05) five one luindreths of one per cent, and liftcen bushels of wheat to be produced where only (.008,) or the eighth one thousandth part of one per cent existed. SODA. Soda, the oxide or rust of a metal called sodium, is another of the necessary consiituents of a fertile soil. It has nearly tha same uses as potash, and may be subsiiluled for it to a ceitain exMent. It cxisis in various proportions in soil, but a very small quantity seems to be all that is necessar\'. I have not been able to make very satisfactory examinations in relation to this substance, a3 the section of (!ie State where I conducted them was supplied, to some extent, by air from the saltwater which surrounded it on every side. The quantity in the soil, therefore, could not be taken us proof of the quantity necessary to suppl}' the crop. On salt water, land produces wheat with bright strong straw, whilst land remote from it with an equal quantity of inorganic jnaiter, will not do this, because it i? not supplied with soda from the atmosphere. PHOSPHORIC ACID. Is also one of the necessary constituents of a fertile soil. With lime and magnesia it forms about fifty per cent of (he bones of animals. Its elements arc also found in the biood and brain, and in combination with difi^erent bases, it forms a very large propor- tion of all grains that are used for food. It exists in the soil, in combination with lime, magnesia, potash, soda, iron and alumina. With those substances, and others of this class, it form salts, which are called phosphates. Unless there be this sub:^tance pre- sent in a sod in sufficient abundance, and in proper for?}i for use, no matter how rank or strong (he crop of straw may be, there will be no corresponding yield of gi,?in. Hence, in soils famous for large crops of straw, with a small quantity of grain, the farmer may increase it by the apphcation of manures containing this sub- stance, wiiich are principally bone dust and guano. SULPHURIC ACID. Sulphuric, acid, (commonl}^ called oil of vitriol,) is also a ne- cessary constituent of fertile soils. It most generally exists in combination with lime, t'orming, with two equivalents of water, what is generally known as gypsum. Its elements exist in all plants, and in the blood of all animals. ' The quantity necessary to constitute a fertile soil, is very small. This has been shown by numerous practical experiments, as-well as by n)any analyses. Sulphates, as such, will not act on a soil which ci.mtains as little as (.005) the five one thousandth pait of' one per cent of sulphuric acid. Besides the soil, the air undoubtedly supplies the plants some portion of the two substances named above, or rather supplies the [GJ 14 elements by which they may be ronued. All animal and vegeta- bhi bodies, by their putrefiiciion, give rise to volaiiie compounds, containing sulphur and phosphorus, and under conditions wliich we know to exist, these comoounds are changed into pliosphoric and sulphurio acid, which, with bases, will form phosphates and sulphates. Although these two substances have not, as yet, been detected in atmospheric air, yet we know that they must exist there, and will be brought down by dew, rain, and snow, to the surface of the earth. CHLORINE. Chlorine is anoiher of (he necessary constituents of a fertile soil. In its pure state it ''is a yellowish green colored gas, which has an astringent taste, and a disagreeable odor." When breath- ed, it excites violent spasm of some of the upper parts of the wind- pipe, and has a very irritant effect on the organs of respiration, even when veiV much diluted with air. In the soil it is almost always united to'soda, and vcyy rarely to lime, magnesia, or potash. United to any of the bases, it loses its poisonous properties. With soda, it forms the different kinds of common table salt. It is be- lieved to add to the weight of the grain. Tjre quantity necessary to constitute a fertile soil, all other things being present, is very sniali. I have not been able to determine, with any degree of certainty, the sjiii.n^^t quantity necessary in a soil, as the atmos- phere from the contiguity of salt water in the localities which I have exau'iined, ahvays contained a varying proportion of this substance. ' Tl7e above compose all of the substances necessary to consti- tute a fertile soil. In some soils manganese is found, which is the oxide or rust of a metal called manganesium. This, (hough occasionally found in feitile soils, and in the ashes of plants grow- ing on them, yet is no: cssantial, since its presence does not in- crease, nor its absence decrease, the productiveness of a soil. The air, in common with the vegetable matter in a soil, fur- nishes to plants carbonic acid, out of which they form woody fibre, and all substances in them which contain charcoal. Besides this, it in common with many manures, affords ammo- nia, a substance which sui:)plies a great share of the nutritious ^rts of plants, and constitutes by its elements a large part of the mass of the bodies of the vegetable and animal creation. Water is supplied, in this country at least, wholly from the at- mosphere, in (he form of dew or rain. To recapitulate, then, we have as food for plants furnished by the soil alone : — ■ **» Silica or sand, ^ Alumina or clay, Iron, Lime, X Magnesia, Potash, 15 [GJ Soda, Chlorine, We have furnished in a great measure by the soil, but prllly also by (he air : — The elements of pliosphonc acid cont;uning pliospJioiiis : The elements of sulphuric acid containing sulphur. In localities adjacent to the ocean, bay, or indeed any salt wa- ter, there is always present in the air bolh soda and chlorine in the form of common salt. We iiave furnislied in a great measure by the air, but parti}- also by the soil : — Carbonic acid containing charcoal : Ammonia containing niirogen. We have furnished exclusively by the air : — Water. These contain all of the elemenls neces.-ary lo the perfection of vegetable and animal life. Those of them which are not present in the soil in sufficient qiianiilies, and which cannot be derived from the atmosphere, nnist be supplied anificially by what, are called MANURES. Manures may be defined to be whatever will contiibute to in- crease the productireness of the soil, either by furnishing dirdclly food to plants, which may be absent, or by causing thai food, which already may be present, to assume a form capable of be- ing used by them. However valuable any substance may be in itself, yet it is no manure to a soil that already contains it in sufficient abundance, or has not some oilier thing present in a form which plants cannot use, and which by the application of the substance used for ma- nure, may be so changed as to yield food for plants. Thus lime may act as a manure, when it is deficient in a soil, by being directly used for Uie structure of plants, or it xxv^y net as a manuie in a soil when it exists in sufficient abundance, but not in a condition to set free other things which may there exist, but' not in a form capable of being used. Vegetable matter may be a manure b}^ yielding its carbon and its salts to plants, or it may act by impregnating water with car- bonic acid, which thus acquires the property of dissolving the mineral constituents of a soil, and of placing them in a fit condi- tion for use. All manures should be in the finest possible stale of division, and mixed either directly, or indirectly most thoroughly with (he soil. Every parjicle of manure should be placed, if possible, ia immediate contact with a grain of saud. [GJ 16 STABLE AND BARN YARD MANURE. This being, to a great number of agriculluiists, the only form ia wliich manures aie applied lo lands, any suggestions to increase its value cannot be oveiiaied. Stable and barnyaid manure is composed of the excrements of cattle, mixed with that part of the produce of land which is un^ consumed by them. It is nothing more than the former produce of tlie land, modified by its passage through the bodies of animals, or modified by the presence of those things which have, at one time served the purposes of food. It, therefoie, contains all of the substances necessary to plants, as well those furnished by the air, as (hose which are obtaind from the soil. I shall not go into any elaborate description of its .several constituents, nor of their properties, but only give directions for preserving it in its greatest possible state of usefulness. In the decomposition or rottening of stable n)anin'e, a substance is formed, called ammonia, which is very volatile, thai is, it will readily escape into the air at all times, but more especially when the weather is waim. There would seem lo an uninstructed mind, no possible way of preventing the loss of this substance, but by making the receptacles of stable ma- nure air tight ; but chemistry shows, by teaching the nature and properties of bodies, that this substance, one of especial value ia stable manure, can be so changed by the addition of another sub- stance of little cost, and of easy application, as not to escape at any degree of heat lo which stable manure isever subject; this change does not in llie least affect the vaiueof the manure To effect this, nothing more is necessary than a sniall quantity of gypsum, (plaster of paris,) say from a half gallon lo a peck, scat- tered over the yards or stables twice a week. When manure is lo be applied to sandy soils, in which the sand is white, sulphate of iron (copperas,) should be prefeired. A few pounds beat very finely, are enough for each week. In this way the value of the manure will be increased one half, or at least one-third, and all disagreable stench removed from the yards or stables. This stench is produceo^ by innumerable fine particles of ammonia escaping into the air, and affects, some- times seriously the health of anii,nals subject to it. In the appli- cation thus recomiTiended above, not only is the health of a farmer's stock, but the value of his manure greatly increased, either con- sideration being sufficient to pay one hundred limes over, the cost of the application of gypsum or of copperas. Either of those substances when applied to privies or any place where animal and vegetable matter is undergoing decomposition, will at once arrest all offensive odors arising fiom them. So much for saving that part of the manure which escapes through the air. As commonly taken cnre of, this kind of manuie is subject to another great loss, which should likewise be zealously guarded against. When any body become? saturated with water, all of the soluble substances in it are at once dissolved, and if, when in this condi- ir [G] 5ion, any nJditional quantity of water be added, it fakes the place of that which previously existed, and forces out, ntjt only the water, hut likewise all of the substances which the water held in sohition. ThiU pait of stable manure which the water dissolves, is most valuable, and when exposed, as it usually is by farmers, nearly all of its valuable matter will be carried away, by water falling on the heaps and then running off". So eirectually does this deprive all substances of their soluble matter, that druggists use a process identical in principle with it, to obtain the active matter of many drugs and medicines. A quan!ity of rhubarb, ginger, &c., being first saturated with water is allowed to remain for a short time, an additional quantity of water then being added, the water first present, passes through, taking with it all the strength of the substances acted on, and leaves behind nothing but a worthless inert mass. A little reflection will show, thf^tthe same thing must constant- ly occur in stable and baru yard manure. The yards, then, for the accumulation of this kind of manure, should be so arranged as to permit no water to run off from them. If provender be scarce, then scrapings from the woods or ditches should be used to absorb all of the water which falls on them. Should the bottom of the yards be sandy, clay should be used on it to prevent the water filtering through the manure. To sum up all in a few words : — Soio gypsum^or copperas finely powdered, over the stable and barn yard manure, and let no water run of from it. Any farmer can easily, if he chooses, carry out all of these im- portant directions. Lime, neither quick, water slaked, nor air slaked, should ever be mixed with this kind of manure. The last can do no good, the other two will do very great ipjury to it. The above directions are short, but they have at least the merit of being easily understood and carried out. When this is done, they are perfectly efficient to preserve this valuable substance from the slightest loss. It is a much mooted question at present, as to whether this ma- nure should be ploughed in with the crop or applied to the sur- face. There is, and can be no general rule on this subject. To some crops it caunot be applied in the latter manner. The mode of application also depends on the degree of roUenness which the manure has uudeigone. When it is much decomposed and where its action is desired immediately, as on tobacco or corn, it is best to mix it thoroughly with the soil. Even when not thoroughly rotted, it is best to plough it under for tobacco. Tobacco land may be so manured, as always to retain its capacity for raising ^'bright tobacco:" such as is now produced on virgin soils or *'new ground" alone. One of the most respectable and intelligent planters in this State, by following out directions based on scientific principles. [G] IS has assured me of the decided advantage experienced j both in regard- to the quantity and quality of his crop. This advantage was proven by the growth of the article on land adjoining, and prepared with gre^t care, in conformily with long established usngje. When it is not well rotted, it is best to apply it to clover preceding the wheat crop which is to, be sown.. I shall be able to publish some very valuable comparative facts en this subject during the present year, which will give much valuable practical information. I can now state, however, with full confidence, that unless this manure he, very thoroughly decom- posed it should never be ploughed in for wheat, as it will alter Ihe texture of the soil and make it less productive for this crop, wheat delights in a close compact soil: — stable and barn yard manure not well rotted, will make the soil porous, and thus iu- jufe it. 'For indian corn this objection does not hold good, and where the land intended for corn is stiff, it will derive benefit from this manure being ploughed in with the soil. Besides alfording all of the necessary food for plants, the straw, litter, &c!, in this manure, during their decay, impregnate rain Wcl'ter with carbonic acid, which renders it a much more powerful solvent of all the minerals in a soil. |A great part of the good effects of green crops when used for manure, such us clover, peas, &c., is also due to this cause. E^My substance capable of being rotted, when covering land, not only' keeps the land moist by preventing the evaporation of water whicti falls, but it also furnishes to the water carbonic acid — and enables it ta disintegrate and dissolve the particles of soil. Besides this, clover, or anything else, when it rots, returns to the, soil all of the constituents necessary to its own growth, which it had extracted, Upon these three causes, and none other, de- penti tlie action of this class of manures, and the efficacy of top- dressing. To the barn yard, or compost Aeo/?, should be added sciap- ingS' 'from the woods, the contents of privies, (one of the most po)A^iful of all manures,) and whatever the experience of farmers may have shown them to be valuable. A small quantity added daiiyy will, in the course of a season, make a very large heap, and 'more than ten time? repay all the cost and labor of coliecling it. Dead animals should never be suffered to lie exposed in the air.- If a common sized horse or ox, when dead, be covered over wiih iearth made moist with oil of vitriol, diluted with ten or twdv^e times its bulk of water, it will make enough manure to produce at least thirty bushels of wheat. 7^he oil of vitriol will not only arrest the volatile compounds formed from the animal undergoing putrefaction, hut also cause them to he formed 'more quickly. When the decomposition of the flesh of, the animal is complete, the whole heap covering it should be dug down and applied lo the land. If the bones be not dissolved, or decomposed, they should be put in some convenient place, to be dealt with as is directed under the head of bone dust. 19 [G] • OJ eUo« MARSH MUD .... ., .r Is also a valuable manure. That at the heads of crefekf axid ravines has been used with a general benefit, second only to stable niaume, TlieJaige marshes on many ofthe rivers on llic Eastern Shore are invaluable, and at the same time exhaustless sources of fertility. I have examined (he "mud" from many of'lhem, and have always found it competent to furnish in large quantities, many of (he necessary constituents. Many specimens are easily burnt, which affords great facility and saving of labor in its appli- cation. . i; ;.. • . 1.: .■ This mud should be dug up and put in Heaps, and at any suit; able time should be burnt, and the ashes immediately applied tb the land. When it will not bum it should be made into a com- post with quick, or water slaked lime, and applied to the soil. :. This mud is very rich in all of tl,ie necessary constituents of soils, as may be seen from the following analysis: ■, y, ;,. ; Marsh mud from Chickamacomico rivef i^i Dorphester countyj .^Specimens being dried was composed of :•—» •■ Vegetable matter, jni.::ii> ei 90.80 ' io ;'^i; ,;, Sand, , ■ 7.40 d ..,: ,,.;;Clay and iron as per oxide, .60 Lime (ox. calc-,) .65 ' Phosphoric acid, '15 Magnesia, .13 Potash and soda, ,..■■•. ..12 ..■■a.l. . ; Sulphuric acid and Chlorine, (a tra«0.);'iM)v:;iu aiam r Jo« Specimens examined from the marshes of the Transqueken an^ D J2 >^ o .2 c "To Si. II 3 3 _o X "> s rrs S ,p o 'o "c:; fi h OT ci 3 !? 0 o _3 (D 3 '^ ^-^ 13 r^ , * jrr £ "Ch o O 3 OT ^ OT OJ O -3 O OT o rt "5 3 .fi *« to > "35 3 CO S ^ o '»0 s J3 00 oo OT c a ri ^ U-. >.-3 "^ r\ ^^ O ^ a-> r- bJD o OT .- X C -a GO ^5 o "s J "S 3 'T2 CO bJ3 OT OT ^ c: 6 5 o -3 O GO CO 00 3 3 i^ r- ^ O ei O 'S v2 he ^ J2 _3 ^ ^*-< «— <*- O o _w O "2 OT o o "^ OT s- OT OT ■1 CO 3 ^ -5 ^ g ^ ^"^ >> o ^ ■^ lO O -5 -^ I— 1 CO I— 1 CQ GO ,.^ •^ N» \« ^ \j ss r3 '-I (M CO 'g" O H-5 wi Value, after deducting cost of jManure. • ^ ^ 05 — 1 ^ OJ ^j CO t^ "^ o o T iO W5 to l^ O "rf P, H O sj 00 lo O „ __ ^ 00 t^ CO 00 00 Value of Barley. *= r- r-l r- l^ C5 10 CB Oi i-0 "^ '^ T »0 'Tf lO iO »0 Weight per Bushel. • 52 o lo ii^) o o ~ «5 «i ^ O XO Produce of Barley. ^fO r^ r-( CO 0} CO ^ —1 xn I- "^ 'X) OT ^'d* C^ CO CO CO Value of Tur- nips. ^. 5. d. 3 0 0 2 16 0 2 15 0 3 1 0 2 15 0 Weight of Turnips. Tons. Cwls. 12 0 11 4 11 0 12 4 ll 0 Cost of Manure. £. s. d. 3 0 . 0 1 17 4 1 16 0 0 11 6 1 5 0 OT o 1 .-H CM CO rj- to [G] 40 ^ s 9 '^•'=' o O A ^" o l>5 CO CO Co Co C- m O ri > '=^ -^ o o i. •>' i; ;j Q ^ -a ^ _i; Oj TO "^ >^ - il 'r. xn r^ TO en --*> r^ ^aa ' 1 c o ■} t- CI 1 (M F— 1 • c ea • . • CO (U "^ -3 :3 o o c . rt • • a . rt 2, • g ^ ^- » TO ^ rr TO " 5- 2d'Q,w ^ "E,- O o "5 -5 C3 02> 5 "= t^ ■ CQ '^ 1 00 F o 3 rt _ o J3 . Si TO ;z; (D TO ■ r- ^ bD O) ^ J^ o o ^-^ •^ gs ^ 03 o § (D "^^ -a 1—' i^"i>i Cl. i^ r« ■3 » W h O 0) — o -o iJ :^ w §3 = 0 3 J.^) »o -^ I- -— OJ -* w ci _r 1= O be . O CQ CO 00 fO ■"" r-. CO 00 c a c5 ■ ■•II -3 r- a n v 1 I • • 1 3 rs" rs" ' C C3 'o 'o S nes, - nes, - Ipliuric A nes, - Iphuric A O O 3 O 3 C2 03 {»£a 02 CO 00 * [CS] 42 ts s ?ii s o ^ O «9 1 s 1 g C^ g d t§ « f. ■^® o CO 0 ^ 0 0 ;-4 « &, OT O fli > W I- I- t- 0 u S: ■-^ 3 'J ^ . 1^ 2i-0 t- I- CO b- Ch S-^ " ''"^ r— ^^ ^ . 1 !» 1- -r; 1 1 . o) .3 >i S 5 •^ 'O ^ -p; 3 cT 0 d o 2 c -^ ~ OD > 0 c 73 0 cS 1 ^ '-> — i rt C3 -a" water eq of the a -ridge p rilled. '-3 _43 .2 "a. a, C3 ' ^ ^ w ^ -0 -c -^3 ■^ wit Bigl irrc eecl c c c3 -a -n ^^ : V O) .-"-' 03 ^ !III^ _- 0) 0 .A-o r:~^ — ^ , w ro TO TO TO »N ushel ound ushel ound M "3 ~ s. >. 3 JD C, -3 C- J^S " 1 '5 -a GO 03 ;:^ 00 CO 'i^ c (£> 5£) 0 CO 0 rt 1—1 ~ r-i %D -^QOxo a est § ' ' 11 , . . • ;|) ' = ' -o '— a 0 a CO . tT . 1 "O 1 V- -0 . 1 3 S 0 0 rt 0 3 -<1 1.2 ne Dust, Iphuric A ater, OT 0 0 3 C Q 3 " - 3 a cfl 0 3 C-ii B o D3 0 3 kT D3 5»;>^ ° 3 b- 0 3 J5^ 0 CO •uoi)ipuoo Ul ^ jood puB '8U0)S9uiri uiq} iCj8A 'l|0g 43 [G]. If no experiments had been ever made, 1 can readily conceive how, not only bones, but any oilier manure, applied in (his ijnan- ner, will pioducea much greater eflect then when applied ev6n in the linest powder. I will not recapitulate the reasons for this opinion heie. Under the general head of manures ihey njay be seen— common sense and experience confirm them. GUANO Is (he next sourse of supply of phosphates. This substance has been, for the last few years, extensively used as a manure. Besides the phosphates wliich it contains, a large quantity of ammonia is generated during the decomposition of its azotised matter. Guano, as is well known, is the dung or fecal, matter of various tribes of sea birds deposited on the coast of Africa, South Ameri- ca, and on tho Florida coast of the United States. The varieties most usually sold are the Chilian, Peruvian, Patigonian, and the African or Ichaboe Guano. Of these, (he first two command much the highest price in the market, the African or Ichaboe be- ing much less valued, and selling for a less price. The difference between the Chilian and Peruvian, and the two latter, depend oa the difFerence of the climate in which they are found. The at- mosphere in Peru and Chili is very dry, scarcely any rain falling, and hence the guano, after its deposition, suffers but little change, no water being present to aid the heat in its decomposition ; both heat and water being essential to that process in organic substances. On the coast of Africa and Patigonia, much rain 'falls, which not only dissolves some of the phosphates in guano, but readily washes out the ammonia as it is formed. These latter vareities, therefore, are never so rich in ammonia as the former, but they fequenily contain a larger quantity of phosphates, inasmuch as the ammonia being formed and driven off, the proporiion of phos- phates in any given quantity will be comparatively greater. The indications for the use of guano, are the absence or deficiency of phosphates in a soil, and the inability of soils to supply themselves with ammonia, for want of power of absorption. The constitu- ents for, and the conditions necessary to this, may be seen under the head of Alumina, Iron, and Sand, in the chapter on the con- stituents (if soils and their properties. I will, however, slate heie, that upon open, loose, light, porous soils, ihat species of guano, containing the largest quantity of ammonia, should be used; but on clayey land, or while oak soils, that kind containing the largest quantity of phosphates is prefer- able, because these soils can supply themselves with ammonia from (he atmosphere. It is a matter, then, of the first importance for the purchaser to be able to know the constituents of guano. At present he cannot know them, unless he employs some chemist, which he had much better do, than to buy and apply guano in the dark. The different specimens of guano differ very much, and the purchaser should know, before buying, the value of each lot that he purchases. {g] 44 There is much difference in opinion, as to the mode in which it should be applied; some ndvocaiing its apphcation to the surface as a lop dressing, others ploughing it under. Where the soil is porous, the former, I believe, is preferable; in stiflT soils the latter is the better mode. In either case gypsum shoukl be applied with it, in the proportion of about one-eighth by weight. The best quantity per acre, depends on the quantity of phosphates and ammonia in the speciinen to be apphed. A quantity of guano, capable of yielding phosphates, equal to about seventy-five pounds of bone dust, is the best, as far as my knowledge enables me to say ; the facts in my possession in relation to this are very few, though I beheve, more numerous than have been obtained by any one else. Indeed, though there has been so much written and published, as to tlie action of guano, no information has beea ehciied of general utility, because neither the composition of ihe guano, nor of the soil, has been given, and yetyet they are the two chief items which can afford us data, whereby to establish rules for the quantity to be used, or, indeed, for its use at all. I know of cases where it has acted well, that is, has more than paid for its cost, where, however, a much less sum expended in other manures, has paid more than twice as well. Phospliates exist in night soil, in poudtette, in ashes, in stable and in barn yard manure, in some maris in oyster shell lime, and also in stone lime, but in the last, not insnfiicient quantity to merit especial attention in reference to agriculture. The next substances claiming attention, are those which furnish SULPHUR OR SULPHURIC ACID to the soil. They are called sulphates, because formed of sul- phuiic acid, (oil of vitriol,) in combination with some base. The sulphate, almost universally used, is gypsum, or plaister of paris, this is a sulphate of lime with two equivalents of water. This substance has been most extravagantly lauded and condemn- ed by different persons, as it chanced to act well or badly, when used by them. The indication for its use, is its absence or deficiency in a soil. When all of the other necessary constituents of a soil are present, this being absent, its use in very small quantities, produces an al- most magical effect, making all the difference between a soil almost absolutely barren, and one very fertile. Even though it be absent <5r deficient, by itself it will not do any good, unless all of the other necessary constituents of a soil be also present, so that when gypsum does not act well on land, it may be for two reasons; the tirst, because of its presence already in the soil, — or secondly, because of the absence or deficiency of some other necessary con- stituent— the analysis of the soil, or a series of experiments, being alone capable of deciding, to which of these causes its non-actiou should be attributed. The very great difference in the gypsum which is sold in market, I shall advert to particularly when recommending some action in 45 [G] regard to its inspection. It, is best applied by beiiif^ sown broad- cast on the growing crop, on clover euily in ibe ISpring, and on Indian corn just before it begins to siioot. 'I'be proper cn^anliiy is from one-ball' to one busbei per acie. An advantage is also de- rived IVoin rolling llie corn in it before planting. 'I'o compost lieaps, to barn yard anil to stable niatune, it slionid be applied every few diiys in cpianiities depending on the number ol' stock, one gallon at a time, being enough (or the laigest yards or stables in the country. This should be done whether gypsum is applicable to the soil upon which the uiamire is to be used or not, as it preserves one of the valuable cousiituents of ihc manure which w(juld be other- wise lost. Sulphate of soda, which is but common ginuber salts, is anothei foim in which the ?ui])huric acid, or one of the sul- phates, can be applied. They are very cheap, being worth about three fourths of a cent per pound, and when the soil is deficient in soda, should be preferred to gypsum, as by it both sulphuric acid and soda wilt be supplied at the same time. Besides furnishing the elements tociops, which enter info its composiiion, gypsum is decon)posed by the ammonia always pre- sent in the atmosphere, which, by uniting itself to the sulphuric acid of the gyiisum, loses its volatility, that is, its tendency to escape into the air. '"I'he application of gypsum, then, beside furnishing its own elements to crops, retains for tiieni much valuable food from the air. This mode of the action of gypsum has been denied by some very distinguished writers who allege against this theory, that the increase of the substances in crops which it absorbs from the air, is far beyond what the quantity applied is capable of retaining. Those who take this ground forget, that when sulphate of lime is decomposed by caibonate of aunnonia, the growing crop takes up the ammonia without using the sujphuric acid, which is thus left to absorb and yield to the crop successive quantities of ammonia, as long as it remains \n the soil. All chemists are familiar with similar action in the manufactme of ceitain chemical conipcunds^ Sulpliate of magnesia, conunon Epsom sails, is another source from which tlie sulphuiic acid may be applied to soils deficient in iis two constituents, viz: sulphuric acid and magnesia. 'J'hough much dccti'er than the two above mentioned, it will be found supe- rior 10 them on ^oils deficient in both sulphuric acid and magnesia. I have now some experiments to be performed in relation to (he use of its substance, which, when complete, will be laid before the public. CA/ony/e, which, in c imbinalion with basts, forms what are called in the language of chemistry chlorides, is another of the necessary constitnenis of soils, and consequently a manme. Com- nion salts is the form in which it is most cheaply supplied. The indication for its use, is its presence or absence in the soil, or the [G] 46 posiiioa of the land in reference to salt water, as the vapor from it conlainsnn appreciable amount of chlorine, which, by winds and storms, nfe curried to the neighboring land. These comprise all of the necessary constituents of plants, all the necessarv constituents of soils. The particular combination of each which will give the greatest yield, has not yet been determined, "^rhis can only be done by many careful analyses of fertile soils, in order to see what quantities are present in them, and, by the analysis of soils, which are unpioduciive, and then to determine, by the apphcaiion of the necessary manure, the smallest quantity which will produce the greatest benefit. The experiments hitherto made determine nothing but the mere fact, that some particular manure has acted well on some particular soil. As long as we remain in ignorance of tlie compositiot) of the soil, so long we can learn almost nothing. I deeply regiei. too, that men, fiom whose repu- tation and knowledge better things might have have been expect- ed, have sanctioned the empirical course of endeavoring to obtain a knowledge of the best manure by its mere application to a soil, without any reference to the composition of the soil experimented upon. The experimenis made with so much care, and reported with such commendable exactness in the journal of the Royal Agricul- tural Society of l^ngland,are incomplete, and those recommend- ed^by l^rofessor Johnston, as well as those reported by him, are valueless, except to the particular individuals who made them. All others would have to go over the same or other experiments, before ihey could (ell whether the manures used successfully would be equally efficacious in theirhands, for if they failed, being igno- rant of the causes of failure, no plan would be suggested to ensure success on a second trial. Tiiere would be a constant groping in the dark, because (he liglit afforded by an analysis of the soil was neitherfurnished nor re( ommended. It rnay to some seem presumptuous, that I thus condemn the course followed by men of high reputation and acknowledged ability ; but neither of these is a safeguard from etror, and nei(her "the sliadow of a great name," nor any authority, however im- posing, should be blindly followed. The science of agriculture like all other sciences, has fixed laws; many of these laws are hidden at present from our view% and the veil which covers them will never be lified, unless they be studied in- a rational and phi- losophical manner. Kach known fact in agriculiure, to be useful, nuist have revealed with it all of the causes which led to its pro- duction. A successful or unsuccessftd application of manure is a fad of no value, unless the compasition of the soil upon which it was useil be determined. Then all of the causes influencing its action will be manifest, and each experiment made will lead us onward tna pel feet sysiem; every trial of a manure will teach us how it slio..ki be uslmI, and when rej-cled with profit. In obedience to the law, 1 commenced the discharge of my duties in the first gubernaloriai district, comprising eight counties, 47 [G] viz: Cecil, Kent, Queen Anne's, Caroline, Tniijot, Dorchester, Somerset ;ind Worcester, which constitule the EASTERN SHORE OF MARYLAND. It is bounded on (he nortli by the far famed Mason and Dixon'd line, (which separates ii fioni Pennsylvania as il does the slave from the non-siavcholding part of our Union ;) on the souiii hy the eastern shore of \'iiqinia; on the east by the Atlantic Ocean and jMason and Dixon's line, separating' it from the Slate of Delaware; and on the west by the Chesapeake Hay. The mild- ness and salubrity of its climate, the natural fertiliiy of its virgin soils, the numerous and various sources of improvement for those that have been worn out by improvident cultivation ; the unequal- Jed advantages of ils geographical position ; tlie high moral and social tone of its population ; — all teml to make it an object of in- terest, as well to those who wish to cultivate the earth for a sub- sistence, ns those who tiied of a city life, or the drudgery of pro- fessional labor, desire to enjoy dignity with leisuie in a retirement from noise and bustle, into the bosom of tlie 4;ountry, where the pleasures of sense may be combined with the higher and purer social enjoyments, which all sigh for, and few obtain. A plain description of this section of our Slate, derived from peisonal obser- vation during a residence t'lcre of nearl}' eighteen months, being the testimony of what 1 have seen, and of what I know, from careful observation, will full}'- confirm what J have said. ^ First, as to the advantages of its geographical position. Any one who will look at a large map of the United States, will not fail to perceive that in thisiespect it is imcqiialled by any wtb.er part of our Union. On one side resting on the ocean^ on the other reposinj^ on the Chesapeake Bay, — (he largest and most beautiful^ in the world, — intersected by rivers, or rather arms of the bay, every few miles, which afford at all seasons of the year a safe, cheap and speedy conveyance to market. Placed within a circle, as it were, sur- rounded by the great cities of New York, Philadelphia and Bal- timore, all ready and willing consumers of its varied agricultural productions: the ingenuity of man could not improve it's locality in this respect. All that railroads and canals, n>ade with enor- mous labor and expense, can, in the opinions of the most san- guine, effect for other portions of the Union, is here accomplished by the hand of nature, in a manner blending'ihe highest bsaijty ■with the greatest utility. Almost every man has fine bold water, either at his door or only a few miles distant from it, navigable for the largest schooners and steamboats, which, with but little time and expense, can convey his productions to market, and bring in leturn whatever may be required for convenience, for comfort, for luxury. These waters are, moreover, abundantly supplied with th-i finest fish, terrapins, [G] 48 crabs and 03'sters, and some of tliem with wild fowl of flavor and excellence, unequalled elsewhere. Tlic character of its soil, and (he means at hand for ilsiinprove- ment, aie no less worthy of adniiiation. The variety of iis soils affords an opportunity for the cuUivation of every kind of grain, fruit or grass, whiich the climate of this latitude will admit of. Many of its soils are ])eculiarly adapted to the growili of wheat; others raise the finest ciops of corn : its fruits, particularly peaches, are equal to the best in the counlr)', and nothing is wanting but careful cidtivation to make it the vineyard of the 'Union ; and its capacit}'" for growing grass will render it a fine grazing country. It has an abundance of the finest timber^ pa^■licuIarly while oak, pine and cypress. In many places there are extensive deposites of bog iron ore, easily obtained, and several of the largest of chrome ore in the world. One great and valuable feature of this country, is the abundance and variety of its resources for agricul- tural improvement. On many of the rivers there are large depo- sites of Indian sheli banks, capable of affording many millions of bushels of the purest lime. It has numerous deposites of very lich shell and green sand marl, Jn some of the counHes the green sand marl contains alarge per cenlage of gypsum. In many laige distiicts of country shell marls, containing from foity to seventy- six per cent of air slaked lime, can be obtained with the greatest facility, being sometimes within a few feet of the surface, some- tiiDes croj)ing out upon it. The shores of the bay, and its numeious creeks and rivers, af- ford laige quantities of sea-weed, a most excellent and valuable malnure. In other counties the marsh mud, easily obtained, is ex- ceedingly lich in those constituents most generally needed by worn out soils. To those of its soils which require magnesia, the Chesapeake and Delaware canal, and Susquehanna rivet, afford every facility for a cheap supply. The whole country is well wooded, timbered and watered. , I find it to be an opinion geneially held, that this is a verv un- healthy section of our State. My opportunity for observation has been better, perhaps, than that of any other individual," whilst my professional studies, as they enable me to observe accu- rately, should give my opinions some consideration. So far as my knowledge extends, no part of our covmtry is more healthy than this. There is no better mode of judging of the health of a country than by the physical appearance of its inhabitants. All writers on the science ofhealth (Hygeine,) agree on this general rule, that the physical development of the inhabitants of a country is the best criterion to judge of the health of that countiy. The reasons of the truthfulness of this index are perfectly in accordance with sovind physiology. Muscular development cannot take place, except when all the organs of nutrition are capable of performing their functions in a proper manner. This they cannot do, if ex- posed to the influences of causes which produce disease ; if they 4^. [G^ do it not, then the appetite will not take food, — or if the nppetite does, it will not be coiivciled into aliment. Hence, instead of the full development of the osseous system, ((he bones,) and muscular system, ihey will be s})aringly nourished, and attain but little size, 1'iavellers, and indeed all persons, speak invariably of the dimi- nutive size of the inhabitants of unhealthy districts, and of the puny statute of the denizens of closely-built nianufactoring towns, in comparison with the large size of the inhabitants of mountain- ous countries. Experience and the laws of physiology, then, alike decJare, that the best test of (he health of a country is, the physical developement of its inhabitants. I have visited many sections of our counlr}', and in no part of it have I seen the mass of population looking more healthy, or having more of all the signs of health manifested in their ap- peara'nce, than on the Eastern Shore of Maryland. I have seea some of (he largest gatherings of men that have ever taken place in our Union, and with any of them, the assemblages of farmeia that I have met in my professional tour will favorably compare. Going through every part of each of the counties during all seasons of the year, I have had an oppoit unity of knowing what- ever amount of sickness might exist, and 1 have in the same ex- tent of population, found as much in those sections of our Union accounted the most healthy, as I have found on the Eastern Shore. The only diseases at all prevalent are intermittent and re- miitant fevers. These only prevail during a portion of the year, and seem to be the best preventatives against the numerous and fatal class of diseases of the chest which are so fearfully present in other parts of the countr^^ Consumption so prevalent in many parts, is here almost unknown. My own observation, and the ex- perience of its resident physicians, fully sustam this assertion. The people^ then, of this part of our State suffe] for a brief period of the year undei a class of maladies, which, with proper treat- ment, are speedily and easily cured, and have almost a total ex- emption from a numerous class of always dangerous and frequently incurable diseases. It may be asked here, why then has this sec- lion of our Slate a reputation for unhealthiness, which it does not deserve ? The only reason which I can give is this : in all of the counties on the Shore, there is a custom of having what are called ^'public days," in the county town, and frequently in other parts of the county. These days are set apart by common consent for the transaction of public and private business, and where very many meet who have no particular business to transact. In this way, several persons from each neighborhood always meet, and what- ever case's of sickness occur in any particular section, are known and told with sympathy all over the county. So every case of sickness or death is known, and from the particular acquaintance and friendship engendered by frequent meetings of the people, is felt as a calamity to the whole comnnmity, although the number of cases do not exceed those in the healthiest parts of the Union T [Gl 60 More is known of the cases which do occur, but no more ac- iually take place here, than in the most healthy parts of the country. As this country progresses in its rapid march of agiicultural improvement, the better and more perfect cultivation of its soils will remove many of the causes of sickness which now exist. This should and will be additional reason for inducing, by all means, the most thorough cultivation and improvement of its soils. I have dwelt somewhat at length on this subject, to correct the erroneous impressions which exist, and to show to those in want 'of certain profitable employment, and of cheap and easily im- ^oved lands, that they need not feel any apprehensions on the score of health. Emigrants will find here land cheaper, taking '6very thing into consideration, thaa they can find in the West, and equally healthy ; and if they are taken sick, or meet with misfortunes of any kind, instead of being subject to the privcilions of a newly settled country, they will experience every aid and as- sistance from a kind, generous and hospitable people. '■ The son of Erin will be received in a manner that will remind "h'im of the warmth of his native land ; the patient industry of the 'German will here meet with a speedy reward; and the Magyar will liere find a home amidst a people capable of appreciating his noble patiotism and chivalric love of liberty. ■ ' '"The, surface of the country is generally level. The upper part, ih Cecil county, is very hilly ; thence the face of the country gradually changes into a gently rolling surface in Kent and Qiiicen Anne's, until it becomes very level and flat in the other dounties. ' Its scenery, though deprived of the grandeur of mountains, is iiiore than compensated in beauty by its unrivalled water pros- pects, The rivers penetrate far up the country, winding graceful- ly from farm to farm, which seem to seek the embrace of the clear blue waters, in whose bosoms they lie. The fresh streams which are bordered by large marshes, in some seasons of the year, present scenes of the most ravishing beauty. The waters of these streams are of a dark amber color, from the organic matter of the marshes which border on them, and are covered with the water-lily, a very large and most beautiful while flower ; and the marshes on the sides next the river are filled with Wild roses, whilst that part next to the highlands, are one unbroken forest of magnolia. As far as the eye can reach, it rests on one il'hbioken series of beautiful flowers, more beautiful from the dark slbggish waters which are in contrast with them. At night, the lilies on the water are covered with fire-flies, givrng the scene an appearance of unequalled beauty and brilliancy. The whole forms a scene which art, with all its ability, can but faintly imitate, and which is without a parallel, even in the climates of the '''gorgeous East." Its population has long been distinguished for the exercise of the highest degree of polished hospitality. Re- 61 [G] silling in the central part of the Union, immediately on Mason and Dixon's line, dicy have all of the virlues, with none of the vices, which bcloiitj io ihe two gieaL sections yC our Union. I'hey possess ihii ihiift, iiichisiiy and economy of the North, without its parsimony, — the generosity and chivalry of the South, with none of its extravagance and recklessness. Living where the land and the waters meet, their minds have all the firmness of the former, their hearts all the freedom of the latter. Though to some, the above short description may seem highly colored, ail who have had the same opportunities for knowledge as I have had, will bear testimony to its correctness. I do not conceive it necessary to go into a minute description of the topography of the several counties. The lesidents know it already, and to others it would possess no interest, and be of no benefit. I shall only speak of the particular deficiencies of each soil, show from what source these deficiencies are to be supplied, and give the compositions of some of the different marls. I shall only publish a few of the many analyses of soils made, as they would possess no particular interest beyond their immediate locahty, and there I have already given all the requisite informa- tion. All of the analyses made by me would occupy a large space, and the great raajoriiy of farmers would derive but little benefit from reading them. I conceive my duty rather to lie in the appli- cation of the aids of science to agriculture, than in teaching that science ; and to do the latter in a report of this kind, would be foreign to its object As the sick man needs not to know the exact mode in which the medicines administered for his relief aot, but is satisfied with his recovery, so for those seeking to improve their lands, it, is only necessary to know what will most certainly and cheaply accomplish their objects. Tiiis I shall show, without going into elaborate reasoning as to the theory of the action of their inanures. The law seemed to indicate, that instruction on this point was to be given during my sojourn in the different coun- ties, by means of lectures, by conversations, and, when required, by means of written communications. This is deemed, (and as far as my experience goes,) with great wisdom, the means best adapted to diffuse scientific agricultural information in the commu- nity. Notice was given in all the public papers of my presence in the respective counties, and of the time and place of delivering public lectures. Free opportunity was thus offered to all, of reap- ing whatever benefits could be derived from this office. Having spoken of the components of soils in general, and of manures, I come now to describe several general varieties which exist in ihe.section of the State where my duties have been per- formed. Although different paifs of the same field present differ- ences, yet on another and adjacent field, the same kind of soils will be found. The varieties of soil, which J shall particularly describe, are those which are met with in gteateror less abundance, in all the counties on the Eastern Shore. [G] 52 WHITE OAK OR PIPE CLAY SOIL, Forming a large proportion of the soil of ihe Eastern Sliore^ must be of great interest, whether viewed as to its barrenness, when unimproved, or its fertility, when correctly manured. I have examined its properties, determined its constituents, and studied the best means of remedying the defects of each, with the most careful attention. To the knowledge of the iirst two, obtained by my own investigations, I am able to add, for the correction of the last, a knowledge derived from the accumulated experience of many of the best farmers on the Shore. This variety of soil is readily distinguished from all others by its white color, FIRM COMPACT TEXTURE, ITS LEVEL SURFACE, ITS GREAT RE- TEXTivENESS OF MOISTURE, by iis softuess and plasticity when wet, and by its firm and unyielding nature when dry. It is al- most always in ils original state, covered with white oak titnber, from which it derives its name. Sometimes, however, pine grows abundantly on it, mixed with the white oak. The water which luns off from its surface is of a dirty white color, and even when it collects in pools, takes a long time to become clear ; in other words, a long time must elapse before all the earthy matter, from its extreme fineness, subsides to the bottom. The sub-soil is most usually a true white clay, (silicate of alumina and protoxide of iron,) unless on the points of land running into the rivers and ocean where red clay predominates. Occasionally, we find the sub-soil of a '^mottled, marbled" character, being a mixture of the red and white clay in various proportions. Its chemical constitu- ents are no less constant and marked than its physical appearance. T It is distinguished by the large proportion of sand, by the small 3 proportion of iron and clay, by the presence of magnesia in 1 Bufiicient quantities, by a great deficiencv of lime, which is con- i.stant, and hy a tolerable supply of the alkalies, phosphates and • sulphates. The sand in these soils is always in a finely commi- nuted state, feeling but slightly giitty under the fingers, and re- ceiving minute impressions when placed in contact with any un- j^ even surface. It is from the extreme firmness of the sand, that -this soil derives its compact texture and its power of retaining t moisture. It is this which makes up for what would otherwise ^'.be a deficiency in the clay andiron. These two latter substances -t are particularly important in soils from their power of absorbing and retaining moisture. From the atmosphei'e they also absorb 1.. ammonia, a powerful fertilizing agent, rnd retain it with gi-eat ji force, for-ming combinations, "true salts," with it until the plant - requires it for support. In a soil deficient in clay and iron, then, -•! and whose sand is course, you will have to supply artificially, some t! manure containing this latter indispensable substance, or a good y crop can never be obtained. There are examples of this kind in \he loose, light, sandy soils in some parts of all of the counties. These soils owe their barrenness alike to their texture, and to their composition. 53 [GJ In ihe while oak soils, the fine sand is a suijstilute for iron and clay, ahsoibinq, with great, power, moisture, and whiitever other ferlilizinj]c ni:uter may be in ilie iilnios[)!icie, and relaininy^ it until the want?; oC the plant ie(|uire its use. Thesand thus performs a vicarious action to iron and clay ; ills a snhsiiluie for them in giving compactness to the soil ; it is a substitute for them in ab- soibing moisture, and the food which plants obtain fiom the at- mosphere. IMie power ofchaicoal to absorb various gasses, is well known, a power derived exclusively from its mechanical texture, as shown by its great number of fine pores ; and when we consider the fine state of divisir)n in which thesand exists in these soils, we readily see how a mass of it must present a very large surface for absorp- tion, and how an almost infinite number of small spaces must exist between the grains of sand, giving it in a great degree the same properties as charcoal. For although this soil appears to form a solid mass, yet no grain of it is in perfect contact with anv oilier grain. This is niost saiisfaciorily demonstrated by placing a snrall lump of it under the field of a microscope, when the inleisiices, the spaces between each grain, are distinctly visible. Another advantage which this land possesses, is, that it more readily yields the mineral agents which it contains, to growing plants, all bodies (other things being equal,) being sohible in proporiion to the fine- ness of their division. This is always acted on by those who wisii to dissolve any substance of difiicult solubilit}-, by pulverizing it in a morter. Now, in a soil, every grain of sand contains some- thing of use to the plant, which can be more readily dissolved from fine, than from coarse pai tides. These soils are uniformly deficient in lime, but have enough of magnesia: they have potash and soda, as well as sulphates and phosphates, in fair proporiion. How does an acquaintance with their lexture and^'composition teach us to improve ihem ? What are the indications, and how are they to be fulfilled ? First, — "^rhese soils are level and retentive of moisture. They should then be drained thoroughly U'ith surface drains. No water should ever be allowed to rest on them. The fields should be ditched at least on two sides', with a wide deep ditch, into •which a number of small surface drains should run, and one or two laige drains through a field are no substimie for a large num- ber of smaller drains. These latter are more effectual and more easily made. A plough run once or twice in the same furrow, aided by ihe hoe, will in most cases, make a very effectual drain. The manure fiom the bottom of ihese ditches will, in a few years, pay for them, even if they had no other use. These soils are compact, and, therefore, do not lequire a great depth of soil in order to give firmness and stability to the roots of plants growing on them. They, also, very eirectiveiy retain mois- ture, thus afibrding it to crop? in a dry season; when overlaying a white sub-soil, they can gain nothing of use from it, for these sub soils contain almost nothing that is useful to vegetation, and [G] 54 some things in a condition that are injurious. How, then, should ilicy be cultivated? Notwithstanding, it is so fashionable to ad- vocate deep ploii.ifhing ; noiwidisianding, it i.-s always insisted on by agriculiural wi iters, speakers, and essayists, yet I must advise ail to beware of it, on these lands, unless (hey have a red clay sub soil. The only rational rules for ploughing, are short and plain. They are, to turn up a sufficient depth of soil to give a firm support to the plant, enough to retain moisture for its use, and never to go deeper, when (hose ends are obtained, unless (lie sub-soil be better tlian the sinface soil. If it be v/orse, you injure, and cannot improve by deep ploughing. If (he sub-soil be belter, tlien, and then only can you gain by deep ploughing. Reason and common sense alike tell us, that if you join a woise with a belter soil, the compound v/ill be infeiior 10 that better soil. If, on (he other hand, (he sub-soil is better than that which overlays it, then should it be turned up with the plough, because the sum of the two will be belter than (he surface soil. Such being the case, you siiould plough shallow in these white oak soils, and never turn up the ickite. clay upon which they rest. The paiticular depth of ploughing, will vary slightly in different soils of this class, and I have never seen any that requited more than five inches ; most frequefilly tluee or four inches are sufficient. This depth is sufficient to support the roots of the plants, sufficient, to retain enough of moisture, and liiere is inferior soil underneath, wliich would deteriorate tlie quality of the surface soils. Where there exists a sub-soil of mottled or marble clay, the same rules are to be observed a,s regards the depth of tillage. Upon the red or yellow clay sub-soils the practice should be dif- ferent, as these may with advantage be turned up, never more, however, than one inch for each rotation, which may be rejieated until the depth of tillage reaches to six or eight inches. These rules are founded on the nature of the sub-soil, and its influence on vegetation. The iron in (he red and yellow clays, is in the state of per oxide, that is, it is in its highest degiee of rust, and can receive no more oxygen. Iron, in this condition, absorbs ammonia, (a very fertilizing constituent of the atmosphere,) and retains it until required by (he growing plar.t. But the advantage does not s(op here. The color of soils has an important influence on (heir pro- ductiveness. Those Vv'hich are dark colored, absorb, and retain heat be(ter than those of a lighter hue. Seed, in the former, sprout quicker, and grow more rapidly than in (he latter. So by mixing a red o.r yellow clay with these white soils, you will cause the crop to take an earlier start, to grow more rapidly, and arrrive at matu- rity sooner, than if a contrary practice was adopted. These clays, too uniformly contain some lime, in which the surface soils are deficient. We cume now to speak of the best means of improving the soils under consideration, by manures, that is by the addition of those 65 ^ [G] substances in which they arc deficient : deficiency or absence be- ing aUiways (he test of a iiKiiuiie. However vnhuihle anylliiiii^ may be in itself, it is no nianiire when applied where it already exists in proper form, and in suflicient quantities. From what has been said of the composition of these soils, the rationale of their ini provement is plain, cheap and certain. They are only deficient in lime: Then it should be applied to them in the purest form, — oyster shell lime is iheliine for tln;se soils, because, in reference to them, it contains less impurities than any other kind of lime. If Wrightsville, JNew York, or Schuylkill lime, be a|)plietl, much less of manure, for the same amount of money and h^bor, is g-iveii to the soil, than if oyster shell lime be used. Each of these limes contain a large pei cenlage of magnesia, and more sand, clay, and iron, than that from oyster shells. As these soils contain enough of magnesia, all the magnesia applied to ihem is so much lost in money and labor, to say nothing of the loss of the crop which a pure lime would have produced. It matters not in what form the lime be applied, as it is a mere question of cost, whether pure oyster shell lime, shell marl, or the mould from Indian shell banks be used : al^ these act by supply- ing lime, the prime deficiency of the soil ; they willact and bring it to a high degree of fertility, pioducing Jtbundant crops of every •kind, and the finest, heaviest crops of wheat ; for these soils, from their texture, is peculiarly adapted to this grain. The manner of applying lime to these lands now icquires some notice. It it be applied to the surface a long time before the crop is to be planted, the rain, instead of carrying the particles of lime down into the soil, will carry them of fiom it, and in this way a large part will be lost. In loose, porous soils, (his surface application will answer very, well, but hard compact soils sliould be first ploughed up, and then have the lime scattered immediately on the surface. In this way none will be lost. The quaniUi/ of lime to be applied, is the next subject of con- \ sideration. Here again we have to consult fertile soils of this class. Science has given them a language, every sound of which is truth. The most productive have not shown over two hundred bushels of air slaked lime (o the acie, to the depth of twelve inches. There is no need then, of evergiving them more than this quanti- ty. Six or seven-tenths of one per cent is always enough. Up to this point, the larger the quantity the bciler will be the crops. All who have this variety of soil should apply lime to them. If it be impossible to apply an hundred bushels, apjily fifty ; if not fifiy, then twenty-five; if not twenty-five, then ten bushels; apply some, and do it at once, make a beginning, however small, and its good results will soon persuade all who make tiie efibrt, to surmount whatever trifling diificulties may intervene, and lead them to apply the necessary quantlt3^ Besides lime, a slight dressing of compost manure, made from the scrapings of the woods, will greatly aid in the improvenierH oi these lands. It will materially quicken the action of the lime. [G] 56 I need noL give the reasons, the fact is certain and quite sufficient for our present purpose. Tliere are millions of acres of this land, now not worth in the iTaiket niore thaa fioiii five to eight dollars, which by tlie appli- cation ofas much money in the [roper manure, will pay for tlieinr selves and for the manure, by the very fir^, or, at most, the second crop. -Lands, precisely similar to them, have produced from fifteen to tweniy bushels of wheat to the acre, afier proper draining and liming, which before would not produce more than fourorfive, frequently no more than two or three. , 1 know some exam- ples of this kind, upon which all may depend, which prove these two prime facts : — 1st. That those lands, when improved, are the most productive and valuable in our State, taking every ihing into consideration ; — 2nd. That lime is the cheapest agency to effect this improvement. I need not say, that in their unimproved con- dition they are the least profitable of all of our varieties of soil. If there be any one kind of manure which I can recommend for any particular soil with more confidence than any other, it is OYSTER SHELL LLME TO WHITE OAK SOILS If that cannot be obtained, then the Baltimoie limes should be used. I have never known one single instance of failure from the use of pyster shell lime on these soils, where proper cultivation was also followed. The most productive lands in Talbot are o^ this kind, and made so by the use of this substance, and manure from the common resources of the farm. Land there, which twenty years ago was considered dear at ten, will now readily bring fifty and sixty dollars. The same degree of improvement has occurred in many other of the counties of this shore, but not so generally as in Talbot, I have now given the nature of the composition, and best means of improving, this variety of soil ; shown what indications Analytical Chemislry declares were to be fulfiilled to render them fertile; and I have shovv^n that where these indications had been carried out, they have never failed to produce the desired lesult; that art and science, theory and practice, all pointed to the same system of cultivation, and the same kind of manures. It remains then for the owners of this land to act their part, and their labor shiuld be the less irksome from the cer(ainty of Its success. The following are a few of the many analyses made of these soils : — Specimen from Farley creek, Kent county. Vegetable matter, 5.60 Silica, (sand,) 89.S0 Iron and pure clay, 3.40 Iron and alumina, as phosphates, .14 Lime, as air slaked lime, .41 Magnesia, -35 Potash and soda, .12 Sulphuric acid, .001 Chlorine, .001 57 [G] This soil produces from twenty lo thirty bushels of wheat unci from six lo ten barrels of corn lo the acre, at present. It has been manured with two hundred bushels of Schuylkill lime lo the acre. This sod in its original condition, contained an abundance of Magnesia. This was not the best lime for it. A specimen taken from an adjoining fiekl gave iwo-tcntbs of one per cent, of ma''"- ne:>ia. Hefore the application of the lime, (he owner of this land informed me, that it would not have produced thiee bushels of wheat to the acre. No. 2. Specimen from the upper district of Queen Anne's county taken to the depth of five inches, was composed as follows of ' Vegetable matter, 3.50 Silica, 91.10 Ahmiina, (clay,) 2.50 Iron as per oxide, 2.00 Iron and alumina as phosphates, 05 Lime as carbonate, (j4 Magnesia as carbonate, jq Potash and soda, 03 Sulf)huric acid, .001 Chlorine, 001 This soil had never been limed, it originally contained only twelve bushels of linie to the depth of 12 inches. It has a laiffe abundance of magnesia, and is very poor. The manure is of couise li7ne, and the common resources of the farm No. 3. Specimen of unimproved while oak land from Kent Island in Queen Anne's county. Specimen taken to the depth of iive'in- ches, and thoroughly dried gave as follows, of — Vegetable matter, 3.73 Silica and sand, 92.30 Alumina, 2.00 Iron as per oxide, 2.25 Iron and alumina, or phosphates, .08 Lime as carbonate, .08 Magnesia, 29 Potash and soda, ^15 Sulphuric acid and . Chlorine, not estimated quantitively, but evidently enough. This land does not produce five buhsels of wheat to the acre" though it has all of the constituents of a fertile soil, except lime' in as good proportions as the other soils which pioduce Iwenty-five bushels of wheat. No. 4. Specimen from near I\liles' River, Talbot county, was composed as follows, of — Organic matter, 5 00 Silica, (sand,) 9U0 8 [G] 58 Alumina and iron as per oxide, 2.90 Iron and alumina as phosphates^ .11 Manganese, (a trace,) Lune as carbonate, .32 Magnesia, • .18 Potash and soda, .07 Sulphuric acid and chlorine in sufficient quantities. This is a very productive soil, made so by the application of mail. No. 5. Specimen from TuckalioeNeck, CaroHne county, was composed Organic matter, 4.60 Silica or sand, 92.10 Alumina and iron as peroxide, 2.80 Iron and alumina as phospl)aies, .03 Lime as carbonate, .17 Magnesia, .10 -^ Potash and soda, .04 Sulphuric acid, a trace, Chlorine, not deficient. This is rather more productive than most of the unimproved "while oak soils," the quantity of hme in it being above, and the quantity of phosphoric acid, under, the aveiage. Besides oyster sU^ll lime, bone dust or guano, particularly the Patagonian or African, should be used on these soils. Several examinations of soil.'=' in this Neck, show very nearly the same composition as the above. No. 6. Soil from near Cambridge, Dot cheslercount}'^, Md. Specimen taken to the depth of six inches. This soil had never been im- proved ; it was composed as follows, of — Organic, i. e., vegetable matter, 7.20 Silica, i. e., sand, 90.50 Alumina, (clay,) and Iron as per oxide, 1.70 Alumina, and iron as phosphates, .09 Lime as carbonate, .10 Magnesia, .21 Potash and soda, .111 Sulphuric and acid, .008 ■ Chlorine, .006 This soil was experimented on by J. Wallace, Esq., with the following result, which I cannot do better than give in his owi\ words: — "I accordingly purchased five hiindred bushels of ashes in Bal- timore, and had them landed at the cost of 12^ cents per bushel, and applied them upon lot No. 1, of field No. 1, at the rate of one hundred bushels per acre ; immediately alongside, I applied one hundred bushels of shell lime, at a cost of 3 cents per bushel. The whole was sown in Vvheat in the fall of 1847, upon an oat 59 [ G ] stubble. At harvest I measured off and reaped separately, one acre of (lie aslied land, and one acre ot lUe unimpi'oved Idnd. Upon ihe ashed land, I have raised seventeen bushels of grain, upon tlic unimproved only scvoi and one-half, an acre of nine and one half bushels. The product of the limed acre was not measured, but as the eye could observe, there was a slight differ- ence in favor of the aslies, but very little. The difference in the cost of improvement, however, was material ; the a^hed land cost $12.50 per acre, and the limed only $3.00. On the young wheat, in the spring, clover seed was sown upon the whole field, but the plants all died in the summer, except where the lime and ashes had been applied. And I may here add, that in every instance I had failed to raise clover where either lime or ashes had not beea applied." For more particular details, the reader is referred to a letter from Mr. Wallace, in the January number of the American Farmer. It is by far the most valuable practical paper yet published on this subject. 'These analyses and experiments place the matter beyond cavil, as to the successful manuring of poor lands of this description. I have examined numerous specimens of this variety of soil in other parts of Dorchester.jin Somerset, and Worcester, in Queen Anne's, Kent, and Cecil, and they all have the same general composiiion, and would be benefitted by th.e same cultivation, the same kind and quantity of manures. ri::d and yellow clay soils. By this term I include all of those soils, having for their bases, red or yellow clay. The surface soil depends very much for ha color, on the quantity of vegetable matter in it. Sometimes it is filled with course gravel, sometimes it is a fine dark grey sand, frequently of a light reddish color, owing to the presence of per oxide of iron, and very often the surface soil has nothing by which • it can be so described as to be recognized. The sub-soil is, how- ever, always characteristic, being a red or yellow clay, similar to that from which bricks are made. The clay differs in color from a bright brick red, m Cecil, to a pale fawn color, in Worcester county. The transition in color is gradual, from Cecil to the southern parts of the shore, becoming less red by almost insensible . - degrees, a fact due to the dimunition in quantity of the iron. These clays, also, are less strong as we proceed downwards; that is t, hey contain a less quantity of pure clay The surface soils over diese clays are deficient in alumina and per oxide of iron, in lime, inagnesia, and the phosphates. The fii'st two can be supplied by deep plowing. The red and yellow clay sub-soils contain fi'om eight and a half, to as much as twenty bushels of lime per acre, for every inch in depth. Hence, on those soils, with every inch of clay which is'/ turned up, from eight and a half to twenty-five bushels of lirnei,, is brought into action. Besides thi:j; they also contain magnesia, and sometimes potash. If there was no other reason but this [G] 60 ii should be sufficient to induce deep culiivation on the red and clay lands, which will also, paitially supply (.he latter deficien- cies. The composition of these soils points out the nianuiTs besi adapted for them. These are the Schuylkill, Wrighisville, or New York lime and bone dust, or guano. Lime devoid of magnesia, will increase the growth of crops on these soils, yei it will never act as well as those which contain it, because, by the latter, both lime and magnesia, two deficiencies instead of one^ are supplied. They should be ploughed deep, but not more than two inches of the clay should be turned up in one rotation. This should be done in the fall, that it may be subject fo the action of the winter's frost, and to the influence of the weather for a. long time For the reason that these soils differ very niuch as to the quan- tity of their necessary constituents, and of course in the quantity of manures which should be applied, I have not given any of their analyses in this report. Those which I made have been given to (he owners of tlie soil, and the necessary manures, both as to kuid and quality, indicated at the same time. I have, moreover, given all the information which I possess in reo"ard to them, to their owners, through conversations and lectures. At present, gypsum would act well on these soils — when, how- ever, thej iiave a large admixtlire of the per oxide of iron and alumina, by means of deep ploughing, the benefits of this will be questionable. The rules whicli I have laid down, aiding by observations of the effects of the specified manure, will aid greatly in their successful cultivation. These lands, from the faciliiy with which they are improved, are very valuable. Though at present they may be cheaply purchased, yet, in a few years, when their worih become better known, they will command a very high price. Indeed, at present, they are rapidly increasing in value. BLACK GUM SWAMP SOILS. These are characterised by their black color, light porous tex- ture, and the large quantity of vegetable mattet which they con- tain. They are very productive in corn, but wheat does not flour- ish on them, owing to their porous texture 'This class of soils is most generally found in bottom lands, and, when at all moist, should be drained. The best application for them, is unslacked magnesian lime, for even when a fair proportion of lime is found on analj^sis, yet lime will act on them, as the substances necessary for plants are held by the vegetable matter, wiiicn cannot be yielded until it is decom- posed : quick lime affects this very* readily, and should be ap- plied for every rotation as long as a large quantity of vegetable matter can be recognized. From twenty to foiiy bushels applied every year, will insure, for a number years, very large crops of corn, and, when the texture of the soil will allow, large crops of wheat will be produced. These soils are generally quite fertile. 01 [G] lieaiins^ from four to eight baiiels of corn every year for a gieaf. number of years. AVIioii quick limccaiuior he procured, water-shikcd liuie sliould be useil. Air-shikcd hiiie u ill benelit. them but very slighily, and coniuion eaiih of any kind, by rendering iheni more compact, will also act beneficially on these soils. Specimen fiom Fourlh Election Disliict, Worcester county, Md., thoroughly dried, was composed as follows, of — Vegetable matter, 41.70 Silica, (sand,) 5.3.80 Iron, as per oxide, .40 Alumina, (pure clay,) . 3. .50 Irop. and alumina, as phosphates) .(>S I.ime, .20 Magnesia, .21 Potash and soda, , .10 Sulphuric ccid and chlorine, (a (race.) This soil produces from thirty to forty bushels of corn every year. Specimens from the long maish in Caroline, and the Beaver Dam in Queen Ann's county, showed a composition nearly simi- lar to the above, except in having a larger quantity of iron and alumina as phosphates, from .2 (two-tenths) to .45 (four and a half temhs of one per cent.) Specimen from near Newtown, Worcester county, Md. Vegetable matter, 44.00 Silica, (sand,) . 53.00 Iron, .SI Alumina, (pure clay,) 1.00 Iron and alumina, as phosphates, .15 Lime, .30 Magnesia, ,25 Potash and soda, .04 Sulphuric acid, , .002 Chlorme, .006 This soil produces from thirty to forty bushels of corn every year — no wheat. Specimen from Worcester county, Md., from near Derickson Cross Roads, being fully dried, was cou)posed as follows, of — Vege'.able matter, 35.00 Silica, (sand,) 60.00 Iron as per oxide, 1.00 Alumina, (pure clay,) ' ^ 2 60 Iron and alumina, as phosphates, .16 Lime, .35 Magnesia, .24 Potash and soda, .15 Sulphuric acid, ,009 Chlorine not estimated, but sufficient. [G] 62- This soil produces fromfiftyvto sixty bushels of Indian com every year — wheat does not thrive on it. Specimen from Somerset county — Vpgeiable maiter, ^ 42.60 SiUca, (sand,) 53.20 Iron, as per oxide, .61 Alumina, (^pure clay,) . 2.70 Lon and ahuTiinaj as phosphates, .13 Lime, ,21 Magnesia, .20 Potash and soda, .15 Sulphuric acid and o^iloiine not estimated quantitatively, but sufficient. This soil produces from thirty to forty bushels of corn every year — no wheat. / LIGHT SANDY SOILS. These soils are chnracterized by their coarse, gritty texture^ their porosity, their white color and their barrenness. Sometimes the sand- in them is brownish from the presence of iron. Their greatest defect is mechanical. They are deficient in clay and iron, and liieir sand is too coaise to absorb much, if anything, from the atmosphere. , Their chemical defects are lime, magnesia, the phosphates; these substances, tiiough present, are not in a condition to be used by plants. They should be treated with, compost, Tiiade of vegetable mat- ter of any kind ^ such as scrapings from the woods, the clearings out of ditches, &c., with any of varieties of lime containing magnesia. Gypsum should always be sown on tiiese lands when not in cultivalion, and as large a crop of grass as possible suf- fered to grow on them, unmolested by catile. When this deca3^s,' it will dissolve much of the mineral matter in the soil, that other- wise would not be taken up by plants. The compost manure^ recommended above, supplying lime and magnesia, would act in the same manner. If the raagnesian lime be applied by itself, not more than twenty bushels per acre should be applied at one time. This ahould be done in the fidl or winter preceding the crop ta be tilled. It should bespread on the surface, for in these porous soils the rain will cairy down the lime into the soil, distributing it very equally through it. As th.ose soils cannot absorb ammonia well, that form of guano coniaining the largest amount of it should be preferred for them. When bone dust is applied, it should be done imn^ediaiely before the crop is planted. Gypsum should always be used on these lands. One of the best means for the improvement of (his class of soils is by crops of peas, and the comr.-ion lady pea is belter for this purpose than all odiers. The ground inienJed for their use, should be ploufjhed up in April or May, and the peas harrowed in about the middle of the latter month, or first of June, by means of a light 63 [G] spike toothed haHow. In the full the peas slioukl be galliored fioin the vines, wliicli will pay as well us any other crop on these lands. Tiie succeeding year they will bring at leasi tiiirly per cent more ol' corn, than if they had not been cultivated in this way. There are soils of this kind near Worion I'oini, in Kent county, and also on the Chester river. 'J'liey are found in the neigiiiibrhood of Sntlleisville, in Queen Anne's, extendini!; on the Chester river, for sonic distance below the Chesteriown bridge, and reaching out into the coiniiry, until they become gradually blended with the red and yellow vlay lands; ihey are found in Talbot, bordering on the Choptank, and Ihey prevail veiy much in Caroline county ; in the upper and middle districts in IJorchester county, on the Choptank, alwve Cambridge, lo the Delawaie line J and in the upper part of Somerset, and that p{>it of Worcester called the Forrest. They also are found east of the Pocomoke, below Snow Hill, extending a few miles above it, until they meet with the yellow and red clay lands of Quepongo and Berlin. The above compose the most marked varieties of soil found in the first gubernatorial district. To describeall which occur, would swell this report to an unieasouable length. The sub-varieties are very numerous, and as far as opportunity permitted, their charac- teristics were examined, their deJiciencies determined, and the ma- nures and cultivation best adapted to them, were made known by the means pointed out by the law. . The analyses of all kinds made of soil, exceed one hundred and fifty in number, but as their publication, would subserve no prac- tical benefit, I have not included themm this report. The owners of the soils will give me, in the course of a few years, the result of their experiments, which will form a coUeciion of the most valuable facts yet given to the art or science of Agri- culture. I have adverted to the variety and richness of the niarls of some parts of the Eastern Shore. These are comprised under two general classes, viz : the green sand marl and shell marl. These are the terms applied to the two vaiieties on the Shore, by which «ll there -.vill readily undeisland my meaning. THE GREEN SAND, OR JERSEY MARL, Is found in large deposites on the head of Sassafras, in Kent county ; on the Sassafias river, in Cecil ; on the branches of the Gieat and Little Bohemia river; and in many other localities in the lower part of Cepil. A bed of it is found also below Chester- town, near the Chester liver, but evidently not in its original posi'ion. Another bed, to the thtcknes of about eighteen inches, is found overlaying shell marl of the very latest deposit e in Talbot, at the head of Wye, on the land of Mr. Tliomas Hopkins. This is also out of place, having been transported hereby a current of water at some distant peiiod. The green sand to which I refer, owes its value to the presence of potash. , Soiuetimes, however, it contains carbonate of lime, and occasionally some sulphate of [ G ] G4 lime, (gypsum,) formed by the decomposition of the sulplniret of iron, and of carbonate of lime furnished by shells. It is, by no means, to be taken as granted, that all sands which are colored green, possess fertilizing properties. Their color is due to (he presence of iron, and not of potash or liiiie. They may, and sometimes do, Lave a bright green color, and yet have not enough of either of these substances to be of the smal'csl value as fertilizing agents. The test of value recommended by Profes- sor Rogers, in his geological survey of New Jersey, that of a green slain being made by the sand on White paper, is not correct ; though it was also mentioned in a report on the geology of Vir- ginia as an unerring mark, and adopted by (he lamented Professor Ducatel of this State. '\h& gi'een color of this marl is caused by the iron and not by potash. It is true, that when potash is pre- sent in the sand, the gieen stain will be made, but it is equally true, that it will be made if no potash is present ; hence it is, by no means, an ''unerring test" of the value of this kind of sand, and, indeed no test at all. The only means to determine the qirantity of potash in green sand, is a chemical analysis made by an expe- rienced, practical chemist. Its analysis is complicated and difficult, and liable to many sources of eri'or. No confidence should be placed in any estiiTiate of its worlh, that is not based on a chemi- cal analysis made by an experienced hand. This marl is some- times found in large grains, sometimes the grains.are very small, and the mass of it is very close and compact, the color is some- times a bright green, which, on exposure to the air, becomes a dusky red, from the per oxidatioir of the iron. Frequently it is of a dull green, approaching to black. No indication of its value, however, is alibrded by its exteriral appearance. The benefits of its action are due principally to the potash which it contains; besides this, its iron, when peroxodised, absorbs am- monia from the air, and improves, very materially, the texture of the soil, especially when the soil is light, loose, porous, sandy, or of a white color-. The following are analyses of some of the dif- ferent specimens examined by me. MARLS OF KENT COUNTY. Green sand from Ebenezer Welch, head of Sassafras, in Kent county, 100 parts, thoroughly dried, gave of — Silica, 58.00 Iron as protoxide, 22.00 Alumina, 5.00 Lime, • 6.00 Magnesia, 1 .50 Potash, ^ 0.50 A stratum in this bed, about four feet in thickness, intermixed with sliell, gave as follows, of— Silica, 3K00 Lime as carbonate, 57.00 Alumina and iron as phosphates, LOO •5 [GJ Iron as protoxide, 4.50 Magnesia, 1.60 Poiasli, 2.60 Secimens from Mr. Briscoe, head of Sassafras river, ihe same locality as i\bove, were composed of — Silica, (sand,) 68.50 Iron as protoxide, 21.50 .Alumina, G-60 Lime, 6.00 Magnesia. 1.50 Potash, 6.70 The bed of green sand, on llie head of Sassafras, is about twenty feel in depth to ihe level of the tide-water, and extends more than (hree-loinihs of a mile down llie river. This sand iff found more or less intermixed witli the sand on the streams, and with the under strata of some of the soils in diffeient parts of the county. Analyses were made fiom many localities, but there was none of any practical value, except that below Chestertown, and a specimen furnished by Mr. George Spencer. I'he foimer contained of potash, 4 per cent, the latter of potash) 3 per cent. A specimen intermixed with many green particles of sand from near St. Paul's church yard, in the Lower District, gave of — Silica, 90.00 lion as protoxide, with per oxide, 4.25 Alumina, 2.00 Lime, 1.60 Potash, 1.25 Specimen of shell marl from Mrs. Julia Merritt, lower district of Kent. Physical characters, hard compact texture, dusky red color, ana intermixed with many small quartz pebbles. Specimens thorough- ly dried, gave of — Sand, 45.00 Iron as per oxide, 5.55 Lime ae caibonate, 49.22 Magnesia, (a trace,) Phosphates, (a trace,) Shell marls from the banks of Chester river, on the farm of Mr. Wm. Decourse, v;as composed as follows: — Sand, • 45.00 Iron as per o:tide, 10.74 Alumina, 1.12 Lime as carbonate, 43.00 This marl was of very easy access, hut had never been used, though the land on the farm, and all thiough the neighborhood, very much needed it. Dark black marl, with small fragments of shells in it, from Mr. Malsberg, near Georse^o^^r. GroE-s Roads, contain of**- 9 [G] 66 Silicn, 13.75 Iron as per oxide, 12.00 Alumina, 1.00 Iron and alumina as phosphates, * .50 Lime as carbonate, , 17.00 Lime as sulphate, (gypsum,) 4.00 Potash, 1 .25 This is a very valuable marl, containing, as it does, almost all of the necessary constituents of soils in fair proportions. Very many different specimens of the matl, and what was sup- posed to be fertilizing matter, were examined in all the counties duiing my stay in them, the analyses in every instance were fur- nished to the different individuals when the specimens were of any value, but when worthless, the result only was announced. It is unnecessary to give them in detail here. Many marls whose efficacy had been determined by long use, were not submitted for examination. Many rich deposites of green sand marl occur in Cecil countyj but as most of the specimens were brought to me only a few days before my duties there closed, I have not had an opportunity of thoroughly analyzing them. This shall be done in the course of a few months, and the results given to the owners in a proper manner. ANALYSES OF SHELL MARLS FROM QUEEN ANNE'S COUNTY. Specimens from W. A. Spencer. The bed situated atthe edge of a running stream, and Of very large size, covering an area of more than 50 acres, to the depth of 6 to 8 feet. Specimen No. 1, was composed as follows, of — Sand, 66.00 Iron as per oxide, 1.00 Alumina, .25 Lime, as carbonate, 32.75 The above are the proportions in 100 parts, after being thorough- ly dried. Specimen No. 2, was composed as follows :^- Sand, 85.00 Iron, 1.50 Alumnia, 1.10 Lime as carbonate, 12.40 Specimen No. 3, was composed as follows: — Sand, 90.00 Iron, 1.70 Alumina, .50 Lime as carbonate, 7.80 This specimen was from a distinct stratii'm, hnmediately abuve the last. 67 [GJ Another specimen from the same bank, also, from a distinct stratum, was composed as follows, of — Sand, 90.50 Iron, 1.50 Alumina, .50 Lime, as carbonate, 7.50 The following shows the composition of two specimens of marl from Mr. Davidson, Wye Neck. No. I, Contains of — Sand, 68.20 Iron, as per oxide, 1.40 Alumina, 1.00 Lime as carbonate, 29.40 A stratum immediately overlaying the above, to all appearance equally good, was composed as follows, of — Sand, 90.00 Iron, 2.50 Alumina, 1.00 Lime, as caAonate, 6.50 This is not worth hauling. Specimen from Dr. Newman's, near Church Hill. This bed is of very large extent; covering about 150 acres, and being about twelve feet in thickness. No. L Contained of — Silica, 57.00 Alumina and Iron, 2.00 Lime as carbonate, 41.00 No. 2. Blue stratum from same beds, the shells being much more thoroughly decomposed was composed as follows, of — Sand, 62.00 Iron, 1.40 ^ Alumina, 2.00 Lime as carbonate, 24.50 Analyses of two specimens from Mr. William Carmichael, Wye river. No. 1. Was composed as follows, of — Sand, 79.00 Iron, as per oxide and alumina, 3.50 Lime as carbonate, 17.50 No. 2. Contained of — Sand, 57.15 Alumina and iron, 5.05 Lime as carbonale, ^ 37.80 [ G ] 68 Specimen from Mr. Walter D. Haidcastle's farm, near Reid*s creek, was composed of — Sand, 49.00 Iron, as per oxide, 3,00 Alumina, 2 25 Lime as carbonate, 45.75 A specimen from Mr. Greenberry Knott's farm, was composed as follows, of — Sand, 71.85 Iron and altmiina, 8.50 Lime as carbonate, 19.65 A specimen from Mr. Madison Brown, Centrevillc District, was composed as follows, of — Sand, 55.00 Iron and alumina, ' 5.92 Lin)e as carbonate, 39.00 A specimerj from Mr. R. E. Clayton, was composed as follows^ of— Sand, 60.80 Iron and alumina, 3.00 Lime as caibonate, 36,50 Specimen from Mr. William Herasley, head of Wye was com- posed as follows, of — Sand, ' 65.00 Alumina and iron, 8.00 Lime as carbonate, 26.50 Besides the above, many other valuable beds of marl are found jn this county. ANALYSES OF SHELL MARLS IN TALBOT COUNTY. Specimen from Cbas. Robinson, near Easton, was composed as follows, of — Sand, 70.00 Iron and alumina, .07 Lime as carbonate, 28.00 Lime as phosphate, 1.15 /. H. McNeill— Marl, No. 1. Hard, compact, while shells, finely comminuted. Specimen fjaving the appearance of mortar. Sand, 17.00 Iron and alumina, 6.50 Lime as carbonate, 76.30 /. U. McNeiU~Red, No. 2, Sand, 19.00 Iron and alumina, 10.50 Lime as carbonate, 70.00 Loss and other components not maleiial, .50 69 [G] iNo. I. Mr. Stiandberg, Sand, 56.60 Iron and alumioa, 3.50 Lime, ns carbonate, 39.60 Mr. Strandberg, No. 2, contained of — Sand, ^ 68.25 Iron and alunaina, 4.00 Lime as carbonate, 37.00 Specimen from Mr. Barlly Haskins, white color, showing but very lidle apperance of shells. It contained of — Sand, 26.00 Clay and iron, 2.20 Lime as carbonate, 70.00 Lime as phosphate, L60 Specimen from Mr. William N. Mulliken, contained of — Sand, 65.00 Iron and alunoina, 4.60 Lime as carbonate, 30.00 Specimen from Mr. Sol. Merrick, contained of — Sand, 56.25 Iron and clay, 5.15 Lime as carbonate, 38.60 The average of four specimens from Baker^s Landing, the pro- perty of Thomas Hughlett, gave ofj»- Sand, 60 00 Iron and clay, 6 00 Lime as carbonate, 33.50 Specimen from T. R. Plater, near Tred Haven, compact, hard, and filled with finely comminuted shells, was composed of — Sand, 21.00 Iron and alumina, 3.76 Lime as carbonate, 74.00 Lime as phosphate, L25 Specimens from Edmundson's Neck, v?a8 composed of — Sand, 36.60 Iron and clay, 3.5d Lime as phosphate, 1.70 Lime as carbonate, 57.70 Ditch Bank Specimen, From Rev. E. J. Way, was composed of — Sand, 6S.50 Iron and clay, .90 Lime as caibonate, 30.60 Specimen from the Upper Pit, (E. J. Way,) was composed of — Sand, 76 50 Iron and clay, 2.30 Lime as carbonate, 21.20 Specimen from Major John Dawson, Miles' river. One speci- men contained of — [G] 70 Lime as carbonate, 41.00 Specimen of blue marl from same, contained of — Lime as carbonate, 2L00 Specimen from Mr. Edward Hambleton. The sliell marl spe- cimen was composed as follows, of — Sand, 47.00 Iron and clay, 4.50 Lime as phosphate, (bone dust,) L75 Lime as carbonate, 46.60 The specimen of ''greenish colored sand," overlaying the above, contained only a trace of sulphate of lime, (gypsum,) and is not worth the labor of its application. Many other analyses of marls were made and given to their owners. These are but a part of the numerous and valuable marl beds in this county. At least one-third of it is underlayed by marl, whose average composition will give fifty per cent of air-slacked lime. These marls are very easily obtained, and produce, un- aided, very great renovation in the adjoining land, frequently increasinor the crop from three to twenty bushels of wheat in a single year, and giving a corresponding increase also of the corn crop. Notwithstanding the great and now universally admitted benefits of shell marl to the land of this county, it is only within the last few years that it has been generally used. Mr. Singleton applied it with great benefit near forty years ago. The only specimens of marl brought to me for analyses in Caro» line county, were two specimens from near Greensboro'. Specimen No. 1. Contained 28.50 per cent of air-slaked lime. Specimen No. 2. Contained 34.36 per cent of air-slaked lime. There is a very valuable deposit also on the farm of Mr. T. H. Slaughter, near Denton, which as yet has never been used to any extent. Its valuable matter is 6S.60 of air-slaked lime, and 1.75 of phosphate of lime, (bone dust.) But very few marls on the shore are better than this. I shall now call the attention of your honorable body to the inspection laws of the Sta'e, so far as they immediately affect the Agricultural interest. They are exceedingly defective, and need prompt and radical amendment. To protect the weak against the oppression of the strong, and to secure to all safety in their persons and property, are duties which the State owes to all of its citizens. In some instances these principles are fully carried out, they should be in all, but this is not the case. If one, by reason of a superior physical ability, wrests from ano- ther his property, the State very wisely and justly interposes its power, causes restitution of the goods forcibly taken away, and punishes the offender, to prevent the commission of similar crimes. Equally binding is its obligation to protect all who may suffer in 71 [GJ ilieii property, from the superior knowledge of oUiers, since^ leased as great may ensue from deficiency of knowledge, as from deficien- cy of strength, to resist imposition. Eveiy care is taken by the Stale to protect our citizens from injury of any kind from the latter cause, but whilst the duty to guard them against injury from the former is acknowledged, ihe means used are, in many instances, inadequate to the attainment of (he end. The State, to protect its citizens from loss, by the superior knowledge of others, has provided inspectors of various things in common use — men especially chosen, fiom their superior fitness, to discharge the duties assigned them; these duties being to de- termine the quality of different things inspected, and to affix to them some maik or brand, by which their value may be known by all. In this way it interposes its superior knowledge, with the same justice that it interposes its superior force, merely to save its citizens from imposition and loss. The duty is as strong in the one case as in the other, and equal necessity exists for its perform- ance. An inspection that does not show the true value of the article inspected, is worse for obvious reasons, than no inspection at all, and in inspections of things made up of different substances, the quantity of those which give the article its value, s\ioi\\d be shown. I wish the above plain truths to be applied to the inspection of two articles of great cost to the Agricultural interest, which it is my duty to benefit by all the means in my power. These two substances are guano and gypsum, (plaister of paris,) the cost of which, to the farmers of this Stale, is but little short of eight hundred thousand dollars. Too much care cannot be taken to determine their value, and 1 cannot urge upon your honorable body, too strongly, the necessity of having ihem subject to a form of inspection, which shall make known for, show to, the buyer the true value of the article which he purchases, and indicate to him the per centageof its valuable constituents. I shall first speak of guano : Notwithstanding the many vari- ous compounds which enter its composition, yet its value almost entirely depends on two of them. On the ammonia already present in it as a salt, with that which is capable of being formed by the decomposition of its azotised matter, and on its phosphoric acid or phosphates, which are combinations of this acid with some base. The small quantity of the other substances in it possess no particu- lar value, as they can, if needed, be supplied much cheaper from other sources. Does the vf»lue of guano depend on its ammonia which it already may have, or which may be formed in it, and its phosphoric acid or phosphates? We have in support of this, a unity of senti- ment among the ablest chemists. Liebig, Ure, Johnston, and indeed nearly all who have written on the subject, agree in the opinion, that guano owes its value to its ammonia and phosphates. Tlipsp two substances mvst g\\p. guano its value, ornothing else [G] 72 does, for, take away these two, and only a moiety of other matters remain, which can be cheaply obtained from many sources. Not only are these substances the cause of the value of guano, but as either may exist in greater or less propoition, in any particu- lar specimen, it makes that specimen better or worse for particular soils. Ammonia is supplied to plants in large quantities from the atmosphere, being absorbed by soils, and, with iron and clay, form "tiue salts." But if any particular soil has not this ab- sorbent capacity, and has a deticieticy of iron and clay, it cannot obtain amnionia from the usual source of suppl}'^, and will be un- productive, unless it be supplied from some other souice. If guano is used, then, the purchaser should know which of the different lots contains the most ammonia. But many soils have the capa- city to supply themselves with ammonia, but are deficient in phos- pliales, andj therefore, barren, and if the owners of soils find it more convenient to buy guano, than any other manure, they should know what specimen contained the largest quantity of phosphates, what samples contained the most of what they want. If the pur- chaser does not know, would he not be constantly liable to loss, in buying the wrong specimen? If it even acts well, he is not as- sured that another specimen would not have acted better. If, on his land, in one year, be makes a luxuriant crop, by the use of guano, !he next year, by the use of a different specimen, even at the same price, he may make a very inferior crop. Guano, therefore, has a relative value in relation to particular soils, as it can supply them with a greater or less proportion of their deficiencies; it has an absolute value depending on the quan- tity of aiTimonia which is already or can be formed in it, and oa its phosphates. Most clearly and unquestionably, then, its inspec- tion should show the proportion of each of these constituents, so as to show its absolute worth, and its relative value to diffeient soils. When a farmer is buying guano, let him know how much of each valuable substance he may be purchasing, then he will not be spending his money without knowing what he is getting for it, and can better suit his guano to his particular soil. The proportion of the two valuable substances is very variable, and yet the guano, at present, has but two, or, at most, three grades of value. Some specimens of No. 1, or No. 2, or No. 3, must be much more valuable than others, and yet each lot of the same number sells at the same price. The purchaser should not be obliged, in buying guano, to pay twice as much for some specimens as he does for others, of only equal, it may be of less value. I have made many analyses of guano, and submit the following to prove what I have above stated. Analyses of different specimens of guano, to determine its agri« cultural value: Specimen A, contained of — Ammonia, 4.00 per cent. Phosphates, 36.00 " 73 [GJ Sand, 7.00 per cent. \\ iiier and organic matter, 50.00 " Specimen N, wliich sold for, I believe, twenty dollars per ton, contained of — Ammonia, .3 tenths of one per cent. Phosphates, 40.0 per cent. Water and organic matter, 33.0 '' Silica, (sand,) 26.0 Specimen G contained of — Ammonia, 7.00 per cent. Phosphates and other constituents, not estimated, Specimen O, contained of— Ammonia, 15.25. per cent. Phosphates, 46.12 '^ Silica, (sand,) .50 '' Organic matter, water, and other constituents, 3S.13 '^ Specimen J, sold in Kent county for twenty-nine dollars pet ton, contained of — Ammonia, 4.00 Phosphates, 40.00 I have not the nofea of this analysis, but am quite certain that' the above vejy nearly represents its value. I have made many other analyses, but the above are sufficient to maintain the correctness of the position which I have assumed. Specimen "O," and specimen "A," were No. 3, and sold at the same price. A glance at the dilTerence in the quantity of their constituents, will show that their value nmst have been verv different. V Specimen A sold for forty dollars per ton. Specimen J sold for twenty-nine. Yet sperimen J is the better of the two. More numerous proofs can be adduced, but the above are sufficient to' show the great difference in this article, and to prove also that the only safety which the buyer has^ is in such an inspection as will show him the proportion of phosphates and ammonia in tlie article. The ammonia in the above, not only shows the quantity already present, but also all that which can be formed during the decom- position of the oiganic matter in the specimen. The mode of in- spection which I have recommended above, is easily practicable, and any one who buys guano lo even a small amount, would be a gainer by paying for its analysis before purchasing it. I do not pretend to give here the details of a proper law, but am ready when called on, to appear before the committee on. Inspections, 'or that on Agriculture, and give them the benefit of all the knowledge which I may have on this subject. I have had numerous con- versations with men of great ability, in relation to this mattery antf am happy to have them all coinciding in opinion with me. ' The form of inspection which I recommend, would save to (he farmers of the State, every year, more than one hundred limes the 10 [G] 74 cost of what would be a fair remuneration for making it. There 7Jiust be a chemical analysis of guano made, before we can ascer- tain its value, and its result should be shown. The merchant who sells, knows no more about its worth than the fanner who buys, and both may be deceived in regard to it. The smell gives no indication of its value, and we can no more judge from its appearance, what (he quantity of its valuable constituents may be, than we can of the quality of the contents by looking at the out- side of a barrel. Since, then, neither the buyer nor seller can know, the State should ascertain and show the quantity of its valuable con- stituents. In reference to the inspection of gypsum, the same argumAit holdsgood. This is a sulphate of lime, with two equivalents of Avater. The rock from which it is obtained, owes its value to the quantity of sulphate of lime in it, and in buying what is sold for gypsum, we wish the barrel as free from any other less valuable substance as it possibly can be, we should only pay for the barrel in proportion to the quantity of gypsum which it contains. Is that which is sold as gypsum, pure gypsum? or does the quantity of it vary very greatly in diffeient barrels? Let the following analyses answer : Report of the analysis of ten different specimens of gypsura, to show its agricultural value. No. 1, Contained of — Sand, ^ 5.77 prct. Lime, as carbonate, 16.41 Alumina, with a trace of iron, 3.66 Lime, as sulphate, i. e., gypsum, 74.10 No. 2, Contained of — Sand, 10.60 Lime, as carbonate, » 17.25 Clay and iron, 1.36 Gypsum, 70.79 No. 3, Contained of — Sand, 4.50 Clay andiron, 2.2S Lime, as corbonate, 4.00 Gypsum, 89.20 Specimen E, contained of — Sand, 13.68 Iron and clay, 5.29 Lime as corbonate, 21.59 Gypsum, 59.40 Specimen R, contained of— Sand, 4.65 75 [Oi] liiine, as caibonafe, 12.20 Clay and iron, . 1.12 Gypsum, S2.0U !i .Specimen T, contained of — Sand, 10.00 Lime, as carbonate, 28.00 Iron and clay, 1.30 Gyp.9um, 60.70 No. 7, C!ontained of — Sand, 2.20 lion and clay, 1.25 Lime, as carbonate, 10.00 Gypsum, 86.40 No. 8, Contained of — Sand, 2.04 Iron and clay, 2.10 Lime, as carbonate, 5.40 Gypsum, ' > 89.90 No. 9, Contained of — Gypsum, 85,04 i. Other constituents not estimated. No. 10, Contained of — Sand, 6.20 Iron and clay, 1.15 Iiime, as carbonate, 7.35 Gypsum, 85.30 It is shown from the above analyses, that some specimens con- tain thirty percent less of gypsum than others, yet he who buys, pays the same price for it, as if it contained the full amount of gypsum. The inspection shoidd show in this, also, not only the loeight of the bairel, but what is in it. When one gives $L37 for a barrel of gypsum containing three bushels, about forty-six cents per bushel, he should know how much of gypsum he is buying, — not to be forced to pay $1.37 for a barrel of something, one third of which is only wortli, at the highest rate, six cents per bushel ; — nor made to pay for common air slaked hme and sand, atlhe same rale as he pays for gypsum. I must not be understood as charging the traders in this article with adulterating it. No such thing is necessary to iTiy pur- pose. A great diflerence exists in the rock from which the gypsum is ground ; and if there was none, still it is possible for it to be adulterated, and the Slate should take the sanre precaution to guard its citizens from loss from this source, as it does in other articles of which the people at lar-ge are good judges, frequently as good as the inspector hit^rself. As the gypsum, (sulphate of [G] ' 7C lime ) is that which every one seeks Lo buy when purchasing a ihino" under (hat name, the State should so order its inspection, that each barrel should show how much of this substance was in it so that its price thereby mi^ht be regulated. No reasonable sel- ler should object to such regulations; and every buyer ought to insist upon them. By ihem, the owner of a good article would ffet the value of his good commodity, and he wiio wished to buy, would not be deceiveil in the purchase of tliat which might be of litde worth. While it would deprive the sellei of no right, it would give great benefits to the buyer, "^rhe seller would get the value of his article, — the buyer tlie worth of his money. The fact is familiar lo all who use plaisler, that it acts much more favorably in some years than others. This has been attributed ex- .clusively to the seasons, but very often the difference is owing'' to a dilTerence in the article used. The smallest per cent of gypsum in the specimens which I have examined, was 59.40; the highest was 89.60 per cent, a difference of more than thirty per cent. If only one half of that sold was of an average quality, a fair way of judging, then fifteea per cent of the money spent for gypsum is thrown away. The cost to the farmers of Maryland of this article, (freight and labor included,) as near as I can judge, is $7t)0,()00, so that con- siderably more than $100,000 is lost to the citizens of the Slate annually, in the attempt to buy what they do not get. They buy gypsum, and only obtain sand and common air-slaked lime. I have thus called the attention of those interested to a sub- ject to them of the deepest interest. I have shown the defects pf the present laws. It remains for them to have those defects remedied. lean assure all interested, that these differences do exist in the manures spoken of above, which are not shown by the present form of inspection, Iti making your lionorable body acquainted with this fact, 1 am only performing a part of my duty to the farmers of the Slate. Let them provide a I51W which, while it will do wrong to none, will do justice to ihe'iQselves. I do not know how the inspection of lime js performed, but its constituents should also be determined in the same manner. This, however, is not practicable in every instance, as a large quantity of that useil in the State comes fr-om beyorid its jurisdic- tion. I have obviated this difficulty as far as I could, by publish- ing analyses of the various limes used by the farmers of Maryland. It is, therefore, a useless office, ser'ves no good purpose, and should be abolished. It is nriy further intention, during the pre- sent year, to procur-e a number of specimens from each of the quarries, both within and without the Stale, which supply lime to our farmers, and subject them to a more minute, rigid, and elabo- rate analysis than has been yet made of them. I have not done so during the present season, because of the impossibilii}'^ of pro- .euringthe specimens. 77 [GJ There is another ihing, perhaps, inchided under tlie broad term of "such oilier matters touching (lie Aoricultural interest of the State, as may be considered necessary," which is the dilliculty that sometimes luippens, between the i)urchaser mid the seller of wheat and other i^iain, as lo its merchantable condition. A loud of grain is frequently contracted for by the merchant, and afterwards thrown upon the hands of the producer, or hia agent, from the alledged diflerence in the condition of the sample and the load. When a merchant, ihus refuses to take the grain, there is no remedy left, but to sue for breach of contract, a course for obvious reasons, not always practicable. In the present state of things, wheat brought in the evening, is frequently retirrned in the morning, csjoecially xulien the market declines. It thus hap- pens that the producer sometimes looses by a decline in the price of grain between the contract for sale and delivery and never gains by any rise, for when any rise takes place, the grain is never returned. That the load of grain sometimes' does not correspond to the sample, I have no doubt ; when it does, and a decline in price takes place, between the bargain for sale and its delivery, that it is sometimes throv/n back upon the producer, is well known. There should be some fixed law, with a competent officer, to de- termine the merchantable quality of all grain offered for sale, and thus give fair play ahke to the purchaser and grower. This officer, moreover, could keep a strict account of all wheat, corn, dec, biought to the market, and give statistical information in legard to the amount of these crops, which would be of great value in an agiitultuial, as well as a commercial point of view. I do not mean to accuse all of the dealers in grain of dishonesty, but to trust to the universal existence of its opposite virtue, is to have a greater amount of confidence than the experience of any would wariant. There is an obvious necessity for some legisla- tion on this subject. The office which the undersigned has the honor to fill, being a new one in this )Stale, the bill creating it was, of course, liable to imperfections, which experience only could correct, and I would fail in my duty, were I not to make such lecorainendations to the Legislature, and people of this State, as would lead to the con- struction of a law better calculated to carry out their liberal views. 1st. I shall call your honorable body's attention to the purposes of the present law creating the office of State Agricultural Chemist. 2nd. Show in what particirlais its errors consist, and recommend such changes as my experience convinces me are necessary. 3rd. Show the utilit]) of the office to the agricultural interest of our State. The intent of the law of 1S47, ch. 249, is best shown by its4lh section, which declares: "That it shall be the duty of said Agriculturm Chemist to ana- lyze specimens of each variety of soil of the county in which he shall be, that may be brought to him, or that he may find to exist, [G] 78 and also to examine and, if necessary, analyze specimens of each kind of mail, or other vegalabie or mineral deposit, that mav come to his knowledge, in order that his instructions may be of more practical utility." The law in this section was not sufficiently explicit. Its letter could have been carried out, and not one single fact of practical value elicited. The farmer would have been as ignorant of the composiiion of his soil, of its defects, and of the manure necessary to supply these defects, as if it never had existed. The mere per- formance of an analysis would have been of no use, unless it could have shown the quantity^ as well as the mere presents of the se- v-eral constituents of a soil. A qualitative analysis could have shown the latter, and done no o-ood. A quantitative analysis was wanting, to show, not only the presence of the different substances necessary to a fertile soil, but at the same time to determine their quantity, to define their pro- portion, to see whether they existed in sufficient quantilies to pro- duce a crop, and to enable the farmer to supply any deficiency which niio'ht exist by the application of the particular substance or substances wanting. The quantity of (he substance to be applied, depends, of course, upon the quantity of that already present, which can be shown only by a quantitative analysis. A qualita- tive analysis would have conformed to the letter of the law. This would have been of no use. A quantitative analysis only could carry out its spirit, which I have done in all of my operations, though It takes ten times the trouble, care, and labor, of a quali- tative analysis. Another great defect of the law is, that sufficient time is not given to carry out its provisions. The quantitative analysis of a soil is said by Parneill, an analytical chemist of the highest authority, to be "the most difficidt and tedious of all analytical operations." All who are at all familiar w^th chemical research, know the great care, labor, and time required to perform it. The utmost attention must be given to each step in the pro- cess. The most exact and cautious manipulation is necessary to avoid all sources of error, and its termination cannot be hastened, except at the expense of its correctness. Many difl^'erent varieties of soil and mail had to be examined iri some of the counties, which would take more time, of themselves, than that allowed by the law to remain in them; but, besides this, the different parts of each county had to be visited in person, a suitable place to be ob- tained for the erection of the apparatus to perform the analyses; lectures to be delivered in the diflferent districts, and a report to be written ; and, in addition, numerous enquiries by leUer, for infor- mation,'had to be answered ; all in the short space of six weeks. Those who attentively consider the nature of the duties to be performed, and thelime allotted for them, cannot ftiil to be struck with its-total inadeqXiacy to that end. To have gone over some of the counties, in the time which the law allowed, would have been useless to the farmers, and have produced no presenter future 79 [GJ good results. It wns uUeify ini])0S3iljle fur any oiric to have per- lorine^l the duties of the law in the time, and with the means al- lotted for them. I, therefore, carried out iu this, the spirit and not the letter of the law. The mere letier of the law carried out, howsoever fuiihfidly, woukl have heen a mere shadow without a suhslance, and would have subjocled any one to.niorited ridicule and contempt, who, under any circuujsiances, might have pro- fessed to have done it. Another, and a great defect in the present la)v, is requiring the State Chemist to lit up his Labaraiory in (he dillerent counties, and there make the analyses, instead of allowing him to fix it permanently in one place. Though it \s possible, to carry the ne- cessary apparatus through the country, and make the analyses, yet it is at the saciilice of Uiuch time, which could be more profitably- spent in other duties, and recpiires much fruitless labor, which ' should be avoided. The rooms in which I had to place my ap- paratus, were such as I could procure, and ahvays unfit for that, purpose. Great injury, even wiih the utmost care, has sometimes happened to the materials, and considerable damage was frequent- ly done to the more delicate and cosily parts of the apparatus. Without the most delicate and accurate balances, no analyses can be performed, for upon their truth and correctness hang the whole value of an analysis. They should, therefore, be preserved from every thing likely to impair their riccuracy. Faraday, the first authority on this subject, and, indeed, on eveiy other coni?ected with chemical manipulation, says, without the n.ost delicate balan- ces, no analyses can be made, and all who are in the liabit making analyses as delicate as those which 1 have to perform, keep their balances out of the room where the analyses are made, though this room (that for analysis,) has all the means and appliances to carry off all vapors which may coirode or ir)jure the balances. It is especially enjoined never to touch them, except for the purposes of weighing, when their case should be innnediately closed, and that when once they are fixed, that they sliould not be moved. It can be readily perceived, now, what ditliculty I endured to !^eep ' mine correct, and the time which I had to spend to preserve thein from harm, and the derangement which they must have suffered in their fiequent removals fronr place to place. The law also, in its oth section, makes it a duty to publish notices of lectures, but makes no appropriation for defraying the cost. I do not know whether the Legislature intended that the State Chemist should pay for it himself. I have always given full notice in all of the county papers, where I have been, both of my presence in the counties, and of the time and place of giving my lectures, and paid for the publication from my own funds. Nor is any provision made for defraying the expense of removing ni}^ laboratory, or for the rent of rooms for it. There is, moreover, this general defect in the law, viz : that it requires mi a^noimt of duty to be performed, in a given time, [G] 80 wliicJt no man can 'perform^ as it ougitt to he done. And no one having any respect for his own reputation^ and capable of per- forming its duties, ivill ever pretend to do it. Knowing the lime lo be inadequate, to perform all of the duties, I devoted myself lo that paiticuh\i class, which would confer the greatest, benefit to agriculture, viz: the analysis of soils, marls, &c., leaving myself little or no time for the preparation of lec- tures, though from them one might gain much greater credit in the community, than f^om any thing else. I have been content to give the result of my investigations in the plainest style, being satisfied that it was better to spend my time in acquiring a large number of facts, otherwise unattainable, than in ornamenting a small number, by studying and writing out lectures. It was better to attend lo their substance, than to lose time in improving their form. • "With a law as defective as the one for the creation of the oflttce of State Agiicultural Cliemist, it is apparent, that to carry it out to the letter, would have been to render it null and void, and have subjected myself to the iinputation of chailataury and ig- norance. I, therefore, in good faiih, devoted myself, with all the energy and knowl^ge which I possessed, to fulfil its spirit, and so to ex- ecute it as to meet the wants of those for whom I was appointed to labor. All will bear witness that I have diligently discharged its duties, devoting myself excludvehj to them. I have had no other end in view but that of serving faithfully the agricultural interest, pro- inoting its welfare, and saving it from imposition and loss. The performing of the letter of the law, would have taken but little time and trouble ; in cariying out its spirit, great labor and inces- sant application was necessary. It cannot be charged, therefoi'e, that it was from any unworthy motive that I disregarded the letter of the law, since, by so doing, my duties were an hundred fold more arduous, my responsibilities and my labor greatly iricreased. I preferred to act right, and to perform my duties, so that they might lead to the knowledge of sound principles, and the true phi- losophy of agiicultuie. I rely with implicit confidence on the knowledge and good sense of the agricultural community, for my justification. I have, at least, the testimony of my own con- science, that I have exerted all my ability to " act W'ell my part," a solace, greater than all human praise could be, for duties imper- fectly performed, even though they should meet with public ap- proval. Your honorable bod}'- will also recollect, that the present law was originally formed for a principal and assistant, but that on its final passage, the section for the appointment of an assistant, was stricken out, while that detailing his duties was retained. There was thus left for me a double duty to perform, and, had I taken double the time indicated in the law, I still would have been within the time allotted by the original bilk 81 [G] Having thus pointed out to your honorable body the defects of tlie piesenl law, I will respect fully offer such suggestions for its amendnienl, as M)y experience in its duties have taught me to be necessary. Frst. — The laboratory should be fixed permanently in one place. The analysis of a soil, is one of the most difficult and delicate of all analytical operations. Any error in it, besides subjecting those who might be governed by its results, to loss, in making improper applications of manures, would also retard or destroy conlkleiice in its ability to render aid ti) the art of Agriculture, and thus cause farmers to reject assistance from the source most capable of rendering it at the cheapest rate. As every thin.g de- depends on the accuracy of an analysis, every care should be taken to insure that accuracy. A much greater nunibei, also, could be performed in avfixed laboratory, and every analysis, is one certain step towards forming a true system of Agriculture. If one analy- sis be of service, a greater number would confer proportionally greater benefit. With a fixed laboratory, no time would be lost, in moving it from place to place ; the soil or marls capable of being easily moved, without injuiy, should be moved to the laboratory — which can be moved only with risk of injury — and not the labora- tory to them. During the past year, could my laboratory have been permanent, many young gentlemen capable of affording me valuable assistance, would have been with me ; who would in time have become so many sources for the diffusion of scientific knowledge, derived from the application of Chemistry to Agricul- ture. In this way the State would secure a much greater amount of profitable work, for the same cost; the benefits of the law would be more quickly and generally diffused, and means would be given for furnishing to a large number of our citizens, without cost, knowledge of practical analysis, now scarcely attainable at the highest expense. So that, while the principal was em- ployed in collecting specimens, taking a general survey of the country, and giving to the community, by lectures or otherwise, the fruits of his investigations, the data of these results would still be accumulating, and their education would not be suspended with his absence from the laboratory. 3rd. The lectures are too numerous, they should only be given at such times and places as to secure a good attendance. Written instructions for publication should take their palce, whenever, in the judgment of the Chemist, it would best subserve the ends of the law. 4th. The time for the examination of any particular county or district, should be left, also, in a great measure to the judgment of the Chemist, under certain restrictions. It is an acknowledged principle, that the followers of every pro- fession or art, are the best judges of the manner in which the duties of their respective callings can be perfornied. This is con- ceded to those who follow occupations, of which all in the commu- 11 f G I 82 nity have some knowledge: — much more then, should it be grant- ed to (hose who follow a profession, of which, almost every one in the community is profoundly ignoiant. It is useless to bind one as to time in doing a particular thing, where no ability exists to know whether that thing be correctly done or not. The State Chemist may be restricted within a certain time to make particular investigations, but no restriction can force him to make these investigations, if he chooses not to do it. None but himself ever knows whether they be made or not, and since the perform- ance of his duty, must be left to his integrity and sense of honor, there is no good reason why the mode of doing it should not de- pend upon the same security. A law embracing the general features which 1 have given above, would much more expeditiously and perfectly supply the wants of the Agricultural community, than the one at present in existence. In this I am sustained by all who are competent judges. I have given thus frankly and freely my opinions as to the pre- sent, and my views as to the construction of a future law, having iri view only, the benefit of those for whom the law was made. To any one who will do his duty faithfully, the office is one of incessant toil and labor, and the object which I have in view is, to make that toil and labor effective when incurred. Your honorable body will perceive, from a comparison of the letter of the law, with the manner in which it has been carried out, that I had in view, principally, its objects, and only a general regard to that lime and mode by which those objects were to be attained. I believed it was more in accordance wiih the law, to fulfil its spirit and intent, though its form might be violated, than to pay attention to form, while its substance should be disregarded. Under this belief, I acted. I sought the counsel of some of the maturest judgments in the State, who coincided with me in opinion ; and I feel sustained in my course when I recollect, thatto have acted in any other manner would have been to injure the interest which I was selected to benefit. There is at this time great and increasing interest felt in Agriculture throughout our State. The great question every where amongst our farmers is, how can soils that have been worn out by improvident cultivation, be restored, most cheaply and quickly, to their original fertility, and how that fertility can be retained ? The only answer to these queistions has hitherto been that afforded by naked, isolated expe- riments; its voice has led some to success, while others who have obeyed it, lament time lost, labor gone, and capital expended in vain. There have been no certain rules to solve these questions, no rational way to unravel the seemingly complex laws which govern the production of crops. At this juncture, the State pointed out and presented to the Agriculturalist, the Science of Sciences, as a key to (he unlocked mysteries of Agriculture: — as a lamp, whose clear, certain light, 83 [G] was to illuminate (he path hitherto obscured by '^ shadows, clouds, and duiknoss. " Had this science been so applied as to have ut- terly failed in its object; —had all felt tbat no benefit could have been derived from it; — that it was powerless for good: — as would have inevitably been the case had the letter of the law only been observed — Agriculture would have received a severe check. The ardor of those foremost in the march of improvement, would have been dantpened, and the only oracle of truth to the anxious en- quirer after the philosophy of Agriculture, would have been con- temptuously spurned. Tlien would have followed a relrogade movement in the farming community, bearing it back beyond the point from which the present progress commenced. Other States, too, were looking on the experiment in Maryland with an anxious eye, leady to follow her example, if successful, but not able to profit by her errors, had the present law failed, — as it must have done, had the strict letter of it been observed. The State of Vir- ginia, at the last session of her legislature, had a bill under conside- ration for the general application of Chemistry to her Agriculture;- which did not then pass, doubtless because she wished to see the result of the law of Maryland. One of the southern States, Mis- sissippi, has a similar law in contemplation, and all will follow the example so worthily begun by our State, When, therefore, the future application of Chemistry to Agriculture, not only in our State, but in others, depended upon a demonstration of its utility, every motive of patriotism, and the plain demands, of duty alike required, that the demonstration should be effected. When I became the humble Minister of Chemistry in its appli- cation to Agriculture, justice to the one and duty to the other alike demanded, that I should only speak its precepts, only give utterance to its oracles, which could be done only, by laboring in each county, for a longer period than the law allowed. Its oracles would, with true inspiration only speak, after a more protracted devotion at its shrine than that contemplated by the law. Appointed to speak the truths of Chemistry for the benefit of Agriculture, I was obliged, either to speak those truths, which by its immutable laws are attainable with great labor and time — or to have submitted to the public, mere fictions of the iniagination, and thus have been a traitor to the science — faithless to the Art — false to myself, and to those whose influence placed me in my present position. The choice was not difficult. I have discharged my duties in a way capable of doing the greatest amount of good. The results are before the public — and to the judgment of enlightened and in- structed public opinion, I am content to submit. By its decision I willingly abide. At the present time it may seem almost a matter of supereroga-' tion, to speak of the utility of Chemistry to Agriculture. The Slate has made provision for its application, and favorable testi- raony from those who are too sincere to flatter and too intelligent to be deceived, has been given to its efficacy. [GJ 84 Why should not science benefit Agriculture? Its study will af- ford all the pleasure, which the Roman orator claimed as the pe- cuMar property of hterature" Studia literarum," says Cicero, "ado- lescentiam alunt^senectutem oblectant,secundas res ornant, ailver- sis profugium ac solatium praebent, delec(ant domi,non impediunt foris penoctant nobiscum perigrinantur, rusticantur,"* — whilst its practice will give those comforts, which, though more homely, yet cannot be supplied by mere literary studies. Its siudy affords all the delights of literature, with the addition of the necessaiies of life. Farmers should not be mere hewers of wood and drawers of water. Let them know, not only the necessary elements of fer- tility, but let them also understand how these act, in supporting vegetable existence, and how mere matter is indispensable to that function of organization, which we call life. Let them not look upon the earth as a mere source of food, while living; a mere place of repose when dead: but rather as a casket, whose treasures they may obtain if they apply their minds to the investigation of its formation. Let them seek to understand the properties of each component part of the soil, anil it will be a volume of endless plea- sure and instruction: then indeed will the toil, as well as " the sleep, of the laboring man be sweet," — for he can read "sermons in stones," and see " good iri every thing." It has been the peculiar province of science, ever to benefit the human race ; ever to afford pleasure in its pursuit, and profit in its application ; to lighten toil, to lessen labor, to assuage care; to relieve the wants of the body; to supply the desires of the mind. It is to the mind, what hope is to the affections, dispelling gloom — and in the daik- est hour, giving assurance of a brighter dawn. The student, in his closet, demonstrates a principle — and, straightway, millions of his fellow creatures receive the benefit ; are blessed with its advantages; and but too frequently, alas, bless not in return! The princi- ples of science perfected the steam engine, giving life and beauty to that, which before was only a crude misshapen mass -straight- way nations used it, to multiply their comfort in a thousand ways! Scientific knowledge in the hands of Archimedes, was a safeguard to his countrymen, more powerful than walls of stone or armies of men : — its power, with the same universality as death, is felt in the hovel and feared in the palace: — its influence, equally potent to relieve the sickness of the infant, and to stay the power of the ihunder-bolt. Let it not then be refused the Agriculturists. If he, through misfortune, cannot obtain it for himself, let the State, that he supports with his labor, and defends with his life, supply it. Let him but receive it, and the return will be, all blessings to her- self, all benefits to him. * Literature nourishes and strengthens our youth, affords delight in old age, adorns prosperity, gives help and consolation in adver- sity; delights us at home, is not in our way when abroad ; gives pleasure to us at night, in our travels abroad, and wanderings at home. S5 [ G ] Of all the sciences, Chemi«^try hns everslood foivmosL in melio- rnting ilie cdnililioii of ihe lnini;in lace. It. lias been lo llic ijody aliuodt wluiL CliiistiMiiiiy lias in-.eii lo l!ic swui ui man. Oiher sciences are pariial, this is universal ; other sciences benelii. the few, this blesses the many; other sciences are of nse to but one particular class, this embraces all. The highest, an J the lowest, ate equally iis debtors. Applied lo mechanics, it gives one the sireiiirili of thousands; — to nieiiicine, and, in 'disease, it lulls the infant as calmly to sleep, as when in health it lests on its inuilnjr's breast. It fnquenily snatches one from death, when it impends, and softens its panu;s when inevitable. Lei it then be applied lo furnish (he "staff of life." But it is not enough to make mere scientific researches. After beitig made, their results should be carried to the doors of the people. THEY SHOULD BE DIFFUSED THROUGH THE LAND. The experience of all should serve to guide each one that tills the soil, and to all should be given (he benefit of whatevei know- ledge is otherwise beyond their reach. To eflfect this dilTusion, agricultural societies, or cluhs of practical farmers, are of great use. In their meetings, the knowledge of one becomes (he property of all, each adds something to the general stock and receives some- thing bengficial in return. By the very act of communicating knowledge once acquired, we improve our minds, cultivate our understandings, enlarge our ca- pacity for the observation of new facts, and increase our ability to investigate them coriectly, when observed. But the benefit is not merely one of a mental or pecuniary nature, the social good accom- plished is of vast consequence. Farmers would think favorably of each other, as they become better acquainted. Tiiey would be more united to resist aggression, niore umted in all efTorts to promote theircommon welfare, and ever"in union theie is strength," Frequent association and the habit of fiee discussion, do niuch to promote the intelligence and good feeling of every class. This is especially remarkable in the legal piofession. I'hough often ad- versaries, ihey are always united in whatever concerns the best in- terests of their pinsuil. We can easily see what excellent results would follow from a more intiniate union of those, who have a common interest (o advance and who meet not to confute, but to aid and assist each other. 1 have witnessed the great good done by t\.ssociaUons oi practical farmers, whh frequent meetings for the discussion or Agricultural subjects, and as great aids (o im- provement, would recommend their formation in every neighbor- hood of our Slate. The Pie;s, too, is all powerful in the diffusion of Agricultural information. This great instrument of human knowledge, speaking a lan- guage whose utterance can be recalled at pleasure, has done much and can do more to spread the amoimt of existing knowledge, and by inducing investigations to increase it. [G] 86 It is well for fanu'ers to recollect, that as lliey increase the sub- pcriplion of pnpers devoted to their interests, they iricrease their abihiy to benefit it, so tliut each one who iiilces a paper lias a per- sonal interest in increasing its subscription as much as possible. But it is not only the present race of farmers who should be thouijht of. The next generation should be taught now, the true principles of agriculture. There are at this ti:ne, thousands of children in the Stale, who should be receiving elementary instruc- tion in Agricultural Chemisti}^ taught them in a plain and com- prehensive manner. There will then be done for the next gener- ation, wh.at can, at best, but be imperfectly done for this. 1 must not be understood as advocating the teaching of analytical chem- istry in our common schools and academies. This is impossible and should not be attempted; but only the elementary principles of chemistry, in its application to agriculture. Farmers from these schools, would be belter able to understand treatises on their pro- fession, and coniprehend the language which belongs to the science nearest allied to their art. They would become acquainted with many facts of great practical benefit, and by having their minds directed to this study when young, would more certaiidy apply to it when old. The benefits from this, all can see. The benefits that have arisen from the execution of the present law of Maryland, are vast and important. It has determined the composition of many deposits of marl, giving to the owners there- of, guidance for its application, which before they had not. Bv determining the compositions of many variety of soils, it has been able to recommend the specific manures for them. There have been expended hundreds of thousands of dollars, in the application of magnesian limes to soil, which already contained a sufficient abundance of ir.agnesia. There have been expended hundreds of thousands of dollars, in the application of limestone containing no magnesia, to soils equally destitute of it : thus with- holding from them a necessary constituent, when no espense would have been incurred in applying it. Some soils are injured by deep ploughing, and these I have ac- curately described to their owners, as far as it was possible to do so. Other soils require deep ploughing. The surface soil, from long and shallow cultivation, was almost entire exhausted of lime, mag- nesia, and potash, and besides, its mechanical texture was unfavor- able to vegetation. The subsoils capable of counteracting the faults of mechanical texture, and having constituents to supply the chemical defects were analysed, and their value insisted on. In many sections of the Stale, the subsoils lying only three or four inches below the surface, contain from eight to twenty-five bushels of lime per acre, for every inch in depth, besides also magnesia and potash. These had been undisturbed for years, and would have re- mained untouched forever, unless some chance experiment had dic- tated their cultivation: the experience of oti)ers on different soils being against the mode of cultivation to bring them into use. In no singie solitary instance has the farmer been disappointed in the mode 87 [CI] of cullivation, predicated on the analysis of itiese paiiicular subsoils. Men of the highest knowledge and education hear (estimony to their value; men of ihe surest practical knowledge have become con- verts to a system of cultivation opposed to their former usage, an»i unsanctioned by any custom of which they were cognizant. The products of these lands in their lirst crop have been greatly increased, and will, if lire rules laid down by the leachings of science be followed, giv-e as large crops as when they were first cleared. There hasbeen besides, asone of the fi nils of this office, and by no means the least important, a spirit of enquiry and in- vestigation set on fool, which, carried on by men who know "oo such word as fail," will confer great benefits on practical Agricul- ture. 1 have also analyzed and deter.iiined, the value of many speci- mens of bog iron ore : there is a prejudice against the iron made from this ore, amongst farmers, who say, that the iron fiom it is al- ways vei-y "brash." This is owing, I am certain, to the carbon, (charcoal,) in the iron, and not to any intrinsic quality of the ore from which the iron is made. This charcoal is (o be destroyed by more skilful preparation of the iron. This not being in the strict line of my duty, I did not follow up my investigations on this most interesting subject. 1 am satisfied however, — ether things being equal, — that the specific gravity and tenacity of iron is in direct ratio to llie quantity of charcoal which it contains. Farmers have been directed to the true sources of knowledge, and when sufficient time elapses for its application, fruits will be seen in more improved lands, and happier homes, than yet have blessed many sections of our State. 1 have been infornred by one of the largest booksellers in the Stale, that he has sold more scientific works on Agriculture since the existence of the present law, than have ever before been sold in the city where he lives. The community, too, have been saved much in avoiding nos- trums, which, under the guise of niunures made on scientific principles, are frequetrtly based on ignorance of the first principles of science, are false in theory, and even have not always the merit of being compounded in accordance with that theory. These truths are the best evidence of the necessity of this law, and I can refer for their evidence, to every county of the State where I have been. The testimony is living, present, and unim- peachable, and I may safely sa}^ will be given fronr more nume- rous sources as its practical operations develop it. VVe can confidently look forward, as the fruits of this office, to a system of Agriculture founded on sound principles of induc- tion. The facts collected by it, when sysiematised, will make the culture of the soil as certain, as airy of the arts which depend on the exact sciences for aid. It will settle, in reference to the soils which may be investigated the following questions: — The best hind of manure; the best time and form, for its application; and the quantity to be used; so as ^0 produce the greatest yield at the least cost. [G] 88 It will eniible us to guard against and counieract some of the diseases to which our most valuable crops are subjecl, and save in this manner thousands (o the Slate. I have, as /ar as my hmited time allowed, been making some observations on the naiure and causes of rust in wheat, a disease which frequenily, in a few hours, destroys (he labor of a whole year, and I am certain that a remedy will be found for this deslruclive enemy of ihe wlieat crop. 1 shall give a brief abstract of the reasons on which this belief is foiuid- ed, so that they may be corrected by the observations of others, if unsound: and I hope that some who may have greater oppor- tunity than myself, may siudy the subject^ and give the public the benellt of their investigalions. Rust in wheat has been attributed to many and various causes, but as some of them are not always present, and in some cases all are absent, it cannot be said that the exact cause of it has hitherto "beea determined. Many circumstances may attend the develop- ment of this disease, but uniil some connection be shown between them and the production of the disease, they can only be viewed as accidental and not as essential attendants. If we find lust occurring always under particular circumstances, all of which are in action when it is produced, we must attribute its production to the influence of those circumstances. We shall then know, frciTi a knowledge of the causes, how they can be counteracted. To understand fully the nature of these causes, it is necessary to remember that the stalk of wheat is filled with nu- merous sap vessels, by which the matter in the soil necessary for the perfection of the grain, is carried to it. If those vessels be broken, burst or injured in any manner, the supply of nutriment lo the grain being cut off, it cannot be perfected. I believe that the rust is nothing more than a fracture or bursting of the vessels of the stalk, destined in the economy of the plant to carry nutri- ment to the grain — I believe it for the following reasons: It always occurs in warm damp weather, at a time when the external pressure of the atmosphere, from its lightness, is least, and when the outward pressure of the juices of the stalk, from heat, is greatest. We have here two efficient causes for the bursting of the vessels, either one of which being absent, rust is never pro- duced; for no matter how damp the weather may be,^if it be cool, there is no rust; and no matter how warm it may be, if the weather be dry, (in that condition in which the pressure of the atmosphere 13 greatest.) there is still no rust. Again, rust occuis in that jmr- ticular stage of the growth of wheat wdien the stalk commences to harden; it does not happen before, because the vessels would expand wlihout breaking, it cannot happen afterwards, because they have become suflSciently strong to resist the expansion of whatever sap they may contain.^ *These fracture" are distinctly visible by means of a good micro- scope.- This instruiiient, which has afforded such great facilities to many other branches of science, had never, as far aa I can 89 [Gl Here arc two causes in action sufficient to explain all the phe- nomena which attends in wheat, and which are explained by none other. We know that if the vessels which convey the materials that form the grain be destroyed, the grain cannot be formed. We see here causes in action sufficient to produce that destruction, and we never see it produced without the existence of those causes. But this is not all. Whenever we find any causes present, able to counteract the influence of either of the above, rust is not pro- duced ; whenever, in the composition of the soil, sufficient materi- als exist to give a firm strong stalk, rust is never seen. On land exposed lo the influence of the spray from saltwater, wheat always escapes the lust, though that in the same neighbor- hood may suffer. A narrow belt of trees frequently separates fields, that are uninjured, from those which are entirely ruined: this belt of trees arresting the spray from the water. This spray contains soda, one of the substances which assists to form a strong hard stalk. Upon soils precisely identical, except in local ion, and in what was derived from salt water, I have found the above fact to exist, which can only be accounted for by materials in the salt water. Wherever the soil contains the materials in proper proportion for forming a strong stalk, rust does not nijure the crop. In localities where rust was before troublesome, it has almost ceased to exist, after the application of green sand marl, which is lich in those substances which form the stalk. Again, common salt has been recommended to prevent rust, by ks antiseptic power, that is, its power to prevent putrefaction. Its eff'ect against the rust, may be better explained by its power to stiengthen the straw. I shall institute during the present season a series of experiments on this subject, and confidently expect to determine the true nautre of this blasting, blighting disease. If it be from the causes which I have given above, then the remedy will, in preventing the efleclg of the injury, greatly increase the product of this, the staple crop of the Union. The material to prevent this is in very great abundance in our State, and now deemed worthier. At this time its owners will pay for its removal. If in the present report, or in the labors which preceded it, any good shall have been conferred on (he Agriculture of the State, those labors will be abundaiiily rewarded. If I have only awakened such an interest in our Agiiculturists, as will induce them to study and apply the sciences of their art, my ambition will be satisfied. learn, been applied to the diagnosis of the constiuients of soils, until used by myself. I have not been able as yet to make but few investigations with it ; though it may not confer the same advantages on the prosecution of the study of the components of soils, as (he tftlescope has done in the study of Astron)ony, yet I am ceitain that it will be of very great utiliti/. During the pre- sent year 1 intend to devole much time in order to see how far that utilitv extends. 12 [|G] yO In conclusion I must slaie^ thnt since my appointment to tlie office of State Agricultural C[ienii:~t, I have been cheered by the warmest and kindest greetings in every county of the State where Miy duties have called me. All have welcomed^, all have tendered m,e t|ieir hospitality to the fullest extent. Id the performajice of the duties of my office, many privations, l^nown only to those acquainted with ihem, had to be endured. The office v/as looked upon by many with distrust; to many its purposes had to be unfolded ; to all its utility had to be demon- strated. Cheered by the kindness and full appreciation of those ]by whom I was surrounded, sustained hy the oisKjirsi in viy heart and heartiest in tnypfayers, I have to be devoutly thankful for iki^ pleasures '^\\\c\\ attended my lalxirs. I here tender to ali my most sincere and heartfelt thanks^ and give my most sincere prayers for their present prosperity and future bappines?. 1 shall ever remember their friendship and kindness with devout gratitude, and while wishing for them, that the produce of their tields may be as generous as their hearts, devoutly pray, that they may enjoy tlie happiness of everlasting life. ■ritiiMi Jufi . JAMES HIGGiNS GLOSSARY A."7ALTSi3, as a chemical operation, consists in the separation of compound substances into their component parts. Qualitative Analysis, is the operation of showing merely the nature of the bodies inakin^ up any compound. QpANTiTATivE ANALYSIS, is the Operation to discover the exact amoant ot each separate constituent. A Special Qualitative ok QciNTiTATivE Analysis, is that which shows the nature or exact quantity, as the case may be, of any number of bodies composins; a compound, short of the whole number. Eleme.vt, a simple body — Elementary bodies are those which are not com- posed of two or more different substances. Atc-vi, the smallest p^itide of matter, necessarily incapable of further division. Chemical AmxiTy, or Affinity, is that property of the atoms of bodie9 which causes them to form new combinations, producifig new bodies diti'erent from those which existed previous to the developement of this propert}'. It is the force which occasions the union of different kinds of matter, whether simple or com- pound, and the greater the difference of the properties of bodies the stronger appeals to be this species of attraction between them. Acid, a substance whether sweet, sour or tasteless^ which combiner icitk bases, forming with them a class of bodies called salts. Base, a term extended to embrace a large group — compounds of the metals, (wUh the exception of ammonia) with those substances which support combustion-^ which having any taste are not sour, which are not disposed to unite with each other, but unite readily with acids forming with them a class of bodies caiU ed salts. , Alkali, an Arabic word applied to bodies having a peculiar caustic taste, in aH of their properties the reverse of acids — all alkalies are base*. Caustic potash is a familiar example of an alkali. Salts, bodies formered by the union of an acid and a base, having properties distinct from eiMier the aaid or the base which enter into their composition. Gas, matter existing in an airiform state, differing from vapour in requiring a much greater force for its condensation. It has different names accordin? to the sub- stance of which it is composed; sometimes it exists as an element,"and is theu named trom some prominent characteristic — thus we have carbonic oxide gas, com- posed of carbon and oxygen, and oxygen gas, which is an element. OxYGE.v, a gas most extensively diffused thro-ughout nature, always in combi- nation with some other substance, either mechanically, as in the air; or chemicaHy as in water. It has strong affinity for almost all bodies, and received its name from two Greek words, oxus, signifying sour or acid, and gennaem, to produce, because when first discovered it was supposed to be the source of acidity — it sometimes is called Vital Air, because it is necessary to the life ot animals and vegetables. Combustiox. — The union of oxygen with any other body accompanied by light and beat. Oxidation. — The union of oxygen with another body, without the concurrence of light and beat. When oxvgen unites with metals it produces what is called Bust". Hydrogen. — A body very extensively diffused through the world, forming a a large part of all vegetable matter, and about two thirds of all water. It is Xhe light ;st of 'all bodies, and on that accoun used to fill t\?lloonsv with oxygen it forma [CJ] 92 water. This is a good example of the change produced by affinity; here two in- visible boities unite to form a third different in all of its physical properties from those of which it is composed. It receives its name from two Gieelc words, HudoT, signifying water, and Gennaein, to produce, because without it water can- not be formed. Nitrogen. — A gas very extensively diffused through the world, entering largely into the composition of the plants and animals, aiii Ibrming about eight tenths of the air we breathe; with hydrogen it for«s aiumonia. It is sometimes called azote from two Greek words signifying not, and zoe, life, because when breathed alone, life will cease to exist. Ammonia. — A compound of hydrogen and nitrogen, and very generally diffused throughout nature, being a general product of the decay of animals and vegetables; it exists in the air we breathe, as has been satisfactorily proven, united to carbonic acid, [t is called ammonia, because first made in large quantities at the Temple of Jupiter Ammon, from the dung of camels — when united to carbonic acid it forms what is familiarly known as sraeliinu; salts, volatile alkali from its great volatility; hartshorn, because made from the horns of Stags, ?cc. Carbon. — Charcoal in common language; forms a very large proportion of the structure of animals and vegetables, and is the reeidup. lelt when they are subjected to a red heat, without the access ol .lir. Coke is the charcoal from coal — Ivory Black is the charcoal from bones — Lamp Black the charcoal from Resin. The Diamond is but chrystalised charcoal, and Black Lead contains from 90 to 95 per cent, of it. Wood charcoal has the property of absorbing many times its volume of different gases, and of giving them up again when heated. This depends entirely on its mechanical structure, all porous substances acting in the same way to a greater or less extent. Carbonic Acid, formed by the union of oxygen with carbon, and exists in the gaseous form when not combined with some other body; it i? extensively diffused through the earth, air and water; is always produced by the burning of wood, and is expired from the lungs of animals in breathing. It is* found united to quick lime, and with if forms marble and the different varieties of lime-stone, from which it is expelled by burning. It is the escape of this acid which pioduces effervescence when soda or seidlitz powders are mixed, and which also causes effer- vescence when vinegar is poured upon marl. It is this gas which sometimes causes death to persons who go down info wells; it extinguishes burning bodies, and is called from this fact fire-damp, sometimes also choke-damp, from its causing, when breathed, spasms of the windpipe. Death has sometimes occurred to persons sleeping iu a close room, from the pro- duction of this gas by a pan of burning charcoal. This is another good erample of the changes pro: iced by affinity; here char- coal which can be seen, felt and handled, —ben united to oxygen, assumes the gaseous form, becoming invisible and intangible.