lA LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY 01 \\ : 'f ^ lA n ^ffl LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY Of ^3v0^^^i LIBRARY OF THE UNIVERSITY OF CALIFORNIA LIBRARY Gi SITY OF CALIFORNIA ft) LIBRARY OF THE UNIVERSITY OF CALIFORN LIBRARY OF THE UNIVERSITY OF CALIFORN ^^^5^^^^^ SITY OF CALIFORNIA LIBRARY OF THE UNIVERSITY OF CALIFORN RURAL ECONOMY, IN ITS RELATIONS WITH CHEmStRY. physics, AM) METEOROLOGY OB, CHEMISTRY APPLIED TO AGRICULTURE. J. B. BOUSSINGAULT, USHBSK OF THK INSTITUTE OF FRAltCK, XTO., KTO. TRANSLATED, WITH AN INTRODUCTION AND NOTES, BT GEORGE LAW, Agbiculturibt. NEW-YORK: ORANGE JUDD & COMPANY 245 BROADWAY. (,- i^ hr^ i A THE AUTHOR'S PREFACE. In the work now published, I present the results of the inquiries in which I have been engaged for many years, and which were un- dertaken in the hope of throwing light upon various points of prac- tical agriculture. My first idea was, to confine myself to the mere re-impression of the several papers which I had communicated from time to time to different periodicals, with the addition of a quantity of inedited matter which I had by me. But upon more mature con- sideration, I was led to believe that I should be doing a useful thing did I fill up the numerous gaps which must necessarily occur be- tween papers published isolatedly, at dates more or less remote from one another, and treating of the most dissimilar subjects. I have thus been led, in addition to my own observations, to give those of numerous writers on almost every branch of agricultural science, being only careful to confine myself in each instance to the most authentic practical conclusions ; for it is certain, that practical data have the most direct interest for rural economy, both in itself and in its bearings upon the general science of political economy. I have a further reason for the plan which I have adopted, which [ am the less disposed to pass by in silence, inasmuch as it may plead in excuse with those who might be disposed to criticize the tone, perhaps somewhat too didactic, of my work. I was invited, in conjunction with several other professors attached to a great educational institution, to give a course embracing my views upon the science of agriculture. I consented to this, and prepared my lectures ^ but motives, to which I was entirely a stranger, having prevented the project from being carried out, 1 made up my mind to publish, not the lectures such as I should have IV AUTHOR S PREFACE. delivered them, but the documents which would have formed the basis of my teaching. The first part of this work treats in succession of the physical and chemical phenomena of vegetation ; of the composition of vege- tables and their immediate principles ; of fermentation ; and of soils. The second comprises a summary of all that has yet been done on the subject of manures, organic and mineral ; a discussion of the subject of rotations ; general views of the maintenance and economy of live-stock ; finally, some considerations on meteorology and cli- mate, and on the relations between organized beings and the atmo- sphere. I have endeavored, therefore, to give a summary view of all the questions of rural economy that admit of scientific treatment. It may be found, perhaps, that the number of these questions is still ex- tremely small. Nevertheless, in regarding the multitude of inquiries that have been instituted within a very few years only, in viewing especially the ever-increasing interest attached to researches bear- ing upon practical agriculture, we are bound to anticipate progress, and to hope for conclusions important as regards science, profitable to practice, and useful to humanity. EDITOR'S INTRODUCTION The following work is submitted to the agritnltural public in the fullest confidence that it stands in need of no recommendatory strictures on the part of those who have undertaken to present it in its present form to the English agriculturist. In the person of its distinguished author the man of science is happily associated with the practical farmer — the accomplished naturalist, the profound chemist and natural philosopher. The friend and fellow-laborer of Arago, Biot, Dumas, and all the leading minds of his age and coun- try— M. Boussingault's title to consideration is recognised wher- ever letters and civilization have extended their influeuce. Surely the collected and carefully recorded experience of such a man, experience by which the conclusions of the member of the In- stitute have been tested and weighed by the results of the farmer of Bechelbronn, must have value in the estimation of every educated mind, and cannot fail to be especially welcome to that class of readers who are professionally engaged in the practical application of that noble science which his labors have contributed to illustrate and advance. When the following pages were confided to the editor, it was the impression both of the publisher and himself, that in the course of the work many points would necessarily arise demanding elucidation, others calculated to provoke controversy or challenge investigation, and others again which could be rendered available or instructive to the British agriculturist only by means of copious explanation, showing with what modification and under what circumstances the views advanced might be applicable to the art as exercised in the climate and soil of this country. But the minute and analytical perusal indispensable in the operation of investing the Author's thoughts and expressions with an English garb, has demonstrated the fallacy of this impression, and if possible has augmented the admiration of the untiring patience, the vast experience, and the as- tute, circumstantial, and elaborate accuracy of the accomplished Author, in whose researches the reader will find the profoundest sagacity, combined with a childlike simplicity which communicates to his work a charm not necessarily inherent in the subject. This is not iD*<^nded to imply an unqualified approval of the illus- trious philosopher's manner of dealing with his own facts and obser 1 2 INTRODUCTION. vations ; still less of nis style of writing, which is often wanJe ing and diffuse, and which, in order to render it presentable to the Eng- lish reader, has required much compression and retrenchment. Still, however, instead of having, as was expected, to pause at each step of the Author's progress, and dissert upon his views upon this or that particular branch of his subject, the observations of the com- mentator must of necessity be restricted in a great degree to an in- dication of such parts of the work as in his judgment are the most valuable and instructive, together with such incidental objections aa appear to be of sufficient importance to require stating at length. The chemical portion of the work is of inestimable value and con- ducted with consummate skill and knowledge ; and with a minute- ness and accuracy perfectly unexampled. At the same time the results of the writer's researches, as well as the means and process- es by which these results were obtained, are displayed with such absolute perspicuity as to be intelligible and instructive to every agricultural inquirer, however superficial his previous acquaintance may be with the details of chemical science. Nothing from the pen of tlie Editor could throw additional light upon the Author's brilliant and most interesting elucidation of vege- table physiology : his exposition is at once masterly and complete, and contains much that is both valuable and new. And even when the novelty of the facts which he adduces, or the originality of the inferences deduced and unfoldea may admit of question, they are still -deserving of the most respectful attention from the new and striking lights in which he places them, and presents them to the agricultural reader, and the clear and convincing way in which he demonstrates their inter-dependency and their most intimate con- nection with many of the most important pecuniary and professional interests of the cultivator. Every intelligent farmer will find his account not merely in a repeated perusal of this portion of the work, but in regarding it as a text-book and manual to be kept by him for permanent reference and consultation. The arrangement of the subject, naturally and judiciously adopted by the writer, presents the consideration of soils as the first topic for the observations of the agricultural commentator ; but on this head the distinguished author is so thoroughly explanatory and judi- cious, that nothing is left for the Editor but to approve, to acquiesce, and to recommend him with admiring confidence to the patient con- sideration and study of the intelligent inquirer. At page 237 the subject of manures is taken up, and discussed with characteristic minuteness through many succeeding pages. It may perhaps be objected, that the various theories respecting the origin, nature, efficacy, and relative nature of the difl^erent ma- nures in use, as well as the various modes of their produttion, con- coction, and application, which M. Boussingault has here collated and elucidated, contain nothing new ; that they have, in fact, under one form or other, been long familiar to practical men ; but without impugning the justness of this opinion, the Editor has long been eonvinced that the subject has received, generally, far less care and INTRODUCTION. 3 attention than it so eminently deserves ; and, in short, that it is much neglected by many who are accounted not merely intelligent, but scientific agriculturists ; and while admitting that much valuable information has been frequently given to the agricultural world by the repeated experiments of several enterprising individuals both in Scotland and England, he still most urgently recommends a careful study of this part of the work, which will probably lead the reader to the conclusion that the methods and practice recommended by the Author are, upon the whole, those best worthy of adoption. In page 260 will be found some very urgent warnings against what he (M. Boussingault) regards as the prevalent and pernicious cus- tom of turning dung-heaps " frequently." If, however, by the term " frequently," a course not exceeding three complete turnings of the heap be comprehended, the Editor can by no means coincide with this opinion ; a long experience having convinced him that there are many circumstances under which the Author's recommendations would be found not merely over-cautious, but positively injurious. For drill crops, for instance, when it happens that the farm-dung is somewhat rough, which must generally be the case towards the close of every season, when the animal dejections are scanty and the great bulk of the already ripened manure has been carried out upon the land, and the fresh additions have not had the advantage of being compounded with matter already concocted, an extra turn- ing is very advantageous. Every farmer will, of course, turn his heap once, for the purpose of thoroughly mixing the various ingredients and different qualities of manure which it contains ; the extra turning, even admitting that it may to a certain extent promote the over-decomposition of the manure, and dissipate the ammoniacal principles which it is impor- tant to preserve, is not attended with so great a loss in this respect as that which is inevitable from keeping open the drill by the appli- cation of coarse dung, which cannot fail to be attended with a most serious loss of the more volatile principles, sometimes even laying the manure quite bare, and in the case of turnips, materially ob- structing the operation of sowing. Our Author brings forward the authority of several eminent inqui- rers in support of his own favorite view of the use of fresh or un- fermented manure ; but however plausible their theories may appear, and however just may be their views in the abstract, there are many intermitting circumstances connected with the general economy of a farm, which must govern and determine their adoption, and in which the practical cultivator must be guided by his own judgment alone. To the Author's 6th chapter the reader may be advantageously referred, as containing a very full and valuable description and dis- cussion, under the head of mineral manures, of the different varieties of the class usually denominated stimulants, and concluding with a brief but lucid and interesting account of Water, considered as an agent of vegetation, and of its importance for manuring purposes. The composition and preparation of liquid manures, as well asth« • INTRODUCTION. various means of procuring and preserving them, will be founc to have engaged much of the Author's attention ; and he justly points to the rapidity of their ameliorating action as a peculiar excellence, not otherwise attainable ; at the same time admitting that in the great majority of cases, the great and unavoidable expense at- tending their application, however moderate may be the prime-coit of the material, has always operated as an insuperable obstacle lo their general adoption. In the justice of this vital objection, most practical agriculturists who have used them to any extent, will read- ily concur ; and it will not be uninteresting to the reader to learn that there is reason to believe that it will henceforth be eflfectually obviated by the use of a very simple and convenient apparatus, de- vised by Mr. Smith of Deanston, a zealous and able friend of agri- culture, who at the Highland Society's meeting at Glasgow in autumn last, explained the details of his contrivance ; and the Edi- tor has reason to suppose that the particulars will be given in a report of the proceedings of the meeting, in the forthcoming January publi- cation of the Highland Society's Transactions. The Editor is anxious to direct especial attention to the Author's 7th chapter, wherein he treats of the organic and inorganic manures, and of crops — of the elements of manures and of crops with their relations inter se^ &c. — a section of the work which presents, in synopsis, a more copious and complete body of new, interesting, and important facts, of a nature more valuable to the practical farmer, than has ever been collected in any previous treatise on agricultural science. The great mass of this invaluable information is condensed, as it were, for practical reference, and displayed in copious and elaborate tabular data— 3. form which, though not attractive, has enabled the writer to comprise within succinct and manageable limits, a quantity of instruction which, in a more discursive shape, must have distended the work to double its actual size. The tables ad- verted to, present not merely the results of multifarious experiments in illustration of the important subject of rotation-cropping, but also these results as especially aflfected by the application of the various manures to which the several experimenters had recourse. The rotations reported may appear strange and curious, and sometimes, perhaps, even amusing to the farmers of England and Scotland ; but not more so, in all probability, than those which are A))1owed in many parts of our Island would appear to the cultivators of that part of Europe where our Author's agricultural speculations have been carried on, and where the bulk of his analyses have been ob- tained : indeed, locality and climate, and their inseparable concomi- tants, will in every country be found to prescribe and control the sorts of crops which may be rendered the most subservient to the permanent advantage both pecuniary and economical of the hus- bandman. Thus, with regard to the Author's more didactic obser- vations and positive directions on the subject of rotations, there is no reason to doubt that, in relation to the soil, climate, and geographical position of the east of France, where his experimental course of rotations has been conducted, they are highly judicious, and hare INTRODUCTION. 5 not been prescribed and required without mature consideration. Moi'eover, they are marked, like the deductions and inferences upon which they are founded, by his unusual acumen, patience, and saga- city ; but in their application to the more circumscribed range of culture to which the agriculturist is limited in the ruder and more fickle climates of north and of south Britain, the practice of the cul- tivator must be governed mainly by his own judgment and experi- ence in the circumstances by which he finds himself surrounded. The interesting and ample instruction conveyed in the observa- tions of this acute and profound observer upon the food and alimen- tary treatment of cattle of every species, accompanied as they are by minute details of the results obtained in the shape of organic and inorganic elements, cannot be too urgently recommended to the at- tentive consideration of every one interested in that important branch of rural economy to which they more particularly relate. The Author's strictures comprehend the economy of the domestic animals with the exception of sheep, a subject from which he pro- fessedly abstains, for the very sufficient reason, that in his opinion, his opportunities of obtaining accurate information thereupon have not been sufficiently ample to enable him to discuss it with confidence and advantage. His theory in favor of the superior fattening quali- ty of hay and the grasses in general above that which is found in tubers and roots, (though apparently supported by his usual convin- cing appeal to experiment,) will be received with considerable al- lowance by the practical farmer. We have many instances, in the present day, of theories ably, plausibly, nay even satisfactorily established, which are nevertheless met by opposite results in practice ; and the hesitation which the Editor ventures to intimate upon the particular point in question, will, he doubts not, be readily concurred in by many experienced feeders. It will be generally admitted that the boiled or steamed potato possesses a much higher nutritive value than belongs to it when in the raw state. In the former case, however, it requires to De mixed with some of the other roots which are not characterized oy the same property, such as beet, turnips, &c. ; the Swede, (Ruta- baga,) or any of the harder sorts are best adapted for this purpose, and form a complete counteractive to the dangerous constipating tendency of the boiled potato when given alone. There are many different substitutes or equivalents in the shape of mashes, containing leguminous ingredients which are admitted to be fully as nutritious as the potato, still there are circumstances connected with market value which render it a most valuable re- source in farm alimentation. The popular notion that (when used ae the feed of horses) the boiled or steamed potato is what is vul- garly called " soft meat," tending to unfit them for active work, is daily losing ground ; for not only is it rapidly getting into more gen- eral use among the farmers of England and Scotland, but even post- masters are adopting it for horses employed in road work. The meteorological section of the volume will be found no less instructive to the agriculturist than fascinating to the general reader ^ 1* 6 INTRODUCTION. no eqaally complete and extensive body of new and interesting fact* has ever before been presented in a collected form to the agricultural world. It will be observed that the capital, the all-important subject of Draining, as the great master-engine of agricultural improvement, is merely touched upon by our Author in a cursory way ; shojld this incite a feeling of disappointment, it must be borne in mind that he has accomplished all, and more than all, that he nroposed to him- self, which was not to write a complete work on practical tillage, but rather, as his title implies, on " Rural Economy," i. e., the eco- nomic production and application of the produce of the soil under the guidance of chemistry. Among the faults of execution for which the Translator ventures to solicit the agricultural reader's indulgence, is the occasional adop- tion of terms which are rather French than English. Many of these words are, in the original, not merely technical, but local and provincial, and are not inserted in any of the dictionaries. More- over, in the description of certain processes and operations, the Author has occasionally employed terms for which there is no Eng- lish equivalent ; and the Translator had frequently no other choice than that of either leaving the sense of the passage obscure and defective, or, on the other hand, of adopting the barbarisms in ques- tion, which not only deform the English of the construction, but cannot fail to be offensive to the taste and professional preposses- sions of the agricultural reader. With reference to the weights and measures made use of in the oiiginal, it may be proper to state, that (against strong temptation to let them stand as in the French, merely adding a table of equiva- lents) they have, at the instance of the Publisher, been reduced into their corresponding quantities in the English standard. Grammes., in the more delicate experiments, have been reduced into grains troy, assuming the gramme as equal to 15.438 grains ; in less deli- cate experiments, grammes have been converted into pennyweights (dwts.) and ounces troy. Kitogrammes are given in lbs. avoir- dupois ; and where the quantity was large, they are often brought into tons, cwts., qrs., &c., taking the French kilogramme at 2.2 lbs. avoirdupois. The Litre^ or present French measure of liquids, has been reduced into pints, calculating the French measure at 1.76 pints English imperial measure. The Hectolitre employed in mea- suring grain, is rendered into bushels, estimating it at 22 gallons English dry measure. The old French Quintal is also sometimes employed : this measure of weight has been either reduced to its proper corresponding quantity, 1 cwt. 3 qrs. 24 lbs. English, or where odd numbers might be disregarded, it has been called 2 cwts. The Are., or French superficial measure of quantity, has been cal- culated throughout at 120 square yards English : the Hectare at 2.4 acres English. The labor of reducing these measures into their English equiva- lents has been immense ; and errors, in spite of the best care which could be exerted, have doubtless in various instances crept into tha INTRODUCTlOrf. 7 reductions. Slight discrepancies between aggregate sums and their component quantities will also be apparent here and there, an inex- actness which arises from the number of decimal places not having always been carried out far enough. Our Author often quotes English agricultural writers, whose weights, &c., he has always been at the pains to reduce into their corresponding French equivalents. Not having at all times the works referred to at command, the Editor was compelled to bring back the French weight or measure into the corresponding English one by calculation. Thus from not knowing the precise equiralents adopted by M. Boussingault, some trivial discrepancy between the computed and the original weights, &c., may have resulted ; but as the quantities that have been treated in this way are especially im- portant as relative, scarcely ever as absolute quantities, the error where it occurs can be of no real consequence. Metres, centime- tres, and millimetres have been reduced into English feet and inches, assuming the metre as equal to 39.370 inches. Finally, and to conclude our list of reductions, (would that it had been shorter !) the degrees of the centigmde thermometer have been brought into degrees of the only scale in familiar use among us, viz. Fahren- heit's. In the translation the Editor has endeavored (not always with perfect success) to be as little technical as possible, with a view to the convenience of the general reader. In a very few places he has even ventured slightly to condense the style of the original in order to keep the volume within moderate dimensions, occasionally throwing the information contained in a table into the text or nar- rative ; and where the Author appeared to him to be forgetting the rural economist in the mere chemist, as where for example he de- scribes the special modes of preparing and purifying indigo, &c. he has made bold to retrench details, and give the results or conclusions only. All analyses bearing on the practical subject, whether it was the soil that produced, the crop that was grown, or the animal which fed on that crop, have been scrupulously retained. In conclusion, the reader is earnestly recommended to read an admirable little work, the joint production of Messrs. Dumas and Boussingault, en- titled in the original, " Essai de Statique Chiraique des Etres orga- nises," which has been presented in a clear English translation, under the title of, " An Essay on the Chemical and Physiological Balance of Organic Nature," and may be regarded as a most valuable intro- ductory aid to the perfect comprehension of Boussingault's Philoso- phy of Agriculture, and as a key to the more scientific and technical portions of the work now submitted to the public. CONTENTS CHAPTER I. ^2 PHTMCAt PHENOMENA OF VEGETATION.— VEGETABLE PBTSIOLOOT ^ n. — Chemical phenomena of Tegetation 25 Germination 26 Germination of wheat 29 Continued germination of peas 30 Continued germination of wheat 31 ^ III.— Evolution and growth of plants 33 Experiment I.— Growth of Red Clover daring three months 44 Experiment II.— Growth of peas 45 Experiment III.— Growth of wheat 46 Experiment IV. — Growth of clover •• 47 Experiment v.— Vegetation of oats 48 ^ IV. — Of the inorganic matters contained in plants— their origin — of the chemical nature of sap 52 Quantity of ashes contained in the different parts of vegetables, according to M. de Saussure 53 Composition of the substances found by M. de Saussure 55 Alkaline salts and insoluble substances contained in ashes 56 Alkaline salts and insoluble substances of ashes, according to M. Berthier. • 57 Composition of the ashes of several plants analyzed by M. Berthier 59 Sap of the Bambusa Ouaduas 68 Sap of the banana plant (Musa Paradisica) 68 Milky saps 69 Sap of the papaw-tree (Carica Papaya) 69 Sap of the cow-tree 69 Milky sap of the Hura Crepitans (Ajuapar) 71 Milky sap of the poppy (Opium) 71 Milk of the Plumeria Americana 72 Sap of the caoutchouc-tree 72 Gummy and resinous saps 73 Saccharine saps 74 CHAPTER n. Or THE CHEMICAL CONSTITTTTION OF VEGETABLE SUBSTANCES 75 % I. — Quarternary azotized principles of vegetables 76 Composition of legumine obtained from diffep^nt seeds 78 % II. — Proximate principles with a ternary composition : of starch 80 Innline 87 Of woody matter and cellular tissue 87 Density of different kinds of wood, according to Brisson 90 Of sugar 114 Beet-root sugar 121 Palm sugar 126 Grape sugar 126 Saccharine principles not fermentai)le 128 Gum 129 Vegetable jelly : pectine and pectic acid 129 10 CONTENTS. Put Of vegetable acids 131 Of the vegetable alkalies 131 Of fatty substances 134 Of essential oils • 141 Of resin 142 Caoutchouc 143 Vegetable wax 143 Chlorophylle 145 Of coloring matters 145 ( ilL — Composition of the different parts of plants 154 Roots and tubers 154 Barks 161 Leaves 164 Seeds 168 Fleshy or pulpy fruits 189 CHAPTER III. Or THX SACCHARINE rRUITS, JUICES, AND INrUSIONS USED IN THE PREPARATION or FERKENTED AND SPIRITUODS LIQUORS •• • 193 CHAPTER IV. Or SOILS 200 Classification of soils 223 CHAPTER V. Or MANURES 237 Excretions of the horse 267 Excretions of the cow 268 Excretions of the pig 268 Animal excrements 285 Table of the comparative value of manures, deduced frjm analyses made by Messrs. Payen and Boussingault • 297 CHAPTER VI. Or MINERAL MANURES OR STIMULANTS • 303 Calcareous manures 303 Of alkaline salts 316 Growth of sainfoin upon soils gypsed and ungypsed in 1792, 1793, and 1794. 321 Comparative growths of white clover, g>'psed and ungypsed, by Mr. Smith. 322 Experinjent with field-beet or mangel-wurzel, opening ine rotation with manured soil, 1842 327 Mineral substances contained in the crop 32C Of ammoniacal salts 33i. Of water 336 CHAPTER VII. Ur THE ROTATION or CROPS 341 ( I.— Of the organic matter of mauOre and of crops 341 Potatoes 348 Wheat 349 Wheat-straw 349 Red clover 349 Turnips 350 Oats 350 Oat-straw 351 Field -beet or mangel-wurzel 351 Rye 351 Rye-straw 351 White peas 358 Feastraw - • 35t CONTENTS. II Page Jerasalem potato or artichoke 3.52 Dried stems of Jerusalem artichokes 352 Table of the proportions of water contained in different substances 353 Composition (»f the same substances dried in vacuo at 230° F 353 Relation of manures to crops 354 Desiccation of half-made or half-decayed manure 354 Experiment I 354 Experiment II 354 Experiment HI 354 Analyses of half-made manures 354 Composition of the manures analyzed 355 Rotation course, No. 1 357 Rotation course, No. 2 357 Rotation course, No. 3 358 Rotation course, No. 4 358 Continuous Jerusalem potato crop. No. 5 358 Quatrennial rotation, adopted by M. Crud, No. 6 358 Summary 359 J ^l -Of the residues of different crops 360 Potato tops or hauni 361 Leaves of field-beet or mangel-wurzel 361 Composition of dry leaves 361 Wheat stubble 362 Clover roots 362 Composition of the roots 362 Oat stubble 362 Summary of the foregoing results 363 § 111. — Of the inoi^anic substances of manures and crops 364 Composition of the ashes proceeding from the plants grown at Bechelbronn 366 Mineral substances taken up from the soil by the various crops grown at Bechelbronn upon one acre 366 Table of the mineral matters of the crops and manures in the course of a rotation 369 CHAPTER VIII. Or THE VeKDINO of the animals BELONOING to ▲ FARM ; AND OP THE IMME- DIATE PRINCIPLES OF ANIMAL ORIGIN 375 41. — Origin of animal principles ., 375 Of the food of animals and feeding 38(? Experiments on the maintenance of horses 400 Experiment 1 400 Experiment II. — Introduction of Jerusalem potatoes into the ration 401 Experiment III. — Ration of hay and potatoes 401 Experiment IV. — Substitution of oats and straw for a portion of the hay 402 Experj,ment V. — Potatoes substituted for a portion of the hay 403 Experiment VI. — Jerusalem potato for a portion of the hay 403 Experiment VII. — Introduction of field-beet or mangel-wurzel into the ration 403 Experiment VIII. — Introduction of the Swedish turnip into the ration and replacing a portion of the hay 404 Experiment IX.— Introduction of carrots into the ration 405 Experiment X. — Boiled rye as a substitute for oats 405 Table of the nutritive equivalents of difierent kinds of forage 407 ^ n.— Of the inorganic constituents of food 410 ^ m. — Of the fatty constituents of forage ; considerations on fattening 416 CHAPTER IX. Or the economy of the animals attached to a FARM. — OF STOCK IN GENERAL, AND ITS RELATIONS WITH THE PRODUCTION OF MANURE 428 $ I —Homed cattle 430 Table of milch-kine three years of age and upwards 440 12 CONTENTS. $U.--Milch-kine .^48 Experiment I. — Two hundred days after calving 447 Experiment II.— Two hundred and seven days after calving 448 Experiment III. — Tw^o hundred and fifteen days after calving 448 Experiment IV. — Two hundred and twenty-nine days after calving 448 Experiment V. — Two hundred and forty days after calving 449 Experiment VI. Two hundred and seventy days after calving 449 Experiment VII. — Two hundred and ninety days after calving 449 Experiment Vin 449 Experiment IX. — Thirty-five days after calving 450 Second Series. Experiment I. — Begun one hundred and seventy-six days after the calving 450 Experiment II. — One hundred aid eighty-two days after the calving 450 Experiment III. — One hundred and ninety-three days after the calving 450 Experiment IV. — Two hundred and four days after the calving 451 $ HI.— Fattening of cattle 452 $ IV.— Of horses 460 $V.— Of hogs 464 $ VI. — Of the production of manure 471 CHAPTER X. Mbtcorolooical considerations 475 $ I.— Temperature 475 $ II. — Decrease of temperature in the superior strata of the atmosphere 478 $ in. — Meteorological circumstances under which certain plants grow in different climates 481 Cultivation of wheat, Alsace *. 482 Cultivation of wheat in America 483 Intertropical region 483 Cultivation of barley 483 Cultivation of maize or Indian com 484 Cultivation of the potato 484 Cultivation of the indigo plant ■.... 485 ^ IV. — Cooling through the night; dew, rain 486 I V. — On the influence of agricultural labors on the climate of a country in lessen- ing streams, &c < 495 RURAL ECONOMY, CHAPTER I. PHYSICAL PHENOMENA OF VEGETATION. VEGETABLE PHYSIOLOGY. The operations of agriculture having- for their object the produc- tion of plants which are either essential as food, or useful in the arts and industrial processes of man, it is well to begin with a summary view of the principal organs of which vegetables are composed ; and by the instrumentality of which, under certain influences which we shall seek to appreciate, all the phenomena of their existence are manifested. Plants fixed in the soil by their roots, live in the atmosphere by the concurrence of their green parts under the combined actions of light, heat, and moisture. We shall by and by ascertain at the cost of what elements, and under what conditions, their growth and com- plete development are accomplished. The seed, which is the final result of vegetable life, and of which the aim is the reproduction and multiplication of the species, should first receive our attention. The seed is, if we may so speak, the starting point of all husbandry ; it is with very few exceptions the first point on which the industry of the farmer exerts itself. Nature, to ensure the preservation of seeds, has had recourse to infinite care and foresight, which are in some measure an assurance of their importance. The seed is often placed in the middle of an abundant fleshy pulp, which serves to afford it nourishment or ma- nure at the time of its future development. Sometimes, as in legu- minous plants, it is lodged between thick and tough membranes, or is covered with hard but flexible scales, as in the gramineous plants ; or again it is enveloped in a woody substance of extreme hardness, as in stone fruits. Nature does not show herself less provident in furnishing means for scattering seeds, and propagating vegetable species at great dis- tances. There are, indeed, seeds which, furnished with light silky plumes or wings, flutter in the air, and are transported afar by the winds. Others, by means of a viscous, hard, impermeable envelope, float on rivers, and descend their courses without suffering the slight- est change, or losing their germinating power. There are seeds again of a sufficiently coherent texture to resist the digestive action 2 14 , VEGETABLE PHYSIOLOGY. of the Stomachs of animals that feed on the fruits which contain them, and which are consequently often found deposited at great distances from the plant which produced them ; they are thus fre- quently dropped to germinate and flourish at the tops of the steepest mountains. By these admirable provisions of nature, then, the air, the water, and even animals themselves become the vehicles by which the migration of various vegetable species over the surface of the globe is effected. We distinguish in seeds the kernel, and the integument which covers or encloses it. In the kernel, the embryo exists, which, as its name indicate^, is destined to reproduce the plant of which the seed is the issue. The embryo is formed of several essential parts : — 1st. of the radicle ; 2d. of the gemmule, plumule, or rudiment of the stem, which by its extension engenders the organs that are to vegetate above the ground ; 3d. of cotyledons, which form the great- est portion of the kernel, aad which are destined to support the plant during the first periods of its existence. In most cases, the cotylejjons are formed of two lobes which sepa- rate during the act of germination. The plumule presents itself under the form of a little white point which penetrates into the in- terior of botn cotyledons. The radicle is of a slightly conical shape, and is first seen when it projects externally from the seed. The seeds of gramineous plants do not separate into two parts at the commencement of their independent existence. They are, in fact, seeds which have but a single cotyledon. As plants which spring from seeds of one or of more cotyledons present capital differences in their organization at large, and mode of development, botanists have established two grand divisions among them — into monocotyledonous vegetables, and dicotyledonous or polycotyledonous vegetables. When the seed is gathered in its state of perfect maturity it is •completely inert, its vital functions are wholly suspended, and it may be kept often for a very long time without being made to grow. The length of time during which seeds may be kept, however, varies extremely, according to the species. There are plants, for instance, the seeds of which preserve for an indefinite period 'heir germinative power ; there are others, on the contrary, which lose it very speedily. From various observations which appear to deserve every con fidence, the seeds — Of Tobacco have germinated after having been keptfor 10 yean. "Stramonium 25 " (DuhameL) " the Sensitive plant 60 " "Wheat 100 " (Pliny.) "Wheat 10 " (Duhimel.) "Melons 41 " (Frievi^ald.) "Cucumbers 17 " (Roger Galen.) "Haricots 33 " "Idem.... 100 " (Gerardin.) "Rape 17 " (Leftbure.) "Rye 140 " (Home.) The seeds of the coffee plant arc perhaps those which lose the SEEDS. . 15 property of geiwiinating most speedily ; planters are well aware that they must be sown almost immediately after they ate taken from the bush. Oleaginous seeds are generally preserved with great dit-, ficulty ; so also are those of rubiaceous plants, of the- laurels, myr- tles, &c.* ' In practical agriculture there is always much advantage, and additional security, in sowing the most recent seed, even of kinds wbitjh are known to be the longest lived. It frequently happens, even after a very short time, that a certain proportion of these seeds die : they have, perhaps, not been gathered under circumstances favorable to their complete preservation. It is, therefore, only when he is compelled to do so, that the farmer trusts wheat to the ground which has been gathered in former years ; and experience has proved that in using such seed, it is necessary to increase very con- siderably the quantity sown. The inactivity of the seed ceases so soon as it is brought into contact with water and the air under the influence of a sufficient temperature. Sown in moist jsarth, a seedtabsorbs water, and swells considerably ; the pellicle which covers it becomes distended, and ends by bursting ; the radicle and the plumule appear, and become more and more distinct ; the root penetrates the ground ; the plu- mule by and by grows into a stalk which gets greener and greener, increases rapidly, and augments the number of its leaves, so that the young plant acquires vigor every day. At a certain period, flowers appear ; and these are succeeded by fruit, the final term of which is the maturity of the seed. The phenomena of vegetation then cease. The whole of the organs of annual plants now wither and die ; the work of reproduction, of multiplication, is accomplished. Thus begins and ends the existence of the plants which are the usual subjects of our husbandry. With regard to biennial plants and trees, which possess more than this ephemeral existence, things pass differently. The plant vege- tates so long as the temperature of the atmosphere and moisture of the soil are favorable to it : during the cold season the leaves fall, and the growth is suspended ; but the plant revives anew on the return of spring. Those vegetables, the stem of which is generally ligneous, and whose roots penetrate deeply into the ground, have a power of resisting cold, and brave the rigors of the winter. In these latitudes, the renewal of the vegetation of trees in the spring presents an obvious analogy to the process of germination : the evo- lution of the buds represents this process very closely ; and the phe- nomena at large, which we observe in annual plants, are for the major part reproduced • — there is increase of size in the stem and root, sprouting of leaves, inflorescence, ripening of fruits, production of seeds, and then suspension of function. In the tropics, where the temperature is nearly uniform through- out the year, vegetation goes on without interruption ; it only varies in its vigor, and this is determined by the abundance or the paucity ♦ DecandoUe, Physiology, page 622 18 VEGETABLE PHYSIOLOGY. of rains and dews. The leaves which have conciirred in the pro duction of the fruit, and in perfecting the seed, fall as it were ex- hausted ; but they are soon replaced, and their fall is only perceived by their presence on the surface of the ground. The perfect plant, therefore, whether it be studied among annuals, or among trees that endure for a century, has analogous organs, destined to fulfil the same functions, to conduce to the same end — the reproduction of the seed. These organs, which we shall study in succession, are, 1st. The roots ; 2d. The stem ; 3d. The leaves ; 4th. The appendages of the fructification. When we follow the progress of a seed set in a proper soil, we observe that from their very first appearance the roots seek or tend towards the interior of the earth ; the plumule, or young stem, on the contrary, takes a direction diametrically opposite ; it grows verti- cally and seeks the air. The lateral shoots in herbaceous plants, and the young branches of shrubs, form various angles with the principal stem or trunk. The first tendency of the branches is to rise vertically ; but as they gain length and weight, they bend more or less downward, yielding to the power of gravitation. Mr. Knight showed, by a series of ingenious experiments, that the direction taken by the roots and branches is mainly due to this force. This able observer arranged a wheel of wood in such a way that he could make it turn with different velocities in planes variously inclined to the horizon. The wheel, which was kept in motion by a stream of water, could be made to revolve vertically or horizon- tally at will. A number of beans were planted upon the circumference of the wheel, in circumstances known to be indispensable to their germi- nation and growth. By giving the wheel a sufficient -velocity, it was easy to make the centrifugal force greater than the centripetal force. In Mr. Knight's apparatus, this happened when the wheel in the vertical plane performed one hundred and fifty revolutions in a minute. The whole of the radicles were then seen to turn theii suckers beyond the circumference in lines which were prolonga- tions of the radii of the wheel, and their growth took place in planes perpendicular to its axis. The stems took a completely opposite direction, and after a time their summits attained the centre or axis of the wheel. In causing the wheel to revolve in a horizontal plane, the same effects were still observed, when the rapidity of rotation was suffi- cient to annul the action of terrestrial gravitation. But when the motion was so far diminished, as merely to modify or to lessen the force of attraction, without entirely annulling it, the plant took a course comprised in a plane which formed a certain angle with the circum- ference of the wheel. With a certain velocity, the roots were in- clined 10° below the horizontal plane in which the wheel moved, and the stems then formed an angle of the same magnitude above the same plane. The angle of deviation formed in this position of the wheel waa always smaller in proportion as the raj»idity of rotation was greater. STEMS. 17 fow^ since gravitation influences the position which vegetables present, as these beautiful experiments of Mr. Knight demonstrate, a practical conclusion which seems to follow from the fact is this, that the number of plants which may be placed upon a certain ex- tent of soil, does not depend solely on the extent of surface ; and that the power of production of a field which is very much sloped, does not exceed its horizontal projection. With regard to creeping plants, and with reference to meadows, it is clear that this principle is not rigorously exact : but in so far as plants with isolated stems are concerned, many agricultural philosophers, and among the num- ber Davy,* have admitted it as perfectly indisputable. This opinion, as M. Corrardf has judiciously observed, is founded on the geome- trical jrinciple, which in itself is perfectly true, that an inclined plane cannot be cut by a greater number of vertical perpendiculars of a determinate thickness, than the horizontal plane which serves it for a base. Thus, says Corrard, as buildings which rest on an in- clined plane are raised perpendicularly to the horizon, it has been concluded that an inclined plane can hold no larger an extent of building than would the horizontal plane which it covers ; so that inclinations of surface do not actually add to the extent of towns. It is further a matter of absolute certainty, that as rain falls vertically, the quantity of water collected upon the eaves of a house is precisely the same as that which would be gauged in the same place upon a horizontal surface, equal to that of the building. But we should very much deceive ourselves, adds Corrard, if upon the same prin- ciple we inferred that on the surface of an inclined plane we could not have a tree more than upon the much smaller horizontal plane which serves as its base. For although plants grow perpendicularly to the horizon, and may in this respect be considered as so many vertical perpendiculars or laminae, still, from circumstances which are peculiar to them, we cannot here apply with propriety the geometrical principle in ques- tion. Because, to make the application exact, it were necessary to suppose that plants required no space around them to thrive, and that the whole surface of the ground might be covered with their stems without any space being left between them, and without this prox- imity interfering with their growth and vigor. But such a supposition is impossible, inasmuch as it is absolutely necessary that plants should have a certain amount of space, both in the ground and in the atmosphere, in which to extend their roots and stretch forth their branches. Supposing, therefore, the inclined plane to be of considerably greater extent than the horizontal plane which supports it, it will necessarily aflford to a larger number of plants, the spaces which their roots require for their growth and nourishment. In other words, upon the inclined surface there will be a larger quantity of vegetable earth, and more of the nutritious iuices favorable to vegetation ; and for these reasons the space which ♦ Agricultural Chemistry, vol. i. t B. Corrard, Verhandel. von der Maatsch. te Haarlem, vol. xv. p. 308. 2* 18 VEGETABLE PHYSIOLOGY. must always exist between plants may be less than on the horizontal plane. Consequently, all the conditions necessary to fertility being assumed as equal, the inclined plane will be capable of supporting a larger number of vegetables having vertical stems than the hori- zontal plane. The organization of different parts of plants, so worthy in all respects of exercising the sagacity of physiologists, need not be made a subject of minu ;e research in this place. Generalities suf- fice in our agricultural science. This organization, however com- plex it is in appearance, is probably much more simple than is usually believed : we might perchance find the proof of this sim- plicity in the readiness with which organs, the most dissimilar in their external forms and so different in their functions, undergo modification and transformation one into another, it might almost be said at the will of the observer. Thus tubers, those fleshy amyla- ceous bodies, which accumulate on the subterranean stems of cer- tain vegetables, such as the potato, give birth to a plant which differs in nothing from that which would arise from the seed of the same vegetable. Certain leaves, — those of the orange, of the ficus elas- tica, &c., will do the same. Woody stems, branches severed from the tree and planted in the ground, produce roots and become inde- pendent plants. If the branches of certain shrubs be buried, and their roots be exposed to the air, these last are soon seen covered with buds and leaves ; while the buried branches acquire a fibrous capillary structure, and in no great length of time they both present the appearance and exercise the functions of roots. This singular mutation readily succeeds with the willow, and it was upon this plant that the English vegetable physiologist, Woodward, effected it for the first time.* The intimate structure of the roots, trunk, and branches, present considerable similarity. Divided perpendicularly to their longitudinal axis, three different zones, so dissimilar that it is impossible to con- found them, are discovered in the different concentric layers which make up their mass ; these are the bark, the wood, and the pith. A more careful examination shows that each of these zones may be further subdivided. The exterior of the bark is covered by an extremely thin, nearly transparent and porous pellicle, formed by an assemblage of little adherent scales ; this is the cuticle, or epidermis, which encloses the entire vegetable. As it is extensible within certain narrow limits only, it gives way and cracks in proportion as the body of the tree increases in size. The pores of the epidermis are minute openings or mouths which communicate with the exterior by an oval orifice, surrounded by a kind of contractile margin. It has been remarked ihat moisture tends to close these pores, and that drought and the action of solar light tend on the contrary to make them open. The chemical nature of the cuticle which covers the bark appears to in- dicate that it is destined to defend the plant agaiast the too direct * DaTy'f AKricoltoral Chemiitry BARK. 1^ action of external influences. In certain trees, the cuticle is covered with wax or resin. The most remarkable example of this kind which can be quoted, is that of the wax-tree (ceroxilon andicola) which grows abundantly upon the slopes of the Andes. This tree, (a palm,) which attains a height of between 130 and 164 English feet, is covered over the whole surface of its trunk with a mixture of wax and resin.* In gramineous plants, the epidermis is almost entirely formed of silica. The bark of the birch-tree is covered with a pellicle of an unctuous nature, capable under the agency of nitric acid of yielding a peculiar suberic (the) acid.f After the epidermis, in going from the circumference towards the centre, a layer of cellular tissue appears, which is designated by many physiologists under the name of the herbaceous envelope. In the cork oak, the cork represents the tissue by which the liber or true bark is covered, an organ formed of a vascular tissue, which with care can be separated into numerous very thin flakes or layers, which have been aptly compared to the leaves of a book. The origin of the liber, or bark, is found in the most central part of the trunk ; it is the result of the exudation of the woody parts, as Duhamel, with the same wonderful sagacity which characterizes all his works, has proved. Having cut away a portion of the bark of a tree in full vigor, and taken care to preserve the incision from contact with the air, he perceived that from the surface of the wood laid bare, and the edges of the bark adhering to it, a viscous mat- ter exudes, which accumulates, acquires consistency, and ends by becoming cellular, thus regenerating the liber which had been taken away. Grew called this viscous secretion cambium, a title which it still retains. It is now generally admitted that cambium proceeds from the descending sap. The liber is a very important organ in vegetables ; we know for instance that it is necessary for the success of a graft that its liber penetrate or be penetrated by that of the tree on which it is grafted. The woody layers are situated under the liber. Those which are at the greatest distance from the axis of the trunk, although they present the fibrous structure, and the principal characteristics of the woody tissue, still differ from it in being less hard and less tena- cious ; this zone, which at the first glance is easily distinguished from the wood properly so called, is the alburnum, the soft or false wood. Its fibres are much looser, and its color paler than that of the wood beneath it, the difference of shade being particularly ap- parent in the dye and deeply colored woods. The alburnum becomes harder and tougher with age, and passes into the woody tissue, the duramen or hard wood, properly so called. The wood begins where the alburnum terminates, and reaches to the centre, to the pith or medullary canal. In dicotyledonous trees, a certain quantity of wood is formed •_ Boussingault, sur le Palmier a cire. Annales ^ Climie et de FhysiquA 3* iitie^ the observations of M. Chevreul. t 59, p. 19. t ftOBt 80 VEGETABLE PHYSIOLOGY. during vegetation at the expense of the alburnum ; while on the opposite side towards the bark, the alburnum increases in about an equal proportion : so that in our climates, the alburnum grows each year from a new concentric layer ; but in tropical countries, where the dicotyledonous trees vegetate without interruption, the annual concentric layers are scarcely perceptible. To prove the conver- sion of alburnum into woody tissue, Duhamel inserted a metallic wire into it in several places. At the end of a few years he found that the wire had become engaged in the proper woody layers. The most central zone of the trunk or stem is traversed by the medullary canal or sheath, which is usually filled with the pith, a diaphanous spongy matter, consisting almost entirely of cellular tissue. The pith sends ramifications towards the external parts of the trunk. Its use is not exactly determined ; and notwithstanding the high purposes ascribed to it by some physiologists, we have many reasons for believing that its functions are not of great importance. Experiment proves, in fact, that the pith may be removed from young trees without killing them, without even stopping their growth. One of the least unquestionable offices assigned to the pith, is that of its being a reservoir for moisture with which it sup- plies the plant in times of drought, and when the ground does not furnish a sufficient quantity of water. The internal structure and progressive development of the stem of monocotyledonous plants differ essentially from those which we have just been describing in connection with dicotyledonous plants. If a perpendicular transverse section of the trunk of a palm-tree be examined, the same arrangement of zones which is observed in the dicotyledonous plants of our climates will not be perceived. The regions of the outer bark, of the liber or true bark, of the al- burnum, and of the wood, forming so many concentric circles round a canal which is their common centre, are no longer distinguishable. The trunk of the palm-tree presents a more homogeneous appearance. The pith is disposed through the whole substance of the stem, and the woody tissue, presenting a fibrous texture disposed longitudinal- ly, is found intimately mixed, or felted, as it were, with the medul- lary substance. The bark, if there be any, is always very indis- tinct ; sometimes reduced to a simple epidermis, it is with difficulty distinguished from other parts of the trunk. In the beginning, and when it first appears above the ground, a palm-tree puts forth a sys- tem of leaves, the adhering extremities of which are attached in the same plane, and usually surround the neck of the root. At the second shoot, a system similar to the preceding one appears, which throws off the outside leaves, and interrupts their power of vege- tating. These leaves wither, bend towards the earth and fall off, leaving a projecting circular ring on the stem, the only vestige of their existence. The same phenomenon takes place periodically. In the centre of the crown of leaves or branches, which terminates tlie palm-tree plant, a bud appears which is at first small and blanciv FALMS. 9X ed ;* but soon displays the most vigorous powers of vegetation. Its growth, inflorescence, and progress towards maturity are indicated by the decay and fall of the leaves which had hitherto protected it. The age of a palnn-tree, or rather the number of times that it has fructified, or become crowned with fresh leaves, is calculated by the number of woody circles which are found marked on the stem. Its power of lasting seems to have no other limits than the resistance which the base offers to the weight it supports. In these colossal trees, a sensible diminution in the diameter of the stem is often per- ceptible towards the top, and in most of the species ^t 's a fact equally well proved, that the fruit decreases in quantity when they have attained a certain epoch of their existence. In the cocoa-nut tree {lodicen. cncus nucifera) the period of this decrease sh'jws itself at about the age of thirty years, although this tree continues to bear for nearly a century. f The leaves, the forms of which are so various, present however the greatest analogy in their organization : the green membranous substance of which they are almost entirely composed, is an exten- sion of the parenchyma ; the envelope which covers them answers to the epidermis. It is in the leaves that the sap is subjected to the action of the atmosphere ; it is there concentrated and peculiarly modified. Ac- cording to the position of leaves upon the plant, their under sides, or those turned towards the ground, are distinguished from their upper sides which meet the light from above. The upper side of the leaf is covered with a thick and frequently shining epidermis; this epidermis is sometimes endued with a sub- stance rich in silicious matter, as in rushes. In the Steppes of South America I observed a tree, called Chapparal, the leaves of which are S(» highly silicious, that they are used for polishing metals. Generally speaking, the covering of the upfier surface of leaves is a matter which is something of the nature of wax or resin. The epidermis which covers the lower surface is formed in most cases r>f a very thin, rough membrane, full of cavities and frequently cov- ered with hairs or down. The appearance and position of the leaves are not the same du- ring the day and night. In the dark, simple leaves incline to fold up; in compound leaves, as in those of the acacia and sensitive plant, the same thing is still more marked ; the effect can even be produced at will. If during the day a sensitive plant is placed in a dark room, the leaves immediately close ; on lighting the room even with candles, they open again as if under the influence of the solar light ;| Linnaeus, who first paid attention to this class of phenome- na, admits that plants in the absence of light experience a sort of sleep. * This bvid, in certain species of palm-trees, is sought after as food, and is often spoken of as the cabbage of the pHJni-tree. t Information communicated by Mr. Codazzi. The trunic of certain species of palm- trees shows an enlargement towards the middle of its height, as in the podma Hrrigout vfChoco. X Observation of M. de CandoUe. 22 VEGETABLE PHYSIOLOGY. The fiower is the forerunner of the fruit, the fruit is the medium in the heart of which the seed is developed. The organs which constitute the flower are the calyx and the corolla, destined to sup- port, nourish, and protect the pistil and the stamina, which are the essential parts ; the calyx is a green membrane which surrounds the corolla, and in certain flowers replaces it. 1 he corolla is monopetalous or poly petalous according as it is com- posed of one or of several pieces. The stamens occupy the interioi of the corolla ; they aie terminated by summits of a vascular tex- ture ; these are the anthers ; the powder which covers and sticks slightly to them is designated under the name of pollen. The pistil placed in the middle of the flower is composed of the ovary, the style, and the stigma. Tiie ovary encloses the germ, the embryo of the seed ; but this embryo is only developed by the action of the pollen. The style is in some sort the tubular prolongation of the ovary ; it supports the stigma, which is the glandular part that receives the fecundating influence of the pollen. From what has now been said, the pistil may be considered as the female organ of the flower, the stamens as the male organs. Many flowers combine the organs of the two sexes. These flow- ers are hermaphrodites ; those which only contain one organ, are called unisexual. Both male and female flowers are produced to- gether on certain plants ; in others, the flowers are all only of one sex, male or female. Polygamous plants are those which show a union of male and female flowers, or which have hermaphrodite flowers on the same stem. In some flowers, the sexual organs at the period of fecundation acquire the property of motion, so as to facilitate this grand act The stamens, for example, are seen in certain plants to approach the stigma, to deposite their pollen on it, and then to withdraw. It occasionally happens again that stamens, which are at first naturally in a position inclined with reference to the pistil, become suddenly straightened in such a A-ay as to cast their pollen on the female or- gan, after which they resume their original position. In certain flowers a very consideiable evolution of caloric has been perceived on the approach of the period of fecundation. In some arums, for example, the temperature has been observed to rise to 40° and even 50° cent. (104° to 122° Fahr.) It is probable that this phenomenon is quite general, and that it only varies in point of intensity. Fecundation accomplished, the office of the flower is at an end. It collapses, withers, and dies. But the impregnated ovary enlarges by degrees, until it has attained maturity, when it presents two dis- tinct parts, which by their union con»pose the fruit : these parts are the pericarp, and the seed — the husk or shell and the grain. The pericarp always surrounds the seed ; but it sometimes happens that it is so thin and delicate that it blends with the seed. The germination of seeds, the evolution of new plants, is only accomplished under certain physical conditions which demand oair consideration. ROOTS, SAP. 28 We have already said incidentally, that in order that a seed may germinate, it must be in contact with moisture, have communication with the air, and be under the influence of a certain temperature. The same conditions continue to be indispensable after the seed has sprung, and the plant has been organized ; and in addition the access of light is now imperative. Roots seek in the soil the moisture which is requisite to vivify the whole vegetable. These organs are terminated by hair-like fibres of extreme delicacy, and having sprngioles at their extremities : it is by these spongioit-s that absorption is effected. Tlie following experiment is sufficient to prove that this is l[ie case : let such a plant as a turnip be p Aced with ilie hair-like extremities of its root plunged in water, and the plant will continue to live, although almost the whole body of the root is in the air ; let things be now so ar- ranged that the hair-like filaments of the root are not in the water, but that the bulb or body of the plant is so : the leaves will soon droop and wither. The force which brings into play the suction power of the roots, resides in almost every part of the plant : thus a root deprived of its spongioles, a stem, a branch, and a leaf, exert this suction power when plunged in water. But the absorption eflfected in this way has a limit, and we soon discover the necessity of making fresh sections of the extremities, which have no power of renovation like the filaments furnished with spongioles, which terminate a root. We are still ignorant of the cause which produces the ascent of liquids in vegetables, and which carries them to the remotest leaves in spite as it were of the laws of hydrostatics. We readily conceive how the spongioles of the roots, surrounded by earth abundantly charged with moisture, should imbibe by the simple effect of poro- sity. We can also understand how, after having been modified by the spongioles, the water and the principles contained in it should be transformed into sap ; but the porosity of the extremities of the roots, and the chemical modification effected by the spongioles upon the fluid imbibed, give no kind of explanation of the rapid ascent of the sap. The force which occasions this rise is very considerable, as was demonstrated by Dr. Stephen Hales in a series of ingenious experiments more than a century ago. Hales adapted a tube bent at a right angle and filled with water, to the extremity of the root of a pear-tree, the point of which had been cut off; the extremity of the tube opposite to that which was connected with the root dipped into a bath -of mercury. In a few minutes a portion of the water contained in the tube was absorbed, and the mercury rose above the surface of the bath to the extent of eight inches. In the beginning of April, Hales cut oflf a vine stem at the distance of thirty-three inches from the ground. The stem had no lateral branches, and its cut surface, which was nearly cir- cular, had a diameter of ^ths of an inch. To this section, he adapt- ed a reversed syphon : and things being so disposed, he poured in a quantity of mercury, which after a time, and from the effect of the pressure exerted by the sap as it escaped, rose in one of the armi 24 VEGETABLE PHYSIOLOGY. of the syphon, and remained stationary at the height of thirty-eigUt inches above its original level. This column of mercury, it is obvious, represents a pressure very much greater than that of oar atmosphere. The ascent of the sap in trees takes place by the woody layers. It is easy to obtain conviction of this by making a plant absorb a watery solution of cochineal. By making sections in the stem at different heights, we can readily trace the colored liquid in its pro- gress; it is undoubtedly the course which the natural sap would nave taken. We see no indication of the coloring matter in the pith nor in the bark, the woody tissue alone is colored, sometimes en- tirely, but more generally in its younger parts only. The dyeing which results from this injection of the wood is in lines, and parallel with the axis of the trunk, like the woody fibres themselves ; but in some cases the sap may deviate from the rectilinear course. Hales showed this by the following experiment : upon a tree he made four notches, one above the other ; each notch occupied one quarter of the trunk and reached to its centre. In this way the whole of the woody fibres were cut through at different heights, so that to continue its ascent the sap must necessarily experience a series of lateral deviation, which in fact took place. The ascending sap of vegetables, as it has hitherto been procured for examination, is an extremely watery fluid, holding in solution very small quantities of divers saline and organic substances. Having attained the leaves, the sap there undergoes modification, and becomes concentrated by losing water. It at the same time experiences, through the agency of the atmospheric air, under the influence of light, a great modification in its constitution. Thus elaborated, the sap takes a descending course ; following the liher^ it retrogrades towards the soil, and therefore performs a kind of cir- culation in its passage through the plant. The descending course of the sap is demonstrated by throwing a ligature round the trunk of a tree ; after a time there is formed, above the part that is tied, an enlargement which is owing to the accumulation of the principles of the sap ; but below it the tree experiences no increase. The descending course of the elaborated sap is no effect of simple gravi- ty ; because, if the ligature be thrown around a pendent branch, the enlargement still forms between the ligature and the free extremity of the branch. The descending sap passing through the cortical layers must necessarily contribute to their formation ; and it is almost certain, as appears from the capital experiment of Duhamel, that it is the cambium which is changed into liber, and so concurs in the growth of trees. The concentration of the ascending sap, which occurs during its passage through the leaves, by the simple effect of evaporation, is the phenomenon which is spoken of under the name of the exhalation of plants : this exhalation of plants, it is easily understood, is favored by a high temperature, dryness, and motion of the air. In favorable circumstances, the water escapes in the state of vapor. Hales compared the watery exhalation of Dlants to the perspiration of animals, and made many experiments EXHALATION. 25 to ascertain the quantity of watery vapor which they usually throw off. Hales planted a sun-flower in an air-tight vessel, the top of which was sealed hermetically by a leaden cover. This cover was pierced by two holes : one for the passage of the stem of the plant, the other for the introduction of the water necessary to its growth. For a fortnight the apparatus was regularly wei.'rhed, and our ingenious experimenter found that the green parts of the sun-flower threw off on an average about twenty ounces of water in twelve hours of Ihc day. The evaporation was always increased during dry and warm weather ; moist air lessened it ; during the night season, the evapo- ration was sometimes no more than three ounces, and it occasional- ly happened that it was nil. Vegetable life appears to be intimately connected with the pheno- menon of evaporation. From the inquiries which I have myself undertaken on this subject, so well deserving the attention of obser- vers, it would appear that a plant grows only when it transpires, and that in hindering this transpiration, we in fact arrest vegetation. We now associate with the phenomenon of exhalation the source or accumulation of certain substances which are met with in con- siderable quantity in the organization of plants, although scarcely a trace of them can be detected in the water with which they are sup- plied. The water evaporating, leaves these substances behind ; and as the mass of liquid imbibed by the roots and exhaled by the green parts is very considerable, it is easy to conceive how they should finally come to be present in rather large quantity. A portion of the water which a plant in full v\gor absorbs, must necessarily enter into its constitution ; the water exhaled by the leaves, therefore, cannot equal the whole of that which has been absorbed by the roots. Sennebier endeavored to ascertain the rela- tion which exists between the absorption and the exhalation, and ho found in the particular case which he observed, that about ^ of the water absorbed was fixed, and became a constituent part of the vegetable. § II.— CHEMICAL PHENOMENA OF VEGETATION. The chemical phenomena of vegetation are accomplished by the concurrence of the elements of the atmosphere, of water, and of certain organic substances which exist as constituents of the soil. The action of the atmosphere upon plants presents two phases perfectly distinct from one another; germination, and vegeta'ion properly so called, which last comprises the development, the grov/th| and the multiplication of species. 3 26 CHEMICAL PHENOMENA OF VEGETATION. GERMINATION. We have ascertained that a seed, considered with reference to its organization, consists, 1st. of an embryo which includes the germs of the root and of the stem; and 2d. of the cotyledon, or cotyledons. Considered with reference to their chemical compositions, seeds ex- hibit a certain similarity of constitution. They contain : 1st. starch and gum ; 2d. a highly azotized matter analogous to the caseum of milk and animal albumen ; this is the matter which is commonly and very improperly designated under the name of gluten, and of vegeta- ble albumen ; 3d. a fatty or oily matter, rich in carbon and hydrogen. Seeds contain either fixed oils, such as hemp-seed, rape-seed, &c., or volatile oils, as aniseed, cmnmin-seed, &c. The different prin- ciples which are associated in the seeds vary considerably in their relative proportions : they also vary slightly in their nature. One seed, that of the colewort, for example, will contain more than forty per cent, of its weight of oily matter, while another, such as wheat, will only contain a few hundredths. Oats may contain ten or twelve per cent, of caseum or gluten ; in certain varieties of wheat, analysis indicates a much larger quantity. The proportions of starch, gum, sugar, or mucilage do not vary less. It almost always hap- pens that these different substances are found associated in the same seed ; sometimes one predominates and the others only enter in very small proportion. After burning, the ashes of seeds are always found composed of phosphates, sulphates, and alkaline and earthy chlorides. These ashes also contain silica, and certain carbonates produced by the destruction of salts formed by organic acids. If some seeds, sufficiently moistened, are placed under a bell- glass containing atmospheric air confined over quicksilver, all the signs of germination will soon be perceived. In the course of a few days, provided the temperature has been sufficiently high, germina- tion will have made a certain progress. Supposing that the tem- perature of the bell-glass has not varied, and that the atmospheric pressure remains the same, we generally find that the air, in which germination has been proceeding, has not changed its original vol- ume ; but it has been modified in its composition : a notable quantity of carbonic acid has been formed, and a portion of oxygen has dis- appeared. The volume of carbonic acid produced, represents for the most part the volume of oxygen which has disappeared. Now we know that carbon being burnt in a certain volume of oxygen gas, produces sensibly an equal volume of carbonic acid gas. It was the knowledge of this fact that induced M. de Saussure to say, that in germination, carbonic acid is produced by the combustion of a por- tion of the carbon which enters into the composition of the seed. Germination and the appearance of carbonic acid, (which is al- ways its consequence,) take place as readily in pure oxygen gas, as in atmospheric air; but if placed in an atmosphere deprived of oxy- gen, seeds cease to germinate. Consequently, germination is out of the question in azote, in hydrogen, or in carbonic acid, however fa- GERMINATION. 27 vorable they may be in reference to humidity and temperature. Some formation of carbonic acid is indeed to be observed under such circumstances, but then this gas is the result of the decompo- sition and putrid fermentation of the seed. It is therefore by means of the oxygen which it contains, that atmospheric air concurs in the germination of seeds. Rollo was the first who ascertained the production of carbonic acid, during the germination of seeds in an atmosphere of oxygen ; but it was M. Theodore de Saussure, who by delicate eudiometrical ex- periments, demonstrated the phenomena in all their nicety, by prov- ing thai the oxygen consumed was replaced by a corresponding volume of carbonic acid.* There are some seeds, for instance, peas, and the seeds of aquatic plants, which have the property of germinating under water. Some observers have, from this fact, come to the premature conclusion that atmospheric air, and consequently oxygen, were by no means neces- sary to germination. Saussure has explained this anomaly by re- ferring to the constant presence of air in a state of solution in water. In fact, having placed some seeds of the polygonum amphibium under water, deprived of its air by long boiling, Saussure proved that ger mination could not take place. f Under like circumstances, the quantity of carbonic acid generated in a given time, is by so much greater, the larger the quantity of oxygen in the atmosphere which immediately surrounds the ger minating seed. Carbonic acid gas is, of all the gases which have been tried, that which is most unfavorable to germination ; and one way of hastening the process is to place under the receivers which cover the seed, some substance capable of absorbing it as fast as it is formorl — quick-lime, for example. By this arrangement the radic- ular increase is sensibly accelerated, J The quantity of oxygen gas necessary to germination, is not the same in reference to all seeds ; lettuce, the french-bean, and the field-bean require about yg^th part of their respective weights ; while J^th less is sufficient for wheat, barley, purslane, &c. Saussure moreover came to the conclusion that the carbonic acid generated by these diflferent seeds in germinating is proportioned to their mass, and altogether independent of their number.^ Inasmuch as seeds during germination yield carbonic acid to the atmosphere, it is quite obvious that they must lose some part of their original weight. And this they do in fact ; but the loss experienced by seeds which have germinated is always greater than that which would have resulted from the destruction of carbon that takes place. Saussure attributed this excess of loss to the volatilization of a por- tion of the water which entered into the composition of the seed.jj According to Saussure, therefore, the phenomena of germination resolve themselves into the diminution of carbon and of the elements of water. It is, nevertheless, doubtful whether the chemical actions * Saussure, Recherches chimiques sur la V6g6tation, p. 10. t Idem, p. 3. t Mem, p. 26. $ Idem, p. 13. ^| Idem, p. ao. 28 CHEMICAL PHENOMENA, ETC. are so simple as this ; we know, for example, that M. Becquerel considered the organic acid which appears during germination as acetic acid, whereas it is much more likely tiiat it should be the lactic acid. There is certainty of the formation of an acid during germination ; to prove its development it is sufficient to make a fev/ moist seeds sprout on blue litmus paper, which speedily acquires the permanent red tint indicating the presence of an acid. The volume of the air in which seeds germinate is not absolutely invariable. On examining, with renewed attention, the action of germinating seeds on a limited volume of air, M. de Saussure as- certained that certain seeds have the property of diminishing the bulk of this atmosphere, while others perceptibly augment it. It must be admitted, therefore, that during germination, tlie volume of carbonic acid produced is now greater, now less, than the volume of oxygen gas that is consumed. The nature of the results obtained appears, however, to vary in regard to the same class according to the stage of the germination. Elementary analysis appeared to me the most satisfactory means of investigating the subject of germination. I shall here recapitu- late a few attempts that have been made in this direction, less how- ever with a view to the final settlement of the question, than to point out the general method of procedure to those who would enter far- ther upon this interesting portion of physiology. The experiments I allude to were made upon the seed of trefoil and on wheat. The seed, on being dried at a heat of 110° cent. (230° Fahr.,) lost 0.120 of water. Duly moistened, it was placed to sprout on a por- celain plate. As soon as the radicle had attained a length of from ^•gth to 2\th of an inch, each seed was placed in a stove, the temera- ture of which was sufficiently high to check the growth immediately. The complete desiccation was then terminated over an oil bath at a temperature of 110° cent. (230° Fahr.) The seed put to germinate weighed 2.474 grammes, (38.193 grains troy;) perfectly dry, its weight would have been 2.405 grms. (37.128 grains troy.) When germinated, the seed, also quite dry, weighed 2.241 grms. (34.596 grains troy.) Analysis gives us the composition of THK SEED BEFORE OERMtNATION. THE SEED AFTER OERMINATIOH. Carbon 51.5 ."id.S Hydrogen 6.0 O.Ii Azote 7.2 8.0 Oxygen .♦■ 36.0 34.2 100.0 100.0 RESULTS OF EXPERI.MENT. (jrains troy. Carbon. Hydrogen. Oxyycn. Ai.-'.e. Seed placed to gemiinrite 37.12S containing 18.865 2.22.3 13.360 2.670 Seed alter gerniinatio:i 34.5% " 17.815 2.176 11.840 2.7f]3 Difference • — 2.-532 '■ — 1.050 — .047 — 1.520 + .093 The total loss then during germination was 0164 grm., (2.531 grs.) while the loss due to the carbon, only amounts to 0.068 grm. (1.C49 GERMINATION. 29' grs. :) the analysis shows besides that in this particular rase, the excess of the loss in the present case over and above that which is ascribed to the carbon, is not altogether due to the elenaents of water, inasmuch as it is partly ascribable to carbonic oxide ; for 1.049 grs. of carbon, 1.404 " of oxygen, Represent 2.453 " of oxide of carbon. Supposing this to be so, and the first period of the germination of the trefoil to have been conducted in a close vessel, the volume of atmospheric air would have been increased ; because 1 volume of carbonic oxide-(-i volume of oxygen— 1 volume of carbonic acid gas. It is consequently evident that for each volume of carbonic oxide produced from the seed, there is one half of this volume added to the total volume of the atmosphere. It will not, perhaps, be useless to advert to the circumstance that the increase of volume, which in the experiment I have just related must have amounted to about twenty-five cubic inches, would cer- tainly have passed undetected, if the experiment had been conducted in a close vessel. For inasmuch as several quarts of atmospheric air must have been used to place 38.193 grs. of seed in conditions favorable for germination, it may readily be imagined that the in- crease of volume must have been too small a fraction of the total mass of air to be appreciated with any certainty. GERMINATION OF WHEAT. The wheat employed, on being dried, lost 0.652 grain of moisture. Thirty-one grains were arranged for germination, which process was suspended immediately after the appearance of the radicles. The young stalks were hardly visible. The germinated grain looked slightly shrivelled : on being crushed, after having been dried, it scarcely differed in appearance from ordinary wheat reduced to powder, a considerable quantity of starch being still recognisable. The wheat, before germinating, taken as dry, and free from ashes, weighed 2.439 grms., or 37.653 grs. troy. The seed when germinated and gathered, under the same condi- tion, weighed 2.365 grms., or 36.510 grs. troy. Elementary analysis gives for the composition of — WHEAT NOT GERMINATED. GERMINATED WHEAT. Carlwn 46.6 47.0 Hydrogen 5-8 5-9 Azote 3.45 3.7 Oxygen ..-44.15 43.4 100.0 100.0 RESULTS OF EXPERIMENT. Grains troy. Carbon. Hydrogen. Oxyg'en. Azote. Wheat placed to genninate 37.653 containing 17-47 2-176 16-56 1-281 Wheat when germinated 36.510 " 17.15 2.145 15.83 1.343^ Diflference —1.143 " —0.032 — 0031 —0-073 +0.063 3* 30 CHEMICAL PHENOMENA, ETC. 0.324 of a grain of carbon -fO.432 of a grain of oxygen represent 0.756 of a grain of carbonic oxide ; 0.030 of a grain of hydro^ajn would require 0.247 of a grain of oxygen to form water. Now, the oxygen remaining, abstraction made of that which enters into the formation of the carbonic oxide is 0.282 of a grain. In the first period of its germination, therefore wheat, like trefoil seed, experiences a loss which may in great part be referred to elimination of the carbonic oxide. The chemical composition of these two kinds of seed at more advanced periods of their germina- tion, no longer presents relations so simple. We easily discover that carbon continues to be eliminated ; but the loss no longer cor- responds with that which the oxygen of the seed ought to suffer, in order that the total loss should be represented by a definite compound of carbon. The phenomenon, in fact, becomes extremely complex ; and we can even perceive that it must be so, when we reflect that in proportion as the green parts are evolved, a new chemical action is set up entirely different from that which takes place in the earliest periods of the germination : the green matter of vegetables having, as we shall find, the singular faculty of decomposing carbonic acid gas, and assimilating its carbon under the agency of light. This action of the green matter begins to be manifested long be- fore the first phases of germination have entirely ceased ; so that during a certain time two opposite forces are at work simultaneously. One of these, as we have seen, tends to discharge carbon from the seed ; the other tends to accumulate this element within it. So long as the first of these forces predominates, the seed loses carbon ; but with the appearance of the green matter the young plant recovers a portion of this principle ; finally, when by the progress of the vege- tation, the second force surpasses the first in energy, the plant grows, increases, and advances to maturity. The presence of light is indispensable to the manifestation of the chemical force by which the green parts of plants appropriate the gaseous elements of the atmosphere. Germination, on the contra- ry, may take place in absolute darkness ; and it would be curious to inquire into the issues of vegetation begiin and ended under such cir- cumstances, in which the organs produced by the seed would have no power to fix any of the principles of the atmosphere to repair the loss of carbon which the seed suffers. It is evident that this loss of carbon must have a limit, which is probably that of germination. CONTINUED GERMINATION OP PEAS Ten peas, weighing together 2.237 grms. or 34.534 grs. troy, taken as quite dry, were put to germinate in a dusky room, the tem- perature of which was maintained between 12° and 17° cent. (54* and G3° Fahr.) The experiment, begun the 5th of May, was ended on the 1st of July. The germinated peas, when dried, weighed 1.075 grm. or 16.595 I IS. troy. GERMINATION. 81 Composition of the peas : BEFORE GERMINATION. AFTER OERMTNATIOM- Carbon 46.5 44.0 Hydrogen 6.1 6.0 Azote 4.2 6.7 Oxygen 40.1 36.9 Ashes 3.1 6.4 100.0 ^ 100.0 SUMMARY OF THE EXPERIMENT. Graing troy. Carbon. Hvdro^en. Oxy»en. Azote. Balti, Earth* Peas set to germinate... 34.534 cont'ng 16.055 "2.115 13.843 1.447 1.064 Peas which had germi- nated 16.595 _ " 7.292 1.003 6.128 1.111 1064__ Difference — 17.939~" —8.763—1.112 —7.715 —0.336 0.000 Peas, during their germination, pushed to this extreme term, therefore, suffered a loss of about 52 per cent., the loss being refer- able to each of their constituent elements, which are summed up in carbon, water, and ammonia. 7.719 of oxygen taking 0.972 of hydrogen to form water ; 0.339 of azote requiring- 0.077 of hydrogen to form ammonia ; 1.049 which represents as nearly as possible the quantity of hydrogen eliminated. In this experiment, therefore, we see that a seed weighing 3.453 grs. troy, suffered a daily loss of about 0.077 of a grain troy of carbon. CONTINUED GERMINATION OF WHEAT. On the 5th of May, 46 corns or grains of wheat, supposed to be quite dry, and weighing 1.665 grm. or 25.704 grs. troy, were set to germinate in the dark. On the 25th of June, the germinated wheat, when dried, weighed 0.713 grm. or 11.007 grs. troy. Composition : BEFORE GERMINATION. AFTER GERMINATION. Carbon 45.5 41.1 Hydrogen 5.7 6.0 Azote 3.4 8.0 supposed. Oxygen 43.1 39.5 Ashes 2.3 5.4 calculated. mo iooio ^ SUMMARY OF THE EXPERIMENT. Grains troy. Carbon. Hydrogen. Oxyg^en. Azote. Salti, Earth*. . Wheat placed to germinate 25.704 containing 11.704 1.466 11.086 0.879 0.588 Wheat germina- ted 11-007 " 4.523 0.343 4.373 0-879 0.588 Difference —14-697 " —7.181—0-803 -6-713 0.000 0-000 Diyjing the germination, continued for fifty-one days, consequently thin wheat lost 57 per cent., and the loss may be wholly referred to 82 CHEMICAL PHENOMENA, ETC. the elements of carbonic acid and water, i. e. to carbon, hydrogen, and oxygen.* These results of the elementary analysis of seeds of different kinds, before and after germination, tend, therefore, to show that the chemical phenomena which take place in the earliest periods of ger- mination, continue to go on even after the organic matter of the seed has been changed into a proper vegetable, imperfect, undoubt- edly, but still possessing the essential organs of plants, — roots, a stem, and leaves. Deprived of light, the blanched vegetable may be said to vegetate in a negative manner, expending, exhaling the ele- mentary principles contained in the seed whence it sprung. The general practice of sowing seeds at some depth in the ground, led to the belief, for a long time, that light was prejudicial to germi- nation. Sennebier had even inferred so much from his experiments, which appeared to derive confirmation from those of Ingenhousz, and which were instituted for the express purpose of discovering the comparative influences of sun-light and darkness on the germination and growth of vegetables.! But M. de Saussure showed that the prejudicial influence attributed to the light was connected with the drying of the seed, in consequence of its exposure to a higher tem- perature. M. de Saussure caused seeds to germinate at the same time under two bell-glasses of equal capacity. One of these shades was opaque, the other was transparent, and so placed as to re- ceive the diffused light of day. The temperature was the same in either. The seeds sprung simultaneously under both glasses. J Within a few days, the vegetation under the transparent shade was most advanced; which is exactly what we should have expecteci from all that has already been said of the functions of the organized parts subjected to the action of light. We are indebted to M. de Humboldt for a number of very curious observations on the property which chlorine possesses of stimulating or favoring germination. This action of chlorine is so decided, that it is apparent even upon old seeds which will not germinate when placed under ordinary circumstances. The experiments of M. de Humboldt were made, in the first instance, on the common cress, {lepidium sativum.) The seeds were placed in two test tubes of glass, one of which contained a weik solution of chlorine, the other common water. The tubes were placed in the dark, the tempera- ture being maintained at about 15° cent. (59° Fahr.) In the chlo rine solution, germination took place in six or seven hours ; from thirty-six to thirty-eight were required before it was manifest in the seeds in the water. In the chlorine, the radicles had attained the length of .0585 Eng. inch, after the lapse of fifteen hours, wlvile they were scarcely visible at the end of twenty hours in the seeds submerged in vvater.^ • The small quantity operated on prevented any estimates being made of the azote lost. Its projwrtion was supposed not to have varied. It is extr?nieiy prolrjiile, how ever, that there was some slight disengagement of azote, as in the preceding experi menu t Saussure, Rech. Chimiques, p. 23. J De Saussiue, op. clt p. 28^ ^ Humboldt, Flora fribergensis subteoanea, p. 126. EVOLUTION AND GROWTH. 33 In the botanical gardens of Berlin, Potsdam, and Vienna, this pro- perty of chlorine lias been made available to excellent ends; by its means many old seeds, upon which a great variety of trials had already been made in vain to make them sprout, were brought to germinate. At Schoenbrunn, for instance, they had never succeeded in raising the clusea rosea from the seed ; but M. de Humboldt suc- ceeded at once, by forming a paste of peroxide of manganese, with water and hydrochloric acid, in which he set the seeds of the clusea, and then placed them in a temperature of from 62° to 75° cent. (143° to 167° Fahr.) It seems very likely that this discovery of M. de Humboldt may yet be taken advantage of in our every-day hus- bandry. It is quite certain that the whole of the seed which we commit to the ground, does not spring up, especially when we are forced to have recourse to seed that is two or three years old ; the loss is then frequently very considerable. But a solution of chlo- rine, or a mixture which would evolve it, could not cost much, its use would add little or nothing to the very trifling expense which is generally incurred in pickling the wheat that is employed as seed. § III.— EVOLUTION AND GROWTH OF PLANTS. As germination advances, we see those organs acquiring shape and size which had appeared at first in the rudimentary state. The roots extend in length, and increase in number, and their extremities become covered with capillary fibres. The stem as it rises puts forth branches in all directions, which become covered with leaves. The cotyledons which had nourished the young plant during the first days of its existence, wither and fall. Under the influence of the solar light, the vegetation progresses amain, and the organic matter, which finally constitutes the plant when it has attained matu- rity, weighs vastly more than the same matter which existed pre- viously in the seed. To quote a single instance from the family of annual plants, a seed of field beet of the weight of ,06175 of a crrain, may by the end of the autumn give birth to a root which with its leaves shall weigh 162099grs. or upwards of 281bs.* This immense and rapid assimilation can have no other source than the soil, the air, and water. Without, at this time, pausing to consider the useful influence which the soil, and the substances it contains, exert upon the entire development of vegetables, we shall here assume it as a general principle that water and the air of the atmosphere alone, are capable of furnishing them with all the ele- ments which enter into their composition, to wit — carbon, hydrogen, oxygen, and azote. In other words, a seed may germinate, vegetate, give birth to a plant which shall attain to complete maturity, by the * Actual weight of a beet-root grown at Bechelbronn in 1841 34 EVOLUTION AND GllOWTH. mere concurrence of water and the gases, or vapors which are dlf fused through the atmosphere. This fact is demonstrated by the following experiment : — In a sufficient quantity of properly moistened roughly pounded brick-dust, (which had been heated to redness in order to destroy every trace of organic matter,) a few peas were sown on the 9th of May, and the pot was transferred to a green-house in order to protect the plants from the dust and impurities which always fiy about in the open air. On the 16th of July, the peas, which looked extremely well and healthy, were in flower. Each seed had sent forth one stem, and each stem, abundantly covered with leaves, bore a flower. On the 15th of August the pods were ripe ; no more water was given, and by the end of the month the plants were dry. The length of the stalks varied from about three feet three inches to five feet ; but they were extremely slender, and the leaves not more than one third the ordinary size. The pods were 1.3 inch, by from 0.3 to 0.4 of an inch broad. They generally contained two peas each ; one contained a single pea only, hut this was almost twice the size of any of the others. In the course of three months, therefore, these peas came to per- fect maturity — ripe seeds were gathered. The analysis of the crop which I shall give by and by, in connection with another question which we shall have to discuss, showed that the harvest obtained under the conditions indicated, contained a considerably larger pro- portion of each of the elements found than was originally contained in the seed from which it sprung. Carbon being the predominating principle in plants, it is our first duty to inquire into the origin of so much of this element as is as- similated in the course of vegetation. Carbon is met with in very small quantity in the atmosphere in the state of carbonic acid, and as this is one of the most soluble of the gases which enter into the constitution of the air, water always contains a considerable quantity of it in solution. Carbonic acid may therefore be in relation with plants by the medium of the air amidst which they live, and of the water which is no less indispen- sable to their existence. We have now to ascertain in what way thit gas evolves and sets free its carbon in favor of living vegetables. Bonnet, having put some fresh leaves at the bottom of a jar con- taining spring water, observed that when exposed to the rays of • the sun, they gave off bubbles of air. He sought to ascertain whether this disengagement of gas was due to the leaves, or to the liquid in which they were contained. For the spring water, he therefore substituted water deprived of its air by boiling, and he found that the leaves exposed to the sun's light in this water, no longer gave oflT any bubbles of air. Bonnet, therefore, concluded that the gas which he collected in his first experiment, proceeded from the water. In 1771, Priestley discovered, that by emitting oxygen, plants had the property of ameliorating atmospherical air, which had been ASSIMILATION OF CARBON. 35 ritiated by the respiration of animals or by combustion.* This un- expected discovery immediately arrested the attention of vegetable physiologists. Nevertheless, Priestley was not yet master, so to speak, of the capital experiment which he had announced to the world of science. He had not seized all the circumstances which assure its success. Occasionally the leaves which were the subjects of experiment did not cause the disengagement of any gas ; occa- sionally, too, the air disengaged, far from being oxygen — far from ameliorating the atmosphere, was found to be carbonic acid gas. It was Ingenhousz who made out the influence of the solar light upon the phenomenon in question. He proved, by a vast number of dis- tinct experiments, that leaves exhale oxygen when they are exposed to the light of the sun. He perceived, moreover, that in the dark they vitiate the air, rendering it improper for respiration and com- bustion, f But the origin of the oxygen disengaged from water by leaves exposed to the light of the sun still remained to be discovered. It was Sennebier who took this important step, by showing that it was to the carbonic acid generally contained in water that leaves ex- posed to the sun's light owed their faculty of evolving oxygen gas. With this interesting fact, it was easy to render an account of all the anomalies that had been successively announced : boiled water, as Bonnet had observed, could not afford any air, and spring water should usually give more than river water, as Ingenhousz had no- ticed, for the simple reason that boiled water neither contains carbonic, acid gas nor any other kind of air ; and that well water generally contains a larger quantity of carbonic acid in solution than river water. In giving the grand features in the history of this brilliant discov- ery of the eighteenth century, it may be said that Bonnet was the first who observed the phenomenon of the gaseous evolution effected by the leaves of vegetables :| that Priestley announced that the gas disengaged was oxygen ; that Ingenhousz demonstrated the neces- sity of the solar light to the production of the phenomenon : finally, that it was Seimebier, to whom was reserved the honor of showing that the oxygen gas obtained under these circumstances is the pro- duct of the decomposition of carbonic acid. It was, however, matter of supreme interest to study this decom- position of carbonic acid in its last details. It was imperative, for instance, to ascertain what relation existed between the volume of the oxygen disengaged and the volume of the carbonic acid decom- posed. This was admirably accomplished by M. Theodore de Saus- sure in a long series of remarkable experiments, of which I shall here endeavor briefly to state the main results. The conclusion which follows naturally from the discovery of Sennebier, was that carbonic acid exercised a favorable influence on vegetation by supplying plants with the carbon which enters into * Experiments and Observations, vol. ii. t Experiments on Vegetables. i Sur I'usage des feuilles dans tea plantes, p. 3! 86 EVOLUTION AND GROWTH. their constitution. Percival ascertaini^d by direct experiment thi accuracy of this inference by placintj plants in a current of atmo spheric air, mixed with a pretty large proportion of this gas. By means of a comparative experiment, he saw that a plant in such circumstances made much greater progress than one subjected to a current of ordinary air.* The researches of Saussure, in confirm- ing in all respects those of his predecessors, added this farther very important fact : that to act beneficially upon vegetables the carbonic acid must be mixed with oxygen. Under a bell glass of the capacity of 398 cubic inches, placed over mercury, with a delicate film of water swimming on its surface, he introduced three young peas, which displaced about y^y of the in- cluded air. The atmosphere was composed of common air and carbonic acid gas in different proportions. The experiments were conducted successively in the sunshine and in the shade. In the sun, the apparatus received daily the direct action of the light during five or six hours : v^hen the light was loo vivid it was somewhat lessened by shading. In the sunlight the plants lived for several days in an atmosphere composed of equal parts of air and carbonic acid ; they then faded. But they died much more speedily in atmospheres which contained two-thirds, or three-fourths, or a fortiori which consisted entirely of carbonic acid. The young plants throve decidedly when the atmosphere contained about —^th of carbonic acid ; their growth was evidently more vigor- ous here than it was in simple air ; and at the conclusion of one ex- periment which extended over ten days, almost the whole of the carbonic acid was found replaced by, or changed into oxygen : the peas had assimilated the carbon. The smallest quantity of carbonic acid added to the air, was found injurious to the plants when they were kept in the shade. Young peas lived only six days under such circumstances, when the atmosphere around them consisted of a quarter of its volume of carbonic acid. They lived ten days when the proportion of this gas did not exceed a twelfth ; but then they scarcely grew at all in the mixture ; they certainly made much less progress than they would have done in common air. Saussure concluded, from these experiments, that carbonic acid was useful to growing vegetables only when present along with oxygen, and that it ceases to be so when the atmosphere contains more than ^^\h of its volume of the gas. To determine the proportion of oxygen set at liberty during the decomposition of carbonic acid by plants, Saussure composed an atmosphere nf common air and carbonic acid, the latter in the pro- portion of 0.075; the mixture was confined under a bell-glass of the capacity of 5.746 litres or 10.112 pints, standing over mercurj as in the former experiments. Seven plants of the periwinkle were introduced into the apparatus, their roots dipping into 15 cub. centim. or 5.895 cub. in. of water — the water was limited as much as possible^ * Maacbcster Mcmcirs, vol. U DECOMPOSITION OF CARBONIC ACID. 37 in order that the absorption of carbonic acid, which must, of course, take place, might be thrown out of ihe reckoning. The experiment was continued for six days, during which the plants received the direct rays of the sun from five to eleven o'clock in the morning. On the seventh day, the plants were withdrawn. They had pre- served their freshness. All the corrections made for temperature and pressure, the volume of the atmosphere in which they had lived was not found changed by more than about 20 cubic centimetres, 7.8 c. in., a quantity which is within the possible errors of compu- tation ; but the composition of the air had undergone very notable changes : the carbonic acid had disappeared, and the eudiometer proclaimed 0.24 of oxygen instead of the 0.21 which it contained originally.* RESULTS OF THE EXPERIMENTS. c. inches. Azote. Oxygen. Garb. acid. Pe/ore : Volume of atmosphere 2257 containing 1650 438-5 169-3 ^fter: " " 2257 " 1704 553 0_^ 0 +54 +14-8 —169-3 The periwinkles, consequently, had caused 169.3 cubic inches of carbonic acid to disappear, and given off upwards of one hundred and fourteen cubic inches of oxygen. Had the whole oxygen of the carbonic acid been set at liberty, this volume would have been pre- cisely equal to that of the acid gas decomposed ; but as no more than one hundred and fourteen cubic inches of oxygen were obtained, it must be inferred that the periwinkles had fixed 54.6 cubic inches of this gas. This is the conclusion, indeed, to which M. de Saussure came, and subsequent experiments have confirmed its accuracy. The following table contains a summary of five experiments that were instituted : C. inches. c. inches. Exp.l. Carbonic acid disappearing. ••169.3 Oxygen disengaged.. • 114-7 Azote disengaged- •• • • 54-6 169-3 Exp. 2. " " " •••121.4 Oxygen disengaged. . . 88 Azote disengaged • • • • 33 121 Exp. 3. " " " ....58-5 Oxygen disengaged — 47.5 Azote disengaged 8-2 55.7 Exp. 4. " " " ...120-2 Oxygen disengaged — 96-6 Azote disengaged . . ... 7-8 104.4 Exp.5. u u u ....72.3 Oxygen disengaged.... 49.5 Azote disengaged 22.4 There is one remark which it is impossible to avoid making in sur- veying this table ; it is to the effect, that the azote disengaged rep- * Saussure, Kccherches chimiques, p 40 4 88 EVOLUTION AND GROWTH. resents almost exactly the volume of oxygen which it would be necessary to add, in order that the oxygen collected should represent the whole of that which entered into the constitution of the carbonic acid decomposed. It is probable that the excess of azote wliich ap- peared in all these experiments was present in principal part in the air contained and condensed within the interstices of the plants, or held in solution in the water which bathed their roots. It would be difficult to assign it any other origin ; such, for instance, as that from changes in the azotized principles of the plants that were the subject of experiment. In his first experiment, in fact, M. de Saus- sure fixes the weight of the dry matter of the seven periwinkle plants at 41.6 grains. Now, from numerous determinations of azote which I have had occasion to make in regard to plants of very dif- ferent ages and species, I think I can say that these periwinkles, taken as dry, did not contain more than .385 of azote ; this, in ref- erence to the weight assumed by M. de Saussure, would be 1.042 grs. or 20.8 cubic inches of azote; and the volume of azote disen- gaged in this first experiment was 54.6 cubic inches. It is proper further to observe, that the state of health which the plants pre- sented on the conclusion of the experiment does not allow us to sup- pose a total decomposition of the azotized matters which entered into their constitution. These various considerations lead us to in- fer that the excess of azote collected must have been displaced by oxygen. We are, therefore, at liberty to presume, from the experi- ments now referred to, that the volume of oxygen produced probably represents the volume of carbonic acid decomposed. The necessity of oxygen gas in the decompounding action which plants exposed to the light exert so energetically upon carbonic acid, leads us to study particularly the phenomena which oxygen exhibits in connection with growing plants. When a number of freshly gathered and healthy leaves are placed during the night under a bell- glass of atmospheric air, they condense a portion of the oxygen ; the volume of the air diminishes, and there is a quantity of free car- bonic acid formed, generally less than the volume of oxygen which l.is disappeared. If the leaves which have absorbed this oxygen during their stay in the dark, be now exposed to the sun's light, they restore it nearly in equal quantity, so that, all corrections made, the atmosphere of the bell-glass returns to its original composition and "volume. Leaves in general have the same effect when they are placed alter- nately in the dark and in the light; there is, however, a very obvious difference in the intensity with which the phenomenon is produced, according to the nature of the leaves. The quantity of carbonic acid formed during the night is by so much the less, as the leaves are more fleshy, thicker, and therefore more watery. The green matter of fleshy leaved plants, of the cactus opuntia, to quote a par- ticular instance, does not produce any sensible quantity of carbonic acid in the dark : but these leaves condense oxygen, and exhale it again like those which are less fleshy, when they are brought into he sun, after having been kept for some time in the dark. DECOMPOSITION OF CARBONIC ACID. 89 Saussure applied the names of inspiration and expiration of plants to these alternate effects, led by the analogfv — somewhat remote, it must be confessed — which the phenomenon presents with the respi- ration of animals. The inspiration of leaves has certain limits ; in prolonging their stay in the dark, the absorption becomes less and less : it ceases entirely when the leaves have condensed about their own volume of oxygen gas. And let it not be supposed that the nocturnal inspira- tion of leaves is the consequence of a merely mechanical action, comparable, for example, to that exerted by porous substances gen- erally upon gases. The proof that it is not so is supplied by the fact that the same effects do not follow when leaves are immersed in carbonic acid, hydrogen, or azote. In such circumstances there is no appreciable diminution of the atmosphere that surrounds the plant. The primary cause of the inspiration of oxygen by the leaves of living plants is, therefore, obviously of a chemical nature. With the facts which have just been announced before us, it seems very probable that during the nocturnal inspiration, the carbonic acid which appears is formed at the cost of carbon contained in the leaves, and that this acid is retained either wholly or in part, in proportion as the parenchyma of the leaf is more or less plentifully provided with water. A plant that remains permanentl}; in a dark place, exposed to the open air, loses carbon incessantly : the oxygen of the atmosphere then exerts an action that only terminates with the life of the plant : a result which is apparently in opposition to what takes place in an atmosphere of limited extent. But it is so, because in the free air the green parts of vegetables can never become entirely saturated with carbonic acid, inasmuch as there is a ceaseless interchange going on between this gas, and the mass of the surround- ing atmosphere ; there is, then, incessant penetration of the gases, as it is called. There is a kind of slow combustion of the carbon of a plant which is abstracted from the reparative influence of the light. The oxygen of the air also acts, but much less energetically, upon the organs of plants that do not possess a green color. The roots buried in the ground are still subjected to the action of this gas. It is indeed well known, that to do their office properly, the soil must be soft and permeable, whence the repeated hoeings and turnings of the soil, and the pains that are taken to give access to the air into the ground in so many of the operations of agricul- ture. The roots that penetrate to a great depth, such as those of many trees, are no less dependent on the same thing ; the moisture that reaches them from without brings them the oxygen in solution, which they require for their development. It is long since Dr. Stephen Hales showed that the interstices of vegetable earth still contained air mingled with a very considerable proportion of oxygen. The roots of vegetables, moreover, appear generally to be stronger and more numerous as they are nearer the surface. In tropical countries various plants have creeping roots which often acquira dimensions little short of those of the trunk they feed. 40 EVOLUTIOiS AND GROWTH. If a root detached from the stern be introduced under a bell-glasa full of oxygen gas, the volume of the gas diminishes, carbonic acid is formed, of which a portion only mingles with the gas of the receiver, a certain quantity being retained hy the moisture of the root. The volume of the gas thus retained is always less than that of the root itself, however long the experiment may be cortinued. In these circumstances, whether in the shade oi the sun, roots act precisely as leaves do when kept in the dark. Roots still connected with their stems, give somewhat different results. When the experiment is made with the stem and the leaves in the free air, while the roots are in a limited atmosphere of oxygen, they then absorb several times their own volume of this gas. This is be- cause the carbonic acid formed and absorbed is carried into the general system of the plant, where it is elaborated by the leaves, if exposed to the same light, or simply exhaled if the plant be kept in the dark. The presence of oxygen in the air which has access to the roots is not merely favorable ; it is absolutely indispensable to the exer- cise of their functions. A plant, the stem and leaves of which are in the air, soon dies if its roots are in contact with pure carbonic acid, with hydrogen gas, or azote. The use of oxygen in the growth of the subterraneous parts of plants, explains wherefore our annual plants, which have largely developed roots, require a friaWe and loose soil for their advantageous cultivation. This also enables us to understand wherefore trees die, when their roots are submerged in stagnant water, and wherefore the effect of submersion in general is less injurious when the water is running, such water always con- taining more air in solution than that which is .stagnant. The woody parts, the fruit, and those organs of plants in general which have not a green color, stand in the same relations to oxygen as the roots : they merely change this gas into carbonic acid, which is then transported to the plant at large, to suffer decomposition by the green parts. In this action we observe a displacement, a kind of translation of the carbon of the lower to the upper parts of plants. The decomposition of carbonic acid by plants admitted, we have still to examine whether, in the phenomena of vegetation, the leaves decompose the carbonic acid of the atmosphere directly, or the acid gas, previously dissolved in the water, which moistens the ground, be conducted by the way of absorption into the tissues of vegetables, there to suffer decomposition. The quantity of carbonic acid con- tained in the air is so small, and the growth of plants, on the con- trary, is often so rapid, that it might reasonably be suspected that the carbon which they require was introduced in great part by this way of absorptitm. In that series of beautiful experiments in '.vlijcii M. Saussure exposed plants to the influence of atmosphere.s more or less charged with carbonic acid, the water in which their routs were plunged was in contact with the mixed atmospheres. It was therefore possible that the carbonic acid gas entered the vegeiablos in the solution by the roots. Sennebier made an experiment to show that leaves decompose DECOMPOSITION OF CARBONIC ACID. 41 both the carbonic acid which is in contact with them externally, and that wliich is dissolved in the water absorbed by their woody tissue. He took' two branches of a peach-tree, and introduced them into a couple of bell-glasses filled with water from the same spring.* The lower snd of each branch dipped into a flask. One of the flasks was filled with water charged with carbonic acid ; the other con- tained air : the two bell-glasses were exposed to the light. Tiie leaves of the branch whose extremity dipped into the solution of carbonic acid, disengaged 99.4 cubic inchi t of oxygen gas undei the bell which covered it : the leaves of ihu uiher branch only pro- duced 52.2 cubic inches in the same lime. This experiment does not perhaps afford all the sufficient evi- dence of the decomposition of gaseous carbonic acid as it occurs in the atmosphere, and mixed with a great mass of air. It appears, however, that the leaves of plants have the power of decomposing the gaseous carbonic acid which is mixed with the air, and that even with surprising rapidity. In the summer of 1840, 1 introduced into a balloon of the capacity of about twelve quarts and a half, and furnished with three tubulures or openings, the branch of a vine in full growth and bearing twenty leaves. The woody part of the branch was fixed by means of a collar of caoutchouc to the lower orifice of the balloon ; a fine tube, intend- ed to establish a communication between the interior of the vessel and the outer air, was introduced into the superior tubulure ; the lateral opening communicated by means of a tube with an apparatus which measured with great accuracy the quantity of carbonic acid contained in the atmosphere. In this experiment the air, before reaching the apparatus for measuring the carbonic acid, passed through the great balloon con- taining the vine branch. The rate with which the air passed through the apparatus was regulated by the flow of an aspirator, and was at the rate of about twelve quarts per hour. The apparatus was exposed to the sun ; the experiment beginning at eleven and finishing at three o'clock. Ir one experiment it was found, all corrections made, that the at- mospheric air, after having passed through the balloon, contained in volume 0.0002 of carbonic acid gas ; the air of the adjoining court contained at the same moment 0.00045 of carbonic acid. In another experiment, the air, after having passed over the leaves, contained but 0.0001 of carbonic acid ; the air of the court contsin- ing 0.0004 of the same gas. In traversing the space in which the vine branch, exposed to the light of the sun, was included, therefore the air was deprived of three fourths of the whole quantity of car- bonic acid which it contained. In operating with the same apparatus during the night, opposite results were obtained ; the air in traversing the balloon generally acquired a quantity of carbonic acid, the double of that which the atmosphere contained at the same moment. • This was common water containing carbonic acid 4* 42 EVOLUTION AND GROWTH. I conceive that it is by such a method as this, that the genera, phenomena of vegetable respiration in plants still connected with the soil ought to be studied. The experiments which I have now related must satisfy every one, that the leaves of living plants actually assimilate the carbon which occurs in our atmosphere in the state of carbonic acid ; they also explain the well-known fact that plants thrive better in air that is in motion, and frequently renewed, than in a perfect calm. From all we have seen up to this time, then, w^e feel authorized to conclude that the greater proportion if not the whole of the carbon which enters into the constitution of vegetables is derived from the carbonic acid of the atmosphere. The experiments cited, show- how the vital force acts at first on the oxygen of the air during ger- mination, and next upon its carbonic acid during vegetation properly so called. But in none of the experiments which have been quoted, have we seen any thing which could lead us to suspect that the azote of the atmosphere was absorbed in sensible quantity. It is true, indeed, that at one time Priestley, and after him, Tn- genhousz, thought that they had observed an absorption of azote during the growth of plants in confined atmospheres. But the ex- periments which have been since performed by Saussure have not confirmed their conclusions upon this point. Saussure even thought that he had perceived a slight exhalation of azote. Nevertheless, the presence of azote in vegetables being incon- testable, and the assimilation of this principle during their growth being in some sort demonstrated by the fact that seeds are multiplied, physiologists were led to imagine that the azote was derived from ihe soil. And in nature, indeed, the growth of a plant does not take place at the sole c«)st of water and the atmosphere. The roots w^hich attach it to the earth there also find elements of nutrition. In ordinary circumstances the growth of a plant takes place by the simultaneous concurrence of the food which the roots encounter in the ground, and that which the leaves abstract from the gaseous elements of the air. As it is further acknowledged that the food which is supplied by the soil is for the most part azotized, manures have therefore been regarded as the principal and even as the ex- clusive source of the azote which is met with in vegetables. The observations of Hermbstadt, in showing that the grain which was grown under the influence of the most highly azotized manures contained the largest quantity of gluten, gave a certain force to this view. Nevertheless, there are facts well established in agriculture which induce us to think that in many cases vegetables find in the atmosphere a part of the azote which is necessary to their con- stitution. The majority of crops exhaust the soil ; but there are still some n'hich render it more fertile. We shall see, by and by, when treat- ing of the rotation of crops, that if, after having cut a field of trefoil once, the second crop be ploughed down, new fertility is communicated to the ground, in spite of the considerable mass of forage which had previously been taken from it. It appears therefore evident, that ASSIMILATION OF AZOTE. > 43 in ploughing down this second crop we restore such a quantity of organic or organizable matter, that, all things taken into account, the ground actually receives more from the atmosphere than was taken away from it in the first cutting. The latest experiments of physiologists would seem to show that plants merely take carbon from the air, and appropriate the elements of water. But the ideas which are now generally adopted in regard to the active principle of manures make it difficult to conceive that the soil, by receiving nou-azotized matters only, could acquire the degree of fertility whic'h is certainly obtained from The cultivation of •hose crops that are called ameliorating^ a fertility which enables us to follow these crops with others, rich in azotized principles. There is therefore reason for believing that the ploughing in of certain green crops, and fallowing, are not effectual merely by in- troducing carbon, hydrogen, and oxygen, but azote also into the soil. And it is absolutely necessary that this should be so, in order that the fertility of those lands may be maintained which, from theii position, can receive no manures from without. Let us take, for example, a farm laid out for the growth of white crops, and the rearing of cattle. Every year there is an exportation of grain, of flesh, and of the produce of the dairy ; that is to say, there is inces- sant exportation without any perceptible importation of azotized matter. Nevertheless, the soil maintains its fertility ; its losses are repaired by the principles which, in a good system of cultivation, pass from the atmosphere into the earth ; and among the number of these fertilizing principles it is beyond all question that azote must be present, in order that so much of this element as has been ex- ported may be replaced. The best established facts in agriculture, therefore, concurred in showing that azote is among the number of the elements that are fixed by plants during their growth. Still, as this truth had not been proved by the experiments of physiologists, the question had to be considered as yet undecided. It was with the hope of clearing up every thing in connection with it that I undertook the series of ex- periments, the chief features of which I shall now detail.* I had necessarily to follow a method of inquiry different from any which had yet been taken ; I had no chance of arriving at more de- finite results than those which had been already come to, had I cho- sen the old line of investigation. I therefore called in the aid of elementary analysis, with a view of romparing the composition of the seed with the composition of the harvest produced from it, at the sole cost of water and the air. By proceeding in this way I believed that the problem was capable of solution : without flattering my- self that I have completely resolved it, I conceive that something has been done in the right direction. The subject is one of the most delicate imaginable, and he who enters it requires indulgence. For soil, I made use of burned clay or silicious sand freed from all organic matter by proper calcination. In this soil, moistened ♦ Boussi- garolt, Annates de chimie et tie physique, f Ixvii. p. 5, 2* 86rie, aan6e 1838 44 EVOLUTION AND GKOWTH. with distilled water, were sown the seeds whose weig^ht was known By a number of preliminary trials, the quantity of moisture which seed of t!te same kind, of the same growth, and taken at the same moment, lost hy drying, commenced in the stove and finished in an oil-hath, ?-t 110" C. (230' Fahr.) was ascertained. The porcelain vessels, in which the experiment was conducted, were placed in a glass houpe at the end of a large garden. During the whole term, the windows were kept closed ; but the sun shone on the house all day. To remove the produce, the vessels were dried by a gentle heat. The roots of the plants then came out readily ; to free them completely from any adhering sand, they were moved about in a little distilled water, but never rubbed or bruised, for fear of loss ; it seem- ed even preferable to leave a little sand adhering. The harvest was then drieii in the stove, so that it might be powdered ; and the com- plete desiccation was effected in the oil-bath in vacuo. In ascertaining previously by muneration the weight cf the ashes contained in the seed, that of the produce, freed from all saline and earthy matter, became exactly known. Elementary analysis then proclaimed the composition of the pro- duce ; and it was only necessary now to compare it with the com- position of the seed, to have ascertained the proportion and the nature of the elements which had been assimilated during the vege- tation. FIRST EXPERIMENT. CULTURE OF RED CLOVER DURING THREE MONTHS. In the beginning of August a quantity of seed was sown, which, being dry and free from ashes, would have weighed 1.586 gramme, or 24.48 grs. troy. The crop presented a very good appearance ; the clover was from three to three and a half inches in height. The largest leaves could be included in a circle of about two inches in diameter. The length of the roots varied between two and four inches. Dried and bruised, the color of the produce was a deep green. The plant gathered quite dry, and supposed free from ash, weighed 4.106 grammes, or 63.38 grs. troy ; analysis showed it to consist of— In the Seed. In the Produce Carbon. 50.8 50.7 Hydrogen 6.0 6.6 Azote 7.2 3.8 Oxygen .36.0 _38.9 100.0 100.0 RESULTS. Carbon. Hvi1ro?cn. Oxr^en. Azote. 5M.48 grs. ircy containing after the analysis 12.44 1.466 8.81"> 1.759 63.38 " " " .... 32.141 4.183 24.ir>5 2.408 38.90 = grs'. during cultivation .... +19.70 +2.717 +15.840 +0.049 Thus, in the course of three months, the elementary matter of the 4eed had nearly doubled, and the azote of the plants gathered shows ASSIMILATION OF ELEMENTS. 4S an excess of 0.042 gramme, or 0.649 grs. troy, above the azote of the seed sown. SECOND EXPERIMENT. GROWTH OF PEAS. Five peas, very nearly of the same weight, and together weighing 1.211 gramme, or 18.69 grs. troy, were planted on the 9th of May, in a soil of recently burned clay in rough powder. On the 16th of July, the plants began to bloom, each pea having furnished a stem bearing a single flower. On the 15th of August the pods were quite ripe ; the stems were then from 39 to 40 inches in height. The leaves were smaller than those of the same peas grown in manured earth. The length of the pods was about 1.27 inch, by a breadth of about 0.43 inch. Four of these pods each contained two seeds ; the fifth had only one, but it was much longer than any of the others. The nine peas gathered and dried in the sun, weighed 1.674 gram., or 25.84 grs. ; after desiccation in vacuo, at 110° C, (230'" F.,) they weighed 1.507 gram., or 23.26 grs. troy ; on combustion they yielded 0.9 per cent, of residue. The roots, the stems, the pods, and the leaves, dried at 230° F., weighed 3.314 gram., or 51.16 grs. troy; and by combu.*tion gave 10 3 per cent, of ashes. As the result of several experiments, it was ascertained that peas, exactly in the condition of those which had been planted, contained 91.4 per cent, of dry matter, and left by incineration 3.14 per cent. t^ residue. The five peas planted, taken as dry and free from ashes, V >uld therefore have weighed 1.072 gram., or 16.54 grs. troy. A-naiysis showed in the Pea* town. Peat collected. Straw and rootfc Carbon 48.0 54.9 52.8 Hydrogen 6.4 6.8 6.2 Azote 4.3 3.6 1.6 Oxygen 41.3 34.7 39.4 100.0 100.0 100.0 RESULTS. Carbon. Hydrog^en. Oxygen. Axote. Seeds 16..549, containing 7.950 1.065 6.523 0.710 Crop 68.560, " * 3G.680 4.384 25.930 1.559 52.02 grs. by cultivation +28.73 +3.319 +19.11 +0.849 From this experiment it appears that 16.549 grs. of seed found in the air, and obtained from the water with which they had b*^en sup- plied during their growth, 52.02 grs of elementary matter io the course of riinety-nine days' growth, during the warmest months of the year ; and that the quantity of azote originally contained in th§ »eed was more than doubled in the produce arrived at inatprity. * Peas 45.89 Straw and shells 22.66 "^otal weight of the crop 46 EVOLUTION AND GROWTH. THIRD EXPERIMENT. GROWTH OF WHEAT. Forty-six wheat corns were sown in burnt sand at the beginning of the month of August. At the end of September, the stalks were from fourteen to fifteen inches in height. The greater number of the lower leaves were yellow. The roots were of very considerable length, and formed a kind of mat, which made it difficult to wash and free them from sand. RESULTS OF THE ANALYSIS. Seeds. Crop. Carbon 46.6 48.2 Hydrogen 5.8 5.8 Azote 3.45 2.0 Oxygen 44.15 44.0 100.00 100.0 RESULTS. Grs. Carbon. Hydfo«^en. Oxyg-en. Aiofo The seed dried 25.38 containing 11.84 1.46 11.19 0.87 The seed dried 46.65 " 22.47 2.67 20.57 0.92 Gainbycultnre 21.27 +10.63 +1.21 +9.38 +0.05 In the course of three months' growth, therefore, the weight of the seed had, so to speak, doubled ; but the grain azote was scarcely appreciable. Nevertheless, this experiment upon the wheat had been conducted under precisely the same circumstances as that made upon the clover. The two crops grew in the same apparatus ; they were watered with the same water, which they received very nearly in the same quantity ; the seed was even sown in vessels having exactly the same extent of surface, in order that either crop might be exposed to the same chances of error arising from the ac- cidental presence of dust in the atmosphere. The plants produced under the circumstances indicated T-ere far from presenting the vigor which they would have shown had they been grown in the open field. After three months of growth, the clover was much less forward than some which had been sown, for comparison, in a manured and gypsumed soil at the same time. The whea* showed the same weakness ; and after the second month, I observed that each new leaf which was developed upward in the stem, caused one of those at the lower part to droop and grow yel- low. The peas, although they reached maturity, had much smaller leaves, and both fewer and smaller seeds than similar plants grown at large. It is well known that it is in great part due to the fertility of the soil in which seeds are grown that the health and vigor of young plants must be ascribed. A celebrated agriculturist, Schwartz, as- certained, for example, that young col^worts or cabbage plants ex- hausted in a remarkable manner the soil in which they were raised fpjr transplantation. The good efiects of the first nourishment ob- ASSIMILATION OF ELEMENTS. 47 tained in a well-manured soil must extend subsequently to every part of the vegetable ; and it is easily understood that a plant which has languished in its earliest periods of existence can never acquire a good constitution afterwards. It therefore becamr interesting to carry out experiments of the nature of those already related, in connection with plants vigorously organized, and which had been raised in the first instance in a fer- tile soil. FOURTH EXPERIMENT. GROWTH OF CLOVER. In a field of clover sown in the spring of the preceding year, several plants as like one another as possible were chosen. The earth adhering to the roots was removed by careful washing under a small stream of water ; the plants were then made dry between leaves of blotting paper, and exposed for a few hours in the air. Three of these plants preserved for analysis weighed when green 5.750 grammes, or 104.20 grs. troy. Three other plants, weighing 6.820 gram, or 105.28 grs. troy, were set in sand recently calcined and moistened with distilled water. The transplanting took place on the 28th of May, and the plants were forthwith protected from dust. For some days they seemed to languish, but by and by they be- came remarkably vigorous. In a month the clover had grown to twice its original height, and the leaves were of the most beautiful green : the plants had in all respects as fine an appearance as the clover of the same age which had been left growing in the field. The flowers showed themselves upon the 8th of July, and by the 15th the flowering was complete : an end was put to the experiment on the 1st of August. RESULTS OF THE ANALYSIS. BEFORE CULTURE. AFTER CULTURE. Carbon 43.42 53.00 Hydrogen 5.40 6.51 Azote 3.75 2.45 Oxygen ..47.43 38.14 100.00 100.00 RESULTS. Tlie trefoil transplanted, weighed when dry and freed from ashes 13.64 After sixty-tiiree days' culture on iiarren soil, it weighed 34.96 Gained during culture 21.32 Carbon. Hydrogen. Oxyg-en. Azote The plant contained : before culture 5.92 0.74 6.4G O.r>0 afterculture 1?.52 2.23 13.32 0.SG4 Difference.. + 12.60 +1.49 +6.86 +0.35 Thus in two months' growth at the cost of the air and water, the clover had, so to say, tripled its quantity of organic matter; and the weight of azote contained in it was very nearly doubled. 48 EVOLUTION AND GKOWTH. - FIFTH EXPERIMENT. VEGETATION OF OATS. I always failed in my attempts to transfer wheat plants from the ordinary soil in which the grain had been sown to barren sand ; they never survived the transplantation. It was not different with oat plants ; they also always died. It was at first supposed that the delicate radicles of these plants had been injured in the process of taking them up and freeing their roots from adhering vegetable soil ; but I soon saw that this could not have been the case, for the same plants, treated precisely in the same manner, took very promptly when transplanted to garden mould, and even when they were put with their roots in pure water. It was with water, therefore, that the following experiment was conducted. June 20th, several oat plants were taken up from a field, and their roots were washed and cleansed. Three plants preserved for analysis, weighed 159.011 grs. Four plants, the subjects of experiment, weighed 221.844 grs. troy. They were protected from dust, their roots dipping into a vessel containing distilled water, which was regularly kept up to the same level. By the middle of July the stalks of these plants had grown to twice their former length ; and at this time it would have been difficult to have distinguished them from those growing in the open field. By the end of July the clusters had formed ; and on the 10th of August the grain seemed ripe. It was, therefore, taken np and dried in the stove, and reduced to powder to complete the desiccation at 110° cent. (230° Fahr.) ANALYSIS OF THE CROP. Transplanted. Gathtred from the Held. Carbon 53.0 48.0 Hydrogen 6.8 6.2 Oxygen 36.4 44.0 Azote 3.8 1.7 100.0 100.0 SUMMARY. Carbon. Ujrdre^a. Oxjrgta. Axott. The oats when transplanted contained 12.967 1.636 8.770 0.910 AAer 48 days of growth in dis- tilled water they contained • • 23.157 2.979 21.180 0.818 +10.190 +1.343 +12.410 —0.099 The analysis, therefore, indicates a trifling loss of azote. In recapitulating the conclusions obtained from these experiments, we find : First. That trefoil and peas grown in a soil absolutely without manure, acquired a very appreciable quantity of azote, in addition to a large quantity of carbon, hydrogen, and oxygen. ASSIMILATION OF ELEMENTS. 49 Second. That wheat and oats grown in the same circumstances, took carbon, hydrogen, and oxygen from the air and water around them ; but that analysis showed no increase of azote in these plants after their maturity. The mode of experimenting followed had it in view simply to determine the assimilation of azote by certain vegetables, without entering into the question of the means by which this was effected ; and, indeed, in reference to the point, I can only offer conjectures. Azote may enter the living frame of plants directly, or, as M. Piobert has maintained, in the state of solution in the water, always aerated, which is taken up by their roots.* The observations of vegetable physiologists are nj)t generaly favorable to this view. It is farther possible that the element in question may be derived from ammoniacal vxpors, which, according to some philosophers, exist in infinitely small proportion in our atmosphere. These vapors, dis- solved by rains and dews, would readily make their way into plants, and might there undergo elaboration. It is long since Saussure alluded to the probable influence of am- moniacal vapors upon vegetation. Prof. Liebig has more recently maintained the same opinion, and has taken particular pains to prove that rain-water always contains a very minute quantity of carbonate of ammonia. To this cause, which must have the effect of infusing an azotized principle into the tissues of plants, must be added another, which is perhaps not thp least energetic. It is this, that under certain elec- trical influences, of which M. Becquerel has made a particular study, hydrogen in the nascent state, in contact with azote, may actually give rise to ammonia. By means of this view, it becomes easy to conceive how non-azotized organic substances, under the mere in- fluence of the putrid fermentation, might give origin to ammoniacal salts, which would then exercise a fertilizing action on the soil. During the growth of plants, a portion of the water absorbed by the roots is evidently assimilated ; and this circumstance enables us to conceive the formation of many of the immediate principles of vegetables, the chemical composition of which is precisely repre- sented by carbon and the elements of water ; such as starch, sugar, etc. We can also understand the presence of those principles, which have further a certain proportion of oxygen in excess, inas- much as we have ascertained that during the decomposition of car- bonic acid by the green parts of vegetables, the whole of the oxygen is not eliminated. But there are substances elaborated by plants which, with reference to oxygen, contain a quantity of hydrogen much greater than is requisite to form water ; such are the resins and other carburets of hydrogen in the cone-bearing trees, and the fat oils in the oleaginous seeds. This excess of hydrogen led severai physiologists to conclude that water was decomposed in the course of vegetation, — that there was fixation of its hydrogen and disen- gagement of its oxygen gas. • Piobert, M6m. de rAcad6mle de Metz, 1837, - - — 'i ■5 ^M^ 69 EVOLTTTION AND GROWTH. Nevertheless, the presence of hydrogen in excess in certain im- mediate vegetable principles is no decisive proof of the disjunction of the elements of water ; and if no definitive conclusion lias been come to on the point, up to the present moment, it is because these hydrogenized principles are produced in plants which live under the influence of certain organic substances that are met with in the soil, where they act as manures, their composition being always complex, and often highly hydrogenized. The experiments of M. de Saussure do not lead us to suspect the decomposition of water ; inasmuch as by keeping plants for a whole month, under receivers filled with atmospheric air freed from carbonic acid, no apparent evolution of oxygen was observed. Operating in the same manner with air containing a certain propor- tion of carbonic acid, the quantity of oxygen disengaged was always less than that which entered into the constitution of the acid de- composed. This is the place to observe, and in connection with these very experiments of M. de Saussure, how little satisfactory this partial decomposition of carbonic acid, which corresponds to no definite proportion, appears. We already feel the difficulty of conceiving that this acid should be completely reduced by a living plant ; that is to say, that the whole of its carbon should become assimilated. The entire separation of a body so greedy of oxygen as carbon from its most highly oxygenated compound, must needs excite the greatest astonishment. The readiest conception suggested by the facts is this ; that by the agency of the solar light, and under the influence of the green matter, carbonic acid is turned into carbonic oxide by losing a por- tion of its oxygen. This modification appears more in conformity with the ascertained principles of chemical and physiological science. Still it must be allowed, that facts agree as little with this mode of viewing the question as with that which assumes the entire decomposition of the carbonic acid. On the first assumption, the proportion of oxygen set at liberty is too small ; in the second, it is too great. The negative results of M. de Saussure, in relation to the separa- tion of the elements of water during vegetation, were obtained in the absence of carbonic acid, whilst the experiments which estab- lished the decomposition of this latter body, were necessarily made under the influence of moisture. It is possible, therefore, that the water and the carbonic acid underwent simultaneous decomposition ; and it becomes interesting, taking this view, to inquire whether the hypothesis according to which carbonic acid undergoes transforma- tion into carbonic oxide does not acquire a certain degree of proba- bility by calling in the effect of the decomposition of water in the phenomena observed. One volume of the gaseous oxide of carbon takes half a volume of oxygen gas to form one volume of carbonic acid. Reciprocally, ©ne volume of carbonic acid gas, in undergoing transformation inta ASSIMILATION OF ELEMENTS. 51 the oxide of carbon, will give one volume of the oxide, -f | a volume of oxygen gas. Thus, in the hypothesis which we now discuss, for each volume of carbonic acid that is modified by the vegetation, there will he half a volume of oxygen gas disengaged. Any oxygen more th.-».n tbi-i t^ ^ C* CJ O rf OS Tf to 00 •itSBjodjoapuomo o o o m o o ec »iO « O^ r^rHOOOOOOOO o oooo'oo'o''o'oo" •qsBiodjo ajBiiding •S es'5 '§.000 »; coojir5»rt SS«--2CJC^C^ a ^ — (OCO-^ > tc.5 00)000 "- OOOO •5b§ sSo'd^o" is o'^o'^o'o •USBjodjoajBqdsoqj O OSOOOt^irt oi 00 v.v.coio(Moa5t-..oj ?o 00 tft o o"o o o «> o"©''o'o*'o' ii II 1 Chestnuts Menyanthes trifoliata in flower (buckbean) The same cleared of seed Beans .... Wheat straw Selected wheat . Wheat bran Indian corn straw Indian corn Barley straw . Barley in the husk : ■ , ■ •«lSilBU8J0-OX r^a «-«<«« o t* 00 o o j-j 66 INORGANIC CONSTITUENTS. In his researches upon the same subject, M. Berthier determineJ the relation of the insoluble to the soluble matters in each species of ash examined ; and the two kinds of salts were then analyzed separately. TS a s s rruginous. s, calcareous careous. eiceous soiL Id. f a plank, d calcareous us sand. 1 1 1 dy and fe: rgilluceoui ewhat cal and argilli le open fie ay, part o strong an r calcareo layey, san ery dry, a andy, som he same. itto. itto. itto. itto. alcareous i rown in tl indy clay. rom Norw rown in a Iicious au( U> mH QGQQUC5 M faOc« s 1 »-iOO0«O»r5Ot0.-HOO'^i0OinOO00 .2 1— •OO'CCJ'^00-^'^— ^ifliOOCi'^OOO— C'oa>t^«o^c;c5-^ o c __O-H««-^-Hr^^C^OO^C0l0C:O 1 d'ooo'ood'o'ooo'd'o'oo'ocrcr < • 1 Horn-beam Oak Oak bark Lime tree Wood of St. Lucia Elder . Judea-tree Hazel Chinese mulberry White mulberry Oitto ditto . Orange or lance-w* White oak Birch False ebony . Fir . / . Wheat straw . Potato stems . ASHES. 57 CO <^ O 60 ^q o O H - 1^ ej M o o o o' o' o o o nil I il SiSSg mi oo^o'oo ooo'o" o' CO o o Ti< o c o'oc ocTc 35 ^ O O in SSSS J5 o'oc'o o ooo'o'c'oo 3000 ■*}222 *^ cJcfo'o o iiii i liii doo'o" « o o •* © o o o d d d d d' d' O « 00 CD O i« QC MOoInoSo d'od" o< ddddddd 2§ : rtS 'spaooduioa eiqniog ^ w : • .3 V, .^ 03 ,* ^ S " £ X X 3 OSmcciJSooo ^~ -y. — » 'spunodoioa diqniosoi 58 INORGANIC CONSTITUENTS. COMPOSITION OF THE ASHES OF SEVERAL PLANTS ANALYZED BY M. BERTHIER. Fern. Wheal straw. Horse-tail grass. Heath. Tansy. Observations. Sulphate of potash- . • Chloride of potassium Carbonate of potash. • Silicate of potash Silica^ 0,007 0,730 0,248 0,010 0,005 0,004 0,032 0,130 0,715 0,096 0,083 0,120 0,114 0,505 0,062 0.144 0,022 0,030 0,050 0,012 0,068 0,375 0,280 0,130 0,010 0,014 0,061 0,033 0,090 0,167 0,i65 0,434 o.]'oo 0,002 0.007 0.002 The wheat straw was from a strong calca- reous 80ll. The tansy wa« from a sandy gar- den soil. Carbonate of lime Sulphate of lime Phosphate of lime . . . Oxide of iron 1 Oxide of manganese.. A remark made by Berthier, and arising out of the preceding analyses, is the absence of alumina in the constituent principles of the ashes examined. The results previously obtained by M. de Saussure fully confirm this remark ; and if in some cases traces of alumina were detected, the circumstance was attributed to the clay which might accidentally have adhered to the plants. According to M. Berthier the absence of alumina is probably owing to its insolu- bility in water, and its weak affinity for the organic acids. The solu- ble salts of alumina with mineral acids are, it is well known, unfa- vorable to vegetation, and in an arable soil they could not exist along with calcareous or alkaline carbonates : they would be immediately decomposed. However, alumina appears actually to have been observed in the state of salt in the juices of certain plants : li/copodium arniplanatum^ an infusion of which is employed as a mordant in dyeing, contains tartrate of alumina ;* the same salt has been detected in verjuice ; and as we shall see presently, Vauquelin found acetate of alumina in the sap of the birch-tree. 1 may add, that in a considerable numb({r of analyses of ashes, produced from plants and seeds of my own grow- ing, I always obtained traces of alumina : but I would not venture to affirm that the earth here was not accidental. Silica is met with in only very small quantity in the ashes of wood. It is found, on the contrary, in considerable proportion in the ashes of several annual and biennial plants, and more especially in those of the cereals. Sir Humphrey Davy found silica in the epidermis of the Indian rush. If we compare the ashes of the same species of wood grown in soils of different kinds, we see, says M. Berthier, that they may dif- fer very perceptibly ; which seems to establish the fact that the soil exercises a certain degree of influence on their constitution. Thus oak-wood from Roque des Arcs, grown in a decidedly calcareous soil, yielded ashes almost entirely ODnsisting of carbonate of lime, Berzelios, TraiU de Chimin, t. r. p. 130, French translation. ABSORPTION OF SALTS. 59 while those left by an oak from the department of la Somme, contain- ed much magnesia and phosphate of lime,* Tlie ashes from a white mulberry of Nemours contained mOre than 0.10 of phosphoric acid, while scarcely any traces of it were ftmnd in those of a similar mul- berry from the calcareous soil of Provence. The most remarkable inference deducible from the analyses of M. Berlhier, is that which is connected with the composition of the ashes yielded by trees growing in the same soil. It is observed that, for analogous species, the ashes also bear the closest analogy ; and on the contrary, it is found that trees of very distinct genera yield ashes of quite a dif- ferent quality ; results which lead to this important conclusion, that plants possess the faculty of selecting in the soil the substances which are best suited to their special organizations. This is a point which we shall have an opportunity of discussing, when we come to treat of rotations of crops. The substances composing the ashes of vegetables, are not all in the state in which they existed in the vegetable tissue. In plants there constantly exist organic acids, which, in general, are combined with mineral bases. During the incineration of plants these organic acids are destroyed, and the result of their destruction is an alkaline carbonate, if the pre-existing acid was united with soda or potash ; a calcareous vegetable salt, again, yields carbonate of lime ; and a magnesian salt gives magnesia, from the well-known inability of this earth to retain carbonic acid at a high temperature. Thus, the greater part of the carbonates which enter into the composition of vegetable ashes, are formed by the mere fact of incineration. The Baits which resist the action of a strong heat, as the phosphates, sul- phates, and chlorides, are the only ones which in the ashes retain the state in which they existed in the living plant. Water being the vehicle which must convey the mineral salts from the soil into the vegetable, we do not always perceive how they can penetrate. To explain the presence in plants of a salt so insoluble as the neutral phosphate of lime, M. de Saussure admits, from satis- factory experiments, that vegetable juices contain the double phos- phate of potash and lime, and of potash and magnesia.f Besides, several bodies considered in chemistry as insoluble, are not so abso- lutely. Silica seems to possess a certain degree of solubility, — at least, M. Payen has met with it in considerable quantity in the wa- ter of the Artesian well of Crenelle, and in the water of the Seine. We know, moreover, that several insoluble earthy salts are dissolv- ed in virtue of the carbonic acid always contained in the waters with which the soil is soaked. Lastly, it is not improbable that certain insoluble salts have their origin in the plant itself, engender- ed there by the successive arrival and reciprocal action of soluble Baits. It now remains for us to examine by what means saline substances are introduced into the tissues of vegetables, and within what limits * These ashes were from the carbon of the oak ; the insoluble part gave 0.14 ol phosphate of lime, and 0.08 of magnesia. t Saussiue, Recherches chimiques, &c. p. 321. 60 INORGANIC CONSTITUENTS. the water, which is essential to living plants, may be charged with them ; for it is within what may be called common experience, that saline solutions of certain degrees of concentration, oftentimes act injuriously on vegetation. The spongioles which terminate roots have too close a tissue to allow any thing but fluids to pass through them. All attempts to make them absorb solid bodies in a stale of minute division, and held in suspension in water, have been ineffectual. In these attempts the spongioles have acted precisely like perfect filters, with which those that we employ in our laboratories cannot be compared. Further, the weakest solutions are not entirely absorbed by certain roots ; a kind of separation takes place ; a portion of the dissolved salt ap- pears to abandon the water at the moment of its penetrating the spongiole. This follows from the researches of M. de Saussure, instituted with a view to ascertain, 1st. If plants absorb substances dissolved in water in the same proportion as they absorb water ;* 2dl.y. If plants make a selection among diflferent substances held in solution in the same liquid. t In solutions severally containing eight ten-thousandths (0.0008) of each of the following substances — chloride of potassium, chloride of sodium, nitrate of lime, sulphate of soda, hydrochlorate of ammo- nia, acetate of lime, sulphate of copper, sugar-candy, gum arabic, and extract of humus,J — several entire plants with their roots, of the polygonum persicaria^ (lakeweed or redshanks,) which had lived for some time in distilled water, until their roots had commenced growing, were immersed. The plants lived in the shade during five weeks, throwing out roots in one of the solutions mentioned. They languished, without show- ing any appearance of growth in the solution of hydrochlorate of ammonia, and could only be kept alive in the sugared water, which soon became changed, by renewing it frequently. They died at the end of from eight to ten days, in gum water, and in the solution of acetate of lime. They held out but for two or three days in the water which contained sulphate of copper. Observations precisely similar made on the bidens cannabina pre- sented the same results, with the sole difference, that this plant lived for much shorter times than the redshanks. To estimate in what proportion the substances dissolved were ab- sorbed, relatively to the water, M. de Saussure made use of the solutions previously employed ; but he brought the experiment to a close when the plants had taken up precisely half the liquid which was feeding them. Each solution fed a suflfieient number of plants to allow of this condition being fulfilled in two days. Half of the liquid remaining after each experiment was analyzed, and the quan- tity of salt found therein, showed, by the difference between this and the quantity originally contained, the amount which had pene- trated the vegetable. Representing by one hundred parts the whole * Siuspure, Rocherches chimiques, &.c. p. 247. t Ihid. rage 253. i This entered into the solutions only in the proportion of t\\ o ten-thousai^dtht 0.0002.) ABSORPTION OF SALTS. 61 of the substance originally dissolved, it is evident that fifty of those parts must enter the plant, if the absorption of the saline substances be in proportion to that of the solvent. But the experiment proved, that in taking up half the volume of the liquid, the polygonum had absorbed but — 15 parts of chloride of potassium, 13 (( chloride of sodium, 4 t( nitrate of lime, 14 i( sulphate of soda, 12 (( hydrochlorate of ammonia, 8 u acetate of lime, 29 (( sugar, 9 (( gum. 5 (( extract of humus, 47 (( sulphate of copper. Under the same circumstances the bident took — 16 parts of chloride of potassium, 15 (( chloride of sodium, 8 « nitrate of lime. 10 (( sulphate of soda. 17 (( hydrochlorate of ammonia, 8 {( acetate of lime. 32 (( sugar. 8 (( gum. 6 (( extract of humus. 48 (( sulphate of copper. It follows from these experiments that the plants absorbed some part of the different substances presented to them ; but without ex- ception, they took up the water in greater proportion than the mat- ters dissolved. On multiplying and varying these experiments, M. de Saussure always arrived at the same general results. The plants uniformly took up more of the alkaline than of the calcareous salts, and more sugar than gum, though the quantities of the different substances absorbed varied considerably. The sulphate of copper presented, in the course of these re- searches, an anomaly which is readily explained. We see that this salt, evidently injurious to vegetation, was taken up in a large dose. This arises from its corrosive action on the roots : sulphate of cop- per disorganizes the spongioles ; and these organs once destroyed, absorption takes place with more rapidity and in greater abundance. A root deprived of spongioles is in the condition of a stalk, or branch, the fresh section of which is immersed in a liquid. Obser- vation proves, in fact, that substances in a state of solution, which by reason of their viscidity are incapable of making their way into a healthy root, are, on the contrary, readily taken up by a cut .stalk or branch, in quantity sufficient to dye it deeply, if it was a coloring matter that was presented for absorption. a 62 INORGANIC CONSTITUENTS. In the preceding experiments, the solution contained only a single substance. In those which follow, M. de Saussure dissolved in the water two or three salts, a mixture of sugar and gum, &c., in order to ascertain whether the plants would make any selection from mixed solutions. In 25 fluid ounces of water two or three species of salt were dis- solved, the weight of each species being nearly 10 grains troy. Each ounce of water would therefore contain either iths or '^ths of a grain of saline or soluble matter. As in the preceding experi- ments, the plants were made to absorb precisely one half of the so- lutions. Analysis pointed out the quantity and the nature of the substances which remained in the liquid not absorbed, and conse- quently the salts which had penetrated the vegetable. In reducing this table, which exhibits the results obtained, the weight of each particular salt in the solution is represented by lOO parts. Substances in the solution with which the experiment was made. Weight of the several sub- stances ti'-eu up by the Polygcnun in imbibing one half of the solution. Weight of the several sub- stances taken up by the Bident in imbibing one half the solution. 100 parts 1,7 weight. Sulphate of soda efflores-ed . Chloride of sodium 12 22 7 20 Sulphate of soda effloresced . Chloride of potassium . 12 17 10 17 Acetate of lime Chloride oi potassium 8 33 5 16 Nitrate of lime Hydrochlorate of ammonia . 4 16 2 15 Acetate of lime . Sulphate of copper 31 34 35 39 Nitrate of lime Sulphate of copper 17 34 9 56 Sulphate of soda . Chloride of sodium Acetate of lime 6 10 traces 13 16 traces Gum Sugar 26 34 21 46 M. de Saussure confirmed these results in experimenting on the common peppermint, {mentha piperita,) Scotch pine, and common luniper. The substances absorbed in greatest proportion by the polygonum and bident were also those that were taken up in largest quantities by these plants. ABSORPTION OF SALTS. 63 The section of the roots, even their destruction, favors, as we ^ave already said, the introduction of the matters dissolved. Plants whose roots had been removed, no longer selected the substances dissolvsd in so striking a manner as they did previously ; after muti- latiort they absorbed them almost indifferently, in larger doses, and perceptibly in the same proportion as the water which held them in solution. Roots with their spongioles entire, therefore, suffer one substance in solution to penetrate the plant in preference to another. The chlorides of potassium and of sodium, for instance, find entrance more readily than the acetate and nitrate of lime : sugar more readily than gum ; and precisely as when isolated, are these substances, when combined, absorbed in much less proportion than the menstruum or water of solution. M. de Saussure is not disposed to admit that the preference which plants evince for certain salts, for certain dissolved substances, results from any particular faculty, from any special affinity. He rather inclines to believe that it should be attributed to the degree of fluidity, or of viscidity communicated to the water by the different substances dissolved ; thus the acetate and nitrate of lime, with the same proportion of liquid, form more viscid solutions, which pass with more difficulty through a filter, than the alkaline sulphates and chlorides ; and these latter salts in solution were absorbed by vege- tables in greater abundance than the calcareous salts. Gum, which imparts more viscidity to water than sugar, is also less capable of being absorbed. Finally, pure water, more fluid than any of the solutions tried, was also that which vegetables preferred to any other. In the results of the incinerations which we have mentioned, it is obvious that in many plants salts are met vt^ith in very small propor- tion. This circumstance has induced several physiologists to con- sider the mineral substances found in vegetables as purely accidental, and consequently unnecessary to their existence. M. de Saussure, however, observes that this scantiness is no true indication of their inutility, and he mentions that the phosphate of lime, which forms an element in the organization of an animal, does not probably amount to one five-hundredth part of the entire mass. We shall add, that as the phosphate of lime was met with by M. de Saussure in the ashes of all vegetables which he examined, and as all the analyses performed since the original labors of this celebrated chemist have tended to confirm the accuracy of his general conclusions, we have no ground for supposing that plants could exist without the interven- tion of saline matter. There are annual plants which, when burned, leave more than 10 per cent, of residue ; and vegetables cultivated in soils free from saline or alkaline matter, and watered with dis- tilled water, though they will live and ripen their seeds in some instances, still they never acquire the vigor which they possess when grown in a fertile soil. Duhamel ascertained that marine plants languish in soils destitute of chloride of sodium ; and this is so much the more readily oon- 64 INORGANie CONSTITUENTS, celved, as those plants which furnish ashes abounding ki carbonate of soda, always contain organic acids combined with «he alkaline base. Borage, the nettle, &c., thrive only in places where they meet with nitrates ; and it is easy to discover that plants when dried contain a notable quantity of either nitrate of potash or of lime. The vine more especially requires alkaline dressings, in order that the large quantities of potash taken from the soil in the tartrate of potash of the grape may be replaced. The organic acids, so different in their composition and in their properties, which are met wHh in the different vegetable families, are always found combined in the state of neutral or acid salts. The proportion of base combined in a plant with a vegetable acid may be readily ascertained from the ashes ; for by the effect of incineration the base passes into the state of an alkaline or earthy carbonate. The vegetable acids undoubtedly perform important functions in the organism of vegetables, and their formation probably depends on the nfluence of the bases with which they form salts. The nature of he oxide or base itself appears to be of little importance ; it is enough that it be present in the plant. It is known that certain bases may mutually replace each other, equivalent for equivalent. These principles assumed, Prof. Liebig draws a remarkable in- ference from the composition of the ashes of different kinds of wood ; namely, that for each vegetable family the sum of the oxygen of the bases combined with the organic acids will be a constant number ; or, in other words, the species of one and the same family will con- tain the same number of basic equivalents combined with vegetable acids. Thus, 100 parts of the ashes of a Breven pine-tree, analyzed by Saussure, contain : Carbonate of potash 3.60 Oxygen of the potash 0.41 i lime 46.34 " lirae 7.33V9.01ox. " magnesia 6.77 " magnesia 1.27) Carbonates 77.56.71 The ashes of a pine from Mount La Salle yielded : Carbonate of potash 7.36 Oxygen of the potash 0'85)ooic«- lime 51.Gd " lime 8.10|^'^*°^ " magnesia 0-00 58.55 M. Berthier found in the ashes of a fir-tree from Allevard the following bases : Potash and Soda 16.8 Oxygen 3.42 Lime 29-5 " 8.20 Magnesia 3-2 " 1.20 V12.J One part of the alkalies containing 1.20 of oxygen was combinea with mineral acids, forming sulphates, phosphates, and a chloride The oxygen of the bases combined with the carbonic acid is cpn$e« quently reduced to 11 62. The ashes of a Norway fir, according to the same analyst, con. taining : sa?. 66 .2.40") .1.69 J Potash 14.10 Oxygen iSii:'::::::::::::::::: T^]^ - ::::::::::::::::3:^^^-^^s^ Magne'iia 14.35 " 51.45 In this ash the bases belonging to the inorganic salts contain 1.37 of oxygen. The oxygen of the bases of the carbonates, or in other words of the bases which formed organic salts in the tree, therefore, becomes 11.47. The numbers 9.01 and 8.95 on the one hand, and 11,62 and 11.47 on the other, which represent the quantity of oxy- gen of the whole of the bases in the ashes obtained from plants of the same species, differ so little, that they may be considered as identical. Accurate analyses of ashes of plants of the same species grown in soils of different kinds, will determine, says Prof. Liebig, whether the fact, deduced from the composition of the ashes of the pine and fir-tree, constitutes a definitive law.* Be this as it may, the utility of alkalies in vegetation cannot be a matter of doubt ; many usages in agriculture prove it in the clearest manner; and, according to M. Liebig, the fact of the forma- tion of the organic alkaloides in plants affords an additional proof of it. M. Liebig thinks that the organic alkalies have a particular tendency to form in the absence of mineral bases ; thus potatoes which germinate in cellars, under conditions where the soil cannot supply them with potash, soda, or lime, develop an organic alkali, solanine, which is not found in the tubers of this vegetable as usually cultivated.! In the cinchonas, quinine and cinchonine are combined with quinic acid ; but there is frequently found quinate of lime also. According to the same chemist, the latter base holds the place of a vegetable alkali in the organism ; the more prevalent it is in the soil, the less rich will the cinchona plant be in quinine and cinchonine.^ These ingenious views certainly deserve the careful attention of physiologists ; they are calculated to add new interest to the study of the chemical constitution of the ashes of vegetables. The inorganic substances contained in vegetables evidently come from the soil. By growing seeds, as M. Lassaigne did, in flowers of sulphur, moistened with distilled water, the plant produced con- tained neither more nor less saline and earthy matter than was origi- nally present in the seed. The water absorbed by the roots, then, becomes charged during Its stay in the ground with the various soluble substances which may be met with there, and which generally contribute to its fer- tility ; suck especially are the salts derived from decomposed organic substances. Water charged with small quantities of the soluble substances diffused through the soil, constitutes the ascending sap. When it ha 3 penetrated the plant, immediately after its passage by the spongi.les of the roots, perhaps even while traversing these * Liebig, Chimie Organiqiie, Introduction, p. cxL t Liebig, idem. p. cxiv. t Liebig, idem. ^ ' 6* 66 TEANSITION OF INORGANIC INTO ORGANIC MATTER. parts, the organic matters dissolved in the fluid appear to undergo important modifications; for in the sap substances are detected which could not have existed in the water which moistened the soil. During its ascent the sap increases in density, as was ascertained by Mr. Knight, according to whom, the sap of an acer platanoides^ taken at the level of the ground, has a density of 1.004 ; at 67 feet above it this density becomes 1.008, and at 13 feet, 1.012. From this Mr. Knight concluded that the sap took up nutritive matter deposited in the vegetable tissues which it traversed in its ascent.* We have already seen that the sap, after being elaborated in the green parts of trees, takes a route the reverse of that which it fol- lowed at first, and we therefore spoke of this modified sap as the descending sap. It is very possible that in Knight's observations the liquid examined was a mixture of the two saps. We should not be over hasty in concluding that the action of the two species of sap was exerted separately in promoting the develop- ment of the plant ; it is very probable, as Dutrochet thinks, that the modified sap, by insinuating itself into the permeable tissue of the vegetable, is continually mixed with the ascending sap, in order to concur in promoting the growth of the buds.f The difficulty of obtaining each particular sap separately, if such a separation is reallv possible, prevents the analytical conclusions we have from possess- ing all the accuracy that seems desirable. Vauquelin has studied the sap of the birch- tree, of the hornbeam, of the beech, of the chestnut, and of the elm. The sap of the hornbeam {Carpinus sylvestris) was obtained in the months of April and May. At this period it is colorless and clear as water ; its taste is slightly saccharine ; its odor resembles that of whey ; it reddens turnsole paper. The sap of this tree contains water in very large quantity, sugar, extractive matter,^ and free acetic acid, acetate of lime and acetate of potash, in very small quantity. This sap left to itself presents in succession all the phenomena of the vinous and then of the acetous fermentation.^ The sap of the birch-tree reddens turnsole intensely ; it is color- less, and has a sweet taste. The water which forms the greater part of it, holds in solution sugar, extractive matter, acetate of lime, acetate of alumina, and acetate of potash. Whea properly concentrated by evaporation, it ferments on the addition of yeast, and then yields alcohol on distillation. The pre- sence of the acetate of alumina may appear extraordinary in this sap, for this reason, that alumina has not yet been discovered in the ashes of the birch-tree. Sap of the beech, {Fagus sylvestris ) The analysis was made in Marcli and April. Tlie color of the sap was a tawny red : it had the taste of an infusion of tanner's bark : it reddened turnsole slignt- * Decandolle, Physiologic, t. i. p. 204. t Dutrochet, sur la Structure, &c. p. 36 t Probably azotized. ^ Vauquelin, Annales de Chunie, t. xxxi. p. 90, lire wMm. SAP 67 \y. Il contained, in very small quantity, acetate of lime, acetate of potash, acetate of alumina, extractive matter, tannin acetic acid, ind gallic acid. The sap of the chestnut-tree, according to Vauquelin, who, foi want of a sufficient quantity of the fluid., was able to study it hut very superficially, contains mucilage, nitrate of potash, and the acetates of potash and lime. The sap of the elm was examined at three periods ; first, at the commencement of April, then some days after, and lastly, a month later. At the beginning of April its color was yellow, its taste sweet and mucilaginous ; it was scarcely acid. Analysis indicated : water 1027.90, acetate of potash 9.23, organic matter 1.06, carbo- nate of lime 0.80. At the second period it contained a little more extractive organic matter, and a little less carbonate of lime and acetate of potash. The last examination showed that these two salts had still further diminished in quantity. When exposed to the air, the sap of the elm undergoes decomposition, and becomes alkaline : the acetate of potash passes into the state of carbonate. M. Regimbeau found in the sap of the vine* bitartrate of potash, tartrate of lime, mucilage, and free carbonic acid. The sap of the maple-tree contains a very considerable quantity of sugar. In Canada, this sap, properly treated, yields sugar which is identical with that of the cane. The nature of the sap is subject to variations ; and Duhamel siates, that at a certain season it loses its saccharine taste, and acquires an herbaceous flavor.f Liebig and Will detected the presence of ammoniacal salts in the sap of the maple and birch-tree, and in the tears of the vine. M. Blot examined the sap of a considerable number of trees, and ascer- tained that the sugar in them often exists in two different states ; in that of cane-sugar, properly so called, and in that of grape-sugar, which, as chemists admit, diflfers from the former only in the pos- session of an additional equivalent of water. The saps which M. Biot examined, contained besides some animal matter (albumine) and a gummy matter ; he found no free carbonic acid. The object which he had in view, namely, to study the changes which occur m the nature of sugar, did not lead M. Biot to notice the minute quan- titiv3s of salts with organic acids which Vauquelin met with in saps. The trunk of a walnut-tree, tapped on the 11th of February, fielded a sap containing some cane sugar. The saps of the syca- more, of the acer negundo and of the lilac-tree, contained the same species of sugar; but that of the birch-tree held in solution some grape-sugar. In the sycamore and birch-tree, M. Biot observed an extremely interesting fact. He ascertained, on felling these trees, that the greater portion of the descending sap was accumulated to- wards the middle of the trunk. That of the birch-tree was acid and saccharine ; the sap of that portion of the trunk which waa * Journal de Pharmacie, t. xviii; p. 36. i Annales de 1' Agriculture, Franjaise, t. v. 2eme s6rie, p. 339. B8 TRANSITION OF INORGANIC INTO ORGANIC MATTER. buried in the ground, contained no sugar, but a substance possessing the principal characters of gum.* It was probably an effect of the season ; for Knight states, that he never could discover the least trace of saccharine matter during winter in the alburnum either of the stem or of the roots of the sycamore. f SAP OF THE BAMBUSA GUADUAS. The guaduas grow-s in the hot and marshy countries of the tropi- cal regions : this grass frequently attains the enormous height of from 65 to 100 feet. Its stem, which is hollow, is divided through its entire length into joints spaced rather regularly at distances of from 11 to 12 inches. Each joint indicates ihe presence of a woody partition, which seems to divide the stem of the guaduas into so many super-imposed tubes. On perforating it immediately above a knot, a clear limpid fluid flows out, which cannot be distinguished from the purest water. This indeed is a store of water of which travellers have frequently availed themselves. This sap, as I have been assured by the inhabitants of the countries where I observed the guaduas, never completely fills the hollow space included be- tween two joints. Analysis satisfied me that the sap of the guaduas is almost pure water. Re-agents detected merely traces of sulphates and chlorides. On evaporating a considerable quantity of it, I was able to discover, independently of these traces of soluble salts, a very small proportion of organic matter and of silica ; the latter sub- stance is probably the element which predominates in the sap of the guaduas. SAP OF THE BANANA PLANT, (mUSA PARADISICA.) The sap of the banana possesses a well-marked astringent taste : It reddens tincture of litmus. Immediately after escaping from the plant, it is limpid and colorless, like water ; nevertheless, it possesses the property of imparting a yellow color to stuffs immersed in it. Exposed to the air it becomes turbid, and throws down flocculi of a dirty rose color. It is to the action of oxygen that this deposite is owing ; for it takes place only in contact with the air. After the formation of this deposite, the sap no longer colors stuffs immersed in it. From a chemical examination which I instituted of the sap of the banana, during my sojourn on the banks of the Magdalena, I think I may state that it contains gallic acid, acetic acid, chloride of sodium, salts of lime and potash, and silica. The sap of vegetables, elaborated during its passage through the leaves, acquires additional consistence. It generally contains pecu- liar principles, which are the result of this elaboration, and these now constitute the liquid which is usually designated by the name of ihe particular juice of the plant from which it is procured. Thia • Annales du Mus6um d'Histoire Naturalle, t. il. ^ Knight, quoted in Annales de rAgriculttue Franf aise, t ▼. 3e t^rie, p. 338 SAP. 69 proper juice or sap is generally obtained by making an incision which penetrates a little below the bark. The characters and properties of the elaborated or descendingrsap. are extremely various. It may, however, be divided into milky sap^ saccharine sap, gummy sap, and resinous sap, according to the na- ture of the juices dissolved or .suspended in the liquid. As several of the peculiar juices of vegetables contain principles employed in the arts or in medicine, they have been more carefully studied, and their history is more complete than that of the ascending saps. I do not propose to give a monograph of these juices ; in this place I shall only mention those which have been examined with some care. MILKY SA.PS. The milky saps, as their name indicates, have the appearance of milk ; they owe this milky appearance to globules of insoluble mat- ter, minutely divided, and suspended in a liquid. SAP OF THE PAPAW-TREE, (CARICA PAPAYA.) The carica papaya grows in tropical regions. The sap, which is extracted from the fruit by incision, is white, and excessively vis- cous. In a specimen of this sap, which came from the Isle of France, Vauquelin found water in large quantity, and also a matter having the chemical properties of animal albumen,* and lastly fatty matter. I took occasion to verify the correctness of the results obtained by Vauquelin, on the milk of the fruit of the carica papaya, during my sojourn at Caraccas, where I examined the sap which flowed from the trunk of the tree itself. This sap is less milky, and much more fluid than that which flows from the fruit ; it had the appearance of milk-and-water. Its odor is rather nauseating, even when coming from the plant ; its taste slightly sour. When exposed to the air it soon coagulates. It contains a considerable portion of matter, which may be compared to animal fibrine, and sugar, wax, and resin, in small quantities. Evaporated and burnt, it leaves a saline residue. This juice is employed by the inhabitants for medical purposes. SAP OF THE COW-TREE. Among the number of astonishing vegetable productions observed in the equinoctial regions, is a tree which yields a milky juice in abundance, similar in its properties to the milk of animals. At the time I left Europe, M. de Humboldt expressly recommended me to di- rect my attention to the milk of the cow-tree. A short time after my arrival in the Cordilleras, on the shore of Caraccas, M- Rivero and myself were able to comply with the wishes of the distinguished traveller.! The milk we examined came from the Palo de Lechc, the milk- tree, which is extremely common in the environs of Maracaibc. * Vauquelin, Annales de Chiinie, t. xlix. p. 219, Ire s*rie. t Bivero and Boussingault, Annales de Chim. et de Phys. t. zzxUi. p. 229, 2e uixit 70 FRANSITION OF INORGANIC INTO ORGANIC MATTER. Vegetable milk possesses the same physical characters as that of the cow, with this sole difference, that it is, in a slight degree, vis- cous ; its flavor is agreeable, slightly balsamic. With respect to chemical properties, these differ perceptibly from those which are peculiar to animal milk. Acids do not curdle it ; alcohol scarcely coagulates it. Under the action of gentle heat, light pellicles are seen to form on the surface of vegetable milk. On evaporating it over a water bath, an extract is obtained resembling fritters ; and if the action of the fire be continued for a certain time, oily drops are observed, which increase in proportion as the water is dissipated, and ulti- mately form a liquid of an oily appearance, in which a fibrinous substance floats, which dries and becomes tough in proportion as the temperature increases. An odor is then diffused, exactly like that of meat frying in fat. By the mere action of heat, then, the milk of the Palo de Leche is separated into two distinct portions : the one fusible, of a fatty nature, the other fibrinous, and presenting all the characters of ani- mal substances. If the evaporation of vegetable milk is not carried too far, i«e fatty matter may be obtained unchanged ; it then possesses the fol- lowing properties ; — it is white, translucent, sufficiently solid to resist the impression of the finger ; it fuses at 140° (Fahr. ;) boiling alcohol dissolves it completely ; it is equally soluble in potash. The fibrinous matter presents all the characters of fibrine, obtained from the blood of animals ; for this reason we have called it fibrine. In fact, when put on a hot iron, it swells up, fuses, and becomes carbonized, exhaling the odor of grilled meat. Treated with weak nitric acid, it gives out nitrogen gas ; by distillation, it disengages ammoniacal vapors in abundance. The presence and nature of this animalized matter in the milk of the cow-tree, explains how this milk acquires the odor of old cheese on becoming changed. We considered the fatty matter of the milk as analogous to beeswax ; I may even say that we made wax-candles of it. However, the property of being completely dis- solved in hot alcohol, combined with its ready solubility in potash, establish a well-marked difference between it and the wax of insects. This is a question which can only be completely cleared up by ele- mentary analysis, and we were altogether without the means of making any minute examination of the wax of vegetable milk. In the water which holds the wax and animal matter in suspension, we met with some saline substances and a free acid, the nature of which we were unable to determine. We did not succeed in detect- ing the presence of caoutchouc in vegetable milk. According to our researches this milk should contain : 1. A fatty substance similar to beeswax ; 2. An animal substance, similar to animal fibrine ; 3. Water, salts, a free acid, and a little sugar. SAP. 7 By incineration, we obtained ashes from the milk in which wer* found phosphate of lime, lime, magnesia, and silica. During their excursions in the Cordilleras, the inhabitants fre quently drink the milk of the cow-tree. M. de Rivero and mysell also used it during our sojourn at Maracaibo. The tree which produces the milk which we examined, is, accord ing to M. de Humboldt, the galactodendron dulce, of the family of the verticas, or fig-trees. But several trees are known in tht mountains along the coast, which yield a milky juice, and which are often confounded with that just described. For instance, in the environs of Maracaibo, according to M. Desvaux,* the clusia galac- todendron yields an abundance of very pleasant vegetable milk ; this milk, however, does not seem to contain much animalized matter; at least it does not putrefy perceptibly, and instead of the waxy matter, a substance much less fusible and of a resinous character is procured from it. MILKY SAP OP THE HURA CREPITANS, (aJUAPAR.) The sap of the hura crepitans is dreaded, and not without good reason ; it is enough to be exposed to the emanations of this milky juice, when recently extracted, to be seriously affected by it. The use which is made of it, to poison the water of rivers, in order to obtain the fish, is a suflUcient indication of its pernicious qualities.! This vegetable sap would perfectly resemble that of the cow-tree, if it were not slightly yellowish. It has no smell ; its taste, which is very little marked at first, soon causes very violent irritation. It reddens the color of turmeric ; mineral acids produce in it a white and viscous curd ; the surrounding fluid is clear and of a yellow color. Left to itself, the milky sap of the hura crepitans yields all the products of the putrefaction of caseum. It contains: 1. An azotized substance similar to gluten, or caseum. 2. A vesicating oil, 3. A crystallized substance, having an alkaline reaction. 4. Malate of potash. 5. Nitrate of potash. 6. A salt of lime, (the malate ?) 7. An odorous azotized principle. MILKY SAP OF THE POPPY, (oPIUM.) The milky sap which, by concreting, furnishes the opium of com- merce, is obtained by making longitudinal incisions in the capsules of the poppy. The operation takes place before the fruit is ripe, and after the fall of the flower. * Benseignements communiques par M. Adolphe Brongniart. t Bivero et BoiHsinguult, Aimales de Chim. et de Phys. t. xviii. p. 430, 2e s6rie. What 1 shall no.v state may give an idea of the energy with which this milky juice acts on the animal economy : when M. Bivero and myself examined the milk of the hura crepitant, we became affected with er>-sipela8 ; the afiection continued for sev- eral days. The milk had l>een sent to us in guaduas by Dr. Boulin ; the messenger who brought it was seriously affected byit ; and along the road the inhabitants of tb« kouses where he lodged felt the same effects. 72 TRANSITION OF INORGANIC INTO ORGANIC MATTER. The concrete sap is brown, firm, of an acrid and bitter taste, and of a peculiar sickening odor. Opium contains a number of principles the study of which has exercised for a considerable time the inge- nuity of the most skilful chemists. It was in this substance that Sertuerner found the first vegetable alkali which was discovered, morphine. After numerous trials made on opium, it was found to contain : — 1. Morphine, (vegetable alkali.) 2. Codeine, (the same.) 3. Narceine. 4. Meconine. 5. Para-morphine. 6. Pseudo-mor- phine. 7. Meconic acid. 8. Resin. 9. Fatty matters. 10. Caout- chouc. 11. Gum. 12. Bassorine. 13. Ulmine. 14. Woody sub- stance. 15. Mineral salts with bases of lime, magnesia, and potash. MILK OF THE PLUMERIA AMERICANA. The plumeria, 'when one of its branches is broken, yields a con- siderable quantity of milky juice. At the time when I examined this juice, the tree was entirely destitute of leaves. The milk of the plumeria is perfectly white ; it is very fluid when it flows from the plant, but soon after deposites a crystalline sediment. The taste is slightly bitter, and it has an acid reaction. The milk of the plumeria appears to contain no animalized matter. I was only able to detect a very large proportion of resinous matter held in solution or sus- pended in water ; and indications of potash, lime, and magnesia, combined with an organic acid. SAP OF THE CAOUTCHOUC TREE. Caoutchouc is found in the sap of many trees, and in that of a great number of herbaceous plants ; but it is the havea caoutchouc, the jatropha elastica, peculiar to South America; the ftcus Indica, and the artocarpus integrifolia, which grow in the East Indies, that yield the caoutchouc so well known in commerce, and which has been converted to so many useful purposes in the arts. The caoutchouc tree is particularly common in Choco and forests near the equator. To obtain the elastic gum, the Indians incise the tree below the bark, when there issues a copious discharge of milky sap, which will remain fluid for a considerable lime, if it be kept from contact with the air. I have seen it carried to great distances, in wooden vessels hermetically closed. When spread out in thinnish layers, it soon coagulates, and acquires the singular elasticity which characterizes caoutchouc. The action of the oxygen of the air may possibly have some influence in producing this coagulation, un- less what I am about to state be the effect of a prompt evaporation of the water of the sap. I have often made a small incision in the trunk of an hcEvea from which milk immediately flowed, and by rea- son of its viscidity, trickled down the tree in a stream of a certain thickness ; this milk was at first extremely fluid, but after from one to two minutes' exposure to the air, it suddenly coagulated, so that on raising the drop from the lower end, I obtained a long string or riband of perfectly elastic caoutchouc. SA?. 73 In Guiana the Indians fashion the caoutchouc into the bottles which are so common in trade : they make a clay mould, and this they cover by immersing it in the milk freshly drawn from the tree ; they allow it to coagulate, which it does very speedily, especially if it be exposed to the smoke of a wood fire. This first layer being coagulated, they c(mtinue the same process until the desired thick- ness is attained. The mould is then broken and taken out piece meal from the interior of the caoutchouc bottle which has been formed. The workmen of Quito, who are very dexterous in manufacturing caoutchouc, make shoes and buskins of it, by applying it in the milky state over moulds of the proper fashion. They also render tissues impervious by spreading it in the same state between two pieces of stuff or cloth; the interposed milk becomes coagulated, and forms a thin elastic lamina, very preferable to the caoutchouc applied by the aid of solvents. The Indians of Choco sometimes procure this substance by felling the tree, and receiving the milk, which then flows in a stream, into large wooden moulds, generally formed from a hollow stem of the guaduas. By keeping the mould open, the milky mass coagulates after some time. Several of these masses of caoutchouc, which were brought to me by the Indians of the Chami nation, were but slightly elastic ; their color also was extremely deep. It is probable, that by proceeding' in this way, the milky juice is mixed with large quantities of the internal sap which is much less milky. Several trees in the valley of the Magdalena which bear the name of caoutchouc, which, however, are neither the hoevea, nor the ja- tropha, also yield a coagulable juice, which may be confounded with the elastic gum ; it is, I believe, caoutchouc combined with a large quantity of wax, and probably also of resin; this caoutchouc pos- sesses but little elasticity. M. Faraday found in the milk of the hcevea, in 100 parts : Water 56 Caoutchouc 32 Bitter azotized matter soluble in water and alcohol 7 A substance soluble in water and alcohol (sugar) « 3 100 As this milk will remain fluid for a considerable time, provided it ne protected from the air, advantage has been taken of this property to convey it to Europe. It is sent in well-filled, hermetically-sealed bottles. GUMMY AND RESINOUS SAPS. I place under this head the saps of those trees which yield gum from incisions in their trunk, as the acacia vera and acacia Arabica^ which grow in Arabia, and from w^hich gum-arabic is obtained ; acacia Senegal, which also furnishes a species of gum. In general, in very warm countries, the mimosas produce gummy matters in abundance. The elaborated sap of the coniferae and terebinthaceae consists ihiofly of resinous matter, dissolved in an essential oil cbmposed of 7 74 TRANSITION OF INORGANIC INffO ORGANIC MfLTTER. carbon and hydrogen, similar to the essence of turpentine. The balsams of Peru and Tolu are obtained by incising the bark of the trees which produce them. In Choco, where I have seen numerous incisions made in the lower part of the trunk of the Tolu trees, the balsam flows slowly, on account of its thickness ; it does not, ap- parently, contain any water. SACCHARINE SAPS. The sap of the fraxinus amu*, and that of the fraxinus rotundu folia, yield manna on drying or becoming thick. The sap of several palms contains a considerable quantity of saccharine matter. At Java, for instance, crystalline sugar is extracted from the arenga saccharifera. In several places, the sap of palm-trees is subjected to fermentation in order to prepare vinous liquors. The Cocos butyracea {palma de vino) is very common in the valley of the Rio-Grande de la Magdalena. From a superficial examina- tion which I made of it, its sap contains sugar, an azotized matter, and some soluble salts. By fermentation, it produces a vinous liquor sufficiently alcoholic to produce intoxication. In order to procure it, the natives of Benadillo first fell the tree, taking care, when it is down, to give the trunk a slight inclination from the summit towards the lower extremity or foot. They then make a hole towards the base of the trunk suf- ficiently large to hold from fifteen to eighteen pints, the orifice of which they plug up with leaves. The woody tissue, to all outward appearance, contains but little moisture ; but in ten or twelve hours after the operation, the cavity is found full of a liquid, of a well- marked vinous odor, and of a sourish taste, owing probably to the carbonic acid which is disengaged in large quantity. The wine thus obtained is rather agreeable. A palm-tree of from 50 to 60 feet in height, and of which the trunk towards the base is from 20 to 24 inches in diameter, will yield from twenty to thirty pints of wine in twenty-four hours during ten or twelve days. The wine must not be allowed to remain too long after it has collected, otherwise it becomes sour. Sugar is far from being the only useful substance afforded by palms. There are several of these trees which are truly astonishing by reason of the many important uses to which they may be applie- ; and it is not without reason that the missionaries have styled the palm, the tree of Providence, the bread of life. Such more espe- cially is the Cocos maurilia, which grows in the plains of the Apure and Oronoko ; its young shoots serve as aliment ; from its fruit, while still green, a farinaceous food may be obtained ; and when perfectly ripe, it yields oil in abundance. Hammocks and various kinds of cloth are made of the fibrous portion of the bark of this tree ; the young leaves serve to make hats, mats, and sails for ships ; the tissue which surrounds the fruit furnishes the Indians with clothing ; the sap ferments and yields wine ; the trunk before fruc- tification contains an amylaceous marrow, of which bread is made ; tki» marrow, on becoming putrid, produces a vast multitude of larg« CHEMICAL CONSTITUTION OF VEGETABLES. 75 white worms which the Indians value as a most delicate dish ; finally, the woody part of the mauritia aflfords excellent timber for building. It is not necessary to enumerate farther the principles produced by vegetables ; we must now study them in reference to their ele- mentary composition. CHAPTER II. OF THE CHEMICAL CONSTITUTION OF VEGETABLE SUBSTANCES From the very first period of vegetable life, during germination, the immediate principles which constitute the seed are destroyed or changed. The young plant, in developing its organs, creates new substances, which are added to the tissues already existing, so as to complete or extend them. In order to account for the productions or changes which take place in the organism of vegetables, it is ex- pedient first to study the intimate nature and general characters of the materials which compose them. Unfortunately, in the present state of science, this study is as yet but little advanced ; and, not- withstanding the eflTorts which chemical physiology has made in recent times, there still remain numerous and important questions to be solved. Carbon, hydrogen, oxygen, azote, combined in some cases with minute quantities of sulphur or phosphorus, are the only elements required by nature to give rise to that almost endless variety of vegetable substances, so different in their properties, as well as in their uses. In the food which sustains the life of animals, as in the virulent poison which destroys it, these same elementary bodies are always found combined in various and dissimilar proportions. The immediate principles of the vegetable kingdom may be divided into three groups, if we look to the number of the elements which constitute these principles as they exist in the several bodies : 1°. Quartcrnari/, containing carbon, hydrogen, oxygen, azote. 2°. Ternary, containing carbon, hydrogen, oxygen. 3°. Binary, containing carbon and hydrogen, or carbon and oxy- gen, or carbon and azote. It is by the examination of the immediate principles which exist m the seed, that we should approach the study of the composition of vegetables ; and this the more, as we shall find these principles diffused throughout the organs of plants. Once we shall have fully considered their properties and their elementary composition, it will be sufficient merely to indicate where they are to )e met with in the organism. 76 CHEMICAL CONSTITUTION OF VEGETABLES. § 1. QUARTERNARY AZOTIZED PRINCIPLES OF VEGETABLES. It has now for some considerable time been ascertained that several seeds contain azote, inasmuch as azotized matters, nearly similar to those obtained from the tissues of animals, can be extract- ed from them. M. Gay-Lussac expressed this fact in the most general manner, by laying it down "as a law that every seed contains a principle abounding in azote.* Azotized animal matters, when heated in close vessels, yield an ammoniacal product ; and to satisfy ourselves of the generality of the law laid down by Gay-Lussac, all that is necessary is to subject any seed whatever to dry distillation. We do not always, indeed, obtain an ammoniacal liquor hnmedi- ately in this way ; rice, for instance, when heated in a retort, yields a product having an acid reaction ; but it is easy to demonstrate in the acid liquor, the presence of ammonia by the addition of lime, which at once sets it free. Peas, kidney-beans, in a word all the legutnens hitherto experimented on, yield a liquor directly, having a highly alkaline reaction. These differences, in the products of the dry distillation of seeds, are explained in a very natural way. Throwing the husk out of the question, we may consider a seed a? formed of two parts ; one, non-azotized, possessing a ternary com- position, and yielding by the action of heat a liquid with an acid re- action ; the other having a quarternary composition, consequently azotized, and yielding an ammoniacal liquor, so that the acid or alka- line reaction of the product, really depends on the predominance of one or other of these two distinct ingredients. M. Gay-Lussac subjected every kind of seed he could procure to distillation, and all yielded ammonia either directly or indirectly. I shall add, that the numerous analyses which I have had occasion to make for several years back support the generality of the principles laid down by the above celebrated chemist. M. Payen has come to the same conclusion, and has further shown that at the period of germination the azotized matter of seeds is determined towards the parts that are most recently organized. Thus the spongioles situ- ated at the extremities of the radicles constantly produce ammoniacal vapors during their destructive distillation by heat, even though pro- ceeding from seeds which, when distilled, yield an acid liquor where- in ammonia only becomes sensible on the addition of lime. f The animalized or azotized substance is extracted readily enough from certain seeds, and has consequently been known to exist in them for a very long time. It is found in wheat, for example, in dif- ferent states, and is obtained with great ease by simply kneading a mass of dough under a small stream of water by which the starch is carried off, and by and by there remains in the hand a grayish highly • Gay-Lussac, Annales de Chimie et de Physique, t liii. p. 110, 3e s6rie t Payen, M^moire sur la cooipoaitioa chimique des v6g6taui, p- 7. AZOTIZED PRINCIPL5S. 77 elastic substance of a peculiar heavy odor; this is the gluten of chemists. By this simple process of analysis, however, we are en- abled in many cases to estimate the quality of a sample of flour with reference to its richness in gluten, a substance which is rightly considered as the most essential among the nutritive elements of the cereals. The washings collected and allowed to stand, soon become clear: the starch which was suspended in the liquid subsides, accompanied by flakes of an animalized matter. If the clear liquor be decanted and boiled, a white froth appears upon its surface, which, skimmed off, is found to have the appearance of coagulated white of egg, and which, in fact, has all the characters of animal albumen. The water from which the albumen is solidified, necessarily contains all the soluble substances of the flour. On evaporation, it leaves substances similar to gum and sugar, and traces of saline matters. With the exception of the starch, which contains very little for- eign matter, the different substances obtained by this process of washing are far from being in a state of purity. I have said that all seeds contain fatty substances, but in the products of the operation just described, no oily matter was detected. As it cannot be discov- ered in perceptible quantity in starch, nor in the substances soluble in water, it must remain attached to the gluten ; and this is actually the case. The gluten, the coagulated albumen then, are not pure proximate principles ; fiit or oil may be obtained from them ; and further, by examining common gluten carefully, we learn that it con- tains several azotized substances, which differ from one another. By boiling crude gluten with alcohol we ultimately obtain a fibrous gray- ish residue, called by M. Dumas vegetable fibrine. On cooling, the alcoholic liquor lets fall a substance which in its properties resembles the caseum or curd of milk. Lastly, if the cold alcoholic solution be concentrated, a pultaceous substance separates from it, called by Messrs. Dumas and Cahours glutine. Analysis, accordingly, indicates the presence of four azotized sub- stances in wheat ; and when these are all combined in the mass of gluten obtained by washing a lump of dough, they retain fatty mat- ters, from which they may be freed by means of alcohol and ether. The following, according to MM. Dumas and Cahours, is the com- position of the azotized principles of wheat, dried at 140 centig. (284" F.)* Carbon. Hydrogen. Azote. Oxygen, Uulph. awt fho^piiorus. Fibrine 53.2 7.0 16.4 23.4 Albumen 53.7 7.1 15.7 20.5 C iseine (caseum) 53.5 7.1 16.0 2:^.4 Glutine 53.3 7.2 15.9 23.6 Legumine. Some vegetables, particularly some seeds, contain a substance different from any of those just described. This M. Bra oonnjt was the first to notice in the seeds of the family of the I^e guminosae, and it has been since detected by Dumas and Cahours ia Dumas et Cahours, Annales de Chimie el 1e Physique, p. 390, 3e s6rl». T8 CHEMICAL CONSTITUTION OF VEGETABLES. many different seeds. Legumine, which plays an important part in the nutrition of animals, is obtained by digesting a quantity of pea or bean meal, 3x crushed peas or beans in tepid water for two or three hours ; the pulp is then pounded in a mortar, and afterwards mixed with its own weight of cold water ; after one hour's macera- tion it is pressed through a cloth. On standing, the liquid throws down some fecula. Filtration is employed to have the liquor per- fectly clear ; upon which a quantity of acetic acid diluted with from eight to ten times its weight of water is gradually added, when a snowy flocculent precipitate^ of legumine falls. This is collected in a filter and washed with water ; the legumine is then treated with alcohol, dried, and pulverized, preparatory to digestion in ether, in order to free it from fatty matters. Legumine thus prepared has a pearly or lustrous appearance. It is insoluble in alcohol and ether. Cold water dissolves it in large quantity. On boiling the watery solution, legumine is coagulated and falls in flocculi analogous to those formed by albumen under the same circumstances. Weak hydrochloric acid throws down legu- mine from its watery solution like the acetic acid ; the concentrated acid, again, dissolves it, acquiring a violet tint, a character which also belongs to albumen ; but that legumine is actually distinct from albumen is proved by the circumstance of its being precipitated by phosphoric acid with three atoms of water, which albumen is not. The alkalies dissolve legumine at common temperatures. COMPOSITION OF LEGUMINE, OBTAINED FROM DIFFERENT SEEDS.* Carbon.... ^< II Is M 1 S?2 .-si 50.9 5n.!> 50.7 50.8 50.7 50.5 50.5 .50.7 Hydrogen.. 6.7 6.7 6.7 6.7 6.7 6.9 6.7 6.8 Azote .... 18.8 18.6 18.8 18.6 18.8 18.2 18.2 17. 6 Oxygen.... 23.6 23.8 23.8 23.9 23.8 24.4 24.6 24.9 100.0 100.0 J 00.0 100.0 100.0 100.0 100.0 100.0 The'W same azotized compounds, or substances differing but little from theri, are very probably those that are now recognised as dis- tributed through the whole body of every vegetable. M. Payen, alter having ascertained the presence of these substances in the radicles and spongioles, proved it in nearly all the organs. The examination was extended to a great number of species of different families. The ascending sap of a fig-tree, {Jicus carica,) that of the lime-tree, of the black poplar, of the vine, have all yielded ammoniacal vapors under the influence of fire ; so also do the buds, the young leaves, the stigmas, the anthers, &c.t Thus, according to M. Payen, the nutritious juices which ascend from the extremities of the radi- cles to the terminal points of the leaves, carry an azotized principle • Dumas et Cahours, Annaies de Chimie et de Physique, t vL, p. 423, 3c s^rl*. t F&yeot M^imoire mr les d^veloppemens des v^taux, p. 3& QUARTERNARY OR AZOTIZED PRINCIPLES. 79 which accumulates in all the growing organs, at the same time ib.at it is deposited within the entire extent of the canals which the sap traverses. It might, therefore, be supposed that in the latter situa tion the azotized substance was associated with matters of ternary constitution, so as to form membranes and tissues. But from the various organs of the many species studied, M. Payen succeeded in dissolving out, by means of alkalies, and entirely eliminating the animalized substances, without causing the slightest rent or erosion in the tissues perceptible with the microscope ; whence it may fairly be concluded, that if these substances everywhere and always accompany the young tissues of plants, they still form no integral part of them.* The animalized matter seems consequently to pre- serve a kind of independence with reference to the organs which secrete, which convey, and which contain it ; it preserves a sort of mobility which allows of its displacement. And it was in fact neces- sary that this should be so ; for as the period of maturity approaches we see the azotized substance carried more particularly towards the generative organs, and finally become fixed, as it were, and accumu- lated in the seeds. I have had frequent occasion to satisfy myself that the trefoil, the red beet, the turnip, &c., contain much less azote after ripening their seeds than they did previously ; and all husbandmen know that the straw or refuse of plants that have run to seed, forms very indifferent fodder for cattle. The cambium^ that peculiar globulo-cellular matter which is con- stantly found accumulated where the vegetable is forming woody tissue, contains, according to MM. Mirbel and Payen, the same azotiaed principle of an animal nature, in conjunction with ternary substances, whose composition, as we shall presently see, is repre- sented nearly by carbon and water.f As the cellular tissue is evolved at the expense of the cambium, the animalized matters show a tendency t6 quit the consolidated organ. The departure of these matters at the epoch of the growth of the cells, explains satisfactorily wherefore the interiors of old trees contain but a few thousandths of azote, while all the organs of recent formation always contain several hundredths. With the assistance of chemical analysis it is possible to follow the appearance and the removal of the azotized matter ; thus in the alburnum and wood it is observed to diminish in quantity from the circumference to the centre ; this diminution is also observed in the branches, proceeding from their extremities ta their point of junction with the trunk. * Payen, M6inoire sur les d6veloppemens des viS'g^taux, p. 42. f De Mirbel et Payen, Comptes rendus de TAcad^uiie des Science.s, t Kri. p. 98L f CHEMICAL CONSTITXTTION OF VEGETABLES. § II.— PROXIMATE PRINl iPLES WITH A TERNARY COM. POSITION. OF STARCH. Starch is contained in the cells of vegetables under the form of small white granules which have no crystalline structure. In the year 1716, Leuwenhoeck ascertained that these granules were globular bodies more or less regular in their contours. He believed that he could perceive each globule enclosed in an envelope, a kind of sac different in its nature from the matter which it con- tained. M. Raspail, a few years ago, confirmed by his own re- searches the observations of Leuwenhoeck ; he further attempted to measure the diameter of the globules in different kinds of starch, and came to the conclusion that their capsule is insoluble, and that it is the internal part alone which is soluble in hot water.* Since then MM. Payen and Persoz have ascertained that if the globules of starch be really surrounded by a capsule, it must he present in a quantity scarcely appreciable — a quantity not exceeding joVo^h of the weight of the starch. Tiiese first researches were followed by the subsequent observations of M. Payen, who has devoted him- self to the study of the amylaceous principle with a zeal and perse- verance which must secure him the gratitude of chemists and physi- ologists. M. Payen has examined a vast number of fceculae microscopi- cally ; the largest granules he observed were obtained from one of the varieties of potato, from the menispermum palmatum, and the carina gigantea. The globules of starch frequently exhibit a polyhedral appearance, a figure which evidently results from their mutual pressure as they have lain in the cells of the vegetable. Notwithstanding a great general analogy of form, the granules of the starch of different species of vegetables sfill present peculiar physiognomies, so that they can be distinguished in many instances by the practised eye. A character common to the majority of foeculae, however, is round- ness of contour, when their panicles have not been compressed by their contact in contiguous cells. Microscopical and chemical researches alike show that starch is homogeneous in properties, as in composition ; that its globules are composed of concentric layers, the external of which have exactly the same characters as the internal layers. f In the natural state, starch is insoluble in water and in alcohol ; it is very ductile, and under the influence of certain agents it exhibits a great degree of contractility. Feculas retain water with considerable force ; the quantity re- In 1812, Villars, in a paper on the structure of the potato, had already eitiinated the volume of the globules of different kinds of starch, t Frit2xhe, Aaniles de Poggendoif; t. ti^^. p. jsa. I TEBNARY PRINCll'LES STARCH. 81 tained varies with the temperature at which the drying was accom- plished. Thus the feeuhi of the potato, which is moist and porous, even when subjected to strong pressure, still retains 45 per cent, of water. This is the green or raw starch of manufacturers. Dry starch is very hygrometric. If after being dried it is placed in an atmosphere saturated with moisture, at 20° centig. (68° Fahr.) it will absorb nearly 36 per cent, of water, and its hulk increases in the ratio of one to one and a half; in this state starch is brilliantly white, and its grains adhere so closely that they foim a mass of sufficient firmness to take the impress of a seal ; starch in this state, however, pressed upon paper yields no perceptible trace of moisture ; it is too hard and adherent to pass through a sieve ; and when thrown on a metal plate heated to 125° (257° Fahr.) its particles im- mediately unite and form a cake. The starch of commerce, in the state in which it is usually found in shops, contains 18 per cent, of water ; it is either pulverulent or readily reducible to powder, though by slight pressure in the hand, it may be formed into a mass or ball. After drying in vacuo at the ordinary temperature, starch retains no more than 10 per cent, of moisture ; a temperature not less than 140" (284° Fahr) is required to dry it completely ; the water which it retains at this temperature belongs to its constitu- tion, and cannot be taken from itexcept by combining it with bases.* MM. Collin and Gaultier de Claubry discovered the important character of starch, that of yielding a fine blue or violet color on combining with iodine. f According to M. Payen, the color is more intense, nearer to blue and more lasting, in proportion as the starch is more strongly compressed ; the effect of separation is to turn the blue to shades of violet which approach redness as the substance is looser. The same fecula, according to the degree of its aggregation in plants, is seen to assume shades, which are first reddish, then violet, and eventually of a more decided blue color, under the action of iodine. J M. Lassaigne has noticed a very curious property of the combina- tion of iodine and starch : if an amylaceous fluid, having the decided blue color, be heated to 89° or 90=" C. (193° or 194° Fahr.) the solu- tion becomes completely blanched ; but it resumes its former tint as the liquid cools.^ This property which starch possesses of striking a blue color with iodine, renders one of these bodies an excellent test for the other. However, as the iodine must exist in the free state to produce its effect, it is necessary, when the blue color does not show itself at once, in a solution in which iodine is suspected, and to which starch has been added, to add a few drops of sulphuric acid, so as to decom- pose the hydriodic acid in cases where it may exist. It is familiarly known that if raw starch be mixed with boiling water, the result will be a thick, paste-made starch. According to • Payen, W6moire citt, p. 88. t Collin et GaiUhier de Claubry, Annales de Chimie, t. xc. p. S8 i Payen, M6moire cite, p. 105. i Lassaigne, JoiiraaKde Chimie M^dicale, t ix. p. 51Q. 82 CHEMICAL CONSTITUTION OF VEGETABLES. M. Payen, the change tliat takes place in the state of the fecula it owing to a swelling, a rupture, or disgregation of its granules. By heating a drachm cf starch, mixed with about a couple of ounces of water, to about 00° cent. (140° Fahr.) the microscope shows us that the smallest or youngest gVains — those possessed of the least cohe- sion— have absorbed a considerable quantity of water, and that the expansion of the contents has caused a certain number of the glo- oulds to burst ; at this temperature, however, some grains of fecula are observed, which do not appear to have yet attained their maxi- mum of enlargement, and whose contents consequently are not yet diffused -through the liquid ; it is only between 72° and 100° cent. (161.6° and 212° Fahr.) that the maximum of expansion becomes general, and that the solution acquires its greatest consistency.* The remarkable property possessed by starch of making a gluti- nous solution or thick paste with water under the influence of heat, led M. Payen to conjecture that a contrary effect would be produced by lowering the temperature — that the starch might be recovered in its original state of distinct globules by suitable management : and this he in fact accomplished by an ingenious procedure. Starch appears to suffer no actual change when diffused in water by exposure to a temperature of 212° Fahr. ; the granules have only swollen to about thirty times their original dimensions by the imbibition of a large quantity of water. We have already seen how starch may be extracted from wheat- en flour ; this method, however, is not the one that is usually followed to procure this useful substance, so large a quantity of which is consumed in the arts. Formerly, starch was universally obtained from grain, — wheat ; at present the potato furnishes a still larger quantity than grain. In the equatorial regions of South America, starch is aoundantly prepared from the YucOy (Jatropha manihot,) and from several species of palm. To obtain starch from wheat, the grain is either coarsely ground and mixed with water in large tubs ; or it is put to steep in sacks until it is so soft that a process of kneading sufiices to set the starch at liberty. Starch from potatoes. The potatoes are grated after having been well washed, and the palp being thrown on a sieve, the starch is carried off by the water and deposited in suitable vessels. The washings in the manufacture of potato starch soon become putrid by reason of the azotized matter which they contain, and until lately occasioned much annoyance, until M. Dailly conceived the happy idea of turning them to account as liquid manure. Starch of the Yvca, or Jatropha manihot. The manihot yields very large foots, rich in starch. These are taken tip a little after the flowering, when the fecula is most abundant. To extract the starch, precisely the same process is employed as in the case of the potato. In South America the manioc is distinguished into yuca duke (mild) and yuca brava, (malignant ;) the latter epithet applying • Payen, M^r.oire cit p 96. TKRNARY PRINCIPLES STARCH. 88 to the jatropha containing poisonous juice. The two yucas are, however, but one and the same species ; at least a skilful botanist, M. Goudot, who resided for several years in America, could not perceive any specific differences between them. The poisonous principle of the yuca brava must be very volatile, or readily destroy- ed by heat, for the root may be eaten with impunity after it has Deen roasted, while the animals who eat it in the raw state soon ex- perience the most distressing effects. The Indians seldom prepare starch from the jatropha ; but the root frequently constitutes the staple of their food. It is from the yvca brava that they obtain the cassava,, which supplies the place of bread with them. Among the Indians in the country near the river Malta, one of the principal tributaries of the Oronoko, I have seen the cassava prepared in the following manner : the roots of the manioc were scraped on a sort of rasp formed of small fragments of flint stuck into a plank ; the pulp was then put to drain in a long strainer made of the entire bark of a species of fig ; the juice having drained away, water was added to finish the washing ; the liquid came out nearly clear and without bringing away any perceptible quantity of starch. To form the pulp into cakes of cassava, it was spread out on an earthen dish placed over the fire ; the process was complete when the cassava was dry, and slightly toasted on the out- side. Cassava bread is not very palatable, but it possesses the pro- perty of keeping for a long time in spite of heat and moisture, and is frequently an indispensable article of provision with the South Amer- ican traveller. The Indians say that they cannot obtain cassava from the yuca dulce. Starch from pabns. In the Moluccas and Philippine Islands, and in the plains of Apure, there are certain palms which yield a species of fecula. This fecula is found in a soft substance, general- ly situated in the centre of these trees. The marrow of these palms is dried, and when sifted presents itself in the form of grains, which in commerce bear the name of sago. None of the amylaceous principles or feculas obtained by the processes which I have mentioned are absolutely pure ; even sup- posing all the soluble substances to have been removed by washing, they still retain fatty matters, azotized principles, and coloring substances. Starch is purified by following up the water washings by the action of alcohol, of acetic acid, and of ammonia. Starch in its state of greatest purity, and dried at 100° cent. (212" Fahr.) contains, according to the analysis of M. Jacquelain : Carbon 44.9 Hydrogen 6'3 Oxygen • 48.8 100.0* By slight roasting, amylaceous feculas undergo considerable changes ; they become soluble in water, and then present the pro- perties of gura.f Starch thus roasted, supplies the place of gtra ia • Jacquelain, Annales de Chimie et de Physique, t. Ixiiii. p. 181, 2e »6rie. f Vaoquelin and Booillun Lagrange, Bulletin de Phnrmacio, t. ill. p. 54. 84 CHEMICAL CONSTITUTION OF VEGETABLES. various manufacturing processes ; still it si juld not be confounded with gum in a cliemical point of view. The acids act with more or less energy on starch, and give rise to different products. Nitrie acid, when it is diluted with water, merely dissolves fecula; but at a certain degree of concentration it exerts a destructive action. In this reaction several acids are formed, among others oxalic acid By employing very dilute sulphuric acid, Kirchhoff succeeded i& changing starch into a saccharine substance similar to the sugar of the grape. The operation may be performed in a leaden or silvei pan, or, what is preferable, especially when the process is carried on upon the great scale, in wooden vessels, in which the liquid mass is heated by steam. According to M. Couverchel, several organic acids are capable of changing fecula into sugar in a similar manner ; such are oxalic, tartaric, and malic acids. The artificial conversion of starch into grape-sugar has not yel been satisfactorily accounted for. The acid employed does not seero to undergo any change : it is found in its original state and quantity after the operation. M. de Saussure thinks that the effect of the reaction is the fixation of water ; thus 100 parts of fecula yielded him 110.40 parts of sugar.* M. Couverchel and M. Guerin, on the contrary, state that the quantity of sugar obtained was less than that of the starch they employed. Ghnen exerts a reaction on starch similar to that produced by acids ; Kirchhoff discovered, that under the influence of the azotized matters which are met with in flour, the fecula is converted into sugar. t Two parts of starch being mixed with four parts of cold water, on adding twenty parts of boiling water, a thick paste is pro- duced ; if into this one part of dry powdered gluten be introduced, and the mixture be kept at the temperature of 60° cent. (140° Fahr.) the paste becomes more and more liquid, so that the mixture may be filtered at the end of from six to eight hours. By concentration a sirup is obtained, in which small crystals of sugar are perceived. It is well known that during the act of germination, fermentable saccharine matter is produced. Kirchhoff concluded, from his ex- periments, that this production of sugar in germination is attributa- ble to the reaction of the gluten on the starch. Germinating grain, barley-malt, for instance, reacts rapidly and powerfully on any fe- cula with which it is brought into contact ; a fact well known to, and constantly taken advantage of, by manufacturers of spirits from potatoes and raw grain, large mashes of which are rapidly converted into sweet fermentable liquids under the action of a little malt. These facts, it is evident, cannot be explained by Kirchhoff's ex- periment ; in the fermentation of the potato, the mass of fecula to be converted into sugar is too great compared with the quantity of glu- ten which exists in the malted barley. Further, the gluten in grain which has not germinated, scarcely exerts any appreciable action. • Sausiure, Bibliothequc britannique, t. Ivi. p. 333. t Kirchhoff, JQUTna! du Pharinacie, t. ii. p. 2ja DIASTASE. 85 The principle which, in the preceding operations, converts the starch into sugar, must therefore become developed daring germination. This important point in the art of the distiller has been investigated with great ingenuity by M. Dubrunfaut ;* and MM. Persoz and Payen succeeded in separating the peculiar matter in barley-malt which possesses the property of converting starch into sugar. This matter has been called diastase. Diastase exists in the seeds of all the cereals which have germi- nated ; it is met with more especially near the germs, it seems even that the radicles contain none of it. Nor is diastase observed in the shoots or roots of the potato ; it is to be met with only in the tubers, around the eyes or points where the young sprouts are developed, precisely as M. Payen has remarked, in the place where we should conceive its presence to be necessary for effecting the solution of the fecula. It is also found to exist in the bark and beneath the buds of trees, always in contact with starch. f Diastase is gene- rally obtained from malt, and when carefully prepared, its peculiar power is such, that one part by weight is sufficient completely to liquefy two thousand parts of starch. Diastase is solid, white, amor- phous, insoluble in pure alcohol, soluble in water and weak alcohol The solution very readily undergoes change ; it becomes acid, and then no longer exerts any action on fecula. When dried, it keeps much better ; still, at the end of two years, it seems to have lost its distinguishing properties. Diastase has no action on vegetable tinc- tures, on albumen, gluten, cane-sugar, gum-arabic, or the woody fibre. That which more especially characterizes it, is its powerful action on fecula ; it may be advantageously used to separate and purify the preceding substances, when they are- mixed with starch. The presence of diastase in malt explains the phenomenon of the liquefaction of starch effected by the action of a small quantity of that substance. This solution is not effected by gluten, nor by hor- deine, as M. Dubrunfaut had imagined. By the action of diastase, or of malted barley, the starch on being liquefied is not entirely converted into sugar ; there are other dis- tinct products to be considered in this change. The sirup ob- tained by concentrating the liquefied starch, contains sugar capable of undergoing the vinous fermentation, and a gummy matter, dextrine. These two substances may be separated by means of dilute alcohol, which dissolves the sugar and leaves the gum untouched. The relative quantities of dextrine and sugar produced by the action of diastase are variable, and depend both on the temperature at which the process is conducted, and on the continuance of the reaction In tlie first period of the process, the dextrine predominates ; but it becomes less and less by degrees, and finally gives place to sugar. M. Guerin ascertained a curious fact, which shows how the dias- tase developed in plants may act on their starch : reaction takes place even at ordinary temperatures. In one of M. Guerin's experi- * Dubrunfaut, M6moires de la Soci6t6 Royale d' Agriculture, annee 1823, p. ^40. t Payen and Persoz, Annales de Chiinie et de Physique, t. liii. p. Ti ' t. Ivi. p. 337 9e sirie. 8 BO f'HEMlCAL CONSTITUTION OF VEGETABLES. ments, at a temperature no higher than 20° cent. (68° Fahr.) a quan- tity of starch, at the end of twenty-four hours, was converted into sirup, which yielded 77 per cent, of saccharine matter.* Pure dextrine. M. Payen freed dextrine from the sugar which usually accompanies it by precipitating a sirup of fecula previously dissolved in dilute alcohol, by means of alcohol nearly free from wa- ter. Dextrine well dried, and reduced to powder, has a specific gravity of 1.51. The specific gravity of pure starch is 1.51, that ol the sugar of starch 1.61.t M. Payen found dextrine dried at a temperature of 212° Fahr. to consist of — Carbon 44.3 H y d rogen 6.0 Oxygen 49.7 100.0t a composition identical with that of starch. We have seen that water, acidulated with sulphuric acid, trans- forms starch into sugar ; and that in this respect, the acid acts pre- cisely in the same way as malted barley, like which, the acid first causes the fecula to pass into the state of dextrine : by checking the reaction at the proper moment, this substance may thus be obtained, as was shown by Messrs. Biot and Persoz.^ When starch, for in- stance, is triturated with concentrated sulphuric acid, if the mixture be diluted with half its volume of water, and be left at rest for an hour, alcohol will throw down almost the whole of the starch employ- ed in the state of dextrine. M. Payen has remarked that starch is never met with in the vege- table tissues while in the rudimentary state ; the spongioles, the radi- cles, the foliaceous buds, the interior of the ovules, contain none of it. Nor is starch found in the epidermis, nor in the primary cells of the subjacent tissues. This proximate principle seems to be exclu- ded from those parts of vegetables that are more directly exposed to atmospheric influences : it is only met at a certain depth ; and the globules which constitute starch increase in number and in size in the cells most remote from the surface. The subterraneous organs of plants, — certain bulbs, most tubers, abound in amylaceous matter. It might be maintained that light modified this substance, at the very moment that it was subjected to the vital influence, and that it was only preserved in the dark. On the globules of some species of fcEcula there is found a point or hilum, which, according to some observers, serves to fix them to the parietes of the cells which enclose them. It often happens, nowever, that no hilum can be distinguished, even by the help of the most powerful microscopes; to render it apparent, recourse must be had to desiccation, which, by causing the globular mass to shrink, allows the part carrying the hilum to project, by reason of its • Gu^rin, Annates de Chlmle, t. Ix. p. 42, 3e 86rie. i Payen, M6moires cit6s, p. 169. % Idem, p. 157 Biot and Tersoz, Annates de Chimie et de Physique, t. lii. p. 73, ~ INULINB. 87 •tronger cohesion. M. Payen does not regard the hilum as a point of permanent attachment, connecting the grain of starch to the in- terior wall of the cell. He considers it as the orifice of the duct by wiiich growth is effected by intersusception. In support of this view, M. Payen observes, that in a great number of vegetable cells, especially in those of the potato, and of the rhizomas, the globules of starch are developed in such quantity, that it is actually impossi- ble that each of these should be united directly to the inner wall of the cell.* INULINE. This substance, discovered by Rose in the Inula helenium, pre- sents certain analogies with starch. It forms the greater part of the solid matter of the tubers of the Jerusalem Artichoke and Dahlia, which do not contain starch. Inuline is dissolved in boiling water ; on cooling it is deposited in globules, which, under the microscope, appear diaphanous, adhering to one another like strings of beads ; exposed to a temperature of 367° Fahr. it melts com- pletely and acquires new properties, becoming soluble in cold water and in alcohol. Inuline is transformed into dextrine and sugar by the mineral acids ; but it possesses certain properties which show it distinct from true starch. In the first place, it is not colored by iodine ; and then acetic acid, which is without action on starch, produces with inuline precisely the same effects as the sulphuric, phosphoric, and hydrochloric acids ; finally, diastase, whose reaction upon starch is so peculiar, so prompt, and so powerful, does not cause any change in inuline. It is therefore easy to separate these two substances when they are mingled, by treating the mixture either with acetic acid, which dissolves the inuline, or with diastase, which liquefies the starch. Inuline has been analyzed by M. Payen, after having been dried at 253° Fahr. and having been melted at 367° Fahr. In both cases it has the same composition. Carbon 46.6 Hydrogen 6.1 Oxygen 493 100.0 The composition here is obviously the same as that of starch and dextrine. OF WOODY MATTER AND CELLULAR TISSUE. The most solid part of plants, thai which forms in some sort theb skeleton, is the wood in trees, the woody fibre in herbaceous plants. Woody fibre, as it used to be prepared and considered, viz. by the reaction of certain agents which have the property of dissolving the gummy, resinous, and saline substances which are commonly asso- ciated vi'ith it, consists, in fact, of two substances, one the cellular substance, constituting the tissue of wood and of all the organs of ♦ Payen, M6molres cit6s, p. 183. 88 CHEMICAL COXSTmrriON OF VEGETABLES. plants, the other the woody substance, properly so called, filling, and in some sort consolidating the cells. This distinction between these two elements of wood was first made by M. Mohl ; but M. Payen was the first who fixed the opinion of chemists and of vege- table physiologists upon the true nature of these immediate princi- ples.* By treating the vegetable tissue in its nascent and stili gelatinous state — the unimpregnated kernel of the almond, of the apricot tree, &c., the membranous matter of the cambium of the cucumber, the spongioles of radicles, leaves, wood, &c. — with differ- ent menstrua, M. Payen obtained the cellular tissue in the state of purity, and having an elementary composition almost identical, from whatever source derired ; a fact which may be seen from the fol- lowing table, which gives the composition of cellular tissue from different sources after having been dried at 352° Fahr. Carbon. Hydrogen. Oxygen. Ovules of the almond-tree . 43.6 6.1 50.3 '* of the apple and pear 44.7 6.1 49.2 " of the helianthus annuus . 44.1 6.2 49.7 Pith of the elder 43.4 6.0 50.6 Cotton 44.4 6.1 49.5 Endive 43.4 6.1 50.5 Banana ... . . 43.2 6.5 50.3 Leaves of the asrave .... 44.7 6.4 48.9 Cotton of the Virginian poplar 44.1 6.5 49.4 Heart of oak 44.5 6.0 49.5 Pine-tree 44.4 7.0 48.6 Peri sperm of the phytelaphas 44.1 6.3 49.6 Mushroom 44.5 6.7 48.8 The primary tissue, consequently, which constitutes the skeleton of wood, is still isomeric or identical in elementary composition with starch. With mineral acids the cellular tissue further undergoes changes which assimilate it with starch ; for on treating it with sul- phuric, acid it is changed into dextrine and sugar. The composition of the cellular tissue differs considerably from that of the woody fibre as it has hitherto been obtained after the action of solvents, and been examined by preceding chemists. Pure wood or woody tissue consists of the following proportions of eie.nients : * Dtunas, Compte* rendos, vol. viii. p. 53. WOOD. 89 1 1 X c Authorities. \Vo:,dy tissue of the oak 41.8 5.7 52.5 Gay-Lussac and Thenard. " of the beech 42.1 5.8 51.5 <« « " of the box 44.4 5.6 50.0 Prout. « of the willow 44.6 5.6 49.8 (( " of the oak 49.7 6.0 44.3 (( " of the beech 44.3 6.0 49.7 Payen. " of the aspen 44.5 6.1 49.4 ill not cause the loss of more than about 25 per cent of water. The wood which is used for burning almost always contains about a quarter of its weight of moisture, which not only does not assist in producing heat, but actually dissipates a great deal during its conversion into vapor. It is, therefore, highly advantageous in all operations where wood is the fuel, only to employ that which is thoroughly dry. So well is this fact ascertained, that in some manufactories the wood is previ- ously dried in stoves before being consumed in the furnace. The composition of woody matter may be represented by carbon and water : of carbon the mean may be stated at 52, of hydrogen and oxygen, in the proportions which form water, at 48. The defi- nitive products of its combustion ought consequently to be carbonic acid and water. The heat disengaged during this combustion, neces- sarily proceeds from the union of the combustible elements of the wood with the oxygen of the atmosphere. But in this particular case, the hydrogen being already present with the proportion of oxy- gen required for its combustion, it may be regarded as already burned, the state of condensation in which the oxygen exists being considered. The heat produced by the wood, tl>«refore, depends solely on the quantity of carbon which it contains. Natural philosophers in France agree in designating as unity, in reference to caloric, the quantity of heat necessary to raise a kilo- gramme, or 2.2 lbs. avoirdupois of water, one degree of the centi- grade thermometer, (r.8 F.) The following table, by Rumford. is intended to show the different calorific or heating powers of dif- ferent kinds of wood, and its interpretation is this : since 1 kilo- gramme or 2.2 lbs. avoird. of lime-tree gave out 3460 units of heat, it follows that this quantity of the combustible would suffice to raise by 1 degree centigrade, (T.SF.,) for example, from 10° to IT cent. 3460 kilogrammes, or 7612 lbs. avoirdupois of water. •2 CHEMICAL CONSTITUTION OF VEGETABLES. Kinds of wood. Units of heat evolved. Lime-tree, dry 3460 The same, thoroughly stove dried 3960 Beech, dry, four years seasoned 3375 The same, well dried in a stove 3630 Elm, from four to five years seasoned . 3037 Oalc, fire-wood 3550 Ash, dry ...... 3075 Wild cherry . . 3375 Fir, dry . . ... 3037 The same, well dried in a stove . 3750 Poplar, seasoned 3450 The same, well dried in a stove 3712 Hornbeam 3187 Oak, dry 3300 From the experiments of Clement, it appears that the heating power of charcoal is equal to 7050 units. Dry wood containing, as we have seen, 52 per cent, of charcoal, its heating power has been deduced theoretically, as equal to 3666. Mr. Marcus Bull in Amer- ica, made a series of experiments to determine the relative quantities of heat given out by different kinds of wood, from which M. Peclet has been led to conclude that the same weight of dry wood of every kind has the same heating power, and that this for a kilogramme, or 2.2 lbs. avoird. of wood dried by artificial means, is equal to 3500 units, while the same quantity of the same wood having been cut and seasoned during from ten to twelve months, and containing from 20 to 25 percent, of water, is no higher than about 260 units. By way of comparison, I shall here add the heating power of the several combustibles in general use, in contrast with that of wood : 1 kilogrm. or 2.2 lbs. avoird. of wood-charcoal produces 7226 units of heat. " coal 6000 " " " peat 3005 " " " peat charcoal 6400 " Although the same quantities of wood, brought to the same degree of dryness, appear to have the same absolute calorific power, all are not alike adapted to the same purposes. Hard woods burn slowly, and give out less heat in a certain time than the less compact kinds of wood. This is the reason why fir is preferred to oak in furnaces where the object is to obtain the most intense heats. It were for- eign to our object to enter upon any consideration of the various qualities, or of the adaptation to particular uses, of different species of limber. I may, however, add a table of the ordinary dimensions of well-grown trees of different kinda, such as are cojuixionly found iu these countries . TREES. 93 Trees. Usual height of Usual Trunk. Diameter. Feet. Inches. The spruce fir Larch 26 to 100 > 47.1 39.3 Poplar 19 " 65 31.8 Pine . ... 16 « 65 34.1 Plane . . 36.1 Oak, Elm . ... 31.4 Birch . .... 29.4 Beech - 16 « 48 28.2 Lime ..... 25.9 Ash 23.5 Willow 11.7 Chestnut ... . . 13 " 48 36.1 Chestnut (another variety) 28.2 Maple 10 « 48 28.2 Service 13 " 39 17.6 Acacia 13 « 26 19.2 Hornbeam . i 21.2 Mulberry .... • 10 « 23 16.5 Wild Pear S 14.1 Crab . . . . 6 " 20 12.9 Walnut 6 " 16 36.1 These may be taken as the measurement of trees at their full growth, and fit for felling. The soil being of the same quality, the dimensions of trees depend especially upon their age ; individual trees of the same species, however, occasionally acquire extraor- dinary dimensions. Every one must have noticed the rapidity with which young trees grow ; but is the growth the same for every period of the existence of trees, or do they attain a certain determinate size like animals, and then cease from further increase ? We have found that in those climates where vegetation is suspended for a portion of the year, the increase in the diameter of trees takes place periodically by the addition of a concentric layer of woody tissue ; so that it is possible to determine the age of a dicotyledonous tree by the number of its concentric rings, counted at the bottom of the trunk. With a view to ascertain the amount of increase in the woody layers at dif- ferent periods of vegetable life, De Candolle measured their thick- ness, and found that if the annual increase presented a certain re- gularity, it was still very far from being absolute even in the case of a single species. The oak especially offered striking anomalies ; thus a trunk which had grown slowly in diameter was found to have increased more rapidly as it got older. He found young trees ol the same species, the growth of which, very slow at first, by and Dy became accelerated, and then fell off in a third period of their existence. From the whole of his observations, De Candolle 900- 04 TREES— TIMBER. eludes that the growth of our common European trees having gone on with a certain rapidity to the age of from about fifty to seventy years, then became slower, but continued regular to extreme age. The inequalities of growth, conspicuous in the different thicknesses of different rings, he thinks are mainly due to the kind of soil which the mass of the roots encountered in their progress, or to the re- moval of other trees which grew in the vicinity. The diminished thickness of the rings, after trees have passed a certain age, he ascribes to the depth to which the roots have now penetrated, and their consequent remoteness from the air ; and further, to the resist- ance opposed to the expansion of the trunk by the bark, which has now become thick, hard, and unyielding. Mr. Knight found that old pear-trees, relieved of their outer bark, formed more wood in a couple of summers afterwards, than they had made in the twenty years that preceded the operation.* The forests of intertropical countries produce a vast number of gigantic trees, many of which might doubtless be turned to excellent use ; but the information we have on the trees of these latitudes is very imperfect. In New Granada, the wood which is known undei the name of wood of St. Martha, {astroneum graveolens ?) is fre quently employed for building purposes as well as for making furni- ture. It is very hard, and more beautiful than mahogany, its color being deeper. M. Goudot measured a tree of this kind, which was 1.6 metre or nearly 4^ feet in diameter, including the alburnum, and had 32 centimetres or upwards of 18 inches of heart- wood. Belfries having supports of this wood are met with, which have stood for more than a century exposed to all the inclemencies of the weather. This tree grows in the dry soils of the hottest regions of South America, and seldom at an elevation of more than about fifteen hun- dred feet above the level of the sea. Cedar {cedrela odorata) is never attacked by insects, doubtless because of its aromatic odor ; this valuable property makes it in- valuable as building timber. The tree attains to large dimensions. M. Goudot measured one in the forest of Quindiu in South America, which was upwards of 150 feet in height by more than Q\ feet in diameter. It grows freely through a zone of considerable "breadth, from a height of about 3280 to 6560 feet above the level of the sea, a circumstance which, according to my own observations, would in- dicate the extreme temperature of the district which it inhabits to be between 66° and 76° Fahr. There are several other beautiful and useful timber trees of the Cordilleras — the Nogal {juglans . . .?) which grows between 0500 and 9800 feeta?bove the sea line ; the escoho, the pino {taxus montana Willd.) whose region lies between the 2.800 and 11.400 feet of eW- vation ; the arayan and the guayacan, — all are serviceable in one direction or another. The caracoli {anacardium caracoli) and the fig {Ignerones) are trees which attain to extraordinary sizes, and ftffoid light woods that prove useful in various circumstances. Uc« • D« CandoUe, Veuetablc Physiology, p. 975. TREES ^TIMBEX. 05 let the tropics, indeed, the trees generally exhibit a luxuriance of vegetation which strikes European travellers with amazement ; M. Goudot, for example, measured a bomhax (B pentandrum) no more than sixty years old, the trunk of which was 8 metres or 26} feet in circumference, and whose boughs covered a circular area of 39 metres or 120 feet in diameter. There is a beautiful tree which grows in the valleys of Arragua in Venezuela, the Zamang, a species of mimosa, according to Hum- boldt, one of whicb, in particular, is greatly celebrated, and under the shade of which I rested on the 24th of January, 1823. This magnificent tree is to be distinguished at the distance of a league ; its branches form a hemispherical crown of 187 metres or 613 feet in circumference, extending like a vast umbrella, the points ap- proaching to within from 10 to 16 or 18 feet of the ground. The trunk of this extraordinary tree is nearly 65 feet in height and up- wards of 9^ feet in diameter. This tree is an object of veneration with the Indians. It does not seem to have altered in its appear- ance since it was first particularly noticed ; the earliest conquerors of Venezuela seem to have met with it in the same state as it is at the present time. When Himiboldt measured the Zamang de Tur- mero, its branches on one side were entirely stripped of their leaves. Twenty years afterwards 1 found it green in every part; but the leaves and branches with the southern aspect were not so numerous nor so vigorous as the others. The dragon-tree of Orotava in the Island of Teneriffe is one of the oldest vegetable monuments of the present world. Humboldt gives it a diameter of 17 feet, and its height, as stated by M. Ledru, is upwards of 65 feet. When Teneriffe was discovered in 1402, this tree appears to have had the same dimensions which it presents at the present time. The mahogany {cedrela mahogani) is a very long-lived tree. In J..\maica it sometimes acquires a diameter of upwards of 6 feet, and Sir W. J. Hooker has calculated that two centuries at least are re- quired to supply timber of the large scantling which we constantly see in the yards of our timber merchants and cabinet-makers. The Hi/mencea cnurbaril, one of the largest trees of the Antilles, yields, like mahogany, a timber that is hard and in great request among cabinet-makers and inlayers. It sometimes grows to 19 feet in diameter. The Baobab {Adansonia digitata) lives for centuries, and acquires extraordinary dimensions. Adanson saw one in the Cape de Verdes, in the trunk of which an inscription was found, which was covered by three hundred layers of wood ; it had been cut by two English travellers three centuries before. From positive observations col- lected by Adanson, a table has been constructed to show the pro- gress and probable age of the baobab : 96 SIZE AND LONGEVITY OP TREES. Age of the Baobab. Diameter of the Trunk. Height. 1 year, 0.10 feet 5.25 feet 20 1.04 16.40 30 2.41 23.30 100 a.84 30.84 1000 14.76 61.68 2400 19.03 68.24 5150 31.99 76.76 De Candolle has remarked that this longevity of the baobab ia made the more surprising by the softness and liability of its wood to decay. But again, it must be considered that the great diameter of the trunk, in relation to the height, gives the tree a stability which is possessed by no other — by enabling it to resist violent gales of wind. It strikes me that there may very well be some mistake in Adan- son's estimates of the age of the baobab. When we see such irregu- larity in the growth of trees of the same species planted in the same soil, little reliance can be placed on any deductions drawn from the size of the trunk when the concentric rings cannot be counted. In proof of this I here give the measurements of two baobabs planted in 1821 in the Botanical Garden of French Guiana. In 1842 these trees were found : — feet. feet. No. 1. Length of stem from ground Diameter of the base 5.41 to first branches 7.70 Do. at origin of branches 4.23 «„ o Tv> QQR Diameter of base 2.63 "°-'*'^^ • ^'^ Do. at origin of branches 1.48 In the tree No. 2 the branches were puny and nowise in relation with the size of the trunk. The bald cypress {taxodium distichum) is a tree that is very abundant in Mexico, and in the southern parts of the United States. At Chapultepec there is one of these trees called the cypress of Mon- tezuma, which tradition says flourished in the reign of that prince. In 1831 the tree was still vigorous, and its trunk was 41 feet in cir- cumference. There is another cypress near Oaxaca, under the shade of which Fernando Cortez is still reported to have rested ; the trunk of this tree is upwards of 39 feet in circumference, and it is 105 feet in heiglit. Michaux measured several taxodiums in the Floridas which approached these two in their dimensions. We have only uncertain data in regard to the age which palms may attain to ; their sizes, however, are well known. In Egypt, according to M. Delille, the date-trees are generally about 65 feet in height. In the Andes of Quindiu several ceroxylons were measured, the trunks of which were from 195 to 230 feet in height ! Martius assigns the following as the extreme dimensions of the palms of the Brazil-s : from 75 to 127 or 128 feet in height, by a diameter of from 6 to about 12^ inches. Among several palms {arica oleacera) planted in the Botanical Garden of Cayenne in 1821, the tallest twenty years afterwards was SIZE AND LONGEVITY OF TREES. 97 i8 feet from the ground to the bottom of the crown, and 3 feet 6^ inches in circumference at the base ; at 6;^ feet from the surface of the ground the circumference was only 2 feet 1 inch, and a small fraction. As the palms and baobabs will be carefully protected in the Botanical Garden of Cayenne, an opportunity wiL je afforded future observers of following these plants in their growth, with a perfect assurance of being correct as to their age. Particular trees of different kinds have occasionally acquired re- markable dimensions and lived to great ages in Europe. An elm is mentioned which grew on the promenade of Morges, the age of which, reckoned from the number of concentric layers, must have been three hundred and thirty-five years ; its trunk was above 18 feet in diameter. The lime is another tree which in temperate countries sometimes grows to a great size. The one planted at Freiburg to commemorate the victory of Morat in 1476, in 1831 was 14i feet in diameter. Near the same place there is another tree of the same kind which must be older than the last, inasmuch as it was already celebrated for its size a century ago ; in 1831 this tree was upwards of 36 feet in circumference, and about 72 feet in height. The lime-tree of Neustadt is scarcely less curious for its size and the immense spread of its branches than for the historical circumstances connected with it. Looking back to old documents, this tree must already have been of great size in 1229 ; in a poem written in 1408 we are told that this tree was then supported by sixty-seven props ; in 1654 it had eighty-two stone pillars to support its branches, and in 1831 the number had increased to one hundred and six. The cir- cumference of the trunk at 6^ feet from the ground measured very nearly 39 feet. An old measurement made one hundred and fifty years before corresponds very nearly with this, a fact which shows that in the course of a century and a half the trunk of the lime-tree of Neustadt had not grown perceptibly. It is said to be from seven to eight hundred years old. The old lime-tree of Chaille in 1801 was upwards of 49 feet in circumference. The beech grows rapidly while young ; but in more advanced age with extreme slowness. In 1818 Deluc saw several beeches near Geneva, the trunk of which was from 14 to 16 feet in diameter. De Candolle measured a larch two hundred and fifty-five years old, the trunk of which was upwards of 5f feet (5.84 ft.) in diame- ter ; and a larch of no move than fifty-four years growth has been measured which was more than 3| feet in diameter. The celebrated chestnut-tree of Mount Etna has been stated to be upwards of 206^ feet in girth, (about 68 feet in diameter,) an-i must therefore be the largest tree described up to the present time ; but the tree has been supposed to be formed by several trunks springing from a common root which have grown together. Other remarka- ble chestnut-trees are mentioned. The plane is one of the largest growing trees of temperate coun- tries. A traveller, who visited the valley of Bujukdere, near Con- stantinople, met with a plane upwards of 95 feet in height, and the trunk of which, hollow internally down to the levpl of the ground, 9 98 SIZE AND LONGEVITY OF TREES. «ras more than 154 feet in circumference. A plaae-tree, which grew in Norfolk, and was of the age of thirty-one years, was T{ feet in circumference, according to Hunter. Cypress-trees often attain to a very great age. In the garden of the palace of Grenada there is one which has stood for more than three centuries. iVt La Somma, near Milan, a cypress is shown which in 1794 was 17 feet in circumference,* Tradition has it that an orange-tree of the convent of St. Sabina at Rome, was planted by St. Dominic in the year 1200 ; this tree still exists. The orange-tree of Versailles, known under the name of the Francis /., is rather more than three hundred years old. In 1804, orange-trees were shown in the green-houses of Bonn three centu- ries old, and of which the trunks were more than 30 inches in cir- cumference.! In South America I had myself occasion to observe citron-trees of great age and of very considerable dimensions ; the trunks of several of these trees were nearly 27| inches in diameter. A sycamore-tree of the village of Trons, in the Grisons, more than five hundred years old, is at this time between 8 and 9 feet in diameter. Many oaks have been described which had survived from eight hundred to one thousand years. Hunter saw one of these trees still extremely vigorous which was IH feet in diameter. Evelyn, who, in his delightful work entitled Sylva, has given a list of the largest oaks known in his day in England, speaks of one growing in Wel- beck Lane which must have been eight hundred and sixty years old at least, and the diameter of whose trunk at the base was upwards of 12| feet. The olive is one of the trees that reaches a great age ; Picconi describes one of about seven centuries, and a circumference of about 25 feet. The cedar of Lebanon grows vigorously and long, especially in soils that are sufficiently loose and permeable. According to M. Paul Vibray, of Sologne, the growth of this tree is more rapid than that of the coniferi in general. The cedars which grew on Mount Lebanon, and were measured by Nauwolff in 1574, and again by Labillardiere in 1787, are generally allowed to be about the age of one thousand years. De Candolle, however, thinks that this age is exaggerated, and in contradiction with observations made on troes, the age of which is positively known. The following are a few of the measurements which have been reported by different observers An. feet circiimrer. Obwrrtrs. CedRr of Chelsea 83 12 " olPHris 40 7 Thou.n. " nl'ditio 83 9.4 Loiseletf " Environs of London 200 16 Hunter " Ditto 113 14 Ditto. *♦ of Mount l^sbanun 600 36.4 MaundreL " ofSologne 30 5 ofVit«y Tbe yew, as is well known, produces a very hard, close, and e» • De C&ndoUe, Physiolosie, p. 9M. t Ibid. p. SOB. AGE FOR FELLING. 90 during wood, qualities which contribute greatly to the longevity of trees. Some of the oldest trees known have been yews. Here are a few that have been particularly described : Where they ^ow. Probable tige. Circumference. Observeri. County of York 1220 28.25 Pennant Ditto 1220 13.85 Ditto. County of Surrey 1287 30.12 Evelyn. Fotheringal (Scotland) 2580 62-34 Pennant, CountyofKent 2800 62.60 Evelyn. According to Duhamel it is extremely difficult to fix upon any age as the best in a general way for felling trees, with a view to ob- taining the largest quantity of sound available timber. When the tree is too young, the timber has not all the excellence which it would have gained with greater age ; when too old, the pores are obstructed, and it has begun to decay in the parts of oldest forma- tion, so that it is not uncommon to find wood in the centre of the trunk which is lighter than that of the circumference. In trees which have already fallen into a certain state of decay, the worst timber in them is decidedly that which is taken from the centre at the base of the trunk ; and, indeed, the wood of the centre generally is then of inferior quality to that of more recent formation. Very aged timber always perishes first in those parts which have formed the most internal layers of the tree. It is, therefore, an obvious and grave error to suffer any tree to stand that has given the slightest indications of decay, inasmuch as that which is ordinarily the most valuable limber is likely to be altogether lost. Neither the age nor the dimensions are always the indications of the proper period for felling trees ; exposure, soil, situation, have immense influence upon their growth, vigor, and general qualities. Trees ought to be cut just when they are on the turn ; the proper moment is that which precedes immediately the alteration of the heart; and although the destructive eflfects of age are principally felt in the interior, this in- testine disorder is nevertheless proclaimed externally ; the whole tree suffers when it has taken place.* Duhamel has given the following characters, as indicating in- cipient decay, or decline of vigor in trees :t 1. A tree, the top of which forms one uniform rounded mass, is not strong ; a vigorous tree always throws out certain branches which surpass the others in luxuriance of growth, 2. When a tree comes into leaf prematurely in the spring, and particularly when the leaves turn, and fall prematurely in the autumn, it is a certain sign of weakness. 3. When several of the top or leading branches of a tree die, even at their mere extremities, the wood in the centre is beginning to undergo alteration. 4. When the bark quits the trunk, or becomes cracked here and there, we may be satisfied that the tree is far gone internally. 5. Mosses, lichens, and funguses growing upon the bark, and red * Duhamel, Exploit, des bois, t. i. p. 126. t Idem, 1. 1, p. 133^ idO SEASON FOR FELLING. or black spots appearing upon it, always lead to a suspicion of change in thf; wood. 6. When the sap is observed to flow from crevices in the bark, the death of the tree is at hand. In I'rance, the cutting dowr of the smaller wood, such as is used for firing, takes place at from twenty to thirty years ; in the forests, the trees are commonly felled at from one hundred to one hundred and thirty years old, and a few trees are generally left as reserves, and for special purposes, till they have attained the age of from two hundred to two hundred and fifty years. The prevalent opinion among foresters, with regard to the proper season for felling, is, thLt it should be done when the sap is in the state of greatest repose, or when it is present in least quantity in the trees. The season fixed by the old law of France (1669) was from October to March inclusive. But the experiments of Duhamel tend to show that this is not actually the season when trees contain the smallest proportion of sap, and that fellings made at other times of the year have had very satisfactory results. All things well weighed, says the illustrious cultivator, our only safe guide in such matters is observation ; and from numerous experiments he concluded that there was actually as much sap in trees in winter as in summer, and that the spring and summer were the seasons most favorable for the speedy drying of the timber. Trees felled in summer were even found by Duhamel to yield timber which stood better and lasted longer than those that were cut down in winter ; while he found the wood of equal strength in either case. He concluded, therefore, that the season of the year at which timber was felled, had no in- fluence upon its quality or durability.* There is, in fact, no general rule observed in different countries as to the period at which timber is felled. The French still go on cutting from October to March ; the English fell in the winter. Convenience of different descriptions appears often to decide the question as to season. In order to procure bark for the tanneries, an act was passed by the English Parliament in 1603, prohibiting all felling of oak timber during the dead season, the penalty for in- fringement of the act being confiscation of the timber felled, or fine to the amount of twice its value. An exception, however, was still made in regard to timber destined for the public service in ship- building, &c. The price of bark afterwards rose to such a height, that it was found most profitable to cut in the spring ; and the prac- tice then became so general, that it by and by became necessary to offer premiums to induce proprietors of oak forests to fell timber in the winter season, for the sake of the British navy. The inhabitants of the county of Stafford appear at a somewhat early period to have sought to combine the advantages of the bark trade, with a fulfil- ment of the conditions that entitled them to the premium on winter- felled timber : they stripped the trees of their bark in the spring, and felled them the following winter. And Buffbn and Duhame. ♦ Dnhamel, op. cit., t, i. p. 400 INFLUENCE OF SOIL ON TIMBER. 101 ihowed subsequently, that by barking trees two or even three years before cutting them down, the white external wood could be render- ed nearly as hard and durable as the heart- wood of the tree. The iccommendation of this procedure by these two distinguished men has not been followed in France ; but ever since 1770 the Dutch have adopted it, and it is now practised in many parts of England, particularly in the royal forests. It is quite certain that the nature of the soil exerts a considerable influence on the rapidity of growth and quality of the timber. The oak, the elm, &c., which have been grown in a damp soil, will not be so hard and compact as the same trees reared on a dry plot. Duhamel found, that although the trees which came in swampy bot- toms were very sappy and wet, they were still lighter than others of the same kind which had grown on a dry bank. Their white wood is thick in comparison with their hard wood ; they are brittle, and do not readily take or keep the shapes into which they are bent for ship-bu'lding or for staves ; and then their pores being large and open, and the whole wood being without that kind of varnish which impregnates good timber, they are readily permeable and unfit for the manufacture of vats, &c. — to say nothing of their being much more perishable. Such soft and porous timber is altogether im- proper for out-of-door constructions and for ship-building ; but it answers extremely well for indoor and cabinet work ; for the latter it has even certain advantages, it is easily wrought ; and once fairly seasoned, it is neither so apt to warp nor to crack as harder wood. It was very probably to guard against any excess of sap in trees, so prejudicial in a general way to the timber they yield, that the Ro- mans, according to Vitruvius, surrounded those that were destined to be cut down with a trench six months beforehand.* Trees which have grown in a good soil sufficiently drained have a fine bark, and their white wood is moderate or small in quantity. Their woody layers, indeed, are apt to be thinner generally, than those of trees that have grown in a wet soil ; but they are much harder and tougher, their grain is more even and close, and their pores are filled with an incrusting matter. They are consequently very heavy, even when thoroughly dry, and with time and due seasoning they become extremely hard, and in the same degree acquire durability. Duhamel was led by his experiments to conclude that the difference in point of density of timber grown in a marshy soil, and in one that was well drained and dry, was occasionally in the ratio of five to seven. The denser, dry-grown timber supports a relatively much greater weight without breaking than the marsh-grown timber ; and when it does yield, it gives way by a large and splintering surface, while the softer, less dense wood snaps off short. In brief, there is na question as to which kind of timber is the most valuable ; and meas- ures ought to be taken by landed proprietors and timber-growers at all times, not merely to grow trees, but to grow them under such cir- * Duhamel, Expl. de-^ bois t. i. p 46. 9* 102 SEASONINO. cumstances as shall ensure their yielding good available timber when they have come to maturity. If wet soils then be uniavorable to the growth of timber of the highest value, in ship-building especially, what has been said must be taken as of application to those trees only which will grow in a great variety of soils. Damp and even marshy lands are well known to be favorable and even indispensable to certain trees, which, by their nature, delight in the neighborhood of water ; but these are generally kinds which are rather sought after for their height and lightness, than for their strength and durability.* Excessively dry soils, on the other hand, have also their disad- vantages for forest cultivation. In such ground, trees seldom ac- quire a sufficient growth to admit of their being applied to any im- portant purpose. It is certain, however, that absolute uniformity is never encountered in any piece of timber. The woody layers that have been formed in a wet or a dry year, in a warm or a cold year, feel and manifest the effects of the varying meteorological influences. They are of different thicknesses and densities, and, when carefully examined, are found to present the characters of the timber grown in soils of the most opposite description in point of wetness and dry- ness.f The treatment of trees after they are felled, the drying and sea- soning of the timber, are points of the highest importance. Standing trees contain a large quantity of water in their composition. After being cut down the moisture is dissipated, rapidly at first, much more slowly afterwards. This drying process is, of course, favored or retarded by the varying states of heat and moistness of the atmo- sphere. At length there comes a time when the wood no longer suffers any sensible change by longer exposure to the air ; or if it does, the change is now on the one side, now on the other, and merely in harmony with the hygrometric state of the atmosphere. Timber has then lost the whole of the moisture which it can get rid of by this mode of drying ; it is now fit for use ; it is seasoned, to use the technical expression. Timber is sometimes seasoned by previous total immersion in water. It has been held that this process favored the thorough dry- ing, by dissolving out certain deliquescent salts which are found in the sap, and prevented after-shrinking. However this may be, ii is quite certain that in warm countries especially, it is advantageous to sink fresh-cut timber in water, with a view to prevent it from split- ting, apparently in consequence of drying too quickly. The old Venetians sank for a season in the sea, the oak timber which was destined for the construction of their galleys. Elm and beech, in particular, are said to improve greatly by the process of submersion in salt water, and to dry afterwards perfectly by simple exposure to the air ;|: * We believe, however, that the live-oak, of which the American navy Is con- structed, and which supplies one of the most imperishable kinds of timber kuown frow.s exclusively in swamps.— Eno. Ed t Duhamel, t. i., p. 57. i Knowlos, Maritime and ColooialAnnaU, 1885. DECAY. 103 Mr. John Knowles, who made a particular study of the means most generally employed in seasoning timber, has given an account of a series of experiments undertaken in the arsenals of Deptford and Woolwich, to determine the rate of drying and ultimate degree of dryness attained by timber variousty treated — unprepared and prepared by previous submersion in water. The pieces of timber were placed vertically, now in the position they had occupied in growing, now in that opposed to this ; and it was found that, circum- stances the same, they dried more quickly in the former than .n the latter. The general results of these experiments were as follows : 1st. That the pieces of timber were best seasoned by being kept about thirty months in the air, but in the shade and protected from wet. 2d. That they lost more of their original weight after six months' alternate immersions and dryings, than by being kept under water for six months and then dried. Ship-builders are generally agreed that it is not expedient to make use of timber until three years after it is cut.* Duhamel advises strongly, that in ship-building all timber from trees already on the decline should be rigorously rejected ; and this the rather, that the most careful examination often fails at first to perceive any alteration in the heart-wood of such trees, although it never fails to show itself by and by at a sufficient interval after the felling. This is undoubtedly a precept which it would be well to bear constantly in mind ; but timber does not always carry within itself the germs of its speedy decay ; and that which has been sea- soned with the most scrupulous care, and was originally of the best quality, does not escape the rot when it is placed under unfavorable circumstances, any more than that which was of inferior worth and less carefully treated. Wood appears to perish or decay through three principal a d ap- preciable causes, which all require similar conditions to con i into play, viz., stagnant air, sufficient warmth, and moisture. Like the generality of organic substances, wood, when moistened in contact with the oxygen of the air, and under the influence of a sufficiently high temperature, undergoes decomposition of a kind which has been compared to a slow combustion, upon which we shall find occasion to say more by and by. It is with a view to escape this kind of de- cay as much as possible that timber is never, or ought never, to be employed in the construction of ships and buildings until it has been thoroughly seasoned. Besides this first cause of decay, which may be prevented in a great measure by using certain precautions, wood has still two re- doubtable enemies, insects and certain plants of the family of the cryptogamiae. In one case, the wood perishes because it is fed upon by certain animals which live and grow at its expense ; in the other it decays because it serves as the soil to one crop of fungus after another which luxuriate on its surface, while their roots penetrate deeply into its interior. There is nothing in either accident which • Dapln, Ann. de CaUmie, t xvii. p^ S77. 104 DRY-ROT. excites astonishment, now that we know the intimate coi.stitution of wood. We know, in fact, that amon^ the number of sohible principles which impregnate the woody tissue, there is an azotized matter analogous in its composition to those that exist so abundantly in all the ordinary esculent vegetables. There is, therefore, in wood ample nourishment for the insects which we find living on it ; and if I state now (reserving to myself the opportunity of demonstrating the fact) that all organic azotized matter becomes an active manure by decaying, we shall understand how it happens that plants, which have the power of living in dark, warm, and damp places, wax and multiply in the joistings of houses, and in the ribs and planks ol hips, causing a dry rot, which separates the integral layers of the wood, and reduces the strongest beams to dust. The rapidity with which wood is, in some circumstances, devour- ed by insects is almost incredible. Some years ago the thermites, or white ants, spread in such strength through the docks and ar- senals of Roehelle and Rochefort, that in a very short space of time serious damage was done. A learned entomologist, M. Audouin, commissioned by the ministry to take information on the subject, reported that the ravages committed by these insects had been very considerable. But it is principally in warmer climates, where the tem- perature is steady throughout the year, and where there is no winter, that the thermites occasion the most alarming injury. At Popayau, for example, it is difficult to meet in a building, even of recent con« struction, with a piece of wood which is not gnawed and ant-eaten. The hardest and most compact woods do not always resist the at- tacks of these insects, which, further, do not spare every kind of odorous wood, cedar for instance. In such countries it is altogether imp. ssible to preserve books and papers. I remember, in connec- tion vith this matter, that having received instructions to examine the archives of Anserma, one of the oldest towns in Popayan, in 1830, I found nothing but books illegible and in pieces ; neverthe- less, the date of the documents, which it was my business to con^ult, could not have been older than the year 1600. The dry rot, which results from the development and growth of cryptogamic plants upon wood, is the curse of navies. Mr. Knowles is of opinion that this disease of timber has been known from the most remote antiquity ; he believes that he can even recognise dry- rot in the sore called house-leprosy, mentioned in the 14th chapter of Leviticus. A ship attacked by dry-rot, becomes in a very short space of time unfit for sea. The Foudroyant of 80 guns is often quoted as an instance of its destructive powers : launched in 1798, she had to be taken into dock and almost rebuilt so soon as 1802.* The fungi which induce dry-rot have been studied by Sowerby. Mr. Knowles signalizes two species in particular ; one of which he describes under the name of Xylostroma giganteum, the other under that of Boletus lacrymans. The Xylostroma does not extend beyond the part where it is developed ; but the Boletus, on the coalrary, it * Pupia, Ann. de Chimle, t. xvii. p. 290i PRESERVATION OF TIMBER. 105 piDpagated with frightful rapidity, and disorganizes deeply and to a great distance around the texture of the wood where it once appears These fungi are generally found on board ship, between the planking and the ribs, in damp situations, and where the air is scarcely, if ever, changed.* The temperature most favorable to the development of dry-rot has been found to lie between T and 32" cent, or 45° and 90° F. These are the extreme limits : below the minimum vegetation languishes ; above the maximum, the fungi droop. With this piece of informa- tion it was hoped that vessels might be freed from dry-rot by raising the temperature sufficiently. The trials were made in winter in the " Queen Charlotte," the air in the lower part of the ship being raised as high as 55° cent, or 130° F. But the general result did not an- swer expectations ; for although the fungi were destroyed in the low- er part of the vessel, it was found that their growth was rather fa- vored in places at a certain elevation above the kelson. The warm air, in fact, as it rose through the timbers became robbed in its course, and deposited the greater portion of the moisture which it had taken up at a lower level. Above the orlop deck, consequently, there was just about the temperature and the quantity of moisture most favora- ble to the development of the fungi. The evil was therefore only transplanted, not destroyed. It was now proposed to heat the "'tween decks" at the same time as the hold, making use of due ventilation ; but this method of p'-oceeding has not been put intp prac- tice. The extreme slowness of the growth of trees stands in strong con- trast with the rapidity of their decay when they are reduced to the shape of timber and employed in constructions of almost every kind. In countries well advanced in civilization, every description of in- dustry tends to consume timber, at the same time that an increas- ing population is every day contracting the extent of forest land, and diminishing the number of trees grown. In some countries, in- deed, it is certain that the production of wood for all purposes, firing, &c., &c., is no longer in relation with its consumption. The price of the article, necessarily high, is therefore tending continually to rise ; and it is not surprising that various measures have been sug- gested and essayed of giving this perishable material greater dura- bility. The well-known great durability of certain trees, the teak, ebony, lignum-vitae, &c., naturally led to the conclusion that the fatty or resinous matters which they contain have the property of preserving the wood against the greater number of the ordinary causes of de- cay ; and unctuous and resinous matters appear in fact to have been •he means most anciently employed to preserve wood from the air, from moisture, and from the attacks of insects. But it is scarcely necessary, at the present time, to say that these varnishes only ac- complish the object proposed in their application in a very imperfect wa^ ; paint and varnishes crack, rub, or scale off with the slightest • Dupin, Ann. de Chimie et de Physique^ t. xvii. p. 291, tie »*ne. 106 PRESERV^ATION OF TLMBER. friction ; nor do they always remove the causes of internal decay on the contrary, by preventing- more complete dryness, they some- times even provoke or favor them, when applied to tender, that is, imperfectly seasoned wood. Merely laid on the surface, indeed, it his always been seen that varnishes of any kind were but indifferen* protectors ; that a really good preserver ought to penetrate the sub- stance of ti..v3 wood, and unite with the tissue itself. But herein lay the whole difficulty ; how was the needful penetration to be effected 1 for the number of chemical substances, from which good effects might reasonably be anticipated, is pretty considerable, — unless in- deed we find ourselves prevented from using them by the considera- tion of the price ; for it is imperative that any preservative proposed be extremely cheap. For a long time the only process for effecting the penetration of timber by substances proposed for its preservation was to macerate them for a longer or shorter time in a solution of the substance. But this means was found as tardy of accomplishment as it was or- dinarily imperfectly effected ; to have got to the heart of logs of large scantling, years would have been required. Any delay, how- ever, in such circumstances, is of itself a cause of enhanced price of the article. By and by a variety of processes, the element in one being pressure, in another exhaustion, were put in practice, and very satisfactory results obtained. M. Breant showed, that by means of strong pressure he could fill the largest logs from one end to the other with any unctuous or resinous substance proposed, in the course of a few minutes. M. Moll, a learned German, proposed creosote introduced in the state of vapor by forcing, as an effectual means of preserving timber, which it probably would be found ; but the high price of the antiseptic, were there no other objections, would neces- sarily be an obstacle to its general employment. The same objection applies to the bichloride of mercury, (Kyan's patent;) and arsenic is inadvisable from its deleterious effects upon the animal economy. Some workmen are said to have lost their lives in consequence of working timber which had been impregnated with a solution of whit(» oxide of arsenic. It had been observed that vessels engaged in the lime-trade lasted long ; and then it was naturally thought that by impregnating the wood to be used for ship-building with lime it would be rendered more durable. But the result did not answer expectation ; the tim- ber treated with lime did not even seem to last the usual time.* Such was the state of the question when Dr. Boucherie made a highly important communication to the Royal Academy of Sciences on the preservation of timber. f Some estimate of its nature may be formed from the list of subjects discussed in this remarkable paper. 1. To protect timber against dry-rot and the ordinary wet-rot 2. To increase its hardness and strength. 3. To ppjserve its flexibility and elasticity. • Dupin, Ann. de Chlmle, t. xvil. p.28S t Idem, t. Ixxiv. p. 113. PRESERVATION OF TIMBER. 107 4. To counteract its alternate contraction and expansion in conse- quence of the varying state of moisiness and temperature of the atmosphere. 5. To diminish its inflammability and combustibility. 6. To give it a variety of permanent colors and odors. In the whole of his experiments M. Boucherie set out from this proposition, the truth of vv^hich appears indisputable and to require no comment, viz : That all the changes which wood undergoes pro- ceed or depend upon the soluble matters which it contains. In confor- mity with this idea, the first step towards giving durability to timber was, either to render these matters insoluble and inert, or to remove them entirely. M. Boucherie, therefore, in his first trials sought to render the matters insoluble by charging the wood with a substance capable of combining chemically and forming a precipitate with the soluble matter left by the sap. To resolve this problem, M. Boucherie investigated the reactions between the soluble matter of wood, which it was his object to precipitate, and a variety of low-priced chemical agents. He found that the pyrolignite of iron combined the greatest number of desirable properties : it is very cheap, the oxide of iron forms stable compounds with the greatest number of the organic substances which are found in the sap of vegetables, and, to conclude, the crude pyrolignite contains a notable quantity of creosote. The facts upon which M. Boucherie relies as proving the preser- vative powers of the pyrolignite of iron flow from numerous experi- ments performed either on vegetable substances which in themselves readily and rapidly undergo changes ; or upon billets of wood of diflferent kinds. A quantity of flour, the pulp of carrots, beet-roots, &c., impregnated with the pyrolignite resist decomposition in a very remarkable manner in contrast with the same substances when they have not been prepared in any way. The wood which was selected for trial, was generally of the most perishable kind. In December, 1838, several empty hogsheads and barrels made of the best timber unimpregnated and impregnated with the pyrolignite were placed together in the dampest parts of the great cellars of Bordeaux. In August, 1839, it was easy to see that the unimpregnated tubs were already deeply stricken, and after from two to three years they fell to pieces with the slightest force ; the casks made of the prepared wood, however, were as sound as on the first day of the experiment.* M. Boucherie concluded from his experiments instituted with a view to the settlement of the question, that about ^^'^th of the weight of the wood in its green state of the pyrolignite was adequate to precipitate and render insoluble all the principles obnoxious to change, which were contained in the woody tissue. M. Boucherie, while he regards the pyrolignite of iron as at once the most powerful, and one of the cheapest preservatives of timber, nevertheless indicates several soluble salts, which are readily avail- able in consequence of their low price, and also very effectual when * Comptes Resdas, t. ii. p. 8[«& 108 PRESERVATION OF TIMBER. the wood, which they are to preserve, is not kept constantly wet. Solutions of common salt, of chloride of lime, the mother-water ol salt-marshes, &c., were all tried and found useful : casks, the wood of which had been prepared with the chlorides, after having been long kept in very damp cellars, came out as fresh as those which had been impregnated with the pyrolignite of iron ; the flexibility of the wood preserved with these alkaline and earthy salts was further as CTreat as at the beginning of the experiment. Having now come to a conchision in regard to the substances most effectual in preserving wood, the next business was to make them penetrate its tissue most intimately. Maceration, M. Bouche- rie soon found, like his predecessors in the same path, to be insuf- ficient, the substances in solution only penetrating a very little way. He then tried various processes of injection ; but all inferior to that imagined by M. Breant^ and therefore less effectual. He then be- thought him of effecting the needful penetration of the wood in the green state, and before it had been sensibly altered by drying and seasoning ; he asked himself if the force which determines the ascent of the sap might not be taken advantage of after the tree was cut down, as a means of determining the entrance of a solution of pyrolignite of iron 1 And all his trials in this direction answered his expectations fully. M. Boucherie had, in fact, discovered a means of securing the penetration of the minutest pores of the largest log by a substance capable of rendering it incorruptible. No one before M. Boucherie thought of taking advantage of an admitted physiolo- gical fact for such a purpose. He announces the principle upon which he proceeds in these terms : " If a tall tree be cut down at the proper season, and the bottom of the trunk be then immersed in a saline solution, weak or strong, the liquid is powerfully drawn up into the tree, penetrates its most intimate tissues, rises to its small- est branches, and even to its terminal leaves."* In the month of September, a poplar, upwards of 90 feet high and nearly 16 inches in diameter, was cut, and the bottom of its bole plunged in a vessel containing a solution of pyrolignite of iron mark- ing 8° of the areoQfieter of Beaume ; in the course of six days it had absorbed upwards of 66 gallons of the fluid. In his first experiments, M. Boucherie procured the needful absorption by placing the bottoms of his trees in vessels containing the solution ; but this mode of proceeding was obviously full of dif- ficulties and open to many objections : the weight of a green tree of large size, with the whole of its top and branches, is often enormous, and to raise a mass of the kind once down again into the perpen- dicular was no easy task ; it implied recurrence to certain mechani- cal means which are not always £t hand, and necessarily expensive. M. Boucherie, therefore, tried ether modes of making the trees absorb ; he adapted a sac of imp.jrmeable material to the bottom of the trunk laid on the ground, and into this sac he poured his solution, «.nd this method answered very well. He next took advantage of ♦Ami. de Chuuic, U !x.\iv. y. 132< TRESERVATION OF TIMBER. 109 one or more of the roots to effect the imbibition. He next bored a hole into the bottom of the trunk, still erect ; and having brought the cavity thus made to communicate with a reservoir, he still suc- ceeded. This last plan was still further simplified in proceeding as follows : the trunk of the tree is pierced by an auger through nearly the whole diameter. Into the auger-hole thus made, a narrow saw is passed, by working which on either side, the trunk is divided in- ternally to a very considerable extent, and the majority of its sap- vessels are thus cut across and made accessible. An impervious cloth is then tied round the trunk, below the opening, and this is made to communicate with the reservoir of liquid.* M Boucherie was almost necessarily led, in the course of his ex- periments, to inquire whether the absorbing power of trees differed at different seasons or not. lie ascertained by trials made in the months of December and February, that though in the oak, the horn- beam, and the plane, the solution of pyrolignite of iron always rises several feet, and even several yards, yet that in the colder season of the year, it never rises so high as it does in summer, in spring, and especially in autumn, the season in which the power of ascent is most remarkable. This conclusion is obviously of interest physio- logically. It proves that if winter be a season of repose for the sap, it is not so absolutely. There is one remarkable exception to the general fact now announced, and this occurs among the resinous trees that keep their leaves till the spring. It has been ascertained, by direct experiment, that the ascent of the sap continues through the whole course of the winter in the cone-bearing trees, and this to such an extent, that it is always possible to impregnate every part of their trunk by the way of simple absorption at any period of the year. As M. Boucherie remarks, this fact might even have been foreseen from the fresh and green state of the leaves of these trees. It now became important, in connection with the practical appli- cation of M. Boucherie's views, to ascertain whether or not the penetration was energetic in the ratio of the vigor of the tree itself, in proportion as it was more numerously provided with branches, more thickly covered with leaves. Experiment showed that the penetration still takes place after the removal of the greater number of branches, provided only the leading bough or terminal crown be left. A stem furnished with a number of leafy branches continues, as has been said, to imbibe, though separated from the roots ; but for how long a time will it continue to do so ] This was a capital point to determine. At the end of September, the bottom of a pine- tree, about 14 inches in diameter, was first put into the solution 48 hours after it had been felled ; nevertheless the imbibition was com- plete. In June the same success attended the experiment made on a plane that had been cut for thirty-six hours. Still it is certain that the penetration takes place with so much the more energy as it is arranged close upon the time of the felling. The power by which it is determined declines rapidly after the first day is passed, and by * Boucherie, Ann. de Chimie, t. Ixxiv. p. 134. 2e s6rie 10 110 PRESERVATION OF TIMBER. the tenth day it is almost entirely gone. In favorable circumstances these ten days suffice to effect the complete impregnat4nn of the largest stem. In one of his experiments upon a poplar, M. Boucherie saw the absorbed liquid reach the height of about 95 feet in seven days. In the white woods it is found that there is an axis of variable diameter in different cases which escapes or rather which resists impregnation. In hard woods the parts which are not penetrated are the inner or undermost circles of the heart. M. Boucherie, after having ascertained these facts, explains them thus : in the white woods, according to the testimony of the workmen, the central part which resists the penetration is at once the weakest and the most perishable portion of the log ; there is no longer any circulation, any life there ; it is dead wood interred in the midst of the living woody layers. This absence of penetration of the woody tissue appears, on some occasions, elsewhere than in the centre of the trunk and branches ; it presents itself under the most various forms and in different parts of the trunk : it appears to depend, as has been said, on the presence of wood abstracted from the influence of vital phe- nomena, and which, impenetrable itself, presents a barrier or an ob- stacle to the passage of the solution to other parts ; it is thus that a knot, or a piece of rotten wood, is generally found as the starting point of the zones that have escaped imbibition. As to the non- penetration of the most central parts of the heart of oak, elm, &c., M. Boucherie views it as affording unquestionable proof of the fact that there the living juices of the tree had long ceased to circulate. The distinction generally drawn between the white or soft, and the perfect or hard wood, rests on the differences of color presented by a transverse section of the trunk. In the oak, for example, the external and nearly white concentric layers are held as the soft and valueless portion of the log, and are commonly hewn away in squar- ing it ; the darker, more central portions constitute the heart-wood, the valuable timber. But, according to M. Boucherie, the distinc- tion is different when the fact of penetrability is taken as the guide, and all that portion of the trunk which imbibes is considered as alburnum, or soft wood, and all that does not imbibe is regarded as hard wood. The alburnum in this way is so much extended that it may be found constituting three-fourths of the whole mass of the trunk. Once introduced, the pyrolignite of iron, according to M. Boucherie, is not only useful in preserving the wood, it also in- creases the density of the timber. Impregnated with this salt of iron, wood becomes so hard as powerfully to resist the tools of the oarpenter and joiner, who even complain of the increased difficulty with which it is worked. - Flexibility and elasticity in timber are qualities in request for cer- tain purposes, particularly for ship-building. The fir timber of the north of Europe is much more prized than that of the south, espe- cially for masting, on account of its greater flexibility and elasticity, qualities which appear to depend in a great measure en the quantity of noisture retained ; to increase these qualities M. Boucherie has PRESERVATION OF TIMBER. Ill eT«'i> intioduced bv imbibition a deliquescent salt, such as the muri- avit 'jf li.iJv, whioh retains moisture powerfully, as is well known, anl seems to have tna power of giving a remarkable degree of sup- pleness to wood. The experiments, contrived to show the effects of dehquescent silts, were made upon deal, which is allowed to be oncsof the most brittle woods. After having impregnated it with concentrated solutions it was sawed into very thin veneers, some of which I have seen in the possession of M. Boueherie, which after being strongly twisted and bent in various senses, immediately re- gained their original flatnesa and evenness when they were left free. Warping, or shrinking, is occasioned by alternate shrinking and swelling in consequence of varying hygrometric states of the atmo- sphere. When timber is worked before it is thoroughly seasoned, — and this is apt to happen in regard to pieces of large scantling es- pecially— the shrinking is of course extremely conspicuous when the time necessary to complete desiccation has elapsed. It is this in- convenience which makes it imperative on builders of all kinds, ship- builders more especially, to keep stocks which necessarily absorb a considerable amount of capital. It has long been a question with engineers to find a remedy for this state of things. Seasoning, in- deed, is now effected somewhat more quickly by squaring the logs at the time the trees are cut down ; but the loss of time is still very considerable. The mode of seasoning by the stove or vapor has been abandoned as too costly. After having found that the shrinking and separation of pieces of carpentry did not begin to take place until the timber was upon the point of losing the last third of the moisture- which it contained at the time of being cut, M. Boueherie thought that to prevent all warping and shrinking it would be enough to retain this quantity of water in combination with the woody tissue ; in other words, to pre- vent complete desiccation. Facts have proved the correctness of this view. Pieces of vv^ood kept at a certain unchanging degree of moistness by means of a deliquescent salt infused into their pores, do not change their bulk or form, in spite of extreme variations in the hygrometric state of the air. Such pieces of wood, however, exhibit great differences in point of weight under the influence of different circumstances. Several planks of great breadth and extremely thin were prepared with chloride of lime and joined together ; some of them were left unpainted, others were painted on one side, or on both sides ; after the lapse of a year these planks were found not to have shrunk or warped, while similar planks of the same thickness and kind of wood, but unprepared, were found to have cast in an extraordinary way.* M. Boueherie has done more than this ; he has not only had it in view to preserve wood and to prevent it from warping, qualities so desirable, — he has made use of the same faculty of imbibition to im- * Boueherie, op. cit. p. 151. 112 PRESERVATION OF TIMBER. pregnate the wood with a variety of beautiful colors, and thus to give even the most common kinds tints that will admit of their being used in the construction of costly furniture. The pyrolignite of iron alone gives an agreeable brown tint that harmonizes excellently with the natural color of the harder parts of so many trees which usually resist penetration. By following up the pyrolignite with an infusion of nutgalls or oak-bark, the mass of the wood is penetrated with ink, which presents a black, blue, or gray color, according to circumstances; a solution of another salt of iron succeeded by one of prussiate of potash will cause a precipitate of prussian blue in the wood, &c. ; in short, by the numerous reactions of this kind with which chemistry is familiar, a great variety of colors may be ob- tained. Among the number of useful properties communicated to wood by impregnation with saline solutions, that of being rendered little apt for combustion ought not to be omitted. M. Gay-Lussac was the first who thought of rendering vegetable tissues incombustible by means of saline impregnations.* By incombustible, we are not to understand unalterable by a red heat ; for every one must see that the protecting power of no salt can extend so far as this ; but tissues which take fire very readily, and burn with great rapidity, cease from giving any flame, and merely smoulder, after they have been impregnated with certain salts ; they take fire with difficulty, go out of themselves, become charred, and are incapable of propagating fire. And this is exactly what happens with wood which has been properly charged : it burns, and is reduced to ashes with extreme slowness, so that two huts exactly alike, built one of charged wood, and the other of ordinary wood, having been set fire to at the same moment, the latter was already burned to the ground, when the in- terior of the former was scarcely charred. f The ingenious process of impregnating wood by the way of vital inspiration is not without certain objections. In the first place, it can only be performed at those periods of the year when the sap is in motion, and the trees are covered with their leaves. This time, however, is limited to a few months of the year, and the usual prac- tice being to fell timber in the winter, wont and usage are opposed to cutting down trees in the spring and autumn. To meet these objections, M. Boucherie engaged in new experiments, which led him to a means of impregnating timber at all seasons, in winter as well as spring and autumn, and in a very short space of time ; this second method is applicable to wood that has already been squared as well as to the round trunk, provided it has been recently felled. To impregnate timber by this process, the logs are placed verti- cally, and the upper extremities are fitted with an impermeable sack for the reception of the saline solution destined to charge them ; the fluid enters from above, and almost at the same moment the sap is Been to begin running out below. There are some woods which ♦ Ann. de Chimie, t. xviii. p. 21], 2e sirie. t Idem, t. l^xiv. p. 1.52, 3e s6rie. PRESERVATION OF TIMBER. 113 include a large quantity of air in their tissues ; in this case the flow does not go on until this air has heen expelled ; once begun, it goes on without interruption. The operation is terminated when the fluid, which drips from the lower part, is of the same nature as that which is entering above. In my opinion this method must be pre- ferable to that by aspiration. In the second mode of proceeding, in fact, we accomplish our object by a true displacement ; almost the whole of the sap is expelled, and the saline solution introduced has only to subdue or neutralfze the very small quantity of soluble organic matter which may remain adhering to the woody tissue. By accomplishing such a displacement by means of simple water w« should undoubtedly obtain results favorable to the preservation of timber, inasmuch as we should have freed it from almost the whole of those matters which are regarded as the most alterable them- selves, and the first cause of rotting in timber. The rapidity with which the fluid introduced is substituted for the sap which it dis- places, and the quantity of this expelled sap which may be readily collected, exceeds any thing that could have been imagined before making the experiment ; thus the trunk of a beech-tree about 52^ feet in length by 33^ inches in diameter, and consequently forming a cube of somewhat more than 29 feet and a half, gave in the course of twenty-five hours upwards of 330 gallons of sap, which were re- placed by about 350 gallons of pyroligneous acid. The liquid which penetrates in this way acts so effectually in displacing the sap, that M. Boucherie says we can readily procure or extract by its means the saccharine, mucilaginous, resinous, and colored juices contained in trees. It would, perhaps, be possible, and I beg to suggest this idea to colonial planters, to apply the method of displacement to the extraction of the coloring matters of dye-woods. The trade in dye- woods does not extend beyond localities favorably situated for ex- portation, so that at a certain distance from the shores of the ocean, or the banks of rivers, it is found absolutely impossible to carry on a trade, the material of which is so heavy and bulky as timber. The greater number of the coloring matters found in wood^ being soluble, it is possible to export them in the state of extract. Various attempts of this kind have already been made, and if they have not been successful, the obvious cause of this lies in the method which has been followed, and which has hitherto consisted in treating the wood reduced to chips by means of boiling water, and then reducing the colored solution obtained ; but it is obvious that in the remote forests of America, or of Africa, where all mechanical means are wanting, nothing but failure could attend upon such a procedure. By the method of M. Boucherie, the main difficulties appear to be got over ; there is nothing more to be done, in fact, than to get the trees into the state of logs, and these are generally readily trans- portable, after which one or more evaporating pans seem all that are further necessary. Dye-woods. — The greater number of these woods belong to the family of leguminosaj ; the principal kinds met with in trade are : I. Mahogany wood, {hmnatoxylon campechianum,) of a reddish 10* 114 SUGAR. yellow, which becomes brown with age ; this wood, besides a variety of alkaline and earthy salts, of volatile oil and unazotized matter, contains a particular coloring principle, called hematine, discovered by M. Ciievreul* The mahogany grows in the hot intertropical regions of America ; Mexico and some of the West India islands export considerable quantities. Pernambuco or Brazil-wood is the name given in trade to the trunks of several trees of the genus Ccesalpinia. The Casalpinia crista of Jamaica, the C. sappan of Japan, the C. echinata of Santa Martha, afford kinds that are very much prized. In point of chemi- cal composition Brazil-wood agrees with Campechy wood ; the col- oring matter which characterizes it has been named Braziline by M. Chevreul ; it is obtained in small crystals of an orange color. This wood comes to Europe in fagots of about 39 inches in length. Red Saunders-wood is furnished by the Plarocarpus san- talinus ; it contains a peculiar dye-stuff, santaline, observed by M. Peltier.f To conclude., the yellow dye-woods of commerce are Fustic, i?/m* cotinus, of the family of turpentine trees, a native of the south of Europe, and the Cuba and Tampico woods, which are probably va- rieties of the Morus tinctoria. OF SUGAR. Sugar is met with in almost every part of vegetables ; it has been found in flowers, in leaves, in stems, and in roots. It is less abun- dant in seeds ; and it may even be said that the quantity of saccha- rine matter contained in vegetables in general is invariably diminished at the period of formation of the seed. Sugar, consequently, as well as starch, appears to contribute to the production of the seed. The very characteristic taste of sugar generally suffices to pro- claim its presence ; nevertheless, it would be a great mistake did we rely upon this character alone for discovering the presence of sugar ; several substances possess a very decided sweet taste, with- out being on that account sugar, in the sense which chemists attach Ixi the name. True sugars, according to chemists, have one properi) which distinguishes them from all substances with which they maj have, in other respects, the greatest analogy ; this characte;isti» property is that of becoming changed, under the influence of wato a suitable temperature, and contact with yeast, into alcohol and cai bonic acid. It is certain, nevertheless, that certain bodies which d not belong to the chemical genus, sugar, may, under the influence o fermentation, yield alcohol. I have already quoted starch as coming under this head ; but it has been distinctly ascertained, as 1 have als« said, that such substances, under the influence of the ferment itsell are first chnnged into sugar, which subsequently undergoes the vi nous fermentation. * Chimie appliqu^e a la teinture, 30e le^on, p. 88. t Chevreol, Cheoiistry applied to dyioe, 30tb Uctor*, p. WL SUGAR. It5 It is admitted at the present time that fermentable su^rs must be divided into two principal species, in harmony with characters which are most easily appreciated. One of these presents itself in the shape of hard, transparent crystals, and is met with in sufficient quantity to be profitably extracted from the juice of the cane and the beet, the sap of the maple and of certain palms ; the other is obtained with some difficulty in the solid state, being most frequently and readily procured in the form of sirup ; the taste of this is less sweet, less decided ; it exists in the grape and the greater number of fruits. The chemical characters of these two kinds of sugar, which are designated cane-sugar and grape-sugar, are somewhat different; and the elegant researches of M. Biot have shown, that from some of their physical properties, particularly the action of their solutions upon polarized light, they cannot be regarded as constituting one and the same species. In the vegetable kingdom, these two kinds of sugar are frequently met with mixed ; and there are certain chemi- cal means which enable us readily to transform cane-sugar into grape-sugar. The inverse transformation has not yet been accom- plished ; but there is nothing which leads us to conclude that it is impossible ; and the time, perhaps, is not very remote when the sugar which is manufactured from potato- starch may be changed into crystallized sugar, similar to that which is obtained from the cane. Crystallized sugar. Cane-sugar is readily obtained in large transparent crystals, which are known under the name of sugar- candy. Sugar is fusible : under the action of a regulated tempera- ture, it acquires a dark-red color, and passes into the state of cara- mel ; a higher temperature effects its decomposition. It is much less soluble in alcohol than in water ; highly concentrated alcohol, indeed, only dissolves an extremely small quantity of sugar. M. Peligot's analysis of cane-sugar shows it to be composed of— Carbon 42.1 Hydrogen 6.4 Oxygen 51.5 100.0* Such is the composition of sugar dried at the temperature ol boil- ing water ; but the substance, like the majority of organic matters, still contains a certain proportion of constitutional water, which it abandons when it combines with certain bases. Thus sugar com- bines with oxide of lead, and forms a true saccharate, in which the sugar, deprived of its Avater of constitution, plays the part of an acid ; this combination, which presents itself to us under the form of white niammillated crystals, analyzed by M. Peligot, would indicate the following as the composition of anhydrous sugar — Carbon 47-1 Hydrogen 5.9 Oxygen 47.0 100.0 * Annales de Chimie, vol. Ixvili. p. 134, 3e t^ii*. 116 SUGAR. Ordinary sugar, deprived of its water of composition in any othei way, has the same elementary composition ; thus caramel obtained hy heating sugar to 180° cent., (356" Fahr.,) until it no longer loses watery vapor, has, according to M. Peligot, the composition of an- hydrous sugar, such as it is found in combination with oxide of lead. Setting aside all theoretical considerations, it is obvious that to have anhydrous sugar reconstituted ordinary hydrated sugar, it were necessary to add to 100 parts 11.76 of water, containing 1.3 hydro- gen and 10.46 oxygen ; the 111.76 parts then contain, in element • Carbon 47.1 percent. 42.1 common sugar Hydrogen 7.2 " 6.4 *' Oxygen 57.46 " 51.5 " 111.76 100.0 Common sugar may therefore be viewed as composed of 100 anhy- drous sugar, and 11.8 water. The whole of the sugar which comes from South America and the West Indies, and a large proportion of that which comes from the East Indies, is extracted from the juice of the sugar-cane. In America three principal varieties of sugar-cane are cultivated, the Creole, the Batavian, and the Otaheitan. The Creole cane has the leaf of a deep green, the stem slender, the knots very close to- gether. This species, a native of India, reached the new world after having passed through Sicily, the Canaries, and the West In- dia islands. The Batavian cane is indigenous in the island of Java ; its foliage is very broad, and has a purple tint ; the sap of this vari- ety is much employed in making rum. The Otaheite cane is that which is most extensively grown at the present time ; it was intro- duced into the West India islands and neighboring continent by Bou gainville. Cook, and Bligh, in their several voyages, and is certainly one of the most important acquisitions which the agriculture of trop- ical countries owes to the voyages of naturalists. This variety of cane grows with extraordinary vigor : its stem is taller, thicker, and richer in juice than that of the other species. I observed it along the whole coast of Venezuela, of New Grenada, and of Peru ; far from having degenerated by its transplantation to the American con- tinent, it appears to have preserved all its original qualities without alteration. The sugar-cane is propagated by cuttings. Pieces of the stem about 18 or 20 inches long, and having several buds or eyes, are placed two or three together in holes a few inches in depth, and are covered with loose moist earth. From a fortnight to three weeks are required for the shoots to show themselves above ground. The space to be left between each clump of plants depends much on the fertility of the soil ; in the most fertile soils the distance may be about a yard, or a little more ; and along the rows the spaces may be about 18 inches. Where land is of no great value it is found more advantageous to give greater space, and so to favor the access of the air and the light. It is not uncommon to see plantations where the canes are spaced at distances of between 4 and 5 feet. The SXTGAR-CANE. 117 time at which the setting of the slips takes place cannot be defini- tively indicated ; it depends entirely upon the epoch at\Ajich the periodical rains are anticipated. But in places where irrigation is possible, the setting goes on through all the months of the year. The holes for the reception of the slips are usually dug with a hoe, and a negro will make from sixty to eighty holes in the course of a day. When the ground has been previously ploughed, as it is in some of the West India islands, he will make twice as many. Loose rich soils, when they have a certain moisture, are the best adapted to the sugar-cane ; it does not thrive in an argillaceous soil, which drains with difficulty. In these moist soils the slips are not laid horizontally and covered, bu-t with one end projecting a little way out of the ground. When the young shoots are covered with nar- row and opposed leaves, watering is particularly advantageous, and the plants are repeatedly hoed until they have acquired sufficient vigor to choke noxious weeds. About the 9th month after the plan- tation of the slips, the shaft of the sugar-cane begins to lose its leaves, the most inferior falling first, the others in succession, so that when arrived at maturity, it only presents a tuft of terminal leaves. The flowering generally takes place with the conclusion of the year ; and the cane is held sufficiently ripe in from two to three months after this epoch, when the stem has acquired a yellow or straw color. The planters, however, are by no means agreed as to the proper period of the sugar-cane harvest, — some even insist upon cutting before the flowering, believing that the quantity of su- gar diminishes on the appearance of the flower. It is unquestiona- ble, however, that the period that elapses between the planting and the harvest, must vary with the nature of the soil, and especially with that of the climate ; while in some places the cane may be cut when it is a year old, doubtless there are others where it requires to stand from fifteen to sixteen months. In Venezuela, where the Ota- heite cane is grown at the level of the sea, and where the mean tem- perature of the year is between 81° and 82° Fahr., the cane ripens, according i\, Dolonel Codazzi, in eleven months. In districts at greater elevations under the same parallels of latitude, where the climate is of course not so hot, the cane requires a longer time to come to maturity ; where the mean temperature is about 78" Fahr., twelve months are required ; where it is about 74° Fahr., fourteen months become necessary ; and where it is no more than about 67° Fahr., sixteen months are requisite.* The Otaheite cane grows to very different heights ; in very favorable circumstances it will reach a height of 16 feet and upw^ards, but its general height may be stated at from 9h to 10^ feet. Great cane, plantations are divided into squares of from 100 to 120 yards on the side, each of which coming to maturity in succession, the labor is easily performed, both in re- gard to field-work and the manufacture of the sugar. The cane is cut close to the root, and before being carried to the mill, the tey rainal tuft of leaves is struck oflf. The.^^e h-^ads in the * Codazzi, Geography of Venezuela, p. 141. 118 SUGAR-CANE. green state afford excellent food for horses and cattle ; when dry they are used for thatching- houses. After the first cuting, fresh sprouts arise, which require no other attention than hoeing. In good soils one planting will yield five or six harvests by successive shoots ; but I have heard planters affirm, that the produce in sugar diminishes from year to year. In Venezuela, cane-pieces are re- planted every five or six years. The cane with its top struck off is carried to the mill, where the juice is expressed, and the stems, which are spoken of under the name of trash, are dried and used as fuel. The expressed juice contains crystallizable sugar, an azotized substance analogous to albumen, and some saline matters dissolved in a large quantity of water, which is dissipated by boiling, and the sugar finally won by crystallization. The manufacturing process is conducted with very different degrees of perfection in different places. In some the produce is obtained almost without admixture of molasses, in others the quantity of this article which drains away from the sugar is very large. It is now generally agreed that mo- lasses proceeds in great part from imperfections in the manufacturing processes employed, especially to changes which the sugar under- goes in the course of its concentration by boiling at a high tempera- ture. By the employment of what are called vacuum pans of vari- ous construction — pans from which the pressure of the atmosphere is removed either by the air-pump, or the condensation of the vapor as fast as it is formed, rapid evaporation is effected at a temperature much below that of boiling water, by which it is found that the rela- tive quantity of sugar to that of molasses is greatly increased. I was long believed, indeed, and that on the authority of the first chemists, that there were two kinds of sugar contained in the sugar- cane, one crystallizable, the other uncrystallizable, and constituting the molasses or treacle. The researches of M. Peligot* have shown definitively that this conclusion is erroneous, that the cane con- tains no sugar that is not crystallizable, and that the pre-existence of uncrystallizable sugar or molasses is entirely chimerical. M. Plague had indeed come to the same conclusion some considerable time ago — as far back as 1826 ; but his labors were not made known by publication till 1840. M. Casaseca, professor of chemistry at Havana, has very lately confirmed these conclusions, so important for the sugar husbandry of the world. f The composition of the juice of the sugar-cane is therefore less complex than it was once believed to be ; making abstraction of very minute quantities of an albuminous azotized substance, of several salts and a little silica, substances which altogether do not amount to more than two or three hundredths, cane juice may be said to consist of water and of crystallizable sugar in the proportion of from 17 to 20 per cent | The Otaheite cane analyzed by M. Peligot actually yielded : ■^ Ann. Mdiivimcs et Coloniales, Aug. 1842. I Vide Comptes Rendus, 1844. % Peligot, op tit SUGAR-CANE. 119 Water 72.1 Woody matter 9.9 Soluble matter (sugar) 18.0 mo" Ti is conclusion was verified by M. Dupuy at Guadaloupe in 1841, who, operating on the spot, found the composition to be as follows • Water 72.0 Woody matter 9.8 Soluble matter (sugar) 17.8 Salts 0.4 100.0 The analyses of the Creole cane made by M. Casaseca at Havana appear to indicate a larger quantity of woody fibre : Water. 65.9 Wood 16.14 Sugar 17.7 100.0 The quantity of sugar yielded by the cane, differs considerably. M. Codazzi assigns 6 and 15 per cent, as the extremes, and 7^ per cent, as the mean. M. Dupuy gives 7.1 per cent, as the average. The quantity is, of course, first and most intimately connected with the quantity of juice obtained. But the produce of juice is extremely variable. In Guadaloupe, the juice varies between 56 and 62 per cent, of the cane subjected to pressure. The generality of mills do not, in fact, enable us to obtain more than about 56 per cent. At New Orleans the usual quantity obtained is said to be 50, and in Cayenne only 36 per cent. At Havana, according to M. Casa- seca, the riband cane yields 45, the crystalline 35, and the Otaheitan 56 per cent, of juice. The Otaheite cane was examined by M. Peligot, under a variety of circumstances of age, growth, part of plant, &c. &c. The fol- lowing table contains the condensed results of his experiments : First shoots ■ Second do. from original sprouts • Third do. from second do. Fourth do. from third do. Inferiorpart of cane Middle part of do Superior part of do. Knots Cane of eight months Cane of ten months Water. Soluble mat- ters (suffar.) Woody fibre. 73.4 17.2 8.9 71.7 17.8 10.5 71.6 16.4 12-0 73.0 16.8 10.2 73.7 15.. 5 10.8 72.6 16.5 10-9 72.8 15.5 11.7 70.8 12.0 17.2 73.9 18.2 7.9 72.3 18.5 9.2 It would therefore appear, making exception always of the knots which occur in the course of a cane, that the composition of the plant in its various states and conditions, is almost identical. M. Peligot's important paper, while it informs us of the average com- position of the Otaheite cane, satisfies us that the gummy and mu 120 SUGAR-CANK. cilaginous substances and the uncrystallizable sugar, tie existence of which was held as demonstrated, are, in fact, nowise constituents of the sugar-cane. Whence we may conclude, with M. Peligot, that every drop of molasses which drains from the sugar is the produce of the manufacture ; an opinion to which I assent the more readily from having myself seen oftener than once the juice of the cane yield nothing but crystallizable sugar These analyses further de- monstrate, more powerfully than could any discussion, the imperfec- tion of the processes usually followed in manufacturing sugar. They prove, in fact, that in the mill rather more than a third of the whole juice contained in the cane is left in the trash. This loss might be considerably diminished were more perfect pressure employed in extracting the juice. But it appears that the planters are indisposed to crush the trash too much, as by this it is rendered less fit for fuel, a considerable quantity of which, by the present mode of manufac- ture, is indispensable. M. Dupree, however, says that by insisting on obtaining from 65 to 66 per cent, of juice in all cases, the trash is still left with all its value as a combustible. The trash on coming from the mill appears quite dry. I have seen some which, after having been pressed twice consecutively, looked as if it were im- possible by any further amount of pressure to express more liquid. Nevertheless, it was enough to taste this pressed cane, to be satis- fied that it still contained a considerable quantity of sugar. To procure this without using more powerful machinery, M. Peligot proposed to steep the trash in water, and to press it a second time. By this means a weak juice is obtained, which, added to the first pressings, raises the produce of sugar from 7 to 10 per cent, upon the whole amount of cane employed. By following this process, suggested by theory, upon the great scale, M. Dupree has succeeded in obtaining |th more than the usual quantity of sugar without ma- king any change in his apparatus, and without finding the trash too much shaken to be burned under his coppers.* In some circum- stances the increase in the quantity of juice which this procedure implies, might be found an objection on account of the larger quan- tity of fuel required for its evaporation ; but wherever a supply of wood is to be had, M. Peligot's method ought undoubtedly to be ap- plied. The very dissimilar quantities of crystallizable sugar obtained from canes, which as we have seen all contain very nearly the same quan- tity of this substance, prove that the processes of concentration and purification of the sap also contribute to the loss which has been in- dicated. M. Peligot has pointed out several causes which concur to deteriorate sugar ; among the number: 1. A viscous fermentation which renders the sap thi(;k and stringy, like mucilage, by which the boiling becomes diflicult and the crystallization of the sugar which has escaped change, is rendered imperfect. 2. An acidity which takes place when the juice is not run at once into the coppers and boiled, an acidity which requires the addition of lime to destroy * Peligot, Maritime and Colonial Annals, August, 1848. SUGAR-CANE. 121 to prevent it. The alkaline iarth, as I have had occasion tc say, • by no means indispensable ; its utility under ordinary circunistan- ces is probably confined to assisting the defecation by forming an in- soluble precipitate with some of the organic substances which are always met with in small quantities in cane juice ; perhaps also to making an earthy soap with the fatty matters which adhere to the cane and are expressed in the crushing. When lime is added, to correct acidity, it forms an acetate or a lactate, salts which are pe- culiarly soluble, uncrystallizable, and which necessarily retain a quantity of sugar in the sirupy state. 3. The presence of certain mineral salts in the cane. Common salt, for instance, in combining with sugar forms a deliquescent compound, in which one part of salt is united with six parts of sugar ; such a compound as this of course renders a large quantity of sirup indisposed to crystallize. It is therefore impossible to be too cautious, according to M. Peligot, in the choice of manure for a cane-field ; that which contains any com- mon salt must needs be injurious in one way, however advantageous it may be in another. The entire absence of this salt in the soil of plantations which are very remote from the sea shore is perhaps one of the causes which increases the quantity of sugar obtained from the crop, and makes it more easily manufactured in such districts. M. Codazzi reckons the quantity of white sugar produced by a hectare of land, (2.473 acres,) planted with the Otaheite cane in the province of Caraccas, at 1875 kilogrammes, or 36 cwt. 3 qrs. 9 lbs. avoir. ; which is at the rate of 15 cwt. 1 or. 10 lbs. per acre. Taking 7| per cent, as the average quantity jf sugar obtained, the weight of cane brought to the mill must obviously have amounted to 19134 kilog. or 18 tons, 15 cwt. 3 qrs. 10 lbs. ; or 7 tons, 11 cwt. 3 qrs. 25 lbs. per acre. Assuming the average composition of the plant to be — Wood (dry) 11.0 Sugar (minimum) 15.5 Water .73.5 100.0 One acre of land will consequently yield a crop of — Tons. Cwt. Qrs. Lb* Wood (dry) 0 16 2 24 Sugar 1 3 2 6 Water -5 i^ ^ I? 7 11 3 25 The trash of the sugar-cane undergoes rapid fermentation : it soon exhales a distinct smell of vinegar, and almost the whole of the sugar which is left in it is destroyed. BEET-ROOT SUGAR. The presence of sugar in the beet was observed by Margraff; and Achard of Berlin by and by attempted the extraction of this sugar on the large scale ; but it was only during the period of the conti- nental system that the manufacture of sugar from the beet acquired 11 122 BEET ANJ> BEET-SUGAR. such perfection in France as made it profitable. The beet so geii' eraliy cultivated at the present time is derived, according to Thaer, from the Beta vulgaris. The two principal varieties of this root are the red beet, which has been grown for a very long time in kitchen gardens, and the white beet. Between these two extremes there are numerous varieties having a flesh color of various intensity, a yellow tint, &c. The seeds of the same plant in fact frequently produce varieties of decidedly diiferent shades of color ; the red and the white beet, however, appear to be the most constant ; and Thaer has said that the intermediate varieties are crosses between them. The field beet has a large root which grows in great part above the ground ; it is a very hardy plant, which has been cultivated for a very long time in various parts of the continent as food for cattle, and is now also very common in England. The root, which has hitherto been preferred for the manufacture of sugar, is conical, of a rose color without, and its concentric external layers are also color- ed ; but it appears that the white beet of Silesia is the more pro- ductive. The beet thrives in almost all kinds of soil, provided only they be sufficiently manured. In Alsace it succeeds in light, and in strong argillaceous soils indifferently. Another precious quality which this root possesses is that of succeeding in the most dissimilar cli- mates ; it is grown to purpose both in the north and in the south of France. The beet is sown at once in the field, or in a bed and transplanted ; the latter method appears now to obtain a decided preference, inasmuch as it leaves plenty of time for the preparation of the soil, and espe- cially for accumulating and carrying out manure. In a piece of ground well broken up by delving or ploughing, and highly manured, which need not be of greater extent than {-'jyth of the entire surface to be planted, the seed is sown in lines or drills as soon as the spring frosts are no longer to be apprehended. The transplanting in the east of France takes place about the middle of May, and even in the beginning of June. The plants are generally set about 15 inches apart. In the north the beet harvest does not begin before the end of September, and generally ends in the course of the month of October. The gathering is delayed as long as possible, inasmuch as the roots increase visibly to the very end of the season. But gathering the beet at a very late period in those countries where the winter seed has to follow this crop, is attended with more than one disadvantage. Without speaking of the difficul- ties that are incidental to wet seasons, a late seed-time is generally unfavorable for wheat. To meet this difficulty, I have been accuS' tomed for some time to take up my crop of beet at the period when it became necessary to prepare the land for winter seed, that is to say, more than a month before the general harvest of the root. In doing so I relied upon the interesting fact ascertained by M. Peligot in the course of his chemical inquiries, viz : that the composition of the beet is identical at every age. In this premature or anticipated beet harvest, a less weight of root is of course gathered than would have been obtained at a later period ; but the nutritious powers of BEET AND BEET-SUGAR. / 123 these beet roots are the same as they would ever have been. The grand questions to be determined were, whether the roots would keep or not, and whether the cattle would eat them from the pile as freely as from the field. All this was ascertained in the course of the winter : the beet kept perfectly, the cattle ate it as freely as ever. The procedure to be adopted therefore to secure a crop of beet of average weight, storing nevertheless some considerable time before the usual period, is simply to transplant somewhat more closely, and to put less space between the drills. If experience decides in favor of this method, the sole inconvenience which attends the cultivation of the beet in a freshly manured soil, and as the first crop in the rotation, that, namely, of causing a late and unfavorable seed-time for winter corn, will be completely got over. The beet which grows above the ground is best gathered with the hand ; kinds that grow under ground require to be loosened by run- ning a plough along the drill, &c. In Alsace it is the custom to take away the leaves, and to trim the roots upon the ground ; the refuse thus obtained constitutes a considerable mass of manure, which it is well to plough in immediately. To extract the sugar of the beet the plant is washed and rasped, and the pulp is then subjected to the action of a powerful press. Like the juice of the cane, the juice of the beet speedily undergoes a change ; it is therefore immediately heated to 70° cent, or 158°Fahr , and a little lime is mixed with it to neutralize acid and favor the clarifi- cation, by combining with albumen. The liquor is skimmed, and in the course of an hour becomes quite limpid, and of a pale yellow color. The liquor is then run upon a filter containing animal charcoal, and from that is transferred to a boiler where it is properly reduced, the process being in all respects the same as in the manufacture of cane sugar. '' In France, the produce of each 110 lbs. weight of beet is estimated at 4.5(5, or somewhat more than 4j lbs. of white sugar. The amount of loss in the manufacture may be conceived from the actual compo- sition of the beet, which, by the process followed by M. Peligot,* and which consists essentially in drying a certain weight of the root, cut into thin slices, and then exhausting the matter with boiling alcohol of moderate density, appears to contain from 4 or 5, up to 9, 10, 11, and even nearly 12 per cent, of sugar. This analysis of M. Peligot has been confirmed by the experiments of M. Braconnot,t who found the white beet of Silesia to have a very complex compo- sition, comprising as many as twenty-one different ingredients, among the number crystallizable sugar, albumen, woody matter, phos- phate of magnesia, phosphate of lime, oxalate of potash, and oxalate of lime, oxide of iron, an ammoniacal salt in small ({uantity, &c. On an average, the analysis of M. Peligot would lead us to conclude tnat the beet ^,ontained in one hundred parts — * Recherches sur I'analyse de la betterave a sucre. t Annales de Chimie, vol. Ixxii. p. 442, 2d. series. 124 BEET AND BEET- SUGAR. Water 87 Matter soluble in water (sugar) 8 Insoluble substances, (woody tissue) 5 "loo from which it appears that no more than about fths of the sugaf contained in the heet-root is extracted. As in crushing the cane, so in squeezing the rasped pulp of the beet, a part of the loss is owing to a certain quantity of sugar being left in the expressed pulp. In fact, with the presses generally in use, while from 60 to 70 per cent, of juice is obtained, the root actually contains 95 per cent. The loss here, however, is of less consequence than it is in the cane-, the trash of which is used for fuel, while the pulp of the beet serves as food for cattle. The pulp, indeed, is found to possess very nearly the same amount of nutritive power as the root which produced it. One of the considerations which is perhaps of highest importance in connection with the production of sugar from the beet, is inherent in lh(5 difficulty of preserving the root after it is full-grown. Gather- ed at the end of autumn the root suffers no less from severe frost, than it does from mild open weather : frost destroys its organiza- tion, and in mild winters vegetation continues at the expense of the sugary principle, which had been formed during the growth. If the beet actually contains at every period of its existence the same quantity of sugar with reference to its weight, there would probably be a great advantage in not waiting for the period of complete ma- turity, by sowing somewhat thicker than wont ; any difference of weight would probably be made up, and then there would be no risk of loss from keeping. The quantity of beet gathered from a given extent of land neces- sarily varies with the soil, the pains bestowed upon the crop, and the quantity of manure that has been used ; the following are a few particulars from official documents : PRODUCE PER ACRE. Ton. Cwt. Qra. Lba. PasdeCalais 12 9 1 19 Department of the North 12 10 2 25 Department of Cher 15 1 39 but in other departments the produce is considerably smaller, so that the average for the whole country has been estimated at not more that 10 tons 9 cwt. 1 qr. 13 lbs. per acre; an average which ap- proaches very closely to that which I have obtained from my own farm at Bechelbronn, calculated during a period of seven years. Assuming 4~7fths lbs. of sugar to be obtained from every 110 lbs. of beet, the produce in sugar from an English acre in the course of seven months will amount in the present state of things to 9 cwt. 2 qrs. and 7 lbs. By way of comparison I shall here remind the reader that an English acre of land laid out in Otaheite sugar-cane yields in the course of about fourteen months, 15 cwt. 1 qr. 10 lbs. I find from my accounts for 1841, that to manage an English acre of land under beet-root in Alsace, 45.6 days ojf a man, and 14.1 BEET AND BEET-STTGAR. 125 days of a horse was the amount of labor expended. In a document upon the sugar plantations of Guadaloupe which I have seen, it is stated that a domain of 150 hectares, or 370 acres, is worked by 150 negroes, which, reckoning the time that the crop is on the ground at fourteen months, would bring the number of days labor by a man,, to 171.8 per English acre. Such an expenditure of labor must in the nature of things absorb the greater part of the profits ; and, indeed, in a commission of inquiry into the laws connected with the sugar trade, it was shown in reference to the plantation in ques- tion, that the cost of cultivation and manufacture was equal to the value of the produce. Still the cane presents one considerable advantage over the beet, that, namely, of furnishing the fuel necessary to the boiling, an advantage which will be better under- stood, when it is known that in the manufacture of every 110 lbs. weight of beet sugar, the consumption of coal amounts to 22 lbs. In countries where sugar is cheap, it becomes an ordinary article of diet; in the public market-places of the great towns of South America, one of the rations commonly exposed for sale consists of brown sugar and cheese. M. Codazzi estimates the quantity of sugar consumed by each inhabitant of Venezuela at 110 lbs. In England it amounts to about 22 lbs. ; in Ireland, to no more than 4 lbs. and ^ths ; in Holland it is 15yV lbs. ; in France it is 8-^^ lbs. ; in Italy, 2^ lbs. ; and in Russia, but ly^j^ lb. per head. Maple sugar. (Acer saccharinum.) The maple is very common in the east of the United States of America. The tree is occa- sionally met with in clumps of several acres in extent, but it is more commonly found dispersed in the forest, growing among pines, poplars, ashes, &c. The tree grows particularly in rich soils, and attains the height of the oak ; the trunk being often more than three feet in diameter. The maple becomes covered with flowers in the spring before the appearance of the leaves. It is supposed to be in its prime at the age of about twenty years. The sap of the maple is obtained by piercing the trunk to the depth of from six to ten inches. A piece of wood to serve as a gutter is placed in the hole, and the sap is received in a vessel placed underneath. It is usual to pierce the tree first on the side that is towards the south ; when the flow of sap begins to lessen, it is tapped upon the north side. The best season for making maple sugar is the beginning of spring, February, March, and April ; the sap continues to flow during five or six weeks. The quantity of sap obtained is found to be largest when the days are hot and the nights cold ; the quantity collected in the course of twenty-four hours will vary from about half a pint to thirty pints and more ; the temperature of the air has the most marked influence upon the flow of the sap ; it ceases completely, for instance, in those nights when it freezes after a very hot day. The maple does not appear to s'iffer from reiterated perforation ; trees are mentioned which were still flourishing after having yielded sugar for forty-two consecutive years. In certain cases, which, however, must be held as exceptions to the rule, as many as 183 pints of sap have been tapped from a maple ia the course of twenty 126 PALM-SFGAR. four hours, which j^ielded 4j\ lbs. of crystallized sugar. A maple of ordinary dimensions, in a good year, will yield, on an average, about 198 pints of sap, producing 5^ lbs. of sugar. The sap of the maple must therefore contain about 2.2 per cent, of its weight of marketable sugar. It has been found, that with care and attention the maple becomes more productive ; maples around which other forest trees have been felled, or which have been transplanted into gardens, yield a sap which is not only more abundant, but also richer in sugar, which, in fact, contains about three per cent, of sugar. The manufacture of maple sugar presents no peculiarity ; pre cisely the same process is followed as in the case of the cane and beet. Unless very speedily boiled down, the sap ferments, and undergoes change ; in some parts of the United States, indeed, a vinous liquor is made of the sap, by allowing it to run into sponta- neous fermentation. PALM SUGAR. The palm which in the southern parts of India furnishes crystal- lized sugar in large quantity, is the cleophora of Gaertner, and reaches a height of about 100 feet. Its fruit hangs in clusters up- wards of a yard in length. The natives procure the sap by cutting short one of the shoots that is about to flower and carry fruit, and hanging under the cut part of a calabash or other vessel, into which the fluid distils ; in a large plantation such an apparatus is seen connected with each palm-tree ; the sap is removed every morning, and it is enough to reduce it by evaporation to obtain the sugar, which diflfers^ in no respect from the finest sugar of the cane ; in the unrefined state it is known over the whole of the East under the name of jaggery,* and is then a kind of moist and sticky muscovado sugar. The sap of the palm-tree obtained in the way above indica- ted, is often turned into a vinous liquor, which is much prized in many places. The pith of the tree yields sago. The palm-trees cultivated in India consequently yinld three most useful products — sugar, oil, and the farinaceous article of diet called sago. In rear- ing the cocoa-nut palm, those nuts are selected for seed which fall naturally, and they are dried in their husk. The ground which is to be sown is dug to a depth of eighteen or twenty inches, and it is left *o settle for three or four days. Some portion of the surface is then taken away, and the fresh soil is covered, to the depth of about six inches, with sand. The nuts are then placed upon the ground 80 prepared, and covered over with a little sand and a light stratum of vegetable mould ; they are then watered for three days consecu- tively. In the course of three months the young palms are fit to be transplanted, and they are set at the distance of about twenty feet every way from one another. For their reception in the permanent ♦ This is the generic name for sugar, and is obviously cither the Latin word sac- charum, or from the same root as the Lntin word. The cocoa-nut tree treated in llie tame way as the cleophora yields abundance of sugar, which is also known under the Baoie of j-dggery. — Eiio. Ed. GRAPE-SUG^R, OR GLUCOSE.. 127 plantation, holes are dn^ of about two feet in depth, in which a layer of sand, about six inches in depth, is put, upon which the young plants, still adherif)>T to the fruit, are placed ; the hole is then filled with sand, and the surface is covered with a little earth. The young trees require watering every day during about three years.' The palm begins to be productive at the age of seven or eight years, and it continues to yield fruit, or sap for the manufacture of sugar, during a very considerable period, without causing any further cost l')r cul- tivation.* The sap of the greater number of the palms appears to be rich in saccharine matter ; it is obvious, indeed, that every sap that is capable of supplying a vinous liquor by fermentation, may also furnish sugar ; and if the palms have not generally been grown with a view to this product, it is because the fruit must then be given up, and, both in India and South America, the produce in the shape of oil from the nuts of the palm, is almost always more valu- able than that which can be had in the shape of sugar.f GRAPE SUGAR. We have already said that starch acted upon by acids, and by malted barley, is changed into a saccharine fermentable substance, which, both in regard to flavor and physical properties, differs in many respects from the sugar which we have hitherto been engaged in studying. As this substance exists naturally in the grape, it has been called grape sugar, a name for which the generic term glucose has been lately substituted in France, this term being used to include all the sugars that are analogous to grape sugar. Grape sugar oc- curs in the form of small white and very soft crystals, grouped in tubercular masses; it softens at 60°, (140° Fahr.,) and becomes quite sirupy at 90°, (194° Fahr.) Alcohol free from water dissolves none of it ; but diluted alcohol takes up a considerable quantity. In the grape this sugar is associated w^ith cream of tartar, tartrate of lime, and several other saline matters. It is easily extracted from the fruit ; but the grape sugar of commerce is now universally prepared from starch ; large quantities, indeed, are manufactured on the continent for the preparation of spirit, and for the amelioration of wine, beer, cider, &c., in short, to supply sugar wherever it is defective in the natural or artificial musts that are subjected to fer- mentation. In England considerable quantities are also manufac- tured ; but here the law does not allow it to be used in the same ad- vantageous direction as in France and Germany ; all that is made is employed for mixing with adulterating cane sugar, which is an arti- cle of higher price. The sugar that is made from starch, and that is obtained from the grape are identical in composition, as is that also which is found in the urine of persons laboring under diabetes. * Buchanan. A Journey from Madras, &c., vol. i. p. 155. t In British India the cocoa-nut palm is beginning to be extensively cultivated as a means of producing sugar. A considerable portion of the East India sugar now brought to market, is manufactured from the palm-tree. It is not improbable, indeed, that the paLm of one spcies or another will one day supersede the sugar-cane and the beetoa tlw source of all Uxe sngar consumed in Eorope.— Eico. Ei>. 138 MAMNA. Grape Sitp&r Sugar ( f Starch. Diabetic Surar (Saussufe.) (Gutrin.) (Pelig-oi.J Carbon 36.7 36.1 36.4 Hydrogen 6.8 7.6 7.0 Ozygen .56.5 56.9 56.6 100.0 100.0 100.0 Like cane su^r, grape sugar in combining with certain bases ibandons a portion of its constitutional water. In the state in which it is combined with the oxide of lead it contains — Carbon 43.3 Hydrogen 6.3 Oxygen 50.4 iooio From these analyses it appears that crystallized grape sugar con- sists of — Anhydrous glucose 100 Water 19 On comparing the two kinds of sugar in the crystallized state, it becomes evident that glucose or grape sugar does not differ from cane sugar, except in containing a larger quantity of water. In fact the composition of grape sugar may be represented in this way : Carbon 42.2 i Hydrogen 6.2 > 100 of cane sugar. Oxygen 51.6) 115.8 of grape sugar. The cane, the beet, the palm, the maple, the vine, and starch, turned into glucose, are the sources from whence all the sugar of commerce is obtained at the present day, although attempts more or less successful have also been made to extract sugar from the pine- apple, from the chestnut, from the sweet orange, and from the stem of the maize or Indian corn. It appears that before the conquest the Mexicans prepared a sirup from the stem of the Indian corn, which was sold in the market-places. Pallas could not obtain more than about 3 per cent, of crystallized sugar from maize, but in "xn experiment which I made in South America along with M. RouL.i, the quantity of raw sugar obtained from this plant was 6 per cent. SACCHARINE PRINCIPLES NOT FERMENTABLE. Manna ; mannite. This saccharine principle is met with in dif- ferent plants ; it has been found in the expressed juice of onions, and in that of asparagus, in the alburnum of several species of pine- trees, and in different mushrooms. Manna, which is an exudation from the fraxinus omus and larch, contains nearly ^ths of its weight of mannite, and it is therefore from this substance that mannite is usually obtained, although it can also be had from the juice of the beet and the onion ; but then it is necessary to destroy the cane or grape sugar which they contain by pre^ jous vinous fermentation, PECTINE. lt?9 and M. Pelouze has even maintained that the mannite thus prepared is a product of fermentation.* Mainite crystallizes in very white semi-transparent needles ; it has a slightly sweet taste, and is soluble in water. According to Tiiebig and Opperman it contains : Carbon 39.6 Hydrogen 7.7 Oxygen ..52.7 100.0 Liquorice, This substance, which is obtained from the root of the Glycirrhiza glabra, is too well known to require particular con- sideration ; it is soluble both in water and in alcohol. GUM. Gum is a substance very extensively diffused in the vegetable kingdom ; there is, perhaps, no plant which does not contain some. Gum is divided into two kinds ; gum, properly so called, the type of which we have in gum-arabic, and vegetable mucilage, such as we meet in gum-tragacanth. Gum in dissolving in water produces a thick and adhesive fluid. It is insoluble in alcohol. Some plants contain such a quantity that upon infusion they seem to give, as it were, nothing else : such are the althea, the malva officinalis, &c. Gum does not crystallize, it is met with in concrete masses which result from the solidification of the drops which flow spontaneously from the trees that yield it : by long boiling with dilute sulphuric acid it is changed into glucose. Nitric acid alters it, and several new products are the result, among the number of which is mucic acid. Gum-arabic, according to the analysis of M. Gay-Lussac and Thenard, consists of : Carbon 42.3 Hydrogen 6-9 Oxygen - 50.8 100.0 To obtain vegetable mucilage, a quantity of linseed is treated with water and expressed. It is also obtained by steeping gum traga- canth in about 1000 parts of water and pouring oflf the solution which covers the mucilaginous mass. The mucilage then forms a jelly more or less consistent, which diluted with a large quantity of water forms a ropy viscid fluid. Dried again, this mucilage becomes hard and translucid ; in water it regains its former state. f VEGETABLE JELLY PECTINE AND PECTIC ACID. It is well known that the juice of all fruits contains a gelatinous substance to which many of them owe the property of forming jellies. * Annales dc Chimie, vol. xlvii. p. 419, 2d series.— The refuse wash of the distiller, appreciated by the taste, appears to contain a consideraMe quantity « f saccharine matter, which is probably mannite.— Eng. Ed. t Berzelius, Chemistry, vol. v. 130 PECTINE, PE.nC ACID. This matter may be obtained by means of alcohol. If into a quantity of currant juice lately'' expressed, a portion of alcohol be poured, a gelatinous precipitate is formed after a certain time ; this jelly, sub- jected to graduated pressure and washed with diluted alcohol, gives the gelatinous principle in a state of.tolerable purity : this is pectine, discovered by M. Braconnot. Pectine dried is in membranous semi-transparent pieces resem- bling isinglass. Thrown into about one hundred times its weight ot water it swells considerably and at length dissolves completely, giving rise to a stiff jelly. By increasing the quantity of water, a mucilaginous solution, having a slightly milky aspect, is obtained. Pure pectine is quite insipid ; it does not affect the color of litmus, the weaker acids have no effect upon it ; a slight excess of potash or of soda does not change it obviously, and nevertheless pectine is singularly modified under the influence of these alkalies, being chang- ed into a particular body, having acid reaction ; for on saturating the alkali employed, it immediately coagulates into a transparent gelatinous mass — pectic acid. As pectine acted upon by the fixed alkalies undergoes so remarkable a change, we may be allowed to conclude, w-ith M. Braconnot, that the pectic acid which is found ready formed in plants, has a similar origin ; a view moreover which tends to confirm that formerly announced by A^'auquelin, when he ascribed the development of the acids of vegetables to the presence of alkalies.* Gelatinous pectic acid immediately becomes defluent upon the addition of a few drops of solution of ammonia. By evaporating this solution in a porcelain dish we obtain an acid pectate of am- monia, which swells in distilled water, dissolves in it, and thickens a large quantity of the fluid. As ammonia has no reaction upon pectine, M. Braconnot has taken advantage of this negative property to determine if pectic acid exists or not, ready formed, in certain plants. Thus in treating carrots with cold water, rendered slightly ammoniacal, a liquid is obtained, from which an acid immediately throws down a precipitate of pectic acid.f Pectine and pectic acid, therefore, may exist together in vegetables, and M. Jacquelain has proved that the acid there is often in a state of combination as an alkaline or earthy pectate. Tt is to these pectates that M. Payen ascribes the origin of the carbonates of the same bases, which are met with in the ashes of plants, the organic acid having of course beon destroyed by the combustion. J M. Braconnot has described an easy process for obtaining pectic acid in large quantity from carrots.^ M. Fremy has published analyses of pectine and pectic acid, which present this remarkable peculiarity, that the cne has exactly the fiame elementary composition as the other. * Braconnot, Annals of Chemistry, vol. xlvii. p. 274, Si icries t Braconnot, op. cit. vol. xxx. p. 99. i Payen, Proceedings of the Academy of Sciences, vol. XV.p.90T i Op. cit. VOL XXX. p. 97. "^ I VEGETABLE ACIDS. 181 Pectine. reetl9«ci4. Carbon 42.9 42.8 Hydrogen 5.1 5.2 Oxygen 52.0 52.0 100.0 100.0 I have thought it right to speak at some length of these two prin- ciples, as they appear to play an important part ii the phenomena of vegetable life. A careful study of pectine and pectic acid will very probaMy aid in throwing light upon the metamorphoses which organic substances undergo in the act of vegetation. Pectic acid has been found in every plant in which it has been sought for ; M. Braconnot discovered it in the turnip, carrot, beet, peony, in all bulbs, in the stalks and leaves of herbaceous plants, in the wood and bark of all the trees examined, in all kinds of fruit, apples, pears, plums, cucumbers, &c, M. Braconnot is even very much inclined to think that pectic acid may constitute the essential principle in the cambium or organ- izable matter of Grew and Duhamel.* OP VEGETABLE ACIDS. w In the series of bodies which we have now considered, one only, sugar, possesses the property of crystallizing. All the others are amorphous, and their globular disposition and gelatinous qualities have led to the presuniption that they form in some sort the line of demarcation between things without and things endowed with life. It was also imagined that these amorphous matters, that these pro- ducts of the vegetable organization, almost organized themselves, would alone suffice for the nourishment of animals. This idea, however, is not well founded ; for if it be true that albumen, caseine, legumine, starch, and gum, are powerful elements of nutrition, it is equally so that sugar may perform an important part in this process, by acting in the same manner as starch, the oils, and other principles of ternary composition, in becoming like them a useful, often an in- dispensable auxiliary of azotized alimentary matters. This disposition to consider the amorphous state of the more im- portant immediate principles of vegetables as a special and distinctive character, cannot be maintained beside the recent observations of Mitscherlich. This illustrious chemist has found, that if the mineral precipitates which are deposited in liquids, are in many cases form- ed of crystals more or less regular, they are also sometimes compos- ed of small spheres or aggregated masses, the particles of which do not unite in a regular way as crystals, but remain separated by a thin layer of fluid. Examined under the microscope these masses present themselves under the form of flocks and of shreds, having a granular or gelatinous appearance, and which xcmain soft and flexi- ble like fresh vegetable or animal substances, so long as they are kept under water ; it is only in drying that they become pulverulent or acquire the vitreous aspect. f * Braconnot, op. cit. vol. xxviii. p. 171. 1 Berzelius, Ann. Report, ISil, p. 20. 132 VEGETABLE ACIDS. The substances, the chemical constitution of which we have still te examine, may in general be obtained in the crystallized state ; their individuality seems more decided ; they are more stable, better characterized, and their specific properties often assimilate them to inorganic bodies. Such, for example, are the acids formed in the course of vegetable existence. Vegetable acids present all the general characters of mineral acids, while they participate in the properties inherent in organic substances. Thus they form salts by uniting with bases ; with potash, soda, ammonia, they form salts soluble in water ; the other bases produce compounds that are soluble or insoluble, according to the nature of the acid. These acids, free or uncombined, are very frequently met with in fruit, sometimes in the leaves, more rarely in the seeds and roots ; but in combination with bases they are met with in almost all parts of plants. Already very numerous, they are increasing rapidly with the progress of discovery ; with the excep- tion of a very few employed in the arts, their study forms a subject of no great interest. I shall therefore confine myself to a few of the most extensively distributed of these acids. Oxalic acid. This acid exists free in the hairs of the cicer or chick-pea, and united with potash constituting an acid salt, the bin- oxolate of potash in the wood sorrel and the common or garden sor- rel. It is from the former of these plants that the salt called salt of lemons, but which is, in fact, the binoxolate of potash, is still ex- tracted in some countries. The juiceof the wood sorrel is expressed and yields about 0.003 of its weight of the salt, from which, by or- dinary chemical manipulation, the oxalic acid is readily obtained. At the present time this acid is prepared artificially by the action of nitric acid upon starch ; it is a powerful acid, and its affinity for lime is such that it takes this base even from its union with sulphuric acid. Tartaric acid is met with above all in the grape in the state of bitartrate of potash, a salt which is deposited upon the sides of the casks in which the wine is kept. After having been properly puri- fied, it is known in commerce under the name of cream of tartar, from which the tartaric acid can readily be obtained. Another par- ticular acid, the racemic acid, the composition of which is identical with that of the tartaric acid, has been discovered in the tartar of the wines grown on the Upper Rhine. Citric acid. This acid is found in the juice of many plants, and abundantly in the juice of lemons, oranges, currants, &c. It is from the lemon and the lime that the citric acid employed in the arts 19 generally obtained. Tannic acid. A certain substance which is met with in the bark of particular trees, and which has the valuable property of renderings the hides of animals with which it is combined insusceptible of pu- trefaction, is familiarly known under the name of tannin. The art of the tanner is founded upon this property of tannin. A solution cf gelatine being poured into an infusion of tannic acid, an insoluble precipitate, torm.ed by the uiiiun ot the acid with the animal matter, VEGETABLE ALKALIES. 133 IS immediately produced. By macerating a piece of raw hide in a solution of tannin, the same combination takes place even into the very interior of the tissue ; the whole of the tannin quits the solu- tion by degrees to combine with the gelatine of the skin. It is not in the bark only that tannin is encountered, it has been found in different organs of plants. Sir Humphrey Davy has stated these quantities of tannin as constituents of 100 parts of the follow^ ing substances : Nutgalls . 27.4 Oak bark , , 6.3 Chestnut bark . 4.3 Elm bark . 2.7 Willow bark . 2.2 Inner white bark of an aged oak 15.0 The same of young oaks" 16.0 The same of the Indian chestnut 15.2 The inner colored bark of the oak 4.0 Sicilian sumac 16.2 Malaga sumac 10.4 Souchong tea 10.0 Green tea 8.5 Bombay catechu 54.3 Bengal catechu 48.1 Gallic acid. This acid is found united with tannin in the greater number of barks, or along with the astringent principles of plants. Gallic acid appears to be the product of a kind of fermentation un- dergone by tannin, as the process by which it is prepared seems to indicate, and which consists essentially in exposing for about a month a quantity of nutgalls reduced to powder and kept constantly moistened. The solution of gallic acid does not precipitate gela- tine. I have added in a table the composition of the principal vegetable acids. I shall speak of the composition of fat acids when I come to treat of fatty substances. The different vegetable acids do not vary essentially in composi- tion, save in a single instance. With one exception they consist of definite proportions of carbon, hydrogen, and oxygen. The excep- tion alluded to is the hydrocyanic acid, which contains no oxygen, but a large quantity, nearly 52 per cent., of azote. OF THE VEGETABLE ALKALIES. The alkaline bases which are formed in the course of vegetation, always contain a certain proportion of azote. Their general prop- erties are those of alkalies ; their watery or alcoholic solutions re- store the blue color of the reddenea tincture of turnsole, and they constitute salts by combining with acids. In their manner of be- having they bear a certain analogy to ammonia. Like ammonia, the organic alkalies combine with the hydrates of the oxacids, and when they are deprived of their water of crystallization, they fix the hydracids without losing weight. 12 134 FATTY SUBSTANCES. The discovery of the vegetable bases is due to Sertuerner, wh(.», in 1804, indicated the existence of morphine in opium. The ma- jority of the vegetable alkalies are insoluble, or little soluble in water ; all are soluble in alcohol ; some of them are sutRciently volatile to be susceptible of distillation. In elementary composition they are all very much alike, consist- ing of various, but, in each instance, definite proportions of carbon, hydrogen, oxygen, and azote, the carbon varying from about 50 to 75, the hydrogen from 6 to 12, the oxygen from 8 or 9 to 27 and even 37, and the azote from 1.6 to 12, 28, and even 35 per cent. OF FATTY SUBSTANCES. Under this title I comprise all the oily substances, liquid or solid, and those that are analogous to wax, which are found disseminated in different organs of plants. A character common to almost all fatty substances, is insolubility in water. They dissolve in sensible quantity in alcohol, and especially in ether. Fatty substances may be divided into two classes : one including those which are easily modified by the action of alkalies, and which form soaps ; the other not susceptible of this action, not susceptible of saponification, or, at all events, that are only attacked by alkalies in very particular cir- cumstances. When a mixture of fat oil and a solution of caustic alkali are heated, the oil is soon observed to incorporate with the alkaline liquid. After boiling for some time, if the alkali is in excess, clots or flocks appear, and in removing the excess of liquid a white mass is obtained which is soluble in water — the oil is saponified ; and the product of the saponification is combined with a portion of the alkali which has been employed. If into a hot solution of this soap a quantity of hydrochloric acid be poured, the acid seizes upon the pot- ash or the soda, setting at liberty the fatty body which had been combined with the alkali, and which collects on the liquid. It is easy to discover that the fatty matter thus collected is no longer the same as that which had been originally employed ; for example, it is completely soluble in boiling alcohol, which, on cooling, deposites brilliant pearly crystals of a fatty substance possessing acid proper- ties. By evaporating the alcohol from which these crystals are formed, an additiona quantity is obtained, and, when the alcohol is entirely dissipated, another unctuous body is obtained, having also acid properties. Three acids having distinguishing characters are, in fact, obtained by the action of alkalies upon fatty substances : the stearic, margaric, and oleic acids. The alkalies consequently trans- form neutral oily bodies into acid substances, as first shown by the admirable researches of M. Chevreul, before whose time it was al- ways assumed that soap was the result f f a direct union of fatty matters with alkalies. The fatty acids arc not the only products of saponification, there are several others, particularly glycerine, which, however, need not occupy us particularly here. The experiments of M. Chevreul would lead us to view all fatty FATTY SUBSTANCES. 185 matters as combinations of glycerine playing the part of a uase with particular acids ; these combinations, analogous to salts if their con- stitution be merely considered, are generally mixed together us oils and fats ; thus the union of stearic acid and glycerine forms stearine, which is fusible at the temperature of about 62° cent, (144° Fahr.) Stearic acid melts at 72° cent., (162° Fahr.,) oleine remains fluid at 4° cent., (24° Fahr.,) and oleic acid is liquid. An oil is, therefore, by so much the more consistent as a larger quantity of solid fatty acid enters into its composition, and it is, on the contrary, by so much the softer and more liquid as this acid is itself more fluid. The wax of the Myrica cerifera, for example, is sufficiently hard to be reduced to powder, and is almost entirely formed of stearine. In the fluid vegetable oils oleine always predominates. It is easy to separate these different fatty compounds from one another. Besides the solid and litjuid acids which are obtained from fatty substances, there are others known which are volatile. Fatty bodies absorb oxygen from the air. This absorption is at first extremely slow, scarcely appreciable ; but once begun, it goes on with great rapidity ; so rapidly, indeed, that if a large surface be exposed to the air, if, for example, a quantity of rags or tow be im- pregnated with oil, the mass may take fire. The consequence of this oxidation is always a thickening of oil, and there are some which become completely solid in its course ; these are designated by the title of drying oils, and are in particular request for the manufacture of varnishes. Nut oil which has remained long exposed to the air acquires the consistence of jelly, and its unctuous properties have sc entirely disappeared that it no longer stains paper. The alteration which fatty substances undergo in contact with air and moisture is still more remarkable. The oils which are inodorous and without taste soon acquire under these circumstances a strong smell and a disagreeable flavor. Fleshy fruits which contain a large quantity of oil, such as the olive and the oleaginous seeds, when moistened suffer true fermentation, the result of which is the sepa- ration of the fatty acids from the glycerine. Oils subjected to the action of a high temperature are alsb greatly modified. The glycerine which they contain is decomposed, and gives rise to various pyrogenous products : stearic acid is changed into margaric acid, and oleic acid into sebacic acid, a crystallizable volatile acid which is soluble in hot water. The fatty substances of plants are principally accumulated in the fruit, and particularly in the seed. In the herbaceous parts they are less abundant, less perfectly elaborated. Oils appear to be included in the vegetable tissue under the form of globules, or minute drops. In such an oily seed as the common almond, when it is growing, we perceive that the cellular tissue is in the first instance full of a col- orless and transparent fluid ; but as the seed advances, each cell is seen to become filled with numbers of little oil globules which in- crease continually in size and number until the kernel is ripe ; there is at the same time a quantity of azotized matter deposited in the midst of the liquid, which disturbs its transparency ; it is this depos- 136 FATTY SUBSTANCES. ite which thickens the walls of the cells.* The capillary force which retains fatty principles combined with the tissue of certain seeds must be very considerable, for havings boiled some rape-seed, wiiich contained 50 per cent, of oil, in water, there was not a trace of oily matter perceptible upon the surface of the liquid. Butter appears to be kept diffused in milk by something of a similar force, for milk when boiled yields but a very small quantity of this sub- stance M. Dumas and I maintain that the oil of seeds is intended for the production of heat by undergoing combustion at the period of germination ; a series of experiments performed in my laboratory by M. Letellier supports this opinion. Having ascertained by a preliminary trial the quantity of oily substance contained in a certain weight of seed, some of the same kind was put to germinate, and the quantity of oil which it contained was tested at two periods of the germination ; it was found that in the course of this process a considerable proportion of the fatty sub- stance had disappeared ; one gramme or 15.438 grains of rape-seed before germination contained 0.50 of oil ; after the first period of germination, namely, when the cotyledons had begun to turn green, the quantity of oil was found reduced to 0.43, and at the end of the second period, when the cotyledons had become quite green and the radicles were from 3.9 to 4.6 inches long, the oil was reduced to 0.28. It would be extremely interesting to ascertain the extreme loss which the oily principles of seeds sustained in the course of the commencement of vegetation, and to follow the return of the same principles in proportion as the plant advanced towards maturity. M. Letellier is going on with these experiments. The numberless uses to which oil is put, make its manufacture an object of the highest importance. Vegetable oils are generally ob- tained from olives, from oleaginous seeds, and from the nut of cer- tain palms. Oil is separated by pressure ; it may often be extracted from the seed in the natural state, in which case the produce is of fine quality, but seldom abundant. The castor-oil bean, for example, yields its oil under the simple action of the press. In America, however, to obtain this oil, the seeds are first roasted slightly, and being bruised they are then boiled in water ; the oil readily sepa- rates from the roasted seed. A similar process is sometimes follow- ed in procuring cacao butter. In the extraction of oil from the common oleaginous seeds, they are first ground or bruised in a proper apparatus ; the paste or pow- der which they now form is generally heated, and being put into woollen sacks, and these enclosed in hair bags, they are subjected to the operation of the press ; after one pressure, the magma which remains in the bags is crushed anew, heated, and pressed again. The oil obtained by the second pressing is never so pure as that procured by the first. The oil-cake is taken out of the bags, completely dry in appear- BOe» but it still contains a large proportion of oil — iron 8 to 15 per * Domas, Chemistrj', vol. v. OIL. 137 cent, of its weight. It is used in fattening cattle and as manure Oil, when newly expressed, is always turbid and very mucilaginous; it becomes clear by standing ; but it always retains certain 8ub« stances which lessen its quality, particularly when it is intended for burning in lamps. Greater obstacles are encountered in extracting the &i\ from some of the pulpy fruits than from seeds. In extracting olive-oil, the olives are crushed under millstones ; and the paste which results be- ing put into flat baskets of wicker-work, is subjected to the press. The first pressing yields virgin oil, which is used for the table. Having removed the baskets from the press, their contents are mix- ed with a little boiling water, replaced, and pressed again, by which a new quantity of oil is obtained. But the pulp is not yet exhausted , by special treatment it still yields a quantity of oil of inferior quality, which is employed in the manufacture of soap. The fruit of the palm yields the oil which it contains with great readiness. I have extracted a butter of excellent quality and very agreeable taste by simply boiling the nuts or. berries of the Palma real in water. The cocoa-nut yields two qualities of oil, according to the mode of extraction. To prepare the best kind, the fleshy part of the fruit is grated, and the pulp being pressed, a milky fluid is obtained, which yields the oil by boiling. An inferior quality of oil is obtained by causing the cocoa-nuts to putrefy ; when the putre- faction has advanced to a certain stage, the oily pulp is thrown into copper vessels and exposed to the sun, and the oil which then rises to the surface is skimmed off. This oil is brown, and has a strong smell ; it contains fatty acids which have probably been set at lib- erty by the putrid fermentation. The value of the produce in oleaginous seeds of a given extent of land, and the quantity of oil which these seeds will yield, depend, as may readily he conceived, on a variety of causes which it is not al- ways easy to appreciate with precision ; such as climate, the nature of the soil, the system of husbandry followed, &c. The observations of M. Gaujac of Dagny on the various plants usually cultivated for the sake of their oleaginous seeds, will however suffice to give a notion of their comparative productiveness in oil and cake : Crop. Seed produced per acre in Cwts. qrs, lbs. Whole quantity of Oil obtained per Acre in lbs. avoird. Oil obtained per cent. Cake per cent. WINTER CROPS. Colewort 19 0 15 15 1 3 16 2 18 15 1 25 16 2 18 13 3 19 17 1 16 15 3 14 15 1 25 10 1 18 7 3 21 11 3 17 875.4 320.8 641.6 595.8 641.6 565.4 545.8 275.0 385.0 560.8 229.0 412.5 40 18 33 33 33 33 27 15 22 46 25 54 73 62 62 62 61 72 80 69 52 70 Rape Swedish turnip.. Curled colewort. . Turnip cabbage.. SPRING CROPS. Gold of Pleasure Sunflower Flax . . • White poppy Summer rape — 30 1 65 13* 138 OIL. M. Matthew de Dombasle made some comparsiive experiments a. Roville on the cultivation of oleaginous plants. The results obtain- ed by this skilful agriculturist are much less favorable than those of M. Gaujac. Instead of 19 cwt. and 15 lbs. of colewort seed yield- ing 875.4 lbs. of oi; per acre, M. de Dombasle only obtained 11 cwt. 2 qrs. 21 \h§. yielding 392.3 lbs. of oil ; and the other kinds of seed in proportion. But as I have said already, the fertility of the soil, and the labor and pains bestowed upon it, may have contributed to the differences observed, because here the influence of climate may be overlooked. There is one circumstance, however, which may explain the great differences in the quantity of oil obtained, which is the perfection of the press employed to extract it. In a general way oil-presses are so imperfect that they all leave a quantity of oil more or less in the cake. Here are two examples : from 2765 lbs. avoird. of fine colewort seed, gathered in 1842, and weighing 52^ lbs. per bushel, I obtained : lb«. Of oil 1130.5 Of cake 1384.9 Loss 249.6 2765.0 In Other terms, per cent. : Oil 40.81 Cake 50.12 Loss 9.07 iooioo but by a careful analysis of the same seed in the laboratory, 50 per Dent, of oil was obtained. 2d. In 1840 and 1841, I made some experiments on the cultiva- tion of the madia sativa, intermixed with carrots in a fertile soil, well manured with farm dung. The crop of the year 1840 was ex- cellent ; it required one hundred and twenty-seven days to come to maturity. ibi. Seed, husks deducted 2424 Dried leaves employed as litter 7700 Carrots without their leaves 31966 The seed gave : Of oil 635.8 Of cake 17067.6 100 of seed gave : Oil 26.24 Cake 70.72 Loss 33.4 100.00 These results agree pretty nearly with those which have been published by ether agriculturis s ; but the seed of this madia, which in the press gave 26.24 of oil per cent., actually yielded 41 per cent, by analysis in the laboratory ; this difference between practical re- suits and those of the laboratory, shows us how large a quantity of oil is generally left in the ;ake. When the cake is used for feeding OIL. 139 cattle, the loss is perhaps less to be regretted, inasmuch as the oily matter evidently assists in the fattening ; but when the cake is used as manure, \he oil which it contains is almost entirely lost. It is often ot importance to the agriculturist to ascertain precisely the quantity of fatty principles contained in oleaginous seeds. For this purpose, it is enough to bruise a given quantity of the seed and to digest it in successive portions of sulphuric ether. After a first digestion, the seed is bruised or pul-verized anew, and the bruising is now accomplished without difficulty. The process may be con- cluded by boiling with a mixture of equal parts of ether and alcohol. The ethereal solutions are decanted from the seed into a porcelain dish, the weight of which is known. The ether evaporates sponta- neously and the oil remains, the weight of which is then taken. The following sums may be taken as a pretty accurate estimate of the average quantity of oil yielded by the different oleaginous seeds : colewort, winter rape, and other species of cruciferous plants, from 30 to 36 and 40 per cent. ; sunflower about 15 per cent. ; lin- seed from 11 to 22 ; poppy from 34 to 63; hempseed from 14 to 26 ; olives from 9 to 11 ; walnuts 40 to 70 ; brazil nuts 60 ; castor- oil beans 62 ; sweet almonds 40 to 54 ; bitter almonds 28 to 46 ; madia sativa 26 to 28 per cent. The quantity of oil yielded by any seed subjected to the press is always considerably less than that which it contains, and the oil re- tained in the cake appears to be in larger proportion as the starch, the woody tissue, and the albuminous matters are more abundant. Thus maize, or Indian corn, which contains from 8 to 10 per cent of fluid oil, gives mere traces of its presence under the press. The oily and fleshy fruits, such as those of the olive and the palm, yield a considerable quantity of oil. In the southern countries of Europe, particularly those which are so well protected that their olive-trees escaped the severe winter of 1789, as many as about 816 J lbs. of oil per acre are obtained, with proper care. The trees which were killed during this memorable winter sprouted again from the roots, and at the present day yield from about one quarter to one half the above quantity, according to the spaces left between them, which vary considerably. Under similar circumstances in regard to climate, it will readily be understood, that the quantity of produce will be influenced by the quantity of manure put into the ground. In some countries the olive is never manured, save indi- rectly ; that is to say, the ground between the trees is only manured with a view to another crop, which is grown between them ; in other countries, again, in the neighborhood of Marseilles, for instance, it is the practice to manure the olive plantations, directly, every three or fonr years. The olive enjoys remarkable longevity ; I have mentioned one more than seven centuries old, and the term of the tree's existence appears only to be limited by the severe winters which cause it to die, from time to time. The produce must of course depend upon the age of the trees which compose a plantation. Up to eleven years, M. Gasparin shows that an olive-tree still remains all but un- 140 OIL. prodQctive ; and that the capital, and the interest upon the capital expended in this husbandry, must necessarily exceed the value of the produce up to the thirtieth year. Yet there are soils which are favorable to the olive, and which are useful for nothing else ; a hole in a rock suffices it, if the climate be favorable and it receive a praper dose of manure. But the grand cause of the disadvantages attending the cultivation of the olive, in France, is connected with the periodical occurrence of severe winters, which kill it ; in an interval of one hundred and twelve years, from 1709 to 1821, the olive plantations have suffered three great mortalities, which give a mean duration of about forty years to each planting. The cocoa-nut-tree is one of those which yields the largest quan- tity of oil with the least labor. The tree grows vigorously in all hot countries, at no great distance from the sea-shore ; wherever the tem- perature is from 78° to 82° Fahr., there the cocoa-nut thrives. It is also found on the banks of great rivers ; and the common practice in planting the cocoa-nut is to put a little salt in the hole. When trans- planted far from the banks of rivers, it thrives best in the neighborhood of human habitations, which has led the Indians to say that the cocoa-nut-tree loves to hear men talking under its shade. It is a tree which requires a soil impregnated with saline substances, and these are never wanting near the habitations of man. The tree bears its first flowers at the age.of four years ; it produces fruit the following year, and continues to fructify until it is eighty years old. The spikes generally bear about twelve cocoa-nuts, and the number of nuts yielded by a tree in the course of a year may be taken at about fifty, which will yield about four litres, or rather more than seven pints of oil. Somewhere about ninety trees are generally found upon the acre of land, and these are capable of yielding about 825 lbs. of oil annually* The cocoa-nut-tree must, therefore, be regarded as among the most productive in oil, and also as the plant which requires the least outlay in its cultivation. Many species of palm yield oils of a very agreeable flavor for the table, and the produce of all answers admira- bly for the manufacture of soap. In the same proportion as agri- cultural industry extends in the equatorial regions of the globe, will the production of palm-oils increase, and this must necessarily in- fluence the cultivation of the olive in a very serious way. The cul- tivation of the tree being already threatened in Europe by that of the mulberry, and the prodigious extension in the trade in palm-oil upon the coasts of Africa in the course of the last few years, justify this conclusion. In 1817, palm-oil was considered as among the list of mere medicinal substances. At this period a London perfumer thought of making it into a soap for the toilet-table. From this time it became the staple of a bartering trade, which has been by so much the more profitable to the nations engaged in it, as the purchase is always effected by manufactured articles, such as cotton and wool len goods, hardware and crockery, arms, powder, &c. The future * Codazzi. Remmen de la Geografia de la Venezuela, p. 133. ESSENTIAL OILS. 141 extent of this traffic may be imagined when it is known that in 1817 the importation of palm-oil into England did not much exceed 140,000 lbs., and that in 1836 it exceeded 70,000,000 lbs ! In tak- ing an acre of surface for unity, I find that on an average the Spring oleaginous plants yield 3201bs. of oil. Winter oleaginous plants 534 " The olive (south of Europe) 534 " The Palm (America) 801 " OF ESSENTIAL OILS. Aromatic plants owe the odors which characterize them to certain volatile principles, which by reason of certain properties which they have in common with fat oils, such as insolubility in water, solubility in ether and alcohol, inflammability, &c., are gen- erally designated as essential oils. They are met with in all parts of plants ; but in one plant the oil is principally found in the flower, in another in the leaves, in another in the bark,, -tCOOl-'<*0S05r^iCC^-Hcy:oo i 1 i-^(?»^oooi«ooooomooiooinio»npoir5o>o 00 05 e»5 oc3 to r^ CO co'iryirj ^t od co* os ^* p4 o6 to irj ^ -COQ0J>'Q0000000t^t»t-00Q0t^l^t>'a000CX)t'l^ 05QOCioojooooooiftOim«oiflt«»nppirtpif5 r^c>co"c^'«odcoTtir5irjco'rH-rj5oodoi.-HrtTfaiQdaJioo I .S small, thin. middling. very large. horny, long. small, brown. middling. reddish. yellow, fine. small, hard. hard. reddish. large. soft. pretty hard. soft. white, hard. ditto. small. gray, hard. yellow, large. wrinkled. small, red. hard, very large. well-formed. t 1 Triticum spelta rufa mutica Small spelter, T. monococon Great spelter Mecca wheat Bearded wheat Winter wheat, T. hybernum . Common wheat (mouret) . Reyel wheat .... Red Egyptian wheat .... A large wheat growing in 4 ranks Fine red wheat of Roussillon . Red Marcel wheat Dantzic wheat Wheat from the North . . . Fine red wheat (pays de Foix) Smyrna wheat Bengal wheat Tangarok wheat Hard African wheat .... Cape wheat Russian wheat Sicilian wheat Giant St. Helena wheat . . . Subernac wheat (Pyrenees) . . 176 WHEAT. The quantity of gluten ind albumen contained in these samples of flour is much larger than that usually indicated ; I have given rea- sons which explain, to a certain extent, this difference. I ought to add, however, that the varieties of wheat, the flour of which was analyzed, were all grown in the rich soil of the garden, a circum- stance which, as Hermbstadt has shown, exerts the most powerfu. influence in increasing the quantity of gluten in wheat. It was already known, from the experiments of Tessier, that the proportion of gluten in the same species of wheat might vary in the ratio of from 12 to 36 per cent, of the weight of the flour, according to the nature of the soil and the quantity of manure. But it was Hermbstadt who first made truly comparative observations on the action of the excrements of diflferent animals on the culture of the cereals. The excrements made use of by this able cultivator in his inquiries w^ere always dried in the air at a temperature of 12|° C. (54^° F.,) and equal areas of the same soil were sown with equal weights of winter wheat, and had a similar dose of manure of one kind or an- other spread over them. One hundred parts of the flour obtained from wheat thus grown yielded : Bran, soluble mai- - Gluten. Starch, ter and moiiture. With human urine 35.1 39.3 25.6 " bullock's blood 34-2 41-3 25.5 " human excrement 33.1 41.4 25.5 " sheep's dung 22-9 42.8 34-3 " goat's ditto 32.9 42.4 24.7 " horse ditto 13.7 61-6 24-7 " pigeon's ditto 12.2 63-2 24-6 " cow's ditto 12.0 62.3 25.7 Soil not manured 9-2 66.7 24-1 It is apparent, therefore, that in general, for the exception onl refers to the pigeon's and the horse dung, the wheat grown in groun manured with the most highly azotized matters yields the target quantity of gluten. By way of adding to and confirming these conclusions of Hermb stadt, I shall give the results of an experiment of my own, made i< 1836, in which the same variety of wheat was grown in the opev field, and in garden ground very highly manured. The grain wjm analyzed after having been dried at 110° C, (230" F.,) and gave : From the open field. From the garilen gnuad. Carbon 46-10 45.51 Hydrogen 5.80 5.67 Oxygen 43.40 43.00 Azote 2.29 3.51 Ashes 2.41 2.31 100.00 100.00 In the produce of the garden there were 21.94 — very nearly 22 per cent, of gluten and albumen ; in that of the open field no more than 14.31 per cent, of the same principles. Davy was of opinion that the wheat of warm climates was richer in azoti'/ed principles than that of temperate lands. Southern coun- tries are known to produce harder, tougher grain, the flour of whicb RYE. 171 contains more gluten than the soft and more friable wheat of the north ; and the inquiries of M. Payen appear to bear out the conclu- sion of the illustrious English chemist. M. Payen, in fact, found in the hard wheat of Africa 3.00 of azote, equivalent to 18.7 ; and in that of Venezuela 3.50 of azote, equivalent to 21.9 of gluten and albumen. The experiments quoted above, however, prove that we may have wheat grown in Europe fully as rich in azotized elements as any that is grown between the tropics ; the influence of the soil in this direction is probably more than the influence of climate. In all the analyses of wheaten and other flour published up to the present time, we find no mention made of the fatty matters which they contain ; and late views in regard to the special part which ihese matters play in nutrition make it very necessary to supply the omission. A ong with MM. Dumas and Payen, I therefore deter- mined the quantity of fatty matter contained in a considerable num- ber of the vegetables and vegetable substances used as food, from which it appears that grain of diflferent kinds contains from 2 to 10 per cent, of oil. One hundred parts of winter wheat gathered at Bechelbronn lost 14.5 of water by drying at 110' C, (230° F.,) and therefore contained 85.5 of dry matter. 100 of this dry wheat gave 13.7 of bran and 86.3 of flour. Various analyses showed the composition of this wheat and its parts to be as follows : Dry matter. Gluten and Starch. Albumen. Bran 20.0 Flour 13.4 73.2 5.6 4.2 2.1 1.5 Wheat 14.3 63.2 Rye, {Secale cereale.) Rye is an important article ot food, par- ticularly in the north of Europe, where the people live upon it almost entirely. It is a very hardy plant, and will thrive in soils which are altogether unfit to grow wheat. In the husbandry of the north this grain occupies the place of wheat in the south : it requires much the same treatment, and stands upon the ground for nearly the same length of time. The bushel of rye weighs on an average about 60 lbs. avoird. The usual quantity of seed sown is from 10 to 11 pecks per acre, and the produce per acre, the seed being deducted, has been stated as follows : Bushels. Brabant 23.0 Flanders 32.4 Austria 206 England 22.0 France 19.0 The German agriculturists say, that the weight of the straw to the weight of the rye produced is in general as 100 is to 47 ; others say as 100 is to 50, and some have taken it even as high as 100 to 33. The relation seems to differ extremely in different years. At Bechelbronn, for example, in 1840-41 we had 63 of grain to 100 of straw; in 1841-42 we had but 25 of grain to 100 of straw. Rye yields flour that is not so white nor so fine as that of wheat, Glucose. (Su^ar.) Gum. Fatty matter. Woody tissue. 5.6 28.8 4.2 12.i 55 2.1 1.6 45.7 7.5 178 BARLEY OATS. which is in consequence of the woody covering of the ofraih getting ground, in great part, in the mill. If but from 50 to 65 purts per cent, of flour be taken from rye, it is white and looks well. The dough made with rye flour is not very adhesive ; it contains little vegetable fibrine, the azotized principle which gives gluten its elas- tic properties. It is this want of vegetable fibrine which renders it more difficult to make good light bread of rye than of wheaten flour, although experiment shows that rye flour of the first quality will form as large a proportion of bread as wheaten flour ; 100 of rye flour have given 145 of bread. Rye bread is more hygrometric than that of wheat, and conse- quently remains for a longer time soft and fresh. Rye generally contains 24 of bran to 76 of flour ; by drj^ng at 230 F. it loses about 17 per cent, of water. Analyses of a dried sample grown at Bechel- bronn yielded : Gluten and albumen (azotized principles united) 10.5 Starch 64.0 Fatty matters 3.5 Sugar (glucose 7) 3.0 Gum ]1.0 Woody matter and salts (phosphates) 6.0 Loss 2.0 looTo Barley, {Hordeum vulgare.) The usual produce of barley varies much from 15 or 20 to 50, 60, and even 70 bushels per acre ; the average for France is stated at about 43| bushels ; and the weight of the bushel may be taken on an average at about 504 lbs. The ratio of the straw to the grain varies very much, but may be taken generally at that of 100 to 50. Barley contains : Of flour 68.6 Bran 18.4 Water .13.0 100.0 Dried, this grain gave 0.0214 of azote, which represents 13.4 per cent, of gluten and other azotized principles. Oats, {Avena sativa.) When oats yield 43 or 44 bushels per acre, the crop is a fair one. At Bechelbronn we have frequently had up- wards of 45 bushels per acre.* Schwertz states the relation between the straw and the grain as 100 is to 60. Some oats gathered in 1841-42 yielded 78 of meal and 22 of husk per cent. One hundred parts of these oats lost by drying at 230° F. , 20.8 of water ; thus dried, analysis showed that they contained : Of starch 46.1 " gluten, albumen, to 13.7 " fatty matter 6.7 " sugar (glucose) 6.0 " gum 3.8 " woody matter, ashes, and loss « 21.7 100.0 ♦ This would be reckoned a poor croo in the North of England and Scotland, whrf» 10^ tW, and even 100 bushels of oate pet \cn are frequently grown*— Eko. Ed MAIZE. 17& Maize, {Zea mais.) This is the true wheat of the Americans, and it is now generally avowed that the plant is a native of the New World. It is also well known that maize was introduced into Spain long before potatoes. Oviedo states in his work, printed in 1525, that he had seen it growing in Andalusia and the neighbor- hood of Madrid. The cultivation of this useful plant was observed everywhere on the discovery of America by Europeans, from the most southern parts of Chili to Pennsylvania in the north ; and in the neighborhood of the equator, from the level of the sea to the high table-lands of the Andes. Garcilasso gives a particular de- scription of the procedure followed by the Incas in the cultivation of this plant, the kind of manure, &c. At Cusco the Indians ma- nured with human excrement dried and reduced to powder. On the coasts they employed in one place guano ; in others, as the dusty and sterile soils of Attica, Atiquiba, &c., they made use of the ofFal of fish. The uses of maize are very numerous. In America it is made into cakes, which are a substitute for bread ; by fermentation a vinous liquor is prepared from it called chicha. Before the conquest, the Mexicans manufactured a sirup from the expressed juice of the stems. In describing to Charles V. the various articles of provision that were.met with in the march to Tlatclolclo, Cortez says, " They sold us the honey of bees, wax, and honey from the stems of the maize plant." Maize when ground and boiled makes a kind of pudding in universal use, and the ear, when nearly ripe, whether boiled in water or roasted in the ashes, is held a luxury by all class- es. In the tropical Cordillera maize is advantageously cultivated from the level of the sea to the height of 9186 feet above it ; that is to say, it thrives in temperatures which vary between 14° and 27.5° C. (57.5° and 81.5° F. ;) this circumstance explains its very general introduction into Europe. Maize succeeds on all soils when they are properly manured ; I have seen beautiful crops upon the most sandy soils and upon the stifFest clays ; it requires much the same management as our ordi- nary grain crops ; the climate alone should decide as to whether its introduction into a particular district is opportune or not ; a certain degree of heat is necessary to ripen it, and above all, the cold to which it is exposed must not be too severe. It is for this reason, that in the east of Europe the maize is sown in spring, when there is no longer any apprehension of frost ; there would be a real advan- tage in sowing late, were it not for fear of the frosts of autumn at the season of ripening. The susceptibility of maize to frost and climate generally, appears to me very analogous to that of the vine ; and I doubt whether it would be wise to attempt its cultivation on the great scale where the grape does not ripen in ordinary years. Maize is sown either with the dibble or with the hand, following a furrow opened by the plough ; I believe that it ought never to be sown broadcast, for it is a plant that requires room ; it is only in the hottest countries that the drill system is less necessary. In Alsace the drills are about 2^ feet apart, and the seeds are sown at the distance of abou'- & foot from each other. This very considerable spaco left be* 180 MAIZE. tween the maize plants appears to authorize the general custom that prevails of interposing som3 other crop in the fields under Indian corn ; that which is most generally interposed is either the dwarf haricot or the potato. I observed the same custom in the more tem- perate valleys of the Andes, where it is almost as necessary as in Europe to leave free spaces between the plants to give them air and sun ; but the plant is cultivated alone in the hotter regions. Soon after maize has sprung it receives a first hoeing, and after it has got to a certain height, a second ; in Alsace, for instance, it is custom- ary to hoe towards the end of June ; but I never saw any operation of the kind performed between the tropics : the only care they seemed to take of their fields of Indian corn, was to pull up foul weeds In Europe it is usual to take away the sprouts which rise beside the principal stem ; this precaution is also unnecessary in equatorial countries where the ground is fertile ; the more lateral stems that rise, the better, as they all become richly laden with grain. I may also say as much for the system of topping which prevails among us, tiiat system which consists in removing the extremity of the stem which bears the male flowers after the fecundation has been efifected. The leaves and heads of stems which are obtained by this operation, compose a forage by no means to be despised. The time during which the crop of maize remains on the ground, is greatly influenced by the mean temperature of the climate ; in hot intertropical countries, the grain ripens in less than three months, and there are even farms upon which four considerable crops are gathered in the course of the year. On the temperate plateau or table-land of Bogota, the plant ripens in six months ; in Alsace about the same length of time is required, although at Bechelbronn, in 1836, the maize which was sown on the 1st of June was gathered ripe on the 1st of October. Maize is dried either in exposing the spikes stripped of their covering upon the floor of a well-ventilated gra- nary, or by hanging them up in bunches or sheaves under sheds, or under the eaves of the house. In warm countries the drying is accomplished by one or two days' exposure to the sun, after which the spikes are stored. The maize is freed from the stem with the hand in small farms, with the flail in larger establishments. In America the operation is never done until the moment when the grain is want- ed, as it is said that the grain is less subject to be attacked by insects v/hen it is kept in the ear. When animals are fed on maize, hey are accustomed to separate it for themselves. The produce in Indian corn varies greatly, as appears by the fol* lowing table, in different countries : Countriei. Produce in butbeli per acr«. Lavanthal 81 Carinthia 55 Austria and Moravia 24 Hungary and Croatia 42 Tuscany % France (climate of PiVs) 29 Alsace 43 Venezuela 147 MAIZE. 181 By far the finest crops of Indian corn in America are obtained upon breaks of virgin seil. I do not hesitate to say that the husbandman gains from six hundred to seven hundred times his seed under such circumstances. The mode of proceeding upon these breaks, which I have frequently witnessed, deserves to fix attention for a moment. The planter chooses the end of the rainy season for cutting down the trees and the brushwood : every thing remains where it falls until it is sufficiently dry ; fire is then set to the heap, and the burn- ing extends and lasts even for weeks; all the smaller branches are completely consumed, nothing but the charred trunks of the larger trees remain. As the rainy season is about to return, a man, with a pointed stick in his hand, goes over the burnt surface, making a hole of no great depth at intervals, into which he throws two or three particles of Indian corn, over which he draws a little earth, or rather ashes, by a slight motion of his foot. This primitive mode of sowing terminated, the planter takes no further heed of the crop ; his habitation is often so remote, that he never visits it until harvest time : the rain and the climate do all the work. It is unnecessary to hoe, the burning having destroyed all the plants that were indi- genous to the soil ; nothing rises but the grain which has been sown. In such fields, stems of Indian corn are frequently seen of the height of from twelve to fourteen feet. It rarely happens that more than three consecutive crops are taken from the burnt soil ; and the last, though still very superior to any thing which we can obtain by our regular husbandry, is not to compare with the first. As there is no want of forest, it is held preferable to make a fresh break. Taking the seed as unity, it is found, from documents now pos- sessed, that 1 of seed will yield — in Mexico (an indifferent harvest) 150 ; in New California (beyond the tropics) 80 ; Alsace (the plants very far apart) 190 ; Venezuela (an ordinary crop) 238. Besides the grain and the straw, the husks and the cores of Indian corn are all extremely valuable upon the farm as forage, and as affording manure. Maize has been analyzed by M. Payen, and found to contain i starch 71.2; gluten, albumen, &c., 12.3 ; fat, oil, 9.0; dextrine and glucose 0.4; woody tissue 5.9; and salts 1.2; 100.0. T found 0.02 of azote in a sample of dry maize, which I analyzed, a quantity which indicates 12.5 of gluten and albumen, a result that coincides exactly with M. Payen's analysis. Rice, {Oriza saliva.) Rice is an aquatic plant which can only be grown in low moist lands that are easily inundated. The ground is ploughed or stirred superficially, and divided into squares of from twenty to thirty yards in the sides, separated from each other by dikes of earth, about two feet in height, and sufficiently broad for a man to walk upon. These dikes are for retaining the water when it is required, and to permit of its being drawn off" when the inunda- tion is no longer necessary. The ground prepared, the water is let on, and kept at a certain height in the several compartments of the rice-field, and the seedsman goes to work. The rice that is to be used as seed must have been kept in the husk ; it is put into a sack, 16 182 COFFEE. which is immersed in water, until the grain swells and shows signs of germination ; the seedsman walking through the inundated fisld, scatters the seed with his iiand as '.'sual, the rice immediately sink* to the bottom, and may even pencorate to a certain depth into the mud. In Piedmont, where the sowing takes place at the beginning of April, they generally use about fifty-five pounds of seed per acre. The rice begins to show itself above the surface of the water at the end of a fortnight ; as the plant grows, the depth of the water is in- creased, so that the stalks may not bend with their own weight. About the middle of June this disposition is no longer to be appre- hended ; the rice is no longer so flexible as it was, so that the water can be drawn off for a few days to permit hoeing, after which the water is let on and maintained to the height of the plant ; in July it is usual to top the stalks, an operation which renders the flowering almost simultaneous. Rice generally flowers in the beginning of the month of August, and a fortnight later the grain begins to form. It is at this period especially that the stalks require to be supported, and this is eflfectually done by keeping the water at about half their height. The rice-field is emptied when the straw turns yellow. The harvest generally takes place at the end of September. In the Isle of France, rice is cultivated in very damp soils, upon which a great deal of rain falls, but which are not flooded artificially, I have seen the same process followed in other tropical countries which I have visited, but I do not think that the produce is so great, or the crop so certain, as where inundation is employed. In Pied- mont, the usual return from a rice-field is reckoned at about 50 for 1 of seed. At Muzo, in New Granada, the paddy fields, which are not inundated, under the influence of a mean temperature of 26° cent. (79° Fahr.) yield 100 for 1. Thrqp kinds of rice yielded, on analysis, the following quantities of— Carolina. Piedmont. Rice. Starch 89.5 90.1 86.9 Gluten, albumen, &c 3.8 3.9 7.5 Fattymatters 0.2 0.3 0.8 Sugar (glucose ?) 0.3 0.1 > «. Gum 0.7 O.U •* Woody tissue 5.1 5.1 3.4 Phosphate of lime 0.4 0.4; «« Chloride of potassium, phosphate of ditto, &c. J '_ 100.0 100 U 100.0 M. Payen's analysis indicates a proportion of azote, the double of that found by M. Braconnot. In a trial for azote, which I made myself, I found 1.2 of this element per cent., which would show the amount of albumen and gluten to be 7.5, a quantity that corresponds exactly with M. Payen's valuation. Coffee, {Coffea Arahica.) The habit of using the infusion of coffee appears to have been introduced into Europe about the middle of the sixteenth century. The first public estabiisfhments for the sale of the drink were opened in Constantinople, in the year 1554. The use of coffee remained for a long time coniiaed to the East ; but b COFFEE. 183 degrees it spread, and at the present day the consumption of the article in Europe exceeds 660,000,000 of pounds annually. The greater portion of coffee consumed in Europe is the produce of America, and yet it is not more than a century since it was first grown in the New W(.rld. The oofFee-plant thrives between the tropics in situations where the mean and nearly constant temperature is between 22° and 26° C, (71.5° and 80° F.) Coffee is rarely sown in a nursery : the seeds are made to germinate still surrounded by their natural pulp, and wrapped up in leaves of the banana. The young plants, after seven or eight days of germina- tion, are put into the ground. In the valley d'Aragua an acre of ground of good quality is generally laid out with about 1040 plants. The coffee-plant flourishes in the course of the second year ; when left to grow unimpeded it will attain a height of from 23 to 26 feet, but it is seldom allowed to grow so high, its upward progress being checked by pruning ; the planters of Venezuela generally keep it at a height of from five to six feet. The shrub receives the care of the planter during the first two years ; the ground must be kept free from vk^eeds, and the growth of parasites must above all be prevented. To thrive, the coffee-plant requires frequent rains up to the time of flowering. The fruit bears a strong resemblance to a small cherry, and is ripe when it becomes of a red color, and the pulp is soft and very sweet. As the berries never ripen simultaneously, the coffee harvest takes place at different times, each requiring at least three visits made at intervals of from five to six days. A negro will gather from ten to twelve gallons of fruit in the course of a day. Two beans are found in the interior of each berry ; in order to free these from the pulp which surrounds them, they are passed hrough a kind of mill, and the coffee is steeped in water for twenty- four hours in order to free it from the mucilaginous matter which adheres to it; it is then dried by being spread out upon a floor under a shed. In the coffee plantations of Venezuela which I visited, I saw them proceed in another way. The berries were exposed to the sun upon a piece of ground somewhat inclined, and spread out to about three inches in thickness ; the pulp soon enters into fer- mentation, and a very distinct vinous odor is exhaled, and the juice altered either flows away or dries up ; at the end of a fortnight or three weeks the berries are all dry and shrivelled, and they then undergo two triturations, one to obtain the seeds or beans, the other to detach a thin pellicle which surrounds them. Three bush- els of berries will yield from 85 to 90 lbs. of marketable coffee. During the destruction of the sugary matter contained in the pulp of the berry, a considerable quantity of spirit is produced and dissi- pated. M. Humboldt, struck with the readiness with which the berry of the coffee-plant runs into fermentation, expresses his sur- prise that no one ever thought of obtaining alcohol from it. In an old work, however, I find the following passage : " The inhabitants of Arabia take the skin which surrounds the coffee bean and prepare it as we do raisins ; they form a drink with it for refreshment during 184 COCOA. the summer."* This vinous liquor appears to enjoy all the exciting properties which are esteemed in the infusion of coffee. The coffee-plant continues to produce to the age of forty to forty- five years ; it bears to a co. siderable extent even in the third year. Some siirubs yield from 17 :o 22 lbs. of dry coffee beans ; but thia is a very large quantity. An acre of land in the valley d'Aragua, planted with about 1040 shrubs, will yield about 940 or 950 lbs., which is at the rate of somewhat less than 1 lb. per shrub. Coffee contains the same active principle as tea, coffeine, but in less proportion ; the researches of different chemists have also shown the presence of a particular acid called coffeic acid, of fatty matters, a volatile oil, a coloring matter, albumen, tannin, and alka- line and earthy salts. Cocoa, {Theobroma cacao.) The ancient Mexicans cultivated the cocoa-tree, and with its seeds prepared tablets similar to the choco- late of modern times. The use of cocoa appears to have been in- troduced after the conquest into the other parts of the continent ; nevertheless, the cocoa-tree is indigenous in the hot and humid forests of South America. M. Goudot discovered several species in New Granada ; among others, that which is known at Muso under the name of the Cacao montaraz : this cocoa-tree, which attains a height of from 25 to 30 feet, yields a considerable quantity of fruit ; the natives prepare a chocolate from its beans, which is extremely bitter, and which they regard as an excellent febrifuge. The wild Indians still appear to be ignorant of the profit that may be made of the seeds of the cocoa-tree ; they only eat the pulp of fruit which surrounds them. Cocoa was introduced into Europe by the Span- iards, and in no long space of time this production of the New World became the object of a very considerable traffic. It is a fact well known to the husbandmen of tropical countries, that a virgin soil is quite indispensable to the success of a cocoa plantation ; nothing but failure has followed attempts to replace the sugar-cane, indigo, maize, &c., with cocoa, a plant which to succeed requires a rich, deep, and moist soil, heat and shade ; nothing suits it better than a forest brake, the surface of which is susceptible of irrigation. AU the important cocoa plantations which I visited had a common physiognomy : they were all situated in the hottest regions, at a short distance from the sea, near torrents, or on the banks of great rivers. The cocoa husbandry ceases to be profitable in localities which have not a mean temperature of at least 24° C, (75.2° Fahr.,) and I have had occasion to take part in attempts that were as fruit- less as expensive to cultivate the cocoa-tree in a brake where the heat of the climate from my own observations did not exceed 22.8" C. (73° Fahr.) Under the influence of this temperature, the trees presented a very good appearance ; in the course of a few years liiey flowered, but the fruit, which was always small, rarely came to uiaturity. When a piece of land has been selected for a cocoa • Mem. of the Academy of Ii-,9;Tiptions, vol. xxiii p. 214. COCOA. 185 plantation, they begin by establishing a good system of shade. Oc- casionally a certain number of trees, with large and leafy crowns, are left standing ; but in general certain plants, which grow rapidly, are had recourse to as a means of procuring shade. In the neigh- borhood of Caraccas they shade with the erylhrina umbrosa ; and in some plantations they take advantage of the shade of the ba- nana ; finally, the two modes of procuring shade are frequently con- ioined. In the province of Guayaquil they plant the beans of the cocoa directly. In Venezuela they prefer raising the plant in a nursery, which is always selected of the most fertile soil, and deeply trenched. The seeds are sown immediately before the setting in of the rains, and germination takes place in from eight to ten days. In a good soil, at two years of age the cocoa-plant will have attained a height of nearly 3 feet ; it is then pruned hy having two of its upper branch- es removed, and is transplanted. In the upper valley of the Rio Magdalena, where there are many valuable cocoa-groves, the sow- ing is performed in ground well prepared and protected by screens made with palm leaves ; here the young cocoas are transplan!«3d when they are six months old. During the whole of the time that the plants remain in this nursery they continue to be well shaded ; and they are watered once a week by water poured upon the screens. The tree seldom comes into flower under thirty months old. I have known planters who always destroyed these first flowers, and who never suffered any fruit to ripen before the fourth year, and that too under the most favorable circumstances in regard to climate, in situations where the mean temperature was 27 5° C., between 81° and 82° Fahr. In less favorable situations it is necessary to wait six or seven years before gathering the first fruits of a cocoa planta- tion. There are few arborescent plants which have so small a flower, and especially a flower so disproportionate to the size of its fruit, as the cocoa-tree. The diameter of a bud, measured at the moment of its expansion, does not exceed 4 millimetres — -0.157 of an English inch. The flowers appear principally upon the trunk of the tree itself; they rarely show themselves beyond the middle of the larger branches ; occasionally they appear upon the roots which happen to be above the ground. To receive the young plants grown in the nursery, the ground properly shaded is first freed from weeds. Trenches are then cut, either to season the ground or to irrigate it when requisite. The young plants are set in rows at regular and considerable distances, which vary, however, with the quality of the soil ; and the general opinion is, that the better the soil the greater should be the space from tree to tree. Thus in the valley of del Tuy, in the neighbor- hood of Puerto Cabello, the cocoa-trees are set at the distance of about 16 feet apart in the best soils, and at the distance of about 13 feet only in soils of inferior quality. In the windward islands, where the soil is generally less fertile th'an on the continent, the trees Btand at the distance of from 6 or 7 to 9 or 10 feet apart. A reasoo 16* 186 COCOA. for this practice may be readily assigned ; in the more fertile soils the trees grow more vigorously, the branches spread further, and consequently require a larger space. Once the cocoa-tree is in the plantation, it is regularly pruned to prevent its branches becoming too numerous. It sometimes happens that the branches show a tendency to bend down towards the ground, in which case they are fastened up around the trunk, until they acquire strength and a better direction. The soil around the trunk is hoed from lime to time to the extent of about a yard in circum- ference, and the capillary roots, which spring from the base of the trunk, are removed in the course of the operation. From the fall of the flower to the complete ripeness of the fruit there elapses an interval of four months. The fruit is of an elon- gated form, slightly bent, and terminated in a point ; its length is about 9 inches, and its greatest diameter, which is near the point of attachment, is from 6 to 7 inches. Externally, the cocoa-nut pod is furrowed longitudinally. Its color varies from a greenish white to a reddish violet, the latter being the more common tint. Internal- ly the flesh of the fruit is generally white, although it has sometimes a rose-color ; it is sweet and acid, and of a very agreeable flavor. The seeds are generally twenty-five in number in each fruit, and at first are white ; they are oleaginous and slightly bitter ; in drying they acquire a brown tint. The fruit is known to be ripe by its color, and particularly by the ease with which it is gathered from the tree. There are two grand cocoa harvests in the course of the year, at six months' interval ; still, in old and large plantations the harvest is almost incessant, as it is not uncommon to observe, on the same cocoa-tree, ripe fruits and fresh flowers. To obtain the seeds the fruit is opened with a piece of wood, having a rounded extremity. The produce is classed according to its quality, care being taken to throw out all the beans that are not sufficiently ripe or that are damaged ; they are then exposed in the sun. Every evening the day's gathering is collected into a heap under a shed, and a brisk fermentation is soon set up, which would become destructive were it suffered to continue. Next day the heap is scattered, and the drying goes on in the sun, several days' exposure being required before the drying is complete. Occasionally the drying is retarded and ren- dered difficult by the occurrence of rain, and there would certainly be many advantages in effecting it by the stove. It has been found that 100 lbs. of fresh beans give from 45 to 50 lbs. of dry and mar- ketable cocoa. In Venezuela, a cocoa-tree which is over seven or eight years old, will yield annually for more than forty years over 1| lb. (1.65 lb.) of dry and marketable cocoa. An acre of ground, which in good plantations will be set with about two hundred and thirty-three trees, produces in a middling year about 383 lbs. weight The cocoa-tree appears to yield most abundantly when it is abou twelve years of age, and its produce in the fertile lands of Upper Magdalena, according to M. Goudot, is greatly superior to what it is in Venezuela. A.t Gigante, for example, each adult tree yieldi PEAS, BEANS, ETC. 187 4.4 lbs. of dry cocoa annually, and the produce of an acre there may be estimated at 733 lbs. 'w Cocoa beans contain albumen, a particular principle, tbeobroxnine, analogous to coffeine, a coloring matter, and a large quantity of oil or fat, which, from experiments made in my laboratory, appears to amount to 43 per cent. The presence of a large quantity of albu- men and fatty matter in cocoa explains its highly nutritious qualities. It is indeed one of the most wholesome and restorative articies of sustenance known. Nevertheless, very opposite statements have been made upon the virtues of cocoa or chocolate, of which the bean forms the basis. Benzoni, in his History ot the New World, de- clared chocolate to be a drink that was fitter for hogs than men ; and Father Acosta declares the taste for cocoa to be unreasonable. On the other hand, Fernando Cortez and one of his gentlemen fol- lowers are perhaps guilty of exaggeration when they say, " that he who has taken a cup of chocolate may march the rest of the day without other aliment I"* Without going the whole of this length with Cortez, 1 still allow that chocolate is one of the best articles for travelling upon, especially in the uninhabited forests of South America, where it is a matter of the highest moment to have the bulk and the weight of necessary rations as small as possible. Seeds of leguminous plants. The leguminous plants that are cul- tivated as food for man are beans, peas, haricots, and lentils; vetches are grown exclusively for the use of cattle. Leguminous plants scarcely ever open rotations ; but they very often wind them up. Speaking generally, however, they may follow any crop. In speaking of the Indian corn, I have said that haricots and beans might be advantageously intercalated. The meteorological observations I have made in different coun- tries lead me to conclude that to succeed, leguminous plants require a temperature which in the mean does not fall below from 14° to 15° C, (57° to 59° F.) Hot climates agree with them perfectly ; I have followed them from the sea-board of the equatorial Andes to a height of from 8-200 to 9800 feet above the level of the sea. Schwertz has given the following statement of the produce of the different legu- minous plants generally cultivated : Plants. Weight per Produce per acre Weight of dry straw bushel in lbs. in bushels. or haulm per acre. Tons. Cvvts. qrs. lbs. Haricots . . 47.5 66.7 Beans . . . 65.5 66.2 2 2 2 17 Peas . . . 57.9 38.5 2 4 2 11 Lentils . . . 62.3 39.8 Vetches . . . 62.3 41.2 2 4 2 11 The analyses we have of leguminous vegetables show the follow ing proportic n of elements : * Humboldt, Travels, vol. v. p. iS8 THE HOP. « Haricots Peas. Lentils. Legumine 22.0 20.4 22.0 Starch .... 41.0 47.0 40.0 Fatty matters 3.0 2.0 2.5 Sugar (glucose ?) . 0.3 2.0 1.5 Gum .... 4.0 5.0 7.0 Woody fibre, pectic acid 8.0 11.0 12.0 Salts, phosphates, &c. 3.2 3.0 2.5 Water and loss 17.5 9.6 12.5 100.0 100.0 100.0 Besides these principles, a quantity of tannin has always been found in the skin of the seed of all leguminous plants. The Hop, {Humulus lupulus.) From its very general use in making beer, the hop has become an object of great importance, both in an agricultural and commercial point of view. The hop may be cultivated in any soil that is of sufficient depth and fertility ; it thrives especially in rich and turfy loams, such as those of Haguenau, where there are many beautiful, hop-gardens. The plant is propagated in the spring by setting the sprouts or radicu- lar buds in ground trenched to the depth of 18 inches at least, at in- tervals of about a couple of yards from one another. Within a few weeks the young hop-plant is growing lustily; and as it is a climber, it is trained upon a pole of from 12 to 20 feet in height. The ground is usually hoed towards the end of June. The first crop from a new plantation is always trifling in amount ; the ground is then manured. The following spring all the eyes or buds that have become devel- oped near the root are removed, except six or seven, which are left to slw»ot. The hop harvest generally occurs about the middle of September : the poles are pulled up, the stems are cut, and the strobiles are picked off into baskets by hand, and immediately car- ried to the stove or kiln, where they are dried with a very gentle heat, in order not to dissipate their fine aromatic particles. A hop-garden produces very variously in different countries and districts, and in different years. The produce of an acre in hopf has been stated to be : In Flanders, 13 cwt Germany (mean of 10 years,) . . 10 " France (near Paris,) . . . 10 " " (Roville, mean of 10 years,) 1\ " [England, from 9 to 10, and from 12 to 14 cwt.] The strobiles of the hop are covered with a yellow pulverulen* substance, which has been held to furnish in principal part the ex tractive matter that is so valuable in brewing. To procure this sub stance it is enough to sift a quantity of hops after they have beer dried by a gentle heat. This yellow powder, which appears to b« the useful principU; in the hop, and consequently gives it its value BANANA. 189 is not found in the same proportion in the produce of all hop-gardens. This clearly appears from the inquiries of Messrs. Payen and Cheva- lier. They found, for example, that while 100 parts of thd hops of Belgium contained 18 of yellow substance and 70 of mere leaf, those of England contained no more than 10 of yellow ir.atler and 87 of leaf, and those of Germany the still smaller quantity of 8 of yellow matter to 88 of leaf. This yellow pulverulent matter con- tains wax, resin, gum, a bitter principle, certain azotized principles, a volatile oil, and salts, among others acetate of ammonia. FLESHY OR PULPY FRUITS. The fleshy fruits almost all contain the same principles, but in very different proportions. It is consequently the predominating piinciple which in some sort characterizes each variety, that gives it its flavor, odor, &c. : sugar, albumen, gum, starch, acids, fixed oils, essential oils, woody fibre, are almost invariably found secreted in their pulps, with a larger or smaller quantity of water. An in- genious classification of fruits has been formed on the basis of the predominance of the different substances which have just been enu- merated : thus those fruits in which the starchy principle predomi- nates are feculent or amylaceous fruits ; those in which the sugar predominates are saccharine fruits, and so on. M. Berard has analyzed a great number of fruits in the course of his researches on their ripening.* It is proper to say, however, that some of the principles brought to light by modern analysis do not figure in M. Berard's list of elements ; among the number, pectic acid, gallic acid, small quantities of volatile oils, and of salts of potash formed by vegetable acids. . i 1 s h .« t i: s a 0 i V 0) Albumen and gluten < Pk ^ o o Pu. 0.2 0.9 0.9 0.6 0.3 0.2 Coloring matter 0.1 0.1 Vegetable tissue 1.9 1.2 8.0 1.1 1.1 2.2 Cum 5.1 4.9 0.8 3.2 2.1 2.1 Sugar 16.5 li.6 6.0 18.1 24.8 11.5 Malic acid 1.80 1.1 2.4 2.0 0.6 0.1 Citric acid (( 0.3 Lime 0.1 0.3 0.1 Water . J4.4 80.2 81.3 74.9 71-0 83.9 100.00 100.0 100.0 lOU.O 100.0 100.0 Banana. Of all the pulpy fruits, the banana is that perhaps whicli IB most extensively used as food by man. It is the usual nourish ♦ Ann. de Chimie, t. xvi. p. 225, 2d series 190 BANANA. ment of the inhabitants of most of the countries between the tropics, where its cultivation is as important as that of the cereals and fari- naceous roots in the temperate zone. The ease with which it is cul- tivated, the small space of ground it occupies, the certainty, the abundance, and the continuance of its produce, the diversity of food it yields according to the degree of maturity, make the banana an object of admiration to the European traveller. In climates where man scarcely feels the necessity of clothing himself, or of raising a shed for his protection, he is seen gathering almost without labor supplies of food as abundant as they are wholesome and varied from the banana-tree. It is the banana which has given rise to that prov- erb so consoling and so true, which is frequently heard between the tropics, viz. " No one dies of hunger in America;" he who is hun- gry will be welcomed and fed in the very poorest cabin. Botanists distinguish three principal- varieties of the banana: 1st. the Musa paradisica; 2d. the Musa sapientium ; 3d. the Musa regia. The American origin of the banana has been called in question. Oviedo in his natural history of the Indies affirms that it was brought from the Canary Isles to St. Domingo by a monk. Foster adopted this opinion, which is corroborated, says M. de Humboldt, by the complete silence of the first travellers who visited the New World in regard to it. Nevertheless, the testimony of the Inca Garcilasso de la Vega proves obviously that the banana flourished in America be- fore the arrival of the Spaniards ; in his royal commentaries he speaks of the banana as constituting the chief food of the Indians in the warmest parts of Peru. The banana is everywhere cultivated in the neighborhood of the equator, in situations at no great height above the level of the sea. The cultivation is most profitable, the crop is most abundant, and at- tains maturity in the shortest space of time in low lying districts where the mean temperature is from 24° to 27.5° C, (75.5° to 82* F.) Some estimate may be formed of this from the low price of the banana in such districts ; upon the borders of the great river de la Magdalena, I gave one franc or about lOd. for about 220 lbs. weight of the fruit. The day's wages of a man being generally about Is. 8d., it is beyond all doubt the cheapest food that can be had in the world. In looking at the cultivation of the banana at different heights in the equatorial Cordilleras, I arrived at the following conclusions : Temperature 28° C. (between 82° and 83° F.) the cultivation ex- tremely advantageous ; at 24° C. (between 75° and 76° F.) the cul- tivation advantageous ; at 22° (71° and 72° F.) the cultivation mid- dling ; at 19° C. (or between 66° and 67° F.) the cultivation disad- vantageous. The banana is propagated by means of suckers or offsets. It re- quires a rich and humid but well-drained soil, the plantation^ being arranged a little before the setimg m ot the rains. The earth is freed from weeds, and dug either entirely or more generally only at regular distances here and there, where it is proposed to set the new plant, a space of 6 feet at least being left between each. The plant lbr9W8 up several shoots, generally 6 or 7, each of which will be dji- I BANANA. 101 iowed to grow and to carry fruit ; when a greater number make theit appearance, some of them are cut away. The time which passes be- tween planting the slip and gathering the fruit varies according to the situation ; in the hottest districts near the level of the sea ihe banana comes into flower about nine months after it has been plant- ed ; and in three months more the fruit has formed and become ripe. In cold situations an interval of four months will elapse between the flowering and the ripening of the fruit. The care required by a ba- nana plantation is not very great, the principal duty being to hoe around the young plants. As the banana is renewed by stems which arise continually from the neck of the root, it is easily understood that the plant will go on yielding fruit for an indefinite length of time ; when the fructification is complete in one stem, the leaves, &c., wither and fall, and give place to a new stem. It is thus that the gatherings from the banana go on successively at short intervals, and that the same plant presents at one and the same moment fruit that is ripe, fruit that is half ripe, fruit that is beginning to be formed flowers, and finally young stems, which are rising as preparations for the future. Thus no crop is more assuring to the planter than the banana. Climatic circumstances may sometimes delay, but can never destroy the hopes of the husbandman. The extraordinary droughts which under the burning climates of the equator so frequently interrupt or destroy ordinary herbaceous plants, rarely exert any pernicious influence upon the banana plantation, the thick shade of which pre- sents a constant obstacle to the evaporation of moisture. During the dry season, when for whole months the heavens preserve their purity, and no drop of rain falls to refresh the earth, the soil which surrounds the banana still continues moist. It looks every morning as it it had been watered during the night; this salutary effe t is produced by the nocturnal radiation of the leaves into the clear sky. These leaves, whose extent of surface is considerable, always fall several degrees below the temperature of the surrounding air, and hus condense the watery vapor contained in the atmosphere, which drips down to the foot of the plant. The produce of a banana plantation depends first upon the dis- tance at which the bananas are placed, and next upon the climate. It is generally estimated in the very warm climates, that a crop of bananas will weigh about 44 lbs., and that from an adult plant three crops will be obtained in the course of a year. In temperate coun- tries, and towards the superior limits of the banana plant, they do not reckon on more than two crops. According to M. de Humboldt, the produce per acre, in hot countries where the mean temperature is about 82° Fahr., will amount to 75 tons, 8 cwt. 1 qr. 17 lbs. ; at Cauca, where the temperature is about 79" Fahr., the produce amounts to ei'tons, 8 cwt. 0 qr, 2 lbs. ; at Ibague, where the temperature is not higher than about 72°, the produce, according to M. Goudot's es- timate, is 26 tons, 17 cwt. 3 qrs. 2 lbs. The pulp of the banana is surrounded by a pod or husk of some thickness, which is easily de- tached, and of which account must be taken if we would estimate the actual weight of the truly alimentary matter afforded. In a 192 BANANA. general way, and when the banana is ripe, the shell may be estimated at about 36.8, the edible banana at 73.2 per cent. The Musa paradisica is the variety of banana generally culti- vated, and it also yields the heaviest crops. The fruit of the other two varieties mentioned is much smaller ; but it is of a much more delicate flavor. The ripe fruit of the banana is of the consistence of a pear ; it is very sweet, and slightly acid. In the common va- riety, 1 found crystallizable sugar, gum, an acid, (probably the rnalic,) gallic acid, albumen, pectic acid, woody fibre, and alkaline and earthy salts. Dried in the sun, 1000 parts of ripe banana were reduced to 439 parts ; so that they contained 561 parts of water. The green or unripe banana has a white and almost insipid flesh. In this state it scarcely contaias any sugar ; it is starch that predominates. In this state, therefore, it is made a substitute for bread, for the potato, or Indian corn ; it may be considered a farinaceous vegetable. After having removed the rind, the banana is dressed by being roasted under the ashes until the outer part is slightly brown ; it is then served up at table, and constitutes a kind of soft bread, very agreeable to the palate, and greatly preferable, in my opinion, to the produce so much vaunted of the bread-fruit tree. In the expeditions which are undertaken into the forest, and when the habitations of man are to be quitted for some considerable time, the green banana is always made a principal part of the provision ; but then it is pre- viously dried, first to lessen its weight, and then to destroy its vi- tality so far as to prevent its ripening. This drying is performed in a baker's oven, into which the green bananas, stripped of their husks, are introduced, and where they are kept for about eight hours. On being taken out, the bananas are hard, brittle, translucent, and pre- sent the appearance of horn ; 100 lbs. of the green fruit give but 40 of dry substance. The banana thus prepared is called^, and will keep for a great length of time without change. To prepare it for food, it is put to steep in water, and then boiled ; by adding a little salted meat, a very substantial and nutritious meal is prepared. I once made a voyage on the Pacific, in a vessel which was princi- pally victualled with dried bananas, which were served out to the company like biscuit. When ripe,, the banana is no longer farinaceous ; as it ripens, its starch is changed into gum and sugar, and an acid is developed. But between the farinaceous and the sugary or perfectly ripe state, there is one intermediate, in which it is generally eaten. Roasted in the ashes, the banana has then a taste which brings to mind that of .he chestnut ; it is also eaten as a vegetable, boiled in the usual way m water. Completely ripe, the fruit is eaten raw or dressed, it is then extremely sweet ; a very common practice is to fry it, cut in slices, in grease. I have no data upon which to estimate the nutritive value of the banana, still I have reasons for believing that it is more nutritious than the potato. I have seen men do a great deal of hard labor upon an allowance of about 6^ pounds of half-ripe bananas, and two ounces of salted meated per diem 193 CHAPTER III. or THE SACCHARINE FRUITS, JUICES, AND INFUSIONS USED IN THB PREPARATION OF FERMENTED AND SPIRITUOUS LIQUORS. The juice of all the sweet fruits when expressed and left to itself under the influence of a suitable temperature, presents the re- markable phenomenon of fermentation, in the course of which the sugar disappears completely, and is replaced by alcohol, the change from first to last being accompanied by the disengagement of car- bonic acid gas. Sugar alone does not suffice to cause the vegetable juices, which contain it, to ferment : for example, a solution of pure sugar in dis- tilled water will remain for a very great length of time without suf- fering the least change ; exposed to the open air it would evaporate, and the saccharine matter would be found in the same state as it was before solution If, however, a small quantity of that azotized principle which we have called albumen, gluten, &c., be introduced into the solution, fermentation will speedily be set up, and will run through its usual course ; it would, therefore, appear to be upon this principle that the commencement and continuance of fermentation depends Fermentation is not set up immediately in the juice of fruits ; a certain time longer or shorter always elapses before it is manifested ; the reason of this is, that the albumen or gluten which always enters into the constitution of these juices, must itself have undergone a certain change in order to act as a ferment. The proof of this is comprised in the fact that all vinous liquors contain a very small but constant quantity of carbonate of ammonia, as was shown by M. Doebereiner. These azotized principles, which in the fresh state remain without action upon sweet juices, act immediately as powerful ferments when they are employed after having been ex- posed for some days to the contact of air and moisture ; after, in a word, they have themselves begun to suffer change. The quantity of ferment used up or consumed in exciting and maintaining the fer- mentation of saccharine juices is so small, that we are led to believe that it really acts by its presence or contact alone. This view ap- pears the more likely, when we know that, after having added an azotized substance to induce fermentation rapidly in a liquid which, besides sugar, contains albumen, we find from six to eight times the quantity of ferment after the phenomena have ceased, which had been added in the first instance ; that is to say, we find the whole, or almost the whole, of the original ferment, and, in addition, that which has been produced by the azotized principles pre-existing in the matter subjected to fermentation ; this fact is seen every day in the process of making beer. The ferment or yeast thus produced is but little soluble in water, and in composition bears a remarkable affinity to the azotized mat- 17 194 THE VINOUS FERMENTATION. lers from whicl is derived ; M. Dumas has in fact found it tot« composed of: Carbon 50.6 Hydrogen 7.3 Azote 15.0 Oxygen ) Sulphur V 27.1 Phosphorus ) 100.0 Under the influence of ferment, sugar becomes entirely cimnged into alcohol and carbonic acid. The composition of grape-sugar— ■^^hich appears to be the only one that is susceptible of fermentation, for cane-sugar before undergoing this process passes into the state of grape-sugar, as was demonstrated by M. Henry Rose — the com- position of grape-sugar is as follows : Carbon 36.4 Hydrogen 7.0 Oxygen .56.6 100.0 and the constitution of the substances which are produced in the process of fermentation, viz. alcohol and carbonic acid, being as under : Anhydrous alcohol. Carbonic acid. Water. Carbon 52.19 27.27 Hydrogen 13.02 " 11.1 Oxygen .34.79 72.73 88.9 100.0 100.0 100.0 It appears that the composition of 100 parts of grape-sugar may be expressed by : Carbon. Hydrogen. Oxygen, Alcohol 46.16 containing 24.24 6.05 16.17 Carbonic acid 44.45 " 11.12 " 32.33 Water 9.09 " " 1.01 8.08 100.00 36.36 7M 58!58 oy which it would appear that during the transformation of hydrated grape-sugar into alcohol and carbonic acid, the combined water is set at liberty. The first fermented vegetable juice of which I shall speak is cane-wine^ or guarapo of the South Americans, a drink which is m common use wherever the sugar-cane is cultivated. It is prepared from the juice of the sugar-cane suffered to run into fermentation. The chicha of South America is a fermented liquor prepared from Indian corn, and constitutes the wine of the Cordilleras. The grain is steeped for six or eight hours in water, bruised upon a stone and boiled ; the pulp which results is then diffused through 4| times its volume of water, and the temperature being from 60° to' 65° F., a violent fermentation is §oon set up in the fluid, which begins to sub- side after a period of twenty-four hours, when the chicha is potable and now constitutes a liquor of an agreeable and decidedly vinous flavor, in high repute with those who have acquired a taste for it although its muddy appearance and the sediment which it alware CIDER AND PERRY WINES. 195 fits fall in the vessel into which it is received, render it somewhat unpleasant at first to European eyes. The Indians, however, always drink it in the muddy state, and even shake the cask before turning- the tap. The truth is, that chicha is at once a drink and a very nu- tritious fqod. Guarazo is another vinous liquor which the Indians. prepare with rice much in the same manner as they proceed with Indian corn. Cider and Perry. In countries where the vine is not cultivated, a substitute for wine is found in the fermented juice of a variety of sweet pulpy fruits, more particularly of apples arid pears. Of the numerous varieties of apples which are grown in cider countries, the preference is generally given to one which has a rough and some- what bitter taste. The fruit is gathered by shaking or beating the trees, and the few that remain are taken off by the hand ; the fruit is piled up in large backs placed in cellars. It is crushed about two months after it is gathered, and the pulp is left for ten or twelve hours to macerate in the juice, in order to give the rusty or yellow color which is esteemed in cider. The pulp is pressed and the juice is run into large vats or tuns, in which it undergoes fermentation, which having gone on for about a month, the temperature being from 55° to 58° F., the liquor is racked off into smaller vessels, in which the fermentation goes on slowly, and the cider is preserved. The fermentation of cider is, or always ought to be, slow ; still, with time, the whole of the sugar is transformed into alcohol, if the pro- cess be not interfered with. Wine. Grape-juice contains — 1st. grape-sugar ; 2d. albumen and gluten ; 3d. pectine ; 4th. a gummy matter; 5th. a coloring matter ; 6th. tannin ; 7th. bitartrate of potash ; 8th. a fragrant volatile oil, or cream of tartar ; 9th. water. It is obvious, therefore, that grape- juice contains within itself the elements necessary for the produc tion of the vinous fermentation. The relative proportions of these different elements, however, are singularly modified according to the nature of the vine, the quality of the soil, and especially the heat of the climate. There are indeed few crops that are so much at the mercy of the atmosphere as that of the vine ; even in the vine- yards that are most favorably situated, it is rare that wines of equal quality and flavor are produced in two consecutive years ; and in districts upon the verge of the productive limits of the vine, under what may be called extreme climates, where the vine only exists in virtue of hot summers, its produce is still more variable, more in- constant. The limits to the culture of the vine in Europe are generally fixed where the mean temperature is from 10° to 11° C, (50° to 52° F. ;) under a colder climate no drinkable wine is pro- duced. To this meteorological datum must be added the further fact that the mean heat of the cycle of vegetation of the vine must be at least 15° C. (59° F.,) and that of the summer from 18° to 19" C, (from 65° to 67° F.) Any country which has not these climatic conditions cannot have other than indifferent vineyards, even when its mean annual temperature is above what I have indicated. It is impossible, for instance, to cultivate the vine upon the temperate 196 WINE. table-lands of South America, where they neverthelejo enjoy a mean temperature of from 17° to 19° C, (about 62.6° to 66.2° F.,) because that which characterizes the climate of these elevated equinoxial countries is the constancy of the temperature ; the vine grows, flourishes, but the grapes never become thoroughly ripe. In these equatorial countries good wine cannot be made where the con- stant temperature is not at least 20° C, (or 68° F.) In France the vine begins to sprout towards the end of March, and the vintage generally occurs in the course of October. As the quality of wine depends mainly on the ripeness of the grapes, of course the vintage does not take place until this is complete, or until there is no longer any prospect of improvement. The must of the grape is procured by treading and pressing the fruit ; the juice is run into vats, and the fermentation takes place in cellars ; different procedures, however, are foUowed in different places. The fermentation having subsided in the larger vessels, the wine is drawn off into smaller casks, which are carefully filled up from time to time, and in which it is preserved. Wine may be defective, especially by wanting strength and being too acid. Sharp wine contains an excess of cream of tartar and free vegetable acids, and is always the produce of grapes which have not been completely ripe. The deficiency of strength is due to the same cause ; for it is well known that as the grape ripens its acids disappear and are replaced by sugar. This deficiency of sac- charine matter in the must, is now habitually supplied by the addition of a quantity of artificial grape-sugar, prepared from starch. In warm countries, where the grape always ripens, the quantity of tar- tar is small ; the sugar then predominates greatly, sometimes to such an extent that the azotized substance of the must is insufficient as a ferment, and it is then that we have wines of too sweet a flavor, such as those of Lunel and of Frontignac. When these musts, which are so rich in sugar, contain the proper quantity of ferment they produce very strong wines, in which, of course, the sweet flavor no longer predominates; such are the dry wines of southern vineyards, of which that of Madeira may be taken as the type. There are some wines which participate at once in the properties that distinguish the two varieties thafti have mentioned, or that show one of them in excess according to circumstances ; such are the wines of Xeres, Alicant, Malaga, &c. Some of these wines are what are called boiled wines, that is to say, a portion of the must, as it flows from the press, is concentrated to a fourth or a fifth of its original bulk by boiling, and this being added to the rest, the strength of ilie resulting wine is increased. Sometimes the concentration of the juice is effected by drying the grapes partially. It is in this way that the celebrated Hungarian wine, called Tokay, is prepared ; the clusters are left upon the vines after they are ripo, and alternate- ly exposed to the cold of the night, which probably decomposes to a certain extent the texture of the grapes, and to the ; eat of the sun. They shrivel and become partially dry. In this state the grapes are subjected to pressure, and a very sweet must, as may be conceived, WINE. 19t flows from hem. In less favorable climates, where the rains of au- tumn prevent the drying of the clusters upon the vine stocks, the same thing is effected by laying the bunches upon straw in open or well-aired granaries or sheds. It is with the must procured from grapes so treated, that the sweet and often strong wines, which are called vins de paille, or straw wines, are obtained. Wines when stored in the cask always deposite with time a copious sediment, the lees. This sediment, in which tartar^ predominates, appears to be the consequence of an increase in the proportion of alcohol in the liquor. The alcohol may increase from two causes : first, by the fermentation which, though nearly insensible, goes on in most winea so long as there is any sugar left unchanged; and next from mere keeping. It is well known, in fact, that wine put into the best casks, and kept in a well-ventilated cellar, loses a very perceptible quantity by evaporation ; it is found necessary to fill up the casks from time to time : the loss has taken place through the pores of the wood, in virtue of an attraction exerted between the substance of the wood and the included liquid ; and as this attraction is much greater between the organic matter and water, than between organic fibre and alcohol, it is easy to conceive how wine kept in wood should improve. The very same thing, in fact, appears to go on in regard to wine in corked bottles : the cork does not oppose all evaporation, and it seems probable that it is not merely upon some new and little known change of a chemical nature in the constitu- tion of the wine that its improvement and mellowing in bottle de- pend, but also upon the loss of a certain quantity of its water through the pores of the cork. Throwing quality, flavor, &c., out of the question, it is well known that a vineyard, culivated in the same way, year after year, receiv- ing the same quantity of the same kind of manure, of which the vintage is managed in the same manner, the wine made by the same method, &c., yields a produce which diflfers greatly in regard to the quantity of alcohol it contains in different years. The vineyard of Schmalzberg, for example, near Lampertsloch, which has been under my management for several years, yields wines of the most dissimilar characters from one year to another. Some idea of this may be formed from the different quantities of alcohol which the wine of different years contains : Tciri. Mean temperature. Wine per acre in gallona. Pure alco- hol per cent. Pure al- cohol per acre, in gaUons. Of the whole term of the growtli of the Of the summer. Of the beginning of autumn. 1833 1834 1835 1836 1837 deg. deg. 14.7C. 58.4F. 17.3 63.1 15.8 60.2 15.8 60.2 15.2 59.5 deg. deg. 17.3C. 63.1F. 20.3 68.i 19.5 67 21.5 71 18,7 66 deg. deg. 11.4C. 51.5F. 17.0 63 12.3 54 12.2 54 11.9 54 311 314 621 544 184 5.0 11.2 8.1 7.1 7.7 11.4 46.3 50.0 38.6 14.0 17* 198 wiifE. If we now inquire how the meteorologica. circumstances of each of these five years influenced the production of our wine, we see at once that the mean temperature of the days which make up the period of the cultivation of the wine has a perceptible influence. The temperature of the summer was 17.3° C. (63.1° Fahr.) of the year which yielded the strongest wine, and only 14.7° C. (58.4° Fahr.) in 1833, the wine of which was scarcely drinkable. A hot summer is naturally /avorable to the vine : the mean heat of 1833 did not exceed 17|° C. (63|° Fahr. ;) with the exception o* this year, which must be regarded as one of the very worst, thi> three favorable summers, 1834, 35, and 36, show a mean tempera- ture of about 20° C. (68° Fahr.) It is not, however, with the warm- est summer that we find the strongest wine to correspond. Besides the sustained heat, which is necessary during the whole year's growth of the vine, it would appear that a mild autumn was a con- dition necessary to the perfect ripening of the grapes : this is one of the essential conditions. We see, in fact, that in 1834, the months of September and October presented the extraordinary temperature of 17° C, (62.6° Fahr.,) while in 1833, the temperature of the same months did not rise higher than 11.4° C. (51.5° Fahr.) I shall here add, that the year 1811, so remarkable over Europe for the quantity and the excellence of its wines, was distinguished by the high temperature of the early part of its autumn ; we find, in fact, from the excellent series of observations with which M. Herren- schneider has presented Alsace, that in this year, after a summer the mean temperature of which was 19.6° C. (67.8° Fahr.,) the heat of the months of September and October was maintained at 15° C, (59° Fahr.,) the usual temperature of the months of September and October not being higher than about 11.5° C. (52.7° Fahr.) If we deduct from these observations the years 1833 and 1837, which were decidedly bad, it seems that we must conclude that me- teorological influences have a greater eflfect upon the quality of wines, than upon the whole quantity of alcohol formed ; thus, al- though the wine of 1836 was very inferior to that of 1834, it actual- ly yielded a larger proportion of alcohol from the acre. In Alsace, in order that a year may be favorable to the vine, the temperature of those months during which the plant is alive must be sensibly superior to the mean : a fact which appears from M. Herrenschneider's long series of observations. In a climate where the vine requires such a condition to succeed, it is obvious that its cultivation can never be advantageous ; and this, in fact, is the case • the cultivation of the wine would, indeed, be altogether ruinous, were it not for the circumstance that ti e value of wine increased in a much greater ratio than its quality, so that one good year often in- demnifies the grower for many bad years. Another consideration is this, that the vine, like the olive, grows and thrives in situations where it would be difficuU to put any thing else. The produce of a vineyard also depends upon its age ; and it would be curious to examine the progressive increase of the quanti- ty of wiRe yielded. This information I am abJe to give in connec- WINE. 190 tion with a vineyard established in Flanders; I only regret that I have no means of presenting parallel observations from a countiy more favorable to the vine. The vineyard of Schmalzberg was planted in 1822, with new cuttings from France, and from the borders of the Rhine. The vines are trained as espaliers, and are now rather more than four feet in height. The vineyard began to yield wine in 1825, and the following table shows the results in the successive years up to 1837 : Years. Wine per Acre in Gallons. Years. Wine per Acre la Gallons. 1825 68.75 1832 209.9 1826 192.0 1833 311.6 1827 0.0 1834 413.4 1828 115.0 1835 620.0 1829 55.9 1836 544.5 1830 . 0.0 1837 184.4 1831 153.0 The mean quantity of wine furnished by this vineyard from the date of its plantation, is 224^ gallons per acre. M. Villeneuve reckons the mean produce of many vineyards in the southwest of France at from about 146 to 192 gallons per acre, considerably less consequently than our vineyard at Schmalzberg ; and official docu- ments, while they give the mean produce of the vine for the whole of France as 170.9 gallons per acre, state the whole of the wine produced over the country at 976,906,414 gallons. From documents recently published, the whole produce of the vineyards of the German States brought to market appears to be 59,180,000 gallons. Pulque. This is a vinous liquor, indigenous to Mexico and some parts of Peru, and is prepared from the sap of the Agave Americana. When this plant is about to flower, a hole is made into the upper part of its stem, which by and by becomes filled with juice, and is removed two or three times in the course of the twenty-four hours ; this sap is very sweet, runs quickly into fermentation, and yields the liquor called pulque. The flow of sap continues for two or three moB :hs, and a single plant will yield from six to eight quarts per day. In the neighborhood of a large town, which ensures a ready sale for the produce, a plantation of Agave is one of the most pro- fitable possessions ; in the neighborhood of Cholula there are singia plantations which are worth from jG8,000 to jCl2,000. 200 SOIL. CHAPTER ;V. OF SOILS. The solid mass of our earth does not everywhere present the same physical characters, or the same chemical composition. In traversing a mountainous country of any extent, we seldom fail to observe a notable difference in the nature and relative position of the rocks which compose it ; the idea which forces itself upon the mind in such circumstances is, that these mineral masses have not had the same origin, that they have been formed and placed in their several situations at distinct and often distant epochs. In examining attentively the inequalities whicn mark the surface of the globe, we soon perceive that those rocks which generally form the most elevated points, the axis or skeleton of mountain chains, result from the agglomeration or intimate mixture of different mineral substances which may be isolated and separately studied. These crystalline masses are frequently covered to a certain depth, and even completely concealed by rocks of more recent for- mation, the fragmentary elements of which proclaim their origin from the attrition or breaking down of the strata which support them. The regular stratification of these superimposed rocks, the configuration of their minute particles, the remains of organized beings which are found in them, proclaim them to be deposites which have taken place successively, and from the ocean. The formation of the crystalline rocks probably dates from the period at which the crust of the globe became solid. These elements, intimately mingled by fusion, combined as they cooled, according to the laws of affinity, to constitute the mineral species which we encounter ; just as it hap- pens that mineral species, identical with those which we observe in nature, are produced and crystallize during the consolidation of cer- tain scoriae from our furnaces. The various circumstances which have accompanied the cooling o'' the crust of the globe, have doubtless occasioned the differences wnich we observe in the distribution of the minerals that enter into the composition of rocks. Thus granite and mica schist, which pre- sent so dissimilar a structure, are nevertheless, and very certainly, varieties of the same species, and contain quartz, felspar, and mica. In sienite,the mica is replaced by amphibolite, and in protogenite by talc. In trachite, a volcanic rock, both of older and more recent date, quartz is almost entirely wanting ; the amphibolite is replaced by pyroxenite, and the felspar which is encountered, is no longer identical in its chemical composition with that which enters into the constitution of granite. The limestone rock, which belongs to the same Plutonic epoch, is granular or saccharoid ; occasionally the intervention of magnesia makes it pass into iolomite. The sedimentary strata do not vary less io their composition. Ths OIL. 201 causes which segregated the rocks of igneous origin, appear to have destroyed or removed one or several of their elements before their new consolidation ; one of the most common deposites, sandstone or grit, is almost wholly composed of grains of quartz, amidst which particles of mica are frequently encountered ; but felspar is ex- tremely rare. In the oldest sedimentary strata of the series, as in the greywackes, the igneous elements are met with more complete, and less altered. The structure of the calcareous rocks of this epoch is often compact, clayey ; it becomes porous and friable in deposites of more recent date. The stratified rocks must have been deposited in parallel superim- posed layers, and these strata, horizontal in the beginning, have been forced into the inclined and perpendicular positions which they now occupy by the tumefaction or rising of the masses upon which they rest. The organic remains which they present, frequently in such quantity, proclaim that in the period when the revolutions of the globe took place that gave them birth, there were already animated beings and plants growing upon the surface of the earth. The pro- duction of sedimentary strata, is an obvious proof that the igneous rocks of which they are the product, must have been segregated, so as to form beds of gravel, and sand, and clay. The elements of all stratified rocks must necessarily have passed through these different stages before the powerful causes which consolidated them, of the nature of which we cannot now form an estimate, came into play. The disintegration of the crystalline igneous rocks proceeds under our eyes, as it were, from the combined actions of water and the at- mosphere. Water, by reason of its fluidity, penetrates the masses of rocks that are at all porous ; it filters into their fissures. If the tempera- ture now fall, and the water comes to congeal, it separates by its dilatation the molecules of the mineral from one another, destroys their cohesion, and produces clefts which slowly reduce the hardest rocks to fragments, and then to powder. During the frozen state^ the ice may serve as a cement, and connect the disintegrated parti- cles ; but with the thaw, the slightest force, currents of water, the mere effect of weight, suffices to carry the fragments to the bottom of the valley, and the rubbing and motion to which these fragments of rocks are exposed in torrents, tend to break them still smaller, and to reduce them to sand. The quantity of earthy matter brought down by streams and rivers, is coripiderable : an idea may be formed of it from the thickness of the slime or mud deposited by a river which has overflowed its banks In many situations, the arable soil is either formed entirely, or is powerfully ameliorated by such alluvial deposites. The fertilizing powers of the mud of the Nile are well known ; according to Shaw, the waters of this river carry with them about the 132d part of their vol- ume ; those of the Rhine, at the periods of its great increase, bring down more than the 100th part ; and Dr. Barrow, from observations made in China, estimates at the 200th part of the volume of the mass of iiuidi the mud and slime which are cariied towards the sea by tho 202 SOIL. Yellow river. These fluviatile deposites accumulate £t vhe mouths of great rivers, and gradually encroach upon the ocean ; ihis is very conspicuous, for example, at the mouths of the Elbe, where, at the turn of the tide,' when there is an interval of calm, the earthy mat- ters which are held in suspension are precipitated, and a sediment results, which is thrown up by the next waves upon the beach. By these successive deposites, the beach rises gradually, and an extensive alluvium is formed which remains dry at neap and ordinary tides. These new lands, the fertility of which is truly surprising, constitute the polders of whicl ihe Dutch make so much. During spring tides, and storms from particular quarters, these polders would of course be all submerged, had not the active industry of the inhabit- ants raised dykes, which successfully oppose the waters of the ocean. Besides the mechanical causes of the destruction of rocks al- ready quoted, there is a chemical action depending upon meteoro- logical influences, which exerts a powerful influence upon the con- stituent elements of crystalline rocks. Felspar, amphibolite, mica, and the protoxide of iron suffer decomposition in certain circum- stances with surprising rapidity, without our being able to foresee, and still less to explain, this singular tendency to destruction. In granite, for example, the felspar and the mica lose their vitreous and crystalline state, they become friable, earthy, and are trans- formed into an argillaceous substance, which is known in the arts under the name of kaoline, and which is extensively used m the manufacture of porcelain ; amphibolite, and pyroxenite, undergo an alteration of the same kind. In these minerals the protoxide of iron passes to the state of the maximum of oxidation. The air and moisture appear to exert a great influence upon this alteration, which frequently extends to a great depth, as we see in the beds of porce- lain earth, which are worked in various granite districts, and as I have myself ascertained, in a bed of decomposed syenitic porphyry where there are very extensive subterraneous works. In these works, which are carried on in auriferous strata, the alteration in the felspar and amphibolite can be followed to a depth of nearly 330 feet. In the midst of the rocks so changed, we every here and there meet with masses which have resisted the decomposing action, and still possess all their original hardness and freshness. Historical monuments also show us unalterable granites ; such is that, for in- stance, which now forms the obelisk ir/ the square of San Giovanni di I^aterano at Rome, and which was cut at Siena, under the reign of a king of Thebes, thirteen hundred years before the Christian era. Such is further the obelisk of the Place of St. Peter, which was consecrated to the sun by a son of Sesostris more than three thou- sand years ago. The schists, by reason of their structure, wear away with much greater facility. Calcareous rocks resist atmcvpherical agencies somewhat better ; but their softness in general suffers them to be readily attacked by mechanical causes, and water even acts upon hem as a sdveat through the medium of the carbonic acid which SOIL. 203 it always contains. The resistance of the gre}Wackes, and of the sandstones depends in a great measure ou the nature and cohesion of the cement which unites their particles; their power of resisting, however, is generally inconsiderable, and these rocks fall down pretty rapidly into sandy soils. The modifications experienced hy the constituent minerals of rocky masses, do not happen solely from changes in the molecular state of their elements ; their chemical nature is further deeply changed, and some of their original principles disappear. The fel- spars, for example, into the constitution of which potash and soda enter, abandon almost the whole of these alkalies, in passing into the state of kaoline. This is made manifest by a comparison of the analyses of the mineral in its two states. Besides the alkali which is lost, we also perceive that in kaoline, the proportion of alumen relatively to that of silica, is much greater than in the undecomposed felspar, a fact which, according to M. Berthier, demonstrates that the alkali is removed in the state of silicate. The final result of the disintegration of rocks, and of the decom- position of the minerals which enter into their constitution, is the formation of those alluviums which occupy the slopes of mountains that are not too steep, the bottoms of valleys, and the most extensive plains. These deposites, however formed, whether of stones, peb- bles, gravel, sand, or clay, may become the basis of a vegetable soil, if they are only sufficiently loose and moist. Vegetation of any kind succeeds upon them at first with difficulty. Plants which by their nature live in a great measure at the expense of the atmosphere, and whick ask from the earth little or nothing more than a support, fix themselves there when the climate permits. Cactuses and fleshy plants take root in sands ; mimosas, the broom, the furze, &c., show themselves upon gravels. These plants grow, and after their death, either in part or wholly, leave a debris which becomes profitable to succeeding generations of vegetables. Organic matter accumulates in the course of ages, even in the most ungrateful soils in this way, and by these repeated additions they become less and less sterile. It is probable that the virgin forests of the new world have thus supplied the wonderful quantity of vegetable mould, in which the present generation of trees is rooted. At Lavega de Supia, in South America, the slipping of a porphyritic mountain covered completely with its debris, to the extent of nearly half a league, the rich plan- tations of sugar-cane which were there established. Ten years af- terwards I saw the blocks of porphyry shadowed by thick groves of mimosas ; and the time perchance is not very remote when this new forest will be cleared away, and the stony soil, enriched with its spoils, will be restored to the husbandman. The chemical composition of the earth, adapted for vegetation, must of course participate in the nature of the rocks and substrata from which it is derived ; and the elements which enter into the constitution of mineral species ought to be found in the soils, which, •y the effect of time or human industry, may serve for the repro- duction of regetables. It is on this account that it becomes inter* 204 SOIL. esting to know the composition of the minerals which are the most abundantly dispersed in the solid mass of the globe. The solid part of our planet, as is well known, occupies but one third of its whole surface. The ocean occupies two-thirds, and the majority of the rocks of sedimentary formation must have been pri- marily deposited at the bottom of the sea. These rocks will there- fore be apt to contain the saline substances which are met with in sea-water, and it is a fact that many of the secondary sandstones show unequivocal traces of these substances. Deltas and low downs, left by the ocean, are constantly being brought under tillage, and the fierce winds of the sea frequently carry saline matters to vast dis- tances, even to the centre of great continents; lastly, .as we shall see by and by, the ocean supplies agriculture with powerful manures. Analysis shows that sea-water contains, besides chloride of sodium or common salt, hydrochlorate of magnesia, sulphate of snd^ sul- phate of magnesia, sulphate of lime, carbonate of lime, caroonate of magnesia, and a quantity of carbonic acid, to which must be added the substances discovered in the mother waters of salt marshes, and which occur with reference to the others in quantities so small as to escape direct analyses of any moderate portions of sea-water : these substances are iodides, bromides, and certain ammoniacal salts. The minerals most generally found in rocks are quartz, felspar, mica, amphibolite, pyroxenite, talc, serpentine, and diallage. Quartz is frequently composed of silica nearly in a state of purity ; but I may save time by presenting in a single table the composition of the principal mineral species such as we find it indicated by the best chemical analysts : Minerals. COMPOSITION. 1 1 Alu- mina. Lime. Mag- nesia. 1 1 1 5^ III 5^' •U i^ ■^ i Felspar of Lomnitz .... Ditto Domite Ditto Albite of Finland Ditto Albite of Arendul 66.8 61.0 08.0 68.7 42 0 48.5 45.7 54.6 54.9 42.3 43.1 47.2 58.2 62.0 17.5 19.2 19.6 199 16.1 33.9 12.2 0.2 0.3 3.7 traces 1.3 0.7 13.8 24.9 23.6 0.5 13.1 1.6 traces 26.0 18.8 18.0 16.5 44.2 40.4 24.4 33.2 30.5 12.0 11.5 7.6 11.3 2.8 11.1 9.1 0.8 4.2 0.2 0.3 4.9 7.3 1.8 4.4 0.2 1.2 7.4 4.6 2.5 0.5 traces 1.3 0.2 2.0 0.4 0.7 1.5 2.0 3.0 1.3.3 12.5 3.2 3.5 0.5 Mica from the U. States Amphibolite of Pargas . White Pyroxenite Ditto, another kind .... Spezian Diallage Talc from St. Bernard. . Ditto from St Gothard. . If we now compare the analyses of the ashes of vegetables which we have already given with those just indicated, we see that the mineral substances which meet us in plants ilsc exist in the soil in dependenlly of any addition from manure. We nay therefore lay jl SOIL. 205 down as a principle that the mineral substances encountered in vege- tables are obtained in the- soil, and that tlie whole of these substan'ces come from rocks which form the solid crust of our planet. I ought, however, to observe in this place that the phosphates, which are so constantly present in plants that it is to be presumed they are essen- tial to their orijanization, do not figure among the elements of crys- talline rocks ; we only meet with phosphoric acid in the strata of a more recent geological epoch, — strata the formation of which has in- deed followed the appearance of organized beings ; so that it would be quite fair to mamtam that this acid had been introduced intc those new strata by the animated beings which are buried in them. Still the phosphatfes are by no means wanting in the rocks of igne- ous origin. In metalliferous strata, to quote those of more common occurrence only, we find phosphate of lead, of copper, of manganese, and of lime ; it is even difficult to discover a ferruginous mineral which does not contain a larger or smaller dose of phosphoric acid. And I must here add, that if phosphoric acid has been rarely indi- cated as a constituent of mineral substances, this is by no means from its uniform absence there, but because it escaped the researches of the analyst, in the same way as iodine and bromine for a long time escaped notice in all the analyses that were made of sea-water. Chemists, in fact, only discover those bodies readily which exist in some very appreciable quantity in the compounds they examine. The substances whose presence is not foreseen, those which only enter in extremely small quantity into a mineral, are apt to pass the eyes of even the most skilful and conscientious unperceived. The ashes of every vegetable examined up to the present time show us phosphates, and yet these salts have never been detected in any of the analyses of saps (not very numerous it is true) which we possess ; it is, nevertheless, all but certain that the sap must contain phosphoric acid in some state of combination or another. Thaer compares the soil in husbandry to the raw material upon which the industry of the manufacturer is exercised ; the comparison would, perhaps, be more exact were the soil likened to the mechani- cal agents he uses ; and, in fact, even as the prosperity of manufac- tures and the perfection of their produce depend upon the perfection of the machinery employed, so are the quality and the quantity of crops connected in the most intimate manner with the quality of the soil. The highest skill of the husbandman, even under a favorable climate, and otherwise in the most advantageous circumstances, may all be made nugatory by the incessantly renewed difficulties which meet him in a barren soil. To be truly fit for agriculture the earth ought to present several essential qualities ; a soil, for instance, must be sufficiently open, sufficiently loose, to permit the roots of plants to penetrate it, and to prevent the water from stagnating upon it. The matter of which it is composed must, further, be of such a kind that the air may insinu- ate itself into it and be renewed, without, however, too rapid a des- iccation following. A great deal has been written since Bergman's time upon th« 18 206 SOIL SAND AND CLAY. chemical composition of soils Chemists of great talent have made mafny complete analyses of soil ; noted for their fertility ; still practical agriculture has hitherto deriv^id very slender benefits from labors of this kind. The reason of this is very simple ; the qualities which we esteem in a workable soil depend almost exclusively upon the me- chanical mixture of its elements ; we are much less interested in its chemical composition than in this; so that simple washing, which shows the relations between the sand and the clay, tells, of itself, much more that is important to us than an elaborate chemical analysis. The quality of an arable soil depends essentially on the association of these two matters. Sand, whether it be silicious, calcareous, or felspathic, always renders a soil friable, permeable, loose ; it facili- tates the access of the air and the drainage of the water, and its in- fluence is more or less favorable as it exists in the state of minute subdivision, or in the state of coarse sand or of gravel. Clay possesses physical properties entirely opposed to those of sand ; united with water it forms an adhesive plastic paste, which, once moistened, becomes almost impermeable. With such charac- ters, it will easily be conceived how it is impossible to work to ad- vantage a soil that is entirely argillaceous. The proper character, or, if you will, the quality of a soil, depends, then, essentially on the element which predominates in the mixture of sand and clay that composes it ; and between the two extremes, which are alike un- favorable to vegetation, viz., the completely sandy soil and the un- mixed clay, all the other varieties, all the intermediate shades can be placed. It is rare, indeed, that arable soils are formed solely of sand and clay : not to mention certain saline substances which are generally encountered, although in small quantity, we always find the remains of organic matters, remains which constitute that part of a soil which has been designated under the somewhat vague name of humus. Although a soil which is entirely without humus may be cultivated by calling in the aid of manure, and as humus, consequent- ly, need not be regarded as indispensable, still this matter generally enters, in certain proportions, into the constitution of soils. The soils of forest lands contain a large quantity of it, and some soils are mentioned which are very rich in this substance, and which yield abundant irops of grain for ages, and with very little attention. In examining a soil, attention ought to be directed, 1st, to the sand, 2d, to the clay, 3d, to the humus which it contains. It would, further, be useful to inquire particularly in regard to certain other principles which exert an unquestionable influence upon vegetation, such as certain alkaline and earthy salts. Vegetable earth dried in the air until it becomes quite friable may, nevertheless, still retain a considerable quantity of water, and which can only be dissipated by the assistance of a somewhat high temperature. It is therefore proper, in the first instance, to bring all the soils which it is proposed to examine comparatively, to one constant degree of dryness. The best and quickest way ff drying such a substance as a portion of soil, is to make use of the oil-bath ; a qiantity of oil contained in a copper vessel is readily kept at ai SOIL ITS ANALYSIS. 207 almost uniform temperature by means of a lamp. A thermometer plunged in the bath shows the degree to which it is heated ; the substance to be dried is put into a glass tube of no great depth, and sufficiently wide ; or into a porcelain or silver capsule, if the quantity to be operated upon be somewhat considerable : these tubes, or ves- sels, are placed in the oil so as to be immersed in it to about two- thirds of their height. For the desiccation of soils, the temperature may be carried to 150" or 160° C, (334° or 352° F.) The weight of the vessel is first accurately taken, and a given weight of the matter to be dried is then thrown into it, after which it is exposed to the action of the bath. If we operate upon from 600 to 700 grains, the drying must be continued during two or three hours; the weight of the capsule with its contents, after having been wiped thoroughly clean, is then taken. It is placed anew in the bath, and its weight is taken a second time after an interval of fifteen or twenty minutes ; if the weight has not diminished, it is a proof that the drying was complete at the time of the first trial. In the contrary case, the operation must be continued, and no drying must be held terminated, until two consecutive weighings* made at an interval of from fifteen to twenty minutes, show any thing more than a very trifling differ- ence. Davy points out another and much more simple method, which, although far from accurate, may, nevertheless, suffice Id many general trials. The soil to be dried is put into a porcelain capsule heated by a lamp, and a thermometer, with which the mass may be stirred, is placed in its middle, and shows the temperature at each moment. Lastly, in many circumstances the marine bath may suffice. In drying, the main point is to do so at a known tem- perature, and one which may be reproduced; for the absolute desic cation of a quantity of soil could not be accomplished except at a heat close upon redness, and this would, of course, alter or destroy the organic matters it contains. The organic matters contained in ordinary soils consist, in part, of pieces of straw and of roots, which are usually separated by sifting the earth through a hair sieve ; the gravel and stones which the soil contains are separated in the same way. The earth sifted is now washed. To accomplish this, it is intro duced into a matrass, w hh three or four times its bulk of hot distilled water, the whole is shaken well for a. time, the matrass is left to stand for a moment, and then the liquid is decanted into a wide porcelain capsule. The washing is continued, fresh quantities of water being added each time, until the whole of the clay has been re- moved, which is known by the fluid becoming clear very speedily ; the sand which remains, is then washed out into another capsule. The argillaceous particles, or the clay and all the matters held in suspension in the water, are thrown upon a filter and dried ; the desiccation is completed by the same process, and under the same circumstances as that of the soil had been. The sand is, in like manner, dried with the same care. If we would ascertain the nature and quantity of the soluble salts^ the whole of the water used in the washing must be put togcthei 208 SOIL ITS ANALYSIS. and evaporated, which may be dona upon a sand-bath. The evapo* ration is pushed to dryness, and thi salts that remain, having been previously weighed, are thrown into a small platinum capsule, in which they are heated to a dull red by means of a spirit-lamp, in order to burn out the organic salts, and thus distinguish, by means of a subsequent weighing, between them and the inorganic salts. The sand may be silicious or calcareous. The presence of car- bonate of lime is readily ascertained by treating it with an acid which will form a soluble salt with lime, such as hydrochloric, nitric, or acetic acid. Effervescence shows the presence of a carbonate ; the quantity of which may be estimated by weighing the sand dry before and after its treatment with the acid, particular care being of course taken to wash the remaining sand well before setting it to dry. This, however, is an operation of little use, the great object is to as- certain the quantity of sandy matter. Had we a particular interest in ascertaining the presence and estimating the quantity of the earthy carbonates contained in a sample of soil, it would be advisable to make a special inquiry, inasmuch as the finely divided calcareous earth being carried off along with the clay in the course of the wash- ing, the sand obtained never contains the whole of the carbonate of lime. The argillaceous matter procured by the washing is far from being pure clay : it contains a quantity of extremely fine sand, particles of calcareous earth, and if the soil contain humus, the more delicate particles of this substance will also be included. To determine the quantity of humus, recourse is generally had to its destruction by heat. A known weight of dried earth is heated to redness in a capsule, and constantly stirred for a time, and when no more of those brilliant points or sparks, which are indications of the combustion of carbon, are observed, it is set to cool and then weighed. This is the method which has been generally followed by Davy and others. It would be difficult to find a method more con- venient than this, but it is unfortunntely very inaccurate. Soils dried at a temperature at which organic matter, such as humus, &c., begins to change, still retain a considerable quantity of water in union with the clay. This water is disengaged at the red heat required for the combustion of the organic matters ; and as their quantity is estimated by the loss of weight on the subsequent weighing, it is ob- vious that the loss from the dissipation of water is added to that which proceeds from the destruction of the humus. It is undoubted- ly to this cause of error that we must ascribe the large proportions of humus mentioned in the soils examined by Thaer and Einhoff ; it is therefore better to restrict the examination to the determination of the presence or absence of humus than to attempt to ascertain its quantity by so imperfect a method. Priestley and Arthur Young were already aware that a more deli- cate operation was required to determine the quantity of humus. They recommend calcination of the soil in a close vessel, and that the gaseous products should be collected. This mode of proceeding, however, would have but slight advantages over that which I hava SOIL ITS ANALYSIS. 209 just criticised, inasmuch as the volume of gas collected varies with every difference of heat employed. The only method in my opinion which we have of learning the quantity of humus, of organic debris, which is contained in a soil, is that of an elementary analysis. It is by burning a known quanti- ty of earth thoroughly dried by means of the oxide of copper, aided by a current of oxygen, that the carbon and hydrogen may be de- termined. But the most important point of all is to ascertain the amount of azote included in the organic remains of the soil ; and we have happily precise means in our elementary analysis of ascertain- ing the quantity of azote, from which the amount of azotized organic matter may be accurately inferred. It may be very useful to determine the presence or absence of carbonate of lime in a so 1 ; this knowledge would of course guide us in our applications of lime, marl, &c. Two modes may be em- ployed for this purpose ; 1st. the soil may be treated by nitric acid slightly diluted with water. Any effervescence will denote the presence, in all probability, of carbonate of lime. I say in all proba- bility, because the disengagement of carbonic acid gas under such circumstances generally indicates the presence of carbonate of lime ; it is not, however, a special character, because the disengagement may be due to the presence of any other carbonate. It is well to boil the acid solution upon the sample of soil that is analyzed ; the part which is not dissolved is thrown upon a filter and washed with distilled or rain-water boiling hot. Into the clear filtered liquor which results from all the portions of water used in the washing, a little ammonia is added ; if any precipitate falls, it is collected upon a filter and washed : to the new liquors obtained by this washing, a solution of oxalate of ammonia is added. If there be any lime pres- ent, it is thrown down in the state of oxalate, and the liquor, having been left at rest for five or six hours, becomes completely clear ; the addition of a few drops of the solution of oxalate of ammonia to this clear fluid satisfies us whether the whole of the lime has been pre- cipitated or not. The oxalate of lime is received upon a filter, wash- ed, and dried ; it is then thrown into a platinum capsule along with the piece of filtering paper upon which it was collected, and is heat- ed to a dull red, until the paper of the filter is completely consumed and no further trace of carbon appears ; the capsule is then taken from the fire or from over the spirit lamp, and cooled ; when cold, the matter which it contains is moistened with a concentrated solu- tion of carbonate of ammonia. The matter is then dried, great care being taken that nothing is lost by particles flying out, and the capsule is again heated to a dull red ; when cold, it is weighed accurately, and the quantity of matter contained then becomes known. This matter is carbonate of lime, 100 of which represent 56.3 of lime and 43.7 of carbonic acid. I have said that in arable soil other carbonates may be met with be- sides that of lime ; calcareous soils, for example, very commonly contain carbonate of magnesia. If we would ascertain the quantity of this earth, the mode of proceeding which I have just particularly 18* 210 SOIL ITS ANALYSIS. indicated enables us to do so ; we have but to evaporate the liquit'. from which the oxalate of lime was deposited, and then to calcine the product of the evaporation in a platinum capsule. Any nitrate of magnesia which may exist there will be decomposed at a dull red heat, as well as any oxalate of ammonia which may have resulted from ammonia added in excess. By treating the residue of the cal- cination with water we obtain the magnesia, which being washed. has only to be calcined and its weight ascertained by weighing. 2d. If we would be ;ontent with a simple approximation, we may judge of the quantity oi calcareous carbonate contained in a vegeta- ble soil by measuring the quantity of carbonic acid which we obtain from it. We counterpoise upon the scale of a balance a phial con- taining some diluted nitric acid ; we weigh a certain quantity of the earth to be analyzed, and this is added by degrees to the acid. If the earth contains carbonates, effervescence ensues. The liquid is shaken with care, and having waited a few minutes in order to let the carbonic acid which is mixed with the air of the phial escape, the phial with its contents is again put into the balance. If there has been no disengagement of carbonic acid, it is clear that to restore the equilibrium it will be sufficient to add to the opposite scale the weight of the earth which was put into the phial ; whatever is want- ing of this weight represents precisely the weight of carbonic acid which has been disengaged. Presuming this acid to have been com- bined with lime, the weight of the calcareous carbonate can be cal- culated exactly. Sulphate of lime is an occasional constituent of soils ; to ascertain its presence and quantity, the following is the method of procedure : The earth well pulverized is first roasted for a considerable time in a crucible or platinum capsule, until all the organic matter is com- pletely destroyed ; it is advisable to operate on about 100 grammes, or about 3.2 ounces troy of soil. After this operation the matter is boiled in 4 or 5 times its weight of distilled water for some time ; water being added to replace that which is dissipated by evaporation ; we then filter, re-wash, and having added all the liquors, we evapor- ate in a capsule until the volume of the liquid is reduced to a few drachms. To the liquid thus concentrated we add its own bulk of alcohol. If the solution contains sulphate of lime it will be deposit- ed, and the deposite being received upon a filter and washed with weak alcohol, its weight is taken after having been dried and calcined. This salt is frequently seen deposited in the form of fine colorless needles on the cooling of the sufficiently concentrated solution ; but the addition of alcohol is always useful, because the sulphate of lime, which is not very soluble in water, is altogether insoluble in weak spirit, which on the contrary dissolves certain alkaline and earthy salts whose presence would interfere with the accuracy of the result. It may be matter of great moment to determine the existence and the quantity of phosphates contained in a soil destined for cultiva- tion. Although the search for phosphoric acid may perhaps require a certain familiarity with chemical analysis, I shall neverthelest SOIL — ITS ANALYSIS. 211 indicate the method of procedure. It is much to be desired that en- ligfhtened agriculturists should not remain strangers to manipulations of this kind. The soil to be analyzed must be first deprived of all organic mat- ters by calcination. After having reduced it to a very fine powder it is to be boiled for about an hour with three or four times its weight of nitric or hydrochloric acid. The solution is then diluted with distilled water, and filtered ; the matter which remains upon the filter is generally silica or alumina which has escaped the action of the acid. After having reduced the washings by evaporation, and added them to the acid liquor, ammonia in solution is poured in. Taking the simplest instance, the precipitate which falls upon the addition of this alkali may contain, 1st, phosphoric acid in union with the peroxide of iron and lime ; 2d. oxide of iron and of man- ganese ; 3d. silica. This precipitate, which is usually of a gelatin- ous appearance, is received upon a filter, well washed and dried, when the precipitate is readily detached from the filter. Tt is thrown into a platinum capsule which is raised to a white heat, after vi'hich the weight of the residue is taken. The precipitate after calcina- tion is thrown into a small glass matrass, and dissolved by hot hy- drochloric acid. If there is any silica undissolved, its quantity is merely estimated, if it be very small ; if it be a larger quantity, it is to be collected upon a filter and weighed. To the new acid solution, about three times its weight of alcohol is added : the mixture is shaken, and pure sulphuric acid is then instilled drop by drop until there is no longer any precipitate. The precipitate is sulphate of lime, which is thrown upon a filter, where it is washed with diluted alcohol ; it is then dried, calcined, and the weight of the sulphate of lime obtained, permits us to calculate that of the lime which formed part of the precipitate throv^'n down by the ammonia in the first in- stance. 100 of sulphate of lime are equivalent to 41.5 of pure lime. The alcoholic liquor is concentrated in order to expel the spirit ; as it is acid, it is saturated with ammonia until a slight precipitate begins to be formed, which is not redissolved upon shaking the mixture. A few drops of the hydrosulphate of ammonia are then added, upon which the iron and the manganese fall in the state of sulphurets. As a part of the metals has been precipitated in the state of oxide by the ammonia added in the hydrosulphate, it is well to digest for eight or ten hours, because the hydrosulphate of am- monia always ends by changing the metals present into sulphurets, which being washed, dried, and reduced to the state of oxides by calcination in a platinum capsule, are weighed. If the first ammoniacal precipitate did not contain phosphoric acid, its weight ought to be reproduced by adding that of the lime to that of the metallic oxides proceeding from the calcination of the sul- phurets. Any loss which is noted after this, is due, if the process has been well conducted, to phosphoric acid, which had not been collected, but which has remained in the state of phosphate of am- monia in the liquid treated by the hydrosulphate. To determine with precision the presence of phosphoric acid, the liquid in questioj* 212 SOIL ITS ANALYSIS. must be evaporated to dryness, and the residue heated strongly in a platinum capsule. After the dissipation and decomposition of the ammoniacal salts, there remains watery phosphoric acid, distinguish- able by its powerful acid reaction, its sirupy consistence, and its fixity. By way of example, I shall give the results obtained in an analysis of this kind : From the acid Hquor, ammonia threw down of : grs. troy. Ph:)sphates and metaliic oxides .... 8.012 These gave of sulphate of Ume .... 8.768 Equivalent to Ume . . . . . . . 3.612 Hydrosiilphate of ammonia caused a precipitate, which, calcined, gave of metallic oxides . . 1.620 Lime and metallic oxides together . . 5.233 Difference due to phosphoric acid . . 2.789 The analysis for phosphoric acid may be simplified by employing a process conceived by M. Berthier, and which is founded upon the strong affinity of this acid for the peroxide of iron and the insolu- bility of the phosphate of the peroxide of iron in dilute acetic acid. If to a fluid containing at once phosphoric acid, lime, peroxide of iron, alumina, and magnesia in solution, ammonia be added, the pre- cipitate will contain the whole of the phosphoric acid. The acid will be in great part combined in the state of phosphate of iron, if the peroxide of iron be in quantity more than sufficient to neutralize it, a condition which must be frequently expected in an arable soil ; however, to make sure of this point it is well to add a certain quantity of the peroxide of iron to the soil which is to be analyzed. Besides the phosphate of iron, the precipitate may contain phosphate of lime, phosphate of alumina, and certainly ammoniacal magnesian phos- phate. Finally, with these phosphates will be found associated alumina and oxide of iron, the latter especially if it has been intro- duced in excess. The precipitate collected upon a filter and wash- ed, must then be treated with dilute acetic acid, which will dissolve the lime, the magnesia, and the excess of the oxides of iron and alumina, and there will remain phosphate of iron or phosphate of alumina, because the latter salt is as insoluble as the former in acetic acid. Whenever the precipitate in question, therefore, leaves a residue which is insoluble in vinegar, the presence of phosphoric acid may be inferred ; this residue may consist of basic phosphates of iron or alumina, or of a mixture of the two salts, and no great error will be committed if one hundred parts of this residue, calcined, be assumed as representing fifty of phosphoric acid. The presence of silica in the precipitate insoluble in acetic acid may, however, lead to error. To make sure that the precipitate is formed by a phosphate it must be redissolved in hydrochloric acid, and the acid solution evaporated to dryness, so as to render the silica, which may exist in it, insoluble. By treating the residue with hy drochloric acid again, the phosphates alone will be dissolved. Th« SOIL — ITS ANALYSIS. 21$ presence of phosphoric acid may otherwise be determined by treat- ing the phosphate of iron in solution in the way which I have already indicated. From what precedes, it must be obvious that the most carefully conducted chemical analysis of a soil, only leads us to the discovery of certain principles which exist in very small quantity, althoug:i their action is unquestionably useful to vegetation. As to the de- termination of the relative quantities of sand and loam, this rests upon simple washing ; and a chemist would spend his time to very little purpose, in seeking by means of elementary analyses to determine the precise composition of these substances. The finest part car- ried off by the water will always show properties analogous to those of clay ; the sand, which is generally silicious, will exhibit the char- acters of quartz ; and the calcareous fragments, which are mixed with it, will exhibit those that belong to carbonate of lime. It will be sufficient then in connection with the mineral constitution of ara- ble soils, to expose very briefly the general properties of day or loam, of quartz, and of carbonate of lime, substances in fact which form the bases of all arable lands. Pure clay composed of silica, alumina, and water, does not contain these substances in the state of simple mixture. The inquiries of M. Berthierhave satisfactorily shown that clay is an hydrated silicate of alumina. When we re- move a portion of the alumina from clay, for example, by treating it with a strong acid, the silica which is set at liberty will dissolve in an alkaline solution, which would not be the case were the silica present in the state of quartzy sand, however fine. Pure clays are white, unctuous to the touch, stick to the tongue when dry, and when breathed upon give out an odor which is well known, and is commonly spoken of as the argillaceous odor. This property of dry clay to adhere to the tongue is owing to its avidity for water. It is known, in fact, that dry clay brought into contact with water, first swells, and finally mixes with it completely. Duly moistened it forms a tough and eminently plastic mass. Exposed to the air, moist clay, as it dries, shrinks considerably ; and if the drying be rapid, the mass cracks in all directions. It is to an action of this kind that we must ascribe the cracks and deep fissures which traverse our clayey soils in all directions during the continuance of great droughts. The constitutional water of clays is retained by a very powerful affinity, and does not separate under a red heat ; pure clay has a specific gravity of about 2.5; but the weight is frequently modified by the presence of foreign matter, for it contains sand, met»Hic oxides, carbonate of lime, carbonate of magnesia, and frequently even combustible substances from bitumen to plumbago, all of which admixtures of course modify the properties which are most highly esteemed in clays, such as fineness, whiteness, infusibility, &c. Quartz is abundantly distributed throughout nature, and is met with in very difl^erent states in the form of transparent colorless crysiais constituting rock crystals, as sand of different fineness; finally, in masses constituting true rocks. Quartz is the silica of 214 SOIL ITS ANALYSIS. chemists, and a compound, according to them, of oxygen and siliconi in the proportion, Berzelius says, of 100 of the radical to 108 of oxygen. Silica in a state of purity occurs in the form of a white powder, and having a density of 2.7. It is infusible in the most violent fur- nace, but it not only melts in the intense heat which results from the combustion of a mixture of hydrogen and oxygen gas, but it is even dissipated in vapor. As generally obtained, silica is held insoluble in water; still, when in a state of extreme subdivision, it is s«)luble ; and then its insolubility is probably not so absolute as is generally supposed, for M, Payen has found notable quantities in the water of the Artesian well of Grenelle, and in that of the Seine. Silica ex- ists especially in very appreciable quantity in certain hot springs where the presence of an alkaline substance favors its solution ; the water of the hot springs of Reikum in Iceland contain about Y75^oth parts of its weight of silica ; and the thermal spring of Las Trincheras, near Puerto Cabello, deposites abundant silicious concre- tions. The water of this latter spring, which is at the temperature of 210° F., besides silica contains a quantity of sulphurated hydro- gen gas, and traces of nitrogen gas. Rock crystal when colorless and transparent may be regarded as pure silica ; in the varieties of quartz which mineralogists designate as chalcedony, agate, opal, &c., the silica is combined with different mineral substances, particularly oxide of iron and of manganese, alumina, lime, and water. Carbonate of lime, considered as rock, belongs to every epoch in the geological series, and frequently constitutes extensive masses. When pure it is composed of lime 56.3, carbonic acid 43.7 ; and its density is then from 2.7 to 2.9. It dissolves with etfervescence without leaving any residue in hydrochloric or nitric acid. Exposed to a red heat its acid is disengaged, and quick-lime remains. Car- bonate of lime is insoluble in water, but it dissolves in very consid- erable quantity under the influence of carbonic acid gas. When such a solution is exposed to the air the acid escapes by degrees, and the carbonate is deposited, by which means those numerous deposites of carbonate of lime are produced, which we see constitu- ting tufas and stalactites. The solubility of carbonate of lime in water acidulated with carbonic acid, enables us to understand how plants should meet with this salt in the soil, inasmuch as rain-water always contains a little carbonic acid. The mineral substances which we have now studied, taken iso- latedly, would form an almost barren soil ; but by mixing them witii discretion a soil would be obtained, presenting all the essential con- ditions of fertility, which depend as it would seem much less on the chemical constitution of the elements of the soil than on their physi- cal properties, such as their faculty of imbibition, their density, their power of conducting heat, &c. It is unquestionably by studying these various properties that we come to form a precise idea of the causes which secure or exclude the qualities we require in arable poiis. This has been done very ably by M. Schiibler, and his admj- SPECIFIC GRAVITY OF SOIL. 215 rable paper will remain a model of one application of the sciences to agriculture.* The researches of M. Schiibler were directed to the mineral sub- stances vvhich are generally found in soils, viz : 1st. silicious sand; 2d. calcareous sand ; 3d. a sanely clay containing about y^^ths of sand ; 4th. a strong clay containing no more than about f^nl'hs of sand ; 5th. a still stronger clay containing no more than about ,-\^th of sand ; 6th. nearly pure clay ; 7th. chalk, or carbonate of lime in the pulverulent state ; 8th. humus ; 9th. gypsum ; 10th. light gar- den earth, black, friable, and fertile, and containing, in 100 parts, clay 52.4, quartzy sand 36.5, calcareous sand 1.8, calcareous earth 2.0, humus 7.3 ; Uth. an arable soil composed of clay 51.2, silicious sand 42.7, calcareous sand 0.4, calcareous earth 2.3, humus 3.4 ; and 12th. an arable soil taken from a valley near the Jura, contain- ing clay 33.3, silicious sand 63.0, calcareous sand 1.2, calcareous earth and humus 1.2, loss 1.3. The object of these inquiries was to ascertain, 1st. the specific gravity of soils ; 2d. their power of retaining water ; 3d. their consistency ; 4th. their aptitude to dry ; 5th, their disposition to contract while drying ; 6th. their hygrometric force ; 7th. their power of absorbing oxygen ; 8th. their faculty of retaining heat ; and 9th. their capacity to acquire temperature when exposed to the sun's rays. Specific gravity of soils. The weight of soils may be compared in the dry and pulverulent state, or in the humid state, or the spe- cific gravity of the particles which enter into their composition may be determined. This last information is easily obtained by the fol- lowing method : take a common ground stopper bottle, weigh it stoppered and full of distilled water ; let it then be emptied, in order that a known quantity of the soil, in the state of powder and quite dry, may be introduced into it. A quantity of water is now poured in, and the phial is shaken to secure the disengagement of all air bubbles ; the phial is then filled with distilled water, and when the upper part has become clear the stopper is replaced ; the phial is then wiped dry and weighed again. The difference between the weight of the phial full of water plus that of the matter, and the weight of the phial containing the matter and the water mixed, gives the weight of the water displaced by this matter. Thus : Weight of the phial full of water 60.0 Weight of the matter ••24.0 84.0 Weight of the phial containing the mingled earth and water — 74.4 Difference of water displaced 9.6 which is the weight of the volume of water equal to that of the matter introduced into the phial ; we have consequently for the spe- cific gravity of the earth ^-:|=2.5, the weight of the water having )}een taken as 1. • SIchiibler, Annals of French Agriculture, vol. xl. p. 122, 2d sories. 216 IMBIBING POWERS OF SOIL. ThU number represents the mean specific gravity of the isolatea particles of the powder which has been examined. J3ut we must not from this density pretend to deduce the weight of a particular volume of soil, a cubic foot or a cubic yard, for instance ; we should come to far too high a number. The weight of a given volume of earth must be determined immediately by ramming it into a mould or measure of a known capacity. From M. Schiibler's experiments it appears, 1st. that silicious and calcareous sandy soils are the heaviest of any ; 2d. that clayey soils are of least density ; 3d. that humus or mould is of much lower density than cl^y ; 4th. that a compound soil being generally by so much the heavier as it contains a larger proportion of sand, and so much the lighter as it contains a larger quantity of clay, of calcareous earth, and of humus, it is possible from the density of a soil to infer the nature of the principles which prevail in it. In the course of his experiments M. Schiibler found that artificial mixtures always gave higher densities than those that ought to have resulted from the- several densities of each of the sorts of substance which formed the mixture. Imbibition of water. The power which soils possess of retaining water or of resisting the too rapid dissipation of their moisture, is highly important in its influence upon their fertility. This faculty is measured comparatively in the following manner : a given quan- tity of soil is taken, say from 3 to 400 grains ; it is dried until it ceases to lose weight ; it is then made into a thin paste and thrown upon a moistened filter ; when it has ceased to drop it is weighed. The increase of weight is plainly due to the quantity of water re- tained by the soil, thus : Weight of the dry soil 300.0 Weight of the moistened filter • • 75.0 375.0 Weight of the filter and moistened earth ••525 Water absorbed 150 In the experiment quoted, 100 of dry earth absorbed or imbibed 60 of water. The following table contains the result of experi- ments made on the imbibing power of diflferent soils. Water absorbed by ' Kind of earth. 100 parts of the earth. Silicious sand • 25 Gypsum 27 Calcareous sand 29 Sandy clay 40 Strong clay 50 Sandy clay 70 Fine calcareous earth 85 ^ Humus 190 Garden earth 89 An arable soil 5£ Another arable soil 48 It appears, therefore, that the silicious and calcareous soils and the gypsum have the least affinity for water ; the clayey soil re- tained by so much the more as it contained a smaller quantity of sand ; the fine calcareous earth retained 15 per cent, more than the I CONSISTENCY OF SOIL. 217 pure clay ; while the calcareous sand retained 41 per cent. less. This fact proves how much the state of suhdivision must influence the physical properties of soils; and it is easily to be understood that in noting the presence of calcareous matter in an arable soil ■we are carefully to indicate the form and degree of subdivision in which it occurs ; humus, however, is the substance which shows itself most greedy of moisture, and we perceive from this fact where- fore soils rich in this principle have so strong an affinity for water. Consistence, tenacity, friability of soils. The consistence or tenacity of soils is an important property which agriculturists indi- cate when they speak of soils being strong or stiff, and light, the amount of power expended in ploughing being taken as a measure of these qualities. To compare different soils under the point of view of their tenacity in the dry state, M. Schiibler moulded various kinds, duly moistened, into equal and similar parallelopipeds. When these solids were completely dry, he placed either extremity upon a fixed support, and by means of the scale of a balance hung exactly from the middle of the prisms, he added weights gradually until they gave way ; the weight, supported by each parallel opiped immediately before it broke, expressed its tenacity. In working x damp soil we have not only to overcome its force of cohesion, but further and principally to get the better of its adhesion to our implements. This consideration led M. Schiibler to estimate, always comparatively, the power which it is necessary to expend in working soils of different descriptions. As the material which enters into the construction of agricultural instruments is in general iron and wood, he did no more than ascertain the disposition of the soil to adhere to these two substances. In the experiments, the results of which we shall immediately detail, two discs were employ- ed, one of iron, the other of beech-wood, having equal surfaces. The disc was connected with the extremity of the arm of a very delicate balance ; it was then brought into perfect contact with the moist soil, and when it adhered, the opposite scale of the balance was loaded until the adhesion was overcome. In experiments of this kind it is obviously indispensable that the soil in each instance should have the same degree of humidity; they were tried, consequently, at the point of saturation with water. Pure dry clay possessed the greatest tenacity, and its power was expressed by the number 100 ; the tenacity possessed by other mat- ters was then compared to that of pure clay. The following table exhibits the results of the two series of experiments, viz. those having reference to the tenacity and those having reference to the farce of cohesion. 10 218 TENACITY OF SOIL. Kind of ••il. TiMCity of «oiI, that of pure clay bein^ 100. Tenacity express- ed iu weight. Ccfie«ion in the mcisi stale. Verticil adhecioB to iran and to wood en a aurfa»« ofS.93r8quar« inches. Silicious sand Calcareous sand Fine calcareous earths Gypsum 0 0. 5.0 7.3 8.7 57.3 68.8 83.3 100.0 7.6 33.0 22.0 kil. 0. 0. 0.55 0.81 0.97 6.36 7.64 9.25 11.10 0.84 3.66 2.44 kil. 0.17 0.19 0.65 0.49 0.40 0.35 0.48 0.78 1.22 0.29 0.26 kil.« 0.19 0.20 0.71 0.53 0.42 0.40 0.52 0.86 1.32 0.34 0.28 0.27 Stiff clayey soil Garden earth Earth from Hoffwyll . . Earth from the Jura . . M. Schiibler finds, from his experiments, that a dry soil is very easily worked vi^hen its tenacity does not exceed 10, that of pure clay being 100 in the moist state. Soils are further worked with ease when their adherence to a surface 3.937 inches square is re- presented by a weight of from 0.15 to 0.30 kil. ; i. e. from 0.380 to 0.760, or nearly ^d to |ths of a lb. avoird. ; the latter term passed, the difliculty of working increases rapidly, and a very considerable force is required when the adherence to the same surface amounts to 0.70 kil. or 1 840 lbs. avoird. The tenacity of a wet soil is not, however, in the direct ratio of its faculty of imbibition. Loams and loose calcareous soils, which absorb much more water than clay, are nevertheless much less tena- cious ; and then water actually makes sandy soils stiffer than they are when dry. Every practical farmer knows how much more friable stiff wet soils become from the effects of frost. The water in expanding as it becomes solid pushes apart the molecules of the soil, and it is to this action that the advantages of autumn ploughing are with justice ascribed. M. Schiibler found that the cohesion of a stiff clay which was equal to 68 fell to 45, when before it was tried the clay was exposed to the frost. Disposition of the soil to become dry. The faculty of throwing off by evaporation any excess of water with which it may be charg- ed, is as essential to constitute a good soil as is that of retaining moisture in due proportions. Those soils which throw off too slow ly the excess of moisture they have acquired during the winter occasion much trouble to the husbandman. They are perfect]y un- workable in the spring, and consequently can only be sown veiy 4ate. M. Schiibler tried the retentive powers of the soil by the following method. A metallic disc, furnished with a narrow rim. was suspended to the «m of a balance. Over this disc, the soil tc * The abbreviate kil. In the above table signifies killogramme, a weight equal to 2.S lbs. avoirdupois. As the weights are principally interesting in their relations lo 90* aootber, it has not been thought necessary to reduce them to English weights. SHRINKING OF SOILS. 219 be tried and previously brought to the point of saturation with moist- ure, was spread as evenly as possible. The weight of the disc thus charged was noted, and it was weighed anew, after having been kept for four hours in a temperature of 18.75° cent. (65.75^ Fahr.) The weight of the water lost by evaporation was obtained by a second weighing; the complete desiccation of the soil was then completed in the stove. The following is the detail of one opera- tion : Weight of the moist earth 310 Weight after four hours' exposure to the air 260 Water evaporated 50 Weight of the moist earth 310 Weight after complete desiccation 200 Whole quantity of water contained in the soil tried ... 110 Thus 100 of water of imbibition lost 45.5 during exposure to the air for 4 hours at a temperature of about 66° Fahr. A more se- verely accurate method might readily be contrived, but that employ- ed by M. Schiibler appears sufficient for ordinary purposes. His results, in regard to the different kinds of soil he tried, are these : 100 parts of (he water contained in the soil lose Kinds of soil. in the course of 4 hours at 66 deor. Fahr. Silicioussand 88.4 Calcareous sand 75.9 Gypsum 71.7 Sandy clay 52.0 Stiffish clay 45.7 Stitfclay •. 34.9 P'ueclay 31.9 Calcareous soil 28.0 Humus 20.5 Garden earth 24.3 Arable soil of Hoffwyll 32.0 Arable soil of the Jura 40.1 Of all the substances examined, sand and gypsum are obviously those which allow the water to pass off most rapidly by evaporation. The calcareous or chalky soil again has a high retentive power ; but it varies much in different instances, apparently in consequence of different degrees of fineness ; it is however surpassed by humus, and the garden soil which was tried. Humus is therefore at the head of the list of substances in reference to retentive properties. All soils shrink more or less in drying, and form cracks, in the way already indicated ; the shrinking has been estimated by means of prisms of soils measured in the moist state, and after being dried in the shade : Kinds of soil. 100 parts cube shrink to. Carbonate of lime in fine powder 950 Sandy clay 940 Stiffish clay 911 Stiff clay 886 Pure clay 817 Humus 846 Garden earth 851 Arable soil of Hoffwyll 880 Arable soil of Jura 90S 220 UYGROMETRIC POWER OF SOILS. Gypsum, silicions, and calcareous siiid do not appeal in this table, because they do not shrink in drying The humus appears to have shrunk the most ; and dry humus is liable to swell in the same pro- portion when it is moistened. This property explains the obvious elevation of certain turfy or mossy soils at the period of the rains. Hygromelric property of soils. Agriculturists allow, that those soils which have the property of attracting moisture from the atmo- sphere are generally among the most fertile. This hygiometric property must not be confounded with that in virtue of which moist- ure is retained. It appears to depend especially on the porousness of a soil, and, probably, also, in soi le degree, on the deliquescent salts which it contains, even in veiy small quantity. Davy was disposed to regard the hygrometric property of soils as a certain index of their good quality ; and the experiments of M. Schiibler upon the point, all tend to confirm the accuracy of this view. In M. Schiibler's experiments, the increase of weight of dry soils was ascertained by exposing them for a certain time in an atmosphere kept at the point of saturation with moisture, and at the same tem- perature, between 60° and 65° Fahr. Kind of soil. 500 centigrammes, or 77.165 grains troy, of soil, spread upon a surface of 36,000 millimetres, or 141.48 square inches, absorbed in— 12 hours. 24 hours. 48 hours. 72 hours. Grains. 0 .154 0.077 1.617 1.925 2.310 2.849 2.002 6.160 2.695 1.232 1.078 Grains. 0 .231 0.077 2.002 2.310 2.772 3.234 2.387 7.469 3.465 1.771 1.463 Grains. 0 .231 0.077 2.156 2.618 3.080 3.696 2.695 8.470 3.850 1.771 1.540 Graius. 0 .231 0.077 2.156 2.695 3.157 3.773 2.695 9.240 4.004 1.771 1.540 Gypsum • I.iorht rliv.....». . Chalky soil in fine powdei Arable soil of Hoffwyll . . . Arable soil of Jura From the results comprised in the preceding table, we may con- clude, first, that the faculty of absorbing lessens as soils acquire moisture; second, that humus is the most hygrometric of all the substances examined ; third, that the clays which. absorb the largest quantity of moisture are those which contain the smallest proportion of .sand ; and fourth, that silicious sand and gypsum do not absorb moisture in any appreciable quantity. Ahsorptum of oxygen gas hy arable soils. Humboldt had already observed, before the year 1793, that argillaceous soils, the lydian stone, certain schists, and humus, deprived the air of its oxygen. He had also observed that the sides of the large cavities dug in the salt mines of Saltzburg, absorbed this gas, and thus rendered the stagnant atmosphere of the virorkings irrespirable and incapable of supporting combustion. Finally, this illustrious observer had satis ABSORPTION OF OXYGEN BY SOILS. 221 factorily ascertained, at the same period, that earth taken from the galleries of these mines, only became fertile after having been ex- posed to the atmosphere for a considerable length of time. I have quoted these curious observations because they are, so far as I know, the first udiich established the necessity of the presence of oxygen in the interstices of the soil, or, as M. Humboldt then said and, in- deed, as may still be maintained, the utility of a previous oxidation of the soil. All our agricultural facts, indeed, confirm this view of the necessity of air in the interstices of the soil that is destined for the growth of vegetables. When, by ploughing very deeply, for example, we bring up a portion of the subsoil into the arable layer, in order to in- crease its thickness, we always lessen the fertility of the ground for a time ; in spite of the action of manures, and of any treatment we may adopt, a certain time must elapse before the subsoil can pro- duce an advantageous effect ; it is absolutely necessary that it have been exposed to the atmospheric influences, and it is then only that deep ploughing, which gives the arable layer a greater thickness, pays completely for the expense it has occasioned. I am disposed to ascribe the absorption of oxygen gas by clayey soils, to the oxide of iron, which they almost always contain, and which is in the minimum state of oxidation, when the clay lies at a certain depth. In the performance of some soundings in a tertiary soil of the department of the lower Rhine, which I performed in 1822, I had occasion to observe that the clays brought up white by the borer, very speedily became blue by exposure to the air; and that in gaining color they condensed oxygen. I propose returning upon this fact to shovi^ the important part which this simple super- oxidation probably plays in the amelioration of soils.* M. Schiibler, again, has studied the action of oxygen gas upon the component parts of arable soils, and, according to him, the absorp- tion of this gas cannot be doubted ; it is very trifling in connection with sand and gypsum, very decided as regards clay, loam, and humus. As M. de Humboldt and M. de Saussure had already done, M. Schiibler observed humus to change a portion of the oxygen which it fixed, into carbonic acid ; but, in general, the other sub- stances, or soils, or elements of soils, upon which he experimented, appeared to absorb the oxygen by the intermedium of the protoxide of iron, from which they are never altogether free. Besides this cause, due to the superoxidation of a metal, M. Schiibler thinks that a certain portion of the oxygen disappears by condensation within the pores of some soils ; and in support of his opinion he appeals to the admirable observations of M. de Saussure, on the condensation of the gases by porous bodies. Starting from the fact that the roots of plants require the presence of oxygen in order to thrive, he * Austin proved, that during the oxidation of metallic iron under water, there is a constant production of ammonia. Certain experiments commenced some time ago, and wliich I still continue, will establish in the most precise manner, as I hope, the fact liiat this formation of ammonia likewise takes place during the passage of the protox- ide of iron to the state of hydrated peroxide. The theoretical conclusions deducibl« from this fact, and the economic applications which may tlow from it, mXist be obvious. 19* £23 CAPACITY OF SOILS FOR HEAT. ascribes a greater power to the gases compressed or condensed within the interstices of the soil. But the action of the air upon ihe roots of vegetables is readily conceivable in soils of a h)ose nature, especially if ihcy have been sufficiently worked, without the necessity of having recourse to such an explanation. Capacity of soUs for heat. The quantity of heat which a soil will receive, retain, or throw off in a given time, depends upon the con- ducting power which it possesses. M. Schiibler endeavored to measure this power comparatively by measuring the rates of cooling. In a vessel of the capacity of 595 cubic centimetres, or 234.2 cubic inches, filled with the substance to be tried, a thermometer was placed, with its bulb in the centre. The temperature having been brought up to 62.5° C, (144.5° Fahr.,) the time was noted which each substance required to fall to 21.2° C, or about 70° Fahr., the temperature of the surrounding air being 16.2° C, or about 61' Fahr. Kindofsofl. Power of retaining heat, that of calcareous sand beinff 100. Time which 234.2 cubic inches of soil required to cool from 141= to 70 = Fahr., the temperature of the surroundin' air being about 61 o jPahr. r!»lrarpnn«i «sinH 100.0 95.6 73.2 76.9 71.1 68.4 6C.7 61.8 49.0 64.8 70.1 74.3 h. ra. 3.30 3.27 2.34 2.41 2.30 2.24 2.19 2.10 1.43 2.16 2.27 0.36 Rnnilv" rlav Rtiffish rlav ArAblesoilofHoffwyil... Arable soil of the Jura. •• • The general observations which these experiments suggest, are that, for equal volumes, calcareous or silicious sand possesses greater powers of retaining heat than any of the other substances tried. This fact explains the high temperature and the dryness which sandy soils maintain even during the night in summer. Humus is obviously the substance which possesses the highest conducting powers. Degrees in which soils become heated under exposure to the sun. There is no one who has not had occasion to observe the high tem- perature which bodies acquire when exposed to the rays of the bright sun. There are some, such as dry sand, slates, and certain colored rocks, which become burning hot. It is by the heat of the sun that the soil, before it is shaded by the leaves and stems of plants, rises in temperature, and throws off the excess of moisture which it had imbibed in the winter. Agriculturists all know how different the degree in which this heating takes place, even in soils that are close to one another. A light-colored, moist, clayey soil will heat giucb less thaa a dajk-colored, calcareous, or sandy soil. The dif CLASSIFICATION OF SOILS. lercnces in the heat acquired in various soils depend, 1st, on the state of their surface ; 2d, on iheir composition ; 3d, on the quantity of water which they contain ; and, 4th, on the anjrle of incidence of the sun's rays. M. Schiibler, by a method which is far from being unobjectionable, but which may be excused, considering the diffi- cuhies of the subject, measured the temperature acquired by different soils exposed to the sun for the same length of time, and in circum- stances as nearly alike as possible ; the numbers obtained are given in the following table : Soils Silicious sand, yellowish gray • • • Calcareous sand, whitish gray Bright gypsum, whitish gray Poorcliy, yellowish .... • Stiff clay Argillaceous earth, yellowish gray Pure clay, bluish gray Calcareous earth, white Humus, blackish gray Garden earth, blackish gray Arable earth of Hoffwyll,gray.... Arable earth of the Jura, gray Highest temperature acquired by the upper layer, the mean tempernture of tbe atmo- sphere being 25° C. (77= F.) The soil moist, de- The soil dry, de- grees centigrade. grees centigrade. 37.25 (99° F.) 44.75 (112 = . 5 F.) 37.38 44.. 50 3G.25 43.62 36.75 44.12 .37.25 44.50 37.38 44.62 37.50 45.00 35.63 (96°. IF.) 43.00 (109».4F.) 39.75 (103».5F.) 47.37 37.50 45.25 36.88 44.25 36.50 43.75 In comparing the circumstances which concur in assisting the action of the sun's rays in raising the temperature of the soil, it appears that the color and moistness of the soil and the angle of incidence of the sun's rays are the most influential ; they may occa- sion differences in the temperature acquired of from 14° to 15° C, (25° to 27° F.) The nature of the surface and the composition of the soil are far from producing such marked difTerences ; although, according to M. Schiibler, the effect of inclination is very decided, dnd may occasion a difference to the amount of 25° C, (45° F.) CLASSIFICATION OF SOILS. Agriculturists class soils according to their fertility, and the cropping which they will stand to advantage. In practice two grand divisions have been adopted : strong soils, and light soils ; every soil belongs wholly or in part to one or other of these divisions. In strong soils clay is tue predominating element ; in light soils it is sand which prevails. The first are stiff, little permeable, and slow in drying ; the second are loose, dry speedily and readily, are permeable, and less difficult to labor. Humus always adds to the qualities of these two kinds of soil, though possessed of properties eo opposite ; but its utility is especially remarkable in argillac^nif w clayey soils, the extreme stiffness of which it diminishes. 224 SOILS. Stiff or strong soils share in the advantages and disadvantage* peculiar to clay ; they absorb a great deal of moisture, and they do not dry readily, retaining obstinately a considerable quantity of wa- ter. The humus which they contain, and the manures which are spread upon them in the course of cultivation, remain with them for a long time, preserved as it were from the too active agency of at- mospheric influences ; the fertilizing power of these substances is further rarely interfered with by too great a degree >f dryness in the soil. Nevertheless, in very wet seasons, and in years of extraordi- nary drought, the advantages which I have enumerated disappear. In wet seasons clay lands become immoderately humid, sometimes they approach the state of mere puddle ; and on the contrary, under severe and long-continued drought, they become so hard that the roots of vegetables can no longer penetrate them, and then they crack in all directions, and the roots perish for want of being prop- erly covered. I might add that severe frost is the cause of effects disadvantageous in the same degree; so that very stiff Ciays are liable to the same bad effects under the influsnce of two causes dia- metrically opposed : the great heat of summer and the severe cold of winter. In such soils all agricultural operations are often impracticable ; changed into a liquid mud, neither horse nor plough can be put i;pon them, or baked into a mass having the hardness of stone, the share will not penetrate them. Light soils rarely accumulate an excess of moisture in their inter- stices, so that they are liable to suffer under want of rain of even short continuance. They are worked with infinitely greater ease, and at much less expense ; vegetation upon them is quicker, and harvests earlier ; but manure is less profitable than in clayey soils, because the rains dissolve and carry it away. The defects of these two kinds of soils are precisely of a nature to compensate one another, and it is in fact by a mixture, or that which is equivalent to a mixture of these two extreme kinds of soil, that those lands are formed which are admitted to be the best adapted to cultivation, and the most fertile of all. Messrs. Thaer and Einhoff, in submitting to mechanical analysis an immense number of arable soils, and in studying at the same time the system of culture best adapted to these soils, and to their relative fertilities, have given us results of great importance, and which may be made the basis of a practical classification of arable soils.* An argillaceous or clayey soil properly so called, generally con- tains about 40 per cent, of sand. If the quantity of sand be less than this, the crop from such a soil will be more or less precarious, and the tenacity will be sv ch, that tonsiderable difficulty will be ex- perienced and necessary expense incurred in working it ; such a clayey soil, (having at least 40 per cent, of sand,) when it contains a sufficient quantity of humus and is properly treated, may be regard- ed as favorable for wheat. Barley succeeds better than wheat, when * Thaer's Rational Principles of Agricaltiue, iaiKMi, .\ccouat of A.vsam, p. 130. LOCALITIES. oukitt. Diajue. Roso. N'Dick. 72.0 89.0 78.0 91.0 10.0 3.0 7.0 1.8 8.0 3.6 5.2 3.0 trace 0.5 trace 0.5 10.0 3.6 9.0 3.0 OJ 0.8 0.7 CLASSIFICATION. 229 Districts. 1^ 2 i 1 i — 1 "3 . £ i <3 if } i 1 J Remark*. County of Kent Norfolk Middlesex Worcestershire Vale of the Teviot Salisbury 66.3 88.9 60.0 60.0 83.3 91 5.2 1.7 12.8 16.4 7.0 12.7 3.3 1.2 11.6 14.0 6.8 6.4 4.8 7.0 11.2 5.6 0.7 57.3 0.8 1.. 0.3 1.2 0.8 1.8 8.0 0.6 4.4 2.8 1.4 12.7 05 4.9 0.3 .0 { Rich soil, } under hops, j Ditto under ( turnips. \ Ver^- good \ soil, vvheat. \ Very lertUe } soil. Good soil. \ Excellent } grazing soil M. Gasparin has published analyses of the soils of the south of France. Instead of destroying the humus and organic matter by- calcination, as Davy and the generality of analysts did, M. Gasparin dissolved out the humus by means of a strong alkaline solution. This method of procedure is. however, at least as liable to objection as the other. Districts Humus. Calca- reous matter. Clay. Sand. Remarks. From Thor (Vaucluse) Alluvium of the Rhone From Palus, near Orange Old deposite of the Rhone From the plains near Orange Neighborhood of Auch 7.5 3.4 2.5 5.0 4.0 1.5 92.5 2.3 555 32.5 50.0 3.5 6.0 53.5 43.5 56.0 48.0 73.0 1.5 42.7 1.0 11.5 2.0 23.0 Middling wheat soil. < Well adapted for mad- ( der, wheat & lucern. Bad wheat land. ->.^ i Good wheat land, vgy^ ( indifferent for madder. Ditto, bad for njadder. There is an important element which must always be taken into the account in estimating the value of soils, no matter what their special composition ; this element is their depth, or thickness. In running a deepish furrow in a cultivated field, we generally distin- guish at a glance the depth of the superficial layer, which is com- monly designated as the mould or vegetable earth ; this is a layer generally impregnated with humus, and looser and more friable than the subsoil upon which it rests. The thickness of this superficial layer is extremely variable ; it is frequently no more than about 3 inches ; but it is also encountered of every depth from 3 or 4 lo 12 or 13 inches. It must be held an exceptional and unusual case when it has a depth of 3 feet or more. Nevertheless we do meet with collections of vegetable soil of great depth, deposited by rivers, washed down into the bottoms of valleys, or accumulated on the surface, as in the virgin forests or vast prairies of America. Depth of mould, or vegetable soil, is always advantageous ; it is one of th» 20 230 DEPTH OP SOIL. best conditions to successful agriculture. If we nave depth of soil, and the routs of our plants do not penetrate sufficiently to derive benefit froui the fertility that lies below, we can always, by working a little deeper, bring up the inferior layers to the surface, and so make them concur in fertilizing the soil. And, independently of this great advantage, a deep soil suffers less either from excess or deficiency of moisture ; the rain that falls has more to moisten, and is therefore absorbed in greater quantity than by thin soils,, and, once imbibed, it remains in store against drought. The layer upon which the vegetable earth rests, is the subsoil, which it is of importance to examine, inasmuch as the qualities, and, consequently, the value of an arable soil, have always a certain rela- tion with the nature and properties of this subjacent stratum. Fre- quently, and especially in hilly countries, the mineral constitution of the subsoil is the same as that of the soil, and any difference that the former may present is owing especially to the presence of humus, and to the looser condition which results from the growth of vege- tables, from ploughing, &c., and not from atmospheric influences. By deep ploughing done cautiously, the thickness of the layer of arable land may be increased at the expense of the subsoil, and, when plenty of manure can be commanded, the operation will go on with considerable rapidity. Still it is maintained, and indeed in many cases it is unquestionable, that the soil loses temporarily some portion of its fertility by the introduction of a certain quantity of the subsoil, and that, under ordinary circumstances, several years elaps» before any amelioration becomes perceptible. In plains, in high table-lands, the analogy, in point of constitution, between the soil and subsoil is not so constant. In such situations the arable land is frequently an alluvial deposite proceeding from the d_es*ruction or disintegration of rocks situated at a great distance. When the superior strata possess properties that are entirely differ- ent from the subsoils, it may be understood how the vegetable earth may be improved by the addition of a certain dose of the subsoil, and this is the case in which the amelioration is the least expensive. The impermeability of the subsoil is one grand cause of the too great humidity of a cultivated soil. A strong soil, very tenacious through the excess of clay which it contains, has its disadvantageous proper- ties considerably lessened, if the subsoil upon which it rests is sandy, 1st, from the evident amelioration which must result from an ad- mixture of the two layers, and, next, because it is always a positive advantage in having a soil which has a strong affinity for water superposed upon a subsoil which is extremely permeable. The in- verse situation is scarcely less desirable ; a light friable soil will have greater value if it lies upon a bottom of a certain consistency, and capable of retaining moisture ; wil i this condition, however, that the clayey layer shall not be too uneven in its surface, that it shall not present great hollows in which water may collect and stagnate ; an impermeable subsoil, to act beneficially in such circumstances, must have a suflScient inclination to admit of its draining itself. The most essential distinction, then, in regard to the nature of subsoils is, int» SOILS IN REFERENCE TO CLIMATE. 231 . permeable and impermeable. Acquainted with the nature of vege- table earth, it is easy to judge of the advantages or disadvantages which will be presented by subsoil having the faculty of retaining or of permitting the escape of moisture. In some situations, particularly upon the slopes of hills, the layer of arable land is of very limited thickness, and it is not uncommon to see it lying upon rocks of the most dense description, such as granite, porphyry, basalt, &c. ; in such circumstances the substrata are unavailable, and there is nothing for it then in the way of ame- lioration except to transport directly vegetable earth from other situations. Mica schist is perhaps the least intractable rocky sub- soil ; the plough often penetrates it, and in the long run it becomes mingled with the arable layer. It is generally agreed that limestone rocks form a less unfavorable substrate. There are in fact some calcareous rocks which absorb water, and crumble away, and the roots of various plants, such as cinquefoin, penetrate them deeply ; but there are many limestone rocks so hard that they resist all de- composing action for a very long period of time. The qualities which we have thus far sought to determine in soils, do not depend solely on their mineral constitution or their physical properties, nor yet on those of the subsoils which support them. These qualities to become obvious require that the soils shall be placed in certain conditions which must not be left out of the reck- oning. Such are those of the climate enjoyed and of the position more or less inclined to the horizon in one direction or another. The precepts which we have laid down are especially applicable to the arable lands of Germany, England, and France. But in gener- alizing it would be proper to say that clayey lands answer better in dry climates, and light sandy soils in countries where rains are fre- quent. Kirwan made this remark long ago in connection with nu- merous analyses of wheat lands. The conclusion to which this celebrated chemist came was this, that the soil best adapted for wheat in a rainy country must be viewed in a very different way with refer ence to a country where the rains are less frequent. The fertility of light sandy soils is notoriously in intimate relationship with the frequent fall of rain. At Turin, for example, where a great deal of rain falls, a soil which contains from 77 to 80 per cent, of sand is still held fertile, while in the neighborhood of Paris, where it rains less frequently than at Turin, no good soil contains more than 50 pei cent, of sand. A light sandy soil which in the south of France would only be of very inferior value, presents real advantages in the moist climate of England.* Irrigation supplies the place of rain, and in those countries or situations where recourse can be had to it, the question in regard to the constitution of soils loses nearly the whole of its interest. Land that can be irrigated has only to be loose and peimeable in order to have the whole of the fertility de- veloped which climate and manure can confer. Sandy deserts are sterile because it never rains. Upon the sandy downs of the coasts ♦ Sinclair's Practical Agricultnre. 232 SOILS If REFERENCE TO CLIMATE. of the Southern Ocean, a brilliant vegetation is seen along the course of the few rivers which traverse them ; all beyond is dust and sler* ility. I have seen rich crops of maize gathered upon the plateau of the Andes of Quito in a sand that was nearly moving, but which was abundantly and dexterously irrigated. A sandy and little coherent soil is by sc much the more favorably situated as it lies in the least elevated parts of a district ; it is then less exposed to the effects of drought ; any considerable degree of inclination is unfavorable to such a soil, inasmuch as the rain drains off too quickly, and because it is itself apt to be washed away. It is to prevent this action of the rains, that the abrupt slopes of hills are generally left covered with trees ; and the deplorable conse- quences which have followed from cutting down the woods in moun- tainous countries are familiarly known. Strong soils, on the contrary, are better placed in opposite cir- cumstances. A certain inclination is peculiarly advantageous to them ; and, indeed, in working clayey lands that stand upon a dead level, we are careful to ridge them in such a way as to favor the escape of water. In countries situated beyond the tropics, where consequently shadows are cast in the same direction throughout the whole year, the exposure of a piece of land is by no means matter of indiffer- ence. In our hemisphere, the lands which have a considerable in- clination and a northern exposure, receive less heat and light, and remain longer wet than those that slope towards the south ; vegeta- tion consequently is less forward upon the former than the latter lands : but, on the contrary, the latter are less exposed to suffer from want of rain ; and it is a fact, now well ascertained from data collected in Switzerland and in Scotland, that the slopes which de- scend towards the north, if they be only not too abrupt, are actually the most productive. This kind of anomaly is explained by the fre- quence and rapidity of the thaws which take place upon slopes that lie to the south. Frost, when not too intense, is certainly less inju- rious to vegetables than too rapid a thaw ; and it is easy to under- stand that in situations where, from the mere effect of nocturnal radiation, vegetables are covered almost every morning through the spring with hoar frost, a rapid thaw must take place every day im- mediately after the rise of the sun. With a northern exposure, the frost occurs in the same measure ; but the cause of its cessation does not operate so suddenly, the fusion of the rime being effected by the gradual rise in temperature of the surrounding air. In other respects, it is obvious that the advantages and disadvantages of dif- ferent exposures are connected with the nature and the constitution of soils. The same may be said with reference to means of shelter from the action of prevailing winds. Stiff wet lands are much bene- fited by the action of free currents of air ; our stiff soils at Bechel- bronn remain impracticable for our ploughs during but too long a period of the spring, when they have not been well dried in the months of March and April by strong winds from the east. Light and sandy soils, again, require to be well sheltered. The whole ob- IMPROVEMENT OF SOILS. 2SS ject of Studying the soil, is its amelioration ; the industry of the agriculturist is, in fact, more effectually bestowed, and exerts a greater amount of influence upon the soil than upon all the other and varied agents which favor vegetation. To improve a soil is as much as to say that we seek to modify its constitution, its physical properties, in order to bring them into har- mony with the climate and the nature of the crops that are grown. In a district where the soil is too clayey our endeavor ought to be, to make it acquire to a certain extent the qualities of light soils. Theory indicates the means to be followed to effect such a change ; it suffices to introduce sand into soils that are too stiff, and to mix clay with those that are too sandy. But these recommendations of science which, indeed, the common sense of mankind had already pointed out, are seldom realized in practice, and only appear feasible to those who are entirely unacquainted with rural economy. The digging up and transport of the various kinds of soil according to the necessities of the case, are very costly operations, and I can quote a particular instance in illustration of the fact : my land at Bechelbronn is generally strong ; experiments made in the garden on a small scale showed that an addition of sand improved it consid- erably. In the middle of the farm there is a manufactory which accumulates such a quantity of sand that it becomes troublesome ; nevertheless, I am satisfied that the improvement by means of sand would be too costly, and that all things taken into account, it would be better policy to buy new lands with the capital which would be required to improve those I already possess in the manner which has been indicated, I should have no difficulty in citing numerous in- stances where improvements by mingling different kinds of soil were ruinous in the end to those who undertook them. A piece of sandy soil, for example, purchased at a very low price, after having been suitably improved by means of clay, cost its pro- prietor much more than the price of the best land in the country. Great caution is therefore necessary in undertaking any improvement of the soil in this direction, — in changing suddenly the nature of the soil. Improvement ought to take place gradually and by good hus- bandry, the necessary tendency of which is to improve the soil. Upon stiff clayey lands we put dressings and manures which tend to divide it, to lessen its cohesion, such as ashes, turf, long manure, &c. But the husbandman has not always suitable materials at his command, and in this case, which is perhaps the usual one, he must endeavor, by selecting his crops judiciously, crops which shall agree best with stiff soils, and at the same time meet the demands of his market, to make the most of his land. In a word, the true husband- man ought to know the qualities and defects of the land which he cultivates, and to be guided in his operations by these ; and in fact it is only with such knowledge that he can know the rent he can afford to pay, and estimate the amount of capital which he can rea- sonably employ in carrying on the operations of his farm. In an argillaceous or clayey soil, which we have seen above is the best adapted for wheat in these countries, it would be absurd to per- 20* 894 IMPROVEMENT OF SOILS. sist in attempting to grow crops that require an open soil. Clayey lands generally answer well for meadows, and autumn ploughing is always highly advantageous to them by reason of the disintegrating effects of the ensuing winter frost. Chalk occupies a large space in recent formations ; as a general rule, the soil it supports immediately is of no great fertility. Sir John Sinclair proposed to improve such soil by growing green crops and consuming them upon the spot. Properly treaicd, the chalky soils of England produce trefoil, turnips, and barley, and they ar« particularly adapted to cinquefoin. It is doubtful whether in France, where the climate is not so moist as in England, chalky lands could be treated to advantage on the English plan. Recent inquiries have shown that chalk contains a small quantity of phosphate bf lime, a salt, as we shall see by and by, whose presence is always desirable in arable lands. Turf or turfy soils yield rich crops when we succeed in converting the turf into humus. The grand difficulty in dealing with turf is to dry it properly, inasmuch as it is generally found at the bottom of valleys or of old lakes and swamps. By a happy coincidence, turfy deposites frequently alternate with layers of sand, of gravel, of clay, and of vegetable earth, which have been accumulated at the 'same epoch. By a mixture, by a division of these different materials, preceded in every case, however, by proper draining, mere peat bogs may be turned into good arable soil. Pyrilic turf, however, shows itself more intractable, it rarely yields any thing of importance. To improve such a soil it is absolutely necessary to have recourse to substances of an alkaline nature, such as chalk or lime, wood-ashes, &c., which have the property of decomposing the sulphate of iron which is formed by the efflorescence of the pyrites. Turfy lands can also be brought into an arable state, with the help of paring and burning. Scotch agriculturists, who are very familiar with reclaim- ing land of this kind, hold, that the best method of improving turf or bog lands, is to turn them into natural meadows. Where the wet and soft state of the soil does not allow cattle to be driven upon it, the crop of hay should only be cut once, the second crop should be left standing. By proceeding in this way mere bogs have been turned into productive meadows.* Turfy lands thoroughly drained and im- proved, present many advantages connected with their natural but not excessive moistness. In the neighborhood of Haguenau, mag- nificent hop-gardens are found upon bottoms of this kind ; madder also thrives in it equally well, and for certain special crops it is in my opinion one of the richest soils. Sandy soils do perfectly well in countries which are not exposed to long droughts ; their cultivation is attended with little expense, and they grow excellent crops of turnips, potatoes, carrots, and rye ; but it is well to exclude clover, oats, wheat, and hemp, which require a soil of greater consistence. In southern countries, a sys- tem of irrigation is absolutely necessary, in connection with the * Sinclair, Practical Agriculture MOVING SANDS DOWNS. SJSfe cultivation of sandy soils-if they are not watered, they remain nearly barren ; the only mode of making them productive is to lay them out in plantations of timber. Those moving sandy plains of great extent, which are found in the interior of many continents, seem at first sight stricken with eternal barrenness Nevertheless, the mobility of the sand of the desert, which permits it to be swept hither and thither, and to be tossed about like a liquid mass, depends less upon the total absence of ar- gillaceous particles than upon the want of the moisture necessary to agglutinate or to fix its grains. The burning steppes of Africa and America have their oases here and there, the surface of which, moistened by a spring, is green with vegetation ; and whenever sandy plains are bathed by a river, it is possible to render them fit for cultivation. In Spain, for instance, in the neighborhood of San Lu- car de Baromeda, a powdery soil of extreme dryness has been fer- tilized by the hand of man. The mammillated downs of San Lucar are covered on the surface by a layer of quartzy sand, so loose that it is blown about by the wind ; but by a happy disposition of things, a lower stratum of these downs is kept constantly moist by the wa- ters of the Guadalquiver, and it is only necessary to remove the su- perficial sand, and to level the surface, in order to have a loose soil which unites in the highest degree two essential conditions of fer- tility, viz : openness, and a constant supply of moisture, which pene- trates the soil in virtue of its permeability ; under the influence of a fine climate and manure, the market gardens established in the riiidst of this desert are remarkable for the rapidity and the vigor of their vegetation. To avoid great expense, the labor of removing the sand is only undertaken in places where the layer is least thick ; and what is removed being heaped up as a mound around the soil which is clear- ed, a kind of boundary wall is formed, which is not without its use in affording shelter, and which becomes productive itself by the plantations of vines and fig-trees that are made upon it with a view mainly to its consolidation. In the same way in Alsace, in the plains of Haguenau, the soil which was a moving desert of sand, has, in the course of less than forty years, become one of the most fertile under the influence of incessant cultivation ; in the same way also it is that in Holland, mountains of sand, which had been accumulated by the winds, have been fixed. This sand, which rests upon a wet bottom, draws up the moisture by capillary attraction, and so be- comes fit to support certain vegetables. These downs, which may be said to have come out of the sea, have a constant tendency in many places to encroach upon the cultivated lands. To oppose their progress, the Dutch sow them with the arundo arenaria. the long and creeping roots of which bind together the movmg mass and imprison the particles of sand within a kind of net-work. These masses of sand become fixed in this way ; but they remain nearly or altogether unproductive. It is therefore a problem of the highest importance in many in- stances to fix permanently masses of sand blown up from the sea, by covering them with productive plantations. This problem wat £38 DOWNS ^ARREST OF MOVING SANDS. studied and successfully resolved by M. Bremontier, a French en gineer, who by sagacity in the choice of means and persever- ance in their employment gave a complete and practical solution of the question among the downs of the Gulf of Gascony.* The downs formed by the sand which is thrown up by the ocean between the mouths of the Adour and the Girond, occupy a surface of 75 square leagues and have a mean elevation of from 60 to 70 feet, 'rhey form a multitude of hillocks, which appear co.iUected by their bases, the crowns of many of them rising to a height of 160 feet and upwards. Under the influence of the prevailing west winds, these masses of sand move with a mean celerity of about 80 feet per annum, covering forests and villages in their progress. A part of the little town of Mimizan is already invaded, and it has been calculated that in the course of twenty centuries, things pro- ceeding at their present rate, the rich territory of Bordeaux will have completely disappeared. In their progress these moving mass- es of sand choke up the beds of rivers, and increase the disastrous effects they produce otherwise by causing formidable inundations. The sands of the Gulf of Gascony, like those of Holland and the Low Countries, are not altogether without moisture ; a very short way below the surface they are moist, and even present a certain degree of cohesion. This, in fact, might have been predicated, for otherwise the wind which brings them from the sea would have dis- persed them in clouds of dust and to great distances ; but no such dispersion takes place. Downs advance slowly, at the rate already indicated, and by rolling over, as it were, upon themselves. The sand driven by the wind creeps up on the flanks of the ridges as upon an inclined plane ; after having got over the summit of the hillocks already formed, it falls down the opposite slope, and accu- mulates at the base. The action of the wind is only exerted upon so much of the sand as is rendered loose and moveable by its dry- ness ; but the moist part is exposed, dried, and swept away in its turn ; in this way the whole mass of sand which was at first deposit- ed upon the west aspect of the hillocks is carried to the east, where it is in the shelter. By this process, under the influence of a wind fvhich blew steadily for six days, a hillock has been seen to advance towards the interior of the country through a space of 3| feet.f The moisture contained in the sand proceeds from the rains, from the surface water that filters through it and displaces the salt water which impregnated it originally. The very slight trace of sea-salt that finally remains it it has no unfavorable influence on vegeta- tion. Once aware of the fact that certain plants throve in the sands of downs, Bremontier saw that they alone were capable of staying their progress and consolidating them. The grand object was to get plants to grow in moving sand, and to protect them from the violent winds which blow oflf the ocean, until their roots had got firm hold of the soil. • Annals of French Agriculture, vol. xxvii. p. 145. t D'Aubiiisson, Geognosy, vol. ii. p. 467. ARREST OF MOVING SANDS. 237 Downs do not bound the ocean like beaches. From the base of the first hillocks to the line which marks the extreme height of spring tidee, there is always a level over which the sand sweeps without pausing. It was upon this level space that Bremontier sowed his first belt of pine and furze seeds, sheltering it by means of green branches, fixed by forked pegs to the ground, and in such a way that the wind should have least hold upon them, viz., by tu.-ning the lopped extremities towards the wind. Experience has shown that by proceeding thus, fir and furze seeds not only germinate, but that the young plants grow with such rapidity, that by and by they form a thick belt, a yard and more in height. Success is now certain. The plantation so far advanced, arrests the sand as it comes from the bed of the sea, and forms an effectual barrier to the other belts that are made to succeed k towards the interior. When the trees are five or six years of age, a new plantation is made contiguous to the first and more inland, from 200 to 300 feet in breadth, and so the process is carried on until the summits of the hillocks are gradu- ally attained. It was by proceeding in this way that Bremontier succeeded in covering the barren sands of the Arrachon basin with useful trees Begun in 1787, the plantations in 1809 covered a surface of between 9,000 and 10,000 square acres. The success of these plantations surpassed all expectation ; in sixteen years the pine trees were from thirty-five to forty feet in height. Nor was the growth of the furze, of the oak, of the cork, of the willow, less rapid. Bremontier show- ed for the first time in the annals of human industry, that moveable sands might not only be stayed in their desolating course, but actu- ally rendered productive. Like all other inventors, this benefactor of humanity was soon the object of jealousy among his contempora- ries. Doubts were of course entertained at first of the possibility of consolidating the moving sands of downs ; and when this was de- monstrated, the honor of originality was denied him. The ingenious engineer defended himself with moderation, and demanded an in- quiry ; in the course of which it was satisfactorily proved that noth- ing of the same kind had been attempted by others previously to the year 1788. The labors of Bremontier must be regarded as another of those remarkable struggles which the industry of man has suc- cessfully waged with the elements. CHAPTER V. OF MANURES. Whatever may be its constitution and physical properties, land yields lucrative crops only in proportion as it contains an adequate quantity of organic matter in a more or less advanced state of de- composition. There are favored soils in which this matter, desig 238 MANtTRES. nated by the name of humus^ or mould,* exists by nature, while there are others, and they form the majority, which are either totally des- titute of it, or contain it but in insignificant proportion. To become productive, these soils require the intervention of manure ; for this "here is no substitute, neither the labor which breaks them up, not the climate which so powerfully promotes their fecundity, nor tho salts and alkalies which are such useful auxiliaries of vegetation. Not that land entirely destitute of organic remains is incapable of producing and developing a plant. We have already seen that the atmosphere, light, heat, and moisture, suffice for its existence ; but in such a condition, vegetation is slow and often imperfect ; nor could agricultural industry be advantageously applied to a soil which approached so near to absolute sterility. Plants, considered in their entire (?Onstitution, contain carbon, water, (completely formed, or in its elements,) azote, phosphorus, sulphur, metallic oxides united to the sulphuric and phosphoric acids, chloildes, and alkaline bases in combination with vegetable acids ; many of these elements form no part of the atmosphere, and are necessarily derived from the soil. Moreover, the manures most generally made use of are nothing but the detritus of plants, or the remains or excretions of animals, including by the very fact of their origin the whole of the elements which constitute organized beings; and although it is very probable that certain tribes of plants are more adapted than others to appropriate the azote or the ammoniacal va- pors of the atmosphere, experience proves that azotized organic re- mains contribute in the most efficacious manner to the fertility of the soil. Besides, we are far from being able to affirm that the carbon of plants is derived from the carbonic acid of the atmosphere. Doubtless this acid is its principal source ; but it is possible that certain elements of carburetted dungs may be directly assimilated. The writers who have treated of manures, have generally formed them into two grand classes : 1st. Manures of organic origin, in which are again found all the elements of the living matter. '2d. Mineral manures, saline or alkaline, which are particularly designated under the name of stimulants, thus ascribing to them the faculty, purely gratuitous, of facilitating the assimilation of the nu- triment which plants find in dung, and of stimulating and exciting their organs. Such a distinction has no real foundation, and nothing shows so much how scanty our knowledge upon this subject has hitherto been as this tendency in the ablest minds to connect vege- table nutrition with the feeding of animals. All the agents employed by the agriculturist to restore, preserve, and augment the fecundity of the soil, 1 shall term Manures. In my view gypsum, marl, and ashes are manures, as much as horse- dung, blood, or urine ; all contribute to the end proposed in em])loy- ing them, which is the increase of vegetable production. The hest * Mould, or vegetable earth, as the word is generally used, is not exactly humua r but as it derives its principal q'ialities from the presence of the humus of the chemist \ iball eenerally employ the terms as synonymous.— Eng. Ed. DECAY OF ORGANIC MATTERS. 239 manure, that which is in most general use, is precisely that which by its complex nature contains all tlire fertilizing principles required in ordinary tillage. Particular cultures may demand particular manures ; but the stand- ard manure, such as farm dung, for example, when it is derived from good feeding, supplied to animals with suitable and abundant litter, affords all the pr'inciples necessary to the development of plants ; such manure contains at once all the usual elements which enter into the organization of plants, and all the mineral substances which are distributed throughout their tissues; in fact, carbon, azote, hy- drogen, and oxygen are found therein united with the phosphates, sulphates, chlorides, &c. In order to be directly efficacious, every manure must present this mixed composition. Ashes, gypsum, or lime spread upon bar- ren land, would not improve it in any sensible degree ; azotized or- ganic matter, absolutely void of saline or earthy substances, would probably produce no better effect ; it is the admixture of these two classes of principles, of which the first is derived definitively from the atmosphere, while the second belongs to the solid part of the globe, which constitutes the normal manure that is indispensable to the improvement of soils. Dead organic matter, subjected to the united influence of heat, of moisture, and of contact with the air, undergoes radical modifica- tions, and passes by a regular course of transformation into a con- dition more and more simple. The tissues, so long as they form a part of the animated being, are protected against the destructive ac- tion of the atmospheric agents ; in plants and animals this protec- tion is not extended beyond the period of th^ir existence ; destruc- tion commences with death, if the accessory circumstances are suf- ficiently intense ; and then ensue all the phenomena of decomposi- tion, of that putrid fermentation which, at the expense of the primi- tive elements of the organized being, generates bodies more stable and less complicated in their constitution, and which present them- selves in the gaseous and crystalline conditions, forms which are affected by the inorganic bodies of nature in general. The mineral substances which had been taken up in the organiza- tion become freed, and are thus again restored to the earth. The organized substances which change the most rapidly, are precisely those into which azote enters as a constituent principle. Left to themselves, whether in solution or merely moistened, these sub- stances exhibit all the characteristic signs of putrefaction ; they ex- hale an insupportable odor ; and the result of their total and com- plete decomposition is finally the production of ammoniacal salts. The water wherein the phenomenon is accomplished facilitates it not only by weakening cohesion and enabling the molecules to move more freely, but it assists also by the very affinity which each of its own principles bears to the elements of the substance subjected to the putrescent fermentation. Proust observed that during the de- composition of glute 1 immersed in water, a mixture of carbonic acid and of pure hydrogen gas is disengaged, i phenomenon which 240 MANURES. he explains by the decomposition of the water ; at the same time are produced ammoniacal sahs, among which are acetates and lac- tales, whose acids are generated by the very act of fermentation. As a striking example of the agency of water in the transit of azote into the ammoniacal state in a quarternary compound, we may tak*» the putrefaction of urea. Urea is found in the urine of man and of quadrupeds ; its compo sition, according* to M. Dumas, is : Carbon... 20.0 Hydrogen 6.6 Oxygen 26.7 Azote .••46.7 100.0 The animal substances dissolved in urine, as the mucus of the bladder, &c., undergo, on contact with the air, a modification which causes them to act upon urea like ferments. By their influence the elements of water react upon this substance, and transform it into carbonate of ammonia. Carbonate of ammonia is composed of : Carbonic acid 56.41, containing j Sxy^g^en .'.'." .' !.*.*.*!!*.*!!.' .'.".'.4l!^ and Hydrogen 7. Ammonia 43.59, containing . j Azote 35.90 But 100 of urea have been found to produce by fermentation 130 of carbonate of ammonia. Carbon. Hydrog^en. Oxygen, Aiote. Previous to fermentation, 100 of urea ) 20 00 6 60 2 67 46.7 contains ....}' After fermentation, 130 of carbonate J 2000 10 00 533 46 7 of ammonia contains . . J ' ' '_ '__ Difference 0.0 3.4 26.6 0.0 So that during its transformation, the urea has gained 3.4 of hy drogen, and 26.6 of oxygen. In water the hydrogen is to the oxygen as 1 to 8. (: : 1 : 8.) Now it is precisely in this proportion that hydrogen and oxygfti' are found to be acquired by the urea in passing into the state of ea* bonate of ammonia ; whence it follows that the elements of wave are fixed in the process. The putrefaction of azotized substances is far from always pre- senting results equally precise ; most frequently in decomposing they pass through a series of changes, still very obscure, before they attain their ultimate limit, viz. the production of ammoniacal salts. Thus from putrefying caseum diffused in water, M. Braconnot obtained, among other products and ammoniacal salts, a very remark- able substance which he calls aposepedine. Aposepedine when purified is a white crystalline substance, soluble in water and in alcohol, capable of combination with the metallic oxides ; azote is one of its elements. This substance, although engendered by the act of putrefaction, is rsvertheless itself capable of putrefying and giving birth to the last products of the spontaneous decomposition of azotized matter. One of the most striking characteristics, at least that which is DECAY OF ORGANIC MATTERS. 241 most readily remarked, is the fetid odor which animal substances exhale during putrefaction. It is not always the smell of ammonia which preciominates ; that of sulphuretted hydrogen gas is often very strong ; yet that is not the emanation which is most repulsive : miasmata and nauseous principles are also developed which seem to be the changed matter itself carried away by the gases that are dis- engaged. Sulphur, like phosphorus, is 'almost always a constituent of or- ganic bodies ; its minute proportion, however, would be insufficient to give out the hepatic odor so intense as we often find it during putrefaction. The production of sulphuretted hydrogen is connect- ed with the very curious fact, first appreciated by M. O. Henri, that sulphates dissolved in a medium impregnated with azotized matter in decomposition, do themselves undergo an actual reduction, pass into the state of sulphurets, and immediately give out sulphuret- ted hydrogen, either by the action of the carbonic acid of the at mosphere, or by that which is formed during the putrefaction of the organic matter. It is by a similar action exerted upon sulphate of lime that M. Henri explains the origin of the sulphureous waters of Enghien, near Paris ; and M. Fontan in his important work on min- eral waters has generalized this explanation. The causes of the destruction of sulphates under such circum- stances if^ easily understood. During the decomposition of organiz- ed substances, the carbon belonging to them forms carbonic acid gas ; by combining both with the oxygen of the substances themselves, and with the oxygen of the water, it is probable that the oxygen of the sulphuric acid contributes equally to this formation, and that the sulphur is liberated. The hydrogen of the decomposed water, as well as that of the solid matter, in contact with sulphur in the nascent state, combines with it to form sulphuretted hydrogen, which straightway reacts upon the base of the sulphate, producing from it, as we know, water and a metallic sulphuret. This sulphuret being unable to exist when exposed to the continued disengagement of carbonic acid gas which takes place in the centre of the mass in putrefaction, yields, as a definite result, a carbonate on the one part, and sulphuretted hydro- gen on the other. The faculty which azotized organic bodies possess of undergoing spontaneous decomposition in presence of water, and under the in- fluence of heat, seems to depend upon the tendency which azote has to unite with hydrogen in order to form ammonia. This tendency is perhaps the determining cause of the phenome- non of fermentation taken in the most general acceptation of the term. Organic bodies void of azote decompose less easily, and the kind of alteration which they undergo from the action of water and air, differs in many respects from the putrefaction of azotized mat- ter. Of this the difficulty experienced in effecting the fermentation of vegetable substances is a proof Nevertheless, the vegetable re- fuse which goes to the dunghill, all without exception, contains azo- tized elements, often, it is true, in extremely minute proportions ; 21 343 MANURES. but we Icnow that there is no example of a vegetable organic tissas from which they are completely excluded. The refuse of plants, the most amply endowed with azote, such as cabbage, beet-root, beans, &c., are certainly those which are sus- ceptible of the most rapid and complete putrid fermentation ; straw, on the contrary, when alone, undergoes it slowly and imperfectly, the small quantity of the azotic principle which it contains is chang* ed, and reacts upon the ligneous particles which surround it ; but the effect is soon arrested, and even ceases entirely, unless substances richer in azote concur. The woody matter of the straw is exactly in the condition of sugar which has not had a dose of ferment suf- ficient for its total transformation into alcohol. Most organized substances, whether they belong to the animal or vegetable kingdom when placed in certain conditions, undergo the profoundest changes from the action of hydrogen ; these alterations ought to be studied with all the more care, because in practical agriculture we are interested successively in fostering or preventing the causes which produce them, according as our object is to accele- rate the decomposition of vegetable refuse for manure, or to adopt the precautions which experience suggests, in order to preserve the produce of our harvests unchanged. Organic substances moist- ened and exposed to the air under a temperature, the minimum of which (I believe after several experiments) may be fixed at 48° or 50" F., seize upon the oxygen and absorb it, in part, in order to form water with their hydrogen, and carbonic acid with their carbon. When these substances are accumulated in a mass sufficiently great, the heat produced is not rapidly dissipated, the temperature rises, and promotes the reaction to such a degree as to produce active burning, a conflagration, in place of the slow combustion manifested at first. It is not very unusual to see hay, which had been gathered in too damp a condition, take fire in the stack ; and the high temperature acquired by wet rags placed in the fermenting vats of paper mills, and the copious production of carbonic acid which results, show that we are right in assimilating this kind of action to the phenomenon of combustion. This sluggish combustion is not peculiar to azotized organic substances : it takes place equally in those destitute of azote. The alteration of organic matters, the combustion which goes on at a low temperature by the action of the air, difi'ers in its results from the decomposition which is effected in the midst of a liquid mass. We have seen, for example, that gluten fermenting under water, disengages hydrogen gas. Now Berthollet has established, and Saussure has confirmed his observations, that an azotized body in putrefaction, the whole of whose parts are in contact with the air, never contributes either hydrogen gas or azote to the confined at- mosphere in which it is placed ; and on the other hand, Saussure has shown, that organic substances which do not emit hydrogen gas during their spontaneous decomposition in a medium void of oxygen, do not alter the volume of an atmosphere of which this gas forms a purt; on the contrary, these sub tances condense oxygen as soon af DECAY OF ORGANIC MATTERS. 243 they attain that stage of their alteration in which they give out hy drogen. In pursuing with persevering sagacity the study of putrefaction, M. de Saussure discovered the cause of this condensation ; it con- sists in the fact, that an organic suhstance in course of spontaneous decomposition, acts in some respects like the platina sponge placed in a mixture of oxygen and hydrogen gas ; we know that platina recently heated and introduced into a mixture of these two gases, determines their union in the proportions required to constitute water. Nowr by substituting for the metal some moistened seeds, previously deprived of their germinating faculty, the same effect is produced : the two gases combine until one of the two entirely disappears. When this combustion of hydrogen, proceeding from the decomposi- tion of organic substances, takes place in the body of the atmosphere which contains azote, it is possible that a minute quantity of ammonia may be produced together with water ; nor is it going too far to suppose, that manures very slightly azotized, take up azote from the atmosphere during their fermentation; that during the act of vegetation itself, the hydrogen proceeding from the decomposed water, or yet more, that which makes part of the essential oils form- ed by plants, may, in oxidating afresh, introduce atmospheric azote into their composition. Dead organized matter, such as wood, straw, or leaves, exposed to wet, and for a long time to the action of the air, ends by becom- ing transformed into a brown substance, which when damped is al- most black, which falls to powder when dry, and which is commonly known by the name of humus or mould. This is, so to speak, the last term of the decomposition of organic matter ; mould appears to belong already to the mineral kingdom ; and whatever may be the diversity of its origin, it presents a suf- ficient number of peculiar characteristics to be considered a distinct substance. In fact, the atmosphere continues to exert its action upon mould ; its inflammable elements are dissipated by a slow and imperceptible combustion, giving place to water and carbonic acid. But in this ulterior decomposition, those fetid products which char- acterize putrid fermentation are no longer observed. Wet saw-dust, placed for some weeks in an atmosphere of oxygen, forms a certain quantit}' of carbonic acid, and the volume of the gas does not perceptibly diminish. The wood at the surface acquires a deep-brown color. Several experiments made by Saussure, prove that dead wood does not absorb the oxygen gas of the atmosphere ; it transforms it into carbonic acid, and the action takes place as if the carbon of the organic matter alone experienced the effects of the oxygen ; for the gaseous volume remains the same. The loss, how- ever, undergone by the ligneous fibre, during its exposure to the air, is greater than it ought to be if carbon alone were eliminated : whence Saussure concludes, that while the woody matter loses carbon, it also lets some of its constituent water escape. As a consequence of these observations, the relative proportion of carbon ought to augment in the humid wood changed by the ac S44 MANURES. tion of the atmosphere, since we have established that by this action the woody fibre suffers loss in the elements of water besides what it loses in carbon. This is confirmed by the following analyses. The first, made upon some oak wood, previously purified by washing ia water and in alcohol, we owe to Messrs. Thenard and Gay-Lussac; the succeeding one to Messrs. Meyer and Will : Oak wood. Id. rotten. Id. rotten. Carbon 52-5 .53.6 5«.2 Hydrogen and oxygen, water ■•47..'> 46.4 43-8 100.0 100.0 100.0 Wood decomposed under water, without being in direct contact with the air, undergoes a different modification ; it is blanched in- stead of blackened, and the carbon far from increasing is diminished. Saussure thinks that this kind of alteration depends mainly on the loss of the soluble and coloring principles of the wood, principles containing more carbon than the ligneous matter itself: so that pure woody fibre exposed wet to the action of the air would yield pro- ducts analogous to those which result from its decomposition under water. The damp linen rags which are fermented in paper manufactories afford a product which is white, and but slightly coherent. The mass, which heats successively during the operation, loses about 20 per cent, of its original weight. This is exactly what takes place in wood decayed by the alternate action of water and air, namely, it becomes white and extremely friable. Some oak arrived at this stage of decomposition contained, ac- cording to Liebig : Carbon 47-6 Hydrogen 6.2 Oxygen 44.9 Ashes 1.3 100.0 Compared with the composition of oak wood when sound, thesd numbers show that during its modification the wood has lost carbon, and that it has gained hydrogen. The elements of water must ne- cessarily have intervened, and become fixed during the reaction. Ligneous fibre decaying under water is not thereby completely pro- tected from the atmosphere. Water always holds some air in solu- tion, and the oxygen of that air reacts exactly as if it were in the gaseous state. Upon all the phenomena of decomposition connected with fermen- tation, with putrefaction, or with dilatory combustion, heat exerts an influence which has certainly not been sufficiently appreciated. Organic bodies sunk in a large mass of water are not exposed to changes of temperature so various and abrupt as when they are placed in the atmosphere ; their decomposition is more gradual, more uniform, and the soluble materials which they contain, or which are the result of the alteration they are undergoing, are in a great measure dissolved. Temperature may also produce great difference! DECAY OF ORGANIC MATTERS. 24S m the final lesiilt of the decomposition. Peat, which is derived, aa we know, from the slow decomposition of submerged plants, does not appear to be formed in the swamps of warm climates ; it has, per- haps, never been encountered in the stagnant waters of the equinoc- tial regions ; there the woody fibre appears to be totally dissipated in carbonic acid gas, and in marsh gas, the probable source of the insalubrity of those countries. Lakes with peat bottoms are not found except on the very high table-lands of the Andes, in localities where the mean temperature does not exceed 49° or 50° F. The alkalies are powerful agents in the decomposition of certain organic substances, whether in determining or in accelerating it. There are some, indeed, which experience no change without their intervention, whatever may be the other conditions favorable to de- composition. Thus, according to M. Chevreul, many coloring sub- stances may be preserved in solution almost indefinitely, without change, in contact with gallic acid ; but the presence ot a very small quantity of free alkali suffices for their immediately acquiring the power of absorbing oxygen, and at the same time of acquiring a brown tint. M. Chevreul observed that 3.087 grs. of hematine dissolved in potash will absorb 3.857 grs. of oxygen in forming 0.925 of car- bonic acid. The oxygen which enters into the carbonic acid, there- fore, represents nothing like the quantity which was fixed by the solution, and it is almost certain that this gas likewise reacted upon the hydrogen of the coloring matter. The use of the alkalies for accelerating the destruction of organized matter has been long known to agriculturists. Straw, fern, and the ligneous parts of plants are sometimes strat- ified with quick-lime, in order to facilitate their disintegration, and consequently their decomposition. The utility of this old practice cannot be disputed while confined within certain limits ; but it is often abused ; for it is beyond doubt that alkalies mingled indiscrim- inately with manure become in reality more injurious than advan- tageous for the end proposed in their introduction. The appearance of a certain brown substance, little soluble in water, but easily dissolving in alkalies, is a characteristic proper to all vegetable matter under decomposition ; a characteristic which becomes more marked as the decomposition advances towards its last stage, namely, the production of humus. This substance is ulmine, which, on account of some acid properties which it pos- sesses, is also named ulmic acid. It forms a part of mould, and M. P. Boullay constantly found it in the water of dunghills. In 1797, Vauquelin discovered ulmine united with potash in the matter of the exudation from the ulcer of an elm-tree. In 1804, Klaproth confirmed this observation. M. Braconnot succeeded in obtaining ulmine artificially by subjecting woody fibre to the action of alkalies. This substance is easily procured by carefully heating in a silver capsule, and continually stirring a mix- ture of equal parts of potash and of saw-dust slightly damped. At a certain time the woody matter softens and suddenly dissolves ; the mass then begins to swell up, and the fire is slaked. The product 3i* 246 HUMTTS. obtained dissolves almost totally in water. The solution is of a very deop brown color, and contains as prinjipal ingredient ulmine com- bined with potash ; the ulmine is precipitated by the addition of a sufficient quantity of weak sulphuric acid. After having been washed and dried, ulmine is black and brittle, and resembles jet ; while still wet, it reddens turnsole paper, and its solution in potash forms with several sahs, and by the way of double decomposition, insoluble ulmates. M. Peligot assigns to ulmine the following composition : Carbon 72.3 Hydrogen 6-2 Oxygen .-21.5 100.0 Dunghills, rotten wood, and mould, always contain a brown sub- stance, which possesses properties very similar to those which char- acterize ulmine obtained by the action of alkalies upon ligneous fibre. Mould which contains this ulmine in abundance, and in the con- dition most favorable to vegetation, ought on that account to be examined with attention. Its history has, indeed, been so ably traced by M. de Saussure, that science at the present day can add but little to the important deductions of the celebrated author of the Re- cherches Chimiques. M. de Saussure defines vegetable mould (humus) to be the black substance which covers dead vegetables after they have been long exposed to the combined action of water and oxygen. His experi- ments refer to mould nearly pure ; that is, separated by a fine sieve from the vegetable remains which are always mixed with it ; to mould which had been gathered on high rocks, or from the trunks of trees, where it could not have been exposed to admixture or to any influence, other than that of the spontaneous decomposition by which it had been produced. All the varieties of mould collected in this way appeared fertile, especially when they were previously mixed with gravel, which supplies support to the roots of plants, and permits the access of the air. That variety, however, must be ex- cepted which was obtained from the interior of trees, and had been formed in such a situation that the rain-water which entered found no free outlet ; the huriius then contained extractive principles, de- rived in part from the living plant, and which seemed to obstruct the pores of the vegetable to which it was applied as manure. In making comparative calcinations in close vessels of different varieties of humus, and of plants similar to those from which they had proceeded, and collecting the charcoal on one hand, and the volatile and gaseous matters on the other, M. de Saussure discover- ed that they contained, for the same weight, a larger quantity of carbon and of azote than the vegetables whence they proceeded. The larger proportion of azote in the humus seems to imply that during their decomposition, vegetables do not throw off this element* but to this cause must be added that which might be connected with the spoils of insects which live in humus. HUMUS. 247 Weak acids have no other effect upon humus than to dissolve out the metallic, earthy, and alkaline elements which it contains. The more powerful acids, such as the sulphuric acid, frequently cause a disengagement of acetic acid. Alcohol scarcely acts upon humus, merely dissolving out of it a few hundredth parts of resinous matter, which probably pre-existed in the vegetable. Potash and soda dis- solve humus almost completely, causing an evolution of ammonia. From this solution, acids throw down a brown, inflammable powder, possessing the characters which we have recognised in ulmine. The ulmine which is separated in this way, is far from corresponding with the weight of the matter treated with the alkalies, which is evidently due to the humus containing principles which are not pre- cipitated from the alkaline solution. A quantity of humus which yielded no more than one tenth of ashes by incineration, only lost one eleventh of its weight under re- peated treatments with boiling water. The humus thus exhausted, was exposed in a moist state to the action of the air for three months, and gave a new quantity of soluble matter under renewed washing with water; and the same effect is constantly reproduced. By ex- posing moist insoluble humus to the air, therefore, a quantity of so- luble extractive matter is formed. This matter, obtained by evapo- rating the water which is charged with it, is not deliquescent ; it yields ammonia on distillation. The watery solution, brought to the consistence of sirup, is neutral to re-agents, and its taste is sensibly sweet. It is familiarly known that the alkaline salts, which enter into the constitution of vegetable juices, but rarely exhibit the reactions that are proper to them ; the plan or the sap must be dried and inciner- ated before their presence can be ascertained. It is the same with regard to the salts contained in humus. Humus, as I have already observed, is the last term in the putre- faction of vegetable organic matter ; its elements have acquired a stability which enables them to resist all fermentation. M. de Saus- sure preserved humus for a whole year in vessels filled with distilled water, and plunged in mercury, without remarking any emission of gas. Still it is unquestionable that the organic portion of humus is. completely destructible when exposed moist to the action of the air; in the course of time it is dissipated, and by and by there remains nothing more than the fixed saline and earthy matters which it con- tained. This fact M. B. de Saussure had already perceived from his observations upon the vegetable soil that occurs in the country between San Germano and Turin. This destructibiliiy of vegetable earth, says M. de Saussure, sen., is a fact without exception ; and as often as agriculturists have proposed to supply the place of ma- nure by repeated ploughings, they have had sad experience of its truth : the soil is gradually impoverished, and fertile fields ultimate- ly become barren. I may add, that the nature of the climate has a vast influence upon the dissipation of the fertilizing principles of the soil, and that Europeans are certainly in error when they object to the superficial ploughings or hoeings which the land ^ commonly M8 nitrificatiopt. receives in tropical countries. It is there well known that too mnch stirring of the soil is i 'ten prejudicial even in irrigated lands, where consequently the bad i ifects cannot be attributed to too great a de- gree of dryness. The information which has lately reached the Academy of Sciences upon the agriculture, of the French posses- sions in Africa, tend to make us perceive that the same cause pro- duces the same effects in Algeria, and that it is not without reason that the Arabs only work their lands that are preparing for grain crops, very superficially. Humus is, in fact, dissipated by a process of slow combustion in the air : in contact with oxygen, it produces carbonic acid, as is proved by the experiments of M. de Saussure. Pure humus, moist- ened with distilled water, confined in bell-glasses placed over me:»- cury, formed carbonic acid, causing the disappearance of the oxygen of the air. The volume of the acid gas formed, corresponded ii volume with that of the oxygen which had disappeared. Humus, therefore, in contact with air, gives off carbonic acid, and the phe- nomenon here still takes place as if carbon were not alone consumed. The loss experienced is greater than that which ought to occur from the quantity of carbon which unites with the oxygen ; and Saussure concluded that there is, at the same time, a loss of the elements of water. The capital fact which results from these experiments of Saussure, the deduction directly applicable to the theory of manures is this : that humus is dissipated when it is exposed to the air, and that during the slow combustion which it undergoes, it is a constant source of carbonic acid gas. To complete the views that may throw light on the part played by manures, I have still to speak of an important phenomenon which occasionally takes place under the same conditions as those that ac- company the decomposition, the putrefaction of animal matters : I mean the spontaneous formation of nitric acid — the occurrence of nitrification as it is called. Nitric acid results from the union of azote with oxygen. Such at least is the constitution of this acid when it is combined in salts ; but in its isolated state, it is always united with a certain quantity of water. It has not yet been obtain- ed, and it appears indeed not to exist, in the perfectly dry or anhy- drous state. The azote, therefore, does not combine directly with the oxygen ; there must be, at all events, the intervention of water, and to effect the union of the two gases by means of the electric spark, the mixture, according to Cavendish, must be moist. Never- theless, the combination of azote with oxygen appears to be singular- ly favored by the presence of earthy or alkaline bases, seeing that in nature the nitrates are met with in a certain abundance ; but the circumstances which determine their formation are still involved in deep obscurity. Three distinct origins may be assigned to the natural nitrates : Ist. certain soils, still indifferently studied, show an efflorescence of nitrate of potash on their surface, or by lixiviation yield large quan- tities of this salt. Such is the gource of the saltpetre which is im- ported from India. PRODUCTION OF NITRE AND NITRATES. 249 According to M. Proust, the soil of certain localities in the neigh- borhood of Saragossa is an inexhaustible mine of saltpetre. I have myself seen, near Latacunga, a short way from Quito, upon a soil formed of trachytic debris, a similar production of nitre taking place as it were under my eyes. 2d. On the coast of Peru, in the desert of Tarapaca, at a short distance from the port of Iquique, and in an argillaceous soil of ex- tremely recent formation, there are numerous stratified deposites of nitrate of soda, analogous to, and perhaps contemporaneous with, the deposites of common salt which are worked upon the same coast, in the desert of Sechura, near the equator. This is, so far as I know, the only instance of a nitrate being dug out of the bowels of the earth as a mineral mass. The nitrate of soda of Tarapaca, reacr.es Europe at the present time in large- quantities, and supplies the place of nitrate of potash in many chemical processes. Various ex- periments have also been made upon the value of the salt as a ma- nure ; but at present these experiments have been very contradic- tory, and further experience seems necessary before any definitive judgment can be come to on the matter. 3d. The greater number of the soils that are exposed to animal emanations — heaps of rubbish proceeding from buildings that have been long inhabited, the soil of stables, cow-houses, cellars, &c., almost always contain a quantity of nitrates. In countries where rain seldom falls, and where consequently these salts, which are ex- tremely soluble, can accumulate in the soil, in Egypt, for example, the ruins of ancient cities are at the present time true nitre-beds. It is with the formation from nitre in such circumstances that we feel particularly interested. The presence of the salt is frequently proclaimed in our agricultural operations ; it is formed during the preparation of our dunghills, in the midst of our cultivated fields, and we discover it in the plants which we gather. We are by so much the more interested in discovering its existence, and in ascer- taining its mode of action, as in the actual state of our knowledge we are still unable to say whether or no nitre is an auxiliary in the phenomena of vegetation, and contributes to the production of the azotized principles which enter into the organization of plants. To have nitrates formed, the presence of azotized organic matter is not sufficient ; it is further necessary that this matter during its decomposition be in contact with alkaline, calcareous, or magnesian carbonates. It has been observed that rocks of a crystalline struc- ture do not nitrify so readily when they are without the substances which have just been named. The calcareous and magnesian rocks which are most favorable to nitrification, under the influence of ani- mal emanations and of vegetables in a state of decomposition, are those which are the least coherent, or which are most porous, such as chalk, tufa, &c. In those countries where the soil does not un- dergo spontaneous nitrification, certain arrangements of circum- stances, known to favor the production of saltpetre, are made : arti- ficial i\itre-Deds are prepared. In the north of Europe where the rocks are 'granitic, m a hut or shed uuilt of wood, a mixture is made 250 THEORY OF THE FORMATION Of NITRIC ACID. of common earth, of calcareous sand or marl, and of wood-ashes. This heap is watered with the urine of herbivorous animals, and the mixture is stirred or shifted from time to time to favor the access of the air ; and with the same view, the workmen are very careful never to beat or press the heap, which is generally from two to two and a half feet in thickness, and usually of the whole length of the hut or shed. Experience has shown that the process of nitrification goes on best in the shade. In Prussia, the practice is to wet vi'ith the water of a dunghill a mixture composed of five parts of vegeta- ble earth, and one part of wood-ashes and straw. With this kind of mortar, solid walls or masses from twenty to four and twenty feet in length, by about six feet and a half in thickness, are built, rods of wood being introduced during the construction in eonsidera- ole numbers, and in such a way that they can be pulled out w^hen the mass has acquired sufficient solidity ; by this means it is obvious that a very free access of air is secured to the interior of these litre walls, which are always built in damp places, and thatched over with straw to preserve them both from the sun and the rain. The mass is watered from time to time, and after the lapse of a year, '.he materials are held sufficiently impregnated with saltpetre to be ivorth lixiviating. In these artificial nitre-beds we perceive the object to be, to com- )ine the circumstances under which the nitrates are formed in the oil of stables, and in the cellars of human habitations. Organic A latters, rich in azote, are, in fact, brought into contact with earthy . kaline carbonates. The necessity that is felt in the arrangement c * nitre-beus for the introduction of substances of animal origin, L \ds us to presume that the greater part of the nitric acid which is pioduced, is derived from the azote of these substances. But whether tliis azote combines with the oxygen of the air, or with the oy.ygen of the organic principles, we do not know — we are still ig- norant of the way in which the acidification is effected. Professor Liebig, setting out from the fact that azotized organic substances always produce ammonia during their putrefaction, and next perceiving that during the combustion of ammoniacal gas, mixed with a large excess of hydrogen, there is always oxidation of the azote, concludes that nitrification is the result of the slow com- bustion of the ammonia which is the product of the azotized matters in progress of decomposition. The azote of ammonia is indeed oxidated under favor of divers conditions which it is easy to secure. In burning animal substances by means of oxide of copper, it is well known how many precautions must be taken to prevent the appear- ance of nitrous acid ; and on the contrary, by taking measures to favor th.>, production of this acid, for example, by passing a current of ammoniacal gas over peroxide of iron or manganese in a red hot tube, abund.ince of nitrate of ammonia is obtained. The same re- sult follows exposure of a mixture of oxygen and ammoniacal gas to the action of incandescent spongy platinum. The determining cause of the acidification of the azote, which forms an element of the ammonia, is probably due to this, that during the combustion two DETECTION OF NITRATES IN THE SOIL. 251 bodies are formed which are capable of combining immediately : nitric acid, on one hand, and on the other water, without which this acid could not exist. The phenomenon, however, only takes place in this instance at a considerably elevated temperature. At ordi- nary temperatures, combustion of the elements of ammonia has not, as far as 1 know, yet been observed ; and in a series of experiments which I undertook, proceeding all the while upon ideas completely in conformity with those advanced by Liebig, I did not succeed in forming any nitrates by enclosing mixtures of chalk, potash, «&c., in an atmosphere composed of oxygen and ammoniacal vapor. In a communication made to the Academy of Sciences, M. Kuhl- man announces that he had ascertained the presence of nitrate of ammonia in the products of the putrefaction of animal matter. If this announcement be confirmed, if nitric acid be in reality one of the numerous products of the putrid fermentation, the nitrification of soils in contact w-ith organic matters would be readily explicable. I must say, however, that I have sought in vain for nitrate of ammo- nia in the product of the putrid fermentation of caseum. And after all, we should still be at a loss to account for the formation of nitre in many places, where it appears to be produced in the absence of organic matter, as in the saltpetre soils of India, South America, and Spain. Dr. John Davy, who visited the nitre districts of Cey- lon, and Proust, who long inhabited the Peninsula, have given it as their opinion that the nitre appears in soils which contain no vestiges of organic matter. The assertion of Proust, however, is open to suspicion, inasmuch as in his memoir he affirms that the lands close to those that produce the nitre are extremely fertile, so that they yield abundant crops without ever receiving manure. But at the present day, it is a law that every fertile soil must contain or receive dead organic matter. In Ceylon, according to Davy, the caverns, the walls of which become covered with an efflorescence of salt- petre with such rapidity, have a fertile and thickly wooded soil lying over them, the percolations from which may readily penetrate their interior. The observations which I had an opporti' lity of making upon the nitre soils near Latacunga, were not perhaps of sufficient precision ; but I think I can affirm that the soil was not without hu- mus : patches were perceived here and there that were covered with turf It must still be admitted, however, that in the localities which have been particularly indicated there must exist some peculiar and permanent cause of nitrification ; inasmuch as in other and fertile soils, saltpetre only appears as it were accidentally, and never in extraordinary quantity. Whatever the value of the ingenious but still very imperfect theo- ries of nitrification, it is still of importance to ascertain the exist- ence or absence of nitrates in the soil. Wollaston recommended a process which enables us to do this very readily. It is founded on the property possessed by the aqua regia — a mixture of the nitric and hydrochloric acids — to dissolve pure gold, which, as^is familiarly knuwn, resists the action of either of these acids applied separately. The soil in which the presence of a nitrate is suspected ie treated 252 FARM-YARD DUNG. with boiling distilled water, and thrown upon a filter. The filtered fluid is reduced by evaporation to a very small quantity, which is then poured into a test tube, and a little pure hydrochloric acid is added ; some particles of leaf gold are then introduced, and the fluid is stirred with a glass rod. If any nitrates have been present, the particles of gold are speedily dissolved. Having now described the circumstances which determine, and the phenomena which accompany the decomposition of dead or- ganic matter, I have next to treat of manures in particular, of their preparation, of their application, and of their relative values. Speaking generally, the manure which is derived from the dejec- tions of animals, supplied in a farm-yard with abundance of food and of litter, used with the double object of cleanliness and health, is the best of all. The principal substances which contribute day by day to increase the mass of our dunghills are straw, and the ex- cretions and urine of horned cattle, horses, hogs, &c. These va- rious substances, besides the organic elements which enter into their composition, further contain the various mineral substances which are indispensable to the development of vegetables. Animal excre- ments of every kind, in fact, when they are burned, leave quantities of ashes which are frequently very considerable, and in which are encountered the same saline and earthy ingredients that pre-existed in the forage with which the animals were supplied. Excrements, therefore, necessarily vary in their composition according to the kind of food that is consumed, and the nature and the state of health of the animal which produced them. Those of the herbivora have never been sufficiently examined. Thaer and Einhof have merely ascertained that cow-dung contains an extractive principle, partly coagulable by heat, and that remains of the food may be separated from it. All excrementitious matters, in fact, contain a certain quantity of the alimentary matter which has escaped digestion, especially when animals are abundantly supplied with food. Some albuminous matter is also found there ; but the substance after vege- table remains that appears to predominate is bilious.* We know that after mastication, the food, mingled with saliva and the secretions of the mucous glands, passes into the gullet, and from thence into the stomach. There it imbibes gastric juice, turns sour, becomes modified, and is finally converted into a kind of pulp which is called chyme. Once formed, chyme passes into the small intes- tines, where it encounters the bile and pacreatic juice, which modify it, and cause it to separate into chyle, which is absorbed by the ves- sels of the bowels, and excrementitious residue, which descends into the large intestines, where it becomes a fetid mass that is expelled from time to time by the animal. * The latest inquiries of the physiological chemists would lead us to suspect that this was not the case. Bile ought only to be an occasional, and even an unnatural constituent of animal excrement, if these views be well founded. It seems that the elements of bile added to the elements of starch supply the precise elements of fat ,• a BUbstnnce so abundantly formed in the process of digestion. The bile that is poured Into the upper part of the uUiucnUry cauul is probjOiiy all usod up in forming Ikt— Sack Ed. MANURES — URINE. 258 The bile which accompanied the fecal matter is secreted by the liver, and is familiarly known as a viscid, bitter fluid bf a yellowish green color and a peculiarly nauseous odor. According to M The- nard, the bile of the ox contains : — Water 700 Picromel* 69 Fatty matter 15 Soda, phosphate of soda, chlorides of potassium and > ,« sodium, sulphate of soda j ^" Phosphate of lime, oxide of iron 1 Urine is a liquid secreted by the kidneys from arterial blood ; it passes into the bladder by the ureters. Its composition varies ac- cording to the animals which produce it. Urea is its most charac- teristic principle ; and in the water which it always contains in large proportion, various saline substances and animal matter, which is re- garded as mucus of the bladder, are encountered. The urine of the horse, according to M. Chevreul, contains carbonate of soda, of lime, and of magnesia, sulphate of soda, chloride of sodium, hippurate of soda, urea, and a red-colored oil. The urine of horned cattle has a similar compositon, with this dif- fer ence, that it is much more watery. In the urine of our cow- houses which had undergone change, I have ascertained the presence of the alkaline carbonates, of common salt, and of the reddish oil mentioned above. Having at various times had occasion to evapor- ate considerable quantities of the urine of the horse, I always ob- served that on coming to the boiling point, a quantity of azotized matter which resembled albumen was coagulated. I also perceived in the urine of herbivorous animals a volatile acid, to which its odor is probably owing. In the urine of the camel, M. Chevreul found the carbonates of lime and magnesia, silica, sulphate of lime, and oxide of iron, in very small quantities ; chloride of potassium, carbonate of potash, sulphate of soda, in small quantities ;* sulphate of potash, in large quantity ; urea ; an alkaline hippurate ; and a reddish oil. The urine of the rabbit, according to Vauquelin, contains carbon- ate of lime, of magnesia, and of potash, chloride of potassium, sul- phate of potash, sulphur, urea, and mucus. The urine of birds is distinguished by the large proportion of uric acid it contains. Food, however, has a great influence upon this proportion ; highly azotized aliments increasing it considerably. Wollaston observed that the excrements of a fowl which was fed * Picromel, discovered in the bile of the ox by M. Thenard, is colorless, and of the consistence of sirup. It produces upon the tongue an acrid and bitter sensation, which rapidly changes to a flavor slightly sugary. The recent researches of Messrs. Tiede- mans and Gmelin have discovered in ox bile substances which had escaped the first in- vestigations. These chemists found : 1st. a subst-ince having the smell of musk, and which is probably one of the causes of the odor peculiar to the excrement of kine; 2d. fatty substances ; 3d. biliary resin : 4th. a crystallized substance called taurine : 5th. biliary sugar, of wliich azote forms one of the elements. According to Messrs. Tiedc mann and Gmelin, the picromel of M. Thenard results from the union of sugar and biliary resin. 254 MANURES THE PUTREFACTIVE FERMENTATIOIf . upon herbage contained only 2 per cent, of uric acid. That of a pheasant fed upon barley contained, on the contrary, 14 per cent. ; and that of a falcon which fed upon flesh alone, yielded scarcely any thing but uric acid. The urine of an ostrich was found by Fourcroy and Vauquelin to contain uric acid in the proportion of about one six- teenth of its mass. I have already given the composition of urea. Hippuric acid is an azotized acid which is readily obtained by adding a little hydro- chloric acid to the fresh urine of the horse reduced by evaporation to about one tenth of its original volume, when a granular crystalline mass is precipitated. If the urine have been stale instead of fresh, benzoic acid and not hippuric acid is obtained ; benzoic acid was, in fact, long admitted as one of the elements of the urine of herbivorous animals ; but it is derived from the transformation of hippuric acid into benzoic acid and ammonia, the change being produced by con- tact with the organic matters which putrefy so quickly in urine. Liebig was the author of this observation; it was in operating upon unchanged urine that he discovered hippuric acid. The following is its composition : — Carbon 60.7 Hydrogen .5.0 Oxygen 26.3 Azote 8-0 100.0 Uric acid has not yet been met with in the urine of mammiferous herbivora ; but it exists in that of man, having been first discovered in calculi from the bladder ; whence it received the name of lithic acid. Liebig's analysis shows it to be composed of : — Carbon 36.1 Hydrogen 2.4 Oxygen 28.2 Azole 33.4^ lOO.O The litter most commonly used to absorb the urine of stall-kept animals is wheat straw, which consists in principal part of lignine or woody fibre : like all vegetable tissues, however, it contains an azotized principle, and substances that are soluble in caustic alkalies. In the ashes of straw, we have indicated silica as abundant, and va- rious alkaline and earthy salts. The proportion of azote appears to vary in t|ie ratio of from 3 to 6 per 1000. An analysis which I made of dry wheat straw gave the following elements : — Carbon 48.4 Hyilrogen 5.3 Oxygen 38.9 Azote 00.4to0.6 Ashes 07.0 100 Agriculturists have, in all ages, admitted that the most powerfu. manures are derived from animal substances, an opinion or rather a fact, which, expressed in scientific language, anounts to this, that MANURES LVALUE OF AMMONIACAL SALTS. 255 rtie most active manures are precisely those which contain the largest proportion of azotized principles. It is obvious indeed from every- thing which precedes, that all the substances which contribute to form farm dung, contain azote ; and that into many of them, such as uric acid, hippuric acid, and urea, this element enters very largely. When we consider the immediate changes which all highly azo- tized substances undergo in the process of putrefaction, we can fore- see that in their transformation into manure, they must give origin to ammoniacal salts ; and well-established facts prove beyond d.oubt that salts, having ammonia for their base, must be ranked among the most powerful of all the agents in promoting vegetation. It is sufficient, for instance, to bear in mind that in the productive hus- bandry of Flanders, putrid urine is the manure that is employed with the greatest success ; but we have seen that by putrefaction, the urea of the urine is entirely changed into carbonate of ammonia. The fields of Flanders are consequently fertilized with a solution of carbonate of ammonia in water. Along a great extent of the coast of Peru, the soil, which con- sists of a quartzy sand mixed with clay, and is perfectly barren of itself, is rendered fertile, is made to yield abundant crops, by the application of guano; and this manure, which effects a change so prompt and so remarkable, consists almost exclusively of ammoniacal salts. It was with this fact before me that in 1832, when I was on the coasts of the Southern Ocean, I adopted the opinion which I now proclaim in regard to the utility of the salts having a basis of ammonia in the phenomena of vegetation. I have stated my views on this subject in a memoir published in 1837.* Previous to this publication, however, M. Schattenmann, one of the most ingenious manufacturers of Alsace, had already directed the attention of hus- bandmen to this important matter, by reminding them that it is the custom in Switzerland to add sulphate of iron or green vitriol to the urine-vats, for the purpose of changing the carbonate of ammonia into the sulphate, and thus obtaining a fixed instead of a highly vola- tile salt, liable to escape and to be lost. In a communication made in 1835 to the agricultural association of Bauchsweiler, M. Schat- tenmann announced positively that the drainings from dunghills thus prepared, applied upon meadow lands, produced very grea effects. Such, to the best of my knowledge, are the practical facts whicK establish the useful influence of ammonia on the growth of plants far better than the experiments of the laboratory could have done. Nevertheless, it must be acknowledged that long before the dates above quoted, Davy had shown that water containing s^oih of car- bonate of ammonia is singularly favorable to the growth of wheat, far more so, under circumstances exactly similar, than the hydro- chlorate and the nitrate of the same base ; and this influence, it is important to observe, Davy ascribed to the fact that carbonate of aimnonia contains carbon, hydrogen, oxygen, and azote ; in a wcrd, * Annates de Chimie, t. Ixv. 2e sirie, p. 301. 256 OTANTTEES — PREPARATION OF DtJNG. all the elements that are essential to the organization of plants. The illustrious English chemist concluded from his experiments, that the well-known efficacy of soot, as a manure, is due, in part, to the vol- atile alkali which it contains. Professor Liebig, in adopting these opinions, has sought to gener- alize them ; he has attempted to show, by very delicate experiments, that the air which lies immediately over the surface of the ground, always contains carbonate of ammonia, and that the same salt can be detected in rain and snow, and in spring water. The ammonia of the atmosphere, according to Liebig, concars with that which is developed in manures, in the formation of the azotized principles proper to vegetables. These ingenious ideas correspond exactly with those which M. de Saussure made public in 1802, when he ascertained that the gaseous azote of the air is not directly absorbed by plants. " If azote be a simple substance, and not an element of water," says this celebrated observer, " we must admit that plants do not assimilate it, save in vegetable and animal extracts, and in the ammoniacal vapors or other compounds soluble in water which they absorb from the soil, or from the atmosphere. It is impossi- ble," he continues, " to doubt the presence of ammoniacal vapors in the atmosphere when we see that the pure sulphate of alumina, ex- posed to the air, ends by becoming changed into the ammoniacal sulphate of alumina."* In agricultural establishments, in which the importance of manure is duly appreciated, every precaution is taken both for its production and preservation. Any expense incurred in improving this vital department of the farm, is soon repaid beyond all proportion to the outlay. The industry and the intelligence possessed by the farmer, may indeed almost be judged of at a glance by the care he bestows on his dunghill. It is truly a deplorable thing to witness the neglect which causes the vast loss and destruction of manure over a great part of these countries. The dunghill is often arranged as if it were a matter of moment that it should be exposed to the water collected from every roof in the vicinity, as if the business were to take ad- vantage of every shower of rain to wash and cleanse it from all it contains that is really valuable. The main secret of the admirable and successful husbandry of French Flanders may perhaps lie in the extreme care that is taken in that country to collect every thing that can contribute to the fertility of the soil. Our agricultural so- cieties, which are now so universally established, would confer one of the greatest services on the community if they would encourage by every means at their command economy of manure ; premiums awarded to those farmers who should preserve their dunghills ia the most rational and advantageous manner, would prove of more real service than premiums in many other and more popular direc- tions. The place where the dung of a farm is laid ought to be rather noar to the stables and cow-houses. The arrangements may be ♦ Becherches Chimiquos, p. 207. MANURES THE DUNG-HEAP. 257 jraried to infinity, but they ounrht all to combine the following condi- tions : 1st. That the drippings from the heap should not run away, but should be collected in a tank or cistern under ground ; 2d. That iio water, except the rain which falls on the dung-heap, or any wa- ter that may be thrown upon it on purpose, should be allowed to drain into this reservoir ; 3d. That the place for the dunghill be of size enough to avoid the necessity of heaping the manure to too great a height. The ground upon which the dung is piled ought to slope gently one way or another — from each side towards the centre is best — so that the drippings may be collected in the tank or cis- tern. It is also desirable that the soil underneath should be clayey and impermeable ; where it is not so, it becomes necessary to pud- dle, to cement, or to pave the bottom of the dunghill stance as well as the bottom and sides of the tank or cistern. The water which runs from the heap should be thrown back upon it occasionally, by means of a pump and hose, so as to preserve it in a state of constant moistness. The opening into the tank, which is best placed imme- diately under the centre of the dung-heap, is closed by means of a strong grating in wood or iron, the bars being sufficiently close to prevent the solid matters from passing through. One very impor- tant arrangement, one which, in fact, must on no account be over- looked, is that the drains from the stables and cow-houses be so contrived, that they all run to the dunghill. The litter, however abundant, never absorbs the whole of the urine, especially at the time when the cattle are upon green food ; and it would be quite unpardonable in the husbandman did he not take measures to se- cure this, the most valuable portion of the manure at his disposal. The litter mixed with the droppings of the animals, and soaked with their urine, ought to be carried from the stables to the dunghill upon a light barrow. The practice of dragging out the manure with dung-hooks, which is often permitted when the field upon which it is to be spread is at no great distance, ought on no account to be al- lowed ; the loss from the practice is always considerable. Materials ought not to be thrown on the dunghill at random or hap-hazard ; they should be evenly spread and divided ; an uneven heap gives rise to vacancies, which by and by become mouldy, to the great detriment of the manure. It is of much importance that the heap be pretty solid, in order to prevent too great a rise of tem- perature, and too rapid a fermentation, which are always injurious. Particular care must also be taken that the heap preserves a suffi- cient degree of moistness, not only of its surface but of its entire mass, which is effected by watering it frequently. At Bechelbronn, our dung-heap is so firmly trodden down, in the course of its accu- mulation, by the feet of the workmen, that a loaded wagon drawn by four horses can be taken across it without very great difficulty. The thickness of the heap is not a matter of indifference : besides the convenience of loading, which must not be forgotten, any great thickness may become injurious by causing the temperature to rise too high ; circumstances occurring which should compel us to keep a mass in this state for any length of time, the decomposition would 22* 258 PREPARATION OF MANURE. make such progress as to occasion very great loss. Experience has shown that the thickness of a dung-heap ought not to exceed from about four feet and a half to six feet and a half; it ought certainly never to exceed the latter amount. With a vievT to prevent the drying of the dung-heap and its con- sequences, too great a rise in temperature and destruction of manure, it is the practice in some places to arrange the dung-heap on the north side of a building, which is undoubtedly advantageous, but not always to be realized, especially in connection with a farm of some magnitude, where the immediate vicinity of a large mass of matter in a state of putrid fermentation is not only unpleasant, but may be unwholesome. In the north of France, the dung-heap is sometimes shaded from the sun by means of a row of elms, and the shelter thus secured is vastly preferable to that which it has been proposed to obtain by means of a roof or shed, which, besides other inconveni- ences, would be found costly at first, liable to speedy decay, &c. If circumstances, such as the smallness of the farm, the permeable nature of the soil, &c., prevent the construction of a reservoir, there is risk of the dung-water being quite lost; but such waste may be prevented by covering the bottom of the pit or stance for the dung- heap with a bed of sand, peat marl, or any other dry and porous sub- stance capable of absorbing liquids. This practice is often followed by the farmers of> Alsace. In some farms, the different kinds of dung are piled apart from one another in particular heaps ; that of the stable being put by it- self, as well as that of the cow-house, that of the hog-stye, and that of the sheep-pen. In great establishments, such a separation is often one of necessity ; but the advantages which are ascribed to it are questionable at least, and the remarks that have been made upon it by writers do not appear founded on any accurate observation. Without denying that certain crops answer better when special ma- nures are employed, it still seems to me more advantageous to pile ■»,very kind of manure together, when the difficiilties of the situation are not such as to make this either particularly inconvenient or ex- pensive. In this way, indeed, a dung-heap of medium constitution is obtained, which is regarded with reason as that, the application of which to the soil is attended with the greatest advantages in the majority of instances. The distinction which seme have sought to make between the relative qualities of manures of different origins is far too absolute ; and this is the reason, without doubt, wliich renders it so difficult to bring the observations of different agricultu- rists to agree. Thus, according to Sinclair, the dung of the hog- stye is the most active of all, the richest in fertilizing principles ; according to Schwertz, on the contrary, it is the most indifferent manure of the farm-yard. The fact is, that manures, which are the produce of the same animals, often present greater differences in regard to quality, than manures which proceed from diferent sources I shall show by and by that the value of manure dfj^ends especially upon the feeding the age, and the condition in which the animal ia placed that pro- PREPARATIOTT OF MANTJRE. 259 iTuces it. It is well known that the dung of cattle, fed during winter upon straw, is greatly inferior to that which they yield when con- suming food of a more nutritious quality. When the litter mixed with animal excrements is accumulated in sufficient quantity in the pit or on the dung stance, fermentation speedily sets in, and abundance of vapor is disengaged. As car- bonate of ammonia is among the volatile products of this decomposi- tion, it is of importance to hold it under control ; this is done by keeping the heap in a state of proper moistness, and in excluding as much as possible the access of air. The daily addition of fresh quantities of litter from the stables and stalls, contributes powerfully to impede the dispersion of the volatile elements, which it is so im- portant to preserve in manure ; duly spread upon the heap, each ad- dition becomes, in fact, a fresh obstacle to evaporation ; it forms a covering which plays the part of a condenser, at the same time that it protects the inferior layers from the direct contact of the air. So long as the dung-heap is kept up and attended to in this way, the fermentation is limited to the inferior layers of the mass. Thaer even satisfied himself that air collected from the surface of a dung- heap, undergoing moderate fermentation, does not contain much more carbonic acid than that -which is taken from the mass of the atmosphere. Neither does a vessel containing nitric acid, when placed upon the fermenting mass, produce those dense white vapors which are a certain indication of the presence of ammonia. The slow decomposition which it is of so much importance to effect, is not readily secured save in masses sufficiently trodden down, and in which the litter of different kinds has been spread as evenly as pos- sible. It is an important point that the manure should be carried out to the field before the upper portions recently added begin to undergo change, otherwise the whole mass enters into full fermentation, and the volatile elements, being no longer arrested by the upper layer, escape and are lost. One means of preventing this loss in any case (which however can but rarely occur) in which there was a neces- sity for suffering the mass to become made through its whole thick- ness, would be to cover it with a layer of vegetable mould, in which the volatile principles would be condensed ; the layer of earth would in fact thus be converted into a most powerful manure. The loss of carbonate of ammonia, during the fermentation of farm-dung, is further prevented by the use of certain salts which have the power of changing the volatile carbonate into a fixed salt. It was with a view of bringing a re-action of this kind into play, that M. Schattenmann, the able director of the manufactories of Bauchsweiler, proposed to add to dung-heaps, in the course of their accumulation and preparation, a certain quantity of sulphate of iron or of sulphate of lime, either of which is decomposed by the carbo- nate of ammonia evolved, and a fixed ammoniacal salt (the sulphate) is produced.* The loss of ammonia from dung-heaps in the course * Annales de Chiniie, 3e s6rje, t. Iv. d. 118 260 PREPARATION OF MAPnJRE. of regulated fermentation, must not however be estimated too hignly ; when the decomposition is carefully conducted, the mass having ^een well trodden and properly damped, the loss is really very small. The gentle fermentation, secured by these means, has characters which differ essentially from those that accompany the rapid putre- faction which never fails to take place when matters are not well managed. As an example of the rapid and injurious fermentation of which I speak, I may cite that which frequently takes place in piles of horse-dung : every one must have seen such dung-hills loosely thrown together, left to themselves, without any addition of water, acquiring a very intense heat in the course of a few days, and have even heard of their taking fire. I have seen piles of this kind reduced to their merely earthy constituents! Such are never the results of the moderate and gradual decomposition which farm- dung ought never to exceed. When the pit or stance is emptied, in which a slow and equal fermentation has taken place, the superior layer is seen to be very nearly in the same state in which it was when it was piled ; the layer immediately beneath this one is chang- ed in a greater degree, and sometimes exhales a slight ammoniacal odor. In the lower strata, the modification is yet greater in degree : the straw has lost its consistency, it is fibrous and breaks into pieces with the greatest ease ; the mass is also progressively darker in color as we go deeper, and on the ground it is completely black ; the smell which this part of the heap exhales, is that of sulphuretted hydrogen, and when it is tested, sulphate of iron is discovered ; no doubt these sulphurous products are all the consequence of the de- composition, under the influence of the organic matter, of the sul phates which were contained in the manure. This is the sign by which I know that farm-dung is duly prepared ; the presence of sulphurets and of the hydrosulphate of ammonia will have no ill effect upon vegetation ; for scarcely is the manure spread upon the ground, than these products are changed into sulphates, and then the manure emits that musky smell which is peculiar to it. Fur- ther, there is no doubt but that the state in which a carefully tended dung-heap is found in the end, is due to the circumstances in which it has been placed and kept during the whole time of its preparation ; its constituent elements would have gone through a totally different course in the progress of their modification had they been left ex- posed to the open air. To be satisfied of this, it is enough to re- mark the powerful and purely ammoniacal smell which meets us in a warm stable, especially during the summer season, upon the ground of which the urine of the animals it contains is left to decompose. From what has now been said, it will be understood how destruc- tive to good manure is the custom which obtains in certain countries of turning dung-heaps frequently, of airing them as it were, in order to hasten decomposition. Treated in this way, stable litter, &c., does in fact decompose much more rapidly ; but it does so, and I own that I do not myself clearly perceive the object proposed by it, %t the expense of the quality ; for it is very evident that the volatile PREPARATION OF MANTJRE. 261 principles must be dissipated and lost in the same propoition as their points of contact with the air are multiplied. The plan of collecting all the litter of the farm into one particular and appropriate place, is that which is generally adopted. Never- theless, there are countries in which the dung is left to accumulate in the cattle- stalls, it being merely covered with fresh straw every day. The ground thus rises continually under *he feet of the cattle, so that it is necessary to have moveable cribs which can also be raised by degrees. This method is so far convenient, that the necessity for cleaning out the stable continually is avoided ; but little is gain- ed in the end in the matter of labor, for the same mass of manure has still ultimately to be removed. The fermentation of the manure would be greatly accelerated by the usual high temperature of the stables, did not the feet of the cattle tread the mass very closely, and this and the daily addition of straw together produce the same effect as I have indicated in treating of the management of the dung- heap out of doors : it condenses vapors and volatile particles, and prevents evaporation. The fact is, that in stalls and stables in which the dung is allowed to accumulate in this way, we are not sensible of any very offensive odor, and the animals which live in them breathe without inconvenience, it being always understood that all communi- cation with the exterior is not interrupted, which in fact it ought never to be, even in cases where the stables and stalls are kept per- fectly clean. This method of proceeding becomes almost impracti- cable when cattle are fed upon food that is not dry, but on the contrary that is extremely watery, such as roots, green clover, &c. ; the quantity of urine that is then passed is so considerable, and the excrements themselves are so copious and so liquid, that an enormous quantity of straw would be required to absorb the liquid parts ; in spite of any reasonable addition of litter, indeed, the animals would still be exposed to be kept in the mire, which would doubtless become a powerful cause of insalubrity among them. In Belgium, according to Schwertz, manure is accumulated in the stables by guarding against the inconveniences which the last mode of proceeding generally implies. The cattle are placed upon a kind of platform raised above the pavement of the stable, and the drop- pings being withdrawn from under them, are trodden down and allowed to accumulate upon the floor. One inconvenience attending the use of straw, is that it is frequently dear ; it is also scarce in some countries. In those parts of Swit- zerland, for instance, where all the available lands are meadows, they are obliged to economize litter as much as possible, so that they even wash it, and thus make it serve repeatedly. Although it would be difficult to give a reason for a practice which has the effect of increasing the bulk of the manure, adding to the expense of transport, and at the same time diminishing its quality ; it is, nevertheless, a fact that this mode of proceeding has been long in use in various Cantons. We probably only see here another means of securing even the last particle of the excrementitious matters passed by cat- tle, the process employed being in fact identical with that us^ed by 262 tiQtriD MAiamK. the chemist in his most delicate analyses. In Switzerland, the urinft that is passed by the cattle flows along a gutter which communicates with a large reservoir containing water, in which not only are the sol- id excrements diffused, but in which the litter is washed, this being tlianged only twice a week. The reservoir is constructed under the floor of the cow-house itself, in order to be protected from the frost. The fermentation of a mass so diluted is scarcely percepti- ble, and, save from leakage, there is no loss of decomposing animal matter. The liquid manure is raised by means of a pump, and car- ried to the meadow in tubs placed upon carls. In Switzerland it is also the usage to employ the urine of cattle separately as manure, under the name of pvrin; to this liquid manure, a quantity of sul- phate of iron is frequently added with the view of bringing the volatile carbonate to the state of the fixed sulphate of ammonia, as I have already said. Liquid manures have their advantages and their inconveniences. We shall immediately discuss their value comparatively with that of solid manures, and we shall be led to adopt the opinion of M. Crud in regard to them, viz., that the advantages ascribed to them in Switz- erland are exaggerated. Whatever the form under which manures are applied, the question has been warmly discussed, whether it be to the interest or disadvantage of the agriculturist to employ them before or after they have undergone fermentation 1 Organic substances, however, are in no condition to favor the growth of vegetables until they have undergone material changes which modify their nature. One of the results of this change, as we have seen, is the development of ammoniacal salts. Fresh ma- nure, such as it comes from the stable, introduced immediately into the ground, there undergoes precisely the same changes, and gives rise to the same producis as it does when subjected to preparation in a dung-heap in the manner already described ; there is only this difference, that being scattered and mixed with a large quantity of inert matter, the decomposition takes place much more slowly than it does in the heap. The question which has been so actively dis- cussed, therefore, reduces itself to this : is it advantageous to have the manure fermented in the soil it is intended to fertilize 1 We may be allowed to express surprise that such a question should have been raised in the present day, and still more that the afl!irmative answer should have been disputed by agriculturists of distinguished merit. Some have even gone so far as to maintain that fresh ex- crements were injurioui to vegetation. Proofs to the contrary are readily obtained ; it is enough to recollect that in the grazing and folding of sheep and ki.ie, the dung and urine pass directly into the ground of our pastures and fields, and who shall say that the land is not benefited by what it thus receives 1 Unquestionably fresh manure in excess proves injurious to vegetables, but as much inay be said in regard to the best-fermented dungs. M. Gazzeri, an Italian chemist, has devoted himself with tr.e most laudable perseverance to inquiries having for thoir object tu I^OW that the general custom of leaving manures to become d«- VALUE OP FRESH AND MADE MANURES. 263 composed before leading them out to the field is attended with a considerable loss of fertilizing principles, and that it is therefore advantageous to use them in the state in which they come from the stable. To remove all doubts which might yet be entertained upon the effects of unfermented manures, M. Gazzeri showed that wheat could be successfully grown in land which had received an extraor- dinary dose of pigeon's dung, which is regarded as one of the most active of all manures; and horse droppings, taiven at the moment they were passed, mixed with earth, in the proportion of one-fourth of the whole bulk, had no injurious effect on the growth of the cereals. To ascertain the amount of loss which fresh manures suf- fered from fermentation, M. Gazzeri placed certain quantities, as- certained by weight, to putrefy under favorable circumstances ; and the decomposition completed, he weighed them again. In this way, he ascertained that horse-dung, in the course of four n.onths, lost more than the half of the dry matter which it contained before its putrefaction. Davy, indeed, had already shown that there is a loss of volatile principles, during the decomposition of fresh manures, that must be useful to vegetation. Davy's experiment consisted in introducing manure into a retort, the extremity of which communi- cated with the soil under turf, and he found that in the course of a few days the grass which was thus exposed to the emanations from the retort, grew with particular luxuriance. Although it appears certain, then, that in conducting the preparation of manure in the heap with prudence, the volatile and ammoniacal principles which appear in the course of the putrefaction may be retained, it is never- theless unquestionable that the employment of manure directly and without previous fermentation, would most effectually prevent the loss of matters that must be valuable. Thaer, Schwertz, Mr Coke, and others, have consequently admitted the advantages of the latter procedure. In agreeing with them completely, which I do, it still remains certain that on the greater number of farms, dung-heaps must be formed as matter of necessity. Manure is only available at certain determinate seasons of the year ; it cannot be carried out and spread as it is produced. In Alsace it is carried out to the fields on which it is to be spread whenever circumstances will permit, and without regard to its more or less advanced state of decomposition. The circumstances which lead to its being kept in the pit for t\\ o or three months, also lead to the manure being half or more than half matured before it is led out ; and this, after all, is perhaps the best state in which it can be put into the ground. It is then easily incor- porated with the soil, and its fertilizing principles are already in that condition which enables them to act, within a limited time, with greater energy than ihey would do were the manure employed quite fresh. This is the condition in which our manures almost always are at Bechelbronn when we carry them out : it rarely happens that they have been three months on the stance before their removal. Speediness of action is a point which is not without importance. Fresh dung will always act more slowly than that which has reach- ed a certain point of decomposition, and the advantage which mostly 264 VALUE OP FRESH AND MADE MANURES. accrues to the farmer in forcing: his crops, will often induce him to use manure that has ripened in the pit or stance. In warm and moist countries, as may be conceived, it is almost matter of indifference whether the dung be put into the ground quite fresh, or in a state of decomposition further advanced ; its decom- position, aided by the heat of the climate, is always effected rapidly enough. But it is otherwise in cold climates, where the tempera- ture which excites and maintains vegetation is often of short dura- tion, and must at once be taken advantage of. During a great part of the year, the ground is so cold that organic substances buried in it are preserved with comparatively little change. Under such climatic conditions, there is no doubt that manures in a state of for- wardness are to be preferred. It is probably from such motives that the extensive use of liquid manures in Switzerland is derived, the action of these being, so to speak, immediate ; and it is with such manure that in Flanders the cultivation of various plants that are of great value in manufacturing processes, is carried on. When the fermentation of manure has been managed discreetly, and all the precautious requisite to prevent the dissipation of ammo- niacal salts and the loss of soluble elements have been taken, there is the immense advantage attending it, besides obtaining immediate action, that a manure is produced of greater value under a smaller bulk and a less weight. The dung-heap often loses a third of its bulk in undergoing fermentation, a circumstance which occasions an important saving in carriage. A like saving may be effected with reference to fresh manures, by drying them in the sun, which I have sometimes seen done ; they are thus reduced to one-third or one- fourth of their original weight, and when the distance to which they have to be carried is great, there may be real advantage in proceed- ing in this way. An objection of some moment made to the use of fresh dung to corn lands is, that it usually contains the seeds of weeds and the eggs of insects which nothing but putrefaction will destroy. This objection of course loses all its weight when the land that is ma- nured is to receive a crop which admits of hoeing ; and the custom which obtains with us at Bechelbronn of using manure in every state of decomposition to the first crop in the rotation, is a guaran- tee that fresh manure is really productive of no inconvenience in practice. Another difficulty pointed out by Thaer, is that of cover- ing in dung so long and full of straw as fresh stable or stall dung. This objection disappears when the manure is laid in furrows formed by the plough, as is done in Alsace, by which means the covering in is effected by a single operation. If opinions are still divided upon the question whether dung ought to be employed before or after fermentation, they are no less so as to the mode of spreading it, and the best periods for laying it on the land. It may be imagined that the conclusion come to upon the first question necessarily influences, the opinions held on the second. Thoge who believe that manure may be advantageously used in the Btate in which it comes from the stables, are altogether indifferent io SPREADING OF MANURE. 265 regard to the times of carryingr it out. They take advantage of every lehiipe moment that occurs for performing this necessary work, which is no trifling advantage ; it is the practice which we folh)w at Be- chelbronn — we carry out our manure as we find opportunity. The lands which are to be manured in the spring have frequently their supply carried out during winter when the frost enables us to get upon them. The dung first shot down in little heaps, at regular distances, is afterwards spread as equally as possible, frequently even upon ti.e snow ; and I have never seen any ill effect from the practice. The custom which some farmers have of keeping dung in large heaps in the field, in order that it may be all spread and work' ed under at the same time by the plough, is certainly objectionable ; the places upon which these heaps have been laid are evidently too strongly ifianured ; no manure, save that which is quite fresh and very long i.i the straw, or which it is proposed to spread immediate- ly in furrows, ought ever to be laid down in large heaps upon the field. The method which I have recommended, of leaving manure spread over the surface of the fields exposed to the weather for several weeks or months, has been severely criticised. By such exposure, it has been said the dung must lose its volatile elements, and the rain must wash out and carry off its more soluble parts. Influenced by such fears, some farmers do not spread their dung until the mo- ment of ploughing it in. Such diversity of opinion among practical men, all personally interested in deriving the greatest possible amount of advantage from the manure they employ, mi.3t not be thought of lightly : when different modes of procedure in agriculture are the subjects of debate, we must not be in too great a hurry to come to general conclusions. Climate is not without its influence in the question which now engages us. In Alsace, experience has pro- nounced in favor of the practice followed ; but in other countries there may be very good reasons for not proceeding in the same way. In Alsace, where the annual depth of rain amounts to 26.7 inches, no more than 4.3 inches fall during the three months of December, January, and February. In a district where a larger quantity of rain falls during the winter, the manure would probably suffer from the procedure followed in Alsace. The quality of the manure must also be taken into consideration. A dunghill which contained a large proportion of carbonate of am- monia, which exhaled a strong smell of volatile alkali, would infal- libly lose in value by any unnecessary or prolonged exposure to the ail ; but the loss becomes insignificant when the manure, by good managemert, is brought to contain but a small proportion of volatile ammoniacal salts, as happens with manures which have received additions of gypsum ; or otherwise, when the dung-heap has been carried out fresh, and at a season so cold that it can be kept without material change until the period arrives for spreading it over or working it into the ground. When the rains are not excessive, the soluble parts of manure spread upon the ground penetrate and remain in its upper stratum, exactly as happens when, instead of 83 266 ELEMENTARY COMPOSITION OF MANURE. being buried, it is spread upon the herbage in full growth. The plan of top-dressing is often of great use, and is another and a prac- tical proof of how little detriment results from leaving manure ex- posed to atmospherical vicissitudes. The procedure by top-dressing has arisen from necessity : it was first resorted to with the view of giving the land an addition to the inadequate dose of manure which it had received before it was sown ; but it has been found to answer so well in many districts, that it has been continued. We have em- ployed it at Bechelbronn upon various occasions, even to hoed crops, and with decided advantage, the main one being, that time was gained for the production of manure. In the district of Marck, the practice of top-dressing lands sowed with winter grain, is rapidly gaining ground; the dressing takes place when the blade is already above ground ; and experience proves that the passage of the wagons over the field, and the feet of the horses and the men, cause no appreciable mischief; all traces of them very soon disappear. Nevertheless it is decidedly better to take advantage of a hard frost, when the land will bear carts, &c., for the performance of the process. This plan, according to Schwertz, is found to answer extremely well in Switzerland, for hemp, and indeed for almost every thing else. In my opinion, top- dressing ought to be viewed as a means of giving the soil, already under a crop, the manure which we had been compelled to refuse it at an earlier period. Still, Thaer assures us, and his authority is always of great weight, that he has loo frequently seen the good effects of top-dressings to beans, peas, and leguminous crops in gen- eral, not to be satisfied of the general advantages of the method, in connectiim with light soils especially, in which the sowing may have been late. The elementary composition of farm-dung is a point which is not undeserving of consideration. I have made repeated analyses of that of Bechelbronn, operating upon it in a medium state of decom- position. The animals which had produced this dung were thirty horses, thirty oxen, and from ten to twenty hogs. The absolute quantity of moisture was ascertained by first drying in the air a con- siderable weight of dung, and, after pounding, continuing and com- pleting the drying of a given quantity in the oil-bath, in vacuo, at a temperature of 230° F. The dung prepared in the winter of the year — 1837-8 contained 20.4 > per cent, of 1838-9 22.2J dry matter. Prepared in summer of 1839 19.6 Medium 20.7 Water 793 Analysis yielded the following results : Ttmei •f preparation. Carbon. Hydrogen. Oxygen. Aiote Aihct. Winter of 1837-8 32.4 3.8 25.8 1.7 36.3 32.5 4.1 26.0 1.7 36.7 38.7 4.5 28.7 1.7 96.4 Bprin«ofl838 36.4 4.0 191 2 4 38.1 1839 400 4.3 27.6 S. 4 25.7 " •♦ 34.5 4J 27.6 2JQ HA COMPOSITION OF FARM-YARD DUNG. 267 On the average, farm-dung dried at 238° contains : Carbon 35.8 Hydrogen 4.2 Oxygen 25.8 Azote ; 2.0 Suits and earths 32.2 100.0 When moist, its composition is represented by — Carbon 7.41 Hydrogen 0.87 Oxygen 5.34 Azoie 0.41 Salts and earths 6.67 Water 79.30 100.0 The constitution of dung-heaps must of necessity vary ; those, however, vvliicii have a common origin do not seem to present very great differences in the proportion of their elements. Thus, horse- dung, in the south of France, yielded, on analysis, in the dry state, 2.4 per cent, of azote. This manure contained only 61 per cent, of moisture. Did we but know the composition and the quantity of the excre- tions passed, in the course of the twenty-four hours, by the various animals which contribute to the production of manure, we should be able to determine approximatively what the elements are which have been eliminated in the course of the fermentation. It would be suf- ficient to compare the elementary matter in the litter, or fresh dung, as it comes from the stable, with that which exists in the fermented or prepared manure. 1 have data which I think sufficient tO" enable me to institute this comparison. It must always be, borne in mind, however, that the analyses which I shall now^ detail were made upon the excrements of a single individual of each kind. It would certainly have been preferable to have had average analyses of average qualities ; but the object I had in view, when I undertook these experiments, was quite different from that which I have nov; before me. EXCRETIONS OF THE HORSE.* The horse was fed upon hay and oats. The urine and the excre- ments together contained 76.2 per cent, of moisture. In twenty-foui hours the excretions weighed — moist, 34.2 lbs. ; dry, 8.1 lbs. Their composition was found to be — In the dry state. Moist ditto. Carbon 38.6 9.19 Hydrogen 5.0 1.20 Oxygen 36.4 8.66 Azote 2.7 4.13 Salts and earth 17.3 4.13 Water " 76.17 1)0.0 100.0 • The size of the horse was rather below the average usual size of farm YiaraaB. tGS *,OMPOSITION OF FARM-YARD DUNt EXCRETIONS OF THE COW. The cow was fed upon hay and raw potatoes. The urine and the excrements together contained 86.4 of moisture. The weight of the excretions, in twenty-four hours, was — moist, 80.5 lbs. ; dry, 10.9 lbs. Their composition by analysis was : Dry. WeU Carbon 39-8 5-39 Hydrogen 4-7 0.64 Oxyfren 35-5 4.81 Azote 2.6 0.36 Sails and earth 17.4 2.36 Water ■ " 86.44 100.0 100.00 EXCRETIONS OF THE PIG. The pigs, upon which the observations were made, were from six to eight months old. They were fed upon steamed potatoes. The urine and the excrements lost by drying 82 per cent, of moisture. The average of the excretions yielded by one pig in twenty-four hours was : moist, 9.1 lbs. ; dry, 1.6 lb. Composition : Dry. Moirt. Carbon 38.7 6.97 Hydiogen 4-8 0-86 Oxygen 32-5 5.85 Azote 3.4 O-Gl Salts and earth 20-6 87.1 Water " 82.00 100.0 100.00 The litter that is generally employed is wheat-straw. This straw, in the condition in which it is used, contains 26 per cent, of moist- 're. Its composition is : Dried. Undriea. * Carbon 48.4 35.8 Hydiogen 5.3 3.9 Oxygen 38.9 28.8 Azote 0.4 00.3 Salt*- and earth 7-0 5.2 Water " 26.0 100.0 100.0 At Bechelbronn each horse receives daily as litter 4.4 lbs. ; each cow 6.6 lbs. ; each pig 4.1 lbs. of straw. To the stables and the cow-houses together are given every twenty-four hours 132.0 lbs. of straw for thirty horses ; 198.0 lbs. for thirty horned cattle ; 06.0 lbs. for sixteen pigs; making 396.0 lbs. of straw, estimated when dry at 292.6 lbs. The composition of the materials which constitute the dung pro- duced in one day are set forth in the following table : COMPOSITION OF FARM- YARD DUNG. 269 ExcretioiiB yieWad ill 24 hours by Wei-ht wlieii dry. Wei-ht in the wet state. Elements of the dry matter. Water Carb. Hydro- Oxygen Azote. Salts & earths. tin^ till! wet mailer Tliiity horses Thirty horned cattle Sixteen pigs Straw used in litter lbs. 245.08 326.36 26.40 292.60 lbs. 1028.28 2416.48 146.74 396.00 lbs. 1 IDS. 94.60 12.32 130.241 «.i.4U 10.12 1.32 41.6815.62 lbs. 89.10 116.16 8. .58 113.74 lbs. 6.60 8.58 0.88 1.10 lbs. 42.46 56.98 5.50 20.46 lbs. 783.20 2089.12 120.34 103.40 The average or mean composition of this mixture may be taken as follows : In the dry state. In the wet state. Carbon. Hydrog. Oxygen. Azote. Salts. Carbbn. Hydrog. Oxygen. Azote. Salt. Water. 42.3 5.0 1 36.7 1.9 14.1 9.4 1.2 8.2 0.4 3.2 77.6 That of the resulting Bung : 1 1 1 1 1 1 35.8 4.2 25.8 2.0 32.2 7.4 0.9 5.3 0.4 6.7 79.3 On comparing the composition of the dung-heap with that of the different kinds of litter collected in a day, little difference is ob- served ; the larger quantity of saline and earthy matters discovered in the fermented manure is readily explained from the additions of ashes incorporated with it, and also by the accidental admixture of earthy matters proceeding from the sweepings of the court, the earth adhering to the roots consumed as food, &c. — refuse of every kind, the residue after cleansing the various kinds of fodder for the stable and stall, &c., all goes to the dung-heap. Lastly, and with reference to the elements that are liable to be dissipated in the state of gas, or which'may be changed into water, the azote is percepti- bly in larger quantity in the prepared manure than in the unfer- mented litter and excretions. This is at once seen on comparing the composition of these two products after the saline and earthy matters have been deducted. The composition of fresh litter, is. That of dung Carbon. Hydrogen. .49.3 5.8 ..52.8 6.1 Oxygen. 42.7 33.1 Azote. 2 3.0 Dung is, therefore, somewhat richer in carbon than litter, and it contains less oxygen. It is the property of lignine undergoing de- composition, that it yields a product which relatively abounds more in carbon than the original matter, in spite of the carbonic acid which is formed and thrown off during the alterations undergone ; this is owing to the elements of water being thrown off in relatively still larger quantity at the same time. Fermented dung contains less oxygen than that which comes from tb^ stable; it ought also to contain less hydrogen: but this analysis does not proclaim. It must be observed, however, that the 23* 270 DURABILITY OF MANURES. quantity of oxygen (4.6,) the loss of which appears would require no more than 0.57 of hydrogen to constitute water ; and this is a quantity which jt is impossible to answer for in experiments made upon such substances without excessive delicacy of tnanipulation. This much may be certainly concluded, viz.. that manure which has undergone preparation contains a larger relative proportion of azote than the substances which have concurred in its production ; and for this reason, it is very probable that upon the whole a very trifling loss of this element is experienced if the fermentation has heen carefully managed, and the manure has been carried out and dis- tributed upon the land before its decomposition is loo far advanced. This conclusion, which I am particularly anxious to establish, is partly explained by the interesting researches of Mr. Hermann, which go to prove that woody fibre in rotting attracts and fixes a quantity of the atmospheric air. Azote is in fact the element which it is of highest importance to augment and to preserve in dung. The organic substances which are the most advantageous in producing manures are precisely those which give origin by their decomposition to the largest proportion of azotized matters soluble or volatile. I say by their decomposi- tion, because the mere presence of azote in matters of organic ori- gin does not suffice to constitute them manure. Coal, for example, contains azote in very appreciable quantity ; and yet its ameliorating influence upon the soil is absolutely null ; this happens from coal resisting the action of those atmospheric agencies which determine that putrid fermentation, the ultimate result of which is always the production of ammoniacal salts, or other azotized compounds favor- able to the growth of vegetables. While we admit the high impor- tance, indeed the absolute necessity of azotic principles in manures, then, we must not therefore conclude that these principles are the only ones which contribute to fertilize the earth. It is unquestionable that the alkaline and earthy salts are further indispensable to the accomplishment of the phenomena of vegeta- tion ; and it is far from being sufficiently shown that the organic principles void of azote play a. merely passive part when added to the soil. But with few exceptions, the lixed salts, water or its ele- ments, and carbon superabound in manure. The element which exists there in smallest proportion is azote, which is the one also that is most apt to be dissipated during the alteration of the bodies that contain it. For these reasons azote is really the element whose presence it is of highest moment to ascertain ; its proportion is that in fact which fixes the comparative value of different manures. Since it is by undergoing modification in the course of their de- composition by putrefaction that those azotized substances which are favorable to vegetation are developed in quaternary compounds, it will be readily understood that all things else being equal, a manure which is completely decompoundable into soluble or gaseous products in the course of a single season, will exert in virtue of this alone the whoie of its uselul influence upon the first crop. It is entirely dififereot if the manure decomposes more slowly ; its actioa upon ti'O STRAW, STEMS, ETC. :271 first crop will be less obvious, but its influence will continue lonjrer. There are manures which act, it may be said, at the moment they are put into the ground ; there are others, the action of which con- tinues during several years. Nevertheless two manures, although acting within periods so different in point of extent, will produce the same final result if they severally contain the same dose of azotic elements, if they are of the same intrinsic value. The durability of manures, the length :f time during which they will continue to exert their influence, is a matter of great impor- tance. It often depends on their state of cohesion, or on their in- solubility, though climate and the nature of the soil have also a marked influence on their decomposition and consequent effects. It }s not easy in the present state of knowledge to predict with cer- tainty how long the beneficial effects of a given manure will con- tinue to be felt ; but we know well enough what will hasten the decomposition of manure, and what will retard this final result, and so apportion as it were the fertilizing principles among the different crops in the rotation. xA.ware of the importance of azote in manures, M. Pay en and I undertook an extensive series of analyses, with a view to ascertain the proportion of this principle in the various mat- ters and mixtures made use of in the improvement of the soil. This labor enabled us to class manures ; and assuming farm-dung as the standard, to refer each to its place in a comparative scale, I shall give the conclusions to which we came in the tabular form ; but be- fore doing this, I think it necessary to premise a few observations upon the several manures, or substances usually employed in prepar- ing manures. Straw, looody stems, haum, leaves, and weeds. The straw^ of corn, the haum and stalks of various plants of farm growth, weeds of allv kinds, and leaves collected in the woods, all contribute to in- crease the supply of manure. Slraio is the article that is generally employed for litter ; its hol- low tubular structure, which makes it apt to imbibe urine, renders it peculiarly valuable for this purpose ; and it at the same time sup- plies a soft and warm bed for the cattle. The weight of the straw used as litter may be doubled by the absorption of urine and admix- ture with excrements ; but it is by its very nature and of itself a manure which is not to be slighted, since it contains from 2 to 6 thousandths of azote. The stems of leguminous plants — bean and pea straw— are much more highly azotiz'ed than the straw of corn ; it is certainly best to consume this article as forage when it is not too woody and hard. As litter it is often unfit to form a good bed for cattle, and should therefore not be so employed alone ; but it presents the t\yofold ad- vantage of adding to the manure a large proportion of azotized prin- ciplesTand at the same time of effecting a saving of straw. At Bechelbronn we have found it very advantageous to mix a certain quantity of the dried stems of the Madia saiiva (gold of pleasure) \»ith both our cowhouse and stable litter. In fttrest districts, the leaves of trees are frequently used aa lit- 1872 LEAVES ^BEAN-STRAW. ter ; they perhaps absorb urine in smaller quantities than straw iloe». but as they are much more highly azotized, they greatly improve the quality of the dung. It is desirable that the materials used for litter should be capable of imbibing a large quantity of liquid ; and these same materials are by so much the more advantageous as the pro- portion of azote which enters into their composition is high. The leaves of trees combine both of these conditions, and are therefore an immense resource in districts where they can be procured in abundance. Where the woods are strictly preserved, the removal of the leaves is generally prohibited ; and it is doubtless injurious to deprive the soil of them in young plantations ; but where the tim- ber is further advanced, the objections to their remi>val are infinitely less, and it is therefore generally permitted to carry them away within certain limits. And when it is seen that from natural causes a great part of the leaves is actually lost to the soil of the forest, the wind sweeping them into the ravines, whence they are carried away by the rains, it is evidently far better to allow the poorer cul- tivators to profit by them. The benefit obtained appears the greater, as the time and labor bestowed in collecting the leaves is not taken into the reckoning. Bean straw, and other stalks of a very hard and thready nature, make but indifferent litter, they are often so hard that they hurt cat- tle : and then their cuticle being impermeable, they absorb little or no urine. It has been proposed to crush them in the mill or to cut them in pieces, but either of these processes is attended with expense. The best thing to do would sometimes be to place them where they would get crushed under the wheels of the farm carts. The use of woody stems of every description would be attended with unques- tionable saving in the useful article of straw, and it must never be forgotten that to economize straw as litter, is to increase the quan- tity of available forage. If, for example, it were possible to reduce to the state of litter the woody stems of the Jerusalem artichoke in places where this vegetable is grown to any extent, the advantages would be very decided ; the quantity of these stalks collected from an acre may amount to from four to five tons ; the pith of which they are almost entirely composed is of a very spongy nature and well fitted to absorb fluids. These stalks are light, and properly bruised, would probably replace an equal weight of straw, first as litter and then as an element of the dunghill, instead of being burn- ed as at present to heat the oven or to boil the copper, which seerns of all methods the worst to derive any advantage from the woody haum, whether of the Jerusalem artichoke, the potato, rape, &c. These substances contain about 4 per 1000 of azote, and are most profitably transformed into manure. We have found that by placing them at the bottom of the dung-heaps, they end by undergoing de- composition ; even the most woody stems of vegetables, indeed, de- compose pretty rapidly when ihey are impregnated with urine and mixed with the droppings of animals. Mere moisture without other addition does not suffice, they then rot with extreme slowness. The green parts of vegetables buried in the ground with the wa- GREEN MANURES. 273 ler they contain, undergo decomposition rapidly ; the best plan of using them as manure would therefore be to plough them in at once, were there not certain objections to this. In the first place it cannot always be done, on account of the season and the crops upon the ground ; and then it might be imprudent to return to the earth the noxious weeds which had just been pulled up, frequently full o/ seeds, which would not fail to make their existence known before long. It is besides often impossible to bring loads of weeds to the farmstead ; the best thing that can then be dont, is to change them rapidly into manure in a corner of one of the fields which has pro- duced them. This is readily accomplished by means of lime ; a bed is first made of the weeds about 14 inches thick, this is ther» covered with a thin layer of quick-lime, from half an inch to an inch in thickness ; another layer of weeds is laid on, and then another layer of quick-lime, and so on in succession. After a few hours the action between the dry lime and the moist herbage begins, and it may be so intense as even to go the length of burning, to prevent which the pile must be covered with earth or with turf, and every means used to prevent the access of air. The process is generally complete within twenty-four hours, and the heap may then be spread as manure. Before proceeding to such an operation, however, it wouM be highly proper to calculate its cost. All depends on the price of the lime and the labor ; and all things considered, I myself much doubt whether the plan could be followed with advantage. Green manures. Under this title I include the green parts of vegetables which form part of our crops, such as the haum of po- tatoes, the outer leaves of carrots, cabbages, beet, turnips, &c. These articles are at once forage and manure, and it is for the hus- bandman to decide in conformity with his position and particular resources whether he ought to bury them at once, or to use them first as food for cattle. From my own experience I should say that the leaves of beet and of turnips, and potato haum were articles which ought only to be given to cattle in cases of necessity. It is generally much better to bury them in the ground immediately after the crop is gathered ; if they be very indifferent food, they are on the contrary excellent manure, superior in quality even to the best farm dung. From the experiments I have made on this subject, I find that the potato tops from an acre of ground may be equal to 6 or 7 hundred weight of that manure presumed to be dry ; and the leaves of the beet, from the same extent of surface, are equal to more than 21 hundred weight of the same manure, also in a state of dryness. It is among green manures that we are to class the sea-weed or marine plants, which in many places are employed for improving the soil. These cryptogamic plants, which abound in azote, have a^fertilizing power superior to that of common dung, a fact which explains the great store which is set in Brittany by the sea-weed that is collected on its coasts. Sea-weed is employed either fresh and as it comes from the sea, or half dried or macerated, or roasted, and even partially Uiraed. It appears to act at once in virtue of the azoiizcd or 874 GEEEN MANURES — SEA-WEED. ganic matters which it contains, of the hygrometric propert'cs which it possesses, and of the saline substances which enter into its com. position. The agriculturists of Brittany have employed sea-weed as manure from time immemorial ; and so have the people oi Scotland and Ireland. In Brittany, the sea-weed is gathered at periods fixed by law. The first gathering, as well as that which has been cast up by the waves, is given up to the poor. The gath- erings then take place at regular intervals by means of a kind, of cutting rake. The sea-weed cut from the rocks is piled upon rafts or thrown into barges, and carried to the shore ; and there is a tiade carried on in the article all along the shores of the channel between Genest and Cape La Hogue, from the Chansey Isles, and from the coast of Calrados. When sea-weed is employed in the fresh state, it is ploughed in as speedily as possible. For those kinds of crops which require made manures, the sea-weed is stratified with dung and so left to ferment. In some places the sea-weed is roasted or imperfectly burned, by which, while a large proportion of the vegetable tissue is destroyed, an azotized product is still left behind. Before burning the sea- weed, it is exposed for a time to the air and the rain, and it is then dried, being frequently turned. In this state, it is even used as fuel in places where wood is scarce. One great advantage in sea-weed which has been particularly indicated, is its total freedom from the seeds of noxious weeds. Aquatic plants which grow in fresh water may also be employed as manure ; the common reed cut and buried green, decomposes rapidly. And here I may mention that to destroy reeds which are often a cause of great annoyance in ponds, Schwertz recommends lowering the water about 16 inches, cutting the plant, and then rais- ing the water to its old level ; the water enters the interior of the Mems and they all die in a very short space of time. Crops which are buried green, for the improvement of the soil, are also to be ranked in the list of the manures which now engage lis. The plan of burying green crops dates from the most remote an- tiquity ; it was greatly recommended by the Romans, and is followed in Italy at the present day. The plants usually grown for the pur- pose of being buried green are colza or colewort, rape, buckwheat, tares, trefoil, &c. The preference, however, is given to one or other of the leguminous plants, such as tares, lupins, &c., plants which appear to have the highest power of extracting azotized prin- ciples from the atmosphere ; and indeed the value of the whole pro cess is founded upon this fact, for otherwise it would be impossible to give any reason for this long accredited mode of improving the soil. This, too, is one of the ways in which fallowing becomes use- ful ; it is not merely the rest which the land thus obtains, it is also benefited by the vegetables which grow upon it spontaneously, which come to maturity and die, leaving in this way in the ground all they had attracted from the atmosphere, or fixed from the water with which they had been supplied. SeedSf Oil-cake. It is in the seed that by fw the largest proper OIL-CAKE MANURE. 275 tion of the ar.otized matter assimilated by vegetables during theit growth is finally concentrated at the period of their maturity. Seeds are consequently very p(»werful manures, and great advantage is taken of them. In Tuscany, lupin seed is sold as manure; it con- tains 3^ per cent, of azote. It is employed after its germinating power has been destroyed by boiling or roasting. The cultivation of the lupin is carried on in districts, the situation of which is such that difficulty would be experienced in exporting more bulky crops. Grains from the brewery would also make excellent manure Were it not generally found more advantageous to use them as food for cat- tle. In some places, however, where there is no adequate demand for them in this direction, they are dried upon a kiln, and are then equal to twice and a half their weight of farm dung; in some places they are actually sold at a proportionate price. The state if divis- ion of grains admits of their being regularly spread. In some parts of England, grains are used in the proportion of from 40 to 50 bushels per acre for wheat or barley.* The refuse of the grape in wine countries contains a large quantity of azotized matter. The decomposition of the grape stones being slow, this refuse answers admirably as a manure for vines. Oleaginous seeds after the extraction of the oil leave a residue which is an article of commerce, and is familiarly known under the name of cake. Oil contains no appreciable quantity of azote ; this principle is contained entirely in the cake, which becomes through this alone most excellent manure. The proportion of azote which cake contains, varies from 3| to 9 per cent. Oil-cake, from its mode of preparation, contains but very little moisture, and consequently of- fers great facilities in the way of carriage ; it may be taken without difficulty to situations whither a load of dung could scarcely be carried. Cake is applied in two modes : 1st. In powder, and by sowing upon the field, sometimes mixed with the seed. 2d. Mixed in water or in the drainings of the dung-hill, in which case the liquid contain- ing the products of the decomposition of the cake is distributed over the land. By putrefaction under water, cake yields a matter of ex- treme fetor, comparable both in point of smell and of effects on vege- tation to human excrement obtained from privies. Although cake, from the large proportion of albumen and legumen which it contains, be an excellent food for cattle, it is still found more advantageous in many districts to use it as manure than for feeding. England imports oil-cake from all parts of the continent. France alone, from 1836 to 1840, exported more than 117,860 tons of the article. Oil-cake has been particularly recommended as manure for light sandy soils. When the soil is clayey and cold, Schwertz recommends a mixture of one part of lime and 6 parts of powdered cake. To me, however, the addition of lime has always appeared a questionable auxiliary in such manures as give rise readily to ammoniacal products, as is the case with oil-cake. For clayey lands, it would perhaps be advisable to employ oil-cake in a statn of ** Sinclair, Agricniture^ vol. i. B76 REFUSE OF BEET AS XTANURE. decomposition and diffused in water ; its effects, I imagine, would not he doubtful. Oil-cake, as a mar.ure, is employed at very different seasons, ac- cording to the nature of the husbandry. It is always well to employ- it in rainy weather. Its effect is always certain, if it comes on to rain two or three weeks after it has been put into the ground. Drought suspends its action ; it frequently happens, indeed, that the first crop shows none of its good effects ; but these never fail to ap- pear in subsequent crops. Schwertz remarks very properly, that this circumstance has led many farmers to overlook the real advan- tages that belong to this manure. Cake, in fact, according to the dryness or moistness of the season, may act as a manure either of difficult or of easy decomposition, and so produce more immediate or more remote effects. In England about 800 weight of oil-cake per acre are commonly applied. Mr. Coke, of Holkham, ploughed in the powdered cake about six weeks before sowing turnips, but it is held more economical and more advantageous to strew it in fine powder along the furrow with the seed. The latter view, however, must not be too confidently acted on by farmers ; the general recommendation to sow the fields with powdered cake, either some weeks before 'or some weeks after putting it in the seed, and when the plants have already sprung, appears to be the right one. We have various ob- servations made by one of our most experienced practical farmers which prove that oil-cake used dry and without mixture often pro- duces the most injurious effects upon germination. In September, 1824, M. Vilmorin, desiring to make a comparative trial of different pulverulent manures, strewed a quantity of powdered colewort-cake upon a piece of red clover. Upon all the parts of the field which had received other manures, applied in the same way, the clover sprung perfectly ; but that which had received the oil-cake continu- ed absolutely naked ; the cake had been employed in the proportion of about 800 cwt per acre. The same result was also obtained in a trial made with vetches and gray winter peas.* Duhamel, refer- ring to similar facts, recommends the cake to be applied ten or twelve days before sowing. In Flanders, from 6 to 7 cwt. per acre is the quantity generally employed for wheat crops, and it is scatter- ed over the surface before winter sets in, when the grain is already above the ground. The pulp of the beet-root vihich has been employed in the sugar manufactories of France and Flanders, is an article which as food for cattle is known not to be inferjftr to the root before it has undergone expression, and it contains nearly the same proportions of sugar, al bumen, &c. It is, therefore, always used as food to as great an ex tent as possible. But the article is kept with difficulty, and the pro duction at times far exceeds the powers of consumption, so that i has to be made into manure, for which it answers excellently. Tin skimmings and dregs which are collected in the process of suga» making, are also available as manure. They contain about the sam< amount of azote or azotized matter as farm dung, and are therefor* • Vilnjorin, in Malson Rnstiin<> vol. i. p. 204. REFUSE OF THE SUGAR-HOUSE, ETC. 277 of similar value. The animal charcoal of the sugar refinery, after it has served its office there, is an admirable manure. It is, in fact bone or ivory-black, mixed with the coagulated blood which has been employed to clarify the sirup by entangling impurities, and a very small quantity of sugar. This mixture, so rich in azotized princi- ples, used actually to be turned into the sewers until the year 1824, when M. Payen showed its value as manure, since which time near- ly 10,000 tons have been annually employed in ameliorating the soil, to the great advantage of practical agriculture. The importance of the trade in this residue of the sugar-house, and complaints of the occasional indiflferent quality of the article, attracted the attention of the department of the Inferior-Loire in 1838, and led to the appoint- ment of an inspector of the manure shipped from the port of Nantz. I may here observe, that in testing a manure it is by no means enough to limit attention to the quantity of organic matter which it contains. The only sure means is to determitie the amount of azote • it is not organic matter, but the amount of azotized organic matter upon which almost alone depends the value of the manure. The residue of the sugar refinery is another of those articles which presents an occasional anomaly in its application, and which must not be left unnoticed. Its eflfect upon the ground has not only been extremely variable, but it has sometimes happened that this manure, laid on very soon after coming from the manufactory, has been found decidedly injurious to vegetation. Kept for some time, for a month or two» in a heap before being applied, its effect has no only been found more certain, but also uniformly favorable. It is not difficult to explain these divers and opposite influences : the sugar contained in the refuse undergoing fermentation yields irst alcohol, and than acetic and lactic acids. Employed in this state, the substance must necessarily prove injurious to vegetation. It is only after it has lain for a sufficient length of time exposed to the air, to have had the animal matter it contains changed into am- monia, and the organic acids engendered saturated with this base, that it becomes truly useful to vegetation. The heap indeed then shows alkaline, not acid re-action.* The residue of the starch manufacturer, the fetid water which is obtained in such quantity in the process of making starch from grain, is a powerful manure, and ought not to be suffered to run to waste. The pulp or residue of the potato which is now produced in con- siderable quantity in the potato starch manufactories, is known to be an excellent article of food for hogs and cattle. Towards the end of the season, however, it is apt to be of very indifferent quality, and green food having by this time come in abundantly, it often goes to the dung-hill. In the dry state, it is worth its own weight of farm dung; wet, 100 of the pulp may be equal to about 131 of farm-yard dung. The water which has served for washing out the starch from the pulp, as in the case of wheat and other grain, coa- tains an organic substance which when dried constitutes pulverulent * Payen and Boussingault, Ann. de Chimie, v. iii. p. 95, 36 seJie 24 278 ANLMAL REMAINS. Taanure that is equal to about half its weight cf: he dry manure prtv pared from night soil, which the French call pc idrette. M. Daillj made a cotnparative trial of these two kinds cf manure, and from actual experiment found that 200 parts of the deposite from th« starch manufactory might be used for 100 of poudrette. Even the water that is used in the manufacture, and from which tlie subsiance m question is deposited, is an excellent manure when thrown upon the ground, a circumstance which is by so much the more fortimate that this water by standing putrefies and throws off' most utFensive ex- halations. By using the liquor to his fields, at once, M. Dailly pre- vents every kind of annoyance to himself and his neighbors, and moreover from his great starch manufactory he realizes in this way an additional profit which he estimates at upwards of jC60 per an- num. Analysis has shown that 100 of this water from the potato starch manufactory represents 17 of moist farm-yard dung. In cider countries, the ■pulp of the apples that have been pressed is always thrown upon land as manure. At Bechelbronu we reserve it for our Jerusalem artichokes ; in Normandy it is thought excel- lent for meadows and young orchards.- Analysis of the pulp of ap- ples grown in Alsace shows that when dry it contains a quantity of azote, which places it on the same footing as farm-yard dung, Sinclair informs us that in Herefordshire the pulp of the cider press is made into good manure by being mixed with quick-lime and turned two or three times in the course of the following summer. Doubtless the addition of lime will hasten the decomposition of the woody matter of the pulp ; but it strikes me that this will take place rapidly enough of itself in the ground without contriving any means of accelerating the process. Animal remains. The remains of dead animals and the animal matters obtained from the slaughter house are powerful manures, which are much sought after in places where their value is properly appreciated. Scraps and the refuse of skin, hair, horn, tendons, bones,. feathers, , -, Laclic acid, and lactate of ammonia \ Mucus of the bladder 0-03 Sulphate of potash 0.37 Sulphate of soda 0.32 Phosphate of soda , 0.29 Chloride of sodium 0.45 Phosphate of ammonia 0.17 Chlorhydrate of ammonia 0.15 Phosphate of lime and of magnesia 0.10 Silica traces Water 93-30 100.00 The phosphates of lime and magnesia which it contains are ex- tremely insoluble salts, and have been supposed to be held in solution by phosphoric acid, lactic acid, and very recently by Professor Liebig, by hippuric acid, which he now states to be a regular con- stituent of healthy human urine. From the interesting inquiries upon urine made by M. Lecanu, it appears that a man passes nearly half an ounce of azote with his urine in the course of twenty-four hours. A quantity of urine taken from a public urine pail of Paris, yielded 7 per 1000 of azote. The dry extract of the same urine yielded nearly 17 per cent. Human soil as commonly obtained consists of a mixture of fecu- lent matters and urine. It may be applied immediately to the ground 292 FLEMISH MANURE. as it eomes from the privy. In some parts of Tuscany it is mixed with three times its bulk of water, and so applied to the surface. I have myself seen night-soil as it was obtained, and without prepara- tion, spread upon a field of wheat without any ill effect : so that the Tuscan preparation may be regarded as a simple means of spread- ing a limited quantity of manure over a given extent of ground. It is in French Flanders, however, that human soil is collected with especial care ; it ought to be so collected everywhere. The reservoir for its preservation ought to be one of the essential articles in every farming establishment, as it is in Flanders, where there is always a cistern or cess-pool in masonry, with an arch turned over it for the purpose of collecting this invaluable manure. The bottom is cemented and paved. Two openings are left : one in the middle of the turned arch for the introduction of the material ; the other, smaller and made on the north side, is for the admission of the air, which is requisite for the fermentation. The Flemish reservoir may be of the dimensions of about 35 cubical yards. Whenever the necessary operations of the farm will permit, the carts are sent off to the neighboring town to purchase night-soil, which is then discharged into the reservoir, where it usual- ly remains for several months before being carried out upon the land. This favorite Flemish manure is applied in the liquid state (mixed in water) before or after the seed is in the ground, or to transplanted crops after they have been dibbled in. Its action is prompt and energetic. The sowing completed, and the land dressed up with all the pains which the Flemish farmer appears to take a pleasure in bestowing upon it, a charge of the manure is carried out at night in tubs or barrels. At the side or corner of the field there is a vat that will hold from 50 to 60 gallons, into which the load is discharged, and from which a workman, armed with a scoop at the end of a handle a dozen feet in length or more, proceeds to lade it out all around him. The vat emptied in one place is removed further on, and the same process is repeated until the whole field is watered.* The purchase, the carriage, and the application of this Flemish manure cannot be otherwise than costly ; we therefore see it given particularly to crops which, when luxuriant and successful, are of the highest market value — such as flax, rape, and tobacco. This manure, the sample of it, at least, which M. Payen and I examined, is of a yellowish green color, and with reference to smell cannot be compared to any thing belter than a weak solution of hydrosulphate of ammonia. This salt is undoubtedly present ; but exposure to the air converts it rapidly into the sulphate of the same base. According to M. Kuhlmann, the quality of the liquid Flemish manure is to be judged of by its smell, its viscidity, and its saline and ^harp taste. By the fermentation which takes place in the cess- pools, which are never emptied completely, the feculent matter, kept for some time there, does in fact acquire a slight viscidity. When solid excrementitious matter predominates in the fermented maaa * Cordier, Agriculture of French Flanders, p. 24a FLEMISH MANURE. 293 its effect upon vegetation is of longer continuance ; but when it is derived entirely from urine, it acts almost immediately after its application. In either case, the effect of Flemish manure does not extend beyond the season ; like all the other organic substances which have undergone complete putrid fermentation, it is a true annual manure. Occasionally, a quantity of powdered oil-cake is thrown into the reservoir. This is either when the manure is supposed to be too dilute, or when there is little night-soil at command. The following, according to Professor Kuhlmann, is an example of the employment of the Flemish manure in a rotation which is common in the neigh- borhood of Lisle, and in the course of which the crops are colza or colewort, wheat and oats. First year. In October or November, the land is manured with farm-dung, which is ploughed in, in the usual way. At this time a dose of the liquid manure, amounting to about 5000 gallons per acre, is applied : a second ploughing is given, and the colewort is planted. Second year. The colza is gathered, the ground is ploughed for autumn sowing ; from 1000 to 1300 gallons or so of liquid manure are distributed, and the wheat is sown. Third year. The wheat stubble is ploughed down at the end of the autumn, and about 1000 or 1100 gallons of the liquid manure per acre are distributed ; the oats are sown in the spring. If cir- cumstances should prevent the application of the liquid manure in autumn, it is laid on in March, and then it has been found that one-fifth iCss will suffice ; but its application at this season is avoided as much as possible on account of the havoc that is made by the passage of horses, carts, and men over the surface of the soft ploughed land. It is with a view to avoid this disturbance of the surface that in many places oil-cake in powder is applied to the fields under colza when the manuring has to be performed after the crop is in the ground. For beet, the dose of Flemish manure is carried the length of from 1300 to 1400 gallons per acre ; but when the root is intended for the manufacture of sugar, liquid manure is sedulously avoided, experience having shown that it has the very worst effect upon the production of sugar, a circumstance which is very easily explained upon ground? that have already been given. The price of Flemish manure at Lisle is 2^c?. for a measure con- taining 22 gallons. In Flanders, it is held that this quantity, which will weigh hard upon 2 cwt., is equal to about 5 cwt. of farm-yard dung. The liquid manure which I analyzed yielded 2 per 1000 of azote. Farm-yard dung, in its usual state, contains as much as 4 per 1000 ; it follows, therefore, that the real equivalent number of Flemish manure is 182, that of farm dung being 100 ; in other words, it would require 182 of Flemish manure to replace 100 of farm-yard manure ; a conclusion that differs widely from that which is usually acted uporn. But it must be observed that from its nature, the Flem- ish manure produces its maximum influence in the course of the -5* 294 POUDRETTE. season in which it is applied. It seems to have no effect oii ihe crop of the succeeding year. Farm-yard dung, on the contrary, only exerts a portion of the whole amount of its beneficial influence in the course of the year in which it is laid on ; it has still something, often much, in reserve for succeeding years. To compare liquid manure with farm-yard dung, with reference to an annual crop, is to compare this manure to the unknown fraction of the farm-yard dung which comes into play in the course of the first year, and from such a contrast no possible inference can be drawn in regard to the rela- tive value of the two kinds of dung. 1 have insisted upon this cir- cumstance, because it is often involved in the estimates that are made of the relative values of the different species of manure ; and because, from losing sight of it, unfavorable conclusions are frequently come to in regard to manures that undergo decomposition very slow- ly ; these manures, nevertheless, acting for a great length of time, produce both a greater amount and a more durable kind of ameliora- tion of the soil. Rapidity of action, in a manure, is undoubtedly a quality that is highly valuable in many cases ; and Flemish manure possesses this quality in the highest degree. Nevertheless, it is also an advantage to possess a manure which elaborates gradually, and according to the exigencies of vegetables, those principles that contribute to their growth, and which suspend in a great measure this elaboration in the course of the winter — which remain during the cold and rainy season in an almost inert condition, when any fecundating matter produced would merely be washed away and lost. These advantages, to which must be added that of breaking up and lightening the soil, are all possessed by good farm-yard manure. They are such, in fact, that this manure, even in Flanders, is still indispensable ; the liquid manures of that country are nothing more than annual auxiliaries. The method followed in Flanders of using night-soil is certainly highly rational ; it is the same as that which is adopted in Alsace, in the neighborhood of towns, with this difference, that our farmers collect no store of the material ; they go in quest of it at the moment it is wanted. It is applied as in Flanders, or it is incorporated with absorbent substances, such as straw, or with other more consistent manures. The night-soil of Paris, which in the course of a year amounts to an immense quantity, is treated in a totally different manner, which appears to be in opposition to the simplest notions of science, of economy, and of all that is conducive to health. I allude to the mode of preparing poudrette. In the neighborhood of Paris there are places appropriated to the reception of the night-soil : it is thrown into reservoirs of no great depth, in comparison with their superficial extent, and of an aggre- gate capacity which is such that they will contain the whole of the products collected by the night-man in the course of six months. These reservoirs are arranged in stages, one above another. Into the upper one are discharged the matters collected in the course of the night. The upper reservoir full, a slu'ce is opened by being pushed partially down, which allows the ir.rre liquid matters to es- POUDRETTE. 295 cape into the second reservoir placed under it. Repeated drainings are effected in this way, and when the second basin is also full, there is a deposition of solid matter as in the first ; the more liquid par- ticles are then let off from the second into the third reservoir, and so on in succession until the last and lowest is attained, from which the liquid used to be turned into a watercourse ; but, of late, these con- taminated liquids have been got rid of by means of what may be called absorbing artesian shafts — deep holes pierced in a dry and porous soil. When the deposite in the first reservoir is held to be sufficiently consistent, it is drained by lowering the sluicd more and more ; no fresh matter is added, the new charges being deposited in another system of reservoirs. The deposite once drained is in the pasty condition ; it is then taken out with the spade, and spread upon au earthen floor which slopes off on either side, and the mass is turned from time to time to favor the drying ; this process, in fact, is con- tinued until the material has become pulverulent. It is then stored under sheds, or thrown up into pyramidal heaps, the sides of which are well beaten in order to enable them to throw off the wet. Poudrette is of a brown color, and weighs nearly 150 lbs. per sack. Put into a retort, and distilled with a heat of from 424° to 930° Fahr., it yields 52.6 of ammoniacal fluid, and 47.3 of dry mat- ter, in which we encounter fixed ammoniacal salts, such as the sul- phates, phosphates, hydrochlorates, &c. M. Jacquemart finds that in 100 parts of poudrette there is 1.26 of ammonia, the greater part in the state of carbonate ; but it contains a quantity of animal matter besides, which, by dry distillation, yields a nearly equal amount of the same substance ; whence it follows that poudrette contains nearly 2^ per cent, of volatile alkali, or 2 of azote. By direct analy- sis, I obtained 1.6 of azote. Poudrette is spread upon the land at the time of ploughing, from 26 to 34 bushels per acre being allowed. On meadow lands it pro- duces very good effects in the dose of about 25 bushels per acre. The disgusting smell of night-soil is, to a certain extent, an obstacle to its general use. This obstacle, however, is only felt in places where agricultural industry, and the manufactures connected with it, are still in a backward state. One remarkable circumstance is, that the disgust which naturally arises from the manipulation of such ar- ticles, has been more especially got over in countries that are justly celebrated for their extreme attention to cleanliness and the easy position of their inhabitants. I quote Flanders and Alsace in proof of the fact. It has been said, moreover, that certain articles pro- duced in soils manured with human excrement contract a smell and taste which give rather unpleasant information of the nature of the manure that has been employed to favor their growth. In the lim- ited circle of my own experience on this subject, I can say that I have observed nothing which favors such a statement. However this may be, Mr. Salmon has succeeded in disinfecting night-soil completely, by mixing it with a kind of animal charcoal obtained by calcining in close vessels a porous earth impregnated with organic^ £96 COMPOSTS. substances. This is the article which is sold under he name of animalized black. Its quality as a manure must depend especially, I might even say entirely, on the quantity of azotized organic matter which enters into its composition. Composts. A great deal has been written, and much has been Baid on the advantages of composts, or mixtures, contrived with a view to the amelioration of the soil. The receipts for these com- posts are very numerous ; they prove that the discovery of a compost is an easy matter, and requires but a small amount of ingenuity. To unite different matters in such a way as to obtain a compound that shall act advantageously, it is only necessary to make it up of sub- stances which of themselves and isolatedl}^ are good manures. But that it is possible to supply the scarcity of manure, to create it in some sort by means of composts, is a subject of dispute. In fact, when we look attentively at the numerous mixtures which have been indicated as leading to this end, we always perceive that the propo- sal amounts to an extension or dilution of some powerful manure with a substance that is either inert or has little activity. This mode of proceeding may have its advantages; it enables us to make a more equal distribution of the manure we have at our disposal, but it actually supplies us with none. Earthy substances almost always figure in composts. Turf-ashes, wood-ashes, marl, and particularly lime, are constant ingredients. Marl may suit certain soils ; lime is a substance of great activity, and which for this reason must be admitted into composts with cau- tion ; it may act in the disintegration of woody parts — of stalks, and stems, and leaves ; but we must be very careful not to follow the recommendation of Schwertz, who would have us throw quick-lime into our privies with the view to bringing the matters there contained into a consistent and readily pulverizable state. By doing so we should infallibly lose the greater part of the principles that are truly useful in the soil. Much mischief and great destruction of manure, indeed, have been the consequence of the insensate and indiscrimi- nate use of quick-lime under all circumstances ; the business is much rather to preserve than to destroy the substances that are used as manures ; the purpose is to fix, not to dissipate the volatile elements which they contain. One great objection to the extensive employ- ment of composts is the amount of labor they require in the repeated turnings which are held necessary in their preparation, and in the large quantity of matter which has to be transported. The following table will be found iseful as giving a comprehen- sive view of the proportion of azote ;ontained in the various kinds of manures which have been partic ilarly examined, and of their equivalents, referred to farm-yard du; g as the standard. MANTJRES. 297 TABLE OF THE COMPARATIVE VALUE OF MANURES DEDUCED FROM ANALYSES MADE BY MESSRS. PAYEN AND BOUSSINGAULT. 1 Azote in Quality ac- Equivalent 100 of matter. cording to state. according to state. Kind of Dung. p. Remarks. s 1 Dry. Wet. Dry. Wet. Dry. Wet. Farm.yar(i dung . . Dung from an inn yard 79.3 1.95 0.41 100 100 1R9 100 Aver, of Bechelbronn. 60.6 2.08 0.79 107 107 94 51 From south of France. Dung wiiter .... 99.6 1.54 0.06 78 2 127 68 Washed by the rain. Fresh, of Alsace. 1838. Wheat straw . . . 19.3 0.30 0.24- 15 60 ^ 167 Idem 5.3 0.53 0.49 27 122.5 367 82 Old Irom environs ol Paris. Ditto stubble. Idem 5.3 ?-^§ 0.41 22 102.5 fi 98 Idem 9.4 L42 L33 73 332.5 137 30 Ditto upper part, ear included. &^*"" : : : : 12.2 0.20 0.17 10 42.5 975 235 Of Alsace, 0.50 0.42 26 105 390 95 Environs of Paris, 1841. Oat straw .... 21 0 0.36 0.28 18 70 542 143 ■i Barley straw . . . n.'o 0.26 0.23 13 57.5 750 174 1 Wheat chaff . . . l-^ 0.94 0.85 48 212.5 207 E i pf Alsace. Pea straw .... 8.5 1.95 1.79 100 447.5 199 22 1 Millet straw . . . 19.0 0.96 0.78 49 195 203 ii j Buckwheat straw . 11.6 0.54 0.48 27 120 361 83 Lentil straw . . .' 9.2 ^•^ 1.01 57 2cO ^^ 40 Dried potato tops . 12.9 0.43 0.37 92.5 453 108 Withered madia stalks 14.3 0.66 0.57 33 142.5 295 70 After seeding. Idem turned under while green . . 70.6 1.53 0.45 79 113 126 89 Before seeding. Dried broom . . . 10.4 1.37 1.22 70 305 142 33 Stalk and leaves. Withered leaves of beet-root .... 88.9 4.50 0.50 230 125 43 80 Of mangel wurzel. Wither*d top & leaves. Ditto of potatoes . . 76.0 2.30 0.55 117 137.5 85 73 Ditto of carrots . . 70.9 2.94 0.85 150 212.5 66 47 Leaves of heather 7.0 i-is 1.74 103 23 Dried in the air. Ditto of pear-trees . 14.5 1.59 1.36 81 5 340 127 29 Ditto of oak . . . 25.0 1.57 1.18 80" 293 125 34 1 Ditto of poplar . . Ditto of beech . . . 51,1 1.17 0.54 66 134 167 ^4 I Leaves fallen in au- 39.3 1.91 1.18 78 294 102 34 1 tumn. Ditto of acacia . . 53.6 1.56 0.72 80 180 125 56 J Box-tree 59.3 2.89 1.17 147 293 68 34 Branches and leaves. Barred clover-roots . 9.7 1.77 1.61 90 402.5 110 25 Dried in the air. Fucus digitatus . . 1.41 72 215 139 46 ) Idem 4o;o 1.58 0.95 81 123 ^ > Dried in the air. Fucus saccharinus . 40.0 2.29 1.38 117 345 85 29 i Idem 75.5 0.54 135 74 Fresh. Burnt sea-weed . . 3.8 6.40 0.38 20 95 488 JS5 Oyster shells . . . 17.9 0.40 0.32 20 80 488 125 Sea shells .... 0.05 0.05 3 13 3750 769 Dried sea shelL« of Dunkirk. Mud of the Morlaix river Trez of Roscoff roads 3.7 0.5 0.42 0.14 0.40 0.13 'i 100 464 100 308 \ Sea sand. Sea-side marl . . . 1.0 0.52 0.51 26.5 128 ^Z '5 Salt cod-fish . . 38.0 10.86 6.70 557 1675 18 6 Cod-fish washed and pressed .... Fir saw-dust . . . 10.0 18.74 16.86 961 4215 10 o-P Dried in the air. 24.0 0.22 0.16 11 40 886 250. } ... Idem 24.0 0.31 0.28 15 57.5 629 174 5 Dried in the air. Oak saw-dust . . . 26.0 0.72 0.54 36 135 256 74 i White lupine seed . Malt grains .... II 3.49 4.51 872.5 1127.5 S nii Tuscan, boiled & dncd Grape husks . . . 3.31 1.71 169 M^ 57 23 Oil-cake of linseed . 13 4 6.00 5.20 307 l.SOO 33 8 Ditto of colewort . . 10.5 5.50 4.92 ^2 1230 35 8 Ditto of Arachis . . 6.6 8.89 8.33 655 2082 5 21 1^ Ditto of madia . . 11.1 5.70 5.06 292 1265 ^ 8 Ditto of sesame , . 6.5 5.93 5.52 304 1378 ^ 71 Oil-cake of hempseed 5.0 4.78 ^ 1052 41 & Ditto of poppy . , Ditto of beech mast . 6.0 5.70 5.36 292 1340 34 7 6.2 3 31 181 828 55 ^f Ditto of walnuts . . Ditto of cotton seed . 6.0 5 59 5-^ ^I 1310 35 3 11.0 4.52 4.02 231 1000 ^ 10 098 MAI4UBES. g .»^"Si. -b:- Equivalent "^ I according to state. KindofDunf. temarki. 1 1 Dry. Wet. Dry. Wet. Dry. Wet. Ditto from refiners . 10.0 3.92 8.54 201 885 50 m Recent fat by means of poplar sawdust. Ditto ditto .... 7.7 0.58 M 30 135 332 75 Fish oil by ditto ditto. Dried in the air. Cider-apple refuse . r,^-^ 0.63 ^•^ 32 147 309 ^ Refuse ofliops . . Beet-root refuse . . 73.0 2.23 0.56 114 140 88 67 9.3 1.26 1.14 64 285 155 35 Dried in the air. Idem 70.0 0.38 64 85 106 Fresh from the press. Process of Dombasle. Squeezed beet-root . 1.76 O.Ol 90 2 lii 4137 Potato refuse . . . 73.0 1.95 0.53 100 131.5 100 76 Potato juice . . . 95.4 8.28 0.38 425 94 23 106 Settled and decanted. Water of the starch - manufactory . . .99.2 8.28 0.07 425 17.5 571 From washing in four Deposite from the wa- volumes of water. ter of ditto . . . 80. 1.81 0.36 92 90. 108 1 111 Drainings from heap. Idem 15. 1.81 L54 92 384.5 .. 1 24 Dried in the air. Solid cow-dung . . Urine of cows . . . 85.9 2.30 0.32 117 80 84 125 3.80 0.44 194 110 51 91 Mixed cow-dung . . 84 3 2.59 0.41 132 102.5 75 98 Solid horse-dung . . Horse urine .... 75^3 2.21 0.55 113 137.5 88 73 79.1 12.50 2.61 6^1 652.5 15i ISA The horse drank but Alixed horse-dung . 75.4 3.02 0.74 154 185 66 1 54 little ; the urine was Pig-dung .... 81.4 3.37 0.63 172 157.5 58 63 thick. Sheep-dung , . . 63.0 2.99 1.11 153 277.5 65 36, (ioal-dung .... 46.0 3.93 2.16 201 540 50 18i Liquid Flem. manure Sl^ 47.5 210 In the normal state. [deiH 0.22 55 , , 182, PoudretteofBelloni. 12.5 4.40 3.85 225 44 loi Dried in the air. Ditto of Montfaucon 41.4 2.67 1.56 137 390 73 % Urine of public vats . 96. 17.56 16.83 900 4213 1 Dried in the stove. Idem ...... 96.9 23.11 0.72 1133 179 Sk 56 Thin, ammoniacal. Animalized black . Idem from the neigh- borhood of Paris . 44.6 1.96 1.09 100.5 272 98 37 Prepared for 11 mouths 42.0 2.96 1.24 151.6 310.5 66 32 Recently made. Idem, called Dutch manure .... 44.1 ^•^ 1.36 127 340 79 i Made at Lyons. Animalized sea. weed 12.1 2.73 2.40 140 600 7 Dried in stove, (from Marseilles.) OfBechelbronn. Pigeon's dung . . 9.6 9.02 8.30 462 2075 21i 5 Guano imported into England .... 19.6 6.20 5.00 323 1247 3U 80 In the ordinary state. Idem 23.4 7.05 5.40 361 1349 28^ 74 Sifted. Do. imp. into France 1L3 15.73 13.95 807 3487 12i 28i Silk-worm litter . . 14.3 3.48 3.29 178.7 827 56 12 Fifth age. Idem 11.4 3.71 3 29 190 822 53 12 Sixth age. Chrysalis of silk-worm 78.5 8.99 1:95 461 485 21i 20J (Jockchafers . . . 77.0 13.93 3.20 714 801 14 13 Dried muscular flesh 8.5 14.25 13.04 730 3260 111 3, Dried in the air. Soluble dried blood . 21.4 15.50 12.18 795 3i As sold. Liquid blood . . . 81.0 2.95 795 736 13i From slaughterhouses. Idem ...... 82.5 2.71 795 580 15' From worn-out horses. Blood coagulated and pressed 78.5 17.00 4.51 871 1128 111 9, Just out of the press. Insoluble dried blood 12.5 17.00 14.88 871 3719 2i Dried in manufactory. blue manufactory . 53.4 2.80 1.31 144 526 7 30i Animalized with blood Meiter's bones . . , 7.5 7.58 7.02 388 26 6 Dried in the air. Fresh bones .... 30.0 5.31 1326 * 7^ As sold by the melters. Fat bones, not heated 8.0 1554 64 Including 0.10 of fat. Dregs of bone g».ue . Glue dregs .... t§ 0.91 5.63 0!53 3.73 A, & ^y 76 11, As sold by the makers. Graves 8.2 12.93 11.88 663 296953 15 3i Animal black of the sugar refiners . . 47.7 2.04 1.06 104 265 96 38 As sent out. Sugar refiner's black 27.7 19.01 13.75 974 3437 103 28 From Paris. From the sugar bakery Scutn from the sugar Enllish'^lack ! '. '. 67.0 1.58 0.54 81 134 127 75 of Vigneux. Blood, lime, soot 13.5 8.02 6.95 411.4 1738 24 6 Feathers 12.9 17 61 15.34 903 11 H Cow-hair flock . . 8.9 15.12 1 13.78 775 3445 13. 3 Woollen rags . . . 11.3 20.26 17.98 1039 4495 ,1 n Horn shavings . . . 9.0 15.78 14.36 809 3590 3 Coal soot .... 15.6 1.59 I.a5 81 337.5 30 Wood soot .... 5.6 1.31 1.15 67 287.5 149 35 Picardy ashes . . . 9.2 0.71 i 0.65 96 162.5 275 62 Veget. mould from bn- 1 mus dnng (terreaii) • • 1 1.03 .. 53 10 33 Dried in the stove. MANURES. 299 It is almost unnecessary to give any explanation of the uses that may be made of the preceding table : I shall, however, give a few il- lustrations from instances which have actually occurred in my ex- perience. Oil-caka is cheap at this time, (1842 ;) and the question is, whether it couM be advantageously employed in connection with the culti- vation of wheat. The presumption is, that wheat obtains the whole of its azote in the soil, that it acquires none from the atmosphere ; and again, I assume that the whole of the azote put into the ground would be used up by the crop. Under the most favorable circum- stances of heat and moisture, this would probably be the case ; were it not so to the letter, the active matter which remained in the ground would operate advantageously in succeeding years. The following, then, are the elements of the question : 1st. In the wheat grown at Bechelbronn there is on an average 0.025 of azote. 2d. In the straw of 1841, 1 have just found 0.003 of azote. 3d. The oil-cake which I propose to employ coi.lains 0.055 of azote, and its actual price, crushing included, is 3.?. 4c?. per cwt. 4th. The relation in point of weight of the grain to the straw is as 47 : 100. A sheaf or bundle of wheat, 220 lbs. in weight, consists of: Wheat 70.4 lbs., containing 1.760 of azote, and is worth 4*. 8d. Straw 149.6 lbs. " 0.415 " " Is. 8d. Total of azote 2.175 Total value 6s. 4d. Difference of value 5s. 4d. To grovir which, 39 lbs. of oil-cake would be required, of the value of. Is. 2d. So that 39 lbs. of oil-cake, converted into a sheaf of wheat, would be increased in intrinsic value to the extent of 5;?. 2d. Supposing that but one-half or one-third of this amount, as indicated by theory, is realized in practice, it is obvious that the addition of the oil-cake might be made with advantage ; and that no means should be neglected to ensure the success of its application as a manure.* The production of oil-cake in France, the Netherlands, and other countries of Europe, is very considerable ; in round numbers, 100 of oleaginous seeds yield 60 of cake ; but it has been calculated, with rare ability, and from authentic documents, by M. Leroy de Bethune, that not only is the whole of the oil-cake, which is the produce of the soil of France, exported, but that likewise of the oleaginous seeds which she imports from other countries. This M. de Bethune looks upon as a very lamentable agricultural fact. I have shown, indeed, from the example which I have quoted, that every pound of cake represents a primary material, which, properly treated, may be transformed into nearly 6 pounds weight of wheat- grain and straw, having a value infinitely greater than that of the oil-cake originally employed. * Our author has of course left many other elements very necessary to be included out of his calcW'Uion here, such as labor, seed, rent charge, interest on capital, *• fiKo. Ed. SOO EXPORTATION : F MANURES. While I agree with M. de Bethu: e, that it is generally wibe to encourage exportation, I also admit with him that there are sub- stances in reference to which it wot Id be prudent to discourage ex- portation ; oil-cake, this powerful rjeans of giving fertility to the soil, might be placed in the foremost rank of such substances. I am far from adopting all the principles of economists, which appear to me to be frequently far too absolute. In my opinion, any exportation, the consequence of which is the impoverishment of the soil, ought to be prohibited. I should, for instance, oppose the exportation of arable soil ; and in the same way, to allow an active manure to pass into the hands of strangers, is, in my eyes, tantamount to exporting the vegetable soil of our fields, to lessening their productiveness, to raising the price of the food of the poor ; for as much labor is re- quired, as much care and capital must be expended upon an ungrate- ful soil to obtain a little, as upon a fertile soil to procure an ample return. To permit the exportation of oil-cake is to hinder the hus- bandman from taking advantage of all the circumstances with which nature presents him ; it is as if a chill were to be brought over the genial climate of France.* I have shown the advantages of the application of oil-cake in the growth of wheat. I shall now inquire whether or not it is equally useful in connection with hay and potato crops ; the price of the article being presumed to be the same as before. Upland meadows, when they have not been soiled, yield miserable returns, and their situation renders them difficult of access to carts : oil-cake in such circumstances comes powerfully to our aid. Taking the price of hay at 5s. per 220 lbs,, which is about its present price in France, and taking into account the composition of the after-math, we may reckon the- azote contained in the hay of natural meadows at 0.015. 220 lbs. of hay, containing 3 lbs. of azote, will be worth 5«. Od, To produce which 56 lbs. of cake (azote 3.3 lbs.) worth Is, 8d. would be required. Difference in value between the cost and the crop 3s. 4d. Upon this showing, oil-cake may be advantageously employed in the amelioration of upland meadows. Besides the cost of the ma- nure, however, there are the very necessary additions to be made of the price of labor and rent. From the observations which I made at Bechelbronn in 1839, I * I own I am surprised at this passage in my esteemed author. There is nothing parallel in the instances he quotes. Did not the French husbandmen and oil-pressors jn-ofit by the exportation of oil-cake they woBld keep it at home ; and the profit of the farmer and manufacturer is the profit of the whole coiimiuriity. To export the soi: would indeed be madness : it would obviously be killinji the goose that lays the goldea eggs ; but to export that which the soil produces in abundance year after year, is a totally diflferent affair, M. Boussingault's reasoning would lead the wine-growers of Bordeaux and Burgundy to refuse us a hogshead of their smallest growth : they cannot send it to vs without impoverishing their sul, any more than they can let us have a pound of their oil-cake. But one half of the vegetables tliat grow, at least, are at work ac- cumulating the materials from the atmosphere and water, out of which the other half are supplied, and so the process of wnste fmd tnpply, of destruction and reproducUoo, goes on wiih'jul limit;-, and wiihcut cnd.-^E.NQ. Ed. USE OF THE PRECEDING TABLE. 301 find that the relation between the weight of potatoes as they come from the ground, and that of the tops or haum, supposed to be dry, is as 100 is to 6.4. The tubers contain : Azote 0.0036 per 10000 parts ; and 220 lbs. contain 0.729 of a lb. of azote, and are worth Is. 8d. The tops or haum, dry, contain : Azote 0.0230 per 10000 parts ; and 14 lbs. contain 0.330 of a pound of azote. Total of azote 1.122. Now 20.4 lbs. of cake which would be required to produce 220 lbs. of potatoes, contain 1.1 lb. of azote, and are worth 0«. lid. Difference ..Is. Oid.. The oil-cake at the price of 3*. 2d. per cwt. may therefore be ad- vantageously used for the production of potatoes : rent, labor, seed, &c., considered as before. At the price of 7s. 6d. or 8^. 6d. per cwt., however, to which oil-cake occasionally rises, it would not be possible to employ it profitably in this way. The cost of the manure would then amount to nearly as much as the value of the crop. The equivalent numbers in the table express the relative values of different manures ; they proclaim the proportions in which one substance must be substituted for another, and when purchases are to be made, they will show at a glance which is the article that is really, and in fact, the cheapest. The equivalent number of one variety of oil-cake, for instance, is 7.25 ; that of farm-yard dung is 100 ; which is as much as to say that in reference to mere fertilizing elements, 100 parts — lbs. cwts. or tons, of farm-yard dung may be replaced by 7^ parts — lbs. cwts. or tons of oil-cake ; — 2 cwt. of farm-dung, for instance, by 14|^ lbs. of cake. The 2 cwt. of farm- dung is valued in the table at 6d., or about 5s. per ton ; the 14| lbs. of cake would cost 5^d. It is obvious, therefore, that even at the above low price of oil-cake, there would be no real advantage in substituting it generally for farm-yard dung ; in situations, however, remote from large towns, where it is almost impossible to procure dung, or where the carriage of large masses of dung would be both difficult and expensive, there would then be advantage in the sub- stitution. Woollen rags at the price of about 2*. 10c?. per cwt. are more pro- fitable than farm-yard dung at 3^. per cwt. The equivalent of the rags is 2.22, and this quantity (2.22 lbs. avoird.) of rags is worth about ^d. ; by the substitution of the rags for farm-yard manure, therefore, a saving is effected of about 2| laand :— SIO MARL. Table of the Number of Cubic Feet of Marl applicable upon an When 100 Acre of Land ploughed to the depth of: parts of marl contain of carbonate of lime. inches. inches. Sr^TT 6fV 7tV 8A inches. inches. inches. inches. 333 444 554 666 776 888 10 1661 222 277 333 388 444 20 111" 146 184^0 222 258^ 296 30 83-iV HI 138fV 166fV 194 222 40 -66fV 88tV llOrV 133^V 155rV 177y3^- 50 55r\ 74 ^'^^ 111 129y2^ 148 60 47A 63A 79A 95^ iioA 126A 70 41t^ 55 fV 69t^ 83f^ 97 111 80 37 49t^o 6li 74 86t^ 98T'ff 90 33^ 44A 55>o 66A 77^ 88A 100 M. Puvis does not by any means give the doses in this table as those that should be invariably employed ; the table is one of aver- ages, deduced from practical results, and tested by experience as most truly useful. But special cases may occur that would make departure from these conclusions not only advisable, but advantage- ous.* The use of marl produces an unquestionable effect on the pro- ductive properties of the soil. According to M. Puvis, the applica- tion of the proper dose of a sandy marl, containing from 30 to 60 per cent, of carbonate of lime, doubled the produce of a piece of parched land in the department of the Isere. Before the application of the marl nothing but dwarfish crops of rye were gathered, yielding at most three for one of the seed ; at present, eight for one of seed, and that wheat, are obtained ; and the good effects are found to continue for ten and even twelve years. The action of marl is not unlimited any more than that of lime, as the last sentence will give the reader reason to conclude. With every harvest, a certain proportion of it is carried off, and the land is finally left with an inadequate quantity of the calcareous element, which then requires to be restored. The nature of the crop, how- ever, has the most marked influence on the quantity of lime that is taken up and carried away from the soil ; allowing the broadest margin, and judging from the composition of the ashes of the plants that form the subjects of our ordinary crops, we can see that the quantity of 3| bushels of marl of the usual composition per acre, which is assumed as the average quantity to be laid on, is vastly more than can be absolutely necessary. Wood ashes contribute to improve the soil. They contain, besides fiilica, both phosphate and carbonate of lime and alkaline sulphates, phosphates, and carbonates. In a general way, every thing derived ♦ Puvis in Annals of French AgricuUuro, vol. xxviii. p. 328, 2d series. PEAT ASHES. 311 fraia plants that have lived must be useful to plants that are about to live, or that are actually living. Although the utility of wood ashes, then, is generally admitted, the numerous purposes to which they are applied in the arts, and their high price, which is the con- sequence of this, enable the husbandman to employ them but rarely on his land ; they are almost always lixiviated in order to procure the carbonate of potash they contain. In countries which are thick- ly wooded, indeed, the trees are actually cut down and burned for the sake of their ashes, just as oxen are run down and slaughtered in the vast plains of South America for the sake of their hides. The good effect of wood a"shes upon vegetation is known to com- munities the least advanced in civilization. The Indians of South America burn the stems and leaves of the maize in order to improve the soil. The same practice occurs among the natives of Africa : on the banks of the river Zaire, according to Tuckey, the ground is prepared by having little piles of dried herbs placed on it, to which fire is set ; and upon the spots where the ashes are collected, they sow peas and Indian corn ; these ashes are in fact the only manure that is employed. In England, wood ashes are esteemed as parti- cularly useful upon gravelly soils ; about 40 bushels per acre are applied in the spring, where the article can be obtained. The lye-ashes from the soap-boiler contain a small quantity of soluble saline matter which has escaped the lixiviation, mixed with a large proportion of lime, partly in the state of carbonate, the lime having been added to bring the carbonate of potash employed in the manufacture of soap into the caustic state. This ash or refuse is much sought after, and is administered in quantities that vary from 45 to 70 bushels per acre, a dose in which its action is felt for ten years or more. In wooded districts, where there is a good deal of potash prepared, ash of this kind is obtained in large quantity ; it is there employed alternately with organic manures. Ashes are ap- plied in th« same way as lime, with this difference, that it is held better not to plough them in until they have received a little rain. There tre places where the ashes that remain in the lixiviating tub are threwn on in the dose of 170 bushels per acre. Turf or peat ashes. Peat is the result of a peculiar spontaneous change that takes place in vegetables. It is produced in bogs or swamps, and in connection with stagnant waters ; turfy deposites are also encountered on the banks of rivers, in valleys, at the bottoms of former lakes, and at the mouths of rivers. Peat is met with from the level of the sea to the elevated platforms of the Vosges and x\lps ; it lies in horizontal beds, frequently divided by strata of gravel, sand, or clay. It is always a product of comparatively re- cent formation, a fact which is attested by the thin layers of vege- table soil that lie over it in many places, and the animal remains and products of human industry that are frequently encountered in it. The state of decomposition of the vegetables that form turf or peat is seldom so far advanced as to make the remains of the plants which compose it doubtful. It is of different kinds : hard or woody, S13 P£AT ASHES. *nd sof> o» hffbajeois peat. Some of it is extremrly compact. Mack, and like vegetable mould in appearance; generally speaking it is light, spongy, ind of a lighter or deeper shade of brown. When quite dry, it is often extremely light ; a fiub c metre, which is about one-eleventh more 1 han a c»ibic yard, wil « weigh from 5 to 6 cwt. The circumstances in which turf has been found lead us to infer that it must contain the elementary insoluble elements of the plants that produced it. It appears, however, to contain a somewhat lar- ger proportion of azote than the average quantity met with in her- baceous vegetables, supposed dry ; but we have seen that in the slow alteration of lignine, azote becomes concentrated, as it were, in the residue ; and that, in fine, mould contains a larger quantity of azote than the wood from which it proceeds. It appears further from some experiments very lately performed by Mr. Hermann, that during the putrefaction of the woody principle, azote is actually ta- ken from the air to concur in the formation of certain products that are perfectly definite. Mr. Hermann quotes the following experi- ment : Twenty-eight parts of wood taken from a log already attacked with rot, and in which, indeed, there were several points already decayed, were moistened and enclosed in a jar containing atmo- spherical air over mercury. The bulk of the atmosphere contained in the bell-glass was 262 volumes. The wood was kept there for ten days at a temperature of 75.2° Fahr. The apparent volume of the air continued unaltered to the end of the experiment ; but a large quantity of carbonic acid had been formed : RESULTS ON THE INCLUDED AIR. The air cont^ned : Azote. . . . Oxygen . Before. ..207 vols. ... 55 Carbonic acid... After. 194 vols. ...40 " 28 " The moist wood in its decomposition during ten days had conse- quently caused thirteen volumes of azote and twenty-seven volumes of oxygen to disappear. And Mr. Hermann found that it now con- tained principles analogous to those of humus, one of which, nitro- iin, is highly azotized, and by the ulterior action of air and moisture, gives rise to ulraate of ammonia. These experiments of Mr. Her- mann are new, and the conclusions to which they lead are both inter- esting and important.* Turf or peat is virtually the woody principle in the last stage of modification by atmospherical influences ; but it appears still to con- tain, although modified, the usual principles which enter into the constitution of herbaceous vegetables also, M. Payen detected a quantity of fatty matter in it, analogous to that which exists in leaves, and M. Reinsch found it to contain tannin. One sample of ♦ Vide hia paper in Journ. fiir prakt. Cliemie, b. xxUi. s. 379. ?EAT ASHES. 31^ turf (from the neighborhood of Moscow, by the way) examined by Mr. Hermann, yielded of carbonaceous matter, nitrolin and vegeta- ble remains 77.5 ; of ulmic acid 17.0 ; extract of humus 4.0 ; am- monia 0.25 ; and ash 1.25=100.0 The elementary composition of these varieties of turf, analyzed oy M. Regnault, gave from 57 to 58 of carbon ; 5.1 to 5.6 hydrogen ; 30.8 to 31.8 oxygen and azote ; and 4.6 to 5.6 ashes. Turf or peat has consequently a certain resemblance to mould or .humus ; it differs, hovvever, in the absence of substances soluble in water ; and it is easy to imagine that, produced as it is in connection with water, continually soaked in moisture, soluble matters ought «ot to be expected in it in appreciable quantity. Peat might, in fact, be likened to the insoluble part of humus left after lixiviation. A.nd there is this further resemblance, that peat, like the humus (vhich has been thoroughly lixiviated, if exposed to the air, by and iy acquires a quantity of soluble material, the evolution of which is also hastened by the contact of the alkalies. The employment of hirf as manure, in some countries, confirms the propriety of this mode of viewing its nature and constitution ; and then it is well knowc that bogs consisting of pure turf, when drained and limed, become tolerably fertile lands, yielding magnificent crops of oats and turnips especially. The ashes of turf we might expect to contain the mineral sub- stances usually found in the ashes of plants, and further a certain quantity of additional earthy matter. But this is not the case : sev- eral alkaline salts, indeed, have been discovered in very small pro- portion ; but no chemist, to my knowledge, has ever even suspected the presence of any of the phosphates ; a special search which was made for them in my laboratory failed to discover them. This is a fact which, I own, amazed me ; some coal ash, and another ash produced from lignite, gave a result equally negative. We might imagine the disappearance of the soluble salts ; but how the earthy phosphates should disappear ; how the ashes of coal should come to be without a trace of phosphoric acid, when we see that the iron ore, in connection with the coal fields, is always more or less phos- phorigerous,* is surprising. Turf or peat ashes are valuable improvers of the soil, and are in Treat request among intelligent farmers. Analysis, in fact, indicates several substances in their composition as calculated to assist vege- tation; carbonate of lime, in a state of extreme subdivision ; occa- sionally sulphate of lime, (gypsum ;) calcined clay, whose action upon strong and retentive lands is always beneficial ; silica in a fa- vorable state for assimilation ; finally, alkaline salts, chlorides, sul- phates, carbonates, and, perhaps, in spite of the negative given by chemical analysis, traces of the phosphates. The peat of the bogs of Sceaux, near Chiteau-Landon, leaves 19 per cent of ashes, composed, according to M. Berthier, of : — * Our author might have added the fact, that the common bog iron ore of this COUB try is a phosphate of iron.— Eng. Ed. 27 814 PEAT ASHES. Caustic and carbonated lime* • 83.C Clay 7JS Gelatinous silica 13.0 Alumina .t. 7.0 Oxide of iron 9.0 Car^.. late of potash 0.5 100.0 The peat of Voiuomra, dug upon the frontiers (.£ Bavaria and Bohemia, contains the remains of trees ; it leaves 1.7 per cent, of ashes, composed, according to M. Fikenscher, of: Silica 36.5 Alumina 17.3 Oxide of iron 33.0 Lime 2.0 Magnesia ••'. 3.5 Sulphate of lime 4.5 Chloride of calcium 0.5 Carbonaceous matter not incinerated — 2.7 100.0 The brown herbaceous peat of the neighborhood of Troyes, leave* 1 1 per cent, of residue ; it contains : Carbonic acid and sulphur 23.0 Lime 23.0 Magnesia 14.0 Alumina and oxide of iron 14.0 Clay and silica 26.0 100.0 The peat of Vassy is compact, and of a brown color; it is mixed with fragments of chalk. On incineration, it leaves 7.2 of residue per cent., containing : Clay 11.0 Carbonate of lime 51.4 Sulphateof lime 26.0 Oxide of iron 11.5 100.0 The peat of Champ-du-Feu, near Framont, (Vosges,) leaves 3 per cent, of ashes, which consist of: Silica 40.0 Alumina and oxide of iron 30.0 Lime 30.0 100.0 The peat of the environs of Haguenau (Lower Rhine) produces 12.5 per cent, of ashes, which, according to the analysis made in my laboratory, contain : Silica and sand 65.5 Alumina 16.2 Lime 6.0 Magnesia 0.6 Oxideofiron 3.7 Potash and soda "... 23 Sulphuric acid 5.4 Chlorine 0.3 10(.0 Supposing the whole of the sulphuric acid fciund to have beeu m COAL-ASHES. 315 comoination with lime, this peat could only ha^e contained 4.1 per cent, of gypsum. These analyses will show that-the composition of peat, or turf, is very various. The varying and dissimilar effects produced by turf- ishes, may probably be owing to this variety of composition. Turf- ashes, in a general way, may be used as a substitute for gypsum ; but this is upon the presumption that they contain lime, either in the state of carbonate or of sulphate. The Vassy turf-ashes, for ex- ample, may be employed for gypsing meadows, inasmuch as they contain a quarter of their weight of sulphate of lime. The ashes from pyritic turf ought not to be used without great circumspection ; they usually contain a quantity of iron pyrites which has not been destroyed in the burning, and which, exposed to the action of the air, gives rise to the formation of green vitriol, or sulphate of iron, which may prove prejudicial to vegetation. These ashes are generally of a red color, and very heavy, in con- sequence of containing a quantity of the oxide of iron. Good turf- ashes ought to be white and light ; the sack ought to weigh some- thing less than a hundred-weight. Schwertz recommends us to keep them from the wet ; but at Bechelbronn, where we use large quanti- ties of peat-ashes, we find no ill effects from leaving them exposed to the rain ; frequently, indeed, we moisten them with water from the dunghill, in order to add to their properties as a mineral manure, those that belong to organic manures. On the whole, however, it is cer- tainly better, for many reasons, to keep them dry ; they are more easily carried, and they are more easily spread. Turf-ashes of a good quality, that is to say, which include in theii composition a large proportion of calcareous and alkaline salts, are adapted to crops of every description ; but it is upon clover especially that their influence is truly surprising. This fact is well established in Flanders ; but one must have employed them one's self to have any adequate idea of the improvement they produce. There is no risk of giving too large a quantity. In winter, when we have peat-ashes at our disposal, we give as many as 60 bushels per acre to our clo- vers ; we scatter them even upon the surface of the snow, and dis- tribute them by means of the rake in the spring. The Dutch use these ashes in still larger quantity, applying, at two different times, from 100 to 160 bushels per acre to their clover fields. Accord- ing to Sinclair, the Dutch also make use of an ash procured from a turf which during winter is in contact with brackish water, a cir- cumstance which renders this ash particularly rich in alkaline salts. It is sowed by hand, in the spring, upon clover, and the following year an abundant crop of wheat is obtained. The same material is also used in the cultivation of the hop ; and it is said that, administer- ed in small quantity to the roots of the vine, they preserve the plant from the attacks of destructive insects. Coal-ashes. Coal, like the two last combustible materials, is the product of vegetables, which, however, have undergone such a change as to have lost almost every trace of organization. Coal of different kinds contains from 1.4 to about 2.3 per cent, of ashes, and 816 ALKALINE SALTS. about 2 per cent, of azote. The ash of a variety of coal of verjf excellent quality gave of — Argillaceous matter (silica"?) not soltble in acids 69 Alumina 5 Lime 9 Magnesia 8 Oxide of manganese 3 Oxide and sulpliuret of iron 16 100 Coal ash also contains very minute quantities of alkaline salts, which usually escape analysis when they are not especially inquired after. One specimen analyzed in my laboratory, gave nearly 00.1 of alkali. Coal-ash is particularly useful on clayey soils ; it acts by lessening the tenacity of the soil ; and further, doubtless, by the in- troduction of certain useful principles, such as lime and alkaline salts. OF ALKALINE SALTS. It is impossible to doubt that salts having potash and soda for their base are useful in agriculture. The influence of u^ood-ashes, and of paring and burning is unquestionable ; and they are so, in some con- siderable degree at least, in consequence of the salts of these bases which they supply, and which always enter into the constitution of vegetables. There are even certain crops which, in order to thrive, require a particular alkali ; the vine, for example, the fruit of which contains bitartrate of potash, and sorrel, which contains the binoxa- late of the same base, must needs have supplies of potash. The plants which are grown for the production of soda, the salsola, <5fC., from which barilla is made, must come in a soil that naturally con- tains a salt of soda, such as that of the sea-shore. It would appear, however, that the salts of soda or potash, must not exceed a very small proportion in the soil. All the experiments that have yet been undertaken with a view to ascertain the action of different saline substances on growing vegetables, have led to no very certain conclusion but this, that they must be used very sparing- ly. M. Lecoq has published an account of some experiments, made apparently with great care, which go to prove that common salt, in the dose of from \\ to 2j cwts. per acre, favored the growth of barley, wheat, lucern, and flax. Chloride of calcium and sulphate of soda, he also found to have the same good effects. M. de Dombasle, how- ever, came to conclusions totally opposed to them, with reference especially to common salt, which, applied in the doses advised by M. Lecoq, was not found to produce any sensible effeci. M. Puvis also obtained results that were equally negative. It would perhaps have been well had M. Lecoq begun by determining the proportion of alkaline salts which existed previously in the soil on which he conducted his experiments. If he operated on a soil that was either destitute of these salts, or that contained them only in minimum proportion, very probably he did good by adding them. Nitrate of potash has been repeatedly recommended ?r an agent useful in agriculture. The conclusions that have been come to however, from its use, are far from accordant. In the processta NITHATE OF SODA. 81 or modes of using- nitre to the soil, it is not uncommon to find il associated with soot, or with vegetable mould, substances which require no assistance of any kind to constitute them powerful manures, and the addition of which is therefore calculated to raise strong doubts of the advantageous qualities ascribed to nitre alone. Were the advantages of nitrate of potash much less questioned than they are, however, the high price of the salt would probably always oppose insuperable obstacles to its employment. This is the reason, in all likelihood that has turned the attention of Eng- lish agriculturists, for several years past, to nitrate of soda, a salt that is imported in quantity from Peru, and of which the price per cwt. may be about forty shillings ; a price which, were it found really useful, would permit of its being used. Admitting the ac- curacy of the experiments that have been made, indeed, we can- not doubt the efficacy of nitrate of soda on soil already furnished with organic manure. The quantity that has been recommended is about one cwt. per acre. Mr. Barclay made a few experiments after having heard muph of the nitrate of soda from his neighbors, of the results of which the following examples will suffice to give a comparative estimate : Without nitrate. With nitrate. Difference in favor of the nitrates. Wheat 31 bush. 2 pecks. 35 bush. 3 pecks. 5 bush. 3 pecks. Straw 21 cwt. 0 qrs. 19 lbs. 23 cwt. 2 qrs. 26 lbs. 3 cwt. 2 qrs. 7 lbs. The produce of the land treated with nitrate, however, did not fetch so high a price at market as that grown without it ; and every item of expense taken into the reckoning, the use of the nitrate was attended with no commercial benefit. Still this does not militate against the fact, that the production of vegetable matter was in- creased upon land treated with the nitrate of soda. And indeed much of the information which M. de Gourcy collected in England, is of a kind that tends to confirm the favorable influence of this salt on vegetation. Wheat, clover, and Swedish turnips are particular- ly specified as benefiting from its use. These facts admitted, we rnay ask : how does the nitrate of soda act ? The chemical consti- tution of the nitrates is such, that we might conceive their acting at once as mineral and as organic manures. The important point for solution was to ascertain whether the azote of the nitrate contribu- ted in any way to the formation of the azotized principles of plants. Davy, in taking with much distrust the report of Sir Kenelm Digby's experiments on the influence of nitre in the cultivation of barley, shows no disinclination to believe that the azote of the salt may concur in the production of albumen and gluten.* This, however, is a point in physiology which may be put to the proof by experi- ment, and seems peculiarly worthy of being tested in this way. I have admitted it as extremely probable, that the azote of the azoti- zed principles of plants has its source either in the ammonia, which 18 the special iltimate product of the organic manure we employ, ox - -. Agricultural Chemistry •27* 819 MANURE — &i?SUM. in the azote of the atmosphere, or in both simultaneously ; b it the opinion which should maintain that the ammonia derived from the organic constituents of the soil, passes into the state of nitric acid before penetrating the tissues of plants, would find support nearly in the same facts which I have quoted as favoring the former view. We have seen, moreover, in our general considerations on nitrifica- tion, with what facility the azote of ammonia undergoes acidification in certain circumstances, a fact from which an argument of much potency for the nitric acid theory naturally flows. I shall here add an observation to which I have, up to this time perhaps, attached too little importance. When M. Rivero and I examined the hig: ly irritating and poisonous milky sap of the hura crepitans, we had oc casion to leave a considerable quantity of the water derived from the sap, after separating the caseum, to itself; by the spontaneous evaporation of this vi'ater, we collected really a considerable quanti- ty of nitrate of potash. Since this time I have had occasion to note the same salt in the sap of several trees of the tropics. In the leaves and fruit, however, I have never found more than very minute qu^l.cities. Gypsum, sulphate of lime, or pla^ier of Parts, is a compcjnd of 41.5 lime with 58.5 sulpnuric acid; gypsum generally contains a quantity of constitutional water, in which case it consists of 79.2 sulphate of lime, and 20.8 water = 100. This hydrate of sulphate of lime is one of the abundant minerals on the surface of the earth ; it is met with in the crystalline state, and in granular and fibrous masses in the strata of most recent formation. It has no sensible taste, but is slightly soluble in water, this fluid dissolving ^ of its weight of the salt. Exposed for some time to a white heat, it loses its water of constitution, and passes into the state in which when ground it is known under the name of plaster of Paris. Gypsum is one of the most commonly employed of the mineral manures. Its virtues appear not to have been unknown to the an- cients : but until lately its employment was limited to a few circum- scribed districts. It was only about the middle of the eighteenth century that the protestant pastor, Mayer, took up the study of gyp- sum in the principality of Hohenlohe, proceeding upon certain in- formation which he had obtained from Hehlen of Hanover, in the neighborhood of which, it was employed as an improver. By extending a knowledge of the virtues of gypsum, both by his example ard his writings, Mayer did great service to agriculture. Experiments were soon instituted in all quarters. Tschiffeli in Switzerland, Schubart in Germany, and Franklin in America, wrote on its effects, or practically demonstrnted them to the satisfaction of all. But it appears to be the fate c " all useful discoveries, of all happy applications of principles, to be opposed at first, and only to be admitted after having been vainly disputed. The use of gypsum soon aroused formidable opposition ; and there is a curious episodf in the history of the paper war that was long carried on upon hi •ubject, which I think worth noting. Among the most strenuous •oemies of the use of gypsum, were the proprietors of the saJt-paiUb GYPSUM. 319 They declared that gypsum was not only incompetent to replace schlot or the refuse of their pans, as had been proposed, but that it was injurious ; schlot was the only veal improver, the stimulant of stimulants, for which there was no substitute. But it turned out by and by, that the schlot oi the salt-pan was found to be neither more nor less than sulphate of lime, than gypsum — the article that was not only inefficient, but injurious. These gentlemen were afraid that the use of gypsum extending, they would want a market for their refuse. The use of gypsum once introduced, extended rapidly in France, particularly around Paris, whence it crossed the Atlantic, and the fields of North America were actually manured with the produce of the quarries of Montmartre. The lately cleared lands of America abound in humus, and the plants indigenous there were most bene- ficially acted on by gypsum, which really produced remarkable effects ; in both the new and the old world, its power, as one of the most useful auxiliaries of vegetation, soon appeared to be estab- lished. We must not blind ourselves to the fact, however, that the parti- sans of gypsum were guilty of exaggeration. They spoke of the substance as a universal manure, capable of supplying the place of every other, as advantageous for every description of crop, as appli cable to every variety of soil. Experience soon set bounds to sucl indiscriminate laudation ; it was found that gypsum alone was inad- equate to produce fertility, that it always required the concurrence of organic manures, if the soil did not contain them of itself; that it only acted beneficially on a certain, and that a very small number of plants ; lastly, that it was upon artificial meadows, constituted by clover, lucern, and sainfoin, that it produced its best effects ; its action, on the contrary, being scarcely perceptible upon natural mead- ows, doubtful in connection with hoed crops, and null with the cereals. These negative results cannot be called in question ; they were come to by parties who were every way interested in having the decision otherwise. The best season for spreading gypsum is the spring, and when the clover, sainfoin, or lucern, has already made a certain degree of progress ; calm and moist weather is the best for laying it on. Opinion wa» long divided as to whether it should be applied in its natural state, and simply ground, or first burned and then ground. But it is now generally admitted that burning adds nothing to the qualities of gypsum. Although the usual practice is to sow or pow- der the meadows with the ground gypsum, it is still acknowledged that good effects are obtained from incorporating the substance with the soil. The advantage of the practice of scattering it on in pow- der, so as to adhere to the wet leaves of the growing plants, I find explained in the equality of distribution which is by this means effected. In some places, the number and extent of which are by no means inconsiderable, no good effect whatever has attended the application of gypsum, altho'igh it has been administered in favorable conditions, 320 GYPSUM. and in connection with crops that elsewhere derive the highest amovinl of advantage from its use. This anomaly has been explained by assuming, without proving experimentally, however, that the fact ia so, that the soil in these districts naturally contains a sufficient dose of gypsum. It has also been said that gypsum produces no effect on low-lying and damp soils. The quantity of gypsum employed in different places, varies great- ly : from li to 16 cwts. per acre have been recommended. The quality of the article employed has a great influence on this question, to say nothing of the price, which in many places is high. The opinions of practical men, with regard to the advantages and propriety of applying gypsum, although they agreed in certain de- terminate circumstances, were still far from being unanimous upon every point. A particular inquiry into the subject was therefore held worthy of its attention by the French government, and a com- prehensive report on all the information collected, was made by M. Bosc to the Royal Central Agricultural Society of France. This report shows in a striking manner the advantage that may be deriv- ed from the lights of practical men ; in a single line or sentence wo frequently find a summary of twenty or thirty years of experience. It is, however, indispensable to go to these gentlemen for their in- formation ; the agriculturists who devote themselves to cultivation, it is notorious, write very little, and those who spend very little time in this way, on the contrary, write a great deal. It may be that the reason for the silence of the one, is that also for the elo- quence of the other. The following series of questions and answers I believe to em- brace most of the points connected with the employment of gypsum, that are of interest. 1st. Does plaster act favorably on artificial meadows? Of 43 opinions given, 40 are in the affirmative ; 3 in the negative. 2d. Does it act favorably on artificial meadows, the soil of which is very damp? Unanimously, no. Ten opinions given. 3d. Will it supply the place of organic manure, or of vegetable mould 1 i. e. will a barren soil be converted into a fertile one by the use of plaster ? No, unanimously. Seven opinions given. 4th. Does gypsing sensibly increase the crops of the cereals'? Of 32 opinions, 30 negative, 2 affirmative. The information thus obtained, valuable as it is, cannot yet be held to embrace every thing that seems desirable. Happily, all that was wanting has been supplied by the individual inquiries of Mr. Smith in England, and of M. de ViMle in France. The soil upon which Mr. Smith made his experiments was light, with a substrate of chalk ; the vegetable earth was a yard in depth at the top of the field, and lessened gradually, in such a way that at bottom it was but three inches thick. Every precaution was taken that the respective breadths contrasted should be as nearly as possi- ble in the same circumstances. The following table shows the teeulta : GTPSUM. 321 GROWTH OP SAINFOIN UPON SOILS GYPSED AND UNGTPSED IN 1792, 1793, AND 1794. Crop on the deeper ungypsed soil Crop upon the contiguous breadth, which had received about 15 bushels of gypsum in April, 1794. . . . . . Bemarks. Difference in favor of the gypsed breadth . . . . Crop upon the same soil, of less depth, and not gypsed . Crop on contiguous soil, dressed with about 15 bushels of gyp- sum in April, 1792 . Difference in favor of the gypsed breadth .... Crop on the same soil, 3 inches deep, and not gypsed Crop on contiguous soil, dressed with about 15 bushels of gyp- sum, 17th May, 1794 . Difference in favor of the gyp- sed piece .... Crop on the contiguous soil of experiment. No. 3, gypsed with the same dose in May, 1792 .... Difference in favor of the crop gypsed twice, at an interval of two years Dry herb p«r acre. Seed per acre. lbs. 3357 5462 2105 2766 4381 1615 2068 4879 2811 4310 2242 lbs. 419 582 163 245 379 134 66 211 145 205 139 Weight of total crop. lbs. 3776 6044 Proportion of stalk to seed. 2268 3011 4760 1749 2134 5090 2956 4515 2381 100 : 12.5 100 : 10.7 100:8.9 100 : 8.7 100 : 3.2 100 : 4.3 100 : 4.8 ^22 GTPSUJI. These results show to what extent gypsum is favorable t39 temperature diminishes. Thus it is that the water of a pond or lake freezes at the surface, while it preserves beneath a tempciature some degrees above 32°. In a situation where the temperature of the air was 29", Davy found the thermometer indicate 43" in he herbage of an inundated meadow completely covered with ice.* Water is always impregnated with atmospheric air, and a minjte quantity of carbonic acid. Deprived of air, it is not agreeable to drink ; it is even said, when long continued, to prove unwholesome if the dissolved gases are expelled by ebullition. River-water usual- ly contains 3'^ th in volume of air, and tJ'o th carbonic acid. In spring- water, the amount of the latter is sometimes far more considerable. The quantity and nature of saline ingredients in drinkable water vary much : in an agricultural point of view, the study of the con- tained salts would certainly be useful. The waters which serve as drink to the cattle of a farm, introduce into the dung-heap all the matters which are dissolved or held in suspension. At Bechelbronn, for example, I find that more than 2 cwts. of alkaline salts get into the dung in this way every year. When a farmer has the choice of several waters for giving his cattle or irrigating his meadows, he will do well to select that which is richest in alkaline salts, and still good to drink. In the steppes of America, it is astonishing with what discernment the cattle choose waters for allaying their thirst, containing minute quantities of sulphate of soda or common salt. I close these considerations with a tabular view of the most recent analyses. The quantities of salts put down have been deduced from 100,000 parts of water for drinking. * Davy. Agricultural Chemistry, p. 3S9 540 V/ATER. Of the Seine above Paris . Marne Onrcq at St. Denis . . Yonne at Avalion . . Benvronne . . . . Therouenne . . . . Gergogne Bievre near Paris . . Arcueil Spring of Roye (Lyons) . Fountain Spring (Lyons) . Rhone at Lyons (July) Ditto ditto (February) . Spring of the garden of plants at Lyons . . . Of Lake Geneva . . . Of the Arve (in August) . Ditto in February . . . Loire near Orleans . . . Loiret 1 H •< H 59 i_i to (-> h- to lO k- I-- l-» JO to t->y-i)-i ^ y-t OD Ox -^ ■cn4i.;-TpH-' Carbonate of lime. Carbonate of magnesia. ..pop- • § B O ^PPP Silica. w- ojccjoc^ tspK-" H- as S H- too g o^ woo bo* cnioosio oc5^*^«o^-'C^bc»5ctWH-a3 00 Sulphate of lime. • • b «3 F- • ^ g b to en Sulphate of magnesia. Sulphate of Soda. ho*-'' ' ' bo ^aw-biocnboibi'-b Chloride of calcium. cn-jix)a5 g' 'o^ioo Chloride of magnesium. traces idem 0.9 1.2 1.9 1.2 0.2 traces 12.6 traces 2.5 Chloride of sodium (marine salt.) traces traces of lime 7.6 Nitrates. traces idem idem idem • • • • traces idem idem idem strong traces 0.6 0.3 0.4 Organic matter. lO to I-" 1— CO I— ^ to to rfi. C^ to W trt rf>. — i-i 00 OS *^ to Cn O OD O 05 05 CS O — ' ^ 4^ -^ ^ OC 00 '►f^ bo 00 00 io bo i^ bs 05 4^ ^ bo b bo c/i ^ bo b to Total weight of matter. Bouchardat Ditto Ditto Ditto Colin Ditto Ditto Ditto Ditto Bot.J8ingauIt Dupasquier Boussingault Dupasquier Ditto Tingry Ditto Ditto Guindant Ditto ROTATION. 341 The water of the Artesian well at Grenelle, near Paris, according to the analysis of M. Payen, contains, in 100,000 parts : Carbonate of lime 6.80 Carbonate of magnesia 1.42 Bicarbonate of potash ...2.96 Sulphate of potash 1.20 Chloride of potassium 1.09 Silica 0.57 Yellow matter, not defined 0.02 Organic azotized matter .. 0.24 14.30 CHAPTER VII. OF THE ROTATION OF CROPS; ^ 1. OF THE ORGANIC MATTER OF MANURE AND OF CROPS. It is known that the atmosphere and the organic matters diffused through the earth concur simultaneously to maintain the life of plants ; but how far each contributes is undetermined. We shall now study the theory of the exhaustion of the soil by culture, and the rotation of crops. When a succession of crops is grown upon fertile land without renewal of manure, the produce gradually diminishes ; and after a certain period, if it be grain, the quantity which at the outset was eight or nine limes the amount of the seed, will be reduced to three times or even to twice the seed. Thus crops impair the fertility of the soil, and eventually exhaust it. It has been long admitted that different species of plants manifest great diversity in their powers of exhaustion. Certain kinds, indeed, as trefoil and lucerne, far from exhausting it, communicate new vigor. As a general rule, however, every plant may be said to impoverish the soil in which it grows. This impoverishment is al- ways manifest when the plant after maturity is completely removed, but is less sensible when much rubbish is left. Thus, for example, clover, after yielding two crops, which are generally cut as fodder, might still yield a third ; this last, however, is generally ploughed into the ground as manure, being buried along with a considerable quantity of roots. This plan of meliorating the soil by the cultiva- tion of trefoil is what is called manuring by smothering ; a method practised from a remote period in the south of Europe, and which offers decided advantages in those districts where there is abun- dance of pasture land. Hence, in smothering trefoil, the soil is amended at the expense of the nutritive matter it contains. Thaer, who endeavored to make theory and practice mutually agree, laid it down as a rule, that the exhaustion occasioned b_> 29* 842 ROTATION. cropping is proportioned to the amount of nutriment in the crops estimating the nutritive value according to Einhof s determination But the above deduction is founded upon error. In fact, to adopt the above principle is tacitly admitting that the whole organic matter of plants originally comes from the soil. This, no doubt, contributes in a certain proportion to the development of plants, but so also do air and water. On the other hand, physiolo- gists, in opposition to the ideas of the school of Thaer, have perhaps exaggerated the material withdrawn from the air. Thus, M. de Saussure reckons that a sun-flower derives from the ground during its growth not more than ^oth of its weight, supposing the plant dry. The reasoning upon which he formed his conclusion is based, on the one hand, upon a knowledge of the extractive matter of garden- mould ; on the other, upon the quantity of water a plant like sun- flower may absorb in a given time, to return it again to the air by transpiration.* Little objection could be urged against the above conclusion, did not the experiments of M. Gazzeri tend to prove that roots virtually exercise, by their contact with solid organic matter, an incontesta- ble absorbent action in imparting solubility.f I might refer to an observation of M. de Saussure, in which he states that plants grown in garden-mould deprived of its soluble components by repeated washing, reached, nevertheless, perfect maturity, although the pro- duce in seed was less abundant than it might have been. J It is most probable that both parties have promulgated extreme opinions. Plants possibly draw from the atmosphere more than agriculturists commonly suppose, and the soil furnishes, independently of saline and earthy substances, a proportion of organic matter larger than certain physiologists admit. There is every reason to believe, from what I could learn respecting guano during my sojourn on the coast of Peru, that the greater part of the azotized principles of plants originates in the ammoniacal salts which exist or are formed in ma- nure.^ In discussing the advantage of one course of crops over another, the question always hinges upon that of exhaustion. Wherever an unlimited supply of dung and of handiwork can be procured, there is no absolute necessity for following any regular system of rotation. Under such favorable circumstances, it is expedient to ascertain what kind of cultivation is, commercially speaking, best suited to the climate and the soil. There is little to fear that by a continued succession of similar crops, the fields will get infested with noxious weeds, because this inconvenience may be obviated by labor. Nor is impoverishment of the soil to be dreaded, since that can be re- medied by the purchase of manure. The whole craft of agricuhure is reducible to comparison of the probable value of the crop with the cost of manure, labor, &c. Farming of this sort excludes the * Saussure, Recherches Chimiques sur la V6g6tation, p. 2681 t Annales de rAj^TicuUnrc Franfaise, No. iii. p. 57 i Saussure, Recherches Chimiques, p. 171. ^ Annales de Chimie, t. Ixv. ann^ 1837. ROTATION. 843 keep and propagation of cattle, and may be strictly regarded morfe as gardening than as agriculture. But where manure cannot be had from without, things must be reduced to a system ; and the amount of produce which it is possi- ble to export each year is fixed within bounds, which cannot be ex- ceeded with impunity. When by judicious cultivation land is rendered fertile, it is ne- cessary, towards securing its fertility, to supply after every succession of crops equal quantities of manure. In considering this in a purely chemical point of view, it may be said that the produce which can be taken away without damaging the fertility of the land, is the or- ganic matter contained in the crops, abstraction made of that present in the manure. Indeed, this latter substance must in some form or other return to the soil to fecundate it anew. It is capital placed in the ground, the interest of which is represented by the commercial value of the produce of all the other agricultural operations. Where lands are extensive, population scattered, and means of communication difficult, there is less necessity for being tied down to systematic cultivation. There is always enough for a scanty popu- lation. A field yields grain, and after the harvest is converted for a series of years into meadow-land ; such is the pastoral system in all its simplicity. To this primitive state of husbandry may be referred those plantations on cleared land in countries covered with forests. When the trees are felled and burned upon the spot, the soil yields for long and without manure, crops of maize and of wheat of sur- prising quality, at the cost of the fecundity acquired during ages of repose. But when from increased population the land becomes more valu- able, a larger amount of produce is demanded. Imperfect culture would prove inadequate. Accordingly a triennial rotation of crops was very anciently adopted in the north of Europe, consisting as is well known of fallow land frequently ploughed during summer, fol- lowed by two years of grain. The fallow land received a certain quantity of manure to repair the exhaustion occasioned by the two crops of grain ; hence when this mode of rotation is adopted there should be always sufficient meadow-land to supply manure. Leaving waste one third of the surface has always been held a grave objection against triennial rotation. Hence various attempts have been made to get rid of the summer fallow. Some encourage- ment was given to these attempts from what occurs in horticulture, where the ground is rendered continually productive.* In certain countries, moreover, tillage is only interrupted by severe weather. On the other hand, it has been long remarked that it is not always beneficial to grow grain during several consecutive years in the same ground, even when it is fertile and manure is abundant, owing to the almost insurmountable difficulty of destroying weeds. The fallow was justly considered the most efficient and economic means of getting rid of these. For this ^pmpose fallow-crops^ as they were • Thaer, Agricaltnre ndsonn^e. 844 ROTATrON. called, were intrDcIuced. Peas, beans. vetcheS; were at first tht only plants used as fallow-crops. However, it was soon perceived that the fallow-crops occasioned a very sensible diminution in the produce of corn ; to counteract this inconvenience recourse was had to a surcharge of manure ; but as this cannot always be obtained, it was necessary either to reduce the cultivated surface or to appropriate a certain amount of meadow. Still the fallow-crops had this advantage, that they enabled the farm- er to derive from land a greater amount of produce in a given time without prejudice to the raising of corn. Hence the plan of turn ing the fallow to account was soon generally adopted. The introduction of clover so modified the system of fallow-crops as at one time to induce the belief that the point of perfection had been attained in agriculture.* This was when it was ascertained that trefoil, which had hitherto been only cultivated in small enclo- sures, might be sown in spring upon corn land, and occupy next year the place of the fallow in the triennial rotation. Trefoil, so far from exhausting the soil, was found to give it new fertility, and the succeeding corn crop yielded a plentiful harvest. It may be easily conceived what advantages were expected in substituting for the unproductive fallow the cultivation of a plant which did not impoverish the land, and furnished a quantity of ex- cellent fodder that served as food for an additional number of cattle. It was even alleged that this plant cleared the fields of weeds. A few years' experience sufficed to show that trefoil did not pos- sess all the advantages attributed to it. On renewing the clover every third year on the same piece of ground it sometimes failed. Schubarth, the most zealous and enlightened advocate for its use, limited the renewal of the artificial meadow at first to the sixth, and eventually to the ninth year ; and finding that it did not completely destroy the weeds in corn, he had recourse to hoed-crops for that purpose. The introduction of trefoil has gradually led to the system of al- ternate rotation of crops generally adopted at present ; and more- over, contrary to the anticipations of Schubarth, it may be renewed every four or five years on the same parcel of land. The impossibility of substituting trefoil for the fallow of the trien- nial rotation was offered as a fresh proof of the principle maintained from time immemorial by agriculturists, namely, that diflferent species of plants should be cultivated in succession on the same land, and that the same species should not recur except at considerable in- tervals ; the earth yielding much finer crops when the same species do not follow in immediate sequence. f Attempts have been made at various times to explain this pheno- menon. It was at first thought that different species of vegetables required a particular nutriment ; but it was soon perceived to be otherwise, and that the organs of each plant derived the necessary juices from substances which cone (r in the nutrition of vegetables ♦ Thaer, Africttlture ral»oiui*e. t Wd. ROTATION. 345 generally. In effect, plants the most opposite in botanical character and properties, alimentary as well as poisonous, will live and flourish on the same mound of earth, and with the same manure. Moreovei these plants reciprocally withdraw nourishment from one another, which could not occur did each species need different elements of nutrition.* When it was taken for granted that the organs of plants elaborate a common nourishment derived from the manure, then vegetables of diverse organizations were supposed endued with the faculty of searching at different depths for the nutritive matter contained in the soil, by reason of a more or less considerable extension and develop- ment of their roots. This served to explain hour a plant with long and perpendicular roots could, as a sequel to corn, derive benefit from manure situate in the undermost layers of ploughed land. It is possible that an action of this kind may take place under certain circumstances, but the explanation can never be generally re- ceived. Another explanation of the necessity for alternate crops is based upon properties assigned to the excretions of the roots, as compared to animal excrements. The excretion of roots, first observed by Brugman in the Viola arvensis,f has been confirmed by the recent observations of M. Ma- caire. This physiologist obtained the matter exuded from certain plants by keeping their roots in water ; but, strange to say, could not discover it in silicious sand in which certain vegetables had been grown. I I myself likewise failed in detecting sensible traces of organic matter in sand which had served as soil during several months to wheat and clover ; a result which renders the fact of radicular excretion doubtful. The excretion consequent upon im- mersion in water is perhaps the effect of disease. Be that as it may, upon the assumption of the excretion from roots, Messrs. Von Humboldt and Plenck have explained the cause of the attractions and repulsions of certain plants. § More recently M. de Candolle has reproduced this idea as the basis of a theory of rotation of crops. If it be supposed, in fact, that the excretion from the roots represents vegetable excrements, it may be easily imagin- ed that these excretions once deposited in the soil may be as pre- judicial to the plant which produced them as would be the excrement of an animal presented to it as food. On the other hand, by change of species, the plant newly implanted may profit by the excretions of the preceding crop, absorbing them as nourishment. This ingenious hypothesis is deficient in the groundwork, inasmuch as the fact of radicular excretion is not sufficiently established. Again, admitting the excretion, several facts concur to demonstrate that plants may thrive in soil charged with their dwn excrements. The culture of corn, for example, may proceed uninterruptedly, as we find in the triennial rotation. I have seen in the table-lands * De Candolle, t. i. p. 248. t Ibid. t. ii. p. 1497. t Ibid, t iu. p. 1474. $ De Candolle, t. iii. p. J474 846 ROTATION. of the Andes wheat fields, which had yielded excellent cr:ps annaa]- iy for more than two centuries. Maize may likewise be continually reproduced upon the same ground without inconvenienc-e : this fact is well known in the south of Europe ; and the greater portion of the coast of Peru has produced nothing else, from a date long ante- rior to the discovery of America. Further, potatoes may come again and again upon the same soil ; they are incessantly cultivated at Santa-Fe and Quito, and nowhere are they of better quality. In- digo and sugar-cane may be brought under the same category. In Europe the Jerusalem artichoke produces constantly in the same place.* It must be conceded, that if all these plants excrete from their roots, their excretions are not of such a nature as to interfere with the progress of vegetation of the species producing them. But the capital objection to the hypothesis of De Candolle is this, that it would be very remarkable indeed did any soluble organic matter, like such secretions, not putrefy when lying in the ground In a word, it is difficult to understand how it should resist for years, as is pretended, the decomposing influence of heat and moisture to« gether. That there is no absolute necessity for alternation of crops when dung and labor can be readily procured, is undeniable. Never- theless, there are certain plants which cannot be reproduced upon the same soil advantageously except at intervals more or less re- mote. The cause of this exigence on the part of certain vegetables is still obscure, and the hypotheses propounded for clearing it up far from satisfactory. One of the marked advantages of alternate cultures, is the periodic cultivation of plants which improve the soil. In this way a sort ol compensation is made for exhaustion. The main thing to be secur- ed in rotation of crops is such a system as shall enable the husband- man to obtain the greatest amount of vegetable produce with the least manure, and in the shortest possible time. This system cao be alone realized by employing in the course of rotation those plants which draw largely upon the atmosphere. The best plan of rotation in theory, is that in which the quantity of organic matter obtained most exceeds the quantity of organic matter introduced into the soil in the shape of manure. This does not hold quite in practice. It is less the surplus amount of organic matter over that contained in the manure, than the value of this same matter which concerns the agriculturist. The excess required, and the form in which it should be produced, must vary widely ac- cording to locality, commercial demand, and the habits of people, considerations wholly apart from theoretical provisions. One point * To this list might be added, according to the recent researches of M. Braconnot, ihe bay-rose with double flowers, and Papaver somniferum. That distinguished chemist terminates his memoir as follows : " My experiments are unfavorable, as may be perceived, to the theory of rotation of cops based on the excretions of the roots. These excretions if really occurring in the lormal state are so obscure and little known as to lead to the inference that the general system of rotations must be referred ta some other source." (Recherches sur I'influence des plantes sur le sol, Annales d« Chimie t Ixxii. p. 27.) ROTATION. 847 in theory that should agree with practice is this, that in no case is it possible to export more organic matter, and particularly more azo- tized organic matter, than the excess of the same matter contained in the manure which is consumed in the course of the rotation. By acting upon another presumption the productiveness of the soil would be infallibly lessened. This irrefragable condition as to the term of exportation from a farm suggests some critical remarks upon sundry notions lately pro- mulgated. The manufacture of beet-root sugar is an instance. European agriculture may probably derive certain advantages from this modern branch of industry, although these have been mu<^h overrated by certain speculators, who contend that sugar may thus be obtained through rotation of crops without lessening the other produce of the domain ; so that the sugar constitutes an additional source of income. This seems to me erroneous. If an estate yields annually 100 tons of beet-root for the support of cattle, their number must be diminished if the root is to he used for making sugar. The organic matter of the sugar extracted there- from, is just so much nourishment withheld from the cattle. To assert the contrary would be equivalent to saying that potatoes grown upon a couple of acres of land, and submitted to the process of dis- tillation before being employed as fodder, would feed as many animals as if eaten directly : assuredly, the organic principles of the potato converted into alcohol are lost as regards nutrition. This does not imply that the manufacture of indigenous sugar, and of potato spirit, is less productive than breeding and fattening cattle. My sole object is to show that only a limited quantity of organic matter can be advantageously exported from an agricultural establishment. It must depend upon local and commercial circum- stances whether this is to be exported in the form of sugar, corn, spirit, or butcher-meat. The above statement is in apparent contradiction with generally received notions. Many persons believe that the manufacture of sugar, instead of injuring, is favorable to the breeding of cattle. It appears, from a Parliamentary return on this subject, in 1836, that in certain estates where sugar was made, the number of animals was increased ; the numerical results are no doubt exact, but this augmentation in cattle is rather to be ascribed to an improved mode of farming than to the manufacture of sugar. In establishments where the triennial rotation with fallow was pursued, a rotation of four or five years with clover and weed-destroying plants has been introduced ; so that it is by no means to be wondered at, that inde- pendently of beet-root, there should have been a considerable increase in other things. The introduction of this root, where it was not formeny grown, is of itself an important melioration. But in highly cultivated countries, where the most productive rotations have been long followed, the extraction of sugar would not effect such advan- tageous changes as those announced in the above return. If at Bechelbronn a time should ever come, and at present it seems far distant, when.it wduld be deemed expedient to make sugar from the S48 ELEMENTS OF CROPS. beet there grown it would certainly be requisite to diminish the number of cattle, or else to annex more meadow land. It is only indirectly, therefo e, that the manufacture of home-sugar can pro- mote the breeding of cattle, and so prove serriceable to agriculture. From the definition given by me of the most advantageous course of crops, theoretically considered, it may be inferred how closely the study of rotations is connected with that of the exhaustion of the soil. Hence, to discuss the value of divers rotations, we must, in consonance with theory, compare the quantity of organic matter in a sequence of crops, with that in the manure expended upon them. From a well-managed farm, where for a series of years an invari- able system of culture has been steadily pursued, we must look for data. This I have done, as regards Bechelbronn, determining by analysis the composition of the manures and crops, and also of the more ordinary kinds of fodder or food. For a long time, a five years' rotation has been there adopted in the following order : 1st year.— Potatoes or beet-root manured. 2d year.— Wheat sown the autumn of the first year ; clover interposed In the spring. 3d year. — Trefoil (clover) two crops ; the third crop ploughed in or smothered. 4th year. — Wheat on the clover-break, turnips after the wheat. 5th year. — Oats. The crop of oats which ends the rotation is generally scanty. The soil is then brought back to the point of fertility which it had before being dunged ; and it is known by experience that it will not now yield a crop of any value. I now proceed to detail the analyses of the different substances which enter into the rotation, indicating at the same time the average produce per acre. POTATOES. In the rather strong soil of Bechelbronn one acre produces upon an average about 105 cwts. of potatoes. This is below the ordinary rate of Alsace, where the crop amounts to from 155 to 165 cwts. per acre. The leaves and stems are left upon the ground. A potato was cut in two, in order to subject it to analysis with a proportional part of the peel. The half weighed 335.2 grs. Stove- dried and reduced to flour, it weighed 289.3 grs. By absolute desic- cation in vacuo, at a temperature of 230° F. it was found that one of moist tuber became 0.241 ; 15.4 grs. left of ash 0.039. The average quantity of azote is 1.2. In 1836, I found 1.8 of azote. This notable difTerence, perhaps, depends on the analysis not having been made immediately after the harvest ; or it may be partly du3 to meteorological influences. To convince myself that it did not depend upon any error of analysis, I examined anew the potato of 1836, preserved in the farinaceous state : it yielded 1.8 of azote I shall, therefore, reckon the azote at 1.5 : I. II. Carbon 43.72 43.40 Hydrogen 6.00 5.60 Oxygen 44.88 45.60 Azote 1.50 1.50 Aih 3. 00 3.90 ELEMENTS OF CROPS. 349 WHEAT. I analyzed the grain gathered in 1837 : one of wheat, dried in vacuo at 230° F. was reduced to 0.885 ; one of dry wheat left of ash 0.0243 : Carbon 46.10 Hydrogen 5.80 Oxygen 43-40 Azote 2.29 Ash 2.43 100.00 The mean produce in wheat at Bechelbronn varies from 20^ to 22 bushels per acre ; this variation depends on the drill crop which commences the rotation. After potatoes the average crop is 19^ bushels; after beet-root, 17 bushels; on clover-breaks it is 24 bushels. The average weight of the grain is 63 lbs. per bushel. WHEAT-STRAW. I estimate the proportion of the produce in grain to that in straw, as 44 to 100. One of straw completely dried in vacuo at 230° F. becomes 0.740; one of dry straw leaves 0.0697 of ash : 1. n. Carbon 48-48 48-38 Hydrogen 5.41 5.21 Oxygen 38.79 39.09 Azote 0-35 0.35 Ash 6-97 69.7 100-00 100.00 RED CLOVER. Clover delights in clayey soils ; it thrives generally in good wheat lands ; in light and sandy ground it gets bare and frosted. During its growth, it always requires the shelter of some other plant. For this reason, in spring, it is generally sown among wheat, which is put in the preceding autumn, or barley sown the same spring. We generally give from 11 to 14 lbs. of seed per acre. Clover is mow- ed the second year, as it is coming into flower ; but when it is not to be consumed as green fodder, the mowing may take place before the flowering ; this is required from the difficulty of making it into hay. In fact, in the process of drying clover, there is great risk of losing part both of the leaves and flower ; besides, the drying always requires a considerable time, during which the clover runs the chance of being damaged by rain, and clover hay-making is almost im- practicable in wet weather. Schwertz proposed to dry the clover on a sort of parrot-perches stuck into the ground. These supports are but eight feet high, and capable of bearing a load of 2 cwt. of green fodder, mowed twenty-four hours, and already withered. This method, as I have seen it practised in the Duchy of Baden, answers well, but there is considerable cost for manual labor, and in the first instance for perches. Schwertz reckons that 2 cwts. of green clover 30 350 ELEMENTS OF CROPS. yield 48 lbs. of hay. The relation of green to dry fodder varies with the age of the plant, and the meteorological circumstances under which it has grown. Subjoined is the result of some experi- ments which I performed on the making of clover hay : 1 ton of clover in flower, 2d year (1841) afforded in hay 7 cwts. 1 ton of clover 1st year (1842) " 4 cwts. 2 qrs. 24 lbs. The average produce of this fodder reduced to hay at Bechel- bronn is 41 cwts. 3 qrs. per acre. One of clover hay, after complete desiccation, weighed 0.790 ; one of dry hay left 0.078 of ash : I. n. Carbon 47.53 47.19 Hydrogen 4.69 5.33 Oxygen 57.96 37.66 Azote 2.06 2-06 Ash 7.76 7.76 100.00 100.00 TURNIPS. When turnips are cultivated as a second crop, as after rye or wheat, the produce is very uncertain. Attempts are occasionally made to raise them after wheat which has followed clover. When cultivated on fresh manured soil, the produce is considera- ble ; in some places it amounts to from 28 to 33 tons per acre ; but as a second crop, we only obtain upon an average 7| tons per acre. This crop is only counted as a half-crop in the general produce of the rotation. Turnip is the most watery root I have examined. A slice weigh- ing 2 oz. 17 dwts. dried in the stove, was reduced to 4 dwts. After thorough desiccation, one of turnip weighed 0.075 ; consequently the root contains 92.5 per cent, of water ; one of dried turnip incin- erated, left 0.0758 of ash : I. n. Carbon 42.80 49.93 Hydrogen 5.54 5.61 Oxygen 42-40 42-20 Azote 1-68 1.68 Ash 7-58 7.58 100.00 100-00 OATS. As this grain closes the rotation, the produce is not great. The average crop is 37 bushels per acre, at the weight of 33^ lbs. per bushel ;* one of oats conrpletely dried weighs 0.792 ; one of dried •ats leaves 0.0398 of ash ; I. n. Carbon 50-32 51.09 Hydrogen 6.32 6.44 Oxygen 37.14 36.25 Azote 2.24 2.24 Ash 3-98 3-98 100.00 100-00 • This is but a light weight for a bushel of oats.— Ejf«. E». ELEMENTS OF CROPS. 851 OAT STRAW. Oat straw is estimated at about 15 cwts. per acre ; one part becomes, when dried in vacuo, 0.713 ; one part burned leaves 0.0509 of ash • Carbon 49.93 50-25 Hydrogen 5.32 5.48 Oxygen 39.28 38.80 Azote 0.38 0.38 Ash 5.09 5.09 100.00 100.00 riELD BEET OR MANGEL-WURZEL. Or a freshly manured soil, the average produce of beet at Bechel« bronn is 10 tons, 15 cwts. 1 qr. per acre. The worst crops do not fall below 5 tons, 2 cwts. 1 qr. 14 lbs., and the best do not exceed 16 tons, 7 cwts. 1 qr., results which I took occasion to.observe varied sensibly from those obtained in different places. I stated that Schwertz and Thaer make the average 14 tons, 14 cwts. 2 qrs. 16 lbs. Moelinger, after taking the mean of ten years, adopts 11 tons, 1 cwt. 3 qrs. 6 lbs. At Roville, M. de Dombasle speaks of 7 tons, 3 cwts. 26 lbs. as the mean of seven years. At Bechelbronn, the leaves of the beet are not given to cattle ; thpy are left upon the ground. A piece of beet-root weighing 1 oz. 16 dwts. was reduced to 4^'^^, say 5 dwts. after being stove dried. After complete desiccation, at 230° F. one part of root became 0. 122 ; one part of root left upon incineration 0.0624 of residuum : Carbon 42.75 42.93 Hydrogen 5.77 5.94 Oxygen 43.58 43.33 Azote 1.66 1.66 Ash 6.24 6.24 100.00 190.00 RYE. Rye is seldom introduced into the rotation at Bechelbronn. They reckon its produce at 26 bushels per acre, when it has had a sup- plementary dose of manure. The bushel weighs fully 58 lbs. I have taken the proportion of grain to straw as 45 is to 100. One part of rye, dried at 230° F. weighed 0.834 ; one part incinerated left 0.0237 of ash : 1. n. in. Carbon 46.35 4.5.72 46.38 Hydrogen 5.38 5.70 5.74 Oxygen 44.21 44.52 43.82 Azote 1.69 1.69 1.69 Ash 2.37 2.37 2.37 100.00 100.00 100.00 RYE-STRAW. One part of straw, completely dried, weighed 0.813 ; one part of which, incinerated, left 0.0368 of ash : 852 ELEMENTS OF CROPS. Carbcn 49.88 Hydrogen 5.58 Oxygen 40..')6 Azote.. 0.30 Ash..... 3.68 100.00 WHITE PEAS Raised on manured land yielded 16 buihels per acre, weighing fully 62 lbs. per bushel. One part of peas, after complete desicca- tion, weighed 0.914 ; one part of dried peas left of ash 0.0314 : I. n. Carbon 46.06 46.94 Hydrogen 6.09 6.34 Oxygen 40.53 39.50 Azote 4.18 4.18 Ash 3.14 3.14 100.00 100.00 PEA STRAW. One acre of peas produces about 22 or 23 cwts. of straw ; one part of the straw after desiccation weighed 0.802 ; one part after incine- ration 0.1132 : Carbon 45.80 Hydrogen 5.00 Oxygen 35.57 Azote •••• 2.31 Ash 11.32 100.0C JERUSALEM POTATO OR ARTICHOKE. In Alsace, Jerusalem artichokes are always grown on one and the same piece of land, which is manured every two years. At Bechelbronn, on a somewhat shallow soil, the produce per acre amounts to : Tubers 10 tons Dry stems Hi cwts. A tuber which weighed on being taken from the ground 1 oz. IS^nr dwts , weighed ^ dwts. after it was dried in the stove. Afler absolute desiccation, one part was reduced to 0.208 ; one portion of the dry tuber left 0.0594 after incineration : n. Carbon 4-12 43.62 Hydrogen 5.91 5.80 Oxygen 43.56 43.07 Azote 1.57 1.57 Ash 5.94 5.94 100.00 100.00 DRIED STEMS OF JERUSALEM ARTICHOKES. These stems had stood through the winter where they grew, and were almost wholly composed of pith. One part after desiccation weighed 0.871 : one part left of ash 0.0276. ELEMENTS OF CROPS. 358 Carbon 45.68 Hydrogen 5.43 Oxygen 45.72 Azote 0.43 Ash 2.76 100.00 I fear that in this analysis the carbon and azote are rated too low. I have collected in two tables the results of the analyses as detail, ed above. The first exhibits the quantity of dry matter and moisture contained in each specimen ; the other, the elementary composition. On careful examination of the numbers given in the second table, certain substances will be found very analogous in composition. If the ashes be deducted, the analogy becomes complete ; for many substances differing widely both in character and properties, never- theless appear to possess the same composition ; a fact which I do not undertake to explain. TABLE OF THE PROPORTIONS OF WATER CONTAINED IN DIFFERENT SUBSTANCES. Substancet. Dry matter. Water. Wheat 0.855 0.145 Rye 0.834 0.166 Oats 0.792 0.208 Wheat-straw 0.740 0.260 Rye-straw 0.813 0.187 Oat-straw 0.713 0287 Potato 0.241 0.759 Field-beet 0.122 0.878 Turnip 0.075 0.925 Jerusalem potato 0.208 0.792 Peas 0.914 0.086 Pea-straw 0.882 0.118 Clover-hay 0.790 0.210 Jerusalem potato-stems • • • . • 0.871 0.129 COMPOSITION OF THE SAME SUBSTANCES DRIED IN VACUO AT SSO* FAHR. SUBSTANCES. Ashes included. Ashes deducted. 1 i >« 1 S so < 1 d X 3 •< \Y^gjit 46.1 46.2 50.7 48.4 49.9 50.1 44.0 42.8 42.9 43.3 46.5 45.8 47.4 45.7 05.8 05.6 06.4 05.3 05.6 05.4 05.8 05.8 05.5 05.8 06.2 05.0 05.0 05.4 43.4 44.2 36.7 38.9 40.6 39.0 44.7 43.4 42.3 43.3 40.0 35.6 37.8 45.7 02.3 01.7 02.2 00.4 00.3 00.4 01.5 01.7 01.7 01.6 04.2 02.3 02.1 00.4 02.4 02.3 04.0 07.0 03.6 05.1 04.0 06.3 07.6 06.0 03.1 11.3 07.7 02.8 47.2 47.3 52.9 52.1 51.8 52.8 45.9 45.7 46.3 46.0 48.0 51.5 51.3 47.0 06.0 05.7 06.6 05.7 05.8 05.7 06.1 06.2 06.0 06.2 06.4 05.6 05.4 05.6 44.4 45.3 38.2 41.8 42.1 41.1 46.4 46.3 45.9 46.1 41.3 40.3 41.1 47.0 02.4 01.7 02.3 00.4 00.3 00.4 01.6 01.8 01.8 01.7 043 02.6 02.2 00.4 Rve Wheat- straw ... Rye-straw Oat-straw Field-beet Turnip Jerusalem potato Pea-straw Clover-hay Jerusalem pota- to-stems 30* 854 ELEMENTS OF MANFRE. RELATIONS OF MANURES TO CROPS. The manure employed at Bechelbronn is what is commonly called farm-yard dung, a compost made up of the excrements of horses, oxen, and straw litter impregnated with urine. The dung of fowls and pigeons, and the sweepings of the yard, are sometimes applied to special purposes. The animals whose excrements form the dung" which I have examined were horses, oxen, and swine. The manure is put upon the ground when it has undergone fer- mentation in the heap : it is manure half-made : the straw litter is not entirely decomposed, but is soft and filamentous ; in this state manure retains a great deal of moisture. DESICCATION OF HALF-MADE OR HALF-DECAYED MANURE. EXPERIMENT I. A quantity of manure prepared during the winter of 1837-1838, which in the state in which it was being put on the ground, weighed 257 lbs after it had been dried so as to be easily reduced to powder, weighed 57 lbs. The loss of water was therefore about 77.3 in 100 This number comes very near the estimate of several German agriculturists, who reckon the moisture in farm-yard dung at 75 per cent. Still this loss does not represent the whole of the water ; for after desiccation at 212° F. the 57 lbs. weighed 54 lbs. In fine, after desiccation in vacuo, at 230° F. it was found that one part of stove-dried manure lost 0.039. Thus the manure parted in totality with 79.62 per cent, of water, and contained in consequence 20.4 of dry substance. EXPERIMENT II. Of the manure prepared in the winter of 1838-1839, 220 lbs. after being chopped and dried weighed 56 lbs. One part of this manure was reduced in dry vacuo at a temperature of 230° F. to 0.872. The 280 lbs. would therefore have weighed when dry 48 lbs. EXPERIMENT III. Of the manure prepared during the summer of 1839, 660 lbs. weighed after desiccation 151 lbs. ; of this dry manure reduced to powder, one part lost by desiccation in vacuo at 230° F. 0.1461. The 151 lbs. would therefore have lost 22 lbs. ; consequently the 660 lbs. of manure contained 129 lbs. of dry matter, that is, 19.64 per cent. Subjoined is a summary of the per centage of dry matter : First experiment 20.4 Second " 22.2 Third ♦ 19.6 Average 20.7 Moisture (average) 793 ANALYSES OF HALF-MADE MANURES. I. Manure prepared during the winter of 1837-1838: Matter 0.5595, gave carbonic acid 0.528, water 0.157 : C. 32.4, H. 3.8^ Asote 1.7.— 1.0 gave ashei 0.462. ELEMENTS OF MANURE. 355 II. Manure prepared during the winter of 1837-1838 : Matter 0.575. gave carbonic acid 0.676, water 0.212 : C 32.5, H. 4.1, .A.zote 1.69.— 1.000 gave ashes 0.357. III. Manure prepared during the winter of 1837-1838: Matter 0.567, gave carbonic acid 0.791, water 0.232 : C. 38.7, H. 4.5, Azote 1.73.— 1.000 gave ashes 0.264. IV. Manure prepared during the spring of 1838 : Matter 0.586, gave carbonic acid 0.759, water 0.308 : C. 36.4, H. 4.0, Azote 2.4.— 1.000 gave ashes 0.381. V. Manure prepared during the spring of 1839 : Matter 0.445, gave carbonic acid 0.643, water 0.171 : C. 40.0, H. 4.3, Azote 2.4.-1.000 gave ashes 0.257. VI. Matter 0.427, gave carbonic acid 0.543, water 0.150 : C. 34.7, H, 3.9. " 0.427, " " 0.530, " 0.127 : " 34.3, " 4.8, Azote 2.0.-1.000 gave ashes 0.315. COMPOSITION OP THE MANURES ANALYZED. Carbon. Hydrogen. Oxy^^en. Azote. Salts and earthly I. 32.4 3.8 25.8 1.7 36.5 II. 32.5 4.1 26.0 1.7 35.7 III. 38.7 4.5 28.7 1.7 26.4 IV. 36.4 4.0 19.1 2.4 38.1 V. 40.0 4.3 27.6 2.4 25.7 VI. 34.5 4.3 27.7 2.0 31.5 Mean . . . 35.8 4.2 25.8 2.0 32.2 In all these analyses, the combustion was promoted by the addi- tion of chlorate of potash ; some oxide of antimony was likewise added. The carbonic acid of the ash was determined and struck off. The measure of dung in use at Bechelbronn is the wagon drawn by four horses. After repeated weighings it was found that this measure contains nearly 1 ton, 15 cwts. 2 qrs. 23 lbs. of moist material, or 7 cwt. 1 qr. 15 lbs. if that be computed dry. The first course of the rotation receives 27 loads of this manure, weighing about 48 tons, 14 qrs. 5 lbs., equivalent to 9 tons, 19 cwts. 0 qr. 2 lbs. of dry ma- nure.* The preceding analyses show that this charge of manure, which is to fertilize the soil during the course of the rotati/>n ^five years) contains : Carbon .- 8027 lbs. Hydrogen 925 Oxygen 5767 Azote 447 Salts and earth 7188 22355 Such are the principles vi4iich together form the organic matter that is to be consumed and in major part assimilated by the crops » I presume that the quantity above specified is that which is laid on the French hectare, equal to 2.4 acres English. To get at the quantity laid on per acre, it would therefore be necessary to divide by 2 4-10 : Thus 48 tons, 14 cwts. 5 lbs. per hectare will be equal to 20 ton's, 1 cwt. 3 qrs. per English acre.— Enq. Ed. 356 relax:, ns of elements grown. I say partly, because I do not believe that the whole or ganic matter necessarily enters into the constitution of the plants which spring up during the rotation ; no doubt a considerable por- tion of the manure is lost through spontaneous decomposition, or is carried away by the rain ; and another portion may remain a long time dormant in the soil, to act as a fertilizer at a more or less dis- tant period ; just as in the present rotation the manure formerly in- troduced co-operates with that recently added. One thing is certain, viz., that the proportion of manure indicated is essential for a\erage crops ; by diminishing it the produce is necessarily lessened. Last- ly, it is proved that after the rotation the crops have consumed the manure, and the earth will not yield its increase unless a fresh quan- tity be added. I now proceed to consider the relation subsisting between the quantity of organic matter buried in the soil as manure, and what is recovered in the crops. In this way the respective proportions of elementary matter which various crops derived from the air and the soil, may be determined approximately, and a knowledge obtained of those rotations which least exhaust the land, or in other words, which obtain from the atmosphere the largest amount of organic matter. The rotations set down in Tables I. and II. are those definitively adopted at Bechelbronn, and throughout the greater part of Alsace. These two rotations, which differ only in the hoed crop introduced, potatoes in one, beet-root in the other, are almost identical ; nearly the same quantity of dry matter being produced per acre, and nearly the same quantity of organic material withdrawn from the atmo- sphere. The rotation No. 3 was introduced by Schwertz at Hohenheim ; theoretically, it is one of the most advantageous ; it was tried at Bechelbronn but abandoned, because, from meteorological causes, peas and vetches fail frequently. Table No. 4, shows the triennial rotation with manured fallow ; this is disadvantageous in point of theory. The organic consti- tuents of the crop exceed but little those of the manure. Suppos- ing that even the whole of the straw were converted into manure, the farmer would still be compelled to procure manure from abroad, in compensation for the out-going of wheat. It is thus obvious why triennial rotation always requires a great deal of meadow land. In table No. 5, the result of the continuous cultivation of Jerusa- lem artichokes is given. At Bechelbronn these are dressed every two years with about ten loads of dung per acre. Upon an average 20 tons of tubers and about 2 tons of woody stems are gathered in the course of two years. It will be perceived from perusal of this table, that the culture of Jerusalem artichokes presents, theoretical- ly, considerable advantages. The organic matter of the crop greatly exceeds that of the manure. Moreover, in Alsace, where it is very common, it is held to be most productive. Still, the organic matter of the stems must be taken into account, which, practically speak- ing, are nearly worthless. IN CROPS AND MANURE. 357 Table No. 6 comprises the data relative to a quadrennial rotation, adopted by M. Crud, and in which are grown successively : 1st. Potatoes or beet-root. 2d. Wheat. 3d. Red clover. 4th. Wheat. The first sowing is dressed with about 18 tons of half-wasted farm- yard dung. The gain in organic matter obtained by this rotation surpasses that of the preceding ; but as the clover crops are not very sure when repeated every four years, M. Crud, for reasons which may be called in question, follows this rotation with one of lucern, which gets a fresh supply of manure. It cannot be denied that lu- cern furnishes a great mass of fodder, and in this respect the fertili- ty of the land ought to be vastly enhanced, were this consumed on the spot ; but I can discover no objection to the renewal of clover, if the lucern succeeds so well as M. Crud says it does. From too frequent repetition, farmers have gone into the opposite extreme of cultivating clover only every five or six years. This subject offers an important field for research. It is not impossible that the ill- success depends often on premature mowing of the clover during the first year, and before its roots have acquired sufficient vigor. This practice has been abandoned with us for some years, and there is now every thing to assure us that the second year's crop is there- by secured. ROTATION COURSE No. 1. Years, Substances. Crops per acre. Crops dry. Carbon. Hydro, gen. Oxygen. Azote. Salts and earths. 1st 2d 3d 4th 5th Potatoes .... Wheat .... Wheat-straw . . Clover-huy . . . Wheat .... Wheat-straw . . Turnips C2d crop) . Oat-stra*w' ! *. ! Manure employed . Difference . . . lbs, 'ii? 2798 1650 1052 1300 1? 975 1176 1244 1002 1750 2832 185 75 135 lbs, 1264 99; 458 'SI- % i 10 5 1 li 1 1! 179 1 60 37050 4495 16307 9314 10236 3426 891 391 6575 2403 229 185 ^ 6993 6810 500 4172 44 a»3 ROTATION COURSE No. 2. Years. Substances. Crops per acre. Crops dry. Carbon. Hydro- gen. Oxygen, Azote, Salts and earths. Ist 2d ■ 6th ^K'"."™'. : Wheat-straw . . Clover-hay . . . Wheat .... Wheat-straw . . Turnips .... Oat-straw' '. '. '. Total Manure employed Difference . . . lbs, 2383 fJ^ 11675 1520 3456 1630 lbs, 1827 lbs. 281 'iii i '1 135 36 lbs. 1 lbs, i 7 77 30 10 ^1 'la ,1 1 i 60 27224 4495 16018 9314 7505 3426 11 6423 2403 231 185 S_ 6704 4079 473 4020 46 2024 S53 RELATIONS OF ELEMENTS. ROTATION COURSE No. 3. Yean. Substances. Crops per acre. Crops dry. Carbon. Hyd- J- gen. Oxygen. Azote. Salts and earths. lbs. lbs. lbs. lbs. lbs. lbs. lbs. 1st Potatoes .... 11733 2^ 1244 164 1264 42 113 2d Wheat .... 1231 1054 485 61 457 24 25 W^heat-straw . . 2;98 2070 1002 110 805 8 145 3d Clover-hay . . . 4675 3693 1750 185 1396 78 284 4th Wheat .... 1515 1300 75 564 30 31 Wheat-straw . . 3456 2558 1238 135 995 10 179 Turnips .... 8754 656 282 36 11 50 5th Peas (dunged) . . 1001 915 425 56 366 38 28 Pea-straw . . . 2558 22.56 1033 112 803 255 6th Rye 1539 1278 590 71 565 22 30 Rye-straw . . . Total 3420 2780 1387 155 1129 « 100 148280 21388 10035 1160 8622 323 1240 Manure employed Difference . . . 148285 11176 4000 470 2883 223 3599 10212 6035 690 5739 100 2359 ROTATION COURSE No. 4. Years. Substances. Crops per acre. Crops dry. Carbon. Hydro- gen. Oxygen. Azote. SalU and earths. 1st 2d&3d Dung^^ fallow. . Straw Total Manure employed Difference . . . lbs. 9041 6875 lbs. 2600 5080 lbs. 2462 lbs. 150 270 lbs. 1128 1979 lbs. lbs. '62 356 S 7680 3795 3413 1358 420 159 'S fS 418 1222 8414 3885 2055 261 2128 4 804 No. 5, CONTINUOUS POTATO CROPS- ! Yean. 1 Substances. Crops per acre. Crops dry. Carbon. Hydro- gen. Oxygen. Azote. Salts and earths. l8t&2d Potatoes .... Stalks .... Total Manure employed . Difference . . . S lbs. 10289 .1 10289 lbs. 161 90 lbs. 605 630 74323 41663 32580 8624 ■S ■1^ '^ 251 172 1235 2777 23956 11568 1438 12430 79 1542 No. 6, QUATRENNIAIi ROTATION, ADOPTED BY M. CRUD. Yean. Crops grown. Crops per acre. ELEMENTARY INGREDIENTS OF THE CROP. •ir Carbon. Hydro- gen. Oxygen. Azote, SulU earths. Ist 2d&4th 8d Hdlf acre of ^tatoes Ditto of beet-rooU . Wheat. 153 bushels . Wheat-straw . , . Clover three cuttings Total Manure consumed . Difference .... lbs. 9167 lbs, 2847 5243 5793 lbs. 1312 1 290 '1 1235 2190 38 if 121 1^ S 8524 2989 991 a30 7422 2154 278 167 1110 2688 9980 5535 641 6268 111 1578 IN CEOPS AND MANURE. 859 SUMMARY. 1 Dry manure Dry produce •5 expendetl upon Azote con- obtained in Azote con- ic maiterni Gain in aiote 1 one acre in tained in the one year upon tained in the one year upon \a one year one year. manure. one acre. produce. one acre. upon one acre. 1 lbs. lbs. lbs. lbs. lbs. lbs. No. 1 1862 37 3261 46 1996 9 No. 2 1862 37 3204 46 1746 9 No. 3 1862 37 3564 54 2513 17 No. 4 1247 23 2567 26 1565 3 No. 5 3710 86 16299 125 12758 39 No. 6 2087 42 4582 70 2889 . From all that precedes, it is obvious that rotations which include trefoils, red clover, lucern, and sainfoin, are those that afford con- siderably the largest proportion of organic matter ; a fact, indeed, which if not legitimately established, has still been long acted on in that system of cropping which embraces forage plants as an ele- ment. Lucerns, too, when they have taken kindly, yield an extra- ordinary quantity of forage, as every one may see by turning to the produce of the piece under that crop which in the system of M.Crud succeeds the quatrennial rotation. At the end of his rotation, M.Crud always lays on manure in the ratio of 18 tons per acre, which lasts for six years, and may be said to suffice for the succession of crops in the appended table : Crops. Produce per acre. Contents in azote. Luceradry, 1st year 3080 lbs. 72 lbs 2dyear 9240 215 3d year 114.58 269 " 4th year 9240 213 " Sthyear 7333 172 Wheat, 6th year 1448 28 Straw 3645 11 980 Dang employed 40233 205 Total gain in azote 775 Gain in azote per annum and per acre 130 In glancing at these tables, it is obvious that the azote of the crop always exceeds the azote of the manure. Generally speaking, I admit that this excess of azote is derived from the atmosphere : but I do not pretend to say in what precise manner the assimilation takes place. I shall only quote the conclusion of a paper which I published on the subject in the year 1837.* Azote may enter immediately into the constitution of vegetables, provided their green parts have the power of fixing it ; azote may also enter vegetables dissolved in the water which bathes their roots, and which always contains it in a certain proportion. Lastly, it is possible that the air may contain an infinitely minute quantity of arnmoniacal vapor, as some natural • Annales de Chimie, t. liix. p. 366. 360 BELATIONS OF ELEMENTS philosophers* have maintained, and that this assimilated, decom- posed, and recomposed anew by the plant, is the source of its azotized constituents. § 2. OF THE RESIDUES OF DIFFERENT CROPS. The vegetable matter which is produced in the course of a season is never found entirely in the crop. A certain quantity of it, for instance, always remains in the ground. It is, therefore, a point of interest to ascertain what quantity of elementary matter is left in the soil after each kind of crop in the rotation ; precise knowledge of this description may even be important in calculating rotations, for it is obvious that the remains of the crop now on the ground must influence that which is to follow, and in the course of a rotation the sum of the residuary matters must be regarded as a supplement oi addition to the manure put into the ground at its commencement. In the systems of rotation very generally followed at the present time, the infloence of these residuary matters is manifest, and it is partly by their means that we can explain how a quantity of manure, frequently very moderate, should suffice for the whole of the crops in a productive rotation. The remarkable effect of clover has not failed to arrest attention even from the most unobserving. The wheat crop which comes after our drill crop in Alsace, beet or potatoes, averages from 18 to 20 bushels per acre ; but the wheat crop that succeeds our clover averages from 23 to 24 bushels per acre. The improvement of the soil, so obvious in connection with clover, in all probability also occurs in connection with the residues of other crops ; but as in most instances the residue merely compensates the loss, or lessens its extent, the effect produced is less remarkable, and is less, indeed, in amount. All the world acknowledge, then, that the residues of the crops that enter into a rotation compensate in greater or less degree for what is carried away in the shape of harvest, and that in some cases they even add to the fertility of the soil ; for in growing crops that leave a large quantity of residue, it is precisely as if a smaller quantity were taken from a given extent of surface. But what is the amount of residue or refuse which is returned to the soil by such and such a crop ? What, in a word, is the value of this residuary matter considered as manure ? This is a point upon which only the most vague and indefinite ideas are generally entertained ; and it was with the purpose of substituting positive facts for mere guesses, that I determined on weighing and analyzing the vegetable residue of the several crops that enter as elements into our more usual rotations. My experiments were made upon breadths of land which varied from 120 to 500 square yards in extent. The clover roots and stubble were taken up with the spade, and before being dried, were freed from adhering earth by washing. The beet-leaves and pota- to-tops were dried at once in the oven ; and it was from each of the * Saoisore Recberches Chimiques, and Liobig, Agricultural Chemistry. IN CROPS AND MANURE. 36 general masses reduced to powder that samples were taken for ulti- mate analysis, before proceeding to which, they were carefully dried in vacuo at 230° F. It is not likely that any accurate mean result should have been come to from^ an examination of the produce of a single season. I should even say that the year in which these inquiries were under- taken was little favorable to them, inasmuch as the crops were gen- erally bad ; but it is obvious that they form a nucleus, around or by the side of which the results of other seasons may be arranged, and an average from larger premises come to. POTATO TOPS OR HAUM. A piece of land measuring 120 square yards, marked off from a spot that had suffered from drought, yielded 47.0 lbs. of green tops, which were reduced by drying to 18.4 lbs. A similar extent of surface, selected from a part of the field that looked well, gave green tops 79 lbs., which dried in the air were reduced to 16 lbs. We should thus have 23^ cwts. of green, and 6j cwts. of dry tops per acre. The crop of potatoes in 1839 yielded at the rate of 101^ cwts. per acre. One hundred grammes, or 3 oz. 4 dwts. 8 grs. troy, of the top dried in the air, lost 12 grammes, or 7 dwts. 17 grs. by thorough drying at 230° F. The weight of the tops yielded per acre, taken as dry, consequently amounts to 5 cwts. 2 qrs. 14 lbs., and by elementary analysis they were found to have the following composition : Carbon 44-8 Hydrogen 5.1 Oxygen 30.5 Azote 2.3 Salts and earths 17.8 100.0 LEAVES OF FIELD-BEET, OR MANGEL-WURZEL. Upon a surface of 500 square yards, 976 lbs. of leaves were gath- ered, the weight being taken two days after the roots were pulled up. 55 lbs. of leaves reducible to powder by drying in an oven, were brought to 6.6 lbs. 3 oz. 4 dwts. of leaves dried and pulverized, lost by desiccation at 230" F. 3| dwts. of moisture. The 6.6 lbs. brought to that state of dryness would have weighed 6.1 lbs. With these data it is found that the 976 lbs. of green leaves gathered upon 500 square yards would have weighed when dry 108.9 lbs. ; and that the acre produced 85| cwts. of green and 9| cwts, of dry leaves. The crop of roots which answers to that quantity of leaves, was in 1839 but 6 tons, 2 cwts., that is to say, little more than half a crop ; for our average is about 10| tons. COMPOSITION OF DRY LEAVES. Carbon 38.1 Hydrogen 5.1 Oxygen 30.8 Azote 4.5 Salts and earths 21.5 100. 0 31 ORGANIC ELEMENTS : MANl' RES AND CRCPS. WHEAT STUBBLE. From 120 square yards of ground we have obtained 13 lbs. of Btubble dried in the air. The same isurface in another field produced 171 lbs. Thus we have 5| cwts. of stubble per acre ; but as wheat recurs twice in the rotation, the residues must be doubled ; say, IH cwts. Stubble loses 0.26 of moisture when dried completely at 230°. In 1839, the wheat after the drilled crop, or £tfter clover, was onlj 17 bushels per acre. I have assigned to stubble the same composition as that of straw. CLOVER ROOTS. A surface of 120 square yards gave 44 lbs. of roots, vveighed after being thoroughly dried in the sun ; when pulverized after drying in the stove the weight was reduced to 37 lbs. 3 oz. 4 dwts. of powdered roots lost by drying, at a temperature of 230° F., 5 dwts. of moisture. Thus the 44 lbs. of roots dried in the sun would have weighed 34 lbs., and one acre would have furnished I2f cwts. of residue perfectly dry. In 1839, the clover crop when reduced to hay was far below the average. COMPOSITION OF THE ROOTS. Carbon 434 Hydrogen 5.3 Oxygen 36.9 Azote L8 Salts and earth 12.6 100.0 OAT STUBBLE. The residue of the oat crop, which concludes the rotation coarse, does not act upon the present, but on the next rotation ; in the same way as the organic remains left in the ground by the oats which ter- minated the antecedent course, exerted their influence upon the present one. In 1839, the oat crop was above the average ; it was as high as 16 cwts. 2 qrs. 18 lbs. per acre. One French are of the land, equal to 120 square yards English, yielded 20 lbs. of stubble dried in the air, or at the rate in round numbers of 8 cwts. per acre. In the following table I have given a srimmary of the results above stated, combining therewith the quantity ind the comi>osition of the manure expended in the rotation. ORGANIC ELEMENTS OF MANc^ES AND CROPS. 363 •UMMARY OF THE FOREGOING RESULTS. Nature of the crop. hat 0^ II 1^ Potatoes . Beetroots . Wheat . . Clover-hay Oats .... bs. 11367 s lbs. 2739 1^ 1810 1474 9527 Total . . . 31349 Manure employed 44995 Nature of the residues buried in the soil. Potatoetops . Beetroot leaves Stubble. . . . Roots dried in the sun . . . Stubble .... ^1. 1* Elementary matter of the residues. ?^5 is Is 1 1 i >> s < ^§1 t lbs. .a 950 1418 596 460 615 •299 r 75 32 1^- 1 lbs. 14 48 4 1, lbs. 67 178 30 16182 '4664 2066 244 1643 94 617 9314 3335 391 2403 186 2995 It therefore appears that the refuse or residue of the several crops of a rotation represent, both in quantity and nature, somewhat less than one half of the manure originally put into the ground ; I say somewhat less, because it must be remembered that in the sum of these residuary matters, the beetroot leaves and potato tops must not be allowed to stand together, the one crop naturally excluding the other, or at all events the two hoed or drilled crops not entering in this proportion into the same rotation. The large quantity of organic matter restored to the soil by several of the crops in the series, consequently explains how the rotation may be closed without its being found indispensable to supply any additional manure in its course. It seems indubitable that without this addition of elementary matter, the fertility of the soil would decline much more rapidly than it does ; the residue of each crop is nothing more than a portion of the crop itself restored to the ground ; it is as if we only carried off one portion, the larger portion of the crop, and buried another portion green. In the five years' rotation, it may be observed that there are two crops, the hoed crop and the forage crop, which yield substa^ices to the ground that are both abundant in quantity and rich in azotized matter, and it is unquestionable that these crops act favorably on the cereals which succeed them. But data are wanting for the appre- ciation of their specific utility in the general rotation. We see, for instance, that despite the large proportion of residuary matter left by the beet or mangel-wurzel, this plant lessens considerably the pro- duce of the wheat crop that comes after it. The potato, though it leaves much less refuse than the beet, seems nevertheless to act lesa unfavorably than this vegetable. Clover leaves more residue than the potato, and on this ground, alone, ought to favor the cereal that follows it ; but it has a favorable influence out of all proportion with its quantity, contrasting this with the residue of either of the hoed crops ; a fact from which we learn that the visible appreciable influ- ence of the residuary matters of preceding crops, upon the luxuriance of succeeding crops, does not result solely from their mass, even supposing earh to be possessed of equal qualities ; this other, this 364 INORGANIC ELEMENTS OF MANURES aN^ CBOPS. additional effect, depends especially on an influence exerted on the Boil by the crops wiiich leave them. Had these crops been power- fully exhausting, we should expect that their refuse or residue, how- ever considerable in quantity, could do no more than lessen the amount of exhaustion produced ; in which case, its useful influence, however real, would pass unnoticed, were it estimated by the produce of the succeeding crop. If, on the contrary, a crop has been but slightly scourging, whether in consequence of the smallness of its quantity, or because it may have derived from the air the major part of its constituent elements, the useful influence of the residue will not fail^to be conspicuous. When the relative value of different sys- tems of rotation is discussed in the way we have done, we in fact estimate the value of the elementary matter derived from the atmo sphere by an aggregate of crops ; but the procedure generally fol- lowed is silent when the question is to assign to each crop in particular the special share which it has had in the total profit. To reply to this question, of which a knowledge of the various residues is one of the elements, we must first ascertain the quantity of ele- mentary matter supplied by the soil and the atmosphere, with refer- ence to each of the crops which enter into the rotation ; in other words, the same investigations must be undertaken in reference to each plant considered by itself, that have been made in reference to the series collectively. There is unquestionable room, in this direc- tion, for an important series of experiments. § 3. OF THE INORGANIC SUBSTANCES OF MANURES AND CROPS. We have but just considered the organic matter developed in a series of successive harvests. To complete the study of rotations, to the extent at least that this can be done in the present state of science, we have still to examine the relations that may exist between the mineral substances which enter into the constitution of the pro- duce, and those that make part of the manure given. We have already shown in a general way that certain mineral salts, certain saline matters or salifiable bases, are essential to the constitution of vegetables. To the best of my knowledge, no seed has yet been met with that is without a phosphate ; and it is now known that the alkaline salts powerfully promote vegetation. Such is their ascertained influence, indeed, that tobacco, barley, and buckwheat sown in soils absolutely without organic matter, but containing saline substances, and only moistened with distilled water, produced perfect plants, which flowered and fruited, and yielded ripe seeds.* Whence it follows, that the presence of saline matter fa- vors remarkably the assimilation of the azote of the atmosphere during the act of vegetation. The importance of considering rotations in connection with the inorganic substances that are assimilated by plants was perfectly well known to Davy. " The exj rtation of grain from a country which receives nothing in exchange that can be turned into manure, must exhaust the soil in the long run," says the illustrious chemist - • Lieblg, in Journ. de Pharmacie, vol. Iv., 3d series, p. 94. INORGANIC ELEMENTS OF MANURES AND CROPS. 36ri who ascribed to this cause the present sterility of various parts of Northern Africa and of Asia Minor, as well as of Sicily, which for a long succession of years was the granary of Italy. Rome un- questionably contains in its catacombs quantities of phosphorus from all the countries of the earth. Professor Liebig, in insisting with the greatest propriety on the useful part played by alkaline bases and saline matters in vegetation, has shown the necessity of taking inorganic substances into serious consideration in discussing rotations. It is long since I came to the same conclusion myself; but it strikes me, that to be truly profitable, such a discussion must necessarily rest on analyses of the ashes of plants which have grown in the same soil, and been manured with the same dung, the contents of which in mineral elements were al- ready known. There is in fact a kind of account current to be es- tablished between the inorganic matter of the crop and that of the manure. Although I give every credit to the fidelity of the analyses of vegetable ashes that have been published up to the present time, I have not felt myself at liberty to make use of any of them in the direction which I now indicate. I have not thought that it would be fair or reasonable to contrast such heterogeneous compounds, as the ashes of plants grown at Geneva and Paris, under such dissimilar circumstances, with those of vegetables produced on a farm of Al- sace, where the point to be explained, through the results of this contrast, had reference to a particular series of agricultural phenom- ena. And then my business was not merely with the scientific ques- tion ; the manufacturing or commercial element in the consideration also touched me. I had to ascertain how I was likely to stand at some future time, did I presume to act upon the conclusions to which I came. There was nothing for me therefore but to analyze the ashes of the several vegetables which entered as elements into the rotation followed at Bechelbronn, but confining my inquiries to that portion of the vegetable which is looked upon particularly as the crop, so much of the plant as remains on the ground and is turned in again, of course taking nothing from it. The ashes examined were almost all from the crops of 1841, two analyses having generally been made of each substance : and here I ought to say, that in this long and tedious labor, in which I spent Dearly a whole year, I was most ably seconded by Mr. Letellier. By way of preface, I should say that in these analyses, losses will fre- quently be apparent, which for the most part exceed the limits that in the present day are tolerated in the more careful operations of the laboratory. These deficiencies, which puzzled me a good deal at first, I by and by discovered to proceed from the difficulty of incin- crating certain vegetable substances completely. When they abound in alkaline salts, they leave ashes that melt so readily, that it becomes difl[icult to prevent their agglutination, and the charcoal that is not consumed is then effectually protected against any further action of the fire. There is nothing for it in such cases but to incinerate at the lowest temperature possible, and then a little moisture is apt to be left ; the charcoal, however, is the substance that occasions th« 31* 866 INORGANIC ELEMENTS OF MANURES .-. ND CROPS. main difficulty, and the more important loss. To quote one of the instances, that of wheat, where the loss or deficiency is as high as 24 per cent. I may say that a direct inquiry after charcoal brought it out equal to 2, by which the actual deficiency is reduced to 0.4. I have not, however, introduced any correction for carbon, but pre- sent the reader with the results as they actually presented them- selves to me. Among the number of the products of the analyses, alumina figures beside the oxide of iron. Alumina is an earth which I have always met with in minimum quantity in the ashes of plants, and is perhaps accidental ; it may proceed from the earth which ad- heres to all herbaceous plants, and from which it is so difficult to free them completely. COMPOSITION OF THE ASHES PROCEEDING FROM THE PLANTS GROWN AT BECHELBRONN. Acids. V 3 11 ■5* Substances which n . •z P V ^ 1 g ■~e m yielded the ashes. -i-- i?,^ « 15 ts 53 ^■f "^•s ^^ O ^ g-i "e Potatoes .... 13.4 7.1 i 11.3 2.7 1.8 5.4 51.5 traces .•j.6 0.5 0.7 Mangel-wurzel Turnips . . lfi.l 1.6 6.1 5.2 7.0 4.4 :«.o 6.0 8.0 2 5 4.2 14.0 10.9 6.0 2.9 10.9 4.3 33.7 4.1 6.4 1.2 5.5 Potato tops . 11.0 2-2 10.8 1.6 2.3 1.8 44.5 truces 13.0 5.2 7.6 Wheat. . . (M) 1.0 ! 47.0 traces 2.9 15.9 iW.5 traces 1.3 0 0 2.4 Wheat-straw 0.() 1.0 i 3.1 0.6 8,5 5.0 9,2 0,3 67.6 1.0 3.7 Oats . . . 1.7 1.0 14.9 0.5 3.7 7.7 12.9 0.0 5;i.3 1.3 3.0 OaUstraw . 8.2 4.11 3.0 4.7 8.3 2.8 24,5 4.4 40.0 2.1 2.9 Clover . . 2.5.0 2.5 6.3 2.6 24.6 6.3 0.5 5.3 0.3 0.0 Peas . . . 0.5 4.7 30.1 1.1 10.1 11.9 35 3 2.5 1.5 traces 2.3 French beans 3.3 1.3 26.8 0.1 5.8 11.5 4.9.1 0.0 1.0 traces 1.1 Horse beans . 1.0 1.6 34.2 0.7 5.1 8.6 45.2 0.0 0.5 traces 3.1 1 1 If these analytical results be now applied to the produce of an acre of ground, we should have the precise quantities of minera. substances abstracted from the soil by each of the several crops tha enter into the rotation. Here they are in a table : MINERAL SUBSTANCES TAKEN UP FROM THE SOIL BY THE VARIOUS CROPS GROWN AT BECHELBRONN UPON ONE ACRE, 1 i 1 < P Acids. 1 i 1 1 1 i 0 Crop. II 11 Ih^. Ih^ lbs. Ihs, IM IN. llw. lbs. lb.. lbs. lbs. Potatoes 2828 4.0 113 13 8 3 2 6 1 58 6 "a Beet-roots .... 2908 6 3 183 11 3 9 13 81 82 15 Half crop of turnips, ) consumed off the> mi 7.6 50 8 5 U 2 19 3 0.7 ground, S Potato tops ....•' 5042 6,0 303 33 7 A m 5J9 16 Wheat . . 1052 24 25 12 0.3 ' R 7 0.4 , , WheatJtraw 2,^58 70 179 5 1.5 1 1 17 121 li Ojit-straw' .' 1^5 40 39 6 0.4 0,2 lii 5 21 0.6 1176 5 1 60 u 2.5 3 1-5 17 24 1 -AiKi 77 284 18" 7 7 70 18 77 15 0.9 Manured peas 915 31 28 8 1.2 0? 3 3 10 0.5 traces. French beans 1448 3,5 51 13 0.7 01 3 6 2.i 0.6 traces. Horse beans . . . 1944 3.0 58 20 0.75 0.5 3 5 ^ 0.3 traces. INORGANIC ELEMENTS OF MANURES AND CROPS. 367 On looking at this table we perceive that a medium crop of wheat takes from one acre of ground about 12 lbs., and a crop of beans about 20 lbs. of phosphoric acid ; a crop of beet takes 11 lbs. of the same acid, and further, a very large quantity of potash and soda. It is obvious that such a process tends continually to exhaust arable land of the mineral substances useful to vegetation which it con- tains , and that a term must come when, without supplies of such mineral matters, the land would become unproductive from their ab straction. In bottoms of great fertility, such as those that are brought under tillage amidst the virgin forests of the New World at the pres- ent day, it may be imagined that any exhaustion of saline matters will remain unperceived for a long succession of years ; for a sue cession of ages almost. And in South America, where the usual preliminary to cultivation is to burn the forest that stands on the ground, by which the saline and earthy constituents of millions of cubic feet of timber are added to the quantities that were already contained in the soil, I have already had occasion to speak of the ample returns which the husbandman receives for very small pains.* Under circumstances, in the neighborhood of large and populous towns, for instance, where the interest of the farmer and market- gardener is to send the largest possible quantity of produce to mar- ket, consuming the least possible quantity on the spot, the want of Baline principles in the soil would very soon be felt, were it not that for every wagon-load of greens and carrots, fruit and potatoes, corn and straw, that finds its way into the city, a wagon-load of dung, containing each and every one of the principles locked up in the several crops, is returned to the land, and proves enough, and often more than enough, to replace all that has been carried away from it. The same principle holds good in regard to inorganic matters, which we have already established with reference to organic substances. The most interesting case for consideration is that of an isolated farming establishment — a rural domain, so situated that it can obtain nothing from without, but exporting a certain proportion of its pro- duce every year, has still to depend on itself for all it requires in the shape of manure. I have already shown, with sufficient clearness, I apprehend, how it is that lands in cultivation derive from the at- mosphere the azotized principles necessary to replace the azotized products ff the farm, which are continually carried away in the shape of grain, cattle, &c. I have now to show how the various saline substances, the alkalies, the phosphates, &c., which are also exported incessantly, are replaced. I believe that I shall be able, with the assistance of chemical analysis, to throw light on one of the most interesting points in the nature and history of cropping, and succeed in practically illustrating the theory of rotations. In what is to follow immediately, I shall always reason on the practical data collected at Bechelbronn, and which have already served for the * The first breaks of the early English settlers in North America are now either very Indifferent soils, or they have only been restored to some portion of their original fer- tility by monarlng; so that the supply of fertilizing eletoents is not inexhaustible — Exa Eo 868 INORGANIC ELEMENTS OF MANXTRES AND CBOPS. illustration of other particulars. My farm, I may say, by way of preliminary, is an ordinary establishment ; the lands which have been brought by a system of rational treatment to a very satisfactory state of fertility, are not rich at bottom and originally, and they fall off rapidly if they have not the dose of manure at regular intervals, which is requisite to maintain them in their state of productiveness. My first business was to determine the nature and the quantity of the mineral substances contained in my manure ; and with a view to arrive at this information, I burned considerable quantities of dung at different periods of the year, mixed the ashes of the several in cinerations, and from the mixture took a sample for ultimate analysis The mean results are represented by : (Carbonic 2.0 Acids < Phosphoric 3.0 (Sulphuric 1.9 Chlorine 0.6 Silica, sand 66.4 Lime 8.6 Magnesia 3.6 Oxide of iron, alumina 6.1 Potash and soda 7.8 100.0 But our farm-yard dung is not the only article we are in the habit of giving to our land ; it further receives a good dose of peat-ashes and gypsum. I here recall to the reader's mind that the mean com- position of peat-ashes is this : Silica 65.5 Alumina 16.2 Lime 6.0 Magnesia 0.6 Oxide of iron 3.7 Potash and soda 23 Sulphuric acid. 5.4 Chlorine • 0.3 100.0 In the system followed at Bechelbronn, the farm-yard dung laid upon an acre contains 26 cwts. 3 qrs. of ashes. On our clover leas we spread the first year 7 cubic feet of turf-ashes ; and in the begin- ning of spring of the second year, we lay on as much more, say 14 cubic feet, in all weighing about 2 tons. I do not take the 8 cwts. of gypsum which, in conformity with usage, the second year's clover generally receives, because I believe this addition to be perfectly useless after the very sufficient dose of peat-ash which we employ. The whole of the mineral substances given to the land in the course of five years per acre is as follows, viz. : Ashes contained in the manure and in the peat-ashes, 7624 lbs. ; consisting of phos- phoric acid 90 lbs., sulphuric acid 304 lbs., chlorine 4.5 lbs., lime 532.5 lbs., magnesia 135.6 lbs., potash and soda 339 lbs., silica and sand 4630 lbs., oxide of iron, &c., 353 lbs. It is therefore easy to perceive, from the preceding data, that what with the manure and the ashes it receives, the land is more than supplied with all the mineral substances required by the sev- eral crops it produces in the course of the rotation. Let us cast a INORGANIC ELEMENTS 0/ MANURES AND CROPS. 369 glance over these with reference to their mineral or inorganic con- stituents, as we have already done in so far as the organic matters are concerned ; let us compare, in a word, the quantity and the na- ture of the mineral substances removed in the course of five succes- sive years, in contrast with the quantity and the nature of the same substances supplied at the commencement of the series, and we shall find that the sums of the phosphoric acid, sulphuric acid, and chlo- rine, and of the alkaline and earthy bases of the crops, are always smaller than the quantities of the same substances which exist in and are supplied to the arable soil. I shall institute the comparison with the rotation No. 1, which begins with potatoes ; and further, with a continuous crop which, as the one that is most common and convenient, shall be Jerusalem artichokes. I have not thought it advisable to discuss the rotation No. 2, in which beet replaces the potato, because the ashes of these two crops are so much alike, that it may be assumed to be matter of indifference which of the two enters as the drill-crop element into the series. With reference to the Jerusalem artichoke, I shall only remind the reader that the piece of land where it grows receives a dose of manure every two years, in the proportion of 41245 lbs. per acre, which manure contains 2776 lbs. of mineral constituent. Fur- ther, in the course of each winter peat-ashes, in the ratio of 2700 lbs. per acre, are laid on the land ; and that the stems are generally in- cinerated on the spot, and the ashes they contain returned directly to the soil. TABLE OF THE MINERAL MATTERS OF THE CROPS AND MANURES IN THE COURSE OF A ROTATION. Average crop per acre. Mineral substances in the crops. ACIDS. 15 O S .S fcC 1 i Phos- phoric Sul- phuric ROTATION NO. 1. Potatoes ...••.... lbs. 113 .50 358 284 39 60 50 lbs. 13 24 11 18 6 I' lbs. 8 4 7 f lbs. 3 2 7 3 1 lbs. 2 1 30 ,0 5 5 lbs. 6 8 18 18 3 ¥ lbs. 58 15 34 77 5 17 19 lbs. 6 242 15 20 24 3 TM ttn • iia t-stra w Sum of mineral substances Mineral substances of the manure Excess over the mineral matters of 927 7582 '^ 27 304 16 32 114 533 56 136" 225 339 310 5049 605 14 65 277 13 15 9 417 14 79 11 114 270 4736 79 INCESSANT PRODUCTION OF THE JE- RUSALEM POTATO. Island 2d years: mineral matters 2777 4583 65 53 248 17 14 239 275 100 27 219 105 1843 3002 TMtlft nf tiirf n«>iAa Whole mineral matters of manures Difference in favor of the manures 83 301 31 514 127 324 4845 18 287 20.5 500 117 52 4767 870 INORGANIC ELEMENTS OF MANURES AND CROPS. It was at one time asserted, that in order to ensure to a crop of wheat the necessary quantity of phosphates, its cultivation w^as pre- ceded by one of roots or tubers, or leguminous plants, which were supposed to contain a much less proportion of these salts. By ref- erence, however, to the table of mineral substances, removed from the soil by different crops, the absurdity of such reasoning becomes evident. For example, beans and haricots take 20 and 13.7 lbs. of phosphoric acid from every acre of land ; potatoes and beet-root from the same surface take but 11 and 12.8 lbs. of that acid, exactly what is found in a crop of wheat. Trefoil is equally rich in phos- phates with the sheaves of corn which have gone before it, and this large dose of phosphoric acid withdrawn from the soil, will nowise diminish the amount which will enter into the wheat that will by and by succeed the artificial meadow. It may be readily under- stood, that if the ground contains more than the quantity of mineral substances necessary for the total series of crops in a rotation, it is a matter of indifi'erence whether the crops draw upon the soil in any particular order, and these succeed according to rules generally adopted for quite different reasons. It suits well, for instance, to begin a rotation with a drill crop sown in spring, and which, conse- quently, follows in our system the oats which closed the preceding rotation ; it is a great advantage to be able to collect and cart out the manure during winter. Besides, the order is quite at the farm- er's discretion, and there are places where, from particular reasons, quite another course is pursued. One part of the produce returns, as has been shown, to manure, after having served as fodder for the animals belonging to the farm. The inorganic matters are restored to the earth from which they came, deducting the fraction assimi- lated in the bodies of the cattle. Lastly, the whole of the wheat, and a certain amount of flesh will be exported, and with these a no- table quantity of inorganic matter. Thus, in the above described rotation of five years, the minimum exportation of saline substances which must be removed from every acre of land, may be represent- ed by 27| lbs. of phosphoric acid, and from 36 to 45 lbs. of alkali ; this is just so much lost for the manure, and as there is definitively found at the end of the rotation a quantity of manure equal and nearly similar to that disposed of at the commencement, it is essen- tial that the loss of mineral substance be made up from without, unless it be naturally contained in the soil. In my first researches on the rotation of crops,* I stated that wherever there are exportable products, it becomes indispensable to keep a large proportion of meadow land, quoting, as an extreme case, the triennial rotation with manured summer-fallow. It is, in fact, the meadow which restores to the arable land the principles which have been carried off. This point, advanced upon analogy, is amply confirmed by the results of analysis. I have examined, in reference to this question, the ashes of the hsLy of our meadows of Durrenbach, irrigated by the Sauer. The * Memok COTununkated to the Acad^mie des Science^ in 1838 INORGANIC ELEMENTS OF MANURES AND CROPS. 371 analyses were made with ashes furnished by the crops of 1841 and 1842. I. II. III. Average (Carbonic 9.0 5.5 " 7 3 Acids < Phosphoric 5.3 5.3 5.5 5.4 (Sulphuric 2.4 2.9 " 2.7 Chlorine 2.3 2.8 " 2.6 Lime 20.4 15.4 " 17.9 Magnesia 6.0 8.3 " 7.2 Potash 16.1 27.3 " 21.7 Soda 1.2 2.3 " 1.8 Silica 33.7 29.2 " 31.5 Oxide of iron, &c 1.5 0.6 0.5 0.9 Loss 2.1 0.4 " 1.0 100.0 100.0 100.0 No. 1 yielded 6.0 per cent, of ash. No. 2 " 6.2 idem. In admitting as the average yearly return of our irrigated mead- ows, 3666 lbs. of hay and after-grass for the acre, it appears that we obtain, from a corresponding surface of land, 223.6 lbs. of ash, containing : (Carbonic 16.3 Acids < Phosphoric 12.1 (Sulphuric 6.0 Chlorine 5.7 Lime 39.1 Magnesia 16.1 Potash and soda 52.0 Silica 70.4 Oxide of iron, andloss:. 4.2 221.9* In reckoning, as I have done, the lowest annual exportation of mineral substance from one acre of arable land at 5.5 lbs. of phos- phoric acid and 8.2 lbs. of alkali, (potash and soda,) there must, in order to make up for loss, arrive each year at the farm a quantity of hay corresponding to about 1800 lbs. for every acre of ploughed land, which would establish between the arable and meadow land, a relation somewhat less than 1 to ^. In practice, the relation in question is sensibly less than that de- duced from analysis ; in some farms the meadow-land only occupies a fourth or fifth of the whole surface. When rye replaces wheat, the extent in meadow-land may be still more limited. It deserves notice, that I have supposed the arable land as destitute of proper inorganic matter, and that all came from the manure ashes and lime laid on, which is not rigorously true. Tnere are soils containing traces of phosphates, and it is difficult to find clay or marl exempt from potash. Nevertheless, many clear-headed practical men begin to suspect that meadow has been too much sacrificed to arable land. In localities placed in similar conditions to those in which we are, removed from every source of organic manures, which, as I have shown in concert with M. Payen, are always furnished with saline * The sura Is only too small here from the number of places of dedtnals not havli|| been carried out far enough. — Evo. Ed. 372 INORGANIC ELEMENTS OF MANURES AND CROPS. principles, an attempt has been made to imitate what is done in more favored districts, where it is possible, for example, to add animal remains to the manure. The corn crops felt this new procedure ; nor could it be otherwise. But now there is a reaction in the op- posite sense, and I could name most thriving establishments, where one-half of the farm is in meadow. The ever-increasing demand for butcher-meat will further this movement to the great advantage of the soil. In consequence of our peculiar position at Bechelbronn, nearly halt 3ur land is meadow, which allows of a large exportation of the prodjce of the arable land. In applying the results of the preceding analyses, I find that each year, provided there is no loss the hay ought to bring at least : 1254 lbs. of phosphoric acid, 627 602 « it sulphuric acid, chlorine, 4155 u lime, 1672 5456 7312 magnesia, potash and soda, silica. This large amount of mineral substances is supplied by the mead- ows, which have no other manure than the water and mud thereby deposited, after flowing over the Vosges' freestone ; they receive no manure from the farm, but are merely earthed with the sludge and mire borne down by the stream ; these are real sources of saline impregnation. Meadows without running water ought not to be ranged in the same category, they only give the principles naturally contained in them ; hence, they must be always manured ev^ry three or four years, and indeed, if not situate upon a naturally rich soil, are, according to my experience, very far from profitable. The excess of mineral matters introduced into the ground over those that issue with the crops, an excess that ought always to be secured by judicious management, enriches the soil in saline and alkaline principles, which accumulate in the lapse of years, just as vegetable remains and azotized organic principles accumulate un- der a good system of rotation. By this, even in localities the most disadvantageously situate for the purchase of manure, temporary recurrence may be had to the introduction of such crops as flax, rape, &c., which being almost wholly exported, leave little organic residuum in the earth, and at the same time carry oflf a considerable quantity of mineral substance ; circumstances which determine, as may be easily conceived, the maximum of exhaustion, and for that reason wend to reduce a soil becoming over-rich to what may be called the standard fertility. In reviewing the chief points examined it will be seen, that as far as regards organic matter, the systems of culture which in borrow- ing most from the atmosphere, leave the most abundant residues in the land, are those that constitute the most productive rotations. In respect to inorganic matter, the rotation, to be advantageous, to have an enduring success, ought to be so munaged that the crops ex- INORGANIC ELEMENTS OF MANURES AND CROPS. 373 ported should not leave the dung-hill with less than that constant quantity of mineral substance which it ought to contain. A crop which abstracts from the ground a notable proportion of one of its mineral elements, should not be repeatedly introduced in the course of a rotation, which depends on a given dose of manure, unless by the effect of time mineral element has been accumulated in the land. A clover crop takes up, for example, 77 lbs. of alkali per acre. If the fodder is consumed on the spot, the greater portion of the potash and soda will return to the manure after passing through the cattle, and the land eventually recover nearly the whole of the alkali. It will be quite otherwise if the fodder is taken to market ; and it is to these repeated exportations of the produce of artificial meadows that the failure of trefoil, now observed in soils which have long yielded abundantly, is undoubtedly due. Accordingly, a means has been proposed of restoring to these lands their reproductive power, by applying alkaline manure.* If under such circumstances carbo- nate of soda would act as favorably as carbonate of potash or wood- ashes, the soda salt, in spite of its commercial value, might prove serviceable, and deserves a trial. The lime manures naturally promote the growth of plants of which calcareous salts form a constituent ; but here a capital distinc- tion must be made. A soil may contain from 15 to 20 in the 100 of lime, and still be unable to dispense with calcareous manure ; be- cause the lime is in some other state than as it exists in chalk, as in the rubbish of pyroxene, mica, serpentine, and the like. A soil of this kind, although replete with lime, might still require gypsum for artificial meadow, and chalk for wheat and oats. It is from the carbonate that plants of rapid growth derive the lime essential to them, as was established by the researches of Rigaud de Lille, re- searches which have been censured by agricultural writers to whom they were unintelligible. I advocate the opinion of Rigaud, be- cause in the Andes of Riobamba I have seen lucern growing in au- gitic rubbish, very rich in calcareous matter, and yet greatly bene- fited by liming. The operation of gypsum is to introduce calcareous matter into plants. This I have endeavored to demonstrate from the analysis of the ash on the one hand, and on the other, from the consideration that finely divided carbonate of lime, as it exists in wood-ashes, acts with equal efficacy upon artificial meadows. By what means gyp- sum, if it does not enter the vegetable as a sulphate, parts with its sulphuric acid, is at present conjectural. It appears highly proba- ble that calcareous matter is chiefly beneficial from the particular action it exercises on the fixed ammoniacal salts of the manure, transforming these successively, slowly, and as they may be wanted, into carbonate of ammonia. In the most favorable condition, the earth is only moist, not soaked with water, but permeable to the air. New researches will perhaps illustrate the utility of ammoniacal va- pors thus developed in a confined atmosphere, where the roots are * Infiarmation communicated by M. Schattenmaim, 32 374 INORGANIC ELEMENTS OF MANURES AND CROPS, in operation. At least, it would be difficult to assign any other office to chalk in the marling or liming of land intended for corn, when we know how little lime corn absorbs. If, indeed, gypsum promotes the vegetation of trefoil, lucerne, sainfoin, &c., by furnishing the needful calcareous element, it could not fail to exercise an equally farorable agency upon wheat and oats, did they require it. The ex- periments adduced prove it not to be so, and their results are in some measure corroborated by analysis. Thus, if we compare the different quantities of lime withdrawn from the soil by trefoil arvd corn, we find them as follows : The clover crop takes from 1 acre of ground nearly 70 lbs. of Ume. Wheat " " " 16 Oat ^ " " " 6.4 " With this comparison before us, it seems evident that if the marl- ing and liming of corn lands had no other object than the introduc- tion of the minute portion of lime which is encountered in the crops, it would be difficult to justify the enormous expenditure of calcare- ous carbonate which is proved by daily experience to be advan- tageous. It may be inferred from the foregoing, that in the most frequent case, namely, that of arable lands not sufficiently rich to do without manure, there can be no continuous cultivation without annexation of meadow ; in a word, one part of the farm must yield crops with- out consuming manure, so as to replace the alkaline and earthy salts that are constantly withdrawn by successive harvests from another part. Lands enriched by rivers alone permit of a total and contin- ued export of their produce without exhaustion. Such are the fields fertilized by the inundations of the Nile ; and it is difficult to form an idea of the prodigious quantities of phosphoric acid, magnesia, and potash, which in a succession of ages have passed out of Egypt with her incessant exports of corn. Irrigation is, without doubt, the most economical and efficient means of increasing the fertility of the soil, out of the abundant for- age which it produces, and the resulting manure. Plants take up and concentrate in their organs the mineral and organic elements contained in the water, sometimes in proportions so minute as to es- cape analysis ; just as they absorb and condense, in modified forms, the aeriform principles which constitute but some 10,000th parts in the composition of the atmosphere. It is thus that vegetables col- lect and organize the elements which are dissolved in water, and disseminated through the earth and the air, as a preparative to their being assimilated by animals. jRlGm OF ANIMAL PRINCIPLES. 375 CHAPTER VIII. OF THE FEEDING OF THE ANIMALS BELONGING TO A FARM; AND OF THE IMMEDIATE PRINCIPLES OF ANIMAL ORIGIN. ^ I. ORIGIN OF ANIMAL PRINCIPLES. It is now generally admitted that the food of animals must ne- cessarily contain azote ; and this circumstance has led to the infer- ence, that the herbivorous tribes obtain from their food the azote which enters into the constitution of their bodies. In a general way, the individual consuming a certain portion of food every day, nevertheless does not increase in his average weight. This is what occurs with animals upon the quantity of food which is known to be sufficient for their keep ; and it has been found that the human subject, living very regularly, returns at a cer- tain hour, or at certain hours of the day, to a certain mean weight. Grooms, farm servants, &c., are perfectly well aware of the fact, that with a certain allowance of hay and corn, a horse will be kept in the condition necessary to do the work required of him without either gaining or losing in flesh. Under such circumstances, the whole of the elementary matter contained in the food consumed, ought to be found in the dejections, the excretions, and the products of the act of respiration. And as- suming that this is so, it might then be maintained that none of the elements is assimilated, assimilation being taken in the sense of an addition of principles introduced with the food to the principles al- ready present in the body. Yet is there unquestionably assimila- tion, in the sense that the alimentary matters of the food become fixed in the system, having there undergone modification or change ; and that they replace, or come instead of other elements of the same kind, which are daily thrown oflf by the vital acts of the economy. During the nutrition of a young animal, and also in the process of fattening an adult, things go on differently ; here there is unques- tionably definitive fixation of a portion of the matter contained in the food : there is no longer balance between the waste and the supply ; an animal then increases in weight notably and rapidly. Looking at the question of feeding in the most general way, then, I admit that an adult animal, upon the daily allowance, voids a quantity of matter in its various excretions precisely equal to the quantity which it receives in its food :* all the elements, the sajnne in nature and in quantity, which are contained in the food, are also contained in the excrements, vapors, and gases, which pass off from the living body ; carbon and azote, hydrogen and oxygen, phospho- * Boussinganlt, Annales de Chimie, 3e sirie, t. Ixzzi, p. IH 376 ORIGIN OF ANIMAL PRINCIPLES. rus, sulphur, and chlorine, calcium, magnesium, srdium, potassium and iron, as they are all encountered in the food • j are they all en countered in the body, and also in the excretions cf an animal ; ana it seems certain, that no one of these primary or simple substance* can be wanting in the nutriment without the body very speedilj feeling the ill effects of its absence. Iron, for example, is a con stant principle in the coloring matter of the blood ; it also exists ii large quantity in the hair ; and he who should live on food that con tained no trace of it would certainly, and before long, become disor dered in his health. In what has just been said, I take it for granted that animals dt not absorb or assimilate any of the azote which forms so large a constituent in the air they breathe ; and I am warranted in this by the researches of every physiologist of any name or distinction. Not only do animals obtain no azote from the atmosphere, but they actu- ally exhale it incessantly, as was proved by M. Despretz in the course of his numerous experiments, and as I myself also demon- strated in the inquiries I undertook to ascertain whether herbivorous animals obtained azote from the air or not. The azote exhaled, it was discovered, proceeded entirely from the food consumed by the animal ; a fact which, already of great importance in a physiologi- cal point of view and in reference to general physics, bears at the same time so immediately upon one of the most important questions of agriculture, that I think it well to give the particulars of one of the procadures by which it has been established. The experiments in this case were performed on a milch-cow and a full-grown horse, which were placed in stalls so contrived that the droppings and the urine could be collected without loss. Before boing made the subjects of experiment, the animals were bal- lasted or fed for a month with the same ration that was furnished to them during the three days and three nights which they passed in the experimental stalls. During the month, the weight of the ani- mals did not vary sensibly, a circumstance which happily enables us to assume that neither did the weight vary during the seventy-two hours when they were under especial observation. The cow was foddered with after-math hay and potatoes ; the horse with the same hay and oats. The quantities of forage were accurately weighed, and their precise degree of moistness and their composition were determined from average samples. The water drunk was measured, its saline and earthy constituents having been previously ascertained. The excrementitious matters passed were of course collected with the greatest care ; the excrements, the urine, and the milk were weighed, and the constitutiaji of the whole estimated from elementary analyses of average specimens of each. The results of the two experim* Us are given in this table : ELEMENTS OF FOOD AND OF EXCRETIONS. 377 FOOD CONSUMED BY THE HORSE IN 24 HOURS. | Weight in the wet state. Weight in Elememary matter in the food. 1 Forag^e. tlie dry state. Carbon. [Hydrogen. Oxygen, j Azote. S«lis and enrihs. Water. - . Total, . . lbs. 20 6 43 lbs. oz. lbs. oz. 7 11 2 7 Ib.oz. dwt. 0 10 7 0 3 18 lb. oz.Uwi. lb. oz.dwt. 6 8 8.03 2 1 10 14 1 0 1 7 b. oz.dwt. 1 6 14 0 2 10 0 0 8 69 23 6 10 6 1 1 2 5 8 7 2 1 0 4 9 1 9 12 PRODUCTS VOIDED BY THE HORSE IN 24 HOURS. Producti. Weig-ht in the wet state. Weight in the dry state. Elementary matter in the producu. 1 Carbon. Hydrogen. Oxygen. Azote. Salts and earths. Urine. . - Excrements, - Total* matter of ? the food, . 5 Difference, lb. oz. dwt. lb. oz. dwt. 0 9 14 9 5 6 lb oz.dwt. §11? Ib.oz. dwt. 0 0 7 0 5 15 lb. oz. dwt. 0 1 2 3 6 14 lb.oz.dw.. 0 1 4 0 2 10 lb. oz. dwt. 0 3 10 1 6 10 41 8 17 69 0 0 10 3 0 22 6 0 3 11 7 10 6 0 0 6 2 1 2 5 3 7 16 8 7 2 0 3 14 0 4 9 1 10 0 1 9 12 27 3 3 Il2 3 0 6 6 13 0 8 3 4 11 6 0 0 15 0 0 8 WATER CONSUMED BY THE HORSE IN 24 HOURS. WATER VOIDED BY THE HORSE IN 24 HOURS. With the hay, .... With the oats, . . - . Taken as drink. .... Total eonsurned. lbs. oz. 2 3 With the urine With the excrements. Total voided, Water consumed, ... lbs. oz. J i 38 4 25 14 38 4 Water exhaled by pulmonary and cutaneous transpiration, 12 6 FOOD CONSUMED BY THE COW IN 24 HOURS. Fodder Weight in the wet st&t«. Weight in the dry ttate. Elementary matter ot the food. Carbon. Hydrogen. Oxygen. | Azote. Salts and earths. Potatoes, . . Atler-math hay. Water, . . Total. . . lb. oz. dwt. ^f 1 160 0 0 lb. oz. dwt. 11 2 1 16 11 0 lb. oz. dwt. 4 11 2 7 11 11 Ib.oz. dwt. 0 7 15 on 7 lb. oz. dwt. lb. 02. dwt. 4 10 17 1 0 1 12 5 10 17 0 4 17 lb. oz. dwt. 0 6 13 1 8 6 0 1 12 220 3 7 28 1 1 12 10 13 1 7 2 10 9 14 0 6 9 2 4 U PRODUCTS VOIDED BY THE COW IN 24 HOURS. Product*. Weight in the wet slate. Weight in the dry state. Elementary matter in the producU. Carbon. Hydrogen. Oxygen. Azote. Salts and earths. Excrements, . Urine, . . Milk. . . Total, " matter of food. Difference. lb. oz. dwt. 76 1 9 21 11 12 22 10 10 lb. oz. dwt. 3 1 0 lb. oz.dwt. 4 7 0 0 8 7 1 8 3 lb. oz.dwt. roil 0 3 3 lb. oz.dwt. tl 1 0 10 6 lb. oz. dwt. lif'l 0 1 9 lb. oz. dwt. 0 1 16 120 11 11 220 3 7 16 4 9 28 1 1 6 11 10 12 10 13 0 10 12 1 7 2 5 6 18 10 9 14 0 5 11 0 6 9 2 5 10 2 4 11 99 3 16 11 8 12 5 11 3 0 8 10 5 2 16 0 0 18 0 0 19 WATER CONSUMED BY THE COW IN 24 HOURS. WATER VOIDED BY THE COW IN 24 HOURS. With the potatoes. With the hay, .... Taken as drink. . . . • T**a1 consumed. lbs. oz. I'l 132 0 With the potatoes. With the urine With the milk. ... Total voided Water consume'', .... lbs. oz. 53 10 15 14 16 3 158 5 .i'l Water passed off ay pulmon Etry and eu taneou stre nspiration » - . _raj!9 378 COMBUSTION OF CARBON. From these f?ams it appears that the azote of the excrements is less by from 339.6 to 455.0 grains than that of the forage consumed. It appears also that the whole q. antity of elementary matter con- tained in the excrements is less than that which had been taken as food ; the difference is of course due to the quantities which were lost by respiration and the cutaneous exhalation. The oxygen and hydrogen that are not accounted for in the sum of the products have not disappeared in the precist proportions re- quisite to form water ; the excess of hydrogen amounts to as many as from 13 to 15 dwts. It is probable that this hydrogen of the food became changed into water by combining during respiration with the oxygen of the air. The loss of carbon, which is very considerable, seeing that in the two experiments it aBiounts to nearly 12^ lbs., must have gone to form the carbonic acid, which is known to be so large and import- ant a constituent in the expired air, and which is also exhaled from the general surface of the body. Neglecting the latter, it appears that each of the animals produced in the course of twenty-four hours upwards of 13 cubic feet of carbonic acid gas, the thermome- ter supposed at 32*^ F., the barometer at 30 inches.* During respiration, then, or as a consequence of respiration, the carbon and hydrogen of the food have disappeared and given rise, by the concurrence of the oxygen of the air, to carbonic acid and water, precisely as if they had been burned. And an animal may, in fact, be regarded as an apparatus or system, in which a slow com- bustion is incessantly going on ; there is perpetual disengagement of carbonic acid gas and of the vapor of water, just as there is from a stove in which any organic substance, wood, for example, is burn- ing. In either case there is evolution of heat ; all animals have a temperature above that of the medium which surrounds them, and the excess of the elevation is in some sort relative to the activity of the respiratory process, or, in other words, to the intensity of the combustion. Under the influence of the oxygen that is taken into the body, the soluble principles of the blood pass through a series of modifications, the last of which is carbonic acid, which is exhaled and dissipated in the air ; and it is in this way that a portion of the carbon of the food is returned to the atmosphere, after having accomplished the important function of supplying the animal with the heat that is ne- cessary to its existence. Far from deriving any thing from the air, consequently, animals, on the contrary, are continually pouring car- bon into it. The food is, therefore, the only source whence animals derive the matter that enters into their constitution ; and, as tho primary food of animals is obtained from vegetables, herbivorous creatures must necessarily find in the plants they consume all the ♦ The large quantity of carbonic acid shows the necessity for large and well-venti- lated stables and cow-houses. A cow, i* appears, will vitiate 66 cubic feet of air in a day. It will bs observed in the table tliat the saline and earthy matters of th« ejects exceed those of the ingesta in both instances. This is from error in observa tlon, and is owing to the difficulty of d Uermining exactly the quantities of these sab ftaaces. The error is less in the case vf the hon* than in that of the cow. IDENTITY OF ANIMAL AND VEGETABLE PRINCIPLES. 370 elements they assimilate. It might be expected from this, that the material constitution of animals should approach, and sometimes even be identical with that of vegetables ; and it is found, in fact, that a considerable number of ternary or quarternary organic compounds, of either kingdom, present the greatest analogy to one another ; their identity, in some cases, is even complete. Some fatty substances of animal origin do not differ in any way from vegetable fats ; the margaric acid which is obtained from hog's lard has the precise characters of the margaric acid which is furnished by olive oil, and the same identity is preserved through the entire series of quarter- nary azotized principles, as a glance at the following table, which contains the results of the analyses performed by Messrs Dumas and Cahours, will show. MBRINK. ALBUMEN. CASEINS. Animal. Vegetable. Animal. Vegetable. Animal Vegetable. r h 52.8 7.0 23.7 16.5 53.2 7.0 23.4 16.4 53.5 7.1 23.6 15.8 53.7 7.1 23.5 15.7 53.5 7.0 23.7 15.8 53.5 7.1 23.4 16.0 Hydrogen 100.0 100.0 100.0 100.0 100.0 100.0 These principles, to which must be added gelatine, the fats and several earthy and alkaline salts, constitute the frame-work of the animal tissues, or the fluids which penetrate them ; it is therefore necessary for us to examine each of them shortly. Gelatine is met with in almost all the solid parts, in the bones, tendons, cartilages, skin, cellular tissue, muscular flesh — all contain it. It is readily soluble in boiling water ; cold water only takes up a small quantity of it. Two or three parts of gelatine dissolved in 100 parts of hot water, suffice to turn the fluid into a tremulous jelly when it has become cold. Tannin, or infusion of gall-nuts, precipi- tates gelatine completely from its solution, the precipitate being very bulky and perfectly insoluble in water ; and it is this chemical com- bina bn or principle which lies at the bottom of the art of tanning. Gelatine is extensively used in the arts, under the familiar name of glue. Isinglass consists of gelatine nearly pure, and, according to Mulder, contains : Carbon. 50.8 Hydrogen 6.6 Azote 18.3 Oxygen 24J 100.0 Fihrine occurs in a state of solution in the blood, and forms the principal ingredient in muscular flesh. It is readily obtained by whipping a quantity of blood just taken from the veins of a living animal ; the white stringy masses that adhere to the rod are fibrine, which, by gentle kneading under water, become colorless. Fibrine, 380 ALBUMEN, CASEUM. when moist, is a highly elastic and flexible substance ; dried, it loses about 30 per cent, of water, and becomes brittle, horny, semi-trans- parent. Thrown into water, it gradually imbibes all it had lost by drying, and regains its former properties. Burned and incinerated, fibrine leaves a quantity of ash, which consists, for the major part, of phosphate of lime, with which is mixed a small quantity of phos- phate of magnesia and of oxide of iron. Albumen exists in large quantity dissolved in the water or serum of the blood, and in the white of the egg ; it is also found in almost all the animal fluids that are not excretions, or destined to be thrown oflf as useless to the system. Albumen, as familiarly known, has the remarkable property of coagulating or setting into a soft fluid, at a certain temperature — 158° F. Caseum, or caseine, is the distinguishing principle of milk. By combining vvith acids it forms an insoluble compound ; and it under- goes a remarkable coagulation, as all the world knows, in contact with a piece of the inner membrane of the stomach of a young ani- mal : from a fluid it sets into a soft solid, which by degrees separates into two portions — whey and curd. The curd, or caseum, always contains fat, and, when burned, leaves a considerable quantity of ash. Physiologists distinguish three principal tissues in the bodies of animals ; the muscular, the nervous, and the cellular. The muscular tissue consists of an assemblage of contractile fibres, here disseminated through the masses of organs, there collected into bundles and constituting the flesh. This is the instrument by which animals perform all their voluntary motions, and it is that also by which all the active but involuntary movements of the body are ex- cited. Muscular flesh is always a compound substance, however ; it consists of fibrine, the contractile or proper element, albumen, fat, gelatine, an odorous extractive matter, lactic acid, different salts and the coloring principle of the blood. Put into cold water, so long as the temperature is below from 130° to 140° F., little effect is produced beyond the solution of the soluble salts which it may contain, and of a portion of its extractive matter and albumen. At from 175° to 195°, the albumen which had been dissolved, coagulates and rises to the top as scum, and the fat melts and floats on the surface. The fibrinous element of the meat, how- ever, preserves its characters even after the action of boiling water continued for some time. The nervous tissue constitutes the brain, spinal marrow, and nerves, distributed to all parts of the body. Brain in its composition contains a large quantity of water, — 80 per cent. — certain fatty mat- ters, albumen, osmazone, phosphorus in combination with fat, sul- phur, and phosphates of potash, lime, and magnesia. The composition of the brain of animals, the dog, the sheep, the ox, appears to be very analogous to that of the human subject. Cellular tissue is the general connecting medium throughout the animal body, and is not only met with, it may be said, everywhere, but forms a main element in many of the textures of the body, sucb BONES, BLOOD. 381 as the serous and mucors membranes, the cartilages, the bones themselves, which are in fact only cellular tissue impregnated with calcareous salts. Tendons may be viewed as condensed ropes of cellular tissue ; by long boiling in water they melt entirely into gela- tine. Bones consist of cellular tissue, as stated, resolvable into gelatine, and of a large proportion of saline earthy matter, consisting princi- pally of phosphate of lime. The presence of this phosphate is not extraordinary, inasmuch as we have found that it forms an element in all the vegetables upon which animals are supported. By boiling bones even reduced to powder under the usual pressure of the atmo- sphere, but a small quantity of their gelatine is obtained ; but by put- ting them into a Papin's digester, and subjecting them to a consider- ably higher temperature than that of boiling water, we can dissolve the whole, or nearly the whole of the animal matter, and leave the earthy parts unchanged ; or by proceeding in another way, by soaking bones for a time in dilute muriatic acid, we can dissolve out the earthy matter, and leave the bone, having its original form indeed, but as an elastic, pliant gristle. The relations between the earthy and organic matter of bone, vary with the species, but especially with the age of the animal. In early life the cellular element predominates ; in adult age the salts predominate. We have three analyses of bone, which I shall here present : Man. Ox. Ox. Cartilage susceptible of change into gelatine 33.3 33.3 50.0 Sub-phospliiite of lime 53.0 57.4 37.0 Carbonate of lime 11.8 3.9 10.0 Phosphate of magnesia 1.2 2.0 1.2 Soda, and a trace of common salt 1.2 3.4 " 100.0 100.0 98.3 Hair has a very complex composition, no fewer than nine different principles or substances having been detected in its constitution ; among the number, mucus, various oily matters, sulphur, and iron ; wool, fur, and horn, are all similar in their composition to hair. Bloody in all the higher animals, is a sluggish fluid, of a deep red color ; in many of the inferior tribes, however, such as insects, crus- taceans, and shell-fish, it is limpid, and generally colorless. Under the microscope, red blood is seen to consist of two distinct portions, a serum or whey, in which float a multitude of minute, solid, opaque corpuscles — the globules of the blood of physiologists, particles which have different characters in different classes of animals. Blood is a very heterogeneous compound. Left to itself, after being drawn from a vein, it sets or coagulates into a soft gelatinous solid, which by and by begins to separate into two portions, one watery, of a yellowish color, and opalescent, the water, whey, or serum ; another solid, of a deep red or reddish brown color, the clot or coagulum. The watery portion contains a large quantity of albu- men in solution. M. Lecanu, in his analysis of the blood, speaks of as many as twenty-five different substances as entering into its cona- positioQ : 882 BLOOD, MILX. Water. 7904 Oxygen, azote, free carbonic acid Iron Hydrochlorates of soda, potash, ammonU Sulphates of potash and of poda Subcarbonate of lime and magnesia Phosphates of soda, lime, and magnesia Lactate of soda A soap, having soda and fixed fat acids fcr its elements An odorous, volatile salt, a fat acid A fatty substance, containing phosphorus Cholesterine Scroll ne Albumen dissolved in the water - IIJO 67.8 Globules and fibrine 130.8 iooo.e The blood globules consist principally of albumen combined with a little fibrine and red coloring matter. Any difference observed between one sample of blood and another, is connected especially, almost exclusively, with the relative proportions of the liquid part or serum, and the solid part or clot. The solids are in larger propor- tion in males than females, in grown-up persons than in aged indi- viduals and children, in subjects well and abundantly fed than in those indifferently supplied with food. No analysis that has yet been made has thrown any true light on the cause of the difference of color perceived between arterial and venous blood ; nevertheless, it is positively known that it is by the concurrence of the oxygen of the atmosphere that the arterial blood in the living body acquires the characters which distinguish it, and that carbonic acid gas is evolved or thrown off in the course of the action that takes place. Ox blood, thoroughly dried, has been found to consist of: Carbon 52.0 Hydrogen 7.2 Azote 15.1 Oxygen 21.3 Ash 4.4 100.0 Milk. This well-known fluid may be said to combine in itself all the organic principles and mineral substances which enter into the constitution of organized beings. Caseum, identical with fibrine and albumen, fatty matters, sugar of milk, and different salts, among the number of which the phosphates stard distinguished. The ciseum, the sugar, and a port:on of the salts, are in solution ; the fatty matters are held in susper sion in the milk in the form of globules. The following table will b^ found useful, as giving a com-> prehensi 'c survey of the compositior of different kinds of milk. MILK. 383 il. .• s , a . •5S2 ■5 fu'^ -s Milk. 1 1 !i Remarks. Authors of the analyses O 2 Ui CO «o Q Of the cow. . 3.6 4.0 5.0 87.4 12.6 Average of 12 Le Bel and Bous- analyses at Be- singault. chclbronn. Of the cow. . 3.8 3.5 6.1 86.6 13.4 Average of 6 an-:Q,uevenne. alyses in the en- virons of Paris. Of the cow. . 4.5 3.1 5.4 87.0 13.0 Idem. Henri and Chev- alier. Of the cow. . 5.6 3.6 4.0 86.8 13.2 Idem. Lecanu. Of the cow. . 5.1 3.0 4.6 87.3 12.7 An analysis, Giessen. Haidlen. Of the ass... 1.7 1.4 6.4 90.5 9.5 Average of 5 an-.P61igot. alyses. | Of woman... 3.1 3.4 4.3 89.2 10.8 Of good quality. jHaidlen. Of woman... 2.7 1.3 3.2 92.8 7.2 Of middUng qual-jHaidlen. ity. 1 Cow's milk always shows slight alkaline reaction ; its density is about 1.03. According to M. Haidlen, it contains no salt formed by an organic acid, no lactates, and the alkali is in combination with caseum, the solution of which it assists. It may contain about a half per cent, of ash, the several constituents of which appear to be very stable, though their proportions vary greatly. In 100 parts of milk, taken from two different cows, Haidlen found the following salts : Phosphate of lime 0.231 0.344 Phosphate of magnesia 0.042 0.064 Phosphate of iron 0.007 0.007 Chloride of potassium 0.144 0.183 Chloride of sodium 0.024 0.034 Soda.... 0.042 0.045 0.490 0.677 As cow's milk is that which is by far the most directly interesting to agriculture, I shall enter somewhat particularly into its history ; having, however, already spoken of caseum, its distinguishing con- stituent, and albumen, I shall here confine myself to the subject of the sugar and the oil or butter. Sugar of milk is prepared for commercial purposes, in countriea or districts where cheese-making is carried on to a great extent, and the quantity of whey at command is very large. In some Can- tons of Switzerland, sugar of milk is obtained by simply evaporating whey properly clarified, to the consistence of sirup, which deposites the sugar in the crystalline form as it cools. This first produce is brown, and contaminated with various impurities, from which it is freed by repeated solutions and crystallizations. It then becomes colorless, transparent, and nearly tasteless, feeling gritty between the teeth, and having only an obscure sweet taste. Ii requires from 8 to 9 parts of cold water to dissolve it ; in hot water it is more soluble. According to Proust, it consists of : 884 MILK. Carbon 40.0 Hydrogen 6.7 Oxygen 53.3 100.0 Buttct To understand the preparation of butter thoroughly, it is absolutely necessary to know the physical constitution of the milk from which it is obtained. Now the microscope shows us that milk holds in suspension an infinity of globules of different dimen- sions, which, by reason of their less specific gravity, tend to rise to the surface of the liquid in which they float, where they collect, and by and by form a film or layer of a diflferent character from the fluid beneath ; the superficial layer is the creairu, and this removed, the subjacent liquid constitutes the skim-milk. This separation ap- pears to take place most completely in a cool temperature from 54" to 60" F. Allowed to stand for a time, which varies with the temperature, milk becomes sour, and by and by separates into three strata or parts : cream, whey, and curd, or coagulated caseum. By suffering the milk to become acid before removing the cream, it has been thought that a larger quantity of this, the most valuable constituent of the milk, was obtained ; and the fact is probably so ; but in dis- tricts where the subject of the dairy has been most carefully stud- ied, it has been found that it is better to cream before the appearance of any signs of acidity have appeared. WTien a knife can be push- ed through the cream, and withdrawn without any milk appearing, the cream ought to be removed.* Butter is obtained from cream by churning, as all the world knows ; by the agitation, the fatty particles cohere and separate from the watery portion, at first in smaller and then in larger masses. The remaining fluid is buttermilk, a fluid slightly acid, and of a very agreeable flavor, containing the larger portion of the caseous element of the cream coagulated, and also a certain portion of the fatty principle which has not been separated. The globules of milk appear, from the latest microscopical ob- servations,f to be formed essentially of fatty matter, surrounded with a delicate, elastic, transparent pellicle. In the course of the agita- tion or trituration of churning, these delicate pellicles give way, and then the globules of oil or fatty matter are left free to cohere, which they were prevented from doing previously, by the interposition of the delicate film or covering of the several globules. Were the butter simply suspended in the state of emulsion in the milk, we should certainly expect that it would separate on the application of heat ; but this it does not : cream or milk may be brought to the boiling point, and even boiled for some time, without a particle of oil appearing. Could M. Romanet show any of these pellicles, apart from the oil-globules they enclose, it would be very satisfacto- ry, and would certainly enable' us to explain the effect of churning Churning is a longer or shorter process, according to a variety of * Thaer, Princlpes, tc, t. iv. p. 34L , t M. Bomanet, MSS. I MILK. 885 circumstances ; it succeeds best between 55 and 60* F. So that, in summer, a cool place, and in winter a warm place, is chosen for the operation. There is no absorption of oxygen during the process of churning, as was once supposed ; the operation succeeds perform- ed in vacuo, and with the churn filled with carbonic acid or hydro- gen gas. On being taken out of the churn, the butter is kneaded and press- ed, and even washed under fair water, to free it as much as possible from the buttermilk and curd which it always contains, and to the presence of which must be ascribed the speedy alteration which butter undergoes in warm weather. To preserve fresh butter it is absolutely necessary to melt it, in order to get rid of all moisture, and at the same time to separate the caseous portion. This is the process employed to keep fresh butter in all the warmer countries of the world. In some districts of the continent, it is also had re- course to with the same view. The butter is thrown into a clean cast-iron pot, and fire is applied. By and by the melted mass enters into violent ebullition, which is owing to the disengagement of wa- tery vapor ; it is stirred continually to favor the escape of the steam, and the fire is moderated. When all ebullition has ceased, the fire is withdrawn, and the melted butter is run upon a strainer, by which all the curd is retained. M. Clouet has proposed to clarify butter by melting it at a temperature between 120° and 140° F., and keep- ing it so long melted as to dissipate the water and secure the depo- sition of the cheesy matter, after which the clear melted butter would be decanted. I doubt whether by this means the water could be sufficiently got rid of, a very important condition in connection with the keeping of butter, though certainly all he caseum would be deposited. The moisture and curd contained in fresh butter may amount to- gether to about 18 per cent. ; at least we find that we lose about 18 lbs. upon every. 100 lbs. weight of butter which we melt at Bechel- bronn. The information which we have on the produce in butter and cheese, from different samples of milk, is very discordant, so that I prefer giving the results of a single experiment made under my own eyes. From 100 lbs. weight of milk, we obtained : Cream 15.60 lbs White curd cheese 8.93 " Whey 75.47 " 100.00 The 15.60 lbs. of cream yielded by churning : 3.3 lbs. butter, or 21.2 per cent., and 12.27 " buttermilk. The reckoning with reference to 100 lbs. of milk consequently stands thus : Cheese 8.93 Butter 3.33 Buttermilk 12.27 Whey 75.47 100.0 33 388 FOOD AND FEEDING. Taking the whole of the milk ootained and treated at differenl seasons of the year, I find that 36,000 lbs. of milk yielded 1080 lbs. of fresh butter, which is at the rate of 3 per cent. From the state- ment of M. Baude, it appears that near Geneva a proportion of butter so high as 3 per cent, is never obtained, probably because there a larger projJortion of fatty matter is left in the cheese. In the dairy of Cartigny, 2200 gallons of milk gave : B'^tter 363 lbs. or about 1.6 per cent, Gruye re cheese 1515 " 6.9 " Clot from the whey, obtained by boiling 1140 " 5.2 " In the same neighborhood, another dairy, that of Lullin, gave from the same quantity of milk : Butter 4181bs.or 1.9 per cent. Cheese 1485 67.5 " Clot from whey 968 4.4 " * OF THE FOOD OF ANIMALS AND FEEDING. The identity, in point of composition and properties, which ap- pears to obtain between certain substances derived from either king- dom of nature, naturally led to the conclusion that animals do not form or originate the substances which enter into their organization, but that they find these ready formed in their food, and merely ap- propriate them ; whence we must conclude, that herbivorous animals assimilate several of the proximate principles of plants immediately, causing them to undergo but slight modifications, and that the ele- ments of the animal tissues and fluids pre-exist in vegetables, which further contain the earthy phosphate that forms the distinguishing characteristic in bone.t The food of herbivorous animals must, therefore, always contain, and in fact always contains, four essential principles, which, by their combination or reunion, constitute nutritious matter, properly so called : — 1st. An azotized matter, such as albumen, caseine, gluten, substances which are probably the original of flesh. ' 2d. An oily or fatty matter, which approaches more or less closely to fatty bodies in general. 3d. A substance having a ternary composition, sugar, gum, fecula. 4th. Certain salts, particularly phosphates of lime, magnesia, and iron. This mixed constitution, which a forage plant must needs offer, justifies the general ideas propounded by Dr. Prout on nutrition. This able chemist has said that milk was to be viewed as the standard food, and that all alimentary matters must resemble it in composition, in greater or less degree : that is to say, besides phosphates, food must contain an azotized principle, a non-azotized principle, and a fatty body, to stand in lieu of caseum, sugar, and butter. The fundamental principle that animals find the several substances which make up their bodies, ready formed in the substances they * In all the dairy counties of England, the milk is never required, like the ground, ta five a double crop ; 'I yields either butter or cheese, not both. Hence the greater rich- ness of English cheese In general. — Eno. Ed. t Dumas and Boussingault. The Chemical and Physiological Balance of Organl* Natnxe, post 8vo. London. BalUiere, 1843. (A very useful little work.— Eno. Ed. J FOOD AND FEEDING. 387 consume, seems very well calculated to assist the practical farmer in managinor the food of the animals upon his land ; for if flesh, fat, and bone exist all but ready formed in the food, it is obvious that the best kind will be that precisely which, under the same weight, contains the largest quantity of the various matters of the organi- zation. It is by no means easy to ascertain precisely the amount of the azotized constituents, gluten, and albumen, contained in plants ; to do so requires both time and pains. But let it be once admitted that the nutritive properties of forage increase in the precise ratio of these matters, this is clearly as much as to say that the value is in proportion to the quantity of azote contained in the food, and that it becomes a matter of the highest moment to have at hand a ready mode of determining the point. I believe it infinitely better to get at the quantity of azote immediately, which is easily done, than by any roundabout and laborious process to ascertain the amount of albumen and gluten : the quantity of azote ascertained, it is most easy to deduce the quantity of albumen and gluten — in other words, o^ flesh — contained in each particular species of food examined ; for, as a general rule, vegetable food does not contain any other azotized principle. It is true, indeed, that all the azotized principles of vege- table origin cannot be considered as nutritious ; some of them, on the contrary, are virulent poisons or active medicines, according to the dose in which they are administered. But these poisonous sub- stances are not met with in appreciable quantity in the plants which are commonly grown for the food either of man or beast. Still, all the truly nutritious articles of food contain an azotized principle. The experiments of M. Magendie have shown, that substances which contain no azote, such as sugar, starch, oil, will not support life ; and, on the other hand, it is ascertained that the quality of alimentary matter, flour for example, increases with the amount of gluten which it contains. It is because the seeds of the leguminous vegetables are richer in azotized principles — that is, in flesh — that they are also more highly nutritious than the seeds of the cereals. These several considerations, therefore, induce me to conclude; that the nutritious principles of plants and their products reside in their azotized principles^ and consequently that their nutritious pow- ers are in proportion to the quantity of azote they contain. From what precedes, however, it is obvious that I am far from regarding azotized principles alone as sufficient for the nutrition of animals ; but it is a fact, that every highly azotized vegetable nutritive sub- stance is generally accompanied by the other organic and inorganic substances which concur in nutrition. In seeking to learn the precise quantity of azote contained in a great number of articles used as food for cattle, I have had it in view particularly to find a standard or fixed point for estimating their comparative nutritive properties. It is long since more than one of the most distinguished farmers, both of England and Germany, essayed to resolve this important problem in rural economy. Thua Thaer and many others have given tables of the quantities by weight 888 FOOD AND FEEDING. in which one article of alimentation might be substituted for another These tables are in 'ict tables of equivalents with reference to food But it is unfortunate that there should be considerable diversity of statement among thnr authors. Yet, even up to the present time, it could not well have been otherwise, and these discrepancies will only surprise those who are unacquainted with the difficulties of the subject. One grand cause of difference probably exists in the de- gree of dryness of the article subjected to experiment. The nature of the soil, a very dry or very rainy season, the climate, &c., must all be regarded as so many causes influencing the quantity of water contained in plants, and in consequence their actual nutritive quali- ties. The only sure mode of proceeding, in short, appears .o be, to reduce the several articles to a state of complete dryness, and to make their quantity in this condition the first element in the reckoning. I may state, that the theoretical data obtained by proceeding in this way have already been approved by practical applications. Hay may be assumed as the most common or universally used of all kinds of fodder : it is in some sort the staple food of the animals that are particularly attached to an agricultural concern, and may therefore be appropriately made the standard of comparison for all other kinds of food or forage. Hay itself, however, varies greatly in point of quality : in assuming it as the standard, I have therefore to state, that meadow hay of good quality is to be understood. The analyses which I have made of this article at different times, satisfy me that in the state in which it is commonly used, it contains from 1.0 to 1.5 of azote per cent. In choosing a specimen for analysis, it is, of course, highly necessary that it be an average specimen ; that it consist of equal or rather relative proportions of the several elements which enter into its constitution, such as stalks, leaves, flowers, and seeds. Taking a sample of hay, for instance, weighing exactly 5 lbs. avoird., I found that it was made up of — Hard woody stems 2.393 lbs. Bottoms of leaves and very fine stems 0.847 Flowers, leaves, and a few seeds 1.760 5.000 The ultimate analysis of which gave : Of azote per cent. >...1.19 Military contract hay of 1840 gave of azote per cent 1.21 Hay made in Alsace in 18:J5 " " 1.04 Hay made in Alsace in 1837 " " 1.15 Average of azote per 100 1.15 Hay, as it is generally used, contains from 11 to 12 per cent, of water, which is got rid of by thorough drying. And as albumen, caseum, and vegetable gluten contain 16 per cet)t. of azote, we perceive that the azotized matter which is the representative of flesh, in hay may be represented by the number 7.2 per cent. Hay does not, indeed, always contain so much azote ; that which is won from marshy lands contains much less ; and again there are samples .hat contain more. After-math, or second-crop hay, is certainly more nutritious than first-crop hay, a fact which we have ascertained POOD AND FEEDTNG. 389 rej€atedly at Bechelbronn ; but this hay is nevertheless held less suitable for horses, probably because, being made late in the season, it is commonly stacked more or less damp, and suffers change in conscjuence : After-math hay gave 2.0 per cent, of azote A choice siiinpie 'f the best hay 1.29 " The flower or ear, containing little woody stem- .. • 2.1 " These examples suffice to show, that when an animal is to be put upon another kind of food than hay, it is very necessary to take the quality of the latter article, which has been employed, into the ac- count. In the table which I shall immediately present, I have as- sumed good meadow-hay, containing 1.15 of azote and 11 of water per cent, for my standard. The importance of a table of equivalents for forage has long been felt by farmers ; and they who have given their attention to the accumulation of data for its construction, de- serve our best thanks. The use of a table of equivalents is extreme- ly simple : the numbers placed underneath the value of hay in- dicate the weights of the several kinds of forage named in the first column, which may respectively be substituted for 100 parts of hay by weight. Thus, according to Block, 366 lbs. of carrots may be substituted for 100 lbs. of meadow-hay. Pabst holds 60 lbs. of oats to be equivalent to 100 lbs. of hay. If the question be to replace 7.26 or 7| lbs. of oats in the ration of a horse by Jerusalem arti- chokes, we find in the table that 60 of oats are equivalent to 274 Jerusalem potatoes, and we therefore infer that 35.2, say 35| lbs. is the weight of the root to be substituted for that of the oats. Certain information on the nutritive value of the various articles consumed by cattle as food, is really of high importance in rural economy : it is obviously the only guide for the feeder in the use or purchase of forage. Let us suppose, for example, that a measure of potatoes (22 gallons) weighing 165 lbs. is worth lOd. at market, and that hay is worth 2*. 6c^. the cwt. ; 2 cwts. or rather 220 lbs. would cost 5s. Let us now admit, on theoretical grounds, that this quantity of hay is equivalent to 693 lbs. of potatoes; it plainly ap- pears, on looking at the cost of these equivalents, that there would be a positive advantage in using potatoes, inasmuch as they are worth no more than 3^. 6^d. There would indeed be money to be made by selling hay, and purchasing its equivalent in potatoes. The equivalents which I have deduced from my elementary ana- lyses, agree on many occasions with the conclusions of practical men ; in others, they differ notably from them ; at the same time it must be observed, that the practical equivalents differ from one another in at least an equal degree. We see, for instance, that Schnee and Thaer think 220 lbs. of hay will be replaced by 1405 lbs. of wheat straw, while Flottow gives 429 lbs. as the equivalent number. According to Mayer, 630 lbs. of turnip are equivalent to 220 lbs. of hay, while Middleton gives 1760 as the equivalent num- ber of turnips, a number which coincides remarkably with that infer- red from theory. Block assigns 66 as the equivalent number of peas. Thaer makes it more than twice as high, viz. 145. Mangel 33* 390 POOD AND FEEDINO. wurzel, according to Thaer, is represented by 1012 ; while Mayei and Pabst call it but 550, ^ud M. de Dombasle states it a little high- er, viz. 574. However highly we estimate the difficulties of com- ing to accurate conclusions on the subject of alimentation or feeding, it is not easy to account for such discrepancies among practical men ; and then, as to the astonishing similarity which their conclu. sions bear to one another upon many heads, it is impossible to over- look the fact, that the resemblance is far more in appearance than in fact ; for it is notorious, that the generality of those who have committed themselves to writing have generally copied each other. Indeed, it is not always very obvious whether the equivalent number which we find assumed, has been determined by the farmer from his own observation or experience, or has been adopted from some other observer. No one who is not a total stranger to the art of making experiments will ever be brought to believe that eleven experiment- ers, operating separately, could have fallen plump upon the number 90 as the equivalent for lucern, or even that any five of them could have lighted upon 600, neither more nor less, as the equivalent num- ber for cabbage ! The method which I have myself pursued, that namely of infer- ring the nutritious quality from the contents in azote, is far from being free from objection ; on the whole, it may be said to place the equivalents somewhat too low, inasmuch as by the process of ele- mentary analysis, the quantity of azote is apt to come out a little too high, some portion of it being derived from the nitrates present in vegetables, which are certainly of no avail in nutrition. This is the source to which I ascribe the anomaly presented by the leaves of mangel-wurzel. And, then, it is not to be forgotten that in dosing the azote we have regard but to the jlesh contained in the article of food, which although unquestionably the principle that is of highest value, and the one which is apt to be most deficient, is still not all. The neutral non-azotized substances, starch, sugar, gum, oil, are in- dispensable as auxiliaries in the alimentation of cattle ; the three first undergo changes in the course of the digestive process which fit them to be absorbed immediately, and the oil is brought to the state of an emulsion, and so is taken up and adds to the fat. The woody fibre alone of vegetables appears to have no direct share iu the nutrition of animals ; it is discovered almost or altogether un- changed in the dejections. It is therefore every thing but matter of indifference whether a par- ticular article of forage contains a larger or a smaller proportion of starch, sugar, &c., associated with a given quantity of azoti/ed or truly animalized matter. The potato and meadow-hay brought to the same state of dryness, contain as nearly as possible the same proportions of azote — from 1.3 to 1.5 per cent.; in other words, about 8^ per cent, of albumen and gluten, i. e., of flesh. But in the pota- to, almost the whole of the 9U per cent, of the remainder consists of starch ; while in hay it is woody fibre, inert matter as we must presume it, that is present in by far the largest proportion. And this explains the higher value of the same weight of dry potato a4 FOOD AND FEEDING. 391 an aiticle of sustenance. To give our theoretical equivalents all the precision that is really desirable, it would be necessary to as- certain the quantity of organic matter which escaped digestion with reference to each particular species of food. This is an inquiry which it is my purpose to enter upon by a:nd by. The labor com- pleted, we should then be in possession of tables in regard to the proportion of the non-azotized as well as the azotized principles ; and further, to the quantity of inert matter which it would be proper to deduct from the weight of the ration allowed in each case. To have determined the azote in an article of food, then, is not to have done all that is strictly necessary : still azote is the scatea element in all kinds of vegetable food; starch, gum, sugar, pectine, oil, are universally present, and generally in adequate quantity. A.s articles, as unlike one another as possible, I have mentioned pota- toes and meadow hay. Now the theory indicates 300 of the root for 100 of the dried grass ; and I can state positively, from long and re- peated observation, that it is not advisable in practice to substitute less than 280 of potatoes for 100 of meadow-hay. The state of dryness of certain kinds of forage may have a mark- ed influence on their nutritious qualities. They may even decline in nutritive value by the process of drying, so that analysis of itself may lead us into error in regard to the nutritive value of dry articles of food. Breeders have in fact long suspected that green fodder is more nutritious than dry fodder; that grass, clover, &c., lose nutri- tious matter by being made into hay. That the thing is so in fact, appears to have been demonstrated by a skilful agriculturist, well acquainted with the ait of experimenting,* who found that 9 lbs. of green lucern were quite equal in foddering sheep to 3^^^ lbs of the same forage made into hay, while he at the same time ascertained that 9 lbs. of green lucern would not on an average yield more than 2.02 lbs. of hay. In allowing each sheep 3i^jj^ lbs. of lucern hay as its ration, consequently, it was as if the animal had had 14.34 or more than 14| lbs. of the green vegetable for its allowance. These practical facts are obviously of great importance ; they prove beyond a shadow of doubt that the belief of agriculturists in general as to the immense advantages of consuming clover and lu- cern as green meat is well founded. Nor is this all ; it is not mere- ly the absolutely greater feeding value of the crop green than of the crop dried and made into hay ; there is further, the saving of ex- pense in making the hay, and still further, the escape of all risk from loss through bad weather during the process, by which that wiiich was valuable fodder but a few days before, may become fit only for the dung-hill. Still, because 100 of green clover or lucern repre- sent 2-3 of the same articles dried, it does not follow that the feeding properties of the fodder in each of the two states can be truly re- presented by the ratios of these numbers to one another. Messrs. Perrault find from their experiments that the true relation is 8 to 3. By assuming 71.5 lbs. as the quantity of dry forage obtained from • M. PterraBlt de Jotemps, in Jcmrn. d'Agricult. v. iii. p. 97. 892 FOOD AND FEEDING. 220 lbs. of gretu clover or lucern, the quantity which is actually obtained on an average, the ratio comes out 8 to 2.G, a number which falls somewhat short of that which is assumed, but not much. With regard to the difference in the feeding or nutritive value of green and dried fodder, the loss may in a general way be ascribed to loss of the more substantia] parts of the plants especially experienced in the process of drying. This is the conclusion, at all events, to which M. Crud came ; I have myself, however, found that clover-hay, made in the field and ricked in the usual way, had not the same nutritive value as a quantity of the same crop carefully dried :n the laboratory. By way of pendant to the conclusions of Messrs. Perrault, from their valuable observations, I shall here add the average of some experiments that were made at Bechelbronn, in 1841, on the eon- version of clover into clover-hay. The clover crops of this season were magnificent ; the plant in its second year growing to more than a yard in height. Green clover on the average may be considered as consisting of: Clover-hay 29.85 Water 70.15 100.00 As extremes in our experiments of 1841, we add : Clover-hay 35.7 25.0 Water 64.3 76.0 100.0 100.0 Analysis gave the number 75 as the nutritive equivalent number of clover-hay. Assuming 76 to represent the moisture lost during the drying, the equivalent becomes 311 for the same fodder in the green state, meadow-hay, the standard, being 100. But practice is not here in harmony with theory ; the value of clover-hay, in point of nutritive power, is found not to differ essen- tially from that of meadow-hay ; and the equivalent of green clover is generally placed between 425 and 500. And I may say, that daily experience in the stable tends to show that the theoretical equivalent of clover-hay is too high, that its nutritious properties are not so great as they are inferred to be. From a mean of four weighings, I find that four cows upon green clover consume 2499 lbs., or 624f lbs. each per diem. The usual allowance to one of our cows, however, is 33 lbs. of hay of good quality ; from which it would follow, that the equivalent of green clover would be 445. But the animals on the green fodder fattened apace, and every thing showed that they were very differently nourished than they would have been with their 33 lbs. of meadow-hay. According to theo- retical data, each cow in its 624| lbs. of green food per day received an equivalent of 47.3 lbs. of hay ; and if it be considered, that during the season of green forage they have it almost at will, it must be conceded that during this period the quantity of food consumed ii actually greater than when it is regularly doled out. .A^dditional ex- FOOD AND FEEDING. 393 pcriments are therefore necessary to decide the question as to whether forage eaten green is really more nutritious than the same forage consumed when converted into hay. For my own part, I should not be surprised, from what I have seen, were it found that dry fodder, previously moistened and carefully portioned out, wa? actually more nourishing than the same food would have been had it been eaten green. Green forage, of a very soft or watery nature, is notoriously possessed of purgative properties, which must lessen its value as food ; but my observation leads me to say, on he othei hand, that animals kept upon dry fodder require more care with re- gard to watering than is generally bestowed upon them. The abso- lute necessity of a sufficient degree of moistness in the food, in order to secure its due and easy digestion, greatly countenances the prac- tice which is beginning to be introduced in some places of steeping hay for some time in water before giving it to cattle. This neces- sity further explains the great advantages in associating with dried fodder other very watery articles, such as roots and tubers, turnips and field-beet, potatoes and Jerusalem artichokes. The oleaginous seeds contain a considerable proportion of animal- ized matter, similar in composition and qualities to the caseum of milk ; and the cake which comes from the oil-mill retains almost the whole of this substance. The proportion of from 0.05 to 0.06 of azote, indicates nearly 42 per cent, of the representative of flesh m oil-cake. Theory, in fact, rates the nutritious power of this sub- stance so high, that 100 of hay may be replaced by from 22 to 27 of cake. The almost universal use of oil-cake in the feeding and fattening of cattle, is of itself sufficient evidence of its highly nutritive quali- ties. It has even been found possible to keep sheep and oxen upon this food almost exclusively. M. Bouscaren finding considerable difficulty in getting rid of his oil-cake, thought of associating with his oil-mill an establishment for feeding cattle ; and he found that oxen put up to fatten throve perfectly upon a mixture of the refuse of the wine-press and oil-cake. Cows, upon a diet of this kind, give on an average 12^ pints of milk per diem. The allowance per head is about 15 lbs. of oil-cake in three meals, given each time imme- diately after the animals have been watered, and in the interval, each is allowed about 12 lbs. of straw or chaff. The cake broken in pieces is steeped in water, and worked up into a paste of the consistency of dough. If the animals show any disinclination to this food at first, they are brought to like it by having a ball of it, the size of the fist, administered to them two or three times. Supposing that the cows fed in this way would be adequately maintained upon 33 lbs. of hay, and that 13 lbs. of straw are equiv- alent to 3 lbs. of hay, it appears that in the allowance given, 15 lbs. of oil-cake will supply the place of 30 lbs. of hay ; the equivalent of the cake, therefore, is 51.5, a number very different from the 22 deduced from analysis. The equivalents of those who have sought to appreciate the alimentary value of oil-cake are, however, suffi- ciently at variance with one another. It will be seen in the table, 894 FOOD AND FEEDING. that the numbers assigned by different authorities are 42, 57, and 108 ; and M. Perranlt, Tom direct experiment, found the equivalent number of colza-cake t* be 36, analysis giving 23 as the theoretical number. On the whole it may be said, that in practice, the results, although sufficiently different, still agree in ascribing to oil-cake a nutritive value inferior to that indicated by theory. I have thought it important to insist upon the discrepancy which is here so conspicuous between the inferences from chemical analy- sis and those arrived at by experience, because it appears to me to depend upon a particular circumstance which frequently intervenes in the feeding of cattle, and which it is very important to be aware of; I allude to the influence of the bulk of the allowance of food. Vegetable food of every description has nearly the same specific gravity ; it is but little above that of water ; the bulk of the allow- ance therefore depends upon its weight. Every one will conceive that a ration of highly nutritious food, which for this reason would occupy but little space, would be open to many objections. A cart- horse, of the ordinary size, from what I have myself repeatedly observed, requires from 26 to 33 lbs. of solid food, and about the same quantity of water in the twenty-four hours. The bulk of this allowance, when masticated and brought to the state in which it is swallowed, will be upwards of 9^ cubic feet. Now, if for the ordi- nary forage, one that is five times more nutritious were substituted, oil-cake, for example, the dry ration, according to the rule of equiv- alents, would be reduced to 6.6, or a Mttle more than 4^ lbs., and its bulk would not surpass 5^ cubic feet. The animal would not feel satisfied with this allowance, it would still feel hungry, or the food given in such a concentrated shape would disagree with it. If, on the contrary, a forage that is very little nutritious were substituted, such as wheat-straw, the equivalent of which is 500, the ration would then become too bulky to be eaten in the course of a day, it would amount to as many as 165 lbs. It is therefore absolutely ne- cessary to take into consideration the bulk of the food allowed : the belly must of necessity be filled ; whatever the nutritive value of any article, it must be given in a certain quantity ; and in the case of such a substance as oil-cake, the consumption to fill the stomach would cease to be in any kind of proportion to the nutritive equiv- alent. It is extremely difficult to appreciate the precise limits beyond which an article of forage or a given ration ceases to be nutritious. When any addition is made to an allowance known and admitted to be sufficient, the effect of the extra quantity is scarcely perceptible ; so that, in practice, we are apt to fall into the error of estimating at too low a rate the nutritious powers of food given in too large quan- tities. I have had proof of this in a series of experiments on the maintenance of a number of milch-kine. To a cow which was receiving the equivalent of 33 lbs. of meadow-hay in dry fodder and Jerusalem potatoes, an addition was made of 6| lbs. of oil-cake, by which the allowance of nourishment was doubled theoretically ; the 4oiraal (Mily ate the half of the cake, howfever : still, the quality of FOOD AND FEEDINa. -• 895 the milk was not improved. Experience heie would oompe. os to set down the 3^ lbs. of cake consumed as nil ; yet it is positively ascertained that tlie article is one of" the most substantial known. The hard and husky grain which is given to cattle frequently escapes digestion, because it has escaped the teeth — a circumstance which leads to the formation of an estimate of its nutritious quali- ties inferior to those it actually possesses. To prevent this loss, oats are now often bruised, as are beans and peas also ; or they are mixed with chopped hay or straw, which the animals are compelled to chew thoroughly before they can swallow it ; or the corn is steamed or steeped in boiling water before it is put into the manger. Some experiments that were instituted by order of the French vete- rinary commission, however, seemed to show, that the loss of corn from passing through the stomach and bowels unchanged was really so trifling, that it might be safely left out of the account. Tubers and roots are invaluable fodder for horned cattle, and in the course of the winter, come instead of hay to a considerable extent. Our experience at Bechelbronn also enables us to say, that horses are readily brought to a regimen of the same description, which, judiciously instituted, becomes the means of great economy in the maintenance of these animals. Roots, turnips, and mangel-wurzel, are frequently thrown down whole before the animals. It is vastly better ; nay, it is so much better that it ought to be made an invariable rule never to give them save cut into slices and mixed with cut straw or chaff. There is always a great advantage in combining any very soft and watery article of food with one that is dry and hard, to say nothing of the chaff absorbing and rendering useful the juices that would escape and be lost. Mangel-wurzel, turnips, carrots, and Jerusalem potatoes, are always given raw. The potato is frequently steamed or boiled first ; yet I can say positively that horned cattle do extremely well upon raw potatoes ; and at Bechelbronn, our cows never have them other- wise than raw : they are never boiled, save for horses and hogs. The best mode of dealing with them is to steam them ; they need never be thoroughly boiled as when they are to serve for the food of man. The steamed or boiled potatoes are crushed between two rollers, or simply broken with a wooden spade or dolly, and mixed with cut hay or straw or chaff before being served out. It may not be unnecessary to observe, that by steaming, potatoes lose no weight ; whence we conclude that the nutritive equivalent for the boiled is the same as that for the raw tuber. Nevertheless, it is possible that the amylaceous principle is rendered more readily assimilable by boiling, and that by this means the tubers actually become more nutritious. Some have proposed to roast potatoes in the oven ; and there can be little question but that, treated in this way, they answ^er admirably for f^*tening hogs or even oxen. Done in the oven, pota- toes may be brought into a state in which they may perfectly supply the place of corn in the foddering of horses and other cattle. There is but the expense of the firing to be taken into the a/Ccouat 396 FOOD AND FEEDING. The only mode of ascertaining the favorable or unfavorable influ- ence of any particular system of diet or regimen upon animals, ia by weighing them. In ref rd to full-grown animals performing regular work, such as cart a;.d plough horses, and to milch-kine, the allowance ought to be such as will maintain them at the same or nearly the same weight. Any thing like stinting is immediately followed by loss of flesh and of weight, of strength and spirit, in the animal. The allowance being continued the same, similar effects will follow any increase of work, any exaction of unusual eifort on the part of the animal. An essential condition, therefore, in all experiments on the due dieting or feeding of animals, is, that they be performed under precisely similar conditions of labor. Young ani- mals receiving a sufficiency of wholesome food, increase from day to day by a quantity which we shall have occasion immex.iately to mention ; and all changes of regimen are followed at once by notable variations in the ratio of the growth ; if the new regimen be less nutritious than that which went before it, the balance immediately proclaims the fact. Cattle put up to fatten are always supplied with a superfluity of fodder ; the excess may be regarded as an addition to the quantity requisite to maintain them in health and strength. The increase in the weight of an animal is often so great within a given time, as to be very appreciable by weighings made even at very close intervals ; the balance also shows us that the rate of increase varies at different periods of the interval during which the fattening is going on. An animal put up to fatten for the butcher, is not the best subject for coming to conclusions upon in regard to the nutritive value of dif- ferent articles of sustenance ; still it is useful, in a practical point of view, to determine the influence of this and of that course of regimen on the production of fat. Any misapplication of nutritive equivalents is speedily proclaimed by the animal's losing weight, instead of maintaining or gaining upon the amount to which it had attained. When the quantity of fodder has been ascertained which an ani- mal ought to have in the twenty-four hours to maintain it in full health and vigor, or that may be necessary to enable it to lay on additional flesh and fat, it is to be weighed, and the article or mix- ture of articles which it is the business of the experimenter to try, is to be given in part or in whole. After the lapse of a certain time the animal is weighed again, and the weight upon this occasion enables us to say whether the new or amended ration is superior, equal, or inferior, to that which had preceded it. Such is the pro- cedure generally followed : but in putting it in practice myself, I saw that it was liable to lead to rather serious mistakes, which I then used every effort to diminish or to nullify in the experiments which I undertook on the keep of horses — experiments which I ^hink interesting enough to deserve being particularly related. In a considerable number of observations with which I had be- >me familiar, I saw that the course had not always been continued 4r a sufficierJ length of time ; so that changes which were the POOD AND FEEDING. 897 effect of more accident must frequently have boen ascribed to the effects of regimen. In a general way, it is acknowledged that an adult animal, upon the ration that is known to be adequate for its maintenance, returns at the same hour every day to the yesterday's weight : this, however, is only strictly true in reference to a series of weighings continued through a number of days, to make any irregularity between one weighing and another disappear. With a view to discovering the amount of variation which an animal experiences in point of weight when it is fed in the same uniform manner, is foddered precisely at the same hours, &c., I weighed a horse and a mare, which were leading the most regular and unvaried life possible, for they were both employed in working an exhausting machine for several days in succession, the weighings being performed at noon each day before they were watered, and from four to five hours after their breakfast. Here are the results in a tabular form : Date of the weighings. Weight of the horse. Weight of the mare. kil. lbs. avoird. 453.0 996.6 4.55.0 456.0 454.0 449.0 988.9 449.5 449.0 454.0 454.0 998.8 459.5 1010.9 448.0 985.6 452.0 994.4 454.0 448.0 452.5 kil. lbs. avoird. 494.0 1086.8 497.0 497.0 497.5 1092.7 487.0 487.5 492.0 496.5 484.5 1065.9 490.5 496.0 491.0 484.0 1064.8 491.0 17 •« '< ,... 18 " " 19 " " 21 «' " 22 «' " 23 " " 24 " " 25 «« «< .... 27 " " 28 " " 29 «« «' 30 " " 31 " " 4.52.0 994.4 459.5 1010.9 448.0 985.6 491.8 1081.9 497.5 1092.7 484.0 1064.8 Greatest difference above the mean Greatest difference below the mean Difference between the extreme weights.. 16.5 8.8 7.7 10.8 17.1 6.3 Another horse (Old Fox) 12 years old, taken fasting, at four o'clock in the morning of the 28th of April, 1842, weighed 1051 lbs. ; at the same hour of the 29th, he weighed 1060 lbs. ; ditto on the 29th, 1038 lbs. It is obvious, therefore, that a horse foddered most regularly and weighed at the same hour, nevertheless presents differences in his weight that may amount to nearly 30 lbs. ; and which, without as- surance of this fact, we should be disposed to ascribe to the effect of our regimen. This is enough to satisfy us that in all experi- ments upon feeding, it is absolutely necessary to carry them on for some considerable time, in order to escape, or at all events to lessen the errors that would be introduced into the conclusions by these ac- cidental differences of weight. They may vary with reference to 34 8d8 MAINTENANCE OF ANIMALS. different animals ; they are necessarily smalkr in amount among those that are young and small, such as calves and sheep, than in adult oxen and horses; hi.-, they do not occur the less on that ac- count, and must, therefore, occasion errors of the same description. What, then, shall we say ot" those small variations in the weight in a ewe or a ram, amounting perhaps to 1^ or 2 lbs., ascertained in the course of an experiment carried over two or three days, though conducted with the most scrupulous attention to accuracy in the world ? That they may very possibly have been purely accidental. The first in every series of experiments on the maintenance of animals, ought in fact to have it in view to ascertain the amount of accidental variation in the weight of the creatures which are their subjects ; as this variation is now on this side now on that, there is an obvious advantage in having a certain number upon trial at a time ; any error that occurs will thus be more apt to be corrected ; and the results may be held more worthy of confidence in propor- tion as the numbers have been large from which they have been de- duced Another cause of error, which I had occasion to discover in the course of my experiments, appears to be connected with the weight of the allowance. Equal in nutritious value, difl^erent allow- ances may still have very diflferent weights ; it is obvious, that a ra- tion of hay and corn will weigh much less than its equivalent in roots, tubers, or green meat. Animals that have been kept for some time upon a dry diet, if put on one that is very bulky and watery, will immediately increase very considerably in weight ; and their increase is both so sudden and so great, that it is impossible to as- cribe it to augmented nutrition, to liesh and fat laid on. The ani- mals are simply distended, their paunch and bowels are filled with a larger quantity of food than they were before ; and the state of dis- tension continues, though it suffers accidental variations, so long as the new course of feeding is persisted in. In opposite circum- stances, as when animals that have been long upon soft and watery food, are suddenly put upon hard diet, they always drop very con- siderably in weight. These sudden changes throw disorder and contradiction into the conclusions, and puzzled me greatly until I discovered their cause. It is obvious that no kind of reliance can be placed upon the conclusions which have been come to from single weighings made at the end of each particular course of alimentation. To get at results which shall be worthy of any credit, the animals that are to be made the subjects of experiment must be fed for sev- eral days upon the particular ration that is to be approved, in order to be brought to the state of body which may be said to belong in particular to each system of dieting, before being weighed ; it is only when this is attained, indeed, that the experiment can be held to be properly begun ; and then it is to be continued for a sufficient length of time to lessen the influence of those accidental variations of weight, of which I have spoken so particularly. It is perhaps oeedless to observe, that any increase in weight and the maintenance of that increase, are not always of themselves sufficient signs for affirmmg that the course then followed is superior or equal to tbe MAINTENANCE OF ANIMALS. 399 one which preceded it. Various other circumstances of divers char- acter must be taken into the reckoning, and in particular the state of the animals. It is very necessary to have an eye to the state of the coat, to the spirit or liveliness of the animal, to the nature of the dejections, the size of the belly, the disposition of draught animals for their w^ork, the quantity of milk given by milch-kine, &c. Nev- ertheless, and as a general proposition, it may be said that a station- ary condition, or a slight increase of weight, is almost always in favor of the course along with which it is gained or maintained, while any loss is almost always an indication of an inadequate al- lowance or of deficient nutritive qualities in the ration, taken in con- nection with the work required or the milk obtained. The experiments which I am about to detail were undertaken to determine the nutritive value of a variety of forages associated with the ordinary articles in keeping the horse. The great dearth of for- age that was felt in Alsace, in consequence of the extraordinary droughts of 1840, led us to feel the full importance of researches in this direction ; for then we were compelled to replace by potatoes a very large proportion of the hay usually consumed in the stable. And, indeed, by assuming the theoretical equivalent as the basis of this substitution, I found that I saved money by the course, at the same time that the health and strength of my draught cattle were maintained unimpaired. Still, as every quesvion that bears upon the keep of the animals attached to a farm is too important to be left to the decision of theory alone, I thought it imperative on me to con- trol the inferences of chemical analysis by the results of experience. The best food for horses has long been admitted to be hay and oats in combination ; neither article alone would have the same happy effect that the two together produce. A ration of hay alone would be too bulky ; one of oats alone would not be bulky enough. But the horse is not particular in his food. Barley in southern countries replaces oats, and answers equally well. I have my- self kept horses and mules for long periods of time on maize and the tops of sugar canes exclusively ; and on the elevated table- lands of the Andes, and in the steppes of South America, the horses, though they do much hard work, are kept wholly on green meat. Much of course depends on the way in which the animal has been brought up. In the circumstances in which we are generally placed in this country, I do not imagine that there would be any actual advantage in replacing the ordinary food of our horses by roots and tubers ; I doubt even whether the substitution would have good effects. I know, indeed, that horses have been kept through the winter upon potatoes and mangel-wurzel ; but it is a different matter to feed an animal and keep him standing quiet in the stable without work, and to feed him at the same time that a certain quantity of labor is re- quired of him every day. A horse in full work would scarcely get through the bulky ration, which should consist of beet»root alone ; his meal-times are restricted ; if he has certain hours for his work, has he certain hours for his breakfast, dinner, and supper also. 400 MAINTENANCE OF ANIMALS. This is one reason why carriers' horses and pi'St-horses, horses, in a word, which have long and severe work to perform, receive the larger portion of their allowance in corn. The inconveniences of bulky rations are much less felt in the cov/-house than in the stable ; not to speak of their particular organization, which actually enables them to take in a much larger quantity of food than the horse, the steer and the cow have always a longer time allowed them for their meals than are regularly given to the horse. The experience of nearly a whole year having satisfied me that a cart-horse may have half his ration in roots or tubers, I set out from this fact in the experiments which I instituted. EXPERIMENTS ON THE MAINTENANCE OF HORSES WITH MIXED FOOD. The usual allowance to a horse at Bechelbronn for the twenty- four hours consists of : Hay . . 22 lbs. Straw . . . 5J Oats . . . . 7i With this ration the teams are kept in excellent condition. Two teams were selected as subjects of experiment, each consisting of four horses ; these I shall distinguish by the titles. Team No. 1 and Team No. 2. Each remained under the care of the same ser- vant throughout. Team No. 1 was composed of: Braun, a mare, 7 years old. Schimmel, a horse, 7 " Hans, do., 16 « Gaty, do., 8 " Team No. 2 was composed of : Old Fox, a mare, 16 years old, Braun, do., 5 " Nickel, do., 14 " Hengst, a horse, 5 " EXPERIMENT I. One half the allowance of hay was replaced by potatoes lightly steamed ; 280 of the tubers being assumed, according to theory, as equivalent to 100 of hay. The ration, therefore, consisted of: Hay . . . .11 lbs. Straw . . . 5i Oats . . . . 7j Potatoes . . . 30 8-10 The potatoes were broken down and mixed with chopped straw, and never put into the mangers until cold. From accidental circumstances, particularly bad weather during the course of the autumnal labors, the teams were exposed to very hard work, an event which of course throws uncertainty over the results of this trial. After having been upon the course of food in- MAINi-ENANCE OF ANIMALS. 401 dicated for a few days, the teams were weighed once, and again after an interval of twenty-four hours : Team No. 1. No. 2. Both teams. Mean per horse. First weighing 4617.8 4461 9079.4 1134.9 Second weighing 4554.0 4334 8888.0 1111.0 In 24 hours loss 63.8 127 191.4 23.9 The loss experienced here authorized me to conclude, that the al- lowance under the circumstances was not sufficient. The 30.8 lbs. of steamed potatoes could not have adequately replaced the 11 lbs. of hay ; it would have been highly interesting to have ascertained how horses kept on the standard and usual allowance would have stood the same amount of fatigue. Unfortunately this comparison could not be made, all the horses in the stable having been put on the potato regimen at the same time. There is this much to be said for the particular course tried, however, that the animals did their work with great spirit, and continued in excellent health. EXPERIMENT II. INTRODUCTION OF JERUSALEM f OTATOES INTO THE RATION. Jerusalem potatoes are held excellent food for the horse ; they are eaten greedily, and he thrives on them. In this second experiment, 30/oths lbs. of Jerusalems cut into slices were substituted for 11 lbs. of hay, the same theoretical equivalents being assumed for them as for the common potato. The ration now consisted of: Hay .... 11 lbs. Straw . .■ . 5i Oats . . . . 7j Jerusalem potatoes . 30.8 Having been accustomed to this regimen for some days, the teams were weighed, and having gone on for eleven days they were weighed again : Team No. 1. No. 2. Both teams. Means per horse. First weighing 4556 3245 8901 1112.7 Second weighing 4611 3412 8923 1113.6 In 11 days gain 55 loss 33 gain 22 gain 0.9 A result which leads to the conclusion, that the equivalent as- sumed for the Jerusalem potato was correct ; the animals had done their work, and gained, one with another, f^ths of a pound in weight. EXPERIMENT III. RATION OF HAY AND POTATOES. Eleven pounds of hay, in the usual allowance, were replaced by 30.8 lbs. of potatoes ; the whole of the oats and straw, by 15.4 lbs of hay. These substitutions were made upon the supposition, that 100 of hay was equivalent to 280 of potatoes, to 50 of oats, and to 630 of straw. The ration, then, was composed as follows : Hay 26.6 lb*. Potatoes 30.8 " 34* 402 MAINTENANCE OF ANIMALS. This was a ration which it was the more interesting to try, from the circumstance of Professor Liebig* having come to the conclu- sion, from certain theoretical views, that it must be impossible to keep horses in health and strength upon hay and potatoes exclusively. The experiment was continued for a fortnight : Team of No. 1. No. f. Both teams. Mean weight per hone. First weighing 4620 4312 8932 1116.5 Second weighing 4675 4697 9372 1171.5 In 14 days gain 55 385 440 55.0 In one fortnight, consequently, the weight of eight horses had in- creased by an aggregate sum of 440 lbs., or 55 lbs. per head — an increase at the rate of, as nearly as possible, 3.9, say 4 lbs. per diem ; and allowing the greatest latitude for error, it seems that we cannot estimate the increase per head at less than 1.76, say If lbs. per diem. The condition of the horses was most satisfactory ; the de- jections were healthy in appearance ; the only inconvenience ob- served was, the considerable bulk of the allowance, and the addi- tional time which had to be given the teams to their meals. This inconvenience was particularl}^ obvious in the case of the older horses. Besides the two experimental lots, other twelve horses were put upon the same regimen, and with the same good effects. The equivalents adopted in the composition of the ration, in this third experiment, may therefore be regarded with perfect confidence as suitable. Experience, indeed, would rather lead us to conclude, that the nutritive power of the potato had been estimated at some- what too low a rate. EXPERIMENT IV. SUBSTITUTION OF OATS AND STRAW FOR A PORTION OF THE HAY. The ration here consisted of: Hay 11 lbs. Straw 11 " Oats 12.1 " The horses, having been two days on this diet, were weighed. The experiment was continued for eleven days : Team No. 1. No. S. Both teams. Arera^ per hone First weighing 4584.8 4348.3 8933.1 1116.7 Second weighing 4593.6 4352.7 8946.3 lllSi! In 11 days gain 8.8 4.4 13.2 1.5 Under this regimen, consequently, the weight of the teams re- mained very nearly the same as it was before beginning the experi- ment ; still there was something gained. In conducting this experiment, we had an opportunity of observing how important it is to habituate the animals to their new regimen before weighing for the first time. Had this precaution been neg- 'ected, the result would hav« come out against the ration, for the animals were found, when first entered on it, to weigh together as many as 9372 lbs., and two days afterwards no more than 8933 lbs., * Afiictiltaxal chemistry. MAINTENANCE OF ANIMALS. 40S which would have indicated a loss of 449 lbs. ; the difference being due, however, in great part, or entirely, to the less bulky or weighty food employed. EXPERIMENT V. POTATOES SUBSTITUTED FOR A PORTION OP THE HAY. The ration made use of in the first experiment looks so well, in reference to economy of hay, and, indeed, answered so well under the peculiar circumstances in whi^ch it was tried, that I thought it would be advisable to try it again when the horses were doing ordi- nary work. The ration consisted of: Hay 11 Ihs. Straw.... 5.5 " Oats 7.23 " Steamed potatoes 30.8 " The first weighing took place after the horses had been over a week on the ration, and the experiment was continued for 63 days. In team No. 1, Braun, from indisposition, had been replaced by Rapp, a horse nine years old, and weighing 1157 lbs. : Team No. I. .... 4425 No. 2. 4362 4428 Bott teams. 8348 8929 Averag^e weight per hone. Second weighing.. .... 4501 1116.2 In 63 days gain 76 66 81 10.1 In the course of two months, consequently, on a ration in which 11 lbs. of hay were replaced by 30.8 lbs. o.^ dressed potatoes, the weight of the horses may be said to have been more than main- tained. This experiment seems to show satisfactorily, that the equivalent of the potato cannot be far from the number 280. EXPERIMENT VI. JERUSALEM POTATO FOR A PORTION OF THE HAY. The horses were brought back to the same conditions as in the second experiment, 30.8 lbs. of Jerusalem.^ being substituted for 11 lbs. of hay. The team No. 2 was alone subjected to this experi- ment, being kept on it for 16 days, and first weighed after having had it for some time : First weighing No. 2. 4395 lbs. Average weight per horse 1098.9 Second weighing.. " 4396.7 " " " 1099.1 Iniedays gain 1.7 0.2 This result confirms that which was elicited by the second ex- periment. EXPERIMENT VH. INTRODUCTION OF FIELD-BEET, OR MANGEL-WURZEL, INTO THE RATION. Horses readily get accustomed to field-beet. The root is sliced, and mixed with chaff, (cut straw.) For 11 lbs. of hay, which I re- trenched, I allowed 44 lbs. of beet ; i. e. I took 400 as the equiva- lent numbei of ^.he root. The ration consisted as under: 404 MAINTENANCE OF ANIMALS. Hay 11 lbs. Straw 5.5 " Oats 7.2 " Beet, 44.0 " A horse, after having: been kept on this diet for some time, wai weighed ; and the regimen having been continued for a fortnight, he was weighed again : First weighing 1014.0 lbs. Second weighing 1023.0 " In a fortnight gain 9.4 This horse was all the while doing rather hard but very regular work ; for eight hours every day he was in the shafts of a grinding mill. He did not alter in condition ; the dejections were healthy. During the winter of 1841-2, our cows ate a considerable propor- tion of our beet ; and, as a substitute for the 33 lbs. of meadow-hay, which is their usual allowance, we gave 72| lbs. of beet. The ration then stood thus : Hay 22 lbs. Beet 72.6 " Straw 4.4 " Upon this regimen, the weight of the inmates of one of our stables i»as: On the 29th January 24615 lbs. On the 21st April 26488 Increase due to births and to growth 1837 It thus appears that, in foddering kine, the quantity of beet allow- ed with advantage may be large ; but it is also obvious, that the nutritive value of the root is not great. At Bechelbronn, at all events, we found it requisite to replace 9 or 10 of hay by 40 of root. Our beet, it is true, contains but 12 per cent, of dry matter ; in other places, where the proportion of dry substance to the water is larger, it is possible that a smaller proportion would be found to answer the end. EXPERIMENT VIII. INTRODUCTION OF THE SWEDISH TURNIP INTO THE RATION AND REPLACING A PORTION OF THE HAY. Swedish turnip, combined with some dry forage, answers excel- lently with the horse. Analysis, indicating 280 as the equivalent of this article, two horses were put upon the following ration, in which 11 lbs. of the usual allowance of hay were replaced by Swe- dish turnip : Hay nibs. Straw 5.5 Oats 7.2 Swedes.... 30.8 It was obvious before the lapse of but a few days, that the horses were falling off upon this regimen, that they were not fed ; and on weighing them, this plainly appeared : First weighing 2283,6 Aver, of each horse 1141,8 Second weighing, 9 diys afterwards 2178,0 " 1089,0 LotslnQdays .105.6 SZ.i MAINTENANCE OF ANIMALS. 405 The equivalent for the Swedish turnip adopted, had therefore been too high ; the allowance was not sufficient. This led me to analyze the article again ; and I discovered that the true equivalent of the sample with which I was operating, was at least 676, and not 280 as 1 had presumed before. Indeed, in another experiment with the same pair of horses where the equivalent of Swedish turnip was as- sumed at 400, I found that though the animals kept up their weight at the point to which it had fallen, they gained nothing ; whence it may be safely inferred that the No. 400 was still too low, and that the new equivalent 676 is nearer the truth. EXPERIMENT IX. INTRODUCTION OF CARROTS INTO THE RATION. Horses are extremely fond of carrots ; and there is no root per- haps, the nutritious qualities of which have been more vaunted or exaggerated. Yet, analysis appears to indicate that 350 of carrot are required to replace 100 of good meadow-hay. On one occasion, in the stable at Bechelbronn, when the potato in one of our rations was replaced by an equal weight of carrots, the eifect was highly disadvantageous ; and even in following the theoretical equivalent of the carrot (350) we had still no reason to be perfectly satisfied. I now believe, in fact, that as many as 400 of carrots may be found requisite to replace 100 of good meadow-hay. The carrot crop of 1841 having been a failure, I had to limit my- self to observations made on a single horse, which was put upon a ration in which 11 lbs. of hay were replaced by 38.5 lbs. of carrots The horse, habituated to this diet, Weighed. 1025.2 lbs. A fortnight after 1014,2 Loss in a fortnight 11.0 Nevertheless he remained in good condition, so that the equivalent 350 is probably not far from the truth. I ought to say, however, that the men think this number too low ; an opinion in which they would be borne out, could we but be certain that the loss of weight of the horse just indicated was not accidental. EXPERIMENT X. BOILED RYE AS A SUBSTITUTE FOR OATS. It has been stated, that rye boiled till the grain bursts may be used as a substitute for an equal bulk of oats in the keep of a horse. The experiment which I made on the point is very far from bearing out any thing of the kind. By preliminary trials I had ascertained that rye of good quality swells to twice its former bulk by boiling. The two horses that were made the subjects of experiment now, had been kept for some time on a ration formed of : Hay 2.2 lbs. Oats 5.5 =8.8 pints. For the oats, the same quantity by measure, 8.8 pints of boiled rye were substituted, containing 4.4 pints of raw grain, weighing 4.15 lbs. On the Uth day it was deemed prudent to interrupt the experinient, of which the following are the results : 406 MAINTENANCE OF ANIMALS. First weighing : Both horses 2010 lbs. Average of each 10045 Second " " 1927 " 963.0 Loss in 11 days 83 41.5 In fact, with such a ration as this, in which water was made to replace solid corn, no other result could reasonably be expected. In continuing it, the health of the horses would very certainly have soon been seriously compromised. There is no objection to rye in Itself as an element in the food of a horse ; but then it must be sub- stituted in the quantity indicated by the table of equivalents, by adopting which, Mr. Dailly found that he could keep the post-horses of Paris in good heart, at a time when the difference between the price of oats and rye made it advantageous to substitute the latter for the for.rier. The experiments of Mr. Dailly on the subject were so decisive and so ably conducted, that I felt myself relieved from the necessity of inquiring further into it myself. From these experiments, the particulars of which have now been given, it may be conc'uded that the nutritive equivalents of the po- tato, beet, Jerusalem potato, and carrot, as they come out upon ana- lysis, or as they are inferred from the amount of azote they contain, may be adopted without detriment to the health of horses. If they err at all, it is that they assign equivalents somewhat too high, which is the same ay saying that their actual nutritive power is rather less than these numbers give it ; so that a portion of the hay of the standard ration being substituted for its equivalent of tuber or root, the diet will be improved. Thus, 100 of good meadow-hay may be taken, as ascertained by experiment, to be equivalent to : 280 potatcjs — ^by analysis, equal to 315 280 Jenisaiems 311 400 beet 548 400 Swede (too little) 676 400 carrot 382 In the following table of nutritive equivalents, to the numbers as- signed by the theory, I have added those of the whole which I find in the entire Heries of observations that have come to my knowledge. I have also given the standard quantity of water, and the quantity of azote, contained in each species of food. When the theoretical equivalents do not differ too widely from those supplied by direct observation, I believe that they ought to be preferred. The details of my experiments, and the precautions needful in entering on and carrying them through, must have satisfied every one of the difficul- ties attending their conduct ; yet all allow how little these have been attentively contemplated, and what slender measures of precaution against error have been taken. Our equivalent for field-beet is 400, a number come to by introducing 44 lbs. of the root into the ration, in lieu of 11 lbs. of hay ; had we introduced 56 lbs., the equivalent number would have come out 500 ; and it is questionable whether the final result would have been aflfected by this substitution. In my o'pinion, direct observation or experiment is indispensable, but mainly, solely as a means of checking within rather wide limits tljp w?'}!^? of cheiflicjl analysi?, MAINTENANCE OF ANIMALS. 407 Ordinary natural meadow-hay . Ditto, of fine quality .... Ditto, select Ditto, freed from woody stems . Lucern hay Red clover.hay, 2d year's growth Red clover cut in flower, green, ditto New wheat-straw, crop 1841 Old wheat-straw Ditto, ditto, lower parts of the stalk . Ditto, ditto, upper part of ditto and ear New rye-straw Old ditto Oat-straw Barley ditto Pea ditto Millet ditto Buckwheat ditto .... Lentil ditto Vetches cut in flower and dried into hay Potato tops Field-beet leaves Carrot ditto Jerusalem potato stems . . Lime-tree young shoots Canada-poplar ditto .... Oak ditto Acacia ditto (autumn) Drum cabbage Swedish turnip Turnip Field-beet (1838) Ditto, white Silesian Carrots Jerusalem potatoes (18^) . Ditto C1836) Standard water per cent. Azote per cent. PPPPPPPP®.O.«.^.®P.®.®.^.-'PP.«P®P.OrP.<='PpH-WJ06S>-M. Azote per cent. in the article not dried. ^im^mB^BB^BBmn^m^mm^m^B^^^^^^ Theory. ' ' mm- g: s^ ss: •• %• • W- • i^i :|: ■• ■■ ill: 's "8 Block. ::g %^^W' ■■ : : : : : ^^m^B^ §: : : §: S5^ = 8 = 8 Petri. .'•g W- W' • ' ' : : : :gss s* •:g::: = 8 Meyer. ::§ n§§^' ' ' •:§: :iss 1= • : ||$8 8 Thaer. ::| • ^^§W- ' :g:§ •m- •B§n '•&'• •• • iisi 8 Pabst. nW' %• ' • = i^s '^' ••'^W-' •i s Flottow. ::§ -m''' '. ijg: : : : : g: : 8 Pohl. ••i ■•ill::: .' •§ •s Rieder. : = ! liii: •• : s •gi §: ' 8 § Gemerhausen. ::| §¥¥'• :::§ 8* '. '. '. 88 i Crud. '•^ :§:§::: : :g •8 Weber. '•'•m i^: : : : : : ; • ■ 8 i Dombasle. '•'^ : : : ; = 8 i Krantz. ::i igi:::: ;. •' li- 88 8 Schwertz. 8 s g£i ij :§ '8 i Schnee. ::S !i:::i: 1 1 Midleton. !§;:i;: ; . ; 1 Murre. • l ! ::§!::: : '8 g Andr*. ill. §::;:!: ® Boussin^auh. 408 MAINTENANCE OF ANIMALS. Potatoes (1838) . Ditto (1836) . Ditto after keeping Cider apple pulpdr Beet-ro(jt magma f Vetciies in seed Field beans Whire peas (dry) White haricots I^entils . New maize . Buckwheat . Barley (1836) Barley-meal Ditto Oats (1838) . . Ditto (1836) . Ditto (Parisian) . Rye (1836) . . Ditto (1838) Ditto from highly n Recent bran . Wheat husks or ch Rice (Piedmont) Gold of pleasure se Ditto, cake . Linseed cake . Calza ditto . Madia ditto . Hemp ditto Poppy ditto Nut ditto Beech mast ditto Arachis (:•>) ditto Dry acorns Refuse of the wine H H ^ i".".'.::: in the pit ied in the air rem the sugar aanured soil aff. . 8d (Madia) 8. 3 Standard water per cent- Azote per cent. .^pooeocnw4^o*.p.w.wrptar!*?o!*r«!*t-t-rrt-wr?=r'^'^ws"s«^ppppf s n <3 s Azote per cent. ffifeSSSI2S2SBgKe£2^ig8RfcfeSg;Sgt3S8S22:gJS;Sgg?Kesii^Kl Theory. ::;•.:: ' 'fe • •■ : g: g: : ' «: &> '• ss" ' : : ggg* :i-'i Block. £2: •. ; : : ::s :::::::;: b: »: s: : 22§ s: &s^f^ :::§ Petri. ::::::: ::::::::.' j^: g: ; ; • a- ' ' feg: :::g Meyer. : : .' : : : :?::::::: g: 3: ag= •s= • '• 'ass :::g Thaer. g: : : : : :::::::: igig: 8" ■s' • • 't^t :::| Pabst. • • 1 1 . 1 1 • • = ife' : : :::| Flottow. 1 '.'.'.',','. : ! : g: : : : : ' 88* S' ' '• -sg: :::| Pohl. 1 ::::::. •b' 8! = •b" Rieder. » ::::::: :::::::::* : : : : Gemerhausen. '.'.'.','.'. ::::;:::: ::i| Crud. :::::: .. s ;:;:;:: ; Weber. •:::....; :::!:;.';: !^l *.'.•.§ Dombasle. 1 : ; :::;;:'.: \^\^\ ! i ! ;:..§ Krantz. ; ; . ; : i I ', ! !!!!!!!!! 1 ! ! ••'•■•8 Schwertz. ' 1 ! 1 1 : ! 1 ; i . ; : ; 'B' Schnee. 1 1 1 1 1 1 1 1 •• 1 1 Midleton. ::::;.';.; Murre. '.III!!!!; ig; 1 AndrA. ::!!: : ; : ; : : : i ; S! : : !] E! ! : ; : !:!i Boussingault. MAINTErrANCE OF ANIMALS. 409 To complete the preceding ample table, I shall still add the equiv- alents of a few articles of forage that have not yet been examined chemically. 100 of meadow-hay are replaced by : From 85 to 90 of sainfoin hay, accor«iing \o Petri and Meyer. By 90 of spurry hay " Petri. 325 to 500 of green spurry " Pabst and Flottow 42 to 50 of chestnuts " Block and Petri. By 50 of Indian chestnuts " Petri. 62 of turnsole seeds " Petri. 109 of rye-bran " Bloclt. In the list of substances there are some which are used almost exclusively for the food of man, and I have thought it not uninter- esting to contrast these different articles with reference particularly to the quantity of azote they contain. I have composed the follow- ing table or list of equivalents on this basis; ha\ing assumed wheat- en flour as the standard and called it 100. As all herbs, roots, leaves, &c., may be pulverized after drying, I hare spoken of these articles dry under the name of meal. Wheat flour (good quality) ... 100 White-heart cabl a ge 810 Wheat 107 Cabbage meal 83 Barley-meal 119 Potatoes 613 Barley 130 Potato meal 126 Rye Ill Carrots 757 Buckwheat 108 Carrotmeal 95 Maize 138 Turnips 1335 Yellow peas 67 Mealy bananas (Ficns Indica) 700 Horse-beans 44 Manihot (casava plart) 700 White French beans 56 Name "? (discorea saliva) 300 Rice 171 Apiol (arracacha) . 1050 Lentils 57 Judging from the equivalents, leguminous vegetables must be pos- sessed of a much higher nutritive value than wheat ; and it is known, indeed, that haricots, peas, and beans, form in some sort substitutes for animal food. The difference indicated is so great, however, that it may surprise those who have never thought of the subject that engages us. In a general way we are all perhaps disposed to re- gard the articles that enter habitually into our food as highly nutri- tious. The fact, however, is, that tubers, roots, and even the seeds of the cereal grasses are but very moderately nutritious. If we see herbivorous animals getting fat upon such things, it is only because their organization enables them to consume them in large quantities. i doubt very much whether a man doing hard work could support himself on bread exclusively. I am aware that countries are quoted where the potato and where rice form the sole articles of food of the inhabitants ; but I believe also that these instances are incom- plete. In Alsace, for example, the peasantry always associate their potato diet with a large quantity of sour or curdled milk ; in Ireland with buttermilk. The Indians of the Upper Andes do not by any means live on potatoes alone, as some travellers have said they do ; at Quito, the daily food of the inhabitants is lorco, a compound of potatoes, and a large quantity of cheese. Rice is often cited as one of the most nourishing articles of diet ; I am satisfied, however, af- ter having lived long in countries where rice is largely consumed, 35 110 INORGANIC ELEMENTS OF FOOD. that it is any thing but a substantial, or, for its bulk, nutritious arti- cle of sustenance. This is an important question, inasmuch as in some departments of the public service rice is sometimes served out as a substitute for other articles of diet. In the French navy, for example, 60 grammes, or about 20 dvi^ts. of rice may be substi- tuted for 60 dwts. of split peas or haricots ; but I cannot hold such a substitution to be either fair or reasonable. At a period when I had myself the charge of the rations for a detachment of men, I found that the experience of the country where I was, assigned 3 lbs. of rice as the equivalent of 1 lb. of haricot beans ; and analysis confirms this practical conclusion. Haricots, in fact, contain about 0.046 of azote ; rice no more than 0.014. And if the nutritious properties be really in proportion to the amount of azote, it is obvious that 3| of rice will be required in lieu of 1 of the leguminous seed. We hear it constantly repeated that rice is the sole nutriment of the nations of the whole of India. But the fact would appear not to be precisely so ; and I may here quote M. Lequerri, who, during a long residence in India, paid particular attention to the manners and customs of the inhabitants of Pondicherri. " The food," says M. L., " is almost entirely vegetable, and rice is the staple ; the infe- rior castes only ever eat meat. But all eat kari, an article prepared with meat, fish, or vegetables, which is mixed with the rice boiled in very little water. It is requisite to have seen the Indians at their meals to have any idea of the enormous quantity of rice they will put into their stomachs. No European could cram so much at a time ; and they very commonly allow that rice alone will not nour- ish them. They very generally still eat a quantity of bread."* ^ II. OF THE INORGANIC CONSTITUENTS OF FOOD. We discover in the bodies of animals the several mineral sub- stances, the existence of which we have ascertained in vegetables. The bones, as we have seen, contain a large quantity of phosphate of lime ; it is requisite therefore that the elements of this salt, phos- phoric acid and lime, should form part of the ration or diet-roll ; this is a point upon which all physiologists are agreed ; but the point upon which there is nothing like uniformity yet attained h«.s refer- ence to the precise quantity of mineral matter which must enter into the constitution of the food. The analyses of ashes which I have given show that if vegetable aliments all contain nearly the same inorganic principles, they still contain them in very different proportions : thus potatoes, wheat, oats, and beans, contain much less lime than clover, straw, and peas. The phosphoric and sulphuric acids and the alka- lies do not vary less ; so that we are led to ask whether a ration compounded of such and such an article, or of such and such arti- cles, will furnish the animals to which it is supplied with the neces- * The Irish peasantry, who live so much on potatoes, have buttermilk with them at least, often salt herring ; and a laboring man, it is said, will consume Ji or 14 Iba per diem !— £ho. Eik INORGANIC ELEMENTS OF FOOD. 411 sary dose of inorganic principles, which must be assimilated daily, and which is quite indispensable to maintain them in health and vigor. It is easy to arrive at a knowledge of the mineral principles which are necessary as elements of the diet, by ascertaining their quantity in the ration, which long experience has shown to be sufficient. Yet as there is reason to believe that in many cases mineral substances are present in excess, I have thought that it might be useful to de- teimine by means of analysis the nature and the proportion of the inorganic elements which are actually assimilated by .an individual, in order to have a minimum which might serve as a basis for any reasonings or inferences on the subject. My experiments were per- formed in two opposite circumstances in which I regard assimilation as most rapid and most complete : videlicit, a calf in full growth, and a milch-cow in calf The calf was six months old, and weighed 369 lbs. Some days before being made the subject of experiment it was fed with hay. During the two days when it had this fodder ad libitum, it ate 19 lbs. In the course of the 1st day the calf passed 21.49 lbs. of excrements. 2d day " 20.39 " " 41.88 Which, dried, was reduced to 7.41 lbs. In the course of the two days 5.584 lbs. of urine were collected, which, evaporated, yielded 2933.2 grains of extract, the animal hav- ing in the same interval drunk 45.7 pints of water. Analysis discovered in 100 : Of the hay Azote 1.6 Ashes 7.6 Of the dry excrements "2.1 " 12.7 Of the urinous extract " 4.0 " 40.0 Now if we inquire from these data in regard to the quantity o' azote and of mineral matters which were assumed with the food in the course of two days, we have : half-drachms. half-drachmi. In the food, discarding fractions, Azote 69 Mineral substances 328 In the excrements " "50.5 " 214 In the urine " " 3-8 " 38 Together 54.3 252 Therefore, azote fixed or exhaled in 2 days 14-7 half-drachms. Mineral substances fixed in 2 days 76 " The composition of the ashes obtained from the hay and from the excrements, shows us approximatively both the quantity and the nature of the several inorganic substances which had been assimi- lated The composition of these ashes is as follows : Of the bay. Of the excrements. Of the urine. (Carbonic 9.0 2.0 17.3 Acids < Phosphoric 5.3 5.1 0.2 (Sulphuric 2.4 2.3 7.0 Chlorine 2.3 1.9 9.9 Lime 20.4 16.0 0.9 Magnesia 6.0 6.5 6.0 Potash and soda 17.3 12.5 57.3 Oxide of iron, alumina 1.5 1.0 " Wlesia 33.7 51.0 1.9 LoM 2.1 1.7 100.0 100.0 IjOOuO 412 INORGANIC ELE3IENTS OF FOOD. if the hay consumed contained 328 half-drachms of ash or mineral matter, the excrements and urine 252 half-drachms of the same matters ; the difference between the two sums, 76 half-drachms,* is the quantity of mineral matter fixed in the course of two days, of which 200.6 grains were phosphoric acid, and 494.0 grains were lime. This quantity of lime, however, is more than four times as much as is necessary to constitute a subphosphate of lime such as exists in the bones. It is true, indeed, that there is always a quan- tity of carbonate of lime associated with the subphosphate in bones ; 10 of carbonate for 38 of phosphate, according to Fourcroy and Vauquelin, in those of the ox. Still the quantity of lime assimilated was vastly more than it ought to have been, had it only gone to assist in the formation of bone. If there was no error in the observations, it is probable that the base in question enters into the constitution of the salts with organic acids which are encountered in all parts of the animal body. By a series of weighings, I ascertained that my calf, fed simply upon hay, increased every day by a quantity equal to 9725.9 grains troy, in which were included 858.35 grains of mineral substances, the calcareous phosphate and carbonate of the bones in this quan- tity being represented by 262.4 grains, or nearly 3 per cent, of the entire weight acquired in the course of twenty-four hours. ' In the experiment with the milch-cow in calf, I limited my inqui- ries to the phosphoric acid and the lime taken in and given out. The animal, four years old, was '2^ months gone with calf, and weighed 1452.6 lbs. She had the same allowance during the expe riment as she had had for several days before, and which for twenty four hours consisted of — Ha3- 16.5 lbs. Cut wheat-straw. ••• 9.9 Beet 59.4 The experiment was continued for four days, during which tho excrements, the urine, and the milk, were carefully collected and weighed, and the ashes, both of the food consumed and of the pro- ducts rendered, were determined by chemical analysis. Suffice it to say, that, representing the quantity of mineral matters assumed into the body in the course of the experiment by 849.9 half-drachms, the quantity voided amounted to no more than 556 half-drachms. In the quantity assumed, there were 100.2 half-drachmsof phosphoric acid, and 203.8 half-drachms of lime ; in the quantity voided, there were but 68.2 half-drachms of phosphoric acid, and 116.8 half-drachms of lime : this is at the rate of about 8 half-drachms of phosphoric acid, and 22 half-drachms of lime assimilated in the course of twenty- four hours. Here, as in the case of the calf, the quantity of lime assimilated is greatly superior to what it ought to be, in order, by combining with the phosphoric acid, to constitute the phosphate of lime of the bones. From these inquiries into the nutrition of a calf and of a cow in • The szact quantity is 2392.8.grain8 troy.— Ema. E». INOBGANIC ELEMENTS OF FOOD. 413 calf, it follows that tnere is a portion of the mineral substance taker in with the food, which remains definitively fixed to concur in the growth or in the evolution of the individual. In an adult animal it is to be presumed that no such definitive fixation of inorganic prin- ciples takes place, or that it is much less considerable ; that in the dejections and several secretions ought to be found the whole of the phosphoric acid, of the lime, &c., taken in with the food. And this presumption is confirmed by experience ; for on instituting an inquiry into the matter upon a horse, it was found that the mineral matters assumed were almost exactly balanced by those discharged. Never- theless, and granting this to be quite true, which it is, it would be a grave mistake to suppose that an adult animal could go on for even a very short period of time upon food that contained no mineral matter. Precisely as in the case of organic matter, it appears that a portion of inorganic matter is also fixed in the living frame, where for a time it forms an integral element in the wonderful structure ; and a supply of the latter kind is undoubtedly no less necessary than is the supply of the former description recognised by all the world. Were there an inadequate quantity of phosphoric acid, of lime, &c., in the food, no question but that the body would speedily feel the effects of the deficiency, and that disease and death would by and by put an end to life. So much, indeed, seems demonstrated by thi> very interesting experiments of M. Chossat, in which he kept granivorous animals upon a diet rich in azotized principles and in starch, but deficient in lime. From some previous inquiries, M. Chossat had observed that pigeons even require to add a certain proportion of lime to their ordinary food, the quantity naturally con- tained in which does not suffice them. Wheat, as we have seen, though it contains a large proportion of phosphate of magnesia, con- tains very little phosphate of lime ; and pigeons put on this grain, though they do perfectly well at first, and even get fat, begin by and by to fall oflf. In from two to three months, the birds appeared to suffer from constant thirst ; they drank frequently ; the fceces be- came soft and liquid, and the flesh wasted, and in from eight to ten months the creatures died under the effects of a diarrhoea, which M. Chossat attributed to deficiency of the calcareous element in the food. And it is neither uninteresting nor unimportant to observe, that the same thing occasionally occurs in the human subject during the period when the process of ossification is usually most active. But one of the most remarkable features of M. Chossat's experi- ments was observed in the state of the bones of the pigeons ; they became so thin and weak that they broke during the life of the birds with the slightest force.* The conclusion from this fact is obvious. Supplies of all the elements of all the parts of the body are indispen- sable to the maintenance of health, to the continuance of life. A pigeon will eat about 463.140 grains of wheat per diem, con- taining 9.725 grains of ash, in which analysis discovers 4.569 grains of phosphoric acid, and 0.277 of a grain of lime. But this smaU * Chossat, in Comptes Rendiis, t. xiv., p, 451. 35* 414 INORGANIC ELEMENTS OF FOOD. quantity of lime is incompetent to maintain the bones in their stan- dard condition. I have thought it of moment to insist upon these facts, because I see that they may sometimes come into play in practi- cal rural economy. No breeder or feeder ought to be ignorant of the influence of mineral substances on nutrition. It is not only indis- oensable that the allowance of an animal in full growth be sufficient to support, and even to add to the soft textures ; it must further con- tain the elements requisite for the nutrition of the osseous system : and it is not impossible but that, in managing the feeding of young cattle or young horses in such a way as to reduce to a minimum, or to give in excess, certain of the inorganic elements of the food, we may succeed in impressing one character or another upon a race. It is even possible that the empirical rules which are acted upon with a view to increase or diminish the quantity of bone, the weight of flesh or of fat, &c., are all connected with various proportions of phosphoric acid, of lime, magnesia, &c., in the food. It will probably be discovered, some day, that Bakewell's art is to be ex- plained through the composition of the ashes of the food. Wheat is not the only alimentary matter that contains an insuf- ficient quantity of lime ; maize or Indian corn contains still less . and if that which is grown in the tropics contains as little as that which is produced in Europe, it would be difficult to explain how the grain should answer so well as it unquestionably does for food.* It is true that it is seldom or never consumed alone and without addition ; and in South America, where the animals have it largely, I have observed that they frequently eat earth. The habit which certain tribes of the natives have of eating earth, too, which has been particularly remarked upon by travellers and missionaries as an instance of depravation of taste, presents itself to me in quite another light, since 1 became acquainted with the composition of the ashes of the ordinary article of diet in the countries where it occurs.f The calcareous and other salts necessary to nutrition, how- ever, are not derived from the food exclusively ; the water that is generally consumed contains a quantity which is by no means to be neglected. A horse or a cow, for instance, which drinks from 15 to 45 quarts of water per diem, will even, if the water be as pure as that of the Artesian well of Grenelle, take in from 35 to 108 grains of saline matter in which carbonate of lime predominates ; water that is less free from saline impregnation would of course introduce a much larger proportion ; some waters in the quantities above speci- fied will contain from 138 to upwards of 400 grains of saline matter, one half of which may be carbonate of lime. And I am here speak- ing of clear or filtered water ; that which is muddy or turbid con- tains a still larger quantity of earthy matter in suspension than in solution. In an experiment made for the purpose of getting at the amount of earthy matter taken by a milch-cow from the watering- ♦ An ash of maize, analyzed in my laboratory by M. LetelJier, contained bat 1.3 pel •ent. of lime to 50.1 of phosphoric acid and 17.0 of magnesia. 1 1 several times saw children chastised in Indian villages who h«d been saufk •ating earth. INORGANIC ELEMENTS OF FOOD. 415 trough in the course of the day, I found that it amounted to about 770 grains troy. Notwithstanding these facts, it is still doubtful whether the lime contained in ordinary well-water would prove sufficient to supply a growing animal with the material requisite to the formation of its bones ; in adults, indeed, changes in the elements of the bones ap- pear to proceed so slowly that a very small quantity of calcareous matter probably suffices to repair losses ; but it is otherwise with young and growing animals. I have shown that a calf six months old receives with its forage a quantity of phosphoric acid which cor- responds to 555.7 grains of phosphate of lime. A calf a few weeks old, when it has 17 or 18 pints of milk per diem, receives 802.7 grains of mineral substances, into which subphosphate of lime or bone earth enters in the proportion ot 370.5 grains. It would be in- teresting to ascertain what quantities of these substances were as- similated by so young an animal, and at a period when the growth is so rapid that the increase from day to day sometimes exceeds 2 pounds. The importance of the inorganic principles of the food once re- cognised, it concerns us to take note of their nature and quantity in the ratio we allow to our domestic animals. It is in fact this con- sideration which has led me to determine the quantities of phospho- ric acid and lime contained in the various articles of food the ashes of which have been analyzed. With these data the proportion of bone earth contained in a given ration is forthwith perceived. One thousand parts of the forage gathered at Bechelbronn in its ordinary state contained : Forage. Hay Potatoes Beet Turnip ■ Jerusalem Potato Wheat Maize Oats Wheat-straw • • • < Oat-straw Clover-hay Peas Haricots Mineral *„„,. Phospho- , -^^ Bone Substance*. ^^°*-^' ric icid. ^"°«' earth. 62.33 9.64 7.70 5.70 12.47 20.51 11.00 31.74 51.90 35.70 73.50 30.00 3500 30.00 11.50 3.70 2.10 1.30 3.75 20.50 16.40 17.87 3.00 300 21.00 38.40 45.80 51.10 3.37 109 0.46 035 1.35 9.64 5.51 4.73 1.61 1.07 4.63 9.03 9.38 10.26 10.04 0.17 0.54 0.62 029 0.60 0.14 1.17 441 2.97 18.08 3.03 2.03 1.53 0.33 0.95 0.72 0.56 1.16 0.27 2.27 3.32 2.21 9.85 5.83 5.94 9.27 We seem here to observe a certain relation between the proportion of azote ard that of the phosphoric acid contained in the food ; the most highly azotized are also those that generally contain the largest quantity of the acid, a circumstance which seems to indicate that in the vegetable kingdom the phosphates are connected more especially with the azotized principles, and that they accompany them in pass- ing into the textures of animals. With the assistance of the above table it is easy to ascertain the quantity of phosphate of lime which 416 FATTY ELEMENTS OF FOOD, AND ON FAITENING. enters into a given ration. Let us take that given to the horse? in experiment 3d, in which the half of the hay was replac-'id by pot\- 4X)es, one of the articles that contains the smallest proportion of liu«*J, and we find in the 26.6 lbs. of hay 632.9 grs. phosphoric acid and 1867.9 grs. of liire. 30.8 lbs. potatoes 387.7 " 37.0 1020.6 1904.9 numbers which correspond with 1798.5 grains of bone earth, \' 078.7 grains of uncombined lime. In his usual allowance a work-horse at Bechelbronn receives : Hay 22 lbs. containing 524.8 grs. phosphoric acid, and 1543.8 grs. of lime. Straw 5.5 " 60.7 Oats 7.2 " 230.2 " 81.57 In other words, 1735 grains of bone earth, and 864 grains of fret lime. I have found that very young foals, growing rapidly, and weigh ing about 374 lbs., consume per diem : '-«-« Hay- ■ . • J9.8 lbs. containing of phosphoric acid 463 grs. : lime 1389 grs. Oats... 75 " " 231 " 58.6 which represent 95 of bone earth or subphosphate of lime. As a consequence of the relation which appears to exist between the azote and phosphoric acid of an article of sustenance, it comes to pass that like nutritive equivalents also indicate like proportions of phosphoric acid ; so that by introducing a suitable quantity of hay or clover, articles that abound in lime, into the ration, we are always certain of having food favorable to the development of the osseous system, whatever the nature and quality of the other articles that enter into the constitution of the allowance. The relation of the phosphoric acid to the azote approaches the ratio of 3 to 10. in the more ordinary articles of forage ; but the same relation is no longer apparent in the cereals and leguminous vegetables ; in grain and in peas, beans, &c., the phosphoric acid amounts to about a fourth of the azote contained. Thus we have : Theoretical equivalent. 100 Hay Potatoes 320 Beet 548 Turnip 885 Jerusalems 273 Dry clover 75 Wheat-straw... 235 Phosphoric acid in the equiralent. 0.34 0.35 0.28 0.31 0.37 0.S4 0.37 Theoretical equivalent. Oat-straw 380 Oats 68 Maize 70 Wheat 43 Peas 25 Haricots 27 Beans 23 Phoiphone acid in the equivalent. 0.40 0.32 0.38 0.41 0.23 0.25 0.24 ^ in. OF THE FATTY CONSTITUENTS OF FORAGE : CONSIDERATIONS ON FATTENING. When fat was observed accumulating in the tissues of the animal body, and it was unknown that the presence of fatty matters in plants is what may be termed a general fact, men naturally con- ceived that the fat was produced from the food in the act of dige» FATTY ELEMENTS OF FOOD, AND ON FATTENING. '117 tion, that it was composed in the animal body much in the same way as it is formed in the seed and leaf of the living vegetable. The inquiries which I am about to present, however, all tend to make us conclude that fatty substances are only produced in vege- tables, and that they pass ready formed into the bodies of animals, where they may either undergo combustion immediately, so as to evolve the heat which the animal requires, or be stored up in the tissues in order to serve as a magazine of combustible matter. This latter view appears the most simple ; but before discussing the experiments which bear it out, it seems necessary to pass in brief review the notions that have been entertained at different times on the formation of fat. When the great burying-place of the In- nocents was emptied, for example, it was commonly imagined that one of the effects of the putrefactive process was to convert the flesh, the brain, the viscera, &c., into fat — adipocire, as it was called ; it was not, indeed, till after the researches of M. Chevreul had been undertaken, and that it was discovered adipocire contained the same acids as human fat, which had, in fact, only been partially saponified by ammonia, — until the inquiries of M. Gay-Lussac were made public — that it was acknowledged that muscular flesh or fibrine subjected to putrefaction leaves no larger a quantity of fat than can be obtained from it by proper solvents before it has undergone any change : the effect of putrefaction is to destroy the fibrine, and so to expose the fatty substance which it contained. It may therefore be said, that all these fortuitous opinions upon the supposed formation of fat by chemical processes, have vanished as they have been successively subjected to careful examination. Let us now turn to the inferences come to by physiology. The Dodies of carnivorous animals are often loaded with fat ; and none can be detected in any of their excretions. It is therefore in these animals that it must be most easy to ascertain the source or origin, and mode of disappearance of fatty matter. When the progress of digestion is watched in a dog, it is soon discovered that the chyle is far from being a fluid having uniformly the same characters and qualities. That which is produced under the influence of a vegetable diet, abounding in the starchy principle and in sugar, or after a meal of perfectly lean meat, is always and alike poor in molecules or globules. The chyle is then nearly trans- parent, extremely serous, and yields very little fat when washed with ether. But if the animal have a meal of fat food, the chyle that re- sults from it is opaque like cream, very rich in particles, and, digest- ed with ether, yields a large quantity of fatty or oily matter to that solvent. These facts, observed by M. Magendie, and confirmed with more ample details by Messrs. Sandras and Bouchardat, show that the fatty principles of our food minutely subdivided or made into an emulsion by the act of digestion, pass without undergoing any es- sential change into the chyle, and from that into the blood, whithei they can in fact be followed, and in which they can be shown tc remain for a longer or a shorter time unaltered, at the disposal of 418 FATTY ELEMENTS OF FOOD, AND ON FATTENING. the economy, as it were. Such observations have naturally led physiologists to conclude that the fatty principles of the food were the principal, if not the only sources whence animals derive the fat which is met with stored up in their tissues, or which appears in the butter of their milk. And this view, so long as the carnivorous tribes alone are considered, has not a single feature which makes it objectionable. But when we would extend it to the herbivorous tribes, two difficulties meet us on the threshold of the inquiry. 1st. Do vegetables actually contain such a quantity of fatty matter in their structure as will explain the fattening of cattle and the for- mation of milk 1 2d. Is it not more simple to suppose fat and butter the product of certain transformations undergone by starch and sugar in the animal economy 1 It appears at first sight most opposite to nature to suppose that the feeding ox finds the whole of the fat he lays on ready formed in the food he eats ; it is only, in fact, after having made repeated analyses of plants, and discovered fatty matters almost everywhere, and in quantities generally superior to any that had been suspected in the composition of plants, that the idea begins to acquire likelihood ; finally, the chemist becomes convinced that it is so when he finds a regular association of neutral azotized substances and fatty principles in all the articles usually employed as food for cattle, — in the grass- es and cereals, in the leaves and stems and seeds of plants. Fatty substances appear to be principally formed in the leaves, where they frequently show themselves under the form and with the properties of wax. Taken into the bodies of animals, mingled with the blood, and exposed to the influence of the oxygen of the inspired air, they will undergo an incipient oxidation, whence will result the stearic or oleic acid that is found as a constituent of suet. By undergoing a second elaboration in the bodies of the carnivora, the same fatty substances, oxidated anew, would produce the mar- garic acid which characterizes their fat. These divers principles, by a still further degree of oxidation, would give rise to the fat vola- tile acids which make their appearance in the blood and in the per- spiration. Finally, did they suffer complete oxidation, i. e. combus- tion, they would be changed into carbonic acid and water, and be in this shape eliminated from the economy. Among the various properties possessed by fatty substances, there is one which may play an important part in the phenomena of fatten- ing ; this is the solvent power which they severally possess in re- gard to one another ; the property of mixing in all imaginable pro- portions, still preserving the general features which severally dis- tinguish them. In the stomach, in the intestines, in the chyle, and in the blood, fatty substances of various kinds may form homoge- neous matters by their intimate admixture, and become divided into globules of complex composition, but everywhere the same. Another property of fatty matters of every kind, which deserves particular attention, is that of insolubility in water. We find, in fact, that when an animal eats a soluble substance, that in general il FATTY ELEME:XTS OF FOOD, AKD OH FATTEJIiXO. 419 i» cob^nmed by a true process of combastion, which conrcrto iU -jarbDQ into carbonic acid, and its hydrogen into water ; or otherwise, •X 13 simply eliminated without change in the nrine. Fatty matters may, indeed, disappear under the first form ; bat %o long as they escape remarkaUe modification, it is certain tint ihey do not pass off by the urine, and that the quantity eliminated by the perspiration is insignificant. Their ins^ubilitj, therefore. retains them in the economy once they have eotered tftie blood or the tissues ; and it is in virtue of this quality that tiiej cuaBlilole a kind of mmgaxine of combustible matter in the umnl body. TUo 18 the principal reason wherefore individuala eapiilied with food mi excess get fat, and that those insufficiently fed fiill leas ; the httj matter being deposited in the interstices of the tiawca ia the foimr case, being taken up from tbem and buned m the aeoood. This explanation is anractively simple ; bat ia oar attachment to it we must not forget that other expiaaatiooe hare also been giren : and in particular it must be contiaMed with a view which has been formed upon certain inquiries undertaken by M. Dumas. It is known, for instance, that sugar may be regarded as a eonpoaad of carbonic acid, water, and olefiant gas. Now there is nnthiag to pie- vent olefiant gas becoming d^aehed sad takia^ diicieait states of condensation, to give rise to bodies whieh by onderg ois^ oiidstina would produce fat acids and consequently fats. Since it has beea known that the oil ofpot^ito spirit is also met with in the spint obtaia- ed from the refuse of the grape, and ia the spint ptocaiod finaa malt, and from the molasses of beeuroot sagar, the assorsace that the oil is a product ef the fermenution of sogar ipposrs to be com- plete. We ought even to be prepared to admit a pheoomen<»i of the same kind as ta^ng place in plants, when we see the sugar of their stems disappearing in the same ratio as their seeds or fiwts bee Mas charg- ed with oleaginous matter : all the palms elabMate si^ar hefoia producing oil. It is upon chemical views of this kind that the socoad opskai as to the source of fat in animals has been formed, sod whieh may he said to stand in direct contrast with that which assumes this sub- stance as pre-existing in the food, which regards it as prodnced in the blood itself, under the influences of the most intimate fagcoo of animal life. For my own part, I adopt the view which lajiiiooes sa animal to be supplied with fait alresidy formed, BMiafy ^miw it presents itself to me as more in harmony with the foi^s which I observe in oar stshles. Still I do not deny that it may be posiMhiii for a certain qaaat^ of fat to be elaborated in the bodies of hsihi- Torous animals, under the influence of a special fermeatatioa of the sugar which forms an element in their food ; slthoogh I fod tntipfed, from practical facts, that sugar plays no essentia] part in the fatten- ing of cattle. The formation theory, nevertheless, is not without data of a very curious and important kind, which require notice. Huber had ' tluil bees fed upon honey, and even upon sugar, did not b^ 420 FATTY ELEMENTS OF FOOD, .'..ND ON FATTENING. power of producing wax for a long period. And Messrs. Milne Edwards and Dumas have lately confirmed the occasional accuracy at least of this conclusion. Their first experiments were unfavora ble to the conclusions of the celebrated bee-master of Geneva. A swarm fed with lump-sugar yielded very insignificant quantities of wax ; three other swarms, placed in glazed hives, and fed on honey and water, failed to produce any wax ; but a fourth swarm gave a totally different result. The procedure by analysis was now instituted. The absolute quantity of wax contained in the body of a bee, or in the bodies of a certain number of bees, was first ascertained ; second, the quantity of wax in the combs constructed by the laborers was determined ; third, the quantity of wax contained in the honey consumed was dis- covered. The final result of the inquiry was, that a swarm of 2005 laborers, after having in the course of a month consumed 12889.43 grs. of honey, had produced 2407 grs. of wax.* Granting the accuracy of this conclusion, admitting that the bee fed upon honey has the power of producing wax, I might still ask whether it was therefore legitimate to conclude that the ox was endowed with any faculty of the same kind 1 Still, to the interesting physiological fact above quoted, may be associated the remarkable fact of the conversion of sugar into butyric acid, observed by Messrs. Pelouze and Gelis, a conversion effected by mixing a small quantity of caseum with a solution of sugar, and adding a sufliciency of chalk to neutralize acid as it was formed. This mixture, placed in a tem- perature of from 77" to 86° F., by and by passes through a series of changes, the last term of which is the butyric fermentation. This butyric acid is a volatile, colorless, and very limpid fluid, having an odor that brings to mind at once that of vinegar and rancid butter. Although it has a resemblance to the acids which prevail in different kinds of fat, it nevertheless, by uniting with glycerine, constitutes a fatty body, butyrine, which forms about one-hundredth part in the constitution of butter, and must therefore be received as one of the elements of the fats ; and the observations of Arthur Young would even incline us to presume that butyric acid exerts a favorable influence in the fattening of animals. Comparative experi- ments satisfied Young that hogs fattened more quickly on food that had become sour, than on the same food before it had turned. Now it is very probable that there was production of butyric acid in the course of the fermentation. The question in reference to the formation of fat is of much more limited interest to the farmer than to the physiologist. The agricul- turist, in fact, cares little whether a couple of pounds of honey con- sumed by a hive of bees will give origin to some 10 dwts. or so of wax ; the matter that concerns him is, as to the degree in which the roots or tubers that he grows are fattening ; and whether or not he can advantageously substitute a cheaper for a more costly articlti in his piggery or stalls 1 And here, as in so many other placei • Vide Co>iii)tcs rcnilus dc rAcadtinlc dcs Sciences t. xvii. p. 131. FATTY ELEMENTS OF FOOD, AND ON FATTENING. 421 practice got the start of theory ; and I own, with perfect humility, that I think its conclusions are in general greatly to be preferred ; the universal custom of giving oil-cake and oleaginous seeds to our milch-kine and fatting oxen and sheep, appears to me to supply an argument of much greater force than any that can be obtained from chemical researches pursued in the laboratory. Such articles as the potato and the banana, which answer admi- rably for the keep of hogs after they are weaned, are not adequate to fatten them for the butcher ; they contain but very small quantities of fatty matter, and though the animals will grow rapidly upon them, and even attain to and maintain a certain condition, all that is re- quired can only be secured by adding some other article to the ration that is richer in oleaginous or fatty principles. At Bechelbronn, whatever others have said on the subject, we find that our hogs will not fatten on potatoes alone ; so that I agree with Schwertz when he says, that while hogs will get into good flesh upon potatoes, and even seem to fatten for a time, they soon cease from improving, and only begin to advance again when they receive in addition an allow- ance of barley or of split peas or beans. A young pig will consume about 13 lbs. of potatoes per diem, into which, as analysis of the ashes informs us, there enters but about 17.2 grs. of lime. But this quantity is probably too small to meet the demand for bone earth in a young animal in full growth, and hence the great advantage of the whey or small quantity of skim milk which is so commonly added to the potato ration. It ought to be laid down as a general rule, that young creatures as well as adults ought to have a ration which contains the earthy elements of the bony system, the azotized elements of the flesh, and the fatty matter of the fat. From a series of experiments which I undertook, in concert with Messrs. Dumas and Payen, it appears that all the arti- cles acknowledged the most powerful as fatteners, are those also that contain the largest proportions of fatty principles. The follo>y- ing substances contain the numerical quantities of matter soluble in et' er in 100 parts : Common maize 8.8 Dryhicem 3.5 Beaked Lombardy maize 7.8 Meadowhay 3.8 Large white Parisian maize...- 8.1 African wheat straw 3.2 Rice 0.8 Ditto Alsace 2.2 Oats 5.5 Ditto near Paris 2.4 Ditto 3.3 Oatstraw 5.1 Rye 1.8 Beanmeal 2.1 Rye flour 3.5 Beans 2.0 Hard Venezuela wheat 2.6 Haricots 3.0 Hard African wheat 2.1 Peas 2.0 Wheat flour 2.1 Lentils 2.5 Ditto 1.4 Potatoes 0.08 Finebran 4.8 Mangel-wurzel 0.1 Coarsebran 5.2 Carrots 0.17 Dryclover 4.0 Oil-cake 9.0 M. Payen found that the oil was everywhere present in the seeds of gramineous plants. The embryo contains much, the husk less, the farinaceous portion still less. But maize and oil-cake contain about 9 per cent., whence the universally admitted superior fattening power of these two articles. 36 422 FATTY ELEMENTS OF FOOD, AND ON FATTENING. If we now discuss particularly one or more of the rations or allowances to oxen put up to fatten, or to milch-cows, we shall find that they uniformly contain a larger quantity of fatty matters than the secretions, excretions, and fat which have heen produced under their influence. Thus a cow, in good condition, that produces 72 pints of milk, containing 3.3 lbs. of butter, while she eats 220 lbs. of meadow-hay, will have consumed more than 6.6 lbs. of matter soluble in ether — fatty substances. The quantity of fat contained in the food, over and above that which is discovered in the milk, has passed with the excrements, which are never entirely free from sub- stances analogous to fatty matters. With a view to comparing as accurately as is possible in inquiries of this kind, the quantity of fatty matter contained in the forage consumed by a cow, with that found in the milk and in the excre- ments, the following experiment was made. A cow, Esmeralda, No. 6 in the stable at Bechelbronn, calved on the 26th of September, and she was put to the bull again on the 4th of November. Up to the 22d of January (inclusive) Esmeralda received the usual allow ance, viz : After-math hay 11 lbs. Oil-cake 22 " Turnips 66 " Wheatchaff. 22 " and the milk she gave in the course of the month of January, amounted on the — Pints. Pints. Istto 12.9 12th 12.3 2d 12.3 13th 11.4 3d 12.3 14th 11.4 4th 11.4 15th.: 12.3 5th 10.5 16th 10.5 6th 12.3 17th 11.4 7th 12.3 18th 10.5 8th 12.9 19th 11.4 9th 12.3 20th 11,4 10th 10.5 21st 11.4 11th 11.4 22d 11.4 The average quantity of milk, therefore, per day, in the course of the week that preceded the experiment, was 10.287 pints. From the 23d of January, when the ration was altered to — Hay 16.5 lbs. Chopped wheat straw 9.9 " Beet-root 59.4 " the quantity of milk yielded was : January. Pints. January. Pints. 23d 11.4 27th 11.6 24th 10.5 28th 11.4 25th 10.5 29th IIA 36th 10.5 30th 11.4 on an average 11.8 pints per diem ; a little more than with the form- er allowance. The excrement passed by this cow was analyzed during four days, from the 24th to the 27th of January ; the whole quantity being weighed moist every day, and well mixed, a mean sample of about 0 oz. in weight was taken for analysis. This being stove-dried, the f ATTY ELEMENTS OF FOOD, AND ON FATTENING. 423 entire quantity of dry matter contained in the moist excrement waa readily ascertained : Dates. Moist excrement. Dry excrement. Milk in pints. Milk in Ibi. Jan. 24 40.7 lbs. 6.8 lbs. 10.5 13.5 25 41.8 7.3 10.5 13.5 26 62.1 9.0 10.5 13.5 27 43.4 7.1 10.5 13.5 188.0 30.2 42.0 54.0 To ascertain the quantity of fatty or waxy substances contained in the food, the several samples were first treated with hot water, then with ether, and finally with a mixture of ether and alcohol boil- ing. The fatty element of the butter was determined by Peligot'a method. Fatty Matters in tbe Food per c»nt. „„„ S 1st Experiment 3.6 "*y )2d ditto 3.9 Straw 1st Experiment 2.4 2d ditto 2.0 Fatty Matter in the Excrements and Milk per cent. Excrements (dry) S ^ ^E"'"*:::::::: i.-.lio Milli 3.7 Let us say, that the proportion of fatty substance contained per cent, in the several articles consumed as food, was as follows — Hay 3.7 Straw 2.2 Beet 0.1 Dry excrements 3.6 Milk 3.7 and we shall have the results of the experiment in this shape : FOOD CONSUMED IN FOUR DAYS. EXCREMENTS AND MILK IN FOUR DAYS. Fatty matter. Fatty matter. Beet 237.6 lbs. 1667.3 grs. Excrements 30.4 lbs. 7688.1 grs. Hay 66.0 1776.1 Milk 54.3 14125.7 Straw 39.6 6113.4 Fatty matter in excrements Fatty matter in food. .24956.8 and milk 21813.8 The excretions 21813.8 Fatty matter fixed or burned 3143.0 The natural conclusion from this experiment appears to be this : that the cow extracts from her food almost the whole of the fatty matter it contains, and that she converts this matter into butter. It would perhaps be possible to make the proportion of butter contained in the milk to vary within certain limits. It is well known that the butter of cows in the same district varies notably according to the nature and abundance of the forage ; the butter of the same country-side, for example, has been ascertained to contain 66 of margarine to 100 of oleine in summer, and 186 of margarine to 100 of oleine in winter. In the first case, the cows are grazing on the mountains, (the Vosges ;) in the second they are eating dry fodder in the stall. I have besides had an opportunity to make a direct experiment upon this subject, which appears to me quite conclusive Having substituted for one half the allowance of hay an equivalen 424 FATTY ELEMENTS OF FOOD, AND ON FATTENING. quantity of rape-cake, still very rich in oil, the cows were kept in excellent condition ; but the butter was extremely soft, and had the taste of rape-seed oil to a degree that was perfectly intolerable. I do not know a single instance in any of the systems followed at Bechelbronn, in which a milch-cow does not receive in her ration a quantity of matter analogous to fat, superior to that which is con- tained in the milk she yields. Having upon a certain occasion put a cow exclusively upon beet, I anticipated an unfavorable effect on her milk ; and in fact a very sensible diminution in all its valuable ele- ments occurred, and the animal began to suffer. By simply adding a few pounds of straw which had been taken away, the milk resumed its standard quality. The two rations thus composed may be con- trasted under the two points of view of contents in fat and contents in organic matter. In the ration of beet and straw (beet 119 lbs., straw 7|lbs.) there were 140 dwts. 20 grs. of fatty matter ; in that composed exclusively of beet (132 lbs.) there were but 38 dwts. 14 grs. of fat. The ill effects of the beet- root ration could not be ascribed to deficiency of inorganic elements, for the phosphate of lime it contained amounted to 37 dwts. 7 grs. — amply sufficient for all the purposes of the economy. The information we have from M. Damoiseau, one of the most careful of the observers who have investigated the subject of the production of milk, confirms us in our views of the necessity of fatty matters in the daily ration of the milch-cQw. The following are the elements of three of the rations for a cow in M. Damoiseau's establishment. No. I. No. «. No. >. Beet, or mangel-wurzel. . 88 lbs. Carrots 74 lbs Potatoes 55 lbs. Bran 6.6 " 6.6 " 6.6 Pollard. 5J " 5.5 " 5.5 Lucern 6.6 " 6.6 " 6.6 Oat-straw 13.2 " 13.2 " 13.2 Salt 0.11 " 0.11 " 0.11 121.0 107.0 88.0 Maximum. Medium. Minimum. Quantity of milk yielded.. From 25 to 26 pts. 16 to 18 pts. 12^ pts. Let us now calculate the actual nutritive value of the different items in the above rations ; or, selecting one, let us take that with the beet for particular consideration, as among the most usual. 6.6 lbs. of bran and 5.5 lbs. of pollard at. .. . 5 per cent=0.60 of fatty matter 6.6 lbs. lucern 3 " =0.33 13.2 lbs. oat-straw 5 " =0.60 " 1.53 Whence it follows, that a cow here received upwards of 1| lbs. of matter of a fatty nature with her food — a quantity more than suf- ficient to produce not only 16 or 18, bu. the maximum quantity of 25 or 26 pints of milk, very rich in cream. Did the cow receive an additional 40 lbs. of beet-root, she would find something like 12 lbs. more of solid matter in this article, composed especially of sugar, which sne would burn to keep up her temperature, and nearly 25 4wt0. ol oily matter, which she would transfer to her milk, — to say FATTY ELEMENTS OF FOOD, AND ON FATTENING. 425 nothing of new azotized principles which would be converted into caseine. If we now, by an easy transition, pass to the phenomena of fatten- ing, we still find that the principles which have been laid down can be most satisfactorily applied. Setting out from the numbers ob- tained from the experiments of Mr. Riedesel, which, in many points, agree with all I have seen myself, we arrive at the following con- clusions. An ox weighing 1320 lbs. avoird. will keep up his weight upon about 22 lbs. of good hay per diem. Put up to fatten, the same ani- mal would require about twice this quantity, say 44 lbs., upon which he would gain at the rate of about 2 lbs. per day. Now, if we even take Mr. Riedesel's conclusions as a little too fa- vorable, as giving at least the maximum nutritive value to the hay and its equivalents, we may still admit, with him, that 22 lbs. of hay will produce about 17 pints of milk, or about 2 lbs. avoird. of flesh, con- taining 0.55 lbs., or rather more than | lb. of fat. Now, 22 lbs. of hay contain nearly 12 oz. 12 dwts. of principles soluble in ether, i. e. of fatty or waxy matter. The fatting ox, consequently, fixes a certain proportion of these principles in the same way as the cow. There is only this differ- ence, that the cow returns with the milk she yields a considerable quantity of the fat she finds in her food. There consequently exists an obvious relation between the formation of milk and fattening — a position which would gain support, did it require any, from a note which I owe to the politeness of M. Yvart, who, in summing up a long array of facts, concludes with these words : " The secretion of milk appears to alternate with that of fat. When a milch-cow fat- tens, she loses her milk ;" and the converse of the proposition is no less true ; when we would fatten a cow, we must let her go dry. The breeds of kine admitted to be the best milkers remain long lean after the calving. In some of the short-horned English breeds, the quantity of milk is often very considerable shortly after the calving ; but the animals are much disposed to get fat, and getting fat, the secretion of milk neither continues so long, nor is it so plen- tiful, as in some of the other less improved kinds. English hogs, which become much fatter than French hogs, appear not to be such good nurses. Now, if we admit that there is this intimate relation between the formation of milk and that of fat, we are obviously very near the admission, that articles of food containing fatty substances indispensable to the production of milk, are also indispensable to the production of animal fat. And, then, has it ever yet happened that animals have been fattened with food devoid of grease ? I have not, for my own part, met with a single fact which countenances such a proposition. I have referred to the distinguished agriculturist, who attempted to fatten pigs upon potatoes, but who only succeeded by adding a certain quantity of graves to the food — an article which, as every one knows, conf ains a considerable proportion of fat in its com- position. M. Payen has, in fine, made some experiments which appear alto 36* 426 FATTY ELEMENTS Cf FOOD, AND ON FATTENING. gether conclusive, and from which it follows, that two Hampshire hogs which, having consumed 66 lbs. of gluten, and upwards of 30| lbs. of starch, had only gained 17| lbs. ; while other two animals of the same breed, having been fed with 99 lbs. of the flesh of sheeps' heads, containing from 12 to 15 per cent, of fat, had gained 35 lbs. Yet, judging from elementary analysis, these two rations were almost identical ; they contained the same quantity of dry nutritious matter. The first ration contained 26.4 lbs. of dry gluten, and 30.4 lbs. of starch ; the second contained 20.9 lbs. of dry flesh, and 15.4 lbs. of fat. The quantities of carbon and azote were, therefore, a little higher in the vegetable than in the animal ration ; but they differed notably in this, that the latter contained an equivalent of fat for the equivalent of starch contained in the former. In a second experiment, four hogs, fed upon boiled potatoes, car- rots, and a little rye, gained 117.7 lbs. ; while other four animals, of the same age, and in the same conditions, but fed upon sheeps' heads, gained as many as 226.6 lbs. In the course of these experiments, M. Payen was struck with this circumstance, that the increase in weight of an animal that is fat- tening being represented by 50 per cent, of water, 33.3 of fat, and 16.6 of azotized matter, the conviction is forced upon us that he ac- tually fixes the greater proportion of the fat of his food in the cellu- lar tissue of his body. The first hogs, for example, had eaten 14.74 lbs. of fat, and had gained 11.44 lbs. in weight; the four last re- ferred to had had 18.48 of grease, and had increased 14.74 lbs. in weight. It has now been the practice for several years, in various places, to maintain hogs in considerable numbers upon muscular flesh, horse- flesh; and it has been ascertained that the article, if extremely lean, though it keeps the animals in good heart and condition, though they grow and thrive on it, yet they will not fatten. When they are to be got ready for the butcher, they must, in addition, be put upon a course that is known to be proper to fatten them. The scientific question of fattening having, of late years, attracted very general attention, the opinions which have now been announced have been very actively contested. Among other arguments, the general freedom from fat of the bodies of carnivorous animals, and the usual fat state of those of the herbivorous races, has been cited. Whales have even mistakenly been included in the list of fat vege- table feeders ; but it is known to all naturalists, that the great ma- jority of the whale tribes, the whole of those that inhabit the northern seas, are carnivorous. And, indeed, the mention of this fact leads me to revert to one of the most curious problems in the physics of the globe — that, to wit, presented by the vast amount of animal life amidst the waters of the ocean, and its support by a quantity of vegetables which to us appear altogether inadequate to such an end. The beautiful researches of M. Morren, however, seem calculated to throw some light on this interesting subject, — that inquirer having shown that certain animalcules possess the faculty of decomposing carbonic acid in the same way as vegetables ; and it is probably ia FATTY ELEMENTS OF FOOD, AND ON FATTENING. 427 virtue of this power that the enigma is to be explained, of the source whence the myriads that people the deep derive.their food. But is it absolutely true that herbivorous animals only abound in fat 1 Who has not seen fat dogs and cats ; and in the Cordilleras, where palm-trees abound, there is a particular species of bear, which lives in a great measure on the oily palm -nuts and young shoots of the palm-tree, which becomes remarkably fat, and proves a great attraction to the tigers of the country.* Before coming to a close with this discussion, I think it right to refer to the experiments of M. Magendie, who has so well establish- ed the fact, that the chyle of animals fed on fat food contains a large quantity of fat ; and that animals kept long on such food frequently become affected with what is called the fatty liver. f To sum up, then, experiment demonstrates that hay contains a larger quantity of fatty matter than the milk and excretions which it forms ; and that it is the same with all the other mixtures and varie- ties of food that are usually given to animals. That oil-cake increases the production of butter, and that, like maize, it owes the fattening properties it possesses to the large quantity of oil it contains. That there is the most perfect analogy between the production of milk and the fattening of animals ; that potatoes, beet, carrot, and turnip, only fatten when they are conjoined with substances that contain fatty matters, such as straw, corn, bran, and oil-cake of various kinds. That in equal weights, gluten mixed with starch, and flesh meat abounding in fat, have a fattening influence on the hog, which differs in the relation of 1 to 2. Lastly, that fat food — food which will aflford fat in the digestive canal — appears to be the indispensable condition of fattening. If it be necessary that the respiration be diminished or lessened in extent, this is only that the fatty substances taken into the stomach, and which have made their way into the blood, may not be oxidated, may not be burned ; not that their formation may be favored. All these facts are in such perfect harmony with the simple view of assumption and assimilation of fatty matters, that it is difficult to conceive on what foundation the opinion can repose which would have them composed out of their elements in the animal body. Nevertheless, 1 am myself the first to admit, that more extensive experience may had to the modification or even entire change of the opinion which I advocate. The facts on which that opinion is based, despite their number, are not probably yet sufficient to }on- Btitute a perfectly satisfactory or conclusive theory. New researches * These bears, evidently, cease to be carnivorous while they live on palm-nuts and leaves. For my own part, I do not thinli the point settled yet. The fatty matter of the generality of vegetables is w^ax rather than grease. And then some of the herbiv orous tribes seem never to get fat. — Eno. Ed. t I may here state the contrary fact, as announced to me by a physiological friena, In whose report I place great reliance, that the chyle of animals fed with substances that give mere traces ol waxy matter, contains fat or oil that can be collected in lar£4 irtfs—Eva Ed. 428 ECONOMY CF FARM ANIMALS. are, therefore, indispensable : it would be requisite to show, that a cow kept on a regimen abundant in point of quantity, but as poor as possible in matters analogous to fat, will continue to maintain her condition and yet yield milk abounding in cream ; and that it is really possible, as some persons affirm, to fatten animals rapidly on roots and tubers alone.* CHAPTER IX. OF THE ECONOMY OF THE ANIMALS ATTACHED TO A FARM OF STOCK IN GENERAL, AND ITS RELATIONS WITH THE PRODUCTION OF MANURE. Agricultural industry generally extends to the breeding and fat- tening of cattle ; the breeding, or at all events the maintenance, of horses ; the breeding and feeding of sheep and swine. The cir- cumstances, indeed, in which the tiller of the ground sees himself spared the necessity of attending to these matters, are rare excep- tions to the general rule, and in fact only occur where it is easy to obtain abundant supplies of manure from without, or in those few favored spots where the fertility of the soil is such that it continues to yield its increase without addition in the shape of manure. In the vicinity of great centres of population, where dung can be bought cheap, or of guano islands, where a cargo costs a trifle, and in some tropical countries, large farming establishments may be found to- tally without stock in the shape of sheep and horned cattle. But in a general way the agriculturist is obliged to give himself up to the care of flocks and herds of one description or another ; and, in fact, we now know that there is a certain and very indispensable relation to be maintained between the extent of surface under crop and the number of cattle to be provided for, variable as regards farms dif- ferently situated and circumstanced ; but invariable when circum- stances are the same, and the system of management pursued is similar in its principal features. The question as to whether the cultivation of grain or other use- ful plants, or the rearing of cattle, is more profitable, which is often agitated, must receive a diflferent solution in regard to each different locality. In one place it may be more advantageous to breed cattle or horses ; in another to rear or fatten them : here, the production of milk, butter, and cheese, may be the best husbandry ; there, the growth of hay, (as for miles round London on the north and west ;) and again, wheat and the other cereal grasses may be the staples ot * Whoever would tr>' experiments in this direction, must be careful to mix his food; one article alone never agrees. The Americans say, a pig will die upon ptmipkins and upon apples alone • but he will live and fatten on a mixture of the two. I have my- self seen scores of oxen fattened upon turnips, with a moderate allowance of straw or bog-hay ; and have seen pigs get into admirable condition for the butcher op itUe mort th%n potatoes.— Eno. £o. ECONOMY OF FARM ANIMALS. 429 prod iction. Even supposing that the growth of grain is that which is most advantageous on the whole, it by no means follows that the farmer shall give himself up to this exclusively ; it is seldom that he can do so, indeed ; he must have manure, and this entails the necessity of keeping cattle. If the latter, however, be the least profitable item in the economy of a particular domain, it will of course be kept within as narrow limits as possible. In many places where the land is well adapted to the plough, and where the production of grain is unquestionably profitable, stock ap- pears to offer few advantages ; it sometimes happens, indeed, that the balance as regards the stall and cow-house is on the wrong side for the farmer, when the actual value of the forage that has been con- sumed is taken into the account. The loss is only made up for by the manure, which is in fact the return. This is the view that M. Crud obviously takes when he speaks of the stock upon a farm as a neces- sary evil.* I am far from participating in his opinion ; the cattle upon a farm are no evil, though they may be very necessary. To be satisfied of this, it is enough, in fact, to recollect the principle which has been established in treating of rotation courses, viz : That in no case is it possible to export a larger quantity of organic matter, and particularly of organic azotized matter, from a farm, than is represented by the excess of the same description of matter contained in the manure consumed in the course of the rotation. By acting otherwise, the standard fertility of the soil would inevt tably be diminished. This principle recognised, and I believe that it cannot be disputed, it is obvious that a portion of the produce of the fields must be re- turned to them to fecundate them anew, and it is precisely this por- tion of the forage crops destined to furnish manure that must be consumed in the stable and cow-house. Reasoning abstractly, the forage plants which it is not intended should quit the farm, might be buried directly as manure, without being made to pass through the bodies of animals ; their fertilizing influence on the soil would come out sensibly the same ; and this is what is done, in fact, so often as we manure by smothering. But we have scarcely made the first step in the rudiments of agriculture before we discover the immense advantages of following the usual custom, which first employs as forage for cattle the crops that are grown with a view to the pro- duction of manure. And we shall by and by find, in fact, that by adding to that portion of these crops a supplement of forage plai ts which it would be legitimate to export, without trenching upon the fundamental principle above laid down, we obtain the same quantity of manure, and turn the whole of this supplement into useful forces, or into animal products which possess a market value greatly supe- rior to that of the forage before its assimilation. It is only the price of this portion of the forage, fixed or modified by the cattle on the farm, which can fairly be set down to the debit account of wool grown, of power created, and of flesh and dairy articles produced. * Thewet. and Pract. Economy of Agricul. vol. ii. p. 235, (in French.) 430 HORNED CATTLE. As to the forage plants which are immediately turned into manuie, it seems to me impossible to regard them as possessed of the proper market value ; the farmer could not have sold them at this. In my mode of looking at the thing, the cost of producing the forage crop, and the value that it actually has, constitute a circulating capital, the annual interest of which, estimated at a certain rate, expresses the true cost-price or value of the manure employed in the 3ourse of a rotation. In a word, in my eyes, the value of the manure which gives fertility to the soil is represented by the price of the labor, the rent charge, &c. — by the general outlay entailed by the growth of the forage from which it is obtained. I shall endeavor, by and by, to illustrate this topic by examples ; but in order thoroughly to understand this mode of estimating the price of manure, there are several elements wanting, which I pro- pose to assemble in this chapter- With this view, I shall first pre- sent the facts which I have been able to collect, or which I have myself had an opportunity of observing in reference to the economy of the domestic animals attached to a farm ; and I shall then make an attempt R) deduce the relation that exists between the consump- tion of forage and litter, animal reproduction and increase, and the formation of manure. ^ HORNED CATTLE. It were foreign to the purpose of this work, did I enter into the natural history of the animals that are usually attached to farming establishments ; neither will I pretend to discuss the relative merits of the different breeds of sheep and oxen, nor speak of the best methods of improving them. I confine myself to the varieties which I have on my own farm, or which I see on the farms of my neigh bors, and upon which I have opportunity of making daily observa- tions. It will be enough if I give a brief summary, in this place, of the general principles admitted by practical men of the highest name and authority upon these points.* Between the external forms of animals and the internal organs essential to life, there is the most obvious and intimate connection. A broad and deep chest is the sure indication of ample lungs and a good general constitution. The pelvis, or bony cincture formed by the rump and haunches, ought to be spacious in the females. A small head is generally the indication of a good kind. Horns in our domestic animals must be regarded as objectionable rather than use- ful ; and by adopting measures which tend to repress their growth, we undoubtedly favor both the prodiiction of flesh and wool. The strength of animals depends far more on the degree in which their muscular system is developed than on the mass of their bones ; it is, besides, flesh, not bone, that has value in the butcher's eyes ; so that the farmer's business is by all means to strive after a delicate but well-covered skeleton. Animals which have been indifferently * Cllne, in General Report of Scotland ; Communication to the Board of Agrlcul tore ; Bpencer on the choice of male animals for breeding from: Cully's Introduciioti, |(C., on live nUK^ kc. . -^ BREEDING. 431 fed while young, have often the bony system very disproportionately developed. Two modes are generally followed with a view to improving the external shape of domestic animals. One of these consists in only breeding from animals of the most faultless forms of the same race, and generally of close degrees of kindred ; another in crossing females with the males of a neighboring race, each possessing in the greatest degree the qualities which it is held desirable to trans- mit to the future race. The former of these plans is spoken of as the method of breeding in and in ; the second as the method hy crossing. Certain disadvantages have been stated as belonging to the sys- tem of breeding in, by the side of several unquestionable and more immediate advantages. While the race acquires small bones and shows a decided disposition to take on fat readily, it is said after several generations to lose in constitution, to become more subject to disease ; the cows to give less milk, and the males, in losing their characteristic masculine forms, to show themselves less fit for pro- pagation. The English breeders who take this view of the subject, are, therefore, in the habit of having recourse to males of the same race, but bred at a distance from themselves. I must for my own part say, that T have seen no reason to admit any ill effects from propagation continued in the same direct line. Our live-stock at Bechelbronn has not been otherwise renewed for a very long time, and without the race appearing to suffer in any way ; our bulk, on the contrary, have very much improved. Mr. Cline insists greatly on the selection of females not only of good shape, but so much above the mean height as to approach the standard of the males. When the bull is very much larger than the cow, the progeny is apt to fall off instead of improving ; the reason for which Mr. Cline finds in the large size of the foetus, the issue of a large male, which a small female can neither accommodate properly in her womb, send easily into the world, nor suckle duly when it is born. Whatever we think of this explanation, there can be no doubt of the propriety of giving the principle pointed at the most careful consideration in practice. Mr. Cline refers to the great improvement that has been effected in the breed of English horses mainly through crosses with small barbs and Arabian stallions ; the introduction of Flemish mares would upon the same principle have been another means of still further improving the race. The neg- lect of this principle, Mr Cline is of opinion, lies at the bottom of the numerous failures and disappointments that have been encoun- tered in attempts to improve the breed of horses. A striking illus- tration of it occurred some years back, when bay horses of great height were in particular request ; the Yorkshire breeders had their mares covered by the tallest stallions that could be found ; but they immediately found that the progeny was merely long-legged, that it was narrow-chested, and without either weight or bottom. Spencer acknowledges with breeders in general that the bodily »nd constitutional qualities are almost always those that preponder- 432 MANAGEMENT OF CATTLE. ated in ancestors, and that the qualities of the father predominate in the posterity, particularly as regards oxen and sheep. This point settled, the choice of a good male is evidently the first point of con- sequence in attempting to improve a breed. As it is not possible, however, to find either a bull, or a tup, or a stallion, quite perfect, the one must be chosen that is most free from defect, particularly the defect or defects which we have it in view to correct in our breeding animals, our cows, ewes, and mares. Certainly no reason- able breeder would bring together animals that presented similar de- ficiencies ; on the contrary, he will strive to have his female served by the male which shows all the qualities in the very highest degree that are most wanting in her. On the whole, the association of animals of the same race appears to me the best mode of continuing desirable qualities, especially when this is conjoined with ample sup- plies of good food to the young. The influence of feeding is im- mense ; in my own neighborhood I see that the progeny of the Bechelbronn bulls are often inferior both in stature and shape to those that are brought up in our own stables. Great size, however, is not always to be regarded as an improve- ment ; height is by no means a constant indication of vigor of con- stitution. Improvement in those particulars of form and stature which are ascertained to be best suited to the circumstances of the locality, the climate, the pasture, &c., are the points to be especially attended to. It is above all indispensable to breed animals of vigor- ous constitution : over-refinement of original races has often led to indiflferent conformation of body, and to undoubted delicacy of con- stitution, which has rendered the herd or the flock much more ob- noxious to attacks of epizootic diseases. The degree of refinement of an original stock is evidently con- nected with the quantity and quality of the forage of the district. In cold and mountainous districts, where the herbage is scanty, it is necessary to restrain the ambition of having highly-improved stock within considerably narrow limits ; in such circumstances, the grand aflfair is to have a hardy race, not over nice in its food, which, through a considerable portion of the year, consists of but coarse grass. The ox {bos taurus) has been reduced to domesticity from the remotest ages, and nothing but conjecture can be offered with regard to its original race. The animal accommodates himself with won- derful facility to the most opposite climatic circumstances ; he mul- tiplies with astonishing rapidity in the hottest regions of the tropics ; unknown at the period of the conquest, he has now overrun the steppes of the vast basins of the Oronoco and the Amazons ; and is met with in vast herds on the highest and coldest table-lands of the Andes, even up to the line of perpetual snow ; wherever there is food, he appears to thrive ; the extremes of temperature seem to have little or no influence upon him. The buffalo (the bos bubulus of naturalists) is the only other mem- ber of this family that has been domesticated. He is fond of warmth, and is supposed to have been introduced into Italy towards the sixth century, from Eastern Asia. The buffalo is also found in Hungary MANAGEMENT OP CATTLE. 433 and Greece ; and wherever he is met with, he is made serviceable as a beast of draught and burden, and as food. In breeding oxen, the great consideration is the bull. According to Thaer, the bull ought to have a short thick neck, the head short and small, the forehead broad and curled, the eyes black and spark- ling, the ears long and well placed, the chest broad and deep, the body long, the legs short and columnar in shape.* A well-made bull would serve seventy or eighty cows were the season spread equally over the whole year ; but as it is not so, Thaer thinks that twenty is as many as can properly be given to the same animal ; and this, in fact, is the number which we adopt at Bechelbronn. The cow gives more milk than any animal known. A great va- riety of external signs of a good milker have been particularized ; but it may be said that there is none infallible. In a general way, I think that race has much to do with the point ; the cow that is the offspring of a mother of a good kind, and a free milker, will herself be a good milker also. I will only a^ent to one-holf of the allow- ance of hay, in which proportion cows d<> very well upon raw potatoes. MILCH-KINE. 44& 6th EXPEKIMENT. 240 DAYS AFTER CALVING. The forage here consisted of the full allowance of hay, or 33 lbs. In the preceding experiment the milk, which had hitherto kept up to from about 9| to 10^ pints a day, fell suddenly to little more than 8 J pints. To ascertain whether the fall was owing to the potato regimen or not, the cow was returned to the ration of hay, mider which in the Ist experiment the daily average of milk was 9.3 pints. In the course of thirty days 188 pints of milk were collected, at the rate of 6.2 pints per day. The declension in the quantity secreted consequently cannot be ascribed to the potatoes which were given in the fourth experiment. 6th EXPERIMENT. 270 DAYS AFTEB CALVING. The ration here was raw potatoes, with salt and straw — the ration of the fourth experiment, with the addition of about 2^ oz. of salt. The animal ate this salted ration with appetite ; she also made away with the whole of the chopped straw, and it agreed well with her ; nevertheless, the milk continued to decrease in quantity ; it had failed oflf to 5.9, say 6 pints a day. 7th EXPERIMENT. 290 DAYS AFTER CALVING. In this trial the ration consisted of Jerusalem potatoes equivalent to 33 lbs. of hay, under which the milk may be said to have remain- ed stationary, though it was above rather than under the 6 pints per diem as in the 6th experiment. In composition it was as follows : Caseum 8.3 ) fuTofn„ii-.:-.-.v.v.v.".v..::;: ti sond.m Ashof Caseum 0.2 j Water 8T.5 100.0 The quantity of the milk had obviously decreased from the first down to the two last experiments ; but its chemical constitution does not appear to have varied during the entire course of the trials ; the varied regimen has had no influence on the proportions in which its several ingredients are encountered. But there was still one point to be ascertained, viz. : whether the milk secreted very shortly after the delivery differed from that which was formed at a period remote from that epoch. 8th EXPERIMENT. A cow which had calved twenty-four dajrs before, and, upon a mixed regimen of hay and green clover, was giving at the rate of 18.6 pints of milk a day, was brought under observation. Analysis showed this milk to consist of : Caseum 8.0) ^^o,-;^:::::::::::::::::: II ^"^^^ Ash of caseum 0.2 j Water 88.8 100.0 38* 450 MILCH-KINE. 9th EXPERIMENT. 35 DAYS AFTER CALVING. The same cow, upon green clover, was now producmg 21.2 pints of milk a-day, and of the following composition : Caseum 8.1 \ L-^r lb8.-Hay 16*lb» Oata. IT —Ditto 26 Total allowsn/vo . . 42# 39* 462 THE HORSE. Until very lately (previoDsly to 1840) the allowance of troop horses in the French army consisted for the reserve cavalry of : Hay nibs. —Hay 11 lbs. Oats 8 =- Ditto 12 Straw. 11 =-Ditto 2^ Total allowance 26* For the cavalry of the line : Hay 8.8 lbs. -= Hay 8.8 lbs. Oats 7.6 =- Ditto 11.5 Straw 11 =Ditto 2.T Total allowance 28.0 For the light cavalry : Hay 8.81b8.-=Hay 8.8 lbs. OatB 6.6 — Ditto 10.1 Straw 11 =Ditto 2.7 Total allowance. 21'6 Influenced by the consideration of the frequent indifferent quality of hay, and its injurious effect upon the health of the horse, it was decided in 1841 to replace a portion of the hay ration by a larger quantity of oats, an article much less liable to be adulterated, or to be indifferent in quality. The allowance now consisted for the re- serve cavalry of: lbs. lbs. Hay 1.8 =" Hay 8.8 Oats. 9.2= Ditto 14.2 Straw 11 =Ditto 2.7 Total allowance 25.7 For the cavalry of the line : lbs. lbs. Hay 6.6 —Hay 6.6 Oats 8.8— Ditto 18.5 Straw 11 —Ditto 2.7 Total allowance 22.8 For the light cavalry : lbs. lbs. Hay 6.6— Hay , 6.« Oats 8.8— Ditto 12.8 Straw 11 —Ditto 2.7 Total allowance 22.1 From what precedes, it appears that the substitution of oats for hay was made upon a calculation which squares well with the theo- retical inferences in regard to the relative nutritive powers of these two articles. The allowance to the horse ought to be distributed into three por- tions, constituting as many meals, and put before him in the morning before going to work, in the middle of the day, and in the evening ; he is generally watered at meal times. It is also highly advantage- ous to the health of the horse that he be made to work with a cer- tain regularity. Our horses at Bechelbronn, upon an allowance equivalent to 33 lbs. of hay, work from 8 to 10 hours a day, having an hour's rest at midday. THE nORSE. 4t)3 There is, of course, a certain relation between the height or, if you will, the weight of the horse, and the quantity of provender he requires. Some attention, as we have seen, has been given to this point, in connection with horned cattle ; but with reference to the horse I know of no data but such as I myself possess. Seventeen horses and mares, aged from 5 to 12 years, and having each proven- der equivalent to 33 lbs. of meadow hay, weighed together 18,190 lbs. The mean weight of each horse being represented by the num- ber 1070 lbs., we perceive that for every 100 lbs. of live weight 6.7 lbs. of meadow-hay are required for the daily ration, the horses working from 8 to 10 hours a day. This relation differs very little from that which we have obtained in reference to cattle. I was anxious to ascertain the rate of growth of the horse ; and in connection with our breed, which have a mean weight of about 1100 lbs., I found that the foals weighed as follows : d a a ^ S H 1 a ,0 bo Vi-O \fA || Names. ^ "S ■s ^ ^ a 11 •s=s fl o 2 E3 S+* s s 1 I § ^ Increa during Increa P 1 1 lbs. lh8. T lbs. lbs. Filly of Chevreuil 25 May, 1842 1 110 20 Aug. 1842 294.8 184.8 2.1 Filly of Hechler 12 June, 1842: 113 7 Sept. 1842 286. 87 172. 1.9 Filly of Brunette. 12 June, 1842: 113 7 Sept. 1842 854. 87 241. 2.7 The mean increase per day during the period of suckling in thtj three cases quoted above, therefore, appears to have been rather more than 2 and /oths lbs. avoirdupois. Immediately after weaning, young horses appear to experience an arrest of their growth for some short time, an event which indeed happens to animals generally. I found, for example that Chevreuil's filly, which on the day of weaning weighed 294 lbs., nine days after- wards weighed but 288 lbs., and had consequently lost 6 lbs. I shall add a few weighings of horses further advanced in age, although still young : Alexander, a colt, weighed at birth 110 lbs. : at the age of 128 days, 337 lbs. ; increase 227 lbs., or about 1.8 per diem : 51 days afterwards, 490 lbs. ; increase 105 lbs., or per day 1.4 lb. Finette, a filly, weighed, when weaned at the age of 86 days, 295 lbs. ; 83 days afterwards, 396 lbs. : increase 101 lbs. ; per day, 1.1 lb. Hechler's filly weighed when weaned at the age of 87 days, 286 lbs. ; 65 days afterwards, 358 lbs. ; increase 72 lbs. or per day 1 J lb. From what precedes we may conclude : *38 464 THE HOG. 1st. That foals, the issue of mares weighing from 960 to 1100 lbs., weigh at birth about 112 lbs. 2d. That during suckling for three months, the weight increases in the relation of 278 to 100, and that the increase corresponds very nearly to 2 and j\ lbs. avoirdupois for each individual per diem. 3d. That the increase of weight per diem of foals from the end of the first to the end of the second year, is about 1 j\ lbs. avoirdu- pois ; and that towards the third year, the increase per day falls something under 1 lb. avoirdupois. After three years complete, the period at which the horse has very nearly attained his growth and development, any increase becomes less and less perceptible. These conclusions in regard to the horse, differ very little from those which I have had occasion to draw in connection with horned cattle. I have also made a few experiments with reference to the quantity of provender consumed by foals in full growth, and have found that Alexander, Finette, and Hechler's filly, weighing together 1106 lbs., consume per day : Hay 19.8— Hay 19.8 Oats T =Ditto....; 11 Total allowance 80.8 Per head 10.22 The mean weight of these foals was 368.6 lbs., so that the hay consumed for every hundred pounds of live weight was 2.85 lbs., with which allowance the daily increase amounted to about 1.2 lb. Consequently, a mixed provender, equivalent to 100 lbs. of hay, had produced 12 lbs. of live weight. I must confess that this result appears to be somewhat too favorable, but I can only set down the numbers as they presented themselves to me. The flesh of the horse is not generally used, or at least openly used, as food for man, though there are countries in which it is ex- posed for sale and commonly eaten. At Paris, indeed, in times of scarcity, horse-flesh has been consumed in quantity. During the Revolution, a knacker exposed publicly for sale, in the Place de Greve, joints from the horses which he had killed, and the sale con- tinued for three years without any ill efi*ect ; in 1811, a scarcity obliged the Parisians to have recourse to the same kind of food, and it is said, indeed, that the traffic in horse-flesh as an article of human sustenance is still continued to a very considerable extent in the French metropolis ; at the present moment, a distinguished writer on Medical Police, M. Parent-Duchatelet, has even proposed to legalize the sale of horse-flesh as food for man. There is perhaps no farming establishment which does not keep a certain number of hogs, a measure by which ofial of all kinds that would jjo directly to the dunghill, is turned to the very best account. The dairy, the kitchen-garden, and the kitchen, all yield their con- tingent of food to the pig-stye, which is moreover an excellent nuians of using up certain portions of the harvest But the rearing THE HOG. 465 and fattening of hogs, although frequently looked upon as mattrra of course, and requiring very little care, do in fact demand consider- able attention and certain conveniences in situation. The rearing of hogs, in a general way, may be said to suit the small farmer better than the great agriculturist. Our common domestic hog appears to derive his origin from the common wild hog of Europe. The breeds are extremely numerous. The black hog, covered with rather fine hair, and commonly found in Spain, is a native of Africa. This is the race which has been carried to South America, where it has multiplied in a truly surpris- ing manner. It grows rapidly ; and if it has little to recommend it with reference to fattening, it is nowise nice in the matter of food and general entertainment ; the flesh is excellent when the animal has been kept upon the banana, and fattened off upon Indian corn. The hogs of the east of Europe are remarkable for their size ; they are of a deep gray color, and have very long ears ; they are not very prolific, the brood swine having rarely more than four or five at a birth. The Westphalian breed, on the contrary, though they resemble the last; are highly prolific, the litter generally con- sisting of from ten to twelve. In Bavaria the hogs are remarkable for the smallness of their bones, and the readiness with which they take on fat. Lastly, the Chinese race, which is common in England, and begins to extend on the continent, differs from those hitherto known, in having the back straight or even hollow, and the belly large. This breed is also remarkable for its quietness ; the pork which it yields is of the very best quality. One of the great advantages connected with the hog being its extreme fecundity, it is important to have a breed which is distin- guished in this respect. There are some brood swine which have regularly borne ten or fifteen, and even eighteen pigs at a litter ; a more general number is eight or nine. According to Thaer, the hog that is disposed to take on fat is distinguished by length of body, long ears and a pendulous belly. The hog attains his growth, at the end of about a year, until which time the female ought not to be put to the boar. One boar generally suffices for about ten females. The hog, 'as all the world knows, is an animal the least dainty in his food ; he is omnivorous, nothing comes amiss to him ; but his food is by no means matter of indifference when the quality of the flesh comes to be considered. Thaer seems to think that maize is of all articles that which is the best for feeding swine ; and I have had occasion to verify the accuracy of his conclusion in South America, where I may add it is found that the oily fruit of the palm- tree contributes powerfully to the fattening. Husbandry, in regard to the hog, comprises two distinct periods : the growth of the animal, and his fattenmg. It is generally admit- ted that it is most advantageous not to fatten swine for the butcher until they have completed or nearly completed their growth. A hog which has been well kept from the period of its birth, may be put up to fatten at the age of about a year. The female shows signs 466 THE HOG. of heat at the age of about five or six: months, and goes with young on an average 115 days, and will produce regularly two litters per annum ; when particularly well kept, she may have three litters in the course of from thirteen to fourteen months. The hogs which are destined to be fattened for the knife are ge- nerally cut at the age of six weeks, particularly if they are to be put up to fatten at the age of nine or ten months, as is often done. Almost all the varieties of roots and grain produced upon the farm are suitable for the maintenance of the hog ; but in Alsace, and I believe generally, the staple is the steamed potato, with which are associated various articles in smaller quantity, such as peas, aod barley and rye meal, &c. The farrow sow ought to have food by so much the more abun- dant and nutritious as she is required to suckle a larger number of pigs. Our allowance at Bechelbronn to the hog with five young ones during the six weeks of suckling is as follows : lbs. lbs. Steamed potatoes 24.75 «= hay 7.8 Evemeal 2.46=- " 40 Skim milk 13.2=- " 6.2 Total allowance 18.0 After the fifth week, when the animal is no longer giving suck, tlie ration consists of: lbs. lbs. Steamed potatoes 12.1 — = hay 7-8 llye tnea! 1.0— " 1.6 Skim milk [sour] 6.5— " 8.8 Total Allowance 12.2 This allowance is gradually reduced to the end of the second mouth after the farrowing, when the animal is upon the maintenance ration of the farm, consisting of : lbs. lbs. Steamed potatoes 16.5— hay 5.2 The potatoes are mixed with dish washings, which certainly con- tribute to improve their nutritive power, although I am altogether at a loss to estimate the value of the article. The young pigs begin to taste the food given to the mother at the age of about a fortnight, but they never take to this kind of food freely until they are four or five weeks old and are weaned ; up to this time they have an allowance of skim milk and whey. To five pigs at the time of weaning we allowed per day : lbs. steamed potatoes 22.0-= bay 7.8 per head 1.4 Eyemeal 1.0—" 1.6 " 0.88 Sklmmilk 6.0— " 2.8 " 0.67 29.6 "llJ This allowance was modified by degrees ; the quantities of milk and rye meal were gradually abridged, and the proportion of pota- toes increased, so that about the third month the allowance per head was from 11 to 13 lbs. of potatoes mixed with greasy water. This THE HOG. 467 is the reg-imen, equivalent to about 5 lbs. of hay, upon which our store pigs are maintained until they ate put up to fatten. During tiie three months which follow the weaning, therefore, we may reckon that each animal has consumed 3.8 lbs. of meadow-hay per day, and that from the third month the consumption may be repre- sented by 5.2 lbs. of the same article. We have attempted in vain to replace the potato by rape or madia oil-cake ; the pigs refused it obstinately ; but they showed no objec- tion to poppy seed, walnut and linseed eake ; during the season they will also eat clover, and are partly maintained- upon this plant. In summer they are put entirely upon green meat, animals from five to six months old consuming about 19 lbs. of clover a day, a quantity which represents very nearly 5 lbs. of clover hay. The hog may be fattened at any age ; but as we have already said, it is not generally advisable to fatten before he is ten months or a year, some say fifteen months or a year and a half old, at which period the animal is undoubtedly in flesh and at its full growth. The other extreme limit appears to be about five years ; but it is only a brood sow that is ever kept to five years of age. It is generally allowed that twelve weeks are required to bring a hog into prime con- dition, when he ought to have a layer of fat under the skin upwards of an inch in thickness. Sixteen weeks may be required to obtain an animal really fat ; and twenty weeks to have him at the highest point that is attainable. The hog requires to be fed regularly. After weaning, pigs should have five or six meals in the course of the day ; the number of meals is diminished gradually, and towards the end of two months they amount to but three in all. I was curious to ascertain the weight of the pigs at the moment of their birth, so as to determine their rate of increase during the period of suckling. On the 5th of September a sow farrowed a litter of five. lbs No. 1 weighed.... 2.205 No. 2 " ....8.025 No. 8 " ....2.476 No. 4 " ....2.750 No. 5 " ....8.800 Weight of the litter 13.756 Average weight per head 2.761 On the 11th of October the weight of the litter was 86.6 lbs., or 17.3 lbs. per head ; increase in thirty-six days, 73.2 lbs. ; per head, 14.6 lbs. : per day, 0.409 lbs. On the 15th of November the weight was 177 lbs. : increase in thirty-five days, 90.2 lbs. : per head, 18 lbs. ; per day, 0.506. During the thirty-six days of suckling, con- sequently, 100 of live weight at birth had become 632. In another instance, I found that eight pigs which at the time of weaning weighed 114 lbs. or 14.3 lbs. per head, at a year old weighed 1320 lbs., or 165 lbs. per head : increase in eleven months 1206 lbs., or 150 lbs. per head. The increase per diem since the weaning had been 0.4. — not quite 468 THE noG. half a pound ; and as the food consumed may be represented by 5.2 lbs. of hay per day and per head, it will follow that 100 of forage had produced 8.58 of live weight. This ratio is too high, however : for these pigs besides the regular allowance had whey and various scraps of which no account was kept ; and we know that whey alone contains a considerable quantity of the representatives both of flesh and fat. Baxter came to some interesting conclusions on the growth and fattening of young hogs. Four animals each of the age of nine months weighed at the beginning of the experiment 458.2 lbs. ; twenty-one days afterwards, 620.8 lbs. : increase of weight 162.6 lbs., to obtain which there were consumed : lbs. lbs. Barley 151 equivalent to hay, 250 Beans 140.8 " 611 Maltgrains 440 « 26T 1229 So that a quantity of nutritive matter represented by 100 lbs. of hay produced 13.21 lbs. of live weight. Assuming the weight of each pig of nine months old before her fatting to have been 29 lbs., the increase per head was 40.6 lbs. in the course of twenty-one days, or at the rate of 1.9 lbs. each. Bax- ter reckoned the carcass weight, sinking ofiFal, at 7.4 per cent. One of the pigs between nine and ten months old weighing 159.5 lbs., at the end of twenty days weighed 198.8 lbs. : increase in twenty days, 39.3 lbs. ; increase per day, 1.9 lbs. During these twenty days, the animal had consumed 188 lbs. of barley, equivalent to 314 lbs. of hay. The increase would consequently give for every 100 lbs. of hay consumed an increase of live weight of 12.52, say 12^ lbs. Arthur Young, by keeping pigs of a year old on peas-meal, obtain- ed the following results. No. 1 weighed 99.0 : 85 days afterwards, 167.5 : gain 58 J5 : per day l.fr2 No. 2 " 91.7; 42 " 145.4; 68.7; " 1.876 No. 8 " 86.6; 63 " 189.4; 62.8; •' 0.886 I shall here give two series of observations made at Bechelbronn on the fattening of hogs. September 6th, 1841, seven hogs, aged fifteen months each, already in good condition, were put up to fatten. They had hitherto had the usual hog's food — sour milk and boiled potatoes after weaning , by and by from 11 to 15 lbs. of potatoes, whey, and dish washings. The seven porkers weighed 1691.8 lbs. ; or 241.67 lbs. each. The increase had been at the rate of 0.528, rather better than half a pound per day and per head, supposing them to have weighed 13.7 lbs. each, at the time of weaning. After fattening, 20th December, the 7 swine weighed 2101.0 Before " 6th September " 169.8 Increase In 104 days. 4''9.2 lbs. ; or fcr head . . . 68.8 Increase per day and per head 0.073 THE HOa. 4<59 In the course of the 104 days, there were consumed : lbs. Barley 772 Peas.. 1042.8 Potatoes. 9504 lbs. equivalent to hay 1144 4171 " 8296 Greasy water and whey — quantity not determined • • 8833.6 So that with the provender equivalent to 100 lbs. of hay, 4.91 lbs. ol live weight had been produced. These seven porkers, slaughtered, yielded : Hogs. Weight alive. "Weight after bleeding. Weight of the blood. Weight of the porkers without heads or feet. \ Weight of heads and Oflfal. 1 2 8 4 5 6 7 lbs. 323.0 259.0 283.0 316.0 264 259.6 393.8 lbs. 312 248 272 306 257.4 250.8 876.2 lbs. 11 11 11 11 6.6 8.8 17.6 lbs. 268.0 208.4 208.2 263.2 220.0 213.4 821.2 lbs. 44.0 39 6 63-8 41.8 37-4 37.4 65.0 2098.6 " 1702.6 " It must be admitted that these animals had increased both in flesh and in fat ; but in spite of this, the experiment appears to be un- favorable to the opinion that fat in animals is the efiect of direct as- similation of the substance. The whole increase in weight of the seven porkers had been 409.2 lbs. ; supposing 27 per cent, of fat in this increase, its amount must have been 110.4 lbs. in all ; but the food consumed did not contain more than 57.4 lbs. It would there- fore be necessary to admit that the food which had not been taken into the account had contained as many as 53.0 lbs. of fatty matter, which I own does not appear to me probable. But no definitive conclusion can be drawn from the circumstance, owing to the actual state of fatness of the animals, when they were specially put up to fatten, not having been ascertained ; perhaps the absolute quantity of fat already accumulated is greater at this time than is generally supposed. I find, for instance, that a young porker of 196.9 lbs., killed at the time when he might have been put up to fatten specially, yielded as many as 25.3 per cent, of fat. The following are the data afforded by the fattening of the farm porkers for 1842 : Nine porkers, from thirteen to fifteen months old, and already in good condition, were put upon the full fatting allowance on the 1st of October, on which day they weighed : lbs. 1940 November 28th, after having been bled, they weighed. . .2807.8 Increase In 58 days per head and per day. 40 470 THE HOG. In the course of fifty-eight days the hogs had consumed : lbs. lbs. Eye. 770 equivalent to hay 1141.8 Peas 1802 " 6209 Potatoes 4796 " 1861 Greasy water and whey undetermined 8221.8 The nine animals gave 1746.8 lbs. of meat, fat and lean, or 75.'3 per cent, of their weight as they stood alive ; besides which, 141.9 say 142 lbs. of lard were obtained from the internal parts. No\n supposing that in the increase of weight obtained in the course o: fifty-eight days, the fat were to be represented by 29 per cent., the fat fixed would amount to 100.1 lbs. ; while the whole of the fatt} substances contained in the food consumed would not amount to mon than 59.6 lbs. It would therefore be imperative to us, did we main tain that all the fat was obtained ready formed from without, to sup pose that the whey and dish washings administered in indeterminate quantity, had introduced 40.5 lbs. of fat into the bodies of the animals Some experiments which are going on at Bechelbronn at this mo ment will, I trust, settle the question definitively as to whether during the fatting of hogs and other animals there is any formation of fat a the cost of the starch and sugar of the food. The observations which I have .made on the fattening of hogs ma] be summed up in these terms : 2 b ^ 1i S"^ fe -§^1 §ag 11 I' 5 Iff <3"S Duration of the experi- ment lbs. lbs. lbs. Months. Months. Days. 5.1 0.440 8.58 1 11 18^ 0.836 18.21 9 u 21 15.7 1.958 12.52 9* t« 20 u 1.254 " 12 t4 « 11.6 0.572 4.91 15 (( 104 15.4 0.660 4.21 14 " 68 The allowance to the hogs in the preceding observations was al ways abundant. To determine the quantity of potatoes consume( each day by a hog in full growth, and whose weight was known, had him weighed at intervals, as well as the potato ration, place* before him at will, which he ate daily, and found that when h weighed : Ter 100 of th« Iba. lbs. Iba, liv 188 he ate 11 equiv.alent in hay to 8.4 145 160.5 184.8 18.2 15.4 17.6 4.' 4.8 6.6 2.52 30.1 8.02 THE HOG. 471 To these observations on the keep and fatting of horned cattle, horses, and hogs, I would gladly have added remarks of like extent on the growth and fattening of sheep ; unfortunately, I have only been able to obtain very imperfect niformation on this branch of rural economy. I have, however, sought to ascertain approximately the relations which exist between the weight of a young animal, the food consumed, and the increase in live weight, by means of the fol- lowing experiment : Two sheep six months old weighed together 184.2 lbs. Sixteen days afterwards they weighed 151.8 Total increase 1T.6 Increase per day, per head 0.55 In the sixteen days the two sheep ate : Hay 22.0 = Hay 22.0 Potatoes 53.3 —Hay 16.9 88.9 Or per head in hay 19.45 Or per head per day 1.21 ^ This would give us about 2.9 of hay provender per cent, of the Kve weight, so that a ration which should be represented by 100 of hay would be followed by an increase on the weight of a sheep of six months old of 27.7 per cent. ^ Vr. OF THE PRODUCTION OF MANURE. The forage consumed on the farm being the source of the manure produced there, it would seem that it must be easy to calculate the value of all that comes from the stables and cow-houses day after day. I do not mean the mass or weight of the dejections here, for it is certain that the more or less watery nature of the food mate- rially influesces the weight of the dung produced ; and if a common mode of calculating the quantity of dung by merely multiplying the weight of food consumed by three be correct in some cases, it is very far from the truth in others. The dung produced on the farm must be calculated on different gTOunds from this ; and without pre- tending to any degree of accuracy which is really unattainable, it is still very possible to get at the quantity of azote which is contained in the litter and in the dejections, so as to be able to refer to a stand- ard the quantity of manure made. Were not the azotized principles of the food partly exhaled by animals, the whole quantity not appearing in the excretions, it is ob- vious that it would suffice to have ascertained the quantity of azote contained in the food, to be in a condition to decide on that con- tained in the dung added to the litter. But this cannot be done ; to be convinced of the fact, it is enough to take the least complex case, that of a full-grown horse, receiving as his allowance per day : Hay 22 lbs, containing 1775.8 grains of azote. Oats 11 " 1389.4 " Straw 11 " 808.T " Litter..... 8.8 " 108.0 ♦* Azote.... 8581.4 :: ' 4T2 THE HOG. Now assumiDg 2 per cent, as the contents in azote of dry farm- yard dung, we see that the food consumed by the horse, speaking theoretically, might or should form 25.5 lbs. of dry manure. But we have seen that a horse or cow will exhale from 355.0 to 41 6.8 grs. of azote, which is all derived from the food, and is consequ ntly lost to the dung-heap. Now 3859 grs. of azote represent 2.75 lbs. of dry manure ; so that the dry dung produced by the horse kept in the stable, will be reduced from 25.5 lbs. to 23.1 lbs. In the course of a year, upon this calculation, the azote exhaled will diminish the weight of dry dung produced by one horse by a quantity equal to 1045 lbs. The azote of the food of a cow is still more considerable in quan- tity, and the loss to the dunghill proportionally larger ; inasmuch as to the amount she exhales, must be added all that goes to constitute the milk she gives. Practical men, without pretending to get at the cause of the thing, have long been aware of the fact, that a cow produces less dung than a horse ; and the truth of this is readily demonstrated on scientific grounds. Suppose a cow, consuming the equivalent of 33 lbs. of hay, and giving about 17 pints of milk per day: 33 lbs. of hay contain 2670 grs. of aiote, 44 " straw for litter contain. 128 " Azote 2793 — 19.8 lbs. of dung supposed to be dry. But in the 24 hours, there have been of Azote exhaled ... 8S5.9 grains, and of Azote in 17 pints, or 22.7 lbs of milk carried ofl^ 802.7 grains. 1188.6 — S 8 of dry dung: The 33 lbs. of hay digested by the cow, consequently, the litter added, have only produced 8.8 of dry dung. The azote of the food, of which we find no account in the dejections, amounts per annum to nearly 30 cwts., (3300 lbs.,) the deficiency in the case of the horse amounting to no more than 1045 lbs., (9 cwts. 1 qr. 9 lbs.) The estimation of the dung produced by growing animals, pre- sents several special difficulties, inasmuch as, besides the azote exhaled from the lungs, there is the quantity that is fixed in the liv- ing body. In one of the experiments which I have related, it appears that a calf six months old, consuming : Hay 9.6 lbs. containing 10C9.S azote. Discharged by its dejections 88S.8 " Azote fixed or exhaled in 24 hours 281.5 " The azote lost to the manure by the fixing of azote is therefore very considerable, in the case of young animals as well as of milch- kine. We find, for example, that for every 100 lbs. weight of hay consumed : A horse supplies the equivalent of 61 lbs. of dry standard dung^ A milch-cow 82 " " A calf of six months ...40 « •* THE HOG. 4*73 To estimate with any rigoi* the quantity of azotized manure which ought to result from the forage consumed on the farm, it were ne- cessary to know the proportion of azote contained in the bodies of all the animals entertained upon it. Having the increase of weight that occurred in the stable, cow-house, pig-stye, and poultry-yard, we should then be in a condition to Know the precise quantity of dung wiiich it would be necessary to retrench from that which the forage ought to have produced, had there been no production of animal matter, had the whole of the azote of the food passed through the live-stock to the dung-hill. Unfortunately, we have no very precise data by which we might calculate the quantity of azote contained in a living animal. I shall, nevertheless, endeavor to apply such as we possess. From a few practical experiments, and the information at my command, I admit that the following substances in their usual state contain per cent. : Moisture. Dry matter. Salts. Azote. Beef-flesh 77 28 1.0 8.5 Veal " Blood 80 20 0.9 8.0 Skin 60 40 1.0 7.2 Hair 9 81 2.0 13.8 Horn 9 91 0.7 14.4 Beef bones (tibia) 80 70 " An entire skeleton 86 64 85.0 5.2 Brain, intestines, &c 81 10 1.0 2.9 Fat freed from skin 20 80 " 1-9 These data applied to the various parts which enter into the constitution of the animals which up to this point have engaged our attention, we should have for the quantity of azote per cent. contained : In homed cattle 8.47 In the horse 8.64 Inthehog 8.80 In the sheep 8.66 Average 8.64 For every 100 lbs. of live weight produced on the farm, conse- quently, we may, without probably being a great way from the truth, presume that there has been 3.6 of azote fixed, azote obtained from the forage, and which, consequently, cannot go to the dung heap ; in other words, every 100 lbs. of live weight produced, deprive the establishment of 180 lbs. of dry standard dung, or nearly 18 cwts. of moist farm-yard dung.* We may be allowed, therefore, to entertain the hope that we shall one day be able, from the quantity of forage consumed upon a farm, to calculate the actual quantity of manure which we shall have at our disposal. To arrive at this result, it would indeed only be ne- cessary to subtract the manure represented by the azote exhaled from and fixed in the bodies of the stock, from the amount of azo- • The discussion will undoubtedly extend by and by to phosphoric acid. I shall only say at this time, that from the results obtained in the case of a pig, tlie phos- phoric add appears to bo in tho proportion of from 2 to 3 per cent, of the live weight 40* 474 THE HOG. tized manure represented by the whole quantity of forage, were it to be used immediately. To obtain results of any accuracy, how ever, it were necessary to possess data both more numerous and more precise than any we have at present. This perfection of co- efficients must be viewed as an affair for the future ; agricultura science has almost every thing to create. In estimating the quantity of manure from the forage consumed, it has been supposed that there is no loss. With reference to the stall or cow-house, a careful husbandman may approach this perfec- tion, by doing almost the contrary of all that is usually done now-a- days ; i. e. by taking every precaution against waste ; but it is obvi- ous that in so far as the stable is concerned, there must always be a considerable and inevitable loss ; all that falls upon • highways and byways is irretrievably gone. It is, indeed, matter of ordinary cal- culation that in consequence of their work out of doors, the horses upon a farm do not afford more than about two thirds of the dung which ought to be obtained from the provender consumed. Some experiments made in the stables at Bechelbronn show that the loss in this way may amount to one quarter of the whole amount of dejections ; still, as the animals are for the major part engaged on the land of the farm, it is obvious that what falls there is by no means lost. To supply my reader with definite sums from a partic- ular instance, upon which he may fix his mind, I shall state for his information that in the course of 1840-41,* my stock at Bechelbronn, consisting of sixteen head of cattle, eleven calves, twenty-seven horses, and (?) hogs, consumed 333,579 lbs. or 148 tons, 18 cwts. 1 qr. 15 lbs. of forage, containing 6925 lbs. of azote, and produced upon their original weight 20,821 lbs. of flesh, fat and milk, contain- ing with the addition of a calculated quantity for loss from out of door droppings, exhalation by the lungs, &c., 2631 lbs. of azote. The forage and litter, from their contents in azote, ought to have produced about 15,356 cwt. of moist farm-yard dung; they, however, produced no more than 9522 cwt. ; and, in fact, we see that there had been a consumption of azote by arrest within the bodies of the stock, by exhalation from their lungs, and by loss, amounting to 2631 lbs. ; by an equivalent quantity of dung, therefore, had the absolute produce necessarily been diminished. Thaer allows that articles of dry forage and litter double their weight in becoming converted into dung. The statement which I have just made agrees on the whole pretty well with this estimate. In our cow-house ration, one half only is generally hay, the other half consists of roots and tubers. The dry forage and litter conse- quently amount to 4G60 cwt. which according to Thaer ought to become changed into 9320 cwt. of dung, a number not very wide of that to which we have come. Sinclair reckons the dung of the cow- house at four times the weight of the litter, a view which neither accords with Thaer's estimate nor with our experience. I think it altogether unnecessary to insist on the importance tt * Twelve months I presume.— Ekg. Ed. METEOROLOGY. ^TEMPERATURE 415 the farmer of a foreknowledge of the quantity of manure which he may reasonable calculate on obtaining from a known weight of forage consumed upon his premises. Of the various methods proposed foi arriving at this information, that which I have employed, and which is based on ascertaining the amount of azote, appears to me the best calculated to supply satisfactory results, particularly when experience shall have corrected or confirmed the numbers which I have adopted as the elements of my calculations. I have already said that any supplementary forage, or forage added to that which is indispensable to the production of manure, generally acquires, by the fact of its conversion into power or into exportable substances, a value superior to that which it could have had of itself in the market place. This additional forage is that fraction of the provender, the azote of which figures in the statements that have just been made as azote exhaled or assimilated and fixed. We find, in fact, in representing this forage which is lost to the dung-heap, but gained to power and exportable articles, that in the stall, 100 lbs. of hay yield 8.6 lbs. of live weight, and 40.8 lbs. of milk, and that in the hog-stye, 100 lbs. of hay yield 21 of living weight. In the stable, again, the azote fixed, exhaled, or lost amounte to nearly 1540 lbs., represented by about 1218 cwts. of hay, which have yielded 1504 lbs. of live weight, due in great part to the birth and growth of foals, in addition to the force represented by 8370 days' work. CHAPTER IX. METEOROLOGICAL CONSTDERA.TIONS. g 1. TEMPERATURE. The phenomena of vegetation are always accomplished under the influence of a certain temperature. If, in addition, the concurrence of light, air, moisture, and various inorganic substances, be required, it is still perfectly certain that all of these agents only contribute to the development of a plant when they are assisted by a due measure of heat, variable with reference to the different vegetable species, and comprised within limits that are rather far apart, but essential. Germination, for example, takes place at a temperature a few degrees above the freezing point of water, 38° or 39° P., and at one indica- ted by 100° or 120° of the same scale. The forests of tropical countries thrive in a hot, moist atmosphere, which often marks up- wards of 100° P. ; and I met with a saxifrage upon the Andes at an elevation of 15,748 feet above the level of the sea, beyond the line of perpetual snow, and very near the line of perpetual con* gelation. Some families of plants require a temperature not only high, but that never falls bolow a certain very limited degree ; the majority 476 METEOROLOGY. ^TEMPERATURE of the intertropical plants are in this predicament. There are others which, imperatively requiring a high temperature for their growth and perfection, nevertheless suspend their powers during the winter, and bear without detriment degrees of cold of great intensity : among the number may be cited the larch-pine, which abounds in Siberia, and stands the utmost rigors of its climate, where the thermometer at mid-winter frequently falls to 30° and even 40" be- low zero, F. The meteorological habitudes or dispositions of plants being ex- tremely various, it follows, that the geographical distribution of plants is a consequence of the distribution of heat over the surface of the globe — of climate. The earth we inhabit appears to have a heat proper to itself ; it is a heated body in progress of cooling. It is found, in fact, that as the centre of the earth is approached, as mines penetrate more deeply below its surface, the temperature increases. Below a very limited distance from the surface, the temperature ceases to be affected by variations in the temperature of the general atmosphere ; from the point of invariable temperature the subterranean heat in- creases uniformly at the rate of 1° cent. (1.8° Fahr.) for every 101 feet of descent. The depth at which the point or stratum of invariable temperature is met with, varies in different places, and is mainly affected by the extent of the thermometrical variations in the superincumbent air in tlie course of the year. In the higher latitudes, consequently, the depth is very considerable ; at Paris, for example, M. Arago has found that a thermometer, buried at 264 feet under the surface, does not reman absolutely stationary. In climates of greater constancy, as may be conceived, the layer of invariable temperature will be found much nearer the surface ; were the temperature of the air in- variable, the layer of invariable temperature would necessarily be- found at the surface of the ground. In countries under and close to the equator, this, in fact, is found to be the case. From a series of observations which I made in So ith America, between the 2d paral- lel of southern and the 11th of northern latitude, I found that, near the line, the layer of invariable temperature is found nearly at the surface ; the thermometer, placed in a hole about one foot deep, under the shade of an Indian cabin, or a shed, does not vary by more than from one tenth to two tenths of a degree Cent. It was probably under the influence of "the internal or proper heat of the globe, according to M. de Humboldt, that the same species of animals which are now confined to the torrid zone, inhabited, in former and remote ages, the northern hemisphere, covered as it then was by arborescent ferns and stately palms. It is easy to imagine how, as the surface of the earth cooled, the distribution of climates became almost exclusively dependent on the action of the solar rays, and how also those tribes of plants and of animals, the organization of which required a higher temperature and more equable climate gradually died out and disappeared.* • Huml)oldt'» Central Aria, r. lli, p. 9a METEOROLOGY. — TEMPERATURE. 47 1 111 the state of stability to which the surface of the globe appears actually to have attained, the sun must be considered as the agent which most directly iniiueiicos the temperature of our atmosphere. The length of the day, the number of hours during which the sun is above the horizon, coupled with the height to which he ascends, such is the cause with which the temperature of each particular lati- tude is primarily connected ; and, in looking at the subject practi- cally, it is found to be so precisely ; not only is the mean tempera- ture of the year dependent on the length of the days, and the meridian altitude of the sun, but the mean temperature of each month in the year is essentially connected with the same circumstances. In the northern hemisphere, the temperature rises from about the middle of January, slowly at first, more rapidly in April and May, to reach its maximum point in July and August, when it begins to fall again until mid-January, when it is at its minimum. The highest mean annual temperature is, of course, observed in the neighborhood of the equator ; between 0° and 10° or 12° of lati- tude on either side, at the level of the sea, where besides the equal- ity of day and night, the sun, always elevated, passes the zenith twice a year. The observations that have been made up to this time, lead us to conclude that this temperature oscillates between 260 and 29" cent. ; 78.8o and 84.2° Fahr. _ Did the earth present unvarying uniformity of surface, not only with reference to elevation but to constitution, so that the power of absorbing and of radiating heat should be everywhere alike, the cli- mate of a place would depend almost entirely on its geographical position ; the points of equal temperature would be found on the same parallels of latitude, or, to employ the happy expression intro- duced by M. de Humboldt, the isothermal lines would all be parallel with the equator. But the surface of our planet is covered with un- dulations and asperities, which cause its outline to vary to infinity ; and then the soil is dry, or swampy ; it is a moving desert of sand, or covered with umbrageous and impenetrable forests ; and all this causes corresponding varieties in climate, for the surface becomes heated in different degrees as it is in one or other of these condi- tions. Another very important consideration is, that the surface is a continent, or an island in the ocean : the climate of a country, or a district, is vastly influenced by its proximity to or distance from the sea. The difficulty, the slowness, with which such a mass of liquid as the ocean becomes either heated or cooled, is the cause of the temperate character both of the summers and winters of the shores it bathes, and the islands of moderate dimensions it surrounds. As we penetrate great continents from the sea-board, we find that the temperature both of summer and winter becomes extreme, and the difference between the mean summer and mean winter tempera- ture is great ; and again we find, that places which have considera- bly different latitudes, have still very nearly the same mean annual temperature. The mean temperature of Paris, in latitude 48° 50 , is about 51.4° F. j that of London, in lat 51° 31', is 50.7° F. j that 478 METEOROLOGY. TEMPERATURE. of Dublin, in lat. 53o 23', is 49 .l^ F. ; and that of Edinburgh, in lai 550 57', is 48.40 F. An island, a peninsula, and the sea shore, consequently, enjoy a more temperate and equable climate — the summers less sultry, the winters more mild. On the shores of Glenarm, in Ireland, in lati- tude 550, the myrtle vegetates throughout the year as in Portugal ; it rarely freezes in winter ; but the heat of summer does not suffice to ripen the grape. Under the very same parallel, however, at Konigsberg, in Prussia, they experience a cold of 17° and 18° below zero of Fahrenheit's scale in the winter. The ponds and little lakes of the Feroe Islands, although situated in N. lat. 62°, never freeze, and the mean winter temperature . is very nearly 40° F. On the coasts of Devonshire, in England, the winters are so mild, that the orange-tree, as a standard, will there carry fruit ; and the agave has been seen to flourish, after having lived both winter and summer, lor twenty-eight years, in the open air, uninjured. One of the grand characteristics of what may be called a mari- time climate, is the less difference which occurs between the tem- perature of summer and that of winter. At Edinburgh, for instance, the difference only amounts to 19° F. ; at Moscow, which is nearly on the same parallel, the difference amounts to 50^ F. ; and at Kasan, (lat. 56°,) it is as much as 56.3o F. The influence of extensive continents, or remoteness from the sea-board, does not seem merely to render a climate extreme, in- creasing at once the heat of summer and the cold of winter. The collective observations on temperature, made in Europe and in Asia, show that the mean annual temperature decreases as we penetrate more into the interior of continents towards the east. Humboldt ascribes this diminution of temperature partly to the refrigerating action of the prevailing winds. While the mean annual temperature of Amsterdam (N. lat. 52° 22') is 49.6° F. , that of Berlin (N. lat. 520 31') is 47.40 F. ; that of Copenhagen, (N. lat. 55o 41') is 46.7° F. ; and that of Kasan (N. lat. 55° 48') is but 35.9o F. The highest temperi\ture which has yet been registered, as occur- ing in the open air, appears to have been observed by Burckhardt, in Upper Egypt ; the thermometer indicated 47.5° cent., upwards of 118^ F. The lowest was seen by Captain Back, in North America, when the thermometer fell to — .56^ cent., 68.° F. below zero. I II. DECREASE OF TEMPERATURE IN THE SUPERIOR STRATA OP THE ATMOSPHERE. The temperature rises rapidly as we ascend in the atmosphere ; places among the mountains always possess a climate more severe as they are higher above the level of the sea. Even under the equator, height of position modifies the seasons so much, that the hamlet of Antisana, which is within one degree of south latitude, but which is upwards of 13,000 feet above the sea level, has a mean temperature which does not differ much from that of St. Peters- burgh. Near it, but at a still greater height, the summit of Cyambe, METEOROLOGY. — ^TEMPERATURE. 479 covered by an immense mass of everlasting snow, is cut by the equinoctial line itself. The cold which prevails among lofty mountains, is ascribed to the dilatation which the air of lower regions experiences in its upward ascent, to a more rapid evaporation under diminished pressure, and to the intensity of nocturnal radiation. Places which are situated upon the same mountain-chain, nearly in the same latitude, and at the same height, have often very differ- ent climates. The temperature which would be proper to a place perfectly isolated, is necessarily modified by a considerable number of circumstances. Thus the radiation of heated plains of considera- ble extent, the nature of the color of the rocks, the thickness of the forests, the moistness or dryness of the soil, the vicinity of glaciers, the prevalence of particular winds, hotter or colder, moister or drier, the accumulation of clouds, &c., are so many causes which tend to modify the meteorological conditions of a country, whatever its mere geographical position. The neighborhood of volcanoes in a state of activity does not appear to affect the temperature sensibly : thus Purace, Pasto, Cumbal, which have flaming volcanoes towering over them, have not warmer climates than Bogata, Santa Eosa, De Osos, Le Param de Herve, &c., situated on sand-stone or syenite. From the whole series of observations which I had an opportunity of making on the Cordilleras, it appears that one degree of tempera- ture, cent., 1.8° F., corresponds to 195 metres, or 649.4 feet of ascent among the equatorial Andes. In Europe, it has been ascer- tained that the decrease of temperature in ascending mountains, is more rapid during the day than during the night — during summer than during the winter ; for example, between Geneva and Mount St. Lernard, to have the Fahrenheit thermometer fall one degree, it is necessary to ascend : In spring 826.1 feet. In summer 886.6 In autumn • 882.2 In winter. 422.2 It sometimes happens, however, that in winter, in a zone of no great elevation, the temperature increases with the elevation — a fact which Messrs. Bravais and Lottin observed in the 70° of N. lat., in calm weather ; at an elevation between 1312 and 1640 feet, the rise amounted to as many as 6° centigrade, 10.8° Fahrenheit. In no part of the globe is the diminution of temperature, occasion- ed by a rise above the level of the sea, more remarkable than among equatorial mountain ranges ; and it is not without astonishment that the European, leaving the burning districts which produce the banana and cocoa-tree, frequently reaches, in the course of a few hours, the barren regions which are covered with everlasting snow. " Upon each particular rock of the rapid slope of the Cordillera," says M. de Humboldt, " in the series of climates superimposed in stages, we find inscribed the laws of the decrease of caloric, and of the geo- graphical distribution of vegetable forms."* ♦ Humboldt's Central Asia, vol. lit, p. 286. 480 METEOROLOGY. — TEMPERATURE. In the hottest countries of the earth, the summits of very lofty mountains are constantly covered with snow ; in the elevated and cold strata of the atmosphere, the watery vapor is condensed, and falls in the state of hail and snow. In the plain, hail melts almost immediately ; the fusion is slower upon the mountains ; and for each latitude there is a certain elevation where hail and snow no longer melt perceptibly. This elevation is the inferior limit of perpetual snow. The accidental causes which tend to modify the temperature of a climate, also act in raising or lowering the snow-line. On the south- em slope of the Himalaya, for example, the snow-line does not de- scend so low as it does upon the northern slope ; and in Peru, from 14° to 16° of S. latitude, Mr. Pentland found the perpetual snow-line, at an elevation of 1312 feet higher than it is under the equator. Elevation above the level of the sea, consequently, has the same eSect upon climate as increase in latitude. Upon mountain ranges, vegetation undergoes modification in its forms, becomes decrepit, and disappears towards the line of perpetual snow, precisely as it does within the polar circle, and for no other than the same reason, viz., depression of temperature. The constancy and the small extent of variation which occurs in the temperature of the atmosphere under the equator, enables us to indicate with some precision the point of mean temperature below which there is no longer any vegetation. In ascending Chimbora- zo I met with this point at the height of 15,774.5 feet, where the mean temperature approached 35° F., and where consequently the saxifrages, which root among the rocks, must still receive a temper- ature of from 41° to 43^ F. during the day, inasmuch as far beyond the inferior snow-line, at an elevation of 19,685 feet above the sea- line, I saw a thermometer suspended in the air, and in the shade mark 44.6° F. In considering the extension of vegetation towards the polar re- gions, we discover plants growing in very high latitudes in places which have a mean temperature much below that which I believe to be the limit of vegetable life on the mountains of the equatorial region. In these rigorous climates vegetation is suspended by the severity of the cold during the greater portion of the year ; it is only during the brief and passing heat of summer that the vegetable world wakes from its long winter sleep. Nova Zembla, lat. 73° N., the mean temperature of whose summer is between 34° and 35^^ F., is, perhaps, like the perpetual snow-line of the equator, the term of vegetable existence. It is also to the very remarkable heat of the summer in countries situated at the nothern extremity of the con- tinent of Asia, remarkable if it be contrasted with the intensity of the winter cold, that man succeeds in rearing a few culinary vegeta- bles in those dreadful climates. At Jakoustk, in 62° of N. lat., and where mercury is frozen during two months of the year, the mean temperature of summer is very nearly 64^ F. We have here as M. de Humboldt observes, " a well-characterized continental climate," examples of which indeed are frequent in the north of America. At METEOROLOGY. GROWTH OF PLANTS. 48 « Jakoustk wheat and rye sometimes yield a return of 15 for 1, al« though at the depth of a yard the soil which grows them is cca- stantly frozen.* The limit of perpetual snow being much lower upon tl e mountains of Europe than in tropical countries, agriculture ceases at a much less elevation. At a height of 6560 feet above the level of the sea the vegetables of the plain have almost entirely disappeared. In Northern Switzerland the vine does not grow at an elevation of more than 1800 feet above the sea-line ; maize scarcely ripens at an elevation of 2850 feet, while in the Andes it still affords abundant harvests at an elevation of 8260 feet. On the plateau or table land of Los Pastes, fidds of barley are seen at upwards of 10,000 feet above the level of the sea ; but on the northern slope of Monte Rosa, in Switzerland, barley fails at an elevation of about 4260 feet ; on the southern slope, indeed, it reaches a height of about 6560 feet ; and this great variation in the ultimate limit of barley is frequently observed with reference to the same plant grown upon opposite as- pects of a mountain range. The difference is ascribed to local in- fluences ; thus, it is a well-ascertained fact, that on the mountains of the northern hemisphere vegetation reaches a much higher lati- tude upon southern than upon northern exposures ; but a general law, and one applicable to every latitude, is, that the higher we rise above the level of the sea, the scantier does vegetation become, the later do harvests reach maturity ; but as the heat of the atmosphere increases with the elevation, it follows that there is an obvious rela- tion between the time a crop is upon the ground a. d the mean tem- perature of the place or season where it grows. We have still to examine this relationship. ^ III. METEOROLOGICAL CIRCUMSTANCES UNDER WHICH CERTAIN PLANTS GROW IN DIFFERENT CLIMATES. In discussing the conditions of temperature under which the va- rious plants that are common in our European agriculture come to maturity, we are led to conclusions which are not without interest. A knowledge of the mean temperature of a place situated between the tropics suffices of itself to give us an idea of the nature of its agriculture ; in fact, the temperature of each day differs little from that of the entire year, during which vegetable life proceeds without interruption. It is altogether different with regard to countries sit uated beyond the limits of the torrid zone. The mean annual tem- perature is not then a datum sufficient to enable us to appreciate the agricultural importance of a country. In order to know what the earth will produce, the temperature proper to the different seasons of the year must be known ; in a word, it is the mean temperature of the cycle in which vegetation begins and ends that it imports us to ascertain, in order to learn what the useful plants are which may be required of the soil. In examining the question which now engages us, we first inquire what time elapses between the sprouting of a plant and its maturity ♦ Humboldt's Central Asia, vol. Ul. p. 49. 41 482 METEOROLOGY. GROWTH OF PLANTS. end then we determine the temperature of the interval which sepe rates these two extreme epochs in vegetable life. In comparing these data with reference to the same species of plant grown in Eu rope an 1 America, we arrive at the following curious result, that the number of days that elapse between the commencement of vegeta tion and the period of ripeness, is by so much the greater as the mean temperature is lower. The duration of the life of the vegeta- ble would be the same, however different the climate, were this tem- perature identical ; it will be longer or it will be shorter as the mean temperature of the cycle itself is lower or higher. In other words, the duration of the vegetation appears to be in the inverse ratio of the mean temperature ; so that if we multiply the number of days during which a given plant grows in different climates, by the mean temperature of each, we obtain numbers that are very nearly equa' This result is not only remarkable in so far as it seems to indicate that upon every parallel of latitude, at all elevations above the level of the sea, the same plant receives in the course of its existence an equal quantity of heat, but it may find its direct application by ena- bling us to foresee the possibility of acclimating a vegetable in a country, the mean temperature of the several months of which is known. CULTIVATION OF WHEAT, ALSACE. In 1835 we sowed our wheat on the 1st of November ; the cold set in shortly after the plant had sprung, and the harvest took place the 16th of July, 1836. The vegetation during the last days of au- tumn is so sl6w and irregular, that it may be assumed without sensi- ble error, that it really begins in spring, when the frosts are no longer felt ; from this period only does it proceed without interruption. For Alsace I regard this period as beginning with the 1st of March. The period of the growth was, therefore, 137 days, the mean tem- perature was 59° F., (3083° F.) Tremois wheat, this same year, required 131^days to ripen under a mean temperature of between 60° and 61° F., (7925° F.) At Paris, setting out from the 31st of March, wheat generally re- quires 160 days to attain maturity, the mean temperature being about 56° F., (8960° F.) At Alais the month of February having generally but few days of heat, it may be regarded as the epoch when the continued vege- tation of autumn-sown wheat commences. The harvest taking place on the 27th of June, the number of days whic h it requires to ripen is 146, the mean temperature being between 57° and 68° F. (8322° F.) CULTIYATION OF WHEAT IN AMERICA. At Kingston, New York, the wheat is sown in autumn ; Tegeta- tion suspended through the winter resumes its activity in the begin- ning of April, and the harvest takes place about the 1st of August The crop is therefore growing during about 122 days under the in- fluence of a mean temperature of 63° F. (7680° F.) METEOROLOGY. GROWTH OF PLANTS. 488 In the same place Tremois wheat is sown in the beginning of May, and the harvest takes place towards the 15th of August, so that it is 106 days on the ground under a mean temperature of 68° F . (7208° F.) At Cincinnati the wheat sown in the end of February is harvest- ed in the 2d week in July, say the 15th day, the crop is therefore 137 days on the ground under a mean temperature of between 60° and 61° F. (8288° F.) INTERTROPICAL REGION. Wheat sown at the end of February was reaped on the 25th of July at Zimijaca, plain of Bogota, having been 147 days on the ground, the mean temperature being between 58° and 59° F. (8526° F.) At Quinchuqui the vegetation of wheat begins in February and ends in the month of July, say, 181 days; and I found the mean temperature to be between 57° and 58° F. At Venezuela, according to M. Codazzi, wheat to ripen require? 92 days at Turmero, mean temperature between 75.2° and 76° F., (6918° F. ;) 100 days at Truxillo, mean temperature 72.1" F., (7210° F.) CULTIVATION OP BARLEY. Of the cereals, barley is that which succeeds in the most diversi- fied climates. It comes to maturity under the burning heats of the tropics ; and in regions where the mean and constant temperature is scarcely 52° F., fields of barley of great beauty are still en- countered. At Alsace (Bechelbronn) barley sown at the end of April was harvested on the 1st of August. It had remained 92 days on the ground, the mean temperature having been between 66° and 67° F., (6118° F.) Winter barley sown on the 1st of November was cut on the 1st of July. Reckoning the period of active vegetation from the 1st of March, it was 122 days in coming to maturity, the mean temper- ature having been between 58° and 59° F., (7076° F.) At Alais winter barley is harvested on the 18th of June. As- suming that, as in the case of wheat, the 1st of February is the date of commencing vegetation, it must have taken 137 days to come to maturity under a mean temperature between 55° and 56° F. In Egypt upon the banks of the Nile barley is sown in the end of November, and the harvest takes place at the end of February, at an interval therefore of 90 days, and the mean temperature of the winter at Cairo is nearly 70° F., (6300° F.) At Kingston, North America, the barley is sown in the begin- ning of May, and the crop is cut towards the beginning of August, in about 92 days, therefore, the mean temperature being between 66° to 67" F. At Cumbal under the line there is no fixed period for sowing bailey. It is generally put into the ground on the approach of th« i64 METEOROLOGY. GROWTH OF PLANTS. rain}' season about the 1st of June, and it is then reaped about the middle of November ; it therefore stands on the ground for about 168 days, and the mean temperature is between 51° and 52° F. At Santa Fe de Bogota they reckon about four months between the barley seed-time and harvest, or about 122 days, the mean tem- perature being between 58° and 59° F. CITLTIVATION OF MAIZE, OR INDIAN CORN. In the neighborhood of Bechelbronn the maize which sprouted on the first of June yielded an abundant harvest on the 1st of October) the mean temperature having been 68° F. In South America maize comes to maturity in the course of three months, say 92 days, the mean temperature being between 81° and 82° F.; but on the elevated plains, as that of Santa Fe, maize will require six months to come to maturity, say 183 days, and there the mean temperature is 69" F. CULTIVATION OF THE POTATO. In 1836 our potatoes at Bechelbronn were put into the ground on the 1st of May, and the crop was gathered on the 15th of October, after 157 days, therefore, the mean temperature having been about 65° F.; but in ordinary years, when the temperature is less elevated than that of 1836, the potato crop is generally gathered at the end of October, after 183 days, the mean temperature having been as before nearly 59° F. In the neighborhood of Alais potatoes are planted at the end of March and taken up about the 1st of September, after five months or 153 days, the mean temperature of which has been 70° F. According to M. Codazzi potatoes are grown near the lake of Va- lencia, (Venezuela,) in 120 days, and the mean temperature of Ma- racaibo near the lake is 78° F. According to the same observer, the potato still yields good crops at Merida in the Cordilleras, where the mean temperature is between 71° and 72° F., and the growth lasts about 4^ months. On the temperate levels of New Granada at Santa F6 I saw po- tatoes set in the middle of December immediately after the rainy season, and the harvest was gathered in the course of the first week in June, the crop therefore was at least 200 days in the ground, the mean temperature having been between 58° and 59° F. On the occasion of my ascent of the volcanic mountain, Antisana, I ate on the 4th of August some potatoes which had just been gath- ered, and which had been planted in the beginning of November, so that the crop had been 276 days in the ground, the mean tempera- ture of the country being 52° Fahr. But this is not yet the superior limit to the cultivation of potatoes under the equator. They are still grown at Cambugan, the mear temperature of which scarcely exceeds 49° Fahr., the plant remain ing nearly eleven months in the ground, and the crop being frequentlj METEOROLOGY. GROWTH OF PLANTS. 48ft lo«< from frorta that occur at this great elevation in the course of the mouths of November and January. CULTIVATION OF THE INDIGO PLANT. In "Venezuela, in plantations very near the level of the sea, the first crop is cut about eighty days after sowing. The mean tem- perature is there between 81° and 82° Fahr. In other countries where the mean temperature ranges between 72° and 74° Fahr., which must be regarded as the limits to the growth of indigo, the first cutting takes place 3^ months or 106 days after the sowing. In India the first cutting seems generally to occur about ninety days after the sowing, and the mean temperature of the two winter months and of the summer months wheii the crop is on the ground, at Bom- bay is about 76° Fahr. I shall terminate this section by calling the attention of vegetable physiologists to a fact which appears to have escaped them. It is this : that plants in general, those of tropical countries very obvi- ously so, spring up, live, and flourish in temperatures that are nearly the same. In Europe and in North America, an annual plant is subjected to climatic influences of the greatest diversity. The cereals, for example, germinate at from 43° to 47° or 48° ; they get through the winter alive, making no progress ; but in the spring they shoot up, and the ear attains maturity at a season when the temperature, which has risen gradually, is somewhat steady at from 74° to 78° Fahr. In equinoctial countries Aings pass diflferently : the germination, growth, and ripening of grain take place under degrees of heat which are nearly invariable. At Santa Fe the thermometer indicates 79° Fahr. at seed as at harvest time. In Europe the potato is planted with the thermometer at from 50° to 54° Fahr., and it does not ripen until it has had the heats of July and August. But we have just seen that this plant grows, slowly indeed, but regularly, in places where the temperature, nearly invariable, does not rise above 48.2° or 50° Fahr. Germination, and the evolution of those organs by which vegeta- bles perform their functions in the soil and in the air, take place at temperatures that vary between 32° and 112° Fahr.; but the most important epoch in their life, ripening, generally happens within much smaller limits, and which indicate the climate best adapted to their cultivation, if not always to their growth ; for the vine grows lustily in many places where its fruit never ripens. To produce drinkable wine, a vineyard must have not only a summer and an autumn sufficiently hot ; it is indjspensable in addition that at a given period — that, namely, which follows the appearance of the seeds — there be a month, the mean temperature of which does not fall below 19° cent, or about 66|° Fahr., a fact of which conviction may be obtained from the following table which 1 borrow from M. de Huitt- boldt: 41* im METEOROLOGY. — GROWTH OF PLANTS. Temperature of Temperature summer. w autumn. Bordeaux 70® Fahiu 58" Frankfort, A. M- . 65 50 Lausanne 65.2 49.7 Paris 65.8 52.2 Berlin 63.2 48.0 London 62.9 51.3 Cherbourg 61.9 54.4 Temperature of the hottest month 73.3® F. very favorahl* 66.0 65.8 66.2 64.4 Wine scarcely drinkable 64.1 Vice not cultivated. 63.2 In high latitudes the disappearance of vigorous vegetation in plants day depend quite as much on intensity of winter colds as on insuf- ficiency of summer heat. The equable climate of the equatorial re- gions is therefore much better adapted than that of Europe to de- termine the extreme limits of temperature between which vegetable species of different kinds will attain to maturity. Thus it has been found that the vine between the tropics is productive in temperatures that vary from 69° F. to 79° or 80°. I shall terminate with a list of the temperatures favorable to the particular vegetables in the success of which man is more especially interested. ^«Ttimiim. Miuimtuit. Pine-apple " Melon " Vanilla " Guaduas " The vine 79 CotBse 79 Anise 77 Wheat 74(1) Barley 74 59 Potatoes 75(1) 52 Arachaca 75 49 Flax 74 54 Apple 72 59 Oak 67 61 Maximum. Minimum. The cocoa, or chocolate bean 82® F. 73° F. Banana " 64 Indigo " 71 Sugar-cane " 71 Cocoa-nut " 78 Palm " 78 Tobacco " 65 Manihot " 72 Cotton-tree " 67 Maize " 50 Haricots " 59 OrchU " 72 Rice " 75 Calabash " 72 rjaricapapaya " 66 ^ IV. COOLING THROUGH THE NIGHT ; DEW, RAIN. When the sky is clear and calm during the night, vegetables cooi down and very soon show a temperature inferior to that of the air which surrounds them. This property of cooling in such circum- stances belongs to all bodies ; but all do not possess it to the same degree. Organic substances, for instance, such as wool or cotton, feathers, &c., radiate powerfully and sink low ; polished metals, on the contrary, have a very weak emissive or radiating power ; and air and the gases in general radiate still more feebly. Inasmuch as a body is continually emitting heat, its temperature can only remain stationary so long as it receives from surrounding objects at every instant a quantity of caloric precisely equal in quan- tity to that which it loses from its surface. From the moment that these incessant exchanges cease to be i: a state of perfect equality, the temperature of a body varies ; it may even experience a considerable degree of cooling if it is exposed during a clear night in an open spot. In such circumstances, a body gives off towards all the visible parts of the heavens more heat than P wceives ; for the higher regions of the atmosphere are excessive* METEOROLOGY. NIGHT COOLING. 487 ly cold, a fact which is proved by the rapid diminution of tempera- ture experienced on ascending mountains, or by rising into the air in balloons. The internal temperature of the globe, the tendency of which would be to compensate the loss experienced by the body which radiates, has scarcely any effect in lessening the cooling, be- cause it is propagated with extreme slowness, in consequence of the indifferent conducting powers of the earthy substances of which its crust is composed. The air, lastly, which surrounds the radiating body, does not warm it save in the most minute, inappreciable degree, and rather by its contact than by transmitting to it rays of heat, for the gases have only very limited emissive powers. It is even in consequence of the small amount of this power that the stratum of air in contact with the surface of the ground, does not by any means sink in the same proportion as the surface upon which it lies. Thus, in the circumstances which I have indicated, a thermometer laid upon the ground always indicates a temperature lower than that which is proclaimed by one suspended in the air ; and the difference is by so much the greater as the radiating power of the bodies ex- posed is more decided, or as it may take place into a greater extent of the heavens. Every cause which agitates the air, which disturbs its transparency, which contracts the extent of the visible sphere, interferes with nocturnal radiation, and therefore with cooling. A cloud, like a screen, compensates either in whole or in part accord- ing to its proper temperature, for the loss of heat which a body upon the surface of the earth experiences in radiating into space. Wind, by continually renewing the air which is in contact with the surface of bodies tending to cool by radiation, always diminishes its effect to a certain extent. It is for this reason that a cloudless sky and a calm atmosphere, when nocturnal radiation attains its maximum, are most dangerous or injurious to our harvests. In a night which combines all the conditions favorable to radiation, a thermometer of small size laid upon the grass will be found to mark from 10° to 14° or 15° Fahr. below the temperature of the sur- rounding atmosphere. Thus in the temperate zone in Europe, as Mr. Daniell has observed, the temperature of meadows and heaths is liable to fall during ten months of the year by the mere effect of nocturnal radiation to a temperature below the freezing point of water ; this is particularly apt to happen both in spring and autumn, when the destructive effects of radiation are most to be apprehend- ed, the nocturnal radiations of those seasons frequently lowering the temperature several degrees below the freezing point. A few observations which I made upon nocturnal radiation at dif- ferent heights in the Cordilleras, seem to indicate that its effects there are less decided than in Europe, in consequence perhaps of the greater quantity of heat acquired by the ground in the course of the day. It appears that in this mountain range it rarely freezes at a height less than 6560 feet above the level of the sea ; although .here are certain circumstances there which favor nocturnal radia- tion so much, that it is really impossible to indicate any very precise timits. In a general way it may be said that the crops of thosr 488 meteorol:>gy. — night cooling. plains which are sufficiently elevated to hare a mean temperature of from 50° to 58° Fahr. are exposed to suffer from frost ; it fre- auently happens that a crop of wheat, barley, maize, or potatoes, of the richest appearance, is destroyed in a single night by the effect of radiation. In Europe during the fine nights of April and May, when the air is calm and the sky clear, buds, leaves, and young shoots are frequently cut off, are frozen ; in a word, although a ther- mometer in the air indicates several degrees above the point of con- gelation. Market gardeners and others who are much exposed to loss from this cause, ascribe the effect to the light of the mc in of the months of April and May ; and they ground their opinion upon the fact that when the sky is clouded, the destructive effects of frost are not apparent, although the same temperature of the atmosphere be indicated by the thermometer. In the lower ranges of the Cordilleras, farmers also ascribe the same injurious consequences to the light of the moon, wuth this dif- ference, that according to them the destructive influence continues throughout the year ; and it is not unworthy of remark that, in the neighborhoods of Paris and of London, the mean temperature of the months of April and May (from 50° to 57°, or 58° F.) represents ex- actly the invariable climate of those places among the Andes, where the effects of frost upon vegetation are particularly to be apprehend- ed. M. Arago has shown, that the cold ascribed to the light of the moon is nothing but a consequence of the nocturnal radiation, at a season when the thermometer in the air is frequently at from 40° to 43° F. and the sky is clear and calm. At this temperature a plant, radiating into space, readily falls below the point of congelation, and then the hopes of the gardener and farmer are destroyed. The phenomenon takes place particularly in a bright night : and if the moon happen to be up when it occurs, the influence is ascribed by the vulgar to her light. Were the sky clouded, the principal con- dition to radiation would be wanting ; the temperature of objects on the surface of the ground would not fall below that of the surround- ing medium, and plants would not freeze unless the air itself fell to 32° F. The observation of gardeners, therefore, as M. Arago remarks, was not in itself false, it was only incomplete. If the freezing of the soft and delicate parts of vegetables in circumstances when the air is several degrees above the freezing point, be really due to the escape of caloric into planetary space, it must happen that a screen placed above a radiating body, so as to mask a portion of the heav- ens, will either prevent or at least diminish the amount of the cooling. And that this takes place in fact, appears from the beautiful experi- ments of Dr. Wells. A thermometer, placed upon a plank of a certain thickness, and raised about a yard above the ground, oc- casionally indicates in clear and calm weather from 6° to T or 8° F. ess than a second thermometer attached to the lower surface of he plank. It is in this way that we explain the use of mats, of ayers of straw, in a word, of all those slight coverings which gar- deners are so careful to supply during the night to delicate plamts ai METEOROLOGY. NIGHT FROSTS. 489 eertain seasons of the year. Before men were aware that bodies on the surface of the ground became colder than the air which sur- rounds them during a clear night, the rationale of this practice was not apparent ; for it was altogether impossible to conceive that coverings 8o slight could protect vegetables from a low temperature of the air. The means indicated, as simple as they are effectual in protecting plants in the garden, are rarely applicable in farming, where the surface to be preserved is always very extensive. Nevertheless, in severe winters, the frost by penetrating the ground would frequently destroy the fields sown in autumn, were it not that in high latitudes the snow which covers the surface becomes a powerful obstacle to excessive cooling, by acting at one and the same time as a covering, and as a screen preventing radiation. As a covering, because snow is one of the worst of conductors, one of those substances which for a given thickness opposes the passage of heat most effectually ; it is, therefore, an obstacle almost insurmountable to the earth beneath it getting into equilibrium in point of temperature with the atmosphere. As a screen, because in sheltering the ground it prevents it from undergoing the cooling which it would not fail to experience in clear nights by radiation into the open firmament. It is familiarly known in many parts of Europe, that the accidental want of the usual cov- ering of snow will cause the loss of the autumn-sown crops of grain It is on the surface of the snow that the great depression of temper- ature takes place ; and the substance being a very bad conductor, the earth cools in a much less degree. In the month of February, 1841, I made some experiments, which show that the snow which covers the ground acts in the manner of a screen. I had first a thermometer upon the snow, the bulb of the instrument being cover- ed by from 0.078 to 0.117 of an inch of snow in powder ; second, a thermometer, the bulb of which was situated completely under the layer of snow in contact with the ground ; third, a thermometer in the open air, at about 37 or 38 feet above the surface, on the north of a building. The layer of snow was about four inches in thickness, an J had covered a field sown with wheat for a month. The sun shone brightly upon the field on those days when my experiments were made. Feb. 11. Five o'clock in the evening; the sun has been hidden by the mountains for half an hour ; the sky is unclouded, the air very calm : thermometer under the snow, 32' F. ; thermometer upon the snow, 29° F. ; thermometer in the air, 36.3' F. Feb. 12. The night very fine, no clouds, the air calm. At sevea o'clock in the morning, the sun is not yet upon the field : thermom eter under the snow, 26.2" F. ; thermometer upon the snow, 10" F. ; thermometer in the air, 26.3° F. At half-past five in the evening, the sun behind the mountains : thermometer under the snow, 32° F. ; thermometer upon the snow, 29° F. ; thermometer in the air, 37.5° F. Feb. 13. At seven in the morning ; the sky gray, the air slightly in motion : thermometer under the snow, 28° F. ; thermometer upon the snow, 17° F. ; thermometer in the air, 25° F. too METEOROLOGY. DEW. At half-past five in the evening ; the air calm, the sky cloudlesSj the sun already concealed for some time : thermometer under the snow, 32° F. ; thermometer upon the snow, 30° F. ; thermometer in the air, 40° F. Feb. 14. Seven in the morning, wind W., a fine rain falling: thermometer under the snow, 32° F. ; thermometer upon the snow. 32° F. ; thermometer in the air, 35.7° F. When we reflect upon the losses occasioned to farmers and mar- ket gardeners by frosts that are entirely due to nocturnal radiation ?t seasons of the year when vegetation has already made considera- ble progress, we ask eagerly if there be no possible means of guard- ing against them. I shall here make known a method imagined and successfully followed by South American agriculturists with this view. The natives of the upper country in Peru who inhabit the elevated plains of Cusco are perhaps more than any other people accustomed to see their harvest destroyed by the effects of nocturnal radiation. The Incas appear to have ascertained the conditions under which frost during the night was most to be apprehended. They had observed that it only froze when the night was clear and the air calm : knowing consequently that the presence of clouds prevented frost, they contrived to make as it were artificial clouds to preserve their fields against the cold. When the evening led them to apprehend a frost — that is to say, when the stars shone with brilUancy, and the air was still — the Indians set fire to a heap of wet straw or dung, and by this means raised a cloud of smoke, and so destroyed the transparency of the atmosphere from which they had so much to apprehend. It is easy in fact to conceive that the transparency of the air can readily be destroyed by raising a smoke in calm weather ; it would be otherwise were there any wind stir- ring ; but then the precaution itself becomes unnecessary, for with air in motion, with a breeze blowing, there is no reason to apprehend frost from nocturnal radiation. The practice followed by the Indians just described is mentioned by the Inca Garcillaso de la Vega in his Royal Commentaries of Peru. Garcillaso in the imperial city of Cusca, and in his youth, had frequently seen the Indians raise a smoke to preserve the fields of maize from the frost.* The cooling of bodies occasioned by nocturnal radiation is always accompanied by a deposite of moisture upon their surface under the form of minute globules : this is dew. The ingenious experiments of Wells having demonstrated that the appearance of dew always follows, never precedes the fall in temperature of the bodies on •vhich it is deposited, the phenomenon cannot be attributed to any hing more than a simple condensation of the watery vapor con- ained in the air, comparable in all respects to that which takes ■)lace upon the surface of a vessel containing a fluid that is colder han t'le air.f The quantity of moisture dissolved in the atmosphere * The good effects of smoke in preventing nocturnal congelation are also sigLalued oy Pliny the naturalist, t Aiigo, Annusiire des Longitudes, Aan*e 1837, p. 160. METEOROLOGY. — DEW. 491 is by so much tlie greater as tlie temperature is higher. In very warm climates the dew is so copious as to assist vegetation essen- tially, supplying the place of rain during a great part of the year. According to some meteorologists dew is most copious near the sea-board of a country ; very little falls in the interior of great con- tinents, and indeed is said only to be apparent in the vicinity of lakes and rivers.* I cannot agree in any statement of this kind ipade so absolutely. I have never had occasion to see more copious dews than those which occasionally fall in the steppes of San Martin to the east of the eastern Cordilleras, and at a very great distance from the sea ; the dew was so copious that for several nights I found it impossible to employ an artificial-horizon of black glass in order to take the meridian altitude of the stars ; the moment the apparatus was exposed there was such a quantity of water deposited on the surface that it soon gathered into drops and trickled off. I found it necessary to have recourse to mercury to reflect the star under ob- servation. During the clear calm nights the turf of these immense plains receives a considerable quantity of moisture in the form of dew, which materially assists vegetation, and by its evaporation tempers the excessive heat of the ensuing day. In tropical coun- tries the forests contribute to keep down the temperature. In very hot countries it is rare to be out in a cleared spot, when the night is favorable to radiation, without hearing drops of water, produced by the copiousness of the dew, falling continually from the surround- ing trees, so that forests contribute further to produce and to main- tain springs by acting as condensers of the watery vapor dissolved in the air. I might cite a number of observations upon this point which I made in the forest of Cauca. In the bivouac between the 4th and 5th of July, 1827, the night was magnificent ; nevertheless, in the forest which began at the distance of a few yards from our encampment, it rained abundantly ; by the light of the unclouded moon we could see the water running from the branches. It is possible that the transpiration from the green parts of the trees might have been added to the dew condensed, and so increased the intensity of the phenomenon which I have described ; but I rather incline to believe that the cooling of the leaves by way of radiation had by far the largest share in the production of this dew- rain. It is true that of all the leaves which form the crown of a tree, those whose surface is exposed and radiate freely into space intercept, as would a screen, the radiation of the leaves and branches which are not so exposed ; but, as M. de Humboldt has observed, if the leaves and branches which crown a tree cool directly by emis- sion, those which are situated immediately beneath them by radiating towards the lower parts of the leaves which are already cooled a greater quantity of heat than they receive, their temperature will also necessarily fall, and the cooling will thus be propagated from above downward until the whole mass of the tree feels its effects It is thus that the ambient air circulating through the leaves become* • Kaemtz, Meteorology, translated by W. Walker, London- 1844. 492 METEOROLOGY. — RAIN. cooled during bright nights, and to judge from the influence which forests exert in lowering the temperature of a country, it is enough to recollect with M. de Hunboldt that by reason of the vast multi- plicity of leaves, a tree, the crown of which does not present a hori- zontal section of more than about 120 or 130 square feet, actually influences the cooling of the atmosphere by an extent of surface several thousand times more extensive than this section. The proportion of watery vapor which a gas will retain in solu- tion is by so much the greater as the tempe^rature of the air is higher. All the causes which cool air saturated with watery vapor occasion, as we have already seen, the precipitation of a certain quantity of moisture. When this condensation takes place in the midst of a gaseous mass, the precipitated water collects into small floating vesicles, which trouble the transparency of the medium that momentarily holds them in suspension. Mists, fogs, and clouds are collections of these vesicles ; a fog, as a celebrated naturalist said, is a cloud in which one is, and a cloud is a fog in which one is not. The vesicles of clouds tend towards the earth, like all heavy bo- dies, but by reason of their specific lightness the resistance of the air which they displace lessens the rapidity of their descent. When they are of larger size they coalesce and form drops of water which fall with greater celerity. When these drops pass through strata of very dry air they undergo partial evaporation, and this is the reason wherefore there is sometimes less rain upon plains than upon mountains. In opposite circumstances it is the inverse phenomenon that is observed ; the drops increase in size in passing through the inferior strata of an atmosphore saturated with moisture, condensing vapor in their course. This is what happens most generally. In taking a survey of a large amount of observations, meteorolo- gists have inferred that the annual quantity of rain varies with the latitude ; that, greatest at the equator, it gradually lessens as higher northern and southern latitudes are attained ; this is as much as saying that the quantity of rain is greater as the temperature of the climate is higher. But to this rule there are numerous exceptions ; for instance, under the line at Payta on the sea-coast it only rains very rarely ; a shower of rain is an event, and when I visited the country eighteen years had elapsed since they had had any thing of a fall of rain. Local causes have the greatest influence upon the fall of rain, so that countries on the same parallel of latitude are far from being equally distinguished by dryness or humidity. It is believed that in Europe it rains more heavily and more fre- quently in the day than in the night. In the equinoctial regions, at least in those parts that I have visited, it would seem that the op- posite rule held good. Every one in South America allows that it rains principally during the night, and the observations which I made in the neighborhood of Marmato enable me to state that of 7.874 inches of rain which fell in the month of October, 1.336 inches fell in the day, 5.638 inches in the night ; of 8.881 inches which C?ll in the month of November, 0.707 inches came dow;j ir the day, METEOROLOGY. RAIN. 498 8.174 inches in the night ; of 5.934 inches which fell in December, 0.786 inches fell in the day, 5.148 inches in the night. Two series of observations taken in the same country al two sta- tions not far from one another, but situated at very different eleva- tions, seem to confirm, in reference to the equatorial regions, the conclusions of European meteorologists as to the fact that the an- nual quantity of rain which falls diminishes as the height above the level of the sea increases. They also show that in latitudes which do not differ materially, more rain falls where the mean temperature is 68° F. than where it is 58° F. Marmato lies in N. lat. 5° 27", and 75° 11" (1) W. long., at a height of 4676 feet above the level of the sea ; Santa Fe in N. lat. 4° 36", W. long. 75° 6", at a height of 8692 feet above the level of the sea. And while the quantity of rain at the former place amount- ed, according to my own observations for 1833, to 60 inches, ac- cording to Caldas, in 1807, at the latter there fell but 39.4 inches. In temperate climates the quantity of rain that falls varies with the seasons. Near the equator, where the temperature remains constant throughout the year, the rainy season commences precisely at the period when the sun approaches the zenith ; and whenever the latitude of a place in the torrid zone where it rains is of the same denomination and equal to the declination of the sun, storms occur. In such circumstances the sky in the morning is of remarkable pu- rity, the air is calm, the heat of the sun insupportable. Towards noon clouds begin to show themselves upon the horizon, the hygrom- eter does not advance towards dryness as it usually does, it remains stationary, or even falls towards extreme humidity. It is always after the sun has passed the meridian that the thunder is heard, which being preceded by a light wind is soon followed by a deluge of rain. In my opinion the permanence or incessant renovation of storms in the bosom of the atmosphere is a capital fact, and is con- nected with one of the most important questions in the physics of our globe, that of the fixation of the azote of the air by organized The most recent inquiries show dry atmospherical air to consist in volume of: Oxygen 20.8 Azote....: 79.2 The air contains in addition from 2 to 5 10,000ths of carbonic acid gas, and quantities perhaps still smaller of carbureted combustible gas. The experiments of M . Theodore de Saussure, as well as those of Professor Liebig, have further demonstrated in it traces of ammoniacal vapor. I have already shown that animals do not directly assimilate the azote of the atmosphere. Azote is nevertheless an element essen- tial to the constitution of every living being, and is met with indif- ferently in either kingdom of nature. If we inquire into the sourc© 5f this principle in connection with the herbivorous tribes of animals, we find it as an element in the food which sustains them. If we next inquire into the immediate origin of the azote which entert 42 494 METEOROLOGY. RAIN. into the constitution of vegetables, it is discovered in the manure which proceeds more >3pecially from animal remains ; for vegeta- bles, to thrive, must receive azotized aliment by their roots. We thus come to apprehend that plants supply animals with their azote, and that these restore it to plants when the term of their existence is accomplished ; we are led to discover, in a word, that living or- ganic matter derives its azote from dead organic matter. This view leads us to conclude that the amount of living matter on the surface of the globe is restricted ; that its limits are in some sort determined by the quantity of azote in circulation among organ- ized beings ; but the question must be viewed from a loftier emi- nence, and we must ask what is the origin of the azote which enters into the constitution of organic matter considered as a whole 1 If we now turn to the possible sources or magazines of azote, we shall find, setting aside organized beings and their remains, tnat there is in truth but one, the atmosphere. It is therefore extremely probable that all living beings have previously obtained their azote from the atmosphere, just as it seems very certain that they have thence derived their carbon.* The most reasonable supposition in the actual state of science, is to consider the ammoniacal vapors diffused through the atmosphere as the prime source of the azotized principles of vegetables, and then through them of animals ; a consequence of which hypothesis would be to assume with Liebig, that carbonate of ammonia existed in the atmosphere before the appearance of living things upon the face of the earth. The phenomena and effects of thunder-storms appear to me cal- culated to support this opinion. It is known, in fact, that so often as a succession of electrical sparks passes through moist air, there is formation and combination of nitric acid and ammonia. Now ni- trate of ammonia is one of the constant ingredients in the rain of thunder-storms. But nitrate of ammonia, being a fixed salt, cannot exist in the atmosphere in the state of gas or vapor ; and then it is not the nitrate, but the carbonate of ammonia that has been signal- ized in the air. In bringing to mind the series of reactions of which I have spoken, it is not difficult to perceive how the nitrate of am- monia, precipitated in thunder-showers, and thus brought into contact with calcareous rocks, should suflfer decomposition, pass into the state of carbonate on the return of fair weather, and become fitted to undergo diffusion in the state of vapor through the atmosphere. We should in this way be led to regard the electrical agency, the flash of lightning, as the means by which the azote of the atmosphere is made fit' for assimilation by organized beings. In Europe, where thunder-storms are rare, an oflice of so much importance will per- haps be accorded reluctantly to the electricity of the clouds ; but ia tropical countries no difficulty would probably be felt on the matter. In the torrid zone, thunder-storms happen in one place or another iSt only every day, but every hour, and even every minute of eTery * Bonssingault, Annales de Chimic, t Izxi 1838. METEOROLOGY. THUNDER-STORMS. 495 hour throughout the year ; so that an observer, placed at th^j equator, were he endowed with organs of sufficient delicacy, would never lose the roll of the thunder. As the equator is quitted, the times at which rain falls become less specific or periodical. Under the tropics, the rains of thunder- storms, which are always the most copious, fall while the sun is in the neighborhood of the zenith. In the northern hemisphere, the greatest quantity of rain falls during winter ; and at places some- what far south on the temperate zone, the summer rain is altogether insignificant. In assuming the number 100 to express the whole annual quantity of rain, we should have in Madeira.. Lisbon. Winter 51 40 Spring 16 34 Summer 3 3 Autumn 30 23 Less rain falls in the eastern parts of Europe than in the western. The annual rain, too, is distributed very unequally over the diflferent seasons, as has been shown by M. Gasparin in a remarkable paper. If we express by 100 the quantity of rain gauged in a year, we should have for each season : In the weit of West of East of Germany. St. Petersburjf. Enrland. France. France. Winter 26 23 20 18 14 Spring 20 13 23 22 18 Summer 23 25 2d 37 37 Autumn 31 34 28 23 30 The quantity of rain which falls in the course of a year varies considerably according to the climate ; to form an idea of the extent of these variations, it is enough to notice the results obtained at dif- ferent observatories ; but it is less the annual quantity of rain that falls, than the way or quantities in which it is distributed over the diflferent months of the year, which interests the farmer ; upon this distribution, in fact, in many districts, depend the productiveness and fertility of the soil. I add a table of the mean quantities of rain in inches and lOths, that fall at London in the diflferent months of the year : Jan. Feb. March. April. May. June. July. Aug. Sept. Oct. Not. Dec. in. in. in. in. in. in. in. in. in. in. in. in. 1.45 1.25 1.17 1.29 1.61 1.72 2.39 1.80 1.84 2.08 2.20 1.72 ^ V. ON THK INFLUENCE OF AGRICULTURAL LABORS ON THE CLIMATE OF A COUNTRY IN LESSENING STREAMS, ETC. A question of great importance, and that is frequently agitated a this time, is, as to whether the agricultural labors of man are influ- ential in modifying the climate of a country or not 1 Do extensive clearings of woods, the draining and drying up of great swamps, which certainly influence the distribution of heat during the differ- ent seasons of the year, also exert an influence on the quantity of running water of a country, whether by lessening the quantity of rain which falls, or by promoting the more speedy evaporation of that which has fallen 1 lit sojae districts it has been held, that the streams which ha4 496 INFLUENCE OF AGRICULTURE ON CLIMATE. Deen used as moving powers, have very sensibly diminished. In other places, the rivers are said to have shrunk visibly ; and in others, springs that were formerly abundant, have almost dried up. Observations to this effect appear to have been principally made in valleys, surmounted by mountains ; and it is generally asserted, that the falling off in the springs and streams, had followed close upon the period at which the woods, scattered over the surface of the country, were cleared away without any kind of reserve. These statements, which may be assumed as facts, see.o to indi- cate that where the woods have been felled, it rains less than it did formerly ; this, indeed, is the general opinion entertained on the subject ; and were it admitted, without further examination, the natural inference from it would be, that the extension of agriculture diminishes the annual quantity of rain which falls in a country. But at the same time that the facts as stated have been observed, it has further been noticed that since the clearing of the surface from for- ests, the torrents and rivers which seemed to have lost in amount of regular supply of water, had become subject to sudden and extra- ordinary risings which had proved the cause of numerous and grave calamities. In the same way, springs that are generally all but dry, have been seen to burst forth again abundantly after violent storms. These latter observations, as may readily be imagined, are of a kind that should lead us not lightly to embrace the vulgar opinion, which maintains that the cutting down of the woods has had the effect of lessening the mean annual quantity of rain : it is not only not impos- sible that this quantity has not varied, but it may even happen that the mass of water which passes over the bed of a stream, supposed shrunken, is actually the same as ever it was ; the only difference may be, that now the flow is much less regular than it used to be : in former times the bed was always and more moderately full ; at present it is excessively full at intervals only. It is very possible, therefore, that here as elsewhere, occasionally, the appearance of the fact has been taken for the reality. It were very important to discover some natural index to a solution of the question at issue : whether or not the destruction of the forests that once covered the face of a district of country, had had the effect of lessening the mean annual fall of rain ? The lakes which are met with in plains, and at different levels in mountain ranges, seem to me peculiarly well calculated to throw .ight on this subject. Lakes may, in fact, be received as natural gauges of the running waters of a country. If the mass of the water contained in the lakes undergo change in one direction or another, it is obvious 'that this change, and the direction in which it has occur- red, will be proclaimed by the state or mean level of the lake or akes, which will differ for the same reason that it does at different seasons of the year, viz. as drought or rain prerails. The mean evel of the lake or lakes of a district will, therefore, fall, if the quantity of water which flows through that district diminishes ; the evel, on the contrary, will rise, if its streams increase ; and it will remain stationary if the afflux and efflux of the lake continue ud INFLUENCE OF AGRICULTURE ON CLIMATE. 497 changed. In the following remarks, I shall attach myself particu- larly to observations upon lakes which have no outlet, by reason of the facility with which any even slight change in the level of these must be discovered. I shall not, however, neglect those lakes which have an exit by a stream or canal, because I believe that the study of these may also lead to accurate enough results ; the only point requiring preliminary remark, is the sense in which the words, change of level, are to be taken. Geologists admit, that the level of the waters upon the surface of the globe has everywhere undergone great changes, whether atten- tion be directed to the shores of the sea or to those of great inland lakes. This fact is universal, and is questioned by none, but great diversity of opinion prevails in regard to the cause of the phenome- non. Some pretend, that in many cases the change of level is only apparent, — that the body of water has not sunk, but that the shores have risen ; others, again, maintain that there has been a true dimi- nution in the mass of fluid, a true drying up, and that its level has actually sunk. I shall not, in this place, enter upon the great geo- logical question ; the variations which are there signalized are often of vast extent, and involve the supposition of violent catastrophes, which, in a general way, were long anterior to the historical epoch. I shall only refer to changes of level observed in lakes by our ances- tors or contemporaries ; in a word, to facts which have taken place under the eyes of men, inasmuch as it is the influence of their ag- ricultural labors upon the meteorological state of the atmosphere, which I am seeking to appreciate. The facts upon which I shall more particularly dwell, were observed in South America ; but I shall show that what is true with regard to this continent, is true also with reference to any other continent. One of the most interesting portions of Venezuela is, undoubtedly, the valley d'Aragua. Situated at a short distance from the sea- board, possessed of a warm climate, and of a soil fertile beyond ex- ample, it combines within itself all the varieties of agriculture that belong in peculiar to tropical regions ; on the hillocks which rise in the bottom of the valley, are seen fields which bring to mind the agriculture of Europe. Wheat succeeds pretty well upon the heights which surround La Vittoria. Bounded on the north by a chain of hills which run parallel with the sea-board, and to the south by the range which separates it from Llanos, the Aragua Valley is limited on the east and west by a series of lesser elevations, which shut it in completely. In consequence of this peculiar configuration of country, the rivers which rise in its interior have no outlet to the ocean ; their waters accumulate in the lowest part of the valley, and form the beautiful lake Valentia. This lake, which M. de Humboldt says exceeds the lake Neufch^tel in size, is raised about 1300 feet above the level of the sea ; it is about ten leagues in length, and about two leagues and a half where it is widest. At the time when M. de Humboldt visited the Aragua Valley, the inhabitants were struck with the gradual diminution which had been going on in the waters of the lake during the last thirty years. J^ 42* 498 INFLUENCE OF AGRICULTURE ON CLIMATE. was enough to compare the statements of older writers with its con • dition at this time, to obtain conviction that the waters had, in fact, rery much diminished. Oviedo, for instance, who visited the valley frequently towards the end of the sixteenth century, says, that the town of New Valencia was founded in 1555, at the distance of half a league from the lake ; in 1800, M. de Humboldt ascertained that the lake was upwards of 549 yards, or upwards of 3y miles, instead of about If mile from its banks. The appearance of the surface also gives new proof of the fact of the recession of the water ; certain hillocks which rise in the plain still preserve the title of islands, which, undoubtedly, they formerly received with propriety, when they were surrounded by water. The land which had been left by the retreat of the lake, soon became transformed into beautiful plantations of cotton-trees, bananas, and sugar-canes. Buildings which had been erected on the banks were left, year after year, further and further from them. In 1796, new islets made their appearance. An important military position, a for- tress built in 1740, in the Isle de la Cabrera, was then upon a penin- sula. Finally, in two islets of granite, M. de Humboldt discovered, several yards above the level of the lake, a bed of fine sand, mixed with fresh-water shells. These facts, so certain, so unquestionable, did not pass without numerous explanations from the wise men of the country, who, as if by common consent, fixed upon a subterra- nean exit for the waters of the lake. M. de Humboldt, after the most careful examination of all the circumstances, did not hesitate to ascribe the diminution of the waters of the lake Valencia to the extensive clearings which had been effected in the course of half a century in the Aragua valley. " In felling the trees which covered the crowns and slopes of the mountains," says this celebrated traveller, *' men in all climates seem to be bringing upon future generations two calamities at once — a want of fuel and a scarcity of water."* In the year 1800, the population of this favored valley, where the cultivation of indigo, of cotton, of cocoa, and the cane had made im- mense progress, was as dense as it was in the most thickly popula- ted districts of England or France, and every one was delighted with the appearance of comfort that prevailed in the numerous villa- ges of this industrious country. Twenty-five years after M. de Humboldt, I explored in my turn the Valley d'Aragua, having fixed my residence in the little town of Maracaibo. The inhabitants had now remarked that for several years, not only had the lake ceased to diminish, but that it had even risen very perceptibly. Some fields that were formerly covered with cotton plantations were now submerged. The Isles de las Nuevas Aparacidas, which had risen from the waters in 1796, had again be- come shoals dangerous to navigation ; the tongue of earth, De la Cacrera, on the north side of the valley, had become so narrow that tl)6 gligh est rise in the water of the lake covered it completely ; a • Humboldt, vol v. p. 173. I INFLUENCE OF AGRICULTURE ON CLIMATE. 499 continuous N.E. wind was sufficient to flood the road which led from Maracaibo to New Valencia ; in short, the fears which the in- habitants of the lake had entertained for so long a period had entirely changed their nature ; they were now no longer afraid of the lake dry- ing up ; they saw with dismay that if the water continued to rise as it had done lately, it would in no long space of time have drowned some of the most valuable estates, &c. Those who had explained the diminution of the lake by supposing subterraneous canals, now hastened to close them up in order to find a cause for the rise in the level of the water. In the course of the last twenty-two years important political events had transpired. Venezuela no longer belonged to Spain ; the peaceful valley d'Aragua had been the theatre of many a bloody con- test ; war to the knife had desolated this beautiful country and deci- mated its inhabitants. On the first cry of independence raised, a great number of slaves found freedom by enlisting under the banners of the new republic ; agricultural operations of any extent were abandoned, and the forest, which makes such rapid progress in the tropics, had soon regained possession of the surface which man had won from it by something like a century of sustained and painful toil. With the increasing prosperity of the valley many of the prin- cipal tributaries to the lake had been turned aside to serve as means of irrigation, so that the beds of some of the rivers were absolutely dry for more than six months in the year. At the period which I now refer to, the water was no longer used in this way, and the beds of the rivers were full. Thus with the growth of agricultural indus- try in the Valley d'Aragua, when the extent of cleared surface was continually on the increase, and when great farming establishments were multiplied, the level of the water sunk ; but by and by, during a period of disasters, happily passing in their nature, the process of clearing is arrested, the lands formerly won from the forest are in part restored to it, and then the waters first cease to fall in their le- vel, and by and by show an unequivocal disposition to rise. I shall now, without, however, quitting America, carry my read- ers into a district where the climate is analogous to that of Europe, where the surface is occupied by immense fields, covered with the cereals as with us. I speak of the table-knds of New Granada, of those valleys raised from 10,000 to 13,000 and 14,000 feet above the level of the sea, in which the mean temperature throughout the year ranges from 58° to about 62° Fahr. Lakes are frequent in the Cordilleras ; and it would be easy for me to describe a great num- ber ; I shall, however, confine myself to those which became subjects of observation in former times. The village of Ubate is now situated in the neighborhood of two lakes. Some seventy years ago these two lakes formed but one ; the old inhabitants saw the water shrinking and new fields pre- senting themselves year after year. At this present time fields of wheat of extraordinary luxuriance occupy levels that were com- pletely inundated 30 years ago. It is enough indeed to perambulate the neighborhood of Ubate 500 METEOROLOGY. to consult the old sportsmen of the country, and to refer to the annals of the various parishes, to be satisfied that extensive forests have been cut down in the whole of the surrounding- country : the clearing, in fact, still continues ; and it is certain that the recession of the waters, although much slower than it was in former times, has not yet entirely ceased. A lake, situated in the same valley, to the east of Ubate, deserves our particular attention. By means of barome trie measurements, made with extreme care, I found that this lake had precisely the same level as that of Ubate. Nearly two centuries ago, it was vis- ited by Piedrahita, Bishop of Panama, an author of great accuracy, to whom we owe the history of the conquest of New Granada. He states this lake to be ten leagues in length, by three leagues in breadth ; but Dr. Roulin having had occasion, a few years ago, to make a plan of the lake, he found it a league and a half in length, by one league in breadth ; my own impression is, that at the time Piedrahita wrote, there was but a single lake, extending all the waj from Ubate to Zimijaca, not two lakes as at present, a supposition which would take away every thing like exaggeration from the state- ment of Piedrahita. But the fact of the retreat of the waters of these lakes is unquestioned ; the inhabitants of Zimijaca all know that the village was founded close to the lake, whereas, at the pres- ent time, it is nearly a league from its banks. Formerly, there was no difficulty in obtaining all the building timber that was wanted ; the mountains which rose from the valley on either hand were cov- ered up to a certain height with the trees proper to these cold re gions ; the oak of the Andes abounded; numerous myrcias were also in existence, from which abundance of wax was obtained : at the present time these mountains are almost stripped of their trees, an event mainly brought about by the eagerness to procure fuel in manufacturing salt from the springs of Taosa and Enemocon. To these authentic facts, which I could multiply and support by many others of a similar kind, it may be replied, that the diminution of the water, incontestable as it is, might perhaps have taken place without the clearing away of the forests. It may indeed be main- tained, that the drying up of the waters is owing to a totally differ- ent cause, altogether unknown to us ; that it must be ranked among the numerous phenomena, the reality of which we perceive, but without being able to render any account of their cause. I cannot, in the instance last quoted, as in that of the lake of Va- lencia, refer to any increase of the lake connected with the suspen- sion of agriculture, or the reappearance of the forest. I might, however, adduce in favor of the opinion which I defend, the slow- ness with which the decrease in the lakes of the valley of Ubate has lately gone on, and since the felling of trees in the neighborhood nas almost entirely ceased. Extensive plots of fertile ground are now no longer left dry and available to the husbandman by the re- reat of the lake ; he already begins to think of means for obtaining oy artifice that which nature, assisted by the clearing of the country presented him with in former times. In the year 1826 there was » METEOROLOGY. 501 Bpeculation on foot for draining the valley completely by cutting a canal and letting off the water. Further proof of the fact which 1 am urging is obtained in another way. It is not difficult to show, that lakes in the immediate vicinity of those that have shrunk most remarkably, but around which no destruction of the forest has taken place, have undergone no change in their level. The lake of Tota, situated at no great distance from the valley of Ubate, at an eleva- tion that must approach 13,000 feet above the level of the sea, in a region where vegetation has almost entirely disappeared, has pre- served its pristine level unaltered. The lake is nearly circular ; and Piedrahita, in 1542, gives it two leagues in breadth. It is sub- ject to violent storms, which render its navigation dangerous ; and even travelling along its banks, from the particular circumstances in which the road is situated, with tho .ake on one hand and a perpen- dicular cliff upon the other, is not without risk. In 1652, the road passed as it does at present, the water laving the foot of the same rocks, and its level having suffered no change, any more than the sterile country which surrounds it. I shall conclude what I have to say on the lakes of South America by speaking of that of Quilatoa, because it has been made the subject of accurate observations sufficiently remote from one another — 1740 and 1831. Living at Latacunga, a town situated at no great distance from Cotopaxi, the traveller is sure to hear of the wonders of the Laguna da Quilatoa. From time to time this lake, it is said, casts forth flames which set fire to the shrubs and withered grass that grow upon its banks, and frequent detonations are heard, the sound of which extends to a great distance. M. de la Condamine, in 1738, visited this lake, which he found of a circular form, and about 1278 feet in diameter ; on the 28th November, 1831, 1 also visited the Lake of Quilatoa. It cannot be better compared to any thing than to the crater of a volcano filled with water ; I found it nearly 13,000 feet above the level of the sea, in the cold region, therefore ; and indeed it is surrounded with immense pastures ; but the information which I obtained from the shepherds in the neighborhood of the Lake of Quilatoa, dissipated all that was marvellous in its history ; they had never seen any flames issue from its bosom, they had never heard any detonations ; in short, I found the lake as M. de la Con- damine appears to have found it, every thing having remained for nearly a century without change. The study of the lakes which are so common in Asia, would probably supply conclusions similar to those deduced from observa- tions made in South America, viz., that the waters which irrigate a country diminish as the forests are cleared away, and as agriculture extends. The recent labors of M. de Humboldt, which have thrown so much new light upon this quarter of the world, appear to leave no doubt upon the subject. After having shown that the system of the Altai is about to lose itself by a succession of slopes in the steppes of Kirgiz, and that consequently the Ural chain is not con- nected with that of the Altai, as was generally belioved, this celebrated ft02 METEOROLOGY. geographer shows, that precisely in the situation where the Alghinic mountains are usually set down, a remarkable region of lakes com- mences, which extend into the plains that are traversed by the Ichim the Omsk, and the Obi.* It would appear that these numerous lakes are remainders as it were of an immense sheet of water, which formerly covered the whole of the country, and which had become divided into so many particular lakes by the configuration of the surface. In crossing the steppe of Baraba, in his way from Tobolsk to Baraoul, M. de Humboldt perceived everywhere that the drying up of waters increases rapidly under the influence of tile cultivation of the soil. Europe also possesses its lakes ; and we have still to examine them from the particular point of view which engages us. M. de Saussure, in his first inquiries in regard to the temperature of the lakes of Switzerland, examined those which are situated at the foot of the first line of the Jura. The Lake of NeufchS.tel is eight leagues in length, and its greatest breadth does not exceed two leagues. On visiting it, Saussure was struck with the extent which this lake must formerly have possessed ; for, as he says, the ex- tensive level and marshy meadows which terminate it on the south- west, had unquestionably been covered with water at a former period. The Lake of Bienne is three leagues long and one broad ; it is separated from the Lake of Neufch^tel by a succession of plains that were probably inundated. Lake Morat is also separated from the Lake of Neufch4tel by low and level marshes, which beyond all question were formerly sub- merged. Unquestionably, adds Saussure, the three great lakes of Neufch^tel, Bienne, and Morat, were formerly connected, and formed one great sheet of water.f In Switzerland, as in America and Asia, the old lakes, those thai may be spoken of under the title of the primitive lakes, and which occupied the bottoms of the valleys when the country was unculti- vated and wild, have become divided, and now form a variable num- ber of smaller and independent lakes. I shall wind up the present subject by referring to the observations of Saussure upon the Lake of Geneva, which may be looked upon as the starting point of the admirable works of this distinguished philosopher. Saussure admits, that at an epoch long anterior to the times of history, the mountains which surround this lake were themselves submerged ; a great catastrophe let off this immense collection of water, and by and by the current possessed no more than the bottom of the valley ; the Lake of Geneva was formed. In merely considering the monuments left by man, it is impossible to doubt that within 1200 or 1300 years the waters of the Lake of Geneva have gradually fallen in their level. It is evidently upon the levels which have thus been left that the quarter de Rive, and the lower streets of the city of Geneva have been built. This de ♦ Humboldt, Fragmens Asiatiques, t. i. p. 40-50. t Saussure, Voyage dans les Alpes, t. ii. chap. 6. METEOBOLOGY. 508 pression of the surface, continues Saussure, is not merely the effect of any deepening of the bed of the Rhone, by which the lake is dis- charged ; it has also been produced by a diminution in the quantity of water which flows into it. The conclusions which it seems legitimate to draw from the ob- servations of Saussure are, that in the course of from 1200 to 1300 years the quantity of running water has sensibly diminished in the districts around the Lake of Geneva. No one will, I apprehend, deny that in this long period there have not been extensive clear- ings of forest lands in Switzerland, and a continual increase in the extent of cultivated land in this beautiful country. Here, conse- quently, as elsewhere, an attentive examination of "the levels of the lakes leads us to conclude, that where extensive clearings froja for- est have been effected, where agriculture has extended, that there has in all probability been diminution of the running waters which irrigate the surface ; while in those districts where no change has been effected, the amount of running stream does not appear to have undergone any variation. The effect of forests considered in this point of view would there- fore be to keep up the amount of the waters which are destined for mills and canals ; and next to prevent the rain-water from collecting and flowing away with too great rapidity. That a soil covered with trees is further less favorable to evaporation than ground that has been cleared, is a truth that all will probably admit without discus- sion. To be aware that it is so, it is enough to have travelled, a short time after the rainy season, upon a road which traverses in succession a country that is free from forests, and one that is thickly wooded. Those parts of the road that pass through the unencum- bered country are found hard and dry, while those that traverse the wooded districts are wet, muddy, and often scarcely passable. In South America, more perhaps than anywhere else, does the obsta- cle to evaporation from a soil thickly shaded with forests, strike the traveller. In the forests the humidity is constant, it exists long after the rainy season has passed ; and the roads that are opened through them remain through the whole year deeply covered with mire : the only means known of keeping forest ways dry, is to give them a width of from 260 to 330 feet, that is to say, to clear the country in their course. If once the fact is admitted that running streams are diminished in size by the effect of felling the forests and the extension of agri- culture, it imports us to examine whether this diminution proceeds from a less quantity of rain, or from a greater amount of evapora- tion, or whether perchance it maybe owing to the practice of irrigation. I set out with the principle that it must be next to impossible to specify the precise share which each of these diflferent causes has in the general result; I shall, nevertheless, endeavor to appreciate them in a summary way. The discussion will have gained some- thing if it be proved that there may be diminution of running streams 'n consequence of clearing off the forests alone, without the whole of the causes being presumed to act simultaneously. 504 METEOROLOGy. "With regard to irrigation, it is necessary to distinguish between that case in which an extensive farm has been substituted for an im- penetrable forest, and that in which an arid soil, which never sup- ported wood, has been rendered productive by the industry of man In the first case it is very probable that irrigation will have contri- buted but little to the diminution in the mass of running water ; it may readily be imagined that the quantity of water used up by a dense forest will equal, at all events, if not exceed, that which wil be required by any of the vegetables which human industry substi- tutes for it. In the second case, that is to say, where a great extent of waste country has been brought under cultivation, there will evi- dently be consumption of water by the vegetation which has been fostered upon the surface ; agricultural industry will thus tend to diminish the quantity of water which irrigates a country. It is ex- tremely probable that it is to a circumstance of this kind that we must ascribe the diminution of the lakes which receive so large a proportion of the running streams of the north of Asia. It is al- most unnecessary to add, that in circumstances of this kind the effect which is due to the simple evaporation of rain- water is not increased ; the loss by this means must be rather less, because from a surface covered with plants evaporation takes place more slowly than from one that is devoid of vegetation. In the considerations which I have presented upon the lakes of Venezuela, of New Granada, and of Switzerland, the diminution may- be directly ascribed to a less mean annual quantity of rain ; but it may with equal reason be maintained to be a simple consequence of more rapid evaporation. There are, in fact, a variety of circumstances under the influence of which the diminution of running streams can be shown to be con- nected with more active evaporation. I shall confine myself to the mention of two particular instances, one noticed by M. Desbassyns de Richemond, in the Island of Ascension ; the other is from obser- vations by myself, and is among the number of facts which I regis tered during my residence for several years at the mines" of Mar mato. In the Island of Ascension there was an excellent spring situated at the foot of a mountain originally covered with wood ; this spring became scanty and dried up after the trees which covered the moun- tain had been felled. The loss of the spring was rightly ascribed to the cutting down of the timber. The mountain was therefore plant- ed anew, and a few years afterwards the spring reappeared by de- grees, and by and by flowed with its former abundance. The metalliferous mountain of Marmato is situated in the province of Popayan, in the midst of immense forests. The stream along which the mining works are established is formed by the junction of several small rivulets which take their rise in the table-land of San Jorge. The country which overlooks the establishment is thickly wooded. In 1826, when I visited the mines for the first time, Marmato con- sisted of a few miserable cabins, inhabited by negro slaves. !■ METEOROLOGY. 505 1830, when I quitted the country, Marmato had the most flourishing appearance • it was covered with workshops, it had a foundry of gold, machinery for grinding and amalgamating the ores, &c., and a free population of nearly three thousand inhabitants. It may be readily imagined, that in the course of these four years an immense quantity of timber had been cut down, not only for the construction of machinery and of houses, but as fuel, and for the manufacture of charcoal. For facility of transport, the felling had principally gone on upon the table-land of San Jorge. But the clearing had scarcely been effected two years before it was perceived that the quantity of water for the supply of the machinery had notably diminished. The volume of water had been measured by the work done by the ma- chinery, and actual gauging at diiferent times showed the progressive diminution of the water. The question assumed a serious aspect, because at Marmato any diminution in the quantity of the water, which is the moving power, would be of course attended with a pro- portional diminution in the quantity of gold produced. Now, in the Island of Ascension, and at Marmato, it is highly improbable that any merely local and limited clearing away of the forest should have had such an influence upon the constitution of the atmosphere as to cause a variation in the mean annual quantity of rain which falls in the country. More than this, as soon as the diminution of the stream at Marmato was ascertained, a pluviometer, or rain-gauge, was set up, and in the course of the second year of observation a larger quantity of rain was gauged than in the first year, although the clearing had been continued ; still there was no appreciable in- crease in the size of the running stream. A couple of years of observation are unquestionably insufficient to show any definitive variation in the annual quantity of rain that falls. But the observations made at Marmato still establish the fact thai .he mass of running water had diminished in spite of the larger quanti- 'y of rain which fell. It is therefore probable that local clearings of •brest land, even of very moderate extent, cause springs and rivu- fets to shrink, and even to disappear, without the effect being ascri- bable to any diminution in the amount of rain that falls. We have still to inquire, whether extensive clearings of the forest — clearings which embrace a whole country — cause any dimi- nution in the quantity of rain that falls. Unfortunately, the observa- ions which we have upon the quantity of rain which falls in par- ticular districts, are only of sufficient antiquity and accuracy in Europe to be worthy of any confidence, and there the soil was cleared before observation, in the generality of instances, began. The United States of America, where the forests are disappearing with such rapidity, will probably one day afford elements for the complete and satisfactory solution of the question, whether or not the cutting down of forests causes any diminution in the quantity of rain which falls in the course of the year. In studying the phenomena accompanying the fall of rain in the tropics, I have come to a conclusion which I have already made known to many observers. My own opinion is, that the felling of 43 506 METEOROLOGY forests over a large extent of country has always the effect of less ening the mean annual quantity of rain. • It has long been said, that in equinoctial countries the rainy sea- son returns each year with astonishing regularity. There can be no doubt of the general accuracy of this observation, but the mete- orological fact must not be announced as universal and admitting of no exception ; the regular alternation of the dry and rainy season is as perfect as possible in countries which present an extreme variety of territory. Thus, in a country whose surface is covered with forests and rivers and lakes, with mountains and plains, and table-lands, the periodical seasons are quite distinct. But it is by no means so where the surface is more uniform in its character. The return of the rainy season will be much less regular if the soil be in general dry and naked ; or if extensive agricultural operations take the place of the primeval forest ; if rivers are less common, and lakes less fre- quent. The rains will then be less abundant ; and such countries will be exposed, from time to time, to droughts of long continuance If, on the contrary, thick forests cover almost the whole of the terri- tory, if its rivulets and rivers be numerous, and agriculture be limited in extent, irregularity in the seasons will then take place, but in a different way ; the rains will prevail, and in some seasons they will become as it were incessant. The continent of America presents us, on the largest scale, with two regions placed in the same conditions as to temperature, but in which we successively encounter the circumstances which are most favorable to the formation and fall of rain in one case, and to its absence in the other. Setting out from Panama, and proceeding towards the south, we encounter the Bay of Cupica, the provinces of San Bonaventura Choco, and Esmeraldas ; in this country, covered with thick forests and intersected with a multitude of streams, the rains are almost incessant ; in the interior of Choco, scarcely a day passes without rain. Beyond Tumbez, towards Payta, an order of things entirely different commences : the forests have entirely disappeared, the soil is sandy, agriculture scarcely exists, and here rain is almost un- known. When I was at Pajrta, the inhabitants informed me that it had not rained for seventeen years ! The same want of rain is common in the whole of the country which surrounds the desert of Sechura, and extends to Lima ; in these countries rain is as rare as trees are. In Choco, where the soil is thickly covered with trees, it rains almost continually ; and on the coasts of Peru, where the soil is sandy, without trees, and devoid of verdure, it never rains ; and this, as I have said, under a climate which enjoys the same tempera- ture, and whose general features and distance from the mountains are nearly the same. Piura is not more remote from the Andes of Assuay than are the moist plains of Choco from the Western Cor- dillera. The facts which ha>e now been laid before the reader seem to authorize me to infer — METEOROLOGY. 507 Ist. That extensive destruction of forests lessens the quantity of running water in a country. 2d That it is impossible to say precisely whether this diminution is due to a less mean annual quantity of rain, or to more active evaporation, or to these two effects combined. 3d. That the quantity of running water does not appear to have suffered any diminution or change in countries which have known nothing of agricultural improvement. 4th. That independently of preserving running streams, by oppo- sing an obstacle to evaporation, forests economize and regulate their flow. 5th. That agriculture established in a dry country, not covered with forests, dissipates an additional portion of its running water. 6th. That clearings of forest land of limited extent may cause the disappearance of particular springs, without our being therefore authorized to conclude that the mean annual quantity of rain has been diminished. 7th, and lastly. That in assuming the meteorological data collect- ed in intertropical countries, it may be presumed that clearing off the forests does actually diminish the mean annual quantity of rain which falls.* ♦ These meteorological observations are highly interesting, and worthy of every consideration. That unforesting a country makes it absolutely drier, seems unques- tionable ; but whether that be in consequence of less rain falling, or of that which falls going further, making more show, cannot be easily determined. It does not seem very legitimate to decide, that because a country is covered with wood, therefore it is wet : the converse of that proposition appears much more probable— viz., that because a country is wet, therefore it is covered with trees. There is one part of the ocean which is called by mariners " The Rains ;" because it rains there almoat ceaselessly, as it does in the province of Choco : but " The Rains" has no forests to account for its dripping sky. Did that region consist of dry land instead of salt-water, then doubt- less its surface would be covered, as that of Choco is, with an impenetrable forest The subject is adverted to here, however, not to discuss the general question, but to throw out the suggestion that under the hand of man, the soil and even the climate of our immense Australian possessions might possibly be improved. Drought is the grand enemy of Australian settlers ; and the country is generally barren of wood. Governors, district governments, and farmers, and all who are interested in the pros- perity of the colony, surely ought to encourage, by every possible means, the growth of the taller trees and shrubs that are indigenous to the country. Expeditions might be made once or twice a year, at the proper season, for scattenn^ or planting the seeds of these trees or shrubs. Could every knoll within a hundred miles of Sidney be seen crowned with a thick screen of leafy trees, there can be little doubt but that the rain which falls would be economized ; and that the beds of the rivers, instead of being dry for eight or nine months, would be occupied all the yetti round by at least a moderate stream of water.— Eno. Ed. THK END. «1 IN CIRCULATION DEPARTMENT 0 : 202 Main Library ^-^ PERIOD 1 2 3 \AEUSE 5 6 >OKS MAY BE RECALLED AFTER 7 DAYS als and Recharges may be made 4 days prior to the due date may be Renewed by calling 642-3405. DUE AS STAMPED BELOW J a 1990 "0, Diwv:. i - ->::^' '. s : : A -- '• • •/ a Ibbb NO. DD6 L-100in-7.'52(A2528sl6)476 UNIVERSITY OF CALIFORNIA, BERKf BERKELEY, CA 94720